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Sample records for 48h waste treatment

  1. Benzene Generation Testing for Tank 48H Waste Disposition

    SciTech Connect

    Peters, T

    2005-05-13

    In support for the Aggregation option1, researchers performed a series of tests using actual Tank 48H slurries. The tests were designed to examine potential benzene generation issues if the Tank 48H slurry is disposed to Saltstone. Personnel used the archived Tank 48H sample (HTF-E-03-127, collected September 17, 2003) for the experiments. The tests included a series of three experiments (Tests A, B, and F) performed in duplicate, giving a total of six experiments. Test A used Tank 48H slurry mixed with {approx}20:1 with Defense Waste Processing Facility (DWPF) Recycle from Tanks 21H and 22H. Test B used Tank 48H slurry mixed with {approx}2.7:1 with DWPF Recycle from Tanks 21H and 22H, while Test F used Tank 48H slurry as-is. Tests A and B occurred at 45 C, while Test F occurred at 55 C. Over a period of 8 weeks, personnel collected samples for analysis, once per week. Each sample was tested with the in-cell gamma counter. The researchers noted a decline in the cesium activity in solution which is attributed to temperature dependence of the complex slurry equilibrium. Selected samples were sent to ADS for potassium, boron, and cesium analysis. The benzene generation rate was inferred from the TPB destruction which is indirectly measured by the in-growth of cesium, potassium or boron. The results of all the analyses reveal no discernible in-growth of radiocesium, potassium or boron, indicating no significant tetraphenylborate (TPB) decomposition in any of the experiments. From boron measurements, the inferred rate of TPB destruction remained less than 0.332 mg/(L-h) implying a maximum benzene generation rate of <0.325 mg/(L-h).

  2. Treatment of SRS Tank 48H Simulants Using Fenton's Reagent

    SciTech Connect

    Taylor, PA

    2003-11-18

    High-level-waste Tank 48H at the Savannah River Site (SRS) contains about 50,000 lb of tetraphenylborate (TPB), which must be destroyed to return the tank to active service. Laboratory-scale tests were conducted to evaluate the use of Fenton's Reagent (hydrogen peroxide and a metal catalyst) to treat simulants of the Tank 48H waste. Samples of the treated slurry and the off-gas were analyzed to determine the reaction products. Process parameters developed earlier by AEA Technology were used for these tests; namely (for 500 mL of waste simulant), reduce pH to 7.5 with nitric acid, heat to boiling, add hydrogen peroxide at 1 mL/min for 1 h, reduce pH to 3.5, and add the remaining peroxide at 2 mL/min. These parameters were developed to minimize the formation of tarry materials during the early part of the reaction and to minimize the concentration of total organic carbon in the final treated slurry. The treated samples contained low concentrations of total organic carbon (TOC) and no detectable TPB. Tests using a mixture of iron and copper salts as the Fenton's catalyst had a lower TOC concentration in the final treated slurry than did tests that used a copper-only catalyst. TPB is known to hydrolyze to benzene, particularly at high temperature and low pH, and copper is known to increase the rate of hydrolysis. Significant amounts of benzene were present in the off-gas from the tests, especially during the early portion of the treatment, indicating that the hydrolysis reaction was occurring in parallel with the oxidation of the TPB by Fenton's reagent. For the reaction conditions used in these tests, approximately equal fractions of the TPB were converted to benzene and carbon dioxide. Minimizing the formation of benzene is important to SRS personnel; however, this consideration was not addressed in the AEA-recommended parameters, since they did not analyze for benzene in the off-gas. Smaller amounts of carbon monoxide and other organics were also produced. One test

  3. Development of Chemical Treatment Alternatives for Tetraphenylborate Destruction in Tank 48H

    SciTech Connect

    Lambert, D.P.

    2003-03-11

    This study assessed chemical treatment options for decomposing the tetraphenylborate in High Level Waste (HLW) Tank 48H. Tank 48H, located at the Savannah River Site in Aiken, SC, contains approximately one million liters of HLW. The tetraphenylborate slurry represents legacy material from commissioning of an In Tank Precipitation process to separate radioactive cesium and actinides from the nonradioactive chemicals. During early operations, the process encountered an unplanned chemical reaction that catalytically decomposed the excess tetraphenylborate producing benzene. Subsequent research indicated that personnel could not control the operations within the existing equipment to both meet the desired treatment rate for the waste and maintain the benzene concentration within allowable concentrations. Since then, the Department of Energy selected an alternate treatment process for handling high-level waste at the site. However, the site must destroy the tetraphenylborate before returning the tank to HLW service. The research focuses on identifying treatments to decompose tetraphenylborate to the maximum extent feasible, with a preference for decomposition methods that produce carbon dioxide rather than benzene. A number of experiments examined whether the use of oxidants, catalysts or acids proved effective in decomposing the tetraphenylborate. Additional experiments developed an understanding of the solid, liquid and gas decomposition products.

  4. BENCH-SCALE STEAM REFORMING OF ACTUAL TANK 48H WASTE

    SciTech Connect

    Burket, P; Gene Daniel, G; Charles Nash, C; Carol Jantzen, C; Michael Williams, M

    2008-09-25

    Fluidized Bed Steam Reforming (FBSR) has been demonstrated to be a viable technology to remove >99% of the organics from Tank 48H simulant, to remove >99% of the nitrate/nitrite from Tank 48H simulant, and to form a solid product that is primarily carbonate based. The technology was demonstrated in October of 2006 in the Engineering Scale Test Demonstration Fluidized Bed Steam Reformer1 (ESTD FBSR) at the Hazen Research Inc. (HRI) facility in Golden, CO. The purpose of the Bench-scale Steam Reformer (BSR) testing was to demonstrate that the same reactions occur and the same product is formed when steam reforming actual radioactive Tank 48H waste. The approach used in the current study was to test the BSR with the same Tank 48H simulant and same Erwin coal as was used at the ESTD FBSR under the same operating conditions. This comparison would allow verification that the same chemical reactions occur in both the BSR and ESTD FBSR. Then, actual radioactive Tank 48H material would be steam reformed in the BSR to verify that the actual tank 48H sample reacts the same way chemically as the simulant Tank 48H material. The conclusions from the BSR study and comparison to the ESTD FBSR are the following: (1) A Bench-scale Steam Reforming (BSR) unit was successfully designed and built that: (a) Emulated the chemistry of the ESTD FBSR Denitration Mineralization Reformer (DMR) and Carbon Reduction Reformer (CRR) known collectively as the dual reformer flowsheet. (b) Measured and controlled the off-gas stream. (c) Processed real (radioactive) Tank 48H waste. (d) Met the standards and specifications for radiological testing in the Savannah River National Laboratory (SRNL) Shielded Cells Facility (SCF). (2) Three runs with radioactive Tank 48H material were performed. (3) The Tetraphenylborate (TPB) was destroyed to > 99% for all radioactive Bench-scale tests. (4) The feed nitrate/nitrite was destroyed to >99% for all radioactive BSR tests the same as the ESTD FBSR. (5) The

  5. DESTRUCTION OF TETRAPHENYLBORATE IN TANK 48H USING WET AIR OXIDATION BATCH BENCH SCALE AUTOCLAVE TESTING WITH ACTUAL RADIOACTIVE TANK 48H WASTE

    SciTech Connect

    Adu-Wusu, K; Paul Burket, P

    2009-03-31

    Wet Air Oxidation (WAO) is one of the two technologies being considered for the destruction of Tetraphenylborate (TPB) in Tank 48H. Batch bench-scale autoclave testing with radioactive (actual) Tank 48H waste is among the tests required in the WAO Technology Maturation Plan. The goal of the autoclave testing is to validate that the simulant being used for extensive WAO vendor testing adequately represents the Tank 48H waste. The test objective was to demonstrate comparable test results when running simulated waste and real waste under similar test conditions. Specifically: (1) Confirm the TPB destruction efficiency and rate (same reaction times) obtained from comparable simulant tests, (2) Determine the destruction efficiency of other organics including biphenyl, (3) Identify and quantify the reaction byproducts, and (4) Determine off-gas composition. Batch bench-scale stirred autoclave tests were conducted with simulated and actual Tank 48H wastes at SRNL. Experimental conditions were chosen based on continuous-flow pilot-scale simulant testing performed at Siemens Water Technologies Corporation (SWT) in Rothschild, Wisconsin. The following items were demonstrated as a result of this testing. (1) Tetraphenylborate was destroyed to below detection limits during the 1-hour reaction time at 280 C. Destruction efficiency of TPB was > 99.997%. (2) Other organics (TPB associated compounds), except biphenyl, were destroyed to below their respective detection limits. Biphenyl was partially destroyed in the process, mainly due to its propensity to reside in the vapor phase during the WAO reaction. Biphenyl is expected to be removed in the gas phase during the actual process, which is a continuous-flow system. (3) Reaction byproducts, remnants of MST, and the PUREX sludge, were characterized in this work. Radioactive species, such as Pu, Sr-90 and Cs-137 were quantified in the filtrate and slurry samples. Notably, Cs-137, boron and potassium were shown as soluble as a

  6. Tank 48H Waste Composition and Results of Investigation of Analytical Methods

    SciTech Connect

    Walker , D.D.

    1997-04-02

    This report serves two purposes. First, it documents the analytical results of Tank 48H samples taken between April and August 1996. Second, it describes investigations of the precision of the sampling and analytical methods used on the Tank 48H samples.

  7. STEAM REFORMING TECHNOLOGY DEMONSTRATION FOR THE DESTRUCTION OF ORGANICS ON ACTUAL DOE SAVANNAH RIVER SITE TANK 48H WASTE 9138

    SciTech Connect

    Burket, P

    2009-02-24

    This paper describes the design of the Bench-scale Steam Reformer (BSR); a processing unit for demonstrating steam reforming technology on actual radioactive waste [1]. It describes the operating conditions of the unit used for processing a sample of Savannah River Site (SRS) Tank 48H waste. Finally, it compares the results from processing the actual waste in the BSR to processing simulant waste in the BSR to processing simulant waste in a large pilot scale unit, the Fluidized Bed Steam Reformer (FBSR), operated at Hazen Research Inc. in Golden, CO. The purpose of this work was to prove that the actual waste reacted in the same manner as the simulant waste in order to validate the work performed in the pilot scale unit which could only use simulant waste.

  8. Treatments (12 and 48 h) with systemic and brain-selective hypothermia techniques after permanent focal cerebral ischemia in rat.

