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Sample records for 206pb 204pb ratios

  1. Characterization of the ground X{sub 1} state of {sup 204}Pb{sup 19}F, {sup 206}Pb{sup 19}F, {sup 207}Pb{sup 19}F, and {sup 208}Pb{sup 19}F

    SciTech Connect

    Mawhorter, Richard J.; Murphy, Benjamin S.; Baum, Alexander L.; Sears, Trevor J.; Yang, T.; Rupasinghe, P. M; McRaven, C. P.; Shafer-Ray, N. E.; Alphei, Lukas D.; Grabow, Jens-Uwe

    2011-08-15

    Pure rotational spectra of the ground electronic-vibrational X{sub 1} state of {sup 204}Pb{sup 19}F, {sup 206}Pb{sup 19}F, {sup 207}Pb{sup 19}F, and {sup 208}Pb{sup 19}F are measured with a resonator pulsed supersonic jet Fourier-transform microwave spectrometer. Also reported is a new measurement of the Stark effect on the optical spectra of A(leftarrow)X{sub 1} transitions. These spectra are combined with published high-resolution infrared spectra of X{sub 2}{r_reversible}X{sub 1} transitions in order to create a complete picture of the ground state of lead monofluoride. For the microwave data, molecules are prepared by laser ablation of lead target rods and stabilized in a supersonic jet of neon mixed with sulfur hexafluoride. For the optical Stark spectra, a continuous source of molecules is created in a nozzle heated to 1000 deg. C. The microwave spectra confirm, improve, and extend previously reported constants that describe the rotational, spin-orbit, and hyperfine interactions of the ground electronic state of the PbF molecule. A discrepancy concerning the sign of the hyperfine constant describing the {sup 207}Pb nucleus is discussed. Magnetic-field-dependent microwave spectra are used to characterize the Zeeman interaction in terms of two g factors of the body-fixed electronic wave function. The optical Stark spectra are used to characterize the electric dipole moment of the X{sub 1} and A states.

  2. European isotopic signatures for lead in atmospheric aerosols: a source apportionment based upon 206Pb/207Pb ratios.

    PubMed

    Flament, Pascal; Bertho, Marie-Laure; Deboudt, Karine; Véron, Alain; Puskaric, Emile

    2002-09-16

    To investigate the capability of the lead isotope signature technique to support a source apportionment study at a Continental scale, atmospheric particulate matter was collected at Cap Gris-Nez (Eastern Channel, northern France), over one year (1995-1996). Four days retrospective trajectories of air masses were available during each sampling experiment. Twenty-eight samples, for which the origin of aerosols was unambiguously determined, were selected for isotopic measurements. Considering the Enrichment Factors, EF(Crust) of lead and its size distribution, we show that lead is mostly from anthropogenic origin and mainly associated with [0.4 < diameter < 0.9 microm] particles. The extent to which various Continental sources influence the lead abundance in aerosols is exhibited by considering both the lead concentration and the origin of air masses. Lead concentration is higher by a factor of approximately seven, when air masses are derived from Continental Europe, by comparison with marine air masses. Taking into account these concentrations and the vertical movements of air masses, we compare the different isotopic compositions using a statistical non-parametric test (Kolmogorov-Smirnov). We produce evidence that, for most of the cases, air masses originating from Continental Europe exhibit a more radiogenic composition (1.134 < 206Pb/207Pb < 1.172) than air masses coming from the United Kingdom (1.106 < 206Pb/207Pb < 1.124). Generally, lead isotopic compositions in aerosols are clearly distinct from the gasoline signatures in European countries, strongly suggesting that automotive lead is no longer the major component of this metal in the air. Gasoline and industrial isotopic signatures could explain the origin of lead in our aerosol samples. A source apportionment based upon 206Pb/207Pb ratios, suggests that the difference between British (206Pb/207Pb = 1.122 +/- 0.038) and Continental (206Pb/207Pb = 1.155 +/- 0.022) signatures may be largely explained by

  3. Lead isotope ratios in bone ash of blesbok (Damaliscus pygargus phillipsi): a means of screening for the accumulation of contaminants from uraniferous rocks.

    PubMed

    Nöthling, Johan O; Du Toit, Johannes S; Myburgh, Jan G

    2014-09-19

    This study was done to determine whether blesbok (Damaliscus pygargus phillipsi) from the Krugersdorp Game Reserve (KGR) in Gauteng Province, South Africa have higher concentrations of (238)U and higher (206)Pb/(204)Pb and (207)Pb/(204)Pb ratios in their bone ash than blesbok from a nearby control reserve that is not exposed to mine water and has no outcrops of uraniferous rocks. Eight blesbok females from the KGR and seven from the control site, all killed with a brain shot, were used. A Thermo X-series 2 quadrupole ICPMS was used to measure the concentrations of (238)U and lead and a Nu Instruments NuPlasma HR MC-ICP-MS to measure the lead isotope ratios in the tibial ash from each animal. KGR blesbok had higher mean concentrations of (238)U (P = 0.02) and ratios of (206)Pb/(204)Pb and (207)Pb/(204)Pb (P < 0.00001) than the control blesbok. The probability of rejecting the false null hypothesis of no difference in the (206)Pb/(204)Pb or (207)Pb/(204)Pb ratios between KGR and control reserve animals (the power of the test) was 0.999. The blesbok from the KGR accumulated contaminants from an uraniferous environment. The (206)Pb/(204)Pb and (207)Pb/(204)Pb ratios in tibial ash proved effective in confirming accumulation of contaminants from uraniferous rocks.

  4. The changing nature of the 206Pb/207Pb isotopic ratio of lead in rainwater, atmospheric particulates, pine needles and leaded petrol in Scotland, 1982-1998.

    PubMed

    Farmer, J G; Eades, L J; Graham, M C; Bacon, J R

    2000-02-01

    The inductively coupled plasma-mass spectrometry (ICP-MS)-determined 206Pb/207Pb ratio of 145 samples of rainwater collected at 25 locations around Scotland during December 1997 and January 1998 and at three longterm monitoring stations in the northeast, central belt and southeast of the country from November 1997 to December 1998 averaged 1.144+/-0.017 (1 s). This represents a significant increase from the mean value of 1.120+/-0.016 recorded for the long-term sites in 1989 1991, only partly attributable to a concomitant increase in the 206Pb/207Pb ratio of leaded petrol from 1.075+/-0.013 to 1.088+/-0.007. The rainwater 206Pb/207Pb data for the late 1990s also contrast markedly with the lower 206Pb/207Pb ratios found for pine needle and atmospheric particulate samples from Scotland (e.g. Glasgow: 1.085+/-0.012 in 1985-1986, 1.099+/-0.007 in 1991-1992), England and Western Europe in this study for the period 1982-1992 when emissions of lead to the atmosphere from petrol-engined vehicles in the UK were approximately 2-9 times higher. The observed change in the lead isotopic signature of rainwater predominantly reflects the impact of measures, such as the introduction and growing uptake of unleaded petrol, to reduce car exhaust emissions of lead to the atmosphere in the UK. Based on the rainwater data, source apportionment calculations suggest a general decline in the contribution of leaded petrol to atmospheric lead in Scotland from 53-61% in 1989-1991 to 32-45% in 1997-1998, with a corresponding decline in the urban environment from 84-86% to 48-58%.

  5. Tree rings as Pb pollution archives? A comparison of 206Pb/207Pb isotope ratios in pine and other environmental media.

    PubMed

    Bindler, Richard; Renberg, Ingemar; Klaminder, Jonatan; Emteryd, Ove

    2004-02-05

    Tree rings, if validated as an environmental archive for pollution, would provide a convenient, geographically widespread archive for studying the temporal and spatial distribution of atmospheric pollutants. We collected tree-ring records from Scots pine (Pinus sylvestris L.), ranging in age from 100 to 300 years and from one spruce (Picea abies), from sites in southern and northern Sweden and analyzed their stable lead isotopic composition (206Pb/207Pb). These results are compared to the Pb isotopic composition in soil profiles from each of the sites and temporal changes in the 206Pb/207Pb ratio in peat and lake sediment deposits in Sweden. The mineral soils at each site are characterized by high 206Pb/207Pb ratios (> 1.35), while the ratios in the mor layer are low (1.14-1.16) and characterized by atmospheric lead pollution. The 206Pb/207Pb ratios of the tree rings, typically approximately 1.18-1.20, indicate a significant (10-30%) contribution of Pb derived from the underlying mineral soil. While peat and lake sediment records show that the 206Pb/207Pb ratio of atmospheric deposition has varied over time, with a pronounced trough between approximately 1930 and 1990, the tree rings show no similar trend. Further comparison of published Pb isotope data from other tree-ring records with time series from peat bogs and herbarium samples also shows poor agreement, and indicates that tree rings always contain a mixture of pollution Pb and Pb from the underlying mineral soil. The majority of Pb in the wood is derived from atmospheric pollution either directly, through aerial interception, or indirectly, through uptake from the large pool of accumulated pollution Pb in the soil. Since the Pb isotope ratios of the wood indicate that some natural Pb is taken up into the tree, then it must also be concluded that some fraction of the pollution Pb in the wood is likewise taken up from the forest soil. Based on the Pb isotope analyses, we can only conclude that dendrochemical

  6. Lead fluxes and 206Pb/207Pb isotope ratios in rime and snow collected at remote mountain-top locations (Czech Republic, Central Europe): Patterns and sources

    NASA Astrophysics Data System (ADS)

    Cimova, Nikoleta; Novak, Martin; Chrastny, Vladislav; Curik, Jan; Veselovsky, Frantisek; Blaha, Vladimir; Prechova, Eva; Pasava, Jan; Houskova, Marie; Bohdalkova, Leona; Stepanova, Marketa; Mikova, Jitka; Krachler, Michael; Komarek, Arnost

    2016-10-01

    During three winter seasons (2009-2011), Pb concentrations were measured in precipitation at 10 high-elevation sites in the Czech Republic, close to the borders with Austria, Germany, Poland, and Slovakia. Soluble and insoluble Pb forms were quantified in snow (vertical deposition), and rime (horizontal deposition). The objective was to compare Pb input fluxes into ecosystems via vertical and horizontal deposition, and to identify the residual Pb pollution sources in an era of rapidly decreasing industrial pollution. Lead soluble in diluted HNO3 made up 96% of total Pb deposition, with the remaining 4% Pb bound mainly in silicates. Three times higher concentrations of soluble Pb in rime than in snow, and 2.5 times higher concentrations of insoluble Pb in rime than in snow were associated with slightly different Pb isotope ratios. On average, the 206Pb/207Pb ratios in rime were higher than those in snow. Higher mean 206Pb/207Pb ratios of insoluble Pb (1.175) than in soluble Pb (1.165) may indicate an increasing role of geogenic Pb in recent atmospheric deposition. A distinct reversal to more radiogenic 206Pb/207Pb ratios in snow and rime in 2010, compared to literature data from rain-fed Sphagnum peatlands (1800-2000 A.D.), documented a recent decrease in anthropogenic Pb in the atmosphere of Central Europe. Since the early 1980s, Pb concentrations in snow decreased 18 times in the rural south of the Czech Republic, but only twice in the industrial north of the Czech Republic. Isotope signatures indicated that Pb in today's atmospheric deposition is mainly derived from Mesozoic ores mined/processed in Poland and coal combustion in the Czech Republic and Poland.

  7. Tracking the origin of the Asian Dust based on its Pb isotope ratios at background ambient air site in Republic of Korea

    NASA Astrophysics Data System (ADS)

    Choi, J.; Yoo, E.; Kim, J.; Park, J.; Nam, Y.; Hwang, J.; Lee, S.; Lee, W.; Han, J.

    2012-12-01

    In order to track the origin of the Asian dust, its Pb isotope ratios had been measured at the national background air monitoring station located in Padori, Chungcheongnam-do, for about one month during March in 2011. High volume air sampler (Shibata Co.) with a quartz fiber filter was used to collect about 1,000 m3 of TSP at the flux of 700 LPM at background ambient air in Republic of Korea. The ratios of five group such as 206/204Pb, 207/204Pb, 208/204Pb, 207/206Pb and 208/206Pb, NIST-SRM 981 were measured by using MC-ICP/MS. The results showed that the Pb isotope ratios during the Asian dust season were quite different from those during the non-dust season. The Pb isotope ratios during Asian dust (A-8) turned out to be 17.98957(206/204Pb), 15.57343(207/204Pb), 37.86195(208/204Pb), 2.10478(208/206Pb) and 0.86569(207/206Pb). Their value differences compared with the non-dust period groups (A-9) were -0.38645, -0.05615, -0.31868, 0.02704 and 0.01515, respectively. This indicates that the ratios of the 204Pb groups were lower during the dust season while those of the 206Pb groups were higher. Besides the difference in the Pb isotope ratios, the backward and forward trajectory was also monitored around the sampling site to compare the current movement of air mass between the dust (A8) and non-dust (A9). The monitoring found that dust shows a typical trajectory during the dust period : it starts from Gobi Desert in Inner Mongolia 72 hours before, traveling along with the strong uplift from the back end of low pressure, passing through the Shantung Peninsula to the west coast of Korea. In conclusion, the analysis of Pb isotope compositions in TSP and the trajectory of air mass helped identify the origin of Asian dust.

  8. The identification of lead ammunition as a source of lead exposure in First Nations: the use of lead isotope ratios.

    PubMed

    Tsuji, Leonard J S; Wainman, Bruce C; Martin, Ian D; Sutherland, Celine; Weber, Jean-Philippe; Dumas, Pierre; Nieboer, Evert

    2008-04-15

    The use of lead shotshell to hunt water birds has been associated with lead-contamination in game meat. However, evidence illustrating that lead shotshell is a source of lead exposure in subsistence hunting groups cannot be deemed definitive. This study seeks to determine whether lead shotshell constitutes a source of lead exposure using lead isotope ratios. We examined stable lead isotope ratios for lichens, lead shotshell and bullets, and blood from residents of Fort Albany and Kashechewan First Nations, and the City of Hamilton, Ontario, Canada. Data were analyzed using ANOVA and regression analyses. ANOVA of isotope ratios for blood revealed significant differences with respect to location, but not sex. Hamilton differed from both Kashechewan and Fort Albany; however, the First Nations did not differ from each other. ANOVA of the isotope ratios for lead ammunition and lichens revealed no significant differences between lichen groups (north and south) and for the lead ammunition sources (pellets and bullets). A plot of (206)Pb/(204)Pb and (206)Pb/(207)Pb values illustrated that lichens and lead ammunition were distinct groupings and only the 95% confidence ellipse of the First Nations group overlapped that of lead ammunition. In addition, partial correlations between blood-lead levels (adjusted for age) and isotope ratios revealed significant (p<0.05) positive correlations for (206)Pb/(204)Pb and (206)Pb/(207)Pb, and a significant negative correlation for (208)Pb/(206)Pb, as predicted if leaded ammunition were the source of lead exposure. In conclusion, lead ammunition was identified as a source of lead exposure for First Nations people; however, the isotope ratios for lead shotshell pellets and bullets were indistinguishable. Thus, lead-contaminated meat from game harvested with lead bullets may also be contributing to the lead body burden.

  9. Time differences in the formation of meteorites as determined from the ratio of lead-207 to lead-206

    USGS Publications Warehouse

    Tatsumoto, M.; Knight, R.J.; Allegre, C.J.

    1973-01-01

    Measurements of the lead isotopic composition and the uranium, thorium, and lead concentrations in meteorites were made in order to obtain more precise radiometric ages of these members of the solar system. The newly determined value of the lead isotopic composition of Canyon Diablo troilite is as follows: 206Pb/204Pb = 9.307, 207Pb/204Pb = 10.294, and 208Pb/204Pb = 29.476. The leads of Angra dos Reis, Sioux County, and Nuevo Laredo achondrites are very radiogenic, the 206Pb/204Pb values are about 200, and the uranium-thorium-lead systems are nearly concordant. The ages of the meteorites as calculated from a single-stage 207Pb/206Pb isochron based on the newly determined primordial lead value and the newly reported 235U and 238U decay constants, are 4.528 ?? 10 9 years for Sioux County and Nuevo Laredo and 4.555 ?? 10 9 years for Angra dos Reis. When calculated with the uranium decay constants used by Patterson, these ages are 4.593 ?? 109 years and 4.620 ?? 109 years, respectively, and are therefore 40 to 70 ?? 106 years older than the 4.55 ?? 109 years age Patterson reported. The age difference of 27 ?? 106 years between Angra dos Reis and the other two meteorites is compatible with the difference between the initial 87Sr/86Sr ratio of Angra dos Reis and that of seven basaltic achondrites observed by Papanastassiou and Wasserburg. The time difference is also comparable to that determined by 129I-129Xe chronology. The ages of ordinary chondrites (H5 and L6) range from 4.52 to 4.57 ?? 109 years, and, here too, time differences in the formation of the parent bodies or later metamorphic events are indicated. Carbonaceous chondrites (C2 and C3) appear to contain younger lead components.

  10. 206Pb-230Th-234U-238U and 207Pb-235U geochronology of Quaternary opal, Yucca Mountain, Nevada

    USGS Publications Warehouse

    Neymark, Leonid A.; Amelin, Yuri V.; Paces, James B.

    2000-01-01

    U–Th–Pb isotopic systems have been studied in submillimeter-thick outermost layers of Quaternary opal occurring in calcite–silica fracture and cavity coatings within Tertiary tuffs at Yucca Mountain, Nevada, USA. These coatings preserve a record of paleohydrologic conditions at this site, which is being evaluated as a potential high-level nuclear waste repository. The opal precipitated from groundwater is variably enriched in 234U (measured 234U/238U activity ratio 1.124–6.179) and has high U (30–313 ppm), low Th (0.008–3.7 ppm), and low common Pb concentrations (measured 206Pb/204Pb up to 11,370). It has been demonstrated that the laboratory acid treatment used in this study to clean sample surfaces and to remove adherent calcite, did not disturb U–Th–Pb isotopic systems in opal. The opal ages calculated from 206Pb∗/238U and 207Pb∗/235U ratios display strong reverse discordance because of excess radiogenic 206Pb∗ derived from the elevated initial 234U. The data are best interpreted using projections of a new four-dimensional concordia diagram defined by 206Pb∗/238U, 207Pb∗/235U, 234U/238Uactivity, and 230Th/238Uactivity. Ages and initial 234U/238U activity ratios have been calculated using different projections of this diagram and tested for concordance. The data are discordant, that is observed 207Pb∗/235U ages of 170 ± 32 (2σ) to 1772 ± 40 ka are systematically older than 230Th/U ages of 34.1 ± 0.6 to 452 ± 32 ka. The age discordance is not a result of migration of uranium and its decay products under the open system conditions, but a consequence of noninstantaneous growth of opal. Combined U–Pb and 230Th/U ages support the model of slow mineral deposition at the rates of millimeters per million years resulting in layering on a scale too fine for mechanical sampling. In this case, U–Pb ages provide more accurate estimates of the average age for mixed multiage samples than 230Th/U ages, because ages based on shorter

  11. The isotope systematics of a juvenile intraplate volcano: Pb, Nd, and Sr isotope ratios of basalts from Loihi Seamount, Hawaii

    USGS Publications Warehouse

    Staudigel, H.; Zindler, A.; Hart, S.R.; Leslie, T.; Chen, C.-Y.; Clague, D.

    1984-01-01

    Sr, Nd, and Pb isotope ratios for a representative suite of 15 basanites, alkali basalts, transitional basalts and tholeiites from Loihi Seamount, Hawaii, display unusually large variations for a single volcano, but lie within known ranges for Hawaiian basalts. Nd isotope ratios in alkali basalts show the largest relative variation (0.51291-0.51305), and include the nearly constant tholeiite value ( ??? 0.51297). Pb isotope ratios show similarly large ranges for tholeiites and alkali basalts and continue Tatsumoto's [31] "Loa" trend towards higher 206Pb 204Pb ratios, resulting in a substantial overlap with the "Kea" trend. 206Pb 204Pb ratios for Loihi and other volcanoes along the Loa and Kea trends [31] are observed to correlate with the age of the underlying lithosphere suggesting lithosphere involvement in the formation of Hawaiian tholeiites. Loihi lavas display no correlation of Nd, Sr, or Pb isotope ratios with major element compositions or eruptive age, in contrast with observations of some other Hawaiian volcanoes [38]. Isotope data for Loihi, as well as average values for Hawaiian volcanoes, are not adequately explained by previously proposed two-end-member models; new models for the origin and the development of Hawaiian volcanoes must include mixing of at least three geochemically distinct source regions and allow for the involvement of heterogeneous oceanic lithosphere. ?? 1984.

  12. Fast and precise method for Pb isotope ratio determination in complex matrices using GC-MC-ICPMS: application to crude oil, kerogen, and asphaltene samples.

    PubMed

    Sanabria-Ortega, Georgia; Pécheyran, Christophe; Bérail, Sylvain; Donard, Olivier F X

    2012-09-18

    A new method to determine Pb isotope ratio without ion-exchange-matrix separation is proposed. After acid digestion, Pb was ethylated to Et(4)Pb, separated from the digested solution (black shale, asphaltene, crude oil and kerogen) by extraction in isooctane, and then injected into a gas chromatograph coupled to a multicollector inductively coupled plasma mass spectrometer. Seven isotopes ((202)Hg, (203)Tl, (204)Pb, (205)Tl, (206)Pb, (207)Pb, (208)Pb) were monitored simultaneously with peak duration of 23 s. GC elution was operated under wet plasma conditions where a thallium standard solution was introduced to the mass spectrometer for mass bias correction. The total time of the procedure (sample preparation and analysis, after acid digestion) was reduced by a factor of 15 compared to conventional-continuous sample introduction. Data treatment was carried out using the linear regression slope method. Mass bias was corrected using the double correction method (first thallium normalization followed by classical bracketing). For the (208/206)Pb and (207/206)Pb ratios, precision (2RSD(EXT), n = 21) was 49 and 69 ppm, and the bias between experimental results and reference values was better than 0.0033 and 0.0007 ‰, when injecting 1.2 ng of ethylated Pb SRM NIST 981 solution. Results obtained by this method were validated by comparison with those obtained via conventional-continuous sample introduction. The applicability of this approach was demonstrated with the analysis of black shale, asphaltene, crude oil and kerogen samples.

  13. Measurement of internal pairs from {sup 206}Pb

    SciTech Connect

    Ahmad, I.; Back, B.B.; Betts, R.R.

    1995-08-01

    The failure to observe sharp sum-energy lines in measurements of {sup 238}U + {sup 181}Ta and {sup 238}U + {sup 232}Th raises the issue of the correct functioning of APEX under in-beam conditions. Extensive measurements with electron and pair emitting sources were used to demonstrate the resolution and acceptance of APEX, but the possibility remains that some unforeseen background or other effects might compromise the ability to see peaks in-beam. In order to test the functioning of APEX under the most stringent conditions, we also performed a measurement of internal pairs produced in the decay of the 2.648-MeV 3{sup -} state in {sup 206}Pb to the 2{sup +} state at 0.803 MeV. The 3{sup -} state was excited in the {sup 206}Pb + {sup 206}Pb reaction at 5.9 MeV/u with a cross section of roughly 40 mb, resulting in an expected pair cross section of approximately 16 {mu}b. It should be emphasized that this measurement represents a much stricter test of the functioning of the apparatus than the observation of sum-energy lines would represent, as the internal pair measurement requires a Doppler shift correction before the transition can be seen. These data were analyzed and clearly show the expected peak. A Doppler-corrected sum-energy spectrum showing the expected IPC line at 823 keV. At present we are evaluating the acceptance of APEX for events of this type but it is clear that the observed yield is close to expectations.

  14. Stable lead isotopic ratios trace thermohaline circulation in the subarctic North Atlantic

    NASA Astrophysics Data System (ADS)

    Véron, A. J.; Church, T. M.; Rivera-Duarte, I.; Flegal, A. R.

    Vertical profiles of lead concentrations in the subarctic North Atlantic attest to the predominance of anthropogenic lead inputs to those waters, while variations in their lead isotopic ratios ( 204Pb : 206Pb : 207Pb : 208Pb) show the multiplicity of those industrial lead inputs. Spatial gradients in the isotopic ratios are consistent with the thermohaline circulation of different water masses, which seemingly have relatively discrete isotopic signatures. These include characteristic 206Pb/ 207Pb ratios of the North Atlantic Drift (1.183-1.187), Iceland-Scotland Overflow Water (1.173-1.176), Denmark Straits Overflow Water (1.179-1.182), and Labrador Sea Water (1.190-1.120). Based on parallels between these initial isotopic data and T- S measurements, it is proposed that stable lead isotopic compositions may be employed as complementary tracers of the mixing of source waters in the Nordic seas, as they overflow the Iceland-Scotland Ridge and Denmark Strait, mixing into the Labrador Sea to form North Atlantic Deep Water.

  15. Optimization of an acidic digestion method for the determination of total Pb concentration and its isotope ratios in human blood using ICP-QMS.

    PubMed

    Pérez-Rodríguez, Rebeca Y; Castro-Larragoitia, Javier; Alfaro-De La Torre, María C; Díaz-Barriga, Fernando

    2017-03-21

    Adverse effects of lead (Pb) on human health are observed even at levels below 5 μg/dL, affecting principally the children population and suggesting that there is not a safe exposure level. The determination of Pb isotopic ratios (LIRs) in biological and environmental samples, is an appropriate tool to track and control the exposure sources, because LIRs constitutes the pollutant's isotopic signature and hence can be used to identify sources of Pb emission. This study proposes the optimization of a method in order to significantly reduce the biological samples' matrix interferences, and improves precision and accuracy in the measurements of LIRs. Four total blood digestion methods were evaluated and the results were subjected to statistical methods (ANOVA) determining the combination of HNO3:H2O2 (2:1 v v(-1))/g from a sample on a hot plate as the best of them. For the method's validation, detection and quantification limits, linearity range, intermediate precision and recovery were evaluated. The total Pb (PbT) and LIRs were performed by ICP-QMS, defining the optimal value of detector dead time (DT), and correcting mass bias and instrumental drift for this matrix. LIRs based on (206)Pb, (207)Pb and (208)Pb were determined at high precision (%RSD 0.03-0.49%), than those involving (204)Pb (%RSD > 0.8). The optimized methodology can be used to identify pollution sources in blood and environmental samples using LIRs ((206)Pb/(207)Pb, (207)Pb/(208)Pb, (208)Pb/(206)Pb, etc.) in a trustworthy and simple way, with accurate results.

  16. Threshold photoneutron cross sections for {sup 208,207,206}Pb isotopes

    SciTech Connect

    Kondo, T.; Utsunomiya, H.; Akimune, H.; Yamagata, T.; Iwamoto, C.; Kamata, M.; Itoh, O.; Toyokawa, H.; Lui, Y.-W.

    2010-06-01

    Photoneutron cross sections for three Pb isotopes ({sup 206}Pb, {sup 207}Pb, {sup 208}Pb) near neutron threshold were measured with the laser inverse-Compton scattering gamma rays at the National Institute of Advanced Industrial Science and Technology. The cross section data are presented.

  17. Identifying sources of Pb pollution in urban soils by means of MC-ICP-MS and TOF-SIMS.

    PubMed

    Rodríguez-Seijo, Andrés; Arenas-Lago, Daniel; Andrade, María Luisa; Vega, Flora A

    2015-05-01

    Lead pollution was evaluated in 17 urban soils from parks and gardens in the city of Vigo (NW Spain). The Pb isotope ratios ((207)Pb/(206)Pb, (208)Pb/(204)Pb, (206)Pb/(204)Pb and (208)Pb/(206)Pb) were determined after being measured by MC-ICP-MS. The association of the isotopes ((204)Pb, (206)Pb, (207)Pb and (208)Pb) with the different components of the soil was studied using TOF-SIMS. The isotopic ranges obtained for the samples were between 1.116 and 1.203 ((206)Pb/(207)Pb), 2.044-2.143 ((208)Pb/(206)Pb), 37.206-38.608 ((208)Pb/(204)Pb), 15.5482-15.6569 ((207)Pb/(204)Pb) and 17.357-18.826 ((206)Pb/(204)Pb). The application of the three-end-member model indicates that the Pb derived from petrol is the main source of Pb in the soils (43.51% on average), followed by natural or geogenic Pb (39.12%) and industrial emissions (17.37%). The emissions derived from coal combustion do not appear to influence the content of Pb in the soil. TOF-SIMS images show that the Pb mainly interacts with organic matter. This technique contributes to the understanding of the association of anthropogenic Pb with the components of the soil, as well as the particle size of these associations, thus allowing the possible sources of Pb to be identified.

  18. Origin of the 'Gabbro' Signature in Ocean Island Basalts: Constraints from Osmium Isotopic Ratios of Galapagos Basalts

    NASA Astrophysics Data System (ADS)

    Gibson, S. A.; Dale, C. W.; Geist, D.; Harpp, K. S.

    2014-12-01

    The Re-Os isotope system has become increasingly used as a tracer of lithological heterogeneity in the convecting mantle, with radiogenic 187Os/188Os in high-Os oceanic basalts and picrites widely interpreted as evidence of a melt contribution from ancient recycled oceanic crust. When combined with 206Pb/204Pb and O isotopes, 187Os/188Os ratios have been used to identify distinct lithological units (i.e. sediments, gabbros and basalts). We report new 187Os/188Os for basalts with high Os (>40 ppt) and MgO from Galápagos, which range from near primitive mantle values (0.130) to highly radiogenic (0.155). While co-variations in 187Os/188Os and 206Pb/204Pb for some Galápagos basalts (Floreana-type) are HIMU like, and consistent with melting of ancient recycled oceanic crust, others have variable 187Os/188Os ratios and primitive to depleted mantle like 206Pb/204Pb. Similar variations in Os and Pb isotopic space have been interpreted in other OIB suites as melts from recycled ancient oceanic gabbros, entrained by upwelling mantle plumes. Nevertheless, a marked east-west spatial variation in 187Os/188Os of Galápagos basalts does not correlate with postulated lithological variations in the Galápagos plume (Vidito et al., 2013). We show that basalts in eastern Galápagos with elevated 187Os/188Os and positive Sr anomalies occur in the vicinity of over-thickened 10 Ma gabbroic crust, that formed when the Galápagos plume was on-axis. We propose the elevated 187Os/188Os of Galápagos basalts are due to in-situ assimilation of young gabbroic lower crust, with high Re/Os, rather than melting of ancient recycled material in the Galápagos plume. In western Galápagos recent plume accreted crust is thick but more mafic, the melt flux higher and assimilation more sporadic. The contamination thresholds of Os and MgO in Galápagos basalts occur at higher contents than for many global OIBs (Azores, Iceland, Hawaii) and may reflect both a relatively low melt flux into the crust

  19. Lead as transient geochemical tracers in the environment: Assessing high precision isotope ratio measurements in lichens, peat, and silicates using multi-collector ICP-MS

    NASA Astrophysics Data System (ADS)

    Weiss, D. J.; Kober, B.; Mason, T. F.; Dolgopolova, A.; Coles, B. J.; Gallagher, K.; Leroux, G.; Spiro, B.; Seltmann, R.

    2003-04-01

    . Samples passed through the columns and measured with TIMS and MC-ICP-MS showed excellent correlation (r=0.9876 for 206Pb/204Pb ratios, slope=0.9474, n=15). The β-values of natural and synthetic samples during a measurement session did not differ significantly, indicating that the complex peat and lichen matrix did not affect the mass bias behaviour of the Tl spike.

  20. Chemical signatures of the Anthropocene in the Clyde estuary, UK: sediment-hosted Pb, (207/206)Pb, total petroleum hydrocarbon, polyaromatic hydrocarbon and polychlorinated biphenyl pollution records.

    PubMed

    Vane, C H; Chenery, S R; Harrison, I; Kim, A W; Moss-Hayes, V; Jones, D G

    2011-03-13

    The sediment concentrations of total petroleum hydrocarbons (TPHs), polyaromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs), Pb and (207/206)Pb isotope ratios were measured in seven cores from the middle Clyde estuary (Scotland, UK) with an aim of tracking the late Anthropocene. Concentrations of TPHs ranged from 34 to 4386 mg kg(-1), total PAHs from 19 to 16,163 μg kg(-1) and total PCBs between less than 4.3 to 1217 μg kg(-1). Inventories, distributions and isomeric ratios of the organic pollutants were used to reconstruct pollutant histories. Pre-Industrial Revolution and modern non-polluted sediments were characterized by low TPH and PAH values as well as high relative abundance of biogenic-sourced phenanthrene and naphthalene. The increasing industrialization of the Clyde gave rise to elevated PAH concentrations and PAH isomeric ratios characteristic of both grass/wood/coal and petroleum and combustion (specifically petroleum combustion). Overall, PAHs had the longest history of any of the organic contaminants. Increasing TPH concentrations and a concomitant decline in PAHs mirrored the lessening of coal use and increasing reliance on petroleum fuels from about the 1950s. Thereafter, declining hydrocarbon pollution was followed by the onset (1950s), peak (1965-1977) and decline (post-1980s) in total PCB concentrations. Lead concentrations ranged from 6 to 631 mg kg(-1), while (207/206)Pb isotope ratios spanned 0.838-0.876, indicative of various proportions of 'background', British ore/coal and Broken Hill type petrol/industrial lead. A chronology was established using published Pb isotope data for aerosol-derived Pb and applied to the cores.

  1. Deep Sub-Barrier Fusion Enhancement in the {sup 6}He+{sup 206}Pb Reaction

    SciTech Connect

    Penionzhkevich, Yu.E.; Zagrebaev, V.I.; Lukyanov, S.M.; Kalpakchieva, R.

    2006-04-28

    The fusion of {sup 6}He with {sup 206}Pb has been studied at energies close to and below the Coulomb barrier. The experiment was carried out at the Dubna Radioactive Ion Beams complex of FLNR, JINR. The {sup 6}He beam intensity was about 5x10{sup 6} pps, the maximum energy being 60.3{+-}0.4 MeV. The yield of the {sup 210}Po isotope, produced in the 2n-evaporation channel, demonstrates an extremely large enhancement of the sub-barrier fusion cross section as compared with the {sup 4}He+{sup 208}Pb reaction. This enhancement is most likely due to the mechanism of 'sequential fusion' with an intermediate neutron transfer from {sup 6}He to the Pb nucleus with positive Q values.

  2. Lead isotope ratio measurements as indicators for the source of lead poisoning in Mute swans (Cygnus olor) wintering in Puck Bay (northern Poland).

    PubMed

    Binkowski, Łukasz J; Meissner, Włodzimierz; Trzeciak, Marta; Izevbekhai, Kelvin; Barker, James

    2016-12-01

    Lead (Pb) poisoning is most commonly linked amongst anthropogenically-caused deaths in waterfowl and this is often associated with hunting and fishing activities. However, the exact identification of the source may be difficult with commonly-used techniques. We have studied isotope ratios using Inductively-Coupled Plasma Mass Spectrometry (ICP-MS) to investigate the source of Pb in the blood of Mute swans (n = 49) wintering in northern Poland. We compared the values of isotopic ratios from blood and ammunition pellets available on the Polish market. The mean Pb concentrations found was 0.241 μg/g (w/w) and nearly half of the blood specimens had elevated Pb levels (higher than the cited 0.23 μg/g w/w threshold of poisoning). Only the mean 208/206 Pb isotope ratio was similar in blood and pellet samples. Mean ratios of isotopes 206/204, 206/207 and 208/207 in swans' blood and in pellets differed significantly. Moreover, coefficients of variation were higher in blood samples than in pellets. These discrepancies and significant differences in abundance of (204)Pb and (207)Pb isotopes in both materials indicated that pellets available today on the Polish market were not the source of Pb in the blood of Mute swans wintering in northern Poland.

  3. 207Pb(n,2n{gamma})206Pb Cross-Section Measurements by In-Beam Gamma-Ray Spectroscopy

    SciTech Connect

    Baumann, P.; Kerveno, M.; Rudolf, G.; Borcea, C.; Jericha, E.; Jokic, S.; Lukic, S.; Mihailescu, L. C.; Plompen, A. J. M.; Pavlik, A.

    2006-03-13

    207Pb(n,2n{gamma})206Pb cross section were measured for incident neutron energies between 6 and 20 MeV with the white neutron beam produced at GELINA. The {gamma}-ray production cross section for the main transition (803 keV, 2+{yields} 0+) in 206Pb is compared to results obtained at Los Alamos and to the TALYS and EMPIRE-II code predictions.

  4. Final report of the key comparison CCQM-K98: Pb isotope amount ratios in bronze

    NASA Astrophysics Data System (ADS)

    Vogl, Jochen; Yim, Yong-Hyeon; Lee, Kyoung-Seok; Goenaga-Infante, Heidi; Malinowskiy, Dmitriy; Ren, Tongxiang; Wang, Jun; Vocke, Robert D., Jr.; Murphy, Karen; Nonose, Naoko; Rienitz, Olaf; Noordmann, Janine; Näykki, Teemu; Sara-Aho, Timo; Ari, Betül; Cankur, Oktay

    2014-01-01

    Isotope amount ratios are proving useful in an ever increasing array of applications that range from studies unravelling transport processes, to pinpointing the provenance of specific samples as well as trace element quantification by using isotope dilution mass spectrometry (IDMS). These expanding applications encompass fields as diverse as archaeology, food chemistry, forensic science, geochemistry, medicine and metrology. However, to be effective tools, the isotope ratio data must be reliable and traceable to enable the comparability of measurement results. The importance of traceability and comparability in isotope ratio analysis has already been recognized by the Inorganic Analysis Working Group (IAWG) within the CCQM. While the requirements for isotope ratio accuracy and precision in the case of IDMS are generally quite modest, 'absolute' Pb isotope ratio measurements for geochemical applications as well as forensic provenance studies require Pb isotope ratio measurements of the highest quality. To support present and future CMCs on isotope ratio determinations, a key comparison was urgently needed and therefore initiated at the IAWG meeting in Paris in April 2011. The analytical task within such a comparison was decided to be the measurement of Pb isotope amount ratios in water and bronze. Measuring Pb isotope amount ratios in an aqueous Pb solution tested the ability of analysts to correct for any instrumental effects on the measured ratios, while the measurement of Pb isotope amount ratios in a metal matrix sample provided a real world test of the whole chemical and instrumental procedure. A suitable bronze material with a Pb mass fraction between 10 and 100 mg•kg-1 and a high purity solution of Pb with a mass fraction of approximately 100 mg•kg-1 was available at the pilot laboratory (BAM), both offering a natural-like Pb isotopic composition. The mandatory measurands, the isotope amount ratios n(206Pb)/n(204Pb), n(207Pb)/n(204Pb) and n(208Pb)/n(204Pb

  5. Stable (206Pb, 207Pb, 208Pb) and radioactive (210Pb) lead isotopes in 1 year of growth of Sphagnum moss from four ombrotrophic bogs in southern Germany: Geochemical significance and environmental implications

    NASA Astrophysics Data System (ADS)

    Shotyk, William; Kempter, Heike; Krachler, Michael; Zaccone, Claudio

    2015-08-01

    behaviour of 210Pb and total Pb in the mosses may reflect differences in the particle size distribution of the corresponding aerosols, their physical and chemical properties, the extent of their interaction with plant surfaces, or some combination of these factors. The 206Pb/207Pb ratios from NBF (HO = 1.159 ± 0.002, n = 19; WI = 1.157 ± 0.003, n = 48) and OB (GS = 1.157 ± 0.003, n = 28; KL = 1.159 ± 0.003, n = 15) are uniform and indicate that both regions are impacted by Pb from predominately anthropogenic sources. Although Sphagnum moss represents an established receptor in monitoring atmospheric Pb deposition, the physical characteristics (size, morphology, composition) of the three predominant kinds of Pb-bearing aerosols considered here, namely 210Pb (adsorbed onto aerosol surfaces, following decay of 222Rn), anthropogenic Pb (sub-micron aerosols from high temperature combustion processes) and lithogenic Pb soil-derived mineral dusts (tens of microns, from chemical weathering of crustal rocks), are fundamentally different and these have consequences for the retention efficiency of the three kinds of particles.

  6. Feather lead concentrations and207Pb/206Pb ratios reveal lead exposure history of California condors (Gymnogyps californianus)

    USGS Publications Warehouse

    Finkelstein, M.E.; George, D.; Scherbinski, S.; Gwiazda, R.; Johnson, M.; Burnett, J.; Brandt, J.; Lawrey, S.; Pessier, Allan P.; Clark, M.; Wynne, J.; Grantham, And J.; Smith, D.R.

    2010-01-01

    Lead poisoning is a primary factor impeding the survival and recovery of the critically endangered California Condor (Gymnogyps californianus). However, the frequency and magnitude of lead exposure in condors is not well-known in part because most blood lead monitoring occurs biannually, and biannual blood samples capture only ???10% of a bird's annual exposure history. We investigated the use of growing feathers from free-flying condors in California to establish a bird's lead exposure history. We show that lead concentration and stable lead isotopic composition analyses of sequential feather sections and concurrently collected blood samples provided a comprehensive history of lead exposure over the 2-4 month period of feather growth. Feather analyses identified exposure events not evident from blood monitoring efforts, and by fitting an empirically derived timeline to actively growing feathers, we were able to estimate the time frame for specific lead exposure events. Our results demonstrate the utility of using sequentially sampled feathers to reconstruct lead exposure history. Since exposure risk in individuals is one determinant ?? 2010 American Chemical Society.

  7. Feather lead concentrations and (207)Pb/(206)Pb ratios reveal lead exposure history of California Condors (Gymnogyps californianus).

    PubMed

    Finkelstein, M E; George, D; Scherbinski, S; Gwiazda, R; Johnson, M; Burnett, J; Brandt, J; Lawrey, S; Pessier, A P; Clark, M; Wynne, J; Grantham, J; Smith, D R

    2010-04-01

    Lead poisoning is a primary factor impeding the survival and recovery of the critically endangered California Condor (Gymnogyps californianus). However, the frequency and magnitude of lead exposure in condors is not well-known in part because most blood lead monitoring occurs biannually, and biannual blood samples capture only approximately 10% of a bird's annual exposure history. We investigated the use of growing feathers from free-flying condors in California to establish a bird's lead exposure history. We show that lead concentration and stable lead isotopic composition analyses of sequential feather sections and concurrently collected blood samples provided a comprehensive history of lead exposure over the 2-4 month period of feather growth. Feather analyses identified exposure events not evident from blood monitoring efforts, and by fitting an empirically derived timeline to actively growing feathers, we were able to estimate the time frame for specific lead exposure events. Our results demonstrate the utility of using sequentially sampled feathers to reconstruct lead exposure history. Since exposure risk in individuals is one determinant of population health, our findings should increase the understanding of population-level effects from lead poisoning in condors; this information may also be helpful for other avian species potentially impacted by lead poisoning.

  8. Sr-Nd-Hf-Pb Isotope Ratios in Recent NE Lau Lavas

    NASA Astrophysics Data System (ADS)

    Todd, E.; Gill, J. B.; Freymuth, H.

    2009-12-01

    Sr-Nd-Hf-Pb isotope ratios in recently erupted NE Lau lavas are being measured and results will be presented. The recent W. Mata boninites lie slightly west of the northern termination of the Tongan volcanic front in an area where previously dredged boninites are enriched in LREE and HFSE. They are interpreted as containing an OIB-type mantle source component fluxed by slab-derived fluids (Falloon et al., 2007; Pearce et al., 2007). However, their Sr-Nd-Pb isotope ratios do not match any known component from the Samoan plume, pelagic sediment, or Louisville Ridge-derived volcaniclastic sediment. Their most distinctive isotopic characteristics are low 87Sr/86Sr and high 206Pb/204Pb relative to Nd-Hf isotope ratios. They are displaced toward HIMU-type basalts from the Cook-Austral islands (e.g., Tubuai) and have been interpreted as derived from diverse HIMU, EMI, and EMII mantle source components that are carried southward from beneath the Pacific Plate into the NE Lau Basin. Basalts from the NE Lau Spreading Center have more of a Indian-MORB source than do the boninites, and are similar to the <3 Ma OIB-type basalts from Fiji (Gill, 1984 and unpub.). If so, then some diverse enriched “plums” melt out of southward-advecting MORB-source “pudding” over as little as 100 km, whereas others persist for ~500 km to Fiji. Data for the recently erupted samples will test these interpretations, and will be compared to characteristics of the earliest (7.4 Ma) boninitic lavas in the region that have less of the OIB component. References: T. J. Falloon, L. Danyushevsky, A. J. Crawford, R. Maas, J. D. Woodhead, S. Eggins, S. Bloomer, D. J. Wright, S. K. Zlobin, and A. R. Stacey. Multiple mantle plume components involved in the petrogenesis of subduction-related lavas from the northern termination of the Tonga Arc and northern Lau Basin: Evidence from the geochemistry of arc and backarc submarine volcanics. Geochemistry, Geophysics, Geosystems, 8(Q09003):45, 2007. J. B. Gill

  9. Lead and strontium isotopic evidence for crustal interaction and compositional zonation in the source regions of Pleistocene basaltic and rhyolitic magmas of the Coso volcanic field, California

    USGS Publications Warehouse

    Bacon, C.R.; Kurasawa, H.; Delevaux, M.H.; Kistler, R.W.; Doe, B.R.

    1984-01-01

    The isotopic compositions of Pb and Sr in Pleistocene basalt, high-silica rhyolite, and andesitic inclusions in rhyolite of the Coso volcanic field indicate that these rocks were derived from different levels of compositionally zoned magmatic systems. The 2 earliest rhyolites probably were tapped from short-lived silicic reservoirs, in contrast to the other 36 rhyolite domes and lava flows which the isotopic data suggest may have been leaked from the top of a single, long-lived magmatic system. Most Coso basalts show isotopic, geochemical, and mineralogic evidence of interaction with crustal rocks, but one analyzed flow has isotopic ratios that may represent mantle values (87Sr/86Sr=0.7036,206Pb/204Pb=19.05,207Pb/204Pb=15.62,208Pb/204Pb= 38.63). The (initial) isotopic composition of typical rhyolite (87Sr/86Sr=0.7053,206Pb/204Pb=19.29,207Pb/204Pb= 15.68,208Pb/204Pb=39.00) is representative of the middle or upper crust. Andesitic inclusions in the rhyolites are evidently samples of hybrid magmas from the silicic/mafic interface in vertically zoned magma reservoirs. Silicic end-member compositions inferred for these mixed magmas, however, are not those of erupted rhyolite but reflect the zonation within the silicic part of the magma reservoir. The compositional contrast at the interface between mafic and silicic parts of these systems apparently was greater for the earlier, smaller reservoirs. ?? 1984 Springer-Verlag.

  10. Lead isotopes in volcanic rocks and possible ocean-floor thrusting beneath island arcs

    USGS Publications Warehouse

    Tatsumoto, M.

    1969-01-01

    The isotopic composition of lead in the Japanese primary basalts gradually decreases in radiogenic character in a transverse from the Pacific Ocean side to the Japan Sea side, whereas the observed 238U 204Pb and 232Th 204Pb ratios in the basalts increase in the same direction. The isotopic composition of lead suggests that tholeiite (Pacific side) is generated at a shallower depth than alkali basalt (Japan Sea side) as postulated by Kuno. The inverse correlation of the 238U 204Pb with the 206Pb 204Pb ratios could be due to preferential Pb extraction with respect to uranium at shallow depths. Alternatively, these geochemical results can be interpreted in terms of the Pacific oceanic rigid plate being underthurst beneath the island arc. The isotopic variation in basalts across the Japanese island arc would result from different proportions of the plate material and the upper mantle of continental side in the partial melt. ?? 1969.

  11. High-precision measurements of seawater Pb isotope compositions by double spike thermal ionization mass spectrometry.

    PubMed

    Paul, Maxence; Bridgestock, Luke; Rehkämper, Mark; van DeFlierdt, Tina; Weiss, Dominik

    2015-03-10

    A new method for the determination of seawater Pb isotope compositions and concentrations was developed, which combines and optimizes previously published protocols for the separation and isotopic analysis of this element. For isotopic analysis, the procedure involves initial separation of Pb from 1 to 2L of seawater by co-precipitation with Mg hydroxide and further purification by a two stage anion exchange procedure. The Pb isotope measurements are subsequently carried out by thermal ionization mass spectrometry using a (207)Pb-(204)Pb double spike for correction of instrumental mass fractionation. These methods are associated with a total procedural Pb blank of 28±21 pg (1sd) and typical Pb recoveries of 40-60%. The Pb concentrations are determined by isotope dilution (ID) on 50 mL of seawater, using a simplified version of above methods. Analyses of multiple aliquots of six seawater samples yield a reproducibility of about ±1 to ±10% (1sd) for Pb concentrations of between 7 and 50 pmol/kg, where precision was primarily limited by the uncertainty of the blank correction (12±4 pg; 1sd). For the Pb isotope analyses, typical reproducibilities (±2sd) of 700-1500 ppm and 1000-2000 ppm were achieved for (207)Pb/(206)Pb, (208)Pb/(206)Pb and (206)Pb/(204)Pb, (207)Pb/(204)Pb, (208)Pb/(204)Pb, respectively. These results are superior to literature data that were obtained using plasma source mass spectrometry and they are at least a factor of five more precise for ratios involving the minor (204)Pb isotope. Both Pb concentration and isotope data, furthermore, show good agreement with published results for two seawater intercomparison samples of the GEOTRACES program. Finally, the new methods were applied to a seawater depth profile from the eastern South Atlantic. Both Pb contents and isotope compositions display a smooth evolution with depth, and no obvious outliers. Compared to previous Pb isotope data for seawater, the (206)Pb/(204)Pb ratios are well correlated

  12. Plume-Lithosphere Interaction beneath the Snake River Plain, Idaho: Constraints from Pb, Sr, Nd, and Hf Isotopes

    NASA Astrophysics Data System (ADS)

    Jean, M. M.; Hanan, B. B.; Shervais, J. W.

    2011-12-01

    The Yellowstone-Snake River Plain (YSRP) volcanic province links 17 million years of volcanic activity that extends from the Owyhee Plateau in western Idaho/eastern Oregon to its current terminus underlying the Yellowstone Plateau. This investigation presents new Strontium, Neodymium, Lead, and Hafnium isotopic compositions of 25 basalts that represent four distinct areas of the YSRP (i.e., eastern province, central province, western province, Owyhee Plateau), which transect the ancient cratonic boundary of North America. The purpose of this study is to test and refine models for plume-lithosphere interaction and determines the mantle origin for YSRP basalts. New results shows: (1) low-K tholeiites from the eastern, central, and western SRP have ɛNd (-2 to -5.5), 87Sr/86Sr (0.7060-0.7071) and similar Pb-isotopes [206Pb/204Pb (17.8-18.6), 207Pb/204Pb (15.5-15.66), 208Pb/204Pb (38.4-39.1)]; (2) central SRP tholeiites are enriched in 208Pb/204Pb (~38.5-38.9), relative to eastern SRP basalts and define a 208Pb/204Pb trend, intermediate between the eastern SRP and Craters of the Moon lavas; (3) western SRP high-K basalts are depleted in ɛNd (> -1) and 87Sr/86Sr (0.7050-0.7057), relative to low-K tholeiites, and plot closer to "bulk silicate earth," but are enriched in 206Pb/204Pb (18.66-18.71), and have 207Pb/204Pb (15.62-15.65) and 208Pb/204Pb (39.1-39.2) isotope ratios similar to high-K basalts of Smith Prairie (Boise River Group 2); (4) Silver City basalt (>16.6 Ma) overlaps in Pb-isotope space with Imnaha basalt compositions (Columbia River Basalt Group); (5) new 177Hf/176Hf isotopic data lie above and parallel to the Mantle array in Nd and Hf isotope space and define a linear trend between Leucite Hills lavas and OIB basalts (i.e., Steens and Hawaii); (6) these basalts follow a systematic geographic pattern: eastern and central plain low-K tholeiites have low ɛNd (-3 to -5) and intermediate 206Pb/204Pb (~17.7-18.5), while western plain low-K tholeiites are

  13. Improved 206Pb/238U microprobe geochronology by the monitoring of a trace-element-related matrix effect; SHRIMP, ID-TIMS, ELA-ICP-MS and oxygen isotope documentation for a series of zircon standards

    USGS Publications Warehouse

    Black, L.P.; Kamo, S.L.; Allen, C.M.; Davis, D.W.; Aleinikoff, J.N.; Valley, J.W.; Mundil, R.; Campbell, I.H.; Korsch, R.J.; Williams, I.S.; Foudoulis, C.

    2004-01-01

    Precise isotope dilution-thermal ionisation mass spectrometry (ID-TIMS) documentation is given for two new Palaeozoic zircon standards (TEMORA 2 and R33). These data, in combination with results for previously documented standards (AS3, SL13, QGNG and TEMORA 1), provide the basis for a detailed investigation of inconsistencies in 206Pb/238U ages measured by microprobe. Although these ages are normally consistent between any two standards, their relative age offsets are often different from those established by ID-TIMS. This is true for both sensitive high-resolution ion-microprobe (SHRIMP) and excimer laser ablation-inductively coupled plasma-mass spectrometry (ELA-ICP-MS) dating, although the age offsets are in the opposite sense for the two techniques. Various factors have been investigated for possible correlations with age bias, in an attempt to resolve why the accuracy of the method is worse than the indicated precision. Crystallographic orientation, position on the grain-mount and oxygen isotopic composition are unrelated to the bias. There are, however, striking correlations between the 206Pb/238U age offsets and P, Sm and, most particularly, Nd abundances in the zircons. Although these are not believed to be the primary cause of this apparent matrix effect, they indicate that ionisation of 206Pb/238U is influenced, at least in part, by a combination of trace elements. Nd is sufficiently representative of the controlling trace elements that it provides a quantitative means of correcting for the microprobe age bias. This approach has the potential to reduce age biases associated with different techniques, different instrumentation and different standards within and between laboratories. Crown Copyright ?? 2004 Published by Elsevier B.V. All rights reserved.

  14. Metal enrichment and lead isotope analysis for source apportionment in the urban dust and rural surface soil.

    PubMed

    Yu, Yang; Li, Yingxia; Li, Ben; Shen, Zhenyao; Stenstrom, Michael K

    2016-09-01

    To understand the metal accumulation in the environment and identify its sources, 29 different metal contents and lead (Pb) isotope ratios were determined for 40 urban dust samples, 36 surface soil samples, and one river sediment sample collected in the municipality of Beijing, China. Results showed that cadmium, copper (Cu), mercury, Pb, antimony (Sb), and zinc demonstrated to be the typical urban contaminants and mostly influenced by the adjacent human activities with higher content to background ratios and SD values. Among the 29 metal elements investigated, Cu and Sb were found to be the most distinct elements that were highly affected by the developing level and congestion status of the cities with much higher contents in dust in more developed and congested cities. There was a relatively wider range of Pb isotope ratios of country surface soil than those of urban dust. The results of source identification based on Pb isotope ratios showed that coal combustion was the first largest Pb source and vehicle exhaust was the second largest source. The sum of them accounted for 74.6% mass proportion of overall Pb pollution on average. The surface soil sample collected at an iron mine had the highest (204)Pb/(206)Pb, (207)Pb/(206)Pb, and (208)Pb/(206)Pb ratios indicating ore had much higher ratios than other sources. The fine particle subsamples had higher (204)Pb/(206)Pb, (207)Pb/(206)Pb, and (208)Pb/(206)Pb ratios than the coarse particle subsamples indicating more anthropogenic sources of coal combustion and vehicle exhaust for fine particles and more background influence for coarse particles. These results help with pinpointing the major Pb sources and applying suitable measures for the target sources.

  15. Primitive and contaminated basalts from the Southern Rocky Mountains, U.S.A

    USGS Publications Warehouse

    Doe, B.R.; Lipman, P.W.; Hedge, C.E.; Kurasawa, H.

    1969-01-01

    Basalts in the Southern Rocky Mountains province have been analyzed to determine if any of them are primitive. Alkali plagioclase xenocrysts armored with calcic plagioclase seem to be the best petrographic indicator of contamination. The next best indicator of contamination is quartz xenocrysts armored with clinopyroxene. On the rocks and the region studied, K2O apparently is the only major element with promise of separating primitive basalt from contaminated basalt inasmuch as it constitutes more than 1 % in all the obviously contaminated basalts. K2O: lead (> 4 ppm) and thorium (> 2 ppm) contents and Rb/Sr (> 0.035) are the most indicative of the trace elements studied. Using these criteria, three basalt samples are primitive (although one contains 1.7% K2O) and are similar in traceelement contents to Hawaiian and Eastern Honshu, Japan, primitive basalts. Contamination causes lead isotope ratios, 206Pb/204Pb and 208Pb/204Pb, to become less radiogenic, but it has little or no effect on 87Sr/86Sr. We interpret the effect on lead isotopes to be due to assimilation either of lower crustal granitic rocks, which contain 5-10 times as much lead as basalt and which have been low in U/Pb and Th/Pb since Precambrian times, or of upper crustal Precambrian or Paleozoic rocks, which have lost much of their radiogenic lead because of heating prior to assimilation. The lack of definite effects on strontium isotopes may be due to the lesser strontium contents of granitic crustal rocks relative to basaltic rocks coupled with lack of a large radiogenic enrichment in the crustal rocks. Lead isotope ratios were found to be less radiogenic in plagioclase separates from an obviously contaminated basalt than in the primitive basalts. The feldspar separate that is rich in sodic plagioclase xenocrysts was found to be similar to the whole-rock composition for 206Pb/204Pb and 208Pb/204Pb whereas a more dense fraction probably enriched in more calcic plagioclase phenocrysts is more similar

  16. Use of stable lead isotopes and trace metals to characterize air mass sources into the eastern North Atlantic

    NASA Astrophysics Data System (ADS)

    VéRon, Alain J.; Church, Thomas M.

    1997-12-01

    Stable lead isotopes (204Pb, 206Pb, 207Pb, 208Pb) and trace metals (Mn, Al, Fe, Ni, Cu, Cd, Zn, Pb) have been analyzed in aerosol collected during the Atlantic Stratocumulus Transition Experiment-Marine Aerosol and Gas Exchange (ASTEX-MAGE) cruise that transited between Miami and the Azores from May to July 1992. Our goal was to define the continental signatures of the air masses encountered between the Azores and the subtropical regions. The combination of air mass trajectories, trace metal concentrations and stable lead isotopes allowed us to characterize the anthropogenic character of encountered air masses. The average 206Pb/207Pb ratio was 1.148±0.021 and corresponded to a mixing between well defined European (such as Great Britain with 1.115<206Pb/207Pb<1.125 and France with 206Pb/207Pb=1.141±0.000) and North American sources (with 206Pb/207Pb=1.184±0.000). On the basis of air mass trajectories and trace metal concentrations, the background isotopic signature associated with the trade winds (206Pb/207Pb=1.161±0.004) is consistent with previous reports by Church et al. [1990] such as 206Pb/207Pb=1.154±0.004 in 1988, (Véron et al., 1993), 206Pb/207Pb=1.155±0.004 in 1989, and Hamelin et al. [1996] (206Pb/207Pb=1.158±0.006) in 1991. Short-term variations of continental air mass sources was particularly investigated by considering the anthropogenic character of aerosols collected during two Lagrangian experiments conducted as part of the ASTEX-MAGE cruise. We demonstrated the utility of stable lead isotopes to assign a "continental source signature" (or mixture thereof) to air masses beyond that normally possible by conventional air mass trajectory analysis in remote oceanic regions.

  17. Levels and source apportionment of children's lead exposure: could urinary lead be used to identify the levels and sources of children's lead pollution?

    PubMed

    Cao, Suzhen; Duan, Xiaoli; Zhao, Xiuge; Wang, Beibei; Ma, Jin; Fan, Delong; Sun, Chengye; He, Bin; Wei, Fusheng; Jiang, Guibin

    2015-04-01

    As a highly toxic heavy metal, the pollution and exposure risks of lead are of widespread concern for human health. However, the collection of blood samples for use as an indicator of lead pollution is not always feasible in most cohort or longitudinal studies, especially those involving children health. To evaluate the potential use of urinary lead as an indicator of exposure levels and source apportionment, accompanying with environmental media samples, lead concentrations and isotopic measurements (expressed as (207)Pb/(206)Pb, (208)Pb/(206)Pb and (204)Pb/(206)Pb) were investigated and compared between blood and urine from children living in the vicinities of a typical coking plant and lead-acid battery factory. The results showed urinary lead might not be a preferable proxy for estimating blood lead levels. Fortunately, urinary lead isotopic measurements could be used as an alternative for identifying the sources of children's lead exposure, which coincided well with the blood lead isotope ratio analysis.

  18. Petrogenesis of pegmatites and granites in southwestern Maine

    SciTech Connect

    Tomascak, P.B.; Walker, R.J.; Krogstad, E.J. . Dept. of Geology)

    1993-03-01

    Granitic pegmatites occurring near the town of Topsham in southwestern Maine are mineralogically diverse, featuring abundant dikes and contain rare earth element minerals as well as one pegmatite that contains Li minerals. The pegmatite series crops out near the Brunswick granite, a texturally diverse granitic pluton, and lies 13 km southeast of the Mississippian age Sebago batholith. Areas intruded by pegmatites that possess such different mineral assemblages are globally rare. The origins of these mixed'' pegmatite series have not been comprehensively investigated. There is no known pattern of regional zonation (mineral/chemical) among Topsham series pegmatites, hence simple fractionation processes are probably not responsible for the compositional variations. The authors are attempting to clarify pegmatite petrogenesis using common Pb isotopic ratios of feldspars and Sm-Nd isotopic data from whole rocks and minerals. Pb isotopic ratios from leached feldspars reflect the Pb ratios of the source from which they were derived. The range of Pb isotopic compositions of alkali feldspars from 7 granitic pegmatites is as follows: [sup 206]Pb/[sup 204]Pb = 18.5-19.1; [sup 207]Pb/[sup 204]Pb = 15.53-15.69; [sup 208]Pb/[sup 204]Pb = 38.3-38.6. The Brunswick granite has K-feldspars with [sup 206]Pb/[sup 204]Pb = 18.40-18.47, [sup 207]/[sup 204]Pb = 15.64-15.66 and [sup 208]Pb/[sup 204]Pb = 38.29-38.39. The Pb isotopic compositions of both pegmatites and granites are significantly more radiogenic than existing data for the Sebago granite and argue against the consanguinity of Topsham pegmatites and the Sebago batholith. These data instead support a genetic link between the pegmatites and the Brunswick granite, which ranges from a fine-grained two-mica granite to a garnet-bearing pegmatitic leucogranite.

  19. Lead shot contribution to blood lead of First Nations people: the use of lead isotopes to identify the source of exposure.

    PubMed

    Tsuji, Leonard J S; Wainman, Bruce C; Martin, Ian D; Sutherland, Celine; Weber, Jean-Philippe; Dumas, Pierre; Nieboer, Evert

    2008-11-01

    Although lead isotope ratios have been used to identify lead ammunition (lead shotshell pellets and bullets) as a source of exposure for First Nations people of Canada, the actual source of lead exposure needs to be further clarified. Whole blood samples for First Nations people of Ontario, Canada, were collected from participants prior to the traditional spring harvest of water birds, as well as post-harvest. Blood-lead levels and stable lead isotope ratios prior to, and after the harvest were determined by ICP-MS. Data were analyzed by paired t-tests and Wilcoxon Signed-Ranks tests. All participants consumed water birds harvested with lead shotshell during the period of study. For the group excluding six males who were potentially exposed to other sources of lead (as revealed through a questionnaire), paired t-tests and Wilcoxon Signed-Ranks tests showed consistent results: significant (p<0.05) increases in blood-lead concentrations and blood levels of (206)Pb/(204)Pb and (206)Pb/(207)Pb towards the mean values we previously reported for lead shotshell pellets; and a significant decrease in (208)Pb/(206)Pb values towards the mean for lead shotshell pellets. However, when we categorized the group further into a group that did not use firearms and did not eat any other traditional foods harvested with lead ammunition other than waterfowl, our predictions for (206)Pb/(204)Pb, (206)Pb/(207)Pb and (208)Pb/(206)Pb hold true, but there was not a significant increase in blood-lead level after the hunt. It appears that the activity of hunting (i.e., use of a shotgun) was also an important route of lead exposure. The banning of lead shotshell for all game hunting would eliminate a source of environmental lead for all people who use firearms and/or eat wild game.

  20. Origin of lead in eight Central European peat bogs determined from isotope ratios, strengths, and operation times of regional pollution sources.

    PubMed

    Novák, Martin; Emmanuel, Simon; Vile, Melanie A; Erel, Yigal; Véron, Alain; Paces, Tomás; Wieder, R Kelman; Vanecek, Mirko; Stepánová, Markéta; Brízová, Eva; Hovorka, Jan

    2003-02-01

    Lead originating from coal burning, gasoline burning, and ore smelting was identified in 210Pb-dated profiles through eight peat bogs distributed over an area of 60,000 km2. The Sphagnum-dominated bogs were located mainly in mountainous regions of the Czech Republic bordering with Germany, Austria, and Poland. Basal peat 14C-dated at 11,000 years BP had a relatively high 206Pb/207Pb ratio (1.193). Peat deposited around 1800 AD had a lower 206Pb/207Pb ratio of 1.168-1.178, indicating that environmental lead in Central Europe had been largely affected by human activity (smelting) even before the beginning of the Industrial Revolution. Five of the sites exhibited a nearly constant 206Pb/207Pb ratio (1.175) throughout the 19th century, resembling the "anthropogenic baseline" described in Northern Europe (1.17). At all sites, the 206Pb/207Pb ratio of peat decreased at least until 1980; at four sites, a reversal to more radiogenic values (higher 206Pb/207Pb), typical of easing pollution, was observed in the following decade (1980-1990). A time series of annual outputs for 14 different mining districts dispersing lead into the environment has been constructed for the past 200 years. The production of Ag-Pb, coal, and leaded gasoline peaked in 1900, 1980, and 1980, respectively. In contrast to other European countries, no peak in annual Pb accumulation rates was found in 1900, the year of maximum ore smelting. The highest annual Pb accumulation rates in peat were consistent with the highest Pb emission rates from coal-fired power plants and traffic (1980). Although maximum coal and gasoline production coincided in time, their isotope ratios were unique. The mean measured 206Pb/207Pb ratios of local coal, ores, and gasoline were 1.19, 1.16, and 1.11, respectively. A considerable proportion of coal emissions, relative to gasoline emisions, was responsible for the higher 206Pb/207Pb ratios in the recent atmosphere (1.15) compared to Western Europe (1.10). As in West European

  1. Southwestern limits of Indian Ocean Ridge mantle and the origin of low Pb-206/Pb-204 mid-ocean ridge basalt - Isotope systematics of the central Southwest Indian Ridge (17 deg - 50 deg E)

    NASA Astrophysics Data System (ADS)

    Mahoney, J.; Le Roex, A. P.; Peng, Z.; Fisher, R. L.; Natland, J. H.

    1992-12-01

    The isotopic characteristics of the Indian Ocean Ridge midocean ridge basalts (MORBs) and of the Atlantic and the Pacific MORBs (north of 25 deg S) were determined in order to estimate the southwestern limits of the Indian Ocean Ridge mantle and the origin of low Pb-206/Pb-204 MORB. In view of the possible importance of a Marion-type mantle along portions of the ridge, lavas from several Marion Island, Prince Edward Island, and Funk Seamount were also analyzed isotopically. The isotopic results include analyses of fields for the Indian Ocean triple junction area, the entire Central Indian and southern Carlsberg ridges, for several oceanic islands, and Pacific and/or North Atlantic MORBs.

  2. Lead Isotope Constraints on the Sources of Ore Metals in SW Mexican Deposits

    NASA Astrophysics Data System (ADS)

    Potra, A.; Macfarlane, A. W.

    2007-12-01

    Lead isotope ratios from mineral deposits in southern Mexico increase with distance from the trench from 206Pb/204Pb values between 18.597 and 18.650 in the coastal area to values between 18.712 and 19.069 approximately 800 km east from the trench. This variation has been attributed to increasing assimilation of radiogenic lead from the crust with increasing distance from the trench. New sampling was undertaken in this area to provide a clearer picture of the potential sources of ore metals in this arc system, and also, if possible, to examine whether ore metal sources differ among the proposed tectonostratigraphic exotic terranes of southern Mexico. New TIMS lead isotope analyses are presented for samples from the metamorphic basement rocks of the Guerrero Terrane, the Late Cretaceous clastic sedimentary rocks from the Upper Mesozoic Assemblage, and for mid-Cretaceous igneous rocks, as well as for samples from the Oligocene La Verde, Esmeralda, and El Malacate copper prospects. Whole rock samples of schist from the Jurassic-Cretaceous Arteaga Complex and phyllite and slate from the Tierra Caliente Complex contain radiogenic lead relative to bulk earth models, with 206Pb/204Pb ranging from 18.981-19.256. These values are substantially more radiogenic than published values of analyses of metagabbro and charnockite from the Grenvillian-age Oaxaca Terrane. Sedimentary rocks (sandstones, siltstones, and marls) belonging to the Huetamo Sequence have 206Pb/204Pb values ranging between 18.630 to 18.998, close to the published data for the sediments from IPOD-DSDP Sites 487 and 488, Cocos Plate. Whole rock analyses of igneous rocks (granodiorite) collected from La Verde and El Malacate have 206Pb/204Pb ranging from 18.764 to 18.989, clustering between the fields represented by the sedimentary and the metamorphic rocks, suggesting assimilation of lead from these components. Ore samples from La Verde and Esmeralda have 206Pb/204Pb between 18.685 and 18.731 and plot within

  3. Tracing the metasomatic and magmatic evolution of continental mantle roots with Sr, Nd, Hf and and Pb isotopes: A case study of Middle Atlas (Morocco) peridotite xenoliths

    NASA Astrophysics Data System (ADS)

    Wittig, Nadine; Pearson, D. Graham; Duggen, Svend; Baker, Joel A.; Hoernle, Kaj

    2010-02-01

    We studied clinopyroxenes from spinel-facies peridotite xenoliths sampled by the Quaternary intra-plate volcanism of the Middle Atlas (Morocco) and present new trace element and Sr-Nd-Hf isotope data. However, we focus in particular on Pb isotope data and 238U/ 204Pb and 232Th/ 204Pb ratios of these clinopyroxenes. This data allows us to investigate: (a) the timing of metasomatic events, (b) the prevalence and persistence of elevated 238U/ 204Pb, 232Th/ 238U and 232Th/ 204Pb in continental mantle roots and (c) the 238U/ 204Pb and 232Th/ 204Pb composition of putative basaltic melts generated from such metasomatised sub-continental lithospheric mantle (SCLM). Incompatible trace element concentrations in these clinopyroxenes are elevated, marked by high-field strength element depletion and fractionated elemental ratios (e.g., U/Nb, Zr/Hf) most consistent with enrichment due to carbonatitic liquids. Sr, Nd and Hf isotopes have an affinity to HIMU. U, Th and Pb abundances in the clinopyroxenes generally exceed estimates of primitive mantle clinopyroxene. Pb isotope compositions of these clinopyroxenes are radiogenic and vary between 206Pb/ 204Pb = 19.93-20.25, 207Pb/ 204Pb = 15.63-15.66 and 208Pb/ 204Pb = 39.72-40.23. These Pb isotope systematics result in generally negative Δ7/4 but positive Δ8/4; setting these samples distinctly apart from typical HIMU. These Pb isotope compositions are also distinct from the associated host volcanic rocks. 238U/ 204Pb and 232Th/ 204Pb of these clinopyroxenes, which range from 26 to 81 and 136 to 399, respectively, are elevated and more extreme than estimates of MORB- and HIMU-source mantle. The Pb isotope evolution of the clinopyroxenes suggests that the metasomatic enrichment is younger than 200 Ma, which discounts the volcanic activity due to the opening of the Atlantic and the onset of the collision of the African and Eurasian plates as processes generating the lithophile element and isotope composition of this continental

  4. Strong Relationship between Hf-Nd-Pb Isotopes in Atlantic Sediments and the Lesser Antilles arc Composition

    NASA Astrophysics Data System (ADS)

    Carpentier, M.; Chauvel, C.; Mattielli, N.

    2006-12-01

    Geochemical variability of lavas from the Lesser Antilles arc is well established and is characterized by a chemical zoning from north to south along the arc. Lavas from the northern part of the arc have usually less radiogenic and less variable Sr and Pb isotopic compositions than those from the south. Possible explanations include a larger contribution from sediments in the source of the southern islands, and/or a north-south change in the chemical composition of the sediments that are subducted beneath the Lesser Antilles arc We conducted a geochemical study (Nd, Hf and Pb isotopic compositions) of Atlantic sediments coming from two different sites drilled during DSDP Leg 78 (site 543, 15.7N) and DSDP Leg 14 (site 144, 9.5N). At site 543, the sedimentary pile has epsilon Nd values between -14.6 and -11 and epsilon Hf between -10.6 and -1. 206Pb/204Pb ratios vary between 19.1 and 19.5. The sediment pile has an overall strong continental signature suggesting that their source is primarily detrital. This is in agreement with the interpretation of White et al. (1985) who suggested that the dominant source was the Archean Guiana Highland drained by the Orinoco River. Further south, at site 144, the succession consists of chalk ooze, marl and clays, and organic-rich black shales. Samples have epsilon Nd between -18.4 and -10 and epsilon Hf between -20.4 and -5.4 and the Pb isotopic compositions are extremely variable. Chalk ooze, marl and clay have 206Pb/204Pb ratios between 18.8 and 20.0, while the black shales have extremely radiogenic compositions with 206Pb/204Pb between 21.6 and 27.7. These compositions reflect the radioactive decay of authigenic uranium concentrated in organic- rich layers characterized by elevated 238U/204Pb ratios (100 up to 600). The isotopic compositions of sediments from both sites are largely influenced by continental input with Nd and Hf isotopes plotting in the continental domain of the "terrestrial array", but the southern site has more

  5. The Solar System primordial lead

    NASA Astrophysics Data System (ADS)

    Blichert-Toft, Janne; Zanda, Brigitte; Ebel, Denton S.; Albarède, Francis

    2010-11-01

    Knowledge of the primordial isotope composition of Pb in the Solar System is critical to the understanding of the early evolution of Earth and other planetary bodies. Here we present new Pb isotopic data on troilite (FeS) nodules from a number of different iron meteorites: Canyon Diablo, Mundrabilla, Nantan, Seeläsgen, Toluca (IAB-IIICD), Cape York (IIIA), Mt Edith (IIIB), and Seymchan (pallasite). Lead abundances and isotopic compositions typically vary from one troilite inclusion to another, even within the same meteorite. The most primitive Pb was found in three leach fractions of two exceptionally Pb-rich Nantan troilite nodules. Its 204Pb/ 206Pb is identical to that of Canyon Diablo troilite as measured by Tatsumoto et al. [M. Tatsumoto, R.J. Knight, C.J. Allègre, Time differences in the formation of meteorites as determined from the ratio of lead-207 to lead-206, Science 180(1973) 1279-1283]. However, our measurements of 207Pb/ 206Pb and 208Pb/ 206Pb are significantly higher than theirs, as well as other older literature data obtained by TIMS, while consistent with the recent data of Connelly et al. [J.N. Connelly, M. Bizzarro, K. Thrane, J.A. Baker, The Pb-Pb age of Angrite SAH99555 revisited, Geochim. Cosmochim. Acta 72(2008) 4813-4824], a result we ascribe to instrumental mass fractionation having biased the older data. Our current best estimate of the Solar System primordial Pb is that of Nantan troilite, which has the following isotopic composition: 204Pb/ 206Pb = 0.107459(16), 207Pb/ 206Pb = 1.10759(10), and 208Pb/ 206Pb = 3.17347(28). This is slightly less radiogenic than the intercept of the bundle of isotopic arrays formed in 207Pb/ 206Pb- 204Pb/ 206Pb space by our measurements of Canyon Diablo, Nantan, Seeläsgen, Cape York, and Mundrabilla, as well as literature data, which, in spite of rather large uncertainties, suggests a common primordial Pb component for all of these meteorites. The radiogenic Pb present in most of these irons is dominantly

  6. Pbsbnd Srsbnd Nd isotopic tracing of the influence of the Amazon River on the bottom sediments in the lower Tapajós River

    NASA Astrophysics Data System (ADS)

    Medeiros Filho, Lucio C.; Lafon, Jean-Michel; Souza Filho, Pedro Walfir M.

    2016-10-01

    The isotopic signatures of Pbsbnd Srsbnd Nd in recent bottom sediments were used to investigate the hydrodynamics of the lower stream of the Tapajós River and its interaction with the Amazon River. Samples from the Tapajós River have Pb isotopic ratios (19.67 < 206Pb/204Pb < 20.02; 15.87 < 207Pb/204Pb < 15.91) different from those of the bottom sediments found downstream in the Amazon River (18.84 < 206Pb/204Pb < 18.94; 207Pb/204Pb ≈ 15.67). In the confluence zone, the ratios have intermediate values (18.69 < 206Pb/204Pb < 19.53; 15.65 < 207Pb/204Pb < 15.83). The sediments in the Tapajós River have lower ɛNd(0) (-21 < ɛNd(0) < -19) values and more radiogenic isotopic Sr ratios (87Sr/86Sr ≈ 0.792) than those of the sediments from the Amazon River (ɛNd(0) ≈ -9 and 0.712 < 87Sr/86Sr < 0.716). The isotopic data suggest that the Amazon River influences the sediments in the Tapajós River, but this influence is restricted to the confluence zone. Additionally, the concentrations of major and trace elements and the mineralogy of the sediments are in agreement with the isotopic data. We conclude that the accumulation of muddy sediments in the lower stream of the Tapajós River is a result of the influence of the Amazon River, which retains this discharge from its affluent thus generating favorable conditions for depositing the finer sediments coming from the Tapajós River without any significant contribution of sediments from the Amazon River itself. The values of ɛNd(0) and TDM and of 87Sr/86Sr ratio of the Tapajós River bottom sediments indicate that the source of the sediments is essentially the erosion of the Paleoproterozoic felsic units from the Tapajós (2.03-1.88 Ga) and Juruena (1.82-1.54 Ga) geotectonic provinces.

  7. Isotopic evidence of pollutant lead sources in Northwestern France

    NASA Astrophysics Data System (ADS)

    Véron, Alain; Flament, Pascal; Bertho, Marie Laure; Alleman, Laurent; Flegal, Russell; Hamelin, Bruno

    Ratios of stable lead isotopes ( 204Pb, 206Pb, 207Pb, 208Pb) are used to characterize both spatial and temporal variations in anthropogenic emissions of industrial lead aerosols to the atmosphere of northwestern France. Differences in isotopic compositions of aerosols collected from a rural area (Wimereux) in the Nord-Pas de Calais region along the English Channel in 1982-1983 ( 206Pb/ 207Pb=1.108±0.005) and 1994 ( 206Pb/ 207Pb=1.148±0.003) are paralleled by similar variations in urban aerosols within France during the same period (e.g., 206Pb/ 207Pb=1.115±0.008 from 1981-1989 and 1.143±0.006 from 1992-1995). These results correlate well with recent findings in the Mediterranean basin (Alleman, 1997) where this radiogenicity increase is clearly associated with industrial sources other than leaded gasoline that has remained relatively constant during its phasing out ( 206Pb/ 207Pb=1.08-1.11). Here we used archived data, air mass trajectories and aerosol diameters combined with isotopic signatures to confirm this trend at a regional scale. Indeed, the main industrial signatures from lead smelting ( 206Pb/ 207Pb=1.133±0.001) and steel metallurgy ( 206Pb/ 207Pb=1.196±0.015) in northwestern France appear more radiogenic than that of leaded gasoline. The shift in isotopic compositions also conform with the systematic change in the mean size (diameter) of aerosols at Wimereux, which ranged from 0.30 to 0.61 μm in 1982-1984 and from 0.70 to 0.89 μm in 1994.

  8. Geochemistry and 207Pb/ 206Pb zircon ages of granitoids from the southern portion of the Tamboril-Santa Quitéria granitic-migmatitic complex, Ceará Central Domain, Borborema Province (NE Brazil)

    NASA Astrophysics Data System (ADS)

    de Araujo, Carlos E. G.; Costa, Felipe G.; Pinéo, Tercyo R. G.; Cavalcante, José C.; Moura, Candido A. V.

    2012-02-01

    The Tamboril-Santa Quitéria Complex is an important Neoproterozoic granitic-migmatitic unit from the Ceará Central Domain that developed from ca. 650 to 610 Ma. In general the granitoids range in composition from diorite to granite with predominance (up to 85%) of granitic to monzogranitic composition with biotite as the main mafic AFM phase. Geochemical and 207Pb/ 206Pb evaporation zircon geochronology studies were applied in a group of these abundant monzogranitic rocks from the region of Novo Oriente in the southern portion of the Ceará Central Domain. In this area the granitoids are weakly peraluminous biotite granitoids and deformed biotite granitoids of high-K calc-alkaline and ferroan composition, which we interpreted as primary magmas (segregated diatexites) derived from the partial melting of crustal material. The close temporal relation of this magmatism with local eclogitic and regional high temperature metamorphism in Ceará Central Domain point out to an orogenic setting, arguably emplaced during the collisional stage. Subordinate coeval juvenile mantle incursions are also present. This crustally derived magmatism is the primary product of the continental thickening that resulted from the collision between the rocks represented by the Amazonian-West African craton (São Luiz cratonic fragment) to the northwest and the Paleoproterozoic-Archean basement of the Borborema Province to the southeast along the Transbrasiliano tectonic corridor.

  9. Pb isotopic composition of Paleozoic sediments derived from the Appalachian orogen

    SciTech Connect

    Krogstad, E.J. . Dept. of Geology)

    1993-03-01

    Differences in [sup 207]Pb/[sup 204]Pb at restricted ranges of [sup 206]Pb/[sup 204]Pb are robust indicators of differences in the earliest history of crust or mantle reservoirs, surviving later changes in U/Pb that may be due to melting, metamorphism, or sedimentary reworking. Ayuso and Bevier (1991) have used the [sup 207]Pb/[sup 204]Pb differences between Late Paleozoic granites in the N. Appalachians to trace their sources in either Laurentian (Grenville) lithosphere, or docked (Avalonian) lithosphere. If the Pb isotopic composition of Avalonian lithosphere is unique to that source among all lithospheric reservoirs in the Appalachian orogeny, the sediments shed off the orogen should record the first appearance of rocks with this extraneous Pb isotopic composition as they become accreted. The high [sup 207]Pb/[sup 204]Pb at similar [sup 206]Pb/[sup 204]Pb that may be indicative of all outboard terranes occurs in sedimentary rocks younger than middle Ordovician in New York and Maine, and younger than Ordovician in Virginia. Older sediments (Hadrynian, Cambrian), as well as autochthonous basement and paraautochonous basement slices, have lower [sup 207]Pb/[sup 204]Pb at similar [sup 206]Pb/[sup 204]Pb. The low [sup 207]Pb/[sup 204]Pb at similar [sup 206]Pb/[sup 204]Pb shown by these rocks may be a locally diagnostic signature of Late Proterozoic Laurentian lithosphere. The high [sup 207]Pb/[sup 204]Pb at similar [sup 206]Pb/[sup 204]Pb may be a locally diagnostic signature of Late Proterozoic accreted terranes. Rocks with accreted terrane Pb isotopic composition became dominant in the provenance of sediments along the strike of the Appalachian orogen by middle Ordovician time.

  10. Changes in the lead isotopic composition of blood, diet and air in Australia over a decade: Globalization and implications for future isotopic studies

    SciTech Connect

    Gulson, Brian . E-mail: bgulson@gse.mq.edu.au; Mizon, Karen; Korsch, Michael; Taylor, Alan

    2006-01-15

    Source apportionment in biological or environmental samples using the lead isotope method, where there are diverse sources of lead, relies on a significant difference between the isotopic composition in the target media and the sources. Because of the unique isotopic composition of Australian lead, source apportionment has been relatively successful in the past. Over the period of a decade, the {sup 206}Pb/{sup 204}Pb ratio for Australian (mainly female) adults has shown an increase from a geometric mean of 16.8-17.3. Associated with this increase, there has been a decrease in mean blood lead concentration from 4.7 to 2.3 {mu}g/dL, or about 5% per year, similar to that observed in other countries. Lead in air, which up until 2000 was derived largely from the continued use of leaded gasoline, showed an overall increase in the {sup 206}Pb/{sup 204}Pb ratio during 1993-2000 from 16.5 to 17.2. Since 1998 the levels of lead in air were less than 0.2 {mu}g/m{sup 3} and would contribute negligibly to blood lead. Over the 10-year period, the {sup 206}Pb/{sup 204}Pb ratio in diet, based mainly on quarterly 6-day duplicate diets, increased from 16.9 to 18.3. The lead concentration in diet showed a small decrease from 8.7 to 6.4 {mu}g Pb/kg although the daily intake increased markedly from 7.4 to 13.9 {mu}g Pb/day during the latter part of the decade probably reflecting differences in demographics. The changes in blood lead from sources such as lead in bone or soil or dust is not dominant because of the low {sup 206}Pb/{sup 204}Pb ratios in these media. Unless there are other sources not identified and analysed for these adults, it would appear that in spite of our earlier conclusions to the contrary, diet does make an overall contribution to blood lead, and this is certainly the case for specific individuals. Certain population groups from south Asia, south-east Asia, the Middle East and Europe (e.g. UK) are unsuitable for some studies as their isotopic ratios in blood are

  11. Isotopic source signatures for atmospheric lead: the Southern Hemisphere

    NASA Astrophysics Data System (ADS)

    Bollhöfer, A.; Rosman, K. J. R.

    2000-10-01

    Aerosols collected between 1994 and 1999 at more than 70 different sites affecting the Southern Hemisphere have been measured for their 206Pb/ 207Pb, 208Pb/ 207Pb and 206Pb/ 204Pb ratios and Pb concentrations. Lower ratios are found at the southern tips of Africa, Australia and South America probably due to the supply of alkyllead from a common supplier such as Associated Octel. The ratios increase in a northerly direction probably due to a changing market share in alkyllead or an increasing industrial Pb contribution. The geographical variations in isotopic signatures made it possible to broadly characterize the different regions that influence the Southern Hemisphere. Brazil and Argentina exhibited 206Pb/ 207Pb, 208Pb/ 207Pb and 206Pb/ 204Pb ratios in aerosols of 1.141-1.184, 2.416-2.442 and 17.77-18.57, respectively. Mexican aerosols had values of 1.188-1.197, 2.452-2.463 and 18.46-18.73. Aerosols sampled in Chile had low ratios in the South of 1.063-1.094, 2.337-2.373 and 16.46-17.13 which increased in a northerly direction. Emissions from South Africa were characterized by ratios 1.067-1.090, 2.340-2.358 and 16.53-16.99. In 1994-1995 Australia and New Zealand had ratios of 1.060-1.193, 2.324-2.445 and 16.08-18.54. In 1997 however, the range was narrower: 1.072-1.112, 2.342-2.398 and 16.55-17.36, respectively. These isotopic signatures are potentially useful for tracing sources of pollution and the movement of air-masses on a global scale.

