Science.gov

Sample records for 3c-6h polytypic transition

  1. Polytypism in superhard transition-metal triborides

    PubMed Central

    Liang, Yongcheng; Yang, Jiong; Yuan, Xun; Qiu, Wujie; Zhong, Zheng; Yang, Jihui; Zhang, Wenqing

    2014-01-01

    The quest of novel compounds with special structures and unusual functionalities continues to be a central challenge to modern materials science. Even though their exact structures have puzzled scientists for decades, superhard transition-metal borides (TMBs) have long been believed to exist only in simple crystal structures. Here, we report on a polytypic phenomenon in superhard WB3 and MoB3 with a series of energetically degenerate structures due to the random stacking of metal layers amongst the interlocking boron layers. Such polytypism can create a multiphase solid-solution compound with a large number of interfaces amongst different polytypes, and these interfaces will strongly hinder the interlayer sliding movement within each polytype, thereby further increase the hardness of this particular material. Furthermore, in contrast to the conventional knowledge that intrinsically strong chemical bonds in superhard materials should lead to high lattice thermal conductivity, the polytypic TMB3 manifest anomalously low lattice thermal conductivity due to structural disorders and phonon folding. These findings promise to open a new avenue to searching for novel superhard materials with additional functionalities. PMID:24863493

  2. Polytypism in superhard transition-metal triborides.

    PubMed

    Liang, Yongcheng; Yang, Jiong; Yuan, Xun; Qiu, Wujie; Zhong, Zheng; Yang, Jihui; Zhang, Wenqing

    2014-05-27

    The quest of novel compounds with special structures and unusual functionalities continues to be a central challenge to modern materials science. Even though their exact structures have puzzled scientists for decades, superhard transition-metal borides (TMBs) have long been believed to exist only in simple crystal structures. Here, we report on a polytypic phenomenon in superhard WB3 and MoB3 with a series of energetically degenerate structures due to the random stacking of metal layers amongst the interlocking boron layers. Such polytypism can create a multiphase solid-solution compound with a large number of interfaces amongst different polytypes, and these interfaces will strongly hinder the interlayer sliding movement within each polytype, thereby further increase the hardness of this particular material. Furthermore, in contrast to the conventional knowledge that intrinsically strong chemical bonds in superhard materials should lead to high lattice thermal conductivity, the polytypic TMB3 manifest anomalously low lattice thermal conductivity due to structural disorders and phonon folding. These findings promise to open a new avenue to searching for novel superhard materials with additional functionalities.

  3. Trisodium citrate, Na3(C6H5O7)

    PubMed Central

    Rammohan, Alagappa; Kaduk, James A.

    2016-01-01

    The crystal structure of anhydrous tris­odium citrate, Na3(C6H5O7), has been solved and refined using synchrotron X-ray powder diffraction data, and optimized using density functional theory (DFT). There are two independent five-coordinate Na+ and one six-coordinate Na+ cations in the asymmetric unit. The [NaO5] and [NaO6] polyhedra share edges and corners to form a three-dimensional framework. There are channels parallel to the a and b axes in which the remainder of the citrate anions reside. The only hydrogen bonds are an intra­molecular one between the hy­droxy group and one of the terminal carboxyl­ate O atoms and an intermolecular one between a methylene group and the hydroxyl O atom. PMID:27308044

  4. Polytypic phase transitions in metal intercalated Bi2Se3

    NASA Astrophysics Data System (ADS)

    Wang, Mengjing; Koski, Kristie J.

    2016-12-01

    The temperature and concentration dependent phase diagrams of zero-valent copper, cobalt, and iron intercalated bismuth selenide are investigated using in situ transmission electron microscopy. Polytypic phase transitions associated with superlattice formation along with order-disorder transitions of the guest intercalant are determined. Dual-element intercalants of CuCo, CuFe, and CoFe-Bi2Se3 are also investigated. Hexagonal and striped domain formation consistent with two-dimensional ordering of the intercalant and Pokrovksy-Talapov theory is identified as a function of concentration. These studies provide a complete picture of the structural behavior of zero-valent metal intercalated Bi2Se3.

  5. Polymorphic polytypic transition induced in crystals by interaction of spirals and 2D growth mechanisms

    NASA Astrophysics Data System (ADS)

    Aquilano, Dino; Veesler, Stéphane; Astier, Jean Pierre; Pastero, Linda

    2003-01-01

    The relationship between crystal polymorphism and polytypism can be revealed by surface patterns through the interlacing of the growth spirals. Simple high-symmetry structures as SiC, ZnS, CdI2 and more complex low-symmetry layered structures as n-paraffins, n-alcohols and micas are concerned with polymorphic-polytypic transition. In this paper, we will show for the first time, through in situ AFM observations and X-ray diffractometry, that a protein polymorph (P2 12 12 1α-amylase) locally changes, during growth, to a monoclinic P2 1 polytype, thanks to the screw dislocation activity. The interplay between spiral steps and 2D nuclei of the polytypes coexisting in the same crystalline individual allows to foresee the consequences on the crystal quality. The discussion is extended to other mineral and biological molecules and a new general rule is proposed to explain the interactions between surface patterns and the bulk crystal structure.

  6. Vapor-Liquid Equilibrium in the Mixture Trichloromethane CHCl3 + C6H10O Cyclohexanone (EVLM1111, LB5654_E)

    NASA Astrophysics Data System (ADS)

    Cibulka, I.; Fontaine, J.-C.; Sosnkowska-Kehiaian, K.; Kehiaian, H. V.

    This document is part of Subvolume A 'Binary Liquid Systems of Nonelectrolytes I' of Volume 26 'Heats of Mixing, Vapor-Liquid Equilibrium, and Volumetric Properties of Mixtures and Solutions' of Landolt-Börnstein Group IV 'Physical Chemistry'. It contains the Chapter 'Vapor-Liquid Equilibrium in the Mixture Trichloromethane CHCl3 + C6H10O Cyclohexanone (EVLM1111, LB5654_E)' providing data from direct measurement of pressure at variable mole fraction in liquid phase and constant temperature.

  7. Volumetric Properties of the Mixture Trichloroethene C2HCl3 + C6H14O Hexan-1-ol (VMSD1511, LB4852_V)

    NASA Astrophysics Data System (ADS)

    Cibulka, I.; Fontaine, J.-C.; Sosnkowska-Kehiaian, K.; Kehiaian, H. V.

    This document is part of Subvolume C 'Binary Liquid Systems of Nonelectrolytes III' of Volume 26 'Heats of Mixing, Vapor-Liquid Equilibrium, and Volumetric Properties of Mixtures and Solutions' of Landolt-Börnstein Group IV 'Physical Chemistry'. It contains the Chapter 'Volumetric Properties of the Mixture Trichloroethene C2HCl3 + C6H14O Hexan-1-ol (VMSD1511, LB4852_V)' providing data from direct measurement of low-pressure thermodynamic speed of sound at variable mole fraction and constant temperature, in the single-phase region(s).

  8. Volumetric Properties of the Mixture Trichloromethane CHCl3 + C6H14O Hexan-1-ol (VMSD1412, LB5058_V)

    NASA Astrophysics Data System (ADS)

    Cibulka, I.; Fontaine, J.-C.; Sosnkowska-Kehiaian, K.; Kehiaian, H. V.

    This document is part of Subvolume C 'Binary Liquid Systems of Nonelectrolytes III' of Volume 26 'Heats of Mixing, Vapor-Liquid Equilibrium, and Volumetric Properties of Mixtures and Solutions' of Landolt-Börnstein Group IV 'Physical Chemistry'. It contains the Chapter 'Volumetric Properties of the Mixture Trichloromethane CHCl3 + C6H14O Hexan-1-ol (VMSD1412, LB5058_V)' providing data by calculation of isentropic compressibility from low-pressure density and thermodynamic speed of sound data at variable mole fraction and constant temperature, in the single-phase region(s).

  9. Volumetric Properties of the Mixture Trichloroethene C2HCl3 + C6H14O Hexan-1-ol (VMSD1412, LB4858_V)

    NASA Astrophysics Data System (ADS)

    Cibulka, I.; Fontaine, J.-C.; Sosnkowska-Kehiaian, K.; Kehiaian, H. V.

    This document is part of Subvolume C 'Binary Liquid Systems of Nonelectrolytes III' of Volume 26 'Heats of Mixing, Vapor-Liquid Equilibrium, and Volumetric Properties of Mixtures and Solutions' of Landolt-Börnstein Group IV 'Physical Chemistry'. It contains the Chapter 'Volumetric Properties of the Mixture Trichloroethene C2HCl3 + C6H14O Hexan-1-ol (VMSD1412, LB4858_V)' providing data by calculation of isentropic compressibility from low-pressure density and thermodynamic speed of sound data at variable mole fraction and constant temperature, in the single-phase region(s).

  10. Volumetric Properties of the Mixture Trichloromethane CHCl3 + C6H14O Hexan-1-ol (VMSD1511, LB5055_V)

    NASA Astrophysics Data System (ADS)

    Cibulka, I.; Fontaine, J.-C.; Sosnkowska-Kehiaian, K.; Kehiaian, H. V.

    This document is part of Subvolume C 'Binary Liquid Systems of Nonelectrolytes III' of Volume 26 'Heats of Mixing, Vapor-Liquid Equilibrium, and Volumetric Properties of Mixtures and Solutions' of Landolt-Börnstein Group IV 'Physical Chemistry'. It contains the Chapter 'Volumetric Properties of the Mixture Trichloromethane CHCl3 + C6H14O Hexan-1-ol (VMSD1511, LB5055_V)' providing data from direct measurement of low-pressure thermodynamic speed of sound at variable mole fraction and constant temperature, in the single-phase region(s).

  11. Heat of Mixing and Solution of 1,1,2-Trichloroethane C2H3Cl3 + C6H10O Cyclohexanone (HMSD1111, LB3665_H)

    NASA Astrophysics Data System (ADS)

    Cibulka, I.; Fontaine, J.-C.; Sosnkowska-Kehiaian, K.; Kehiaian, H. V.

    This document is part of Subvolume C 'Binary Liquid Systems of Nonelectrolytes III' of Volume 26 'Heats of Mixing, Vapor-Liquid Equilibrium, and Volumetric Properties of Mixtures and Solutions' of Landolt-Börnstein Group IV 'Physical Chemistry'. It contains the Chapter 'heat of Mixing and Solution of 1,1,2-Trichloroethane C2H3Cl3 + C6H10O Cyclohexanone (HMSD1111, LB3665_H)' providing data from direct low-pressure calorimetric measurement of molar excess enthalpy at variable mole fraction and constant temperature.

  12. Heat of Mixing and Solution of 1,1,1-Trichloroethane C2H3Cl3 + C6H10O Cyclohexanone (HMSD1111, LB3664_H)

    NASA Astrophysics Data System (ADS)

    Cibulka, I.; Fontaine, J.-C.; Sosnkowska-Kehiaian, K.; Kehiaian, H. V.

    This document is part of Subvolume C 'Binary Liquid Systems of Nonelectrolytes III' of Volume 26 'Heats of Mixing, Vapor-Liquid Equilibrium, and Volumetric Properties of Mixtures and Solutions' of Landolt-Börnstein Group IV 'Physical Chemistry'. It contains the Chapter 'heat of Mixing and Solution of 1,1,1-Trichloroethane C2H3Cl3 + C6H10O Cyclohexanone (HMSD1111, LB3664_H)' providing data from direct low-pressure calorimetric measurement of molar excess enthalpy at variable mole fraction and constant temperature.

  13. Insights into Hydrocarbon Chain and Aromatic Ring Formation in the Interstellar Medium: Computational Study of the Isomers of C4H3+ C6H3+ and C6H5+ and Their Formation Pathways

    NASA Astrophysics Data System (ADS)

    Peverati, Roberto; Bera, Partha P.; Lee, Timothy J.; Head-Gordon, Martin

    2016-10-01

    Small hydrocarbons such as acetylene is present in circumstellar envelopes of carbon-rich stars, but the processes that yield larger molecules, and eventually polycyclic aromatic hydrocarbons (PAHs), remain poorly understood. To gain additional insight into the early steps of such processes, electronic structure calculations were performed on the potential energy surfaces of {{{C}}}4{{{{H}}}3}+, {{{C}}}6{{{{H}}}3}+ and {{{C}}}6{{{{H}}}5}+. The results establish reactive pathways from acetylene and its ion to formation of the first aromatic ring. We characterize the stable isomers, their spectroscopic properties, and many of the transition structures that represent barriers to isomerization. The pathways to stabilized {{{C}}}4{{{{H}}}3}+ and {{{C}}}6{{{{H}}}3}+ are most likely to arise from unimolecular decomposition of hot {{{C}}}4{{{{H}}}4}+ and {{{C}}}6{{{{H}}}4}+ by H atom elimination. By contrast, we found an ion-molecule pathway to {{{C}}}6{{{{H}}}5}+ to be very stable to fragmentation and elimination reactions even without collisional stabilization. This aromatic species is a good nucleation center for the growth of larger PAHs in interstellar conditions.

  14. Volumetric Properties of the Mixture (+,-)-Methyl-1,3-dioxolan-2-one C4H6O3 + C6H12O3 2,4,6-Trimethyl-1,3,5-trioxane (VMSD1511, LB4523_V)

    NASA Astrophysics Data System (ADS)

    Cibulka, I.; Fontaine, J.-C.; Sosnkowska-Kehiaian, K.; Kehiaian, H. V.

    This document is part of Subvolume C 'Binary Liquid Systems of Nonelectrolytes III' of Volume 26 'Heats of Mixing, Vapor-Liquid Equilibrium, and Volumetric Properties of Mixtures and Solutions' of Landolt-Börnstein Group IV 'Physical Chemistry'. It contains the Chapter 'Volumetric Properties of the Mixture (+,-)-Methyl-1,3-dioxolan-2-one C4H6O3 + C6H12O3 2,4,6-Trimethyl-1,3,5-trioxane (VMSD1511, LB4523_V)' providing data from direct measurement of low-pressure thermodynamic speed of sound at variable mole fraction and constant temperature, in the single-phase region(s).

  15. Volumetric Properties of the Mixture Diethyl carbonate C5H10O3 + C6H12O3 2,4,6-Trimethyl-1,3,5-trioxane (VMSD1511, LB4522_V)

    NASA Astrophysics Data System (ADS)

    Cibulka, I.; Fontaine, J.-C.; Sosnkowska-Kehiaian, K.; Kehiaian, H. V.

    This document is part of Subvolume C 'Binary Liquid Systems of Nonelectrolytes III' of Volume 26 'Heats of Mixing, Vapor-Liquid Equilibrium, and Volumetric Properties of Mixtures and Solutions' of Landolt-Börnstein Group IV 'Physical Chemistry'. It contains the Chapter 'Volumetric Properties of the Mixture Diethyl carbonate C5H10O3 + C6H12O3 2,4,6-Trimethyl-1,3,5-trioxane (VMSD1511, LB4522_V)' providing data from direct measurement of low-pressure thermodynamic speed of sound at variable mole fraction and constant temperature, in the single-phase region(s).

  16. Volumetric Properties of the Mixture Dimethyl carbonate C3H6O3 + C6H12O3 2,4,6-Trimethyl-1,3,5-trioxane (VMSD1511, LB4517_V)

    NASA Astrophysics Data System (ADS)

    Cibulka, I.; Fontaine, J.-C.; Sosnkowska-Kehiaian, K.; Kehiaian, H. V.

    This document is part of Subvolume C 'Binary Liquid Systems of Nonelectrolytes III' of Volume 26 'Heats of Mixing, Vapor-Liquid Equilibrium, and Volumetric Properties of Mixtures and Solutions' of Landolt-Börnstein Group IV 'Physical Chemistry'. It contains the Chapter 'Volumetric Properties of the Mixture Dimethyl carbonate C3H6O3 + C6H12O3 2,4,6-Trimethyl-1,3,5-trioxane (VMSD1511, LB4517_V)' providing data from direct measurement of low-pressure thermodynamic speed of sound at variable mole fraction and constant temperature, in the single-phase region(s).

  17. Vapor-Liquid Equilibrium in the Mixture 1,1,1-Trichloroethane C2H3Cl3 + C6H10O Cyclohexanone (EVLM1111, LB5638_E)

    NASA Astrophysics Data System (ADS)

    Cibulka, I.; Fontaine, J.-C.; Sosnkowska-Kehiaian, K.; Kehiaian, H. V.

    This document is part of Subvolume C 'Binary Liquid Systems of Nonelectrolytes III' of Volume 26 'Heats of Mixing, Vapor-Liquid Equilibrium, and Volumetric Properties of Mixtures and Solutions' of Landolt-Börnstein Group IV 'Physical Chemistry'. It contains the Chapter 'vapor-Liquid Equilibrium in the Mixture 1,1,1-Trichloroethane C2H3Cl3 + C6H10O Cyclohexanone (EVLM1111, LB5638_E)' providing data from direct measurement of pressure at variable mole fraction in liquid phase and constant temperature.

  18. Solvent effect on infrared spectra of methyl methacrylate in CCl4/C6H14, CHCl3/C6H14 and C2H5OH/C6H14 binary solvent systems.

    PubMed

    Zheng, Jianping; Liu, Qing; Zhang, Hui; Fang, Danjun

    2004-11-01

    Research of methyl methacrylate (MMA) in three kinds of binary solvent systems (CCl4/C6H14, CHCl3/C6H14 and C2H5OH/C6H14) on the infrared (IR) spectra was reported. Two types of carbonyl stretching vibration bands for MMA in CHCl3/C6H14 or C2H5OH/C6H14 mixtures were found with the changing of the mole fraction of CHCl3 (XCHCl3) or C2H5OH (XC2H5OH). The carbonyl stretching vibration bands at lower frequencies in the above two mixtures were attributed to the formation of hydrogen bonding between MMA and CHCl3 or C2H5OH. While in CCl4/C6H14 mixtures there was only one type of carbonyl stretching vibration band of MMA. Good linear correlations between the frequencies of C=O or C=C stretching vibration band of MMA and XCCl4, XCHCl3 or XC2H5OH were found, respectively. The solute-solvent interactions in the three different binary solvent systems were discussed in detail.

  19. Static and dynamic interaction between π and d electrons in organic superconductor β″-(BEDT-TTF)4[(H3O ) Fe (C2O4)3] .C6H5Br studied by 13C NMR spectroscopy

    NASA Astrophysics Data System (ADS)

    Ihara, Y.; Futami, Y.; Kawamoto, A.; Matsui, K.; Goto, T.; Sasaki, T.; Benmansour, S.; Gómez-García, C. J.

    2016-08-01

    We present the results of 13C NMR experiments in an organic superconductor with localized Fe spins β″-(BEDT-TTF) 4[(H3O ) Fe (C2O4)3] .C6H5Br . We reveal the antiferromagnetic coupling between Fe d spins and π spins, which creates an exchange field antiparallel to the external field direction at the π electrons. In addition to the static effects of Fe spins, we show from the nuclear spin-lattice relaxation rate measurement that the magnetic fluctuations generated by Fe spins are suppressed at low temperatures and high magnetic fields. These conditions are suitable to stabilize the field-induced superconductivity by the field compensation mechanism. After the suppression of Fe-spin dynamics by a magnetic field of 19 T, we observed the underlying π -electron contribution. We discuss a possible anomaly in the π -electron system.

  20. Synthesis, structural characterization, electrical properties and antioxidant activity of [p-(NH3)C6H4NH3]3P6O18·6H2O

    NASA Astrophysics Data System (ADS)

    Fezai, Ramzi; Mezni, Ali; Kahlaoui, Messaoud; Rzaigui, Mohamed

    2016-09-01

    Single crystals of a novel organic cyclohexaphosphate, [p-(NH3)C6H4NH3]3P6O18.6H2O, have been prepared in aqueous solution. Its crystal structure can be described by a three-dimensional framework where the P6O186- rings are interconnected by hydrogen bonds to form anionic layers between which organic cations are located. Hydrogen bonding network connecting the different components is given. The thermal stability and spectroscopic properties of this material are given too. Its DC and AC electrical conductivities, modulus analysis and dielectric constants have been investigated. The AC conductivity is found to obey the universal power law. The DC electrical conductivity indicates a semiconductor behavior. The kind of the observed conduction is protonic by translocation. X-rays structural and electrical results are correlated. This compound has also been screened for its antioxidant activity, determined in vitro, using 1,1-diphenyl-2-picrylhydrazyl, reducing power, hydroxyl scavenging ability and ferrous ion chelating (FIC) methods and with ascorbic acid as reference.

  1. Synthesis, crystal structure, thermal analysis and vibrational spectroscopy accomplished with DFT calculation of new hybrid compound [2-CH3C6H4NH3]HSO4.H2O

    NASA Astrophysics Data System (ADS)

    Ben Hassen, C.; Boujelbene, M.; Marweni, S.; Bahri, M.; Mhiri, T.

    2015-10-01

    The present paper undertakes the study of a new organic/inorganic hybrid compound [2-CH3C6H4NH3]HSO4.H2O characterized by the X-ray diffraction, TG-DTA, IR and Raman spectroscopy accomplished with DFT calculation. It is crystallized in the monoclinic system with the centrosymmetric space group P 21/c, with a = 9.445 (5) Å, b = 10.499 Å, c = 10.073 Å, β = 90.627 (5)° and Z = 4. The atomic arrangement can be described as inorganic layers built by infinite chains, parallel to the (a c) planes between which the organic cations are inserted. In this atomic arrangement, hydrogen bonds and π-π interactions between the different species have an important role in the tri-dimensional network cohesion. Besides, the X-ray powder diffraction of the title compound confirms the existence of only one phase at room temperature. The thermal decomposition of precursors studied by thermo gravimetric analysis (TGA), the differential thermal analysis (DTA) and the temperature-dependent X-ray diffraction, show crystalline anhydrous compounds upon dehydration. DFT/BHHLYP calculations were performed, using the DZV (d,p) basis set, to determine the harmonic frequencies of the vibrational modes of an optimized cluster structure. The calculated modes were animated using the Molden graphical package to give tentative assignments of the observed IR and Raman spectra.

  2. Linearly arranged polytypic CZTSSe nanocrystals

    PubMed Central

    Fan, Feng-Jia; Wu, Liang; Gong, Ming; Chen, Shi You; Liu, Guang Yao; Yao, Hong-Bin; Liang, Hai-Wei; Wang, Yi-Xiu; Yu, Shu-Hong

    2012-01-01

    Even colloidal polytypic nanostructures show promising future in band-gap tuning and alignment, researches on them have been much less reported than the standard nano-heterostructures because of the difficulties involved in synthesis. Up to now, controlled synthesis of colloidal polytypic nanocrsytals has been only realized in II-VI tetrapod and octopod nanocrystals with branched configurations. Herein, we report a colloidal approach for synthesizing non-branched but linearly arranged polytypic I2-II-IV-VI4 nanocrystals, with a focus on polytypic non-stoichiometric Cu2ZnSnSxSe4−x nanocrystals. Each synthesized polytypic non-stoichiometric Cu2ZnSnSxSe4−x nanocrystal is consisted of two zinc blende-derived ends and one wurtzite-derived center part. The formation mechanism has been studied and the phase composition can be tuned through adjusting the reaction temperature, which brings a new band-gap tuning approach to Cu2ZnSnSxSe4-x nanocrystals. PMID:23233871

  3. Polytypism, polymorphism, and superconductivity in TaSe(2-x)Te(x).

    PubMed

    Luo, Huixia; Xie, Weiwei; Tao, Jing; Inoue, Hiroyuki; Gyenis, András; Krizan, Jason W; Yazdani, Ali; Zhu, Yimei; Cava, Robert Joseph

    2015-03-17

    Polymorphism in materials often leads to significantly different physical properties--the rutile and anatase polymorphs of TiO2 are a prime example. Polytypism is a special type of polymorphism, occurring in layered materials when the geometry of a repeating structural layer is maintained but the layer-stacking sequence of the overall crystal structure can be varied; SiC is an example of a material with many polytypes. Although polymorphs can have radically different physical properties, it is much rarer for polytypism to impact physical properties in a dramatic fashion. Here we study the effects of polytypism and polymorphism on the superconductivity of TaSe2, one of the archetypal members of the large family of layered dichalcogenides. We show that it is possible to access two stable polytypes and two stable polymorphs in the TaSe(2-x)Te(x) solid solution and find that the 3R polytype shows a superconducting transition temperature that is between 6 and 17 times higher than that of the much more commonly found 2H polytype. The reason for this dramatic change is not apparent, but we propose that it arises either from a remarkable dependence of Tc on subtle differences in the characteristics of the single layers present or from a surprising effect of the layer-stacking sequence on electronic properties that are typically expected to be dominated by the properties of a single layer in materials of this kind.

  4. Polytypism, polymorphism, and superconductivity in TaSe2−xTex

    PubMed Central

    Luo, Huixia; Xie, Weiwei; Tao, Jing; Inoue, Hiroyuki; Gyenis, András; Krizan, Jason W.; Yazdani, Ali; Zhu, Yimei; Cava, Robert Joseph

    2015-01-01

    Polymorphism in materials often leads to significantly different physical properties—the rutile and anatase polymorphs of TiO2 are a prime example. Polytypism is a special type of polymorphism, occurring in layered materials when the geometry of a repeating structural layer is maintained but the layer-stacking sequence of the overall crystal structure can be varied; SiC is an example of a material with many polytypes. Although polymorphs can have radically different physical properties, it is much rarer for polytypism to impact physical properties in a dramatic fashion. Here we study the effects of polytypism and polymorphism on the superconductivity of TaSe2, one of the archetypal members of the large family of layered dichalcogenides. We show that it is possible to access two stable polytypes and two stable polymorphs in the TaSe2−xTex solid solution and find that the 3R polytype shows a superconducting transition temperature that is between 6 and 17 times higher than that of the much more commonly found 2H polytype. The reason for this dramatic change is not apparent, but we propose that it arises either from a remarkable dependence of Tc on subtle differences in the characteristics of the single layers present or from a surprising effect of the layer-stacking sequence on electronic properties that are typically expected to be dominated by the properties of a single layer in materials of this kind. PMID:25737540

  5. Ferromagnetism-dependent polytypism: CrAs versus MnAs

    NASA Astrophysics Data System (ADS)

    Benaissa, H.; Zaoui, A.; Ferhat, M.

    2016-12-01

    Density spin-polarized functional theory using pseudopotential plane wave method is used here to explore the structural and magnetic properties of 3C, 4H, 6H and 2H polytypes of transition metal arsenides: CrAs and MnAs. The results reveal that CrAs manifest weak dependence of the lattice parameter a and the c/a ratio versus hexagonality, but for MnAs, the lattice parameters display strong dependence on crystal polytype. Most importantly, our results show that the different crystal 3C, 4H, 6H and 2H polytypes exhibit significant distinct magnetism in CrAs and MnAs. While the total spin moments induced in CrAs is strongly independent of the crystal structure adopted, the ferromagnetism in MnAs is found sensitive to polytypism.

  6. Mixed triorganobismuthines RAr2Bi [Ar = C6F5, 2,4,6-(C6F5)3C6H2] and hypervalent racemic Bi-chiral diorganobismuth(iii) bromides RArBiBr (Ar = C6F5, Mes, Ph) with the ligand R = 2-(Me2NCH2)C6H4. Influences of the organic substituent.

    PubMed

    Olaru, Marian; Nema, Mihai G; Soran, Albert; Breunig, Hans J; Silvestru, Cristian

    2016-06-21

    Triorganobismuthines R(C6F5)2Bi (1) and R[2,4,6-(C6F5)3C6H2]2Bi (2) [R = 2-(Me2NCH2)C6H4] were synthesized by reaction of RBiBr2 with C6F5MgBr and 2,4,6-(C6F5)3C6H2Li, respectively, in a 1 : 2 molar ratio. The Bi-chiral bromides R(C6F5)BiBr (3), R(Mes)BiBr (4), and R(Ph)BiBr (5) were obtained from RBiBr2 and C6F5MgBr, MesMgBr or PhMgBr, or from PhBiBr2 and RLi, in a 1 : 1 molar ratio. The molecular structures of 1-5 were determined by single-crystal X-ray diffraction and are discussed taking into account the chirality of the species. Supramolecular aspects in the solid state are presented. The solution behaviour of the title compounds, including dynamic aspects, are discussed on the basis of multinuclear ((1)H, (13)C, (19)F) NMR spectroscopy.

  7. Distribution of mica polytypes among space groups.

    NASA Technical Reports Server (NTRS)

    Takeda, H.

    1971-01-01

    All the possible space groups for mica polytypes are deduced by making use of the characteristics of the mica unit layer and stacking mode. The algebraic properties of the vector-stacking symbol of Ross et al. (1966) are examined, and a simple algorithm for deducing the space group from this symbol is presented. A method considered for enumerating all possible stacking sequences of mica polytypes makes use of a computer.

  8. Second sphere coordination in anion binding: Synthesis, characterization and single crystal X-ray structure determination of tris(1,10-phenanthroline)cobalt(III) chloride dimesitylenesulphonate undecahydrate, [Co(phen) 3]Cl[(CH 3) 3C 6H 2SO 3] 2·11H 2O

    NASA Astrophysics Data System (ADS)

    Sharma, Raj Pal; Singh, Ajnesh; Brandão, Paula; Félix, Vítor; Venugopalan, Paloth

    2009-01-01

    Orange coloured single crystals of [Co(phen) 3]Cl[(CH 3) 3C 6H 2SO 3] 2·11H 2O were obtained, when the solution obtained by mixing separately dissolved, tris(1,10-phenanthroline)cobalt(III)chloride and sodium salt of mesitylenesulphonic acid in aqueous medium in 1:3 molar ratio was allowed to evaporate slowly at room temperature. The newly synthesized complex salt was characterized by elemental analyses, TGA, spectroscopic studies (IR, UV/Visible, 1H, 13C and 59Co NMR), conductance and solubility product measurements. Single crystal X-ray structure determination of [Co(phen) 3]Cl[(CH 3) 3C 6H 2SO 3] 2·11H 2O revealed that complex salt crystallizes in the monoclinic crystal system with space group P2 1/ c where a = 17.7628(4), b = 15.7546(3), c = 20.8338(5)Å, β = 104.691(1), V = 5639.65 Å 3, Z = 4. The asymmetric unit consists of one cation, one chloride, two mesitylenesulphonate ions and eleven lattice water molecules. Crystal lattice is stabilized by hydrogen bonding interactions of type C sbnd H⋯O, C sbnd H⋯Cl through second sphere coordination and O sbnd H⋯O interactions besides the electrostatic forces of attractions. The solubility product measurements indicated that the affinity of cationic metal complex tris(1,10-phenanthroline)cobalt(III), [Co(phen) 3] 3+ is greater for mesitylenesulphonate ion than for chloride ion in aqueous medium. The structural studies suggest that [Co(phen) 3] 3+ is a potential anion receptor for the mesitylenesulphonate ion. This is the first crystal structure report of [Co(phen) 3] 3+ complex cation with any arylsulphonate ion.

  9. A new perovskite polytype in the high-pressure sequence of BaIrO(3).

    PubMed

    Cheng, Jin-Guang; Alonso, José Antonio; Suard, Emmanuelle; Zhou, Jian-Shi; Goodenough, John B

    2009-06-03

    structure could be identified as a minority phase, with a = 4.0611(7) A, defined in the Pm3m space group. The precarious stability of the 5H polytype, as well as the novel pressure sequence displayed by BaIrO(3) that is distinct from the classical sequence 9R-4H-6H-3C exhibited by many transition metal oxides, for instance BaRuO(3), is a result of the particular stability of the "9R" ambient-pressure structure, which is reinforced by a strong Ir-Ir bond across the octahedral faces, and the Ir-Ir Coulombic repulsion across shared faces that destabilizes the 4H polytype relative to the 6H phase to allow stabilization of the hybrid 5H polytype in a narrow presure range.

  10. Development of a spinodal decomposition model for the example of a heterostructure based on silicon carbide polytypes

    NASA Astrophysics Data System (ADS)

    Davydov, S. Yu.; Lebedev, A. A.; Lebedev, S. P.; Sitnikova, A. A.; Sorokin, L. M.

    2016-12-01

    The transition region of a 3C-SiC/4 H-SiC heterostructure constituted by layers of the 3 C and 4 H polytypes has been studied. A previously proposed spinodal decomposition model was used to estimate the thickness ratio of 4 H and 3 C layers in comparison with the image furnished by transmission electron microscopy.

  11. Coexistence of multiple metastable polytypes in rhombohedral bismuth

    PubMed Central

    Shu, Yu; Hu, Wentao; Liu, Zhongyuan; Shen, Guoyin; Xu, Bo; Zhao, Zhisheng; He, Julong; Wang, Yanbin; Tian, Yongjun; Yu, Dongli

    2016-01-01

    Derivative structural polytypes coexisting with the rhombohedral A7 structure of elemental bismuth (Bi) have been discovered at ambient condition, based on microstructure analyses of pure Bi samples treated under high pressure and high temperature conditions. Three structures with atomic positions close to those of the A7 structure have been identified through first-principles calculations, showing these polytypes energetically comparable to the A7 structure under ambient condition. Simulated diffraction data are in excellent agreement with the experimental observations. We argue that previously reported some variations of physical properties (e.g., density, electrical conductivity, and magnetism) in bismuth could be due to the formation of these polytypes. The coexistence of metastable derivative structural polytypes may be a widely occurring phenomenon in other elemental materials. PMID:26883895

  12. Epitaxial growth of hexagonal silicon polytypes on sapphire

    SciTech Connect

    Pavlov, D. A.; Pirogov, A. V. Krivulin, N. O.; Bobrov, A. I.

    2015-01-15

    The formation of a single-crystal silicon polytype is observed in silicon-on-sapphire structures by high-resolution transmission electron microscopy. The appearance of inclusions with a structure different from that of diamond is attributed to the formation of strong-twinning regions and the aggregation of stacking faults, which form their own crystal structure in the crystal lattice of silicon. It is demonstrated that the given modification belongs to the 9R silicon polytype.

  13. Rhombohedral polytypes of the layered honeycomb delafossites with optical brilliance in the visible.

    PubMed

    Roudebush, John H; Sahasrabudhe, Girija; Bergman, Susanna L; Cava, R J

    2015-04-06

    We report the synthesis of the Delafossite honeycomb compounds Cu3Ni2SbO6 and Cu3Co2SbO6 via a copper topotactic reaction from the layered α-NaFeO2-like precursors Na3Ni2SbO6 and Na3Co2SbO6. The low-temperature exchange reaction exclusively produces the rhombahedral 3R polytype subcell, whereas only the hexagonal 2H polytype subcell has been made by conventional synthesis. The thus-synthesized 3R variants are visually striking; they are bright lime-green (Ni variant) and terracotta-orange (Co variant), while both of the conventionally synthesized 2H variants have a burnt-red color. The new structures are characterized by powder X-ray diffraction and Rietveld analysis as well as magnetic susceptibility, X-ray photoelectron spectroscopy (XPS), and diffuse-reflectance optical spectroscopy. Using thermogravimetric analysis, we identify a second order 3R → 2H phase transition as well as a first-order structural transition associated with rearrangement of the honeycomb stacking layers. The optical absorbance spectra of the samples show discrete edges that correlate well to their visual colors. Exposing Cu3Ni2SbO6 to O2 and heat causes the sample to change color. XPS confirms the presence of Cu(2+) in these samples, which implies that the difference in color between the polytypes is due to oxygen intercalation resulting from their different synthetic routes.

  14. Polytypism in LaOBi S2 -type compounds based on different three-dimensional stacking sequences of two-dimensional Bi S2 layers

    NASA Astrophysics Data System (ADS)

    Liu, Qihang; Zhang, Xiuwen; Zunger, Alex

    2016-05-01

    LaOBi S2 -type materials have drawn much attention recently because of various interesting physical properties, such as low-temperature superconductivity, hidden spin polarization, and electrically tunable Dirac cones. However, it was generally assumed that each LaOBi S2 -type compound has a unique and specific crystallographic structure (with a space group P 4 /nmm) separated from other phases. Using first-principles total energy and stability calculations we confirm that the previous assignment of the P 4 /nmm structure to LaOBi S2 is incorrect. Furthermore, we find that the unstable structure is replaced by a family of energetically closely spaced modifications (polytypes) differing by the layer sequences and orientations. We find that the local Bi-S distortion leads to three polytypes of LaOBi S2 with different stacking patterns of the distorted Bi S2 layers. The energy difference between the polytypes of LaOBi S2 is merely ˜1 meV/u.c., indicating the possible coexistence of all polytypes in the real sample and that the particular distribution of polytypes may be growth induced. The in-plane distortion can be suppressed by pressure, leading to a phase transition from polytypes to the high-symmetry P 4 /nmm structure with a pressure larger than 2.5 GPa. In addition, different choices of the intermediate atoms (replacing La) or active atoms (Bi S2 ) could also manifest different ground-state structures. One can thus tune the distortion and the ground state by pressure or by substituting covalence atoms in the LaOBi S2 family.

  15. Interband polarized absorption in InP polytypic superlattices

    SciTech Connect

    Faria Junior, P. E.; Sipahi, G. M.; Campos, T.

    2014-11-21

    Recent advances in growth techniques have allowed the fabrication of semiconductor nanostructures with mixed wurtzite/zinc-blende crystal phases. Although the optical characterization of these polytypic structures is well reported in the literature, a deeper theoretical understanding of how crystal phase mixing and quantum confinement change the output linear light polarization is still needed. In this paper, we theoretically investigate the mixing effects of wurtzite and zinc-blende phases on the interband absorption and in the degree of light polarization of an InP polytypic superlattice. We use a single 8 × 8 k⋅p Hamiltonian that describes both crystal phases. Quantum confinement is investigated by changing the size of the polytypic unit cell. We also include the optical confinement effect due to the dielectric mismatch between the superlattice and the vaccum and we show it to be necessary to match experimental results. Our calculations for large wurtzite concentrations and small quantum confinement explain the optical trends of recent photoluminescence excitation measurements. Furthermore, we find a high sensitivity to zinc-blende concentrations in the degree of linear polarization. This sensitivity can be reduced by increasing quantum confinement. In conclusion, our theoretical analysis provides an explanation for optical trends in InP polytypic superlattices, and shows that the interplay of crystal phase mixing and quantum confinement is an area worth exploring for light polarization engineering.

  16. On the formation of polytypes in CdTe thin films

    NASA Astrophysics Data System (ADS)

    Tiwari, Brajesh Kumar; Srivastava, O. N.

    1981-08-01

    The single crystal films of CdTe have been found to exhibit polytypism. Three different polytypic series have been found to result in the films prepared from the as supplied and the homogenized CdTe fluxes. The polytypes are formed when the as grown amorphous films get crystallized on electron beam pulse annealing in the electron microscope. The polytypes which are the first known polytypes of CdTe correspond to (i) 2H, 3C, 5H, 6H, 6R, 15R, (ii) 2H', 4H', 5H', and (iii) 2H''. A feasible mechanism for the polytype formation has been suggested. This is based on the interaction between the constant energy surface and the Brilllouin zone leading to a reduction in the electronic energy.

  17. Characterization of the Waukesha Illite: A mixed-polytype illite in the Clay Mineral Society repository

    USGS Publications Warehouse

    Grathoff, Georg H.; Moore, D.M.

    2002-01-01

    The Waukesha Illite is an excellent example of the illites found in argillaceous rocks, typical for Paleozoic shales that have undergone significant burial diagenesis during their geologic history. It consists of a mixture of detrital 2M1, interpreted to be a residuum of karstification within Silurian carbonates, and diagenetic 1M and 1Md illite. The chemistry and the age of the illite polytypes are different. Extrapolating to 100%, the 1M and 1Md polytypes have an apparent diagenetic age between 295 and 325 Ma. The chemistry of the 1M polytype could not be determined because of its low abundance. The approximate chemical composition of the 1Md polytype is 0.67 K, 3.6 Si, and 1.9 Al per half unit cell. The 2M1 polytype has an apparent detrital age between 440 and 520 Ma, and an approximate chemical composition per half unit cell of 0.78 K, 3.4 Si, and 2.1 Al, all within our margin of error. X-ray diffraction (XRD) results of both random powder and oriented preparations both indicate that the Waukesha Illite consists of a mixture of illites. The XRD patterns of the random powder preparation indicate it is a physical mixture of three different illite polytypes. This result was confirmed using 3 different methods: (1) by measuring illite polytype-specific reflections; (2) by mixing illite polytype reference samples; and (3) by mixing WILDFIRE calculated XRD patterns. Decomposition of the illite 001 XRD peak from oriented preparations also indicates mixtures of illites. However, the proportions of the three illitic components derived from the oriented 001 peak decomposition differ from those results derived from the analysis of the random powder data. Therefore, the shape of the 001 reflection of the Waukesha Illite cannot be explained by mixing the three different illite polytypes.

  18. Novel heterostructured Ge nanowires based on polytype transformation.

    PubMed

    Vincent, Laetitia; Patriarche, Gilles; Hallais, Géraldine; Renard, Charles; Gardès, Cyrille; Troadec, David; Bouchier, Daniel

    2014-08-13

    We report on a strain-induced phase transformation in Ge nanowires under external shear stresses. The resulted polytype heterostructure may have great potential for photonics and thermoelectric applications. ⟨111⟩-oriented Ge nanowires with standard diamond structure (3C) undergo a phase transformation toward the hexagonal diamond phase referred as the 2H-allotrope. The phase transformation occurs heterogeneously on shear bands along the length of the nanowire. The structure meets the common phenomenological criteria of a martensitic phase transformation. This point is discussed to initiate an on going debate on the transformation mechanisms. The process results in unprecedented quasiperiodic heterostructures 3C/2H along the Ge nanowire. The thermal stability of those 2H domains is also studied under annealing up to 650 °C by in situ TEM.

  19. Analysis of polytype stability in PVT grown silicon carbide single crystal using competitive lattice model Monte Carlo simulations

    NASA Astrophysics Data System (ADS)

    Guo, Hui-Jun; Huang, Wei; Liu, Xi; Gao, Pan; Zhuo, Shi-Yi; Xin, Jun; Yan, Cheng-Feng; Zheng, Yan-Qing; Yang, Jian-Hua; Shi, Er-Wei

    2014-09-01

    Polytype stability is very important for high quality SiC single crystal growth. However, the growth conditions for the 4H, 6H and 15R polytypes are similar, and the mechanism of polytype stability is not clear. The kinetics aspects, such as surface-step nucleation, are important. The kinetic Monte Carlo method is a common tool to study surface kinetics in crystal growth. However, the present lattice models for kinetic Monte Carlo simulations cannot solve the problem of the competitive growth of two or more lattice structures. In this study, a competitive lattice model was developed for kinetic Monte Carlo simulation of the competition growth of the 4H and 6H polytypes of SiC. The site positions are fixed at the perfect crystal lattice positions without any adjustment of the site positions. Surface steps on seeds and large ratios of diffusion/deposition have positive effects on the 4H polytype stability. The 3D polytype distribution in a physical vapor transport method grown SiC ingot showed that the facet preserved the 4H polytype even if the 6H polytype dominated the growth surface. The theoretical and experimental results of polytype growth in SiC suggest that retaining the step growth mode is an important factor to maintain a stable single 4H polytype during SiC growth.

  20. Complex (Nonstandard) Six-Layer Polytypes of Lizardite Revealed from Oblique-Texture Electron Diffraction Patterns

    SciTech Connect

    Zhukhlistov, A.P.; Zinchuk, N.N.; Kotel'nikov, D.D.

    2004-11-01

    Association of simple (1T and 3R) and two complex (nonstandard) orthogonal polytypes of the serpentine mineral lizardite from the Catoca kimberlite pipe (West Africa) association is revealed from oblique-texture electron diffraction patterns. A six-layer polytype with an ordered superposition of equally oriented layers (notation 3{sub 2}3{sub 2}3{sub 4}3{sub 4}3{sub 6}3{sub 6} or ++ - -00) belonging to the structural group A and a three-layer (336 or I,I,II) or a six-layer (336366 or I,I,II,I,II,II) polytype with alternating oppositely oriented layers and semi-disordered structure are identified using polytype analysis.

  1. Nanostructural and electronic properties of polytypes in InN nanocolumns

    SciTech Connect

    Kioseoglou, J.; Koukoula, T.; Komninou, Ph.; Kehagias, Th.; Georgakilas, A.; Androulidaki, M.

    2013-08-21

    Transmission electron microscopy techniques and density functional theory calculations were employed to investigate the nanostructural and electronic properties of InN polytypes observed in InN nanocolumns, grown on Si(111) by molecular beam epitaxy. Moiré fringes and alternating hexagonal and cubic lattice stacking sequences along the c-axis, observed among the wurtzite layers, implied the presence of different structures embedded in the basic 2H structure of the nanocolumns. Quantitative electron diffraction analysis and high-resolution image simulations verified the coexistence of the wurtzite structure with the 4H, 6H, and the 3C zinc-blende structural polytypes. Total energies calculations established the 2H wurtzite structure as the most stable polytype. The band gap of all polytypes was found direct with the energies and the band gaps of the 4H (E{sub g} = 0.64 eV) and 6H (E{sub g} = 0.60 eV) structures calculated between the corresponding values of the 2H (E{sub g} = 0.75 eV) and 3C (E{sub g} = 0.49 eV) basic structures. Theoretical and experimental analysis showed that at the initial stages of growth InN nanocolumns were under tensile strain along both the basal plane and growth direction. Structural polytypes were then introduced in the form of embedded inclusions to accommodate the excess tensile strain along the growth direction, allowing the entire process of polymorphism to be the dominant strain relaxation mechanism of InN nanocolumns. Moreover, the lattice and energetic properties and band gap values of InN polytypes showed a linear dependence on hexagonality, while the presence of polytypes led to a characteristic broadening of the photoluminescence emission peak toward lower emission energies.

  2. Metallic VS2 Monolayer Polytypes as Potential Sodium-Ion Battery Anode via ab Initio Random Structure Searching.

    PubMed

    Putungan, Darwin Barayang; Lin, Shi-Hsin; Kuo, Jer-Lai

    2016-07-27

    We systematically investigated the potential of single-layer VS2 polytypes as Na-battery anode materials via density functional theory calculations. We found that sodiation tends to inhibit the 1H-to-1T structural phase transition, in contrast to lithiation-induced transition on monolayer MoS2. Thus, VS2 can have better structural stability in the cycles of charging and discharging. Diffussion of Na atom was found to be very fast on both polytypes, with very small diffusion barriers of 0.085 eV (1H) and 0.088 eV (1T). Ab initio random structure searching was performed in order to explore stable configurations of Na on VS2. Our search found that both the V top and the hexagonal center sites are preferred adsorption sites for Na, with the 1H phase showing a relatively stronger binding. Notably, our random structures search revealed that Na clusters can form as a stacked second layer at full Na concentration, which is not reported in earlier works wherein uniform, single-layer Na adsorption phases were assumed. With reasonably high specific energy capacity (232.91 and 116.45 mAh/g for 1H and 1T phases, respectively) and open-circuit voltage (1.30 and 1.42 V for 1H and 1T phases, respectively), VS2 is a promising alternative material for Na-ion battery anodes with great structural sturdiness. Finally, we have shown the capability of the ab initio random structure searching in the assessment of potential materials for energy storage applications.

  3. Strain effects in polytypical wurtzite/zinc-blend nanowhiskers

    NASA Astrophysics Data System (ADS)

    Sipahi, Guilherme; Faria, Paulo

    2012-02-01

    The recent interest on III-V nanowhiskers has led to the growth of high quality samples of systems with two different crystalline structures [1]. The crystals grown in [111]-direction for the zinc-blend (ZB) phase and [0001]-direction for the wurtzite (WZ) phase are very similar and can both be described as stacked hexagonal layers. The effect of two different structural phases coexisting in the same nanostrucure is known as polytypism and creates confinement profiles similar to a heterostructure. One can notice band offsets at the interface and the formation of electronic minibands that can be explored to design systems for device applications. Although some of the III-V compounds do not present WZ structure in bulk form, recent calculations [2] presented a theoretical prediction of their band structure. However, as they considered that ZB and WZ to have the same lattice parameters no strain effects should appear on a first approach. Our theoretical approach introduces strain effects in our previous model [3] by using group theory arguments. It allows the analysis of the biaxial strain effects for both structures in a single matrix. [1] P. Caroff et al. Nature Nanotech. 4, 50, 2009. [2] A. De and C. E. Pryor, Phys. Rev. B 81, 155210, 2010 [3] http://arxiv.org/abs/1012.022

  4. Low-temperature production of silicon carbide films of different polytypes

    SciTech Connect

    Semenov, A. V. Puzikov, V. M.; Golubova, E. P.; Baumer, V. N.; Dobrotvorskaya, M. V.

    2009-05-15

    The study is concerned with the effect of temperature on the structure of SiC films formed by deposition of the C and Si ions with the energy 120 eV. On the basis of the X-ray structural studies, it is unambiguously established that the structure of the growing polytype is finely dependent on the substrate temperature. In the temperature range from 1080 deg. C to 1510 deg. C, the sequence of films involving the 21R, 51R, 27R, and 6H polytypes is produced for the first time. The effect of temperature on the silicon-carbon atomic content ratio [Si]/[C] in the deposited films is determined. At optimized parameters of deposition the film structured as the 51R rhombohedral polytype is grown.

  5. Thermal expansion and thermal expansion anisotropy of SiC polytypes

    NASA Technical Reports Server (NTRS)

    Li, Z.; Bradt, R. C.

    1987-01-01

    The principal axial coefficients of thermal expansion for the (3C), (4H), and (6H) polytypes of SiC are considered to identify the structural role of the stacking layer sequence as it affects the thermal expansion. A general equation based on the fractions of cubic and hexagonal layer stacking is developed that expresses the principal axial thermal expansion coefficients of all of the SiC polytypes. It is then applied to address the thermal expansion anisotropy of the noncubic SiC structures.

