Cell colonization in degradable 3D porous matrices
Lawrence, Benjamin J
2008-01-01
Cell colonization is an important in a wide variety of biological processes and applications including vascularization, wound healing, tissue engineering, stem cell differentiation and biosensors. During colonization porous 3D structures are used to support and guide the ingrowth of cells into the matrix. In this review, we summarize our understanding of various factors affecting cell colonization in three-dimensional environment. The structural, biological and degradation properties of the matrix all play key roles during colonization. Further, specific scaffold properties such as porosity, pore size, fiber thickness, topography and scaffold stiffness as well as important cell material interactions such as cell adhesion and mechanotransduction also influence colonization. PMID:19262124
Parton shower evolution in a 3D hydrodynamical medium
Renk, Thorsten
2008-09-15
We present a Monte Carlo simulation of the perturbative quantum chromodynamics shower developing after a hard process embedded in a heavy-ion collision. The main assumption is that the cascade of branching partons traverses a medium that (consistent with standard radiative energy loss pictures) is characterized by a local transport coefficient q-circumflex that measures the virtuality per unit length transferred to a parton that propagates in this medium. This increase in parton virtuality alters the development of the shower and in essence leads to extra induced radiation and hence a softening of the momentum distribution in the shower. After hadronization, this leads to the concept of a medium-modified fragmentation function. On the level of observables, this is manifest as the suppression of high-transverse-momentum (P{sub T}) hadron spectra. We simulate the soft medium created in heavy-ion collisions by a 3D hydrodynamical evolution and average the medium-modified fragmentation function over this evolution to compare with data on single inclusive hadron suppression and extract the q-circumflex that characterizes the medium. Finally, we discuss possible uncertainties of the model formulation and argue that the data in a soft momentum show evidence of qualitatively different physics that presumably cannot be described by a medium-modified parton shower.
A Mechanistic Study of Wetting Superhydrophobic Porous 3D Meshes.
Yohe, Stefan T; Freedman, Jonathan D; Falde, Eric J; Colson, Yolonda L; Grinstaff, Mark W
2013-08-01
Superhydrophobic, porous, 3D materials composed of poly( ε -caprolactone) (PCL) and the hydrophobic polymer dopant poly(glycerol monostearate- co - ε -caprolactone) (PGC-C18) are fabricated using the electrospinning technique. These 3D materials are distinct from 2D superhydrophobic surfaces, with maintenance of air at the surface as well as within the bulk of the material. These superhydrophobic materials float in water, and when held underwater and pressed, an air bubble is released and will rise to the surface. By changing the PGC-C18 doping concentration in the meshes and/or the fiber size from the micro- to nanoscale, the long-term stability of the entrapped air layer is controlled. The rate of water infiltration into the meshes, and the resulting displacement of the entrapped air, is quantitatively measured using X-ray computed tomography. The properties of the meshes are further probed using surfactants and solvents of different surface tensions. Finally, the application of hydraulic pressure is used to quantify the breakthrough pressure to wet the meshes. The tools for fabrication and analysis of these superhydrophobic materials as well as the ability to control the robustness of the entrapped air layer are highly desirable for a number of existing and emerging applications. PMID:25309305
Vorticity and upscaled dispersion in 3D heterogeneous porous media
NASA Astrophysics Data System (ADS)
Di Dato, Mariaines; Chiogna, Gabriele; de Barros, Felipe; Bellin, Alberto; Fiori, Aldo
2015-04-01
Modeling flow in porous media is relevant for many environmental, energy and industrial applications. From an environmental perspective, the relevance of porous media flow becomes evident in subsurface hydrology. In general, flow in natural porous media is creeping, yet the large variability in the hydraulic conductivity values encountered in natural aquifers leads to highly heterogeneous flow fields. This natural variability in the conductivity field will affect both dilution rates of chemical species and reactive mixing. A physical consequence of this heterogeneity is also the presence of a various localized kinematical features such as straining, shearing and vorticity in aquifers, which will influence the shape of solute clouds and its fate and transport. This work aims in fundamentally characterizing the vorticity field in spatially heterogeneous flow fields as a function of their statistical properties in order to analyze the impact on transport processes. In our study, three-dimensional porous formations are constructed with an ensemble of N independent, non-overlapping spheroidal inclusions submerged into an homogeneous matrix, of conductivity K0. The inclusions are randomly located in a domain of volume W and are fully characterized by the geometry of spheroid (oblate or prolate), their conductivity K (random and drawn from a given probability density function fκ), the centroid location ¯x, the axes ratio e, the orientation of the rotational axis (α1,α2) and the volume w. Under the assumption of diluted medium, the flow problem is solved analitically by means of only two parameters: the conductivity contrast κ = K/K0 and the volume fraction n = Nw/W . Through the variation of these parameters of the problem, it is possible to approximate the structure of natural heterogeneous porous media. Using a random distribution of the orientation of the inclusions, we create media defined by the same global anisotropy f = Iz/Ix but different micro
Computing Radiative Transfer in a 3D Medium
NASA Technical Reports Server (NTRS)
Von Allmen, Paul; Lee, Seungwon
2012-01-01
A package of software computes the time-dependent propagation of a narrow laser beam in an arbitrary three- dimensional (3D) medium with absorption and scattering, using the transient-discrete-ordinates method and a direct integration method. Unlike prior software that utilizes a Monte Carlo method, this software enables simulation at very small signal-to-noise ratios. The ability to simulate propagation of a narrow laser beam in a 3D medium is an improvement over other discrete-ordinate software. Unlike other direct-integration software, this software is not limited to simulation of propagation of thermal radiation with broad angular spread in three dimensions or of a laser pulse with narrow angular spread in two dimensions. Uses for this software include (1) computing scattering of a pulsed laser beam on a material having given elastic scattering and absorption profiles, and (2) evaluating concepts for laser-based instruments for sensing oceanic turbulence and related measurements of oceanic mixed-layer depths. With suitable augmentation, this software could be used to compute radiative transfer in ultrasound imaging in biological tissues, radiative transfer in the upper Earth crust for oil exploration, and propagation of laser pulses in telecommunication applications.
3D Bioprinting Using a Templated Porous Bioink.
Armstrong, James P K; Burke, Madeline; Carter, Benjamin M; Davis, Sean A; Perriman, Adam W
2016-07-01
3D tissue printing with adult stem cells is reported. A novel cell-containing multicomponent bioink is used in a two-step 3D printing process to engineer bone and cartilage architectures. PMID:27125336
Updegraff, C.D. ); Lee, C.E. ); Gallegos, D.P. )
1991-02-01
This report constitutes the user's manual for DCM3D. DCM3D is a computer code for solving three-dimensional, ground-water flow problems in variably saturated, fractured porous media. The code is based on a dual-continuum model with porous media comprising one continuum and fractures comprising the other. The continua are connected by a transfer term that depends on the unsaturated permeability of the porous medium. An integrated finite-difference scheme is used to discretize the governing equations in space. The time-dependent term is allowed to remain continuous. The resulting set of ordinary differential equations (ODE's) is solved with a general ODE solver, LSODES. The code is capable of handling transient, spatially dependent source terms and boundary conditions. The boundary conditions can either prescribed head or prescribed flux. 24 refs., 22 figs., 5 tabs.
3D finite element analysis of porous Ti-based alloy prostheses.
Mircheski, Ile; Gradišar, Marko
2016-11-01
In this paper, novel designs of porous acetabular cups are created and tested with 3D finite element analysis (FEA). The aim is to develop a porous acetabular cup with low effective radial stiffness of the structure, which will be near to the architectural and mechanical behavior of the natural bone. For the realization of this research, a 3D-scanner technology was used for obtaining a 3D-CAD model of the pelvis bone, a 3D-CAD software for creating a porous acetabular cup, and a 3D-FEA software for virtual testing of a novel design of the porous acetabular cup. The results obtained from this research reveal that a porous acetabular cup from Ti-based alloys with 60 ± 5% porosity has the mechanical behavior and effective radial stiffness (Young's modulus in radial direction) that meet and exceed the required properties of the natural bone. The virtual testing with 3D-FEA of a novel design with porous structure during the very early stage of the design and the development of orthopedic implants, enables obtaining a new or improved biomedical implant for a relatively short time and reduced price.
Elastic properties of model 3-D porous ceramics and foams
NASA Astrophysics Data System (ADS)
Roberts, Anthony; Garboczi, Edward
2000-03-01
The novel properties of many new porous materials are related to their interesting internal microstructure. Apart from simple cases, there exist no theoretical means of predicting the bulk properties of these materials. This limits our ability to guide microstructure optimization for a particular purpose. We use a large scale finite element method to demonstrate the complex relationship between microstructure and the effective properties of realistic three-dimensional model porous ceramics and foams. We find that pore-shape and interconnectivity strongly influence the properties of sintered ceramics. For porous foams we have studied the role of coordination number, random disorder, and strut shape on the Young's modulus and Poisson's ratio. We find that that Voronoi tesselations, commonly used to model solid foams, show unphysical behavior, in particular they are incompressible (rubber-like) at low densities. Deletion of just 10% of the bonds in the model reduces the bulk modulus by 75%, more in line with experimental evidence. The FEM results are generally in good agreement with experimental data for ceramics and foams, and can be used as both a predictive and interpretative tool by experimentalists.
3D Hierarchical Porous Mo2 C for Efficient Hydrogen Evolution.
Ang, Huixiang; Wang, Huanwen; Li, Bing; Zong, Yun; Wang, Xuefeng; Yan, Qingyu
2016-06-01
Porous electrocatalyst for hydrogen production. 3D hierarchical porous molybdenum carbide provides a low operating potential (97 mV at 10 mA cm(-2) ). These beneficial textures of large specific surface area (302 m(2) g(-1) ) and hierarchical porous architecture containing dominant pore size distribution peak at 11 Å in width can provide large surface active sites and facilitate proton mass transport. PMID:27076208
Zhang, Xue; Li, Xiao-Wu; Li, Ji-Guang; Sun, Xu-Dong
2014-09-01
Porous magnesium has been recently recognized as a biodegradable metal for bone substitute applications. A novel porous Mg scaffold with three-dimensional (3D) interconnected pores and with a porosity of 33-54% was produced by the fiber deposition hot pressing (FDHP) technology. The microstructure and morphologies of the porous Mg scaffold were characterized by scanning electron microscopy (SEM), and the effects of porosities on the microstructure and mechanical properties of the porous Mg were investigated. Experimental results indicate that the measured Young's modulus and compressive strength of the Mg scaffold are ranged in 0.10-0.37 GPa, and 11.1-30.3 MPa, respectively, which are fairly comparable to those of cancellous bone. Such a porous Mg scaffold having a 3D interconnected network structure has the potential to be used in bone tissue engineering.
Method to prepare nanoparticles on porous mediums
Vieth, Gabriel M [Knoxville, TN; Dudney, Nancy J [Oak Ridge, TN; Dai, Sheng [Knoxville, TN
2010-08-10
A method to prepare porous medium decorated with nanoparticles involves contacting a suspension of nanoparticles in an ionic liquid with a porous medium such that the particles diffuse into the pores of the medium followed by heating the resulting composition to a temperature equal to or greater than the thermal decomposition temperature of the ionic liquid resulting in the removal of the liquid portion of the suspension. The nanoparticles can be a metal, an alloy, or a metal compound. The resulting compositions can be used as catalysts, sensors, or separators.
Transport of iron oxide nanoparticles in saturated porous media: a large-scale 3D study
NASA Astrophysics Data System (ADS)
Velimirovic, Milica; Schmid, Doris; Micić, Vesna; Miyajima, Kumiko; Klaas, Norbert; Braun, Jürgen; Bosch, Julian; Meckenstock, Rainer; von der Kammer, Frank; Hofmann, Thilo
2016-04-01
Iron oxide nanoparticles (FeOxNp) have a high potential as electron acceptor for in situ microbial oxidation of a wide range of recalcitrant groundwater contaminants (Bosch et al., 2010). Tosco et al. (2012) reported on high colloidal stability of FeOxNp dispersed in water, their low deposition behavior, and consequently improved transport in column experiments compared to extensively studied zerovalent iron nanoparticles. However, determination of FeOxNp transport behavior at the field-relevant conditions has not been done before. The present work is aimed to evaluate different complementary methods for detection, quantification and transport characterization of FeOxNp in a large-scale three-dimensional (3D) model aquifer. Prior to that, batch-scale experiments were performed in order to elucidate the potential of the selected methods for direct and indirect characterization and detection of FeOxNp. Direct methods included measurements of particle size distribution, particle concentration, Fetot content and turbidity of the FeOxNp suspension. Indirect methods included measurements of particle zeta potential, as well as TOC content and pH of the FeOxNp suspension. The results of the batch experiments indicated that the most suitable approach for detecting and quantifying FeOxNp was measuring Fetot content and suspension turbidity, as well as particle size determined using dynamic light scattering principle. These complementary methods were further applied in a large-scale 3D study containing medium and coarse sand in order to 1) assess the transport of FeOxNp in saturated porous medium during injection (VFeOx = 6 m3, cparticle = 20 g/L, Qinj = 0.7 m3/h), and 2) illustrate their spatial distribution after injection. The outcomes of the large-scale 3D study confirmed that FeOxNp transport can be successfully investigated applying complementary methods. Monitoring data including Fetot content, turbidity and particle size showed the transport of particles towards the
Chatterjee, Kaushik; Hung, Stevephen; Kumar, Girish; Simon, Carl G
2012-01-01
Protein adsorption is known to direct biological response to biomaterials and is important in determining cellular response in tissue scaffolds. In this study we investigated the effect of the duration of protein adsorption to 3D polymer scaffolds on cell attachment and proliferation. 3D macro-porous polymer scaffolds were pre-aged in serum-containing culture medium for 5 min, 1 d or 7 d prior to seeding osteoblasts. The total amount of protein adsorbed was found to increase with pre-ageing time. Cell attachment and proliferation were measured 1 d and 14 d, respectively, after cell seeding. Osteoblast proliferation, but not attachment, increased with scaffold pre-ageing time and amount of adsorbed serum protein. These results demonstrate that the amount of time that scaffolds are exposed to serum-containing medium can affect cell proliferation and suggest that these effects are mediated by differences in the amount of protein adsorption.
3-D model of ICME in the interplanetary medium
NASA Astrophysics Data System (ADS)
Borgazzi, A.; Lara, A.; Niembro, T.
2011-12-01
We developed a method that describes with simply geometry the coordinates of intersection between the leading edge of an ICME and the position of an arbitrary satellite. When a fast CME is ejected from the Sun to the interplanetary space in most of the cases drives a shock. As the CME moves in the corona and later in the interplanetary space more material is stacking in the front and edges of the ejecta. In a first approximation, it is possible to assume the shape of these structures, the CME and the stacked material as a cone of revolution, (the ice-cream model [Schwenn et al., (2005)]). The interface may change due to the interaction of the structure and the non-shocked material in front of the ICME but the original shape of a cone of revolution is preserved. We assume, in a three dimensional geometry, an ice-cream cone shape for the ICME and apply an analytical model for its transport in the interplanetary medium. The goal of the present method is to give the time and the intersection coordinates between the leading edge of the ICME and any satellite that may be in the path of the ICME. With this information we can modelate the travel of the ICME in the interplanetary space using STEREO data.
A 3-D constitutive model for pressure-dependent phase transformation of porous shape memory alloys.
Ashrafi, M J; Arghavani, J; Naghdabadi, R; Sohrabpour, S
2015-02-01
Porous shape memory alloys (SMAs) exhibit the interesting characteristics of porous metals together with shape memory effect and pseudo-elasticity of SMAs that make them appropriate for biomedical applications. In this paper, a 3-D phenomenological constitutive model for the pseudo-elastic behavior and shape memory effect of porous SMAs is developed within the framework of irreversible thermodynamics. Comparing to micromechanical and computational models, the proposed model is computationally cost effective and predicts the behavior of porous SMAs under proportional and non-proportional multiaxial loadings. Considering the pressure dependency of phase transformation in porous SMAs, proper internal variables, free energy and limit functions are introduced. With the aim of numerical implementation, time discretization and solution algorithm for the proposed model are also presented. Due to lack of enough experimental data on multiaxial loadings of porous SMAs, we employ a computational simulation method (CSM) together with available experimental data to validate the proposed constitutive model. The method is based on a 3-D finite element model of a representative volume element (RVE) with random pores pattern. Good agreement between the numerical predictions of the model and CSM results is observed for elastic and phase transformation behaviors in various thermomechanical loadings.
Rieger, Elisabeth; Dupret-Bories, Agnès; Salou, Laetitia; Metz-Boutigue, Marie-Helene; Layrolle, Pierre; Debry, Christian; Lavalle, Philippe; Vrana, Nihal Engin
2015-06-01
Porous titanium implants are widely employed in the orthopaedics field to ensure good bone fixation. Recently, the use of porous titanium implants has also been investigated in artificial larynx development in a clinical setting. Such uses necessitate a better understanding of the interaction of soft tissues with porous titanium structures. Moreover, surface treatments of titanium have been generally evaluated in planar structures, while the porous titanium implants have complex 3 dimensional (3D) architectures. In this study, the determining factors for soft tissue integration of 3D porous titanium implants were investigated as a function of surface treatments via quantification of the interaction of serum proteins and cells with single titanium microbeads (300-500 μm in diameter). Samples were either acid etched or nanostructured by anodization. When the samples are used in 3D configuration (porous titanium discs of 2 mm thickness) in vivo (in subcutis of rats for 2 weeks), a better integration was observed for both anodized and acid etched samples compared to the non-treated implants. If the implants were also pre-treated with rat serum before implantation, the integration was further facilitated. In order to understand the underlying reasons for this effect, human fibroblast cell culture tests under several conditions (directly on beads, beads in suspension, beads encapsulated in gelatin hydrogels) were conducted to mimic the different interactions of cells with Ti implants in vivo. Physical characterization showed that surface treatments increased hydrophilicity, protein adsorption and roughness. Surface treatments also resulted in improved adsorption of serum albumin which in turn facilitated the adsorption of other proteins such as apolipoprotein as quantified by protein sequencing. The cellular response to the beads showed considerable difference with respect to the cell culture configuration. When the titanium microbeads were entrapped in cell
Proton exchange membrane micro fuel cells on 3D porous silicon gas diffusion layers
NASA Astrophysics Data System (ADS)
Kouassi, S.; Gautier, G.; Thery, J.; Desplobain, S.; Borella, M.; Ventura, L.; Laurent, J.-Y.
2012-10-01
Since the 90's, porous silicon has been studied and implemented in many devices, especially in MEMS technology. In this article, we present a new approach to build miniaturized proton exchange membrane micro-fuel cells using porous silicon as a hydrogen diffusion layer. In particular, we propose an innovative process to build micro fuel cells from a “corrugated iron like” 3D structured porous silicon substrates. This structure is able to increase up to 40% the cell area keeping a constant footprint on the silicon wafer. We propose here a process route to perform electrochemically 3D porous gas diffusion layers and to deposit fuel cell active layers on such substrates. The prototype peak power performance was measured to be 90 mW cm-2 in a “breathing configuration” at room temperature. These performances are less than expected if we compare with a reference 2D micro fuel cell. Actually, the active layer deposition processes are not fully optimized but this prototype demonstrates the feasibility of these 3D devices.
Mechanical properties and shape memory effect of 3D-printed PLA-based porous scaffolds.
Senatov, F S; Niaza, K V; Zadorozhnyy, M Yu; Maksimkin, A V; Kaloshkin, S D; Estrin, Y Z
2016-04-01
In the present work polylactide (PLA)/15wt% hydroxyapatite (HA) porous scaffolds with pre-modeled structure were obtained by 3D-printing by fused filament fabrication. Composite filament was obtained by extrusion. Mechanical properties, structural characteristics and shape memory effect (SME) were studied. Direct heating was used for activation of SME. The average pore size and porosity of the scaffolds were 700μm and 30vol%, respectively. Dispersed particles of HA acted as nucleation centers during the ordering of PLA molecular chains and formed an additional rigid fixed phase that reduced molecular mobility, which led to a shift of the onset of recovery stress growth from 53 to 57°C. A more rapid development of stresses was observed for PLA/HA composites with the maximum recovery stress of 3.0MPa at 70°C. Ceramic particles inhibited the growth of cracks during compression-heating-compression cycles when porous PLA/HA 3D-scaffolds recovered their initial shape. Shape recovery at the last cycle was about 96%. SME during heating may have resulted in "self-healing" of scaffold by narrowing the cracks. PLA/HA 3D-scaffolds were found to withstand up to three compression-heating-compression cycles without delamination. It was shown that PLA/15%HA porous scaffolds obtained by 3D-printing with shape recovery of 98% may be used as self-fitting implant for small bone defect replacement owing to SME.
A 3D porous Ni-Cu alloy film for high-performance hydrazine electrooxidation
NASA Astrophysics Data System (ADS)
Sun, Ming; Lu, Zhiyi; Luo, Liang; Chang, Zheng; Sun, Xiaoming
2016-01-01
Structural design and catalyst screening are two most important factors for achieving exceptional electrocatalytic performance. Herein we demonstrate that constructing a three-dimensional (3D) porous Ni-Cu alloy film is greatly beneficial for improving the hydrazine oxidation reaction (HzOR) performance. A facile electrodeposition process is employed to synthesize a Ni-Cu alloy film with a 3D hierarchical porous structure. As an integrated electrode for HzOR, the Ni-Cu alloy film exhibits superior catalytic activity and stability to the Ni or Cu counterparts. The synthesis parameters are also systematically tuned for optimizing the HzOR performance. The excellent HzOR performance of the Ni-Cu alloy film is attributed to its high intrinsic activity, large electrochemical specific surface area, and 3D porous architecture which offers a ``superaerophobic'' surface to effectively remove the gas product in a small volume. It is believed that the Ni-Cu alloy film electrode has potential application in direct hydrazine fuel cells as well as other catalytic fields.Structural design and catalyst screening are two most important factors for achieving exceptional electrocatalytic performance. Herein we demonstrate that constructing a three-dimensional (3D) porous Ni-Cu alloy film is greatly beneficial for improving the hydrazine oxidation reaction (HzOR) performance. A facile electrodeposition process is employed to synthesize a Ni-Cu alloy film with a 3D hierarchical porous structure. As an integrated electrode for HzOR, the Ni-Cu alloy film exhibits superior catalytic activity and stability to the Ni or Cu counterparts. The synthesis parameters are also systematically tuned for optimizing the HzOR performance. The excellent HzOR performance of the Ni-Cu alloy film is attributed to its high intrinsic activity, large electrochemical specific surface area, and 3D porous architecture which offers a ``superaerophobic'' surface to effectively remove the gas product in a small
Bottom-up topography assembly into 3D porous scaffold to mediate cell activities.
Cheng, Delin; Hou, Jie; Hao, Lijing; Cao, Xiaodong; Gao, Huichang; Fu, Xiaoling; Wang, Yingjun
2016-08-01
Native cells live in a three-dimensional (3D) extracellular matrix (ECM) capable of regulating cell activities through various physical and chemical factors. Designed topographies have been well proven to trigger significant difference in cell behaviours. However, present topographies are almost all constructed on two-dimensional (2D) substrates like discs and films, which are far from features like 3D and porosity required in application like bone repair. Here we bottom-up assembled poly(lactic-co-glycolic acid)/calcium carbonate (PLGA/CC) microspheres with superficial porous topography intactly into a 3D porous scaffold. Because the scaffold was obtained through a mild technique, the bioactivity of released BMP-2 was well retained. Mouse bone marrow mesenchymal stem cells (mMSCs) were cultured on produced scaffolds having different 3D topographies. It turned out that osteogenic differentiation of mMSCs did respond to the 3D topographies, while proliferation didn't. Gene expression of αv and β1 integrins revealed that adhesion was supposed to be the underlying mechanism for osteogenic response. The study provides insight into enhancing function of practical scaffolds by elaborate topography design. © 2015 Wiley Periodicals, Inc. J Biomed Mater Res Part B: Appl Biomater, 104B: 1056-1063, 2016.
NASA Astrophysics Data System (ADS)
Rieger, Elisabeth; Dupret-Bories, Agnès; Salou, Laetitia; Metz-Boutigue, Marie-Helene; Layrolle, Pierre; Debry, Christian; Lavalle, Philippe; Engin Vrana, Nihal
2015-05-01
Porous titanium implants are widely employed in the orthopaedics field to ensure good bone fixation. Recently, the use of porous titanium implants has also been investigated in artificial larynx development in a clinical setting. Such uses necessitate a better understanding of the interaction of soft tissues with porous titanium structures. Moreover, surface treatments of titanium have been generally evaluated in planar structures, while the porous titanium implants have complex 3 dimensional (3D) architectures. In this study, the determining factors for soft tissue integration of 3D porous titanium implants were investigated as a function of surface treatments via quantification of the interaction of serum proteins and cells with single titanium microbeads (300-500 μm in diameter). Samples were either acid etched or nanostructured by anodization. When the samples are used in 3D configuration (porous titanium discs of 2 mm thickness) in vivo (in subcutis of rats for 2 weeks), a better integration was observed for both anodized and acid etched samples compared to the non-treated implants. If the implants were also pre-treated with rat serum before implantation, the integration was further facilitated. In order to understand the underlying reasons for this effect, human fibroblast cell culture tests under several conditions (directly on beads, beads in suspension, beads encapsulated in gelatin hydrogels) were conducted to mimic the different interactions of cells with Ti implants in vivo. Physical characterization showed that surface treatments increased hydrophilicity, protein adsorption and roughness. Surface treatments also resulted in improved adsorption of serum albumin which in turn facilitated the adsorption of other proteins such as apolipoprotein as quantified by protein sequencing. The cellular response to the beads showed considerable difference with respect to the cell culture configuration. When the titanium microbeads were entrapped in cell
Zheng, Xueqin; Sun, Hong; Hou, Shifeng
2015-01-01
In this work, an electroactive porous Mb-CA's composite film was fabricated by incorporating myoglobin (Mb) in a three-dimension (3D) porous calcium alginate (CA) film with polyvinyl alcohol, glycerol, and gelatin. The porous Mb-CA's film modified electrodes exhibited a pair of well-defined, quasi-reversible cyclic voltammetric (CV) peaks at about -0.37 V vs. SCE in pH 7.0 buffers, characteristic of Mb heme Fe((III))/Fe((II)) redox couples. The electrochemical parameters, such as formal potentials (E(o')) and apparent heterogeneous electron-transfer rate constants (ks), were estimated by square-wave voltammetry with nonlinear regression analysis. The porous CA's composite film could form hydrogel in aqueous solution. The positions of the Soret absorbance band suggest that Mb in the CA's composite film kept its native states in the medium pH range. Hydrogen peroxide, oxygen, and nitrite were electrochemically catalyzed by the Mb-CA's composite film with significant lowering of the reduction overpotential.
3D porous metal-organic framework exhibiting selective adsorption of water over organic solvents.
Gu, Jin-Zhong; Lu, Wen-Guan; Jiang, Long; Zhou, Hong-Cai; Lu, Tong-Bu
2007-07-23
A 3D porous metal-organic framework (MOF) with 1D open channels has been constructed hydrothermally using Zn(II) and a rigid planar ligand IDC(3)- (imidazole-4,5-dicarboxylate). This MOF can adsorb water selectively over organic solvents and can be regenerated and reused. It also represents a rare example of a MOF with open channels that form/collapse reversibly upon hydration/dehydration.
Synthesis of various 3D porous gold-based alloy nanostructures with branched shapes.
Swiatkowska-Warkocka, Zaneta; Pyatenko, Alexander; Koshizaki, Naoto; Kawaguchi, Kenji
2016-12-01
This paper presents a facile and flexible synthesis platform for various 3D porous gold-iron nanostructures based on selective laser heating of colloidal nanoparticles and selective acid treatment. The presented approach allows to create porous gold-based nanostructures with different morphologies. In addition, for the first time, our studies indicate that various nanoarchitectures (brain-like, flower-like, cage-like, or raspberry-like structures) can be obtained by varying the experimental conditions such as size of Au and Fe3O4 nanoparticles, solvent, laser fluence, and irradiation time. We believe that these porous structures will find immediate applications in catalysis and separations, where high surface area and magnetic properties are often simultaneously required. PMID:27565959
Synthesis of various 3D porous gold-based alloy nanostructures with branched shapes.
Swiatkowska-Warkocka, Zaneta; Pyatenko, Alexander; Koshizaki, Naoto; Kawaguchi, Kenji
2016-12-01
This paper presents a facile and flexible synthesis platform for various 3D porous gold-iron nanostructures based on selective laser heating of colloidal nanoparticles and selective acid treatment. The presented approach allows to create porous gold-based nanostructures with different morphologies. In addition, for the first time, our studies indicate that various nanoarchitectures (brain-like, flower-like, cage-like, or raspberry-like structures) can be obtained by varying the experimental conditions such as size of Au and Fe3O4 nanoparticles, solvent, laser fluence, and irradiation time. We believe that these porous structures will find immediate applications in catalysis and separations, where high surface area and magnetic properties are often simultaneously required.
Ducci, Daniela; Sellerino, Mariangela
2013-03-01
The aim of this paper is to apply a methodology in order to reconstruct a lithostratigraphic 3D model of an aquifer so as to define some parameters involved in the evaluation of the aquifer vulnerability to contamination of porous aquifers. The DRASTIC, SINTACS and AVI methods have been applied to an alluvial coastal aquifer of southern Italy. The stratigraphic reconstruction has been obtained by interpolating stratigraphic data from more than one borehole per 2 km. The lithostratigraphic reconstruction of a 3D model has been applied and used for three-dimensional or two-dimensional representations. In the first two methods, the layers of the vadose zone and the aquifer media have been evaluated not only by the interpolation of the single boreholes and piezometers, but also by the 3D model, assigning the scores of the parameters of each layer of the 3D model. The comparison between the maps constructed from the weighted values in each borehole and the maps deriving from the attribution of the values of each layer of the 3D model, highlights that the second representation avoids or minimizes the "bullseye" effect linked to the presence of boreholes with higher or lower values. The study has demonstrated that it is possible to integrate a 3D lithostratigraphic model of an aquifer in the assessment of the parameters involved in the evaluation of the aquifer vulnerability to contamination by Point Count System methods.
Electrochemical fabrication of 2D and 3D nickel nanowires using porous anodic alumina templates
NASA Astrophysics Data System (ADS)
Mebed, A. M.; Abd-Elnaiem, Alaa M.; Al-Hosiny, Najm M.
2016-06-01
Mechanically stable nickel (Ni) nanowires array and nanowires network were synthesized by pulse electrochemical deposition using 2D and 3D porous anodic alumina (PAA) templates. The structures and morphologies of as-prepared films were characterized by X-ray diffraction and scanning electron microscopy, respectively. The grown Ni nanowire using 3D PAA revealed more strength and larger surface area than has grown Ni use 2D PAA template. The prepared nanowires have a face-centered cubic crystal structure with average grain size 15 nm, and the preferred orientation of the nucleation of the nanowires is (111). The diameter of the nanowires is about 50-70 nm with length 3 µm. The resulting 3D Ni nanowire lattice, which provides enhanced mechanical stability and an increased surface area, benefits energy storage and many other applications which utilize the large surface area.
Fan, Li-Zhen; Chen, Tian-Tian; Song, Wei-Li; Li, Xiaogang; Zhang, Shichao
2015-01-01
Supercapacitors fabricated by 3D porous carbon frameworks, such as graphene- and carbon nanotube (CNT)-based aerogels, have been highly attractive due to their various advantages. However, their high cost along with insufficient yield has inhibited their large-scale applications. Here we have demonstrated a facile and easily scalable approach for large-scale preparing novel 3D nitrogen-containing porous carbon frameworks using ultralow-cost commercial cotton. Electrochemical performance suggests that the optimal nitrogen-containing cotton-derived carbon frameworks with a high nitrogen content (12.1 mol%) along with low surface area 285 m2 g−1 present high specific capacities of the 308 and 200 F g−1 in KOH electrolyte at current densities of 0.1 and 10 A g−1, respectively, with very limited capacitance loss upon 10,000 cycles in both aqueous and gel electrolytes. Moreover, the electrode exhibits the highest capacitance up to 220 F g−1 at 0.1 A g−1 and excellent flexibility (with negligible capacitance loss under different bending angles) in the polyvinyl alcohol/KOH gel electrolyte. The observed excellent performance competes well with that found in the electrodes of similar 3D frameworks formed by graphene or CNTs. Therefore, the ultralow-cost and simply strategy here demonstrates great potential for scalable producing high-performance carbon-based supercapacitors in the industry. PMID:26472144
NASA Astrophysics Data System (ADS)
Fan, Li-Zhen; Chen, Tian-Tian; Song, Wei-Li; Li, Xiaogang; Zhang, Shichao
2015-10-01
Supercapacitors fabricated by 3D porous carbon frameworks, such as graphene- and carbon nanotube (CNT)-based aerogels, have been highly attractive due to their various advantages. However, their high cost along with insufficient yield has inhibited their large-scale applications. Here we have demonstrated a facile and easily scalable approach for large-scale preparing novel 3D nitrogen-containing porous carbon frameworks using ultralow-cost commercial cotton. Electrochemical performance suggests that the optimal nitrogen-containing cotton-derived carbon frameworks with a high nitrogen content (12.1 mol%) along with low surface area 285 m2 g-1 present high specific capacities of the 308 and 200 F g-1 in KOH electrolyte at current densities of 0.1 and 10 A g-1, respectively, with very limited capacitance loss upon 10,000 cycles in both aqueous and gel electrolytes. Moreover, the electrode exhibits the highest capacitance up to 220 F g-1 at 0.1 A g-1 and excellent flexibility (with negligible capacitance loss under different bending angles) in the polyvinyl alcohol/KOH gel electrolyte. The observed excellent performance competes well with that found in the electrodes of similar 3D frameworks formed by graphene or CNTs. Therefore, the ultralow-cost and simply strategy here demonstrates great potential for scalable producing high-performance carbon-based supercapacitors in the industry.
From micro-scale 3D simulations to macro-scale model of periodic porous media
NASA Astrophysics Data System (ADS)
Crevacore, Eleonora; Tosco, Tiziana; Marchisio, Daniele; Sethi, Rajandrea; Messina, Francesca
2015-04-01
In environmental engineering, the transport of colloidal suspensions in porous media is studied to understand the fate of potentially harmful nano-particles and to design new remediation technologies. In this perspective, averaging techniques applied to micro-scale numerical simulations are a powerful tool to extrapolate accurate macro-scale models. Choosing two simplified packing configurations of soil grains and starting from a single elementary cell (module), it is possible to take advantage of the periodicity of the structures to reduce the computation costs of full 3D simulations. Steady-state flow simulations for incompressible fluid in laminar regime are implemented. Transport simulations are based on the pore-scale advection-diffusion equation, that can be enriched introducing also the Stokes velocity (to consider the gravity effect) and the interception mechanism. Simulations are carried on a domain composed of several elementary modules, that serve as control volumes in a finite volume method for the macro-scale method. The periodicity of the medium involves the periodicity of the flow field and this will be of great importance during the up-scaling procedure, allowing relevant simplifications. Micro-scale numerical data are treated in order to compute the mean concentration (volume and area averages) and fluxes on each module. The simulation results are used to compare the micro-scale averaged equation to the integral form of the macroscopic one, making a distinction between those terms that could be computed exactly and those for which a closure in needed. Of particular interest it is the investigation of the origin of macro-scale terms such as the dispersion and tortuosity, trying to describe them with micro-scale known quantities. Traditionally, to study the colloidal transport many simplifications are introduced, such those concerning ultra-simplified geometry that usually account for a single collector. Gradual removal of such hypothesis leads to a
A miniature microbial fuel cell with conducting nanofibers-based 3D porous biofilm
NASA Astrophysics Data System (ADS)
Jiang, Huawei; Halverson, Larry J.; Dong, Liang
2015-12-01
Miniature microbial fuel cell (MFC) technology has received growing interest due to its potential applications in high-throughput screening of bacteria and mutants to elucidate mechanisms of electricity generation. This paper reports a novel miniature MFC with an improved output power density and short startup time, utilizing electrospun conducting poly(3,4-ethylenedioxythiophene) (PEDOT) nanofibers as a 3D porous anode within a 12 μl anolyte chamber. This device results in 423 μW cm-3 power density based on the volume of the anolyte chamber, using Shewanella oneidensis MR-1 as a model biocatalyst without any optimization of bacterial culture. The device also excels in a startup time of only 1hr. The high conductivity of the electrospun nanofibers makes them suitable for efficient electron transfer. The mean pore size of the conducting nanofibers is several micrometers, which is favorable for bacterial penetration and colonization of surfaces of the nanofibers. We demonstrate that S. oneidensis can fully colonize the interior region of this nanofibers-based porous anode. This work represents a new attempt to explore the use of electrospun PEDOT nanofibers as a 3D anode material for MFCs. The presented miniature MFC potentially will provide a high-sensitivity, high-throughput tool to screen suitable bacterial species and mutant strains for use in large-size MFCs.
Dynamics of osmosis in a porous medium.
Cardoso, Silvana S S; Cartwright, Julyan H E
2014-11-01
We derive from kinetic theory, fluid mechanics and thermodynamics the minimal continuum-level equations governing the flow of a binary, non-electrolytic mixture in an isotropic porous medium with osmotic effects. For dilute mixtures, these equations are linear and in this limit provide a theoretical basis for the widely used semi-empirical relations of Kedem & Katchalsky (Kedem & Katchalsky 1958 Biochim. Biophys. Acta 27, 229-246 (doi:10.1016/0006-3002(58)90330-5), which have hitherto been validated experimentally but not theoretically. The above linearity between the fluxes and the driving forces breaks down for concentrated or non-ideal mixtures, for which our equations go beyond the Kedem-Katchalsky formulation. We show that the heretofore empirical solute permeability coefficient reflects the momentum transfer between the solute molecules that are rejected at a pore entrance and the solvent molecules entering the pore space; it can be related to the inefficiency of a Maxwellian demi-demon.
Cox, Sophie C; Thornby, John A; Gibbons, Gregory J; Williams, Mark A; Mallick, Kajal K
2015-02-01
A systematic characterisation of bone tissue scaffolds fabricated via 3D printing from hydroxyapatite (HA) and poly(vinyl)alcohol (PVOH) composite powders is presented. Flowability of HA:PVOH precursor materials was observed to affect mechanical stability, microstructure and porosity of 3D printed scaffolds. Anisotropic behaviour of constructs and part failure at the boundaries of interlayer bonds was highlighted by compressive strength testing. A trade-off between the ability to facilitate removal of PVOH thermal degradation products during sintering and the compressive strength of green parts was revealed. The ultimate compressive strength of 55% porous green scaffolds printed along the Y-axis and dried in a vacuum oven for 6h was 0.88 ± 0.02 MPa. Critically, the pores of 3D printed constructs could be user designed, ensuring bulk interconnectivity, and the imperfect packing of powder particles created an inherent surface roughness and non-designed porosity within the scaffold. These features are considered promising since they are known to facilitate osteoconduction and osteointegration in-vivo. Characterisation techniques utilised in this study include two funnel flow tests, scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), compressive strength testing and computed tomography (CT).
Cox, Sophie C; Thornby, John A; Gibbons, Gregory J; Williams, Mark A; Mallick, Kajal K
2015-02-01
A systematic characterisation of bone tissue scaffolds fabricated via 3D printing from hydroxyapatite (HA) and poly(vinyl)alcohol (PVOH) composite powders is presented. Flowability of HA:PVOH precursor materials was observed to affect mechanical stability, microstructure and porosity of 3D printed scaffolds. Anisotropic behaviour of constructs and part failure at the boundaries of interlayer bonds was highlighted by compressive strength testing. A trade-off between the ability to facilitate removal of PVOH thermal degradation products during sintering and the compressive strength of green parts was revealed. The ultimate compressive strength of 55% porous green scaffolds printed along the Y-axis and dried in a vacuum oven for 6h was 0.88 ± 0.02 MPa. Critically, the pores of 3D printed constructs could be user designed, ensuring bulk interconnectivity, and the imperfect packing of powder particles created an inherent surface roughness and non-designed porosity within the scaffold. These features are considered promising since they are known to facilitate osteoconduction and osteointegration in-vivo. Characterisation techniques utilised in this study include two funnel flow tests, scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), compressive strength testing and computed tomography (CT). PMID:25492194
Modeling and Reconstruction of Micro-structured 3D Chitosan/Gelatin Porous Scaffolds Using Micro-CT
NASA Astrophysics Data System (ADS)
Gong, Haibo; Li, Dichen; He, Jiankang; Liu, Yaxiong; Lian, Qin; Zhao, Jinna
2008-09-01
Three dimensional (3D) channel networks are the key to promise the uniform distribution of nutrients inside 3D hepatic tissue engineering scaffolds and prompt elimination of metabolic products out of the scaffolds. 3D chitosan/gelatin porous scaffolds with predefined internal channels were fabricated and a combination of light microscope, laser confocal microscopy and micro-CT were employed to characterize the structure of porous scaffolds. In order to evaluate the flow field distribution inside the micro-structured 3D scaffolds, a computer reconstructing method based on Micro-CT was proposed. According to this evaluating method, a contrast between 3D porous scaffolds with and without predefined internal channels was also performed to assess scaffolds' fluid characters. Results showed that the internal channel of the 3D scaffolds formed the 3D fluid channel network; the uniformity of flow field distribution of the scaffolds fabricated in this paper was better than the simple porous scaffold without micro-fluid channels.
Huang, Jian-Wen; Lv, Xiang-Guo; Li, Zhe; Song, Lu-Jie; Feng, Chao; Xie, Min-Kai; Li, Chao; Li, Hong-Bin; Wang, Ji-Hong; Zhu, Wei-Dong; Chen, Shi-Yan; Wang, Hua-Ping; Xu, Yue-Min
2015-09-01
The goal of this study was to evaluate the effects of urethral reconstruction with a three-dimensional (3D) porous bacterial cellulose (BC) scaffold seeded with lingual keratinocytes in a rabbit model. A novel 3D porous BC scaffold was prepared by gelatin sponge interfering in the BC fermentation process. Rabbit lingual keratinocytes were isolated, expanded, and seeded onto 3D porous BC. BC alone (group 1, N = 10), 3D porous BC alone (group 2, N = 10), and 3D porous BC seeded with lingual keratinocytes (group 3, N = 10) were used to repair rabbit ventral urethral defects (2.0 × 0.8 cm). Scanning electron microscopy revealed that BC consisted of a compact laminate while 3D porous BC was composed of a porous sheet buttressed by a dense outer layer. The average pore diameter and porosity of the 3D porous BC were 4.23 ± 1.14 μm and 67.00 ± 6.80%, respectively. At 3 months postoperatively, macroscopic examinations and retrograde urethrograms of urethras revealed that all urethras maintained wide calibers in group 3. Strictures were found in all rabbits in groups 1 and 2. Histologically, at 1 month postoperatively, intact epithelium occurred in group 3, and discontinued epithelium was found in groups 1 and 2. However, groups 2 and 3 exhibited similar epithelial regeneration, which was superior to that of group 1 at 3 months (p < 0.05). Comparisons of smooth muscle content and endothelia density among the three groups revealed a significant increase at each time point (p < 0.05). Our results demonstrated that 3D porous BC seeded with lingual keratinocytes enhanced urethral tissue regeneration. 3D porous BC could potentially be used as an optimized scaffold for urethral reconstruction. PMID:26358641
Huang, Jian-Wen; Lv, Xiang-Guo; Li, Zhe; Song, Lu-Jie; Feng, Chao; Xie, Min-Kai; Li, Chao; Li, Hong-Bin; Wang, Ji-Hong; Zhu, Wei-Dong; Chen, Shi-Yan; Wang, Hua-Ping; Xu, Yue-Min
2015-09-11
The goal of this study was to evaluate the effects of urethral reconstruction with a three-dimensional (3D) porous bacterial cellulose (BC) scaffold seeded with lingual keratinocytes in a rabbit model. A novel 3D porous BC scaffold was prepared by gelatin sponge interfering in the BC fermentation process. Rabbit lingual keratinocytes were isolated, expanded, and seeded onto 3D porous BC. BC alone (group 1, N = 10), 3D porous BC alone (group 2, N = 10), and 3D porous BC seeded with lingual keratinocytes (group 3, N = 10) were used to repair rabbit ventral urethral defects (2.0 × 0.8 cm). Scanning electron microscopy revealed that BC consisted of a compact laminate while 3D porous BC was composed of a porous sheet buttressed by a dense outer layer. The average pore diameter and porosity of the 3D porous BC were 4.23 ± 1.14 μm and 67.00 ± 6.80%, respectively. At 3 months postoperatively, macroscopic examinations and retrograde urethrograms of urethras revealed that all urethras maintained wide calibers in group 3. Strictures were found in all rabbits in groups 1 and 2. Histologically, at 1 month postoperatively, intact epithelium occurred in group 3, and discontinued epithelium was found in groups 1 and 2. However, groups 2 and 3 exhibited similar epithelial regeneration, which was superior to that of group 1 at 3 months (p < 0.05). Comparisons of smooth muscle content and endothelia density among the three groups revealed a significant increase at each time point (p < 0.05). Our results demonstrated that 3D porous BC seeded with lingual keratinocytes enhanced urethral tissue regeneration. 3D porous BC could potentially be used as an optimized scaffold for urethral reconstruction.
Evaluation of 3D nano-macro porous bioactive glass scaffold for hard tissue engineering.
Wang, S; Falk, M M; Rashad, A; Saad, M M; Marques, A C; Almeida, R M; Marei, M K; Jain, H
2011-05-01
Recently, nano-macro dual-porous, three-dimensional (3D) glass structures were developed for use as bioscaffolds for hard tissue regeneration, but there have been concerns regarding the interconnectivity and homogeneity of nanopores in the scaffolds, as well as the cytotoxicity of the environment deep inside due to limited fluid access. Therefore, mercury porosimetry, nitrogen absorption, and TEM have been used to characterize nanopore network of the scaffolds. In parallel, viability of MG 63 human osteosarcoma cells seeded on scaffold surface was investigated by fluorescence, confocal and electron microscopy methods. The results show that cells attach, migrate and penetrate inside the glass scaffold with high proliferation and viability rate. Additionally, scaffolds were implanted under the skin of a male New Zealand rabbit for in vivo animal test. Initial observations show the formation of new tissue with blood vessels and collagen fibers deep inside the implanted scaffolds with no obvious inflammatory reaction. Thus, the new nano-macro dual-porous glass structure could be a promising bioscaffold for use in regenerative medicine and tissue engineering for bone regeneration. PMID:21445655
Multi-contrast 3D X-ray imaging of porous and composite materials
Sarapata, Adrian; Herzen, Julia; Ruiz-Yaniz, Maite; Zanette, Irene; Rack, Alexander; Pfeiffer, Franz
2015-04-13
Grating-based X-ray computed tomography allows for simultaneous and nondestructive determination of the full X-ray complex index of refraction and the scattering coefficient distribution inside an object in three dimensions. Its multi-contrast capabilities combined with a high resolution of a few micrometers make it a suitable tool for assessing multiple phases inside porous and composite materials such as concrete. Here, we present quantitative results of a proof-of-principle experiment performed on a concrete sample. Thanks to the complementarity of the contrast channels, more concrete phases could be distinguished than in conventional attenuation-based imaging. The phase-contrast reconstruction shows high contrast between the hardened cement paste and the aggregates and thus allows easy 3D segmentation. Thanks to the dark-field image, micro-cracks inside the coarse aggregates are visible. We believe that these results are extremely interesting in the field of porous and composite materials studies because of unique information provided by grating interferometry in a non-destructive way.
Maji, Kanchan; Dasgupta, Sudip; Pramanik, Krishna; Bissoyi, Akalabya
2016-01-01
The aim of the present study was to prepare and characterize bioglass-natural biopolymer based composite scaffold and evaluate its bone regeneration ability. Bioactive glass nanoparticles (58S) in the size range of 20–30 nm were synthesized using sol-gel method. Porous scaffolds with varying bioglass composition from 10 to 30 wt% in chitosan, gelatin matrix were fabricated using the method of freeze drying of its slurry at 40 wt% solids loading. Samples were cross-linked with glutaraldehyde to obtain interconnected porous 3D microstructure with improved mechanical strength. The prepared scaffolds exhibited >80% porosity with a mean pore size range between 100 and 300 microns. Scaffold containing 30 wt% bioglass (GCB 30) showed a maximum compressive strength of 2.2 ± 0.1 MPa. Swelling and degradation studies showed that the scaffold had excellent properties of hydrophilicity and biodegradability. GCB 30 scaffold was shown to be noncytotoxic and supported mesenchymal stem cell attachment, proliferation, and differentiation as indicated by MTT assay and RUNX-2 expression. Higher cellular activity was observed in GCB 30 scaffold as compared to GCB 0 scaffold suggesting the fact that 58S bioglass nanoparticles addition into the scaffold promoted better cell adhesion, proliferation, and differentiation. Thus, the study showed that the developed composite scaffolds are potential candidates for regenerating damaged bone tissue. PMID:26884764
Dynamics of osmosis in a porous medium
Cardoso, Silvana S. S.; Cartwright, Julyan H. E.
2014-01-01
We derive from kinetic theory, fluid mechanics and thermodynamics the minimal continuum-level equations governing the flow of a binary, non-electrolytic mixture in an isotropic porous medium with osmotic effects. For dilute mixtures, these equations are linear and in this limit provide a theoretical basis for the widely used semi-empirical relations of Kedem & Katchalsky (Kedem & Katchalsky 1958 Biochim. Biophys. Acta 27, 229–246 (doi:10.1016/0006-3002(58)90330-5), which have hitherto been validated experimentally but not theoretically. The above linearity between the fluxes and the driving forces breaks down for concentrated or non-ideal mixtures, for which our equations go beyond the Kedem–Katchalsky formulation. We show that the heretofore empirical solute permeability coefficient reflects the momentum transfer between the solute molecules that are rejected at a pore entrance and the solvent molecules entering the pore space; it can be related to the inefficiency of a Maxwellian demi-demon. PMID:26064566
NASA Astrophysics Data System (ADS)
Bao, Weizhai; Mondal, Anjon Kumar; Xu, Jing; Wang, Chengyin; Su, Dawei; Wang, Guoxiu
2016-09-01
We report a rational design and synthesis of 3D hybrid-porous carbon with a hierarchical pore architecture for high performance supercapacitors. It contains micropores (<2 nm diameter) and mesopores (2-4 nm), derived from carbonization of unique porous metal organic frameworks (MOFs). Owning to the synergistic effect of micropores and mesopores, the hybrid-porous carbon has exceptionally high ion-accessible surface area and low ion diffusion resistance, which is desired for supercapacitor applications. When applied as electrode materials in supercapacitors, 3D hybrid-porous carbon demonstrates a specific capacitance of 332 F g-1 at a constant charge/discharge current of 500 mA g-1. The supercapacitors can endure more than 10,000 cycles without degradation of capacitance.
Lee, Kwang Hoon; Lee, Young-Woo; Lee, Seung Woo; Ha, Jeong Sook; Lee, Sang-Soo; Son, Jeong Gon
2015-01-01
A simple ice-templated self-assembly process is used to prepare a three-dimensional (3D) and vertically porous nanocomposite of layered vanadium phosphates (VOPO4) and graphene nanosheets with high surface area and high electrical conductivity. The resulting 3D VOPO4–graphene nanocomposite has a much higher capacitance of 527.9 F g−1 at a current density of 0.5 A g−1, compared with ~247 F g−1 of simple 3D VOPO4, with solid cycling stability. The enhanced pseudocapacitive behavior mainly originates from vertically porous structures from directionally grown ice crystals and simultaneously inducing radial segregation and forming inter-stacked structures of VOPO4–graphene nanosheets. This VOPO4–graphene nanocomposite electrode exhibits high surface area, vertically porous structure to the separator, structural stability from interstacked structure and high electrical conductivity, which would provide the short diffusion paths of electrolyte ions and fast transportation of charges within the conductive frameworks. In addition, an asymmetric supercapacitor (ASC) is fabricated by using vertically porous VOPO4–graphene as the positive electrode and vertically porous 3D graphene as the negative electrode; it exhibits a wide cell voltage of 1.6 V and a largely enhanced energy density of 108 Wh kg−1. PMID:26333591
Momentum transfer within a porous medium. II. Stress boundary condition
NASA Astrophysics Data System (ADS)
Minale, Mario
2014-12-01
In this paper, we derive a boundary condition at the interface between a free fluid and a porous medium stating that the stress is transferred both to the fluid within the porous medium and to the solid skeleton. A zero stress jump is obtained so that the total stress is preserved at the interface. The boundary condition is obtained with the volume averaging method following the approach of Ochoa-Tapia and Whitaker ["Momentum transfer at the boundary between a porous medium and a homogeneous fluid—I. Theoretical development," Int. J. Heat Mass Transfer 38(14), 2635-2646 (1995)], but starting from the momentum balances written on the fluid and on the solid of the porous region, the latter was derived in part I of this paper. In the same way, also the boundary condition at the interface between a porous medium and a homogeneous solid is obtained. Both boundary conditions describe the equilibrium of forces at the interface, where part of the stress is carried by the solid skeleton and part by the fluid within the porous medium. With the derived boundary conditions, together with the stress transfer equation within the solid skeleton, it is now possible to satisfy the overall force equilibrium on a shear cell partially filled with a porous medium.
3D distribution of interstellar medium in the Galaxy: Preparation for analysis of Gaia observations
Puspitarini, Lucky; Lallement, Rosine
2015-09-30
Accurate and detailed three-dimensional (3D) maps of Galactic interstellar medium (ISM) are still lacking. One way to obtain such 3D descriptions is to record a large set of individual absorption or reddening measurements toward target stars located at various known distances and directions. The inversion of these measurements using a tomographic method can produce spatial distribution of the ISM. Until recently absorption data were very limited and distances to the target stars are still uncertain, but the situation will greatly improve thanks to current and future massive stellar surveys from ground, and to Gaia mission. To prepare absorption data for inversion from a huge number of stellar spectra, automated tools are needed. We have developed various spectral analysis tools adapted to different type of spectra, early- or late- type star. We also have used diffuse interstellar bands (DIBs) to trace IS structures and kinematics. Although we do not know yet their carriers, they can be a promising tool to trace distant interstellar clouds or Galactic arms. We present some examples of the interstellar fitting and show the potentiality of DIBs in tracing the ISM. We will also briefly show and comment the latest 3D map of the local ISM which reveal nearby cloud complexes and cavities.
3D Printing Bioceramic Porous Scaffolds with Good Mechanical Property and Cell Affinity.
Chang, Chih-Hao; Lin, Chih-Yang; Liu, Fwu-Hsing; Chen, Mark Hung-Chih; Lin, Chun-Pin; Ho, Hong-Nerng; Liao, Yunn-Shiuan
2015-01-01
Artificial bone grafting is widely used in current orthopedic surgery for bone defect problems. Unfortunately, surgeons remain unsatisfied with the current commercially available products. One of the major complaints is that these products cannot provide sufficient mechanical strength to support the human skeletal structure. In this study, we aimed to develop a bone scaffold with better mechanical property and good cell affinity by 3D printing (3DP) techniques. A self-developed 3D printer with laser-aided gelling (LAG) process was used to fabricate bioceramic scaffolds with inter-porous structures. To improve the mechanical property of the bioceramic parts after heating, CaCO3 was added to the silica ceramic slurry. CaCO3 was blended into a homogenous SiO2-sol dispersion at weight ratios varying from 0/100 to 5/95 to 9/91 (w/w). Bi-component CaCO3/SiO2-sol was prepared as a biocomposite for the 3DP scaffold. The well-mixed biocomposite was used to fabricate the bioceramic green part using the LAG method. The varied scaffolds were sintered at different temperatures ranging from 900 to 1500°C, and the mechanical property was subsequently analyzed. The scaffolds showed good property with the composite ratio of 5:95 CaCO3:SiO2 at a sintering temperature of 1300°C. The compressive strength was 47 MPa, and the porosity was 34%. The topography of the sintered 3DP bioceramic scaffold was examined by SEM, EDS and XRD. The silica bioceramic presented no cytotoxicity and good MG-63 osteoblast-like cell affinity, demonstrating good biocompatibility. Therefore, the new silica biocomposite is viable for fabricating 3DP bone bioceramics with improved mechanical property and good cell affinity. PMID:26618362
3D Printing Bioceramic Porous Scaffolds with Good Mechanical Property and Cell Affinity
Chang, Chih-Hao; Lin, Chih-Yang; Liu, Fwu-Hsing; Chen, Mark Hung-Chih; Lin, Chun-Pin; Ho, Hong-Nerng; Liao, Yunn-Shiuan
2015-01-01
Artificial bone grafting is widely used in current orthopedic surgery for bone defect problems. Unfortunately, surgeons remain unsatisfied with the current commercially available products. One of the major complaints is that these products cannot provide sufficient mechanical strength to support the human skeletal structure. In this study, we aimed to develop a bone scaffold with better mechanical property and good cell affinity by 3D printing (3DP) techniques. A self-developed 3D printer with laser-aided gelling (LAG) process was used to fabricate bioceramic scaffolds with inter-porous structures. To improve the mechanical property of the bioceramic parts after heating, CaCO3 was added to the silica ceramic slurry. CaCO3 was blended into a homogenous SiO2-sol dispersion at weight ratios varying from 0/100 to 5/95 to 9/91 (w/w). Bi-component CaCO3/SiO2-sol was prepared as a biocomposite for the 3DP scaffold. The well-mixed biocomposite was used to fabricate the bioceramic green part using the LAG method. The varied scaffolds were sintered at different temperatures ranging from 900 to 1500°C, and the mechanical property was subsequently analyzed. The scaffolds showed good property with the composite ratio of 5:95 CaCO3:SiO2 at a sintering temperature of 1300°C. The compressive strength was 47 MPa, and the porosity was 34%. The topography of the sintered 3DP bioceramic scaffold was examined by SEM, EDS and XRD. The silica bioceramic presented no cytotoxicity and good MG-63 osteoblast-like cell affinity, demonstrating good biocompatibility. Therefore, the new silica biocomposite is viable for fabricating 3DP bone bioceramics with improved mechanical property and good cell affinity. PMID:26618362
3D Printing Bioceramic Porous Scaffolds with Good Mechanical Property and Cell Affinity.
Chang, Chih-Hao; Lin, Chih-Yang; Liu, Fwu-Hsing; Chen, Mark Hung-Chih; Lin, Chun-Pin; Ho, Hong-Nerng; Liao, Yunn-Shiuan
2015-01-01
Artificial bone grafting is widely used in current orthopedic surgery for bone defect problems. Unfortunately, surgeons remain unsatisfied with the current commercially available products. One of the major complaints is that these products cannot provide sufficient mechanical strength to support the human skeletal structure. In this study, we aimed to develop a bone scaffold with better mechanical property and good cell affinity by 3D printing (3DP) techniques. A self-developed 3D printer with laser-aided gelling (LAG) process was used to fabricate bioceramic scaffolds with inter-porous structures. To improve the mechanical property of the bioceramic parts after heating, CaCO3 was added to the silica ceramic slurry. CaCO3 was blended into a homogenous SiO2-sol dispersion at weight ratios varying from 0/100 to 5/95 to 9/91 (w/w). Bi-component CaCO3/SiO2-sol was prepared as a biocomposite for the 3DP scaffold. The well-mixed biocomposite was used to fabricate the bioceramic green part using the LAG method. The varied scaffolds were sintered at different temperatures ranging from 900 to 1500°C, and the mechanical property was subsequently analyzed. The scaffolds showed good property with the composite ratio of 5:95 CaCO3:SiO2 at a sintering temperature of 1300°C. The compressive strength was 47 MPa, and the porosity was 34%. The topography of the sintered 3DP bioceramic scaffold was examined by SEM, EDS and XRD. The silica bioceramic presented no cytotoxicity and good MG-63 osteoblast-like cell affinity, demonstrating good biocompatibility. Therefore, the new silica biocomposite is viable for fabricating 3DP bone bioceramics with improved mechanical property and good cell affinity.
Hou, Hongshuai; Banks, Craig E; Jing, Mingjun; Zhang, Yan; Ji, Xiaobo
2015-12-16
A new methodology for the synthesis of carbon quantum dots (CQDs) for large production is proposed. The as-obtained CQDs can be transformed into 3D porous carbon frameworks exhibiting superb sodium storage properties with ultralong cycle life and ultrahigh rate capability, comparable to state-of-the-art carbon anode materials for sodium-ion batteries.
Highly Porous Gelatin Reinforced 3D Scaffolds for Articular Cartilage Regeneration.
Amadori, Sofia; Torricelli, Paola; Panzavolta, Silvia; Parrilli, Annapaola; Fini, Milena; Bigi, Adriana
2015-07-01
3D highly porous (93% total porosity) gelatin scaffolds were prepared according to a novel, simple method, which implies gelatin foaming, gelification, soaking into ethanol and successive freeze-drying. Reinforcement of the as-prepared scaffolds (GEL) was performed through immersion in aqueous solutions at different gelatin concentrations. Reinforcement solutions with and without genipin addition allowed to prepare two series of samples:cross-linked and uncross-linked samples, respectively. The amount of gelatin adsorbed onto the reinforced samples increases as a function of gelatin concentration in solution and provokes a drastic improvement of the compressive modulus and collapse strength up to values of about 30 and 4 MPa, respectively. The open and interconnected porosity, although slightly reduced, is still of the order of 80% in the samples reinforced with the highest concentration of gelatin. Water uptake ability evaluated after immersion in PBS for 20 s decreases with gelatin reinforcement. The presence of genipin in cross-linked samples reduces gelatin release and stabilizes the scaffolds in solution. Chondrocytes from human articular cartilage adhere, proliferate, and penetrate into the scaffolds. The evaluation of differentiation markers both on the supernatants of cell culture and by means of quantitative polymerase chain reaction (qPCR) indicates a dose-dependent promotion of cell differentiation.
Osteogenic effect of controlled released rhBMP-2 in 3D printed porous hydroxyapatite scaffold.
Wang, Hai; Wu, Gui; Zhang, Jing; Zhou, Kui; Yin, Bo; Su, Xinlin; Qiu, Guixing; Yang, Guang; Zhang, Xianglin; Zhou, Gang; Wu, Zhihong
2016-05-01
Recently, 3D printing as effective technology has been highlighted in the biomedical field. Previously, a porous hydroxyapatite (HA) scaffold with the biocompatibility and osteoconductivity has been developed by this method. However, its osteoinductivity is limited. The main purpose of this study was to improve it by the introduction of recombinant human bone morphogenetic protein-2 (rhBMP-2). This scaffold was developed by coating rhBMP-2-delivery microspheres with collagen. These synthesized scaffolds were characterized by Scanning Electron Microscopy (SEM), a delivery test in vitro, cell culture, and the experiments in vivo by a Micro-computed tomography (μCT) scan and histological evaluation of VanGieson staining. SEM results indicated the surface of scaffolds were more fit for the adhesion of hMSCs to coat collagen/rhBMP-2 microspheres. Biphasic release of rhBMP-2 could continue for more than 21 days, and keep its osteoinductivity to induce osteogenic differentiation of hMSCs in vitro. In addition, the experiments in vivo showed that the scaffold had a good bone regeneration capacity. These findings demonstrate that the HA/Collagen/Chitosan Microspheres system can simultaneously achieve localized long-term controlled release of rhBMP-2 and bone regeneration, which provides a promising route for improving the treatment of bone defects.
Porous Structures in Stacked, Crumpled and Pillared Graphene-Based 3D Materials
Guo, Fei; Creighton, Megan; Chen, Yantao; Hurt, Robert; Külaots, Indrek
2015-01-01
Graphene, an atomically thin material with the theoretical surface area of 2600 m2g−1, has great potential in the fields of catalysis, separation, and gas storage if properly assembled into functional 3D materials at large scale. In ideal non-interacting ensembles of non-porous multilayer graphene plates, the surface area can be adequately estimated using the simple geometric law ~ 2600 m2g−1/N, where N is the number of graphene sheets per plate. Some processing operations, however, lead to secondary plate-plate stacking, folding, crumpling or pillaring, which give rise to more complex structures. Here we show that bulk samples of multilayer graphene plates stack in an irregular fashion that preserves the 2600/N surface area and creates regular slot-like pores with sizes that are multiples of the unit plate thickness. In contrast, graphene oxide deposits into films with massive area loss (2600 to 40 m2g−1) due to nearly perfect alignment and stacking during the drying process. Pillaring graphene oxide sheets by co-deposition of colloidal-phase particle-based spacers has the potential to partially restore the large monolayer surface. Surface areas as high as 1000 m2g−1 are demonstrated here through colloidal-phase deposition of graphene oxide with water-dispersible aryl-sulfonated ultrafine carbon black as a pillaring agent. PMID:26478597
Cation Exchange in Dynamic 3D Porous Magnets: Improvement of the Physical Properties.
Grancha, Thais; Acosta, Alvaro; Cano, Joan; Ferrando-Soria, Jesús; Seoane, Beatriz; Gascon, Jorge; Pasán, Jorge; Armentano, Donatella; Pardo, Emilio
2015-11-16
We report two novel three-dimensional porous coordination polymers (PCPs) of formulas Li4{Mn4[Cu2(Me3mpba)2]3}·68H2O (2) and K4{Mn4[Cu2(Me3mpba)2]3}·69H2O (3) obtained-via alkali cation exchange in a single-crystal to single-crystal process-from the earlier reported anionic manganese(II)-copper(II) PCP of formula Na4{Mn4[Cu2(Me3mpba)2]3}·60H2O (1) [Me3mpba(4-) = N,N'-2,4,6-trimethyl-1,3-phenylenebis(oxamate)]. This postsynthetic process succeeds where the direct synthesis in solution from the corresponding building blocks fails and affords significantly more robust PCPs with enhanced magnetic properties [long-range 3D magnetic ordering temperatures for the dehydrated phases (1'-3') of 2.0 (1'), 12.0 (2'), and 20.0 K (3')]. Changes in the adsorptive properties upon postsynthetic exchange suggest that the nature, electrostatic properties, mobility, and location of the cations within the framework are crucial for the enhanced structural stability. Overall, these results further confirm the potential of postsynthetic methods (including cation exchange) to obtain PCPs with novel or enhanced physical properties while maintaining unaltered their open-framework structures. PMID:26492551
Cation Exchange in Dynamic 3D Porous Magnets: Improvement of the Physical Properties.
Grancha, Thais; Acosta, Alvaro; Cano, Joan; Ferrando-Soria, Jesús; Seoane, Beatriz; Gascon, Jorge; Pasán, Jorge; Armentano, Donatella; Pardo, Emilio
2015-11-16
We report two novel three-dimensional porous coordination polymers (PCPs) of formulas Li4{Mn4[Cu2(Me3mpba)2]3}·68H2O (2) and K4{Mn4[Cu2(Me3mpba)2]3}·69H2O (3) obtained-via alkali cation exchange in a single-crystal to single-crystal process-from the earlier reported anionic manganese(II)-copper(II) PCP of formula Na4{Mn4[Cu2(Me3mpba)2]3}·60H2O (1) [Me3mpba(4-) = N,N'-2,4,6-trimethyl-1,3-phenylenebis(oxamate)]. This postsynthetic process succeeds where the direct synthesis in solution from the corresponding building blocks fails and affords significantly more robust PCPs with enhanced magnetic properties [long-range 3D magnetic ordering temperatures for the dehydrated phases (1'-3') of 2.0 (1'), 12.0 (2'), and 20.0 K (3')]. Changes in the adsorptive properties upon postsynthetic exchange suggest that the nature, electrostatic properties, mobility, and location of the cations within the framework are crucial for the enhanced structural stability. Overall, these results further confirm the potential of postsynthetic methods (including cation exchange) to obtain PCPs with novel or enhanced physical properties while maintaining unaltered their open-framework structures.
Surface functionalization of 3D glass-ceramic porous scaffolds for enhanced mineralization in vitro
NASA Astrophysics Data System (ADS)
Ferraris, Sara; Vitale-Brovarone, Chiara; Bretcanu, Oana; Cassinelli, Clara; Vernè, Enrica
2013-04-01
Bone reconstruction after tissue loosening due to traumatic, pathological or surgical causes is in increasing demand. 3D scaffolds are a widely studied solution for supporting new bone growth. Bioactive glass-ceramic porous materials can offer a three-dimensional structure that is able to chemically bond to bone. The ability to surface modify these devices by grafting biologically active molecules represents a challenge, with the aim of stimulating physiological bone regeneration with both inorganic and organic signals. In this research work glass ceramic scaffolds with very high mechanical properties and moderate bioactivity have been functionalized with the enzyme alkaline phosphatase (ALP). The material surface was activated in order to expose hydroxyl groups. The activated surface was further grafted with ALP both via silanization and also via direct grafting to the surface active hydroxyl groups. Enzymatic activity of grafted samples were measured by means of UV-vis spectroscopy before and after ultrasonic washing in TRIS-HCl buffer solution. In vitro inorganic bioactivity was investigated by soaking the scaffolds after the different steps of functionalization in a simulated body fluid (SBF). SEM observations allowed the monitoring of the scaffold morphology and surface chemical composition after soaking in SBF. The presence of ALP enhanced the in vitro inorganic bioactivity of the tested material.
Estimation of Porous Medium Tortuosity Directly from Flow Path Lines
NASA Astrophysics Data System (ADS)
Pakalapati, Suryanarayana; Celik, Ismail
2013-11-01
A thorough understanding of transport processes inside porous materials is vital for improving the efficiency of energy devices such as fuel cells and batteries. Continuum simulations of porous media make use of parameters such as porosity and tortuosity to account for the influence of the actual pore geometry and orientation on the transport processes. In most studies the tortuosity is treated as an adjustable parameter which is calibrated to match the predictions with the experiments. In this study a direct method is utilized to estimate the tortuosity of a porous medium. The actual geometry of a fuel cell electrode is obtained from an experimental study where the porous structure is reconstructed from slice images. The detailed geometry of porous medium is used to simulate fully resolved fluid flow through the pores. Stream lines are then generated which show the actual paths taken by the fluid flowing through the porous medium. The lengths of these path lines are then used to calculate the tortuosity of the porous medium by employing the actual definition of the tortuosity. It is shown that the tortuosities obtained in this way are smaller than the typical values reported in literature.