  12. Uranium-lead isotope systematics of Mars inferred from the basaltic shergottite QUE 94201

    SciTech Connect

    Gaffney, A M; Borg, L E; Connelly, J N

    2006-12-22

    Uranium-lead ratios (commonly represented as {sup 238}U/{sup 204}Pb = {mu}) calculated for the sources of martian basalts preserve a record of petrogenetic processes that operated during early planetary differentiation and formation of martian geochemical reservoirs. To better define the range of {mu} values represented by the source regions of martian basalts, we completed U-Pb elemental and isotopic analyses on whole rock, mineral and leachate fractions from the martian meteorite Queen Alexandra Range 94201 (QUE 94201). The whole rock and silicate mineral fractions have unradiogenic Pb isotopic compositions that define a narrow range ({sup 206}Pb/{sup 204}Pb = 11.16-11.61). In contrast, the Pb isotopic compositions of weak HCl leachates are more variable and radiogenic. The intersection of the QUE 94201 data array with terrestrial Pb in {sup 206}Pb/{sup 204}Pb-{sup 207}Pb/{sup 204}Pb-{sup 208}Pb/{sup 204}Pb compositional space is consistent with varying amounts of terrestrial contamination in these fractions. We calculate that only 1-7% contamination is present in the purified silicate mineral and whole rock fractions, whereas the HCl leachates contain up to 86% terrestrial contamination. Despite the contamination, we are able to use the U-Pb data to determine the initial {sup 206}Pb/{sup 204}Pb of QUE 94201 (11.086 {+-} 0.008) and calculate the {mu} value of the QUE 94201 mantle source to be 1.823 {+-} 0.008. This is the lowest {mu} value calculated for any martian basalt source, and, when compared to the highest values determined for martian basalt sources, indicates that {mu} values in martian source reservoirs vary by at least 100%. The range of source {mu} values further indicates that the {mu} value of bulk silicate Mars is approximately three. The amount of variation in the {mu} values of the mantle sources ({mu} {approx} 2-4) is greater than can be explained by igneous processes involving silicate phases alone. We suggest the possibility that a small

  13. Pb-concentrations and Pb-isotope ratios in soils collected along an east-west transect across the United States

    USGS Publications Warehouse

    Reimann, Clemens; Smith, David B.; Woodruff, Laurel G.; Flem, Belinda

    2011-01-01

    Analytical results for Pb-concentrations and isotopic ratios from ca. 150 samples of soil A horizon and ca. 145 samples of soil C horizon collected along a 4000-km east–west transect across the USA are presented. Lead concentrations along the transect show: (1) generally higher values in the soil A-horizon than the C-horizon (median 21 vs. 16.5 mg/kg), (2) an increase in the median value of the soil A-horizon for central to eastern USA (Missouri to Maryland) when compared to the western USA (California to Kansas) (median 26 vs. 20 mg/kg) and (3) a higher A/C ratio for the central to eastern USA (1.35 vs. 1.14). Lead isotopes show a distinct trend across the USA, with the highest 206Pb/207Pb ratios occurring in the centre (Missouri, median A-horizon: 1.245; C-horizon: 1.251) and the lowest at both coasts (e.g., California, median A-horizon: 1.195; C-horizon: 1.216). The soil C-horizon samples show generally higher 206Pb/207Pb ratios than the A-horizon (median C-horizon: 1.224; A-horizon: 1.219). The 206Pb/207Pb-isotope ratios in the soil A horizon show a correlation with the total feldspar content for the same 2500-km portion of the transect from east-central Colorado to the Atlantic coast that shows steadily increasing precipitation. No such correlation exists in the soil C horizon. The data demonstrate the importance of climate and weathering on both Pb-concentration and 206Pb/207Pb-isotope ratios in soil samples and natural shifts thereof in the soil profile during soil-forming processes.

  14. Character of the pre-Mesozoic basement along the edge of the western US craton: Pb isotopic evidence from Mesozoic plutonism

    SciTech Connect

    Wooden, J.L.; Kistler, R.W.; Robinson, A.; Tosdal, R.M. ); Wright, J.E. . Dept. of Geology and Geophysics)

    1993-04-01

    The pre-Mesozoic cratonic crust of the western US was a composite of provinces composed mostly of Archean and Early Proterozoic rocks that had been truncated by Late Proterozoic rifting and had some new Paleozoic crust added along the western edge. Mesozoic and younger geologic events greatly obscured this pre-Mesozoic basement along the craton edge. However, the Pb isotopic signatures of Mesozoic plutons provide significant clues to the character of the crust in which they formed or were emplaced because of a strong contrast in Pb concentration between low-Pb, mantle-derived melts and Pb-rich crust. Thus, magmas whether derived from the crust or the mantle with subsequent crustal interaction, will likely have Pb isotopic compositions that reflect those of the crust. In the western US the Pb isotopic compositions of Mesozoic plutonic rocks have strong regional characteristics. Within the Early Proterozoic Mojave crustal province, Mesozoic plutonic rocks have a large range of 206Pb/204Pb ratios that plot above the crustal average, relatively high 207Pb/204Pb ratios that suggest an Archean contribution, and Pb and Sr isotopic compositions that are not correlated and that do not distinguish age groups. At the southern and western edge of this province where some 1.1 Ga rocks are exposed, 208Pb/204Pb ratios lie along the average crust model curve. These data suggest that any individual pluton provides a composite Pb isotopic composition for a discrete vertical section of the crust. Pb isotopic compositions of plutons in the Sierra Nevada and Great Basin are very different from those described above with 206Pb/204Pb ratios starting at 18.6, well-correlated Pb isotopic trends starting below the crustal model but extending to values that require input from the very radiogenic Wyoming province Archean crust, and good correlations between Pb and (1) Sr isotopic compositions and (2) W-E geographic position.

  15. The Rurutu Hotspot: Isotopic and Trace Element Evidence of HIMU Hotspot Volcanism in the Tuvalu Islands

    NASA Astrophysics Data System (ADS)

    Finlayson, V.; Konter, J. G.; Konrad, K.; Koppers, A. A. P.; Jackson, M. G.

    2014-12-01

    Current Pacific absolute plate motion (APM) models include 2 major, long-lived hotspot tracks: the ~85 Ma Hawaiian-Emperor and the ~76 Ma Louisville tracks. Prior to ~50 Ma, these two hotspot tracks show significant inter-hotspot drift, mainly due to large southern motion of the Hawaiian hotspot [1,2]. A third track would allow for a more robust evaluation of the relationship between APM models and inter-hotspot drift. We present trace element and Pb isotope evidence for a potential third long-lived Pacific hotspot trail—the Rurutu hotspot—anchored in the Cook-Austral Islands. Based on high 206Pb/204Pb ratios, 70-55 Ma volcanism in the Gilbert Ridge has been linked to the Rurutu hotspot [3]. The Gilbert Ridge may continue south into the Tuvalu Islands, where APM models predict that the Rurutu hotspot track captures the change in Pacific plate motion around 50 Ma at the intersection of Tuvalu and Samoa. Sampling of the deep submarine flanks of atolls and seamounts in Tuvalu and westernmost Samoa took place during the 2013 RR1310 (R/V Roger Revelle) expedition. We present new Pb isotope and HFSE trace element data on 28 samples that support a Rurutu origin for Tuvalu volcanism and confirm HIMU signatures previously observed in 5 Tuvalu samples (206Pb/204Pb >20.1, several >21.0; 87Sr/86Sr < 0.705). Statistical tests indicate that Tuvalu HFSE element ratios show similarities with Cook-Austral HIMU and differences with Samoa EMII volcanism. Low Hf/Nb ratios are often a predictor of HIMU samples (206Pb/204Pb > 20.8). Moderately HIMU compositions (206Pb/204Pb = 20.0) correspond to slightly higher Hf/Nb. In an effort to test if compositional agreement with the Cook-Australs is reflected in an age progression, 40Ar/39Ar ages will be presented by Konrad et al. (this volume). [1] Tarduno et al., (2003) DOI:10.1126/science.1086442 [2] Koppers et al., (2012) DOI: 10.1038/ngeo1638 [3] Konter et al., (2008) DOI: 10.1016/j.epsl.2008.08.023

  16. Temporal evolution of lead isotope ratios in sediments of the Central Portuguese Margin: a fingerprint of human activities.

    PubMed

    Mil-Homens, Mário; Caetano, Miguel; Costa, Ana M; Lebreiro, Susana; Richter, Thomas; de Stigter, Henko; Trancoso, Maria A; Brito, Pedro

    2013-09-15

    Stable Pb isotope ratios ((206)Pb/(207)Pb, (208)Pb/(206)Pb), (210)Pb, Pb, Al, Ca, Fe, Mn and Si concentrations were measured in 7 sediment cores from the west coast of the Iberian Peninsula to assess the Pb contamination throughout the last 200 years. Independently of their locations, all cores are characterized by increasing Pb/Al rends not related to grain-size changes. Conversely, decreasing trends of (206)Pb/(207)Pb were found towards the present. This tendency suggest a change in Pb sources reflecting an increased proportion derived from anthropogenic activities. The highest anthropogenic Pb inventories for sediments younger than 1950s were found in the two shallowest cores of Cascais and Lisboa submarine canyons, reflecting the proximity of the Tagus estuary. Lead isotope signatures also help demonstrate that sediments contaminated with Pb are not constrained to estuarine-coastal areas and upper parts of submarine canyons, but are also to transferred to a lesser extent to deeper parts of the Portuguese Margin.

  17. Evaporation residue cross-section in the decay of 254No* formed in 206Pb + 48Ca and its isotopic dependence using other Pb targets within the dynamical cluster-decay model

    NASA Astrophysics Data System (ADS)

    Niyti; Gupta, Raj K.; Hess, Peter Otto

    2015-06-01

    The dynamical cluster-decay model (DCM), with deformation and orientation effects included, is used to calculate the fusion evaporation residue cross-sections σxn for x = 1, 2, 3 and 4 neutrons emission in a fusion reaction 206Pb + 48Ca → 254No* at various 48Ca-beam energies Elab = 212.7- 242.5 MeV (equivalently, E* = 19.8- 43.9 MeV). Considering the higher multipole deformations up to hexadecapole deformation β4i and the sticking moment-of-inertia IS, the DCM with pocket formula for nuclear proximity potential is shown to give a good description of the measured individual light-particle (here neutrons) decay channels for configurations of "hot, compact" orientations θci, within one parameter fitting of the neck-length ΔR. A check on some of the variables involved in DCM shows that (i) spherical configurations give nearly the same result as above for deformed and oriented ones; (ii) the non-sticking moment-of-inertia INS gives unphysical results; and (iii) configurations of "cold, elongated" orientations do not fit the data at all. Furthermore, for the four different isotopes of 204,206,207,208Pb-based reactions, the dependence of, say, the 2n-emission yield σ2n on the isotopic composition of the compound nucleus is also studied within the DCM for "hot" fusion process. Of all the four Pb-isotopes and three excitation energies E* considered, at each E*, the ΔR is largest for compound system 256No*, followed by 255No*, 254No* and smallest for 252No*, which means to suggest that the neutrons emission occur earliest for 256No*, then for 255No*, 254No* and finally by 252No*, in complete agreement with experimental data according to which compound system 256No* has the highest cross-section and 252No* the lowest with 255No* and 254No* lying in between. This result is related to the double magicity of both the target (208Pb) and projectile (48Ca) nuclei, as well as to the experimentally known result of projectile with a larger number of neutrons (here the target

  18. Comment on "207Pb-206Pb single-zircon evaporation ages of some granitoid rocks reveal continent-oceanic island arc collision during the Cretaceous geodynamic evolution of the Central Anatolian crust, Turkey" - Boztug, D., Tichomirowa, M. & Bombach, K., 2007, JAES 31, 71-86

    NASA Astrophysics Data System (ADS)

    Göncüoglu, M. Cemal

    A continent-oceanic island arc collision model was proposed as a new geodynamic scenario for the evolution of the Cretaceous Central Anatolian granitoids in the Central Anatolian crystalline complex (CACC) by Boztug et al. (2007b) [Boztug, D., Tichomirowa, M., Bombach, K., 2007b. 207Pb-206Pb single-zircon evaporation ages of some granitoid rocks reveal continent-oceanic island arc collision during the Cretaceous geodynamic evolution of the central Anatolian crust, Turkey. Journal of Asian Earth Sciences 31, 71-86]. The key aspects of this model include an intra-oceanic subduction in the Neotethyan Izmir-Ankara Ocean, formation of an island arc and its subsequent collision with the northern margin of the Tauride-Anatolide Platform. The identical scenario was initially proposed by Göncüoglu et al. (1992) [Göncüoglu, M.C., Erler, A., Toprak, V., Yalınız, K., Olgun, E., Rojay, B., 1992. Geology of the western Central Anatolian Massif, Part II: Central Areas. TPAO Report No: 3155, 76 p] . Moreover, the weighted mean values of the reported 207Pb-206Pb single-zircon evaporation ages by Boztug et al. (2007b) [Boztug, D., Tichomirowa, M., Bombach, K., 2007b. 207Pb-206Pb single-zircon evaporation ages of some granitoid rocks reveal continent-oceanic island arc collision during the Cretaceous geodynamic evolution of the central Anatolian crust: Turkey. Journal of Asian Earth Sciences 31, 71-86] from A-type granitoids in the CACC seem to be miscalculated and contrast with the field data.

  19. Ratio

    NASA Astrophysics Data System (ADS)

    Webster, Nathan A. S.; Pownceby, Mark I.; Madsen, Ian C.; Studer, Andrew J.; Manuel, James R.; Kimpton, Justin A.

    2014-12-01

    Effects of basicity, B (CaO:SiO2 ratio) on the thermal range, concentration, and formation mechanisms of silico-ferrite of calcium and aluminum (SFCA) and SFCA-I iron ore sinter bonding phases have been investigated using an in situ synchrotron X-ray diffraction-based methodology with subsequent Rietveld refinement-based quantitative phase analysis. SFCA and SFCA-I phases are the key bonding materials in iron ore sinter, and improved understanding of the effects of processing parameters such as basicity on their formation and decomposition may assist in improving efficiency of industrial iron ore sintering operations. Increasing basicity significantly increased the thermal range of SFCA-I, from 1363 K to 1533 K (1090 °C to 1260 °C) for a mixture with B = 2.48, to ~1339 K to 1535 K (1066 °C to 1262 °C) for a mixture with B = 3.96, and to ~1323 K to 1593 K (1050 °C to 1320 °C) at B = 4.94. Increasing basicity also increased the amount of SFCA-I formed, from 18 wt pct for the mixture with B = 2.48 to 25 wt pct for the B = 4.94 mixture. Higher basicity of the starting sinter mixture will, therefore, increase the amount of SFCA-I, considered to be more desirable of the two phases. Basicity did not appear to significantly influence the formation mechanism of SFCA-I. It did, however, affect the formation mechanism of SFCA, with the decomposition of SFCA-I coinciding with the formation of a significant amount of additional SFCA in the B = 2.48 and 3.96 mixtures but only a minor amount in the highest basicity mixture. In situ neutron diffraction enabled characterization of the behavior of magnetite after melting of SFCA produced a magnetite plus melt phase assemblage.

  20. From olivine nephelinite, basanite and basalt to peralkaline trachyphonolite and comendite in the Ankaratra volcanic complex, Madagascar: 40Ar/39Ar ages, phase compositions and bulk-rock geochemical and isotopic evolution

    NASA Astrophysics Data System (ADS)

    Cucciniello, Ciro; Melluso, Leone; le Roex, Anton P.; Jourdan, Fred; Morra, Vincenzo; de'Gennaro, Roberto; Grifa, Celestino

    2017-03-01

    The Ankaratra volcanic field covers an area of 3800 km2 in central Madagascar and comprises of lava flows, lava domes, scoria cones, tuff rings and maars emplaced at different ages (Miocene to Recent). The volcanic products include ultramafic-mafic (olivine-leucite nephelinite, basanite, alkali basalt, hawaiite and tholeiitic basalt), intermediate (mugearite and benmoreite) and felsic rocks (trachyphonolite, quartz trachyte and rhyolite), the latter often peralkaline. The 40Ar/39Ar determinations for mafic lavas yield ages of 17.45 ± 0.12 Ma, 16.63 ± 0.08 Ma and 8.62 ± 0.09 Ma, indicating a prolonged magmatic activity. The mineralogical and geochemical variations suggest that the magmatic evolution of the alkali basalt-hawaiite-mugearite-benmoreite-trachyte series can be accounted for by removal of olivine, feldspars, clinopyroxene, Fe-Ti oxides and accessory phases, producing residual trachytic and trachyphonolitic compositions mineralogically very similar to those of other volcanic areas and tectonic settings. The Ankaratra olivine leucite nephelinites, basanites and tholeiitic basalts do not seem to be associated with significant amounts of evolved comagmatic rocks. The 87Sr/86Sr (0.70504-0.71012), 143Nd/144Nd (0.51259-0.51244) and 206Pb/204Pb (17.705-18.563) isotopic ratios of trachytes and comendite are consistent with open-system processes. However, other trachyphonolites have 143Nd/144Nd (0.51280), 206Pb/204Pb (18.648), 207Pb/204Pb (15.582) and 208Pb/204Pb (38.795) similar to those of mafic rocks, suggesting differentiation processes without appreciable interaction with crustal materials. The Ankaratra volcanism is to be directly linked to a broadly E-W-trending intracontinental extension. A large-scale thermal anomaly, associated with an anomalously hot source region, is not required to explain the Cenozoic magmatism of Madagascar.

  1. Dust Deposition and Migration of the ITCZ through the Last Glacial Cycle in the Central Equatorial Pacific (Line Islands).

    NASA Astrophysics Data System (ADS)

    Reimi Sipala, M. A.; Marcantonio, F.

    2014-12-01

    Atmospheric dust can be used to record climate change in addition to itself playing a role in several key climate processes, such as affecting Earth's albedo, fomenting rain coalescence, encouraging biological productivity, and enhancing carbon export though particle sinks. Using deep sea sediments, it is possible to quantify and locate the sources and sinks of atmospheric dust. A key area of research is the shift in the inter-tropical converge zone (ITCZ), a thermally influenced area that shifts according to the northern and southern hemisphere temperature gradient. This ongoing project focuses on the changes of the ITCZ over the Central Equatorial Pacific (CEP) over the past ~25000 years. The research focuses on two cores taken from the Line Islands Ridge at 0° 29' N (ML1208-18GC), and 4° 41' N (ML1208-31BB). The main aim is to quantify the magnitude and provenance of windblown dust deposited in the CEP, and to address questions regarding the nature of the variations of dust through ice-age climate transitions. Radiogenic isotopes (Sr, Nd, Pb) have been successfully used to distinguish between different potential dust sources in the aluminosilicates fractions of Pacific Sediments. Our preliminary Pb isotope ratios suggest that, for modern deposition, the northern core's (31BB) detrital sediment fraction is likely sourced from Asian Loess (average ratios are 206Pb/204Pb = 18.88, 207Pb/204Pb = 15.69, 208Pb/204Pb = 39.06). The equatorial core's (18GC) detrital fraction has a less radiogenic Pb signature, which is consistent with South American dust sourcing (206Pb/204Pb = 18.62, 207Pb/204Pb = 15.63, 208Pb/204Pb = 38.62). This is indicative of a strong modern ITCZ that acts as an effective barrier for inter-hemispheric dust transport. Prior to Holocene time, the changes in Pb isotope ratios in both cores appear to be in anti-phase; the northern core becomes less radiogenic up to the LGM, while the southern core becomes more radiogenic. This is potentially due to a

  2. Lead Isotopic Compositions of the Endeavour Sulfides, Juan de Fuca Ridge

    NASA Astrophysics Data System (ADS)

    Labonte, F.; Hannington, M. D.; Cousens, B. L.; Blenkinsop, J.; Gill, J. B.; Kelley, D. S.; Lilley, M. D.; Delaney, J. R.

    2006-12-01

    32 sulfide samples from the main structures of the Endeavour vent field, Juan de Fuca Ridge, were analyzed for their Pb isotope composition. The samples were collected from 6 main vent fields between 1985 and 2005 and encompass a strike length of more than 15 km along the ridge crest. The sulfides are typical of black smoker deposits on sediment-starved mid-ocean ridges. Pb isotope compositions of the massive sulfides within the six hydrothermal fields vary within narrow ranges, with 206Pb/204Pb = 18.58 18.75, 207Pb/204Pb = 15.45 15.53 and 208Pb/204Pb = 37.84 38.10. A geographic trend is observed, with the lower Pb ratios restricted mostly to the northern part of the segment (Salty Dawg, Sasquatch and High Rise fields), and the higher Pb ratios restricted mostly to the southern part of the segment (Main Endeavour, Clam Bed and Mothra fields). Variations within individual fields are much smaller than those between fields, and variation within individual sulfide structures is within the uncertainty of the measurements. Therefore, it is unlikely that the ranges of Pb isotope compositions along the length of the segment reflect remobilization, replacement, and recrystallization of sulfides, as suggested for the observed Pb isotope variability in some large seafloor sulfide deposits. Instead, the differences in isotopic compositions from north to south are interpreted to reflect differences in the source rocks exposed to hydrothermal circulation of fluids below the seafloor. Possible sources of the somewhat more radiogenic Pb may be small amounts of buried sediment, either from turbidites or from hemipelagic sediment. This possibility is supported by high concentrations of CH4 and NHC4 found in the high-temperature vent fluids at the Main Endeavour Field, which are interpreted to reflect subseafloor interaction between hydrothermal fluids and organic material in buried sediments. However, the majority of the samples fall below and are approximately parallel to the

  3. Inter-Tropical Convergence Zone Shifts During the Last Glacial Cycle Near the Line Islands Ridge.

    NASA Astrophysics Data System (ADS)

    Reimi Sipala, M. A.; Marcantonio, F.

    2015-12-01

    This research focuses on the shift in the inter-tropical convergence zone (ITCZ) during the last glacial cycle. Deep sea sediments from the Central Equatorial Pacific (CEP) are used to quantify and isolate the sources and sinks of atmospheric dust. Dust records and influences climate affecting a wide range of process from Earth's Albedo to carbon export. Our aim is to determine the provenance of windblown dust deposited in the CEP near the Line Islands Ridge using radiogenic Nd and Pb isotopes, and to infer the location of the ITCZ and the changes of atmospheric transport through ice-age climate transitions. We focus on three cores from the CEP, along a meridional transect at approximately 160° W --- 0° 28' N (ML1208-17PC), 4° 41' N (ML1208-31BB), and 7 ° 2'N (ML1208-31BB). Radiogenic isotopes (Sr, Nd, Pb) have been successfully used to distinguish between different potential dust sources in the aluminosilicates fractions of Pacific Sediments. Our preliminary data suggest that the equatorial core (17PC) predominantly receives its dust from South America and South American volcanics South America (206Pb/204Pb = 18.62, 207Pb/204Pb = 15.63, 208Pb/204Pb = 38.62; ; ɛNd = ~ -5). The middle core, which more closely reflects the modern position of the ITCZ, has varied dust provenance through time, at times consistent with Asian Loess (average ratios are 206Pb/204Pb = 18.88, 207Pb/204Pb = 15.69, 208Pb/204Pb = 39.06; ɛNd = ~ -7) and Asian Volcanics (ɛNd = ~-1) suggesting a shift in the ITCZ south of 4N before the LGM. Our results for the most northern core are forthcoming. Prior to Holocene time, the changes in Pb isotope ratios in both cores appear to be in anti-phase; the northern core becomes less radiogenic up to the LGM, while the southern core becomes more radiogenic. This is potentially due to a weakening of the ITCZ during glacial times. A secondary aim of this work is to determine if the ITCZ migrated further south than core 17PC during Heinrich stage II.

  4. Metals and isotopes in Juan de Fuca Ridge hydrothermal fluids and their associated solid materials

    SciTech Connect

    Hinkley, T.K.; Tatsumoto, M.

    1987-10-10

    The /sup 87/Sr//sup 86/Sr ratio of the hydrothermal solution (HTS) (0.7034) is larger than that of basalt (0.7025) at the southern vent field of the Juan de Fuca Ridge (SJFR). Both the Sr isotopic ratio for HTS and the water/rock interaction ratio lie between those at two sites farther south on the East Pacific Rise, 13 /sup 0/N and 21 /sup 0/N. These parameters may be closely related to subsurface temperatures and rates of magma ascent and to extent of faulting and surface areas of the frameworks of the hydrothermal systems. For these three Pacific Ocean sites there is no steady geographical progression of these measured parameters, nor of reported spreading rate, with increasing latitude northward. Pb and Nd isotopic measurements are uniform for all samples from the SJFR, ranging only from 18.43 to 18.58 for /sup 206/Pb//sup 204/Pb (fluids and associated solids) and centering near 0.5131 for /sup 143/Nd//sup 144/Nd (only fluids measured). Values for basalts and sulfides from the site have similar values. Relatively high /sup 206/Pb//sup 204/Pb values at the SJFR suggest the potential for the existence of an anomalous radiogenic heat source in the underlying mantle material.

  5. Trace-element and Sr, Nd, Pb, and O isotopic composition of Pliocene and Quaternary alkali basalts of the Patagonian Plateau lavas of southernmost South America

    USGS Publications Warehouse

    Stern, C.R.; Frey, F.A.; Futa, K.; Zartman, R.E.; Peng, Z.; Kurtis, Kyser T.

    1990-01-01

    The Pliocene and Quaternary Patagonian alkali basalts of southernmost South America can be divided into two groups. The "cratonic" basalts erupted in areas of Cenozoic plateau volcanism and continental sedimentation and show considerable variation in 87Sr/86Sr (0.70316 to 0.70512), 143Nd/144Nd (e{open}Nd) and 206Pb/204Pb, 207Pb/204Pb, and 208Pb/204Pb ratios (18.26 to 19.38, 15.53 to 15.68, and 38.30 to 39.23, respectively). These isotopic values are within the range of oceanic island basalts, as are the Ba/La, Ba/Nb, La/Nb, K/Rb, and Cs/Rb ratios of the "cratonic" basalts. In contrast, the "transitional" basalts, erupted along the western edge of the outcrop belt of the Pliocene and Quaternary plateau lavas in areas that were the locus of earlier Cenozoic Andean orogenic arc colcanism, have a much more restricted range of isotopic composition which can be approximated by 87Sr/86Sr=0.7039??0.0004, e{open}Nd, 206Pb/204Pb=18.60??0.08, 207Pb/204Pb=15.60??0.01, and 208Pb/204Pb=38.50??0.10. These isotopic values are similar to those of Andean orogenic are basalts and, compared to the "cratonic" basalts, are displaced to higher 87Sr/86Sr at a given 143Nd/144Nd and to higher 207Pb/204Pb at a given 208Pb/204Pb. The "transitional" basalts also have Ba/La, Ba/Nb, La/Nb, and Cs/Rb ratios higher than the "cratonic" and oceanic island basalts, although not as high as Andean orogenic are basalts. In contrast to the radiogenic isotopes, ??18O values for both groups of the Patagonian alkali basalts are indistinguishable and are more restricted than the range reported for Andean orogenic are basalts. Whole rock ??18O values calculated from mineral separates for both groups range from 5.3 to 6.5, while measured whole rock ??18O values range from 5.1 to 7.8. The trace element and isotopic data suggest that decreasing degrees of partial melting in association with lessened significance of subducted slabderived components are fundamental factors in the west to east transition from arc

  6. Geochemistry, Sr-Nd-Pb isotopes and geochronology of amphibole- and mica-bearing lamprophyres in northwestern Iran: Implications for mantle wedge heterogeneity in a palaeo-subduction zone

    NASA Astrophysics Data System (ADS)

    Aghazadeh, Mehraj; Prelević, Dejan; Badrzadeh, Zahra; Braschi, Eleonora; van den Bogaard, Paul; Conticelli, Sandro

    2015-02-01

    Lamprophyres of different age showing distinctive mineralogy, geochemistry and isotopic ratios are exposed in northwestern Iran. They can be divided into Late Cretaceous sannaite, Late Oligocene-Early Miocene camptonite (amphibole-bearing) and Late Miocene minette (mica-bearing) and spessartite (amphibole-bearing) lamprophyres. Sannaites have high-Ti amphibole along with high-Ti and Al clinopyroxene, and they are characterised by homogeneous enrichment in incompatible trace elements with troughs at Pb. Spessartites have hornblende and low-Al and Ti clinopyroxene, and they are characterised by enriched incompatible trace element pattern with depletions of Nb, Ta, Pb, and Ti with respect to large ion lithophile elements. Minettes have high-Ti and Al brown mica and low-Al and Ti clinopyroxene, and similar to spessartite, are characterised by fractionation of high field strength elements with respect to large ion lithophile elements, with troughs at Nb, Ta, and Ti and a peak at Pb. Minettes show high initial 87Sr/86Sr values up to 0.70760 and low initial 143Nd/144Nd down to 0.512463 with a negative correlation, consistent with the trace element distribution related with an enriched mantle source modified after sediment recycling during subduction and continental collision. Cretaceous sannaites and Early Miocene spessartites show low initial 87Sr/86Sr approaching 0.70447 and high 143Nd/144Nd values up to 0.512667, which are consistent with a depleted within-plate mantle source. Minette and spessartite lamprophyres show high initial 206Pb/204Pb, 207Pb/204Pb, and 208Pb/204Pb values, whereas sannaites have lower, but variable, initial 206Pb/204Pb, 207Pb/204Pb, and 208Pb/204Pb values with respect to those of calc-alkaline lamprophyres. Minettes originated by partial melting of a metasomatised lithospheric mantle following siliciclastic sediment recycling by subduction. In contrast, sannaites were generated from the partial melting of a similar lithospheric mantle that was

  7. Radiogenic Isotopes As Paleoceanographic Tracers in Deep-Sea Corals: Advances in TIMS Measurements of Pb Isotopes and Application to Southern Ocean Corals

    NASA Astrophysics Data System (ADS)

    Wilson, D. J.; van de Flierdt, T.; Bridgestock, L. J.; Paul, M.; Rehkamper, M.; Robinson, L. F.; Adkins, J. F.

    2014-12-01

    Deep-sea corals have emerged as a valuable archive of deep ocean paleoceanographic change, with uranium-series dating providing absolute ages and the potential for centennial resolution. In combination with measurements of radiocarbon, neodymium isotopes and clumped isotopes, this archive has recently been exploited to reconstruct changes in ventilation, water mass sourcing and temperature in relation to millennial climate change. Lead (Pb) isotopes in both corals and seawater have also been used to track anthropogenic inputs through space and time and to trace transport pathways within the oceans. Better understanding of the oceanic Pb cycle is emerging from the GEOTRACES programme. However, while Pb isotopes have been widely used in environmental studies, their full potential as a (pre-anthropogenic) paleoceanographic tracer remains to be exploited. In deep-sea corals, challenges exist from low Pb concentrations in aragonite in comparison to secondary coatings, the potential for contamination, and the efficient elemental separation required for measurement by thermal ionisation mass spectrometry (TIMS). Here we discuss progress in measuring Pb isotopes in coral aragonite using a 207Pb-204Pb double spike on a ThermoFinnigan Triton TIMS. For a 2 ng NIST-981 Pb standard, the long term reproducibility (using 1011 Ω resistors) is ~1000 ppm (2 s.d.) on 206Pb/204Pb, 207Pb/204Pb and 208Pb/204Pb ratios. We now show that using a new 1012 Ω resistor to measure the small 204Pb beam improves the internal precision on these ratios from ~500 ppm (2 s.e.) to ~250 ppm (2 s.e.) and we envisage a potential improvement in the long term reproducibility as a consequence. We further assess the internal precision and external reproducibility of our method using a BCR-2 rock standard and an in-house coral standard. Preliminary evidence on the application of this method to natural samples is derived from cleaning experiments and replication tests on deep-sea corals from the Southern

  8. Isotopic identification of natural vs. anthropogenic lead sources in marine sediments from the inner Ría de Vigo (NW Spain).

    PubMed

    Álvarez-Iglesias, P; Rubio, B; Millos, J

    2012-10-15

    San Simón Bay, the inner part of the Ría de Vigo (NW Spain), an area previously identified as highly polluted by Pb, was selected for the application of Pb stable isotope ratios as a fingerprinting tool in subtidal and intertidal sediment cores. Lead isotopic ratios were determined by inductively coupled plasma mass spectrometry on extracts from bulk samples after total acid digestion. Depth-wise profiles of (206)Pb/(207)Pb, (206)Pb/(204)Pb, (207)Pb/(204)Pb, (208)Pb/(204)Pb and (208)Pb/(207)Pb ratios showed, in general, an upward decrease for both intertidal and subtidal sediments as a consequence of the anthropogenic activities over the last century, or centuries. Waste channel samples from a nearby ceramic factory showed characteristic Pb stable isotope ratios different from those typical of coal and petrol. Natural isotope ratios from non-polluted samples were established for the study area, differentiating sediments from granitic or schist-gneiss sources. A binary mixing model employed on the polluted samples allowed estimating the anthropogenic inputs to the bay. These inputs represented between 25 and 98% of Pb inputs in intertidal samples, and 9-84% in subtidal samples, their contributions varying with time. Anthropogenic sources were apportioned according to a three-source model. Coal combustion-related emissions were the main anthropogenic source Pb to the bay (60-70%) before the establishment of the ceramic factory in the area (in the 1970s) which has since constituted the main source (95-100%), followed by petrol-related emissions. The Pb inputs history for the intertidal area was determined for the 20th century, and, for the subtidal area, the 19th and 20th centuries.

  9. Spatial Distribution of Lead Isotope Ratios and Inorganic Element Concentrations in Epiphytic Lichens from the Athabasca Oil Sands Region

    NASA Astrophysics Data System (ADS)

    Graney, J. R.; Landis, M. S.; Puckett, K.; Edgerton, E.; Krupa, S.; Percy, K.

    2013-12-01

    Coupled studies of inorganic element concentrations and lead (Pb) isotope ratios have been conducted on Hypogymnia physodes samples collected in the Athabasca Oil Sands Region (AOSR) in Alberta, Canada in 2002, 2008, and 2011. To investigate the spatial extent of air emissions, the lichens were collected from sites as far as 160 km from the mining and processing operations. 30 milligram sub-samples of the lichens were microwave digested, and the extracts were analyzed using DRC-ICPMS to determine elemental concentrations, and sector field ICPMS to measure Pb isotope ratios. Concentrations of elements in the lichens were found to reflect proximity to mining and oil processing sites as well as topography, ecosystem differences, and the metabolic biogeochemistry of the lichens. An exponential decrease in concentration of metals associated with fugitive dust (aluminum and others) versus distance from the mining sites, suggests elevated coarse particle emissions associated with mining operations. Near source concentrations of metals with an oil signature (vanadium and others) are less enhanced and more homogeneous than the metals in the fugitive dust, reflecting emission and deposition of smaller diameter particles at greater distances from oil processing sources. The mining and oil processing signatures are superimposed over elemental concentrations that reflect the nutrient needs of the lichens. These findings are being confirmed through ongoing studies using dichot samplers to collect coarse and fine particulate aerosol samples. The lichen samples collected beyond 50 km from the mining and processing sites cluster into a Pb isotope grouping with a 207Pb / 206Pb ratio of 0.8650 and a 208Pb / 206Pb ratio near 2.095. This grouping likely reflects the regional background Pb isotope ratio signature. 207Pb / 206Pb and 208Pb / 206Pb ratios decrease as one nears the mining and processing operations. This indicates that other Pb source(s), (e.g. Pb in the bitumen from the oil

  10. Lead isotope and trace element composition of urban soils in Mongolia

    NASA Astrophysics Data System (ADS)

    Tserenpil, Sh.; Sapkota, A.; Liu, C.-Q.; Peng, J.-H.; Liu, B.; Segebade, P. Chr.

    2016-08-01

    Lead (Pb) pollution in and around Ulaanbaatar is of national concern, given that the Mongolian capital is home to nearly half of the country's entire population. By comparison, Mongolian countryside is a pristine environment because of its sparse population and low industrial activity. The concentration of Pb in urban soils (average of 39.1 mg kg-1) was twice the values found (average 18.6 mg kg-1) in background territories (i.e., Mongolian rural sites). Furthermore, Pb contamination was examined by using Pb stable isotopic composition, and covariance of Pb isotopic ratios showed two groups between rural and urban soils as pristine and disturbed sites. The 206Pb/207Pb ratio, the most prominent fingerprint for Pb pollution, was 1.163-1.185 for the urban whereas values for rural soils (1.186-1.207) were analogue to the regional Pb isotopic signatures. Local coal sources and their combustion products, one of the potential Pb pollution sources in Ulaanbaatar, have significant radiogenic properties in terms of Pb isotopic composition and revealed an average of 1.25 for 206Pb/207Pb and 19.551 for 206Pb/204Pb ratios. Thus, contributions from coal firing activity to Pb pollution lower than it was assumed, and smaller range of these values measured in urban soils may be attributed to the mixing of less radiogenic Pb as a constituent of the leaded gasolines.

  11. Isotopic Studies of the Guerrero Composite Terrane, West-Central Mexico: Implications for Provenance of Crustal Rocks and Ore Metals

    NASA Astrophysics Data System (ADS)

    Potra, A.; Macfarlane, A. W.; Salters, V. J.; Sachi-Kocher, A.

    2010-12-01

    New Pb, Sr, and Nd isotope analyses of various crustal units and ores from the Guerrero terrane are presented in order to gain insight into their provenance. Mesozoic basement rocks from the Arteaga Complex and Tejupilco metamorphic suite contain radiogenic Pb relative to bulk earth models (206Pb/204Pb between 18.701 and 19.256, 207Pb/204Pb between 15.623 and 15.693, and 208Pb/204Pb between 38.694 and 39.216), plotting to the right of the average Pb crust evolution curve of Stacey and Kramers (1975). The isotopic compositions of Pb in these rocks are substantially more radiogenic than published data on high-grade metamorphic rocks from the Grenvillian-age Oaxaca terrane, but are similar to Paleozoic basement rocks of the Mixteca terrane. Sr and Nd isotope data suggest that the basement rocks of the Guerrero terrane partly originated from ocean-floor rocks which were overlain by sediments derived from a cratonic terrane, possibly represented by the metamorphic complexes of the Oaxaca or Mixteca terranes. Lead isotope ratios of Cretaceous sedimentary rocks of the Zihuatanejo and Huetamo Sequences define two different clusters, with the Zihuatanejo Sequence units shifted to more radiogenic values (206Pb/204 between 18.763 and 19.437, 207Pb/204Pb between 15.580 and 15.643, and 208Pb/204Pb between 38.510 and 38.892). Samples from the Huetamo Sequence are less radiogenic than the metamorphic basement, with Pb isotope ratios between 18.630 and 18.998 for 206Pb/204, 15.563 and 15.641 for 207Pb/204Pb, and 38.369 and 38.610 for 208Pb/204Pb. They plot close to the radiogenic end of the MORB field, suggesting a possible mixing line between the basement rocks and the MORB component. Lead isotope ratios of Tertiary intrusive rocks from La Verde, El Malacate, and La Esmeralda resemble the orogene reservoir in the plumbotectonics model of Zartman and Doe (1981). Plutonic rocks from La Verde show the most radiogenic Pb compositions, suggesting a significant influence of old

  12. Anthropogenic Pb input into Bohai Bay, China: Evidence from stable Pb isotopic compositions in sediments

    NASA Astrophysics Data System (ADS)

    Ning-jing, Hu; Peng, Huang; Hui, Zhang; Ai-mei, Zhu; Ji-hua, Liu; Jun, Zhang; Lian-hua, He

    2015-10-01

    To investigate the source of Pb within Bohai Bay, Pb concentrations and Pb isotopic compositions (204Pb, 206Pb, 207Pb, and 208Pb) of surface sediments in this area were determined. The Pb concentration in this bay varied widely from 6.9 to 39.2 μg/g (average: 21.8±7.8 μg/g), and the Pb isotopic compositions ranged from 0.8338 to 0.8864 (average: 2.0997±0.0180) for 208Pb/206Pb and from 2.0797 to 2.1531 (average: 0.8477±0.0135) for 207Pb/206Pb, presenting in three distinct clusters. The Pb isotopic ratios of sediments from the northeastern (NE zone) and northwestern (NW zone) coastal areas were significantly influenced by anthropogenic sources such as coal combustion and automobile emission. In sediments from the central and southern Bohai Bay (C-S zone); however, Pb mainly originated from the Yellow River catchment, as a result of lithogenic sediment (from rock weathering) accumulation. The Pb isotopic ratios further indicate that, apart from riverine inputs, the neighboring large-scale ports and aerosols significantly contributed to the anthropogenic Pb contained in these sediments. Pb contamination in the Haihe and Luanhe river mouths as well as in the regions near ports is also suggested from anthropogenic enrichment factors. As cities and ports continue to develop around Bohai Bay, a long-term extensive sewage monitoring program is highly recommended.

  13. Spatial and temporal evolution of lead isotope ratios in the North Atlantic Ocean between 1981 and 1989

    NASA Astrophysics Data System (ADS)

    Weiss, Dominik; Boyle, Edward A.; Wu, Jingfeng; Chavagnac, ValéRie; Michel, Anna; Reuer, Matthew K.

    2003-10-01

    Lead concentrations and isotope ratios were measured in North Atlantic surface water samples collected in 1981 (29°-79°N, 6°E-49°W) and in 1989 (23°-39°N, 29°-68°W). In the early 1980s, 206Pb/207Pb ratios in the North African Basin averaged 1.193 ± 0.005 (1 σ). Similar radiogenic ratios within the level of analytical precision (average 0.29%) were found in the Labrador and Iceland Basins (1.198 ± 0.006) and in the Norwegian Sea (1.196 ± 0.008). These radiogenic mixed layer signatures along with atmospheric global lead emission patterns suggest that most North Atlantic lead in the early 1980s was derived from North American leaded gasoline. Samples in the East Iberian Basin near Portugal and France showed lower 206Pb/207Pb ratios, between 1.167 and 1.182, indicating a significant influence of less radiogenic atmospheric lead transported from Europe and possibly the influence of the Rio Tinto acid mine drainage very close to shore in the Gulf of Cadiz. [Pb] across the entire North Atlantic Basin ranged between 54 and 145 pmol/kg, with the lowest values (54-74 pmol/kg) found at high latitudes (>65°N). In the late 1980s, surface waters in the western subtropical North Atlantic (North American Basin/Sargasso Sea, >47°W) and in the eastern subtropical North Atlantic (North African Basin/Central Iberian Basin, <45°W) showed very similar 206Pb/207Pb signatures with little zonal variation, ranging from 1.177 to 1.192. Lead concentrations ranged between 47 and 137 pmol/kg, increasing slightly from west to east. South of 25°N in the equatorial North Atlantic, crossing the subtropical/tropical surface water boundary, the 206Pb/207Pb seawater signatures were significantly less radiogenic (1.170-1.175) and concentrations were lower (≤51 pmol/kg). This difference suggests a relative increase in the atmospheric lead supply from the western Mediterranean/North African continent via Trade Easterlies and illustrates the effective barrier between the subtropical

  14. Lead isotopes in lichen transplants around a Cu smelter in Russia determined by MC-ICP-MS reveal transient records of multiple sources.

    PubMed

    Spiro, B; Weiss, D J; Purvis, O W; Mikhailova, I; Williamson, B J; Coles, B J; Udachin, V

    2004-12-15

    Transplants of the lichen Hypogymnia physodes, which is relatively tolerant to SO2 and heavy metals, were deployed for 3 months over a 60 km long SW-NE transect centered on a highly polluting Cu smelter and its adjoining town of Karabash, southern Urals, Russia. The abundance of 206Pb, 207Pb, 208Pb, and 204Pb were determined by MC-ICP-MS. The measurement of 204Pb revealed critical features, which would otherwise remain concealed: (i) The precise isotope ratios referenced to 204Pb allowed several different sources to be resolved even within the small area covered: (a) the obvious pollutant source of the Karabash Cu smelter; (b) two dispersed sources, likely to include soil with lower and different contributions of thorogenic and uranogenic lead; and (c) one anthropogenic source with higher contribution of 235U derived Pb. (ii) In part of the transect, the Pb isotope composition changed while the Pb concentrations remained the same. This indicates that the Pb content of the transplantation material from the background site was largely replaced and that the transplants provide a transient record reflecting a continuous accumulation and loss of environmental Pb, probably mainly in the form of extracellular particles. Overall, the method of lichen transplantation coupled with Pb isotope ratio determinations proved effective in assessing the usefulness of lichens in biomonitoring and in resolving different sources of atmospheric deposition.

  15. Enriched Nd-Sr-Pb isotopic signatures in the Dovyren layered intrusion ( eastern Siberia, Russia): Evidence for source contamination by ancient upper-crustal material

    USGS Publications Warehouse

    Amelin, Yu. V.; Neymark, L.A.; Ritsk, E. Yu; Nemchin, A.A.

    1996-01-01

    Major- and trace-element concentrations and Nd-, Sr- and Pb-isotopic ratios are reported for the Dovyren layered mafic-ultramafic intrusion in the northern Baikal region, eastern Siberia. Sm-Nd internal isochrons for an olivine gabbro from the layered series and a gabbronorite from a sill at the bottom of the Dovyren intrusion yield ages of 673 ?? 22 and 707 ?? 40 Ma, respectively. Initial isotopic ratios: 87Sr/86Sr (673) from 0.7101 to 0.7135, ??Nd(673 Ma) from - 16.3 to - 14.1, 206Pb/204Pb from 16.80 to 17.14, 207Pb/204Pb from 15.477 to 15.501 and 208Pb/204Pb from 37.17 to 37.59, are similar to those of late Archean-early Proterozoic upper continental crust, but do not appear to be a result of wallrock assimilation in the magma chamber. These isotopic features, as well as high K, Rb and LREE and low Ti concentrations in the calculated composition of the Dovyren parental magma, may be explained by subduction of sediments derived from upper continental crust into depleted mantle and subsequent melting of the metasomatized peridotite.

  16. Two-types of Early Cretaceous adakitic porphyries from the Luxi terrane, eastern North China Block: Melting of subducted Paleo-Pacific slab and delaminated newly underplated lower crust

    NASA Astrophysics Data System (ADS)

    Wang, Hao; Xu, Zhaowen; Lu, Xiancai; Fu, Bin; Lu, Jianjun; Yang, Xiaonan; Zhao, Zengxia

    2016-01-01

    The origin and tectonic setting of Early Cretaceous adakitic rocks from the Luxi terrane in the eastern North China Block (NCB) remain debated. To resolve this issue, we determined whole-rock geochemistry, zircon U-Pb ages, and in situ Hf-O isotopes of the Mengyin and Liujing adakitic porphyries from the Luxi terrane. Zircon U-Pb dating results reveal that both the Mengyin and Liujing plutons were emplaced during the Early Cretaceous, with weighted mean 206Pb/238U ages of 130 ± 1 Ma (2σ) and 131 ± 2 Ma (2σ), respectively. In addition, abundant Neoarchean-Paleoproterozoic inherited zircon cores are identified in the Mengyin adakitic porphyry with 207Pb/206Pb ages ranging from 2.53 to 2.42 Ga. Rocks of both plutons are silicic (SiO2 = 65.4-70.2 wt.%), metaluminous, and alkaline in composition, comprising mainly quartz syenite porphyries. Samples from both plutons are enriched in large ion lithophile elements (LILEs) (e.g., Rb, Sr, and Ba), and light rare earth elements (LREEs), depleted in high field strength elements (HFSEs) (e.g., Nb, Ta, and Ti), and heavy rare earth elements (HREEs), and have either positive or no Eu anomalies. In addition, both adakitic porphyries have high Mg# values (51-64), high Sr and La contents, low Y and Yb contents, and high Sr/Y (Mengyin = 149-264; Liujing = 58-110) and (La/Yb)N (Mengyin = 32.4-45.3; Liujing = 43.8-53.1) ratios, similar to adakitic rocks worldwide. The Mengyin adakitic porphyry has higher whole-rock εNd(t) values (-5.8 to - 4.1), more radiogenic Pb [(206Pb/204Pb)i = 18.35-18.39, (207Pb/204Pb)i = 15.55-15.56, (208Pb/204Pb)i = 38.20-38.23], higher zircon rim εHf(t) values (+ 3.3 to + 8.8) and δ18O values (+ 6.5‰ to + 7.9‰), and lower (87Sr/86Sr)i ratios (0.7049-0.7050) than the Liujing adakitic porphyry [εNd(t) = - 12.4 to - 12.2, (206Pb/204Pb)i = 17.63-17.72, (207Pb/204Pb)i = 15.56-15.58, (208Pb/204Pb)i = 37.76-37.94, εHf(t) = - 14.8 to - 11.2, δ18O = + 5.9‰ to + 7.1‰, (87Sr/86Sr)i = 0.7090-0.7091]. The

  17. Some Pb and Sr isotopic measurements on eclogites from the Roberts Victor mine, South Africa

    USGS Publications Warehouse

    Manton, W.I.; Tatsumoto, M.

    1971-01-01

    Five nodules of eclogite, one nodule of garnet peridotite and one sample of kimberlite from the Roberts Victor mine were analyzed for concentrations of U, Th, Pb, Rb and Sr and isotopic compositions of Pb and Sr. In the eclogites, U content ranges from 0.09 to 0.26 ppm, Th from 0.35 to 1.1 ppm, Pb from 0.79 to 5.5 ppm, Rb from 2.1 to 28 ppm and Sr from 133 to 346 ppm; 206Pb/204Pb ratios range from 14.8 to 18.5, 207Pb/204Pb from 14.9 to 15.7, 208Pb/204Pb from 35.2 to 38.5. The garnet peridotite contains 0.22 ppm U, 0.97 ppm Th, 1.05 ppm Pb, 6.9 ppm Rb and 108 ppm Sr and the kimberlite contains 2.5 ppm U, 30 ppm Th, 37 ppm Pb, 113 ppm Rb and 2040 ppm Sr. The lead in the eclogites has two components, a lead pyroextractable at 1100-1200?? and a non-pyroextractable residual lead. In three of the eclogites, which are to some extent altered, a proportion of the pyroextractable lead may be contaminating lead from the kimberlite, but an altered kyanite eclogite does not appear to be contaminated by this same kimberlite. The pyroextractable lead from a less altered eclogite contains a much larger proportion of 206Pb. Compositions calculated for the residual leads vary greatly. In many of the pyroextraction runs the primary eclogitic phases disappeared and the new phases plagioclase, clinopyroxene and a magnetic iron compound were formed. Why part of the lead should have been retained by these new phases is not understood. ?? 1971.

  18. Southern Cordilleran Basaltic Andesite suite, southern Chihuahua, Mexico: A link between Tertiary continental arc and flood basalt magmatism in the North America

    SciTech Connect

    Cameron, K. L.; Nimz, G. J.; Kuentz, D.; Niemeyer, S.; Gunn, S.

    1989-06-10

    Mid-Cenozoic orogenic andesites and ignimbrites of western Mexico, southwestern New Mexico, and Arizona are commonly capped by basaltic andesites, most from 29--20 Ma. We refer to these mafic lavas as the Southern Cordilleran Basaltic Andesite (SCORBA) suite, and they may constitute the most extensive Cenozoic basaltic suite in North America. The SCORBA suite has trace element and isotopic characteristics of orogenic (arc) rocks (i.g., Ba/Nb/gt/40), and silica content (53--56% SiO/sub 2/) like the Grande Ronde Basalt, which represents about 80% of the volume of the Columbia River Group. Geochemical and isotopic data are presented on SCORBA lavas and rare mafic lavas (PRE-SCORBA) interlayered with older ignimbrites from a 700-km-long NE-SW transect of southern Chihuahua, Mexico. SCORBA and PRE-SCORBA lavas with relatively low K/P (/lt/7) and differing Ba/Nd (50 versus 18) have similar isotopic compositions, arguing against their isotopic signatures being controlled by crustal assimilation. Along the entire length of the transect, the basaltic rocks have /var epsilon//sub Nd/ and /sup 87/Sr//sup 86/Sr near bulk Earth and /sup 206/Pb//sup 204/Pb and /sup 207/Pb//sup 204/Pb ratios that lie along a 1.7 Ga pseudoisochron. The Pb isotopic variation is geographically controlled, becoming more radiogenic from east to west, reflecting mixing in mantle source regions. The eastern mantle source has low/sup 206/Pb//sup 204/Pb and is a mixture of an enriched, enriched-mantle-like (EMI) component with one or more depleted components, which could include an intraplate component with relatively high Nb/Y (/gt/0.8).

  19. Estimating distributions of endogenous and exogenous Pb in soils by using Pb isotopic ratios.

    PubMed

    Semlali, R M; van Oort, F; Denaix, L; Loubet, M

    2001-11-01

    Metal contamination of soils by diffuse atmospheric deposition is a worldwide phenomenon. The assessment of incorporation of exogenous metal contaminants in soils is of major environmental importance. Once entering in the soil's biogeochemical cycling, specific pedogenetic soil processes govern metal distribution patterns with depth. In this paper, we attempt to estimate the distribution of endogenous and exogenous Pb in two soils with contrasting pedogenesis, both representative of undisturbed ecosystems. Pb isotope analyses were performed using high-precision thermal ionization mass spectrometry. Endogenous and exogenous Pb concentrations and exogenous 206Pb/207Pb ratios of the samples were calculated using bulk Pb and Sc concentrations and bulk 206Pb/207Pb ratios. Endogenous Pb distribution was in agreementwith dominant soil characteristics, almost constant in the young Andosol and with a clear minimum and maximum in the eluvial and illuvial horizons of the Podzol. The distribution of exogenous Pb was closely related to that of organic C in both soils. Exogenous Pb was evidenced in significant amounts at depth. Using moderate dispersive particle-size fractionation allowed us to evidence the presence of exogenous Pb in functional soil compartments and to highlight preferential distributions of Pb, according to pedology.

  20. A LREE-depleted component in the Afar plume: Further evidence from Quaternary Djibouti basalts

    NASA Astrophysics Data System (ADS)

    Daoud, Mohamed A.; Maury, René C.; Barrat, Jean-Alix; Taylor, Rex N.; Le Gall, Bernard; Guillou, Hervé; Cotten, Joseph; Rolet, Joël

    2010-02-01

    Major, trace element and isotopic (Sr, Nd, Pb) data and unspiked K-Ar ages are presented for Quaternary (0.90-0.95 Ma old) basalts from the Hayyabley volcano, Djibouti. These basalts are LREE-depleted (La n/Sm n = 0.76-0.83), with 87Sr/ 86Sr ratios ranging from 0.70369 to 0.70376, and rather homogeneous 143Nd/ 144Nd ( ɛNd = + 5.9-+ 7.3) and Pb isotopic compositions ( 206Pb/ 204Pb = 18.47-18.55, 207Pb/ 204Pb = 15.52-15.57, 208Pb/ 204Pb = 38.62-38.77). They are very different from the underlying enriched Tadjoura Gulf basalts, and from the N-MORB erupted from the nascent oceanic ridges of the Red Sea and Gulf of Aden. Their compositions closely resemble those of (1) depleted Quaternary Manda Hararo basalts from the Afar depression in Ethiopia and (2) one Oligocene basalt from the Ethiopian Plateau trap series. Their trace element and Sr, Nd, Pb isotope systematics suggest the involvement of a discrete but minor LREE-depleted component, which is probably an intrinsic part of the Afar plume.

  1. Some triple-filament lead isotope ratio measurements and an absolute growth curve for single-stage leads

    USGS Publications Warehouse

    Stacey, J.S.; Delevaux, M.E.; Ulrych, T.J.

    1969-01-01

    Triple-filament analyses of three standard lead samples are used to calibrate a mass spectrometer in an absolute sense. The bias we measure is 0.0155 percent per mass unit, and the precision (for 95% confidence limits) is ??0.13% or less for all ratios relative to 204Pb. Although its precision is not quite so good as that of the lead-tetramethyl method in the analysis of large samples, the triple-filament method is less complex and is an attractive alternative for smaller sample sizes down to 500 ??g. Triple-filament data are presented for six possibly single-stage lead ores and one feldspar. These new data for ores are combined with corrected tetramethyl data for stratiform lead deposits to compute absolute parameters for a universal single-stage lead isotope growth curve. Absolute isotopic ratios for primeval lead have been determined by Oversby and because all the previous data for both meteorites and lead ores were similarly fractionated, the absolute value of 238U 204Pb = 9.09 ?? 0.06 for stratiform leads is little different from the value 8.99 ?? 0.05 originally computed by Ostic, Russell and Stanton. Absolute values for lead isotope ratios for all interlaboratory standard samples presently available from the literature are tabulated. ?? 1969.

  2. The origin of Cenozoic continental basalts in east-central China: Constrained by linking Pb isotopes to other geochemical variables

    NASA Astrophysics Data System (ADS)

    Xu, Zheng; Zheng, Yong-Fei; Zhao, Zi-Fu

    2017-01-01

    Cenozoic continental basalts in east-central China are characterized by OIB-like trace element patterns with more depleted to less enriched Sr-Nd isotope compositions. Such geochemical signatures are attributable to variable contributions to their mantle sources from crustal components in the oceanic subduction zone. A combined study of basalt Pb isotope variations with other geochemical variables indicates that four mantle and crustal components were involved in the basalt petrogenesis. Model calculations verify the geochemical transfer from the subducted crustal components to the mantle sources. The depleted MORB mantle component is indicated by the depleted Sr-Nd isotope compositions of basalts. Relatively high 206Pb/204Pb and low Δ8/4 ratios are ascribed to contributions from the igneous oceanic crust with high U/Pb and low Th/U ratios, low 206Pb/204Pb and high Δ8/4 ratios are ascribed to the lower continental crust, and high 206Pb/204Pb and high Δ8/4 ratios are linked to the seafloor sediment. This generates different compositions of mantle sources for these OIB-like continental basalts. The basalts with the most depleted Sr-Nd isotope compositions show Pb isotope compositions distinct from Pacific MORB but similar to Indian MORB, suggesting the occurrence of Indian type asthenospheric mantle beneath the continental lithosphere of eastern China. The depleted MORB mantle would be metasomatized by the three crustal components at the slab-mantle interface in oceanic subduction channel, generating the mantle sources that are enriched in melt-mobile incompatible trace elements and their pertinent radiogenic isotopes. Nevertheless, the crustal components were not directly incorporated in the forms of crustal rocks into the mantle sources, but underwent partial melting to produce the felsic melts that predominate the composition of those trace elements and their pertinent radiogenic isotopes in the basalts. As such, the depleted MORB mantle component was

  3. Lead isotope studies of the Guerrero composite terrane, west-central Mexico: implications for ore genesis

    NASA Astrophysics Data System (ADS)

    Potra, Adriana; Macfarlane, Andrew W.

    2014-01-01

    New thermal ionization mass spectrometry and multi-collector inductively coupled plasma mass spectrometry Pb isotope analyses of three Cenozoic ores from the La Verde porphyry copper deposit located in the Zihuatanejo-Huetamo subterrane of the Guerrero composite terrane are presented and the metal sources are evaluated. Lead isotope ratios of 3 Cenozoic ores from the El Malacate and La Esmeralda porphyry copper deposits located in the Zihuatanejo-Huetamo subterrane and of 14 ores from the Zimapan and La Negra skarn deposits from the adjoining Sierra Madre terrane are also presented to look for systematic differences in the lead isotope trends and ore metal sources among the proposed exotic tectonostratigraphic terranes of southern Mexico. Comparison among the isotopic signatures of ores from the Sierra Madre terrane and distinct subterranes of the Guerrero terrane supports the idea that there is no direct correlation between the distinct suspect terranes of Mexico and the isotopic signatures of the associated Cenozoic ores. Rather, these Pb isotope patterns are interpreted to reflect increasing crustal contribution to mantle-derived magmas as the arc advanced eastward onto a progressively thicker continental crust. The lead isotope trend observed in Cenozoic ores is not recognized in the ores from Mesozoic volcanogenic massive sulfide and sedimentary exhalative deposits. The Mesozoic ores formed prior to the amalgamation of the Guerrero composite terrane to the continental margin, which took place during the Late Cretaceous, in intraoceanic island arc and intracontinental marginal basin settings, while the Tertiary deposits formed after this event in a continental arc setting. Lead isotope ratios of the Mesozoic and Cenozoic ores appear to reflect these differences in tectonic setting of ore formation. Most Pb isotope values of ores from the La Verde deposit (206Pb/204Pb = 18.674-18.719) are less radiogenic than those of the host igneous rocks, but plot within the

  4. Relationships of lead in breast milk to lead in blood, urine, and diet of the infant and mother.

    PubMed Central

    Gulson, B L; Jameson, C W; Mahaffey, K R; Mizon, K J; Patison, N; Law, A J; Korsch, M J; Salter, M A

    1998-01-01

    We have obtained stable lead isotope and lead concentration data from a longitudinal study of mobilization of lead from the maternal skeleton during pregnancy and lactation and in which the newly born infants were monitored for 6 months postpartum to evaluate the effects of the local environment on lead body burden of the infant. Samples of maternal and infant blood, urine, and diet and especially breast milk were measured for 21 mothers and 24 infants. Blood lead concentrations were less than 5 microg/dl in all except one subject. The mean lead concentration in breast milk +/- standard deviation was 0.73 +/- 0.70 microg/kg. In seven subjects for whom serial breast milk sampling was possible, the lead concentration varied by factors of from 2 to 4, and for three subjects there was an increase at or after 90 days postpartum. For the first 60-90 days postpartum, the contribution from breast milk to blood lead in the infants varied from 36 to 80%. Multiple linear regression analyses indicated statistically significant relationships for some of the variables of isotope ratios and lead concentrations between breast milk, blood, urine, and diet for infants and mothers. For example, the analyses revealed that both a mother's breast milk 207Pb/206Pb and 206Pb/204Pb ratios and lead concentration provide information to predict her infant's blood 207Pb/206Pb and 206Pb/204Pb ratios. The major sources of lead in breast milk are from the maternal bone and diet. An evaluation of breast milk lead concentrations published over the last 15 years indicates that studies in which the ratio of lead concentrations in breast milk to lead concentrations in whole maternal blood (Multiple>100) were greater than 15 should be viewed with caution because of potential contamination during sampling and/or laboratory analyses. Selected studies also appear to show a linear relationship between breast milk and maternal whole blood, with the percentage of lead in breast milk compared with whole blood

  5. The origin of the Line Islands: plate or plume controlled volcanism?

    NASA Astrophysics Data System (ADS)

    Storm, L. P.; Konter, J. G.; Koppers, A. A.

    2011-12-01

    foundation of the central and southern provinces is shallower than the regional seafloor, suggesting that the thickness of the lithosphere in these two provinces may have an influence on the chemical compositions of seamounts. A suite of samples, previously analyzed for 40Ar/39Ar age data, was processed for lead (Pb), neodymium (Nd), hafnium (Hf) and strontium (Sr) isotope measurements to investigate whether the Line Islands are caused by 4-5 concurrent plumes or a lithospherically controlled source. Pb isotope compositions define two distinct groups: (1) low 206Pb/204Pb and 207Pb/204Pb ratios, and (2) high 206Pb/204Pb and 207Pb/204Pb ratios. When Pb isotope compositions are considered in relation to their dredge locations, the two identified groups do not define age-progressive volcanic chains expected for a plume origin. Instead, high 206Pb/204Pb and 207Pb/204Pb samples are strictly limited between the Molokai and Clarion fracture zones, suggesting that ocean crust segmentation related to mid-ocean ridge spreading and adjustments in the Pacific-Phoenix-Farallon triple junction partly controlled the melt compositions. These results, therefore, suggest that this major volcanic chain was likely not plume-derived.

  6. On the recent enrichment of subcontinental lithosphere: A detailed UPb study of spinel lherzolite xenoliths, Yukon, Canada

    NASA Astrophysics Data System (ADS)

    Carignan, Jean; Ludden, John; Francis, Don

    1996-11-01

    Lead strontium, and osmium isotopic data have been obtained for whole rocks and mineral separates (olivine, orthopyroxene, clinopyroxene, and spinel) for spinel lherzolite xenoliths hosted by lavas of the Quaternary Alligator Lake volcanic centre, southern Yukon. Whole-rock xenolith samples display a large variation of lead concentrations, from 16 ppb for a harzburgite to up to 400 ppb for a lherzolite. However, their lead isotope ratios are relatively homogeneous with 206Pb /204Pb of 19.07 ± 0.08, 207Pb /204Pb of 15.65 ± 0.07, and 208Pb /204Pb of 38.67 ± 0.17 ( n = 7). However, the 238U /204Pb ratios display a large variation, from 12.2 to 46.5, and do not correlate with indices of fertility such as calcium or aluminum content. Mineral separates yield even larger variations in lead isotopic composition and lead and uranium concentrations. Some olivine fractions have both the lowest radiogenic compositions ( 206Pb /204Pb = 18.75 ) and the lowest 238U /204Pb ratios (˜3.1). Clinopyroxenes (cpx) display the highest lead and uranium concentrations (up to 1277 ppb and 195 ppb, respectivelly) and generally similar or more radiogenic lead isotopic composition and higher 238U /204Pb ratios than their whole-rock compositions. Orthopyroxene and spinel fractions yield intermediate compositions between olivine and cpx. Although whole rocks and cpx for individual samples yield almost identical 87Sr /86Sr , the xenoliths ( n = 5) display a large variation of strontium isotopic compositions ( 87Sr /86Sr from 0.07033 to 0.7050), lead and strontium isotope ratios of cpx and the distribution of the data in a UPb isochron diagram suggest that the subcontinental lithosphere under the Yukon was affected by a recent (< ˜30 Ma) enrichment in uranium, lead, and strontium. The metasomatic fluid/magma might have had an isotopic composition close to that of some sediments in the northern Pacific Ocean. When compared to K d values reported in the literature, olivine is enriched in

  7. Corrigendum to "A redox-stratified ocean 3.2 billion years ago" [Earth Planet. Sci. Lett. 430 (2015) 43-53

    NASA Astrophysics Data System (ADS)

    Satkoski, Aaron M.; Beukes, Nicolas J.; Li, Weiqiang; Beard, Brian L.; Johnson, Clark M.

    2017-02-01

    The authors have discovered a calculation error in the concentration data for U, Th and Pb. This error does not affect any measured isotopic compositions: 206Pb/204Pb, 207Pb/204Pb, 238U/204Pb, 232Th/204Pb, and 235U/204Pb; these all remain the same. None of the Fe isotope data are affected. Hence, none of the conclusions for open or closed-system U-Th-Pb behavior are affected, nor the conclusions of a redox gradient between shallow- and deep-water U contents. The magnitude of the shallow- and deep-water U content contrast remains the same, where U contents in shallow seawater are estimated to have been about three times that of deep-water samples.

  8. Source of lead in Central American and Caribbean mineralization, II. Lead isotope provinces

    NASA Astrophysics Data System (ADS)

    Cumming, George L.; Kesler, Stephen E.; Krstic, Dragan

    1981-12-01

    In an earlier study of Mesozoic and Cenozoic mineralization in Central America and the Caribbean region, we found that lead isotopic compositions of deposits in northern Central America, which is underlain by a pre-Mesozoic craton, ranged to higher 206Pb/ 204Pb and 207Pb/ 204Pb compositions than did deposits from elsewhere in the region, where the basement is Mesozoic oceanic material. Using 16 analyses for 12 new deposits, as well as new analyses for 11 of the samples studied previously, we have found that lead isotopic compositions correlate closely with crustal type but show little or no correlation with depth to the M-discontinuity. The deposits are divisible into three main groups including (in order of increasing 207Pb/ 204Pb and 208Pb/ 204Pb ratio): (1) deposits in southern Central America and all deposits in the Greater Antilles except Cuba; (2) all deposits in northern Central America; and (3) the Cuban deposits. Southern Central American and Caribbean lead is higher in 207Pb/ 204Pb and 208Pb/ 204Pb than most mid-ocean ridge basalts but could have been derived directly or indirectly from undepleted mantle. Northern Central America can be divided into the Maya block, which belongs to the Americas plate, and the Chortis block, which belongs to the Caribbean plate. Maya block deposits fall along a linear array whereas those of the Chortis block (except the Monte Cristo deposit) form a cluster. These results suggest that the Maya block is underlain by crust or mantle with a large range of U/Pb and Th/U ratios, whereas the Chortis block basement is more homogeneous. Two-stage model calculations indicate an age of about 2280±310 m.y. for the Maya block basement, although no such rocks are known in the region. Comparison of the Chortis block data to our recently published lead isotopic analyses of Mexican deposits shows considerable similarities suggesting that the Chortis block could have been derived from Mexico.

  9. CONCH: A Visual Basic program for interactive processing of ion-microprobe analytical data

    NASA Astrophysics Data System (ADS)

    Nelson, David R.

    2006-11-01

    A Visual Basic program for flexible, interactive processing of ion-microprobe data acquired for quantitative trace element, 26Al- 26Mg, 53Mn- 53Cr, 60Fe- 60Ni and U-Th-Pb geochronology applications is described. Default but editable run-tables enable software identification of secondary ion species analyzed and for characterization of the standard used. Counts obtained for each species may be displayed in plots against analysis time and edited interactively. Count outliers can be automatically identified via a set of editable count-rejection criteria and displayed for assessment. Standard analyses are distinguished from Unknowns by matching of the analysis label with a string specified in the Set-up dialog, and processed separately. A generalized routine writes background-corrected count rates, ratios and uncertainties, plus weighted means and uncertainties for Standards and Unknowns, to a spreadsheet that may be saved as a text-delimited file. Specialized routines process trace-element concentration, 26Al- 26Mg, 53Mn- 53Cr, 60Fe- 60Ni, and Th-U disequilibrium analysis types, and U-Th-Pb isotopic data obtained for zircon, titanite, perovskite, monazite, xenotime and baddeleyite. Correction to measured Pb-isotopic, Pb/U and Pb/Th ratios for the presence of common Pb may be made using measured 204Pb counts, or the 207Pb or 208Pb counts following subtraction from these of the radiogenic component. Common-Pb corrections may be made automatically, using a (user-specified) common-Pb isotopic composition appropriate for that on the sample surface, or for that incorporated within the mineral at the time of its crystallization, depending on whether the 204Pb count rate determined for the Unknown is substantially higher than the average 204Pb count rate for all session standards. Pb/U inter-element fractionation corrections are determined using an interactive log e-log e plot of common-Pb corrected 206Pb/ 238U ratios against any nominated fractionation-sensitive species pair

  10. Geochemical stages at Jasper Seamount and the origin of intraplate volcanoes

    NASA Astrophysics Data System (ADS)

    Konter, J. G.; Staudigel, H.; Blichert-Toft, J.; Hanan, B. B.; Polvé, M.; Davies, G. R.; Shimizu, N.; Schiffman, P.

    2009-02-01

    Ocean intraplate volcanoes (OIVs) are formed in a sequence of stages, from large to small, that involve a systematic progression in mantle melting in terms of volumes and melt fractions with concomitant distinct mantle source signatures. The Hawaiian volcanoes are the best-known example of this type of evolution, even though they are extraordinarily large. We explore the Pb-Sr-Nd-Hf isotopic evolution of much smaller OIVs in the Fieberling-Guadalupe Seamount Trail (FGST) and small, near-ridge generated seamounts in the same region. In particular, we investigate whether we can extend the Hawaiian models to Jasper Seamount in the FGST, which displays three distinct volcanic stages. Each stage has characteristic variations in Pb-Sr-Nd-Hf isotopic composition and trace element enrichment that are remarkably similar to the systematics observed in Hawaii: (1) The most voluminous, basal "shield building" stage, the Flank Transitional Series (FTS), displays slightly isotopically enriched compositions compared to the common component C and the least enriched trace elements (143Nd/144Nd: 0.512866-0.512909, 206Pb/204Pb: 18.904-19.054; La/Sm: 3.71-4.82). (2) The younger and substantially less voluminous Flank Alkalic Series (FAS) is comparatively depleted in Sr, Nd, and Hf isotope compositions plotting on the side of C, near the least extreme values for the Austral Islands and St. Helena. Trace elements are highly enriched (143Nd/144Nd: 0.512912-0.512948, 206Pb/204Pb: 19.959-20.185; La/Sm: 9.24). (3) The Summit Alkalic Series (SAS) displays the most depleted Sr, Nd, and Hf isotope ratios and is very close in isotopic composition to the nearby near-ridge seamounts but with highly enriched trace elements (143Nd/144Nd: 0.512999-0.513050, 206Pb/204Pb: 19.080-19.237; La/Sm: 5.73-8.61). These data fit well with proposed multicomponent melting models for Hawaii, where source lithology controls melt productivity. We examine the effect of melting a source with dry peridotite, wet

  11. Correlated helium and lead isotope variations in Hawaiian lavas

    SciTech Connect

    Eiler, J.M.; Farley, K.A.; Stolper, E.M.

    1998-06-01

    Variations in {sup 3}He/{sup 4}He ratios among Hawaiian shield-building and pre-shield basalts are correlated with variations in {sup 208}Pb/{sup 204}Pb and {sup 206}Pb/{sup 204}Pb ratios. Using this correlation, the {sup 32}He/{sup 4}He ratio of Hawaiian lavas can be predicted to within 2.9 R{sub A} (mean deviation) between 7 and 32 R{sub A} based only upon the lead isotope composition. This level of prediction is as good as can be expected based upon the precision of lead isotope ratio measurements. This correlation demonstrates a coupling of volatile and nonvolatile elements in the sources of Hawaiian basalts and allows the nonvolatile-element characteristics of the high-{sup 3}He/{sup 4}He component of the mantle sources of Hawaiian lavas to be defined. This result confirms and extends previous inferences based upon correlations between helium and strontium isotope ratios in individual suites of Hawaiian lavas. The source of high {sup 3}He/{sup 4}He ratios in Hawaiian lavas has a higher time-integrated Th/U ratio than the sources of Pacific mid-ocean ridge basalts, consistent with it being a mixture containing primitive mantle or having differentiated in two or more stages from primitive mantle.

  12. Nd, Sr, Pb, Ar, and O isotopic systematics of Sturgeon Lake kimberlite, Saskatchewan, Canada: constraints on emplacement age, alteration, and source composition

    NASA Astrophysics Data System (ADS)

    Hegner, E.; Roddick, J. C.; Fortier, S. M.; Hulbert, L.

    1995-06-01

    Rb-Sr isotopic dating of phlogopite megacryst samples separated from Sturgeon Lake kimberlite, Saskatchewan, yields a crystallization age of 98±1 Ma (2 σ, MSWD=1.2; 87Sr/86Sr( t)=0.7059). The 40Ar/39Ar analyses of a phlogopite megacryst sample indicate the presence of large amounts of excess 40Ar and yield an excessively old age of ˜410 Ma. Assessment of the Ar data using isotope correlation plots indicates clustering of the data points about a mixing line between the radiogenic 40Ar component at 98 Ma and a trapped component with uniform 36Ar/40Ar and Cl/40Ar. Values of δ 18O as high as +20‰ (VSMOW) for calcite from the groundmass and a whole-rock sample indicate pervasive low-temperature alteration. The δ 13C of matrix carbonate is -11.3‰ (PDB), slightly lighter than typical values from the literature. The δ 18O values of about +5‰ (VSMOW) for brown phlogopite megacrysts may be primary, green phlogopites are interpreted to be an alteration product of the brown variety and are 2‰ heavier. Initial Nd-Sr-Pb isotopic ratios for a whole-rock sample ( ɛ Nd=+0.8; 87Sr/86Sr=0.7063, 206Pb/204Pb=18.67, 207Pb/204Pb=15.54, 208Pb/204Pb=38.97) suggest an affinity with group I kimberlites. Initial ɛ Nd values of +1.7 and +0.5 (87Sr/86Sr( t)=0.7053 and 0.7050) for eclogitic and lherzolitic garnet megacryst samples, and values of 0.0 for two phlogopite megacryst samples reflect an origin from an isotopically evolving melt due to assimilation of heterogeneous mantle. Lilac high-Cr lherzolitic garnet megacrysts give an unusually high ɛ Nd(98. Ma) of +28.6 (87Sr/86Sr=0.7046) indicating a xenocrystic origin probably from the lithospheric mantle. The very radiogenic 87Sr/86Sr and 206Pb/204Pb ratios of the kimberlite are consistent with melting of EM II (enriched) mantle components.

  13. Effects of interaction between ultramafic tectonite and mafic magma on Nd-Pb-Sr isotopic systems in the Neoproterozoic Chaya Massif, Baikal-Muya ophiolite belt

    USGS Publications Warehouse

    Amelin, Y.V.; Ritsk, E. Yu; Neymark, L.A.

    1997-01-01

    Sm-Nd, Rb-Sr and U-Pb isotopic systems have been studied in minerals and whole rocks of harzburgites and mafic cumulates from the Chaya Massif, Baikal-Muya ophiolite belt, eastern Siberia, in order to determine the relationship between mantle ultramafic and crustal mafic sections. Geological relations in the Chaya Massif indicate that the mafic magmas were emplaced into, and interacted with older solid peridotite. Hand picked, acid-leached, primary rock-forming and accessory minerals (olivine, orthopyroxene, clinopyroxene and plagioclase) from the two harzburgite samples show coherent behavior and yield 147Sm/144Nd- 143Nd/144Nd and 238U/204Pb-206Pb/204Pb mineral isochrons, corresponding to ages of 640 ?? 58 Ma (95% confidence level) and 620 ?? 71 Ma, respectively. These values are indistinguishable from the crystallization age of the Chaya mafic units of 627 ?? 25 Ma (a weighted average of internal isochron Sm-Nd ages of four mafic cumulates). The Rb-Sr and Sm-Nd isotopic systems in the harzburgite whole-rock samples were disturbed by hydrothermal alteration. These alteration-related isotopic shifts mimic the trend of variations in primary isotopic compositions in the mafic sequence, thus emphasizing that isotopic data for ultramafic rocks should be interpreted with great caution. On the basis of initial Sr and Nd values, ultramafic and mafic rocks of the Chaya Massif can be divided into two groups: (1) harzburgites and the lower mafic unit gabbronorites with ??Nd = +6.6 to +7.1 and ??Sr = -11 to -16; and (2) websterite of the lower unit and gabbronorites of the upper mafic unit: ??Nd = + 4.6 to + 6.1 and ??Sr = - 8 to -9. Initial Pb isotopic ratios are identical in all rocks studied, with mean values of 206Pb/204Pb = 16.994 ?? 0.023 and 207Pb/204Pb = 15.363 ?? 0.015. The similarity of ages and initial isotopic ratios within the first group indicates that the isotopic systems in the pre-existing depleted peridotite were reset by extensive interaction with basaltic

  14. Childhood lead exposure in an industrial town in China: coupling stable isotope ratios with bioaccessible lead.

    PubMed

    Li, Hong-Bo; Chen, Kai; Juhasz, Albert L; Huang, Lei; Ma, Lena Q

    2015-04-21

    Fingerprinting based on stable isotopes of lead (Pb) in blood and environmental media helps to identify Pb exposure pathways in children. However, previous studies used stable isotopes of total Pb in media. In this study, a wire rope production town in China (Zhuhang) was selected for investigating the effectiveness of using isotope ratios in bioaccessible Pb to identify childhood Pb exposure pathways. Blood Pb levels of 115 children in Zhuhang were 1.7-20.4 μg dL(-1), averaging 6.1 ± 3.2 μg dL(-1) (mean ± standard deviation), and were ∼1.6 times the national average in China (3.9 ± 1.8 μg dL(-1)). Among different environmental media (housedust, soil, PM10, vegetables, rice, and drinking water), housedust (695 ± 495 mg kg(-1)) and vegetables [0.36 ± 0.40 mg (kg of fresh weight)(-1)] contained elevated Pb concentrations. The isotope ratios ((207)Pb/(206)Pb and (208)Pb/(206)Pb) of total Pb were the highest in housedust (0.8587 ± 0.0039 and 2.1049 ± 0.0087) but lower than blood Pb ratios (0.8634 ± 0.0027 and 2.1244 ± 0.0061). When using bioaccessible Pb in housedust (0.8639 ± 0.0018 and 2.1171 ± 0.0036), the isotope ratios overlapped with blood Pb ratios, suggesting that incidental ingestion of housedust was the predominant contributor to children's blood Pb. Coupling the stable isotope technique with bioaccessible Pb is more reliable for identifying Pb exposure pathways than total Pb determinations.

  15. H, O, Sr, Nd, and Pb isotope geochemistry of the Latir volcanic field and cogenetic intrusions, New Mexico, and relations between evolution of a continental magmatic center and modifications of the lithosphere

    USGS Publications Warehouse

    Johnson, C.M.; Lipman, P.W.; Czamanske, G.K.

    1990-01-01

    Over 200 H, O, Sr, Nd, and Pb isotope analyses, in addition to geologic and petrologic constraints, document the magmatic evolution of the 28.5-19 Ma Latir volcanic field and associated intrusive rocks, which includes multiple stages of crustal assimilation, magma mixing, protracted crystallization, and open- and closed-system evolution in the upper crust. In contrast to data from younger volcanic centers in northern New Mexico, relatively low and restricted primary ??18O values (+6.4 to +7.4) rule out assimilation of supracrustal rocks enriched in 18O. Initial 87Sr/86Sr ratios (0.705 to 0.708), ??18O values (-2 to-7), and 206Pb/204Pb ratios (17.5 to 18.4) of metaluminous precaldera volcanic rocks and postcaldera plutonic rocks suggest that most Latir rocks were generated by fractional crystallization of substantial volumes of mantle-derived basaltic magma that had near-chondritic Nd isotope ratios, accompanied by assimilation of crustal material in two main stages: 1) assimilation of non-radiogenic lower crust, followed by 2) assimilation of middle and upper crust by inter-mediate-composition magmas that had been contaminated during the first stage. Magmatic evolution in the upper crust peaked with eruption of the peralkaline Amalia Tuff (???26 Ma), which evolved from metaluminous parental magmas. A third stage of late, roofward assimilation of Proterozoic rocks in the Amalia Tuff magma is indicated by trends in initial 87Sr/86Sr and 206Pb/204Pb ratios from 0.7057 to 0.7098 and 19.5 to 18.8, respectively, toward the top of the pre-eruptive magma chamber. Highly evolved postcaldera plutons are generally fine grained and are zoned in initial 87Sr/86Sr and 206Pb/204Pb ratios, varying from 0.705 to 0.709 and 17.8 to 18.6, respectively. In contrast, the coarser-grained Cabresto Lake (???25 Ma) and Rio Hondo (???21 Ma) plutons have relatively homogeneous initial 87Sr/86Sr and 206Pb/204Pb ratios of approximately 0.7053 and 17.94 and 17.55, respectively. ??18O values for

  16. A lead isotope study of mineralization in the Saudi Arabian Shield

    USGS Publications Warehouse

    Stacey, J.S.; Doe, B.R.; Roberts, R.J.; Delevaux, M.H.; Gramlich, J.W.

    1980-01-01

    New lead isotope data are presented for some late Precambrian and early Paleozoic vein and massive sulfide deposits in the Arabian Shield. Using the Stacey Kramers (1975) model for lead isotope evolution, isochron model ages range between 720 m.y. and 420 m.y. Most of the massive sulfide deposits in the region formed before 680 m.y. ago, during evolution of the shield. Vein type mineralization of higher lead content occurred during the Pan African event about 550 m.y. ago and continued through the Najd period of extensive faulting in the shield that ended about 530 m.y. ago. Late post-tectonic metamorphism may have been responsible for vein deposits that have model ages less than 500 m.y. Alternatively some of these younger model ages may be too low due to the mineralizing fluids acquiring radiogenic lead from appreciably older local crustal rocks at the time of ore formation. The low207Pb/204Pb ratios found for the deposits in the main part of the shield and for those in north-eastern Egypt, indicate that the Arabian craton was formed in an oceanic crustal environment during the late Precambrian. Involvement of older, upper-crustal material in the formation of the ore deposits in this part of the shield is precluded by their low207Pb/204Pb and208Pb/204Pb characteristics. In the eastern part of the shield, east of longitude 44??20???E towards the Al Amar-Idsas fault region, lead data are quite different. They exhibit a linear207Pb/204Pb-206Pb/204Pb relationship together with distinctly higher208Pb/204Pb characteristics. These data imply the existence of lower crustal rocks of early Proterozoic age that apparently have underthrust the shield rocks from the east. If most of the samples we have analyzed from this easterly region were mineralized 530 m.y. ago, then the age of the older continental rocks is 2,100??300 m.y. (2??). The presence of upper crustal rocks, possibly also of early Proterozoic age, is indicated by galena data from Hailan in South Yemen and also

  17. Oceanic Pb-isotopic sources of proterozoic and paleozoic volcanogenic massive sulfide deposits on Prince of Wales Island and vicinity, southeastern Alaska

    USGS Publications Warehouse

    Ayuso, Robert A.; Karl, Susan M.; Slack, John F.; Haeussler, Peter J.; Bittenbender, Peter E.; Wandless, Gregory A.; Colvin, Anna

    2005-01-01

    Volcanogenic massive sulfide (VMS) deposits on Prince of Wales Island and vicinity in southeastern Alaska are associated with Late Proterozoic through Cambrian volcanosedimentary rocks of the Wales Group and with Ordovician through Early Silurian felsic volcanic rocks of the Moira Sound unit (new informal name). The massive sulfide deposits in the Wales Group include the Big Harbor, Copper City, Corbin, Keete Inlet, Khayyam, Ruby Tuesday, and Stumble-On deposits, and those in the Moira Sound unit include the Barrier Islands, Moira Copper, Niblack, and Nichols Bay deposits. Pb-isotopic signatures were determined on sulfide minerals (galena, pyrite, chalcopyrite, pyrrhotite, and sphalerite) to constrain metal sources of the massive sulfides and for comparison with data for other deposits in the region. Except for the Ruby Tuesday deposit, galena is relatively rare in most of these deposits. Pb-isotopic signatures distinguish the mainly Cu+Zn±Ag±Au massive sulfide deposits in the Wales Group from the Zn+Cu±Ag±Au massive sulfide deposits in the Moira Sound unit. Among the older group of deposits, the Khayyam deposit has the widest variation in Pb-isotopic ratios (206Pb/204Pb=17.169–18.021, 207Pb/204Pb=15.341–15.499, 208Pb/204Pb=36.546–37.817); data for the other massive sulfide deposits in the Wales Group overlap the isotopic variations in the Khayyam deposit. Pb-isotopic ratios for both groups of deposits are lower than those on the average crustal Pbevolution curve (µ=9.74), attesting to a large mantle influence in the Pb source. All the deposits show no evidence for Pb evolution primarily in the upper or lower continental crust. Samples from the younger group of deposits have scattered Pb-isotopic compositions and plot as a broad band on uranogenic and thorogenic Pb diagrams. Data for these deposits overlap the trend for massive sulfide deposits in the Wales Group but extend to significantly more radiogenic Pb-isotopic values. Pb-isotopic ratios of

  18. Origin and fate of sulfide liquids in hotspot volcanism (La Réunion): Pb isotope constraints from residual Fe-Cu oxides

    NASA Astrophysics Data System (ADS)

    Vlastélic, I.; Gannoun, A.; Di Muro, A.; Gurioli, L.; Bachèlery, P.; Henot, J. M.