  6. Predicted electronic markers for polytypes of LaOBi S2 examined via angle-resolved photoemission spectroscopy

    NASA Astrophysics Data System (ADS)

    Zhou, Xiaoqing; Liu, Qihang; Waugh, J. A.; Li, Haoxiang; Nummy, T.; Zhang, Xiuwen; Zhu, Xiangde; Cao, Gang; Zunger, Alex; Dessau, D. S.

    2017-02-01

    The natural periodic stacking of symmetry-inequivalent planes in layered compounds can lead to the formation of natural superlattices; albeit close in total energy, (thus in their thermodynamic stability), such polytype superlattices can exhibit different structural symmetries, thus have markedly different electronic properties which can in turn be used as "structural markers". We illustrate this general principle on the layered LaOBi S2 compound where density-functional theory (DFT) calculations on the (Bi S2 )/(LaO)/(Bi S2 ) polytype superlattices reveal both qualitatively and quantitatively distinct electronic structure markers associated with the Rashba physics, yet the total energies are only ˜ 0.1 meV apart. This opens the exciting possibility of identifying subtle structural features via electronic markers. We show that the pattern of removal of band degeneracies in different polytypes by the different forms of symmetry breaking leads to Rashba "minigaps" with characteristic Rashba parameters that can be determined from spectroscopy, thereby narrowing down the physically possible polytypes. By identifying these distinct DFT-predicted fingerprints via angle-resolved photoemission spectroscopy (ARPES) measurements on LaBiO S2 we found the dominant polytype with small amounts of mixtures of other polytypes. This conclusion, consistent with neutron scattering results, establishes ARPES detection of theoretically established electronic markers as a powerful tool to delineate energetically quasidegenerate polytypes.

  7. Modelling polytypism in III-V nanowires: role of group V and nucleation patterns during the growth

    NASA Astrophysics Data System (ADS)

    Grecenkov, J.; Dubrovskii, V. G.

    2015-11-01

    This theoretical work deals with polytypism in nanowires by utilizing nucleation theory and by modifying standard expression for nucleation rate. Polycentric and monocentric nucleation cases are also considered. Results show good agreement with experimental data.

  8. Discovery of elusive structures of multifunctional transition-metal borides

    NASA Astrophysics Data System (ADS)

    Liang, Yongcheng; Wu, Zhaobing; Yuan, Xun; Zhang, Wenqing; Zhang, Peihong

    2015-12-01

    A definitive determination of crystal structures is an important prerequisite for designing and exploiting new functional materials. Even though tungsten and molybdenum borides (TMBx) are the prototype for transition-metal light-element compounds with multiple functionalities, their elusive crystal structures have puzzled scientists for decades. Here, we discover that the long-assumed TMB2 phases with the simple hP3 structure (hP3-TMB2) are in fact a family of complex TMB3 polytypes with a nanoscale ordering along the axial direction. Compared with the energetically unfavorable and dynamically unstable hP3-TMB2 phase, the energetically more favorable and dynamically stable TMB3 polytypes explain the experimental structural parameters, mechanical properties, and X-ray diffraction (XRD) patterns better. We demonstrate that such a structural and compositional modification from the hP3-TMB2 phases to the TMB3 polytypes originates from the relief of the strong antibonding interaction between d electrons by removing one third of metal atoms systematically. These results resolve the longstanding structural mystery of this class of metal borides and uncover a hidden family of polytypic structures. Moreover, these polytypic structures provide an additional hardening mechanism by forming nanoscale interlocks that may strongly hinder the interlayer sliding movements, which promises to open a new avenue towards designing novel superhard nanocomposite materials by exploiting the coexistence of various polytypes.

  9. Polytypic phase formation in DyAl3 by rapid solidification

    NASA Astrophysics Data System (ADS)

    Xu, Yan; Altounian, Z.; Muir, W. B.

    1991-01-01

    Amorphous ribbons of AlxDy100-x, 93≳x≳85, were obtained by melt spinning. During crystallization, in addition to Al, four different metastable crystalline phases of DyAl3 were observed. These phases are, in order of appearance, the high-pressure face-centered cubic phase, γ-DyAl3 and three polytypic rhombohedral phases, β-DyAl3, β'-DyAl3, and α'-DyAl3. It is the first time that the β' phase in rare-earth trialuminides and the α' phase in Dy-Al alloy system have been observed. It is shown that all these phases are associated with the polytypic packing of the hexagonal DyAl3 atomic layers. The relative stability of the phases is found to be related to the hexagonal to cubic stacking ratio in the structure.

  10. Synthesis of 15R polytype of diamond in oxy-acetylene flame grown diamond thin films

    NASA Astrophysics Data System (ADS)

    Kapil, R.; Mehta, B. R.; Vankar, V. D.

    1996-04-01

    15R polytype of diamond has been synthesized using a specially designed oxy-acetylene flame system along with 3C diamond and cubic carbon on polycrystalline molybdenum substrates. X-ray diffraction has been used to detect the 15R phase as the dominant phase in these films. Rapid changes in the substrate temperature during the growth process are expected to be responsible for the growth of these phases.

  11. An ab initio study of the polytypism in InP

    PubMed Central

    Dacal, Luis C. O.; Cantarero, A.

    2016-01-01

    The existence of polytypism in semiconductor nanostructures gives rise to the appearance of stacking faults which many times can be treated as quantum wells. In some cases, despite of a careful growth, the polytypism can be hardly avoided. In this work, we perform an ab initio study of zincblende stacking faults in a wurtzite InP system, using the supercell approach and taking the limit of low density of narrow stacking faults regions. Our results confirm the type II band alignment between the phases, producing a reliable qualitative description of the band gap evolution along the growth axis. These results show an spacial asymmetry in the zincblende quantum wells, that is expected due to the fact that the wurtzite stacking sequence (ABAB) is part of the zincblende one (ABCABC), but with an unexpected asymmetry between the valence and the conduction bands. We also present results for the complex dielectric function, clearly showing the influence of the stacking on the homostructure values and surprisingly proving that the correspondent bulk results can be used to reproduce the polytypism even in the limit we considered. PMID:27666092

  12. Bent Polytypic ZnSe and CdSe Nanowires Probed by Photoluminescence.

    PubMed

    Kim, Yejin; Im, Hyung Soon; Park, Kidong; Kim, Jundong; Ahn, Jae-Pyoung; Yoo, Seung Jo; Kim, Jin-Gyu; Park, Jeunghee

    2017-03-15

    Nanowires (NWs) have witnessed tremendous development over the past two decades owing to their varying potential applications. Semiconductor NWs often contain stacking faults due to the presence of coexisting phases, which frequently hampers their use. Herein, it is investigated how stacking faults affect the optical properties of bent ZnSe and CdSe NWs, which are synthesized using the vapor transport method. Polytypic zinc blende-wurtzite structures are produced for both these NWs by altering the growth conditions. The NWs are bent by the mechanical buckling of poly(dimethylsilioxane), and micro-photoluminescence (PL) spectra were then collected for individual NWs with various bending strains (0-2%). The PL measurements show peak broadening and red shifts of the near-band-edge emission as the bending strain increases, indicating that the bandgap decreases with increasing the bending strain. Remarkably, the bandgap decrease is more significant for the polytypic NWs than for the single phase NWs. This work provides insights into flexible electronic devices of 1D nanostructures by engineering the polytypic structures.

  13. Polytype and stacking faults in the Li2CoSiO4 Li-ion battery cathode.

    PubMed

    Truong, Quang Duc; Devaraju, Murukanahally Kempaiah; Sasaki, Yoshikazu; Hyodo, Hiroshi; Honma, Itaru

    2014-12-01

    Atomic-resolution imaging of the crystal defects of cathode materials is crucial to understand their formation and the correlation between the structure, electrical properties, and electrode performance in rechargeable batteries. The polytype, a stable form of varied crystal structure with uniform chemical composition, holds promise to engineer electronic band structure in nanoscale homojunctions.1-3 Analyzing the exact sites of atoms and the chemistry of the boundary in polytypes would advance our understanding of their formation and properties. Herein, the polytype and stacking faults in the lithium cobalt silicates are observed directly by aberration-corrected scanning transmission electron microscopy. The atomic-scale imaging allows clarification that the polytype is formed by stacking of two different close-packed crystal planes in three-dimensional space. The formation of the polytype was induced by Li-Co cation exchange, the transformation of one phase to the other, and their stacking. This finding provides insight into intrinsic structural defects in an important Li2 CoSiO4 Li-ion battery cathode.

  14. Observation of two polytypes of MoS2 ultrathin layers studied by second harmonic generation microscopy and photoluminescence

    NASA Astrophysics Data System (ADS)

    Mishina, E.; Sherstyuk, N.; Lavrov, S.; Sigov, A.; Mitioglu, A.; Anghel, S.; Kulyuk, L.

    2015-03-01

    Second harmonic generation (SHG) of a high intensity was found in MoS2 flakes of different thicknesses exfoliated on a silicon substrate. Reduction of the SHG intensity was observed only for a small portion of flakes, for both very thin and quite thick ones. This was attributed to the presence of polytypism, i.e., of 3R non-centrosymmetric and 2H centrosymmetric polytypes, in a source bulk crystal grown by the chemical vapor transport technique. The presence of two polytypes in the sample was confirmed by the spectral structure of the photoluminescence of bound excitons observed in flakes at low temperature. Absolute values of nonlinear susceptibility of MoS2 flakes of different thicknesses were estimated.

  15. Hexagonal Close-Packed ^4{He} as Crystalline Multilayered Polytype: An Alternative for `Supersolid' or `Glassy-Like' Phase

    NASA Astrophysics Data System (ADS)

    Chishko, K. A.; Antsygina, T. N.; Poltavskaya, M. I.

    2017-01-01

    We apply the model of a crystalline polytype built of close-packed 2D monoatomic basal planes with triangular lattice to interpret the anomalous thermodynamical and mechanical properties of solid hexagonal close-packed (HCP) ^4{He} . The polytype is a 3D stack of the basal planes, and its structure can be built from the simplest periodic packing (HCP, FCC, 4H, 5H, 6R, ldots etc.) up to random stacking fault system (RSFS) totally aperiodic in only c-direction perpendicular to the basal planes. RSFS is a crystal without microscopic translation symmetry along c-axis, i.e., entirely disordered in only one spatial direction. Despite of packing disorder, c-direction remains the crystallographic axis of third order at arbitrary sequence of the 2D plates in the whole stack. In a long-wave limit the HCP polytype can be treated as 3D anisotropic continuum, as a result its phonon spectrum and Helmholtz free energy have been calculated. The temperature dependence of the phonon pressure is calculated theoretically and compared with experimental data. A quantitative agreement between the theory and the experiment is achieved. Mechanical properties of ^4{He} crystals in the framework of the polytype model are briefly discussed.

  16. Polytypic transformations during the thermal decomposition of cobalt hydroxide and cobalt hydroxynitrate

    SciTech Connect

    Ramesh, Thimmasandra Narayan

    2010-06-15

    The isothermal decomposition of cobalt hydroxide and cobalt hydroxynitrate at different intervals of temperature leads to the formation of Co{sub 3}O{sub 4}. The phase evolution during the decomposition process was monitored using powder X-ray diffraction. The transformation of cobalt hydroxide to cobalt oxide occurs via three phase mixture while cobalt hydroxynitrate to cobalt oxide occurs through a two phase mixture. The nature of the sample and its preparation method controls the decomposition mechanism. The comparison of topotactical relationship between the precursors to the decomposed product has been reported in relation to polytypism. - Graphical abstract: Isothermal thermal decomposition studies of cobalt hydroxide and cobalt hydroxynitrate at different intervals of temperature show the metastable phase formed prior to Co{sub 3}O{sub 4} phase.

  17. Thermal expansion of the cubic (3C) polytype of SiC

    NASA Technical Reports Server (NTRS)

    Li, Z.; Bradt, R. C.

    1986-01-01

    Thermal expansion of the cubic beta or (3C) polytype of SiC was measured from 20 to 1000 C by the X-ray-diffraction technique. Over that temperature range, the coefficient of thermal expansion can be expressed by a second-order polynomial. It increases continuously from about 3.2 x 10 to the -6th/C at room temperature to 5.1 x 10 to the -6th/C at 1000 C, with an average value of 4.45 x 10 to the -6th/C between room temperature and 1000 C. This trend is compared with other published results and is discussed in terms of structural contributions to the thermal expansion.

  18. Crystal structure of Cr-bearing Mg3BeAl8O16, a new polytype of magnesiotaaffeite-2N′2S

    PubMed Central

    Malcherek, Thomas; Schlüter, Jochen

    2016-01-01

    The crystal structure of a new polytype of magnesiotaaffeite-2N′2S, ideally Mg3BeAl8O16 (trimagnesium beryllium octa­aluminium hexa­deca­oxide), is described in space-group symmetry P-3m1. It has been identified in a fragment of a mineral sample from Burma (Myanmar). The new polytype is composed of two Mg2Al4O8 (S)- and two BeMgAl4O8 (N′)-modules in a stacking sequence N′SSN′′ which differs from the N′SN′S-stacking sequence of the known magnesiotaaffeite-2N′2S polytype. The crystal structure can be derived from a close-packed arrangement of O atoms and is discussed with regard to its polytypism and its Cr3+ chromophore content. PMID:27555963

  19. Crystal structure of Cr-bearing Mg3BeAl8O16, a new polytype of magnesiotaaffeite-2N'2S.

    PubMed

    Malcherek, Thomas; Schlüter, Jochen

    2016-07-01

    The crystal structure of a new polytype of magnesiotaaffeite-2N'2S, ideally Mg3BeAl8O16 (trimagnesium beryllium octa-aluminium hexa-deca-oxide), is described in space-group symmetry P-3m1. It has been identified in a fragment of a mineral sample from Burma (Myanmar). The new polytype is composed of two Mg2Al4O8 (S)- and two BeMgAl4O8 (N')-modules in a stacking sequence N'SSN'' which differs from the N'SN'S-stacking sequence of the known magnesiotaaffeite-2N'2S polytype. The crystal structure can be derived from a close-packed arrangement of O atoms and is discussed with regard to its polytypism and its Cr(3+) chromophore content.

  20. Process for the controlled growth of single-crystal films of silicon carbide polytypes on silicon carbide wafers

    NASA Technical Reports Server (NTRS)

    Larkin, David J. (Inventor); Powell, J. Anthony (Inventor)

    1992-01-01

    A method for the controlled growth of single-crystal semiconductor-device-quality films of SiC polytypes on vicinal (0001) SiC wafers with low tilt angles is presented. Both homoepitaxial and heteroepitaxial SiC films can be produced on the same wafer. In particular, 3C-SiC and 6H-SiC films can be produced within selected areas of the same 6H-SiC wafer.

  1. Rapid and Nondestructive Identification of Polytypism and Stacking Sequences in Few-Layer Molybdenum Diselenide by Raman Spectroscopy

    DOE PAGES

    Lu, Xin; Utama, M. Iqbal Bakti; Lin, Junhao; ...

    2015-07-02

    Various combinations of interlayer shear modes emerge in few-layer molybdenum diselenide grown by chemical vapor deposition depending on the stacking configuration of the sample. Raman measurements may also reveal polytypism and stacking faults, as supported by first principles calculations and high-resolution transmission electron microscopy. Thus, Raman spectroscopy is an important tool in probing stacking-dependent properties in few-layer 2D materials.

  2. Process for the controlled growth of single-crystal films of silicon carbide polytypes on silicon carbide wafers

    NASA Technical Reports Server (NTRS)

    Powell, J. Anthony (Inventor)

    1991-01-01

    This invention is a method for the controlled growth of single-crystal semiconductor device quality films of SiC polytypes on vicinal (0001) SiC wafers with low tilt angles. Both homoepitaxial and heteroepitaxial SiC films can be produced on the same wafer. In particular, 3C-SiC and 6H-SiC films can be produced within selected areas of the same 6H-SiC wafer.

  3. Crystal structure of the 4H BaCrO 3 polytype

    NASA Astrophysics Data System (ADS)

    Chamberland, B. L.

    1982-07-01

    The structure of the four-layer hexagonal BaCrO 3 polytype, prepared at high temperature and high pressure, was determined utilizing a Picker FACS-I diffractometer. The hexagonal black crystal was found to crystallize with a four-layer stacking sequence in space group {P6 3}/{mmc} having unit cell parameters a = 5.660(1) and c = 9.357(1) Å. The structure was determined from 668 independent reflections of which 605 were considered observed. Equivalent reflections were averaged and this operation yielded 130 unique, observed reflections. Refinement of the structure by least-squares methods gave a conventional R value of 3.0%. The structure consists of a four-layer stacking sequence of close-packed BaO 3 layers containing tetravalent chromium in all the octahedral oxygen interstices. The compound was found to be isostructural with β-BaMnO 3 and the recently reported BaRhO 3 and SrMnO 3.

  4. Transition.

    ERIC Educational Resources Information Center

    Thompson, Sandy, Ed.; And Others

    1990-01-01

    This "feature issue" focuses on transition from school to adult life for persons with disabilities. Included are "success stories," brief program descriptions, and a list of resources. Individual articles include the following titles and authors: "Transition: An Energizing Concept" (Paul Bates); "Transition…

  5. Polytypism and unexpected strong interlayer coupling in two-dimensional layered ReS2

    NASA Astrophysics Data System (ADS)

    Qiao, Xiao-Fen; Wu, Jiang-Bin; Zhou, Linwei; Qiao, Jingsi; Shi, Wei; Chen, Tao; Zhang, Xin; Zhang, Jun; Ji, Wei; Tan, Ping-Heng

    2016-04-01

    Anisotropic two-dimensional (2D) van der Waals (vdW) layered materials, with both scientific interest and application potential, offer one more dimension than isotropic 2D materials to tune their physical properties. Various physical properties of 2D multi-layer materials are modulated by varying their stacking orders owing to significant interlayer vdW coupling. Multilayer rhenium disulfide (ReS2), a representative anisotropic 2D material, was expected to be randomly stacked and lack interlayer coupling. Here, we demonstrate two stable stacking orders, namely isotropic-like (IS) and anisotropic-like (AI) N layer (NL, N > 1) ReS2 are revealed by ultralow- and high-frequency Raman spectroscopy, photoluminescence and first-principles density functional theory calculation. Two interlayer shear modes are observed in AI-NL-ReS2 while only one shear mode appears in IS-NL-ReS2, suggesting anisotropic- and isotropic-like stacking orders in IS- and AI-NL-ReS2, respectively. This explicit difference in the observed frequencies identifies an unexpected strong interlayer coupling in IS- and AI-NL-ReS2. Quantitatively, the force constants of them are found to be around 55-90% of those of multilayer MoS2. The revealed strong interlayer coupling and polytypism in multi-layer ReS2 may stimulate future studies on engineering physical properties of other anisotropic 2D materials by stacking orders.Anisotropic two-dimensional (2D) van der Waals (vdW) layered materials, with both scientific interest and application potential, offer one more dimension than isotropic 2D materials to tune their physical properties. Various physical properties of 2D multi-layer materials are modulated by varying their stacking orders owing to significant interlayer vdW coupling. Multilayer rhenium disulfide (ReS2), a representative anisotropic 2D material, was expected to be randomly stacked and lack interlayer coupling. Here, we demonstrate two stable stacking orders, namely isotropic-like (IS) and

  6. Conduction Band Offset and Polarization Effects in InAs Nanowire Polytype Junctions.

    PubMed

    Chen, I-Ju; Lehmann, Sebastian; Nilsson, Malin; Kivisaari, Pyry; Linke, Heiner; Dick, Kimberly A; Thelander, Claes

    2017-02-08

    Although zinc-blende (ZB) and wurtzite (WZ) structures differ only in the atomic stacking sequence, mixing of crystal phases can strongly affect the electronic properties, a problem particularly common to bottom up-grown nanostructures. A lack of understanding of the nature of electronic transport at crystal phase junctions thus severely limits our ability to develop functional nanowire devices. In this work we investigated electron transport in InAs nanowires with designed mixing of crystal structures, ZB/WZ/ZB, by temperature-dependent electrical measurements. The WZ inclusion gives rise to an energy barrier in the conduction band. Interpreting the experimental result in terms of thermionic emission and using a drift-diffusion model, we extracted values for the WZ/ZB band offset, 135 ± 10 meV, and interface sheet polarization charge density on the order of 10(-3) C/m(2). The extracted polarization charge density is 1-2 orders of magnitude smaller than previous experimental results, but in good agreement with first principle calculation of spontaneous polarization in WZ InAs. When the WZ length is reduced below 20 nm, an effective barrier lowering is observed, indicating the increasing importance of tunneling transport. Finally, we found that band-bending at ZB/WZ junctions can lead to bound electron states within an enclosed WZ segment of sufficient length, evidenced by our observation of Coulomb blockade at low temperature. These findings provide critical input for modeling and designing the electronic properties of novel functional devices, such as nanowire transistors, where crystal polytypes are commonly found.

  7. Chemical potential effects on polytypism in Au-catalyzed GaAs nanowire molecular beam epitaxy growth: A first-principles study

    NASA Astrophysics Data System (ADS)

    Yao, Luchi; Zhou, Xiaohao; Lu, Wei; Chen, Xiaoshuang

    2016-01-01

    We have studied the polytypism induced by the chemical potential through an ab-initio-thermodynamic-combined approach in Au-catalyzed GaAs nanowire growth. The nucleation in nanowire growth is numerically discussed by classical nucleation theory parameterized by ab initio calculations on the formation energies of the GaAs surfaces and steps. By using the approach we found that the polytypism induced by chemical potential could be explained by the energy competition of lateral walls of the nucleus very well. Furthermore, the obtained results confirmed that the driving force of wurtzite phase nucleation originates from the lower formation energy of its (1 0 ⿿1 0) surface.

  8. Pristine and intercalated transition metal dichalcogenide superconductors

    NASA Astrophysics Data System (ADS)

    Klemm, Richard A.

    2015-07-01

    Transition metal dichalcogenides (TMDs) are quasi-two-dimensional layered compounds that exhibit strongly competing effects of charge-density wave (CDW) formation and superconductivity (SC). The weak van der Waals interlayer bonding between hexagonal layers of octahedral or trigonal prismatic TMD building blocks allows many polytypes to form. In the single layer 1 T polytype materials, one or more CDW states can form, but the pristine TMDs are not superconducting. The 2 H polytypes have two or more Fermi surfaces and saddle bands, allowing for dual orderings, which can be coexisting CDW and SC orderings, two SC gaps as in MgB2, two CDW gaps, and possibly even pseudogaps above the onset TCDW s of CDW orderings. Higher order polytypes allow for multiple CDW gaps and at least one superconducting gap. The CDW transitions TCDW s usually greatly exceed the superconducting transitions at their low Tc values, their orbital order parameters (OPs) are generally highly anisotropic and can even contain nodes, and the SC OPs can be greatly affected by their simultaneous presence. The properties of the CDWs ubiquitously seen in TMDs are remarkably similar to those of the pseudogaps seen in the high-Tc cuprates. In 2H-NbSe2, for example, the CDW renders its general s-wave SC OP orbital symmetry to be highly anisotropic and strongly reduces its Josephson coupling strength (IcRn) with the conventional SC, Pb. Hence, the pristine TMDs are highly "unconventional" in comparison with Pb, but are much more "conventional" than are the ferromagnetic superconductors such as URhGe. Applied pressure and intercalation generally suppress the TMD CDWs, allowing for enhanced SC formation, even in the 1 T polytype materials. The misfit intercalation compound (LaSe)1.14(NbSe2) and many 2 H -TMDs intercalated with organic Lewis base molecules, such as TaS2(pyridine)1/2, have completely incoherent c-axis transport, dimensional-crossover effects, and behave as stacks of intrinsic Josephson junctions

  9. Structure and magnetic properties of Ba{sub 5}Ce{sub 1.25}Mn{sub 3.75}O{sub 15}, a new 10H-polytype in the Ba-Ce-Mn-O system

    SciTech Connect

    Macias, Mario A.; Mentre, Olivier; Cuello, Gabriel J.; Gauthier, Gilles H.

    2013-02-15

    Based on the peculiar magnetic properties that are observed in pseudo one-dimensional manganites, we decided to synthesize the new Ba{sub 5}Ce{sub 1.25}Mn{sub 3.75}O{sub 15} compound. The preparation was performed by solid state reaction in air at about 1350 Degree-Sign C, for which we found that the compound crystallizes in a hexagonal symmetry with space group P6{sub 3}/mmc (No-194) and cell parameters a=b=5.7861(2) A and c=23.902(1) A. The structural description was correlated with neutron diffraction and bond valence calculations, confirming the presence of Ce{sup 4+} and Mn{sup 4+} segregated in the different crystallographic positions. Ba{sub 5}Ce{sub 1.25}Mn{sub 3.75}O{sub 15} displays evidence for strong AFM couplings already set at room temperature. The main arrangement of Mn{sup 4+} in magnetically isolated tetramers of face-sharing octahedra is responsible for a metamagnetic-like transition around 50 K. - Graphical abstract: The new Ba{sub 5}Ce{sub 1.25}Mn{sub 3.75}O{sub 15} polytype shows strong AFM couplings in magnetically isolated [Ce{sub 0.25}Mn{sub 3.75}O{sub 15}] tetramers of face-sharing octahedral, resulting in a metamagnetic-like transition around 50 K. Highlights: Black-Right-Pointing-Pointer Ba{sub 5}Ce{sub 1.25}Mn{sub 3.75}O{sub 15}, a new 10H polytype, has been prepared in the Ba-Ce-Mn-O system. Black-Right-Pointing-Pointer The compound crystallizes in the P6{sub 3}/mmc space group with (cchhh){sub 2} stacking sequence. Black-Right-Pointing-Pointer [Ce{sub 0.25}Mn{sub 3.75}O{sub 15}] tetramers are separated by [CeO{sub 6}] octahedra in the structure. Black-Right-Pointing-Pointer Instead of robust AFM ordering, a metamagnetic-like transition is found around 50 K.

  10. Role of polytypism and degree of hexagonality on the photoinduced optical second harmonic generation in SiC nanocrystalline films

    NASA Astrophysics Data System (ADS)

    Semenov, A.; Puziko, V.; Skorik, S.; Wojciechowski, A.; Fedorchuk, A. O.; Maciąg, A.

    2015-05-01

    Photoinduced optiсal second harmonic generation was studied in nanocrystalline SiC films prepared by the method of direct ion deposition. For the studies were chosen three types of polytypes (with different degree of hexagonality) - 24R with degree hexagonality G=25, 27R-G=44, 33R with - G=36. The bicolor photoinduced treatment was performed by the wavelengths 1064nm/532 nm by 15 ns YAG:Nd laser. The efficiency of the output SHG was evaluated by ratio of the corresponding signal intensities with respect to the references and by the time delay between the SHG and the fundamental maxima. Explanation of the observed effect is given within a framework of the occurrence of the nano-trapping levels in the film crystalline interfaces.

  11. Nucleation Mechanism of 6H-SiC Polytype Inclusions Inside 15R-SiC Crystals

    SciTech Connect

    Zhang, Y.; Zhang, L.; Chen, H.; Choi, G.; Raghothamachar, B.; Dudley, M.; Edgar, J.H.; Grasza, K.; Tymicki, E.; Su, D.; Zhu, Y.

    2010-06-01

    A model is presented for the nucleation mechanism of 6H-SiC polytype inclusions inside 15R-SiC boules. Inhomogeneous densities of screw dislocations lead to uneven growth rates, resulting in complex step overgrowth processes which can partially suppress the Burgers vector of a 15R 1c screw dislocation through the creation of Frank faults and Frank partial dislocations. Combined with stacking shifts induced by the passage of basal plane partial dislocations, it is shown that the partial Burgers vector suppression can leave behind a residual 6H 1c dislocation, which then acts as a nucleus for reproduction of 6H-SiC structure in the 15R-SiC crystal.

  12. Investigation of the transition layer in 3C-SiC/6H-SiC heterostructures

    SciTech Connect

    Lebedev, A. A.; Zamorianskaya, M. V.; Davydov, S. Yu.; Kirilenko, D. A.; Lebedev, S. P. Sorokin, L. M.; Shustov, D. B.; Scheglov, M. P.

    2013-11-15

    Transmission electron microscopy and the cathodoluminescence method are used to study the transition region in 3C-SiC/6H-SiC heterostructures. It is shown that this region is, as a rule, constituted by alternating 3C-SiC and 6H-SiC layers with the possible inclusion of other silicon carbide polytypes. An assumption is made that this structure of the transition region can be explained in terms of the model of spinodal decomposition.

  13. Evolution of polytypism in GaAs nanowires during growth revealed by time-resolved in situ x-ray diffraction.

    PubMed

    Schroth, Philipp; Köhl, Martin; Hornung, Jean-Wolfgang; Dimakis, Emmanouil; Somaschini, Claudio; Geelhaar, Lutz; Biermanns, Andreas; Bauer, Sondes; Lazarev, Sergey; Pietsch, Ullrich; Baumbach, Tilo

    2015-02-06

    In III-V nanowires the energetic barriers for nucleation in the zinc blende or wurtzite arrangement are typically of a similar order of magnitude. As a result, both arrangements can occur in a single wire. Here, we investigate the evolution of this polytypism in self-catalyzed GaAs nanowires on Si(111) grown by molecular beam epitaxy with time-resolved in situ x-ray diffraction. We interpret our data in the framework of a height dependent Markov model for the stacking in the nanowires. In this way, we extract the mean sizes of faultless wurtzite and zinc blende segments-a key parameter of polytypic nanowires-and their temporal evolution during growth. Thereby, we infer quantitative information on the differences of the nucleation barriers including their evolution without requiring a model of the nucleus.

  14. Polytypism in GaAs nanowires: determination of the interplanar spacing of wurtzite GaAs by X-ray diffraction.

    PubMed

    Köhl, Martin; Schroth, Philipp; Minkevich, Andrey A; Hornung, Jean Wolfgang; Dimakis, Emmanouil; Somaschini, Claudio; Geelhaar, Lutz; Aschenbrenner, Timo; Lazarev, Sergey; Grigoriev, Daniil; Pietsch, Ullrich; Baumbach, Tilo

    2015-01-01

    In GaAs nanowires grown along the cubic [111]c direction, zinc blende and wurtzite arrangements have been observed in their stacking sequence, since the energetic barriers for nucleation are typically of similar order of magnitude. It is known that the interplanar spacing of the (111)c Ga (or As) planes in the zinc blende polytype varies slightly from the wurtzite polytype. However, different values have been reported in the literature. Here, the ratio of the interplanar spacing of these polytypes is extracted based on X-ray diffraction measurements for thin GaAs nanowires with a mean diameter of 18-25 nm. The measurements are performed with a nano-focused beam which facilitates the separation of the scattering of nanowires and of parasitic growth. The interplanar spacing of the (111)c Ga (or As) planes in the wurtzite arrangement in GaAs nanowires is observed to be 0.66% ± 0.02% larger than in the zinc blende arrangement.

  15. Self-mixing magma in the Ruiz Peak rhyodacite (New Mexico, USA): A mechanism explaining the formation of long period polytypes of mica

    NASA Astrophysics Data System (ADS)

    Pignatelli, I.; Faure, F.; Mosser-Ruck, R.

    2016-12-01

    The rhyodacite of Ruiz Peak Volcano (New Mexico, USA) is an exceptional rock because it contains both long period and short period polytypes of mica. Our petrographic study shows that this rhyodacite is characterized by numerous disequilibrium textures of phenocrysts (mica, amphibole, clinopyroxene, olivine and plagioclase) contained within both dark-grey and reddish coloured groundmass. The presence of two groundmasses, as well as of disequilibrium textures (reaction rims, resorption, dendritic, skeletal morphologies, etc.) suggests a complex magmatic history. These two types of groundmass are not due to a mixing of magmas but result from a degassing process during the magma ascent in the conduit. The disequilibrium textures are interpreted to be the result of small, short-lived convection cells in the magmatic chamber, which may allow crystal-crystal, crystal-spiral and spiral-spiral interactions to occur, leading to the formation of long period polytypes of mica. For the first time, the relationships between the crystallographic features of mica and the host-rock formation are underlined in this study. It follows that long period polytypes of mica can be considered markers of the complex history of magmas.

  16. ESR study of p-type natural 2H-polytype MoS2 crystals: The As acceptor activity

    NASA Astrophysics Data System (ADS)

    Stesmans, A.; Iacovo, S.; Afanas'ev, V. V.

    2016-10-01

    Low-temperature (T = 1.7-77 K) multi frequency electron spin resonance (ESR) study on p-type 2H-polytype geological MoS2 crystals reveals p-type doping predominantly originating from As atoms substituting for S sites in densities of (2.4 ± 0.2) × 1017 cm-3. Observation of a "half field"(g ˜ 3.88) signal firmly correlating with the central Zeeman As accepter signal indicates the presence of spin S > ½ As agglomerates, which together with the distinct multicomponent makeup of the Zeeman signal points to manifest non-uniform As doping; only ˜13% of the total As response originates from individual decoupled As dopants. From ESR monitoring the latter vs. T, an activation energy Ea = (0.7 ± 0.2) meV is obtained. This unveils As as a noticeable shallow acceptor dopant, appropriate for realization of effective p-type doping in targeted 2D MoS2-based switching devices.

  17. Measurement of Optical, Mechanical and Transport properties of the hexagonal closed packed 4H polytype of metallic silver

    NASA Astrophysics Data System (ADS)

    Chakraborty, Indrani; Shirodkar, Sharmila N.; Gohil, Smita; Waghmare, Umesh; Ayyub, Pushan

    2013-03-01

    Optical, mechanical and transport property measurements were done on the hexagonal closed packed (hcp) 4H polytype of Ag with stacking sequence ABCBABCB.. grown as bulk films on Al2O3 substrates. Diffused reflectance measurements done on the 4H films showed a general loss of reflectivity amounting to a decrease of 35% as compared to normal fcc (3C) Ag near 500 nm with a blueshift of 5nm in the bulk plasmon frequency, possibly due to the modified electronic structure of the hcp form. Raman spectroscopic measurements showed the appearance of a peak at 64.3 cm-1 at 4K which underwent ``Mode softening,'' that is shifted to lower wave numbers with increase of temperature and disappeared above 350K. Low temperature transport measurements done on 4H films gave the in-plane resistivity value to be 39 times higher than that of a similarly synthesized fcc Ag film at 295 K. Vicker's microhardness measurements done on the 4H films showed that the 4H samples to be almost 5 times harder than the 3C Ag. Density functional theory simulations were done to obtain the phonon dispersion, band structure and nature of Fermi surface for the 4H Ag which corroborated with the experimental observations. The 4H form appears to be a much less metallic, darker and harder form of Ag.

  18. The Pleistocene glaciations and the evolutionary history of the polytypic snail species Arianta arbustorum (Gastropoda, Pulmonata, Helicidae).

    PubMed

    Gittenberger, E; Piel, W H; Groenenberg, D S J

    2004-01-01

    The evolutionary history of the snail Arianta arbustorum is controversial. This diverse, polytypic species has two distinct forms: one, with a globular shell and closed umbilicus, is found from lowland to high altitudes; the other, with a depressed shell and open umbilicus, is found at a few scattered, high altitude localities. What is the origin of these two forms? Some believe that the depressed shell is a recent, local, ecotypic adaptation to alpine environments. Others believe that this form is a relic of an ancestral condition that may have survived the Pleistocene glaciations on nunatak-like montane refugia, while the globular shell is a derived condition and its presence at high altitudes follows post-Pleistocene recolonisation. We analysed a portion of the mitochondrial gene cytochrome oxidase I for 100 snails of the species A. arbustorum, three additional Arianta species, and nine outgroup taxa from five genera, in order to understand the phylogeographic history of the species. Despite some confounding artefacts that are likely due to introgression among the morphological forms, the resulting phylogeny shows that the depressed shell is plesiomorphic, while the globular shell is derived. Moreover, their disparate histories suggest that the depressed shell variety survived the glaciations in pockets of alpine refugia, while the globular shell variety recolonised the alpine environment post-glacially.

  19. Selective epitaxial growth of zinc blende-derivative on wurtzite-derivative: the case of polytypic Cu2CdSn(S(1-x)Se(x))4 nanocrystals.

    PubMed

    Wu, Liang; Fan, Feng-Jia; Gong, Ming; Ge, Jin; Yu, Shu-Hong

    2014-03-21

    Polytypic nanocrystals with zinc blende (ZB) cores and wurtzite (WZ) arms, such as tetrapod and octopod nanocrystals, have been widely reported. However, polytypic nanocrystals with WZ cores and ZB arms or ends have been rarely reported. Here, we report a facile, solution-based approach to the synthesis of polytypic Cu2CdSn(S1-xSex)4 (CCTSSe) nanocrystals with ZB-derivative selectively engineered on (000±2)WZ facets of WZ-derived cores. Accordingly, two typical morphologies, i.e., bullet-like nanocrystals with a WZ-derivative core and one ZB-derivative end, and rugby ball-like nanocrystals with a WZ-derivative core and two ZB-derivative ends, can be selectively prepared. The epitaxial growth mechanism is confirmed by the time-dependent experiments. The ratio of rugby ball-like and bullet-like polytypic CCTSSe nanocrystals can be tuned through changing the amount of Cd precursor to adjust the reactivity difference between (0002)WZ and (000-2)WZ facets. These unique polytypic CCTSSe nanocrystals may find applications in energetic semiconducting materials for energy conversion in the future.

  20. Identifying and mapping the polytypes and orientation relationships in ZnO/CdSe core-shell nanowire arrays.

    PubMed

    Consonni, Vincent; Rapenne, Laetitia; Renou, Gilles; Roussel, Hervé; Gérard, Lionel; Cuscó, Ramón; Artús, Lluís; André, Régis; Rauch, Edgar F

    2016-09-30

    Identifying and mapping the crystalline phases and orientation relationships on the local scale in core-shell ZnO nanowire heterostructures are of primary importance to improve the interface quality, which governs the performances of the nanoscale devices. However, this represents a major difficulty, especially when the expected polytypes exhibit very similar properties as in the case of CdSe. In the present work, we address that issue in ZnO nanowire heterostructures involving a uniform and highly conformal CdSe shell grown by molecular beam epitaxy. It is shown by x-ray diffraction and Raman spectroscopy through the occurrence of the (101̄0) and (101̄1) diffraction peaks and of the [Formula: see text] mode at 34 cm(-1), respectively, that the CdSe shell is mostly crystallized into the wurtzite phase. By using automated crystal phase and orientation mapping with precession (ASTAR) in a transmission electron microscope and thus by benefiting from highly precise electron diffraction patterns, the CdSe shell is found to crystallize also into the minority zinc blende phase. The wurtzite CdSe shell is epitaxially grown on the top of ZnO nanowires, and some specific orientation relationships are mapped and revealed when grown on their vertical sidewalls. Zinc blende CdSe domains are also formed exclusively in the center of wurtzite CdSe grains located on the vertical sidewalls; both wurtzite and zinc blende CdSe crystalline phases have a strong orientation relationship. These findings reveal that ASTAR is a powerful technique to elucidate the structural properties on the local scale and to gain a deeper insight into their crystalline phases and orientation relationships, which is highly promising for many types of semiconducting nanowire heterostructures.

  1. Identifying and mapping the polytypes and orientation relationships in ZnO/CdSe core-shell nanowire arrays

    NASA Astrophysics Data System (ADS)

    Consonni, Vincent; Rapenne, Laetitia; Renou, Gilles; Roussel, Hervé; Gérard, Lionel; Cuscó, Ramón; Artús, Lluís; André, Régis; Rauch, Edgar F.

    2016-11-01

    Identifying and mapping the crystalline phases and orientation relationships on the local scale in core-shell ZnO nanowire heterostructures are of primary importance to improve the interface quality, which governs the performances of the nanoscale devices. However, this represents a major difficulty, especially when the expected polytypes exhibit very similar properties as in the case of CdSe. In the present work, we address that issue in ZnO nanowire heterostructures involving a uniform and highly conformal CdSe shell grown by molecular beam epitaxy. It is shown by x-ray diffraction and Raman spectroscopy through the occurrence of the (101¯0) and (101¯1) diffraction peaks and of the {{{{E}}}2}{{low}} mode at 34 cm-1, respectively, that the CdSe shell is mostly crystallized into the wurtzite phase. By using automated crystal phase and orientation mapping with precession (ASTAR) in a transmission electron microscope and thus by benefiting from highly precise electron diffraction patterns, the CdSe shell is found to crystallize also into the minority zinc blende phase. The wurtzite CdSe shell is epitaxially grown on the top of ZnO nanowires, and some specific orientation relationships are mapped and revealed when grown on their vertical sidewalls. Zinc blende CdSe domains are also formed exclusively in the center of wurtzite CdSe grains located on the vertical sidewalls; both wurtzite and zinc blende CdSe crystalline phases have a strong orientation relationship. These findings reveal that ASTAR is a powerful technique to elucidate the structural properties on the local scale and to gain a deeper insight into their crystalline phases and orientation relationships, which is highly promising for many types of semiconducting nanowire heterostructures.

  2. Structure-Band Gap Relationships in Hexagonal Polytypes and Low-Dimensional Structures of Hybrid Tin Iodide Perovskites.

    PubMed

    Stoumpos, Constantinos C; Mao, Lingling; Malliakas, Christos D; Kanatzidis, Mercouri G

    2017-01-03

    The present study deals with the structural characterization and classification of the novel compounds 1-8 into perovskite subclasses and proceeds in extracting the structure-band gap relationships between them. The compounds were obtained from the employment of small, 3-5-atom-wide organic ammonium ions seeking to discover new perovskite-like compounds. The compounds reported here adopt unique or rare structure types akin to the prototype structure perovskite. When trimethylammonium (TMA) was employed, we obtained TMASnI3 (1), which is our reference compound for a "perovskitoid" structure of face-sharing octahedra. The compounds EASnI3 (2b), GASnI3 (3a), ACASnI3 (4), and IMSnI3 (5) obtained from the use of ethylammonium (EA), guanidinium (GA), acetamidinium (ACA), and imidazolium (IM) cations, respectively, represent the first entries of the so-called "hexagonal perovskite polytypes" in the hybrid halide perovskite library. The hexagonal perovskites define a new family of hybrid halide perovskites with a crystal structure that emerges from a blend of corner- and face-sharing octahedral connections in various proportions. The small organic cations can also stabilize a second structural type characterized by a crystal lattice with reduced dimensionality. These compounds include the two-dimensional (2D) perovskites GA2SnI4 (3b) and IPA3Sn2I7 (6b) and the one-dimensional (1D) perovskite IPA3SnI5 (6a). The known 2D perovskite BA2MASn2I7 (7) and the related all-inorganic 1D perovskite "RbSnF2I" (8) have also been synthesized. All compounds have been identified as medium-to-wide-band-gap semiconductors in the range of Eg = 1.90-2.40 eV, with the band gap progressively decreasing with increased corner-sharing functionality and increased torsion angle in the octahedral connectivity.

  3. Effects of growth temperature and growth rate on polytypes in gold-catalyzed GaAs nanowires studied by in situ X-ray diffraction

    NASA Astrophysics Data System (ADS)

    Takahasi, Masamitu; Kozu, Miwa; Sasaki, Takuo

    2016-04-01

    The polytypism of GaAs nanowires was investigated by in situ X-ray diffraction under different growth conditions. The growth of nanowires was found to start with the formation of the zincblende structure, followed by the growth of the wurtzite structure. The observed growth process of nanowires was well reproduced by simulations based on a layer-by-layer nucleation model. At a low growth temperature and a high growth rate, stacking faults were found to be frequently introduced owing to the reduction in energy barrier. As a result, the zincblend and wurtzite segments in nanowires were highly fragmented and the wurtzite structure was formed in the early stage of growth.

  4. Polytypes and twins in the diamond-lonsdaleite system formed by high-pressure and high-temperature treatment of graphite.

    PubMed

    Kulnitskiy, Boris; Perezhogin, Igor; Dubitsky, Gennady; Blank, Vladimir

    2013-10-01

    As a result of the high-temperature and high-pressure treatment of graphite we obtained a powder containing diamond and lonsdaleite. The structure and properties of the powder were studied by transmission electron microscopy (TEM) and electron energy-loss spectroscopy (EELS). It was found that the synthesized material contains not only diamond nanoparticles, but also some relatively large (up to several nanometers) fragments of lonsdaleite. 4H and 6H polytypes were found in some of the diamond particles. Incoherent twin boundaries were observed in the diamond particle containing fragments of lonsdaleite.

  5. High-pressure BaCrO{sub 3} polytypes and the 5H–BaCrO{sub 2.8} phase

    SciTech Connect

    Arévalo-López, Angel M.; Paul Attfield, J.

    2015-12-15

    Polytypism of BaCrO{sub 3} perovskites has been investigated at 900–1100 °C and pressures up to 22 GPa. Hexagonal 5H, 4H, and 6H perovskites are observed with increasing pressure, and the cubic 3C perovskite (a=3.99503(1) Å) is observed in bulk form for the first time at 19–22 GPa. An oxygen-deficient material with limiting composition 5H–BaCrO{sub 2.8} is synthesised at 1200 °C under ambient pressure. This contains double tetrahedral Cr{sup 4+} layers and orders antiferromagnetically below 260 K with a (0 0 1/2) magnetic structure. - Graphical abstract: Hexagonal 5H, 4H, and 6H perovskites polytypes of BaCrO{sub 3} are observed with increasing pressure and the cubic 3C perovskite is stabilised in bulk form for the first time at 19–22 GPa. Oxygen-deficient 5H–BaCrO{sub 2.8} synthesised at ambient pressure contains double tetrahedral Cr{sup 4+} layers and orders antiferromagnetically below 260 K with a (0 0 1/2) magnetic structure.

  6. Pressure dependence of the phonon spectrum in BaTiO3 polytypes studied by ab initio calculations

    NASA Astrophysics Data System (ADS)

    Seo, Yu-Seong; Ahn, Jai Seok

    2013-07-01

    We report the first principles investigations on the phonons of three polytypes of BaTiO3 (BTO): paraelectric (PE) cubic Pm3¯m and two ferroelectric (FE) phases, tetragonal P4mm and rhombohedral R3m. The phonon frequencies were calculated using various exchange-correlation functionals, including density functional theory, Hartree-Fock approximation, and their hybrids were reviewed. The pressure-induced interplays between the modes from individual phases were explored by calculating the phonon modes as a function of pressure, P from -15 to 230 GPa. The pressure-sensitive modes of the FE phases showed softening and converged to the modes of the PE phase at pressures below ˜10 GPa. These results on the FE phases can be interpreted as phonon precursors for a change in symmetry from low- to high-symmetry and partly as a theoretical explanation for the pressure-induced mode-coupling behaviors reported by Sood [Phys. Rev. BPRBMDO1098-012110.1103/PhysRevB.51.8892 51, 8892 (1995)]. As pressure is applied further beyond ˜50 GPa to the cubic PE phase, the lowest F1u mode softens again and diverges into two separate modes of tetragonal FE P4mm at above ˜150 GPa. These phonon-branching behaviors at high pressures provide a clear reconfirmation of the re-entrant ferroelectricity predicted in earlier papers [Phys. Rev. Lett.PRLTAO0031-900710.1103/PhysRevLett.95.196804 95, 196804 (2005); Phys. Rev. BPRBMDO1098-012110.1103/PhysRevB.74.180101 74, 180101 (2006); Phys. Rev. BPRBMDO1098-012110.1103/PhysRevB.85.054108 85, 054108 (2012)]. The high-pressure-re-entrant FE polarization was not found in the rhombohedral structure. Instead, the centrosymmetric R3¯m phase was favored at above ˜30 GPa. The phonon modes calculated for the phonon-propagation vectors in the high-symmetry directions show that the Pm3¯m phase exhibits polar instability at the Γ point and nonpolar instability at the X, M, and R points under high pressure.

  7. Synthesis, characterization and sorption properties of functionalized Cr-MIL-101-X (X=-F, -Cl, -Br, -CH3, -C6H4, -F2, -(CH3)2) materials

    NASA Astrophysics Data System (ADS)

    Buragohain, Amlan; Couck, Sarah; Van Der Voort, Pascal; Denayer, Joeri F. M.; Biswas, Shyam

    2016-06-01

    Four existing and three new functionalized chromium terephthalates having MIL-101 topology and denoted as Cr-MIL-101-X (existing ones with X=-F, 1-F; -Cl, 2-Cl; -Br, 3-Br; -CH3, 4-CH3; new ones with X=-C6H4, 5-C6H4; -F2, 6-F2, -(CH3)2, 7-(CH3)2) were synthesized under hydrothermal conditions. All the materials except 5-C6H4 could be prepared by a general synthetic route, in which the mixtures of CrO3, H2BDC-X (BDC=1,4-benzenedicarboxylate) linkers, conc. HCl and water with a molar ratio of 1:1:3.9:222.2 were reacted at 180 °C for 144 h. Compared to the 144 h of synthesis time, three of the compounds, namely 1-Cl, 2-Br and 5-C6H4, could be prepared in much shorter reaction times (12-18 h at 180-210 °C). The materials possess high thermal stability up to 270-300 °C in an air atmosphere. The activated compounds exhibit significant porosity (SBET range: 1273-2135 m2 g-1). At 0 °C and 1 bar, the CO2 adsorption capacities of the compounds fall in the 1.7-2.9 mmol g-1 range. Compounds 1-F and 6-F2 showed enhanced CO2 uptake values compared to parent Cr-MIL-101. The benzene adsorption capacities of the compounds lie in the range of 66.2-139.5 molecules per unit cell at 50 °C and p/p0=0.35. The increased benzene uptake value of 1-F compared to un-functionalized Cr-MIL-101 and 4-CH3 suggests that the fluorination has induced more hydrophobicity in Cr-MIL-101 as compared to the methylation.

  8. The Nature of the Dimethyl-aluminum (-gallium and -indium) Methylphenylamide Dimers in Solution and the Molecular Structure of (CH3)2 InN (CH3)- (C6H5)2.