Instant gelation synthesis of 3D porous MoS2@C nanocomposites for lithium ion batteries.
Fei, Ling; Xu, Yun; Wu, Xiaofei; Chen, Gen; Li, Yuling; Li, Binsong; Deng, Shuguang; Smirnov, Sergei; Fan, Hongyou; Luo, Hongmei
2014-04-01
Three-dimensional (3D) nanoporous architectures, possessing high surface area, massive pores, and excellent structural stability, are highly desirable for many applications including catalysts and electrode materials in lithium ion batteries. However, the preparation of such materials remains a major challenge. Here, we introduce a novel method, instant gelation, for the synthesis of such materials. The as-prepared porous 3D MoS2@C nanocomposites, with layered MoS2 clusters or strips ingrained in porous and conductive 3D carbon matrix, indeed showed excellent electrochemical performance when applied as anode materials for lithium ion batteries. Its interconnected carbon network ensures good conductivity and fast electron transport; the micro-, and mesoporous nature effectively shortens the lithium ion diffusion path and provides room necessary for volume expansion. The large specific surface area is beneficial for a better contact between electrode materials and electrolyte.
NASA Astrophysics Data System (ADS)
De Lucia, Marco; Kühn, Michael
2015-04-01
The 3D imaging of porous media through micro tomography allows the characterization of porous space and mineral abundances with unprecedented resolution. Such images can be used to perform computational determination of permeability and to obtain a realistic measure of the mineral surfaces exposed to fluid flow and thus to chemical interactions. However, the volume of the plugs that can be analysed with such detail is in the order of 1 cm3, so that their representativity at a larger scale, i.e. as needed for reactive transport modelling at Darcy scale, is questionable at best. In fact, the fine scale heterogeneity (from plug to plug at few cm distance within the same core) would originate substantially different readings of the investigated properties. Therefore, a comprehensive approach including the spatial variability and heterogeneity at the micro- and plug scale needs to be adopted to gain full advantage from the high resolution images in view of the upscaling to Darcy scale. In the framework of the collaborative project H2STORE, micro-CT imaging of different core samples from potential H2-storage sites has been performed by partners at TU Clausthal and Jena University before and after treatment with H2/CO2 mixtures in pressurized autoclaves. We present here the workflow which has been implemented to extract the relevant features from the available data concerning the heterogeneity of the medium at the microscopic and plug scale and to correlate the observed chemical reactions and changes in the porous structure with the geometrical features of the medium. First, a multivariate indicator-based geostatistical model for the microscopic structure of the plugs has been built and fitted to the available images. This involved the implementation of exploratory analysis algorithms such as experimental indicator variograms and cross-variograms. The implemented methods are able to efficiently deal with images in the order of 10003 voxels making use of parallelization
Simultaneous elastic parameter inversion in 2-D/3-D TTI medium combined later arrival times
NASA Astrophysics Data System (ADS)
Bai, Chao-ying; Wang, Tao; Yang, Shang-bei; Li, Xing-wang; Huang, Guo-jiao
2016-04-01
Traditional traveltime inversion for anisotropic medium is, in general, based on a "weak" assumption in the anisotropic property, which simplifies both the forward part (ray tracing is performed once only) and the inversion part (a linear inversion solver is possible). But for some real applications, a general (both "weak" and "strong") anisotropic medium should be considered. In such cases, one has to develop a ray tracing algorithm to handle with the general (including "strong") anisotropic medium and also to design a non-linear inversion solver for later tomography. Meanwhile, it is constructive to investigate how much the tomographic resolution can be improved by introducing the later arrivals. For this motivation, we incorporated our newly developed ray tracing algorithm (multistage irregular shortest-path method) for general anisotropic media with a non-linear inversion solver (a damped minimum norm, constrained least squares problem with a conjugate gradient approach) to formulate a non-linear inversion solver for anisotropic medium. This anisotropic traveltime inversion procedure is able to combine the later (reflected) arrival times. Both 2-D/3-D synthetic inversion experiments and comparison tests show that (1) the proposed anisotropic traveltime inversion scheme is able to recover the high contrast anomalies and (2) it is possible to improve the tomographic resolution by introducing the later (reflected) arrivals, but not as expected in the isotropic medium, because the different velocity (qP, qSV and qSH) sensitivities (or derivatives) respective to the different elastic parameters are not the same but are also dependent on the inclination angle.
3D MHD SIMULATION OF FLARE SUPRA-ARCADE DOWNFLOWS IN A TURBULENT CURRENT SHEET MEDIUM
Cécere, M.; Zurbriggen, E.; Costa, A.; Schneiter, M.
2015-07-01
Supra-arcade downflows (SADs) are sunward, generally dark, plasma density depletions originated above posteruption flare arcades. In this paper, using 3D MHD simulations we investigate whether the SAD cavities can be produced by a direct combination of the tearing mode and Kelvin–Helmholtz instabilities leading to a turbulent current sheet (CS) medium or if the current sheet is merely the background where SADs are produced, triggered by an impulsive deposition of energy. We find that to give an account of the observational dark lane structures an addition of local energy, provided by a reconnection event, is required. We suggest that there may be a closed relation between characteristic SAD sizes and CS widths that must be satisfied to obtain an observable SAD.
From ATLASGAL to SEDIGISM: Towards a Complete 3D View of the Dense Galactic Interstellar Medium
NASA Astrophysics Data System (ADS)
Schuller, F.; Urquhart, J.; Bronfman, L.; Csengeri, T.; Bontemps, S.; Duarte-Cabral, A.; Giannetti, A.; Ginsburg, A.; Henning, T.; Immer, K.; Leurini, S.; Mattern, M.; Menten, K.; Molinari, S.; Muller, E.; Sánchez-Monge, A.; Schisano, E.; Suri, S.; Testi, L.; Wang, K.; Wyrowski, F.; Zavagno, A.
2016-09-01
The ATLASGAL survey has provided the first unbiased view of the inner Galactic Plane at sub-millimetre wavelengths. This is the largest ground-based survey of its kind to date, covering 420 square degrees at a wavelength of 870 µm. The reduced data, consisting of images and a catalogue of > 104 compact sources, are available from the ESO Science Archive Facility through the Phase 3 infrastructure. The extremely rich statistics of this survey initiated several follow-up projects, including spectroscopic observations to explore molecular complexity and high angular resolution imaging with the Atacama Large Millimeter/submillimeter Array (ALMA), aimed at resolving individual protostars. The most extensive follow-up project is SEDIGISM, a 3D mapping of the dense interstellar medium over a large fraction of the inner Galaxy. Some notable results of these surveys are highlighted.
NASA Astrophysics Data System (ADS)
Mural, Prasanna Kumar S.; Jain, Shubham; Kumar, Sachin; Madras, Giridhar; Bose, Suryasarathi
2016-04-01
3D porous membranes were developed by etching one of the phases (here PEO, polyethylene oxide) from melt-mixed PE/PEO binary blends. Herein, we have systematically discussed the development of these membranes using X-ray micro-computed tomography. The 3D tomograms of the extruded strands and hot-pressed samples revealed a clear picture as to how the morphology develops and coarsens over a function of time during post-processing operations like compression molding. The coarsening of PE/PEO blends was traced using X-ray micro-computed tomography and scanning electron microscopy (SEM) of annealed blends at different times. It is now understood from X-ray micro-computed tomography that by the addition of a compatibilizer (here lightly maleated PE), a stable morphology can be visualized in 3D. In order to anchor biocidal graphene oxide sheets onto these 3D porous membranes, the PE membranes were chemically modified with acid/ethylene diamine treatment to anchor the GO sheets which were further confirmed by Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS) and surface Raman mapping. The transport properties through the membrane clearly reveal unimpeded permeation of water which suggests that anchoring GO on to the membranes does not clog the pores. Antibacterial studies through the direct contact of bacteria with GO anchored PE membranes resulted in 99% of bacterial inactivation. The possible bacterial inactivation through physical disruption of the bacterial cell wall and/or reactive oxygen species (ROS) is discussed herein. Thus this study opens new avenues in designing polyolefin based antibacterial 3D porous membranes for water purification.3D porous membranes were developed by etching one of the phases (here PEO, polyethylene oxide) from melt-mixed PE/PEO binary blends. Herein, we have systematically discussed the development of these membranes using X-ray micro-computed tomography. The 3D tomograms of the extruded strands and
Intermittent Lagrangian velocities and accelerations in three-dimensional porous medium flow.
Holzner, M; Morales, V L; Willmann, M; Dentz, M
2015-07-01
Intermittency of Lagrangian velocity and acceleration is a key to understanding transport in complex systems ranging from fluid turbulence to flow in porous media. High-resolution optical particle tracking in a three-dimensional (3D) porous medium provides detailed 3D information on Lagrangian velocities and accelerations. We find sharp transitions close to pore throats, and low flow variability in the pore bodies, which gives rise to stretched exponential Lagrangian velocity and acceleration distributions characterized by a sharp peak at low velocity, superlinear evolution of particle dispersion, and double-peak behavior in the propagators. The velocity distribution is quantified in terms of pore geometry and flow connectivity, which forms the basis for a continuous-time random-walk model that sheds light on the observed Lagrangian flow and transport behaviors.
Design of advanced porous graphene materials: from graphene nanomesh to 3D architectures.
Jiang, Lili; Fan, Zhuangjun
2014-02-21
In order to make full utilization of the high intrinsic surface area of graphene, recently, porous graphene materials including graphene nanomesh, crumpled graphene and graphene foam, have attracted tremendous attention and research interest, owing to their exceptional porous structure (high surface area, and high pore volume) in combination with the inherent properties of graphene, such as high electronic conductivity, good thermal stability, and excellent mechanical strength. Interestingly, porous graphene materials and their derivatives have been explored in a wide range of applications in the fields of electronic and photonic devices, energy storage, gas separation/storage, oil absorption and sensors. This article reviews recent progress in the synthesis, characterization, properties, and applications of porous graphene materials. We aim to highlight the importance of designing different porous structures of graphene to meet future challenges, and the trend on future design of porous graphene materials is analyzed.
Design of advanced porous graphene materials: from graphene nanomesh to 3D architectures
NASA Astrophysics Data System (ADS)
Jiang, Lili; Fan, Zhuangjun
2014-01-01
In order to make full utilization of the high intrinsic surface area of graphene, recently, porous graphene materials including graphene nanomesh, crumpled graphene and graphene foam, have attracted tremendous attention and research interest, owing to their exceptional porous structure (high surface area, and high pore volume) in combination with the inherent properties of graphene, such as high electronic conductivity, good thermal stability, and excellent mechanical strength. Interestingly, porous graphene materials and their derivatives have been explored in a wide range of applications in the fields of electronic and photonic devices, energy storage, gas separation/storage, oil absorption and sensors. This article reviews recent progress in the synthesis, characterization, properties, and applications of porous graphene materials. We aim to highlight the importance of designing different porous structures of graphene to meet future challenges, and the trend on future design of porous graphene materials is analyzed.
NASA Astrophysics Data System (ADS)
Jung, Gyeong-Bok; Kim, Ji-Hye; Burm, Jin Sik; Park, Hun-Kuk
2013-05-01
We propose a simple, low-cost, large-area, and functional surface enhanced Raman scattering (SERS) substrate for biomedical applications. The SERS substrate with chitosan-silver nanoparticles (chitosan-Ag NPs) hybrid 3D porous structure was fabricated simply by a one-step method. The chitosan was used as a template for the Ag NPs deposition. SERS enhancement by the chitosan-Ag NPs substrate was experimentally verified using rhodamine B as an analyte. Thiolated single stranded DNA was also measured for atopic dermatitis genetic markers (chemokines CCL17) at a low concentration of 5 pM. We successfully designed a novel SERS substrate with silver nanoparticle hybridized 3D porous chitosan that has the potential to become a highly sensitive and selective tool for biomedical applications.
Ren, Long; Hui, K. N.; Hui, K. S.; Liu, Yundan; Qi, Xiang; Zhong, Jianxin; Du, Yi; Yang, Jianping
2015-01-01
New and novel 3D hierarchical porous graphene aerogels (HPGA) with uniform and tunable meso-pores (e.g., 21 and 53 nm) on graphene nanosheets (GNS) were prepared by a hydrothermal self-assembly process and an in-situ carbothermal reaction. The size and distribution of the meso-pores on the individual GNS were uniform and could be tuned by controlling the sizes of the Co3O4 NPs used in the hydrothermal reaction. This unique architecture of HPGA prevents the stacking of GNS and promises more electrochemically active sites that enhance the electrochemical storage level significantly. HPGA, as a lithium-ion battery anode, exhibited superior electrochemical performance, including a high reversible specific capacity of 1100 mAh/g at a current density of 0.1 A/g, outstanding cycling stability and excellent rate performance. Even at a large current density of 20 A/g, the reversible capacity was retained at 300 mAh/g, which is larger than that of most porous carbon-based anodes reported, suggesting it to be a promising candidate for energy storage. The proposed 3D HPGA is expected to provide an important platform that can promote the development of 3D topological porous systems in a range of energy storage and generation fields. PMID:26382852
Mural, Prasanna Kumar S; Jain, Shubham; Kumar, Sachin; Madras, Giridhar; Bose, Suryasarathi
2016-04-21
3D porous membranes were developed by etching one of the phases (here PEO, polyethylene oxide) from melt-mixed PE/PEO binary blends. Herein, we have systematically discussed the development of these membranes using X-ray micro-computed tomography. The 3D tomograms of the extruded strands and hot-pressed samples revealed a clear picture as to how the morphology develops and coarsens over a function of time during post-processing operations like compression molding. The coarsening of PE/PEO blends was traced using X-ray micro-computed tomography and scanning electron microscopy (SEM) of annealed blends at different times. It is now understood from X-ray micro-computed tomography that by the addition of a compatibilizer (here lightly maleated PE), a stable morphology can be visualized in 3D. In order to anchor biocidal graphene oxide sheets onto these 3D porous membranes, the PE membranes were chemically modified with acid/ethylene diamine treatment to anchor the GO sheets which were further confirmed by Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS) and surface Raman mapping. The transport properties through the membrane clearly reveal unimpeded permeation of water which suggests that anchoring GO on to the membranes does not clog the pores. Antibacterial studies through the direct contact of bacteria with GO anchored PE membranes resulted in 99% of bacterial inactivation. The possible bacterial inactivation through physical disruption of the bacterial cell wall and/or reactive oxygen species (ROS) is discussed herein. Thus this study opens new avenues in designing polyolefin based antibacterial 3D porous membranes for water purification.
NASA Astrophysics Data System (ADS)
Yuan, Zhinan; Zhao, Naiqin; Shi, Chunsheng; Liu, Enzuo; He, Chunnian; He, Fang
2016-05-01
A SiO2/porous carbon nanocomposite was synthesized by a facile combined heat and acid treatments method. The nanocomposite featured a 3D porous carbon structure with amorphous SiO2 nanoparticles embedded in the wall of the pores. The microstructure improved the electrical conductivity, shortened the diffusion distance of lithium ions, and alleviated the volume expansion of SiO2 during Li intercalation. Accordingly, the SiO2/porous carbon nanocomposite displayed excellent cyclic performance with a high reversible capacity of 434 mAh g-1 after 50 cycles at 0.1 A g-1 and rate capability delivering a capacity of 187.4 mAh g-1 even at 5 A g-1.
Vigorous convection in a layered, heterogeneous porous medium
NASA Astrophysics Data System (ADS)
Hewitt, D.; Neufeld, J. A.; Lister, J. R.
2014-12-01
Convective flow in a porous medium plays an important role in numerous geophysical and industrial processes, and has recently been investigated in the context of geological CO2 sequestration. Previous studies of vigorous porous convection at high Rayleigh number Ra have focused on homogeneous porous media, whereas natural porous media are often highly heterogeneous. In particular, many geological porous formations are interspersed with thin, roughly horizontal, low-permeability layers. In order to gain understanding of the interaction of low-permeability layering with convective flow, and to develop simple parameterized models of the underlying physical processes, we have performed a numerical study of high-Ra convection in a two-dimensional porous medium that contains a thin, horizontal, low-permeability interior layer. The medium is heated at the lower boundary and cooled at the upper, which sets up statistically steady convective flow throughout the domain. This archetypal system is readily applicable to compositional convection, owing to an assumption of thermal equilibrium between solid and liquid phase in the medium. We show that, in the limit that both the dimensionless thickness h and permeability Π of the low-permeability layer are small, the flow is described solely by the impedance of the layer Ω= h/Π and by Ra. As Ω → 0 (i.e. h → 0), the system reduces to a homogeneous medium. We observe two notable features as Ω is increased: the dominant horizontal lengthscale of the flow increases; and, surprisingly, the heat flux through the cell, as measured by the Nusselt number Nu, can increase. For larger values of Ω, Nu always decreases. We explore the dependence of the flow on Ra, and develop simple theoretical models to describe some of the observed features of the relationship Nu(Ω). The theoretical models have implications for the simulation of convective dissolution of CO2 at reservoir scales, as heterogeneities can be much smaller than the grid
NASA Astrophysics Data System (ADS)
Peters, C. A.; Crandell, L. E.; Um, W.; Jones, K. W.; Lindquist, W. B.
2011-12-01
Geochemical reactions in the subsurface can alter the porosity and permeability of a porous medium through mineral precipitation and dissolution. While effects on porosity are relatively well understood, changes in permeability are more difficult to estimate. In this work, pore-network modeling is used to estimate the permeability of a porous medium using pore and throat size distributions. These distributions can be determined from 2D Scanning Electron Microscopy (SEM) images of thin sections or from 3D X-ray Computed Tomography (CT) images of small cores. Each method has unique advantages as well as unique sources of error. 3D CT imaging has the advantage of reconstructing a 3D pore network without the inherent geometry-based biases of 2D images but is limited by resolutions around 1 μm. 2D SEM imaging has the advantage of higher resolution, and the ability to examine sub-grain scale variations in porosity and mineralogy, but is limited by the small size of the sample of pores that are quantified. A pore network model was created to estimate flow permeability in a sand-packed experimental column investigating reaction of sediments with caustic radioactive tank wastes in the context of the Hanford, WA site. Before, periodically during, and after reaction, 3D images of the porous medium in the column were produced using the X2B beam line facility at the National Synchrotron Light Source (NSLS) at Brookhaven National Lab. These images were interpreted using 3DMA-Rock to characterize the pore and throat size distributions. After completion of the experiment, the column was sectioned and imaged using 2D SEM in backscattered electron mode. The 2D images were interpreted using erosion-dilation to estimate the pore and throat size distributions. A bias correction was determined by comparison with the 3D image data. A special image processing method was developed to infer the pore space before reaction by digitally removing the precipitate. The different sets of pore
Visualization studies of turbulent transition flows in a porous medium
NASA Technical Reports Server (NTRS)
Bilardo, V. J.
1983-01-01
Results are reported for flow-visualization studies of the flow regimes of water passing through a porous medium consisting of cylindrical glass and plexiglas rods arranged in a complex and fixed three-dimensional geometry. The Reynolds number (Re) varied from 50 to 700; the flow was visualized by injecting a 5% potassium permanganate dye solution into the pores and photographing the resulting dye streaklines with both a still camera and a movie camera. The results indicate that four distinct flow regimes exist in the porous medium: (1) Darcy or creeping flow up to Re = 3; (2) steady inertia-dominated laminar flow for Re = 3-150; (3) unsteady transitional laminar flow for Re = 150-250; and (4) fully turbulent flow for Re greater than 250. It is concluded that a laminar wake instability mechanism typical of the external flow about bluff bodies may be responsible for the overall transition from laminar to turbulent flow in porous media.
Instability of fluid flow over saturated porous medium
NASA Astrophysics Data System (ADS)
Lyubimova, Tatyana; Kolchanova, Ekaterina; Lyubimov, Dmitry
2013-04-01
We investigate the stability of a fluid flow over a saturated porous medium. The problem is of importance due to the applications to washing out of contaminants from the bottom layer of vegetation, whose properties are similar to the properties of porous medium. In the case of porous medium with the relatively high permeability and porosity the flow involves a part of the fluid saturating the porous medium, with the tangential fluid velocity drop occurring because of the resistance of the solid matrix. The drop leads to the instability analogous to Kelvin-Helmholtz one accompanied by the formation of travelling waves. In the present paper we consider a two-layer system consisting of a pure fluid layer and a porous layer saturated by the fluid located underneath. The system is bounded by a rigid surface at the bottom and a non-deformable free surface at the top. It is under the gravity and inclined at a slight angle to the horizontal axis. The boundary conditions at the interface between the fluid and porous layers are the continuity of fluid velocities and the balance of normal and tangential stresses taking into account the resistance of the solid matrix with respect to the fluid flow near the interface [1-2]. The problem is solved in the framework of the Brinkman model applying the classical shooting algorithm with orthogonalization. The stability boundaries of the stationary fluid flow over the saturated porous medium with respect to the small oscillatory perturbations are obtained for the various values of the Darcy number and the ratio of the porous layer thickness to the full thickness of the system d. It was shown that at the d > 0.5 with increasing the porous layer thickness (or with decreasing of the fluid layer thickness) the stability threshold rises. This is because of the fact that the instability is primarily caused by perturbations located in the fluid layer. At the d < 0.5 the reduction of the porous layer thickness leads to the stability threshold
Oxygen- and Nitrogen-Enriched 3D Porous Carbon for Supercapacitors of High Volumetric Capacity.
Li, Jia; Liu, Kang; Gao, Xiang; Yao, Bin; Huo, Kaifu; Cheng, Yongliang; Cheng, Xiaofeng; Chen, Dongchang; Wang, Bo; Sun, Wanmei; Ding, Dong; Liu, Meilin; Huang, Liang
2015-11-11
Efficient utilization and broader commercialization of alternative energies (e.g., solar, wind, and geothermal) hinges on the performance and cost of energy storage and conversion systems. For now and in the foreseeable future, the combination of rechargeable batteries and electrochemical capacitors remains the most promising option for many energy storage applications. Porous carbonaceous materials have been widely used as an electrode for batteries and supercapacitors. To date, however, the highest specific capacitance of an electrochemical double layer capacitor is only ∼200 F/g, although a wide variety of synthetic approaches have been explored in creating optimized porous structures. Here, we report our findings in the synthesis of porous carbon through a simple, one-step process: direct carbonization of kelp in an NH3 atmosphere at 700 °C. The resulting oxygen- and nitrogen-enriched carbon has a three-dimensional structure with specific surface area greater than 1000 m(2)/g. When evaluated as an electrode for electrochemical double layer capacitors, the porous carbon structure demonstrated excellent volumetric capacitance (>360 F/cm(3)) with excellent cycling stability. This simple approach to low-cost carbonaceous materials with unique architecture and functionality could be a promising alternative to fabrication of porous carbon structures for many practical applications, including batteries and fuel cells.
Oxygen- and Nitrogen-Enriched 3D Porous Carbon for Supercapacitors of High Volumetric Capacity.
Li, Jia; Liu, Kang; Gao, Xiang; Yao, Bin; Huo, Kaifu; Cheng, Yongliang; Cheng, Xiaofeng; Chen, Dongchang; Wang, Bo; Sun, Wanmei; Ding, Dong; Liu, Meilin; Huang, Liang
2015-11-11
Efficient utilization and broader commercialization of alternative energies (e.g., solar, wind, and geothermal) hinges on the performance and cost of energy storage and conversion systems. For now and in the foreseeable future, the combination of rechargeable batteries and electrochemical capacitors remains the most promising option for many energy storage applications. Porous carbonaceous materials have been widely used as an electrode for batteries and supercapacitors. To date, however, the highest specific capacitance of an electrochemical double layer capacitor is only ∼200 F/g, although a wide variety of synthetic approaches have been explored in creating optimized porous structures. Here, we report our findings in the synthesis of porous carbon through a simple, one-step process: direct carbonization of kelp in an NH3 atmosphere at 700 °C. The resulting oxygen- and nitrogen-enriched carbon has a three-dimensional structure with specific surface area greater than 1000 m(2)/g. When evaluated as an electrode for electrochemical double layer capacitors, the porous carbon structure demonstrated excellent volumetric capacitance (>360 F/cm(3)) with excellent cycling stability. This simple approach to low-cost carbonaceous materials with unique architecture and functionality could be a promising alternative to fabrication of porous carbon structures for many practical applications, including batteries and fuel cells. PMID:26477268
Liu, Yong; Ma, Jiaqi; Lu, Ting; Pan, Likun
2016-01-01
Carbon nanofibers reinforced 3D porous carbon polyhedra network (e-CNF-PCP) was prepared through electrospinning and subsequent thermal treatment. The morphology, structure and electrochemical performance of the e-CNF-PCP were characterized using scanning electron microscopy, Raman spectra, nitrogen adsorption-desorption, cyclic voltammetry and electrochemical impedance spectroscopy, and their electrosorption performance in NaCl solution was studied. The results show that the e-CNF-PCP exhibits a high electrosorption capacity of 16.98 mg g(-1) at 1.2 V in 500 mg l(-1) NaCl solution, which shows great improvement compared with those of electrospun carbon nanofibers and porous carbon polyhedra. The e-CNF-PCP should be a very promising candidate as electrode material for CDI applications. PMID:27608826
Liu, Yong; Ma, Jiaqi; Lu, Ting; Pan, Likun
2016-01-01
Carbon nanofibers reinforced 3D porous carbon polyhedra network (e-CNF-PCP) was prepared through electrospinning and subsequent thermal treatment. The morphology, structure and electrochemical performance of the e-CNF-PCP were characterized using scanning electron microscopy, Raman spectra, nitrogen adsorption-desorption, cyclic voltammetry and electrochemical impedance spectroscopy, and their electrosorption performance in NaCl solution was studied. The results show that the e-CNF-PCP exhibits a high electrosorption capacity of 16.98 mg g−1 at 1.2 V in 500 mg l−1 NaCl solution, which shows great improvement compared with those of electrospun carbon nanofibers and porous carbon polyhedra. The e-CNF-PCP should be a very promising candidate as electrode material for CDI applications. PMID:27608826
NASA Astrophysics Data System (ADS)
Liu, Yong; Ma, Jiaqi; Lu, Ting; Pan, Likun
2016-09-01
Carbon nanofibers reinforced 3D porous carbon polyhedra network (e-CNF-PCP) was prepared through electrospinning and subsequent thermal treatment. The morphology, structure and electrochemical performance of the e-CNF-PCP were characterized using scanning electron microscopy, Raman spectra, nitrogen adsorption-desorption, cyclic voltammetry and electrochemical impedance spectroscopy, and their electrosorption performance in NaCl solution was studied. The results show that the e-CNF-PCP exhibits a high electrosorption capacity of 16.98 mg g‑1 at 1.2 V in 500 mg l‑1 NaCl solution, which shows great improvement compared with those of electrospun carbon nanofibers and porous carbon polyhedra. The e-CNF-PCP should be a very promising candidate as electrode material for CDI applications.
NASA Astrophysics Data System (ADS)
Bartlewska-Urban, Monika; Zombroń, Marek; Strzelecki, Tomasz
2016-03-01
The following study presents numerical calculations for establishing the impact of temperature changes on the process of distortion of bi-phase medium represented using Biot consolidation equations with Kelvin-Voigt rheological skeleton presented, on the example of thermo-consolidation of a pavement of expressway S17. We analyzed the behavior of the expressway under the action of its own weight, dynamic load caused by traffic and temperature gradient. This paper presents the application of the Biot consolidation model with the Kelvin-Voigt skeleton rheological characteristics and the influence of temperature on the deformation process is taken into account. A three-dimensional model of the medium was created describing the thermal consolidation of a porous medium. The 3D geometrical model of the area under investigation was based on data obtained from the land surveying and soil investigation of a 200 m long section of the expressway and its shoulders.
Moment tensors of a dislocation in a porous medium
NASA Astrophysics Data System (ADS)
Wang, Zhi; Hu, Hengshan
2016-06-01
A dislocation can be represented by a moment tensor for calculating seismic waves. However, the moment tensor expression was derived in an elastic medium and cannot completely describe a dislocation in a porous medium. In this paper, effective moment tensors of a dislocation in a porous medium are derived. It is found that the dislocation is equivalent to two independent moment tensors, i.e., the bulk moment tensor acting on the bulk of the porous medium and the isotropic fluid moment tensor acting on the pore fluid. Both of them are caused by the solid dislocation as well as the fluid-solid relative motion corresponding to fluid injection towards the surrounding rocks (or fluid outflow) through the fault plane. For a shear dislocation, the fluid moment tensor is zero, and the dislocation is equivalent to a double couple acting on the bulk; for an opening dislocation or fluid injection, the two moment tensors are needed to describe the source. The fluid moment tensor only affects the radiated compressional waves. By calculating the ratio of the radiation fields generated by unit fluid moment tensor and bulk moment tensor, it is found that the fast compressional wave radiated by the bulk moment tensor is much stronger than that radiated by the fluid moment tensor, while the slow compressional wave radiated by the fluid moment tensor is several times stronger than that radiated by the bulk moment tensor.
Petrochenko, Peter E; Torgersen, Jan; Gruber, Peter; Hicks, Lucas A; Zheng, Jiwen; Kumar, Girish; Narayan, Roger J; Goering, Peter L; Liska, Robert; Stampfl, Jürgen; Ovsianikov, Aleksandr
2015-04-01
A reproducible method is needed to fabricate 3D scaffold constructs that results in periodic and uniform structures with precise control at sub-micrometer and micrometer length scales. In this study, fabrication of scaffolds by two-photon polymerization (2PP) of a biodegradable urethane and acrylate-based photoelastomer is demonstrated. This material supports 2PP processing with sub-micrometer spatial resolution. The high photoreactivity of the biophotoelastomer permits 2PP processing at a scanning speed of 1000 mm s(-1), facilitating rapid fabrication of relatively large structures (>5 mm(3)). These structures are custom printed for in vitro assay screening in 96-well plates and are sufficiently flexible to enable facile handling and transplantation. These results indicate that stable scaffolds with porosities of greater than 60% can be produced using 2PP. Human bone marrow stromal cells grown on 3D scaffolds exhibit increased growth and proliferation compared to smooth 2D scaffold controls. 3D scaffolds adsorb larger amounts of protein than smooth 2D scaffolds due to their larger surface area; the scaffolds also allow cells to attach in multiple planes and to completely infiltrate the porous scaffolds. The flexible photoelastomer material is biocompatible in vitro and is associated with facile handling, making it a viable candidate for further study of complex 3D-printed scaffolds.
Gauvin, Robert; Chen, Ying-Chieh; Lee, Jin Woo; Soman, Pranav; Zorlutuna, Pinar; Nichol, Jason W.; Bae, Hojae; Chen, Shaochen; Khademhosseini, Ali
2013-01-01
The success of tissue engineering will rely on the ability to generate complex, cell seeded three-dimensional (3D) structures. Therefore, methods that can be used to precisely engineer the architecture and topography of scaffolding materials will represent a critical aspect of functional tissue engineering. Previous approaches for 3D scaffold fabrication based on top-down and process driven methods are often not adequate to produce complex structures due to the lack of control on scaffold architecture, porosity, and cellular interactions. The proposed projection stereolithography (PSL) platform can be used to design intricate 3D tissue scaffolds that can be engineered to mimic the microarchitecture of tissues, based on computer aided design (CAD). The PSL system was developed, programmed and optimized to fabricate 3D scaffolds using gelatin methacrylate (GelMA). Variation of the structure and prepolymer concentration enabled tailoring the mechanical properties of the scaffolds. A dynamic cell seeding method was utilized to improve the coverage of the scaffold throughout its thickness. The results demonstrated that the interconnectivity of pores allowed for uniform human umbilical vein endothelial cells (HUVECs) distribution and proliferation in the scaffolds, leading to high cell density and confluency at the end of the culture period. Moreover, immunohistochemistry results showed that cells seeded on the scaffold maintained their endothelial phenotype, demonstrating the biological functionality of the microfabricated GelMA scaffolds. PMID:22365811
Gauvin, Robert; Chen, Ying-Chieh; Lee, Jin Woo; Soman, Pranav; Zorlutuna, Pinar; Nichol, Jason W; Bae, Hojae; Chen, Shaochen; Khademhosseini, Ali
2012-05-01
The success of tissue engineering will rely on the ability to generate complex, cell seeded three-dimensional (3D) structures. Therefore, methods that can be used to precisely engineer the architecture and topography of scaffolding materials will represent a critical aspect of functional tissue engineering. Previous approaches for 3D scaffold fabrication based on top-down and process driven methods are often not adequate to produce complex structures due to the lack of control on scaffold architecture, porosity, and cellular interactions. The proposed projection stereolithography (PSL) platform can be used to design intricate 3D tissue scaffolds that can be engineered to mimic the microarchitecture of tissues, based on computer aided design (CAD). The PSL system was developed, programmed and optimized to fabricate 3D scaffolds using gelatin methacrylate (GelMA). Variation of the structure and prepolymer concentration enabled tailoring the mechanical properties of the scaffolds. A dynamic cell seeding method was utilized to improve the coverage of the scaffold throughout its thickness. The results demonstrated that the interconnectivity of pores allowed for uniform human umbilical vein endothelial cells (HUVECs) distribution and proliferation in the scaffolds, leading to high cell density and confluency at the end of the culture period. Moreover, immunohistochemistry results showed that cells seeded on the scaffold maintained their endothelial phenotype, demonstrating the biological functionality of the microfabricated GelMA scaffolds.
A generalization of averaging theorems for porous medium analysis
NASA Astrophysics Data System (ADS)
Gray, William G.; Miller, Cass T.
2013-12-01
The contributions of Stephen Whitaker to the rigorous analysis of porous medium flow and transport are built on the use of temporal and spatial averaging theorems applied to phases in representative elementary volumes. Here, these theorems are revisited, common point theorems are considered, extensions of existing theorems are developed to include the effects of lower dimensional entities represented as singularities, and a unified form of the theorems for phases, interfaces, common curves, and common points is established for both macroscale and mixed macroscale-megascale systems. The availability of the full set of theorems facilitates detailed analysis of a variety of porous medium systems. Explicit modeling of the physical processes associated with interfaces, common curves, and common points, as well as the kinematics of these entities, can be undertaken at both the macroscale and megascale based on these theorems.
Oscillatory motion of a viscous fluid in a porous medium
Siraev, R. R.
2015-08-15
An oscillatory flow of an incompressible fluid in a saturated porous medium in the presence of a solid inclusion has been theoretically studied. Unsteady filtration has been described by the Brinkman–Forchheimer equation, where inertial effects and terms with acceleration characteristic of high filtration rates and the presence of pulsations are taken into account. The convective part of the acceleration is responsible for nonlinear effects near macroinhomogeneities. These effects can play a noticeable role in unsteady flows in the porous medium, as is shown for the problem of a solid ball streamed by an oscillatory flow having a given velocity at infinity. The results indicate that a secondary averaged flow appears in the case of high frequencies and cannot be described by Darcy’s or Forchheimer’s filtration laws.
Bharatham, B Hemabarathy; Abu Bakar, Md Zuki; Perimal, Enoch Kumar; Yusof, Loqman Mohamed; Hamid, Muhajir
2014-01-01
A novel porous three-dimensional bone scaffold was developed using a natural polymer (alginate/Alg) in combination with a naturally obtained biomineral (nano cockle shell powder/nCP) through lyophilization techniques. The scaffold was developed in varying composition mixture of Alg-nCP and characterized using various evaluation techniques as well as preliminary in vitro studies on MG63 human osteoblast cells. Morphological observations using SEM revealed variations in structures with the use of different Alg-nCP composition ratios. All the developed scaffolds showed a porous structure with pore sizes ideal for facilitating new bone growth; however, not all combination mixtures showed subsequent favorable characteristics to be used for biological applications. Scaffolds produced using the combination mixture of 40% Alg and 60% nCP produced significantly promising results in terms of mechanical strength, degradation rate, and increased cell proliferation rates making it potentially the optimum composition mixture of Alg-nCP with future application prospects.
Real-time 3D imaging of Haines jumps in porous media flow
Berg, Steffen; Ott, Holger; Klapp, Stephan A.; Schwing, Alex; Neiteler, Rob; Brussee, Niels; Makurat, Axel; Leu, Leon; Enzmann, Frieder; Schwarz, Jens-Oliver; Kersten, Michael; Irvine, Sarah; Stampanoni, Marco
2013-01-01
Newly developed high-speed, synchrotron-based X-ray computed microtomography enabled us to directly image pore-scale displacement events in porous rock in real time. Common approaches to modeling macroscopic fluid behavior are phenomenological, have many shortcomings, and lack consistent links to elementary pore-scale displacement processes, such as Haines jumps and snap-off. Unlike the common singular pore jump paradigm based on observations of restricted artificial capillaries, we found that Haines jumps typically cascade through 10–20 geometrically defined pores per event, accounting for 64% of the energy dissipation. Real-time imaging provided a more detailed fundamental understanding of the elementary processes in porous media, such as hysteresis, snap-off, and nonwetting phase entrapment, and it opens the way for a rigorous process for upscaling based on thermodynamic models. PMID:23431151
Drying of porous materials in a medium with variable potentials
Liu, J.Y. )
1991-08-01
This paper presents an application of the Luikov system of heat and mass transfer equations in dimensionless form to predict the temperature and moisture distributions in a slab of capillary-porous material during drying. The heat and mass potentials of the external medium in the boundary conditions are assumed to vary linearly with time. The method of solution is illustrated by considering the drying of a slab of lumber. Numerical results based on the estimated thermophysical properties of spruce are presented.
Laboratory investigations of steam flow in a porous medium.
Herkelrath, W.N.; Moench, A.F.; O'Neal, II
1983-01-01
Experiments were carried out in the laboratory to test a theory of transient flow of pure steam in a uniform porous medium. It was found in experiments run at 100o, 125o, and 146oC that the time required for steam pressure transients to propagate through an unconsolidated material containing sand, silt, and clay was 10-25 times longer than predicted by conventional superheated steam flow theory. -from Authors
Optimization and Use of 3D sintered porous material in medical field for mixing fibrin glue.
NASA Astrophysics Data System (ADS)
Delmotte, Y.; Laroumanie, H.; Brossard, G.
2012-04-01
In medical field, Mixing of two or more chemical components (liquids and/or gases) is extremely important as improper mixing can affect the physico-chemical properties of the final product. At Baxter Healthcare Corporation, we are using a sintered porous material (PM) as a micro-mixer in medical device for mixing Fibrinogen and Thrombin in order to obtain a homogeneous polymerized Fibrin glue clot used in surgery. First trials were carried out with an interconnected PM from Porvair® (made of PE - porosity: 40% - permeability: 18Darcy). The injection rate is very low, usually about 10mL/min (Re number about 50) which keeps fluids in a laminar flow. Such a low flow rate does not favour mixing of fluids having gradient of viscosity if a mixer is not used. Promising results that were obtained lead the team to understand this ability to mix fluids which will be presented in the poster. Topology of porous media (PM) which associates a solid phase with interconnected (or not) porous structure is known and used in many commodity products. Researches on PM usually focus on flows inside this structure. By opposition to transport and filtration capacity, as well as mechanic and thermic properties, mixing is rarely associated with PM. However over the past few years, we shown that some type of PM have a real capacity to mix certain fluids. Poster will also describe the problematic of mixing complex biological fluids as fibrinogen and Thrombin. They indeed present a large viscosity difference (ratio about 120) limiting the diffusion and the interaction between the two solutions. As those products are expensive, we used Water (1cPo) and Glycerol 87% (120cPo) which are matching the viscosities of Thrombin and Fibrinogen. A parametric investigation of the "porous micro-mixer" as well as a scale up investigation was carried out to examine the influence of both diffusion and advection to successful mix fluids of different viscosity. Experiments were implemented with Planar Laser
PHT3D-UZF: A reactive transport model for variably-saturated porous media
Wu, Ming Zhi; Post, Vincent E. A.; Salmon, S. Ursula; Morway, Eric; Prommer, H.
2016-01-01
A modified version of the MODFLOW/MT3DMS-based reactive transport model PHT3D was developed to extend current reactive transport capabilities to the variably-saturated component of the subsurface system and incorporate diffusive reactive transport of gaseous species. Referred to as PHT3D-UZF, this code incorporates flux terms calculated by MODFLOW's unsaturated-zone flow (UZF1) package. A volume-averaged approach similar to the method used in UZF-MT3DMS was adopted. The PHREEQC-based computation of chemical processes within PHT3D-UZF in combination with the analytical solution method of UZF1 allows for comprehensive reactive transport investigations (i.e., biogeochemical transformations) that jointly involve saturated and unsaturated zone processes. Intended for regional-scale applications, UZF1 simulates downward-only flux within the unsaturated zone. The model was tested by comparing simulation results with those of existing numerical models. The comparison was performed for several benchmark problems that cover a range of important hydrological and reactive transport processes. A 2D simulation scenario was defined to illustrate the geochemical evolution following dewatering in a sandy acid sulfate soil environment. Other potential applications include the simulation of biogeochemical processes in variably-saturated systems that track the transport and fate of agricultural pollutants, nutrients, natural and xenobiotic organic compounds and micropollutants such as pharmaceuticals, as well as the evolution of isotope patterns.
3D-printed silicate porous bioceramics using a non-sacrificial preceramic polymer binder.
Zocca, A; Elsayed, H; Bernardo, E; Gomes, C M; Lopez-Heredia, M A; Knabe, C; Colombo, P; Günster, J
2015-05-22
Silicate bioceramics possess an excellent bioactivity; however, shaping them into complex geometries is still challenging. Therefore, this paper aims to present a new strategy for the shaping of a bioglass-ceramic with controlled geometry and properties starting from a glass powder combined with a preceramic polymer, i.e. a silicon resin, and reactive fillers. The powder-based three-dimensional (3D)-printing of wollastonite (CaSiO3)-based silicate bioceramic parts was demonstrated in this work. The resin plays a dual role, as it not only acts as a non-sacrificial binder for the filler powders in the printing process but it also reacts with the fillers to generate the desired bioceramic phases. The mechanical and physical properties, i.e. ball-on-three-balls test, density, porosity and morphology, were evaluated in 3D-printed discs. These samples possessed a total porosity around 64 vol% and a biaxial flexural strength around 6 MPa. The raw materials used in this work also enabled the 3D-printing of scaffolds possessing a designed multi-scale porosity, suitable bioceramic phase assemblage and a compressive strength of 1 MPa (for cylindrical scaffolds with total porosity ~80 vol%). Solubility in TRIS/HCl and in vitro assays, i.e. viability, cytotoxicity and apoptosis assays, were also performed. In vitro tests indicated good cell viability and no cytotoxicity effect on the cells.
3D-printed silicate porous bioceramics using a non-sacrificial preceramic polymer binder.
Zocca, A; Elsayed, H; Bernardo, E; Gomes, C M; Lopez-Heredia, M A; Knabe, C; Colombo, P; Günster, J
2015-06-01
Silicate bioceramics possess an excellent bioactivity; however, shaping them into complex geometries is still challenging. Therefore, this paper aims to present a new strategy for the shaping of a bioglass-ceramic with controlled geometry and properties starting from a glass powder combined with a preceramic polymer, i.e. a silicon resin, and reactive fillers. The powder-based three-dimensional (3D)-printing of wollastonite (CaSiO3)-based silicate bioceramic parts was demonstrated in this work. The resin plays a dual role, as it not only acts as a non-sacrificial binder for the filler powders in the printing process but it also reacts with the fillers to generate the desired bioceramic phases. The mechanical and physical properties, i.e. ball-on-three-balls test, density, porosity and morphology, were evaluated in 3D-printed discs. These samples possessed a total porosity around 64 vol% and a biaxial flexural strength around 6 MPa. The raw materials used in this work also enabled the 3D-printing of scaffolds possessing a designed multi-scale porosity, suitable bioceramic phase assemblage and a compressive strength of 1 MPa (for cylindrical scaffolds with total porosity ~80 vol%). Solubility in TRIS/HCl and in vitro assays, i.e. viability, cytotoxicity and apoptosis assays, were also performed. In vitro tests indicated good cell viability and no cytotoxicity effect on the cells. PMID:26000907
PHT3D-UZF: A Reactive Transport Model for Variably-Saturated Porous Media.
Wu, Ming Zhi; Post, Vincent E A; Salmon, S Ursula; Morway, Eric D; Prommer, Henning
2016-01-01
A modified version of the MODFLOW/MT3DMS-based reactive transport model PHT3D was developed to extend current reactive transport capabilities to the variably-saturated component of the subsurface system and incorporate diffusive reactive transport of gaseous species. Referred to as PHT3D-UZF, this code incorporates flux terms calculated by MODFLOW's unsaturated-zone flow (UZF1) package. A volume-averaged approach similar to the method used in UZF-MT3DMS was adopted. The PHREEQC-based computation of chemical processes within PHT3D-UZF in combination with the analytical solution method of UZF1 allows for comprehensive reactive transport investigations (i.e., biogeochemical transformations) that jointly involve saturated and unsaturated zone processes. Intended for regional-scale applications, UZF1 simulates downward-only flux within the unsaturated zone. The model was tested by comparing simulation results with those of existing numerical models. The comparison was performed for several benchmark problems that cover a range of important hydrological and reactive transport processes. A 2D simulation scenario was defined to illustrate the geochemical evolution following dewatering in a sandy acid sulfate soil environment. Other potential applications include the simulation of biogeochemical processes in variably-saturated systems that track the transport and fate of agricultural pollutants, nutrients, natural and xenobiotic organic compounds and micropollutants such as pharmaceuticals, as well as the evolution of isotope patterns. PMID:25628017
NASA Astrophysics Data System (ADS)
Naftaly, Aviv; Dror, Ishai; Berkowitz, Brian
2016-07-01
A continuous time random walk particle tracking (CTRW-PT) method was employed to model flow cell experiments that measured transport of engineered nanoparticles (ENPs) in a reactive porous medium. The experiments involved a water-saturated medium containing negatively charged, polyacrylamide beads, resembling many natural soils and aquifer materials, and having the same refraction index as water. Negatively and positively charged ENPs were injected into a uniform flow field in a 3-D horizontal flow cell, and the spatial and temporal concentrations of the evolving ENP plumes were obtained via image analysis. As a benchmark, and to calibrate the model, Congo red tracer was employed in 1-D column and 3-D flow cell experiments, containing the same beads. Negatively charged Au and Ag ENPs demonstrated migration patterns resembling those of the tracer but were slightly more dispersive; the transport was well represented by the CTRW-PT model. In contrast, positively charged AgNPs displayed an unusual behavior: establishment of an initial plume of essentially immobilized ENPs, followed by development of a secondary, freely migrating plume. The mobile plume was found to contain ENPs that, with aging, exhibited aggregation and charge inversion, becoming negatively charged and mobile. In this case, the CTRW-PT model was modified to include a probabilistic law for particle immobilization, to account for the decreasing tendency (over distance and time) of the positively charged AgNPs to attach to the porous medium. The agreement between experimental results and modeling suggests that the CTRW-PT framework can account for the non-Fickian and surface-charge-dependent transport and aging exhibited by ENPs in porous media.
Zhang, Fengqiao; Zhu, Dong; Chen, Xi'an; Xu, Xin; Yang, Zhi; Zou, Chao; Yang, Keqin; Huang, Shaoming
2014-03-01
A three-dimensional (3D) porous graphene hollow sphere (PGHS) framework has been fabricated via a hard template method and used to anchor α-Ni(OH)2 nanoparticles with the size of about 4 nm through electrochemical deposition. It is found that a 3D PGHS framework can improve the capacitive performance of Ni(OH)2 effectively. In hybrid materials, α-Ni(OH)2 achieves the high specific capacitance of 2815 F g(-1) at a scan rate of 5 mV s(-1) and 1950 F g(-1) even at 200 mV s(-1) with a capacitance retention of about 70%, indicating that the α-Ni(OH)2-coated 3D PGHS framework exhibits high rate capability. The excellent performance of such hybrid material is believed to be due to the smaller size of Ni(OH)2 nanoparticles and the PGHS framework with large specific surface area promoting efficient electron transport and facilitating the electrolyte ions migration. These impressive results suggest that the composite is a promising electrode material for an efficient supercapacitor.
Bharatham, B Hemabarathy; Abu Bakar, Md Zuki; Perimal, Enoch Kumar; Yusof, Loqman Mohamed; Hamid, Muhajir
2014-01-01
A novel porous three-dimensional bone scaffold was developed using a natural polymer (alginate/Alg) in combination with a naturally obtained biomineral (nano cockle shell powder/nCP) through lyophilization techniques. The scaffold was developed in varying composition mixture of Alg-nCP and characterized using various evaluation techniques as well as preliminary in vitro studies on MG63 human osteoblast cells. Morphological observations using SEM revealed variations in structures with the use of different Alg-nCP composition ratios. All the developed scaffolds showed a porous structure with pore sizes ideal for facilitating new bone growth; however, not all combination mixtures showed subsequent favorable characteristics to be used for biological applications. Scaffolds produced using the combination mixture of 40% Alg and 60% nCP produced significantly promising results in terms of mechanical strength, degradation rate, and increased cell proliferation rates making it potentially the optimum composition mixture of Alg-nCP with future application prospects. PMID:25110655
NASA Astrophysics Data System (ADS)
Cai, Hongzhu; Xiong, Bin; Han, Muran; Zhdanov, Michael
2014-12-01
This paper presents a linear edge-based finite element method for numerical modeling of 3D controlled-source electromagnetic data in an anisotropic conductive medium. We use a nonuniform rectangular mesh in order to capture the rapid change of diffusive electromagnetic field within the regions of anomalous conductivity and close to the location of the source. In order to avoid the source singularity, we solve Maxwell's equation with respect to anomalous electric field. The nonuniform rectangular mesh can be transformed to hexahedral mesh in order to simulate the bathymetry effect. The sparse system of finite element equations is solved using a quasi-minimum residual method with a Jacobian preconditioner. We have applied the developed algorithm to compute a typical MCSEM response over a 3D model of a hydrocarbon reservoir located in both isotropic and anisotropic mediums. The modeling results are in a good agreement with the solutions obtained by the integral equation method.
Mehr, Nima Ghavidel; Li, Xian; Chen, Gaoping; Favis, Basil D; Hoemann, Caroline D
2015-07-01
Poly(epsilon-caprolactone) (PCL) is a hydrophobic bioplastic under development for bone tissue engineering applications. Limited information is available on the role of internal geometry and cell-surface attachment on osseous integration potential. We tested the hypothesis that human bone marrow mesenchymal stem cells (MSCs) deposit more mineral inside porous 3D PCL scaffolds with fully interconnected 84 or 141 µm pores, when the surfaces are coated with chitosan via Layer-by-Layer (LbL)-deposited polyelectrolytes. Freshly trypsinized MSCs were seeded on PCL 3D cylinders using a novel static cold seeding method in 2% serum to optimally populate all depths of the scaffold discs, followed by 10 days of culture in proliferation medium and 21 additional days in osteogenic medium. MSCs were observed by SEM and histology to spread faster and to proliferate more on chitosan-coated pore surfaces. Most pores, with or without chitosan, became filled by collagen networks sparsely populated with fibroblast-like cells. After 21 days of culture in osteogenic medium, sporadic matrix mineralization was detected histologically and by micro-CT in highly cellular surface layers that enveloped all scaffolds and in cell aggregates in 141 µm pores near the edges. LbL-chitosan promoted punctate mineral deposition on the surfaces of 84 µm pores (p < 0.05 vs. PCL-only) but not the 141 µm pores. This study revealed that LbL-chitosan coatings are sufficient to promote MSC attachment to PCL but only enhance mineral formation in 84 µm pores, suggesting a potential inhibitory role for MSC-derived fibroblasts in osteoblast terminal differentiation. PMID:25504184
Physical and mechanical characterisation of 3D-printed porous titanium for biomedical applications.
El-Hajje, Aouni; Kolos, Elizabeth C; Wang, Jun Kit; Maleksaeedi, Saeed; He, Zeming; Wiria, Florencia Edith; Choong, Cleo; Ruys, Andrew J
2014-11-01
The elastic modulus of metallic orthopaedic implants is typically 6-12 times greater than cortical bone, causing stress shielding: over time, bone atrophies through decreased mechanical strain, which can lead to fracture at the implantation site. Introducing pores into an implant will lower the modulus significantly. Three dimensional printing (3DP) is capable of producing parts with dual porosity features: micropores by process (residual pores from binder burnout) and macropores by design via a computer aided design model. Titanium was chosen due to its excellent biocompatibility, superior corrosion resistance, durability, osteointegration capability, relatively low elastic modulus, and high strength to weight ratio. The mechanical and physical properties of 3DP titanium were studied and compared to the properties of bone. The mechanical and physical properties were tailored by varying the binder (polyvinyl alcohol) content and the sintering temperature of the titanium samples. The fabricated titanium samples had a porosity of 32.2-53.4% and a compressive modulus of 0.86-2.48 GPa, within the range of cancellous bone modulus. Other physical and mechanical properties were investigated including fracture strength, density, fracture toughness, hardness and surface roughness. The correlation between the porous 3DP titanium-bulk modulus ratio and porosity was also quantified. PMID:25052736
Characterization of Silk Fibroin/Chitosan 3D Porous Scaffold and In Vitro Cytology
Zeng, Shuguang; Liu, Lei; Shi, Yong; Qiu, Junqi; Fang, Wei; Rong, Mingdeng; Guo, Zehong; Gao, Wenfeng
2015-01-01
Bone tissue engineering is a powerful tool to treat bone defects caused by trauma, infection, tumors and other factors. Both silk fibroin (SF) and chitosan (CS) are non-toxic and have good biocompatibility, but are poor biological scaffolds when used alone. In this study, the microscopic structure and related properties of SF/CS composite scaffolds with different component ratios were examined. The scaffold material most suitable for osteoblast growth was determined, and these results offer an experimental basis for the future reconstruction of bone defects. First, via freeze-drying and chemical crosslinking methods, SF/CS composites with different component ratios were prepared and their structure was characterized. Changes in the internal structure of the SF and CS mixture were observed, confirming that the mutual modification between the two components was complete and stable. The internal structure of the composite material was porous and three-dimensional with a porosity above 90%. We next studied the pore size, swelling ratio, water absorption ratio, degradation and in vitro cell proliferation. For the 40% SF-60% CS group, the pore size of the scaffold was suitable for the growth of osteoblasts, and the rate of degradation was steady. This favors the early adhesion, growth and proliferation of MG-63 cells. In addition to good biocompatibility and satisfactory cell affinity, this material promotes the secretion of extracellular matrix materials by osteoblasts. Thus, 40% SF-60% CS is a good material for bone tissue engineering. PMID:26083846
Physical and mechanical characterisation of 3D-printed porous titanium for biomedical applications.
El-Hajje, Aouni; Kolos, Elizabeth C; Wang, Jun Kit; Maleksaeedi, Saeed; He, Zeming; Wiria, Florencia Edith; Choong, Cleo; Ruys, Andrew J
2014-11-01
The elastic modulus of metallic orthopaedic implants is typically 6-12 times greater than cortical bone, causing stress shielding: over time, bone atrophies through decreased mechanical strain, which can lead to fracture at the implantation site. Introducing pores into an implant will lower the modulus significantly. Three dimensional printing (3DP) is capable of producing parts with dual porosity features: micropores by process (residual pores from binder burnout) and macropores by design via a computer aided design model. Titanium was chosen due to its excellent biocompatibility, superior corrosion resistance, durability, osteointegration capability, relatively low elastic modulus, and high strength to weight ratio. The mechanical and physical properties of 3DP titanium were studied and compared to the properties of bone. The mechanical and physical properties were tailored by varying the binder (polyvinyl alcohol) content and the sintering temperature of the titanium samples. The fabricated titanium samples had a porosity of 32.2-53.4% and a compressive modulus of 0.86-2.48 GPa, within the range of cancellous bone modulus. Other physical and mechanical properties were investigated including fracture strength, density, fracture toughness, hardness and surface roughness. The correlation between the porous 3DP titanium-bulk modulus ratio and porosity was also quantified.
Pak, Tannaz; Butler, Ian B.; Geiger, Sebastian; van Dijke, Marinus I. J.; Sorbie, Ken S.
2015-01-01
Using X-ray computed microtomography, we have visualized and quantified the in situ structure of a trapped nonwetting phase (oil) in a highly heterogeneous carbonate rock after injecting a wetting phase (brine) at low and high capillary numbers. We imaged the process of capillary desaturation in 3D and demonstrated its impacts on the trapped nonwetting phase cluster size distribution. We have identified a previously unidentified pore-scale event during capillary desaturation. This pore-scale event, described as droplet fragmentation of the nonwetting phase, occurs in larger pores. It increases volumetric production of the nonwetting phase after capillary trapping and enlarges the fluid−fluid interface, which can enhance mass transfer between the phases. Droplet fragmentation therefore has implications for a range of multiphase flow processes in natural and engineered porous media with complex heterogeneous pore spaces. PMID:25646491
Wang, Yongzhong; Kim, Ung-Jin; Blasioli, Dominick J; Kim, Hyeon-Joo; Kaplan, David L
2005-12-01
Adult cartilage tissue has limited self-repair capacity, especially in the case of severe damages caused by developmental abnormalities, trauma, or aging-related degeneration like osteoarthritis. Adult mesenchymal stem cells (MSCs) have the potential to differentiate into cells of different lineages including bone, cartilage, and fat. In vitro cartilage tissue engineering using autologous MSCs and three-dimensional (3-D) porous scaffolds has the potential for the successful repair of severe cartilage damage. Ideally, scaffolds designed for cartilage tissue engineering should have optimal structural and mechanical properties, excellent biocompatibility, controlled degradation rate, and good handling characteristics. In the present work, a novel, highly porous silk scaffold was developed by an aqueous process according to these criteria and subsequently combined with MSCs for in vitro cartilage tissue engineering. Chondrogenesis of MSCs in the silk scaffold was evident by real-time RT-PCR analysis for cartilage-specific ECM gene markers, histological and immunohistochemical evaluations of cartilage-specific ECM components. Dexamethasone and TGF-beta3 were essential for the survival, proliferation and chondrogenesis of MSCs in the silk scaffolds. The attachment, proliferation, and differentiation of MSCs in the silk scaffold showed unique characteristics. After 3 weeks of cultivation, the spatial cell arrangement and the collagen type-II distribution in the MSCs-silk scaffold constructs resembles those in native articular cartilage tissue, suggesting promise for these novel 3-D degradable silk-based scaffolds in MSC-based cartilage repair. Further in vivo evaluation is necessary to fully recognize the clinical relevance of these observations.
Numerical methods for a general class of porous medium equations
Rose, M. E.
1980-03-01
The partial differential equation par. deltau/par. deltat + par. delta(f(u))/par. deltax = par. delta(g(u)par. deltau/par. deltax)/par. deltax, where g(u) is a non-negative diffusion coefficient that may vanish for one or more values of u, was used to model fluid flow through a porous medium. Error estimates for a numerical procedure to approximate the solution are derived. A revised version of this report will appear in Computers and Mathematics with Applications.
Conservations laws for a porous medium equation through nonclassical generators
NASA Astrophysics Data System (ADS)
Gandarias, M. L.
2014-02-01
In Ibragimov (2007) [13] a general theorem on conservation laws was proved. In Gandarias (2011) and Ibragimov (2011) [7,15] the concepts of self-adjoint and quasi self-adjoint equations were generalized and the definitions of weak self-adjoint equations and nonlinearly self-adjoint equations were introduced. In this paper, we find the subclasses of nonlinearly self-adjoint porous medium equations. By using the property of nonlinear self-adjointness, we construct some conservation laws associated with classical and nonclassical generators of the differential equation.
NASA Astrophysics Data System (ADS)
Brueck, C. L.; Meisenheimer, D.; Wildenschild, D.
2015-12-01
Understanding the mechanisms controlling colloid transport and deposition in the vadose zone is an important step in protecting our water resources. Not only may these particles themselves be undesirable contaminants, but they can also aid in the transport of smaller, molecular-scale contaminants by chemical attachment. In this research, we examined the influence that air-water interfaces (AWI) and air-water-solid contact lines (AWS) have on colloid deposition and mobilization in three-dimensional systems. We used x-ray microtomography to visualize the transport of hydrophobic colloids as they move through a partially saturated glass bead pack. Drainage and imbibition experiments were conducted using syringe pumps to control the flow of a colloid suspension through the porous media at 0.6 mL/hr. The high ionic strength fluid was adjusted to a pH of 9.5 and a concentration of 1.0 mol/L KI. During the drainage and imbibition, the flow was periodically halted and allowed to equilibrate before collecting the microtomography scans. Dopants were used to enhance the contrast between the four phases (water, air, beads, and colloids), including potassium iodide dissolved in the fluid, and an outer layer of silver coating the colloids. We hypothesized that AWIs and AWSs will scour and mobilize a significant percentage of colloids, and therefore reduce the concentration of colloids along the vertical profile of the column. The concentration of potassium iodide, and thus the ionic strength, necessary for adequate image segmentation was also explored in separate experiments so that the influence of ionic strength on colloid deposition and mobilization can be studied.
Hou, Jianhua; Cao, Chuanbao; Ma, Xilan; Idrees, Faryal; Xu, Bin; Hao, Xin; Lin, Wei
2014-01-01
Controlled micro/mesopores interconnected structures of three-dimensional (3D) carbon with high specific surface areas (SSA) are successfully prepared by carbonization and activation of biomass (raw rice brans) through KOH. The highest SSA of 2475 m2 g−1 with optimized pore volume of 1.21 cm3 g−1 (40% for mesopores) is achieved for KOH/RBC = 4 mass ratio, than others. The as-prepared 3D porous carbon-based electrode materials for supercapacitors exhibit high specific capacitance specifically at large current densities of 10 A g−1 and 100 A g−1 i.e., 265 F g−1 and 182 F g−1 in 6 M KOH electrolyte, respectively. Moreover, a high power density ca. 1223 W kg−1 (550 W L−1) and energy density 70 W h kg−1 (32 W h L−1) are achieved on the base of active material loading (~10 mg cm2) in the ionic liquid. The findings can open a new avenue to use abundant agricultural by-products as ideal materials with promising applications in high-performance energy-storage devices. PMID:25434348
NASA Astrophysics Data System (ADS)
Yang, Pengliang; Brossier, Romain; Métivier, Ludovic; Virieux, Jean
2016-07-01
In this paper we study 3D multiparameter full waveform inversion (FWI) in viscoelastic media based on the generalized Maxwell/Zener body (GMB/GZB) including arbitrary number of attenuation mechanisms. We present a frequency-domain energy analysis to establish the stability condition of a full anisotropic viscoelastic system, according to zero-valued boundary condition and the elastic-viscoelastic correspondence principle: the real-valued stiffness matrix becomes a complex-valued one in Fourier domain when seismic attenuation is taken into account. We develop a least-squares optimization approach to linearly relate the quality factor with the anelastic coefficients by estimating a set of constants which are independent of the spatial coordinates, which supplies an explicit incorporation of the parameter Q in the general viscoelastic wave equation. By introducing the Lagrangian multipliers into the matrix expression of the wave equation with implicit time integration, we build a systematic formulation of multiparameter full waveform inversion for full anisotropic viscoelastic wave equation, while the equivalent form of the state and adjoint equation with explicit time integration is available to be resolved efficiently. In particular, this formulation lays the foundation for the inversion of the parameter Q in the time domain with full anisotropic viscoelastic properties. In the 3D isotropic viscoelastic settings, the anelastic coefficients and the quality factors using bulk and shear moduli parameterization can be related to the counterparts using P- and S- velocity. Gradients with respect to any other parameter of interest can be found by chain rule. Pioneering numerical validations as well as the real applications of this most generic framework will be carried out to disclose the potential of viscoelastic FWI when adequate high performance computing resources and the field data are available.
NASA Astrophysics Data System (ADS)
Yang, Pengliang; Brossier, Romain; Métivier, Ludovic; Virieux, Jean
2016-10-01
In this paper, we study 3-D multiparameter full waveform inversion (FWI) in viscoelastic media based on the generalized Maxwell/Zener body including arbitrary number of attenuation mechanisms. We present a frequency-domain energy analysis to establish the stability condition of a full anisotropic viscoelastic system, according to zero-valued boundary condition and the elastic-viscoelastic correspondence principle: the real-valued stiffness matrix becomes a complex-valued one in Fourier domain when seismic attenuation is taken into account. We develop a least-squares optimization approach to linearly relate the quality factor with the anelastic coefficients by estimating a set of constants which are independent of the spatial coordinates, which supplies an explicit incorporation of the parameter Q in the general viscoelastic wave equation. By introducing the Lagrangian multipliers into the matrix expression of the wave equation with implicit time integration, we build a systematic formulation of multiparameter FWI for full anisotropic viscoelastic wave equation, while the equivalent form of the state and adjoint equation with explicit time integration is available to be resolved efficiently. In particular, this formulation lays the foundation for the inversion of the parameter Q in the time domain with full anisotropic viscoelastic properties. In the 3-D isotropic viscoelastic settings, the anelastic coefficients and the quality factors using bulk and shear moduli parametrization can be related to the counterparts using P and S velocity. Gradients with respect to any other parameter of interest can be found by chain rule. Pioneering numerical validations as well as the real applications of this most generic framework will be carried out to disclose the potential of viscoelastic FWI when adequate high-performance computing resources and the field data are available.
Features of saturates mixture filtration in porous medium
NASA Astrophysics Data System (ADS)
Kachalov, V. V.; Maikov, I. L.; Molchanov, D. A.; Torchinsky, V. M.; Zaichenko, V. M.
2015-11-01
Consideration is given to the filtration process of the two-phase multicomponent mixture in the porous. It is shown that “mixture-porous medium” system becomes self- oscillating one during filtration process under special conditions when there is a region of retrograde condensation on the phase diagram of the mixture. A mathematical model of the hydrocarbon mixtures filtration process of the methane series has been developed and a computer program for calculating hydrodynamic and thermodynamic characteristics of this process under isothermal conditions with phase transitions has been created. Consideration is given to the basic mechanisms influencing the filtration dynamics. Limits of the model applicability are discussed. Condition range for occurring self-oscillatory properties in “mixture-porous medium” system is determined by medium permeability, viscosity of the mixture, initial and boundary filtration conditions. Experimental filtration research of mixtures “methane-n-butane”, “methane-propane-butane”, “methane-pentane” under the thermodynamic conditions corresponding retrograde condensation region on the phase diagram have shown validity of this model. It is argued that any multicomponent mixture having a retrograde condensation region on the phase diagram appears as self-oscillating system under right conditions.
Axisymmetric viscous gravity currents flowing over a deep porous medium
NASA Astrophysics Data System (ADS)
Spannuth, Melissa; Neufeld, Jerome; Wettlaufer, John S.; Grae Worster, M.
2006-11-01
When a viscous fluid flows over a porous substrate, it not only spreads but also seeps into the underlying medium. Such flows have relevance to the design of shingle beds for use as safety features around storage facilities of dense fluids and to flow through fissures in porous rocks. Whereas previous investigations have been confined to two-dimensional flows of fixed volume, we have investigated currents fed by a constant fluid flux flowing axisymmetrically over a deep porous bed. Our experimental system consisted of glycerin spreading over monodisperse glass spheres of known permeability and the data were analyzed using scaling analyses. We have also solved a mathematical model using the well-known equations for a viscous gravity current spreading due to the slope of its free surface augmented by a simple draining law. Its predictions agree well with our experimental results and quantify, in particular, the maximum distance to which the current spreads as a function of the material and input properties.
NASA Technical Reports Server (NTRS)
Leventis, Nicholas
2005-01-01
In analogy to supramolecular assemblies, which are pursued because of properties above and beyond those of the individual molecules, self-standing monolithic three-dimensional assemblies of nanoparticles also have unique properties attributed to their structure. For example, ultra low-density 3-D assemblies of silica nanoparticles, known as silica aerogels, are characterized by large internal void space, high surface area and very low thermal conductivity. Aerogels, however, are also extremely fragile materials, limiting their application to a few specialized environments, e.g., in nuclear reactors as Cerenkov radiation detectors, in space (refer to NASA's Stardust Program) and aboard certain planetary vehicles (thermal insulators on Mars Rovers in 1997 and 2004). The fragility problem is traced to well-defined weak points in the aerogel skeletal framework, the interparticle necks. Using the surface functionality of the nanoparticle building blocks as a focal point, we have directed attachment of a conformal polymer coating over the entire framework, rendering all necks wider. Thus, although the bulk density may increase only by 3x, the mesoporosity (pores in the range 2-50 nm) remains unchanged, while the strength of the material increases by up to 300... Having addressed the fragility problem, aerogels are now robust materials, and a variety of applications, ranging from thermal/acoustic insulators to catalyst supports, to platform for sensors, and dielectrics are all within reach. Our approach employs molecular science to manipulate nanoscopic matter for achieving useful macroscopic properties, and in our view it resides at the core of what defines nanotechnology. In that spirit, this technology is expandable in three directions. Thus, we have already crosslinked successfully amine-modified silica, and we anticipate that more rich chemistry will be realized by been creative with the nanoparticle surface modifiers. On the other hand, although we do not expect
On NaCl efflorescence formation and growth at the surface of a porous medium
NASA Astrophysics Data System (ADS)
Veran-Tissoires, S.; Marcoux, M.; Prat, M.