    PubMed

    Clark, Darren L; Penner, Mark; Wowk, Shannon; Orellana-Jordan, Ian; Colbourne, Frederick

    2009-12-01

    Mild hypothermia lessens brain injury when initiated after the onset of global or focal ischemia. The present study sought to determine whether cooling to approximately 33 degrees C provides enduring benefit when initiated 1 h after permanent middle cerebral artery occlusion (pMCAO, via electrocautery) in adult rats and whether protection depends upon treatment duration and cooling technique. In the first experiment, systemic cooling was induced in non-anesthetized rats through a whole-body exposure technique that used fans and water mist. In comparison to normothermic controls, 12- and 48-h bouts of hypothermia significantly lessened functional impairment, such as skilled reaching ability, and lesion volume out to a 1-month survival. In the second experiment, brain-selective cooling was induced in awake rats via a water-cooled metal strip implanted underneath the temporalis muscle overlying the ischemic territory. Use of a 48-h cooling treatment significantly mitigated injury and behavioral impairment whereas a 12-h treatment did not. These findings show that while systemic and focal techniques are effective when initiated after the onset of pMCAO, they differ in efficacy depending upon the treatment duration. A direct and uncomplicated comparison between methods is problematic, however, due to unknown gradients in brain temperature and the use of two separate experiments. In summary, prolonged cooling, even when delayed after onset of pMCAO, provides enduring behavioral and histological protection sufficient to suggest that it will be clinically effective. Nonetheless, further pre-clinical work is needed to improve treatment protocols, such as identifying the optimal depth of cooling, and how these factors interact with cooling method.

  9. FATE OF FISSILE MATERIAL BOUND TO MONOSODIUM TITANATE DURING COOPER CATALYZED PEROXIDE OXIDATION OF TANK 48H WASTE

    SciTech Connect

    Taylor-Pashow, K.

    2012-08-09

    At the Savannah River Site (SRS), Tank 48H currently holds approximately 240,000 gallons of slurry which contains potassium and cesium tetraphenylborate (TPB). A copper catalyzed peroxide oxidation (CCPO) reaction is currently being examined as a method for destroying the TPB present in Tank 48H. Part of the development of that process includes an examination of the fate of the Tank 48H fissile material which is adsorbed onto monosodium titanate (MST) particles. This report details results from experiments designed to examine the potential degradation of MST during CCPO processing and the subsequent fate of the adsorbed fissile material. Experiments were conducted to simulate the CCPO process on MST solids loaded with sorbates in a simplified Tank 48H simulant. Loaded MST solids were placed into the Tank 48H simplified simulant without TPB, and the experiments were then carried through acid addition (pH adjustment to 11), peroxide addition, holding at temperature (50 C) for one week, and finally NaOH addition to bring the free hydroxide concentration to a target concentration of 1 M. Testing was conducted without TPB to show the maximum possible impact on MST since the competing oxidation of TPB with peroxide was absent. In addition, the Cu catalyst was also omitted, which will maximize the interaction of H{sub 2}O{sub 2} with the MST; however, the results may be non-conservative assuming the Cu-peroxide active intermediate is more reactive than the peroxide radical itself. The study found that both U and Pu desorb from the MST when the peroxide addition begins, although to different extents. Virtually all of the U goes into solution at the beginning of the peroxide addition, whereas Pu reaches a maximum of {approx}34% leached during the peroxide addition. Ti from the MST was also found to come into solution during the peroxide addition. Therefore, Ti is present with the fissile in solution. After the peroxide addition is complete, the Pu and Ti are found to

  10. Packaged Waste Treatment

    NASA Technical Reports Server (NTRS)

    1977-01-01

    This Jacksonville, Florida, apartment complex has a wastewater treatment system which clears the water, removes harmful microorganisms and reduces solid residue to ash. It is a spinoff from spacecraft waste management and environmental control technology.

  11. Lyophilization -Solid Waste Treatment

    NASA Technical Reports Server (NTRS)

    Litwiller, Eric; Flynn, Michael; Fisher, John; Reinhard, Martin

    2004-01-01

    This paper discusses the development of a solid waste treatment system that has been designed for a Mars transit exploration mission. The technology described is an energy-efficient lyophilization technique that is designed to recover water from spacecraft solid wastes. Candidate wastes include feces, concentrated brines from water processors, and other solid wastes that contain free water. The system is designed to operate as a stand-alone process or to be integrated into the International Space Station Waste Collection System. In the lyophilization process, water in an aqueous waste is frozen and then sublimed, separating the waste into a dried solid material and liquid water. The sublimed water is then condensed in a solid ice phase and then melted to generate a liquid product. In the subject system the waste solids are contained within a 0.2 micron bio-guard bag and after drying are removed from the system and stored in a secondary container. This technology is ideally suited to applications such as the Mars Reference Mission, where water recovery rates approaching 100% are desirable but production of CO2 is not. The system is designed to minimize power consumption through the use of thermoelectric heat pumps. The results of preliminary testing of a prototype system and testing of the final configuration are provided. A mathematical model of the system is also described.

  12. Treatment of organic waste

    DOEpatents

    Grantham, LeRoy F.

    1979-01-01

    An organic waste containing at least one element selected from the group consisting of strontium, cesium, iodine and ruthenium is treated to achieve a substantial reduction in the volume of the waste and provide for fixation of the selected element in an inert salt. The method of treatment comprises introducing the organic waste and a source of oxygen into a molten salt bath maintained at an elevated temperature to produce solid and gaseous reaction products. The gaseous reaction products comprise carbon dioxide and water vapor, and the solid reaction products comprise the inorganic ash constituents of the organic waste and the selected element which is retained in the molten salt. The molten salt bath comprises one or more alkali metal carbonates, and may optionally include from 1 to about 25 wt.% of an alkali metal sulfate.

  13. Microbiology of Waste Treatment.

    ERIC Educational Resources Information Center

    Unz, Richard F.

    1978-01-01

    Presents a literature review of the microbiology of waste treatment, covering publications of 1976-77. This review includes topics such as: (1) sanitary microbiology; (2) wastewater disinfectant; (3) viruses in wastewater; and (4) wastewater microbial populations. A list of 142 references is also presented. (HM)

  14. Waste Treatment Plant - 12508

    SciTech Connect

    Harp, Benton; Olds, Erik

    2012-07-01

    The Waste Treatment Plant (WTP) will immobilize millions of gallons of Hanford's tank waste into solid glass using a proven technology called vitrification. The vitrification process will turn the waste into a stable glass form that is safe for long-term storage. Our discussion of the WTP will include a description of the ongoing design and construction of this large, complex, first-of-a-kind project. The concept for the operation of the WTP is to separate high-level and low-activity waste fractions, and immobilize those fractions in glass using vitrification. The WTP includes four major nuclear facilities and various support facilities. Waste from the Tank Farms is first pumped to the Pretreatment Facility at the WTP through an underground pipe-in-pipe system. When construction is complete, the Pretreatment Facility will be 12 stories high, 540 feet long and 215 feet wide, making it the largest of the four major nuclear facilities that compose the WTP. The total size of this facility will be more than 490,000 square feet. More than 8.2 million craft hours are required to construct this facility. Currently, the Pretreatment Facility is 51 percent complete. At the Pretreatment Facility the waste is pumped to the interior waste feed receipt vessels. Each of these four vessels is 55-feet tall and has a 375,000 gallon capacity, which makes them the largest vessels inside the Pretreatment Facility. These vessels contain a series of internal pulse-jet mixers to keep incoming waste properly mixed. The vessels are inside the black-cell areas, completely enclosed behind thick steel-laced, high strength concrete walls. The black cells are designed to be maintenance free with no moving parts. Once hot operations commence the black-cell area will be inaccessible. Surrounded by black cells, is the 'hot cell canyon'. The hot cell contains all the moving and replaceable components to remove solids and extract liquids. In this area, there is ultrafiltration equipment, cesium

  15. Microbiological aspects of aerobic thermophilic treatment of swine waste.

    PubMed Central

    Beaudet, R; Gagnon, C; Bisaillon, J G; Ishaque, M

    1990-01-01

    A thermophilic strain (D2) identified as a Bacillus sp. was isolated from an aerobic digestor of swine waste after several months of operation at 55 degrees C. Aerobic thermophilic batch treatment of swine waste inoculated with strain D2 was studied in a 4-liter fixed-bed reactor. Stabilization of the waste was achieved in less than 30 h when the original chemical oxygen demand (COD) was between 15 and 20 g/liter or in less than 48 h when the COD was around 35 g/liter. When the COD was higher than 30 g/liter, the pH of the waste reached 9.2 to 9.5 during the treatment, and periodic adjustment of the pH to 8.5 was necessary to maintain the activity of the biofilm. In this reactor, ammoniacal nitrogen was completely eliminated by desorption in less than 72 h of incubation. The different packing materials used resulted in similar rates of degradation of organic matter. The thermophilic treatment was also efficient in the 75-liter digestor, and stabilization was achieved in approximately 50 h. A bank of 22 thermophilic bacterial strains originating from different environments and adapted to the thermophilic treatment of swine waste was established. This thermophilic treatment allows, in one step, rapid stabilization of the waste, elimination of the bad smell, and complete elimination of ammonia nitrogen by stripping. PMID:2339880

  16. PNNL Supports Hanford Waste Treatment

    ScienceCinema

    None

    2016-07-12

    For more than 40 years, technical assistance from PNNL has supported the operations and processing of Hanford tank waste. Our expertise in tank waste chemistry, fluid dynamics and scaling, waste forms, and safety bases has helped to shape the site’s waste treatment baseline and solve operational challenges. The historical knowledge and unique scientific and technical expertise at PNNL are essential to the success of the Hanford mission.

  17. PNNL Supports Hanford Waste Treatment

    SciTech Connect

    2015-06-16

    For more than 40 years, technical assistance from PNNL has supported the operations and processing of Hanford tank waste. Our expertise in tank waste chemistry, fluid dynamics and scaling, waste forms, and safety bases has helped to shape the site’s waste treatment baseline and solve operational challenges. The historical knowledge and unique scientific and technical expertise at PNNL are essential to the success of the Hanford mission.

  18. Treatment of mercury containing waste

    DOEpatents

    Kalb, Paul D.; Melamed, Dan; Patel, Bhavesh R; Fuhrmann, Mark

    2002-01-01

    A process is provided for the treatment of mercury containing waste in a single reaction vessel which includes a) stabilizing the waste with sulfur polymer cement under an inert atmosphere to form a resulting mixture and b) encapsulating the resulting mixture by heating the mixture to form a molten product and casting the molten product as a monolithic final waste form. Additional sulfur polymer cement can be added in the encapsulation step if needed, and a stabilizing additive can be added in the process to improve the leaching properties of the waste form.