    DTIC Science & Technology

    1981-03-16

    by evaluating the effects of solvent and temperature on the cis/trans isomer ratios. All data are consistent with the hypotheses that the aluminum...investigated by IH NMR spectroscopy by evaluating the effects of solvent and temperature on the cis/trans isomer ratios. All data are consistent with...essentially independent of the nature of the nonreactive solvent . 3𔃾 Thus, [(CH 3 )2AIN(CH3)(C6Hs) 2 exists as an 83%/17% mixture of cis/trans isomers in

  9. In situ doping of catalyst-free InAs nanowires with Si: Growth, polytypism, and local vibrational modes of Si

    SciTech Connect

    Dimakis, Emmanouil; Ramsteiner, Manfred; Huang, Chang-Ning; Trampert, Achim; Riechert, Henning; Geelhaar, Lutz; Davydok, Anton; Biermanns, Andreas; Pietsch, Ullrich

    2013-09-30

    Growth and structural aspects of the in situ doping of InAs nanowires with Si have been investigated. The nanowires were grown catalyst-free on Si(111) substrates by molecular beam epitaxy. The supply of Si influenced the growth kinetics, affecting the nanowire dimensions, but not the degree of structural polytypism, which was always pronounced. As determined by Raman spectroscopy, Si was incorporated as substitutional impurity exclusively on In sites, which makes it a donor. Previously unknown Si-related Raman peaks at 355 and 360 cm{sup −1} were identified, based on their symmetry properties in polarization-dependent measurements, as the two local vibrational modes of an isolated Si impurity on In site along and perpendicular, respectively, to the c-axis of the wurtzite InAs crystal.

  10. In situ doping of catalyst-free InAs nanowires with Si: Growth, polytypism, and local vibrational modes of Si

    NASA Astrophysics Data System (ADS)

    Dimakis, Emmanouil; Ramsteiner, Manfred; Huang, Chang-Ning; Trampert, Achim; Davydok, Anton; Biermanns, Andreas; Pietsch, Ullrich; Riechert, Henning; Geelhaar, Lutz

    2013-09-01

    Growth and structural aspects of the in situ doping of InAs nanowires with Si have been investigated. The nanowires were grown catalyst-free on Si(111) substrates by molecular beam epitaxy. The supply of Si influenced the growth kinetics, affecting the nanowire dimensions, but not the degree of structural polytypism, which was always pronounced. As determined by Raman spectroscopy, Si was incorporated as substitutional impurity exclusively on In sites, which makes it a donor. Previously unknown Si-related Raman peaks at 355 and 360 cm-1 were identified, based on their symmetry properties in polarization-dependent measurements, as the two local vibrational modes of an isolated Si impurity on In site along and perpendicular, respectively, to the c-axis of the wurtzite InAs crystal.

  11. Size- and structure-dependence of thermal and mechanical behaviors of single-crystalline and polytypic superlattice ZnS nanowires

    SciTech Connect

    Moon, Junghwan; Cho, Maenghyo; Zhou, Min

    2015-06-07

    Molecular dynamics (MD) simulations are carried out to study the thermal and mechanical behaviors of single-crystalline wurtzite (WZ), zinc-blende (ZB), and polytypic superlattice ZnS nanowires containing alternating WZ and ZB regions with thicknesses between 1.85 nm and 29.62 nm under tensile loading. The wires analyzed have diameters between 1.77 nm and 5.05 nm. The Green-Kubo method is used to calculate the thermal conductivity of the wires at different deformed states. A non-equilibrium MD approach is used to analyze the thermal transport behavior at the interfaces between different structural regions in the superlattice nanowires (SLNWs). The Young's modulus and thermal conductivity of ZB nanowires are approximately 2%–12% and 23%–35% lower than those of WZ nanowires, respectively. The lower initial residual compressive stress due to higher irregularity of surface atoms causes the Young's modulus of ZB nanowires to be lower. The dependence of the thermal conductivity on structure comes from differences in phonon group velocities associated with the different wires. The thermal conductivity of polytypic superlattice nanowires is up to 55% lower than that of single-crystalline nanowires, primarily because of phonon scattering at the interfaces and the resulting lower effective phonon mean free paths for each structural region. As the periodic lengths (1.85–29.62 nm) and specimen lengths (14.81–59.24 nm) of SLNWs decrease, these effects become more pronounced, causing the thermal conductivity to further decrease by up to 30%.

  12. Possibility of combining ferroelectricity and Rashba-like spin splitting in monolayers of the 1 T -type transition-metal dichalcogenides M X2 (M = Mo ,W ;X =S ,Se ,Te )

    NASA Astrophysics Data System (ADS)

    Bruyer, Emilie; Di Sante, Domenico; Barone, Paolo; Stroppa, Alessandro; Whangbo, Myung-Hwan; Picozzi, Silvia

    2016-11-01

    First-principles calculations were carried out to explore the possible coupling between spin-polarized electronic states and ferroelectric polarization in monolayers of transition-metal dichalcogenides M X2 (M =Mo ,W ;X =S ,Se ,Te ) with distorted octahedrally coordinated 1 T structures. For d2 metal ions, two competing metal clustering effects can take place, where metal ions are arranged in trimers or zigzag chains. Among these, the former structural distortion comes along with an improper ferroelectric phase which persists in the monolayer limit. Switchable Rashba-like spin-polarization features are predicted in the trimerized polytype, which can be permanently tuned by acting on its ferroelectric properties. The polar trimerized structure is found to be stable for 1 T -MoS2 only, while the nonpolar polytype with zigzag metal clustering is predicted to stabilize for other transition-metal dichalcogenides with d2 metal ions.

  13. Thermoelectric properties of the 3C, 2H, 4H, and 6H polytypes of the wide-band-gap semiconductors SiC, GaN, and ZnO

    SciTech Connect

    Huang, Zheng; Lü, Tie-Yu; Wang, Hui-Qiong; Zheng, Jin-Cheng

    2015-09-15

    We have investigated the thermoelectric properties of the 3C, 2H, 4H, and 6H polytypes of the wide-band-gap(n-type) semiconductors SiC, GaN, and ZnO based on first-principles calculations and Boltzmann transport theory. Our results show that the thermoelectric performance increases from 3C to 6H, 4H, and 2H structures with an increase of hexagonality for SiC. However, for GaN and ZnO, their power factors show a very weak dependence on the polytype. Detailed analysis of the thermoelectric properties with respect to temperature and carrier concentration of 4H-SiC, 2H-GaN, and 2H-ZnO shows that the figure of merit of these three compounds increases with temperature, indicating the promising potential applications of these thermoelectric materials at high temperature. The significant difference of the polytype-dependent thermoelectric properties among SiC, GaN, and ZnO might be related to the competition between covalency and ionicity in these semiconductors. Our calculations may provide a new way to enhance the thermoelectric properties of wide-band-gap semiconductors through atomic structure design, especially hexagonality design for SiC.

  14. The lead acceptor in p-type natural 2H-polytype MoS2 crystals evidenced by electron paramagnetic resonance

    NASA Astrophysics Data System (ADS)

    Iacovo, S.; Stesmans, A.; Houssa, M.; Afanas'ev, V. V.

    2017-03-01

    A low-temperature (T  =  1.5-8 K) electron paramagnetic resonance study of p-type 2H-polytype natural MoS2 crystals reveals a previously unreported anisotropic signal of corresponding defect density (spin S  =  ½) ~5  ×  1014 cm-3. For the applied magnetic field B//c-axis, the response is comprised of a single central asymmetric Zeeman peak at zero-crossing g  =  2.102(1), amid a symmetrically positioned hyperfine doublet of splitting 6.6(2) G. Field angular observations reveal a two-branch g pattern, indicative of a defect of lower than axial symmetry, likely orthorhombic (C 2v). Based on the signal specifics, it is ascribed to a system of decoupled Pb impurities substituting for Mo, the defect operating as an acceptor, with estimated thermal activation energy  >10 meV. Supporting theoretical anticipation, the results pinpoint the conduct of the Pb impurity in layered MoS2.

  15. Population dynamics and dephasing of excitons and electron-hole pairs in polytype wurtzite/zinc-blende InP nanowires

    NASA Astrophysics Data System (ADS)

    Wagner, H. P.; Kaveh, M.; Gao, Q.; Tan, H.; Jagadish, C.; Langbein, W.

    2017-01-01

    We investigated the dephasing and population dynamics of electron-hole (e-h) pairs and excitons in vapor-liquid-solid grown polytype wurtzite/zinc-blende (WZ/ZB) InP nanowires (NWs) using heterodyne four-wave mixing (HFWM) in three-beam configuration at temperatures from 80 to 270 K. The photon energy of the 100 fs excitation pulses was varied to predominantly excite either mobile excitons and e-h pairs or indirect WZ/ZB excitons. The population dynamics reveal a multiexponential decay with time constants ranging over six orders of magnitude. The dynamics has been interpreted by a coupled rate equation model which considers WZ and ZB electron states, donor electron states, and band bending trapping holes to the surface. The model reproduces the essential features of the experimentally observed dynamics at different excitation energies, fluences, and lattice temperatures. Intraband thermalization is reached within 5-50 ps, after which the nonradiative recombination dominates the dynamics. Notably, the screenable surface band bending results in long-lived spatially separated carriers, causing a photogenerated, spatially separated electron and hole density which is dominating the long-lived dynamics.

  16. Rare earth ferrites LuFe2O4±x polymorphism, polytypism and metastable phases

    NASA Astrophysics Data System (ADS)

    Hervieu, M.; Damay, F.; Maignan, A.; Martin, C.

    2015-10-01

    This work is a compendium of the structural properties of layered LnFe2O4±x ferrites, focussed on recently discovered polymorphs and their transitions through five complex commensurate and incommensurate modulated structures. These phases are obtained varying the oxygen content (reversibly from O4.0 to O4.5) or applying high pressure (up to 15 GPa). The relationships between the different structures are discussed and models are proposed. These ferrites, which contain magnetic cations and exhibit remarkable 3D flexibility, open the road for magnetic, electric, catalytic or energy materials.

  17. Effects of Polytypism on Optical Properties and Band Structure of Individual Ga(N)P Nanowires from Correlative Spatially Resolved Structural and Optical Studies.

    PubMed

    Dobrovolsky, Alexander; Persson, Per O Å; Sukrittanon, Supanee; Kuang, Yanjin; Tu, Charles W; Chen, Weimin M; Buyanova, Irina A

    2015-06-10

    III-V semiconductor nanowires (NWs) have gained significant interest as building blocks in novel nanoscale devices. The one-dimensional (1D) nanostructure architecture allows one to extend band structure engineering beyond quantum confinement effects by utilizing formation of different crystal phases that are thermodynamically unfavorable in bulk materials. It is therefore of crucial importance to understand the influence of variations in the NWs crystal structure on their fundamental physical properties. In this work we investigate effects of structural polytypism on the optical properties of gallium phosphide and GaP/GaNP core/shell NW structures by a correlative investigation on the structural and optical properties of individual NWs. The former is monitored by transmission electron microscopy, whereas the latter is studied via cathodoluminescence (CL) mapping. It is found that structural defects, such as rotational twins in zinc blende (ZB) GaNP, have detrimental effects on light emission intensity at low temperatures by promoting nonradiative recombination processes. On the other hand, formation of the wurtzite (WZ) phase does not notably affect the CL intensity neither in GaP nor in the GaNP alloy. This suggests that zone folding in WZ GaP does not enhance its radiative efficiency, consistent with theoretical predictions. We also show that the change in the lattice structure have negligible effects on the bandgap energies of the GaNP alloys, at least within the range of the investigated nitrogen compositions of <2%. Both WZ and ZB GaNP are found to have a significantly higher efficiency of radiative recombination as compared with that in parental GaP, promising for potential applications of GaNP NWs as efficient nanoscale light emitters within the desirable amber-red spectral range.

  18. Lithium-stuffed diamond polytype Zn-Tt structures (Tt = Sn, Ge): the two lithium-zinc-tetrelides Li3Zn2Sn4 and Li2ZnGe3.

    PubMed

    Stegmaier, Saskia; Fässler, Thomas F

    2013-03-18

    In view of the search for alternative structures for Li ion battery materials and electron-poor framework semiconductors for thermoelectric applications, the systems Li-Zn-Tt with Tt = Ge or Sn were investigated. Li3Zn2Sn4 and Li2ZnGe3 were obtained by high-temperature syntheses from the elements. The crystal structures of both phases were determined with single-crystal X-ray diffraction methods and the electronic structure of Li3Zn2Sn4 was analyzed by means of DFT calculations (TB-LMTO-ASA). Both phases show diamond polytype analogous Zn-Tt networks with tetrahedrally four-coordinated Zn and Tt atoms. The new phase Li3Zn2Sn4 crystallizes in space group P6(3)/mmc (No. 194) with lattice parameters a = 4.528(1) Å and c = 22.119(2) Å. Zn and Sn atoms are fully ordered on three sites that constitute a 6H diamond polytype like network. Li2ZnGe3 is also described in space group P6(3)/mmc (No. 194) with lattice parameters a = 4.167(1) Å and c = 6.754(1) Å. The Zn-Ge substructure is a hexagonal diamond (2H polytype) like network. The existence of such a Ge-rich Li-Zn-Ge phase has already been reported, but a full structure determination has not yet been published. No indication for an ordering of Zn and Ge atoms on different sites could be deduced from the X-ray diffraction data. Band structure calculations for Li3Zn2Sn4 indicate that the phase is metallic, with the Fermi level at the flank of a pseudogap in the density of states curve. The topological analysis of the electron localization function (ELF) shows covalent Sn-Sn bonding and lone pair like valence basins for the Sn atoms. Concerning the appearance of the lone pair like ELF basins, a strong influence of the basis set for Li that is employed in the calculations is found.

  19. Boundary conditions for transition-metal dichalcogenide monolayers in the continuum model

    NASA Astrophysics Data System (ADS)

    Péterfalvi, Csaba G.; Kormányos, Andor; Burkard, Guido

    2015-12-01

    We derive the boundary conditions for MoS2 and similar transition-metal dichalcogenide honeycomb (2H polytype) monolayers with the same type of k .p Hamiltonian within the continuum model around the K points. In an effective two-band description, the electron-hole symmetry breaking quadratic terms are also taken into account. We model the effect of the edges with a linear edge constraint method that has been applied previously to graphene. Focusing mainly on zigzag edges, we find that different reconstruction geometries with different edge atoms can generally be described with one scalar parameter varying between 0 and 2 π . We analyze the edge states and their dispersion relation in MoS2 in particular, and we find good agreement with the results of previous density functional theory calculations for various edge types.

  20. Transition Planning

    ERIC Educational Resources Information Center

    Statfeld, Jenna L.

    2011-01-01

    Post-school transition is the movement of a child with disabilities from school to activities that occur after the completion of school. This paper provides information about: (1) post-school transition; (2) transition plan; (3) transition services; (4) transition planning; (5) vocational rehabilitation services; (6) services that are available…

  1. Cooperative reactivity of early-late heterodinuclear transition metal complexes with polar organic substrates

    PubMed

    Gade; Memmler; Kauper; Schneider; Fabre; Bezougli; Lutz; Galka; Scowen; McPartlin

    2000-02-18

    A comprehensive investigation into the cooperative reactivity of two chemically complementary metal-complex fragments in early-late heterodinuclear complexes has been carried out. Reaction of the partially fluorinated tripodal amidozirconium complexes [HC-(SiMe2NR)3Zr(mu-Cl)2Li(OEt2)2] (R = 2-FC6H4: 2a, 2,3,4-F3C6H4: 2b) with K[CpM(CO)2] (M=Fe, Ru) afforded the stable metal-metal bonded heterodinuclear complexes [HC[SiMe2NR]3-Zr-MCp(CO)2] (3-6). Reaction of the dinuclear complexes with methyl isonitrile as well as the heteroallenes CO2, CS2, RNCO and RNCS led to insertion into the polar metal-metal bond. Two of these complexes, [HC[SiMe2N(2-FC6-H4)]3Zr(S2C)Fe(CO)2Cp] (9a) and [HC-[SiMe2N(2-FC2H4)]3Zr-(SCNPh)Fe(CO)2-Cp] (12), have been structurally characterized by a single crystal X-ray structure analysis, proving the structural situation of the inserted substrate as a bridging ligand between the early and late transition metal centre. The reactivity towards organic carbonyl derivatives proved to be varied. Reaction of the heterobimetallic complexes with benzyl and ethylbenzoate led to the cleavage of the ester generating the respective alkoxozirconium complexes [HC[SiMe2N(2-FC6H4)]3ZrOR] (R = Ph-CH2: 13a, Et: 13b) along with [CpFe-[C(O)Ph](CO)2], whereas the analogous reaction with ethyl formate gave 13b along with [CpFeH(CO)2]; this latter complex results from the instability of the formyliron species initially formed. Aryl aldehydes were found to react with the Zr-M complexes according to a Cannizzaro disproportionation pattern yielding the aroyliron and ruthenium complexes along with the respective benzoxyzirconium species. The transfer of the aldehyde hydrogen atom in the course of the reaction was established in a deuteriation experiment. [HC[SiMe2-N(2-FC6H4)]3Zr-M(CO)2Cp] reacted with lactones to give the ring-opened species containing an alkoxozirconium and an acyliron or acylruthenium fragment; the latter binds to the early transition metal centre through

  2. Work transitions.

    PubMed

    Fouad, Nadya A; Bynner, John

    2008-01-01

    Individuals make choices in, and adjust to, a world of work that is often a moving target. Because work is so central to human functioning, and transitions in and out of work can have major mental health repercussions, the authors argue that applied psychologists in health services need to understand those transitions. This article focuses on the different types of transition throughout a person's working life and the resources needed at different stages to ensure the success of these transitions. The authors start by examining the roles of capability and adaptability in supporting and facilitating adjustment to work transitions and their relation to identity development. They then examine the role of social and institutional contexts in shaping work transitions and their outcomes. The authors focus on voluntary versus involuntary transitions and then broaden the lens in discussing the policy implications of research on work transitions.

  3. Transitional Care

    ERIC Educational Resources Information Center

    Naylor, Mary; Keating, Stacen A.

    2008-01-01

    Transitional care encompasses a broad range of services and environments designed to promote the safe and timely passage of patients between levels of health care and across care settings. High-quality transitional care is especially important for older adults with multiple chronic conditions and complex therapeutic regimens, as well as for their…

  4. Transition metals

    PubMed Central

    Rodrigo-Moreno, Ana; Poschenrieder, Charlotte; Shabala, Sergey

    2013-01-01

    Transition metals such as Iron (Fe) and Copper (Cu) are essential for plant cell development. At the same time, due their capability to generate hydroxyl radicals they can be potentially toxic to plant metabolism. Recent works on hydroxyl-radical activation of ion transporters suggest that hydroxyl radicals generated by transition metals could play an important role in plant growth and adaptation to imbalanced environments. In this mini-review, the relation between transition metals uptake and utilization and oxidative stress-activated ion transport in plant cells is analyzed, and a new model depicting both apoplastic and cytosolic mode of ROS signaling to plasma membrane transporters is suggested. PMID:23333964

  5. High-pressure Synthesis and Magnetic Properties of 4d and 5d Transition-metal Oxides

    NASA Astrophysics Data System (ADS)

    Cheng, J.-G.

    2011-03-01

    , but to the orbital hybridization between 6 s and . As the end member, metallic undergoes a first-order phase transition to a metallic Imma phase at . (2) A new polytype phase 5H has been synthesized under a narrow pressure range, which fits the structural sequence along with other polytypes 9R, 6H and 3C of t ~ . The ground states of these polytypes evolve from a ferromagnetic insulator with 3 in the 9R phase to a ferromagnetic metal with BaIrO in the 5H phase, and finally to an exchange-enhanced paramagnetic metal in the 6H phase, which may be close to a quantum critical point. (3) In the system, high pressure stabilizes the post-perovskite structure on the Ca side (x < 0.3), but favors the perovskite structure on the Sr side (x > 0.6). Refs. J.-G. Cheng, et al. PRB 80, 104430(2009); 80, 174426 (2009);81, 134412(2010); JACS 131, 7461(2009). Supported by NSF-DMR-0904282. Work under the supervision of Profs. J.-S. Zhou and J. B. Goodenough.

  6. Microwave Measurements of Structure Changes for Ligand Molecules Bound to Transition Metals

    NASA Astrophysics Data System (ADS)

    Kukolich, Stephen G.

    2010-06-01

    Precise values for structural parameters for transition metal complexes have been obtained from high-resolution PBFT microwave measurements. The changes in structural parameters for the small organic molecule ligands are relatively large and well-determined. Results for C_2H_4-Os-(CO)_4, C_2H_4-Fe-(CO)_4, C_2H_2-Re-(O)_2CH_3, C_6H_6-Cr-(CO)_3 and C_4H_6-Fe-(CO)_3 will be discussed and compared. For the Ethylene Osmium Tetracarbonyl complex, the experimental ethylene C-C bond length is 1.432 Å, which falls between the free ethylene value of 1.339 Å { } and the ethane value of 1.534 Å. The angle between the plane of the CH_2 group and the extended ethylene C-C bond (out-of-plane angle) is 26 °. Ethylene structural changes are larger for the Os complex than for the similar Fe complex. For Acetylene Methyl dioxoRhenium, the C-C bond length is increased by 0.08 Å { } to 1.29 Å. The H-C-C interbond angles are reduced from 180 ° to 146 °, and 147 °. The planar, D_6_h structure of free benzene is changed to a C_3_v structure with alternating C-C bond lengths due to interaction with Cr-(CO)_3 in the complex. The structural changes are small but significant, since the benzene reactivity is changed. For Butadiene Iron Tricarbonyl, the terminal CH_2 groups are rotated by 28 ° out of the butadiene plane and the CH_2 plane is folded away from the butadiene C1-C2 axis by 27 ° in a direction away from the iron atom. Free butadiene has a trans planar conformation, much different from the distorted cis conformation in the complex. These structural changes are usually accompanied by significant changes in reactivity, which has proved useful for transition metal catalysts and metal containing enzymes.

  7. Presidential Transitions

    DTIC Science & Technology

    2006-06-09

    Podesta for the Heads of Executive Departments and Agencies, “Presidential Transition Guidance,” Nov. 13, 2000. 89 U.S. General Services Administration...2000, presidential election, White House Chief of Staff John Podesta issued a November 13, 2000, memorandum to executive branch agencies stating that

  8. Tessellations & Transitions.

    ERIC Educational Resources Information Center

    Cassidy, Joan

    1998-01-01

    Describes two sixth-grade lessons on the work of M. C. Escher: (1) the first lesson instructs students on tessellations, or tiles that interlock in a repeated pattern; (2) the second lesson explores Escher's drawings of transitions from two- to three-dimensional space. (DSK)

  9. Eliminating Transitions

    ERIC Educational Resources Information Center

    Gallick, Barb; Lee, Lisa

    2010-01-01

    Adults often find themselves transitioning from one activity to another in a short time span. Most of the time, they do not feel they have a lot of control over their schedules, but wish that they could carve out extended time to relax and focus on one project. Picture a group of children in the block area who have spent 15 or 20 minutes building…

  10. Luminescent transition metal dichalcogenide nanosheets through one-step liquid phase exfoliation

    NASA Astrophysics Data System (ADS)

    Mar Bernal, M.; Álvarez, Lidia; Giovanelli, Emerson; Arnáiz, Adriana; Ruiz-González, Luisa; Casado, Santiago; Granados, Daniel; Pizarro, Ana M.; Castellanos-Gomez, Andres; Pérez, Emilio M.

    2016-09-01

    Liquid phase exfoliation (LPE) from the bulk is an adequate method for the mass-production of thin nanosheets of transition metal dichalcogenides (TMDCs). However, making suspensions in which the extraordinary properties of mechanically exfoliated TMDCs are observable remains a challenge. We describe a mild LPE method to produce luminescent suspensions of MoS2 and WS2 in N-methylpyrrolidone or isopropanol/water mixtures, without the need for a purification step. The key differences in our experimental procedure compared to previously reported LPE methods are the use of mild bath sonication at controlled temperature and the low initial concentration of the parent TMDC. Spectroscopic and AFM data confirm that an overwhelming majority of the sample is composed of ultrathin nanosheets. HREM data support the formation of the luminescent 2H polytype. The ultrathin nanosheets can be transferred to pure water and cell culture medium. Confocal fluorescence microscopy experiments on MCF-7 breast cancer cells exposed to LPE WS2 show that the cells are viable and the photoluminescence of the nanosheets is detectable.

  11. Transition metal doping of GaSe implemented with low temperature liquid phase growth

    NASA Astrophysics Data System (ADS)

    Lei, Nuo; Sato, Youhei; Tanabe, Tadao; Maeda, Kensaku; Oyama, Yutaka

    2017-02-01

    Our group works on improving the conversion efficiencies of terahertz (THz) wave generation using GaSe crystals. The operating principle is based on difference frequency generation (DFG) which has the advantages such as high output power, a single tunable frequency, and room temperature operation. In this study, GaSe crystals were grown by the temperature difference method under controlled vapor pressure (TDM-CVP). It is a liquid phase growth method with temperature 300 °C lower than that of the Bridgman method. Using this method, the point defects concentration is decreased and the polytype can be controlled. The transition metal Ti was used to dope the GaSe in order to suppress free carrier absorption in the low frequency THz region. As a result, a deep acceptor level of 38 meV was confirmed as being formed in GaSe with 1.4 at% Ti doping. Compared with undoped GaSe, a decrease in carrier concentration ( 1014 cm-3) at room temperature was also confirmed. THz wave transmittance measurements reveal the tendency for the absorption coefficient to increase as the amount of dopant is increased. It is expected that there is an optimum amount of dopant.

  12. Topological Lifshitz transitions

    NASA Astrophysics Data System (ADS)

    Volovik, G. E.

    2017-01-01

    Different types of Lifshitz transitions are governed by topology in momentum space. They involve the topological transitions with the change of topology of Fermi surfaces, Weyl and Dirac points, nodal lines, and also the transitions between the fully gapped states.

  13. Transitions: A Personal Perspective.

    ERIC Educational Resources Information Center

    Wood, Ann Stace

    1995-01-01

    Distinguishes between unchosen transitions (children maturing and leaving, parents aging, companies downsizing) and chosen ones (moving, divorce, marriage, career changes). Describes the steps one goes through: uneasiness, renewed energy, complaining, exploration, partial transition, and the completed transition. (JOW)

  14. Tips for Transition

    ERIC Educational Resources Information Center

    Kellems, Ryan, Comp.; Morningstar, Mary E., Comp.

    2009-01-01

    The Tips for Transition contains 134 Transition Tips submitted from all over the country by practitioners. The purpose of the Tips was to identify grassroots transition practices being used by practitioners. Tips are categorized into the following domains: (1) Transition Planning; (2) Student Involvement; (3) Family Involvement; (4) Curriculum and…

  15. Gas turbine combustor transition

    DOEpatents

    Coslow, Billy Joe; Whidden, Graydon Lane

    1999-01-01

    A method of converting a steam cooled transition to an air cooled transition in a gas turbine having a compressor in fluid communication with a combustor, a turbine section in fluid communication with the combustor, the transition disposed in a combustor shell and having a cooling circuit connecting a steam outlet and a steam inlet and wherein hot gas flows from the combustor through the transition and to the turbine section, includes forming an air outlet in the transition in fluid communication with the cooling circuit and providing for an air inlet in the transition in fluid communication with the cooling circuit.

  16. Gas turbine combustor transition

    DOEpatents

    Coslow, B.J.; Whidden, G.L.

    1999-05-25

    A method is described for converting a steam cooled transition to an air cooled transition in a gas turbine having a compressor in fluid communication with a combustor, a turbine section in fluid communication with the combustor, the transition disposed in a combustor shell and having a cooling circuit connecting a steam outlet and a steam inlet and wherein hot gas flows from the combustor through the transition and to the turbine section, includes forming an air outlet in the transition in fluid communication with the cooling circuit and providing for an air inlet in the transition in fluid communication with the cooling circuit. 7 figs.

  17. Conceptualizing Transitions to Adulthood

    ERIC Educational Resources Information Center

    Wyn, Johanna

    2014-01-01

    This chapter provides an overview of theories of the transition to young adulthood. It sets out the argument for conceptual renewal and discusses some implications of new patterns of transition for adult education.

  18. Transition to Adulthood

    MedlinePlus

    ... fix that! Keep reading… Back to top IDEA’s Definition of Transition Services Any discussion of transition services ... from special education. Back to top Considering the Definition A number of key words in the definition ...

  19. Transition in Turbines

    NASA Technical Reports Server (NTRS)

    1985-01-01

    The concept of a large disturbance bypass mechanism for the initiation of transition is reviewed and studied. This mechanism, or some manifestation thereof, is suspected to be at work in the boundary layers present in a turbine flow passage. Discussion is presented on four relevant subtopics: (1) the effect of upstream disturbances and wakes on transition; (2) transition prediction models, code development, and verification; (3) transition and turbulence measurement techniques; and (4) the hydrodynamic condition of low Reynolds number boundary layers.

  20. Cosmological phase transitions

    SciTech Connect

    Kolb, E.W. |

    1993-10-01

    If modern ideas about the role of spontaneous symmetry breaking in fundamental physics are correct, then the Universe should have undergone a series of phase transitions early in its history. The study of cosmological phase transitions has become an important aspect of early-Universe cosmology. In this lecture I review some very recent work on three aspects of phase transitions: the electroweak transition, texture, and axions.

  1. Transition: Preschool to Kindergarten

    ERIC Educational Resources Information Center

    Arizona Department of Education, 2007

    2007-01-01

    Transition is movement or change without interruption. It should be a smooth flow from one place or condition to another. While the transition plan for a student receiving special education services is designed to prepare him or her for life after high school, transition can start when a child enters preschool. The second of six distinct stages of…

  2. Transition. Feature Issue.

    ERIC Educational Resources Information Center

    Wallace, Teri, Ed.; And Others

    1992-01-01

    This feature issue of a quarterly bulletin on community integration addresses the topic of transition services for preparing youth with disabilities for adult community living. It contains articles with the following titles and authors: "Transition: The Next Five Years" (David R. Johnson and others); "Transition Policy in the 1990s:…

  3. Transit pricing and performance

    SciTech Connect

    Pickerell, D.H.; Abkowitz, M.; Tozzi, J.; McCord, M.R.; Cheng, L.H.

    1986-01-01

    The 9 papers in the report deal with the following areas: Federal operating assistance for urban mass transit; a decade of experience; transit route characteristics and headway-based reliability control; day-of-week and part-of-month variation in bus ridership; job satisfaction and transit operator recognition programs; results of a survey of muni operators; bus marketing costs: the experience of 18 section 15 reporters from 1981 to 1983; prospects for differential transit pricing in the United States; an initial analysis of total factor productivity for public-transit coordination of transportation resources: the Georgia experience; absenteeism, accidents, and attrition: part-time versus full-time bus drivers.

  4. Gravitationally induced quantum transitions

    NASA Astrophysics Data System (ADS)

    Landry, A.; Paranjape, M. B.

    2016-06-01

    In this paper, we calculate the probability for resonantly inducing transitions in quantum states due to time-dependent gravitational perturbations. Contrary to common wisdom, the probability of inducing transitions is not infinitesimally small. We consider a system of ultracold neutrons, which are organized according to the energy levels of the Schrödinger equation in the presence of the Earth's gravitational field. Transitions between energy levels are induced by an oscillating driving force of frequency ω . The driving force is created by oscillating a macroscopic mass in the neighborhood of the system of neutrons. The neutron lifetime is approximately 880 sec while the probability of transitions increases as t2. Hence, the optimal strategy is to drive the system for two lifetimes. The transition amplitude then is of the order of 1.06 ×10-5, and hence with a million ultracold neutrons, one should be able to observe transitions.

  5. Transition Region Models

    NASA Astrophysics Data System (ADS)

    Hansteen, V.; Murdin, P.

    2000-11-01

    The SOLAR TRANSITION REGION comprises the PLASMA between the CHROMOSPHERE and the CORONA. In both of these regions the temperature is fairly uniform. The transition region, by contrast, is believed to be characterized by a very steep temperature rise from a chromospheric temperature of slightly less than 104 K to coronal temperatures on the order of 106 K. The goal of modeling the transition regi...

  6. [From epidemiological transition to health transition].

    PubMed

    Meslé, F; Vallin, J

    2007-12-01

    The "Epidemiological Transition" concept proposed by Abdel Omran in 1971 was the first theory attempting to explain the extraordinary progess that industrialized countries have achieved in health since the 18th century. Within the broader framework of the demographic transition, an important implication of this concept was that life expectancy in modern societies would converge toward limits determined by the new epidemiological conditions. In the ensuing decades, however the convergence process appears to have stopped as a result of a number of setbacks including the health crisis in Eastern Europe and AIDS in Africa. These setbacks do not fundamentally contradict the theory. A much greater contradiction was the unexpected dramatic decrease in cardiovascular disease that began as early as the 70s and had a major positive impact on life expectancy. Based on the concept of "Health Transition" described by Julio Frenk et al., we propose a complete revision of the health implications of the demographic transition based the idea of successive cycles of divergences/convergences induced by the appearance and generalization of major breakthroughs in health technologies and strategies. Three such cycles can be clearly identified on an international level corresponding to control of infectious then cardiovascular diseases, and perhaps most recently to the initial successes achieved in the field of ageing.

  7. Transitional Division Algorithms.

    ERIC Educational Resources Information Center

    Laing, Robert A.; Meyer, Ruth Ann

    1982-01-01

    A survey of general mathematics students whose teachers were taking an inservice workshop revealed that they had not yet mastered division. More direct introduction of the standard division algorithm is favored in elementary grades, with instruction of transitional processes curtailed. Weaknesses in transitional algorithms appear to outweigh…

  8. Expanding Views on Transition.

    ERIC Educational Resources Information Center

    Repetto, Jeanne B.; Correa, Vivian I.

    1996-01-01

    This position paper proposes an expanded definition of transition, based on common components of early childhood and secondary perspectives. It advocates for a seamless model of transition service delivery for students with disabilities, including program planning, from birth through age 21. The model addresses curriculum, location of services,…

  9. Transition to Living.

    ERIC Educational Resources Information Center

    Repetto, Jeanne B.

    2003-01-01

    Discussion of transition for students with disabilities emphasizes transition skills needed for life beyond work. The importance of assisting students in planning for their life roles as workers, family members, friends, consumers, and community members is discussed. Suggestions are offered to better prepare students for all their life roles by…

  10. Modeling the transition region

    NASA Astrophysics Data System (ADS)

    Singer, Bart A.

    1994-04-01

    The calculation of engineering flows undergoing laminar-turbulent transition presents special problems. Mean-flow quantities obey neither the fully laminar nor the fully turbulent correlations. In addition, local maxima in skin friction, wall temperature, and heat transfer often occur near the end of the transition region. Traditionally, modeling this region has been important for the design of turbine blades, where the transition region is long in relation to the chord length of the blade. More recently, the need for better transition-region models has been recognized by designers of hypersonic vehicles where the high Mach number, the low Reynolds number, and the low-disturbance flight environment emphasize the importance of the transition region. Needless to say, a model that might work well for the transitional flows typically found in gas turbines will not necessarily work well for the external surface of a hypersonic vehicle. In Section 2 of this report, some of the important flow features that control the transition region will be discussed. In Section 3, different approaches to the modeling problem will be summarized and cataloged. Fully turbulent flow models will be discussed in detail in Section 4; models specifically designed for transitional flow, in Section 5; and the evaluation of models, in Section 6.

  11. Seamless Transition for All

    ERIC Educational Resources Information Center

    Test, David W.

    2008-01-01

    Postschool outcomes for students with disabilities have been dismal for quite some time now. Although recent data from the National Longitudinal Transition Study 2 indicate some improvement, students with severe intellectual disabilities continue to transition into segregated employment at unacceptable rates in spite of a multitude of studies,…

  12. Transitioning between Clerkship Directors

    ERIC Educational Resources Information Center

    Soltys, Stephen M.; Pary, Robert J.; Robinson, Stephen W.; Markwell, Stephen J.

    2011-01-01

    Objective: The authors report on succession-planning for mid-level academic positions. Method: The authors describe the process of succession-planning between clerkship directors and the smooth transition resulting in one case. Results: Gradually transitioning allowed a new faculty person to assume the clerkship-director position with minimal…

  13. Transitions in Spousal Caregiving.

    ERIC Educational Resources Information Center

    Burton, Lynda C.; Zdaniuk, Bozena; Schulz, Richard; Jackson, Sharon; Hirsch, Calvin

    2003-01-01

    Describes transitions over 5 years among community-dwelling elderly spouses into and within caregiving roles and associated health outcomes. The trajectory of health outcomes associated with caregiving was generally downward. Those who transitioned to heavy caregiving had more symptoms of depression, and poorer self-reported health and health…

  14. Transitivity of Preferences

    ERIC Educational Resources Information Center

    Regenwetter, Michel; Dana, Jason; Davis-Stober, Clintin P.

    2011-01-01

    Transitivity of preferences is a fundamental principle shared by most major contemporary rational, prescriptive, and descriptive models of decision making. To have transitive preferences, a person, group, or society that prefers choice option "x" to "y" and "y" to "z" must prefer "x" to…

  15. Good Transitions = Great Starts!

    ERIC Educational Resources Information Center

    Our Children: The National PTA Magazine, 2012

    2012-01-01

    The smooth transition of outgoing and incoming board members and officers is of vital importance and can determine the PTA's success for years to come. The transition process is the responsibility of both incoming and outgoing officers and board members. It gives closure to those leaving their positions and allows those coming in to be properly…

  16. Transition Coordinators: Define Yourselves.

    ERIC Educational Resources Information Center

    Asselin, Susan B.; Todd-Allen, Mary; deFur, Sharon

    1998-01-01

    Describes a technique that was used successfully to identify the changing roles and responsibilities of special educators as transition coordinators. The Developing a Curriculum (DACUM) model uses people who are currently working in the occupation to define job responsibilities. The duties of a transition coordinator are identified. (CR)

  17. Matter in transition

    SciTech Connect

    Anderson, Lara B.; Gray, James; Raghuram, Nikhil; Taylor, Washington

    2016-04-13

    In this study, we explore a novel type of transition in certain 6D and 4D quantum field theories, in which the matter content of the theory changes while the gauge group and other parts of the spectrum remain invariant. Such transitions can occur, for example, for SU(6) and SU(7) gauge groups, where matter fields in a three-index antisymmetric representation and the fundamental representation are exchanged in the transition for matter in the two-index antisymmetric representation. These matter transitions are realized by passing through superconformal theories at the transition point. We explore these transitions in dual F-theory and heterotic descriptions, where a number of novel features arise. For example, in the heterotic description the relevant 6D SU(7) theories are described by bundles on K3 surfaces where the geometry of the K3 is constrained in addition to the bundle structure. On the F-theory side, non-standard representations such as the three-index antisymmetric representation of SU(N) require Weierstrass models that cannot be realized from the standard SU(N) Tate form. We also briefly describe some other situations, with groups such as Sp(3), SO(12), and SU(3), where analogous matter transitions can occur between different representations. For SU(3), in particular, we find a matter transition between adjoint matter and matter in the symmetric representation, giving an explicit Weierstrass model for the F-theory description of the symmetric representation that complements another recent analogous construction.

  18. Transition Implementation Guide. Instructor Materials.

    ERIC Educational Resources Information Center

    Boyer-Stephens, Arden, Ed.

    This transition model, called Guiding Education toward Adult Roles for Success (GEARS), provides a comprehensive framework from which transition services and programs can evolve. Three components of transition services are considered: transition partners, the transition process, and adult outcomes. After an introduction, the report's second…

  19. Extrasolar Planetary Transits

    NASA Astrophysics Data System (ADS)

    Cameron, Andrew Collier

    An extrasolar planet will transit the visible hemisphere of its host star if its orbital plane lies sufficiently close to the observer's line of sight. The resulting periodic dips in stellar flux reveal key system parameters, including the density of the host star and, if radial-velocity observations are available, the surface gravitational acceleration of the planet. In this chapter I present the essential methodology for modelling the time-dependent flux variation during a transit, and its use in determining the posterior probability distribution for the physical parameters of the system. Large-scale searches for transiting systems are an efficient way of discovering planets whose bulk densities, and hence compositions, can be accessed if their masses can also be determined. I present algorithms for detrending large ensembles of light curves, for searching for transit-like signals among them. I also discuss methods for identifying diluted stellar eclipsing binaries mimicking planetary transit signals, and validation of transit candidates too faint for radial-velocity follow-up. I review the use of time-resolved spectrophotometry and high-resolution spectroscopy during transits to identify the molecular constituents of exoplanetary atmospheres.

  20. Predictability of critical transitions

    NASA Astrophysics Data System (ADS)

    Zhang, Xiaozhu; Kuehn, Christian; Hallerberg, Sarah

    2015-11-01

    Critical transitions in multistable systems have been discussed as models for a variety of phenomena ranging from the extinctions of species to socioeconomic changes and climate transitions between ice ages and warm ages. From bifurcation theory we can expect certain critical transitions to be preceded by a decreased recovery from external perturbations. The consequences of this critical slowing down have been observed as an increase in variance and autocorrelation prior to the transition. However, especially in the presence of noise, it is not clear whether these changes in observation variables are statistically relevant such that they could be used as indicators for critical transitions. In this contribution we investigate the predictability of critical transitions in conceptual models. We study the quadratic integrate-and-fire model and the van der Pol model under the influence of external noise. We focus especially on the statistical analysis of the success of predictions and the overall predictability of the system. The performance of different indicator variables turns out to be dependent on the specific model under study and the conditions of accessing it. Furthermore, we study the influence of the magnitude of transitions on the predictive performance.

  1. Variational Transition State Theory

    SciTech Connect

    Truhlar, Donald G.

    2016-09-29

    This is the final report on a project involving the development and applications of variational transition state theory. This project involved the development of variational transition state theory for gas-phase reactions, including optimized multidimensional tunneling contributions and the application of this theory to gas-phase reactions with a special emphasis on developing reaction rate theory in directions that are important for applications to combustion. The development of variational transition state theory with optimized multidimensional tunneling as a useful computational tool for combustion kinetics involved eight objectives.

  2. Transition nozzle combustion system

    DOEpatents

    Kim, Won-Wook; McMahan, Kevin Weston; Maldonado, Jaime Javier

    2016-11-29

    The present application provides a combustion system for use with a cooling flow. The combustion system may include a head end, an aft end, a transition nozzle extending from the head end to the aft end, and an impingement sleeve surrounding the transition nozzle. The impingement sleeve may define a first cavity in communication with the head end for a first portion of the cooling flow and a second cavity in communication with the aft end for a second portion of the cooling flow. The transition nozzle may include a number of cooling holes thereon in communication with the second portion of the cooling flow.

  3. Holographic magnetic phase transition

    SciTech Connect

    Lifschytz, Gilad; Lippert, Matthew

    2009-09-15

    We study four-dimensional interacting fermions in a strong magnetic field, using the holographic Sakai-Sugimoto model of intersecting D4- and D8-branes in the deconfined, chiral-symmetric parallel phase. We find that as the magnetic field is varied, while staying in the parallel phase, the fermions exhibit a first-order phase transition in which their magnetization jumps discontinuously. Properties of this transition are consistent with a picture in which some of the fermions jump to the lowest Landau level. Similarities to known magnetic phase transitions are discussed.

  4. Superconductivity in transition metals.

    PubMed

    Slocombe, Daniel R; Kuznetsov, Vladimir L; Grochala, Wojciech; Williams, Robert J P; Edwards, Peter P

    2015-03-13

    A qualitative account of the occurrence and magnitude of superconductivity in the transition metals is presented, with a primary emphasis on elements of the first row. Correlations of the important parameters of the Bardeen-Cooper-Schrieffer theory of superconductivity are highlighted with respect to the number of d-shell electrons per atom of the transition elements. The relation between the systematics of superconductivity in the transition metals and the periodic table high-lights the importance of short-range or chemical bonding on the remarkable natural phenomenon of superconductivity in the chemical elements. A relationship between superconductivity and lattice instability appears naturally as a balance and competition between localized covalent bonding and so-called broken covalency, which favours d-electron delocalization and superconductivity. In this manner, the systematics of superconductivity and various other physical properties of the transition elements are related and unified.

  5. Coping with Transitions.

    ERIC Educational Resources Information Center

    Bendersky, Nora; And Others

    1984-01-01

    Describes a workshop for nine South American students at the Hebrew University of Jerusalem. The two-day session focussed on exploring coping behaviors that could help students adjust to transitions. (JAC)

  6. Transit Timing Variations

    NASA Video Gallery

    The animation shows the difference between planet transit timing of single and multiple planet system. In tightly packed planetary systems, the gravitational pull of the planets among themselves ca...

  7. Oligocyclopentadienyl transition metal complexes

    SciTech Connect

    de Azevedo, Cristina G.; Vollhardt, K. Peter C.

    2002-01-18

    Synthesis, characterization, and reactivity studies of oligocyclopentadienyl transition metal complexes, namely those of fulvalene, tercyclopentadienyl, quatercyclopentadienyl, and pentacyclopentadienyl(cyclopentadienyl) are the subject of this account. Thermal-, photo-, and redox chemistries of homo- and heteropolynuclear complexes are described.

  8. Alternative fuel transit buses

    SciTech Connect

    Motta, R.; Norton, P.; Kelly, K.

    1996-10-01

    The National Renewable Energy Laboratory (NREL) is a U.S. Department of Energy (DOE) national laboratory; this project was funded by DOE. One of NREL`s missions is to objectively evaluate the performance, emissions, and operating costs of alternative fuel vehicles so fleet managers can make informed decisions when purchasing them. Alternative fuels have made greater inroads into the transit bus market than into any other. Each year, the American Public Transit Association (APTA) surveys its members on their inventory and buying plans. The latest APTA data show that about 4% of the 50,000 transit buses in its survey run on an alternative fuel. Furthermore, 1 in 5 of the new transit buses that members have on order are alternative fuel buses. This program was designed to comprehensively and objectively evaluate the alternative fuels in use in the industry.

  9. Palaeontology: turtles in transition.

    PubMed

    Lee, Michael S Y

    2013-06-17

    One of the major remaining gaps in the vertebrate fossil record concerns the origin of turtles. The enigmatic little reptile Eunotosaurus could represent an important transitional form, as it has a rudimentary shell that resembles the turtle carapace.

  10. Urban guideway transit workshop: Proceedings

    SciTech Connect

    Larsen, H. )

    1992-03-01

    On March 20--21, 1991, EPRI sponsored a workshop on urban guideway transit. The purpose of this workshop was to provide utility managers with increased knowledge about urban guideway transit options, public policy regarding transit, and the effect of transit options on utility operations. With this information utilities should be better prepared to make decisions about transit development in their service areas. The workshop also provided EPRI with ideas and information for developing an R D project plan for urban guideway transit.

  11. Bridging the Transition Gap

    DTIC Science & Technology

    2013-05-23

    state and prevent instability agents from establishing 3Nicholas J. Armstrong and Jacqueline Chura-Beaver, Harnessing Post-Conflict Transition: A...reassessing the transition period with a wider range of stakeholder begins with a communal understanding of 118George K. Tanham, War without Guns ...Future.” Military Review (March/April 2006): 11. Armstrong, Nicholas J., and Jacqueline Chura-Beaver. Harnessing Post-Conflict. Carlisle, PA

  12. Quantum Phase Transitions

    DTIC Science & Technology

    2011-05-01

    Park, NC 27709-2211 15. SUBJECT TERMS Quantum Thoery Phase transitions Subir Sachdev Harvard University Office of Sponsored Research 1350...magnetism, and solvable models obtained from string theory. After introducing the basic theory, it moves on to a detailed description of the canonical...students and researchers in condensed matter physics and particle and string theory. Print | Close Quantum Phase Transitions 2nd Edition Subir Sachdev

  13. Matter in transition

    DOE PAGES

    Anderson, Lara B.; Gray, James; Raghuram, Nikhil; ...

    2016-04-13

    In this study, we explore a novel type of transition in certain 6D and 4D quantum field theories, in which the matter content of the theory changes while the gauge group and other parts of the spectrum remain invariant. Such transitions can occur, for example, for SU(6) and SU(7) gauge groups, where matter fields in a three-index antisymmetric representation and the fundamental representation are exchanged in the transition for matter in the two-index antisymmetric representation. These matter transitions are realized by passing through superconformal theories at the transition point. We explore these transitions in dual F-theory and heterotic descriptions, wheremore » a number of novel features arise. For example, in the heterotic description the relevant 6D SU(7) theories are described by bundles on K3 surfaces where the geometry of the K3 is constrained in addition to the bundle structure. On the F-theory side, non-standard representations such as the three-index antisymmetric representation of SU(N) require Weierstrass models that cannot be realized from the standard SU(N) Tate form. We also briefly describe some other situations, with groups such as Sp(3), SO(12), and SU(3), where analogous matter transitions can occur between different representations. For SU(3), in particular, we find a matter transition between adjoint matter and matter in the symmetric representation, giving an explicit Weierstrass model for the F-theory description of the symmetric representation that complements another recent analogous construction.« less

  14. Controlled Thin-Film Growth Of Silicon Carbide Polytypes

    NASA Technical Reports Server (NTRS)

    Powell, J. Anthony; Larkin, David J.

    1995-01-01

    Improved deposition process to grows thin layers of silicon carbide having chosen crystalline structures. Process incorporated into sequences of deposition and etching steps used to fabricate silicon-carbide-based semiconductor devices. Important advance because silicon carbide emerging as superior semiconductor for devices operating under conditions of high power, high temperature, and/or high frequency. Furthermore, various crystalline structures of SiC have different electronic properties, each suited to specific application.

  15. Growth mechanisms, polytypism, and real structure of kaolinite microcrystals

    SciTech Connect

    Samotoin, N. D.