2012-04-01
Rocks or building materials are often altered by the presence of dissolved salts. Salt precipitation is one of the main processes damaging the porous matrix. In this context, our study focuses on salt crystallization which results from evaporation at the surface of porous media. These crystallized salt structures are called efflorescence. Efflorescence is an important issue for the conservation of old paintings and frescoes. The challenge is to understand why these structures do not form everywhere at the porous medium surface but at some specific locations and why there exists an exclusion distance around an efflorescence structure where no new efflorescence forms. These behaviours are explained from a visualization experiment, pore-network simulations and a simple efflorescence growth model. A wicking/evaporating experiment is conducted on packings of glass beads (~1mm diameter) contained in a hollow cylinder. The porous sample is open at the bottom where it is in contact with a brine solution. The upper surface is open to external dry air. In this configuration, the sample remains fully saturated and salt precipitation takes place at the sample surface. This setup is set in an enclosure where temperature is kept constant and dry air is maintained, which imposes a nearly uniform evaporation flux over the sample surface. After a few days of evaporation, efflorescence structures appear, grow and remain discrete, i.e. continue to form individual halite structures. Simulations with a 3D pore network model enable us to show that discrete location of efflorescence results from small scale heterogeneities of the beads packing. Locally some menisci are connected to smaller pores which enhance salt transport by advection. The second objective of the study is to understand the mechanism which makes the efflorescence to growth under the form of a set of individual structures. By studying numerically the growth of one efflorescence structure, we observe a global increase of
Studying Cracking and Oil Invasion in Porous Medium During Drying
NASA Astrophysics Data System (ADS)
Jin, Qiu
We study two interesting phenomena occurred during the evaporation of solvent in porous medium: first, the cracking behavior; and second, the expanding mechanism and the collecting methods of the non-evaporative phase. In the first part of this thesis, we visualize the cracking behavior of colloidal suspensions during drying by a confocal microscope. We develop an effective method which can completely eliminate cracking during drying: by adding emulsion droplets into colloidal suspensions, we can systematically decrease the amount of cracking, and eliminate it completely above a critical droplet concentration. We also find another effect that the emulsion droplets can bring: it varies the speed of air invasion and provides a powerful method to adjust drying rate. Besides, we investigate the samples' fundamental mechanical properties with a rheometer and clarify the underlying physical mechanism for the decreasing of crack amounts. With the effective control over cracking and drying rate, our study may find important applications in many drying and cracking related industrial processes. In the second part of the thesis, we conduct a study on the expanding mechanism and collecting methods of the non-evaporative phase in porous medium, which is inspired by a practical pollution problem that occurs when oil spills to the sandy beach. We build a system in a smaller scale to mimic the practical pollution and investigate the distribution change of the polluting phase as the flushing cycle increases. We find an obvious expansion of the polluting phase after several flushing cycles in both hydrophilic and hydrophobic porous media, but with different distributions and expanding behaviors. We explained this difference by analyzing the pressure distribution in the system at the pore level. Finally, we develop two methods to concentrate the polluting phase in some particular regions, which is beneficial to collect and solve the practical pollution problem.
Fabrication of 3D porous SF/β-TCP hybrid scaffolds for bone tissue reconstruction.
Park, Hyun Jung; Min, Kyung Dan; Lee, Min Chae; Kim, Soo Hyeon; Lee, Ok Joo; Ju, Hyung Woo; Moon, Bo Mi; Lee, Jung Min; Park, Ye Ri; Kim, Dong Wook; Jeong, Ju Yeon; Park, Chan Hum
2016-07-01
Bio-ceramic is a biomaterial actively studied in the field of bone tissue engineering. But, only certain ceramic materials can resolve the corrosion problem and possess the biological affinity of conventional metal biomaterials. Therefore, the recent development of composites of hybrid composites and polymers has been widely studied. In this study, we aimed to select the best scaffold of silk fibroin and β-TCP hybrid for bone tissue engineering. We fabricated three groups of scaffold such as SF (silk fibroin scaffold), GS (silk fibroin/small granule size of β-TCP scaffold) and GM (silk fibroin/medium granule size of β-TCP scaffold), and we compared the characteristics of each group. During characterization of the scaffold, we used scanning electron microscopy (SEM) and a Fourier transform infrared spectroscopy (FTIR) for structural analysis. We compared the physiological properties of the scaffold regarding the swelling ratio, water uptake and porosity. To evaluate the mechanical properties, we examined the compressive strength of the scaffold. During in vitro testing, we evaluated cell attachment and cell proliferation (CCK-8). Finally, we confirmed in vivo new bone regeneration from the implanted scaffolds using histological staining and micro-CT. From these evaluations, the fabricated scaffold demonstrated high porosity with good inter-pore connectivity, showed good biocompatibility and high compressive strength and modulus. In particular, the present study indicates that the GM scaffold using β-TCP accelerates new bone regeneration of implanted scaffolds. Accordingly, our scaffold is expected to act a useful application in the field of bone tissue engineering. © 2016 Wiley Periodicals, Inc. J Biomed Mater Res Part A: 104A: 1779-1787, 2016. PMID:26999521
Duan, Shasha; Yang, Ke; Wang, Zhihui; Chen, Mengting; Zhang, Ling; Zhang, Hongbo; Li, Chunzhong
2016-01-27
The combination of carbon nanomaterial with three-dimensional (3D) porous polymer substrates has been demonstrated to be an effective approach to manufacture high-performance stretchable conductive materials (SCMs). However, it remains a challenge to fabricate 3D-structured SCMs with outstanding electrical conductivity capability under large strain in a facile way. In this work, the 3D printing technique was employed to prepare 3D porous poly(dimethylsiloxane) (O-PDMS) which was then integrated with carbon nanotubes and graphene conductive network and resulted in highly stretchable conductors (OPCG). Two types of OPCG were prepared, and it has been demonstrated that the OPCG with split-level structure exhibited both higher electrical conductivity and superior retention capability under deformations, which was illustrated by using a finite element method. The specially designed split-level OPCG is capable of sustaining both large strain and repeated deformations showing huge potential in the application of next-generation stretchable electronics.
3D Spatial Distribution of the Intergalactic Medium: The ESO Blues?
NASA Astrophysics Data System (ADS)
Rollinde, Emmanuel; Petitjean, Patrick; Pichon, Christophe; Colombi, Stéphane; Aracil, Bastien
The numerous absorption lines seen in the spectra of distant quasars (the so-called Lyman-α forest) reveal the intergalactic medium (IGM) up to redshifts larger than 5. It is believed that the space distribution of the gas traces the potential wells of the dark matter. Indeed, recent numerical N-body simulations have been successful at reproducing the observed characteristics of the Lyman-α forest (e.g. [1][12][5]). The IGM is therefore seen as a smooth pervasive medium which can be used to study the spatial distribution of the mass on scales larger than the Jeans' length. This idea is reinforced by observations of multiple lines of sight. It is observed that the Lyman-α forest is fairly homogeneous on scale smaller than 100 kpc (e.g. [11]) and highly correlated on scale up to one megaparsec (e.g. [13][3]). The number of suitable multiple lines of sight is small however and the sample need to be significantly enlarged before any firm conclusion can be drawn (see Section 3.3).
Sekar, Pandiaraj; Anothumakkool, Bihag; Kurungot, Sreekumar
2015-04-15
Here, we report synthesis of a 3-dimensional (3D) porous polyaniline (PANI) anchored on pillared graphene (G-PANI-PA) as an efficient charge storage material for supercapacitor applications. Benzoic acid (BA) anchored graphene, having spatially separated graphene layers (G-Bz-COOH), was used as a structure controlling support whereas 3D PANI growth has been achieved by a simple chemical oxidation of aniline in the presence of phytic acid (PA). The BA groups on G-Bz-COOH play a critical role in preventing the restacking of graphene to achieve a high surface area of 472 m(2)/g compared to reduced graphene oxide (RGO, 290 m(2)/g). The carboxylic acid (-COOH) group controls the rate of polymerization to achieve a compact polymer structure with micropores whereas the chelating nature of PA plays a crucial role to achieve the 3D growth pattern of PANI. This type of controlled interplay helps G-PANI-PA to achieve a high conductivity of 3.74 S/cm all the while maintaining a high surface area of 330 m(2)/g compared to PANI-PA (0.4 S/cm and 60 m(2)/g). G-PANI-PA thus conceives the characteristics required for facile charge mobility during fast charge-discharge cycles, which results in a high specific capacitance of 652 F/g for the composite. Owing to the high surface area along with high conductivity, G-PANI-PA displays a stable specific capacitance of 547 F/g even with a high mass loading of 3 mg/cm(2), an enhanced areal capacitance of 1.52 F/cm(2), and a volumetric capacitance of 122 F/cm(3). The reduced charge-transfer resistance (RCT) of 0.67 Ω displayed by G-PANI-PA compared to pure PANI (0.79 Ω) stands out as valid evidence of the improved charge mobility achieved by the system by growing the 3D PANI layer along the spatially separated layers of the graphene sheets. The low RCT helps the system to display capacitance retention as high as 65% even under a high current dragging condition of 10 A/g. High charge/discharge rates and good cycling stability are the other
Sekar, Pandiaraj; Anothumakkool, Bihag; Kurungot, Sreekumar
2015-04-15
Here, we report synthesis of a 3-dimensional (3D) porous polyaniline (PANI) anchored on pillared graphene (G-PANI-PA) as an efficient charge storage material for supercapacitor applications. Benzoic acid (BA) anchored graphene, having spatially separated graphene layers (G-Bz-COOH), was used as a structure controlling support whereas 3D PANI growth has been achieved by a simple chemical oxidation of aniline in the presence of phytic acid (PA). The BA groups on G-Bz-COOH play a critical role in preventing the restacking of graphene to achieve a high surface area of 472 m(2)/g compared to reduced graphene oxide (RGO, 290 m(2)/g). The carboxylic acid (-COOH) group controls the rate of polymerization to achieve a compact polymer structure with micropores whereas the chelating nature of PA plays a crucial role to achieve the 3D growth pattern of PANI. This type of controlled interplay helps G-PANI-PA to achieve a high conductivity of 3.74 S/cm all the while maintaining a high surface area of 330 m(2)/g compared to PANI-PA (0.4 S/cm and 60 m(2)/g). G-PANI-PA thus conceives the characteristics required for facile charge mobility during fast charge-discharge cycles, which results in a high specific capacitance of 652 F/g for the composite. Owing to the high surface area along with high conductivity, G-PANI-PA displays a stable specific capacitance of 547 F/g even with a high mass loading of 3 mg/cm(2), an enhanced areal capacitance of 1.52 F/cm(2), and a volumetric capacitance of 122 F/cm(3). The reduced charge-transfer resistance (RCT) of 0.67 Ω displayed by G-PANI-PA compared to pure PANI (0.79 Ω) stands out as valid evidence of the improved charge mobility achieved by the system by growing the 3D PANI layer along the spatially separated layers of the graphene sheets. The low RCT helps the system to display capacitance retention as high as 65% even under a high current dragging condition of 10 A/g. High charge/discharge rates and good cycling stability are the other
Wang, Wenzhong; Xu, Jie
2015-01-14
A two-step strategy has been developed to fabricate 3D flower-like Co3O4 hierarchical microstructures assembled by hexagonal porous nanoplates. The synthetic procedure was described as (1) 3D flower-like α-Co(OH)2 microstructures were prepared by a facile surfactant-free low-temperature hydrothermal process; (2) 3D flower-like Co3O4 hierarchical microstructures were fabricated by annealing the obtained 3D flower-like α-Co(OH)2 microstructures. X-ray diffraction and Raman spectrum analyses demonstrate that the hierarchical microstructures formed from 3D flower-like α-Co(OH)2 microstructures are composed of pure cubic phase Co3O4. Scanning electronic microscopy demonstrates that the as-prepared Co3O4 microstructures exhibit 3D flower-like hierarchical structures assembled by hexagonal porous nanoplates. Photoluminescence demonstrates that these novel 3D flower-like Co3O4 hierarchical microstructures display a broad strong emission in the visible range of 650 to 800 nm with a peak at around 710 nm (1.75 eV), which is very close to the indirect optical band gap of 1.60 eV for Co3O4 thin film. The result indicates that the photoluminescence emission likely originates from the indirect optical band gap emission. The broad photoluminescence emission may be resulted from a wide size distribution of porous nanoplates in 3D hierarchical microstructures. These 3D flower-like Co3O4 hierarchical microstructures with unique optical properties may find new potential applications in visible light emitting materials.
Wen Lili; Wang Dong'e; Wang Chenggang; Wang Feng; Li Dongfeng Deng Kejian
2009-03-15
A new metal-organic framework, [Zn{sub 5}(trencba){sub 2}(OH){sub 2}Cl{sub 2}.4H{sub 2}O] (1) [H{sub 3}trencba=N,N,N',N',N'',N''-tris[(4-carboxylate-2-yl)methyl]-tris (2-aminoethyl)amine], constructed from a flexible tripodal ligand based on C{sub 3} symmetric tris(2-aminoethyl)amine, has been synthesized hydrothermally and characterized by elemental analysis, IR, TG, XRD and single-crystal X-ray diffraction analysis. Compound 1 contains an unprecedented linear penta-nuclear zinc cluster fragment. Each ligand links four penta-nuclear fragments, and every fragment links eight ligands to generate a three-dimensional non-interpenetrated porous framework. The uncoordinated water molecules were observed trapped in the void pores. Compound 1 represents the first example of (6,8)-connected 3D bi-nodal framework based on a single kind of organic ligand. The photoluminescence measurements showed that complex 1 exhibits relatively stronger blue emissions at room temperature than that of the ligand. - Graphical abstract: The MOF [Zn{sub 5}(trencba){sub 2}(OH){sub 2}Cl{sub 2}.4H{sub 2}O] (H{sub 3}trencba=N,N,N',N',N',N'-tris[(4-carboxylate-2-yl)methyl]-tris (2-aminoethyl)amine) reveals a (6,8)-connected bi-nodal three-dimensional porous framework with unprecedented penta-nuclear fragment, which appears to be a good candidate of hybrid inorganic-organic photoactive materials.
Axisymmetric flows from fluid injection into a confined porous medium
NASA Astrophysics Data System (ADS)
Guo, Bo; Zheng, Zhong; Celia, Michael A.; Stone, Howard A.
2016-02-01
We study the axisymmetric flows generated from fluid injection into a horizontal confined porous medium that is originally saturated with another fluid of different density and viscosity. Neglecting the effects of surface tension and fluid mixing, we use the lubrication approximation to obtain a nonlinear advection-diffusion equation that describes the time evolution of the sharp fluid-fluid interface. The flow behaviors are controlled by two dimensionless groups: M, the viscosity ratio of displaced fluid relative to injected fluid, and Γ, which measures the relative importance of buoyancy and fluid injection. For this axisymmetric geometry, the similarity solution involving R2/T (where R is the dimensionless radial coordinate and T is the dimensionless time) is an exact solution to the nonlinear governing equation for all times. Four analytical expressions are identified as asymptotic approximations (two of which are new solutions): (i) injection-driven flow with the injected fluid being more viscous than the displaced fluid (Γ ≪ 1 and M < 1) where we identify a self-similar solution that indicates a parabolic interface shape; (ii) injection-driven flow with injected and displaced fluids of equal viscosity (Γ ≪ 1 and M = 1), where we find a self-similar solution that predicts a distinct parabolic interface shape; (iii) injection-driven flow with a less viscous injected fluid (Γ ≪ 1 and M > 1) for which there is a rarefaction wave solution, assuming that the Saffman-Taylor instability does not occur at the reservoir scale; and (iv) buoyancy-driven flow (Γ ≫ 1) for which there is a well-known self-similar solution corresponding to gravity currents in an unconfined porous medium [S. Lyle et al. "Axisymmetric gravity currents in a porous medium," J. Fluid Mech. 543, 293-302 (2005)]. The various axisymmetric flows are summarized in a Γ-M regime diagram with five distinct dynamic behaviors including the four asymptotic regimes and an intermediate regime
NASA Astrophysics Data System (ADS)
Moortgat, Joachim; Amooie, Mohammad Amin; Soltanian, Mohamad Reza
2016-10-01
We present a new implicit higher-order finite element (FE) approach to efficiently model compressible multicomponent fluid flow on unstructured grids and in fractured porous subsurface formations. The scheme is sequential implicit: pressures and fluxes are updated with an implicit Mixed Hybrid Finite Element (MHFE) method, and the transport of each species is approximated with an implicit second-order Discontinuous Galerkin (DG) FE method. Discrete fractures are incorporated with a cross-flow equilibrium approach. This is the first investigation of all-implicit higher-order MHFE-DG for unstructured triangular, quadrilateral (2D), and hexahedral (3D) grids and discrete fractures. A lowest-order implicit finite volume (FV) transport update is also developed for the same grid types. The implicit methods are compared to an Implicit-Pressure-Explicit-Composition (IMPEC) scheme. For fractured domains, the unconditionally stable implicit transport update is shown to increase computational efficiency by orders of magnitude as compared to IMPEC, which has a time-step constraint proportional to the pore volume of discrete fracture grid cells. However, when lowest-order Euler time-discretizations are used, numerical errors increase linearly with the larger implicit time-steps, resulting in high numerical dispersion. Second-order Crank-Nicolson implicit MHFE-DG and MHFE-FV are therefore presented as well. Convergence analyses show twice the convergence rate for the DG methods as compared to FV, resulting in two to three orders of magnitude higher computational efficiency. Numerical experiments demonstrate the efficiency and robustness in modeling compressible multicomponent flow on irregular and fractured 2D and 3D grids, even in the presence of fingering instabilities.
Fredrich, J.T.
1999-02-10
We present advances in the application of laser scanning confocal microscopy (LSCM) to image, reconstruct, and characterize statistically the microgeometry of porous geologic and engineering materials. We discuss technical and practical aspects of this imaging technique, including both its advantages and limitations. Confocal imaging can be used to optically section a material, with sub-micron resolution possible in the lateral and axial planes. The resultant volumetric image data, consisting of fluorescence intensities for typically {approximately}50 million voxels in XYZ space, can be used to reconstruct the three-dimensional structure of the two-phase medium. We present several examples of this application, including studying pore geometry in sandstone, characterizing brittle failure processes in low-porosity rock deformed under triaxial loading conditions in the laboratory, and analyzing the microstructure of porous ceramic insulations. We then describe approaches to extract statistical microgeometric descriptions from volumetric image data, and present results derived from confocal volumetric data sets. Finally, we develop the use of confocal image data to automatically generate a three-dimensional mesh for numerical pore-scale flow simulations.
Laboratory Investigations of Steam Flow in a Porous Medium
NASA Astrophysics Data System (ADS)
Herkelrath, W. N.; Moench, A. F.; O'Neal, C. F., II
1983-08-01
Experiments were carried out in the laboratory to test a theory of transient flow of pure steam in a uniform porous medium. This theory is used in modeling pressure transient behavior in vapor dominated geothermal systems. Transient, superheated steam flow experiments were run by bringing a cylinder of porous material to a uniform initial pressure and then making a step increase in pressure at one end of the sample while monitoring the pressure transient breakthrough at the other end. It was found in experiments run at 100°, 125°, and 146°C that the time required for steam pressure transients to propagate through an unconsolidated material containing sand, silt, and clay was 10-25 times longer than predicted by conventional superheated steam flow theory. It is hypothesized that the delay in the steam pressure transient was caused by adsorption of steam in the porous sample. In order to account for steam adsorption, a sink term was included in the conservation of mass equation. In addition, energy transfer in the system has to be considered because latent heat is released when steam adsorption occurs, increasing the sample temperature by as much as 10°C. Finally, it was recognized that the steam pressure was a function of both the temperature and the amount of adsorption in the sample. This function was assumed to be an equilibrium adsorption isotherm, which was determined by experiment. By solving the modified mass and energy equations numerically, subject to the empirical adsorption isotherm relationship, excellent theoretical simulation of the experiments was achieved.
Large-scale 3D mapping of the intergalactic medium using the Lyman α forest
NASA Astrophysics Data System (ADS)
Ozbek, Melih; Croft, Rupert A. C.; Khandai, Nishikanta
2016-03-01
Maps of the large-scale structure of the Universe at redshifts 2-4 can be made with the Lyman α forest which are complementary to low-redshift galaxy surveys. We apply the Wiener interpolation method of Caucci et al. to construct three-dimensional maps from sets of Lyman α forest spectra taken from cosmological hydrodynamic simulations. We mimic some current and future quasar redshift surveys [Baryon Oscillation Spectroscopic Survey (BOSS), extended BOSS (eBOSS) and Mid-Scale Dark Energy Spectroscopic Instrument (MS-DESI)] by choosing similar sightline densities. We use these appropriate subsets of the Lyman α absorption sightlines to reconstruct the full three-dimensional Lyman α flux field and perform comparisons between the true and the reconstructed fields. We study global statistical properties of the intergalactic medium (IGM) maps with autocorrelation and cross-correlation analysis, slice plots, local peaks and point-by-point scatter. We find that both the density field and the statistical properties of the IGM are recovered well enough that the resulting IGM maps can be meaningfully considered to represent large-scale maps of the Universe in agreement with Caucci et al., on larger scales and for sparser sightlines than had been tested previously. Quantitatively, for sightline parameters comparable to current and near future surveys the correlation coefficient between true and reconstructed fields is r > 0.9 on scales >30 h-1 Mpc. The properties of the maps are relatively insensitive to the precise form of the covariance matrix used. The final BOSS quasar Lyman α forest sample will allow maps to be made with a resolution of ˜30 h-1 Mpc over a volume of ˜15 h-3 Gpc3 between redshifts 1.9 and 2.3.
Thermal Dispersion Within a Porous Medium Near a Solid Wall
NASA Technical Reports Server (NTRS)
Simon, T.; McFadden, G.; Ibrahim, M.
2006-01-01
The regenerator is a key component to Stirling cycle machine efficiency. Typical regenerators are of sintered fine wires or layers of fine-wire screens. Such porous materials are contained within solid-waH casings. Thermal energy exchange between the regenerator and the casing is important to cycle performance for the matrix and casing would not have the same axial temperature profile in an actual machine. Exchange from one to the other may allow shunting of thermal energy, reducing cycle efficiency. In this paper, temperature profiles within the near-wall region of the matrix are measured and thermal energy transport, termed thermal dispersion, is inferred. The data show how the wall affects thermal transport. Transport normal to the mean flow direction is by conduction within the solid and fluid and by advective transport within the matrix. In the near-wall region, both may be interrupted from their normal in-core pattern. Solid conduction paths are broken and scales of advective transport are damped. An equation is presented which describes this change for a wire screen mesh. The near-wall layer typically acts as an insulating layer. This should be considered in design or analysis. Effective thermal conductivity within the core is uniform. In-core transverse thermal effective conductivity values are compared to direct and indirect measurements reported elsewhere and to 3D numerical simulation results, computed previously and reported elsewhere. The 3-D CFD model is composed of six cylinders in cross flow, staggered in arrangement to match the dimensions and porosity of the matrix used in the experiments. The commercial code FLUENT is used to obtain the flow and thermal fields. The thermal dispersion and effective thermal conductivities for the matrix are computed from the results.
Two-phase flow in a chemically active porous medium
Darmon, Alexandre Dauchot, Olivier; Benzaquen, Michael; Salez, Thomas
2014-12-28
We study the problem of the transformation of a given reactant species into an immiscible product species, as they flow through a chemically active porous medium. We derive the equation governing the evolution of the volume fraction of the species, in a one-dimensional macroscopic description, identify the relevant dimensionless numbers, and provide simple models for capillary pressure and relative permeabilities, which are quantities of crucial importance when tackling multiphase flows in porous media. We set the domain of validity of our models and discuss the importance of viscous coupling terms in the extended Darcy’s law. We investigate numerically the steady regime and demonstrate that the spatial transformation rate of the species along the reactor is non-monotonous, as testified by the existence of an inflection point in the volume fraction profiles. We obtain the scaling of the location of this inflection point with the dimensionless lengths of the problem. Eventually, we provide key elements for optimization of the reactor.
Tear film dynamics: modeling the glycocalyx as a porous medium
NASA Astrophysics Data System (ADS)
Siddique, Javed; Mastroberardinob, , Antonio; Braun, Richard; Anderson, Daniel
2015-11-01
The human tear film is a complex fluid structure composed of multiple layers: an aqueous layer that comprises most of the film and an outermost thinner lipid layer coat a forest of large transmembrane mucins at the epithelial surface. The glycocalyx helps provide stability to the ocular surface by assisting the tear film to wet it. It is also permeable to water, but less so to ions. We formulate a thin film model based on lubrication theory in order to understand the dynamics between the aqueous layer and the glycocalyx, which we treat as a rigid porous medium. We present numerical solutions for the evolution of the tear film and discuss the roles played by the key parameters of the system. This work was supported by the Simons Foundation Grant No. 281839.
Properties of equilibrium carbon dioxide hydrate in porous medium
NASA Astrophysics Data System (ADS)
Voronov, V. P.; Gorodetskii, E. E.; Podnek, V. E.; Grigoriev, B. A.
2016-09-01
Specific heat capacity, dissociation heat and hydration number of carbon dioxide hydrate in porous medium are determined by adiabatic calorimetry method. The measurements were carried out in the temperature range 250-290 K and in pressure range 1-5 MPa. The measured specific heat of the hydrate is approximately 2.7 J/(g K), which is significantly larger than the specific heat of methane hydrate. In particular, at heating, larger value of the specific heat of carbon dioxide hydrate is a result of gas emission from the hydrate. The hydration number at the hydrate-gas coexistence changes from 6.2 to 6.9. The dissociation heat of carbon dioxide hydrate varies from the 55 kJ/mol near the upper quadruple point to the 57 kJ/mol near the lower quadruple point.
Qian, Xin; Hang, Tao; Shanmugam, Sangaraju; Li, Ming
2015-07-29
Micro-/nanoscale noble metal (Ag, Au, and Pt) particle-decorated 3D porous nickel electrodes for hydrogen evolution reaction (HER) in alkaline electrolyte are fabricated via galvanostatic electrodeposition technique. The developed electrodes are characterized by field emission scanning electron microscopy and electrochemical measurements including Tafel polarization curves, cyclic voltammetry, and electrochemical impedance spectroscopy. It is clearly shown that the enlarged real surface area caused by 3D highly porous dendritic structure has greatly reinforced the electrocatalytic activity toward HER. Comparative analysis of electrodeposited Ag, Au, and Pt particle-decorated porous nickel electrodes for HER indicates that both intrinsic property and size of the noble metal particles can lead to distinct catalytic activities. Both nanoscale Au and Pt particles have further reinforcement effect toward HER, whereas microscale Ag particles exhibit the reverse effect. As an effective 3D hydrogen evolution cathode, the nanoscale Pt-particle-decorated 3D porous nickel electrode demonstrates the highest catalytic activity with an extremely low overpotential of -0.045 V for hydrogen production, a considerable exchange current density of 9.47 mA cm(-2) at 25 °C, and high durability in long-term electrolysis, all of which are attributed to the intrinsic catalytic property and the extremely small size of Pt particles.
Xin X.; Zhu Y.; Zhou, X.; Wang, F.; Yao, X.; Xu, X.; Liu, Z.
2012-04-28
A 3D porous architecture of Si/graphene nanocomposite has been rationally designed and constructed through a series of controlled chemical processes. In contrast to random mixture of Si nanoparticles and graphene nanosheets, the porous nanoarchitectured composite has superior electrochemical stability because the Si nanoparticles are firmly riveted on the graphene nanosheets through a thin SiO{sub x} layer. The 3D graphene network enhances electrical conductivity, and improves rate performance, demonstrating a superior rate capability over the 2D nanostructure. This 3D porous architecture can deliver a reversible capacity of {approx}900 mA h g{sup -1} with very little fading when the charge rates change from 100 mA g{sup -1} to 1 A g{sup -1}. Furthermore, the 3D nanoarchitechture of Si/graphene can be cycled at extremely high Li{sup +} extraction rates, such as 5 A g{sup -1} and 10 A g{sup -1}, for over than 100 times. Both the highly conductive graphene network and porous architecture are considered to contribute to the remarkable rate capability and cycling stability, thereby pointing to a new synthesis route to improving the electrochemical performances of the Si-based anode materials for advanced Li-ion batteries.
Fan, Qi; Lei, Lixu; Sun, Yueming
2014-07-01
A facile and efficient synthesis was developed to fabricate a 3D-porous LiNbO3 nanocomposite by microwave-induced auto-combustion. Such a material shows a high reversible capacity, excellent rate performance and stable cycle performance indicating its great potential as a promising anode material for Li-ion batteries.
Yan, D; Cheng, S; Zhuo, R F; Chen, J T; Feng, J J; Feng, H T; Li, H J; Wu, Z G; Wang, J; Yan, P X
2009-03-11
Hydrohausmannite nanoparticles (approximately 10 nm) were prepared by the hydrothermal method at 100 degrees C for 72 h. Subsequent annealing was done in air at 400 degrees C and 800 degrees C for 10 h, Mn(3)O(4) nanoparticles (approximately 25 nm) and 3D Mn(2)O(3) porous networks were obtained, respectively. The products were characterized by XRD, TEM, SAED and FESEM. Time-dependent experiments were carried out to exhibit the formation process of the Mn(2)O(3) networks. Their microwave absorption properties were investigated by mixing the product and paraffin wax with 50 vol%. The Mn(3)O(4) nanoparticles possess excellent microwave absorbing properties with the minimum reflection loss of -27.1 dB at 3.1 GHz. In contrast, the Mn(2)O(3) networks show the weakest absorption of all samples. The absorption becomes weaker with the annealing time increasing at 800 degrees C. The attenuation of microwave can be attributed to dielectric loss and their absorption mechanism was discussed in detail. PMID:19417534
Gagg, Graham; Ghassemieh, Elaheh; Wiria, Florencia Edith
2013-10-01
Porous titanium samples were manufactured using the 3D printing and sintering method in order to determine the effects of final sintering temperature on morphology and mechanical properties. Cylindrical samples were printed and split into groups according to a final sintering temperature (FST). Irregular geometry samples were also printed and split into groups according to their FST. The cylindrical samples were used to determine part shrinkage, in compressive tests to provide stress-strain data, in microCT scans to provide internal morphology data and for optical microscopy to determine surface morphology. All of the samples were used in microhardness testing to establish the hardness. Below 1100 °C FST, shrinkage was in the region of 20% but increased to approximately 30% by a FST of 1300 °C. Porosity varied from a maximum of approximately 65% at the surface to the region of 30% internally. Between 97 and 99% of the internal porosity is interconnected. Average pore size varied between 24 μm at the surface and 19 μm internally. Sample hardness increased to in excess of 300 HV0.05 with increasing FST while samples with an FST of below 1250 °C produced an elastic-brittle stress/strain curve and samples above this displayed elastic-plastic behaviour. Yield strength increased significantly through the range of sintering temperatures while the Young's modulus remained fairly consistent. PMID:23910288
Kang, Qin-Shu; Shen, Xiao-Fan; Hu, Na-Na; Hu, Meng-Jia; Liao, Hui; Wang, Han-Zhong; He, Zhi-Ke; Huang, Wei-Hua
2013-05-01
In this work, we demonstrate the immunocapture and on-line fluorescence immunoassay of protein and virus based on porous polymer monoliths (PPM) in microfluidic devices. Poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate) [poly(GMA-co-EGDMA)] monoliths were successfully synthesized in the polydimethylsiloxane (PDMS) microfluidic channels by in situ UV-initiated free radical polymerization. After surface modification, PPM provides a high-surface area and specific affinity 3D substrate for immunoassays. Combining with well controlled microfluidic devices, the direct immunoassay of IgG and sandwich immunoassay of inactivated H1N1 influenza virus using 5 μL sample has been accomplished, with detection limits of 4 ng mL(-1) and less than 10 pg mL(-1), respectively. The enhanced detection sensitivity is due to both high surface area of PPM and flow-through design. The detection time was obviously decreased mainly due to the shortened diffusion distance and improved convective mass transfer inside the monolith, which accelerates the reaction kinetics between antigen and antibody. This work provides a novel microfluidic immunoassay platform with high efficiency thereby enabling fast and sensitive immunoassay.
Du, Shangfeng; Liu, Haidi; Chen, Yunfa
2009-02-25
A facile procedure for large-scale preparation of porous ZnO 1D nanomaterials with good electrical conductivity has been demonstrated for the first time. Porous ultrathin Ga-doped ZnO nanoneedles can be prepared by calcining the precursor of ultrathin Ga-doped basic zinc carbonate (BZC) nanoneedles obtained from BZC 3D superstructures, which are synthesized by a simple chemical co-precipitation method at room temperature, without using any catalyst, template or surfactant. There is evidence that the growth mechanisms of the BZC 3D superstructures and nanoneedles are correlated with the concentrations of ammonium ions and ethanol in the synthesis solution. The as-prepared porous Ga-doped ZnO nanoneedles have a thickness of only a couple of nanometers, consisting of many fine nanoparticles in a few nanometers. Electrical conductivity measurements indicate that porous ultrathin ZnO nanoneedles have a volume resistivity similar to that of the spherical Ga-doped ZnO nanoparticles. The porous nanostructures and good electrical conductivity make the porous ultrathin ZnO 1D nanoneedles promising candidates for applications in electrochemical fields.
Nonlinear self-adjointness and conservation laws for a porous medium equation with absorption
NASA Astrophysics Data System (ADS)
Gandarias, M. L.; Bruzón, M. S.
2013-10-01
We give conditions for a general porous medium equation to be nonlinear self-adjoint. By using the property of nonlinear self-adjointness we construct some conservation laws associated with classical and nonclassical generators of a porous medium equation with absorption.
Holford, D.J.
1994-01-01
This document is a user`s manual for the Rn3D finite element code. Rn3D was developed to simulate gas flow and radon transport in variably saturated, nonisothermal porous media. The Rn3D model is applicable to a wide range of problems involving radon transport in soil because it can simulate either steady-state or transient flow and transport in one-, two- or three-dimensions (including radially symmetric two-dimensional problems). The porous materials may be heterogeneous and anisotropic. This manual describes all pertinent mathematics related to the governing, boundary, and constitutive equations of the model, as well as the development of the finite element equations used in the code. Instructions are given for constructing Rn3D input files and executing the code, as well as a description of all output files generated by the code. Five verification problems are given that test various aspects of code operation, complete with example input files, FORTRAN programs for the respective analytical solutions, and plots of model results. An example simulation is presented to illustrate the type of problem Rn3D is designed to solve. Finally, instructions are given on how to convert Rn3D to simulate systems other than radon, air, and water.
NASA Astrophysics Data System (ADS)
Rohan, Eduard; Naili, Salah; Nguyen, Vu-Hieu
2016-08-01
We study wave propagation in an elastic porous medium saturated with a compressible Newtonian fluid. The porous network is interconnected whereby the pores are characterized by two very different characteristic sizes. At the mesoscopic scale, the medium is described using the Biot model, characterized by a high contrast in the hydraulic permeability and anisotropic elasticity, whereas the contrast in the Biot coupling coefficient is only moderate. Fluid motion is governed by the Darcy flow model extended by inertia terms and by the mass conservation equation. The homogenization method based on the asymptotic analysis is used to obtain a macroscopic model. To respect the high contrast in the material properties, they are scaled by the small parameter, which is involved in the asymptotic analysis and characterized by the size of the heterogeneities. Using the estimates of wavelengths in the double-porosity networks, it is shown that the macroscopic descriptions depend on the contrast in the static permeability associated with pores and micropores and on the frequency. Moreover, the microflow in the double porosity is responsible for fading memory effects via the macroscopic poroviscoelastic constitutive law. xml:lang="fr"
NASA Astrophysics Data System (ADS)
Luquet, David; Marchiano, Régis; Coulouvrat, François
2015-10-01
Many situations involve the propagation of acoustical shock waves through flows. Natural sources such as lightning, volcano explosions, or meteoroid atmospheric entries, emit loud, low frequency, and impulsive sound that is influenced by atmospheric wind and turbulence. The sonic boom produced by a supersonic aircraft and explosion noises are examples of intense anthropogenic sources in the atmosphere. The Buzz-Saw-Noise produced by turbo-engine fan blades rotating at supersonic speed also propagates in a fast flow within the engine nacelle. Simulating these situations is challenging, given the 3D nature of the problem, the long range propagation distances relative to the central wavelength, the strongly nonlinear behavior of shocks associated to a wide-band spectrum, and finally the key role of the flow motion. With this in view, the so-called FLHOWARD (acronym for FLow and Heterogeneous One-Way Approximation for Resolution of Diffraction) method is presented with three-dimensional applications. A scalar nonlinear wave equation is established in the framework of atmospheric applications, assuming weak heterogeneities and a slow wind. It takes into account diffraction, absorption and relaxation properties of the atmosphere, quadratic nonlinearities including weak shock waves, heterogeneities of the medium in sound speed and density, and presence of a flow (assuming a mean stratified wind and 3D turbulent ? flow fluctuations of smaller amplitude). This equation is solved in the framework of the one-way method. A split-step technique allows the splitting of the non-linear wave equation into simpler equations, each corresponding to a physical effect. Each sub-equation is solved using an analytical method if possible, and finite-differences otherwise. Nonlinear effects are solved in the time domain, and others in the frequency domain. Homogeneous diffraction is handled by means of the angular spectrum method. Ground is assumed perfectly flat and rigid. Due to the 3D
Luquet, David; Marchiano, Régis; Coulouvrat, François
2015-10-28
Many situations involve the propagation of acoustical shock waves through flows. Natural sources such as lightning, volcano explosions, or meteoroid atmospheric entries, emit loud, low frequency, and impulsive sound that is influenced by atmospheric wind and turbulence. The sonic boom produced by a supersonic aircraft and explosion noises are examples of intense anthropogenic sources in the atmosphere. The Buzz-Saw-Noise produced by turbo-engine fan blades rotating at supersonic speed also propagates in a fast flow within the engine nacelle. Simulating these situations is challenging, given the 3D nature of the problem, the long range propagation distances relative to the central wavelength, the strongly nonlinear behavior of shocks associated to a wide-band spectrum, and finally the key role of the flow motion. With this in view, the so-called FLHOWARD (acronym for FLow and Heterogeneous One-Way Approximation for Resolution of Diffraction) method is presented with three-dimensional applications. A scalar nonlinear wave equation is established in the framework of atmospheric applications, assuming weak heterogeneities and a slow wind. It takes into account diffraction, absorption and relaxation properties of the atmosphere, quadratic nonlinearities including weak shock waves, heterogeneities of the medium in sound speed and density, and presence of a flow (assuming a mean stratified wind and 3D turbulent ? flow fluctuations of smaller amplitude). This equation is solved in the framework of the one-way method. A split-step technique allows the splitting of the non-linear wave equation into simpler equations, each corresponding to a physical effect. Each sub-equation is solved using an analytical method if possible, and finite-differences otherwise. Nonlinear effects are solved in the time domain, and others in the frequency domain. Homogeneous diffraction is handled by means of the angular spectrum method. Ground is assumed perfectly flat and rigid. Due to the 3D
Inclusion-based effective medium models for the field-scale permeability of 3D fractured rock masses
NASA Astrophysics Data System (ADS)
Ebigbo, Anozie; Lang, Philipp S.; Paluszny, Adriana; Zimmerman, Robert W.
2016-04-01
Fractures that are more permeable than their host rock can act as preferential, or at least additional, pathways for fluid to flow through the rock. The additional transmissivity contributed by these fractures will be of great relevance in several areas of earth science and engineering, such as radioactive waste disposal in crystalline rock, exploitation of fractured hydrocarbon and geothermal reservoirs, or hydraulic fracturing. In describing or predicting flow through fractured rock, the effective permeability of the rock mass, comprising both the rock matrix and a network of fractures, is a crucial parameter, and will depend on several geometric properties of the fractures/networks, such as lateral extent, aperture, orientation, and fracture density. This study investigates the ability of classical inclusion-based effective medium models (following the work of Sævik et al., Transp. Porous Media, 2013) to predict this permeability. In these models, the fractures are represented as thin, spheroidal inclusions, the interiors of which are treated as porous media having a high (but finite) permeability. The predictions of various effective medium models, such as the symmetric and asymmetric self-consistent schemes, the differential scheme, and Maxwell's method, are tested against the results of explicit numerical simulations of mono- and polydisperse isotropic fracture networks embedded in a permeable rock matrix. Comparisons are also made with the Hashin-Shrikman bounds, Snow's model, and Mourzenko's heuristic model (Mourzenko et al., Phys. Rev. E, 2011). This problem is characterised mathematically by two small parameters, the aspect ratio of the spheroidal fractures, α, and the ratio between matrix and fracture permeability, κ. Two different regimes can be identified, corresponding to α/κ < 1 and α/κ > 1. The lower the value of α/κ, the more significant is flow through the matrix. Due to differing flow patterns, the dependence of effective permeability on
Flow regimes for fluid injection into a confined porous medium
Zheng, Zhong; Guo, Bo; Christov, Ivan C.; Celia, Michael A.; Stone, Howard A.
2015-02-24
We report theoretical and numerical studies of the flow behaviour when a fluid is injected into a confined porous medium saturated with another fluid of different density and viscosity. For a two-dimensional configuration with point source injection, a nonlinear convection–diffusion equation is derived to describe the time evolution of the fluid–fluid interface. In the early time period, the fluid motion is mainly driven by the buoyancy force and the governing equation is reduced to a nonlinear diffusion equation with a well-known self-similar solution. In the late time period, the fluid flow is mainly driven by the injection, and the governing equation is approximated by a nonlinear hyperbolic equation that determines the global spreading rate; a shock solution is obtained when the injected fluid is more viscous than the displaced fluid, whereas a rarefaction wave solution is found when the injected fluid is less viscous. In the late time period, we also obtain analytical solutions including the diffusive term associated with the buoyancy effects (for an injected fluid with a viscosity higher than or equal to that of the displaced fluid), which provide the structure of the moving front. Numerical simulations of the convection–diffusion equation are performed; the various analytical solutions are verified as appropriate asymptotic limits, and the transition processes between the individual limits are demonstrated.
Flow regimes for fluid injection into a confined porous medium
Zheng, Zhong; Guo, Bo; Christov, Ivan C.; Celia, Michael A.; Stone, Howard A.
2015-02-24
We report theoretical and numerical studies of the flow behaviour when a fluid is injected into a confined porous medium saturated with another fluid of different density and viscosity. For a two-dimensional configuration with point source injection, a nonlinear convection–diffusion equation is derived to describe the time evolution of the fluid–fluid interface. In the early time period, the fluid motion is mainly driven by the buoyancy force and the governing equation is reduced to a nonlinear diffusion equation with a well-known self-similar solution. In the late time period, the fluid flow is mainly driven by the injection, and the governingmore » equation is approximated by a nonlinear hyperbolic equation that determines the global spreading rate; a shock solution is obtained when the injected fluid is more viscous than the displaced fluid, whereas a rarefaction wave solution is found when the injected fluid is less viscous. In the late time period, we also obtain analytical solutions including the diffusive term associated with the buoyancy effects (for an injected fluid with a viscosity higher than or equal to that of the displaced fluid), which provide the structure of the moving front. Numerical simulations of the convection–diffusion equation are performed; the various analytical solutions are verified as appropriate asymptotic limits, and the transition processes between the individual limits are demonstrated.« less
Wi, Sungun; Woo, Hyungsub; Lee, Sangheon; Kang, Joonhyeon; Kim, Jaewon; An, Subin; Kim, Chohui; Nam, Seunghoon; Kim, Chunjoong; Park, Byungwoo
2015-01-01
The reduced graphene oxide (RGO)/carbon double-coated 3-D porous ZnO aggregates (RGO/C/ZnO) have been successfully synthesized as anode materials for Li-ion batteries with excellent cyclability and rate capability. The mesoporous ZnO aggregates prepared by a simple solvothermal method are sequentially modified through distinct carbon-based double coating. These novel architectures take unique advantages of mesopores acting as space to accommodate volume expansion during cycling, while the conformal carbon layer on each nanoparticle buffering volume changes, and conductive RGO sheets connect the aggregates to each other. Consequently, the RGO/C/ZnO exhibits superior electrochemical performance, including remarkably prolonged cycle life and excellent rate capability. Such improved performance of RGO/C/ZnO may be attributed to synergistic effects of both the 3-D porous nanostructures and RGO/C double coating.
NASA Astrophysics Data System (ADS)
He, Shuijian; Hou, Haoqing; Chen, Wei
2015-04-01
3D porous and self-supported carbon hybrids are promising electrode materials for supercapacitor application attributed to their prominent properties such as binder-free electrode fabrication process, excellent electric conductivity and high power density etc. We present here a facile chemical vapor deposition method to fabricate a novel 3D flexible carbon hybrid nanostructure by growing a monolayer of nitrogen-doped carbon nanotubes on the skeleton of carbon foam (N-CNTs/CF) with Fe nanoparticle as catalyst. With such 3D porous, flexible and ultralight carbon nanostructure as binder-free electrode material, large surface area is available and fast ionic transport is facilitated. Moreover, the carbon-based network can provide excellent electronic conductivity. The electrochemical studies demonstrate that the supercapacitor constructed from the N-CNTs/CF hybrid exhibit high power density of 69.3 kW kg-1 and good stability with capacitance retention ration above 95% after cycled at 50 A g-1 for 5000 cycles. Therefore, the prepared porous N-CNTs/CF nanostructure is expected to be a type of excellent electrode material for electrical double layer capacitors.
Flaibani, Marina; Elvassore, Nicola
2012-08-01
The mass transport through biocompatible and biodegradable polymeric 3D porous scaffolds may be depleted by non-porous impermeable internal walls. As consequence the concentration of metabolites and growth factors within the scaffold may be heterogeneous leading to different cell fate depending on spatial cell location, and in some cases it may compromise cell survival. In this work, we fabricated polymeric scaffolds with micro- and nano-scale porosity by developing a new technique that couples two conventional scaffold production methods: solvent casting-salt leaching and gas antisolvent precipitation. 10-15 w/w solutions of a hyaluronic benzyl esters (HYAFF11) and poly-(lactic acid) (PLA) were used to fill packed beds of 0.177-0.425 mm NaCl crystals. The polymer precipitation in micro and nano-porous structures between the salt crystals was induced by high-pressure gas, then its flushing extracted the residual solvent. The salt was removed by water-wash. Morphological analysis by scanning electron microscopy showed a uniform porosity (~70%) and a high interconnectivity between porous. The polymeric walls were porous themselves counting for 30% of the total porosity. This wall porosity did not lead to a remarkable change in compressive modulus, deformation, and rupture pressure. Scaffold biocompatibility was tested with murine muscle cell line C2C12 for 4 and 7 days. Viability analysis and histology showed that micro- and nano-porous scaffolds are biocompatible and suitable for 3D cell culture promoting cell adhesion on the polymeric wall and allowing their proliferation in layers. Micro- and nano-scale porosities enhance cell migration and growth in the inner part of the scaffold.
Flaibani, Marina; Elvassore, Nicola
2012-08-01
The mass transport through biocompatible and biodegradable polymeric 3D porous scaffolds may be depleted by non-porous impermeable internal walls. As consequence the concentration of metabolites and growth factors within the scaffold may be heterogeneous leading to different cell fate depending on spatial cell location, and in some cases it may compromise cell survival. In this work, we fabricated polymeric scaffolds with micro- and nano-scale porosity by developing a new technique that couples two conventional scaffold production methods: solvent casting-salt leaching and gas antisolvent precipitation. 10-15 w/w solutions of a hyaluronic benzyl esters (HYAFF11) and poly-(lactic acid) (PLA) were used to fill packed beds of 0.177-0.425 mm NaCl crystals. The polymer precipitation in micro and nano-porous structures between the salt crystals was induced by high-pressure gas, then its flushing extracted the residual solvent. The salt was removed by water-wash. Morphological analysis by scanning electron microscopy showed a uniform porosity (~70%) and a high interconnectivity between porous. The polymeric walls were porous themselves counting for 30% of the total porosity. This wall porosity did not lead to a remarkable change in compressive modulus, deformation, and rupture pressure. Scaffold biocompatibility was tested with murine muscle cell line C2C12 for 4 and 7 days. Viability analysis and histology showed that micro- and nano-porous scaffolds are biocompatible and suitable for 3D cell culture promoting cell adhesion on the polymeric wall and allowing their proliferation in layers. Micro- and nano-scale porosities enhance cell migration and growth in the inner part of the scaffold. PMID:24364970
Dense, Viscous Brine Behavior in Heterogeneous Porous Medium Systems
Wright, D. Johnson; Pedit, J.A.; Gasda, S.E.; Farthing, M.W.; Murphy, L.L.; Knight, S.R.; Brubaker, G.R.
2010-01-01
The behavior of dense, viscous calcium bromide brine solutions used to remediate systems contaminated with dense nonaqueous phase liquids (DNAPLs) is considered in laboratory and field porous medium systems. The density and viscosity of brine solutions are experimentally investigated and functional forms fit over a wide range of mass fractions. A density of 1.7 times, and a corresponding viscosity of 6.3 times, that of water is obtained at a calcium bromide mass fraction of 0.53. A three-dimensional laboratory cell is used to investigate the establishment, persistence, and rate of removal of a stratified dense brine layer in a controlled system. Results from a field-scale experiment performed at the Dover National Test Site are used to investigate the ability to establish and maintain a dense brine layer as a component of a DNAPL recovery strategy, and to recover the brine at sufficiently high mass fractions to support the economical reuse of the brine. The results of both laboratory and field experiments show that a dense brine layer can be established, maintained, and recovered to a significant extent. Regions of unstable density profiles are shown to develop and persist in the field-scale experiment, which we attribute to regions of low hydraulic conductivity. The saturated-unsaturated, variable-density ground-water flow simulation code SUTRA is modified to describe the system of interest, and used to compare simulations to experimental observations and to investigate certain unobserved aspects of these complex systems. The model results show that the standard model formulation is not appropriate for capturing the behavior of sharp density gradients observed during the dense brine experiments. PMID:20444520
Dense, viscous brine behavior in heterogeneous porous medium systems.
Wright, D Johnson; Pedit, J A; Gasda, S E; Farthing, M W; Murphy, L L; Knight, S R; Brubaker, G R; Miller, C T
2010-06-25
The behavior of dense, viscous calcium bromide brine solutions used to remediate systems contaminated with dense nonaqueous phase liquids (DNAPLs) is considered in laboratory and field porous medium systems. The density and viscosity of brine solutions are experimentally investigated and functional forms fit over a wide range of mass fractions. A density of 1.7 times, and a corresponding viscosity of 6.3 times, that of water is obtained at a calcium bromide mass fraction of 0.53. A three-dimensional laboratory cell is used to investigate the establishment, persistence, and rate of removal of a stratified dense brine layer in a controlled system. Results from a field-scale experiment performed at the Dover National Test Site are used to investigate the ability to establish and maintain a dense brine layer as a component of a DNAPL recovery strategy, and to recover the brine at sufficiently high mass fractions to support the economical reuse of the brine. The results of both laboratory and field experiments show that a dense brine layer can be established, maintained, and recovered to a significant extent. Regions of unstable density profiles are shown to develop and persist in the field-scale experiment, which we attribute to regions of low hydraulic conductivity. The saturated-unsaturated, variable-density groundwater flow simulation code SUTRA is modified to describe the system of interest, and used to compare simulations to experimental observations and to investigate certain unobserved aspects of these complex systems. The model results show that the standard model formulation is not appropriate for capturing the behavior of sharp density gradients observed during the dense brine experiments.
A Two-Dimensional Model for the Analysis of Contaminant Transport in a Fractured Porous Medium.
1991-03-05
CHAINT-MC is a two-dimensional finite element model applicable to the transport of a dissolved radionuclide in a fractured porous medium along with radioactive chain decay and subsequent transport of the dissolved daughters.
A New Contraction Family for Porous Medium and Fast Diffusion Equations
NASA Astrophysics Data System (ADS)
Chmaycem, G.; Jazar, M.; Monneau, R.
2016-08-01
In this paper, we present a surprising two-dimensional contraction family for porous medium and fast diffusion equations. This approach provides new a priori estimates on the solutions, even for the standard heat equation.
Effect of thermal stratification on free convection within a porous medium
Nakayama, A.; Koyama, H.
1987-07-01
Free convection over a vertical flat plate embedded in a thermally stratified porous medium is analyzed by exploiting the similarity transformation procedure. Numerical integration results are presented for a series of wall and ambient temperature distributions which permit similarity solutions. The conjugate conduction connection problems of a free convection fin embedded in a thermally stratified porous medium is examined, and it is shown that the influence of the thermal stratification on the heat transfer is quite significant. 8 references.
Study of flow at the interface of a porous medium using particle image velocimetry
NASA Astrophysics Data System (ADS)
Shams Saryazdi, Masoud
This thesis reports the results of an experimental study of the flow at the interface of a fibrous porous medium and a freely flowing fluid. The model for the porous medium was a square array of parallel rods, and arrays with three different solid volume fractions were tested; namely 2.5%, 5.2%, and 10%. The flow adjacent to the porous medium was a shear flow perpendicular to the interface. It was created by generating circular Couette flow in a narrow channel outside the porous medium. Comprehensive velocity measurements were made inside and outside the various porous media using a PIV system that was developed for the experiment. An adverse pressure gradient in the streamwise direction was found to exist between the rods for the media with solid volume fractions of 5.2% and 10%. However no such pressure gradient was found for the 2.5% medium. The fluid motion corresponding to the adverse pressure gradients inside the medium was circulatory. The slip coefficient proposed by Beavers and Joseph was found directly by measuring the local velocity near the boundary of the porous medium. The slip coefficient for the media tested was found to be approximately 3. Comparisons show that Brinkman's equation in its original form (with the same viscosity inside the porous medium mu* and outside mu) did not produce results that matched the measured velocity field. Furthermore, Brinkman's equation did not produce results that matched the experimental velocity fields using any value of the viscosity ratio, mu*/mu. The measurements show that the slip velocity is small, and that Brinkman's equation with mu*/mu ≈ 9 predicts slip velocities quite well. The shear penetration length decreases as the solid volume fraction increases, and for a porous medium with a solid volume fraction of around 10%, the penetration length is smaller than all length scales of the medium. Therefore, for the higher solid volume fractions tested, shear penetration is practically negligible. Penetration of
Yin, Bo; Ma, Pei; Chen, Jun; Wang, Hai; Wu, Gui; Li, Bo; Li, Qiang; Huang, Zhifeng; Qiu, Guixing; Wu, Zhihong
2016-01-01
Porous titanium is a kind of promising material for bone substitution, while its bio-inert property results in demand of modifications to improve the osteointegration capacity. In this study, gelatin (Gel) and nano-hydroxyapatite (nHA) were used to construct 3D micro-scaffolds in the pores of porous titanium in the ratios of Gel:nHA = 1:0, Gel:nHA = 1:1, and Gel:nHA = 1:3, respectively. Cell attachment and proliferation, and gene and protein expression levels of osteogenic markers were evaluated in MC3T3-E1 cells, followed by bone regeneration assessment in a rabbit radius defect model. All hybrid scaffolds with different composition ratio were found to have significant promotional effects in cell adhesion, proliferation and differentiation, in which the group with Gel:nHA = 1:1 showed the best performance in vitro, as well as the most bone regeneration volume in vivo. This 3D micro-scaffolds modification may be an innovative method for porous titanium ornamentation and shows potential application values in clinic. PMID:27092492
Yin, Bo; Ma, Pei; Chen, Jun; Wang, Hai; Wu, Gui; Li, Bo; Li, Qiang; Huang, Zhifeng; Qiu, Guixing; Wu, Zhihong
2016-04-15
Porous titanium is a kind of promising material for bone substitution, while its bio-inert property results in demand of modifications to improve the osteointegration capacity. In this study, gelatin (Gel) and nano-hydroxyapatite (nHA) were used to construct 3D micro-scaffolds in the pores of porous titanium in the ratios of Gel:nHA = 1:0, Gel:nHA = 1:1, and Gel:nHA = 1:3, respectively. Cell attachment and proliferation, and gene and protein expression levels of osteogenic markers were evaluated in MC3T3-E1 cells, followed by bone regeneration assessment in a rabbit radius defect model. All hybrid scaffolds with different composition ratio were found to have significant promotional effects in cell adhesion, proliferation and differentiation, in which the group with Gel:nHA = 1:1 showed the best performance in vitro, as well as the most bone regeneration volume in vivo. This 3D micro-scaffolds modification may be an innovative method for porous titanium ornamentation and shows potential application values in clinic.
Luo, Wen-Bin; Gao, Xuan-Wen; Shi, Dong-Qi; Chou, Shu-Lei; Wang, Jia-Zhao; Liu, Hua-Kun
2016-06-01
Pt-Gd alloy polycrystalline thin film is deposited on 3D nickel foam by pulsed laser deposition method serving as a whole binder/carbon-free air electrode, showing great catalytic activity enhancement as an efficient bifunctional catalyst for the oxygen reduction and evolution reactions in lithium oxygen batteries. The porous structure can facilitate rapid O2 and electrolyte diffusion, as well as forming a continuous conductive network throughout the whole energy conversion process. It shows a favorable cycle performance in the full discharge/charge model, owing to the high catalytic activity of the Pt-Gd alloy composite and 3D porous nickel foam structure. Specially, excellent cycling performance under capacity limited mode is also demonstrated, in which the terminal discharge voltage is higher than 2.5 V and the terminal charge voltage is lower than 3.7 V after 100 cycles at a current density of 0.1 mA cm(-2) . Therefore, this electrocatalyst is a promising bifunctional electrocatalyst for lithium oxygen batteries and this depositing high-efficient electrocatalyst on porous substrate with polycrystalline thin film by pulsed laser deposition is also a promising technique in the future lithium oxygen batteries research.
NASA Astrophysics Data System (ADS)
Peng, Yuncheng; Wang, Yao; Deng, Yuan
2016-08-01
With the ever increasing level of performance of energy conversion micro-devices, such as thin-film solar cells and thermoelectric micro-generators or coolers, their reliability and stability still remain a challenge. The high electrical and mechanical stability of an electrode is two of the critical factors that affect the long-term life of devices. Here we show that these factors can be achieved by constructing a 3D porous network of nanostructures in copper film using facile magnetron sputtering technology without any templates. The constructed 3D porous network of nanostructures in Cu film provides not only the advantages of light weight, prominently high conductivity, and large elastic deformation, but also the ability to absorb stress, preventing crack propagation, which is crucial for electrodes to maintain stable electrical and mechanical properties under working conditions. The nanopores inside the 3D network are capable of unrestrained deformation under applied stress resulting in strong elastic recovery. This work puts forward a feasible solution for manufacturing electrodes with excellent electrical and mechanical properties for micro-energy devices.
Farzadi, Arghavan; Solati-Hashjin, Mehran; Asadi-Eydivand, Mitra; Abu Osman, Noor Azuan
2014-01-01
Powder-based inkjet 3D printing method is one of the most attractive solid free form techniques. It involves a sequential layering process through which 3D porous scaffolds can be directly produced from computer-generated models. 3D printed products' quality are controlled by the optimal build parameters. In this study, Calcium Sulfate based powders were used for porous scaffolds fabrication. The printed scaffolds of 0.8 mm pore size, with different layer thickness and printing orientation, were subjected to the depowdering step. The effects of four layer thicknesses and printing orientations, (parallel to X, Y and Z), on the physical and mechanical properties of printed scaffolds were investigated. It was observed that the compressive strength, toughness and Young's modulus of samples with 0.1125 and 0.125 mm layer thickness were more than others. Furthermore, the results of SEM and μCT analyses showed that samples with 0.1125 mm layer thickness printed in X direction have more dimensional accuracy and significantly close to CAD software based designs with predefined pore size, porosity and pore interconnectivity. PMID:25233468
Farzadi, Arghavan; Solati-Hashjin, Mehran; Asadi-Eydivand, Mitra; Abu Osman, Noor Azuan
2014-01-01
Powder-based inkjet 3D printing method is one of the most attractive solid free form techniques. It involves a sequential layering process through which 3D porous scaffolds can be directly produced from computer-generated models. 3D printed products' quality are controlled by the optimal build parameters. In this study, Calcium Sulfate based powders were used for porous scaffolds fabrication. The printed scaffolds of 0.8 mm pore size, with different layer thickness and printing orientation, were subjected to the depowdering step. The effects of four layer thicknesses and printing orientations, (parallel to X, Y and Z), on the physical and mechanical properties of printed scaffolds were investigated. It was observed that the compressive strength, toughness and Young's modulus of samples with 0.1125 and 0.125 mm layer thickness were more than others. Furthermore, the results of SEM and μCT analyses showed that samples with 0.1125 mm layer thickness printed in X direction have more dimensional accuracy and significantly close to CAD software based designs with predefined pore size, porosity and pore interconnectivity.
Linear stability of a Berman flow in a channel partially filled with a porous medium
NASA Astrophysics Data System (ADS)
Deng, Chuntao; Martinez, D. Mark
2005-02-01
The temporal stability of similarity solutions for an incompressible fluid moving in a channel partially filled with a porous medium is analyzed. A constant wall suction acting on the bottom surface of the porous medium drives the fluid; the upper wall of the channel is impermeable. This work extends the work of King and Cox ["Asymptotic analysis of the steady-state and time-dependent Berman problem," J. Eng. Math. 39, 87 (2001)] to a wider class of similarity solutions where coupled flow, both above and through a porous medium, is considered. In this work, a similarity transform is proposed which satisfies both the Navier-Stokes equation in the clear fluid portion of the domain and the Brinkman extended Darcy law relationship in the porous medium. The boundary conditions between the clear fluid and porous regions are those outlined by Ochoa-Tapia and Whitaker ["Momentum transfer at the boundary between a porous medium and a homogeneous fluid I: theoretical development," Int. J. Heat Mass Transfer 38, 2635 (1995)]. The solutions of the steady flow are approximated analytically, in the limit of small wall suction, and numerically. Multiple steady-state solutions were found. The temporal stability of the solutions indicates turning-point bifurcations and instability only occurred with reverse flows.
Migration of salt bands through a porous medium
NASA Astrophysics Data System (ADS)
Gitelman, E. M.; Dragila, M. I.
2010-12-01
In order to improve agricultural conditions in saline and sodic soils, we must better understand salt precipitation dynamics and the limiting kinetic mechanisms associated with the salinization process. We used laboratory techniques to monitor salt crystal formation in porous media cells under highly controlled conditions to examine the temporal evolution of salt crystallization. We found that salt crusts first precipitate on the surface and then move down through the porous media towards the water source forming bands collinear with equipotential moisture planes. We compare the kinetic data with a salt crystal formation and transport model and conclude that salt band formation and transport occurs via a cycle of vapor transport, osmotic deposition and deliquescence in the moving front, followed by evaporation and recrystallization in the receding front. Vapor density gradients and deliquescence kinetics controls the transport rate of salt bands through porous media.
Lewallen, Eric A; Jones, Dakota L; Dudakovic, Amel; Thaler, Roman; Paradise, Christopher R; Kremers, Hilal M; Abdel, Matthew P; Kakar, Sanjeev; Dietz, Allan B; Cohen, Robert C; Lewallen, David G; van Wijnen, Andre J
2016-05-01
Integration of porous metal prosthetics, which restore form and function of irreversibly damaged joints, into remaining healthy bone is critical for implant success. We investigated the biological properties of adipose-tissue-derived mesenchymal stromal/stem cells (AMSCs) and addressed their potential to alter the in vitro microenvironment of implants. We employed human AMSCs as a practical source for musculoskeletal applications because these cells can be obtained in large quantities, are multipotent, and have trophic paracrine functions. AMSCs were cultured on surgical-grade porous titanium disks as a model for orthopedic implants. We monitored cell/substrate attachment, cell proliferation, multipotency, and differentiation phenotypes of AMSCs upon osteogenic induction. High-resolution scanning electron microscopy and histology revealed that AMSCs adhere to the porous metallic surface. Compared to standard tissue culture plastic, AMSCs grown in the porous titanium microenvironment showed differences in temporal expression for genes involved in cell cycle progression (CCNB2, HIST2H4), extracellular matrix production (COL1A1, COL3A1), mesenchymal lineage identity (ACTA2, CD248, CD44), osteoblastic transcription factors (DLX3, DLX5, ID3), and epigenetic regulators (EZH1, EZH2). We conclude that metal orthopedic implants can be effectively seeded with clinical-grade stem/stromal cells to create a pre-conditioned implant. PMID:26774799
Lewallen, Eric A; Jones, Dakota L; Dudakovic, Amel; Thaler, Roman; Paradise, Christopher R; Kremers, Hilal M; Abdel, Matthew P; Kakar, Sanjeev; Dietz, Allan B; Cohen, Robert C; Lewallen, David G; van Wijnen, Andre J
2016-05-01
Integration of porous metal prosthetics, which restore form and function of irreversibly damaged joints, into remaining healthy bone is critical for implant success. We investigated the biological properties of adipose-tissue-derived mesenchymal stromal/stem cells (AMSCs) and addressed their potential to alter the in vitro microenvironment of implants. We employed human AMSCs as a practical source for musculoskeletal applications because these cells can be obtained in large quantities, are multipotent, and have trophic paracrine functions. AMSCs were cultured on surgical-grade porous titanium disks as a model for orthopedic implants. We monitored cell/substrate attachment, cell proliferation, multipotency, and differentiation phenotypes of AMSCs upon osteogenic induction. High-resolution scanning electron microscopy and histology revealed that AMSCs adhere to the porous metallic surface. Compared to standard tissue culture plastic, AMSCs grown in the porous titanium microenvironment showed differences in temporal expression for genes involved in cell cycle progression (CCNB2, HIST2H4), extracellular matrix production (COL1A1, COL3A1), mesenchymal lineage identity (ACTA2, CD248, CD44), osteoblastic transcription factors (DLX3, DLX5, ID3), and epigenetic regulators (EZH1, EZH2). We conclude that metal orthopedic implants can be effectively seeded with clinical-grade stem/stromal cells to create a pre-conditioned implant.
Thermal analysis of porous medium with ellipsoidal pores using a homogenization method
NASA Astrophysics Data System (ADS)
Asakuma, Yusuke; Yamamoto, Tsuyoshi
2016-10-01
Effective thermal conductivity including radiation is analyzed using a homogenization method. This method can precisely represent the microstructure of a porous medium with ellipsoidal pores. Here, the effects of parameters such as porosity, pore shape, pore distribution, and temperature of the porous medium on the conductivity are estimated to clarify the mechanisms in complex pore structures. For example, heat transfer by radiation does not dominate if the medium has pores of less than 1 mm in size. Moreover, the anisotropy of the effective thermal conductivity is found to depend on temperature, pore shape, pore size, and pore distribution.
Khan, Sami Ullah; Ali, Nasir; Abbas, Zaheer
2015-01-01
An analysis is carried out to study the heat transfer in unsteady two-dimensional boundary layer flow of a magnetohydrodynamics (MHD) second grade fluid over a porous oscillating stretching surface embedded in porous medium. The flow is induced due to infinite elastic sheet which is stretched periodically. With the help of dimensionless variables, the governing flow equations are reduced to a system of non-linear partial differential equations. This system has been solved numerically using the finite difference scheme, in which a coordinate transformation is used to transform the semi-infinite physical space to a bounded computational domain. The influence of the involved parameters on the flow, the temperature distribution, the skin-friction coefficient and the local Nusselt number is shown and discussed in detail. The study reveals that an oscillatory sheet embedded in a fluid-saturated porous medium generates oscillatory motion in the fluid. The amplitude and phase of oscillations depends on the rheology of the fluid as well as on the other parameters coming through imposed boundary conditions, inclusion of body force term and permeability of the porous medium. It is found that amplitude of flow velocity increases with increasing viscoelastic and mass suction/injection parameters. However, it decreases with increasing the strength of the applied magnetic field. Moreover, the temperature of fluid is a decreasing function of viscoelastic parameter, mass suction/injection parameter and Prandtl number. PMID:26657931
Khan, Sami Ullah; Ali, Nasir; Abbas, Zaheer
2015-01-01
An analysis is carried out to study the heat transfer in unsteady two-dimensional boundary layer flow of a magnetohydrodynamics (MHD) second grade fluid over a porous oscillating stretching surface embedded in porous medium. The flow is induced due to infinite elastic sheet which is stretched periodically. With the help of dimensionless variables, the governing flow equations are reduced to a system of non-linear partial differential equations. This system has been solved numerically using the finite difference scheme, in which a coordinate transformation is used to transform the semi-infinite physical space to a bounded computational domain. The influence of the involved parameters on the flow, the temperature distribution, the skin-friction coefficient and the local Nusselt number is shown and discussed in detail. The study reveals that an oscillatory sheet embedded in a fluid-saturated porous medium generates oscillatory motion in the fluid. The amplitude and phase of oscillations depends on the rheology of the fluid as well as on the other parameters coming through imposed boundary conditions, inclusion of body force term and permeability of the porous medium. It is found that amplitude of flow velocity increases with increasing viscoelastic and mass suction/injection parameters. However, it decreases with increasing the strength of the applied magnetic field. Moreover, the temperature of fluid is a decreasing function of viscoelastic parameter, mass suction/injection parameter and Prandtl number.
Khan, Sami Ullah; Ali, Nasir; Abbas, Zaheer
2015-01-01
An analysis is carried out to study the heat transfer in unsteady two-dimensional boundary layer flow of a magnetohydrodynamics (MHD) second grade fluid over a porous oscillating stretching surface embedded in porous medium. The flow is induced due to infinite elastic sheet which is stretched periodically. With the help of dimensionless variables, the governing flow equations are reduced to a system of non-linear partial differential equations. This system has been solved numerically using the finite difference scheme, in which a coordinate transformation is used to transform the semi-infinite physical space to a bounded computational domain. The influence of the involved parameters on the flow, the temperature distribution, the skin-friction coefficient and the local Nusselt number is shown and discussed in detail. The study reveals that an oscillatory sheet embedded in a fluid-saturated porous medium generates oscillatory motion in the fluid. The amplitude and phase of oscillations depends on the rheology of the fluid as well as on the other parameters coming through imposed boundary conditions, inclusion of body force term and permeability of the porous medium. It is found that amplitude of flow velocity increases with increasing viscoelastic and mass suction/injection parameters. However, it decreases with increasing the strength of the applied magnetic field. Moreover, the temperature of fluid is a decreasing function of viscoelastic parameter, mass suction/injection parameter and Prandtl number. PMID:26657931
Methyl alcohol used as penetrant inspection medium for porous materials
NASA Technical Reports Server (NTRS)
Hendron, J. A.
1971-01-01
Porous material thoroughly wetted with alcohol shows persistent wet line or area at locations of cracks or porosity. Inspection is qualitative and repeatable, but is used quantitatively with select samples to grade density variations in graphite blocks. Photography is employed to achieve permanent record of results.
Sherwood, Juli L; Sung, James C; Ford, Roseanne M; Fernandez, Erik J; Maneval, James E; Smith, James A
2003-02-15
In this study, we demonstrate the application of immunomagnetic labeling and magnetic resonance imaging (MRI) for the noninvasive visualization of changes in bacterial density distributions as a function of time in a water-saturated porous medium. Magnetite particles (50-60 nm diameter) were attached via a monoclonal antibody to the surface' of Escherichia coli K12 NR50 cells. The cells maintained their motility after labeling, and the presence of the magnetite did not significantly alter cell swimming speed. Diffusive migration for both motile and nonmotile E. coli through a porous medium with a particle-diameter distribution of 250-300 microm was compared. The movement of the nonmotile cells was described by an effective random motility coefficient consistent with Brownian diffusion of a nonmotile colloid. An effective coefficient determined a priori from bacterial motility in an aqueous medium and properties of the porous medium adequately described the movement of the motile cells. The ability to noninvasively visualize bacterial concentrations within an opaque porous medium in real time provides researchers with a powerful tool for studying bacterial transport in porous media. This is important for understanding the impact of bacterial transport on remediation strategies for environmental cleanup of polluted groundwater.