  19. Solid Waste Treatment Technology

    ERIC Educational Resources Information Center

    Hershaft, Alex

    1972-01-01

    Advances in research and commercial solid waste handling are offering many more processing choices. This survey discusses techniques of storage and removal, fragmentation and sorting, bulk reduction, conversion, reclamation, mining and mineral processing, and disposal. (BL)

  20. Treatment of ORNL process waste

    SciTech Connect

    Berry, J.B.; Brown, C.H. Jr.; Fowler, V.L.; Robinson, S.M.

    1988-01-01

    Because of the shutdown of the hydrofracture process at ORNL, intensive efforts were made to reduce contaminated liquid waste generation rates. Treatment of slightly radioactive process waste has been dramatically improved. The volume of secondary, radioactively contaminated waste streams and the concentration of pollutants discharged to the environment have been reduced. Further improvements, based on results of research and development, are planned. The future value of alternative flowsheets will be compared with process flexibility to determine the optimal upgrade to the treatment plant. 1 ref., 4 figs., 2 tabs.

  1. SECONDARY WASTE MANAGEMENT STRATEGY FOR EARLY LOW ACTIVITY WASTE TREATMENT

    SciTech Connect

    TW, CRAWFORD

    2008-07-17

    This study evaluates parameters relevant to River Protection Project secondary waste streams generated during Early Low Activity Waste operations and recommends a strategy for secondary waste management that considers groundwater impact, cost, and programmatic risk. The recommended strategy for managing River Protection Project secondary waste is focused on improvements in the Effiuent Treatment Facility. Baseline plans to build a Solidification Treatment Unit adjacent to Effluent Treatment Facility should be enhanced to improve solid waste performance and mitigate corrosion of tanks and piping supporting the Effiuent Treatment Facility evaporator. This approach provides a life-cycle benefit to solid waste performance and reduction of groundwater contaminants.

  2. Assessing mixed waste treatment technologies

    SciTech Connect

    Berry, J.B.; Bloom, G.A.; Hart, P.W.

    1994-06-01

    The US Department of Energy (DOE) is responsible for the management and treatment of its mixed low-level wastes (MLLW). As discussed earlier in this conference MLLW are regulated under both the Resource Conservation and Recovery Act and various DOE orders. During the next 5 years, DOE will manage over 1,200,000 m{sup 3} of MLLW and mixed transuranic (MTRU) waste at 50 sites in 22 states (see Table 1). The difference between MLLW and MTRU waste is in the concentration of elements that have a higher atomic weight than uranium. Nearly all of this waste will be located at 13 sites. More than 1400 individual mixed waste streams exist with different chemical and physical matrices containing a wide range of both hazardous and radioactive contaminants. Their containment and packaging vary widely (e.g., drums, bins, boxes, and buried waste). This heterogeneity in both packaging and waste stream constituents makes characterization difficult, which results in costly sampling and analytical procedures and increased risk to workers.

  3. WASTE TREATMENT BUILDING SYSTEM DESCRIPTION DOCUMENT

    SciTech Connect

    F. Habashi

    2000-06-22

    The Waste Treatment Building System provides the space, layout, structures, and embedded subsystems that support the processing of low-level liquid and solid radioactive waste generated within the Monitored Geologic Repository (MGR). The activities conducted in the Waste Treatment Building include sorting, volume reduction, and packaging of dry waste, and collecting, processing, solidification, and packaging of liquid waste. The Waste Treatment Building System is located on the surface within the protected area of the MGR. The Waste Treatment Building System helps maintain a suitable environment for the waste processing and protects the systems within the Waste Treatment Building (WTB) from most of the natural and induced environments. The WTB also confines contaminants and provides radiological protection to personnel. In addition to the waste processing operations, the Waste Treatment Building System provides space and layout for staging of packaged waste for shipment, industrial and radiological safety systems, control and monitoring of operations, safeguards and security systems, and fire protection, ventilation and utilities systems. The Waste Treatment Building System also provides the required space and layout for maintenance activities, tool storage, and administrative facilities. The Waste Treatment Building System integrates waste processing systems within its protective structure to support the throughput rates established for the MGR. The Waste Treatment Building System also provides shielding, layout, and other design features to help limit personnel radiation exposures to levels which are as low as is reasonably achievable (ALARA). The Waste Treatment Building System interfaces with the Site Generated Radiological Waste Handling System, and with other MGR systems that support the waste processing operations. The Waste Treatment Building System interfaces with the General Site Transportation System, Site Communications System, Site Water System, MGR

  4. Drydock Waste Treatment Study.

    DTIC Science & Technology

    1977-07-01

    are primary contaminants. Theoretical and experimental analysis of heavy metal treatment methods are presented. This analysis indicates that sulfide...precipitation would be a prime candidate for heavy metal removal but would require further research and development. (Author)

  5. Innovative hazardous waste treatment technology

    SciTech Connect

    Freeman, H.M.; Sferra, P.R. . Hazardous Waste Engineering Research Lab.)

    1990-01-01

    This book contains 21 various biodegradation techniques for hazardous waste treatment. Topics include: cyclic vertical water table movement for enhancement of in situ biodegradation of diesel fuel; enhanced biodegradation of petroleum hydrocarbons; and evaluation of aeration methods to bioremediate fuel-contaminated soils.

  6. Biological treatment of drilling waste

    SciTech Connect

    Perie, F.H.; Seris, J.L.; Martignon, A.P.

    1995-12-01

    Off shore operators are now faced with more stringent forthcoming regulations regarding waste discharge. Several aspects are to be taken into account when considering waste disposal in the sea; among them, the total amount of COD and the toxicity. While, in many regards, the problem caused by the processing fluids toxicity has been addressed, the elimination of residual COD from the waste is yet to be solved. Biodegradation of drilling waste is one of the major routes taken by third party contracters to address the reduction of COD in sea-discharged cuttings. This report describes a technique specifically developed to enhance drilling waste biodegradation under selected conditions. The suggested treatment involved biological catalysts used in conjunction with or prior to the biodegradation. We demonstrated that the considered environment-compatible substitute for oil-based mud could be more efficiently biodegraded if an enzymatic pretreatment was carried out prior to or during the actual biodegradation. The biodegradation rate, expressed as CO{sub 2} envolvement, was significantly higher in lipase-treated cultures. In addition, we demonstrated that this treatment was applicable to substrates in emulsion, suspension, or adsorbed on solid.

  7. Multimedia strategy considers waste treatment

    SciTech Connect

    Phillips, J.B.

    1995-05-01

    The advent of multimedia pollution prevention programs has raised some interesting and challenging questions on the subject of facility operations. First and foremost is the goal of a multimedia pollution prevention program: how can industrial streams in an operating facility be treated to prevent pollutants from escaping in a particular effluent or waste streams without transferring the same pollutants to another medium? Once this is resolved, the next issue to be addressed is the fate of pollutants removed from effluent streams. EPA is moving toward discouraging destruction as an acceptable means of waste treatment. The strategies are presented for handling pollutants from one media without contaminating another.

  8. Biological treatment of hazardous waste

    SciTech Connect

    Lewandowski, G.A.; Filippi, L.J. de

    1998-12-01

    This reference book is intended for individuals interested in or involved with the treatment of hazardous wastes using biological/biochemical processes. Composed of 13 chapters, it covers a wide variety of topics ranging from engineering design to hydrogeologic factors. The first four chapters are devoted to a description of several different types of bioreactors. Chapter 5 discusses the biofiltration of volatile organic compounds. Chapters 6 through 9 discuss specific biological, biochemical, physical, and engineering factors that affect bioremediation of hazardous wastes. Chapter 10 is a very good discussion of successful bioremediation of pentachlorophenol contamination under laboratory and field conditions, and excellent references are provided. The next chapter discusses the natural biodegradation of PCB-contaminated sediments in the Hudson River in New York state. Chapter 12 takes an excellent look at the bioremediation capability of anaerobic organisms. The final chapter discusses composting of hazardous waste.

  9. Treatment of mixed waste coolant

    SciTech Connect

    Kidd, S.; Bowers, J.S.

    1995-02-01

    The primary processes used at Lawrence Livermore National Laboratory (LLNL) for treatment of radioactively contaminated machine coolants are industrial waste treatment and in situ carbon adsorption. These two processes simplify approaches to meeting the sanitary sewer discharge limits and subsequent Land Disposal Restriction criteria for hazardous and mixed wastes (40 CFR 268). Several relatively simple technologies are used in industrial water treatment. These technologies are considered Best Demonstrated Available Technologies, or BDAT, by the Environmental Protection Agency. The machine coolants are primarily aqueous and contain water soluble oil consisting of ethanol amine emulsifiers derived from fatty acids, both synthetic and natural. This emulsion carries away metal turnings from a part being machined on a lathe or other machining tool. When the coolant becomes spent, it contains chlorosolvents carried over from other cutting operations as well as a fair amount of tramp oil from machine bearings. This results in a multiphasic aqueous waste that requires treatment of metal and organic contaminants. During treatment, any dissolved metals are oxidized with hydrogen peroxide. Once oxidized, these metals are flocculated with ferric sulfate and precipitated with sodium hydroxide, and then the precipitate is filtered through diatomaceous earth. The emulsion is broken up by acidifying the coolant. Solvents and oils are adsorbed using powdered carbon. This carbon is easily separated from the remaining coolant by vacuum filtration.

  10. Electrochemical treatment of liquid wastes

    SciTech Connect

    Hobbs, D.T.

    1997-10-01

    Under this task, electrochemical treatment processes are being evaluated and developed for the destruction of organic compounds and nitrates/nitrites and the removal of other hazardous species from liquid wastes stored throughout the DOE complex. This technology targets the (1) destruction of nitrates, nitrites and organic compounds; (2) removal of radionuclides; and (3) removal of RCRA metals. The development program consists of five major tasks: (1) evaluation of electrochemical reactors for the destruction and removal of hazardous waste components, (2) development and validation of engineering process models, (3) radioactive laboratory-scale tests, (4) demonstration of the technology in an engineering-scale reactor, and (5) analysis and evaluation of test data. The development program team is comprised of individuals from national laboratories, academic institutions, and private industry. Possible benefits of this technology include: (1) improved radionuclide separation as a result of the removal of organic complexants, (2) reduction in the concentrations of hazardous and radioactive species in the waste (e.g., removal of nitrate, mercury, chromium, cadmium, {sup 99}Tc, and {sup 106}Ru), (3) reduction in the size of the off-gas handling equipment for the vitrification of low-level waste (LLW) by reducing the source of NO{sub x} emissions, (4) recovery of chemicals of value (e.g. sodium hydroxide), and (5) reduction in the volume of waste requiring disposal.