    2008-09-15

    The mechanisms of growth of kaolinite microcrystals (0.1-5.0 {mu}m in size) at deposits related to the cluvial weathering crust, as well as to the low-temperature and medium-temperature hydrothermal processes of transformations of minerals in different rocks in Russia, Kazakhstan, Ukraine, Czechia, Vietnam, India, Cuba, and Madagascar, are investigated using transmission electron microscopy and vacuum decoration with gold. It is established that kaolinite microcrystals grow according to two mechanisms: the mechanism of periodic formation of two-dimensional nuclei and the mechanism of spiral growth. The spiral growth of kaolinite microcrystals is dominant and occurs on steps of screw dislocations that differ in sign and magnitude of the Burgers vector along the c axis. The layered growth of kaolinite originates from a widespread source in the form of a step between polar (+ and -) dislocations, i.e., a growth analogue of the Frank-Read dislocation source. The density of growth screw dislocations varies over a wide range and can be as high as {approx}10{sup 9} cm{sup -2}. Layered stepped kaolinite growth pyramids for all mechanisms of growth on the (001) face of kaolinite exhibit the main features of the triclinic 1Tc and real structures of this mineral.

  16. Venus Transit 2004

    NASA Astrophysics Data System (ADS)

    Mayo, L. A.; Odenwald, S. F.

    2002-09-01

    December 6th, 1882 was the last transit of the planet Venus across the disk of the sun. It was heralded as an event of immense interest and importance to the astronomical community as well as the public at large. There have been only six such occurrences since Galileo first trained his telescope on the heavens in 1609 and on Venus in 1610 where he concluded that Venus had phases like the moon and appeared to get larger and smaller over time. Many historians consider this the final nail in the coffin of the Ptolemaic, Earth centered solar system. In addition, each transit has provided unique opportunities for discovery such as measurement and refinement of the astronomical unit, calculation of longitudes on the earth, and detection of Venus' atmosphere. The NASA Sun Earth Connection Education Forum in partnership with the Solar System Exploration Forum, DPS, and a number of NASA space missions is developing plans for an international education program centered around the June 8, 2004 Venus transit. The transit will be visible in its entirety from Europe and partially from the East Coast of the United States. We will use a series of robotic observatories including the Telescopes In Education network distributed in latitude to provide observations of the transit that will allow middle and high school students to calculate the A.U. through application of parallax. We will also use Venus transit as a probe of episodes in American history (e.g. 1769: revolutionary era, 1882: post civil war era, and 2004: modern era). Museums and planetariums in the US and Europe will offer real time viewing of the transit and conduct educational programs through professional development seminars, public lectures, and planetarium shows. We are interested in soliciting advice from the research community to coordinate professional research interests with this program.

  17. Noise and Phase Transitions

    NASA Astrophysics Data System (ADS)

    Chen, Zhi; Yu, Clare C.

    2006-03-01

    Noise is present in many physical systems and is often viewed as a nuisance. Yet it can also be a probe of microscopic fluctuations. There have been indications recently that the noise in the resistivity increases in the vicinity of the metal-insulator transition. But what are the characteristics of the noise associated with well-understood first and second order phase transitions? It is well known that critical fluctuations are associated with second order phase transitions, but do these fluctuations lead to enhanced noise? We have addressed these questions using Monte Carlo simulations to study the noise in the 2D Ising model which undergoes a second order phase transition, and in the 5-state Potts model which undergoes a first order phase transition. We monitor these systems as the temperature drops below the critical temperature. At each temperature, after equilibration is established, we obtain the time series of quantities characterizing the properties of the system, i.e., the energy and magnetization per site. We apply different methods, such as the noise power spectrum, the Detrended Fluctuation Analysis (DFA) and the second spectrum of the noise, to analyze the fluctuations in these quantities.

  18. Examining hydrogen transitions.

    SciTech Connect

    Plotkin, S. E.; Energy Systems

    2007-03-01

    This report describes the results of an effort to identify key analytic issues associated with modeling a transition to hydrogen as a fuel for light duty vehicles, and using insights gained from this effort to suggest ways to improve ongoing modeling efforts. The study reported on here examined multiple hydrogen scenarios reported in the literature, identified modeling issues associated with those scenario analyses, and examined three DOE-sponsored hydrogen transition models in the context of those modeling issues. The three hydrogen transition models are HyTrans (contractor: Oak Ridge National Laboratory), MARKAL/DOE* (Brookhaven National Laboratory), and NEMS-H2 (OnLocation, Inc). The goals of these models are (1) to help DOE improve its R&D effort by identifying key technology and other roadblocks to a transition and testing its technical program goals to determine whether they are likely to lead to the market success of hydrogen technologies, (2) to evaluate alternative policies to promote a transition, and (3) to estimate the costs and benefits of alternative pathways to hydrogen development.

  19. RTGs on Transit

    NASA Astrophysics Data System (ADS)

    Dassoulas, John; McNutt, Ralph L.

    2007-01-01

    Transit, the US Navy's Navigation Satellite System was conceived at the Applied Physics Laboratory in 1957 by observing the Doppler shift while tracking Sputnik I. As spacecraft development proceeded there was concern about the ability of batteries to maintain the hermetic seal over a 5-year operational life requirement; therefore, alternate energy sources were investigated. The radioisotope thermoelectric generator (RTG) concept was pursued and resulted in the launch of SNAP 3s, providing partial power on both Transit 4A and 4B. SNAP 9s provided full power on three Transit 5BNs. All launches occurred in the early 1960s. When the U.S. conducted the high altitude nuclear test from Johnson Island, several spacecraft were lost due to artificial enhancement of charged particles in the Earth's magnetosphere resulting in rapid degradation of solar cell power production. This led to the decision to have both an RTG and Solar cell/battery design for Transit power systems; hence, a new RTG design, with a separable heat source and radiative coupling to the thermoelectric elements, was flown on TRIAD. This pioneering effort provided the impetus for future RTGs on interplanetary spacecraft. This paper describes the origin and purpose of the Transit program and provides details on the five satellites in that program that were powered by the first American RTGs used in space. The rationale and some of the challenges inherent in that use are also described.

  20. The Concept of Transition System

    ERIC Educational Resources Information Center

    Raffe, David

    2008-01-01

    The term "transition system" describes features of a country's institutional arrangements which shape young people's education-work transitions. It explains why national differences in transition processes and outcomes persist despite apparent pressures for convergence. This paper asks how the concept of transition system has been…

  1. Quantum interface unbinding transitions

    NASA Astrophysics Data System (ADS)

    Jakubczyk, P.

    2012-08-01

    We consider interfacial phenomena accompanying bulk quantum phase transitions in the presence of surface fields. On general grounds we argue that the surface contribution to the system free energy involves a line of singularities characteristic of an interfacial phase transition, occurring below the bulk transition temperature Tc down to T=0. This implies the occurrence of an interfacial quantum critical regime extending into finite temperatures and located within the portion of the phase diagram where the bulk is ordered. Even in situations where the bulk order sets in discontinuously at T=0, the system's behavior at the boundary may be controlled by a divergent length scale if the tricritical temperature is sufficiently low. Relying on an effective interfacial model we compute the surface phase diagram in bulk spatial dimensionality d⩾2 and extract the values of the exponents describing the interfacial singularities in d⩾3.

  2. Electroweak phase transitions

    SciTech Connect

    Anderson, G.W.

    1991-09-16

    An analytic treatment of the one Higgs doublet, electroweak phase transition is given. The phase transition is first order, occurs by the nucleation of thin walled bubbles and completes at a temperature where the order parameter, {l_angle}{phi}{r_angle}{sub T} is significantly smaller than it is when the origin becomes absolutely unstable. The rate of anomalous baryon number violation is an exponentially function of {l_angle}{phi}{r_angle}{sub T}. In very minimal extensions of the standard model it is quite easy to increase {l_angle}{phi}{r_angle}{sub T} so that anomalous baryon number violation is suppressed after completion of the phase transition. Hence baryogenesis at the electroweak phase transition is tenable in minimal of the standard model. In some cases additional phase transitions are possible. For a light Higgs boson, when the top quark mass is sufficiently large, the state where the Higgs field has a vacuum expectation value {l_angle}{phi}{r_angle} = 246 GeV is not the true minimum of the Higgs potential. When this is the case, and when the top quark mass exceeds some critical value, thermal fluctuations in the early universe would have rendered the state {l_angle}{phi}{r_angle} = 246 GeV unstable. The requirement that the state {l_angle}{phi}{r_angle} = 246 GeV is sufficiently long lived constrains the masses of the Higgs boson and the top quark. Finally, we consider whether local phase transitions can be induced by heavy particles which act as seeds for deformations in the scalar field.

  3. Electroweak phase transitions

    SciTech Connect

    Anderson, G.W.

    1991-09-16

    An analytic treatment of the one Higgs doublet, electroweak phase transition is given. The phase transition is first order, occurs by the nucleation of thin walled bubbles and completes at a temperature where the order parameter, {l angle}{phi}{r angle}{sub T} is significantly smaller than it is when the origin becomes absolutely unstable. The rate of anomalous baryon number violation is an exponentially function of {l angle}{phi}{r angle}{sub T}. In very minimal extensions of the standard model it is quite easy to increase {l angle}{phi}{r angle}{sub T} so that anomalous baryon number violation is suppressed after completion of the phase transition. Hence baryogenesis at the electroweak phase transition is tenable in minimal of the standard model. In some cases additional phase transitions are possible. For a light Higgs boson, when the top quark mass is sufficiently large, the state where the Higgs field has a vacuum expectation value {l angle}{phi}{r angle} = 246 GeV is not the true minimum of the Higgs potential. When this is the case, and when the top quark mass exceeds some critical value, thermal fluctuations in the early universe would have rendered the state {l angle}{phi}{r angle} = 246 GeV unstable. The requirement that the state {l angle}{phi}{r angle} = 246 GeV is sufficiently long lived constrains the masses of the Higgs boson and the top quark. Finally, we consider whether local phase transitions can be induced by heavy particles which act as seeds for deformations in the scalar field.

  4. UTM: Universal Transit Modeller

    NASA Astrophysics Data System (ADS)

    Deeg, Hans J.

    2014-12-01

    The Universal Transit Modeller (UTM) is a light-curve simulator for all kinds of transiting or eclipsing configurations between arbitrary numbers of several types of objects, which may be stars, planets, planetary moons, and planetary rings. A separate fitting program, UFIT (Universal Fitter) is part of the UTM distribution and may be used to derive best fits to light-curves for any set of continuously variable parameters. UTM/UFIT is written in IDL code and its source is released in the public domain under the GNU General Public License.

  5. Variational transition state theory

    SciTech Connect

    Truhlar, D.G.

    1993-12-01

    This research program involves the development of variational transition state theory (VTST) and semiclassical tunneling methods for the calculation of gas-phase reaction rates and selected applications. The applications are selected for their fundamental interest and/or their relevance to combustion.

  6. Youth Policy in Transition.

    ERIC Educational Resources Information Center

    Timpane, Michael; And Others

    A study team was commissioned to critically review three independent reports on youth and schooling: "Youth: Transition to Adulthood"; "The Education of Adolescents"; and "The Reform of Secondary Education." The study team examined the reports in light of the most recent available social science evidence. The three reports, presenting similar…

  7. Singing Smoothes Classroom Transitions

    ERIC Educational Resources Information Center

    Mathews, Sarah E.

    2012-01-01

    Just as humming a merry tune helped Snow White and her furry animal friends to quickly clean a filthy cottage in the movie "Snow White and the Seven Dwarfs" (Disney & Cottrell, 1937), singing can be an effective way to help keep young children fully engaged during classroom transitions. The purposes of this article are to: (1) consider why…

  8. A Transiting Jupiter Analog

    NASA Astrophysics Data System (ADS)

    Kipping, D. M.; Torres, G.; Henze, C.; Teachey, A.; Isaacson, H.; Petigura, E.; Marcy, G. W.; Buchhave, L. A.; Chen, J.; Bryson, S. T.; Sandford, E.

    2016-04-01

    Decadal-long radial velocity surveys have recently started to discover analogs to the most influential planet of our solar system, Jupiter. Detecting and characterizing these worlds is expected to shape our understanding of our uniqueness in the cosmos. Despite the great successes of recent transit surveys, Jupiter analogs represent a terra incognita, owing to the strong intrinsic bias of this method against long orbital periods. We here report on the first validated transiting Jupiter analog, Kepler-167e (KOI-490.02), discovered using Kepler archival photometry orbiting the K4-dwarf KIC-3239945. With a radius of (0.91+/- 0.02) {R}{{J}}, a low orbital eccentricity ({0.06}-0.04+0.10), and an equilibrium temperature of (131+/- 3) K, Kepler-167e bears many of the basic hallmarks of Jupiter. Kepler-167e is accompanied by three Super-Earths on compact orbits, which we also validate, leaving a large cavity of transiting worlds around the habitable-zone. With two transits and continuous photometric coverage, we are able to uniquely and precisely measure the orbital period of this post snow-line planet (1071.2323 ± 0.0006d), paving the way for follow-up of this K = 11.8 mag target.

  9. String mediated phase transitions

    NASA Technical Reports Server (NTRS)

    Copeland, ED; Haws, D.; Rivers, R.; Holbraad, S.

    1988-01-01

    It is demonstrated from first principles how the existence of string-like structures can cause a system to undergo a phase transition. In particular, the role of topologically stable cosmic string in the restoration of spontaneously broken symmetries is emphasized. How the thermodynamic properties of strings alter when stiffness and nearest neighbor string-string interactions are included is discussed.

  10. exorings: Exoring Transit Properties

    NASA Astrophysics Data System (ADS)

    Zuluaga, Jorge I.; Kipping, David M.; Sucerquia, Mario; Alvarado, Jaime A.

    2017-03-01

    Exorings is suitable for surveying entire catalogs of transiting planet candidates for exoring candidates, providing a subset of objects worthy of more detailed light curve analysis. Moreover, it is highly suited for uncovering evidence of a population of ringed planets by comparing the radius anomaly and PR-effects in ensemble studies.

  11. A Survey Transition Course

    ERIC Educational Resources Information Center

    Johnston, William; McAllister, Alex M.

    2012-01-01

    Successful outcomes for a "Transition Course in Mathematics" have resulted from two unique design features. The first is to run the course as a "survey course" in mathematics, introducing sophomore-level students to a broad set of mathematical fields. In this single mathematics course, undergraduates benefit from an introduction of proof…

  12. Tips for Transition

    ERIC Educational Resources Information Center

    Kellems, Ryan O.; Morningstar, Mary E.

    2010-01-01

    The Individuals With Disabilities Education Improvement Act of 2004 (IDEA) states that transition planning should begin at the earliest age appropriate and no later than age 16. IDEA requires schools to make collaborative efforts to provide students access to an array of postschool activities including integrated employment, postsecondary…

  13. Families in Transition.

    ERIC Educational Resources Information Center

    Britton, Patti O., Ed.; McGee, Michael, Ed.

    1987-01-01

    This issue of "Emphasis" deals with families in transition, providing some model programs for the new family and some historical perspectives on how families have developed over time. Articles include: (1) "Nostalgia on the Right" (Nancy Theriot); (2) "Heart to Heart" (Nancy Harrington-MacLennan); (3) "The Media Get the Message" (Janet Alyn); (4)…

  14. The TRANSITION Program.

    ERIC Educational Resources Information Center

    Office of the Assistant Secretary of Defense for Manpower and Reserve Affairs (DOD), Washington, DC.

    Operated on a voluntary, decentralized basis at 215 military bases (58 overseas), the TRANSITION Program is designed to provide maximum guidance and training or educational opportunities for servicemen during their last six months of duty to prepare them for productive reentry into civilian life. Public and private placement services are also…

  15. Selected Readings in Transition.

    ERIC Educational Resources Information Center

    Harnisch, Delwyn L.; And Others

    This collection of readings covers critical issues related to transition of youth with disabilities from school to post-school experiences. The first paper, titled "'Cognitive Return' of Schooling for Students with Disabilities: Preliminary Findings from 'High School and Beyond'" by Delwyn L. Harnisch and Ian A. G. Wilkinson, applies…

  16. Learning for Life Transitions

    ERIC Educational Resources Information Center

    Varmecky, Jane Hyde

    2012-01-01

    Many adults return to formal learning situations to pursue lifelong learning goals because their lives are in transition from dealing with real-life problems such as divorce and re-marriage. The purpose of this study was to describe what couples learned that contributed to the success of their subsequent marriages and how they learned it. The…

  17. Modeling of transitional flows

    NASA Technical Reports Server (NTRS)

    Lund, Thomas S.

    1988-01-01

    An effort directed at developing improved transitional models was initiated. The focus of this work was concentrated on the critical assessment of a popular existing transitional model developed by McDonald and Fish in 1972. The objective of this effort was to identify the shortcomings of the McDonald-Fish model and to use the insights gained to suggest modifications or alterations of the basic model. In order to evaluate the transitional model, a compressible boundary layer code was required. Accordingly, a two-dimensional compressible boundary layer code was developed. The program was based on a three-point fully implicit finite difference algorithm where the equations were solved in an uncoupled manner with second order extrapolation used to evaluate the non-linear coefficients. Iteration was offered as an option if the extrapolation error could not be tolerated. The differencing scheme was arranged to be second order in both spatial directions on an arbitrarily stretched mesh. A variety of boundary condition options were implemented including specification of an external pressure gradient, specification of a wall temperature distribution, and specification of an external temperature distribution. Overall the results of the initial phase of this work indicate that the McDonald-Fish model does a poor job at predicting the details of the turbulent flow structure during the transition region.

  18. Families in Transition .

    ERIC Educational Resources Information Center

    Bundy, Michael L., Ed.; Gumaer, James, Ed.

    1984-01-01

    Focuses on disrupted families and the role of the school counselor in helping children adjust. Describes characteristics of healthy families, and discusses the transition to the blended family, effects of divorce groups on children's classroom behavior, counseling children in stepfamilies, single-parent families, and parenting strengths of single…

  19. Immigration and Adult Transitions

    ERIC Educational Resources Information Center

    Rumbaut, Ruben G.; Komaie, Golnaz

    2010-01-01

    Almost 30 percent of the more than 68 million young adults aged eighteen to thirty-four in the United States today are either foreign born or of foreign parentage. As these newcomers make their transitions to adulthood, say Ruben Rumbaut and Golnaz Komaie, they differ significantly not only from one another but also from their native-parentage…

  20. Nursing Role Transition Preceptorship

    ERIC Educational Resources Information Center

    Batory, Susan M.

    2014-01-01

    The preceptorship clinical experience in a practical nursing (PN) program at a Midwestern community college is considered crucial to the PN students' transition from novice nurse to professional nurse. However, no research has been available to determine whether the preceptorship clinical accomplishes its purpose. A case study was conducted to…

  1. Administrative Theory in Transition.

    ERIC Educational Resources Information Center

    Griffiths, Daniel E.

    This monograph analyzes transition in educational administrative theory. A brief introductory section describes the theoretical movement, the substance and repercussions of Thomas Greenfield's critique of educational administrative theory in 1974, and emerging qualitative approaches. Seven readings, all written by the volume's author, view…

  2. Transition at hypersonic speeds

    NASA Technical Reports Server (NTRS)

    Morkovin, Mark V.

    1987-01-01

    Certain conjectures on the physics of instabilities in high-speed flows are discussed and the state of knowledge of hypersonic transition summarized. The case is made for an unpressured systematic research program in this area consisting of controlled microscopic experiments, theory, and numerical simulations.

  3. Transit of Extrasolar Planets

    NASA Technical Reports Server (NTRS)

    Doyle, Laurance R.

    1998-01-01

    During the past five years we have pursued the detection of extrasolar planets by the photometric transit method, i.e. the detection of a planet by watching for a drop in the brightness of the light as it crosses in front of a star. The planetary orbit must cross the line-of-sight and so most systems will not be lined up for such a transit to ever occur. However, we have looked at eclipsing binary systems which are already edge-on. Such systems must be very small in size as this makes the differential light change due to a transit much greater for a given planet size (the brightness difference will be proportional to the area of the transiting planet to the disc area of the star). Also, the planet forming region should be closer to the star as small stars are generally less luminous (that is, if the same thermal regime for planet formation applies as in the solar system). This led to studies of the habitable zone around other stars, as well. Finally, we discovered that our data could be used to detect giant planets without transits as we had been carefully timing the eclipses of the stars (using a GPS antenna for time) and this will drift by being offset by any giant planets orbiting around the system, as well. The best summary of our work may be to just summarize the 21 refereed papers produced during the time of this grant. This will be done is chronological order and in each section separately.

  4. Quantum Transition State Theory

    NASA Astrophysics Data System (ADS)

    Waalkens, Holger

    2009-03-01

    The main idea of Wigner's transition state theory (TST) is to compute reaction rates from the flux through a dividing surface placed between reactants and products. In order not to overestimate the rate the dividing surface needs to have the no- recrossing property, i.e. reactive trajectories cross the dividing surface exactly once, and nonreactive trajectories do not cross it at all. The long standing problem of how to construct such a diving surface for multi-degree-of-freedom systems was solved only recently using ideas from dynamical systems theory. Here a normal form allows for a local decoupling of the classical dynamics which leads to the explicit construction of the phase space structures that govern the reaction dynamics through transition states. The dividing surface is spanned by a normally hyperbolic manifold which is the mathematical manifestation of the transition state as an unstable invariant subsystem of one degree of freedom less than the full system. The mere existence of a quantum version of TST is discussed controversially in the literature. The key isssue is the presence of quantum mechanical tunneling which prohibits the existence of a local theory analogous to the classical case. Various approaches have been devloped to overcome this problem by propagating quantum wavefunctions through the transition state region. These approaches have in common that they are computationally very expensive which seriously limits their applicability. In contrast the approach by Roman Schubert, Stephen Wiggins and myself is local in nature. A quantum normal form allows us to locally decouple the quantum dynamics to any desired order in Planck's constant. This yields not only the location of the scattering and resonance wavefunctions relative to the classical phase space structures, but also leads to very efficient algorithms to compute cumulative reaction probabilities and Gamov-Siegert resonances which are the quantum imprints of the transition state.

  5. Transition States and transition state analogue interactions with enzymes.

    PubMed

    Schramm, Vern L

    2015-04-21

    Enzymatic transition states have lifetimes of a few femtoseconds (fs). Computational analysis of enzyme motions leading to transition state formation suggests that local catalytic site motions on the fs time scale provide the mechanism to locate transition states. An experimental test of protein fs motion and its relation to transition state formation can be provided by isotopically heavy proteins. Heavy enzymes have predictable mass-altered bond vibration states without altered electrostatic properties, according to the Born-Oppenheimer approximation. On-enzyme chemistry is slowed in most heavy proteins, consistent with altered protein bond frequencies slowing the search for the transition state. In other heavy enzymes, structural changes involved in reactant binding and release are also influenced. Slow protein motions associated with substrate binding and catalytic site preorganization are essential to allow the subsequent fs motions to locate the transition state and to facilitate the efficient release of products. In the catalytically competent geometry, local groups move in stochastic atomic motion on the fs time scale, within transition state-accessible conformations created by slower protein motions. The fs time scale for the transition state motions does not permit thermodynamic equilibrium between the transition state and stable enzyme states. Isotopically heavy enzymes provide a diagnostic tool for fast coupled protein motions to transition state formation and mass-dependent conformational changes. The binding of transition state analogue inhibitors is the opposite in catalytic time scale to formation of the transition state but is related by similar geometries of the enzyme-transition state and enzyme-inhibitor interactions. While enzymatic transition states have lifetimes as short as 10(-15) s, transition state analogues can bind tightly to enzymes with release rates greater than 10(3) s. Tight-binding transition state analogues stabilize the rare but

  6. Alternative fuel transit buses: The Pierce Transit Success Story

    SciTech Connect

    1996-10-01

    The Pierce transit program for operating mass transit buses on compressed natural gas (CNG) is described. Cost, reliability, fuel efficiency, emission of combustion products, and future trends are discussed.

  7. Transitions: exploring the frontier.

    PubMed

    Corless, Inge B

    End-of-life experiences go by various terms, including near-death experiences (NDEs), death bed visions, death bed phenomena, death bed coincidences, and nearing death awareness. Death bed escorts is the term applied to the vision of deceased family members or friends who inform the dying person that they will be accompanied in the transition from life. In this article, I examine the subject of NDEs and death bed escorts, starting with the rich body of work provided by Robert and Beatrice Kastenbaum. A subject of some interest to Robert Kastenbaum, he explored this frontier in his many writings on dying, death, and bereavement. Ever the pioneer and having made the ultimate transition, he may yet be exploring new frontiers.

  8. Emergence and Phase Transitions

    NASA Astrophysics Data System (ADS)

    Sikkema, Arnold

    2006-05-01

    Phase transitions are well defined in physics through concepts such as spontaneous symmetry breaking, order parameter, entropy, and critical exponents. But emergence --- also exhibiting whole-part relations (such as top-down influence), unpredictability, and insensitivity to microscopic detail --- is a loosely-defined concept being used in many disciplines, particularly in psychology, biology, philosophy, as well as in physics[1,2]. I will review the concepts of emergence as used in the various fields and consider the extent to which the methods of phase transitions can clarify the usefulness of the concept of emergence both within the discipline of physics and beyond.1. Robert B. Laughlin, A Different Universe: Reinventing Physics from the Bottom Down (New York: Basic Books, 2005). 2. George F.R. Ellis, ``Physics and the Real World'', Physics Today, vol. 58, no. 7 (July 2005) pp. 49-54.

  9. The Need for Transition

    DTIC Science & Technology

    2013-05-01

    assumptions. According to the original plan and assumptions, the Iraqi Police forces, which intelligence sources asserted were going to capitulate and...higher. This was all a result of failed assumptions in the prewar planning. Colonel Gregory Gardner , a member of the Joint Staff and then also on the...Institute (PKSOI) held a two day conference with multiple forces and international partners involved just to try and define transition. Each one of these

  10. Stimulated coherent transition radiation

    SciTech Connect

    Hung-chi Lihn

    1996-03-01

    Coherent radiation emitted from a relativistic electron bunch consists of wavelengths longer than or comparable to the bunch length. The intensity of this radiation out-numbers that of its incoherent counterpart, which extends to wavelengths shorter than the bunch length, by a factor equal to the number of electrons in the bunch. In typical accelerators, this factor is about 8 to 11 orders of magnitude. The spectrum of the coherent radiation is determined by the Fourier transform of the electron bunch distribution and, therefore, contains information of the bunch distribution. Coherent transition radiation emitted from subpicosecond electron bunches at the Stanford SUNSHINE facility is observed in the far-infrared regime through a room-temperature pyroelectric bolometer and characterized through the electron bunch-length study. To measure the bunch length, a new frequency-resolved subpicosecond bunch-length measuring system is developed. This system uses a far-infrared Michelson interferometer to measure the spectrum of coherent transition radiation through optical autocorrelation with resolution far better than existing time-resolved methods. Hence, the radiation spectrum and the bunch length are deduced from the autocorrelation measurement. To study the stimulation of coherent transition radiation, a special cavity named BRAICER is invented. Far-infrared light pulses of coherent transition radiation emitted from electron bunches are delayed and circulated in the cavity to coincide with subsequent incoming electron bunches. This coincidence of light pulses with electron bunches enables the light to do work on electrons, and thus stimulates more radiated energy. The possibilities of extending the bunch-length measuring system to measure the three-dimensional bunch distribution and making the BRAICER cavity a broadband, high-intensity, coherent, far-infrared light source are also discussed.

  11. Transition Region Flows

    NASA Astrophysics Data System (ADS)

    Brekke, P.; Murdin, P.

    2000-11-01

    Ultraviolet emission lines emitted from the SOLAR TRANSITION REGION are often shifted from their expected rest wavelengths. Shifts of spectral lines are due to the so-called DOPPLER EFFECT, where the source of emission is moving either away from or towards the observer, causing a change in the apparent wavelength. The shifted emission lines are most often interpreted as a flow of plasma along ...

  12. The Myths of Mass Transit.

    ERIC Educational Resources Information Center

    Burke, Catherine G.

    1982-01-01

    Criticizes eight commonly held notions about the value of mass transit systems in public transportation programs. Alternative approaches for improving the quality and quantity of urban transit systems are discussed. (AM)

  13. Psychological Aspects of Transitive Verbs

    ERIC Educational Resources Information Center

    Polzella, Donald J.; Rohrman, Nicholas L.

    1970-01-01

    The experiments reported here confirmed the findings of earlier researchers that transitive verbs are more difficult to recall than intransitive ones and furthermore established a close relationship between transitive verbs and nouns. Implications for linguistic theory are discussed. (FB)

  14. Youths Transitioning as Adult Learners

    ERIC Educational Resources Information Center

    Davis, C. Amelia

    2014-01-01

    This chapter considers how transitions to adulthood have been historically represented and presents alternative ways of thinking about transitions to adulthood through the context of adult basic education programs.

  15. Transition mixing study

    NASA Technical Reports Server (NTRS)

    Reynolds, R.; White, C.

    1986-01-01

    A computer model capable of analyzing the flow field in the transition liner of small gas turbine engines is developed. A FORTRAN code has been assembled from existing codes and physical submodels and used to predict the flow in several test geometries which contain characteristics similar to transition liners, and for which experimental data was available. Comparisons between the predictions and measurements indicate that the code produces qualitative results but that the turbulence models, both K-E and algebraic Reynolds Stress, underestimate the cross-stream diffusion. The code has also been used to perform a numerical experiment to examine the effect of a variety of parameters on the mixing process in transition liners. Comparisons illustrate that geometries with significant curvature show a drift of the jet trajectory toward the convex wall and weaker wake region vortices and decreased penetration for jets located on the convex wall of the liner, when compared to jets located on concave walls. Also shown were the approximate equivalency of angled slots and round holes and a technique by which jet mixing correlations developed for rectangular channels can be used for can geometries.

  16. Dynamic rigidity transition

    NASA Astrophysics Data System (ADS)

    Åström, J. A.; Latva-Kokko, M.; Timonen, J.

    2003-01-01

    An inflated closed loop (or membrane) is used to demonstrate a dynamic rigidity transition that occurs when impact energy is added to the loop in static equilibrium at zero temperature. The only relevant parameter in this transition is the ratio of the energy needed to collapse the loop and the impact energy. When this ratio is below a threshold value close to unity, the loop collapses into a high-entropy floppy state, and it does not return to the rigid state unless the impact energy can escape. The internal oscillations are in the floppy state dominated by 1/f2 noise. When the ratio is above the threshold, the loop does not collapse, and the internal oscillations resulting from the impact are dominated by the eigenfrequencies of the stretched membrane. In this state, the loop can bounce for a long time. It is still an open question whether bouncing will eventually vanish or whether a stationary bouncing state will be reached. The dynamic transition between the floppy and the rigid state is discontinuous.

  17. Structural transitions in clusters.

    PubMed

    Hartke, Bernd

    2002-05-03

    If one adds more particles to a cluster, the energetically optimal structure is neither preserved nor does it change in a continuous fashion. Instead, one finds several cluster size regions where one structural principle dominates almost without exception, and rather narrow boundary regions in-between. The structure of the solid is usually reached only at relatively large sizes, after more than one structural transition. The occurrence of this general phenomenon of size-dependent structural transitions does not seem to depend on the nature of the particles, it is found for atomic, molecular, homogeneous, and heterogeneous clusters alike. Clearly, it is a collective many-body phenomenon which can in principle be calculated but not understood in a fully reductionistic manner. Actual calculations with sufficient accuracy are not feasible today, because of the enormous computational expense, even when unconventional evolutionary algorithms are employed for global geometry optimization. Therefore, simple rules for cluster structures are highly desirable. In fact, we are dealing here not just with the academic quest for linkages between cluster structure and features of the potential energy surface, but structural transitions in clusters are also of immediate relevance for many natural and industrial processes, ranging from crystal growth all the way to nanotechnology. This article provides an exemplary overview of research on this topic, from simple model systems where first qualitative explanations start to be successful, up to more realistic complex systems which are still beyond our understanding.

  18. NASA metric transition plan

    NASA Technical Reports Server (NTRS)

    1992-01-01

    NASA science publications have used the metric system of measurement since 1970. Although NASA has maintained a metric use policy since 1979, practical constraints have restricted actual use of metric units. In 1988, an amendment to the Metric Conversion Act of 1975 required the Federal Government to adopt the metric system except where impractical. In response to Public Law 100-418 and Executive Order 12770, NASA revised its metric use policy and developed this Metric Transition Plan. NASA's goal is to use the metric system for program development and functional support activities to the greatest practical extent by the end of 1995. The introduction of the metric system into new flight programs will determine the pace of the metric transition. Transition of institutional capabilities and support functions will be phased to enable use of the metric system in flight program development and operations. Externally oriented elements of this plan will introduce and actively support use of the metric system in education, public information, and small business programs. The plan also establishes a procedure for evaluating and approving waivers and exceptions to the required use of the metric system for new programs. Coordination with other Federal agencies and departments (through the Interagency Council on Metric Policy) and industry (directly and through professional societies and interest groups) will identify sources of external support and minimize duplication of effort.

  19. Column continuous transition functions

    NASA Astrophysics Data System (ADS)

    Li, Yangrong

    2007-04-01

    A column continuous transition function is by definition a standard transition function P(t) whose every column is continuous for t[greater-or-equal, slanted]0 in the norm topology of bounded sequence space l[infinity]. We will prove that it has a stable q-matrix and that there exists a one-to-one relationship between column continuous transition functions and increasing integrated semigroups on l[infinity]. Using the theory of integrated semigroups, we give some necessary and sufficient conditions under which the minimal q-function is column continuous, in terms of its generator (of the Markov semigroup) as well as its q-matrix. Furthermore, we will construct all column continuous Q-functions for a conservative, single-exit and column bounded q-matrix Q. As applications, we find that many interesting continuous-time Markov chains (CTMCs), say Feller-Reuter-Riley processes, monotone processes, birth-death processes and branching processes, etc., have column continuity.

  20. The transition to agricultural sustainability

    PubMed Central

    Ruttan, Vernon W.

    1999-01-01

    The transition to sustainable growth in agricultural production during the 21st century will take place within the context of a transition to a stable population and a possible transition to a stable level of material consumption. If the world fails to successfully navigate a transition to sustainable growth in agricultural production, the failure will be due more to a failure in the area of institutional innovation than to resource and environmental constraints. PMID:10339524

  1. Visual Analytics Technology Transition Progress

    SciTech Connect

    Scholtz, Jean; Cook, Kristin A.; Whiting, Mark A.; Lemon, Douglas K.; Greenblatt, Howard

    2009-09-23

    The authors provide a description of the transition process for visual analytic tools and contrast this with the transition process for more traditional software tools. This paper takes this into account and describes a user-oriented approach to technology transition including a discussion of key factors that should be considered and adapted to each situation. The progress made in transitioning visual analytic tools in the past five years is described and the challenges that remain are enumerated.

  2. Analyses of some exoplanets' transits and transit timing variations

    NASA Astrophysics Data System (ADS)

    Püsküllü, ćaǧlar; Soydugan, Faruk

    2017-02-01

    We present solutions of the transit light curves and transit timing variations (TTVs) analyses of the exoplanets HAT-P-5b, HAT-P-9b and HAT-P-25b. Transit light curves were collected at Çanakkale Onsekiz Mart University Observatory and TUBITAK National Observatory. The models were produced by WINFITTER program and stellar, planetary and orbital properties were obtained and discussed. We gave new transit times and generated TTVs with them by appending additional data based on Exoplanet Transit Database (ETD). Significant signals at the TTVs were also investigated.

  3. Slow Transit Constipation.

    PubMed

    Wald, Arnold

    2002-08-01

    The diagnosis of slow transit functional constipation is based upon diagnostic testing of patients with idiopathic constipation who responded poorly to conservative measures such as fiber supplements, fluids, and stimulant laxatives. These tests include barium enema or colonoscopy, colonic transit of radio-opaque markers, anorectal manometry, and expulsion of a water-filled balloon. Plain abdominal films can identify megacolon, which can be further characterized by barium or gastrografin studies. Colonic transit of radio-opaque markers identifies patients with slow transit with stasis of markers in the proximal colon. However, anorectal function should be characterized to exclude outlet dysfunction, which may coexist with colonic inertia. Because slow colonic transit is defined by studies during which patients consume a high-fiber diet, fiber supplements are generally not effective, nor are osmotic laxatives that consist of unabsorbed sugars. Stimulant laxatives are considered first-line therapy, although studies often show a diminished colonic motor response to such agents. There is no evidence to suggest that chronic use of such laxatives is harmful if they are used two to three times per week. Polyethylene glycol with or without electrolytes may be useful in a minority of patients, often combined with misoprostol. I prefer to start with misoprostol 200 mg every other morning and increase to tolerance or efficacy. I see no advantage in prescribing misoprostol on a TID or QID basis or even daily because it increases cramping unnecessarily. This drug is not acceptable in young women who wish to become pregnant. An alternative may be colchicine, which is reported to be effective when given as 0.6 mg TID. Long-term efficacy has not been studied. Finally, biofeedback is a risk-free approach that has been reported as effective in approximately 60% of patients with slow transit constipation in the absence of outlet dysfunction. Although difficult to understand

  4. Alameda-Contra Costa Transit District (AC Transit) Fuel Cell Transit Buses: Preliminary Evaluation Results

    SciTech Connect

    Chandler, K.; Eudy, L.

    2007-03-01

    This report provides an evaluation of three prototype fuel cell-powered transit buses operating at AC Transit in Oakland, California, and six baseline diesel buses similar in design to the fuel cell buses.

  5. Pivotal Transitions - Historical and Today

    NASA Astrophysics Data System (ADS)

    Hurley, M.

    2008-08-01

    The goal of this paper is to enable readers to better "design" successful transitions that move Science and Technology or Research and Development (S&T/R&D) technologies and systems into operational capabilities for users. Transitions from S&T/R&D into acquisition and operations are challenging and critical to providing capab ilities to end users. Two historical examples, the Global Positioning System (GPS) and the Disaster Monitoring Constellation (DMC), are explored. Two current examples are also explored, including one from Operationally Responsive Space (ORS) which is in th e early stages of transition. While transitions are necessary, transition periods are inherently challenging and dynamically changing situations. These situations must be carefully managed and led in order to succeed. Characteristics, approaches, and incentives that foster effective transitions are discussed. Understanding the transition process and the communities involved allows one to maximize the chance of successfully moving an S&T/R&D development into an operational capability supporting end users.

  6. A translational evaluation of transitions.

    PubMed

    Jessel, Joshua; Hanley, Gregory P; Ghaemmaghami, Mahshid

    2016-06-01

    Transitions with nonhuman animals are typically framed as inescapable changes in signaled reinforcement schedules that result in a pause in responding unique to switches from rich to lean schedules. Pausing is considered to be a function of the aversive qualities of the contrasting reinforcement schedules. Transitions are typically framed in applied research as physical changes in location that evoke problem behavior maintained by the escape of an aversive event or resumption of a preferred event. We attempted to extend the basic framing of transitions to behaviors and contexts of social significance and evaluate a novel treatment for the problem of dawdling by 3 boys who had been diagnosed with autism spectrum disorder during rich-to-lean transitions. Dawdling during physical transitions was most readily observed when transitioning to lean contexts in Experiment 1. We then shortened transition duration in Experiment 2 by programming unsignaled and probabilistic rich reinforcement in the upcoming context.

  7. MINEHOUND: transition to production

    NASA Astrophysics Data System (ADS)

    Daniels, David J.; Curtis, Paul; Hunt, Nigel; Braunstein, Jürgen; Merz, Armin

    2007-04-01

    The UK Department for International Development (DfID), in collaboration with the German Foreign Ministry (Auswärtiges Amt), contracted ERA Technology to carry out extensive field trials in Cambodia, Bosnia and Angola of an advanced technology, dual sensor, and hand-held landmine detector system called MINEHOUND TM. This detector combines a metal detector with a Ground Penetrating Radar (GPR). As a result of extremely successful trials MINEHOUND TM was developed as a product by ERA Technology and Vallon GmbH and has been available for sale since late 2006. This paper describes the transition to production of the detector.

  8. Transition Path Theory

    NASA Astrophysics Data System (ADS)

    vanden-Eijnden, E.

    The dynamical behavior of many systems arising in physics, chemistry, biology, etc. is dominated by rare but important transition events between long lived states. For over 70 years, transition state theory (TST) has provided the main theoretical framework for the description of these events [17,33,34]. Yet, while TST and evolutions thereof based on the reactive flux formalism [1, 5] (see also [30,31]) give an accurate estimate of the transition rate of a reaction, at least in principle, the theory tells very little in terms of the mechanism of this reaction. Recent advances, such as transition path sampling (TPS) of Bolhuis, Chandler, Dellago, and Geissler [3, 7] or the action method of Elber [15, 16], may seem to go beyond TST in that respect: these techniques allow indeed to sample the ensemble of reactive trajectories, i.e. the trajectories by which the reaction occurs. And yet, the reactive trajectories may again be rather uninformative about the mechanism of the reaction. This may sound paradoxical at first: what more than actual reactive trajectories could one need to understand a reaction? The problem, however, is that the reactive trajectories by themselves give only a very indirect information about the statistical properties of these trajectories. This is similar to why statistical mechanics is not simply a footnote in books about classical mechanics. What is the probability density that a trajectory be at a given location in state-space conditional on it being reactive? What is the probability current of these reactive trajectories? What is their rate of appearance? These are the questions of interest and they are not easy to answer directly from the ensemble of reactive trajectories. The right framework to tackle these questions also goes beyond standard equilibrium statistical mechanics because of the nontrivial bias that the very definition of the reactive trajectories imply - they must be involved in a reaction. The aim of this chapter is to

  9. Transition Metal Switchable Mirror

    SciTech Connect

    2009-01-01

    The switchable-mirrors technology was developed by Tom Richardson and Jonathan Slack of Berkeley Lab's Environmental Energy Technologies Division. By using transition metals rather than the rare earth metals used in the first metal-hydride switchable mirrors, Richardson and Slack were able to lower the cost and simplify the manufacturing process. Energy performance is improved as well, because the new windows can reflect or transmit both visible and infrared light. Besides windows for offices and homes, possible applications include automobile sunroofs, signs and displays, aircraft windows, and spacecraft. More information at: http://windows.lbl.gov/materials/chromogenics/default.htm

  10. Transition Metal Switchable Mirror

    SciTech Connect

    2009-08-21

    The switchable-mirrors technology was developed by Tom Richardson and Jonathan Slack of Berkeley Lab's Environmental Energy Technologies Division. By using transition metals rather than the rare earth metals used in the first metal-hydride switchable mirrors, Richardson and Slack were able to lower the cost and simplify the manufacturing process. Energy performance is improved as well, because the new windows can reflect or transmit both visible and infrared light. Besides windows for offices and homes, possible applications include automobile sunroofs, signs and displays, aircraft windows, and spacecraft.

  11. Transition Metal Switchable Mirror

    ScienceCinema

    None

    2016-07-12

    The switchable-mirrors technology was developed by Tom Richardson and Jonathan Slack of Berkeley Lab's Environmental Energy Technologies Division. By using transition metals rather than the rare earth metals used in the first metal-hydride switchable mirrors, Richardson and Slack were able to lower the cost and simplify the manufacturing process. Energy performance is improved as well, because the new windows can reflect or transmit both visible and infrared light. Besides windows for offices and homes, possible applications include automobile sunroofs, signs and displays, aircraft windows, and spacecraft. More information at: http://windows.lbl.gov/materials/chromogenics/default.htm

  12. Transition Metal Switchable Mirror

    ScienceCinema

    None

    2016-07-12

    The switchable-mirrors technology was developed by Tom Richardson and Jonathan Slack of Berkeley Lab's Environmental Energy Technologies Division. By using transition metals rather than the rare earth metals used in the first metal-hydride switchable mirrors, Richardson and Slack were able to lower the cost and simplify the manufacturing process. Energy performance is improved as well, because the new windows can reflect or transmit both visible and infrared light. Besides windows for offices and homes, possible applications include automobile sunroofs, signs and displays, aircraft windows, and spacecraft.

  13. Planet Demographics from Transits

    NASA Astrophysics Data System (ADS)

    Howard, Andrew

    2015-08-01

    From the demographics of planets detected by the Kepler mission, we have learned that there exists approximately one planet per star for planets larger than Earth orbiting inside of 1 AU. We have also learned the relative occurrence of these planets as a function of their orbital periods, sizes, and host star masses and metallicities. In this talk I will review the key statistical findings that the planet size distribution peaks in the range 1-3 times Earth-size, the orbital period distribution is characterized by a power-law cut off at short periods, small planets are more prevalent around small stars, and that approximately 20% of Sun-like stars hosts a planet 1-2 times Earth-size in a habitable zone. Looking forward, I will describe analysis of photometry from the K2 mission that is yielding initial planet discoveries and offering the opportunity to measure planet occurrence in widely separated regions of the galaxy. Finally, I will also discuss recent techniques to discover transiting planets in space-based photometry and to infer planet population properties from the ensemble of detected and non-detected transit signals.

  14. Physicians in transition.

    PubMed

    Bluestein, P

    1995-12-01

    The study of physicians as managed care executives has been relatively recent. Much of what was written in the past focused primarily on doctors who had taken hospital-based administrative positions, especially as medical directors or vice presidents of medical affairs.1 But the '80s brought rising health care costs and the emergence of the "O's"--HMOs, PPOs, UROs, EPOs, PHOs, H2Os, and Uh-Ohs--in response. It also brought a growing number of physicians who traded their white coats and their particular "ologies" for the blue suits of executive management. I am convinced that it is important now, and will be increasingly important in the future, to better understand that transition. That belief led me to undertake, with the help and support of ACPE, the survey that is reported in this article. A questionnaire was sent in 1994 to a random sample of 300 managed care physician executive members of ACPE. Responses were returned by 225 members, a response rate of better than 80 percent. Twenty-five of the responses were not applicable, having been returned by physicians who had never made a transition from clinical careers. The remaining 230 responses form the basis for this report.

  15. 309 Building transition plan

    SciTech Connect

    Graves, C.E.

    1994-08-31

    The preparation for decontamination and decommissioning (transition) of the 309 Building is projected to be completed by the end of the fiscal year (FY) 1998. The major stabilization and decontamination efforts include the Plutonium Recycle Test Reactor (PRTR), fuel storage and transfer pits, Transfer Waste (TW) tanks and the Ion Exchange Vaults. In addition to stabilizing contaminated areas, equipment, components, records, waste products, etc., will be dispositioned. All nonessential systems, i.e., heating, ventilation, and air conditioning (HVAC), electrical, monitoring, fluids, etc., will be shut down and drained/de-energized. This will allow securing of the process, laboratory, and office areas of the facility. After that, the facility will be operated at a level commensurate with its surveillance needs while awaiting D&D. The implementation costs for FY 1995 through FY 1998 for the transition activities are estimated to be $1,070K, $2,115K, $2,939K, and $4,762K, respectively. Costs include an assumed company overhead of 20% and a 30% out year contingency.

  16. Transit Timing Study of Kepler Planets

    NASA Astrophysics Data System (ADS)

    Xie, Jiwei

    2015-08-01

    Kepler space telescope has found over 4000 transiting planet candidates. Transit timing is a powerful tool to study these transit planet candidates. In this talk, I will talk about two transit timing techniques, i.e., transit timing variation (TTV) and transit duration (TD), which enable confirming their planetary nature and obtaining insight into their orbital properties.

  17. Partnership Transitions and Maternal Parenting

    PubMed Central

    Beck, Audrey N.; Cooper, Carey E.; McLanahan, Sara; Brooks-Gunn, Jeanne

    2011-01-01

    We use data from the Fragile Families and Child Wellbeing Study (N = 1,975) to examine the association between mothers’ partnership changes and parenting behavior during the first five years of their children’s lives. We compare coresidential with dating transitions, and recent with more distal transitions. We also examine interactions between transitions and race/ethnicity, maternal education and family structure at birth. Findings indicate that both coresidential and dating transitions were associated with higher levels of maternal stress and harsh parenting; recent transitions had stronger associations than distal transitions. Maternal education significantly moderates these associations, with less educated mothers responding more negatively to instability in terms of maternal stress, and more educated mothers responding more negatively in terms of literacy activities. PMID:21423848

  18. Pubertal transitions in health.

    PubMed

    Patton, George C; Viner, Russell

    2007-03-31

    Puberty is accompanied by physical, psychological, and emotional changes adapted to ensure reproductive and parenting success. Human puberty stands out in the animal world for its association with brain maturation and physical growth. Its effects on health and wellbeing are profound and paradoxical. On the one hand, physical maturation propels an individual into adolescence with peaks in strength, speed, and fitness. Clinicians have viewed puberty as a point of maturing out of childhood-onset conditions. However, puberty's relevance for health has shifted with a modern rise in psychosocial disorders of young people. It marks a transition in risks for depression and other mental disorders, psychosomatic syndromes, substance misuse, and antisocial behaviours. Recent secular trends in these psychosocial disorders coincide with a growing mismatch between biological and social maturation, and the emergence of more dominant youth cultures.

  19. Nonadiabatic transition path sampling

    NASA Astrophysics Data System (ADS)

    Sherman, M. C.; Corcelli, S. A.

    2016-07-01

    Fewest-switches surface hopping (FSSH) is combined with transition path sampling (TPS) to produce a new method called nonadiabatic path sampling (NAPS). The NAPS method is validated on a model electron transfer system coupled to a Langevin bath. Numerically exact rate constants are computed using the reactive flux (RF) method over a broad range of solvent frictions that span from the energy diffusion (low friction) regime to the spatial diffusion (high friction) regime. The NAPS method is shown to quantitatively reproduce the RF benchmark rate constants over the full range of solvent friction. Integrating FSSH within the TPS framework expands the applicability of both approaches and creates a new method that will be helpful in determining detailed mechanisms for nonadiabatic reactions in the condensed-phase.

  20. Phases and Phase Transitions

    NASA Astrophysics Data System (ADS)

    Gitterman, Moshe

    2014-09-01

    In discussing phase transitions, the first thing that we have to do is to define a phase. This is a concept from thermodynamics and statistical mechanics, where a phase is defined as a homogeneous system. As a simple example, let us consider instant coffee. This consists of coffee powder dissolved in water, and after stirring it we have a homogeneous mixture, i.e., a single phase. If we add to a cup of coffee a spoonful of sugar and stir it well, we still have a single phase -- sweet coffee. However, if we add ten spoonfuls of sugar, then the contents of the cup will no longer be homogeneous, but rather a mixture of two homogeneous systems or phases, sweet liquid coffee on top and coffee-flavored wet sugar at the bottom...