2014-01-01
Three-dimensional hollow porous superparamagnetic Fe3O4 microspheres were synthesized via a facile hydrothermal process. A series of characterizations done with X-ray diffraction, Brunauer-Emmett-Teller method, Fourier transform infrared spectroscopy, scanning electron microscopy, and transmission electron microscopy indicated that the production of Fe3O4 microspheres possessed good monodispersity, uniform size distribution, hollow and porous structural characters, and strong superparamagnetic behavior. The obtained Fe3O4 microspheres have a diameter of ca. 300 nm, which is composed of many interconnected nanoparticles with a size of ca. 20 nm. The saturation magnetization is 80.6 emu·g-1. The as-prepared products had promising applications as novel catalysts to remove organic pollutants (methylene blue) from wastewater in the presence of H2O2 and ultrasound irradiation. PMID:25520596
Chai, Yoke Chin; Kerckhofs, Greet; Roberts, Scott J; Van Bael, Simon; Schepers, Evert; Vleugels, Jozef; Luyten, Frank P; Schrooten, Jan
2012-06-01
Successful clinical repair of non-healing skeletal defects requires the use of bone substitutes with robust bone inductivity and excellent biomechanical stability. Thus, three-dimensionally functionalised porous calcium phosphate-Ti6Al4V (CaP-Ti) hybrids were produced by perfusion electrodeposition, and the in vitro and in vivo biological performances were evaluated using human periosteum derived cells (hPDCs). By applying various current densities at the optimised deposition conditions, CaP coatings with sub-micrometer to nano-scale porous crystalline structures and different ion dissolution kinetics were deposited on the porous Ti6Al4V scaffolds. These distinctive physicochemical properties caused a significant impact on in vitro proliferation, osteogenic differentiation, and matrix mineralisation of hPDCs. This includes a potential role of hPDCs in mediating osteoclastogenesis for the resorption of CaP coatings, as indicated by a significant down-regulation of osteoprotegerin (OPG) gene expression and by the histological observation of abundant multi-nucleated giant cells near to the coatings. By subcutaneous implantation, the produced hybrids induced ectopic bone formation, which was highly dependent on the physicochemical properties of the CaP coating (including the Ca(2+) dissolution kinetics and coating surface topography), in a cell density-dependent manner. This study provided further insight on stem cell-CaP biomaterial interactions, and the feasibility to produced bone reparative units that are predictively osteoinductive in vivo by perfusion electrodeposition technology.
Chang, Jin; Ahmad, Muhammad Z; Wlodarski, Wojtek; Waclawik, Eric R
2013-07-02
Complex three-dimensional structures comprised of porous ZnO plates were synthesized in a controlled fashion by hydrothermal methods. Through subtle changes to reaction conditions, the ZnO structures could be self-assembled from 20 nm thick nanosheets into grass-like and flower-like structures which led to the exposure of high proportions of ZnO {0001} crystal facets for both these materials. The measured surface area of the flower-like and the grass, or platelet-like ZnO samples were 72.8 and 52.4 m2∙g-1, respectively. Gas sensing results demonstrated that the porous, flower-like ZnO structures exhibited enhanced sensing performance towards NO2 gas compared with either grass-like ZnO or commercially sourced ZnO nanoparticle samples. The porous, flower-like ZnO structures provided a high surface area which enhanced the ZnO gas sensor response. X-ray photoelectron spectroscopy characterization revealed that flower-like ZnO samples possessed a higher percentage of oxygen vacancies than the other ZnO sample-types, which also contributed to their excellent gas sensing performance.
Taboas, J M; Maddox, R D; Krebsbach, P H; Hollister, S J
2003-01-01
Precise control over scaffold material, porosity, and internal pore architecture is essential for tissue engineering. By coupling solid free form (SFF) manufacturing with conventional sponge scaffold fabrication procedures, we have developed methods for casting scaffolds that contain designed and controlled locally porous and globally porous internal architectures. These methods are compatible with numerous bioresorbable and non-resorbable polymers, ceramics, and biologic materials. Phase separation, emulsion-solvent diffusion, and porogen leaching were used to create poly(L)lactide (PLA) scaffolds containing both computationally designed global pores (500, 600, or 800 microm wide channels) and solvent fashioned local pores (50-100 microm wide voids or 5-10 microm length plates). Globally porous PLA and polyglycolide/PLA discrete composites were made using melt processing. Biphasic scaffolds with mechanically interdigitated PLA and sintered hydroxyapatite regions were fabricated with 500 and 600 microm wide global pores. PLA scaffolds with complex internal architectures that mimicked human trabecular bone were produced. Our indirect fabrication using casting in SFF molds provided enhanced control over scaffold shape, material, porosity and pore architecture, including size, geometry, orientation, branching, and interconnectivity. These scaffolds that contain concurrent local and global pores, discrete material regions, and biomimetic internal architectures may prove valuable for multi-tissue and structural tissue interface engineering. PMID:12417192
NASA Astrophysics Data System (ADS)
Wang, Hongbin; Wang, Ning; Hang, Tao; Li, Ming
2016-05-01
Three-dimensional porous micro-nano hierarchical structure Cu films were prepared by electrochemical deposition with the Hydrogen bubble dynamic template. The morphologies of the deposited films characterized by Scanning Electronic Microscopy (SEM) exhibit a porous micro-nano hierarchical structure, which consists of three levels in different size scales, namely the honeycomb-like microstructure, the dendritic substructure and the nano particles. Besides, the factors which influenced the microscopic morphology were studied, including the deposition time and the additive Ethylene diamine. By measuring the water contact angle, the porous copper films were found to be super-hydrophobic. The maximum of the contact angles could reach as high as 162.1°. An empirical correlation between morphologies and wetting properties was revealed for the first time. The pore diameter increased simultaneously with the deposition time while the contact angle decreased. The mechanism was illustrated by two classical models. Such super-hydrophobic three-dimensional hierarchical micro-nano structure is expected to have practical application in industry.
Analysis of shape of porous cooled medium for an imposed surface heat flux and temperature
NASA Technical Reports Server (NTRS)
Siegel, R.
1973-01-01
The surface of a porous cooled medium is to be maintained at a specified design temperature while being subjected to uniform heating by an external source. An analytical method is given for determining the shape of the medium surface that will satisfy these boundary conditions. The analysis accounts for temperature dependent variations of fluid density and viscosity and for temperature dependent matrix thermal conductivity. The energy equation is combined with Darcy's law in such a way that a potential can be defined that satisfies Laplace's equation. All of the heat-transfer and flow quantities are expressed in terms of this potential. The determination of the shape of the porous cooled region is thereby reduced to a free-boundary problem such as in inviscid free jet theory. Two illustrative examples are carried out: a porous leading edge with coolant supplied through a slot and a porous cooled duct with a rectangular outer boundary.
NASA Astrophysics Data System (ADS)
Darvini, G.; Salandin, P.
2009-12-01
To analyze the impact of the hydraulic conductivity K spatial variability in a real field case (as an example to delimitate a well catchment), numerical simulations can be reasonably developed in a two-dimensional vertical average context. Nevertheless the plume evolution is a consequence of a more complex three-dimensional heterogeneous structure whose vertical variability dominates the dispersion phenomena at local scale. In larger domains, the effect of the vertical heterogeneity combines itself with that one due to the horizontal variability of K, and only when the plume has travelled a large number of (horizontal) integral scales, its evolution can be analyzed in a regional context, under the hypothesis that the transmissivity spatial distribution prevails. Until this limit is reached, the vertical and horizontal variability of K are combined to give a fully 3-D dispersion process. In all these situations, to successfully accomplish the 3-D heterogeneous structure of the aquifer in 2-D simulations, more than the planimetric depth-averaged variability of K must be accounted for. To define the uncertainty related to the use of different planimetric schematizations of the real hydraulic conductivity spatial distribution, we present here the results of some numerical experiments that compare the 3-D plume evolution with 2-D simulations developed by tacking into account different hydraulic conductivity distribution schematization, by considering a hierarchical architecture of media also. This description of a sedimentary formation combined with the finite size of the plume requires theoretical and numerical tools able to take into account the flow field inhomogeneity and the ergodicity lack that characterize the transport phenomena. Following this way it will be possible to quantify / reduce the uncertainty related to a 2-D schematization in a large number of real cases where the domain spans between the local and the regional scale and whose dimension may lead to
2015-01-01
One-dimensional (1D) boron nitride nanotube (BNNT) and 2D hexagonal BN (h-BN) are attractive for demonstrating fundamental physics and promising applications in nano-/microscale devices. However, there is a high anisotropy associated with these BN allotropes as their excellent properties are either along the tube axis or in-plane directions, posing an obstacle in their widespread use in technological and industrial applications. Herein, we report a series of 3D BN prototypes, namely, pillared boron nitride (PBN), by fusing single-wall BNNT and monolayer h-BN aimed at filling this gap. We use density functional theory and molecular dynamics simulations to probe the diverse mechano-mutable properties of PBN prototypes. Our results demonstrate that the synergistic effect of the tubes, junctions, and sheets imparts cooperative deformation mechanisms, which overcome the intrinsic limitations of the PBN constituents and provide a number of superior characteristics including 3D balance of strength and toughness, emergence of negative Poisson’s ratio, and elimination of strain softening along the armchair orientation. These features, combined with the ultrahigh surface area and lightweight structure, render PBN as a 3D multifunctional template for applications in graphene-based nanoelectronics, optoelectronics, gas storage, and functional composites with fascinating in-plane and out-of-plane tailorable properties. PMID:25289114
Numerical modeling of fresh concrete flow through porous medium
NASA Astrophysics Data System (ADS)
Kolařík, F.; Patzák, B.; Zeman, J.
2016-06-01
The paper focuses on a numerical modeling of a non-Newtonian fluid flow in a porous domain. It presents combination of a homogenization approach to obtain permeability from the underlying micro-structure with coupling of a Stokes and Darcy flow through the interface on the macro level. As a numerical method we employed the Finite Element method. The results obtained from the homogenization approach are validated against fully resolved solution computed by direct numerical simulation.
NASA Astrophysics Data System (ADS)
Jadhav, Harsharaj S.; Thorat, Gaurav M.; Mun, Junyoung; Seo, Jeong Gil
2016-01-01
Transition metal oxides have attracted great attention as an anode material for next generation lithium ion batteries. Here we report the preparation of self-assembled hierarchical 3D-NiO microspheres with ultra-thin porous nanoflakes by simple and cost effective urea assisted chemical co-precipitation method followed by annealing at different temperature. It is noteworthy that the annealing temperature has an impact on the formation of different morphologies and resultantly on the electrochemical performance. This hierarchical 3D-NiO microspheres with ultra-thin porous nanoflakes shows enhanced electrochemical performance with a large reversible capacity, superior cyclic performance, high rate capability, and improved ionic conductivity as an anode material for lithium ion batteries. A high reversible capacity up to 795 mA h g-1 after 150 cycles at a rate of 0.5 C, and a capacity higher than 460.2 mA h g-1 at a rate as high as 10 C were obtained for optimized NiO sample. In particular, enhancement of the electrochemical performance was attributed to the high specific surface area, good electric contact among the particles, and easier lithium ion diffusion.
NASA Astrophysics Data System (ADS)
Boon, M.; Niu, B.; Krevor, S. C.
2014-12-01
Processes involving feedbacks between chemical reaction and fluid flow through porous media are poorly understood. Non-reactive and reactive core flooding experiments have been carried out in sandstone and two carbonate cores with varying degrees of heterogeneity. The dispersion, mixing and reaction of chemical components in an aqueous solution injected into rock cores were visualised in 3D with the use of chemical dopants and a medical x-ray CT scanner. With regards to solid-fluid reactions, the impact of rock dissolution on subsequent chemical transport was observed by injecting a carefully selected acidic solution. Simultaneous observations of the permeability evolution were made along with analysis of the effluent chemistry using an ICP-MS. This has resulted in a high quality 3D data set of the space and time evolution of the concentration of aqueous chemical components in non-reactive and reactive core-flooding experiments in rocks with different degrees of heterogeneity in combination with precise data of the effluent composition and rock permeability. This will allow us to assess the effect of flow and transport heterogeneity on upscaled effective reaction rates. Furthermore, these observations can be used as a future benchmark test for numerical models for chemical transport and fluid-solid reactions and in the development of upscaling techniques for accurate and efficient modelling of chemical processes during flow in porous media.
The Analytical Solutions for Magnetohydrodynamic Flow of a Third Order Fluid in a Porous Medium
NASA Astrophysics Data System (ADS)
Hayat, Tasawar; Ellahi, Rahmat; Mahomed, Fazal Mehmood
2009-10-01
An analysis has been carried out for flow and heat transfer characteristics in a third grade fluid between two porous plates. The electrically conducting fluid fills the porous medium. The solutions have been developed for small porosity and magnetic field. Three flow problems are investigated and analytical expressions for the velocity field and temperature distribution are given for each case. Moreover, we recover and extend the results of Siddiqui et al. [1] by presenting exact solutions for the governing equations derived in [1].
Ye, Yu; Chiogna, Gabriele; Cirpka, Olaf; Grathwohl, Peter; Rolle, Massimo
2015-01-01
Dilution of solute plumes in groundwater strongly depends on transverse mixing. Thus, the correct parameterization of transverse dispersion is of critical importance for the quantitative description of solute transport. In this study we perform flow-through laboratory experiments to investigate the influence of transport dimensionality on transverse mixing. We present a high-resolution experimental setup to study solute dilution and transverse dispersion in three-dimensional porous media. We conduct multi-tracer experiments in the new 3-D setup and compare the results with the outcomes of analogous tracer experiments performed in a quasi 2-D system. We work under steady-state flow and transport conditions and consider a range of velocities relevant for groundwater flow (0.5-8 m/day). Transverse dispersion coefficients are determined from high-resolution concentration profiles at the outlet of the flow-through chambers (7×7 ports in the 3-D setup and 7 ports in the quasi 2-D system), considering conservative tracers with significantly different aqueous diffusion coefficients, namely fluorescein and dissolved oxygen. To quantify dilution in the 2-D and 3-D systems, we experimentally determine the flux-related dilution index using the flow rates and the concentrations measured at the inlet and outlet ports, and we propose semi-analytical expressions to predict its evolution with travel distance in uniform groundwater flow. The experimental results in the quasi 2-D and 3-D flow-through systems are consistent and show a compound-specific behavior of the transverse dispersion coefficient and its non-linear dependence on the seepage velocity in both setups. The degree of dilution and the compound-specific effects of transverse dispersion are considerably more pronounced in 3-D than in quasi 2-D transport systems.
A comparison of measured and modeled velocity fields for a laminar flow in a porous medium
NASA Astrophysics Data System (ADS)
Wood, B. D.; Apte, S. V.; Liburdy, J. A.; Ziazi, R. M.; He, X.; Finn, J. R.; Patil, V. A.
2015-11-01
Obtaining highly-resolved velocity data from experimental measurements in porous media is a significant challenge. The goal of this work is to compare the velocity fields measured in a randomly-packed porous medium obtained from particle image velocimetry (PIV) with corresponding fields predicted from direct numerical simulation (DNS). Experimentally, the porous medium was comprised of 15 mm diameter spherical beads made of optical glass placed in a glass flow cell to create the packed bed. A solution of ammonium thiocyanate was refractive-index matched to the glass creating a medium that could be illuminated with a laser sheet without distortion. The bead center locations were quantified using the imaging system so that the geometry of the porous medium was known very accurately. Two-dimensional PIV data were collected and processed to provide high-resolution velocity fields at a single plane within the porous medium. A Cartesian-grid-based fictitious domain approach was adopted for the direct numerical simulation of flow through the same geometry as the experimental measurements and without any adjustable parameters. The uncertainties associated with characterization of the pore geometry, PIV measurements, and DNS predictions were all systematically quantified. Although uncertainties in bead position measurements led to minor discrepancies in the comparison of the velocity fields, the axial and normal velocity deviations exhibited normalized root mean squared deviations (NRMSD) of only 11.32% and 4.74%, respectively. The high fidelity of both the experimental and numerical methods have significant implications for understanding and even for engineering the micro-macro relationship in porous materials. The ability to measure and model sub-pore-scale flow features also has relevance to the development of upscaled models for flow in porous media, where physically reasonable closure models must be developed at the sub-pore scale. These results provide valuable data
Instabilities of a free bilayer flowing on an inclined porous medium.
Praveen Kumar, A Ananth; Usha, R; Banerjee, Tamal; Bandyopadhyay, Dipankar
2013-12-01
The instabilities of a free bilayer flowing on an inclined Darcy-Brinkman porous layer have been explored. The bilayer is composed of a pair of immiscible liquid films with a deformable liquid-liquid interface and a liquid-air free surface. An Orr-Sommerfeld analysis of the governing equations and boundary conditions uncovers that this configuration can be unstable by a pair of long-wave interfacial modes at the free surface and at the interface together with a couple of finite wave-number shear modes originating from the inertial influences at the liquid layers. In particular, one of the shear modes originates beyond a threshold flow rate owing to the slippage at the porous-liquid interface and is found to be the dominant one even when the porous medium is moderately thin, porous, and permeable. The strength of the porous media mediated mode (a) grows with increase in porosity, (b) grows and then remains invariant with increase in thickness, and (c) initially grows and then decays with increase in the permeability of the porous layer. Further, the presence of a lower layer with smaller viscosity and a thicker upper layer is found to facilitate the growth of this newly identified porous media mode. Importantly, beyond a threshold upper to lower thickness and viscosity ratios and the angle of inclination the porous media mode dominates over all the other interfacial or shear modes, highlighting its importance in the bilayer flows down an inclined porous medium. The study showcases the importance of a porous layer in destabilizing a free bilayer flow down an inclined plane, which can be of importance to improve mixing, emulsification, and heat and mass transfer characteristics in the microscale devices.
Formation of bubbly horizon in liquid-saturated porous medium by surface temperature oscillation.
Goldobin, Denis S; Krauzin, Pavel V
2015-12-01
We study nonisothermal diffusion transport of a weakly soluble substance in a liquid-saturated porous medium in contact with a reservoir of this substance. The surface temperature of the porous medium half-space oscillates in time, which results in a decaying solubility wave propagating deep into the porous medium. In this system, zones of saturated solution and nondissolved phase coexist with ones of undersaturated solution. The effect is first considered for the case of annual oscillation of the surface temperature of water-saturated ground in contact with the atmosphere. We reveal the phenomenon of formation of a near-surface bubbly horizon due to temperature oscillation. An analytical theory of the phenomenon is developed. Further, the treatment is extended to the case of higher frequency oscillations and the case of weakly soluble solids and liquids. PMID:26764828
NASA Astrophysics Data System (ADS)
Liao, M. W.; Chung, C. K.
2014-08-01
The porous anodic aluminum oxide (AAO) with high-aspect-ratio pore channels is widely used as a template for fabricating nanowires or other one-dimensional (1D) nanostructures. The high specific surface area of AAO can also be applied to the super capacitor and the supporting substrate for catalysis. The rough surface could be helpful to enhance specific surface area but it generally results in electrical field concentration even to ruin AAO. In this article, the aluminum (Al) films with the varied 2D-3D morphology on Si substrates were prepared using magnetron sputtering at a power of 50 W-185 W for 1 h at a working pressure of 2.5 × 10-1 Pa. Then, AAO was fabricated from the different Al films by means of one-step hybrid pulse anodizing (HPA) between the positive 40 V and the negative -2 V (1 s:1 s) for 3 min in 0.3 M oxalic acid at a room temperature. The microstructure and morphology of Al films were characterized by X-ray diffraction, scanning electron microscope and atomic force microscope, respectively. Some hillocks formed at the high target power could be attributed to the grain texture growth in the normal orientation of Al(1 1 1). The 3D porous AAO structure which is different from the conventional 2D planar one has been successfully demonstrated using HPA on the film with greatly rough hillock-surface formed at the highest power of 185 W. It offers a potential application of the new 3D AAO to high specific surface area devices.
Plantamura, E; Huyghe, G; Panterne, B; Delesalle, N; Thépot, A; Reverdy, M E; Damour, O; Auxenfans, Céline
2012-08-01
Living tissue engineering for regenerative therapy cannot withstand the usual pharmacopoeia methods of purification and terminal sterilization. Consequently, these products must be manufactured under aseptic conditions at microbiologically controlled environment facilities. This study was proposed to validate BacT/ALERT(®)3D automated culture system for microbiological control of epithelial cell culture medium (ECCM). Suspensions of the nine microorganisms recommended by the European Pharmacopoeia (Chap. 2.6.27: "Microbiological control of cellular products"), plus one species from oral mucosa and two negative controls with no microorganisms were prepared in ECCM. They were inoculated in FA (anaerobic) and SN (aerobic) culture bottles (Biomérieux, Lyon, France) and incubated in a BacT/ALERT(®)3D automated culture system. For each species, five sets of bottles were inoculated for reproducibility testing: one sample was incubated at the French Health Products Agency laboratory (reference) and the four others at Cell and Tissue Bank of Lyon, France. The specificity of the positive culture bottles was verified by Gram staining and then subcultured to identify the microorganism grown. The BacT/ALERT(®)3D system detected all the inoculated microorganisms in less than 2 days except Propionibacterium acnes which was detected in 3 days. In conclusion, this study demonstrates that the BacT/ALERT(®)3D system can detect both aerobic and anaerobic bacterial and fungal contamination of an epithelial cell culture medium consistent with the European Pharmacopoeia chapter 2.6.27 recommendations. It showed the specificity, sensitivity, and precision of the BacT/ALERT(®)3D method, since all the microorganisms seeded were detected in both sites and the uncontaminated medium ECCM remained negative at 7 days. PMID:22160810
Yuan, Xiaoya; Zhou, Chou; Jin, Yanrong; Jing, Qiuye; Yang, Yaling; Shen, Xu; Tang, Qi; Mu, Yuanhua; Du, An-Ke
2016-04-15
3D porous framework composed of exfoliated ultrathin nanosheets is a hot topic in the field of energy storage and conversion. A facile method to prepare 3D mesoporous C3N4 with few-layered nanosheets interconnected in large quantity via H2SO4 intercalation and subsequent thermal treatment was described herein. The obtained thermally-exfoliated C3N4 (TE-C3N4) was thoroughly characterized by scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), powder X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Fourier transform infrared (FTIR) spectroscopy, atomic force microscopy (AFM), UV-Vis diffuse reflectance spectroscopy (DRS) and Brunauer-Emmett-Teller (BET) measurements. The detailed analysis indicated that TE-C3N4 possessed enlarged inter-layer space, enhanced UV-light adsorption and high specific surface area with 3D interconnected structure composed of ultrathin 2D nanosheets. Compared to bulk C3N4, TE-C3N4 showed an enhanced photocatalytic activity for photodegradation of Rhodamine B under UV-light irradiation and exhibited no significant loss of photocatalytic activity after 11 recycled runs. The pseudo-first reaction rate constant for TE-C3N4 was about four times higher than that for pure bulk-C3N4. The better photocatalytic performance could be attributed to more active catalytic sites, prolonged photo-excited carrier lifetime and shorted pathway of the carriers to the reaction sites.
Pan, David; Ombaba, Matthew; Zhou, Zhi-You; Liu, Yang; Chen, Shaowei; Lu, Jennifer
2012-12-21
For carbon nanotube-based electronics to achieve their full performance potential, it is imperative to minimize the contact resistance between macroscale metal contacts and the carbon nanotube (CNT) nanoelectrodes. We have developed a three-dimensional electrode platform that consists of carbon nanofibers (CNFs) that are directly grown on a metal contact, such as copper (Cu). Carbon nanofiber morphology can be tailored by adjusting the annealing time of a thin electrochemically deposited nickel catalyst layer on copper. We demonstrate that increasing the annealing time increases the amount of copper infused into the nickel catalyst layer. This reduces the carbon deposition rate, and consequently a more well-defined CNF 3D architecture can be fabricated. This direct growth of CNFs on a Cu substrate yields an excellent electron transfer pathway, with contact resistance between CNFs and Cu being comparable to that of a Cu-Cu interface. Furthermore, the excellent bonding strength between CNFs and Cu can be maintained over prolonged periods of ultrasonication. The porous 3D platform affixed with intertwined CNFs allows facile surface functionalization. Using a simple solution soaking procedure, the CNF surface has been successfully functionalized with iron(II) phthalocyanine (FePc). FePc functionalized CNFs exhibit excellent oxygen reduction capability, equivalent to platinum-carbon electrodes. This result demonstrates the technological promise of this new 3D electrode platform that can be exploited in other applications that include sensing, battery, and supercapacitors. PMID:23171171
NASA Astrophysics Data System (ADS)
MacKinnon, David K.; Cournoyer, Luc; Beraldin, J.-Angelo
2015-05-01
Within the context of the ASTM E57 working group WK12373, we compare the two methods that had been initially proposed for calculating the relative range error of medium-range (2 m to 150 m) optical non-contact 3D imaging systems: the first is based on a single plane (single-plane assembly) and the second on an assembly of three mutually non-orthogonal planes (three-plane assembly). Both methods are evaluated for their utility in generating a metric to quantify the relative range error of medium-range optical non-contact 3D imaging systems. We conclude that the three-plane assembly is comparable to the single-plane assembly with regard to quantification of relative range error while eliminating the requirement to isolate the edges of the target plate face.
Heat transfer in porous medium embedded with vertical plate: Non-equilibrium approach - Part A
NASA Astrophysics Data System (ADS)
Badruddin, Irfan Anjum; Quadir, G. A.
2016-06-01
Heat transfer in a porous medium embedded with vertical flat plate is investigated by using thermal non-equilibrium model. Darcy model is employed to simulate the flow inside porous medium. It is assumed that the heat transfer takes place by natural convection and radiation. The vertical plate is maintained at isothermal temperature. The governing partial differential equations are converted into non-dimensional form and solved numerically using finite element method. Results are presented in terms of isotherms and streamlines for various parameters such as heat transfer coefficient parameter, thermal conductivity ratio, and radiation parameter
Saalfrank, Rolf W; Scheurer, Andreas
2012-01-01
Supramolecular coordination cages and polymers bear exceptional advantages over their organic counterparts. They are available in one-pot reactions and in high yields and display physical properties that are generally inaccessible with organic species. Moreover, their weak, reversible, noncovalent bonding interactions facilitate error checking and self-correction. This review emphasizes the achievements in supramolecular coordination container as well as polymer chemistry initiated by serendipity and their materialization based on rational design. The recognition of similarities in the synthesis of different supramolecular assemblies allows prediction of potential structures in related cases. The combination of detailed symmetry considerations with the basic rules of coordination chemistry has only recently allowed for the design of rational strategies for the construction of a variety of nanosized spherical containers, bowls, 1D-, 2D-, and 3D-coordination polymers with specified size and shape. PMID:22160460
Pyka, Grzegorz; Kerckhofs, Greet
2014-01-15
In material science microfocus X-ray computed tomography (micro-CT) is one of the most popular non-destructive techniques to visualise and quantify the internal structure of materials in 3D. Despite constant system improvements, state-of-the-art micro-CT images can still hold several artefacts typical for X-ray CT imaging that hinder further image-based processing, structural and quantitative analysis. For example spatial resolution is crucial for an appropriate characterisation as the voxel size essentially influences the partial volume effect. However, defining the adequate image resolution is not a trivial aspect and understanding the correlation between scan parameters like voxel size and the structural properties is crucial for comprehensive material characterisation using micro-CT. Therefore, the objective of this study was to evaluate the influence of the spatial image resolution on the micro-CT based morphological analysis of three-dimensional (3D) open porous structures with a high surface complexity. In particular the correlation between the local surface properties and the accuracy of the micro-CT-based macro-morphology of 3D open porous Ti6Al4V structures produced by selective laser melting (SLM) was targeted and revealed for rough surfaces a strong dependence of the resulting structure characteristics on the scan resolution. Reducing the surface complexity by chemical etching decreased the sensitivity of the overall morphological analysis to the spatial image resolution and increased the detection limit. This study showed that scan settings and image processing parameters need to be customized to the material properties, morphological parameters under investigation and the desired final characteristics (in relation to the intended functional use). Customization of the scan resolution can increase the reliability of the micro-CT based analysis and at the same time reduce its operating costs. - Highlights: • We examine influence of the image resolution
NASA Astrophysics Data System (ADS)
Thakur, R. C.; Rana, G. C.
2013-06-01
In this paper, we investigate the effect of a vertical magnetic field on thermal instability of an Oldroydian visco-elastic rotating fluid in a porous medium. By applying the normal mode analysis method, the dispersion relation governing the effects of rotation, magnetic field and medium permeability is derived and solved analytically and numerically. For the case of stationary convection, the Oldroydian viscoelastic fluid behaves like an ordinary Newtonian fluid and it is observed that rotation has a stabilizing effect while the magnetic field and medium permeability have a stabilizing/destabilizing effect under certain conditions on thermal instability of the Oldroydian viscoelastic fluid in a porous medium. The oscillatory modes are introduced due to the presence of rotation, the magnetic field and gravity field. It is also observed that the `principle of exchange of stability' is invalid in the presence of rotation and the magnetic field.
Modification of Surface Density of a Porous Medium
NASA Technical Reports Server (NTRS)
Stackpoole, Margaret M. (Inventor); Espinoza, Christian (Inventor)
2016-01-01
A method for increasing density of a region of a porous, phenolic bonded ("PPB") body adjacent to a selected surface to increase failure tensile strength of the adjacent region and/or to decrease surface recession at elevated temperatures. When the surface-densified PPB body is brought together with a substrate, having a higher failure tensile strength, to form a composite body with a PPB body/substrate interface, the location of tensile failure is moved to a location spaced apart from the interface, the failure tensile strength of the PPB body is increased, and surface recession of the material at elevated temperature is reduced. The method deposits and allows diffusion of a phenolic substance on the selected surface. The PPB body and the substrate may be heated and brought together to form the composite body. The phenolic substance is allowed to diffuse into the PPB body, to volatilize and to cure, to provide a processed body with an increased surface density.
NASA Astrophysics Data System (ADS)
Hou, Yang; Li, Jianyang; Gao, Xianfeng; Wen, Zhenhai; Yuan, Chris; Chen, Junhong
2016-04-01
Although lithium-sulfur (Li-S) batteries have attracted much attention due to their high theoretical specific energy and low cost, their practical applications have been severely hindered by poor cycle life, inadequate sulfur utilization, and the insulating nature of sulfur. Here, we report a rationally designed Li-S cathode with a dual-confined configuration formed by confining sulfur in 2D carbon nanosheets with an abundant porous structure followed by 3D graphene aerogel wrapping. The porous carbon nanosheets act as the sulfur host and suppress the diffusion of polysulfide, while the graphene conductive networks anchor the sulfur-adsorbed carbon nanosheets, providing pathways for rapid electron/ion transport and preventing polysulfide dissolution. As a result, the hybrid electrode exhibits superior electrochemical performance, including a large reversible capacity of 1328 mA h g-1 in the first cycle, excellent cycling stability (maintaining a reversible capacity of 647 mA h g-1 at 0.2 C after 300 cycles) with nearly 100% Coulombic efficiency, and a high rate capability of 512 mA h g-1 at 8 C for 30 cycles, which is among the best reported rate capabilities.Although lithium-sulfur (Li-S) batteries have attracted much attention due to their high theoretical specific energy and low cost, their practical applications have been severely hindered by poor cycle life, inadequate sulfur utilization, and the insulating nature of sulfur. Here, we report a rationally designed Li-S cathode with a dual-confined configuration formed by confining sulfur in 2D carbon nanosheets with an abundant porous structure followed by 3D graphene aerogel wrapping. The porous carbon nanosheets act as the sulfur host and suppress the diffusion of polysulfide, while the graphene conductive networks anchor the sulfur-adsorbed carbon nanosheets, providing pathways for rapid electron/ion transport and preventing polysulfide dissolution. As a result, the hybrid electrode exhibits superior
Smoothed Particle Hydrodynamics Modeling of Gravity Currents on a Dry Porous Medium
NASA Astrophysics Data System (ADS)
Daly, E.; Grimaldi, S.; Bui, H.
2014-12-01
Gravity currents flowing over porous media occur in many environmental processes and industrial applications, such as irrigation, benthic boundary layers, and oil spills. The coupling of the flow over the porous surface and the infiltration of the fluid in the porous media is complex and difficult to model. Of particular interest is the prediction of the position of the runoff front and the depth of the infiltration front. We present here a model for the flow of a finite volume of a highly viscous Newtonian fluid over a dry, homogenous porous medium. The Navier-Stokes equations describing the runoff flow are coupled to the Volume Averaged Navier-Stokes equations for the infiltration flow. The numerical solution of these equations is challenging because of the presence of two free surfaces (runoff and infiltration waves), the lack of fixed boundary conditions at the runoff front, and the difficulties in defining appropriate conditions at the surface of the porous medium. The first two challenges were addressed by using Smoothed Particle Hydrodynamics, which is a Lagrangian, mesh-free particle method particularly suitable for modelling free surface flows. Two different approaches were used to model the flow conditions at the surface of the porous medium. The Two Domain Approach (TDA) assumes that runoff and infiltration flows occur in two separate homogenous domains; here, we assume the continuity of velocity and stresses at the interface of the two domains. The One Domain Approach (ODA) models runoff and infiltration flows as occurring through a medium whose hydraulic properties vary continuously in space. The transition from the hydraulic properties of the atmosphere and the porous medium occur in a layer near the surface of the porous medium. Expressions listed in literature were used to compute the thickness of this transition layer and the spatial variation of porosity and permeability within it. Our results showed that ODA led to slower velocities of the runoff
Kumar, Rajesh; Oh, Jung-Hwan; Kim, Hyun-Jun; Jung, Jung-Hwan; Jung, Chan-Ho; Hong, Won G; Kim, Hae-Jin; Park, Jeong-Young; Oh, Il-Kwon
2015-07-28
Atomic-scale defects on carbon nanostructures have been considered as detrimental factors and critical problems to be eliminated in order to fully utilize their intrinsic material properties such as ultrahigh mechanical stiffness and electrical conductivity. However, defects that can be intentionally controlled through chemical and physical treatments are reasonably expected to bring benefits in various practical engineering applications such as desalination thin membranes, photochemical catalysts, and energy storage materials. Herein, we report a defect-engineered self-assembly procedure to produce a three-dimensionally nanohole-structured and palladium-embedded porous graphene hetero-nanostructure having ultrahigh hydrogen storage and CO oxidation multifunctionalities. Under multistep microwave reactions, agglomerated palladium nanoparticles having diameters of ∼10 nm produce physical nanoholes in the basal-plane structure of graphene sheets, while much smaller palladium nanoparticles are readily impregnated inside graphene layers and bonded on graphene surfaces. The present results show that the defect-engineered hetero-nanostructure has a ∼5.4 wt % hydrogen storage capacity under 7.5 MPa and CO oxidation catalytic activity at 190 °C. The defect-laden graphene can be highly functionalized for multipurpose applications such as molecule absorption, electrochemical energy storage, and catalytic activity, resulting in a pathway to nanoengineering based on underlying atomic scale and physical defects.
Zhang, Long; Zhang, Fan; Yang, Xi; Long, Guankui; Wu, Yingpeng; Zhang, Tengfei; Leng, Kai; Huang, Yi; Ma, Yanfeng; Yu, Ao; Chen, Yongsheng
2013-01-01
Until now, few sp2 carbon materials simultaneously exhibit superior performance for specific surface area (SSA) and electrical conductivity at bulk state. Thus, it is extremely important to make such materials at bulk scale with those two outstanding properties combined together. Here, we present a simple and green but very efficient approach using two standard and simple industry steps to make such three-dimensional graphene-based porous materials at the bulk scale, with ultrahigh SSA (3523 m2/g) and excellent bulk conductivity. We conclude that these materials consist of mainly defected/wrinkled single layer graphene sheets in the dimensional size of a few nanometers, with at least some covalent bond between each other. The outstanding properties of these materials are demonstrated by their superior supercapacitor performance in ionic liquid with specific capacitance and energy density of 231 F/g and 98 Wh/kg, respectively, so far the best reported capacitance performance for all bulk carbon materials. PMID:23474952
Regularity for the porous medium equation with variable exponent: The singular case
NASA Astrophysics Data System (ADS)
Henriques, Eurica
We extend to the singular case the results of [E. Henriques, J.M. Urbano, Intrinsic scaling for PDEs with an exponential nonlinearity, Indiana Univ. Math. J. 55 (5) (2006) 1701-1721] concerning the regularity of weak solutions of the porous medium equation with variable exponent. The method of intrinsic scaling is used to show that local weak solutions are locally continuous.
Westdickenberg, Michael; Wilkening, Jon
2008-12-10
We introduce variational particle schemes for the porous medium equation and the system of isentropic Euler equations in one space dimension. The methods are motivated by the interpretation of each of these partial differential equations as a 'steepest descent' on a suitable abstract manifold. We show that our methods capture very well the nonlinear features of the flows.
Fractal continuum model for tracer transport in a porous medium.
Herrera-Hernández, E C; Coronado, M; Hernández-Coronado, H
2013-12-01
A model based on the fractal continuum approach is proposed to describe tracer transport in fractal porous media. The original approach has been extended to treat tracer transport and to include systems with radial and uniform flow, which are cases of interest in geoscience. The models involve advection due to the fluid motion in the fractal continuum and dispersion whose mathematical expression is taken from percolation theory. The resulting advective-dispersive equations are numerically solved for continuous and for pulse tracer injection. The tracer profile and the tracer breakthrough curve are evaluated and analyzed in terms of the fractal parameters. It has been found in this work that anomalous transport frequently appears, and a condition on the fractal parameter values to predict when sub- or superdiffusion might be expected has been obtained. The fingerprints of fractality on the tracer breakthrough curve in the explored parameter window consist of an early tracer breakthrough and long tail curves for the spherical and uniform flow cases, and symmetric short tailed curves for the radial flow case.
Hou, Yang; Li, Jianyang; Gao, Xianfeng; Wen, Zhenhai; Yuan, Chris; Chen, Junhong
2016-04-21
Although lithium-sulfur (Li-S) batteries have attracted much attention due to their high theoretical specific energy and low cost, their practical applications have been severely hindered by poor cycle life, inadequate sulfur utilization, and the insulating nature of sulfur. Here, we report a rationally designed Li-S cathode with a dual-confined configuration formed by confining sulfur in 2D carbon nanosheets with an abundant porous structure followed by 3D graphene aerogel wrapping. The porous carbon nanosheets act as the sulfur host and suppress the diffusion of polysulfide, while the graphene conductive networks anchor the sulfur-adsorbed carbon nanosheets, providing pathways for rapid electron/ion transport and preventing polysulfide dissolution. As a result, the hybrid electrode exhibits superior electrochemical performance, including a large reversible capacity of 1328 mA h g(-1) in the first cycle, excellent cycling stability (maintaining a reversible capacity of 647 mA h g(-1) at 0.2 C after 300 cycles) with nearly 100% Coulombic efficiency, and a high rate capability of 512 mA h g(-1) at 8 C for 30 cycles, which is among the best reported rate capabilities. PMID:27029963
NASA Astrophysics Data System (ADS)
Zhang, Luojiang; Hui, Kwun Nam; San Hui, Kwan; Lee, Haiwon
2016-06-01
The synthesis of layered double hydroxide (LDH) as electroactive material has been well reported; however, fabricating an LDH electrode with excellent electrochemical performance at high current density remains a challenge. In this paper, we report a 3D hierarchical porous flower-like NiAl-LDH grown on nickel foam (NF) through a liquid-phase deposition method as a high-performance binder-free electrode for energy storage. With large ion-accessible surface area as well as efficient electron and ion transport pathways, the prepared LDH-NF electrode achieves high specific capacity (1250 C g-1 at 2 A g-1 and 401 C g-1 at 50 A g-1) after 5000 cycles of activation at 20 A g-1 and high cycling stability (76.7% retention after another 5000 cycles at 50 A g-1), which is higher than those of most previously reported NiAl-LDH-based materials. Moreover, a hybrid supercapacitor with LDH-NF as the positive electrode and porous graphene nanosheet coated on NF (GNS-NF) as the negative electrode, delivers high energy density (30.2 Wh kg-1 at a power density of 800 W kg-1) and long cycle life, which outperforms the other devices reported in the literature. This study shows that the prepared LDH-NF electrode offers great potential in energy storage device applications.
NASA Astrophysics Data System (ADS)
Xie, D.; Tang, W. J.; Xia, X. H.; Wang, D. H.; Zhou, D.; Shi, F.; Wang, X. L.; Gu, C. D.; Tu, J. P.
2015-11-01
Scrupulous design and fabrication of advanced anode materials are of great importance for developing high-performance lithium ion batteries. Herein, we report a facile strategy for construction of free-standing and free-binder 3D porous carbon coated MoS2/nitrogen-doped graphene (C-MoS2/N-G) integrated electrode via a hydrothermal-induced self-assembly process. The preformed carbon coated MoS2 is strongly anchored on the porous nitrogen-doped graphene aerogel architecture. As an anode for lithium ion batteries, the C-MoS2/N-G electrode delivers a high first discharge capacity of 1600 mAh g-1 and maintains 900 mAh g-1 after 500 cycles at a current density of 200 mA g-1. Impressively, superior high-rate capability is achieved for the C-MoS2/N-G with a reversible capacity of 500 mAh g-1 at a high current density of 4000 mA g-1. Furthermore, the lithium storage mechanism of the obtained integrated electrode is investigated by ex-situ X-ray photoelectron spectroscopy and transmission electron microscopy in detail.
Koh, Joo Hwan; Koh, Jong Kwan; Seo, Jin Ah; Shin, Jong-Shik; Kim, Jong Hak
2011-09-01
Porous TiO(2) nanotube arrays with three-dimensional (3D) interconnectivity were prepared using a sol-gel process assisted by poly(vinyl chloride-graft-4-vinyl pyridine), PVC-g-P4VP graft copolymer and a ZnO nanorod template. A 7 µm long ZnO nanorod array was grown from the fluorine-doped tin oxide (FTO) glass via a liquid phase deposition method. The TiO(2) sol-gel solution templated by the PVC-g-P4VP graft copolymer produced a random 3D interconnection between the adjacent ZnO nanorods during spin coating. Upon etching of ZnO, TiO(2) nanotubes consisting of 10-15 nm nanoparticles were generated, as confirmed by wide-angle x-ray scattering (WAXS), energy-filtering transmission electron microscopy (EF-TEM) and field-emission scanning electron microscopy (FE-SEM). The ordered and interconnected nanotube architecture showed an enhanced light scattering effect and increased penetration of polymer electrolytes in dye-sensitized solar cells (DSSC). The energy conversion efficiency reached 1.82% for liquid electrolyte, and 1.46% for low molecular weight (M(w)) and 0.74% for high M(w) polymer electrolytes.
Nellore, Bhanu Priya Viraka; Kanchanapally, Rajashekhar; Pedraza, Francisco; Sinha, Sudarson Sekhar; Pramanik, Avijit; Hamme, Ashton T; Arslan, Zikri; Sardar, Dhiraj; Ray, Paresh Chandra
2015-09-01
More than a billion people lack access to safe drinking water that is free from pathogenic bacteria and toxic metals. The World Health Organization estimates several million people, mostly children, die every year due to the lack of good quality water. Driven by this need, we report the development of PGLa antimicrobial peptide and glutathione conjugated carbon nanotube (CNT) bridged three-dimensional (3D) porous graphene oxide membrane, which can be used for highly efficient disinfection of Escherichia coli O157:H7 bacteria and removal of As(III), As(V), and Pb(II) from water. Reported results demonstrate that versatile membrane has the capability to capture and completely disinfect pathogenic pathogenic E. coli O157:H7 bacteria from water. Experimentally observed disinfection data indicate that the PGLa attached membrane can dramatically enhance the possibility of destroying pathogenic E. coli bacteria via synergistic mechanism. Reported results show that glutathione attached CNT-bridged 3D graphene oxide membrane can be used to remove As(III), As(V), and Pb(II) from water sample at 10 ppm level. Our data demonstrated that PGLa and glutathione attached membrane has the capability for high efficient removal of E. coli O157:H7 bacteria, As(III), As(V), and Pb(II) simultaneously from Mississippi River water. PMID:26273843
Nellore, Bhanu Priya Viraka; Kanchanapally, Rajashekhar; Pedraza, Francisco; Sinha, Sudarson Sekhar; Pramanik, Avijit; Hamme, Ashton T; Arslan, Zikri; Sardar, Dhiraj; Ray, Paresh Chandra
2015-09-01
More than a billion people lack access to safe drinking water that is free from pathogenic bacteria and toxic metals. The World Health Organization estimates several million people, mostly children, die every year due to the lack of good quality water. Driven by this need, we report the development of PGLa antimicrobial peptide and glutathione conjugated carbon nanotube (CNT) bridged three-dimensional (3D) porous graphene oxide membrane, which can be used for highly efficient disinfection of Escherichia coli O157:H7 bacteria and removal of As(III), As(V), and Pb(II) from water. Reported results demonstrate that versatile membrane has the capability to capture and completely disinfect pathogenic pathogenic E. coli O157:H7 bacteria from water. Experimentally observed disinfection data indicate that the PGLa attached membrane can dramatically enhance the possibility of destroying pathogenic E. coli bacteria via synergistic mechanism. Reported results show that glutathione attached CNT-bridged 3D graphene oxide membrane can be used to remove As(III), As(V), and Pb(II) from water sample at 10 ppm level. Our data demonstrated that PGLa and glutathione attached membrane has the capability for high efficient removal of E. coli O157:H7 bacteria, As(III), As(V), and Pb(II) simultaneously from Mississippi River water.
Modeling of porous scaffold deformation induced by medium perfusion.
Podichetty, Jagdeep T; Madihally, Sundararajan V
2014-05-01
In this study, we tested the possibility of calculating permeability of porous scaffolds utilized in soft tissue engineering using pore size and shape. We validated the results using experimental measured pressure drop and simulations with the inclusion of structural deformation. We prepared Polycaprolactone (PCL) and Chitosan-Gelatin (CG) scaffolds by salt leaching and freeze drying technique, respectively. Micrographs were assessed for pore characteristics and mechanical properties. Porosity for both scaffolds was nearly same but the permeability varied 10-fold. Elastic moduli were 600 and 9 kPa for PCL and CG scaffolds, respectively, while Poisson's ratio was 0.3 for PCL scaffolds and ∼1.0 for CG scaffolds. A flow-through bioreactor accommodating a 10 cm diameter and 0.2 cm thick scaffold was used to determine the pressure-drop at various flow rates. Additionally, computational fluid dynamic (CFD) simulations were performed by coupling fluid flow, described by Brinkman equation, with structural mechanics using a dynamic mesh. The experimentally obtained pressure drop matched the simulation results of PCL scaffolds. Simulations were extended to a broad range of permeabilities (10(-10) m(2) to 10(-14) m(2) ), elastic moduli (10-100,000 kPa) and Poisson's ratio (0.1-0.49). The results showed significant deviation in pressure drop due to scaffold deformation compared to rigid scaffold at permeabilities near healthy tissues. Also, considering the scaffold as a nonrigid structure altered the shear stress profile. In summary, scaffold permeability can be calculated using scaffold pore characteristics and deformation could be predicted using CFD simulation. These relationships could potentially be used in monitoring tissue regeneration noninvasively via pressure drop. PMID:24259467
Numerical simulation of seismo-electromagnetic fields associated with a fault in a porous medium
NASA Astrophysics Data System (ADS)
Ren, Hengxin; Huang, Qinghua; Chen, Xiaofei
2016-07-01
In this work, we carry out numerical simulations of the seismo-electromagnetic fields associated with a fault in a porous medium by considering the electrokinetic effect. In addition to porous materials, the adopted layered models comprise solid materials in which the electrokinetic effect is inoperative. First, sensitivity study is performed for the evanescent and direct radiation electromagnetic (EM) waves generated by a double couple point source embedded in a porous half-space below a solid half-space. Results suggest that both the evanescent and direct radiation EM waves are sensitive to some medium properties, for example porosity, salinity, fluid viscosity, and conductivity of solid layer. Then, adopting an eight-layer half-space model, we simulate the seismic and EM wavefields generated by the rupture process of a finite fault. It is shown that the electrokinetic effect is able to generate observable corupture EM signals, but the observability depends on some factors such as the epicentral distance, properties of the medium where the fault is located, and local activity levels of EM noise. Time synchronization coseismic EM signals are recorded when the receiver is close to the ground water level but located in a solid medium. In addition to the post-seismic electric field, our results also show the post-seismic magnetic field which has not been identified in previous simulation studies on the electrokinetic effect. The generation of the post-seismic magnetic field probably requires a sufficiently strong medium heterogeneity or fluid-pressure gradient.
Yuan, Xiaoya; Zhou, Chou; Jin, Yanrong; Jing, Qiuye; Yang, Yaling; Shen, Xu; Tang, Qi; Mu, Yuanhua; Du, An-Ke
2016-04-15
3D porous framework composed of exfoliated ultrathin nanosheets is a hot topic in the field of energy storage and conversion. A facile method to prepare 3D mesoporous C3N4 with few-layered nanosheets interconnected in large quantity via H2SO4 intercalation and subsequent thermal treatment was described herein. The obtained thermally-exfoliated C3N4 (TE-C3N4) was thoroughly characterized by scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), powder X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Fourier transform infrared (FTIR) spectroscopy, atomic force microscopy (AFM), UV-Vis diffuse reflectance spectroscopy (DRS) and Brunauer-Emmett-Teller (BET) measurements. The detailed analysis indicated that TE-C3N4 possessed enlarged inter-layer space, enhanced UV-light adsorption and high specific surface area with 3D interconnected structure composed of ultrathin 2D nanosheets. Compared to bulk C3N4, TE-C3N4 showed an enhanced photocatalytic activity for photodegradation of Rhodamine B under UV-light irradiation and exhibited no significant loss of photocatalytic activity after 11 recycled runs. The pseudo-first reaction rate constant for TE-C3N4 was about four times higher than that for pure bulk-C3N4. The better photocatalytic performance could be attributed to more active catalytic sites, prolonged photo-excited carrier lifetime and shorted pathway of the carriers to the reaction sites. PMID:26851454
Momentum transfer at the interface between a porous medium and a pure fluid
NASA Astrophysics Data System (ADS)
Hu, Howard; Zhang, Songpeng
2015-11-01
We examine the flow parallel to the interface between a porous medium and a liquid, focusing on the boundary conditions at the interface. When Darcy's law is used to describe the momentum transport in the porous layer, the classic Beavers-Joseph condition relates the shear rate and the slip velocity at the interface with a slip parameter that depends on the structure of the porous surface. When the Brinkman equation is used, the averaged velocity is continuous at the interface, however the fluid shear stress across the interface commonly experiences a jump. This shear stress jump can be expressed in terms of the slip velocity at the interface divided by a length characterized by the square root of the permeability, and a dimensionless stress jump coefficient. In this work, we study the momentum transfer from the clear fluid onto the solid structure at the interface, and proposed a stress partition parameter that characterizes the stress transfer from the clear fluid to the fluid (and solid) phase of the porous medium. Simple models are developed to formulate this stress partition parameter for porous media that are brush-like, long fibers, and random, respectively. Our model predictions are compared with numerical and experimental results in the literature.
Ma, Xue; Tian, Jing; Yang, Hong-Y.; Zhao, Kai; Li, Xia
2013-05-01
The reaction of RE(NO)₃·6H₂O and formamide yielded the coordination polymers, [RE(HCOO)₄]⁻[NH₂CHNH₂]⁺ (RE=Y 1, Eu 2, Gd 3, Tb 4, Dy 5, Er 6, and Yb 7). They possess 3D porous frameworks with the 1D rhombic channels occupied by [NH₂CHNH₂]⁺ cations. Complexes 2 and 4 display the characteristic down-conversion emissions corresponding to ⁵D₀→⁷F_{J} (J=1–4) transitions of Eu(III) ion and ⁵D₄→⁷F_{J} (J=6–3) transitions of Tb(III) ion, respectively. Longer lifetime values of 2.128±0.002 ms (⁵D₀) for 2 and 2.132±0.002 ms (⁵D₄) for 4 have been observed. The up-conversion spectra of the Y:Yb,Er and Gd:Yb,Er codoped complexes exhibit three emission bands around 410 (⁴H_{9/2}→⁴I_{15/2}, blue), 518–570 (⁴S_{3/2}, ²H_{11/2}→⁴I_{15/2}, green), and 655 nm (⁴F_{9/2}→⁴I_{15/2}, red). - Graphical Abstract: The complexes [RE(HCOO)₄]⁻[NH₂CHNH₂]⁺ possess 3D porous frameworks. Eu(III) and Tb(III) complexes show characteristic emission of Ln(III) ions. The up-conversion emission of the Y:Yb,Er and Gd:Yb,Er codoped complexes was observed. Highlights: •The reaction of RE(NO)₃·6H₂O and formamide produced complexes [RE(HCOO)₄]⁻[NH₂CHNH₂]⁺. • The complexes possess 3D frameworks with the 1D channels occupied by [NH₂CHNH₂]^{+} cations. • Eu(III)/Tb(III) complexes display the characteristic down-conversion emission of Ln(III) ions. • The Y:Yb,Er and Gd:Yb,Er doped complexes exhibit the up-conversion emission.
NASA Astrophysics Data System (ADS)
Monga, O.; Garnier, P.; Pot, V.; Coucheney, E.; Nunan, N.; Otten, W.; Chenu, C.
2014-04-01
This paper deals with the simulation of microbial degradation of organic matter in soil within the pore space at a microscopic scale. Pore space was analysed with micro-computed tomography and described using a sphere network coming from a geometrical modelling algorithm. The biological model was improved regarding previous work in order to include the transformation of dissolved organic compounds and diffusion processes. We tested our model using experimental results of a simple substrate decomposition experiment (fructose) within a simple medium (sand) in the presence of different bacterial strains. Separate incubations were carried out in microcosms using five different bacterial communities at two different water potentials of -10 and -100 cm of water. We calibrated the biological parameters by means of experimental data obtained at high water content, and we tested the model without changing any parameters at low water content. Same as for the experimental data, our simulation results showed that the decrease in water content caused a decrease of mineralization rate. The model was able to simulate the decrease of connectivity between substrate and microorganism due the decrease of water content.
Magneto-polar fluid flow through a porous medium of variable permeability in slip flow regime
NASA Astrophysics Data System (ADS)
Gaur, P. K.; Jha, A. K.; Sharma, R.
2016-05-01
A theoretical study is carried out to obtain an analytical solution of free convective heat transfer for the flow of a polar fluid through a porous medium with variable permeability bounded by a semi-infinite vertical plate in a slip flow regime. A uniform magnetic field acts perpendicular to the porous surface. The free stream velocity follows an exponentially decreasing small perturbation law. Using the approximate method the expressions for the velocity, microrotation, and temperature are obtained. Further, the results of the skin friction coefficient, the couple stress coefficient and the rate of heat transfer at the wall are presented with various values of fluid properties and flow conditions.
Hibi, Yoshihiko; Tomigashi, Akira; Hirose, Masafumi
2015-12-01
Numerical simulations that couple flow in a surface fluid with that in a porous medium are useful for examining problems of pollution that involve interactions among the atmosphere, surface water and groundwater, including, for example, saltwater intrusion along coasts. We previously developed a numerical simulation method for simulating a coupled atmospheric gas, surface water, and groundwater system (called the ASG method) that employs a saturation equation for flow in a porous medium; this equation allows both the void fraction of water in the surface system and water saturation in the porous medium to be solved simultaneously. It remained necessary, however, to evaluate how global pressure, including gas pressure, water pressure, and capillary pressure, should be specified at the boundary between the surface and the porous medium. Therefore, in this study, we derived a new equation for global pressure and integrated it into the ASG method. We then simulated water saturation in a porous medium and the void fraction of water in a surface system by the ASG method and reproduced fairly well the results of two column experiments. Next, we simulated water saturation in a porous medium (sand) with a bank, by using both the ASG method and a modified Picard (MP) method. We found only a slight difference in water saturation between the ASG and MP simulations. This result confirmed that the derived equation for global pressure was valid for a porous medium, and that the global pressure value could thus be used with the saturation equation for porous media. Finally, we used the ASG method to simulate a system coupling atmosphere, surface water, and a porous medium (110m wide and 50m high) with a trapezoidal bank. The ASG method was able to simulate the complex flow of fluids in this system and the interaction between the porous medium and the surface water or the atmosphere.
NASA Astrophysics Data System (ADS)
Hibi, Yoshihiko; Tomigashi, Akira; Hirose, Masafumi
2015-12-01
Numerical simulations that couple flow in a surface fluid with that in a porous medium are useful for examining problems of pollution that involve interactions among the atmosphere, surface water and groundwater, including, for example, saltwater intrusion along coasts. We previously developed a numerical simulation method for simulating a coupled atmospheric gas, surface water, and groundwater system (called the ASG method) that employs a saturation equation for flow in a porous medium; this equation allows both the void fraction of water in the surface system and water saturation in the porous medium to be solved simultaneously. It remained necessary, however, to evaluate how global pressure, including gas pressure, water pressure, and capillary pressure, should be specified at the boundary between the surface and the porous medium. Therefore, in this study, we derived a new equation for global pressure and integrated it into the ASG method. We then simulated water saturation in a porous medium and the void fraction of water in a surface system by the ASG method and reproduced fairly well the results of two column experiments. Next, we simulated water saturation in a porous medium (sand) with a bank, by using both the ASG method and a modified Picard (MP) method. We found only a slight difference in water saturation between the ASG and MP simulations. This result confirmed that the derived equation for global pressure was valid for a porous medium, and that the global pressure value could thus be used with the saturation equation for porous media. Finally, we used the ASG method to simulate a system coupling atmosphere, surface water, and a porous medium (110 m wide and 50 m high) with a trapezoidal bank. The ASG method was able to simulate the complex flow of fluids in this system and the interaction between the porous medium and the surface water or the atmosphere.
Development of the 3-D Track Imager for Medium and High-Energy Gamma-Ray Telescopes
NASA Technical Reports Server (NTRS)
Hunter, Stanley D.
2006-01-01
The Advanced Compton Telescope (ACT) and Advanced Pair Telescope (APT) are envisioned as the next medium (0.3 ^ 50 MeV) and high-energy (30 MeV - greater than 100 GeV) gamma-ray missions. These missions will address many research focus areas of the Structure and Evolution of the Universe Roadmap. These areas include: element formation, matter, energy, & magnetic field interactions in galaxies, AGN & GRB emission, and behavior of matter in extreme environments of black holes & pulsars. Achieving these science goals requires a substantial increases in telescope sensitivity and angular resolution. This talk will discuss how these goals can be met with the three-dimensional track imager (3-DTI), a large volume, low density, time projection chamber with two-dimensional micro-well detector readout and report on our development of a 10 cm x 10 cm x 30 prototype instrument.
Quenching of a highly superheated porous medium by injection of water
NASA Astrophysics Data System (ADS)
Fichot, F.; Bachrata, A.; Repetto, G.; Fleurot, J.; Quintard, M.
2012-11-01
Understanding of two-phase flow through porous medium with intense phase change is of interest in many situations, including nuclear, chemical or geophysical applications. Intense boiling occurs when the liquid is injected into a highly superheated medium. Under such conditions, the heat flux extracted by the fluid from the porous medium is mainly governed by the nucleation of bubbles and by the evaporation of thin liquid films. Both configurations are possible, depending on local flow conditions and on the ratio of bubble size to pore size. The present study is motivated by the safety evaluation of light water nuclear reactors in case of a severe accident scenario, such as the one that happened in Fukushima Dai-ichi plant in March, 2011. If water sources are not available for a long period of time, the reactor core heats up due to the residual power and eventually becomes significantly damaged due to intense oxidation of metals and fragmentation of fuel rods resulting in the formation of a porous medium where the particles have a characteristic length-scale of 1 to 5 mm. The coolability of the porous medium will depend on the water flow rate which can enter the medium under the available driving head and on the geometrical features of the porous matrix (average pore size, porosity). Therefore, it is of high interest to evaluate the conditions for which the injection of water in such porous medium is likely to stop the progression of the accident. The present paper addresses the issue of modelling two-phase flow and heat transfers in a porous medium initially dry, where water is injected. The medium is initially at a temperature well above the saturation temperature of water. In a first part, a summary of existing knowledge is provided, showing the scarcity of models and experimental data. In a second part, new experimental results obtained in an IRSN facility are analysed. The experiment consists in a bed of steel particles that are heated up to 700
Thermal consolidation of porous medium with a rheological kelvin-voigt skeleton
NASA Astrophysics Data System (ADS)
Bartlewska-Urban, Monika; Strzelecki, Tomasz
2012-10-01
This study presents calculations results of thermal consolidation process of the porous medium with the rheological Kelvin-Voigt skeleton, obtained numerically with the use of Flex.PDE software. The investigated calculation scheme consisted of the porous column filled with a liquid. The vertical load was applied to the top surface of the column through a porous plate allowing the free flow of liquid through this surface. Numerical solution is based on compression of the sample at appropriately defined boundary conditions. The aim of this study was to describe the influence of external load and temperature gradient on the deformation tests progress at different values of three parameters: λ,
New porous medium Poisson-Nernst-Planck equations for strongly oscillating electric potentials
NASA Astrophysics Data System (ADS)
Schmuck, M.
2013-02-01
We consider the Poisson-Nernst-Planck system which is well-accepted for describing dilute electrolytes as well as transport of charged species in homogeneous environments. Here, we study these equations in porous media whose electric permittivities show a strong contrast compared with the electric permittivity of the electrolyte phase. Our main result is the derivation of convenient low-dimensional equations, that is, of effective macroscopic porous media Poisson-Nernst-Planck equations, which reliably describe ionic transport. The contrast in the electric permittivities between liquid and solid phase and the heterogeneity of the porous medium induce strongly oscillating electric potentials (fields). In order to account for this specific physical scenario, we introduce a modified asymptotic multiple-scale expansion which takes advantage of the nonlinearly coupled structure of the ionic transport equations. This allows for a systematic upscaling resulting in a new effective porous medium formulation which shows a new transport term on the macroscale. Solvability of all arising equations is rigorously verified. The emergence of a new transport term indicates promising physical insights into the influence of the microscale material properties on the macroscale. Hence, systematic upscaling strategies provide a source and a prospective tool to capitalize intrinsic scale effects for scientific, engineering, and industrial applications.
Oostrom, Martinus; Freedman, Vicky L.; Wietsma, Thomas W.; Dane, Jacob H.; Truex, Michael J.
2012-11-01
Soil desiccation (drying), involving water evaporation induced by dry gas injection, is a potentially robust vadose zone remediation process to limit contaminant transport through the vadose zone. A series of four intermediate-scale flow cell experiments was conducted in homogeneous and simple layered heterogeneous porous medium systems to investigate the effects of heterogeneity on desiccation of unsaturated porous media. The permeability ratios of porous medium layers ranged from about five to almost two orders of magnitude. The insulated flow cell was equipped with twenty humidity and temperature sensors and a dual-energy gamma system was used to determine water saturations at various times. The multiphase code STOMP was used to simulate the desiccation process. Results show that injected dry gas flowed predominantly in the higher permeability layer and delayed water removal from the lower permeability material. For the configurations tested, water vapor diffusion from the lower to the higher permeability zone was considerable over the duration of the experiments, resulting in much larger relative humidity values of the outgoing air than based on permeability ratios alone. Acceptable numerical matches with the experimental data were obtained when an extension of the saturation-capillary pressure relation below the residual water saturation was used. The agreements between numerical and experimental results suggest that the correct physics are implemented in the simulator and that the thermal and hydraulic properties of the porous media, flow cell wall and insulation materials were properly represented.
Sanya, Arthur S O; Akowanou, Christian; Sanya, Emile A; Degan, Gerard
2014-01-01
The problems of steady film condensation on a vertical surface embedded in a thin porous medium with anisotropic permeability filled with pure saturated vapour are studied analytically by using the Brinkman-Darcy flow model. The principal axes of anisotropic permeability are oriented in a direction that non-coincident with the gravity force. On the basis of the flow permeability tensor due to the anisotropic properties and the Brinkman-Darcy flow model adopted by considering negligible macroscopic and microscopic inertial terms, boundary-layer approximations in the porous liquid film momentum equation is solved analytically. Scale analysis is applied to predict the order-of-magnitudes involved in the boundary layer regime. The first novel contribution in the mathematics consists in the use of the anisotropic permeability tensor inside the expression of the mathematical formulation of the film condensation problem along a vertical surface embedded in a porous medium. The present analytical study reveals that the anisotropic permeability properties have a strong influence on the liquid film thickness, condensate mass flow rate and surface heat transfer rate. The comparison between thin and thick porous media is also presented. PMID:26034679
NASA Astrophysics Data System (ADS)
Geistlinger, Helmut; Ataei-Dadavi, Iman; Mohammadian, Sadjad; Vogel, Hans-Jörg
2015-11-01
We study the impact of pore structure and surface roughness on capillary trapping of nonwetting gas phase during imbibition with water for capillary numbers between 10-7 and 5 × 10-5, within glass beads, natural sands, glass beads monolayers, and 2-D micromodels. The materials exhibit different roughness of the pore-solid interface. We found that glass beads and natural sands, which exhibit nearly the same grain size distribution, pore size distribution, and connectivity, showed a significant difference of the trapped gas phase of about 15%. This difference can be explained by the microstructure of the pore-solid interface. Based on the visualization of the trapping dynamics within glass beads monolayers and 2-D micromodels, we could show that bypass trapping controls the trapping process in glass beads monolayers, while snap-off trapping controls the trapping process in 2-D micromodels. We conclude that these different trapping processes are the reason for the different trapping efficiency, when comparing glass beads packs with natural sand packs. Moreover, for small capillary numbers of 10-6, we found that the cluster size distribution of trapped gas clusters of all 2-D and 3-D porous media can be described by a universal power law behavior predicted from percolation theory. This cannot be expected a priori for 2-D porous media, because bicontinuity of the two bulk phases is violated. Obviously, bicontinuity holds for the thin-film water phase and the bulk gas phase. The snap-off trapping process leads to ordinary bond percolation in front of the advancing bulk water phase and is the reason for the observed universal power law behavior in 2-D micromodels with rough surfaces.
The Diffusion Eigenstates in a Periodic Porous Medium with a Strong Surface Absorption
NASA Astrophysics Data System (ADS)
Bergman, D. J.; Dunn, K. J.; Latorraca, G. A.
1997-03-01
The Bloch diffusion eigenstates of a periodic porous medium, but with an otherwise arbitrary microstructure, and with strong absorption at the pore/matrix interface, have been calculated by expanding them in a series of eigenfunctions of an unphysical porous medium which has the same microstructure but no interface absorption, and where the diffusion also takes place inside the matrix with a diffusion coefficient that approaches infinity. The results are especially simple in the case where the interface absorption coefficient is infinite and for the q=0 eigenstates, but are very accurate also for large but finite rho and arbitrary q-vectors. The results of such calculations are compared with previous calculations that were limited to the regime of low interface absorption.
Experimental investigations of heat transport dynamics in a 1D porous medium column
NASA Astrophysics Data System (ADS)
Cherubini, Claudia; Pastore, Nicola; Giasi, Concetta I.; Allegretti, Nicoletta M.
2016-04-01
A laboratory physical model has been set up to analyse the forced convective flow and the related heat transport dynamics through a 1d porous medium column. In particular, the experiments regard the observation of thermal breakthrough curves obtained through a continuous flow injection in correspondence of eight thermocouple positioned uniformly along a thermally isolated column of porous medium. The experiment has been conducted for different flow rates in order to investigate the critical issues regarding heat transport phenomena such as the influence of non-linear flow regime, the relationship between the thermal dispersion with the flow velocity and the validity of the local thermal equilibrium assumption between the fluid and solid phase. The results emphasize the magnitude of the errors of the commonly used assumptions in the numerical modelling of heat transport.
Temporal behavior of a solute cloud in a fractal heterogeneous porous medium at different scales
NASA Astrophysics Data System (ADS)
Ross, Katharina; Attinger, Sabine
2010-05-01
Water pollution is still a very real problem and the need for efficient models for flow and solute transport in heterogeneous porous or fractured media is evident. In our study we focus on solute transport in heterogeneous fractured media. In heterogeneous fractured media the shape of the pores and fractures in the subsurface might be modeled as a fractal network or a heterogeneous structure with infinite correlation length. To derive explicit results for larger scale or effective transport parameters in such structures is the aim of this work. To describe flow and transport we investigate the temporal behavior of transport coefficients of solute movement through a spatially heterogeneous medium. It is necessary to distinguish between two fundamentally different quantities characterizing the solute dispersion: The effective dispersion coefficient Deff(t) represents the physical (observable) dispersion in one given realization of the medium. It is conceptually different from the mathematically simpler ensemble dispersion coefficient Dens(t) which characterizes the (abstract) dispersion with respect to the set of all possible realizations of the medium. In the framework of a stochastic approach DENTZ ET AL. (2000 I[2] & II[3]) derive explicit expressions for the temporal behavior of the center-of-mass velocity and the dispersion of the concentration distribution, using a second order perturbation expansion. In their model the authors assume a finite correlation length of the heterogeneities and use a GAUSSIAN correlation function. In a first step, we model the fractured medium as a heterogeneous porous medium with infinite correlation length and neglect single fractures. ZHAN & WHEATCRAFT (1996[4]) analyze the macrodispersivity tensor in fractal porous media using a non-integer exponent which consists of the HURST coefficient and the fractal dimension D. To avoid this non-integer exponent for numerical reasons we extend the study of DENTZ ET AL. (2000 I[2] & II[3
Samiulhaq; Ahmad, Sohail; Vieru, Dumitru; Khan, Ilyas; Shafie, Sharidan
2014-01-01
Magnetic field influence on unsteady free convection flow of a second grade fluid near an infinite vertical flat plate with ramped wall temperature embedded in a porous medium is studied. It has been observed that magnitude of velocity as well as skin friction in case of ramped temperature is quite less than the isothermal temperature. Some special cases namely: (i) second grade fluid in the absence of magnetic field and porous medium and (ii) Newtonian fluid in the presence of magnetic field and porous medium, performing the same motion are obtained. Finally, the influence of various parameters is graphically shown. PMID:24785147
Samiulhaq; Ahmad, Sohail; Vieru, Dumitru; Khan, Ilyas; Shafie, Sharidan
2014-01-01
Magnetic field influence on unsteady free convection flow of a second grade fluid near an infinite vertical flat plate with ramped wall temperature embedded in a porous medium is studied. It has been observed that magnitude of velocity as well as skin friction in case of ramped temperature is quite less than the isothermal temperature. Some special cases namely: (i) second grade fluid in the absence of magnetic field and porous medium and (ii) Newtonian fluid in the presence of magnetic field and porous medium, performing the same motion are obtained. Finally, the influence of various parameters is graphically shown.