  11. A Primer on Waste Water Treatment.

    ERIC Educational Resources Information Center

    Department of the Interior, Washington, DC. Federal Water Pollution Control Administration.

    This information pamphlet is for teachers, students, or the general public concerned with the types of waste water treatment systems, the need for further treatment, and advanced methods of treating wastes. Present day pollution control methods utilizing primary and secondary waste treatment plants, lagoons, and septic tanks are described,…

  12. Mixed waste characterization, treatment & disposal focus area

    SciTech Connect

    1996-08-01

    The mission of the Mixed Waste Characterization, Treatment, and Disposal Focus Area (referred to as the Mixed Waste Focus Area or MWFA) is to provide treatment systems capable of treating DOE`s mixed waste in partnership with users, and with continual participation of stakeholders, tribal governments, and regulators. The MWFA deals with the problem of eliminating mixed waste from current and future storage in the DOE complex. Mixed waste is waste that contains both hazardous chemical components, subject to the requirements of the Resource Conservation and Recovery Act (RCRA), and radioactive components, subject to the requirements of the Atomic Energy Act. The radioactive components include transuranic (TRU) and low-level waste (LLW). TRU waste primarily comes from the reprocessing of spent fuel and the use of plutonium in the fabrication of nuclear weapons. LLW includes radioactive waste other than uranium mill tailings, TRU, and high-level waste, including spent fuel.

  13. Waste treatment integration in space

    NASA Technical Reports Server (NTRS)

    Baresi, L.; Kern, R.

    1991-01-01

    The circumstances and criteria for space-based waste treatment bioregenerative life-support systems differ in many ways from those needed in terrestrial applications. In fact, the term "waste" may not even be appropriate in the context of nearly closed, cycling, ecosystems such as those under consideration. Because of these constraints there is a need for innovative approaches to the problem of "materials recycling". Hybrid physico-chemico-biological systems offer advantages over both strictly physico-chemico or biological approaches that would be beneficial to material recycling. To effectively emulate terrestrial cycling, the use of various microbial consortia ("assemblies of interdependent microbes") should be seriously considered for the biological components of such systems. This paper will examine the use of consortia in the context of a hybrid-system for materials recycling in space.

  14. Waste treatment integration in space.

    PubMed

    Baresi, L; Kern, R

    1991-10-01

    The circumstances and criteria for space-based waste treatment bioregenerative life-support systems differ in many ways from those needed in terrestrial applications. In fact, the term "waste" may not even be appropriate in the context of nearly closed, cycling, ecosystems such as those under consideration. Because of these constraints there is a need for innovative approaches to the problem of "materials recycling". Hybrid physico-chemico-biological systems offer advantages over both strictly physico-chemico or biological approaches that would be beneficial to material recycling. To effectively emulate terrestrial cycling, the use of various microbial consortia ("assemblies of interdependent microbes") should be seriously considered for the biological components of such systems. This paper will examine the use of consortia in the context of a hybrid-system for materials recycling in space.

  15. Electrochemical treatment of liquid wastes

    SciTech Connect

    Hobbs, D.

    1996-10-01

    Electrochemical treatment processes are being evaluated and developed for the destruction of organic compounds and nitrates/nitrites and the removal of other hazardous species from liquid wastes stored throughout the DOE complex. This activity consists of five major tasks: (1) evaluation of different electrochemical reactors for the destruction and removal of hazardous waste components, (2) development and validation of engineering process models, (3) radioactive laboratory-scale tests, (4) demonstration of the technology in an engineering-scale size reactor, and (5) analysis and evaluation of testing data. The development program team is comprised of individuals from federal, academic, and private industry. Work is being carried out in DOE, academic, and private industrial laboratories.

  16. New treatment technologies for mixed waste

    SciTech Connect

    Bloom, G.

    1994-12-31

    This presentation describes new treatment technologies for mixed and low-level radioactive wastes. Several processes are described including mercury removal techniques, steam reforming from aqueous organic wastes, development of plasma treatment systems, waste vitrification and control and recovery of vapor phase mercury in combustion flue gas. Continuous monitoring of mercury, ammonia, acid gases, and volatile organic compounds and a brief description of final waste form development is presented.

  17. DOE mixed waste treatment capacity analysis

    SciTech Connect

    Ross, W.A.; Wehrman, R.R.; Young, J.R.; Shaver, S.R.

    1994-06-01

    This initial DOE-wide analysis compares the reported national capacity for treatment of mixed wastes with the calculated need for treatment capacity based on both a full treatment of mixed low-level and transuranic wastes to the Land Disposal Restrictions and on treatment of transuranic wastes to the WIPP waste acceptance criteria. The status of treatment capacity is reported based on a fifty-element matrix of radiation-handling requirements and functional treatment technology categories. The report defines the classifications for the assessment, describes the models used for the calculations, provides results from the analysis, and includes appendices of the waste treatment facilities data and the waste stream data used in the analysis.

  18. Mixed waste treatment model: Basis and analysis

    SciTech Connect

    Palmer, B.A.

    1995-09-01

    The Department of Energy`s Programmatic Environmental Impact Statement (PEIS) required treatment system capacities for risk and cost calculation. Los Alamos was tasked with providing these capacities to the PEIS team. This involved understanding the Department of Energy (DOE) Complex waste, making the necessary changes to correct for problems, categorizing the waste for treatment, and determining the treatment system requirements. The treatment system requirements depended on the incoming waste, which varied for each PEIS case. The treatment system requirements also depended on the type of treatment that was desired. Because different groups contributing to the PEIS needed specific types of results, we provided the treatment system requirements in a variety of forms. In total, some 40 data files were created for the TRU cases, and for the MLLW case, there were 105 separate data files. Each data file represents one treatment case consisting of the selected waste from various sites, a selected treatment system, and the reporting requirements for such a case. The treatment system requirements in their most basic form are the treatment process rates for unit operations in the desired treatment system, based on a 10-year working life and 20-year accumulation of the waste. These results were reported in cubic meters and for the MLLW case, in kilograms as well. The treatment system model consisted of unit operations that are linked together. Each unit operation`s function depended on the input waste streams, waste matrix, and contaminants. Each unit operation outputs one or more waste streams whose matrix, contaminants, and volume/mass may have changed as a result of the treatment. These output streams are then routed to the appropriate unit operation for additional treatment until the output waste stream meets the treatment requirements for disposal. The total waste for each unit operation was calculated as well as the waste for each matrix treated by the unit.

  19. Thermal co-treatment of combustible hazardous waste and waste incineration fly ash in a rotary kiln.

    PubMed

    Huber, Florian; Blasenbauer, Dominik; Mallow, Ole; Lederer, Jakob; Winter, Franz; Fellner, Johann

    2016-12-01

    As current disposal practices for municipal solid waste incineration (MSWI) fly ash are either associated with significant costs or negative environmental impacts, an alternative treatment was investigated in a field scale experiment. Thereto, two rotary kilns were fed with hazardous waste, and moistened MSWI fly ash (water content of 23%) was added to the fuel of one kiln with a ratio of 169kg/Mg hazardous waste for 54h and 300kg/Mg hazardous waste for 48h while the other kiln was used as a reference. It was shown that the vast majority (>90%) of the inserted MSWI fly ash was transferred to the bottom ash of the rotary kiln. This bottom ash complied with the legal limits for non-hazardous waste landfills, thereby demonstrating the potential of the investigated method to transfer hazardous waste (MSWI fly ash) into non-hazardous waste (bottom ash). The results of a simple mixing test (MSWI fly ash and rotary kiln bottom ash have been mixed accordingly without thermal treatment) revealed that the observed transformation of hazardous MSWI fly ash into non-hazardous bottom ash during thermal co-treatment cannot be referred to dilution, as the mixture did not comply with legal limits for non-hazardous waste landfills. For the newly generated fly ash of the kiln, an increase in the concentration of Cd, K and Pb by 54%, 57% and 22%, respectively, was observed. In general, the operation of the rotary kiln was not impaired by the MSWI fly ash addition.

  20. Innovative hazardous waste treatment technology

    SciTech Connect

    Freeman, H.M.; Sferra, P.R. . Hazardous Waste Engineering Research Lab.)

    1990-01-01

    This book contains information about the latest developments in destroying hazardous wastes by incineration or pyrolysis. Topics include: hydrogenation and reuse of hazardous organic wastes; catalytic incineration of gaseous wastes; oxygen enhancement of hazardous waste incineration; and thermal fixation of hazardous metal sludges in an alumina-silicate matrix.

  1. Liquid waste treatment system. Final report

    SciTech Connect

    Baker, M.N.; Houston, H.M.

    1999-06-01

    Pretreatment of high-level liquid radioactive waste (HLW) at the West Valley Demonstration Project (WVDP) involved three distinct processing operations: decontamination of liquid HLW in the Supernatant Treatment System (STS); volume reduction of decontaminated liquid in the Liquid Waste Treatment System (LWTS); and encapsulation of resulting concentrates into an approved cement waste form in the Cement Solidification System (CSS). Together, these systems and operations made up the Integrated Radwaste Treatment System (IRTS).

  2. Life cycle assessment of electronic waste treatment.

    PubMed

    Hong, Jinglan; Shi, Wenxiao; Wang, Yutao; Chen, Wei; Li, Xiangzhi

    2015-04-01

    Life cycle assessment was conducted to estimate the environmental impact of electronic waste (e-waste) treatment. E-waste recycling with an end-life disposal scenario is environmentally beneficial because of the low environmental burden generated from human toxicity, terrestrial ecotoxicity, freshwater ecotoxicity, and marine ecotoxicity categories. Landfill and incineration technologies have a lower and higher environmental burden than the e-waste recycling with an end-life disposal scenario, respectively. The key factors in reducing the overall environmental impact of e-waste recycling are optimizing energy consumption efficiency, reducing wastewater and solid waste effluent, increasing proper e-waste treatment amount, avoiding e-waste disposal to landfill and incineration sites, and clearly defining the duties of all stakeholders (e.g., manufacturers, retailers, recycling companies, and consumers).