  1. Hybrid Electric Transit Bus

    NASA Technical Reports Server (NTRS)

    Viterna, Larry A.

    1997-01-01

    A government, industry, and university cooperative is developing an advanced hybrid electric city transit bus. Goals of this effort include doubling the fuel economy compared to current buses and reducing emissions to one-tenth of current EPA standards. Unique aspects of the vehicle's power system include the use of ultra-capacitors as an energy storage system, and a planned natural gas fueled turbogenerator developed from a small jet engine. Power from both the generator and energy storage system is provided to a variable speed electric motor attached to the rear axle. At over 15000 kg gross weight, this is the largest vehicle of its kind ever built using ultra-capacitor energy storage. This paper describes the overall power system architecture, the evolution of the control strategy, and its performance over industry standard drive cycles.

  2. Transit satellite system timing capabilities

    NASA Technical Reports Server (NTRS)

    Finsod, T. D.

    1978-01-01

    Current time transfer capabilities of the Transit Satellite System are reviewed. Potential improvements in the changes in equipment and operational procedures using operational satellites are discussed.

  3. Diverse types of percolation transitions

    NASA Astrophysics Data System (ADS)

    Lee, Deokjae; Cho, Y. S.; Kahng, B.

    2016-12-01

    Percolation has long served as a model for diverse phenomena and systems. The percolation transition, that is, the formation of a giant cluster on a macroscopic scale, is known as one of the most robust continuous transitions. Recently, however, many abrupt percolation transitions have been observed in complex systems. To illustrate such phenomena, considerable effort has been made to introduce models and construct theoretical frameworks for explosive, discontinuous, and hybrid percolation transitions. Experimental results have also been reported. In this review article, we describe such percolation models, their critical behaviors and universal features, and real-world phenomena.

  4. Transit administration and planning research

    SciTech Connect

    de Corla-Souza; Gupta.

    1989-01-01

    The 10 papers in the report deal with the following areas: Evaluation of demand-management strategies for Toledo's year 2010 transportation plan; Accommodating deaf and hard-of-hearing persons on public transportation systems in Massachusetts; Quick approach to compare highway and bus transit alternatives using the arterial analysis package; Panel survey approach to measuring transit route service elasticity of demand; UMTA and major investments: evaluation process and results; Using early performance to project transit route ridership: comparison of methods; Institutional requirements for competition: labor issues; Updating ride checks with multiple point checks; Producing section 15 service-consumed data: challenge for large transit; Parkrose targeted marketing campaign pass-incentive program.

  5. Essentials of Transition Planning. Brookes Transition to Adulthood Series

    ERIC Educational Resources Information Center

    Wehman, Paul

    2011-01-01

    For young people with disabilities, crossing the bridge to adulthood will be empowering instead of intimidating--when their support teams know the essentials of effective transition planning. Now all the fundamentals of well-crafted transition plans are collected in one concise quick-guide, straight from one of the top authorities on helping young…

  6. Transitions to Least Restrictive Environments: A Guide to Transition. Revised.

    ERIC Educational Resources Information Center

    Beninghof, Anne M.

    This guide to the transition of special education students to less restrictive environments or from school to work stresses the importance of planning and communication during the entire process, from initial plans through implementation and follow-up. Section 1 consists of a "Transition Process Checklist" to aid in the organization and follow…

  7. Connecticut Transit (CTTRANSIT) Fuel Cell Transit Bus: Preliminary Evaluation Results

    SciTech Connect

    Chandler, K.; Eudy, L.

    2008-10-01

    This report provides preliminary results from a National Renewable Energy Laboratory evaluation of a protoptye fuel cell transit bus operating at Connecticut Transit in Hartford. Included are descriptions of the planned fuel cell bus demonstration and equipment; early results and agency experience are also provided.

  8. Phase transitions in disordered systems

    NASA Astrophysics Data System (ADS)

    Hrahsheh, Fawaz Y.

    Disorder can have a wide variety of consequences for the physics of phase transitions. Some transitions remain unchanged in the presence of disorder while others are completely destroyed. In this thesis we study the effects of disorder on several classical and quantum phase transitions in condensed matter systems. After a brief introduction, we study the ferromagnetic phase transition in a randomly layered Heisenberg magnet using large-scale Monte-Carlo simulations. Our results provide numerical evidence for the exotic infinite-randomness scenario. We study classical and quantum smeared phase transitions in substitutional alloys A1-xBx. Our results show that the disorder completely destroys the phase transition with a pronounced tail of the ordered phase developing for all compositions x < 1. In addition, we find that short-ranged disorder correlations can have a dramatic effect on the transition. Moreover, we show an experimental realization of the composition-tuned ferromagnetic-to-paramagnetic quantum phase transition in Sr1-xCa xRuO3. We investigate the effects of disorder on first-order quantum phase transitions on the example of the N-color quantum Ashkin-Teller model. By means of a strong disorder renormalization group, we demonstrate that disorder rounds the first-order transition to a continuous one for both weak and strong coupling between the colors. Finally, we investigate the superfluid-insulator quantum phase transition of one-dimensional bosons with off-diagonal disorder by means of large-scale Monte-Carlo simulations. Beyond a critical disorder strength, we find nonuniversal, disorder dependent critical behavior.

  9. Light Scattering in Exoplanet Transits

    NASA Astrophysics Data System (ADS)

    Robinson, Tyler D.; Fortney, Jonathan J.

    2016-10-01

    Transit spectroscopy is currently the leading technique for studying exoplanet atmospheric composition, and has led to the detection of molecular species, clouds, and/or hazes for numerous worlds outside the Solar System. The field of exoplanet transit spectroscopy will be revolutionized with the anticipated launch of NASA's James Webb Space Telescope (JWST) in 2018. Over the course of the design five year mission for JWST, the observatory is expected to provide in-depth observations of many tens of transiting exoplanets, including some worlds in the poorly understood 2-4 Earth-mass regime. As the quality of transit spectrum observations continues to improve, so should models of exoplanet transits. Thus, certain processes initially thought to be of second-order importance should be revisited and possibly added to modeling tools. For example, atmospheric refraction, which was commonly omitted from early transit spectrum models, has recently been shown to be of critical importance in some terrestrial exoplanet transits. Beyond refraction, another process that has seen little study with regards to exoplanet transits is light multiple scattering. In most cases, scattering opacity in exoplanet transits has been treated as equivalent to absorption opacity. However, this equivalence cannot always hold, such as in the case of a strongly forward scattering, weakly absorbing aerosol. In this presentation, we outline a theory of exoplanet transit spectroscopy that spans the geometric limit (used in most modern models) to a fully multiple scattering approach. We discuss a new technique for improving model efficiency that effectively separates photon paths, which tend to vary slowly in wavelength, from photon absorption, which can vary rapidly in wavelength. Using this newly developed approach, we explore situations where cloud or haze scattering may be important to JWST observations of gas giants, and comment on the conditions necessary for scattering to become a major

  10. Detection by Transit Photometry

    NASA Technical Reports Server (NTRS)

    Borucki, William J.; Koch, David G.; Jenkins, Jon M.; DeVincenzi, D. (Technical Monitor)

    2002-01-01

    A periodic sequence of planetary transits provides a valid detection of an orbiting planet and provides the relative size of the planet and its orbital period. Ancillary measurements of the stellar spectrum and the variations of the star's radial velocity or position combined with stellar models allow the absolute size of the planet and its mass to be obtained. The results of this approach have already shown that the planet orbiting HD209458 has only 70% of the mass of Jupiter, but is nearly 50% larger in radius. Based on models of planetary structure, these results imply that the planet must have spent most of its lifetime so close to the star that it has not been able to cool and contract as have the giant planets in our Solar System. Thus its density is much less than Jupiter and Saturn and is actually less than that of water; i.e., about 0.4 gr/cu cm. If more sensitive measurements of the light curve of stars with closely orbiting planets can be made that provide the varying amplitude of the light reflected by the planet at various phases in its orbit, then characteristics of the planetary atmosphere can be obtained. Potentially, these data can identify major molecular species present in the atmosphere and tell us if clouds are present and yield the phase function of the aerosols. Although such detail cannot be obtained for Earth-size planets because their signal amplitudes are too small, it is possible to get data critical to the determination of the structure of extrasolar planetary systems. In particular, the size distributions and their orbital distributions can be measured by the transit photometry missions now in development. The COROT mission should be able to find large terrestrial planets in short-period orbits while the more ambitious Kepler and Eddington missions should be able to detect planets even smaller than the Earth and at orbital distances that place them in the habitable zone of their stars.

  11. Transition Planning for Foster Youth

    ERIC Educational Resources Information Center

    Geenen, Sarah J.; Powers, Laurie E.

    2006-01-01

    The study evaluated the IEPs/Individualized Transition Plans of 45 students who were in special education and foster care, and compared them to the plans of 45 students who were in special education only. Results indicate that the transition plans of foster youth with disabilities were poor in quality, both in absolute terms and in comparison to…

  12. Adult Transition Program without Walls

    ERIC Educational Resources Information Center

    Moberg, Eric

    2010-01-01

    Best practices in adult transition special education for moderate to severe students suggest student-centered planning that maximizes independence in adult life. Based on the above sources, school districts and governing boards would best serve moderate to severe transition special education students with increasing integration into the community…

  13. Nonadiabatic transitions and gauge structure

    SciTech Connect

    Nakamura, K. ); Rice, S.A. )

    1994-04-01

    We examine the role of fictitious gauge structure in nonadiabatic transitions for transport in open paths. Local features of the gauge potential modify the nature of the intersection of the adiabatic energy surfaces and thereby affect crucially the Landau-Zener formula for a single-passage transition rate.

  14. Role Transitions in Small Groups.

    ERIC Educational Resources Information Center

    Moreland, Richard L.; Levine, John M.

    This paper analyzes role transitions in small groups within the context of a more general model of group socialization that is based on the psychological processes of evaluation, commitment, and decision making. The major advantage of such an approach is that it specifies why role transitions in small groups occur. According to the model, groups…

  15. Assessing transitional phenomena with the transitional object memory probe.

    PubMed

    Fowler, C; Hilsenroth, M J; Handler, L

    1998-01-01

    Winnicott's concept of transitional relatedness has captured the interest of psychoanalysts because it provides an understanding of the dialectical process occurring between inner and outer reality, and by extension, between analyst and analysand. Clinical observations related to transitional phenomena have led the authors to develop a projective early memory probe that assesses transitional phenomena. The transitional object early memory probe was tested both for its empirical validity and for its clinical utility in psychodynamic psychotherapy. Construct validity was assessed by comparing memory scores to the Rorschach Transitional Object Scale, as well as to therapist ratings of patient behaviors. Results demonstrated moderate correlations between early memory scores and Rorschach scale scores. Equally important was the finding that early memory scores were significantly correlated with therapist ratings of key behavioral patterns in therapy. A case vignette highlights the clinical application of the transitional object probe in assessing the capacity for transitional relatedness. In this case, the data gleaned from the patient's memories provided the therapist with a sharper focus on their role in the patient's growing capacity for more vital and creative contact with reality.

  16. Selenophene transition metal complexes

    SciTech Connect

    White, Carter James

    1994-07-27

    This research shows that selenophene transition metal complexes have a chemistry that is similar to their thiophene analogs. Selenophene coordination has been demonstrated and confirmed by molecular structure in both the η5- and the η1(Se)-coordination modes. The reaction chemistry of selenophene complexes closely resembles that of the analogous thiophene complexes. One major difference, however, is that selenophene is a better donor ligand than thiophene making the selenophene complexes more stable than the corresponding thiophene complexes. The 77Se NMR chemical shift values for selenophene complexes fall within distinct regions primarily depending on the coordination mode of the selenophene ligand. In the final paper, the C-H bond activation of η1(S)-bound thiophenes, η1(S)-benzothiophene and η1(Se)-bound selenophenes has been demonstrated. The deprotonation and rearrangement of the η1(E)-bound ligand to the carbon bound L-yl complex readily occurs in the presence of base. Reprotonation with a strong acid gives a carbene complex that is unreactive towards nucleophilic attack at the carbene carbon and is stable towards exposure to air. The molecular structure of [Cp(NO)(PPh3)Re(2-benzothioenylcarbene)]O3SCF3 was determined and contains a Re-C bond with substantial double bond character. Methyl substitution for the thienylcarbene or selenylcarbene gives a carbene that rearranges thermally to give back the η1(E)-bound complex. Based on these model reactions, a new mechanism for the H/D exchange of thiophene over the hydrodesulfurization catalyst has been proposed.

  17. Unusual spin transitions

    NASA Astrophysics Data System (ADS)

    Ovcharenko, V. I.; Fokin, S. V.; Romanenko, G. V.; Ikorskii, V. N.; Tretyakov, E. V.; Vasilevsky, S. F.; Sagdeev, R. Z.

    New heterospin complexes of Cu(hfac) 2 (hfac, hexafluoroacetylacetonate) with pyrazole-substituted nitronyl nitroxides have been found that in the solid state exhibit thermally induced spin transitions analogous to spin crossover. For the first complex, [Cu(hfac) 2 L i-Pr ], at room temperature, the Cu - O L distances, where O L is the oxygen atom of the nitroxyl group, are very short (2.143 Å). This leads to a strong antiferromagnetic exchange (~-120 cm -1 ) in the > N - •O - Cu 2+ - O •- N< exchange clusters. The CuO 6 coordination units formed by four O atoms of the two hfac anions and by the nitroxyl O atoms of the two bridging nitroxides have a rare form of flattened octahedra, transformed at low temperatures into elongated octahedra with shorter Cu - O L distances (2.143 Å ⇔2.002 Å) and two longer Cu - O hfac distances (2.130 Å ⇔2.293 Å). For the second complex, [Cu(hfac) 2 L Bu ·0.5C 6 H 14 ], unusual low temperature structural dynamics of heterospin systems have been found. It is characterized by the formation of two types of CuO 6 unit. The axial Cu - O L distances are lengthened in one unit (2.250 Å 2.347 Å) and shortened in the other (2.250 Å ⇔2.006 Å). This leads to a sophisticated μeff ( T ) dependence with μeff drastically decreased at 163 K as a result of full coupling of two spins in half of all >N - •O - Cu 2+ - O •- N< exchange clusters and to a shift from antiferromagnetic to ferromagnetic exchange in the other half.

  18. 22 CFR 41.71 - Transit aliens.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 22 Foreign Relations 1 2012-04-01 2012-04-01 false Transit aliens. 41.71 Section 41.71 Foreign... NATIONALITY ACT, AS AMENDED Transit Aliens § 41.71 Transit aliens. (a) Transit aliens—general. An alien is classifiable as a nonimmigrant transit alien under INA 101(a) (15) (C) if the consular officer is...

  19. 22 CFR 41.71 - Transit aliens.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 22 Foreign Relations 1 2014-04-01 2014-04-01 false Transit aliens. 41.71 Section 41.71 Foreign... NATIONALITY ACT, AS AMENDED Transit Aliens § 41.71 Transit aliens. (a) Transit aliens—general. An alien is classifiable as a nonimmigrant transit alien under INA 101(a) (15) (C) if the consular officer is...

  20. 22 CFR 41.71 - Transit aliens.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 22 Foreign Relations 1 2010-04-01 2010-04-01 false Transit aliens. 41.71 Section 41.71 Foreign... NATIONALITY ACT, AS AMENDED Transit Aliens § 41.71 Transit aliens. (a) Transit aliens—general. An alien is classifiable as a nonimmigrant transit alien under INA 101(a) (15) (C) if the consular officer is...

  1. 22 CFR 41.71 - Transit aliens.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 22 Foreign Relations 1 2013-04-01 2013-04-01 false Transit aliens. 41.71 Section 41.71 Foreign... NATIONALITY ACT, AS AMENDED Transit Aliens § 41.71 Transit aliens. (a) Transit aliens—general. An alien is classifiable as a nonimmigrant transit alien under INA 101(a) (15) (C) if the consular officer is...

  2. 22 CFR 41.71 - Transit aliens.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 22 Foreign Relations 1 2011-04-01 2011-04-01 false Transit aliens. 41.71 Section 41.71 Foreign... NATIONALITY ACT, AS AMENDED Transit Aliens § 41.71 Transit aliens. (a) Transit aliens—general. An alien is classifiable as a nonimmigrant transit alien under INA 101(a) (15) (C) if the consular officer is...

  3. Electronic Transitions of Yttrium Monophosphide

    NASA Astrophysics Data System (ADS)

    Cheung, Allan S. C.; Li, Biu Wa; Chan, MAN-CHOR

    2015-06-01

    Electronic transition spectrum of the yttrium monophosphide (YP) molecule in the visible region between 715 nm and 880 nm has been recorded using laser ablation/reaction free-jet expansion and laser induced fluorescence spectroscopy. The YP molecule was produced by reacting laser - ablated yttrium atoms with PH3 seeded in argon. Thirteen vibrational bands were analyzed and five electronic transition systems have identified, namely the [12.2] Ω = 3 - X3 Π_2 transition, [13.3] Ω = 3 - X3 Π_2 transition, [13.4] Ω = 3 - X3 Π_2 transition, [13.5] Ω = 3 - X3 Π_2 transition, and [13.4] Ω = 2 - X3 Π_2 transition. Least squares fits of the measured rotational lines yielded molecular constants for the ground and excited states. The ground state symmetry and the bond length r_0 of the YP molecule have been determined to be a X3 Π_2 state and 2.4413 Å respectively in this work. A molecular orbital energy level diagram has been used to help the assignment of the observed electronic states. This work represents the first experimental investigation of the spectrum of the YP molecule.

  4. Observational biases for transiting planets

    NASA Astrophysics Data System (ADS)

    Kipping, David M.; Sandford, Emily

    2016-12-01

    Observational biases distort our view of nature, such that the patterns we see within a surveyed population of interest are often unrepresentative of the truth we seek. Transiting planets currently represent the most informative data set on the ensemble properties of exoplanets within 1 au of their star. However, the transit method is inherently biased due to both geometric and detection-driven effects. In this work, we derive the overall observational biases affecting the most basic transit parameters from first principles. By assuming a trapezoidal transit and using conditional probability, we infer the expected distribution of these terms both as a joint distribution and in a marginalized form. These general analytic results provide a baseline against which to compare trends predicted by mission-tailored injection/recovery simulations and offer a simple way to correct for observational bias. Our results explain why the observed population of transiting planets displays a non-uniform impact parameter distribution, with a bias towards near-equatorial geometries. We also find that the geometric bias towards observed planets transiting near periastron is attenuated by the longer durations which occur near apoastron. Finally, we predict that the observational bias with respect to ratio-of-radii is super-quadratic, scaling as (RP/R⋆)5/2, driven by an enhanced geometric transit probability and modestly longer durations.

  5. The Visibility of Earth Transits

    NASA Technical Reports Server (NTRS)

    Castellano, Timothy P.; Doyle, Laurance; McIntosh, Dawn; DeVincenzi, Donald (Technical Monitor)

    2000-01-01

    The recent photometric detection of planetary transits of the solar-like star HD 209458 at a distance of 47 parsecs suggest that transits can reveal the presence of Jupiter-size planetary companions in the solar neighborhood. Recent space-based transit searches have achieved photometric precision within an order of magnitude of that required to detect the much smaller transit signal of an earth-size planet across a solar-size star. Laboratory experiments in the presence of realistic noise sources have shown that CCDs can achieve photometric precision adequate to detect the 9.6 E-5 dimming of the Sun due to a transit of the Earth. Space-based solar irradiance monitoring has shown that the intrinsic variability of the Sun would not preclude such a detection. Transits of the Sun by the Earth would be detectable by observers that reside within a narrow band of sky positions near the ecliptic plane, if the observers possess current Earth epoch levels of technology and astronomical expertise. A catalog of solar-like stars that satisfy the geometric condition for Earth transit visibility are presented.

  6. The Visibility of Earth Transits

    NASA Technical Reports Server (NTRS)

    Castellano, Tim; DeVincenzi, Donald L. (Technical Monitor)

    2000-01-01

    The recent detection of planetary transits of the solar-like star HD 209458 at a distance of 47 parsecs suggest that transits can reveal the presence of Jupiter-size planetary companions in the solar neighborhood. Recent space-based transit searches have achieved photometric precision within an order of magnitude of that required to detect the much smaller transit signal of an earth-size planet around a solar-size star. Laboratory experiments in the presence of realistic noise sources have shown that CCDs can achieve photometric precision adequate to detect the 9.6 E-5 dimming, of the Sun due to a transit of the Earth. Space-based solar irradiance monitoring has shown that the intrinsic variability of the Sun would not preclude such a detection. Transits of the Sun by the Earth would be detectable by observers that reside within a narrow band of sky positions near the ecliptic plane, if the observers possess current Earth epoch levels of technology and astronomical expertise. A catalog of candidate target stars, their properties, and simulations of the photometric Earth transit signal detectability at each target is presented.

  7. Major evolutionary transitions in individuality

    PubMed Central

    West, Stuart A.; Fisher, Roberta M.; Gardner, Andy; Kiers, E. Toby

    2015-01-01

    The evolution of life on earth has been driven by a small number of major evolutionary transitions. These transitions have been characterized by individuals that could previously replicate independently, cooperating to form a new, more complex life form. For example, archaea and eubacteria formed eukaryotic cells, and cells formed multicellular organisms. However, not all cooperative groups are en route to major transitions. How can we explain why major evolutionary transitions have or haven’t taken place on different branches of the tree of life? We break down major transitions into two steps: the formation of a cooperative group and the transformation of that group into an integrated entity. We show how these steps require cooperation, division of labor, communication, mutual dependence, and negligible within-group conflict. We find that certain ecological conditions and the ways in which groups form have played recurrent roles in driving multiple transitions. In contrast, we find that other factors have played relatively minor roles at many key points, such as within-group kin discrimination and mechanisms to actively repress competition. More generally, by identifying the small number of factors that have driven major transitions, we provide a simpler and more unified description of how life on earth has evolved. PMID:25964342

  8. Fluctuation driven electroweak phase transition

    NASA Technical Reports Server (NTRS)

    Gleiser, Marcelo; Kolb, Edward W.

    1991-01-01

    We examine the dynamics of the electroweak phase transition in the early Universe. For Higgs masses in the range 46 less than or = M sub H less than or = 150 GeV and top quark masses less than 200 GeV, regions of symmetric and asymmetric vacuum coexist to below the critical temperature, with thermal equilibrium between the two phases maintained by fluctuations of both phases. We propose that the transition to the asymmetric vacuum is completed by percolation of these subcritical fluctuations. Our results are relevant to scenarios of baryogenesis that invoke a weakly first-order phase transition at the electroweak scale.

  9. Transition circumnstellar disks in Lupus

    NASA Astrophysics Data System (ADS)

    Romero, G. A.; Schreiber, M. R.; Cieza, L. A.; Rebassa-Manssergas, A.; Williams, J. P.; Merin, B.; Smith-Castelli, A.; Orellana, M.

    2011-10-01

    Based on Spitzer selected YSOs, we present a study of transition disks located in Lupus. Several mechanisms have been proposed to explain their defining characteristic: an inner opacity hole and an optically thick outer disk. These processes are: planet formation, grain growth, photoevaporation, tidal truncation in close binaries. We have carried out Adaptive Optics (AO) imaging, submillimeter photometry, and echelle spectroscopy in order to observationally characterize our transition disk sample. With the analyzed data we can distinguish the four scenarios and identify candidate transition disk systems that are currently forming planets. Such objects are excellent targets to be followed-up with Herschel and ALMA.

  10. Menstruation and the menopausal transition.

    PubMed

    Harlow, Siobán D; Paramsothy, Pangaja

    2011-09-01

    This paper characterizes changes in menstrual bleeding during perimenopause,including bleeding changes that represent markers of the menopausal transition. Recent results from the Study of Women's Health Across the Nation and other cohort studies are reviewed. Emerging data describing subpopulation differences in the transition experience are highlighted. When treating women in the midlife, clinicians should pay careful attention to medical factors, including both conditions and treatments, that may increase menstrual blood loss or alter menstrual cycle characteristics sufficiently to obscure the onset of the menopausal transition or the final menstrual period.

  11. Theory on instability and transition

    NASA Technical Reports Server (NTRS)

    Smith, Frank T.

    1990-01-01

    The fundamental fluid dynamics governing instability and transition to turbulence in boundary layers are considered, and attention is focused on the key aspects of nonlinear dynamics central to the transition process and to turbulent boundary-layer phenomena. Emphasis is placed on truly nonlinear theories, in which the boundary layer mean-flow profile is completely altered from its original form. Nonlinear TS transitions, Euler-stage interactions, and vortex/wave interactions are discussed, and compressible boundary layers are analyzed. Connections with experiments and computations are outlined, along with overall trends including the extension of the nonlinear theory and the advancement in the compressible and other flow regimes.

  12. The 2012 Transit of Venus

    NASA Astrophysics Data System (ADS)

    Deans, P.

    2012-08-01

    On June 5-6, 2012, much of the world will experience an event that will not occur again for another 105 years - a transit of Venus. During the 18th and 19th centuries, astronomers made arduous trips to remote corners of Earth to make Venus transit observations in an attempt to calculate the Earth-Sun distance. Today a transit of Venus is simply a rare spectacle. But it is important to take care when viewing it, because observing the Sun is dangerous if proper filters for eye protection are not used.

  13. Nonradiative transition dynamics in alexandrite

    NASA Technical Reports Server (NTRS)

    Gayen, S. K.; Wang, W. B.; Petricevic, V.; Alfano, R. R.

    1986-01-01

    The first direct picosecond time-resolved measurement of the nonradiative transition dynamics between the excited 4T2 pump band and the metastable 2E storage level of the trivalent chromium ion in alexandrite is reported. The nonradiative relaxation times of 17 ps for intra-4T2 vibrational transitions, and 27 ps for 4T2-2E electronic transition are obtained. The thermal repopulation rate of the 4T2 state from the metastable 2E level is of the order 3.5 x 10 to the 9th per s.

  14. Phase transition in Liouville theory

    SciTech Connect

    Johnston, D. )

    1989-11-15

    We suggest that the vortices arising in a Kosterlitz-Thouless phase transition in Liouville theory correspond to transitions between different genera, producing the plumber's nightmare'' and other phases that have been predicted in fluid membrane theory from energetic considerations. This transition has previously been invoked by Cates to explain the degeneration of numerical simulations of Gaussian random surfaces into branched polymers. The difficulty in quantizing Liouville theory for {ital d}{gt}1 is conjectured to be due to our insistence on working at a fixed genus.

  15. Phase transition in Liouville theory

    NASA Astrophysics Data System (ADS)

    Johnston, D.

    1989-11-01

    We suggest that the vortices arising in a Kosterlitz-Thouless phase transition in Liouville theory correspond to transitions between different genera, producing the ``plumber's nightmare'' and other phases that have been predicted in fluid membrane theory from energetic considerations. This transition has previously been invoked by Cates to explain the degeneration of numerical simulations of Gaussian random surfaces into branched polymers. The difficulty in quantizing Liouville theory for d>1 is conjectured to be due to our insistence on working at a fixed genus.

  16. Empowering Students in Transition

    PubMed Central

    Sullivan, Ann-Catherine

    2016-01-01

    The purpose of this study was to (a) identify potential benefits for students with disabilities taking part in a physical activity program with same-age typical peers on a Midwest university campus and (b) to determine if the program impacted the students with disabilities empowerment. Empowerment theory was used to determine how transition students’ attitudes change over the course of the semester while participating in a workout buddy program with same-age college peers. The program was structured to provide a sense of empowerment to students to make their own decisions and learn for themselves so they do not feel a lack of power in their lives. This study implemented elements of a quantitative design but a majority utilized a qualitative design based on the assumptions of the Interpretivist paradigm. The quantitative design elements focused on the analysis of two questionnaires: Sports Questionnaire and the Perceived Control Scale Questionnaire. The analysis of the focus group data revealed the following themes as positive effects of the intervention: positive effect on empowerment, how happy the program made the students, what benefits the students gained from the program, the student’s familiarity with university students, and the environment, and, lastly, the students ability to ask for assistance when need. Findings from the study determined that the empowerment of the students with disabilities was impacted while participating in the program. In general, the findings of gaining empowerment were similar to previous studies in that students with disabilities are able to gain empowerment from participation in fitness and recreation programs. The researcher noted during focus groups that some of the Best of Both Worlds (BOBW) students were not confident in starting conversations with their university peers. Although the BOBW students felt a sense of losing empowerment with this specific instance, there was an overall positive impact on the BOBW students

  17. Immigration and adult transitions.

    PubMed

    Rumbaut, Rubén G; Komaie, Golnaz

    2010-01-01

    Almost 30 percent of the more than 68 million young adults aged eighteen to thirty-four in the United States today are either foreign born or of foreign parentage. As these newcomers make their transitions to adulthood, say Rubén Rumbaut and Golnaz Komaie, they differ significantly not only from one another but also from their native-parentage counterparts, including blacks and whites. The authors document the demographic changes in the United States over the past forty years and describe the ways in which generation and national origin shape the experiences of these newcomers as they become adults. Rumbaut and Komaie point out that immigrant groups experience gaps in social, economic, and legal status that are even greater than the gaps between native whites and blacks. By far the most-educated (Indians) and the least-educated (Mexicans) groups in the United States today are first-generation immigrants, as are the groups with the lowest poverty rate (Filipinos) and the highest poverty rate (Dominicans). These social and economic divides reflect three very different ways immigrants enter the country: through regular immigration channels, without legal authorization, or as state-sponsored refugees. For many ethnic groups, significant progress takes place from the first to the second generation. But, say the authors, for millions of young immigrants, a lack of legal permanent residency status blocks their prospects for social mobility. Having an undocumented status has become all the more consequential with the failure of Congress to pass comprehensive federal immigration reforms. In the coming two decades, as the U.S. native-parentage labor force continues to shrink, immigrants and their children are expected to account for most of the growth of the nation's labor force, with the fastest-growing occupations requiring college degrees. Rumbaut and Komaie stress that one key to the nation's future will be how it incorporates young adults of immigrant origin in its

  18. Empowering Students in Transition.

    PubMed

    Sullivan, Ann-Catherine

    2016-01-01

    The purpose of this study was to (a) identify potential benefits for students with disabilities taking part in a physical activity program with same-age typical peers on a Midwest university campus and (b) to determine if the program impacted the students with disabilities empowerment. Empowerment theory was used to determine how transition students' attitudes change over the course of the semester while participating in a workout buddy program with same-age college peers. The program was structured to provide a sense of empowerment to students to make their own decisions and learn for themselves so they do not feel a lack of power in their lives. This study implemented elements of a quantitative design but a majority utilized a qualitative design based on the assumptions of the Interpretivist paradigm. The quantitative design elements focused on the analysis of two questionnaires: Sports Questionnaire and the Perceived Control Scale Questionnaire. The analysis of the focus group data revealed the following themes as positive effects of the intervention: positive effect on empowerment, how happy the program made the students, what benefits the students gained from the program, the student's familiarity with university students, and the environment, and, lastly, the students ability to ask for assistance when need. Findings from the study determined that the empowerment of the students with disabilities was impacted while participating in the program. In general, the findings of gaining empowerment were similar to previous studies in that students with disabilities are able to gain empowerment from participation in fitness and recreation programs. The researcher noted during focus groups that some of the Best of Both Worlds (BOBW) students were not confident in starting conversations with their university peers. Although the BOBW students felt a sense of losing empowerment with this specific instance, there was an overall positive impact on the BOBW students

  19. Hybrid percolation transition in complex networks

    NASA Astrophysics Data System (ADS)

    Kahng, Byungnam

    Percolation has been one of the most applied statistical models. Percolation transition is one of the most robust continuous transitions known thus far. However, recent extensive researches reveal that it exhibits diverse types of phase transitions such as discontinuous and hybrid phase transitions. Here hybrid phase transition means the phase transition exhibiting natures of both continuous and discontinuous phase transitions simultaneously. Examples include k-core percolation, cascading failures in interdependent networks, synchronization, etc. Thus far, it is not manifest if the critical behavior of hybrid percolation transitions conforms to the conventional scaling laws of second-order phase transition. Here, we investigate the critical behaviors of hybrid percolation transitions in the cascading failure model in inter-dependent networks and the restricted Erdos-Renyi model. We find that the critical behaviors of the hybrid percolation transitions contain some features that cannot be described by the conventional theory of second-order percolation transitions.

  20. ISS Update: Transit of Venus

    NASA Video Gallery

    ISS Update commentator Brandi Dean interviews Mario Runco, NASA astronaut, about Venus's transit across the sun on June 5, 2012. Questions? Ask us on Twitter @NASA_Johnson and include the hashtag #...

  1. Magnetic fields from phase transitions

    NASA Astrophysics Data System (ADS)

    Hindmarsh, Mark; Everett, Allen

    1998-11-01

    The generation of primordial magnetic fields from cosmological phase transitions is discussed, paying particular attention to the electroweak transition and to the various definitions of the ``average'' field that have been put forward. It is emphasized that only the volume average has dynamical significance as a seed for galactic dynamos. On rather general grounds of causality and energy conservation, it is shown that, in the absence of MHD effects that transfer power in the magnetic field from small to large scales, processes occurring at the electroweak transition cannot generate fields stronger than 10-20 G on a scale of 0.5 Mpc. However, it is implausible that this upper bound could ever be reached, as it would require all the energy in the Universe to be turned into a magnetic field coherent at the horizon scale. Non-linear MHD effects seem therefore to be necessary if the electroweak transition is to create a primordial seed field.

  2. Moved by a Rapid Transit

    NASA Astrophysics Data System (ADS)

    Bueter, C.

    2013-04-01

    Enticing by virtue of its predictability, historical utility, and spectacle, the transit of Venus is a niche event among astronomical phenomena. Though the value of a transit for scientific purposes is now diminished, the brief appearance of Venus silhouetted against the background of the Sun in 2004 moved the artistic community to celebrate the rare alignment. Artists of all ages combined old traditions with fresh technology to create a 21st-century tapestry of music, sculpture, paintings, glasswork, quilts, sky shows, and digital imagery. A full catalog of transit-related art generated over the centuries would feature the sampling of entries presented here and at the Moved by a Rapid Transit website.

  3. Phase Transitions in Brownian Pumps

    NASA Astrophysics Data System (ADS)

    Dierl, Marcel; Dieterich, Wolfgang; Einax, Mario; Maass, Philipp

    2014-04-01

    We study stochastic particle transport between two reservoirs along a channel, where the particles are pumped against a bias by a traveling wave potential. It is shown that phase transitions of period-averaged densities or currents occur inside the channel when exclusion interactions between the particles are taken into account. These transitions reflect those known for the asymmetric simple exclusion process. We argue that their occurrence is a generic feature of Brownian motors operating in open systems.

  4. Universal Keplerian state transition matrix

    NASA Technical Reports Server (NTRS)

    Shepperd, S. W.

    1985-01-01

    A completely general method for computing the Keplerian state transition matrix in terms of Goodyear's universal variables is presented. This includes a new scheme for solving Kepler's problem which is a necessary first step to computing the transition matrix. The Kepler problem is solved in terms of a new independent variable requiring the evaluation of only one transcendental function. Furthermore, this transcendental function may be conveniently evaluated by means of a Gaussian continued fraction.

  5. Boundary layer transition studies

    NASA Technical Reports Server (NTRS)

    Watmuff, Jonathan H.

    1995-01-01

    A small-scale wind tunnel previously used for turbulent boundary layer experiments was modified for two sets of boundary layer transition studies. The first study concerns a laminar separation/turbulent reattachment. The pressure gradient and unit Reynolds number are the same as the fully turbulent flow of Spalart and Watmuff. Without the trip wire, a laminar layer asymptotes to a Falkner & Skan similarity solution in the FPG. Application of the APG causes the layer to separate and a highly turbulent and approximately 2D mean flow reattachment occurs downstream. In an effort to gain some physical insight into the flow processes a small impulsive disturbance was introduced at the C(sub p) minimum. The facility is totally automated and phase-averaged data are measured on a point-by-point basis using unprecedently large grids. The evolution of the disturbance has been tracked all the way into the reattachment region and beyond into the fully turbulent boundary layer. At first, the amplitude decays exponentially with streamwise distance in the APG region, where the layer remains attached, i.e. the layer is viscously stable. After separation, the rate of decay slows, and a point of minimum amplitude is reached where the contours of the wave packet exhibit dispersive characteristics. From this point, exponential growth of the amplitude of the disturbance is observed in the detached shear layer, i.e. the dominant instability mechanism is inviscid. A group of large-scale 3D vortex loops emerges in the vicinity of the reattachment. Remarkably, the second loop retains its identify far downstream in the turbulent boundary layer. The results provide a level of detail usually associated with CFD. Substantial modifications were made to the facility for the second study concerning disturbances generated by Suction Holes for laminar flow Control (LFC). The test section incorporates suction through interchangeable porous test surfaces. Detailed studies have been made using isolated

  6. Boundary layer transition studies

    NASA Astrophysics Data System (ADS)

    Watmuff, Jonathan H.

    1995-02-01

    A small-scale wind tunnel previously used for turbulent boundary layer experiments was modified for two sets of boundary layer transition studies. The first study concerns a laminar separation/turbulent reattachment. The pressure gradient and unit Reynolds number are the same as the fully turbulent flow of Spalart and Watmuff. Without the trip wire, a laminar layer asymptotes to a Falkner & Skan similarity solution in the FPG. Application of the APG causes the layer to separate and a highly turbulent and approximately 2D mean flow reattachment occurs downstream. In an effort to gain some physical insight into the flow processes a small impulsive disturbance was introduced at the C(sub p) minimum. The facility is totally automated and phase-averaged data are measured on a point-by-point basis using unprecedently large grids. The evolution of the disturbance has been tracked all the way into the reattachment region and beyond into the fully turbulent boundary layer. At first, the amplitude decays exponentially with streamwise distance in the APG region, where the layer remains attached, i.e. the layer is viscously stable. After separation, the rate of decay slows, and a point of minimum amplitude is reached where the contours of the wave packet exhibit dispersive characteristics. From this point, exponential growth of the amplitude of the disturbance is observed in the detached shear layer, i.e. the dominant instability mechanism is inviscid. A group of large-scale 3D vortex loops emerges in the vicinity of the reattachment. Remarkably, the second loop retains its identify far downstream in the turbulent boundary layer. The results provide a level of detail usually associated with CFD. Substantial modifications were made to the facility for the second study concerning disturbances generated by Suction Holes for laminar flow Control (LFC). The test section incorporates suction through interchangeable porous test surfaces. Detailed studies have been made using isolated

  7. Transition boiling heat transfer and the film transition regime

    NASA Technical Reports Server (NTRS)

    Ramilison, J. M.; Lienhard, J. H.

    1987-01-01

    The Berenson (1960) flat-plate transition-boiling experiment has been recreated with a reduced thermal resistance in the heater, and an improved access to those portions of the transition boiling regime that have a steep negative slope. Tests have been made in Freon-113, acetone, benzene, and n-pentane boiling on horizontal flat copper heaters that have been mirror-polished, 'roughened', or teflon-coated. The resulting data reproduce and clarify certain features observed by Berenson: the modest surface finish dependence of boiling burnout, and the influence of surface chemistry on both the minimum heat flux and the mode of transition boiling, for example. A rational scheme of correlation yields a prediction of the heat flux in what Witte and Lienhard (1982) previously identified as the 'film-transition boiling' region. It is also shown how to calculate the heat flux at the boundary between the pure-film, and the film-transition, boiling regimes, as a function of the advancing contact angle.

  8. Scanning tunnelling microscopy of charge-density waves in transition metal chalcogenides

    NASA Astrophysics Data System (ADS)

    Coleman, R. V.; Giambattista, B.; Hansma, P. K.; Johnson, A.; McNairy, W. W.; Slough, C. G.

    1988-11-01

    We have used scanning tunnelling microscopes (STMs) operating at liquid helium and liquid nitrogen temperatures to image the charge-density waves (CDWs) in transition metal chalcogenides. The layer structure dichalcogenides TaSe2, TaS2, NbSe2, VSe2, TiSe2 and TiS2 have been studied including representative polytype phases such as 1T, 2H and 4Hb. Experimental results are presented for the complete range of CDW amplitudes and structures observed in these materials. In most cases both the CDW and the surface atomic structure have been simultaneously imaged. Results on the trichalcogenide NbSe3 are also included.The formation of the CDW along with the associated periodic lattice distortion gaps the Fermi surface (FS) and modifies the local density-of-states (LDOS) detected by the tunnelling process. The tunnelling microscopes have been operated mostly in the constant current mode which maps the LDOS at the position of the tunnelling tip. The relative amplitudes and profiles of the CDW superlattice and the atomic lattice have been measured and confirm on an atomic scale the CDW structures predicted by X-ray, electron and neutron diffraction. The absolute STM deflections are larger than expected for the CDW induced modifications of the LDOS above the surface and possible enhancement mechanisms are reviewed.In the 2H trigonal prismatic coordination phases the CDWs involve a relatively small charge transfer and the atomic structure dominates the STM images. In the 1T octahedral coordination phases the charge transfer is large and the CDW structure dominates the STM image with an anomalously large enhancement of the STM profile. Systematic comparison of the STM profiles with band structure and FS information is included.In the case of the 4Hb mixed coordination phases at the lowest temperatures two nearly independent CDWs form in alternate sandwiches. STM studies on 4Hb crystals with both octahedral and trigonal prismatic surface sandwiches have been carried out. The STM

  9. GATE (Gaia Transiting Exoplanets): Detecting Transiting Exoplanets with Gaia

    NASA Astrophysics Data System (ADS)

    Zucker, Shay; Eyer, Laurent; Hodgkin, Simon; Clementini, Gisella

    2016-10-01

    Gaia will have a revolutionary impact on most fields of astronomy. However, its scanning law is too sparse for traditional transit detection approaches (de Bruijne 2012). Practically, only stars brighter than 16th magnitude are relevant for follow-up of transiting exoplanets. For those stars, Gaia's precision is of the order of 1 mmag (Eyer et al. 2015). On average, Gaia will have sampled each target 70 times, but certain stars may be observed as many as 200 times (Voss et al. 2013). Hipparcos scanning law was similar, but its precision much worse. Nevertheless the transit of HD209458 could be seen, aposteriori, in Hipparcos' data (Söderhelm 1999). This inspired our GATE initiative.

  10. Electronic Transitions of Ruthenium Monoxide

    NASA Astrophysics Data System (ADS)

    Wang, Na; Ng, Y. W.; Cheung, A. S.-C.

    2013-06-01

    The electronic transition spectrum of ruthenium monoxide (RuO) molecule in the spectral region between 545nm to 640nm has been recorded and analyzed using laser ablation/reaction free-jet expansion and laser induced fluorescence spectroscopy. The RuO molecule was produced by reacting laser- ablated ruthenium atoms with N_{2}O seeded in argon. Nine vibrational bands were recorded and they are identified to be belonging to four electronic transition systems, namely the [18.1]Ω = 4 - X^{5} Δ_4 transition, [16.0]^{5} Φ_5 - X^{5} Δ_4 transition, [18.1]Ω = 3 - X^{5} Δ_3, and [15.8] ^{5} Φ_4 - X^{5} Δ_3 transition. RuO has been determined to have a X^{5} Δ_4 ground state. A least squares fit of the measured rotational lines yielded molecular constants for the ground and the low-lying electronic states. A molecular orbital energy level diagram has been used to help with the assignment of the observed electronic states.

  11. Observation of optomechanical buckling transitions

    PubMed Central

    Xu, H.; Kemiktarak, U.; Fan, J.; Ragole, S.; Lawall, J.; Taylor, J. M.

    2017-01-01

    Correlated phases of matter provide long-term stability for systems as diverse as solids, magnets and potential exotic quantum materials. Mechanical systems, such as buckling transition spring switches, can have engineered, stable configurations whose dependence on a control variable is reminiscent of non-equilibrium phase transitions. In hybrid optomechanical systems, light and matter are strongly coupled, allowing engineering of rapid changes in the force landscape, storing and processing information, and ultimately probing and controlling behaviour at the quantum level. Here we report the observation of first- and second-order buckling transitions between stable mechanical states in an optomechanical system, in which full control of the nature of the transition is obtained by means of the laser power and detuning. The underlying multiwell confining potential we create is highly tunable, with a sub-nanometre distance between potential wells. Our results enable new applications in photonics and information technology, and may enable explorations of quantum phase transitions and macroscopic quantum tunnelling in mechanical systems. PMID:28248293

  12. Electromechanical transition in quantum dots

    NASA Astrophysics Data System (ADS)

    Micchi, G.; Avriller, R.; Pistolesi, F.

    2016-09-01

    The strong coupling between electronic transport in a single-level quantum dot and a capacitively coupled nanomechanical oscillator may lead to a transition towards a mechanically bistable and blocked-current state. Its observation is at reach in carbon-nanotube state-of-art experiments. In a recent publication [Phys. Rev. Lett. 115, 206802 (2015), 10.1103/PhysRevLett.115.206802] we have shown that this transition is characterized by pronounced signatures on the oscillator mechanical properties: the susceptibility, the displacement fluctuation spectrum, and the ring-down time. These properties are extracted from transport measurements, however the relation between the mechanical quantities and the electronic signal is not always straightforward. Moreover the dependence of the same quantities on temperature, bias or gate voltage, and external dissipation has not been studied. The purpose of this paper is to fill this gap and provide a detailed description of the transition. Specifically we find (i) the relation between the current-noise and the displacement spectrum; (ii) the peculiar behavior of the gate-voltage dependence of these spectra at the transition; (iii) the robustness of the transition towards the effect of external fluctuations and dissipation.

  13. Observation of optomechanical buckling transitions

    NASA Astrophysics Data System (ADS)

    Xu, H.; Kemiktarak, U.; Fan, J.; Ragole, S.; Lawall, J.; Taylor, J. M.

    2017-03-01

    Correlated phases of matter provide long-term stability for systems as diverse as solids, magnets and potential exotic quantum materials. Mechanical systems, such as buckling transition spring switches, can have engineered, stable configurations whose dependence on a control variable is reminiscent of non-equilibrium phase transitions. In hybrid optomechanical systems, light and matter are strongly coupled, allowing engineering of rapid changes in the force landscape, storing and processing information, and ultimately probing and controlling behaviour at the quantum level. Here we report the observation of first- and second-order buckling transitions between stable mechanical states in an optomechanical system, in which full control of the nature of the transition is obtained by means of the laser power and detuning. The underlying multiwell confining potential we create is highly tunable, with a sub-nanometre distance between potential wells. Our results enable new applications in photonics and information technology, and may enable explorations of quantum phase transitions and macroscopic quantum tunnelling in mechanical systems.

  14. Simulation methods for looping transitions.

    PubMed

    Gaffney, B J; Silverstone, H J

    1998-09-01

    Looping transitions occur in field-swept electron magnetic resonance spectra near avoided crossings and involve a single pair of energy levels that are in resonance at two magnetic field strengths, before and after the avoided crossing. When the distance between the two resonances approaches a linewidth, the usual simulation of the spectra, which results from a linear approximation of the dependence of the transition frequency on magnetic field, breaks down. A cubic approximation to the transition frequency, which can be obtained from the two resonance fields and the field-derivatives of the transition frequencies, along with linear (or better) interpolation of the transition-probability factor, restores accurate simulation. The difference is crucial for accurate line shapes at fixed angles, as in an oriented single crystal, but the difference turns out to be a smaller change in relative intensity for a powder spectrum. Spin-3/2 Cr3+ in ruby and spin-5/2 Fe3+ in transferrin oxalate are treated as examples.

  15. Major transitions in human evolution

    PubMed Central

    Foley, Robert A.; Martin, Lawrence; Mirazón Lahr, Marta; Stringer, Chris

    2016-01-01

    Evolutionary problems are often considered in terms of ‘origins', and research in human evolution seen as a search for human origins. However, evolution, including human evolution, is a process of transitions from one state to another, and so questions are best put in terms of understanding the nature of those transitions. This paper discusses how the contributions to the themed issue ‘Major transitions in human evolution’ throw light on the pattern of change in hominin evolution. Four questions are addressed: (1) Is there a major divide between early (australopithecine) and later (Homo) evolution? (2) Does the pattern of change fit a model of short transformations, or gradual evolution? (3) Why is the role of Africa so prominent? (4) How are different aspects of adaptation—genes, phenotypes and behaviour—integrated across the transitions? The importance of developing technologies and approaches and the enduring role of fieldwork are emphasized. This article is part of the themed issue ‘Major transitions in human evolution’. PMID:27298461

  16. Observation of optomechanical buckling transitions.

    PubMed

    Xu, H; Kemiktarak, U; Fan, J; Ragole, S; Lawall, J; Taylor, J M

    2017-03-01

    Correlated phases of matter provide long-term stability for systems as diverse as solids, magnets and potential exotic quantum materials. Mechanical systems, such as buckling transition spring switches, can have engineered, stable configurations whose dependence on a control variable is reminiscent of non-equilibrium phase transitions. In hybrid optomechanical systems, light and matter are strongly coupled, allowing engineering of rapid changes in the force landscape, storing and processing information, and ultimately probing and controlling behaviour at the quantum level. Here we report the observation of first- and second-order buckling transitions between stable mechanical states in an optomechanical system, in which full control of the nature of the transition is obtained by means of the laser power and detuning. The underlying multiwell confining potential we create is highly tunable, with a sub-nanometre distance between potential wells. Our results enable new applications in photonics and information technology, and may enable explorations of quantum phase transitions and macroscopic quantum tunnelling in mechanical systems.

