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Sample records for 2-4 kev band

  1. Underwater wireless sensor communications in the 2.4 GHz ISM frequency band.

    PubMed

    Lloret, Jaime; Sendra, Sandra; Ardid, Miguel; Rodrigues, Joel J P C

    2012-01-01

    One of the main problems in underwater communications is the low data rate available due to the use of low frequencies. Moreover, there are many problems inherent to the medium such as reflections, refraction, energy dispersion, etc., that greatly degrade communication between devices. In some cases, wireless sensors must be placed quite close to each other in order to take more accurate measurements from the water while having high communication bandwidth. In these cases, while most researchers focus their efforts on increasing the data rate for low frequencies, we propose the use of the 2.4 GHz ISM frequency band in these special cases. In this paper, we show our wireless sensor node deployment and its performance obtained from a real scenario and measures taken for different frequencies, modulations and data transfer rates. The performed tests show the maximum distance between sensors, the number of lost packets and the average round trip time. Based on our measurements, we provide some experimental models of underwater communication in fresh water using EM waves in the 2.4 GHz ISM frequency band. Finally, we compare our communication system proposal with the existing systems. Although our proposal provides short communication distances, it provides high data transfer rates. It can be used for precision monitoring in applications such as contaminated ecosystems or for device communicate at high depth.

  2. Underwater Wireless Sensor Communications in the 2.4 GHz ISM Frequency Band

    PubMed Central

    Lloret, Jaime; Sendra, Sandra; Ardid, Miguel; Rodrigues, Joel J. P. C.

    2012-01-01

    One of the main problems in underwater communications is the low data rate available due to the use of low frequencies. Moreover, there are many problems inherent to the medium such as reflections, refraction, energy dispersion, etc., that greatly degrade communication between devices. In some cases, wireless sensors must be placed quite close to each other in order to take more accurate measurements from the water while having high communication bandwidth. In these cases, while most researchers focus their efforts on increasing the data rate for low frequencies, we propose the use of the 2.4 GHz ISM frequency band in these special cases. In this paper, we show our wireless sensor node deployment and its performance obtained from a real scenario and measures taken for different frequencies, modulations and data transfer rates. The performed tests show the maximum distance between sensors, the number of lost packets and the average round trip time. Based on our measurements, we provide some experimental models of underwater communication in fresh water using EM waves in the 2.4 GHz ISM frequency band. Finally, we compare our communication system proposal with the existing systems. Although our proposal provides short communication distances, it provides high data transfer rates. It can be used for precision monitoring in applications such as contaminated ecosystems or for device communicate at high depth. PMID:22666029

  3. Measurements of the H2 4-0 quadrupole bands of Uranus and Neptune

    SciTech Connect

    Smith, W.H.; Macy, W. Jr.

    1980-01-01

    It is found that the equivalent widths of the lines of the 4-0 H2 quadrupole band on Uranus and Neptune are substantially smaller than the values found by some previous observers. An analysis of the results based on a range of atmospheric models yields H2 abundances of 240 + or - 60 km-amagats for Uranus and greater than approximately 200 km amagats for Neptune.

  4. Degree of interdependence among atmospheric optical thicknesses in spectral bands between 0.36-2.4 micron

    NASA Technical Reports Server (NTRS)

    Fraser, R. S.

    1975-01-01

    The degree of dependence among the atmospheric optical thicknesses that are measured in nonselective absorption bands is studied. The observations were made previously in many spectral bands within the range 0.36-2.4 micron from near sea level in two continents where urban and industrial pollutions were weak. The sample covariance matrices and corresponding eigenvalues and eigenvectors are computed. The two highest eigenvalues account for 90% of the total variance in 10 spectral bands within the range 0.4-1.6 micron. The linear regression of the optical thickness on the total precipitable water vapor is computed to determine the attenuation coefficient that is associated with water vapor. This coefficient shows a rapid power-law decrease with wavelength in the visible spectrum and indicates that numerous water particles of radius 0.03-0.06 micron cause the attenuation.

  5. Low-temperature volume radiation annealing of cold-worked bands of Al-Li-Cu-Mg alloy by 20-40 keV Ar+ ion

    NASA Astrophysics Data System (ADS)

    Ovchinnikov, V. V.; Gushchina, N. V.; Mozharovsky, S. M.; Kaigorodova, L. I.

    2017-01-01

    The processes of radiation-dynamic nature (in contrast to the thermally-activated processes) in the course of short-term irradiation of 1 mm thick bands of cold-worked aluminum alloy 1441 (of system Al-Li-Cu-Mg) with Ar+ 20-40 keV were studied. An effect of in-the-bulk (throughout the whole of metal bands thickness) low-temperature radiation annealing of the named alloy, multiply accelerated as compared with common thermal annealing processes was registered (with projected ranges of ions of considered energies definitely not exceeding 0.1 μm). The processes of recrystallization and intermetallic structure changes (occurring within a few seconds of Ar+ irradiation) have the common features as well as the differences in comparison with the results of two hour standard thermal annealing.

  6. Diagenetic nanometric ferrihydrite clusters in 2.4 Ga carbonate banded iron formations from the Minas Supergroup

    NASA Astrophysics Data System (ADS)

    Morgan, R. R.; Wirth, R.; Orberger, B.

    2011-12-01

    Iron (oxyhydr)oxides, abundant on the Martian surface, can be formed via magmatic, hydrothermal, diagenetic or weathering processes. At present their formation are poorly understood. The study of Precambrian samples may be key to better understanding the Martian environmental conditions, past and present. Our FIB-TEM study of iron oxides from a banded iron formation (Gandarela Formation (2.4 Ga), Minas Supergroup, Minas Gerais, Brazil) provides a Precambrian terrestrial analogue for the formation of diagenetic ferrihydrite. A detailed mineralogical, petrological and FIB-TEM study of a carbonate banded iron formation (known locally as carbonate itabirites-CI) has revealed the presence of previously unknown nano-platelets of ferrihydrite, goethite and hematite hosted within dolomite. The CI are millimetrically alternating bands of pink dolomite and grey hematite. The fine sedimentary laminations, micritic sized dolomite crystals and nano (oxyhydr)oxide inclusions in the dolomite grains likely reflect a primary origin during deposition. The pink colour of the dolomite is a result of the nano inclusions of euhedral hematite (≤1 μm) and nano platelets of ferrihydrite and gothite (≥10 nm). The smallest ferrihydrites (~10 nm) are mostly rounded with a hint of a euhedral shape whereas the larger ferrihydrites (400 nm) are euhedral platelets. Clinochlore and talc indicate that the CI have experienced greenschist facies metamorphism at two major intervals; the Transamazonian at 2.1 Ga and the Brasiliano at 0.8 Ga. The ferrihydrites occur either as individual droplets or as clusters of up to 30 crystals. A common feature of all the ferrihydrite platelets is their close association with porosity indicating that the ferrihydrite platelets are a result of precipitation from fluid inclusions trapped within the dolomite during its formation. Deciphering the relative time of precipitation of the ferrihydrite is key in understanding the overall history of the rock. Dislocations

  7. Evidence of Eu{sup 2+} 4f electrons in the valence band spectra of EuTiO{sub 3} and EuZrO{sub 3}

    SciTech Connect

    Kolodiazhnyi, T.; Valant, M.; Williams, J. R.; Bugnet, M.; Botton, G. A.; Ohashi, N.; Sakka, Y.

    2012-10-15

    We report on optical band gap and valence electronic structure of two Eu{sup 2+}-based perovskites, EuTiO{sub 3} and EuZrO{sub 3} as revealed by diffuse optical scattering, electron energy loss spectroscopy, and valence-band x-ray photoelectron spectroscopy. The data show good agreement with the first-principles studies in which the top of the valence band structure is formed by the narrow Eu 4f{sup 7} electron band. The O 2p band shows the features similar to those of the Ba(Sr)TiO{sub 3} perovskites except that it is shifted to higher binding energies. Appearance of the Eu{sup 2+} 4f{sup 7} band is a reason for narrowing of the optical band gap in the title compounds as compared to their Sr-based analogues.

  8. Evidence of Eu2+ 4f electrons in the valence band spectra of EuTiO3 and EuZrO3

    NASA Astrophysics Data System (ADS)

    Kolodiazhnyi, T.; Valant, M.; Williams, J. R.; Bugnet, M.; Botton, G. A.; Ohashi, N.; Sakka, Y.

    2012-10-01

    We report on optical band gap and valence electronic structure of two Eu2+-based perovskites, EuTiO3 and EuZrO3 as revealed by diffuse optical scattering, electron energy loss spectroscopy, and valence-band x-ray photoelectron spectroscopy. The data show good agreement with the first-principles studies in which the top of the valence band structure is formed by the narrow Eu 4f7 electron band. The O 2p band shows the features similar to those of the Ba(Sr)TiO3 perovskites except that it is shifted to higher binding energies. Appearance of the Eu2+ 4f7 band is a reason for narrowing of the optical band gap in the title compounds as compared to their Sr-based analogues.

  9. A new grating X-ray spectrometer for 2-4 keV enabling a separate observation of In-Lβ and Sn-Lα emissions of indium tin oxide.

    PubMed

    Terauchi, Masami; Takahashi, Hideyuki; Handa, Nobuo; Murano, Takanori; Koike, Masato; Kawachi, Tetsuya; Imazono, Takashi; Hasegawa, Noboru; Koeda, Masaru; Nagano, Tetsuya; Sasai, Hiroyuki; Oue, Yuki; Yonezawa, Zeno; Kuramoto, Satoshi

    2013-06-01

    A new multilayer-coated varied line-spaced grating, JS4000, was fabricated and tested for extending the upper limit of a grating X-ray spectrometer for electron microscopy. This grating was designed for 2-3.8 keV at a grazing incidence angle of 1.35°. It was revealed that this new multilayer structure enables us to take soft-X-ray emission spectra continuously from 1.5 to 4.3 keV at the same optical setting. The full-width at half maximum of Te-L(α1,2) (3.8 keV) emission peak was 27 eV. This spectrometer was applied to indium tin oxide particles and clearly resolved Sn-L(α) (3444 eV) and In-L(β1) (3487 eV) peaks, which could not be resolved by a widely used energy-dispersive X-ray spectrometer.

  10. A multilayer grating with a novel layer structure for a flat-field spectrograph attached to transmission electron microscopes in energy region of 2-4 keV

    SciTech Connect

    Imazono, T.; Koike, M.; Koeda, M.; Nagano, T.; Sasai, H.; Oue, Y.; Yonezawa, Z.; Kuramoto, S.; Terauchi, M.; Takahashi, H.; Handa, N.; Murano, T.

    2012-05-17

    A multilayer mirror with a novel layer structure to uniformly enhance the reflectivity in a few keV energy range at a fixed angle of incidence is invented and applied to a multilayer grating for use in a flat-field spectrograph attached to a conventional electron microscope. The diffraction efficiency of the fabricated multilayer grating having the new layer structure is evaluated at the angle of incidence of 88.65 deg. in the energy region of 2.1-4.0 keV. It is shown that the multilayer grating is effective to uniformly enhance the diffraction efficiency and able to be practically used in this energy region.

  11. Sub-arcsec X-Ray Telescope for Imaging The Solar Corona In the 0.25 - 1.2 keV Band

    NASA Technical Reports Server (NTRS)

    Gallagher, Dennis; Cash, Webster; Jelsma, Schuyler; Farmer, Jason

    1996-01-01

    We have developed an X-ray telescope that uses a new technique for focusing X-rays with grazing incidence optics. The telescope was built with spherical optics for all of its components, utilizing the high quality surfaces obtainable when polishing spherical (as opposed to aspherical) optics. We tested the prototype X-ray telescope in the 300 meter vacuum pipe at White Sands Missile Range, NM. The telescope features 2 degee graze angles with tungsten coatings, yielding a bandpass of 0.25-1.5 keV with a peak effective area of 0.8 sq cm at 0.83 keV. Results from X-ray testing at energies of 0.25 keV and 0.93 keV (C-K and Cu-L) verify 0.5 arcsecond performance at 0.93 keV. Results from modeling the X-ray telescope's response to the Sun show that the current design would be capable of recording 10 half arcsecond images of a solar active region during a 300 second NASA sounding rocket flight.

  12. Impact of High Power Interference Sources in Planning and Deployment of Wireless Sensor Networks and Devices in the 2.4 GHz Frequency Band in Heterogeneous Environments

    PubMed Central

    Iturri, Peio López; Nazábal, Juan Antonio; Azpilicueta, Leire; Rodriguez, Pablo; Beruete, Miguel; Fernández-Valdivielso, Carlos; Falcone, Francisco

    2012-01-01

    In this work, the impact of radiofrequency radiation leakage from microwave ovens and its effect on 802.15.4 ZigBee-compliant wireless sensor networks operating in the 2.4 GHz Industrial Scientific Medical (ISM) band is analyzed. By means of a novel radioplanning approach, based on electromagnetic field simulation of a microwave oven and determination of equivalent radiation sources applied to an in-house developed 3D ray launching algorithm, estimation of the microwave oven's power leakage is obtained for the complete volume of an indoor scenario. The magnitude and the variable nature of the interference is analyzed and the impact in the radio link quality in operating wireless sensors is estimated and compared with radio channel measurements as well as packet measurements. The measurement results reveal the importance of selecting an adequate 802.15.4 channel, as well as the Wireless Sensor Network deployment strategy within this type of environment, in order to optimize energy consumption and increase the overall network performance. The proposed method enables one to estimate potential interference effects in devices operating within the 2.4 GHz band in the complete scenario, prior to wireless sensor network deployment, which can aid in achieving the most optimal network topology. PMID:23202228

  13. Impact of high power interference sources in planning and deployment of wireless sensor networks and devices in the 2.4 GHz frequency band in heterogeneous environments.

    PubMed

    Iturri, Peio López; Nazábal, Juan Antonio; Azpilicueta, Leire; Rodriguez, Pablo; Beruete, Miguel; Fernández-Valdivielso, Carlos; Falcone, Francisco

    2012-11-12

    In this work, the impact of radiofrequency radiation leakage from microwave ovens and its effect on 802.15.4 ZigBee-compliant wireless sensor networks operating in the 2.4 GHz Industrial Scientific Medical (ISM) band is analyzed. By means of a novel radioplanning approach, based on electromagnetic field simulation of a microwave oven and determination of equivalent radiation sources applied to an in-house developed 3D ray launching algorithm, estimation of the microwave oven’s power leakage is obtained for the complete volume of an indoor scenario. The magnitude and the variable nature of the interference is analyzed and the impact in the radio link quality in operating wireless sensors is estimated and compared with radio channel measurements as well as packet measurements. The measurement results reveal the importance of selecting an adequate 802.15.4 channel, as well as the Wireless Sensor Network deployment strategy within this type of environment, in order to optimize energy consumption and increase the overall network performance. The proposed method enables one to estimate potential interference effects in devices operating within the 2.4 GHz band in the complete scenario, prior to wireless sensor network deployment, which can aid in achieving the most optimal network topology.

  14. X-ray spectroscopy for chemistry in the 2-4 keV energy regime at the XMaS beamline: ionic liquids, Rh and Pd catalysts in gas and liquid environments, and Cl contamination in γ-Al2O3.

    PubMed

    Thompson, Paul B J; Nguyen, Bao N; Nicholls, Rachel; Bourne, Richard A; Brazier, John B; Lovelock, Kevin R J; Brown, Simon D; Wermeille, Didier; Bikondoa, Oier; Lucas, Christopher A; Hase, Thomas P A; Newton, Mark A

    2015-11-01

    The 2-4 keV energy range provides a rich window into many facets of materials science and chemistry. Within this window, P, S, Cl, K and Ca K-edges may be found along with the L-edges of industrially important elements from Y through to Sn. Yet, compared with those that cater for energies above ca. 4-5 keV, there are relatively few resources available for X-ray spectroscopy below these energies. In addition, in situ or operando studies become to varying degrees more challenging than at higher X-ray energies due to restrictions imposed by the lower energies of the X-rays upon the design and construction of appropriate sample environments. The XMaS beamline at the ESRF has recently made efforts to extend its operational energy range to include this softer end of the X-ray spectrum. In this report the resulting performance of this resource for X-ray spectroscopy is detailed with specific attention drawn to: understanding electrostatic and charge transfer effects at the S K-edge in ionic liquids; quantification of dilution limits at the Cl K- and Rh L3-edges and structural equilibria in solution; in vacuum deposition and reduction of [Rh(I)(CO)2Cl]2 to γ-Al2O3; contamination of γ-Al2O3 by Cl and its potential role in determining the chemical character of supported Rh catalysts; and the development of chlorinated Pd catalysts in `green' solvent systems. Sample environments thus far developed are also presented, characterized and their overall performance evaluated.

  15. Effects of Shipboard Compartment Fuel Fire and Fire Extinguishing on RF Signal Propagation in the 2.4 GHz ISM Band

    DTIC Science & Technology

    2000-06-01

    analyzer, were used onboard ex-USS SHADEWELL to measure the attenuation of 2.4 - 2.485 GHz signals transmitted through diesel and heptane fire , water mist...use. Even in normal conditions, without fire , water mist, or steam, we have determined that frequency selective fading would be problem for non

  16. Frequency sharing between passive sensors and aeronautical radionavigation systems employing ground transponders in the band 4.2 - 4.4 GHz

    NASA Technical Reports Server (NTRS)

    Degroot, N. F.

    1982-01-01

    The 4.2 to 4.4 GHz band is reserved for radio altimeters aboard aircraft and for associated transponders on the ground. A radar altimeter system which utilizes associated ground transponders is described and the feasibility of co-channel operation of such a system with a typical passive sensor is analyzed.

  17. Spin-resolved band structure of heterojunction Bi-bilayer/3D topological insulator in the quantum dimension regime in annealed Bi2Te2.4Se0.6

    PubMed Central

    Klimovskikh, I. I.; Sostina, D.; Petukhov, A.; Rybkin, A. G.; Eremeev, S. V.; Chulkov, E. V.; Tereshchenko, O. E.; Kokh, K. A.; Shikin, A. M.

    2017-01-01

    Two- and three-dimensional topological insulators are the key materials for the future nanoelectronic and spintronic devices and quantum computers. By means of angle- and spin-resolved photoemission spectroscopy we study the electronic and spin structure of the Bi-bilayer/3D topological insulator in quantum tunneling regime formed under the short annealing of Bi2Te2.4Se0.6. Owing to the temperature-induced restructuring of the topological insulator’s surface quintuple layers, the hole-like spin-split Bi-bilayer bands and the parabolic electronic-like state are observed instead of the Dirac cone. Scanning Tunneling Microscopy and X-ray Photoemission Spectroscopy measurements reveal the appearance of the Bi2 terraces at the surface under the annealing. The experimental results are supported by density functional theory calculations, predicting the spin-polarized Bi-bilayer bands interacting with the quintuple-layers-derived states. Such an easily formed heterostructure promises exciting applications in spin transport devices and low-energy electronics. PMID:28378826

  18. Theoretical analysis and simulation of the influence of self-bunching effects and longitudinal space charge effects on the propagation of keV electron bunch produced by a novel S-band Micro-Pulse electron Gun

    NASA Astrophysics Data System (ADS)

    Zhao, Jifei; Lu, Xiangyang; Zhou, Kui; Yang, Ziqin; Yang, Deyu; Luo, Xing; Tan, Weiwei; Yang, Yujia

    2016-06-01

    As an important electron source, Micro-Pulse electron Gun (MPG) which is qualified for producing high average current, short pulse, low emittance electron bunches steadily holds promise to use as an electron source of Coherent Smith-Purcell Radiation (CSPR), Free Electron Laser (FEL). The stable output of S-band MPG has been achieved in many labs. To establish reliable foundation for the future application of it, the propagation of picosecond electron bunch produced by MPG should be studied in detail. In this article, the MPG which was working on the rising stage of total effective Secondary Electron Yield (SEY) curve was introduced. The self-bunching mechanism was discussed in depth both in the multipacting amplifying state and the steady working state. The bunch length broadening induced by the longitudinal space-charge (SC) effects was investigated by different theoretical models in different regions. The 2D PIC codes MAGIC and beam dynamic codes TraceWin simulations were also performed in the propagation. The result shows an excellent agreement between the simulation and the theoretical analysis for bunch length evolution.

  19. 2,4-Diaminotoluene

    Integrated Risk Information System (IRIS)

    2,4 - Diaminotoluene ; CASRN 95 - 80 - 7 Human health assessment information on a chemical substance is included in the IRIS database only after a comprehensive review of toxicity data , as outlined in the IRIS assessment development process . Sections I ( Health Hazard Assessments for Noncarcinogen

  20. 2,4-Dinitrophenol

    Integrated Risk Information System (IRIS)

    2,4 - Dinitrophenol ; CASRN 51 - 28 - 5 Human health assessment information on a chemical substance is included in the IRIS database only after a comprehensive review of toxicity data , as outlined in the IRIS assessment development process . Sections I ( Health Hazard Assessments for Noncarcinogeni

  1. 2,4-Dichlorophenol

    Integrated Risk Information System (IRIS)

    2,4 - Dichlorophenol ; CASRN 120 - 83 - 2 Human health assessment information on a chemical substance is included in the IRIS database only after a comprehensive review of toxicity data , as outlined in the IRIS assessment development process . Sections I ( Health Hazard Assessments for Noncarcinoge

  2. 2,4-Dinitrotoluene

    Integrated Risk Information System (IRIS)

    2,4 - Dinitrotoluene ; CASRN 121 - 14 - 2 Human health assessment information on a chemical substance is included in the IRIS database only after a comprehensive review of toxicity data , as outlined in the IRIS assessment development process . Sections I ( Health Hazard Assessments for Noncarcinoge

  3. 2,4-Dimethylphenol

    Integrated Risk Information System (IRIS)

    2,4 - Dimethylphenol ; CASRN 105 - 67 - 9 Human health assessment information on a chemical substance is included in the IRIS database only after a comprehensive review of toxicity data , as outlined in the IRIS assessment development process . Sections I ( Health Hazard Assessments for Noncarcinoge

  4. 2,4-Dichlorophenoxyacetic acid (2,4-D)

    Integrated Risk Information System (IRIS)

    2,4 - Dichlorophenoxyacetic acid ( 2,4 - D ) ; CASRN 94 - 75 - 7 Human health assessment information on a chemical substance is included in the IRIS database only after a comprehensive review of toxicity data , as outlined in the IRIS assessment development process . Sections I ( Health Hazard Asses

  5. ULO_2.4W

    SciTech Connect

    Pitarka, A.

    2012-03-02

    ULO_2.4W is a computer program that can be used to model elastic wave propagation in heterogeneous media from earthquake (souble couple) point sources. The program is a modified version of the orginal program ULO_2.4 developed by Arben Pitarka. The modifications allow for treatment of solid liquid boundary conditions.

  6. Possible contributions of supernova remnants to the soft X-ray diffuse background (0.1 - 1keV)

    NASA Technical Reports Server (NTRS)

    Sanders, W. T.; Burrows, D. N.; Mccammon, D.; Kraushaar, W. L.

    1982-01-01

    Almost all of the B band (0.10-0.19 keV) and C band (0.15-0.28 keV) X-rays probably originate in a hot region surrounding the Sun, which Cox and Anderson modeled as a supernova remnant. This same region may account for a significant fraction of the M band (0.5-1 keV) X-rays if the nonequilibrium models of Cox and Anderson are applicable. A population of distant SNR similar to the local region, with center-to-center spacing of about 300 pc, could provide enough galactic M band emission to fill in the dip in the count rate in the galactic plane that would otherwise be present due to absorption of both the extra galactic power law flux and any large-scale-height stellar (or galactic halo) emission.

  7. Reflectance and transmittance spectra (2.2 2.4 μm) of ion irradiated frozen methanol

    NASA Astrophysics Data System (ADS)

    Brunetto, R.; Baratta, G. A.; Domingo, M.; Strazzulla, G.

    2005-05-01

    We present near-IR (2.2-2.4 μm) reflectance and transmittance spectra of frozen (16 and 77 K) methanol (CH 3OH) and water-methanol (1:1) mixtures before and after irradiation with 30 keV He + and 200 keV H + ions. Spectra of other simple hydrocarbons (CH 4, C 2H 2, C 2H 4, C 2H 6) and CO have also been obtained both to help in the identification of the new molecules formed after ion irradiation of methanol-rich ices, and to get insight into the question of the presence of simple frozen hydrocarbons on the surface of some objects in the outer Solar System. The results confirm what obtained by studies performed in different spectral ranges, namely the ion-induced formation of CO and CH 4, and, for the first time, evidence a strong decrease of the intensity of the methanol band at about 2.34 μm in comparison with that at 2.27 μm. The results are discussed in view of their relevance for icy objects in the Solar System (namely comets, Centaurs, and Kuiper belt objects) where CH 3OH has been observed or suggested to be present.

  8. 2,4,5-Trichlorophenol

    Integrated Risk Information System (IRIS)

    2,4,5 - Trichlorophenol ; CASRN 95 - 95 - 4 Human health assessment information on a chemical substance is included in the IRIS database only after a comprehensive review of toxicity data , as outlined in the IRIS assessment development process . Sections I ( Health Hazard Assessments for Noncarcino

  9. 1,2,4-Tribromobenzene

    Integrated Risk Information System (IRIS)

    1,2,4 - Tribromobenzene ; CASRN 615 - 54 - 3 Human health assessment information on a chemical substance is included in the IRIS database only after a comprehensive review of toxicity data , as outlined in the IRIS assessment development process . Sections I ( Health Hazard Assessments for Noncarcin

  10. 2,2,4-Trimethylpentane

    Integrated Risk Information System (IRIS)

    EPA / 635 / R - 07 / 003 www.epa.gov / iris TOXICOLOGICAL REVIEW OF 2,2,4 - TRIMETHYLPENTANE ( CAS No . 540 - 84 - 1 ) In Support of Summary Information on the Integrated Risk Information System ( IRIS ) July 2007 U.S . Environmental Protection Agency Washington , DC DISCLAIMER This document has bee

  11. 2,4,6-Trichlorophenol

    Integrated Risk Information System (IRIS)

    2,4,6 - Trichlorophenol ; CASRN 88 - 06 - 2 Human health assessment information on a chemical substance is included in the IRIS database only after a comprehensive review of toxicity data , as outlined in the IRIS assessment development process . Sections I ( Health Hazard Assessments for Noncarcino

  12. 1,2,4-Trichlorobenzene

    Integrated Risk Information System (IRIS)

    1,2,4 - Trichlorobenzene ; CASRN 120 - 82 - 1 Human health assessment information on a chemical substance is included in the IRIS database only after a comprehensive review of toxicity data , as outlined in the IRIS assessment development process . Sections I ( Health Hazard Assessments for Noncarci

  13. Hyper-filter-fluorescer spectrometer for x-rays above 120 keV

    DOEpatents

    Wang, Ching L.

    1983-01-01

    An apparatus utilizing filter-fluorescer combinations is provided to measure short bursts of high fluence x-rays above 120 keV energy, where there are no practical absorption edges available for conventional filter-fluorescer techniques. The absorption edge of the prefilter is chosen to be less than that of the fluorescer, i.e., E.sub.PRF E.sub.F. In this way, the response function is virtually zero between E.sub.PRF and E.sub.F and well defined and enhanced in an energy band of less than 1000 keV above the 120 keV energy.

  14. Steady State Sputtering Yields and Surface Compositions of Depleted Uranium and Uranium Carbide bombarded by 30 keV Gallium or 16 keV Cesium Ions.

    SciTech Connect

    Siekhaus, W. J.; Teslich, N. E.; Weber, P. K.

    2014-10-23

    Depleted uranium that included carbide inclusions was sputtered with 30-keV gallium ions or 16-kev cesium ions to depths much greater than the ions’ range, i.e. using steady-state sputtering. The recession of both the uranium’s and uranium carbide’s surfaces and the ion corresponding fluences were used to determine the steady-state target sputtering yields of both uranium and uranium carbide, i.e. 6.3 atoms of uranium and 2.4 units of uranium carbide eroded per gallium ion, and 9.9 uranium atoms and 3.65 units of uranium carbide eroded by cesium ions. The steady state surface composition resulting from the simultaneous gallium or cesium implantation and sputter-erosion of uranium and uranium carbide were calculated to be U₈₆Ga₁₄, (UC)₇₀Ga₃₀ and U₈₁Cs₉, (UC)₇₉Cs₂₁, respectively.

  15. Grazing incidence diffraction of keV helium atoms on a Ag(110) surface.

    PubMed

    Bundaleski, N; Khemliche, H; Soulisse, P; Roncin, P

    2008-10-24

    Diffraction of fast atoms at grazing incidence has been recently demonstrated on the surface of alkali halides and wide band gap semiconductors, opening applications for the online monitoring of surface processes such as growth of ultrathin layers. This Letter reports energy resolved diffraction of helium on Ag(110) metal surface showing that a band gap is not mandatory to restrict the decoherence due to electron-hole pair excitations by the keV projectile. Measurement of the energy loss, which is in the eV range, sheds light on the scattering process.

  16. The Solar Flare 4: 10 keV X-ray Spectrum

    NASA Technical Reports Server (NTRS)

    Phillips, K. J. H.

    2004-01-01

    The 4-10 keV solar flare spectrum includes highly excited lines of stripped Ca, Fe, and Ni ions as well as a continuum steeply falling with energy. Groups of lines at approximately 7 keV and approximately 8 keV, observed during flares by the broad-band RHESSI spectrometer and called here the Fe-line and Fe/Ni-line features, are formed mostly of Fe lines but with Ni lines contributing to the approximately 8 keV feature. Possible temperature indicators of these line features are discussed - the peak or centroid energies of the Fe-line feature, the line ratio of the Fe-line to the Fe/Ni-line features, and the equivalent width of the Fe-line feature. The equivalent width is by far the most sensitive to temperature. However, results will be confused if, as is commonly believed, the abundance of Fe varies from flare to flare, even during the course of a single flare. With temperature determined from the thermal continuum, the Fe-line feature becomes a diagnostic of the Fe abundance in flare plasmas. These results are of interest for other hot plasmas in coronal ionization equilibrium such as stellar flare plasmas, hot gas in galaxies, and older supernova remnants.

  17. The 2-79 keV X-ray spectrum of the Circinus galaxy with NuSTAR, XMM-Newton, and Chandra: a fully Compton-thick active galactic nucleus

    SciTech Connect

    Arévalo, P.; Bauer, F. E.; Puccetti, S.; Walton, D. J.; Fuerst, F.; Grefenstette, B. W.; Harrison, F. A.; Madsen, K. K.; Koss, M.; Boggs, S. E.; Craig, W. W.; Brandt, W. N.; Luo, B.; Brightman, M.; Christensen, F. E.; Comastri, A.; Gandhi, P.; Hailey, C. J.; Madejski, G.; and others

    2014-08-20

    The Circinus galaxy is one of the closest obscured active galactic nuclei (AGNs), making it an ideal target for detailed study. Combining archival Chandra and XMM-Newton data with new NuSTAR observations, we model the 2-79 keV spectrum to constrain the primary AGN continuum and to derive physical parameters for the obscuring material. Chandra's high angular resolution allows a separation of nuclear and off-nuclear galactic emission. In the off-nuclear diffuse emission, we find signatures of strong cold reflection, including high equivalent-width neutral Fe lines. This Compton-scattered off-nuclear emission amounts to 18% of the nuclear flux in the Fe line region, but becomes comparable to the nuclear emission above 30 keV. The new analysis no longer supports a prominent transmitted AGN component in the observed band. We find that the nuclear spectrum is consistent with Compton scattering by an optically thick torus, where the intrinsic spectrum is a power law of photon index Γ = 2.2-2.4, the torus has an equatorial column density of N {sub H} = (6-10) × 10{sup 24} cm{sup –2}, and the intrinsic AGN 2-10 keV luminosity is (2.3-5.1) × 10{sup 42} erg s{sup –1}. These values place Circinus along the same relations as unobscured AGNs in accretion rate versus Γ and L{sub X} versus L {sub IR} phase space. NuSTAR's high sensitivity and low background allow us to study the short timescale variability of Circinus at X-ray energies above 10 keV for the first time. The lack of detected variability favors a Compton-thick absorber, in line with the spectral fitting results.

  18. The 2-79 keV X-Ray Spectrum of the Circinus Galaxy with NuSTAR, XMM-Newton, and Chandra: A Fully Compton-thick Active Galactic Nucleus

    NASA Astrophysics Data System (ADS)

    Arévalo, P.; Bauer, F. E.; Puccetti, S.; Walton, D. J.; Koss, M.; Boggs, S. E.; Brandt, W. N.; Brightman, M.; Christensen, F. E.; Comastri, A.; Craig, W. W.; Fuerst, F.; Gandhi, P.; Grefenstette, B. W.; Hailey, C. J.; Harrison, F. A.; Luo, B.; Madejski, G.; Madsen, K. K.; Marinucci, A.; Matt, G.; Saez, C.; Stern, D.; Stuhlinger, M.; Treister, E.; Urry, C. M.; Zhang, W. W.

    2014-08-01

    The Circinus galaxy is one of the closest obscured active galactic nuclei (AGNs), making it an ideal target for detailed study. Combining archival Chandra and XMM-Newton data with new NuSTAR observations, we model the 2-79 keV spectrum to constrain the primary AGN continuum and to derive physical parameters for the obscuring material. Chandra's high angular resolution allows a separation of nuclear and off-nuclear galactic emission. In the off-nuclear diffuse emission, we find signatures of strong cold reflection, including high equivalent-width neutral Fe lines. This Compton-scattered off-nuclear emission amounts to 18% of the nuclear flux in the Fe line region, but becomes comparable to the nuclear emission above 30 keV. The new analysis no longer supports a prominent transmitted AGN component in the observed band. We find that the nuclear spectrum is consistent with Compton scattering by an optically thick torus, where the intrinsic spectrum is a power law of photon index Γ = 2.2-2.4, the torus has an equatorial column density of N H = (6-10) × 1024 cm-2, and the intrinsic AGN 2-10 keV luminosity is (2.3-5.1) × 1042 erg s-1. These values place Circinus along the same relations as unobscured AGNs in accretion rate versus Γ and LX versus L IR phase space. NuSTAR's high sensitivity and low background allow us to study the short timescale variability of Circinus at X-ray energies above 10 keV for the first time. The lack of detected variability favors a Compton-thick absorber, in line with the spectral fitting results.

  19. Linear attenuation coefficients of tissues from 1 keV to 150 keV

    NASA Astrophysics Data System (ADS)

    Böke, Aysun

    2014-09-01

    The linear attenuation coefficients and three interaction processes have been computed for liver, kidney, muscle, fat and for a range of x-ray energies from 1 keV to 150 keV. Molecular photoelectric absorption cross sections were calculated from atomic cross section data. Total coherent (Rayleigh) and incoherent (Compton) scattering cross sections were obtained by numerical integration over combinations of F2m(x) with the Thomson formula and Sm(x) with the Klein-Nishina formula, respectively. For the coherent (Rayleigh) scattering cross section calculations, molecular form factors were obtained from recent experimental data in the literature for values of x<1 Å-1 and from the relativistic modified atomic form factors for values of x≥1 Å-1. With the inclusion of molecular interference effects in the coherent (Rayleigh) scattering, more accurate knowledge of the scatter from these tissues will be provided. The number of elements involved in tissue composition is 5 for liver, 47 for kidney, 44 for muscle and 3 for fat. The results are compared with previously published experimental and theoretical linear attenuation coefficients. In general, good agreement is obtained. The molecular form factors and scattering functions and cross sections are incorporated into a Monte Carlo program. The energy distributions of x-ray photons scattered from tissues have been simulated and the results are presented.

  20. The Hard X-ray 20-40 keV AGN Luminosity Function

    NASA Technical Reports Server (NTRS)

    Beckmann, V.; Soldi, S.; Shrader, C. R.; Gehrels, N.; Produit, N.

    2006-01-01

    We have compiled a complete, significance limited extragalactic sample based on approximately 25,000 deg(sup 2) to a limiting flux of 3 x 10(exp -11) ergs per square centimeter per second. (approximately 7,000 deg(sup 2)) to a flux limit of 10(exp -11) ergs per square centimeter per second)) in the 20 - 40 keV band with INTEGRAL. We have constructed a detailed exposure map to compensate for effects of non-uniform exposure. The flux-number relation is best described by a power-law with a slope of alpha = 1.66 plus or minus 0.11. The integration of the cumulative flux per unit area leads to f(sub 20-40 keV) = 2.6 x 10(exp -10) ergs per square centimeter per second per sr(sup -1) which is about 1% of the known 20-40 keV X-ray background. We present the first luminosity function of AGN in the 20-40 keV energy range, based on 68 extragalactic objects detected by the imager IBIS/ISGRI on-board INTEGRAL. The luminosity function shows a smoothly connected two power-law form, with an index of gamma (sub 1) = 0.9 below, and gamma (sub 2) = 2.2 above the turn-over luminosity of L(sub *), = 4.6 x 10(sup 43) ergs per second. The emissivity of all INTEGRAL AGNs per unit volume is W(sub 20-40keV)(greater than 10(sup 41) ergs per second) = 2.8 x 10(sup 38) ergs per second h(sup 3)(sub 70) Mpc(sup -3). These results are consistent with those derived in the 2-20keV energy band and do not show a significant contribution by Compton-thick objects. Because the sample used in this study is truly local (z(raised bar) = 0.022)), only limited conclusions can be drawn for the evolution of AGNs in this energy band. But the objects explaining the peak in the cosmic X-ray background are likely to be either low luminosity AGN (L(sub x) less than 10(sup 41) ergs per second) or of other type, such as intermediate mass black holes, clusters, and star forming regions.

  1. 43 CFR 3712.2-4 - Publication.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 43 Public Lands: Interior 2 2012-10-01 2012-10-01 false Publication. 3712.2-4 Section 3712.2-4 Public Lands: Interior Regulations Relating to Public Lands (Continued) BUREAU OF LAND MANAGEMENT... the Act § 3712.2-4 Publication. If the request for publication and the accompanying papers conform...

  2. 43 CFR 3712.2-4 - Publication.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 43 Public Lands: Interior 2 2011-10-01 2011-10-01 false Publication. 3712.2-4 Section 3712.2-4 Public Lands: Interior Regulations Relating to Public Lands (Continued) BUREAU OF LAND MANAGEMENT... the Act § 3712.2-4 Publication. If the request for publication and the accompanying papers conform...

  3. 43 CFR 3712.2-4 - Publication.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 43 Public Lands: Interior 2 2014-10-01 2014-10-01 false Publication. 3712.2-4 Section 3712.2-4 Public Lands: Interior Regulations Relating to Public Lands (Continued) BUREAU OF LAND MANAGEMENT... the Act § 3712.2-4 Publication. If the request for publication and the accompanying papers conform...

  4. 43 CFR 3712.2-4 - Publication.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 43 Public Lands: Interior 2 2013-10-01 2013-10-01 false Publication. 3712.2-4 Section 3712.2-4 Public Lands: Interior Regulations Relating to Public Lands (Continued) BUREAU OF LAND MANAGEMENT... the Act § 3712.2-4 Publication. If the request for publication and the accompanying papers conform...

  5. 45 CFR 1206.2-4 - Procedures.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 45 Public Welfare 4 2011-10-01 2011-10-01 false Procedures. 1206.2-4 Section 1206.2-4 Public Welfare Regulations Relating to Public Welfare (Continued) CORPORATION FOR NATIONAL AND COMMUNITY SERVICE GRANTS AND CONTRACTS-SUSPENSION AND TERMINATION AND DENIAL OF APPLICATION FOR REFUNDING Denial of Application for Refunding § 1206.2-4 Procedures....

  6. 43 CFR 8365.2-4 - Vehicles.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 43 Public Lands: Interior 2 2011-10-01 2011-10-01 false Vehicles. 8365.2-4 Section 8365.2-4 Public... OF THE INTERIOR RECREATION PROGRAMS VISITOR SERVICES Rules of Conduct § 8365.2-4 Vehicles. Unless otherwise authorized, no motor vehicle shall be driven within developed recreation sites or areas except...

  7. 43 CFR 8365.2-4 - Vehicles.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 43 Public Lands: Interior 2 2013-10-01 2013-10-01 false Vehicles. 8365.2-4 Section 8365.2-4 Public... OF THE INTERIOR RECREATION PROGRAMS VISITOR SERVICES Rules of Conduct § 8365.2-4 Vehicles. Unless otherwise authorized, no motor vehicle shall be driven within developed recreation sites or areas except...

  8. 43 CFR 8365.2-4 - Vehicles.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 43 Public Lands: Interior 2 2014-10-01 2014-10-01 false Vehicles. 8365.2-4 Section 8365.2-4 Public... OF THE INTERIOR RECREATION PROGRAMS VISITOR SERVICES Rules of Conduct § 8365.2-4 Vehicles. Unless otherwise authorized, no motor vehicle shall be driven within developed recreation sites or areas except...

  9. 43 CFR 8365.2-4 - Vehicles.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 43 Public Lands: Interior 2 2012-10-01 2012-10-01 false Vehicles. 8365.2-4 Section 8365.2-4 Public... OF THE INTERIOR RECREATION PROGRAMS VISITOR SERVICES Rules of Conduct § 8365.2-4 Vehicles. Unless otherwise authorized, no motor vehicle shall be driven within developed recreation sites or areas except...

  10. Rotational bands in99Sr

    NASA Astrophysics Data System (ADS)

    Pfeiffer, B.; Monnand, E.; Pinston, J. A.; Münzel, J.; Möller, P.; Krumlinde, J.; Ziegert, W.; Kratz, K.-L.

    1984-02-01

    The β-decay of 59 ms99Rb has been studied at OSTIS. As is confirmed by RPA calculations with Nilsson model wave functions, the lowest energy levels in99Sr are consistent with rotational bands built on the [411 3/2], [413 5/2] and [422 3/2] Nilsson neutron configurations at 0, 423 and 1071 keV, respectively. All three bands have similar values of the inertial parameter ħ2/2θ indicating a nearly rigid rotor.

  11. Energy monitoring device for 1.5-2.4 MeV electron beams

    NASA Astrophysics Data System (ADS)

    Fuochi, P. G.; Lavalle, M.; Martelli, A.; Kovács, A.; Mehta, K.; Kuntz, F.; Plumeri, S.

    2010-03-01

    An easy-to-use and robust energy monitoring device has been developed for reliable detection of day-to-day small variations in the electron beam energy, a critical parameter for quality control and quality assurance in industrial radiation processing. It has potential for using on-line, thus providing real-time information. Its working principle is based on the measurement of currents, or charges, collected by two aluminium absorbers of specific thicknesses (dependent on the beam energy), insulated from each other and positioned within a faraday cup-style aluminium cage connected to the ground. The device has been extensively tested in the energy range of 4-12 MeV under standard laboratory conditions at Institute of Isotopes and CNR-ISOF using different types of electron accelerators; namely, a TESLA LPR-4 LINAC (3-6 MeV) and a L-band Vickers LINAC (7-12 MeV), respectively. This device has been also tested in high power electron beam radiation processing facilities, one equipped with a 7-MeV LUE-8 linear accelerator used for crosslinking of cables and medical device sterilization, and the other equipped with a 10 MeV Rhodotron TT100 recirculating accelerator used for in-house sterilization of medical devices. In the present work, we have extended the application of this method to still lower energy region, i.e. from 1.5 to 2.4 MeV. Also, we show that such a device is capable of detecting deviation in the beam energy as small as 40 keV.

  12. Neutron fluence and energy reconstruction with the IRSN recoil detector μ-TPC at 27 keV, 144 keV and 565 keV

    SciTech Connect

    Maire, D.; Lebreton, L.; Richer, J.P.; Bosson, G.; Bourrion, O.; Guillaudin, O.; Riffard, Q.; Santos, D.

    2015-07-01

    The French Institute for Radioprotection and Nuclear Safety (IRSN), associated to the French Metrology Institute (LNE), is developing a time projection chamber using a Micromegas anode: μ-TPC. This work is carried out in collaboration with the Laboratory of Subatomic Physics and Cosmology (LPSC). The aim is to characterize with a primary procedure the energy distribution of neutron fluence in the energy range 8 keV - 1 MeV. The time projection chambers are gaseous detectors, which are able to measure charged particles energy and to reconstruct their track if a pixelated anode is used. In our case, the gas is used as a (n, p) converter in order to detect neutrons down to few keV. Coming from elastic collisions with neutrons, recoil protons lose a part of their kinetic energy by ionizing the gas. The ionization electrons are drifted toward a pixelated anode (2D projection), read at 50 MHz by a self-triggered electronic system to obtain the third track dimension. The neutron energy is reconstructed event by event thanks to proton scattering angle and proton energy measurements. The scattering angle is deduced from the 3D track. The proton energy is obtained by charge collection measurements, knowing the ionization quenching factor (i.e. the part of proton kinetic energy lost by ionizing the gas). The fluence is calculated thanks to the detected events number and the simulated detector response. The μ-TPC is a new reliable detector which enables to measure energy distribution of the neutron fluence without deconvolution or neutron calibration contrary to usual gaseous counters. The μ-TPC is still being developed and measurements have been carried out at the AMANDE facility, with neutrons energies going from 8 keV to 565 keV. After the context and the μ-TPC working principle presentation, measurements of the neutron energy and fluence at 27.2 keV, 144 keV and 565 keV are shown and compared to the complete detector simulation. This work shows the first direct

  13. Implications of the 17 keV neutrino

    SciTech Connect

    Hall, L.J.

    1991-06-01

    Constraints on the theoretical interpretation of the 17 keV neutrino are reviewed. A simple understanding of the 17 keV neutrino is provided by flavon models, which involve the spontaneous breaking of Abelian lepton symmetries and have only the usual three light neutrino species. Signatures for this class of models include neutrino oscillations, tau decay to an electron and a flavon, and invisible decay modes of the Higgs boson to two flavons.

  14. New Observations of Soft X-ray (0.5-5 keV) Solar Spectra

    NASA Astrophysics Data System (ADS)

    Caspi, A.; Woods, T. N.; Mason, J. P.; Jones, A. R.; Warren, H. P.

    2013-12-01

    The solar corona is the brightest source of X-rays in the solar system, and the X-ray emission is highly variable on many time scales. However, the actual solar soft X-ray (SXR) (0.5-5 keV) spectrum is not well known, particularly during solar quiet periods, as, with few exceptions, this energy range has not been systematically studied in many years. Previous observations include high-resolution but very narrow-band spectra from crystal spectrometers (e.g., Yohkoh/BCS), or integrated broadband irradiances from photometers (e.g., GOES/XRS, TIMED/XPS, etc.) that lack detailed spectral information. In recent years, broadband measurements with moderate energy resolution (~0.5-0.7 keV FWHM) were made by SphinX on CORONAS-Photon and SAX on MESSENGER, although they did not extend to energies below ~1 keV. We present observations of solar SXR emission obtained using new instrumentation flown on recent SDO/EVE calibration rocket underflights. The photon-counting spectrometer, a commercial Amptek X123 with a silicon drift detector and an 8 μm Be window, measures the solar disk-integrated SXR emission from ~0.5 to >10 keV with ~0.15 keV FWHM resolution and 1 s cadence. A novel imager, a pinhole X-ray camera using a cooled frame-transfer CCD (15 μm pixel pitch), Ti/Al/C filter, and 5000 line/mm Au transmission grating, images the full Sun in multiple spectral orders from ~0.1 to ~5 nm with ~10 arcsec/pixel and ~0.01 nm/pixel spatial and spectral detector scales, respectively, and 10 s cadence. These instruments are prototypes for future CubeSat missions currently being developed. We present new results of solar observations on 04 October 2013 (NASA sounding rocket 36.290). We compare with previous results from 23 June 2012 (NASA sounding rocket 36.286), during which solar activity was low and no signal was observed above ~4 keV. We compare our spectral and imaging measurements with spectra and broadband irradiances from other instruments, including SDO/EVE, GOES/XRS, TIMED

  15. Bacterial metabolism of 2,4-dichlorophenoxyacetate

    PubMed Central

    Evans, W. C.; Smith, B. S. W.; Fernley, H. N.; Davies, J. I.

    1971-01-01

    1. Two Pseudomonas strains isolated from soil metabolized 2,4-dichlorophenoxyacetate (2,4-D) as sole carbon source in mineral salts liquid medium. 2. 2,4-Dichlorophenoxyacetate cultures of Pseudomonas I (Smith, 1954) contained 2,4-dichlorophenol, 2-chlorophenol, 3,5-dichlorocatechol and α-chloromuconate, the last as a major metabolite. 3. Dechlorination at the 4(p)-position of the aromatic ring must therefore take place at some stages before ring fission. 4. Pseudomonas N.C.I.B. 9340 (Gaunt, 1962) cultures metabolizing 2,4-dichlorophenoxyacetate contained 2,4-dichloro-6-hydroxyphenoxyacetate, 2,4-dichlorophenol, 3,5-dichlorocatechol and an unstable compound, probably αγ-dichloromuconate. 5. Cell-free extracts of the latter organism grown in 2,4-dichlorophenoxyacetate cultures contained an oxygenase that converted 3,5-dichlorocatechol into αγ-dichloromuconate, a chlorolactonase that in the presence of Mn2+ ions converted the dichloromuconate into γ-carboxymethylene-α-chloro-Δαβ-butenolide, and a delactonizing enzyme that gave α-chloromaleylacetate from this lactone. 6. Pathways of metabolism of 2,4-dichlorophenoxyacetate are discussed. PMID:5123888

  16. Study about the coloration of quartz glass induced by proton radiation with 80 keV

    NASA Astrophysics Data System (ADS)

    Wei, Q.; Liu, H.; He, S. Y.

    2004-03-01

    Under the environment of vacuum and heat sink, the change in optical transmittance of JGS3 optical quartz glass induced by radiation of protons with 80 keV was studied. When the radiation fluence exceeded 5 x 10(14) cm(-2) , two absorption bands appeared in the wavelength range of 209 and 220-240 nm and their peaks increased monotonously with the growing radiation fluence. With higher radiation fluence, weaker absorption bands were formed in the near-ultraviolet and visible regions. Color center E' was responsible for the 209 nm absorption peak, while it was disturbed by hydrogen for the 220-240 nm absorption peak. During the radiation, not only breaking of Si-O bonds and the formation of para-magnetism E' but also transition from the [=Si] and [=SiO] radicals into the [=SiH] and [=SiOH] should occur. Thus, a varied color center E' is formed.

  17. Decline of the 2-10 keV Emission from Eta Carinae

    NASA Technical Reports Server (NTRS)

    Liburd, Jamar; Corcoran, Michael F.; Hamaguchi, Kenji; Gull, Theodore R.; Madura, Thomas; Teodoro, Mairan; Moffat, Anthony; Richardson, Noel; Russell, Chris; Pollock, Andrew; Owocki, Stan

    2014-01-01

    Analysis of Eta Car's X-ray spectrum in the 2-10 keV band using processed data from the X-ray Telescope on Swift reveals a peak flux on July 16, 2014 of 0.046 photons s(exp -1) cm(exp -2) (3.37+/-0.15×10(exp -10) ergs s(exp -1) cm(exp -2). This flux is similar to the previous maximum flux seen by the XRT, 3.53+/-0.13×10(exp -10) ergs s(exp -1) cm(exp -2) (0.049 photons s(exp -1) cm(exp -2), ATEL #6298). Since this peak on July 16, the most recent Swift XRT quicklook data show a drop in flux. On July 20, 2014 the XRT flux as seen in the quicklook data was 0.011 photons s(exp -1) cm(exp -2) (8.3+/-0.5×10(exp -11) ergs s(exp -1) cm(exp -2)). This most likely indicates that the 2-10 keV flux is in its declining phase as Eta Car approaches its deep X-ray minimum stage (Hamaguchi et al., 2014, ApJ, 784, 125) associated with periastron passage of the 2024-day binary orbit. The column density derived from analysis of the July 20 XRT quicklook data is 7.2×10(exp 22) cm(exp -2). This is consistent with the column density seen near the same orbital phase in 2003 (7.7×10(exp 22) cm(exp -2), Hamaguchi et al., 2007, ApJ, 663, 522). Eta Car's deep X-ray minimum phase is expected to begin on July 30, 2014. Weekly Swift/XRT observations of Eta Car in the 2-10 keV band are planned throughout the X-ray minimum.

  18. Band structure in 113Sn

    NASA Astrophysics Data System (ADS)

    Banerjee, P.; Ganguly, S.; Pradhan, M. K.; Sharma, H. P.; Muralithar, S.; Singh, R. P.; Bhowmik, R. K.

    2016-07-01

    The structure of collective bands in 113Sn, populated in the reaction 100Mo(19F,p 5 n ) at a beam energy of 105 MeV, has been studied. A new positive-parity sequence of eight states extending up to 7764.9 keV and spin (39 /2+) has been observed. The band is explained as arising from the coupling of the odd valence neutron in the g7 /2 or the d5 /2 orbital to the deformed 2p-2h proton configuration of the neighboring even-A Sn isotope. Lifetimes of six states up to an excitation energy of 9934.9 keV and spin 47 /2-belonging to a Δ I =2 intruder band have been measured for the first time, including an upper limit for the last state, from Doppler-shift-attenuation data. A moderate average quadrupole deformation β2=0.22 ±0.02 is deduced from these results for the five states up to spin 43 /2- . The transition quadrupole moments decrease with increase in rotational frequency, indicating a reduction of collectivity with spin, a feature common for terminating bands. The behavior of the kinematic and dynamic moments of inertia as a function of rotational frequency has been studied and total Routhian surface calculations have been performed in an attempt to obtain an insight into the nature of the states near termination.

  19. ART: Surveying the Local Universe at 2-11 keV

    NASA Astrophysics Data System (ADS)

    O'Dell, Stephen L.; Ramsey, B. D.; Adams, M. L.; Areviev, V.; Brandt, W. N.; Buntov, M.; Elsner, R. F.; Grigorovich, S.; Gubarev, M. V.; Hasinger, G.; Lapshov, I.; Litvin, D.; Meidinger, N.; Pavlinsky, M.; Predehl, P.; Revnivtsev, M.; Romaine, S. E.; Sazonov, S.; Semena, N.; Swartz, D. A.; Tkachenko, A.; Urry, C. M.; Vikhlinin, A.; Weisskopf, M. C.

    2008-03-01

    The Astronomical Röntgen Telescope (ART) is a medium-energy x-ray telescope system proposed for the Russian-led mission Spectrum Röntgen-Gamma (SRG). Optimized for performance over the 2-11-keV band, ART complements the softer response of the SRG prime instrument - the German eROSITA x-ray telescope system. The anticipated number of ART detections is 50,000 - with about 1,000 heavily-obscured (NH > 3×1023 cm-2) active galactic nuclei (AGN) - in the SRG 4-year all-sky survey, plus a comparable number in deeper wide-field (500 deg2 total) surveys. ART's surveys will provide a minimally-biased, nearly-complete census of the local Universe in the medium-energy x-ray band (including Fe-K lines), at CCD spectral resolution. During long (�-ks) pointed observations, ART can obtain statistically significant spectral data up to about 15 keV for bright sources and medium-energy x-ray continuum and Fe-K-line spectra of AGN detected with the contemporaneous NuSTAR hard-x-ray mission.

  20. 14 CFR 2-4 - Accounting period.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 14 Aeronautics and Space 4 2012-01-01 2012-01-01 false Accounting period. Sec. 2-4 Section Sec. 2... Accounting Provisions Sec. 2-4 Accounting period. (a) The accounting year of each air carrier subject to this... settlement with debtors or creditors. (c) Expenditures incurred during the current accounting year...

  1. Mineralization of 2,4-Dichlorophenoxyacetic Acid (2,4-D) and Mixtures of 2,4-D and 2,4,5-Trichlorophenoxyacetic Acid by Phanerochaete chrysosporium

    PubMed Central

    Yadav, J. S.; Reddy, C. A.

    1993-01-01

    Evidence is presented for mineralization of 2,4-dichlorophenoxyacetic acid (2,4-D) in nutrient-rich media (high-nitrogen and malt extract media) by wild-type Phanerochaete chrysosporium and by a peroxidase-negative mutant of this organism. Mass balance analysis of [U-ring-14C]2,4-D mineralization in malt extract cultures showed 82.7% recovery of radioactivity. Of this, 38.6% was released as 14CO2 and 27.0, 11.2, and 5.9% were present in the aqueous, methylene chloride, and mycelial fractions, respectively. 2,4-D and 2,4,5-trichlorophenoxyacetic acid (2,4,5-T) were simultaneously mineralized when presented as a mixture, and mutual inhibition of degradation was not observed. In contrast, a relatively higher rate of mineralization of 2,4-D and 2,4,5-T was observed when these compounds were tested as mixtures than when they were tested alone. PMID:16349039

  2. Development of an immunoassay for determination of 2,4-dichlorophenoxyacetic acid (2,4-D) based upon the recombinant Fab fragment of 2,4-D specific antibody

    NASA Astrophysics Data System (ADS)

    Nguyen, Van C.; Nguyen, Thi D. T.; Dau, Hung A.; Tham, Thu N.; Quyen, Dinh T.; Bachmman, Till; Schmid, Rolf D.

    2001-09-01

    To develop an immunoassay and further an immunosensor for 2,4-D based upon recombinant antibody, the Fab fragments of 2,4-D specific antibody were expressed in E. coli. Western blotting analysis of the periplasmic cell fractions shown that under the non-reducing condition only a single protein band at a molecular mass of 45-kDa, corresponding to the whole Fab fragment was detected. Antigen binding activity for 2,4-D was found only in the extract of cells bearing the 2,4-D plasmid. An immunoassay based on the competitive reaction of 2,4-D and enzyme tracer with 2,4-D Fab fragments immobilized on micro titer plates via rabbit anti-mouse IgC was developed. Using this assay, 2,4-D could be detected at concentration range of 0.5 (mu) g/1 to 10(mu) g/1. The center point of the 2,4-D test was found at a concentration of 5 (mu) g/l. The assay was applied for detection of 2,4-D in spiked orange samples, resulting in recovery rate of 90 percent. The immunoassay could be applied to monitor human exposure to 2,4-D from contamination in fruit samples.

  3. Seeded quantum FEL at 478 keV

    SciTech Connect

    Guenther, M. M.; Jentschel, M.; Thirolf, P. G.; Seggebrock, T.; Habs, D.

    2012-07-09

    We present for the first time the concept of a seeded {gamma} quantum Free-Electron-Laser (QFEL) at 478 keV, which has very different properties compared to a classical. The basic concept is to produce a highly brilliant {gamma} beam via SASE. To produce highly intense and coherent {gamma} beam, we intend to use a seeded FEL scheme. Important for the production of such a {gamma} beam are novel refractive {gamma}-lenses for focusing and an efficient monochromator, allowing to generate a very intense and coherent seed beam. The energy of the {gamma} beam is 478 keV, corresponding to a wavelength in the sub-Angstrom regime (1/38 A). To realize a coherent {gamma} beam at 478 keV, it is necessary to use a quantum FEL design. At such high radiation energies a classical description of the {gamma}-FEL becomes wrong.

  4. Compact, maintainable 80-KeV neutral beam module

    DOEpatents

    Fink, Joel H.; Molvik, Arthur W.

    1980-01-01

    A compact, maintainable 80-keV arc chamber, extractor module for a neutral beam system immersed in a vacuum of <10.sup.-2 Torr, incorporating a nested 60-keV gradient shield located midway between the high voltage ion source and surrounding grounded frame. The shield reduces breakdown or arcing path length without increasing the voltage gradient, tends to keep electric fields normal to conducting surfaces rather than skewed and reduces the peak electric field around irregularities on the 80-keV electrodes. The arc chamber or ion source is mounted separately from the extractor or ion accelerator to reduce misalignment of the accelerator and to permit separate maintenance to be performed on these systems. The separate mounting of the ion source provides for maintaining same without removing the ion accelerator.

  5. Band heterotopia.

    PubMed

    Alam, M S; Naila, N

    2010-01-01

    Band heterotopias are one of the rarest groups of congenital disorder that result in variable degree of structural abnormality of brain parenchyma. Band of heterotopic neurons result from a congenital or acquired deficiency of the neuronal migration. MRI is the examination of choice for demonstrating these abnormalities because of the superb gray vs. white matter differentiation, detail of cortical anatomy and ease of multiplanar imaging. We report a case of band heterotopia that showed a bilateral band of gray matter in deep white matter best demonstrated on T2 Wt. and FLAIR images.

  6. Synthesis and characterization of trans-M2(T(i)PB)2(O2C-CH=CH-2-C4H3S)2 (M = Mo or W) and comments on the metal-to-ligand charge transfer bands in MM quadruply bonded complexes of the type trans-M2(T(i)PB)2L2, where T(i)PB = 2,4,6-triisopropylbenzoate and L = π-accepting carboxylate ligand.

    PubMed

    Alberding, Brian G; Chisholm, Malcolm H; Lear, Benjamin J; Naseri, Vesal; Reed, Carly R

    2011-10-28

    The preparation and characterization of the compounds trans-M(2)(T(i)PB)(2)(O(2)C-CH=CH-2-C(4)H(3)S)(2) where M = Mo or W and T(i)PB = 2,4,6-triisopropylbenzoate are reported. The optical spectra of the new compounds are compared with those of related trans-M(2)(T(i)PB)(2)L(2) compounds where L = O(2)C-C(6)H(4)-4-CN, O(2)C-α,α'-terthienyl (TTh), and O(2)C-4-C(6)H(4)N-B(C(6)F(5))(3), that show strong metal-to-ligand charge transfer bands because of M(2)δ to Lπ conjugation, and are notably temperature dependant due to the various conformations of the two trans-L groups. Upon cooling the spectral features sharpen as the planar geometry that optimizes M(2)δ-Lπ conjugation is favored. As the electronic coupling of the two trans-Lπ systems increases the (0,0) electronic transition gains intensity indicating a greater nesting of the ground state (S(0)) and excited state (S(1)) potential energy surfaces. These features are discussed in terms of the related electronic coupling of [M(2)]-[M(2)] complexes.