  3. Radioactive waste treatment technologies and environment

    SciTech Connect

    HORVATH, Jan; KRASNY, Dusan

    2007-07-01

    The radioactive waste treatment and conditioning are the most important steps in radioactive waste management. At the Slovak Electric, plc, a range of technologies are used for the processing of radioactive waste into a form suitable for disposal in near surface repository. These technologies operated by JAVYS, PLc. Nuclear and Decommissioning Company, PLc. Jaslovske Bohunice are described. Main accent is given to the Bohunice Radwaste Treatment and Conditioning Centre, Bituminization plant, Vitrification plant, and Near surface repository of radioactive waste in Mochovce and their operation. Conclusions to safe and effective management of radioactive waste in the Slovak Republic are presented. (authors)

  4. Solid waste treatment processes for space station

    NASA Technical Reports Server (NTRS)

    Marrero, T. R.

    1983-01-01

    The purpose of this study was to evaluate the state-of-the-art of solid waste(s) treatment processes applicable to a Space Station. From the review of available information a source term model for solid wastes was determined. An overall system is proposed to treat solid wastes under constraints of zero-gravity and zero-leakage. This study contains discussion of more promising potential treatment processes, including supercritical water oxidation, wet air (oxygen) oxidation, and chemical oxidation. A low pressure, batch-type treament process is recommended. Processes needed for pretreatment and post-treatment are hardware already developed for space operations. The overall solid waste management system should minimize transfer of wastes from their collection point to treatment vessel.

  5. Life cycle assessment of electronic waste treatment

    SciTech Connect

    Hong, Jinglan; Shi, Wenxiao; Wang, Yutao; Chen, Wei; Li, Xiangzhi

    2015-04-15

    Highlights: • Life cycle assessment of electronic waste recycling is quantified. • Key factors for reducing the overall environmental impact are indentified. • End-life disposal processes provide significant environmental benefits. • Efficiently reduce the improper disposal amount of e-waste is highly needed. • E-waste incineration can generate significant environmental burden. - Abstract: Life cycle assessment was conducted to estimate the environmental impact of electronic waste (e-waste) treatment. E-waste recycling with an end-life disposal scenario is environmentally beneficial because of the low environmental burden generated from human toxicity, terrestrial ecotoxicity, freshwater ecotoxicity, and marine ecotoxicity categories. Landfill and incineration technologies have a lower and higher environmental burden than the e-waste recycling with an end-life disposal scenario, respectively. The key factors in reducing the overall environmental impact of e-waste recycling are optimizing energy consumption efficiency, reducing wastewater and solid waste effluent, increasing proper e-waste treatment amount, avoiding e-waste disposal to landfill and incineration sites, and clearly defining the duties of all stakeholders (e.g., manufacturers, retailers, recycling companies, and consumers)

  6. Experiences with treatment of mixed waste

    SciTech Connect

    Dziewinski, J.; Marczak, S.; Smith, W.H.; Nuttall, E.

    1996-04-10

    During its many years of research activities involving toxic chemicals and radioactive materials, Los Alamos National Laboratory (Los Alamos) has generated considerable amounts of waste. Much of this waste includes chemically hazardous components and radioisotopes. Los Alamos chose to use an electrochemical process for the treatment of many mixed waste components. The electro-chemical process, which the authors are developing, can treat a great variety of waste using one type of equipment built at a moderate expense. Such a process can extract heavy metals, destroy cyanides, dissolve contamination from surfaces, oxidize toxic organic compounds, separate salts into acids and bases, and reduce the nitrates. All this can be accomplished using the equipment and one crew of trained operating personnel. Results of a treatability study of chosen mixed wastes from Los Alamos Mixed Waste Inventory are presented. Using electrochemical methods cyanide and heavy metals bearing wastes were treated to below disposal limits.

  7. Electrochemical treatment of mixed and hazardous waste

    SciTech Connect

    Dziewinski, J.; Marczak, S.; Smith, W.; Nuttall, E.

    1995-12-31

    Los Alamos National Laboratory (LANL) and The University of New Mexico are jointly developing an electrochemical process for treating hazardous and radioactive wastes. The wastes treatable by the process include toxic metal solutions, cyanide solutions, and various organic wastes that may contain chlorinated organic compounds. The main component of the process is a stack of electrolytic cells with peripheral equipment such as a rectifier, feed system, tanks with feed and treated solutions, and a gas-venting system. During the treatment, toxic metals are deposited on the cathode, cyanides are oxidized on the anode, and organic compounds are anodically oxidized by direct or mediated electrooxidation, depending on their type. Bench scale experimental studies have confirmed the feasibility of applying electrochemical systems to processing of a great variety of hazardous and mixed wastes. The operating parameters have been defined for different waste compositions using surrogate wastes. Mixed wastes are currently treated at bench scale as part of the treatability study.

  8. Innovative hazardous waste treatment technology

    SciTech Connect

    Freeman, H.M.; Sferra, P.R. . Hazardous Waste Engineering Research Lab.)

    1990-01-01

    This book contains technical overviews of new processes for reducing hazardous waste volume. These processes are based upon physico-chemical principles. Topics include: vacuum extraction for cleanup of soils and groundwater; catalytic hydrodechlorination; on stripping technology; and recovery and disposal of nitrate wastes.

  9. Chemical aspects of nuclear waste treatment

    SciTech Connect

    Bond, W. D.

    1980-01-01

    The chemical aspects of the treatment of gaseous, liquid, and solid wastes are discussed in overview. The role of chemistry and the chemical reactions in waste treatment are emphasized. Waste treatment methods encompass the chemistry of radioactive elements from every group of the periodic table. In most streams, the radioactive elements are present in relatively low concentrations and are often associated with moderately large amounts of process reagents, or materials. In general, it is desirable that waste treatment methods are based on chemistry that is selective for the concentration of radionuclides and does not require the addition of reagents that contribute significantly to the volume of the treated waste. Solvent extraction, ion exchange, and sorbent chemistry play a major role in waste treatment because of the high selectivity provided for many radionuclides. This paper deals with the chemistry of the onsite treatment methods that is typically used at nuclear installations and is not concerned with the chemistry of the various alternative materials proposed for long-term storage of nuclear wastes. The chemical aspects are discussed from a generic point of view in which the chemistry of important radionuclides is emphasized.

  10. Waste treatment in silicon production operations

    NASA Technical Reports Server (NTRS)

    Coleman, Larry M. (Inventor); Tambo, William (Inventor)

    1985-01-01

    A battery of special burners, each adapted for the treatment of a particular range of waste material formed during the conversion of metallurgical grade silicon to high purity silane and silicon, is accompanied by a series arrangement of filters to recover fumed silica by-product and a scrubber to recover muriatic acid as another by-product. All of the wastes are processed, during normal and plant upset waste load conditions, to produce useful by-products in an environmentally acceptable manner rather than waste materials having associated handling and disposal problems.

  11. Disposition of Tank 48H Organics by Fluidized Bed Steam Reforming (FBSR)

    SciTech Connect

    Jantzen, C.M.

    2003-12-02

    In order to make space in the Savannah River Site Tank farm, the Tank 48H waste must be removed. Therefore, the Tank 48H waste must be processed to reduce or eliminate levels of nitrates, nitrites, and sodium tetraphenyl borate in order to reduce impacts of these species before it is vitrified. Fluidized Bed Steam Reforming is being considered as a candidate technology for destroying the nitrates and the NaTPB prior to melting. The Idaho National Engineering and Environmental Laboratory was tasked to perform a proof-of-concept steam reforming test to evaluate the technical feasibility for pretreating the Tank 48H waste. The crucible (bench scale) tests conducted at the Savannah River Technology Center were initiated to optimize and augment the parameters subsequently tested at the pilot scale at INEEL. The purposes of the current study, organic destruction and downstream processing of T48H waste slurry were fulfilled. TPB was destroyed in all 19 samples tested with the simulated FB SR process at operational temperatures 650-725 degrees Celsius. A test temperature of 650 degrees Celsius optimized NO3 destruction during the formation of an Na2CO3 FBSR product. A test temperature of 725 degrees Celsius optimized NO3 destruction during formation of a sodium silicate FBSR product. Destruction of nitrate at greater than 99 per cent was achieved with addition of sugar as a reductant at 1X stoichiometry and total organic carbon analyses indicated that excess reductant was not present in the FBSR product. The use of sugar at 1X stoichiometry appears to ensure that excess reductant is not contained in the FBSR product that would alter the REDuction/OXidation equilibrium of the DWPF melter, while simultaneously assuring that NO3 is destroyed adequately. Destruction of antifoam with the simulated FBSR process was also achieved at operating temperatures between 650-725 degrees Celsius. based on measured total organic carbon.

  12. Hazardous waste treatment and environmental remediation research

    SciTech Connect

    Not Available

    1989-09-29

    Los Alamos National Laboratory (LANL) is currently evaluating hazardous waste treatment and environmental remediation technologies in existence and under development to determine applicability to remediation needs of the DOE facilities under the Albuquerque Operations Office and to determine areas of research need. To assist LANL is this effort, Science Applications International Corporation (SAIC) conducted an assessment of technologies and monitoring methods that have been demonstrated or are under development. The focus of this assessment is to: (1) identify existing technologies for hazardous waste treatment and environmental remediation of old waste sites; (2) identify technologies under development and the status of the technology; (3) assess new technologies that need development to provide adequate hazardous waste treatment and remedial action technologies for DOD and DOE sites; and (4) identify hazardous waste and remediation problems for environmental research and development. There are currently numerous research and development activities underway nationwide relating to environmental contaminants and the remediation of waste sites. To perform this effort, SAIC evaluated current technologies and monitoring methods development programs in EPA, DOD, and DOE, as these are the primary agencies through which developmental methods are being demonstrated. This report presents this evaluation and provides recommendations as to pertinent research needs or activities to address waste site contamination problems. The review and assessment have been conducted at a programmatic level; site-specific and contaminant-specific evaluations are being performed by LANL staff as a separate, related activity.

  13. TREATMENT OF FISSION PRODUCT WASTE

    DOEpatents

    Huff, J.B.

    1959-07-28

    A pyrogenic method of separating nuclear reactor waste solutions containing aluminum and fission products as buring petroleum coke in an underground retort, collecting the easily volatile gases resulting as the first fraction, he uminum chloride as the second fraction, permitting the coke bed to cool and ll contain all the longest lived radioactive fission products in greatly reduced volume.

  14. Closed Fuel Cycle Waste Treatment Strategy

    SciTech Connect

    Vienna, J. D.; Collins, E. D.; Crum, J. V.; Ebert, W. L.; Frank, S. M.; Garn, T. G.; Gombert, D.; Jones, R.; Jubin, R. T.; Maio, V. C.; Marra, J. C.; Matyas, J.; Nenoff, T. M.; Riley, B. J.; Sevigny, G. J.; Soelberg, N. R.; Strachan, D. M.; Thallapally, P. K.; Westsik, J. H.