  17. Phonon Analysis in Multiphonon Transitions

    NASA Astrophysics Data System (ADS)

    Huang, Kun; Gu, Zongquan

    In the investigation of multiphonon transitions, single-mode or single-frequency models are widely used. In view of the fact that such oversimplified models can be seriously inadequate, the present work bridges the gap between the complexity of the general formal theory and the simplicity required for concrete applications by introducing the concept of multi-frequency models. That is, the theory is so formulated that a general system can be approximated by multi-frequency models of any degree of elaboration. A statistical thermodynamic formalism is developed for treating such multi-frequency models, which, on the one hand, greatly reduces the labour of calculation with such models and, on the other hand, leads directly to a simple statistical distribution law for numbers of phonons of each frequency participating in a multiphonon transition. Applications of the theory to concrete models lead to certain general conclusions on frequency dispersion effects in multiphonon transitions. The use of the theory is further demonstrated by fully accounting for the paradoxical experimental results reported by Jia and Yen that the isotopic substitution of H by D in CsMn Cl3· 2H2O reduces the multiphonon nonradiative transition probability of excited Mn2+ ion by more than ten-fold, and yet leaves the corresponding luminescence phonon sideband little changed. In the last section of the paper, the relation between the statistical thermodynamic formalism and existing multiphonon transition theory is elucidated, thereby the theoretical basis of the statistical formalism becomes clearly defined.

  18. The major synthetic evolutionary transitions

    PubMed Central

    Solé, Ricard

    2016-01-01

    Evolution is marked by well-defined events involving profound innovations that are known as ‘major evolutionary transitions'. They involve the integration of autonomous elements into a new, higher-level organization whereby the former isolated units interact in novel ways, losing their original autonomy. All major transitions, which include the origin of life, cells, multicellular systems, societies or language (among other examples), took place millions of years ago. Are these transitions unique, rare events? Have they instead universal traits that make them almost inevitable when the right pieces are in place? Are there general laws of evolutionary innovation? In order to approach this problem under a novel perspective, we argue that a parallel class of evolutionary transitions can be explored involving the use of artificial evolutionary experiments where alternative paths to innovation can be explored. These ‘synthetic’ transitions include, for example, the artificial evolution of multicellular systems or the emergence of language in evolved communicating robots. These alternative scenarios could help us to understand the underlying laws that predate the rise of major innovations and the possibility for general laws of evolved complexity. Several key examples and theoretical approaches are summarized and future challenges are outlined. This article is part of the themed issue ‘The major synthetic evolutionary transitions’. PMID:27431528

  19. 33 CFR 401.74 - Transit declaration.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 33 Navigation and Navigable Waters 3 2013-07-01 2013-07-01 false Transit declaration. 401.74... Transit declaration. (a) Seaway Transit Declaration Form (Cargo and Passenger) shall be forwarded to the... ships, within fourteen days after the vessel enters the Seaway on any upbound or downbound transit....

  20. 33 CFR 401.74 - Transit declaration.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 33 Navigation and Navigable Waters 3 2014-07-01 2014-07-01 false Transit declaration. 401.74... Transit declaration. (a) A Seaway Transit Declaration Form (Cargo and Passenger) shall be forwarded to the... bound transit. The form may be obtained from the St. Lawrence Management Corporation, 151 Ecluse...

  1. 33 CFR 401.74 - Transit declaration.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 33 Navigation and Navigable Waters 3 2012-07-01 2012-07-01 false Transit declaration. 401.74... Transit declaration. (a) Seaway Transit Declaration Form (Cargo and Passenger) shall be forwarded to the... ships, within fourteen days after the vessel enters the Seaway on any upbound or downbound transit....

  2. 33 CFR 401.74 - Transit declaration.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 33 Navigation and Navigable Waters 3 2010-07-01 2010-07-01 false Transit declaration. 401.74... Transit declaration. (a) Seaway Transit Declaration Form (Cargo and Passenger) shall be forwarded to the... ships, within fourteen days after the vessel enters the Seaway on any upbound or downbound transit....

  3. 33 CFR 401.74 - Transit declaration.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 33 Navigation and Navigable Waters 3 2011-07-01 2011-07-01 false Transit declaration. 401.74... Transit declaration. (a) Seaway Transit Declaration Form (Cargo and Passenger) shall be forwarded to the... ships, within fourteen days after the vessel enters the Seaway on any upbound or downbound transit....

  4. Individualized Transition Plans (ITP): A National Perspective.

    ERIC Educational Resources Information Center

    Repetto, Jeanne B.; And Others

    1990-01-01

    Information concerning implementation of Individualized Transition Plans (ITP) was collected from 46 states and analyzed to determine documentation used in transition planning, relationship between the ITP and Individualized Education Programs, age for beginning transition planning, individuals involved in transition planning, and issues addressed…

  5. 10 CFR 5.230 - Transition plans.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 10 Energy 1 2010-01-01 2010-01-01 false Transition plans. 5.230 Section 5.230 Energy NUCLEAR... FEDERAL FINANCIAL ASSISTANCE Coverage § 5.230 Transition plans. (a) Submission of plans. An institution to... either a single transition plan applicable to all such units, or a separate transition plan applicable...

  6. 29 CFR 36.230 - Transition plans.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 29 Labor 1 2010-07-01 2010-07-01 true Transition plans. 36.230 Section 36.230 Labor Office of the... FEDERAL FINANCIAL ASSISTANCE Coverage § 36.230 Transition plans. (a) Submission of plans. An institution... submit either a single transition plan applicable to all such units, or a separate transition...

  7. 18 CFR 1317.230 - Transition plans.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 18 Conservation of Power and Water Resources 2 2010-04-01 2010-04-01 false Transition plans. 1317... Coverage § 1317.230 Transition plans. (a) Submission of plans. An institution to which § 1317.225 applies... transition plan applicable to all such units, or a separate transition plan applicable to each such unit....

  8. 7 CFR 15a.18 - Transition plans.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 7 Agriculture 1 2014-01-01 2014-01-01 false Transition plans. 15a.18 Section 15a.18 Agriculture... FEDERAL FINANCIAL ASSISTANCE Coverage § 15a.18 Transition plans. (a) Submission of plans. An institution... submit either a single transition plan applicable to all such units, or a separate transition...

  9. 10 CFR 5.230 - Transition plans.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 10 Energy 1 2014-01-01 2014-01-01 false Transition plans. 5.230 Section 5.230 Energy NUCLEAR... FEDERAL FINANCIAL ASSISTANCE Coverage § 5.230 Transition plans. (a) Submission of plans. An institution to... either a single transition plan applicable to all such units, or a separate transition plan applicable...

  10. 36 CFR 1211.230 - Transition plans.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 36 Parks, Forests, and Public Property 3 2012-07-01 2012-07-01 false Transition plans. 1211.230... FINANCIAL ASSISTANCE Coverage § 1211.230 Transition plans. (a) Submission of plans. An institution to which... a single transition plan applicable to all such units, or a separate transition plan applicable...

  11. 7 CFR 15a.18 - Transition plans.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 7 Agriculture 1 2013-01-01 2013-01-01 false Transition plans. 15a.18 Section 15a.18 Agriculture... FEDERAL FINANCIAL ASSISTANCE Coverage § 15a.18 Transition plans. (a) Submission of plans. An institution... submit either a single transition plan applicable to all such units, or a separate transition...

  12. 44 CFR 19.230 - Transition plans.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 44 Emergency Management and Assistance 1 2012-10-01 2011-10-01 true Transition plans. 19.230... RECEIVING FEDERAL FINANCIAL ASSISTANCE Coverage § 19.230 Transition plans. (a) Submission of plans. An... submit either a single transition plan applicable to all such units, or a separate transition...

  13. 10 CFR 5.230 - Transition plans.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 10 Energy 1 2012-01-01 2012-01-01 false Transition plans. 5.230 Section 5.230 Energy NUCLEAR... FEDERAL FINANCIAL ASSISTANCE Coverage § 5.230 Transition plans. (a) Submission of plans. An institution to... either a single transition plan applicable to all such units, or a separate transition plan applicable...

  14. 45 CFR 2555.230 - Transition plans.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 45 Public Welfare 4 2012-10-01 2012-10-01 false Transition plans. 2555.230 Section 2555.230 Public... Coverage § 2555.230 Transition plans. (a) Submission of plans. An institution to which § 2555.225 applies... transition plan applicable to all such units, or a separate transition plan applicable to each such unit....

  15. 29 CFR 36.230 - Transition plans.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 29 Labor 1 2014-07-01 2013-07-01 true Transition plans. 36.230 Section 36.230 Labor Office of the... FEDERAL FINANCIAL ASSISTANCE Coverage § 36.230 Transition plans. (a) Submission of plans. An institution... submit either a single transition plan applicable to all such units, or a separate transition...

  16. 7 CFR 15a.18 - Transition plans.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 7 Agriculture 1 2012-01-01 2012-01-01 false Transition plans. 15a.18 Section 15a.18 Agriculture... FEDERAL FINANCIAL ASSISTANCE Coverage § 15a.18 Transition plans. (a) Submission of plans. An institution... submit either a single transition plan applicable to all such units, or a separate transition...

  17. 32 CFR 196.230 - Transition plans.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 32 National Defense 2 2012-07-01 2012-07-01 false Transition plans. 196.230 Section 196.230... FINANCIAL ASSISTANCE Coverage § 196.230 Transition plans. (a) Submission of plans. An institution to which... a single transition plan applicable to all such units, or a separate transition plan applicable...

  18. 32 CFR 196.230 - Transition plans.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 32 National Defense 2 2013-07-01 2013-07-01 false Transition plans. 196.230 Section 196.230... FINANCIAL ASSISTANCE Coverage § 196.230 Transition plans. (a) Submission of plans. An institution to which... a single transition plan applicable to all such units, or a separate transition plan applicable...

  19. 36 CFR 1211.230 - Transition plans.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 36 Parks, Forests, and Public Property 3 2011-07-01 2011-07-01 false Transition plans. 1211.230... FINANCIAL ASSISTANCE Coverage § 1211.230 Transition plans. (a) Submission of plans. An institution to which... a single transition plan applicable to all such units, or a separate transition plan applicable...

  20. 32 CFR 196.230 - Transition plans.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 32 National Defense 2 2011-07-01 2011-07-01 false Transition plans. 196.230 Section 196.230... FINANCIAL ASSISTANCE Coverage § 196.230 Transition plans. (a) Submission of plans. An institution to which... a single transition plan applicable to all such units, or a separate transition plan applicable...

  1. 10 CFR 5.230 - Transition plans.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 10 Energy 1 2011-01-01 2011-01-01 false Transition plans. 5.230 Section 5.230 Energy NUCLEAR... FEDERAL FINANCIAL ASSISTANCE Coverage § 5.230 Transition plans. (a) Submission of plans. An institution to... either a single transition plan applicable to all such units, or a separate transition plan applicable...

  2. 7 CFR 15a.18 - Transition plans.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 7 Agriculture 1 2011-01-01 2011-01-01 false Transition plans. 15a.18 Section 15a.18 Agriculture... FEDERAL FINANCIAL ASSISTANCE Coverage § 15a.18 Transition plans. (a) Submission of plans. An institution... submit either a single transition plan applicable to all such units, or a separate transition...

  3. Sliding Over a Phase Transition

    NASA Astrophysics Data System (ADS)

    Tosatti, Erio; Benassi, Andrea; Vanossi, Andrea; Santoro, Giuseppe E.

    2011-03-01

    The frictional response experienced by a stick-slip slider when a phase transition occurs in the underlying solid substrate is a potentially exciting, poorly explored problem. We show, based on 2-dimensional simulations modeling the sliding of a nanotip, that indeed friction may be heavily affected by a continuous structural transition. First, friction turns nonmonotonic as temperature crosses the transition, peaking at the critical temperature Tc where fluctuations are strongest. Second, below Tc friction depends upon order parameter directions, and is much larger for those where the frictional slip can cause a local flip. This may open a route towards control of atomic scale friction by switching the order parameter direction by an external field or strain, with possible application to e.g., displacive ferroelectrics such as BaTi O3 , as well as ferro- and antiferro-distortive materials. Supported by project ESF FANAS/AFRI sponsored by the Italian Research Council (CNR).

  4. Electronic transitions of iridium monophosphide

    NASA Astrophysics Data System (ADS)

    Yang, M.; Chan, Man-Chor; Cheung, A. S.-C.

    2016-05-01

    Laser induced fluorescence spectrum of IrP in the near infrared spectral region between 720 and 820 nm has been recorded and analyzed. Six vibrational bands with resolved rotational structure for both 191IrP and 193IrP were analyzed, they have been grouped into three new electronic transitions: the [13.6] Ω = 2 - a3Π2, the [12.3]1Π1-X1Σ+, and the [12.7]1Π1-X1Σ+ transitions. Ab initio calculation results were used to aid the assignment of the observed transitions. A new triplet state has been observed for the first time. The observed electronic states of IrP are compared with those of the isovalent IrN molecule.

  5. Alternative approaches to fertility transition.

    PubMed

    Micheli, G A

    1995-01-01

    "Using anomalies of the Italian case as the basis, the aim of this article is to verify how the theoretical framework [of demographic transition] put forward by Lesthaeghe can be interpreted.... While the changes in mores in the Italy of the economic boom were a component of the large-scale processes of secularization, rationalization and modernization specific to the [first demographic transition], the practices, values and models of the collective imagination characterizing the second phase of Lesthaeghe's [second demographic transition] are marked by a state of mind that cannot be put down to the 'spirit of the age' during the years of large-scale modernization, but to the emancipatory and 'rational' falling away of many of the barriers to the unfolding of individual life destiny over and above that based on class, gender and age."

  6. Transition metals in superheat melts

    NASA Technical Reports Server (NTRS)

    Jakes, Petr; Wolfbauer, Michael-Patrick

    1993-01-01

    A series of experiments with silicate melts doped with transition element oxides was carried out at atmospheric pressures of inert gas at temperatures exceeding liquidus. As predicted from the shape of fO2 buffer curves in T-fO2 diagrams the reducing conditions for a particular oxide-metal pair can be achieved through the T increase if the released oxygen is continuously removed. Experimental studies suggest that transition metals such as Cr or V behave as siderophile elements at temperatures exceeding liquidus temperatures if the system is not buffered by the presence of other oxide of more siderophile element. For example the presence of FeO prevents the reduction of Cr2O3. The sequence of decreasing siderophility of transition elements at superheat conditions (Mo, Ni, Fe, Cr) matches the decreasing degree of depletion of siderophile elements in mantle rocks as compared to chondrites.

  7. Reactivity of transition metal solvates

    NASA Astrophysics Data System (ADS)

    Berezin, Boris D.

    1991-09-01

    Reactivity data are generalised for one of the most important classes of complexes, solvates, which are quantitatively nearly unstudied. Various approaches to studying and describing the reactivity are compared with respect to solvation of the reagents and the transition state. The specifics and mechanism of ligand substitution in pure and mixed organic solvents are found. The reactivity of simple (homoleptic) and mixed solvates toward macrocycles is examined in detail using porphyrins as an example. The kinetic method of indicator reactions is applied to porphyrins in order to study the state of transition metal salts in organic solvents and the stability of the coordination spheres of acidosalts (MXnn-2), acidosolvates (MX2Sn-2) and their transition states. The concentration dependence of the rate constant of an indicator reaction is demonstrated to be due to a change in the inner coordination sphere and a shift of equilibria between the various coordination complexes. The bibliography includes 38 references.

  8. Presidential Transition Teams: Fostering a Collaborative Transition Process

    ERIC Educational Resources Information Center

    Artman, Richard B.; Franz, Mark

    2009-01-01

    Whether hiring a sitting president or one beginning a first presidency, the board of trustees should be keenly interested in ensuring that the new president's first months in office flow as smoothly as possible. Increasing attention has been paid in recent years to the idea of using a transition team to assist the new president. Using a transition…

  9. Wetting transition on patterned surfaces: transition states and energy barriers.

    PubMed

    Ren, Weiqing

    2014-03-18

    We study the wetting transition on microstructured hydrophobic surfaces. We use the string method [J. Chem. Phys. 2007, 126, 164103; J. Chem. Phys. 2013, 138, 134105] to accurately compute the transition states, the energy barriers, and the minimum energy paths for the wetting transition from the Cassie-Baxter state to the Wenzel state. Numerical results are obtained for the wetting of a hydrophobic surface textured with a square lattice of pillars. It is found that the wetting of the solid substrate occurs via infiltration of the liquid in a single groove, followed by lateral propagation of the liquid front. The propagation of the liquid front proceeds in a stepwise manner, and a zipping mechanism is observed during the infiltration of each layer. The minimum energy path for the wetting transition goes through a sequence of intermediate metastable states, whose wetted areas reflect the microstructure of the patterned surface. We also study the dependence of the energy barrier on the drop size and the gap between the pillars.

  10. Theoretical Studies of Atomic Transitions

    SciTech Connect

    Charlotte Froese Fischer

    2005-07-08

    Atomic structure calculations were performed for properties such as energy levels, binding energies, transition probabilities, lifetimes, hyperfine structure, and isotope shifts. Accurate computational procedures were devised so that properties could be predicted even when they could not be obtained from experiment, and to assist in the identification of observed data. The method used was the multiconfiguration Hartree-Fock (MCHF) method, optionally corrected for relativistic effects in the Breit-Pauli approximation. Fully relativistic Dirac-Fock calculations also were performed using the GRASP code A database of energy levels, lifetimes, and transition probabilities was designed and implemented and, at present, includes many results for Be-like to Ar-like.

  11. Thailand's Work and Health Transition.

    PubMed

    Kelly, Matthew; Strazdins, Lyndall; Dellora, Tarie; Khamman, Suwanee; Seubsman, Sam-Ang; Sleigh, Adrian C

    2010-09-01

    Thailand has experienced a rapid economic transition from agriculture to industry and services, and from informal to formal employment. It has much less state regulation and worker representation relative to developed nations, who underwent these transitions more slowly and sequentially, decades earlier. We examine the strengthening of Thai government policy and legislation affecting worker's health, responding to international norms, a new democratic constitution, fear of foreign importer embargos and several fatal workplace disasters. We identify key challenges remaining for Thai policy makers, including legislation enforcement and the measurement of impacts on worker's mental and physical health.

  12. William Crabtree's Venus transit observation

    NASA Astrophysics Data System (ADS)

    Kollerstrom, Nicholas

    2005-04-01

    The close collaboration between the two North-country astronomers Jeremiah Horrocks and William Crabtree gave them special insight into the new astronomy published by the recently-deceased Kepler, whereby Horrocks became the only person to apprehend that the Rudolphine tables were in fact predicting a Venus transit in 1639. This paper focuses especially upon William Crabtree's role and contribution. A comparison is made with an earlier, unsuccessful endeavour by these two concerning a possible transit of Mercury. Much of the record of their work was lost during the civil war. Finally, thanks to Christiaan Huygens, Horrock's manuscript was published by Johannes Hevelius in Danzig, in 1662.

  13. Mode Transition of Trichel pulses

    NASA Astrophysics Data System (ADS)

    Kexin, Zhang; Yongjun, Piao; Miao, Tang; Jingfeng, Tang; Liqiu, Wei; Chaohai, Zhang

    2015-11-01

    The trichel pulse is a typical kind of negative corona current observed in electronegative gases. In this work, stochastic behavior of the trichel pulse has been investigated. The experiment is performed in a negative corona reactor consisting of a stainless steel pin and a stainless steel powered by a dc high voltage source. The characteristic parameters distributions of corona current pulses, including the amplitude, rise time, half-wave time, and repetition frequency, are analyzed statistically. The results show there is a mode transition during the period of voltage increasing. This transition process happens in a certain voltage region, and change of pulse amplitude is the main difference between the two modes.

  14. Probabilities of transversions and transitions.

    PubMed

    Vol'kenshtein, M V

    1976-01-01

    The values of the mean relative probabilities of transversions and transitions have been refined on the basis of the data collected by Jukes and found to be equal to 0.34 and 0.66, respectively. Evolutionary factors increase the probability of transversions to 0.44. The relative probabilities of individual substitutions have been determined, and a detailed classification of the nonsense mutations has been given. Such mutations are especially probable in the UGG (Trp) codon. The highest probability of AG, GA transitions correlates with the lowest mean change in the hydrophobic nature of the amino acids coded.

  15. Epigenetic switches and network transitions

    NASA Astrophysics Data System (ADS)

    Sasai, Masaki

    2012-02-01

    We investigate dynamics of gene networks which are regulated by both the fast binding/unbinding of transcription factors to/from DNA and the slow processes of chromatin structural change or histone modification. This heterogeneous dynamics consisting of different time scales is analyzed by the mean-field approximation and the stochastic simulation to show that the network exhibits multiple metastable states and is characterized by transitions among them. We discuss distribution and fluctuation of states of the core gene network of embryonic stem cells as an example of such heterogeneous dynamics and the simulated transitions are compared with the experimental data on the distribution of stem cell states.

  16. Electronic transitions of yttrium monophosphide

    NASA Astrophysics Data System (ADS)

    Li, Biu Wa; Chan, Man-Chor; Cheung, A. S.-C.

    2015-11-01

    The electronic transition spectrum of the yttrium monophosphide (YP) molecule in the near infrared region between 715 nm and 880 nm has been recorded using laser ablation/reaction free-jet expansion and laser induced fluorescence spectroscopy. The YP molecule was produced by reacting laser - ablated yttrium atoms with PH3 gas seeded in argon. Eleven vibrational bands were analyzed and six electronic transitions have been identified, namely the [12.17] Ω = 3 - X3Π2, [13.27] Ω = 3 - X3Π2, [13.44] Ω = 3 - X3Π2, [13.46] Ω = 3 - X3Π2 and [13.40] Ω = 2 - X3Π2 transitions and a [13.69] Ω = 3 - a1Δ2 transition. Least squares fits of the measured rotational lines yielded molecular constants for the ground and excited states. The ground state has been determined to be a X3Π2 state and the bond length ro and vibrational separation, ΔG1/2, were determined to be 2.4413 Å and 390.77 cm-1 respectively. A molecular orbital energy level diagram has been used to aid the assignment of the observed electronic states. This work represents the first experimental investigation of the electronic spectrum of the YP molecule.

  17. Sustainability Transitions as new perspective

    NASA Astrophysics Data System (ADS)

    Rotmans, J.

    2012-04-01

    Sustainability transitions are radical transformations towards a sustainable society as a response to a number of persistent problems confronting contemporary modern societies. The most striking example of such a persistent problem is the current economic and financial crisis. This crisis is only a symptom of a deeper-lying systems crisis, which is rooted in the disbalance between overly consuming and producing during the last decennia on the one hand and exhausting our natural resources and materials on the other hand. The perverse effects of this disbalance are not accounted for in the economic order that we have created. This means that the economic order is not sustainable in the long run. Without a fundamental shift, a transition, to a new, sustainable economy, we will revert to old patterns and mechanisms that will automatically generate the next crises. In this transition process we are at a turning point. On the verge of a new era, characterized by a battle of the old paradigm against the new one, with a crucial role for sustainable innovation. Such a transition perspective might help to unravel the unprecedented complexity of the interrelated economic, financial, energy and climate crisis and to shed some light on structural, sustainable solutions.

  18. Career Transitions: The Australian Experience.

    ERIC Educational Resources Information Center

    Stevens, Paul

    This book is designed to aid career counselors in Australia help their clients search for enhanced well-being in their occupations and to help organizations and human resource staff members dealing with employees' career development. The book is organized in four parts. Parts 1 and 2 explore the career transition journey that a typical person…

  19. "Mexico in Transition." Curriculum Units.

    ERIC Educational Resources Information Center

    Oregon Univ., Eugene. Foreign Language Resource Center.

    These curriculum units were developed in a National Endowment for the Humanities 1994 summer seminar "Mexico in Transition." The 23 lessons are written in Spanish. Lessons are entitled: (1) "La Migracion Mexicana Vista a Traves del Cuento 'Paso del Norte' de Juan Rulfo" (Jose Jorge Armendariz); (2) "Los Grupos Indigenas de…

  20. Transition and Transport in Turbomachinery

    DTIC Science & Technology

    2012-06-01

    REPORT TYPE 3. DATES COVERED (From- To) 1 MAR 07- 30 NOV 09 4. TITLE AND SUBTITLE Sa. CONTRACT NUMBER Transition and transport in turbomachinery Sb...light of the re-orientation of AFOSR university pro- grams, I should note that the proposal was funded under Dr. Jeffries’ program on turbomachinery and

  1. Transition state in atomic physics

    NASA Astrophysics Data System (ADS)

    Jaffé, Charles; Farrelly, David; Uzer, T.

    1999-11-01

    The transition state is fundamental to modern theories of reaction dynamics: essentially, the transition state is a structure in phase space that all reactive trajectories must cross. While transition-state theory (TST) has been used mainly in chemical physics, it is possible to apply the theory to considerable advantage in any collision problem that involves some form of reaction. Of special interest are systems in which chaotic scattering or half-scattering occurs such as the ionization of Rydberg atoms in external fields. In this paper the ionization dynamics of a hydrogen atom in crossed electric and magnetic fields are shown to possess a transition state: We compute the periodic orbit dividing surface (PODS) which is found not to be a dividing surface when projected into configuration space. Although the possibility of a PODS occurring in phase space rather than configuration space has been recognized before, to our knowledge this is the first actual example: its origin is traced directly to the presence of velocity-dependent terms in the Hamiltonian. Our findings establish TST as the method of choice for understanding ionization of Rydberg atoms in the presence of velocity-dependent forces. To demonstrate this TST is used to (i) uncover a multiple-scattering mechanism for ionization and (ii) compute ionization rates. In the process we also develop a method of computing surfaces of section that uses periodic orbits to define the surface, and examine the fractal nature of the dynamics.

  2. Supporting Student Veterans in Transition

    ERIC Educational Resources Information Center

    Rumann, Corey B.; Hamrick, Florence A.

    2009-01-01

    The purpose of this chapter is to offer frameworks and considerations for student affairs professionals seeking to serve the transition needs of the current generation of student veterans. The historical intersections of the military and higher education, particularly with respect to the effects of the draft on students and higher education,…

  3. Understanding Student Veterans in Transition

    ERIC Educational Resources Information Center

    Jones, Kevin C.

    2013-01-01

    In this research report the author details a phenomenological study documenting identity development in student veterans making the transition from active military service to higher education. This study took place at a doctoral granting proprietary university with a significant veteran population and consisted of in-depth interviews. This…

  4. Detecting non-transiting exoplanets

    NASA Astrophysics Data System (ADS)

    Placek, Ben; Richards, Zachary; Knuth, Kevin H.

    2013-08-01

    Currently, the most popular way of detecting Extra-solar planets (exoplanets) is via the Transit Method. This method is limited only to planets with orbits such that we observe them transiting their host star. In this work in progress, we propose to identify non-transiting exoplanets in the data currently being collected by the Kepler Space Telescope by detecting orbital phase reflected light variations. Since such variations are due to light from the host star reflected by the planet, we expect this method to work best on closely orbitting large planets. Using the Metropolis-Hastings Monte Carlo and Nested Sampling algorithms, we will determine the presence or absence of nontransiting planets and estimate their orbital parameters such as, orbital inclination, semi-major axis, period, and eccentricity. Our estimates indicate that the development of this technique has the potential to double the number of detectable planets in the Kepler data sets. Here we demonstrate feasibility using portions of data from one of the first transiting planets detected by Kepler, HAT-P-7b.

  5. Leadership Transitions during Fundraising Campaigns

    ERIC Educational Resources Information Center

    Nehls, Kimberly

    2012-01-01

    Capital campaigns are intense efforts to build the financial assets of an institution in a specified amount of time. This study provides an empirical view of how changes in leadership affected concomitant capital campaigns at ten colleges and universities. The transitions during these 10 campaigns influenced morale on campus, altered timing of the…

  6. Presidential Transitions during Capital Campaigns

    ERIC Educational Resources Information Center

    Nehls, Kimberly

    2008-01-01

    In the past few decades, capital campaigns at institutions of higher education have increased in duration, while collegiate presidential tenures have been doing just the opposite. Turnover in the top post was frequent, even during major fundraising campaigns. Before this study, presidential transitions during campaigns had not been previously…

  7. Menopause: A Life Cycle Transition.

    ERIC Educational Resources Information Center

    Evarts, Barbara Kess; Baldwin, Cynthia

    1998-01-01

    Family therapists need to address the issue of menopause proactively to be of benefit to couples and families during this transitional period in the family life cycle. Physical, psychological, and psychosocial factors affecting the menopausal woman and her family, and ways to address these issues in counseling are discussed. (Author/EMK)

  8. Predicting transition to chronic pain

    PubMed Central

    Apkarian, A. Vania; Baliki, Marwan N.; Farmer, Melissa A.

    2016-01-01

    Purpose of review Most individuals who develop pain following an inciting event will return to a healthy state as the injury heals. However, a small percentage continue to suffer, that is, transition to chronic pain. Chronic pain may persist for years and is accompanied by cognitive abnormalities, as well as diminished quality of life. In animals, persistent pain is characterized by peripheral and spinal cord reorganization, and recent evidence in humans also indicates cortical reorganization. Yet, despite more than 30 years of research, there is little agreement on the neural mechanisms that mediate the transition from acute to chronic pain. Recent findings In a longitudinal brain-imaging study, individuals who developed an intense back pain episode were followed over a 1-year period, during which pain and brain parameters were collected repeatedly. A smaller number of healthy individuals and chronic back pain patients were also studied concomitantly, as positive and negative controls. At the time of entry into the study, strength of synchrony between the medial prefrontal cortex and nucleus accumbens (i.e. functional connectivity) was predictive (>80% accuracy) of individuals who subsequently transition to chronicity 1 year later. Summary Properties of the brain’s emotional learning circuitry predict the transition to chronic pain. The involvement of this circuitry in pain remains mostly unexplored. Future human and animal model studies are necessary to unravel underlying mechanisms driving pain chronicity, with the potential of advancing novel therapeutics for preventing pain chronification. PMID:23823463

  9. N-{Delta} weak transition

    SciTech Connect

    Graczyk, Krzysztof M.

    2011-11-23

    A short review of the Rein-Sehgal and isobar models is presented. The attention is focused on the nucleon-{Delta}(1232) weak transition form-factors. The results of the recent re-analyses of the ANL and BNL bubble chamber neutrino-deuteron scattering data are discussed.

  10. The nature of transition blazars

    SciTech Connect

    Ruan, J. J.; Anderson, S. F.; Plotkin, R. M.; Brandt, W. N.; Schneider, D. P.; Burnett, T. H.; Myers, A. D.

    2014-12-10

    Blazars are classically divided into the BL Lacertae (BLL) and flat-spectrum radio quasar (FSRQ) subclasses, corresponding to radiatively inefficient and efficient accretion regimes, respectively, largely based on the equivalent width (EW) of their optical broad emission lines (BELs). However, EW-based classification criteria are not physically motivated, and a few blazars have previously transitioned' from one subclass to the other. We present the first systematic search for these transition blazars in a sample of 602 unique pairs of repeat spectra of 354 blazars in the Sloan Digital Sky Survey, finding six clear cases. These transition blazars have bolometric Eddington ratios of ∼0.3 and low-frequency synchrotron peaks, and are thus FSRQ-like. We show that the strong EW variability (up to an unprecedented factor of >60) is due to swamping of the BELs from variability in jet continuum emission, which is stronger in amplitude and shorter in timescale than typical blazars. Although these transition blazars appear to switch between FSRQ and BLL according to the phenomenologically based EW scheme, we show that they are most likely rare cases of FSRQs with radiatively efficient accretion flows and especially strongly beamed jets. These results have implications for the decrease of the apparent BLL population at high redshifts, and may lend credence to claims of a negative BLL redshift evolution.

  11. Percolation transitions with nonlocal constraint.

    PubMed

    Shim, Pyoung-Seop; Lee, Hyun Keun; Noh, Jae Dong

    2012-09-01

    We investigate percolation transitions in a nonlocal network model numerically. In this model, each node has an exclusive partner and a link is forbidden between two nodes whose r-neighbors share any exclusive pair. The r-neighbor of a node x is defined as a set of at most N(r) neighbors of x, where N is the total number of nodes. The parameter r controls the strength of a nonlocal effect. The system is found to undergo a percolation transition belonging to the mean-field universality class for r<1/2. On the other hand, for r>1/2, the system undergoes a peculiar phase transition from a nonpercolating phase to a quasicritical phase where the largest cluster size G scales as G~N(α) with α=0.74(1). In the marginal case with r=1/2, the model displays a percolation transition that does not belong to the mean-field universality class.

  12. GLOBAL TRANSITION TO SUSTAINABLE DEVELOPMENT

    EPA Science Inventory

    Global transition to sustainable development is possible but many obstacles lie in the way and it will require acts of political will on the part of both the developed and developing nations to become a reality. In this paper, sustainable development is defined as continuous prog...

  13. Transition metal sulfide loaded catalyst

    DOEpatents

    Maroni, V.A.; Iton, L.E.; Pasterczyk, J.W.; Winterer, M.; Krause, T.R.

    1994-04-26

    A zeolite-based catalyst is described for activation and conversion of methane. A zeolite support includes a transition metal (Mo, Cr or W) sulfide disposed within the micropores of the zeolite. The catalyst allows activation and conversion of methane to C[sub 2]+ hydrocarbons in a reducing atmosphere, thereby avoiding formation of oxides of carbon.

  14. Transition metal sulfide loaded catalyst

    DOEpatents

    Maroni, Victor A.; Iton, Lennox E.; Pasterczyk, James W.; Winterer, Markus; Krause, Theodore R.

    1994-01-01

    A zeolite based catalyst for activation and conversion of methane. A zeolite support includes a transition metal (Mo, Cr or W) sulfide disposed within the micropores of the zeolite. The catalyst allows activation and conversion of methane to C.sub.2 + hydrocarbons in a reducing atmosphere, thereby avoiding formation of oxides of carbon.

  15. Preterm Birth: Transition to Adulthood

    ERIC Educational Resources Information Center

    Allen, Marilee C.; Cristofalo, Elizabeth; Kim, Christina

    2010-01-01

    Preterm birth is associated with greater difficulty with transitions from childhood to adolescence to adulthood. Adolescents and young adults born preterm have higher rates of cerebral palsy, intellectual disability, cognitive impairment, learning disability, executive dysfunction, attention deficit disorder, and social-emotional difficulties than…

  16. Miami Bound: Issues in Transition.

    ERIC Educational Resources Information Center

    Parks, Russell E.

    The Outdoor Pursuit Center at Miami University, Ohio, has provided an outdoor orientation experience for incoming first-year students since 1995. The experience provides an environment that is effective in easing the transition into higher education settings. Student trip coordinators, student facilitators, faculty, and professional staff use…

  17. Transiting Exoplanet Survey Satellite (TESS)

    NASA Technical Reports Server (NTRS)

    Ricker, G. R.; Clampin, M.; Latham, D. W.; Seager, S.; Vanderspek, R. K.; Villasenor, J. S.; Winn, J. N.

    2012-01-01

    The Transiting Exoplanet Survey Satellite (TESS) will discover thousands of exoplanets in orbit around the brightest stars in the sky. In a two-year survey, TESS will monitor more than 500,000 stars for temporary drops in brightness caused by planetary transits. This first-ever spaceborne all-sky transit survey will identify planets ranging from Earth-sized to gas giants, around a wide range of stellar types and orbital distances. No ground-based survey can achieve this feat. A large fraction of TESS target stars will be 30-100 times brighter than those observed by Kepler satellite, and therefore TESS . planets will be far easier to characterize with follow-up observations. TESS will make it possible to study the masses, sizes, densities, orbits, and atmospheres of a large cohort of small planets, including a sample of rocky worlds in the habitable zones of their host stars. TESS will provide prime targets for observation with the James Webb Space Telescope (JWST), as well as other large ground-based and space-based telescopes of the future. TESS data will be released with minimal delay (no proprietary period), inviting immediate community-wide efforts to study the new planets. The TESS legacy will be a catalog of the very nearest and brightest main-sequence stars hosting transiting exoplanets, thus providing future observers with the most favorable targets for detailed investigations.

  18. Poland's Transition in Business Education

    ERIC Educational Resources Information Center

    Leven, Bozena

    2010-01-01

    Prior to Poland's transition from central planning to a market system, which began in 1990, schools of business were non-existent in that country. Instead, university level instruction on economics during the socialist period was closely tied to ideological priorities, and limited to imparting skills suitable for planned economy. All universities…

  19. Suicide and Mass Urban Transit.

    ERIC Educational Resources Information Center

    Berman, Alan L., Ed.

    1991-01-01

    Presents case consultation in which consultants respond to issues of urban planning for mass transit (subway) system and how to maximize prevention of intentional injury within subway stations. Also asks what type of research study should be used and what type of data collected once system is operating. Case is discussed by Morton M. Silverman and…

  20. Transition in Pulsatile Pipe Flow

    NASA Astrophysics Data System (ADS)

    Vlachos, Pavlos; Brindise, Melissa

    2016-11-01

    Transition has been observed to occur in the aorta, and stenotic vessels, where pulsatile flow exists. However, few studies have investigated the characteristics and effects of transition in oscillating or pulsatile flow and none have utilized a physiological waveform. In this work, we explore transition in pipe flow using three pulsatile waveforms which all maintain the same mean and maximum flow rates and range to zero flow, as is physiologically typical. Velocity fields were obtained using planar particle image velocimetry for each pulsatile waveform at six mean Reynolds numbers ranging between 500 and 4000. Turbulent statistics including turbulent kinetic energy (TKE) and Reynolds stresses were computed. Quadrant analysis was used to identify characteristics of the production and dissipation of turbulence. Coherent structures were identified using the λci method. We developed a wavelet-Hilbert time-frequency analysis method to identify high frequency structures and compared these to the coherent structures. The results of this study demonstrate that the different pulsatile waveforms induce different levels of TKE and high frequency structures, suggesting that the rates of acceleration and deceleration influence the onset and development of transition.

  1. Leadership Transitions: Keys for Success

    ERIC Educational Resources Information Center

    Goodyear, Marilu; Golden, Cynthia

    2008-01-01

    A leadership transition poses dangers and challenges for both leaders and followers. While each party naturally focuses on the organization's success, time needs to be spent on how the new relationships will develop and mature into effective working relationships. This article discusses the following four areas of interaction between leaders and…

  2. Narratives about Labour Market Transitions

    ERIC Educational Resources Information Center

    Cort, Pia; Thomsen, Rie

    2014-01-01

    In European Union policy, Denmark is often referred to as a model country in terms of its flexicurity model and provision of financial support and access to education and training during periods of unemployment, i.e. during transitional phases in a working life. However, in the research on flexicurity and its implications for labour market…

  3. American Higher Education in Transition

    ERIC Educational Resources Information Center

    Ehrenberg, Ronald G.

    2011-01-01

    American higher education is in transition and if there ever was a "golden age" for faculty, it probably is behind us. The best historical data on the composition of faculty is collected annually by the American Mathematical Society. Between 1967 and 2009, the share of full-time faculty with PhDs remained constant at about 90 percent at…

  4. Electrical Conductivity in Transition Metals

    ERIC Educational Resources Information Center

    Talbot, Christopher; Vickneson, Kishanda

    2013-01-01

    The aim of this "Science Note" is to describe how to test the electron-sea model to determine whether it accurately predicts relative electrical conductivity for first-row transition metals. In the electron-sea model, a metal crystal is viewed as a three-dimensional array of metal cations immersed in a sea of delocalised valence…

  5. 75 FR 70966 - Transit Asset Management (TAM) Pilot Program

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-11-19

    ... Federal Transit Administration Transit Asset Management (TAM) Pilot Program AGENCY: Federal Transit... Federal Transit Administration (FTA) is soliciting proposals from public transportation providers, state... partnership--to demonstrate effective Transit Asset Management (TAM) systems and ``best practices'', which...

  6. 76 FR 47296 - Transit Asset Management (TAM) Pilot Program Funds

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-08-04

    ... Federal Transit Administration Transit Asset Management (TAM) Pilot Program Funds AGENCY: Federal Transit Administration (FTA), DOT. ACTION: Transit Asset Management Pilot Program Announcement of Project Selections. SUMMARY: The U.S. Department of Transportation's (DOT) Federal Transit Administration (FTA) announces...

  7. Comparative Habitability of Transiting Exoplanets

    NASA Astrophysics Data System (ADS)

    Barnes, Rory; Meadows, Victoria S.; Evans, Nicole

    2015-12-01

    Exoplanet habitability is traditionally assessed by comparing a planet’s semimajor axis to the location of its host star’s “habitable zone,” the shell around a star for which Earth-like planets can possess liquid surface water. The Kepler space telescope has discovered numerous planet candidates near the habitable zone, and many more are expected from missions such as K2, TESS, and PLATO. These candidates often require significant follow-up observations for validation, so prioritizing planets for habitability from transit data has become an important aspect of the search for life in the universe. We propose a method to compare transiting planets for their potential to support life based on transit data, stellar properties and previously reported limits on planetary emitted flux. For a planet in radiative equilibrium, the emitted flux increases with eccentricity, but decreases with albedo. As these parameters are often unconstrained, there is an “eccentricity-albedo degeneracy” for the habitability of transiting exoplanets. Our method mitigates this degeneracy, includes a penalty for large-radius planets, uses terrestrial mass-radius relationships, and, when available, constraints on eccentricity to compute a number we call the “habitability index for transiting exoplanets” that represents the relative probability that an exoplanet could support liquid surface water. We calculate it for Kepler objects of interest and find that planets that receive between 60% and 90% of the Earth’s incident radiation, assuming circular orbits, are most likely to be habitable. Finally, we make predictions for the upcoming TESS and James Webb Space Telescope missions.

  8. COMPARATIVE HABITABILITY OF TRANSITING EXOPLANETS

    SciTech Connect

    Barnes, Rory; Meadows, Victoria S.; Evans, Nicole

    2015-12-01

    Exoplanet habitability is traditionally assessed by comparing a planet’s semimajor axis to the location of its host star’s “habitable zone,” the shell around a star for which Earth-like planets can possess liquid surface water. The Kepler space telescope has discovered numerous planet candidates near the habitable zone, and many more are expected from missions such as K2, TESS, and PLATO. These candidates often require significant follow-up observations for validation, so prioritizing planets for habitability from transit data has become an important aspect of the search for life in the universe. We propose a method to compare transiting planets for their potential to support life based on transit data, stellar properties and previously reported limits on planetary emitted flux. For a planet in radiative equilibrium, the emitted flux increases with eccentricity, but decreases with albedo. As these parameters are often unconstrained, there is an “eccentricity-albedo degeneracy” for the habitability of transiting exoplanets. Our method mitigates this degeneracy, includes a penalty for large-radius planets, uses terrestrial mass–radius relationships, and, when available, constraints on eccentricity to compute a number we call the “habitability index for transiting exoplanets” that represents the relative probability that an exoplanet could support liquid surface water. We calculate it for Kepler objects of interest and find that planets that receive between 60% and 90% of the Earth’s incident radiation, assuming circular orbits, are most likely to be habitable. Finally, we make predictions for the upcoming TESS and James Webb Space Telescope missions.

  9. Characteristic length of glass transition

    NASA Astrophysics Data System (ADS)

    Donth, E.

    1996-03-01

    The characteristic length of the glass transition (ξ _α ) is based on the concept of cooperatively rearranging regions (CRR's) by Adam & Gibbs (1965): ξ _α is the diameter of one CRR. In the theoretical part of the talk a formula is derived how this length can be calculated from calorimetric data of the transformation interval. The approach is based on fluctuations in natural functional subsystems. The corresponding thermodynamics is represented e.g. in a book of the author (E. Donth, Relaxation and Thermodynamics in Polymers. Glass Transition, Akademie-Verlag, Berlin 1992). A typical value for this length is 3 nanometers. In the experimental part several examples are reported to enlarge the experimental evidence for such a length: Squeezing the glass transition in the amorphous layers of partially crystallized PET (C. Schick, Rostock), glass transition of small-molecule glass formers in a series of nanoscaled pores of porous glasses (F. Kremer, Leipzig), comparison with a concentration fluctuation model in homogeneous polymer mixtures (E.W. Fischer, Mainz), and, from our laboratory, backscaling to ξ _α across the main transition from the entanglement spacing in several amorphous polymers such as PVAC, PS, NR, and some polymer networks. Rouse backscaling was possible in the α β splitting region of several poly(n alkyl methacrylates) resulting in small characteristic lengths of order 1 nanometer near the onset of α cooperativity. In a speculative outlook a dynamic density pattern is presented, having a cellular structure with higher density and lower mobility of the cell walls. It will be explained, with the aid of different thermal expansion of wall and clusters, how the clusters within the cells maintain a certain mobility far below the glass temperature.

  10. Agile Port System Transition Support Transition Plan Development

    DTIC Science & Technology

    2013-07-29

    the  form  of documented science and technology and combatant commander  needs (expressed in terms of technology gaps and seams) for those selected...CRADA),  Joint Capability Technology Demonstrations (JCTD), as traditional paths for transition, as well as other  forms  for rapid transition, such as...TIP) 3.1.1 Description TIP is a prototype web portal in the  form  of a virtual private network (VPN) hosted by a third  party logistics services

  11. Transitions

    NASA Technical Reports Server (NTRS)

    2006-01-01

    26 May 2006 This Mars Global Surveyor (MGS) Mars Orbiter Camera (MOC) image shows a variety of textures observed on a dust-covered plain in the Marte Valles region of Mars. Textural variations across the scene include: areas that are littered with small impact craters, a channel-like feature that is dominated by mounds of a variety of sizes, small ripples and/or ridges, and relatively smooth, unremarkable terrain. The contact between the cratered plain and the area dominated by mounds marks one of the banks along the edge of one of the shallow valleys of the Marte Valles system.

    Location near: 17.7oN, 175.0oW Image width: 3 km (1.9 mi) Illumination from: lower left Season: Northern Spring

  12. Aging transition by random errors

    PubMed Central

    Sun, Zhongkui; Ma, Ning; Xu, Wei

    2017-01-01

    In this paper, the effects of random errors on the oscillating behaviors have been studied theoretically and numerically in a prototypical coupled nonlinear oscillator. Two kinds of noises have been employed respectively to represent the measurement errors accompanied with the parameter specifying the distance from a Hopf bifurcation in the Stuart-Landau model. It has been demonstrated that when the random errors are uniform random noise, the change of the noise intensity can effectively increase the robustness of the system. While the random errors are normal random noise, the increasing of variance can also enhance the robustness of the system under certain conditions that the probability of aging transition occurs reaches a certain threshold. The opposite conclusion is obtained when the probability is less than the threshold. These findings provide an alternative candidate to control the critical value of aging transition in coupled oscillator system, which is composed of the active oscillators and inactive oscillators in practice. PMID:28198430

  13. Transition probabilities in O III

    NASA Astrophysics Data System (ADS)

    Froese Fischer, Charlotte

    1994-01-01

    Transition data has been computed in the MCHF + Breit-Pauli approximation for a number of the low lying triplets in O III. Special attention was given to the 2p3p 3P-2p3d 3P transition which is a primary cascade for the Bowen fluorescence mechanism in O III. The relativistic, largely spin-orbit, effect on the intensity ratio of primary decays was found to be as large as 50%, whereas the effect on secondary cascades was less than 30%. Agreement with astrophysically observed intensity ratios is excellent. There also is good agreement between the present liftimes and the beam-foil mean lifetimes obtained by Pinnington et al., though for 2p3p 3D and 3S the theoretical lifetimes are considerably shorter.

  14. Electronic transitions of palladium dimer

    SciTech Connect

    Qian, Yue; Ng, Y. W.; Chen, Zhihua; Cheung, A. S.-C.

    2013-11-21

    The laser induced fluorescence spectrum of palladium dimer (Pd{sub 2}) in the visible region between 480 and 700 nm has been observed and analyzed. The gas-phase Pd{sub 2} molecule was produced by laser ablation of palladium metal rod. Eleven vibrational bands were observed and assigned to the [17.1] {sup 3}II{sub g} - X{sup 3}Σ{sub u}{sup +} transition system. The bond length (r{sub o}) and vibrational frequency (ΔG{sub 1/2}) of the ground X{sup 3}Σ{sub u}{sup +} state were determined to be 2.47(4) Å and 211.4(5) cm{sup −1}, respectively. A molecular orbital energy level diagram was used to understand the observed ground and excited electronic states. This is the first gas-phase experimental investigation of the electronic transitions of Pd{sub 2}.

  15. Articulated transition duct in turbomachine

    DOEpatents

    Flanagan, James Scott; McMahan, Kevin Weston; LeBegue, Jeffrey Scott; Pentecost, Ronnie Ray

    2014-04-29

    Turbine systems are provided. A turbine system includes a transition duct comprising an inlet, an outlet, and a duct passage extending between the inlet and the outlet and defining a longitudinal axis, a radial axis, and a tangential axis. The outlet of the transition duct is offset from the inlet along the longitudinal axis and the tangential axis. The duct passage includes an upstream portion and a downstream portion. The upstream portion extends from the inlet between an inlet end and an aft end. The downstream portion extends from the outlet between an outlet end and a head end. The turbine system further includes a joint coupling the aft end of the upstream portion and the head end of the downstream portion together. The joint is configured to allow movement of the upstream portion and the downstream portion relative to each other about or along at least one axis.

  16. Electronic Transitions of Yttrium Monoxide

    NASA Astrophysics Data System (ADS)

    Ng, Y. W.; Wang, Na; Clark, Andrew B.; Cheung, A. S.-C.

    2013-06-01

    The electronic transition spectrum of yttrium monoxide (YO) in the spectral region between 284nm and 307nm has been recorded using laser ablation/reaction free-jet expansion and laser induced fluorescence (LIF) spectroscopy. The YO molecule was produced by reacting laser-ablated yttrium atoms with O_{2} seeded in argon. Twenty transition bands were observed in that region and a few bands were selected for further study using optical-optical double resonance (OODR) spectroscopy. The excited C^{2} Π state has been reached via the intermediate B^{2} Σ^{+} state from the ground X^{2} Σ^{+} state. The excited sub-states observed so far have Ω = 0.5 and 1.5. A least squares fit of the measured rotational lines yielded molecular constants for the newly observed excited states.