  7. The Soft Gamma-Ray Spectrum of A0535+26: Detection of an Absorption Feature at 110 keV by OSSE

    DTIC Science & Technology

    1995-01-01

    At the maximum, the pulsed emission reached 8 Crab ( nebula + pulsar) ux units in the 20{40 keV band (Finger, Wilson, & Hagedon 1994; Wilson et al...observation, the source and background elds were placed to ensure that the Crab Nebula , a potentially contaminating source, did not cause a signi cant

  8. Search for 511 keV emission in satellite galaxies of the Milky Way with INTEGRAL/SPI

    NASA Astrophysics Data System (ADS)

    Siegert, Thomas; Diehl, Roland; Vincent, Aaron C.; Guglielmetti, Fabrizia; Krause, Martin G. H.; Boehm, Celine

    2016-10-01

    Context. The positron (e+) annihilation γ-ray signal in the Milky Way (MW) shows a puzzling morphology: a very bright bulge and a very low surface-brightness disk. A coherent explanation of the e+ origin, propagation through the Galaxy and subsequent annihilation in the interstellar medium has not yet been found. Tentative explanations involve e+s from radioactivity, X-ray binaries, and dark matter (DM). Aims: Dwarf satellite galaxies (DSGs) are believed to be dominated by DM and hence are promising candidates in the search for 511 keV emission as a result of DM annihilation into e+e--pairs. The goal of this study is to constrain possible 511 keV γ-ray signals from 39 DSGs of the MW and to test the annihilating DM scenario. Methods: We used the spectrometer SPI on INTEGRAL to extract individual spectra for the studied objects in the range 490-530 keV. As the diffuse galactic 511 keV emission dominates the overall signal, we modelled the large-scale morphology of the MW accordingly and included this in a maximum likelihood analysis. Alternatively, a distance-weighted stacked spectrum was determined, representing an average DSG seen in 511 keV. Results: Only Reticulum II (Ret II) shows a 3.1σ signal. Five other sources show tentative 2σ signals. The ratio of mass to 511 keV luminosity, Υ511, shows a marginal trend towards higher values for intrinsically brighter objects in contrast to the mass-to-light ratio, ΥV in the V band, which is generally used to uncover DM in DSGs. Conclusions: All derived 511 keV flux values or upper limits are above the flux level implied by a DM interpretation of the MW bulge signal. The signal detected from Ret II is unlikely to be related to a DM origin alone, otherwise, the MW bulge would be ~100 times brighter in 511 keV than what is seen with SPI. Ret II is exceptional considering the DSG sample and rather points to enhanced recent star formation activity if its origins are similar to processes in the MW. Understanding this

  9. KevJumba and the Adolescence of YouTube

    ERIC Educational Resources Information Center

    Saul, Roger

    2010-01-01

    This article considers the significance of YouTube as a pedagogical space from which young people can play participatory roles as theorists in their own constructions as popular cultural subjects. Drawing upon the public profile of "KevJumba," a teenager who makes videos of himself on YouTube, the article suggests that representational practices…

  10. OSSE observations of galactic 511 keV annihilation radiation

    NASA Technical Reports Server (NTRS)

    Purcell, W. R.; Grabelsky, D. A.; Johnson, W. N.; Jung, G. V.; Kinzer, R. L.; Kurfess, J. D.; Strickman, M. S.; Ulmer, M. P.

    1992-01-01

    The Oriented Scintillation Spectrometer Experiment (OSSE) on the Compton Gamma-Ray Observatory has performed several observations of the galactic plane and galactic center region to measure the distribution of galactic 511 keV positron annihilation radiation. Preliminary analysis of data collected during the observation of the galactic center region over the period 13-24 Jun. 1991, indicates the presence of a 511 keV line and positronium continuum superimposed on a power-law continuum. The line of flux was found to be (2.7 +/- 0.5) x 10(exp -4) gamma/sq cm sec, with a positronium fraction of (0.9 +/- 0.2). The 3(sigma) upper limit to daily variations in the 511 keV line flux from the mean during the observation interval is 3 x 10(exp -4) gamma/sq cm sec. If all of the observed annihilation radiation is assumed to originate from the x-ray source 1E 1740.7-2942, the corresponding 511 keV line flux would be (3.0 +/- 0.6) x 10(exp -4) gamma/sq cm sec. The 3(sigma) upper limit for 511 keV line emission from the x-ray binary GX1+4 is 6 x 10(exp -4) gamma/sq cm sec. Results from the galactic plane observations at galactic longitudes of 25 degrees (16-21 Aug. 1991) and 339 degrees (6-11 Sep. 1991) suggest that the emission is concentrated near the galactic center. The observations and the preliminary results are described.

  11. Dose dependence of surface damage profiles for Ge(111) irradiated with 3 keV Ar +

    NASA Astrophysics Data System (ADS)

    Kido, Yoshiaki; Nakano, Hirohiko

    1990-12-01

    The damage profiles of 3 keV Ar + -irradiated Ge(111) were measured by medium energy ion scattering (MEIS) with 220 keV H + beams. A depth resolution of 0.5 nm has been achieved using an electrostatic toroidal analyzer. With doses over 1 × 10 14Ar+/ cm2 at room temperature, an amorphous layer is formed and the amorphous layer thickness is saturated by a dose of 1 × 10 15Ar+/ cm2. The saturated amorphous layer thickness of 12-13 nm obtained is in good agreement with that observed by a cross section transmission electron microscope. The dose dependence of the induced defects derived from MEIS is consistent with that determined by electron channeling pattern analysis. The amorphized damage profiles determined directly by MEIS agree well with those obtained by solving the rate equation using the unsaturated initial defect profile for a dose of 2 × 10 13Ar+/ cm2 and assuming a sputtering rate of 2.4-3.0.

  12. 1,2,4,5-Tetrachlorobenzene

    Integrated Risk Information System (IRIS)

    1,2,4,5 - Tetrachlorobenzene ; CASRN 95 - 94 - 3 Human health assessment information on a chemical substance is included in the IRIS database only after a comprehensive review of toxicity data , as outlined in the IRIS assessment development process . Sections I ( Health Hazard Assessments for Nonca

  13. 2,4,6-Trinitrotoluene (TNT)

    Integrated Risk Information System (IRIS)

    2,4,6 - Trinitrotoluene ( TNT ) ; CASRN 118 - 96 - 7 Human health assessment information on a chemical substance is included in the IRIS database only after a comprehensive review of toxicity data , as outlined in the IRIS assessment development process . Sections I ( Health Hazard Assessments for N

  14. 2,4-/2,6-Dinitrotoluene mixture

    Integrated Risk Information System (IRIS)

    2,4 - / 2,6 - Dinitrotoluene mixture ; no CASRN Human health assessment information on a chemical substance is included in the IRIS database only after a comprehensive review of toxicity data , as outlined in the IRIS assessment development process . Sections I ( Health Hazard Assessments for Noncar

  15. NuSTAR Resolves the First Dual AGN above 10 keV in SWIFT J2028.5+2543

    NASA Astrophysics Data System (ADS)

    Koss, Michael J.; Glidden, Ana; Baloković, Mislav; Stern, Daniel; Lamperti, Isabella; Assef, Roberto; Bauer, Franz; Ballantyne, David; Boggs, Steven E.; Craig, William W.; Farrah, Duncan; Fürst, Felix; Gandhi, Poshak; Gehrels, Neil; Hailey, Charles J.; Harrison, Fiona A.; Markwardt, Craig; Masini, Alberto; Ricci, Claudio; Treister, Ezequiel; Walton, Dominic J.; Zhang, William W.

    2016-06-01

    We have discovered heavy obscuration in the dual active galactic nucleus (AGN) in the Swift/Burst Alert Telescope (BAT) source SWIFT J2028.5+2543 using Nuclear Spectroscopic Telescope Array (NuSTAR). While an early XMM-Newton study suggested the emission was mainly from NGC 6921, the superior spatial resolution of NuSTAR above 10 keV resolves the Swift/BAT emission into two sources associated with the nearby galaxies MCG +04-48-002 and NGC 6921 (z = 0.014) with a projected separation of 25.3 kpc (91″). NuSTAR's sensitivity above 10 keV finds both are heavily obscured to Compton-thick levels (N H ≈ (1-2) × 1024 cm-2) and contribute equally to the BAT detection ({L}10-50 {keV}{{int}} ≈ 6 × 1042 erg s-1). The observed luminosity of both sources is severely diminished in the 2-10 keV band ({L} 2-10 {keV}{{obs}}\\lt 0.1× {L} 2-10 {keV}{{int}}), illustrating the importance of >10 keV surveys like those with NuSTAR and Swift/BAT. Compared to archival X-ray data, MCG +04-48-002 shows significant variability (>3) between observations. Despite being bright X-ray AGNs, they are difficult to detect using optical emission-line diagnostics because MCG +04-48-002 is identified as a starburst/composite because of the high rates of star formation from a luminous infrared galaxy while NGC 6921 is only classified as a LINER using line detection limits. SWIFT J2028.5+2543 is the first dual AGN resolved above 10 keV and is the second most heavily obscured dual AGN discovered to date in the X-rays other than NGC 6240.

  16. A photoluminescence study of CuInSe2 single crystals ion implanted with 5 keV hydrogen

    NASA Astrophysics Data System (ADS)

    Yakushev, M. V.; Krustok, J.; Grossberg, M.; Volkov, V. A.; Mudryi, A. V.; Martin, R. W.

    2016-03-01

    CuInSe2 single crystals ion implanted with 5 keV hydrogen at doses from 3  ×  1014 to 1016 cm-2 are studied by photoluminescence (PL). The PL spectra before and after implantation reveal two bands, a main dominant band centred at 0.96 eV and a lower intensity band centred at 0.93 eV. Detailed analysis of the shape of these bands, their temperature and excitation intensity dependencies allow the recombination mechanisms to be identified as band-to-tail (BT) and band-to-impurity (BI), respectively. The implantation causes gradual red shifts of the bands increasing linearly with the dose. The average depth of potential fluctuations is also estimated to increase with the dose and saturates for doses above 1015 cm-2. A model is proposed which associates the potential fluctuations with the antisite defects copper on indium site and indium on copper site. The saturation is explained by full randomization of copper and indium atoms on the cation sub-lattice.

  17. Spectroscopy from 2 to 200 keV

    NASA Technical Reports Server (NTRS)

    Helfand, D. J.; Chanan, G. A.; Novick, R.; Maccallum, C. J.; Leventhal, M.

    1981-01-01

    The astrophysical processes responsible for line and continuum emission in the spectra range 2 keV to 200 keV are examined from the viewpoint of designing a spectrometer which would operate in this regime. Phenomena considered include fluorescent line radiation in X-ray binaries, magnetically shifted iron lines and cyclotron emission from neutron star surfaces, line emission from cosmically abundant elements in thermal plasmas, and nuclear deexcitation lines in fresh nucleosynthetically produced matter. An instrument consisting of a approximately 10 sq cm array of planar germanium detectors surrounded by a large sodium-iodide anticoincidence shield is described and projected background rates and sensitivities are considered. A sample observing program for a two-day shuttle-based mission is included as an example of the wide range of scientific questions which could be addressed by such an instrument.

  18. Excitation of Banded Whistler Waves in the Magnetosphere

    SciTech Connect

    Gary, S. Peter; Liu, Kaijun; Winske, Dan

    2012-07-13

    Banded whistler waves can be generated by the whistler anisotropy instability driven by two bi-Maxwellian electron components with T{sub {perpendicular}}/T{sub {parallel}} > 1 at different T{sub {parallel}} For typical magnetospheric condition of 1 < {omega}{sub e}/{Omega}{sub e} < 5 in regions associated with strong chorus, upper-band waves can be excited by anisotropic electrons below {approx} 1 keV, while lower-band waves are excited by anisotropic electrons above {approx} 10 keV. Lower-band waves are generally field-aligned and substantially electromagnetic, while upper-band waves propagate obliquely and have quasi-electrostatic fluctuating electric fields. The quasi-electrostatic feature of upper-band waves suggests that they may be more easily identified in electric field observations than in magnetic field observations. Upper-band waves are liable to Landau damping and the saturation level of upperband waves is lower than lower-band waves, consistent with observations that lower-band waves are stronger than upper-band waves on average. The oblique propagation, the lower saturation level, and the more severe Landau damping together would make upper-band waves more tightly confined to the geomagnetic equator (|{lambda}{sub m}| < {approx}10{sup o}) than lower-band waves.

  19. Anisotropy measurements of nearly 50 KeV solar protons

    NASA Technical Reports Server (NTRS)

    Gold, R. E.; Bostrom, C. O.; Roelof, E. C.; Williams, D. J.

    1975-01-01

    The Energetic Particles Experiment on IMP-7 measures the angular distribution of 50-200 keV solar protons in 16 sectors. The velocity of 50 keV protons may be less than 5 times that of the solar wind. A generalized nonlinear Compton-Getting point transformation into the co-moving frame that contains no assumptions as to the angular distribution of either the spectrum or intensity is presented. Nearly 50 keV proton data in the spacecraft frame exhibit an anisotropy ratio that is large (not less than 5) and radial throughout the October 29, 1972 event lasting more than 9 days at this energy. This anisotropy argues against impulsive injection and diffusive decay in the inner solar system. Application of the transformation to the data reveals a long lasting residual anisotropy in the co-moving frame with protons streaming from the sun. Differences between the co-moving frame and solar wind frame velocities suggest residual electric fields upstream from the bow shock.

  20. 4-(2,4-Dichlorophenoxy)butyric acid (2,4-DB)

    Integrated Risk Information System (IRIS)

    4 - ( 2,4 - Dichlorophenoxy ) butyric acid ( 2,4 - DB ) ; CASRN 94 - 82 - 6 Health assessment information on a chemical substance is included in IRIS only after a comprehensive review of chronic toxicity data by U.S . EPA health scientists from several Program Offices and the Office of Research and

  1. 2(2,4,5-Trichlorophenoxy) propionic acid (2,4,5-TP)

    Integrated Risk Information System (IRIS)

    2 ( 2,4,5 - Trichlorophenoxy ) propionic acid ( 2,4,5 - TP ) ; CASRN 93 - 72 - 1 Human health assessment information on a chemical substance is included in the IRIS database only after a comprehensive review of toxicity data , as outlined in the IRIS assessment development process . Sections I ( Hea

  2. 2,4,5-Trichlorophenoxyacetic acid (2,4,5-T)

    Integrated Risk Information System (IRIS)

    2,4,5 - Trichlorophenoxyacetic acid ( 2,4,5 - T ) ; CASRN 93 - 76 - 5 Human health assessment information on a chemical substance is included in the IRIS database only after a comprehensive review of toxicity data , as outlined in the IRIS assessment development process . Sections I ( Health Hazard

  3. Evaluation of the 232Th Neutron Cross Sections between 4 keV and 140 keV

    SciTech Connect

    Volev, K.; Koyumdjieva, N.; Brusegan, A.; Borella, A.; Siegler, P.; Schillebeeckx, P.; Janeva, N.; Lukyanov, A.; Leal, L.

    2005-05-24

    An evaluation of the 232Th neutron total and capture cross sections has been performed in the energy region between 4 keV and 140 keV. The evaluation results from a simultaneous analysis of capture, transmission, and self-indication measurement data, including the most recent capture cross-section data obtained at the GELINA facility of the Institute for Reference Materials and Measurements at Geel (B) and at the n-TOF facility at CERN (CH). The experimental data have been analysed in terms of average resonance parameters exploiting two independent theoretical approaches -- the Characteristic Function model and the Hauser-Feshbach-Moldauer theory. The resulting parameters are consistent with the resolved resonance parameters deduced from the transmission measurements of Olsen et al. at the ORELA facility.

  4. A New Observation of the Quiet Sun Soft X-ray (0.5-5 keV) Spectrum

    NASA Astrophysics Data System (ADS)

    Caspi, A.; Woods, T. N.; Stone, J.

    2012-12-01

    The solar corona is the brightest source of X-rays in the solar system, and the X-ray emission is highly variable with solar activity. While this is particularly true during solar flares, when emission can be enhanced by many orders of magnitude up to gamma-ray energies, even the so-called "quiet Sun" is bright in soft X-rays (SXRs), as the ~1-2 MK ambient plasma of the corona emits significant thermal bremsstrahlung up to ~5 keV. However, the actual solar SXR (0.5-5 keV) spectrum is not well known, particularly during quiet periods, as, with few exceptions, this energy range has not been systematically studied in many years. Previous observations include ultra-high-resolution but very narrow-band spectra from crystral spectrometers (e.g. Yohkoh/BCS), or integrated broadband irradiances from photometers (e.g. GOES/XRS, TIMED/XPS, etc.) that lack detailed spectral information. In recent years, broadband measurements with fair energy resolution (~0.5-0.7 keV FWHM) were made by SphinX on CORONAS-Photon and XRS on MESSENGER, although they did not extend below ~1 keV. We present observations of the quiet Sun SXR emission obtained using a new SXR spectrometer flown on the third SDO/EVE underflight calibration rocket (NASA 36.286). The commercial off-the-shelf Amptek X123 silicon drift detector, with an 8-micron Be window and custom aperture, measured the solar SXR emission from ~0.5 to >10 keV with ~0.15 keV FWHM resolution (though, due to hardware limitations, with only ~0.12 keV binning) and 2-sec cadence over ~5 minutes on 23 June 2012. Despite the rising solar cycle, activity on 23 June 2012 was abnormally low, with no visible active regions and GOES XRS emission near 2010 levels; we measured no solar counts above ~4 keV during the observation period. We compare our X123 measurements with spectra and broadband irradiances from other instruments, including the SphinX observations during the deep solar minimum of 2009, and with upper limits of >3 keV quiet Sun emission

  5. Hydrophobic metabolites of 2,4-dichlorophenoxyacetic acid (2,4-D) in cultured coconut tissue.

    PubMed

    López-Villalobos, Arturo; Hornung, Roland; Dodds, Peter F

    2004-10-01

    Cultures of inflorescence and plumular tissues of coconut palm (Cocos nucifera L.) were maintained in the presence of the auxin, [14C]2,4-dichlorophenoxyacetic acid (2,4-D), so that its metabolic fate could be studied. Thin layer chromatography of methanol extracts of the plumular tissue showed that four classes of metabolites, as well as the unchanged acid, were recovered in the extract. In inflorescence tissue, only the unchanged acid and the most polar class of metabolites (metabolite I) were recovered. Metabolite I was shown to consist mostly of a mixture of sugar conjugates and metabolite II (the next most polar) was an unidentified basic metabolite. Metabolites III and IV were both novel triacylglycerol analogues in which one of the natural fatty acids was replaced with a chain-elongated form of 2,4-D. Reversed-phase thin layer chromatography was used to identify the 2,4-D-derived acids and it was found that metabolite III contained the 2,4-dichlorophenoxy-moiety attached to a chain-length of between 2 and 12 carbons, whereas metabolite IV contained 12, 14 and 16 carbon chain lengths. In inflorescence tissue, and in plumular tissue at low sucrose or 2,4-D concentrations and after short periods in culture, metabolite I predominated. The other metabolites increased as a percentage when plumular culture was prolonged or when sucrose or 2,4-D concentrations were raised. These changes correlated with better development of the explant.

  6. Shock initiation of 2,4-dinitroimidazole (2,4-DNI)

    SciTech Connect

    Urtiew, P.A.; Tarver, C.M.; Simpson, R.L.

    1995-07-19

    The shock sensitivity of the pressed solid explosive 2,4-dinitroimidazole (2,4-DNI) was determined using the embedded manganin pressure gauge technique. At an initial shock pressure of 2 GPa, several microseconds were required before any exothermic reaction was observed. At 4 GPa, 2,4-DNI reacted more rapidly but did not transition to detonation at the 12 mm deep gauge position. At 6 GPa, detonation occurred in less than 6 mm of shock propagation. Thus, 2,4-DNI is more shock sensitive than TATB-based explosives but is considerably less shock sensitive than HMX-based explosives. An Ignition and Growth reactive flow model for 2,4-DNI based on these gauge records showed that 2,4-DNI exhibits shock initiation characteristics similar to TATB but reacts faster. The chemical structure of 2,4-DNI suggests that it may exhibit thermal decomposition reactions similar to nitroguanine and explosives with similar ring structures, such as ANTA and NTO.

  7. NAS Parallel Benchmarks. 2.4

    NASA Technical Reports Server (NTRS)

    VanderWijngaart, Rob; Biegel, Bryan A. (Technical Monitor)

    2002-01-01

    We describe a new problem size, called Class D, for the NAS Parallel Benchmarks (NPB), whose MPI source code implementation is being released as NPB 2.4. A brief rationale is given for how the new class is derived. We also describe the modifications made to the MPI (Message Passing Interface) implementation to allow the new class to be run on systems with 32-bit integers, and with moderate amounts of memory. Finally, we give the verification values for the new problem size.

  8. Astrophysics and cosmology confront the 17 keV neutrino

    NASA Technical Reports Server (NTRS)

    Kolb, Edward W.; Turner, Michael S.

    1991-01-01

    A host of astrophysical and cosmological arguments severely constrain the properties of a 17 keV Dirac neutrino. Such a neutrino must have interactions beyond those of the standard electroweak theory to reduce its cosmic abundance (through decay or annihilation) by a factor of two hundred. A predicament arises because the additional helicity states of the neutrino necessary to construct a Dirac mass must have interactions strong enough to evade the astrophysical bound from SN 1987A, but weak enough to avoid violating the bound from primordial nucleosynthesis.

  9. Proposed FNAL 750 KeV Linac Injector Upgrade

    SciTech Connect

    Tan, C.Y.; Bollinger, D.S.; Schmidt, C.W.; /Fermilab

    2009-04-01

    The present FNAL linac H{sup -} injector has been operational since 1978 and consists of a magnetron H{sup -} source and a 750 keV Cockcroft-Walton Accelerator. The proposed upgrade to this injector is to replace the present magnetron source having a rectangular aperture with a circular aperture, and to replace the Cockcroft-Walton with a 200 MHz RFQ. Operational experience at other laboratories has shown that the upgraded source and RFQ will be more reliable and require less manpower than the present system.

  10. Astrophysics and cosmology confront the 17-keV neutrino

    NASA Technical Reports Server (NTRS)

    Kolb, Edward W.; Turner, Michael S.

    1991-01-01

    A host of astrophysical and cosmological arguments severely constrain the properties of a 17 keV Dirac neutrino. Such a neutrino must have interactions beyond those of the standard electroweak theory to reduce its cosmic abundance (through decay or annihilation) by a factor of two hundred. A predicament arises because the additional helicity states of the neutrino necessary to construct a Dirac mass must have interactions strong enough to evade the astrophysical bound from SN 1987A, but weak enough to avoid violating the bound from primordial nucleosynthesis.

  11. GALAXY CLUSTERS IN THE SWIFT/BAT ERA. II. 10 MORE CLUSTERS DETECTED ABOVE 15 keV

    SciTech Connect

    Ajello, M.; Reimer, O.; Rebusco, P.; Cappelluti, N.; Boehringer, H.; La Parola, V.; Cusumano, G.

    2010-12-20

    We report on the discovery of 10 additional galaxy clusters detected in the ongoing Swift/Burst Alert Telescope (BAT) all-sky survey. Among the newly BAT-discovered clusters there are Bullet, A85, Norma, and PKS 0745-19. Norma is the only cluster, among those presented here, which is resolved by BAT. For all the clusters, we perform a detailed spectral analysis using XMM-Newton and Swift/BAT data to investigate the presence of a hard (non-thermal) X-ray excess. We find that in most cases the clusters' emission in the 0.3-200 keV band can be explained by a multi-temperature thermal model confirming our previous results. For two clusters (Bullet and A3667), we find evidence for the presence of a hard X-ray excess. In the case of the Bullet cluster, our analysis confirms the presence of a non-thermal, power-law-like, component with a 20-100 keV flux of 3.4 x 10{sup -12} erg cm{sup -2} s{sup -1} as detected in previous studies. For A3667, the excess emission can be successfully modeled as a hot component (kT {approx} 13 keV). We thus conclude that the hard X-ray emission from galaxy clusters (except the Bullet) has most likely a thermal origin.

  12. Galaxy Clusters in the Swift/BAT era II: 10 more Clusters detected above 15 keV

    SciTech Connect

    Ajello, M.; Rebusco, P.; Cappelluti, N.; Reimer, O.; Boehringer, H.; La Parola, V.; Cusumano, G.; /Palermo Observ.

    2010-10-27

    We report on the discovery of 10 additional galaxy clusters detected in the ongoing Swift/BAT all-sky survey. Among the newly BAT-discovered clusters there are: Bullet, Abell 85, Norma, and PKS 0745-19. Norma is the only cluster, among those presented here, which is resolved by BAT. For all the clusters we perform a detailed spectral analysis using XMM-Newton and Swift/BAT data to investigate the presence of a hard (non-thermal) X-ray excess. We find that in most cases the clusters emission in the 0.3-200 keV band can be explained by a multi-temperature thermal model confirming our previous results. For two clusters (Bullet and Abell 3667) we find evidence for the presence of a hard X-ray excess. In the case of the Bullet cluster, our analysis confirms the presence of a non-thermal, power-law like, component with a 20-100 keV flux of 3.4 x 10{sup -12} erg cm{sup -2} s{sup -1} as detected in previous studies. For Abell 3667 the excess emission can be successfully modeled as a hot component (kT = {approx}13 keV). We thus conclude that the hard X-ray emission from galaxy clusters (except the Bullet) has most likely thermal origin.

  13. ART: Surveying the Local Universe at 2-11 keV

    NASA Technical Reports Server (NTRS)

    O'Dell, S. L.; Ramsey, B. D.; Adams, M. L.; Brandt, W. N.; Bubarev, M. V.; Hassinger, G.; Pravlinski, M.; Predehl, P.; Romaine, S. E.; Swartz, D. A.; Urry, C. M.; Vikhlinin, A.; Weisskopf, M. C.

    2008-01-01

    The Astronomical Rontgen Telescope (ART) is a medium-energy x-ray telescope system proposed for the Russian-led mission Spectrum Rontgen-Gamma (SRG). Optimized for performance over the 2-11-keV band, ART complements the softer response of the SRG prime instrument-the German eROSITA x-ray telescope system. The anticipated number of ART detections is 50,000-with 1,000 heavily-obscured (N(sub H)> 3x10(exp 23)/sq cm) AGN-in the SRG 4-year all-sky survey, plus a comparable number in deeper wide-field (500 deg(sup 2) total) surveys. ART's surveys will provide a minimally-biased, nearly-complete census of the local Universe in the medium-energy x-ray band (including Fe-K lines), at CCD spectral resolution. During long (approx.100-ks) pointed observations, ART can obtain statistically significant spectral data up to about 15 keY for bright sources and medium-energy x-ray continuum and Fe-K-line spectra of AGN detected with the contemporaneous NuSTAR hard-x-ray mission.

  14. Review of 2,4-dichlorophenoxyacetic acid (2,4-D) biomonitoring and epidemiology

    PubMed Central

    Burns, Carol J.; Swaen, Gerard M. H.

    2012-01-01

    A qualitative review of the epidemiological literature on the herbicide 2,4-dichlorophenoxyacetic acid (2,4-D) and health after 2001 is presented. In order to compare the exposure of the general population, bystanders and occupational groups, their urinary levels were also reviewed. In the general population, 2,4-D exposure is at or near the level of detection (LOD). Among individuals with indirect exposure, i.e. bystanders, the urinary 2,4-D levels were also very low except in individuals with opportunity for direct contact with the herbicide. Occupational exposure, where exposure was highest, was positively correlated with behaviors related to the mixing, loading and applying process and use of personal protection. Information from biomonitoring studies increases our understanding of the validity of the exposure estimates used in epidemiology studies. The 2,4-D epidemiology literature after 2001 is broad and includes studies of cancer, reproductive toxicity, genotoxicity, and neurotoxicity. In general, a few publications have reported statistically significant associations. However, most lack precision and the results are not replicated in other independent studies. In the context of biomonitoring, the epidemiology data give no convincing or consistent evidence for any chronic adverse effect of 2,4-D in humans. PMID:22876750

  15. Observations of the Galactic center 511 keV line

    NASA Technical Reports Server (NTRS)

    Gehrels, Neil

    1991-01-01

    A review of observations of the positron annihilation 511 keV line from the Galactic center and plane is presented. Emphasis is given to the new data from balloon observations in 1988 and 1989. The positron annihilation source in the direction of the center was found to be turned on again in 1988 October after being observed in a quiescent state since the early 1980s. There is evidence for variability between May and October in 1988. The new observations give the first data in which the line is spectrally resolved and in which the Galactic center and plane components of the annihilation radiation are independently measured. These data support the two-component model of the emission with a variable point source near the center and a steady-state source distributed along the galactic plane. Comparing measurements of narrow and wide field instruments in the 1980s gives a flux of about 8 x 10 exp -4 photons/sq cm/s for the point source in its high state and a flux of about 1.2 x 10 exp-3 photons/sq cm/s/rad for the galactic plane component with a relatively flat distribution over the central radian. The line width for the point source component is about 3 keV FWHM.

  16. Laparoscopic gastric banding

    MedlinePlus

    ... adjustable gastric banding; Bariatric surgery - laparoscopic gastric banding; Obesity - gastric banding; Weight loss - gastric banding ... gastric banding is not a "quick fix" for obesity. It will greatly change your lifestyle. You must ...

  17. Radio Frequency Mapping using an Autonomous Robot: Application to the 2.4 GHz Band

    NASA Astrophysics Data System (ADS)

    Lebreton, J. M.; Murad, N. M.; Lorion, R.

    2016-03-01

    Radio signal strength measurement systems are essential to build a Radio Frequency (RF) mapping in indoor and outdoor environments for different application scenarios. This paper presents an autonomous robot making the construction of a radio signal mapping, by collecting and forwarding different useful information related to all access point devices and inherent to the robot towards the base station. A real case scenario is considered by measuring the RF field from our department network. The RF signal mapping consistency is shown by fitting the measurements with the radio signal strength model in two-dimensional area, and a path-loss exponent of 2.3 is estimated for the open corridor environment.

  18. High resolution 17 keV to 75 keV backlighters for High Energy Density experiments

    SciTech Connect

    Park, H; Maddox, B R; Giraldez, E; Hatchett, S P; Hudson, L; Izumi, N; Key, M H; Pape, S L; MacKinnon, A J; MacPhee, A G; Patel, P K; Phillips, T W; Remington, B A; Seely, J F; Tommasini, R; Town, R; Workman, J

    2008-02-25

    We have developed 17 keV to 75 keV 1-dimensional and 2-dimensional high-resolution (< 10 {micro}m) radiography using high-intensity short pulse lasers. High energy K-{alpha} sources are created by fluorescence from hot electrons interacting in the target material after irradiation by lasers with intensity I{sub L} > 10{sup 17} W/cm{sup 2}. We have achieved high resolution point projection 1-dimensional and 2-dimensional radiography using micro-foil and micro-wire targets attached to low-Z substrate materials. The micro-wire size was 10 {micro}m x 10 {micro}m x 300 {micro}m on a 300 {micro}m x 300 {micro}m x 5 {micro}m CH substrate. The radiography performance was demonstrated using the Titan laser at LLNL. We observed that the resolution is dominated by the micro-wire target size and there is very little degradation from the plasma plume, implying that the high energy x-ray photons are generated mostly within the micro-wire volume. We also observe that there are enough K{alpha} photons created with a 300 J, 1-{omega}, 40 ps pulse laser from these small volume targets, and that the signal-to-noise ratio is sufficiently high, for single shot radiography experiments. This unique technique will be used on future high energy density (HED) experiments at the new Omega-EP, ZR and NIF facilities.

  19. Effect of 200 keV Ar{sup +} implantation on optical and electrical properties of polyethyleneterepthalate (PET)

    SciTech Connect

    Kumar, Rajiv Goyal, Meetika Sharma, Ambika; Aggarwal, Sanjeev; Sharma, Annu; Kanjilal, D.

    2015-05-15

    In the present paper we have discussed the effect of 200 keV Ar{sup +} ions on the electrical and optical properties of PET samples. PET samples were implanted with 200 keV Ar{sup +} ions to various doses ranging from 1×10{sup 15} to 1×10{sup 17} Ar{sup +} cm{sup 2}. The changes in the electrical and optical properties of pristine and implanted PET specimens have been studied by using Keithley electrometer and UV-Visible absorption spectroscopy. The electrical conductivity has found to be increased with increasing ion dose. The optical studies have revealed the drastic alterations in optical band gap from 3.63 eV to 1.48 eV and also increase in number of carbon atoms per cluster from 215 to 537. Further, the change in the electrical conductivity and optical band gap has also been correlated with the formation of conductive islands in the implanted layers of PET.

  20. Quantification of Myofascial Taut Bands

    PubMed Central

    Chen, Qingshan; Wang, Hua-jun; Gay, Ralph E.; Thompson, Jeffrey M.; Manduca, Armando; An, Kai-Nan; Ehman, Richard E.; Basford, Jeffrey R.

    2015-01-01

    Objective To assess the correlation of clinician identified myofascial taut bands with their presence and characteristics on Magnetic Resonance Elastography (MRE) imaging. Design Cross-sectional study. Setting An MRI research laboratory. Participants A convenience sample of 65 adults (45 women, 20 men) identified by skilled musculoskeletal physicians as having upper trapezius myofascial pain associated taut bands. Interventions Subjects had their taut bands outlined and were positioned within a 1.5T MRI machine. Shear waves were induced with a pneumatic transducer located over the belly of the involved muscle. Wave propagation was visualized with MRE images across a vibration-cycle. Imaging data was assessed independently by two skilled MRE interpreters. Main Outcome Measures The primary outcome measure was the determination of the intra- and inter-rater reliabilities of MRE taut band identification and their correlation with clinician identification of band presence. Secondary outcomes consisted of the elucidation of the physical characteristics of taut bands and their surrounding muscle tissue. Results MRE intra- and inter-rater reliability was excellent with Kappa's and 95% Confidence intervals (CI) of 0.86, [0.68, 1.00]; and 0.93, [0.79, 1.00], respectively. Stiffness in MRE identified taut bands was elevated at a mean of 11.5 KPa (±2.4 KPa) and fell to a mean of 5.8 KPa (± 0.9 KPa) in surrounding muscle tissue (p<0.001); muscular tone in trapezius muscles without a taut band was relatively uniform at a mean of 6.6 KPa (±2.1 KPa). Agreement between the physicians and the MRE raters, however, was relatively poor (63.1%, 95% CI [50.2%, 74.7%]). Conclusions Our findings suggest that while clinicians may overestimate, and current MRE techniques may underestimate, the presence of taut bands, that these bands exist, can be assessed quantitatively, and do represent localized areas of increased muscle stiffness. PMID:26461163

  1. Magnetospheric plasma modeling (0-100 keV)

    NASA Technical Reports Server (NTRS)

    Garrett, H. B.; Spitale, G. C.

    1985-01-01

    Spacecraft surface charging, which is primarily a current balance phenomenon, is in general a function of the dominant currents to and from the vehicle's surface. Within the near-earth magnetosphere the dominant currents to the surface are the ambient space plasma fluxes between approximately 0 and 100 keV. A major effort to understand the near-earth environment was initiated when spacecraft charging became a major issue. The present paper has the objective to summarize the basic features of the models which have resulted from this effort. A description is given of four categories of models, based primarily on the degree of empirical and theoretical input. Types of quantitative models are discussed, taking into account definitions, statistical models, analytic models, static models, and time-dependent models. Engineering models are also considered, giving attention to baseline models and 'worst-case' models.

  2. Photoelectron spectroscopic study of the negative ions of 4-thiouracil and 2,4-dithiouracil

    NASA Astrophysics Data System (ADS)

    Li, Xiang; Chen, Jing; Bowen, Kit H.

    2011-02-01

    We report the photoelectron spectra of the negative ions of 4-thiouracil (4-TU)- and 2,4-dithiouracil (2,4-DTU)-. Both of these spectra are indicative of valence anions, and they are each dominated by a single broad band with vertical detachment energies of 1.05 and 1.4 eV, respectively. Complementary calculations by Dolgounitcheva, Zakrzewski, and Ortiz (see companion paper) are in accord with our experimental results and conclude that the (4-TU)- and (2,4-DTU)- anions, reported herein, are valence anions of canonical 4-thiouracil and canonical dithiouracil. Comparisons among the anions and corresponding neutrals of 4-thiouracil, 2,4-dithiouracil, 5-chlorouracil, 5-fluorouracil, and uracil itself show that both sulfur and halogen modifications of uracil give rise to significant changes in the electronic structure. The electron affinities of the first four are all substantially larger than that of the canonical uracil.

  3. Broad-Band Spectroscopy of Hercules X-1 with Suzaku

    NASA Technical Reports Server (NTRS)

    Asami, Fumi; Enoto, Teruaki; Iwakiri, Wataru; Yamada, Shin'ya; Tamagawa, Toru; Mihara, Tatehiro; Nagase, Fumiaki

    2014-01-01

    Hercules X-1 was observed with Suzaku in the main-on state from 2005 to 2010. The 0.4- 100 keV wide-band spectra obtained in four observations showed a broad hump around 4-9 keV in addition to narrow Fe lines at 6.4 and 6.7 keV. The hump was seen in all the four observations regardless of the selection of the continuum models. Thus it is considered a stable and intrinsic spectral feature in Her X-1. The broad hump lacked a sharp structure like an absorption edge. Thus it was represented by two different spectral models: an ionized partial covering or an additional broad line at 6.5 keV. The former required a persistently existing ionized absorber, whose origin was unclear. In the latter case, the Gaussian fitting of the 6.5-keV line needs a large width of sigma = 1.0-1.5 keV and a large equivalent width of 400-900 eV. If the broad line originates from Fe fluorescence of accreting matter, its large width may be explained by the Doppler broadening in the accretion flow. However, the large equivalent width may be inconsistent with a simple accretion geometry.

  4. Identification of the Hard X-Ray Source Dominating the E > 25 keV Emission of the Nearby Galaxy M31

    NASA Astrophysics Data System (ADS)

    Yukita, M.; Ptak, A.; Hornschemeier, A. E.; Wik, D.; Maccarone, T. J.; Pottschmidt, K.; Zezas, A.; Antoniou, V.; Ballhausen, R.; Lehmer, B. D.; Lien, A.; Williams, B.; Baganoff, F.; Boyd, P. T.; Enoto, T.; Kennea, J.; Page, K. L.; Choi, Y.

    2017-03-01

    We report the identification of a bright hard X-ray source dominating the M31 bulge above 25 keV from a simultaneous NuSTAR–Swift observation. We find that this source is the counterpart to Swift J0042.6+4112, which was previously detected in the Swift BAT All-sky Hard X-ray Survey. This Swift BAT source had been suggested to be the combined emission from a number of point sources; our new observations have identified a single X-ray source from 0.5 to 50 keV as the counterpart for the first time. In the 0.5–10 keV band, the source had been classified as an X-ray Binary candidate in various Chandra and XMM-Newton studies; however, since it was not clearly associated with Swift J0042.6+4112, the previous E < 10 keV observations did not generate much attention. This source has a spectrum with a soft X-ray excess (kT ∼ 0.2 keV) plus a hard spectrum with a power law of {{Γ }}∼ 1 and a cutoff around 15–20 keV, typical of the spectral characteristics of accreting pulsars. Unfortunately, any potential pulsation was undetected in the NuSTAR data, possibly due to insufficient photon statistics. The existing deep HST images exclude high-mass (>3 {M}ȯ ) donors at the location of this source. The best interpretation for the nature of this source is an X-ray pulsar with an intermediate-mass (<3 {M}ȯ ) companion or a symbiotic X-ray binary. We discuss other possibilities in more detail.

  5. CAPILLARY ELECTROPHORESIS IMMUNOASSAY FOR 2,4-DICHLOROPHENOXYACETIC ACID

    EPA Science Inventory

    A capillary electrophoresis (CE) immunoassay format for 2,4-dichlorophenoxyacetic acid (2,4-D) is demonstrated. A fluorescent labeled 2,4-D analog competes with the analyte of interest for a finite number of binding sites provided by anti-2,4-D monoclonal antibodies. CE then pr...

  6. An X-ray Raman spectrometer for EXAFS studies on minerals: bent Laue spectrometer with 20 keV X-rays.

    PubMed

    Hiraoka, N; Fukui, H; Tanida, H; Toyokawa, H; Cai, Y Q; Tsuei, K D

    2013-03-01

    An X-ray Raman spectrometer for studies of local structures in minerals is discussed. Contrary to widely adopted back-scattering spectrometers using ≤10 keV X-rays, a spectrometer utilizing ~20 keV X-rays and a bent Laue analyzer is proposed. The 20 keV photons penetrate mineral samples much more deeply than 10 keV photons, so that high intensity is obtained owing to an enhancement of the scattering volume. Furthermore, a bent Laue analyzer provides a wide band-pass and a high reflectivity, leading to a much enhanced integrated intensity. A prototype spectrometer has been constructed and performance tests carried out. The oxygen K-edge in SiO(2) glass and crystal (α-quartz) has been measured with energy resolutions of 4 eV (EXAFS mode) and 1.3 eV (XANES mode). Unlike methods previously adopted, it is proposed to determine the pre-edge curve based on a theoretical Compton profile and a Monte Carlo multiple-scattering simulation before extracting EXAFS features. It is shown that the obtained EXAFS features are reproduced fairly well by a cluster model with a minimal set of fitting parameters. The spectrometer and the data processing proposed here are readily applicable to high-pressure studies.

  7. Triaxial Superdeformed Bands in ^163Tm

    NASA Astrophysics Data System (ADS)

    Pattabiraman, N. S.; Ghugre, S. S.; Garg, Umesh; Li, T.; Nayak, B. K.; Zhu, S.; Chakrawarthy, R. S.; Macchiavelli, A. O.; Janssens, R. V. F.

    2002-10-01

    Following the recent discovery of triaxial superdeformation bands in the Z = 71, 72 nuclei [1,2], we have investigated the Z = 69 nucleus ^163 Tm using the reaction ^130 Te( ^37 Cl, 4n) ^163 Tm with a beam energy of 170 MeV. Gamma-ray spectroscopy was performed using the Gammasphere array at LBNL. The data were sorted into a hypercube. The preliminary results have indicated two bands with δ E _γ 60 keV above the previously known 5286 keV, 49/2^- state. These bands appear to talk to one another. It may be recalled that evidence for wobbling motion has recently been reported in the isobaric nucleus ^163 Lu The detailed experimental results and comparisons with the neighboring nuclei will be presented. [1] H. Amro et al, Phys. Lett. B 506, 39(2001). [2] G. Schonwasser eet al., Eur. Phys. J. A13, 291(2002). [3] D. R. Jensen et al, Nucl. Phys. A 703, 3 (2002).

  8. High resolution spectrometer for extended x-ray absorption fine structure measurements in the 6 keV to 15 keV energy range

    NASA Astrophysics Data System (ADS)

    Seely, J. F.; Hudson, L. T.; Henins, Albert; Feldman, U.

    2016-11-01

    A Cauchois transmission-crystal spectrometer has been developed with high crystal resolving power in the 6 keV-15 keV energy range and sufficient sensitivity to record single-shot spectra from the Lawrence Livermore National Laboratory (LLNL) Titan laser and other comparable or more energetic lasers. The spectrometer capabilities were tested by recording the W L transitions from a laboratory source and the extended x-ray absorption fine structure (EXAFS) spectrum through a Cu foil.

  9. STABILITY OF EXTRATERRESTRIAL GLYCINE UNDER ENERGETIC PARTICLE RADIATION ESTIMATED FROM 2 keV ELECTRON BOMBARDMENT EXPERIMENTS

    SciTech Connect

    Maté, B.; Tanarro, I.; Escribano, R.; Moreno, M. A.; Herrero, V. J.

    2015-06-20

    The destruction of solid glycine under irradiation with 2 keV electrons has been investigated by means of IR spectroscopy. Destruction cross sections, radiolysis yields, and half-life doses were determined for samples at 20, 40, 90, and 300 K. The thickness of the irradiated samples was kept below the estimated penetration depth of the electrons. No significant differences were obtained in the experiments below 90 K, but the destruction cross section at 300 K was larger by a factor of 2. The radiolysis yields and half-life doses are in good accordance with recent MeV proton experiments, which confirms that electrons in the keV range can be used to simulate the effects of cosmic rays if the whole sample is effectively irradiated. In the low temperature experiments, electron irradiation leads to the formation of residues. IR absorptions of these residues are assigned to the presence CO{sub 2}, CO, OCN{sup −}, and CN{sup −} and possibly to amide bands I to III. The protection of glycine by water ice is also studied. A water ice film of ∼150 nm is found to provide efficient shielding against the bombardment of 2 keV electrons. The results of this study show also that current Monte Carlo predictions provide a good global description of electron penetration depths. The lifetimes estimated in this work for various environments ranging from the diffuse interstellar medium to the inner solar system, show that the survival of hypothetical primeval glycine from the solar nebula in present solar system bodies is not very likely.

  10. Stability of Extraterrestrial Glycine under Energetic Particle Radiation Estimated from 2 keV Electron Bombardment Experiments

    NASA Astrophysics Data System (ADS)

    Maté, B.; Tanarro, I.; Escribano, R.; Moreno, M. A.; Herrero, V. J.

    2015-06-01

    The destruction of solid glycine under irradiation with 2 keV electrons has been investigated by means of IR spectroscopy. Destruction cross sections, radiolysis yields, and half-life doses were determined for samples at 20, 40, 90, and 300 K. The thickness of the irradiated samples was kept below the estimated penetration depth of the electrons. No significant differences were obtained in the experiments below 90 K, but the destruction cross section at 300 K was larger by a factor of 2. The radiolysis yields and half-life doses are in good accordance with recent MeV proton experiments, which confirms that electrons in the keV range can be used to simulate the effects of cosmic rays if the whole sample is effectively irradiated. In the low temperature experiments, electron irradiation leads to the formation of residues. IR absorptions of these residues are assigned to the presence CO2, CO, OCN-, and CN- and possibly to amide bands I to III. The protection of glycine by water ice is also studied. A water ice film of ˜150 nm is found to provide efficient shielding against the bombardment of 2 keV electrons. The results of this study show also that current Monte Carlo predictions provide a good global description of electron penetration depths. The lifetimes estimated in this work for various environments ranging from the diffuse interstellar medium to the inner solar system, show that the survival of hypothetical primeval glycine from the solar nebula in present solar system bodies is not very likely.

  11. Measurement of the x-ray mass energy-absorption coefficient of air using 3 keV to 10 keV synchrotron radiation.

    PubMed

    Büermann, L; Grosswendt, B; Kramer, H-M; Selbach, H-J; Gerlach, M; Hoffmann, M; Krumrey, M

    2006-10-21

    For the first time absolute photon mass energy-absorption coefficients of air in the energy range 3 keV to 10 keV have been measured with relative standard uncertainties less than 1%, significantly smaller than those of up to 5% assumed hitherto for calculated data. Monochromatized synchrotron radiation was used to measure both the total radiant energy by means of silicon photodiodes calibrated against a cryogenic radiometer and the fraction of radiant energy that is deposited in dry air by means of a free air ionization chamber. The measured ionization charge was converted into energy absorbed in air by calculated effective W values of photons as a function of their energy based on new measurements of the W values in dry air for electron kinetic energies between 1 keV and 7 keV, also presented in this work. The measured absorption coefficients were compared with state-of-the art calculations and found to agree within 0.7% with data calculated earlier by Hubbell at energies above 4 keV but were found to differ by values up to 2.1% at 10 keV from more recent calculations of Seltzer.

  12. Total electron scattering cross sections of molecules containing H, C, N, O and F in the energy range 0.2-6.0 keV

    NASA Astrophysics Data System (ADS)

    Gurung, Meera Devi; Ariyasinghe, W. M.

    2017-03-01

    Based on the effective atomic total electron scattering cross sections (EATCS) of atoms in a molecular environment, a simple model is proposed to predict the total electron scattering cross sections (TCS) of H, C, N, O, and F containing molecules. The EATCS for these five atoms are reported for 0.2-6.0 keV energies. The predicted TCS by this model are compared with experimental TCS in the literature. The experimental TCS of CHF3, C2F4, C2F2H2, C4F6, and c-C4F8 have been obtained for 0.2-4.5 keV electrons by measuring the attenuation of the electron beam through a gas cell.

  13. An Einstein survey of the 1 keV soft X-ray background in the Galactic plane

    NASA Technical Reports Server (NTRS)

    Stanford, John M.; Caillault, Jean-Pierre

    1994-01-01

    We have analyzed 56 Einstein Observatory Imaging Proportional Counter (IPC) observations within +/- 3 deg of the Galactic plane in order to determine the low-latitude soft X-ray background flux in the 0.56-1.73 keV band. Any detected X-ray point source which fell within our regions of study was removed from the image, enabling us to present maps of the background flux as a function of Galactic latitude along 18 meridians. These maps reveal considerable structure to the background in the Galactic plane on an angular scale of approximately 1 deg. Our results are compared with those of an earlier study of the 1 keV X-ray background along l = 25 deg by Kahn & Caillault. The double-peaked structure they found is not discernible in our results, possibly because of the presence of solar backscattered flux in their data. A model which takes into account contributions to the background by extragalactic and stellar sources, the distribution of both atomic and molecular absorbing material with the Galaxy, the energy dependence of the cross section for absorption of X-rays, and the energy dependence of the detector has been constructed and fitted to these new data to derive constraints on the scale height, temperature, and volume emissivity of the unaccounted-for X-ray-emitting material. The results of this model along l = 25 deg are roughly similar to those of the model of Kahn & Caillault along the same meridian.

  14. Sub-second variations of high energy ( 300 keV) hard X-ray emission from solar flares

    NASA Technical Reports Server (NTRS)

    Bai, Taeil

    1986-01-01

    Subsecond variations of hard X-ray emission from solar flares were first observed with a balloon-borne detector. With the launch of the Solar Maximum Mission (SMM), it is now well known that subsecond variations of hard X-ray emission occur quite frequently. Such rapid variations give constraints on the modeling of electron energization. Such rapid variations reported until now, however, were observed at relatively low energies. Fast mode data obtained by the Hard X-ray Burst Spectrometer (HXRBS) has time resolution of approximately 1 ms but has no energy resolution. Therefore, rapid fluctuations observed in the fast-mode HXRBS data are dominated by the low energy hard X-rays. It is of interest to know whether rapid fluctuations are observed in high-energy X-rays. The highest energy band at which subsecond variations were observed is 223 to 1057 keV. Subsecond variations observed with HXRBS at energies greater than 300 keV are reported, and the implications discussed.

  15. 22 CFR 2.4 - Designation of official guests.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 22 Foreign Relations 1 2011-04-01 2011-04-01 false Designation of official guests. 2.4 Section 2.4... PERSONNEL § 2.4 Designation of official guests. The Chief of Protocol shall also maintain a roster of persons designated by the Secretary of State as official guests. Any inquiries by law enforcement...

  16. 22 CFR 2.4 - Designation of official guests.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 22 Foreign Relations 1 2014-04-01 2014-04-01 false Designation of official guests. 2.4 Section 2.4... PERSONNEL § 2.4 Designation of official guests. The Chief of Protocol shall also maintain a roster of persons designated by the Secretary of State as official guests. Any inquiries by law enforcement...

  17. 22 CFR 2.4 - Designation of official guests.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 22 Foreign Relations 1 2012-04-01 2012-04-01 false Designation of official guests. 2.4 Section 2.4... PERSONNEL § 2.4 Designation of official guests. The Chief of Protocol shall also maintain a roster of persons designated by the Secretary of State as official guests. Any inquiries by law enforcement...

  18. 22 CFR 2.4 - Designation of official guests.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 22 Foreign Relations 1 2013-04-01 2013-04-01 false Designation of official guests. 2.4 Section 2.4... PERSONNEL § 2.4 Designation of official guests. The Chief of Protocol shall also maintain a roster of persons designated by the Secretary of State as official guests. Any inquiries by law enforcement...

  19. 22 CFR 2.4 - Designation of official guests.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 22 Foreign Relations 1 2010-04-01 2010-04-01 false Designation of official guests. 2.4 Section 2.4... PERSONNEL § 2.4 Designation of official guests. The Chief of Protocol shall also maintain a roster of persons designated by the Secretary of State as official guests. Any inquiries by law enforcement...

  20. 14 CFR Sec. 2-4 - Accounting period.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 14 Aeronautics and Space 4 2014-01-01 2014-01-01 false Accounting period. Sec. 2-4 Section 2-4... REGULATIONS UNIFORM SYSTEM OF ACCOUNTS AND REPORTS FOR LARGE CERTIFICATED AIR CARRIERS General Accounting Provisions Sec. 2-4 Accounting period. (a) The accounting year of each air carrier subject to this...

  1. 14 CFR Sec. 2-4 - Accounting period.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 14 Aeronautics and Space 4 2013-01-01 2013-01-01 false Accounting period. Sec. 2-4 Section 2-4... REGULATIONS UNIFORM SYSTEM OF ACCOUNTS AND REPORTS FOR LARGE CERTIFICATED AIR CARRIERS General Accounting Provisions Sec. 2-4 Accounting period. (a) The accounting year of each air carrier subject to this...

  2. 14 CFR Sec. 2-4 - Accounting period.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 14 Aeronautics and Space 4 2011-01-01 2011-01-01 false Accounting period. Sec. 2-4 Section 2-4... REGULATIONS UNIFORM SYSTEM OF ACCOUNTS AND REPORTS FOR LARGE CERTIFICATED AIR CARRIERS General Accounting Provisions Sec. 2-4 Accounting period. (a) The accounting year of each air carrier subject to this...

  3. 12 CFR 2.4 - Bonus and incentive plans.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 12 Banks and Banking 1 2011-01-01 2011-01-01 false Bonus and incentive plans. 2.4 Section 2.4 Banks and Banking COMPTROLLER OF THE CURRENCY, DEPARTMENT OF THE TREASURY SALES OF CREDIT LIFE INSURANCE § 2.4 Bonus and incentive plans. A bank employee or officer may participate in a bonus or...

  4. 12 CFR 2.4 - Bonus and incentive plans.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 12 Banks and Banking 1 2013-01-01 2013-01-01 false Bonus and incentive plans. 2.4 Section 2.4 Banks and Banking COMPTROLLER OF THE CURRENCY, DEPARTMENT OF THE TREASURY SALES OF CREDIT LIFE INSURANCE § 2.4 Bonus and incentive plans. A bank employee or officer may participate in a bonus or...

  5. 1 CFR 2.4 - General authority of Director.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 1 General Provisions 1 2011-01-01 2011-01-01 false General authority of Director. 2.4 Section 2.4 General Provisions ADMINISTRATIVE COMMITTEE OF THE FEDERAL REGISTER GENERAL GENERAL INFORMATION § 2.4 General authority of Director. (a) The Director of the Federal Register is delegated authority...

  6. 1 CFR 2.4 - General authority of Director.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 1 General Provisions 1 2010-01-01 2010-01-01 false General authority of Director. 2.4 Section 2.4 General Provisions ADMINISTRATIVE COMMITTEE OF THE FEDERAL REGISTER GENERAL GENERAL INFORMATION § 2.4 General authority of Director. (a) The Director of the Federal Register is delegated authority...

  7. 43 CFR 5511.2-4 - Timber on withdrawn lands.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 43 Public Lands: Interior 2 2011-10-01 2011-10-01 false Timber on withdrawn lands. 5511.2-4 Section 5511.2-4 Public Lands: Interior Regulations Relating to Public Lands (Continued) BUREAU OF LAND... § 5511.2-4 Timber on withdrawn lands. Sections 5511.2-1 to 5511.2-5 are inapplicable to timber...

  8. 17 CFR 4.2-4.4 - [Reserved

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 17 Commodity and Securities Exchanges 1 2010-04-01 2010-04-01 false 4.2-4.4 Section 4.2-4.4 Commodity and Securities Exchanges COMMODITY FUTURES TRADING COMMISSION COMMODITY POOL OPERATORS AND COMMODITY TRADING ADVISORS General Provisions, Definitions and Exemptions §§ 4.2-4.4...

  9. 17 CFR 4.2-4.4 - [Reserved

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 17 Commodity and Securities Exchanges 1 2011-04-01 2011-04-01 false 4.2-4.4 Section 4.2-4.4 Commodity and Securities Exchanges COMMODITY FUTURES TRADING COMMISSION COMMODITY POOL OPERATORS AND COMMODITY TRADING ADVISORS General Provisions, Definitions and Exemptions §§ 4.2-4.4...

  10. 17 CFR 4.2-4.4 - [Reserved

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 17 Commodity and Securities Exchanges 1 2012-04-01 2012-04-01 false 4.2-4.4 Section 4.2-4.4 Commodity and Securities Exchanges COMMODITY FUTURES TRADING COMMISSION COMMODITY POOL OPERATORS AND COMMODITY TRADING ADVISORS General Provisions, Definitions and Exemptions §§ 4.2-4.4...

  11. 17 CFR 4.2-4.4 - [Reserved

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 17 Commodity and Securities Exchanges 1 2014-04-01 2014-04-01 false 4.2-4.4 Section 4.2-4.4 Commodity and Securities Exchanges COMMODITY FUTURES TRADING COMMISSION COMMODITY POOL OPERATORS AND COMMODITY TRADING ADVISORS General Provisions, Definitions and Exemptions §§ 4.2-4.4...

  12. 17 CFR 4.2-4.4 - [Reserved

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 17 Commodity and Securities Exchanges 1 2013-04-01 2013-04-01 false 4.2-4.4 Section 4.2-4.4 Commodity and Securities Exchanges COMMODITY FUTURES TRADING COMMISSION COMMODITY POOL OPERATORS AND COMMODITY TRADING ADVISORS General Provisions, Definitions and Exemptions §§ 4.2-4.4...

  13. 42 CFR 2.4 - Criminal penalty for violation.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 42 Public Health 1 2010-10-01 2010-10-01 false Criminal penalty for violation. 2.4 Section 2.4 Public Health PUBLIC HEALTH SERVICE, DEPARTMENT OF HEALTH AND HUMAN SERVICES GENERAL PROVISIONS CONFIDENTIALITY OF ALCOHOL AND DRUG ABUSE PATIENT RECORDS Introduction § 2.4 Criminal penalty for violation....

  14. 42 CFR 2.4 - Criminal penalty for violation.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 42 Public Health 1 2011-10-01 2011-10-01 false Criminal penalty for violation. 2.4 Section 2.4 Public Health PUBLIC HEALTH SERVICE, DEPARTMENT OF HEALTH AND HUMAN SERVICES GENERAL PROVISIONS CONFIDENTIALITY OF ALCOHOL AND DRUG ABUSE PATIENT RECORDS Introduction § 2.4 Criminal penalty for violation....

  15. BeppoSAX broad-band observations of Gamma Cassiopeiae

    NASA Astrophysics Data System (ADS)

    Owens, A.; Oosterbroek, T.; Parmar, A. N.; Schulz, R.; Stüwe, J. A.; Haberl, F.

    1999-08-01

    We report broad-band X-ray measurements of the Be star gamma Cassiopeiae by the BeppoSAX X-ray astronomy satellite. The observations took place on 1998 July, 18-23. The 0.1-200 keV X-ray spectrum is reasonably well fit by an optically thin thermal plasma model of temperature 12.5+/-0.6 keV with significant residuals around 0.3 keV and 1 keV. The former is interpreted as the variable soft component reported by ROSAT, although there is no evidence for variability at the 5% level. For a blackbody interpretation, the fitted temperature is 100+/- (320) 13 eV, in agreement with the ROSAT value of 200+/- 10 eV. However, a MEKAL interpretation gives a significantly lower temperature of (48+/-11 eV). The fitted abundances are about half solar values, in agreement with previous measurements. At higher energies, the spectrum does not require non-thermal components and the observation of a line at 6.8 keV supports the ASCA interpretation of the source as an accreting white dwarf. Assuming a source distance of 188 pc, the bolometric luminosity in the 2-10 keV band is 6x10(32) ergs s(-1) . Simultaneous optical measurements by the Wendelstein Observatory near Munich, indicate that the source continues to be in a late but rather normal Be phase, with no obvious signs of a transition to the Be-shell phase. The measured magnitudes at B, V and R wavelengths of 2.18+/-0.06, 2.23+/-0.02 and 2.36+/-0.03, respectively, confirm this.

  16. Solid-phase thermal decomposition of 2,4-dinitroimidazole (2,4-DNI)

    SciTech Connect

    Minier, L.; Behrens, R. Jr.; Bulusu, S.