Samiulhaq; Ahmad, Sohail; Vieru, Dumitru; Khan, Ilyas; Shafie, Sharidan
2014-01-01
Magnetic field influence on unsteady free convection flow of a second grade fluid near an infinite vertical flat plate with ramped wall temperature embedded in a porous medium is studied. It has been observed that magnitude of velocity as well as skin friction in case of ramped temperature is quite less than the isothermal temperature. Some special cases namely: (i) second grade fluid in the absence of magnetic field and porous medium and (ii) Newtonian fluid in the presence of magnetic field and porous medium, performing the same motion are obtained. Finally, the influence of various parameters is graphically shown. PMID:24785147
Thermal conductivity in porous media: Percolation-based effective-medium approximation
NASA Astrophysics Data System (ADS)
Ghanbarian, Behzad; Daigle, Hugh
2016-01-01
Knowledge of porosity and saturation-dependent thermal conductivities is necessary to investigate heat and water transfer in natural porous media such as rocks and soils. Thermal conductivity in a porous medium is affected by the complicated relationship between the topology and geometry of the pore space and the solid matrix. However, as water content increases from completely dry to fully saturated, the effect of the liquid phase on thermal conductivity may increase substantially. Although various methods have been proposed to model the porosity and saturation dependence of thermal conductivity, most are empirical or quasiphysical. In this study, we present a theoretical upscaling framework from percolation theory and the effective-medium approximation, which is called percolation-based effective-medium approximation (P-EMA). The proposed model predicts the thermal conductivity in porous media from endmember properties (e.g., air, solid matrix, and saturating fluid thermal conductivities), a scaling exponent, and a percolation threshold. In order to evaluate our porosity and saturation-dependent models, we compare our theory with 193 porosity-dependent thermal conductivity measurements and 25 saturation-dependent thermal conductivity data sets and find excellent match. We also find values for the scaling exponent different than the universal value of 2, in insulator-conductor systems, and also different from 0.76, the exponent in conductor-superconductor mixtures, in three dimensions. These results indicate that the thermal conductivity under fully and partially saturated conditions conforms to nonuniversal behavior. This means the value of the scaling exponent changes from medium to medium and depends not only on structural and geometrical properties of the medium but also characteristics (e.g., wetting or nonwetting) of the saturating fluid.
Thermal instability of a fluid-saturated porous medium bounded by thin fluid layers
Pillatsis, G.; Taslim, M.E.; Narusawa, U. )
1987-08-01
A linear stability analysis is performed for a horizontal Darcy porous layer of depth 2d{sub m} sandwiched between two fluid layers of depth d (each) with the top and bottom boundaries being dynamically free and kept at fixed temperatures. The Beavers-Joseph condition is employed as one of the interfacial boundary conditions between the fluid and the porous layer. The critical Rayleigh number and the horizontal wave number for the onset of convective motion depend on the following four dimensional parameters: {cflx d} (= d{sub m}/d, the depth ratio), {delta} (= {radical}K/d{sub m} with K being the permeability of the porous medium) {alpha} (the proportionality constant in the Beavers-Joseph condition), and k/k{sub m} (the thermal conductivity ratio). In order to analyze the effect of these parameters on the stability condition, a set of numerical solutions is obtained in terms of a convergent series for the respective layers, for the case in which the thickness of the porous layer is much greater than that of the fluid layer. A comparison of this study with the previously obtained exact solution for the case of constant heat flux boundaries is made to illustrate quantitative effects of the interfacial and the top/bottom boundaries on the thermal instability of a combined system of porous and fluid layers.
A numerical inversion of a the Laplace transform solution to radial dispersion in a porous medium.
Moench, A.F.; Ogata, A.
1981-01-01
A special form of the numerical inversion of the Laplace transform described by Stehfest (1970) is applied to the transformed solution of dispersion in a radial flow system in a porous medium. The inversion is extremely simple to use because the weighting coefficients depend only on the number of terms used in the computation and not upon the transform solution as required by most numerical inversion techniques.-from Authors
Dynamics of shear layers at the interface of a highly porous medium and a pure fluid
NASA Astrophysics Data System (ADS)
Antoniadis, P. D.; Papalexandris, M. V.
2015-01-01
In this paper, we report on shear flows in domains that contain a macroscopic interface between a highly porous medium and a pure fluid. Our study is based on the single-domain approach, according to which, the same set of governing equations is employed for both inside the porous medium and in the pure-fluid domain. In particular, we introduce a mathematical model for the flows of interest that is derived directly from a continuum theory for fluid-saturated granular materials. The resulting set of equations is a variation of the well-known unsteady Darcy-Brinkman model. First, we employ this model to perform a linear stability analysis of inviscid shear layers over a highly porous medium. Our analysis shows that such layers are unconditionally unstable. Next, we present results from numerical simulations of temporally evolving shear layers in both two and three dimensions. The simulations are performed via a recently designed algorithm that employs a predictor-corrector time-marching scheme and a projection method for the computation of the pressure field on a collocated grid. According to our numerical predictions, the onset of the Kelvin-Helmholtz instability leads to the formation of vortices that extend to both sides of the material interface, thus producing substantial recirculation inside the porous medium. These vortices eventually merge, leading to significant growth of the shear layer and, in three dimensional flows, transition to turbulence. The dynamics of the shear layers, including growth rate and self-similarity, is presented and analysed. Finally, the structure of these layers is described in detail and compared to the one of plain mixing layers.
NASA Astrophysics Data System (ADS)
Walker, R. C.; Hofstee, C.; Dane, J. H.; Hill, W. E.
1998-10-01
Although surfactant enhanced remediation of nonaqueous phase liquids (NAPLs) by pump-and-treat technology has been studied extensively in the laboratory with one-dimensional columns, very few multi-dimensional investigations have been reported. In this study we focus on the removal of perchloroethylene (PCE) from a two-dimensional, saturated porous medium containing a low permeability sand layer situated in an otherwise high permeability sand. A PCE spill was applied at the surface of the porous medium and allowed to redistribute until static equilibrium was achieved. The porous medium was then flushed with various surfactant and co-solvent formulations injected at the PCE source location and extracted at the bottom of the porous medium using a configuration similar to that of Abdul and Ang [Abdul, S.A., Ang, C.C., 1994. In situ surfactant washing of polychlorinated biphenyls and oils from a contaminated field site: Phase II. Pilot study. Ground Water 32, 727-734]. Effluent samples were analyzed for dissolved PCE concentrations. Volumetric water and PCE content values were determined at a number of locations by means of dual-energy gamma radiation measurements. Once surfactant flushing had started, PCE moved as a distinct separate phase ahead of the surfactant front. Most of this downward moving PCE accumulated on top of the low permeability sand layer. Some PCE, however, passed quickly through this layer and subsequently through the high permeability sand below it. Movement of some of the PCE into and through the low permeability sand layer was attributed to local heterogeneities combined with reduced interfacial tensions associated with the surfactant formulation. Clean-up of PCE in most of the high permeability sand was considered to be effective. PCE accumulated on top of the fine layer, however, posed a significant challenge to remediation and required several pumping configurations and surfactant/co-solvent formulations before most of it was removed.
Coupled consolidation of a porous medium with a cylindrical or a spherical cavity
NASA Astrophysics Data System (ADS)
Zhou, Y.; Rajapakse, R. K. N. D.; Graham, J.
1998-06-01
This paper presents a theoretical approach to analyse coupled, linear thermoporoelastic fields in a saturated porous medium under radial and spherical symmetry. The governing equations account for compressibility and thermal expansion of constituents, heat sink due to thermal dilatation of water and thermal expansion of the medium, and thermodynamically coupled heat-water flow. It has been reported in the literature that thermodynamically coupled heat-water flows known as thermo-osmosis and thermal filtration have the potential to significantly alter the flow fields in clay-rich barriers in the near field of a underground waste containment scheme. This study presents a mathematical model and examines the effects of thermo-osmosis and thermal-filtration on coupled consolidation fields in a porous medium with a cavity. Analytical solutions of the governing equations are presented in the Laplace transform space. A numerical inversion scheme is used to obtain the time-domain solutions for a cylindrical cavity in a homogeneous or a non-homogeneous medium. A closed form time-domain solution is presented for a spherical cavity in a homogeneous medium. Selected numerical solutions for homogeneous and non-homogeneous media show a significant increase in pore pressure and displacements due to the presence of thermodynamically coupled flows and a negligible influence on temperature.
Bleyer, J; Coussot, P
2014-06-01
We study the flow, through a model two-dimensional porous medium, of Newtonian fluids, power-law fluids, and viscoplastic fluids in the laminar regime and with moderate or dominant effects of the yielding term. A numerical technique able to take properly into account yielding effects in viscoplastic flows without any regularization is used to determine the detailed flow characteristics. We show that as soon as the distance between the disks forming the porous medium is sufficiently small, the velocity field and in particular the distribution function of the velocity of these different fluids in a wide range of flow regimes are similar. Moreover, the volume fraction of fluid at rest is negligible even at low flow rate. Thus the non-Newtonian character of a fluid flowing through such a complex geometry tends to be broken. We suggest that this is due to the fact that in a flow through a channel of rapidly varying cross section, the deformation, and thus the flow field, is imposed on the fluid, a situation that is encountered almost everywhere in a porous medium. These results make it possible to deduce a general expression for Darcy's law of these fluid types and estimate the parameters appearing in this expression.
NASA Astrophysics Data System (ADS)
Deng, Weina; Hu, Aiping; Chen, Xiaohua; Zhang, Shiying; Tang, Qunli; Liu, Zheng; Fan, Binbin; Xiao, Kuikui
2016-08-01
A rational 3D hierarchical porous nitrogen-doped aligned carbon nanotubes (HPNACNTs) with well-directed 1D conductive electron paths is designed as scaffold to load sulfur. The HPNACNTs have abundant micropores, mesopores and macropores with a relatively high specific surface area and a large total pore volume. The sulfur-HPNACNTs composite is synthesized for lithium-sulfur batteries by a melt-diffusion of sulfur powders into HPNACNTs scaffolds. Electrochemical tests reveal that the sulfur-HPNACNTs (68.8 wt% sulfur) composite exhibits a high initial discharge capacity of 1340 mAh g-1 at 0.1 C and retains as high as 979 mAh g-1 at 0.2 C after 200 cycles. More importantly, it shows high reversible capacity at high rates (817 mAh g-1 at 5 C). Its enhanced electrochemical performance can be attributed to the excellent electrical conductivity of aligned carbon nanotubes, the synergetic effect of its hierarchical porosity and the restraint of the shuttle effect due to the SxLi … N interactions via the N lone-pair electron.
Migration of Air Flow in Non-Fixed Saturated Porous Medium
NASA Astrophysics Data System (ADS)
Kong, X.; Fritz, S.; Kinzelbach, W.
2008-12-01
Two phase flow in porous media is of importance in a number of processes relevant in environmental engineering. The study of gas movement following injection into liquid saturated porous media is an active area of exploration for theoretical and practical reasons, e.g., in air-sparging, oil recovery, and bio-filter. A set of two-dimensional laboratory visualization experiments reveals a previously unrecognized gas-flow instability in a liquid-saturated porous medium packed by its own weight. The medium is made of crushed fused silica glass and saturated with a glycerine-water solution for refractive-index-matching. The interaction of the air flow injected at the bottom and the matrix (porous medium) structure leads to mobilization of the matrix and an instability, which causes the air channel to migrate. The instability of air-channel migration differs significantly from the gas-flow instability in a fixed matrix described in previous research. The migration of the air channel appears as a sequence of former channels collapsing and new channels opening. This process is characterized by the reorganization of the matrix, and the switching between channelized flow and pulsating slug flow. The channel migration comes to a stop after some time, leaving one thin and stable channel. The process is studied by calculating the cumulated lateral movement distance of channel and the lateral width of the area affected by the migration. A dimensionless number is defined to describe the migration. It is observed to be a function of grain size, height of bed, and air flow rate.
Xiu, Peng; Jia, Zhaojun; Lv, Jia; Yin, Chuan; Cheng, Yan; Zhang, Ke; Song, Chunli; Leng, Huijie; Zheng, Yufeng; Cai, Hong; Liu, Zhongjun
2016-07-20
3D printed porous titanium (Ti) holds enormous potential for load-bearing orthopedic applications. Although the 3D printing technique has good control over the macro-sturctures of porous Ti, the surface properties that affect tissue response are beyond its control, adding the need for tailored surface treatment to improve its osseointegration capacity. Here, the one step microarc oxidation (MAO) process was applied to a 3D printed porous Ti6Al4V (Ti64) scaffold to endow the scaffold with a homogeneous layer of microporous TiO2 and significant amounts of amorphous calcium-phosphate. Following the treatment, the porous Ti64 scaffolds exhibited a drastically improved apatite forming ability, cyto-compatibility, and alkaline phosphatase activity. In vivo test in a rabbit model showed that the bone in-growth at the untreated scaffold was in a pattern of distance osteogenesis by which bone formed only at the periphery of the scaffold. In contrast, the bone in-growth at the MAO-treated scaffold exhibited a pattern of contact osteogenesis by which bone formed in situ on the entire surface of the scaffold. This pattern of bone in-growth significantly increased bone formation both in and around the scaffold possibly through enhancement of bone formation and disruption of bone remodeling. Moreover, the implant surface of the MAO-treated scaffold interlocked with the bone tissues through the fabricated microporous topographies to generate a stronger bone/implant interface. The increased osteoinetegration strength was further proven by a push out test. MAO exhibits a high efficiency in the enhancement of osteointegration of porous Ti64 via optimizing the patterns of bone in-growth and bone/implant interlocking. Therefore, post-treatment of 3D printed porous Ti64 with MAO technology might open up several possibilities for the development of bioactive customized implants in orthopedic applications. PMID:27341499
Xiu, Peng; Jia, Zhaojun; Lv, Jia; Yin, Chuan; Cheng, Yan; Zhang, Ke; Song, Chunli; Leng, Huijie; Zheng, Yufeng; Cai, Hong; Liu, Zhongjun
2016-07-20
3D printed porous titanium (Ti) holds enormous potential for load-bearing orthopedic applications. Although the 3D printing technique has good control over the macro-sturctures of porous Ti, the surface properties that affect tissue response are beyond its control, adding the need for tailored surface treatment to improve its osseointegration capacity. Here, the one step microarc oxidation (MAO) process was applied to a 3D printed porous Ti6Al4V (Ti64) scaffold to endow the scaffold with a homogeneous layer of microporous TiO2 and significant amounts of amorphous calcium-phosphate. Following the treatment, the porous Ti64 scaffolds exhibited a drastically improved apatite forming ability, cyto-compatibility, and alkaline phosphatase activity. In vivo test in a rabbit model showed that the bone in-growth at the untreated scaffold was in a pattern of distance osteogenesis by which bone formed only at the periphery of the scaffold. In contrast, the bone in-growth at the MAO-treated scaffold exhibited a pattern of contact osteogenesis by which bone formed in situ on the entire surface of the scaffold. This pattern of bone in-growth significantly increased bone formation both in and around the scaffold possibly through enhancement of bone formation and disruption of bone remodeling. Moreover, the implant surface of the MAO-treated scaffold interlocked with the bone tissues through the fabricated microporous topographies to generate a stronger bone/implant interface. The increased osteoinetegration strength was further proven by a push out test. MAO exhibits a high efficiency in the enhancement of osteointegration of porous Ti64 via optimizing the patterns of bone in-growth and bone/implant interlocking. Therefore, post-treatment of 3D printed porous Ti64 with MAO technology might open up several possibilities for the development of bioactive customized implants in orthopedic applications.
Magneto-rotatory compressible couple-stress fluid heated from below in porous medium
NASA Astrophysics Data System (ADS)
Mehta, Chander Bhan
2016-03-01
The study is aimed at analysing thermal convection in a compressible couple stress fluid in a porous medium in the presence of rotation and magnetic field. After linearizing the relevant equations, the perturbation equations are analysed in terms of normal modes. A dispersion relation governing the effects of rotation, magnetic field, couple stress parameter and medium permeability have been examined. For a stationary convection, the rotation postpones the onset of convection in a couple stress fluid heated from below in a porous medium in the presence of a magnetic field. Whereas, the magnetic field and couple stress postpones and hastens the onset of convection in the presence of rotation and the medium permeability hastens and postpones the onset of convection with conditions on Taylor number. Further the oscillatory modes are introduced due to the presence of rotation and the magnetic field which were non-existent in their absence, and hence the principle of exchange stands valid. The sufficient conditions for nonexistence of over stability are also obtained.
Transport of bare and capped zinc oxide nanoparticles is dependent on porous medium composition.
Kurlanda-Witek, H; Ngwenya, B T; Butler, I B
2014-07-01
Zinc oxide (ZnO) nanoparticles are one of the most frequently used nanoparticles in industry and hence are likely to be introduced to the groundwater environment. The mobility of these nanoparticles in different aquifer materials has not been assessed. While some studies have been published on the transport of ZnO nanoparticles in individual porous media, these studies do not generally account for varying porous medium composition both within and between aquifers. As a first step towards understanding the impact of this variability, this paper compares the transport of bare ZnO nanoparticles (bZnO-NPs) and capped ZnO nanoparticles, coated with tri-aminopropyltriethoxysilane (cZnO-NPs), in saturated columns packed with glass beads, fine grained sand and fine grained calcite, at near-neutral pH and groundwater salinity levels. With the exception of cZnO-NPs in sand columns, ZnO nanoparticles are highly immobile in all three types of studied porous media, with most retention taking place near the column inlet. Results are in general agreement with DLVO theory, and the deviation in experiments with cZnO-NPs flowing through columns packed with sand is linked to variability in zeta potential of the capped nanoparticles and sand grains. Therefore, differences in surface charge of nanoparticles and porous media are demonstrated to be key drivers in nanoparticle transport.
Transport of bare and capped zinc oxide nanoparticles is dependent on porous medium composition
NASA Astrophysics Data System (ADS)
Kurlanda-Witek, H.; Ngwenya, B. T.; Butler, I. B.
2014-07-01
Zinc oxide (ZnO) nanoparticles are one of the most frequently used nanoparticles in industry and hence are likely to be introduced to the groundwater environment. The mobility of these nanoparticles in different aquifer materials has not been assessed. While some studies have been published on the transport of ZnO nanoparticles in individual porous media, these studies do not generally account for varying porous medium composition both within and between aquifers. As a first step towards understanding the impact of this variability, this paper compares the transport of bare ZnO nanoparticles (bZnO-NPs) and capped ZnO nanoparticles, coated with tri-aminopropyltriethoxysilane (cZnO-NPs), in saturated columns packed with glass beads, fine grained sand and fine grained calcite, at near-neutral pH and groundwater salinity levels. With the exception of cZnO-NPs in sand columns, ZnO nanoparticles are highly immobile in all three types of studied porous media, with most retention taking place near the column inlet. Results are in general agreement with DLVO theory, and the deviation in experiments with cZnO-NPs flowing through columns packed with sand is linked to variability in zeta potential of the capped nanoparticles and sand grains. Therefore, differences in surface charge of nanoparticles and porous media are demonstrated to be key drivers in nanoparticle transport.
Natural convection heat transfer of nanofluids along a vertical plate embedded in porous medium.
Uddin, Ziya; Harmand, Souad
2013-02-07
The unsteady natural convection heat transfer of nanofluid along a vertical plate embedded in porous medium is investigated. The Darcy-Forchheimer model is used to formulate the problem. Thermal conductivity and viscosity models based on a wide range of experimental data of nanofluids and incorporating the velocity-slip effect of the nanoparticle with respect to the base fluid, i.e., Brownian diffusion is used. The effective thermal conductivity of nanofluid in porous media is calculated using copper powder as porous media. The nonlinear governing equations are solved using an unconditionally stable implicit finite difference scheme. In this study, six different types of nanofluids have been compared with respect to the heat transfer enhancement, and the effects of particle concentration, particle size, temperature of the plate, and porosity of the medium on the heat transfer enhancement and skin friction coefficient have been studied in detail. It is found that heat transfer rate increases with the increase in particle concentration up to an optimal level, but on the further increase in particle concentration, the heat transfer rate decreases. For a particular value of particle concentration, small-sized particles enhance the heat transfer rates. On the other hand, skin friction coefficients always increase with the increase in particle concentration and decrease in nanoparticle size.
Sadovskii, V. M. Sadovskaya, O. V.
2015-10-28
Based on the generalized rheological method, the mathematical model describing small deformations of a single-phase porous medium without regard to the effects of a fluid or gas in pores is constructed. The change in resistance of a material to the external mechanical impacts at the moment of pore collapse is taken into account by means of the von Mises–Schleicher strength condition. In order to consider irreversible deformations, alongside with the classical yield conditions by von Mises and Tresca– Saint-Venant, the special condition modeling the plastic loss of stability of a porous skeleton is used. The random nature of the pore size distribution is taken into account. It is shown that the proposed mathematical model satisfies the principles of thermodynamics of irreversible processes. Phenomenological parameters of the model are determined on the basis of the approximate calculation of the problem on quasi-static loading of a cubic periodicity cell with spherical voids. In the framework of the obtained model, the process of propagation of plane longitudinal waves of the compression in a homogenous porous medium, accompanied by the plastic deformation of a skeleton and the collapse of pores, is analyzed.
NASA Astrophysics Data System (ADS)
Sadovskii, V. M.; Sadovskaya, O. V.
2015-10-01
Based on the generalized rheological method, the mathematical model describing small deformations of a single-phase porous medium without regard to the effects of a fluid or gas in pores is constructed. The change in resistance of a material to the external mechanical impacts at the moment of pore collapse is taken into account by means of the von Mises-Schleicher strength condition. In order to consider irreversible deformations, alongside with the classical yield conditions by von Mises and Tresca- Saint-Venant, the special condition modeling the plastic loss of stability of a porous skeleton is used. The random nature of the pore size distribution is taken into account. It is shown that the proposed mathematical model satisfies the principles of thermodynamics of irreversible processes. Phenomenological parameters of the model are determined on the basis of the approximate calculation of the problem on quasi-static loading of a cubic periodicity cell with spherical voids. In the framework of the obtained model, the process of propagation of plane longitudinal waves of the compression in a homogenous porous medium, accompanied by the plastic deformation of a skeleton and the collapse of pores, is analyzed.
MHD flow of Burger's fluid over an off-centered rotating disk in a porous medium
NASA Astrophysics Data System (ADS)
Khan, Najeeb Alam; Khan, Sidra; Ullah, Saif
2015-08-01
In this study, off-centered stagnation flow of three dimensional Burger's fluid over an infinite rotating disk in a porous medium with a uniform magnetic field, which is applying normal to the disk, is investigated. A uniform suction/injection is applied through the surface of the porous disk. The structure has been modeled in the form of ordinary differential equations, which are reduced from partial differential equations by using the similarity transformation. Analytical solution is obtained by non-perturbation technique of homotopy analysis method (HAM). The influence of non-dimensional parameters on velocity profile is presented in graphical form and the numerical comparison is made with the viscous fluid as a special case.
Hall effects on peristaltic flow of a Maxwell fluid in a porous medium
NASA Astrophysics Data System (ADS)
Hayat, T.; Ali, N.; Asghar, S.
2007-04-01
This work is concerned with the peristaltic transport of an incompressible, electrically conducting Maxwell fluid in a planar channel. The flow in the porous space is due to a sinusoidal wave traveling on the channel walls. The Hall effect is taken into account and permeability of porous medium is considered uniform. Modified Darcy's law has been used to model the governing equation. An analytical solution is obtained, which satisfies the momentum equation for the case in which the amplitude ratio is small. The present theoretical model may be considered as mathematical representation to the case of gall bladder and bile duct with stones and dynamics of blood flow in living creatures. Finally, the graphical results are reported and discussed for various values of the physical parameters of interest.
Li, Ching-Wen; Pan, Wei-Ting; Ju, Jyh-Cherng; Wang, Gou-Jen
2016-04-01
In this study, we have developed a microporous poly(lactic-co-glycolic acid) (PLGA) scaffold that combines a continuous release property and a three-dimensional (3D) scaffolding technique for the precise and efficient formation of endothelial cell lineage from embryonic stem cells (ESCs). Eight PLGA scaffolds (14.29%, 16.67%, 20% and 25% concentrations of PLGA solutions) mixed with two crystal sizes of sodium chloride (NaCl) were fabricated by leaching. Then, vascular endothelial cell conditioned medium (ECCM) mixed with gelatin was embedded into the scaffold for culturing of mouse embryonic stem cells (mESCs). The 14.29% PLGA scaffolds fabricated using non-ground NaCl particles (NG-PLGA) and the 25% PLGA containing scaffolds fabricated using ground NaCl particles (G-PLGA) possessed minimum and maximum moisture content and bovine serum albumin (BSA) content properties, respectively. These two groups of scaffolds were used for future experiments in this study. Cell culture results demonstrated that the proposed porous scaffolds without growth factors were sufficient to induce mouse ESCs to differentiate into endothelial-like cells in the early culture stages, and combined with embedded ECCM could provide a long-term inducing system for ESC differentiation. PMID:27068738
Brenner, Annette K; Frøystein, Nils Åge
2014-01-01
The backbone assignment of medium-sized proteins is rarely as straightforward as that of small proteins, and thus often requires creative solutions. Here, we describe the application of a combination of standard 3D heteronuclear methods with CC(CO)NH and a variety of MUltiplicity Selective In-phase Coherence transfer (MUSIC) experiments. Both CC(CO)NH and MUSIC are, in theory, very powerful methods for the backbone assignment of proteins. Due to low sensitivity, their use has usually been linked to small proteins only. However, we found that combining CC(CO)NH and MUSIC experiments simplified the assignment of two challenging medium-sized proteins of 13 and 19.5 kDa, respectively. These methods are to some extent complementary to each other: CC(CO)NH acquired with a long isotropic mixing time can identify amino acids with large aliphatic side chains. Whereas the most sensitive MUSIC experiments identify amino acid types that cannot be detected by CC(CO)NH, comprising the residues with acid and amide groups, and aromatic rings in their side chains. Together these methods provide a means of identifying the majority of peaks in the 2D 15N HSQC spectrum which simplifies the backbone assignment work even for proteins, e.g., small kinases, whose standard spectra resulted in little spectral resolution and low signal intensities.
Intracranial stents being modeled as a porous medium: flow simulation in stented cerebral aneurysms.
Augsburger, L; Reymond, P; Rufenacht, D A; Stergiopulos, N
2011-02-01
Intracranial aneurysms may be treated by flow diverters, alternatively to stents and coils combination. Numerical simulation allows the assessment of the complex nature of aneurismal flow. Endovascular devices present a rather dense and fine strut network, increasing the complexity of the meshing. We propose an alternative strategy, which is based on the modeling of the device as a porous medium. Two patient-specific aneurysm data sets were reconstructed using conventional clinical setups. The aneurysms selection was done so that intra-aneurismal flow was shear driven in one and inertia driven in the other. Stents and their porous medium analog were positioned at the aneurysm neck. Physiological flow and standard boundary conditions were applied. The comparison between both approaches was done by analyzing the velocity, vorticity, and shear rate magnitudes inside the aneurysm as well as the wall shear stress (WSS) at the aneurysm surface. Simulations without device were also computed. The average flow reduction reaches 76 and 41% for the shear and inertia driven flow models, respectively. When comparing the two approaches, results show a remarkable similarity in the flow patterns and magnitude. WSS, iso-velocity surfaces and velocity on a trans-sectional plane are in fairly good agreement. The root mean squared error on the investigated parameters reaches 20% for aneurysm velocity, 30.6% for aneurysm shear rate, and 47.4% for aneurysm vorticity. It reaches 20.6% for WSS computed on the aneurysm surface. The advantages of this approach reside in its facility to implement and in the gain in computational time. Results predicted by the porous medium approach compare well with the real stent geometry model and allow predicting the main effects of the device on intra-aneurismal flow, facilitating thus the analysis.
NASA Astrophysics Data System (ADS)
Amiaz, Yanai; Ronen, Zeev; Adar, Eilon; Weisbrod, Noam
2015-04-01
A chalk fractured aquitard beneath an industrial site is subjected to intense contamination due to percolation of contaminants from the different facilities operating at the site. In order to reduce further contamination, draining trenches were excavated and filled with coarse gravel (3-4 cm in diameter) forming a porous medium, to which the contaminated groundwater discharges from the fractures surrounding the trenches. This research is aimed at establishing a biodegrading process of high efficiency and performance within the draining trenches. The research includes both field and laboratory experiments. An experimental setup of five columns (50 cm length and 4.5 cm in diameter) was constructed under highly controlled conditions. Over the course of the experiments, the columns were filled with different particle sizes and placed in a temperature controlled chamber. Filtered groundwater (0.2 µm) from the site groundwater, enriched by a model contaminant carbofuran (CRF), was injected to the columns; as two of the columns were inoculated by CRF degrading microorganisms native in the site's groundwater, two columns were inoculated by CRF degrading bacteria from the external environment, and one column was used as a control. During the experiment, measurements were taken from different locations along each column. These include: (a) CRF concentration and (b) hydraulic pressure and solution viscosity (in order to obtain the changes in permeability). A tracer test using uranine was carried out in parallel, in order to obtain the changes in hydraulic parameters. Correlating CRF concentration variations to changes of hydraulic parameters enable the deduction due to the effect that biological activity (under different temperature regimes) has on the hydraulic properties of the porous medium and its effect on the process of contaminant groundwater bodies' remediation. Preliminary results suggest that although biodegradation occurs, microbial activity has minor effect on
Iontophoresis from a micropipet into a porous medium depends on the ζ-potential of the medium.
Guy, Yifat; Faraji, Amir H; Gavigan, Colleen A; Strein, Timothy G; Weber, Stephen G
2012-03-01
Iontophoresis uses electricity to deliver solutes into living tissue. Often, iontophoretic ejections from micropipets into brain tissue are confined to millisecond pulses for highly localized delivery, but longer pulses are common. As hippocampal tissue has a ζ-potential of approximately -22 mV, we hypothesized that, in the presence of the electric field resulting from the iontophoretic current, electroosmotic flow in the tissue would carry solutes considerably farther than diffusion alone. A steady state solution to this mass transport problem predicts a spherically symmetrical solute concentration profile with the characteristic distance of the profile depending on the ζ-potential of the medium, the current density at the tip, the tip size, and the solute electrophoretic mobility and diffusion coefficient. Of course, the ζ-potential of the tissue is defined by immobilized components of the extracellular matrix as well as cell-surface functional groups. As such, it cannot be changed at will. Therefore, the effect of the ζ-potential of the porous medium on ejections is examined using poly(acrylamide-co-acrylic acid) hydrogels with various magnitudes of ζ-potential, including that similar to hippocampal brain tissue. We demonstrated that nearly neutral fluorescent dextran (3 and 70 kD) solute penetration distance in the hydrogels and OHSCs depends on the magnitude of the applied current, solute properties, and, in the case of the hydrogels, the ζ-potential of the matrix. Steady state solute ejection profiles in gels and cultures of hippocampus can be predicted semiquantitatively.
Liekens, Anuschka; Denayer, Joeri; Desmet, Gert
2011-07-15
The difference in B-term diffusion between fully porous and porous-shell particles is investigated using the physically sound diffusion equations originating from the Effective Medium Theory (EMT). Experimental data of the B-term diffusion obtained via peak parking measurements on six different commercial particle types have been analyzed (3 porous and 3 non porous). All particles were investigated using the same experimental design and test analytes, over a very broad range of retention factor values. First, the B-term reducing effect of the solid core (inducing an additional obstruction compared to fully porous particles) has been quantified using the Hashin-Shtrikman expression, showing that the presence of a solid core can account for a reduction of about 11% when the core diameter makes up 63% of the total particle diameter (Halo and Poroshell-particles) and a reduction of 16% when the core diameter makes up 73% (Kinetex). Remaining differences can be attributed to differences in the microscopic structure of the meso-porous material (meso-pore diameter, internal porosity or relative void volume). The much lower B-term diffusion of Halo and Kinetex particles compared to the fully porous Acquity particles (some 20-40% difference, of which about 10-15% can be attributed to the presence of the solid core) can hence largely be attributed to the much smaller internal porosity and the smaller pore size of the meso-porous material making up the shell of these particles. PMID:21628063
Numerical solutions for steady thermal convection from a concentrated source in a porous medium
Hickox, C.E.; Watts, H.A.
1980-06-01
Solutions for the steady, axisymmetric velocity and temperature fields associated with a point source of thermal energy in a fluid-saturated porous medium are obtained numerically through use of similarity transformations. The two cases considered are those of a point source located on the lower, insulated boundary of a semi-infinite region and a point source embedded in an infinite region. Numerical results are presented from which complete descriptions of the velocity and temperature fields can be constructed for Rayleigh numbers ranging from 10/sup -3/ to 10/sup 2/.
Weak self-adjointness and conservation laws for a porous medium equation
NASA Astrophysics Data System (ADS)
Gandarias, M. L.
2012-06-01
The concepts of self-adjoint and quasi self-adjoint equations were introduced by Ibragimov (2006, 2007) [4,7]. In Ibragimov (2007) [6] a general theorem on conservation laws was proved. In Gandarias (2011) [3] we generalized the concept of self-adjoint and quasi self-adjoint equations by introducing the definition of weak self-adjoint equations. In this paper we find the subclasses of weak self-adjoint porous medium equations. By using the property of weak self-adjointness we construct some conservation laws associated with symmetries of the differential equation.
When Air is Injected into Mobile Liquid-saturated Porous Medium
NASA Astrophysics Data System (ADS)
Kong, X.-Z.; Kinzelbach, W.; Stauffer, F.
2009-04-01
The study of gas movement following injection into liquid saturated porous media is an active area of exploration for theoretical and practical reasons, e.g., in air-sparging, oil recovery, and bio-filter. Here, we report a set of two-dimensional laboratory visualization experiments by injecting air into a vertically placed granular medium. The medium is made of crushed fused silica glass and saturated with a glycerine-water solution for refractive-index-matching. We learn that: i) A previously unrecognized gas-flow instability was observed. The interaction of the injected air flow and the medium structure leads to mobilization of the medium and an instability, which causes the air channel to migrate. This instability is dominated by a dimensionless number α, which can be interpreted as a normalization of a critical velocity with a dipole velocity for saturated conditions. The channel migration appears as a sequence of previous channels collapsing and new channels opening. ii) The channel migration comes to a stop after some time, leaving one stable preferential channel for air flow. Furthermore, the grains' packing is compacted due to a rearrangement process. The compacted process is indicated by a set of tracing experiments. iii) Due to a mobilization of the granular medium, segregation on grain size occurs depending on a critical grain size, below which the coarser grains tend to accumulate at the downstream end of the preferred air pathway, and above which the finer grains tend to accumulate there.
DeAngelis, D.L.; Yeh, G.T.; Huff, D.D.
1984-10-01
This report documents a model, FRACPORT, that simulates the transport of a solute through a fractured porous matrix. The model should be useful in analyzing the possible transport of radionuclides from shallow-land burial sites in humid environments. The use of the model is restricted to transport through saturated zones. The report first discusses the general modeling approach used, which is based on the Integrated Compartmental Method. The basic equations of solute transport are then presented. The model, which assumes a known water velocity field, solves these equations on two different time scales; one related to rapid transport of solute along fractures and the other related to slower transport through the porous matrix. FRACPORT is validated by application to a simple example of fractured porous medium transport that has previously been analyzed by other methods. Then its utility is demonstrated in analyzing more complex cases of pulses of solute into a fractured matrix. The report serves as a user's guide to FRACPORT. A detailed description of data input, along with a listing of input for a sample problem, is provided. 16 references, 18 figures, 3 tables.
NASA Astrophysics Data System (ADS)
Ghanbarian, Behzad; Hunt, Allen G.; Skinner, Thomas E.; Ewing, Robert P.
2015-02-01
Accurate prediction of the saturation dependence of different modes of transport in porous media, such as those due to conductivity, air permeability, and diffusion, is of broad interest in engineering and natural resources management. Most current predictions use a "bundle of capillary tubes" concept, which, despite its widespread use, is a severely distorted idealization of natural porous media. In contrast, percolation theory provides a reliable and powerful means to model interconnectivity of disordered networks and porous materials. In this study, we invoke scaling concepts from percolation theory and effective medium theory to predict the saturation dependence of modes of transport — hydraulic and electrical conductivity, air permeability, and gas diffusion — in two disturbed soils. Universal scaling from percolation theory predicts the saturation dependence of air permeability and gas diffusion accurately, even when the percolation threshold for airflow is estimated from the porosity. We also find that the non-universal scaling obtained from the critical path analysis (CPA) of percolation theory can make excellent predictions of hydraulic and electrical conductivity under partially saturated conditions.
Flow of an aqueous foam through a two-dimensional porous medium: a pore scale investigation
NASA Astrophysics Data System (ADS)
Meheust, Y.; Jones, S. A.; Dollet, B.; Cox, S.; Cantat, I.
2012-12-01
Flowing foams are used in many engineering and technical applications. A well-known application is oil recovery. Another one is the remediation of polluted soil: the foam is injected into the ground in order to mobilize chemical species present in the medium. Apart from potential interesting physico-chemical and biochemical properties, foams have peculiar flow properties that might be of benefit to the application. We address here this physical aspect of the topic. As a precursor to the study of foam flow through a complex porous material, we first study the behavior of an aqueous two-dimensional foam flowing through a medium consisting of two parallel channels with different widths, at fixed medium porosity, that is, at fixed total combined width of the two channels. The flow velocity, and hence flux, in each channel is measured by analyzing images of the flowing foam. It is then compared to a theoretical model, the basic assumption of which is that the pressure drop along a channel is identical for both channels. This pressure drop both consists of (i) a dynamic pressure drop, which is controlled by bubble-wall friction and depends on the foam velocity in the channel, and (ii) a capillary pressure drop over the bubble films that emerge at the channel outlet, the latter pressure drop being controlled by the radius of curvature of the bubble film. Based on this assumption, the dependence of the ratio of the foam velocities in the two channels is inferred as a function of the channel width ratio. It compares well to the measurements and shows that the flow behavior is highly dependent on the foam structure within the narrowest of the two channels, especially when a "bamboo" structure is obtained. Consequently, the flux in a channel is found to have a more complicated relation to the channel width than expected for the flow of a standard Newtonian fluid in the same geometry. We provide a comparison to this reference configuration. We then study the flow of the same
The effect of critical pH on virus fate and transport in saturated porous medium.
Guan, Huade; Schulze-Makuch, Dirk; Schaffer, Steve; Pillai, Suresh D
2003-01-01
Several viral transport experiments were conducted in a model aquifer 1 m long, using bacteriophages MS2 and phiX174 at various pH (4.6 to 8.3) conditions, to increase our understanding of virus behavior in ground water. The results indicate the existence of a critical pH at which the virus behavior changes abruptly. This is supported by data from field and batch experiments. The critical pH is determined to be 0.5 unit below the highest isoelectric point of the virus and porous medium. When water pH is below the critical pH, the virus has an opposite charge to at least one component of the porous medium, and is almost completely and irreversibly removed from the water. This suggests that electrostatic attraction at a subcritical water pH condition is an important factor controlling virus attenuation in ground water. The concept of critical pH can assist in the design of geologic barriers for preventing viral contamination in ground water.
Green, R.T.; Manteufel, R.D.; Dodge, F.T.; Svedeman, S.J.
1993-07-01
The performance of a geologic repository for high-level nuclear waste will be influenced to a large degree by thermohydrologic phenomena created by the emplacement of heat-generating radioactive waste. The importance of these phenomena is manifest in that they can greatly affect the movement of moisture and the resulting transport of radionuclides from the repository. Thus, these phenomena must be well understood prior to a definitive assessment of a potential repository site. An investigation has been undertaken along three separate avenues of analysis: (i) laboratory experiments, (ii) mathematical models, and (iii) similitude analysis. A summary of accomplishments to date is as follows. (1) A review of the literature on the theory of heat and mass transfer in partially saturated porous medium. (2) A development of the governing conservation and constitutive equations. (3) A development of a dimensionless form of the governing equations. (4) A numerical study of the importance and sensitivity of flow to a set of dimensionless groups. (5) A survey and evaluation of experimental measurement techniques. (6) Execution of laboratory experiments of nonisothermal flow in a porous medium with a simulated fracture.
Laboratory investigations of the physics of steam flow in a porous medium
Herkelrath, W.N.; Moench, A.F.
1982-01-01
Experiments were carried out in the laboratory to test a theory of transient flow of pure steam in a uniform porous medium. This theory is used extensively in modeling pressure-transient behavior in vapor-dominated geothermal systems. Transient, superheated steam-flow experiments were run by bringing a cylinder of porous material to a uniform initial pressure, and then making a step increase in pressure at one end of the sample, while monitoring the pressure-transient breakthrough at the other end. It was found in experiments run at 100?, 125?, and 146?C that the time required for steam-pressure transients to propagate through an unconsolidated material containing sand, silt, and clay was 10 to 25 times longer than predicted by theory. It is hypothesized that the delay in the steam-pressure transient was caused by adsorption of steam in the porous sample. In order to account for steam adsorption, a sink term was included in the conservation of mass equation. In addition, energy transfer in the system has to be considered because latent heat is released when steam adsorption occurs, increasing the sample temperature by as much as 10?C. Finally, it was recognized that the steam pressure was a function of both the temperature and the amount of adsorption in the sample. For simplicity, this function was assumed to be in equilibrium adsorption isotherm, which was determined by experiment. By solving the modified mass and energy equations numerically, subject to the empirical adsorption isotherm relationship, excellent theoretical simulation of the experiments was achieved. The experiments support the hypothesis that adsorption of steam can strongly influence steam pressure-transient behavior in porous media; the results suggest that the modified steam-flow theory, which includes steam adsorption terms, should be used in modeling steam flow in vapor-dominated geothermal systems.
Two-dimensional network simulation of diffusion driven coarsening of foam inside a porous medium
Cohen, D.; Patzek, T.W.; Radke, C.J.
1996-04-01
In order to use foams in subsurface applications, it is necessary to understand their stability in porous media. Diffusion driven coarsening of a stationary or nonflowing foam in a porous medium results in changing gas pressures and a coarsening of the foam texture. A two-dimensional network simulation has been created that predicts the behavior of foam in a porous medium by physically specifying the locations of all the lamellae in the system and by solving the complete set of Young-Laplace and diffusion equations. An hourglass approximates the shape of the pores, and the pore walls are considered to be highly water wet. A singularity arises in the system of differential algebraic equations due to the curvature of the pore walls. This singularity is a signal that the system must undergo oscillations or sudden lamellar rearrangements before the diffusion process can continue. Newton-Raphson iteration is used along with Keller`s method of arc-length continuation and a new jump resolution technique to locate and resolve bifurcations in the system of coupled lamellae. Gas bubbles in pore throats are regions of encapsulated pressure. As gas is released from these bubbles during diffusion, the pressure of the bubbles in the pore bodies increases. When the pressure increase is scaled by the characteristic Young-Laplace pressure, the equilibrium time for the diffusion process is scaled by the ratio of the square of the characteristic length to the gas diffusivity and two dimensionless groups. One describes the ease with which gas can diffuse through a lamella, the second represents the amount of gas encapsulated within the pore throats initially. Given this scaling, the resulting plots of pressure versus time and normalized lamellae positions versus time are universal for all system sizes and characteristics. This is true as long as the initial lamella distribution is the same in each case.
NASA Astrophysics Data System (ADS)
Tsiberkin, K. B.
2016-08-01
The structure of a homogeneous liquid flow at the interface with a porous medium saturated with the same liquid has been studied in the boundary layer approximation. The porous medium is described by the Brinkman model. Self-similar equations of motion in the form of Blasius equation have been found, and their numerical solutions have been presented. An expression for the force exerted by the flow on the porous medium is derived.
Instability of uniform gas flow within liquid-saturated porous medium
NASA Astrophysics Data System (ADS)
Tsiberkin, Kirill
2014-05-01
Problem of flow instability in porous media are important for applied fields like mining, water supply, etc. There is a fundamental interest to mechanisms are influence on flow too. E.g., a viscous fingering is typical phenomenon of displacement processes in porous medium [1,2]. The instability of gas flow in liquid-saturated domain have no wide studies but it can make significant influence on heat and mass transport. If the one phase have a high saturation, the other phase will form the droplets are break and captured within pores due to the capillary forces [2-4]. It is possible to neglect the capillarity if the saturation of both fluids exceed a percolation thresholds [5,6]. We consider an infinite flat layer of uniform porous medium is saturated with gas and liquid have close saturation. Its upper boundary is impermeable for liquid phase and gas can pass freely through the border, and the down boundary is permeable for both phases. The temperature and pressure are fixed at the top while their gradients are fixed at the bottom side. Neglecting the capillarity, gas solubility, liquid evaporation and any phase transitions, we obtain a steady solution and study its' stability. The governing parameter of the flow is α = αgAPe, αg = (ρwCg )/(ρsCs), A = ρstatvstat (1) where Pe is the thermal Peclet number determines a ratio between convective and conductive heat transfer, αg is ratio of thermal capacities of fluid and matrix, and A is determined by gas density and velocity in the steady state. Analyzing the perturbations, we found that a long-wave instability realizes in the system. The critical value of parameter is: αc = a1 + k2a2 + O(ρg/ρw), (2) where a1,a2 are positive coefficients are calculated using thermal perturbations combinations and k is wave number along horizontal direction. The minimal αc equals 2.47, and it correspond the critical Peclet number near 200 in the methane-water system. An error of the dependence is of order of gas to water
Velocity and stress jump conditions between a porous medium and a fluid
NASA Astrophysics Data System (ADS)
Valdés-Parada, Francisco J.; Aguilar-Madera, Carlos G.; Ochoa-Tapia, J. Alberto; Goyeau, Benoît
2013-12-01
Modeling transport phenomena in hierarchical systems can be carried out by either a one domain approach or a two domain approach. The first one involves assuming the system as a pseudo-continuum and is expressed in terms of position-dependent effective medium coefficients. In the two domain approach, the differential equations have position-independent coefficients but require accounting for the corresponding boundary conditions that couple the equations between each homogeneous region. For momentum transport between a porous medium and a fluid, stress boundary conditions have been derived in terms of a jump coefficient that needs to be predicted within a two-domain approach formulation. However, continuity of the velocity is postulated at the dividing surface. In this work, we propose a methodology for the derivation of boundary conditions for both the velocity and the stress. These conditions are expressed in terms of jump coefficients that are computed from the solution of an ancillary macroscopic closure problem. This problem accounts for the deviations from the one and two domain approaches. From the closure problem solution we were also able to determine the position at which the jump conditions should be applied, i.e., the dividing surface position. In addition, we used this methodology adopting the assumptions proposed by Ochoa-Tapia and Whitaker as well as those by Beavers and Joseph. We found that any version of the two domain approach was in agreement with the one domain approach in the bulk of the porous medium and the fluid. However, the same is not true for the process of capturing the essential information of the inter-region.
The flow of a foam in a two-dimensional porous medium
NASA Astrophysics Data System (ADS)
Géraud, Baudouin; Jones, Siân. A.; Cantat, Isabelle; Dollet, Benjamin; Méheust, Yves
2016-02-01
Foams have been used for decades as displacing fluids for enhanced oil recovery and aquifer remediation, and more recently, for remediation of the vadose zone, in which case foams carry chemical amendments. Foams are better injection fluids than aqueous solutions due to their low sensitivity to gravity and because they are less sensitive to permeability heterogeneities, thus allowing a more uniform sweep. The latter aspect results from their peculiar rheology, whose understanding motivates the present study. We investigate foam flow through a two-dimensional porous medium consisting of circular obstacles positioned randomly in a horizontal transparent Hele-Shaw cell. The local foam structure is recorded in situ, which provides a measure of the spatial distribution of bubble velocities and sizes at regular time intervals. The flow exhibits a rich phenomenology including preferential flow paths and local flow nonstationarity (intermittency) despite the imposed permanent global flow rate. Moreover, the medium selects the bubble size distribution through lamella division-triggered bubble fragmentation. Varying the mean bubble size of the injected foam, its water content, and mean velocity, we characterize those processes systematically. In particular, we measure the spatial evolution of the distribution of bubble areas, and infer the efficiency of bubble fragmentation depending on the various control parameters. We furthermore show that the distributions of bubble sizes and velocities are correlated. This study sheds new light on the local rheology of foams in porous media and opens the way toward quantitative characterization of the relationship between medium geometry and foam flow properties. It also suggests that large-scale models of foam flows in the subsurface should account for the correlation between bubble sizes and velocities.
NASA Astrophysics Data System (ADS)
Sadovskaya, O. V.; Sadovskii, V. M.
2015-10-01
The parallel computational algorithm for analysis of the processes of elastic-plastic deformation of a porous medium under the action of external dynamic loads is developed. This algorithm is based on the mathematical model taking into account threshold nature of change in the strength of a material under the collapse of pores. The algorithm is implemented in Fortran by means of functions of the MPI library. The parallel program system has been tested on clusters in computations of the propagation of plane longitudinal shock waves of the compression and in computations of the expansion of a cylindrical cavity in an infinite porous medium. The comparison of numerical results and exact solutions has shown their good qualitative and quantitative correspondence. Using the obtained algorithm, the process of propagation of elastic-plastic waves of the compression in a homogenous porous medium, accompanied by the deformation of a skeleton and the collapse of pores, is analyzed.
NASA Astrophysics Data System (ADS)
Chen, Xingxin; Cai, Qipeng; Ding, Jianwen; Guo, Liqun
2016-02-01
identified that could explain the rate change: (1) only particles deposited in the porous medium by fouling mechanisms could be released by ultrasound stimulations at power levels below a certain critical value, or (2) ultrasound stimulations at power levels above a certain critical value are sufficient to change the structure of the porous medium, producing more dead-end pore openings that allow particle flow through the porous medium. The results presented are unique in indicating that successive particle release can be induced using increasing ultrasound stimulation.
NASA Astrophysics Data System (ADS)
Degan, Gérard; Sanya, Arthur; Akowanou, Christian
2016-10-01
This work analytically investigates the problem of steady film condensation along a vertical surface embedded in an anisotropic porous medium filled with a dry saturated vapor. The porous medium is anisotropic in permeability whose principal axes are oriented in a direction which is oblique to the gravity vector. On the basis of the generalized Darcy's law and within the boundary layer approximations, similar solutions have been obtained for the temperature and flow patterns in the condensate. Moreover, closed form solutions for the boundary layer thickness and heat transfer rate have been obtained in terms of the governing parameters of the problem.
Modeling the Effect of Fluid Flow on a Growing Network of Fractures in a Porous Medium
NASA Astrophysics Data System (ADS)
Alhashim, Mohammed; Koch, Donald
2015-11-01
The injection of a viscous fluid at high pressure in a geological formation induces the fracturing of pre-existing joints. Assuming a constant solid-matrix stress field, a weak joint saturated with fluid is fractured when the fluid pressure exceeds a critical value that depends on the joint's orientation. In this work, the formation of a network of fractures in a porous medium is modeled. When the average length of the fractures is much smaller than the radius of a cluster of fractured joints, the fluid flow within the network can be described as Darcy flow in a permeable medium consisting of the fracture network. The permeability and porosity of the medium are functions of the number density of activated joints and consequently depend on the fluid pressure. We demonstrate conditions under which these relationships can be derived from percolation theory. Fluid may also be lost from the fracture network by flowing into the permeable rock matrix. The solution of the model shows that the cluster radius grows as a power law with time in two regimes: (1) an intermediate time regime when the network contains many fractures but fluid loss is negligible; and (2) a long time regime when fluid loss dominates. In both regimes, the power law exponent depends on the Euclidean dimension and the injection rate dependence on time.
Modeling tree water flow as an unsaturated flow through a porous medium.
Aumann, Craig A; Ford, E David
2002-12-21
The electric circuit analogy has had a profound influence on how tree physiologists measure, model and think about tree water flow. For example, previous models that attempt to account for changes in saturation use the electric circuit analogy to define capacitance as the change in saturation per change in pressure. Given that capacitance is constant, this relationship implies that subjecting a block of wood to a pressure of -2.5 MPa for 2 min results in the same change in saturation as subjecting the same block to the same pressure for 2 days. Given the definition of capacitance, it is unclear how the electric circuit analogy could be used to predict changes in saturation separately from changes in pressure. The inadequacies in the electric circuit analogy discussed in this paper necessitate a new theory of tree water flow that recognizes the sapwood as being a porous medium and explicitly deals with the full implications of the unsaturated flow occurring in the sapwood. The theory proposed in this paper combines the Cohesion theory with a mathematical theory of multiphase flow through porous media. Based on this theory, both saturated and unsaturated tree water flow models are presented. Previous partial differential equation models of tree water flow based on the electric circuit analogy are shown to be mathematically equivalent to the model of saturated porous flow. The unsaturated model of tree water flow explicitly models the pressure profile and the rates of change in saturation and specific interfacial area (a measure of how the water in the unsaturated sapwood is partitioned between mobile and immobile components). The unsaturated model highlights the differences between saturated and unsaturated flow and the need to measure the variables governing tree water flow at higher spatial and temporal resolutions. PMID:12425977
Variation in Hydraulic Conductivity with Decreasing pH in a Biologically-Clogged Porous Medium
NASA Astrophysics Data System (ADS)
Kirk, M. F.; Santillan, E.; McGrath, L. K.; Altman, S. J.
2011-12-01
Biological clogging can significantly lower the hydraulic conductivity of porous media, potentially helping to limit CO2 transport from geological carbon storage reservoirs. How clogging is affected by CO2 injection, however, is unclear. We used column experiments to examine how decreasing pH, a geochemical change associated with CO2 injection, will affect the hydraulic conductivity (K) of biologically clogged porous medium. Four biologically-active experiments and two control experiments were performed. Columns consisted of 1 mm2 capillary tubes filled with 105-150 μm diameter glass beads. Artificial groundwater medium containing 1 mM glucose was pumped through the columns at a rate of 0.015 mL/min (q = 21.6 m/day; Re = 0.045). Each column was inoculated with 10^8 CFU of Pseudomonas fluorescens tagged with a green fluorescent protein; cells introduced to control columns were heat sterilized. Biomass distribution and transport was monitored using scanning laser confocal microscopy and effluent plating. Growth was allowed to occur for 5 days in medium with pH 7 in the biologically active columns. During that time, K decreased to values ranging from 10 to 27% of the average control K and effluent cell levels increased to about 10^8 CFU/mL. Next, the pH of the inflowing medium was lowered to 4 in three experiments and 5.5 in one experiment. After pH 4 medium was introduced, K increased to values ranging from 21 to 64% of the average control K and culturable cell levels in the effluent fell by about 4 log units. Confocal images show that clogging persisted in the columns at pH 4 because most of the microbial biomass remained attached to bead surfaces. In the experiment where pH was lowered to 5.5, K changed little because biological clogging remained entirely intact. The concentration of culturable cells in the effluent was also invariant. These results suggest that biomass in porous medium will largely remain in place following exposure to acidic water in a CO2
Oostrom, Martinus; Wietsma, Thomas W.; Strickland, Christopher E.; Freedman, Vicky L.; Truex, Michael J.
2012-02-01
Soil desiccation, in conjunction with surface infiltration control, is considered at the Hanford Site as a potential technology to limit the flux of technetium and other contaminants in the vadose zone to the groundwater. An intermediate-scale experiment was conducted to test the response of a series of instruments to desiccation and subsequent rewetting of porous media. The instruments include thermistors, thermocouple psychrometers, dual-probe heat pulse sensors, heat dissipation units, and humidity probes. The experiment was simulated with the multifluid flow simulator STOMP, using independently obtained hydraulic and thermal porous medium properties. All instrument types used for this experiment were able to indicate when the desiccation front passed a certain location. In most cases the changes were sharp, indicating rapid changes in moisture content, water potential, or humidity. However, a response to the changing conditions was recorded only when the drying front was very close to a sensor. Of the tested instruments, only the heat dissipation unit and humidity probes were able to detect rewetting. The numerical simulation results reasonably match the experimental data, indicating that the simulator captures the pertinent gas flow and transport processes related to desiccation and rewetting and may be useful in the design and analysis of field tests.
Film Flow Dominated Simultaneous Flow of Two Viscous Incompressible Fluids Through a Porous Medium
NASA Astrophysics Data System (ADS)
Aursjø, Olav; Erpelding, Marion; Tallakstad, Ken; Flekkøy, Eirik; Hansen, Alex; Måløy, Knut Jørgen
2014-11-01
We present an experimental study of two-phase flow in a quasi-two-dimensional porous medium. The two phases, a water-glycerol solution and a commercial food grade rapeseed/canola oil, having an oil to water-glycerol viscosity ratio of 1.3, are injected simultaneously into a Hele-Shaw cell with a mono-layer of randomly distributed glass beads. The two liquids are injected into the model from alternating point inlets. Initially, the porous model is filled with the water-glycerol solution. We observe that after an initial transient state, an overall static cluster configuration is obtained. While the oil is found to create a connected system spanning cluster, a large part of the water-glycerol clusters left behind the initial invasion front is observed to remain immobile throughout the rest of the experiment. This could suggest that the water-glycerol flow-dynamics is largely dominated by film flow. The flow pathways are thus given through the dynamics of the initial invasion. This behavior is quite different from that observed in systems with large viscosity differences between the two fluids, and where compressibility plays an important part of the process.
A one-domain approach for modeling and simulation of free fluid over a porous medium
NASA Astrophysics Data System (ADS)
Chen, Huangxin; Wang, Xiao-Ping
2014-02-01
We propose a one-domain approach based on the Brinkman model for the modeling and simulation of the transport phenomenon between free fluid and a porous medium. A thin transition layer is introduced between the free fluid region and the porous media region, across which the porosity and permeability undergo a rapid but continuous change. We study the behavior of the solution to the one-domain model analytically and numerically. Using the method of matched asymptotic expansion, we recover the Beavers-Joseph-Saffman (BJS) interface condition as the thickness of the transition layer goes to zero. We also calculate the error estimates between the leading order solution of the one-domain model and the standard Darcy-Stokes model of two-domain model with BJS condition. Numerical methods are developed for both the one-domain model and the two-domain model. Numerical results are presented to support the analytical results, thereby justifying the one-domain model as a good approximation to the two domain Stokes-Darcy model.
BISQ model based on a Kelvin-Voigt viscoelastic frame in a partially saturated porous medium
NASA Astrophysics Data System (ADS)
Nie, Jian-Xin; Ba, Jing; Yang, Ding-Hui; Yan, Xin-Fei; Yuan, Zhen-Yu; Qiao, Hai-Peng
2012-06-01
Taking into account three important porous media mechanisms during wave propagation (the Biot-flow, squirt-flow, and solid-skeleton viscoelastic mechanisms), we introduce water saturation into the dynamic governing equations of wave propagation by analyzing the effective medium theory and then providing a viscoelastic Biot/squirt (BISQ) model which can analyze the wave propagation problems in a partially viscous pore fluid saturated porous media. In this model, the effects of pore fluid distribution patterns on the effective bulk modulus at different frequencies are considered. Then we derive the wave dynamic equations in the time-space domain. The phase velocity and the attenuation coefficient equations of the viscoelatic BISQ model in the frequency-wavenumber domain are deduced through a set of plane harmonic solution assumptions. Finally, by means of numerical simulations, we investigate the effects of water saturation, permeability, and frequency on compressional wave velocity and attenuation. Based on tight sandstone and carbonate experimental observed data, the compressional wave velocities of partially saturated reservoir rocks are calculated. The compressional wave velocity in carbonate reservoirs is more sensitive to gas saturation than in sandstone reservoirs.
Modeling spatial competition for light in plant populations with the porous medium equation.
Beyer, Robert; Etard, Octave; Cournède, Paul-Henry; Laurent-Gengoux, Pascal
2015-02-01
We consider a plant's local leaf area index as a spatially continuous variable, subject to particular reaction-diffusion dynamics of allocation, senescence and spatial propagation. The latter notably incorporates the plant's tendency to form new leaves in bright rather than shaded locations. Applying a generalized Beer-Lambert law allows to link existing foliage to production dynamics. The approach allows for inter-individual variability and competition for light while maintaining robustness-a key weakness of comparable existing models. The analysis of the single plant case leads to a significant simplification of the system's key equation when transforming it into the well studied porous medium equation. Confronting the theoretical model to experimental data of sugar beet populations, differing in configuration density, demonstrates its accuracy. PMID:24623311
Fractional Cahn-Hilliard, Allen-Cahn and porous medium equations
NASA Astrophysics Data System (ADS)
Akagi, Goro; Schimperna, Giulio; Segatti, Antonio
2016-09-01
We introduce a fractional variant of the Cahn-Hilliard equation settled in a bounded domain Ω ⊂RN and complemented with homogeneous Dirichlet boundary conditions of solid type (i.e., imposed in the whole of RN ∖ Ω). After setting a proper functional framework, we prove existence and uniqueness of weak solutions to the related initial-boundary value problem. Then, we investigate some significant singular limits obtained as the order of either of the fractional Laplacians appearing in the equation is let tend to 0. In particular, we can rigorously prove that the fractional Allen-Cahn, fractional porous medium, and fractional fast-diffusion equations can be obtained in the limit. Finally, in the last part of the paper, we discuss existence and qualitative properties of stationary solutions of our problem and of its singular limits.
Qayyum, Mubashir; Khan, Hamid; Rahim, M. Tariq; Ullah, Inayat
2015-01-01
The aim of this article is to model and analyze an unsteady axisymmetric flow of non-conducting, Newtonian fluid squeezed between two circular plates passing through porous medium channel with slip boundary condition. A single fourth order nonlinear ordinary differential equation is obtained using similarity transformation. The resulting boundary value problem is solved using Homotopy Perturbation Method (HPM) and fourth order Explicit Runge Kutta Method (RK4). Convergence of HPM solution is verified by obtaining various order approximate solutions along with absolute residuals. Validity of HPM solution is confirmed by comparing analytical and numerical solutions. Furthermore, the effects of various dimensionless parameters on the longitudinal and normal velocity profiles are studied graphically. PMID:25738864
Natural convection on a vertical plate in a saturated porous medium with internal heat generation
NASA Astrophysics Data System (ADS)
Guedda, M.; Sriti, M.; Achemlal, D.
2014-08-01
The main goal of this paper is to re-exam a class of exact solutions for the two-dimensional free convection boundary layers induced by a heated vertical plate embedded in a saturated porous medium with an exponential decaying heat generation. The temperature distribution of the plate has been assumed to vary as a power of the axial coordinate measured from the leading edge of the plate and subjected to an applied lateral mass flux. The boundary layer equations are solved analytically and numerically using a fifth-order Runge-Kutta scheme coupled with the shooting iteration method. As for the classical problem without internal heat generation, it is proved that multiple (unbounded) solutions arise for any and for any suction/injection parameter. For such solutions, the asymptotic behavior as the similarity variable approaches infinity is determined.
A numerical model of controlled bioinduced mineralization in a porous medium to prevent corrosion
NASA Astrophysics Data System (ADS)
Afanasyev, Michael; van Paassen, Leon; Heimovaara, Timo
2013-04-01
This paper presents a numerical model of controlled bioinduced mineralization in a porous medium as a possible corrosion protection mechanism. Corrosion is a significant economic problem - recent reports evaluate the annual cost of metal corrosion as 3-4% of the gross domestic product (GDP), in both developed and developing countries. Corrosion control methods currently used are costly and unsustainable as they require the use of larger volumes of materials, hazardous chemicals and regular inspections. As an alternative corrosion control method, bioinduced deposition of protective mineral layers has been proposed. Bioinduced precipitation of calcite has already been investigated for CO2 geological sequestration and soil improvement. To our knowledge, though, no numerical study of biomineralization for corrosion protection has been described yet. Our model includes three phases - solid, biofilm and mobile water. In the latter the reactive elements are dissolved, which are involved in the precipitation and the biofilm growth. The equations that describe the pore water flow, chemical reactions in the mobile water, consumption of substrate and expulsion of metabolic products by the biofilm are briefly presented. Also, the changes in porosity and permeability of the porous medium through biofilm growth and solids precipitation are included. Our main assumptions are that the biofilm is uniform, has a constant density and composition, that all chemical reactions except for substrate consumption occur in the mobile water, and that the precipitates are uniformly distributed on the surface of the solids. We validate the model with simple analytical solutions and against experimental data. The metabolism of the micro-organisms introduces changes in the physical and chemical characteristics of the environment, such as concentrations of chemicals and pH levels. As an extension to the model, we couple these changes to the rates of biofilm growth and precipitation rates. The
A Newton-Krylov solution to the porous medium equations in the agree code
Ward, A. M.; Seker, V.; Xu, Y.; Downar, T. J.
2012-07-01
In order to improve the convergence of the AGREE code for porous medium, a Newton-Krylov solver was developed for steady state problems. The current three-equation system was expanded and then coupled using Newton's Method. Theoretical behavior predicts second order convergence, while actual behavior was highly nonlinear. The discontinuous derivatives found in both closure and empirical relationships prevented true second order convergence. Agreement between the current solution and new Exact Newton solution was well below the convergence criteria. While convergence time did not dramatically decrease, the required number of outer iterations was reduced by approximately an order of magnitude. GMRES was also used to solve problem, where ILU without fill-in was used to precondition the iterative solver, and the performance was slightly slower than the direct solution. (authors)
Modeling spatial competition for light in plant populations with the porous medium equation.
Beyer, Robert; Etard, Octave; Cournède, Paul-Henry; Laurent-Gengoux, Pascal
2015-02-01
We consider a plant's local leaf area index as a spatially continuous variable, subject to particular reaction-diffusion dynamics of allocation, senescence and spatial propagation. The latter notably incorporates the plant's tendency to form new leaves in bright rather than shaded locations. Applying a generalized Beer-Lambert law allows to link existing foliage to production dynamics. The approach allows for inter-individual variability and competition for light while maintaining robustness-a key weakness of comparable existing models. The analysis of the single plant case leads to a significant simplification of the system's key equation when transforming it into the well studied porous medium equation. Confronting the theoretical model to experimental data of sugar beet populations, differing in configuration density, demonstrates its accuracy.
Darcy Flow in a Wavy Channel Filled with a Porous Medium
Gray, Donald D; Ogretim, Egemen; Bromhal, Grant S
2013-05-17
Flow in channels bounded by wavy or corrugated walls is of interest in both technological and geological contexts. This paper presents an analytical solution for the steady Darcy flow of an incompressible fluid through a homogeneous, isotropic porous medium filling a channel bounded by symmetric wavy walls. This packed channel may represent an idealized packed fracture, a situation which is of interest as a potential pathway for the leakage of carbon dioxide from a geological sequestration site. The channel walls change from parallel planes, to small amplitude sine waves, to large amplitude nonsinusoidal waves as certain parameters are increased. The direction of gravity is arbitrary. A plot of piezometric head against distance in the direction of mean flow changes from a straight line for parallel planes to a series of steeply sloping sections in the reaches of small aperture alternating with nearly constant sections in the large aperture bulges. Expressions are given for the stream function, specific discharge, piezometric head, and pressure.
Breaking of non-Newtonian character in flows through a porous medium.
Chevalier, T; Rodts, S; Chateau, X; Chevalier, C; Coussot, P
2014-02-01
From NMR measurements we show that the velocity field of a yield stress fluid flowing through a disordered well-connected porous medium is very close to that for a Newtonian fluid. In particular, it is shown that no arrested regions exist even at very low velocities, for which the solid regime is expected to be dominant. This suggests that these results obtained for strongly nonlinear fluid can be extrapolated to any nonlinear fluid. We deduce a generalized form of Darcy's law for such materials and provide insight into the physical origin of the coefficients involved in this expression, which are shown to be moments of the second invariant of the strain rate tensor.
Radiation Effect On Three Dimensional Vertical Channel Flow Through Porous Medium
NASA Astrophysics Data System (ADS)
Guria, M.
2015-12-01
The flow of a viscous incompressible fluid through a vertical channel in the presence of radiation immersed in a porous medium has been studied. Approximate solutions have been obtained for the velocity and temperature fields, shear stresses and rate of heat transfer using the perturbation technique. It is found that the primary velocity decreases with an increase in the radiation parameter as well as the Prandtl number for cooling of the plate. It is also found that with an increase in the permeability parameter, the primary velocity increases for cooling of the plate. The magnitude of the secondary velocity decreases near the plate y = 0 and increases near the plate y = d with an increase in the permeability parameter. The temperature distribution decreases with an increase of the radiation parameter as wall as the Prandtl number for cooling of the plate. The shear stresses and the rate of heat transfer, which are of physical interest, are presented in the form of tables.
NASA Astrophysics Data System (ADS)
Chew, J. V. L.; Sulaiman, J.
2016-06-01
This paper considers Newton-MSOR iterative method for solving 1D nonlinear porous medium equation (PME). The basic concept of proposed iterative method is derived from a combination of one step nonlinear iterative method which known as Newton method with Modified Successive Over Relaxation (MSOR) method. The reliability of Newton-MSOR to obtain approximate solution for several PME problems is compared with Newton-Gauss-Seidel (Newton-GS) and Newton-Successive Over Relaxation (Newton-SOR). In this paper, the formulation and implementation of these three iterative methods have also been presented. From four examples of PME problems, numerical results showed that Newton-MSOR method requires lesser number of iterations and computational time as compared with Newton-GS and Newton-SOR methods.