  17. Venus transits - A French view

    NASA Astrophysics Data System (ADS)

    Débarbat, Suzanne

    2005-04-01

    After a careful study of Mars observations obtained by Tycho Brahé (1546-1601), Kepler (1571-1630) discovered the now-called Kepler's third law. In 1627 he published his famous Tabulae Rudolphinae, a homage to his protector Rudolph II (1552-1612), tables (Kepler 1609, 1627) from which he predicted Mercury and Venus transits over the Sun. In 1629 Kepler published his Admonitio ad Astronomos Advertisement to Astronomers (Kepler 1630), Avertissement aux Astronomes in French Au sujet de phénomènes rares et étonnants de l'an 1631: l'incursion de Vénus et de Mercure sur le Soleil. This was the beginning of the interest of French astronomers, among many others, in such transits, mostly for Venus, the subject of this paper in which dates are given in the Gregorian calendar.

  18. Counting paths with Schur transitions

    NASA Astrophysics Data System (ADS)

    Díaz, Pablo; Kemp, Garreth; Véliz-Osorio, Alvaro

    2016-10-01

    In this work we explore the structure of the branching graph of the unitary group using Schur transitions. We find that these transitions suggest a new combinatorial expression for counting paths in the branching graph. This formula, which is valid for any rank of the unitary group, reproduces known asymptotic results. We proceed to establish the general validity of this expression by a formal proof. The form of this equation strongly hints towards a quantum generalization. Thus, we introduce a notion of quantum relative dimension and subject it to the appropriate consistency tests. This new quantity finds its natural environment in the context of RCFTs and fractional statistics; where the already established notion of quantum dimension has proven to be of great physical importance.

  19. Adolescents Transitioning to High School.

    PubMed

    Williams, Susan G; Langhinrichsen-Rohling, Jennifer; Wornell, Cory; Finnegan, Heather

    2017-01-01

    Adolescents transitioning to high school may be at greater risk of depression and suicide if they are victims of bullying behavior. This study explored sex differences in bullying victimization (physical, verbal/social, and cyberbullying) and the impact on depressive symptoms and suicidal behaviors in ninth-grade students ( N = 233). Females reported significantly more verbal/social and cyberbullying than male students. There were no significant sex differences in physical bullying; male students who reported physical bullying victimization were more likely to experience depressive symptoms. Verbal/social bullying predicted depressive symptoms in males and females. Females who reported being victims of cyberbullying were more likely to report depressive symptoms, suicide ideation, and suicide attempts. Eighteen students reported suicide attempts, and each also experienced verbal/social bullying. School nurses are positioned to reach out to transitioning students, screen for mental health issues, provide a safe place to talk about bullying experiences, and promote positive mental health.

  20. Aging transition by random errors

    NASA Astrophysics Data System (ADS)

    Sun, Zhongkui; Ma, Ning; Xu, Wei

    2017-02-01

    In this paper, the effects of random errors on the oscillating behaviors have been studied theoretically and numerically in a prototypical coupled nonlinear oscillator. Two kinds of noises have been employed respectively to represent the measurement errors accompanied with the parameter specifying the distance from a Hopf bifurcation in the Stuart-Landau model. It has been demonstrated that when the random errors are uniform random noise, the change of the noise intensity can effectively increase the robustness of the system. While the random errors are normal random noise, the increasing of variance can also enhance the robustness of the system under certain conditions that the probability of aging transition occurs reaches a certain threshold. The opposite conclusion is obtained when the probability is less than the threshold. These findings provide an alternative candidate to control the critical value of aging transition in coupled oscillator system, which is composed of the active oscillators and inactive oscillators in practice.

  1. Investigation of EO transition rates

    NASA Astrophysics Data System (ADS)

    Colvin, G. G.; Schreckenbach, K.

    1985-01-01

    Basic ideas on the nature of electric monopole transitions and their experimental realisation are presented. Some feeling for the sensitivity obtainable for X=B(EO)/B(E2) ratios are discussed. Examples of measurements performed using the electron spectrometer BILL are described to demonstrate their relevance in testing nuclei models. These include even-even and odd-even nuclei such as nuclei close to Z=50, rare-earth nuclei, Pt-Os isotopes and the actinides.

  2. Transiting Exoplanet Survey Satellite (TESS)

    NASA Astrophysics Data System (ADS)

    Ricker, George R.; Winn, Joshua N.; Vanderspek, Roland; Latham, David W.; Bakos, Gáspár. Á.; Bean, Jacob L.; Berta-Thompson, Zachory K.; Brown, Timothy M.; Buchhave, Lars; Butler, Nathaniel R.; Butler, R. Paul; Chaplin, William J.; Charbonneau, David; Christensen-Dalsgaard, Jørgen; Clampin, Mark; Deming, Drake; Doty, John; De Lee, Nathan; Dressing, Courtney; Dunham, E. W.; Endl, Michael; Fressin, Francois; Ge, Jian; Henning, Thomas; Holman, Matthew J.; Howard, Andrew W.; Ida, Shigeru; Jenkins, Jon; Jernigan, Garrett; Johnson, John A.; Kaltenegger, Lisa; Kawai, Nobuyuki; Kjeldsen, Hans; Laughlin, Gregory; Levine, Alan M.; Lin, Douglas; Lissauer, Jack J.; MacQueen, Phillip; Marcy, Geoffrey; McCullough, P. R.; Morton, Timothy D.; Narita, Norio; Paegert, Martin; Palle, Enric; Pepe, Francesco; Pepper, Joshua; Quirrenbach, Andreas; Rinehart, S. A.; Sasselov, Dimitar; Sato, Bun'ei; Seager, Sara; Sozzetti, Alessandro; Stassun, Keivan G.; Sullivan, Peter; Szentgyorgyi, Andrew; Torres, Guillermo; Udry, Stephane; Villasenor, Joel

    2014-08-01

    The Transiting Exoplanet Survey Satellite (TESS ) will search for planets transiting bright and nearby stars. TESS has been selected by NASA for launch in 2017 as an Astrophysics Explorer mission. The spacecraft will be placed into a highly elliptical 13.7-day orbit around the Earth. During its two-year mission, TESS will employ four wide-field optical CCD cameras to monitor at least 200,000 main-sequence dwarf stars with IC (approximately less than) 13 for temporary drops in brightness caused by planetary transits. Each star will be observed for an interval ranging from one month to one year, depending mainly on the star's ecliptic latitude. The longest observing intervals will be for stars near the ecliptic poles, which are the optimal locations for follow-up observations with the James Webb Space Telescope. Brightness measurements of preselected target stars will be recorded every 2 min, and full frame images will be recorded every 30 min. TESS stars will be 10-100 times brighter than those surveyed by the pioneering Kepler mission. This will make TESS planets easier to characterize with follow-up observations. TESS is expected to find more than a thousand planets smaller than Neptune, including dozens that are comparable in size to the Earth. Public data releases will occur every four months, inviting immediate community-wide efforts to study the new planets. The TESS legacy will be a catalog of the nearest and brightest stars hosting transiting planets, which will endure as highly favorable targets for detailed investigations.

  3. Transiting Exoplanet Survey Satellite (TESS)

    NASA Astrophysics Data System (ADS)

    Ricker, George R.; Winn, Joshua N.; Vanderspek, Roland; Latham, David W.; Bakos, Gáspár Á.; Bean, Jacob L.; Berta-Thompson, Zachory K.; Brown, Timothy M.; Buchhave, Lars; Butler, Nathaniel R.; Butler, R. Paul; Chaplin, William J.; Charbonneau, David; Christensen-Dalsgaard, Jørgen; Clampin, Mark; Deming, Drake; Doty, John; De Lee, Nathan; Dressing, Courtney; Dunham, Edward W.; Endl, Michael; Fressin, Francois; Ge, Jian; Henning, Thomas; Holman, Matthew J.; Howard, Andrew W.; Ida, Shigeru; Jenkins, Jon M.; Jernigan, Garrett; Johnson, John Asher; Kaltenegger, Lisa; Kawai, Nobuyuki; Kjeldsen, Hans; Laughlin, Gregory; Levine, Alan M.; Lin, Douglas; Lissauer, Jack J.; MacQueen, Phillip; Marcy, Geoffrey; McCullough, Peter R.; Morton, Timothy D.; Narita, Norio; Paegert, Martin; Palle, Enric; Pepe, Francesco; Pepper, Joshua; Quirrenbach, Andreas; Rinehart, Stephen A.; Sasselov, Dimitar; Sato, Bun'ei; Seager, Sara; Sozzetti, Alessandro; Stassun, Keivan G.; Sullivan, Peter; Szentgyorgyi, Andrew; Torres, Guillermo; Udry, Stephane; Villasenor, Joel

    2015-01-01

    The Transiting Exoplanet Survey Satellite (TESS) will search for planets transiting bright and nearby stars. TESS has been selected by NASA for launch in 2017 as an Astrophysics Explorer mission. The spacecraft will be placed into a highly elliptical 13.7-day orbit around the Earth. During its 2-year mission, TESS will employ four wide-field optical charge-coupled device cameras to monitor at least 200,000 main-sequence dwarf stars with IC≈4-13 for temporary drops in brightness caused by planetary transits. Each star will be observed for an interval ranging from 1 month to 1 year, depending mainly on the star's ecliptic latitude. The longest observing intervals will be for stars near the ecliptic poles, which are the optimal locations for follow-up observations with the James Webb Space Telescope. Brightness measurements of preselected target stars will be recorded every 2 min, and full frame images will be recorded every 30 min. TESS stars will be 10 to 100 times brighter than those surveyed by the pioneering Kepler mission. This will make TESS planets easier to characterize with follow-up observations. TESS is expected to find more than a thousand planets smaller than Neptune, including dozens that are comparable in size to the Earth. Public data releases will occur every 4 months, inviting immediate community-wide efforts to study the new planets. The TESS legacy will be a catalog of the nearest and brightest stars hosting transiting planets, which will endure as highly favorable targets for detailed investigations.

  4. Nucleon Resonance Transition Form factors

    SciTech Connect

    Burkert, Volker D.; Mokeev, Viktor I.; Aznauryan, Inna G.

    2016-08-01

    We discuss recent results from CLAS on electromagnetic resonance transition amplitudes and their dependence on the distance scale (Q2). From the comparison of these results with most advanced theoretical calculations within QCD-based approaches there is clear evidence that meson-baryon contributions are present and important at large distances, i.e. small Q2, and that quark core contributions dominate the short distance behavior.

  5. Phase transitions in nuclear matter

    SciTech Connect

    Glendenning, N.K.

    1984-11-01

    The rather general circumstances under which a phase transition in hadronic matter at finite temperature to an abnormal phase in which baryon effective masses become small and in which copious baryon-antibaryon pairs appear is emphasized. A preview is also given of a soliton model of dense matter, in which at a density of about seven times nuclear density, matter ceases to be a color insulator and becomes increasingly color conducting. 22 references.

  6. Resolution requirements for numerical simulations of transition

    NASA Technical Reports Server (NTRS)

    Zang, Thomas A.; Krist, Steven E.; Hussaini, M. Yousuff

    1989-01-01

    The resolution requirements for direct numerical simulations of transition to turbulence are investigated. A reliable resolution criterion is determined from the results of several detailed simulations of channel and boundary-layer transition.

  7. Blue Dots Team Transits Working Group Review

    NASA Astrophysics Data System (ADS)

    Sozzetti, A.; Afonso, C.; Alonso, R.; Blank, D. L.; Catala, C.; Deeg, H.; Grenfell, J. L.; Hellier, C.; Latham, D. W.; Minniti, D.; Pont, F.; Rauer, H.

    2010-10-01

    Transiting planet systems offer a unique opportunity to observationally constrain proposed models of the interiors (radius, composition) and atmospheres (chemistry, dynamics) of extrasolar planets. The spectacular successes of ground-based transit surveys (more than 60 transiting systems known to-date) and the host of multi-wavelength, spectro-photometric follow-up studies, carried out in particular by HST and Spitzer, have paved the way to the next generation of transit search projects, which are currently ongoing (CoRoT, Kepler), or planned. The possibility of detecting and characterizing transiting Earth-sized planets in the habitable zone of their parent stars appears tantalizingly close. In this contribution we briefly review the power of the transit technique for characterization of extrasolar planets, summarize the state of the art of both ground-based and space-borne transit search programs, and illustrate how the science of planetary transits fits within the Blue Dots perspective.

  8. Functions and Requirements for the Transition Project

    SciTech Connect

    YANOCHKO, R.M.

    2000-04-24

    This document describes the functional requirement baseline for the Transition of 100 K Area Facilities Project (Transition Project). This baseline information consists of top-level functions, requirements, concept description, interface description, issues, and enabling assumptions.

  9. Fast flux test facility, transition project plan

    SciTech Connect

    Guttenberg, S.

    1994-11-15

    The FFTF Transition Project Plan, Revision 1, provides changes and project baseline for the deactivation activities necessary to transition the FFTF to a radiologically and industrially safe shutdown condition.

  10. Aspects of the electroweak phase transition

    SciTech Connect

    Huet, P.

    1992-11-01

    The electroweak phase transition is reviewed in light of some recent developments. Emphasis is on the issue whether the transition is first or second order and its possible role in the generation of the baryon asymmetry of the universe.

  11. Marital transitions. A child's perspective.

    PubMed

    Hetherington, E M; Stanley-Hagan, M; Anderson, E R

    1989-02-01

    Despite a recent leveling off of the divorce rate, almost half of the children born in the last decade will experience the divorce of their parents, and most of these children will also experience the remarriage of their parents. Most children initially experience their parents' marital rearrangements as stressful; however, children's responses to their parents marital transitions are diverse. Whereas some exhibit remarkable resiliency and in the long term may actually be enhanced by coping with these transitions, others suffer sustained developmental delays or disruptions. Others appear to adapt well in the early stages of family reorganizations but show delayed effects that emerge at a later time, especially in adolescence. The long-term effects are related more to the child's developmental status, sex, and temperament; the qualities of the home and parenting environments; and to the resources and support systems available to the parents and child than they are to divorce or remarriage per se. In recent years, researchers have begun to move away from the view that single-parent and remarried families are atypical or pathogenic families and are focusing on the diversity of children's responses and to the factors that facilitate or disrupt the development and adjustment of children experiencing their parents' marital transitions.

  12. Major transitions in information technology.

    PubMed

    Valverde, Sergi

    2016-08-19

    When looking at the history of technology, we can see that all inventions are not of equal importance. Only a few technologies have the potential to start a new branching series (specifically, by increasing diversity), have a lasting impact in human life and ultimately became turning points. Technological transitions correspond to times and places in the past when a large number of novel artefact forms or behaviours appeared together or in rapid succession. Why does that happen? Is technological change continuous and gradual or does it occur in sudden leaps and bounds? The evolution of information technology (IT) allows for a quantitative and theoretical approach to technological transitions. The value of information systems experiences sudden changes (i) when we learn how to use this technology, (ii) when we accumulate a large amount of information, and (iii) when communities of practice create and exchange free information. The coexistence between gradual improvements and discontinuous technological change is a consequence of the asymmetric relationship between complexity and hardware and software. Using a cultural evolution approach, we suggest that sudden changes in the organization of ITs depend on the high costs of maintaining and transmitting reliable information.This article is part of the themed issue 'The major synthetic evolutionary transitions'.

  13. Radionuclide transit in esophageal varices

    SciTech Connect

    Yeh, S.H.; Wang, S.J.; Wu, L.C.; Liu, R.S.; Tsai, Y.T.; Chiang, T.T.

    1985-05-01

    This study assessed esophageal motility in patients with esophageal varices by radionuclide transit studies. Data were acquired in list mode after an oral dose of 0.5 mCi Tc-99m sulfur colloid in 10 ml of water in the supine position above a low-energy all-purpose collimator of a gamma camera. The condensed image (CI) superimposed with a centroid curve was also produced in each case. Twenty-five normal subjects (N) and 32 patients (pts) with esophageal varices by endoscopy (large varices in Grades IV and V in 8 and small varices in Grade III or less in 24) were studied. TMTT, RTT, RF, and RI were all significantly increased in pts as compared to N. Especially, the transit time for the middle third (6.7 +- 2.6 sec vs 3.5 +- 0.9 sec in N, rho < 0.005) had the optimal sensitivy and specificity of 88% each at the cutoff value of 4.2 sec as determined by ROC analysis. In summary, radionuclide transit disorders occur in the majority of pts with esopageal varices. The middle RTT and CI are both optimal in sensitivity and specificity for detecting the abnormalities.

  14. Financing pharmaceuticals in transition economies.

    PubMed

    Kanavos, P

    1999-06-01

    This paper (a) provides a methodological taxonomy of pricing, financing, reimbursement, and cost containment methodologies for pharmaceuticals; (b) analyzes complex agency relationships and the health versus industrial policy tradeoff; (c) pinpoints financing measures to balance safety and effectiveness of medicines and their affordability by publicly funded systems in transition; and (d) highlights viable options for policy-makers for the financing of pharmaceuticals in transition. Three categories of measures and their implications for pharmaceutical policy cost containing are analyzed: supply-side measures, targeting manufacturers, proxy demand-side measures, targeting physicians and pharmacists, and demand-side measures, targeting patients. In pursuing supply side measures, we explore free pricing for pharmaceuticals, direct price controls, cost-plus and cost pricing, average pricing and international price comparisons, profit control, reference pricing, the introduction of a fourth hurdle, positive and negative lists, and other price control measures. The analysis of proxy-demand measures includes budgets for physicians, generic policies, practice guidelines, monitoring the authorizing behavior of physicians, and disease management schemes. Demand-side measures explore the effectiveness of patient co-payments, the impact of allowing products over-the-counter and health promotion programs. Global policies should operate simultaneously on the supply, the proxy demand, and the demand-side. Policy-making needs to have a continuous long-term planning. The importation of policies into transition economy may require extensive and expensive adaptation, and/or lead to sub-optimal policy outcomes.

  15. Trust Transitivity in Social Networks

    PubMed Central

    Richters, Oliver; Peixoto, Tiago P.

    2011-01-01

    Non-centralized recommendation-based decision making is a central feature of several social and technological processes, such as market dynamics, peer-to-peer file-sharing and the web of trust of digital certification. We investigate the properties of trust propagation on networks, based on a simple metric of trust transitivity. We investigate analytically the percolation properties of trust transitivity in random networks with arbitrary in/out-degree distributions, and compare with numerical realizations. We find that the existence of a non-zero fraction of absolute trust (i.e. entirely confident trust) is a requirement for the viability of global trust propagation in large systems: The average pair-wise trust is marked by a discontinuous transition at a specific fraction of absolute trust, below which it vanishes. Furthermore, we perform an extensive analysis of the Pretty Good Privacy (PGP) web of trust, in view of the concepts introduced. We compare different scenarios of trust distribution: community- and authority-centered. We find that these scenarios lead to sharply different patterns of trust propagation, due to the segregation of authority hubs and densely-connected communities. While the authority-centered scenario is more efficient, and leads to higher average trust values, it favours weakly-connected “fringe” nodes, which are directly trusted by authorities. The community-centered scheme, on the other hand, favours nodes with intermediate in/out-degrees, in detriment of the authorities and its “fringe” peers. PMID:21483683

  16. Transition physics and scaling overview

    SciTech Connect

    Carlstrom, T.N.

    1995-12-01

    This paper presents an overview of recent experimental progress towards understanding H-mode transition physics and scaling. Terminology and techniques for studying H-mode are reviewed and discussed. The model of shear E x B flow stabilization of edge fluctuations at the L-H transition is gaining wide acceptance and is further supported by observations of edge rotation on a number of new devices. Observations of poloidal asymmetries of edge fluctuations and dephasing of density and potential fluctuations after the transition pose interesting challenges for understanding H-mode physics. Dedicated scans to determine the scaling of the power threshold have now been performed on many machines. A dear B{sub t} dependence is universally observed but dependence on the line averaged density is complicated. Other dependencies are also reported. Studies of the effect of neutrals and error fields on the power threshold are under investigation. The ITER threshold database has matured and offers guidance to the power threshold scaling issues relevant to next-step devices.

  17. Transit times in turbulent flows.

    PubMed

    Pécseli, H L; Trulsen, J

    2010-04-01

    Statistics of the motion of passively convected point particles in turbulent flows are studied. The database used is obtained by direct numerical solution of the Navier-Stokes equation. We estimate the probability distribution of the transit times of such particles through reference volumes with given forms and sizes. A selected position within the reference volume is moving with the local flow velocity, thus determining the motion of the entire surface. The transit time is defined as the interval between entrance and exit times of surrounding particles convected through the volume by the turbulent motions. Spherical as well as hemispherical surfaces are studied. Scale sizes in the inertial as well as in the viscous subranges of the turbulence are considered. Simple, and seemingly universal, scaling laws are obtained for the probability density of the transit times in terms of the basic properties of the turbulent flow and the geometry. In the present formulation, the results of the analysis are relevant for chemical reactions, but also for understanding details of the feeding rate of micro-organisms in turbulent waters, for instance.

  18. Search For Planetary Transits in Auriga

    NASA Astrophysics Data System (ADS)

    Mandushev, G. I.; Dunham, E. W.; Latham, D. W.; Everett, M.

    2007-07-01

    We report the results of an extensive, three-year search for planetary transits in a Milky Way field in the constellation of Auriga. More than 60 objects with transit-like events in their light curves were detected. Photometric and spectroscopic follow-up observations were carried out on the most promising transit candidates. Despite the large number of candidates, so far none of them has been found to be a transiting planet.

  19. Microscopic Description of Nuclear Quantum Phase Transitions

    SciTech Connect

    Niksic, T.; Vretenar, D.; Lalazissis, G. A.; Ring, P.

    2007-08-31

    The relativistic mean-field framework, extended to include correlations related to restoration of broken symmetries and to fluctuations of the quadrupole deformation, is applied to a study of shape transitions in Nd isotopes. It is demonstrated that the microscopic self-consistent approach, based on global effective interactions, can describe not only general features of transitions between spherical and deformed nuclei, but also the singular properties of excitation spectra and transition rates at the critical point of quantum shape phase transition.

  20. Planets in Transit V Passages of Discovery

    NASA Astrophysics Data System (ADS)

    Castellano, T. P.

    2003-05-01

    Eclipses of the Sun have long influenced culture, history, and science. The analogous but much more subtle phenomena of a transit of the Sun by Mercury was first predicted by Johannes Kepler. Soon, predictions of transits of Venus inspired bold expeditions to better understand the scale of our solar system. These passages of discovery sometimes succeeded scientifically but always captured the public imagination and played an unexpected role in history. The possibility of detecting planets outside the solar system by the transit method was first outlined by Otto Struve in 1952. Early inquiries usually assumed that extrasolar planetary systems would have a distribution of planetary radii and orbital sizes like the solar system. The detection of transits from the ground in such systems would be daunting. The recent, unexpected discovery of a class of extrasolar planets (by the radial velocity technique) with orbital periods less than a week and masses near to the planet Jupiter has resulted in a resurgence of interest in the transit method. These so called "hot Jupiters", can produce transits that are likely enough, frequent enough, the transit method. These so called "hot Jupiters", can produce transits that are likely enough, frequent enough, and deep enough that ground-based transit searches can be successful. In November 1999, a planet orbiting the star HD 209458 was found to transit, and many measurements of the transit have since been made that challenge formation and evolution theories. Numerous ground based searches for transits are now underway. Several planned high precision space-based missions designed to detect transits of earth-sized planets, also have the potential to detect transits of hundreds of "hot Jupiters". These efforts and the upcoming transit of the Sun by Venus on June 8, 2004 present an opportunity for transits to once again capture the public imagination and perhaps play a role in history.

  1. Current fluctuations at a phase transition

    NASA Astrophysics Data System (ADS)

    Gerschenfeld, A.; Derrida, B.

    2011-10-01

    The ABC model is a simple diffusive one-dimensional non-equilibrium system which exhibits a phase transition. Here we show that the cumulants of the currents of particles through the system become singular near the phase transition. At the transition, they exhibit an anomalous dependence on the system size (an anomalous Fourier's law). An effective theory for the dynamics of the single mode which becomes unstable at the transition allows one to predict this anomalous scaling.

  2. 9 CFR 332.12 - Transition grants.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 9 Animals and Animal Products 2 2014-01-01 2014-01-01 false Transition grants. 332.12 Section 332... CARCASSES, MEAT, AND MEAT FOOD PRODUCTS § 332.12 Transition grants. (a) Transition grants are funds that a... grant must use grant funds to reimburse the training costs of one employee per each...

  3. 9 CFR 381.522 - Transition grants.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 9 Animals and Animal Products 2 2014-01-01 2014-01-01 false Transition grants. 381.522 Section 381... Interstate Shipment of Poultry Products § 381.522 Transition grants. (a) Transition grants are funds that a... grant must use grant funds to reimburse the training costs of one employee per each...

  4. Lost in Transition? Student Food Consumption

    ERIC Educational Resources Information Center

    Blichfeldt, Bodil Stilling; Gram, Malene

    2013-01-01

    Findings from transition studies as well as studies of student food show that the transition from living at home to independent living influences student food consumption and that food consumption might be problematic during this period. Furthermore, both students' enactment of being in transition and the food habits and practices they bring with…

  5. 33 CFR 401.89 - Transit refused.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 33 Navigation and Navigable Waters 3 2011-07-01 2011-07-01 false Transit refused. 401.89 Section... TRANSPORTATION SEAWAY REGULATIONS AND RULES Regulations General § 401.89 Transit refused. (a) An officer may refuse to allow a vessel to transit when, (1) The vessel is not equipped in accordance with §§ 401.5...

  6. 33 CFR 401.89 - Transit refused.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 33 Navigation and Navigable Waters 3 2012-07-01 2012-07-01 false Transit refused. 401.89 Section... TRANSPORTATION SEAWAY REGULATIONS AND RULES Regulations General § 401.89 Transit refused. (a) An officer may refuse to allow a vessel to transit when, (1) The vessel is not equipped in accordance with §§ 401.5...

  7. 33 CFR 401.89 - Transit refused.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 33 Navigation and Navigable Waters 3 2014-07-01 2014-07-01 false Transit refused. 401.89 Section... TRANSPORTATION SEAWAY REGULATIONS AND RULES Regulations General § 401.89 Transit refused. (a) An officer may refuse to allow a vessel to transit when, (1) The vessel is not equipped in accordance with §§ 401.5...

  8. 33 CFR 401.89 - Transit refused.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 33 Navigation and Navigable Waters 3 2010-07-01 2010-07-01 false Transit refused. 401.89 Section... TRANSPORTATION SEAWAY REGULATIONS AND RULES Regulations General § 401.89 Transit refused. (a) An officer may refuse to allow a vessel to transit when, (1) The vessel is not equipped in accordance with §§ 401.5...

  9. 33 CFR 401.89 - Transit refused.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 33 Navigation and Navigable Waters 3 2013-07-01 2013-07-01 false Transit refused. 401.89 Section... TRANSPORTATION SEAWAY REGULATIONS AND RULES Regulations General § 401.89 Transit refused. (a) An officer may refuse to allow a vessel to transit when, (1) The vessel is not equipped in accordance with §§ 401.5...

  10. School to Work: Making the Transition.

    ERIC Educational Resources Information Center

    Academy for Educational Development, Washington, DC. National Inst. for Work and Learning.

    This publication describes the Academy for Educational Development's (AED's) vision and work in school-to-work transition and related areas. School-to-work transition is defined, and components of a successful school-to-work transition system are listed. The National Institute for Work and Learning (NIWL) is currently conducting an extensive study…

  11. 9 CFR 332.12 - Transition grants.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 9 Animals and Animal Products 2 2012-01-01 2012-01-01 false Transition grants. 332.12 Section 332... CARCASSES, MEAT, AND MEAT FOOD PRODUCTS § 332.12 Transition grants. (a) Transition grants are funds that a... grant must use grant funds to reimburse the training costs of one employee per each...

  12. 9 CFR 381.522 - Transition grants.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 9 Animals and Animal Products 2 2012-01-01 2012-01-01 false Transition grants. 381.522 Section 381... Interstate Shipment of Poultry Products § 381.522 Transition grants. (a) Transition grants are funds that a... grant must use grant funds to reimburse the training costs of one employee per each...

  13. A Latent Transition Model with Logistic Regression

    ERIC Educational Resources Information Center

    Chung, Hwan; Walls, Theodore A.; Park, Yousung

    2007-01-01

    Latent transition models increasingly include covariates that predict prevalence of latent classes at a given time or transition rates among classes over time. In many situations, the covariate of interest may be latent. This paper describes an approach for handling both manifest and latent covariates in a latent transition model. A Bayesian…

  14. TRANSITION WITHOUT TRAGEDY, A COMMUNITY PREPARATION HANDBOOK.

    ERIC Educational Resources Information Center

    ROBIN, FLORENCE

    SOUTHERN COMMUNITIES ARE IN A PERIOD OF TRANSITION TOWARD AN INTEGRATED SOCIETY. IT IS THE CHOICE OF EVERY COMMUNITY WHETHER OR NOT THIS TRANSITION WILL EVOLVE PEACEFULLY OR WHETHER IT WILL BE RESISTED WITH VIOLENT AND TRAGIC RESULTS. IF THE DECISION FOR A PEACEFUL TRANSITION IS MADE, EXAMPLES OF SUCCESSFUL TECHNIQUES, EXPERIENCES, AND EFFORTS IN…

  15. No Wasted Moments: Planning Purposeful Transitions

    ERIC Educational Resources Information Center

    Nicolucci, Sandra

    2010-01-01

    This article focuses on the nature of the "transitional minutes" in "any" music class. When transitional minutes before, during, and after rehearsals and classes are unplanned and left to chance, much viable and valuable teaching time is lost. When transitional minutes are well structured, learning can proceed efficiently. One…

  16. 45 CFR 618.230 - Transition plans.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 45 Public Welfare 3 2010-10-01 2010-10-01 false Transition plans. 618.230 Section 618.230 Public... Coverage § 618.230 Transition plans. (a) Submission of plans. An institution to which § 618.225 applies and... plan applicable to all such units, or a separate transition plan applicable to each such unit....

  17. 34 CFR 106.17 - Transition plans.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 34 Education 1 2010-07-01 2010-07-01 false Transition plans. 106.17 Section 106.17 Education... Coverage § 106.17 Transition plans. (a) Submission of plans. An institution to which § 106.16 applies and... plan applicable to all such units, or a separate transition plan applicable to each such unit....

  18. 31 CFR 28.230 - Transition plans.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 31 Money and Finance: Treasury 1 2010-07-01 2010-07-01 false Transition plans. 28.230 Section 28... Transition plans. (a) Submission of plans. An institution to which § 28.225 applies and that is composed of more than one administratively separate unit may submit either a single transition plan applicable...

  19. 45 CFR 618.230 - Transition plans.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 45 Public Welfare 3 2013-10-01 2013-10-01 false Transition plans. 618.230 Section 618.230 Public... Coverage § 618.230 Transition plans. (a) Submission of plans. An institution to which § 618.225 applies and... plan applicable to all such units, or a separate transition plan applicable to each such unit....

  20. 40 CFR 7.75 - Transition plan.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 1 2014-07-01 2014-07-01 false Transition plan. 7.75 Section 7.75... of Handicap § 7.75 Transition plan. If structural changes to facilities are necessary to make the program or activity accessible to handicapped persons, a recipient must prepare a transition plan....

  1. 24 CFR 3.230 - Transition plans.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 24 Housing and Urban Development 1 2014-04-01 2014-04-01 false Transition plans. 3.230 Section 3... Coverage § 3.230 Transition plans. (a) Submission of plans. An institution to which § 3.225 applies and... plan applicable to all such units, or a separate transition plan applicable to each such unit....

  2. 31 CFR 28.230 - Transition plans.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 31 Money and Finance: Treasury 1 2012-07-01 2012-07-01 false Transition plans. 28.230 Section 28... Transition plans. (a) Submission of plans. An institution to which § 28.225 applies and that is composed of more than one administratively separate unit may submit either a single transition plan applicable...

  3. 34 CFR 106.17 - Transition plans.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 34 Education 1 2014-07-01 2014-07-01 false Transition plans. 106.17 Section 106.17 Education... Coverage § 106.17 Transition plans. (a) Submission of plans. An institution to which § 106.16 applies and... plan applicable to all such units, or a separate transition plan applicable to each such unit....

  4. 38 CFR 23.230 - Transition plans.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 38 Pensions, Bonuses, and Veterans' Relief 2 2013-07-01 2013-07-01 false Transition plans. 23.230... Coverage § 23.230 Transition plans. (a) Submission of plans. An institution to which § 23.225 applies and... plan applicable to all such units, or a separate transition plan applicable to each such unit....

  5. 45 CFR 86.17 - Transition plans.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 45 Public Welfare 1 2013-10-01 2013-10-01 false Transition plans. 86.17 Section 86.17 Public... Transition plans. (a) Submission of plans. An institution to which § 86.16 applies and which is composed of more than one administratively separate unit may submit either a single transition plan applicable...

  6. 15 CFR 8a.230 - Transition plans.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 15 Commerce and Foreign Trade 1 2014-01-01 2014-01-01 false Transition plans. 8a.230 Section 8a... Transition plans. (a) Submission of plans. An institution to which § 8a.225 applies and that is composed of more than one administratively separate unit may submit either a single transition plan applicable...

  7. 15 CFR 8a.230 - Transition plans.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 15 Commerce and Foreign Trade 1 2012-01-01 2012-01-01 false Transition plans. 8a.230 Section 8a... Transition plans. (a) Submission of plans. An institution to which § 8a.225 applies and that is composed of more than one administratively separate unit may submit either a single transition plan applicable...

  8. 24 CFR 3.230 - Transition plans.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 24 Housing and Urban Development 1 2013-04-01 2013-04-01 false Transition plans. 3.230 Section 3... Coverage § 3.230 Transition plans. (a) Submission of plans. An institution to which § 3.225 applies and... plan applicable to all such units, or a separate transition plan applicable to each such unit....

  9. Vulnerable Youth and Transitions to Adulthood

    ERIC Educational Resources Information Center

    Xie, Rongbing; Sen, Bisakha; Foster, E. Michael

    2014-01-01

    This chapter focuses on vulnerable youth, the challenges they face during their transitions to adulthood, and the adverse effects of limited support systems on those transitions. The authors offer recommendations on how adult educators can help facilitate smooth transitions into adulthood for vulnerable youth.

  10. Analysis of abrupt transitions in ecological systems

    Technology Transfer Automated Retrieval System (TEKTRAN)

    The occurrence and causes of abrupt transitions, thresholds, or regime shifts between ecosystem states are of great concern and the likelihood of such transitions is increasing for many ecological systems. General understanding of abrupt transitions has been advanced by theory, but hindered by the l...

  11. 24 CFR 3.230 - Transition plans.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 24 Housing and Urban Development 1 2011-04-01 2011-04-01 false Transition plans. 3.230 Section 3... Coverage § 3.230 Transition plans. (a) Submission of plans. An institution to which § 3.225 applies and... plan applicable to all such units, or a separate transition plan applicable to each such unit....

  12. 31 CFR 28.230 - Transition plans.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 31 Money and Finance: Treasury 1 2011-07-01 2011-07-01 false Transition plans. 28.230 Section 28... Transition plans. (a) Submission of plans. An institution to which § 28.225 applies and that is composed of more than one administratively separate unit may submit either a single transition plan applicable...

  13. 45 CFR 86.17 - Transition plans.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 45 Public Welfare 1 2011-10-01 2011-10-01 false Transition plans. 86.17 Section 86.17 Public... Transition plans. (a) Submission of plans. An institution to which § 86.16 applies and which is composed of more than one administratively separate unit may submit either a single transition plan applicable...

  14. 45 CFR 618.230 - Transition plans.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 45 Public Welfare 3 2011-10-01 2011-10-01 false Transition plans. 618.230 Section 618.230 Public... Coverage § 618.230 Transition plans. (a) Submission of plans. An institution to which § 618.225 applies and... plan applicable to all such units, or a separate transition plan applicable to each such unit....

  15. 13 CFR 113.230 - Transition plans.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 13 Business Credit and Assistance 1 2011-01-01 2011-01-01 false Transition plans. 113.230 Section... Coverage § 113.230 Transition plans. (a) Submission of plans. An institution to which § 113.225 applies and... plan applicable to all such units, or a separate transition plan applicable to each such unit....

  16. Evidence-Based Practices in Secondary Transition

    ERIC Educational Resources Information Center

    Test, David W.; Fowler, Catherine H.; Richter, Sharon M.; White, James; Mazzotti, Valerie; Walker, Allison R.; Kohler, Paula; Kortering, Larry

    2009-01-01

    A literature review was conducted to identify evidence-based practices in secondary transition using quality indicator checklists for experimental research. Practices were categorized by the Taxonomy for Transition Programming. Overall, 32 secondary transition evidence-based practices were identified. Two practices had a strong level of evidence,…

  17. Research in bus and rail transit operations

    SciTech Connect

    Chatterjee, A.; Wegmann, F.J.; Ceder, A.; Levinson, H.S.; Hollander, A.

    1989-01-01

    The 10 papers in the report deal with the following areas: Private Sector Involvement in Sponsoring Sunday Bus Service; Optimal Design of Transit Short-Turn Trips; New York City's Unfranchised Buses: Case Study in Deregulation; Critical Factors in Planning Multimodal Passenger Terminals; Use of Travelers' Attitudes in Rail Service Design; Driven, Attended, and Fully Automated Transit; Qualitative Comparison; Impact on Transit Patronage of Cessation or Inauguration of Rail Service; Use of Productivity Factors in Estimating LRT Operating Costs; Simulation Study To Evaluate Spare Ratios in Bus Transit Systems; Statistical Evaluation of Spare Ratio in Transit Rolling Stock.

  18. Some Scenarios for Transition on Turbomachinery Blading

    NASA Technical Reports Server (NTRS)

    Gostelow, J. P.

    2007-01-01

    Measurements on transition under different levels of adverse pressure gradient and free-stream turbulence level are described. This extensive series of investigations, which was predicated on intermittency measurement techniques, has resulted in correlations for transition length and turbulent spot formation rate. These correlations rae intended to be used in conjunction with boundary layer prediction methods and examples are given of such predictions. More effective predictions of the transition region, especially under conditions of variable pressure gradient, are dependent on a more comprehensive understanding of transition and spot behavior. It is expected that this will result in improved transition modeling.

  19. Work and quantum phase transitions: quantum latency.

    PubMed

    Mascarenhas, E; Bragança, H; Dorner, R; França Santos, M; Vedral, V; Modi, K; Goold, J

    2014-06-01

    We study the physics of quantum phase transitions from the perspective of nonequilibrium thermodynamics. For first-order quantum phase transitions, we find that the average work done per quench in crossing the critical point is discontinuous. This leads us to introduce the quantum latent work in analogy with the classical latent heat of first order classical phase transitions. For second order quantum phase transitions the irreversible work is closely related to the fidelity susceptibility for weak sudden quenches of the system Hamiltonian. We demonstrate our ideas with numerical simulations of first, second, and infinite order phase transitions in various spin chain models.

  20. Dynamics of a Quantum Phase Transition

    SciTech Connect

    Zurek, Wojciech H.; Dorner, Uwe; Zoller, Peter

    2005-09-02

    We present two approaches to the dynamics of a quench-induced phase transition in the quantum Ising model. One follows the standard treatment of thermodynamic second order phase transitions but applies it to the quantum phase transitions. The other approach is quantum, and uses Landau-Zener formula for transition probabilities in avoided level crossings. We show that predictions of the two approaches of how the density of defects scales with the quench rate are compatible, and discuss the ensuing insights into the dynamics of quantum phase transitions.

  1. Electronic transitions and multiferroicity in transition metal oxides

    NASA Astrophysics Data System (ADS)

    Zhou, Haidong

    Four systems have been studied for the localized-itinerant electronic transition in transition-metal oxides: (i) In CaV1- xTixO3, substitution of Ti(IV) introduces Anderson-localized states below a mobility edge mu c that increases with x, crossing epsilon F in the range 0.2 < x< 0.4 and also transforms the strong-correlation fluctuations to localized V(IV): t1e0 configurations for x ≥ 0.1. (ii) The properties of LaTiO3+delta reveal that a hole-poor, strongly correlated electronic phase coexists with a hole-rich, itinerant-electron phase. With delta ≥ 0.03, the hole-rich phase exists as a minority phase of isolated, mobile itinerant-electron clusters embedded in the hole-poor phase. With delta ≥ 0.08, isolated hole-poor clusters are embedded in an itinerant-electron matrix. As delta > 0.08 increases, the hole-poor clusters become smaller and more isolated until they are reduced to super-paramagnetic strong-correlation fluctuations by delta = 0.12. (iii) The data of Y1-xLaxTiO 3 appears to distinguish an itinerant-electron antiferromagnetic phase in the La-rich samples from a localized-electron ferromagnetic phase with a cooperative Jahn-Teller distortion in the Y-rich phase. (iv) The transition at Tt in Mg[Ti2]O4 is a semiconductor-semiconductor transition associated with Ti-Ti dimerization instabilities. The dimerization is caused by lattice instabilities resulting from a double-well Ti-Ti bond potential at a crossover from localized to itinerant electronic behavior. RMn1-xGaxO 3 (R = Ho, Y) and Ho1-xY xMnO3 have been studied for the multiferroicity of RMnO3. Ga doping raises the ferrielectric Curie temperature TC and the Mn-spin reorientation temperature TSR while lowering TN of the Mn spins and the Ho magnetic ordering temperature T 2. The data show an important coupling between the Mn3+-ion and HO3+-ion spins as well as a TSR that is driven by a cooperative MnO5 site rotation and R 3+-ion displacements that modify the c lattice parameter. The data also

  2. Chemical Signposts in Transition Disks

    NASA Astrophysics Data System (ADS)

    Cleeves, I.; Bergin, E. A.; Fogel, J.

    2011-05-01

    In the era of the Kepler Mission, the detection of numerous multi-planet systems has demonstrated that planet-formation appears to be a rather ubiquitous phenomenon. Such systems are believed to form from nascent protoplanetary disks, whose environment sets the stage for initial planetary chemical composition and evolution. However, disk systems typically vary by orders of magnitude in radiation field, densities and temperatures, and thus complex disk models are necessary to fully understand this unique chemical environment. Further evidence for disks as progenitors to planetary systems comes from Spitzer surveys of young disk systems, which have revealed a class of objects known as ``transition disks''. These systems appear to have inner voids and gaps in the dust opacity, possibly indicative of planet evolution and disk clearing. This physical evolution in the dust disk will significantly impact its chemical nature, and therefore these potentially planet-forming systems in ``transition'' should have unique chemical signatures. We predict one such signature to be an active chemistry at the wall interface where the conditions are such that the disk is both heated and optically thick to the photo-dissociating UV. The net result is a wide variety of gas-phase molecules, appearing in line emission as bright molecular rings far from the central star. This behavior should also reveal a wealth of information about the physical conditions in this actively evolving zone between the inner ``cleared'' disk and the massive outer disk. For this presentation I will discuss the features of our disk chemical model pipeline and select model results of transition disk systems. I will also highlight the exciting future of protoplanetary disk chemistry in the era of ALMA, which will truly revolutionize our understanding of the chemical nature of disks.

  3. Transitional Care Strategies From Hospital to Home

    PubMed Central

    Ranji, Sumant R.

    2015-01-01

    Hospitals are challenged with reevaluating their hospital’s transitional care practices, to reduce 30-day readmission rates, prevent adverse events, and ensure a safe transition of patients from hospital to home. Despite the increasing attention to transitional care, there are few published studies that have shown significant reductions in readmission rates, particularly for patients with stroke and other neurologic diagnoses. Successful hospital-initiated transitional care programs include a “bridging” strategy with both predischarge and postdischarge interventions and dedicated transitions provider involved at multiple points in time. Although multicomponent strategies including patient engagement, use of a dedicated transition provider, and facilitation of communication with outpatient providers require time and resources, there is evidence that neurohospitalists can implement a transitional care program with the aim of improving patient safety across the continuum of care. PMID:25553228

  4. TERMS PHOTOMETRY OF KNOWN TRANSITING EXOPLANETS

    SciTech Connect

    Dragomir, Diana; Kane, Stephen R.; Ciardi, David R.; Gelino, Dawn M.; Payne, Alan; Ramirez, Solange V.; Von Braun, Kaspar; Wyatt, Pamela; Pilyavsky, Genady; Mahadevan, Suvrath; Wright, Jason T.; Zachary Gazak, J.; Rabus, Markus

    2011-10-15

    The Transit Ephemeris Refinement and Monitoring Survey conducts radial velocity and photometric monitoring of known exoplanets in order to refine planetary orbits and predictions of possible transit times. This effort is primarily directed toward planets not known to transit, but a small sample of our targets consists of known transiting systems. Here we present precision photometry for six WASP (Wide Angle Search for Planets) planets acquired during their transit windows. We perform a Markov Chain Monte Carlo analysis for each planet and combine these data with previous measurements to redetermine the period and ephemerides for these planets. These observations provide recent mid-transit times which are useful for scheduling future observations. Our results improve the ephemerides of WASP-4b, WASP-5b, and WASP-6b and reduce the uncertainties on the mid-transit time for WASP-29b. We also confirm the orbital, stellar, and planetary parameters of all six systems.

  5. Transitions, transversions, and the molecular evolutionary clock.

    PubMed

    Jukes, T H

    1987-01-01

    Nucleotide substitutions in the form of transitions (purine-purine or pyrimidine-pyrimidine interchanges) and transversions (purine-pyrimidine interchanges) occur during evolution and may be compiled by aligning the sequences of homologous genes. Referring to the genetic code tables, silent transitions take place in third positions of codons in family boxes and two-codon sets. Silent transversions in third positions occur only in family boxes, except for A = C transversions between AGR and CGR arginine codons (R = A or G). Comparisons of several protein genes have been made, and various subclasses of transitional and transversional nucleotide substitutions have been compiled. Considerable variations occur among the relative proportions of transitions and transversions. Such variations could possibly be caused by mutator genes, favoring either transitions or, conversely, transversions, during DNA replication. At earlier stages of evolutionary divergence, transitions are usually more frequent, but there are exceptions. No indication was found that transversions usually originate from multiple substitutions in transitions.

  6. Shim for sealing transition pieces

    DOEpatents

    Lacy, Benjamin Paul [Greer, SC; Demiroglu, Mehmet [Troy, NY; Sarawate, Neelesh Nandkumar [Niskayuna, NY

    2012-07-24

    According to one aspect of the invention, a shim for sealing two adjacent turbine transition pieces is disclosed. The shim includes a circumferential member that includes a first lateral flange and a second lateral flange. Further, the first and second lateral flanges each comprise a tab configured to mate to a first surface plane and the first and second lateral flanges are configured to mate to a second surface plane, wherein the first and second surface planes are substantially parallel. In addition, the shim includes a first flange extending substantially perpendicular from the circumferential member.

  7. Low floor mass transit vehicle

    DOEpatents

    Emmons, J. Bruce; Blessing, Leonard J.

    2004-02-03

    A mass transit vehicle includes a frame structure that provides an efficient and economical approach to providing a low floor bus. The inventive frame includes a stiff roof panel and a stiff floor panel. A plurality of generally vertical pillars extend between the roof and floor panels. A unique bracket arrangement is disclosed for connecting the pillars to the panels. Side panels are secured to the pillars and carry the shear stresses on the frame. A unique seating assembly that can be advantageously incorporated into the vehicle taking advantage of the load distributing features of the inventive frame is also disclosed.

  8. The Amazon basin in transition.

    PubMed

    Davidson, Eric A; de Araújo, Alessandro C; Artaxo, Paulo; Balch, Jennifer K; Brown, I Foster; C Bustamante, Mercedes M; Coe, Michael T; DeFries, Ruth S; Keller, Michael; Longo, Marcos; Munger, J William; Schroeder, Wilfrid; Soares-Filho, Britaldo S; Souza, Carlos M; Wofsy, Steven C

    2012-01-18

    Agricultural expansion and climate variability have become important agents of disturbance in the Amazon basin. Recent studies have demonstrated considerable resilience of Amazonian forests to moderate annual drought, but they also show that interactions between deforestation, fire and drought potentially lead to losses of carbon storage and changes in regional precipitation patterns and river discharge. Although the basin-wide impacts of land use and drought may not yet surpass the magnitude of natural variability of hydrologic and biogeochemical cycles, there are some signs of a transition to a disturbance-dominated regime. These signs include changing energy and water cycles in the southern and eastern portions of the Amazon basin.

  9. Conformational Transitions in Molecular Systems

    NASA Astrophysics Data System (ADS)

    Bachmann, M.; Janke, W.

    2008-11-01

    Proteins are the "work horses" in biological systems. In almost all functions specific proteins are involved. They control molecular transport processes, stabilize the cell structure, enzymatically catalyze chemical reactions; others act as molecular motors in the complex machinery of molecular synthetization processes. Due to their significance, misfolds and malfunctions of proteins typically entail disastrous diseases, such as Alzheimer's disease and bovine spongiform encephalopathy (BSE). Therefore, the understanding of the trinity of amino acid composition, geometric structure, and biological function is one of the most essential challenges for the natural sciences. Here, we glance at conformational transitions accompanying the structure formation in protein folding processes.

  10. 2008 Enterprise Transition Plan (ETP)

    DTIC Science & Technology

    2008-09-30

    bring things to a conclusion, or at least have things packaged in a way that they can easily transition to the next team. The best thing we can do for...Officer. As directed by the President’s Executive Order, the PIO, among other things , supervises the performance management activities of the...environment, EMALL will need to mature to a business to business ( B2B ) model. The B2C model presents a web-based front-end for purchasers, whereas the

  11. Transition state structures in solution

    SciTech Connect

    Bertran, J.; Lluch, J. M.; Gonzalez-Lafont, A.; Dillet, V.; Perez, V.

    1995-04-05

    In the present paper the location of transition state structures for reactions in solution has been studied. Continuum model calculations have been carried out on the Friedel-Crafts alkylation reaction and a proton transfer through a water molecule between two oxygen atoms in formic acid. In this model the separation between the chemical system and the solvent has been introduced. On the other hand, the discrete Monte Carlo methodology has also been used to simulate the solvent effect on dissociative electron transfer processes. In this model, the hypothesis of separability is not assumed. Finally, the validity of both approaches is discussed.