    1996-07-01

    The solid-phase thermal decomposition of the insensitive energetic aromatic heterocycle 2,4-dinitroimidazole (2,4-DNI: mp 265--274 C) is studied utilizing simultaneous thermogravimetric modulated beam mass spectrometry (STMBMS) between 200 and 247 C. The pyrolysis products have been identified using perdeuterated and {sup 15}N-labeled isotopomers. The products consist of low molecular-weight gases and a thermally stable solid residue. The major gaseous products are NO, CO{sub 2}, CO, N{sub 2}, HNCO and H{sub 2}O. Minor gaseous products are HCN, C{sub 2}N{sub 2}, NO{sub 2}, C{sub 3}H{sub 4}N{sub 2}, C{sub 3}H{sub 3}N{sub 3}O and NH{sub 3}. The elemental formula of the residue is C{sub 2}HN{sub 2}O and FTIR analysis suggests that it is polyurea- and polycarbamate-like in nature. The rates of formation of the gaseous products and their respective quantities have been determined for a typical isothermal decomposition experiment at 235 C. The temporal behaviors of the gas formation rates indicate that the overall decomposition is characterized by a sequence of four events: (1) an early decomposition period induced by impurities and H{sub 2}O, (2) an induction period where CO{sub 2} and NO are the primary products formed at relatively constant rates, (3) an autoacceleratory period that peaks when the sample is depleted and (4) a final period in which the residue decomposes. Arrhenius parameters for the induction period are E{sub a} = 46.9 {+-} 0.7 kcal/mol and Log(A) = 16.3 {+-} 0.3. Decomposition pathways that are consistent with the data are presented.

  17. Solid-phase thermal decomposition of 2,4-dinitroimidazole (2,4-DNI)

    SciTech Connect

    Minier, L.; Behrens, R. Jr.; Bulusu, S.

    1996-12-31

    The solid-phase thermal decomposition of the insensitive energetic nitroaromatic heterocycle 2,4-dinitroimidazole (2,4-DNI: mp 265--274C) is studied utilizing simultaneous thermogravimetric modulated beam mass spectrometry (STMBMS) between 200 and 247C. The pyrolysis products have been identified using perdeuterated and {sup 15}N-labeled isotopomers. The products consist of low molecular-weight gases and a thermally stable solid residue. The major gaseous products are NO, CO{sub 2}, CO, N{sub 2}, HNCO and H{sub 2}O. Minor gaseous products are HCN, C{sub 2}N{sub 2}, NO{sub 2}, C{sub 3}H{sub 4}N{sub 2}, C{sub 3}H{sub 3}N{sub 3}O and NH{sub 3}. The elemental formula of the residue is C{sub 2}HN{sub 2}O and FTIR analysis suggests that it is polyurea- and polycarbamate-like in nature. Rates of formation of the gaseous products and their respective quantities have been determined for a typical isothermal decomposition experiment at 235C. The temporal behaviors of the gas formation rates indicate that the overall decomposition is characterized by a sequence of four events; (1) an early decomposition period induced by impurities and water, (2) an induction period where C0{sub 2} and NO are the primary products formed at relatively constant rates, (3) an autoacceleratory period that peaks when the sample is depleted and (4) a final period in which the residue decomposes. Arrhenius parameters for the induction period are E{sub a} = 46.9 {plus_minus} 0.7 kcal/mol and Log(A) = 16.3 {plus_minus} 0.3. Decomposition pathways that are consistent with the data are presented.

  18. Growth and characterization of potassium strontium iodide: A new high light yield scintillator with 2.4% energy resolution

    NASA Astrophysics Data System (ADS)

    Stand, L.; Zhuravleva, M.; Lindsey, A.; Melcher, C. L.

    2015-04-01

    A new ternary metal halide scintillator, potassium strontium iodide, activated with divalent europium (KSr2I5:Eu) has been discovered. This material has a monoclinic crystal structure with a density of 4.39 g/cm3. Differential scanning calorimetry indicates a congruent melting point of 470 °C and suggests that this compound has no solid-solid phase transitions. As is the case with most metal halides, the material is hygroscopic, and it has some internal radioactivity due to the presence of 40K. Single crystals of KSr2I5 doped with 4% Eu2+ were grown in evacuated quartz ampoules via the Bridgman technique. The X-ray excited emission spectrum consisted of a single peak at ~445 nm due to the 5d-4f transition in Eu2+. The measured light yield is ~94,000 photons/MeV with an energy resolution of 2.4% at 662 keV. The crystal has an excellent proportionality response over a wide range of energies from 14 keV to 1275 keV.

  19. Search for a 17 keV neutrino in the internal bremsstrahlung spectrum of 125I

    NASA Astrophysics Data System (ADS)

    Hindi, M. M.; Kozub, R. L.; Robinson, S. J.

    1994-06-01

    We have searched for evidence of the emission of a 17 keV neutrino in the internal bremsstrahlung (IB) spectrum accompanying the electron capture decay of 125I. The IB spectrum, recorded in a planar Ge detector, has 1.2×106 counts per keV at 17 keV below the 2p end point. We set an upper limit of 0.4% for the admixture of a 17 keV neutrino, at the 90% confidence level, and exclude a 0.8% admixture at the 99.6% confidence level. The QEC value is found to be 185.77+/-0.06 keV. We also find that the recent calculations of Surić et al., which employ relativistic self-consistent-field atomic wave functions, reproduce the shape and relative intensity of IB partial spectra within a few percent.

  20. On the source of the 5-55 keV Heliosphere ENAs measured with Cassini/INCA

    NASA Astrophysics Data System (ADS)

    Dialynas, Konstantinos; Roelof, Edmond; Mitchell, Donald; Krimigis, Stamatios; Decker, Robert

    2016-07-01

    The Low Energy Charged Particle (LECP) in situ measurements from V1 and V2 have revealed a reservoir of ions and electrons that constitute the heliosheath (HS) after crossing the termination shock (TS) 35deg north and 32deg south of the ecliptic plane at 94 and 84 astronomical units (1 AU= 1.5 x10 ^{8} km), respectively. The outer Heliosphere boundary, the Heliopause (HP), has now been determined in the direction of V1 to be at ˜122 AU. The in situ measurements by each Voyager were placed in a global context by remote sensing images using ENA obtained with the Ion and Neutral Camera (INCA) onboard Cassini orbiting Saturn. The ENA images have revealed a 5.2-55 keV hydrogen (H) ENA region (Belt) that loops through the celestial sphere and contributes to balancing the pressure of the interstellar magnetic field (ISMF). Here we address one of the remaining and most important questions: Where do the 5-55 keV ENAs that INCA measures come from? We analyzed INCA all-sky maps from 2003 to 2015 and compare the solar cycle (SC) variation of the ENAs in both the nose (upstream) and anti-nose (downstream) directions with the intensities of > 30 keV ions (source of ENA through charge exchange-CE with H) measured in-situ by V1 and V2, in overlapping energy bands ˜30-55 keV. ENA intensities decrease during the declining phase of SC23 by ˜x3 from 2003 to 2011 but recover through 2014 (SC24); similarly, V1 and V2 ion intensities also decrease and then recover through 2014. The similarity of time profiles of remotely sensed ENA and locally measured ions are consistent with (a) ENA originating in the HS, and (b) the global HS responding promptly (within ˜1-1.5 years) to outward-propagating solar wind changes throughout the SC. Further, recovery of the Belt during SC24 precedes asymmetrically from south to north in the general direction of the nose. This may be related to the non-symmetric evolution of solar coronal holes during SC recovery.

  1. Experimental Determination of the HPGe Spectrometer Efficiency Calibration Curves for Various Sample Geometry for Gamma Energy from 50 keV to 2000 keV

    SciTech Connect

    Saat, Ahmad; Hamzah, Zaini; Yusop, Mohammad Fariz; Zainal, Muhd Amiruddin

    2010-07-07

    Detection efficiency of a gamma-ray spectrometry system is dependent upon among others, energy, sample and detector geometry, volume and density of the samples. In the present study the efficiency calibration curves of newly acquired (August 2008) HPGe gamma-ray spectrometry system was carried out for four sample container geometries, namely Marinelli beaker, disc, cylindrical beaker and vial, normally used for activity determination of gamma-ray from environmental samples. Calibration standards were prepared by using known amount of analytical grade uranium trioxide ore, homogenized in plain flour into the respective containers. The ore produces gamma-rays of energy ranging from 53 keV to 1001 keV. Analytical grade potassium chloride were prepared to determine detection efficiency of 1460 keV gamma-ray emitted by potassium isotope K-40. Plots of detection efficiency against gamma-ray energy for the four sample geometries were found to fit smoothly to a general form of {epsilon} = A{Epsilon}{sup a}+B{Epsilon}{sup b}, where {epsilon} is efficiency, {Epsilon} is energy in keV, A, B, a and b are constants that are dependent on the sample geometries. All calibration curves showed the presence of a ''knee'' at about 180 keV. Comparison between the four geometries showed that the efficiency of Marinelli beaker is higher than cylindrical beaker and vial, while cylindrical disk showed the lowest.

  2. The Swift/Fermi GRB 080928 from 1 eV to 150 keV

    NASA Technical Reports Server (NTRS)

    Sonbas, Eda; Rossi, A.; Schulze, S.; Klose, S.; Kann, D. A.; Ferrero, P.; NicuesaGuelbenzu, A.; Rau, A.; Kruehler, T.; Greiner, J.; Schady, P.; Afonso, P. M. J.; Clemens, C.; Filgas, R.; KuepcuYoldas, A.; McBreen, S.; Olivares, F.; Szokoly, G.; Yoldas, A.; Krimm, H. A.; Johannesson, G.; Panaitescu, A.; Yuan, F.; Pandey, S. B.; Akerlof, C. W.

    2010-01-01

    We present the results of a comprehensive study of the Gamma-Ray Burst 080928 and of its afterglow. GRB 08092 was a long burst detected by Swift/BAT and Fermi/GBM, It is one of the exceptional cases where optical emission was already detected when the GRB itself was still radiating in the gamma-ray band. for nearly 100 seconds simultaneous optical X-ray and gamma-ray data provide a coverage of the spectral energy distribution of the transient source from about 1 eV to 150 keV. Here we analyze the prompt emission, constrain its spectral propertIes. and set lower limits on the initial Lorentz factor of the relativistic outflow, In particular. we show that the SED during the main prompt emission phase is in agreement with synchrotron radiation. We construct the optical/near-infrared light curve and the spectral energy distribution based on Swift/UVOT. ROTSE-Illa (Australia) and GROND (La Silla) data and compare it to the X-ray light curve retrieved from the Swift/XRT repository. We show that its bumpy shape can be modeled by multiple energy injections into the forward shock. Furthermore, we provide evidence that the temporal and spectral evolution of the first strong flare seen in the early X-ray light curve can be explained by large-angle emission. Finally, we report on the results of our search for the GRB host galaxy, for which only a deep upper limit can be provided.

  3. MEISENHEIMER COMPLEX BETWEEN 2,4,6-TRINITROTOLUENE AND 3-AMINOPROPYLTRIETHOXYSILANE AND ITS USE FOR A PAPER-BASED SENSOR

    PubMed Central

    Hughes, Shantelle; Dasary, Samuel S. R.; Begum, Salma; Williams, Nya; Yu, Hongtao

    2015-01-01

    2,4,6-Trinitrotoluene (TNT) forms a red-colored Meisenheimer complex with 3-aminopropyltrenthoxysilane (APTES) both in solution and on solid phase. The TNT-APTES complex is unique since it forms yellow-colored complexes with 2,4,6-trinitrophenol and 4-nitrophenol, and no complex with 2,4-dinitrotoluene. The absorption spectrum of TNT-APTES has two absorption bands at 530 and 650 nm, while APTES complexes with 2,4,6-trinitrophenol and 4-nitrophenol have absorption maxima at around 420 nm, and no absorption change for 2,4-dinitrotoluene. The TNT-APTES complex facilitates the exchange of the TNT-CH3 proton/deuteron with solvent molecules. The red color of TNT-APTES is immediately visible at 1 µM of TNT. PMID:26380171

  4. Killing Weeds with 2,4-D. Extension Bulletin 389.

    ERIC Educational Resources Information Center

    Lee, Oliver C.

    Discussed is the use of the herbicide 2,4-D. Though written for farmers and agricultural workers, the pamphlet considers turf weed control and use of 2,4-D near ornamental plants. Aspects of the use of this herbicide covered are: (1) the common forms of 2,4-D; (2) plant responses and tolerances to the herbicide; (3) dilution and concentration of…

  5. Extension of the yrast band in 74Se

    NASA Astrophysics Data System (ADS)

    Gross, C. J.; Cottle, P. D.; Headly, D. M.; Hüttmeier, U. J.; Moore, E. F.; Tabor, S. L.

    1987-11-01

    New states in the yrast band of 74Se have been seen with the reaction 52Cr(28Si,α2p)74Se at 98 MeV. The new states extend the known level scheme up to Jπ=(22+). For the states Jπ>=6+ the spectrum shows a relatively constant moment of inertia parameter ħ2/2θ=27.8+/-0.5 keV.

  6. Measurement of the mass attenuation coefficient from 81 keV to 1333 keV for elemental materials Al, Cu and Pb

    NASA Astrophysics Data System (ADS)

    Gjorgieva, Slavica; Barandovski, Lambe

    2016-03-01

    The mass attenuation coefficients (μ/ρ) for 3 high purity elemental materials Al, Cu and Pb were measured in the γ-ray energy range from 81 keV up to 1333 keV using 22Na, 60Co 133Ba and 133Cs as sources of gamma radiation. Well shielded detector (NaI (Tl) semiconductor detector) was used to measure the intensity of the transmitted beam. The measurements were made under condition of good geometry, assuring that any photon absorbed or deflected appreciably does not reach the detector. The measured values are compared with the theoretical ones obtained by Seltzer (1993).

  7. ISM band to U-NII band frequency transverter and method of frequency transversion

    DOEpatents

    Stepp, Jeffrey David; Hensley, Dale

    2006-09-12

    A frequency transverter (10) and method for enabling bi-frequency dual-directional transfer of digitally encoded data on an RF carrier by translating between a crowded or otherwise undesirable first frequency band, such as the 2.4 GHz ISM band, and a less-crowded or otherwise desirable second frequency band, such as the 5.0 GHz 6.0 GHz U-NII band. In a preferred embodiment, the transverter (10) connects between an existing data radio (11) and its existing antenna (30), and comprises a bandswitch (12); an input RF isolating device (14); a transmuter (16); a converter (18); a dual output local oscillator (20); an output RF isolating device (22); and an antenna (24) tuned to the second frequency band. The bandswitch (12) allows for bypassing the transverter (10), thereby facilitating its use with legacy systems. The transmuter (14) and converter (16) are adapted to convert to and from, respectively, the second frequency band.

  8. ISM band to U-NII band frequency transverter and method of frequency transversion

    DOEpatents

    Stepp, Jeffrey David; Hensley, Dale

    2006-04-04

    A frequency transverter (10) and method for enabling bi-frequency dual-directional transfer of digitally encoded data on an RF carrier by translating between a crowded or otherwise undesirable first frequency band, such as the 2.4 GHz ISM band, and a less-crowded or otherwise desirable second frequency band, such as the 5.0 GHz-6.0 GHz U-NII band. In a preferred embodiment, the transverter (10) connects between an existing data radio (11) and its existing antenna (30), and comprises a bandswitch (12); an input RF isolating device (14); a transmuter (16); a converter (18); a dual output local oscillator (20); an output RF isolating device (22); and an antenna (24) tuned to the second frequency band. The bandswitch (12) allows for bypassing the transverter (10), thereby facilitating its use with legacy systems. The transmuter (14) and converter (16) are adapted to convert to and from, respectively, the second frequency band.

  9. Ionised outflows in z ~ 2.4 quasar host galaxies

    NASA Astrophysics Data System (ADS)

    Carniani, S.; Marconi, A.; Maiolino, R.; Balmaverde, B.; Brusa, M.; Cano-Díaz, M.; Cicone, C.; Comastri, A.; Cresci, G.; Fiore, F.; Feruglio, C.; La Franca, F.; Mainieri, V.; Mannucci, F.; Nagao, T.; Netzer, H.; Piconcelli, E.; Risaliti, G.; Schneider, R.; Shemmer, O.

    2015-08-01

    Aims: Outflows driven by active galactic nuclei (AGN) are invoked by galaxy evolutionary models to quench star formation and to explain the origin of the relations observed locally between super-massive black holes and their host galaxies. We here aim to detect extended ionised outflows in luminous quasars, where we expect the highest activity both in star formation and in black-hole accretion. Currently, there are only a few studies based on spatially resolved observations of outflows at high redshift, z > 2. Methods: We analysed a sample of six luminous (L > 1047 erg/s) quasars at z ~ 2.4, observed in H-band using the near-IR integral field spectrometer SINFONI at the VLT. We performed a kinematic analysis of the [Oiii] emission line at λ = 5007 Å. Results: We detect fast, spatially extended outflows in five out of six targets. [Oiii]λ5007 has a complex gas kinematic, with blue-shifted velocities of a few hundreds of km s-1 and line widths up to 1500 km s-1. Using the spectroastrometric method, we infer a size of the ionised outflows of up to ~2 kpc. The properties of the ionised outflows, mass outflow rate, momentum rate, and kinetic power, are correlated with the AGN luminosity. The increase in outflow rate with increasing AGN luminosity is consistent with the idea that a luminous AGN pushes away the surrounding gas through fast outflows that are driven by radiation pressure, which depends on the emitted luminosity. Conclusions: We derive mass outflow rates of about 6-700 M⊙ yr-1 for our sample, which are lower than those observed in molecular outflows. The physical properties of ionised outflows show dependences on AGN luminosity that are similar to those of molecular outflows, but indicate that the mass of ionised gas is lower than that of molecular outflows. Alternatively, this discrepancy between ionised and molecular outflows could be explained with different acceleration mechanisms. Based on Observations collected at the European Organisation for

  10. Come Join the Band

    ERIC Educational Resources Information Center

    Olson, Cathy Applefeld

    2011-01-01

    A growing number of students in Blue Springs, Missouri, are joining the band, drawn by a band director who emphasizes caring and inclusiveness. In the four years since Melissia Goff arrived at Blue Springs High School, the school's extensive band program has swelled. The marching band alone has gone from 100 to 185 participants. Also under Goff's…

  11. Elimination of 2,4,5,2',4',5'-hexachlorobiphenyl by the purple sea urchin, Strongylocentrotus purpuratus, following single exposure

    SciTech Connect

    Tjeerdema, R.S.; Jacobs, R.S.

    1987-06-01

    Understanding the fate of a single PCB isomer in a resident species may aid in assessing the risk to the marine community. Therefore, the elimination of 2,4,5,2',4',5'-hexachlorobiphenyl (HCBP) by the purple sea urchin, Strongylocentrotus purpuratus, following a single exposure, was investigated. The purple sea urchin was chosen because of its economic importance and ability to proliferate in certain polluted conditions. Single exposure may best mimic the effects of intermittent oceanic incineration or disposal, and 2,4,5,2',4',5'-HCBP was chosen due to its presence in common PCB mixtures and high chlorine content, thus strong lipophilicity.

  12. 43 CFR 2920.2-4 - Proposal content.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 43 Public Lands: Interior 2 2014-10-01 2014-10-01 false Proposal content. 2920.2-4 Section 2920.2-4 Public Lands: Interior Regulations Relating to Public Lands (Continued) BUREAU OF LAND MANAGEMENT, DEPARTMENT OF THE INTERIOR LAND RESOURCE MANAGEMENT (2000) LEASES, PERMITS AND EASEMENTS Leases, Permits and Easements: General Provisions §...

  13. 43 CFR 2920.2-4 - Proposal content.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 43 Public Lands: Interior 2 2012-10-01 2012-10-01 false Proposal content. 2920.2-4 Section 2920.2-4 Public Lands: Interior Regulations Relating to Public Lands (Continued) BUREAU OF LAND MANAGEMENT, DEPARTMENT OF THE INTERIOR LAND RESOURCE MANAGEMENT (2000) LEASES, PERMITS AND EASEMENTS Leases, Permits and Easements: General Provisions §...

  14. 43 CFR 2920.2-4 - Proposal content.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 43 Public Lands: Interior 2 2011-10-01 2011-10-01 false Proposal content. 2920.2-4 Section 2920.2-4 Public Lands: Interior Regulations Relating to Public Lands (Continued) BUREAU OF LAND MANAGEMENT, DEPARTMENT OF THE INTERIOR LAND RESOURCE MANAGEMENT (2000) LEASES, PERMITS AND EASEMENTS Leases, Permits and Easements: General Provisions §...

  15. 43 CFR 2920.2-4 - Proposal content.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 43 Public Lands: Interior 2 2013-10-01 2013-10-01 false Proposal content. 2920.2-4 Section 2920.2-4 Public Lands: Interior Regulations Relating to Public Lands (Continued) BUREAU OF LAND MANAGEMENT, DEPARTMENT OF THE INTERIOR LAND RESOURCE MANAGEMENT (2000) LEASES, PERMITS AND EASEMENTS Leases, Permits and Easements: General Provisions §...

  16. 18 CFR 2.4 - Suspension of rate schedules.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 18 Conservation of Power and Water Resources 1 2012-04-01 2012-04-01 false Suspension of rate schedules. 2.4 Section 2.4 Conservation of Power and Water Resources FEDERAL ENERGY REGULATORY COMMISSION... and should not be changed during suspension. (f) Changes under escalator clauses may be suspended...

  17. 18 CFR 2.4 - Suspension of rate schedules.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 18 Conservation of Power and Water Resources 1 2010-04-01 2010-04-01 false Suspension of rate schedules. 2.4 Section 2.4 Conservation of Power and Water Resources FEDERAL ENERGY REGULATORY COMMISSION... and should not be changed during suspension. (f) Changes under escalator clauses may be suspended...

  18. 18 CFR 2.4 - Suspension of rate schedules.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 18 Conservation of Power and Water Resources 1 2013-04-01 2013-04-01 false Suspension of rate schedules. 2.4 Section 2.4 Conservation of Power and Water Resources FEDERAL ENERGY REGULATORY COMMISSION... and should not be changed during suspension. (f) Changes under escalator clauses may be suspended...

  19. 36 CFR 2.4 - Weapons, traps and nets.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 36 Parks, Forests, and Public Property 1 2011-07-01 2011-07-01 false Weapons, traps and nets. 2.4... PROTECTION, PUBLIC USE AND RECREATION § 2.4 Weapons, traps and nets. (a)(1) Except as otherwise provided in... prohibited: (i) Possessing a weapon, trap or net (ii) Carrying a weapon, trap or net (iii) Using a...

  20. 36 CFR 2.4 - Weapons, traps and nets.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 36 Parks, Forests, and Public Property 1 2012-07-01 2012-07-01 false Weapons, traps and nets. 2.4... PROTECTION, PUBLIC USE AND RECREATION § 2.4 Weapons, traps and nets. (a)(1) Except as otherwise provided in... prohibited: (i) Possessing a weapon, trap or net (ii) Carrying a weapon, trap or net (iii) Using a...

  1. 36 CFR 2.4 - Weapons, traps and nets.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 36 Parks, Forests, and Public Property 1 2014-07-01 2014-07-01 false Weapons, traps and nets. 2.4... PROTECTION, PUBLIC USE AND RECREATION § 2.4 Weapons, traps and nets. (a)(1) Except as otherwise provided in... prohibited: (i) Possessing a weapon, trap or net (ii) Carrying a weapon, trap or net (iii) Using a...

  2. 36 CFR 2.4 - Weapons, traps and nets.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 36 Parks, Forests, and Public Property 1 2013-07-01 2013-07-01 false Weapons, traps and nets. 2.4... PROTECTION, PUBLIC USE AND RECREATION § 2.4 Weapons, traps and nets. (a)(1) Except as otherwise provided in... prohibited: (i) Possessing a weapon, trap or net (ii) Carrying a weapon, trap or net (iii) Using a...

  3. 36 CFR 2.4 - Weapons, traps and nets.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 36 Parks, Forests, and Public Property 1 2010-07-01 2010-07-01 false Weapons, traps and nets. 2.4... PROTECTION, PUBLIC USE AND RECREATION § 2.4 Weapons, traps and nets. (a)(1) Except as otherwise provided in... prohibited: (i) Possessing a weapon, trap or net (ii) Carrying a weapon, trap or net (iii) Using a...

  4. 43 CFR 3811.2-4 - Lands in national forests.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 43 Public Lands: Interior 2 2014-10-01 2014-10-01 false Lands in national forests. 3811.2-4... Lands Subject to Location and Purchase § 3811.2-4 Lands in national forests. For mining claims in national forests, see § 3811.1....

  5. 43 CFR 3811.2-4 - Lands in national forests.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 43 Public Lands: Interior 2 2012-10-01 2012-10-01 false Lands in national forests. 3811.2-4... Lands Subject to Location and Purchase § 3811.2-4 Lands in national forests. For mining claims in national forests, see § 3811.1....

  6. 43 CFR 3811.2-4 - Lands in national forests.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 43 Public Lands: Interior 2 2013-10-01 2013-10-01 false Lands in national forests. 3811.2-4... Lands Subject to Location and Purchase § 3811.2-4 Lands in national forests. For mining claims in national forests, see § 3811.1....

  7. 43 CFR 3811.2-4 - Lands in national forests.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 43 Public Lands: Interior 2 2011-10-01 2011-10-01 false Lands in national forests. 3811.2-4 Section 3811.2-4 Public Lands: Interior Regulations Relating to Public Lands (Continued) BUREAU OF LAND MANAGEMENT, DEPARTMENT OF THE INTERIOR MINERALS MANAGEMENT (3000) LANDS AND MINERALS SUBJECT TO...

  8. 14 CFR Sec. 2-4 - Accounting period.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... REGULATIONS UNIFORM SYSTEM OF ACCOUNTS AND REPORTS FOR LARGE CERTIFICATED AIR CARRIERS General Accounting Provisions Sec. 2-4 Accounting period. (a) The accounting year of each air carrier subject to this Uniform... 14 Aeronautics and Space 4 2010-01-01 2010-01-01 false Accounting period. Sec. 2-4 Section...

  9. 47 CFR 25.213 - Inter-Service coordination requirements for the 1.6/2.4 GHz Mobile-Satellite Service.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... radio astronomy service in the 1610.6-1613.8 MHz band against interference from 1.6/2.4 GHz Mobile... System. (i) In the band 1610.6-1613.8 MHz, within a 160 km radius of the following radio astronomy sites... attenuated so that the power flux density it produces in the 1610.6-1613.8 MHz band at any radio...

  10. 47 CFR 25.213 - Inter-Service coordination requirements for the 1.6/2.4 GHz Mobile-Satellite Service.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... radio astronomy service in the 1610.6-1613.8 MHz band against interference from 1.6/2.4 GHz Mobile... System. (i) In the band 1610.6-1613.8 MHz, within a 160 km radius of the following radio astronomy sites... attenuated so that the power flux density it produces in the 1610.6-1613.8 MHz band at any radio...

  11. Characteristic 8 keV X rays possess radiobiological properties of higher-LET radiation.

    PubMed

    Shridhar, Ravi; Estabrook, William; Yudelev, Mark; Rakowski, Joseph; Burmeister, Jay; Wilson, George D; Joiner, Michael C

    2010-03-01

    Electronic brachytherapy systems are being developed that can deliver X rays of varying energy depending on the material of a secondary target. A copper target produces characteristic 8 keV X rays. Our aim was to determine whether 8 keV X rays might deliver greater biological effectiveness than megavoltage photons. Cells of the U251 human glioma cell line were used to compare the biological effects of 8 keV X rays and (60)Co gamma rays in terms of relative biological effectiveness (RBE), oxygen enhancement ratio (OER), and DNA damage. The RBE at 50% and 10% survival was 2.6 and 1.9, respectively. At 50% survival, the OER for cells treated with 8 keV X rays was 1.6 compared with 3.0 for (60)Co gamma rays. The numbers of H2AX foci per Gy after treatment with 8 keV X rays and (60)Co gamma rays were similar; however, the size of the foci generated at 8 keV was significantly larger, possibly indicating more complex DNA damage. The mean area of H2AX foci generated by 8 keV X rays was 0.785 microm(2) (95% CI: 0.756-0.814) compared with 0.491 microm(2) (95% CI: 0.462-0.520) for (60)Co gamma rays (P < 0.0001). Characteristic 8 keV X rays produce two to three times the biological effectiveness of megavoltage photons, with a radiobiological profile similar to higher-LET radiations.

  12. Biomarker correlations of urinary 2,4-D levels in foresters: genomic instability and endocrine disruption.

    PubMed Central

    Garry, V F; Tarone, R E; Kirsch, I R; Abdallah, J M; Lombardi, D P; Long, L K; Burroughs, B L; Barr, D B; Kesner, J S

    2001-01-01

    Forest pesticide applicators constitute a unique pesticide use group. Aerial, mechanical-ground, and focal weed control by application of herbicides, in particular chlorophenoxy herbicides, yield diverse exposure scenarios. In the present work, we analyzed aberrations in G-banded chromosomes, reproductive hormone levels, and polymerase chain reaction-based V(D)J rearrangement frequencies in applicators whose exposures were mostly limited to chlorophenoxy herbicides. Data from appliers where chlorophenoxy use was less frequent were also examined. The biomarker outcome data were compared to urinary levels of 2,4-dichlorophenoxyacetic acid (2,4-D) obtained at the time of maximum 2,4-D use. Further comparisons of outcome data were made to the total volume of herbicides applied during the entire pesticide-use season.Twenty-four applicators and 15 minimally exposed foresters (control) subjects were studied. Categorized by applicator method, men who used a hand-held, backpack sprayer in their applications showed the highest average level (453.6 ppb) of 2,4-D in urine. Serum luteinizing hormone (LH) values were correlated with urinary 2,4-D levels, but follicle-stimulating hormone and free and total testosterone were not. At the height of the application season; 6/7 backpack sprayers, 3/4 applicators who used multinozzle mechanical (boom) sprayers, 4/8 aerial applicators, and 2/5 skidder-radiarc (closed cab) appliers had two or more V(D)J region rearrangements per microgram of DNA. Only 5 of 15 minimally exposed (control) foresters had two or more rearrangements, and 3 of these 5 subjects demonstrated detectable levels of 2,4-D in the urine. Only 8/24 DNA samples obtained from the exposed group 10 months or more after their last chlorophenoxy use had two rearrangements per microgram of DNA, suggesting that the exposure-related effects observed were reversible and temporary. Although urinary 2,4-D levels were not correlated with chromosome aberration frequency, chromosome

  13. pH-dependent aquatic criteria for 2,4-dichlorophenol, 2,4,6-trichlorophenol and pentachlorophenol.

    PubMed

    Xing, Liqun; Liu, Hongling; Giesy, John P; Yu, Hongxia

    2012-12-15

    Due to their agricultural as well as industrial uses, 2,4-dichlorophenol (2,4-DCP), 2,4,6-trichlorophenol (2,4,6-TCP), and pentachlorophenol (PCP) are ubiquitous in the environment and recognized as priority pollutants in many countries. In this study, effects of pH on toxicity to the crustacean Daphnia magna and the alga Scenedesmus obliquus were investigated. Combined published toxicity data of the three chlorophenols along with; relationships between toxicity and pH reported here were used to establish pH-dependent water quality criteria (WQC). The WQC expressed as a function of pH, also considered intra-species variation and proportions of taxonomic groups. At pH 7.8, the recommended acute exposure water quality criteria (WQC) were 286.2 μg 2,4-DCP/l, 341.5 μg 2,4,6-TCP/l and 11.4 μg PCP/l. The recommended chronic exposure WQC were 16.3 μg 2,4-DCP/l, 54.6 μg 2,4,6-TCP/land 3.9 μg PCP/l.

  14. 2, 4-dinitrophenol poisoning caused by non-oral exposure.

    PubMed

    Jiang Jiukun; Yuan Zhihua; Huang Weidong; Wang Jiezan

    2011-05-01

    2, 4-Dinitrophenol (2, 4-DNP) is widely used in industry, but recently, poisoning through consumption for weight control has been frequently reported. We report the cases of two patients whose deaths were attributed to occupational and non-oral exposure of 2, 4-DNP. They were all poisoned through skin absorption and respiratory tract inhalation; common features were excessive sweating, hyperthermia, tachycardia, clouded consciousness and asystole. Because of the lack of specific early symptoms, effective antidotes and the means of washing the contamination from the skin, their arrival in hospital was delayed and the supportive therapy was ineffectual. Cardiac arrest occurred quickly and unexpected after admission.

  15. 20-150-keV proton-impact-induced ionization of uracil: Fragmentation ratios and branching ratios for electron capture and direct ionization

    SciTech Connect

    Tabet, J.; Eden, S.; Feil, S.; Abdoul-Carime, H.; Farizon, B.; Farizon, M.; Ouaskit, S.; Maerk, T. D.

    2010-01-15

    Fragmentation ratios and branching ratios are measured for ionization and dissociative ionization for 20-150 keV (0.9-2.4v{sub 0}) proton collisions with gas-phase uracil molecules. Through event-by-event determination of the postcollision projectile charge, it is possible for such a key biomolecule to distinguish between electron capture (EC) by the incident proton and direct ionization (DI) without projectile neutralization. While the same fragment ion groups are observed in the mass spectra for both processes, EC induces dissociation with greater efficiency than DI in the impact energy range of 35-150 keV (1.2-2.4v{sub 0}). In this range EC is also less abundant than DI with a branching ratio for EC/total ionization of <50%. Moreover, whereas fragmentation ratios do not change with energy in the case of EC, DI mass spectra show a tendency for increased fragmentation at lower impact energies.

  16. Preparation of 4-amino-2,4-dioxobutanoic acid

    DOEpatents

    Unkefer, Pat J.; Martinez, Rodolfo A.; Glass, David R.

    2016-03-22

    A process for synthesizing 4-amino-2,4-dioxobutanoate involves reacting a dialkyl oxalate with an alkoxide in ethanol to form a reaction mixture, and afterward adding an alkyl cyano acetate to the reaction mixture and allowing a reaction to proceed under conditions suitable to form a first reaction product of the formula diethyl 2-cyano-3-hydroxy-butenedioate, and then isolating the diethyl 2-cyano-3-hydroxy-butenedioate, and afterward reacting the diethyl-2-cyano-3-hydroxy-butenedioate with an aqueous hydroxide under conditions suitable to form 4-amino-2,4-dioxobutanoate. The 4-amino-2,4-dioxobutanoate may be acidified into 4-amino-2,4-dioxobutanoic acid.

  17. Adjustable gastric banding (image)

    MedlinePlus

    ... normal digestive process. In this procedure, a hollow band made of special material is placed around the ... pouch and causes a feeling of fullness. The band can be tightened or loosened over time to ...

  18. Unravelling the resistance mechanisms to 2,4-D (2,4-dichlorophenoxyacetic acid) in corn poppy (Papaver rhoeas).

    PubMed

    Rey-Caballero, Jordi; Menéndez, Julio; Giné-Bordonaba, Jordi; Salas, Marisa; Alcántara, Ricardo; Torra, Joel

    2016-10-01

    In southern Europe, the intensive use of 2,4-D (2,4-dichlorophenoxyacetic acid) and tribenuron-methyl in cereal crop systems has resulted in the evolution of resistant (R) corn poppy (Papaver rhoeas L.) biotypes. Experiments were conducted to elucidate (1) the resistance response to these two herbicides, (2) the cross-resistant pattern to other synthetic auxins and (3) the physiological basis of the auxin resistance in two R (F-R213 and D-R703) populations. R plants were resistant to both 2,4-D and tribenuron-methyl (F-R213) or just to 2,4-D (D-R703) and both R populations were also resistant to dicamba and aminopyralid. Results from absorption and translocation experiment revealed that R plants translocated less [14C]-2,4-D than S plants at all evaluation times. There was between four and eight-fold greater ethylene production in S plants treated with 2,4-D, than in R plants. Overall, these results suggest that reduced 2,4-D translocation is the resistance mechanism in synthetic auxins R corn poppy populations and this likely leads to less ethylene production and greater survival in R plants.

  19. Soil matrix and macropore biodegradation of 2,4-D

    SciTech Connect

    Pivetz, B.E.; Steenhuis, T.S.

    1995-07-01

    Preferential flow of pesticides in macropores can lead to decreased travel times through the vadose zone and increased groundwater contamination. Macropores, however, may present a favorable environment for biodegradation because of greater oxygen, nutrient, and substrate supply, and higher microbial populations in earthworm burrows, compared to the soil matrix. The biodegradation of 2,4-dichlorophenoxyacetic acid (2,4-D) was measured in macropores and soil matrix of packed soil columns (7.0-cm diam., 10-cm length) and undisturbed cores contained as well-defined artificial macropore and the undisturbed cores contained earthworm-burrow macropores. A 50 {mu}g/L 2,4-D solution was continuously applied to the unsaturated soil surface and breakthrough curves (BTCs) indicating pesticide loss in the effluent were obtained from the soil matrix and macropore flow paths. Biodegradation rates were calculated separately for each flow path by comparing the BTCs to BTCs representing abiotic conditions, and dividing the 2,4-D loss by the travel time through each flow path. The biodegradation rates increased with time in both flow paths, and the final biodegradation rate in the macropore region surpassed that of the matrix, presumably because of increased microbial populations in the macropore. Complete loss of the 2,4-D in both flow paths was observed after continuous application of 2,4-D for 400 h, with maximum column-averaged 2,4-D loss rates of 0.879 {mu}g/(L h) in the matrix and 1.073 {mu}g/(L h) in the macropore. Biodegradation of 2,4-D was also observed in the macropore and matrix regions of the undisturbed soil cores. 19 refs., 7 figs., 2 tabs.

  20. Low Power Band to Band Tunnel Transistors

    DTIC Science & Technology

    2010-12-15

    the E-field and tunneling at the source- pocket junction you form a parasitic NPN + transistor and the injection mechanism of carriers into the...hypothesis that the 1000 ° C, 5s anneal split lead to a very wide pocket and the accidental formation of a NPN + transistor , while the 1000 ° C, 1s anneal...Low Power Band to Band Tunnel Transistors Anupama Bowonder Electrical Engineering and Computer Sciences University of California at Berkeley

  1. Solar Cycle dependence of 5-55 keV Cassini/INCA energetic neutral atom (ENA) images of the Heliosheath and in situ Voyager/LECP ion measurements

    NASA Astrophysics Data System (ADS)

    Krimigis, S. M.; Dialynas, K.; Mitchell, D. G.; Decker, R. B.; Roelof, E. C.

    2015-12-01

    The heliosheath has been identified as the most probable source of ENAs that INCA detects but its variability due to solar activity throughout the solar cycle (SC) has not been resolved to date. We show all-sky, 5-55 keV ENA H maps from the year 2003 to 2014 and compare the solar cycle variation of the ENAs in both the heliospheric nose (upstream) and anti-nose (downstream) directions with the > 30 keV ions measured within the heliosheath by the Low Energy Charged Particle (LECP) detector on Voyagers 1, 2 (V1, V2) where we measure protons in overlapping energy bands ~30-55 keV. We find that a) Toward the anti-nose direction the ENA-H intensities decline during SC23, i.e. after 2003 ENA intensities decreased by ~ x2 at all energies by the end of year 2011, ~1 year after the observed minimum in solar activity; b) This ENA decrease (5.2-55 keV) during 2009-2011 is consistent with the concurrent intensity decrease of the > 30 keV ions (by a factor of 2-3) observed in situ by V1 and V2 in the heliosheath; c) Toward the nose direction, minimum intensities in both INCA ENAs and the V2 ions at E > 28 keV occur during the year 2013, with a subsequent recovery from 2014 to date (by a factor of ~2 in the > 35 keV ENA data). These quantitative correlations between the decreases of INCA ENAs (in both the heliospheric nose and anti-nose directions) and the in situ V1 and V2 ion measurements (separated by > 130 AU) during the declining phase of SC23, along with their concurrent jointly shared recoveries at the onset of SC24, imply that: 1) the 5-55 keV ENAs are produced in the heliosheath (because their transit times over 100 AU are less than a few months at energies > 40 keV), thus proving that our ENA observations can provide the ground truth for constructing comprehensive global heliosphere models; 2) the global heliosheath responds promptly (within ~1-1.5 yrs) to outward-propagating solar wind changes throughout the solar cycle.

  2. Comprehensive investigations of kinetics of alkaline hydrolysis of TNT (2,4,6-trinitrotoluene), DNT (2,4-dinitrotoluene), and DNAN (2,4-dinitroanisole).

    PubMed

    Sviatenko, Liudmyla; Kinney, Chad; Gorb, Leonid; Hill, Frances C; Bednar, Anthony J; Okovytyy, Sergiy; Leszczynski, Jerzy

    2014-09-02

    Combined experimental and computational techniques were used to analyze multistep chemical reactions in the alkaline hydrolysis of three nitroaromatic compounds: 2,4,6-trinitrotoluene (TNT), 2,4-dinitrotoluene (DNT), and 2,4-dinitroanisole (DNAN). The study reveals common features and differences in the kinetic behavior of these compounds. The analysis of the predicted pathways includes modeling of the reactions, along with simulation of UV-vis spectra, experimental monitoring of reactions using LC/MS techniques, development of the kinetic model by designing and solving the system of differential equations, and obtaining computationally predicted kinetics for decay and accumulation of reactants and products. Obtained results suggest that DNT and DNAN are more resistant to alkaline hydrolysis than TNT. The direct substitution of a nitro group by a hydroxide represents the most favorable pathway for all considered compounds. The formation of Meisenheimer complexes leads to the kinetic first-step intermediates in the hydrolysis of TNT. Janovsky complexes can also be formed during hydrolysis of TNT and DNT but in small quantities. Methyl group abstraction is one of the suggested pathways of DNAN transformation during alkaline hydrolysis.

  3. The Search for 17-KEV Neutrino Emission in the Beta-Decay Spectrum of SULFUR-35.

    NASA Astrophysics Data System (ADS)

    Berman, Gregg Evan

    For this work, the electron momentum spectrum resulting from the beta-decay of ^{35}S, ^{35}{rm S} to ^ {35}{rm Cl} + {rm e }^- + |nu_{rm e}quad (E_0 - m_{e} = 167 {rm keV, T}_{1/2 } = 87.4 {rm days}), has been measured in order to search for the presence of 17-keV electron neutrino emission. Originally observed by J. Simpson in 1985, evidence supporting a 1% 17-keV neutrino branch in the decay spectra of ^3 H, ^{35}S, ^{63}Ni, ^{55 }Fe, ^{14}C and ^{71}Ge has since been reported. However, other groups observing these nuclei have not seen any evidence of 17-keV neutrino emission, and very stringent limits ruling out a 1% branch have been published. Therefore, an important goal of this work is to reduce and/or understand experimental systematic errors that can mask or mimic the effects of a 17-keV neutrino. This ^{35}S spectrum measurement was performed using Princeton's extensively renovated, iron-free, intermediate-image, magnetic spectrometer. To ensure radio-chemical purity, the ^{35 }S source was prepared by ion-implantation using an isotope separator. To accurately determine the overall response of the spectrometer, electron data was accumulated over the very wide energy range of 40-167 keV. In addition, a detailed study of the spectrometer response using various ^{111}In calibration sources was undertaken, and the effects of source positioning and background magnetic fields have been explored. Furthermore, new computer codes for electron orbit raytracing and Monte-Carlo simulations have been developed to help further study the response of the spectrometer as well as to predict the effects of electron backscattering in both the source and detector substrates. To analyze the experimental data for the presence of a 17-keV neutrino branch, the measured ^ {35}S spectrum was convolved with the overall response of the spectrometer, and then fit by least -squares reduction to a theoretical beta -decay shape that allows heavy-neutrino mixing. The results show that the

  4. Origins of the 2,4-Dinitrotoluene Pathway

    PubMed Central

    Johnson, Glenn R.; Jain, Rakesh K.; Spain, Jim C.

    2002-01-01

    The degradation of synthetic compounds requires bacteria to recruit and adapt enzymes from pathways for naturally occurring compounds. Previous work defined the steps in 2,4-dinitrotoluene (2,4-DNT) metabolism through the ring fission reaction. The results presented here characterize subsequent steps in the pathway that yield the central metabolic intermediates pyruvate and propionyl coenzyme A (CoA). The genes encoding the degradative pathway were identified within a 27-kb region of DNA cloned from Burkholderia cepacia R34, a strain that grows using 2,4-DNT as a sole carbon, energy, and nitrogen source. Genes for the lower pathway in 2,4-DNT degradation were found downstream from dntD, the gene encoding the extradiol ring fission enzyme of the pathway. The region includes genes encoding a CoA-dependent methylmalonate semialdehyde dehydrogenase (dntE), a putative NADH-dependent dehydrogenase (ORF13), and a bifunctional isomerase/hydrolase (dntG). Results from analysis of the gene sequence, reverse transcriptase PCR, and enzyme assays indicated that dntD dntE ORF13 dntG composes an operon that encodes the lower pathway. Additional genes that were uncovered encode the 2,4-DNT dioxygenase (dntAaAbAcAd), methylnitrocatechol monooxygenase (dntB), a putative LysR-type transcriptional (ORF12) regulator, an intradiol ring cleavage enzyme (ORF3), a maleylacetate reductase (ORF10), a complete ABC transport complex (ORF5 to ORF8), a putative methyl-accepting chemoreceptor protein (ORF11), and remnants from two transposable elements. Some of the additional gene products might play as-yet-undefined roles in 2,4-DNT degradation; others appear to remain from recruitment of the neighboring genes. The presence of the transposon remnants and vestigial genes suggests that the pathway for 2,4-DNT degradation evolved relatively recently because the extraneous elements have not been eliminated from the region. PMID:12107140

  5. Engineering Pseudomonas fluorescens for Biodegradation of 2,4-Dinitrotoluene†

    PubMed Central

    Monti, Mariela R.; Smania, Andrea M.; Fabro, Georgina; Alvarez, María E.; Argaraña, Carlos E.

    2005-01-01

    Using the genes encoding the 2,4-dinitrotoluene degradation pathway enzymes, the nonpathogenic psychrotolerant rhizobacterium Pseudomonas fluorescens ATCC 17400 was genetically modified for degradation of this priority pollutant. First, a recombinant strain designated MP was constructed by conjugative transfer from Burkholderia sp. strain DNT of the pJS1 megaplasmid, which contains the dnt genes for 2,4-dinitrotoluene degradation. This strain was able to grow on 2,4-dinitrotoluene as the sole source of carbon, nitrogen, and energy at levels equivalent to those of Burkholderia sp. strain DNT. Nevertheless, loss of the 2,4-dinitrotoluene degradative phenotype was observed for strains carrying pJS1. The introduction of dnt genes into the P.fluorescens ATCC 17400 chromosome, using a suicide chromosomal integration Tn5-based delivery plasmid system, generated a degrading strain that was stable for a long time, which was designated RE. This strain was able to use 2,4-dinitrotoluene as a sole nitrogen source and to completely degrade this compound as a cosubstrate. Furthermore, P. fluorescens RE, but not Burkholderia sp. strain DNT, was capable of degrading 2,4-dinitrotoluene at temperatures as low as 10°C. Finally, the presence of P. fluorescens RE in soils containing levels of 2,4-dinitrotoluene lethal to plants significantly decreased the toxic effects of this nitro compound on Arabidopsis thaliana growth. Using synthetic medium culture, P. fluorescens RE was found to be nontoxic for A.thaliana and Nicotiana tabacum, whereas under these conditions Burkholderia sp. strain DNT inhibited A.thaliana seed germination and was lethal to plants. These features reinforce the advantageous environmental robustness of P. fluorescens RE compared with Burkholderia sp. strain DNT. PMID:16332883

  6. Uptake of 2,4-Dichlorophenoxyacetic Acid by Pseudomonas fluorescens

    USGS Publications Warehouse

    Wedemeyer, Gary

    1966-01-01

    Factors influencing the uptake of the sodium salt of 2,4-dichlorophenoxyacetic acid (2,4-D), under conditions in which no net metabolism occurred, were investigated in an effort to determine both the significance of “non-metabolic” uptake as a potential agent in reducing pesticide levels and the mechanisms involved. Uptake of 2,4-D was affected by pH, temperature, and the presence of other organic and inorganic compounds. Uptake was more pronounced at pH values less than 6, which implies that there may be some interaction between charged groups on the cell and the ionized carboxyl group of 2,4-D. Active transport, carrier-mediated diffusion, passive diffusion, and adsorption were considered as possible mechanisms. Though uptake was inhibited by glucose, sodium azide, and fluorodinitrobenzene (but not by uranyl ion), 2,4-D was not accumulated against a concentration gradient, a necessary consequence of an active transport system, nor was isotope counterflow found to occur. Thus, carrier-mediated diffusion was finally precluded, implying that uptake probably occurs by a two-step process: sorption onto the cell wall followed by passive diffusion into the cytoplasm.

  7. Uptake of 2, 4-Dichlorophenoxyacetic acid by Pseudomonas fluorescens

    USGS Publications Warehouse

    Wedemeyer, G.A.

    1966-01-01

    Factors influencing the uptake of the sodium salt of 2,4-dichlorophenoxyacetic acid (2,4-D), under conditions in which no net metabolism occurred, were investigated in an effort to determine both the significance of “nonmetabolic” uptake as a potential agent in reducing pesticide levels and the mechanisms involved. Uptake of 2,4-D was affected by pH, temperature, and the presence of other organic and inorganic compounds. Uptake was more pronounced at pH values less than 6, which implies that there may be some interaction between charged groups on the cell and the ionized carboxyl group of 2,4-D. Active transport, carriermediated diffusion, passive diffusion, and adsorption were considered as possible mechanisms. Though uptake was inhibited by glucose, sodium azide, and fluorodinitrobenzene (but not by uranylion), 2,4-D was not accumulated against a concentration gradient, a necessary consequence of an active transport system, nor was isotope counterflow found to occur. Thus, carrier-mediated diffusion was finally precluded, implying that uptake probably occurs by a two-step process: sorption onto the cell wall followed by passive diffusion into the cytoplasm.

  8. 330-keV electron line in e sup + +Th interactions

    SciTech Connect

    Sakai, M.; Fujita, Y.; Imamura, M.; Omata, K.; Ohya, S.; Muto, S.; Miura, T.; Gono, Y.; Chojnacki, S. Niigata University, Niigata National Laboratory for High Energy Physics, Tsukuba Institute for Physical and Chemical Research, Wako-shi, Saitama-ken Accelerator Laboratory, Warsaw University, Warsaw )

    1991-09-01

    The previously reported 330.8{plus minus}1.0-keV electron line in {ital e}{sup +}+Th interactions has been reinvestigated to confirm its existence. We have made a definite observation of the relevant peak with an energy of 330.1{plus minus}0.3 keV, a fullwidth at half maximum of less than 1.7{plus minus}0.7 keV and a cross section of 160(1{plus minus}0.19{plus minus}0.25) mb. We have assigned the generation site of the electrons to the Th target by comparing the energy shift and the shape change of the line with those of the neighboring conversion lines in the spectra taken under different scattering conditions.

  9. Evaluation of the 1077 keV γ-ray emission probability from 68Ga decay

    NASA Astrophysics Data System (ADS)

    Huang, Xiao-Long; Jiang, Li-Yang; Chen, Xiong-Jun; Chen, Guo-Chang

    2014-04-01

    68Ga decays to the excited states of 68Zn through the electron capture decay mode. New recommended values for the emission probability of 1077 keV γ-ray given by the ENSDF and DDEP databases all use data from absolute measurements. In 2011, JIANG Li-Yang deduced a new value for 1077 keV γ-ray emission probability by measuring the 69Ga(n,2n) 68Ga reaction cross section. The new value is about 20% lower than values obtained from previous absolute measurements and evaluations. In this paper, the discrepancies among the measurements and evaluations are analyzed carefully and the new values are re-recommended. Our recommended value for the emission probability of 1077 keV γ-ray is (2.72±0.16)%.

  10. keV sterile neutrino dark matter and low scale leptogenesis

    NASA Astrophysics Data System (ADS)

    Kang, Sin Kyu; Patra, Ayon

    2016-10-01

    We consider a simple extension of the Standard Model to consistently explain the observation of a peak in the galactic X-ray spectrum at 3.55 keV, the light neutrino masses, and the baryon asymmetry of the universe. The baryon asymmetry is generated through leptogenesis, the lepton asymmetry being generated by the decay of a heavy neutrino with a TeV mass scale. The extra singlet fermion introduced in the model can be identified as a dark matter candidate with a mass of 7.1 keV. It decays with a lifetime much larger than the age of the universe, producing a final state photon. The Yukawa interactions between the extra singlet neutrino and a heavier right-handed neutrino play a crucial role in simultaneously achieving low-scale leptogenesis and the relic density of the keV dark matter candidate.

  11. Quark nugget dark matter: no contradiction with 511 keV line emission from dwarf galaxies

    NASA Astrophysics Data System (ADS)

    Lawson, Kyle; Zhitnitsky, Ariel

    2017-02-01

    The observed galactic 511 keV line has been interpreted in a number of papers as a possible signal of dark matter annihilation within the galactic bulge. If this is the case then it is possible that a similar spectral feature may be observed in association with nearby dwarf galaxies. These objects are believed to be strongly dark matter dominated and present a relatively clean observational target. Recently INTEGRAL observations have provided new constraints on the 511 keV flux from nearby dwarf galaxies [1] motivating further investigation into the mechanism by which this radiation may arise. In the model presented here dark matter in the form of heavy quark nuggets produces the galactic 511 keV emission line through interactions with the visible matter. It is argued that this type of interaction is not strongly constrained by the flux limits reported in [2].

  12. The energy spectrum of 662 keV photons in a water equivalent phantom

    NASA Astrophysics Data System (ADS)

    Akar Tarim, U.; Gurler, O.; Ozmutlu, E. N.; Yalcin, S.; Gundogdu, O.; Sharaf, J. M.; Bradley, D. A.

    2012-07-01

    Investigation is made on the energy spectrum of photons originating from interactions of 662 keV primary gamma-ray photons emitted by a point source positioned at the centre of a water equivalent solid phantom of dimensions 19 cm×19 cm×24 cm. Peaks resulting from total energy loss (photopeak) and multiple and back scattering have been observed using a 51 mm×51 mm NaI(Tl) detector; good agreement being found between the measured and simulated response functions. The energy spectrum of the gamma photons obtained through the Monte Carlo simulation reveals local maxima at about 100 keV and 210 keV, being also observed in the experimental response function. Such spectra can be used as a method of testing the water equivalence of solid phantom media before their use for dosimetry measurements.

  13. The Morphology of the X-ray Emission above 2 keV from Jupiter's Aurorae

    NASA Technical Reports Server (NTRS)

    Elsner, R.; Branduardi-Raymont, G.; Galand, M.; Grodent, D.; Waite, J. H.; Cravens, T.; Ford, P.

    2007-01-01

    The discovery in XMM-Newton X-ray data of X-ray emission above 2 keV from Jupiter's aurorae has led us to reexamine the Chandra ACIS-S observations taken in Feb 2003. Chandra's superior spatial resolution has revealed that the auroral X-rays with E > 2 keV are emitted from the periphery of the region emitting those with E < 1 keV. We are presently exploring the relationship of this morphology to that of the FUV emission from the main auroral oval and the polar cap. The low energy emission has previously been established as due to charge exchange between energetic precipitating ions of oxygen and either sulfur or carbon. It seems likely to us that the higher energy emission is due to precipitation of energetic electrons, possibly the same population of electrons responsible for the FUV emission. We discuss our analysis and interpretation.

  14. Study of 1–8 keV K-α x-ray emission from high intensity femtosecond laser produced plasma

    SciTech Connect

    Arora, V. Naik, P. A.; Chakera, J. A.; Bagchi, S.; Tayyab, M.; Gupta, P. D.

    2014-04-15

    We report an experimental study on the optimization of a laser plasma based x-ray source of ultra-short duration K-α line radiation. The interaction of pulses from a CPA based Ti:sapphire laser (10 TW, 45 fs, 10 Hz) system with magnesium, titanium, iron and copper solid target generates bright 1-8 keV K-α x-ray radiation. The x-ray yield was optimized with the laser pulse duration (at fixed fluence) which is varied in the range of 45 fs to 1.4 ps. It showed a maximum at laser pulse duration of ∼740 fs, 420 fs, 350 and 250 fs for Mg (1.3 keV), Ti (4.5 keV), Fe (6.4 keV) and Cu (8.05 keV) respectively. The x-ray yield is observed to be independent of the sign of the chirp. The scaling of the K-α yield (I{sub x} ∝ I{sub L}{sup β}) for 45 fs and optimized pulse duration were measured for laser intensities in the region of 3 × 10{sup 14} – 8 × 10{sup 17}. The x-ray yield shows a much faster scaling exponent β = 1.5, 2.1, 2.4 and 2.6 for Mg, Ti, Fe and Cu respectively at optimized pulse duration compared to scaling exponent of 0.65, 1.3, 1.5, and 1.7 obtained for 45 fs duration laser pulses. The laser to x-ray energy conversion efficiencies obtained for different target materials are η{sub Mg} = 1.2 × 10{sup −5}, η{sub Ti} = 3.1 × 10{sup −5}, η{sub Fe} = 2.7 × 10{sup −5}, η{sub Cu} = 1.9 × 10{sup −5}. The results have been explained from the efficient generation of optimal energy hot electrons at longer laser pulse duration. The faster scaling observed at optimal pulse duration indicates that the x-ray source is generated at the target surface and saturation of x-ray emission would appear at larger laser fluence. An example of utilization of the source for measurement of shock-wave profiles in a silicon crystal by time resolved x-ray diffraction is also presented.

  15. Preparation of 4-amino-2,4-dioxobutanoic acid

    DOEpatents

    Unkefer, Pat J.; Martinez, Rodolfo A.; Glass, David R.

    2016-03-22

    A process for synthesizing 4-amino-2,4-dioxobutanoic acid involves reacting diethyl oxalate with an alkoxide in ethanol to form a reaction mixture, and afterward adding ethyl cyanoacetate to the reaction mixture and allowing a reaction to proceed under conditions suitable to form a first reaction product of the formula diethyl 2-cyano-3-hydroxy-butenedioate, and then isolating the diethyl 2-cyano-3-hydroxy-butenedioate, and afterward reacting the diethyl-2-cyano-3-hydroxy-butenedioate with an aqueous hydroxide under conditions suitable to form 4-amino-2,4-dioxobutanoic acid.

  16. Preparation of 4-amino-2,4-dioxobutanoic acid

    DOEpatents

    Unkefer, Pat J.; Martinez, Rodolfo A.; Glass, David R.

    2015-06-02

    A process for synthesizing 4-amino-2,4-dioxobutanoic acid involves reacting diethyl oxalate with sodium ethoxide in ethanol to form a reaction mixture, and afterward adding ethyl cyanoacetate to the reaction mixture and allowing a reaction to proceed under conditions suitable to form a first reaction product of the formula diethyl-2-cyano-3-hydroxy-butenedioate, and then isolating the diethyl-2-cyano-3-hydroxybutenedioate, and afterward reacting the diethyl-2-cyano-3-hydroxy-butenedioate with aqueous sodium hydroxide under conditions suitable to form 4-amino-2,4-dioxobutanoic acid.

  17. Synthesis and controlled release properties of 2,4-dichlorophenoxy acetate–zinc layered hydroxide nanohybrid

    SciTech Connect

    Bashi, Abbas M.; Hussein, Mohd Zobir; Zainal, Zulkarnain; Tichit, Didier

    2013-07-15

    Direct reaction of ZnO with 2,4-dichlorophenoxyacetic acid (24D) solutions of different concentrations allows obtaining new organic–inorganic nanohybrid materials formed by intercalation of 24D into interlayers of zinc layered hydroxide (ZLH). XRD patterns show a progressive evolution of the structure as 24D concentration increases. The nanohybrid obtained at higher 24D concentration (24D–ZLH(0.4)) reveals a well ordered layered structure with two different basal spacings at 25.2 Å and 24 Å. The FTIR spectrum showing the vibrations bands of the functional groups of 24D and of the ZLH confirms the intercalation. SEM images are in agreement with the structural evolution observed by XRD and reveal the ribbon morphology of the nanohybrids. The release studies of 24D showed a rapid release of 94% for the first 100 min governed by the pseudo-second order kinetic model. - Graphical abstract: The phenomenon indicates that the optical energy gap is enlarged with the increase of molar concentrations in 2,4-dichlorophenoxy acetate anion content into ZnO to create a ZLH–24D nanohybrid. - Highlights: • Nanohybrid was synthesized from 2,4-dichlorophenoxy acetate with-Zinc LHD, using wet chemistry. • Characterized using SEM, TEM, EDX, FTIR, XRD and TGA. • Ribbon-shaped 24D–Zn-layered hydroxide nanoparticles with (003) diffractions of 2.5 nm phase were synthesized.

  18. 3.55 keV line in minimal decaying dark matter scenarios

    SciTech Connect

    Arcadi, Giorgio; Covi, Laura; Dradi, Federico

    2015-07-20

    We investigate the possibility of reproducing the recently reported 3.55 keV line in some simple decaying dark matter scenarios. In all cases a keV scale decaying DM is coupled with a scalar field charged under SM gauge interactions and thus capable of pair production at the LHC. We will investigate how the demand of a DM lifetime compatible with the observed signal, combined with the requirement of the correct DM relic density through the freeze-in mechanism, impacts the prospects of observation at the LHC of the decays of the scalar field.

  19. Relative biological effectiveness of 280 keV neutrons for apoptosis in human lymphocytes.

    PubMed

    Ryan, L A; Wilkins, R C; McFarlane, N M; Sung, M M; McNamee, J P; Boreham, D R

    2006-07-01

    The relative biological effectiveness (RBE) of neutrons varies from unity to greater than ten depending upon neutron energy and the biological endpoint measured. In our study, we examined apoptosis in human lymphocytes to assess the RBE of low energy 280 keV neutrons compared to Cs gamma radiation and found the RBE to be approximately one. Similar results have been observed for high energy neutrons using the same endpoint. As apoptosis is a major process that influences the consequences of radiation exposure, our results indicate that biological effect and the corresponding weighting factors for 280 keV neutrons may be lower in some cell types and tissues.