    2016-12-01

    Immiscible sulfide liquids in basaltic magmas play an important role in trace metal transport and the sulfur budget of volcanic eruptions. However, sulfides are transient phases, whose origin and fate are poorly constrained. We address these issues by analyzing sulfide destabilization products preserved in lavas from La Réunion Island. Iron oxide globules and coatings, typically 20-80 μm in size, were found to occur in vesicles of differentiated lavas from Piton des Neiges, and recent pumice samples from Piton de la Fournaise. Field and mineralogical evidence indicates that the iron oxides are syn-eruptive phases not resulting from hydrothermal processes. Samples were first studied by Scanning Electron Microscopy. The globules were separated, whereas the smaller spherules and coatings were concentrated by magnetic sorting and acid leaching, and samples were processed through wet chemistry. The Fe oxide phases comprise 49-74 wt.% Fe, 26-40 wt.% O, and up to 6 wt.% Cu, 811 ppm Ni, 140 ppm Bi, and 8.5 ppm Pb. Compared to the host lava, Cu, Ni, and Bi are enriched by a factor of 101-103. Systematic Pb isotope disequilibrium (between 500 ppm and 2.9% for 206Pb/204Pb) exists between Fe oxides and host rocks, with Fe oxides generally displaying less radiogenic ratios. Unradiogenic Pb is a typical signature of sulfide, which tends to concentrate Pb, but not its parent elements U and Th. Thus, both the chemical and isotopic compositions of the vesicle-hosted Fe oxides suggest that they are more or less direct products of the destabilization of immiscible sulfide liquids. Although Pb dominantly partitions into the gas phase during sulfide breakdown, the original Pb isotope signature of sulfide is preserved in the residual oxide. The composition estimated for the parent sulfides (206Pb/204Pb = 18.20-18.77, 207Pb/204Pb = 15.575, and 208Pb/204Pb = 38.2-38.8) precludes a genetic link with the La Réunion plume, and suggests a lithospheric or crustal origin. It is estimated

  19. Binary mixing of enriched and undegassed (primitive?) mantle components (He, Sr, Nd, Pb) in Samoan lavas

    NASA Astrophysics Data System (ADS)

    Farley, K. A.; Natland, J. H.; Craig, H.

    1992-06-01

    We have measured He, Sr, Nd, and Pb isotope ratios and Rb, Sr, Sm, and Nd concentrations in stratigraphically controlled lavas from the Pago shield volcano on Tutuila, American Samoa. We interpret these lavas as products of mixing between two isotopically extreme mantle constituents. The first is a highly enriched component with very high Sr isotope ratios, low 3He/ 4He ratios, and high "Δ(74)" and "Δ(84)" Pb isotopic characteristics. This is probably recently recycled ( < 400 Ma) crustal material. The second component has high 3He/ 4He ratios ( > 24R A) and intermediate Sr, Nd, and Pb isotopic ratios. This material was derived from a largely undegassed mantle source, and, in conjunction with data from several other ocean islands, provides strong evidence for the existence of a high 3He/ 4He ratio mantle end member (primitive helium mantle, PHEM) with consistent Sr, Nd, and Pb isotopic characteristics: near bulk-earth 87Sr/ 86Sr (0.7042-0.7052) and 143Nd/ 144Nd (0.51265-0.51280,ɛ Nd = +0.2to+3.2), and radiogenic Pb ( 206Pb/ 204Pb˜ 18.5-19.0, 207Pb/ 204Pb˜ 15.5-15.57, 208Pb/ 204Pb˜ 38.4-39.2). Although this material cannot have been derived from a reservoir completely closed to elemental fractionation for the full 4.55 Ga duration of Earth's history, it may indicate the presence of a highly primitive mantle source. Erratic temporal variations in the isotopic composition of individual flows indicate sporadic and variable mixing of these two sources. We interpret these results using a model in which high 3He/ 4He ratio plume material, rising intermittently from a lower-mantle source, intercepts and melts recycled crustal matter in the upper mantle or lithosphere and erupts as a binary mixture of PHEM and the so-called "EM" components derived from this recycled material.

  20. Mantle Heterogeneity and Mixing Beneath the Bouvet Triple Junction Region: Hf Isotope Constraints from the Westernmost Southwest Indian Ridge (0-11deg.E)

    NASA Astrophysics Data System (ADS)

    Janney, P. E.; le Roex, A. P.

    2013-12-01

    We have undertaken new Hf (and supplementary Sr, Nd and Pb) isotope and trace element measurements of MORB from the westernmost Southwest Indian Ridge (SWIR; 0 to 11 deg. E) in order to clarify mixing relationships and the effect of the Bouvet and other local hot spots on the composition of the upper mantle beneath the Bouvet Triple Junction (BTJ) region. The new data are fully consistent with the findings of previous studies (le Roex et al., J. Petrol., 1983; Kurz et al., GCA, 1998) that isotopic heterogeneity in this region is largely explained by mixing between a moderately depleted mantle source (i.e., ɛHf ≈ +14, ɛNd ≈ +9, 87Sr/86Sr ≈ 0.7026; 206Pb/204Pb ≈ 18.5) and an enriched component isotopically similar to Bouvet OIB. Unlike the pattern expressed by He isotopes (Kurz et al., GCA, 1998; Georgen et al., EPSL, 2003) the strength of the Bouvet hot spot signature in terms of Hf-Sr-Nd-Pb isotope ratios is not well correlated with distance from Bouvet Island along ridge, except in the most general sense. Some MORB from 0-11E do approach the Hf-Sr-Nd-Pb isotopic composition of Bouvet OIB. However, the most extreme isotopic compositions (with ɛHf values that are slightly lower than, and Nd and Pb isotope compositions that are equivalent to, those of Bouvet OIB), are actually found in MORB from the 11-16E oblique spreading segment of the SWIR (le Roex et al., CMP, 1992; Janney et al., J. Petrol., 2005), located further from Bouvet Island than the segments at 0-11E. The lack of a strong correlation between the radiogenic isotope ratios of SWIR MORB and proximity to the Bouvet hot spot in this region supports the notion that local conditions of melting of a lithologically heterogeneous mixture of enriched, Bouvet hot spot-derived and depleted mantle materials plays the dominant role in controlling the radiogenic isotope composition of western SWIR MORB (le Roex et al., CMP, 1992; Salters & Dick, Nature, 2002). The depleted mantle present beneath the western

  1. Crustal contamination and mantle source characteristics in continental intra-plate volcanic rocks: Pb, Hf and Os isotopes from central European volcanic province basalts

    NASA Astrophysics Data System (ADS)

    Jung, S.; Pfänder, J. A.; Brauns, M.; Maas, R.

    2011-05-01

    We report new Os-Pb-Hf isotope data for a suite of alkaline to basaltic (nephelinites, basanites, olivine tholeiites to quartz-tholeiites) lavas from the Miocene Vogelsberg (Germany), the largest of the rift-related continental volcanic complexes of the Central European Volcanic Province (CEVP). 187Os/ 188Os in primitive (high-MgO) alkaline lavas show a much wider range than has been observed in alkaline basalts and peridotite xenoliths from elsewhere in the CEVP, from ratios similar to those in modern MORB and OIB (0.1260-0.1451; 58.9-168 ppt Os) to more radiogenic ratios (0.1908 and 0.2197; 27.6-15.1 ppt Os). Radiogenic Os is associated with high ɛ Hf and ɛ Nd, low 87Sr/ 86Sr and does not correlate with Mg ∗ or incompatible trace elements (e.g. Ce/Pb), suggesting the presence of a radiogenic endmember in the mantle rather than crustal contamination as the source of radiogenic Os. This contrasts with another high-Mg alkaline lava characterized by highly radiogenic 187Os/ 188Os (0.4344, 10.3 ppt Os), lower ɛ Hf and ɛ Nd, higher 87Sr/ 86Sr, and Pb isotope signatures than the other alkaline lavas with similar trace element composition suggestive of contamination with crustal material. Hafnium (ɛ Hf: +8.9 to +5.0) and Pb isotope compositions ( 206Pb/ 204Pb: 19.10-19.61; 207Pb/ 204Pb: 15.56-15.60) of the alkaline rocks fall within the range of enriched MORB and some OIB. The Vogelsberg tholeiites show even more diverse 187Os/ 188Os, ranging from 0.1487 in Os-rich olivine tholeiite (31.7 ppt) to ratios as high as 0.7526 in other olivine-tholeiites and in quartz-tholeiites with lower Os concentrations (10.3-2.0 ppt). Low- 187Os/ 188Os tholeiites show Pb-Hf isotope ratios ( 206Pb/ 204Pb:18.81; 207Pb/ 204Pb: 15.61; ɛ Hf: +2.7) that are distinct from those in alkaline lavas with similar 187Os/ 188Os and originate from a different mantle source. By contrast, the combination of radiogenic Os and low 206Pb/ 204Pb and ɛ Hf in the other tholeiites probably reflects

  2. Comparison of the concentrations of metal elements and isotopes of lead found in rice and rice bran.

    PubMed

    Dai, Shouhui; Yang, Hui; Yang, Lan; Wang, Fuhua; Du, Ruiying; Wen, Dian

    2014-08-01

    Very few studies have investigated the difference in the distribution of metal elements between rice and rice bran samples. In this study, the concentrations of 27 metal elements (Li, Be, Na, Mg, Al, K, Ca, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, As, Se, Rb, Sr, Ag, Cd, Cs, Ba, Tl, Pb, and U) in 56 polished rice and their corresponding bran samples were determined. A significant difference in concentrations of all elements except Ag and Cd was found between rice and bran (P < 0.05), with bran/rice ratios of 1.21 to 36.3. High concentrations of metal elements, especially that of the heavy metal Cr, in bran samples present a potential safety issue for bran products, such as food and feed containing bran. Pb isotope ((204)Pb, (206)Pb, (207)Pb, and (208)Pb) ratios also were determined. The (206)Pb/(207)Pb and (208)Pb/(207)Pb ratios in bran were generally higher than those in rice (P < 0.0001), and rice and bran samples were distinctly different from each other, indicating that Pb isotope composition is an effective for discriminating between bran and rice samples.

  3. Lead (Pb) Isotope Baselines for Studies of Ancient Human Migration and Trade in the Maya Region

    PubMed Central

    Kamenov, George D.; Gilli, Adrian; Hodell, David A.; Emery, Kitty F.; Brenner, Mark; Krigbaum, John

    2016-01-01

    We examined the potential use of lead (Pb) isotopes to source archaeological materials from the Maya region of Mesoamerica. The main objectives were to determine if: 1) geologic terrains throughout the Maya area exhibit distinct lead isotope ratios (206Pb/204Pb, 207Pb/204Pb, and 208Pb/204Pb), and 2) a combination of lead and strontium ratios can enhance sourcing procedures in the Mesoamerica region. We analyzed 60 rock samples for lead isotope ratios and a representative subset of samples for lead, uranium, and thorium concentrations across the Maya region, including the Northern Lowlands of the Mexican Yucatan Peninsula, the Southern Lowlands of Guatemala and Belize, the Volcanic Highlands, the Belizean Maya Mountains, and the Metamorphic Province/Motagua Valley. Although there is some overlap within certain sub-regions, particularly the geologically diverse Metamorphic Province, lead isotopes can be used to distinguish between the Northern Lowlands, the Southern Lowlands, and the Volcanic Highlands. The distinct lead isotope ratios in the sub-regions are related to the geology of the Maya area, exhibiting a general trend in the lowlands of geologically younger rocks in the north to older rocks in the south, and Cenozoic volcanic rocks in the southern highlands. Combined with other sourcing techniques such as strontium (87Sr/86Sr) and oxygen (δ18O), a regional baseline for lead isotope ratios can contribute to the development of lead isoscapes in the Maya area, and may help to distinguish among geographic sub-regions at a finer scale than has been previously possible. These isotope baselines will provide archaeologists with an additional tool to track the origin and movement of ancient humans and artifacts across this important region. PMID:27806065

  4. Lead (Pb) Isotope Baselines for Studies of Ancient Human Migration and Trade in the Maya Region.

    PubMed

    Sharpe, Ashley E; Kamenov, George D; Gilli, Adrian; Hodell, David A; Emery, Kitty F; Brenner, Mark; Krigbaum, John

    2016-01-01

    We examined the potential use of lead (Pb) isotopes to source archaeological materials from the Maya region of Mesoamerica. The main objectives were to determine if: 1) geologic terrains throughout the Maya area exhibit distinct lead isotope ratios (206Pb/204Pb, 207Pb/204Pb, and 208Pb/204Pb), and 2) a combination of lead and strontium ratios can enhance sourcing procedures in the Mesoamerica region. We analyzed 60 rock samples for lead isotope ratios and a representative subset of samples for lead, uranium, and thorium concentrations across the Maya region, including the Northern Lowlands of the Mexican Yucatan Peninsula, the Southern Lowlands of Guatemala and Belize, the Volcanic Highlands, the Belizean Maya Mountains, and the Metamorphic Province/Motagua Valley. Although there is some overlap within certain sub-regions, particularly the geologically diverse Metamorphic Province, lead isotopes can be used to distinguish between the Northern Lowlands, the Southern Lowlands, and the Volcanic Highlands. The distinct lead isotope ratios in the sub-regions are related to the geology of the Maya area, exhibiting a general trend in the lowlands of geologically younger rocks in the north to older rocks in the south, and Cenozoic volcanic rocks in the southern highlands. Combined with other sourcing techniques such as strontium (87Sr/86Sr) and oxygen (δ18O), a regional baseline for lead isotope ratios can contribute to the development of lead isoscapes in the Maya area, and may help to distinguish among geographic sub-regions at a finer scale than has been previously possible. These isotope baselines will provide archaeologists with an additional tool to track the origin and movement of ancient humans and artifacts across this important region.

  5. Helium isotope ratios in Easter microplate basalts

    NASA Astrophysics Data System (ADS)

    Poreda, R. J.; Schilling, J. G.; Craig, H.

    1993-09-01

    He-3/He-4 ratios in Easter Microplate basalt glasses show clear evidence of the effects of a mantle plume. The East Rift of the microplate between 26 and 28 deg S, identified by La/Sm, Sr and Pb isotopes and ridge crest elevation as the region of maximum plume influence, has He-3/He-4 ratios spanning the entire range from 7.5 to 11.7 R(sub A). The Easter Microplate is the only section of the entire East Pacific Rise that is associated with a known `hotspot' track (mantle plume) and has elevated He-3/He-4 ratios. Although most of the West Rift basalts contain MORB helium (8.0 - 8.7 (R sub A)), the basalt closest to the East Rift has an elevated He-3/He-4 ratio (11.3 R(sub A)), consistent with a significant plume component. The diversity in isotopic signatures also indicates that homogenization of isotopic anomalies does not occur, even in this region of `super-fast' spreading. The overall He-3/He-4-Pb-206/Pb-204 and He-3/He-4-Sr-87/Sr-86 trends have positive correlations, although the high between the He and Sr isotope distribution is modeled in the context of a plume source-migrating ridge sink. During channeling of the plume toward the ridge, helium if preferentially lost from the center of the channeled plume, resulting in lower He/Pb and He/Sr concentration ratios in the high He-3/He-4 component. Mixing trajectories in He-Sr isotopic space between a LILE depleted asthenosphere and a variably degassed plume component provide a reasonably good fit to the data and may explain the isotope systematics of plume-ridge interactions in the context of modern theories of plume dynamics.

  6. Isotopic composition of Late Mesozoic basic and ultrabasic rocks from the Andes (23-32°S) - implications for the Andean mantle

    NASA Astrophysics Data System (ADS)

    Lucassen, Friedrich; Escayola, Monica; Romer, Rolf; Viramonte, José; Koch, Kerstin; Franz, Gerhard

    2002-02-01

    Mesozoic mantle-derived magmatic rocks from the Jurassic-Early Cretaceous active continental margin of N Chile near 24°S, and from the Cretaceous rift system of NW Argentina near 26°S (central rift) and 32°S (southern rift) are used to constrain the isotopic composition of mantle reservoirs before the onset of the Cenozoic Andean orogeny. They are largely uncontaminated by assimilation of the local Palaeozoic basement as seen in the major and trace element patterns and Sr and Nd isotopic composition of most samples, but small amounts of crustal contamination are detected in the Pb isotope composition. Two different types of mantle sources have been identified. (1) For rocks from the Jurassic arc, now at the continental margin at 24°S, and for rocks from the central rift at 26°S, a depleted mantle source with 143Nd/144Nd(t) 0.5127-0.5128, 87Sr/86Sr(t) ca. 0.7033 may be inferred. Pb isotopic ratios of most samples from the magmatic arc are overall less radiogenic than those from the rift (206Pb/204Pb(t) ca. 18.0-18.4 vs. 18.1-19.1, 207Pb/204Pb(t) 15.55-15.59 vs 15.58-15.64 and 208Pb/204Pb(t) 37.8-38.6 vs. 38.4-38.9). (2) In the southern rift at ca. 30-32°S [Sierras Los Cóndores region (LC) and Sierras Chaján region (Ch)], an enriched mantle source has been identified, which is similar to the composition of the mantle lithosphere beneath the Brazilian Shield. Samples from LC and Ch show some isotopic differences because of varying degrees of crustal contamination in the LC samples. The LC samples have a higher Th/U ratio than the Ch samples and different Pb isotopic ratios 206Pb/204Pb(t) 18.0-18.6 (LC) vs. 17.7 and 17.8 (Ch), 207Pb/204Pb(t) 15.50-15.66 (LC) vs. 15.50 (Ch) and 208Pb/204Pb(t) 38.6-39.2 (LC) vs. ca. 37.5 (Ch). The Nd isotopic ratios of LC and Ch samples are similar 143Nd/144Nd(t) 0.5123-0.5122 (LC) vs. 0.5123 (Ch), whereas their Sr isotopic ratios differ 87Sr/86Sr(t) 0.7054-0.7079 (LC) vs. ca. 0.704 (Ch). Electronic supplementary material to this

  7. Stable lead isotope ratios in Alaskan arctic aerosols

    NASA Astrophysics Data System (ADS)

    Sturges, W. T.; Hopper, J. F.; Barrie, L. A.; Schnell, R. C.

    Aerosol samples collected at Barrow, Alaska, during February and March 1990 were found to have uniform stable lead isotope compositions. The mean 208Pb/ 207Pb ratio was 2.423±0.009 and the mean 206Pb/ 207Pb ratio was 1.161±0.014. The latter ratio is essentially the same as that obtained from an earlier study of aerosols at two Canadian stations in the High Arctic and is typical of, but not unique to, Eurasian sources of atmospheric lead. Further discriminating power was available in this study through the inclusion of 208Pb/ 207Pb ratios, which provided additional evidence that the former Soviet Union and eastern Europe are major contributors to atmospheric particulate lead in the Alaskan Arctic, accounting for around two-thirds of the particulate lead measured at Barrow. The remaining third of the lead is attributed to west European sources. There was no evidence for a substantial North American component, other than local contamination.

  8. Petrogenesis and geodynamics of plagiogranites from Central Turkey (Ekecikdağ/Aksaray): new geochemical and isotopic data for generation in an arc basin system within the northern branch of Neotethys

    NASA Astrophysics Data System (ADS)

    Köksal, Serhat; Toksoy-Köksal, Fatma; Göncüoglu, M. Cemal

    2016-09-01

    In the Late Cretaceous, throughout the closure of the Neotethys Ocean, ophiolitic rocks from the İzmir-Ankara-Erzincan ocean branch were overthrusted the northern margin of the Tauride-Anatolide Platform. The ophiolitic rocks in the Ekecikdaǧ (Aksaray/Central Turkey) region typify the oceanic crust of the İzmir-Ankara-Erzincan branch of Neotethys. The gabbros in the area are cut by copious plagiogranite dykes, and both rock units are intruded by mafic dykes. The plagiogranites are leucocratic, fine- to medium-grained calc-alkaline rocks characterized mainly by plagioclase and quartz, with minor amounts of biotite, hornblende and clinopyroxene, and accessory phases of zircon, titanite, apatite and opaque minerals. They are tonalite and trondhjemite in composition with high SiO2 (69.9-75.9 wt%) and exceptionally low K2O (<0.5 wt%) contents. The plagiogranites in common with gabbros and mafic dykes show high large-ion lithophile elements/high-field strength element ratios with depletion in Nb, Ti and light rare-earth elements with respect to N-MORB. The plagiogranites together with gabbros and mafic dykes show low initial 87Sr/86Sr ratios (0.70419-0.70647), high ƐNd(T) (6.0-7.5) values with 206Pb/204Pb (18.199-18.581), 207Pb/204Pb (15.571-15.639) and 208Pb/204Pb (38.292-38.605) ratios indicating a depleted mantle source modified with a subduction component. They show similar isotopic characteristics to the other supra-subduction zone (SSZ) ophiolites in the Eastern Mediterranean to East Anatolian-Lesser Caucasus and Iran regions. It is suggested that the Ekecikdaǧ plagiogranite was generated in a short time interval from a depleted mantle source in a SSZ/fore-arc basin setting, and its nature was further modified by a subduction component during intra-oceanic subduction.

  9. Mesozoic igneous intrusions in New England and Quebec: Implications from lead (Pb) isotopes on petrogenesis and mantle sources (Ascutney Mountain, Vermont; Mont Saint Hilaire, Quebec; Pliny Complex, New Hampshire)

    SciTech Connect

    Schucker, D.E.

    1992-01-01

    Lead isotopes are used to study Mesozoic intrusions from New England and Quebec, specifically the igneous complexes of Ascutney Mountain (Vermont), Mont Saint Hilaire (Quebec), and Pliny (New Hampshire). The main objectives are to address the: (1) petrogenesis of specific complexes using Pb isotopes along with previous results; and (2) sources of parental magmas in the context of a possible plume source for the Cretaceous intrusions and New England Seamounts. Analytical procedures for Pb and U are also described in detail. For each of the three complexes, significant variation in apparent initial [sup 208]Pb/[sup 204]Pb, [sup 207]Pb/[sup 204]Pb, and [sup 206]Pb/[sup 204]Pb ratios are observed. These variations reflect crustal contamination and local country rocks are isotopically suitable contaminants. Contamination lowers the Pb isotopic ratios of the modified magmas. The Pb ratios of the parental magmas are constrained by defining trends resulting from crustal contamination. At the Ascutney complex, granites appear to be uniform at the time of formation based on feldspar results. Granite whole rocks exhibit open system U-Pb behavior which is attributed to significant recent U loss (of up to 38%). Both local schists and gneisses are important contaminants with generally <25% contamination. Significant isotopic variations are apparent at Mont Saint Hilaire where rock-feldspar variations are apparently not in isotopic equilibrium. Feldspars reflect magmatic values and indicate crustal contamination of a parental magma for the Hilaire complex. A limited data set for the Pliny complex suggests a parental magma. The Pb results support a common mantle source for the Cretaceous continental intrusions (Ascutney and Mont Saint Hilaire) and the New England Seamounts. They imply magma from a sublithospheric mantle-plume, and that magmas ascended with little or no lithospheric interaction. The magma source for the Jurassic Pliny complex appears to be different.

  10. A proposed new approach and unified solution to old Pb paradoxes

    NASA Astrophysics Data System (ADS)

    Castillo, Paterno R.

    2016-05-01

    One of the most remarkable features of many and, perhaps, all oceanic basalts is that their Pb isotopic ratios (206Pb/204Pb, 207Pb/204Pb and 208Pb/204Pb) are too radiogenic to be coming from the undifferentiated mantle or bulk silicate Earth. This has created three major concerns in the behavior of U, Th and Pb in the Earth's mantle that have been termed the Pb paradoxes. These are the unexpectedly long time-integrated high U/Pb (1st paradox), long time-integrated low Th/U (2nd paradox) and constant Ce/Pb and Nb/U (3rd paradox) in the mantle sources of oceanic basalts. The origins of such unexpected ratios have been the object of intense studies that produced several highly significant, but generally individualized results during the last four decades. Detailed analysis of available data shows that the paradoxes are closely interrelated as they all pertain to the mantle and have many common characteristic features. Thus, the Pb paradoxes constitute a system of equations that must be solved all together as each solution must satisfy every equation in the system. For example, compositional data for the voluminous mid-ocean ridge basalts (MORB) show that the 1st and 2nd paradoxes exhibit a long time-integrated enrichment of U and the Th/U and Nb/Th ratios are also constant. A single solution to simultaneously explain the paradoxes in MORB is possible if recycled materials with variable enrichments in incompatible trace elements, particularly U and its daughter Pb* plus Nb, Ce, and Th are added to or mixed with the depleted upper mantle. Significantly, a similar binary mixing solution has been proposed for the Pb paradoxes in ocean island basalts.

  11. Isotopic evidence from lavas and mantle xenoliths for a mixed asthenospheric-lithospheric source for Rio Grande rift magmas

    NASA Astrophysics Data System (ADS)

    Chatterjee, R. N.; Byerly, B. L.; Lassiter, J. C.

    2011-12-01

    Lavas from the Rio Grande rift have a wide range of isotopic compositions from MORB-like to OIB and further enriched values. Most previous studies have interpreted this as reflecting variable melt derivation from asthenospheric and lithospheric mantle sources with temporal evolution related to thinning or delamination of the lithosphere associated with rifting. Alternatively, Wolff et al. (2005) and Crocker et al. (2010) have argued for strong crustal overprinting of the lavas; which swamps the mantle signature and limits our understanding of the mantle evolution beneath the rift. We have examined lavas and mantle xenoliths from West Potrillo, Elephant Butte and Cerro Chato localities of the rift in order to investigate whether the mantle beneath the rift possesses the isotopic signature of the lavas or if crustal inputs are required to explain the enrichments in the lavas. The lavas display a wide range of isotopic composition with 87Sr/86Sr (0.702990-0.704936), 143Nd/144Nd (0.512745-0.512973), 206Pb/204Pb (18.66-19.93), 207Pb/204Pb (15.54-15.66) and 208Pb/204Pb (38.32-39.53). The Elephant Butte lavas are more enriched than the West Potrillo lavas. Clinopyroxene separates from the mantle xenoliths have 87Sr/86Sr (0.701756-0.704455), 143Nd/144Nd (0.512880-0.514040), 206Pb/204Pb (17.99-19.52), 207Pb/204Pb (15.39-15.68) and 208Pb/204Pb (37.46-39.22). The Elephant Butte xenoliths have depleted mantle-like compositions while the Cerro Chato xenoliths are chemically similar to SCLM. The lavas lie on a mixing line between these two end-members in Sr-Nd-Pb space. The isotopic ratios of the lavas are correlated with Sm/Yb, La/Sm and Ba/Nb ratios, which are generally more sensitive to melting processes rather than crustal assimilation. Indices of fractional crystallization such as SiO2 and Mg# are not correlated with the isotopic ratios. The West Potrillo lavas generally have lower SiO2 and higher Sm/Yb compared to Elephant Butte, likely due to a greater depth of melt

  12. Alpha / Mendeleev Ridge and Chukchi Borderland 40Ar/39Ar Geochronology and Geochemistry: Character of the First Submarine Intraplate Lavas Recovered from the Arctic Ocean

    NASA Astrophysics Data System (ADS)

    Mukasa, Samuel B.; Mayer, Larry A.; Aviado, Kimberly; Bryce, Julie; Andronikov, Alex; Brumley, Kelley; Blichert-Toft, Janne; Petrov, Oleg; Shokalsky, Sergey

    2015-04-01

    At least three episodes of magmatic activity have been recognized on the basis of 40Ar/39Ar age determinations in the submarine basaltic samples dredged, drilled or grabbed with a manipulation arm from Alpha / Mendeleev Ridge and Chukchi Borderland of the Arctic Ocean by US Coast Guard Icebreaker Healy, in August-September 2008, and Russian research vessel Captain Dranitsin in August-October 2012: ca. 112 Ma, ca. 100 Ma and ca. 85-73 Ma. Major-oxide and trace-element concentrations, and Pb, Sr, Nd, and Hf isotopic ratios of the recovered lavas provide important constraints on the composition and sources for the original melts. Lavas erupted at ca. 112 Ma (Group 1) have alkali basalt major-oxide compositions. Their low degree of rare-earth-element (REE) fractionation (CeN/YbN = 1.7-2.5), combined with high overall HREE (22-24 times chondrite) and Mg# ~54, suggest derivation from a garnet-free source followed by only minimal crystal fractionation for this group. Pb-Sr-Nd-Hf isotopic systematics of the lavas (206Pb/204Pb = 18.73-18.79; 207Pb/204Pb = 15.54-15.56; 208Pb/204Pb = 38.28-38.35; 143Nd/144Nd = 0.512594-0.512610; 87Sr/86Sr = 0.709458-0.709601; 176Hf/177Hf = 0.283224), together with ratios of highly incompatible trace elements (Th/Ce = 0.09-0.11; Ce/Nb = 2.58-3.09; Th/Nb = 0.24-0.33), point toward a lithospheric source for the magmas. Eruptions at ca. 100 Ma and 85-73 Ma produced two types of lavas: low-Ti tholeiitic basalts - LT, and high-Ti alkali basalts - HT, both assigned to Group 2. This distribution of low- and high-Ti lavas is common in continental flood basalt (CFB) provinces elsewhere, and has been attributed to plume activity in some studies. The trace-element abundance patterns for these Group 2 Arctic lavas are also very similar to those of CFBs elsewhere. Their low degrees of REE fractionation (CeN/YbN = 2.0-3.3) accompanied by progressively decreasing Mg#s (from 53 to 33) suggest a garnet-free source, with the derivative magmas experiencing

  13. Pb-Sr-Nd isotope study of the 100- to 2700-Ma old alkalic rock-carbonatite complexes in the Canadian shield: inferences on the geochemical and structural evolution of the mantle

    SciTech Connect

    Kwon, S.T.

    1986-01-01

    The isotopic signatures of young continental alkalic complexes (CAC) display a remarkable similarity to those of oceanic island basalts (OIB). A study of Sr isotopic evolution showed that the mantle, presumably similar to the source of OIB, beneath the shield appears to have been depleted in large ion lithophile elements (LILE) and to have remained as a closed system since ca. 3000 Ma ago. The present investigations apply Pb and Nd as well as Sr isotopic systems for those complexes to study the secular geochemical evolution of the mantle over the past 2700 million years, and address the question of the processes responsible for the geochemical heterogeneity of the mantle. The data suggest: (1) Like Sr, Pb and Nd isotopic data indicate LILE depleted sources for the southern Canadian shield CAC over at least the past 1900 Ma. (2) Sr, Nd and Pb are compatible with an age of ca. 3000 Ma for the depleted source. (3) In contrast to Sr, and probably Nd, the Pb isotopic data cannot be explained by a closed system model for the depleted mantle source. (4) Coherent fractionation patterns are observed in the mantle sources of CAC since at least 1900 Ma ago: higher U/Pb and Sm/Nd, and lower Th/U and Rb/Sr ratios versus lower U/Pb and Sm/Nd, and higher Th/U and Rb/Sr ratios, indicating OlB-like sources for CAC. (5) The inverse correlation between /sup 206/Pb//sup 204/Pb and /sup 87/Sr//sup 86/Sr initial ratios permit calculation of apparent mean earth Pb isotope ratios with time, which yield 8.35 for the present day /sup 238/U//sup 204/Pb ratio, and 17.82 for /sup 206/Pb//sup 204/Pb. (6) A model for the geochemical and structural evolution of the mantle is based on the diverging isotopic evolution of the midocean ridge basalts (MORB) and OlB sources.

  14. Chronicling a century of lead pollution in Mexico: stable lead isotopic composition analyses of dated sediment cores.

    PubMed

    Soto-Jimenez, Martin F; Hibdon, Sharon A; Rankin, Charley W; Aggarawl, Jugdeep; Ruiz-Fernandez, A Carolina; Paez-Osuna, Federico; Flegal, A Russell

    2006-02-01

    Analyses of lead isotopic compositions (204Pb, 206Pb, 207Pb, and 208Pb) of dated sediment cores from two coastal estuaries and two inland lakes chronicle the predominance of industrial lead emissions in Mexico over the past century. These isotopic ratios exhibit a shift in composition from the turn of the previous century (1900) that corresponds with measurable increases (from 2- to 10-fold) in lead concentrations in the cores above their baseline values (3-22 microg/g)--both changes are consistent with the development of Mexican lead production for export and the manufacture of tetraethyl lead additives for Mexican gasolines. While subsequent changes in lead concentrations in the cores correspond with calculated emissions from the combustion of leaded gasoline in Mexico, isotopic compositions of the cores remain relatively constant throughout most of the 1900s (e.g., 206Pb/207Pb = 1.200 +/- 0.003; 208Pb/207Pb = 2.463 +/- 0.004). That isotopic constancy is attributed to the widespread pollution from lead production in Mexico and the dispersion of some of that lead used as an additive in Mexican gasolines.

  15. Pb, Sr, and Nd isotopes in basalts and sulfides from the Juan de Fuca Ridge

    SciTech Connect

    Hegner, E.; Tatsumoto, M.

    1987-10-10

    Pb, Sr, Nd isotopes of seven basalt glasses collected by the submersible Alvin from the southern Juan de Fuca Ridge (SJFR) are almost identical (/sup 206/Pb//sup 204/Pbapprox.18.45, /sup 207/Pb//sup 204/Pbapprox.15.47, /sup 208/Pb//sup 204/Pbapprox.37.81, /sup 87/Sr//sup 86/Srapprox.0.70249, /sup 143/Nd//sup 144/Ndapprox.0.51315). Whereas all basalts appear cogenetic, four of the samples have uniform abundances of U, Th, Rb, Nd, Sm, Pb, and Sr, indicating that they are also comagmatic. Two basalt glasses dredged previously at the SJFR have similar isotopic compositions but higher concentrations of U, Th, and Pb. The /sup 206/Pb//sup 204/Pb ratios are intermediate between generally less radiogenic ridge basalts from south of the Juan de Fuca Ridge (JFR) and often more radiogenic basalts from the northern JFR and NE Pacific seamounts. Sr and Nd isotopic compositions closely resemble data of other ridge basalts from the northernmost East Pacific Rise and are intermediate between isotopically more diverse seamount basalts produced nearby.

  16. Anthropogenic Pb input into Bohai Bay, China: Evidence from stable Pb isotopic compositions in sediments

    NASA Astrophysics Data System (ADS)

    Hu, Ningjing; Huang, Peng

    2016-04-01

    Anthropogenic Pb input into Bohai Bay, China: Evidence from stable Pb isotopic compositions in sediments Hu Ning-jinga, Huang Pengb,, Liu Ji-huaa, a First Institute of Oceanography, State Oceanic Administration, Qingdao 266061, China b Institute of Oceanology, Chinese Academy of Sciences, Qingdao 266071, China To investigate the source of Pb within Bohai Bay, Pb concentrations and Pb isotopic compositions (204Pb, 206Pb, 207Pb, and 208Pb) of surface sediments in this area were determined. The Pb concentration in this bay varied widely from 6.9 to 39.2 μg/g (average: 21.8 ± 7.8 μg/g), and the Pb isotopic compositions ranged from 0.8338 to 0.8864 (average: 2.0997 ± 0.0180) for 208Pb/206Pb and from 2.0797 to 2.1531 (average: 0.8477 ± 0.0135) for 207Pb/206Pb, presenting in three distinct clusters. The Pb isotopic ratios of sediments from the northeastern (NE zone) and northwestern (NW zone) coastal areas were significantly influenced by anthropogenic sources such as coal combustion and automobile emission. In sediments from the central and southern Bohai Bay (C-S zone); however, Pb mainly originated from the Yellow River catchment, as a result of lithogenic sediment (from rock weathering) accumulation. The Pb isotopic ratios further indicate that, apart from riverine inputs, the neighboring large-scale ports and aerosols significantly contributed to the anthropogenic Pb contained in these sediments. Pb contamination in the Haihe and Luanhe river mouths as well as in the regions near ports is also suggested from anthropogenic enrichment factors. As cities and ports continue to develop around Bohai Bay, a long-term extensive sewage monitoring program is highly recommended.

  17. Lead isotopes and trace metal ratios of aerosols as tracers of Pb pollution sources in Kanpur, India

    NASA Astrophysics Data System (ADS)

    Sen, Indra; Bizimis, Michael; Tripathi, Sachchida; Paul, Debajyoti; Tyagi, Swati; Sengupta, Deep

    2015-04-01

    The anthropogenic flux of Pb in the Earth's surface is almost an order of magnitude higher than its corresponding natural flux [1]. Identifying the sources and pathways of anthropogenic Pb in environment is important because Pb toxicity is known to have adverse effects on human health. Pb pollution sources for America, Europe, and China are well documented. However, sources of atmospheric Pb are unknown in India, particularly after leaded gasoline was phased out in 2000. India has a developing economy with a rapidly emerging automobile and high temperature industry, and anthropogenic Pb emission is expected to rise in the next decade. In this study, we report on the Pb- isotope compositions and trace metal ratios of airborne particulates collected in Kanpur, an industrial city in northern India. The Pb concentration in the airborne particulate matter varies between 14-216 ng/m3, while the other heavy metals vary by factor of 10 or less, e.g. Cd=0.3-3 ng/m3, As=0.4-3.5 ng/m3, Zn=36-161 ng/m3, and Cu=3-22 ng/m3. The 206Pb/207Pb, 208Pb/206Pb, and 208Pb/207Pb vary between 1.112 - 1.129, 2.123-2.141, and 2.409-2.424 respectively, and are highly correlated with each other (R2>0.9). Pb isotopes and trace metal data reveals that coal combustion is the major source of anthropogenic Pb in the atmosphere, with limited contribution from mining and smelting processes. We further conclude that combination of Pb isotope ratios and V/Pb ratios are powerful tracers for Pb source apportionment studies, which is otherwise difficult to differentiate based only on Pb systematics [1] Sen and Peucker-Ehrenbrink (2012), Environ. Sci. Technol.(46), 8601-8609

  18. Mesozoic vein-type Pb-Zn mineralization in the Pyrenees: Lead isotopic and fluid inclusion evidence from the Les Argentières and Lacore deposits

    NASA Astrophysics Data System (ADS)

    Munoz, Marguerite; Baron, Sandrine; Boucher, Adrien; Béziat, Didier; Salvi, Stefano

    2016-03-01

    The Axial Zone of the Pyrenees contains numerous sedimentary-exhalative Pb-Zn deposits formed during the Early Palaeozoic, which have been the subject of several studies. In addition to these, base-metal vein-type mineralizations are also exposed within the Axial Zone metasediments. These deposits, however, have not been investigated in depth and the timing and geodynamic context of their formation has not been specifically addressed. The vein-type Pb-Zn deposits of Les Argentières and Lacore are located in Devonian terranes of the eastern Pyrenees, south of the Mesozoic Aulus basin. They are interpreted as having been emplaced under an extensional setting. They are characterized by silver-rich tetrahedrite that occurs with Pb-Zn sulphides deposited by low-temperature NaCl-CaCl2 brines. Lead isotopic 208Pb/204Pb and 206Pb/204Pb ratios acquired on galena show more radiogenic values compared to those from the Palaeozoic sedimentary-exhalative mineralization, thus indicating younger ages. According to the model ages, the formation of the two deposits may be narrowed down to middle Late Triassic and Late Jurassic periods, respectively, which allows us to argue in favour of the role of pre-Alpine rifting phases in hydrothermal fluids circulation and mineralization deposition in a vein system bounding the Mesozoic Aulus basin.

  19. A study of REE and Pb, Sr and Nd isotopes in garnet-lherzolite xenoliths from Mingxi, Fujian Province

    USGS Publications Warehouse

    Wankang, H.; Junwen, W.; Basu, A.R.; Tatsumoto, M.

    1993-01-01

    The REE and Pb, Sr, Nd isotopes in three xenoliths from limburgite and scoria-breccias, including spinel-lherzolite, spinel-garnet-lherzolite and phlogopite-gamet-lherzolite, were analysed. The REE contents of the xenoliths are 1.3 to 3.3 times those of the chondrites with their REE patterns characterized by weak LREE depletion. The143Nd/144Nd values of whole rocks and minerals range from 0.51306 to 0.51345 with ??Nd=+ 8.2- +15.8,206Pb/204 Pb < 18.673, and207Pb/204Pb < 15.574. All this goes to show that the upper mantle in Mingxi at the depth of 67-82 km is a depleted mantle of MORB type, with87Sr/86 Sr ratios 0.70237-0.70390. In Nd-Sr diagram the data points of whole rocks are all out of the mantle array, implying that the xenoliths from Mingxi have more radiogenic Sr isotopes than those of the mantle array. ?? 1993 Institute of Geochemistry, Chinese Academy of Sciences.

  20. Isotopic (Pb, Sr, Nd, C, O) evidence for plume-related sampling of an ancient, depleted mantle reservoir

    NASA Astrophysics Data System (ADS)

    Chen, Wei; Simonetti, Antonio

    2015-02-01

    The exact mantle source for carbonatite melts remains highly controversial. Despite their predominant occurrence within continental (lithospheric) domains, the radiogenic isotope data from young (< 200 Ma) carbonatite complexes worldwide overlap the fields defined by present-day oceanic island basalts (OIBs). This feature suggests an intimate petrogenetic relationship with asthenospheric mantle. New Pb, Sr, C, and O isotopic data are reported here for constituent minerals from the Oka carbonatite complex, which is associated with the Cretaceous Monteregian Igneous Province (MIP), northeastern North America. The Pb isotope data define linear arrays in Pb-Pb isotope diagrams, with the corresponding Sr isotope ratios being highly variable (0.70314-0.70343); both these features are consistent with open system behavior involving at least three distinct mantle reservoirs. Compared to the isotope composition of known mantle sources for OIBs and carbonatite occurrences worldwide, the least radiogenic 207Pb/204Pb (14.96 ± 0.07) and 208Pb/204Pb (37.29 ± 0.15) isotopic compositions relative to their corresponding 206Pb/204Pb ratios (18.86 ± 0.08) reported here are distinct, and indicate the involvement of an ancient depleted mantle (ADM) source. The extremely unradiogenic Pb isotope compositions necessitate U/Pb fractionation early in Earth's history (prior to 4.0 Ga ago) and growth via a multi-stage Pb evolution model. The combined stable (C and O) and radiogenic isotopic compositions effectively rule out crustal/lithosphere contamination during the petrogenetic history of the Oka complex. Instead, the isotopic variations reported here most likely result from the mixing of discrete, small volume partial melts derived from a heterogeneous plume source characterized by a mixed HIMU-EM1-ADM signature.

  1. Lead isotopic studies of the Samail ophiolite, Oman

    SciTech Connect

    Chen, J.H.; Pallister, J.S.

    1981-04-10

    The isotopic composition of Pb and the concentrations of U, Th, and Pb have been determined for samples from various lithologic units and massive sulfides of the Samail ophiolite. The observed /sup 206/Pb//sup 204/Pb ratios range from 17.90 to 19.06, /sup 207/Pb//sup 204/Pb ratios from 15.43 to 15.63, and /sup 208/Pb//sup 204/Pb from 37.66 to 38.78. In Pb isotopic evolution diagrams, the initial Pb isotopic compositions of most of the samples from the Samail ophiolite plot within the field of oceanic basalt, clearly distinct from island arc data, and define some of the least radiogenic Pb observed from oceanic rocks. Lead data from the Samail are compatible with a model involving magma generation from an oceanic mantle source and formation of the ophiolite at an oceanic spreading center. U--Th--Pb isotopic systematics demonstrate that vertical heterogeneity in the oceanic crust can be created through differential concentration of U, Th, and Pb during crystal fractionation and alteration at, or near, the spreading ridge. Calcite form amygdules in the ophiolite basalt has similar Pb isotopic composition to the igneous rocks, suggesting precipitation of the calcite from seawater which contained Pb derived mostly from the oceanic crust. Lead isotopic data on Fe--Cu sulfides are also similar to the results from the igneous suite suggesting that the source of the sulfides is predominently from the oceanic crust. Lead data from serpentinized peridotite and a galena sample from below the ophiolite suggest that part of the serpentinization process and the formation of galena could involve addition of radiogenic Pb from either a continental source or from oceanic sediments.

  2. Early Cretaceous (ca. 100 Ma) magmatism in the southern Qiangtang subterrane, central Tibet: Product of slab break-off?

    NASA Astrophysics Data System (ADS)

    Li, Yalin; He, Haiyang; Wang, Chengshan; Wei, Yushuai; Chen, Xi; He, Juan; Ning, Zijie; Zhou, Aorigele

    2016-09-01

    The lack of Early Cretaceous magmatic records with high-quality geochemical data in the southern Qiangtang subterrane has inhibited a complete understanding of the magmatic processes and geological evolution of central Tibet. In this study, we present zircon U-Pb ages, whole-rock geochemistry, and Sr-Nd-Pb and zircon Hf isotopic data for the newly discovered Moku pluton in the southern Qiangtang subterrane. Zircon U-Pb dating reveals that the Moku granites were emplaced in the Early Cretaceous (ca. 100 Ma) and are coeval with the hosted dioritic enclaves. The granites are slightly peraluminous and high-K calc-alkaline I-type granites and characterized by initial (87Sr/86Sr)i ratios of 0.70605-0.70658, negative ɛ Nd(t) values (-4.44 to -3.35), and Nd isotopic model ages of 1.19-1.29 Ga. The granites have a wide range of zircon ɛ Hf(t) values (-24.4 to 2.6) and concordant ratios of (206Pb/204Pb)t = 18.645-18.711, (207Pb/204Pb)t = 15.656-15.666, and (208Pb/204Pb)t = 38.751-38.836. The coeval dioritic enclaves are medium- to high-K calc-alkaline rocks with zircon ɛ Hf(t) values of -13.3 to +3.6. The geochemical signatures of the host granites and coeval dioritic enclaves indicate that the Moku pluton was most likely generated by partial melting of the ancient lower crust with contributions from mantle-derived melts. Our new data, together with other recently published data, indicate that the ca. 100 Ma magmatic rocks were derived from anatexis of the Qiangtang lower crust that mixed with upwelling asthenosphere materials in response to the slab break-off of the northward subduction of the Bangong-Nujiang oceanic lithosphere.

  3. Pb, Nd, and Sr isotopic evidence for a multicomponent source for rocks of Cook-Austral Islands and heterogeneities of mantle plumes

    USGS Publications Warehouse

    Nakamura, Y.; Tatsumoto, M.

    1988-01-01

    Sr, Nd, and Pb isotopic compositions were measured in alkaline volcanic rocks (alkali basalt, ankaramite, nephelinite, phonolite, and trachyte) from the South Cook Islands (Aitutaki, Mauke, Rarotonga, Atiu, and Mangaia) and the Austral Islands (Rimatara and Rurutu). The results show that the Cook-Austral rocks have an extremely wide range in isotopic compositions of Pb: 206Pb 204Pb from 18.25 to 21.76, 207pb 204pb from 15.48 to 15.83, and sol208pb 204Pb from 38.37 to 40.62, whereas isotopic compositions of Sr and Nd are less variable. Isotopically, Mangaia, Rimatara, and Rurutu form one group (Mangaia group), which shows extremely radiogenic Pb isotopic compositions but near-MORB (mid-oceanic ridge basalts) values for Sr and Nd isotopic ratios. In contrast, samples from Aitutaki, Rarotonga, Mauke, and Atiu (Aitutaki group) have high 207Pb 204Pb and 208Pb 204Pb and moderately high 87Sr 86Sr (Dupal anomaly). The Aitutaki group could have been derived from heterogeneous mantle plumes, which rose from the enriched deep mantle (the almost primitive lower mantle or recycled continental and oceanic slabs). On the other hand, the Mangaia component could have been derived from the depleted upper mantle which may have been metasomatized with a CO2-rich fluid, as indicated by the near-MORB values of Sr and Nd isotopes. Although Pb isotopic data of the two groups cannot be distinguished from each other statistically, the end components of the Pb-Pb system do not match with those of the Nd-Sr system. Thus, the data must be explained by a multi-, at least three, component mixing model: the mantle plumes (Dupal component and a recycled oceanic slab), metasomatized upper mantle, and lithosphere. The K-Ar ages and isotopic characteristics of the Cook-Austral rocks indicate that if one mantle plume rises from the deep mantle in this region, it has separated into at least two segments on the way to the surface. ?? 1988.

  4. Pb, Nd, and Sr isotopic evidence for a multicomponent source for rocks of Cook-Austral Islands and heterogeneities of mantle plumes

    SciTech Connect

    Nakamura, Yoichi; Tatsumoto, Mitsunobu )

    1988-12-01

    Sr, Nd, and Pb isotopic compositions were measured in alkane volcanic rocks from the South Cook Islands and the Austral Islands. The results show that the Cook-Austral rocks have an extremely wide range in isotopic compositions of Pb: {sup 206}Pb/{sup 204}Pb from 18.25 to 21.76, {sup 207}Pb/{sup 204}Pb from 15.48 to 15.83, and {sup 208}Pb/{sup 204}Pb from 38.37 to 40.62, whereas isotopic compositions of Sr and Nd are less variable. Isotopically, Mangaia, Rimatara, and Rurutu form one group, which shows extremely ratiogenic Pb isotopic compositions but near-MORB (mid-ocean ridge basalts) values for Sr and Nd isotopic ratios. In contrast, samples from Aitutaki, Rarotonga, Mauke, and Atiu (Aitutaki group) have high {sup 207}Pb/{sup 204}Pb and {sup 208}Pb/{sup 204}Pb and moderately high {sup 87}Sr/{sup 86}Sr (Dupal anomaly). The Aitutaki group could have been derived from heterogeneous mantle plumes, which rose from the enriched deep mantle (the almost primitive lower mantle or recycled continental and oceanic slabs). On the other hand, the Mangaia component could have been derived from the depleted upper mantle which may have been metasomatized with a Co{sub 2}-rich fluid, as indicated by the near-MORB values of Sr and Nd isotopes. Although Pb isotopic data of the two groups cannot be distinguished from each other statistically, the end components of the Pb-Pb system do not match with those of the Nd-Sr system. Thus, the data must be explained by a multi-, at least three, component mixing model: the mantle plumes, metasomatized upper mantle, and lithosphere. The K-Ar ages and isotopic characteristics of the Cook-Austral rocks indicate that if one mantle plume rises from the deep mantle in this region, it has separated into at least two segments on the way to the surface.

  5. The geochemical components that distinguish Loa- and Kea-trend Hawaiian shield lavas

    NASA Astrophysics Data System (ADS)

    Frey, Frederick A.; Huang, Shichun; Xu, Guangping; Jochum, Klaus P.

    2016-07-01

    Recent (<5 Ma) Hawaiian volcanoes define two sub-parallel spatial trends, Loa and Kea. Despite the short distance (∼30 km) between adjacent volcanoes on these trends, most of the Loa-trend shield lavas are geochemically distinct from most of the Kea-trend shield lavas. These geochemical differences arise from small amounts of the LOA component in the source of Loa-trend shield lavas. This component is most prominent in the uppermost shield lavas of Koolau, Lanai and Kahoolawe volcanoes. Correlations between abundance ratios of incompatible elements and isotopic ratios of Sr, Nd, Hf and Pb in Hawaiian shield lavas indicate that the LOA component consists of three geochemically distinct materials formed by diverse processes. A gabbroic adcumulate (i.e. no trapped melt) with abundant cumulus plagioclase is responsible for the high Sr/Nd, La/Th and La/Nb in Loa-trend shield lavas relative to Kea-trend shield lavas. Also it has relatively low 206Pb/204Pb and high 208Pb/204Pb at a given 206Pb/204Pb, consistent with the low U/Pb and Th/Pb that are characteristic of plagioclase; these distinctive Pb isotope ratios require a long-time interval, ∼3 Ga, to develop. This material is most abundant in the uppermost shield lavas of Koolau volcano. Possible origins of adcumulate gabbros with abundant cumulus plagioclase are the lower oceanic and continental crust. A second material in the LOA component is distinctive because it is offset from the linear trend of 176Hf/177Hf versus 143Nd/144Nd, known as the terrestrial array, to high 176Hf/177Hf at low 143Nd/144Nd. This offset requires an ancient material with high Lu/Hf. It is equally abundant in the shield lavas at Koolau, Lanai and Kahoolawe volcanoes. Possible origins of this material are ancient pelagic sediment or ancient depleted lithosphere. A third material in the LOA component is characterized by relatively high 87Sr/86Sr, but the Rb/Sr of this material is too low to explain the high 87Sr/86Sr in 4.5 Ga. A relatively

  6. The U, Th and Pb elemental and isotope compositions of mantle clinopyroxenes and their grain boundary contamination derived from leaching and digestion experiments

    NASA Astrophysics Data System (ADS)

    Wittig, Nadine; Pearson, D. Graham; Downes, Hilary; Baker, Joel A.

    2009-01-01

    Minerals from peridotites are known to be affected by trace element contamination on their grain boundaries. In this contribution we investigate the extent and origin of exogenous contamination associated with mantle clinopyroxenes from various localities (Middle Atlas, Beni Bousera [Morocco], Pyrenean Massif, Massif Central [France]) and test the efficacy of different leaching methodologies used to remove this contamination. In doing so we present new U-Th-Pb (double-spike) isotope and trace elemental data of clinopyroxenes and their leachates from spinel-facies sub-continental lithospheric mantle (SCLM, n = 18). Sequential leaching and dissolution of one clinopyroxene separate shows that multiple and short leaching attacks with dilute HCl at moderate temperatures (e.g., 120 °C) interspersed with rigorous ultra-pure water washes do not induce elemental fractionation and are sufficient to remove grain-boundary contamination. Short attacks with very dilute mixtures of HF and HCl induced strong parent/daughter elemental fractionation and significant elemental loss prior to the clinopyroxene digestion with HF/HNO 3. Such leaching is not suitable for studies investigating parent/daughter elemental or isotope ratios of mantle clinopyroxenes. Fluoride co-precipitates that formed in the presence of moderately dilute HF, used during leaching and typical HF/HNO 3 digestions, are an important sink for all trace elements studied here and lock up at least 60% of the trace elements considered. A suite of clinopyroxene-leachate pairs from Moroccan peridotites confirm extreme grain-boundary contamination and show that up to 65% of U, 82% of Th and 91% of Pb, respectively, are of exogenous origin. Pb isotopes of all leachates considered and nearly all reconstructed unleached clinopyroxenes have highly positive Δ7/4 and 207Pb/ 204Pb- 206Pb/ 204Pb systematics reminiscent of enriched mantle (particularly EM II), whereas the corresponding extensively leached clinopyroxenes have very

  7. Geochemical and geochronological constraints on the genesis of Au-Te deposits at Cripple Creek, Colorado

    USGS Publications Warehouse

    Kelley, K.D.; Romberger, S.B.; Beaty, D.W.; Pontius, J.A.; Snee, L.W.; Stein, H.J.; Thompson, T.B.

    1998-01-01

    compositions, together with major and trace element data, indicate that the phonolitic magmas probably evolved by fractional crystallization of an alkali basalt that assimilated lower crustal material. Upper crustal contamination of the magmas was not significant. The 206Pb/204Pb compositions of vein galenas almost entirely overlap those of phonolites, suggesting a genetic relationship between alkaline magmatism and mineralization. However, a trend toward higher 207Pb/204Pb (15.57-15.60) and 208Pb/204Pb ratios (38.94-39.48) of some galenas suggests a contribution to the ore fluid from surrounding Early Proterozoic rocks, probably through leaching by mineralizing fluids. Limited stable isotope compositions of quartz, K feldspar, and biotite from this and previous studies support a largely magmatic origin for the early vein fluids. It is suggested that three features were collectively responsible for generating alkaline magmas and associated mineral deposits: (1) the timing of magmatism and mineralization, which coincided with the transition between subduction-related compression and extension related to continental rifting; (2) the location of Cripple Creek at the junction of four major Precambrian units and at the intersection of major northeast-trending regional structures with northwest-trending faults, which served as conduits for magmas and subsequent hydrothermal fluids; and (3) the complex magmatic history which included emplacement of relatively felsic magmas followed by successively more mafic magmas with time.

  8. Coexistence of galenas with different Pb isotopic composition in Los Pedroches batholith area (Spain)

    NASA Astrophysics Data System (ADS)

    García de Madinabeitia, S.; Santos Zalduegui, J. F.; Larrea, F. J.; Carracedo, M.; Gil Ibarguchi, J. I.

    2003-04-01

    The Los Pedroches batholith region (S Spain) includes three separated mining districts: Linares, La Carolina and Los Pedroches. The Pb isotopic composition of thirty-three galenas from this sector has been measured. On the basis of the Pb data two types of mineralization are established. A first type including: (i) the Linares and La Carolina districts where ore-bearing filons cut Hercynian granites or their hostrocks (SE of the batholith), and (ii) the so-called "peribatholithic" ore bodies represented by scarce mines in the host-rock of the batholith; all of them exhibit homogeneous Pb isotopic compositions of: 206Pb/204Pb = 18.236, 207Pb/204Pb = 15.615, 208Pb/204Pb = 38.347 and a model age of ca. 324 Ma. The second type is represented by a huge N120^oE hydrotermal vein (the El Zumajo vein) intrusive in granitoid bodies of the batholith; the Pb isotopic composition of the vein is: 206Pb/204Pb = 18.457, 207Pb/204Pb = 15.636, 208Pb/204Pb = 38.611 and a model age of ca. 201 Ma. Analysed K-feldspars from batholithic granodiorite and granites have Pb isotopic compositions similar to those reported previously from Hercynian granites of the area (1) and to the galenas of Linares, La Carolina and "peribatholithic" ores. The whole dataset reveals a Pb evolution curve with μ_2 = 9.8 and ω_2 = 38.3, close to the model curve for the "orogen" (2). This suggests for Linares, La Carolina and the "peribatholithic" mineralizations a Pb source related to that of the granites. The pre-Tremadoc metasedimentary rocks of the area, with Pb isotopic composition (3) very close to that of feldspars and galenas studied is proposed as a possible source of Pb for both the granites and associated mineralizations, although the Pb isotopic composition of El Zumajo calls for a different origin. The observed difference in Pb isotopic ratios of the studied galenas points to, at least, two ore-forming events: (i) one relating older mineralizations and granitoid intrusives, in agreement with

  9. Trace Metals, Rare Earths, Carbon and Pb Isotopes as Proxies of Environmental Catastrophe at the Permian - Triassic Boundary in Spiti Himalayas, India

    NASA Astrophysics Data System (ADS)

    Ghosh, N.; Basu, A. R.; Garzione, C. N.; Ghatak, A.; Bhargava, O. N.; Shukla, U. K.; Ahluwalia, A. D.

    2015-12-01

    Himalayan sediments from Spiti Valley, India preserve geochemical signatures of the Permian - Triassic (P-Tr) mass extinction in the Neo-Tethys Ocean. We integrate new sedimentological and fossil record with high-resolution geochemical-isotopic data from Spiti that reveals an ecological catastrophe of global proportions. Trace elements of U, Th, Nb, Ta, Zr, Hf, the rare earths (REE) and carbon, oxygen and lead isotopes measured across the P-Tr boundary in Spiti are used as proxies for evaluating abrupt changes in this continental shelf environment. δ13Corg excursions of 2.4‰ and 3.1‰ in Atargu and Guling P-Tr sections in Spiti Valley are associated with an abrupt fall of biological productivity while δ13Ccarb and δ18Ocarb record of these sediments shows effects of diagenesis. Here, the P-Tr boundary is compositionally distinct from the underlying Late Permian gray shales, as a partly gypsiferous ferruginous layer that allows additional geochemical-isotopic investigation of sedimentary sources. Conspicuous Ce - Eu anomalies in the light REE-enriched Late Permian shales reflect the source composition of the adjacent Panjal Trap basalts of Kashmir. An abrupt change of this source to continental crust is revealed by Nb - Ta and Zr - Hf anomalies at the P-Tr ferruginous layer and continuing through the overlying Early Triassic carbonate rocks. Pb concentration and isotope ratios of 206Pb/204Pb, 207Pb/204Pb and 208Pb/204Pb identify changes in the sedimentary element flux, distinguishing the Late Permian shales from the distinct siliciclastic continental crustal signature in the Early Triassic carbonates. These geochemical-isotopic constraints on the sedimentary geochemistry of one of the most critical transitions in geological record establish the utility of multi-proxy datasets for paleoenvironmental reconstructions.

  10. Petrogenesis and tectonic setting of the early Mesozoic Xitian granitic pluton in the middle Qin-Hang Belt, South China: Constraints from zircon U-Pb ages and bulk-rock trace element and Sr-Nd-Pb isotopic compositions

    NASA Astrophysics Data System (ADS)

    Wu, Qianhong; Cao, Jingya; Kong, Hua; Shao, Yongjun; Li, Huan; Xi, Xiaoshuang; Deng, Xuantong

    2016-10-01

    The Xitian pluton in southeast Hunan province is one of the early Mesozoic (Indosinian) granitic plutons in the South China Block. It is composed of biotite adamellite with K-feldspar megacrysts, biotite adamellite, and biotite granite that have U-Pb zircon ages of 229.9 ± 1.4 Ma, 223.6 ± 1.3 Ma, and 224.0 ± 1.4 Ma, respectively. The Indosinian granitoids in the Xitian pluton belong to S-type granites, with highly radiogenic initial 87Sr/86Sr ratios (0.71397-0.71910), negative εNd(t) values ranging from -10.1 to -9.4, and old Nd model ages (1858-1764 Ma). They are enriched in radiogenic Pb isotopes, with (206Pb/204Pb)t ranging from 18.130 to 18.903, (207Pb/204Pb)t from 15.652 to 15.722, and (208Pb/204Pb)t from 38.436 to 39.037, respectively. These features indicate that the granitoidswithin the Xitian pluton were formed from magmas generated by remelting of metapelite and metapsammite of the Paleoproterozoic metamorphic basement at temperatures of ca. 800 °C, with low oxygen fugacity. The Sr-Nd isotopic compositions of the rocks from Xitian pluton indicate that the granitic magmas were mixed with less than 10% mantle-derived magmas. We suggest that the Xitian pluton was emplaced in an extensional tectonic setting related to release of compressional stresses within the thickened crust during the early Mesozoic.

  11. Exotic lamproites or normal ultrapotassic rocks? The Late Miocene volcanic rocks from Kef Hahouner, NE Algeria, in the frame of the circum-Mediterranean lamproites

    NASA Astrophysics Data System (ADS)

    Lustrino, Michele; Agostini, Samuele; Chalal, Youcef; Fedele, Lorenzo; Stagno, Vincenzo; Colombi, Francesco; Bouguerra, Abdellah

    2016-11-01

    The late Miocene (11-9 Ma) volcanic rocks of Kef Hahouner, 40 km NE of Constantine (NE Algeria), are commonly classified as lamproites in literature. However, these rocks are characterized by an anhydrous paragenesis with plagioclase and Mg-rich olivine phenocrysts, set in a groundmass made up of feldspars, pyroxenes and opaque minerals. Thus, we classify the Kef Hahouner rocks as ultrapotassic shoshonites and latites, having K2O > 3 wt.%, K2O/Na2O > 2.5, MgO > 3-4 wt.%, SiO2 < 55-57 wt.% and SiO2/K2O < 15. All the investigated samples show primitive mantle-normalized multi-element patterns typical of orogenic (arc-type) magmas, i.e. enriched in LILE (e.g. Cs, Rb and Ba) and LREE (e.g. La/Yb = 37-59) with respect to the HFSE, peaks at Pb and troughs at Nb and Ta. Initial isotopic ratios are in the range of 87Sr/86Sr = 0.70874-0.70961, 143Nd/144Nd = 0.51222-0.51223, 206Pb/204Pb = 18.54-18.60, 207Pb/204Pb = 15.62-15.70 and 208Pb/204Pb = 38.88-39.16. The Kef Hahouner volcanic rocks show multi-element patterns similar to the other circum-Mediterranean lamproites and extreme Sr, Nd and Pb isotopic compositions. Nevertheless, the abundant plagioclase, the presence of Al-rich augite coupled with high Al2O3 whole rock compositions (9.6-21.4 wt.%), and the absence of phlogopite are all at inconsistent with the definition of lamproite. We reviewed the rocks classified as lamproites worldwide, and found that many of these rocks, as for the Kef Hahouner samples, should be actually defined as "normal" potassic to ultrapotassic volcanic rocks. Even the grouping of lamproites into "orogenic" and "anorogenic" types appears questionable.

  12. Mt. St. Augustine, Alaska: Geochemical evolution of an eastern Aleutian volcanic center

    SciTech Connect

    Johnson, K.E. . Dept. of Geology); Harmon, R.S. . Kingsley Dunham Centre); Moorbath, S. . Dept. of Earth Sciences); Sigmarsson, O. )

    1993-04-01

    Mt. St. Augustine is a calc-alkaline Quaternary volcano, situated within Cook Inlet, Alaska. The island is composed of low- to medium-K andesite and dacite domes and pyroclastic flows. Major element variations indicate the magmatic evolution is dominantly influenced by fractionation and magma-mixing processes. Incompatible element and isotopic compositions suggest that despite its continental location, crustal assimilation is not significant factor in magmatic evolution. Alkali contents for Augustine are generally lower than elsewhere in the Aleutians (e.g. Augustine Cs/Rb = 0.016--0.024, K/Rb = 372--553; Aleutians Cs/Rb = 0.016--0.17, K/Rb = 231--745). Sr- and Nd-isotope ratios encompass narrow ranges ([sup 87]Sr/[sup 86]Sr = 0.70317--0.70343; [sup 143]Nd/[sup 144]Nd = 0.513011--0.513085), characteristic of uncontaminated mantle-derived melts. U-Th disequilibrium isotopic values also indicate little or no assimilation of evolved continental crust. Pb-isotopic ranges are also relatively restricted ([sup 206]Pb/[sup 204]Pb = 18.62--18.82; [sup 207]Pb/[sup 204]Pb = 15.54--15.57; [sup 208]Pb/[sup 204]Pb = 38.18--38.34) and comparison with north Pacific enriched (OIB) and depleted (MORB) mantle sources suggest the incorporation of only a small percentage of subducted terrigenous sediments. A model for Augustine magma genesis is proposed where parental magmas are generated by 5--20% partial melting of a lherzolite mantle with up to a 5% subducted terrigenous sediment component. The major influence of the thickened continental crust is to prevent the ascent and eruption of basaltic magma. The data exhibit no temporal variations, indicating that the magmatic system which produced the historic eruptions is well established.

  13. Oceanic mafic magmatism in the Siletz terrane, NW North America: Fragments of an Eocene oceanic plateau?

    NASA Astrophysics Data System (ADS)

    Phillips, Bethan A.; Kerr, Andrew C.; Mullen, Emily K.; Weis, Dominique

    2017-03-01

    The Siletz terrane, a predominantly mafic accreted oceanic terrane, is located in the Cascadia forearc region of Oregon, Washington and Vancouver Island. The terrane represents a late Palaeocene-Eocene large igneous province that consists of pillow lavas, massive flows and intrusive sheets. Previously it has been proposed that the Siletz terrane represents either an accreted oceanic plateau, hotspot island chain, backarc basin, island arc, or a sequence of slab window volcanics. A province-wide geochemical reassessment of the terrane, including new high precision Sr-Pb-Nd-Hf isotope data, has been used to assess the validity of the proposed tectonomagmatic models for the Siletz terrane. The trace element data show little evidence of crustal contamination, or an arc signature, and the samples have rare earth element (REE) patterns that are flat to light REE enriched. These features are similar to other oceanic plateaus such as the Ontong Java and the Caribbean. Initial isotope ratios range from 206Pb/204 Pb: 18.751 to 19.668, 207Pb/204Pb: 15.507 to 15.661, 208Pb/204Pb: 38.294 to 39.2128, 176Hf/177Hf: 0.28300 to 0.28316 (εHf: 9.0 to 14.5), 143Nd/144Nd: 0.51282 to 0.51299 (εNd: 5.0 to 8.1) and 87Sr/86Sr: 0.70302 to 0.70380. These data are consistent with a mantle source of the Siletz terrane that appears to have been heterogeneous and slightly enriched. The enriched signature has characteristics of both EM2 and HIMU components and this, combined with a calculated mantle potential temperature well above ambient mantle, indicates derivation of the Siletz magmatism from a mantle plume, possibly the Yellowstone Hotspot. We therefore conclude that the Siletz terrane represents an accreted oceanic plateau.

  14. Using biochemical and isotope geochemistry to understand the environmental and public health implications of lead pollution in the lower Guadiana River, Iberia: a freshwater bivalve study.

    PubMed

    Company, R; Serafim, A; Lopes, B; Cravo, A; Shepherd, T J; Pearson, G; Bebianno, M J

    2008-11-01

    Lead is a natural component of aquatic ecosystems with no known biological role and is highly toxic. Its toxicity stems from its ability to mimic biologically important metals and to produce membrane damage through lipid peroxidation (LPO). Most lead poisoning symptoms are thought to occur by interfering with an essential enzyme, delta-aminolevulinic acid dehydratase (ALAD), the activity of which is markedly inhibited by lead. The purpose of this work was to study the levels and effects of lead pollution (responses of ALAD and oxidative stress biomarker LPO) in the freshwater bivalve Corbicula fluminea along the lower Guadiana River (Portugal and Spain); a major river system impacted by historic mining pollution and more recent anthropogenic inputs. The results show that the enzymatic activity of ALAD is negatively correlated with the total Pb concentration of the whole tissue suggesting that ALAD has considerable potential as a biomarker of lead exposure in C. fluminea. To identify the sources of lead to which bivalves have been exposed, high precision (206)Pb/(204)Pb, (207)Pb/(204)Pb, (208)Pb/(204)/Pb ratios for C. fluminea confirm that historical mining activities in the Iberian Pyrite Belt are the dominant source of lead pollution in the lower Guadiana River. The isotope patterns however exhibit marked seasonal and geographic variation in response to rainfall and river water management. Locally, other anthropogenic sources of lead have been detected in C. fluminea close to population centres, thus adding to its versatility as a freshwater bio-indicator. Overall, the study highlights the value of natural ecosystems as monitors of water quality and their importance for public health assessment and surveillance.

  15. Tracing lead pollution sources in abandoned mine areas using stable Pb isotope ratios.

    PubMed

    Yoo, Eun-Jin; Lee, Jung-A; Park, Jae-Seon; Lee, Khanghyun; Lee, Won-Seok; Han, Jin-Seok; Choi, Jong-Woo

    2014-02-01

    This study focused on Pb isotope ratios of sediments in areas around an abandoned mine to determine if the ratios can be used as a source tracer. For pretreatment, sediment samples were dissolved with mixed acids, and a multi-collector inductively coupled plasma mass spectrometer (MC-ICP-MS, Nu plasma II) was used to investigate the Pb isotopic composition of the samples. The measured isotope ratios were then corrected for instrumental mass fractionation by measuring the (203)Tl/(205)Tl ratio. Repeated measurements with the NIST SRM 981 reference material showed that the precision of all ratios was below 104 ppm (±2σ) for 50 ng/g. The isotope ratios ((207)Pb/(206)Pb) found were 0.85073 ± 0.0004~0.85373 ± 0.0003 for the main stream, while they were 0.83736 ± 0.0010 for the tributary and 0.84393 ± 0.0002 for the confluence. A binary mixing equation for isotope ratios showed that the contributions of mine lead to neighboring areas were up to 60%. Therefore, Pb isotope ratios can be a good source tracer for areas around abandoned mines.

  16. Pb isotope geochemistry of Piton de la Fournaise historical lavas

    NASA Astrophysics Data System (ADS)

    Vlastélic, Ivan; Deniel, Catherine; Bosq, Chantal; Télouk, Philippe; Boivin, Pierre; Bachèlery, Patrick; Famin, Vincent; Staudacher, Thomas

    2009-07-01

    Variations of Pb isotopes in historical lavas (1927-2007) from Piton de la Fournaise are investigated based on new (116 samples) and published (127 samples) data. Lead isotopic signal exhibits smooth fluctuations (18.87 < 206Pb/ 204Pb < 18.94) on which superimpose unradiogenic spikes ( 206Pb/ 204Pb down to 18.70). Lead isotopes are decoupled from 87Sr/ 86Sr and 143Nd/ 144Nd, which display small and barely significant variations, respectively. No significant change of Pb isotope composition occurred during the longest (> 3 years) periods of inactivity of the volcano (1939-1942, 1966-1972, 1992-1998), supporting previous inferences that Pb isotopic variations occur mostly during and not between eruptions. Intermediate compositions (18.904 < 206Pb/ 204Pb < 18.917) bracket the longest periods of quiescence. In this respect, the highly frequent occurrence of an intermediate composition (18.90 < 206Pb/ 204Pb < 18.91), which clearly defines an isotopic baseline during the most recent densely sampled period (1975-2007), either suggests direct sampling of plume melts or sampling of a voluminous magma reservoir that buffers Pb isotopic composition. Deviations from this prevalent composition occurred during well-defined time periods, namely 1977-1986 (radiogenic signature), 1986-1990 and 1998-2005 (unradiogenic signatures). The three periods display a progressive isotopic drift ending by a rapid return (mostly during a single eruption) to the isotopic baseline. The isotopic gradients could reflect progressive emptying of small magma reservoirs or magma conduits, which are expected to be more sensitive to wall-rock interactions than the main magma chamber. These gradients provide a lower bound ranging from 0.1 to 0.17 km 3 for the size of the shallow magma storage system. The isotopic shifts (March 1986, January 1990 and February 2005) are interpreted as refilling the plumbing system with deep melts that have not interacted with crustal components. The volume of magma

  17. Variations in Pb concentrations and Pb-isotope ratios in soils collected along an east-west transect across the United States

    NASA Astrophysics Data System (ADS)

    Smith, David; Woodruff, Laurel; Reimann, Clemens; Flem, Belinda

    2014-05-01

    Soil A-horizon and C-horizon samples were collected along a 4000 km long transect cutting the USA from the west to the east coast. For purposes of site selection, the transect was divided into approximately 40-km segments. For each segment, a 1-km2 target area was selected at random. Soil A- and C-horizon samples were collected at a site within each target area that was most representative of the surrounding landscape. The samples were air-dried at ambient temperature, disaggregated, and sieved through a 2-mm stainless steel screen. The <2-mm material was crushed to <150 µm in a ceramic mill prior to chemical analysis. Lead was analyzed in all the A- and C-horizon samples by inductively coupled plasma-mass spectrometry following a 4-acid digestion. The complete dataset can be found in Smith et al., 2005. Pb-isotope ratio measurements were carried out on 159 soil A-horizon and 137 soil C-horizon samples on an inductively coupled sector field plasma mass spectrometer (SF-ICP-MS; ELEMENT 1, Finnigan MAT) in the laboratory of the Geological Survey of Norway (NGU), following a 7 N HNO3 digestion. Lead concentrations along the transect show (1) generally higher values in the soil A-horizon than the C-horizon (median 21 vs. 16.5 mg/kg), (2) an increase in the median value of the soil A-horizon for the central to eastern U.S. (Missouri to Maryland) when compared to the western U.S. (California to Kansas) (median 26 vs. 20 mg/kg) and (3) a higher A/C ratio for the central to eastern US (1.35 vs. 1.14). Lead isotopes show a distinct trend across the U.S., with the highest 206Pb/207Pb ratios occurring in the centre (Missouri, median A-horizon: 1.245; C-horizon: 1.251) and the lowest at both coasts (e.g. California, median A-horizon: 1.195; C-horizon:1.216). The soil C-horizon samples show generally higher 206Pb/207Pb ratios than the A-horizon (median C-horizon: 1.224; A-horizon: 1.219). The 206Pb/207Pb isotope ratios in the soil A horizon show a correlation with the total

  18. Petrogenesis of pillow basalts from Baolai in southwestern Taiwan

    NASA Astrophysics Data System (ADS)

    Liu, Chih-Chun; Yang, Huai-Jen

    2016-04-01

    The pillow basalts from Baolai in southwestern Taiwan have been inferred to bear Dupal signautres based on their Th/Ce ratio, linking the Baolai basalts to the South China Sea (SCS) seamounts that are characterized by Dupal Pb isotope signatures (Smith and Lewis, 2007). In this study, thirty-two Baolai basalt samples were analyzed for abundances of major and trace elements as well as Pb and Nd isotope ratios to verify their Dupal characters and to constrain their petrogenesis significance. The Baolai basalts contain 4-10 % L.O.I.. Three stages of alteration are inferred from plots of L.O.I. abundance versus concentrations major oxides as well as mineral textures and compositions. The first alteration stage was characterized by albitization that converted Ca-rich plagioclase to albite. The second alteration stage was dominated by chloritization of olivine and augite, resulting in increases in L.O.I. abundance. The last alteration stage is represented by formation of secondary calcite in vesicles and cracks. These alteration processes reflect interaction with seawater and apparently did not affect the magmatic Pb isotope composition for the low Pb concentration in seawater. Relative to the North Hemisphere Reference Line (NHRL), the Baolai pillow basalts have higher 208Pb/204Pb ratios at a given 206Pb/204Pb value, showing Dupal anomaly. For their relatively higher 208Pb/204Pb, 207Pb/204Pb, and 206Pb/204Pb ratios, the Baolai basalts are distinct from majority of the Cenozoic basalts in the Hainan-Leizhou peninsula, the Indochina peninsula, and the SCS seamounts, for which derivation from the Hainan mantle plume has been recently proposed (Wang et al., 2013). In contrast, the Baolai basalts and the Cenozoic basalts from eastern Guangdong at southeastern China have similar Pb and Nd isotope compositions, indicating derivation from similar mantle sources. However, the Baolai basalts have lower abundance ratios of Zr/Hf (40.3-45.6 versus 46.5-50.5), La/Yb (12

  19. U-Th-Pb and Rb-Sr systematics of Allende and U-Th-Pb systematics of Orgueil

    USGS Publications Warehouse

    Tatsumoto, M.; Unruh, D.M.; Desborough, G.A.

    1976-01-01

    U-Th-Pb systematics study of Allende inclusions showed that U, Th and Sr concentrations in Ca, Al (pyroxene)-rich chondrules and white and pinkish-white aggregate separates of Allende are five to ten times higher than those of the matrix, whereas Mg (olivine)-rich chondrules have U and Th concentrations about twice as high as the matrix. Th concentrations are extremely high in white aggregates and in pinkish-white (spinel-rich) aggregates while U and Sr concentrations in white aggregates are more than twice as high as those in pinkish-white aggregates. Large enrichment of these refractory elements in the white aggregates indicates that they contain high-temperature condensates from the solar nebula. The Pb concentrations in the inclusions are less than half of those in the whole rock and matrix, indicating that the matrix is a lower-temperature condensate. The isotopic composition of lead in the matrix is less radiogenic than that of the whole meteorite, whereas lead in Ca- and Al-rich chondrules and aggregates is extremely radiogenic. The 206Pb/204Pb ratio reaches as high as 55.9 in a white aggregate separate. The lead of Mg-rich chondrules is moderately radiogenic and the 206Pb/204Pb ratio ranges from 18 to 26. A striking linear relationship exists among leads in the chondrules, aggregates and matrix on the 207Pb/204Pb vs 204Pb/204Pb plot. The slope of the best fit line is 0.6188 ?? 0.0016, yielding an isochron age of 4553 ?? 4 m.y. The regression line passes through primordial lead values obtained from Canyon Diablo troilite. The data, when corrected for Canyon Diablo troilite Pb and plotted on a U-Pb concordia diagram, show that the pink and white aggregates and the Ca-Al-rich and Mg-rich inclusions have excess Pb and define a chord which intersects the concordia curve at 4548 ?? 25 m.y. and 107 ?? 70 m.y. The intercepts might correspond to the agglomeration age of the meteorite and a time of probably later disturbance, respectively. The matrix and some

  20. Application of lead and strontium isotope ratio measurements for the origin assessment of uranium ore concentrates.

    PubMed

    Varga, Zsolt; Wallenius, Maria; Mayer, Klaus; Keegan, Elizabeth; Millet, Sylvain

    2009-10-15

    Lead and strontium isotope ratios were used for the origin assessment of uranium ore concentrates (yellow cakes) for nuclear forensic purposes. A simple and low-background sample preparation method was developed for the simultaneous separation of the analytes followed by the measurement of the isotope ratios by multicollector inductively coupled plasma mass spectrometry (MC-ICPMS). The lead isotopic composition of the ore concentrates suggests applicability for the verification of the source of the nuclear material and by the use of the radiogenic (207)Pb/(206)Pb ratio the age of the raw ore material can be calculated. However, during data interpretation, the relatively high variation of the lead isotopic composition within the mine site and the generally high contribution of natural lead as technological contamination have to be carefully taken into account. The (87)Sr/(86)Sr isotope ratio is less prone to the variation within one mine site and less affected by the production process, thus it was found to be a more purposeful indicator for the origin assessment and source verification than the lead. The lead and strontium isotope ratios measured and the methodology developed provide information on the initial raw uranium ore used, and thus they can be used for source attribution of the uranium ore concentrates.

  1. A lead isotopic study of the Stillwater Complex, Montana: constraints on crustal contamination and source regions

    USGS Publications Warehouse

    Wooden, J.L.; Czamanske, G.K.; Zientek, M.L.

    1991-01-01

    Analyses of the Pb isotopic compositions of plagioclase from 23 samples covering the stratigraphic thickness of the Stillwater Complex indicate a narrow range of apparent initial isotopic compositions (206Pb/ 204Pb=13.95; 207Pb/204Pb=14.95-15.01; 208Pb/204Pb=33.6). The uniformity of our data is in contrast to, but not necessarily contradictory to, other recent investigations which give indications that the complex formed by repeated injection of magmas with at least two distinct compositions that were presumably derived from different source regions. Samples from the Basal series of the complex have consistently higher 207Pb/204Pb ratios, suggesting either minor contamination from adjacent country rocks or a slight distinction between parental magmas. Apparent initial Pb isotopic compositions of the complex are very radiogenic compared to Late Archean model-mantle values, but are nearly identical to initial Pb isotopic compositions found for the the adjacent, slightly older (2.73-2.79 Ga), Late Archean crustal suite in the Beartooth Mountains. Contamination of magmas parental to the Stillwater Complex by the Late Archean crustal suite is rejected for two reasons: (1) Th and U concentrations in Stillwater rocks and plagioclase are very low (about 0.08 and 0.02 ppm respectively), yet Th/U ratios are uniform at about 4, in contrast to the highly variable (2-26) but often high Th/U ratios found for the Late Archean crustal complex; (2) it seems improbable that any contamination process would have adjusted the isotopic compositions of the diverse magmas entering the Stillwater chamber to near-identical values. The preferred hypothesis to explain the Pb isotopic data for the Stillwater Complex and the associated Late Archean crustal suite involves a major Late Archean crust-forming event that resulted in a compositionally complex crust/mantle system with relatively homogeneous and unusual Pb isotopic compositions. The parental magmas of the Stillwater Complex were

  2. The Condor seamount at Mid-Atlantic Ridge as a supplementary source of trace and rare earth elements to the sediments

    NASA Astrophysics Data System (ADS)

    Caetano, Miguel; Vale, Carlos; Anes, Bárbara; Raimundo, Joana; Drago, Teresa; Schimdt, Sabine; Nogueira, Marta; Oliveira, Anabela; Prego, Ricardo

    2013-12-01

    The Condor Seamount rises from seabed to 180m water depth, being located 10 nautical miles southwest of the island of Faial, Azores Archipelago at the Mid-Atlantic Ridge (MAR). The vertical distribution of major, minor, trace and rare earth elements (REE) and Pb isotopes was studied in four sediment cores: one from the top of the Condor Seamount (200m, MC9), two from the seamount base (1400m, MC2 and MC4), and one from a deep area (1900m, MC8). Sediments from the top of the Condor were composed by coarser particles being the fine fraction lower than 1%. Conversely the other sediments were constituted by 51-92% of fine particles (<63μm). Individual fragments of volcanic material (>2mm) were found at several depths of the cores sampled at the base of the seamount. The core collected in the top of the Condor showed higher carbonate content (76-86%) compared with the other cores (41-64%). The chemical compositions of MC2 and MC4 point to an enhancement of V, Cr, Co, Ni and Fe concentrations. Lower concentrations in MC8 hypothesis that Condor seamount constitutes a supplementary source of trace elements. The most plausible explanation for the enhancement found in sediments of the seamount base is the weathering of slopes with volcanic activities, which supply particles with higher element concentrations than pelagic sediments. This hypothesis is corroborated by REE data, showing increased chondrite normalized ratios in MC2 and MC4. Moreover, the REE pattern found in those cores was comparable to that existing in volcanic material with Light REE enrichment in comparison to Heavy REE. These results indicate a substantial contribution of particles derived from volcanic activities to sediments settled in the vicinity of the Condor Seamount. It is argued the potential use of REE in sediments from this region as tracers of volcanic activities. Depth profiles of 206Pb/207Pb and 206Pb/208Pb showed lower ratios in the first 8cm sediment layers, reflecting atmospheric input of

  3. Ancient Pb and Ti mobilization revealed by Scanning Ion Imaging

    NASA Astrophysics Data System (ADS)

    Kusiak, Monika A.; Whitehouse, Martin J.; Wilde, Simon A.

    2014-05-01

    Zircons from strongly layered early Archean ortho- and paragneisses in ultra-high temperature (UHT) metamorphic rocks of the Napier Complex, Enderby Land, East Antarctica are characterized by complex U-Th-Pb systematics [1,2,3]. A large number of zircons from three samples, Gage Ridge, Mount Sones and Dallwitz Nunatak, are reversely discordant (U/Pb ages older than 207Pb/206Pb ages) with the oldest date of 3.9 Ga [4] (for the grain from Gage Ridge orthogneiss). To further investigate this process, we utilized a novel high spatial resolution Scanning Ion Imaging technique on the CAMECA IMS 1280 at the Natural History Museum in Stockholm. Areas of 70 μm x 70 μm were selected for imaging in mono- and multicollection modes using a ~2 μm rastered primary beam to map out the distribution of 48Ti, 89Y, 180Hf, 232Th, 238U, 204Pb, 206Pb and 207Pb. The ion maps reveal variable distribution of certain elements within analysed grains that can be compared to their CL response. Yttrium, together with U and Th, exhibits zonation visible on the CL images, Hf shows expected minimal variation. Unusual patchiness is visible in the map for Ti and Pb distribution. The bright patches with enhanced signal do not correspond to any zones or to crystal imperfections (e.g. cracks). The presence of patchy titanium is likely to affect Ti-in-zircon thermometry, and patchy Pb affecting 207Pb/206Pb ages, usually considered as more robust for Archean zircons. Using the WinImage program, we produced 207Pb/206Pb ratio maps that allow calculation of 207Pb/206Pb ages for spots of any size within the frame of the picture and at any time after data collection. This provides a new and unique method for obtaining age information from zircon. These maps show areas of enhanced brightness where the 207Pb/206Pb ratio is higher and demonstrate that within these small areas (μm scale) the apparent 207Pb/206Pb age is older, in some of these patches even > 4 Ga. These data are a result of ancient Pb

  4. Sr-Nd-Pb isotope mapping of Mesozoic igneous rocks in NE China: Constraints on tectonic framework and Phanerozoic crustal growth

    NASA Astrophysics Data System (ADS)

    Guo, Feng; Fan, Weiming; Gao, Xiaofeng; Li, Chaowen; Miao, Laicheng; Zhao, Liang; Li, Hongxia

    2010-12-01

    New Sr-Nd-Pb isotope dataset of Mesozoic igneous rocks shows that the NE China can be subdivided into four Sr-Nd-Pb isotope provinces: (1) the northern Hinggan Mountains (NHM) region; (2) the southern Hinggan Mountain (SHM)-Yanji-Liaoyuan (YL) region; (3) the Zhangguangcai Range-Jiamusi (ZGJ) Block; and (4) the exotic Wandashan massif (WDM). The Wandashan massif contains Mesozoic (high-μ)-type oceanic island basalts (HIMU-OIBs) with highly radiogenic Pb isotopic compositions (e.g., 206Pb/ 204Pb(i) = 18.9-22.7), quite different from other regions that have moderately radiogenic Pb (i.e., 206Pb/ 204Pb(i)) is generally less than 18.6. These HIMU-OIBs also show negative Δ7/4 and Δ8/4 values, signatures of Southern Gondwanaland Continent. By contrast, the majority of Mesozoic igneous rocks in other areas of NE China have positive Δ7/4 and Δ8/4 values, akin to the Northern Laurasian Continent. Such isotopic variations were probably due to the enrichment processes mainly caused by Paleozoic Paleo-Asian ocean subduction and to some extent by subduction of the Paleo-Pacific Ocean since early Mesozoic. The mantle-derived rocks in the NHM region is characterized by moderately radiogenic Nd and Pb isotopic compositions (ɛ Nd(t) = -0.2 to + 3.6 and 206Pb/ 204Pb(i) = 18.3-18.6). Compared with the NHM region, the mantle-derived magmas in the SHM-YL region show wider Nd isotopic variation (ɛ Nd(t) = -1.1 to + 6.6) and less radiogenic Pb ( 206Pb/ 204Pb(i) = 18.1-18.4). Along the Hegenshan-Solonker suture distributes an early Cretaceous felsic magmatic belt with highly positive-ɛ Nd (ɛ Nd(t) = + 4.0 to + 5.9) and radiogenic Pb compositions ( 206Pb/ 204Pb(i) = 18.4-18.6), suggesting that it was not only an important Phanerozoic crustal growth belt but also a zone containing significant volume of pelagic sediments or their metamorphosed derivates. Adjacent to the Hengenshan ophiolite occurs a suite of andesites showing nonradiogenic Nd (ɛ Nd(t) = -10.5 to -6.3) and Pb ( 206

  5. Study of the charge radii of the stable lead isotopes

    SciTech Connect

    Borchert, G.L.; Schult, O.W.B.; Speth, J.; Hansen, P.G.; Jonson, B.; Ravn, H.; McGrory, J.B.