  12. Transition state structures in solution

    NASA Astrophysics Data System (ADS)

    Bertrán, J.; Lluch, J. M.; Gonzàlez-Lafont, A.; Dillet, V.; Pérez, V.

    1995-04-01

    In the present paper the location of transition state structures for reactions in solution has been studied. Continuum model calculations have been carried out on the Friedel-Crafts alkylation reaction and a proton transfer through a water molecule between two oxygen atoms in formic acid. In this model the separation between the chemical system and the solvent has been introduced. On the other hand, the discrete Monte Carlo methodology has also been used to simulate the solvent effect on dissociative electron transfer processes. In this model, the hypothesis of separability is not assumed. Finally, the validity of both approaches is discussed.

  13. Radiative transitions in metallic nanoclusters

    NASA Astrophysics Data System (ADS)

    Shalin, A. S.

    2008-02-01

    In this article, a new theoretical approach to studying light-scattering characteristics of nanosized objects based on the solution to the Thomas-Fermi equation and quasi-classical approximation is considered. It is shown that the distribution of valence electrons in the volume of metallic clusters exhibits a specific structure of "spatial zones." With the aid of quasi-classical wave functions, expressions for the appropriate dipole moments of the transitions between the ground and excited states are obtained; the behavior of the spectrum of gold clusters depending on their sizes is studied; a comparison with existing experimental data is carried out.

  14. Transition section for acoustic waveguides

    DOEpatents

    Karplus, H.H.B.

    1975-10-28

    A means of facilitating the transmission of acoustic waves with minimal reflection between two regions having different specific acoustic impedances is described comprising a region exhibiting a constant product of cross-sectional area and specific acoustic impedance at each cross-sectional plane along the axis of the transition region. A variety of structures that exhibit this feature is disclosed, the preferred embodiment comprising a nested structure of doubly reentrant cones. This structure is useful for monitoring the operation of nuclear reactors in which random acoustic signals are generated in the course of operation.

  15. Nutrition transition and food sustainability.

    PubMed

    Belahsen, Rekia

    2014-08-01

    The aim of the present paper is to review nutrition transition (NT) ongoing in low and middle income countries and the associated dietary changes. NT is accompanied by demographic and epidemiological transition associated with economic development and urbanisation. In these countries, while the problems of hunger and undernourishment persist, there is an escalation of diet-related non-communicable diseases; making them face both problems of malnutrition, under and overnutrition. Indeed, in addition to protein energy malnutrition underweight and micronutrient deficiencies affect a high proportion of children and women. Conversely, changes in dietary habits and physical activity patterns have led to emergence of chronic diseases such as obesity, diabetes, hypertension, stroke, hyperlipidaemia, CHD and cancer. One possible explanation of weight gain and its associated health consequences is the trend of the consumption of already prepared meals and the restaurants that are in continuous development leading to high consumption of foods rich in sugar and fat. The health problems associated with NT have not spared populations in the Mediterranean area where the type of diet is reported to be healthy and to protect against cardiovascular risks. This is seen in North Africa that belongs also to the Mediterranean basin, where the nutritional situation raises the problem of traditional foods sustainability. Accurate nutritional policy and education are needed to redress the effects of malnutrition related to NT on health.

  16. Electronic transitions of tantalum monofluoride

    NASA Astrophysics Data System (ADS)

    Ng, K. F.; Zou, Wenli; Liu, Wenjian; Cheung, A. S.-C.

    2017-03-01

    The electronic transition spectrum of the tantalum monofluoride (TaF) molecule in the spectral region between 448 and 560 nm has been studied using the technique of laser-ablation/reaction free jet expansion and laser induced fluorescence spectroscopy. The TaF molecule was produced by reacting laser-ablated tantalum atoms with sulfur hexafluoride gas seeded in argon. Twenty-two vibrational bands with resolved rotational structure have been recorded and analyzed, which were organized into seven electronic transitions. The X3Σ-(0+) state has been identified to be the ground state and the determined equilibrium bond length, re, and vibrational frequency, ωe, are 1.8184 Å and 700.1 cm-1, respectively. The low-lying Λ-S states and Ω sub-states of TaF were also theoretically studied at the MRCISD+Q level of theory with spin-orbit coupling. The Ω = 0+ and 2 sub-states from the -3Σ and 3Φ state have been found to be the ground and the first excited states, respectively, which agrees well with our experimental determinations. This work represents the first experimental investigation of the molecular structure of the TaF molecule.

  17. Gardner transition in finite dimensions

    NASA Astrophysics Data System (ADS)

    Urbani, Pierfrancesco; Biroli, Giulio

    2015-03-01

    Recent works on hard spheres in the limit of infinite dimensions revealed that glass states, envisioned as metabasins in configuration space, can break up in a multitude of separate basins at low enough temperature or high enough pressure, leading to the emergence of new kinds of soft-modes and unusual properties. In this paper we study by perturbative renormalization group techniques the critical properties of this transition, which has been discovered in disordered mean-field models in the 1980s. We find that the upper-critical dimension du, above which mean-field results hold, is strictly larger than six and apparently nonuniversal, i.e., system dependent. Below du, we do not find any perturbative attractive fixed point (except for a tiny region of the one-step replica symmetry breaking parameter), thus showing that the transition in three dimensions either is governed by a nonperturbative fixed point unrelated to the Gaussian mean-field one or becomes first order or does not exist. We also discuss possible relationships with the behavior of spin glasses in a field.

  18. Dynamic transition in supercritical iron

    PubMed Central

    Fomin, Yu. D.; Ryzhov, V. N.; Tsiok, E. N.; Brazhkin, V. V.; Trachenko, K.

    2014-01-01

    Recent advance in understanding the supercritical state posits the existence of a new line above the critical point separating two physically distinct states of matter: rigid liquid and non-rigid gas-like fluid. The location of this line, the Frenkel line, remains unknown for important real systems. Here, we map the Frenkel line on the phase diagram of supercritical iron using molecular dynamics simulations. On the basis of our data, we propose a general recipe to locate the Frenkel line for any system, the recipe that importantly does not involve system-specific detailed calculations and relies on the knowledge of the melting line only. We further discuss the relationship between the Frenkel line and the metal-insulator transition in supercritical liquid metals. Our results enable predicting the state of supercritical iron in several conditions of interest. In particular, we predict that liquid iron in the Jupiter core is in the “rigid liquid” state and is highly conducting. We finally analyse the evolution of iron conductivity in the core of smaller planets such as Earth and Venus as well as exoplanets: as planets cool off, the supercritical core undergoes the transition to the rigid-liquid conducting state at the Frenkel line. PMID:25424664

  19. Transit Fixatives: An Innovative Study

    PubMed Central

    A, Ravi Prakash; G, Sreenath; JK, Sonia Bai; NDVN, Shyam

    2015-01-01

    Background: Universally accepted fixative is 10% formalin which has been used for preserving the tissues and their architecture. In certain conditions, formalin might not be readily available for immediate fixation. We here by explore more economical, eco-friendly and easily available solutions that can be used as transit media/ transporting media for tissue specimens. Materials and Methods: The study included commonly available solutions like Spirit, Saline, Betadine solution, Hydrogen peroxide (H2O2), Local anesthesia (L.A), Rose water, Coconut oil, Coconut water, Ice cold water, Honey and Milk while keeping formalin as control. The fresh tissue sample was cut into multiple bits and placed in different containers for a period of 8 hours before transferring to formalin solution. Conclusion: Transit fixatives are very important in certain situations where formalin is not readily available. These fixatives can be used to fix the tissues for a period of at least 8 hours without causing any damage or distortion before they are fixed in formalin solution. PMID:25954725

  20. Elaborating transition interface sampling methods

    SciTech Connect

    Erp, Titus S. van . E-mail: bolhuis@science.uva.nl

    2005-05-01

    We review two recently developed efficient methods for calculating rate constants of processes dominated by rare events in high-dimensional complex systems. The first is transition interface sampling (TIS), based on the measurement of effective fluxes through hypersurfaces in phase space. TIS improves efficiency with respect to standard transition path sampling (TPS) rate constant techniques, because it allows a variable path length and is less sensitive to recrossings. The second method is the partial path version of TIS. Developed for diffusive processes, it exploits the loss of long time correlation. We discuss the relation between the new techniques and the standard reactive flux methods in detail. Path sampling algorithms can suffer from ergodicity problems, and we introduce several new techniques to alleviate these problems, notably path swapping, stochastic configurational bias Monte Carlo shooting moves and order-parameter free path sampling. In addition, we give algorithms to calculate other interesting properties from path ensembles besides rate constants, such as activation energies and reaction mechanisms.

  1. Family transitions in young adulthood.

    PubMed

    Schoen, Robert; Landale, Nancy S; Daniels, Kimberly

    2007-11-01

    Using the first (1995) and third (2001-2002) waves of the Add Health survey, we examine women 's family transitions up to age 24. Only a third of all women marry, and a fifth of those marriages dissolve before age 24. Three out of eight women have afirst birth, with a substantial majority of those births outside of marriage: 66% for whites, 96% for blacks, and 72% for Mexican Americans. Cohabitation is the predominant union form; 59% of women cohabit at least once by age 24. Most cohabitations are short lived, with approximately one in five resulting in a marriage. We summarize the family and relationship experience of women up to age 24 in terms offour categories, each accounting for roughly a quarter of all women. Category 1 has the women who remain single nonparents. Category 2 has the early marriers, women whose marriage is not preceded by a first birth. Category 3 has those who become single parents. Category 4 has the women who cohabit at least once, but who do not marry or have a birth by age 24. The strictly ordered transitions of the 1950s are long gone and have been replaced by a variety of paths to adulthood.

  2. Dynamic transition in supercritical iron.

    PubMed

    Fomin, Yu D; Ryzhov, V N; Tsiok, E N; Brazhkin, V V; Trachenko, K

    2014-11-26

    Recent advance in understanding the supercritical state posits the existence of a new line above the critical point separating two physically distinct states of matter: rigid liquid and non-rigid gas-like fluid. The location of this line, the Frenkel line, remains unknown for important real systems. Here, we map the Frenkel line on the phase diagram of supercritical iron using molecular dynamics simulations. On the basis of our data, we propose a general recipe to locate the Frenkel line for any system, the recipe that importantly does not involve system-specific detailed calculations and relies on the knowledge of the melting line only. We further discuss the relationship between the Frenkel line and the metal-insulator transition in supercritical liquid metals. Our results enable predicting the state of supercritical iron in several conditions of interest. In particular, we predict that liquid iron in the Jupiter core is in the "rigid liquid" state and is highly conducting. We finally analyse the evolution of iron conductivity in the core of smaller planets such as Earth and Venus as well as exoplanets: as planets cool off, the supercritical core undergoes the transition to the rigid-liquid conducting state at the Frenkel line.

  3. Photochemistry of Transition Metal Hydrides.

    PubMed

    Perutz, Robin N; Procacci, Barbara

    2016-08-10

    Photochemical reactivity associated with metal-hydrogen bonds is widespread among metal hydride complexes and has played a critical part in opening up C-H bond activation. It has been exploited to design different types of photocatalytic reactions and to obtain NMR spectra of dilute solutions with a single pulse of an NMR spectrometer. Because photolysis can be performed on fast time scales and at low temperature, metal-hydride photochemistry has enabled determination of the molecular structure and rates of reaction of highly reactive intermediates. We identify five characteristic photoprocesses of metal monohydride complexes associated with the M-H bond, of which the most widespread are M-H homolysis and R-H reductive elimination. For metal dihydride complexes, the dominant photoprocess is reductive elimination of H2. Dihydrogen complexes typically lose H2 photochemically. The majority of photochemical reactions are likely to be dissociative, but hydride complexes may be designed with equilibrated excited states that undergo different photochemical reactions, including proton transfer or hydride transfer. The photochemical mechanisms of a few reactions have been analyzed by computational methods, including quantum dynamics. A section on specialist methods (time-resolved spectroscopy, matrix isolation, NMR, and computational methods) and a survey of transition metal hydride photochemistry organized by transition metal group complete the Review.

  4. Dynamic transition in supercritical iron

    NASA Astrophysics Data System (ADS)

    Fomin, Yu. D.; Ryzhov, V. N.; Tsiok, E. N.; Brazhkin, V. V.; Trachenko, K.

    2014-11-01

    Recent advance in understanding the supercritical state posits the existence of a new line above the critical point separating two physically distinct states of matter: rigid liquid and non-rigid gas-like fluid. The location of this line, the Frenkel line, remains unknown for important real systems. Here, we map the Frenkel line on the phase diagram of supercritical iron using molecular dynamics simulations. On the basis of our data, we propose a general recipe to locate the Frenkel line for any system, the recipe that importantly does not involve system-specific detailed calculations and relies on the knowledge of the melting line only. We further discuss the relationship between the Frenkel line and the metal-insulator transition in supercritical liquid metals. Our results enable predicting the state of supercritical iron in several conditions of interest. In particular, we predict that liquid iron in the Jupiter core is in the ``rigid liquid'' state and is highly conducting. We finally analyse the evolution of iron conductivity in the core of smaller planets such as Earth and Venus as well as exoplanets: as planets cool off, the supercritical core undergoes the transition to the rigid-liquid conducting state at the Frenkel line.

  5. STELLAR TRANSITS IN ACTIVE GALACTIC NUCLEI

    SciTech Connect

    Beky, Bence; Kocsis, Bence E-mail: bkocsis@cfa.harvard.edu

    2013-01-01

    Supermassive black holes (SMBHs) are typically surrounded by a dense stellar population in galactic nuclei. Stars crossing the line of site in active galactic nuclei (AGNs) produce a characteristic transit light curve, just like extrasolar planets do when they transit their host star. We examine the possibility of finding such AGN transits in deep optical, UV, and X-ray surveys. We calculate transit light curves using the Novikov-Thorne thin accretion disk model, including general relativistic effects. Based on the expected properties of stellar cusps, we find that around 10{sup 6} solar mass SMBHs, transits of red giants are most common for stars on close orbits with transit durations of a few weeks and orbital periods of a few years. We find that detecting AGN transits requires repeated observations of thousands of low-mass AGNs to 1% photometric accuracy in optical, or {approx}10% in UV bands or soft X-ray. It may be possible to identify stellar transits in the Pan-STARRS and LSST optical and the eROSITA X-ray surveys. Such observations could be used to constrain black hole mass, spin, inclination, and accretion rate. Transit rates and durations could give valuable information on the circumnuclear stellar clusters as well. Transit light curves could be used to image accretion disks with unprecedented resolution, allowing us to resolve the SMBH silhouette in distant AGNs.

  6. THE QUASIPERIODIC AUTOMATED TRANSIT SEARCH ALGORITHM

    SciTech Connect

    Carter, Joshua A.; Agol, Eric

    2013-03-10

    We present a new algorithm for detecting transiting extrasolar planets in time-series photometry. The Quasiperiodic Automated Transit Search (QATS) algorithm relaxes the usual assumption of strictly periodic transits by permitting a variable, but bounded, interval between successive transits. We show that this method is capable of detecting transiting planets with significant transit timing variations without any loss of significance-{sup s}mearing{sup -}as would be incurred with traditional algorithms; however, this is at the cost of a slightly increased stochastic background. The approximate times of transit are standard products of the QATS search. Despite the increased flexibility, we show that QATS has a run-time complexity that is comparable to traditional search codes and is comparably easy to implement. QATS is applicable to data having a nearly uninterrupted, uniform cadence and is therefore well suited to the modern class of space-based transit searches (e.g., Kepler, CoRoT). Applications of QATS include transiting planets in dynamically active multi-planet systems and transiting planets in stellar binary systems.

  7. Research on Methods of Processing Transit IC Card Information and Constructing Transit OD Matrix

    NASA Astrophysics Data System (ADS)

    Han, Xiuhua; Li, Jin; Peng, Han

    Transit OD matrix is of vital importance when planning urban transit system. Traditional transit OD matrix constructing method needs a large range of spot check survey. It is expensive and needs long cycle time to process information. Recently transit IC card charging systems have been widely applied in big cities. Being processed reasonably, transit passenger information stored in IC card database can turn into information resource. It will reduce survey cost a lot. The concept of transit trip chain is put forward in this paper. According to the characteristics of closed transit trip chain, it discusses how to process IC card information and construct transit OD matrix. It also points out that urban transit information platform and data warehouse should be constructed, and how to integrate IC card information.

  8. Transition to turbulence: 2D directed percolation

    NASA Astrophysics Data System (ADS)

    Chantry, Matthew; Tuckerman, Laurette; Barkley, Dwight

    2016-11-01

    The transition to turbulence in simple shear flows has been studied for well over a century, yet in the last few years has seen major leaps forward. In pipe flow, this transition shows the hallmarks of (1 + 1) D directed percolation, a universality class of continuous phase transitions. In spanwisely confined Taylor-Couette flow the same class is found, suggesting the phenomenon is generic to shear flows. However in plane Couette flow the largest simulations and experiments to-date find evidence for a discrete transition. Here we study a planar shear flow, called Waleffe flow, devoid of walls yet showing the fundamentals of planar transition to turbulence. Working with a quasi-2D yet Navier-Stokes derived model of this flow we are able to attack the (2 + 1) D transition problem. Going beyond the system sizes previously possible we find all of the required scalings of directed percolation and thus establish planar shears flow in this class.

  9. The transition to a sustainable society.

    PubMed Central

    Speth, J G

    1992-01-01

    Transitions in dealing with the root causes of environmental problems are advocated to achieve environmental sustainability. These transformations include (i) a demographic transition, (ii) a technology transition that includes the "green" automobile, (iii) an economic transition to one in which prices reflect full environmental costs, (iv) a transition in social equity, and (v) an institutional transition to different arrangements among governments, businesses, and peoples. Businessmen and environmentalists are urged to work together in the next decade to make the environment a personal issue, to call for government action, to recognize the environmental challenges, and to commit to accountability in order to leave a legacy of hope to the twenty-first century. PMID:11607270

  10. Role of transit amenities and vehicle characteristics in building transit ridership: Amenities for transit handbook and the transit design game workbook

    SciTech Connect

    Not Available

    1999-01-01

    This report consists of a Handbook and a Workbook. The Handbook identifies and describes passenger amenities and transit vehicle characteristics that attract ridership and explores how amenities may affect ridership. The Workbook includes information gathered from passenger surveys, focus groups, discussion sessions, and transit agency staff on the effect of a recently implemented transit amenities on passengers. As a companion to the Workbook, a disk. The Transit Design Game, enables transit agencies to survey their customers about their priorities for enhancements and estimate the potential effect of enhancements on ridership. The intended audience includes transit planners, designers, general managers, and project managers; transportation policy makers; city and regional planners; and suppliers; vendors, and manufacturers.

  11. Role of transit amenities and vehicle characteristics in building transit ridership: Amenities for transit handbook and the transit design game workbook

    SciTech Connect

    1999-11-01

    This report consists of a Handbook and a Workbook. The Handbook identifies and describes passenger amenities and transit vehicle characteristics that attract ridership and explores how amenities may affect ridership. The Workbook includes information gathered from passenger surveys, focus groups, discussion sessions, and transit agency staff on the effect of a recently implemented transit amenities on passengers. As a companion to the Workbook, a disk. The Transit Design Game, enables transit agencies to survey their customers about their priorities for enhancements and estimate the potential effect of enhancements on ridership. The intended audience includes transit planners, designers, general managers, and project managers; transportation policy makers; city and regional planners; and suppliers; vendors, and manufacturers.

  12. Kepler Systems That Show Multiple Transiting Objects

    NASA Astrophysics Data System (ADS)

    Steffen, Jason H.; Fabrycky, D. C.; Ford, E. B.; Holman, M. J.; Lissauer, J. J.; Ragozzine, D.; Welsh, W. F.; Kepler Science Team

    2011-01-01

    Exoplanetary systems that have multiple transiting planets provide unique and important insight into the formation, evolution, and dynamics of exoplanetary systems. Kepler has announced the discovery of a confirmed planetary system with multiple transiting planets (Kepler 9, Holman et al. 2010) as well as several candidate planetary systems that show multiple transiting objects (Steffen et al. 2010). Kepler 9 shows deviations from a constant period due to the ongoing dynamical interactions between the confirmed planets. From these transit timing variations (TTV) one can measure the planetary masses from the photometric data alone. The presence of several systems with multiple transiting candidates from the first quarter of data indicate that Kepler should continue to find systems with multiple transiting planets. Such systems will provide important, general information about the histories of planetary systems.

  13. Approximating metal-insulator transitions

    NASA Astrophysics Data System (ADS)

    Danieli, Carlo; Rayanov, Kristian; Pavlov, Boris; Martin, Gaven; Flach, Sergej

    2015-12-01

    We consider quantum wave propagation in one-dimensional quasiperiodic lattices. We propose an iterative construction of quasiperiodic potentials from sequences of potentials with increasing spatial period. At each finite iteration step, the eigenstates reflect the properties of the limiting quasiperiodic potential properties up to a controlled maximum system size. We then observe approximate Metal-Insulator Transitions (MIT) at the finite iteration steps. We also report evidence on mobility edges, which are at variance to the celebrated Aubry-André model. The dynamics near the MIT shows a critical slowing down of the ballistic group velocity in the metallic phase, similar to the divergence of the localization length in the insulating phase.

  14. Cloud regimes as phase transitions

    NASA Astrophysics Data System (ADS)

    Stechmann, Samuel N.; Hottovy, Scott

    2016-06-01

    Clouds are repeatedly identified as a leading source of uncertainty in future climate predictions. Of particular importance are stratocumulus clouds, which can appear as either (i) closed cells that reflect solar radiation back to space or (ii) open cells that allow solar radiation to reach the Earth's surface. Here we show that these clouds regimes -- open versus closed cells -- fit the paradigm of a phase transition. In addition, this paradigm characterizes pockets of open cells as the interface between the open- and closed-cell regimes, and it identifies shallow cumulus clouds as a regime of higher variability. This behavior can be understood using an idealized model for the dynamics of atmospheric water as a stochastic diffusion process. With this new conceptual viewpoint, ideas from statistical mechanics could potentially be used for understanding uncertainties related to clouds in the climate system and climate predictions.

  15. Synthesis of transition metal carbonitrides

    DOEpatents

    Munir, Zuhair A. R.; Eslamloo-Grami, Maryam

    1994-01-01

    Transition metal carbonitrides (in particular, titanium carbonitride, TiC.sub.0.5 N.sub.0.5) are synthesized by a self-propagating reaction between the metal (e.g., titanium) and carbon in a nitrogen atmosphere. Complete conversion to the carbonitride phase is achieved with the addition of TiN as diluent and with a nitrogen pressure .gtoreq.0.6 MPa. Thermodynamic phase-stability calculations and experimental characterizations of quenched samples provided revealed that the mechanism of formation of the carbonitride is a two-step process. The first step involves the formation of the nonstoichiometric carbide, TiC.sub.0.5, and is followed by the formation of the product by the incorporation of nitrogen in the defect-structure carbide.

  16. Transition delay using control theory.

    PubMed

    Bagheri, S; Henningson, D S

    2011-04-13

    This review gives an account of recent research efforts to use feedback control for the delay of laminar-turbulent transition in wall-bounded shear flows. The emphasis is on reducing the growth of small-amplitude disturbances in the boundary layer using numerical simulations and a linear control approach. Starting with the application of classical control theory to two-dimensional perturbations developing in spatially invariant flows, flow control based on control theory has progressed towards more realistic three-dimensional, spatially inhomogeneous flow configurations with localized sensing/actuation. The development of low-dimensional models of the Navier-Stokes equations has played a key role in this progress. Moreover, shortcomings and future challenges, as well as recent experimental advances in this multi-disciplinary field, are discussed.

  17. Structural Transitions in Densifying Networks

    NASA Astrophysics Data System (ADS)

    Lambiotte, R.; Krapivsky, P. L.; Bhat, U.; Redner, S.

    2016-11-01

    We introduce a minimal generative model for densifying networks in which a new node attaches to a randomly selected target node and also to each of its neighbors with probability p . The networks that emerge from this copying mechanism are sparse for p <1/2 and dense (average degree increasing with number of nodes N ) for p ≥1/2 . The behavior in the dense regime is especially rich; for example, individual network realizations that are built by copying are disparate and not self-averaging. Further, there is an infinite sequence of structural anomalies at p =2/3 , 3/4 , 4/5 , etc., where the N dependences of the number of triangles (3-cliques), 4-cliques, undergo phase transitions. When linking to second neighbors of the target can occur, the probability that the resulting graph is complete—all nodes are connected—is nonzero as N →∞ .

  18. Altitude transitions in energy climbs

    NASA Technical Reports Server (NTRS)

    Weston, A. R.; Cliff, E. M.; Kelley, H. J.

    1982-01-01

    The aircraft energy-climb trajectory for configurations with a sharp transonic drag rise is well known to possess two branches in the altitude/Mach-number plane. Transition in altitude between the two branches occurs instantaneously, a 'corner' in the minimum-time solution obtained with the energy-state model. If the initial and final values of altitude do not lie on the energy-climb trajectory, then additional jumps (crude approximations to dives and zooms) are required at the initial and terminal points. With a singular-perturbation approach, a 'boundary-layer' correction is obtained for each altitude jump, the transonic jump being a so-called 'internal' boundary layer, different in character from the initial and terminal layers. The determination of this internal boundary layer is examined and some computational results for an example presented.

  19. Perpetual transitions in Romanian healthcare.

    PubMed

    Spiru, Luiza; Traşcu, Răzvan Ioan; Turcu, Ileana; Mărzan, Mircea

    2011-12-01

    Although Romania has a long-lasting tradition in organized medical healthcare, in the last two decades the Romanian healthcare system has been undergoing a perpetual transition with negative effects on all parties involved. The lack of long-term strategic vision, the implementation of initiatives without any impact studies, hence the constant short-term approach from the policy makers, combined with the "inherited" low allocation from GDP to the healthcare system have contributed significantly to its current evolution. Currently, most measures taken are of the "fire-fighting" type, rather than looking to the broader, long time perspective. There should be no wonder then, that predictive and preventive services do not get the proper attention and support. Patient and physicians should step in and take action in regulating a system that was originally designed for them. But until this happens, the organizations with leadership skills and vision need to take action-and this has already started.

  20. Picking the right transition strategy.

    PubMed

    Watkins, Michael D

    2009-01-01

    Leaders in transition reflexively rely on the skills and strategies that worked for them in the past. That's a mistake, says Watkins, whose research shows that executives moving into new roles must gain a deep understanding of the situation at hand and adapt to it. To help them accurately assess their organizations and tailor their strategies and styles accordingly, he developed the STARS framework. "STARS" is an acronym for the five common situations leaders move into: start-up, turnaround, accelerated growth, realignment, and sustaining success. Thus, the model outlines the challenges of launching a venture or project; saving a business or initiative that's in serious trouble; dealing with rapid expansion; reenergizing a once-leading company that's now facing problems; and following in the footsteps of a highly regarded leader with a strong legacy of success. Executives can accelerate their immersion in new roles by following certain fundamental principles: Organize to learn about the business, establish A-item priorities, define strategic intent, quickly build the leadership team, secure early wins, and create supportive alliances across the company. But the way those principles should be applied depends very much on the business situation, which the STARS framework can help leaders analyze. Turnarounds and realignments present especially distinct leadership challenges that call for particular transition strategies. Regardless of the business situation, leaders must figure out which things need to happen--perhaps a jump in market share or an expansion into different markets--for their business to achieve its goals. And they must determine which leadership style best fits the new culture they're joining. Armed with such clarity, executives can design effective plans to manage their organizations and themselves.

  1. Phase transition in a super superspin glass

    NASA Astrophysics Data System (ADS)

    Mathieu, R.; De Toro, J. A.; Salazar, D.; Lee, S. S.; Cheong, J. L.; Nordblad, P.

    2013-06-01

    We here confirm the occurrence of spin glass phase transition and extract estimates of associated critical exponents of a highly monodisperse and densely compacted system of bare maghemite nanoparticles. This system has earlier been found to behave like an archetypal spin glass, with, e.g., a sharp transition from paramagnetic to non-equilibrium behavior, suggesting that this system undergoes a spin glass phase transition at a relatively high temperature, Tg ∼ 140 K.

  2. Typology of State Types: Persistence and Transition

    DTIC Science & Technology

    2015-04-28

    developed in this paper, a more tailored policy to each type of state might be applied. Such nuances cannot be captured by broader categorizations such as...DRDC-RDDC-2014-P105 1 Typology of State Types : Persistence and Transition Peter Tikuisis Defence Research and Development Canada David...Additionally, changes in legitimacy most often led state transitions into or out of fragility. Implications of intervention policy for transitioning

  3. Analysis of Nuclear Quantum Phase Transitions

    SciTech Connect

    Li, Z. P.; Meng, J.; Niksic, T.; Vretenar, D.; Lalazissis, G. A.; Ring, P.

    2009-08-26

    A microscopic analysis, based on nuclear energy density functionals, is presented for shape phase transitions in Nd isotopes. Low-lying excitation spectra and transition probabilities are calculated starting from a five-dimensional Hamiltonian, with parameters determined by constrained relativistic mean-field calculations for triaxial shapes. The results reproduce available data, and show that there is an abrupt change of structure at N = 90, that corresponds to a first-order quantum phase transition between spherical and axially deformed shapes.

  4. Observation of transitions in lithiumlike germanium

    NASA Technical Reports Server (NTRS)

    Behring, W. E.; Seely, J. F.; Brown, C. M.; Feldman, U.; Knauer, J. P.

    1989-01-01

    Transitions of the type n = 2-2, n = 2-3 and n = 3-4 in Li-like Ge(29+) have been observed in the spectrum from a laser-produced plasma. The energy levels and ionization energy of Ge(29+) were derived from the observed wavelengths. The wavelength of the 2s 2S1/2-2p 2P3/2 transition is sufficiently accurate to determine the quantum-electrodynamic contribution to the transition energy.

  5. New O(3) transition in three dimensions

    NASA Astrophysics Data System (ADS)

    Kamal, Michael; Murthy, Ganpathy

    1993-09-01

    A three-dimensional lattice of Heisenberg spins with nearest-neighbor interactions is studied by numerical simulation under the constraint that no free topological singularities (hedgehogs) are allowed. Only nearest-neighbor pairs of oppositely charged hedgehogs are permitted in the sum over configurations. A disordering transition with exponents different from the usual Heisenberg transition is found and tentatively identified as a pure spin wave disordering transition.

  6. Cancer as a dynamical phase transition.

    PubMed

    Davies, Paul Cw; Demetrius, Lloyd; Tuszynski, Jack A

    2011-08-25

    This paper discusses the properties of cancer cells from a new perspective based on an analogy with phase transitions in physical systems. Similarities in terms of instabilities and attractor states are outlined and differences discussed. While physical phase transitions typically occur at or near thermodynamic equilibrium, a normal-to-cancer (NTC) transition is a dynamical non-equilibrium phenomenon, which depends on both metabolic energy supply and local physiological conditions. A number of implications for preventative and therapeutic strategies are outlined.

  7. NO TRANSIT TIMING VARIATIONS IN WASP-4

    SciTech Connect

    Petrucci, R.; Schwartz, M.; Buccino, A. P.; Mauas, P. J. D.; Jofré, E.; Cúneo, V.; Gómez, M.; Martínez, C.

    2013-12-20

    We present six new transits of the system WASP-4. Together with 28 light curves published in the literature, we perform a homogeneous study of its parameters and search for variations in the transits' central times. The final values agree with those previously reported, except for a slightly lower inclination. We find no significant long-term variations in i or R{sub P} /R {sub *}. The O-C mid-transit times do not show signs of transit timing variations greater than 54 s.

  8. Transition manager is liaison between teams.

    PubMed

    2014-08-01

    At University of Utah Health Care, a transition case manager acts as a liaison between the outpatient care team at community clinics and the inpatient care team. The transition navigator works with case managers at the hospital and the clinics to make sure both have the information they need to coordinate care for the patient. The transition navigator visits patients in the hospital and works with the unit case manager to make sure the discharge plan will work. To further smooth transitions, the patients receive a one-page sheet that summarizes their discharge instructions, follow-up appointments, and medication regimen.

  9. Explosive Percolation Transition is Actually Continuous

    NASA Astrophysics Data System (ADS)

    da Costa, R. A.; Dorogovtsev, S. N.; Goltsev, A. V.; Mendes, J. F. F.

    2010-12-01

    Recently a discontinuous percolation transition was reported in a new “explosive percolation” problem for irreversible systems [D. Achlioptas, R. M. D’Souza, and J. Spencer, Science 323, 1453 (2009)SCIEAS0036-807510.1126/science.1167782] in striking contrast to ordinary percolation. We consider a representative model which shows that the explosive percolation transition is actually a continuous, second order phase transition though with a uniquely small critical exponent of the percolation cluster size. We describe the unusual scaling properties of this transition and find its critical exponents and dimensions.

  10. Nonadiabatic transitions in electrostatically trapped ammonia molecules

    SciTech Connect

    Kirste, Moritz; Schnell, Melanie; Meijer, Gerard; Sartakov, Boris G.

    2009-05-15

    Nonadiabatic transitions are known to be major loss channels for atoms in magnetic traps but have thus far not been experimentally reported upon for trapped molecules. We have observed and quantified losses due to nonadiabatic transitions for three isotopologues of ammonia in electrostatic traps by comparing the trapping times in traps with a zero and a nonzero electric field at the center. Nonadiabatic transitions are seen to dominate the overall loss rate even for the present samples that are at relatively high temperatures of 30 mK. It is anticipated that losses due to nonadiabatic transitions in electric fields are omnipresent in ongoing experiments on cold molecules.

  11. X-Ray Transition Energies Database

    National Institute of Standards and Technology Data Gateway

    SRD 128 X-Ray Transition Energies Database (Web, free access)   This X-ray transition table provides the energies and wavelengths for the K and L transitions connecting energy levels having principal quantum numbers n = 1, 2, 3, and 4. The elements covered include Z = 10, neon to Z = 100, fermium. There are two unique features of this data base: (1) a serious attempt to have all experimental values on a scale consistent with the International System of measurement (the SI) and (2) inclusion of accurate theoretical estimates for all transitions.

  12. Negative refraction using Raman transitions and chirality

    SciTech Connect

    Sikes, D. E.; Yavuz, D. D.

    2011-11-15

    We present a scheme that achieves negative refraction with low absorption in far-off resonant atomic systems. The scheme utilizes Raman resonances and does not require the simultaneous presence of an electric-dipole transition and a magnetic-dipole transition near the same wavelength. We show that two interfering Raman tran-sitions coupled to a magnetic-dipole transition can achieve a negative index of refraction with low absorption through magnetoelectric cross-coupling. We confirm the validity of the analytical results with exact numerical simulations of the density matrix. We also discuss possible experimental implementations of the scheme in rare-earth metal atomic systems.

  13. 18 CFR 1317.230 - Transition plans.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... steps and the individual directly responsible for their implementation. (5) Include estimates of the... include in its transition plan, and shall implement, specific steps designed to encourage individuals...

  14. 38 CFR 23.230 - Transition plans.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... steps and the individual directly responsible for their implementation. (5) Include estimates of the... transition plan, and shall implement, specific steps designed to encourage individuals of the...

  15. 45 CFR 2555.230 - Transition plans.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... steps and the individual directly responsible for their implementation. (5) Include estimates of the... include in its transition plan, and shall implement, specific steps designed to encourage individuals...

  16. 36 CFR 1211.230 - Transition plans.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... taking these steps and the individual directly responsible for their implementation. (5) Include... include in its transition plan, and shall implement, specific steps designed to encourage individuals...

  17. 45 CFR 2555.230 - Transition plans.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... steps and the individual directly responsible for their implementation. (5) Include estimates of the... include in its transition plan, and shall implement, specific steps designed to encourage individuals...

  18. 18 CFR 1317.230 - Transition plans.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... steps and the individual directly responsible for their implementation. (5) Include estimates of the... include in its transition plan, and shall implement, specific steps designed to encourage individuals...

  19. 18 CFR 1317.230 - Transition plans.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... steps and the individual directly responsible for their implementation. (5) Include estimates of the... include in its transition plan, and shall implement, specific steps designed to encourage individuals...

  20. Kepler Stars with Multiple Transiting Planet Candidates

    NASA Technical Reports Server (NTRS)

    Lissauer, Jack J.

    2012-01-01

    NASA's Kepler spacecraft was launched into an Earth-trailing heliocentric orbit in March of 2009. Kepler is designed to conduct a statistical census of planetary system properties using transit photometry. Among the most exciting early results from Kepler are target stars found to have photometric signatures that suggest the presence of more than one transiting planet. Individual transiting planets provide information on the size and orbital period distributions of exoplanets. Multiple transiting planets provide additional information on the spacing and flatness distributions of planetary systems. Results to d ate and plans for future analysis will be presented.

  1. The multiuniverse transition in superfluid 3He

    NASA Astrophysics Data System (ADS)

    Bunkov, Yury

    2013-10-01

    The symmetry-breaking phase transitions of the universe and of superfluid 3He may lead to the formation of different states with different order parameters. In both cases the energy potential below the transition temperature has a complicated multidimensional profile with many local minima and saddle points, which correspond to different states. Consequently, not only topological defects, but also islands of different metastable states can be created. Using 3He we can analyse the properties and experimental consequences of such transitions and, in particular, the first-order phase transition between the two low symmetry states.

  2. The multiuniverse transition in superfluid 3He.

    PubMed

    Bunkov, Yury

    2013-10-09

    The symmetry-breaking phase transitions of the universe and of superfluid (3)He may lead to the formation of different states with different order parameters. In both cases the energy potential below the transition temperature has a complicated multidimensional profile with many local minima and saddle points, which correspond to different states. Consequently, not only topological defects, but also islands of different metastable states can be created. Using (3)He we can analyse the properties and experimental consequences of such transitions and, in particular, the first-order phase transition between the two low symmetry states.

  3. Local bias-induced phase transitions

    DOE PAGES

    Seal, Katyayani; Baddorf, Arthur P.; Jesse, Stephen; ...

    2008-11-27

    Electrical bias-induced phase transitions underpin a wide range of applications from data storage to energy generation and conversion. The mechanisms behind these transitions are often quite complex and in many cases are extremely sensitive to local defects that act as centers for local transformations or pinning. Furthermore, using ferroelectrics as an example, we review methods for probing bias-induced phase transitions and discuss the current limitations and challenges for extending the methods to field-induced phase transitions and electrochemical reactions in energy storage, biological and molecular systems.

  4. The Helix Coil Transition of DNA

    ERIC Educational Resources Information Center

    Steinert, Roger; Hudson, Bruce

    1973-01-01

    This transition, observed with an inexpensive ultraviolet photometer, is a potentially useful experiment for an advanced freshman class because it introduces several concepts of general physical interest. (DF)

  5. Unidirectional Transition Waves in Bistable Lattices

    NASA Astrophysics Data System (ADS)

    Nadkarni, Neel; Arrieta, Andres F.; Chong, Christopher; Kochmann, Dennis M.; Daraio, Chiara

    2016-06-01

    We present a model system for strongly nonlinear transition waves generated in a periodic lattice of bistable members connected by magnetic links. The asymmetry of the on-site energy wells created by the bistable members produces a mechanical diode that supports only unidirectional transition wave propagation with constant wave velocity. We theoretically justify the cause of the unidirectionality of the transition wave and confirm these predictions by experiments and simulations. We further identify how the wave velocity and profile are uniquely linked to the double-well energy landscape, which serves as a blueprint for transition wave control.

  6. A liquid-liquid transition can exist in monatomic transition metals with a positive melting slope

    PubMed Central

    Lee, Byeongchan; Lee, Geun Woo

    2016-01-01

    Liquid-liquid transitions under high pressure are found in many elemental materials, but the transitions are known to be associated with either sp-valent materials or f-valent rare-earth elements, in which the maximum or a negative slope in the melting line is readily suggestive of the transition. Here we find a liquid-liquid transition with a positive melting slope in transition metal Ti from structural, electronic, and thermodynamic studies using ab-initio molecular dynamics calculations, showing diffusion anomaly, but no density anomaly. The origin of the transition in liquid Ti is a pressure-induced increase of local structures containing very short bonds with directionality in electronic configurations. This behavior appears to be characteristic of the early transition metals. In contrast, the late transition metal liquid Ni does not show the L-L transition with pressure. This result suggests that the possibility of the L-L transition decreases from early to late transition metals as electronic structures of late transition metals barely have a Jahn-Teller effect and bond directionality. Our results generalize that a phase transition in disordered materials is found with any valence band regardless of the sign of the melting slope, but related to the symmetry of electronic structures of constituent elements. PMID:27762334

  7. A liquid-liquid transition can exist in monatomic transition metals with a positive melting slope

    NASA Astrophysics Data System (ADS)

    Lee, Byeongchan; Lee, Geun Woo

    2016-10-01

    Liquid-liquid transitions under high pressure are found in many elemental materials, but the transitions are known to be associated with either sp-valent materials or f-valent rare-earth elements, in which the maximum or a negative slope in the melting line is readily suggestive of the transition. Here we find a liquid-liquid transition with a positive melting slope in transition metal Ti from structural, electronic, and thermodynamic studies using ab-initio molecular dynamics calculations, showing diffusion anomaly, but no density anomaly. The origin of the transition in liquid Ti is a pressure-induced increase of local structures containing very short bonds with directionality in electronic configurations. This behavior appears to be characteristic of the early transition metals. In contrast, the late transition metal liquid Ni does not show the L-L transition with pressure. This result suggests that the possibility of the L-L transition decreases from early to late transition metals as electronic structures of late transition metals barely have a Jahn-Teller effect and bond directionality. Our results generalize that a phase transition in disordered materials is found with any valence band regardless of the sign of the melting slope, but related to the symmetry of electronic structures of constituent elements.

  8. Structural transitions in nanoscale systems

    NASA Astrophysics Data System (ADS)

    Yoon, Mina

    In this work I investigate three different materials: nanoscale carbon systems, ferrofluid systems, and molecular-electronic devices. In particular, my study is focused on the theoretical understanding of structural changes and the associated electronic, mechanical, and magnetic properties of these materials. To study the equilibrium packing of fullerenes in carbon nanotube peapods optimization techniques were applied. In agreement with experimental measurements, my results for nanotubes containing fullerenes with 60--84 atoms indicate that the axial separation between the fullerenes is smaller than in the bulk crystal. The reduction of the inter-fullerene distance and also the structural relaxation of fullerenes result from a large internal pressure within the peapods. This naturally induced "static" pressure may qualify nanotubes as nanoscale autoclaves for chemical reactions. Combining total energy calculations with a search of phase space, I investigated the microscopic fusion mechanism of C60 fullerenes. I show that the (2+2) cycloaddition reaction, a necessary precursor for fullerene fusion, can be accelerated inside a nanotube. Fusion occurs along the minimum energy path as a finite sequence of Stone-Wales (SW) transformations. A detailed analysis of the transition states shows that Stone-Wales transformations are multi-step processes. I propose a new microscopic mechanism to explain the unusually fast fusion process of carbon nanotubes. The detailed pathway for two adjacent (5, 5) nanotubes to gradually merge into a (10, 10) tube, and the transition states have been identified. The propagation of the fused region is energetically favorable and proceeds in a morphology reminiscent of a Y-junction via a so called zipper mechanism, involving only SW bond rearrangements with low activation barriers. Using density functional theory, the equilibrium structure, stability, and electronic properties of nanostructured, hydrogen terminated diamond fragments have been

  9. HD209458b Transit Spectroscopy

    NASA Astrophysics Data System (ADS)

    Harrington, J.; Deming, L. D.; Matthews, K.; Richardson, L. J.; Rojo, P.; Steyert, D.; Wiedemann, G.; Zeehandelaar, D.

    2002-09-01

    We search for the spectral signature of H2O, CH4, and CO on the extrasolar planet HD 209458b using transit spectroscopy. The planet will modulate the stellar spectrum during transit. The extinction altitude of tangent rays of a given wavelength depends on the abundance and distribution of molecular species that absorb at that wavelength. The depth of the occultation at a given wavelength depends on the cross-sectional area of the planet, which is determined by the extinction altitude. For deep lines of H2O, CH4, and CO, the effect is about 0.07%, due to the ~750 km scale height. Our S/N calculations show that well-calibrated, ground-based spectra, integrated over time and wavelength, can measure or place useful limits on the atmospheric abundances of H2O, CH4, and CO. Carbon forms predominantly CH4 below 1400 K and CO if hotter. Since the effective temperature is around 1400 K, detecting CH4 and/or CO would provide a tight constraint on atmospheric temperatures. Observations began in August 2001 at Palomar and we have 12 additional nights granted in 2002 at Keck, VLT, and IRTF. The expected modulation of the stellar spectrum is model-dependent: high-altitude hazes, photochemical effects, and different thermal profiles would substantially modify the effect for the same planetary elemental abundances. Since the effect is subtle compared to the noise in the data, we correlate model spectra against thousands of observed spectra and average the correlations to test whether the data support a given model. We are developing a radiative-transfer model to predict the spectrum of a given planetary model, and we are measuring H2O, CH4, and CO in the laboratory at 1300 K, with pressure-broadening by H2, to make our model spectra realistic at these elevated temperatures (crucial for detecting H2O). Analysis of the 2001 data and acquisition of 2002 data are in progress. We solicit participation by those who wish to test their planetary models.

  10. Decreasing Transition Times in a Second Grade Classroom: Scientific Support for the Timely Transitions Game

    ERIC Educational Resources Information Center

    Yarrough, Jamie L.; Skinner, Christopher H.; Lee, Young Ju; Lemmons, Cathy

    2004-01-01

    Campbell and Skinner used an A-B design to evaluate the effects of the Timely Transitions Game (TTG) on room-to-room transitions in a sixth-grade classroom. The TTG incorporated explicit timing, publicly posted feedback, and an interdependent group contingency with randomly selected transitions and criteria. The purpose of the current study was to…

  11. Implementing Secondary Transition Evidence-Based Practices: A Multi-State Survey of Transition Service Providers

    ERIC Educational Resources Information Center

    Mazzotti, Valerie L.; Plotner, Anthony J.

    2016-01-01

    Inadequate transition outcomes for youth with disabilities have produced a call for enhanced transition service delivery that includes implementation of evidence-based practices (EBPs). However, research indicates transition service providers still lack the knowledge and skills to effectively implement EBPs to ensure youth with disabilities…

  12. College Students in Transition: An Annotated Bibliography

    ERIC Educational Resources Information Center

    Foote, Stephanie M., Ed.; Hinkle, Sara M., Ed.; Kranzow, Jeannine, Ed.; Pistilli, Matthew D., Ed.; Miles, LaTonya Rease, Ed.; Simmons, Jannell G., Ed.

    2013-01-01

    The transition from high school to college is an important milestone, but it is only one of many steps in the journey through higher education. This volume is an annotated bibliography of the emerging literature examining the many other transitions students make beyond the first year, including the sophomore year, the transfer experience, and the…

  13. Quick Guide: Mental Health-Secondary Transition

    ERIC Educational Resources Information Center

    National Technical Assistance Center in Transition, 2016

    2016-01-01

    Recently researchers have begun focusing on young adults with mental health disorders transitioning into adulthood. Research exploring the importance of mental health support in secondary transition have yielded positive outcomes. For example, strong collaboration between educational and mental health agencies ensuring academic, employment, and…

  14. Transitional objects: idealization of a phenomenon.

    PubMed

    Brody, S

    1980-10-01

    Winnicott's thesis about transitional objects and transitional phenomena indicates that Kleinian theory, as well as his own preference for imaginative play with ideas, influenced his interpretation of his discovery and led to misapplications of its meaning. An alternative interpretation of its meaning, one that may be aligned more easily with other clinical data, is submitted. A brief review of the literature is appended.

  15. Branding and Bricolage. Gender, Consumption and Transition

    ERIC Educational Resources Information Center

    Russell, Rachel; Tyler, Melissa

    2005-01-01

    The analysis presented here focuses on the relationship between femininity, transition and consumer culture. It explores the relationship between gender and consumer culture in the context of a discussion of the transition from childhood to teenage status for a group of young girls, and seeks to make a critical contribution to contemporary debates…

  16. Transition to School: Revisiting the Bridge Metaphor

    ERIC Educational Resources Information Center

    Huser, Carmen; Dockett, Sue; Perry, Bob

    2016-01-01

    Policymakers, researchers and educators around the world have acknowledged the importance of children's transition to school, both as a significant life event and as a factor in future engagement with education. As a result, much attention has been directed towards researching transition experiences, developing policies to support positive…

  17. 45 CFR 86.17 - Transition plans.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... SEX IN EDUCATION PROGRAMS OR ACTIVITIES RECEIVING FEDERAL FINANCIAL ASSISTANCE Coverage § 86.17... more than one administratively separate unit may submit either a single transition plan applicable to... order to be approved by the United States Commissioner of Education, a transition plan shall: (1)...

  18. 43 CFR 41.230 - Transition plans.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... Public Lands: Interior Office of the Secretary of the Interior NONDISCRIMINATION ON THE BASIS OF SEX IN EDUCATION PROGRAMS OR ACTIVITIES RECEIVING FEDERAL FINANCIAL ASSISTANCE Coverage § 41.230 Transition plans... one administratively separate unit may submit either a single transition plan applicable to all...

  19. 38 CFR 23.230 - Transition plans.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ...) NONDISCRIMINATION ON THE BASIS OF SEX IN EDUCATION PROGRAMS OR ACTIVITIES RECEIVING FEDERAL FINANCIAL ASSISTANCE... that is composed of more than one administratively separate unit may submit either a single transition...) Content of plans. In order to be approved by the Secretary of Education, a transition plan shall:...

  20. 40 CFR 5.230 - Transition plans.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... Protection of Environment ENVIRONMENTAL PROTECTION AGENCY GENERAL NONDISCRIMINATION ON THE BASIS OF SEX IN EDUCATION PROGRAMS OR ACTIVITIES RECEIVING FEDERAL FINANCIAL ASSISTANCE Coverage § 5.230 Transition plans... one administratively separate unit may submit either a single transition plan applicable to all...