  20. Antimicrobial studies of some novel quinazolinones fused with [1,2,4]-triazole, [1,2,4]-triazine and [1,2,4,5]-tetrazine rings.

    PubMed

    Pandey, Sarvesh Kumar; Singh, Abhishek; Singh, Ashutosh; Nizamuddin

    2009-03-01

    Three series of novel and new fused heterocyclic systems, viz. triazolo[4,3-a]-quinazolin-7-ones (4), [1,2,4,5]-tetrazino[4,3-a]-quinazolin-8-ones (6) and indolo[2,3-c][1,2,4]-triazino[4,3-a]-quinazolin-8-ones (8) have been synthesized from the key intermediate 3-(substituted-phenyl)-2-hydrazino-quinazolin-4-ones (3). Thus, condensation of (3) with appropriate aromatic acids in the presence of DCC in dichloromethane afforded the fused system (4), while reaction of (3) with isatin in methanol gave the corresponding Schiff base (7) which on cyclodehydration furnished another fused heterocyclic system (8). The intermediate (3) on refluxing with substituted-phenylisothiocyanate gave the substituted-thiosemicarbazide (5), which on oxidative cyclization with bromine in CCl(4) furnished the novel fused system (6). The structures of intermediate and final compounds have been determined by means of IR, (1)H NMR, (13)C NMR, UV and elemental analysis. All the synthesized compounds have been screened for their antibacterial activity against gram-negative bacteria, Escherichia coli, Pseudomonas aeruginosa and gram-positive bacteria, Streptococcus pneumoniae, Bacillus subtilis, as well as demonstrated significant antifungal activity against fungi viz. Candida albicans, Aspergillus fumigatus, Aspergillus flavus, and Aspergillus niger.

  1. Effect of 2,4-Dichlorophenoxyacetic Acid on Glucosylation of Scopoletin to Scopolin in Tobacco Tissue Culture

    PubMed Central

    Hino, Fumitsugu; Okazaki, Mitsuo; Miura, Yoshiharu

    1982-01-01

    2,4-Dichlorophenoxyacetic acid (2,4-D) stimulated the formation of scopoletin and scopolin in tobacco (Nicotiana tabacum L. `Bright Yellow') cell culture. It especially stimulated the uptake of scopoletin from culture medium into the cells and the glucosylation of scopoletin to its monoglucoside, scopolin. This phenomenon is peculiar to 2,4-D, in contrast to other plant hormones. 2,4-D (1 μg/ml) stimulated the glucosylation of scopoletin to scopolin by enhancing UDP-glucose:scopoletin glucosyltransferase (SGTase) activity. The enhancement of SGTase activity caused by treatment with 2,4-D was observed when the syntheses of RNA and protein were inhibited by either actinomycin-D and/or cycloheximide. However, the stimulatory effect of 2,4-D was inhibited by treatment with dinitrophenol. Furthermore, SGTase with or without treatment by 2,4-D in vivo for 24 hours, was isolated from cultured tobacco cells. The enzymes were purified about 200-fold by precipitation with (NH4)2SO4 and chromatography with Sephadex G-100, DEAE-cellulose, and hydroxyapatite. The specific activity of 2,4-D-treated SGTase was 10 times higher than that of untreated SGTase even in the purified fraction, which showed one protein band under electrophoresis. These results suggest that the enhancement of SGTase activity by 2,4-D is due to the energy-dependent activation of the enzyme already present, but not due to the de novo synthesis of the enzyme. Images PMID:16662301

  2. Photocopy of drawing. VAB HB2 & 4 ET HOLDING CELLS, ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    Photocopy of drawing. VAB HB-2 & 4 ET HOLDING CELLS, UPGRADE TO CHECKOUT CELLS. NASA John F. Kennedy Space Center, Florida. File Number 79K33180, Reynolds, Smith & Hill, February 1991. GENERAL ARRANGEMENT, PLAN & ELEVATIONS. Sheet 4 - Cape Canaveral Air Force Station, Launch Complex 39, Vehicle Assembly Building, VAB Road, East of Kennedy Parkway North, Cape Canaveral, Brevard County, FL

  3. Photocopy of drawing. VAB HB2 & 4 ET HOLDING CELLS, ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    Photocopy of drawing. VAB HB-2 & 4 ET HOLDING CELLS, UPGRADE TO CHECKOUT CELLS. NASA John F. Kennedy Space Center, Florida. File Number 79K33180, Reynolds, Smith & Hill, February 1991. HINGED PANEL EQUIPMENT SCHEDULE. Sheet 28 - Cape Canaveral Air Force Station, Launch Complex 39, Vehicle Assembly Building, VAB Road, East of Kennedy Parkway North, Cape Canaveral, Brevard County, FL

  4. 2,4,6-TRINITROTOLUENE TRANSFORMATION IN PLANTED, SOIL COLUMNS

    EPA Science Inventory

    2,4,6-Trinitrotoluene (TNT), has been used extensively by the United States military to manufacture explosive devices. Since the conclusion of World War 11, many of these military installations have also been involved in the disposal of surplus and outdated explosives. Both the c...

  5. 41 CFR 51-2.4 - Determination of suitability.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Public Contracts COMMITTEE FOR PURCHASE FROM PEOPLE WHO ARE BLIND OR SEVERELY DISABLED 2-COMMITTEE FOR PURCHASE FROM PEOPLE WHO ARE BLIND OR SEVERELY DISABLED § 51-2.4 Determination of suitability. (a) For a... generate employment for persons who are blind or have other severe disabilities. (2) Nonprofit...

  6. 1,2,4-Butanetriol: Analysis and Synthesis

    DTIC Science & Technology

    1982-12-08

    ANHYDRIDE ........................41 CLEAVAGE OF CYCLIC ETHERS. .. ....... ......... 43 REFERENCES .. ... .......... .......... ......... 45... NOMENCLATURE .. ... .......... .......... ........ 49 1. iii/jy NSWC TR 82-380 ILLUSTRATIONS Figure Page I HYDROGENATION OF DIETHYLMALATE IN ETHANOL OVER NIKKI...of acetic acid, acetic anhydride , and sul Uric acid yielded 1,2,4-butanetriol triacetate. Subsequent methanolysis of the acetate produced BT. Wagaman

  7. 2,2\\',4,4\\',5-Pentabromodiphenyl ether (BDE-99)

    Integrated Risk Information System (IRIS)

    EPA / 635 / R - 07 / 006F www.epa.gov / iris TOXICOLOGICAL REVIEW OF 2,2 ' , 4,4 ' , 5 - PENTABROMODIPHENYL ETHER ( BDE - 99 ) ( CAS No . 60348 - 60 - 9 ) In Support of Summary Information on the Integrated Risk Information System ( IRIS ) June 2008 U.S . Environmental Protection Agency Washington ,

  8. 2,2\\',4,4\\'-Tetrabromodiphenyl ether (BDE-47)

    Integrated Risk Information System (IRIS)

    EPA / 635 / R - 07 / 005F www.epa.gov / iris TOXICOLOGICAL REVIEW OF 2,2 ' , 4,4 ' - TETRABROMODIPHENYL ETHER ( BDE - 47 ) ( CAS No . 5436 - 43 - 1 ) In Support of Summary Information on the Integrated Risk Information System ( IRIS ) June 2008 U.S . Environmental Protection Agency Washington , DC D

  9. A Discovery-Learning 2,4-Dinitrophenylhydrazone Experiment

    ERIC Educational Resources Information Center

    Vittimberga, Bruno M.; Ruekberg, Ben

    2006-01-01

    Selections of liquid aldehydes and ketones are proposed for students to determine what property is the best predictor of the color (yellow to red) of their 2,4-dinitrophenylhydrazone derivative. Students may use a computer (spreadsheet or word processor) to analyze results. (Contains 1 table and 3 notes.)

  10. Di(hydroxyphenyl)- 1,2,4-triazole monomers

    NASA Technical Reports Server (NTRS)

    Connell, John W. (Inventor); Hergenrother, Paul M. (Inventor); Wolf, Peter (Inventor)

    1993-01-01

    The di(hydroxyphenyl)- 1,2,4-triazole monomers were first synthesized by reacting bis (4-hydroxyphenyl) hydrazide with aniline hydrochloride at 250 C in the melt and also by reacting 1,3 or 1,4-bis- (4-hydroxyphenyl)- phenylene- dihydrazide with 2 moles of aniline hydrochloride in the melt. Purification of the di(hydroxyphenyl)- 1,2,4-triazole monomers was accomplished by recrystallization. Poly (1,2,4-triazoles) (PT) were prepared by the aromatic nucleophilic displacement reaction of di(hydroxyphenyl)- 1,2,4-triazole monomers with activated aromatic dihalides or activated aromatic dinitro compounds. The reactions were carried out in polar aprotic solvents such as sulfolane or diphenylsulfone using alkali metal bases such as potassium carbonate at elevated temperatures under nitrogen. This synthetic route has provided high molecular weight PT of new chemical structure, is economically and synthetically more favorable than other routes, and allows for facile chemical structure variation due to the availability of a large variety of activated aromatic dihalides.

  11. 2,4-/2,6-Toluene diisocyanate mixture (TDI)

    Integrated Risk Information System (IRIS)

    2,4 - / 2,6 - Toluene diisocyanate mixture ( TDI ) ; CASRN 26471 - 62 - 5 Human health assessment information on a chemical substance is included in the IRIS database only after a comprehensive review of toxicity data , as outlined in the IRIS assessment development process . Sections I ( Health Haz

  12. FLESNews, Volume 4, Numbers 2-4, 1990-91.

    ERIC Educational Resources Information Center

    Rosenbusch, Marcia H., Ed.

    Issues 2-4 of this volume of the newsletter concerning foreign language instruction in elementary schools (FLES) contain articles on theory, classroom practice, instructional materials, class activities, and professional news, including conferences and information on public policy at the federal level. Articles in these issues include the…

  13. Study of surface activation of PET by low energy (keV) Ni + and N + ion implantation

    NASA Astrophysics Data System (ADS)

    Nathawat, Rashi; Kumar, Anil; Kulshrestha, V.; Vijay, Y. K.; Kobayashi, T.; Kanjilal, D.

    2008-11-01

    Polyethyleneterephthalate (PET) has been modified by 100 keV Ni + and N + ions using metal ion from volatile compound (MIVOC) ion source to fluence ranging from 1 × 10 14 to 1 × 10 16 ions/cm 2. The increasing application of polymeric material in technological and scientific field has motivated the use of surface treatment to modify the physical and chemical properties of polymer surfaces. When a material is exposed to ionization radiation, it suffers damage leading to surface activation depending on the type. The surface morphology was observed by atomic force microscopy (AFM). That show the roughness increases with fluence in both the cases. The Ni particles as precipitation in PET were observed by cross-section transmission electron microscopy (XTEM). The optical band gap ( Eg) deduced from absorption spectra; was calculated by Tau'c relation. Raman spectroscopy shows quantitatively the chemical nature at the damage caused by the Ni + and N + bombardment. The ration of ID/ IG shows graphite-like structure is formed on the surface. A layer of hydrogenated amorphous carbon is formed on the surface, which has confirmed by XPS results also.

  14. Distribution and excretion of 2,4,5,2',4',5'-hexabromobiphenyl, the major component of Firemaster BP-6.

    PubMed

    Matthews, H B; Kato, S; Morales, N M; Tuey, D B

    1977-10-01

    The intestinal absorption, distribution, and excretion of the major component of Firemaster BP-6,2,4,5,2',4',5'-hexabromobiphenyl, has been studied in the male rat. This polybrominated biphenyl was readily absorbed from the intestine, initially distributed throughout the body, and eventually stored primarily in the adipose tissue, was not subject to appreciable metabolism, and was excreted almost exclusively in the feces and at a very slow rate. Approximately 90% of an oral dose was absorbed from the intestine, and extrapolation of the rate of excretion to infinity indicates that less than 10% of the total dose would ever be excreted.

  15. Wide Band to ''Double Band'' upgrade

    SciTech Connect

    Kasper, P.; Currier, R.; Garbincius, P.; Butler, J.

    1988-06-01

    The Wide Band beam currently uses electrons obtained from secondary photon conversions to produce the photon beam incident on the experimental targets. By transporting the positrons produced in these conversions as well as the electrons it is possible to almost double the number of photons delivered to the experiments per primary beam proton. 11 figs.

  16. Broad-band X-ray observations of CIR X-1

    NASA Astrophysics Data System (ADS)

    Maisack, M.; Staubert, R.; Balucinska-Church, M.; Skinner, G.; Doebereiner, S.; Englhauser, J.; Aref'ev, V. A.; Efremov, V. V.; Sunyaev, R. A.

    1995-08-01

    We present broad-band (2-88 keV) X-ray observations of the X-ray binary Cir X-1 with the TTM and HEXE instruments on board of the Mir space station. The observations were made in January/February 1989. The spectrum is best described by a model with 3 components: a blackbody at low energies, an iron line and a Comptonized hard continuum. The spectrum is variable during our observations; when the Comptonized component becomes harder, the spectrum becomes softer below 15 keV. The high-energy spectrum resembles that of X-ray binary pulsars.

  17. Solar wind ions accelerated to 40 keV by shock wave disturbances

    NASA Astrophysics Data System (ADS)

    Gosling, J. T.; Asbridge, J. R.; Bame, S. J.; Feldman, W. C.; Paschmann, G.; Sckopke, N.

    1980-02-01

    Observations in the solar wind with the LASL/MPI fast plasma experiment on ISEE 1 and 2 reveal the common presence of ions with energies extending from 100 eV up to at least 40 keV in a broad region, typically 10 million kilometers wide, following interplanetary shocks. Peak differential fluxes up to 5000/sq cm s sr keV at 28 keV are observed either at the shock or within the first 1.5 hours following shock passage. In the solar wind frame the distribution function of these ions is roughly isotropic, peaks near zero velocity, and above 5 keV can adequately be characterized as power law in energy with a spectral index of 2.7. The effective 'temperature' of these ions generally exceeds 100 million K. These suprathermal interplanetary ions are almost certainly solar wind ions which have been accelerated by some mechanism associated with the shock wave disturbance. Present evidence leads the authors to favor stochastic particle acceleration involving electrostatic and/or electromagnetic turbulence in the postshock flow.

  18. A gas scintillation proportional detector to search for 17 keV neutrinos

    SciTech Connect

    Okx, W.J.C.; Bom, V.R.; Eijk, C.W.E. van; Hollander, R.W. )

    1993-08-01

    Evidence for the existence of a 17 keV neutrino was first reported in 1985. Since then many experiments have been performed with contradicting results. In this paper the authors describe an experiment with a new approach to the problem by the introduction of a Gas Scintillation Proportional Detector.

  19. A study on the microstructural parameters of 550 keV electron irradiated Lexan polymer films

    SciTech Connect

    Hareesh, K.; Pramod, R.; Petwal, V. C.; Dwivedi, Jishnu; Sangappa; Sanjeev, Ganesh

    2012-06-05

    Lexan polymer films irradiated with 550 keV Electron Beam (EB) were characterized using Wide Angle Xray Scattering (WAXS) data to study the microstructural parameters. The crystal imperfection parameters like crystal size , lattice strain (g in %) and enthalpy ({alpha}) have been determined by Line Profile Analysis (LPA) using Fourier method of Warren.

  20. Heliospheric Neutral Atom Spectra Between 0.01 and 6 keV fom IBEX

    NASA Technical Reports Server (NTRS)

    Fuselier, S. A.; Allegrini, F.; Bzowski, M.; Funsten, H. O.; Ghielmetti, A. G.; Gloeckler, G.; Heirtzler, D.; Janzen, P.; Kubiak, M.; Kucharek, H.; McComas, D. J.; Moebius, E.; Moore, T. E.; Petrinec, S. M.; Quinn, M.; Reisenfeld, D.; Saul, L. A.; Scheer, J. A.; Schwardron, N.; Trattner, K. J.; Vanderspek, R.; Wurz, P.

    2012-01-01

    Since 2008 December, the Interstellar Boundary Explorer (IBEX) has been making detailed observations of neutrals from the boundaries of the heliosphere using two neutral atom cameras with overlapping energy ranges. The unexpected, yet defining feature discovered by IBEX is a Ribbon that extends over the energy range from about 0.2 to 6 keV. This Ribbon is superposed on a more uniform, globally distributed heliospheric neutral population. With some important exceptions, the focus of early IBEX studies has been on neutral atoms with energies greater than approx. 0.5 keV. With nearly three years of science observations, enough low-energy neutral atom measurements have been accumulated to extend IBEX observations to energies less than approx. 0.5 keV. Using the energy overlap of the sensors to identify and remove backgrounds, energy spectra over the entire IBEX energy range are produced. However, contributions by interstellar neutrals to the energy spectrum below 0.2 keV may not be completely removed. Compared with spectra at higher energies, neutral atom spectra at lower energies do not vary much from location to location in the sky, including in the direction of the IBEX Ribbon. Neutral fluxes are used to show that low energy ions contribute approximately the same thermal pressure as higher energy ions in the heliosheath. However, contributions to the dynamic pressure are very high unless there is, for example, turbulence in the heliosheath with fluctuations of the order of 50-100 km/s.

  1. NEUTRON TOTAL CROSS SECTIONS OF 235U FROM TRANSMISSION MEASUREMENTS IN THE ENERGY RANGE 2 keV to 300 keV AND STATISTICAL MODEL ANALYSIS OF THE DATA

    SciTech Connect

    Derrien, H.

    2000-05-22

    The average {sup 235}U neutron total cross sections were obtained in the energy range 2 keV to 330 keV from high-resolution transmission measurements of a 0.033 atom/b sample. The experimental data were corrected for the contribution of isotope impurities and for resonance self-shielding effects in the sample. The results are in very good agreement with the experimental data of Poenitz et al. in the energy range 40 keV to 330 keV and are the only available accurate experimental data in the energy range 2 keV to 40 keV. ENDF/B-VI evaluated data are 1.7% larger. The SAMMY/FITACS code was used for a statistical model analysis of the total cross section, selected fission cross sections and {alpha} data in the energy range 2 keV to 200 keV. SAMMY/FITACS is an extended version of SAMMY which allows consistent analysis of the experimental data in the resolved and unresolved resonance region. The Reich-Moore resonance parameters were obtained from a SAMMY Bayesian fits of high resolution experimental neutron transmission and partial cross section data below 2.25 keV, and the corresponding average parameters and covariance data were used in the present work as input for the statistical model analysis of the high energy range of the experimental data. The result of the analysis shows that the average resonance parameters obtained from the analysis of the unresolved resonance region are consistent with those obtained in the resolved energy region. Another important result is that ENDF/B-VI capture cross section could be too small by more than 10% in the energy range 10 keV to 200 keV.

  2. Neutron Total Cross Sections of {sup 235}U From Transmission Measurements in the Energy Range 2 keV to 300 keV and Statistical Model Analysis of the Data

    SciTech Connect

    Derrien, H.; Harvey, J.A.; Larson, N.M.; Leal, L.C.; Wright, R.Q.

    2000-05-01

    The average {sup 235}U neutron total cross sections were obtained in the energy range 2 keV to 330 keV from high-resolution transmission measurements of a 0.033 atom/b sample.1 The experimental data were corrected for the contribution of isotope impurities and for resonance self-shielding effects in the sample. The results are in very good agreement with the experimental data of Poenitz et al.4 in the energy range 40 keV to 330 keV and are the only available accurate experimental data in the energy range 2 keV to 40 keV. ENDF/B-VI evaluated data are 1.7% larger. The SAMMY/FITACS code 2 was used for a statistical model analysis of the total cross section, selected fission cross sections and data in the energy range 2 keV to 200 keV. SAMMY/FITACS is an extended version of SAMMY which allows consistent analysis of the experimental data in the resolved and unresolved resonance region. The Reich-Moore resonance parameters were obtained 3 from a SAMMY Bayesian fits of high resolution experimental neutron transmission and partial cross section data below 2.25 keV, and the corresponding average parameters and covariance data were used in the present work as input for the statistical model analysis of the high energy range of the experimental data. The result of the analysis shows that the average resonance parameters obtained from the analysis of the unresolved resonance region are consistent with those obtained in the resolved energy region. Another important result is that ENDF/B-VI capture cross section could be too small by more than 10% in the energy range 10 keV to 200 keV.

  3. Singing with the Band

    ERIC Educational Resources Information Center

    Altman, Timothy Meyer; Wright, Gary K.

    2012-01-01

    Usually band, orchestra, and choir directors work independently. However, the authors--one a choral director, the other a band director--have learned that making music together makes friends. Not only can ensemble directors get along, but joint concerts may be just the way to help students see how music can reach the heart. Combined instrumental…

  4. Rubber Band Science

    ERIC Educational Resources Information Center

    Cowens, John

    2005-01-01

    Not only are rubber bands great for binding objects together, but they can be used in a simple science experiment that involves predicting, problem solving, measuring, graphing, and experimenting. In this article, the author describes how rubber bands can be used to teach the force of mass.

  5. Stretch Band Exercise Program

    ERIC Educational Resources Information Center

    Skirka, Nicholas; Hume, Donald

    2007-01-01

    This article discusses how to use stretch bands for improving total body fitness and quality of life. A stretch band exercise program offers a versatile and inexpensive option to motivate participants to exercise. The authors suggest practical exercises that can be used in physical education to improve or maintain muscular strength and endurance,…

  6. High-spin states and a new band based on the isomeric state in 152Nd

    NASA Astrophysics Data System (ADS)

    Yeoh, E. Y.; Zhu, S. J.; Hamilton, J. H.; Ramayya, A. V.; Yang, Y. C.; Sun, Y.; Hwang, J. K.; Liu, S. H.; Wang, J. G.; Luo, Y. X.; Rasmussen, J. O.; Lee, I. Y.; Ding, H. B.; Li, K.; Gu, L.; Xu, Q.; Xiao, Z. G.; Ma, W. C.

    2010-08-01

    High-spin states of the neutron-rich 152Nd nucleus have been reinvestigated by measuring the prompt γ -rays in the spontaneous fission of 252Cf . The ground-state band and a side negative-parity band have been updated. A new band based on the 2243.7keV isomeric state has been identified. The half-life for the isomeric state has been measured to be 63(7)ns. The projected shell model is employed to study the band structure of this nucleus. The results show that the calculated levels of the bands are in good agreement with the experimental ones, and the isomeric state and the negative-parity band are based on the proton π5/2-[532] ⊗ π9/2+[404] and neutron ν3/2-[521] ⊗ ν5/2+[642] two-quasiparticles configurations, respectively.

  7. Progressive Band Selection

    NASA Technical Reports Server (NTRS)

    Fisher, Kevin; Chang, Chein-I

    2009-01-01

    Progressive band selection (PBS) reduces spectral redundancy without significant loss of information, thereby reducing hyperspectral image data volume and processing time. Used onboard a spacecraft, it can also reduce image downlink time. PBS prioritizes an image's spectral bands according to priority scores that measure their significance to a specific application. Then it uses one of three methods to select an appropriate number of the most useful bands. Key challenges for PBS include selecting an appropriate criterion to generate band priority scores, and determining how many bands should be retained in the reduced image. The image's Virtual Dimensionality (VD), once computed, is a reasonable estimate of the latter. We describe the major design details of PBS and test PBS in a land classification experiment.

  8. Decision document for function 4.2.4 dispose waste

    SciTech Connect

    Mcconville, C.M.

    1996-09-23

    This report formally documents the planning assumptions for Function 4.2.4, {ital Dispose Waste} to provide a basis for lower level Tank Waste Remediation System (TWRS) Disposal Program decisions and analyses. The TWRS Environmental Impact Statement (DOE/EIS 1996) and a supplemental Environmental Impact Statement for closure of operable units will provide the ultimate Records of Decision for the TWRS strategy at this level. However, in the interim, this decision document provides a formal basis for the TWRS Dispose Waste planning assumptions. Function 4.2.4 addresses the disposition of immobilized high-level waste (IHLW), the disposition of immobilized low-activity waste (ILAW), and closure of the tank farm operable units.

  9. Photocopy of drawing. VAB HB2 & 4 ET HOLDING CELLS, ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    Photocopy of drawing. VAB HB-2 & 4 ET HOLDING CELLS, UPGRADE TO CHECKOUT CELLS. NASA John F. Kennedy Space Center, Florida. File Number 79K33180, Reynolds, Smith & Hill, February 1991. H.B.-2, PLANS AT LEVELS 4,5,&6. Sheet 7 - Cape Canaveral Air Force Station, Launch Complex 39, Vehicle Assembly Building, VAB Road, East of Kennedy Parkway North, Cape Canaveral, Brevard County, FL

  10. Photocopy of drawing. VAB HB2 & 4 ET HOLDING CELLS, ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    Photocopy of drawing. VAB HB-2 & 4 ET HOLDING CELLS, UPGRADE TO CHECKOUT CELLS. NASA John F. Kennedy Space Center, Florida. File Number 79K33180, Reynolds, Smith & Hill, February 1991. H.B.-2, PLANS AT LEVELS 7,8,&9. Sheet 8 - Cape Canaveral Air Force Station, Launch Complex 39, Vehicle Assembly Building, VAB Road, East of Kennedy Parkway North, Cape Canaveral, Brevard County, FL

  11. Photocopy of drawing. VAB HB2 & 4 ET HOLDING CELLS, ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    Photocopy of drawing. VAB HB-2 & 4 ET HOLDING CELLS, UPGRADE TO CHECKOUT CELLS. NASA John F. Kennedy Space Center, Florida. File Number 79K33180, Reynolds, Smith & Hill, February 1991. H.B.-2, PLANS AT LEVELS 1,2,&3. Sheet 6 - Cape Canaveral Air Force Station, Launch Complex 39, Vehicle Assembly Building, VAB Road, East of Kennedy Parkway North, Cape Canaveral, Brevard County, FL

  12. Anaerobic transformation of 2,4,6-trinitrotoluene (TNT).

    PubMed

    Preuss, A; Fimpel, J; Diekert, G

    1993-01-01

    A sulfate-reducing bacterium using trinitrotoluene (TNT) as the sole nitrogen source was isolated with pyruvate and sulfate as the energy sources. The organism was able to reduce TNT to triaminotoluene (TAT) in growing cultures and cell suspensions and to further transform TAT to still unknown products. Pyruvate, H2, or carbon monoxide served as the electron donors for the reduction of TNT. The limiting step in TNT conversion to TAT was the reduction of 2,4-diamino-6-nitrotoluene (2,4-DANT) to triaminotoluene. The reduction proceeded via 2,4-diamino-6-hydroxylaminotoluene (DAHAT) as an intermediate. The intermediary formation of DAHAT was only observed in the presence of carbon monoxide or hydroxylamine, respectively. The reduction of DAHAT to triaminotoluene was inhibited by both CO and NH2OH. The inhibitors as well as DANT and DAHAT significantly inhibited sulfide formation from sulfite. The data were taken as evidence for the involvement of dissimilatory sulfite reductase in the reduction of DANT and/or DAHAT to triaminotoluene. Hydrogenase purified from Clostridium pasteurianum and carbon monoxide dehydrogenase partially purified from Clostridium thermoaceticum also catalyzed the reduction of DANT in the presence of methyl viologen or ferredoxin, however, as the main reduction product DAHAT rather than triaminotoluene was formed. The findings could explain the function of CO as an electron donor for the DANT reduction (to DAHAT) and the concomitant inhibitory effect of CO on triaminotoluene formation (from DAHAT) by the inhibition of sulfite reductase.(ABSTRACT TRUNCATED AT 250 WORDS)

  13. Effect of 800 keV argon ions pre-damage on the helium blister formation of tungsten exposed to 60 keV helium ions

    NASA Astrophysics Data System (ADS)

    Chen, Zhe; Han, Wenjia; Yu, Jiangang; Zhu, Kaigui

    2016-04-01

    This study aims to investigate the effect of Ar8+ ions pre-damage on the following He2+ irradiation behavior of polycrystalline tungsten. We compared the irradiation resistance performance against 60 keV He2+ ions of undamaged tungsten samples with that of pre-damaged samples which were preliminarily exposed to 800 keV Ar8+ ions at a fluence of 4 × 1019 ions m-2. The experimental results indicate that the helium blistering of tungsten could be effectively relieved by the Ar8+ ions pre-damage, while the retention of helium around low energy desorption sites in the pre-damaged tungsten was larger than that of the undamaged samples. A strong orientation dependence of blistering had been observed, with the blister occurred preferentially on the surface of grains with normal direction close to <111>. The Ar8+ ions irradiation-induced damage altered the morphology of helium bubbles in tungsten exposed to the following He2+ irradiation significantly. The intensity of helium release peaks at relatively low temperatures (<600 K) was enhanced due to Ar8+ ions pre-damage.

  14. Design of the Core 2-4 GHz Betatron Equalizer

    SciTech Connect

    Deibele, C.; /Fermilab

    2000-01-01

    The core betatron equalizer in the Accumulator in the Antiproton Source at Fermilab needed to be upgraded. The performance could be rated as only circa 650 MHz when the system was a 2 GHz system. The old equalizer did not correct for the strong phase mismatch for the relatively strong gain of the system slightly below 2 GHz. The design corrects this phase mismatch and is relatively well matched both in and out of band.

  15. Cross calibration of AGFA-D7 x-ray film against direct exposure film from 2 to 8.5 keV using laser generated x-rays

    SciTech Connect

    Kyrala, George A.

    2006-05-15

    Direct exposure film (DEF) is being discontinued. DEF film has been the workhorse in inertial confinement fusion (ICF) research and is used to record x-ray images and spectra. A previous search for a replacement [K. M. Chandler et al., Rev. Sci. Instrum. 76, 113111 (2005)] did not consider AGFA film. We present comparisons using the results of measurements using AGFA-D7 film, XAR, TMG, and Biomax-MS films in the same spectrometer recording a gold spectrum in the 2-4 keV range and the iron spectrum in the 5-8.5 keV range. AGFA film was found to have some unique properties useful in x-ray spectroscopy and imaging, especially when signal strength is not a concern.

  16. Cross calibration of AGFA-D7 x-ray film against direct exposure film from 2 to 8.5 keV using laser generated x-rays

    NASA Astrophysics Data System (ADS)

    Kyrala, George A.

    2006-05-01

    Direct exposure film (DEF) is being discontinued. DEF film has been the workhorse in inertial confinement fusion (ICF) research and is used to record x-ray images and spectra. A previous search for a replacement [K. M. Chandler et al., Rev. Sci. Instrum. 76, 113111 (2005)] did not consider AGFA film. We present comparisons using the results of measurements using AGFA-D7 film, XAR, TMG, and Biomax-MS films in the same spectrometer recording a gold spectrum in the 2-4keV range and the iron spectrum in the 5-8.5keV range. AGFA film was found to have some unique properties useful in x-ray spectroscopy and imaging, especially when signal strength is not a concern.

  17. A Compton camera for spectroscopic imaging from 100keV to 1MeV

    NASA Astrophysics Data System (ADS)

    Earnhart, Jonathan Raby Dewitt

    The objective of this work is to investigate Compton camera technology for spectroscopic imaging of gamma rays in the 100keV to 1MeV range. An efficient, specific purpose Monte Carlo code was developed to investigate the image formation process in Compton cameras. The code is based on a pathway sampling technique with extensive use of variance reduction techniques. The code includes detailed Compton scattering physics, including incoherent scattering functions, Doppler broadening, and multiple scattering. Experiments were performed with two different camera configurations for a scene containing a 75Se source and a 137Cs source. The first camera was based on a fixed silicon detector in the front plane and a CdZnTe detector mounted in the stage. The second camera configuration was based on two CdZnTe detectors. Both systems were able to reconstruct images of 75Se, using the 265keV line, and 137Cs, using the 662keV line. Only the silicon-CdZnTe camera was able to resolve the low intensity 400keV line of 75Se. Neither camera was able to reconstruct the 75Se source location using the 136keV line. The energy resolution of the silicon-CdZnTe camera system was 4% at 662keV. This camera reproduced the location of the 137Cs source by event circle image reconstruction with angular resolutions of 10° for a source on the camera axis and 14° for a source 30° off axis. Typical detector pair efficiencies were measured as 3 x 10-11 at 662keV. The dual CdZnTe camera had an energy resolution of 3.2% at 662keV. This camera reproduced the location of the 137Cs source by event circle image reconstruction with angular resolutions of 8° for a source on the camera axis and 12° for a source 20° off axis. Typical detector pair efficiencies were measured as 7 x 10-11 at 662keV. Of the two prototype camera configurations tested, the silicon-CdZnTe configuration had superior imaging characteristics. This configuration is less sensitive to effects caused by source decay cascades and random

  18. Close-packed Arrays of Transition-edge X-ray Microcalorimeters with High Spectral Resolution at 5.9 keV

    NASA Technical Reports Server (NTRS)

    Iyomoto, N.; Bandler, S. R.; Brekosky, R. P.; Brown, A.-D.; Chervenak, J. A.; Finkbeiner, F. M.; Kelley, R. L.; Kilbourne, C. A.; Porter, F. S.; Sadleir, J. E.; Smith, S. J.; Figueroa-Feliciano, E.

    2007-01-01

    We present measurements of high fill-factor arrays of superconducting transition-edge x-ray microcalorimeters designed to provide rapid thermalization of the x-ray energy. We designed an x-ray absorber that is cantilevered over the sensitive part of the thermometer itself, making contact only at normal metal-features. With absorbers made of electroplated gold, we have demonstrated an energy resolution between 2.4 and 3.1 eV at 5.9 keV on 13 separate pixels. We have determined the thermal and electrical parameters of the devices throughout the superconducting transition, and, using these parameters, have modeled all aspects of the detector performance.

  19. Close-packed arrays of transition-edge x-ray microcalorimeters with high spectral resolution at 5.9 keV

    SciTech Connect

    Iyomoto, N.; Bandler, S. R.; Brekosky, R. P.; Brown, A.-D.; Chervenak, J. A.; Finkbeiner, F. M.; Kelley, R. L.; Kilbourne, C. A.; Porter, F. S.; Sadleir, J. E.; Smith, S. J.; Figueroa-Feliciano, E.

    2008-01-07

    We present measurements of high fill-factor arrays of superconducting transition-edge x-ray microcalorimeters designed to provide rapid thermalization of the x-ray energy. We designed an x-ray absorber that is cantilevered over the sensitive part of the thermometer itself, making contact only at normal-metal features. With absorbers made of electroplated gold, we have demonstrated an energy resolution between 2.4 and 3.1 eV at 5.9 keV on 13 separate pixels. We have determined the thermal and electrical parameters of the devices throughout the superconducting transition and, using these parameters, have modeled all aspects of the detector performance.

  20. Iliotibial band friction syndrome

    PubMed Central

    2010-01-01

    Published articles on iliotibial band friction syndrome have been reviewed. These articles cover the epidemiology, etiology, anatomy, pathology, prevention, and treatment of the condition. This article describes (1) the various etiological models that have been proposed to explain iliotibial band friction syndrome; (2) some of the imaging methods, research studies, and clinical experiences that support or call into question these various models; (3) commonly proposed treatment methods for iliotibial band friction syndrome; and (4) the rationale behind these methods and the clinical outcome studies that support their efficacy. PMID:21063495

  1. Oxidative degradation of 2,4-xylidine by photosensitization with 2,4,6-triphenylpyrylium: homogeneous and heterogeneous catalysis.

    PubMed

    Amat, Ana M; Arques, Antonio; Bossmann, Stefan H; Braun, André M; Göb, Sabine; Miranda, Miguel A; Oliveros, Esther

    2004-12-01

    The possibility of using zeolites containing the 2,4,6-triphenylpyrylium cation as photocatalysts for the degradation of pollutants has been tested on aqueous xylidine (2,4-dimethylaniline) solutions as models for contaminated wastewaters. The influence of the photocatalyst and substrate concentrations on xylidine oxidation has been investigated in homogeneous solution, by performing a series of experiments chosen according to the experimental design methodology (Doehlert uniform array). The empirical models and the corresponding response surfaces obtained from data analysis have been used for simulating and predicting degradation efficiency. The results have shown that conversion increases with increasing amounts of photocatalyst and decreasing concentration of the model pollutant. The fluorescence of 2,4,6-triphenylpyrylium was quenched by xylidine with a rate constant k(q) of 3.1x10(9)M(-1)s(-1). This result suggests a direct electron transfer between the excited pyrylium salt and xylidine. Because of the limited stability of the photocatalyst in homogeneous media, a pyrylium containing Y-zeolite has been tested for the photocatalytic oxidation of xylidine under heterogeneous conditions. The results suggest that the supported catalyst has a much improved stability and that xylidine oxidation rates remain nearly constant during the whole reaction time. An additional advantage of the pyrylium containing zeolite photocatalyst is that it can be recycled and used for further experiments.

  2. Luminescent collisions of He+ and He++ ions with H2 molecules at energies below 2 keV

    NASA Astrophysics Data System (ADS)

    Pranszke, B.; Werbowy, S.; Miotk, R.; Borkowski, K. J.; Kowalski, A.

    2013-10-01

    Spectroscopic studies of collisions between He+ and He++ ions with H2 gas target have been performed in the 200-600 nm wavelength range. Atomic lines of hydrogen Balmer series and several helium lines were identified and their excitation functions between 50 eV and 1 keV (2 keV for He++) were determined.

  3. Superlattice Intermediate Band Solar Cell on Gallium Arsenide

    DTIC Science & Technology

    2015-02-09

    cell .................. 10  4.2.3  Effect of Sunlight Concentration (terrestrial applications) ..................................... 11  4.2.4...distribution is unlimited. 1 1 SUMMARY This work evaluates the viability of an intermediate band solar cell design, wherein a superlattice, comprising...AFRL-RV-PS- AFRL-RV-PS- TR-2015-0048 TR-2015-0048 SUPERLATTICE INTERMEDIATE BAND SOLAR CELL ON GALLIUM ARSENIDE Alexandre Freundlich

  4. Colliding the hydrocarbon building blocks of astrochemical polycyclic aromatic hydrocarbons with 8 keV He+* and H2+* ions: Luminescence from methane, acetylene, benzene and naphthalene

    NASA Astrophysics Data System (ADS)

    Rashid, Shaan; Sit, Alicia; West, Brandi; Mayer, Paul M.

    2017-01-01

    Emission spectra from collisions of 8 keV He+ and H2+rad with neutral naphthalene, benzene, acetylene and methane were acquired over 190-1020 nm on a modified double-focusing mass spectrometer. The bands, emission intensities and the minimum excitation energy to produce the observed transitions (Emin) were compared for the two projectile ions. Emin values were the same for both projectiles but the emission intensity is greater in the case of He+ . This is consistent with calculations at the CISD/6-311+G(2df) level on the excited states of the respective collision complexes which exhibited two distinct state-crossing points for He+ collisions but none for H2+rad collisions.

  5. DEGRADATION OF THE CHLORINATED PHENOXYACETATE HERBICIDES 2,4-DICHLOROPHENOXYACETIC ACID AND 2,4,5- TRICHLOROPHENOXYACETIC BY PURE AND MIXED BACTERIAL CULTURES

    EPA Science Inventory

    Combined cell suspensions of the 2,4,5-trichlorophenoxyacetic acid (2,4,5-T)-metabolizing organism Pseudomonas cepacia AC1100, and the 2,4-dichlorophenoxyacetic acid (2,4-D)-metabolizing organism Alcaligenes eutrophus JMP134 were shown to effectively degrade either of these compo...

  6. High order reflectivity of graphite (HOPG) crystals for x ray energies up to 22 keV

    SciTech Connect

    Doeppner, T; Neumayer, P; Girard, F; Kugland, N L; Landen, O L; Niemann, C; Glenzer, S H

    2008-04-30

    We used Kr K{alpha} (12.6 keV) and Ag K{alpha} (22.1 keV) x-rays, produced by petawatt class laser pulses interacting with a Kr gas jet and a silver foil, to measure the integrated crystal reflectivity of flat Highly Oriented Pyrolytic Graphite (HOPG) up to fifth order. The reflectivity in fourth order is lower by a factor of 50 when compared to first order diffraction. In second order the integrated reflectivity decreases from 1.3 mrad at 12.6 keV to 0.5 mrad at 22.1 keV. The current study indicates that HOPG crystals are suitable for measuring scattering signals from high energy x ray sources (E {ge} 20 keV). These energies are required to penetrate through the high density plasma conditions encountered in inertial confinement fusion capsule implosions on the National Ignition Facility.

  7. Linearizing W2,4 and WB2 algebras

    NASA Astrophysics Data System (ADS)

    Bellucci, S.; Krivonos, S.; Sorin, A.

    1995-02-01

    It has recently been shown that the W3 and W3(2) algebras can be considered as subalgebras in some linear conformal algebras. In this paper we show that the nonlinear algebras W2,4 and WB2 as well as Zamolodchikov's spin {5}/{2} superalgebra also can be embedded as subalgebras into some linear conformal algebras with a finite set of currents. These linear algebras give rise to new realizations of the nonlinear algebras which could be suitable in the construction of W-string theories.

  8. Magnetic clouds between 2-4 AU: Voyager observations

    NASA Technical Reports Server (NTRS)

    Burlaga, L. F.; Behannon, K. W.

    1981-01-01

    Magnetic clouds were observed in the solar wind between 2-4 AU. It was shown that they are stable enough to persist without major changes out to such distances. It is estimated that the clouds expand at a speed of the order of 45 km/s. The average Alfven speed at the front and rear boundaries is 104 km/s, the expansion speed is estimated to be nearly half of the Alfven speed, which is consistent with an earlier estimate of the expansion speed of clouds between the Sun and 1 AU. The magnetic field configuration is highly ordered and consistent with the passage of some kind of loop.

  9. Preparation of crosslinked 1,2,4-oxadiazole polymer

    NASA Technical Reports Server (NTRS)

    Rosser, R. W.; Shalhoub, I. M.; Kwong, H. (Inventor)

    1981-01-01

    New crosslinked 1,2,4-oxadiazole elastomers were prepared by thermally condensing a monomer having the formula H2N(HON)C-R-Q, wherein Q is a triazine ring-forming group such as nitrile or amidine or a mixture of such group with amidoxime, or a mixture of said monomer with R C(NOH)NH2 sub 2 with R in these formulas standing for a bivalent organic radical. In the monomer charge, the overall proportions of amidoxime groups to triazine ring-forming groups varies depending on the extent of crosslinking desired in the final polymer.

  10. Preparation of perfluorinated 1,2,4-oxadiazoles

    NASA Technical Reports Server (NTRS)

    Kratzer, R. H.; Paciorek, K. J. L.; Ito, T. I.; Rosser, R. W. (Inventor)

    1982-01-01

    Fluorinated alkyl or alkylether 1,2,4 oxadiazole compounds are prepared by cyclizing the corresponding alkyl or alkylether imidoyl amidoximes in vacuo or in an inert atmosphere at a temperature within the range of 40 C to 100 C. for a period of 8 to 144 hours in the presence of an acid compound which can accept ammonia to form a salt. The imidoyl amidoximes usable in this process are either polymeric or nonpolymeric. The products, when polymeric, have excellent heat, chemical and solvent resistance.

  11. Structure of 2,4-Diaminopyrimidine - Theobromine Alternate Base Pairs

    NASA Technical Reports Server (NTRS)

    Gengeliczki, Zsolt; Callahan, Michael P.; Kabelac, Martin; Rijs, Anouk M.; deVries, Mattanjah S.

    2011-01-01

    We report the structure of clusters of 2,4-diaminopyrimidine with 3,7-dimethylxanthine (theobromine) in the gas phase determined by IR-UV double resonance spectroscopy in both the near-IR and mid-IR regions in combination with ab initio computations. These clusters represent potential alternate nucleobase pairs, geometrically equivalent to guanine-cytosine. We have found the four lowest energy structures, which include the Watson-Crick base pairing motif. This Watson-Crick structure has not been observed by resonant two-photon ionization (R2PI) in the gas phase for the canonical DNA base pairs.

  12. Sonochemical Effect Using Ultrasonic Atomizer at 2.4 MHz

    NASA Astrophysics Data System (ADS)

    Shinashi, Kiyoaki; Houkin, Toshinori; Harada, Hisashi

    2012-07-01

    Sonochemical reactions were demonstrated using a commercial ultrasonic atomizer at 2.4 MHz. The influences of experimental conditions, bottom shape and glass thickness of reactors, irradiation method, and liquid height on the sonochemical yield were discussed. The sonochemical effect was evaluated by potassium iodide dosimetry and degradation of methylene blue. Direct and indirect irradiations were examined. The former had the highest yield. In the latter case, sonochemical yield decreased in the solution because glass prevented the transmission of ultrasonic waves. Poly film, on the other hand, could transmit ultrasonic waves very well without damage.

  13. CSF oligoclonal banding

    MedlinePlus

    ... system. Oligoclonal bands may be a sign of multiple sclerosis. How the Test is Performed A sample of ... Performed This test helps support the diagnosis of multiple sclerosis (MS). However, it does not confirm the diagnosis. ...

  14. Decay of superdeformed bands

    SciTech Connect

    Carpenter, M.P.; Khoo, T.L.; Lauritsen, T.

    1995-12-31

    One of the major challenges in the study of superdeformation is to directly connect the large number of superdeformed bands now known to the yrast states. In this way, excitation energies, spins and parities can be assigned to the levels in the second well which is essential to establish the collective and single-particle components of these bands. This paper will review some of the progress which has been made to understand the decay of superdeformed bands using the new arrays including the measurement of the total decay spectrum and the establishment of direct one-step decays from the superdeformed band to the yrast line in {sup 194}Hg. 42 refs., 5 figs.

  15. Study on the parameters of the scanning system for the 300 keV electron accelerator

    SciTech Connect

    Leo, K. W.; Chulan, R. M. Hashim, S. A.; Baijan, A. H.; Sabri, R. M.; Mohtar, M.; Glam, H.; Lojius, L.; Zahidee, M.; Azman, A.; Zaid, M.

    2016-01-22

    This paper describes the method to identify the magnetic coil parameters of the scanning system. This locally designed low energy electron accelerator with the present energy of 140 keV will be upgraded to 300 keV. In this accelerator, scanning system is required to deflect the energetic electron beam across a titanium foil in vertical and horizontal direction. The excitation current of the magnetic coil is determined by the energy of the electron beam. Therefore, the magnetic coil parameters must be identified to ensure the matching of the beam energy and excitation coil current. As the result, the essential parameters of the effective lengths for X-axis and Y-axis have been found as 0.1198 m and 0.1134 m and the required excitation coil currents which is dependenton the electron beam energies have be identified.

  16. Evaluation of 238U Resonance Parameters from 0 to 20 keV

    SciTech Connect

    Derrien, H.; Leal, L.C.; Larson, N.; Courcelle, A.; Santamarina, A.

    2005-05-24

    The neutron resonance parameters of 238U were obtained in the energy range 0 to 20 keV from a sequential SAMMY analysis of the most recent high-resolution neutron transmission and neutron capture cross-section measurements. Special care was taken in the analysis of the lowest s-wave resonances leading to resonance parameters slightly different from those of ENDF/B-VI (Moxon-Sowerby resonance parameters). The resolved-resonance range was extended to 20 keV, taking advantage of the high-resolution neutron transmission data of Harvey and neutron capture data of Macklin et al. Preliminary integral tests were performed with the new resonance parameters; thermal low-enriched benchmark calculations show an improvement of the keff prediction, mainly due to a 1.5% decrease of the capture cross section at 0.0253 eV and about a 0.4% decrease of the effective shielded resonance capture integral.

  17. Microbeam of 100 keV x ray with a sputtered-sliced Fresnel zone plate

    NASA Astrophysics Data System (ADS)

    Kamijo, Nagao; Suzuki, Yoshio; Takano, Hidekazu; Tamura, Shigeharu; Yasumoto, Masato; Takeuchi, Akihisa; Awaji, Mitsuhiro

    2003-12-01

    Microfocusing of 100 keV x ray with a sputtered-sliced Fresnel zone plate (ss-FZP) has been performed at the 250-m-long beamline (20XU) of SPring-8. The ss-FZP with an outermost zone width 0.16 μm which is composed of 70 layers of alternating Cu and Al layers and having thickness ˜180 μm was fabricated and characterized. The minimum focal spot size attained for the first order focal beam was 0.5 μm with a focal distance 900 mm at a photon energy 100 keV. The total flux of the microprobe was ˜2×106 photons s-1 μm-2.

  18. SMM detection of diffuse Galactic 511 keV annihilation radiation

    NASA Technical Reports Server (NTRS)

    Share, G. H.; Kinzer, R. L.; Kurfess, J. D.; Messina, D. C.; Purcell, W. R.

    1988-01-01

    Observations of the 511 keV annihilation line from the vicinity of the Galactic center from October to February for 1980/1981, 1981/1982, 1982/1983, 1984/1985, and 1985/1986 are presented. The measurements were made with the gamma-ray spectrometer on the SMM. The design of the instrument and some of its properties used in the analysis are described, and the methods used for accumulating, fitting, and analyzing the data are outlined. It is shown how the Galactic 511 keV line was separated from the intense and variable background observed in orbit. The SMM observations are compared with previous measurements of annihilation radiation from the Galactic center region, and the astrophysical implications are discussed. It is argued that most of the measurements made to date suggest the presence of an extended Galactic source of annihilation radiation.

  19. Tuning of wettability of PANI-GNP composites using keV energy ions

    NASA Astrophysics Data System (ADS)

    Lakshmi, G. B. V. S.; Avasthi, D. K.

    2016-07-01

    Polyaniline nanofiber composites with various nanomaterials have several applications in electrochemical biosensors. The surface properties of these composites coated electrodes play crucial role in enzyme absorption and analyte detection process. In the present study, Polyaniline-Graphene nanopowder (PANI-GNP) composites were prepared by rapid-mixing polymerization method. The films were prepared on ITO coated glass substrates and irradiated with 42 keV He+ ions produced by indigenously fabricated accelerator at IUAC, New Delhi. The films were characterized before and after irradiation by SEM, Raman spectroscopy and contact angle measurements. The as-prepared films show superhydrophilic nature and after irradiation the films show highly hydrophobic nature with water contact angle (135°). The surface morphology was studied by SEM and structural changes were studied by Raman spectra. The surface morphological modifications induced by keV energy ions helps in tuning the wettability at different ion fluences.

  20. The Morphology of the X-ray Emission above 2 keV from Jupiter's Aurorae

    NASA Technical Reports Server (NTRS)

    Elsner, R.; Branduardi-Raymont, G.; Galand, M.; Grodent, D.; Gladstone, G. R.; Waite, J. H.; Cravens, T.; Ford, P.

    2007-01-01

    The discovery in XMM-Newton X-ray data of X-ray emission above 2 keY from Jupiter's aurorae has led us to reexamine the Chandra ACIS-S observations taken in Feb 2003. Chandra's superior spatial resolution has revealed that the auroral X-rays with E > 2 keV are emitted from the periphery of the region emitting those with E < 1 keV. We are presently exploring the relationship of this morphology to that of the FUV emission from the main auroral oval and the polar cap. The low energy emission has previously been established as due to charge exchange between energetic precipitating ions of oxygen and either sulfur or carbon. It seems likely to us that the higher energy emission is due to precipitation of energetic electrons, possibly the same population of electrons responsible for the FUV emission. We discuss our analysis and interpretation.

  1. State-selective electron capture in 30- and 100-keV He++He collisions

    NASA Astrophysics Data System (ADS)

    Guo, D. L.; Ma, X.; Zhang, R. T.; Zhang, S. F.; Zhu, X. L.; Feng, W. T.; Gao, Y.; Hai, B.; Zhang, M.; Wang, H. B.; Huang, Z. K.

    2017-01-01

    A combined experimental and theoretical study on single capture in 30- and 100-keV He+ on He collisions was performed. By using a reaction microscope, we obtained the state selective cross sections and the angular-differential cross sections. It was found that the experimental state-selective cross sections were in good agreement with the dynamic screening classical trajectory Monte Carlo calculation for 100-keV He+ incident. The comparisons with various versions of such calculations reveal the roles played by different electron-electron correlation effects. Moreover, a prominent oscillatory structure was observed in the angular-differential cross sections for both projectile energies. With the single capture probability distribution obtained from the classical trajectory Monte Carlo calculation, the oscillation structures can be well explained by atomic-size Fraunhofer-type diffraction.

  2. Limits on a variable source of 511 keV annihilation radiation near the Galactic center

    NASA Technical Reports Server (NTRS)

    Share, Gerald H.; Leising, Mark D.; Messina, Daniel C.; Purcell, William R.

    1990-01-01

    The Gamma Ray Spectrometer (GRS) on the Solar Maximum Mission satellite (SMM) has observed a strong Galactic source of 511 keV annihilation radiation from its launch in 1980 to its reentry in 1989. These observations are consistent with an extended source having an intensity of about 0.002 gamma/sq cm/s averaged over the central radian of Galactic longitude. These data are searched for evidence of the variable Galactic center source of 511 keV line radiation which was reported to have reappeared in 1988 by Leventhal et al. The SMM data are consistent with, but do not require, a compact source emitting a time-averaged flux of about 0.0004 gamma/sq cm/s during about 3 month transits in 1987 and 1988; they are inconsistent with a compact source flux in excess of 0.0008 gamma/sq cm/s for each year.

  3. Polygonal deformation bands

    NASA Astrophysics Data System (ADS)

    Antonellini, Marco; Mollema, Pauline Nella

    2015-12-01

    We report for the first time the occurrence of polygonal faults in sandstone, which is compelling given that layer-bound polygonal fault systems have been observed so far only in fine-grained sediments such as clay and chalk. The polygonal faults are shear deformation bands that developed under shallow burial conditions via strain hardening in dm-wide zones. The edges of the polygons are 1-5 m long. The shear deformation bands are organized as conjugate faults along each edge of the polygon and form characteristic horst-like structures. The individual deformation bands have slip magnitudes ranging from a few mm to 1.5 cm; the cumulative average slip magnitude in a zone is up to 10 cm. The deformation bands heaves, in aggregate form, accommodate a small isotropic horizontal extension (strain <0.005). The individual shear deformation bands show abutting T-junctions, veering, curving, and merging where they mechanically interact. Crosscutting relationships are rare. The interactions of the deformation bands are similar to those of mode I opening fractures. The documented fault networks have important implications for evaluating the geometry of km-scale polygonal fault systems in the subsurface, top seal integrity, as well as constraining paleo-tectonic stress regimes.

  4. Hitomi Constraints on the 3.5 keV Line in the Perseus Galaxy Cluster

    NASA Astrophysics Data System (ADS)

    Aharonian, F. A.; Akamatsu, H.; Akimoto, F.; Allen, S. W.; Angelini, L.; Arnaud, K. A.; Audard, M.; Awaki, H.; Axelsson, M.; Bamba, A.; Bautz, M. W.; Blandford, R. D.; Bulbul, E.; Brenneman, L. W.; Brown, G. V.; Cackett, E. M.; Chernyakova, M.; Chiao, M. P.; Coppi, P.; Costantini, E.; de Plaa, J.; den Herder, J.-W.; Done, C.; Dotani, T.; Ebisawa, K.; Eckart, M. E.; Enoto, T.; Ezoe, Y.; Fabian, A. C.; Ferrigno, C.; Foster, A. R.; Fujimoto, R.; Fukazawa, Y.; Furuzawa, A.; Galeazzi, M.; Gallo, L. C.; Gandhi, P.; Giustini, M.; Goldwurm, A.; Gu, L.; Guainazzi, M.; Haba, Y.; Hagino, K.; Hamaguchi, K.; Harrus, I.; Hatsukade, I.; Hayashi, K.; Hayashi, T.; Hayashida, K.; Hiraga, J.; Hornschemeier, A. E.; Hoshino, A.; Hughes, J. P.; Ichinohe, Y.; Iizuka, R.; Inoue, H.; Inoue, S.; Inoue, Y.; Ishibashi, K.; Ishida, M.; Ishikawa, K.; Ishisaki, Y.; Itoh, M.; Iwai, M.; Iyomoto, N.; Kaastra, J. S.; Kallman, T.; Kamae, T.; Kara, E.; Kataoka, J.; Katsuda, S.; Katsuta, J.; Kawaharada, M.; Kawai, N.; Kelley, R. L.; Khangulyan, D.; Kilbourne, C. A.; King, A. L.; Kitaguchi, T.; Kitamoto, S.; Kitayama, T.; Kohmura, T.; Kokubun, M.; Koyama, S.; Koyama, K.; Kretschmar, P.; Krimm, H. A.; Kubota, A.; Kunieda, H.; Laurent, P.; Lebrun, F.; Lee, S.-H.; Leutenegger, M. A.; Limousin, O.; Loewenstein, M.; Long, K. S.; Lumb, D. H.; Madejski, G. M.; Maeda, Y.; Maier, D.; Makishima, K.; Markevitch, M.; Matsumoto, H.; Matsushita, K.; McCammon, D.; McNamara, B. R.; Mehdipour, M.; Miller, E. D.; Miller, J. M.; Mineshige, S.; Mitsuda, K.; Mitsuishi, I.; Miyazawa, T.; Mizuno, T.; Mori, H.; Mori, K.; Moseley, H.; Mukai, K.; Murakami, H.; Murakami, T.; Mushotzky, R. F.; Nakagawa, T.; Nakajima, H.; Nakamori, T.; Nakano, T.; Nakashima, S.; Nakazawa, K.; Nobukawa, K.; Nobukawa, M.; Noda, H.; Nomachi, M.; O’ Dell, S. L.; Odaka, H.; Ohashi, T.; Ohno, M.; Okajima, T.; Ota, N.; Ozaki, M.; Paerels, F.; Paltani, S.; Parmar, A.; Petre, R.; Pinto, C.; Pohl, M.; Porter, F. S.; Pottschmidt, K.; Ramsey, B. D.; Reynolds, C. S.; Russell, H. R.; Safi-Harb, S.; Saito, S.; Sakai, K.; Sameshima, H.; Sasaki, T.; Sato, G.; Sato, K.; Sato, R.; Sawada, M.; Schartel, N.; Serlemitsos, P. J.; Seta, H.; Shidatsu, M.; Simionescu, A.; Smith, R. K.; Soong, Y.; Stawarz, Ł.; Sugawara, Y.; Sugita, S.; Szymkowiak, A. E.; Tajima, H.; Takahashi, H.; Takahashi, T.; Takeda, S.; Takei, Y.; Tamagawa, T.; Tamura, K.; Tamura, T.; Tanaka, T.; Tanaka, Yasuo; Tanaka, Yasuyuki; Tashiro, M.; Tawara, Y.; Terada, Y.; Terashima, Y.; Tombesi, F.; Tomida, H.; Tsuboi, Y.; Tsujimoto, M.; Tsunemi, H.; Tsuru, T.; Uchida, H.; Uchiyama, H.; Uchiyama, Y.; Ueda, S.; Ueda, Y.; Ueno, S.; Uno, S.; Urry, C. M.; Ursino, E.; de Vries, C. P.; Watanabe, S.; Werner, N.; Wik, D. R.; Wilkins, D. R.; Williams, B. J.; Yamada, S.; Yamaguchi, H.; Yamaoka, K.; Yamasaki, N. Y.; Yamauchi, M.; Yamauchi, S.; Yaqoob, T.; Yatsu, Y.; Yonetoku, D.; Yoshida, A.; Zhuravleva, I.; Zoghbi, A.; Hitomi Collaboration

    2017-03-01

    High-resolution X-ray spectroscopy with Hitomi was expected to resolve the origin of the faint unidentified E≈ 3.5 {keV} emission line reported in several low-resolution studies of various massive systems, such as galaxies and clusters, including the Perseus cluster. We have analyzed the Hitomi first-light observation of the Perseus cluster. The emission line expected for Perseus based on the XMM-Newton signal from the large cluster sample under the dark matter decay scenario is too faint to be detectable in the Hitomi data. However, the previously reported 3.5 keV flux from Perseus was anomalously high compared to the sample-based prediction. We find no unidentified line at the reported high flux level. Taking into account the XMM measurement uncertainties for this region, the inconsistency with Hitomi is at a 99% significance for a broad dark matter line and at 99.7% for a narrow line from the gas. We do not find anomalously high fluxes of the nearby faint K line or the Ar satellite line that were proposed as explanations for the earlier 3.5 keV detections. We do find a hint of a broad excess near the energies of high-n transitions of S xvi (E≃ 3.44 {keV} rest-frame)—a possible signature of charge exchange in the molecular nebula and another proposed explanation for the unidentified line. While its energy is consistent with XMM pn detections, it is unlikely to explain the MOS signal. A confirmation of this interesting feature has to wait for a more sensitive observation with a future calorimeter experiment.

  5. Compton polarimeter for 10-30 keV x rays

    NASA Astrophysics Data System (ADS)

    Weber, S.; Beilmann, C.; Shah, C.; Tashenov, S.

    2015-09-01

    We present a simple and versatile polarimeter for x rays in the energy range of 10-30 keV. It uses Compton scattering in low-Z materials such as beryllium or boron carbide. The azimuthal distribution of the scattered x rays is sampled by an array of 12 silicon PIN diodes operated at room temperature. We evaluated the polarimetry performance using Monte-Carlo simulations and show experimental results.

  6. The 511 keV emission from positron annihilation in the Galaxy

    SciTech Connect

    Prantzos, N.; Boehm, C.; Bykov, A. M.; Diehl, R.; Ferriere, K.; Guessoum, N.; Jean, P.; Knoedlseder, J.; Marcowith, A.; Moskalenko, I. V.; Strong, A.; Weidenspointner, G.