NASA Astrophysics Data System (ADS)
Wen, Baole
Buoyancy-driven convection in fluid-saturated porous media is a key environmental and technological process, with applications ranging from carbon dioxide storage in terrestrial aquifers to the design of compact heat exchangers. Porous medium convection is also a paradigm for forced-dissipative infinite-dimensional dynamical systems, exhibiting spatiotemporally chaotic dynamics if not "true" turbulence. The objective of this dissertation research is to quantitatively characterize the dynamics and heat transport in two-dimensional horizontal and inclined porous medium convection between isothermal plane parallel boundaries at asymptotically large values of the Rayleigh number Ra by investigating the emergent, quasi-coherent flow. This investigation employs a complement of direct numerical simulations (DNS), secondary stability and dynamical systems theory, and variational analysis. The DNS confirm the remarkable tendency for the interior flow to self-organize into closely-spaced columnar plumes at sufficiently large Ra (up to Ra ≃ 105), with more complex spatiotemporal features being confined to boundary layers near the heated and cooled walls. The relatively simple form of the interior flow motivates investigation of unstable steady and time-periodic convective states at large Ra as a function of the domain aspect ratio L. To gain insight into the development of spatiotemporally chaotic convection, the (secondary) stability of these fully nonlinear states to small-amplitude disturbances is investigated using a spatial Floquet analysis. The results indicate that there exist two distinct modes of instability at large Ra: a bulk instability mode and a wall instability mode. The former usually is excited by long-wavelength disturbances and is generally much weaker than the latter. DNS, strategically initialized to investigate the fully nonlinear evolution of the most dangerous secondary instability modes, suggest that the (long time) mean inter-plume spacing in
NASA Astrophysics Data System (ADS)
Bianco, Carlo; Tosco, Tiziana; Sethi, Rajandrea
2016-10-01
Engineered nanoparticles (NPs) in the environment can act both as contaminants, when they are unintentionally released, and as remediation agents when injected on purpose at contaminated sites. In this work two carbon-based NPs are considered, namely CARBO-IRON®, a new material developed for contaminated site remediation, and single layer graphene oxide (SLGO), a potential contaminant of the next future. Understanding and modeling the transport and deposition of such NPs in aquifer systems is a key aspect in both cases, and numerical models capable to simulate NP transport in groundwater in complex 3D scenarios are necessary. To this aim, this work proposes a modeling approach based on modified advection-dispersion-deposition equations accounting for the coupled influence of flow velocity and ionic strength on particle transport. A new modeling tool (MNM3D - Micro and Nanoparticle transport Model in 3D geometries) is presented for the simulation of NPs injection and transport in 3D scenarios. MNM3D is the result of the integration of the numerical code MNMs (Micro and Nanoparticle transport, filtration and clogging Model - Suite) in the well-known transport model RT3D (Clement et al., 1998). The injection in field-like conditions of CARBO-IRON® (20 g/l) amended by CMC (4 g/l) in a 2D vertical tank (0.7 × 1.0 × 0.12 m) was simulated using MNM3D, and compared to experimental results under the same conditions. Column transport tests of SLGO at a concentration (10 mg/l) representative of a possible spill of SLGO-containing waste water were performed at different values of ionic strength (0.1 to 35 mM), evidencing a strong dependence of SLGO transport on IS, and a reversible blocking deposition. The experimental data were fitted using the numerical code MNMs and the ionic strength-dependent transport was up-scaled for a full scale 3D simulation of SLGO release and long-term transport in a heterogeneous aquifer. MNM3D showed to potentially represent a valid tool for
Leis, Andrew P.; Schlicher, Sven; Franke, Hilmar; Strathmann, Martin
2005-01-01
We describe a novel and noninvasive, microscopy-based method for visualizing the structure and dynamics of microbial biofilms, individual fluorescent microbial cells, and inorganic colloids within a model porous medium. Biofilms growing in flow cells packed with granules of an amorphous fluoropolymer could be visualized as a consequence of refractive index matching between the solid fluoropolymer grains and the aqueous immersion medium. In conjunction with the capabilities of confocal microscopy for nondestructive optical sectioning, the use of amorphous fluoropolymers as a solid matrix permits observation of organisms and dynamic processes to a depth of 2 to 3 mm, whereas sediment biofilms growing in sand-filled flow cells can only be visualized in the region adjacent to the flow cell wall. This method differs fundamentally from other refractive index-matching applications in that optical transparency was achieved by matching a solid phase to water (and not vice versa), thereby permitting real-time microscopic studies of particulate-containing, low-refractive-index media such as biological and chromatographic systems. PMID:16085878
Map of fluid flow in fractal porous medium into fractal continuum flow.
Balankin, Alexander S; Elizarraraz, Benjamin Espinoza
2012-05-01
This paper is devoted to fractal continuum hydrodynamics and its application to model fluid flows in fractally permeable reservoirs. Hydrodynamics of fractal continuum flow is developed on the basis of a self-consistent model of fractal continuum employing vector local fractional differential operators allied with the Hausdorff derivative. The generalized forms of Green-Gauss and Kelvin-Stokes theorems for fractional calculus are proved. The Hausdorff material derivative is defined and the form of Reynolds transport theorem for fractal continuum flow is obtained. The fundamental conservation laws for a fractal continuum flow are established. The Stokes law and the analog of Darcy's law for fractal continuum flow are suggested. The pressure-transient equation accounting the fractal metric of fractal continuum flow is derived. The generalization of the pressure-transient equation accounting the fractal topology of fractal continuum flow is proposed. The mapping of fluid flow in a fractally permeable medium into a fractal continuum flow is discussed. It is stated that the spectral dimension of the fractal continuum flow d(s) is equal to its mass fractal dimension D, even when the spectral dimension of the fractally porous or fissured medium is less than D. A comparison of the fractal continuum flow approach with other models of fluid flow in fractally permeable media and the experimental field data for reservoir tests are provided.
Hrabe, Nikolas W; Heinl, Peter; Bordia, Rajendra K; Körner, Carolin; Fernandes, Russell J
2013-01-01
Regular 3D periodic porous Ti-6Al-4 V structures were fabricated by the selective electron beam melting method (EBM) over a range of relative densities (0.17-0.40) and pore sizes (500-1500 µm). Structures were seeded with human osteoblast-like cells (SAOS-2) and cultured for four weeks. Cells multiplied within these structures and extracellular matrix collagen content increased. Type I and type V collagens typically synthesized by osteoblasts were deposited in the newly formed matrix with time in culture. High magnification scanning electron microscopy revealed cells attached to surfaces on the interior of the structures with an increasingly fibrous matrix. The in-vitro results demonstrate that the novel EBM-processed porous structures, designed to address the effect of stress-shielding, are conducive to osteoblast attachment, proliferation and deposition of a collagenous matrix characteristic of bone.
Magnetic field nonuniformities and NMR of protons diffusing in a porous medium.
Bergman, D J; Dunn, K J; LaTorraca, G A
1996-01-01
Magnetic field inhomogeneity can arise either because of an externally applied field gradient or because of spatial variations in magnetic susceptibility. The latter are most important when the solid matrix includes paramagnetic substances and when the uniform applied field, and, consequently, also the Larmor precession frequency are very large. Both types of field inhomogeneity add extra phase shifts to the precessing spins. These phase shifts vary with time and position in a complex and random fashion as a result of the diffusive motion of the spins. We have studied these effects by performing detailed calculations for the case of a fluid filled porous medium with a periodic microstructure. Special attention was devoted to the question of whether the statistical distribution of the phase shifts encountered in a Hahn spin echo experiment or in a Carr-Purcell-Meiboom-Gill (CPMG) spin-echo train can be approximated as a Gaussian. The mean square phase shift is measured in such experiments as an enhanced relaxation rate of the precessing transverse magnetization. We determine this mean square phase shift for periodic composites from the diffusion eigenstates, which were calculated using a previously developed Fourier expansion method. The enhanced relaxation rate depends on the echo spacing time tau in a way that can be correlated with important length scales of the porous microstructure. Those correlations can be extended also to disordered microstructures, like the ones that are found in natural rocks. We compare these theoretically predicted correlations with CPMG measurements performed on protons in laboratory samples of brine saturated sandstone. PMID:8970094
Studying the flow dynamics of a karst aquifer system with an equivalent porous medium model.
Abusaada, Muath; Sauter, Martin
2013-01-01
The modeling of groundwater flow in karst aquifers is a challenge due to the extreme heterogeneity of its hydraulic parameters and the duality in their discharge behavior, that is, rapid response of highly conductive karst conduits and delayed drainage of the low-permeability fractured matrix after recharge events. There are a number of different modeling approaches for the simulation of the karst groundwater dynamics, applicable to different aquifer as well as modeling problem types, ranging from continuum models to double continuum models to discrete and hybrid models. This study presents the application of an equivalent porous model approach (EPM, single continuum model) to construct a steady-state numerical flow model for an important karst aquifer, that is, the Western Mountain Aquifer Basin (WMAB), shared by Israel and the West-Bank, using MODFLOW2000. The WMAB was used as a catchment since it is a well-constrained catchment with well-defined recharge and discharge components and therefore allows a control on the modeling approach, a very rare opportunity for karst aquifer modeling. The model demonstrates the applicability of equivalent porous medium models for the simulation of karst systems, despite their large contrast in hydraulic conductivities. As long as the simulated saturated volume is large enough to average out the local influence of karst conduits and as long as transport velocities are not an issue, EPM models excellently simulate the observed head distribution. The model serves as a starting basis that will be used as a reference for developing a long-term dynamic model for the WMAB, starting from the pre-development period (i.e., 1940s) up to date.
NASA Astrophysics Data System (ADS)
Mosthaf, K.; Baber, K.; Flemisch, B.; Helmig, R.; Leijnse, A.; Rybak, I.; Wohlmuth, B.
2011-10-01
Domains composed of a porous part and an adjacent free-flow region are of special interest in many fields of application. So far, the coupling of free flow with porous-media flow has been considered only for single-phase systems. Here we extend this classical concept to two-component nonisothermal flow with two phases inside the porous medium and one phase in the free-flow region. The mathematical modeling of flow and transport phenomena in porous media is often based on Darcy's law, whereas in free-flow regions the (Navier-) -Stokes equations are used. In this paper, we give a detailed description of the employed subdomain models. The main contribution is the developed coupling concept, which is able to deal with compositional (miscible) flow and a two-phase system in the porous medium. It is based on the continuity of fluxes and the assumption of thermodynamic equilibrium, and uses the Beavers-Joseph-Saffman condition. The phenomenological explanations leading to a simple, solvable model, which accounts for the physics at the interface, are laid out in detail. Our model can account for evaporation and condensation processes at the interface and is used to model evaporation from soil influenced by a wind field in a first numerical example.
NASA Astrophysics Data System (ADS)
Gastone, Francesca; Tosco, Tiziana; Sethi, Rajandrea
2014-10-01
The present work is the first part of a comprehensive study on the use of guar gum to improve delivery of microscale zero-valent iron particles in contaminated aquifers. Guar gum solutions exhibit peculiar shear thinning properties, with high viscosity in static conditions and lower viscosity in dynamic conditions: this is beneficial both for the storage of MZVI dispersions, and also for the injection in porous media. In the present paper, the processes associated with guar gum injection in porous media are studied performing single-step and multi-step filtration tests in sand-packed columns. The experimental results of single-step tests performed by injecting guar gum solutions prepared at several concentrations and applying different dissolution procedures evidenced that the presence of residual undissolved polymeric particles in the guar gum solution may have a relevant negative impact on the permeability of the porous medium, resulting in evident clogging. The most effective preparation procedure which minimizes the presence of residual particles is dissolution in warm water (60 °C) followed by centrifugation (procedure T60C). The multi-step tests (i.e. injection of guar gum at constant concentration with a step increase of flow velocity), performed at three polymer concentrations (1.5, 3 and 4 g/l) provided information on the rheological properties of guar gum solutions when flowing through a porous medium at variable discharge rates, which mimic the injection in radial geometry. An experimental protocol was defined for the rheological characterization of the fluids in porous media, and empirical relationships were derived for the quantification of rheological properties and clogging with variable injection rate. These relationships will be implemented in the second companion paper (Part II) in a radial transport model for the simulation of large-scale injection of MZVI-guar gum slurries.
Gastone, Francesca; Tosco, Tiziana; Sethi, Rajandrea
2014-10-01
The present work is the first part of a comprehensive study on the use of guar gum to improve delivery of microscale zero-valent iron particles in contaminated aquifers. Guar gum solutions exhibit peculiar shear thinning properties, with high viscosity in static conditions and lower viscosity in dynamic conditions: this is beneficial both for the storage of MZVI dispersions, and also for the injection in porous media. In the present paper, the processes associated with guar gum injection in porous media are studied performing single-step and multi-step filtration tests in sand-packed columns. The experimental results of single-step tests performed by injecting guar gum solutions prepared at several concentrations and applying different dissolution procedures evidenced that the presence of residual undissolved polymeric particles in the guar gum solution may have a relevant negative impact on the permeability of the porous medium, resulting in evident clogging. The most effective preparation procedure which minimizes the presence of residual particles is dissolution in warm water (60°C) followed by centrifugation (procedure T60C). The multi-step tests (i.e. injection of guar gum at constant concentration with a step increase of flow velocity), performed at three polymer concentrations (1.5, 3 and 4g/l) provided information on the rheological properties of guar gum solutions when flowing through a porous medium at variable discharge rates, which mimic the injection in radial geometry. An experimental protocol was defined for the rheological characterization of the fluids in porous media, and empirical relationships were derived for the quantification of rheological properties and clogging with variable injection rate. These relationships will be implemented in the second companion paper (Part II) in a radial transport model for the simulation of large-scale injection of MZVI-guar gum slurries. PMID:25065767
Gastone, Francesca; Tosco, Tiziana; Sethi, Rajandrea
2014-10-01
The present work is the first part of a comprehensive study on the use of guar gum to improve delivery of microscale zero-valent iron particles in contaminated aquifers. Guar gum solutions exhibit peculiar shear thinning properties, with high viscosity in static conditions and lower viscosity in dynamic conditions: this is beneficial both for the storage of MZVI dispersions, and also for the injection in porous media. In the present paper, the processes associated with guar gum injection in porous media are studied performing single-step and multi-step filtration tests in sand-packed columns. The experimental results of single-step tests performed by injecting guar gum solutions prepared at several concentrations and applying different dissolution procedures evidenced that the presence of residual undissolved polymeric particles in the guar gum solution may have a relevant negative impact on the permeability of the porous medium, resulting in evident clogging. The most effective preparation procedure which minimizes the presence of residual particles is dissolution in warm water (60°C) followed by centrifugation (procedure T60C). The multi-step tests (i.e. injection of guar gum at constant concentration with a step increase of flow velocity), performed at three polymer concentrations (1.5, 3 and 4g/l) provided information on the rheological properties of guar gum solutions when flowing through a porous medium at variable discharge rates, which mimic the injection in radial geometry. An experimental protocol was defined for the rheological characterization of the fluids in porous media, and empirical relationships were derived for the quantification of rheological properties and clogging with variable injection rate. These relationships will be implemented in the second companion paper (Part II) in a radial transport model for the simulation of large-scale injection of MZVI-guar gum slurries.
Hayat, Tasawar; Rafiq, Maimona; Ahmad, Bashir
2016-01-01
The objective of present paper is to examine the peristaltic flow of magnetohydrodynamic (MHD) Jeffrey fluid saturating porous space in a channel through rotating frame. Unlike the previous attempts, the flow formulation is based upon modified Darcy's law porous medium effect in Jeffrey fluid situation. In addition the impacts due to Soret and Dufour effects in the radiative peristaltic flow are accounted. Rosseland's approximation has been utilized for the thermal radiative heat flux. Lubrication approach is implemented for the simplification. Resulting problems are solved for the stream function, temperature and concentration. Graphical results are prepared and analyzed for different parameters of interest entering into the problems. PMID:26808387
Hayat, Tasawar; Rafiq, Maimona; Ahmad, Bashir
2016-01-01
The objective of present paper is to examine the peristaltic flow of magnetohydrodynamic (MHD) Jeffrey fluid saturating porous space in a channel through rotating frame. Unlike the previous attempts, the flow formulation is based upon modified Darcy's law porous medium effect in Jeffrey fluid situation. In addition the impacts due to Soret and Dufour effects in the radiative peristaltic flow are accounted. Rosseland’s approximation has been utilized for the thermal radiative heat flux. Lubrication approach is implemented for the simplification. Resulting problems are solved for the stream function, temperature and concentration. Graphical results are prepared and analyzed for different parameters of interest entering into the problems. PMID:26808387
The flow of an aqueous foam through a two-dimensional porous medium
NASA Astrophysics Data System (ADS)
Dollet, B.; Jones, S. A.; Géraud, B.; Meheust, Y.; Cox, S. J.; Cantat, I.
2013-12-01
Flowing foams are used in many engineering and technical applications. A well-known application is oil recovery. Another one is the remediation of polluted soils: the foam is injected into the ground in order to mobilize chemical species present in the medium. Apart from potential interesting physico-chemical and biochemical properties, foams have peculiar flow properties that applications might benefit of. In particular, viscous dissipation arises mostly from the contact zones between the soap films and the walls, which results in peculiar friction laws allowing the foam to invade narrow pores more efficiently than Newtonian fluids would. We investigate the flow of a two-dimensional foam in three geometrical configurations. The flow velocity field and pressure field can both be reconstructed from the kinematics of the foam bubbles. We first consider a medium consisting of two parallel channels with different widths, at fixed medium porosity, that is, at fixed total combined width of the two channels. The flow behavior is highly dependent on the foam structure within the narrowest of the two channels [1]; consequently, the flux ratio between the two channels exhibits a non-monotonic dependence on the ratio of their widths. We then consider two parallel channels that are respectively convergent and divergent. The resulting flow kinematics imposes asymmetric bubble deformations in the two channels; these deformations strongly impact the foam/wall friction, and consequently the flux distribution between the two channels, causing flow irreversibility. We quantitatively predict the flux ratio as a function of the channel widths by modeling pressure drops of both viscous and capillary origins. This study reveals the crucial importance of boundary-induced bubble deformation on the mobility of a flowing foam. We then study how film-wall friction, capillary pressures and bubble deformation impact the flow of a foam in a two-dimensional porous medium consisting of randomly
Variation in Biofilm Stability with Decreasing pH Affects Porous Medium Hydraulic Properties
NASA Astrophysics Data System (ADS)
Kirk, M. F.; Santillan, E. F.; McGrath, L. K.; Altman, S. J.
2010-12-01
Changes to microbial communities caused by subsurface CO2 injection may have many consequences, including possible impacts to CO2 transport. We used column experiments to examine how decreasing pH, a geochemical change associated with CO2 injection, will affect biofilm stability and ultimately the hydraulic properties of porous media. Columns consisted of 1 mm2 square capillary tubes filled with 105-150 µm diameter glass beads. Artificial groundwater medium containing 1 mM glucose was pumped through the columns at a rate of 0.01 mL/min (q = 14.4 m/day; Re = 0.03). Columns were inoculated with 3 × 10^8 CFU (avg.) of Pseudomonas fluorescens, a model biofilm former, transformed with a green fluorescent protein. Biomass distribution and transport was examined using scanning laser confocal microscopy and effluent plating. Variation in the bulk hydraulic properties of the columns was measured using manometers. In an initial experiment, biofilm growth was allowed to occur for seven days in medium with pH 7.3. Within this period, cells uniformly coated bead surfaces, effluent cell numbers stabilized at 1 × 10^9 CFU/mL, and hydraulic conductivity (K) decreased 77%. Next, medium with pH 4 was introduced. As a result, biomass within the reactor redistributed from bead surfaces to pores, effluent cell numbers decreased to 3 × 10^5 CFU/mL, and K decreased even further (>94% reduction). This decreased K was maintained until the experiment was terminated, seven days after introducing low pH medium. These results suggest that changes in biomass distribution as a result of decreased pH may initially limit transport of solubility-trapped CO2 following CO2 injection. Experiments in progress and planned will test this result in more detail and over longer periods of time. This material is based upon work supported as part of the Center for Frontiers of Subsurface Energy Security, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office
NASA Astrophysics Data System (ADS)
Turkaya, Semih; Toussaint, Renaud; Eriksen, Fredrik; Zecevic, Megan; Daniel, Guillaume; Flekkøy, Eirik; Måløy, Knut Jørgen
2015-09-01
The characterization and understanding of rock deformation processes due to fluid flow is a challenging problem with numerous applications. The signature of this problem can be found in Earth Science and Physics, notably with applications in natural hazard understanding, mitigation or forecast (e.g. earthquakes, landslides with hydrological control, volcanic eruptions), or in industrial applications such as hydraulic-fracturing, steam-assisted gravity drainage, CO sequestration operations or soil remediation. Here we investigate the link between the visual deformation and the mechanical wave signals generated due to fluid injection into porous media. In a rectangular Hele-Shaw Cell, side air injection causes burst movement and compaction of grains along with channeling (creation of high permeability channels empty of grains). During the initial compaction and emergence of the main channel, the hydraulic fracturing in the medium generates a large non-impulsive low frequency signal in the frequency range 100 Hz - 10 kHz. When the channel network is established, the relaxation of the surrounding medium causes impulsive aftershock-like events, with high frequency (above 10 kHz) acoustic emissions, the rate of which follows an Omori Law. These signals and observations are comparable to seismicity induced by fluid injection. Compared to the data obtained during hydraulic fracturing operations, low frequency seismicity with evolving spectral characteristics have also been observed. An Omori-like decay of microearthquake rates is also often observed after injection shut-in, with a similar exponent p≃0.5 as observed here, where the decay rate of aftershock follows a scaling law dN/dt ∝(t-t₀ )-p . The physical basis for this modified Omori law is explained by pore pressure diffusion affecting the stress relaxation.
NASA Astrophysics Data System (ADS)
Mehta, C. B.; Singh, M.; Kumar, S.
2016-02-01
An investigation is made on the effect of Hall currents on thermal instability of a compressible couple-stress fluid in the presence of a horizontal magnetic field saturated in a porous medium. The analysis is carried out within the framework of the linear stability theory and normal mode technique. A dispersion relation governing the effects of viscoelasticity, Hall currents, compressibility, magnetic field and porous medium is derived. For the stationary convection a couple-stress fluid behaves like an ordinary Newtonian fluid due to the vanishing of the viscoelastic parameter. Compressibility, the magnetic filed and couple-stress parameter have stabilizing effects on the system whereas Hall currents and medium permeability have a destabilizing effect on the system, but in the absence of Hall current couple-stress has a destabilizing effect on the system. It has been observed that oscillatory modes are introduced due to the presence of viscoelasticity, magnetic field porous medium and Hall currents which were non-existent in their absence.
Zhu, Changbao; Kopold, Peter; Li, Weihan; van Aken, Peter A.; Maier, Joachim
2015-01-01
Transition metal sulfides have a great potential for energy storage due to the pronouncedly higher capacity (owing to conversion to metal or even alloy) than traditional insertion electrode materials. However, the poor cycling stability still limits the development and application in lithium and sodium ion batteries. Here, taking SnS as a model material, a novel general strategy is proposed to fabricate a 3D porous interconnected metal sulfide/carbon nanocomposite by the electrostatic spray deposition technique without adding any expensive carbonaceous materials such as graphene or carbon nanotube. In this way, small nanorods of SnS are generated with sizes of ≈10–20 nm embedded in amorphous carbon and self‐assembled into a 3D porous interconnected nanocomposite. The SnS:C is directly deposited on the Ti foil as a current collector and neither conductive additives nor binder are needed for battery assembly. Such electrodes exhibit a high reversible capacity, high rate capability, and long cycling stability for both lithium and sodium storage. PMID:27722078
Parameters analysis of a porous medium model for treatment with hyperthermia using OpenMP
NASA Astrophysics Data System (ADS)
Freitas Reis, Ruy; dos Santos Loureiro, Felipe; Lobosco, Marcelo
2015-09-01
Cancer is the second cause of death in the world so treatments have been developed trying to work around this world health problem. Hyperthermia is not a new technique, but its use in cancer treatment is still at early stage of development. This treatment is based on overheat the target area to a threshold temperature that causes cancerous cell necrosis and apoptosis. To simulate this phenomenon using magnetic nanoparticles in an under skin cancer treatment, a three-dimensional porous medium model was adopted. This study presents a sensibility analysis of the model parameters such as the porosity and blood velocity. To ensure a second-order solution approach, a 7-points centered finite difference method was used for space discretization while a predictor-corrector method was used to time evolution. Due to the massive computations required to find the solution of a three-dimensional model, this paper also presents a first attempt to improve performance using OpenMP, a parallel programming API.
Dependence of the conductivity of a porous medium on electrolyte conductivity
NASA Astrophysics Data System (ADS)
Johnson, David Linton; Sen, Pabitra N.
1988-03-01
For an arbitrary geometry of insulating, but charged, objects immersed in an electrolyte for which diffusion currents are important, the mathematical problem of the dc electrical conductivity can be mapped onto that of an ordinary conduction problem without diffusion currents but with a conductive surface layer. As a result, using variational arguments we can prove two general theorems which hold irrespective of the geometry of the porous medium: (a) At high salinities, so that the conductivity of the pore fluid, σf, is large, the conductivity of the system as a whole, σeff, is a linear function of σf, with a slope of 1/F and with an offset proportional to 1/Λ. (b) For lower values of salinity, σeff as a function of σf is convex-up as long as the conductivity within the double-layer region is independent of the salinity of the pore fluid. The parameters F and Λ introduced previously [D. L. Johnson, J. Koplik, and L. M. Schwartz, Phys. Rev. Lett. 57, 2564 (1986); D. L. Johnson, J. Koplik, and R. Dashen, J. Fluid Mech. 176, 379 (1987)] are hereby shown to be relevant to the electrolyte problem. An illustration of an ordered suspension is given to show how to implement these ideas.
Interstitial fluid flow in tendons or ligaments: a porous medium finite element simulation.
Butler, S L; Kohles, S S; Thielke, R J; Chen, C; Vanderby, R
1997-11-01
The purpose of this study is to describe interstitial fluid flow in axisymmetric soft connective tissue (ligaments or tendons) when they are loaded in tension. Soft hydrated tissue was modelled as a porous medium (using Darcy's Law), and the finite element method was used to solve the resulting equations governing fluid flow. A commercially available computer program (FiDAP) was used to create an axisymmetric model of a biomechanically tested rat ligament. The unknown variables at element nodes were pressure and velocity of the interstitial fluid (Newtonian and incompressible). The effect of variations in fluid viscosity and permeability of the solid matrix was parametrically explored. A transient loading state mimicking a rat ligament mechanical experiment was used in all simulations. The magnitude and distribution of pressure, stream lines, shear (stress) rate, vorticity and velocity showed regular patterns consistent with extension flow. Parametric changes of permeability and viscosity strongly affected fluid flow behaviour. When the radial permeability was 1000 times less than the axial permeability, shear rate and vorticity increased (approximately 5-fold). These effects (especially shear stress and pressure) suggested a strong interaction with the solid matrix. Computed levels of fluid flow suggested a possible load transduction mechanism for cells in the tissue.
Larabi, Mohamed Aziz; Mutschler, Dimitri; Mojtabi, Abdelkader
2016-06-28
Our present work focuses on the coupling between thermal diffusion and convection in order to improve the thermal gravitational separation of mixture components. The separation phenomenon was studied in a porous medium contained in vertical columns. We performed analytical and numerical simulations to corroborate the experimental measurements of the thermal diffusion coefficients of ternary mixture n-dodecane, isobutylbenzene, and tetralin obtained in microgravity in the international space station. Our approach corroborates the existing data published in the literature. The authors show that it is possible to quantify and to optimize the species separation for ternary mixtures. The authors checked, for ternary mixtures, the validity of the "forgotten effect hypothesis" established for binary mixtures by Furry, Jones, and Onsager. Two complete and different analytical resolution methods were used in order to describe the separation in terms of Lewis numbers, the separation ratios, the cross-diffusion coefficients, and the Rayleigh number. The analytical model is based on the parallel flow approximation. In order to validate this model, a numerical simulation was performed using the finite element method. From our new approach to vertical separation columns, new relations for mass fraction gradients and the optimal Rayleigh number for each component of the ternary mixture were obtained. PMID:27369539
NASA Astrophysics Data System (ADS)
Saller, S. P.; Ronayne, M. J.; Long, A. J.
2013-12-01
Karst conduits are commonly treated as high-conductivity zones in equivalent porous medium (EPM) models. In this study, an EPM model for a Paleozoic age carbonate aquifer was updated to include discrete conduits, and flow was simulated using the coupled continuum pipe-flow method. The modeled area, encompassing 2000 square km of the Madison aquifer in western South Dakota (USA), includes four karst springs with contributing conduit networks. The updated model considered the same observation data that were used to calibrate the EPM model: measured hydraulic heads at matrix observation wells and estimated springflow. Adjusted parameters included the conduit locations and hydraulic properties, as well as the matrix hydraulic conductivity distribution. Inferred karst pathways from environmental tracer analysis were used to guide the placement of conduits. The new coupled continuum pipe-flow model is characterized by a simpler conductivity distribution; extreme high-K values used in the EPM model are not necessary when conduit flow is explicitly simulated. Results are presented to illustrate the influence of conduits on simulated flow behavior.
NASA Astrophysics Data System (ADS)
Chen, Daiquan
Wood's metal injection method is used to perform imbibitions and drainage of ethylene glycol into natural samples of Berea sandstone. Results on the measurement of interfacial area per volume (IAV) in this natural three-dimensional porous medium by the method of image analysis are presented. In Wood's metal injection experiments, Wood's metal was used to represent a non-wetting fluid and ethylene glycol (EG) was used to represent a wetting phase fluid. To determine the IAV for a Wood's metal injected sample, images of the Wood's-metal-injected core were taken with a Scanning Electron Microscope (SEM). This is the first attempt to perform IAV measurements within Berea sandstone based on a large quantity of SEM images. Measurements were performed on two-dimensional micro-models to quantify interfacial area per volume for known pore geometry as a function of fluid pressure and saturation. The transparent micro-models make it possible to visualize and quantify the fluid distributions within the samples and study the detailed capillary pressure-saturation-IAV relationship of each micro-model. The results have shown that as porosity increases, the hysteresis of IAV-saturation relationship decreases. The difference between the drainage and imbibition surfaces from the same sample is small. The theoretical capillary pressure values based on a theoretical equation cannot fit the measured values well and changes need to be made to this equation.
Effect of first-order chemical reaction on gravitational instability in a porous medium.
Kim, Min Chan; Choi, Chang Kyun
2014-11-01
To understand the CO_{2} sequestration in the saline aquifer, the effect of a first-order chemical reaction on the onset of the buoyancy-driven instability in an isotropic reactive porous medium is analyzed theoretically. Under the linear stability theory, the stability equations are derived in the semi-infinite domain and they are solved with and without the quasi-steady-state approximation. We also considered the stability of the reactive system at a steady-state limit. The analysis for the steady-state case proposed that the onset of instability motion can occur during the transient period even if the system is stable at the steady state. Through the initial growth rate analysis the most unstable initial disturbance is determined, and it is found that initially the system is unconditionally stable regardless of the Damköhler number D_{a} and the Darcy-Rayleigh number Ra. Based on the results of the initial growth rate analysis, the direct numerical simulation is also conducted by using the Fourier pseudospectral method. The present theoretical and numerical analyses suggest that the chemical reaction makes the system stable and no convective motion can be expected for D_{a}/Ra^{2}>2.5×10^{-3}.
NASA Astrophysics Data System (ADS)
Miller, C. T.; Gray, W. G.; McClure, J. E.; Dye, A. L.; Weigand, T. M.; Hauswirth, S.; Schultz, P. B.
2015-12-01
The thermodynamically constrained averaging theory (TCAT) has been developed over the last decade as a rigorous, formal method of deriving mechanistic mathematical models that describe a wide range of porous medium systems. TCAT models are consistent across length scales and provide explicit linkages between important physics known to be operative at the microscale and larger scale models. This produces a straightforward mechanism to evaluate macroscale quantities based on information generated from microscale simulations or experiments as way to inform model development. TCAT models inherently include interface, common curve, and common point properties in models that admit such entities. Elements of the TCAT theory are discussed, model hierarchies are derived and summarized, and specific aspects of TCAT models are examined in detail. Comparisons of TCAT model constructs with both experimental data and high-resolution microscale simulations illustrate that, contrary to common belief, virtually all capillary pressure vs. saturation data that is available for two-fluid-phase systems is not equilibrium data. Agreement between theory and observation for TCAT models is demonstrated, and aspects of the models posed are validated.
Convection and reaction in a diffusive boundary layer in a porous medium: Nonlinear dynamics
NASA Astrophysics Data System (ADS)
Andres, Jeanne Therese H.; Cardoso, Silvana S. S.
2012-09-01
We study numerically the nonlinear interactions between chemical reaction and convective fingering in a diffusive boundary layer in a porous medium. The reaction enhances stability by consuming a solute that is unstably distributed in a gravitational field. We show that chemical reaction profoundly changes the dynamics of the system, by introducing a steady state, shortening the evolution time, and altering the spatial patterns of velocity and concentration of solute. In the presence of weak reaction, finger growth and merger occur effectively, driving strong convective currents in a thick layer of solute. However, as the reaction becomes stronger, finger growth is inhibited, tip-splitting is enhanced and the layer of solute becomes much thinner. Convection enhances the mass flux of solute consumed by reaction in the boundary layer but has a diminishing effect as reaction strength increases. This nonlinear behavior has striking differences to the density fingering of traveling reaction fronts, for which stronger chemical kinetics result in more effective finger merger owing to an increase in the speed of the front. In a boundary layer, a strong stabilizing effect of reaction can maintain a long-term state of convection in isolated fingers of wavelength comparable to that at onset of instability.
NASA Astrophysics Data System (ADS)
Larabi, Mohamed Aziz; Mutschler, Dimitri; Mojtabi, Abdelkader
2016-06-01
Our present work focuses on the coupling between thermal diffusion and convection in order to improve the thermal gravitational separation of mixture components. The separation phenomenon was studied in a porous medium contained in vertical columns. We performed analytical and numerical simulations to corroborate the experimental measurements of the thermal diffusion coefficients of ternary mixture n-dodecane, isobutylbenzene, and tetralin obtained in microgravity in the international space station. Our approach corroborates the existing data published in the literature. The authors show that it is possible to quantify and to optimize the species separation for ternary mixtures. The authors checked, for ternary mixtures, the validity of the "forgotten effect hypothesis" established for binary mixtures by Furry, Jones, and Onsager. Two complete and different analytical resolution methods were used in order to describe the separation in terms of Lewis numbers, the separation ratios, the cross-diffusion coefficients, and the Rayleigh number. The analytical model is based on the parallel flow approximation. In order to validate this model, a numerical simulation was performed using the finite element method. From our new approach to vertical separation columns, new relations for mass fraction gradients and the optimal Rayleigh number for each component of the ternary mixture were obtained.
Larabi, Mohamed Aziz; Mutschler, Dimitri; Mojtabi, Abdelkader
2016-06-28
Our present work focuses on the coupling between thermal diffusion and convection in order to improve the thermal gravitational separation of mixture components. The separation phenomenon was studied in a porous medium contained in vertical columns. We performed analytical and numerical simulations to corroborate the experimental measurements of the thermal diffusion coefficients of ternary mixture n-dodecane, isobutylbenzene, and tetralin obtained in microgravity in the international space station. Our approach corroborates the existing data published in the literature. The authors show that it is possible to quantify and to optimize the species separation for ternary mixtures. The authors checked, for ternary mixtures, the validity of the "forgotten effect hypothesis" established for binary mixtures by Furry, Jones, and Onsager. Two complete and different analytical resolution methods were used in order to describe the separation in terms of Lewis numbers, the separation ratios, the cross-diffusion coefficients, and the Rayleigh number. The analytical model is based on the parallel flow approximation. In order to validate this model, a numerical simulation was performed using the finite element method. From our new approach to vertical separation columns, new relations for mass fraction gradients and the optimal Rayleigh number for each component of the ternary mixture were obtained.
Aziz, Asim; Siddique, J. I.; Aziz, Taha
2014-01-01
In this paper, a simplified model of an incompressible fluid flow along with heat and mass transfer past a porous flat plate embedded in a Darcy type porous medium is investigated. The velocity, thermal and mass slip conditions are utilized that has not been discussed in the literature before. The similarity transformations are used to transform the governing partial differential equations (PDEs) into a nonlinear ordinary differential equations (ODEs). The resulting system of ODEs is then reduced to a system of first order differential equations which was solved numerically by using Matlab bvp4c code. The effects of permeability, suction/injection parameter, velocity parameter and slip parameter on the structure of velocity, temperature and mass transfer rates are examined with the aid of several graphs. Moreover, observations based on Schmidt number and Soret number are also presented. The result shows, the increase in permeability of the porous medium increase the velocity and decrease the temperature profile. This happens due to a decrease in drag of the fluid flow. In the case of heat transfer, the increase in permeability and slip parameter causes an increase in heat transfer. However for the case of increase in thermal slip parameter there is a decrease in heat transfer. An increase in the mass slip parameter causes a decrease in the concentration field. The suction and injection parameter has similar effect on concentration profile as for the case of velocity profile. PMID:25531301
Aziz, Asim; Siddique, J I; Aziz, Taha
2014-01-01
In this paper, a simplified model of an incompressible fluid flow along with heat and mass transfer past a porous flat plate embedded in a Darcy type porous medium is investigated. The velocity, thermal and mass slip conditions are utilized that has not been discussed in the literature before. The similarity transformations are used to transform the governing partial differential equations (PDEs) into a nonlinear ordinary differential equations (ODEs). The resulting system of ODEs is then reduced to a system of first order differential equations which was solved numerically by using Matlab bvp4c code. The effects of permeability, suction/injection parameter, velocity parameter and slip parameter on the structure of velocity, temperature and mass transfer rates are examined with the aid of several graphs. Moreover, observations based on Schmidt number and Soret number are also presented. The result shows, the increase in permeability of the porous medium increase the velocity and decrease the temperature profile. This happens due to a decrease in drag of the fluid flow. In the case of heat transfer, the increase in permeability and slip parameter causes an increase in heat transfer. However for the case of increase in thermal slip parameter there is a decrease in heat transfer. An increase in the mass slip parameter causes a decrease in the concentration field. The suction and injection parameter has similar effect on concentration profile as for the case of velocity profile.
NASA Astrophysics Data System (ADS)
Dobberschütz, Sören; Böhm, Michael
2010-02-01
The behaviour of a free fluid flow above a porous medium, both separated by a curved interface, is investigated. By carrying out a coordinate transformation, we obtain the description of the flow in a domain with a straight interface. Using periodic homogenisation, the effective behaviour of the transformed partial differential equations in the porous part is given by a Darcy law with non-constant permeability matrix. Then the fluid behaviour at the porous-liquid interface is obtained with the help of generalised boundary-layer functions: Whereas the velocity in normal direction is continuous across the interface, a jump appears in tangential direction. Its magnitude seems to be related to the slope of the interface. Therefore the results indicate a generalised law of Beavers and Joseph.
NASA Astrophysics Data System (ADS)
Ciriello, Valentina; Longo, Sandro; Chiapponi, Luca; Di Federico, Vittorio
2016-06-01
We develop a model to grasp the combined effect of rheology and spatial stratifications on two-dimensional non-Newtonian gravity-driven flow in porous media. We consider a power-law constitutive equation for the fluid, and a monomial variation of permeability and porosity along the vertical direction (transverse to the flow) or horizontal direction (parallel to the flow). Under these assumptions, similarity solutions are derived in semi-analytical form for thin gravity currents injected into a two-dimensional porous medium and having constant or time-varying volume. The extent and shape of the porous domain affected by the injection is significantly influenced by the interplay of model parameters. These describe the fluid (flow behaviour index n), the spatial heterogeneity (coefficients β, γ, δ, ω for variations of permeability and porosity in the horizontal or vertical direction), and the type of release (volume exponent α). Theoretical results are validated against two sets of experiments with α = 1 (constant inflow) conducted with a stratified porous medium (simulated by superimposing layers of glass beads of different diameter) and a Hele-Shaw analogue for power-law fluid flow, respectively. In the latter case, a recently established Hele-Shaw analogy is extended to the variation of properties parallel to the flow direction. Comparison with experimental results shows that the proposed model is able to capture the propagation of the current front and the current profile.
Doughty, C.; Pruess, K.
1991-06-01
Over the past few years the authors have developed a semianalytical solution for transient two-phase water, air, and heat flow in a porous medium surrounding a constant-strength linear heat source, using a similarity variable {eta} = r/{radical}t. Although the similarity transformation approach requires a simplified geometry, all the complex physical mechanisms involved in coupled two-phase fluid and heat flow can be taken into account in a rigorous way, so that the solution may be applied to a variety of problems of current interest. The work was motivated by adverse to predict the thermohydrological response to the proposed geologic repository for heat-generating high-level nuclear wastes at Yucca Mountain, Nevada, in a partially saturated, highly fractured volcanic formation. The paper describes thermal and hydrologic conditions near the heat source; new features of the model; vapor pressure lowering; and the effective-continuum representation of a fractured/porous medium.
NASA Astrophysics Data System (ADS)
Sharma, Mukesh Kumar; Bansal, Kuldip; Bansal, Seema
2012-09-01
The periodic nature of the cardiac cycle induces a pulsatile, unsteady flow within the circulatory system. The pulsatile model of blood flow provides data to analyse the physiological situation in close proximity. The distribution of fatty cholesterol and artery-clogging blood clots in the lumen of the coronary artery is assumed as a porous medium. A mathematical model for pulsatile flow through an stenosed artery filled with porous medium in the presence of transverse static magnetic field has been formulated under the consideration of hematocrit dependent viscosity of blood that governed by Einstein equation. The velocity profile, volume flux, pressure gradient and wall shear stress are obtained and the effects of magnetic number, Darcy number, Womersely number are computed and represented through graphs.
Ren, Dianjun; Smith, James A
2013-04-16
The retention and transport of silver nanoparticles (Ag-NPs) through a ceramic porous medium used for point-of-use drinking water purification is investigated. Two general types of experiments were performed: (i) pulse injections of suspensions of Ag-NPs in aqueous MgSO4 solutions were applied to the ceramic medium, and effluent silver was quantified over time; (ii) Ag-NPs were applied directly to the porous medium during fabrication using a paint-on, dipping, or fire-in method, a synthetic, moderately hard water sample with monovalent and divalent inorganic ions was applied to the ceramic medium, and effluent silver was quantified over time. These latter experiments were performed to approximate real-world use of the filter medium. For experiments with Ag-NPs suspended in the inflow solution, the percentage of applied Ag-NPs retained in the ceramic porous medium ranged from about 13 to 100%. Ag-NP mobility decreased with increasing ionic strength for all cases and to a lesser extent with increasing nanoparticle diameter. Citrate-capped particles were slightly less mobile than proteinate-capped particles. For ceramic disks fabricated with Ag-NPs by the paint-on and dipping methods (where the Ag-NPs are applied to the disks after firing), significant release of nanoparticles into the filter disk effluent was observed relative to the fire-in method (where the nanoparticles are combined with the clay, water, grog, and flour before firing). These results suggest that the fire-in method may be a new and significant improvement to ceramic filter design.
Borman, Vladimir D; Belogorlov, Anton A; Byrkin, Victor A; Tronin, Vladimir N
2013-11-01
An approach has been proposed for the description of the dispersion transition of a nonwetting liquid in confinement. This approach describes intrusion and extrusion processes for the ground state of a disordered porous medium, which is characterized by the formation of a fractal percolation cluster. The observed transition of the system of liquid nanoclusters in confinement to a metastable state in a narrow range of degrees of filling and temperatures has been explained by the appearance of a potential barrier owing to fluctuations of the collective "multiparticle interaction" of liquid nanoclusters in neighboring pores of different sizes on the shell of the fractal percolation cluster of filled pores. The energy of the metastable state forms a potential relief in the space of the porous medium with many maxima and minima. The volume of the dispersed liquid in the metastable state has been calculated within the analytical percolation theory for the ground state with the infinite percolation cluster. The extrusion-time distribution function of pores has been calculated. It has been found that the volume of the nonwetting liquid remaining in the porous medium decreases with time according to a power law. Relaxation in the system under study is a multistep process involving discontinuous equilibrium and overcoming of many local maxima of the potential relief. The formation of the metastable state of the trapped nonwetting liquid has been attributed to the nonergodicity of the disordered porous medium. The model reproduces the observed dependence of the volume of the dispersed liquid both on the degree of filling and on the temperature. PMID:24329223
Borman, Vladimir D; Belogorlov, Anton A; Byrkin, Victor A; Tronin, Vladimir N
2013-11-01
An approach has been proposed for the description of the dispersion transition of a nonwetting liquid in confinement. This approach describes intrusion and extrusion processes for the ground state of a disordered porous medium, which is characterized by the formation of a fractal percolation cluster. The observed transition of the system of liquid nanoclusters in confinement to a metastable state in a narrow range of degrees of filling and temperatures has been explained by the appearance of a potential barrier owing to fluctuations of the collective "multiparticle interaction" of liquid nanoclusters in neighboring pores of different sizes on the shell of the fractal percolation cluster of filled pores. The energy of the metastable state forms a potential relief in the space of the porous medium with many maxima and minima. The volume of the dispersed liquid in the metastable state has been calculated within the analytical percolation theory for the ground state with the infinite percolation cluster. The extrusion-time distribution function of pores has been calculated. It has been found that the volume of the nonwetting liquid remaining in the porous medium decreases with time according to a power law. Relaxation in the system under study is a multistep process involving discontinuous equilibrium and overcoming of many local maxima of the potential relief. The formation of the metastable state of the trapped nonwetting liquid has been attributed to the nonergodicity of the disordered porous medium. The model reproduces the observed dependence of the volume of the dispersed liquid both on the degree of filling and on the temperature.
NASA Astrophysics Data System (ADS)
Timoumi, M.; Chérif, B.; Sifaoui, M. S.
2005-12-01
In this paper, heat transfer problem through a semi-transparent porous medium in a cylindrical enclosure is investigated. The governing equations for this problem and the boundary conditions are non-linear differential equations depending on the dimensionless radial coordinate, Planck number N, scattering albedo ω, walls emissivity and thermal conductivity ratio kr. The set of differential equations are solved by a numerical technique taken from the IMSL MATH/LIBRARY. Various results are obtained for the dimensionless temperature profiles in the solid and fluid phases and the radiative heat flux. The effects of some radiative properties of the medium on the heat transfer rate are examined.
Guzman, Juan; Maximov, Serguei; Escarela-Perez, Rafael; López-García, Irvin; Moranchel, Mario
2015-01-01
The diffusion and distribution coefficients are important parameters in the design of barrier systems used in radioactive repositories. These coefficients can be determined using a two-reservoir configuration, where a saturated porous medium is allocated between two reservoirs filled by stagnant water. One of the reservoirs contains a high concentration of radioisotopes. The goal of this work is to obtain an analytical solution for the concentration of all radioisotopes in the decay chain of a two-reservoir configuration. The analytical solution must be obtained by taking into account the diffusion and sorption processes. Concepts such as overvalued concentration, diffusion and decay factors are employed to this end. It is analytically proven that a factor of the solution is identical for all chains (considering a time scaling factor), if certain parameters do not change. In addition, it is proven that the concentration sensitivity, due to the distribution coefficient variation, depends of the porous medium thickness, which is practically insensitive for small porous medium thicknesses. The analytical solution for the radioisotope concentration is compared with experimental and numerical results available in literature.
NASA Astrophysics Data System (ADS)
Huang, Shao-Zhuan; Jin, Jun; Cai, Yi; Li, Yu; Deng, Zhao; Zeng, Jun-Yang; Liu, Jing; Wang, Chao; Hasan, Tawfique; Su, Bao-Lian
2015-10-01
Bicontinuous hierarchically porous Mn2O3 single crystals (BHP-Mn2O3-SCs) with uniform parallelepiped geometry and tunable sizes have been synthesized and used as anode materials for lithium-ion batteries (LIBs). The monodispersed BHP-Mn2O3-SCs exhibit high specific surface area and three dimensional interconnected bimodal mesoporosity throughout the entire crystal. Such hierarchical interpenetrating porous framework can not only provide a large number of active sites for Li ion insertion, but also good conductivity and short diffusion length for Li ions, leading to a high lithium storage capacity and enhanced rate capability. Furthermore, owing to their specific porosity, these BHP-Mn2O3-SCs as anode materials can accommodate the volume expansion/contraction that occurs with lithium insertion/extraction during discharge/charge processes, resulting in their good cycling performance. Our synthesized BHP-Mn2O3-SCs with a size of ~700 nm display the best electrochemical performance, with a large reversible capacity (845 mA h g-1 at 100 mA g-1 after 50 cycles), high coulombic efficiency (>95%), excellent cycling stability and superior rate capability (410 mA h g-1 at 1 Ag-1). These values are among the highest reported for Mn2O3-based bulk solids and nanostructures. Also, electrochemical impedance spectroscopy study demonstrates that the BHP-Mn2O3-SCs are suitable for charge transfer at the electrode/electrolyte interface.
Nonlinear instability of an Oldroyd elastico-viscous magnetic nanofluid saturated in a porous medium
NASA Astrophysics Data System (ADS)
Moatimid, Galal M.; Alali, Elham M. M.; Ali, Hoda S. M.
2014-09-01
Through viscoelastic potential theory, a Kelvin-Helmholtz instability of two semi-infinite fluid layers, of Oldroydian viscoelastic magnetic nanofluids (MNF), is investigated. The system is saturated by porous medium through two semi-infinite fluid layers. The Oldroyd B model is utilized to describe the rheological behavior of viscoelastic MNF. The system is influenced by uniform oblique magnetic field that acts at the surface of separation. The model is used for the MNF incorporated the effects of uniform basic streaming and viscoelasticity. Therefore, a mathematical simplification must be considered. A linear stability analysis, based upon the normal modes analysis, is utilized to find out the solutions of the equations of motion. The onset criterion of stability is derived; analytically and graphs have been plotted by giving numerical values to the various parameters. These graphs depict the stability characteristics. Regions of stability and instability are identified and discussed in some depth. Some previous studies are recovered upon appropriate data choices. The stability criterion in case of ignoring the relaxation stress times is also derived. To relax the mathematical manipulation of the nonlinear approach, the linearity of the equations of motion is taken into account in correspondence with the nonlinear boundary conditions. Taylor's theory is adopted to expand the governing nonlinear characteristic equation according to of the multiple time scales technique. This analysis leads to the well-known Ginzburg-Landau equation, which governs the stability criteria. The stability criteria are achieved theoretically. To simplify the mathematical manipulation, a special case is considered to achieve the numerical estimations. The influence of orientation of the magnetic fields on the stability configuration, in linear as well as nonlinear approaches, makes a dual role for the magnetic field strength in the stability graphs. Stability diagram is plotted for
Co-symmetry breakdown in problems of thermal convection in porous medium
NASA Astrophysics Data System (ADS)
Bratsun, Dmitry A.; Lyubimov, Dmitry V.; Roux, Bernard
We investigate two-dimensional thermal convection of saturating incompressible fluid in a horizontal cylinder filled with porous medium. The temperature distribution on the boundaries is time-independent and corresponds to the heating from below. At supercritical parameter values the problem has infinite number of stationary solutions for arbitrary shape of the region. This degeneracy is connected with the so-called co-symmetry property: the existence of the vector field which is orthogonal to the considered one. Non-coincidence of zeroes of these two fields leads generally speaking, to the degeneracy of the solutions. To destroy the degeneracy we add weak fluid seeping of the fluid through the boundaries either in vertical or in the horizontal direction. The breakdown of the family of the stationary solutions at high supercritical values of the Rayleigh number is studied in detail with the help of the corresponding normal form. Several limit cycles with the twisted leading manifolds appear as a result of the family destruction. To investigate the dynamical behavior the finite-dimensional models of the convection which maintain the breakdown of co-symmetry, are constructed on the base of the Galerkin approximation. The same scenario of the transition to chaos which seems to be connected with the co-symmetry breakdown, is recovered for both kinds of seeping. The quasi-periodic solution branches from the limit cycle. The further increase of the Peclet number leads to mode-locking, which is followed by the appearance of the homoclinic surface formed by the unstable manifold of the saddle periodic orbit; destruction of the latter surface leaves in the phase space the object with torus-like shape and non-integer fractal dimension.
Bubbling behaviors induced by gas-liquid mixture permeating through a porous medium
NASA Astrophysics Data System (ADS)
Hu, Liang; Li, Mingbo; Chen, Wenyu; Xie, Haibo; Fu, Xin
2016-08-01
This paper investigates the bubbling behaviors induced by gas-liquid mixture permeating through porous medium (PM), which was observed in developing immersion lithography system and was found having great differences with traditional bubbling behaviors injected with only gas phase through the PM. An experimental setup was built up to investigate the bubbling characteristics affected by the mixed liquid phase. Both the flow regimes of gas-liquid mixture in micro-channel (upstream of the PM) and the bubbling flow regimes in water tank (downstream of the PM) were recorded synchronously by high-speed camera. The transitions between the flow regimes are governed by gas and liquid Weber numbers. Based on the image analysis, the characteristic parameters of bubbling region, including the diameter of bubbling area on PM surface, gas-phase volume flux, and dispersion angle of bubbles in suspending liquid, were studied under different proportions of gas and liquid flow rate. Corresponding empirical correlations were developed to describe and predict these parameters. Then, the pertinent bubble characteristics in different bubbling flow regimes were systematically investigated. Specifically, the bubble size distribution and the Sauter mean diameter affected by increasing liquid flow rate were studied, and the corresponding analysis was given based on the hydrodynamics of bubble-bubble and bubble-liquid interactions. According to dimensionless analysis, the general prediction equation of Sauter mean diameter under different operating conditions was proposed and confirmed by experimental data. The study of this paper is helpful to improve the collection performance of immersion lithography and aims to reveal the differences between the bubbling behaviors on PM caused by only gas flow and gas-liquid mixture flow, respectively, for the researches of fluid flow.
NASA Astrophysics Data System (ADS)
Hauswirth, Scott C.; Miller, Cass T.
2014-10-01
The remediation of former manufactured gas plant (FMGP) sites contaminated with tar DNAPLs (dense non-aqueous phase liquids) presents a significant challenge. The tars are viscous mixtures of thousands of individual compounds, including known and suspected carcinogens. This work investigates the use of combinations of mobilization, solubilization, and chemical oxidation approaches to remove and degrade tars and tar components in porous medium systems. Column experiments were conducted using several flushing solutions, including an alkaline-polymer (AP) solution containing NaOH and xanthan gum (XG), a surfactant-polymer (SP) solution containing Triton X-100 surfactant (TX100) and XG, an alkaline-surfactant-polymer (ASP) solution containing NaOH, TX100, and XG, and base-activated sodium persulfate both with and without added TX100. The effectiveness of the flushing solutions was assessed based on both removal of polycyclic aromatic hydrocarbon (PAH) mass and on the reduction of dissolved-phase PAH concentrations. SP flushes of 6.6 to 20.9 PV removed over 99% of residual PAH mass and reduced dissolved-phase concentrations by up to two orders of magnitude. ASP flushing efficiently removed 95-96% of residual PAH mass within about 2 PV, and significantly reduced dissolved-phase concentrations of several low molar mass compounds, including naphthalene, acenaphthene, fluorene, and phenanthrene. AP flushing removed a large portion of the residual tar (77%), but was considerably less effective than SP and ASP in terms of the effect on dissolved PAH concentrations. Persulfate was shown to oxidize tar components, primarily those with low molar mass, however, the overall degradation was relatively low (30-50% in columns with low initial tar saturations), and the impact on dissolved-phase concentrations was minimal.
Hauswirth, Scott C; Miller, Cass T
2014-10-15
The remediation of former manufactured gas plant (FMGP) sites contaminated with tar DNAPLs (dense non-aqueous phase liquids) presents a significant challenge. The tars are viscous mixtures of thousands of individual compounds, including known and suspected carcinogens. This work investigates the use of combinations of mobilization, solubilization, and chemical oxidation approaches to remove and degrade tars and tar components in porous medium systems. Column experiments were conducted using several flushing solutions, including an alkaline-polymer (AP) solution containing NaOH and xanthan gum (XG), a surfactant-polymer (SP) solution containing Triton X-100 surfactant (TX100) and XG, an alkaline-surfactant-polymer (ASP) solution containing NaOH, TX100, and XG, and base-activated sodium persulfate both with and without added TX100. The effectiveness of the flushing solutions was assessed based on both removal of polycyclic aromatic hydrocarbon (PAH) mass and on the reduction of dissolved-phase PAH concentrations. SP flushes of 6.6 to 20.9 PV removed over 99% of residual PAH mass and reduced dissolved-phase concentrations by up to two orders of magnitude. ASP flushing efficiently removed 95-96% of residual PAH mass within about 2 PV, and significantly reduced dissolved-phase concentrations of several low molar mass compounds, including naphthalene, acenaphthene, fluorene, and phenanthrene. AP flushing removed a large portion of the residual tar (77%), but was considerably less effective than SP and ASP in terms of the effect on dissolved PAH concentrations. Persulfate was shown to oxidize tar components, primarily those with low molar mass, however, the overall degradation was relatively low (30-50% in columns with low initial tar saturations), and the impact on dissolved-phase concentrations was minimal.
Nonlinear instability of an Oldroyd elastico–viscous magnetic nanofluid saturated in a porous medium
Moatimid, Galal M.; Alali, Elham M. M. Ali, Hoda S. M.
2014-09-15
Through viscoelastic potential theory, a Kelvin-Helmholtz instability of two semi-infinite fluid layers, of Oldroydian viscoelastic magnetic nanofluids (MNF), is investigated. The system is saturated by porous medium through two semi-infinite fluid layers. The Oldroyd B model is utilized to describe the rheological behavior of viscoelastic MNF. The system is influenced by uniform oblique magnetic field that acts at the surface of separation. The model is used for the MNF incorporated the effects of uniform basic streaming and viscoelasticity. Therefore, a mathematical simplification must be considered. A linear stability analysis, based upon the normal modes analysis, is utilized to find out the solutions of the equations of motion. The onset criterion of stability is derived; analytically and graphs have been plotted by giving numerical values to the various parameters. These graphs depict the stability characteristics. Regions of stability and instability are identified and discussed in some depth. Some previous studies are recovered upon appropriate data choices. The stability criterion in case of ignoring the relaxation stress times is also derived. To relax the mathematical manipulation of the nonlinear approach, the linearity of the equations of motion is taken into account in correspondence with the nonlinear boundary conditions. Taylor's theory is adopted to expand the governing nonlinear characteristic equation according to of the multiple time scales technique. This analysis leads to the well-known Ginzburg–Landau equation, which governs the stability criteria. The stability criteria are achieved theoretically. To simplify the mathematical manipulation, a special case is considered to achieve the numerical estimations. The influence of orientation of the magnetic fields on the stability configuration, in linear as well as nonlinear approaches, makes a dual role for the magnetic field strength in the stability graphs. Stability diagram is plotted for
Eckold, Pierre; Gee, William J; Hill, Matthew R; Batten, Stuart R
2012-11-21
The synthesis and characterisation of microporous coordination polymers containing copper(II) or cobalt(II) and 2-(pyridin-4-yl)malonaldehyde (Hpma) is described and the gas adsorption properties evaluated. Single-crystal X-ray structure determinations identified the structures as [M(pma)(2)]·2X (M = Cu, 1; Co, 2; X = MeOH, MeCN), which contain 3D networks with rutile topology and continuous 1D rectangular channels with diameters ranging from 3 to 4 Å. The materials exhibit low BET surface areas of 143 m(2) g(-1), but possess large capacities for carbon dioxide capture of 14.1 wt%. The small pore channels are shown to account for this, delivering a particularly strong binding enthalpy to adsorbed CO(2) of 38 kJ mol(-1), and a very large adsorption capacity relative to the low surface area.
Huang, Wei E; Oswald, Sascha E; Lerner, David N; Smith, Colin C; Zheng, Chunmiao
2003-05-01
A novel combination of noninvasive imaging with an oxygen sensitive fluorescent indicator was developed to investigate the biodegradation processes occurring at the fringe of a solute plume, where the supply of oxygen was limited. A thin transparent porous matrix (156 x 120 x 3 mm) was made from quartz plates and quartz sand (212-300 microm) and enriched with acetate-degrading bacteria. A degrading plume developed from a continuous acetate source in the uniform flow field containing dissolved oxygen. Ruthenium (II)-dichlorotris(1,10-phenanthroline) (Ru(phen)3Cl2), a water-soluble fluorescent dye, was used as an indicator of dissolved oxygen. The fluorescence intensity was dependent on the concentration of oxygen because the dissolved oxygen acted as collisional quencher. The oxygen distribution was interpreted from images recorded by a CCD camera. These two-dimensional experimental results showed quantitatively how the oxygen concentrations decreased strongly at the narrow plume fringe and that oxygen was depleted at the core of the plume. Separately, dispersivity was measured in a series of nonreactive transport experiments, and biodegradation parameters were evaluated by batch experiments. Two-dimensional numerical simulations with MT3D/RT3D used these parameters, and the predicted oxygen distributions were compared with the experimental results. This measurement method provides a novel approach to investigate details of solute transport and biodegradation in porous media.
Ma, Rui; Lai, Yu-xiao; Li, Long; Tan, Hong-lue; Wang, Jia-li; Li, Ye; Tang, Ting-ting; Qin, Ling
2015-01-01
Bone infections are common in trauma-induced open fractures with bone defects. Therefore, developing anti-infection scaffolds for repairing bone defects is desirable. This study develoepd novel Mg-based porous composite scaffolds with a basal matrix composed of poly(lactic-co-glycolicacid) (PLGA) and tricalcium phosphate (TCP). A unique low-temperature rapid prototyping technology was used to fabricate the scaffolds, including PLGA/TCP (PT), PLGA/TCP/5%Mg (PT5M), PLGA/TCP/10%Mg (PT10M), and PLGA/TCP/15%Mg (PT15M). The bacterial adhesion and biofilm formation of Staphylococcus aureus were evaluated. The results indicated that the Mg-based scaffolds significantly inhibited bacterial adhesion and biofilm formation compared to PT, and the PT10M and PT15M exhibited significantly stronger anti-biofilm ability than PT5M. In vitro degratation tests revealed that the degradation of the Mg-based scaffolds caused an increase of pH, Mg2+ concentration and osmolality, and the increased pH may be one of the major contributing factors to the antibacterial function of the Mg-based scaffolds. Additionally, the PT15M exhibited an inhibitory effect on cell adhesion and proliferation of MC3T3-E1 cells. In conclusion, the PLGA/TCP/Mg scaffolds could inhibit bacterial adhesion and biofilm formation, and the PT10M scaffold was considered to be an effective composition with considerable antibacterial ability and good cytocompatibility. PMID:26346217
Xie, Xiuqiang; Chen, Shuangqiang; Sun, Bing; Wang, Chengyin; Wang, Guoxiu
2015-09-01
Low-cost and sustainable sodium-ion batteries are regarded as a promising technology for large-scale energy storage and conversion. The development of high-rate anode materials is highly desirable for sodium-ion batteries. The optimization of mass transport and electron transfer is crucial in the discovery of electrode materials with good high-rate performances. Herein, we report the synthesis of 3 D interconnected SnO2 /graphene aerogels with a hierarchically porous structure as anode materials for sodium-ion batteries. The unique 3 D architecture was prepared by a facile in situ process, during which cross-linked 3 D conductive graphene networks with macro-/meso-sized hierarchical pores were formed and SnO2 nanoparticles were dispersed uniformly on the graphene surface simultaneously. Such a 3 D functional architecture not only facilitates the electrode-electrolyte interaction but also provides an efficient electron pathway within the graphene networks. When applied as anode materials in sodium-ion batteries, the as-prepared SnO2 /graphene aerogel exhibited high reversible capacity, improved cycling performance compared to SnO2 , and promising high-rate capability.
NASA Astrophysics Data System (ADS)
Cooper, Gene R.
1988-06-01
White Phosphorous (WP) impregnated felt wedges are used as a payload in the M825 improved smoke projectile. An assumption made in this work in that the WP is in a liquid state (i.e., temperature greater than 44 degrees C) where such payloads have been seen to cause flight instabilities. The analytical results given here formulate an initial effort to gain an understanding of the dynamics of a projectile interacting with a WP/felt payload. The analytical methods used here are a simple extension of previous methods used to describe bulk-filled liquid payloads. Moments are predicted due to an inviscid liquid moving through a ridged porous medium which is confined to a spinning cylindrical cavity undergoing coning motion. A drag term is added to the classical Stewartson theory which is used to describe the flow in the porous media. The cylindrical cavity is assumed to consist of several chambers of circular cross section and uniform height, each separated by solid endcaps. This porous media theory is used to calculate the total liquid side moments exerted by all the chambers in the cylinder. Results are presented for a range of coning frequencies, fineness ratios, and porous drag coefficients.
Moortgat, Joachim Firoozabadi, Abbas
2013-10-01
Numerical simulation of multiphase compositional flow in fractured porous media, when all the species can transfer between the phases, is a real challenge. Despite the broad applications in hydrocarbon reservoir engineering and hydrology, a compositional numerical simulator for three-phase flow in fractured media has not appeared in the literature, to the best of our knowledge. In this work, we present a three-phase fully compositional simulator for fractured media, based on higher-order finite element methods. To achieve computational efficiency, we invoke the cross-flow equilibrium (CFE) concept between discrete fractures and a small neighborhood in the matrix blocks. We adopt the mixed hybrid finite element (MHFE) method to approximate convective Darcy fluxes and the pressure equation. This approach is the most natural choice for flow in fractured media. The mass balance equations are discretized by the discontinuous Galerkin (DG) method, which is perhaps the most efficient approach to capture physical discontinuities in phase properties at the matrix-fracture interfaces and at phase boundaries. In this work, we account for gravity and Fickian diffusion. The modeling of capillary effects is discussed in a separate paper. We present the mathematical framework, using the implicit-pressure-explicit-composition (IMPEC) scheme, which facilitates rigorous thermodynamic stability analyses and the computation of phase behavior effects to account for transfer of species between the phases. A deceptively simple CFL condition is implemented to improve numerical stability and accuracy. We provide six numerical examples at both small and larger scales and in two and three dimensions, to demonstrate powerful features of the formulation.
NASA Astrophysics Data System (ADS)
Meisenheimer, D.; Brueck, C. L.; Wildenschild, D.
2015-12-01
X-ray microtomography imaging of fluid-fluid interfaces in three-dimensional porous media allows for the testing of thermodynamically derived predictions that seek a unique relationship between capillary pressure, fluid saturation, and specific interfacial area (Pc-Sw-Anw). Previous experimental studies sought to test this functional dependence under quasi-equilibrium conditions (assumed static on the imaging time-scale); however, applying predictive models developed under static conditions for dynamic scenarios can lead to substantial flaws in predicted outcomes. Theory and models developed using dynamic data can be verified using fast x-ray microtomography which allows for the unprecedented measurement of developing interfacial areas, curvatures, and trapping behaviors of fluid phases in three-dimensional systems. We will present results of drainage and imbibition experiments of air and water within a mixture of glass beads. The experiments were performed under both quasi-equilibrium and dynamic conditions at the Advanced Photon Source (APS) at Argonne National Laboratory. Fast x-ray microtomography was achieved by utilizing the high brilliance of the x-ray beam at the APS under pink-beam conditions where the white beam is modified with a 4 mm Al absorber and a 0.8 mrad Pt-coated mirror to eliminate low and high-energy photons, respectively. We present a comparison of the results from the quasi-equilibrium and dynamic experiments in an effort to determine if the Pc-Sw-Anw relationship is comparable under either experimental condition and to add to the discussion on whether the Pc-Sw-Anw relationship is unique as hypothesized by existing theory.
Instability of plane-parallel flow of incompressible liquid over a saturated porous medium
NASA Astrophysics Data System (ADS)
Lyubimova, T. P.; Lyubimov, D. V.; Baydina, D. T.; Kolchanova, E. A.; Tsiberkin, K. B.
2016-07-01
The linear stability of plane-parallel flow of an incompressible viscous fluid over a saturated porous layer is studied to model the instability of water flow in a river over aquatic plants. The saturated porous layer is bounded from below by a rigid plate and the pure fluid layer has a free, undeformable upper boundary. A small inclination of the layers is imposed to simulate the riverbed slope. The layers are inclined at a small angle to the horizon. The problem is studied within two models: the Brinkman model with the boundary conditions by Ochoa-Tapia and Whitaker at the interface, and the Darcy-Forchheimer model with the conditions by Beavers and Joseph. The neutral curves and critical Reynolds numbers are calculated for various porous layer permeabilities and relative thicknesses of the porous layer. The results obtained within the two models are compared and analyzed.
Instability of plane-parallel flow of incompressible liquid over a saturated porous medium.
Lyubimova, T P; Lyubimov, D V; Baydina, D T; Kolchanova, E A; Tsiberkin, K B
2016-07-01
The linear stability of plane-parallel flow of an incompressible viscous fluid over a saturated porous layer is studied to model the instability of water flow in a river over aquatic plants. The saturated porous layer is bounded from below by a rigid plate and the pure fluid layer has a free, undeformable upper boundary. A small inclination of the layers is imposed to simulate the riverbed slope. The layers are inclined at a small angle to the horizon. The problem is studied within two models: the Brinkman model with the boundary conditions by Ochoa-Tapia and Whitaker at the interface, and the Darcy-Forchheimer model with the conditions by Beavers and Joseph. The neutral curves and critical Reynolds numbers are calculated for various porous layer permeabilities and relative thicknesses of the porous layer. The results obtained within the two models are compared and analyzed. PMID:27575214
Instability of plane-parallel flow of incompressible liquid over a saturated porous medium.
Lyubimova, T P; Lyubimov, D V; Baydina, D T; Kolchanova, E A; Tsiberkin, K B
2016-07-01
The linear stability of plane-parallel flow of an incompressible viscous fluid over a saturated porous layer is studied to model the instability of water flow in a river over aquatic plants. The saturated porous layer is bounded from below by a rigid plate and the pure fluid layer has a free, undeformable upper boundary. A small inclination of the layers is imposed to simulate the riverbed slope. The layers are inclined at a small angle to the horizon. The problem is studied within two models: the Brinkman model with the boundary conditions by Ochoa-Tapia and Whitaker at the interface, and the Darcy-Forchheimer model with the conditions by Beavers and Joseph. The neutral curves and critical Reynolds numbers are calculated for various porous layer permeabilities and relative thicknesses of the porous layer. The results obtained within the two models are compared and analyzed.