    2015-02-01

    This study is aimed at evaluating the existing waste management approaches for nuclear fuel cycle facilities in comparison to the objectives of implementing an advanced fuel cycle in the U.S. under current legal, regulatory, and logistical constructs. The study begins with the Global Nuclear Energy Partnership (GNEP) Integrated Waste Management Strategy (IWMS) (Gombert et al. 2008) as a general strategy and associated Waste Treatment Baseline Study (WTBS) (Gombert et al. 2007). The tenets of the IWMS are equally valid to the current waste management study. However, the flowsheet details have changed significantly from those considered under GNEP. In addition, significant additional waste management technology development has occurred since the GNEP waste management studies were performed. This study updates the information found in the WTBS, summarizes the results of more recent technology development efforts, and describes waste management approaches as they apply to a representative full recycle reprocessing flowsheet. Many of the waste management technologies discussed also apply to other potential flowsheets that involve reprocessing. These applications are occasionally discussed where the data are more readily available. The report summarizes the waste arising from aqueous reprocessing of a typical light-water reactor (LWR) fuel to separate actinides for use in fabricating metal sodium fast reactor (SFR) fuel and from electrochemical reprocessing of the metal SFR fuel to separate actinides for recycle back into the SFR in the form of metal fuel. The primary streams considered and the recommended waste forms include; Tritium in low-water cement in high integrity containers (HICs); Iodine-129: As a reference case, a glass composite material (GCM) formed by the encapsulation of the silver Mordenite (AgZ) getter material in a low-temperature glass is assumed. A number of alternatives with distinct advantages are also considered including a fused silica waste form

  15. Surrogate formulations for thermal treatment of low-level mixed waste, Part II: Selected mixed waste treatment project waste streams

    SciTech Connect

    Bostick, W.D.; Hoffmann, D.P.; Chiang, J.M.; Hermes, W.H.; Gibson, L.V. Jr.; Richmond, A.A.; Mayberry, J.; Frazier, G.

    1994-01-01

    This report summarizes the formulation of surrogate waste packages, representing the major bulk constituent compositions for 12 waste stream classifications selected by the US DOE Mixed Waste Treatment Program. These waste groupings include: neutral aqueous wastes; aqueous halogenated organic liquids; ash; high organic content sludges; adsorbed aqueous and organic liquids; cement sludges, ashes, and solids; chloride; sulfate, and nitrate salts; organic matrix solids; heterogeneous debris; bulk combustibles; lab packs; and lead shapes. Insofar as possible, formulation of surrogate waste packages are referenced to authentic wastes in inventory within the DOE; however, the surrogate waste packages are intended to represent generic treatability group compositions. The intent is to specify a nonradiological synthetic mixture, with a minimal number of readily available components, that can be used to represent the significant challenges anticipated for treatment of the specified waste class. Performance testing and evaluation with use of a consistent series of surrogate wastes will provide a means for the initial assessment (and intercomparability) of candidate treatment technology applicability and performance. Originally the surrogate wastes were intended for use with emerging thermal treatment systems, but use may be extended to select nonthermal systems as well.

  16. Economic and environmental optimization of waste treatment

    SciTech Connect

    Münster, M.; Ravn, H.; Hedegaard, K.; Juul, N.; Ljunggren Söderman, M.

    2015-04-15

    Highlights: • Optimizing waste treatment by incorporating LCA methodology. • Applying different objectives (minimizing costs or GHG emissions). • Prioritizing multiple objectives given different weights. • Optimum depends on objective and assumed displaced electricity production. - Abstract: This article presents the new systems engineering optimization model, OptiWaste, which incorporates a life cycle assessment (LCA) methodology and captures important characteristics of waste management systems. As part of the optimization, the model identifies the most attractive waste management options. The model renders it possible to apply different optimization objectives such as minimizing costs or greenhouse gas emissions or to prioritize several objectives given different weights. A simple illustrative case is analysed, covering alternative treatments of one tonne of residual household waste: incineration of the full amount or sorting out organic waste for biogas production for either combined heat and power generation or as fuel in vehicles. The case study illustrates that the optimal solution depends on the objective and assumptions regarding the background system – illustrated with different assumptions regarding displaced electricity production. The article shows that it is feasible to combine LCA methodology with optimization. Furthermore, it highlights the need for including the integrated waste and energy system into the model.

  17. CRUCIBLE TESTING OF TANK 48H RADIOACTIVEWASTE SAMPLE USING FLUIDIZED BED STEAMREFORMING TECHNOLOGY FOR ORGANICDESTRUCTION

    SciTech Connect

    Crawford, C

    2008-07-31

    The purpose of crucible scale testing with actual radioactive Tank 48H material was to duplicate the test results that had been previously performed on simulant Tank 48H material. The earlier crucible scale testing using simulants was successful in demonstrating that bench scale crucible tests produce results that are indicative of actual Fluidized Bed Steam Reforming (FBSR) pilot scale tests. Thus, comparison of the results using radioactive Tank 48H feed to those reported earlier with simulants would then provide proof that the radioactive tank waste behaves in a similar manner to the simulant. Demonstration of similar behavior for the actual radioactive Tank 48H slurry to the simulant is important as a preliminary or preparation step for the more complex bench-scale steam reformer unit that is planned for radioactive application in the Savannah River National Laboratory (SRNL) Shielded Cells Facility (SCF) later in 2008. The goals of this crucible-scale testing were to show 99% destruction of tetraphenylborate and to demonstrate that the final solid product produced is sodium carbonate. Testing protocol was repeated using the specifications of earlier simulant crucible scale testing, that is sealed high purity alumina crucibles containing a pre-carbonated and evaporated Tank 48H material. Sealing of the crucibles was accomplished by using an inorganic 'nepheline' sealant. The sealed crucibles were heat-treated at 650 C under constant argon flow to inert the system. Final product REDOX measurements were performed to establish the REDuction/OXidation (REDOX) state of known amounts of added iron species in the final product. These REDOX measurements confirm the processing conditions (pyrolysis occurring at low oxygen fugacity) of the sealed crucible environment which is the environment actually achieved in the fluidized bed steam reformer process. Solid product dissolution in water was used to measure soluble cations and anions, and to investigate insoluble

  18. Mixed waste treatment capabilities at Envirocare

    SciTech Connect

    Rafati, A.

    1994-12-31

    This presentation gives an overview of the business achievements and presents a corporate summary for the whole handling company Envirocare located in Clive, Utah. This company operates a permitted low-level radioactive and mixed waste facility which handles waste from the United States Department of Energy, Environmental Protection Agency, Department of Defense, and Fortune 500 companies. A description of business services and treatment capabilities is presented.

  19. Treatment of oil field wastes

    SciTech Connect

    Terry, E.G.; Seedall, L.K.

    1988-06-21

    An apparatus for recovery of barite and clays from spend drilling fluids is described comprising: (a) a rotary kiln having a first end higher than a second end whereby drilling fluids therein will flow from the first end to the second end, the kiln having an inlet at the first end for receiving drilling fluids and combustion air; (b) a burner connected to the first end of the kiln for supplying fire to the kiln for aiding in burning the combustible components of the drilling fluids in the kiln; (c) a fuel and pressurized air inlet connected to the burner; (d) an outlet at the second end of the kiln for removing the light weight waste; (e) means connected to the outlet for removing high weight dried waste from the kiln by gravity; (f) cyclone separator means located downstream of the kiln outlet for separation of particulates such as barite and clays; (g) secondary combustion means located downstream from the cyclone separator means for oxidation of residual pyrolized gases from oxidized carbonaceous waste from the kiln; (h) heat exchanger means for cooling the exhaust gases to substantially a 100% water saturation point with incoming combustion air to preheat the combustion air; and (i) means for removing residual oxides of sulfur from the exhaust gases prior to vending to the atmosphere.

  20. Fungal hydrolysis in submerged fermentation for food waste treatment and fermentation feedstock preparation.

    PubMed

    Pleissner, Daniel; Kwan, Tsz Him; Lin, Carol Sze Ki

    2014-04-01

    Potential of fungal hydrolysis in submerged fermentation by Aspergillus awamori and Aspergillus oryzae as a food waste treatment process and for preparation of fermentation feedstock has been investigated. By fungal hydrolysis, 80-90% of the initial amount of waste was reduced and degraded within 36-48 h into glucose, free amino nitrogen (FAN) and phosphate. Experiments revealed that 80-90% of starch can be converted into glucose and highest concentration of FAN obtained, when solid mashes of A. awamori and A. oryzae are successively added to fermentations at an interval of 24h. A maximal solid-to-liquid ratio of 43.2% (w/v) of food waste has been tested without a negative impact on releases of glucose, FAN and phosphate, and final concentrations of 143 g L(-1), 1.8 g L(-1) and 1.6 g L(-1) were obtained in the hydrolysate, respectively. Additionally, fungal hydrolysis as an alternative to conventional treatments for utilization of food waste is discussed.

  1. 2009 PILOT SCALE FLUIDIZED BED STEAM REFORMING TESTING USING THE THOR (THERMAL ORGANIC REDUCTION) PROCESS: ANALYTICAL RESULTS FOR TANK 48H ORGANIC DESTRUCTION - 10408

    SciTech Connect

    Williams, M.; Jantzen, C.; Burket, P.; Crawford, C.; Daniel, G.; Aponte, C.; Johnson, C.

    2009-12-28

    The Savannah River Site (SRS) must empty the contents of Tank 48H, a 1.3 million gallon Type IIIA HLW storage tank, to return this tank to service. The tank contains organic compounds, mainly potassium tetraphenylborate that cannot be processed downstream until the organic components are destroyed. The THOR{reg_sign} Treatment Technologies (TTT) Fluidized Bed Steam Reforming (FBSR) technology, herein after referred to as steam reforming, has been demonstrated to be a viable process to remove greater than 99.9% of the organics from Tank 48H during various bench scale and pilot scale tests. These demonstrations were supported by Savannah River Remediation (SRR) and the Department of Energy (DOE) has concurred with the SRR recommendation to proceed with the deployment of the FBSR technology to treat the contents of Tank 48H. The Savannah River National Laboratory (SRNL) developed and proved the concept with non-radioactive simulants for SRR beginning in 2003. By 2008, several pilot scale campaigns had been completed and extensive crucible testing and bench scale testing were performed in the SRNL Shielded Cells using Tank 48H radioactive sample. SRNL developed a Tank 48H non-radioactive simulant complete with organic compounds, salt, and metals characteristic of those measured in a sample of the radioactive contents of Tank 48H. FBSR Pilot Scaled Testing with the Tank 48H simulant has demonstrated the ability to remove greater than 98% of the nitrites and greater than 99.5% of the nitrates from the Tank 48H simulant, and to form a solid product that is primarily alkali carbonate. The alkali carbonate is soluble and, thus, amenable to pumping as a liquid to downstream facilities for processing. The FBSR technology was demonstrated in October of 2006 in the Engineering Scale Test Demonstration (ESTD) pilot scale steam reformer at the Hazen Research Inc. (HRI) facility in Golden, CO. Additional ESTD tests were completed in 2008 and in 2009 that further demonstrated the

  2. Medical waste treatment and decontamination system

    DOEpatents

    Wicks, George G.; Schulz, Rebecca L.; Clark, David E.