    2011-07-01

    The first {gamma}-ray line originating from outside the Solar System that was ever detected is the 511 keV emission from positron annihilation in the Galaxy. Despite 30 years of intense theoretical and observational investigation, the main sources of positrons have not been identified up to now. Observations in the 1990s with OSSE/CGRO (Oriented Scintillation Spectrometer Experiment on GRO satellite/Compton Gamma Ray Observatory) showed that the emission is strongly concentrated toward the Galactic bulge. In the 2000s, the spectrometer SPI aboard the European Space Agency's (ESA) International Gamma Ray Astrophysics Laboratory (INTEGRAL) allowed scientists to measure that emission across the entire Galaxy, revealing that the bulge-to-disk luminosity ratio is larger than observed at any other wavelength. This mapping prompted a number of novel explanations, including rather ''exotic'' ones (e.g., dark matter annihilation). However, conventional astrophysical sources, such as type Ia supernovae, microquasars, or x-ray binaries, are still plausible candidates for a large fraction of the observed total 511 keV emission of the bulge. A closer study of the subject reveals new layers of complexity, since positrons may propagate far away from their production sites, making it difficult to infer the underlying source distribution from the observed map of 511 keV emission. However, in contrast to the rather well-understood propagation of high-energy (>GeV) particles of Galactic cosmic rays, understanding the propagation of low-energy ({approx}MeV) positrons in the turbulent, magnetized interstellar medium still remains a formidable challenge. The spectral and imaging properties of the observed 511 keV emission are reviewed and candidate positron sources and models of positron propagation in the Galaxy are critically discussed.

  7. Compton polarimeter for 10–30 keV x rays

    SciTech Connect

    Weber, S.; Beilmann, C.; Shah, C.; Tashenov, S.

    2015-09-15

    We present a simple and versatile polarimeter for x rays in the energy range of 10–30 keV. It uses Compton scattering in low-Z materials such as beryllium or boron carbide. The azimuthal distribution of the scattered x rays is sampled by an array of 12 silicon PIN diodes operated at room temperature. We evaluated the polarimetry performance using Monte-Carlo simulations and show experimental results.

  8. Origin of the Galactic Disk 6.7 kev Line Emission

    NASA Technical Reports Server (NTRS)

    Churchwell, Ed

    1997-01-01

    The goal of this program was to determine if the extended FeXXV 6.7 kev line emission might possibly be produced and confined by the hot wind-shocked bubbles to accompany UC HII regions. The main result of this study are: (1) FeXXV is detected in the W3 complex, but at a level that could only explain a small fraction of the galactic disk emission if all UC HII regions emit at about the same intensity as the W3 complex; (2) Two X-ray sources are detected in W3. W3-X 1 coincides with the radio image of this region, but W3-X2 has no radio, optical, or infrared counterpart; (3) There is no evidence for variability of W3-X1 during the period of observations (approx, 40,000 sec); (4) The X-ray spectrum of W3-X1 has no emission shortward of 1 kev, it peaks at approx. 2 kev and show significant emission out to approx. 6 kev. No individual lines are resolved. There is currently no generally accepted theory for extended hard X-ray emission in HII regions. Perhaps the most significant discovery of this program has been the detection of extended hard X-rays and the realization that some entirely new processes must be invoked to understand this; and (5)A minimum (chi)(sup 2) fit of the spectrum implies a H absorbing column of N(sub H) approx, equals to 2.1 x 10(exp 22)/ cm, a temperature of the emitting plasma of 7 x 10(exp 7) K, and a luminosity of approx. equal to 10(33)erg/s.

  9. The 93Zr(n,γ) reaction up to 8 keV neutron energy

    NASA Astrophysics Data System (ADS)

    Tagliente, G.; Milazzo, P. M.; Fujii, K.; Abbondanno, U.; Aerts, G.; Álvarez, H.; Alvarez-Velarde, F.; Andriamonje, S.; Andrzejewski, J.; Audouin, L.; Badurek, G.; Baumann, P.; Bečvář, F.; Belloni, F.; Berthoumieux, E.; Calviño, F.; Calviani, M.; Cano-Ott, D.; Capote, R.; Carrapiço, C.; Cennini, P.; Chepel, V.; Chiaveri, E.; Colonna, N.; Cortes, G.; Couture, A.; Dahlfors, M.; David, S.; Dillmann, I.; Domingo-Pardo, C.; Dridi, W.; Duran, I.; Eleftheriadis, C.; Embid-Segura, M.; Ferrari, A.; Ferreira-Marques, R.; Furman, W.; Goncalves, I.; Gonzalez-Romero, E.; Gramegna, F.; Guerrero, C.; Gunsing, F.; Haas, B.; Haight, R.; Heil, M.; Herrera-Martinez, A.; Jericha, E.; Käppeler, F.; Kadi, Y.; Karadimos, D.; Karamanis, D.; Kerveno, M.; Kossionides, E.; Krtička, M.; Lamboudis, C.; Leeb, H.; Lindote, A.; Lopes, I.; Lukic, S.; Marganiec, J.; Marrone, S.; Martínez, T.; Massimi, C.; Mastinu, P.; Mengoni, A.; Moreau, C.; Mosconi, M.; Neves, F.; Oberhummer, H.; O'Brien, S.; Papachristodoulou, C.; Papadopoulos, C.; Paradela, C.; Patronis, N.; Pavlik, A.; Pavlopoulos, P.; Perrot, L.; Pigni, M. T.; Plag, R.; Plompen, A.; Plukis, A.; Poch, A.; Praena, J.; Pretel, C.; Quesada, J.; Reifarth, R.; Rosetti, M.; Rubbia, C.; Rudolf, G.; Rullhusen, P.; Salgado, J.; Santos, C.; Sarchiapone, L.; Savvidis, I.; Stephan, C.; Tain, J. L.; Tassan-Got, L.; Tavora, L.; Terlizzi, R.; Vannini, G.; Vaz, P.; Ventura, A.; Villamarin, D.; Vincente, M. C.; Vlachoudis, V.; Vlastou, R.; Voss, F.; Walter, S.; Wiescher, M.; Wisshak, K.

    2013-01-01

    The (n,γ) reaction of the radioactive isotope 93Zr has been measured at the n_TOF high-resolution time-of-flight facility at CERN. Resonance parameters have been extracted in the neutron energy range up to 8 keV, yielding capture widths smaller (14%) than reported in an earlier experiment. These results are important for detailed nucleosynthesis calculations and for refined studies of waste transmutation concepts.

  10. Gamma ray interaction studies of organic nonlinear optical materials in the energy range 122 keV-1330 keV

    NASA Astrophysics Data System (ADS)

    Awasarmol, V. V.; Gaikwad, D. K.; Raut, S. D.; Pawar, P. P.

    The mass attenuation coefficients (μm) for organic nonlinear optical materials measured at 122-1330 keV photon energies were investigated on the basis of mixture rule and compared with obtained values of WinXCOM program. It is observed that there is a good agreement between theoretical and experimental values of the samples. All samples were irradiated with six radioactive sources such as 57Co, 133Ba, 22Na, 137Cs, 54Mn and 60Co using transmission arrangement. Effective atomic and electron numbers or electron densities (Zeff and Neff), molar extinction coefficient (ε), mass energy absorption coefficient (μen/ρ) and effective atomic energy absorption cross section (σa,en) were determined experimentally and theoretically using the obtained μm values for investigated samples and graphs have been plotted. The graph shows that the variation of all samples decreases with increasing photon energy.

  11. Relative detection efficiency of back- and front-illuminated charge-coupled device cameras for X-rays between 1 keV and 18 keV.

    PubMed

    Szlachetko, J; Dousse, J-Cl; Hoszowska, J; Berset, M; Cao, W; Szlachetko, M; Kavcic, M

    2007-09-01

    High-resolution x-ray measurements were performed with a von Hamos-type bent crystal spectrometer using for the detection of the diffracted photons either a back-illuminated charge-coupled device (CCD) camera or a front-illuminated one. For each CCD the main x-ray emission lines (e.g., Kalpha, Kbeta, Lalpha, and Lbeta) of a variety of elements were measured in order to probe the performances of the two detectors between 1 and 18 keV. From the observed x-ray lines the linearity of the energy response, the noise level, the energy resolution, and the quantum efficiency ratio of the two CCDs were determined.

  12. Kinetic Batch Soil Adsorption Studies of 2, 4-dinitroanisole (DNAN)

    NASA Astrophysics Data System (ADS)

    Arthur, J.; Mark, N. W.; Taylor, S.; Brusseau, M. L.; Dontsova, K.

    2014-12-01

    Currently the explosive 2, 4, 6- trinitrotoluene (TNT) is used as a main ingredient in munitions; however the compound has failed to meet sensitivity requirements. The replacement compound being tested is 2, 4-dinitroanisole (DNAN). DNAN is less sensitive to shock, high temperatures, and has good detonation characteristics. However, DNAN is more soluble than TNT, which can influence transport and fate behavior and thus bioavailability and exposure potential. DNAN has been shown to have some human and environmental toxicity. The objective of this study was to investigate the environmental fate of DNAN in soil, with a specific focus on sorption processes. Batch experiments were conducted using 11 soils collected from military installations located across the United States. The soils were characterized for pH, specific surface area, electrical conductivity, cation exchange capacity, and organic carbon content. Adsorption kinetic data determined at room temperature were fitted using the first order kinetic equation. Adsorption isotherms were fitted with linear and Freundlich isotherm equations. The magnitudes of the linear adsorption coefficients ranged from 0.6 to 6 cm3/g. Results indicated that the adsorption of DNAN is strongly dependent on the amount of organic carbon present in the soil.

  13. Testing the Axion-Conversion Hypothesis of 3.5 keV Emission with Polarization

    NASA Astrophysics Data System (ADS)

    Gong, Yan; Chen, Xuelei; Feng, Hua

    2017-02-01

    The recently measured 3.5 keV line in a number of galaxy clusters, the Andromeda galaxy (M31), and the Milky Way (MW) center can be well accounted for by a scenario in which dark matter decays to axionlike particles (ALPs) and subsequently convert to 3.5 keV photons in magnetic fields of galaxy clusters or galaxies. We propose to test this hypothesis by performing x-ray polarization measurements. Since ALPs can only couple to photons with a polarization orientation parallel to the magnetic field, we can confirm or reject this model by measuring the polarization of the 3.5 keV line and compare it to the orientation of the magnetic field. We discuss luminosity and polarization measurements for both a galaxy cluster and spiral galaxy, and provide a general relation between the polarization and galaxy inclination angle. This effect is marginally detectable with x-ray polarimetry detectors currently under development, such as the enhanced X-ray Timing and Polarization satellite, the Imaging X-ray Polarimetry Explorer and the X-ray Imaging Polarimetry Explorer. The sensitivity can be further improved in the future with detectors of a larger effective area or better energy resolutions.

  14. A study of 2-20 KeV X-rays from the Cygnus region

    NASA Technical Reports Server (NTRS)

    Bleach, R. D.

    1972-01-01

    Two rocket-borne proportional counters, each with 650 sq c, met area and 1.8 x 7.1 deg FWHM rectangular mechanical collimation, surveyed the Cygnus region in the 2 to 20 keV energy range on two occasions. X-ray spectral data gathered on 21 September 1970 from discrete sources in Cygnus are presented. The data from Cyg X-1, Cyg X-2, and Cyg X-3 have sufficient statistical significance to indicate mutually exclusive spectral forms for the three. Upper limits are presented for X-ray intensities above 2 keV for Cyg X-4 and Cyg X-5 (Cygnus loop). A search was made on 9 August 1971 for a diffuse component of X-rays 1.5 keV associated with an interarm region of the galaxy at galactic longitudes in the vicinity of 60 degrees. A statistically significant excess associated with a narrow disk component was detected. Several possible emission models are discussed, with the most likely candidate being a population of unresolvable low luminosity discrete sources.

  15. Mutagenic effect of a keV range N + beam on mammalian cells

    NASA Astrophysics Data System (ADS)

    Feng, Huiyun; Wu, Lijun; Yu, Lixiang; Han, Wei; Liu, Xuelan; Yu, Zengliang

    2005-07-01

    The radiobiological effects of a keV (5-20 keV) range nitrogen ion (N +) beam on mammalian cells were studied, particularly with regard to the induction of mutation in the cell genome. The experiment demonstrated that the 20 keV N + beam, which resulted in cell death to a certain extent, induced a 2-3 fold increase in the mutation rates at the CD59 gene locus of the mammalian A L cells as compared to the control. Within certain fluence ranges (0-6 × 10 14 N +/cm 2), the cell survival displayed a down-up-down pattern which is similar to the phenomenon known as 'hyper-radiosensitivity' manifested under low-dose irradiation; the CD59 mutation rate firstly showed a gradual rise up to a 3-fold increment above the background level as the ion fluence went up to 4 × 10 14 N +/cm 2, after this peak point however, a downtrend appeared though the ion fluence increased further. It was also observed that the fraction of CD59 mutation bears no proportional relation to ion energy in further experiments of mutation induction by N + beams with the incident energies of 5, 10, 15 and 20 keV at the same fluence of 3 × 10 14 N +/cm 2. Analyses of the deletion patterns of chromosome 11 in CD59- mutants induced by 5-20 keV N + beams showed that these ions did not result in large-size chromosome deletions in this mammalian cell system. A preliminary discussion, suggesting that the mutagenic effect of such low-energy ion influx on mammalian cells could result from multiple processes involving direct collision of particles with cellular DNA, and cascade atomic and molecular reactions due to plentiful primary and secondary particles, was also presented. The study provided the first glimpse into the roles low-energy ions may play in inducing mutagenesis in mammalian cells, and results will be of much value in helping people to understand the contribution of low-energy ions to radiological effects of various ionising radiations.

  16. 47 CFR 25.213 - Inter-Service coordination requirements for the 1.6/2.4 GHz mobile-satellite service.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... radio astronomy service in the 1610.6-1613.8 MHz band against interference from 1.6/2.4 GHz Mobile... System. During periods of radio astronomy observations, land mobile earth stations shall not operate when... astronomy sites: Observatory Latitude (DMS) Longitude (DMS) Arecibo, PR 18 20 46 66 45 11 Green...

  17. 47 CFR 25.213 - Inter-Service coordination requirements for the 1.6/2.4 GHz mobile-satellite service.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... radio astronomy service in the 1610.6-1613.8 MHz band against interference from 1.6/2.4 GHz Mobile... System. During periods of radio astronomy observations, land mobile earth stations shall not operate when... astronomy sites: Observatory Latitude (DMS) Longitude (DMS) Arecibo, PR 18 20 46 66 45 11 Green...

  18. 47 CFR 25.213 - Inter-Service coordination requirements for the 1.6/2.4 GHz mobile-satellite service.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... radio astronomy service in the 1610.6-1613.8 MHz band against interference from 1.6/2.4 GHz Mobile... System. During periods of radio astronomy observations, land mobile earth stations shall not operate when... astronomy sites: Observatory Latitude (DMS) Longitude (DMS) Arecibo, PR 18 20 46 66 45 11 Green...

  19. Influence of 400 keV carbon ion implantation on structural, optical and electrical properties of PMMA

    NASA Astrophysics Data System (ADS)

    Arif, Shafaq; Rafique, M. Shahid; Saleemi, Farhat; Sagheer, Riffat; Naab, Fabian; Toader, Ovidiu; Mahmood, Arshad; Rashid, Rashad; Mahmood, Mazhar

    2015-09-01

    Ion implantation is a useful technique to modify surface properties of polymers without altering their bulk properties. The objective of this work is to explore the 400 keV C+ ion implantation effects on PMMA at different fluences ranging from 5 × 1013 to 5 × 1015 ions/cm2. The surface topographical examination of irradiated samples has been performed using Atomic Force Microscope (AFM). The structural and chemical modifications in implanted PMMA are examined by Raman and Fourier Infrared Spectroscopy (FTIR) respectively. The effects of carbon ion implantation on optical properties of PMMA are investigated by UV-Visible spectroscopy. The modifications in electrical conductivity have been measured using a four point probe technique. AFM images reveal a decrease in surface roughness of PMMA with an increase in ion fluence from 5 × 1014 to 5 × 1015 ions/cm2. The existence of amorphization and sp2-carbon clusterization has been confirmed by Raman and FTIR spectroscopic analysis. The UV-Visible data shows a prominent red shift in absorption edge as a function of ion fluence. This shift displays a continuous reduction in optical band gap (from 3.13 to 0.66 eV) due to formation of carbon clusters. Moreover, size of carbon clusters and photoconductivity are found to increase with increasing ion fluence. The ion-induced carbonaceous clusters are believed to be responsible for an increase in electrical conductivity of PMMA from (2.14 ± 0.06) × 10-10 (Ω-cm)-1 (pristine) to (0.32 ± 0.01) × 10-5 (Ω-cm)-1 (irradiated sample).

  20. Experimental study of {Delta}I=1 bands in {sup 111}In

    SciTech Connect

    Banerjee, P.; Pradhan, M. K.; Ganguly, S.; Sharma, H. P.; Muralithar, S.; Singh, R. P.; Bhowmik, R. K.

    2011-02-15

    The two {Delta}I=1 bands in {sup 111}In, built upon the 3461.0 and 4931.8 keV states, have been studied. The bands were populated in the reaction {sup 100}Mo({sup 19}F, {alpha}4n{gamma}) at a beam energy of 105 MeV. Mean lifetimes of nine states, four in the first and five in the second band, have been determined for the first time from Doppler shift attenuation data. The deduced B(M1) rates and their behavior as a function of level spin support the interpretation of these bands within the framework of the shears mechanism. The geometrical model of Machiavelli et al. has been used to derive the effective gyromagnetic ratios for the two bands.

  1. Aerobic biotransformation and mineralization of 2,4,6-trinitrotoluene

    SciTech Connect

    Bae, B.H.; Autenrieth, R.L.; Bonner, J.S.

    1995-12-31

    Respirometric mineralization studies of 2,4,6-trinitrotoluene (TNT) were conducted with microorganisms isolated from a site contaminated with munitions waste in Illinois. Nine aerobic bacterial species were isolated under a carbon- and nitrogen-limited condition and tentatively identified as: one Pseudomonas species; one Enterobacter species; and seven Alcaligenes species. Experiments were performed using each of the nine organisms individually and with a consortium of all nine bacterial species. The aerobic microorganisms were cultured in a sterile nutrient solution with glucose and 20 mg/L TNT. Mineralization was determined using uniformly ring-labeled {sup 14}C-TNT in a respirometer that trapped the evolved CO{sub 2}. Biodegradation behavior was characterized based on oxygen consumption, distribution of {sup 14}C activity, and high-performance liquid chromatography (HPLC) analysis of TNT and its transformation products.

  2. The 1,2,4-oxadiazole elastomers. [heat resistant polymers

    NASA Technical Reports Server (NTRS)

    Rosser, R. W.; Shalhoub, I. M.; Kwong, H. (Inventor)

    1981-01-01

    Crosslinked 1,2,4-oxadiazole elastomers were prepared either by thermally condensing a monomer having the formula HwN(HON)C-R-Q, wherein Q is a triazine ring forming group such as nitrile or amidine, or by a mixture of said monomer with RC(NOH)NH22, with R in these formulas standing for a bivalent organic radical containing fluorine, hydrogen, or trifluoromethyl. In the monomer charge, the overall proportions of amidoxime groups to triazine ring forming groups varies depending on the extent of crosslinking desired in the final polymer. The heat and chemical resistant elastomers disclosed can serve, for instance, as adhesives, caulking compounds, channel sealants, fuel tank liners.

  3. Computation of affinity and selectivity: Binding of 2,4-diaminopteridine and 2,4-diaminoquinazoline inhibitors to dihydrofolate reductases

    NASA Astrophysics Data System (ADS)

    Marelius, John; Graffner-Nordberg, Malin; Hansson, Tomas; Hallberg, Anders; Åqvist, Johan

    1998-03-01

    Binding energy calculations for complexes of mutant and wild-type human dihydrofolate reductases with 2,4-diaminopteridine and 2,4-diaminoquinazoline inhibitors are reported. Quantitative insight into binding energetics of these molecules is obtained from calculations based on force field energy evaluation and thermal sampling by molecular dynamics simulations. The calculated affinity of methotrexate for wild-type and mutant enzymes is reasonably well reproduced. Truncation of the methotrexate glutamate tail results in a loss of affinity by several orders of magnitude. No major difference in binding strength is predicted between the pteridines and the quinazolines, while the N-methyl group present in methotrexate appears to confer significantly stronger binding. The recent improvement, which is used here, of our linear interaction energy method for binding affinity prediction, as well as problems with treating charged and flexible ligands are discussed. This approach should be suitable in a drug discovery context for prediction of binding energies of new inhibitors prior to their synthesis, when some information about the binding mode is available.

  4. Anharmonicity of the excited octupole band in actinides using supersymmetric quantum mechanics

    NASA Astrophysics Data System (ADS)

    Jolos, R. V.; von Brentano, P.; Casten, R. F.

    2013-09-01

    Background: Low-lying octupole collective excitations play an important role in the description of the structure of nuclei in the actinide region. Ground state alternating parity rotational bands combining both positive and negative parity states are known in several nuclei. However, only recently it has been discovered in 240Pu an excited positive parity rotational band having an octupole nature and demonstrating strong anharmonicity of the octupole motion in the band head energies.Purpose: To suggest a model describing both ground state and excited alternating parity bands, which includes a description of the anharmonic effects in the bandhead excitation energies and can be used to predict the energies of the excited rotational bands of octupole nature and the E1 transition probabilities.Methods: The mathematical technique of the supersymmetric quantum mechanics with a collective Hamiltonian depending only on the octupole collective variable which keeps axial symmetry is used to describe the ground state and excited alternating parity rotational bands.Results: The excitation energies of the states belonging to the lowest negative parity and the excited positive parity bands are calculated for 232Th, 238U, and 240Pu. The E1 transition matrix elements are also calculated for 240Pu.Conclusions: It is shown that the suggested model describes the excitation energies of the states of the lowest negative parity band with the accuracy around 10 keV. The anharmonicity in the bandhead energy of the excited positive parity band is described also. The bandhead energy of the excited positive parity band is described with the accuracy around 100 keV.

  5. A balanced wide-band amplifier for microwave applications

    NASA Astrophysics Data System (ADS)

    Panzariu, Mircea; Lupescu, Horia; Dumitrascu, Ana; Tamas, Razvan D.

    2015-02-01

    Due to its better performance, high fiability and large power capability, balanced amplifier is one of the most popular designs used in narrow band applications. However, with a balanced amplifier in class A operation, the band-pass is still narrow with classical coupler [1]. In this paper, we propose a new method for widen the band-pass and linearity of the amplifier, by using two Lange couplers and by adding two drivers, so that small signal could be amplified [2], [3], [4], [5]. The proposed amplifier works in the 0.9 - 2.4 GHz band, with good performances. We also propose an A class X-band amplifier, with Wilkinson power divider used as a combiner and divider. The amplifier will operate at 9,5 GHz with Continuous Wave (C.W). The two methods were validated by simulating the balanced amplifier with Lange coupler and the balanced amplifier with Wilkinson power divider, in class A operation.

  6. Decay-out of 151Tb Yrast Superdeformed Band and Shape Coexistence

    SciTech Connect

    Duchene, G.; Robin, J.; Odahara, A.; Byrski, Th.; Beck, F.A.; Bednarczyk, P.; Curien, D.; Courtin, S.; Dorvaux, O.; Gall, B.; Joshi, P.; Nourreddine, A.; Pachoud, E.; Piqueras, I.; Vivien, J.P.; Twin, P.J.; Cullen, D.M.; Ertueck, S.; King, S.L.; Paul, E.S.

    2004-02-27

    Linking transitions between the superdeformed (SD) and the normal deformed (ND) wells have been searched in 151Tb nucleus. Two experiments of 5 and 17 days have been performed with EUROBALL IV. Transitions of 2818 keV and 3748 keV with intensities of about 1 % relative to the yrast SD band have been observed. Their decay-out properties are discussed in the text. In addition the eight known SD bands have been extended towards higher rotational frequencies where orbital crossings are observed. For the first time, weakly populated collective ND structures, likely triaxial, similar to the ones recently identified in 152Dy, 153Ho and 155Er nuclei have been observed in 151Tb. The SD and ND structures are interpreted in the frame of Woods-Saxon theoretical calculations.

  7. 77 FR 29236 - Unlicensed Operation in the TV Broadcast Band

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-05-17

    ...). Protection of Radio Astronomy 39. Section 15.712(h) of the rules prohibits the operation of TV bands devices within 2.4 kilometers of certain radio astronomy and other receive sites to prevent interference to...) in 2005. NTIA recently discovered inaccuracies in the coordinates for several radio astronomy...

  8. Banded transformer cores

    NASA Technical Reports Server (NTRS)

    Mclyman, C. W. T. (Inventor)

    1974-01-01

    A banded transformer core formed by positioning a pair of mated, similar core halves on a supporting pedestal. The core halves are encircled with a strap, selectively applying tension whereby a compressive force is applied to the core edge for reducing the innate air gap. A dc magnetic field is employed in supporting the core halves during initial phases of the banding operation, while an ac magnetic field subsequently is employed for detecting dimension changes occurring in the air gaps as tension is applied to the strap.

  9. A comparative study of inelastic scattering models at energy levels ranging from 0.5 keV to 10 keV

    NASA Astrophysics Data System (ADS)

    Hu, Chia-Yu; Lin, Chun-Hung

    2017-03-01

    Six models, including a single-scattering model, four hybrid models, and one dielectric function model, were evaluated using Monte Carlo simulations for aluminum and copper at incident beam energies ranging from 0.5 keV to 10 keV. The inelastic mean free path, mean energy loss per unit path length, and backscattering coefficients obtained by these models are compared and discussed to understand the merits of the various models. ANOVA (analysis of variance) statistical models were used to quantify the effects of inelastic cross section and energy loss models on the basis of the simulated results deviation from the experimental data for the inelastic mean free path, the mean energy loss per unit path length, and the backscattering coefficient, as well as their correlations. This work in this study is believed to be the first application of ANOVA models towards evaluating inelastic electron beam scattering models. This approach is an improvement over the traditional approach which involves only visual estimation of the difference between the experimental data and simulated results. The data suggests that the optimization of the effective electron number per atom, binding energy, and cut-off energy of an inelastic model for different materials at different beam energies is more important than the selection of inelastic models for Monte Carlo electron scattering simulation. During the simulations, parameters in the equations should be tuned according to different materials for different beam energies rather than merely employing default parameters for an arbitrary material. Energy loss models and cross-section formulas are not the main factors influencing energy loss. Comparison of the deviation of the simulated results from the experimental data shows a significant correlation (p < 0.05) between the backscattering coefficient and energy loss per unit path length. The inclusion of backscattering electrons generated by both primary and secondary electrons for

  10. Observation of the single step links of the yrast superdeformed band in {sup 194}Pb

    SciTech Connect

    Hannachi, F.; Lopez-Martens, A.; Schueck, C.

    1996-12-01

    The EUROGAM array has been used to investigate the decay out of the yrast superdeformed (SD) band in {sup 194}Pb. Eigth single step decays from the lowest observed SD states to low-lying states at normal deformation (ND) have been identified. From this observation, the excitation energy (4877 {plus_minus} 1.5 keV) and the spin (6+) of the lowest observed SD state in {sup 194}Pb are established.

  11. The 2-10 keV X-Ray Background Dipole and Its Cosmological Implications

    NASA Astrophysics Data System (ADS)

    Scharf, C. A.; Jahoda, K.; Treyer, M.; Lahav, O.; Boldt, E.; Piran, T.

    2000-11-01

    The hard X-ray (>2 keV) emission of the local and distant universe as observed with the HEAO 1 A-2 experiment is reconsidered in the context of large-scale cosmic structure. Using all-sky X-ray samples of active galactic nuclei (AGNs) and galaxy clusters, we remove the dominant local X-ray flux from within a redshift of ~0.02. We evaluate the dipolar and higher order harmonic structure in four X-ray colors. The estimated dipole anisotropy of the unresolved flux appears to be consistent with a combination of the Compton-Getting effect due to the Local Group motion (dipole amplitude Δ=0.0042) and remaining large-scale structure (0.0023<~Δ<~0.0085), in good agreement with the expectations of cold dark matter models. The observed anisotropy does, however, also suggest a nonnegligible Galactic contribution that is more complex than current, simple models of >2 keV Galactic X-ray emission. Comparison of the soft and hard color maps with a harmonic analysis of the 1.5 keV ROSAT all-sky data qualitatively suggests that at least a third of the faint, unresolved ~18° scale structure in the HEAO 1 A-2 data may be Galactic in origin. However, the effect on measured flux dipoles is small (<~3%). We derive an expression for dipole anisotropy and acceleration and demonstrate how the dipole anisotropy of the distant X-ray frame can constrain the amplitude of bulk motions of the universe. From observed bulk motions over a local ~50 h-1 Mpc radius volume, we determine 0.14<~Ω0.60/bX(0)<~0.59, where Ω0 is the universal density parameter and bX(0) is the present-epoch bias parameter, defined as the ratio of fluctuations in the X-ray source density and the mass density.

  12. Efficiency of Scintillator Materials in the Energy Range 8.0-32.0 keV

    SciTech Connect

    Kinney, J H; Haupt, D L

    2002-07-01

    X-ray microtomography requires the measurement of x-ray attenuation along ray paths through a specimen, and on the inversion of these data to obtain a spatially resolved mapping of the microstructure of the specimen. To do this efficiently, two-dimensional array detectors are often used to measure the transmitted x-rays by capturing and recording each x-ray incident on the detector. The highest resolution CT instruments perform this by converting the incident x-rays to visible light, and then focusing this light onto a charge-coupled-device (CCD) detector. The light output of the scintillator (photons per incident x-ray), the numerical aperture of the optical lens system, and the quantum efficiency of the CCD govern the efficiency of the detection process. Several years earlier, our group performed an investigation aimed at determining the best scintillator material for high-resolution synchrotron CT. The selection criteria included light output in the 8-32 keV energy range, the spatial resolution of the scintillator, the wavelength of the scintillation radiation, and the stability and ease of polishing of the scintillator. A list of the scintillators that we considered, with the exceptions of the more recently developed glass scintillators, is provided in Table 1. Among these scintillators, we concluded that single crystal cadmium tungstate was optimum; we have used this material in all subsequent synchrotron CT systems. Since this original study, several doped-glass scintillators have become available. The LSO (Lu orthosilicates) scintillators, developed for PET scanning, show considerable light output at high energy (energies above 500 keV). Theoretically, the light output of these scintillators should be twice that of the cadmium tungstate. The purpose of this study was to determine the efficiency of two such scintillators (LSO:Yt and IQI-401 high density terbium activated glass) in the energy range from 8-32 keV.

  13. NEW OBSERVATIONS OF THE SOLAR 0.5–5 KEV SOFT X-RAY SPECTRUM

    SciTech Connect

    Caspi, Amir; Woods, Thomas N.; Warren, Harry P.

    2015-03-20

    The solar corona is orders of magnitude hotter than the underlying photosphere, but how the corona attains such high temperatures is still not understood. Soft X-ray (SXR) emission provides important diagnostics for thermal processes in the high-temperature corona, and is also an important driver of ionospheric dynamics at Earth. There is a crucial observational gap between ∼0.2 and ∼4 keV, outside the ranges of existing spectrometers. We present observations from a new SXR spectrometer, the Amptek X123-SDD, which measured the spatially integrated solar spectral irradiance from ∼0.5 to ∼5 keV, with ∼0.15 keV FWHM resolution, during sounding rocket flights on 2012 June 23 and 2013 October 21. These measurements show that the highly variable SXR emission is orders of magnitude greater than that during the deep minimum of 2009, even with only weak activity. The observed spectra show significant high-temperature (5–10 MK) emission and are well fit by simple power-law temperature distributions with indices of ∼6, close to the predictions of nanoflare models of coronal heating. Observations during the more active 2013 flight indicate an enrichment of low first-ionization potential elements of only ∼1.6, below the usually observed value of ∼4, suggesting that abundance variations may be related to coronal heating processes. The XUV Photometer System Level 4 data product, a spectral irradiance model derived from integrated broadband measurements, significantly overestimates the spectra from both flights, suggesting a need for revision of its non-flare reference spectra, with important implications for studies of Earth ionospheric dynamics driven by solar SXRs.

  14. Multi-Band-SWIFT

    NASA Astrophysics Data System (ADS)

    Idiyatullin, Djaudat; Corum, Curtis A.; Garwood, Michael

    2015-02-01

    A useful extension to SWIFT (SWeep Imaging with Fourier Transformation) utilizing sidebands of the excitation pulse is introduced. This MRI method, called Multi-Band-SWIFT, achieves much higher bandwidth than standard SWIFT by using multiple segmented excitations (bands) of the field of view. A description of the general idea and variants of the pulse sequence are presented. From simulations and semi-phenomenological theory, estimations of power deposition and signal-to-noise ratio are made. MB-SWIFT and ZTE (zero-TE) sequences are compared based on images of a phantom and human mandible. Multi-Band-SWIFT provides a bridge between SWIFT and ZTE sequences and allows greatly increased excitation and acquisition bandwidths relative to standard SWIFT for the same hardware switching parameters and requires less peak amplitude of the radiofrequency field (or greater flip angle at same peak amplitude) as compared to ZTE. Multi-Band-SWIFT appears to be an attractive extension of SWIFT for certain musculoskeletal and other medical imaging applications, as well as for imaging materials.

  15. Multi-Band-SWIFT.

    PubMed

    Idiyatullin, Djaudat; Corum, Curtis A; Garwood, Michael

    2015-02-01

    A useful extension to SWIFT (SWeep Imaging with Fourier Transformation) utilizing sidebands of the excitation pulse is introduced. This MRI method, called Multi-Band-SWIFT, achieves much higher bandwidth than standard SWIFT by using multiple segmented excitations (bands) of the field of view. A description of the general idea and variants of the pulse sequence are presented. From simulations and semi-phenomenological theory, estimations of power deposition and signal-to-noise ratio are made. MB-SWIFT and ZTE (zero-TE) sequences are compared based on images of a phantom and human mandible. Multi-Band-SWIFT provides a bridge between SWIFT and ZTE sequences and allows greatly increased excitation and acquisition bandwidths relative to standard SWIFT for the same hardware switching parameters and requires less peak amplitude of the radiofrequency field (or greater flip angle at same peak amplitude) as compared to ZTE. Multi-Band-SWIFT appears to be an attractive extension of SWIFT for certain musculoskeletal and other medical imaging applications, as well as for imaging materials.

  16. Banded Sunflower Moth

    Technology Transfer Automated Retrieval System (TEKTRAN)

    The banded sunflower moth, Cochylis hospes Walsingham, is an important insect pest of cultivated sunflower. Eggs are deposited on the bracts of sunflower heads. Larvae develop through five instars within the heads and are present in fields from mid-July to mid-September. Larvae feed initially on the...

  17. Birnessite-induced mechanochemical degradation of 2,4-dichlorophenol.

    PubMed

    Nasser, A; Mingelgrin, U

    2014-07-01

    DCP (2,4-dichlorophenol) is the key-intermediate in the synthesis of some widely used pesticides and is an EPA priority pollutant. The mechanochemical breakdown of DCP loaded on birnessite (δ-MnO2), montmorillonite saturated with Na(+) or Cu(2+) and hematite was investigated. Mechanical force was applied by grinding of mixtures of DCP and the minerals, using mortar and pestle. Grinding of DCP for 5 min with the montmorillonites or with hematite resulted in negligible degradation during grinding, while grinding with birnessite induced the immediate degradation of 90% of the loaded DCP. Incubation for 24h after grinding did result in up to 30% degradation of the DCP loaded on the other minerals tested. HPLC and LC-MS analysis revealed that the transformation of DCP yielded oligomerization products as well as partial dechlorination. DCP degradation on birnessite was accompanied with a substantial increase in the extractability of manganese from the mineral into an acidic aqueous solution, indicating that Mn(IV) in the mineral transformed into Mn(II) and that birnessite served as an electron acceptor in the transformation. The oligomerization and partial dechlorination brought about by grinding, suggest a reduction in bioavailability and toxicity.

  18. Biodegradation of 2,4-dinitrotoluene by a Pseudomonas sp.

    PubMed Central

    Spanggord, R J; Spain, J C; Nishino, S F; Mortelmans, K E

    1991-01-01

    Previous studies of the biodegradation of nonpolar nitroaromatic compounds have suggested that microorganisms can reduce the nitro groups but cannot cleave the aromatic ring. We report here the initial steps in a pathway for complete biodegradation of 2,4-dinitrotoluene (DNT) by a Pseudomonas sp. isolated from a four-member consortium enriched with DNT. The Pseudomonas sp. degraded DNT as the sole source of carbon and energy under aerobic conditions with stoichiometric release of nitrite. During induction of the enzymes required for growth on DNT, 4-methyl-5-nitrocatechol (MNC) accumulated transiently in the culture fluid when cells grown on acetate were transferred to medium containing DNT as the sole carbon and energy source. Conversion of DNT to MNC in the presence of 18O2 revealed the simultaneous incorporation of two atoms of molecular oxygen, which demonstrated that the reaction was catalyzed by a dioxygenase. Fully induced cells degraded MNC rapidly with stoichiometric release of nitrite. The results indicate an initial dioxygenase attack at the 4,5 position of DNT with the concomitant release of nitrite. Subsequent reactions lead to complete biodegradation and removal of the second nitro group as nitrite. PMID:1781682

  19. User's guide for LTGSTD24 program, Version 2. 4

    SciTech Connect

    Hanlon, R.L.; Connell, L.M.

    1993-05-01

    On January 30, 1989, the US Department of Energy (DOE) promulgated an interim rule entitled [open quotes]Energy Conservation Voluntary Performance Standards for New Commercial and Multi-Family High Rise Residential Buildings; Mandatory for New Federal Buildings[close quotes] (10 CFR Part 435, Subpart A). These standards require federal agencies to design all future federal commercial and multifamily high-rise residential buildings in accordance with the standards, or demonstrate that their current requirements already meet or exceed the energy-efficiency requirements of the standards. Although these newly enacted standards do not regulate the design of non-federal buildings, the DOE recommends that all design professionals use the standards as guidelines for designing energy-conserving buildings. To encourage private sector use, the DOE published the standards in the January 30, 1989, Federal Register in the format typical of commercial standards. The Pacific Northwest Laboratory developed several computer programs for the DOE to make it easier for designers to comply with the standards. One of the programs, LTGSTD24 (Version 2.4), is detailed in this user's guide and is provided on the accompanying diskettes. The program will facilitate the designer's use of the standards dealing specifically with building lighting design. Using this program will greatly simplify the designer's task of performing the calculations needed to determine if a design complies with the standards.

  20. User's guide for ENVSTD24 program, Version 2. 4

    SciTech Connect

    Hanlon, R.L.; Connell, L.M.

    1993-05-01

    On January 30, 1989, the US Department of Energy (DOE) promulgated an interim rule entitled [open quotes]Energy Conservation Voluntary Performance Standards for New Commercial and Multi-Family High Rise Residential Buildings; Mandatory for New Federal Buildings[close quotes] (10 CFR Part 435, Subpart A). These standards require federal agencies to design all future federal commercial and multifamily high-rise residential buildings in accordance with the standards, or demonstrate that their current requirements already meet or exceed the energy-efficiency requirements of the standards. Although these newly enacted standards do not regulate the design of nonfederal buildings, the DOE recommends that all design professionals use the standards as guidelines for designing energy-conserving buildings. To encourage private sector use, the DOE published the standards in the January 30, 1989, Federal Register in the format typical of commercial standards. The Pacific Northwest Laboratory developed several computer programs for the DOE to make it easier for designers to comply with the standards. One of the programs, ENVSTD24 (Version 2.4), is detailed in this user's guide and is provided on the accompanying diskettes. The program will facilitate the designer's use of the standards dealing specifically with building envelope design. Using this program will greatly simplify the designer's task of performing the calculations needed to determine if a design complies with the standards.

  1. Excitation-wavelength Dependent Fluorescence of Ethyl 5-(4-aminophenyl)-3-amino-2,4-dicyanobenzoate

    PubMed Central

    Heldt, Janina R.

    2010-01-01

    The excitation wavelength dependence of the steady-state and time-resolved emission spectra of ethyl 5-(4-aminophenyl)-3-amino-2,4-dicyanobenzoate (EAADCy) in tetrahydrofuran (THF) at room temperature has been examined. It is found that the ratio of the fluorescence intensity of the long-wavelength and short-wavelength fluorescence bands strongly depends on the excitation wavelength, whereas the wavelengths of the fluorescence excitation and fluorescence bands maxima are independent on the observation/excitation wavelengths. The dynamic Stokes shift of fluorophore in locally excited (LE) and intramolecular charge transfer (ICT) states has been studied with a time resolution about 30 ps. The difference between Stokes shift in the LE and ICT states was attributed to the solvent response to the large photoinduced dipole moment of EAADCy in the fluorescent charge transfer state. On this base we can state that, the relaxation of the polar solvent molecules around the fluorophore was observed. PMID:20798980

  2. High temperature stability of anatase in titania-alumina semiconductors with enhanced photodegradation of 2, 4-dichlorophenoxyacetic acid.

    PubMed

    López-Granada, G; Barceinas-Sánchez, J D O; López, R; Gómez, R

    2013-12-15

    The incorporation of aluminum acetylacetonate as alumina source during the gelation of titanium alkoxide reduces the nucleation sites for the formation of large rutile crystals on temperatures ranging from 400 to 800°C. As a result, the aggregation of anatase crystals is prevented at high temperature. A relationship among the specific surface area, pore size, energy band gap, crystalline structure and crystallite size as the most relevant parameters are evaluated and discussed. According to the results for the photocatalytic degradation of 2,4-dichlorophenoxyacetic acid, the specific surface area, pore size, Eg band gap are not determinant in the photocatalytic properties. It was found that the anatase crystallite size is the mores important parameter affecting the degradation efficiency.

  3. Coexistence issues for a 2.4 GHz wireless audio streaming in presence of bluetooth paging and WLAN

    NASA Astrophysics Data System (ADS)

    Pfeiffer, F.; Rashwan, M.; Biebl, E.; Napholz, B.

    2015-11-01

    Nowadays, customers expect to integrate their mobile electronic devices (smartphones and laptops) in a vehicle to form a wireless network. Typically, IEEE 802.11 is used to provide a high-speed wireless local area network (WLAN) and Bluetooth is used for cable replacement applications in a wireless personal area network (PAN). In addition, Daimler uses KLEER as third wireless technology in the unlicensed (UL) 2.4 GHz-ISM-band to transmit full CD-quality digital audio. As Bluetooth, IEEE 802.11 and KLEER are operating in the same frequency band, it has to be ensured that all three technologies can be used simultaneously without interference. In this paper, we focus on the impact of Bluetooth and IEEE 802.11 as interferer in presence of a KLEER audio transmission.

  4. Microchannel plate pinhole camera for 20 to 100 keV x-ray imaging

    SciTech Connect

    Wang, C.L.; Leipelt, G.R.; Nilson, D.G.

    1984-10-03

    We present the design and construction of a sensitive pinhole camera for imaging suprathermal x-rays. Our device is a pinhole camera consisting of four filtered pinholes and microchannel plate electron multiplier for x-ray detection and signal amplification. We report successful imaging of 20, 45, 70, and 100 keV x-ray emissions from the fusion targets at our Novette laser facility. Such imaging reveals features of the transport of hot electrons and provides views deep inside the target.

  5. Kinetic energy releases of small amino acids upon interaction with keV ions

    NASA Astrophysics Data System (ADS)

    Bari, S.; Alvarado, F.; Postma, J.; Sobocinski, P.; Hoekstra, R.; Schlathölter, T.

    2009-01-01

    In chromatin, DNA is tightly packed into one complex together with histone and non-histone proteins. These proteins are known to protect the DNA against indirect and to some extent even direct radiation damage. Radiation action upon amino acids is thus one of the primary steps in biological radiation action. In this paper we investigate the ionization and fragmentation of the gas-phase amino acids glycine, alanine and valine upon interaction with keV α-particles. High resolution coincidence time-of-flight mass spectrometry is used to determine the dominant fragmentation channels as well as fragment kinetic energies.

  6. Inelastic scattering of 45-keV neutrons by {sup 187}Os

    SciTech Connect

    Litvinskii, L.L.; Zhigalov, Ya.A.; Libman, V.A.; Murzin, A.V.; Shkarupa, A.M.

    1995-02-01

    The cross sections of elastic and inelastic scattering of 45-keV neutrons by {sup 187}Os are measured by the technique of filtered neutron beams at the Kiev VVR-M reactor and are found to be {sigma}{sub e1} = 11.90 {+-} 0.50 b and {sigma}{sub inel} = 1.51 {+-} 0.45 b, respectively. These results confirm the existence of a nonstatistical enhancement of the inelastic-scattering channel due to a noticeable contribution of a preequilibrium state involving two particles and a hole. 8 refs., 1 fig.

  7. A 17 keV neutrino and large magnetic moment solution of the solar neutrino puzzle

    NASA Astrophysics Data System (ADS)

    Akhmedov, E. Kh.; Senjanovic, G.; Tao, Zhijian; Berezhiani, Z. G.

    1992-08-01

    Zee-type models with Majorons naturally incorporate the 17 keV neutrino but in their minimal version fail to simultaneously solve the solar neutrino puzzle. If there is a sterile neutrino state, a particularly simple solution is found to the solar neutrino problem, which besides nu(sub 17) predicts a light Zeldovich-Konopinski-Mahmoud neutrino nu(sub light) = nu(sub e) + nu(sub mu)(sup c) with a magnetic moment being easily as large as 10(exp -11)(mu)(sub B) through the Barr-Freire-Zee mechanism.

  8. 17 keV neutrino and large magnetic moment solution of the solar neutrino puzzle

    NASA Astrophysics Data System (ADS)

    Akhmedov, Eugeni Kh.; Berezhiani, Zurab G.; Senjanović, Goran; Tao, Zhijian

    1993-01-01

    Zee-type models with majorons naturally incorporate the 17 keV neutrino but in their minimal version fail to simultaneously solve the solar neutrino puzzle. If there is a sterile neutrino state, we find a particularly simple solution to the solar neutrino problem, which besides ν17 predicts a light Zeldovich-Konopinski-Mahmoud neutrino νlight = νe + νcμ with a magnetic moment being easily as large as 10 -11μB through the Barr-Freire-Zee mechanism.

  9. Simultaneous ejection of two molecular ions from keV gold atomic and polyatomic projectile impacts.

    PubMed

    Rickman, R D; Verkhoturov, S V; Parilis, E S; Schweikert, E A

    2004-01-30

    We present the first experimental data on the simultaneous ejection of two molecular ions from the impact of Au(+)(n) (1< or =n< or =4) with energies ranging between 17 and 56 keV. The yields from single phenylalanine (Ph) emission, coemission of two Ph ions, and emission of the Ph dimer were measured. Large increases (1 to 2 orders of magnitude) in coemitted ion yields were observed with increasing projectile energy and complexity. Correlation coefficients were calculated for the coemission of two Ph ions; their behavior suggests differences in emission pathways for bombardment by atomic and polyatomic projectiles.

  10. Asymmetric 511 keV Positron Annihilation Line Emission from the Inner Galactic Disk

    NASA Technical Reports Server (NTRS)

    Skinner, Gerry; Weidenspointner, Georg; Jean, Pierre; Knodlseder, Jurgen; Ballmoos, Perer von; Bignami, Giovanni; Diehl, Roland; Strong, Andrew; Cordier, Bertrand; Schanne, Stephane; Winkler, Christoph

    2008-01-01

    A recently reported asymmetry in the 511 keV gamma-ray line emission from the inner galactic disk is unexpected and mimics an equally unexpected one in the distribution of LMXBs seen at hard X-ray energies. A possible conclusion is that LMXBs are an important source of the positrons whose annihilation gives rise to the line. We will discuss these results, their statistical significance and that of any link between the two. The implication of any association between LMXBs and positrons for the strong annihilation radiation from the galactic bulge will be reviewed.

  11. The effect of 1 to 5 keV electrons on the reproductive integrity of microorganisms

    NASA Technical Reports Server (NTRS)

    Barengoltz, J. B.; Brady, J.

    1977-01-01

    Microorganisms were exposed to simulated space environment in order to assess the effect of electrons in the energy range 1 to 5 keV on their colony-forming ability. The test system consisted of an electron gun and power supply, a dosimetry subsystem, and a vacuum subsystem. The system was capable of current densities ranging from 0.1 nA/sq cm to 5 micro A/sq cm on a 25 sq on target and an ultimate vacuum of 0.0006 N/sq m (0.000004 torr). The results of the experimental program show a significant reduction in microbial reproductive integrity.

  12. On the vectorial photoelectric effect at 2.69 keV

    NASA Technical Reports Server (NTRS)

    Shaw, P. S.; Hanany, S.; Liu, Y.; Church, E. D.; Fleischman, J.; Kaaret, P.; Novick, R.; Santangelo, A.

    1991-01-01

    Recent experiments conducted to study the vectorial photoelectric effect with CsI, Al2O3 and Si photocathodes at 2.69 keV indicate null results. Detailed analysis shows that previously measured modulation can be well explained by geometrical misalignment and a combination of the asymmetric shape of the incident X-ray beam and a small detection area of the photoelectron detector. After the elimination of the sources of spurious modulation, we observed a modulation factor of less than 3 percent for a grazing incidence angle as small as 5 deg. There is no observable difference in the pulse height distribution between s and p states.

  13. Extension to Low Energies (<7keV) of High Pressure X-Ray Absorption Spectroscopy

    SciTech Connect

    Itie, J.-P.; Flank, A.-M.; Lagarde, P.; Idir, M.; Polian, A.; Couzinet, B.

    2007-01-19

    High pressure x-ray absorption has been performed down to 3.6 keV, thanks to the new LUCIA beamline (SLS, PSI) and to the use of perforated diamonds or Be gasket. Various experimental geometries are proposed, depending on the energy of the edge and on the concentration of the studied element. A few examples will be presented: BaTiO3 at the titanium K edge, Zn0.95 Mn0.05O at the manganese K edge, KCl at the potassium K edge.

  14. 3.55 keV line in minimal decaying dark matter scenarios

    SciTech Connect

    Arcadi, Giorgio; Covi, Laura; Dradi, Federico E-mail: Laura.Covi@theorie.physik.uni-goettingen.de

    2015-07-01

    We investigate the possibility of reproducing the recently reported 3.55 keV line in some simple decaying dark matter scenarios. In all cases a keV scale decaying DM is coupled with a scalar field charged under SM gauge interactions and thus capable of pair production at the LHC. We will investigate how the demand of a DM lifetime compatible with the observed signal, combined with the requirement of the correct DM relic density through the freeze-in mechanism, impacts the prospects of observation at the LHC of the decays of the scalar field.

  15. Calibration of the 67 keV mössbauer resonance of73Ge

    NASA Astrophysics Data System (ADS)

    Svane, A.; Antoncik, E.

    1986-06-01

    Using the first-principles scalar-relativistic LMTO method, we have calculated the electronic structure of crystalline Ge and rutile-structured GeO2. By comparing the calculated electron contact densities with experimental isomer shifts of the 67 keV transition of73Ge in these materials, we obtain a value for the relative change in the nuclear radius of Δ R/R=(7.4±0.7)×10-4. The results of the present work are compared with previous attempts to calibrate this isomeric transition.

  16. Ionization and Fragmentation of 5-Chlorouracil induced by 100 keV protons collisions

    SciTech Connect

    Cafarelli, Pierre; Champeaux, Jean-Philippe; Le Padellec, Arnaud; Moretto-Capelle, Patrick; Rabier, Julien; Sence, Martine; Carcabal, Pierre

    2008-12-08

    We present preliminary experimental results on the dissociation of singly and doubly ionized 5-Chlorouracil induced by collisions with proton of 100 keV energy. Multiple coincidence techniques are used to detect the ionic fragments from single dissociation events. This enables a thorough analysis of kinetic momentums of the charged and neutral species involved in the dissociation. In many cases, this leads to the establishment of the scenario the molecule undergoes after ionization as well as the determination of the nature of intermediate (undetected) species. In other cases, the dissociation scenario cannot be unambiguously identified and further analysis as well as theoretical support is needed.

  17. SEARCH FOR TWO-PHONON OCTUPOLE VIBRATIONAL BANDS IN 88, 89, 92, 93, 94, 96Sr AND 95, 96, 97, 98Zr

    NASA Astrophysics Data System (ADS)

    Hwang, J. K.; Hamilton, J. H.; Ramayya, A. V.; Brewer, N. T.; Wang, E. H.; Luo, Y. X.; Zhu, S. J.

    2012-09-01

    Several new gamma transitions were identified in 94Sr, 93Sr, 92Sr, 96Zr and 97Zr from the spontaneous fission of 252Cf. Excited states in 88, 89, 92, 94, 96Sr and 95, 96, 97, 98Zr were reanalyzed and reorganized to propose the new two-phonon octupole vibrational states and bands. The spin and parity of 6+ are assigned to a 4034.5 keV state in 94Sr and 3576.4 keV state in 98Zr. These states are proposed as the two-phonon octupole vibrational states along with the 6+ states at 3483.4 keV in 96Zr, at 3786.0 keV in 92Sr and 3604.2 keV in 96Sr. The positive parity bands in 88, 94, 96Sr and 96, 98Zr are the first two-phonon octupole vibrational bands based on a 6+ state assigned in spherical nuclei. It is thought that in 94, 96Sr and 96, 98Zr a 3- octupole vibrational phonon is weakly coupled to an one-phonon octupole vibrational band to make the two-phonon octupole vibrational band. Also, the high spin states of odd-A95Zr and 97Zr are interpreted to be generated by the neutron 2d5/2 hole and neutron 1g7/2 particle, respectively, weakly coupled to one- and two-phonon octupole vibrational bands of 96Zr. The high spin states of odd-A87Sr are interpreted to be caused by the neutron 1g9/2 hole weakly coupled to 3- and 5- states of 88Sr. New one- and two-POV bands in 95, 97Zr and 87, 89Sr are proposed, for the first time, in the present work.

  18. Spinor Field Realizations of Non-critical W2,4 String Based on Linear W1,2,4 Algebra

    NASA Astrophysics Data System (ADS)

    Zhang, Li-Jie; Liu, Yu-Xiao

    2006-10-01

    In this paper, we investigate the spinor field realizations of the W2,4 algebra, making use of the fact that the W2,4 algebra can be linearized through the addition of a spin-1 current. And then the nilpotent BRST charges of the spinor non-critical W2,4 string were built with these realizations.

  19. Effects of 2,4-Dichlorophenol, a Metabolite of a Genetically Engineered Bacterium, and 2,4-Dichlorophenoxyacetate on Some Microorganism-Mediated Ecological Processes in Soil

    PubMed Central

    Short, K. A.; Doyle, J. D.; King, R. J.; Seidler, R. J.; Stotzky, G.; Olsen, R. H.

    1991-01-01

    A genetically engineered microorganism, Pseudomonas putida PPO301(pRO103), and the plasmidless parent strain, PPO301, were added at approximately 107 CFU/g of soil amended with 500 ppm of 2,4-dichlorophenoxyacetate (2,4-D) (500 μg/g). The degradation of 2,4-D and the accumulation of a single metabolite, identified by gas chromatography-mass spectrophotometry as 2,4-dichlorophenol (2,4-DCP), occurred only in soil inoculated with PPO301(pRO103), wherein 2,4-DCP accumulated to >70 ppm for 5 weeks and the concentration of 2,4-D was reduced to <100 ppm. Coincident with the accumulation of 2,4-DCP was a >400-fold decline in the numbers of fungal propagules and a marked reduction in the rate of CO2 evolution, whereas 2,4-D did not depress either fungal propagules or respiration of the soil microbiota. 2,4-DCP did not appear to depress the numbers of total heterotrophic, sporeforming, or chitin-utilizing bacteria. In vitro and in situ assays conducted with 2,4-DCP and fungal isolates from the soil demonstrated that 2,4-DCP was toxic to fungal propagules at concentrations below those detected in the soil. PMID:16348408

  20. Experimental study of the 2p-2h band in {sup 111}Sn

    SciTech Connect

    Ganguly, S.; Banerjee, P.; Ray, I.; Kshetri, R.; Raut, R.; Bhattacharya, S.; Saha-Sarkar, M.; Goswami, A.; Basu, S. K.

    2008-09-15

    The {delta}I=2 intruder band in {sup 111}Sn, built upon the 4074.3 keV state, was studied. The states were populated in the {sup 100}Mo({sup 20}Ne, {alpha}5n) reaction at a beam energy of 136 MeV. Mean lifetimes of five states up to 8737.2 keV (spin 43/2{sup -}) have been measured for the first time using the Doppler shift attenuation method. In addition, an upper limit of mean lifetime has been estimated for the 9860.0 keV (spin 47/2{sup -}) state. The B(E2) values, derived from the present lifetime results, indicate a quadrupole deformation of {beta}{sub 2}=0.28{+-}0.02 for the 31/2{sup -} state and decrease progressively with spin, suggesting a reduction in collectivity. The dynamic moment of inertia for the band also decreases continuously up to the highest observed frequencies. These results, along with the predictions of a total Routhian surface calculation, suggest that the {delta}I=2 band in {sup 111}Sn undergoes a change of shape from collective prolate to triaxial with increase in spin and possibly terminates in a noncollective oblate state at a high spin.

  1. Band reject filtration of the excitation spectrum at energy dispersive X-ray spectroscopy of weak signals

    NASA Astrophysics Data System (ADS)

    Tur'yanskii, A. G.; Gizha, S. S.; Senkov, V. M.; Pirshin, I. V.; Stanishevskii, Ya. M.

    2016-09-01

    The possibility of the efficient band reject filtration of the continuous X-ray excitation spectrum in the energy range E ≥ 8 keV is demonstrated. This makes it possible to strongly increase the sensitivity of energy dispersive X-ray spectroscopy at detecting of weak fluorescence lines. Spectral rejection is implemented by transmitting a primary beam through highly oriented pyrolytic graphite with given structural parameters. Diffraction extinction in pyrolytic graphite ensures the possibility of reducing the intensity by more than 20 dB and rejecting the spectral band with a width of 1 keV. The reduction of statistical fluctuations of the background of elastically scattered radiation is achieved when the bottom of the formed spectral valley is adjusted to the analyzed fluorescence line. The proposed scheme of band reject filtration also allows the suppression of intense characteristic lines in the primary and scattered radiation spectra.

  2. R-Matrix Analysis of 238U High Resolution Neutron Transmissions and Capture Cross Sections in the Energy Range 0 keV to 20 keV

    SciTech Connect

    Derrien, Herve; Leal, Luiz C; Larson, Nancy M

    2009-01-01

    The neutron resonance parameters of 238U were obtained from a SAMMY analysis of high-resolution neutron transmission measurements and high-resolution capture cross section measurements performed at the Oak Ridge Electron Linear Accelerator (ORELA) in the years 1970-1990 and from more recent transmission and capture cross section measurements performed at the Geel Linear Accelerator (GELINA). Compared with previous evaluations, the energy range for this resonance analysis was extended from 10 to 20 keV, taking advantage of the high resolution of the most recent ORELA transmission measurements. The experimental database and the method of analysis are described in this report. The neutron transmissions and the capture cross sections calculated with the resonance parameters are compared with the experimental data. A description is given of the statistical properties of the resonance parameters and of the recommended values of the average parameters. The new evaluation results in a slight decrease of the effective capture resonance integral and improves the prediction of integral thermal benchmarks by 70 to 200 pcm.

  3. Model study of the mid-latitude atmospheric interaction with energetic O/sup +/ and He/sup +/ (< 20 keV) precipitation during a storm

    SciTech Connect

    Ishimoto, M.

    1986-01-01

    The purpose of this study is to use a model computation to investigate the mid-latitude atmospheric interaction with energetic O/sup +/ and He/sup +/ (<20 keV) precipitation during a storm. The steady-state continuity equations for the fluxes are formulated as a system of first-order ordinary differential equations. The model, consisting of three components, O, N/sub 2/ and He, computes the upward and downward fluxes resulting from energetic ion precipitation by solving sets of this system of equations. The model computes the heating, the ion production, the N/sub 2//sup +/ first negative (O-O) band and N/sub 2/ second-positive (O-O) band emission intensities in the atmosphere, and the escape fluxes to the magnetosphere. Energetic O/sup +/ deposit 80% of their energy for heating and a few percent for ionization below 200 km, and bring 20% of their incident energy back to the magnetosphere together with 30 O and 5 N/sub 2/ particles from the ionospheres for each incident O/sup +/. Energetic He/sup +/ dissipate by ionization (50%) instead of atmospheric heating (10%). He/sup +/ are reflected at an altitude of about 200 km back to the magnetosphere without losing much energy. He/sup +/ precipitation does not bring the ionospheric neutrals back to the magnetosphere.

  4. Static and time-resolved 10-1000 keV x-ray imaging detector options for NIF

    SciTech Connect

    Landen, O.L.; Bell, P.M.; McDonald, J.W.; Park, H.-S.; Weber, F.; Moody, J.D.; Lowry, M.E.; Stewart, R.E.

    2004-10-01

    High energy (>10 keV) x-ray self-emission imaging and radiography will be essential components of many NIF high energy density physics experiments. In preparation for such experiments, we have evaluated the pros and cons of various static [x-ray film, bare charge-coupled device (CCD), and scintillator + CCD] and time-resolved (streaked and gated) 10-1000 keV detectors.