Hindered nanoparticle diffusion and void accessibility in a three-dimensional porous medium.
Skaug, Michael J; Wang, Liang; Ding, Yifu; Schwartz, Daniel K
2015-02-24
The inherent pore-scale heterogeneity of many natural and synthetic porous materials can make it difficult to model and predict porous transport because the underlying microscopic processes are often poorly understood. Here we present the results of single-particle tracking experiments in which we followed the pore-scale diffusion of individual nanoparticles, deep within a three-dimensional porous material of moderate porosity. We observed significant hydrodynamic damping of particle motion at subpore length scales, resulting in heterogeneous and spatially dependent mobility. The accessibility of the void space was strongly dependent on particle size, and related to the heterogeneous hydrodynamics. Our results suggest that pore-scale diffusion is more heterogeneous and volume accessibility more limited than previously expected. The method demonstrated here will enable studies of a broad new class of materials including porous polymers of technological interest.
Cheng, Alice; Humayun, Aiza; Cohen, David J.; Boyan, Barbara D.; Schwartz, Zvi
2014-01-01
Additive manufacturing by laser sintering is able to produce high resolution metal constructs for orthopaedic and dental implants. In this study, we used a human trabecular bone template to design and manufacture Ti-6Al-4V constructs with varying porosity via laser sintering. Characterization of constructs revealed interconnected porosities ranging from 15–70% with compressive moduli of 2063–2954 MPa. These constructs with macro porosity were further surface-treated to create a desirable multi-scale micro-/nano-roughness, which has been shown to enhance the osseointegration process. Osteoblasts (MG63 cells) exhibited high viability when grown on the constructs. Proliferation (DNA) and alkaline phosphatase specific activity (ALP), an early differentiation marker, decreased as porosity increased, while osteocalcin (OCN), a late differentiation marker, as well as osteoprotegerin (OPG), vascular endothelial growth factor (VEGF) and bone morphogenetic proteins 2 and 4 (BMP2, BMP4) increased with increasing porosity. 3D constructs with the highest porosity and surface modification supported the greatest osteoblast differentiation and local factor production. These results indicate that additively manufactured 3D porous constructs mimicking human trabecular bone and produced with additional surface treatment can be customized for increased osteoblast response. Increased factors for osteoblast maturation and differentiation on high porosity constructs suggest the enhanced performance of these surfaces for increasing osseointegration in vivo. PMID:25287305
NASA Astrophysics Data System (ADS)
Roux, Nicolas; Grenier, Christophe; Costard, François
2015-04-01
In permafrost-affected regions, hydrological changes due to global warming are still under investigation. But yet, we can already foresee from recent studies that for example, the variability and intensity of surface/subsurface flow are likely to be affected by permafrost degradation. The feedback induced by such changes on permafrost degradation is still not clearly assessed. Of particular interest are lake and river's taliks. A talik is a permanently unfrozen zone that lies below rivers or lakes. They are likely to play a key role in the formerly presented interactions, given that they are the only paths for groundwater flow in permafrost regions. Thus heat transfers on a regional scale are influenced by groundwater circulation. The aim of our study is therefore to investigate the evolution of river's taliks. In addition, they are the only perennial liquid water resources in continuous permafrost environments. The issue associated is to what extent can taliks develop into the future because of climate change and how likely are they to become open taliks, connecting sub-permafrost water with surface water with potentially strong geochemical changes? We developed a multidisciplinary approach coupling field investigation, experimental studies in a cold room and numerical modeling. The field investigation concerns Central Yakutia, Siberia, where we have installed instruments to monitor ground temperatures and water pressure in a small river's talik between two thermokarst lakes. We present here the results corresponding to the cold room experimental work, associating numerical modeling and laboratory experiments in order to look after the main parameters controlling river's talik installation and validate our numerical simulation approach. In a cold room at GEOPS, where a metric scale channel is filled with a porous medium (sand or silty-clay), we are able to control air, water and permafrost initial temperature, but also water flow. At initial time, the "river
NASA Astrophysics Data System (ADS)
Hasan, Raisul
2016-07-01
In this research paper firstly theoretical analysis and design of the porous matrix for filtration and selection of associated liquid (highly viscous and low viscous liquid) is carried out. Hence, porosity of the bed has been found out followed by a detailed CFD analysis of the flow to identify displacement structure (fingering: due to the nonlinear interactions among viscous, capillary and gravitational forces). Moreover, an experiment will be with synthetic porous medium consists of a single layer of glass beads which are then positioned homogeneously or non-homogeneously between two Perspex sheets and then fluid displacement structure/fingering will be photographed. Then the effort will be made to validate results with the experiment based photograph and then the CFD model will be extended to microgravity condition KEYWORDS: CFD, Fingering, microgravity, Non-homogeneously, Capillary .
NASA Astrophysics Data System (ADS)
Zubair Akbar, Muhammad; Ashraf, Muhammad; Farooq Iqbal, Muhammad; Ali, Kashif
2016-04-01
The paper presents the numerical study of heat and mass transfer analysis in a viscous unsteady MHD nanofluid flow through a channel with porous walls and medium in the presence of metallic nanoparticles. The two cases for effective thermal conductivity are discussed in the analysis through H-C model. The impacts of the governing parameters on the flow, heat and mass transfer aspects of the issue are talked about. Under the patronage of small values of permeable Reynolds number and relaxation/contraction parameter, we locate that, when wall contraction is together with suction, flow turning is encouraged close to the wall where the boundary layer is shaped. On the other hand, when the wall relaxation is coupled with injection, the flow adjacent to the porous walls decreased. The outcome of the exploration may be beneficial for applications of biotechnology. Numerical solutions for the velocity, heat and mass transfer rate at the boundary are obtained and analyzed.
Hibi, Yoshihiko; Tomigashi, Akira
2015-09-01
Numerical simulations that couple flow in a surface fluid with that in a porous medium are useful for examining problems of pollution that involve interactions among atmosphere, water, and groundwater, including saltwater intrusion along coasts. Coupled numerical simulations of such problems must consider both vertical flow between the surface fluid and the porous medium and complicated boundary conditions at their interface. In this study, a numerical simulation method coupling Navier-Stokes equations for surface fluid flow and Darcy equations for flow in a porous medium was developed. Then, the basic ability of the coupled model to reproduce (1) the drawdown of a surface fluid observed in square-pillar experiments, using pillars filled with only fluid or with fluid and a porous medium and (2) the migration of saltwater (salt concentration 0.5%) in the porous medium using the pillar filled with fluid and a porous medium was evaluated. Simulations that assumed slippery walls reproduced well the results with drawdowns of 10-30 cm when the pillars were filled with packed sand, gas, and water. Moreover, in the simulation of saltwater infiltration by the method developed in this study, velocity was precisely reproduced because the experimental salt concentration in the porous medium after saltwater infiltration was similar to that obtained in the simulation. Furthermore, conditions across the boundary between the porous medium and the surface fluid were satisfied in these numerical simulations of square-pillar experiments in which vertical flow predominated. Similarly, the velocity obtained by the simulation for a system coupling flow in surface fluid with that in a porous medium when horizontal flow predominated satisfied the conditions across the boundary. Finally, it was confirmed that the present simulation method was able to simulate a practical-scale surface fluid and porous medium system. All of these numerical simulations, however, required a great deal of
NASA Astrophysics Data System (ADS)
Butt, A. S.; Tufail, M. N.; Ali, Asif
2016-03-01
A three-dimensional flow of a magnetohydrodynamic Casson fluid over an unsteady stretching surface placed into a porous medium is examined. Similarity transformations are used to convert time-dependent partial differential equations into nonlinear ordinary differential equations. The transformed equations are then solved analytically by the homotopy analysis method and numerically by the shooting technique combined with the Runge-Kutta-Fehlberg method. The results obtained by both methods are compared with available reported data. The effects of the Casson fluid parameter, magnetic field parameter, and unsteadiness parameter on the velocity and local skin friction coefficients are discussed in detail.
Hayat, Tasawar; Awais, Muhammad; Imtiaz, Amna
2016-01-01
This communication deals with the properties of heat source/sink in a magneto-hydrodynamic flow of a non-Newtonian fluid immersed in a porous medium. Shrinking phenomenon along with the permeability of the wall is considered. Mathematical modelling is performed to convert the considered physical process into set of coupled nonlinear mathematical equations. Suitable transformations are invoked to convert the set of partial differential equations into nonlinear ordinary differential equations which are tackled numerically for the solution computations. It is noted that dual solutions for various physical parameters exist which are analyzed in detail. PMID:27598314
NASA Astrophysics Data System (ADS)
Rauf, A.; Ashraf, M.; Batool, K.; Hussain, M.; Meraj, M. A.
2015-07-01
This article studies the simultaneous impacts of heat and mass transfer of an incompressible electrically conducting micropolar fluid generated by the stretchable disk in presence of porous medium. The thermal radiation effect is accounted via Rosseland's approximation. The governing boundary layer equations are reduced into dimensionless form by employing the suitable similarity transformations. A finite difference base algorithm is utilized to obtain the solution expressions. The impacts of physical parameters on dimensionless axial velocity, radial velocity, micro-rotation, temperature and concentrations profiles are presented and examined carefully. Numerical computation is performed to compute shear stress, couple stress, heat and mass rate at the disk.
Rauf, A. Meraj, M. A.; Ashraf, M.; Batool, K.; Hussain, M.
2015-07-15
This article studies the simultaneous impacts of heat and mass transfer of an incompressible electrically conducting micropolar fluid generated by the stretchable disk in presence of porous medium. The thermal radiation effect is accounted via Rosseland’s approximation. The governing boundary layer equations are reduced into dimensionless form by employing the suitable similarity transformations. A finite difference base algorithm is utilized to obtain the solution expressions. The impacts of physical parameters on dimensionless axial velocity, radial velocity, micro-rotation, temperature and concentrations profiles are presented and examined carefully. Numerical computation is performed to compute shear stress, couple stress, heat and mass rate at the disk.
Hayat, Tasawar; Awais, Muhammad; Imtiaz, Amna
2016-01-01
This communication deals with the properties of heat source/sink in a magneto-hydrodynamic flow of a non-Newtonian fluid immersed in a porous medium. Shrinking phenomenon along with the permeability of the wall is considered. Mathematical modelling is performed to convert the considered physical process into set of coupled nonlinear mathematical equations. Suitable transformations are invoked to convert the set of partial differential equations into nonlinear ordinary differential equations which are tackled numerically for the solution computations. It is noted that dual solutions for various physical parameters exist which are analyzed in detail. PMID:27598314
Ismail, Zulkhibri; Khan, Ilyas; Nasir, Nadirah Mohd; Awang, Rahimah Jusoh; Salleh, Mohd Zuki; Shafie, Sharidan
2015-02-03
An analysis of the exact solutions of second grade fluid problem for unsteady magnetohydrodynamic (MHD) flows past an infinite inclined plate in a porous medium is presented. It is assumed that the bounding infinite inclined plate has a constant temperature with radiation effects. Based on Boussinesq approximation the expressions for dimensionless velocity, temperature and concentration are obtained by using Laplace transform method. The derived solutions satisfying the involved differential equations, and all the boundary and initial conditions. The influence of various parameters on the velocity has been illustrated graphically and analyzed.
NASA Astrophysics Data System (ADS)
Filo, Ján; Hundertmark-Zaušková, Anna
2016-10-01
The aim of this paper is to design a rescaling algorithm for the numerical solution to the system of two porous medium equations defined on two different components of the real line, that are connected by the nonlinear contact condition. The algorithm is based on the self-similarity of solutions on different scales and it presents a space-time adaptable method producing more exact numerical solution in the area of the interface between the components, whereas the number of grid points stays fixed.
On the stability and uniqueness of the flow of a fluid through a porous medium
NASA Astrophysics Data System (ADS)
Hill, A. A.; Rajagopal, K. R.; Vergori, L.
2016-06-01
In this short note, we study the stability of flows of a fluid through porous media that satisfies a generalization of Brinkman's equation to include inertial effects. Such flows could have relevance to enhanced oil recovery and also to the flow of dense liquids through porous media. In any event, one cannot ignore the fact that flows through porous media are inherently unsteady, and thus, at least a part of the inertial term needs to be retained in many situations. We study the stability of the rest state and find it to be asymptotically stable. Next, we study the stability of a base flow and find that the flow is asymptotically stable, provided the base flow is sufficiently slow. Finally, we establish results concerning the uniqueness of the flow under appropriate conditions, and present some corresponding numerical results.
Determining Pore Pressures Along a Slip Surface Within a Saturated Elastic-Plastic Porous Medium
NASA Astrophysics Data System (ADS)
Viesca, R. C.; Rice, J. R.; Dunham, E. M.
2008-12-01
Here we consider shear rupture along a slip surface in a fluid-saturated elastic-plastic porous medium, like in landslide and earthquake modeling, and assume that there are different poro-elasto-plastic response properties on the two sides of the slip surface. This different response may be because the fault bordering materials are dissimilar, or just because one side is actively yielding and the other is not, or is yielding but in a different mode. In effect, we are representing a core about a slip surface that divides two similar or contrasting materials. This representation is especially relevant in earthquake rupture dynamics. Studies of mature fault zones have noted a trend of fractured host rock extending 10--100m from the fault, with an ultracataclastic core ~100mm about or to one side of the principal slip surface (e.g., Chester and Chester, Tectonophys, 1998; Chester et al., Columbia Univ Pr, 2004). Furthermore, there is likely to exist a material contrast that may come from accumulating km of slip and a bias in accumulated damage. The local pore pressure at the slip surface influences the rupture dynamics because, through the effective stress concept, it controls the local shear strength along the fault, a feature neglected as a simplification in our preliminary poro-elasto-plastic modeling of dynamic rupture (Viesca et al., JGR, 2008). To determine pore pressures at the slip surface under locally elastic-plastic response, we must consider pore pressure discontinuities about that surface that arise in an undrained treatment of off-fault material and their amelioration within resulting thin diffusive boundary layers, such that pore pressure and fluid mass flux in the normal direction are continuous at the slip surface. Our approach builds on previous work considering the effect of contrasts in poroelastic properties on rupture propagation (Rudnicki and Rice, JGR, 2006; Dunham and Rice, JGR, 2008). Here we find expressions for the undrained pore pressure
Study of the fluid flow characteristics in a porous medium for CO2 geological storage using MRI.
Song, Yongchen; Jiang, Lanlan; Liu, Yu; Yang, Mingjun; Zhou, Xinhuan; Zhao, Yuechao; Dou, Binlin; Abudula, Abuliti; Xue, Ziqiu
2014-06-01
The objective of this study was to understand fluid flow in porous media. Understanding of fluid flow process in porous media is important for the geological storage of CO2. The high-resolution magnetic resonance imaging (MRI) technique was used to measure fluid flow in a porous medium (glass beads BZ-02). First, the permeability was obtained from velocity images. Next, CO2-water immiscible displacement experiments using different flow rates were investigated. Three stages were obtained from the MR intensity plot. With increasing CO2 flow rate, a relatively uniform CO2 distribution and a uniform CO2 front were observed. Subsequently, the final water saturation decreased. Using core analysis methods, the CO2 velocities were obtained during the CO2-water immiscible displacement process, which were applied to evaluate the capillary dispersion rate, viscous dominated fractional flow, and gravity flow function. The capillary dispersion rate dominated the effects of capillary, which was largest at water saturations of 0.5 and 0.6. The viscous-dominant fractional flow function varied with the saturation of water. The gravity fractional flow reached peak values at the saturation of 0.6. The gravity forces played a positive role in the downward displacements because they thus tended to stabilize the displacement process, thereby producing increased breakthrough times and correspondingly high recoveries. Finally, the relative permeability was also reconstructed. The study provides useful data regarding the transport processes in the geological storage of CO2.
Nonlinear Stress/Strain Behavior of a Synthetic Porous Medium at Seismic Frequencies
NASA Astrophysics Data System (ADS)
Roberts, P. M.; Ibrahim, R. H.
2008-12-01
Laboratory experiments on porous core samples have shown that seismic-band (100 Hz or less) mechanical, axial stress/strain cycling of the porous matrix can influence the transport behavior of fluids and suspended particles during steady-state fluid flow through the cores. In conjunction with these stimulated transport experiments, measurements of the applied dynamic axial stress/strain were made to investigate the nonlinear mechanical response of porous media for a poorly explored range of frequencies from 1 to 40 Hz. A unique core-holder apparatus that applies low-frequency mechanical stress/strain to 2.54-cm-diameter porous samples during constant-rate fluid flow was used for these experiments. Applied stress was measured with a load cell in series with the source and porous sample, and the resulting strain was measured with an LVDT attached to the core face. A synthetic porous system consisting of packed 1-mm-diameter glass beads was used to investigate both stress/strain and stimulated mass-transport behavior under idealized conditions. The bead pack was placed in a rubber sleeve and static confining stresses of 2.4 MPa radial and 1.7 MPa axial were applied to the sample. Sinusoidal stress oscillations were applied to the sample at 1 to 40 Hz over a range of RMS stress amplitude from 37 to 275 kPa. Dynamic stress/strain was measured before and after the core was saturated with deionized water. The slope of the linear portion of each stress/strain hysteresis loop was used to estimate Young's modulus as a function of frequency and amplitude for both the dry and wet sample. The modulus was observed to increase after the dry sample was saturated. For both dry and wet cases, the modulus decreased with increasing dynamic RMS stress amplitude at a constant frequency of 23 Hz. At constant RMS stress amplitude, the modulus increased with increasing frequency for the wet sample but remained constant for the dry sample. The observed nonlinear behavior of Young's modulus
NASA Astrophysics Data System (ADS)
Pletinckx, D.
2011-09-01
The current 3D hype creates a lot of interest in 3D. People go to 3D movies, but are we ready to use 3D in our homes, in our offices, in our communication? Are we ready to deliver real 3D to a general public and use interactive 3D in a meaningful way to enjoy, learn, communicate? The CARARE project is realising this for the moment in the domain of monuments and archaeology, so that real 3D of archaeological sites and European monuments will be available to the general public by 2012. There are several aspects to this endeavour. First of all is the technical aspect of flawlessly delivering 3D content over all platforms and operating systems, without installing software. We have currently a working solution in PDF, but HTML5 will probably be the future. Secondly, there is still little knowledge on how to create 3D learning objects, 3D tourist information or 3D scholarly communication. We are still in a prototype phase when it comes to integrate 3D objects in physical or virtual museums. Nevertheless, Europeana has a tremendous potential as a multi-facetted virtual museum. Finally, 3D has a large potential to act as a hub of information, linking to related 2D imagery, texts, video, sound. We describe how to create such rich, explorable 3D objects that can be used intuitively by the generic Europeana user and what metadata is needed to support the semantic linking.
NASA Astrophysics Data System (ADS)
Swarnalathamma, B. V.; Krishna, M. Veera
2016-05-01
In this paper, we discussed the theoretical and computational study of peristaltic hemodynamic flow of couple stress fluids through a porous medium under the influence of magnetic field with wall slip condition. Actually this study is motivated towards the physiological flow of the blood in the micro circulatory system by taking account of the particle size effect. We consider the Reynolds number is small enough and the wave length to diameter ratio is large enough to negate inertial effects. The governing equations for the couple stress fluid flow through porous medium based on stoke constitutive equations and Brinkman model. The exact solutions for axial velocity, pressure gradient, frictional force, stream function and mechanical efficiency are obtained analytically, its behaviour computationally discussed with reference to different physical parameters reflecting couple stress parameter, Hartmann number, permeability parameter, slip parameter as well as amplitude ratio on pumping characteristics and frictional force, stream lines pattern and trapping of peristaltic flow pattern are studied with particular emphasis making use of graphs.
Chen, Jui-Sheng; Liu, Chen-Wuing
2004-08-01
A reactive fluid circulating within a porous medium can dissolve minerals with which it is out of equilibrium and modify the porosity and permeability. The positive feedback between fluid transport and mineral dissolution causes complex reaction front morphologies such as fingers or wormholes. This study presents a numerical model to investigate reaction front instability, temporal aquifer porosity, and species concentration evolution during reactive transport in a homogeneous porous medium with two small, initially local non-uniformities. Simulation results indicate that a stable planar front develops for a small upstream pressure gradient while the growth of two non-uniformities becomes unstable for a large upstream pressure gradient. Moreover, the unstable reaction front may be either double- or single-finger in shape. Reaction front shape selection depends on the spacing of the two local non-uniformities and the upstream pressure gradients. A behavior diagram is constructed to identify a planar, single- or double-front morphology. The critical non-uniformities spacing at which a reaction front begins to merge into a single-finger decreases with increasing upstream pressure gradient.
NASA Astrophysics Data System (ADS)
Yang, PeiPei; Wen, Zhi; Dou, RuiFeng; Liu, Xunliang
2016-08-01
Flow and heat transfer through a 2D random porous medium are studied by using the lattice Boltzmann method (LBM). For the random porous medium, the influence of disordered cylinder arrangement on permeability and Nusselt number are investigated. Results indicate that the permeability and Nusselt number for different cylinder locations are unequal even with the same number and size of cylinders. New correlations for the permeability and coefficient b‧Den of the Forchheimer equation are proposed for random porous medium composed of Gaussian distributed circular cylinders. Furthermore, a general set of heat transfer correlations is proposed and compared with existing experimental data and empirical correlations. Our results show that the Nu number increases with the increase of the porosity, hence heat transfer is found to be accurate considering the effect of porosity.
3d-3d correspondence revisited
NASA Astrophysics Data System (ADS)
Chung, Hee-Joong; Dimofte, Tudor; Gukov, Sergei; Sułkowski, Piotr
2016-04-01
In fivebrane compactifications on 3-manifolds, we point out the importance of all flat connections in the proper definition of the effective 3d {N}=2 theory. The Lagrangians of some theories with the desired properties can be constructed with the help of homological knot invariants that categorify colored Jones polynomials. Higgsing the full 3d theories constructed this way recovers theories found previously by Dimofte-Gaiotto-Gukov. We also consider the cutting and gluing of 3-manifolds along smooth boundaries and the role played by all flat connections in this operation.
3d-3d correspondence revisited
Chung, Hee -Joong; Dimofte, Tudor; Gukov, Sergei; Sułkowski, Piotr
2016-04-21
In fivebrane compactifications on 3-manifolds, we point out the importance of all flat connections in the proper definition of the effective 3d N = 2 theory. The Lagrangians of some theories with the desired properties can be constructed with the help of homological knot invariants that categorify colored Jones polynomials. Higgsing the full 3d theories constructed this way recovers theories found previously by Dimofte-Gaiotto-Gukov. As a result, we also consider the cutting and gluing of 3-manifolds along smooth boundaries and the role played by all flat connections in this operation.
NASA Astrophysics Data System (ADS)
Sakaguchi, Shigeru
2002-01-01
In previous papers we considered the Cauchy problem for the one-dimensional evolution p-Laplacian equation for nonzero, bounded, and nonnegative initial data having compact support, and showed that after a finite time the set of spatial critical points of the nonnegative solution u=u(x, t) in {u>0} consists of one point, the spatial maximum point of u, and the curve of the spatial maximum points is continuous with respect to the time variable. Since the spatial derivative ∂xu satisfies the porous medium equation with sign changes, the curve of the spatial maximum points is regarded as an interface with sign changes of ∂xu. On the other hand, in a paper by M. Bertsch and D. Hilhorst (1991, Appl. Anal.41, 111-130) the interfaces where the solutions change their sign were studied in detail for the initial-boundary value problems of the generalized porous medium equation over two-dimensional cylinders. But the monotonicity of the initial data is assumed there. As is noted in Section 4 of our earlier work (1996, J. Math. Anal. Appl.203, 78-103), the monotonicity of ∂xu(ċ, t) in some neighborhood of the spatial maximum point of u(ċ, t) cannot be assumed, and therefore, if this monotonicity for some large t>0 is proved, then by the method of Bertsch and Hilhorst (cited above) one may get more precise regularity properties of the curve of the spatial maximum points. The purpose of the present paper is twofold. One is to remove some monotonicity assumption for initial data in Bertsch and Hilhorst's theorem concerning the regularity of the interfaces with sign changes of solutions of the one-dimensional generalized porous medium equation. By comparing the solution with appropriate symmetric nonnegative solutions we shall get the monotonicity of the solution near the interface after a finite time. The other is as a by-product of the method to get C1 regularity of the curves of the spatial maximum points of nonnegative solutions of the Cauchy problem for the evolution
Dynamics of a liquid drop in porous medium saturated by another liquid under gravity
NASA Astrophysics Data System (ADS)
Ivantsov, A. O.; Lyubimova, T. P.
2016-02-01
The work deals with numerical simulations of settling or ascension process of a liquid drop in porous media saturated by another liquid. The calculations were carried out using the Darcy model by Level set method with adaptive mesh refinement algorithm that dynamically refines computational mesh near interface. It is shown that the drop is unstable and the finger instability develops at the forefront of moving drop for any ratio of the viscosities of liquids. Under modulated pressure gradient small-scale perturbations of interface are suppressed and in the case of modulation with large enough intensity drop becomes stable.
Modelling of 3D fractured geological systems - technique and application
NASA Astrophysics Data System (ADS)
Cacace, M.; Scheck-Wenderoth, M.; Cherubini, Y.; Kaiser, B. O.; Bloecher, G.
2011-12-01
All rocks in the earth's crust are fractured to some extent. Faults and fractures are important in different scientific and industry fields comprising engineering, geotechnical and hydrogeological applications. Many petroleum, gas and geothermal and water supply reservoirs form in faulted and fractured geological systems. Additionally, faults and fractures may control the transport of chemical contaminants into and through the subsurface. Depending on their origin and orientation with respect to the recent and palaeo stress field as well as on the overall kinematics of chemical processes occurring within them, faults and fractures can act either as hydraulic conductors providing preferential pathways for fluid to flow or as barriers preventing flow across them. The main challenge in modelling processes occurring in fractured rocks is related to the way of describing the heterogeneities of such geological systems. Flow paths are controlled by the geometry of faults and their open void space. To correctly simulate these processes an adequate 3D mesh is a basic requirement. Unfortunately, the representation of realistic 3D geological environments is limited by the complexity of embedded fracture networks often resulting in oversimplified models of the natural system. A technical description of an improved method to integrate generic dipping structures (representing faults and fractures) into a 3D porous medium is out forward. The automated mesh generation algorithm is composed of various existing routines from computational geometry (e.g. 2D-3D projection, interpolation, intersection, convex hull calculation) and meshing (e.g. triangulation in 2D and tetrahedralization in 3D). All routines have been combined in an automated software framework and the robustness of the approach has been tested and verified. These techniques and methods can be applied for fractured porous media including fault systems and therefore found wide applications in different geo-energy related
Vapour-liquid phase diagram for an ionic fluid in a random porous medium.
Holovko, M F; Patsahan, O; Patsahan, T
2016-10-19
We study the vapour-liquid phase behaviour of an ionic fluid confined in a random porous matrix formed by uncharged hard sphere particles. The ionic fluid is modelled as an equimolar binary mixture of oppositely charged equisized hard spheres, the so-called restricted primitive model (RPM). Considering the matrix-fluid system as a partly-quenched model, we develop a theoretical approach which combines the method of collective variables with the extension of the scaled-particle theory (SPT) for a hard-sphere fluid confined in a disordered hard-sphere matrix. The approach allows us to formulate the perturbation theory using the SPT for the description of the thermodynamics of the reference system. The phase diagrams of the RPM in matrices of different porosities and for different size ratios of matrix and fluid particles are calculated in the random-phase approximation and also when the effects of higher-order correlations between ions are taken into account. Both approximations correctly reproduce the basic effects of porous media on the vapour-liquid phase diagram, i.e. with a decrease of porosity the critical point shifts towards lower fluid densities and lower temperatures and the coexistence region gets narrower. For the fixed matrix porosity, both the critical temperature and the critical density increase with an increase of size of matrix particles and tend to the critical values of the bulk RPM. PMID:27548356
Vapour-liquid phase diagram for an ionic fluid in a random porous medium
NASA Astrophysics Data System (ADS)
Holovko, M. F.; Patsahan, O.; Patsahan, T.
2016-10-01
We study the vapour-liquid phase behaviour of an ionic fluid confined in a random porous matrix formed by uncharged hard sphere particles. The ionic fluid is modelled as an equimolar binary mixture of oppositely charged equisized hard spheres, the so-called restricted primitive model (RPM). Considering the matrix-fluid system as a partly-quenched model, we develop a theoretical approach which combines the method of collective variables with the extension of the scaled-particle theory (SPT) for a hard-sphere fluid confined in a disordered hard-sphere matrix. The approach allows us to formulate the perturbation theory using the SPT for the description of the thermodynamics of the reference system. The phase diagrams of the RPM in matrices of different porosities and for different size ratios of matrix and fluid particles are calculated in the random-phase approximation and also when the effects of higher-order correlations between ions are taken into account. Both approximations correctly reproduce the basic effects of porous media on the vapour-liquid phase diagram, i.e. with a decrease of porosity the critical point shifts towards lower fluid densities and lower temperatures and the coexistence region gets narrower. For the fixed matrix porosity, both the critical temperature and the critical density increase with an increase of size of matrix particles and tend to the critical values of the bulk RPM.
NASA Astrophysics Data System (ADS)
Grančič, Peter; Štěpánek, František
2011-08-01
The multibody dynamics of a system of chemical swarm robots in a porous environment is investigated. The chemical swarm robots are modeled as Brownian particles capable of delivering an encapsulated chemical payload toward a given target location and releasing it in response to an external stimulus. The presence of chemical signals (chemo-attractant) in the system plays a crucial role in coordinating the collective movement of the particles via chemotaxis. For a number of applications, such as distributed chemical processing and targeted drug delivery, the understanding of factors that govern the collective behavior of the particles, especially their ability to localize a given target, is of immense importance. A hybrid modeling methodology based on the combination of the Brownian dynamics method and diffusion problem coupled through the chemotaxis phenomena is used to analyze the impact of a varying signaling threshold and the strength of chemotaxis on the ability of the chemical robots to fulfill their target localization mission. The results demonstrate that the selected performance criteria (the localization half time and the success rate) can be improved when an appropriate signaling process is chosen. Furthermore, for an optimum target localization strategy, the topological complexity of the porous environment needs to be reflected.
NASA Astrophysics Data System (ADS)
Meulien Ohlmann, Odile
2013-02-01
Today the industry offers a chain of 3D products. Learning to "read" and to "create in 3D" becomes an issue of education of primary importance. 25 years professional experience in France, the United States and Germany, Odile Meulien set up a personal method of initiation to 3D creation that entails the spatial/temporal experience of the holographic visual. She will present some different tools and techniques used for this learning, their advantages and disadvantages, programs and issues of educational policies, constraints and expectations related to the development of new techniques for 3D imaging. Although the creation of display holograms is very much reduced compared to the creation of the 90ies, the holographic concept is spreading in all scientific, social, and artistic activities of our present time. She will also raise many questions: What means 3D? Is it communication? Is it perception? How the seeing and none seeing is interferes? What else has to be taken in consideration to communicate in 3D? How to handle the non visible relations of moving objects with subjects? Does this transform our model of exchange with others? What kind of interaction this has with our everyday life? Then come more practical questions: How to learn creating 3D visualization, to learn 3D grammar, 3D language, 3D thinking? What for? At what level? In which matter? for whom?
Khan, Arshad; Khan, Ilyas; Ali, Farhad; ulhaq, Sami; Shafie, Sharidan
2014-01-01
This study investigates the effects of an arbitrary wall shear stress on unsteady magnetohydrodynamic (MHD) flow of a Newtonian fluid with conjugate effects of heat and mass transfer. The fluid is considered in a porous medium over a vertical plate with ramped temperature. The influence of thermal radiation in the energy equations is also considered. The coupled partial differential equations governing the flow are solved by using the Laplace transform technique. Exact solutions for velocity and temperature in case of both ramped and constant wall temperature as well as for concentration are obtained. It is found that velocity solutions are more general and can produce a huge number of exact solutions correlative to various fluid motions. Graphical results are provided for various embedded flow parameters and discussed in details. PMID:24621775
NASA Astrophysics Data System (ADS)
Govardhan, K.; Kaladhar, K.; Nagaraju, G.; Balaswamy, B.
2014-12-01
This paper examines the effect of MHD, and injection through one side of a long vertical channel embedded in porous medium with transpiration cooling. The governing nonlinear partial differential equations have been transformed by similarity transformation into a set of ordinary differential equations, which are solved numerically by Adam-moultan Predictor-Corrector method with Newton-Raphson Method for missing initial conditions. Proflles of dimensionless velocity, temperature and concentration are shown graphically for different parameters entering into the analysis. Also the effects of the pertinent parameters on the heat transfer rates are tabulated. An analysis of the results obtained shows that the flow field is influenced appreciably by emerging parameters of the present study.
Gray, William G.
2008-01-01
This work is the fourth in a series of papers on the thermodynamically constrained averaging theory (TCAT) approach for modeling flow and transport phenomena in multiscale porous medium systems. The general TCAT framework and the mathematical foundation presented in previous works are built upon by formulating macroscale models for conservation of mass, momentum, and energy, and the balance of entropy for a species in a phase volume, interface, and common curve. In addition, classical irreversible thermodynamic relations for species in entities are averaged from the microscale to the macroscale. Finally, we comment on alternative approaches that can be used to connect species and entity conservation equations to a constrained system entropy inequality, which is a key component of the TCAT approach. The formulations detailed in this work can be built upon to develop models for species transport and reactions in a variety of multiphase systems. PMID:19255613
NASA Astrophysics Data System (ADS)
Sharma, Rajesh; Bhargava, Rama
2015-07-01
In this article, the two-dimensional boundary layer problem of Hiemenz flow (two-dimensional flow of a fluid near a stagnation point) of an incompressible micropolar fluid towards a nonlinear stretching surface placed in a porous medium in the presence of transverse magnetic field is examined. The resulting nonlinear differential equations governing the problem have been transformed by a similarity transformation into a system of nonlinear ordinary differential equations which are solved numerically by the Element Free Galerkin method. The influence of various parameters on the velocity, microrotation, temperature, and concentration is shown. Some of the results are compared with the Finite Element Method. Finally, validation of the numerical results is demonstrated for local skin friction ? for hydrodynamic micropolar fluid flow on a linearly stretching surface.
Taylor, S.W.; Jaffe, P.R. )
1990-09-01
An experimental investigaton was conducted to quantify the permeability reduction caused by enhanced biological growth in a porous medium. Studies were conducted using sand-packed column reactors for which variations in piezometric head, substrate concentration, and biomass measured as organic carbon were monitored in space and time. Methanol was used as a growth substrate. Permeability reductions by factors of order 10{sup {minus}3} were observed. The data show that a limit on permeability reduction exists, having a magnitude of 5 {times} 10{sup {minus}4} in the present study. The limit on permeability reduction and the existence of high densities of bacteria in substrate depleted zones are explained with an open pore model. Permeability reduction was observed to correlate well with biomass density for values less than about 0.4 mg/cm{sup 3}, and exhibited independence at higher densities.
NASA Astrophysics Data System (ADS)
Khalid Aurangzaib, M.; Bhattacharyya, Krishnendu; Shafie, Sharidan
2016-06-01
The characteristics of the unsteady boundary layer flow with melting heat transfer near a stagnation-point towards a flat plate embedded in a DarcyBrinkman porous medium with thermal radiation are investigated. The governing partial differential equations are transformed into self-similar ordinary differential equations by similarity transformations. The transformed self-similar equations are solved numerically using bvp4c from Matlab for several values of the flow parameters. The study reveals that the multiple solutions exist for the decelerating (A < 0) flow, whereas for the accelerating (A ≥ 0) flow, the solution is unique. The results also indicate that the melting phenomenon increases the rate of heat transfer and delays the boundary layer separation. To validate the current numerical results, comparison with available results is made and found to be in a good agreement.
Swarming behavior of gradient-responsive Brownian particles in a porous medium
NASA Astrophysics Data System (ADS)
Grančič, Peter; Štěpánek, František
2012-07-01
Active targeting by Brownian particles in a fluid-filled porous environment is investigated by computer simulation. The random motion of the particles is enhanced by diffusiophoresis with respect to concentration gradients of chemical signals released by the particles in the proximity of a target. The mathematical model, based on a combination of the Brownian dynamics method and a diffusion problem is formulated in terms of key parameters that include the particle diffusiophoretic mobility and the signaling threshold (the distance from the target at which the particles release their chemical signals). The results demonstrate that even a relatively simple chemical signaling scheme can lead to a complex collective behavior of the particles and can be a very efficient way of guiding a swarm of Brownian particles towards a target, similarly to the way colonies of living cells communicate via secondary messengers.
Swarming behavior of gradient-responsive Brownian particles in a porous medium.
Grančič, Peter; Štěpánek, František
2012-07-01
Active targeting by Brownian particles in a fluid-filled porous environment is investigated by computer simulation. The random motion of the particles is enhanced by diffusiophoresis with respect to concentration gradients of chemical signals released by the particles in the proximity of a target. The mathematical model, based on a combination of the Brownian dynamics method and a diffusion problem is formulated in terms of key parameters that include the particle diffusiophoretic mobility and the signaling threshold (the distance from the target at which the particles release their chemical signals). The results demonstrate that even a relatively simple chemical signaling scheme can lead to a complex collective behavior of the particles and can be a very efficient way of guiding a swarm of Brownian particles towards a target, similarly to the way colonies of living cells communicate via secondary messengers.
Experiment and theory for heterogeneous nucleation of protein crystals in a porous medium
NASA Astrophysics Data System (ADS)
Chayen, Naomi E.; Saridakis, Emmanuel; Sear, Richard P.
2006-01-01
The determination of high-resolution structures of proteins requires crystals of suitable quality. Because of the new impetus given to structural biology by structural genomics/proteomics, the problem of crystallizing proteins is becoming increasingly acute. There is therefore an urgent requirement for the development of new efficient methods to aid crystal growth. Nucleation is the crucial step that determines the entire crystallization process. Hence, the holy grail is to design a "universal nucleant," a substrate that induces the nucleation of crystals of any protein. We report a theory for nucleation on disordered porous media and its experimental testing and validation using a mesoporous bioactive gel-glass. This material induced the crystallization of the largest number of proteins ever crystallized using a single nucleant. The combination of the model and the experimental results opens up the scope for the rational design of nucleants, leading to alternative means of controlling crystallization. protein crystallization | phase diagram | microbatch | vapor diffusion
Evaluation of Porous Medium Permeability by Acoustic Logging Finds Geothermal Applications
Conche, B.; Lebreton, F.; Rojas, J.
1986-01-21
In a well, after an acoustic waveform has circulated through the surrounding porous media, the study of its alteration can help in evaluating their permeability. The treatment of the acoustic compressional wave's first three cycles yields a unique parameter called I-c. The recording of this I-c log all along any open hole interval is now possible by respecting some practical rules known by logging companies. Large flows of fluid found in geothermal low-enthalpy operations have provided an opportunity to check the validity of this method. Cumulative I-c derived permeability with depth (''EXAFLO'' log) correlates with the flowmeter log, as examples will show. Some new aspects of the theory underlying the I-c/permeability relationship have been developed and are described here.
Park, Byung Hyun; Lee, Myong-Hwa; Kim, Sang Bum; Kim, Gyung Soo; Jo, Young Min
2010-02-01
The high costs of ceramic and Teflon filter media for hot gas cleaning has limited their industrial applications. This paper presents a foam coating technology that can be used to produce an inexpensive and highly efficient filter for industrial applications. A new apparatus was designed and built that coats porous glass mats with liquid-phase polytetrafluoroethylene (PTFE). The machine generates bubbles, enables the formation of uniform micropores less than 45 microm in diameter, and produces a product with air permeability greater than 5.5 cm3/cm2/sec. The resulting filter was found to be thermally stable up to 270 degrees C without any visible distortion and was comparable in dust collection efficiency to other commercial filter media. In addition, its de-dusting efficiency was greater than 85%, which is similar to that of other test filter media.
NASA Astrophysics Data System (ADS)
Slob, E. C.; Grobbe, N.
2014-12-01
The theory of coupled elastic waves and electromagnetic fields in porous media exists for two decades. Several modeling codes have been developed and some field work has been carried out with mixed success. Modeling the so-called electroseismic and seismo-electromagnetic wavefields is tricky because of the strong elastic fields generated by mechanical sources and strong electromagnetic fields generated by electromagnetic sources, while the coupled fields have relatively small amplitudes. A second difficulty is the fact that the elastic field is essentially a wavefield, while the electromagnetic field is a diffusive field. The slow P-wave is usually also a diffusive field depending on the frequency bandwidth of the data. On the other hand, for porous soils and rocks, laboratory measurements have been carried out to experimentally validate the current theoretical model and to some extent this has been successful. To be able to understand measured data it is crucially important that we have good control on the accuracy of modeled data. Today we don't have this control, which makes it hard to judge the quality of the modeled data and trust the experimental validation of the theory. It is therefore important that exact solutions are found to validate modeling codes in simple configurations. These modeling codes can then numerically validate the theory by matching the results obtained in laboratory or field experiments. The simplest configuration is the homogeneous space and we show exact solutions for the governing equations for point sources and point receivers. These Green's functions are obtained for any type of point source and any type of receiver. We reduce the coupled equations to two scalar equations for the electric field and the particle velocity vectors. Solutions for longitudinal and transverse waves are obtained separately and these are combined to obtain the Green's functions for the electric field and the particle velocity, from which the solutions for
Clement, T.P.; Jones, N.L.
1998-02-01
RT3D (Reactive Transport in 3-Dimensions) is a computer code that solves coupled partial differential equations that describe reactive-flow and transport of multiple mobile and/or immobile species in a three dimensional saturated porous media. RT3D was developed from the single-species transport code, MT3D (DoD-1.5, 1997 version). As with MT3D, RT3D also uses the USGS groundwater flow model MODFLOW for computing spatial and temporal variations in groundwater head distribution. This report presents a set of tutorial problems that are designed to illustrate how RT3D simulations can be performed within the Department of Defense Groundwater Modeling System (GMS). GMS serves as a pre- and post-processing interface for RT3D. GMS can be used to define all the input files needed by RT3D code, and later the code can be launched from within GMS and run as a separate application. Once the RT3D simulation is completed, the solution can be imported to GMS for graphical post-processing. RT3D v1.0 supports several reaction packages that can be used for simulating different types of reactive contaminants. Each of the tutorials, described below, provides training on a different RT3D reaction package. Each reaction package has different input requirements, and the tutorials are designed to describe these differences. Furthermore, the tutorials illustrate the various options available in GMS for graphical post-processing of RT3D results. Users are strongly encouraged to complete the tutorials before attempting to use RT3D and GMS on a routine basis.
Dual-function growth medium and structural soil for use as porous pavement.
Sloan, John J; Hegemann, Mary Ann; George, Steve A
2008-01-01
Permeable grass-covered surfaces can reduce the quantity of storm water runoff and filter out potentially harmful chemicals. The objective of this study was to develop permeable structural soils that sustained healthy turf growth and filtered heavy metals from contaminated pavement runoff. The basic soil medium was a 50:50 mixture (v/v) of expanded shale (ExSh) and quartz sand (QS). The ExSh component consisted of (i) large-diameter particles (3-6 mm), (ii) small-diameter particles (1-3 mm), or (iii) a 50:50 mixture (v/v) of the two. The basic blends were mixed with 0, 10, and 20% sphagnum peat moss (v/v) and 0, 10, and 20% natural zeolites (v/v) and placed in 15-cm-diameter pots in a greenhouse. Bermudagrass plugs were planted in each pot. The addition of sphagnum peat moss to the basic ExSh/QS blend increased bermudagrass growth and improved plant response to added fertilizer. Zeolites had no significant effect on plant growth in the absence of sphagnum peat moss. Growing mediums that contained 10 to 20% sphagnum peat moss and 10 to 20% zeolites consistently produced more bermudagrass biomass than the unamended ExSh/QS mixture. Changing the ratio of small- to large-diameter ExSh in the basic medium did not affect bermudagrass yield. Very low amounts of Cd, Cu, Pb, and Zn were recovered in leachate after the addition of 10 mg metal per pot, suggesting that most heavy metals (>99%) were retained in the growing mediums. Zeolites reduced the amount of Cd and Pb in leachate water, but not Cu or Zn.
Dual-function growth medium and structural soil for use as porous pavement.
Sloan, John J; Hegemann, Mary Ann; George, Steve A
2008-01-01
Permeable grass-covered surfaces can reduce the quantity of storm water runoff and filter out potentially harmful chemicals. The objective of this study was to develop permeable structural soils that sustained healthy turf growth and filtered heavy metals from contaminated pavement runoff. The basic soil medium was a 50:50 mixture (v/v) of expanded shale (ExSh) and quartz sand (QS). The ExSh component consisted of (i) large-diameter particles (3-6 mm), (ii) small-diameter particles (1-3 mm), or (iii) a 50:50 mixture (v/v) of the two. The basic blends were mixed with 0, 10, and 20% sphagnum peat moss (v/v) and 0, 10, and 20% natural zeolites (v/v) and placed in 15-cm-diameter pots in a greenhouse. Bermudagrass plugs were planted in each pot. The addition of sphagnum peat moss to the basic ExSh/QS blend increased bermudagrass growth and improved plant response to added fertilizer. Zeolites had no significant effect on plant growth in the absence of sphagnum peat moss. Growing mediums that contained 10 to 20% sphagnum peat moss and 10 to 20% zeolites consistently produced more bermudagrass biomass than the unamended ExSh/QS mixture. Changing the ratio of small- to large-diameter ExSh in the basic medium did not affect bermudagrass yield. Very low amounts of Cd, Cu, Pb, and Zn were recovered in leachate after the addition of 10 mg metal per pot, suggesting that most heavy metals (>99%) were retained in the growing mediums. Zeolites reduced the amount of Cd and Pb in leachate water, but not Cu or Zn. PMID:18948478
NASA Astrophysics Data System (ADS)
Minale, Mario
2016-02-01
In this paper, a stress boundary condition at the interface between a porous medium saturated by a viscoelastic fluid and the free viscoelastic fluid is derived. The volume averages are used to upscale the problem. The boundary condition is obtained on the assumption that the free fluid stress is transferred partially to the fluid within the porous medium and partially to the solid skeleton. To this end the momentum balance on the solid skeleton saturated by the viscoelastic fluid is derived and a generalised Biot's equation is obtained, which is coupled with the generalised Brinkman's equation derived in Part I of the paper. They together state that the whole stress carried by the porous medium, sum of that of the fluid and that of the solid skeleton, is not dissipated. The boundary condition here derived does not show any stress jump and as in Part I, to emphasize the effect of elasticity, a second order fluid of Coleman and Noll is considered as viscoelastic fluid. Also the stress boundary condition at the interface between a homogeneous solid and the porous medium saturated by the viscoelastic fluid is obtained.
ERIC Educational Resources Information Center
Hastings, S. K.
2002-01-01
Discusses 3 D imaging as it relates to digital representations in virtual library collections. Highlights include X-ray computed tomography (X-ray CT); the National Science Foundation (NSF) Digital Library Initiatives; output peripherals; image retrieval systems, including metadata; and applications of 3 D imaging for libraries and museums. (LRW)
Heat transfer in porous medium embedded with vertical plate: Non-equilibrium approach - Part B
NASA Astrophysics Data System (ADS)
Quadir, G. A.; Badruddin, Irfan Anjum
2016-06-01
This work is continuation of the paper Part A. Due to large number of results, the paper is divided into two section with section-A (Part A) discussing the effect of various parameters such as heat transfer coefficient parameter, thermal conductivity ratio etc. on streamlines and isothermal lines. Section-B highlights the heat transfer characteristics in terms of Nusselt number The Darcy model is employed to simulate the flow inside the medium. It is assumed that the heat transfer takes place by convection and radiation. The governing partial differential equations are converted into non-dimensional form and solved numerically using finite element method.
NASA Astrophysics Data System (ADS)
Lokajíček, T.; Kern, H.; Svitek, T.; Ivankina, T.
2014-06-01
Ultrasonic measurements of the 3D velocity distribution of P- and S-waves were performed on a spherical sample of a biotite gneiss from the Outokumpu scientific drill hole. Measurements were done at room temperature and pressures up to 400 and 70 MPa, respectively, in a pressure vessel with oil as a pressure medium. A modified transducer/sample assembly and the installation of a new mechanical system allowed simultaneous measurements of P- and S-wave velocities in 132 independent directions of the sphere on a net in steps of 15°. Proper signals for P- and S-waves could be recorded by coating the sample surface with a high-viscosity shear wave gel and by temporal point contacting of the transmitter and receiver transducers with the sample surface during the measurements. The 3D seismic measurements revealed a strong foliation-related directional dependence (anisotropy) of P- and S-wave velocities, which is confirmed by measurements in a multi-anvil apparatus on a cube-shaped specimen of the same rock. Both experimental approaches show a marked pressure sensitivity of P- and S-wave velocities and velocity anisotropies. With increasing pressure, P- and S-wave velocities increase non-linearly due to progressive closure of micro-cracks. The reverse is true for velocity anisotropy. 3D velocity calculations based on neutron diffraction measurements of crystallographic preferred orientation (CPO) of major minerals show that the intrinsic bulk anisotropy is basically caused by the CPO of biotite constituting about 23 vol.% of the rock. Including the shape of biotite grains and oriented low-aspect ratio microcracks into the modelling increases bulk anisotropy. An important finding from this study is that the measurements on the sample sphere and on the sample cube displayed distinct differences, particularly in shear wave velocities. It is assumed that the differences are due to the different geometries of the samples and the configuration of the transducer-sample assembly
Anomalously slow relaxation of interacting liquid nanoclusters confined in a porous medium
NASA Astrophysics Data System (ADS)
Borman, V. D.; Belogorlov, A. A.; Tronin, V. N.
2016-02-01
Anomalously slow relaxation of clusters of a liquid confined in a disordered system of pores has been studied for the (water-L23 nanoporous medium) system. The evolution of the system of confined liquid clusters consists of a fast formation stage followed by slow relaxation of the system and its decay. The characteristic time for the formation of the initial state is τp˜10 s after the reduction of excess pressure after complete filling. Anomalously slow relaxation has been observed for times of 101- 105 s, and decay has been observed at times of >105 s. The time dependence of the volume fraction θ of pores filled with the confined liquid is described by a power law θ ˜t-α with the exponent α <0.15 . The exponent α and temperature dependence α (T ) are qualitatively described theoretically for the case of a slightly polydisperse medium in a mean-field approximation with the inclusion of the interaction of liquid clusters and averaging over various degenerate local configurations of clusters. In this approximation, slow relaxation is represented as a continuous transition through a sequence of metastable states of the system of clusters with a decreasing barrier.
Comparison of theory and experiment for solute transport in highly heterogeneous porous medium
NASA Astrophysics Data System (ADS)
Golfier, Fabrice; Quintard, Michel; Cherblanc, Fabien; Zinn, Brendan A.; Wood, Brian D.
2007-11-01
In this work we compare the recently developed two-region mass transfer theory reported by Ahmadi et al. [A. Ahmadi, M. Quintard, S. Whitaker (1998), Transport in chemically and mechanically heterogeneous porous media, V, two-equation model for solute transport with adsorption, Adv. Water Resour. 1998;22:59-86] with experimental results reported by Zinn et al. [Zinn, B., L. C. Meigs, C. F. Harvey, R. Haggerty, W. J. Peplinski, C. F. Von Schwerin. Experimental visualization of solute transport and mass transfer processes in two-dimensional conductivity fields with connected regions of high conductivity. Environ Sci Technol 2004;38:3916-3926]. We find that the constant mass transfer coefficient predicted by the steady-state closure to the theory, when used with the macroscale transport equation, provides a reasonable prediction of the observed breakthrough curve. However, the use of a constant mass transfer coefficient does not allow good representation of the tailing that is observed in the data. We show that the mass transfer coefficient can be represented in terms of the eigenvalue expansion of a Green's function. For a steady solution to the closure problem, this expansion leads to the effective mass transfer coefficient being defined in terms of the harmonic average of the eigenvalues of the expansion; this is consistent with previous work on this topic. To further investigate the influence of using a single, constant value for the mass transfer coefficient, we examine the solution to the mass transfer problem in terms of a mixed model, where the eigenvalues of one region (the inclusions) are kept, while the second region (the matrix) is treated as a homogenized material. The results from this comparison indicate that the mass transfer coefficient predicted via volume averaging using a quasi-steady closure could potentially be improved upon by development of new methods that retain more of the eigenvalues of the system.
Impact of kinetic mass transfer on free convection in a porous medium
NASA Astrophysics Data System (ADS)
Lu, Chunhui; Shi, Liangsheng; Chen, Yiming; Xie, Yueqing; Simmons, Craig T.
2016-05-01
We investigate kinetic mass transfer effects on unstable density-driven flow and transport processes by numerical simulations of a modified Elder problem. The first-order dual-domain mass transfer model coupled with a variable-density-flow model is employed to describe transport behavior in porous media. Results show that in comparison to the no-mass-transfer case, a higher degree of instability and more unstable system is developed in the mass transfer case due to the reduced effective porosity and correspondingly a larger Rayleigh number (assuming permeability is independent on the mobile porosity). Given a constant total porosity, the magnitude of capacity ratio (i.e., immobile porosity/mobile porosity) controls the macroscopic plume profile in the mobile domain, while the magnitude of mass transfer timescale (i.e., the reciprocal of the mass transfer rate coefficient) dominates its evolution rate. The magnitude of capacity ratio plays an important role on the mechanism driving the mass flux into the aquifer system. Specifically, for a small capacity ratio, solute loading is dominated by the density-driven transport, while with increasing capacity ratio local mass transfer dominated solute loading may occur at later times. At significantly large times, however, both mechanisms contribute comparably to solute loading. Sherwood Number could be a nonmonotonic function of mass transfer timescale due to complicated interactions of solute between source zone, mobile zone and immobile zone in the top boundary layer, resulting in accordingly a similar behavior of the total mass. The initial assessment provides important insights into unstable density-driven flow and transport in the presence of kinetic mass transfer.
Molnar, Ian L; Willson, Clinton S; O'Carroll, Denis M; Rivers, Mark L; Gerhard, Jason I
2014-01-21
Attempts at understanding nanoparticle fate and transport in the subsurface environment are currently hindered by an inability to quantify nanoparticle behavior at the pore scale (within and between pores) within realistic pore networks. This paper is the first to present a method for high resolution quantification of silver nanoparticle (nAg) concentrations within porous media under controlled experimental conditions. This method makes it possible to extract silver nanoparticle concentrations within individual pores in static and quasi-dynamic (i.e., transport) systems. Quantification is achieved by employing absorption-edge synchrotron X-ray computed microtomography (SXCMT) and an extension of the Beer-Lambert law. Three-dimensional maps of X-ray mass linear attenuation are converted to SXCMT-determined nAg concentration and are found to closely match the concentrations determined by ICP analysis. In addition, factors affecting the quality of the SXCMT-determined results are investigated: 1) The acquisition of an additional above-edge data set reduced the standard deviation of SXCMT-determined concentrations; 2) X-ray refraction at the grain/water interface artificially depresses the SXCMT-determined concentrations within 18.1 μm of a grain surface; 3) By treating the approximately 20 × 10(6) voxels within each data set statistically (i.e., averaging), a high level of confidence in the SXCMT-determined mean concentrations can be obtained. This novel method provides the means to examine a wide range of properties related to nanoparticle transport in controlled laboratory porous medium experiments. PMID:24354304
Sharmin, Rumana; Ioannidis, Marios A; Legge, Raymond L
2006-01-01
At concentrations above the critical micelle concentration, surfactants can significantly enhance the solubilization of residual nonaqueous phase liquids (NAPL) and, for this reason, are the focus of research on surfactant-enhanced aquifer remediation (SEAR). As a consequence of their amphiphilic nature, surfactants may also partition to various extents between the organic and aqueous phases, thereby affecting SEAR performance. We report here on the observation and analysis of the effect of surfactant partitioning on the dissolution kinetics of residual perchloroethylene (PCE) by aqueous solutions (1000 mg/L) of the non-ionic surfactant Triton X-100 in a model porous medium. For this fluid system, batch equilibration experiments showed that the surfactant partitions strongly into the NAPL (NAPL-water partition coefficient equal to 12.5). Dynamic interfacial tension (IFT) measurements were employed to study surfactant diffusion and interfacial adsorption. The dynamic IFT measurements were consistent with partitioning of the surfactant between the two liquid phases. PCE dissolution experiments, conducted in a transparent glass micromodel using an aqueous surfactant solution, were contrasted to experiments using clean water. Surfactant partitioning was observed to delay significantly the onset of micellar solubilization of PCE, an observation reproduced by a numerical model. This effect is attributed to the reduction of surfactant concentration in the immediate vicinity of the NAPL-water interface, which accompanies transport of the surfactant into the NAPL. Accordingly, it is suggested that both the rate and the extent of diffusion of the surfactant into the NAPL affect the onset of and the driving force for micellar solubilization. While many surfactants do not readily partition in NAPL, this possibility must be considered when selecting non-ionic surfactants for the enhanced solubilization of residual chlorinated solvents in porous media.
Pore Scale Modeling of Competitive Adsorption of a Plume in a Porous Medium
Ryan, Emily M.; Tartakovsky, Alexandre M.; Amon, Cristina
2010-06-30
In this paper we present a smoothed particle hydrodynamics (SPH) pore scale reactive transport model of competitive adsorption of a binary system in a porous media. SPH is a Lagrangian, particle based modeling method which uses the particles as interpolation points to directly discretize the governing equations of the system. The theory and details of the SPH pore scale model are presented along with a novel method for handling surface reactions based on the continuum surface force model [1]. The numerical accuracy of the model is validated with analytical and finite difference solutions, and the effects of spatial and temporal resolution on the accuracy of the model are also discussed. The pore scale model is used to study competitive adsorption for different Damköhler and Peclet numbers in a binary system where a plume of species B is introduced into a system which initially contains species A. The pore scale model results are compared with a Darcy scale model to investigate the accuracy of a Darcy scale reactive transport model for a wide range of Damköhler and Peclet numbers. The results demonstrate that the Darcy model is able to accurately predict the total mass of aqueous and adsorbed species of both species A and B for low Damköhler numbers. For high Damköhler numbers the Darcy model is able to accurately model the aqueous and absorbed mass of species A, but is unable to accurately predict the total mass of aqueous and adsorbed species B, which moves through the domain as a plume. At high Peclet numbers, the Darcy model was able to accurately predict the aqueous and adsorbed masses of species A and B at higher Damköhler numbers then low Peclet number simulations, however at both high and low Peclet numbers the Darcy model was not able to accurately predict the total mass of species B at high Damköhler numbers. The simulation results demonstrate the limitations of simple Darcy scale models with constant transport coefficients.
NASA Astrophysics Data System (ADS)
Oostrom, M.; Dane, J. H.; Wietsma, T. W.
2004-12-01
An intermediate-scale flow cell experiment was conducted to study the behavior of a multicomponent DNAPL at structural interfaces and subsequent remediation using two different forms of the soil vapor extraction (SVE) technique. The flow cell (100-cm long, 5-cm wide, and 80 cm high), was packed under saturated conditions with sloped layers of Hanford silt and coarse sand, embedded in a matrix of a medium-grained laboratory sand. After packing, the water table was lowered to 2 cm above the bottom of the flow cell to establish variably saturated conditions. A finite amount of a volatile multicomponent DNAPL, mimicking the organic liquid disposed at the Hanford Site, was then injected from a small source zone. The infiltration and redistribution processes were visually recorded. In addition, a dual-energy gamma radiation system was used to determine DNAPL and water saturation at more than 1000 locations. Results indicate that lateral spreading of the DNAPL is greatly enhanced by the heterogeneities. The silt layers, by virtue of their substantial non-wetting fluid entry pressures and high water saturations, completely diverted the DNAPL laterally. The relatively dry coarse-sand layers forced some of the DNAPL to move laterally but also allowed some infiltration.
NASA Astrophysics Data System (ADS)
Sulochana, C.; Sandeep, N.; Sugunamma, V.; Rushi Kumar, B.
2016-06-01
In this paper, we investigated the effects of aligned magnetic field, thermal radiation, heat generation/absorption, cross-diffusion, viscous dissipation, heat source and chemical reaction on the flow of a nanofluid past an exponentially stretching sheet in porous medium. The governing partial differential equations are transformed to set of ordinary differential equations using self-similarity transformation, which are then solved numerically using bvp4c Matlab package. Finally the effects of various non-dimensional parameters on velocity, temperature, concentration, skin friction, local Nusselt and Sherwood numbers are thoroughly investigated and presented through graphs and tables. We observed that an increase in the aligned angle strengthens the applied magnetic field and decreases the velocity profiles of the flow. Soret and Dufour numbers are helpful to enhance the heat transfer rate. An increase in the heat source parameter, radiation parameter and Eckert number increases the mass transfer rate. Mixed convection parameter has tendency to enhance the friction factor along with the heat and mass transfer rate.
Waheed, Shimaa E
2016-01-01
A problem of flow and heat transfer in a non-Newtonian Maxwell liquid film over an unsteady stretching sheet embedded in a porous medium in the presence of a thermal radiation is investigated. The unsteady boundary layer equations describing the problem are transformed to a system of non-linear ordinary differential equations which is solved numerically using the shooting method. The effects of various parameters like the Darcy parameter, the radiation parameter, the Deborah number and the Prandtl number on the flow and temperature profiles as well as on the local skin-friction coefficient and the local Nusselt number are presented and discussed. It is observed that increasing values of the Darcy parameter and the Deborah number cause an increase of the local skin-friction coefficient values and decrease in the values of the local Nusselt number. Also, it is noticed that the local Nusselt number increases as the Prandtl number increases and it decreases with increasing the radiation parameter. However, it is found that the free surface temperature increases by increasing the Darcy parameter, the radiation parameter and the Deborah number whereas it decreases by increasing the Prandtl number. PMID:27462509
Antraygues, P.; Aubert, M.
1993-12-01
In order to characterize the relationships between self-potential generation and hydrothermal convection, laboratory measurements of electric potential and temperature are made along a vertical cylindrical column of porous material where a two-phase flow (wet steam) occurs. For steady state convection, the vertical distributions of vapor and water flow rates are calculated from thermal balance. At the initiation of convection, a positive electrical charge flux is related to the convective front. For isothermal and steady state columns, a positive electric potential gradient is observed along the vapor flow direction. These electric potentials are mainly a function of the vapor flow rates and of the medium permeability. A sudden and large increase in the vapor flow rate and in the volume fraction of vapor can induce a large and long-lived increase in the potential differences along the vapor flow direction. An electrokinetic effect related to the saturated vapor flow is the best candidate for this electric potential generation. The experimental resutls obtained in the present study are applied to self-potential generation in rising two-phase convective cells on active volcanoes. The observed positive self-potential anomalies close to active fissures depend on the electrical charge flux related to the upward saturated vapor flow. These results also demonstrate the value of self-potential monitoring in the early stages preceding a volcanic eruption.
NASA Astrophysics Data System (ADS)
Oldham, Mark
2015-01-01
Radiochromic materials exhibit a colour change when exposed to ionising radiation. Radiochromic film has been used for clinical dosimetry for many years and increasingly so recently, as films of higher sensitivities have become available. The two principle advantages of radiochromic dosimetry include greater tissue equivalence (radiologically) and the lack of requirement for development of the colour change. In a radiochromic material, the colour change arises direct from ionising interactions affecting dye molecules, without requiring any latent chemical, optical or thermal development, with important implications for increased accuracy and convenience. It is only relatively recently however, that 3D radiochromic dosimetry has become possible. In this article we review recent developments and the current state-of-the-art of 3D radiochromic dosimetry, and the potential for a more comprehensive solution for the verification of complex radiation therapy treatments, and 3D dose measurement in general.
NASA Astrophysics Data System (ADS)
Moore, Gregory F.
2009-05-01
This volume is a brief introduction aimed at those who wish to gain a basic and relatively quick understanding of the interpretation of three-dimensional (3-D) seismic reflection data. The book is well written, clearly illustrated, and easy to follow. Enough elementary mathematics are presented for a basic understanding of seismic methods, but more complex mathematical derivations are avoided. References are listed for readers interested in more advanced explanations. After a brief introduction, the book logically begins with a succinct chapter on modern 3-D seismic data acquisition and processing. Standard 3-D acquisition methods are presented, and an appendix expands on more recent acquisition techniques, such as multiple-azimuth and wide-azimuth acquisition. Although this chapter covers the basics of standard time processing quite well, there is only a single sentence about prestack depth imaging, and anisotropic processing is not mentioned at all, even though both techniques are now becoming standard.
Iliesiu, Luca; Kos, Filip; Poland, David; Pufu, Silviu S.; Simmons-Duffin, David; Yacoby, Ran
2016-03-17
We study the conformal bootstrap for a 4-point function of fermions <ψψψψ> in 3D. We first introduce an embedding formalism for 3D spinors and compute the conformal blocks appearing in fermion 4-point functions. Using these results, we find general bounds on the dimensions of operators appearing in the ψ × ψ OPE, and also on the central charge CT. We observe features in our bounds that coincide with scaling dimensions in the GrossNeveu models at large N. Finally, we also speculate that other features could coincide with a fermionic CFT containing no relevant scalar operators.
Fauske, H.K.; Cash, R.J.
1993-11-01
The conditions under which ferrocyanide waste sludge flows as a homogeneous non-Newtonian two-phase (solid precipitate-liquid) mixture rather than as a liquid through a porous medium (of stationary precipitate) are examined theoretically, based on the notion that the preferred rheological behavior of the sludge is the one which imposes the least resistance to the sludge flow. The homogeneous two-phase mixture is modeled as a power-law fluid and simple criteria are derived that show that the homogeneous power-law sludge-flow is a much more likely flow situation than the porous medium model of sludge flow. The implication of this finding is that the formation of a hot spot or the drainage of sludge from a waste tank are not likely to result in the uncovering (drying) and subsequent potential overheating of the reactive-solid component of the sludge.
Suresh, M; Manglik, A
2014-01-01
This paper proposes the exact solution for unsteady flow of a viscous incompressible electrically conducting fluid past a impulsively started infinite horizontal surface which is rotating with an angular velocity embedded in a saturated porous medium under the influence of strong magnetic field with hall effect. Our study focuses on the change of direction of the external magnetic field on the flow system which leads to change in the flow behavior and skin frictional forces at the boundary. Systems of flow equations are solved using Laplace transform technique. The impacts of control parameters Hartman number, rotation of the system, hall effect, inclination of the magnetic field, and Darcy number on primary and secondary velocities are shown graphically, skin friction at horizontal boundary in tabular form. For validating our results, in the absence of permeability of the porous medium and inclination of the magnetic field the results are in good agreement with the published results.
Tsimpanogiannis, Ioannis N.; Yortsos, Yanis C.
2001-08-15
This report, focuses on the isothermal gas phase growth from a supersaturated, slightly compressible, binary liquid in a porous medium. This is driven by mass transfer, the extent of which is controlled by the application of either a constant-rate decline of the system pressure or the withdrawal of the liquid at a constant rate. This report deals with the first process. Pressure depletion due to constant-rate liquid withdrawal is analyzed in a companion report .
NASA Astrophysics Data System (ADS)
Plaut, J. J.
1993-08-01
Stereographic images of the surface of Venus which enable geologists to reconstruct the details of the planet's evolution are discussed. The 120-meter resolution of these 3D images make it possible to construct digital topographic maps from which precise measurements can be made of the heights, depths, slopes, and volumes of geologic structures.
Van, B.T.; Pajon, J.L.; Joseph, P. )
1991-11-01
This paper shows how some simple 3D computer graphics tools can be combined to provide efficient software for visualizing and analyzing data obtained from reservoir simulators and geological simulations. The animation and interactive capabilities of the software quickly provide a deep understanding of the fluid-flow behavior and an accurate idea of the internal architecture of a reservoir.
NASA Astrophysics Data System (ADS)
Oostrom, M.; Hofstee, C.; Walker, R. C.; Dane, J. H.
1999-04-01
An intermediate-scale flow cell experiment was conducted to remove a liquid trichloroethylene (TCE) spill from a saturated, heterogeneous porous medium using pump-and-treat (P&T) as well as surfactant flushing (SF) techniques. Dissolved TCE concentrations were measured at 20 locations, while fluid saturations were obtained with a dual-energy gamma scanner. The behavior of the TCE spill has been described by Oostrom et al. (1998b) [Oostrom, M., Hofstee, C., Walker, R.C., Dane, J.H., 1998b. Movement and remediation of TCE in a saturated heterogeneous porous medium: 1. Spill behavior and initial dissolution, this issue.]. A total of six alternating P&T and SF periods were used to remediate the flow cell. A two-well system, consisting of an injection and an extraction well, was used during the first five remediation periods. For the last SF period, a three-well system was employed with two injection wells and one extraction well. During the first P&T period, most entrapped TCE was removed, but TCE saturations in a substantial pool on top of a fine-grained sand layer were largely unaffected. During the first SF period, a dense plume was formed containing solubilized TCE which partially sank into the fine-grained sand. In addition, unstable fingers developed below the liquid TCE in the pool. In several samples, small TCE droplets were found, indicating mobilization of TCE. Most of the samples with concentrations larger than 5000 ppm had a milky, emulsion-like appearance. The SF considerably reduced the amount of TCE in the pool on top of the fine-grained sand. During the second P&T period, plume sinking and instabilities were not observed. After starting the second SF period, some unstable fingering and plume sinking resumed, starting at the upstream end of the TCE in the pool. The saturation distribution obtained after the second SF period was quite similar to the one obtained after the first SF period, indicating that additional removal of TCE through SF was difficult
Bolton, E.W.; Lasaga, A.C.; Rye, D.M.