    1982-01-01

    Isotope shifts have been measured of the K/sub ..cap alpha..l/ x-ray lines emitted after photo ionization of /sup 204/Pb, /sup 206/Pb, /sup 207/Pb and /sup 208/Pb samples. The results are compared with theoretical values for delta < r/sup 2/> calculated with a microscopic model. The x-ray shift data are also compared with optical data and the nuclear parameters lambda derived from electron scattering results.

  6. Factors controlling elevated lead concentrations in water samples from aquifer systems in Florida

    USGS Publications Warehouse

    Katz, B.G.; Bullen, M.P.; Bullen, T.D.; Hansard, Paul

    1999-01-01

    Concentrations of total lead (Pb) and dissolved Pb exceeded the U.S. Environmental Protection Agency action level of 15 micrograms per liter (mg/L) in approximately 19 percent and 1.3 percent, respectively, of ground-water samples collected during 1991-96 from a statewide network of monitoring wells designed to delineate background water quality of Florida's major aquifer systems. Differences in total Pb concentrations among aquifer systems reflect the combined influence of anthropogenic sources and chemical conditions in each system. A highly significant (p<0.001) difference in median total Pb concentrations was found for water samples from wells with water-level recording devices that contain Pb-counterweights (14 mg/L) compared to non-recorder wells (2 mg/L). Differences between total Pb concentrations for recorder and non-recorder wells are even more pronounced when compared for each aquifer system. The largest differences for recorder status are found for the surficial aquifer system, where median total Pb concentrations are 44 and 2.4 mg/L for recorder wells and non-recorder wells, respectively. Leaching of Pb from metal casing materials is another potential source of Pb in ground water samples. Median total Pb concentrations in water samples from the surficial, intermediate, and Floridan aquifer systems are higher from recorder wells cased with black iron than for recorder wells with steel and PVC casing material. Stable isotopes of Pb were used in this study to distinguish between anthropogenic and natural sources of Pb in ground water, as Pb retains the isotopic signature of the source from which it is derived. Based on similarities between slopes and intercepts of trend lines for various sample types (plots of 206Pb/204Pb versus 208Pb/204Pb and 207Pb/204Pb versus 208Pb/204Pb) the predominant source of total Pb in water samples from the surficial aquifer system is corrosion of Pb counterweights. It is likely that only ground-water samples, not the aquifer

  7. Lead-isotopic data from sulfide minerals from the Cascade Range, Oregon and Washington

    USGS Publications Warehouse

    Church, S.E.; LeHuray, A.P.; Grant, A.R.; Delevaux, M.H.; Gray, J.E.

    1986-01-01

    Lead-isotopic studies of mineral deposits associated with Tertiary plutons found in the Cascade Range of Oregon and Washington demonstrate a rather uniform isotopic composition in various sulfide minerals ( 206Pb 204Pb = 18.84 to 19.05; 207Pb 204Pb = 15.57 to 15.62; 208Pb 204Pb = 38.49 to 38.74), show less variation than data from the volcanic rocks of the Cascade Range and fall within the mixing array defined by the MORB regression line and continental sediments. An evaluation of the role of crustal assimilation by hydrothermal convection during emplacement was made on five sulfide deposits associated with a single composite batholith, the Cloudy Pass pluton. The Pb-isotopic data and mass balance calculations suggest that only minor amounts of the lead were derived from the overlying Precambrian (?) Swakane Biotite Gneiss during emplacement. The bulk of the metal that occurs in sulfide deposits in the Cascade mineral belt appears to have been derived from subducted continental detritus. The variation of the Pb-isotopic signature of Sulfides from specific districts or deposits suggests that there is a correlation with age and structure of the crust. 206Pb 204Pb is greater than 18.92 in northern Washington and southern Oregon where deposits have intruded Mesozoic or older crust. However, the ore deposits between the northern Oregon border and central Oregon, south of Eugene, have intruded younger crust composed largely of mafic and andesitic volcanic rocks and 206Pb 204Pb lies between 18.84 and 18.92. This region, previously called the Columbia embayment, appears to be underlain by Tertiary volcanic rocks. Lead-isotopic data may be used to define the boundaries between discontinuous blocks of Mesozoic crust and Tertiary volcanic cover. ?? 1986.

  8. Historical lead isotope record of a sediment core from the Derwent River (Tasmania, Australia): a multiple source environment.

    PubMed

    Townsend, Ashley T; Seen, Andrew J

    2012-05-01

    A 105 cm sediment core from the Derwent River (Tasmania, Australia) was collected in 2004 and was characterised considering both physical (loss on ignition at 550 °C and grain size) and chemical (Fe, Cu, Zn, Cd and Pb concentrations, Pb isotope ratios and (210)Pb dating) properties. The core was analysed to (i) investigate the historical profiles of some important elements associated with the Risdon zinc refinery adjacent to the Derwent River, (ii) determine Pb isotopic signatures of sediment samples, and (iii) assess the veracity of Pb isotope ratios as indicators of contaminant Pb input. Extractable metal concentrations were (all values as mgkg(-1), non-normalised for grain size) Fe: 20,000-35,000, Zn: 42-4500, Pb: 5-1090, Cu: 13-141, and Cd: 1-31; with a close correlation between Cu, Zn, Cd and Pb. Metal enrichment factors (normalised to Al) were Pb: 0.9-144, Zn: 0.8-93, Cd: 0.8-30, Cu: 0.8-8.9 and Fe: 0.9-1.3, confirming anthropogenic contributions of Cu, Zn, Pb and Cd to the sediments. The onset of metal contamination above background levels occurred at a depth between 43 and 49 cm, with maximum concentrations noted near 20 cm for Cu, Zn, Cd and Pb. Lead isotope ratios were determined in sediments using sector field ICP-MS, and were found to be 36.5-38.8, 16.5-18.7 and 1.07-1.20 for (208)Pb/(204)Pb, (206)Pb/(204)Pb and (206)Pb/(207)Pb ratios, respectively. Major Australian ores processed at the refinery over the previous ~90 years include those from Broken Hill, Rosebery, Mt Isa, Elura, Hellyer and Century deposits. Anthropogenic impact by Pb with Broken Hill type isotopic ratio was initially evident in the core at 43-49 cm. The introduction of Rosebery and Elura ores to the refinery was also clearly noted. Pb isotope ratios further highlight that the Derwent River has been exposed to a greater impact by anthropogenic Pb in comparison to other major Tasmanian rivers, namely the Huon and Tamar.

  9. U-Th-Pb ion microprobe analysis of monazite from the Paleoproterozoic Karrat rare earth element (REE) deposit, western Greenland

    NASA Astrophysics Data System (ADS)

    Mott, A.; Grove, M.; Bird, D. K.

    2012-12-01

    The Karrat rare earth element (REE) deposit is located at 72°N on the Niaqornakavsak peninsula of Qeqertarssuq Island on the western coast of Greenland. Metasomatic alteration of an amphibolite host rock by carbonatite derived fluids resulted in REE mineralization in the Karrat Isfjord area. REE in the mineralization are primarily found in bastnasite, allanite, and monazite. In-situ analysis of monazite was conducted on samples obtained from three sites of mineralization: (1) the primary deposit at Niaqornakavsak consisting of a single distinct ~30m thick unit; (2) at Umiamako Nuna 7 km to the east of Niaqornakavsak where the majority of REE mineralization occurs within the first 20m of the surface; and (3) a 6m thick REE-rich vein 100m below the surface at Umiamako Nuna. Formation ages for monazite at Niaqornakavsak, Umiamako Nuna (surface), and Umiamako Nuna (vein) have been calculated using 207Pb/206Pb, 206Pb/238U, and 208Pb/232Th isotope ratios. Multiple isotope ratios were examined to determine the ideal method of monazite analysis based on the inherent issues of low U content of monazite, difficulties measuring 204Pb, common Pb corrections, and peak interferences resulting from high concentrations of REE. 208Pb/232Th analysis resulted in the best precision and smallest spread of values. Energy filtering was applied to 208Pb/232Th analyses in an effort to reduce interferences at several peaks. Although all three isotope ratio analyses result in a Paleoproterozoic age similar to the timing of convergence of the North Atlantic craton, Rae craton, and Aasiat domain as well as the emplacement of the Prøven Igneous Complex in Greenland (1.95-1.80Ga), the values range between 1.7-1.9Ga depending on the isotope ratio.

  10. Monitoring steel bridge renovation using lead isotopic tracing.

    PubMed

    Salome, Fred; Gulson, Brian; Chiaradia, Massimo; Davis, Jeffrey; Morris, Howard

    2017-05-01

    Monitoring removal of lead (Pb) paint from steel structures usually involves analysis of environmental samples for total lead and determination of blood Pb levels of employees involved in the Pb paint removal. We used high precision Pb isotopic tracing for a bridge undergoing Pb paint removal to determine if Pb in the environmental and blood samples originated from the bridge paint. The paint system on the bridge consisted of an anti-corrosive red Pb primer top-coated with a Micaceous Iron Oxide (MIO) alkyd. Analysis of the red Pb primer gave uniform isotopic ratios indicative of Pb from the geologically-ancient Broken Hill mines in western New South Wales, Australia. Likewise waste abrasive material, as anticipated, had the same isotopic composition as the paint. The isotopic ratios for other samples lay on 2 separate linear arrays on a(207)Pb/(204)Pb versus (206)Pb/(204)Pb diagram, one largely defined by gasoline and the majority of the ambient air data, and the other by data for one sample each of gasoline and ambient air and underwater sediments. Isotopic ratios in background ambient air samples for the project were characteristic of leaded gasoline. Air sampling during paint removal showed a contribution of paint Pb ranging from about 20 to 40%. Isotopic ratios in the blood of 8 employees prior to the commencement of work showed that 6 of these had been previously exposed to the Broken Hill Pb possibly from earlier bridge paint removal projects. One subject appeared to have increased exposure to Pb probably from the paint renovations.

  11. Isotopic composition of Pb in ore deposits of the Betic Cordillera, Spain; origin and relationship to other European deposits

    USGS Publications Warehouse

    Arribas , Antonio; Tosdal, Richard M.

    1994-01-01

    The Betic Cordillera in southern Spain is a complex Alpine fold belt that resulted from the Cretaceous through Cenozoic collision of Africa with Europe. The region is illustrative of one of the characteristics of the Alpine-Mediterranean orogen: the occurrence over a limited area of mineral deposits with a wide variety of host rocks, mineralization ages, and styles. The metamorphic basement in the Betic zone is characterized by a nappe structure of superimposed tectonostratigraphic units and consists of lower Paleozoic to Lower Triassic clastic metasedimentary rocks. This is overlain by Middle to Upper Triassic platform carbonate rocks with abundant strata-bound F-Pb-Zn-(Ba) deposits (e.g., Sierra de Gador, Sierra Alhamilla). Cretaceous to Paleogene subduction-related compression in southeastern Spain was followed by Miocene postcollisional extension and resulted in the formation of the Almeria-Cartagena volcanic belt and widespread hydrothermal activity and associated polymetallic mineralization. Typical Miocene hydrothermal deposits include volcanic-hosted Au (e.g., Rodalquilar) and Ag-rich base metal (e.g., Cabo de Gata, Mazarron) deposits as well as complex polymetallic veins, mantos, and irregular replacement bodies which are hosted by Paleozoic and Mesozoic metamorphic rocks and Neogene sedimentary and volcanic rocks (e.g., Cartagena, Sierra Almagrera, Sierra del Aguilon, Loma de Bas).Lead isotope compositions were measured on sulfide samples from nine ore districts and from representative fresh samples of volcanic and basement rock types of the region. The results have been used to evaluate ore-forming processes in southeastern Spain with emphasis on the sources of metals. During a Late Triassic mineralizing event, Pb was leached from Paleozoic clastic metasedimentary rocks and incorporated in galena in strata-bound F-Pb-Zn-(Ba) deposits ( 206 Pb/ 204 Pb = 18.332 + or - 12, 207Pb/ 204 Pb = 15.672 + or - 12, 208 Pb/ 204 Pb = 38.523 + or - 46). The second

  12. Black Carbon, Metal Concentrations and Lead Isotopes Ratios in Aerosols as Tracers of Human and Natural Activities in Northern Vietnam

    NASA Astrophysics Data System (ADS)

    Guinot, B. P.

    2015-12-01

    Atmospheric brown clouds (ABC) observed as widespread layers of brownish haze are regional scale plumes of air pollutants with a hot spot of emission located in East Asia. ABC are mainly composed of aerosol particles such as Black Carbon (BC) emitted to the atmosphere during biomass burning and fossil fuels combustion. The atmospheric lifetime of BC ranges from a few days in wet season up to one month in dry season. The use of stable lead isotopes and 21 elements as tracers of air pollution was applied to identify and characterized the main sources of anthropogenic activities in Asian region. Aerosol samples from Haiphong (North Vietnam) were collected by a high volume sampler for a period of one year from October 2012 to October 2013. Vietnam's 207Pb/206Pb ratios were almost identical to those found for China. Ratios of 207Pb/206Pb ranged from 0.837 to 0.871 which agrees with values previously reported for the last 10 years in China (0.841 - 0.879). No significant variation in isotope ratio was observed during the sampling period, which suggests that there was no large seasonal variation in the isotope ratios of airborne lead. Trajectory analysis showed that almost two third of the air masses originated from East Northeast which implies that China was a major source of lead in atmosphere. Enrichment factor calculations indicated a large influence of coal activity (EF(Al) As = 1982 ± 796, EF(Al) Cd = 972 ± 659, EF(Al) Sb = 1358 ± 930) but the difference between combustion and mining exploitation could not be evidenced. Significant correlations were found between two others groups of elements: As, Cu, Ni, Zn, and Al, Fe K, Co. Wind dilution was effective on metals concentration variation. During the cold and dry season (winter) ambient concentrations were high and variable, during the warm and wet season (summer) concentrations were stable and low. Taken together, these factors also identified industrial and lithogenic activities in the region.

  13. Revisiting mobilisation of skeletal lead during pregnancy based on monthly sampling and cord/maternal blood lead relationships confirm placental transfer of lead.

    PubMed

    Gulson, Brian; Mizon, Karen; Korsch, Michael; Taylor, Alan

    2016-04-01

    Lead (Pb) can be released from the maternal skeleton during pregnancy and lactation and transferred to the infant. Most support for this hypothesis comes from blood Pb (PbB) studies involving limited sampling during pregnancy, the maximum usually being five samplings, including at delivery. We provide longitudinal data for PbB concentrations and Pb isotopic ratios for three cohorts of pregnant females (n = 31), two of which are based on monthly sampling and the other on quarterly sampling. We also provide data for samples collected post-partum. The data are compared with changes observed in a matched, by country and age, non-pregnant control cohort (n = 5). The monthly data illustrate the variability between subjects, which is also apparent when the data are compared on a trimester basis. Mixed model analyses showed that, in the third trimester, the mean PbB level was significantly lower for women (n = 10) who took a calcium (Ca) supplement (PbB 1.6 µg/dL) than those whose Ca intake was low (low-Ca cohort; n = 15; PbB 2.5 µg/dL) because low Ca means more mobilisation is required for homoeostasis so that more Pb was mobilised from the skeleton. For women who took the supplement, post-partum PbB levels were significantly higher than those in the other periods (2.7 vs 1.4-1.6 µg/dL). For women in the low-Ca cohort, PbB levels were higher at post-partum than in pre-pregnancy and in the first and second trimesters (3.1 vs 1.8 µg/dL), while the levels in the third trimester were higher than those in the first and second trimesters. Importantly, the increase in PbB during gestation was delayed until the third trimester in the Ca-supplemented cohort compared with the low-Ca cohort. Regression analysis showed that the changes over trimester were very similar for PbB and the (206)Pb/(204)Pb ratio providing convincing evidence for extra mobilisation of Pb from the maternal skeleton during pregnancy and lactation. Isotopic ratios in the cord blood samples were similar to

  14. Geochemical and isotopic profile of Pico de Orizaba (Citlaltépetl) volcano, Mexico: Insights for magma generation processes

    NASA Astrophysics Data System (ADS)

    Schaaf, Peter; Carrasco-Núñez, Gerardo

    2010-11-01

    Pico de Orizaba or Citlaltépetl volcano is the easternmost and highest stratovolcano of the subduction-related Mexican Volcanic Belt (MVB) located > 400 km NNE of the Middle America Trench. This active volcano comprises four evolutionary stages, ranging in age from 0.65 Ma to the Holocene, and is surrounded by Quaternary monogenetic scoria cones and maar volcanoes. Magmatic products of the stratocone range from basaltic andesites to rhyolites and the cinder cones erupted basalts and basaltic andesites. All rock compositions form a continuous calc-alkaline suite. Petrogenetic processes involved in magma generation and evolution include fractional crystallization and mid-crustal assimilation. Trace element patterns with elevated Ba/Nb, positive Pb spikes, and Th enrichments indicate contributions from subducted sediment. Low Ba/Th ratios suggest melting of hydrous sediment without significant loss of fluid-mobile elements prior to melting. Sr-Nd isotopic ratios of Pico de Orizaba and cinder cones are nearly chondritic and are located on a mixing curve between Pacific MORB and Paleozoic crust of SE Mexico. However, vertical Nd distributions in an 87Sr/ 86Sr vs. ɛNd diagram cannot be explained by crustal assimilation and indicate contributions of a sedimentary component with unradiogenic Nd. In contrast to other eastern MVB volcanic centres, Pico de Orizaba magmas are derived almost exclusively from a depleted mantle source. Compared to other MVB stratocones, Pico de Orizaba shows the least radiogenic Nd isotope ratios at nearly identical 87Sr/ 86Sr. Steep trends in a 206Pb/ 204Pb vs. 207Pb/ 204Pb diagram favour the involvement of young, 207Pb-enriched oceanic sediments in magma generation processes of Pico de Orizaba volcano. The Pb isotope data do not support any assimilation of lower crustal Grenvillian basement.

  15. The 1998-2001 submarine lava balloon eruption at the Serreta ridge (Azores archipelago): Constraints from volcanic facies architecture, isotope geochemistry and magnetic data

    NASA Astrophysics Data System (ADS)

    Madureira, Pedro; Rosa, Carlos; Marques, Ana Filipa; Silva, Pedro; Moreira, Manuel; Hamelin, Cédric; Relvas, Jorge; Lourenço, Nuno; Conceição, Patrícia; Pinto de Abreu, Manuel; Barriga, Fernando J. A. S.

    2017-01-01

    The most recent submarine eruption observed offshore the Azores archipelago occurred between 1998 and 2001 along the submarine Serreta ridge (SSR), 4-5 nautical miles WNW of Terceira Island. This submarine eruption delivered abundant basaltic lava balloons floating at the sea surface and significantly changed the bathymetry around the eruption area. Our work combines bathymetry, volcanic facies cartography, petrography, rock magnetism and geochemistry in order to (1) track the possible vent source at seabed, (2) better constrain the Azores magma source(s) sampled through the Serreta submarine volcanic event, and (3) interpret the data within the small-scale mantle source heterogeneity framework that has been demonstrated for the Azores archipelago. Lava balloons sampled at sea surface display a radiogenic signature, which is also correlated with relatively primitive (low) 4He/3He isotopic ratios. Conversely, SSR lavas are characterized by significantly lower radiogenic 87Sr/86Sr, 206Pb/204Pb and 208Pb/204Pb ratios than the lava balloons and the onshore lavas from the Terceira Island. SSR lavas are primitive, but incompatible trace-enriched. Apparent decoupling between the enriched incompatible trace element abundances and depleted radiogenic isotope ratios is best explained by binary mixing of a depleted MORB source and a HIMU­type component into magma batches that evolved by similar shallower processes in their travel to the surface. The collected data suggest that the freshest samples collected in the SSR may correspond to volcanic products of an unnoticed and more recent eruption than the 1998-2001 episode.

  16. Os isotopic constraints on the identification of pyroxenite in the source of OIBs

    NASA Astrophysics Data System (ADS)

    Gibson, Sally; Dale, Chris; Geist, Dennis; Harpp, Karen

    2015-04-01

    The Re-Os isotope system has become increasingly used as a tracer of lithological heterogeneity in the convecting mantle, with radiogenic 187Os/188Os in high-Os oceanic basalts and picrites widely interpreted as evidence of a melt contribution from ancient recycled oceanic crust. When combined with 206Pb/204Pb and O isotopes, 187Os/188Os ratios have been used to identify distinct lithological units (i.e. sediments, gabbros and basalts). We report new 187Os/188Os for basalts with high Os (>40 ppt) and MgO from Galápagos, which range from near primitive mantle values (0.130) to highly radiogenic (0.155). While co-variations in 187Os/188Os and 206Pb/204Pb for some Galápagos basalts (Floreana-type) are HIMU like, and consistent with melting of ancient recycled oceanic crust, others have variable 187Os/188Os ratios and primitive to depleted mantle like 206Pb/204Pb. Similar variations in Os and Pb isotopic space have been interpreted in other OIB suites as melts from recycled ancient oceanic gabbros, entrained by upwelling mantle plumes. Nevertheless, a marked east-west spatial variation in 187Os/188Os of Galápagos basalts does not correlate with postulated lithological variations in the Galápagos plume based on trace element contents of olivine (Vidito et al., 2013). We show that basalts in eastern Galápagos with elevated 187Os/188Os and positive Sr anomalies occur in the vicinity of over-thickened 10 Ma gabbroic crust, that formed when the Galápagos plume was on-axis. We propose the elevated 187Os/188Os of Galápagos basalts are due to in-situ assimilation of young gabbroic lower crust, with high Re/Os, rather than melting of ancient recycled material in the Galápagos plume. In western Galápagos recent plume accreted crust is thick but more mafic, the melt flux higher and assimilation more sporadic. The contamination thresholds of Os and MgO in Galápagos basalts occur at higher contents than for many global OIBs (Azores, Iceland, Hawaii) and may reflect both a

  17. Geochemistry and age of Shatsky, Hess, and Ojin Rise seamounts: Implications for a connection between the Shatsky and Hess Rises

    NASA Astrophysics Data System (ADS)

    Tejada, Maria Luisa G.; Geldmacher, Jörg; Hauff, Folkmar; Heaton, Daniel; Koppers, Anthony A. P.; Garbe-Schönberg, Dieter; Hoernle, Kaj; Heydolph, Ken; Sager, William W.

    2016-07-01

    Shatsky Rise in the Northwest Pacific is the best example so far of an oceanic plateau with two potential hotspot tracks emanating from it: the linear Papanin volcanic ridge and the seamounts comprising Ojin Rise. Arguably, these hotspot tracks also project toward the direction of Hess Rise, located ∼1200 km away, leading to speculations that the two plateaus are connected. Dredging was conducted on the massifs and seamounts around Shatsky Rise in an effort to understand the relationship between these plateaus and associated seamounts. Here, we present new 40Ar/39Ar ages and trace element and Nd, Pb, and Hf isotopic data for the recovered dredged rocks and new trace elements and isotopic data for a few drill core samples from Hess Rise. Chemically, the samples can be subdivided into plateau basalt-like tholeiites and trachytic to alkalic ocean-island basalt compositions, indicating at least two types of volcanic activity. Tholeiites from the northern Hess Rise (DSDP Site 464) and the trachytes from Toronto Ridge on Shatsky's TAMU massif have isotopic compositions that overlap with those of the drilled Shatsky Rise plateau basalts, suggesting that both Rises formed from the same mantle source. In contrast, trachytes from the southern Hess Rise (DSDP Site 465A) have more radiogenic Pb isotopic ratios that are shifted toward a high time-integrated U/Pb (HIMU-type mantle) composition. The compositions of the dredged seamount samples show two trends relative to Shatsky Rise data: one toward lower 143Nd/144Nd but similar 206Pb/204Pb ratios, the other toward similar 143Nd/144Nd but more radiogenic 206Pb/204Pb ratios. These trends can be attributed to lower degrees of melting either from lower mantle material during hotspot-related transition to plume tail or from less refractory shallow mantle components tapped during intermittent deformation-related volcanism induced by local tectonic extension between and after the main volcanic-edifice building episodes on Shatsky

  18. Resolving mantle and magmatic processes in basalts from the Cameroon volcanic line using the Re-Os isotope system

    NASA Astrophysics Data System (ADS)

    Gannoun, A.; Burton, K. W.; Barfod, D. N.; Schiano, P.; Vlastélic, I.; Halliday, A. N.

    2015-05-01

    This study presents major-, trace element and Re-Os isotope and elemental data for young alkaline basalts (< 10 Ma) from oceanic (Annobon, S. Tomé, Principe), continental (Manengouba) and continent-oceanic boundary (COB, Mt. Cameroon) sectors of the Cameroon volcanic line (CVL). The CVL is a chain of Tertiary to recent, transitional to strongly alkaline intraplate volcanoes extending from the south Atlantic island of Annobon to the continental interior of West Africa (Biu Plateau). The basalts from the oceanic sector display a range of initial 187Os/188Os ratios between 0.128 and 0.190 and those from the COB and continental sector range between 0.142 and 0.560. The samples with high 206Pb/204Pb (e.g. ratios > 20) possess 187Os/188Os isotope compositions between 0.14 and 0.18 (e.g., basalts from Mt Cameroon and Sao Tomé) which reflect the chemical characteristics that are more likely to be primary features of CVL, and are close to the value of 0.153 attributed to the HIMU end-member (Tubuai-Mangaia). However, most of the lavas from the continental sector show highly radiogenic initial 187Os/188Os ratios (0.36 to 0.56) that are outside the range previously observed for ocean island basalts, with shifts to radiogenic Os isotope compositions accompanied by less radiogenic 206Pb/204Pb and increasing SiO2 contents. The increase in 187Os/188Os is also associated with the decrease of Os, Ni, MgO and phenocryst abundances. These data can be explained by fractional crystallisation and assimilation of continental crust by the ascending magma. The systematic shift to unradiogenic lead isotope compositions from the COB into the oceanic sector is positively correlated with variations in 187Os/188Os isotope composition (from 0.140 to 0.128). At first sight this covariation might be attributed to the mixing of HIMU material with the ambient upper mantle (DMM). However, there is a clear covariation of the Os isotope and elemental composition, best explained with contamination of

  19. Comparison of lead isotopes with source apportionment models, including SOM, for air particulates.

    PubMed

    Gulson, Brian; Korsch, Michael; Dickson, Bruce; Cohen, David; Mizon, Karen; Davis, J Michael

    2007-08-01

    We have measured high precision lead isotopes in PM(2.5) particulates from a highly-trafficked site (Mascot) and rural site (Richmond) in the Sydney Basin, New South Wales, Australia to compare with isotopic data from total suspended particulates (TSP) from other sites in the Sydney Basin and evaluate relationships with source fingerprints obtained from multi-element PM(2.5) data. The isotopic data for the period 1998 to 2004 show seasonal peaks and troughs that are more pronounced in the rural site for the PM(2.5).samples but are consistent with the TSP. The Self Organising Map (SOM) method has been applied to the multi-element PM(2.5) data to evaluate its use in obtaining fingerprints for comparison with standard statistical procedures (ANSTO model). As seasonal effects are also significant for the multi-element data, the SOM modelling is reported as site and season dependent. At the Mascot site, the ANSTO model exhibits decreasing (206)Pb/(204)Pb ratios with increasing contributions of fingerprints for "secondary smoke" (industry), "soil", "smoke" and "seaspray". Similar patterns were shown by SOM winter fingerprints for both sites. At the rural site, there are large isotopic variations but for the majority of samples these are not associated with increased contributions from the main sources with the ANSTO model. For two winter sampling times, there are increased contributions from "secondary industry", "smoke", "soil" and seaspray with one time having a source or sources of Pb similar to that of Mascot. The only positive relationship between increasing (206)Pb/(204)Pb ratio and source contributions is found at the rural site using the SOM summer fingerprints, both of which show a significant contribution from sulphur. Several of the fingerprints using either model have significant contributions from black carbon (BC) and/or sulphur (S) that probably derive from diesel fuels and industrial sources. Increased contributions from sources with the SOM summer

  20. Petrology of continental tholeiitic magmas forming a 350-km-long Mesozoic dyke swarm in NE Brazil: Constraints of geochemical and isotopic data

    NASA Astrophysics Data System (ADS)

    Ngonge, Emmanuel Donald; de Hollanda, Maria Helena Bezerra Maia; Archanjo, Carlos José; de Oliveira, Diógenes Custódio; Vasconcelos, Paulo Marcosde Paula; Muñoz, Patrício Rodrigo Montecinos

    2016-08-01

    The Ceará Mirim dyke swarm (northeastern Brazil) is composed of Cretaceous tholeiites with plagioclase, clinopyroxene (± olivine), Fe-Ti oxides and pigeonite in their groundmass. These tholeiites have been subdivided into three groups: high-Ti olivine tholeiites, evolved high-Ti tholeiites (TiO2 ≥ 1.5 wt.%; Ti/Y > 360), and low-Ti tholeiites (TiO2 ≤ 1.5 wt%; Ti/Y ≤ 360), with all exhibiting distinct degrees of enrichment in incompatible elements relative to Primitive Mantle. Negative Pb anomalies are found in all three groups, while Nb-Ta abundances similar to those of OIB-type magmas are found in the olivine tholeiites, with moderate to high depletions being observed, respectively, in the evolved high-Ti and low-Ti tholeiites. The low-Ti tholeiites exhibit some contamination with crustal (felsic) materials during ascent. The initial isotopic compositions of the olivine tholeiites show uniform and unradiogenic 87Sr/86Sr (~ 0.7035-0.7039) combined with (in part) radiogenic 143Nd/144Nd and 206Pb/204Pb (> 19.1) ratios, which together reveal a likely contribution of FOZO (FOcalZOne) component in their genesis. The other tholeiite groups show variable Sr-Nd ratios with relatively consistent 206Pb/204Pb ratios clustering towards an isotopically enriched mantle (EM1) component. Taken in conjunction with the Nb, this enriched signature reflects the involvement of a subduction-modified lithospheric mantle in the source of the evolved high-Ti and low-Ti tholeiites. Thus, we propose that FOZO and EMI components coexisted (including minor mixing with E-MORB magmas) and contributed in varying extents to the generation of the Ceará-Mirim dyke swarm primary melts, which segregated at 75 to 60 km in depth around the garnet-spinel facies transition zone. The mechanism that promoted melting was most likely non-plume related. We suggest that plate-boundary forces linked to the opening of the Atlantic Ocean promoted passive rifting and that the resulting asthenospheric

  1. Sr-Nd-Pb isotope systematics of mantle xenoliths from Somerset Island kimberlites: Evidence for lithosphere stratification beneath Arctic Canada

    NASA Astrophysics Data System (ADS)

    Schmidberger, S. S.; Simonetti, A.; Francis, D.

    2001-11-01

    Sr, Nd, and Pb isotopic compositions were determined for a suite of Archean garnet peridotite and garnet pyroxenite xenoliths and their host Nikos kimberlite (100 Ma) from Somerset Island to constrain the isotopic character of the mantle root beneath the northern Canadian craton. The Nikos peridotites are enriched in highly incompatible trace elements (La/Sm N = 4-6), and show 143Nd/ 144Nd (t) (0.51249-0.51276) and a large range in 87Sr/ 86Sr (t) (0.7047-0.7085) and Pb ( 206Pb/ 204Pb (t) = 17.18 to 19.03) isotope ratios that are distinct from those estimated for "depleted mantle" compositions at the time of kimberlite emplacement. The Nd isotopic compositions of the peridotites overlap those of the Nikos kimberlite, suggesting that the xenoliths were contaminated with kimberlite or a kimberlite-related accessory phase (i.e., apatite). The highly variable Sr and Pb isotopic compositions of the peridotites, however, indicate that kimberlite contribution was restricted to very small amounts (˜1 wt % or less). The high-temperature peridotites (>1100°C) that sample the deep Somerset lithosphere trend toward more radiogenic 87Sr/ 86Sr (t) (0.7085) and unradiogenic 206Pb/ 204Pb (t) (17.18) isotopic ratios than those of the low-temperature peridotites (<1100°C). This is in agreement with Sr isotopic compositions of clinopyroxene from the low-temperature peridotites ( 87Sr/ 86Sr (t) = 0.7038-0.7046) that are significantly less radiogenic than those of clinopyroxene from the high-temperature peridotites ( 87Sr/ 86Sr (t) = 0.7052-0.7091). The depth correlation of Sr isotopes for clinopyroxene and Sr and Pb isotopic compositions for the Nikos whole-rocks indicate that the deep Somerset lithosphere (>160 km) is isotopically distinct from the shallow lithospheric mantle. The isotopic stratification with depth suggests that the lower lithosphere is probably younger and may have been added to the existing Archean shallow mantle in a Phanerozoic magmatic event. The radiogenic Sr

  2. U-Pb Dating, whole rock and Sr-Nd-Pb-O isotope geochemistry of collisional magmatism in the CACC: Çiçekdaǧ igneous complex (ÇIC)

    NASA Astrophysics Data System (ADS)

    Deniz, Kiymet; Kagan Kadioglu, Yusuf; Stuart, Finlay; Ellam, Rob; Boyce, Adrian; Condon, Daniel

    2015-04-01

    these intrusive rocks have experienced fractional crystallisation coupled with crustal assimilation. The calcalkaline and alkaline series show enrichment in LILE and LREE relative to HFSE and HREE. These rocks have moderate 208Pb/204Pb (38.87-39.16) and 207Pb/204Pb (15.62-15.71) and high 206Pb/204Pb (18.76-18.81). Both trace element and Pb isotope data indicate enriched mantle source (EM-II). Mafic alkaline rocks differed with their low 206Pb/204Pb (17.55-17.62). These rocks are derived from subduction modified lithospheric mantle. The geochemistry and Sr-Nd-O isotope data of ophiolitic rocks and late alkaline dykes are very similar. Both of them have flat REE pattern, high 87Sr/86Sr and 143Nd/144Nd, low δ18O values (1.9-4.0), moderate 208Pb/204Pb (38.81-38.97, 38.51-38.91) and 207Pb/204Pb (15.62-15.70, 15.54-15.69) and high 206Pb/204Pb (18.37-18.77, 18.39-18.73). All data indicate heterogeneous mantle source. Trace element ratio diagrams suggest depleted mantle source and subduction enrichment for late alkaline dykes. Dy versus Dy/Yb diagram and calculated partial melting curves suggest 20-25% degree of partial melting of amphibole-phlogopite bearing spinel lherzolitic mantle sources. Ba/Rb versus Rb/Sr diagram indicate the presence of amphibole in the mantle source of ophiolitic rocks and phlogopite for the late alkaline dykes. U-Pb dating of zircon yielded crystallization ages of 73.74±0.027-73.78±0.046 and 73.78±0.071 for calcalkaline series and alkaline series, respectively. Both series are coexistence and may have coevally been confined from same sources.

  3. HIMU-type Mid-Ocean Ridge Basalts Incorporate a Primitive Component

    NASA Astrophysics Data System (ADS)

    Tucker, J.; Mukhopadhyay, S.; Schilling, J. E.

    2011-12-01

    Samples from 5°N to 7°S along the MAR axis span a range of compositions from depleted MORB (La/SmN ~0.5, 206Pb/204Pb ~18) to very enriched MORB (La/SmN ~3, 206Pb/204Pb ~20). The measured 206Pb/204Pb in the enriched samples are among the highest measured MORB values and are thought to represent a HIMU type mantle (high μ where μ is the U/Pb ratio). Therefore, the enriched samples provide a unique opportunity to characterize the heavy noble gas composition of the HIMU mantle. If HIMU mantle is related to recycled crust, then the noble gas measurements can also provide insights into recycling of atmospheric noble gases back into the mantle. Additionally, the depleted equatorial samples provide an opportunity to characterize the Ar and Xe composition of the N-MORB source for comparison to the 14°N E-MORB popping rock. Finally, the large variations in lithophile isotopes over a geographically short distance affords the opportunity to study the nature of coupling between the noble gases and lithophile tracers, and understand the origin of the heterogeneities in the MORB source. Stepwise crushing and rare gas analysis (He, Ne, Ar, Xe) was undertaken for both enriched and depleted samples. Many of the crushing steps yielded 20Ne/22Ne > 12, and good correlations between Ne, Ar, and Xe isotopes allow for mantle source compositions of Ar and Xe to be determined by extrapolating the measured values to a mantle 20Ne/22Ne of 12.5. The highest measured values of Ar and Xe in a depleted N-MORB are comparable to measured values of the E-MORB popping rock (40Ar/36Ar ~28,000, 129Xe/130Xe ~7.7). When extrapolated to a mantle 20Ne/22Ne of 12.5, the depleted MORB sample indicates a 40Ar/36Ar of ~43,000 (higher than popping rock) and 129Xe/130Xe of ~7.8. Enriched MORB samples from this suite, thought to represent the HIMU mantle, have the same He and Ne characteristics as HIMU basalts from the Cook and Austral Islands; more radiogenic He than MORBs is accompanied by less nucleogenic

  4. Geochemical Systematics of Hawaiian Post-shield Lavas: Implications for the Chemical Structure of the Hawaiian Mantle Plume

    NASA Astrophysics Data System (ADS)

    Hanano, D.; Weis, D.; Aciego, S.; Scoates, J. S.; Depaolo, D. J.

    2005-12-01

    High-precision Pb and Hf isotopic ratios by MC-ICP-MS and trace element concentrations by HR-ICP-MS of lavas forming Hawaiian volcanoes allow for new perspectives in the study of the source components associated with the Hawaiian mantle plume. In particular, late-stage lavas represent small-volume eruptions and small degrees of melting, and can provide better resolution of the geochemical heterogeneities in the plume. This study involves post-shield lavas from the Mauna Kea, Kohala, and Hualalai volcanoes on the island of Hawaii. Lavas from these specific volcanoes provide information about the region in which the plume is being deflected and sheared to the northwest by the movement of the Pacific plate. Pb isotopic compositions from Hualalai are the least radiogenic with 206Pb/204Pb = 17.888-18.028, compared to 18.343-18.408 for Mauna Kea and 18.286-18.439 for Kohala, which is consistent with each volcano belonging to their respective Loa-Kea Pb trends. Mauna Kea post-shield lavas are less radiogenic in Pb than the shield and post-shield Mauna Kea lavas from HSDP-2, showing a systematic decrease as the volcano evolved from the shield to post-shield stage. A similar trend is observed between the tholeiites and alkaline lavas of Hualalai, while the opposite trend is observed for Kohala. Hualalai and Kohala post-shield lavas form linear arrays in Pb-Pb space with their respective tholeiites, indicating an origin from the same source. However, the relative proportions of the components involved in the genesis of the post-shield lavas appear to be different. Mauna Kea post-shield lavas lie along the lower extension of the Kea-lo8 array of HSDP-2 (Eisele et al., 2003), distinct from older (350-550 kyr) Mauna Kea lavas and recent Kilauea lavas (Abouchami et al., 2005). The low 206Pb/204Pb ratios of Hualalai post-shield lavas are indicative of a unique component in that volcano. The Pb isotopic compositions of the post-shield lavas are thus sampling isotopically distinct

  5. Does a Superswell Exist Between Antarctica and Australia?

    NASA Astrophysics Data System (ADS)

    Park, S. H.; Langmuir, C. H.; Scott, S. R.; Sims, K. W. W.; Lin, J.; Kim, S.; Michael, P. J.; Hahm, D.

    2015-12-01

    The Australian-Antarctic Ridge (AAR) is located between the Australian-Antarctic Discordance (AAD) of the Southeast Indian ridge (SEIR) in the west and Pacific-Antarctic Ridge (PAR) in the east. The AAR has intermediate spreading rate (~70 mm/yr) and consists of a series of 1st order segments bounded by parallel transform faults. KR1, a southernmost segment (63°S) of the AAR, is a 300-km-long super-segment with shallow axial depth (~2000 m). KR1 is bounded by the Macquarie transform fault in the east and the Balleney transform fault in the west, which connects KR1 with KR2 at ~ 200 km north. KR2 is 180 km long with axial depth (~2300 m) deeper than KR1. Both KR1 and KR2 are shallow relative to global mid-ocean ridges. Most of the basaltic rocks from the two segments show enriched geochemical characteristics that differ from both the AAD (Southeast Indian Ridge) and the PAR. La/Sm ratios vary from N-MORB to T-MORB; however, K2O/Nb ratios of all samples are consistently low like OIB. Their Pb isotopes are mostly more radiogenic than the N-MORB samples from PAR (and EPR) and SEIR, with 206Pb/204Pb mostly >18.6. At a given 206Pb/204Pb, their 87Sr/86Sr are higher than the PAR, but lower than the SEIR. The basalts from the two segments are geochemically similar to Cenozoic volcanoes erupted on southeast Australia, Zealandia and northwest Antarctica, suggesting a genetic relationship. According to tectonic reconstruction models, these three continents were originally joined, but separated from each other after ~80 Ma. Notably, the KR1 and KR2 segments are located at the boundary of this continental separation. The ages of Cenozoic volcanoes span from ~ 60 Ma to the recent, and the volcanoes might be related to a plume head that caused the breakup of the continents. Seismic tomography studies show that there is a low velocity zone (LVZ) in the shallow mantle (> 250 km) between Antarctica and Australia where the AAR is located. The AAR would be sampling this LVZ, and this

  6. Investigating Compositional Links Between Arc Magmas And The Subducted Altered Oceanic Crust

    NASA Astrophysics Data System (ADS)

    Straub, S. M.

    2015-12-01

    Arc magmatism is causally related to the recycling of materials from the subducting plate. Numerous studies showed that the recycled material flux is dominated by recycled continental crust (oceanic sediment, eroded crust) and altered oceanic igneous crust (AOC). The crustal component is highly enriched, and thus its signal in arc magmas can readily be distinguished from mantle wedge contributions. In contrast, the impact of the AOC flux is much more difficult to detect, since the AOC isotopically resembles the mantle. Mass balance studies of arc input and output suggest that the recycled flux from the thick (6000 meter on average) AOC may buffer the flux of the recycled continental crust to the point of concealment in arc settings where the latter is volumetrically minor. In particular, highly fluid- mobile elements Sr and Pb in arc magmas are strongly influenced by the AOC, implying that the arc chemistry may allow for inferring the Sr and Pb isotopic composition of the subducted AOC. This hypothesis is being tested by a compilation of published data of high-quality trace element and isotope compositions from global arcs. In agreement with previous studies, our results confirm that the Sr-rich fluids released from the AOC control the arc Sr isotopes, whereby the slightly elevated 87Sr/86Sr (up to 0.705) of many arcs may principally reflect the similarly elevated Sr isotope ratios of the AOC rather than a recycled crustal component. In contrast, the arc Pb isotope ratios are influenced by both the AOC and the recycled crustal component which create the typical binary mixing arrays. These arrays should then point to the Pb isotope composition of the AOC and the recycled crust, respectively. However, as the proportions of these end members may strongly vary in arc magmas, the exact 206Pb/204Pb of the subducted AOC in a given setting is challenging. Remarkably, the Pb isotope systematics from well-constrained western Aleutian (minimal sediment subduction) and central

  7. Geochemical signatures of the oceanic complexes in southern Central America

    NASA Astrophysics Data System (ADS)

    Gazel, E.; Herzberg, C. T.; Carr, M. J.; Denyer, P.

    2006-12-01

    /204Pb (18.5-19.0) and 207Pb/204Pb (15.53-15.58). Cretaceous oceanic islands show the same 206Pb/204Pb ratios but higher 207Pb/204Pb. Both could be included in the north and central fields of the Galapagos hot-spot. The post-Cretaceous oceanic islands show higher Pb isotopic ratios that reflect a higher HIMU component and could be included in the in the eastern Galapagos Hot-Spot field. Zr/Nb, Nb/Th, Nb/Y, and Zr/Y show that the CLIP rocks are included within the range of the oceanic plateau basalts with primitive and MORB components. The oceanic islands share these components but also include a recycling component (OIB). Santa Elena Nappe trends toward the subduction component (ARC).

  8. Lower-crustal xenoliths from Jurassic kimberlite diatremes, upper Michigan (USA): Evidence for Proterozoic orogenesis and plume magmatism in the lower crust of the southern Superior Province

    USGS Publications Warehouse

    Zartman, Robert E.; Kempton, Pamela D.; Paces, James B.; Downes, Hilary; Williams, Ian S.; Dobosi, Gábor; Futa, Kiyoto

    2013-01-01

    Jurassic kimberlites in the southern Superior Province in northern Michigan contain a variety of possible lower-crustal xenoliths, including mafic garnet granulites, rare garnet-free granulites, amphibolites and eclogites. Whole-rock major-element data for the granulites suggest affinities with tholeiitic basalts. P–T estimates for granulites indicate peak temperatures of 690–730°C and pressures of 9–12 kbar, consistent with seismic estimates of crustal thickness in the region. The granulites can be divided into two groups based on trace-element characteristics. Group 1 granulites have trace-element signatures similar to average Archean lower crust; they are light rare earth element (LREE)-enriched, with high La/Nb ratios and positive Pb anomalies. Most plot to the left of the geochron on a 206Pb/€204Pb vs 207Pb/€204Pb diagram, and there was probably widespread incorporation of Proterozoic to Archean components into the magmatic protoliths of these rocks. Although the age of the Group 1 granulites is not well constrained, their protoliths appear to be have been emplaced during the Mesoproterozoic and to be older than those for Group 2 granulites. Group 2 granulites are also LREE-enriched, but have strong positive Nb and Ta anomalies and low La/Nb ratios, suggesting intraplate magmatic affinities. They have trace-element characteristics similar to those of some Mid-Continent Rift (Keweenawan) basalts. They yield a Sm–Nd whole-rock errorchron age of 1046 ± 140 Ma, similar to that of Mid-Continent Rift plume magmatism. These granulites have unusually radiogenic Pb isotope compositions that plot above the 207Pb/€204Pb vs 206Pb/€204Pb growth curve and to the right of the 4·55 Ga geochron, and closely resemble the Pb isotope array defined by Mid-Continent Rift basalts. These Pb isotope data indicate that ancient continental lower crust is not uniformly depleted in U (and Th) relative to Pb. One granulite xenolith, S69-5, contains quartz, and has a

  9. Geochemistry and zircon ages of mafic dikes in the South Qinling, central China: evidence for late Neoproterozoic continental rifting in the northern Yangtze block

    NASA Astrophysics Data System (ADS)

    Zhu, Xiyan; Chen, Fukun; Liu, Bingxiang; Zhang, He; Zhai, Mingguo

    2015-01-01

    Neoproterozoic volcanic-sedimentary sequences of the southern Qinling belt, central China, were intruded by voluminous mafic dikes. secondary ion mass spectrometry zircon U-Pb dating indicates that these dikes were emplaced at 650.8 ± 5.2 Ma, coeval with mafic rocks occurring at the northern margin of the Yangtze block. The dikes are characterized by enrichment of large ion lithophile elements, high Ti contents (up to 3.73 wt%) and Nb/Ta ratios between 14.5 and 19.6, suggesting a mantle source of oceanic island basalt affinity. Initial 87Sr/86Sr ratios show positive correlation with SiO2 contents and negative correlation with Zr/Nb ratios, implying that these rocks were affected by crustal contamination during the magma ascend and emplacement process. The dikes have initial ɛ Nd values of +0.2 to +3.3, low 206Pb/204Pb ratios of 16.96-17.45, and moderate 87Sr/86Sr ratios of 0.7043-0.7076, likely pointing to the involvement of an enriched mantle source. The mafic dikes and coeval mafic volcanic equivalents in the South Qinling and the northern Yangtze are hypothesized to be related with the prolonged breakup of the supercontinent Rodinia, suggesting that continental rifting lasted until ca. 650 Ma.

  10. Zircon U-Pb dating, geochemistry and Sr-Nd-Pb-Hf isotopes of the Wajilitag alkali mafic dikes, and associated diorite and syenitic rocks: Implications for magmatic evolution of the Tarim large igneous province

    NASA Astrophysics Data System (ADS)

    Zou, Si-Yuan; Li, Zi-Long; Song, Biao; Ernst, Richard E.; Li, Yin-Qi; Ren, Zhong-Yuan; Yang, Shu-Feng; Chen, Han-Lin; Xu, Yi-Gang; Song, Xie-Yan

    2015-01-01

    The Early Permian Tarim large igneous province (Tarim LIP) consists mainly of basaltic lavas, mafic-ultramafic intrusions including dikes and, syenite bodies in the Tarim Basin, NW China. A major unit of the Tarim LIP, the Wajilitag intrusive complex, consists of olivine pyroxenite, clinopyroxenite and gabbro units (from bottom to top), diorite and syenite rocks occurred in the upper part of the complex and alkali mafic dikes intrude the clinopyroxenite phase. Here we report the zircon U-Pb age and Hf isotopes, geochemical characteristics and Sr-Nd-Pb isotopic data of the alkali mafic dikes, and diorite, aegirine-nepheline syenite and syenite porphyry units in the Wajilitag intrusive complex. Zircons from the diorite and alkali mafic rocks yield concordant crystallization ages of 275.2 ± 1.2 Ma and 281.4 ± 1.7 Ma, respectively. The diorite and syenitic rocks in Wajilitag area have a narrow range of SiO2 contents (51.9-57.3 wt.%), and are enriched in total alkalis (Na2O + K2O = 8.3-14.3 wt.%), among which the aegirine-nepheline syenite and syenite porphyry have the geochemical affinity of A-type granites. The alkali mafic rocks and syenitic rocks have high Al2O3 (19.4-21.1 wt.%), Zr, Hf, Ba contents, total rare earth element abundances and LREE/HREE ratios and low Mg# value, K, P and Ti contents. Diorites have lower Al2O3 contents, total REE abundances and LREE/HREE ratios and higher Mg# values than the alkali mafic rocks and syenitic rocks. The diorites and syenitic rocks have low initial 87Sr/86Sr ratios (0.7034-0.7046), and high εNd(t) values (0.1-4.1) and zircon εHf(t) values (- 0.9-4.4). All the diorites and syenitic rocks show the 206Pb/204Pb ratios ranging of 18.0-19.5, 207Pb/204Pb of 15.4-15.6 and 208Pb/204Pb of 38.0-39.9. Sr-Nd isotopic ratios indicate a FOZO-like mantle source for the diorite and syenitic rocks, similar to that of the mafic-ultramafic rocks in the Wajilitag complex. In contrast, zircon Hf isotopes of basalt and syenite elsewhere in the

  11. Zircon U-Pb ages, geochemical and Sr-Nd-Pb-Hf isotopic constraints on petrogenesis of the Tarom-Olya pluton, Alborz magmatic belt, NW Iran

    NASA Astrophysics Data System (ADS)

    Nabatian, Ghasem; Jiang, Shao-Yong; Honarmand, Maryam; Neubauer, Franz

    2016-02-01

    A petrological, geochemical and Sr-Nd-Pb isotopic study was carried out on the Tarom-Olya pluton, Iran, in the central part of the Alpine-Himalayan orogenic belt. The pluton is composed of diorite, monzonite, quartz-monzonite and monzogranite, which form part of the Western Alborz magmatic belt. LA-ICP-MS analyses of zircons yield ages from 35.7 ± 0.8 Ma to 37.7 ± 0.5 Ma, interpreted as the ages of crystallization of magmas. Rocks from the pluton have SiO2 contents ranging from 57.0 to 69.9 wt.%, high K2O + Na2O (5.5 to 10.3 wt.%) and K2O/Na2O ratio of 0.9 to 2.0. Geochemical discrimination criteria show I-type and shoshonitic features for the studied rocks. All investigated rocks are enriched in light rare earth elements (LREEs), large ion lithophile elements (LILEs), depleted in high-field strength elements (HFSEs), and show weak or insignificant Eu anomalies (Eu/Eu* = 0.57-1.02) in chondrite-normalized trace element patterns. The Tarom-Olya pluton samples also show depletions in Nb, Ta and Ti typical of subduction-related arc magmatic signatures. The samples have relatively low ISr (0.7047-0.7051) and positive εNd(36 Ma) (+ 0.39 to + 2.10) values. The Pb isotopic ratios show a (206Pb/204Pb)i ratio of 18.49-18.67, (207Pb/204Pb)i ratio of 15.58-15.61 and (208Pb/204Pb)i ratio of 38.33-38.77. The εHf(t) values of the Tarom-Olya pluton zircons vary from - 5.9 to + 8.4, with a peak at + 2 to + 4. The depleted mantle Hf model ages for the Tarom-Olya samples are close to 600 Ma. These isotope evidences indicate contribution of juvenile sources in petrogenesis of the Tarom-Olya pluton. Geochemical and isotopic data suggest that the parental magma of the Tarom-Olya pluton was mainly derived from a sub-continental lithospheric mantle source, which was metasomatized by fluids and melts from the subducted Neotethyan slab with a minor crustal contribution. Subsequent hot asthenospheric upwelling and lithospheric extension caused decompression melting in the final stage of

  12. Surface dust wipes are the best predictors of blood leads in young children with elevated blood lead levels

    SciTech Connect

    Gulson, Brian; Anderson, Phil; Taylor, Alan

    2013-10-15

    Background: As part of the only national survey of lead in Australian children, which was undertaken in 1996, lead isotopic and lead concentration measurements were obtained from children from 24 dwellings whose blood lead levels were ≥15 µg/dL in an attempt to determine the source(s) of their elevated blood lead. Comparisons were made with data for six children with lower blood lead levels (<10 µg/dL). Methods: Thermal ionisation and isotope dilution mass spectrometry were used to determine high precision lead isotopic ratios ({sup 208}Pb/{sup 206}Pb, {sup 207}Pb/{sup 206}Pb and {sup 206}Pb/{sup 204}Pb) and lead concentrations in blood, dust from floor wipes, soil, drinking water and paint (where available). Evaluation of associations between blood and the environmental samples was based on the analysis of individual cases, and Pearson correlations and multiple regression analyses based on the whole dataset. Results and discussion: The correlations showed an association for isotopic ratios in blood and wipes (r=0.52, 95% CI 0.19–0.74), blood and soil (r=0.33, 95% CI −0.05–0.62), and blood and paint (r=0.56, 95% CI 0.09–0.83). The regression analyses indicated that the only statistically significant relationship for blood isotopic ratios was with dust wipes (B=0.65, 95% CI 0.35–0.95); there were no significant associations for lead concentrations in blood and environmental samples. There is a strong isotopic correlation of soils and house dust (r=0.53, 95% CI 0.20–0.75) indicative of a common source(s) for lead in soil and house dust. In contrast, as with the regression analyses, no such association is present for bulk lead concentrations (r=−0.003, 95% CI −0.37–0.36), the most common approach employed in source investigations. In evaluation of the isotopic results on a case by case basis, the strongest associations were for dust wipes and blood. -- Highlights: • Children with elevated blood lead ≥15 µg/dL compared with a group with <10

  13. Tectonic events, continental intraplate volcanism, and mantle plume activity in northern Arabia: Constraints from geochemistry and Ar-Ar dating of Syrian lavas

    NASA Astrophysics Data System (ADS)

    Krienitz, M.-S.; Haase, K. M.; Mezger, K.; van den Bogaard, P.; Thiemann, V.; Shaikh-Mashail, M. A.

    2009-04-01

    New 40Ar/39Ar ages combined with chemical and Sr, Nd, and Pb isotope data for volcanic rocks from Syria along with published data of Syrian and Arabian lavas constrain the spatiotemporal evolution of volcanism, melting regime, and magmatic sources contributing to the volcanic activity in northern Arabia. Several volcanic phases occurred in different parts of Syria in the last 20 Ma that partly correlate with different tectonic events like displacements along the Dead Sea Fault system or slab break-off beneath the Bitlis suture zone, although the large volume of magmas and their composition suggest that hot mantle material caused volcanism. Low Ce/Pb (<20), Nb/Th (<10), and Sr, Nd, and Pb isotope variations of Syrian lavas indicate the role of crustal contamination in magma genesis, and contamination of magmas with up to 30% of continental crustal material can explain their 87Sr/86Sr. Fractionation-corrected major element compositions and REE ratios of uncontaminated lavas suggest a pressure-controlled melting regime in western Arabia that varies from shallow and high-degree melt formation in the south to increasingly deeper regions and lower extents of the beginning melting process northward. Temperature estimates of calculated primary, crustally uncontaminated Arabian lavas indicate their formation at elevated mantle temperatures (Texcess ˜ 100-200°C) being characteristic for their generation in a plume mantle region. The Sr, Nd, and Pb isotope systematic of crustally uncontaminated Syrian lavas reveal a sublithospheric and a mantle plume source involvement in their formation, whereas a (hydrous) lithospheric origin of lavas can be excluded on the basis of negative correlations between Ba/La and K/La. The characteristically high 206Pb/204Pb (˜19.5) of the mantle plume source can be explained by material entrainment associated with the Afar mantle plume. The Syrian volcanic rocks are generally younger than lavas from the southern Afro-Arabian region, indicating

  14. Europium and strontium anomalies in the MORB source mantle

    NASA Astrophysics Data System (ADS)

    Tang, Ming; McDonough, William F.; Ash, Richard D.

    2017-01-01

    materials, which have positive Eu and Sr anomalies, are partially mixed into the upper mantle (i.e., MORB source region), a significant amount of this crustal component must have been sequestered into the deep mantle, as supported by the negative 206Pb/204Pb-Eu/Eu∗ and 206Pb/204Pb-Sr/Sr∗ correlations in ocean island basalts.

  15. Mantle Source of Cretaceous Seafloor in the Nova-Canton Trough

    NASA Astrophysics Data System (ADS)

    Pyle, D. G.; Mahoney, J. J.

    2006-12-01

    The Nova-Canton Trough (NCT) is an 8-km-deep abyss that merges with the far western trace of the Clipperton Fracture Zone north-northwest of the Manihiki Plateau. Ocean crust in this region formed during Cretaceous long magnetic normal Chron 34. Larson (Geology, 25, 779) argued that the NCT is part of an aborted rift system that formed between the Ontong Java and Manihiki plume heads, and terminated plateau construction around 120 Ma via drain-off of plume mantle to the region of rifting. Taylor (EPSL, 241, 372) instead proposed the two plateaus formed as one short-lived mega-plateau that broke apart, and that the NCT is part of the post-breakup transform system that separated a series of short spreading segments. Recently, the R.V. Kilo Moana dredged four sites along the prominent north-facing escarpment of the NCT between 168° 06' W and 168° 42' W at ~1° 24' S, and retrieved basalt, diabase, gabbro, pyroxenite, peridotite, serpentinite, breccias and sedimentary rocks. The diversity of rock types recovered demonstrates that a large cross-section through Cretaceous seafloor is exposed. The MgO content of the basalt and diabase samples varies from 8.9-4.3 wt.%. Incompatible element patterns display relative depletions in alteration- resistant large-ion lithophile elements, and most samples have a distinctive hump-shaped REE pattern, with chondrite-normalized (Sm/Yb)n >1.3 and (La/Sm)n <0.75, suggesting generation by high pressure, relatively low-degree melting of a MORB-type mantle source. One sample is less light-REE- depleted, with (La/Sm)n= 0.96. Age-adjusted (to 120 Ma) Nd-Pb isotope ratios plot within the high- 206Pb/204Pb portion of the Pacific MORB field at ɛNd values between +8.2 and +7.5. In contrast, data for the Ontong Java and Manihiki plateaus fall well below the Pacific MORB field at lower 206Pb/204Pb and ɛNd < +6.6. Thus, our data provide no evidence for Ontong Java or Manihiki mantle components in the NCT source.

  16. Sr-Nd-Pb-C-O isotope systematics of carbonated ultramafic xenoliths from Mafu, Taiwan: Evidence for an extremely enriched lithospheric mantle source beneath the extended margin of the South China block

    NASA Astrophysics Data System (ADS)

    Smith, A. D.; Wen, D.; Chung, S.; Wang, K.; Chiang, H.; Tsai, C.

    2008-12-01

    Deep-seated carbonate melt is widely proposed as an effective agent to metasomatize the lithospheric mantle. However, such carbonate melts may have a great diversity of composition and a mantle or recycled origin remains unclear. Here we present the evidence for unique carbonate metasomatism of the continental lithospheric mantle (CLM) beneath the extended southeast margin of the South China block from severely replaced spinel peridotite xenoliths from Mafu, northwestern Taiwan. The metasomatic calcitic carbonates and whole carbonated xenoliths from Mafu have unusually low trace element abundances (total REE abundance < 6 ppm), except for enrichment in Sr, Ba, Pb, Mn and LREE. A magmatic origin is suggested by textural observation that the chromium diopside is resorbed by carbonate melts. In addition, the carbonate melts are distinguishable from the overlaying Miocene limestone and the amygdaloidal carbonate in the host lava with respect to Sr, Nd, C and O isotopic compositions, thereby precluding a crustal origin or surficial alteration, respectively. Compared with the depleted CLM source(s) represented by the unaltered chromium diopside and/or leach residue (86Sr/87Sr = 0.7041; ɛ Nd = +4.9, one residual sample up to +12; 206Pb/204Pb = 18.3), the Sr-Nd-Pb-C-O isotope systematics of the carbonates (86Sr/87Sr = 0.7044-0.7045; ɛ Nd = -6.9 to -7.7; 206Pb/204Pb = 18.5; δ13C = -4.5 to -5.7; δ18O = +21.8 to +22.9) reveal an extremely enriched and heterogeneous CLM. According to the Nd model age, the enriched component evolved for at least 1 Gyrs after isolation from the depleted CLM, before the Late Miocene entrapment. Coupled with high Sr/Nd, Ba/Th, La/Yb, Zr/Hf, and low Nb/U, Ce/Pb, Th/U, Ti/Eu ratios, this EM1-like metasomatic agent may be one of the most efficient percolating melt to cause disequlibrium interaction or Sr-Nd isotope decoupling. To a broader interpretation, it offers an alternative to account for some enriched signatures in mantle lithosphere, such

  17. Isotopic and geochemical constraints on lead and fluid sources of the Pbsbnd Znsbnd Ag mineralization in the polymetallic Tighza-Jbel Aouam district (central Morocco), and relationships with the geodynamic context

    NASA Astrophysics Data System (ADS)

    Rossi, Magali; Gasquet, Dominique; Cheilletz, Alain; Tarrieu, Leïla; Bounajma, Hassan; Mantoy, Tristan; Reisberg, Laurie; Deloule, Etienne; Boulvais, Philippe; Burnard, Pete

    2017-03-01

    The Wsbnd Au, Pbsbnd Znsbnd Ag, and Sbsbnd Ba mineralizations of the polymetallic Tighza-Jbel Aouam district (central Meseta, Morocco), are hosted in Paleozoic rocks surrounding late-Carboniferous granitic stocks. The Pbsbnd Znsbnd Ag Tighza deposit formed at 254 ± 16 Ma, and is clearly disconnected from the late-Variscan Wsbnd Au deposit (295-280 Ma). The Pbsbnd Znsbnd Ag mineralization precipitated from a complex hydrothermal fluid. It displays air-normalized 3He/4He ratio (0.018-0.103) typical of the upper crust. This crustal component is confirmed by the oxygen and carbon isotope compositions (δ18O = +19 to +25‰; δ13C = -3.6 to -11.2‰) and the ɛNd values (-4.84 to -9.01) of gangue carbonates, which show mixing of (i) fluids that have interacted with late-Carboniferous magmatic rocks, and (ii) fluids in equilibrium with the Paleozoic metasediments. In addition, the Pbsbnd Znsbnd Ag mineralization has 40Ar/36Ar values in the range 284-315 typical of a meteoric fluid. The radiogenic Pb isotopic compositions (207Pb/204Pb = 15.70-15.80 and 206Pb/204Pb = 18.30-18.50) suggest leaching of Pb from the surrounding Paleozoic metasediments and late-Variscan granites, whereas the low radiogenic signatures (207Pb/204Pb = 15.40 and 206Pb/204Pb = 18.05) provide evidence of a deeper source attributed to the lower crust. Crustal thinning related to extensional tectonics in late-Permian and Early-Triassic lead to high-K calc-alkaline to alkaline magmatic activity, which is evidenced by a dense SW-NE-trending dike network that pre-dated the Atlantic Ocean opening (early Liassic times). This magmatic event induced a regional heat flux increase that triggered the circulation of a complex hydrothermal fluid, which has a strong crustal component, but also a meteoric and a lower crustal components. The polymetallic district of Tighza-Jbel Aouam thus results from superposition of an intrusion related porphyry-gold mineralization (Wsbnd Au, 286 Ma) followed by a Pbsbnd Znsbnd Ag

  18. Geochemistry, geochronology and isotope geology of Nakfa intrusive rocks, northern Eritrea: products of a tectonically thickened Neoproterozoic arc crust

    NASA Astrophysics Data System (ADS)

    Teklay, M.; Kröner, A.; Mezger, K.

    2001-08-01

    The north-south-trending Neoproterozoic volcano-sedimentary plutonic associations in northern Eritrea are part of the Nubian Shield. The Nakfa intrusive rocks range in composition from gabbro to syeno-diorite to granite and alkaline syenite and intrude supracrustal rocks of volcanic and sedimentary origin. All granitoid rocks are metaluminous or slightly peraluminous and have typical I-type chemical signatures. The calc-alkaline intrusive rocks and the alkaline syenites have geochemical characteristics (e.g. low Nb values) typical of arc intrusives and plot as volcanic arc granites on various discriminant diagrams. Single zircon evaporation Pb-Pb ages and conventional multigrain U-Pb ages on zircons and titanites yielded emplacement ages of ˜620-640 Ma. These are comparable to those of adjacent juvenile terranes in the Nubian Shield. No pre-Pan-African rocks have so far been found in northern Eritrea. Isotopic data show a limited range, with initial ɛ Nd values ranging from 3.5 to 5.6 and initial Sr ratios from 0.7018 to 0.7037. The high positive initial ɛ Nd values and low initial Sr ratios indicate that the granitoid rocks were derived from a mantle and/or juvenile crustal source with no, or only insignificant, contribution from an older continental component. This is further supported by the absence of inherited zircons and the lack of rocks of continental affinity. Leached K-feldspars from Nakfa intrusive rocks have Pb isotope ratios ( 206Pb/ 204Pb = 17.60-17.88, 207Pb/ 204Pb = 15.49-15.53 and 208Pb/ 204Pb = 37.12-37.37) similar to those for 'oceanic leads' from Saudi Arabia, which are interpreted as manifesting a mantle source. Hence, the Pb isotope ratios, in agreement with the Sr and Nd isotopic data, indicate an insignificant involvement of older crustal components in the generation of Pan-African crust in northern Eritrea. The ages and isotopic characteristics of the Nakfa intrusive rocks are comparable to those of adjacent juvenile terranes in the

  19. Geochemical and Sr-Nd-Pb Isotopic Insights of the Low-Ti basalts from Paraná-Etendeka Igneous Province, Southern Brazil: Constraints on Petrogenesis and the Role of Crustal Contamination

    NASA Astrophysics Data System (ADS)

    Raposo, I.; Barreto, C. J.; Lima, E. F. D.; Lafon, J. M.; Sommer, C. A.; Waichel, B. L.

    2015-12-01

    The south hinge of the Torres Syncline in southernmost Brazil hosts a volcanic succession of pahoehoe and rubbly Gramado-type lavas belonging to the ~132 Ma Paraná-Etendeka Igneous Province. We employ local-scale stratigraphy in three distinct profiles (Santa Cruz do Sul-Herveiras, Morro da Cruz and Lajeado geologic sections) as guidelines for geochemical and Sr-Nd-Pb isotope studies in order to discuss the petrogenesis of lava flows in a single magma type and to quantitatively evaluate the role of crustal contamination and the potential contaminants involved. In all profiles, the lava flows exhibit compositions ranging from basalt to andesite with tholeiitic affinity. The compositional and isotopic variations are not systematic according to stratigraphy, implying that the magma chamber could have undergone periodic replenishments or distinct magma pulses through time or multiple plumbling systems may have existed. The andesites (SiO2 55-58 wt.%) with ponded pahoehoe morphology represent evolved melts at early stages of volcanism with strong susceptibility to crustal contamination as they established pathways to the surface. The olivine basalts (SiO2 47-50 wt.%) and basaltic andesites (SiO2 51-56 wt.%) showing compound morphology and simple pahoehoe morphology, respectively, could be explained by longer time residence of liquids in the crust with higher degrees of crustal assimilation than the ponded pahoehoe lavas. The basaltic andesites (SiO2 52-56 wt. %) with rubbly morphology are related to late differentiation process in shallow magma chambers. Crustal assimilation process accounts for the high initial 87Sr/86Sr ratios at 0.707798-0.715751, very low ɛNd between -8.36 and -5.41, high 206Pb/204Pb ratios at 18.424-18.865, with intermediate 207Pb/204Pb and 208Pb/204Pb ratios at 15.649-15.710 and 38.618-39.369, respectively. The isotopic variations require assimilation of both Paleoproterozoic and Neoproterozoic contaminants at variable degrees.

  20. Sm-Nd dating and REE Composition of scheelite for the Honghuaerji scheelite deposit, Inner Mongolia, Northeast China

    NASA Astrophysics Data System (ADS)

    Guo, Zhijun; Li, Jinwen; Xu, Xinying; Song, Zeyou; Dong, Xuzhou; Tian, Jing; Yang, Yuncheng; She, Hongquan; Xiang, Anping; Kang, Yongjian

    2016-09-01

    Sm-Nd analyses of seven scheelite samples from scheelite-quartz veins in the Honghuaerji scheelite deposit produce a well-defined linear array on an isochron diagram with a mean square weighted deviation (MSWD) of 0.87 corresponding to an age of 178.4 ± 2.9 Ma with εNd(t) = + 1.50. This age is interpreted to represent the age of scheelite mineralization. The scheelite Sm-Nd age is in good agreement with U-Pb ages obtained from a mineralization-related granite (179.4 178.6 Ma), indicating that there is no apparent age gap between granite crystallization and ore formation. Rare earth element (REE) abundances in the scheelite were determined by in situ laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS), and the scheelite samples contain elevated REE concentrations with total ΣREE + Y contents in the range of 3339 to 6321 ppm. The chondrite-normalized REE distribution patterns of all scheelites are middle REE (MREE)-enriched, with strong negative Eu-anomalies (Eu/Eu* = 0.09 0.23). The REE characteristics of the Honghuaerji scheelite suggest that REE3 + substituted into the Ca site along with Na and Nb (dominated by Na), whereas Eu is predominantly present as Eu2 + in the scheelite and may have crystallized from relatively reduced fluids. All sulfur isotope data (δ34S) for sulfide separates range from + 2.0 to + 3.8‰, with an average of 3.2‰. Measured 206Pb/204Pb, 207Pb/204Pb, and 208Pb/204Pb ratios vary from 18.243 to 18.451, 15.494 to 15.574, and 37.933 to 38.340, respectively. On the basis of common Sr-Nd-Pb-Hf isotopic characteristics between the scheelite and the host granite and the positive initial Nd isotope ratios (+ 1.46 - + 1.52), low 87Sr/86Sr ratios (0.704983-0.705297) in the scheelites, it is inferred that the hydrothermal fluids responsible for tungsten mineralization at Honghuaerji were of magmatic origin with a mantle-derived signature. Based on the regional geology, tectonic evolution, and geochemical evidence, the

  1. Tracking mobility using human hair: What can we learn from lead and strontium isotopes?

    PubMed

    Vautour, Geneviève; Poirier, André; Widory, David

    2015-01-01

    The isotope ratios of strontium (Sr) and lead (Pb) in water derive from local geology and their isotopic signature can be linked to the age and type of underlying bedrocks and soils (if applicable), and are transferred up the food-chain. Both elements are transferred to human blood through diet and water, and some of it will ultimately be incorporated into the hair structure, making Sr and Pb isotopes interesting tools for tracing human mobility. In this study, we analyzed both the elemental concentration and isotope ratios of Sr and Pb from four different women of different ages to monitor their permanent relocation from central France to Eastern Canada during the summer 2012. For comparison, we also characterized bulk hair samples of sedentary individuals and local tap waters from their regions of origin and of settlement. Our results indicate that the 87Sr/86Sr and 206Pb/204Pb ratios are significantly modified by the change of environment, but also confirm that human hair compositions are impacted by other external factors (such as dust). Sr and Pb isotope systematics demonstrate their added value for detecting human mobility, but require further studies to better constrain the main sources and processes controlling their respective budgets in human hair for provenancing purposes.

  2. [High-precision in situ analysis of the lead isotopic composition in copper using femtosecond laser ablation MC-ICP-MS and the application in ancient coins].

    PubMed

    Chen, Kai-Yun; Fan, Chao; Yuan, Hong-Lin; Bao, Zhi-An; Zong, Chun-Lei; Dai, Meng-Ning; Ling, Xue; Yang, Ying

    2013-05-01

    In the present study we set up a femtosecond laser ablation MC-ICP-MS method for lead isotopic analysis. Pb isotopic composition of fifteen copper (brass, bronze) standard samples from the National Institute of Standards Material were analyzed using the solution method (MC-ICP-MS) and laser method (fLA-MC-ICPMS) respectively, the results showed that the Pb isotopic composition in CuPb12 (GBW02137) is very homogeneous, and can be used as external reference material for Pb isotopic in situ analysis. On CuPb12 112 fLA-MC-ICPMS Pb isotope analysis, the weighted average values of the Pb isotopic ratio are in good agreement with the results analyzed by bulk solution method within 2sigma error, the internal precision RSEs of the 208 Pb/204 Pb ratio and 207 Pb/206 Pb ratio are less than 90 and 40 ppm respectively, and the external precision RSDs of them are less than 60 and 30 ppm respectively. Pb isotope of thirteen ancient bronze coins was analyzed via fLA-MC-ICPMS, the results showed that the Pb isotopic composition of ancient coins of different dynasties is significantly different, and not all the Pb isotopic compositions in the coins even from the same dynasty are in agreement with each other.

  3. A study of radionuclides, metals and stable lead isotope ratios in sediments and soils in the vicinity of natural U-mineralisation areas in the Northern Territory.

    PubMed

    Frostick, A; Bollhöfer, A; Parry, D

    2011-10-01

    Australian guidelines recommend that tailings materials from uranium (U) mining and milling be contained without any detrimental impact on the environment for at least 1000 years. Natural analogue sites are being investigated to determine if they can provide data on the rates of natural erosion processes which occur over these timescales, for input into predictive geomorphic computer models. This paper presents radionuclide, metal and stable lead (Pb) isotope data from sediment cores and surface soils in the vicinity of two mineralised areas in the Alligator Rivers Region. Surface scrapes from the natural Anomaly #2, south of the Ranger mineral lease, exhibit radiogenic (206)Pb/(207)Pb and (208)Pb/(207)Pb ratios, and elevated U and metal concentrations typical for a near surface U anomaly. In contrast, samples taken from the Koongarra mineral lease (KML) show radionuclide activity and metal concentrations similar to natural areas elsewhere in the Alligator Rivers Region and Pb isotope ratios are closer to present day average crustal ratios (PDAC), as the orebodies at KML are covered by surficial sand. A sediment core collected from Anbangbang Billabong, downstream of KML, exhibits small variations in Pb isotope ratios that indicate that approximately 1% of the upper sediments in the sediment core may be derived from material originating from the U anomaly at Koongarra.

  4. Petrogenesis of the Yaochong granite and Mo deposit, Western Dabie orogen, eastern-central China: Constraints from zircon U-Pb and molybdenite Re-Os ages, whole-rock geochemistry and Sr-Nd-Pb-Hf isotopes

    NASA Astrophysics Data System (ADS)

    Chen, Wei; Xu, Zhaowen; Qiu, Wenhong; Li, Chao; Yu, Yang; Wang, Hao; Su, Yang

    2015-05-01

    The Dabie orogen is among the most famous continent-continent collisional orogenic belts in the world, and is characterized by intensive post-collisional extension, magmatism and Mo mineralization. However, the genetic links between the mineralization and the geodynamic evolution of the orogen remain unresolved. In this paper, the Yaochong Mo deposit and its associated granitic stocks were investigated to elucidate this issue. Our new zircon U-Pb ages yielded an Early Cretaceous age (133.3 ± 1.3 Ma) for the Yaochong granite, and our molybdenite Re-Os dating gave a similar age (135 ± 1 Ma) for the Mo deposit. The Yaochong stock is characterized by high silica and alkali but low Mg, Fe and Ca. It is enriched in light rare earth elements (LREEs) and large ion lithophile elements (LILEs: Rb, K, Th and U), but strongly depleted in heavy REEs, and high field strength elements (HFSEs: Nb, Ta, Ti and Y). The Yaochong granite has initial 87Sr/86Sr ratios of 0.7087-0.7096, and Pb isotopic ratios of (206Pb/204Pb)i = 16.599-16.704, (207Pb/204Pb)i = 15.170-15.618 and (208Pb/204Pb)i = 36.376-38.248. The granite has εNd(t) of -18.0 to -16.3 and εHf(t) values of -26.5 to -20.0. All these data indicate that the Yaochong granite is a high-K calc-alkaline fractionated I-type granite, and may have originated from partial melting of the thickened Yangtze continental crust. The Mo ores also show low radiogenic Pb isotopes similar to the Yaochong stock. Medium Re content in molybdenite (21.8-74.8 ppm) also suggests that the ore-forming materials were derived from the thickened lower crust with possibly minor mixing with the mantle. Similar to the Eastern Dabie orogen, the thickened crust beneath the Western Dabie orogen may also have experienced tectonic collapse, which may have exerted fundamental geodynamic controls on the two-stage Mo mineralization in the region.

  5. Late Permian basalts in the Yanghe area, eastern Sichuan Province, SW China: Implications for the geodynamics of the Emeishan flood basalt province and Permian global mass extinction

    NASA Astrophysics Data System (ADS)

    Li, Hongbo; Zhang, Zhaochong; Santosh, M.; Lü, Linsu; Han, Liu; Liu, Wei

    2017-02-01

    We report the finding of a ∼20 m thick sequence of massive pyroxene-plagioclase-phyric basalt lava flows in the Yanghe area of the northeastern Sichuan Basin, within the Yangtze craton of SW China, which were previously considered to be located outside the Emeishan flood basalt province. This basaltic sequence above the middle Permian Maokou Formation (Fm.) is overlain by the late Permian Longtan Fm. Thus, the Yanghe basalts should be stratigraphically correlated with the Emeishan flood basalts. The Yanghe basalts show typical oceanic island basalt (OIB) affinity, and geochemically resemble Emeishan basalts, especially in the case of high-Ti (HT) basalts from the eastern domain of the Emeishan flood basalt province. The rocks have low age-corrected (87Sr/86Sr)t (t = 260 Ma) ratios (0.704158-0.704929) and Pb isotopic ratios [206Pb/204Pb(t) (18.264-18.524), 207Pb/204Pb(t) (15.543-15.58), and 208Pb/204Pb(t) (38.147-38.519)], and positive εNd(t) values (+3.15 to +3.61), suggesting that the lavas have not undergone any significant crustal contamination. The crystallization temperature of clinopyroxene is estimated to be 1368-1420 °C, suggesting anomalously thermal inputs from a mantle source and a possible plume-head origin. The fractionation of middle rare earth elements (MREE) to heavy REE (HREE) suggests that these rocks were produced by small degrees of partial melting of mantle peridotite within the garnet-spinel transition region. The stratigraphic relationships and similar geochemical signatures with the Emeishan flood basalts suggest that the Yanghe basalts are part of the Emeishan flood basalt province and can be considered as the northeastern limit of the Emeishan flood basalt province. Our finding extends the diameter of the Emeishan flood basalt province to ∼1200-1400 km, covering an area of up to ∼7 × 105 km2, two times more than previously estimated. The larger areal extent and giant eruption volume, incorporating the Sichuan Basin, lend support

  6. Lead isotopes in North Pacific deep water - Implications for past changes in input sources and circulation patterns

    USGS Publications Warehouse

    van de Flierdt, T.; Frank, M.; Halliday, A.N.; Hein, J.R.; Hattendorf, B.; Gunther, D.; Kubik, P.W.

    2003-01-01

    The sources of non-anthropogenic Pb in seawater have been the subject of debate. Here we present Pb isotope time-series that indicate that the non-anthropogenic Pb budget of the northernmost Pacific Ocean has been governed by ocean circulation and riverine inputs, which in turn have ultimately been controlled by tectonic processes. Despite the fact that the investigated locations are situated within the Asian dust plume, and proximal to extensive arc volcanism, eolian contributions have had little impact. We have obtained the first high-resolution and high-precision Pb isotope time-series of North Pacific deep water from two ferromanganese crusts from the Gulf of Alaska in the NE Pacific Ocean, and from the Detroit Seamount in the NW Pacific Ocean. Both crusts were dated applying 10 Be/9Be ratios and yield continuous time-series for the past 13.5 and 9.6 Myr, respectively. Lead isotopes show a monotonic evolution in 206Pb/204Pb from low values in the Miocene (??? 18.57) to high values at present day (??? 18.84) in both crusts, even though they are separated by more than 3000 km along the Aleutian Arc. The variation exceeds the amplitude found in Equatorial Pacific deep water records by about three-fold. There also is a striking similarity in 207Pb/204Pb and 208Pb/ 204Pb ratios of the two crusts, indicating the existence of a local circulation cell in the sub-polar North Pacific, where efficient lateral mixing has taken place but only limited exchange (in terms of Pb) with deep water from the Equatorial Pacific has occurred. Both crusts display well-defined trends with age in Pb-Pb isotope mixing plots, which require the involvement of at least four distinct Pb sources for North Pacific deep water. The Pb isotope time-series reveal that eolian supplies (volcanic ash and continent-derived loess) have only been of minor importance for the dissolved Pb budget of marginal sites in the deep North Pacific over the past 6 Myr. The two predominant sources have been young

  7. Lead isotopes in North Pacific deep water - implications for past changes in input sources and circulation patterns

    NASA Astrophysics Data System (ADS)

    van de Flierdt, Tina; Frank, Martin; Halliday, Alex N.; Hein, James R.; Hattendorf, Bodo; Günther, Detlef; Kubik, Peter W.

    2003-04-01

    The sources of non-anthropogenic Pb in seawater have been the subject of debate. Here we present Pb isotope time-series that indicate that the non-anthropogenic Pb budget of the northernmost Pacific Ocean has been governed by ocean circulation and riverine inputs, which in turn have ultimately been controlled by tectonic processes. Despite the fact that the investigated locations are situated within the Asian dust plume, and proximal to extensive arc volcanism, eolian contributions have had little impact. We have obtained the first high-resolution and high-precision Pb isotope time-series of North Pacific deep water from two ferromanganese crusts from the Gulf of Alaska in the NE Pacific Ocean, and from the Detroit Seamount in the NW Pacific Ocean. Both crusts were dated applying 10Be/ 9Be ratios and yield continuous time-series for the past 13.5 and 9.6 Myr, respectively. Lead isotopes show a monotonic evolution in 206Pb/ 204Pb from low values in the Miocene (≤18.57) to high values at present day (≥18.84) in both crusts, even though they are separated by more than 3000 km along the Aleutian Arc. The variation exceeds the amplitude found in Equatorial Pacific deep water records by about three-fold. There also is a striking similarity in 207Pb/ 204Pb and 208Pb/ 204Pb ratios of the two crusts, indicating the existence of a local circulation cell in the sub-polar North Pacific, where efficient lateral mixing has taken place but only limited exchange (in terms of Pb) with deep water from the Equatorial Pacific has occurred. Both crusts display well-defined trends with age in Pb-Pb isotope mixing plots, which require the involvement of at least four distinct Pb sources for North Pacific deep water. The Pb isotope time-series reveal that eolian supplies (volcanic ash and continent-derived loess) have only been of minor importance for the dissolved Pb budget of marginal sites in the deep North Pacific over the past 6 Myr. The two predominant sources have been young

  8. Pb, Sr, and Nd isotopes in seamount basalts from the Juan de Fuca Ridge and Kodiak-Bowie seamount chain, northeast Pacific

    USGS Publications Warehouse

    Hegner, E.; Tatsumoto, M.

    1989-01-01

    Pb, Sr, and Nd isotopic ratios and their parent/daughter element concentrations for 28 basalts from 10 hotspot and nonhotspot seamounts are reported. Nd and Sr isotopic compositions (143Nd/144Nd = 0.51325-0.51304; 87Sr/86Sr = 0.70237-0.70275) plot in the envelope for Juan de Fuca-Gorda ridge basalts with tholeiitic basalts showing more depleted sources and a better negative correlation than transitional to alkalic basalts. Pb isotopic ratios in tholeiitic and alkalic basalts overlap (206Pb/204Pb = 18.29-19.44) and display a trend toward more radiogenic Pb in alkalic basalts. The isotopic data for hotspot and nonhotspot basalts are indistinguishable and correlate broadly with rock composition, implying that they are controlled by partial melting. The isotopic variation in the seamount basalts is about 60% (Nd-Sr) to 100% (Pb) of that in East Pacific Rise basalts and is interpreted as a lower limit for the magnitude of mantle heterogeneity in the northeast Pacific. The data indicate absence of a chemically distinct plume component in the linear seamount chains and strongly suggest an origin from mid-ocean ridge basalt-like east Pacific mantle. -Authors

  9. Basalt Geochemistry of the Endeavour Segment, Juan de Fuca Ridge

    NASA Astrophysics Data System (ADS)

    Woodcock, J. P.; Gill, J.; Kela, J.; Michael, P.; Ramos, F.