  5. A quasi-time-dependent radiative transfer model of OH 104.9+2.4

    NASA Astrophysics Data System (ADS)

    Riechers, D.; Balega, Y.; Driebe, T.; Hofmann, K.-H.; Men'shchikov, A. B.; Shenavrin, V. I.; Weigelt, G.

    2005-06-01

    We investigate the pulsation-phase dependent properties of the circumstellar dust shell (CDS) of the OH/IR star OH 104.9+2.4 based on radiative transfer modeling (RTM) using the code DUSTY. Our previous study concerning simultaneous modeling of the spectral energy distribution (SED) and near-infrared (NIR) visibilities (Riechers et al. 2004) has now been extended by means of a more detailed analysis of the pulsation-phase dependence of the model parameters of OH 104.9+2.4. In order to investigate the temporal variation in the spatial structure of the CDS, additional NIR speckle interferometric observations in the K' band were carried out with the 6 m telescope of the Special Astrophysical Observatory (SAO). At a wavelength of λ = 2.12 μm the diffraction-limited resolution of 74 mas was attained. Several key parameters of our previous best-fitting model had to be adjusted in order to be consistent with the newly extended amount of observational data. It was found that a simple rescaling of the bolometric flux F_bol is not sufficient to take the variability of the source into account, as the change in optical depth τ over a full pulsation cycle is rather high. On the other hand, the impact of a change in effective temperature T_eff on SED and visibility is rather small. However, observations, as well as models for other AGB stars, show the necessity of including a variation of T_eff with pulsation phase in the radiative transfer models. Therefore, our new best-fitting model accounts for these changes.

  6. Symmetry properties of the K =0 sup + bands in reflection asymmetric sup 224 Ac

    SciTech Connect

    Sheline, R.K.; Kvasil, J. ); Liang, C.F.; Paris, P. )

    1991-11-01

    Parity doublet bands with {ital K}=0{sup {plus minus}} implying reflection asymmetry (with an average spacing between the levels of the same spin and opposite parity of 12.6 keV) are observed in {sup 224}Ac. In the strong coupling limit all {ital K}=0{sup {plus minus}} parity doublet bands are shown to be constrained to Newby splittings with the same absolute magnitude, but with opposite sign. Experimentally, the Newby splittings in {sup 224}Ac approach this theoretical expectation.

  7. Sorption of 2,4-dinitroanisole (DNAN) on lignin.

    PubMed

    Saad, Rabih; Radovic-Hrapovic, Zorana; Ahvazi, Behzad; Thiboutot, Sonia; Ampleman, Guy; Hawari, Jalal

    2012-01-01

    The present study describes the use of two commercially available lignins, namely, alkali and organosolv lignin, for the removal of 2,4-dinitroanisole (DNAN), a chemical widely used by the military and the dye industry, from water. Sorption of DNAN on both lignins reached equilibrium within 10 hr and followed pseudo second-order kinetics with sorption being faster with alkali than with organosolv lignin, i.e. k2 10.3 and 0.3 g/(mg x hr), respectively. In a separate study we investigated sorption of DNAN between 10 and 40 degrees C and found that the removal of DNAN by organosolv lignin increased from 0.8 to 7.5 mg/g but reduced slightly from 8.5 to 7.6 mg/g in the case of alkali lignin. Sorption isotherms for either alkali or organosolv lignin best fitted Freundlich equation with enthalpy of formation, deltaH0 equaled to 14 or 80 kJ/mol. To help understand DNAN sorption mechanisms we characterized the two lignins by elemental analysis, BET nitrogen adsorption-desorption and 31P NMR. Variations in elemental compositions between the two lignins indicated that alkali lignin should have more sites (O- and S-containing functionalities) for H-bonding. The BET surface area and calculated total pore volume of alkali lignin were almost 10 times greater than that of organosolv lignin suggesting that alkali lignin should provide more sites for sorption. 31P NMR showed that organosolv lignin contains more phenolic -OH groups than alkali lignin, i.e., 70% and 45%, respectively. The variations in the type of OH groups between the two lignins might have affected the strength of H-bonding between DNAN and the type of lignin used.

  8. Structural study of 2,4,6-triisopropylbenzenesulfonyl chloride

    SciTech Connect

    Laba, V. I. Sviridova, A. V.; Nesterov, V. N.

    2009-01-15

    The structure of 2,4,6-triisopropylbenzenesulfonyl chloride (TPSCl) (I) was studied by X-ray diffraction. Compound I is a highly selective condensing agent first suggested by Khorana for the formation of the C3'-C5' interribonucleotide linkage in the oligo- and polyribonucleotide synthesis. I crystals are orthorhombic. At -120 deg. C, the unit-cell parameters are a = 14.184(4) A, b = 11.344(5) A, c = 19.883(6) A, V = 3199(2) A{sup 3}, d{sub calc} = 1.257 g/cm{sup 3}, Z = 8, sp. gr. Pbca. Molecule I adopts a strongly flattened boat conformation with the carbon atoms C-SO{sub 2}Cl (C{sub 1}) and C-i-Pr (C4) of the benzene ring deviating from the bottom of the boat by 0.065(1) and 0.032(1) A, respectively. Molecule I is sterically overcrowded, resulting in an increase in the bond lengths and bond-angle distortions in the fragment containing the SO{sub 2}Cl group and two ortho-i-Pr groups. Nonbonded contacts that are present in the molecule can be considered weak intramolecular hydrogen bonds (for example, the (CH{sub 3}){sub 2}C-H-O=S bond). There is no rotation of the SO{sub 2}Cl, ortho-i-Pr, and CH{sub 3} groups. The above-mentioned facts are, apparently, responsible for the specific selectivity of TPSCl. New readily available sterically hindered arenesulfonyl chlorides were designed.

  9. Time Sequence of Jupiter's Equatorial Region (Time Sets 2 & 4)

    NASA Technical Reports Server (NTRS)

    1997-01-01

    Time sequence of Jupiter's equatorial region at 756 nanometers (nm). The mosaics cover an area of 34,000 kilometers by 22,000 kilometers and were taken ten hours (approximately one Jovian rotation) apart. The dark region near the center of the mosaic is an equatorial 'hotspot' similar to the Galileo Probe entry site. The near-infrared continuum filter shows the features of Jupiter's main visible cloud deck.

    Jupiter's atmospheric circulation is dominated by alternating jets of east/west (zonal) winds. The bands have different widths and wind speeds but have remained constant as long as telescopes and spacecraft have measured them. The top half of these mosaics lies within Jupiter's North Equatorial Belt, a westward (left) current. The bottom half shows part of the Equatorial Zone, a fast moving eastward current. The clouds near the hotspot are the fastest moving features in these mosaics, moving at about 100 meters per second, or 224 miles per hour.

    North is at the top. The mosaics cover latitudes 1 to 19 degrees and are centered at longitude 336 degrees West. The grid lines, fixed in longitude, mark 350 degrees west (on the left edge) with decreasing longitude lines marking every 5 degrees moving east (to the right). The smallest resolved features are tens of kilometers in size. These images were taken on December 17, 1996, at a range of 1.5 million kilometers by the Solid State Imaging system aboard NASA's Galileo spacecraft.

    The Jet Propulsion Laboratory, Pasadena, CA manages the mission for NASA's Office of Space Science, Washington, DC.

    This image and other images and data received from Galileo are posted on the World Wide Web, on the Galileo mission home page at URL http://galileo.jpl.nasa.gov. Background information and educational context for the images can be found at URL http://www.jpl.nasa.gov/galileo/sepo

  10. Calibration of semiconductor detectors in the 200-8500 keV range at VNIIM.

    PubMed

    Tereshchenko, Evgeny E; Moiseev, Nikolay

    2012-09-01

    At the ionising radiation department of the D.I. Mendeleyev Institute for Metrology, a semiconductor detector was calibrated in the energy range 200-8500 keV using (n,2γ) and (n,γ) reactions. Separate cylindrical targets (77 mm diameter and 10mm height) were made from mercuric sulphate, sodium chloride and metallic titanium. A (252)Cf spontaneous fission neutron source, placed in 150 mm diameter polyethylene ball, was used to generate thermal neutrons. The optimal target dimensions were determined taking into account the thermal neutron cross-sections and gamma-radiation attenuations in the target materials. The influence of the background radiation induced by neutrons from the walls, floors and ceilings was also taken into account. The shapes of the efficiency curves for point and volume sources in the 200-8500 keV range have been investigated. The experimental results are in good agreement with Monte-Carlo calculations. The emission rate of the 6.13 MeV photons from a (238)Pu-(13)C source was determined with an expanded uncertainty, U(c), of 10% (k=2).

  11. Evaluation of Silicon Neutron Resonance Parameters in the Energy Range Thermal to 1800 keV

    SciTech Connect

    Derrien, H.

    2002-09-30

    The evaluation of the neutron cross sections of the three stable isotopes of silicon in the energy range thermal to 20 MeV was performed by Hetrick et al. for ENDF/B-VI (Evaluated Nuclear Data File). Resonance parameters were obtained in the energy range thermal to 1500 keV from a SAMMY analysis of the Oak Ridge National Laboratory experimental neutron transmission data. A new measurement of the capture cross section of natural silicon in the energy range 1 to 700 keV has recently been performed at the Oak Ridge Electron Linear Accelerator. Results of this measurement were used in a SAMMY reevaluation of the resonance parameters, allowing determination of the capture width of a large number of resonances. The experimental data base is described; properties of the resonance parameters are given. For the first time the direct neutron capture component has been taken into account from the calculation by Rauscher et al. in the energy range from thermal to 1 MeV. Results of benchmark calculations are also given. The new evaluation is available in the ENDF/B-VI format.

  12. Full characterization of a laser-produced keV x-ray betatron source

    NASA Astrophysics Data System (ADS)

    Albert, F.; Phuoc, K. Ta; Shah, R.; Corde, S.; Fitour, R.; Tafzi, A.; Burgy, F.; Douillet, D.; Lefrou, T.; Rousse, A.

    2008-12-01

    This paper presents the complete characterization of a kilo-electron-volt laser-based x-ray source. The main parameters of the electron motion (amplitude of oscillations and initial energy) in the laser wakefield have been investigated using three independent methods relying on spectral and spatial properties of this betatron x-ray source. First we will show studies on the spectral correlation between electrons and x-rays that is analyzed using a numerical code to calculate the expected photon spectra from the experimentally measured electron spectra. High-resolution x-ray spectrometers have been used to characterize the x-ray spectra within 0.8-3 keV and to show that the betatron oscillations lie within 1 µm. Then we observed Fresnel edge diffraction of the x-ray beam. The observed diffraction at the center energy of 4 keV agrees with the Gaussian incoherent source profile of full width half maximum <5 µm, meaning that the amplitude of the betatron oscillations is less than 2.5 µm. Finally, by measuring the far field spatial profile of the radiation, we have been able to characterize the electron's trajectories inside the plasma accelerator structure with a resolution better than 0.5 µm.

  13. Evaluation of silicon neutron resonance parameters in the thermal to 1800 keV energy range.

    PubMed

    Derrien, H; Leal, L C; Guber, K H; Larson, N M

    2005-01-01

    Because silicon is a major constituent of concrete and soil, neutron and gamma ray information on silicon is important for reactor shielding and criticality safety calculations. Therefore, much effort was put into the ENDF/B-VI evaluation for the three stable isotopes of silicon. The neutron capture cross section of natural silicon was recently measured at the Oak Ridge Electron Linear Accelerator (ORELA) in the energy range 1-700 keV. Using the ENDF/B-VI evaluation for initial values, a new evaluation of the resonance parameters was performed by adding the results of the ORELA capture measurements to the experimental database. The computer code SAMMY was used for the analysis of the experimental data; the new version of SAMMY allows accurate calculations of the self-shielding and multiple scattering effects in the capture measurements. The accuracy of the radiative capture widths of the resonances was improved by this analysis. Accurate values of the s-, p- and d-wave neutron strength functions were also obtained. Although the resonance capture component of the present evaluation is 2-3 times smaller than that in ENDF/B-VI, the total capture cross section is much larger, at least for energies >250 keV, because the direct capture component contributes values of the same order of magnitude as the resonance component. The direct component was not taken into account in the ENDF/B-VI evaluation and was calculated for the first time in the present evaluation.

  14. Improving accuracy and reliability of 186-keV measurements for unattended enrichment monitoring

    SciTech Connect

    Ianakiev, Kiril D; Boyer, Brian D; Swinhoe, Martyn T; Moss, Calvin E; Goda, Joetta M; Favalli, Andrea; Lombardi, Marcie; Paffett, Mark T; Hill, Thomas R; MacArthur, Duncan W; Smith, Morag K

    2010-04-13

    Improving the quality of safeguards measurements at Gas Centrifuge Enrichment Plants (GCEPs), whilst reducing the inspection effort, is an important objective given the number of existing and new plants that need to be safeguarded. A useful tool in many safeguards approaches is the on-line monitoring of enrichment in process pipes. One aspect of this measurement is a simple, reliable and precise passive measurement of the 186-keV line from {sup 235}U. (The other information required is the amount of gas in the pipe. This can be obtained by transmission measurements or pressure measurements). In this paper we describe our research efforts towards such a passive measurement system. The system includes redundant measurements of the 186-keV line from the gas and separately from the wall deposits. The design also includes measures to reduce the effect of the potentially important background. Such an approach would practically eliminate false alarms and can maintain the operation of the system even with a hardware malfunction in one of the channels. The work involves Monte Carlo modeling and the construction of a proof-of-principle prototype. We will carry out experimental tests with UF{sub 6} gas in pipes with and without deposits in order to demonstrate the deposit correction.

  15. 3.55 keV line from exciting dark matter without a hidden sector

    NASA Astrophysics Data System (ADS)

    Berlin, Asher; DiFranzo, Anthony; Hooper, Dan

    2015-04-01

    Models in which dark matter particles can scatter into a slightly heavier state which promptly decays to the lighter state and a photon (known as eXciting Dark Matter, or XDM) have been shown to be capable of generating the 3.55 keV line observed from galaxy clusters, while suppressing the flux of such a line from smaller halos, including dwarf galaxies. In most of the XDM models discussed in the literature, this up-scattering is mediated by a new light particle, and dark matter annihilations proceed into pairs of this same light state. In these models, the dark matter and the mediator effectively reside within a hidden sector, without sizable couplings to the Standard Model. In this paper, we explore a model of XDM that does not include a hidden sector. Instead, the dark matter both up-scatters and annihilates through the near resonant exchange of an O (1 02) GeV pseudoscalar with large Yukawa couplings to the dark matter and smaller, but non-neglibile, couplings to Standard Model fermions. The dark matter and the mediator are each mixtures of Standard Model singlets and S U (2 )W doublets. We identify parameter space in which this model can simultaneously generate the 3.55 keV line and the gamma-ray excess observed from the Galactic center, without conflicting with constraints from colliders, direct detection experiments, or observations of dwarf galaxies.

  16. Feasibility study for DEXA using synchrotron CT at 20-35 keV

    NASA Astrophysics Data System (ADS)

    Midgley, S. M.

    2013-02-01

    A nonlinear model for the x-ray linear attenuation coefficient μ is employed for dual energy x-ray analysis (DEXA). Nonlinear simultaneous equations formed by μ and energy dependent model parameters are solved for the electron density Ne and fourth compositional ratio R4 which has the same ‘units’ as the atomic number. Computed tomography data was acquired at 20-35 keV using bending magnet synchrotron radiation, a double crystal monochromator, a rotation stage and an area detector. Test objects contained liquid samples as mixtures of ethanol, water and salt solutions with known density and composition. Various noise sources are identified and give μ uncertainties of 1-2%. A fan beam geometry allowed the detection of forward scattered radiation with measured μ being 6% lower than expectations for a narrow beam. Energy dependent model parameters were obtained by solving linear simultaneous equations formed by μ and material parameters based upon Ne and R4. DEXA accuracy was studied as a function of photon energy and sample composition. Propagation of errors analysis identifies the importance of the fractional compositional cross-products whose difference at the two beam energies should exceed 0.1, requiring 10 keV or more separation. For a reasonable approximation for the adjustable model parameters, the mean difference between the DEXA solution and true values (ΔNe, ΔR4) are (1.0%, 0.5%) for soft tissue and (1.5%, 0.8%) for bone like samples.

  17. The 16 August 1997 Novaya Zemlya seismic event as viewed from GSN stations KEV and KBS

    SciTech Connect

    Hartse, H.E.

    1997-11-01

    Using current and historic seismic records from Global Seismic Network stations KEV and KBS, the authors find that S minus P arrival time comparisons between nuclear explosions and the 16 August 1997 seismic event (m{sub b} {approx} 3.6) from near Novaya Zemlya clearly indicate that (relative to KEV) the 16 August event occurred at least 80 km east of the Russian test site. Including S minus P arrival times from KBS constrains the location to beneath the Kara Sea and in good agreement with previously reported locations, over 100 km southeast of the test site. From an analysis of P{sub n}/S{sub n} waveform ratios at frequencies above 4 Hz, they find that the 16 August event falls within the population of regional earthquakes and is distinctly separated from Novaya Zemlya and other northern Eurasian nuclear explosion populations. Thus, given its location and waveform characteristics, they conclude the 16 August event was an earthquake. The 16 August event was not detected at teleseismic distances, and thus, this event provides a good example of the regional detection, location, and identification efforts that will be required to monitor the Comprehensive Test Ban Treaty below m{sub b} {approx} 4.

  18. Application of keV and MeV ion microbeams through tapered glass capillaries

    NASA Astrophysics Data System (ADS)

    Ikeda, T.; Kojima, T. M.; Kobayashi, T.; Meissl, W.; Mäckel, V.; Kanai, Y.; Yamazaki, Y.

    2012-11-01

    We have developed a method to produce micrometer-sized beams of keV energy highly charged ions (HCIs) and MeV energy protons/helium ions with tapered glass capillary optics for the applications of micrometer sized surface modifications and a biological tool, respectively. The transmission experiments of keV HCIs through the glass capillaries show a density enhancement of about 10, beam guiding up to 5°, and the extracted beam keeping the initial charge-state. The combination of MeV ion beams and the capillary with a thin end window at its outlet was used for the irradiation of a part of nucleus of a HeLa cell in culture solution. Escherichia coli cells are irradiated by MeV proton microbeam to determine the minimum dose to stop the single flagellar motor. Scanning irradiation of polymer surface by the beam extracted from the capillary in solution containing acrylic acid was found to provide a deposition layer with large affinity with water.

  19. Observation of 'Band' Structures in Spacecraft Observations of Inner Magnetosphere Plasma Electrons

    NASA Astrophysics Data System (ADS)

    Mohan Narasimhan, Kirthika; Fazakerley, Andrew; Milhaljcic, Branislav; Grimald, Sandrine; Dandouras, Iannis; Owen, Chris

    2013-04-01

    In previous studies, several authors have reported inner magnetosphere observations of proton distributions confined to narrow energy bands in the range of 1-25 keV. These structures have been known as "nose structures", with reference to their appearance in energy-time spectrograms and are known as "bands" if they are observed for extended periods of time. These proton structures have been studied quite extensively with multiple mechanisms proposed for their formation, not all of which apply for electrons. We examine Double-Star TC1 PEACE electron data recorded in the inner magnetosphere (L<15) near the equatorial plane to see if these features are also observed in the electron energy spectra. These "bands" also appear in electron spectrograms, spanning an energy range of 0.2-30 keV, and are shown to occur predominantly towards the dayside and dusk sectors. We also see multiple bands in some instances. We investigate the properties of these multi-banded structures and carry out a statistical survey analysing them as a function of geomagnetic activity, looking at both the Kp and Auroral Indices, in an attempt to explain their presence.

  20. Banded electromagnetic stator core

    DOEpatents

    Fanning, Alan W.; Gonzales, Aaron A.; Patel, Mahadeo R.; Olich, Eugene E.

    1996-01-01

    A stator core for an electromagnetic pump includes a plurality of circumferentially adjoining groups of flat laminations disposed about a common centerline axis and collectively defining a central bore and a discontinuous outer perimeter, with adjacent groups diverging radially outwardly to form V-shaped gaps. An annular band surrounds the groups and is predeterminedly tensioned to clamp together the laminations, and has a predetermined flexibility in a radial direction to form substantially straight bridge sections between the adjacent groups.

  1. Banded electromagnetic stator core

    DOEpatents

    Fanning, A.W.; Gonzales, A.A.; Patel, M.R.; Olich, E.E.

    1994-04-05

    A stator core for an electromagnetic pump includes a plurality of circumferentially adjoining groups of flat laminations disposed about a common centerline axis and collectively defining a central bore and a discontinuous outer perimeter, with adjacent groups diverging radially outwardly to form V-shaped gaps. An annular band surrounds the groups and is predeterminedly tensioned to clamp together the laminations, and has a predetermined flexibility in a radial direction to form substantially straight bridge sections between the adjacent groups. 5 figures.

  2. Banded electromagnetic stator core

    DOEpatents

    Fanning, Alan W.; Gonzales, Aaron A.; Patel, Mahadeo R.; Olich, Eugene E.

    1994-01-01

    A stator core for an electromagnetic pump includes a plurality of circumferentially adjoining groups of flat laminations disposed about a common centerline axis and collectively defining a central bore and a discontinuous outer perimeter, with adjacent groups diverging radially outwardly to form V-shaped gaps. An annular band surrounds the groups and is predeterminedly tensioned to clamp together the laminations, and has a predetermined flexibility in a radial direction to form substantially straight bridge sections between the adjacent groups.

  3. Banded electromagnetic stator core

    DOEpatents

    Fanning, A.W.; Gonzales, A.A.; Patel, M.R.; Olich, E.E.

    1996-06-11

    A stator core for an electromagnetic pump includes a plurality of circumferentially adjoining groups of flat laminations disposed about a common centerline axis and collectively defining a central bore and a discontinuous outer perimeter, with adjacent groups diverging radially outwardly to form V-shaped gaps. An annular band surrounds the groups and is predeterminedly tensioned to clamp together the laminations, and has a predetermined flexibility in a radial direction to form substantially straight bridge sections between the adjacent groups. 5 figs.

  4. Wideband S Band Transmitter

    DTIC Science & Technology

    1989-10-01

    the phase variations across a +/-I nanosecond compressed pulse . During experimentation in the RADC Module Evaluation Lab the paired echos could be...22 4-11. Pulsing Interlock ....................................... 23 4-12. Pulse Fault Detector and Fault Summary...band transmitter was built by RCA Corporation under contract F30602-78-C-0122, titled "Wideband Amplifier, P/O Digitally Coded Radar’. After use by

  5. Micromechanics of shear banding

    SciTech Connect

    Gilman, J.J.

    1992-08-01

    Shear-banding is one of many instabilities observed during the plastic flow of solids. It is a consequence of the dislocation mechanism which makes plastic flow fundamentally inhomogeneous, and is exacerbated by local adiabatic heating. Dislocation lines tend to be clustered on sets of neighboring glide planes because they are heterogeneously generated; especially through the Koehler multiple-cross-glide mechanism. Factors that influence their mobilities also play a role. Strain-hardening decreases the mobilities within shear bands thereby tending to spread (delocalize) them. Strain-softening has the inverse effect. This paper reviews the micro-mechanisms of these phenomena. It will be shown that heat production is also a consequence of the heterogeneous nature of the microscopic flow, and that dislocation dipoles play an important role. They are often not directly observable, but their presence may be inferred from changes in thermal conductivity. It is argued that after deformation at low temperatures dipoles are distributed a la Pareto so there are many more small than large ones. Instability at upper yield point, the shapes of shear-band fronts, and mechanism of heat generation are also considered. It is shown that strain-rate acceleration plays a more important role than strain-rate itself in adiabatic instability.

  6. Biological Degradation of 2,4,6-Trinitrotoluene

    PubMed Central

    Esteve-Núñez, Abraham; Caballero, Antonio; Ramos, Juan L.

    2001-01-01

    Nitroaromatic compounds are xenobiotics that have found multiple applications in the synthesis of foams, pharmaceuticals, pesticides, and explosives. These compounds are toxic and recalcitrant and are degraded relatively slowly in the environment by microorganisms. 2,4,6-Trinitrotoluene (TNT) is the most widely used nitroaromatic compound. Certain strains of Pseudomonas and fungi can use TNT as a nitrogen source through the removal of nitrogen as nitrite from TNT under aerobic conditions and the further reduction of the released nitrite to ammonium, which is incorporated into carbon skeletons. Phanerochaete chrysosporium and other fungi mineralize TNT under ligninolytic conditions by converting it into reduced TNT intermediates, which are excreted to the external milieu, where they are substrates for ligninolytic enzymes. Most if not all aerobic microorganisms reduce TNT to the corresponding amino derivatives via the formation of nitroso and hydroxylamine intermediates. Condensation of the latter compounds yields highly recalcitrant azoxytetranitrotoluenes. Anaerobic microorganisms can also degrade TNT through different pathways. One pathway, found in Desulfovibrio and Clostridium, involves reduction of TNT to triaminotoluene; subsequent steps are still not known. Some Clostridium species may reduce TNT to hydroxylaminodinitrotoluenes, which are then further metabolized. Another pathway has been described in Pseudomonas sp. strain JLR11 and involves nitrite release and further reduction to ammonium, with almost 85% of the N-TNT incorporated as organic N in the cells. It was recently reported that in this strain TNT can serve as a final electron acceptor in respiratory chains and that the reduction of TNT is coupled to ATP synthesis. In this review we also discuss a number of biotechnological applications of bacteria and fungi, including slurry reactors, composting, and land farming, to remove TNT from polluted soils. These treatments have been designed to achieve

  7. Infrared imaging of Mars for volatile distribution and seasonal variability between 2.4 and 5.1 microns

    NASA Technical Reports Server (NTRS)

    Blaney, Diana L.

    1992-01-01

    Recent advances in ground-based infrared imaging now allow for sub-arc second spectral imaging. Data collected at the NASA Infrared Telescope Facility using protocam, a 62 x 58 InSb array camera with a circular variable filter and a plate scale 0.2 arc-seconds/pixel, are discussed. These images are a first attempt at extended seasonal infrared coverage of Mars to look for seasonal variations. Currently, data collected in Jun. 1990 at Ls = 241 (southern spring) and in Jan. 1991 Ls = 360 (late southern summer) are being reduced and analyzed. The 3 micron bound water band is the strongest surface absorption feature on Mars in the infrared. Infrared spectroscopy can also be useful in the detection of ice and frost deposits, especially in the polar regions. While imaging and spectroscopy at visible wavelengths allows for the detection of condensates, infrared information is needed to distinguish between water and CO2 ice/frost deposits. In the Jun. images, the southern polar cap totally disappears in the 3.4 micron CO2 frost band and is bright in the 3.1 micron water ice band, indicating that water ice is not a detectable component of the southern polar cap at this season. Further investigations are currently under way to look for residual water ice after the disappearance of the seasonal south polar cap in the Jan. images. The Jun. images that were focused on had a sub-earth point located at 184 longitude, and 23.8 S latitude which put the center of the disk in the southern highland region between Elysium and Amazonis. Examination of the Jun. images show that there are four surface units identifiable: a CO2 frost deposit, a northern plains unit, an equatorial unit, and a southern highland unit. At this resolution there does not appear to be any latitudinal variations in the 3 micron band that is independent of the 2.4 micron albedo features. The northern planes unit and the southern highland unit have very similar 'color' in the three micron band as demonstrated by the

  8. A multitude of rotational bands in {sup 163}Er and their mutual interaction

    SciTech Connect

    Bosetti, P.; Leoni, S.; Bracco, A.

    1996-12-31

    Using the {sup 150}Nd({sup 18}O, 5n){sup 163}Er reaction a multitude of rotational bands have been established with firm spin and parity assignments in {sup 163}Er. In 16 out of {approximately} 23 band crossings E2 cross-band transitions have been observed. The interaction strength varies between {approximately} 1 and {approximately} 50 keV. These interactions sample a variety of the lowest (multi)-quasiparticle configurations. Some of the band configurations, in particular those with high K-values, can be rather well established. Quite complicated changes in the wavefunctions must occur at these crossings, and, to explain the observed interaction strengths, one may have to invoke coupling to various vibrational degrees of freedom, in addition to possible residual neutron-proton interactions.

  9. Identification of a quasiparticle band in very neutron-rich {sup 104}Zr

    SciTech Connect

    Yeoh, E. Y.; Wang, J. G.; Ding, H. B.; Gu, L.; Xu, Q.; Xiao, Z. G.; Zhu, S. J.; Hamilton, J. H.; Ramayya, A. V.; Hwang, J. K.; Liu, S. H.; Liu, Y. X.; Sun, Y.; Luo, Y. X.; Rasmussen, J. O.; Lee, I. Y.

    2010-08-15

    The high spin levels of a very neutron-rich {sup 104}Zr nucleus have been reinvestigated by measuring the prompt {gamma} rays in the spontaneous fission of {sup 252}Cf. The ground-state band has been confirmed. A new sideband has been identified with a band-head energy at 1928.7 keV. The projected shell model is employed to investigate the band structure of {sup 104}Zr. The results of calculated levels are in good agreement with the experimental data, and suggest that the new band in {sup 104}Zr may be based on the neutron {nu}5/2{sup -}[532] x {nu}3/2{sup +}[411] configuration.

  10. Synthesis and characterization of zinc oxide nanorods and its photocatalytic activities towards degradation of 2,4-D.

    PubMed

    Meenakshi, G; Sivasamy, A

    2017-01-01

    Semiconductor zinc oxide nanorods (NRZnO) were prepared by sol-gel technique using zinc acetate as the precursor and ammonia as the precipitating agent. The prepared photocatalyst were characterized by X-ray diffraction (XRD), Fourier Transform Infrared (FTIR), UV-Visible diffuse reflectance spectroscopy (UV-Vis-DRS), X-ray photoelectron spectroscopy (XPS), Field Emission-Scanning Electron Microscopy (FE-SEM), Atomic Force Microscopy (AFM), High Resolution-Tunneling Microscope (HR-TEM), Brunauer, Emmett and Teller (BET) and electron paramagnetic resonance spectroscopy (EPR) analysis. Particle size of the prepared photocatalyst was established by XRD and FE-SEM analysis. The morphology and the formation of uniform NRZnO was controlled by the temperature, entire concentration of precursors, duration of aging process. High surface roughness and porosity confirmed by AFM analysis. Band gap energy of the synthesized photocatalyst (3.2eV) was determined by using diffuse reflectance spectroscopy. The in-situ production of OH radicals by the prepared photocatalyst was confirmed by electron paramagnetic resonance spectroscopy (EPR) spin trapping technique. The photocatalytic activity of prepared NRZnO was evaluated by photo degradation of 2, 4-dichlorophenoxyacetic acid (2, 4-D) under UV and visible light irradiations. Experimental parameter such as effect of pH, catalyst dosage, initial 2, 4- D concentrations and addition of different electrolytes on the degradation of 2, 4-D was also studied in detail. Neutral pH was found to be the optimum and catalyst dosage of 30mg/10ml resulted in higher percentage of degradation. The photo degraded samples were analyzed by chemical oxygen demand (COD) analysis, UV-Visible spectroscopy. Reusability of the prepared photocatalyst was tested upto three cycles without affecting its performance. The experimental shown the rate of degradation follows pseudo-first order rate kinetics with respect to 2, 4 D.

  11. Compounds 2,4,6-trinitrotoluene and 2,4-diamino-6-nitrotoluene: The absence of recA-dependent mutagenesis

    SciTech Connect

    Karamova, N.S.; Mynina, I.I.; Garaeva, G.G.

    1995-05-01

    The genotoxicity of 2,4,6-trinitrotoluene (2,4,6-TNT) and its amino derivative, 2,4-diamino-6-nitrotoluene (2,4-DA-6-NT), was studied using the Escherichia coli tester strain PQ37 in the SOS chromotest. The compound 2,4,6-TNT, without metabolic activation, virtually failed to induce an SOS effect in cells of the tester bacteria. Consequently, mutagenic activity of 2,4,6-TNT, which was shown earlier in the Ames test, does not depend on SOS mutagenesis. It was demonstrated that metabolic activation with the microsomal S9 human placenta fraction results in a threefold increase in the induction factor of the SOS effect caused by 2,4,6-TNT. The absence of the SOS-inducing activity of 2,4-DA-6-NT, regardless of the presence of a microsomal activating mixture, is shown. Thus, 2,4-DA-6-NT does not belong to metabolites of 2,4,6-TNT, responsible for the genotoxicity of this compound. 25 refs., 1 fig., 2 tabs.

  12. Band crossing in a shears band of {sup 108}Cd

    SciTech Connect

    Roy, Santosh; Datta, Pradip; Pal, S.; Chattopadhyay, S.; Bhattacharya, S.; Goswami, A.; Jain, H. C.; Joshi, P. K.; Bhowmik, R. K.; Kumar, R.; Muralithar, S.; Singh, R. P.; Madhavan, N.; Rao, P. V. Madhusudhana

    2010-05-15

    The level lifetimes have been measured for a shears band of {sup 108}Cd that exhibits band crossing. The observed level energies and B(M1) rates have been successfully described by a semiclassical geometric model based on shear mechanism. In this geometric model, the band crossing in the shears band has been described as the reopening of the angle between the blades of a shear.

  13. The ISO-SWS 2.4-45.2 Micron Spectrum Toward Orion IR c2

    NASA Astrophysics Data System (ADS)

    van Dishoeck, Ewine F.; Wright, Christopher M.; Cernicharo, José; González-Alfonso, Eduardo; de Graauw, Thijs; Helmich, Frank P.; Vandenbussche, Bart

    1998-08-01

    The complete infrared spectrum from 2.4 to 45.2 μm toward the prototypical massive star-forming region Orion IRc2 is presented, obtained with the Short Wavelength Spectrometer (SWS) on board the Infrared Space Observatory (ISO) at a resolving power λ/Δλ~1300-2500. A wealth of emission and absorption features is found, including H2 vibration-rotation lines, the full set of H2 pure rotational lines (0,0) S(1)-S(17), H recombination lines, ionic fine-structure lines, PAH emission features, and absorption and emission bands by interstellar ices and gas-phase molecules, including CO2, CH4, and SO2. Particularly interesting is the detection of strong emission and absorption lines in the H2O ν2 bending mode at 6.2 μm and the observation of highly excited pure rotational lines of H2O in absorption at 25-45 μm. The origin of these lines in each of the physical components included in the ISO-SWS beam (H II region, PDR, quiescent ridge, shocked low-velocity plateau) is briefly discussed. Based on observations with ISO, an ESA project with instruments funded by ESA Member States (especially the PI countries France, Germany, the Netherlands, and the United Kingdom) and with participation of ISAS and NASA.

  14. Crystallographic structure of a photoreceptor protein at 2.4 A resolution.

    PubMed

    McRee, D E; Tainer, J A; Meyer, T E; Van Beeumen, J; Cusanovich, M A; Getzoff, E D

    1989-09-01

    The first essential step in protein photoreception is the capture and storage of energy from a photon. We have recently identified and isolated, from the purple photoautotrophic bacterium, Ectothiorhodospira halophila, a 13,000-dalton photoactive yellow protein (PYP) that has a photocycle with kinetics similar to sensory rhodopsin and a very high quantum efficiency. To study the structural chemistry of protein photoreception, we determined, refined, and analyzed the crystallographic structure of PYP at 2.4 A resolution and report here that it is composed of two perpendicular antiparallel beta-sheets that enclose the chromophore. Each of the 10 beta-strands of PYP is connected directly to its nearest neighbor with +1 topology. Globally, an asymmetric distribution of side chains places aromatic and acidic side chains in an ellipsoidal band around the chromophore with a cluster of basic side chains on one side. Locally, the electron density maps place an internal lysine and the chromophore in an apparent Schiff base linkage stabilized by a buried glutamate and a tyrosine side chain. To our knowledge, the atomic resolution structure of a protein with a reversible photoisomerization has not been reported previously. Furthermore, PYP may also represent a class of proteins that bind conjugated molecules and interact with a secondary receptor system.

  15. Investigations into the origin of the spurious 17 keV neutrino signal observed in35S beta decay

    NASA Astrophysics Data System (ADS)

    Bowler, M. G.; Jelley, N. A.

    1995-09-01

    An exhaustive study has been made of the β spectrum of35S, recorded with a Si(Li) detector. The object was to identify the origin of a distortion in the35S β spectrum some 17 keV below the end point, reported over three years ago and interpreted then as evidence for a 17 keV neutrino. Measurements with different source-detector spacings and with varied collimation have shown that there is a long range curvature in the Kurie plot which is a sensitive function of configuration, but the principal origin of the distortion is energy loss in the35S sources. The35S sources, prepared by chemical adsorption of Ba35SO4 on a gold substrate, are clumped and locally thick. Electrons near the end point lose ˜0.3 keV in the source material and if this is taken into account the spectra are well fitted without any admixture of 17 keV neutrino. The source thickness has been investigated with a proton microprobe and determined from both source tilting and the yield of barium K X-rays; these studies are discussed in detail. The uncertainties in and justification for the form of the electron response function employed are also thoroughly discussed. If there is no systematic error common to the majority of 14 independent sets of35S data, the admixture of 17 keV neutrino is <10-3 (95% CL). A simple search for a kink at 150 keV in the combined data from all 14 runs yielded a limit of 1.8×10-3 (95% CL). The end point of the35S β spectrum is found to be 167.60±0.05 keV.

  16. Reduction of 2,4-dinitrotoluene by Wistar rat liver microsomal and cytosol fractions.

    PubMed

    Mori, M; Matsuhashi, T; Miyahara, T; Shibata, S; Izima, C; Kozuka, H

    1984-10-01

    2,4-Dinitrotoluene (2,4-DNT) is an important industrial nitroaromatic compound. 2,4-Diaminotoluene (2,4-DAT), one of the urinary metabolites of 2,4-DNT, is carcinogenic when fed to rats. The objectives of these studies were to determine whether 2,4-DAT was formed from 2,4-DNT in rat liver and to clarify the nature of enzymes responsible for reduction of 2,4-DNT to 2,4-DAT. Data obtained from thin-layer and high-pressure liquid chromatography indicated that metabolites produced by microsomal preparations were 2-amino-4-nitrotoluene (2A4NT) and its isomer (4A2NT). This microsomal activity is probably mediated by cytochrome P-450 because the reduction is blocked by carbon monoxide and primary amines [aniline, n-octylamine, and 2,4-dichloro-6-phenylphenoxyethylamine (DPEA)]. In contrast, 2,4-DNT was metabolized via 2A4NT and 4A2NT to 2,4-DAT by cytosolic preparations. The greatest part of the reduction activity was due to cytosolic xanthine oxidase because the reduction was blocked by allopurinol. The results of this investigation suggest that reduction of 2,4-DNT to 2,4-DAT by cytosolic xanthine oxidase may play a role in 2,4-DNT hepatocarcinogenicity.

  17. Syn/anti isomerization of 2,4-dinitrophenylhydrazones in the determination of airborne unsymmetrical aldehydes and ketones using 2,4-dinitrophenylhydrazine derivation.

    PubMed

    Binding, N; Müller, W; Witting, U

    1996-10-01

    Aldehydes and ketones readily react with 2,4-dinitrophenylhydrazine (2,4-DNPH) to form the corresponding hydrazones. This reaction has been frequently used for the quantification of airborne carbonyl compounds. Since unsymmetrical aldehydes and ketones are known to form isomeric 2,4-dinitrophenylhydrazones (syn/ anti-isomers), the influence of isomerization on the practicability and accuracy of the 2,4-DNPH-method using 2,4-dinitrophenylhydrazine-coated solid sorbent samplers has been studied with three ketones (methyl ethyl ketone (MEK), methyl isopropyl ketone (MIPK), and methyl isobutyl ketone (MIBK)). With all three ketones the reaction with 2,4-DNPH resulted in mixtures of the isomeric hydrazones which were separated by HPLC and GC and identified by mass spectroscopy and (1)H nuclear magnetic resonance spectroscopy. The isomers show similar chromatographic behaviour in HPLC as well as in GC, thus leading to problems in quantification and interpretation of chromatographic results.

  18. Noise exposure in marching bands

    NASA Astrophysics Data System (ADS)

    Keefe, Joseph

    2005-09-01

    Previous studies involving orchestras have shown that music ensembles can produce hazardous noise levels. There are no similar data for marching bands and pep bands. In order to evaluate the noise levels produced by marching and pep bands, 1/3-octave-band sound-pressure levels were measured while these groups rehearsed and performed. Data were collected while marching with the bands to ensure a realistic environment. Comparing these data to OSHA and NIOSH criteria, marching and pep band exposures often exceed safe values. For typical exposures, OSHA doses range from 11% to 295%, while NIOSH doses range from 35% to 3055%. Exposures that would be considered hazardous in the workplace are common in marching and pep bands; students and band directors should take steps to recognize the risk posed by various instruments and various locations, and should implement hearing conservation efforts.

  19. Magnetic field design for a Penning ion source for a 200 keV electrostatic accelerator

    NASA Astrophysics Data System (ADS)

    Fathi, A.; Feghhi, S. A. H.; Sadati, S. M.; Ebrahimibasabi, E.

    2017-04-01

    In this study, the structure of magnetic field for a Penning ion source has been designed and constructed with the use of permanent magnets. The ion source has been designed and constructed for a 200 keV electrostatic accelerator. With using CST Studio Suite, the magnetic field profile inside the ion source was simulated and an appropriate magnetic system was designed to improve particle confinement. Designed system consists of two ring magnets with 9 mm distance from each other around the anode. The ion source was constructed and the cylindrical magnet and designed magnetic system were tested on the ion source. The results showed that the ignition voltage for ion source with the designed magnetic system is almost 300 V lower than the ion source with the cylindrical magnet. Better particle confinement causes lower voltage discharge to occur.

  20. Neutral beam injector for 475 keV MARS sloshing ions

    SciTech Connect

    Goebel, D.M.; Hamilton, G.W.

    1983-12-13

    A neutral beam injector system which produces 5 MW of 475 keV D/sup 0/ neutrals continuously on target has been designed. The beamline is intended to produce the sloshing ion distribution required in the end plug region of the conceptual MARS tandem mirror commercial reactor. The injector design utilizes the LBL self-extraction negative ion source and Transverse Field Focusing (TFF) accelerator to generate a long, ribbon ion beam. A laser photodetachment neutralizer strips over 90% of the negative ions. Magnetic and neutron shield designs are included to exclude the fringe fields of the end plug and provide low activation by the neutron flux from the target plasma. The use of a TFF accelerator and photodetachment neutralizer produces a total system electrical efficiency of about 63% for this design.

  1. Preliminary resolved resonance region evaluation of copper-63 from 0 to 300 keV

    SciTech Connect

    Sobes, V.; Forget, B.; Leal, L.; Guber, K.

    2012-07-01

    A new preliminary evaluation of Cu-63 was done in the energy region from 0 to 300 keV extending the resolved resonance region of the previous, ENDF/B-VII.0, evaluation three-fold. The new evaluation was based on three experimental transmission data sets; two measured at the Oak Ridge Electron Linear Accelerator (ORELA) and one from the Massachusetts Inst. of Technology Nuclear Reactor (MITR). A total of 275 new resonances were identified and a corresponding set of external resonances was approximated to mock up the external levels. The negative external levels (bound level) were modified to match the thermal cross section values. A preliminary benchmarking calculation was made using 11 ICSBEP benchmarks. This work is in support of the DOE Nuclear Criticality Safety Program. (authors)

  2. Microstructural investigation of alumina implanted with 30 keV nitrogen ions

    NASA Astrophysics Data System (ADS)

    Shikha, Deep; Jha, Usha; Sinha, S. K.; Barhai, P. K.; Sarkhel, G.; Nair, K. G. M.; Dash, S.; Tyagi, A. K.; Kothari, D. C.

    2007-11-01

    Among ceramics, alumina is being widely used as biomaterials now these days. It is being used as hip joints, tooth roots etc. Ion implantation has been employed to modify its surface without changing it bulk properties. 30 keV nitrogen with varying ion dose ranging from 5 × 10 15 ions/cm 2 to 5 × 10 17 ions/cm 2 is implanted in alumina. Surface morphology has been studied with optical microscope and atomic force microscope (AFM). Improvement in brittleness has been observed with the increase in ion dose. Compound formation and changes in grain size have been studied using X-Ray diffraction (XRD). AlN compound formation is also observed by Fourier transform infrared spectroscopy (FTIR). The change in the grain size is related with the nanohardness and Hall-Petch relationship is verified.

  3. A microwave beam waveguide undulator for a brilliant above 100 keV photon source.

    SciTech Connect

    Kang, Y. W.

    1999-04-19

    For generation of photons above 100-keV with a magnetic field strength in the range 0.2-0.5 Tesla, an undulator wavelength {lambda}{sub u} shorter than 5 mm may be needed with beam in the Advanced Photon Source (APS) storage ring. A microwave beam waveguide undulator system has been investigated for generation of such light. The waveguide structure consists of two parallel reflector surfaces that can be derived from an elliptically cylindrical waveguide. The structure can support deflecting TE{sub m0} modes with very low microwave loss. A microwave ring resonator circuit employing the beam waveguide is considered to construct an undulator with the above requirement. Microwave properties of the beam waveguide structure have been investigated, and the design criteria for a microwave undulator are discussed.

  4. Charge transfer and excitation in H++CH3 collisions below 10keV

    NASA Astrophysics Data System (ADS)

    Nagao, Masatoshi; Hida, Ken-Nosuke; Kimura, Mineo; Rai, Sachchida N.; Liebermann, Heinz-Peter; Buenker, Robert J.; Suno, Hiroya; Stancil, Phillip C.

    2008-07-01

    Charge transfer and electronic excitation in collisions of H+ ions with CH3 from a few tens of eV up to 10keV are theoretically investigated. The adiabatic potential energy curves and corresponding wave functions are calculated by using the multireference single- and double-excitation configuration interaction method, and the scattering dynamics is studied based on the semiclassical impact parameter molecular-orbital close-coupling approach. Charge-transfer cross sections are found to be large and rather energy-dependent over the entire energy region studied. Electronic excitation is also energy-dependent with a sharp increase from below 10-17to10-16cm2 . Most of the molecular products produced through charge transfer or excitation are known to be unstable and undergo fragmentation producing various hydrocarbon radical species. Hence, identification of fragmented species and their production mechanism are important for spectroscopic analysis.

  5. Irradiation effects on secondary structure of protein induced by keV ions

    NASA Astrophysics Data System (ADS)

    Cui, F. Z.; Lin, Y. B.; Zhang, D. M.; Tian, M. B.

    2001-01-01

    Protein secondary structure changes by low-energy ion irradiation are reported for the first time. The selected system is 30 keV N + irradiation on bovine serum albumin (BSA). After irradiation at increasing fluences from 1.0×10 15 to 2.5×10 16 ion/cm 2, Fourier transform infrared spectra analysis was conducted. It was found that the secondary structures of BSA molecules were very sensitive to ion irradiation. Secondary conformations showed different trends of change during irradiation. With the increase of ion fluence from 0 to 2.5×10 16 ion/cm 2, the fraction of α-helix and β-turns decreased from 17 to 12%, and from 40 to 31%, respectively, while that of random coil and β-sheet structure increased from 18 to 27%, and from 25 to 30%, respectively. Possible explanations for the secondary conformational changes of protein are proposed.

  6. 100 keV 10-B + implantation into poly-(di-n-hexyl silane), (PDHSi)

    NASA Astrophysics Data System (ADS)

    Fink, D.; Müller, M.; Behar, M.; Papaleo, R. M.

    2006-07-01

    100 keV10B+ ions were implanted into poly-(di-n-hexyl silane) in different directions at a fluence of 1×1014 cm-2, and their depth distribution was determined by means of the neutron depth profiling technique. In no case were the projectile ions found to come to rest according to their predicted range profiles. Instead, they are always found to undergo considerable long-range migration. During the irradiation process this motion appears to be radiation-enhanced, and during the subsequent annealing steps one appears to deal with regular thermal diffusion. The implant redistribution is always found to be governed strongly by the self-created damage, insofar as both electronic and nuclear defects in the polymer act as trapping centers. Their population ratio is modified by thermal annealing.

  7. Electron Bremsstrahlung Cross Sections at 25 and 50 keV from Xe and Kr

    NASA Astrophysics Data System (ADS)

    Portillo, Salvador; Quarles, C. A.

    2002-05-01

    Absolute doubly differential bremsstrahlung cross sections for radiation at 90 from 25 and 50 keV electron bombardment of Kr and Xe of will be presented. The electrons were accelerated by a Cockcroft - Walton accelerator into an Al chamber through a .06" Al collimator. Thick target bremsstrahlung background was minimized by having Al nipples and fixtures and by the addition of a carbon lined nipple placed at 180 to the SiLi detector. A comparison of the doubly differential cross sections will be made with current bremsstrahlung theories. The ratio of the Kr and Xe cross sections will also be compared with the theoretical cross section ratios. The ratio provides a more sensitive test of the contribution, if any, of polarization bremsstrahlung.

  8. Effects of 70-keV electrons on two polyarylene ether ketones

    NASA Technical Reports Server (NTRS)

    Kingsbury, Kevin B.; Hawkins, Douglas S.; Orwoll, Robert A.; Kiefer, Richard L.; Long, Sheila A. T.

    1989-01-01

    Films prepared from two polyarylene ether ketones with the repeat units -PhC(O)PhC(O)-PhOPhXPhO- where X = C(CH3)2 or CH2 and Ph = C6H4, were bombarded with 70-keV electrons. The effects of irradiation were determined from the fraction of gel formed; the intrinsic viscosities, gel permeation chromatography, and NMR spectroscopy of the soluble portion of the irradiated films; and the changes in the IR spectra of the materials. In a Charlesby-Pinner analysis of the gel fractions of the polyarylene ether ketone with the isopropylidene group, the numbers of scission and cross-linking events per 100 eV (9649 kJ/mol) absorbed were found to be small with G(S) = 0.002 and G(X) = 0.009, respectively.

  9. 350 keV accelerator based PGNAA setup to detect nitrogen in bulk samples

    NASA Astrophysics Data System (ADS)

    Naqvi, A. A.; Al-Matouq, Faris A.; Khiari, F. Z.; Gondal, M. A.; Rehman, Khateeb-ur; Isab, A. A.; Raashid, M.; Dastageer, M. A.

    2013-11-01

    Nitrogen concentration was measured in explosive and narcotics proxy material, e.g. anthranilic acid, caffeine, melamine, and urea samples, bulk samples through thermal neutron capture reaction using 350 keV accelerator based prompt gamma ray neutron activation (PGNAA) setup. Intensity of 2.52, 3.53-3.68, 4.51, 5.27-5.30 and 10.38 MeV prompt gamma rays of nitrogen from the bulk samples was measured using a cylindrical 100 mm×100 mm (diameter×height ) BGO detector. Inspite of interference of nitrogen gamma rays from bulk samples with capture prompt gamma rays from BGO detector material, an excellent agreement between the experimental and calculated yields of nitrogen gamma rays has been obtained. This is an indication of the excellent performance of the PGNAA setup for detection of nitrogen in bulk samples.

  10. Ion source development for the proposed FNAL 750keV injector upgrade

    SciTech Connect

    Bollinger, D.S.; /Fermilab

    2010-11-01

    Currently there is a Proposed FNAL 750keV Injector Upgrade for the replacement of the 40 year old Fermi National Laboratory (FNAL) Cockcroft-Walton accelerators with a new ion source and 200MHz Radio Frequency Quadruple (RFQ). The slit type magnetron being used now will be replaced with a round aperture magnetron similar to the one used at Brookhaven National Lab (BNL). Operational experience from BNL has shown that this type of source is more reliable with a longer lifetime due to better power efficiency. The current source development effort is to produce a reliable source with >60mA of H- beam current, 15Hz rep-rate, 100s pulse width, and a duty factor of 0.15%. The source will be based on the BNL design along with development done at FNAL for the High Intensity Neutrino Source (HINS).

  11. A search for the 478 keV line from the decay of nucleosynthetic Be-7

    NASA Technical Reports Server (NTRS)

    Harris, Michael J.; Leising, Mark D.; Share, Gerald H.

    1991-01-01

    Unstable Be-7 (half-life 53.28 days) is expected to be present in the ejecta of classical novae. If the frequency of novae in the central Galaxy is high enough, a nearly steady state abundance of Be-7 will be present there. Data accumulated during transits of the Galactic center across the aperture of the Solar Maximum Mission Gamma Ray Spectrometer have been searched for evidence of the 478 keV gamma-ray line resulting from Be-7 decay. A 3-sigma upper limit of 0.00016 gamma/sq cm s has been placed on the emission in this line from the central radian of the Galactic plane. Less stringent limits have been set on the production of Be-7 in Nova Aquilae 1982, Nova Vulpeculae 1984 No. 2, and Nova Centauri 1986 from observations with the same instrument.

  12. Laser acceleration and deflection of 963 keV electrons with a silicon dielectric structure

    DOE PAGES

    Leedle, Kenneth J.; Pease, R. Fabian; Byer, Robert L.; ...

    2015-02-12

    Radio frequency particle accelerators are ubiquitous in ultrasmall and ultrafast science, but their size and cost have prompted exploration of compact and scalable alternatives such as the dielectric laser accelerator. We present the first demonstration, to the best of our knowledge, of high gradient laser acceleration and deflection of electrons with a silicon structure. Driven by a 5 nJ, 130 fs mode-locked Ti:sapphire laser at 907 nm wavelength, our devices achieve accelerating gradients in excess of 200 MeV/m and suboptical cycle streaking of 96.30 keV electrons. These results pave the way for high gradient silicon dielectric laser accelerators using commercialmore » lasers and subfemtosecond electron beam experiments.« less

  13. Recent Updates on the Searches for the 3.55 keV Line

    NASA Astrophysics Data System (ADS)

    Bulbul, Esra; Miller, Eric D.; Bautz, Mark W.

    2016-04-01

    The abundance of ubiquitous dark matter is now well quantified by observations, yet its nature remains unknown. Dark matter is believed to be composed primarily of an elementary particle. The search for this particle is one of the major efforts in astrophysics and particle physics today. X-ray observations of dark matter dominated objects have the potential to reveal a signal from decaying or annihilating dark matter. We previously reported the detection of an unidentified emission line at 3.55 keV in the stacked XMM-Newton observations of galaxy clusters. The origin of this unidentified line could be attributed to the decay of dark matter particles. I will present the new results from the stacked Suzaku observations of galaxy clusters and provide a comprehensive review on the detections and limits in the literature.

  14. Auroral electrons of energy less than 1 keV observed at rocket altitudes.

    NASA Technical Reports Server (NTRS)

    Arnoldy, R. L.; Choy, L. W.

    1973-01-01

    Measurements of electrons of energy less than 1 keV in the auroral precipitation with detectors aboard three rocket flights are discussed. Detectors simultaneously measured the flux of electrons moving up and down the magnetic field lines. Electrons of energy less than a few hundred electron volts show directional intensities ranging from isotropic over the upper hemisphere, to field aligned into the atmosphere, to a net streaming out of the atmosphere. Cases of reflection coefficients greater than 1 for the few hundred electron volts and lower-energy electrons occur when measurements were made north of auroral forms. These electrons might represent the high-energy tail of the return Birkeland currents. The origin of the low-energy electrons is itself in question.

  15. MOLECULAR DYNAMICS OF CASCADES OVERLAP IN TUNGSTEN WITH 20-KEV PRIMARY KNOCK-ON ATOMS

    SciTech Connect

    Setyawan, Wahyu; Nandipati, Giridhar; Roche, Kenneth J.; Kurtz, Richard J.; Wirth, Brian D.

    2015-04-16

    Molecular dynamics simulations are performed to investigate the mutual influence of two subsequent cascades in tungsten. The influence is studied using 20-keV primary knock-on atoms, to induce one cascade after another separated by 15 ps, in a lattice temperature of 1025 K (i.e. 0.25 of the melting temperature of the interatomic potential). The center of mass of the vacancies at the peak damage during the cascade is taken as the location of the cascade. The distance between this location to that of the next cascade is taken as the overlap parameter. Empirical fits describing the number of surviving vacancies and interstitial atoms as a function of overlap are presented.

  16. Laboratory source based full-field x-ray microscopy at 9 keV

    SciTech Connect

    Fella, C.; Balles, A.; Wiest, W.; Zabler, S.; Hanke, R.

    2016-01-28

    In the past decade, hard x-ray transmission microscopy experienced tremendous developments. With the avail-ability of efficient Fresnel zone plates, even set-ups utilizing laboratory sources were developed [1]. In order to improve the performance of these x-ray microscopes, novel approaches to fabricate optical elements [2] and brighter x-ray tubes [3] are promising candidates. We are currently building a laboratory transmission x-ray microscope for 9.25 keV, using an electron impact liquid-metal-jet anode source. Up to now, the further elements of our setup are: a polycapillary condenser, a tungsten zone plate, and a scintillator which is optically coupled to a CMOS camera. However, further variations in terms of optical elements are intended. Here we present the current status of our work, as well as first experimental results.

  17. Identification of the ~3.55 keV emission line candidate objects across the sky

    NASA Astrophysics Data System (ADS)

    Savchenko, D. O.; Iakubovskyi, D. A.

    2015-12-01

    An emission line at the energy ~3.55 keV detected in different galaxies and galaxy clusters has caused numerous discussions in high-energy astrophysics and particle physics communities. To reveal the origin of the line, we analyzed publicly-available observations of MOS cameras from XMM-Newton cosmic observatory - the instrument with the largest sensitivity for narrow faint X-ray lines - previously combined in X-ray sky maps. Because an extremely large timescale is needed for detailed analysis, we used the wavelet method instead. Extensive simulations of the central part of the Andromeda galaxy are used to check the validity of this method. The resulting list of wavelet detections now contains 235 sky regions. This list will be used in future works for more detailed spectral analysis.

  18. High Spatial Resolution STXM at 6.2 keV Photon Energy

    SciTech Connect

    Vila-Comamala, Joan; Kewish, Cameron M.; Thibault, Pierre; Guzenko, Vitaliy; Gorelick, Sergey; Menzel, Andreas; Bunk, Oliver; David, Christian; Dierolf, Martin; Pfeiffer, Franz; Pilvi, Tero; Faerm, Elina; Ritala, Mikko

    2010-04-06

    We report on a zone-doubling technique that bypasses the electron-beam lithography limitations for the production of X-ray diffractive optics and enables the fabrication of Fresnel zone plates with smaller outermost zone widths than other well-established approaches. We have applied this method to manufacture hard X-ray Fresnel zone plates with outermost zone widths of 25 and 20 nm. These lenses have been tested in scanning transmission X-ray microscopy (STXM) at energies up to 6.2 keV, producing images of test structures that demonstrate a spatial resolution of 25 nm. High spatial resolution STXM images of several biological specimens have been acquired in transmission, dark-field and differential phase contrast modes.

  19. Nonlinear optical properties of Cu nanocluster composite fabricated by 180 keV ion implantation

    NASA Astrophysics Data System (ADS)

    Wang, Y. H.; Wang, Y. M.; Lu, J. D.; Ji, L. L.; Zang, R. G.; Wang, R. W.

    2009-11-01

    Metal nanocluster composite glass prepared by 180 keV Cu ions into silica with dose of 5×10 16 ions/cm 2 has been studied. The microstructural properties of the nanoclusters has been verified by optical absorption spectra and transmission electron microscopy (TEM). Third-order nonlinear optical properties of the nanoclusters were measured at 1064 and 532 nm excitations using Z-scan technique. The nonlinear refraction index, nonlinear absorption coefficient, and the real and imaginary parts of the third-order nonlinear susceptibility were deduced. Results of the investigation of nonlinear refraction by the off-axis Z-scan configuration were presented and the mechanisms responsible for the nonlinear response were discussed. Third-order nonlinear susceptibility χ(3) of this kind of sample was determined to be 8.7×10 -8 esu at 532 nm and 6.0×10 -8 esu at 1064 nm, respectively.

  20. Active detection of shielded SNM with 60-keV neutrons

    SciTech Connect

    Hagmann, C; Dietrich, D; Hall, J; Kerr, P; Nakae, L; Newby, R; Rowland, M; Snyderman, N; Stoeffl, W

    2008-07-08

    Fissile materials, e.g. {sup 235}U and {sup 239}Pu, can be detected non-invasively by active neutron interrogation. A unique characteristic of fissile material exposed to neutrons is the prompt emission of high-energy (fast) fission neutrons. One promising mode of operation subjects the object to a beam of medium-energy (epithermal) neutrons, generated by a proton beam impinging on a Li target. The emergence of fast secondary neutrons then clearly indicates the presence of fissile material. Our interrogation system comprises a low-dose 60-keV neutron generator (5 x 10{sup 6}/s), and a 1 m{sup 2} array of scintillators for fast neutron detection. Preliminary experimental results demonstrate the detectability of small quantities (370 g) of HEU shielded by steel (200 g/cm{sup 2}) or plywood (30 g/cm{sup 2}), with a typical measurement time of 1 min.

  1. Mechanisms of O2 Sputtering from Water Ice by keV Ions

    NASA Technical Reports Server (NTRS)

    Teolis, B. D.; Vidal, R. A.; Shi, J.; Baragiola, R. A.

    2005-01-01

    We have conducted experiments on the sputtering of water ice by 100 keV Ar(+) between 20 and 150 K. Our findings indicate that the temperature dependence of the total sputtering yield is heavily influenced by the thermal and irradiation history of the ice, showing a complex dependence on irradiation fluence that is correlated to the ejection of O2 molecules. The results suggest that O2 produced by the ions inside the ice diffuses to the surface where it is trapped and then ejected via sputtering or thermal desorption. A high concentration of O2 can trap in a subsurface layer during bombardment at 130 K, which we relate to the formation of hydrogen and its escape from that region. A simple model allows us to determine the depth profile of the absolute concentration of O2 trapped in the ice.