1999-01-01
The kinetics of dissolution and precipitation is of central importance to understanding the long-term evolution of fluid flows in crustal environments, with implications for problems as diverse as nuclear waste disposal and crustal evolution. The authors examine the dynamics of such evolution for several geologically relevant permeability distributions (models for en-echelon cracks, an isolated sloping fractured zone, and two sloping high-permeability zones that are close enough together to interact). Although the focus is on a simple quartz matrix system, generic features emerge from this study that can aid in the broader goal of understanding the long-term feedback between flow and chemistry, where dissolution and precipitation is under kinetic control. Examples of thermal convection in a porous medium with spatially variable permeability reveal features of central importance to water-rock interaction. After a transient phase, an accelerated rate of change of porosity may be used with care to decrease computational time, as an alternative to the quasi-stationary state approximation (Lichtner, 1988). Kinetic effects produce features not expected by traditional assumptions made on the basis of equilibrium, for example, that cooling fluids are oversaturated and heating fluids are undersaturated with respect to silicic acid equilibrium. Indeed, the authors observe regions of downwelling oversaturated fluid experiencing heating and regions of upwelling, yet cooling, undersaturated fluid. When oscillatory convection is present, the amplitudes of oscillation generally increase with time in near-surface environments, whereas amplitudes tend to decrease over long times near the heated lower boundary. The authors examine the scaling behavior of characteristic length scales, of terms in the solute equation, and of the typical deviation from equilibrium, each as a function of the kinetic rate parameters.
Kieft, T.L.; Ringelberg, D.B.; White, D.C.
1994-09-01
Ester-linked phospholipid fatty acid (PLFA) profiles of a Pseudomonas aureofaciens strain and an Arthrobacter protophormiae strain, each isolated from a subsurface sediment, were quantified in a starvation experiment in a silica sand porous medium under moist and dry conditions. Washed cells were added to sand microcosms and maintained under saturated conditions or subjected to desiccation by slow drying over a period of 16 days. In a third treatment, cells were added to saturated microcosms along with organic nutrients and maintained under saturated conditions. The numbers of culturable cells of both bacterial strains declined to below detection level within 16 days in both the moist and dried nutrient-deprived conditions, while direct counts and total PLFAs remained relatively constant. Both strains of bacteria maintained culturability in the nutrient-amended microcosms. The dried P. aureofaciens cells showed increased ratios of saturated to unsaturated fatty acids, increased ratios of trans- to cis-monoenoic fatty acids, and increased ratios of cyclopropyl fatty acids to their monoenoic precursors. P. aureofaciens starved under moist conditions showed few changes in PLFA profiles during the 16-day incubation, whereas cells incubated in the presence of nutrients showed decreases in the ratios of both saturated fatty acids to unsaturated fatty acids and cyclopropyl fatty acids to their monoenoic precursors. The PLFA profiles of A. protophormiae changed very little in response to either nutrient deprivation or desiccation. Diglyceride fatty acids, proposedindicators of dead or lysed cells, remained relatively constant throughout the experiment. The results of this laboratory experiment can be useful for interpreting PLFA profiles of subsurface communities of microorganisms for the purpose of determining their physiological status. 43 refs., 8 figs.
Wicks, George G; Serkiz, Steven M.; Zidan, Ragaiy; Heung, Leung K.
2014-06-24
Porous wall hollow glass microspheres are provided as a template for formation of nanostructures such as carbon nanotubes, In addition, the carbon nanotubes in combination with the porous wall hollow glass microsphere provides an additional reaction template with respect to carbon nanotubes.
NASA Astrophysics Data System (ADS)
Isaksson, Folke; Borg, Johan; Haglund, Leif
2008-04-01
In this paper the performance of passive range measurement imaging using stereo technique in real time applications is described. Stereo vision uses multiple images to get depth resolution in a similar way as Synthetic Aperture Radar (SAR) uses multiple measurements to obtain better spatial resolution. This technique has been used in photogrammetry for a long time but it will be shown that it is now possible to do the calculations, with carefully designed image processing algorithms, in e.g. a PC in real time. In order to get high resolution and quantitative data in the stereo estimation a mathematical camera model is used. The parameters to the camera model are settled in a calibration rig or in the case of a moving camera the scene itself can be used for calibration of most of the parameters. After calibration an ordinary TV camera has an angular resolution like a theodolite, but to a much lower price. The paper will present results from high resolution 3D imagery from air to ground. The 3D-results from stereo calculation of image pairs are stitched together into a large database to form a 3D-model of the area covered.
Small scale flow processes in aqueous heterogeneous porous media
Rashidi, M.; Dickenson, E.
1996-04-01
Small scale flow processes in aqueous heterogeneous porous systems have been studied experimentally via novel nonintrusive fluorescence imaging techniques. The techniques involve 3D visualization and quantification of flow fields within a refractive index-matched transparent porous column. The refractive index-matching yields a transparent porous medium, free from any scattering and refraction at the solid-liquid interfaces, as a result allowing direct optical probing at any point within the porous system. By illuminating the porous regions within the column with a planar sheet of laser beam, flow processes through the porous medium can be observed microscopically, and qualitative and quantitative in-pore transport information can be obtained at a good resolution and a good accuracy. A CCD camera is used to record the fluorescent images at every vertical plane location while sweeping back and forth across the column. These digitized flow images are then analyzed and accumulated over a 3D volume within the column. Series of flow experiments in aqueous, refractive index-matched, porous systems packed with natural mineral particles have been performed successfully in these laboratories.
McClure, James E.; Berrill, Mark A.; Gray, William G.; Miller, Cass T.
2016-09-02
Here, multiphase flow in porous medium systems is typically modeled using continuum mechanical representations at the macroscale in terms of averaged quantities. These models require closure relations to produce solvable forms. One of these required closure relations is an expression relating fluid pressures, fluid saturations, and, in some cases, the interfacial area between the fluid phases, and the Euler characteristic. An unresolved question is whether the inclusion of these additional morphological and topological measures can lead to a non-hysteretic closure relation compared to the hysteretic forms that are used in traditional models, which typically do not include interfacial areas, ormore » the Euler characteristic. We develop a lattice-Boltzmann (LB) simulation approach to investigate the equilibrium states of a two-fluid-phase porous medium system, which include disconnected now- wetting phase features. The proposed approach is applied to a synthetic medium consisting of 1,964 spheres arranged in a random, non-overlapping, close-packed manner, yielding a total of 42,908 different equilibrium points. This information is evaluated using a generalized additive modeling approach to determine if a unique function from this family exists, which can explain the data. The variance of various model estimates is computed, and we conclude that, except for the limiting behavior close to a single fluid regime, capillary pressure can be expressed as a deterministic and non-hysteretic function of fluid saturation, interfacial area between the fluid phases, and the Euler characteristic. This work is unique in the methods employed, the size of the data set, the resolution in space and time, the true equilibrium nature of the data, the parameterizations investigated, and the broad set of functions examined. The conclusion of essentially non-hysteretic behavior provides support for an evolving class of two-fluid-phase flow in porous medium systems models.« less
Taming supersymmetric defects in 3d-3d correspondence
NASA Astrophysics Data System (ADS)
Gang, Dongmin; Kim, Nakwoo; Romo, Mauricio; Yamazaki, Masahito
2016-07-01
We study knots in 3d Chern-Simons theory with complex gauge group {SL}(N,{{C}}), in the context of its relation with 3d { N }=2 theory (the so-called 3d-3d correspondence). The defect has either co-dimension 2 or co-dimension 4 inside the 6d (2,0) theory, which is compactified on a 3-manifold \\hat{M}. We identify such defects in various corners of the 3d-3d correspondence, namely in 3d {SL}(N,{{C}}) CS theory, in 3d { N }=2 theory, in 5d { N }=2 super Yang-Mills theory, and in the M-theory holographic dual. We can make quantitative checks of the 3d-3d correspondence by computing partition functions at each of these theories. This Letter is a companion to a longer paper [1], which contains more details and more results.
NASA Technical Reports Server (NTRS)
1992-01-01
Ames Research Center research into virtual reality led to the development of the Convolvotron, a high speed digital audio processing system that delivers three-dimensional sound over headphones. It consists of a two-card set designed for use with a personal computer. The Convolvotron's primary application is presentation of 3D audio signals over headphones. Four independent sound sources are filtered with large time-varying filters that compensate for motion. The perceived location of the sound remains constant. Possible applications are in air traffic control towers or airplane cockpits, hearing and perception research and virtual reality development.
Visualizing 3D fracture morphology in granular media
NASA Astrophysics Data System (ADS)
Dalbe, Marie-Julie; Juanes, Ruben
2015-11-01
Multiphase flow in porous media plays a fundamental role in many natural and engineered subsurface processes. The interplay between fluid flow, medium deformation and fracture is essential in geoscience problems as disparate as fracking for unconventional hydrocarbon production, conduit formation and methane venting from lake and ocean sediments, and desiccation cracks in soil. Recent work has pointed to the importance of capillary forces in some relevant regimes of fracturing of granular materials (Sandnes et al., Nat. Comm. 2011), leading to the term hydro-capillary fracturing (Holtzman et al., PRL 2012). Most of these experimental and computational investigations have focused, however, on 2D or quasi-2D systems. Here, we develop an experimental set-up that allows us to observe two-phase flow in a 3D granular bed, and control the level of confining stress. We use an index matching technique to directly visualize the injection of a liquid in a granular media saturated with another, immiscible liquid. We determine the key dimensionless groups that control the behavior of the system, and elucidate different regimes of the invasion pattern. We present result for the 3D morphology of the invasion, with particular emphasis on the fracturing regime.
Visualizing 3D Fracture Morphology in Granular Media
NASA Astrophysics Data System (ADS)
Dalbe, M. J.; Juanes, R.
2015-12-01
Multiphase flow in porous media plays a fundamental role in many natural and engineered subsurface processes. The interplay between fluid flow, medium deformation and fracture is essential in geoscience problems as disparate as fracking for unconventional hydrocarbon production, conduit formation and methane venting from lake and ocean sediments, and desiccation cracks in soil. Recent work has pointed to the importance of capillary forces in some relevant regimes of fracturing of granular materials (Sandnes et al., Nat. Comm. 2011), leading to the term hydro-capillary fracturing (Holtzman et al., PRL 2012). Most of these experimental and computational investigations have focused, however, on 2D or quasi-2D systems. Here, we develop an experimental set-up that allows us to observe two-phase flow in a 3D granular bed, and control the level of confining stress. We use an index matching technique to directly visualize the injection of a liquid in a granular media saturated with another, immiscible liquid. We determine the key dimensionless groups that control the behavior of the system, and elucidate different regimes of the invasion pattern. We present result for the 3D morphology of the invasion, with particular emphasis on the fracturing regime.
NASA Astrophysics Data System (ADS)
Altman, S. J.; Kirk, M. F.; Santillan, E. U.; McGrath, L. K.
2013-12-01
Microbial biomass can clog porous media and ultimately affect both structural and mineral trapping of CO2 in geological carbon storage reservoirs. Whether biomass can remain intact following a sudden decrease in groundwater pH, a geochemical change associated with CO2 injection, is unclear. We examined this question using twelve biologically-active and three control column-reactor experiments. Cell abundance and distribution was monitored using confocal microscopy, plating, and direct counting. Hydraulic conductivity (K) was monitored using pressure sensors. Growth occurred for four days at neutral pH. During that time, K within the clogged portion of the reactors decreased from 0.013 to 0.0006 cm s-1 on average, a 1.47 log reduction. Next, the pH of the inflowing aqueous medium was lowered to pH 4 in six experiments and pH 5.7 in six experiments. As a result, K increased in five of the pH 4 experiments and two of the pH 5.7 experiments. Despite this increase, however, the columns remained largely clogged. Compared to pre-inoculation K values, log reductions averaged 1.13 and 1.44 in pH 4 and pH 5.7 experiments, respectively. Our findings show that biomass can largely remain intact following acidification and continue to reduce K, even when considerable cell stress and death occurs. This material is based upon work supported as part of the Center for Frontiers of Subsurface Energy Security, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences under Award Number DE-SC0001114. Sandia National Laboratories is a multi-program laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000.
Aziz, Asim; Ali, Yasir; Aziz, Taha; Siddique, J. I.
2015-01-01
In this paper, we investigate the slip effects on the boundary layer flow and heat transfer characteristics of a power-law fluid past a porous flat plate embedded in the Darcy type porous medium. The nonlinear coupled system of partial differential equations governing the flow and heat transfer of a power-law fluid is transformed into a system of nonlinear coupled ordinary differential equations by applying a suitable similarity transformation. The resulting system of ordinary differential equations is solved numerically using Matlab bvp4c solver. Numerical results are presented in the form of graphs and the effects of the power-law index, velocity and thermal slip parameters, permeability parameter, suction/injection parameter on the velocity and temperature profiles are examined. PMID:26407162
Aziz, Asim; Ali, Yasir; Aziz, Taha; Siddique, J I
2015-01-01
In this paper, we investigate the slip effects on the boundary layer flow and heat transfer characteristics of a power-law fluid past a porous flat plate embedded in the Darcy type porous medium. The nonlinear coupled system of partial differential equations governing the flow and heat transfer of a power-law fluid is transformed into a system of nonlinear coupled ordinary differential equations by applying a suitable similarity transformation. The resulting system of ordinary differential equations is solved numerically using Matlab bvp4c solver. Numerical results are presented in the form of graphs and the effects of the power-law index, velocity and thermal slip parameters, permeability parameter, suction/injection parameter on the velocity and temperature profiles are examined.
Nakayama, A. )
1993-05-01
Convection problems associated with concentrated heat sources within fluid-saturated porous media are of great practical significance, for there are a number of practical applications in geophysics and energy-related problems, such as recovery of petroleum resources, geophysical flows, cooling of underground electric cables, and environmental impact of buried heat generating waste. In this note, a boundary layer analysis is presented for free convection from a point heat source embedded in a porous medium saturated with a non-Newtonian power-law fluid. The governing equations are found to possess a similarity solution for an arbitrary value of the power-law index. Closed-form solutions are presented for both flow and temperature fields, and the effects of pseudoplasticity on the plumes are examined. 17 refs., 5 figs.
Vasco, D.W.
2011-10-01
Using an asymptotic technique, valid when the medium properties are smoothly-varying, I derive a semi-analytic expression for the propagation velocity of a quasi-static disturbance traveling within a nonlinear-elastic porous medium. The phase, a function related to the propagation time, depends upon the properties of the medium, including the pressure-sensitivities of the medium parameters, and on pressure and displacement amplitude changes. Thus, the propagation velocity of a disturbance depends upon its amplitude, as might be expected for a nonlinear process. As a check, the expression for the phase function is evaluated for a poroelastic medium, when the material properties do not depend upon the fluid pressure. In that case, the travel time estimates agree with conventional analytic estimates, and with values calculated using a numerical simulator. For a medium with pressure-dependent permeability I find general agreement between the semi-analytic estimates and estimates from a numerical simulation. In this case the pressure amplitude changes are obtained from the numerical simulator.
Simulation of contaminant flow ina laboratory-scale porous system
Rashidi, M.
1995-12-01
The microscopic movement of contaminants in a porous medium has been simulated in an experiment. The approach has been to study the microscale transport processes using a novel nonintrusive fluorescence imaging technique developed in our laboratories. The system studied consists of a packed porous column with a refractive index-matched fluid seeded with fluorescent tracer particles (for flow measurements) or an organic dye (for contaminant concentration measurements). Microscopic measurements of contaminant concentration, contaminant velocity, and pore geometry were obtained in a full three-dimensional volume of the test section at a good accuracy and a high resolution. 3D plots of these measurements show the complex geometry of the porous medium. It is also seen that near the contaminant front there is a significant correlation between the flow and the contaminant concentration. The goal is to use these and future results toward better understanding of contaminant flow and report thorough natural porous media.
ERIC Educational Resources Information Center
Matsuda, Hiroshi; Shindo, Yoshiaki
2006-01-01
The 3D computer graphics (3D-CG) animation using a virtual actor's speaking is very effective as an educational medium. But it takes a long time to produce a 3D-CG animation. To reduce the cost of producing 3D-CG educational contents and improve the capability of the education system, we have developed a new education system using Virtual Actor.…
NASA Astrophysics Data System (ADS)
McClure, James E.; Berrill, Mark A.; Gray, William G.; Miller, Cass T.
2016-09-01
Multiphase flows in porous medium systems are typically modeled at the macroscale by applying the principles of continuum mechanics to develop models that describe the behavior of averaged quantities, such as fluid pressure and saturation. These models require closure relations to produce solvable forms. One of these required closure relations is an expression relating the capillary pressure to fluid saturation and, in some cases, other topological invariants such as interfacial area and the Euler characteristic (or average Gaussian curvature). The forms that are used in traditional models, which typically consider only the relationship between capillary pressure and saturation, are hysteretic. An unresolved question is whether the inclusion of additional morphological and topological measures can lead to a nonhysteretic closure relation. Relying on the lattice Boltzmann (LB) method, we develop an approach to investigate equilibrium states for a two-fluid-phase porous medium system, which includes disconnected nonwetting phase features. A set of simulations are performed within a random close pack of 1964 spheres to produce a total of 42 908 distinct equilibrium configurations. This information is evaluated using generalized additive models to quantitatively assess the degree to which functional relationships can explain the behavior of the equilibrium data. The variance of various model estimates is computed, and we conclude that, except for the limiting behavior close to a single fluid regime, capillary pressure can be expressed as a deterministic and nonhysteretic function of fluid saturation, interfacial area between the fluid phases, and the Euler characteristic. To our knowledge, this work is unique in the methods employed, the size of the data set, the resolution in space and time, the true equilibrium nature of the data, the parametrizations investigated, and the broad set of functions examined. The conclusion of essentially nonhysteretic behavior provides
NASA Astrophysics Data System (ADS)
Reddy, Ch. Ram; Kaladhar, K.; Srinivasacharya, D.; Pradeepa, T.
2016-02-01
This paper analyzes the laminar, incompressible mixed convective transport inside vertical channel in an electrically conducting fluid saturated porous medium. In addition, this model incorporates the combined effects of Soret, Hall current and Joule heating. The nonlinear governing equations and their related boundary conditions are initially cast into a dimensionless form using suitable similarity transformations and hence solved using Adomian Decomposition Method (ADM). In order to explore the influence of various parameters on fluid flow properties, quantitative analysis is exhibited graphically and shown in tabular form.
Tsimpanogiannis, Ioannis N.; Yortsos, Yanis C.
2001-08-15
This report describes the development of an effective continuum model to describe the nucleation and subsequent growth of a gas phase from a supersaturated, slightly compressible binary liquid in a porous medium, driven by solute diffusion.This report also focuses on the processes resulting from the withdrawal of the liquid at a constant rate. As before, the model addresses two stages before the onset of bulk gas flow, nucleation and gas phase growth. Because of negligible gradients due to gravity or viscous forces, the critical gas saturation, is only a function of the nucleation fraction.
NASA Astrophysics Data System (ADS)
RamReddy, Chetteti; Pradeepa, Teegala
2016-05-01
Based on the nonlinear variation of density with temperature (NDT) in the buoyancy term, the mixed convection flow along a vertical plate of a micropolar fluid saturated porous medium is considered. In addition, the effect of homogeneous-heterogeneous reaction and convective boundary condition has been taken into account. Using lie scaling group transformations, the similarity representation is attained for the system of partial differential equations, prior to being solved by a spectral quasilinearization method. The results show that in the presence of aiding and opposing flow situations, both the species concentration and mass transfer rate decreases when the strength of homogeneous and heterogeneous reaction parameters are enhanced.
NASA Astrophysics Data System (ADS)
Harfash, Akil J.; Alshara, Ahmed K.
2015-05-01
The linear and nonlinear stability analysis of the motionless state (conduction solution) and of a vertical throughflow in an anisotropic porous medium are tested. In particular, the effect of a nonhomogeneous porosity and a constant anisotropic thermal diffusivity have been taken into account. Then, the accuracy of the linear instability thresholds are tested using a three dimensional simulation. It is shown that the strong stabilising effect of gravity field. Moreover, the results support the assertion that the linear theory, in general, is accurate in predicting the onset of convective motion, and thus, regions of stability.
NASA Astrophysics Data System (ADS)
Srinivasacharya, D.; Pranitha, J.; RamReddy, Ch.
2012-05-01
In this paper, effects of magnetic field and double dispersion on free convection heat and mass transfer along a vertical plate embedded in a doubly stratified non-Darcy porous medium saturated with power-law fluid is considered. The governing partial differential equations are transformed into ordinary differential equations using similarity transformations and then solved numerically. The numerical results are compared and found to be in good agreement with previously published results as special cases of the present investigation. The effects of magnetic parameter, dispersion parameters, and power-law index on the velocity, temperature, and concentration are illustrated graphically.
NASA Astrophysics Data System (ADS)
Ferrante, Aldo Pedro; Fallico, Carmine; Rios, Ana C.; Fernanda Rivera, Maria; Santillan, Patricio; Salazar, Mario
2013-04-01
The contamination of large areas and correspondent aquifers often imposes to implement some recovery operations which are generally complex and very expensive. Anyway, these interventions necessarily require the preventive characterization of the aquifers to be reclaimed and in particular the knowledge of the relevant hydrodispersive parameters. The determination of these parameters requires the implementation tracer tests for the specific site (Sauty JP, 1978). To reduce cost and time that such test requires tracer tests on undisturbed soil samples, representative of the whole aquifer, can be performed. These laboratory tests are much less expensive and require less time, but the results are certainly less reliable than those obtained by field tests for several reasons, including the particular scale of investigation. In any case the hydrodispersive parameters values, obtained by tests carried out in laboratory, can provide useful information on the considered aquifer, allowing to carry out initial verifications on the transmission and propagation of the pollutants in the aquifer considered. For this purpose, tracer tests with inlet of short time were carried out in the Soil Physics Laboratory of the Department of Soil Protection (University of Calabria), on a series of sandy soil samples with six different lengths, repeating each test with three different water flow velocities (5 m/d; 10 m/s and 15 m/d) (J. Feyen et al., 1998). The lengths of the samples taken into account are respectively 15 cm, 24 cm, 30 cm, 45 cm, 60 cm and 75 cm, while the solution used for each test was made of 100 ml of water and NaCl with a concentration of this substance corresponding to 10 g/L. For the porous medium taken into consideration a particle size analysis was carried out, resulting primarily made of sand, with total porosity equal to 0.33. Each soil sample was placed in a flow cell in which was inlet the tracer from the bottom upwards, measuring by a conductivimeter the
Preferential water and solute fluxes in a model macropored porous medium as a function of flow rate
NASA Astrophysics Data System (ADS)
batany, stephane; Peyneau, Pierre-Emmanuel; Lassabatere, Laurent; Bechet, Beatrice; Faure, Pamela; Dangla, Patrick
2016-04-01
Macropores in soils can induce preferential flow and increase solute transport. Close to water saturation, most of the water flows through macropores at a much higher rate than it would in the same soil without any macropore. Preferential flow and water infiltration in soils with macropores have been investigated with different modeling approaches. Most of these are based on dual porosity or dual permeability approaches. These approaches consider that macropored soils are constituted by the association of two regions exchanging water, a matrix and a macropore domain, both of them obeying Darcy's law. Nevertheless, these approaches restrict preferential flow to the macropore domain and cannot simulate any enhancement of flow in the matrix surrounding the macropores. However, this hypothesis has been strongly questioned by several studies that had investigated solute transfer in macropored soils for which solute breakthrough curves (BTCs) were in complete disagreement with the flow restriction to the macropore domain. Thus, the understanding of water infiltration in soils requires more investigations regarding the effect of macropore and cracks in soils. The proposed paper aims at investigating water flow and tracer transport in a water saturated model macropored system as a function of the flow rate. Various solutes were injected in a 5 cm diameter, 14.5 cm high column filled with 425-800 μm diameter glass beads glued together. A 3 mm diameter Teflon rod inserted along the axis of the column during the preparation of the system was removed after the consolidation of the porous medium to create a macropore. Several flow rates - always ensuring a laminar flow - were tested, from values for which the diffusion transport rate is similar to the advective transport rate to values several orders of magnitude higher for which advection dominates. For all flow rates, solute BTCs were analyzed using the moment method and MIM model to quantify the volume of water visited by
A Diffuse Interface Model for solid-liquid-air dissolution problems based on a porous medium theory
NASA Astrophysics Data System (ADS)
Luo, H.; Quintard, M.; Debenest, G.; Laouafa, F.
2011-12-01
The underground cavities may be dissolved by the flows of groundwater where the dissolution mainly happens at the liquid-solid interface. In many real cases, the cavities are not occupied only by the water, but also the gas phase, e.g., air, or other gases. In this case, there are solid-liquid-gas three phases. Normally, the air does not participate the dissolution. However, it may influence the dissolution as the position of the solid-liquid interface may gradually lower down with the dissolution process. Simulating the dissolution problems with multi- moving interfaces is a difficult task but rather interesting to study the evolution of the underground cavities. In this paper, we propose a diffuse interface model (DIM) to simulate the three-phase dissolution problem, based on a porous medium theory and a volume averaging theory te{Whitaker1999,Golfier2002,Quintard1994}. The interface is regarded as a continuous layer where the phase indicator (mainly for solid-liquid interface) and phase saturation (mainly for liquid-gas interface) vary rapidly but smoothly. The DIM equations enable us to simulate the moving interface under a fixed mesh system, instead of a deformed or moving mesh. Suppose we have three phases, solid, liquid and gas. The solid phase contains only species A. The gas phase contains only the air. The volume averaging theory is used to upscale the balance equations. The final DIM equations are presented below. The balance equation of solid phase can be written as {partialrho_{s}(1-\\varepsilon_{f})}/{partial t}=-K_{sl} where \\varepsilonf represents the volume fraction of the fluids (liquid+gas) and Ksl refers to the mass exchange between the solid phase and the liquid phase. Ksl cam be expressed as K_{sl}=rho_{l}alpha(omega_{eq}-Omega_{Al}). The balance equations of liquid phase can be written as {partialrho_{l}\\varepsilon_{f}S_{l}}/{partial t}+nabla\\cdot(rho_{l}{V}_{l})= K_{sl}. The balance equation of liquid phase can be written as {partialrho
NASA Technical Reports Server (NTRS)
1997-01-01
Many prominent rocks near the Sagan Memorial Station are featured in this image, taken in stereo by the Imager for Mars Pathfinder (IMP) on Sol 3. 3D glasses are necessary to identify surface detail. Wedge is at lower left; Shark, Half-Dome, and Pumpkin are at center. Flat Top, about four inches high, is at lower right. The horizon in the distance is one to two kilometers away.
Mars Pathfinder is the second in NASA's Discovery program of low-cost spacecraft with highly focused science goals. The Jet Propulsion Laboratory, Pasadena, CA, developed and manages the Mars Pathfinder mission for NASA's Office of Space Science, Washington, D.C. JPL is an operating division of the California Institute of Technology (Caltech). The Imager for Mars Pathfinder (IMP) was developed by the University of Arizona Lunar and Planetary Laboratory under contract to JPL. Peter Smith is the Principal Investigator.
Click below to see the left and right views individually. [figure removed for brevity, see original site] Left [figure removed for brevity, see original site] Right
NASA Technical Reports Server (NTRS)
2004-01-01
This 3-D, microscopic imager mosaic of a target area on a rock called 'Diamond Jenness' was taken after NASA's Mars Exploration Rover Opportunity ground into the surface with its rock abrasion tool for a second time.
Opportunity has bored nearly a dozen holes into the inner walls of 'Endurance Crater.' On sols 177 and 178 (July 23 and July 24, 2004), the rover worked double-duty on Diamond Jenness. Surface debris and the bumpy shape of the rock resulted in a shallow and irregular hole, only about 2 millimeters (0.08 inch) deep. The final depth was not enough to remove all the bumps and leave a neat hole with a smooth floor. This extremely shallow depression was then examined by the rover's alpha particle X-ray spectrometer.
On Sol 178, Opportunity's 'robotic rodent' dined on Diamond Jenness once again, grinding almost an additional 5 millimeters (about 0.2 inch). The rover then applied its Moessbauer spectrometer to the deepened hole. This double dose of Diamond Jenness enabled the science team to examine the rock at varying layers. Results from those grindings are currently being analyzed.
The image mosaic is about 6 centimeters (2.4 inches) across.
NASA Technical Reports Server (NTRS)
1997-01-01
This area of terrain near the Sagan Memorial Station was taken on Sol 3 by the Imager for Mars Pathfinder (IMP). 3D glasses are necessary to identify surface detail.
The IMP is a stereo imaging system with color capability provided by 24 selectable filters -- twelve filters per 'eye.' It stands 1.8 meters above the Martian surface, and has a resolution of two millimeters at a range of two meters.
Mars Pathfinder is the second in NASA's Discovery program of low-cost spacecraft with highly focused science goals. The Jet Propulsion Laboratory, Pasadena, CA, developed and manages the Mars Pathfinder mission for NASA's Office of Space Science, Washington, D.C. JPL is an operating division of the California Institute of Technology (Caltech). The Imager for Mars Pathfinder (IMP) was developed by the University of Arizona Lunar and Planetary Laboratory under contract to JPL. Peter Smith is the Principal Investigator.
Click below to see the left and right views individually. [figure removed for brevity, see original site] Left [figure removed for brevity, see original site] Right
NASA Astrophysics Data System (ADS)
Borman, V. D.; Belogorlov, A. A.; Bortnikova, S. A.; Tronin, V. N.
2016-09-01
The relaxation of a confined nonwetting liquid dispersed in a disordered nanoporous medium has been experimentally studied in the system consisting of water and the L23 hydrophobized silica gel. Discovered that the relaxation of these states to study the system occurs as a result of the relaxation of local metastable configurations of filled and empty pores of the porous medium. Such relaxation occurs abnormally slowly back to the power law with the exponent α < 0.16. The observed anomalously slow relaxation of such a system and comparison with the time dependence of the volume of the confined liquid obtained in confirm the correctness of the description of disordered media on the basis of the notion of local metastable structures.
NASA Astrophysics Data System (ADS)
Garg, B. P.; Singh, K. D.; Bansal, A. K.
2015-02-01
An analysis of an oscillatory magnetohydrodynamic (MHD) convective flow of a second order (viscoelastic), incompressible, and electrically conducting fluid through a porous medium bounded by two infinite vertical parallel porous plates is presented. The two porous plates with slip-flow condition and the no-slip condition are subjected respectively to a constant injection and suction velocity. The pressure gradient in the channel varies periodically with time. A magnetic field of uniform strength is applied in the direction perpendicular to the planes of the plates. The induced magnetic field is neglected due to the assumption of a small magnetic Reynolds number. The temperature of the plate with no-slip condition is non-uniform and oscillates periodically with time and the temperature difference of the two plates is assumed high enough to induce heat radiation. The entire system rotates in unison about the axis perpendicular to the planes of the plates. Adopting complex variable notations, a closed form solution of the problem is obtained. The analytical results are evaluated numerically and then presented graphically to discuss in detail the effects of different parameters of the problem. The velocity, temperature and the skin-friction in terms of its amplitude and phase angle have been shown graphically to observe the effects of the viscoelastic parameter γ, rotation parameter Ω, suction parameter λ , Grashof number Gr, Hartmann number M, the pressure A, Prandtl number Pr, radiation parameter N and the frequency of oscillation ω .
NASA Astrophysics Data System (ADS)
Ray, Nadja; Rupp, Andreas; Knabner, Peter
2016-04-01
Soil is arguably the most prominent example of a natural porous medium that is composed of a porous matrix and a pore space. Within this framework and in terms of soil's heterogeneity, we first consider transport and fluid flow at the pore scale. From there, we develop a mechanistic model and upscale it mathematically to transfer our model from the small scale to that of the mesoscale (laboratory scale). The mathematical framework of (periodic) homogenization (in principal) rigorously facilitates such processes by exactly computing the effective coefficients/parameters by means of the pore geometry and processes. In our model, various small-scale soil processes may be taken into account: molecular diffusion, convection, drift emerging from electric forces, and homogeneous reactions of chemical species in a solvent. Additionally, our model may consider heterogeneous reactions at the porous matrix, thus altering both the porosity and the matrix. Moreover, our model may additionally address biophysical processes, such as the growth of biofilms and how this affects the shape of the pore space. Both of the latter processes result in an intrinsically variable soil structure in space and time. Upscaling such models under the assumption of a locally periodic setting must be performed meticulously to preserve information regarding the complex coupling of processes in the evolving heterogeneous medium. Generally, a micro-macro model emerges that is then comprised of several levels of couplings: Macroscopic equations that describe the transport and fluid flow at the scale of the porous medium (mesoscale) include averaged time- and space-dependent coefficient functions. These functions may be explicitly computed by means of auxiliary cell problems (microscale). Finally, the pore space in which the cell problems are defined is time- and space dependent and its geometry inherits information from the transport equation's solutions. Numerical computations using mixed finite
Gray, William G.; Miller, Cass T.
2010-01-01
This work is the eighth in a series that develops the fundamental aspects of the thermodynamically constrained averaging theory (TCAT) that allows for a systematic increase in the scale at which multiphase transport phenomena is modeled in porous medium systems. In these systems, the explicit locations of interfaces between phases and common curves, where three or more interfaces meet, are not considered at scales above the microscale. Rather, the densities of these quantities arise as areas per volume or length per volume. Modeling of the dynamics of these measures is an important challenge for robust models of flow and transport phenomena in porous medium systems, as the extent of these regions can have important implications for mass, momentum, and energy transport between and among phases, and formulation of a capillary pressure relation with minimal hysteresis. These densities do not exist at the microscale, where the interfaces and common curves correspond to particular locations. Therefore, it is necessary for a well-developed macroscale theory to provide evolution equations that describe the dynamics of interface and common curve densities. Here we point out the challenges and pitfalls in producing such evolution equations, develop a set of such equations based on averaging theorems, and identify the terms that require particular attention in experimental and computational efforts to parameterize the equations. We use the evolution equations developed to specify a closed two-fluid-phase flow model. PMID:21197134
Miller, Cass T.
2009-01-01
This work is the fifth in a series of papers on the thermodynamically constrained averaging theory (TCAT) approach for modeling flow and transport phenomena in multiscale porous medium systems. The general TCAT framework and the mathematical foundation presented in previous works are used to develop models that describe species transport and single-fluid-phase flow through a porous medium system in varying physical regimes. Classical irreversible thermodynamics formulations for species in fluids, solids, and interfaces are developed. Two different approaches are presented, one that makes use of a momentum equation for each entity along with constitutive relations for species diffusion and dispersion, and a second approach that makes use of a momentum equation for each species in an entity. The alternative models are developed by relying upon different approaches to constrain an entropy inequality using mass, momentum, and energy conservation equations. The resultant constrained entropy inequality is simplified and used to guide the development of closed models. Specific instances of dilute and non-dilute systems are examined and compared to alternative formulation approaches. PMID:22563137
NASA Astrophysics Data System (ADS)
Ezzat, M. A.; El-Bary, A. A.; Hatem, A. S.
2014-07-01
A technique of the state space approach and the inversion of the Laplace transform method are applied to dimensionless equations of an unsteady one-dimensional boundary-layer flow due to heat and mass transfer through a porous medium saturated with a viscoelastic fluid bounded by an infinite vertical plate in the presence of a uniform magnetic field is described. Complete analytical solutions for the temperature, concentration, velocity, and induced magnetic and electric fields are presented. The inversion of the Laplace transforms is carried out by using a numerical approach. The proposed method is used to solve two problems: boundary-layer flow in a viscoelastic fluid near a vertical wall subjected to the initial conditions of a stepwise temperature and concentration and viscoelastic fluid flow between two vertical walls. The solutions are found to be dependent on the governing parameters including the Prandtl number, the Schmidt number, the Grashof number, reaction rate coefficient, viscoelastic parameter, and permeability of the porous medium. Effects of these major parameters on the transport behavior are investigated methodically, and typical results are illustrated to reveal the tendency of the solutions. Representative results are presented for the velocity, temperature, concentration, and induced magnetic and electric field distributions, as well as the local skin-friction coefficient and the local Nusselt and Sherwood numbers.
Bioinspired gas bubble spontaneous and directional transportation effects in an aqueous medium.
Ma, Rui; Wang, Jingming; Yang, Zhongjia; Liu, Meng; Zhang, Jingjing; Jiang, Lei
2015-04-01
A series of well-ordered, 3D gradient porous interconnected network surfaces composed of micro-nano hierarchical geometries is constructed on a copper wire. A continuous gas film can be trapped around its interface in an aqueous medium acting as an effective channel for gas transportation. Driving by the difference of the Laplace pressure, gas bubbles can be transported spontaneously and directionally.
Microscale transport in porous media
Rashidi, M.; Rinker, R.
1996-04-01
In-pore transport processes in homogeneous and heterogeneous porous media have been investigated using novel 3D imaging techniques. The experimental system consists of a clear column packed with clear particles and a refractive index-matched fluid seeded with fluorescent tracers and an organic solute dye. By illuminating the porous regions within the column with a planar sheet of laser beam, flow and transport processes through the porous medium can be observed microscopically, and qualitative and quantitative in-pore transport information can be obtained at a good resolution and a high accuracy. Fluorescent images are captured and recorded at every vertical plane location while sweeping back and forth across the test section. These digitized transport images are then analyzed and accumulated over a 3D volume within the column. This paper reports on pore-scale observations of velocity, chemical concentration, and fluxes. Tests were undertaken with two separate columns. One is a rectangular column for chemical transport and bioremediation studies in aqueous heterogeneous systems and the other is a cylindrical column for flow and transport investigations in nonaqueous homogeneous systems.
Shim3d Helmholtz Solution Package
2009-01-29
This suite of codes solves the Helmholtz Equation for the steady-state propagation of single-frequency electromagnetic radiation in an arbitrary 2D or 3D dielectric medium. Materials can be either transparent or absorptive (including metals) and are described entirely by their shape and complex dielectric constant. Dielectric boundaries are assumed to always fall on grid boundaries and the material within a single grid cell is considered to be uniform. Input to the problem is in the formmore » of a Dirichlet boundary condition on a single boundary, and may be either analytic (Gaussian) in shape, or a mode shape computed using a separate code (such as the included eigenmode solver vwave20), and written to a file. Solution is via the finite difference method using Jacobi iteration for 3D problems or direct matrix inversion for 2D problems. Note that 3D problems that include metals will require different iteration parameters than described in the above reference. For structures with curved boundaries not easily modeled on a rectangular grid, the auxillary codes helmholtz11(2D), helm3d (semivectoral), and helmv3d (full vectoral) are provided. For these codes the finite difference equations are specified on a topological regular triangular grid and solved using Jacobi iteration or direct matrix inversion as before. An automatic grid generator is supplied.« less
Full-color holographic 3D printer
NASA Astrophysics Data System (ADS)
Takano, Masami; Shigeta, Hiroaki; Nishihara, Takashi; Yamaguchi, Masahiro; Takahashi, Susumu; Ohyama, Nagaaki; Kobayashi, Akihiko; Iwata, Fujio
2003-05-01
A holographic 3D printer is a system that produces a direct hologram with full-parallax information using the 3-dimensional data of a subject from a computer. In this paper, we present a proposal for the reproduction of full-color images with the holographic 3D printer. In order to realize the 3-dimensional color image, we selected the 3 laser wavelength colors of red (λ=633nm), green (λ=533nm), and blue (λ=442nm), and we built a one-step optical system using a projection system and a liquid crystal display. The 3-dimensional color image is obtained by synthesizing in a 2D array the multiple exposure with these 3 wavelengths made on each 250mm elementary hologram, and moving recording medium on a x-y stage. For the natural color reproduction in the holographic 3D printer, we take the approach of the digital processing technique based on the color management technology. The matching between the input and output colors is performed by investigating first, the relation between the gray level transmittance of the LCD and the diffraction efficiency of the hologram and second, by measuring the color displayed by the hologram to establish a correlation. In our first experimental results a non-linear functional relation for single and multiple exposure of the three components were found. These results are the first step in the realization of a natural color 3D image produced by the holographic color 3D printer.
NASA Astrophysics Data System (ADS)
Meheust, Y.; Toussaint, R.; Lovoll, G.; Maloy, K. J.
2015-12-01
P.G. Saffman & G. Taylor (1958) studied the stability of the interface between two immiscible fluids of different densities and viscosities when one displaces the other inside a Hele-Shaw (HS) cell. They showed that with a horizontal cell and if the displaced fluid is the more viscous, the interface is unstable and leads to a viscous fingering which they nearly fully modeled [1]. The HS geometry was introduced as a geometry imposing the same flow behavior as the Darcy-scale flow in a two-dimensional (2D) porous medium, and therefore allowing an analogy between the two configurations. This is however not obvious, since capillary forces act at very different scales in the two. Later, researchers performing unstable displacement experiments in HS cells containing random 2D porous media also observed viscous fingering at large viscosity ratios, but with invasion patterns very different from those of Saffman and Taylor (ST) [2-3]. It was however considered that the two processes were both Laplacian growth processes, i.e., processes in which the invasion probability density is proportional to the pressure gradient. Ten years ago, we investigated viscously-unstable drainage in 2D porous media experimentally and measured the growth activity as well as occupation probability maps for the invasion process [4-5]. We concluded that in viscous fingering in 2D porous media, the activity was rather proportional to the square of the pressure gradient magnitude (a so-called DBM model of exponent 2), so that the universality class of the growth/invasion process was different from that of ST viscous fingering. We now strengthen our claim with new results based on the comparison of (i) pressure measurements with the pressure field around a finger such as described by the ST analytical model, and (ii) branching angles in the invasion patterns with those expected for DBMs of various exponents. [1] Saffman, P. G. and Taylor, G. Proc. Soc. London 1958(Ser A 245), 312-329. [2] Lenormand, R
Embedding objects during 3D printing to add new functionalities.
Yuen, Po Ki
2016-07-01
A novel method for integrating and embedding objects to add new functionalities during 3D printing based on fused deposition modeling (FDM) (also known as fused filament fabrication or molten polymer deposition) is presented. Unlike typical 3D printing, FDM-based 3D printing could allow objects to be integrated and embedded during 3D printing and the FDM-based 3D printed devices do not typically require any post-processing and finishing. Thus, various fluidic devices with integrated glass cover slips or polystyrene films with and without an embedded porous membrane, and optical devices with embedded Corning(®) Fibrance™ Light-Diffusing Fiber were 3D printed to demonstrate the versatility of the FDM-based 3D printing and embedding method. Fluid perfusion flow experiments with a blue colored food dye solution were used to visually confirm fluid flow and/or fluid perfusion through the embedded porous membrane in the 3D printed fluidic devices. Similar to typical 3D printed devices, FDM-based 3D printed devices are translucent at best unless post-polishing is performed and optical transparency is highly desirable in any fluidic devices; integrated glass cover slips or polystyrene films would provide a perfect optical transparent window for observation and visualization. In addition, they also provide a compatible flat smooth surface for biological or biomolecular applications. The 3D printed fluidic devices with an embedded porous membrane are applicable to biological or chemical applications such as continuous perfusion cell culture or biocatalytic synthesis but without the need for any post-device assembly and finishing. The 3D printed devices with embedded Corning(®) Fibrance™ Light-Diffusing Fiber would have applications in display, illumination, or optical applications. Furthermore, the FDM-based 3D printing and embedding method could also be utilized to print casting molds with an integrated glass bottom for polydimethylsiloxane (PDMS) device replication
Embedding objects during 3D printing to add new functionalities.
Yuen, Po Ki
2016-07-01
A novel method for integrating and embedding objects to add new functionalities during 3D printing based on fused deposition modeling (FDM) (also known as fused filament fabrication or molten polymer deposition) is presented. Unlike typical 3D printing, FDM-based 3D printing could allow objects to be integrated and embedded during 3D printing and the FDM-based 3D printed devices do not typically require any post-processing and finishing. Thus, various fluidic devices with integrated glass cover slips or polystyrene films with and without an embedded porous membrane, and optical devices with embedded Corning(®) Fibrance™ Light-Diffusing Fiber were 3D printed to demonstrate the versatility of the FDM-based 3D printing and embedding method. Fluid perfusion flow experiments with a blue colored food dye solution were used to visually confirm fluid flow and/or fluid perfusion through the embedded porous membrane in the 3D printed fluidic devices. Similar to typical 3D printed devices, FDM-based 3D printed devices are translucent at best unless post-polishing is performed and optical transparency is highly desirable in any fluidic devices; integrated glass cover slips or polystyrene films would provide a perfect optical transparent window for observation and visualization. In addition, they also provide a compatible flat smooth surface for biological or biomolecular applications. The 3D printed fluidic devices with an embedded porous membrane are applicable to biological or chemical applications such as continuous perfusion cell culture or biocatalytic synthesis but without the need for any post-device assembly and finishing. The 3D printed devices with embedded Corning(®) Fibrance™ Light-Diffusing Fiber would have applications in display, illumination, or optical applications. Furthermore, the FDM-based 3D printing and embedding method could also be utilized to print casting molds with an integrated glass bottom for polydimethylsiloxane (PDMS) device replication
NASA Astrophysics Data System (ADS)
Parand, K.; Rad, J. A.; Ahmadi, M.
2016-09-01
Natural convective heat transfer in porous media which is of importance in the design of canisters for nuclear waste disposal has received considerable attention during the past few decades. This paper presents a comparison between two different analytical and numerical methods, i.e. pseudospectral and Adomian decomposition methods. The pseudospectral approach makes use of the orthogonal rational Jacobi functions; this method reduces the solution of the problem to a solution of a system of algebraic equations. Numerical results are compared with each other, showing that the pseudospectral method leads to more accurate results and is applicable on similar problems.
3D Elevation Program—Virtual USA in 3D
Lukas, Vicki; Stoker, J.M.
2016-01-01
The U.S. Geological Survey (USGS) 3D Elevation Program (3DEP) uses a laser system called ‘lidar’ (light detection and ranging) to create a virtual reality map of the Nation that is very accurate. 3D maps have many uses with new uses being discovered all the time.
3D Elevation Program—Virtual USA in 3D
Lukas, Vicki; Stoker, J.M.
2016-04-14
The U.S. Geological Survey (USGS) 3D Elevation Program (3DEP) uses a laser system called ‘lidar’ (light detection and ranging) to create a virtual reality map of the Nation that is very accurate. 3D maps have many uses with new uses being discovered all the time.
James Saiers; Joseph Ryan
2006-07-02
Radionuclides, metals, and dense non-aqueous phase liquids have contaminated about six billion cubic meters of soil at Department of Energy (DOE) sites. The subsurface transport of many of these contaminants is facilitated by colloids (i.e., microscopic, waterborne particles). The first step in the transport of contaminants from their sources to off-site surface water and groundwater is migration through the vadose zone. Developing our understanding of the migration of colloids and colloid-associated contaminants through the vadose zone is critical to assessing and controlling the release of contaminants from DOE sites. In this study, we examined the mobilization, transport, and filtration (retention) of mineral colloids and colloidassociated radionuclides within unsaturated porous media. This investigation involved laboratory column experiments designed to identify properties that affect colloid mobilization and retention and pore-scale visualization experiments designed to elucidate mechanisms that govern these colloid-mass transfer processes. The experiments on colloid mobilization and retention were supplemented with experiments on radionuclide transport through porous media and on radionuclide adsorption to mineral colloids. Observations from all of these experiments – the column and visualization experiments with colloids and the experiments with radionuclides – were used to guide the development of mathematical models appropriate for describing colloids and colloid-facilitated radionuclide transport through the vadose zone.
James Saiers
2006-06-28
Radionuclides, metals, and dense non-aqueous phase liquids have contaminated about six billion cubic meters of soil at Department of Energy (DOE) sites. The subsurface transport of many of these contaminants is facilitated by colloids (i.e., microscopic, waterborne particles). The first step in the transport of contaminants from their sources to off-site surface water and groundwater is migration through the vadose zone. Developing our understanding of the migration of colloids and colloid-associated contaminants through the vadose zone is critical to assessing and controlling the release of contaminants from DOE sites. In this study, we examined the mobilization, transport, and filtration (retention) of mineral colloids and colloid-associated radionuclides within unsaturated porous media. This investigation involved laboratory column experiments designed to identify properties that affect colloid mobilization and retention and pore-scale visualization experiments designed to elucidate mechanisms that govern these colloid-mass transfer processes. The experiments on colloid mobilization and retention were supplemented with experiments on radionuclide transport through porous media and on radionuclide adsorption to mineral colloids. Observations from all of these experiments – the column and visualization experiments with colloids and the experiments with radionuclides – were used to guide the development of mathematical models appropriate for describing colloids and colloid-facilitated radionuclide transport through the vadose zone.
Saiers, James; Ryan, Joseph
2005-06-01
Our research is guided by an EMSP objective to improve conceptual and predictive models of contaminant movement in vadose-zone environments. As described in the report National Roadmap for Vadose-Zone Science and Technology [DOE, 2001], soil-water colloids are capable of adsorbing contaminants, such as radionuclides and metals, and facilitating their migration through the vadose zone and towards groundwater reservoirs. Our research centers on advancing understanding of this phenomenon. In particular, we are combining mathematical modeling with laboratory experimentation at pore and column scales to (1) elucidate the effects of porewater-flow transients on colloid mobilization in unsaturated porous media; (2) explore the sensitivity of colloid deposition rates to changes in porewater chemistry and colloid mineralogy; (3) develop mathematical models appropriate for simulating colloid mobilization, transport, and deposition under both steady-flow and transient-flow conditions; (4) identify mechanisms that govern mineral-colloid mobilization and deposition in unsaturated porous media; (5) quantify the effects of mineral-grain geometry and surface roughness on colloid-filtration rates; and (6) evaluate the influences of colloids on the transport of strontium and cesium (i.e., DOE-contaminants-of-concern) through soils and sediments.
NASA Astrophysics Data System (ADS)
Rashidi, S.; Dehghan, M.; Ellahi, R.; Riaz, M.; Jamal-Abad, M. T.
2015-03-01
A mathematical model for two-dimensional fluid flow under the influence of stream wise transverse magnetic fields in laminar regime is simulated in this study. Heat transfer past a square diamond shaped porous obstacle is also taken into account. The attention is focused to investigate the effects of intensity and direction of magnetic field, Darcy and Reynolds numbers on the mechanism of convective heat transfer and flow structures. The Darcy-Brinkman-Forchheimer model along with the Maxwell equations is used. The nonlinear coupled equations using a finite volume approach (FVA) are solved numerically. The calculations are performed for different governing parameters such as Reynolds number, Nusselt number, Stuart number and Prandtl Number. The physical interpretation of velocity and isothermal contours is assigned through graphs. It is shown that the effects of a transverse magnetic field on flow behavior and heat transfer mechanism are more than that of the stream wise magnetic field. The configuration of streamlines and vorticity contours phenomena are also presented for porous diamond obstacle. Comparison of the numerical solutions with existing literature is also made.
Highly compressible 3D periodic graphene aerogel microlattices
Zhu, Cheng; Han, T. Yong-Jin; Duoss, Eric B.; Golobic, Alexandra M.; Kuntz, Joshua D.; Spadaccini, Christopher M.; Worsley, Marcus A.
2015-01-01
Graphene is a two-dimensional material that offers a unique combination of low density, exceptional mechanical properties, large surface area and excellent electrical conductivity. Recent progress has produced bulk 3D assemblies of graphene, such as graphene aerogels, but they possess purely stochastic porous networks, which limit their performance compared with the potential of an engineered architecture. Here we report the fabrication of periodic graphene aerogel microlattices, possessing an engineered architecture via a 3D printing technique known as direct ink writing. The 3D printed graphene aerogels are lightweight, highly conductive and exhibit supercompressibility (up to 90% compressive strain). Moreover, the Young's moduli of the 3D printed graphene aerogels show an order of magnitude improvement over bulk graphene materials with comparable geometric density and possess large surface areas. Adapting the 3D printing technique to graphene aerogels realizes the possibility of fabricating a myriad of complex aerogel architectures for a broad range of applications. PMID:25902277
Highly compressible 3D periodic graphene aerogel microlattices
Zhu, Cheng; Han, T. Yong-Jin; Duoss, Eric B.; Golobic, Alexandra M.; Kuntz, Joshua D.; Spadaccini, Christopher M.; Worsley, Marcus A.
2015-04-22
Graphene is a two-dimensional material that offers a unique combination of low density, exceptional mechanical properties, large surface area and excellent electrical conductivity. Recent progress has produced bulk 3D assemblies of graphene, such as graphene aerogels, but they possess purely stochastic porous networks, which limit their performance compared with the potential of an engineered architecture. Here we report the fabrication of periodic graphene aerogel microlattices, possessing an engineered architecture via a 3D printing technique known as direct ink writing. The 3D printed graphene aerogels are lightweight, highly conductive and exhibit supercompressibility (up to 90% compressive strain). Moreover, the Young’s moduli of the 3D printed graphene aerogels show an order of magnitude improvement over bulk graphene materials with comparable geometric density and possess large surface areas. Ultimately, adapting the 3D printing technique to graphene aerogels realizes the possibility of fabricating a myriad of complex aerogel architectures for a broad range of applications.
Highly compressible 3D periodic graphene aerogel microlattices.
Zhu, Cheng; Han, T Yong-Jin; Duoss, Eric B; Golobic, Alexandra M; Kuntz, Joshua D; Spadaccini, Christopher M; Worsley, Marcus A
2015-04-22
Graphene is a two-dimensional material that offers a unique combination of low density, exceptional mechanical properties, large surface area and excellent electrical conductivity. Recent progress has produced bulk 3D assemblies of graphene, such as graphene aerogels, but they possess purely stochastic porous networks, which limit their performance compared with the potential of an engineered architecture. Here we report the fabrication of periodic graphene aerogel microlattices, possessing an engineered architecture via a 3D printing technique known as direct ink writing. The 3D printed graphene aerogels are lightweight, highly conductive and exhibit supercompressibility (up to 90% compressive strain). Moreover, the Young's moduli of the 3D printed graphene aerogels show an order of magnitude improvement over bulk graphene materials with comparable geometric density and possess large surface areas. Adapting the 3D printing technique to graphene aerogels realizes the possibility of fabricating a myriad of complex aerogel architectures for a broad range of applications.
Highly compressible 3D periodic graphene aerogel microlattices
NASA Astrophysics Data System (ADS)
Zhu, Cheng; Han, T. Yong-Jin; Duoss, Eric B.; Golobic, Alexandra M.; Kuntz, Joshua D.; Spadaccini, Christopher M.; Worsley, Marcus A.
2015-04-01
Graphene is a two-dimensional material that offers a unique combination of low density, exceptional mechanical properties, large surface area and excellent electrical conductivity. Recent progress has produced bulk 3D assemblies of graphene, such as graphene aerogels, but they possess purely stochastic porous networks, which limit their performance compared with the potential of an engineered architecture. Here we report the fabrication of periodic graphene aerogel microlattices, possessing an engineered architecture via a 3D printing technique known as direct ink writing. The 3D printed graphene aerogels are lightweight, highly conductive and exhibit supercompressibility (up to 90% compressive strain). Moreover, the Young's moduli of the 3D printed graphene aerogels show an order of magnitude improvement over bulk graphene materials with comparable geometric density and possess large surface areas. Adapting the 3D printing technique to graphene aerogels realizes the possibility of fabricating a myriad of complex aerogel architectures for a broad range of applications.
Zhong, Hua; Liu, Guansheng; Jiang, Yongbing; Brusseau, Mark L; Liu, Zhifeng; Liu, Yang; Zeng, Guangming
2016-03-01
The success of effective bioaugmentation processes for remediation of soil and groundwater contamination requires effective transport of the injected microorganisms in the subsurface environment. In this study, the effect of low concentrations of monorhamnolipid biosurfactant solutions on transport of Pseudomonas aeruginosa in an ideal porous medium (glass beads) with hydrophilic or hydrophobic surfaces was investigated by conducting miscible-displacement experiments. Transport behavior was examined for both glucose-grown and hexadecane-grown cells, with low and high surface hydrophobicity, respectively. A clean-bed colloid deposition model was used for determination of deposition rate coefficients. Results show that cells with high surface hydrophobicity exhibit greater retention than cells with low surface hydrophobicity. Rhamnolipid affects cell transport primarily by changing cell surface hydrophobicity, with an additional minor effect by increasing solution ionic strength. There is a good linear relation between k and rhamnolipid-regulated cell surface hydrophobicity presented as bacterial-adhesion-to-hydrocarbon (BATH) rate of cells (R(2)=0.71). The results of this study show the importance of hydrophobic interaction for transport of bacterial cells in silica-based porous media, and the potential of using low-concentration rhamnolipid solutions for facilitating bacterial transport in bioaugmentation efforts. PMID:26722821
Zhong, Hua; Liu, Guansheng; Jiang, Yongbing; Brusseau, Mark L; Liu, Zhifeng; Liu, Yang; Zeng, Guangming
2016-03-01
The success of effective bioaugmentation processes for remediation of soil and groundwater contamination requires effective transport of the injected microorganisms in the subsurface environment. In this study, the effect of low concentrations of monorhamnolipid biosurfactant solutions on transport of Pseudomonas aeruginosa in an ideal porous medium (glass beads) with hydrophilic or hydrophobic surfaces was investigated by conducting miscible-displacement experiments. Transport behavior was examined for both glucose-grown and hexadecane-grown cells, with low and high surface hydrophobicity, respectively. A clean-bed colloid deposition model was used for determination of deposition rate coefficients. Results show that cells with high surface hydrophobicity exhibit greater retention than cells with low surface hydrophobicity. Rhamnolipid affects cell transport primarily by changing cell surface hydrophobicity, with an additional minor effect by increasing solution ionic strength. There is a good linear relation between k and rhamnolipid-regulated cell surface hydrophobicity presented as bacterial-adhesion-to-hydrocarbon (BATH) rate of cells (R(2)=0.71). The results of this study show the importance of hydrophobic interaction for transport of bacterial cells in silica-based porous media, and the potential of using low-concentration rhamnolipid solutions for facilitating bacterial transport in bioaugmentation efforts.
NASA Astrophysics Data System (ADS)
Lin, Yanhai; Zheng, Liancun; Zhang, Xinxin
2015-11-01
We present a research for the MHD Marangoni boundary layer flow and heat transfer in pseudo-plastic power law nanofluids over a porous medium driven by temperature gradient. A variable magnetic field is considered. Four different types of nanoparticles, copper, aluminum oxide, copper oxide, and titanium oxide are considered with pseudo-plastic power-law carboxy methyl cellulose (CMC)-water used as base fluids. A generalized Fourier law proposed by Zheng for varying thermal conductivity of nanofluids is taken into account, and the surface tension is assumed a quadratic function of the temperature. The governing partial differential equations (PDEs) are formulated, and similarity solutions are obtained numerically using shooting technique combined with Runge-Kutta iteration program and Newton's scheme. The effects of various physical parameters on horizontal velocity component and temperature curves are discussed and graphically illustrated in details.
NASA Astrophysics Data System (ADS)
Aaiza, Gul; Khan, Ilyas; Shafie, Sharidan
2015-12-01
Energy transfer in mixed convection unsteady magnetohydrodynamic (MHD) flow of an incompressible nanofluid inside a channel filled with saturated porous medium is investigated. The channel with non-uniform walls temperature is taken in a vertical direction under the influence of a transverse magnetic field. Based on the physical boundary conditions, three different flow situations are discussed. The problem is modelled in terms of partial differential equations with physical boundary conditions. Four different shapes of nanoparticles of equal volume fraction are used in conventional base fluids, ethylene glycol (EG) ( C 2 H 6 O 2 ) and water ( H 2 O). Solutions for velocity and temperature are obtained discussed graphically in various plots. It is found that viscosity and thermal conductivity are the most prominent parameters responsible for different results of velocity and temperature. Due to higher viscosity and thermal conductivity, C 2 H 6 O 2 is regarded as better convectional base fluid compared to H 2 O.
Yih, K.A.
1997-03-01
Effect of transpiration velocity on the heat and mass transfer characteristics of mixed convection about a permeable vertical plate embedded in a saturated porous medium under the coupled effects of thermal and mass diffusion is numerically analyzed. The plate is maintained at a uniform temperature and species concentration with constant transpiration velocity. The transformed governing equations are solved by Keller box method. Numerical results for the local Nusselt number and local Sherwood number are presented. In general, it has been found for thermally assisted flow that the local surface heat and mass transfer rates increase owing to suction of fluid. This trend reversed for blowing of fluid. It is apparent that the Lewis number has a pronounced effect on the local Sherwood number than it does on the local Nusselt number. Increasing the Lewis number decreases (increases) the local heat (mass) transfer rate.
Gray, William G.; Miller, Cass T.
2009-01-01
This work is the seventh in a series that introduces and employs the thermodynamically constrained averaging theory (TCAT) for modeling flow and transport in multiscale porous medium systems. This paper expands the previous analyses in the series by developing models at a scale where spatial variations within the system are not considered. Thus the time variation of variables averaged over the entire system is modeled in relation to fluxes at the boundary of the system. This implementation of TCAT makes use of conservation equations for mass, momentum, and energy as well as an entropy balance. Additionally, classical irreversible thermodynamics is assumed to hold at the microscale and is averaged to the megascale, or system scale. The fact that the local equilibrium assumption does not apply at the megascale points to the importance of obtaining closure relations that account for the large-scale manifestation of small-scale variations. Example applications built on this foundation are suggested to stimulate future work. PMID:20436941
2011-01-01
A boundary layer analysis is presented for the mixed convection past a vertical wedge in a porous medium saturated with a nano fluid. The governing partial differential equations are transformed into a set of non-similar equations and solved numerically by an efficient, implicit, iterative, finite-difference method. A parametric study illustrating the influence of various physical parameters is performed. Numerical results for the velocity, temperature, and nanoparticles volume fraction profiles, as well as the friction factor, surface heat and mass transfer rates have been presented for parametric variations of the buoyancy ratio parameter Nr, Brownian motion parameter Nb, thermophoresis parameter Nt, and Lewis number Le. The dependency of the friction factor, surface heat transfer rate (Nusselt number), and mass transfer rate (Sherwood number) on these parameters has been discussed. PMID:21711715
NASA Astrophysics Data System (ADS)
Singh, M.
2016-02-01
The instability of the plane interface between two uniform, superposed and streaming Rivlin-Ericksen elastico-viscous fluids through porous media, including the `effective interfacial tension' effect, is considered. In the absence of the `effective interfacial tension' stability/instability of the system as well as perturbations transverse to the direction of streaming are found to be unaffected by the presence of streaming if perturbations in the direction of streaming are ignored, whereas for perturbation in all other directions, there exists instability for a certain wave number range. The `effective interfacial tension' is able to suppress this Kelvin-Helmholtz instability for small wavelength perturbations, the medium porosity reduces the stability range given in terms of a difference in streaming velocities.
NASA Astrophysics Data System (ADS)
Singh, K. D.
2016-08-01
An unsteady mixed convection flow of a visco-elastic, incompressible and electrically conducting fluid in a hot vertical channel is analyzed. The vertical channel is filled with a porous medium. The temperature of one of the channel plates is considered to be fluctuating span-wise cosinusoidally, i.e., T^* ( {y^* ,z^* ,t^* } ) = T_1 + ( {T_2} - {T_ 1} ) cos ( {{{π z^* } over d} - ω ^* t^* } ). A magnetic field of uniform strength is applied perpendicular to the planes of the plates. The magnetic Reynolds number is assumed very small so that the induced magnetic field is neglected. It is also assumed that the conducting fluid is gray, absorbing/emitting radiation and non-scattering. Governing equations are solved exactly for the velocity and the temperature fields. The effects of various flow parameters on the velocity, temperature and the skin friction and the Nusselt number in terms of their amplitudes and phase angles are discussed with the help of figures.
Aaiza, Gul; Khan, Ilyas; Shafie, Sharidan
2015-12-01
Energy transfer in mixed convection unsteady magnetohydrodynamic (MHD) flow of an incompressible nanofluid inside a channel filled with saturated porous medium is investigated. The channel with non-uniform walls temperature is taken in a vertical direction under the influence of a transverse magnetic field. Based on the physical boundary conditions, three different flow situations are discussed. The problem is modelled in terms of partial differential equations with physical boundary conditions. Four different shapes of nanoparticles of equal volume fraction are used in conventional base fluids, ethylene glycol (EG) (C 2 H 6 O 2 ) and water (H 2 O). Solutions for velocity and temperature are obtained discussed graphically in various plots. It is found that viscosity and thermal conductivity are the most prominent parameters responsible for different results of velocity and temperature. Due to higher viscosity and thermal conductivity, C 2 H 6 O 2 is regarded as better convectional base fluid compared to H 2 O. PMID:26698873
Gorla, Rama Subba Reddy; Chamkha, Ali Jawad; Rashad, Ahmed Mohamed
2011-01-01
A boundary layer analysis is presented for the mixed convection past a vertical wedge in a porous medium saturated with a nano fluid. The governing partial differential equations are transformed into a set of non-similar equations and solved numerically by an efficient, implicit, iterative, finite-difference method. A parametric study illustrating the influence of various physical parameters is performed. Numerical results for the velocity, temperature, and nanoparticles volume fraction profiles, as well as the friction factor, surface heat and mass transfer rates have been presented for parametric variations of the buoyancy ratio parameter Nr, Brownian motion parameter Nb, thermophoresis parameter Nt, and Lewis number Le. The dependency of the friction factor, surface heat transfer rate (Nusselt number), and mass transfer rate (Sherwood number) on these parameters has been discussed.
Rao, B V Bhaskara; Yadav, Prasad; Aepuru, Radhamanohar; Panda, H S; Ogale, Satishchandra; Kale, S N
2015-07-28
In this study, a novel composite of Fe3O4 nanofiller-decorated single-layer graphene-assembled porous carbon (SLGAPC) with polyvinyl alcohol (PVA) having flexibility and a density of 0.75 g cm(-3) is explored for its dielectric and electromagnetic interference (EMI) response properties. The composite is prepared by the solution casting method and its constituents are optimized as 15 wt% SLGAPC and 20 wt% Fe3O4 through a novel solvent relaxation nuclear magnetic resonance experiment. The PVA-SLGAPC-Fe3O4 composite shows high dielectric permittivity in the range of 1 Hz-10 MHz, enhanced by a factor of 4 as compared to that of the PVA-SLGAPC composite, with a reduced loss by a factor of 2. The temperature dependent dielectric properties reveal the activation energy behaviour with reference to the glass transition temperature (80 °C) of PVA. The dielectric hysteresis with the temperature cycle reveals a remnant polarization. The enhanced dielectric properties are suggested to be the result of improvement in the localized polarization of the integrated interface system (Maxwell-Wagner-Sillars (MWS) polarization) formed by the uniform adsorption of Fe3O4 on the surface of SLGAPC conjugated with PVA. The EMI shielding property of the composite with a low thickness of 0.3 mm in the X-band (8.2-12.4 GHz) shows a very impressive shielding efficiency of ∼15 dB and a specific shielding effectiveness of 20 dB (g cm(-3))(-1), indicating the promising character of this material for flexible EMI shielding applications. PMID:26105548
Rao, B V Bhaskara; Yadav, Prasad; Aepuru, Radhamanohar; Panda, H S; Ogale, Satishchandra; Kale, S N
2015-07-28
In this study, a novel composite of Fe3O4 nanofiller-decorated single-layer graphene-assembled porous carbon (SLGAPC) with polyvinyl alcohol (PVA) having flexibility and a density of 0.75 g cm(-3) is explored for its dielectric and electromagnetic interference (EMI) response properties. The composite is prepared by the solution casting method and its constituents are optimized as 15 wt% SLGAPC and 20 wt% Fe3O4 through a novel solvent relaxation nuclear magnetic resonance experiment. The PVA-SLGAPC-Fe3O4 composite shows high dielectric permittivity in the range of 1 Hz-10 MHz, enhanced by a factor of 4 as compared to that of the PVA-SLGAPC composite, with a reduced loss by a factor of 2. The temperature dependent dielectric properties reveal the activation energy behaviour with reference to the glass transition temperature (80 °C) of PVA. The dielectric hysteresis with the temperature cycle reveals a remnant polarization. The enhanced dielectric properties are suggested to be the result of improvement in the localized polarization of the integrated interface system (Maxwell-Wagner-Sillars (MWS) polarization) formed by the uniform adsorption of Fe3O4 on the surface of SLGAPC conjugated with PVA. The EMI shielding property of the composite with a low thickness of 0.3 mm in the X-band (8.2-12.4 GHz) shows a very impressive shielding efficiency of ∼15 dB and a specific shielding effectiveness of 20 dB (g cm(-3))(-1), indicating the promising character of this material for flexible EMI shielding applications.
NASA Technical Reports Server (NTRS)
1977-01-01
A market study of a proposed version of a 3-D eyetracker for initial use at NASA's Ames Research Center was made. The commercialization potential of a simplified, less expensive 3-D eyetracker was ascertained. Primary focus on present and potential users of eyetrackers, as well as present and potential manufacturers has provided an effective means of analyzing the prospects for commercialization.
None
2016-07-12
This video provides an overview of the Sandia National Laboratories developed 3-D World Model Building capability that provides users with an immersive, texture rich 3-D model of their environment in minutes using a laptop and color and depth camera.
2013-10-30
This video provides an overview of the Sandia National Laboratories developed 3-D World Model Building capability that provides users with an immersive, texture rich 3-D model of their environment in minutes using a laptop and color and depth camera.
2013-10-01
Earth3D is a computer code designed to allow fast calculation of seismic rays and travel times through a 3D model of the Earth. LLNL is using this for earthquake location and global tomography efforts and such codes are of great interest to the Earth Science community.
[3-D ultrasound in gastroenterology].
Zoller, W G; Liess, H
1994-06-01
Three-dimensional (3D) sonography represents a development of noninvasive diagnostic imaging by real-time two-dimensional (2D) sonography. The use of transparent rotating scans, comparable to a block of glass, generates a 3D effect. The objective of the present study was to optimate 3D presentation of abdominal findings. Additional investigations were made with a new volumetric program to determine the volume of selected findings of the liver. The results were compared with the estimated volumes of 2D sonography and 2D computer tomography (CT). For the processing of 3D images, typical parameter constellations were found for the different findings, which facilitated processing of 3D images. In more than 75% of the cases examined we found an optimal 3D presentation of sonographic findings with respect to the evaluation criteria developed by us for the 3D imaging of processed data. Great differences were found for the estimated volumes of the findings of the liver concerning the three different techniques applied. 3D ultrasound represents a valuable method to judge morphological appearance in abdominal findings. The possibility of volumetric measurements enlarges its potential diagnostic significance. Further clinical investigations are necessa