    2006-12-01

    We present new trace element, volatile, isotope, and modeling data for mid-ocean ridge basalts (MORB) from the Endeavour Axial Ridge Volcano (EARV) segment of the Juan de Fuca Ridge. Endeavour MORB are categorized to a first order using K2O/TiO2, with T-MORB = 0.15-0.25, N-MORB lower, and E- MORB higher. Within these groups, there are 2 subgroups of N-MORB and 3 of T-MORB, distinguished by differences in Si8, Fe8, Ti8, and differentiation paths. Liquid lines of descent are best explained by crystallization within the crust at measured water contents (0.2-0.5 wt. %). EARV basalts exhibit spatial heterogeneities that far exceed what can be explained by these fractional crystallization models. Incompatible trace element ratios such as Zr/Nb, La/Yb, and K2O/TiO2 exhibit 3- to 4-fold variations, indicating heterogeneity of source or melting processes. The heterogeneity is observed along axis in samples only tens to hundreds of meters apart and is most prominent along the western wall of the axial valley, suggesting that axial magma chambers may be short-lived. Despite their heterogeneity, axial samples have nearly constant 87Sr/86Sr and ^{143}Nd/^{144}Nd ratios. Pb isotopes are more variable (206Pb/204Pb = 18.35-18.90). The heterogeneity seems unrelated to the chemical influence of a plume or the thermal perturbations of a transform fault.

  10. Hafnium isotope variations in oceanic basalts.

    USGS Publications Warehouse

    Patchett, P.J.; Tatsumoto, M.

    1980-01-01

    Routine low-blank chemistry and 0.01-0.04% precision on the ratio 176Hf/177Hf allows study of Hf isotopic variations, generated by beta --decay of 176Lu, in volcanic rocks derived from the suboceanic mantle. Normalized to 176Hf/177Hf = 0.7325, 176Hf/177Hf ranges 0.2828-0.2835, based on 24 basalt samples. 176Hf/177Hf is positively correlated with 143Nd/144Nd, and negatively correlated with 87Sr/86Sr and 206Pb/204Pb. Along the Iceland-Reykjanes ridge traverse, 176Hf/177Hf increases southwards. The coherence of Hf, Nd and Sr isotopes in the oceanic mantle allows an approximate bulk Earth 176Hf/177Hf of 0.28295 to be inferred from the bulk Earth 143Nd/144Nd. This requires the bulk Earth Lu/Hf to be 0.25, similar to that of the Juvinas eucrite. 60% of the Hf isotopic variation in oceanic basalts occurs among mid-ocean ridge samples. Lu-Hf fractionation probably decouples from Sm-Nd and Rb-Sr fractionation in very depleted source regions, with high Lu/Hf, and consequent high 176Hf/177Hf ratios developing in mantle residual from partial melting. (Authors' abstract) -T.R.

  11. Using stable lead isotopes to trace heavy metal contamination sources in sediments of Xiangjiang and Lishui Rivers in China.

    PubMed

    Sun, Guo-Xin; Wang, Xin-Jun; Hu, Qin-Hong

    2011-12-01

    Lead isotopes and heavy metal concentrations were measured in two sediment cores sampled in estuaries of Xiangjiang and Lishui Rivers in Hunan province, China. The presence of anthropogenic contribution was observed in both sediments, especially in Xiangjiang sediment. In the Xiangjiang sediment, the lower (206)Pb/(207)Pb and higher (208)Pb/(206)Pb ratio, than natural Pb isotope signature (1.198 and 2.075 for (206)Pb/(207)Pb and (208)Pb/(206)Pb, respectively), indicated a significant input of non-indigenous Pb with low (206)Pb/(207)Pb and high (208)Pb/(206)Pb. The corresponding concentrations of heavy metals (As, Cd, Zn, Mn and Pb) were much higher than natural values, suggesting the contaminations of heavy metals from extensive ore-mining activities in the region.

  12. Determination of trace element concentrations and stable lead, uranium and thorium isotope ratios by quadrupole-ICP-MS in NORM and NORM-polluted sample leachates.

    PubMed

    Mas, J L; Villa, M; Hurtado, S; García-Tenorio, R

    2012-02-29

    This work focuses on the monitoring of the potential pollution in scenarios that involve NORM-related industrial activities (environmental or in-door scenarios). The objective was to develop a method to determine extent and origin of the contamination, suitable for monitoring (i.e. simple, fast and economical) and avoiding the use of too many different instruments. It is presented a radiochemical method that allows the determination of trace element concentrations and 206Pb/207Pb/208Pb, 238U/234U and 232Th/230Th isotope ratios using a single sample aliquot and a single instrument (ICP-QMS). Eichrom UTEVA® extraction chromatography minicolumns were used to separate uranium and thorium in sample leachates. Independent ICP-MS determinations of uranium and thorium isotope ratios were carried out afterwards. Previously a small aliquot of the leachate was used for the determination of trace element concentrations and lead isotope ratios. Several radiochemical arrangements were tested to get maximum performances and simplicity of the method. The performances of the method were studied in terms of chemical yields of uranium and thorium and removal of the potentially interfering elements. The established method was applied to samples from a chemical industry and sediments collected in a NORM-polluted scenario. The results obtained from our method allowed us to infer not only the extent, but also the sources of the contamination in the area.

  13. Isotope geochemistry and fluid inclusion study of skarns from Vesuvius

    USGS Publications Warehouse

    Gilg, H.A.; Lima, A.; Somma, R.; Belkin, H.E.; de Vivo, B.; Ayuso, R.A.

    2001-01-01

    We present new mineral chemistry, fluid inclusion, stable carbon and oxygen, as well as Pb, Sr, and Nd isotope data of Ca-Mg-silicate-rich ejecta (skarns) and associated cognate and xenolithic nodules from the Mt. Somma-Vesuvius volcanic complex, Italy. The typically zoned skarn ejecta consist mainly of diopsidic and hedenbergitic, sometimes "fassaitic" clinopyroxene, Mg-rich and Ti-poor phlogopite, F-bearing vesuvianite, wollastonite, gehlenite, meionite, forsterite, clinohumite, anorthite and Mg-poor calcite with accessory apatite, spinell, magnetite, perovskite, baddeleyite, and various REE-, U-, Th-, Zr- and Ti-rich minerals. Four major types of fluid inclusions were observed in wollastonite, vesuvianite, gehlenite, clinopyroxene and calcite: a) primary silicate melt inclusions (THOM = 1000-1050??C), b) CO2 ?? H2S-rich fluid inclusions (THOM = 20-31.3??C into the vapor phase), c) multiphase aqueous brine inclusions (THOM = 720-820??C) with mainly sylvite and halite daughter minerals, and d) complex chloride-carbonate-sulfate-fluoride-silicate-bearing saline-melt inclusions (THOM = 870-890??C). The last inclusion type shows evidence for immiscibility between several fluids (silicate melt - aqueous chloride-rich liquid - carbonate/sulfate melt?) during heating and cooling below 870??C. There is no evidence for fluid circulation below 700??C and participation of externally derived meteoric fluids in skarn formation. Skarns have considerably variable 206Pb/204Pb (19.047-19.202), 207Pb/204Pb (15.655-15.670), and 208Pb/204Pb (38.915-39.069) and relatively low 143Nd/144Nd (0.51211-0.51244) ratios. The carbon and oxygen isotope compositions of skarn calcites (??13CV-PDB = -5.4 to -1.1???; ??18OV-SMOW = 11.7 to 16.4???) indicate formation from a 18O- and 13C-enriched fluid. The isotope composition of skarns and the presence of silicate melt inclusion-bearing wollastonite nodules suggests assimilation of carbonate wall rocks by the alkaline magma at moderate depths (< 5

  14. Geochemical heterogeneities within the Crozet hotspot

    NASA Astrophysics Data System (ADS)

    Breton, Thomas; Nauret, François; Pichat, Sylvain; Moine, Bertrand; Moreira, Manuel; Rose-Koga, Estelle F.; Auclair, Delphine; Bosq, Chantal; Wavrant, Laurène-Marie

    2013-08-01

    The Crozet Plateau is a 54 Ma-old volcanic plateau that supports five islands characterized by recent volcanic manifestations that are the surface expression of a deep-mantle plume. Due to their remote location and difficult access, the Crozet Islands are poorly sampled. Both the petrological descriptions and geochemical data are scarce. Thus, the sources of the Crozet plume are still under debate. Similarly, the interactions between the Southwest Indian Ridge (SWIR) and the Crozet plume remain questioned. Here, we present a new set of isotopes (Pb, Sr, Nd and He), major and trace elements data on basalts from three islands of the Crozet Archipelago: Penguins, East, and Possession Islands. Our main purpose is to characterize the sources of the Crozet plume and to test its influence at regional scale. Two groups of lavas can be distinguished based on the isotopic data: East and Possession lavas, and Penguins lavas. Principal component analyses on our high-precision Pb isotopes data and literature data show that two mantle sources can explain most of the geochemical variability measured in Crozet lavas. A third minor contribution is however needed to fully explain the data. The entire set of isotopic compositions (Pb, Sr, Nd and He) can be explained by a mixing between three mantle sources: (1) a FOZO (Focus Zone) component, with 206Pb/204Pb higher than 19.5 and high 207Pb/204Pb, 208Pb/204Pb 87Sr/86Sr, 143Nd/144Nd and R/Ra (R/Ra=(He3/He4)sample/(He3/He4)atmosphere) ratios, that is mainly sampled Penguins lavas, (2) a component called “East-Possession” that is mostly sampled by the East-Possession lava group and which presents Pb, Sr and Nd isotope signatures similar to those of the Reunion-Mauritius Islands, and (3) a third minor contribution of the local Depleted MORB Mantle (DMM). The new He isotopes data on the Crozet plume allow us to propose that Crozet plume material is present in the segment of the Southwest Indian Ridge located between the Indomed (ITF

  15. Temporal and geochemical evolution of the Cenozoic intraplate volcanism of Zealandia

    NASA Astrophysics Data System (ADS)

    Timm, Christian; Hoernle, Kaj; Werner, Reinhard; Hauff, Folkmar; den Bogaard, Paul van; White, James; Mortimer, Nick; Garbe-Schönberg, Dieter

    2010-01-01

    In order to constrain better the distribution, age, geochemistry and origin of widespread Cenozoic intraplate volcanism on Zealandia, the New Zealand micro-continent, we report new 40Ar/ 39Ar and geochemical (major and trace element and Sr-Nd-Hf-Pb isotope) data from offshore (Chatham Rise, Campbell and Challenger Plateaus) and onland (North, South, Auckland, Campbell, Chatham and Antipodes Islands of New Zealand) volcanism on Zealandia. The samples include nephelinite, basanite through phonolite, alkali basalt through trachyte/rhyolite, and minor tholeiite and basaltic andesite, all of which have ocean island basalt (OIB)-type trace element signatures and which range in age from 64.8 to 0.17 Ma. Isotope ratios show a wide range in composition ( 87Sr/ 86Sr = 0.7027-0.7050, 143Nd/ 144Nd = 0.5128-0.5131, 177Hf/ 176Hf = 0.2829-0.2831, 206Pb/ 204Pb = 18.62-20.67, 207Pb/ 204Pb = 15.54-15.72 and 208Pb/ 204Pb = 38.27-40.34) with samples plotting between mid-ocean-ridge basalts (MORB) and Cretaceous New Zealand intraplate volcanic rocks. Major characteristics of Zealandia's Cenozoic volcanism include longevity, irregular distribution and lack of age progressions in the direction of plate motion, or indeed any systematic temporal or spatial geochemical variations. We believe that these characteristics can be best explained in the context of lithospheric detachment, which causes upwelling and melting of the upper asthenospheric mantle and portions of the removed lithosphere. We propose that a large-scale seismic low-velocity anomaly, that stretches from beneath West Antarctica to Zealandia at a depth of > 600 km may represent a geochemical reservoir that has been in existence since the Cretaceous, and has been supplying the upper mantle beneath Zealandia with HIMU-type plume material throughout the Cenozoic. In addition, the sources of the Cenozoic intraplate volcanism may be at least partially derived through melting of locally detached Zealandia lower lithosphere.

  16. Geochemical and isotopic perspectives on the origin and evolution of the Siletzia Terrane.

    NASA Astrophysics Data System (ADS)

    Phillips, B. A.; Weis, D.; Mullen, E.; Kerr, A. C.

    2015-12-01

    The Siletzia terrane, located in the Cascadia forearc region of Oregon, Washington and Vancouver Island, consists of a series of accreted basaltic pillow lavas, massive flows and intrusive sheets. It represents a late Paleocene-Eocene oceanic large igneous province (LIP), previously proposed to represent an accreted oceanic plateau, hotspot island chain, backarc basin, island arc, or a sequence of slab window volcanics formed by ridge subduction. A province-wide geochemical reassessment of the terrane, including new high precision Sr-Pb-Nd-Hf isotope data on basaltic samples, has been used to assess the validity of the proposed tectonomagmatic models for Siletzia. The trace element data show REE patterns that are flat to LREE enriched with an absence of any arc signatures. These features are comparable to other oceanic plateaus such as the Ontong Java and the Caribbean and so therefore support a mantle plume origin. Initial isotope ratios range from 206Pb/204Pb = 18.869 - 19.673, 207Pb/204Pb = 15.527 - 15.609, 208Pb/204Pb = 38.551 - 39.220, ɛHf = +9.0 - 14.8, ɛNd = +5.0 - 8.0 and 87Sr/86Sr = 0.70304 - 0.70397. The isotope signatures become more varied southward across the terrane and reveal two trends: i) HIMU-DMM and ii) another extending from DMM towards the Imnaha component, thought to represent the mantle plume source of the Columbia River Basalts and Yellowstone 1,2. The data may support the previously proposed idea that the volcanism of the Siletzia terrane represents initial melting of the mantle plume head of the Yellowstone hotspot 3,4,5. Other evidence indicating a LIP origin includes the relatively rapid eruption/intrusion of an estimated magma volume of 2.6 x 106 km3 6 between ~56-49 Ma 5, which, in conjunction with our new elemental and isotopic data, indicates that the Siletzia terrane most likely represents an accreted oceanic plateau. 1. Wolff et al., (2008) Nature Geoscience 1, 177-180. 2. Jean et al., (2014) EPSL 389, 119-131 3. Duncan (1982

  17. A Coast Mountains provenance for the Valdez and Orca groups, southern Alaska, based on Nd, Sr, and Pb isotopic evidence

    USGS Publications Warehouse

    Farmer, G.L.; Ayuso, R.; Plafker, G.

    1993-01-01

    Nd, Sr, and Pb isotopic data were obtained for fourteen fine- to coarse-grained samples of accreted flysch of the Late Cretaceous and early Tertiary Valdez and Orca Groups in southern Alaska to determine the flysch provenance. Argillites and greywackes from the Orca Group, as well as compositionally similar but higher metamorphic grade rocks from the Valdez Group, show a restricted range of correlated ??{lunate}Nd ( -0.6 to -3.8) and 87Sr 86Sr (0.7060-0.7080) at the time of sediment deposition ( ??? 50 Ma). Pb isotopic compositions also vary over a narrow range ( 206Pb 204Pb = 19.138-19.395, 207Pb 204Pb = 15.593-15.703, 208Pb 204Pb = 38.677-39.209), and in the Orca Group the samples generally become more radiogenic with decreasing ??{lunate}Nd and increasing 87Sr 86Sr. All samples have similar trace element compositions characterized by moderate light rare earth element enrichments, and low ratios of high field strength elements to large ion lithophile elements. Based on petrographic, geochemical, and isotopic data the sedimentary rocks are interpreted to have been derived largely from a Phanerozoic continental margin arc complex characterized by igneous rocks with ??{lunate}Nd values between 0 and -5. The latter conclusion is supported by the ??{lunate}Nd values of a tonalite clast and a rhyodacite clast in the Orca Group (??{lunate}Nd = -4.9 and -0.9, respectively). However, trondjemitic clasts in the Orca Group have significantly lower ??{lunate}Nd ( ??? -10) and require a derivation of a portion of the flysch from Precambrian crustal sources. The Nd, Sr, and Pb isotopic compositions of both the Valdez and Orca Groups overlap the values determined for intrusive igneous rocks exposed within the northern portion of the Late Cretaceous to early Tertiary Coast Mountains Plutonic Complex in western British Columbia and equivalent rocks in southeastern Alaska. The isotopic data support previous conclusions based on geologic studies which suggest that the flysch was

  18. Geochronology and geochemistry of Eocene potassic felsic intrusions in the Nangqian basin, eastern Tibet: Tectonic and metallogenic implications

    NASA Astrophysics Data System (ADS)

    Xu, Yue; Bi, Xian-Wu; Hu, Rui-Zhong; Chen, You-wei; Liu, He-qing; Xu, Lei-luo

    2016-03-01

    The Jinshajiang-Ailaoshan copper belt is the most significant porphyry copper belt in eastern Tibet. In the northern segment of this belt within the Nangqian basin, which occurs 100 km east of the Yulong porphyry copper deposit, several felsic intrusions have been recently discovered. The Yulong porphyry copper deposit is one of the largest porphyry copper deposits in China, and it is associated with peraluminous adakitic rocks formed in a post-collisional setting. The Nangqian felsic intrusions vary from syenite porphyry to monzonite porphyry in rock types. No significant Cu-Au mineralization has been found in the Nangqian felsic intrusions despite extensive exploration in recent years. LA-ICP-MS zircon U-Pb dating reveals that the Nangqian syenite porphyry and monzonite porphyry were emplaced at 35.6±0.3 Ma and from 39.5±0.3 to 37.4±0.3 Ma, respectively, similar to the age of the Yulong porphyry copper deposit. The Nangqian felsic intrusions are characterized by metaluminous compositions (A/CNK = 0.82-1.01), and they share some common features with shoshonites such as high K2O contents (4.58-5.58 wt.%), high K2O/Na2O ratios (0.92-1.28), LREE-LILE enrichments and negative Nb-Ta-Ti-P anomalies, as well as with adakites derived from an eclogite-facies source with high Al2O3 (14.98-15.74 wt.%), Sr (954-2190 ppm), Sr/Y (68-132) and La/Yb (53-85), and low Y and Yb contents. The Nangqian felsic intrusions have high initial 87Sr/86Sr (0.7050-0.7055), variable εNd(t) (- 0.31-1.43) and small variations in (206Pb/204Pb)i (18.68-18.74), (207Pb/204Pb)i (15.53-15.62) and (208Pb/204Pb)i (38.51-38.80). Zircon crystals from both syenite and monzonite porphyries are characterized by positive εHf(t) from 5.2 to 8.5. The results suggest that the syenite and monzonite magmas were differentiated from parental shoshonitic melts by fractional crystallization of olivine, clinopyroxene and minor feldspar. The parent magmas originated from a lithospheric mantle metasomatized by slab

  19. Late Paleozoic crustal history of central coastal Queensland interpreted from geochemistry of Mesozoic plutons: The effects of continental rifting

    NASA Astrophysics Data System (ADS)

    Allen, C. M.; Wooden, J. L.; Chappell, B. W.

    1997-12-01

    The eastern margin of Australia is understood to be the result of continental rifting during the Cretaceous and Tertiary. Consistent with this model, Cretaceous igneous rocks (granites to basalts) in a continental marginal setting near Bowen, Queensland are isotonically retarded, having isotopic ratios similar to those of most island arcs (Sr1 = 0.7030-0.7039, ɛNd = +6.46 to +3.00 and 206Pb/204Pb = 18.44-18.77, 207Pb/204Pb = 15.552-15.623, and 208Pb/204Pb = 37.90-38.52). These isotopic signatures are much less evolved than the Late Carboniferous-Permian batholith that many Cretaceous plutons intrude. As rocks ranging in age from about 300-100 Ma are well exposed near Bowen, we can track magma evolution through time. The significant change of magma source occurred much earlier than the Cretaceous based on the fact that Triassic granites in the same area are also isotonically primitive. We attribute the changes of magma composition to crustal rifting during the Late Permian and earliest Triassic. The Cretaceous rocks (actually latest Jurassic to Cretaceous, 145-98 Ma) themselves show compositional trends with time. Rocks of appropriate mineralogy for Al-in-hornblende geobarometry yield pressures ranging from 250 to 80 MPa for rocks ranging in age from 145 to 125 Ma, respectively. More significantly, this older group is relatively compositionally restricted, and is Sr-rich, and Y- and Zr-poor compared to 120-98 Ma rocks. This younger groups is bimodal, being comprised principally of basalts and rhyolites (granites). REE patterns for a given rock type, however, do not differ with age tribute these relatively subtle trace element differences to small differences in conditions (T, aH2O) at the site of melting. Cretaceous crustal rifting can explain the range of rock types and the spatial distribution of rocks < 120 Ma in a longitudinal strip between and overlapping with provinces of older Cretaceous intrusions. A subduction-related setting is assigned to the 145-125 Ma

  20. Late Paleozoic crustal history of central coastal Queensland interpreted from geochemistry of Mesozoic plutons: The effects of continental rifting

    USGS Publications Warehouse

    Allen, C.M.; Wooden, J.L.; Chappell, B.W.

    1997-01-01

    The eastern margin of Australia is understood to be the result of continental rifting during the Cretaceous and Tertiary. Consistent with this model, Cretaceous igneous rocks (granites to basalts) in a continental marginal setting near Bowen, Queensland are isotonically retarded, having isotopic ratios similar to those of most island arcs (Sri = 0.7030-0.7039, ??Nd = +6.46 to +3.00 and 206Pb/204Pb = 18.44-18.77, 207Pb/204Pb = 15.552-15.623, and 208Pb/204Pb = 37.90-38.52). These isotopic signatures are much less evolved than the Late Carboniferous-Permian batholith that many Cretaceous plutons intrude. As rocks ranging in age from about 300-100 Ma are well exposed near Bowen, we can track magma evolution through time. The significant change of magma source occurred much earlier than the Cretaceous based on the fact that Triassic granites in the same area are also isotonically primitive. We attribute the changes of magma composition to crustal rifting during the Late Permian and earliest Triassic. The Cretaceous rocks (actually latest Jurassic to Cretaceous, 145-98 Ma) themselves show compositional trends with time. Rocks of appropriate mineralogy for Al-in-hornblende geobarometry yield pressures ranging from 250 to 80 MPa for rocks ranging in age from 145 to 125 Ma, respectively. More significantly, this older group is relatively compositionally restricted, and is Sr-rich, and Y- and Zr-poor compared to 120-98 Ma rocks. This younger groups is bimodal, being comprised principally of basalts and rhyolites (granites). REE patterns for a given rock type, however, do not differ with age tribute these relatively subtle trace element differences to small differences in conditions (T, aH2O) at the site of melting. Cretaceous crustal rifting can explain the range of rock types and the spatial distribution of rocks < 120 Ma in a longitudinal strip between and overlapping with provinces of older Cretaceous intrusions. A subduction-related setting is assigned to the 145-125 Ma

  1. Magmas with slab fluid and decompression melting signatures coexisting in the Gulf of Fonseca: Evidence from Isla El Tigre volcano (Honduras, Central America)

    NASA Astrophysics Data System (ADS)

    Mattioli, Michele; Renzulli, Alberto; Agostini, Samuele; Lucidi, Roberto

    2016-01-01

    Isla El Tigre volcano is located in the Gulf of Fonseca (Honduras) along the Central America volcanic front, where a significant change in the strike of the volcanic chain is observed. The studied samples of this poorly investigated volcano are mainly subalkaline basic to intermediate lavas (basalts and basaltic andesites) and subordinate subalkaline/alkaline transitional basalts, both having the typical mineralogical and geochemical characteristics of arc volcanic rocks. On the basis of petrographic and geochemical features, two groups of rocks have been distinguished. Lavas from the main volcanic edifice are highly porphyritic and hy-qz normative, and have lower MgO contents (< 5 wt.%). They show significant LILE and LREE enrichments and Nb-Ta depletions, and have a strong slab signature as well as incompatible element contents similar to those of the main front of the adjacent volcanoes in El Salvador and Nicaragua (e.g., Ba/La up to 80). In contrast, lavas from the parasitic cones have higher MgO contents (> 5 wt.%), are ol-hy normative and show lower HFSE depletions relative to LILE and LREE, with lower Ba/La, Ba/Nb and Zr/Nb ratios. This suggests that mantle-derived magmas were not produced by the same process throughout the activity of the volcano. The bulk rock geochemistry and 87Sr/86Sr (0.70373-0.70382), 143Nd/144Nd (0.51298-0.51301), 206Pb/204Pb (18.55-18.58), 207Pb/204Pb (15.54-15.56) and 208Pb/204Pb (38.23-38.26) isotopic data of Isla El Tigre compared with the other volcanoes of the Gulf of Fonseca and all available literature data for Central America suggests that this stratovolcano was mainly built by mantle-derived melts driven by slab-derived fluid-flux melting, while magmas erupted through its parasitic cones have a clear signature of decompression melting with minor slab contribution. The coexistence of these two different mantle melting generation processes is likely related to the complex geodynamic setting of the Gulf of Fonseca, where the

  2. Geology, geochemistry and genesis of the Eocene Lailishan Sn deposit in the Sanjiang region, SW China

    NASA Astrophysics Data System (ADS)

    Cao, Hua-Wen; Pei, Qiu-Ming; Zhang, Shou-Ting; Zhang, Lin-Kui; Tang, Li; Lin, Jin-Zhan; Zheng, Luo

    2017-04-01

    The Lailishan deposit is an important tin deposit that is genetically associated with an Early Eocene biotite granite in the western Yunnan metallogenic belt in the Sanjiang region, SW China. This study reports new zircon U-Pb ages and Hf isotopic data, whole-rock elements, mica Ar-Ar age and C-H-O-S-Pb isotope for the Lailishan Sn deposit. The mineralization-related biotite granite crystallized during the Early Eocene (50.5 Ma), with its zircon εHf(t) values ranging from -11.5 to -7.6 and two-stage Hf model ages (TDM2) ranging from 1.60 to 1.85 Ga. The rocks are peraluminous with A/CNK values of 0.99-1.08. The granites display high Si, Al and K contents but low Mg, Fe and Ca contents. The rocks show flat chondrite-normalized REE patterns with strong Eu negative anomalies. These characteristics indicate that the magma originated from a continental crustal source. The hydrothermal muscovite exhibits an Ar-Ar plateau age of 50.4 ± 0.2 Ma. The δ18O and δD values of hydrothermal quartz from the deposit range from -7.32‰ to 4.01‰ and from -124.9‰ to -87.1‰, respectively. The δ13CPDB and δ18OSMOW values of calcite range from -11.3‰ to -3.7‰ and from +2.2‰ to +12.7‰, respectively. The sulfur isotopic compositions (δ34SV-CDT) range from +3.3‰ to +8.6‰ for sulfide separates, and the lead isotopic ratios 206Pb/204Pb, 207Pb/204Pb and 208Pb/204Pb range from 18.668 to 18.746, from 15.710 to 15.743 and from 39.202 to 39.295, respectively. These isotopic compositions are similar to those of magma-derived fluids, indicating that the ore-forming fluids and materials mainly originated from magmatic rocks with some input from meteoric water. This evidence suggests that the tin mineralization is closely linked to the Lailishan I-type granites. In combination with previous data, it is proposed in this study that widespread early Eocene magmatism resulted from the slab breakoff of the subducting Neo-Tethyan slab at ca. 55 Ma.

  3. Major, trace element and isotope geochemistry (Sr-Nd-Pb) of interplinian magmas from Mt. Somma-Vesuvius (Southern Italy)

    USGS Publications Warehouse

    Somma, R.; Ayuso, R.A.; de Vivo, B.; Rolandi, G.

    2001-01-01

    compositions in the interplinian rocks show a tendency to become slightly more radiogenic with age, from the Protohistoric (143Nd/144Nd=0.51240-0.51247) to Ancient Historic (143Nd/144Nd=0.51245-0.51251). Medieval interplinian activity (143Nd/144Nd: 0.51250-0.51241) lacks meaningful internal trends. All the interplinian rocks have virtually homogeneous compositions of 207Pb/204Pb and 208Pb/204Pb in acid-leached residues (207Pb/204Pb ???15.633 to 15.687, 208Pb/204Pb ???38.947 to 39.181). Values of 206Pb/204Pb are very distinctive, however, and discriminate among the three interplinian cycles of activity (Protohistoric: 18.929-18.971, Ancient Historic: 19.018-19.088, Medieval: 18.964-19.053). Compositional trends of major, trace element and isotopic compositions clearly demonstrate strong temporal variations of the magma types feeding the Somma-Vesuvius activity. These different trends are unlikely to be related only to low pressure evolutionary processes, and reveal variations of parental melt composition. Geochemical data suggest a three component mixing scheme for the interplinian activity. These involve HIMU-type and DMM-type mantle and Calabrian-type lower crust. Interaction between these components has taken place in the source; however, additional quantitative constraints must be acquired in order to better discriminate between magma characteristics inherited from the sources and those acquired during shallow level evolution.

  4. Bone turnover in elderly females and males using bisphosphonate treatment-A pilot study

    NASA Astrophysics Data System (ADS)

    Gulson, B. L.; Mizon, K. J.; Smith, H.; Eisman, J.; Palmer, J. M.; Korsch, M. J.; Donnelly, J.; Waite, K.

    2003-05-01

    We undertook a 2 year pilot study in premenopausal and postmenopausal females and male partners in which the subjects were administered a bisphosphonate, alendronate, for 6 months. The aim ot the study was to determine how lead isotopes and lead concentrations changed in relation to bone remodelling processes. Each subject had blood and urine samples collected for markers of bone turnover and for lead isotope studies monthly for 7-9 months before and then 3 monthly during and for up to 6 months after treatment with alendronate as an agent for inhibiting bone resorption. There were significant decreases in the lead isotope ratio, ^{206}Pb/^{204}Pb, for the migrant subjects cluring treatment compared with thepre-treatment period (p<0.01). The average bloodlead concentrations in migrant subjects decreased by about 20% during the treatment compared with the pre-treatment period (p<0.01). The changes in lead isotopic composition and lead concentration are consistent with a decrease m bone résorption and associated mobilisation of lead during alendronate therapy.

  5. Contrasting zircon morphology and UPb systematics in peralkaline and metaluminous post-orogenic granite complexes of the Arabian Shield, Kingdom of Saudi Arabia

    USGS Publications Warehouse

    Aleinikof, J.N.; Stoeser, D.B.

    1989-01-01

    Uzircon ages are reported for seven metaluminous-to-peralkaline post-orogenic granites from the Late Proterozoic Arabian Shield of Saudi Arabia. Zircons from the metaluminous rocks are prismatic, with length-to-width ratios of ??? 2-4: 1 and small pyramidal terminations. In contrast, zircons from three of the four peralkaline complexes either lack well-developed prismatic faces (are pseudo-octahedral) or are anhedral. Some zircons from the peralkaline granites contain inherited radiogenic Pb and have very high common Pb contents (206Pb/204Pb < 150), making the UPb method poorly suited for determining the age of these rocks. Zircons in the metaluminous granites do not contain inheritance and yield well-defined concordia intercepts. The span of ages of the seven complexes (670-470 Ma) indicates that post-orogenic granitic magmatism was not a singular event in the Arabian Shield but rather occurred as multiple intrusive episodes from the Late Proterozoic to the Middle Ordovician. ?? 1989.

  6. Ancient melt depletion overprinted by young carbonatitic metasomatism in the New Zealand lithospheric mantle

    NASA Astrophysics Data System (ADS)

    Scott, J. M.; Hodgkinson, A.; Palin, J. M.; Waight, T. E.; Van der Meer, Q. H. A.; Cooper, A. F.

    2014-01-01

    Spinel facies dunite, harzburgite, lherzolite and wehrlite mantle xenoliths from a cluster of Miocene volcanoes in southern New Zealand preserve evidence of the complex evolution of the underlying continental mantle lithosphere. Spinel Cr# records melt extraction with some values indicative of near complete removal of clinopyroxene. LREE-enriched, low Ti/Eu and low Al2O3 clinopyroxene and rare F-, LREE-rich apatite indicates subsequent interaction between peridotite and a metasomatising carbonatitic melt. The clearest metasomatic signature occurs in the formerly highly depleted samples because there was little or no pre-existing clinopyroxene to dilute the carbonatite signature. For the same reason, the isotopic character of the metasomatising agent is best observed in the formerly highly depleted peridotites (87Sr/86Sr = 0.7028-0.7031; 143Nd/144Nd = 0.5129; 206Pb/204Pb = 20.2-20.3). These isotope ratios are very close to, but slightly less radiogenic than, the HIMU end-member mantle reservoir. Nd isotope data imply carbonatite metasomatism occurred within the last several hundred million years, with ubiquitous pyroxene core-to-rim Al diffusion zoning indicating that it must pre-date cooling of the lithospheric mantle following Late Cretaceous-Eocene rifting of Zealandia from Gondwana. Metasomatism was significantly younger than ancient Re-depletion ages of ~2 Ga and shows that decoupling of peridotite isotope systems has occurred.

  7. Tracking lead origin in the Yellow River Estuary and nearby Bohai Sea based on its isotopic composition

    NASA Astrophysics Data System (ADS)

    Hu, Ning-jing; Huang, Peng; Liu, Ji-hua; Shi, Xue-fa; Ma, De-yi; Zhu, Ai-mei; Zhang, Jun; Zhang, Hui; He, Lian-hua

    2015-09-01

    The Pb concentration and Pb isotopes (204Pb, 206Pb, 207Pb, and 208Pb) in surface sediments from the Yellow River Estuary and nearby Bohai Sea have been determined to investigate the Pb sources in this area. Results showed that Pb in the Yellow River Estuary and northern Laizhou Bay (YRE-NL) sediments was mainly from the Yellow River catchment as a consequence of lithogenic sediments (from rock weathering) accumulation. However, Pb in the coastal area of southern Laizhou Bay (CSLB) sediments was from both natural and anthropogenic sources. Sewage discharged near the Mihe mouth of the CSLB did not extend further to the middle and outer shelves because of the current in Laizhou Bay. The total Pb concentration varied from 14.5 to 30.4 μg/g with an average concentration of 20.1 ± 4.2 μg/g. Thus, significant Pb pollution was not observed in the Yellow River Estuary and nearby Bohai Sea. However, Pb contamination in some sites was indicated by Pb isotope ratios.

  8. High-precision UPb ages of metamorphic rutile: application to the cooling history of high-grade terranes

    USGS Publications Warehouse

    Mezger, K.; Hanson, G.N.; Bohlen, S.R.

    1989-01-01

    Metamorphic rutiles occurring in granulite and upper amphibolite facies metapelitic rocks of the Archean Pikwitonei granulite domain (Manitoba) and the Proterozoic Adirondack terrane (New York) give concordant and near concordant UPb ages. The Pb concentrations in rutile range from 2.85 to 168 ppm, U concentrations range from 10.9 to 390 ppm and the measured 206Pb 204Pb ratios range from 182 to 22,100 corresponding to 238U 204Pb ratios of 398-75,100. The proportions of radiogenic 208Pb are very low, ranging from 0.0 to 6.9% of total radiogenic Pb. The habits of the rutile crystals range from stubby to acicular, the physical properties vary from opaque/black to transparent/reddish-brown. Separate batches of black and reddish-brown rutile grains from the same samples have similar U and Pb concentrations, Pb-isotope ratios, and yield the same U Pb ages within analytical uncertainty. No correlation of U concentration and 206Pb 204Pb ratios with morphology or color of the rutiles was observed among the samples analyzed. Most rutiles yield concordant UPb ages which are reproducible within analytical uncertainty, i.e. generally ??2 Ma. The UPb ages for prograde rutile are younger than the time of peak metamorphism given by UPb ages for garnet and zircon, and also younger than UPb ages for sphene and monazite, and 40Ar 39Ar and KAr ages for hornblende but older than 40Ar 39Ar and KAr ages for biotite from the same area. This suggests that the rutile ages reflect cooling below closure temperatures. Within a single hand-specimen, and thus for an identical thermal history, larger rutile grains give older ages than do smaller grains. This suggests that volume diffusion is the most probable mechanism responsible for the ages being younger than the time of peak metamorphism. It also suggests that the dimensions for such diffusion are directly related to the dimensions of the rutile crystal and not to the dimensions of sub-grain domains, as is the case for Ar diffusion in

  9. Lead isotope ratios in lichen samples evaluated by ICP-ToF-MS to assess possible atmospheric pollution sources in Havana, Cuba.

    PubMed

    Alvarez, Alfredo Montero; Estévez Alvarez, Juan R; do Nascimento, Clístenes Williams Araújo; González, Iván Pupo; Rizo, Oscar Díaz; Carzola, Lázaro Lima; Torres, Roberto Ayllón; Pascual, Jorge Gómez

    2017-01-01

    Epiphytic lichens, collected from 119 sampling sites grown over "Roistonea Royal Palm" trees, were used to assess the spatial distribution pattern of lead (Pb) and identify possible pollution sources in Havana (Cuba). Lead concentrations in lichens and topsoils were determined by flame atomic absorption spectrophotometry and inductively coupled plasma (ICP) atomic emission spectrometry, respectively, while Pb in crude oils and gasoline samples were measured by ICP-time of flight mass spectrometry (ICP-ToF-MS). Lead isotopic ratios measurements for lichens, soils, and crude oils were obtained by ICP-ToF-MS. We found that enrichment factors (EF) reflected a moderate contamination for 71% of the samples (EF > 10). The (206)Pb/(207)Pb ratio values for lichens ranged from 1.17 to 1.20 and were a mixture of natural radiogenic and industrial activities (e.g., crude oils and fire plants). The low concentration of Pb found in gasoline (<7.0 μg L(-1)) confirms the official statement that leaded gasoline is no longer used in Cuba.

  10. Geochemistry of Garibaldi Lake andesites and dacites indicates crustal contamination involved in formation of Northern Cascade arc lavas

    NASA Astrophysics Data System (ADS)

    Martindale, M.; Mullen, E.; Weis, D.

    2013-12-01

    The Cascade Arc presents a unique setting for studying the controls on andesite genesis and the implications for growth and evolution of the continental crust. It is the type-locality for a ';hot' subduction zone, where the downgoing slab is young and subduction is relatively slow. The northern segment of the Cascade arc, the Garibaldi Volcanic Belt (GVB), hosts the youngest subducting crust in Cascadia and the termination of the subducting slab. These conditions may affect magma generation processes by reducing the amount of water reaching the area of melt generation [1,2] and imparting an adakitic signature to magmas generated there if the slab edge melts [3]. We provide insights on the origin of andesites and dacites from the Garibaldi Lake area using new high-precision Pb, Sr, Nd, Hf isotope ratios and trace element data. Andesites and dacites from the Garibaldi Lake area (The Black Tusk, Mt. Price, and The Table) are calc-alkaline and show evidence for crustal contamination such as positive correlations between Ba/Nb and SiO2. Silica variation diagrams show no systematic trend for any of the volcanic centres, suggesting the presence of distinct magma batches. Garibaldi Lake andesites and dacites have among the least radiogenic Pb isotope ratios of all Cascade arc lavas, and define a linear array in Pb-isotope space. This most likely reflects mixing between MORB-source mantle (similar to Gorda and Explorer plate sources) and locally subducting sediments [4]. However, relative to GVB basalts and lavas from the rest of the Cascades (High Cascades), the andesites and dacites have higher 207Pb/204Pb (15.55-15.56) for a given 206Pb/204Pb (18.66-18.74). The Garibaldi Lake lavas also have higher 87Sr/86Sr (0.7033-0.7036) and lower ɛNd (5.8-7.9) at a given 206Pb/204Pb than GVB basalts and High Cascades lavas but among the highest ɛNd for a given SiO2 for the whole of the Cascades. ɛHf values (10.5-13.5) are higher at a given SiO2 value for Garibaldi Lake evolved

  11. Using S and Pb isotope ratios to trace leaching of toxic substances from an acid-impacted industrial-waste landfill (Pozdatky, Czech Republic).

    PubMed

    Novak, Martin; Pacherova, Petra; Erbanova, Lucie; Veron, Alain J; Buzek, Frantisek; Jackova, Ivana; Paces, Tomas; Rukavickova, Lenka; Blaha, Vladimir; Holecek, Jan

    2012-10-15

    Slightly elevated concentrations of toxic species in waters sampled in the surroundings of a leaky landfill may be both a sign of an approaching contaminant plume, or a result of water-rock interaction. Isotopes can be instrumental in distinguishing between anthropogenic and geogenic species in groundwater. We studied sulfur and lead isotope ratios at an abandoned industrial-waste landfill, located in a densely populated part of Central Europe. Stable isotope variability in space and time was used to follow the movement of a groundwater plume, contaminated with toxic metals (Cd, Cr, Be), in fractured granitoids. Toxic metals had been mobilized from industrial waste by a strong pulse of sulfuric acid, also deposited in the landfill. Both tracers exhibited a wide range of values (δ(34)S between +2.6 and +18.9‰; (206)Pb/(207)Pb between 1.16 and 1.39), which facilitated identification of mixing end-members, and made it possible to assess the sources of the studied species. In situ fractionations did not hinder source apportionment. Influx of contaminated groundwater was observed neither in irrigation wells in a nearby village, nor at distances greater than 300 m from the landfill. Combination of stable isotope tracers can be used as part of an early-warning system in landscapes affected by landfills.

  12. Early Cretaceous continental delamination in the Yangtze Block: Evidence from high-Mg adakitic intrusions along the Tanlu fault, central Eastern China

    NASA Astrophysics Data System (ADS)

    Jia, Liqiong; Mo, Xuanxue; Santosh, M.; Yang, Zhusen; Yang, Dan; Dong, Guochen; Wang, Liang; Wang, Xinchun; Wu, Xuan

    2016-09-01

    Early Cretaceous high-Mg adakitic rocks from central Eastern China provide important insights into the thinning mechanism of the over-thickened lithosphere in the Yangtze Block (YB) as well as the North China Block (NCB). The Tanlu fault (TLF), located between the North China and Yangtze Blocks, and has been considered as a prominent pathway of magmas and fluids that resulted in lithosphere thinning of the YB during the Mesozoic-Cenozoic. Here we report the petrology, whole-rock geochemistry, zircon U-Pb geochronology, in situ Hf isotopes, and whole-rock Sr-Nd-Pb isotopes of four high-Mg adakitic intrusions along the TLF in northeastern Langdai. These adakitic intrusions consist of monzodiorite, quartz monzonite porphyry, and quartz monzodiorite. Zircon LA-MC-ICPMS analyses of five samples yield weighted mean 206Pb/238U ages of 127.58 ± 0.80, 126.90 ± 0.81, 120.71 ± 0.64, 122.75 ± 0.57, and 129.2 ± 1.1 Ma, indicating their emplacement during the Early Cretaceous. The intrusions have intermediate SiO2 (53.18-65.48 wt%) and high potassium (K2O = 3.07-3.95 wt%; Na2O/K2O = 1.02-1.26) and are classified as shoshonitic to high-K calc-alkaline series. They are characterized by high MgO (1.80-7.35 wt%), Mg# (50-65), Sr (591-1183 ppm), Ni (20.3-143.0 ppm), and Cr (51.40-390.0 ppm) contents, high (La/Yb)N (11.60-28.33) and Sr/Y (27.9-113.5) ratios, and low Y (7.79-22.4 ppm) and Yb (0.60-2.01 ppm) contents, comparable with high-Mg adakites. The samples are enriched in light rare earth elements but depleted in heavy rare earth elements and high field strength elements with slightly negative to positive Eu anomalies (δEu = 0.81-1.30), resembling the features of high-Mg adakitic rocks. Their whole-rock εNd(t) = -16.2 to -15.0, initial (87Sr/86Sr)i = 0.7060-0.7074, low radiogenic Pb (206Pb/204Pb(t) = 16.208-16.509, 207Pb/204Pb(t) = 15.331-15.410, and 208Pb/204Pb(t) = 36.551-36.992), and zircon εHf(t) = -36.6 to -16.6 suggest magma derivation from a continental crustal

  13. The isotopic and chemical evolution of Mount St. Helens

    USGS Publications Warehouse

    Halliday, A.N.; Fallick, A.E.; Dickin, A.P.; Mackenzie, A.B.; Stephens, W.E.; Hildreth, W.

    1983-01-01

    Isotopic and major and trace element analysis of nine samples of eruptive products spanning the history of the Mt. St. Helens volcano suggest three different episodes; (1) 40,000-2500 years ago: eruptions of dacite with ??{lunate}Nd = +5, ??{lunate}Sr = -10, variable ??18O, 206Pb/204Pb ??? 18.76, Ca/Sr ??? 60, Rb/Ba ??? 0.1, La/Yb ??? 18, (2) 2500-1000 years ago: eruptions of basalt, andesite and dacite with ??{lunate}Nd = +4 to +8, ??{lunate}Sr = -7 to -22, variable ??18O (thought to represent melting of differing mantle-crust reservoirs), 206Pb/204Pb = 18.81-18.87, variable Ca/Sr, Rb/Ba, La/Yb and high Zr, (3) 1000 years ago to present day: eruptions of andesite and dacite with ??{lunate}Nd = +6, ??{lunate}Sr = -13, ??18O ???6???, variable 206Pb/204Pb, Ca/Sr ??? 77, Rb/Ba = 0.1, La/Yb ??? 11. None of the products exhibit Eu anomalies and all are LREE enriched. There is a strong correlation between 87Sr/86Sr and differentiation indices. These data are interpreted in terms of a mantle heat source melting young crust bearing zircon and garnet, but not feldspar, followed by intrusion of this crustal reservoir by mantle-derived magma which caused further crustal melting and contaminated the crustal magma system with mafic components. Since 1000 years ago all the eruptions have been from the same reservoir which has displayed a much more gradual re-equilibration of Pb isotopic compositions than other components suggesting that Pb is being transported via a fluid phase. The Nd and Sr isotopic compositions lie along the mantle array and suggest that the mantle underneath Mt. St. Helens is not as depleted as MORB sources. There is no indication of seawater involvement in the source region. ?? 1983.

  14. Louisville seamount subduction and its implication on mantle flow beneath the central Tonga-Kermadec arc

    NASA Astrophysics Data System (ADS)

    Timm, Christian; Bassett, Daniel; Graham, Ian J.; Leybourne, Matthew I.; de Ronde, Cornel E. J.; Woodhead, Jon; Layton-Matthews, Daniel; Watts, Anthony B.

    2013-04-01

    Subduction of intraplate seamounts beneath a geochemically depleted mantle wedge provides a seldom opportunity to trace element recycling and mantle flow in subduction zones. Here we present trace element and Sr, Nd and Pb isotopic compositions of lavas from the central Tonga-Kermadec arc, west of the contemporary Louisville-Tonga trench intersection, to provide new insights into the effects of Louisville seamount subduction. Elevated 206Pb/204Pb, 208Pb/204Pb, 86Sr/87Sr in lavas from the central Tonga-Kermadec arc front are consistent with localized input of subducted alkaline Louisville material (lavas and volcaniclastics) into sub-arc partial melts. Furthermore, absolute Pacific Plate motion models indicate an anticlockwise rotation in the subducted Louisville seamount chain that, combined with estimates of the timing of fluid release from the subducting slab, suggests primarily trench-normal mantle flow beneath the central Tonga-Kermadec arc system.

  15. Sulfate-water isotope geothermometry and lead isotope data for the regional geothermal system in the Twin Falls Area, South-Central Idaho

    SciTech Connect

    Mariner, R.H.; Bullen, T.D.; Janik, C.J.; Young, H.W.

    1997-12-31

    Sulfate-water isotope geothermometry for the geothermal system at Twin Falls, Idaho indicates aquifer-temperatures of 90{degrees} to 106{degrees}C; most sites are between 90{degrees} and 93{degrees}C. {sup 206}Pb/{sup 204}Pb and {sup 208}Pb/{sup 204}Pb of individual thermal waters are principally a function of how much lead has been dissolved from the carbonate and silicate fractions of the Paleozoic limestone collected west of Grand View Peak. Although most thermal waters are recovered from Tertiary rhyolite, very little of the dissolved lead is from the rhyolite. Recharge to this system occurs in northern Nevada and the fluid moves northward in the Paleozoic limestones. The occurrence of thermal fluid in the Idavada Volcanics near and south of Twin Falls, Idaho is the result of upward movement of this fluid from the Paleozoic limestone.

  16. Louisville seamount subduction and its implication on mantle flow beneath the central Tonga-Kermadec arc.

    PubMed

    Timm, Christian; Bassett, Daniel; Graham, Ian J; Leybourne, Matthew I; de Ronde, Cornel E J; Woodhead, Jon; Layton-Matthews, Daniel; Watts, Anthony B

    2013-01-01

    Subduction of intraplate seamounts beneath a geochemically depleted mantle wedge provides a seldom opportunity to trace element recycling and mantle flow in subduction zones. Here we present trace element and Sr, Nd and Pb isotopic compositions of lavas from the central Tonga-Kermadec arc, west of the contemporary Louisville-Tonga trench intersection, to provide new insights into the effects of Louisville seamount subduction. Elevated (206)Pb/(204)Pb, (208)Pb/(204)Pb, (86)Sr/(87)Sr in lavas from the central Tonga-Kermadec arc front are consistent with localized input of subducted alkaline Louisville material (lavas and volcaniclastics) into sub-arc partial melts. Furthermore, absolute Pacific Plate motion models indicate an anticlockwise rotation in the subducted Louisville seamount chain that, combined with estimates of the timing of fluid release from the subducting slab, suggests primarily trench-normal mantle flow beneath the central Tonga-Kermadec arc system.

  17. Direct ion microprobe U-Pb dating of fossil tooth of a Permian shark

    NASA Astrophysics Data System (ADS)

    Sano, Yuji; Terada, Kentaro

    1999-12-01

    We report here direct ion microprobe dating of fossil tooth (dentine) of a Permian fresh-water shark, Orthacanthus senckenbergianus using the SHRIMP instrument recently installed at Hiroshima University. Fifteen spots on the small sample (approximately 2 mm×1 mm) indicate a 238U/ 206Pb isochron age of 266±18 Ma and a Tera-Wasserburg concordia intercept age of 266±24 Ma in a three-dimensional 238U/ 206Pb- 207Pb/ 206Pb- 204Pb/ 206Pb diagram. These Permian ages are consistent with a 235U/ 207Pb age of 453±170 Ma and a 232Th- 208Pb age of 235±310 Ma, suggesting indistinguishable depositional and early diagenetic ages of the fossil in its sedimentary sequences. The success of the method depends on the chemical fractionation of uranium from lead in a specimen a few hundred microns in size and the consequent variations in lead isotopic compositions due to radioactive decay.

  18. In situ ion microprobe U-Pb dating and REE abundances of a carboniferous conodont

    NASA Astrophysics Data System (ADS)

    Sano, Yuji; Terada, Kentaro

    We report here in situ ion microprobe U-Pb dating of a conodont micro-fossil using an ion microprobe method. Thirteen spots on the single fragment of the Carboniferous conodont (size: approximately 800 µm × 100 µm) yield a 238U/206Pb isochron age of 323±36 Ma and a Tera-Wasserburg concordia intercept age of 332±44 Ma in a three-dimensional 238U/206Pb-207Pb/206 Pb-204Pb/206Pb diagram. These ages are consistent with the depositional and early diagenetic ages of the fossil in its host Mississippian sedimentary sequence within experimental error. The success of the method depends on the chemical fractionation of U from Pb within a hundred-µm length scale and the consequent variations in Pb isotopic compositions due to radioactive decay. Shale-normalized rare earth element (REE) abundances of two spots on the same sample show flat patterns from light REE to middle REE and decreases from middle REE to heavy REE with negative anomalies of both Ce and Eu. The REE characteristics are significantly different from those of Devonian conodonts reported by other workers, suggesting discrepant redox states and/or formation environments.

  19. The Quaternary adakite distribution of Kyushu Island, Ryukyu Arc, Japan

    NASA Astrophysics Data System (ADS)

    Shibata, T.; Yoshikawa, M.; Takemura, K.

    2011-12-01

    The Quaternary volcanoes are widely distributed in Kyusu Island, Japan. Philippine Sea plate is subducting beneath Kyushu. Clear distribution of deep seismic foci is observed below the Quaternary volcanoes in southern area, but not in northern area. Notsu et al. (1990, JVGR) examined the contribution of subduction to the magma source, and emphasized that no slab derived material is observed in northern area from Sr isotopic compositions. Volcanic activity similar to the within-plate type volcanism has been also emphasized for the magma genesis of this area (e.g. Kita et al, 2001, JVGR). However, we found adakitic rocks, which show high Sr/Y ratios and low Y concentrations (e.g. Defant and Drummond, 1990, Nature) from some Quaternary volcanoes in north Kyushu on the basis of published data (Otha et al, 1990, GANKO; Itoh, 1990, GANKO). Therefore, the magma genesis is still controversial. We studied lateral variations of Sr, Nd and Pb isotopic and trace element compositions for Quaternary volcanics from Kyushu to investigate the magma genesis. From the results, a clear variation of Sr/Y ratio, decreasing from north to south, is observed along the volcanic front. Some of the Sr/Y ratio of the most northern part of Kyusu shows the value >100. The all analyzed Pb isotope compositions show a single liner trend in 208Pb/204Pb v.s. 206Pb/204Pb diagram. The liner trend of Pb isotope ratios can be explained by the binary mixing of the Shikoku Basin basalt and tereginious sediment which might be a constituent of the subducting slab. The similar binary mixing relationships are found in Sr and Nd isotopic systematics. The isotopic characteristics of the Quaternary magma in Kyushu can be explained by the magma generation process of island arc, in spite of the lack of deep seismic foci in northern area. It is considered that high and low Sr/Y ratios suggest the contributions of partial melt in the north and aqueous fluid derived from subducting slab in the south, respectively. If

  20. Geochemical and isotopic composition of Pan-African metabasalts from southwestern Gondwana: Evidence of Cretaceous South Atlantic opening along a Neoproterozoic back-arc

    NASA Astrophysics Data System (ADS)

    Will, Thomas M.; Frimmel, Hartwig E.; Gaucher, Claudio; Bossi, Jorge

    2014-08-01

    A lithogeochemical and Sr-Nd-Pb isotope study of former oceanic crustal rocks from the Cuchilla Dionisio Terrane in the southern Dom Feliciano Belt, Uruguay (La Tuna amphibolites) and metabasites in the Chameis Subterrane of the Marmora Terrane in the Gariep Belt, Namibia/South Africa shows that these rocks are compositionally very similar and probably represent the same unit on opposite sides of the modern South Atlantic. The mafic rocks from both terranes are tholeiitic metabasalts and -andesites and have depleted rare earth element patterns, generally low TiO2 (< 1.5 wt.%), very low Th/Nb ratios and lack negative Nb-Ta anomalies, all features that are typical of ‘normal' mid-ocean ridge basalts (N-MORB) and/or back-arc basin basalts (BABB). In addition, both rock suites have extremely depleted Nd isotope compositions (εNd630 Ma = 6.7-9.4), superchondritic 147Sm/144Nd ratios, and low 206Pb/204Pb and 207Pb/204Pb initial ratios. The 87Sr/86Sr initial ratios of the La Tuna mafic rocks are low, whereas the Chameis metagabbro samples have higher, possibly alteration-related ratios. The geochemical and isotopic signatures are consistent with the formation of both rock suites in the same mature Neoproterozoic back-arc basin (Marmora Basin), supporting conclusions drawn from earlier provenance studies of metasedimentary units from these terranes. Other mafic rocks from the Marmora Terrane are interpreted as ocean island basalts that formed in a within-plate setting. A corollary of the conclusion that the mafic rocks in the Cuchilla Dionisio and Marmora Terranes formed in the same back-arc basin is (1) that the main Pan-African suture between the Río de la Plata Craton and the Kalahari Craton lies to the west of the Dom Feliciano Belt in South America, and (2) that the opening of the modern South Atlantic did not occur along that suture but along the axis of the Neoproterozoic Marmora back-arc basin.

  1. Multispectroscopic and Isotopic Ratio Analysis To Characterize the Inorganic Binder Used on Pompeian Pink and Purple Lake Pigments.

    PubMed

    Marcaida, Iker; Maguregui, Maite; Morillas, Héctor; García-Florentino, Cristina; Knuutinen, Ulla; Carrero, Jose Antonio; Fdez-Ortiz de Vallejuelo, Silvia; Pitarch Martı́, Africa; Castro, Kepa; Madariaga, Juan Manuel

    2016-06-21

    Because of the fact that pigments are not ubiquitous in the archeological record, the application of noninvasive analytical methods is a necessity. In this work, pink and purple lake pigments recovered from the excavations of the ancient city of Pompeii (Campania, Italy) and preserved in their original bowls at the Naples National Archaeological Museum (Italy) were analyzed to characterize the composition of their inorganic binders (mordants). In situ preliminary analyses using a hand-held energy dispersive X-ray fluorescence spectrometer (HH-ED-XRF) allowed us to determine the use of an aluminosilicate enriched in Cu and Pb. Scanning electron microscopy coupled to energy dispersive X-ray spectrometry (SEM-EDS) and benchtop ED-XRF analyses confirmed these results, while inductively coupled plasma mass spectrometry (ICPMS) allowed one to determine the concentration of major, minor, and trace elements. The use of other techniques such as X-ray diffraction (XRD), and micro-Raman and infrared spectroscopies allowed one to characterize the pigments at the molecular level. The high concentration of Cu detected in the pigments (1228-12937 μg g(-1)) could be related to the addition of Cu salts to obtain the desired final hue. The concentrations of Pb (987-2083 μg g(-1)) was also remarkable. Lead isotopic ratio analysis ((206)Pb/(207)Pb) suggested a possible origin related to the leaching of the ancient lead pipes from Pompeii and the subsequent transfer to the buried pigments or to the inorganic binder. Molecular analysis also showed that the binder is composed of an allophane-like clay. Moreover, it was possible to determine that to obtain the final purple hue of a specific pigment, Pompeian blue pigment was also mixed into the dyed clay.

  2. Lead in the Getchell-Turquoise ridge Carlin-type gold deposits from the perspective of potential igneous and sedimentary rock sources in Northern Nevada: Implications for fluid and metal sources

    USGS Publications Warehouse

    Tosdal, R.M.; Cline, J.S.; Fanning, C.M.; Wooden, J.L.

    2003-01-01

    Lead isotope compositions of bulk mineral samples (fluorite, orpiment, and realgar) determined using conventional techniques and of ore-stage arsenian pyrite using the Sensitive High Resolution Ion-Microprobe (SHRIMP) in the Getchell and Turquoise Ridge Carlin-type gold deposits (Osgood Mountains) require contribution from two different Pb sources. One Pb source dominates the ore stage. It has a limited Pb isotope range characterized by 208Pb/206Pb values of 2.000 to 2.005 and 207Pb/206Pb values of 0.8031 to 0.8075, as recorded by 10-??m-diameter spot SHRIMP analyses of ore-stage arsenian pyrite. These values approximately correspond to 206Pb/204Pb of 19.3 to 19.6, 207Pb/204Pb of 15.65 to 15.75, and 208Pb/204Pb of 39.2 to 39.5. This Pb source is isotopically similar to that in average Neoproterozoic and Cambrian elastic rocks but not to any potential magmatic sources. Whether those clastic rocks provided Pb to the ore fluid cannot be unequivocally proven because their Pb isotope compositions over the same range as in ore-stage arsenian pyrite are similar to those of Ordovician to Devonian siliciclastic and calcareous rocks. The Pb source in the calcareous rocks most likely is largely detrital minerals, since that detritus was derived from the same sources as the detritus in the Neoproterozoic and Cambrian clastic rocks. The second Pb source is characterized by a large range of 206Pb/204Pb values (18-34) with a limited range of 208Pb/204Pb values (38.1-39.5), indicating low but variable Th/U and high and variable U/Pb values. The second Pb source dominates late and postore-stage minerals but is also found in preore sulfide minerals. These Pb isotope characteristics typify Ordovician to Devonian siliciclastic and calcareous rocks around the Carlin trend in northeast Nevada. Petrologically similar rocks host the Getchell and Turquoise Ridge deposits. Lead from the second source was either contributed from the host sedimentary rock sequences or brought into the

  3. Eolian inputs of lead to the North Pacific

    SciTech Connect

    Jones, C.E.; Halliday, A.N.; Rea, D.K.; Owen, R.M.

    2000-04-01

    The authors evaluate the importance of natural eolian Pb to the dissolved oceanic Pb budget by measuring the isotopic composition of Pb in 35 Holocene and late Quaternary sediment samples from the North Pacific and in 10 samples of Chinese loess. When the Pacific is divided into sediments provinces based on published {var_epsilon}{sub Nd} and sedimentological data, Pb from the central North Pacific tends to be the most radiogenic and homogeneous due to the dominance of eolian Chinese loess. Lead from the marginal North Pacific and the sparsely sampled regions south of 5{degree}N are less radiogenic and more variable owing to hemipelagic inputs from various volcanic arcs and older continental crust located around the Pacific Rim. {sup 208}Pb/{sup 204}Pb ratios provide the most distinctive provenance information due to the relatively high ratios in Chinese loess. The Chinese loess samples come from 3 localities and span up to 2 Myr of time. Acetic-acid leachate, bulk loess, and loess silicate fractions were analyzed separately. Leachate Pb is considerably less radiogenic than silicate Pb. The isotopic composition of the silicate component closely matches the sediment data from the central North Pacific, confirming the dominance of eolian loess in this region. The authors divided up a suite of published hydrogenous Pb-isotope data from the Pacific Ocean according to their locations within the three independently defined sediment provinces. These data define three distinct fields differentiated primarily by their {sup 206}Pb/{sup 204}Pb ratios, which increase going form the Central to Southern to Marginal provinces. This relationship with sediment province strongly suggests that natural eolian and probably hemipelagic inputs significantly impact the seawater Pb budget. Direct support for the dominance of eolian Chinese loess in the central North Pacific dissolved Pb budget comes from the close match between loess leachate Pb and the Central Province hydrogenous Pb data

  4. Petrogenesis of the post-collisional Oligo-Miocene Volcanism in NW Anatolia (Turkey): Balıkesir Volcanites

    NASA Astrophysics Data System (ADS)

    Ünal, Alp; Altunkaynak, Şafak; Benowitz, Jeff A.

    2016-04-01

    In this study, we present whole-rock chemical and Sr-Nd-Pb-O isotopic compositions as well as 40Ar/39Ar ages of Balıkesir volcanites to evaluate the nature, genesis and timing of the post-collisional Oligo-Miocene magmatism in NW Anatolia. Three main volcano-stratigraphic groups distinguished in the Balıkesir volcanites on the basis of field observations and petrographical investigations; 1) andesitic lavas and related pyroclastic units representing the lower part of the volcanic sequence; 2) Trachyandesite- basaltic trachyandesite lavas and 3) dacitic lavas and associated pyroclastic units corresponding to the upper part of the volcanic sequence. Both andesitic and dacitic pyroclastic units are represented with ash fall, ash block flow and flow breccia units. Geochemically, Balıkesir volcanites are ranging in composition from basaltic trachy-andesite to dacite. They are sub-alkaline in character and show enrichment in large ion lithophile elements (LILE) and light rare earth elements (LREE) relative to the high field strength elements (HFSE). Balıkesir volcanites display depletion in P, Ta, Nb and Ti. All these trace element characteristics and inter-element ratios suggest that magma forming the Balıkesir volcanites show similar patterns to those of subduction-related arc magmas and/or post collisional lavas. They have high initial 87Sr/86Sr ratios (0.707109-0.708620), low 143Nd/144Nd (0.512322- 0.512493). 206Pb/204Pb and 207Pb/204Pb values vary from 18.703 to 18.867 and 15.681 to 15.714, respectively and ɛNd values range between -5.61 and -2.27. 18O isotopic ratios range between 8.3 and 11.8. All these isotopic characteristics and major-trace element compositions of Balıkesir volcanites suggest that the lavas are co-genetic and originated from a hybrid magma derived from enriched mantle (EM II) source. 40Ar/39Ar dating yielded isochron ages of 22.9±0.2 - 21.0±0.2 which is consistent with other volcanic and plutonic associations of western Anatolia (eg

  5. Rapid Cenozoic ingrowth of isotopic signatures simulating "HIMU" in ancient lithospheric mantle: Distinguishing source from process

    NASA Astrophysics Data System (ADS)

    McCoy-West, Alex J.; Bennett, Vickie C.; Amelin, Yuri

    2016-08-01

    Chemical and isotopic heterogeneities in the lithospheric mantle are increasingly being recognised on all scales of examination, although the mechanisms responsible for generating this variability are still poorly understood. To investigate the relative behaviour of different isotopic systems in off-cratonic mantle, and specifically the origin of the regional southwest Pacific "HIMU" (high time integrated 238U/204Pb) Pb isotopic signature, we present the first U-Th-Pb, Rb-Sr, Sm-Nd and Re-Os isotopic dataset for spinel peridotite xenoliths sampling the subcontinental lithospheric mantle (SCLM) beneath Zealandia. Strongly metasomatised xenoliths converge to a restricted range of Sr and Nd isotopic compositions (87Sr/86Sr = 0.7028-0.7033; εNd ≈ +3-+6) reflecting pervasive overprinting of their original melt depletion signatures by carbonatite-rich melts. In contrast, rare, weakly metasomatised samples possess radiogenic Nd isotopic compositions (εNd > +15) and unradiogenic Sr isotopic compositions (87Sr/86Sr < 0.7022). This is consistent with melt extraction at ca. 2.0 Ga and in accord with widespread Paleoproterozoic Re-Os model ages from both weakly metasomatised and the more numerous, strongly metasomatised xenoliths. The coupling of chalcophile (Os), and lithophile (Sr and Nd) melt depletion ages from peridotite xenoliths on a regional scale under Zealandia argues for preservation of a significant mantle keel (⩾2 million km3) associated with a large-scale Paleoproterozoic melting event. Lead isotopic compositions are highly variable with 206Pb/204Pb = 17.3-21.3 (n = 34) and two further samples with more extreme compositions of 22.4 and 25.4, but are not correlated with other isotopic data or U/Pb and Th/Pb ratios in either strongly or weakly metasomatised xenoliths; this signature is thus a recent addition to the lithospheric mantle. Lead model ages suggest that this metasomatism occurred in the last 200 m.y., with errorchrons from individual localities

  6. Origin of the Red Dog Zn-Pb-Ag deposits, Brooks Range, Alaska: Evidence from regional Pb and Sr isotope sources

    USGS Publications Warehouse

    Ayuso, R.A.; Kelley, K.D.; Leach, D.L.; Young, L.E.; Slack, J.F.; Wandless, G.; Lyon, A.M.; Dillingham, J.L.

    2004-01-01

    Pb and Sr isotope data were obtained on the shale-hosted Zn-Pb-Ag Red Dog deposits (Qanaiyaq, Main, Aqqaluk, and Paalaaq), other shale-hosted deposits near Red Dog, and Zn-Pb-Ag sulfide and barite deposits in the western and central Brooks Range. The Red Dog deposits and other shale-hosted Zn-Pb-Ag deposits near Red Dog are hosted in the Mississippian Kuna Formation, which is underlain by a sequence of marine-deltaic clastic rocks of the Upper Devonian to Lower Mississippian Endicott Group. Ag-Pb-Zn vein-breccias are found in the Endicott Group. Galena formed during the main mineralization stages in the Red Dog deposits and from the Anarraaq and Wulik deposits have overlapping Pb isotope compositions in the range 206Pb/204Pb = 18.364 to 18.428, 207Pb/204Pb = 15.553 to 15.621, and 208Pb/204Pb = 38.083 to 38.323. Galena and sphalerite formed during the main ore-forming stages in the Red Dog deposits define a narrow field on standard uranogenic and thorogenic Pb isotope diagrams. Lead in sulfides of the Red Dog district is less radiogenic (238U/204Pb: ?? = 9.51-9.77) than is indicated by the average crustal lead evolution model (?? = 9.74), a difference consistent with a long history of evolution at low ratios of ?? before the Carboniferous. The homogeneous regional isotopic reservoir of Pb may indicate large-scale transport and leaching of minerals with various ?? ratios and Th/Pb ratios. Younger and genetically unrelated fluids did not significantly disturb the isotopic compositions of galena and sphalerite after the main mineralization event in the Red Dog district. Some pyrite shows evidence of minor Pb remobilization. The overall lead isotope homogeneity in the shale-hosted massive sulfide deposits is consistent with three types of control: a homogeneous regional source, mixing of lead during leaching of a thick sedimentary section and fluid transport, or mixing at the site of deposition. Isotopic variability of the hydrothermal fluids, as represented by galena

  7. Pb and O isotopic constraints on the source of granitic rocks from Cape Breton Island, Nova Scotia, Canada

    USGS Publications Warehouse

    Ayuso, R.A.; Barr, S.M.; Longstaffe, F.J.

    1996-01-01

    Pb isotopic compositions of leached feldspars from twenty-three plutons in Cape Breton Island can be divided into two groups: anorthosite, syenite, and granite in the Blair River Complex, which have the least radiogenic compositions on the Island, and granitic rocks from terranes (Aspy, Bras d'Or, and Mira) to the south. Pb isotopic data for the Blair River Complex (206Pb/204Pb = 17.399-18.107; 207Pb/204Pb = 15.505-15.560; 208Pb/204Pb = 36.689-37.733) are consistent with an old source region ultimately derived from the mantle and contaminated by sialic crust. Oxygen isotopic compositions of syenite in the Blair River Complex (??18O = +8.0 to +8.5 permil) are slightly higher than anorthosite (+7.0 to +8.3 permil); a Silurian granite in the Blair River Complex has ??18O = +7.5 permil. Cambrian to Devonian plutons in the Aspy, Bras d'Or, and Mira terranes are more radiogenic (206Pb/204Pb = 18.192-18.981; 207Pb/204Pb = 15.574-15.712; 208Pb/ 204Pb =37.815-38.936) than the Blair River Complex and were generated from source regions having a predominant crustal Pb signature (high ??). The ??18O values of granites and granodiorites in the Aspy terrane (+7.5 to +9.2 permil; avg = +8.6 permil) and Bras d'Or (+3.7 to +11.3 permil; avg = +9.4 permil) are also consistent with involvement of sialic crust. Many Late Proterozoic granites from the Mira terrane have anomalously low ??18O values (+0.2 to +5.9 permil), perhaps produced from protoliths that had undergone hydrothermal alteration prior to melting. Paleozoic granitic rocks from the Aspy, Bras d'Or, and Mira terranes cannot be uniquely distinguished on the basis of their Pb and O isotopic compositions. The granitic rocks could have been generated during terrane amalgamation from combinations of unradiogenic (Grenville-like) and more radiogenic (Avalon-like) sources.

  8. Modification of an oceanic plateau, Aruba, Dutch Caribbean: Implications for the generation of continental crust

    NASA Astrophysics Data System (ADS)

    White, R. V.; Tarney, J.; Kerr, A. C.; Saunders, A. D.; Kempton, P. D.; Pringle, M. S.; Klaver, G. T.

    1999-01-01

    The generation of the continental crust may be connected to mantle plume activity. However, the nature of this link, and the processes involved, are not well constrained. An obstacle to understanding relationships between plume-related mafic material and associated silicic rocks is that later tectonic movements are liable to obscure the original relationships, particularly in ancient greenstone belts. Studies of younger analogous regions may help to clarify these relationships. On the island of Aruba in the southern Caribbean, a sequence of partly deformed mafic volcanic rocks intruded by a predominantly tonalitic batholith is exposed. The mafic lavas show geochemical and isotopic affinities with other basaltic, picritic and komatiitic rocks that crop out elsewhere in the Caribbean—these are well documented as belonging to an 88-91 Ma plume-related oceanic plateau, which is allochthonous with respect to the Americas, and is thought to have been formed in the Pacific region. The ˜85 to ˜82 Ma tonalitic rocks share some geochemical characteristics (high Sr and Ba, low Nb and Y) with Archaean tonalite-trondhjemite-granodiorite (TTG) suites. Field relationships suggest that deformation of the plateau sequence, possibly related to collision with a subduction zone, was synchronous with intrusion of the Aruba batholith. New incremental heating 40Ar/ 39Ar dates, combined with existing palaeontological evidence, show that cooling of the batholith occurred shortly after eruption of the plateau basalt sequence. Sr-Nd isotopic data for both rock suites are uniform ( 87Sr/ 86Sr i≈0.7035 , ɛNd i≈+7), whereas Pb isotopes are more variable (Plateau sequence: 206Pb/ 204Pb =18.6-19.1 , 207Pb/ 204Pb =15.54-15.60 , 208Pb/ 204Pb =38.3-38.75 ; Aruba batholith: 206Pb/ 204Pb =18.4-18.9 , 207Pb/ 204Pb =15.51-15.56 , 208Pb/ 204Pb =38.0-38.5 ). This suggests that there has been a minor sedimentary input into the source region of the batholith. However, the limited time interval

  9. Galapagos-OIB signature in southern Central America: Mantle refertilization by arc-hot spot interaction

    NASA Astrophysics Data System (ADS)

    Gazel, Esteban; Carr, Michael J.; Hoernle, Kaj; Feigenson, Mark D.; Szymanski, David; Hauff, Folkmar; van den Bogaard, Paul

    2009-02-01

    Although most Central American magmas have a typical arc geochemical signature, magmas in southern Central America (central Costa Rica and Panama) have isotopic and trace element compositions with an ocean island basalt (OIB) affinity, similar to the Galapagos-OIB lavas (e.g., Ba/La < 40, La/Yb > 10, 206Pb/204Pb > 18.8). Our new data for Costa Rica suggest that this signature, unusual for a convergent margin, has a relatively recent origin (Late Miocene ˜6 Ma). We also show that there was a transition from typical arc magmas (analogous to the modern Nicaraguan volcanic front) to OIB-like magmas similar to the Galapagos hot spot. The geographic distribution of the Galapagos signature in recent lavas from southern Central America is present landward from the subduction of the Galapagos hot spot tracks (the Seamount Province and the Cocos/Coiba Ridge) at the Middle American Trench. The higher Pb isotopic ratios, relatively lower Sr and Nd isotopic ratios, and enriched incompatible-element signature of central Costa Rican magmas can be explained by arc-hot spot interaction. The isotopic ratios of central Costa Rican lavas require the subducting Seamount Province (Northern Galapagos Domain) component, whereas the isotopic ratios of the adakites and alkaline basalts from southern Costa Rica and Panama are in the geochemical range of the subducting Cocos/Coiba Ridge (Central Galapagos Domain). Geological and geochemical evidence collectively indicate that the relatively recent Galapagos-OIB signature in southern Central America represents a geochemical signal from subducting Galapagos hot spot tracks, which started to collide with the margin ˜8 Ma ago. The Galapagos hot spot contribution decreases systematically along the volcanic front from central Costa Rica to NW Nicaragua.

  10. Sr, Nd, Pb and Os Isotopic Compositions of Lavas From the Mount Baker Volcanic Field, Cascade Arc

    NASA Astrophysics Data System (ADS)

    Mullen, E. K.; McCallum, I.; Brandon, A. D.

    2008-12-01

    We present the results of a trace element and Sr, Nd, Pb and Os isotopic study of the Mt. Baker volcanic field (MBVF), part of the northern segment of the Cascade magmatic arc known as the Garibaldi Belt. To date, only 4 Sr isotopic ratios (all from the Sulphur Creek flow) have been published. The Mount Baker volcanic field extends to 3.72 Ma and a case can be made for continuous magmatic activity in this region extending from 34 Ma to present. Our goal is to use isotope ratios to characterize the mantle source regions that underlie the Garibaldi Belt, to document the chemical inputs of slab fluid/melt, sediment, and lower crust, and to assess temporal and spatial variations in these factors. We measured 29 Sr and Nd isotopic ratios, 8 Pb isotopic ratios, and 9 Os isotopic ratios, representing the full age range and compositional diversity (calc- alkaline basalt through rhyolite) of the MBVF, including all known MBVF basalts. A 22.86-Ma gabbronorite from the adjacent Chilliwack batholith was analyzed as an analog for the modern mafic lower crust. All Mt. Baker lavas are calc-alkaline with the arc-characteristic signatures of HFSE depletion and LILE enrichment. MBVF 87Sr/86Sr values (0.703932 to 0.703057) and ɛNd (+4.71 to +7.79) are well correlated and lie within the mantle array. Mt. Baker Sr and Nd data are indistinguishable from other Garibaldi belt lavas (Green & Harry 1999, Green & Sinha 2005), and also overlap data from the neighboring Chilliwack batholith (Tepper 1996; Tepper et al. 1993). In contrast, central and southern Cascade arc lavas with similar Sr ratios have corresponding ɛNd values that are lower by ~2 epsilon units. The Garibaldi Belt and Chilliwack magmas are tapping a mantle source distinct from that of the rest of the Cascade arc. 206Pb/204Pb, 207Pb/204Pb and 208Pb/204Pb ratios of MBVF basalts plot close to the NHRL, in a linear trend between Juan de Fuca MORB and Pacific sediment, indicating a sediment contribution to the MBVF magmas. With

  11. Lead isotopic analyses of selected soil samples from the USEPA Vasquez Blvd.-I-70 study area, Denver, CO

    USGS Publications Warehouse

    Unruh, D.M.

    2002-01-01

    Large amounts of arsenic contamination, in excess of 2000 ppm, have been found in some residential surface soils in northern Denver, Colorado (USEPA, 1999). Associated with the arsenic are elevated levels of metals such as lead, cadmium and mercury. Potential sources of this contamination include waste from smelters in the area and commercial herbicide containing arsenic trioxide and lead arsenate (USEPA, 1999). As a part of the U.S. Environmental Protection Agency’s Vasquez Boulevard-I-70 Project (VBI70 project; USEPA, 1999), lead isotopic analyses of selected soil samples, smelter waste, and a commercial herbicide and a commercial lead arsenate pesticide have been performed in order to constrain the possible sources of elevated lead, and by proxy arsenic, found in these residential soils. The isotopes of lead can be used as a natural tracer in determining sources of contaminants in soils and stream sediments (e.g. Church and others, 1997; Fey and others, 1999; Unruh and others, 2000). The element lead (Pb) consists of four naturally occurring and stable isotopes, 204Pb, 206Pb, 207Pb, and 208Pb. Three of these, 206Pb, 207Pb, and 208Pb are radiogenic decay products of naturally occurring 238U, 235U, and 232Th, respectively. Owing to variations among the U/Pb and Th/Pb elemental abundance ratios among different types of geologic materials, variations in the relative abundances of the Pb isotopes are produced among different materials during geologic time. In order for the Pb isotope method to be useful for determining possible contaminant sources, two important criteria must be met (e.g. Church and others 1997): (1) It must be possible to obtain and measure the Pb isotopic compositions in all potential contaminant sources and in uncontaminated material and (2) the Pb isotopic compositions of the potential contaminant sources must be distinctly different from one another and from uncontaminated background. Variations among the Pb isotopic ratios in selected samples

  12. Preliminary Geochemical Results from the Mozambique Ridge, SW Indian Ocean

    NASA Astrophysics Data System (ADS)

    Jacques, G.; Werner, R.; Hauff, F.; Uenzelmann-Neben, G.; Hoernle, K.

    2015-12-01

    The Mozambique Ridge (120-140 Ma old) is a submarine plateau located in the southwest Indian Ocean. The relationship between plateau formation and the break-up of the Gondwana supercontinent is still unclear. Different models for the origin of this plateau include: 1) a continental fragment split off of Africa or Antarctica during Gondwana break-up and 2) an oceanic Large Igneous Province (LIP) formed by a mantle plume involved in Gondwana break-up. On the R/V SONNE (cruise SO232), we carried out bathymetric mapping, seismic reflection studies and rock sampling of the plateau basement, which confirmed the volcanic nature of at least the upper parts of the plateau. By reconstructing the spatial and temporal evolution in geochemistry of volcanic samples, we hope to gain new insights into the origin of the plateau. The recovered samples are mainly basaltic (SiO2 = 47-52 wt. %). On the Nb/Yb versus Th/Yb diagram, the samples overlap the field for enriched-mid-ocean-ridge basalts (EMORB) and extend towards the field for ocean island basalts (OIB). Most of the samples have relatively flat REE patterns, similar to EMORB or LIP type lavas. Initial Sr-Nd-Hf isotope ratios form tight correlations, excluding late alteration effects. The samples overlap and extend to slightly more radiogenic values than age-corrected SW Indian and South Atlantic MORB and OIB, indicating a two-component mixing between depleted (NMORB source) and enriched (OIB-type) mantle. Similar to some early Kerguelen plateau basalts, some of our samples have low Nd isotope and (Nb/La)n (< 1) ratios suggesting involvement of continental lithosphere and/or lower crust. On the 206Pb/204Pb versus 207Pb/204Pb isotope diagram, the samples extend to higher Δ7/4 than the South West Indian array, overlapping with Kerguelen lavas. Bathymetric data show numerous small cones scattered on the plateau, which are thought to represent a reactivation of volcanism after formation of the plateau basement. Moreover, seismic

  13. Investigation of the Influence of the Amlia Fracture Zone on the Islands of Four Mountains Region of the Aleutian Arc, AK

    NASA Astrophysics Data System (ADS)

    Nicolaysen, K. P.; Myers, J. D.; Weis, D.

    2013-12-01

    Regional isotopic and trace element investigations of the magmatic source characteristics of the Aleutian arc have attributed regional patterns to variations in the contribution of eclogite through slab melting, to increased proportions of sediment melts, and to variation in the amount of fluid derived by progressive metamorphism of the downgoing slab. Currently the Amlia Fracture Zone (AFZ) is located between the islands of Atka and Seguam and marks a prominent boundary between subduction of large quantities of trench sediments to the east versus sediment impoverished subduction to the west of the AFZ. This boundary is not stationary through time. Instead oblique subduction of the Pacific plate moves the AFZ westward along the arc front, causing sequential subduction beneath the islands of Chuginadak, Yunaska and Seguam circa 5, 2.5 and 1 million years ago, respectively. Lavas from Atka Island, which has not yet received the sediment and fluid spike from the AFZ, act as reference compositions. Comparison of bulk rock trace element ratios and Sr, Nd, Hf, and Pb isotopic compositions for lavas from these islands relative to Atka show that contributions from melted subducted sediment are important in the genesis of Holocene and Pleistocene lavas erupted in the Islands of Four Mountains region of the arc. Sr and Pb isotopic compositions for Yunaska and Chuginadak lavas are as high or higher than Seguam values and trend in the direction of sediment values. La/Nb ratios similarly indicate sediment melting is important for all these lavas. Comparison of values for Holocene relative to Pleistocene values indicate that once sediments are introduced to the magma source, they persist in affecting magma compositions. Comparison of higher Mg# lavas (molar Mg#>50) shows that a group of the oldest sampled lavas on Chuginadak have much lower 208Pb/204Pb, 206Pb/204Pb, and 87Sr/86Sr and higher 143Nd/144Nd, Zr/Y and Zn/Mn relative to all sampled Holocene and Pleistocene lavas from

  14. Anomalous intra-plate high-Mg andesites in the Choshi area (Chiba, Central Japan) produced during early stages of Japan Sea opening?

    NASA Astrophysics Data System (ADS)

    Hoang, Nguyen; Yamamoto, Takahiro; Itoh, Jun'ichi; Flower, Martin F. J.

    2009-10-01

    Geochemical and isotopic data are reported for 20 Ma high-magnesian andesite (HMA) lavas erupted on the forearc side of Central Japan in the Choshi coastal area (Chiba). Rarely olivine-phyric (< 3% vol), these rocks have ca. 56 wt.% SiO 2, Na 2O ranging between 3.9 and 4.2 wt.%, and relatively low K 2O/Na 2O ratios (ca. 0.44). Their Mg numbers are relatively high (ca. 0.64) and matched by high Cr (> 345 ppm), high Sr (> 520 ppm), high Sr/Y (ca. 30), and high [La/Yb] N (> 8), conforming to the definition of low-silica adakites, transitional in character to HMA. However, despite slight negative Nb and Ta 'troughs' in a few samples, their incompatible element distribution patterns appear closer to those of intra-plate basalts, apparently confirming previous suggestions that terms such as HMA and adakite cover a diverse range of compositions. Enriched in radiogenic Sr and Nd (ca. 0.7040 to 0.7043 and 0.5128 to 0.51275, respectively), the Choshi HMA shows relatively low 206Pb/ 204Pb (18.25 to 18.35) and 208Pb/ 204Pb (38.37 to 38.48) ratios, resembling those of late Miocene intra-plate basalts in the Japan Sea and SW Japan. In this regard the Choshi HMA differs from those of the 'classic' Middle Miocene (14 to 12 Ma) HMA described from the Setouchi volcanic belt (e.g. Tatsumi, 1981), a short distance to the west which also shows relative high K contents. Although HMAs have been generally attributed to subduction-related processes, the lack of high field strength element (HFSE) depletions cf. large ionic lithophile elements (LILE) in most Choshi HMA suggests an absence of so-called 'subduction signatures'. Accordingly, we suggest that the Choshi HMA probably tapped a fertile (asthenospheric) region of the convecting mantle wedge, primitive melt products having acquired HMA-like character as a result of shallow level modification by interaction with lithospheric components, aided by thermal input resulting from mantle extrusion, during the early stages of Japan Sea opening

  15. Geochemical variability of MORBs along slow to intermediate spreading Carlsberg-Central Indian Ridge, Indian Ocean

    NASA Astrophysics Data System (ADS)

    Ray, D.; Misra, S.; Banerjee, R.

    2013-07-01

    We present new major and ICP-MS trace element data from the Carlsberg Ridge MORBs from two different locations (i.e., 3°35'N/64°05'E and 3°41'N/64°09'E). Using this data we reassess the intra-ridge geochemical variations of the Carlsberg Ridge- Central Indian Ridge MORBs. Trace element contents of the Carlsberg Ridge MORBs are similar to the Rodriguez Triple Junction MORBs [e.g., LIL and REE spidergrams and (La/Sm)N ratio etc.]; both closely resemble the average N-MORB. However, the MORBs from the northern- and southern Central Indian Ridge, significantly vary in composition from the average N- and E-MORBs. Most Carlsberg Ridge- Central Indian Ridge MORBs show significantly less fractionation in FeOt, in the MgO-CaO-FeOt diagram, compared to those of the Mid Atlantic- and East Pacific Rise MORBs. Furthermore, the depleted LREE and nearly flat HREE patterns of the Carlsberg Ridge-Central Indian Ridge MORBs (along with their low compatible trace element (Ni, Cr, Sr) variability compared with the increasing incompatible trace element (Y, Zr) contents in the log-log plots, as well as their increasing incompatible trace element ratios) favor partial melting dominated processes for their petrogenetic evolution. Our (Sr, Nd, Pb) isotope data review shows that the Carlsberg Ridge-Central Indian Ridge MORBs are derived from a depleted mantle source that was variously contaminated by continental crust, perhaps during the third stage of Gondwana break up between 155 and 135 Ma. Such contamination could also have occurred later during the strike slip movement along a mega fracture (a member of the Davie Transform Faults in the Somali Basin that broke Gondwanaland into the East and West Gondwanas). The 208Pb/204Pb versus 206Pb/204Pb plot of above mentioned MORBs suggests that the depleted mantle source of the Rodriguez Triple Junction MORBs was contaminated by ˜21% lower continental crust, whereas the mantle source of the Central Indian Ridge MORBs was contaminated by

  16. Pb Isotopes as Tracers of Weathering in Glacial Systems

    NASA Astrophysics Data System (ADS)

    Martin, E. E.; Deuerling, K. M.; Scribner, C. A.; Martin, J. B.; Clements, K.