  2. Hard X-ray Polarimetry With Wide Band Laue Lens Telescopes

    NASA Astrophysics Data System (ADS)

    Caroli, E.

    2011-09-01

    Polarimetry is today considered a key observational parameter which can be used to help solve important scientific issues that are still open in the hard X-ray domain (above 10 keV). Therefore the ability to perform high sensitivity polarisation measurements has become a mandatory requirement for the next generation of space telescopes operating in this energy range. In particular the development of new high energy focusing optics, such as wide band Laue lenses operating from ~60 keV up to several hundred keV, with their 50-100 times better sensitivity with respect to current instrumentation, opens a real possibility to make hard X-ray polarimetry an almost standard measurement. Hard X-ray polarimetry can be performed using highly segmented focal plane detectors operated as scattering polarimeters. In this work we summarize results obtained by our group in a series of experiments with CZT/CdTe pixel detector prototypes operating as scattering polarimeters in the range between ~100-700 keV as well as Montecarlo evaluations of the achievable performance in polarisation measurements for Laue lens telescopes using focal planes based on CdTe/CZT pixel detectors.

  3. Broad band waveguide spectrometer

    DOEpatents

    Goldman, Don S.

    1995-01-01

    A spectrometer for analyzing a sample of material utilizing a broad band source of electromagnetic radiation and a detector. The spectrometer employs a waveguide possessing an entry and an exit for the electromagnetic radiation emanating from the source. The waveguide further includes a surface between the entry and exit portions which permits interaction between the electromagnetic radiation passing through the wave guide and a sample material. A tapered portion forms a part of the entry of the wave guide and couples the electromagnetic radiation emanating from the source to the waveguide. The electromagnetic radiation passing from the exit of the waveguide is captured and directed to a detector for analysis.

  4. Dead Band Controls Guide.

    DTIC Science & Technology

    1978-11-01

    n o m i z e r c on t ro l , damper repair may re quire c onsideration. 2. No tubin g costs are included in the above estima tes . Typically 150 to...guidelines include techniques for estimating construction and maintenance cost , and performing economic analysis for each system . N \\ 0~c...43 Cost Estimate 43 Payback Anal ysis 43 PART I V A P P E N D I C E S A EXAMPLE - COST ESTIMATE OF DEAD BAND RETROFIT 52 B E X A M P L E - P A Y B A

  5. Rapid, Microwave Accelerated Synthesis of [1,2,4]Triazolo[3,4-b][1,3,4]oxadiazoles from 4-Acylamino-1,2,4-Triazoles.

    PubMed

    Breunig, Stesphanie L; Olson, Margaret E; Harki, Daniel A

    2016-09-07

    1,2,4-Triazoles and 1,3,4-oxadiazoles are prevalent moieties in pharmaceutical agents, yet fused [1,2,4]-triazolo[3,4-b][1,3,4]oxadiazoles are surprisingly under-represented for both synthesis and biological application. We report a rapid, two-step synthesis of [1,2,4]-triazolo[3,4-b][1,3,4]oxadiazoles from commercial 4-amino-1,2,4-triazoles that is highlighted by a microwave accelerated intramolecular cyclization to generate the fused ring system. Our efforts to optimize reaction conditions and elucidate reaction mechanism are also described.

  6. K-(alpha) Radiography at 20-100 keV Using Short-Pulse Lasers

    SciTech Connect

    Park, H S; Chambers, D; Clarke, R; Eagleton, R; Giraldez, E; Goldsack, T; Heathcote, R; Izumi, N; Key, M; King, J; Koch, J; Landen, O L; Mackinnon, A; Nikroo, A; Patel, P; Pasley, J; Remington, B; Robey, H; Snavely, R; Steinman, D; Stephenson, R; Stoeckl, C; Storm, M; Tabak, M; Theobald, W; Town, R J

    2005-08-29

    X-ray radiography is an important tool for diagnosing and imaging planar and convergent hydrodynamics phenomena for laser experiments. Until now, hydrodynamics experiments at Omega and NIF utilize E{sub x-ray} < 9 keV backlighter x-rays emitted by thermal plasmas. However, future experiments will need to diagnose larger and denser targets and will require x-ray probes of energies from 20-100 keV and possibly up to 1 MeV. Hard K-{alpha} x-ray photons can be created through high-energy electron interactions in the target material after irradiation by petawatt-class high-intensity-short-pulse lasers with > 10{sup 17} W/cm{sup 2}. We have performed several experiments on the JanUSP, and the Vulcan 100TW, and Vulcan Petawatt lasers to understand K-{alpha} sources and to test radiography concepts. 1-D radiography using an edge-on foil and 2-D radiography using buried wires and cone-fiber targets were tested. We find that 1-D thin edge-on foils can have imaging resolution better than 10 {micro}m. Micro volume targets produce bright sources with measured conversion efficiency from laser energy to x-ray photons of {approx} 1 x 10{sup -5}. This level of conversion may not be enough for 2-D point projection radiography. A comparison of our experimental measurements of small volume sources with the LSP/PIC simulation show similar K-{alpha} creation profiles but discrepancy in absolute yields.

  7. QUIET-TIME INTERPLANETARY {approx}2-20 keV SUPERHALO ELECTRONS AT SOLAR MINIMUM

    SciTech Connect

    Wang, Linghua; Lin, Robert P.; Salem, Chadi; Pulupa, Marc; Larson, Davin E.; Luhmann, Janet G.; Yoon, Peter H.

    2012-07-01

    We present a statistical survey of {approx}2-20 keV superhalo electrons in the solar wind measured by the SupraThermal Electron instrument on board the two STEREO spacecraft during quiet-time periods from 2007 March through 2009 March at solar minimum. The observed superhalo electrons have a nearly isotropic angular distribution and a power-law spectrum, f{proportional_to}v{sup -{gamma}}, with {gamma} ranging from 5 to 8.7, with nearly half between 6.5 and 7.5, and an average index of 6.69 {+-} 0.90. The observed power-law spectrum varies significantly on a spatial scale of {approx}>0.1 AU and a temporal scale of {approx}>several days. The integrated density of quiet-time superhalo electrons at 2-20 keV ranges from {approx}10{sup -8} cm{sup -3} to 10{sup -6} cm{sup -3}, about 10{sup -9}-10{sup -6} of the solar wind density, and, as well as the power-law spectrum, shows no correlation with solar wind proton density, velocity, or temperature. The density of superhalo electrons appears to show a solar-cycle variation at solar minimum, while the power-law spectral index {gamma} has no solar-cycle variation. These quiet-time superhalo electrons are present even in the absence of any solar activity-e.g., active regions, flares or microflares, type III radio bursts, etc.-suggesting that they may be accelerated by processes such as resonant wave-particle interactions in the interplanetary medium, or possibly by nonthermal processes related to the acceleration of the solar wind such as nanoflares, or by acceleration at the CIR forward shocks.

  8. keV sterile neutrino dark matter from singlet scalar decays: basic concepts and subtle features

    SciTech Connect

    Merle, Alexander; Totzauer, Maximilian E-mail: totzauer@mpp.mpg.de

    2015-06-01

    We perform a detailed and illustrative study of the production of keV sterile neutrino Dark Matter (DM) by decays of singlet scalars in the early Universe. In the current study we focus on providing a clear and general overview of this production mechanism. For the first time we study all regimes possible on the level of momentum distribution functions, which we obtain by solving a system of Boltzmann equations. These quantities contain the full information about the production process, which allows us to not only track the evolution of the DM generation but to also take into account all bounds related to the spectrum, such as constraints from structure formation or from avoiding too much dark radiation. In particular we show that this simple production mechanism can, depending on the regime, lead to strongly non-thermal DM spectra which may even feature more than one peak in the momentum distribution. These cases could have particularly interesting consequences for cosmological structure formation, as their analysis requires more refined tools than the simplistic estimate using the free-streaming horizon. Here we present the mechanism including all concepts and subtleties involved, for now using the assumption that the effective number of relativistic degrees of freedom is constant during DM production, which is applicable in a significant fraction of the parameter space. This allows us to derive analytical results to back up our detailed numerical computations, thus leading to the most comprehensive picture of keV sterile neutrino DM production by singlet scalar decays that exists up to now.

  9. SURVIVAL DEPTH OF ORGANICS IN ICES UNDER LOW-ENERGY ELECTRON RADIATION ({<=}2 keV)

    SciTech Connect

    Barnett, Irene Li; Lignell, Antti; Gudipati, Murthy S.

    2012-03-01

    Icy surfaces in our solar system are continually modified and sputtered with electrons, ions, and photons from solar wind, cosmic rays, and local magnetospheres in the cases of Jovian and Saturnian satellites. In addition to their prevalence, electrons specifically are expected to be a principal radiolytic agent on these satellites. Among energetic particles (electrons and ions), electrons penetrate by far the deepest into the ice and could cause damage to organic material of possible prebiotic and even biological importance. To determine if organic matter could survive and be detected through remote sensing or in situ explorations on these surfaces, such as water ice-rich Europa, it is important to obtain accurate data quantifying electron-induced chemistry and damage depths of organics at varying incident electron energies. Experiments reported here address the quantification issue at lower electron energies (100 eV-2 keV) through rigorous laboratory data analysis obtained using a novel methodology. A polycyclic aromatic hydrocarbon molecule, pyrene, embedded in amorphous water ice films of controlled thicknesses served as an organic probe. UV-VIS spectroscopic measurements enabled quantitative assessment of organic matter survival depths in water ice. Eight ices of various thicknesses were studied to determine damage depths more accurately. The electron damage depths were found to be linear, approximately 110 nm keV{sup -1}, in the tested range which is noticeably higher than predictions by Monte Carlo simulations by up to 100%. We conclude that computational simulations underestimate electron damage depths in the energy region {<=}2 keV. If this trend holds at higher electron energies as well, present models utilizing radiation-induced organic chemistry in icy solar system bodies need to be revisited. For interstellar ices of a few micron thicknesses, we conclude that low-energy electrons generated through photoionization processes in the interstellar medium

  10. keV sterile neutrino dark matter from singlet scalar decays: basic concepts and subtle features

    SciTech Connect

    Merle, Alexander; Totzauer, Maximilian

    2015-06-08

    We perform a detailed and illustrative study of the production of keV sterile neutrino Dark Matter (DM) by decays of singlet scalars in the early Universe. In the current study we focus on providing a clear and general overview of this production mechanism. For the first time we study all regimes possible on the level of momentum distribution functions, which we obtain by solving a system of Boltzmann equations. These quantities contain the full information about the production process, which allows us to not only track the evolution of the DM generation but to also take into account all bounds related to the spectrum, such as constraints from structure formation or from avoiding too much dark radiation. In particular we show that this simple production mechanism can, depending on the regime, lead to strongly non-thermal DM spectra which may even feature more than one peak in the momentum distribution. These cases could have particularly interesting consequences for cosmological structure formation, as their analysis requires more refined tools than the simplistic estimate using the free-streaming horizon. Here we present the mechanism including all concepts and subtleties involved, for now using the assumption that the effective number of relativistic degrees of freedom is constant during DM production, which is applicable in a significant fraction of the parameter space. This allows us to derive analytical results to back up our detailed numerical computations, thus leading to the most comprehensive picture of keV sterile neutrino DM production by singlet scalar decays that exists up to now.

  11. Ionization and fragmentation of polycyclic aromatic hydrocarbon clusters in collisions with keV ions

    SciTech Connect

    Johansson, H. A. B.; Zettergren, H.; Holm, A. I. S.; Seitz, F.; Schmidt, H. T.; Cederquist, H.; Rousseau, P.; Lawicki, A.; Capron, M.; Domaracka, A.; Lattouf, E.; Maclot, S.; Maisonny, R.; Chesnel, J.-Y.; Adoui, L.; Huber, B. A.

    2011-10-15

    We report on an experimental study of the ionization and fragmentation of clusters of k polycyclic aromatic hydrocarbon (PAH) molecules using anthracene, C{sub 14}H{sub 10}, or coronene, C{sub 24}H{sub 12}. These PAH clusters are moderately charged and strongly heated in small impact parameter collisions with 22.5-keV He{sup 2+} ions, after which they mostly decay in long monomer evaporation sequences with singly charged and comparatively cold monomers as dominating end products. We describe a simple cluster evaporation model and estimate the number of PAH molecules in the clusters that have to be hit by He{sup 2+} projectiles for such complete cluster evaporations to occur. Highly charged and initially cold clusters are efficiently formed in collisions with 360-keV Xe{sup 20+} ions, leading to cluster Coulomb explosions and several hot charged fragments, which again predominantly yield singly charged, but much hotter, monomer ions than the He{sup 2+} collisions. We present a simple formula, based on density-functional-theory calculations, for the ionization energy sequences as functions of coronene cluster size, rationalized in terms of the classic electrostatic expression for the ionization of a charged conducting object. Our analysis indicates that multiple electron removal by highly charged ions from a cluster of PAH molecules rapidly may become more important than single ionization as the cluster size k increases and that this is the main reason for the unexpectedly strong heating in these types of collisions.

  12. Toward Realization of 2.4 GHz Balunless Narrowband Receiver Front-End for Short Range Wireless Applications.

    PubMed

    El-Desouki, Munir M; Qasim, Syed Manzoor; BenSaleh, Mohammed S; Deen, M Jamal

    2015-05-07

    The demand for radio frequency (RF) transceivers operating at 2.4 GHz band has attracted considerable research interest due to the advancement in short range wireless technologies. The performance of RF transceivers depends heavily on the transmitter and receiver front-ends. The receiver front-end is comprised of a low-noise amplifier (LNA) and a downconversion mixer. There are very few designs that focus on connecting the single-ended output LNA to a double-balanced mixer without the use of on-chip transformer, also known as a balun. The objective of designing such a receiver front-end is to achieve high integration and low power consumption. To meet these requirements, we present the design of fully-integrated 2.4 GHz receiver front-end, consisting of a narrow-band LNA and a double balanced mixer without using a balun. Here, the single-ended RF output signal of the LNA is translated into differential signal using an NMOS-PMOS (n-channel metal-oxide-semiconductor, p-channel metal-oxide-semiconductor) transistor differential pair instead of the conventional NMOS-NMOS transistor configuration, for the RF amplification stage of the double-balanced mixer. The proposed receiver circuit fabricated using TSMC 0.18 µm CMOS technology operates at 2.4 GHz and produces an output signal at 300 MHz. The fabricated receiver achieves a gain of 16.3 dB and consumes only 6.74 mW operating at 1.5 V, while utilizing 2.08 mm2 of chip area. Measurement results demonstrate the effectiveness and suitability of the proposed receiver for short-range wireless applications, such as in wireless sensor network (WSN).

  13. Toward Realization of 2.4 GHz Balunless Narrowband Receiver Front-End for Short Range Wireless Applications

    PubMed Central

    El-Desouki, Munir M.; Qasim, Syed Manzoor; BenSaleh, Mohammed S.; Deen, M. Jamal

    2015-01-01

    The demand for radio frequency (RF) transceivers operating at 2.4 GHz band has attracted considerable research interest due to the advancement in short range wireless technologies. The performance of RF transceivers depends heavily on the transmitter and receiver front-ends. The receiver front-end is comprised of a low-noise amplifier (LNA) and a downconversion mixer. There are very few designs that focus on connecting the single-ended output LNA to a double-balanced mixer without the use of on-chip transformer, also known as a balun. The objective of designing such a receiver front-end is to achieve high integration and low power consumption. To meet these requirements, we present the design of fully-integrated 2.4 GHz receiver front-end, consisting of a narrow-band LNA and a double balanced mixer without using a balun. Here, the single-ended RF output signal of the LNA is translated into differential signal using an NMOS-PMOS (n-channel metal-oxide-semiconductor, p-channel metal-oxide-semiconductor) transistor differential pair instead of the conventional NMOS-NMOS transistor configuration, for the RF amplification stage of the double-balanced mixer. The proposed receiver circuit fabricated using TSMC 0.18 µm CMOS technology operates at 2.4 GHz and produces an output signal at 300 MHz. The fabricated receiver achieves a gain of 16.3 dB and consumes only 6.74 mW operating at 1.5 V, while utilizing 2.08 mm2 of chip area. Measurement results demonstrate the effectiveness and suitability of the proposed receiver for short-range wireless applications, such as in wireless sensor network (WSN). PMID:25961380

  14. DISPLACEMENT CASCADE SIMULATION IN TUNGSTEN UP TO 200 KEV OF DAMAGE ENERGY AT 300, 1025, AND 2050 K

    SciTech Connect

    Setyawan, Wahyu; Nandipati, Giridhar; Roche, Kenneth J.; Kurtz, Richard J.; Wirth, Brian D.

    2015-09-22

    We generated molecular dynamics database of primary defects that adequately covers the range of tungsten recoil energy imparted by 14-MeV neutrons. During this semi annual period, cascades at 150 and 200 keV at 300 and 1025 K were simulated. Overall, we included damage energy up to 200 keV at 300 and 1025 K, and up to 100 keV at 2050 K. We report the number of surviving Frenkel pairs (NF) and the size distribution of defect clusters. The slope of the NF curve versus cascade damage energy (EMD), on a log-log scale, changes at a transition energy (μ). For EMD > μ, the cascade forms interconnected damage regions that facilitate the formation of large clusters of defects. At 300 K and EMD = 200 keV, the largest size of interstitial cluster and vacancy cluster is 266 and 335, respectively. Similarly, at 1025 K and EMD = 200 keV, the largest size of interstitial cluster and vacancy cluster is 296 and 338, respectively. At 2050 K, large interstitial clusters also routinely form, but practically no large vacancy clusters do

  15. Intermolecular interactions in ternary solutions of some 1,2,4-triazolium ylids studied by spectral means

    NASA Astrophysics Data System (ADS)

    Closca, Valentina; Melniciuc-Puica, Nicoleta; Dorohoi, Dana Ortansa; Benchea, A. C.

    2014-08-01

    Triazolium ylids are dipolar molecules with separated charges in their ground electronic state; the positive charge is located on one Nitrogen atom belonging to the heterocycle and the negative charge is located near the ylid carbanion. The intramolecular charge transfer from the carbanion to heterocycle gives a visible electronic absorption band, very sensitive to the solvent nature. Its position in the wavenumber scale offers information about the intermolecular interactions in which the ylid molecules are engaged. The spectral study revealed the presence of both universal and specific interactions in solutions of 1,2,4-triazolium ylids with protic solvents. By choosing adequate binary solvents, the contribution of the specific interaction of the weak hydrogen bond between the -OH atomic group of the protic solvents and the ylid carbanion can be estimated. Ternary solutions of the studied ylids achieved with Methanol +Benzene, Water + Ethanol and 1,3 Propanediol + Dimethyl formamide binary solvents are analyzed from spectral point of view and the difference between the potential energies in molecular pairs of the types: 1,2,4-triazolium ylid-protic solvent and 1,2,4-triazolium ylid-non protic were estimated on the basis of the statistic cell model of ternary solutions.

  16. The Oxygen a Band

    NASA Astrophysics Data System (ADS)

    Benner, D. Chris; Devi, V. Malathy; Hoo, Jiajun; Hodges, Joseph; Long, David A.; Sung, Keeyoon; Drouin, Brian; Okumura, Mitchio; Bui, Thinh Quoc; Rupasinghe, Priyanka

    2014-06-01

    The oxygen A band is used for numerous atmospheric experiments, but spectral line parameters that sufficiently describe the spectrum to the level required by OCO2 and other high precision/accuracy experiments are lacking. Fourier transform spectra from the Jet Propulsion Laboratory and cavity ring down spectra from the National Institute of Standards and Technology were fitted simultaneously using the William and Mary multispectrum nonlinear least squares fitting technique into a single solution including the entire band. In addition, photoacoustic spectra already available from the California Institute of Technology will be added to the solution. The three types of spectrometers are complementary allowing the strengths of each to fill in the weaknesses of the others. With this technique line positions, intensities, widths, shifts, line mixing, Dicke narrowing, temperature dependences and collision induced absorption have been obtained in a single physically consistent fit. D. Chris Benner, C. P. Rinsland, V. M. Devi, M. A. H. Smith, and D. Atkins, JQSRT 1995;53:705-21. Part of the research described in this paper was performed at The College of William and Mary, the, Jet Propulsion Laboratory, California Institute of Technology, under contracts and cooperative agreements with the National Aeronautics and Space Administration and the Jet Propulsion Laboratory. Support for the National Institute of Standards and Technology was provided by the NIST Greenhouse Gas Measurements and Climate Research Program and a NIST Innovations in Measurement Science (IMS) award.

  17. Surface brightness measurements of supernova remanants in the energy band 0.15 - 4 keV and an XUV survey from an altitude controlled rocket

    NASA Technical Reports Server (NTRS)

    Garmire, G. P.; Riegler, G.

    1973-01-01

    Reports are presented concerning the flight of Aerobee 170, 13.063 UG. The papers presented include: soft X-rays for Cygnus X-1 and Cygnus X-2; X-ray spectrum of the entire Cygnus loop; X-ray surface brightness of the Cygnus loop; and observations of He II 304 A and He I 584 a nightglow.

  18. Analytical studies of the interaction of Tb(III)-2-{[(4-methoxy benzoyl) oxy]} methyl benzoic acid binary complex with nucleosides

    NASA Astrophysics Data System (ADS)

    Shehata, A. M. A.; Azab, H. A.; El-assy, N. B.; Anwar, Z. M.; Mostafa, H. M.

    2016-01-01

    The interaction of Tb(III)-2-{[(4-methoxy benzoyl) oxy]} methyl benzoic acid binary complex with nucleosides (adenosine, cytidine, guanosine and inosine) was investigated using UV and fluorescence methods. The reaction of Tb-complex with cytidine, guanosine and adenosine is accompanied by shift to longer wavelength in the absorption band, while there is a blue shift in the absorption band with an enhancement in the molar absorptivity upon the reaction with inosine. The fluorescence intensity of Tb(III)-2-{[(4- methoxy benzoyl) oxy]} methyl benzoic acid binary complex at λ = 545 nm (5D4 → 7F5) was decreased with the addition of the nucleoside molecule following the order: cytidine > inosine > guanosine > adenosine.

  19. Demonstration of a 13-keV Kr K-shell x-ray source at the National Ignition Facility

    NASA Astrophysics Data System (ADS)

    Fournier, K. B.; May, M. J.; Colvin, J. D.; Barrios, M. A.; Patterson, J. R.; Regan, S. P.

    2013-09-01

    We report 3% conversion efficiency of laser energy into Kr K-shell (≈13 keV) radiation, consistent with theoretical predictions. This is ≈10× greater than previous work. The emission was produced from a 4.1-mm-diameter, 4-mm-tall gas pipe target filled with 1.2 or 1.5 atm of Kr gas. 160 of the National Ignition Facility laser beams deposited ≈700 kJ of 3ω light into the target in an ≈140 TW, 5.0-ns-duration square pulse. The Dante diagnostics measured ≈5 TW into 4π solid angle of ≥12 keV x rays for ≈4 ns, which includes both continuum emission and flux in the Kr Heα line at 13 keV.

  20. Applications of “Tender” Energy (1-5 keV) X-ray Absorption Spectroscopy in Life Sciences

    SciTech Connect

    Northrup, Paul; Leri, Alessandra; Tappero, Ryan

    2016-02-15

    The “tender” energy range of 1 to 5 keV, between the energy ranges of most “hard” (>5 keV) and “soft” (<1 keV) synchrotron X-ray facilities, offers some unique opportunities for synchrotron-based X-ray absorption fine structure spectroscopy in life sciences. In particular the K absorption edges of Na through Ca offer opportunities to study local structure, speciation, and chemistry of many important biological compounds, structures and processes. This is an area of largely untapped science, in part due to a scarcity of optimized facilities. Such measurements also entail unique experimental challenges. Lastly, this brief review describes the technique, its experimental challenges, recent progress in development of microbeam measurement capabilities, and several highlights illustrating applications in life sciences.

  1. The diffuse X-ray spectrum from 14-200 keV as measured on OSO-5

    NASA Technical Reports Server (NTRS)

    Dennis, B. R.; Suri, A. N.; Frost, K. J.

    1973-01-01

    The measurement of energy spectrum of the diffuse component of cosmic X-ray flux made on the OSO-5 spacecraft is described. The contributions to the total counting rate of the actively shielded X-ray detector are considered in some detail and the techniques used to eliminate the non-cosmic components are described. Positive values for the cosmic flux are obtained in seven energy channels between 14 and 200 keV and two upper limits are obtained between 200 and 254 keV. The results can be fitted by a power law spectrum. A critical comparison is made with the OSO-3 results. Conclusions show that the reported break in the energy spectrum at 40 keV is probably produced by an erroneous correction for the radioactivity induced in the detector on each passage through the intense charged particle fluxes in the South Atlantic anomaly.

  2. Applications of “Tender” Energy (1-5 keV) X-ray Absorption Spectroscopy in Life Sciences

    DOE PAGES

    Northrup, Paul; Leri, Alessandra; Tappero, Ryan

    2016-02-15

    The “tender” energy range of 1 to 5 keV, between the energy ranges of most “hard” (>5 keV) and “soft” (<1 keV) synchrotron X-ray facilities, offers some unique opportunities for synchrotron-based X-ray absorption fine structure spectroscopy in life sciences. In particular the K absorption edges of Na through Ca offer opportunities to study local structure, speciation, and chemistry of many important biological compounds, structures and processes. This is an area of largely untapped science, in part due to a scarcity of optimized facilities. Such measurements also entail unique experimental challenges. Lastly, this brief review describes the technique, its experimental challenges,more » recent progress in development of microbeam measurement capabilities, and several highlights illustrating applications in life sciences.« less

  3. Multilayer Fresnel zone plates for high energy radiation resolve 21 nm features at 1.2 keV.

    PubMed

    Keskinbora, Kahraman; Robisch, Anna-Lena; Mayer, Marcel; Sanli, Umut T; Grévent, Corinne; Wolter, Christian; Weigand, Markus; Szeghalmi, Adriana; Knez, Mato; Salditt, Tim; Schütz, Gisela

    2014-07-28

    X-ray microscopy is a successful technique with applications in several key fields. Fresnel zone plates (FZPs) have been the optical elements driving its success, especially in the soft X-ray range. However, focusing of hard X-rays via FZPs remains a challenge. It is demonstrated here, that two multilayer type FZPs, delivered from the same multilayer deposit, focus both hard and soft X-rays with high fidelity. The results prove that these lenses can achieve at least 21 nm half-pitch resolution at 1.2 keV demonstrated by direct imaging, and sub-30 nm FWHM (full-pitch) resolution at 7.9 keV, deduced from autocorrelation analysis. Reported FZPs had more than 10% diffraction efficiency near 1.5 keV.

  4. Coulomb excitation of ground band rotational states in /sup 249/Bk

    SciTech Connect

    Bemis, C.E. Jr.; McGowan, F.K.; Ford, J.L.C. Jr.; Milner, W.T.; Robinson, R.L.; Stelson, P.H.

    1982-03-01

    Coulomb-excitation probabilities for the first few members of the 7/2/sup +/(633up-arrow) ground-state rotational band in /sup 249/Bk have been determined with 17.06-MeV /sup 4/He ions. These previously know excited states include the 9/2/sup +/ (41.8-keV), 11/2/sup +/ (93.7-keV), and 13/2/sup +/ (155.8-keV) members of the 7/2/sup +/(633up-arrow) band. Within experimental uncertainties, the Coulomb-excitation probabilities for these rotational states are reproduced by calculated values when only E2 excitations are considered with an intrinsic quadrupole moment, Q/sub 20/, of 12.70 +- 0.24 eb in the rigid rotor limit. The deduced ground-state spectroscopic quadrupole moment is 5.93 +- 0.11 eb. Intraband M1 transition rates have been deduced by combining the Q/sub 20/ result with other experimental data. Within the rotational model, a ground-state magnetic moment of +3.45 +- 0.10 ..mu../sub N/ is indicated.

  5. AN ENZYME LINKED IMMUNOSORBENT ASSAY (ELISA) METHOD FOR THE URINARY BIOMONITORING OF 2,4-DICHLOROPHRENOCYACETIC ACID (2,4-D)

    EPA Science Inventory

    An enzyme-linked immunosorbent assay (ELISA) method was developed to quantitatively measure 2,4-dichlorophenoyacetic acid (2,4-D) in human urine. Samples were diluted (1:5) with phosphate-buffered saline, 0.05% Tween 20, with 0.02% sodium azide, and analyzed by a 96-microwekk pl...

  6. Effect of 2,4-Dichlorophenoxyacetic Acid (2,4-D) on PCDD/F Emissions from Open Burning of Biomass

    EPA Science Inventory

    Use of pesticides prior to agricultural burning and overspray onto forests and grasslands prior to fires has been cited as a cause of halogenated organic compound emissions from biomass combustion. Some pesticides such as 2,4-dichlorophenoxyacetic acid (2,4-D) are used in conside...

  7. Effects of prenatal exposure to 2,4-D/2,4,5-T mixture on postnatal changes in rat brain glutamate, GABA protein, and nucleic acid levels

    SciTech Connect

    Mohammad, F.K.; Omer, V.E.V.

    1988-02-01

    The opportunity of maternal exposure to various chemicals in the work place and the general environments have increased, and the fetus and neonate may be at greater risk than the adult. However, the embryotoxic and teratogenic effects of the chlorinated phenoxy herbicides 2,4-dichlorophenoxyacetic acid (2,4-D) and 2,4,5-trichlorophenoxyacetic acid (2,4,5-T), the main chemicals in Agent Orange, are well documented only in laboratory animals. The brain of the developing fetus is vulnerable to the toxic effects of the phenoxy herbicides which readily cross the placental barrier and distribute into fetal tissues, including brain. Although the neurochemical basis for the behavioral teratogenicity of the phenoxy herbicides is not know, it was recently reported that non-teratogenic doses of a 1:1 mixture of 2,4-D and 2,4,5-T delayed the ontogeny of dopamine and serotonin in the brain of the developing rate. This communication provides further descriptive information about the ontogeny of rat brain nucleic acid, protein, glutamate and ..gamma..-aminobutyrate (GABA) following in utero exposure to non-teratogenic levels of a 1:1 mixture of 2,4-D/2,4,5-T.

  8. 2,4-D and IAA Amino Acid Conjugates Show Distinct Metabolism in Arabidopsis

    PubMed Central

    Eyer, Luděk; Vain, Thomas; Pařízková, Barbora; Oklestkova, Jana; Barbez, Elke; Kozubíková, Hana; Pospíšil, Tomáš; Wierzbicka, Roksana; Kleine-Vehn, Jürgen; Fránek, Milan; Strnad, Miroslav; Robert, Stéphanie

    2016-01-01

    The herbicide 2,4-D exhibits an auxinic activity and therefore can be used as a synthetic and traceable analog to study auxin-related responses. Here we identified that not only exogenous 2,4-D but also its amide-linked metabolite 2,4-D-Glu displayed an inhibitory effect on plant growth via the TIR1/AFB auxin-mediated signaling pathway. To further investigate 2,4-D metabolite conversion, identity and activity, we have developed a novel purification procedure based on the combination of ion exchange and immuno-specific sorbents combined with a sensitive liquid chromatography-mass spectrometry method. In 2,4-D treated samples, 2,4-D-Glu and 2,4-D-Asp were detected at 100-fold lower concentrations compared to 2,4-D levels, showing that 2,4-D can be metabolized in the plant. Moreover, 2,4-D-Asp and 2,4-D-Glu were identified as reversible forms of 2,4-D homeostasis that can be converted to free 2,4-D. This work paves the way to new studies of auxin action in plant development. PMID:27434212

  9. Adaptation of Delftia acidovorans for degradation of 2,4-dichlorophenoxyacetate in a microfluidic porous medium.

    PubMed

    Yoon, Hongkyu; Leibeling, Sabine; Zhang, Changyong; Müller, Roland H; Werth, Charles J; Zilles, Julie L

    2014-07-01

    Delftia acidovorans MC1071 can productively degrade R-2-(2,4-dichlorophenoxy)propionate (R-2,4-DP) but not 2,4-dichlorophenoxyacetate (2,4-D) herbicides. This work demonstrates adaptation of MC1071 to degrade 2,4-D in a model two-dimensional porous medium (referred to here as a micromodel). Adaptation for 2,4-D degradation in the 2 cm-long micromodel occurred within 35 days of exposure to 2,4-D, as documented by substrate removal. The amount of 2,4-D degradation in the adapted cultures in two replicate micromodels (~10 and 20 % over 142 days) was higher than a theoretical maximum (4 %) predicted using published numerical simulation methods, assuming instantaneous biodegradation and a transverse dispersion coefficient obtained for the same pore structure without biomass present. This suggests that the presence of biomass enhances substrate mixing. Additional evidence for adaptation was provided by operation without R-2,4-DP, where degradation of 2,4-D slowly decreased over 20 days, but was restored almost immediately when R-2,4-DP was again provided. Compared to suspended growth systems, the micromodel system retained the ability to degrade 2,4-D longer in the absence of R-2,4-DP, suggesting slower responses and greater resilience to fluctuations in substrates might be expected in the soil environment than in a chemostat.

  10. Biodegradation of IMX-101 explosive formulation constituents: 2,4-dinitroanisole (DNAN), 3-nitro-1,2,4-triazol-5-one (NTO), and nitroguanidine.

    PubMed

    Richard, Thomas; Weidhaas, Jennifer

    2014-09-15

    Defense agencies are increasingly using insensitive munitions (IM) in place of explosives such as 2,4,6-trinitrotoluene. In this study simultaneous aerobic degradation of the IMX-101 formulation constituents 2,4-dinitroanisole (DNAN), 3-nitro-1,2,4-triazol-5-one (NTO), and nitroguanidine (NQ) was observed and degradation products were examined. Degradation products over four days of incubation included: nitrourea, 1,2-dihydro-3H-1,2,4-triazol-3-one, and 2,4-dinitrophenol. The enrichment culture maximum specific growth rate of 0.12h(-1) and half saturation constant of 288 mg L(-1) during degradation of IMX-101 as a sole nitrogen source suggest that enrichment culture growth kinetics may closely relate to those of other explosive and nitroaromatic compounds.

  11. Wide Band Artificial Pulsar

    NASA Astrophysics Data System (ADS)

    Parsons, Zackary

    2017-01-01

    The Wide Band Artificial Pulsar (WBAP) is an instrument verification device designed and built by the National Radio Astronomy Observatory (NRAO) in Green Bank, West Virgina. The site currently operates the Green Bank Ultimate Pulsar Processing Instrument (GUPPI) and the Versatile Green Bank Astronomical Spectrometer (VEGAS) digital backends for their radio telescopes. The commissioning and continued support for these sophisticated backends has demonstrated a need for a device capable of producing an accurate artificial pulsar signal. The WBAP is designed to provide a very close approximation to an actual pulsar signal. This presentation is intended to provide an overview of the current hardware and software implementations and to also share the current results from testing using the WBAP.

  12. Anomalous X-ray galactic signal from 7.1 keV spin-3/2 dark matter decay

    SciTech Connect

    Dutta, Sukanta; Goyal, Ashok; Kumar, Sanjeev E-mail: agoyal45@yahoo.com

    2016-02-01

    In order to explain the recently reported peak at 3.55 keV in the galactic X-ray spectrum, we propose a simple model. In this model, the Standard Model is extended by including a neutral spin-3/2 vector-like fermion that transforms like a singlet under SM gauge group. This 7.1 keV spin-3/2 fermion is considered to comprise a portion of the observed dark matter. Its decay into a neutrino and a photon with decay life commensurate with the observed data, fits the relic dark matter density and obeys the astrophysical constraints from the supernova cooling.

  13. Observations of solar flare photon energy spectra from 20 keV to 7 MeV

    NASA Technical Reports Server (NTRS)

    Yoshimori, M.; Watanabe, H.; Nitta, N.

    1985-01-01

    Solar flare photon energy spectra in the 20 keV to 7 MeV range are derived from the Apr. 1, Apr. 4, apr. 27 and May 13, 1981 flares. The flares were observed with a hard X-ray and a gamma-ray spectrometers on board the Hinotori satellite. The results show that the spectral shape varies from flare to flare and the spectra harden in energies above about 400 keV. Effects of nuclear line emission on the continuum and of higher energy electron bremsstrahlung are considered to explain the spectral hardening.

  14. Searching for a 3.5-keV line in the spectrum of the deepest Chandra blank fields

    NASA Astrophysics Data System (ADS)

    Urry, C. Megan; Cappelluti, Nico; Bulbul, Esra

    2017-01-01

    We report results of our spectral analysis of ~10 Ms of data in the deep Chandra COSMOS Legacy and CDFS surveys. We discuss a possible emission feature at 3.5 keV, which has been reported in other XMM-Newton, Chandra and NuSTAR X-ray data. If due to dark matter decay, the 3.5-keV feature, together with the result from the DAMA dark matter detection experiment, is to date the only positive dark matter signature surviving experimental tests. We discuss possible instrumental contaminations, proper statistical treatment and interpretation in terms of dark matter decay or S XVII charge exchange.

  15. Measurement of the MACS of 159Tb(n, γ) at kT = 30 keV by Activation

    NASA Astrophysics Data System (ADS)

    Praena, J.; Mastinu, P. F.; Pignatari, M.; Quesada, J. M.; Capote, R.; Morilla, Y.

    2014-06-01

    The measurement of the Maxwellian-Averaged Cross-Section (MACS) of the 159Tb(n, γ) reaction at kT = 30 keV by the activation technique is presented. An innovative method for the generation of Maxwellian neutron spectra at kT = 30 keV is used. An experimental value of 2166 ± 181 mb agrees well with the MACS value derived from the ENDF/B-VII.1 evaluation, but is higher than KADoNiS recommended value of 1580 ± 150 mb. Astrophysical implications are studied.

  16. An innovative experimental setup for the measurement of sputtering yield induced by keV energy ions.

    PubMed

    Salou, P; Lebius, H; Benyagoub, A; Langlinay, T; Lelièvre, D; Ban-d'Etat, B

    2013-09-01

    An innovative experimental equipment allowing to study the sputtering induced by ion beam irradiation is presented. The sputtered particles are collected on a catcher which is analyzed in situ by Auger electron spectroscopy without breaking the ultra high vacuum (less than 10(-9) mbar), avoiding thus any problem linked to possible contamination. This method allows to measure the angular distribution of sputtering yield. It is now possible to study the sputtering of many elements such as carbon based materials. Preliminary results are presented in the case of highly oriented pyrolytic graphite and tungsten irradiated by an Ar(+) beam at 2.8 keV and 7 keV, respectively.

  17. False Color Bands

    NASA Technical Reports Server (NTRS)

    2005-01-01

    [figure removed for brevity, see original site]

    The theme for the weeks of 1/17 and 1/24 is the north polar region of Mars as seen in false color THEMIS images. Ice/frost will typically appear as bright blue in color; dust mantled ice will appear in tones of red/orange.

    In a gray scale image, the suble variations seen in this false color image are almost impossible to identify. Note the orange band in the center of the frame, and the bluer bands to either side of it.

    Image information: VIS instrument. Latitude 87, Longitude 65.5 East (294.5 West). 19 meter/pixel resolution.

    Note: this THEMIS visual image has not been radiometrically nor geometrically calibrated for this preliminary release. An empirical correction has been performed to remove instrumental effects. A linear shift has been applied in the cross-track and down-track direction to approximate spacecraft and planetary motion. Fully calibrated and geometrically projected images will be released through the Planetary Data System in accordance with Project policies at a later time.

    NASA's Jet Propulsion Laboratory manages the 2001 Mars Odyssey mission for NASA's Office of Space Science, Washington, D.C. The Thermal Emission Imaging System (THEMIS) was developed by Arizona State University, Tempe, in collaboration with Raytheon Santa Barbara Remote Sensing. The THEMIS investigation is led by Dr. Philip Christensen at Arizona State University. Lockheed Martin Astronautics, Denver, is the prime contractor for the Odyssey project, and developed and built the orbiter. Mission operations are conducted jointly from Lockheed Martin and from JPL, a division of the California Institute of Technology in Pasadena.

  18. Effects of combined irradiation of 500 keV protons and atomic oxygen on polyimide films

    NASA Astrophysics Data System (ADS)

    Novikov, Lev; Chernik, Vladimir; Zhilyakov, Lev; Voronina, Ekaterina; Chirskaia, Natalia

    2016-07-01

    Polyimide films are widely used on the spacecraft surface as thermal control coating, films in different constuctions, etc. However, the space ionizing radiation of different types can alter the mechanical, optical and electrical properties of polyimide films. For example, it is well known that 20-100 keV proton irradiation causes breaking of chemical bonds and destruction of the surface layer in polyimide, deterioration of its optical properties, etc. In low-Earth orbits serious danger for polymeric materials is atomic oxygen of the upper atmosphere of the Earth, which is the main component in the range of heights of 200-800 km. Due to the orbital spacecraft velocity, the collision energy of oxygen atoms with the surface ( 5 eV) enhances their reactivity and opens additional pathways of their reaction with near-surface layers of materials. Hyperthermal oxygen atom flow causes erosion of the polyimide surface by breaking chemical bonds and forming of volatiles products (primarily, CO and CO _{2}), which leads to mass losses and degradation of material properties. Combined effect of protons and oxygen plasma is expected to give rise to synergistic effects enhancing the destruction of polyimide surface layers. This paper describes experimental investigation of polyimide films sequential irradiation with protons and oxygen plasma. The samples were irradiated by 500 keV protons at fluences of 10 ^{14}-10 ^{16} cm ^{-2} produced with SINP cascade generator KG-500 and 5-20 eV neutral oxygen atoms at fluence of 10 ^{20} cm ^{-2} generated by SINP magnetoplasmodynamics accelerator. The proton bombardment causes the decrease in optical transmission coefficient of samples, but their transmittance recovers partially after the exposure to oxygen plasma. The results of the comparative analysis of polyimide optical transmission spectra, Raman and XPS spectra obtained at different stages of the irradiation of samples, data on mass loss of samples due to erosion of the surface are

  19. 41 CFR 301-2.4 - For what travel expenses am I responsible?

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 41 Public Contracts and Property Management 4 2014-07-01 2014-07-01 false For what travel expenses am I responsible? 301-2.4 Section 301-2.4 Public Contracts and Property Management Federal Travel Regulation System TEMPORARY DUTY (TDY) TRAVEL ALLOWANCES INTRODUCTION 2-GENERAL RULES § 301-2.4 For...

  20. 41 CFR 301-2.4 - For what travel expenses am I responsible?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 41 Public Contracts and Property Management 4 2010-07-01 2010-07-01 false For what travel expenses am I responsible? 301-2.4 Section 301-2.4 Public Contracts and Property Management Federal Travel Regulation System TEMPORARY DUTY (TDY) TRAVEL ALLOWANCES INTRODUCTION 2-GENERAL RULES § 301-2.4 For...

  1. 41 CFR 301-2.4 - For what travel expenses am I responsible?

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 41 Public Contracts and Property Management 4 2013-07-01 2012-07-01 true For what travel expenses am I responsible? 301-2.4 Section 301-2.4 Public Contracts and Property Management Federal Travel Regulation System TEMPORARY DUTY (TDY) TRAVEL ALLOWANCES INTRODUCTION 2-GENERAL RULES § 301-2.4 For...

  2. 41 CFR 301-2.4 - For what travel expenses am I responsible?

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 41 Public Contracts and Property Management 4 2012-07-01 2012-07-01 false For what travel expenses am I responsible? 301-2.4 Section 301-2.4 Public Contracts and Property Management Federal Travel Regulation System TEMPORARY DUTY (TDY) TRAVEL ALLOWANCES INTRODUCTION 2-GENERAL RULES § 301-2.4 For...

  3. 17 CFR 2.4 - Employee Recreation Association's use of Commission seal.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... Association's use of Commission seal. 2.4 Section 2.4 Commodity and Securities Exchanges COMMODITY FUTURES TRADING COMMISSION OFFICIAL SEAL § 2.4 Employee Recreation Association's use of Commission seal. (a) As a... Employee Recreation Association (“Association”) is hereby authorized to use the Commission seal as...

  4. 17 CFR 2.4 - Employee Recreation Association's use of Commission seal.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... Association's use of Commission seal. 2.4 Section 2.4 Commodity and Securities Exchanges COMMODITY FUTURES TRADING COMMISSION OFFICIAL SEAL § 2.4 Employee Recreation Association's use of Commission seal. (a) As a... Employee Recreation Association (“Association”) is hereby authorized to use the Commission seal as...

  5. 17 CFR 2.4 - Employee Recreation Association's use of Commission seal.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... Association's use of Commission seal. 2.4 Section 2.4 Commodity and Securities Exchanges COMMODITY FUTURES TRADING COMMISSION OFFICIAL SEAL § 2.4 Employee Recreation Association's use of Commission seal. (a) As a... Employee Recreation Association (“Association”) is hereby authorized to use the Commission seal as...

  6. 17 CFR 2.4 - Employee Recreation Association's use of Commission seal.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... Association's use of Commission seal. 2.4 Section 2.4 Commodity and Securities Exchanges COMMODITY FUTURES TRADING COMMISSION OFFICIAL SEAL § 2.4 Employee Recreation Association's use of Commission seal. (a) As a... Employee Recreation Association (“Association”) is hereby authorized to use the Commission seal as...

  7. 17 CFR 2.4 - Employee Recreation Association's use of Commission seal.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... Association's use of Commission seal. 2.4 Section 2.4 Commodity and Securities Exchanges COMMODITY FUTURES TRADING COMMISSION OFFICIAL SEAL § 2.4 Employee Recreation Association's use of Commission seal. (a) As a... Employee Recreation Association (“Association”) is hereby authorized to use the Commission seal as...

  8. 41 CFR 301-2.4 - For what travel expenses am I responsible?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 41 Public Contracts and Property Management 4 2011-07-01 2011-07-01 false For what travel expenses am I responsible? 301-2.4 Section 301-2.4 Public Contracts and Property Management Federal Travel Regulation System TEMPORARY DUTY (TDY) TRAVEL ALLOWANCES INTRODUCTION 2-GENERAL RULES § 301-2.4 For...

  9. 40 CFR 180.142 - 2,4-D; tolerances for residues.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ...,4-D; tolerances for residues. (a) General. Tolerances are established for residues of the herbicide... § 180.1(l), are established for residues of the herbicide, plant regulator, and fungicide 2,4-D (2,4... established for indirect or inadvertent residues of the herbicide, plant regulator, and fungicide 2,4-D...

  10. 40 CFR 180.142 - 2,4-D; tolerances for residues.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ...,4-D; tolerances for residues. (a) General. Tolerances are established for residues of the herbicide... § 180.1(m), are established for residues of the herbicide, plant regulator, and fungicide 2,4-D (2,4... established for indirect or inadvertent residues of the herbicide, plant regulator, and fungicide 2,4-D...

  11. 9 CFR 2.4 - Non-interference with APHIS officials.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 9 Animals and Animal Products 1 2012-01-01 2012-01-01 false Non-interference with APHIS officials. 2.4 Section 2.4 Animals and Animal Products ANIMAL AND PLANT HEALTH INSPECTION SERVICE, DEPARTMENT OF AGRICULTURE ANIMAL WELFARE REGULATIONS Licensing § 2.4 Non-interference with APHIS officials....

  12. 9 CFR 2.4 - Non-interference with APHIS officials.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 9 Animals and Animal Products 1 2013-01-01 2013-01-01 false Non-interference with APHIS officials. 2.4 Section 2.4 Animals and Animal Products ANIMAL AND PLANT HEALTH INSPECTION SERVICE, DEPARTMENT OF AGRICULTURE ANIMAL WELFARE REGULATIONS Licensing § 2.4 Non-interference with APHIS officials....

  13. 9 CFR 2.4 - Non-interference with APHIS officials.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 9 Animals and Animal Products 1 2011-01-01 2011-01-01 false Non-interference with APHIS officials. 2.4 Section 2.4 Animals and Animal Products ANIMAL AND PLANT HEALTH INSPECTION SERVICE, DEPARTMENT OF AGRICULTURE ANIMAL WELFARE REGULATIONS Licensing § 2.4 Non-interference with APHIS officials....

  14. 9 CFR 2.4 - Non-interference with APHIS officials.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 9 Animals and Animal Products 1 2010-01-01 2010-01-01 false Non-interference with APHIS officials. 2.4 Section 2.4 Animals and Animal Products ANIMAL AND PLANT HEALTH INSPECTION SERVICE, DEPARTMENT OF AGRICULTURE ANIMAL WELFARE REGULATIONS Licensing § 2.4 Non-interference with APHIS officials....

  15. 9 CFR 2.4 - Non-interference with APHIS officials.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 9 Animals and Animal Products 1 2014-01-01 2014-01-01 false Non-interference with APHIS officials. 2.4 Section 2.4 Animals and Animal Products ANIMAL AND PLANT HEALTH INSPECTION SERVICE, DEPARTMENT OF AGRICULTURE ANIMAL WELFARE REGULATIONS Licensing § 2.4 Non-interference with APHIS officials....

  16. A SIMPLE ASSAY FOR 2,4-DICHLOROPHENOXYACETIC ACID USING COATED TEST-STRIPS

    EPA Science Inventory

    Immunoassay test strips utilizing ascending chromatography has been devised for the detection of 2.4-dichlorophenoxyacetic acid (2,4-D). This test requires no instrumentation, inexpensive reagents and relies on the application of antibodies to 2,4-D adsorbed onto colloidal gol...

  17. ELECTROCHEMICALLY DEPOSITED POLYMER-COATED GOLD ELECTRODES SELECTIVE FOR 2,4-DICHLOROPHENOXYACETIC ACID

    EPA Science Inventory

    Electropolymerized membranes on gold electrodes doped with 2,4-dichlorophenoxyacetic acid (2,4-D) were prepared from a solution containing resorcinol, o-phenylenediamine and 2,4-D. Fourier Transform Infrared (FTIR) spectroscopy was used to evaluate the incorporation and interact...

  18. 10 CFR 960.3-2-2-4 - The environmental assessment.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 10 Energy 4 2011-01-01 2011-01-01 false The environmental assessment. 960.3-2-2-4 Section 960.3-2-2-4 Energy DEPARTMENT OF ENERGY GENERAL GUIDELINES FOR THE PRELIMINARY SCREENING OF POTENTIAL SITES FOR A NUCLEAR WASTE REPOSITORY Implementation Guidelines § 960.3-2-2-4 The environmental...

  19. 10 CFR 960.3-2-2-4 - The environmental assessment.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 10 Energy 4 2013-01-01 2013-01-01 false The environmental assessment. 960.3-2-2-4 Section 960.3-2-2-4 Energy DEPARTMENT OF ENERGY GENERAL GUIDELINES FOR THE PRELIMINARY SCREENING OF POTENTIAL SITES FOR A NUCLEAR WASTE REPOSITORY Implementation Guidelines § 960.3-2-2-4 The environmental...

  20. 10 CFR 960.3-2-2-4 - The environmental assessment.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 10 Energy 4 2012-01-01 2012-01-01 false The environmental assessment. 960.3-2-2-4 Section 960.3-2-2-4 Energy DEPARTMENT OF ENERGY GENERAL GUIDELINES FOR THE PRELIMINARY SCREENING OF POTENTIAL SITES FOR A NUCLEAR WASTE REPOSITORY Implementation Guidelines § 960.3-2-2-4 The environmental...

  1. 10 CFR 960.3-2-2-4 - The environmental assessment.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 10 Energy 4 2014-01-01 2014-01-01 false The environmental assessment. 960.3-2-2-4 Section 960.3-2-2-4 Energy DEPARTMENT OF ENERGY GENERAL GUIDELINES FOR THE PRELIMINARY SCREENING OF POTENTIAL SITES FOR A NUCLEAR WASTE REPOSITORY Implementation Guidelines § 960.3-2-2-4 The environmental...

  2. 10 CFR 960.3-2-2-4 - The environmental assessment.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 10 Energy 4 2010-01-01 2010-01-01 false The environmental assessment. 960.3-2-2-4 Section 960.3-2-2-4 Energy DEPARTMENT OF ENERGY GENERAL GUIDELINES FOR THE PRELIMINARY SCREENING OF POTENTIAL SITES FOR A NUCLEAR WASTE REPOSITORY Implementation Guidelines § 960.3-2-2-4 The environmental...

  3. 2,4-D removal via denitrification using volatile fatty acids.

    PubMed

    He, X; Wareham, D G

    2011-01-01

    Many countries have waters contaminated with both herbicides and nitrates; however, information is limited with respect to removal rates for combined nitrate and herbicide elimination. This research investigates the removal of 2,4-D via denitrification, with a particular emphasis on the effect of adding naturally generated volatile fatty acids (VFAs). The acids were produced from an acid-phase anaerobic digester with a mean VFA concentration of 3153±801 mg/L (as acetic acid). Initially, 2,4-D degrading bacteria were developed in an SBR fed with both sewage and 2,4-D (30-100 mg/L). Subsequent denitrification batch tests demonstrated that the specific denitrification rate increased from 0.0119±0.0039 using 2,4-D alone to 0.0192±0.0079 g NO₃-N/g VSS per day, when 2,4-D was combined with natural VFAs from the digester. Similarly, the specific 2,4-D consumption rate increased from 0.0016±0.0009 using 2,4-D alone to 0.0055±0.0021 g 2,4-D/g VSS per day, when using 2,4-D plus natural VFAs. Finally, a parallel increase in the percent 2,4-D removal was observed, rising from 28.33±11.88 using 2,4-D alone to 54.17±21.89 using 2,4-D plus natural VFAs.

  4. Effects of color bands on Semipalmated Sandpipers banded at hatch

    USGS Publications Warehouse

    Bart, J.; Battaglia, D.; Senner, N.

    2001-01-01

    Effects of color bands on adult birds have been investigated in many studies, but much less is known about the effects of bands on birds banded at hatch. We captured Semipalmated Sandpiper (Calidris pusilla) chicks at hatch on the Alaskan North Slope and attached 0-3 bands to them. The chicks were resighted and reweighed during the subsequent two weeks. The number of chicks banded varied from 18 to 21 among treatments; 6-9 were resighted, and 6-7 were reweighed, per treatment. The proportion resighted varied from 0.33 to 0.45. The estimated resighting probability, given that we encountered a brood, was 82%. We tested for effects of the bands on survival and mass gain by analyzing whether the proportion of chicks resighted, or their mass, varied with the number of bands. We found no evidence that bands affected the chicks and were able to rule out (with 95% confidence) a decline in survivorship of more than 13% and a loss of mass of more than 10%. Although bands had little if any effect on chicks in our study, we believe their effects should be evaluated whenever survivorship or mass gain are estimated using color-marked chicks.

  5. Modelling Neutron-induced Reactions on 232-237U from 10 keV up to 30 MeV

    NASA Astrophysics Data System (ADS)

    Sin, M.; Capote, R.; Herman, M. W.; Trkov, A.

    2017-01-01

    Comprehensive calculations of cross sections for neutron-induced reactions on 232-237U targets are performed in the 10 keV-30 MeV incident energy range with the code EMPIRE-3.2 Malta. The advanced modelling and consistent calculation scheme are aimed at improving our knowledge of the neutron scattering and emission cross sections, and to assess the consistency of available evaluated libraries for light uranium isotopes. The reaction model considers a dispersive optical potential (RIPL 2408) that couples from five (even targets) to nine (odd targets) levels of the ground-state rotational band, and a triple-humped fission barrier with absorption in the wells described within the optical model for fission. A modified Lorentzian model (MLO) of the radiative strength function and Enhanced Generalized Superfluid Model nuclear level densities are used in Hauser-Feschbach calculations of the compound-nuclear decay that include width fluctuation corrections. The starting values for the model parameters are retrieved from RIPL. Excellent agreement with available experimental data for neutron emission and fission is achieved, giving confidence that the quantities for which there is no experimental information are also accurately predicted. Deficiencies in existing evaluated libraries are highlighted.

  6. Measured and Simulated Dark J-V Characteristics of a-Si:H Single Junction p-i-n Solar Cells Irradiated with 40 keV Electrons

    NASA Technical Reports Server (NTRS)

    Lord, Kenneth; Woodyard, James R.

    2002-01-01

    The effect of 40 keV electron irradiation on a-Si:H p-i-n single-junction solar cells was investigated using measured and simulated dark J-V characteristics. EPRI-AMPS and PC-1D simulators were explored for use in the studies. The EPRI-AMPS simulator was employed and simulator parameters selected to produce agreement with measured J-V characteristics. Three current mechanisms were evident in the measured dark J-V characteristics after electron irradiation, namely, injection, shunting and a term of the form CV(sup m). Using a single discrete defect state level at the center of the band gap, good agreement was achieved between measured and simulated J-V characteristics in the forward-bias voltage region where the dark current density was dominated by injection. The current mechanism of the form CV(sup m) was removed by annealing for two hours at 140 C. Subsequent irradiation restored the CV(sup m) current mechanism and it was removed by a second anneal. Some evidence of the CV(sup m) term is present in device simulations with a higher level of discrete density of states located at the center of the bandgap.

  7. Removal of 2,4-Dichlorophenolyxacetic acid (2,4-D) herbicide in the aqueous phase using modified granular activated carbon

    PubMed Central

    2014-01-01

    Background Low cost 2,4-Dichlorophenolyxacetic acid (2,4-D) widely used in controlling broad-leafed weeds is frequently detected in water resources. The main objectives of this research were focused on evaluating the feasibility of using granular activated carbon modified with acid to remove 2,4-D from aqueous phase, determining its removal efficiency and assessing the adsorption kinetics. Results The present study was conducted at bench-scale method. The influence of different pH (3–9), the effect of contact time (3–90 min), the amount of adsorbent (0.1-0.4 g), and herbicide initial concentration (0.5-3 ppm) on 2,4-D removal efficiency by the granular activated carbon were investigated. Based on the data obtained in the present study, pH of 3 and contact time of 60 min is optimal for 2,4-D removal. 2,4-D reduction rate increased rapidly by the addition of the adsorbent and decreased by herbicide initial concentration (63%). The percent of 2,4-D reduction were significantly enhanced by decreasing pH and increasing the contact time. The adsorption of 2,4-D onto the granular activated carbon conformed to Langmuir and Freundlich models, but was best fitted to type II Langmuir model (R2 = 0.999). The second order kinetics was the best for the adsorption of 2,4-D by modified granular activated carbon with R2 > 0.99. Regression analysis showed that all of the variables in the process have been statistically significant effect (p < 0.001). Conclusions In conclusion, granular activated carbon modified with acid is an appropriate method for reducing the herbicide in the polluted water resources. PMID:24410737

  8. Inner Magnetosphere keV Ion Drift Path Boundaries as Observed by the Van Allen Probes

    NASA Astrophysics Data System (ADS)

    Strangeway, R. J.; Zhang, J.; Larsen, B.

    2014-12-01

    The drifts of keV ions in the inner magnetosphere are controlled by both electric field drifts and gradient and curvature (i.e., magnetic field) drifts, and further the magnetic field drifts oppose the corotation electric field drift in the dusk local time sector. Consequently, the ion drift paths can be quite complicated with the medium-energy ions drifting close to the Earth, but still being on open drift paths. In addition, structure in the energy-time spectrograms can be a consequence of either particle injection or particle loss. In order to distinguish between the two we will compare the energy-time spectrograms acquired with the Helium Oxygen Proton Electron (HOPE) mass spectrometer on board the Van Allen Probes with predictions of drift path boundaries. The simplest model assumes a uniform convection electric field and dipole model field, and we will use this a starting point for the comparison. The model can be modified to include shielding of the convection electric field, and rotation in local time of the zero-energy dusk-side stagnation point. As an additional check of the model we will compare the electric field used in the model with the electric field as measured by the Van Allen Probes, as well as the validity of using a dipole magnetic field through comparison with the measured magnetic field.

  9. Making channeling visible: keV noble gas ion trails on Pt(111)

    NASA Astrophysics Data System (ADS)

    Redinger, A.; Standop, S.; Rosandi, Y.; Urbassek, H. M.; Michely, T.

    2011-01-01

    The impact of argon and xenon noble gas ions on Pt(111) in grazing incidence geometry are studied through direct comparison of scanning tunneling microscopy images and molecular dynamics simulations. The energy range investigated is 1-15 keV and the angles of incidence with respect to the surface normal are between 78.5° and 88°. The focus of the paper is on events where ions gently enter the crystal at steps and are guided in channels between the top most layers of the crystal. The trajectories of the subsurface channeled ions are visible as trails of surface damage. The mechanism of trail formation is analyzed using simulations and analytical theory. Significant differences between Xe+ and Ar+ projectiles in damage, in the onset energy of subsurface channeling as well as in ion energy dependence of trail length and appearance are traced back to the projectile and ion energy dependence of the stopping force. The asymmetry of damage production with respect to the ion trajectory direction is explained through the details of the channel shape and subchannel structure as calculated from the continuum approximation of the channel potential. Measured and simulated channel switching in directions normal and parallel to the surface as well as an increase of ions entering into channels from the perfect surface with increasing angles of incidence are discussed.