    2001-01-01

    The invention discloses a tandem microwave system consisting of a primary chamber in which hybrid microwave energy is used for the controlled combustion of materials. A second chamber is used to further treat the off-gases from the primary chamber by passage through a susceptor matrix subjected to additional hybrid microwave energy. The direct microwave radiation and elevated temperatures provide for significant reductions in the qualitative and quantitative emissions of the treated off gases. The tandem microwave system can be utilized for disinfecting wastes, sterilizing materials, and/or modifying the form of wastes to solidify organic or inorganic materials. The simple design allows on-site treatment of waste by small volume waste generators.

  3. Handbook of industrial and hazardous wastes treatment. 2nd ed.

    SciTech Connect

    Lawrence Wang; Yung-Tse Hung; Howard Lo; Constantine Yapijakis

    2004-06-15

    This expanded Second Edition offers 32 chapters of industry- and waste-specific analyses and treatment methods for industrial and hazardous waste materials - from explosive wastes to landfill leachate to wastes produced by the pharmaceutical and food industries. Key additional chapters cover means of monitoring waste on site, pollution prevention, and site remediation. Including a timely evaluation of the role of biotechnology in contemporary industrial waste management, the Handbook reveals sound approaches and sophisticated technologies for treating: textile, rubber, and timber wastes; dairy, meat, and seafood industry wastes; bakery and soft drink wastes; palm and olive oil wastes; pesticide and livestock wastes; pulp and paper wastes; phosphate wastes; detergent wastes; photographic wastes; refinery and metal plating wastes; and power industry wastes. This final chapter, entitled 'Treatment of power industry wastes' by Lawrence K. Wang, analyses the stream electric power generation industry, where combustion of fossil fuels coal, oil, gas, supplies heat to produce stream, used then to generate mechanical energy in turbines, subsequently converted to electricity. Wastes include waste waters from cooling water systems, ash handling systems, wet-scrubber air pollution control systems, and boiler blowdown. Wastewaters are characterized and waste treatment by physical and chemical systems to remove pollutants is presented. Plant-specific examples are provided.

  4. Waste Treatment Technology Process Development Plan For Hanford Waste Treatment Plant Low Activity Waste Recycle

    SciTech Connect

    McCabe, Daniel J.; Wilmarth, William R.; Nash, Charles A.

    2013-08-29

    The purpose of this Process Development Plan is to summarize the objectives and plans for the technology development activities for an alternative path for disposition of the recycle stream that will be generated in the Hanford Waste Treatment Plant Low Activity Waste (LAW) vitrification facility (LAW Recycle). This plan covers the first phase of the development activities. The baseline plan for disposition of this stream is to recycle it to the WTP Pretreatment Facility, where it will be concentrated by evaporation and returned to the LAW vitrification facility. Because this stream contains components that are volatile at melter temperatures and are also problematic for the glass waste form, they accumulate in the Recycle stream, exacerbating their impact on the number of LAW glass containers. Approximately 32% of the sodium in Supplemental LAW comes from glass formers used to make the extra glass to dilute the halides to acceptable concentrations in the LAW glass, and reducing the halides in the Recycle is a key component of this work. Additionally, under possible scenarios where the LAW vitrification facility commences operation prior to the WTP Pretreatment facility, this stream does not have a proven disposition path, and resolving this gap becomes vitally important. This task seeks to examine the impact of potential future disposition of this stream in the Hanford tank farms, and to develop a process that will remove radionuclides from this stream and allow its diversion to another disposition path, greatly decreasing the LAW vitrification mission duration and quantity of glass waste. The origin of this LAW Recycle stream will be from the Submerged Bed Scrubber (SBS) and the Wet Electrostatic Precipitator (WESP) from the LAW melter off-gas system. The stream is expected to be a dilute salt solution with near neutral pH, and will likely contain some insoluble solids from melter carryover or precipitates of scrubbed components (e.g. carbonates). The soluble

  5. Economic and environmental optimization of waste treatment.

    PubMed

    Münster, M; Ravn, H; Hedegaard, K; Juul, N; Ljunggren Söderman, M

    2015-04-01

    This article presents the new systems engineering optimization model, OptiWaste, which incorporates a life cycle assessment (LCA) methodology and captures important characteristics of waste management systems. As part of the optimization, the model identifies the most attractive waste management options. The model renders it possible to apply different optimization objectives such as minimizing costs or greenhouse gas emissions or to prioritize several objectives given different weights. A simple illustrative case is analysed, covering alternative treatments of one tonne of residual household waste: incineration of the full amount or sorting out organic waste for biogas production for either combined heat and power generation or as fuel in vehicles. The case study illustrates that the optimal solution depends on the objective and assumptions regarding the background system--illustrated with different assumptions regarding displaced electricity production. The article shows that it is feasible to combine LCA methodology with optimization. Furthermore, it highlights the need for including the integrated waste and energy system into the model.

  6. RETRIEVAL & TREATMENT OF HANFORD TANK WASTE

    SciTech Connect

    EACKER, J.A.; SPEARS, J.A.; STURGES, M.H.; MAUSS, B.M.

    2006-01-20

    The Hanford Tank Farms contain 53 million gal of radioactive waste accumulated during over 50 years of operations. The waste is stored in 177 single-shell and double-shell tanks in the Hanford 200 Areas. The single-shell tanks were put into operation from the early 1940s through the 1960s with wastes received from several generations of processing facilities for the recovery of plutonium and uranium, and from laboratories and other ancillary facilities. The overall hanford Tank Farm system represents one of the largest nuclear legacies in the world driving towards completion of retrieval and treatment in 2028 and the associated closure activity completion by 2035. Remote operations, significant radiation/contamination levels, limited access, and old facilities are just some of the challenges faced by retrieval and treatment systems. These systems also need to be able to successfully remove 99% or more of the waste, and support waste treatment, and tank closure. The Tank Farm retrieval program has ramped up dramatically in the past three years with design, fabrication, installation, testing, and operations ongoing on over 20 of the 149 single-shell tanks. A variety of technologies are currently being pursued to retrieve different waste types, applications, and to help establish a baseline for recovery/operational efficiencies. The paper/presentation describes the current status of retrieval system design, fabrication, installation, testing, readiness, and operations, including: (1) Saltcake removal progress in Tanks S-102, S-109, and S-112 using saltcake dissolution, modified sluicing, and high pressure water lancing techniques; (2) Sludge vacuum retrieval experience from Tanks C-201, C-202, C-203, and C-204; (3) Modified sluicing experience in Tank C-103; (4) Progress on design and installation of the mobile retrieval system for sludge in potentially leaking single-shell tanks, particularly Tank C-101; and (5) Ongoing installation of various systems in the next

  7. Biological treatment of hazardous aqueous wastes

    SciTech Connect

    Opatken, E.J.; Howard, H.K.; Bond, J.J.

    1987-06-01

    Studies were conducted with a rotating biological conractor (RBC) to evaluate the treatability of leachates from the Stringfellow and New Lyme hazardous-waste sites. The leachates were transported from the waste sites to Cincinnati at the United States Environmental Protection Agency's Testing and Evaluation Facility. A series of batches were run with primary effluent from Cincinnati's Mill Creek Sewage Treatment Facility. The paper reports on the results from these experiments and the effectiveness of an RBC to adequately treat leachates from Superfund sites.

  8. Waste management system alternatives for treatment of wastes from spent fuel reprocessing

    SciTech Connect

    McKee, R.W.; Swanson, J.L.; Daling, P.M.; Clark, L.L.; Craig, R.A.; Nesbitt, J.F.; McCarthy, D.; Franklin, A.L.; Hazelton, R.F.; Lundgren, R.A.

    1986-09-01

    This study was performed to help identify a preferred TRU waste treatment alternative for reprocessing wastes with respect to waste form performance in a geologic repository, near-term waste management system risks, and minimum waste management system costs. The results were intended for use in developing TRU waste acceptance requirements that may be needed to meet regulatory requirements for disposal of TRU wastes in a geologic repository. The waste management system components included in this analysis are waste treatment and packaging, transportation, and disposal. The major features of the TRU waste treatment alternatives examined here include: (1) packaging (as-produced) without treatment (PWOT); (2) compaction of hulls and other compactable wastes; (3) incineration of combustibles with cementation of the ash plus compaction of hulls and filters; (4) melting of hulls and failed equipment plus incineration of combustibles with vitrification of the ash along with the HLW; (5a) decontamination of hulls and failed equipment to produce LLW plus incineration and incorporation of ash and other inert wastes into HLW glass; and (5b) variation of this fifth treatment alternative in which the incineration ash is incorporated into a separate TRU waste glass. The six alternative processing system concepts provide progressively increasing levels of TRU waste consolidation and TRU waste form integrity. Vitrification of HLW and intermediate-level liquid wastes (ILLW) was assumed in all cases.

  9. A perspective of hazardous waste and mixed waste treatment technology at the Savannah River Site

    SciTech Connect

    England, J.L.; Venkatesh, S.; Bailey, L.L.; Langton, C.A.; Hay, M.S.; Stevens, C.B.; Carroll, S.J.