    2013-12-01

    Incongruent chemical weathering of freshly exposed continental material produces weathering solutions with Sr and Pb isotopic values that are distinctly more radiogenic than the parent material. As soils age, weathering becomes more congruent and the isotopic ratio in the solution approaches the composition of parent material. In light of this response, rapid increases in seawater Pb isotopes in the North Atlantic over the last deglacial have been attributed to incongruent weathering of fine grained glacial sediment exposed as the ice sheet retreated. This theory has not been tested using modern glacial river systems due to concerns about contamination by anthropogenic Pb. In this study we analyzed Pb isotopes from: 1) leachates of moraine material, 2) bedload and river water samples along a proglacial river, and 3) sediment and water samples from closed basin lakes in deglaciated terrains, from the Kangerlussuaq region of western Greenland. As expected, 0.1N HCl leachates of moraine soils exhibit 206,207,208Pb/204Pb ratios that are more radiogenic than the bulk soil. Samples from a Little Ice Age moraine close to the Russell Glacier exhibit greater offsets between the leachate and bulk soil Pb isotopes than samples from Orkendalen moraines (6.8 ka), which also record a slightly greater offset than Umivit-Keglen moraines (7.3 ka). Proglacial Watson (Akuliarusuarsuup Kuua) River water samples collected closest to the Russell Glacier also record the most radiogenic Pb isotopes and the largest increase relative to bedload values. Bedload 206Pb/204Pb ratios along the 40 km length of the proglacial river are 14.7+/0.6. Values for all water samples are distinctly more radiogenic than bedload, with the highest value (18.02) closest to the glacier and a general decreasing trend to ~15.82 farthest from the glacier. For comparison to anthropogenic Pb isotopes, 206Pb/207Pb ratios are 1.00+/-.03 for bedload, with water values ranging from 1.18 to 1.06 in a decreasing trend

  17. A Mantle Cross-Section Through Western And Central Nevada From Young Basaltic Magmas In The Sierra Nevada And Western Great Basin

    NASA Astrophysics Data System (ADS)

    Gupta, V.; Cousens, B. L.; Henry, C. D.

    2007-12-01

    The geochemistry of basaltic magmas erupted in the Basin and Range province of the western USA has demonstrated that at least two mantle sources exist, one with a subduction signature and another with an "ocean island basalt" (OIB) signature. Here we investigate the distribution of these two sources during the Pleistocene and Holocene in a 250 km-long transect from the eastern Sierra Nevada near Reno, NV, into central Nevada. Samples were collected from young, dated mafic lava flows from the Carson Range (2.5 to 1.4 Ma), Steamboat Hills (2.6 Ma), Virginia City and Chalk Hills (1.5 to 1.44 Ma), east of Carson City (1.36 Ma), Rattlesnake Hill (1.2 to 0.9 Ma), Buffalo Valley (1.1 to 0.95 Ma), Upsal Hogback (0.6 Ma), and Soda Lake (Holocene). With the exception of Carson Range andesites, all of the lavas are alkaline basalts and basaltic trachyandesites with K2O/Na2O > 0.4. Incompatible element abundances, incompatible element ratios, and radiogenic isotope ratios vary widely between locations. Many key incompatible element ratios, such as Ce/Pb, Sr/P, Ba/Nb, and Nb/La, and isotopic ratios vary as a function of age and longitude. Lavas less than 1 Ma in age have low Ba/Nb, Sr/P, 87Sr/86Sr, 206Pb/204Pb, and high Ce/Pb and Nd/La compared to lavas greater than 1Ma in age. These ratios vary more strongly as a function of longitude, from high Ba/Nb, Sr/P, 206Pb/204Pb, 87Sr/86Sr and low Ce/Pb and Nb/La (subduction signature mantle) lavas in the Sierra Nevada margin to lavas with the opposite characteristics (OIB signature mantle) in central Nevada. La/Sm does not vary with either age or longitude. The relationship with longitude indicates that two mantle sources currently exist beneath western Nevada, subduction-modified mantle to the west and OIB-type mantle to the east, and that these two mantle types probably taper in thickness towards one another. The termination of subduction beneath the Reno area at 5-3 Ma, in conjunction with 87Sr/86Sr greater than modern Cascade arc

  18. Geological, rare earth elemental and isotopic constraints on the origin of the Banbanqiao Zn-Pb deposit, southwest China

    NASA Astrophysics Data System (ADS)

    Li, Bo; Zhou, Jia-Xi; Huang, Zhi-Long; Yan, Zai-Fei; Bao, Guang-Ping; Sun, Hai-Rui

    2015-11-01

    The newly discovered Banbanqiao Zn-Pb deposit in the southeastern part of the Sichuan-Yunnan-Guizhou (SYG) Pb-Zn metallogenic province is located on the western Yangtze Block, southwest China. Ore bodies of the Banbanqiao deposit are stratiform type, host in dolomitic limestone and dolostone of the Lower Carboniferous Dapu Formation and occur within the NNE-trending Banbanqiao anticline. More than 1.5 million tones (Mt) Zn-Pb ores at grades of 0.26-10.32 wt.% Pb and 0.81-28.8 wt.% Zn have been controlled until now. δ13CPDB and δ18OSMOW values of calcite separates range from -2.8‰ to -0.7‰ (average -1.1‰) and +14.1‰ to +17.0‰ (average +15.5‰), respectively. The δ13CPDB values are similar to those of marine carbonate rocks, but higher than those of mantle and significantly different from those of sedimentary organic matter. However, the δ18OSMOW values are among those of mantle, marine carbonate rocks and sedimentary organic matter. δ34SCDT values of sulfide separates range from +3.2‰ to +9.9‰ (average +6.5‰), unlike mantle-derived sulfur (0 ± 3‰), whilst lower than evaporites (+22‰ to +28‰) within host strata. 206Pb/204Pb, 207Pb/204Pb and 208Pb/204Pb values of country shale and dolostone whole-rock samples are 18.47, 15.66 and 38.70, and 18.44-18.60, 15.66-15.85 and 38.70-39.14, respectively. Sulfide separates have 206Pb/204Pb, 207Pb/204Pb and 208Pb/204Pb values ranging from 18.03 to 18.73, 15.65 to 15.78 and 38.15 to 39.14, respectively. These Pb isotopic data indicate a clearly crustal source of Pb in the plot of 207Pb/204Pb vs. 206Pb/204Pb. Total REE (ΣREE) contents of country shale and dolostone whole-rock samples are 2.63 ppm and 0.72-86.2 ppm with δEu values are 2.79 and 0.34-0.70, respectively. Pyrite, sphalerite, galena and calcite samples have ΣREE contents of 5.3-36.4 ppm, 0.29-3.39 ppm, 0.52 ppm and 22.0-41.1 ppm, respectively, and δEu values of 0.64-0.86, 0.94-2.86, 0.32 and 0.21-0.45, respectively. These rare earth

  19. Petrogenesis of synorogenic diorite-granodiorite-granite complexes in the Damara Belt, Namibia: Constraints from U-Pb zircon ages and Sr-Nd-Pb isotopes

    NASA Astrophysics Data System (ADS)

    Jung, S.; Kröner, A.; Hauff, F.; Masberg, P.

    2015-01-01

    The synorogenic Palmental complex (central Damara Belt, Nambia) consists of ca. 545 Ma old quartz diorites and rare granodiorites and ca. 520 Ma-old leucogranites, representing one of the earliest and most primitive phase of crustal plutonism predating the main high-T regional metamorphism. Most quartz diorites and one granodiorite evolved through multistage, polybaric evolutionary processes involving fractionation from a lithospheric mantle-derived melt, followed by fractional crystallization of mainly hornblende, plagioclase and apatite which is shown by decreasing MgO, FeO, CaO, TiO2 and P2O5 with increasing SiO2. Assimilation of felsic basement gneisses was also important during formation of these granitoids. Although their chemical characteristics (high LILE, low HFSE) resemble those of quartz diorites and granodiorites with calc-alkaline affinity, they differ in their enriched Sr (initial 87Sr/86Sr: 0.7061-0.7098) and Nd (initial εNd: -2.7 to -9.9) isotopic composition. Neodymium depleted mantle mean crustal residence ages range from 1.3 to 1.9 Ga for the quartz diorites including the granodiorite. These model ages correlate with major and trace element abundances, further substantiating that AFC processes modified the initial isotopic systematics. Lead (206Pb/204Pb: 17.43-17.68, 207Pb/204Pb: 15.61-15.66, 208Pb/204Pb: 38.19-38.49) isotopic composition are unradiogenic relative to other Damaran intrusive rocks but plot above the Stacey and Kramers (1975) reference line, indicating that the source underwent an ancient (pre Pan-African) increase in U/Pb and Th/U, followed by more recent U-depletion. Some variation in 206Pb/204Pb at high 207Pb/204Pb further indicates involvement of ancient crustal material, most likely through AFC processes. A cross-cutting leucogranite dyke has also evolved isotopic compositions (initial 87Sr/86Sr: 0.7326; initial εNd: -15.6; 206Pb/204Pb: 17.42, 207Pb/204Pb: 15.62, 208Pb/204Pb: 38.16) but in view of the apparent younger age of

  20. Genesis and open-system evolution of Quaternary magmas beneath southeastern margin of Tibet: Constraints from Sr-Nd-Pb-Hf isotope systematics

    NASA Astrophysics Data System (ADS)

    Zou, Haibo; Ma, Mingjia; Fan, Qicheng; Xu, Bei; Li, Shuang-Qing; Zhao, Yongwei; King, David T.

    2017-02-01

    Post-collisional volcanic rocks on the Tibetan Plateau and its margins contain valuable information about the geodynamic processes associated with this Cenozoic continent-continent collision. The Quaternary Tengchong volcanic field at the southeastern margin of the Tibetan Plateau formed high-potassium calc-alkaline volcanic rocks. Herein, we present comprehensive Nd-Sr-Pb-Hf isotopic and elemental data for trachybasalts, basaltic trachyandesites, and trachyandesites from four Quaternary Tengchong volcanoes (Maanshan, Dayingshan, Heikongshan, and Laoguipo) in order to understand their magma genesis and evolution as well as tectonic significance. Good correlations between SiO2 content and the ratios 87Sr/86Sr, 143Nd/144Nd, 206Pb/204Pb, and 177Hf/176Hf for these Quaternary volcanics strongly suggest that the combined assimilation and fractional crystallization (AFC) was an important process in the origin of basaltic trachyandesites and trachyandesites. High Y and Yb contents and low Sr/Y ratios of these basaltic trachyandesites and trachyandesites are uncharacteristic of adakites that formed by partial melting of eclogitic lower crust or partial melting of basaltic oceanic crust with eclogite as a restite. A combined assimilation-fractional crystallization model is proposed for these basaltic trachyandesites and trachyandesites. Nd-Sr-Pb-Hf isotopes for the uncontaminated Tengchong magma (trachybasalts with SiO2 < 52.5 wt.% and MgO > 5.5% wt.%) reflect a heterogeneous enriched mantle source. High Th/U, Th/Ta, and Rb/Nb ratios and Nd-Sr-Pb-Hf isotope characteristics of the uncontaminated magmas suggest that the enriched mantle beneath Tengchong formed as a result of subduction of clay-rich sediments, which probably came from the Indian continental plate. Partial melting of the enriched mantle was generated by deep continental subduction coupled with recent regional extension in the Tengchong area.

  1. Abrupt change in magma generation processes across the Central American arc in southeastern Guatemala: flux-dominated melting near the base of the wedge to decompression melting near the top of the wedge

    NASA Astrophysics Data System (ADS)

    Walker, J. A.; Carr, M. J.; Patino, L. C.; Johnson, C. M.; Feigenson, M. D.; Ward, R. L.

    1995-07-01

    Lavas erupted behind the volcanic front in southeastern Guatemala have many important distinctions from lavas erupted on the volcanic front. These include: generally higher MgO, Nb, Sr, TiO2, and rare earth element concentrations; higher La/Yb and Nb/Y ratios; and lower Ba/La, La/Nb, Ba/Zr and Zr/Nb ratios. These major and trace element distinctions are caused by reduced fractionation during ascent and storage in the crust, lower degrees of melting in the source, and greatly reduced contributions from the subducted Cocos plate in the source. In addition, because all of these important distinctions are even borne in lavas erupted within 20 km of the front, there is little apparent petrogenetic continuity between front and behind-the-front magmas. What little geochemical continuity exists is in radiogenic isotopes: 143Nd/144Nd falls across the arc, Pb isotopic ratios (except 206Pb/204Pb) rise across the arc, and 87Sr/86Sr rise across the arc after an initial discontinuity within 20 km of the front. These continuous across-arc changes in radiogenic isotopes are caused by increased contamination with older, more isotopically disparate rocks, away from the front. Once the effects of crustal contamination are removed, the remaining isotopic variability behind the front is non-systematic and reflects the inherent isotopic heterogeneity of the source, the mantle wedge. Geochemical disconnection in southeastern Guatemala suggests that behind-the-front magmas are produced by decompression melting near the top of the wedge, not by flux-dominated melting near the base of the wedge.

  2. 40Ar/39Ar geochronology and geochemical reconnaissance of the Eocene Lowland Creek volcanic field, west-central Montana

    USGS Publications Warehouse

    Dudas, F.O.; Ispolatov, V.O.; Harlan, S.S.; Snee, L.W.

    2010-01-01

    We report geochronological and geochemical data for the calc-alkalic Lowland Creek volcanic field (LCVF) in westcentral Montana. 40Ar/ 39Ar age determinations show that the LCVF was active from 52.9 to 48.6 Ma, with tuff-forming eruptions at 52.9 ?? 0.14 and 51.8 ?? 0.14 Ma. These dates span the age range of vigorous Eocene igneous activity in the Kamloops-Absaroka-Challis belt. The LCVF evolved upward from basal rhyolites (SiO 2>71 wt%) to dacites and andesites (SiO 2 > 62 wt%). Compositional change parallels a transition from early explosive volcanism to late effusive activity. Four geochemical components can be detected in the rocks. A component with 206Pb/204Pb < 16.5 and epsilon;Nd near-15 is predominant in anhydrous, two-pyroxene dacites; hydrous rhyolites, rhyodacites, and dacites with epsilon;Nd below-10 are dominated by a second component; hydrous rocks with 206Pb/ 204Pb > 18.3 and epsilon;Nd>-9 contain a third component; and an andesite with low Nd content and epsilon;Nd near-9 probably contains a fourth component. The first three components probably derive from the lower and middle crust, whereas the fourth is probably from the lithospheric mantle. ?? 2010 by The University of Chicago.

  3. Sr, Nd and Pb isotopes in Proterozoic intrusives astride the Grenville Front in Labrador: Implications for crustal contamination and basement mapping

    USGS Publications Warehouse

    Ashwal, L.D.; Wooden, J.L.; Emslie, R.F.

    1986-01-01

    We report Sr, Nd and Pb isotopic compositions of mid-Proterozoic anorthosites and related rocks (1.45-1.65 Ga) and of younger olivine diabase dikes (1.4 Ga) from two complexes on either side of the Grenville Front in Labrador. Anorthositic or diabasic samples from the Mealy Mountains (Grenville Province) and Harp Lake (Nain-Churchill Provinces) complexes have very similar major, minor and trace element compositions, but distinctly different isotopic signatures. All Mealy Mountains samples have ISr = 0.7025-0.7033, ??{lunate}Nd = +0.6 to +5.6 and Pb isotopic compositions consistent with derivation from a mantle source depleted with respect to Nd/Sm and Rb/Sr. Pb isotopic compositions for the Mealy Mountains samples are slightly more radiogenic than model mantle compositions. All Harp Lake samples have ISr = 0.7032-0.7066, ??{lunate}Nd = -0.3 to -4.4 and variable, but generally unradiogenic 207Pb 204Pb and 206Pb 204Pb compared to model mantle, suggesting mixing between a mantle-derived component and a U-depleted crustal contaminant. Crustal contaminants are probably a variety of Archean high-grade quartzofeldspathic gneisses with low U/Pb ratios and include a component that must be isotopically similar to the early Archean (>3.6 Ga) Uivak gneisses of Labrador or the Amitsoq gneisses of west Greenland. This would imply that the ancient gneiss complex of coastal Labrador and Greenland is larger than indicated by present surface exposure and may extend in the subsurface as far west as the Labrador Trough. If Harp Lake and Mealy Mountains samples were subjected to the same degree of contamination, as suggested by their chemical similarities, then the Mealy contaminants must be much younger, probably early or middle Proterozoic in age. The Labrador segment of the Grenville Front, therefore, appears to coincide with the southern margin of the Archean North Atlantic craton and may represent a pre mid-Proterozoic suture. ?? 1986.

  4. Pb-Sr-O-C isotope compositions of metacarbonate rocks of the Derbina Formation (East Sayan): Chemostratigraphic and geochronological significance

    NASA Astrophysics Data System (ADS)

    Gorokhov, I. M.; Kuznetsov, A. B.; Ovchinnikova, G. V.; Nozhkin, A. D.; Azimov, P. Ya.; Kaurova, O. K.

    2016-01-01

    The Pb-Sr-O-C isotope compositions of calcite marbles of the Derbina Formation, exposed in the northwestern part of the Derbina block of the East Sayan, were studied. Rocks of the Derbina Formation were metamorphosed under high-temperature amphibolite facies conditions. The carbonate constituent of marbles contains (ppm) 15-130 Mn, 130-160 Fe, 0.008-0.039 Rb, 645-2190 Sr, 0.565-0.894 U, and 0.288-1.42 Pb. These concentrations are similar to those in modern carbonate sediments. The values of δ13C in marbles of the Derbina Formation range from-0.6 to +1.4‰ PDB; the values of δ18O range from 21.5 to 28.6‰ SMOW. The 87Sr/86Sr ratio values in the two least altered rocks, which meet geochemical criteria of the Rb-Sr system preservation in high-grade carbonate rocks, are 0.70804 and 0.70829. The protolith ages of marbles determined using Sr and C chemostratigraphy lie within the interval of 560-530 Ma, which is regarded as the period of carbonate sedimentation. The slope of the straight line on the 206Pb/204Pb-207Pb/204Pb diagram ( n = 9, MSWD = 19) constructed on the basis of the data points of bulk carbonate constituents of all samples studied and those representing leachate steps of one of them in 0.5N HBr yields Late Vendian age (556 ± 31 (2σ) Ma. Taking into account the data on Sr and C isotope systematics of Derbina marbles, this age is regarded as the age of early diagenesis of carbonate sediments close to the age of sedimentation. Thus, metacarbonate rocks of the Derbina Formation preserved the pre-metamorphic chemostratigraphic and isotope-geochronological information. The age obtained testifies that formation of the carbonate cover of the Derbina block occurred in the Late Vendian. At the end of the Cambrian, carbonate deposits were metamorphosed during the Early Caledonian tectonic event in the southeastern part of the Central Asian Fold Belt.

  5. CHRONOLOGICAL CONSTRAINTS ON FLUID CIRCULATION IN MESOZOIC FORMATIONS OF THE EASTERN PART OF THE PARIS BASIN INFERRED FROM U-Pb DATING OF SECONDARY INFILLING CARBONATES

    NASA Astrophysics Data System (ADS)

    Pisapia, C.; Deschamps, P.; Hamelin, B.; Buschaert, S.

    2009-12-01

    equilibrium composition, indicating that the precipitation phase was older than 650 ky. U-Pb measurements were performed on a VG sector Thermal Ionization Mass Spectrometer (TIMS) using a 205Pb-236U-233U-229Th spike. Pb contents are generally very low, between 3 and 20 ppb, while U contents are more variable, leading to μ = 238U/204Pb up to ~600. Sub-samples with high μ show radiogenic 206Pb/204Pb ratio, but at this stage isochrons generally show high scatter. These U-Pb data however are consistent with an Eocene-Oligocene period for the late carbonates precipitation phase. We will discuss the different processes that may be responsible for these errorchrons (i.e. heterogeneities in the initial isotopic composition; multi-stage growth) as well as the chronological constraints that can be drawn from these data.

  6. Taming the Mighty Mississippi: Integrating paleo-flood data and modeling to understand the patterns and causes of extreme floods on a major river system

    NASA Astrophysics Data System (ADS)

    Munoz, Samuel; Giosan, Liviu; Jeffrey, Donnelly; Dee, Sylvia; Shen, Zhixiong

    2016-04-01

    The Mississippi River is an economic artery of the United States that is heavily managed to provide flood control and maintain a navigable shipping channel. The current system of levees and spillway structures was conceived in the early 20th century, but the ability of this system to withstand the altered hydroclimatic conditions projected for the next century is poorly understood. Here, we present initial results from a project that integrates new sedimentary records from floodplain lakes with analyses of sediment geochemistry and climate model simulations to better understand the causes of extreme floods on the lower Mississippi River. In our sedimentary paleoflood records, flood event beds are characterized by an upward fining sequence from deposition of the bedload and suspended load during overbank floods, identified here using high-resolution laser particle-size analysis and elemental composition (XRF), and dated using radioisotopes (137Cs, 210Pb, 14C) and optically-stimulated luminescence (OSL) on quartz. Grain-size descriptors and elemental ratios of Zr/Fe and Fe/Rb are highly correlated, and are used alongside historical discharge records to develop a statistical model for reconstructing flood magnitude in prehistoric contexts. Geochemical analyses of sediments from the floodplains of major tributaries of the Mississippi are used to assess the systematics of 87Sr/86Sr, 143Nd/144Nd, 206Pb/204Pb, and 208Pb/204Pb across the basin, enabling identification of the synoptic patterns of individual paleo-flood events. We investigate the dynamical drivers of past floods on the lower Mississippi using both reanalysis data and the last millennium simulation from NCAR model CESM1 to find that increased likelihoods of extreme floods on the lower Mississippi River are associated with enhanced moisture flux over midcontinental North America that is controlled by the interaction of seasonally variable soil moisture over major tributaries with inter-annual (e.g., ENSO) and

  7. Genesis of ilmenite-series I-type granitoids at the Baogutu reduced porphyry Cu deposit, western Junggar, NW-China

    NASA Astrophysics Data System (ADS)

    Cao, MingJian; Qin, KeZhang; Li, GuangMing; Evans, Noreen J.; Hollings, Pete; Jin, LuYing

    2016-03-01

    The Baogutu porphyry Cu deposit is a typical reduced porphyry Cu deposit, likely related to ilmenite-series I-type granitoids. However, the nature of the granitoids (ilmenite-series or magnetite-series) and the genesis of the Baogutu deposit are still under debate. In order to resolve these issues, whole-rock magnetic susceptibility, geochemistry and Sr-Nd-Pb isotopic, zircon U-Pb dating and Hf-O isotopic compositions were carried out. Three different intrusive phases are recognized within the deposit, from oldest to youngest, they are diorite with trace gabbro, diorite-granodiorite porphyry, and hornblende diorite porphyry, all of which were emplaced in the Late Carboniferous (320-306 Ma) and show a metaluminous, calc-alkaline I-type granitoid character with typical supra-subduction zone geochemical affinities. The intrusions are characterized by widespread primary pyrrhotite without anhydrite and hematite, dominant ilmenite over magnetite, low whole rock magnetic susceptibility (< 1 × 10- 4 emu g- 1 oe- 1 or < 3 × 10- 3 SI unit) and low whole rock Fe2O3/FeO ratios (< 0.4), indicating that the granitoids are ilmenite- rather than magnetite-series I-type granitoids. Whole rock Sr-Nd-Pb isotopic compositions show limited variation but slightly enriched characteristics with (87Sr/86Sr)i values of 0.70357-0.70404, εNd (t) of + 6.3 to + 7.8, 206Pb/204Pb of 18.20-19.54 and 208Pb/204Pb of 37.97-39.55. Zircon Hf-O isotopic compositions show εHf (t) values of + 10.7 to + 15.8 and δ18O of 5.3-7.4‰. Zircon and apatite saturation thermometries yield temperatures of 720 to 920 °C with relatively higher temperatures for the porphyries than for the diorite. Limited variations in Sr-Nd-Pb-Hf-O isotopic compositions and extremely young whole rock T2DM (Nd) (430 to 570 Ma) and zircon TDMC (Hf) (310 to 640 Ma) do not indicate significant crustal contamination during magma ascent or emplacement. Rather the Baogutu ilmenite-series I-type granitoids were probably formed by

  8. Amsterdam-St. Paul Hotspot: Composition, Motion and History

    NASA Astrophysics Data System (ADS)

    Janin, Myriam; Hemond, Christophe; Maia, Marcia; Guillou, Herve; Nonnotte, Philippe; Ponzevera, Emmanuel

    2010-05-01

    The Amsterdam-St Paul (ASP) plateau results of the excess of melting induced by the interaction between the ASP hotspot and the South-East Indian Ridge. The ASP plume was originally located beneath the Australian Plate and its interaction with the SEIR began about 10 Ma ago. This location provides an unique opportunity to study the hotspot prior to its interaction with the SEIR and its chemical and physical evolution. An exhaustive study of the hotspot characteristics prior to its interaction lead to know its geochemical compositions. The geochemistry of its interaction with the SEIR (i. e. ASP plateau) provides indirect information on the regional Indian Ocean upper mantle. ASP plume has a moderately enriched composition with resulting seamount melts having 2.5 < (La/Sm)C1norm < 2.8. In addition isotope ratios are not as extreme as estimated in previous works [Doucet et al. 2004; Nicolaysen et al., 2007] with 86Sr/87Sr ≈ 0.7040, 143Nd/144Nd ≈ 0.5128, 206Pb/204Pb ≈ 19.0 and 208Pb/204Pb ≈ 39.2. The ASP plateau isotopic composition reveals that the Indian Ocean upper mantle is extremely heterogeneous. It was proposed that the ridge segments across the plateau have interacted 40 My ago with Kerguelen plume [Frey et al. 2000]. We therefore assume that some plume material has been left behind in the Indian Ocean upper mantle during the movement of the Australian plate above it. Consequently, the upper mantle in the area might be a good example of 'marble cake' [Allegre&Turcotte, 1986]. When the SEIR approaches the ASP hotspot, plume derived material mixes with the surrounded mantle leading to the complexity seen in ASP plateau materials. K-Ar datings reveal that the absolute motion of the Australian plate calculated with respect to the fixity of ASP plume is of about 77 km/My. With a spreading rate of about 6-7 cm/yr the accretion at the SEIR axis cannot account for this velocity. In consequence, an absolute motion of the ASP plume of about 10-20km

  9. Pb isotopic variability in the modern-Pleistocene Indus River system measured by ion microprobe in detrital K-feldspar grains

    NASA Astrophysics Data System (ADS)

    Alizai, Anwar; Clift, Peter D.; Giosan, Liviu; VanLaningham, Sam; Hinton, Richard; Tabrez, Ali R.; Danish, Muhammad; Edinburgh Ion Microprobe Facility (EIMF)

    2011-09-01

    The western Himalaya, Karakoram and Tibet are known to be heterogeneous with regard to Pb isotope compositions in K-feldspars, which allows this system to be used as a sediment provenance tool. We used secondary ion mass spectrometry to measure the isotopic character of silt and sand-sized grains from the modern Sutlej and Chenab Rivers, together with Thar Desert sands, in order to constrain their origin. The rivers show a clear Himalayan provenance, contrasting with grains from the Indus Suture Zone, but with overlap to known Karakoram compositions. The desert dunes commonly show 207Pb/ 204Pb and 206Pb/ 204Pb values that are much higher than those seen in the rivers, most consistent with erosion from Nanga Parbat. This implies at least some origin from the trunk Indus, probably reworked by summer monsoon winds from the SW, a hypothesis supported by bulk Nd and U-Pb zircon dating. Further data collected from Holocene and Pleistocene sands shows that filled and abandoned channels on the western edge of the Thar Desert were sourced from Himalayan rivers before and at 6-8 ka, but that after that time the proportion of high isotopic ratio grains rose, indicating increased contribution from the Thar Desert dunes prior to ˜4.5 ka when flow ceased entirely. This may be linked to climatic drying, northward expansion of the Thar Desert, or changes in drainage style including regional capture, channel abandonment, or active local Thar tributaries. Our data further show a Himalayan river channel east of the present Indus, close to the delta, in the Nara River valley during the middle Holocene. While this cannot be distinguished from the Indus it is not heavily contaminated by reworking from the desert. The Pb system shows some use as a provenance tool, but is not effective at demonstrating whether these Nara sediments represent a Ghaggar-Hakra stream independent from the Indus. Our study highlights an important role for eolian reworking of floodplain sediments in arid rivers

  10. Rare-earth elements and Nd and Pb isotopes as source indicators for Labrador Sea clay-size sediments during Heinrich event 2

    USGS Publications Warehouse

    Benson, L.; Barber, David; Andrews, John T.; Taylor, H.; Lamothe, P.

    2003-01-01

    Elemental abundances and Nd and Pb isotope ratios were determined on samples from the carbonate-free, clay-size fractions of sediments from intervals above, within, and below Heinrich event 2 (H-2) in core HU87-9 from the Northwest Labrador Sea slope. In HU87-9, rare-earth element (REE) distributions and elemental concentrations within the H-2 event are distinct from those outside this event, ??Nd(0) and 206Pb/204Pb data also indicate different values for sediments deposited within and outside the H-2 event. Comparisons of REE patterns from the H-2 interval with those from bedrock units in Baffin Island, northern Quebec, and Labrador indicate that the Lake Harbour Group (LHG), which crops out on the north side of the Hudson Strait, is the most probable bedrock source of the clay-size fraction found within the H-2 interval in HU87-9. The Tasiuyak Gneiss (TG) and Lac Lomier Complex (LLC) have REE patterns (including a negative Eu anomaly) similar to those found in H-2 sediments; however, the La/Yb ratios of these units are smaller than those associated with H-2 sediments. The Nd and Pb isotope data support and complement REE-based interpretations of provenance; i.e., the Nd-Pb signatures of sediments deposited at the HU87-9 site during the H-2 event are similar to Nd-Pb signatures obtained on diamicts from the western end of Hudson Strait. Published by Elsevier Science Ltd.

  11. Copahue volcano and its regional magmatic setting

    USGS Publications Warehouse

    Varekamp, J C; Zareski, J E; Camfield, L M; Todd, Erin

    2016-01-01

    Copahue volcano (Province of Neuquen, Argentina) has produced lavas and strombolian deposits over several 100,000s of years, building a rounded volcano with a 3 km elevation. The products are mainly basaltic andesites, with the 2000–2012 eruptive products the most mafic. The geochemistry of Copahue products is compared with those of the main Andes arc (Llaima, Callaqui, Tolhuaca), the older Caviahue volcano directly east of Copahue, and the back arc volcanics of the Loncopue graben. The Caviahue rocks resemble the main Andes arc suite, whereas the Copahue rocks are characterized by lower Fe and Ti contents and higher incompatible element concentrations. The rocks have negative Nb-Ta anomalies, modest enrichments in radiogenic Sr and Pb isotope ratios and slightly depleted Nd isotope ratios. The combined trace element and isotopic data indicate that Copahue magmas formed in a relatively dry mantle environment, with melting of a subducted sediment residue. The back arc basalts show a wide variation in isotopic composition, have similar water contents as the Copahue magmas and show evidence for a subducted sedimentary component in their source regions. The low 206Pb/204Pb of some backarc lava flows suggests the presence of a second endmember with an EM1 flavor in its source. The overall magma genesis is explained within the context of a subducted slab with sediment that gradually looses water, water-mobile elements, and then switches to sediment melt extracts deeper down in the subduction zone. With the change in element extraction mechanism with depth comes a depletion and fractionation of the subducted complex that is reflected in the isotope and trace element signatures of the products from the main arc to Copahue to the back arc basalts.

  12. Back-arc basalts from the Loncopue graben (Province of Neuquen, Argentina)

    NASA Astrophysics Data System (ADS)

    Varekamp, J. C.; Hesse, A.; Mandeville, C. W.

    2010-11-01

    Young basaltic back-arc volcanoes occur east of the main Andes chain at about 37.5°-39°S in the Loncopue graben, Province of Neuquen, Argentina. These olivine-rich basalts and trachybasalts have up to 8% MgO, with high Ni and Cr contents, but highly variable incompatible element concentrations. Mafic lava flows and cinder cones at the southern end of the graben lack phenocrystic plagioclase. The northern samples have relative Ta-Nb depletions and K, Pb and LREE enrichment. These samples strongly resemble rocks of the nearby arc volcanoes Copahue and Caviahue, including their Fe-Ti enrichment relative to the main Andes arc rocks. The Sr, Nd and Pb isotope ratios show that the source regions of these back-arc basalts are enriched in subducted components that were depleted in the aqueous mobile elements such as Cs, Sr and Ba as a result of prior extractions from the subducted complex below the main arc. Some mafic flows show slightly low 206Pb/ 204Pb and 143Nd/ 144Nd values as well as incompatible trace element ratios similar to southern Patagonia plateau back-arc basalts, suggesting contributions from an EM1 mantle source. Geothermometry and barometry suggest that the basalts crystallized and fractionated small amounts of olivine and spinel at ˜ 35 km depth at temperatures of 1170-1220 °C, at about QFM + 0.5 to QFM + 1 with 1-2% H 2O, and then rose rapidly to the surface. The Loncopue graben back-arc basalts are transitional in composition between the South Patagonia back-arc plateau basalts and the Caviahue and Copahue arc volcanoes to the northwest. The EM1 source endmember is possibly the subcontinental lithospheric mantle. Strong variations in incompatible element enrichment and isotopic compositions between closely spaced cinder cones and lava flows suggest a heterogeneous mantle source for the Loncopue graben volcanics.

  13. The sources and time-integrated evolution of diamond-forming fluids - Trace elements and isotopic evidence

    NASA Astrophysics Data System (ADS)

    Klein-BenDavid, Ofra; Pearson, D. Graham; Nowell, Geoff M.; Ottley, Chris; McNeill, John C. R.; Logvinova, Alla; Sobolev, Nikolay V.

    2014-01-01

    , kimberlite-like 206Pb/204Pb and 208Pb/204Pb ratios. A multi-stage evolution of the diamond-forming fluids source can be constrained from our new isotopic data, indicating an Achaean enrichment event resulting in elevated U/Pb, Rb/Sr ratios and enrichment in LREEs. This source underwent a more recent fractionation, in the last 500 Myr that may have been related to the diamond-forming event. There is a strong correspondence between fluids with relatively unradiogenic Sr isotopes and relatively low (La, Nd, Sm)/(Nb, Zr) and (Ba, Th)/(Nb) ratios. Sr isotopic enrichment is accompanied by an increase in these ratios. The least trace element enriched and most isotopically depleted fluids are from the high-Mg carbonatitic suite. Thus, HDFs could be derived from asthenospheric mantle as low degree melts that interact to varying degrees with an ancient, metasomatized, rutile- and phlogopite bearing, sub continental lithosphere mantle. The internal heterogeneity in the Sr isotopic ratios within a single diamond suite and even within single diamonds may indicate fluid-mixing processes. Such mixing may occur during migration through preferred mantle veins and may be affected by the small-scale geochemical variability within them.

  14. Anthropogenic and natural lead isotopes in Fe-hydroxides and Fe-sulphates in a watershed associated with arsenic-enriched groundwater, Maine, USA

    USGS Publications Warehouse

    Ayuso, Robert A.; Foley, Nora K.

    2008-01-01

    A survey of the natural and anthropogenic sources of lead contributing to secondary minerals in sulphidic schists associated with arsenic-enriched groundwater in Coastal Maine shows that the most likely source is natural Pb, particularly from coexisting sulphide minerals. The secondary minerals also reflect notable contributions from anthropogenic Pb. The Pb isotopes establish pathways by which Pb, and by inference As, could have been transported from As-bearing minerals (arsenian pyrite, arsenopyrite, lollingite, orpiment, arsenic oxide and others), via sulphide oxidation or carbonation reactions into multiple generations of secondary minerals (goethite, hematite, jarosite, natrojarosite and others). Lead isotopic compositions of the sulphides and secondary minerals determined by thermal ionization mass spectrometry (n=53) range widely. Lead and As contents of the sulphides and secondary minerals overlap, and are generally positively correlated. Pyrite, the dominant sulphide in sulphidic schists associated with As-enriched groundwater in Coastal Maine, has values of 206Pb/204Pb from 18.186 to 18.391, 207Pb/204Pb from 15.617 to 15.657, 208Pb/204Pb from 38.052 to 38.210, 206Pb/207Pb from c. 1.1625 to 1.1760 and 208Pb/207Pb from c. 2.4276 to 2.4394. Mixtures of Fe-hydroxide and oxide minerals (predominantly goethite and hematite) and secondary Fe-sulphate minerals (jarosite, natrojarosite, rozenite and melanterite) in the sulphidic schists have overlapping but generally higher values of 206Pb/204Pb from 18.495 to 19.747 (one sample at 21.495), 207Pb/204Pb from 15.595 to 15.722 (one sample at 15.839), 208Pb/204Pb from 38.186 to 39.162,206Pb/207Pb from c.1.1860 to 1.2575 (one sample at 1.3855) and 208Pb/207Pb from c. 2.4441 to 2.4865 than the sulphides. Sulphides from Zn-Pb metal mines are somewhat less radiogenic than sulphides from the schists. Other sulphides (mostly pyrite) associated with pegmatites and granitic rocks are heterogeneous and more

  15. Origin of adakite-like plutons in southern Korea

    NASA Astrophysics Data System (ADS)

    Oh, Jeong-Im; Choi, Sung Hi; Yi, Keewook

    2016-10-01

    We present Sr-Nd-Pb isotopic compositions for two adakite-like intrusions in southern Korea (Jindong and Bongnae), including major and trace element concentrations, and the sensitive high-resolution ion microprobe (SHRIMP) zircon U-Pb age. Our aim is to constrain the origin and tectonomagmatic processes that gave rise to the plutons. A SHRIMP U-Pb zircon age of 88.7 ± 0.7 Ma was obtained from a Jindong granodiorite sample. The Jindong plutons belong to the medium-K calc-alkaline series, and have an overall enrichment in large ion lithophile elements (LILE), such as K, Rb, Ba, and Pb, and a relative depletion in high field strength elements, such as Nb, Ta, and Ti, compared with the neighboring elements in the primitive mantle-normalized multi-trace element variation diagram. It was found that (87Sr/86Sr)i = 0.70475-0.70596, (143Nd/144Nd)i = 0.512547-0.512604, [(εNd)i = + 0.4 to 2.2], and (206Pb/204Pb)i = 18.19-18.37, which fall within the field of the arc-type Cretaceous to Tertiary Bulguksa intrusive rocks in the Sr-Nd and Pb-Pb isotopic correlation diagrams. The elevated Sr/Y (17-40), but low La/Yb (3.7-8.8) ratios of the Jindong plutons, together with their coherent geochemical trends and U-shaped rare earth element (REE) patterns, indicate that they were not formed by slab melting, but by amphibole-dominated fractional crystallization of the Bulguksa-like arc magma. A SHRIMP U-Pb zircon age of 226.5 ± 2.5 Ma was obtained from a Bongnae tonalite sample. The Bongnae plutons belong to the shoshonitic series. Their trace element patterns resemble the Jindong samples, but are characterized by significantly negative U anomalies in mafic rocks. They also have elevated MgO, Ni, Co, Cr, Rb, Ba, Sr, and low Al2O3 and Na2O contents at a given SiO2 concentration compared with the Jindong plutons, and are typified by highly radiogenic Sr and unradiogenic Nd and Pb isotopic compositions: [(87Sr/86Sr)i = 0.71096-0.71290, (143Nd/144Nd)i = 0.511641-0.511681, (εNd)i = - 13

  16. Hydrothermal versus active margin sediment supply to the eastern equatorial Pacific over the past 23 million years traced by radiogenic Pb isotopes: Paleoceanographic and paleoclimatic implications

    NASA Astrophysics Data System (ADS)

    Höfig, Tobias W.; Hoernle, Kaj; Hauff, Folkmar; Frank, Martin

    2016-10-01

    We investigated the evolution of the Pb isotopic composition of bulk sediments on the Cocos Plate in sedimentary successions of Deep Sea Drilling Project (DSDP) Site 495 and Ocean Drilling Program/Integrated Ocean Drilling Program (ODP/IODP) Site 1256 over the past 23 million years of depositional history. Our study addresses the relationship of the sediment Pb isotope record to plate tectonics, weathering inputs, and paleoceanography. It is the first effort to characterize the Pb isotopic evolution of eastern equatorial Pacific sedimentation covering the entire tectonic pathway of the Cocos Plate from its formation at the East Pacific Rise to its arrival at the Central American subduction zone. The Sites 495 and 1256 bulk sediment Pb isotope records are fully consistent over time despite distinct differences between the type of sediment deposited at both locations. A systematic and continuous trend from ∼23 to ∼6-4 Ma toward more radiogenic Pb isotopic compositions, e.g., 206Pb/204Pb ratios increase from 18.29 to 18.81, reflects a decrease in the contribution of hydrothermal particles from the East Pacific Rise and an increase in the predominantly eolian contribution of mixed weathering products from the continental arcs of the Northern and south Central Andes as well as from southern Mexico. Surprisingly, both the Pb isotopic composition of the detrital fraction and that of past seawater indicate that inputs from nearby Central America and the Galápagos Archipelago did not significantly contribute to the sediments of our core locations but were overwhelmed by other sediment sources. A systematic change to less radiogenic Pb isotope ratios in sediments younger than ∼4-3 Ma, reaching present-day 206Pb/204Pb values near 18.70, reflects a reduction of the continental input from the South Central Volcanic Zone of the Andean Arc and increased contributions from southern Mexican igneous complexes. This isotopic trend reversal took place as a consequence of

  17. Small-Scale Mantle Heterogeneities Beneath the Endeavour Segment, Juan de Fuca Ridge

    NASA Astrophysics Data System (ADS)

    Harris, C. R.; Gill, J.; Woodcock, J.; Anderson, R.

    2008-12-01

    The Endeavour segment of the Juan de Fuca Ridge samples at least two different geochemical heterogeneities unrelated to adjacent hot spots. One is FOZO-like in isotopes and HFSE-rich. Another is K+LREE-rich. Both are sampled randomly in short spatial (few-km) and temporal succession through separate MORB melting events, but the FOZO-like MORB is restricted to axial magmas that rise along a major fault and by-pass the axial magma chamber. The large geochemical diversity and high density of submersible-collected samples creates opportunity for constraining melting processes and mantle dynamics beneath an intermediate spreading-rate ridge. Basalts from the Endeavour Axial Ridge Volcano (EARV) can be divided into N-type (normal) MORBs (K2O/TiO2 < 0.15), transitional, or T-MORBs (K2O/TiO2 = 0.15 - 0.25), and enriched, or E-MORBs (K2O/TiO2 > 0.25). N-MORBs have highest Zr/Nb and E-MORBs the lowest Zr/Nb. Recently we discovered the most trace element depleted N- MORB yet at Endeavour. This sample originates from the base of the western wall of the axial valley south of the Mothra vent field, located in the southern-most part of the EARV. However, none of the samples are as depleted as those from the sea floor beyond the ridge flanks or from the Heckle Seamounts to the north. Two subgroups of N-MORBs and three subgroups of T-MORBs are defined by consistent major and trace element characteristics. For example, T1 MORBs have the lowest SiO2; the T2 group has the lowest Na2O and higher Fe8 than T3. Trace element differences among the various groups can not be explained by crystal fractionation alone. Pb isotopes do not correlate with K2O/TiO2. T1 MORBs have the highest 206Pb/204Pb ratios and T3 MORBs generally have the lowest 206Pb/204Pb and lowest 143Nd/144Nd ratios. Pb isotopes of bulk rocks and sulfides define an array beneath the Northern Hemispheric Reference Line. The sulfide data (LaBonte et al., 2006; Cook, 1994; Tivey and Delaney, 1985) indicate deposition from

  18. Pb - Isotopes and Pulses of the Deccan Plume

    NASA Astrophysics Data System (ADS)

    Basu, A. R.; Yannopoulos, A. S.

    2015-12-01

    Mantle plumes are generally implicated for flood basalt generation in both continental and oceanic environments by impact of large plume heads beneath or within the lithosphere. The Deccan and Siberian flood basalt eruptions, synchronous with the Cretaceous-Paleogene and end-Permian extinctions, respectively, continue to fascinate geoscientists in search for the "kill-mechanisms" by impacts, volcanisms or both. Recently, Richards et al. (2015) proposed that bulk of the Deccan eruption was triggered by the Chicxulub impact. We showed (Basu et al., 1993) that early (68.5 Ma) and late (65 Ma) alkalic pulses of the Deccan were before and after the impact event at 66 Ma. Here, we focus on an extensive volcano-stratigraphic study of Pb isotopic systematics of 69 basaltic samples from 3 subgroups and 12 formations of the Deccan, each sampled from bottom to top along the stratigraphic section, covering the 3km thick 12 Deccan formations. Pb is sensitive to crustal contamination of mantle plume-derived magmas as both the upper and lower mantle are low in Pb (0.02 - 0.15 ppm) compared to ~ 4 ppm in continental crust. The lower Deccan formations of Kalsubai and Lonavala have initial 206Pb/204Pb with a widely varying range (16.543 - 22.823) indicating continental crustal contamination. In contrast, the upper formations of the Wai subgroup show a narrow range of 16.883 to 18.956, reflecting the plume signature. In addition, the 206Pb/204Pb and 207Pb/204Pb data of the Kalsubai subgroup lavas give an isochron age of 2603±140 Ma (single-stage, µ = 8). The Wai subgroup shows a narrow and restricted Pb isotopic range plotting closer to the Geochron. We interpret these data to infer that the basement rocks of the Deccan, the Archean Indian craton, were assimilated by the upwelling melt, ultimately clearing the conduit passages for the lavas sourced from direct melting of the plume head.

  19. Dissolved lead in the deep Southeast Pacific Ocean: results of the 2013 US GEOTRACES cruise

    NASA Astrophysics Data System (ADS)

    Boyle, E. A.; Lee, J. M.; Zhang, J.; Echegoyen, Y.

    2014-12-01

    Lead (Pb) in the modern ocean is dominated by anthropogenic Pb, which has been evidenced by highly elevated seawater Pb concentrations and Pb stable isotope ratios (204Pb, 206Pb, 207Pb, and 208Pb) altered from pre-anthropogenic values. A number of studies have shown the human impact on oceanic Pb in many parts of the world ocean, but little Pb data has been available for the Southeast Pacific Ocean. In this presentation, we will show the dissolved Pb (<0.2µm) results from the US GEOTRACES cruise in October - December 2013, which sailed from Manta, Ecuador, to Tahiti along around 12 degrees south. Dissolved Pb concentrations from all 36 surface stations and deep (>1000m) Pb profiles from 18 stations will be presented, and the results will be also compared to our unpublished data from the BiG RAPA cruise in 2010, whose cruise track from Arica, Peru, to Easter Island is slightly south of the US GEOTRACES cruise. The BiG RAPA data showed that dissolved Pb concentrations of the southeast Pacific Ocean are relatively low, varying in the range of 8-20 pmol/kg at the surface with a slight maximum (14-22 pmol/kg) at around 400m depth, and 2-10 pmol/kg in deep waters below 1000m depth. The Pb concentrations were found to be higher at a marginal station off Peru, reaching 45 pmol/kg at the surface and 65 pmol/kg in the subsurface maximum at 150m depth, and varying between 17 and 23 pmol/kg in deep waters. Our dataset, along with the results from the BiG RAPA cruise, will provide the first overview on the dissolved Pb distribution of the southeast Pacific Ocean, which will further our understanding on the human impact on the global ocean.

  20. Impact of Dust from Ore Processing Facilities on Rain Water Collection Tanks in a Tropical Environment—The Obvious Source “Ain’t Necessarily So”

    PubMed Central

    Gulson, Brian; Korsch, Michael; Bradshaw, Anthony

    2016-01-01

    Concerns have been expressed that dust from the minerals processing facilities at Karumba Queensland Australia have resulted in elevated lead (Pb) concentrations in rain water tanks. The ores derived from the Century mine some 304 km from the port. High precision Pb isotopic measurements on environmental samples have been undertaken to evaluate the source of Pb in rainwaters and acid digests from roof wipes and gutter wipes. There does not appear to be any relationship between sample location and the processing facility but samples from the area subject to the prevailing winds show the highest contribution of Century Pb. All gutter wipes (82 to 1270 µg Pb/wipe) have contributions of Century ore ranging from 87% to 96%. The contribution of Century ore to five roof wipes (22 to 88 µg Pb/wipe) ranges from 89% to 97% and in the other two samples there is a mix of Century and Broken Hill Pb. Three of the seven rainwater have contributions of Century ore Pb ranging from 33% to 75%. Two of the other four rainwater samples have the highest water Pb concentrations of 88 and 100 µg/L and their isotopic data show Broken Hill Pb contributions ranging from 77% to 80%. The source of the Broken Hill Pb is probably from the galvanized roofing material and/or brass fittings in the rainwater tanks. The discrimination between various sources is only detectable using high precision 204Pb-based isotopic ratios and not the now common inductively coupled plasma mass spectrometry (ICP-MS ) data presentations of the higher abundance isotopes 208Pb, 207Pb and 206Pb. Isotopic results for the waters demonstrate that apportioning blame where there is an obvious point source may not always be the correct conclusion. Nevertheless the isotopic data for the gutter wipes indicates that there was widespread contamination from the processing facilities throughout the town. PMID:26907319

  1. Impact of Dust from Ore Processing Facilities on Rain Water Collection Tanks in a Tropical Environment--The Obvious Source "Ain't Necessarily So".

    PubMed

    Gulson, Brian; Korsch, Michael; Bradshaw, Anthony

    2016-02-22

    Concerns have been expressed that dust from the minerals processing facilities at Karumba Queensland Australia have resulted in elevated lead (Pb) concentrations in rain water tanks. The ores derived from the Century mine some 304 km from the port. High precision Pb isotopic measurements on environmental samples have been undertaken to evaluate the source of Pb in rainwaters and acid digests from roof wipes and gutter wipes. There does not appear to be any relationship between sample location and the processing facility but samples from the area subject to the prevailing winds show the highest contribution of Century Pb. All gutter wipes (82 to 1270 µg Pb/wipe) have contributions of Century ore ranging from 87% to 96%. The contribution of Century ore to five roof wipes (22 to 88 µg Pb/wipe) ranges from 89% to 97% and in the other two samples there is a mix of Century and Broken Hill Pb. Three of the seven rainwater have contributions of Century ore Pb ranging from 33% to 75%. Two of the other four rainwater samples have the highest water Pb concentrations of 88 and 100 µg/L and their isotopic data show Broken Hill Pb contributions ranging from 77% to 80%. The source of the Broken Hill Pb is probably from the galvanized roofing material and/or brass fittings in the rainwater tanks. The discrimination between various sources is only detectable using high precision (204)Pb-based isotopic ratios and not the now common inductively coupled plasma mass spectrometry (ICP-MS ) data presentations of the higher abundance isotopes (208)Pb, (207)Pb and (206)Pb. Isotopic results for the waters demonstrate that apportioning blame where there is an obvious point source may not always be the correct conclusion. Nevertheless the isotopic data for the gutter wipes indicates that there was widespread contamination from the processing facilities throughout the town.

  2. Chemical and isotopic studies of granitic Archean rocks, Owl Creek Mountains, Wyoming: Uranium-thorium-lead systematics of an Archean granite from the Owl Creek Mountains, Wyoming

    SciTech Connect

    Stuckless, J.S.; Nkomo, I.T.; Butt, K.A.

    1986-01-01

    Isotopic analyses of apparently unaltered whole-rock samples of a granite from the Owl Creek Mountains, Wyo., yield a lead-lead isochron age of 2730 {plus minus} 35 Ma, which is somewhat older than the age obtained by the rubidium-strontium whole-rock method. Thorium-lead data for the same samples deviate markedly from an isochronal relation; however, calculated initial {sup 208}Pb/{sup 204}Pb ratios correlate with whole-rock {delta}{sup 18}O values and lead to the conclusion that the {sup 232}Th-{sup 208}Pb data are not colinear because of an originally heterogeneous granitic magma. Relationships in the {sup 207}Pb/{sup 235}U-{sup 206}Pb/{sup 238}U system show that uranium was mobilized during early Laramide time or shortly before, such that most surface and shallow drill-core samples lost 60-80 percent of their uranium, and some fractured, deeper drill-core samples gained from 50 to 10,000 percent uranium. Fission-track maps show that much uranium is located along edges and cleavages of biotite and magnetic where it is readily accessible to oxidizing ground water. Furthermore, qualitative comparisons of uranium distribution in samples with excess radiogenic lead and in samples with approximately equilibrium amounts of uranium and lead suggest that the latter contain more uranium in these readily accessible sites. Unlike other granites that have uranium distributions and isotopic systematics similar to those observed in this study, the granite of the Owl Creek Mountains is not associated with economic uranium deposits.

  3. Pb isotope variations among Bandelier Tuff feldspars: No evidence for a long-lived silicic magma chamber

    NASA Astrophysics Data System (ADS)

    Wolff, J. A.; Ramos, F. C.

    2003-06-01

    We report, for the first time, high-precision Pb isotope data from a high-silica rhyolite. Prior work on Sr isotopes in the 1.6 Ma Otowi Member of the Bandelier Tuff (Valles caldera, New Mexico) established that large 87Sr/86Sr variations exist among Otowi glasses and sanidine phenocrysts. While the glasses display unequivocal evidence for wall-rock contamination of the Otowi magma following sanidine growth, a positive correlation between 87Sr/86Sri and 87Rb/86Sr among the feldspars could be interpreted as either a mixing line or an in situ magmatic isochron dating a differentiation event ˜270 k.y. prior to eruption. The 206Pb/204Pb and 87Sr/86Sr ranges for Otowi sanidines are 17.790 ± 0.002 to 17.831 ± 0.002 and 0.7074 0.7052, respectively. This Pb isotope range cannot be produced by radiogenic ingrowth at the U/Pb ratios of the host magma on any geologically reasonable time scale, and hence is unequivocal evidence for open-system behavior of the Otowi magma prior to and/or concurrent with feldspar growth. Open-system behavior is predicted to control Sr isotope variations due to much higher concentrations of Sr, relative to Pb, in the country rock than in the magma. These observations therefore undermine any age significance of the Rb-Sr isotope variations. In the absence of supporting data, Rb-Sr relations alone do not impart any information about residence times of high-silica rhyolite magmas with subchondritic concentrations of Sr.

  4. Evolution of Mauna Kea Volcano, Hawaii: Petrologic and geochemical constraints on postshield volcanism

    SciTech Connect

    Frey, F.A.; Kennedy, A. ); Wise, W.S.; Kwon, S.T. ); Garcia, M.O.; West, H. )

    1990-02-10

    The postshield stage of volcano construction formed as the magma supply rate from the mantle decreased. The basaltic substage (Hamakua Volcanics) contains a diverse array of lava types including picrites, ankaramites, alkalic and tholeiitic basalt, and high Fe-Ti basalt. In contrast, the hawaiite substage (Laupahoehoe Volcanics) contains only evolved alkalic lavas, hawaiite, and mugearite; basalts are absent. Sr and Nd isotopic ratios for lavas from the two substages are similar, but there is a distinct compositional gap between the substages. The authors conclude that the petrogenetic processes forming the postshield lavas at Maina Kea and other Hawaiian volcanoes reflect movement of the volcano away from the hotspot. Specifically, they postulate the following sequence of events for postshield volcanism at Mauna Kea: (1) As the magma supply rate from the mantle decreased, major changes in volcanic plumbing occurred. The shallow magma chamber present during shield construction cooled and crystallized, and the fractures enabling magma ascent to the magma chamber closed. (2) Therefore subsequent basaltic magma ascending from the mantle stagnated within the lower crust, or perhaps at the crust-mantle boundary. Eruptions of basaltic magma ceased. (3) Continued volcanism was inhibited until basaltic magma in the lower crust cooled sufficiently to create relatively low-density, residual hawaiitic melts. Minor assimilation of MORB-related wall rocks, reflected by a trend toward lower {sup 206}Pb/{sup 204}/Pb in evolved postshield lavas, may have occurred at this time. A compositional gap developed because magma ascent was not possible until a low-density hawaiitic melt could escape from a largely crystalline mush.

  5. The provenance of ice-rafted debris in the glacial NE Atlantic: Ice sheet dynamics and global sea-level change during Heinrich event 4

    NASA Astrophysics Data System (ADS)

    Austin, William; Hibbert, Fiona; Leigh, Sasha; Ellam, Robert; Hodell, David

    2015-04-01

    The growth of the last British and Irish ice sheet (BIIS) through Marine Isotope Stage (MIS) 3 and its expansion onto and across the continental shelf of NW Scotland provides an excellent opportunity to test the relative contribution of BIIS ice-rafted debris (IRD) into Heinrich layers (HL ) adjacent to the European margin. Radiogenic isotope measurements of the sediments and quantification of the IRD components enable us to differentiate between geological source regions and provide a critical test of rapid, non-destructive mineral magnetic measurements which have been used to model sediment provenance through this interval. Within Greenland stadial (GS) 9 (approximately 40,120 - 38,360 yr ago) we recognize HL4 as a prominent, short-lived (ca. 200 yr) IRD event, characterized by a marked increase in the concentration of detrital carbonate grains with a diagnostic LIS δ18O fingerprint and decrease in the 206Pb/204Pb ratio and ɛNd(0) values of bulk sediments. A magnetic un-mixing model confirms that a Laurentide ice sheet (LIS)-sourced component dominates HL4 and that a BIIS-sourced component characterizes the latter part of GS9, increasing in relative abundance until the abrupt warming that marks the GS9 - Greenland interstadial (GI) 8 transition. The observed LIS-BIIS sequence, which we have replicated from cores MD95-2006 and MD04-2822, located 83 km apart in the northeastern North Atlantic, does not provide evidence of European "precursor" IRD events prior to HL4. Our results suggest that an extensive lobe of the BIIS extended onto the continental shelf of NW Europe during GS9 (ca. 38.5 kyr) and that an abrupt sea-level rise associated with the LIS-sourced component of HL4 triggered regional BIIS instability and collapse, with important implications for the relative timing of global sea-level change at this time.

  6. Geochemistry of Alvarado and Sarmiento Ridges Suggests Widespread Galapagos Plume-Upper Mantle Interaction in the Miocene Eastern Pacific?

    NASA Astrophysics Data System (ADS)

    Castillo, P. R.; Lonsdale, P. F.

    2004-12-01

    Alvarado and Sarmiento are 1-2 km high, ~400 km-long, NE striking volcanic ridges in the Peru Basin that lie 150 km and 250 km, respectively, southeast of the Grijalva Scarp. The latter marks the southern boundary between the younger Cocos-Nazca and older EPR-Farallon crusts. The two ridges were originally proposed as transform fault trails on the Farallon plate, but new evidence suggest that they were the result of fissure eruption during an initially (pre-24Ma) broad zone of Farallon plate rupture. The rupture later became focussed along the Grijalva fracture, splitting the Farallon plate at 23Ma to create the Cocos and Nazca plates and initiating the Cocos-Nazca spreading center. Lava samples from the ridges were dredged during the DANA 02 expedition aboard R/V Revelle in Fall 2003. The lavas are invariably basalts ranging from tholeiitic to alkalic in composition. The basalts have flat to highly incompatible element-enriched trace element patterns and although their isotopic ratios are not as radiogenic as those of some of the Galapagos hotspot lavas, they are neither as depleted as those of normal-MORB (87Sr/86Sr[25Ma] >0.7027; 143Nd/144Nd[25Ma] <0.5130; 206Pb/204Pb[25Ma] >18.66). Some of the ridge lavas are compositionally similar to enriched-MORB erupted along the GSC section close to the Galapagos hotspot, but the majority are more akin to the relatively depleted hotspot lavas erupted at the center of the Galapagos Archipelago. The new geochemical data suggest that the volcanic ridge lavas came from a fairly large, anomalous region of the upper mantle that may have been created by the interaction between a Galapagos plume and the depleted source of MORB.

  7. Magma types and mantle sources of the Bárðarbunga volcanic system, Iceland

    NASA Astrophysics Data System (ADS)

    Halldórsson, Sæmundur; Rubin, Ken; Sverrisdóttir, Guðrún; Sigurðsson, Gylfi

    2015-04-01

    , Holocene lavas from the Veiðivötn fissure swarm lie on two parallel trends, with 206Pb/204Pb ratios >18.40. In contrast, subglacial formations in the Dyngjuháls region, form a single trend with 206Pb/204Pb always <18.39. Significantly, another group of young lavas fall right in-between the three trends: those from the new fissure lava north of Dyngjujökull, historical Veiðivötn fissure swarm lavas, and Holocene Dyngjuháls lavas. In sharp contrast, samples of unknown age from the ice-free part of the Bárðarbunga volcano display significant heterogeneity and overlap all of these data/trends. We propose that at least three mantle components contribute melts to the BVS, in different proportions in space and time. However, recent eruptions, regardless of location appear to be fed from the same or at least a more uniform magma source. Finally, we note that removal of ~2500 m. of glacial ice that overlaid the BVS during the last deglaciation, could have strongly influenced the melting regime in addition to magma delivery and/or storage under central Iceland - much more so than along the Northern rift zone (e.g., Theistareykir; Slater et al. 1998). Slater, L., Jull, M., McKenzie, D., Grönvold, K., 1998. Deglaciation effects on mantle melting beneath Iceland: Results from the northern volcanic zone. Earth Planet. Sci. Lett. 164, 151-164.

  8. Lead isotopes in iron and manganese oxide coatings and their use as an exploration guide for concealed mineralization

    USGS Publications Warehouse

    Gulson, B.L.; Church, S.E.; Mizon, K.J.; Meier, A.L.

    1992-01-01

    Lead isotopes from Fe and Mn oxides that coat stream pebbles from around the Mount Emmons porphyry molybdenum deposit in Colorado were studied to assess the feasibility of using Pb isotopes to detect concealed mineral deposits. The Fe/Mn oxide coatings were analyzed to determine their elemental concentrations using ICP-AES. The Pb isotope compositions of solutions from a selected suite of samples were measured, using both thermal ionization and ICP mass spectrometry, to compare results determined by the two analytical methods. Heavy mineral concentrates from the same sites were also analyzed to compare the Pb isotope compositions of the Fe/Mn coatings with those found in panned concentrates. The Fe/Mn and 206Pb/204Pb ratios of the oxide coatings are related to the lithology of the host rocks; Fe/Mn oxide coatings on pebbles of black shale have higher Fe/Mn values than do the coatings on either sandstone or igneous rocks. The shale host rocks have a more radiogenic signature (e.g. higher 206Pb/ 204Pb) than the sandstone or igneous host rocks. The Pb isotope data from sandstone and igneous hosts can detect concealed mineralized rock on both a regional and local scale, even though there are contributions from: (1) metals from the main-stage molybdenite ore deposit; (2) metals from the phyllic alteration zone which has a more radiogenic Pb isotope signature reflecting hydrothermal leaching of Pb from the Mancos Shale; (3) Pb-rich base metal veins with a highly variable Pb isotope signature; and (4) sedimentary country rocks which have a more radiogenic Pb isotope signature. An investigation of within-stream variation shows that the Pb isotope signature of the molybdenite ore zone is retained in the Fe/Mn oxide coatings and is not camouflaged by contributions from Pb-rich base-metal veins that crop out upstream. In another traverse, the Pb isotope data from Fe/Mn oxide coatings reflect a complex mixing of Pb from the molybdenite ore zone and its hornfels margin, Pb

  9. Linking serpentinite geochemistry with tectonic evolution at the subduction plate-interface: The Voltri Massif case study (Ligurian Western Alps, Italy)

    NASA Astrophysics Data System (ADS)

    Cannaò, E.; Scambelluri, M.; Agostini, S.; Tonarini, S.; Godard, M.

    2016-10-01

    Recent geochemical work shows that subduction-zone serpentinites are repositories for fluid-mobile elements absorbed during interaction with sediment-derived fluids. Unraveling the geochemical fingerprint of these rocks helps to define timing of tectonic accretion of sediments along the subduction interface and the role of serpentinite in element recycling to volcanic arcs. Here we present the trace element and isotopic composition (B-O-H, Sr, Pb) of high-pressure serpentinites from the Voltri Massif (Ligurian Western Alps, Italy), to discuss their role as incompatible element carriers and their contribution to recycling of sediment-derived components in subduction zones. The serpentinites presented here record metamorphic olivine growth during eclogite-facies metamorphism and show undeformed and mylonitic textures. Field relations show that undeformed rocks are enclosed in deformed ones and that no metasedimentary rocks are present nearby. Undeformed serpentinite has very high δ11BSRM951 (from +26‰ to +30‰), low Sr and Pb isotope ratios (87Sr/86Sr = 0.7053-0.7069; 206Pb/204Pb = 18.131-18.205) and low As and Sb contents (0.1 and 0.01 μg/g, respectively). Oxygen and hydrogen isotope compositions are +4.5‰ and -67‰, respectively. In contrast, mylonitic serpentinite shows lower δ11B (from +22‰ to +17‰), significant enrichment in radiogenic Sr and Pb isotopes (87Sr/86Sr up to 0.7105; 206Pb/204Pb up to 18.725), and enrichment in As and Sb (1.3 and 0.39 μg/g, respectively). δ18O of the mylonitic serpentinites reaches values of +5.9‰, whereas δD is comparable with that of undeformed rocks (approximately -70‰). In mylonitic serpentinites, the B and Sr isotopic values and the fluid-mobile element (FME) concentrations are near those for the Voltri metasedimentary rocks (calc- and mica-schists). Pb systematics also reveal influx of a crust-derived component. Our dataset shows that undeformed serpentinite still preserves an oceanic geochemical fingerprint

  10. Sources and Spatial Distribution of Metal Pollutants in Soils near the El Paso Smelter: A Forensic Study with Pb and Pu Isotopes.

    NASA Astrophysics Data System (ADS)

    Ketterer, Michael; Moan, Matthew; Gremillion, Paul

    2010-05-01

    Lead and copper smelting has been conducted at El Paso since the late 1800's, and as a result, environmental media near the smelter have become contaminated. A study has been conducted to investigate the sources and spatial distribution of metal pollutants (Pb, Cd, Zn, Hg, As, Cu) and concomitant tracers (Ag, In, Sb, Bi) in soils from the smelter vicinity. Sampled locations were residential and non-residential locations in El Paso (Texas, USA), Anapra (New Mexico, USA) and Ciudad Juarez (Chihuahua, Mexico). Lead isotope studies indicate that the soil Pb is derived from smelting, and is consistent with two-component mixing between lead ores from Chihuahua (northern Mexico) having 206Pb/204Pb of 18.6 - 18.8 and ores from the Hanover, New Mexico (USA) mining district with 206Pb/204Pb of ~ 17.6. The Pb isotope results also exclude other common anthropogenic Pb sources such as paint and gasoline emissions as being major contributors. Concentrations of Hg and Pb of up to 10 and 11,000 ppm were found in surface soils within 1 km of the smelter. The metal concentration results clearly indicate that soils near the smelter (< 5 km) exhibit much higher concentrations of smelter-related elements than do soils from control locations (> 10 km distant). A general trend of decreasing concentrations vs. distance from the smelter was also observed. However, the results indicate that metal concentrations vary widely even at a fixed distance from the smelter point source. This phenomenon results from a combination of natural and anthropogenic processes that disturb and re-distribute soils in the surface environment. The site conditions consist of a very arid environment with little vegetation cover that is frequently disturbed by high winds and severe episodic rainfall. To study these effects, we have investigated stratospheric fallout plutonium (239+240Pu) as a proxy measure of disturbed vs. undisturbed soil conditions. The premise is that 'undisturbed' locations will have high 239

  11. The influence of melt flux and crustal processing on Re-Os isotope systematics of ocean island basalts: Constraints from Galápagos

    NASA Astrophysics Data System (ADS)

    Gibson, S. A.; Dale, C. W.; Geist, D. J.; Day, J. A.; Brügmann, G.; Harpp, K. S.

    2016-09-01

    New rhenium-osmium data for high-MgO (>9 wt.%) basalts from the Galápagos Archipelago reveal a large variation in 187Os/188Os (0.1304 to 0.173), comparable with the range shown by primitive global ocean island basalts (OIBs). Basalts with the least radiogenic 187Os/188Os occur closest to the Galápagos plume stem: those in western Galápagos have low 187Os/188Os, moderate 87Sr/86Sr, 143Nd/144Nd, 206Pb/204Pb and high 3He/4He whereas basalts in the south also have low 187Os/188Os but more radiogenic 87Sr/86Sr, 143Nd/144Nd, 206Pb/204Pb and 3He/4He. Our new Os isotope data are consistent with the previously established spatial zonation of the common global isotopic mantle reservoir ;C; and ancient recycled oceanic crust in the mantle plume beneath western and southern parts of Galápagos, respectively. Galápagos basalts with the most radiogenic 187Os/188Os (up to 0.1875) typically have moderate MgO (7-9 wt.%) and low Os (<50 pg g-1) but have contrastingly unenriched Sr, Nd and Pb isotope signatures. We interpret this decoupling of chalcophile and lithophile isotopic systems as due to assimilation of young Pacific lower crust during crystal fractionation. Mixing models show the assimilated crust must have higher contents of Re and Os, and more radiogenic 187Os/188Os (0.32), than previously proposed for oceanic gabbros. We suggest the inferred, exceptionally-high radiogenic 187Os of the Pacific crust may be localised and due to sulfides precipitated from hydrothermal systems established at the Galápagos Spreading Centre. High 187Os/188Os Galápagos basalts are found where plume material is being dispersed laterally away from the plume stem to the adjacent spreading centre (i.e. in central and NE parts of the archipelago). The extent to which crustal processing influences 187Os/188Os appears to be primarily controlled by melt flux: as distance from the stem of the Galápagos plume increases, the melt flux decreases and crustal assimilation becomes proportionally

  12. Petrogenesis of Late Jurassic granodiorites from Gutian, Fujian Province, South China: Implications for multiple magma sources and origin of porphyry Cu-Mo mineralization

    NASA Astrophysics Data System (ADS)

    Li, Bin; Jiang, Shao-Yong; Lu, An-Huai; Lai, Jian-Qing; Zhao, Kui-Dong; Yang, Tao

    2016-11-01

    The Gutian porphyry Cu-Mo deposit is a newly proved porphyry copper deposit in the coastal South China associated with granodioritic porphyries. In this study, zircon U-Pb ages and Hf isotope data, as well as geochemical and Sr-Nd-Pb-Re-Os isotopic compositions, are reported for these intrusions and minerals. Both zircon U-Pb and molybdenite Re-Os dating suggest that the Gutian granodiorite porphyries and related mineralization formed at 160 Ma. The Gutian granodiorites show a low-Mg adakitic geochemical affinity, with relatively high K2O but low Cr and Ni contents. These rocks have initial (87Sr/86Sr)i ratios of 0.7085 to 0.7097, negative εNd(t) values (- 12.5 to - 7.8), (206Pb/204Pb)t ratios of 18.048 to 18.241, (207Pb/204Pb)t ratios of 15.609 to 15.628, and (208Pb/204Pb)t ratios of 38.494 to 38.667. Zircons from the granodiorites have negative εHf(t) values of - 15.7 to - 8.5, which are close to those of Cathaysia crust-derived melts. Geochemical and Sr-Nd-Pb-Hf isotopic compositions suggest that they may be derived from Late Jurassic thickened juvenile lower crust. These lower crustal magma sources may not only contain pre-Proterozoic basement rocks, but also involve Triassic and Middle-Late Jurassic arc magmas within the lower crust, which were likely derived from an enriched mantle source associated with paleo-Pacific Plate subduction from the Middle to Late Jurassic. The Gutian ore-related granodiorites represent a new example for significant contributions of ancient subduction melts and enriched mantle-derived sources for porphyry-type magmatism and Cu-Mo mineralization, which occurred in response to an arc regime during the Middle to Late Jurassic in South China. Supplemental Table S2. Hf isotopic compositions of zircons from the studied rocks from the Gutian porphyry deposit in South China. Supplemental Table S3. Statistics for zircon U-Pb ages and Hf isotope compositions from Gutian granodiorites in South China Supplemental Table S4. Major element (wt

  13. Origin of andesitic rocks: Geochemical constraints from Mesozoic volcanics in the Luzong basin, South China

    NASA Astrophysics Data System (ADS)

    Chen, Long; Zhao, Zi-Fu; Zheng, Yong-Fei

    2014-03-01

    A combined study of whole-rock major-trace elements and Sr-Nd-Pb-Hf isotopes as well as zircon U-Pb ages and Hf-O isotopes was carried out for Mesozoic andesitic-basaltic volcanics from the Luzong basin in the Middle-Lower Yangtze River Belt, South China. The results provide insights into the origin of mantle sources above fossil Andes-type oceanic subduction zone and thus into the petrogenesis of andesitic rocks on fossil and modern continental margins. These volcanics are primarily composed of basaltic trachyandesite and trachyandesite, with small amounts of trachybasalt and trachyte. They exhibit variable contents of SiO2 (48.66-63.43 wt.%), MgO (0.39-4.85 wt.%), Na2O (1.22-6.07 wt.%) and K2O (2.53-10.10 wt.%), with highly variable K2O/Na2O ratios from 0.45 to 7.39. They are characterized by arc-like trace element distribution patterns, with significant enrichment of LILE, Pb and LREE but depletion of HFSE. They exhibit relatively enriched Sr-Nd-Pb-Hf isotope compositions, with initial 87Sr/86Sr ratios of 0.7050 to 0.7066, negative ɛNd(t) values of - 8.0 to - 3.1, negative ɛHf(t) values of - 11.1 to - 1.1, and elevated 207Pb/204Pb and 208Pb/204Pb ratios at given 206Pb/204Pb ratios. Zircon U-Pb dating yields consistent ages of 127 ± 2 to 137 ± 1 Ma for magma emplacement through volcanic eruption. The zircon exhibits slightly high δ18O values of 5.3 to 7.6‰ and variable ɛHf(t) values of - 13.1 to 2.6. An integrated interpretation of all these geochemical data leads to the conclusion that the Luzong andesitic-basaltic volcanics were primarily derived from partial melting of fertile and enriched, mafic-ultramafic mantle sources that are similar to those of continental arc andesites. Such mantle sources are hypothesized to form by reaction of the mantle wedge peridotite not only with hydrous felsic melts derived from partial melting of seafloor sediment but also with aqueous fluid derived from metamorphic dehydration of altered oceanic basalt during

  14. Geology, isotope geochemistry and geochronology of the Jinshachang carbonate-hosted Pb-Zn deposit, southwest China

    NASA Astrophysics Data System (ADS)

    Zhou, Jia-Xi; Bai, Jun-Hao; Huang, Zhi-Long; Zhu, Dan; Yan, Zai-Fei; Lv, Zhi-Cheng

    2015-02-01

    The Jinshachang Pb-Zn deposit, an exceptionally radiogenic Pb-enriched sulfide deposit, hosted by dolostone of the Upper Sinian (Neoproterozoic) Dengying Formation and the Lower Cambrian Meishucun Formation, is located in the western Yangtze Block, about 300 km northeast of Kunming city in southwest China. Ore bodies in this deposit are dominated by strata-bound type and steeply dipping vein type. Primary ores in these two types are composed of sphalerite, galena, fluorite, barite and quartz with massive, banded, veined and disseminated structures. Twenty-seven ore bodies in the Jinshachang deposit host 4.6 million tons of sulfide ores at average grades of 4.07 wt.% Pb and 5.03 wt.% Zn. Quartz separates from the sulfide ores have δDH2O values ranging from -137‰ to -86.2‰ with an average of -114‰ (n = 7), lower than those of magmatic, metamorphic and meteoric water, suggesting a contribution of organic water. δ34SCDT values of ninety-one sulfide separates range from +1.1‰ to +13.4‰ with an average of +5.7‰, lower than those of evaporites (δ34SCDT = +15‰ to +35‰) in the Cambrian to Triassic sedimentary strata in NE Yunnan province. δ34SCDT values of eight barite separates range from +32‰ to +35‰ (average +34‰), within the range of evaporites. These data suggest that S2- in the hydrothermal fluids derived from evaporites by thermo-chemical sulfate reduction (TSR), whereas SO42- directly originated from the evaporites. Six sulfide separates have highly radiogenic 206Pb/204Pb ratios ranging from 20.74 to 21.18 (average 20.92), 207Pb/204Pb ratios ranging from 15.85 to 15.89 (average 15.87), and 208Pb/204Pb ratios ranging from 40.89 to 41.42 (average 41.16). The Pb isotopes of the sulfides plot above the upper crust Pb average evolution curve and overlap the Cambrian sedimentary rocks, but are different from the Sinian dolostone. This indicates a crustal source of Pb most likely derived from the Cambrian sedimentary rocks. The initial 87Sr/86Sr

  15. Lead and strontium isotope data for thermal waters of the regional geothermal system in the Twin Falls and Oakley areas, South-Central Idaho

    SciTech Connect

    Mariner, R.H.; Young, H.W.

    1995-12-31

    Thermal fluids obviously related to aquifers in both rhyolite and limestone occur in the Twin Falls-Oakley area of south-central Idaho. Limestone-related waters (high calcium with low silica and fluoride) occur in the middle and upper (southern) parts of the area. Rhyolite-related waters (low calcium but high in silica and fluoride) occur in the lower (northern) part of the area. The relation of thermal fluids in Paleozoic limestone to thermal fluids in Tertiary rhyolite is unknown. Thermal fluids from limestone are dilute, so water-rock reaction in rhyolite could obliterate chemical evidence of fluid residence in a limestone. However, isotopic tracers such as {sup 206}Pb/{sup 204}Pb, {sup 207}Pb/{sup 204}Pb, {sup 208}Pb/{sup 204}Pb, and {sup 87}Sr/{sup 86}Sr might preserve evidence of fluid residence in limestone. Systematic relations between these isotopes and dissolved constituents in the water demonstrate the presence of limestone beneath most if not all of the study area and that aquifers in the limestone and rhyolite are hydrologically connected.

  16. Rb-Sr whole-rock and mineral ages, K-Ar, 40Ar/39Ar, and U-Pb mineral ages, and strontium, lead, neodymium, and oxygen isotopic compositions for granitic rocks from the Salinian Composite Terrane, California:

    USGS Publications Warehouse

    Kistler, R.W.; Champion, D.E.

    2001-01-01

    This report summarizes new and published age and isotopic data for whole-rocks and minerals from granitic rocks in the Salinian composite terrane, California. Rubidium-strontium whole-rock ages of plutons are in two groups, Early Cretaceous (122 to 100 Ma) and Late Cretaceous (95 to 82 Ma). Early Cretaceous plutons occur in all granitic rock exposures from Bodega Head in the north to those from the Santa Lucia and Gabilan Ranges in the central part of the terrane. Late Cretaceous plutons have been identified in the Point Reyes Peninsula, the Santa Lucia and the Gabilan Ranges, and in the La Panza Range in the southern part of the terrane. Ranges of initial values of isotopic compositions are 87Sr/86Sr, 0.7046-0.7147, δ18O, +8.5 to +12.5 per mil, 206Pb/204Pb, 18.901-19.860, 207Pb/204Pb, 15.618-15.814, 208Pb/204Pb, 38.569- 39.493, and εNd, +0.9 to -8.6. The initial 87Sr/86Sr=0.706 isopleth is identified in the northern Gabilan Range and in the Ben Lomond area of the Santa Cruz Mountains, in Montara Mountain, in Bodega Head, and to the west of the Farallon Islands on the Cordell Bank. This isotopic boundary is offset about 95 miles (160km) by right-lateral displacements along the San Gregorio-Hosgri and San Andreas fault systems.

  17. Lead isotopic composition of paleozoic and late proterozoic marine carbonate rocks in the vicinity of Yucca Mountain, Nevada

    USGS Publications Warehouse

    Zartman, Robert E.; Kwak, Loretta M.

    1993-01-01

    Paleozoic and Late Proterozoic marine carbonate rocks (limestones, dolomites, and their metamorphic equivalents) cropping out in the vicinity of Yucca Mountain contain lead with an isotopic composition strongly suggesting them to be a major source of the lead observed at Trench 14 in the carbonate phase of carbonate-silica veins and nearby surficial calcrete deposits. Six whole-rock samples of marine carbonate rocks yield 206Pb/204Pb = 19.21-29.06, 207Pb/204Pb = 15.74-16.01, and 208Pb/204Pb = 37.90-39.25, and leachate and residue fractions of the rocks reveal additional isotopic heterogeneity within individual samples. Two samples of eolian dust also have isotopic compositions lying along a 'carbonate' to 'silicate' mixing trend that appears to arise entirely from pedogenic processes. The tendency for the marine carbonate rocks to evolve highly uranogenic, but no thorogenic, lead results in a distinctive isotopic composition that serves as a tracer in eolian dust and secondary carbonate minerals derived from the marine carbonate rocks.

  18. ICP-MS measurements of lead isotopic ratios in soils heavily contaminated by lead smelting: tracing the sources of pollution.

    PubMed

    Ettler, Vojtech; Mihaljevic, Martin; Komárek, Michael

    2004-01-01

    The Pb isotopic composition (206Pb/207Pb and 208Pb/206Pb) in smelter-impacted soils was measured using a quadrupole-based ICP-MS. Four forest/tilled soil profiles were sampled according to the distance from the lead smelter in Príbram (Czech Republic), prevailing wind direction, geological background and soil type. The results were compared with the Pb isotopic composition of bedrocks and waste materials from Pb metallurgy (smelting slags, air-pollution-control residues). The isotopic composition of soils confirms the predominant role of metallurgy on the general pollution in the area. The highly contaminated soils from the vicinity of the smelter contain up to 35,300 mg Pb kg(-1) and exhibit an isotopic composition close to that of car battery processing (206Pb/207Pb up to 1.177). A coupled concentration/isotopic study of soil profiles showed that the smelter-induced pollution had penetrated even to the mineral soil horizons, indicating an important vertical mobility of Pb contaminant within the soil profile. The calculated downward penetration rate of Pb in soils ranges from 0.3 to 0.36 cm year(-1).

  19. Petrology of the Guenfalabo ring-complex: An example of a complete series along the Cameroon Volcanic Line (CVL), Cameroon

    NASA Astrophysics Data System (ADS)

    Donald Ngonge, E.; Hollanda, Maria Helena B. M.; Nsifa, E. Nkonguin; Tchoua, Felix M.

    2014-08-01

    In the Guenfalabo ring-complex (GRC), two non-comagmatic rock suites have been identified as a result of two volcanic episodes: Suite 1 (68.8 ± 1.7 Ma by K/Ar on trachyte) of peralkaline trachytes and pantellerites cogenetic with alkaline syenites, granites and rhyolitic flows and tuffs; Suite 2 (62 ± 2 Ma by K/Ar on basalt), a bimodal and complete series of alkali olivine basalts and associated microgabbro dykes, diorites, syenites and granites, cross-cutting the former. Kaersutite in the trachytes of Suite 1 has mantle-derived signatures: TiO2 > 4%, MgO < 15%, FeO > 8%, Ti = 0.63 c.p.f.u. and Al = 2, characteristic of kaersutites of HP and HT origin: 13-23 kbar, 1100-1220 °C. The trachytes are probably products of FC of a basaltic parent that did not attain higher crustal levels. The Suite 1 rocks are enriched in Rb, K, Zr, Nb, LREE, alkalis, and (Ce/Yb)N = 7-15 probably due to some effect of metasomatism during the magma ascension. Fe-Ti enrichment is corroborated by the presence of ferropseudobrookite-ilmenite-ulvospinel in the syenites and ilmenite in the pantellerite. The Rb/Ba > 1 in the trachytes (2.44, 26.7), pantellerite (6.33), alkaline granites (0.63-1.8) and the 87Sr/86Sr in the alkaline granites (=0.74060) depict the role of AFC. The ankaramites of the Suite 2 rocks are olivine-phyric (25%), Fo85-88, have 50-52% clinopyroxene (salite), 5% plagioclase (An55-36) and 7% Fe-Ti oxides. Trace element modeling indicates an origin from a basaltic magma of about 25% PM of spinel lherzolite mixed with a magma from <1% PM of garnet lherzolite (3-4% garnet) in a proportion of 1:4. The cogenetic alkali basalts and the microgabbro-diorite-syenite-granite that constitute the Suite 2 rocks, with a Daly gap of 54% > SiO2 < 58%, result from this Early Cenozoic magmatic event. The basalts have: Zr = 225-253, Nb = 98-111, Y = 33-56, typical of FOZO, a HIMU-type OIB related magmas (Sr/Sri = 0.70202-0.7034; Nd/Nd = 0.51282-0.512545; 206Pb/204Pb = 19.13, 207Pb/204Pb = 15

  20. Chemical and isotopic provenance tracers in ancient copper and bronze artifacts: a geochemical database of copper mines

    NASA Astrophysics Data System (ADS)

    Giunti, I.; Artioli, G.; Giussani, B.; Marelli, M.; Recchia, S.; Angelini, I.; Baumgarten, B.; Omenetto, P.; Villa, I. M.

    2009-04-01

    The provenance of ore minerals used in prehistoric and historic times for copper smelting and extraction is one of the basic questions that archaeologists pose to modern analytical archaeometry [1]. To aid metal provenancing studies, a database of fully characterized Alpine copper mineralisations is being developed as the fundamental reference frame for metal extraction and diffusion in the past. In the early stages of the project, some of the most well known copper deposits in the Western Alps were selected and compared with very different minerogenetic deposits from the French Queyras (Saint Veran) and the Ligurian Apennines (Libiola, Monte Loreto). The fully characterized samples were then analysed by ICP-QMS (inductively coupled plasma-quadrupolar mass spectrometry). The abundances of about 60 minor and trace elements, including most transition metals and chalcophile elements, and the rare earths were measured in all samples. Furthermore, the feasibility of the routine reliable measurement of the 65Cu/63Cu isotope ratio [2] and its eventual use as a possible ore tracer was tested. Multicollector ICP-Mass Spectrometry was used to determine precise Pb isotopic ratios (206Pb/204Pb, 207Pb/204Pb, 208Pb/204Pb) and is being used for 65Cu/63Cu ratios as well. Advanced strategies based on multivariate analysis were then used to discriminate the ore mineral provenance. Data were treated with the chemometric software "The Unscrambler Version 9.5" (CAMO AS, Trondheim, Norway). Data pre-treatment, PCA [3] and PLS-DA [4,5] models were performed as implemented in the software. The availability of such unprecedented and complete amount of data of Alpine copper deposits also yields information relevant for the geochemical and minerogenetic intepretation of the deposits themselves. Application of PCA and PLS-DA to the geochemical and isotopic database proved to be a very powerful tool to discriminate the ore source areas with very little ambiguity. The applications to

  1. Pb isotope composition in lichens and aerosols from eastern Sicily: Insights into the regional impact of volcanoes on the environment

    SciTech Connect

    Monna, F. ); Aiuppa, A.; Varrica, D. ); Dongarra, G. CNR, Palermo . Istituto Geochimica dei Fluidi)

    1999-08-01

    A total of 25 lichen thalli of Parmelia conspersa (Ehrh), collected at Vulcano island and at Mt. Etna, during a one-year biogeochemical survey, were analyzed for Pb, br, Al, Sc,[sup 206]Pb/[sup 207]Pb, and [sup 208]Pb/[sup 206]Pb ratios. Lead isotope ratios were also measured on aerosol samples from urban areas and industrial sites of Sicily. The observed [sup 206]Pb/[sup 207]Pb range for urban and industrial aerosols matches the anthropogenic signature. Lichens instead, are closer to the compositional field of [sup 206]Pb rich geogenic sources. This natural input is more evident at Vulcano island than at Mt. Etna, where the anthropogenic activities are considerably more effective. On the basis of lead isotope data, Pb/Br ratios and calculated lead enrichment factors, a natural lead pollution from volcanoes is suggested. Volcanic lead contribution ranges from 10 to 30% at Mt. Etna to 10--80% at Vulcano island.