  10. The poker face of the Majoron dark matter model: LUX to keV line

    NASA Astrophysics Data System (ADS)

    Queiroz, Farinaldo S.; Sinha, Kuver

    2014-07-01

    We study the viability of pseudo Nambu-Goldstone bosons (Majorons) arising in see-saw models as dark matter candidates. Interestingly the stability of the Majoron as dark matter is related to the scale that sets the see-saw and leptogenesis mechanisms, while its annihilation and scattering cross section off nuclei can be set through the Higgs portal. For O (GeV)- O (TeV) Majorons, we compute observables such as the abundance, scattering cross section, Higgs invisible decay width, and emission lines and compare with current data in order to outline the excluded versus still viable parameter space regions. We conclude that the simplest Majoron dark matter models coupling through the Higgs portal, except at the Higgs resonance, are excluded by current direct detection data for Majorons lighter than 225 GeV and future runnings are expected to rule out decisively the 1 GeV-1 TeV window. Lastly, we point out that light keV-scale Majorons whose relic density is set by thermal freeze-in from sterile neutrinos can account for the keV line observed by XMM-Newton observatory in the spectrum of 73 galaxy clusters, within a see-saw model with a triplet Higgs.

  11. Frequency analysis of 4- to 6-keV electrons associated with an auroral arc

    NASA Technical Reports Server (NTRS)

    Murphree, J. S.; Anderson, H. R.

    1978-01-01

    The high time resolution (HTR) experiment considered consists of four sections, including electrostatic deflection plates, electron multiplier, preamplifier-integrator, and frequency analyzer. Electrons in the energy range from 4 to 6 keV electrons are selected by the deflection system, after which they are detected, multiplied, and passed to the charge sensitive preamplifier. The charge pulses are amplified and integrated, and the resulting voltage pulse series is fed to the frequency analyzer. The experiment is essentially a flux detector, so that estimates of the input flux can be made from the mean value of the output spectrum. The results obtained with the HTR in a rocket flight on March 14, 1974, are discussed. The lack of modulation noticed in the high-frequency range indicates that there is insufficient wave energy available in the vicinity of the rocket to produce a wave-particle interaction which the HTR is able to observe. This finding is consistent with the stabilization of the plasma by the low flux of energetic electrons.

  12. High-efficiency multilevel zone plates for keV X-rays

    NASA Astrophysics Data System (ADS)

    di Fabrizio, E.; Romanato, F.; Gentili, M.; Cabrini, S.; Kaulich, B.; Susini, J.; Barrett, R.

    1999-10-01

    The development of high brilliance X-ray sources coupled with advances in manufacturing technologies has led to significant improvements in submicrometre probes for spectroscopy, diffraction and imaging applications. The generation of a small beam spot size is commonly based on three principles: total reflection (as used in optical elements involving mirrors or capillaries), refraction (such as in refractive lenses) and diffraction. The latter effect is employed in Bragg-Fresnel or Soret lenses, commonly known as Fresnel zone plate lenses. These lenses currently give the best spatial resolution, but are traditionally limited to rather soft X-rays-at high energies, their use is still limited by their efficiency. Here we report the fabrication of high-efficiency, high-contrast gold and nickel multistep (quaternary) Fresnel zone plates using electron beam lithography. We achieve a maximum efficiency of 55% for the nickel plate at 7keV. In addition to their high efficiency, the lenses offer the advantages of low background signal and effective reduction of unwanted diffraction orders. We anticipate that these lenses should have a significant impact on techniques such as microscopy, micro-fluorescence and micro-diffraction, which require medium resolution (500-100nm) and high flux at fixed energies.

  13. A DATABASE OF >20 keV ELECTRON GREEN'S FUNCTIONS OF INTERPLANETARY TRANSPORT AT 1 AU

    SciTech Connect

    Agueda, N.; Sanahuja, B.; Vainio, R.

    2012-10-15

    We use interplanetary transport simulations to compute a database of electron Green's functions, i.e., differential intensities resulting at the spacecraft position from an impulsive injection of energetic (>20 keV) electrons close to the Sun, for a large number of values of two standard interplanetary transport parameters: the scattering mean free path and the solar wind speed. The nominal energy channels of the ACE, STEREO, and Wind spacecraft have been used in the interplanetary transport simulations to conceive a unique tool for the study of near-relativistic electron events observed at 1 AU. In this paper, we quantify the characteristic times of the Green's functions (onset and peak time, rise and decay phase duration) as a function of the interplanetary transport conditions. We use the database to calculate the FWHM of the pitch-angle distributions at different times of the event and under different scattering conditions. This allows us to provide a first quantitative result that can be compared with observations, and to assess the validity of the frequently used term beam-like pitch-angle distribution.

  14. The production and sputtering of S2 by keV ion bombardment

    NASA Technical Reports Server (NTRS)

    Boring, J. W.; Chrisey, D. B.; Oshaughnessy, D. J.; Phipps, J. A.; Zhao, N.

    1986-01-01

    The ion bombardment of S-containing molecules in comets is simulated experimentally. Mass-analyzed 30-keV beams of Ar(+) and He(+) are directed at solid S, H2S, and CS2 targets at temperatures 15 K, and the neutral molecular species produced are ionized and analyzed using a quadrupole mass spectrometer. The dominant species detected are S1 and S2 for the S target, H2S and S2 for the H2S target, and S, CS, S2, and CS2 for the CS2 target. In the latter case, it is found that after about 10 to the 14th He(+) ions/sq cm have struck the target, further sputtering is prevented by formation of a dark brown deposit which is stable at room temperature; the residue forms more slowly when Ar(+) ions are used. These results, indicating relatively efficient S2 production by ion bombardment, are applied to theoretical models of S2 production and/or ejection by solar-wind, solar-flare, or cosmic-ray ions striking comets. It is found that direct solar-wind production of S2 by sputtering is unlikely at realistic bombardment rates, but that H2S-S2 conversion by energetic ions could be significant, with less stringent ice-temperature and irradiation-flux constraints than in the case of S2 production by photons.

  15. Is keV ion-induced pattern formation on Si(001) caused by metal impurities?

    PubMed

    Macko, Sven; Frost, Frank; Ziberi, Bashkim; Förster, Daniel F; Michely, Thomas

    2010-02-26

    We present ion beam erosion experiments performed in ultrahigh vacuum using a differentially pumped ion source and taking care that the ion beam hits the Si(001) sample only. Under these conditions no ion beam patterns form on Si for angles theta < or = 45 degrees with respect to the global surface normal using 2 keV Kr+ and fluences of approximately 2 x 10(22) ions m(-2). In fact, the ion beam induces a smoothening of preformed patterns. Simultaneous sputter deposition of stainless steel in this angular range creates a variety of patterns, similar to those previously ascribed to clean ion-beam-induced destabilization of the surface profile. Only for grazing incidence with 60 degrees < or = theta < or = 83 degrees do pronounced ion beam patterns form. It appears that the angular-dependent stability of Si(001) against pattern formation under clean ion beam erosion conditions is related to the angular dependence of the sputtering yield, and not primarily to a curvature-dependent yield as invoked frequently in continuum theory models.

  16. Electron capture in Ar++H2 collisions in the keV energy regime

    NASA Astrophysics Data System (ADS)

    Kimura, M.; Chapman, S.; Lane, N. F.

    1986-03-01

    Electron capture in Ar+( 2P)+H2(X 1Σg) collisions in the keV energy regime has been studied theoretically. The molecular-orbital expansion method was used within a semiclassical formalism and an electron translation factor correction was incorporated to the first order in the magnitude of the relative velocity V. The molecular wave function and eigenenergy were obtained using the diatoms-in-molecules (DIM) method. We have examined the effect of the orientation of the target H2 molecule on the electron-capture mechanism within the sudden adiabatic approximation. Since π symmetry arising from the p orbital of the Ar+ ion is involved in this system, a strong influence on the probability of the molecular orientation was found in all energies studied. As the collision energy increases, the Π-symmetry state in the initial channel becomes more important through the rotational coupling to the electron-capture mechanism, while at lower energies the Σ-symmetry state in the initial channel is the dominant source for the electron capture through strong radial coupling. Agreement of the present theory with measurements is good, but marked disagreement is seen with the atomic-orbital calculation.

  17. The galactic 511 keV line from electroweak scale WIMPs

    NASA Astrophysics Data System (ADS)

    Pospelov, Maxim; Ritz, Adam

    2007-07-01

    We consider possible mechanisms via which electroweak scale WIMPs χ could provide the source of the INTEGRAL/SPI 511 keV photon flux from the galactic centre. We consider scenarios where the WIMP spectrum contains near-degeneracies, with MeV-scale splitting, and focus on three possible production mechanisms for galactic positrons: (i) collisional excitation of the WIMP to a nearby charged state, χ+χ→χ+χ, with the subsequent decay producing positrons; (ii) capture of the WIMP by nuclei in the galactic interstellar medium, χ+N→e+(χN); and (iii) the decay of a nearby long-lived state surviving from the big bang, χ20→χ10+e+e. We find that process (i) requires a cross section which is significantly larger than the unitarity bound, process (ii) is allowed by unitarity, but is impractical due to terrestrial bounds on the χN cross section, while process (iii) is viable and we construct a simple model realization with singlet dark matter fields interacting with the Standard Model via the Higgs sector.

  18. Black-hole Binaries: Life Begins at 40 keV

    NASA Astrophysics Data System (ADS)

    Belloni, Tomaso M.; Motta, Sara

    2009-05-01

    In the study of black-hole transients, an important problem that still needs to be answered is how the high-energy part of the spectrum evolves from the low-hard to the high-soft state, given that they have very different properties. Recent results obtained with RXTE and INTEGRAL have given inconsistent results. With RXTE, we have found that the high-energy cutoff in GX 339-4 during the transition first decreases (during the low-hard state), then increases again across the Hard-Intermediate state, to become unmeasurable in the soft states (possibly because of statistical limitations). We show Simbol-X will be able to determine the spectral shape with superb accuracy. As the high-energy part of the spectrum is relatively less known than the one below 20 keV, Simbol-X will provide important results that will help out understanding of the extreme physical conditions in the vicinity of a stellar-mass black hole.

  19. Origins of Anisotropic 40 300 keV Electron Events Observed at Low and High Latitudes

    NASA Astrophysics Data System (ADS)

    Hawkins, S. E., III; Gold, R. E.; Pick, M.; Maia, D.

    2001-05-01

    Using a survey of anisotropic electron events in the energy range of ˜40 300 keV observed by HI-SCALE on Ulysses, we have selected several time intervals during 1999 when Ulysses traveled from about 20° S at 5.2 AU (January 1999) to 42° S at 4.2 AU (January 2000). We compare these events with observations at ˜1 AU using the nearly identical instrument, EPAM on ACE. In order to study the solar origins of these electrons using the imaging Nançay Radioheliograph, we further restricted the list of events to those in which interplanetary magnetic field lines with origins on the visible solar disk, intersected Ulysses. We find that not all the anisotropic electron events are observed by both spacecraft and there exists a strong dependence on the spacecraft's magnetic connection back to the Sun. We have identified the solar origin for five electron events using radio observations, and correlate these with interplanetary type-III radio emissions using the WIND/WAVES experiment.

  20. ON THE SPECTRAL HARDENING AT {approx}>300 keV IN SOLAR FLARES

    SciTech Connect

    Li, G.; Kong, X.; Zank, G.; Chen, Y.

    2013-05-20

    It has long been noted that the spectra of observed continuum emissions in many solar flares are consistent with double power laws with a hardening at energies {approx}>300 keV. It is now widely believed that at least in electron-dominated events, the hardening in the photon spectrum reflects an intrinsic hardening in the source electron spectrum. In this paper, we point out that a power-law spectrum of electrons with a hardening at high energies can be explained by the diffusive shock acceleration of electrons at a termination shock with a finite width. Our suggestion is based on an early analytical work by Drury et al., where the steady-state transport equation at a shock with a tanh profile was solved for a p-independent diffusion coefficient. Numerical simulations with a p-dependent diffusion coefficient show hardenings in the accelerated electron spectrum that are comparable with observations. One necessary condition for our proposed scenario to work is that high-energy electrons resonate with the inertial range of the MHD turbulence and low-energy electrons resonate with the dissipation range of the MHD turbulence at the acceleration site, and the spectrum of the dissipation range {approx}k {sup -2.7}. A {approx}k {sup -2.7} dissipation range spectrum is consistent with recent solar wind observations.

  1. Monte Carlo calculations of energy deposition distributions of electrons below 20 keV in protein.

    PubMed

    Tan, Zhenyu; Liu, Wei

    2014-05-01

    The distributions of energy depositions of electrons in semi-infinite bulk protein and the radial dose distributions of point-isotropic mono-energetic electron sources [i.e., the so-called dose point kernel (DPK)] in protein have been systematically calculated in the energy range below 20 keV, based on Monte Carlo methods. The ranges of electrons have been evaluated by extrapolating two calculated distributions, respectively, and the evaluated ranges of electrons are compared with the electron mean path length in protein which has been calculated by using electron inelastic cross sections described in this work in the continuous-slowing-down approximation. It has been found that for a given energy, the electron mean path length is smaller than the electron range evaluated from DPK, but it is large compared to the electron range obtained from the energy deposition distributions of electrons in semi-infinite bulk protein. The energy dependences of the extrapolated electron ranges based on the two investigated distributions are given, respectively, in a power-law form. In addition, the DPK in protein has also been compared with that in liquid water. An evident difference between the two DPKs is observed. The calculations presented in this work may be useful in studies of radiation effects on proteins.

  2. The System of Nanosecond 280-KeV He+ Pulsed Beam

    SciTech Connect

    Junphong, P.; Ano, V.; Lekprasert, B.; Suwannakachorn, D.; Thongnopparat, N.; Vilaithong, T.; Wiedemann, H.; /SLAC /SLAC, SSRL

    2006-05-01

    At Fast Neutron Research Facility, the 150 kV-pulses neutron generator is being upgraded to a 280-kV-pulsed-He beam for time-of-flight Rutherford backscattering spectrometry. It involves replacing the existing beam line elements by a multicusp ion source, a 400-kV accelerating tube, 45{sup o}-double focusing dipole magnet and quadrupole lens. The multicusp ion source is a compact filament-driven of 2.6 cm in diameter and 8 cm in length. The current extracted is 20.4 {micro}A with 13 kV of extraction voltage and 8.8 kV of Einzel lens voltage. The beam emittance has found to vary between 6-12 mm mrad. The beam transport system has to be redesigned based on the new elements. The important part of a good pulsed beam depends on the pulsing system. The two main parts are the chopper and buncher. An optimized geometry for the 280 keV pulsed helium ion beam will be presented and discussed. The PARMELA code has been used to optimize the space charge effect, resulting in pulse width of less than 2 ns at a target. The calculated distance from a buncher to the target is 4.6 m. Effects of energy spread and phase angle between chopper and buncher have been included in the optimization of the bunch length.

  3. Sputtering of octatetraene by 15 keV C60 projectiles: Comparison of reactive interatomic potentials

    NASA Astrophysics Data System (ADS)

    Kanski, Michal; Maciazek, Dawid; Golunski, Mikolaj; Postawa, Zbigniew

    2017-02-01

    Molecular dynamics computer simulations have been used to probe the effect of the AIREBO, ReaxFF and COMB3 interatomic potentials on sputtering of an organic sample composed of octatetraene molecules. The system is bombarded by a 15 keV C60 projectile at normal incidence. The effect of the applied force fields on the total time of simulation, the calculated sputtering yield and the angular distribution of sputtered particles is investigated and discussed. It has been found that caution should be taken when simulating particles ejection from nonhomogeneous systems that undergo significant fragmentation described by the ReaxFF. In this case, the charge state of many particles is improper due to an inadequacy of a procedure used for calculating partial charges on atoms in molecules for conditions present during sputtering. A two-step simulation procedure is proposed to minimize the effect of this deficiency. There is also a possible problem with the COMB3 potential, at least at conditions present during cluster impact, as its results are very different from AIREBO or ReaxFF.

  4. Silicon photodiode characterization from 1 eV to 10 keV

    SciTech Connect

    Idzorek, G.C.; Bartlett, R.J.

    1997-10-01

    Silicon photodiodes offer a number of advantages over conventional photocathode type soft x-ray detectors in pulsed power experiments. These include a nominally flat response, insensitivity to surface contamination, low voltage biasing requirements, sensitivity to low energy photons, excellent detector to detector response reproducibility, and ability to operate in poor vacuum or gas backfilled experiments. Silicon photodiodes available from International Radiation Detectors (IRD), Torrance, California have been characterized for absolute photon response from 1 eV to 10 keV photon energy, time response, and signal saturation levels. The authors have assembled individually filtered photodiodes into an array designated the XUV-7. The XUV-7 provides seven photodiodes in a vacuum leak tight, electrically isolated, low noise, high bandwidth, x-ray filtered assembly in a compact package with a 3.7 cm outside diameter. In addition they have assembled the diodes in other custom configurations as detectors for spectrometers. Their calibration measurements show factor of ten deviations from the silicon photodiode theoretical flat response due to diode sensitivity outside the center `sensitive area`. Detector response reproducibility between diodes appears to be better than 5%. Time response measurements show a 10-90% rise time of about 0.1 nanoseconds and a fall time of about 0.5 nanoseconds. Silicon photodiodes have proven to be a versatile and useful complement to the standard photocathode detectors for soft x-ray measurement and are very competitive with diamond for a number of applications.

  5. Pitch angle distributions of 35-1000 keV protons at quasi-perpendicular interplanetary shocks

    NASA Technical Reports Server (NTRS)

    Balogh, A.; Erdoes, G.

    1985-01-01

    The characteristic features of the scatter-free acceleration process near perpendicular shocks are examined in the upstream and downstream pitch angle distributions of 35 to 1000 keV protons. Reasonable quantitative agreement is found between theoretical predictions and observations. The role played by bottle geometries, leading to enhanced acceleration, is highlighted.

  6. Intensity of 253 keV {gamma}-rays ({sup 245}Am) from {alpha}-decay of {sup 249}Bk

    SciTech Connect

    Popov, Yu.S.; Srurov, D.Kh.; Baranov, A.A.; Chistyakov, V.M.; Timofeev, G.A.

    1995-01-01

    The intensity of 253 keV {gamma}-rays ({sup 245}Am) from {alpha}-decay of {sup 249}Bk is 3.09(9)% at the P = 0.95 confidence level. Precision semi-conducting {gamma}-spectrometry and coulometry are used.

  7. Comparative Effects of 10.2 eV Photon and 200 keV Proton Irradiation on Condensed CO

    NASA Astrophysics Data System (ADS)

    Loeffler, M. J.; Baratta, G. A.; Palumbo, M. E.; Strazzulla, G.; Baragiola, R. A.

    2004-03-01

    We present results from experiments that use infrared spectroscopy to compare production rates of carbon dioxide formed by UV photolysis and 200 keV proton irradiation of carbon monoxide ice at 16 K. We find production rates to be similar for both types of irradiation.

  8. 3.55 keV photon lines from axion to photon conversion in the Milky Way and M31

    SciTech Connect

    Conlon, Joseph P.; Day, Francesca V. E-mail: francesca.day@physics.ox.ac.uk

    2014-11-01

    We further explore a scenario in which the recently observed 3.55 keV photon line arises from dark matter decay to an axion-like particle (ALP) of energy 3.55 keV, which then converts to a photon in astrophysical magnetic fields. This ALP scenario is well-motivated by the observed morphology of the 3.55 keV flux. For this scenario we study the expected flux from dark matter decay in the galactic halos of both the Milky Way and Andromeda (M31). The Milky Way magnetic field is asymmetric about the galactic centre, and so the resulting 3.55 keV flux morphology differs significantly from the case of direct dark matter decay to photons. However the Milky Way magnetic field is not large enough to generate an observable signal, even with ASTRO-H. In contrast, M31 has optimal conditions for a → γ conversion and the intrinsic signal from M31 becomes two orders of magnitude larger than for the Milky Way, comparable to that from clusters and consistent with observations.

  9. Radial Profile of the 3.5 keV Line Out to R200 in the Perseus Cluster

    NASA Astrophysics Data System (ADS)

    Franse, Jeroen; Bulbul, Esra; Foster, Adam; Boyarsky, Alexey; Markevitch, Maxim; Bautz, Mark; Iakubovskyi, Dmytro; Loewenstein, Mike; McDonald, Michael; Miller, Eric; Randall, Scott W.; Ruchayskiy, Oleg; Smith, Randall K.

    2016-10-01

    The recent discovery of the unidentified emission line at 3.5 keV in galaxies and clusters has attracted great interest from the community. As the origin of the line remains uncertain, we study the surface brightness distribution of the line in the Perseus cluster since that information can be used to identify its origin. We examine the flux distribution of the 3.5 keV line in the deep Suzaku observations of the Perseus cluster in detail. The 3.5 keV line is observed in three concentric annuli in the central observations, although the observations of the outskirts of the cluster did not reveal such a signal. We establish that these detections and the upper limits from the non-detections are consistent with a dark matter decay origin. However, absence of positive detection in the outskirts is also consistent with some unknown astrophysical origin of the line in the dense gas of the Perseus core, as well as with a dark matter origin with a steeper dependence on mass than the dark matter decay. We also comment on several recently published analyses of the 3.5 keV line.

  10. Observational consistency and future predictions for a 3.5 keV ALP to photon line

    SciTech Connect

    Alvarez, Pedro D.; Conlon, Joseph P.; Day, Francesca V.; Marsh, M.C. David; Rummel, Markus

    2015-04-09

    Motivated by the possibility of explaining the 3.5 keV line through dark matter decaying to axion-like particles that subsequently convert to photons, we study ALP-photon conversion for sightlines passing within 50 pc of the galactic centre. Conversion depends on the galactic centre magnetic field which is highly uncertain. For fields at low or mid-range of observational estimates (10–100 μG), no observable signal is possible. For fields at the high range of observational estimates (a pervasive poloidal mG field over the central 150 pc) it is possible to generate sufficient signal to explain recent observations of a 3.5 keV line in the galactic centre. In this scenario, the galactic centre line signal comes predominantly from the region with z>20pc, reconciling the results from the Chandra and XMM-Newton X-ray telescopes. The dark matter to ALP to photon scenario also naturally predicts the non-observation of the 3.5 keV line in stacked galaxy spectra. We further explore predictions for the line flux in galaxies and suggest a set of galaxies that is optimised for observing the 3.5 keV line in this model.

  11. Measuring the 511 keV emission in the direction of 1E1740.7-2942 with BATSE

    NASA Technical Reports Server (NTRS)

    Wallyn, P.; Ling, J. C.; Mahoney, W. A.; Wheaton, W. A.; Durouchoux, P.; Corbel, S.; Astier-Perret, L.; Poirot, L.

    1997-01-01

    Observations of the 511 keV emission in the direction of 1E 1740.7-2942 (1E) using the earth burst and transient source experiment (BATSE) onboard the Compton Gamma Ray Observatory (CGRO), are presented. The CGRO phase 1 average spectrum of 1E is calculated using a method which assumes that a given source spectrum is the sum of the flux coming directly from the object and the contribution from the surrounding diffuse emission. The 1E light curve is calculated in the 40 to 150 keV range. It presents a constant flux excess of 70 mCrab in comparison with observations from the SIGMA gamma ray telescope onboard the GRANAT observatory. By removing this contribution, the 1E spectral transition from the low state to the high standard state observed by SIGMA is confirmed, and it is shown that the 511 keV flux is independent of the 1E long term evolution from low state to high standard state. It is concluded that the 511 keV emission of (4.2 +/- 1.3) x 140(exp -4) photons/sq cm s observed in the direction of 1E is mainly diffuse and spatially extended.

  12. OSSE observations of Galactic 511 keV positron annihilation radiation - Initial phase 1 results. [Oriented Scintillation Spectrometer Experiment

    NASA Technical Reports Server (NTRS)

    Purcell, W. R.; Grabelsky, D. A.; Ulmer, M. P.; Johnson, W. N.; Kinzer, R. L.; Kurfess, J. D.; Strickman, M. S.; Jung, G. V.

    1993-01-01

    The Oriented Scintillation Spectrometer Experiment (OSSE) on the Compton Gamma-Ray Observatory (GRO) has performed numerous observations of the Galactic plane and Galactic center region to measure the distribution of Galactic 511 keV positron annihilation radiation and to search for time variability of the emission. The initial 511 keV line fluxes for the observations performed during the first 18 months of the GRO mission are presented. The 511 keV line flux for a typical Galactic center observation is (2.5 +/- 0.3) x 10 exp -4 gamma/sq cm per sec, where the quoted uncertainty represents the 1 sigma statistical uncertainty. No statistically significant time variability of the line flux has been observed; the 3 sigma upper limit to daily variations from the mean is 3 x 10 exp -4 gamma/sq cm per sec. The distribution of Galactic 511 keV positron annihilation radiation implied by the OSSE observations is discussed and compared with observations by other instruments.

  13. Photonic band structure

    SciTech Connect

    Yablonovitch, E.

    1993-05-01

    We learned how to create 3-dimensionally periodic dielectric structures which are to photon waves, as semiconductor crystals are to electron waves. That is, these photonic crystals have a photonic bandgap, a band of frequencies in which electromagnetic waves are forbidden, irrespective of propagation direction in space. Photonic bandgaps provide for spontaneous emission inhibition and allow for a new class of electromagnetic micro-cavities. If the perfect 3-dimensional periodicity is broken by a local defect, then local electromagnetic modes can occur within the forbidden bandgap. The addition of extra dielectric material locally, inside the photonic crystal, produces {open_quotes}donor{close_quotes} modes. Conversely, the local removal of dielectric material from the photonic crystal produces {open_quotes}acceptor{close_quotes} modes. Therefore, it will now be possible to make high-Q electromagnetic cavities of volume {approx_lt}1 cubic wavelength, for short wavelengths at which metallic cavities are useless. These new dielectric micro-resonators can cover the range all the way from millimeter waves, down to ultraviolet wavelengths.

  14. Band calculation of lonsdaleite Ge

    NASA Astrophysics Data System (ADS)

    Chen, Pin-Shiang; Fan, Sheng-Ting; Lan, Huang-Siang; Liu, Chee Wee

    2017-01-01

    The band structure of Ge in the lonsdaleite phase is calculated using first principles. Lonsdaleite Ge has a direct band gap at the Γ point. For the conduction band, the Γ valley is anisotropic with the low transverse effective mass on the hexagonal plane and the large longitudinal effective mass along the c axis. For the valence band, both heavy-hole and light-hole effective masses are anisotropic at the Γ point. The in-plane electron effective mass also becomes anisotropic under uniaxial tensile strain. The strain response of the heavy-hole mass is opposite to the light hole.

  15. Neutron transmission and capture measurements and analysis of /sup 60/Ni from 1 to 450 keV

    SciTech Connect

    Perey, C.M.; Harvey, J.A.; Macklin, R.L.; Winters, R.R.; Perey, F.G.

    1982-11-01

    High-resolution transmission and capture measurements of /sup 60/Ni-enriched targets have been made at the Oak Ridge Electron Linear Accelerator (ORELA) from a few eV to 1800 keV in transmission and from 2.5 keV to 5 MeV in capture . The transmission data from 1 to 450 keV were analyzed with a multi-level R-matrix code which uses the Bayes' theorem for the fitting process. This code provides the energies and neutron widths of the resonances inside the 1- to 450-keV region as well as a possible parameterization for outside resonances to describe the smooth cross section in this region. The capture data were analyzed with a least-squares fitting code using the Breit-Wigner formula. From 2.5 to 450 keV, 166 resonances were seen in both sets of data. Correspondence between the energy scales shows a discontinuity around 300 keV which makes the matching of resonances at higher energies difficult. Eighty-nine resonances were seen in the capture data only. Average parameters for the 30 observed s-wave resonances were deduced. The average level spacing D/sub 0/ was found to be equal to 15.2 +- 1.5 keV, the strength function, S/sub 0/, equal to (2.2 +- 0.6) x 10/sup -4/ and the average radiation width, GAMMA/sub ..gamma../, equal to 1.30 +- 0.07 eV. The staircase plot of the reduced level widths and the plot of the Lorentz-weighted strength function averaged over various energy intervals show possible evidence for doorway states. The level densities calculated with the Fermi-gas model for l = 0 and for l > 0 resonances were compared with the cumulative number of observed resonances, but the analysis is not conclusive. The average capture cross section as a function of the neutron incident energy is compared to the tail of the giant electric dipole resonance prediction.

  16. A Catalog of Soft X-Ray Shadows, and More Contemplation of the 1/4 KeV Background

    NASA Technical Reports Server (NTRS)

    Snowden, S. L.; Freyberg, M. J.; Kuntz, K. D.; Sanders, W. T.

    1999-01-01

    This paper presents a catalog of shadows in the 1/4 keV soft X-ray diffuse background 4 (SXRB) that were identified by a comparison between ROSAT All-Sky Survey maps and DIRB&corrected IRAS 100 micron maps. These "shadows" are the negative correlations between the surface brightness of the SXRB and the column density of the Galactic interstellar medium (ISIM) over limited angular regions (a few degrees in extent). We have compiled an extensive but not exhaustive set of 378 shadows in the polar regions of the Galaxy (Absolute value (beta) > and approximately equal 20 deg.), and determined their foreground and background X-ray intensities (relative to the absorbing features), and the respective hardness ratios of that emission. The portion of the sky that was examined to find these shadows was restricted in general to regions where the minimum column density is less than and approximately equal to 4 x 10(exp 20) H/square cm, i.e., relatively high Galactic latitudes, and to regions away from distinct extended features in the SXRB such as supernova remnants and superbubbles. The results for the foreground intensities agree well with the recent results of a general analysis of the local 1/4 KeV emission while the background intensities show additional. but not unexpected scatter. The results also confirm the existence of a gradient in the hardness of the local 1/4 keV emission along a Galactic center/ anticenter axis with a temperature that varies from 10(exp 6.13) K to 10(exp 6.02) K, respectively. The average temperature of the foreground component from this analysis is 10(exp 6.08) K, compared to 10(exp 6.06) K in the previous analysis. Likewise, the average temperature for the distant component for the current and previous analyses are 10(exp 6.06) K and 10(exp 6.02) K, respectively. Finally, the results for the 1/4 keV halo emission are compared to the observed fluxes at 3/4 keV, where the lack of correlation suggests that the Galactic halo's 1/4 keV and 3/4 keV

  17. Multiwavelength observations of the energetic GRB 080810: detailed mapping of the broad-band spectral evolution

    NASA Astrophysics Data System (ADS)

    Page, K. L.; Willingale, R.; Bissaldi, E.; Postigo, A. De Ugarte; Holland, S. T.; McBreen, S.; O'Brien, P. T.; Osborne, J. P.; Prochaska, J. X.; Rol, E.; Rykoff, E. S.; Starling, R. L. C.; Tanvir, N. R.; van der Horst, A. J.; Wiersema, K.; Zhang, B.; Aceituno, F. J.; Akerlof, C.; Beardmore, A. P.; Briggs, M. S.; Burrows, D. N.; Castro-Tirado, A. J.; Connaughton, V.; Evans, P. A.; Fynbo, J. P. U.; Gehrels, N.; Guidorzi, C.; Howard, A. W.; Kennea, J. A.; Kouveliotou, C.; Pagani, C.; Preece, R.; Perley, D.; Steele, I. A.; Yuan, F.

    2009-11-01

    GRB 080810 was one of the first bursts to trigger both Swift and the Fermi Gamma-ray Space Telescope. It was subsequently monitored over the X-ray and UV/optical bands by Swift, in the optical by Robotic Optical Transient Search Experiment (ROTSE) and a host of other telescopes, and was detected in the radio by the Very Large Array. The redshift of z = 3.355 +/- 0.005 was determined by Keck/High Resolution Echelle Spectrometer (HIRES) and confirmed by RTT150 and NOT. The prompt gamma/X-ray emission, detected over 0.3-103 keV, systematically softens over time, with Epeak moving from ~600 keV at the start to ~40 keV around 100s after the trigger; alternatively, this spectral evolution could be identified with the blackbody temperature of a quasi-thermal model shifting from ~60 to ~3keV over the same time interval. The first optical detection was made at 38s, but the smooth, featureless profile of the full optical coverage implies that this is originated from the afterglow component, not from the pulsed/flaring prompt emission. Broad-band optical and X-ray coverage of the afterglow at the start of the final X-ray decay (~8ks) reveals a spectral break between the optical and X-ray bands in the range of 1015-2 × 1016Hz. The decay profiles of the X-ray and optical bands show that this break initially migrates blueward to this frequency and then subsequently drifts redward to below the optical band by ~3 × 105s. GRB 080810 was very energetic, with an isotropic energy output for the prompt component of 3 × 1053 and 1.6 × 1052 erg for the afterglow; there is no evidence for a jet break in the afterglow up to 6d following the burst. This paper is dedicated to the memory of Professor Martin Turner, who sadly passed away during its writing. Martin was an influential figure in X-ray Astronomy and an excellent PhD supervisor. He will be greatly missed. E-mail: kpa@star.le.ac.uk ‡ NASA postdoctoral program fellow.

  18. The Context for IMAP: Voyager and INCA Observations of the Heliosheath at E > 5 keV

    NASA Astrophysics Data System (ADS)

    Krimigis, Stamatios M.

    2016-04-01

    The basic premise of the proposed Interstellar Mapping and Acceleration Probe (IMAP) is detailed scientific understanding of the Heliosheath (HS) and beyond, a region of space explored in situ by Voyager 1 (V1) since 2004, Voyager 2 (V2) since 2007, and remotely via energetic neutral atoms (ENA) by the Cassini/INCA (Ion and Neutral CAmera) since 2003 and IBEX since 2009. The IMAP instrumentation proposed for this purpose combines and extends the IBEX and INCA ENA energy ranges (0.3- 20 keV and 3-200 keV, for low and high energy, respectively). All three missions-Voyagers, Cassini/INCA, and IBEX- have made discovery-class measurements in the HS, the Voyagers providing in situ ion intensities at E > 30 keV, while INCA images ENA in the range 5 < E < 55 keV, and IBEX 0.3 < E < 6 keV. The partial overlap in energy coverage between Voyager ions and INCA ENA allows for the possibility of observing the intensity and time evolution of ions in the HS, thought to give rise to the ENAs via charge-exchange, and the resultant ENA images in the inner heliosphere and their spatial and/or temporal variability. Unfortunately, no such "ground truth" ion measurements are possible at Voyager in the ENA energy range imaged by IBEX. Some of the key findings from the Voyager and Cassini/INCA measurements are as follows: (1) The HS contains a hot plasma population that carries a substantial part (30-50 %) of the total pressure at E > 5 keV, the rest residing below that range, resulting in a beta (particle/magnetic pressure) always > 1, typically >10. (2) The width of the HS in the direction of V1 is ~ 30 AU, but is thought to be larger (40-70 AU) in the southern ecliptic where V2 currently travels.. (3) The ENA intensities at E > 5 keV exhibit a correlation with the solar cycle (SC) over the period 2003 to 2015, with minimum intensities in the anti-nose direction observed ~ 1.5 yrs after solar minimum followed by a recovery thereafter. (4) The in situ ion measurements at V2 within the HS

  19. Synthesis of 3-((2,4-dichlorophenoxy)methyl)-1,2,4-triazolo(thiadiazoles and thiadiazines) as anti-inflammatory and molluscicidal agents.

    PubMed

    El Shehry, M F; Abu-Hashem, A A; El-Telbani, E M

    2010-05-01

    A series of fused and non fused 1,2,4-triazoles with (2,4-dichlorophenoxy) moiety are prepared utilizing 3-((2,4-dichlorophenoxy)methyl)-4-amino-4H-1,2,4-triazole-5-thiol (3). The latter on reaction with carboxylic acids, ethylchloroformate, ethylcyanoacetate and sodium nitrite gives five membered fused triazole derivatives 4a-d, 5, 6, 7 and 10, respectively. The six membered heterocycles 11, 12 and 14 are prepared by cyclization of compound 3 with phenacyl bromide, chloroacetic acid and alpha-bromoketone respectively. Most of the newly synthesized compounds were screened for their anti-inflammatory and molluscicidal activities. The compounds 4b, 4d, 11 and 14 showed potent anti-inflammatory activities in dose dependent manner while compounds 3, 4b, 8 and 10 exhibited promising molluscicidal activities.

  20. Garage Band or GarageBand[R]? Remixing Musical Futures

    ERIC Educational Resources Information Center

    Vakeva, Lauri

    2010-01-01

    In this paper, I suggest that it is perhaps time to consider the pedagogy of popular music in more extensive terms than conventional rock band practices have to offer. One direction in which this might lead is the expansion of the informal pedagogy based on a "garage band" model to encompass various modes of digital artistry wherever this artistry…

  1. Simultaneous recovery of metals and degradation of organic species: copper and 2,4,5-trichlorophenoxyacetic acid (2,4,5-T).

    PubMed

    Chaudhary, Abdul J; Hassan, Mukhtar-ul; Grimes, Susan M

    2009-06-15

    In mixed wastewater streams, the presence of metal ions can retard the destruction of organic contaminants and the efficiency of recovery of the metal is reduced by the presence of organic species. The reduction in the efficiency of these methods is due to the formation of complexes between the organic species and the metal ions in solution. Results are presented for copper-2,4,5-T system in which both effects occur. A photolytic cell alone can achieve the complete degradation of 2,4,5-T, in the presence of TiO(2) or H(2)O(2), at pH 3.5. The addition of Cu(II) ions, however, retard the degradation of 2,4,5-T and complete mineralisation of 2,4,5-T was not achieved and the system also leaves Cu(II) ions in solution. An electrolytic cell alone can be used to recover copper in pH range 1.5-4.5 but is not capable of achieving complete disappearance of 2,4,5-T by anodic oxidation. A combined photolytic-electrolytic system is capable of achieving simultaneous destruction of 2,4,5-T and recovery of copper from mixed wastewater streams at pH 3.5. The percentage destruction of 2,4,5-T and the recovery of copper can be increased further by using a combined photolytic and an activated carbon concentrator cell system. This system can achieve the simultaneous recovery of copper and the degradation of 2,4,5-T without the use of an additional oxidants or catalysts.

  2. A molecular imprinting-based turn-on Ratiometric fluorescence sensor for highly selective and sensitive detection of 2,4-dichlorophenoxyacetic acid (2,4-D).

    PubMed

    Wang, Xiaoyan; Yu, Jialuo; Wu, Xiaqing; Fu, Junqing; Kang, Qi; Shen, Dazhong; Li, Jinhua; Chen, Lingxin

    2016-07-15

    A novel molecular imprinting-based turn-on ratiometric fluorescence sensor was constructed via a facile sol-gel polymerization for detection of 2,4-dichlorophenoxyacetic acid (2,4-D) on the basis of photoinduced electron transfer (PET) by using nitrobenzoxadiazole (NBD) as detection signal source and quantum dots (QDs) as reference signal source. With the presence and increase of 2,4-D, the amine groups on the surface of QDs@SiO2 could bind with 2,4-D and thereby the NBD fluorescence intensities could be significantly enhanced since the PET process was inhibited, while the QDs maintained constant intensities. Accordingly, the ratio of the dual-emission intensities of green NBD and red QDs could be utilized for turn-on fluorescent detection of 2,4-D, along with continuous color changes from orange-red to green readily observed by the naked eye. The as-prepared fluorescence sensor obtained high sensitivity with a low detection limit of 0.14μM within 5min, and distinguished recognition selectivity for 2,4-D over its analogs. Moreover, the sensor was successfully applied to determine 2,4-D in real water samples, and high recoveries at three spiking levels of 2,4-D ranged from 95.0% to 110.1% with precisions below 4.5%. The simple, rapid and reliable visual sensing strategy would not only provide potential applications for high selective ultratrace analysis of complicated matrices, but also greatly enrich the research connotations of molecularly imprinted sensors.

  3. Development of an X-ray Telescope with a Large Effective Area for the Iron K Line Band

    NASA Astrophysics Data System (ADS)

    Matsumoto, Hironori; Tachibana, Sasagu; Yoshikawa, Shun; Tamura, Keisuke; Mori, Hideyuki; Mitsuishi, Ikuyuki; Tawara, Yuzuru; Kunieda, Hideyo; Yamashita, Kojun

    2015-08-01

    X-ray micro-calorimeters such as the Soft X-ray Spectrometer (SXS) on board ASTRO-H will enable precise spectroscopy of iron K lines even for spatially extended objects. To exploit the full power of the high-energy resolution, X-ray telescopes with a large effective area around 6 keV are essentially important. Conventional Wolter-I X-ray telescopes aimed at X-rays below 10 keV have used the principle of total reflection to collect the X-rays. Enlarging the diameter of this type of telescopes is not effective to obtain the large effective area, since the incident angle of X-rays for the outer part of the telescope exceeds the critical angle, and the X-ray reflectivity of the outer part is significantly low. For example, the critical angle of Ir for an X-ray of 6 keV is 0.748 deg. Thus if we assume a focal length of 6 m for a Wolter-I optics using mirrors covered with Ir as a reflector, the mirrors the radial position of which are larger than 34 cm cannot reflect X-rays above 6 keV effectively. If multi-layer mirrors are applied to the outer part of the telescope, however, the X-ray reflectivity can be enhanced significantly by the principle of Bragg reflection. Our objective is to develop a Wolter-I X-ray telescope with an aperture of 110 cm and a focal length of 6 m, and make all mirrors in the telescope can reflect X-rays around 6 keV effectively by utilizing the multi-layer mirrors. The size of the telescope is determined by a boundary condition that can be launched by the epsilon rocket of ISAS/JAXA. The multi-layer is designed to enhance the reflectivity at 6.4 keV, 6.7 keV, or 6.9 keV. Our simulation suggests that the effective area averaged in the 5.7-7.7 keV band could be 2000 cm2, whichis comparable to the effective area of Athena launched in 2028 by ESA. Furthermore, we showed that the Ir/C multi-layers produced by our DC magnetron sputtering machine has a surface roughness of less than 4 angstrom. This value is smaller than the average surface roughness

  4. A 7.2 keV spherical crystal backlighter system for Sandia's Z Pulsed Power Facility

    NASA Astrophysics Data System (ADS)

    Schollmeier, M.; Knapp, P. F.; Ampleford, D. J.; Loisel, G. P.; Robertson, G.; Shores, J. E.; Smith, I. C.; Speas, C. S.; Porter, J. L.; McBride, R. D.

    2016-10-01

    Many experiments on Sandia's Z facility, a 30 MA, 100 ns rise-time, pulsed-power driver, use a monochromatic Quartz crystal imaging backlighter system at 1.865 keV (Si Heα) or 6.151 keV (Mn Heα) x-ray energy to radiograph an imploding liner (cylindrical tube) or wire array. The x-ray source is generated by the Z-Beamlet Laser (ZBL), which provides up to 4.5 kJ at 527 nm during a 6 ns window. Radiographs of an imploding thick-walled Beryllium liner at a convergence ratio of about 20 [CR =Rin . (0) /Rin . (t) ] were too opaque to identify the inner surface of the liner with high confidence, demonstrating the need for a higher-energy x-ray backlighter between 6 and 10 keV. We present the design, test and first application of a Ge (335) spherical crystal x-ray backlighter system using the 7.242 keV Co Heα resonance line. The system operates at an almost identical Bragg angle as the existing 1.865 and 6.151 keV backlighters, enhancing our capabilities such as two-color, two-frame radiography, without changing detector shielding hardware. SAND No: SAND2016-6724 A. Sandia National Laboratories is a multi-program laboratory managed and operated by Sandia Corp., a wholly owned subsidiary of Lockheed Martin Corp., for the U.S. DoE NNSA under contract DE-AC04-94AL85000.

  5. Crystal structure, spectroscopic and theoretical studies on two Schiff base compounds of 2,6-dichlorobenzylidene-2,4-dichloroaniline and 2,4-dichlorobenzylidene-2,4-dichloroaniline.

    PubMed

    Soltani, Alireza; Ghari, Fereshteh; Khalaji, Aliakbar Dehno; Lemeski, E Tazikeh; Fejfarova, Karla; Dusek, Michal; Shikhi, Masoomeh

    2015-03-15

    The crystal structures of two Schiff base compounds, 2,6-dichlorobenzylidene-2,4-dichloroaniline (1) and 2,4-dichlorobenzylidene-2,4-dichloroaniline (2) have been determined from single-crystal X-ray diffraction and characterized by FT-IR and (1)H NMR spectroscopy. The electronic structures of compounds 1 and 2 in the gas phase were computed by the density functional theory (DFT) method. The obtained theoretical results were supported by the crystallographic data. In addition, theoretical configurations of the title compounds were relaxed and studied in terms of the combined analysis of HOMO-LUMO energy gap, total density of states (DOS), molecular electrostatic potential (MEP), NMR spectra and harmonic vibrational frequencies.

  6. Crystal structure, spectroscopic and theoretical studies on two Schiff base compounds of 2,6-dichlorobenzylidene-2,4-dichloroaniline and 2,4-dichlorobenzylidene-2,4-dichloroaniline

    NASA Astrophysics Data System (ADS)

    Soltani, Alireza; Ghari, Fereshteh; Khalaji, Aliakbar Dehno; Tazikeh Lemeski, E.; Fejfarova, Karla; Dusek, Michal; Shikhi, Masoomeh

    2015-03-01

    The crystal structures of two Schiff base compounds, 2,6-dichlorobenzylidene-2,4-dichloroaniline (1) and 2,4-dichlorobenzylidene-2,4-dichloroaniline (2) have been determined from single-crystal X-ray diffraction and characterized by FT-IR and 1H NMR spectroscopy. The electronic structures of compounds 1 and 2 in the gas phase were computed by the density functional theory (DFT) method. The obtained theoretical results were supported by the crystallographic data. In addition, theoretical configurations of the title compounds were relaxed and studied in terms of the combined analysis of HOMO-LUMO energy gap, total density of states (DOS), molecular electrostatic potential (MEP), NMR spectra and harmonic vibrational frequencies.

  7. Mechanistic and Kinetic Studies on the Homogeneous Gas-Phase Formation of PCTA/DTs from 2,4-Dichlorothiophenol and 2,4,6-Trichlorothiophenol

    PubMed Central

    Xu, Fei; Shi, Xiangli; Li, Yunfeng; Zhang, Qingzhu

    2015-01-01

    Polychlorinated thianthrene/dibenzothiophenes (PCTA/DTs) are sulfur analogues compounds to polychlorinated dibenzo-p-dioxin/dibenzofurans (PCDD/Fs). Chlorothiophenols (CTPs) are key precursors to form PCTA/DTs. 2,4-DCTP has the minimum number of Cl atoms to form 2,4,6,8-tetrachlorinated dibenzothiophenes (2,4,6,8-TeCDT), which is the most important and widely detected of the PCDTs. In this paper, quantum chemical calculations were carried out to investigate the homogeneous gas-phase formation of PCTA/DTs from 2,4-DCTP and 2,4,6-TCTP precursors at the MPWB1K/6-311+G(3df,2p)//MPWB1K/6-31+G(d,p) level. Several energetically feasible pathways were revealed to compare the formation potential of PCTA/DT products. The rate constants of the crucial elementary reactions were evaluated by the canonical variational transition-state (CVT) theory with the small curvature tunneling (SCT) correction over a wide temperature range of 600–1200 K. This study shows that pathways that ended with elimination of Cl step were dominant over pathways ended with elimination of the H step. The water molecule has a negative catalytic effect on the H-shift step and hinders the formation of PCDTs from 2,4-DCTP. This study, together with works already published from our group, clearly illustrates an increased propensity for the dioxin formation from CTPs over the analogous CPs. PMID:26343647

  8. A novel strategy for chromogenic chemosensors highly selective toward cyanide based on its reaction with 4-(2,4-dinitrobenzylideneamino)benzenes or 2,4-dinitrostilbenes

    NASA Astrophysics Data System (ADS)

    Heying, Renata S.; Nandi, Leandro G.; Bortoluzzi, Adailton J.; Machado, Vanderlei G.

    2015-02-01

    N-(2,4-dinitrobenzylidene)-4-methoxyaniline (1), 4-(N,N-dimethylamine)-N-(2,4-dinitrobenzylidene)aniline (2), 2,4-dinitro-4‧-methoxystilbene (3), and 2,4-dinitro-4‧-(dimethylamino)stilbene (4) were synthesized and studied in dimethyl sulfoxide in a novel strategy as anionic chromogenic chemosensors. The color of the solutions of these compounds changed only in the presence of cyanide. The kinetic studies were performed with compounds 1-3 in an excess of cyanide. Higher second-order rate constant values were obtained for the compounds containing a methoxy group in relation to the compounds with a dimethylamino substituent, since the methoxy group donates electronic density to the 2,4-dinitrophenyl electron-accepting group less easily compared with the dimethylamino group. Stilbenes generally have greater structural rigidity than imines, facilitating the action of the substituents through the mesomeric effect. The data obtained indicate that the anion acts as a nucleophile, being responsible for Cdbnd N bond breaking. The Cdbnd C bridge is not broken in the stilbene dyes, but cyanide performs a nucleophilic attack on the 2,4-dinitrophenyl group.

  9. Mechanistic and Kinetic Studies on the Homogeneous Gas-Phase Formation of PCTA/DTs from 2,4-Dichlorothiophenol and 2,4,6-Trichlorothiophenol.

    PubMed

    Xu, Fei; Shi, Xiangli; Li, Yunfeng; Zhang, Qingzhu

    2015-08-28

    Polychlorinated thianthrene/dibenzothiophenes (PCTA/DTs) are sulfur analogues compounds to polychlorinated dibenzo-p-dioxin/dibenzofurans (PCDD/Fs). Chlorothiophenols (CTPs) are key precursors to form PCTA/DTs. 2,4-DCTP has the minimum number of Cl atoms to form 2,4,6,8-tetrachlorinated dibenzothiophenes (2,4,6,8-TeCDT), which is the most important and widely detected of the PCDTs. In this paper, quantum chemical calculations were carried out to investigate the homogeneous gas-phase formation of PCTA/DTs from 2,4-DCTP and 2,4,6-TCTP precursors at the MPWB1K/6-311+G(3df,2p)//MPWB1K/6-31+G(d,p) level. Several energetically feasible pathways were revealed to compare the formation potential of PCTA/DT products. The rate constants of the crucial elementary reactions were evaluated by the canonical variational transition-state (CVT) theory with the small curvature tunneling (SCT) correction over a wide temperature range of 600-1200 K. This study shows that pathways that ended with elimination of Cl step were dominant over pathways ended with elimination of the H step. The water molecule has a negative catalytic effect on the H-shift step and hinders the formation of PCDTs from 2,4-DCTP. This study, together with works already published from our group, clearly illustrates an increased propensity for the dioxin formation from CTPs over the analogous CPs.

  10. Band of Rubble

    NASA Technical Reports Server (NTRS)

    2005-01-01

    This artist's animation illustrates a massive asteroid belt in orbit around a star the same age and size as our Sun. Evidence for this possible belt was discovered by NASA's Spitzer Space Telescope when it spotted warm dust around the star, presumably from asteroids smashing together.

    The view starts from outside the belt, where planets like the one shown here might possibly reside, then moves into to the dusty belt itself. A collision between two asteroids is depicted near the end of the movie. Collisions like this replenish the dust in the asteroid belt, making it detectable to Spitzer.

    The alien belt circles a faint, nearby star called HD 69830 located 41 light-years away in the constellation Puppis. Compared to our own solar system's asteroid belt, this one is larger and closer to its star - it is 25 times as massive, and lies just inside an orbit equivalent to that of Venus. Our asteroid belt circles between the orbits of Mars and Jupiter.

    Because Jupiter acts as an outer wall to our asteroid belt, shepherding its debris into a series of bands, it is possible that an unseen planet is likewise marshalling this belt's rubble. Previous observations using the radial velocity technique did not locate any large gas giant planets, indicating that any planets present in this system would have to be the size of Saturn or smaller.

    Asteroids are chunks of rock from 'failed' planets, which never managed to coalesce into full-sized planets. Asteroid belts can be thought of as construction sites that accompany the building of rocky planets.

  11. Metabolism of 2,4-dichlorophenol in tobacco engineered with bacterial degradative genes

    SciTech Connect

    Perkins, E.J.; Sekine, M.; Gordon, M.P. )

    1990-05-01

    The potential use of plants in toxic waste remediation has been overlooked. While chlorophenols are relatively slowly metabolized in Nicotiana tabacum var. Xanthi leaf extracts, chlorocatechols are rapidly metabolized, presumably by polyphenol oxidases. Our initial focus has been the fate of 2,4-dichlorophenol (2,4DCP) in var. Xanthi plants which express a bacterial 2,4DCP hydroxylase, which converts 2,4DCP to 3,5-dichlorocatechol. The roots of wild type and 2,4DCP hydroxylase transgenic plants growing in hydroponics were exposed to {sup 14}C-2,4DCP. Approximately 95% of {sup 14}C-2,4DCP metabolites remained in the roots when exposed to 2,4DCP. Upon extraction of root tissue, three major metabolites were found in untransformed plants and four major metabolites in transformed plants. Upon digestion with beta-D-glucosidase, these metabolites disappeared concomitant with the appearance of free 2,4DCP in wild type plants and 2,4DCP and 3,5-dichlorocatechol in transgenic plants. It is apparent that the chlorophenols are not readily available substrates for polyphenol oxidases in whole plants.

  12. Report from the banding lab

    USGS Publications Warehouse

    Tautin, J.

    1995-01-01

    Mr. Tautin reported on the seemingly everchanging structure of biological science units within the Interior Department. Current Congressional proposals would either change the name of the Bird Banding Lab's parent agency or make it part of the Geological Survey. The current Congress has not looked favorably on science budgets within the Interior Department, and the Banding Lab's budget is being squeezed ever tighter.

  13. Curriculum Guide for Advanced Band.

    ERIC Educational Resources Information Center

    Bazar, W. Gayre

    The advanced band of the Vermilion Parish School System is a selective organization comprised of school instrumental students who have successfully completed all phases of the beginning and intermediate band programs. It functions largely as a performing group for varied school and community activities. This guide describes the advanced band…

  14. The Moral Ends of Band

    ERIC Educational Resources Information Center

    Allsup, Randall Everett

    2012-01-01

    This article provides a theoretical framework through which to reimagine and revitalize contemporary music education practices, using the large ensemble paradigm called "band" as the primary unit of analysis. Literature suggests that band places too much emphasis on teacher control and external measures of validation. Critics propose replacing…

  15. Excitation energies and spins of a superdeformed band in {sup 194}{ital H}{ital g} from one-step discrete decays to the yrast line

    SciTech Connect

    Khoo, T.L.; Carpenter, M.P.; Lauritsen, T.; Ackermann, D.; Ahmad, I.; Blumenthal, D.J.; Fischer, S.M.; Janssens, R.V.; Nisius, D.; Moore, E.F.; Lopez-Martens, A.; Do Kruecken, R.; Asztalos, S.J.; Becker, J.A.; Bernstein, L.; Clark, R.M.; Deleplanque, M.A.; Diamond, R.M.; Fallon, P.; Farris, L.P.; Hannachi, F.; Henry, E.A.; Korichi, A.; Lee, I.Y.; Macchiavelli, A.O.; Stephens, F.S. ||||||

    1996-03-01

    Discrete {gamma} rays directly connecting states of a superdeformed (SD) band in {sup 194}Hg to the yrast states have been discovered. Thus, the excitation energies and spins of all members of the lowest SD band are established for the first time, together with their likely parity. The SD band decays from its 10{sup +} and 12{sup +} states, which lie 4204.8 and 4407.4 keV above the normal-deformed yrast states of the same spins. {copyright} {ital 1996 The American Physical Society.}

  16. 1-40-keV fixed-exit monochromator for a wafer mapping TXRF facility

    NASA Astrophysics Data System (ADS)

    Comin, Fabio; Apostolo, G.; Freund, Andreas K.; Mangiagalli, P.; Navizet, M.; Troxel, C. L.

    1998-12-01

    An industrial facility for the mapping of trace impurities on the surface of 300 mm Silicon wafers will be commissioned at the end of 1998. The elements to be detected range from Na to Hg with a target routine detection limit of 108 atoms/cm2. The monochromator of the facility plays a central role and fulfills the following requirements: ease of operations and fast tuning (one single motor); extended energy range (1 - 40 KeV covered by a fixed exit Si(111) channel cut and multilayer pair); smooth and reliable running (water cooling even in the powerful ESRF undulator beams at high energies). The mechanical structure of the monochromator is based on well-established concepts: an external goniometer transfers the main rotation to the in-vacuum plateau via a hollow differentially pumped feed-through. The optical arrangement shows some novelties: the plateau can be cooled either by water or liquid nitrogen and it holds the convex- concave machined Si(111) channel-cut for fixed exit performances. The shape of the machined surfaces of the crystal helps also on to spread the power density of the beam on the silicon surface. A set of two identical multilayers are also mounted on the plateau and the transition from the Si(111) crystal to the multilayer operation is performed by rotating the wafer main axis by about 180 degrees. The whole facility is centered around the three main components: the monochromator, the wafer handling robots and the two linear arrays of solid state fluorescence detectors.

  17. Stochastic spatial energy deposition profiles for MeV protons and keV electrons

    NASA Astrophysics Data System (ADS)

    Udalagama, C.; Bettiol, A. A.; Watt, F.

    2009-12-01

    With the rapid advances being made in novel high-energy ion-beam techniques such as proton beam writing, single-ion-event effects, ion-beam-radiation therapy, ion-induced fluorescence imaging, proton/ion microscopy, and ion-induced electron imaging, it is becoming increasingly important to understand the spatial energy-deposition profiles of energetic ions as they penetrate matter. In this work we present the results of comprehensive yet straightforward event-by-event Monte Carlo calculations that simulate ion/electron propagation and secondary electron ( δ ray) generation to yield spatial energy-deposition data. These calculations combine SRIM/TRIM features, EEDL97 data and volume-plasmon-localization models with a modified version of one of the newer δ ray generation models, namely, the Hansen-Kocbach-Stolterfoht. The development of the computer code DEEP (deposition of energy due to electrons and protons) offers a unique means of studying the energy-deposition/redistribution problem while still retaining the important stochastic nature inherent in these processes which cannot be achieved with analytical modeling. As an example of an application of DEEP we present results that compare the energy-deposition profiles of primary MeV protons and primary keV electrons in polymethymethacrylate. Such data are important when comparing proximity effects in the direct write lithography processes of proton-beam writing and electron-beam writing. Our calculations demonstrate that protons are able to maintain highly compact spatial energy-deposition profiles compared with electrons.

  18. Band anticrossing in dilute nitrides

    SciTech Connect

    Shan, W.; Yu, K.M.; Walukiewicz, W.; Wu, J.; Ager III, J.W.; Haller, E.E.

    2003-12-23

    Alloying III-V compounds with small amounts of nitrogen leads to dramatic reduction of the fundamental band-gap energy in the resulting dilute nitride alloys. The effect originates from an anti-crossing interaction between the extended conduction-band states and localized N states. The interaction splits the conduction band into two nonparabolic subbands. The downward shift of the lower conduction subband edge is responsible for the N-induced reduction of the fundamental band-gap energy. The changes in the conduction band structure result in significant increase in electron effective mass and decrease in the electron mobility, and lead to a large enhance of the maximum doping level in GaInNAs doped with group VI donors. In addition, a striking asymmetry in the electrical activation of group IV and group VI donors can be attributed to mutual passivation process through formation of the nearest neighbor group-IV donor nitrogen pairs.

  19. Well-defined linear Au n (n = 2-4) chains encapsulated in SWCNTs: a DFT study.

    PubMed

    Liu, Yiliang; Hua, Yawen; Yan, Anying; Wu, Shuang; Kong, Fanjie

    2017-01-01

    One-dimensional (1D) gold nanostructures have been extensively studied due to their potential applications in nanoelectronic devices. Using first-principles calculations, composites consisting of a well-defined linear Au n (n = 2-4) chain encapsulated in a (9,0) single-walled carbon nanotube (SWCNT) were studied. The translational energy barrier of a single Au atom in a (9,0) SWCNT was found to be 0.03 eV. This low barrier guaranteed the formation of Au n @ (9,0) SWCNT (n = 1-4) composites. Bond lengths, differential charge densities, and electronic band structures of the composites were studied. The average Au-Au bond lengths in the composites were found to be almost the same as those in the corresponding free-standing linear Au n . The average bond length increased as the number of Au atoms increased. Charge transfer in all of these composites was slight, although a few valence electrons were transferred from the (9,0) SWCNT and the Au chains to intercalations. The conductivities of the encapsulated linear Au n (n = 2-4) chains were enhanced to some extent by encapsulating them in the SWCNT.

  20. Synthesis, molecular structure, spectroscopic properties and stability of (Z)-N-methyl-C-2,4,6-trimethylphenylnitrone

    NASA Astrophysics Data System (ADS)

    Lasri, Jamal; Ismail, Ali I.; Haukka, Matti; Soliman, Saied M.

    2015-02-01

    New N-methyl-C-2,4,6-trimethylphenylnitrone 1 has been synthesized starting from N-methylhydroxylamine and mesitaldehyde. The product was fully characterized using different spectroscopic techniques; FTIR, NMR, UV-Vis, high resolution mass spectrometry and X-ray diffraction. The relative stability and percent of population of its two possible isomers (E and Z) were calculated using the B3LYP/6-311++G(d,p) method in gas phase and in solution. In agreement with the X-ray results, it was found that Z-isomer is the most stable one in both gas phase and solution. The molecular geometry, vibrational frequencies, gauge-including atomic orbital (GIAO), and chemical shift values were also calculated using the same level of theory. The TD-DFT results of the studied nitrone predicted a π-π∗ transition band at 285.1 nm (fosc = 0.3543) in the gas phase. The rest of the spectral bands undergo either hyperchromic or hypsochromic shifts in the presence of solvent. Polarizability and HOMO-LUMO gap values were used to predict the nonlinear optical properties (NLO) of the studied compound. NBO analysis has been used to determine the most accurate Lewis structure of the studied molecule.