  2. Radiogenic Isotope Constraints on Plume - Lithosphere Interaction Beneath the Snake River Plain

    NASA Astrophysics Data System (ADS)

    Hanan, B. B.; Shervais, J. W.; Vetter, S. K.

    2006-12-01

    continental component. We tested this prediction with fifty basalts from along the SRP analyzed for major and trace contents and Pb, Sr, and Nd isotopes. The SRP Pb isotope results are consistent with mixing between an OIB-like plume component with 1% to 4% melt derived from about 2.8 Ga Wyoming-like enriched SCML and show that the relative amount of plume-like OIB component increases from 90-98% in the YP, to 98-99% in the central and western SRP. Basalts of the main phase CRBG (5), the central and eastern SRP, and the YP (6) show an overall decrease in 206Pb/204Pb and ^{143}Nd/^{144}Nd, variable 87Sr/86Sr, and increase in 207Pb/206Pb and ^{208}Pb/206Pb from west to east with distance from the Yellowstone caldera, with OIB-like values in Oregon and Washington toward values typical of the lower crust and lithosphere of the Wyoming Province along the SRP and YP. These results are consistent with a progressive decrease in craton thickness from east to west approaching the craton margin, a concomitant decrease in the age, and compositional heterogeneity in the lower crust and SCML beneath the SRP. (1) Camp and Ross, JGR 109, 2004; (2) Wooden and Mueller, EPSL 87, 1988; (3) Leeman et al., EPSL 75, 1985; (4) Wolf et al., GSA Abstracts with Programs 37, 2005; (5) Hooper, G3 1, 2000; (6) Doe, JGR 87, 1982.

  3. Genesis of the Touissit-Bou Beker Mississippi Valley-type district (Morocco-Algeria) and its relation to the Africa-Europe collision

    USGS Publications Warehouse

    Bouabdellah, Mohammed; Sangster, Donald F.; Leach, David L.; Brown, Alex C.; Johnson, Craig A.; Emsbo, Poul

    2012-01-01

    isotope ratios (206Pb/204Pb = 18.319–18.390; 207Pb/204Pb = 15.620–15.680; 208Pb/204Pb = 38.452–38.650) of sulfides are consistent with Pb being derived from the Visean rhyodacite and associated volcaniclastic rocks. The intimate link between faults and mineralization suggests the strong possibility of brine flow along both ENE-trending regional-scale faults and NW-SW-trending local-scale faults. The data suggest that MVT mineralization was emplaced during the late Neogene-Quaternary (i.e., ca. 15–0 Ma), possibly as a result of subsurface gravity-driven fluid flow in response to the collision between the African and Eurasian plates.

  4. Genesis of the Touissit-Bou Beker Mississippi valley-type district (Morocco-Algeria) and its relationship to the Africa-Europe collision

    USGS Publications Warehouse

    Bouabdellah, M.; Sangster, D.F.; Leach, D.L.; Brown, A.C.; Johnson, C.A.; Emsbo, P.

    2012-01-01

    isotope ratios ( 206Pb/ 204Pb = 18.319-18.390; 207Pb/ 204Pb = 15.620. 15.680; 208Pb/ 204Pb = 38.452-38.650) of sulfides are consistent with Pb being derived from the Visean rhyodacite and associated volcaniclastic rocks. The intimate link between faults and mineralization suggests the strong possibility of brine flow along both ENE-trending regional-scale faults and NW-SW-trending local-scale faults. The data suggest that MVT mineralization was emplaced during the late Neogene-Quaternary (i.e., ca. 15.0 Ma), possibly as a result of subsurface gravity-driven fluid flow in response to the collision between the African and Eurasian plates. ?? 2012 Society of Economic Geologists, Inc.

  5. Stratigraphy, geochemistry and tectonic significance of the Oligocene magmatic rocks of western Oaxaca, southern Mexico

    USGS Publications Warehouse

    Martiny, B.; Martinez-Serrano, R. G.; Moran-Zenteno, D. J.; MacIas-Romo, C.; Ayuso, R.A.

    2000-01-01

    the volcanic rocks, from 0.7042 to 0.7046 and 0 +2.6. The range of these isotope ratios and those reported for the basement rocks in this region suggest a relatively low degree of old crustal involvement for most of the studied rocks. The Pb isotopic compositions of the Tertiary magmatic rocks also show a narrow range [(206Pb/204Pb) = 18.67-18.75; (207Pb/204Pb) = 15.59-15.62; (208Pb/204Pb) = 38.44-38.59], suggesting a similar source region for the volcanic and plutonic rocks. Trace elements and isotopic compositions suggest a mantle source in the subcontinental lithosphere that has been enriched by a subduction component. General tectonic features in this region indicate a more active rate of transtensional deformation for the inland volcanic region than along the coastal margin during the main events of Oligocene magmatism. The lower degree of differentiation of the inland volcanic sequences, particularly the upper unit of the northern sector, compared to the plutons of the coastal margin, suggests that the differentiation of the Tertiary magmas in southern Mexico was controlled to a great extent by the characteristics of the different strain domains. (C) 2000 Elsevier Science B.V. All rights reserved.

  6. Petrogenesis of Tertiary continental intra-plate lavas between Siebengebirge and Westerwald, Germany: Constraints from trace element systematics and Nd, Sr and Pb isotopes

    NASA Astrophysics Data System (ADS)

    Schubert, S.; Jung, S.; Pfänder, J. A.; Hauff, F.; Garbe-Schönberg, D.

    2015-10-01

    New 39Ar/40Ar ages and major- and trace-element and radiogenic isotope data are presented for basanites and alkali basalts from the transition area between the Westerwald and Siebengebirge volcanic fields (Germany) that belongs to the Central European Volcanic Province (CEVP). The 39Ar/40Ar ages indicate ages of c. 24 and c. 5 Ma which are fully compatible with previous K/Ar ages indicating that the evolution of this volcanic field belongs to the Westerwald area (28-22 Ma and 5 Ma) rather than to the Siebengebirge area (26-23 Ma). Based on the occurrence of > 30 isolated volcanic plugs with a simple igneous history, this volcanic field can be viewed as a monogenetic volcanic field. Compositions of some basanites are primitive, whereas others and the alkali basalts show decreasing Cr and Ni contents and CaO/Al2O3 ratios. However, increasing TiO2, Al2O3 and incompatible elements (Sr, Zr, Y, Hf, Ta) concentrations with decreasing MgO indicating fractionation of mainly olivine with minor amounts of clinopyroxene and spinel can be noticed. Rare earth element systematics suggest that most of the alkaline rocks are generated by different degrees of melting (5%-10%) of a garnet-bearing peridotite containing some residual amphibole. Negative anomalies of Rb and K in primitive mantle-normalized diagrams and a lack of Ba/Rb fractionation suggest that amphibole was the major OH-bearing mineral phase in the mantle. The alkaline rocks have a restricted range in 87Sr/86Sr and 143Nd/144Nd ratios ranging from 0.7033 to 0.7044 and from 0.51275 to 0.51285, respectively. Lead isotope compositions (206Pb/204Pb: 19.21-19.65; 207Pb/204Pb: 15.62-15.67; 208Pb/204Pb: 39.10-39.46) of the alkaline rocks are within the range of most OIB in which the higher values approach the composition of the European Asthenospheric Reservoir (EAR). The correlation between Sr and Nd isotopes and trace element constraints (Ce/Pb; Nb/U) indicates that for some samples interaction with crustal rocks during

  7. Early-Cretaceous highly fractionated I-type granites from the northern Tengchong block, western Yunnan, SW China: Petrogenesis and tectonic implications

    NASA Astrophysics Data System (ADS)

    Zhu, Ren-Zhi; Lai, Shao-Cong; Qin, Jiang-Feng; Zhao, Shao-Wei

    2015-03-01

    Western Yunnan, an important constituent of the southeastern segment of the East Tethyan tectonic domain, lies along a transformed orientation from the NWW trending Himalayan-Tethyan segment to the northerly trending Southeast Asian segment. However, the geodynamical setting of the Early Cretaceous tectonothermal magmatism along the Bangong-Nujiang-Lushui-Luxi-Ruili belt as the Tethyan branch in western Yunnan (SW China) remains controversial. The Donghe granitoid, which is located between the Gaoligong and Tengliang belts in the northern Tengchong block, reveals its petrogenesis and its tectonics, both of which play a vital role in resolving previous disputes. Our zircon laser ablation inductively coupled plasma mass spectrometry U-Pb dating of granites from the Donghe batholith yields ages of 119.9 ± 0.9-130.6 ± 2.5 Ma. These granites display features typical of highly fractionated I-type granites: high SiO2 contents (>71 wt.%), high K contents (K2O = 3.88-5.66 wt.%), calc-alkaline character, slight peraluminosity (A/CNK = 1.02-1.16), and a highly differentiated index ranging from 83.6 to 95.6. In addition, as SiO2 contents increase, the rare earth element (REE) abundances, especially heavy REE abundances, and REE pattern slopes change gradually, but the negative Eu anomalies increase sharply, while the degree of enrichment in Rb, Th, U, and Pb and depletion in Ba, Nb, Sr, P, and Ti are enhanced. These features indicate that K-feldspar, ±plagioclase, ±biotite, ±amphibole, ±apatite, ±sphene/garnet, and ±Fe-Ti oxides such as ilmenite play the major role in the fractional crystallization process. The high initial 87Sr/86Sr (0.7067 and 0.7079) and negative εNd(t) values (-8.6 to -10.1), with T2DM ranging from 1.39 to 1.49 Ga, indicate that the sources were mainly derived from the mature ancient middle to lower crust and minor mantle-derived materials. The initial 206Pb/204Pb, 207Pb/204Pb, and 208Pb/204Pb ratios of 18.462-18.646, 15.717-15.735, and 38

  8. Tracing of ca 800 yr old mining activity in peat bog using Pb elemental concentrations and isotope compositions.

    NASA Astrophysics Data System (ADS)

    Baron, S.; Carignan, J.; Ploquin, A.

    2003-04-01

    Sixty sites of slags have been documented on the Mont-Lozère in southern France. The petrographic analysis shows that slags are metallurgical wastes (800 to 850 yr BP) which certainly result from smelting activity for lead and silver extraction (Ploquin et al., 2001). The aims of this study are: 1) to trace the source of Pb ores which supplied the smelting sites, by using the Pb isotopic composition of several surrounding Pb deposits, 2) to evaluate the actual pollution caused by these slags, by using elemental and isotopic compositions of soils, water and vegetation, and 3) to document the pollution history of the region, by using elemental and isotopic compositions of peat bog cores collected in the neighbourhood of the historical smelting sites. The lead isotopic composition of galena collected in most surrounding ores is very similar to that of different slag samples. On the other hand, the high precision of the results allowed us to select the mineralised areas which were probably the ore sources. The Pb isotopic composition of slags is even more homogeneous: 208/206 Pb: 2.092±0.002; 206/207 Pb: 1.179±0.001; 208/204 Pb: 38.663±0.025; 207/204 Pb: 15.665±0.006; 206/204 Pb: 18.476±0.023, and will allow source tracing in the environment. The "Narses Mortes" peat bog, around which two smelting sites have been reported, is strongly minerotrophic and contains 8 to 60% ash. A 1.40 m core have been retrieved and divided into 58 individual samples. Minerotrophic peat bog records both atmospheric deposition, soils leaching and the grounwater influence. The measured metal concentrations are normalised to Al contents of peat bog samples and the metal/Al ratios are compared to that of the Mont-Lozère granite: relative excess in metal concentrations are found in peat bog samples. An increasing excess of most metals (Pb, Zn, Cd...) was measured for surface samples, from 55 cm depth to the top of the core (23 cm depth). This profil might be attributed to atmospheric

  9. High Resolution, Pb Isotope Variability Within Historic Eruptions of the Cumbre Vieja Volcano, La Palma, Canary Islands

    NASA Astrophysics Data System (ADS)

    Locke, J. A.; Peterson, B. T.; Nelson, B. K.

    2005-12-01

    The range of time-scales over which ocean island basalt (OIB) magmatism taps different mantle heterogeneities is a fundamental dynamic of mantle plumes. The variability of long-lived radiogenic isotopes in OIB magmas erupted on time scales less than 100 years has been addressed primarily for Hawaiian magmas (e.g., Pietruszka et al., 2001). Similar data are relatively sparse for hot spots with low buoyancy fluxes. The Canary Islands have low eruption rates and have been historically active. The Cumbre Vieja volcano in southern La Palma, Canary Islands, has six, well-mapped, historic eruptions spanning the entire southern rift zone. We have investigated Pb isotope compositional variations expressed in magmas erupted in a series of events spanning 500 years (the 1480, 1585, 1677, 1712, 1949, and 1971 eruptions), and sampled in detail two of these events (the 1677 and 1712 eruptions) to document isotopic variability at the month to year time-scale as well as the 100-year time scale. Previous Pb isotope investigations of Cumbre Vieja did not reveal systematic variations (e.g., Marcantonio et al., 1995 and Ovchinnikova et al., 1995). With denser sampling (40 samples) and higher precision MC-ICP-MS analyses, we observe that radiogenic Pb isotope compositions over the 500 year eruptive history decrease systematically with time (206Pb/204Pb =19.669 -- 19.611, 207Pb/ 204Pb = 15.618 -- 15.602, 208Pb/204Pb = 39.530 -- 39.430). Detailed Pb isotope analyses of the 1677 and 1712 eruptions indicate isotopically homogeneous magmas within a single eruptive episode. However, samples from both the 1677 and 1712 eruptions display mineralogic evidence for magma mixing: 1677 samples include isotopically distinct gabbroic xenoliths, and both magmas have reversely- zoned clinopyroxene phenocrysts with corroded cores of Na-rich salite, and zoned overgrowths of Al-rich salite. With time, an increasing proportion of partial melt from a less radiogenic end-member within a heterogeneous plume

  10. Petrogenesis of basaltic volcanic rocks from the Pribilof Islands, Alaska, by melting of metasomatically enriched depleted lithosphere, crystallization differentiation, and magma mixing

    USGS Publications Warehouse

    Chang, J.M.; Feeley, T.C.; Deraps, M.R.

    2009-01-01

    The Pribilof Islands, Alaska, are located in the Bering Sea in a continental intraplate setting. In this study we examine the petrology and geochemistry of volcanic rocks from St. Paul (0??54-0??003 Ma) and St. George (2??8-1??4 Ma) Islands, the two largest Pribilof Islands. Rocks from St. George can be divided into three groups: group 1 is a high-MgO, low-SiO. 2 suite composed primarily of basanites; group 2 is a high-MgO, high-SiO 2 suite consisting predominantly of alkali basalts; group 3 is an intermediate- to low-MgO suite that includes plagioclase-phyric subalkali basalts and hawaiites. Major and trace element geochemistry suggests that groups 1 and 2 formed by small-degree partial melting of amphibole-bearing to amphibole-free garnet peridotite. Group 1 rocks were the earliest melts produced from the most hydrous parts of the mantle, as they show the strongest geochemical signature of amphibole in their source. The suite of rocks from St. Paul ranges from 14??4 to 4??2 wt % MgO at relatively constant SiO 2 contents (43??1-47??3 wt %). The most primitive St. Paul rocks are modeled as mixtures between magmas with compositions similar to groups 1 and 2 from St. George Island, which subsequently fractionated olivine, clinopyroxene, and spinel to form more evolved rocks. Plagioclase-phyric group 3 rocks from St. George are modeled as mixtures between an evolved melt similar to the evolved magmas on St. Paul and a fractionated group 2 end-member from St. George. Mantle potential temperatures estimated for primitive basanites and alkali basalts are ???1400??C and are similar to those of mid-ocean ridge basalts (MORB). Similarly, 87Sr/. 86Sr and 143Nd/. 144Nd values for all rocks are MORB-like, in the range of 0??702704-0??703035 and 0??513026-0??513109, respectively. 208Pb/. 204Pb vs 206Pb/. 204Pb values lie near the MORB end-member but show a linear trend towards HIMU (high time-integrated 238U/. 204Pb). Despite isotopic similarities to MORB, many of the major and

  11. Atmospheric trace metal inputs in the Misten bog (East Belgium): Special attention to sampling techniques and site-spatial variability.

    NASA Astrophysics Data System (ADS)

    Allan, Mohammed; Fagel, Nathalie; de Vleeschouwer, François; Mattielli, Nadine; Piotrowska, Natalia; Sikorski, Jarek; Sonke, Jeroen E.; Le Roux, Gaël.

    2010-05-01

    Peat bogs have a great potential to record anthropogenic inputs via their constituting mosses, because they draw their nutrients only from the atmosphere. These atmospheric inputs can be studied thanks to geochemical characteristics such as trace metal concentrations. Coupling lead isotopes to elemental geochemistry allows one to decipher between natural (erosion of rocks) and anthropogenic (pollution due to industrial development, vehicles...) inputs. The purpose of our work was to study the pollution history of trace metals in the region of Misten (Belgium) at a local and a regional level, and to place modern industrial pollution in this region in a wider historical perspective. Four peat cores (01W, 04W, 05W and 06W) were collected in 2008 in the Misten bog (Hautes-Fagnes plateau, E-Belgium) and studied for their trace metal and lead isotopic signatures. Analyses were accompanied by coupled 210Pb-14C age models in order to estimate the mercury and lead accumulation rates in each core and compare them to other European records. The Hg record was compared to the various anthropogenic sources as determined by Pb isotopes. The Hg concentration profiles resemble those of Pb, an element known to be immobile in peatlands. The correlation between these two metals suggests a predominant anthropogenic source of Hg (and Pb). In the W06 core, low and stable Hg accumulation rates (0.9-3.1 μg m-2 yr-1) are found in the lower layers (503-1823AD). High Hg accumulation rates are found in the surface and sub-surface layers (post-1823AD) and peak at 123.3 μg m-2 yr-1 (1969AD). In 01W, the lead enrichment factor (Pb E.F.) coupled with the continuous drop in 206Pb/204Pb, 207Pb/204Pb, 208Pb/204Pb isotopic ratios since 539 AD until 1973AD indicates the growing importance of the non-radiogenic Pb released from anthropogenic activities. The highest concentrations of Pb (613-662 µg g-1) have been found near the surface of the bog dated between 1902 and 1954AD. The Pb E.F. also

  12. Geochemical and isotopic (Nd-Pb-Sr-O) variations bearing on the genesis of volcanic rocks from Vesuvius, Italy

    USGS Publications Warehouse

    Ayuso, R.A.; de Vivo, B.; Rolandi, G.; Seal, R.R.; Paone, A.

    1998-01-01

    commonly seen in rocks generated at orogenic margins are absent in our samples. Sr isotopic compositions are known to be variable within some of the units, in agreement with our data (87Sr/86Sr ~ 0.70699 to 0.70803) and with contributions from several isotopic components. Isotopic compositions for ??18O (7.3 to 10.2%), Pb for mineral separates and whole rocks (206Pb/204Pb ~ 18.947 to 19.178, 207Pb/204/Pb ~ 15.617 to 15.769, 208Pb/204Pb ~38.915 to 39.345), and Nd (143Nd ~ 0.51228 to 0.51251) also show variability. Oxygen isotope data show that pumices have higher ??18O values than cogenetic lavas, and that ??18O values and SiO2 are correlated. Radiogenic and stable isotope data plot within range of isotopic compositions for the Roman comagmatic province. Fractional crystallization cannot account for the radiogenic isotopic compositions of the Vesuvius magmas. We favor instead the combined effects of heterogeneous magma sources, together with isotopic exchange near the roof of the magma chamber. We suggest that metasomatized continental mantle lithosphere is the principal source of the magmas. This kind of enriched mantle was melted and reactivated in an area of continental extension (incipient rift setting) without direct reliance on contemporaneous subduction processes but possibly with input from mantle sources that resemble those that produce ocean island basalts.

  13. Carslberg Ridge and Mid-Atlantic Ridge: Slow-spreading Apparent Analogs

    NASA Astrophysics Data System (ADS)

    Rona, P. A.; Murton, B. J.; Bostrom, K.; Widenfalk, L.; Melson, W. G.; O'Hearn, T.; Cronan, D. S.; Jenkins, W. J.

    2005-12-01

    fracture zone (9.93wt percent). Sr, Nd, and Pb isotopic compositions of Indian Ocean MORB are distinct from those of other oceans. They exhibit relatively higher 87Sr/86Sr, and lower 143Nd/144Nd, 207Pb/204Pb and 208Pb/204Pb for a given 206Pb/204Pb invoking mixing and regional-scale contamination of a depleted mantle with a variously designated enriched reservoir (EM1, EM2, DUPAL, etc.). 4) Hydrothermal activity: The MAR section encompasses a low-T hydrothermal field driven by the serpentinization at the Atlantis fracture zone (Lost City at 30N), and three high-temperature fields driven by magmatic heat in the axial valley (Broken Spur 29N, TAG 26N, and Snake Pit 23N). A 70 km-long, 1000 m-thick megaplume was detected in the water column up to 1400 m above the CR axial valley centered at 6.05N, 60.95E in August 2003, the first clear evidence of high-temperature hydrothermal activity on the CR. Further CR hydrothermal evidence includes relict sulfide chimneys at 58E; Mn-oxide coatings on basalts in the axial valley with Fe/Mn ratios at the boundary between hydrogenous and hydrothermal composition with thickness at two stations (1.67S, 67.77E; 5.35S, 68.62E) suggestive of hydrothermal input; and a d3He anomaly (166 per mil) in the water column at one of our stations in April 1979 (5.35S, 68.62E).

  14. Origin of the granites and related Sn and Pb-Zn polymetallic ore deposits in the Pengshan district, Jiangxi Province, South China: constraints from geochronology, geochemistry, mineral chemistry, and Sr-Nd-Hf-Pb-S isotopes

    NASA Astrophysics Data System (ADS)

    Xu, Bin; Jiang, Shao-Yong; Luo, Lan; Zhao, Kui-Dong; Ma, Liang

    2016-05-01

    relatively higher δ34S values of 22.7-28.7 ‰. Lead isotopes indicate that the granites have higher 206Pb/204Pb, 207Pb/204Pb, and 208Pb/204Pb ratios than the host Precambrian metasedimentary rocks, and the sulfide minerals from the orebodies fall in between them. Again, there is no difference for Pb isotopes between the Sn deposits (Huangjinwa, Zengjialong, Jianfengpo) and the Zhangshiba Pb-Zn deposit. The coincidence in S and Pb isotope compositions for Sn and Pb-Zn deposits suggests that similar sources for these mineralization, possibly derived from a mixed source of the granitic magmas and the Precambrian metasedimentary rocks. These data therefore favor of a magmatic-hydrothermal origin for both the Sn and Pb-Zn polymetallic mineralization in the Pengshan district.

  15. Geochemistry and argon thermochronology of the Variscan Sila Batholith, southern Italy: source rocks and magma evolution

    USGS Publications Warehouse

    Ayuso, R.A.; Messina, A.; de Vivo, B.; Russo, S.; Woodruff, L.G.; Sutter, J.F.; Belkin, H.E.

    1994-01-01

    The Sila batholith is the largest granitic massif in the Calabria-Peloritan Arc of southern Italy, consisting of syn to post-tectonic, calc-alkaline and metaluminous tonalite to granodiorite, and post-tectonic, peraluminous and strongly peraluminous, two-mica??cordierite??Al silicate granodiorite to leucomonzogranite. Mineral 40Ar/39Ar thermochronologic analyses document Variscan emplacement and cooling of the intrusives (293-289 Ma). SiO2 content in the granitic rocks ranges from ???57 to 77 wt%; cumulate gabbro enclaves have SiO2 as low as 42%. Variations in absolute abundances and ratios involving Hf, Ta, Th, Rb, and the REE, among others, identify genetically linked groups of granitic rocks in the batholith: (1) syn-tectonic biotite??amphibole-bearing tonalites to granodiorites, (2) post-tectonic two-mica??Al-silicate-bearing granodiorites to leucomonzogranites, and (3) post-tectonic biotite??hornblende tonalites to granodiorites. Chondrite-normalized REE patterns display variable values of Ce/Yb (up to ???300) and generally small negative Eu anomalies. Degree of REE fractionation depends on whether the intrusives are syn- or post-tectonic, and on their mineralogy. High and variable values of Rb/Y (0.40-4.5), Th/Sm (0.1-3.6), Th/Ta (0-70), Ba/Nb (1-150), and Ba/Ta (???50-2100), as well as low values of Nb/U (???2-28) and La/Th (???1-10) are consistent with a predominant and heterogeneous crustal contribution to the batholith. Whole rock ??18O ranges from ???+8.2 to +11.7???; the mafic cumulate enclaves have the lowest ??18O values and the two-mica granites have the highest values. ??18O values for biotite??honblende tonalitic and granodioritic rocks (9.1 to 10.8???) overlap the values of the mafic enclaves and two-mica granodiorites and leucogranites (10.7 to 11.7???). The initial Pb isotopic range of the granitic rocks (206Pb/204Pb ???18.17-18.45, 207Pb/204Pb ???15.58-15.77, 208Pb/204Pb ???38.20-38.76) also indicates the predominance of a crustal source

  16. Origin of the granites and related Sn and Pb-Zn polymetallic ore deposits in the Pengshan district, Jiangxi Province, South China: constraints from geochronology, geochemistry, mineral chemistry, and Sr-Nd-Hf-Pb-S isotopes

    NASA Astrophysics Data System (ADS)

    Xu, Bin; Jiang, Shao-Yong; Luo, Lan; Zhao, Kui-Dong; Ma, Liang

    2017-03-01

    relatively higher δ34S values of 22.7-28.7 ‰. Lead isotopes indicate that the granites have higher 206Pb/204Pb, 207Pb/204Pb, and 208Pb/204Pb ratios than the host Precambrian metasedimentary rocks, and the sulfide minerals from the orebodies fall in between them. Again, there is no difference for Pb isotopes between the Sn deposits (Huangjinwa, Zengjialong, Jianfengpo) and the Zhangshiba Pb-Zn deposit. The coincidence in S and Pb isotope compositions for Sn and Pb-Zn deposits suggests that similar sources for these mineralization, possibly derived from a mixed source of the granitic magmas and the Precambrian metasedimentary rocks. These data therefore favor of a magmatic-hydrothermal origin for both the Sn and Pb-Zn polymetallic mineralization in the Pengshan district.

  17. The Amazon-Laurentian connection as viewed from the Middle Proterozoic rocks in the central Andes, western Bolivia and northern Chile

    USGS Publications Warehouse

    Tosdal, R.M.

    1996-01-01

    Middle Proterozoic rocks underlying the Andes in western Bolivia, western Argentina, and northern Chile and Early Proterozoic rocks of the Arequipa massif in southern Peru?? from the Arequipa-Antofalla craton. These rocks are discontinuously exposed beneath Mesozoic and Cenozoic rocks, but abundant crystalline clasts in Tertiary sedimentary rocks in the western altiplano allow indirect samples of the craton. Near Berenguela, western Bolivia, the Oligocene and Miocene Mauri Formation contains boulders of granodiorite augen gneiss (1171??20 Ma and 1158??12 Ma; U-Pb zircon), quartzose gneiss and granofels that are inferred to have arkosic protoliths (1100 Ma source region; U-Pb zircon), quartzofeldspathic and mafic orthogneisses that have amphibolite- and granulite-facies metamorphic mineral assemblages (???1080 Ma metamorphism; U-Pb zircon), and undeformed granitic rocks of Phanerozoic(?) age. The Middle Proterozoic crystalline rocks from Berenguela and elsewhere in western Bolivia and from the Middle Proterozoic Bele??n Schist in northern Chile generally have present-day low 206Pb/204Pb ( 15.57), and elevated 208Pb/204Pb (37.2 to 50.7) indicative of high time-averaged Th/U values. The Middle Proterozoic rocks in general have higher presentday 206Pb/204Pb values than those of the Early Proterozoic rocks of the Arequipa massif (206Pb/204Pb between 16.1 and 17.1) but lower than rocks of the southern Arequipa-Antofalla craton (206Pb/204Pb> 18.5), a difference inferred to reflect Grenvillian granulite metamorphism. The Pb isotopic compositions for the various Proterozoic rocks lie on common Pb isotopic growth curves, implying that Pb incorporated in rocks composing the Arequipa-Antofalla craton was extracted from a similar evolving Pb isotopic reservoir. Evidently, the craton has been a coherent terrane since the Middle Proterozoic. Moreover, the Pb isotopic compositions for the Arequipa-Antofalla craton overlap those of the Amazon craton, thereby supporting a link

  18. Pb-Sr-Nd isotopes in surficial materials at the Pebble Porphyry Cu-Au-Mo Deposit, Southwestern Alaska: can the mineralizing fingerprint be detected through cover?

    USGS Publications Warehouse

    Ayuso, Robert A.; Kelley, Karen D.; Eppinger, Robert G.; Forni, Francesca

    2013-01-01

    The Cretaceous Pebble porphyry Cu-Au-Mo deposit is covered by tundra and glacigenic sediments. Pb-Sr-Nd measurements were done on sediments and soils to establish baseline conditions prior to the onset of mining operations and contribute to the development of exploration methods for concealed base metal deposits of this type. Pebble rocks have a moderate range for 206Pb/204Pb = 18.574 to 18.874, 207Pb/204Pb = 15.484 to 15.526, and 208,Pb/204Pb = 38.053 to 38.266. Mineralized granodiorite shows a modest spread in 87Sr/86Sr (0.704354–0.707621) and 143Nd/144Nd (0.512639–0.512750). Age-corrected (89 Ma) values for the granodiorite yield relatively unradiogenic Pb (e.g., 207Pb/204Pb 87Sr/86Sr, and positive values of ɛNd (1.00–4.52) that attest to a major contribution of mantle-derived source rocks. Pond sediments and soils have similar Pb isotope signatures and 87Sr/86Sr and 143Nd/144Nd values that resemble the mineralized granodiorites. Glacial events have obscured the recognition of isotope signatures of mineralized rocks in the sediments and soils. Baseline radiogenic isotope compositions, prior to the onset of mining operations, reflect natural erosion, transport and deposition of heterogeneous till sheets that included debris from barren rocks, mineralized granodiorite and sulfides from the Pebble deposit, and other country rocks that pre- and postdate the mineralization events. Isotopic variations suggest that natural weathering of the deposit is generally reflected in these surficial materials. The isotope data provide geochemical constraints to glimpse through the extensive cover and together with other geochemical observations provide a vector to concealed mineralized rocks genetically linked with the Pebble deposit.

  19. The Golden Ratio

    ERIC Educational Resources Information Center

    Hyde, Hartley

    2004-01-01

    The Golden Ratio is sometimes called the "Golden Section" or the "Divine Proportion", in which three points: A, B, and C, divide a line in this proportion if AC/AB = AB/BC. "Donald in Mathmagicland" includes a section about the Golden Ratio and the ratios within a five-pointed star or pentagram. This article presents two computing exercises that…

  20. Jurassic metabasic rocks in the Kızılırmak accretionary complex (Kargı region, Central Pontides, Northern Turkey)

    NASA Astrophysics Data System (ADS)

    Çelik, Ömer Faruk; Chiaradia, Massimo; Marzoli, Andrea; Özkan, Mutlu; Billor, Zeki; Topuz, Gültekin

    2016-03-01

    The Kızılırmak accretionary complex near Kargı is tectonically bounded by the Jurassic and Early Cretaceous metamorphic massives of the Central Pontides. It consists mainly of serpentinite, serpentinized peridotite, gabbro, basalt, metabasite and deep-marine sedimentary rocks. The metabasites in the Kızılırmak accretionary complex are tectonically located within a serpentinite, radiolarian chert, spilitized basalt, gabbro association and commonly display a steep contact with serpentinites. Amphiboles from metabasites yielded robust 40Ar/39Ar plateau ages ranging between 159.4 ± 0.4 Ma and 163.5 ± 0.8 Ma. These are interpreted as cooling ages of the metabasites. The metabasites have 87Sr/86Sr(i) between 0.7035 and 0.7044 and 206Pb/204Pb(i) ranging between 18.18 and 18.92. The gabbros have higher 87Sr/86Sr(i) between 0.7044 and 0.7060 and 206Pb/204Pb(i) ranging between 17.98 and 18.43. Three basalt samples display 87Sr/86Sr(i) between 0.7040 and 0.7059. Their 206Pb/204Pb(i) are unrealistically low (15.42 and 15.62), suggesting, most likely, Pb loss which results in over-corrected values for decay through time. Pb-Sr-Nd isotopic compositions for all samples consistently plot between the fields of MORB or the Depleted MORB Mantle reservoirs and enriched mantle reservoirs (EMII rather than EMI). All the samples (except one dolerite dike) have negative ɛNdDM(t = 160 Ma) values, suggesting derivation from a reservoir more enriched than the depleted mantle. The protoliths of metabasites correspond to diverse sources (N-MORB, E-MORB, OIB and IAT) based on whole rock major and trace element composition. An IAT-like protolith for the metabasites indicates that the İzmir-Ankara-Erzincan ocean domain was subducting and the tectonic regime was compressional during Late Jurassic and before. The protoliths of these rocks were metamorphosed during the subduction/accretion processes, as observed in the metamorphic rocks located along the Balkan, Northern Turkey and

  1. Isotope geochemistry of early Kilauea magmas from the submarine Hilina bench: The nature of the Hilina mantle component

    USGS Publications Warehouse

    Kimura, Jun-Ichi; Sisson, Thomas W.; Nakano, Natsuko; Coombs, Michelle L.; Lipman, Peter W.

    2006-01-01

    Submarine lavas recovered from the Hilina bench region, offshore Kilauea, Hawaii Island provide information on ancient Kilauea volcano and the geochemical components of the Hawaiian hotspot. Alkalic lavas, including nephelinite, basanite, hawaiite, and alkali basalt, dominate the earliest stage of Kilauea magmatism. Transitional basalt pillow lavas are an intermediate phase, preceding development of the voluminous tholeiitic subaerial shield and submarine Puna Ridge. Most alkalic through transitional lavas are quite uniform in Sr–Nd–Pb isotopes, supporting the interpretation that variable extent partial melting of a relatively homogeneous source was responsible for much of the geochemical diversity of early Kilauea magmas (Sisson et al., 2002). These samples are among the highest 206Pb/204Pb known from Hawaii and may represent melts from a distinct geochemical and isotopic end-member involved in the generation of most Hawaiian tholeiites. This end-member is similar to the postulated literature Kea component, but we propose that it should be renamed Hilina, to avoid confusion with the geographically defined Kea-trend volcanoes. Isotopic compositions of some shield-stage Kilauea tholeiites overlap the Hilina end-member but most deviate far into the interior of the isotopic field defined by magmas from other Hawaiian volcanoes, reflecting the introduction of melt contributions from both “Koolau” (high 87Sr/86Sr, low 206Pb/204Pb) and depleted (low 87Sr/86Sr, intermediate 206Pb/204Pb) source materials. This shift in isotopic character from nearly uniform, end-member, and alkalic, to diverse and tholeiitic corresponds with the major increase in Kilauea's magmatic productivity. Two popular geodynamic models can account for these relations: (1) The upwelling mantle source could be concentrically zoned in both chemical/isotopic composition, and in speed/extent of upwelling, with Hilina (and Loihi) components situated in the weakly ascending margins and the

  2. Isotopic and geochemical provinces of the western Indian Ocean Spreading Centers

    NASA Astrophysics Data System (ADS)

    Mahoney, J. J.; Natland, J. H.; White, W. M.; Poreda, R.; Bloomer, S. H.; Fisher, R. L.; Baxter, A. N.

    1989-04-01

    Basalt glasses from the Central Indian Ridge are distinct isotopically from mid-ocean ridge basalts (MORB) of the Indian Ocean triple junction and western few hundred kilometers of the Southeast Indian Ridge. In particular, very low 206Pb/204Pb and high 87Sr/86Sr signatures, which characterize the latter region, are absent over most of the Central Indian Ridge. In turn, lavas from the unusually deep eastern 1100-1500 km of the Southwest Indian Ridge are different chemically and isotopically from those of the above areas. A rather abrupt eastern boundary to Southwest Indian Ridge-type compositions occurs at or very near the geographic triple junction. This provinciality in western Indian Ocean ridge basalts partly mirrors fundamental regional differences in the underlying mantle but, at least between the eastern Southwest Indian Ridge and the western Southeast Indian Ridge and triple junction, also may reflect variations in extent and depth of melting in a vertically zoned upper mantle. A pronounced low ɛNd, high 206Pb/204Pb, high 87Sr/86Sr anomaly exists on the Central Indian Ridge at the Marie Celeste Fracture Zone and on the adjacent ridge segment to the south. Despite the great distance (>1100 km) of Réunion Island from the ridge, this zone appears to demark a region of mantle containing substantial Réunion hotspotlike material. Several old (35-60 m.y.) Deep Sea Drilling Project basalts which erupted on the ancestral Central Indian Ridge also record a significant Réunion hotspotlike influence, whereas a 46-m.y.-old sample that formed farther from the presumed locus of the hotspot possesses isotopic values identical to many present (non-Marie Celeste area) Central Indian Ridge MORB. The variably expressed and/or heterogeneous low 206Pb/204Pb material partly responsible for the isotopic distinctiveness of Indian Ocean ridge basalts may have entered into the Indian MORB mantle as a result of continental lithospheric remobilization preceding the breakup of

  3. Isotopic and trace element compositions of upper mantle and lower crustal xenoliths, Cima volcanic field, California: Implications for evolution of the subcontinental lithospheric mantle

    USGS Publications Warehouse

    Mukasa, S.B.; Wilshire, H.G.

    1997-01-01

    Ultramafic and mafic xenoliths from the Cima volcanic field, southern California, provide evidence of episodic modification of the upper mantle and underplating of the crust beneath a portion of the southern Basin and Range province. The upper mantle xenoliths include spinel peridotite and anhydrous and hydrous pyroxenite, some cut by igneous-textured pyroxenite-gabbro veins and dikes and some by veins of amphibole ?? plagioclase. Igneous-textured pyroxenites and gabbros like the dike rocks also occur abundantly as isolated xenoliths inferred to represent underplated crust. Mineral and whole rock trace element compositions among and within the different groups of xenoliths are highly variable, reflecting multiple processes that include magma-mantle wall rock reactions, episodic intrusion and it filtration of basaltic melts of varied sources into the mantle wall rock, and fractionation. Nd, Sr, and Pb isotopic compositions mostly of clinopyroxene and plagioclase mineral separates show distinct differences between mantle xenoliths (??Nd = -5.7 to +3.4; 87Sr/86Sr = 0.7051 - 0.7073; 206Pb/204Pb = 19.045 - 19.195) and the igneous-textured xenoliths (??Nd = +7.7 to +11.7; 87Sr/86Sr = 0.7027 - 0.7036 with one carbonate-affected outlier at 0.7054; and 206Pb/204Pb = 18.751 - 19.068), so that they cannot be related. The igneous-textured pyroxenites and gabbros are similar in their isotopic compositions to the host basaltic rocks, which have ??Nd of+5.1 to +9.3; 87Sr/86Sr of 0.7028 - 0.7050, and 206Pb/204Pb of 18.685 - 21.050. The igneous-textured pyroxenites and gabbros are therefore inferred to be related to the host rocks as earlier cogenetic intrusions in the mantle and in the lower crust. Two samples of peridotite, one modally metasomatized by amphibole and the other by plagioclase, have isotopic compositions intermediate between the igneous-textured xenoliths and the mantle rock, suggesting mixing, but also derivation of the metasomatizing magmas from two separate and

  4. Subalkaline andesite from Valu Fa Ridge, a back-arc spreading center in southern Lau Basin: petrogenesis, comparative chemistry, and tectonic implications

    USGS Publications Warehouse

    Vallier, T.L.; Jenner, G.A.; Frey, F.A.; Gill, J.B.; Davis, A.S.; Volpe, A.M.; Hawkins, J.W.; Morris, J.D.; Cawood, Peter A.; Morton, J.L.; Scholl, D. W.; Rautenschlein, M.; White, W.M.; Williams, Ross W.; Stevenson, A.J.; White, L.D.

    1991-01-01

    Tholeiitic andesite was dredged from two sites on Valu Fa Ridge (VFR), a back-arc spreading center in Lau Basin. Valu Fa Ridge, at least 200 km long, is located 40-50 km west of the active Tofua Volcanic Arc (TVA) axis and lies about 150 km above the subducted oceanic plate. One or more magma chambers, traced discontinuously for about 100 km along the ridge axis, lie 3-4 km beneath the ridge. The mostly aphyric and glassy lavas had high volatile contents, as shown by the abundance and large sizes of vesicles. An extensive fractionation history is inferred from the high SiO2 contents and FeO* MgO ratios. Chemical data show that the VFR lavas have both volcanic arc and back-arc basin affinities. The volcanic arc characteristics are: (1) relatively high abundances of most alkali and alkaline earth elements; (2) low abundances of high field strength elements Nb and Ta; (3) high U/Th ratios; (4) similar radiogenic isotope ratios in VFR and TVA lavas, in particular the enrichment of 87Sr 86Sr relative to 206Pb 204Pb; (5) high 238U 230Th, 230Th 232Th, and 226Ra 230Th activity ratios; and (6) high ratios of Rb/Cs, Ba/Nb, and Ba/La. Other chemical characteristics suggest that the VFR lavas are related to MORB-type back-arc basin lavas. For example, VFR lavas have (1) lower 87Sr 86Sr ratios and higher 143Nd 144Nd ratios than most lavas from the TVA, except samples from Ata Island, and are similar to many Lau Basin lavas; (2) lower Sr/REE, Rb/Zr, and Ba/Zr ratios than in arc lavas; and (3) higher Ti, Fe, and V, and higher Ti/V ratios than arc lavas generally and TVA lavas specifically. Most characteristics of VFR lavas can be explained by mixing depleted mantle with either small amounts of sediment and fluids from the subducting slab and/or an older fragment of volcanic arc lithosphere. The eruption of subalkaline andesite with some arc affinities along a back-arc spreading ridge is not unique. Collision of the Louisville and Tonga ridges probably activated back-arc extension

  5. Trace element and isotopic geochemistry of Cretaceous magmatism in NE Asia: Spatial zonation, temporal evolution, and tectonic controls

    NASA Astrophysics Data System (ADS)

    Tikhomirov, Petr L.; Kalinina, Elena A.; Moriguti, Takuya; Makishima, Akio; Kobayashi, Katsura; Nakamura, Eizo

    2016-11-01

    Results of a comprehensive geochemical study (major and trace elements, and isotopes of Sr, Nd, Pb, Hf) of Cretaceous volcanic rocks from the Chukotka area in northeastern Russia are presented. Synthesis of available geological and geochronological data suggests diachronous onset of activity of the Okhotsk-Chukotka volcanic belt (OCVB), the largest magmatic province in the region. The OCVB consists of ca. 106 km3 of volcanic rocks. At 106-105 Ma, subduction-related magmatism initiated in the southern and central segments of the OCVB. In the Central and Northern Chukotka areas, where the northern OCVB is exposed, onset of arc magmatism occurred ca. 10 m.y. after extension-related magmatism of the Chaun igneous province at 109-104 Ma. Mafic rocks from the OCVB yield (87Sr/86Sr)80 Ma of 0.7033 to 0.7047, εNd80 Ma of 0.0 to 7.10, εHf80 Ma of 4.12 to 12.88, (206Pb/204Pb)80 Ma of 18.11 to 18.42, and (208Pb/204Pb)80 Ma of 37.96 to 38.21. Volcanic rocks from the Chaun province, as well as OCVB rocks from Northern Chukotka, originate from a relatively enriched source and have (87Sr/86Sr)80 Ma of 0.7088 to 0.7100, εNd80 Ma of - 5.81 to - 3.42, εHf80 Ma of - 3.40 to - 0.25, (206Pb/204Pb)80 Ma of 18.69 to 18.90, and (208Pb/204Pb)80 Ma of 38.65 to 38.86. No definitive across-arc elemental or isotopic zonation of the OCVB has been revealed, probably because of wide-scale crustal melting and subsequent contamination of mantle-derived melts. However, there is a clear along-arc isotopic zonation. In our interpretation, this results from heterogeneity of the subcontinental lithospheric mantle, which likely was a major contributor to the magma source. The similar isotopic signatures of silicic (dominantly crust-derived) and mafic (mantle-derived) volcanic rocks in each OCVB segment imply that remelting of juvenile mafic underplated material was the main process responsible for the crust-derived magma generation. These data from the major Cretaceous magmatic provinces of northeast

  6. Upper and lower crust recycling in the source of CAMP basaltic dykes from southeastern North America

    NASA Astrophysics Data System (ADS)

    Callegaro, Sara; Marzoli, Andrea; Bertrand, Hervé; Chiaradia, Massimo; Reisberg, Laurie; Meyzen, Christine; Bellieni, Giuliano; Weems, Robert E.; Merle, Renaud

    2013-08-01

    The densest dykes swarm of the Central Atlantic magmatic province (CAMP) occur in southeastern North America (SENA) and were intruded between 202 and 195 Ma during Pangea break-up. New combined geochemical data (major and trace elements, Sr-Nd-Pb-Os isotopes) constrain the mantle source of these magmatic bodies and their evolution path. While Sr-Nd isotopic compositions for SENA rocks (87Sr/86Sr200Ma 0.70438-0.70880 and 143Nd/144Nd200Ma 0.51251-0.51204) fall within the low-Ti CAMP field, Pb-Pb isotopes (206Pb/204Pb200Ma 17.46-18.85, 207Pb/204Pb200Ma 15.54-15.65, 208Pb/204Pb200Ma 37.47-38.76) are peculiar to this area of the CAMP and cover a considerable span of compositions, especially in 206Pb/204Pb200Ma. Given the generally unradiogenic Os isotopic compositions (187Os/188Os200Ma 0.127-0.144) observed and the lack of correlation between these and other geochemical markers, crustal contamination during the evolution of SENA dykes must have been limited (less than 10%). Thus the isotopic variation is interpreted to reside primarily within the mantle source. These observations, coupled with typical continental signatures in trace elements (positive anomaly in Pb and negative anomalies in Ti and Nb), require another means of conveying a continental flavor to these magmas, which is here hypothesized to be the shallow recycling within the upper mantle of subducted lower and upper crustal materials. Pseudo-ternary mixing models show that a maximum of 10% recycled crust is enough to explain their trace element patterns as well as their isotopic heterogeneity. Looking at the larger picture of the origin of the CAMP, the thermal contribution of a mantle plume cannot be ruled out due to the relatively high mantle potential temperatures (1430-1480 °C) calculated for high-Fo SENA olivines. Nevertheless, our results suggest that the chemical involvement of a mantle plume is negligible (less than 5%) if either a C- or an EM-flavored plume is considered. Rather, the possibility

  7. Lead isotopic evidence for mixed sources of Proterozoic granites and pegmatites, Black Hills, South Dakota, USA

    NASA Astrophysics Data System (ADS)

    Krogstad, Eirik J.; Walker, Richard J.; Nabelek, Peter I.; Russ-Nabelek, Carol

    1993-10-01

    The lead isotopic compositions of K-feldspars separated from the ca. 1700 Ma Harney Peak Granite complex and spatially associated granitic pegmatites indicate that these rocks were derived from at least two sources. It has been reported previously that the core of the Harney Peak Granite complex is dominated by relatively lower/ gd18O (avg. 11.5 %.) granites, whereas higher / gd18O (avg. 13.2%.) granites occur around the periphery of the complex. The higher δ 18O granites and one simple pegmatite have low values of 207Pb /204Pb for their 206Pb /204Pb Thus, they likely were derived from a source with a short crustal residence time. This source may have been the pelitic schists into which the Harney Peak Granite complex and pegmatites were intruded. Feldspars from granites with lower / gd18O values have significantly higher 207Pb /204Pb for their 206Pb /204Pb . The data define a linear array with a slope equivalent to an age of ca. 2.6 Ga with t 2 defined to be 1.7 Ga. Such a slope could represent a mixing array or a secondary isochron for the source. These low δ18O granites could have been derived from a source with a high U/ Pb and with a crustal residence beginning before the Proterozoic. The source (s) of these granites may have been a sediment derived from late Archean continental crust. The highly evolved Tin Mountain pegmatite has lead isotopic systematics intermediate between those of the two granite groups, suggesting either a mixed source or contamination. Two late Archean granites, the Little Elk Granite and the Bear Mountain Granite, had precursors with high U/Pb and low Th/U histories. The Th/U history of the Bear Mountain Granite is too low for this rock to have been an important component of the source of the Proterozoic granites. However, crustal rocks with lead isotopic compositions similar to those of the Little Elk Granite were an important source of lead for some of the Proterozoic granitic rocks.

  8. Influences upon the lead isotopic composition of organic and mineral horizons in soil profiles from the National Soil Inventory of Scotland (2007-09).

    PubMed

    Farmer, John G; Graham, Margaret C; Eades, Lorna J; Lilly, Allan; Bacon, Jeffrey R

    2016-02-15

    Some 644 individual soil horizons from 169 sites in Scotland were analyzed for Pb concentration and isotopic composition. There were three scenarios: (i) 36 sites where both top and bottom (i.e. lowest sampled) soil horizons were classified as organic in nature, (ii) 67 with an organic top but mineral bottom soil horizon, and (iii) 66 where both top and bottom soil horizons were mineral. Lead concentrations were greater in the top horizon relative to the bottom horizon in all but a few cases. The top horizon (206)Pb/(207)Pb ratio was lesser (outside analytical error) than the corresponding bottom horizon (206)Pb/(207)Pb ratio at (i) 64%, (ii) 94% and (iii) 73% of sites, and greater at only (i) 8%, (ii) 3% and (iii) 8% of sites. A plot of (208)Pb/(207)Pb vs. (208)Pb/(206)Pb ratios showed that the Pb in organic top (i, ii) and bottom (i) horizons was consistent with atmospherically deposited Pb of anthropogenic origin. The (206)Pb/(207)Pb ratio of the organic top horizon in (ii) was unrelated to the (206)Pb/(207)Pb ratio of the mineral bottom horizon as demonstrated by the geographical variation in the negative shift in the ratio, a result of differences in the mineral horizon values arising from the greater influence of radiogenic Pb in the north. In (iii), the lesser values of the (206)Pb/(207)Pb ratio for the mineral top horizon relative to the mineral bottom horizon were consistent with the presence of anthropogenic Pb, in addition to indigenous Pb, in the former. Mean anthropogenic Pb inventories of 1.5 and 4.5 g m(-2) were obtained for the northern and southern halves of Scotland, respectively, consistent with long-range atmospheric transport of anthropogenic Pb (mean (206)Pb/(207)Pb ratio~1.16). For cultivated agricultural soils (Ap), this corresponded to about half of the total Pb inventory in the top 30 cm of the soil column.

  9. Offer/Acceptance Ratio.

    ERIC Educational Resources Information Center

    Collins, Mimi

    1997-01-01

    Explores how human resource professionals, with above average offer/acceptance ratios, streamline their recruitment efforts. Profiles company strategies with internships, internal promotion, cooperative education programs, and how to get candidates to accept offers. Also discusses how to use the offer/acceptance ratio as a measure of program…

  10. Pliocene to late Pleistocene magmatism in the Aurora Volcanic Field, Nevada and California, USA

    NASA Astrophysics Data System (ADS)

    Kingdon, S.; Cousens, B.; John, D. A.; du Bray, E. A.

    2013-12-01

    The 3.9- 0.1 Ma Aurora Volcanic Field (AVF) covers 325 km2 east and southeast of the Bodie Hills, north of Mono Lake, California, USA. The AVF is located immediately northwest of the Long Valley magmatic system and adjacent and overlapping the Miocene Bodie Hills Volcanic Field (BHVF). Rock types range from trachybasalt to trachydacite, and high-silica rhyolite. The trachybasalts to trachydacites are weakly to moderately porphyritic (1-30%) with variable phenocryst assemblages that are some combination of plagioclase, hornblende, clinopyroxene, and lesser orthopyroxene, olivine, and/or biotite. Microphenocrysts are dominated by plagioclase, and include opaque oxides, clinopyroxene, and apatite. These rocks are weakly to strongly devitrified. The high-silica rhyolites are sparsely porphyritic with trace to 10% phenocrysts of quartz, sanidine, plagioclase, biotite, (+/- hornblende), accessory opaque oxide minerals, titanite, allanite, (+/-apatite, zircon), and have glassy groundmasses. Rocks in the AVF are less strongly porphyritic than those of BHVF. Plagioclase phenocrysts are often oscillatory zoned and many have sieve texture. Amphiboles have distinct black opaque rims. Xenocrystic quartz and plagioclase are rare. AVF lavas have bimodal SiO2 compositions, ranging from 49 to 78 wt%, with a gap between 65 and 75 wt%. They are high-K calc-alkaline to shoshonitic in composition, and are metaluminous to weakly peraluminous. They are enriched in rare earth elements (REE), especially light REEs, compared to the Miocene BHVF rocks. Primordial mantle-normalized incompatible element patterns show arc- or subduction-related signatures, with enrichment in Ba and Pb, and depletion in Nb and Ta. Enrichment in K and Sr and depletion in Ti are less pronounced than in the BHVF rocks. There is no correlation between lead isotope ratios and silica (initial 206Pb/204Pb ratios range from 18.974 to 19.151). Neodymium isotope ratios show a moderate negative correlation with silica

  11. Discrimination of the Cigarettes Geographical Origin by DRC-ICP-MS Measurements of Pb Isotope Compositions

    NASA Astrophysics Data System (ADS)

    Guo, W.; Hu, S.; Jin, L.

    2014-12-01

    Trace Pb are taken up with the same isotopic ratios as is present in the source soil, and the isotopic composition of Pb could used to reflect these sources and provide powerful indicators of the geographic origin of agriculture products derived from vegetative matter. We developed a simple and high throughput method, which based on DRC-ICP-MS for determination of Pb isotope ratios for discriminating the geographic origin of cigarettes. After acid digestion procedure, the cigarette digested solutions were directly analyzed by ICP-QMS with a DRC pressurized by the non-reactive gas Ne. In the DRC, Ne molecules collision with Pb ions and improves Pb isotope ratios precision 3-fold, which may be due to the collisional dampling smoothes out the ion beam fluctuations. Under the optimum DRC rejection parameter Q (RPq = 0.45), the main matrix components (K, Na, Ca, Mg, Al, Fe etc.) originating from cigarettes were filtered out. Mass discrimination of 208Pb/206Pb ratio in Ne DRC mode increased 0.3% compared to the standard mode, the mass bias due to the in-cell Ne gas collision can be accurately corrected by NIST 981 Pb isotope standard. This method was verified by a tobacco reference material CTV-OTL-2. Results of 208Pb/206Pb and 207Pb/206Pb were 2.0848 ± 0.0028 (2δ) and 0.8452 ± 0.0011 (2δ) for CTA-VTL-2, which were agreed with the literature values (208Pb/206Pb = 2.0884 ± 0.0090 and 207Pb/206Pb = 0.8442 ± 0.0032). The precision of Pb isotope ratios (208Pb/206Pb and 207Pb/206Pb) for the cigarette samples are ranged from 0.01 to 0.08% (N = 5). It has sufficient precision to discriminate 91 different brand cigarettes originated from four different geographic regions (Shown in Fig).

  12. High Aspect Ratio Wrinkles

    NASA Astrophysics Data System (ADS)

    Chen, Yu-Cheng; Crosby, Alfred

    2015-03-01

    Buckling-induced surface undulations are widely found in living creatures, for instance, gut villi and the surface of flower petal cells. These undulations provide unique functionalities with their extremely high aspect ratios. For the synthetic systems, sinusoidal wrinkles that are induced by buckling a thin film attached on a soft substrate have been proposed to many applications. However, the impact of the synthetic wrinkles have been restricted by limited aspect ratios, ranging from 0 to 0.35. Within this range, wrinkle aspect ratio is known to increase with increasing compressive strain until a critical strain is reached, at which point wrinkles transition to localizations, such as folds or period doublings. Inspired by the living creatures, we propose that wrinkles can be stabilized in high aspect ratio by manipulating the strain energy in the substrate. We experimentally demonstrate this idea by forming a secondary crosslinking network in the wrinkled surface and successfully achieve aspect ratio as large as 0.8. This work not only provides insights for the mechanism of high aspect ratio structures seen in living creatures, but also demonstrates significant promise for future wrinkle-based applications.

  13. Lithium Isotope Systematics in Azores Basalts

    NASA Astrophysics Data System (ADS)

    Yu, H.; Widom, E.; Qiu, L.; Rudnick, R.; Gelinas, A.; Franca, Z.

    2009-05-01

    Basalts from the Azores archipelago and MORB from the nearby Azores Platform exhibit extreme chemical and isotopic variations attributed to the influence of a heterogeneous mantle plume, with compositions ranging from depleted mantle (DMM) to strong HIMU, EMI and EMII signatures. In order to assess the utility of Li isotopes as a mantle source tracer and to better constrain the origin of heterogeneous mantle beneath the Azores, we have analyzed Li isotopes in a suite of young, fresh, MgO-rich basalts from São Miguel and three Central Group islands including Pico, Faial and Terceira. Despite large variations in radiogenic isotope signatures (e.g. 206Pb/204Pb = 19.3 to 20.1), δ7Li varies only slightly (3.1-4.7‰), and is within the range for global and North Atlantic MORB [1, 2]. More extreme δ7Li values such as those reported previously for some EMII, EMI and HIMU ocean island basalts (-17‰ to +10‰; [3-5]) were not observed. Nevertheless, basalts from the Central Group islands with EMI-type signatures are, on average, slightly heavier in δ7Li than the São Miguel samples, and they exhibit positive correlations with 87Sr/86Sr and negative correlations with 206Pb/204Pb, Nd, and Hf isotopes. Li isotopes do not correlate with indices of fractionation such as MgO, suggesting that the δ7Li correlations with radiogenic isotopes may represent subtle variations in mantle source signatures. Positive and negative correlations of δ7Li with 87Sr/86Sr and 206Pb/204Pb, respectively, and relatively unradiogenic Os (187Os/188Os = 0.1244-0.1269), may reflect old, slab-fluid metasomatized mantle beneath the Central Group islands. In contrast, δ7Li signatures in the São Miguel basalts do not correlate with radiogenic isotopes. Rather, δ7Li is essentially constant despite extremely high 87Sr/86Sr and 206Pb/204Pb and low ΔɛHf signatures that have been attributed to 3.5 Ga recycled E-MORB or evolved oceanic crust [6; 7]. This suggests either that the São Miguel source

  14. Development of procedure for measurement of Pb isotope ratios in seawater by application of seaFAST sample pre-treatment system and Sector Field Inductively Coupled Plasma Mass Spectrometry

    NASA Astrophysics Data System (ADS)

    Vassileva, Emilia; Wysocka, Irena

    2016-12-01

    Anthropogenic Pb in the oceans, derived from high-temperature industrial processes, fuel combustion and incineration can have an isotopic signature distinct from naturally occurring Pb, supplied by rock weathering. To identify the different pollution sources accurately and to quantify their relative contributions, Pb isotope ratios are widely used. Due to the high salt content (approximately 3.5% of total dissolved solids) and very low levels of Pb (typically from 1 to 100 ng L- 1) in seawater the determination of Pb isotope ratios requires preliminary matrix separation and analyte preconcentration. An analytical protocol for the measurements of Pb isotope ratios in seawater combining seaFAST sample pre-treatment system and Sector Field Inductively Coupled Plasma Mass Spectrometry (SF ICP-MS) was developed. The application of seaFAST system was advantageous, because of its completely closed working cycle and small volumes of chemicals introduced in pre-treatment step, resulting in very low detection limits and procedural blanks. The preconcentration/matrix separation step was also of crucial importance for minimizing the isobaric and matrix interferences, coming from the seawater. In order to differentiate between anthropogenic and natural Pb sources, particular attention was paid to the determination of 204Pb isotope because of its implication in some geological interpretations. The validation of the analytical procedure was effectuated according to the recommendations of the ISO/IEC 17025 standard. The method was validated by processing the common Pb isotope reference material NIST SRM 981. All major sources of uncertainty were identified and propagated together following the ISO/GUM guidelines. The estimation of the total uncertainty associated to each measurement result was fundamental tool for sorting the main sources of possible biases. The developed analytical procedure was applied to the coastal and open seawater samples, collected in different regions of

  15. Geochemical trends across an arc-continent collision zone: magma sources and slab-wedge transfer processes below the Pantar Strait volcanoes, Indonesia

    NASA Astrophysics Data System (ADS)

    Elburg, Marlina A.; van Bergen, Manfred; Hoogewerff, Jurian; Foden, John; Vroon, Pieter; Zulkarnain, Iskandar; Nasution, Asnawir

    2002-09-01

    Four volcanoes in the Pantar Strait, the westernmost part of the extinct sector of the east Sunda arc, show remarkable across-arc variation in elemental abundances (K 2O: 1.2 to 4.3%), trace element ratios (Pb/Ce: 0.4 to 0.18; Ce/Yb: 20 to 55) and isotope ratios ( 143Nd/ 144Nd: 0.51263 to 0.51245; 87Sr/ 86Sr: 0.7053 to 0.7068; 206Pb/ 204Pb: 19.29 to 19.15). Pb isotopes are decoupled from Sr and Nd isotopes, with the frontal volcanoes showing the higher Nd and Pb and lower Sr isotopic ratios. The isotopic and trace element ratios of the volcanic samples are best explained by modification of a MORB-type source (with Indian Ocean island basalt-type Pb isotopic characteristics) by a fluid and a partial melt of subducted continental material (SCM). The frontal volcano contains the highest proportion of the fluid component, with a small contribution of partial melt. The source of the rear-arc volcano is strongly influenced by a partial melt of SCM that had undergone a previous dehydration event, by which it lost most of its fluid-mobile elements such as Pb. The SCM partial melt was in equilibrium with both rutile and garnet, whereas mantle melting took place in the presence of residual mica. The relatively large across-arc increase in incompatible elements can be explained by a combination of increasing addition of SCM partial melt, changing mantle wedge fertility and smaller degrees of partial melting toward the rear of the arc. Comparison with a more westerly across-arc transect shows that the relatively low 143Nd/ 144Nd ratios of the frontal volcano, and the decoupling of Pb from Sr and Nd isotopes are unique to the Pantar Strait volcanoes. This is likely to reflect magma generation in a collisional environment, where the leading edge of the Australian continent, rather than subducted sediment, contributes to the magma source.

  16. Temporal magma source changes at Gaua volcano, Vanuatu island arc

    NASA Astrophysics Data System (ADS)

    Beaumais, Aurélien; Bertrand, Hervé; Chazot, Gilles; Dosso, Laure; Robin, Claude

    2016-08-01

    Gaua Island (also called Santa Maria), from the central part of the Vanuatu arc, consists of a large volcano marked by a caldera that hosts the active Mount Garet summit cone. In this paper, a geochemical study including Sr, Nd, Pb and Hf isotopic compositions of 25 lavas emitted since 1.8 Ma is presented, with a focus on the volcanic products that preceded (old volcanics, main cone and pyroclastic series) and followed (Mount Garet) the caldera forming event. All lavas show an island arc signature with enrichment in LILE and depletion in HFSE. Post-caldera lavas define a medium-K calc-alkaline trend, whereas lavas from the former main cone have high-K calc-alkaline compositions. Compared to the pre-caldera volcanic suite, the Mount Garet lavas have similar Th/Nb ( 1.5), 143Nd/144Nd ( 0.51295) and 176Hf/177Hf ( 0.28316) ratios, but higher Ba/La ( 42 vs. 27) and 87Sr/86Sr (0.70417 vs. 0.70405) ratios and lower Ce/Pb ( 2.7 vs. 4.6), La/Sm ( 2.5 vs. 4.0) and 206Pb/204Pb (18.105 vs. 18.176) ratios. High Th/Nb and low Nd and Hf isotopic ratios compared to N-MORB suggest the contribution of 2% of subducted sediment melt to the mantle source of Gaua magmas. Most of the observed differences between pre- and post-caldera lavas can be accounted for by the involvement of at least two portions of the mantle wedge, metasomatized by different slab-derived aqueous fluids. In addition, the lower La/Sm (at a given 143Nd/144Nd) ratios of Mount Garet lavas suggest a higher degree of partial melting ( 10-15%) compared to the pre-caldera lavas ( 5%). The Santa Maria Pyroclastic Series (SMPS) eruption probably triggered the caldera collapse, in response to emptying of the magmatic chamber. This event may have allowed new access to the surface for a geochemically distinct batch of magma issued from a separate magma chamber, resulting in the birth and construction of Mount Garet within the caldera. As both magmatic suites were emitted over a very short time, the storage of their parental

  17. Geochemical characteristics of basaltic glasses from the AMAR and FAMOUS axial valleys, Mid-Atlantic Ridge (36°-37°N): Petrogenetic implications

    NASA Astrophysics Data System (ADS)

    Frey, F. A.; Walker, N.; Stakes, D.; Hart, S. R.; Nielsen, R.

    1993-03-01

    The axial valley of the Mid-Atlantic Ridge from 36° to 37°N was intensively sampled by submersible during the FAMOUS and AMAR projects. Our research focussed on the compositional and isotopic characteristics of basaltic glasses from the AMAR valley and the NARROWGATE region of the FAMOUS valley. These basaltic glasses are characterized by: (1) major element abundance trends that are consistent with control by multiphase fractionation (olivine, plagioclase and clinopyroxene) and magma mixing, (2) near isotopic homogeneity δ 18O= 5.2to6.4 , 87Sr/ 86Sr= 0.70288to0.70299 and 206Pb/ 204Pb= 18.57to18.84 , and (3) a wide range of incompatible element abundance ratios; e.g., within the AMAR valley chondrite-normalized La/Sm ranges from 0.7 to 1.5 and La/Yb from 0.6 to 1.6. These ratios increase with decreasing MgO content. Because of the limited variations in isotopic ratios of Sr, Nd and Pb, it is plausible that these compositional variations reflect post-melting magmatic processes. However, it is not possible to explain the correlated variation in MgO content and incompatible element abundance ratios, such as La/Sm and Zr/Nb, by fractional crystallization or more complex processes such as boundary layer fractionation. These geochemical trends can be explained by mixing of parental magmas that formed by very different extents of melting. In particular, the factor of three variation in Ce content in samples with ˜ 2.1% Na 2O and 8% MgO requires a component derived by < 1% melting. If the large variations in abundance ratios of incompatible elements reflect the melting process, a large, long-lived magma chamber was not present during eruption of these AMAR lavas. The geological characteristics of the AMAR valley and the compositions of AMAR lavas are consistent with episodic volcanism; i.e., periods of magma eruption were followed by extensive periods of tectonism with little or no magmatism.

  18. Lead-isotopic signatures of porphyry copper deposits in oceanic and continental settings, Colombian Andes

    NASA Astrophysics Data System (ADS)

    Sillitoe, R. H.; Hart, S. R.

    1984-10-01

    Three discrete sub-belts of porphyry copper-type mineralization are recognized in the Colombian Andes: a western Eocene sub-belt, an eastern Jurassic to early Cretaceous sub-belt and, between them, a central Miocene sub-belt. The western sub-belt is part of an oceanic domain constituted by oceanic crust and overlying immature island-arc rocks, the eastern sub-belt is within a continental domain underlain by the leading edge of the Guayana shield, and the central sub-belt spans the faulted boundary between them. The thicker continental crust includes important granulitic rocks which crop out locally, as in the vicinity of the Mocoa porphyry copper deposit. Pb-isotopic ratios were determined for pyrite samples collected from 6 porphyry copper centers, 3 in the western sub-belt, 2 in the eastern sub-belt, and one in the central sub-belt. Ratios fall into 3 discrete populations: the most radiogenic values represent the western sub-belt, the least radiogenic represent the eastern sub-belt, and an intermediate value corresponds to the central sub-belt. Ratios therefore become progressively less radiogenic from the western oceanic domain to the eastern cratonic domain. Comparison of the Pb-isotopic ratios with those given in the literature for possible source materials for Colombian porphyry copper leads enables the subcontinental mantle wedge, subducted oceanic crust and subducted metalliferous sediments to be discounted as principal sources. The relatively radiogenic signatures of 5 of the porphyry copper centers appear to be broadly compatible with either a subducted pelagic sediment source or an upper continental crust source, whereas the sixth center, Mocoa, is characterized by a distinctly less radiogenic 206Pb /204Pb ratio. An admixture of a relatively small percentage of non-radiogenic Pb from granulitic material in the upper crust with the more radiogenic Pb typical of the western sub-belt centers could account for the Mocoa data. Because much of the upper

  19. Large Pb Isotopic Variations in Pre-shield Stage Kilauea Magmas

    NASA Astrophysics Data System (ADS)

    Shimizu, N.; Sisson, T. W.; Layne, G. D.

    2001-12-01

    Volcaniclastic sediments found from a scarp below the mid-slope bench at water depths between 3,000 and 5,000m offshore south of Kilauea, Hawaii, contain abundant glass shards that represent submarine eruptions from an ancestral Kilauea volcano (Lipman et al., 2000; Sisson et al., 2001). Their major element compositions range from tholeiites/transitional basalts to alkali basalts to basanites and nephelinites. Pb isotopic compositions of the glasses were determined using a Cameca IMS 1270 ion microprobe at Woods Hole Oceanographic Institution. Replicate analyses of basalt glass stnadards show that 208Pb/206Pb and 207Pb/206Pb ratios could be determined in basalt glasses with external precisions better than 0.15% (1σ ) in a spot of 30 μ m across. Results show that: (1) a range of Pb isotopic compositions observed in the glasses are much greater than the entire spectrum of the Hawaiian volcanics. 208Pb/206Pb ratios vary from 2.099 to 2.004 and 207Pb/206Pb from 0.864 to 0.805. (2) There appear to be three distinct compositions, with each being represented by diverse magmatic compositions. There appears to be no significant mixing between them, and they form a linear array in a 208/206 vs 207/206 space, encompassing the entire Hawaiian Pb isotopic composition array. The least radiogenic composition (208Pb/206Pb=2.099, 207Pb/206Pb=0.864) in on an extension of the Honolulu Volcanics array, whereas the most radiogenic composition (208Pb/206Pb=2.004, 207Pb/206Pb=0.805) is far more radiogenic than any known Hawaiian magmas. The intermediate composition (208Pb/206Pb=2.041, 207Pb/206Pb=0.827) is close to the "Kea" endmember composition proposed by Eiler et al. (1998). The ancestral Kilauea nephelinites are derived from two distinct sources with radiogenic compositions and are quite distinct from all other Hawaiian post-erosional nephelinites. It is evident that diverse sources were tapped during the pre-shield stage Kilauea magmatism, and that melts erupted without mixing

  20. Lead isotope compositions of Late Cretaceous and early Tertiary igneous rocks and sulfide minerals in Arizona: Implications for the sources of plutons and metals in porphyry copper deposits

    USGS Publications Warehouse

    Bouse, R.M.; Ruiz, J.; Titley, S.R.; Tosdal, R.M.; Wooden, J.L.

    1999-01-01

    Porphyry copper deposits in Arizona are genetically associated with Late Cretaceous and early Tertiary igneous complexes that consist of older intermediate volcanic rocks and younger intermediate to felsic intrusions. The igneous complexes and their associated porphyry copper deposits were emplaced into an Early Proterozoic basement characterized by different rocks, geologic histories, and isotopic compositions. Lead isotope compositions of the Proterozoic basement rocks define, from northwest to southeast, the Mojave, central Arizona, and southeastern Arizona provinces. Porphyry copper deposits are present in each Pb isotope province. Lead isotope compositions of Late Cretaceous and early Tertiary plutons, together with those of sulfide minerals in porphyry copper deposits and of Proterozoic country rocks, place important constraints on genesis of the magmatic suites and the porphyry copper deposits themselves. The range of age-corrected Pb isotope compositions of plutons in 12 Late Cretaceous and early Tertiary igneous complexes is 206Pb/204Pb = 17.34 to 22.66, 207Pb/204Pb = 15.43 to 15.96, and 208Pb/204Pb = 37.19 to 40.33. These Pb isotope compositions and calculated model Th/U are similar to those of the Proterozoic rocks in which the plutons were emplaced, thereby indicating that Pb in the younger rocks and ore deposits was inherited from the basement rocks and their sources. No Pb isotope differences distinguish Late Cretaceous and early Tertiary igneous complexes that contain large economic porphyry copper deposits from less rich or smaller deposits that have not been considered economic for mining. Lead isotope compositions of Late Cretaceous and early Tertiary plutons and sulfide minerals from 30 metallic mineral districts, furthermore, require that the southeastern Arizona Pb province be divided into two subprovinces. The northern subprovince has generally lower 206Pb/204Pb and higher model Th/U, and the southern subprovince has higher 206Pb/204Pb and

  1. Miocene-Pleistocene magmas in the Monbetsu area, Northeast Hokkaido, tap N-MORB-like sources contaminated by slab-derived fluids

    NASA Astrophysics Data System (ADS)

    Hoang, Nguyen; Miyagi, Isoji; Itoh, Jun'ichi

    2015-05-01

    Cenozoic intraplate volcanism in northern and northeastern Hokkaido appears to have been closely associated with the Late Oligocene to Mid-Miocene opening of the Japan and Okhotsk Seas (c. 23-12 Ma). Between 12 and 2 Ma, volcanism appeared in the Monbetsu area of northeastern Hokkaido, whose magmatic products are characterized by relative depletions in Nb and Ta and enrichments in LILE and Pb, suggesting a subduction-related source. Likewise, their N-MORB-like isotopic affinity resembles that of active arcs in eastern Hokkaido. These geochemical features are distinct from those of intraplate Cenozoic magmas in Sikhote-Alin, Sakhalin and within the Japan Sea itself, which appear to show a secular change from high-87Sr/86Sr, -206Pb/204Pb and low-143Nd/144Nd (EM2-rich) mantle sources to relatively low-87Sr/86Sr and -206Pb/204Pb (EM1-rich) types, resembling the progression of magmatic activity during early stages of Japan Sea opening. The EM2 is interpreted to derive from lithospheric mantle while EM1-like components may have been introduced by material delaminated from the Sino-Korea craton, following the Indo-Eurasia collision. In contrast, the Cenozoic Monbetsu volcanics in northern and northeastern Hokkaido appear to lack any such temporal pattern, implying that their respective source regions have not changed since at least c. 14 Ma. We suggest, accordingly, that upper mantle beneath Hokkaido may have been isolated after opening of the Japan and Okhotsk Seas, to the west and northwest, the Kurile Basin to the northeast, and continuing west-vergent subduction of the Pacific plate. Given the fact that Cenozoic volcanism in north and northeastern Hokkaido shows apparent subduction-related character, and that the relationship between this activity and opening of the Kurile Basin remains unclear, we tentatively conclude that intraplate mantle melting may reflect a combination of effects, that of slab-derived hydrous fluid superimposed on upwelling asthenosphere.

  2. Ratio imaging instrumentation.

    PubMed

    Dunn, Kenneth; Maxfield, Frederick R

    2003-01-01

    Using ratio imaging to obtain quantitative information from microscope images is a powerful tool that has been used successfully in numerous studies. Although ratio imaging reduces the effects of many parameters that can interfere with accurate measurements, it is not a panacea. In designing a ratio imaging experiment, all of the potential problems discussed in this chapter must be considered. Undoubtedly, other problems that were not discussed can also interfere with accurate and meaningful measurements. Many of the problems discussed here were observed in the authors' laboratories. In our experience there are no standard routines or methods that can foresee every problem before it has been encountered. Good experimental design can minimize problems, but the investigator must continue to be alert. Progress in instrumentation continues to overcome some of the difficulties encountered in ratio imaging. CCD cameras with 12- to 14-bit pixel depth are being used more frequently, and several confocal microscope manufacturers are now also using 12-bit digitization. The dramatic increase in the use of confocal microscopes over the past decade is now causing microscope manufacturers to more critically evaluate the effect of axial chromatic aberration in objectives, and recent designs to minimize this problem are being implemented. Other developments such as the use of AOTFs to attenuate laser lines extend the applicability of ratio imaging. Ratio imaging is clearly applicable to a wide range of cell biological problems beyond its widespread use for measuring ion concentrations. Imaginative but careful use of this technique should continue to provide novel insights into the properties of cells.

  3. Geochemical and Sr-Nd-Pb isotopic characteristics of Late Cenozoic leucite lamproites from the East European Alpine belt (Macedonia and Yugoslavia)

    NASA Astrophysics Data System (ADS)

    Altherr, R.; Meyer, H.-P.; Holl, A.; Volker, F.; Alibert, C.; McCulloch, M. T.; Majer, V.

    In the East European Alpine belt, leucite-sanidine-phlogopite-olivine-bearing volcanic rocks of Late Cenozoic age occur at eight localities within the Vardar suture zone and at one locality in the Southern Carpathian fold-and-thrust belt. Most of these volcanics are characterized by high Mg# (66.6-78.6), high abundances of Ni (117-373 ppm) and Cr (144-445 ppm) as well as high primary K2O contents (5.63-7.01 %) and K2O/Na2O values (1.93-4.91). Rocks with more differentiated compositions are rare. A lamproite affinity of these rocks is apparent from their relatively low contents of Al2O3 (9.9-14.3 wt%) and CaO (6.2-8.3 wt%) in combination with high abundances of Rb (85-967 ppm), Ba (1,027-4,189 ppm), Th (18.9-76.5 ppm), Pb (19-54 ppm), Sr (774-1,712 ppm) and F (0.16-0.52 wt%), and the general lack of plagioclase. Although eruption of the magmas took place in post-collisional extensional settings, significant depletions of Nb and Ta relative to Th and La, low TiO2 contents (0.92-2.17 %), low ratios of Rb/Cs, K/Rb and Ce/Pb as well as high ratios of Ba/La and Ba/Th suggest close genetic relationships to subduction zone processes. Whereas Sr and Nd isotope ratios show relatively large variations (87Sr/86Sr = 0.7078-0.7105, 143Nd/144Nd = 0.51242-0.51215), Pb isotope ratios display a very restricted range with 206Pb/204Pb = 18.68-18.88 and variable but generally high Δ7/4 (11-18) and Δ8/4 (65-95) values. The observed petrographic, geochemical and isotopic characteristics are best explained by a genetic model involving preferential melting of phlogopite-rich veins in an originally depleted lithospheric mantle source, whereby the metasomatic enrichment of the mantle source is tentatively related to the addition of components from subducted sediments during consumption of Tethyan oceanic lithosphere.

  4. Combined Sr, Nd, Pb and Hf isotopic constraints on the origin of Shatsky Rise (NW Pacific)

    NASA Astrophysics Data System (ADS)

    Geldmacher, J.; Heydolph, K.; Murphy, D. T.; Romanova, I.; Mahoney, J. J.; Hoernle, K.

    2012-12-01

    and 206Pb/204Pb ratios, placing them closer to a composition recently proposed for a non-chondritic, primitive mantle reservoir which is supposed to be preferentially sampled by large igneous province volcanism (Jackson and Carlson, 2011). Expedition 324 Scientists, IODP Prel. Rept. 324, 2010 Jackson, M.G. and Carlson, R.W., Nature, vol. 476, 2011 Sano T., Shimizu K., Ishikawa A., Senda R., Chang Q., Kimura J.-I., Widdowson M., Sager W.W. Geochemistry, Geophysics, Geosystems (in press)

  5. Digit ratio in birds.

    PubMed

    Lombardo, Michael P; Thorpe, Patrick A; Brown, Barbara M; Sian, Katie

    2008-12-01

    The Homeobox (Hox) genes direct the development of tetrapod digits. The expression of Hox genes may be influenced by endogenous sex steroids during development. Manning (Digit ratio. New Brunswick, NJ: Rutgers University Press, 2002) predicted that the ratio between the lengths of digits 2 (2D) and 4 (4D) should be sexually dimorphic because prenatal exposure to estrogens and androgens positively influence the lengths of 2D and 4D, respectively. We measured digits and other morphological traits of birds from three orders (Passeriformes, house sparrow, Passer domesticus; tree swallow, Tachycineta bicolor; Pscittaciformes, budgerigar, Melopsittacus undulates; Galliformes, chicken, Gallus domesticus) to test this prediction. None were sexually dimorphic for 2D:4D and there were no associations between 2D:4D and other sexually dimorphic traits. When we pooled data from all four species after we averaged right and left side digits from each individual and z-transformed the resulting digit ratios, we found that males had significantly larger 2D:4D than did females. Tetrapods appear to be sexually dimorphic for 2D:4D with 2D:4D larger in males as in some birds and reptiles and 2D:4D smaller in males as in some mammals. The differences between the reptile and mammal lineages in the directionality of 2D:4D may be related to the differences between them in chromosomal sex determination. We suggest that (a) natural selection for a perching foot in the first birds may have overridden the effects of hormones on the development of digit ratio in this group of vertebrates and (b) caution be used in making inferences about prenatal exposure to hormones and digit ratio in birds.

  6. Petrogenesis and economic potential of the Erhongwa mafic-ultramafic intrusion in the Central Asian Orogenic Belt, NW China: Constraints from olivine chemistry, U-Pb age and Hf isotopes of zircons, and whole-rock Sr-Nd-Pb isotopes

    NASA Astrophysics Data System (ADS)

    Sun, Tao; Qian, Zhuang-Zhi; Li, Chusi; Xia, Ming-Zhe; Yang, Su-Hong

    2013-12-01

    The Erhongwa mafic-ultramafic intrusion is located in the southern margin of the Central Asian Orogenic Belt in northern Xinjiang where many early-Permian mafic-ultramafic intrusions host important Ni-Cu sulfide deposits. In this paper we report zircon U-Pb age, olivine chemistry and integrated whole-rock chemical and isotopic compositions for the Erhongwa mafic-ultramafic intrusion. This intrusion is composed of lherzolites and gabbroic rocks. The U-Pb age of zircon from a large olivine gabbro sample from the intrusion is 283.1 ± 1.5 Ma, which indicates that the Erhongwa intrusion is contemporaneous with the early-Permian sulfide ore-bearing mafic-ultramafic intrusions in the central Tianshan region. Olivine from the Erhongwa intrusion contains up to 89.5 mol% Fo and 3000 ppm Ni, which are the highest among all known early-Permian mafic-ultramafic intrusions in the region. The occurrence of small sulfide inclusions in the most primitive olivine and significant Ni depletion in more fractionated olivine in the Erhongwa intrusion indicate that sulfide segregation took place during olivine fractional crystallization. The Erhongwa intrusive rocks are characterized by light REE enrichment relative to heavy REE, negative Nb anomalies, positive εNd (t = 283 Ma) values from + 6.3 to + 7.7, low initial 87Sr/86Sr ratios from 0.7034 to 0.7036, initial 206Pb/204Pb ratios from 17.8 to 17.9 and zircon εHf values from 8.0 to 15.5. The Erhongwa mafic-ultramafic rocks and coeval A-type granites in the region have similar isotopic compositions but the former have lower Th/Nb ratios than the latter. These similarities and differences are consistent with the interpretation that the Erhongwa magma formed by the mixing of a mafic magma derived from a depleted mantle with a granitic melt derived from a juvenile arc crust. It is deduced that sulfide saturation in the Erhongwa magmatic system was related to the magma mixing event at depth. More significant sulfide mineralization may

  7. Magma Diversity in the Trans-Mexican Volcanic Belt: the role of Mantle Heterogeneities, Slab-derived Fluxes and Crustal Contamination.

    NASA Astrophysics Data System (ADS)

    Schaaf, P.; Valdez, G.; Siebe, C.; Carrasco, G.

    2005-12-01

    The Plio-Quaternary Trans-Mexican Volcanic Belt (TMVB) is related to subduction of the Cocos and Rivera plates underneath the North American plate. Non-parallelism of the magmatic arc with respect to the trench can be explained by oblique subduction and changes of dip angle. In this contribution we compare geochemical and Sr-Nd-Pb isotope data of five TMVB stratovolcanoes (from east to west: Colima Volcano, Nevado de Toluca, Popocatepetl, La Malinche, and Pico de Orizaba) and associated cinder cones. Volcanic products range in stratovolcanoes from andesites (e.g. Colima, Popocatepetl) to rhyolites (e.g. Pico de Orizaba), and from basalts to andesites in the monogenetic cones. Concentrations of incompatible elements correlate positively with Sr-Nd-Pb isotope ratios from east to west along the arc. 87Sr/86Sr, eNd, and 206Pb/204Pb range from 0.7034-0.7050, +6.9 to minus 1.8, and 18.57-18.78, respectively, displaying considerable differences. In the central TMVB, REE patterns of closely spaced high-Mg basaltic andesites differ substantially. This cannot be explained by fractional crystallization processes or differential partial melting of a homogeneous mantle source. Instead, it points towards small-scale mantle heterogeneities. LILE (e.g. Cs, Rb, Ba, Pb) and HFSE (e.g. Ta, Nb, Zr) display variations of orders in magnitude at different segments along the arc. These variations might correlate with amounts of slab-derived aqueous fluids and intensity of metasomatic reactions between the subducting lithosphere and the overlying mantle wedge. Isotopic ratios of mid-lower crustal xenoliths found in nearly all stratovolcano products reflect the nature of the underlying crust beneath the TMVB. Tertiary-Cretaceous plagiogranites (Colima), Cretaceous limestones (Popocatepetl), and Grenvillian quartzites (Pico de Orizaba)and their increasing radiogenic isotope ratios match well with the observed isotopic signatures of the stratovolcanoes. Moreover, elevated CO2 amounts in

  8. Crust-Mantle Interactions at Pico de Orizaba (Citlaltepetl) Volcano, Mexico.

    NASA Astrophysics Data System (ADS)

    Schaaf, P.; Carrasco, G.

    2006-12-01

    Pico de Orizaba (Citlaltepetl) volcano constitutes the easternmost and highest stratovolcano of the subduction- related Plio-Quaternary Trans-Mexican Volcanic Belt (TMVB). The volcano can be divided into three main constructional stages. Its activity started during the mid-Pleistocene. The present cone was built on the remnants of the ancestral buildings by eruption of amphibole-two pyroxene dacitic lava flows, the most recent of which was erupted in the seventeenth century. The volcano is surrounded to the SW by monogenetic Quaternary cindercones and maars. All representative units were sampled in this work for geochemical and isotopic purposes, including a small quartzitic xenolith found in the basaltic monogenetic suite. Volcanic products of the stratocone are quite heterogeneous and range from calc-alkaline basaltic andesites to dome rhyolites, also displayed by a wide range of SiO2 and MgO (72.6-53.2 and 7.0-0.3 wt. %, respectively). In comparison to other TMVB stratovolcanoes (e.g., Colima, Nevado de Toluca), Pico de Orizaba shows similar 87Sr/86Sr ratios (0.7037-0.7048) but considerably more evolved Nd-Pb isotopic ratios (eNd: -1.8 to + 1.4; 206Pb/204Pb: 18.61-18.78). Elevated LILE concentrations and depleted HFSE witness the importance of slab- derived aqueous fluids and metasomatic reactions between the subducting lithosphere and overlying mantle wedge. On the other hand, Pico de Orizaba volcano shows additionally high crustal contributions of a source with depleted Sr and enriched Nd and Pb isotopic signatures, best explained by considerable assimilation of the local Grenvillian basement in magma generation processes. In contrast to Popocatépetl volcano with a high-level magma reservoir emplacement (7-8 km) and obvious interaction with the carbonate-dominated shallow basement rocks (e.g. elevated 87Sr/86Sr ratios and CO2 in gas plumes), this effect cannot be observed at Pico de Orizaba volcano, although a regional Cretaceous limestone basement is also

  9. Geochemical Composition of Volcanic Rocks from the May 2003 Eruption of Anatahan Volcano, Mariana Islands

    NASA Astrophysics Data System (ADS)

    Wade, J. A.; Plank, T.; Stern, R.; Hilton, D.; Fischer, T. P.; Moore, R.; Trusdell, F.; Sako, M.

    2003-12-01

    The first historical eruption of Anatahan volcano began on May 10, 2003, from the easternmost of the island's two craters. Samples of tephra, scoria, and bombs, collected in May by a MARGINS-supported rapid-response team, were analyzed for 34 trace elements by solution ICP-MS at Boston University and Sr-Nd-Pb isotopic composition at the University of Texas-Dallas. The new eruptive materials can be compared with an extensive suite of pre-existing volcanics (basalts through dacites) from Anatahan sampled by the USGS in 1990 and 1992, and analyzed by XRF and INAA. While most Mariana volcanoes erupt basalts and basaltic andesites, Anatahan is unusual for erupting a wide range of compositions, from basalt to dacite, and thus provides the best opportunity for addressing questions of magma evolution in this classic island arc. The newly erupted scoria and pumice are andesites and dacites that are among the most silicic materials erupted in the northern Mariana islands. The recent eruptives are highly homogeneous; 13 samples vary by only 3-5% relative standard deviation for incompatible trace elements. Isotopic compositions (0.703450 +/- 2 87Sr/86Sr and 18.806 +/- 5 206Pb/204Pb) are within the range of previously measured samples from Anatahan and other volcanic centers in the Marianas. The combined dataset for Anatahan defines virtually a single liquid line of descent. This is consistent with nearly-parallel REE patterns, and small variations in the ratios of the most incompatible trace elements (e.g., Th/Rb varies by <10% over the entire fractionation trend). Low values of Th/La and Th/Zr in Anatahan volcanics provide evidence against partial melting of crustal material as a source of the silicic magmas, as these ratios are highly senstive to apatite- and zircon- saturated crustal melts. Instead, the basalts, andesites and dacites of Anatahan appear to be related predominantly by crystal fractionation with little evidence for assimilation of crustal melts. The new data

  10. Precaldera lavas of the southeast San Juan Volcanic Field: Parent magmas and crustal interactions

    NASA Astrophysics Data System (ADS)

    Colucci, M. T.; Dungan, M. A.; Ferguson, K. M.; Lipman, P. W.; Moorbath, S.

    1991-07-01

    Early intermediate composition volcanic rocks of the Oligocene (circa 34-29 Ma) southeast San Juan volcanic field, southern Colorado, comprise the Conejos Formation. Conejos lavas include both high-K calc-alkaline and alkaline magma series (54-69% SiO2) ranging in composition from basaltic andesite (basaltic trachyandesite) to dacite (trachydacite). The subsequent Platoro caldera complex (29-27 Ma) was superimposed on a cluster of broadly precursory Conejos stratocones. Precaldera volcanism occurred in three pulses corresponding to three time-stratigraphic members: (1) the Horseshoe Mountain member, (2) the Rock Creek member, and (3) the Willow Mountain member. Each member exhibits distinctive phenocryst modes and incompatible trace element contents. Horseshoe Mountain lavas (hornblende-phyric) have relatively low alkali and incompatible element abundances, Rock Creek lavas (anhydrous phenocrysts) and ash-flow tuffs have the highest abundances, and Willow Mountain lavas (diverse mineralogy) are intermediate. All Conejos lavas exhibit low ratios of lead (206Pb/204Pb = 17.5 to 18.2) and neodymium (ɛNd = -8 to -4) isotopes and high 87Sr/86Sr (0.7045 to 0.7056) compared to depleted asthenospheric mantle. These values lie between those of likely mantle compositions and the isotopic composition of Proterozoic crust of the southern Rocky Mountains. Mafic lavas of the Horseshoe Mountain member have the lowest Pb and Nd isotope ratios among Conejos members but trend toward higher isotopic values with increasing degrees of differentiation. Compositions within the Rock Creek series trend toward higher Pb and lower Nd isotope ratios with increasing SiO2. Willow mountain volcanic sequences define diverse chemical-isotopic correlations. We interpret the chemical and isotopic differences observed between mafic lavas of each member to reflect derivation from compositionally distinct mantle derived parent magmas that have experienced extensive deep level crustal contamination

  11. Multi-ratio transmission

    SciTech Connect

    Polak, J.C.

    1987-07-14

    A preselected multi-ratio power transmission is described comprising: input means for transmitting drive forces; output means; first, second and third friction clutch means each selectively engageable with the input means for accepting drive forces. First input gear means drivingly connects with the first friction clutch means; second input gear means drivingly connects with the second friction clutch means; third input gear means drivingly connects with the third clutch means; first output gear means drivingly connects with the first input gear means; second output gear means drivingly connects with the first and second input gear means; third output means drivingly connects between the third input gear means and the output means; and one double-acting synchronizer clutch for selectively engaging the first output gear means with the output means and alternately the second output gear means with the output means. The first friction clutch means and the one double-acting synchronizer clutch cooperates during engagement to establish two forward drive ratios between the input and output means. The second friction clutch means and the one double-acting synchronizer clutch cooperates during engagement to establish two other forward drive ratios between the input and output means. The third friction clutch means is engageable to provide another forward drive ratio between the input means and the output means; and the one double-acting synchronizer clutch is relieved of transmitting drive forces during the engagement of the third friction clutch means and being manipulable for alternate connection with either the first output gear or the second output gear while the third friction clutch means is engaged.

  12. Tracing the transport of anthropogenic lead in the atmosphere and in soils using isotopic ratios

    SciTech Connect

    Erel, Y.; Veron, A.; Halicz, L.

    1997-11-01

    The isotopic composition of lead in aerosols and soils in Israel is used to characterize the sources of anthropogenic lead in the region, to ascertain the isotopic composition of natural, rock-derived lead in specific areas, and to determine rates of anthropogenic lead migration in soils. The isotopic composition of lead currently emitted from cars in Israel ({sup 206}Pb/{sup 207}Pb = 1.115 {+-} 2) is controlled by alkyl-lead produced in France and Germany. In addition to petrol-lead, two more sources of anthropogenic lead can be detected in sampled aerosols; the first one has low concentrations of lead ({approximately} ng/m{sup 3}) and {sup 206}Pb/{sup 207}Pb {approximately} 1.157, and is most likely lead, emitted in Turkey, that traveled across the eastern Mediterranean basin; the second type of aerosols contains a mixture of lead emitted in several countries including Turkey, Greece, and Ukraine ({sup 206}Pb/{sup 207}Pb value of 1.155-1.160; [Pb] {approximately}20-30 ng/m{sup 3}). Anthropogenic lead is more accessible for acid leaching than natural lead, therefore, it is more labile in the soil. The isotopic composition of lead in the acid-leached fraction of near-road soil profiles records the history of alkyl-lead emission in the country. Based on changes in the isotopic composition of lead with soil depth, it is estimated that anthropogenic lead migrates into the soil at approximately 0.5 cm/y. A soil profile from a relatively remote area is less contaminated by anthropogenic lead and displays a different distribution of lead isotopic values with depth. The isotopic composition of lead suggests that natural lead in soils developed on carbonate bedrock is derived from clays, either from the rock-residue (the clay fraction in the carbonate bedrock), or from airborne clay, but not from lead released from the carbonate fraction in the rock. 44 refs., 6 figs., 2 tabs.

  13. Evidence for influence of the Galápagos hotspot on the East Pacific Rise MORB composition during times of superfast spreading

    NASA Astrophysics Data System (ADS)

    Geldmacher, J.; Höfig, T.; Hauff, S. F.; Hoernle, K.; Garbe-Schoenberg, C.

    2011-12-01

    ODP/IODP Hole 1256D on the Cocos Plate is located on oceanic crust that formed 15 m.y. ago at the East Pacific Rise (EPR) during a period of superfast spreading (~11-20 Ma). This site is considered to be a reference site for crust formed during fast (>8 cm/y) and particularly superfast (>20 cm/y) spreading rates. The question exists whether its formation was geochemically influenced by the Galápagos hotspot. Today, the effect of the Galápagos hotspot on mid ocean ridge geochemistry can only be seen along the Cocos-Nasca Spreading Center (located immediately north of the hotspot). It has been speculated that Galápagos plume material might have reached the EPR during times of superfast spreading due to processes such as increased "ridge suction" (Niu & Hékinian, 2004). To test this idea, MORB samples from several DSDP, ODP and IODP drill sites that formed along the EPR between 3°S and 7°N and between 9 and 21 Ma have been studied to delineate any effect of the Galápagos hotspot on their geochemistry. N-MORB from sites formed during times of superfast spreading show slighty, but systematically, lower incompatible element ratios (e.g. La/Yb < 0.65, Ce/Lu <0.76), compared to rocks formed shortly before, or after, superfast spreading (La/Yb >0.66, Ce/Lu >0.8). In addition, the melts formed during superfast spreading show generally higher Eu/Hf and Eu/Eu* ratios which is interpreted to indicate a recycled gabbroic component in their source. Despite their more depleted incompatible trace element patterns, Pb (double-spike) and Nd isotope ratios of the superfast spreading MORB are enriched (higher 206Pb/204Pb, 207Pb/204Pb and lower 143Nd/144Nd) compared to the samples from MORB created during normal spreading. The combined trace element and isotope data suggest that EPR MORB created during superfast spreading was formed by greater degrees of melting of a possibly trace element depleted, but isotopically enriched source component. It is suggested that the source of

  14. Sr, Nd and Pb isotope and geochemical data from the Quaternary Nevado de Toluca volcano, a source of recent adakitic magmatism, and the Tenango Volcanic Field, Mexico

    NASA Astrophysics Data System (ADS)

    Martínez-Serrano, Raymundo G.; Schaaf, Peter; Solís-Pichardo, Gabriela; Hernández-Bernal, Ma. del Sol; Hernández-Treviño, Teodoro; Julio Morales-Contreras, Juan; Macías, José Luis

    2004-11-01

    Volcanic activity at Nevado de Toluca (NT) volcano began 2.6 Ma ago with the emission of andesitic lavas, but over the past 40 ka, eruptions have produced mainly lava flows and pyroclastic deposits of predominantly orthopyroxene-hornblende dacitic composition. In the nearby Tenango Volcanic Field (TVF) pyroclastic products and lava flows ranging in composition from basaltic andesite to andesite were erupted at most of 40 monogenetic volcanic centers and were coeval with the last stages of NT. All volcanic rocks in the study area are characterized by a calc-alkaline affinity that is consistent with a subduction setting. Relatively high concentrations of Sr (>460 ppm) coupled with low Y (<21 ppm), along with relatively low HREE contents and Pb isotopic values similar to MORB-EPR, suggest a possible geochemical adakitic signature for the majority of the volcanic rocks of NT. The HFS- and LIL-element patterns for most rocks of the TVF suggest a depleted source in the subcontinental lithosphere modified by subduction fluids, similar to most rocks from the Trans-Mexican Volcanic Belt (TMVB). The isotopic compositions are similar for volcanic rocks of NT and TVF regions ( 87Sr/ 86Sr: 0.703853-0.704226 and 0.703713-0.704481; ɛNd: +4.23-+5.34 and +2.24-+6.85; 206Pb/ 204Pb: 18.55-18.68 and 18.58-18.69; 207Pb/ 204Pb: 15.54-15.62 and 15.56-15.61; 208Pb/ 204Pb: 38.19-38.47 and 38.28-38.50, respectively), suggesting a MORB-like source with low crustal contamination. Metamorphic xenoliths from deeper continental crust beneath NT volcano show isotopic patterns similar to those of Grenvillian rocks of north-central Mexico ( 87Sr/ 86Sr: 0.715653-0.721984, ɛNd: -3.8 to -7.2, 206Pb/ 204Pb: 18.98-19.10, 207Pb/ 204Pb: 15.68-15.69, 208Pb/ 204Pb: 39.16-39.26 and Nd model age (T DM) of 1.2-1.3 Ga). In spite of a thick continental crust (>45 km) that underlies the volcanoes of the study area, the geochemical and isotopic patterns of these rocks indicate low interaction with this crust. NT

  15. Two Distinct Sets of Magma Sources in Cretaceous Rocks From Magnet Cove, Prairie Creek, and Other Igneous Centers of the Arkansas Alkaline Province, USA

    NASA Astrophysics Data System (ADS)

    Duke, G. I.; Carlson, R. W.; Eby, G. N.

    2008-12-01

    Two distinct sets of magma sources from the Arkansas alkaline province (~106-89 Ma) are revealed by Sr-Nd-Pb isotopic compositions of olivine lamproites vs. other alkalic rock types, including carbonatite, ijolite, lamprophyres, tephrite, malignite, jacupirangite, phonolite, trachyte, and latite. Isotopic compositions of diamond-bearing olivine lamproites from Prairie Creek and Dare Mine Knob point to Proterozoic lithosphere as an important source, and previous Re-Os isotopic data indicate derivation from subcontinental mantle lithosphere. Both sources were probably involved in lamproite generation. Magnet Cove carbonatites and other alkalic magmas were likely derived from an asthenospheric source. Lamproite samples are isotopically quite different from other rock types in Sr-Nd-Pb isotopic space. Although three lamproite samples from Prairie Creek have a large range of SiO2 contents (40-60 wt %), initial values of ɛNd (-10 to -13), 206Pb/204Pb (16.61-16.81), 207Pb/204Pb (15.34-15.36), and 208Pb/204Pb (36.57-36.76) are low and similar. Only 87Sr/86Sr(i) displays a wide range in the Prairie Creek lamproites (0.70627-0.70829). A fourth lamproite from Dare Mine Knob has the most negative ɛNd(i) of -19. Lamproite isotope values show a significant crustal component and isotopically overlap subalkalic rhyolites from the Black Hills (SD), which assimilated Proterozoic crust. Six samples of carbonatite, ijolite, and jacupirangite from Magnet Cove and Potash Sulphur Springs exhibit the most depleted Sr-Nd isotopic signatures of all samples. For these rock types, 87Sr/86Sr(i) is 0.70352 - 0.70396, and ɛNd(i) is +3.8 - +4.3. Eight other rock types have a narrow range of ɛNd(i) (+1.9 - +3.7), but a wide range of 87Sr/86Sr(i) (0.70424 - 0.70629). These 14 samples comprise a fairly tight cluster of Pb isotopic values: 206Pb/204Pb (18.22-19.23), 207Pb/204Pb (15.54-15.62), and 208Pb/204Pb (38.38-38.94), suggesting very little crustal assimilation. They are most similar to EM-2

  16. Triassic fluid mobilization and epigenetic lead-zinc sulphide mineralization in the Transdanubian Shear Zone (Pannonian Basin, Hungary)

    NASA Astrophysics Data System (ADS)

    Benkó, Zsolt; Molnár, Ferenc; Lespinasse, Marc; Billström, Kjell; Pécskay, Zoltán; Németh, Tibor

    2014-06-01

    A combined fluid inclusion, fluid inclusion plane, lead isotope and K/Ar radiometric age dating work has been carried out on two lead-zinc mineralizations situated along the Periadriatic-Balaton Lineament in the central part of the Pannonian Basin, in order to reveal their age and genetics as well as temporal-spatial relationships to other lead-zincfluorite mineralization in the Alp-Carpathian region. According to fluid inclusion studies, the formation of the quartzfluorite- galena-sphalerite veins in the Velence Mts is the result of mixing of low (0-12 NaCl equiv. wt. %) and high salinity (10-26 CaCl2 equiv. wt. %) brines. Well-crystallized (R3-type) illite associated with the mineralized hydrothermal veins indicates that the maximum temperature of the hydrothermal fluids could have been around 250 °C. K/Ar radiometric ages of illite, separated from the hydrothermal veins provided ages of 209-232 Ma, supporting the Mid- to Late-Triassic age of the hydrothermal fluid flow. Fluid inclusion plane studies have revealed that hydrothermal circulation was regional in the granite, but more intensive around the mineralized zones. Lead isotope signatures of hydrothermal veins in the Velence Mts (206Pb/204Pb = 18.278-18.363, 207Pb/204Pb = 15.622-15.690 and 208Pb/204Pb = 38.439-38.587) and in Szabadbattyán (206Pb/204Pb = 18.286-18.348, 207Pb/204Pb = 15.667-15.736 and 208Pb/204Pb = 38.552-38.781) form a tight cluster indicating similar, upper crustal source of the lead in the two mineralizations. The nature of mineralizing fluids, age of the fluid flow, as well as lead isotopic signatures of ore minerals point towards a genetic link between epigenetic carbonate-hosted stratiform-stratabound Alpine-type lead-zinc-fluorite deposits in the Southern and Eastern Alps and the studied deposits in the Velence Mts and at Szabadbattyán. In spite of the differences in host rocks and the depth of the ore precipitation, it is suggested that the studied deposits along the Periadriatic

  17. The plumbotectonic model for Pb isotopic systematics among major terrestrial reservoirs-A case for bi-directional transport

    USGS Publications Warehouse

    Zartman, R.E.; Haines, S.M.

    1988-01-01

    Version IV of plumbotectonics expands and refines the original model of Doe and Zartman (1979) and Zartman and Doe (1981) for explaining Pb (Sr, and Nd) isotopic systematics among major terrestrial reservoirs. A case for bi-directional transport among reservoirs is based on the observed isotopic compositions for different tectonic settings, and finds a rationale in the kinetics of plate tectonics. Chemical fractionation and radioactive decay create isotopic differences during periods of isolation of one reservoir from another, whereas dynamic processes allowing mixing between reservoirs tend to reduce these differences. Observed isotopic characteristics reflect a balance between these opposing tendencies and provide constraints on the extent and timing of fractionation and mixing processes. Plumbotectonics does not require interaction with a lower mantle or core reservoir over most of the Earth's lifetime, and, in fact, achieves a material balance consistent with no such exchange of material. Important evidence of the amount and timing of crustal recycling, and of the residence times of mantle heterogeneities lies in the coupled 207Pb 204Pb-206 Pb 204Pb systematics. We believe that examination of the published data base fully supports our contention of significant bi-directional transport of material among terrestrial reservoirs. Plumbotectonics allows us to explore many aspects of reservoir interaction, and to identify parameters that provide meaningful constraints on mantle-crust differentiation. We put forth a compromise fit to many of the model variables in version IV, which can serve as a reference for future work. ?? 1988.

  18. Evaluating Young Volcanism at Baitoushan Volcano: Insights From Single Mineral Crystal Sr and Pb Isotope Analyses

    NASA Astrophysics Data System (ADS)

    Rodgers, S. L.; Ramos, F. C.; Gill, J. B.

    2008-12-01

    Baitoushan volcano, located along the North-Korea/China border, generated one of the largest caldera- forming rhyolitic eruptions in the northern hemisphere in the last 2000 years. In addition to a large ~1000AD comendite eruption, a pantellerite eruption occurred at ~0AD which left a small pumice deposit. We have evaluated the isotopic signatures of single mineral crystals and pumice fragments from this pantellerite to evaluate the sources, petrogenetic history, timing, and residence of highly alkaline rhyolitic magma at Baitoushan. Single mineral isotope characteristics of this pantellerite are complex. Rb/Sr analyses of whole pumice fragments suggest a pantellerite residence age of ~348ky, similar to residence ages determined for Long Valley Caldera and Valles Caldera. Individual potassium feldspar and clinopyroxene crystals have similarly variable and overlapping 87Sr/86Sr signatures that are different than those of host pumice fragments but similar to crystals erupted in the ~1000AD comendite. These same crystals define a linear trend in 207Pb/204Pb vs 206Pb/204Pb that suggests mixing between host pumice and a second currently unidentified endmember. Results, however, unequivocally demonstrate mixing and undermine any residence age associated with Rb/Sr isotope systematics of pumice fragments. Overall Sr and Pb isotope systematics reflect variable signatures as compared to all other recent eruptive products at Baitoushan and suggest highly variable processes involved in melt production and that select minerals may be shared between different eruptions spanning a 2000 to 4000 year time period.

  19. Petrology and geochemistry of lower crustal granulites from the Geronimo Volcanic Field, southeastern Arizona

    SciTech Connect

    Kempton, P.D.; Hawkesworth, C.J. ); Harmon, R.S. ); Moorbath, S. )

    1990-12-01

    Mafic to intermediate composition granulite xenoliths occur in Pliocene to Recent alkali basalts from the Geronimo Volcanic Field (GVF), southeastern Arizona, USA. The range of compositions and mineral assemblages observed suggests that the ultimate derivation of these rocks is from a variety of protoliths and that more than one mechanism has operated during the geologic evolution of the lower crust in this area. Two-pyroxene, two-feldspar granulites (meta-diorites) have major and trace element characteristics similar to estimates of post-Archaen lower crust. Low {sup 143}Nd/{sup 144}Nd values and Proterozoic Nd-depleted-mantle model ages (1.2-1.4 Ga) for these rocks require that Precambrian material exists in the lower crust of southeastern Arizona, either as the meta-diorites themselves or as older crust available for melting during production of the meta-diorite protoliths. K-feldspar-free granulites have more mafic compositions and their trace element characteristics are consistent with a cumulate origin. A negative correlation of {sup 208}Pb/{sup 204}Pb vs. {sup 206}Pb/{sup 204}Pb suggests that the meta-cumulate granulites represent mixing between Basin and Range age lavas with older meta-diorite crust and is, thus, evidence for Cenozoic underplating of the lower crust beneath the Basin and Range.

  20. Isotopic Variations in the Post-Shield Lavas of Mauna Kea, Hualalai and Kohala: Evidence for a Koolau Component

    NASA Astrophysics Data System (ADS)

    Aciego, S.; Depaolo, D. J.; Eiler, J. M.; Hanano, D.; Weis, D.

    2005-12-01

    We have measured O, He, Pb, Sr, and Nd isotope ratios in olivine separates and whole rock powders from post-shield lavas of the island of Hawaii. These small-volume eruptions, which presumably correspond to small-volume source regions in the mantle, serve as high resolution probes of geochemical heterogeneity to complement data available from shield-stage tholeiites that originate in the primary melting region. He, Sr, and Nd ratios show small amplitude variations, well within the range of previously published data indicating little evidence for isotopically anomalous material in the melting region - either recycled sediments or oceanic crust. These data suggest that the plume does not contain large-amplitude isotopic variations at the scale of the source volume of post-shield lavas, which is likely to be about 100 times smaller than the volume averaged during main stage tholeiite production. However, the oxygen and lead isotope data indicate consistent, large amplitude differences between Hualalai and the other volcanoes. Samples from Hualalai have high δ18O (+5.5) and low 206Pb/204Pb (17.888-18.028). The only other volcanoes in the Hawaiian chain with such correlated extreme values are Koolau and Lanai, which have enriched radiogenic isotopic Sr and Nd compositions not seen in the data from Hualalai. Furthermore, correlated low helium values (8-10R/Ra)- high δ18O from Hualalai are consistent with a Koolau component in the source region for this volcano. The high δ18O contra-indicates a significant lithospheric interaction that would probably decrease δ18O rather than increase it to the values we measure. Samples from Mauna Kea and Kohala are consistently lower in δ18O (+4.8-5.12) than those from Hualalai, and fall within the range of previously measured values for late shield-stage lavas. The multiple isotope systems measured on the same post-shield samples indicate that simple models for Kea and Loa trends based on main stage tholeiitic lavas do not capture

  1. U-Pb (zircon) and geochemical constraints on the age, origin, and evolution of Paleozoic arc magmas in the Oyu Tolgoi porphyry Cu-Au district, southern Mongolia

    USGS Publications Warehouse

    Wainwright, A.J.; Tosdal, R.M.; Wooden, J.L.; Mazdab, F.K.; Friedman, R.M.

    2011-01-01

    Uranium-Pb (zircon) ages are linked with geochemical data for porphyry intrusions associated with giant porphyry Cu-Au systems at Oyu Tolgoi to place those rocks within the petrochemical framework of Devonian and Carboniferous rocks of southern Mongolia. In this part of the Gurvansayhan terrane within the Central Asian Orogenic Belt, the transition from Devonian tholeiitic marine rocks to unconformably overlying Carboniferous calc-alkaline subaerial to shallow marine volcanic rocks reflects volcanic arc thickening and maturation. Radiogenic Nd and Pb isotopic compositions (??Nd(t) range from +3.1 to +7.5 and 206Pb/204Pb values for feldspars range from 17.97 to 18.72), as well as low high-field strength element (HFSE) contents of most rocks (mafic rocks typically have <1.5% TiO2) are consistent with magma derivation from depleted mantle in an intra-oceanic volcanic arc. The Late Devonian and Carboniferous felsic rocks are dominantly medium- to high-K calc-alkaline and characterized by a decrease in Sr/Y ratios through time, with the Carboniferous rocks being more felsic than those of Devonian age. Porphyry Cu-Au related intrusions were emplaced in the Late Devonian during the transition from tholeiitic to calc-alkaline arc magmatism. Uranium-Pb (zircon) geochronology indicates that the Late Devonian pre- to syn-mineral quartz monzodiorite intrusions associated with the porphyry Cu-Au deposits are ~372Ma, whereas granodiorite intrusions that post-date major shortening and are associated with less well-developed porphyry Cu-Au mineralization are ~366Ma. Trace element geochemistry of zircons in the Late Devonian intrusions associated with the porphyry Cu-Au systems contain distinct Th/U and Yb/Gd ratios, as well as Hf and Y concentrations that reflect mixing of magma of distinct compositions. These characteristics are missing in the unmineralized Carboniferous intrusions. High Sr/Y and evidence for magma mixing in syn- to late-mineral intrusions distinguish the Late

  2. Assessing the origin of old apparent ages derived by Pb stepwise leaching of vein-hosted epidote from Mount Isa, northwest Queensland, Australia

    NASA Astrophysics Data System (ADS)

    Duncan, Robert J.; Maas, Roland

    2014-12-01

    Epidote metasomatism affected large areas of tholeiitic metabasalts of the ~1,780 Ma Eastern Creek Volcanics in the Western Fold Belt of the Proterozoic Mount Isa inlier. Hydrothermal epidote generally occurs in quartz veins parallel to or boudinaged within the dominant S2 fabrics which formed during the regional metamorphic peak at ~1,570 Ma associated with the Isan orogeny. Previously published stable isotopic and halogen data suggest that the fluids responsible for epidote formation are metamorphic in origin (with an evaporitic component). Application of the Pb stepwise leaching technique to the epidote does not separate radiogenic Pb4+ and common Pb2+, generating little spread in 206Pb/204Pb (between 16.0 and 30.5). The causes for this relatively low range are twofold: There is little radiogenic Pb in the epidotes (the most radiogenic steps account for <1 % of Pb released) and both Pb2+ and uranogenic Pb4+ substitute into the same site in the epidote crystal lattice. Consequently, age regressions using the Pb stepwise leaching data give ages between 150 and 1,500 myrs older than the host rocks and over 450 myrs older than the thermal metamorphic peak. These old ages are attributed to chemical inheritance from the host metabasalts, via radiogenic Pb release by breakdown of phases such as zircon, monazite, titanomagnetite, and ilmenite during metamorphism. This idea is supported by trace element data and chrondrite-normalized rare earth element patterns that are similar to both the metabasalts and epidotes (except for a variable Eu anomaly in the latter). Relatively high fO2 during vein formation (Fe3+ dominates in the epidote crystal lattice) would allow the incorporation of Th4+ and exclusion of U6+ and would explain elevated Th/U ratios (up to 12) in epidote compared with the host metabasalts. Non-incorporation of U would explain the relatively low U/Pb ratios and non-radiogenic character of the epidote. This process may provide a source of metal for the small

  3. Petrogenesis of postcollisional magmatism at Scheelite Dome, Yukon, Canada: Evidence for a lithospheric mantle source for magmas associated with intrusion-related gold systems

    USGS Publications Warehouse

    Mair, John L.; Farmer, G. Lang; Groves, David I.; Hart, Craig J.R.; Goldfarb, Richard J.

    2011-01-01

    The type examples for the class of deposits termed intrusion-related gold systems occur in the Tombstone-Tungsten belt of Alaska and Yukon, on the eastern side of the Tintina gold province. In this part of the northern Cordillera, extensive mid-Cretaceous postcollisional plutonism took place following the accretion of exotic terranes to the continental margin. The most cratonward of the resulting plutonic belts comprises small isolated intrusive centers, with compositionally diverse, dominantly potassic rocks, as exemplified at Scheelite Dome, located in central Yukon. Similar to other spatially and temporally related intrusive centers, the Scheelite Dome intrusions are genetically associated with intrusion-related gold deposits. Intrusions have exceptional variability, ranging from volumetrically dominant clinopyroxene-bearing monzogranites, to calc-alkaline minettes and spessartites, with an intervening range of intermediate to felsic stocks and dikes, including leucominettes, quartz monzonites, quartz monzodiorites, and granodiorites. All rock types are potassic, are strongly enriched in LILEs and LREEs, and feature high LILE/HFSE ratios. Clinopyroxene is common to all rock types and ranges from salite in felsic rocks to high Mg augite and Cr-rich diopside in lamprophyres. Less common, calcic amphibole ranges from actinolitic hornblende to pargasite. The rocks have strongly radiogenic Sr (initial 87Sr/86Sr from 0.711-0.714) and Pb isotope ratios (206Pb/204Pb from 19.2-19.7), and negative initial εNd values (-8.06 to -11.26). Whole-rock major and trace element, radiogenic isotope, and mineralogical data suggest that the felsic to intermediate rocks were derived from mafic potassic magmas sourced from the lithospheric mantle via fractional crystallization and minor assimilation of metasedimentary crust. Mainly unmodified minettes and spessartites represent the most primitive and final phases emplaced. Metasomatic enrichments in the underlying lithospheric mantle

  4. New isotopic data for Mid-Atlantic Ridge basalts from the Arkhangelsk-Sierra Leone fracture zone (central Atlantic)

    NASA Astrophysics Data System (ADS)

    Skolotnev, S. G.

    2014-11-01

    This study presents Sr, Nd, and Pb isotopic data for basalts collected from the MAR axis between the Arkhangelsk transform fault and 5° N. The isotopic data for basalts from the MAR segment between the Arkhangelsk and Vernadsky faults indicate the presence of N-MORB depleted tholeiites, which are similar to some basalts from the MAR segment between the Cape Verde and Marathon faults, at the location of the 14° N geochemical anomaly. Broad positive along-axis gradients in isotopic values (and negative for 143Nd/144Nd) are observed from south to north, superimposed by isotopic variations in the 9.6° N anomalous basalts. A north-south increase in (La/Sm) n suggests a smaller degree of partial melting. The range of isotopic variations in basalts south of the Bogdanov fault is similar to that of basalts recovered at the more southerly 1.7° N anomaly. P-MORB compositions with a large proportion of the HIMU-like component are widely distributed in the vicinity of the 5.4° N rise. The isotopic ratios decrease gradually (with increasing 143Nd/144Nd) farther to the north toward the Bogdanov transform fault. A similar trend is observed for (La/Sm) n . Therefore, the basalts recovered to the south and north of Bogdanov fault have different sources of radiogenic isotope enrichment: 5.4° N and 9.6° N rises. Basalts recovered to the north of the Vernadsky transform fault have higher 143Nd/144Nd and lower 206Pb/204Pb at similar 87Sr/86Sr ratios. We conclude that the localized manifestations of enriched basalts with isotopic characteristics close to the HIMU-like plume-derived component, including the 14° N and 1.7° N geochemical anomalies, may have been formed by microplumes entrained at the base of the upper mantle by asthenospheric mantle flows arranged into a system of cylindrical convective cells, 450-500 km in diameter. Northward of the Bogdanov transform, the upper mantle is contaminated with lower continental crust material, which was entrained during tectonic

  5. Heavy-Ion Transfer Reactions with Deformed Nuclei

    NASA Astrophysics Data System (ADS)

    Helmer, Karl Gerard

    1992-01-01

    One-neutron transfer reactions involving actinide nuclei are used to investigate the effects of rotational motion on transfer populations. Deexcitation gamma rays were measured using a particle -particle-gamma triple coincidence method. Rotational states up to 28^{+ }(30^{+}) were seen in ^{234}U originating from the reaction ^{235}U( ^{206}Pb, ^ {207}Pb)^{234} U at a laboratory bombarding energy of 1394 MeV. Angular distributions for both inelastic excitation and transfer are presented and the one-neutron transfer reaction cross section as well as the grazing angle have been extracted. This study demonstrates the feasibility of using heavy-ion induced transfer reactions for spectroscopic studies. The second section of this thesis explores the question of diabolical pair transfer in nuclear physics using the reactions ^{206}Pb( ^{156}Gd, ^ {154}Gd)^{208} Pb (diabolical case) and ^{206 }Pb(^{156}Gd, ^{158}Gd)^ {204}Pb (nondiabolic case) at a laboratory bombarding energy of 888 MeV. Early calculations by Nikam, Ring and Canto predicted oscillatory behavior of pair transfer matrix elements as the cranking frequency was varied, within the cranking Hartree-Fock-Bogoliubov (CHFB) model, and explained this behavior as a manifestation of Berry's phase. Significant suppression of the high spin population in the diabolical nucleus was predicted. The diabolical point is supplied by the crossing of the ground-state band with the two-quasiparticle band. The strength of this band interaction is predicted to be oscillatory with chemical potential in the CHFB model. The study of pair transfer populations can therefore shed light not only on the possible existence of Berry's phase in nuclear systems, but also on whether the band interaction goes strictly to zero as predicted by the CHFB model. The results of this experiment agree with the latest calculations that the expected effects are more subtle than the earliest calculations predicted.

  6. Petrogenesis of Late Triassic ultramafic rocks from the Andong Ultramafic Complex, South Korea

    NASA Astrophysics Data System (ADS)

    Kim, Nak Kyu; Choi, Sung Hi

    2016-11-01

    To constrain the source and tectonomagmatic processes that gave rise to the Andong Ultramafic Complex (AUC) in South Korea, we determined the clinopyroxene Sr-Nd-Hf-Pb isotope and trace element compositions as well as the whole-rock and mineral compositions for the Late Triassic (ca. 222 Ma) ultramafic rocks from the complex. They are composed of dunites, wehrlites, pyroxene/hornblende peridotites, and pyroxenites. The constituent minerals are olivines, diopsides/augites, bronzites, calcic-amphiboles, and spinels. Clinopyroxenes exhibit a convex-upward rare earth element (REE) pattern, with an apex at Sm. The whole-rock compositions plot away from the residual mantle peridotite trends, with variable but lower Al2O3 and SiO2 contents, and higher CaO, FeO*, and TiO2 contents at a given value of MgO. Estimated equilibrium temperatures for the AUC rocks range from 420 to 780 °C. These observations, together with the absence of reaction or melt impregnation textures, indicate that the AUC ultramafic rocks are magmatic cumulates emplaced within the crust rather than residual mantle or mantle-melt reaction products. The AUC clinopyroxenes have compositions intermediate between the oceanic island basalt- and arc basalt-related cumulate clinopyroxenes. The AUC spinels have lower Cr#s than the arc-related magmatic cumulate spinels. They plot within the field for spinels from mid-ocean ridge basalts (MORB) on a TiO2 vs. Cr# diagram. However, the AUC clinopyroxenes have much more radiogenic Sr ([87Sr/86Sr]i = 0.70554 to 0.70596), unradiogenic Nd ([εNd]i = - 1.0 to - 0.3), and Hf ([εHf]i = + 4.4 to + 6.6) isotopic compositions than those of the MORB or fore-arc basalts (FAB). In the Sr-Nd isotopic correlation diagram, the AUC clinopyroxenes plot in the enriched extension of the "mantle array". They also have more elevated 207Pb/204Pb ratios at a given 206Pb/204Pb than those of the MORB or FAB. In the Nd-Hf isotope space, the AUC clinopyroxenes have somewhat elevated 176Hf

  7. Primitive magmas at five Cascade volcanic fields: Melts from hot, heterogeneous sub-arc mantle

    USGS Publications Warehouse

    Bacon, C.R.; Bruggman, P.E.; Christiansen, R.L.; Clynne, M.A.; Donnelly-Nolan, J. M.; Hildreth, W.

    1997-01-01

    Major and trace element concentrations, including REE by isotope dilution, and Sr, Nd, Pb, and O isotope ratios have been determined for 38 mafic lavas from the Mount Adams, Crater Lake, Mount Shasta, Medicine Lake, and Lassen volcanic fields, in the Cascade arc, northwestern part of the United States. Many of the samples have a high Mg# [100Mg/(Mg + FeT) > 60] and Ni content (>140 ppm) such that we consider them to be primitive. We recognize three end-member primitive magma groups in the Cascades, characterized mainly by their trace-element and alkali-metal abundances: (1) High-alumina olivine tholeiite (HAOT) has trace element abundances similar to N-MORB, except for slightly elevated LILE, and has Eu/Eu* > 1. (2) Arc basalt and basaltic andesite have notably higher LILE contents, generally have higher SiO2 contents, are more oxidized, and have higher Cr for a given Ni abundance than HAOT. These lavas show relative depletion in HFSE, have lower HREE and higher LREE than HAOT, and have smaller Eu/Eu* (0.94-1.06). (3) Alkali basalt from the Simcoe volcanic field east of Mount Adams represents the third end-member, which contributes an intraplate geochemical signature to magma compositions. Notable geochemical features among the volcanic fields are: (1) Mount Adams rocks are richest in Fe and most incompatible elements including HFSE; (2) the most incompatible-element depleted lavas occur at Medicine Lake; (3) all centers have relatively primitive lavas with high LILE/HFSE ratios but only the Mount Adams, Lassen, and Medicine Lake volcanic fields also have relatively primitive rocks with an intraplate geochemical signature; (4) there is a tendency for increasing 87Sr/86Sr, 207Pb/204Pb, and ??18O and decreasing 206Pb/204Pb and 143Nd/144Nd from north to south. The three end-member Cascade magma types reflect contributions from three mantle components: depleted sub-arc mantle modestly enriched in LILE during ancient subduction; a modern, hydrous subduction component

  8. Plume-orogenic lithosphere interaction recorded in the Haladala layered intrusion in the Southwest Tianshan Orogen, NW China

    NASA Astrophysics Data System (ADS)

    He, Peng-Li; Huang, Xiao-Long; Xu, Yi-Gang; Li, Hong-Yan; Wang, Xue; Li, Wu-Xian

    2016-03-01

    The plume-orogenic lithosphere interaction may be common and important for the generation of large igneous provinces. The information regarding such a process is recorded by the Haladala gabbroic intrusion (~300 Ma), the largest layered ultramafic-mafic intrusion hosting V-Ti magnetite deposits in the Southwest Tianshan Orogen, NW China. The Haladala gabbros exhibit unfractionated chondrite-normalized rare earth element patterns with negative Nb and Ta anomalies and positive Pb anomaly on the primitive mantle-normalized multielement variation diagram. They are characterized by low initial Sr isotopes, slightly decoupled but high positive bulk rock ɛNd(t) and ɛHf(t), and high 207Pb/204Pb and 208Pb/204Pb relative to 206Pb/204Pb, delineating a DUPAL signature in the sources. The Haladala gabbros cannot be arc or postcollisional magmatism, given the lack of hydrous minerals and low K contents, respectively. This is further supported by the relatively low oxygen fugacity required for the gradual enrichment of V-Ti magnetite during the magma fractionation and by an overall anhydrous mantle source suggested by troctolite mineral assemblage (olivine + plagioclase). The emplacement age of the Haladala gabbros is identical to that of the Wajilitag kimberlites in the Tarim's interior, which have been interpreted as the first magmatic expression of the Tarim mantle plume. We thus propose that the Haladala gabbroic intrusion was generated in a hybrid geodynamic setting in which the Southwest Tianshan Orogen was impacted by an upwelling mantle plume. In this sense, the Haladala layered gabbroic intrusion records the early phase of magmatism of the Tarim plume, which was preferentially emplaced in a lithospheric weak zone.

  9. Solving petrological problems through machine learning: the study case of tectonic discrimination using geochemical and isotopic data

    NASA Astrophysics Data System (ADS)

    Petrelli, Maurizio; Perugini, Diego

    2016-10-01

    Machine-learning methods are evaluated to study the intriguing and debated topic of discrimination among different tectonic environments using geochemical and isotopic data. Volcanic rocks characterized by a whole geochemical signature of major elements (SiO2, TiO2, Al2O3, Fe2O3T, CaO, MgO, Na2O, K2O), selected trace elements (Sr, Ba, Rb, Zr, Nb, La, Ce, Nd, Hf, Sm, Gd, Y, Yb, Lu, Ta, Th) and isotopes (206Pb/204Pb, 207Pb/204Pb, 208Pb/204Pb, 87Sr/86Sr and 143Nd/144Nd) have been extracted from open-access and comprehensive petrological databases (i.e., PetDB and GEOROC). The obtained dataset has been analyzed using support vector machines, a set of supervised machine-learning methods, which are considered particularly powerful in classification problems. Results from the application of the machine-learning methods show that the combined use of major, trace elements and isotopes allows associating the geochemical composition of rocks to the relative tectonic setting with high classification scores (93 %, on average). The lowest scores are recorded from volcanic rocks deriving from back-arc basins (65 %). All the other tectonic settings display higher classification scores, with oceanic islands reaching values up to 99 %. Results of this study could have a significant impact in other petrological studies potentially opening new perspectives for petrologists and geochemists. Other examples of applications include the development of more robust geothermometers and geobarometers and the recognition of volcanic sources for tephra layers in tephro-chronological studies.

  10. Mantle heterogeneities beneath the Northeast Indian Ocean as sampled by intra-plate volcanism at Christmas Island

    NASA Astrophysics Data System (ADS)

    Taneja, Rajat; Rushmer, Tracy; Blichert-Toft, Janne; Turner, Simon; O'Neill, Craig

    2016-10-01

    The intra-plate region of the Northeast Indian Ocean, located between the Ninetyeast Ridge and the North West Shelf of Australia, contains numerous submerged seamounts and two sub-aerially exposed volcanic island groups. While the Cocos (Keeling) Archipelago is a coral atoll, Christmas Island is the only sub-aerially exposed volcanic island and contains Late Cretaceous, Eocene and Pliocene lavas. The lavas are predominantly basaltic in composition, except for one sampled flow that is trachytic. Although the evolution of the western margin of Australia, and the seismicity in the intra-plate region, has received considerable attention, the origin of the seamount province in the Northeast Indian Ocean is still a matter of debate. In order to constrain the origin of volcanism on Christmas Island and the associated Seamount Province we analysed 14 Christmas Island samples for major and trace element abundances and 12 of these for Nd, Hf and Pb isotope compositions. The trace element patterns of the lavas are similar to many ocean island basalts, while high 208Pb/204Pb and 207Pb/204Pb at a given 206Pb/204Pb suggest affiliation with the DUPAL anomaly. The reconstructed position of Christmas Island during the Eocene (44-37 Ma) places the island in close proximity to the (present-day) upper mantle low-seismic velocity anomalies. Moreover, an enriched mantle (EM-2) type component in addition to the DUPAL anomaly is observed in the Eocene volcanic phase. The younger Pliocene ( 4 Ma) sequences at Christmas Island are inferred to be the product of partial melting of existing material induced by lithospheric flexure.

  11. Syn-collisional granitoids in the Qilian Block on the Northern Tibetan Plateau: A long-lasting magmatism since continental collision through slab steepening

    NASA Astrophysics Data System (ADS)

    Huang, Hui; Niu, Yaoling; Mo, Xuanxue

    2016-03-01

    In this paper we present a new model that can explain the large zircon age spectrum of 510 - 420 Ma within a single sample from the Gangcha (Gcha) biotite granodiorite and the Huangyuan (HY) two-mica monzogranite on the northern Tibetan Plateau. The large age spread recorded in zircons is characteristic of granitoid samples from the studied region, which is best explained by the long-lasting magmatism since the onset of continental collision at 500 Ma, followed by slab steepening and the ultimate slab break-off at 450 Ma. These granitoids have a large major and trace element compositional variation, but limited initial Sr (ISr[450] = 0.709 to 0.715), Nd (ԐNd[450] = - 6.5 to - 3.7), Hf (ԐHf[450] = - 4.3 to 1.5) and Pb (206Pb/204Pb[450] = 17.70 to 17.17; 207Pb/204Pb[450] = 15.60 to 15.69; 208Pb/204Pb[450] = 38.04 to 38.73) isotopic variation. The small negative whole rock ԐNd[450] and ԐHf[450] values are most consistent with the granitoid source being dominated by subducted seafloor materials. The inherited zircons with large negative ԐHf[450] values (e.g. - 50) are indicative of input from the lower continental crust and subducted sediments. The correlated variations among major elements, trace elements and radiogenic isotopes are best interpreted as reflecting melting-induced mixing of a compositionally heterogeneous source with superimposed effect of varying extent of fractional crystallization and crustal assimilation. The inherited zircons of Palaeo-Proterozoic age and the Archean crustal model ages signify the involvement of ancient basement rocks.

  12. Sr-Nd-Pb-Hf isotope systematics of the Hugo Dummett Cu-Au porphyry deposit (Oyu Tolgoi, Mongolia)

    NASA Astrophysics Data System (ADS)

    Dolgopolova, A.; Seltmann, R.; Armstrong, R.; Belousova, E.; Pankhurst, R. J.; Kavalieris, I.

    2013-04-01

    Major and trace element geochemistry including Sr-Nd-Pb-Hf isotopic data are presented for a representative sample suite of Late Devonian to Early Carboniferous plutonic and volcanic rocks from the Hugo Dummett deposit of the giant Oyu Tolgoi porphyry Cu-Au district in South Gobi, Mongolia. Sr and Nd isotopes (whole-rock) show restricted ranges of initial compositions, with positive ɛNdt mainly between + 3.4 and + 7.4 and (87Sr/86Sr)t predominantly between 0.7037 and 0.7045 reflecting magma generation from a relatively uniform juvenile lithophile-element depleted source. Previously dated zircons from the plutonic rocks exhibit a sample-averaged range of ɛHft values of + 11.6 to + 14.5. Depleted-mantle model ages of 420-830 (Nd) and 320-730 Ma (zircon Hf) limit the involvement of pre-Neoproterozoic crust in the petrogenesis of the intermediate to felsic calc-alkaline magmas to, at most, a minor role. Pb isotopes (whole-rock) show a narrow range of unradiogenic initial compositions: 206Pb/204Pb 17.40-17.94, 207Pb/204Pb 15.43-15.49 and 208Pb/204Pb 37.25-37.64, in agreement with Sr-Nd-Hf isotopes indicating the dominance of a mantle component. All four isotopic systems suggest that the magmas from which the large Oyu Tolgoi porphyry system was generated originated predominantly from juvenile material within the subduction-related setting of the Gurvansayhan terrane.

  13. A precise 232Th-208Pb chronology of fine-grained monazite: Age of the Bayan Obo REE-Fe-Nb ore deposit, China

    USGS Publications Warehouse

    Wang, Jingyuan; Tatsumoto, M.; Li, X.; Premo, W.R.; Chao, E.C.T.

    1994-01-01

    We have obtained precise Th-Pb internal isochron ages on monazite and bastnaesite for the world's largest known rare earth elements (REE)-Fe-Nb ore deposit, the Bayan Obo of Inner Mongolia, China. The monazite samples, collected from the carbonate-hosted ore zone, contain extremely small amounts of uranium (less than 10 ppm) but up to 0.7% ThO2. Previous estimates of the age of mineralization ranged from 1.8 to 0.255 Ga. Magnetic fractions of monazite and bastnaesite samples (<60-??m size) showed large ranges in 232Th 204Pb values (900-400,000) and provided precise Th-Pb internal isochron ages for paragenetic monazite mineralization ranging from 555 to 398 Ma within a few percent error (0.8% for two samples). These results are the first indication that REE mineralization within the giant Bayan Obo ore deposit occurred over a long period of time. The initial lead isotopic compositions (low 206Pb 204Pb and high 208Pb 204Pb) and large negative ??{lunate}Nd values for Bayan Obo ore minerals indicate that the main source(s) for the ores was the lower crust which was depleted in uranium, but enriched in thorium and light rare earth elements for a long period of time. Zircon from a quartz monzonite, located 50 km south of the ore complex and thought to be related to Caledonian subduction, gave an age of 451 Ma, within the range of monazite ages. Textural relations together with the mineral ages favor an epigenetic rather than a syngenetic origin for the orebodies. REE mineralization started around 555 Ma (disseminated monazite in the West, the Main, and south of the East Orebody), but the main mineralization (banded ores) was related to the Caledonian subduction event ca. 474-400 Ma. ?? 1994.

  14. Peak power ratio generator

    DOEpatents

    Moyer, R.D.

    A peak power ratio generator is described for measuring, in combination with a conventional power meter, the peak power level of extremely narrow pulses in the gigahertz radio frequency bands. The present invention in a preferred embodiment utilizes a tunnel diode and a back diode combination in a detector circuit as the only high speed elements. The high speed tunnel diode provides a bistable signal and serves as a memory device of the input pulses for the remaining, slower components. A hybrid digital and analog loop maintains the peak power level of a reference channel at a known amount. Thus, by measuring the average power levels of the reference signal and the source signal, the peak power level of the source signal can be determined.

  15. Peak power ratio generator

    DOEpatents

    Moyer, Robert D.

    1985-01-01

    A peak power ratio generator is described for measuring, in combination with a conventional power meter, the peak power level of extremely narrow pulses in the gigahertz radio frequency bands. The present invention in a preferred embodiment utilizes a tunnel diode and a back diode combination in a detector circuit as the only high speed elements. The high speed tunnel diode provides a bistable signal and serves as a memory device of the input pulses for the remaining, slower components. A hybrid digital and analog loop maintains the peak power level of a reference channel at a known amount. Thus, by measuring the average power levels of the reference signal and the source signal, the peak power level of the source signal can be determined.

  16. High-Ratio Gear Train

    NASA Technical Reports Server (NTRS)

    Lefever, A. E.

    1982-01-01

    Proposed arrangement of two connected planetary differentials results in gear ratio many times that obtainable in conventional series gear assembly of comparable size. Ratios of several thousand would present no special problems. Selection of many different ratios is available with substantially similar gear diameters. Very high gear ratios would be obtained from small mechanism.

  17. Investigation of off-site airborne transport of lead from a superfund removal action site using lead isotope ratios and concentrations

    USGS Publications Warehouse

    Pribil, Michael J.; Maddaloni, Mark A.; Staiger, Kimberly; Wilson, Eric; Magriples, Nick; Ali, Mustafa; Santella, Dennis

    2014-01-01

    Lead (Pb) concentration and Pb isotopic composition of surface and subsurface soil samples were used to investigate the potential for off-site air transport of Pb from a former white Pb processing facility to neighboring residential homes in a six block area on Staten Island, NY. Surface and subsurface soil samples collected on the Jewett White Pb site were found to range from 1.122 to 1.138 for 206Pb/207Pb and 2.393 to 2.411 for 208Pb/207Pb. The off-site surface soil samples collected from residential backyards, train trestle, near site grass patches and background areas varied from 1.144 to 1.196 for 206Pb/207Pb and 2.427 to 2.464 for 208Pb/207Pb. Two soil samples collected along Richmond Terrace, where Jewett site soils accumulated after major rain events, varied from 1.136 to 1.147 for 206Pb/207Pb and 2.407 to 2.419 for 208Pb/207Pb. Lead concentration for on-site surface soil samples ranged from 450 to 8000 ug/g, on-site subsurface soil samples ranged from 90,000 to 240,000 ug/g and off-site samples varied from 380 to 3500 ug/g. Lead concentration and isotopic composition for the Staten Island off-site samples were similar to previously published data for other northeastern US cities and reflect re-suspension and re-mobilization of local accumulated Pb. The considerable differences in both the Pb isotopic composition and Pb concentration of on-site and off-site samples resulted in the ability to geochemically trace the transport of particulate Pb. Data in this study indicate minimal off-site surface transport of Pb from the Jewett site into the neighboring residential area.

  18. Low-productivity Hawaiian volcanism between Kaua‘i and O‘ahu

    NASA Astrophysics Data System (ADS)

    Greene, Andrew R.; Garcia, Michael O.; Weis, Dominique; Ito, Garrett; Kuga, Maia; Robinson, Joel; Yamasaki, Seiko

    2010-11-01

    The longest distance between subaerial shield volcanoes in the Hawaiian Islands is between the islands of Kaua`i and O`ahu, where a field of submarine volcanic cones formed astride the axis of the Hawaiian chain during a period of low magma productivity. The submarine volcanoes lie ˜25-30 km west of Ka`ena Ridge that extends ˜80 km from western O`ahu. These volcanoes were sampled by three Jason2 dives. The cones are flat topped, <400 m high and 0.4-2 km in diameter at water depths between ˜2700 and 4300 m, and consist predominantly of pillowed flows. Ar-Ar and K-Ar ages of 11 tholeiitic lavas are between 4.9 and 3.6 Ma. These ages overlap with shield volcanism on Kaua`i (5.1-4.0 Ma) and Wai`anae shield basalts (3.9-3.1 Ma) on O`ahu. Young alkalic lavas (circa 0.37 Ma) sampled southwest of Ka`ena Ridge are a form of offshore secondary volcanism. Half of the volcanic cones contain high-SiO2 basalts (51.0-53.5 wt % SiO2). The trends of isotopic compositions of West Ka`ena tholeiitic lavas diverge from the main Ko`olau-Kea shield binary mixing trend in isotope diagrams and extend to lower 208Pb/204Pb and 206Pb/204Pb than any Hawaiian tholeiitic lava. West Ka`ena tholeiitic lavas have geochemical and isotopic characteristics similar to volcanoes of the Loa trend. Hence, our results show that the Loa-type volcanism has persisted for at least 4.9 Myr, beginning prior to the development of the dual, subparallel chain of volcanoes. Several West Ka`ena samples are similar to higher SiO2, Loa trend lavas of Ko`olau Makapu`u stage, Lāna`i, and Kaho`olawe; these lavas may have been derived from a pyroxenite source in the mantle. The high Ni contents of olivines in West Ka`ena lavas also indicate contribution from pyroxenite-derived melting. Average compositions of Hawaiian shield volcanoes show a clear relation between 206Pb/204Pb and SiO2 within Loa trend volcanoes, which supports a prominent but variable influence of pyroxenite in the Hawaiian plume source. In addition

  19. Two magma bodies beneath the summit of Kīlauea Volcano unveiled by isotopically distinct melt deliveries from the mantle

    NASA Astrophysics Data System (ADS)

    Pietruszka, Aaron J.; Heaton, Daniel E.; Marske, Jared P.; Garcia, Michael O.

    2015-03-01

    The summit magma storage reservoir of Kīlauea Volcano is one of the most important components of the magmatic plumbing system of this frequently active basaltic shield-building volcano. Here we use new high-precision Pb isotopic analyses of Kīlauea summit lavas-from 1959 to the active Halema'uma'u lava lake-to infer the number, size, and interconnectedness of magma bodies within the volcano's summit reservoir. From 1971 to 1982, the 206Pb/204Pb ratios of the lavas define two separate magma mixing trends that correlate with differences in vent location and/or pre-eruptive magma temperature. These relationships, which contrast with a single magma mixing trend for lavas from 1959 to 1968, indicate that Kīlauea summit eruptions since at least 1971 were supplied from two distinct magma bodies. The locations of these magma bodies are inferred to coincide with two major deformation centers identified by geodetic monitoring of the volcano's summit region: (1) the main locus of the summit reservoir ∼2-4 km below the southern rim of Kīlauea Caldera and (2) a shallower magma body <2 km below the eastern rim of Halema'uma'u pit crater. Residence time modeling suggests that the total volume of magma within Kīlauea's summit reservoir during the late 20th century (1959-1982) was exceedingly small (∼0.1-0.5 km3). Voluminous Kīlauea eruptions, such as the ongoing, 32-yr old Pu'u 'Ō'ō rift eruption (>4 km3 of lava erupted), must therefore be sustained by a nearly continuous supply of new melt from the mantle. The model results show that a minimum of four compositionally distinct, mantle-derived magma batches were delivered to the volcano (at least three directly to the summit reservoir) since 1959. These melt inputs correlate with the initiation of energetic (1959 Kīlauea Iki) and/or sustained (1969-1974 Mauna Ulu, 1983-present Pu'u 'Ō'ō and 2008-present Halema'uma'u) eruptions. Thus, Kīlauea's eruptive behavior is partly tied to the delivery of new magma batches

  20. A combined Sm-Nd, Rb-Sr, and U-Pb isotopic study of Mg-suite norite 78238: Further evidence for early differentiation of the Moon

    SciTech Connect

    Edmunson, J; E.Borg, L; Nyquist, L E; Asmerom, Y

    2008-11-17

    Lunar Mg-suite norite 78238 was dated using the Sm-Nd, Rb-Sr, and U-Pb isotopic systems in order to constrain the age of lunar magma ocean solidification and the beginning of Mg-suite magmatism, as well as to provide a direct comparison between the three isotopic systems. The Sm-Nd isotopic system yields a crystallization age for 78238 of 4334 {+-} 37 Ma and an initial {var_epsilon}{sub Nd}{sup 143} value of -0.27 {+-} 0.74. The age-initial {var_epsilon}{sub Nd}{sup 143} (T-I) systematics of a variety of KREEP-rich samples, including 78238 and other Mg-suite rocks, KREEP basalts, and olivine cumulate NWA 773, suggest that lunar differentiation was completed by 4492 {+-} 61 Ma assuming a Chondritic Uniform Reservoir bulk composition for the Moon. The Rb-Sr isotopic systematics of 78238 were disturbed by post-crystallization processes. Nevertheless, selected data points yield two Rb-Sr isochrons. One is concordant with the Sm-Nd crystallization age, 4366 {+-} 53 Ma. The other is 4003 {+-} 95 Ma and is concordant with an Ar-Ar age for 78236. The {sup 207}Pb-{sup 206}Pb age of 4333 {+-} 59 Ma is concordant with the Sm-Nd age. The U-Pb isotopic systematics of 78238 yield linear arrays equivalent to younger ages than the Pb-Pb system, and may reflect fractionation of U and Pb during sample handling. Despite the disturbed nature of the U-Pb systems, a time-averaged {mu} ({sup 238}U/{sup 204}Pb) value of the source can be estimated at 27 {+-} 30 from the Pb-Pb isotopic systematics. Because KREEP-rich samples are likely to be derived from source regions with the highest U/Pb ratios, the relatively low {mu} value calculated for the 78238 source suggests the bulk Moon does not have an exceedingly high {mu} value.

  1. Two magma bodies beneath the summit of Kilauea Volcano unveiled by isotopically distinct melt deliveries from the mantle

    USGS Publications Warehouse

    Pietruszka, Aaron J; Heaton, Daniel E.; Marske, Jared P.; Garcia, Michael O.

    2015-01-01

    The summit magma storage reservoir of Kīlauea Volcano is one of the most important components of the magmatic plumbing system of this frequently active basaltic shield-building volcano. Here we use new high-precision Pb isotopic analyses of Kīlauea summit lavas—from 1959 to the active Halema‘uma‘u lava lake—to infer the number, size, and interconnectedness of magma bodies within the volcano's summit reservoir. From 1971 to 1982, the 206Pb/204Pb ratios of the lavas define two separate magma mixing trends that correlate with differences in vent location and/or pre-eruptive magma temperature. These relationships, which contrast with a single magma mixing trend for lavas from 1959 to 1968, indicate that Kīlauea summit eruptions since at least 1971 were supplied from two distinct magma bodies. The locations of these magma bodies are inferred to coincide with two major deformation centers identified by geodetic monitoring of the volcano's summit region: (1) the main locus of the summit reservoir ∼2–4 km below the southern rim of Kīlauea Caldera and (2) a shallower magma body <2 km below the eastern rim of Halema‘uma‘u pit crater. Residence time modeling suggests that the total volume of magma within Kīlauea's summit reservoir during the late 20th century (1959–1982) was exceedingly small (∼0.1–0.5 km3). Voluminous Kīlauea eruptions, such as the ongoing, 32-yr old Pu‘u ‘Ō‘ō rift eruption (>4 km3 of lava erupted), must therefore be sustained by a nearly continuous supply of new melt from the mantle. The model results show that a minimum of four compositionally distinct, mantle-derived magma batches were delivered to the volcano (at least three directly to the summit reservoir) since 1959. These melt inputs correlate with the initiation of energetic (1959 Kīlauea Iki) and/or sustained (1969–1974 Mauna Ulu, 1983-present Pu‘u ‘Ō‘ō and 2008-present Halema‘uma‘u) eruptions. Thus, Kīlauea's eruptive behavior is partly tied to

  2. Geochemical Evolution of the Louisville Seamount Chain

    NASA Astrophysics Data System (ADS)

    Vanderkluysen, L.; Mahoney, J. J.; Koppers, A. A.; Lonsdale, P. F.

    2007-12-01

    The Louisville seamount chain is a 4300 km long chain of submarine volcanoes in the southwestern Pacific that is commonly thought to represent a hotspot track. It spans an ~80 Myr age range, comparable to that of the Hawaiian-Emperor chain (Koppers et al., G-cubed, 5 (6), 2004). The few previously dredged igneous samples are dominantly basaltic and alkalic, and have been inferred to represent post-shield volcanism (Hawkins et al., AGU Monograph, 43, 235, 1987). Their isotope and trace element signatures suggest an unusually homogenous mantle source (Cheng et al., AGU Monograph, 43, 283, 1987). Dredging in 2006, during the AMAT02RR cruise of the R.V. Revelle, was carried out in the hope of recovering both shield and post-shield samples and of exploring the geochemical evolution of the chain. Igneous rocks were recovered from 33 stations on 23 seamounts covering some 47 Myr of the chain's history. Our study, focusing on the major and trace element and Sr, Nd and Pb isotopic characteristics of these samples, shows that all are alkalic basalts, basanites and tephrites containing normative nepheline. Variations in major and trace elements appear to be controlled predominantly by variable extents of melting and fractional crystallization, with little influence from mantle source heterogeneity. Indeed, age-corrected isotopic values define only a narrow range, in agreement with long-term source homogeneity relative to the scale of melting; e.g., ɛNd varies from +4.1 to +5.7, 206Pb/204Pb from 19.048 to 19.281, and 87Sr/86Sr from 0.70362 to 0.70398. These values broadly fall within the fields of the proposed "C" or "FOZO" mantle end-members. However, small variations are present, with less radiogenic Nd and Pb isotope ratios at the older, western end of the chain, defining a trend toward a broadly EM2-like composition. Although some workers have postulated that the Louisville hotspot was the source of the ~120 Myr Ontong Java Plateau, our samples are isotopically distinct

  3. The He isotope composition of the earliest picrites erupted by the Ethiopia plume, implications for mantle plume source

    NASA Astrophysics Data System (ADS)

    Stuart, Finlay; Rogers, Nick; Davies, Marc

    2016-04-01

    The earliest basalts erupted by mantle plumes are Mg-rich, and typically derived from mantle with higher potential temperature than those derived from the convecting upper mantle at mid-ocean ridges and ocean islands. The chemistry and isotopic composition of picrites from CFB provide constraints on the composition of deep Earth and thus the origin and differentiation history. We report new He-Sr-Nd-Pb isotopic composition of the picrites from the Ethiopian flood basalt province from the Dilb (Chinese Road) section. They are characterized by high Fe and Ti contents for MgO = 10-22 wt. % implying that the parent magma was derived from a high temperature low melt fraction, most probably from the Afar plume head. The picrite 3He/4He does not exceed 21 Ra, and there is a negative correlation with MgO, the highest 3He/4He corresponding to MgO = 15.4 wt. %. Age-corrected 87Sr/86Sr (0.70392-0.70408) and 143Nd/144Nd (0.512912-0.512987) display little variation and are distinct from MORB and OIB. Age-corrected Pb isotopes display a significant range (e.g. 206Pb/204Pb = 18.70-19.04) and plot above the NHRL. These values contrast with estimates of the modern Afar mantle plume which has lower 3He/4He and Sr, Nd and Pb isotope ratios that are more comparable with typical OIB. These results imply either interaction between melts derived from the Afar mantle plume and a lithospheric component, or that the original Afar mantle plume had a rather unique radiogenic isotope composition. Regardless of the details of the origins of this unusual signal, our observations place a minimum 3He/4He value of 21 Ra for the Afar mantle plume, significantly greater than the present day value of 16 Ra, implying a significant reduction over 30 Myr. In addition the Afar source was less degassed than convecting mantle but more degassed than mantle sampled by the proto-Iceland plume (3He/4He ~50 Ra). This suggests that the largest mantle plumes are not sourced in a single deep mantle domain with a

  4. Provenance of the late Proterozoic to early Cambrian metaclastic sediments of the Sierra de San Luis (Eastern Sierras Pampeanas) and Cordillera Oriental, Argentina

    NASA Astrophysics Data System (ADS)

    Drobe, Malte; López de Luchi, Mónica G.; Steenken, André; Frei, Robert; Naumann, Rudolf; Siegesmund, Siegfried; Wemmer, Klaus

    2009-10-01

    Provenance studies have been performed utilising major and trace elements, Nd systematics, whole rock Pb-Pb isotopes and zircon U/Pb SHRIMP data on metasedimentary rocks of the Sierra de San Luis (Nogolí Metamorphic Complex, Pringles Metamorphic Complex, Conlara Metamorphic Complex and San Luis Formation) and the Puncoviscana Formation of the Cordillera Oriental. The goal was the characterisation of the different domains in the study area and to give insights to the location of the source rocks. An active continental margin setting with typical composition of the upper continental crust is depicted for all the complexes using major and trace elements. The Pringles Metamorphic Complex shows indications for crustal recycling, pointing to a bimodal provenance. Major volcanic input has to be rejected due to Th/Sc, Y/Ni and Cr/V ratios for all units. The ɛNd (540 Ma) data is lower for the San Luis Formation and higher for the Conlara Metamorphic Complex, as compared to the other units, in which a good consistency is given. This is similar to the TDM ages, where the metapsammitic samples of the San Luis Formation are slightly older. The spread of data is largest for the Pringles Metamorphic Complex, again implying two different sources. The whole rock 207Pb/ 206Pb isotopic data lies in between the South American and African sources, excluding Laurentian provenances. The whole rock Pb-Pb data is almost indistinguishable in the different investigated domains. Only the PMC shows slightly elevated 208Pb/ 204Pb values. Possible source rocks for the different domains could be the Quebrada Choja in the Central Arequipa-Antofalla domain, the Southern domain of the Arequipa-Antofalla basement, the Brazilian shield or southern Africa. Zircon SHRIMP data point to a connection between the Puncoviscana Formation and the Conlara Metamorphic Complex. Two maxima around 600 Ma and around 1000 Ma have been determined. The Nogolí Metamorphic Complex and the Pringles Metamorphic Complex

  5. Geochemical and Sr-Nd-Pb isotope constraints on the petrogenesis of the K-rich Pedra Branca Syenite: Implications for the Neoproterozoic post-collisional magmatism in SE Brazil

    NASA Astrophysics Data System (ADS)

    Carvalho, Bruna Borges; Janasi, Valdecir de Assis; Henrique-Pinto, Renato

    2014-09-01

    The Pedra Branca Syenite is a 610 Ma post-collisional pluton intrusive in the Socorro-Guaxupé Nappe, an allochthonous terrain emplaced at the SW border of the São Francisco craton, Brazil. The pluton is largely dominated by laminated syenites with colour index 20-25 displayed in a zoned structure, with a first unit of marginally peralkaline silica-saturated syenites exposed at its E and N border intruded by silica-oversaturated metaluminous syenites making up its core. Mafic to ultramafic coarse-grained enclaves and lenses are frequent in the laminated units, and must correspond to disrupted cumulate layers. Fine-grained enclaves are rare, and vary from microsyenites, which seem to be products of new magma pulses frozen within mushy portions of the magma chamber, to monzonites and diorites, which reflect the existence of contemporaneous “basalt” (plagioclase-bearing) magmas that interacted with the syenitic magmas at greater depths and were carried up during ascension. All syenitic units share important geochemical signatures with high contents of LILE such as Ba (4000-10,000 ppm) and Sr (2000-4500 ppm), as well as P2O5 (1-2%) and have strongly fractionated LREE patterns ((La/Yb)N = 40-120; La = 100-400 ppm). An important contrast between silica-oversaturated and saturated syenites is the higher Al2O3 content in the former, reflected in higher normative anorthite, mostly hosted in high temperature alkali feldspar. The Pedra Branca syenites have 87Sr/86Sr(t) = 0.7077 to 0.7078 and unradiogenic Nd (ɛNd(t) ~ - 8) and Pb (206Pb/204Pb = 17.2-17.3); this isotope signature, associated with high LREE/HFS ratios indicates that the parent melts were generated in enriched (metasomatic phlogopite-clinopyroxenite) portions of the shallow (lithospheric) continental mantle affected by previous subduction. The chemical characteristics of the silica-oversaturated syenites and their association with microgranular dioritic enclaves are suggestive that their contrasts with the

  6. Noble gas isotope signals of mid-ocean ridge basalts and their implication for upper mantle structure

    NASA Astrophysics Data System (ADS)

    Stroncik, Nicole A.; Niedermann, Samuel

    2016-04-01

    The geochemical structure of the upper mantle in general and its noble gas isotopic structure in particular have been the subject of countless studies, as both provide important insights into mantle dynamic processes and are essential for the formulation of mantle geodynamic models. This contribution presents a noble gas study of basaltic glasses derived from the Mid-Atlantic-Ridge (MAR) between 4 and 12° S, an area well known for its high degree of lithophile isotope heterogeneity and exhibiting anomalous crustal thickness. The Sr, Nd, Pb and Hf isotopies along this segment of the MAR range from ultra-depleted (more than NMORB) to highly enriched, and different concepts have been proposed to explain the observed isotopic signatures. Here we show that the high degree of heterogeneity is not confined to the isotopes of the lithophile elements, but is also shown by the noble gas isotopes and noble gas interelement ratios, such as e.g. 3He/22NeM or 4He/40Ar*. 3He/4He, 21Ne/22Neextra and 40Ar/36Ar range from 7.3 to 9.3 RA, from 0.05 to 0.08, and from 346 to 37,400, respectively. Nevertheless, the majority of the Ne isotope data are clearly aligned along a single mixing line in the Ne-three-isotope diagram, represented by the equation 20Ne/22Ne=70.5 x 21Ne/22Ne + 7.782, with a slope distinctly different from that of the MORB line, indicating that the ultra-depleted material is characterised by a significantly more nucleogenic 21Ne/22Ne isotopy than the normal depleted mantle. We show, based on covariations between 3He/4He and 21Ne/22Neextra with 206Pb/204Pb and 178Hf/177Hf, that the ultra-depleted material erupted at this MAR segment was most likely produced by an ancient, deep melting event. This implies that isotopic heterogeneities in the upper mantle are not solely caused by the injection of enriched materials from deep-seated mantle plumes or by crustal recycling but may also be due to differences in the depth and degree of melting of upper mantle material within

  7. The Banhadão Alkaline Complex, Southeastern Brazil: source and evolution of potassic SiO2-undersaturated high-Ca and low-Ca magmatic series

    NASA Astrophysics Data System (ADS)

    Ruberti, Excelso; Enrich, Gaston E. R.; Azzone, Rogério G.; Comin-Chiaramonti, Piero; de Min, Angelo; Gomes, Celso B.

    2012-01-01

    and REE chondrite-normalized patterns as compared to the low-Ca series. The 87Sr/86Sr, 143Nd/144Nd, 206Pb/204Pb and 208Pb/204Pb initial ratios for the high-Ca series (0.70407-0.70526, 0.51242-0.51251, 17.782-19.266 and 38.051-39.521, respectively) were slightly different from those of the low-Ca series (0.70542-0.70583, 0.51232-0.51240, 17.758-17.772 and 38.021-38.061, respectively). For both series, a CO2-rich potassic metasomatized lithospheric mantle enriched the source with rutile-bearing phlogopite clinopyroxenite veins. Kamafugite-like parental magma is attributed to the high-Ca series with major contributions from the melting of the veins. Potassic nephelinite-like parental magma is assigned to the low-Ca series, where the metasomatized wall-rock played a more significant role in the melting process.

  8. Mo-mineralized porphyries are relatively hydrous and differentiated: insights from the Permian-Triassic granitic complex in the Baituyingzi Mo-Cu district, eastern Inner Mongolia, NE China

    NASA Astrophysics Data System (ADS)

    Sun, Yan; Liu, Jianming; Zeng, Qingdong; Wang, Jingbin; Wang, Yuwang; Hu, Ruizhong; Zhou, Lingli; Wu, Guanbin

    2016-12-01

    Mo-Cu mineralization in the Baituyingzi district of eastern Inner Mongolia occurs within a granitic complex. This paper presents and discusses zircon U-Pb ages and whole-rock geochemical and Sr-Nd-Pb isotopic data from the granitic complex as potential indicators for porphyry Mo fertility. The U-Pb ages indicate that five units of the granitic complex were emplaced between 265.2 ± 0.7 and 246.5 ± 1.0 Ma. Constrained by crosscutting dikes, Mo-Cu mineralization was probably related to the Baituyingzi monzogranite porphyry dated at 248.2 ± 0.64 Ma. The intrusions belong to high-K calc-alkaline to shoshonitic series that are characterized by highly fractionated rare earth element (REE) patterns and strong enrichments of large ion lithophile elements, relative to high-field strength elements. Apart from the ˜246-Ma dike that shows negative ɛNd (t) values (-14.9 to -13.1), the intrusions have ɛNd(t) values ranging from -3.9 to 1.0, relatively young depleted mantle model ages (811 to 1183 Ma), 206Pb/204Pb of 18.137-18.335, and 207Pb/204Pb of 15.591-15.625, which are consistent with a juvenile lower crustal origin. Among the intrusions, the ˜248-Ma porphyry and the ˜246-Ma dike show adakite-like characteristics (e.g., Sr/Y = 44.9-185) and listric-shaped REE patterns that indicate amphibole fractionation and a hydrous magma source. However, the porphyry exhibits a higher differentiation index (81.4-91.5) and a steeper REE profile (e.g., LaN/YbN = 25.6-87.0) than those of the ˜246-Ma dike, which suggests that it is highly differentiated. We propose that the complex was generated by the partial melting of juvenile mafic lower crust (containing minor old crustal relicts) that was triggered by collision between the North China Craton and Siberian Craton. As indicated by the Th/Nb, Th/Yb, Ba/Th, and Ba/La ratios of the intrusions, the crust may have been derived from the melting of the fertile mantle wedge that was metasomatized by various amounts of slab-derived fluids

  9. Petrogenesis of Post-collisional high Ba-Sr granitoids: the Solarya Pluton, NW Turkey

    NASA Astrophysics Data System (ADS)

    Unal, Alp; Kamaci, Omer; Altunkaynak, Safak

    2015-04-01

    In NW Turkey, the Late Oligocene-Early Miocene phase of post-collisional magmatism is characterized by widespread granitic pluton emplacements straddling the continental collision zone marked by the Izmir-Ankara suture zone (IASZ). This granitic magmatism produced both low Ba-Sr- and high Ba-Sr granitoids with distinct geochemical properties. One of the major plutons emplaced to the north of İzmir-Ankara suture zone, the Solarya pluton is representative of high Ba-Sr granitoids. We present here whole-rock chemical and Sr-Nd-Pb-O isotopic compositions, as well as 40Ar/39Ar ages of the Solarya pluton to evaluate the timing, nature and genesis of potassic, high Ba-Sr granites. The Solarya pluton consists of three coeval granitic members (K-Feldspar megacrystalline granodiorite, fine grained granodiorite and haplogranite) and associated mafic magmatic enclaves/dykes of gabbroic diorite to dioritic in composition. K-feldspar megacrystalline granodiorite, fine grained granodiorite and haplogranite are high K calc-alkaline in character whereas low silica mafic magmatic enclaves and dykes are mildly alkaline and display shoshonitic affinity. Both granitic members and mafic enclaves/dykes are characterized by high Ba (710-2489 ppm), Sr (305-708ppm), low Y and HREE contents and lack of significant negative Eu anomalies. They are metaluminous and display enrichment in LILE and depletion in P, Ta, Nb and Ti. Sr-Nd-Pb and O isotope compositions of mafic enclaves and dykes are similar to their host granitoids. They have initial 87Sr/86Sr values of 0.70702- 0.70805 and 143Nd/144Nd values of 0.51235-0.51250 and their ɛNd values range between -4,9 and -2,05. 206Pb/204Pb and 207Pb/204 Pb isotopic values vary from 18,75 to 18,88 and 15,68 to 15,73, respectivelly. Whole rock and quartz 18O isotopic ratios range between 8 and 10,6. All these isotopic characteristics and major-trace element compositions of Solarya pluton and associated mafic enclaves/dykes suggest a subcontinental

  10. An atmospheric lead source-areas apportionment study in Europe

    NASA Astrophysics Data System (ADS)

    Flament, P.; Deboudt, K.; Bertho, M.-L.; Véron, A.; Puskaric, E.

    2003-05-01

    Atmospheric particulate matter samples, for which the origin of aerosols was unambiguousty determined, has been collected in the Eastern Channel (Northem France). Associated lead concentrations are higher by a factor of about 7, when air masses are runnig from continental Europe, by comparison with marine air masses. We statistically evidence that air masses originating from continental Europe exhibit a more radiogenic composition (1.134<^{206}Pb/^{207}Pb<1.172) than air masses coming from British Islands (1.106<^{206}Pb/^{207}Pb<1.1243. Generally, lead isotopic compositions in aerosols are dearly distinct from the gasoline signatures in European countries, strongly suggesting that automotive lead is no more the major component of this metal in the air. Gasoline and industrial isotopic signatures could explain the origin of lead in our aerosol samples. A source apportionment based upon ^{206}Pb/^{207}Pb ratios suggests that thé difference between British (^{206}Pb/^{207}Pb = 1.122 ± 0.038) and continental (^{206}Pb/^{207}Pb = 1.155 ± 0.022) signatures may be explained by differenees iro the petrol leard content of aerosols (23 to 62% in Great Britain versus 10 to 36% in continental Europe).

  11. Ratio estimation in SIMS analysis

    NASA Astrophysics Data System (ADS)

    Ogliore, R. C.; Huss, G. R.; Nagashima, K.

    2011-09-01

    The determination of an isotope ratio by secondary ion mass spectrometry (SIMS) traditionally involves averaging a number of ratios collected over the course of a measurement. We show that this method leads to an additive positive bias in the expectation value of the estimated ratio that is approximately equal to the true ratio divided by the counts of the denominator isotope of an individual ratio. This bias does not decrease as the number of ratios used in the average increases. By summing all counts in the numerator isotope, then dividing by the sum of counts in the denominator isotope, the estimated ratio is less biased: the bias is approximately equal to the ratio divided by the summed counts of the denominator isotope over the entire measurement. We propose a third ratio estimator (Beale's estimator) that can be used when the bias from the summed counts is unacceptably large for the hypothesis being tested. We derive expressions for the variance of these ratio estimators as well as the conditions under which they are normally distributed. Finally, we investigate a SIMS dataset showing the effects of ratio bias, and discuss proper ratio estimation for SIMS analysis.

  12. A lead isotopic study of the human bioaccessibility of lead in urban soils from Glasgow, Scotland.

    PubMed

    Farmer, John G; Broadway, Andrew; Cave, Mark R; Wragg, Joanna; Fordyce, Fiona M; Graham, Margaret C; Ngwenya, Bryne T; Bewley, Richard J F

    2011-11-01

    The human bioaccessibility of lead (Pb) in Pb-contaminated soils from the Glasgow area was determined by the Unified Bioaccessibility Research Group of Europe (BARGE) Method (UBM), an in vitro physiologically based extraction scheme that mimics the chemical environment of the human gastrointestinal system and contains both stomach and intestine compartments. For 27 soils ranging in total Pb concentration from 126 to 2160 mg kg(-1) (median 539 mg kg(-1)), bioaccessibility as determined by the 'stomach' simulation (pH ~1.5) was 46-1580 mg kg(-1), equivalent to 23-77% (mean 52%) of soil total Pb concentration. The corresponding bioaccessibility data for the 'stomach+intestine' simulation (pH ~6.3) were 6-623 mg kg(-1) and 2-42% (mean 22%) of soil Pb concentration. The soil (206)Pb/(207)Pb ratios ranged from 1.057 to 1.175. Three-isotope plots of (208)Pb/(206)Pb against (206)Pb/(207)Pb demonstrated that (206)Pb/(207)Pb ratios were intermediate between values for source end-member extremes of imported Australian Pb ore (1.04)--used in the manufacture of alkyl Pb compounds (1.06-1.10) formerly added to petrol--and indigenous Pb ores/coal (1.17-1.19). The (206)Pb/(207)Pb ratios of the UBM 'stomach' extracts were similar (<0.01 difference) to those of the soil for 26 of the 27 samples (r=0.993, p<0.001) and lower in 24 of them. A slight preference for lower (206)Pb/(207)Pb ratio was discernible in the UBM. However, the source of Pb appeared to be less important in determining the extent of UBM-bioaccessible Pb than the overall soil total Pb concentration and the soil phases with which the Pb was associated. The significant phases identified in a subset of samples were carbonates, manganese oxides, iron-aluminium oxyhydroxides and clays.

  13. Lidar ratio and depolarization ratio for cirrus clouds.

    PubMed

    Chen, Wei-Nai; Chiang, Chih-Wei; Nee, Jan-Bai

    2002-10-20

    We report on studies of the lidar and the depolarization ratios for cirrus clouds. The optical depth and effective lidar ratio are derived from the transmission of clouds, which is determined by comparing the backscattering signals at the cloud base and cloud top. The lidar signals were fitted to a background atmospheric density profile outside the cloud region to warrant the linear response of the return signals with the scattering media. An average lidar ratio, 29 +/- 12 sr, has been found for all clouds measured in 1999 and 2000. The height and temperature dependences ofthe lidar ratio, the optical depth, and the depolarization ratio were investigated and compared with results of LITE and PROBE. Cirrus clouds detected near the tropopause are usually optically thin and mostly subvisual. Clouds with the largest optical depths were found near 12 km with a temperature of approximately -55 degrees C. The multiple-scattering effect is considered for clouds with high optical depths, and this effect lowers the lidar ratios compared with a single-scattering condition. Lidar ratios are in the 20-40 range for clouds at heights of 12.5-15 km and are smaller than approximately 30 in height above 15 km. Clouds are usually optically thin for temperatures below approximately -65 degrees C, and in this region the optical depth tends to decrease with height. The depolarization ratio is found to increase with a height at 11-15 km and smaller than 0.3 above 16 km. The variation in the depolarization ratio with the lidar ratio was also reported. The lidar and depolarization ratios were discussed in terms of the types of hexagonal ice crystals.

  14. The origin of the Maozu carbonate-hosted Pb-Zn deposit, southwest China: Constrained by C-O-S-Pb isotopic compositions and Sm-Nd isotopic age

    NASA Astrophysics Data System (ADS)

    Zhou, Jiaxi; Huang, Zhilong; Yan, Zaifei

    2013-09-01

    The Maozu Pb-Zn deposit, located on the western margin of the Yangtze Block, southwest China, is a typical carbonate-hosted deposit in the Sichuan-Yunnan-Guizhou Pb-Zn metallogenic province with Pb + Zn reserves of about 2.0 million tonnes grading 4.15 wt.% Pb and 7.25 wt.% Zn. Its ore bodies are hosted in Sinian (635-541 Ma) Dengying Formation dolostone and show stratiform, vein and irregular textures. Ores are composed of sphalerite, galena, pyrite, calcite, dolomite, quartz and fluorite with massive, banded, disseminated and veined structures. The C-O-Sm-Nd isotopic compositions of hydrothermal calcites and S-Pb isotopic compositions of sulfides were analyzed to constrain the origin of the Maozu deposit. δ13CPDB and δ18OSMOW values of hydrothermal calcites range from -3.7‰ to -2.0‰ and +13.8‰ to +17.5‰, respectively, and plot near the marine carbonate rocks field in a plot of δ13CPDB vs. δ18OSMOW, with a negative correlation. It suggests that CO2 in the hydrothermal fluids was mainly originated from marine carbonate rocks, with limited influence from sedimentary organic matter. δ34SCDT values of sulfides range from +9.9‰ to +19.2‰, similar to that of Cambrian to Triassic seawater sulfate (+15‰ to +35‰) and evaporate (+15‰ to +30‰) in the Cambrian to Triassic sedimentary strata. It suggests that reduced sulfur was derived from evaporate in sedimentary strata by thermo chemical sulfate reduction. Sulfides have low radiogenic Pb isotope compositions (206Pb/204Pb = 18.129-18.375, 207Pb/204Pb = 15.640-15.686 and 208Pb/204Pb = 38.220-38.577) that plot in the field between upper crust and the orogenic belt evolution curve in the plot of 207Pb/204Pb vs. 206Pb/204Pb, and similar to that of age corrected Proterozoic basement rocks (Dongchuan and Kunyang Groups). This indicates that ore-forming metals were mainly derived from basement rocks. Hydrothermal calcite yields a Sm-Nd isotopic age of 196 ± 13 Ma, possibly reflecting the timing of Pb

  15. Sex Ratio Elasticity Influences the Selection of Sex Ratio Strategy.

    PubMed

    Wang, Yaqiang; Wang, Ruiwu; Li, Yaotang; Sam Ma, Zhanshan

    2016-12-23

    There are three sex ratio strategies (SRS) in nature-male-biased sex ratio, female-biased sex ratio and, equal sex ratio. It was R. A. Fisher who first explained why most species in nature display a sex ratio of ½. Consequent SRS theories such as Hamilton's local mate competition (LMC) and Clark's local resource competition (LRC) separately explained the observed deviations from the seemingly universal 1:1 ratio. However, to the best of our knowledge, there is not yet a unified theory that accounts for the mechanisms of the three SRS. Here, we introduce the price elasticity theory in economics to define sex ratio elasticity (SRE), and present an analytical model that derives three SRSs based on the following assumption: simultaneously existing competitions for both resources A and resources B influence the level of SRE in both sexes differently. Consequently, it is the difference (between two sexes) in the level of their sex ratio elasticity that leads to three different SRS. Our analytical results demonstrate that the elasticity-based model not only reveals a highly plausible mechanism that explains the evolution of SRS in nature, but also offers a novel framework for unifying two major classical theories (i.e., LMC &LRC) in the field of SRS research.

  16. Sex Ratio Elasticity Influences the Selection of Sex Ratio Strategy

    PubMed Central

    Wang, Yaqiang; Wang, Ruiwu; Li, Yaotang; (Sam) Ma, Zhanshan

    2016-01-01

    There are three sex ratio strategies (SRS) in nature—male-biased sex ratio, female-biased sex ratio and, equal sex ratio. It was R. A. Fisher who first explained why most species in nature display a sex ratio of ½. Consequent SRS theories such as Hamilton’s local mate competition (LMC) and Clark’s local resource competition (LRC) separately explained the observed deviations from the seemingly universal 1:1 ratio. However, to the best of our knowledge, there is not yet a unified theory that accounts for the mechanisms of the three SRS. Here, we introduce the price elasticity theory in economics to define s