    1991-01-01

    Treatment technologies for the preparation and treatment of heavy metal mixed wastes, contaminated soils, and mixed mercury wastes are being considered at the Savannah River Site (SRS), a DOE nuclear material processing facility operated by Westinghouse Savannah River Company (WSRC). The proposed treatment technologies to be included at the Hazardous Waste/Mixed Waste Treatment Building at SRS are based on the regulatory requirements, projected waste volumes, existing technology, cost effectiveness, and project schedule. Waste sorting and size reduction are the initial step in the treatment process. After sorting/size reduction the wastes would go to the next applicable treatment module. For solid heavy metal mixed wastes the proposed treatment is macroencapsulation using a thermoplastic polymer. This process reduces the leachability of hazardous constituents from the waste and allows easy verification of the coating integrity. Stabilization and solidification in a cement matrix will treat a wide variety of wastes (i.e. soils, decontamination water). Some pretreatments may be required (i.e. Ph adjustment) before stabilization. Other pretreatments such as soil washing can reduce the amount of waste to be stabilized. Radioactive contaminated mercury waste at the SRS comes in numerous forms (i.e. process equipment, soils, and lab waste) with the required treatment of high mercury wastes being roasting/retorting and recovery. Any unrecyclable radioactive contaminated elemental mercury would be amalgamated, utilizing a batch system, before disposal.

  10. A perspective of hazardous waste and mixed waste treatment technology at the Savannah River Site

    SciTech Connect

    England, J.L.; Venkatesh, S.; Bailey, L.L.; Langton, C.A.; Hay, M.S.; Stevens, C.B.; Carroll, S.J.

    1991-12-31

    Treatment technologies for the preparation and treatment of heavy metal mixed wastes, contaminated soils, and mixed mercury wastes are being considered at the Savannah River Site (SRS), a DOE nuclear material processing facility operated by Westinghouse Savannah River Company (WSRC). The proposed treatment technologies to be included at the Hazardous Waste/Mixed Waste Treatment Building at SRS are based on the regulatory requirements, projected waste volumes, existing technology, cost effectiveness, and project schedule. Waste sorting and size reduction are the initial step in the treatment process. After sorting/size reduction the wastes would go to the next applicable treatment module. For solid heavy metal mixed wastes the proposed treatment is macroencapsulation using a thermoplastic polymer. This process reduces the leachability of hazardous constituents from the waste and allows easy verification of the coating integrity. Stabilization and solidification in a cement matrix will treat a wide variety of wastes (i.e. soils, decontamination water). Some pretreatments may be required (i.e. Ph adjustment) before stabilization. Other pretreatments such as soil washing can reduce the amount of waste to be stabilized. Radioactive contaminated mercury waste at the SRS comes in numerous forms (i.e. process equipment, soils, and lab waste) with the required treatment of high mercury wastes being roasting/retorting and recovery. Any unrecyclable radioactive contaminated elemental mercury would be amalgamated, utilizing a batch system, before disposal.

  11. 40 CFR 268.37 - Waste specific prohibitions-ignitable and corrosive characteristic wastes whose treatment...

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... for metals, reduction of hexavalent chromium, or other treatment technology that can be demonstrated... and corrosive characteristic wastes whose treatment standards were vacated. 268.37 Section 268.37... characteristic wastes whose treatment standards were vacated. (a) Effective August 9, 1993, the wastes...

  12. 40 CFR 268.37 - Waste specific prohibitions-ignitable and corrosive characteristic wastes whose treatment...

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... for metals, reduction of hexavalent chromium, or other treatment technology that can be demonstrated... and corrosive characteristic wastes whose treatment standards were vacated. 268.37 Section 268.37... characteristic wastes whose treatment standards were vacated. (a) Effective August 9, 1993, the wastes...

  13. Raw liquid waste treatment process

    NASA Technical Reports Server (NTRS)

    Humphrey, Marshall F. (Inventor)

    1980-01-01

    A raw sewage treatment process is disclosed in which substantially all the non-dissolved matter, which is suspended in the sewage water is first separated from the water, in which at least organic matter is dissolved. The non-dissolved material is pyrolyzed to form an activated carbon and ash material without the addition of any conditioning agents. The activated carbon and ash material is added to the water from which the non-dissolved matter was removed. The activated carbon and ash material absorbs organic matter and heavy metal ions, it is believed, are dissolved in the water and is thereafter supplied in a counter current flow direction and combined with the incoming raw sewage to facilitate the separation of the non-dissolved settleable materials from the sewage water. The used carbon and ash material together with the non-dissolved matter which was separated from the sewage water are pyrolyzed to form the activated carbon and ash material.

  14. National Institutes of Health: Mixed waste minimization and treatment

    SciTech Connect

    1995-08-01

    The Appalachian States Low-Level Radioactive Waste Commission requested the US Department of Energy`s National Low-Level Waste Management Program (NLLWMP) to assist the biomedical community in becoming more knowledgeable about its mixed waste streams, to help minimize the mixed waste stream generated by the biomedical community, and to identify applicable treatment technologies for these mixed waste streams. As the first step in the waste minimization process, liquid low-level radioactive mixed waste (LLMW) streams generated at the National Institutes of Health (NIH) were characterized and combined into similar process categories. This report identifies possible waste minimization and treatment approaches for the LLMW generated by the biomedical community identified in DOE/LLW-208. In development of the report, on site meetings were conducted with NIH personnel responsible for generating each category of waste identified as lacking disposal options. Based on the meetings and general waste minimization guidelines, potential waste minimization options were identified.

  15. Regulatory framework for the thermal treatment of various waste streams.

    PubMed

    Lee, C C; Huffman, G L; Mao, Y L

    2000-08-28

    Since 1990, regulations and standards have changed considerably. This article is an update of the regulatory requirements for the thermal treatment of various waste streams. The waste categories covered, along with the laws they are governed under, include: Hazardous waste under Subtitle C of the Resource Conservation and Recovery Act (RCRA) and under the Clean Air Act; municipal solid waste under Subtitle D of the RCRA; medical waste under Subtitle J of the RCRA; Superfund waste under the Comprehensive Environmental Response, Compensation and Liability Act (CERCLA); toxic waste under the Toxic Substances Control Act (TSCA); and sludge waste under the Clean Water Act (CWA).

  16. Combustible radioactive waste treatment by incineration and chemical digestion

    SciTech Connect

    Stretz, L.A.; Crippen, M.D.; Allen, C.R.

    1980-05-28

    A review is given of present and planned combustible radioactive waste treatment systems in the US. Advantages and disadvantages of various systems are considered. Design waste streams are discussed in relation to waste composition, radioactive contaminants by amount and type, and special operating problems caused by the waste.

  17. Aqueous Waste Treatment Plant at Aldermaston

    SciTech Connect

    Keene, D.; Fowler, J.; Frier, S.

    2006-07-01

    For over half a century the Pangbourne Pipeline formed part of AWE's liquid waste management system. Since 1952 the 11.5 mile pipeline carried pre-treated wastewater from the Aldermaston site for safe dispersal in the River Thames. Such discharges were in strict compliance with the exacting conditions demanded by all regulatory authorities, latterly, those of the Environment Agency. In March 2005 AWE plc closed the Pangbourne Pipeline and ceased discharges of treated active aqueous waste to the River Thames via this route. The ability to effectively eliminate active liquid discharges to the environment is thanks to an extensive programme of waste minimization on the Aldermaston site, together with the construction of a new Waste Treatment Plant (WTP). Waste minimization measures have reduced the effluent arisings by over 70% in less than four years. The new WTP has been built using best available technology (evaporation followed by reverse osmosis) to remove trace levels of radioactivity from wastewater to exceptionally stringent standards. Active operation has confirmed early pilot scale trials, with the plant meeting throughput and decontamination performance targets, and final discharges being at or below limits of detection. The performance of the plant allows the treated waste to be discharged safely as normal industrial effluent from the AWE site. Although the project has had a challenging schedule, the project was completed on programme, to budget and with an exemplary safety record (over 280,000 hours in construction with no lost time events) largely due to a pro-active partnering approach between AWE plc and RWE NUKEM and its sub-contractors. (authors)

  18. Evaluation of waste treatment technologies by LLWDDD (Low-Level Waste Disposal Development and Demonstration) Programs

    SciTech Connect

    Kennerly, J.M.; Williams, L.C.; Dole, L.R.; Genung, R.K.

    1987-01-01

    Waste treatments are divided into four categories: (1) volume reduction; (2) conditioning to improve waste form performance; (3) segregation to achieve waste reduction; and (4) separation to remove radioactive (or hazardous) constituents. Two waste treatment demonstrations are described. In the first, volume reduction by mechanical means was achieved during the supercompaction of 300 55-gal drums of solid waste at ORNL. In the second demonstration, conditioning of waste through immobilization and packaging to improve the performance of the waste form is being evaluated. The final section of this paper describes potential scenarios for the management of uranium-contaminated wastes at the Y-12 Plant in Oak Ridge and emphasizes where demonstrations of treatment technology will be needed to implement the scenarios. Separation and thermal treatment are identified as the principal means for treating these wastes. 15 figs.

  19. Biological waste air treatment in biofilters.

    PubMed

    Deshusses, M A

    1997-06-01

    Recent studies in the area of biological waste air treatment in biofilters have addressed fundamental key issues such as microbial dynamics, microscopical characterization of the process culture and oxygen and nutrient limitations. The results from these studies have provided a deeper insight into the overall biofiltration process. In the coming years, such advances should allow for the design of better reactor controls and the improvement of pollutant removal in gas-phase bioreactors.

  20. Energy requirements for waste water treatment.

    PubMed

    Svardal, K; Kroiss, H

    2011-01-01

    The actual mathematical models describing global climate closely link the detected increase in global temperature to anthropogenic activity. The only energy source we can rely on in a long perspective is solar irradiation which is in the order of 10,000 kW/inhabitant. The actual primary power consumption (mainly based on fossil resources) in the developed countries is in the range of 5 to 10 kW/inhabitant. The total power contained in our nutrition is in the range of 0.11 kW/inhabitant. The organic pollution of domestic waste water corresponds to approximately 0.018 kW/inhabitant. The nutrients contained in the waste water can also be converted into energy equivalents replacing market fertiliser production. This energy equivalent is in the range of 0.009 kW/inhabitant. Hence waste water will never be a relevant source of energy as long as our primary energy consumption is in the range of several kW/inhabitant. The annual mean primary power demand of conventional municipal waste water treatment with nutrient removal is in the range of 0.003-0.015 kW/inhabitant. In principle it is already possible to reduce this value for external energy supply to zero. Such plants should be connected to an electrical grid in order to keep investment costs low. Peak energy demand will be supported from the grid and surplus electric energy from the plant can be is fed to the grid. Zero 'carbon footprint' will not be affected by this solution. Energy minimisation must never negatively affect treatment efficiency because water quality conservation is more important for sustainable development than the possible reduction in energy demand. This argument is strongly supported by economical considerations as the fixed costs for waste water infrastructure are dominant.

  1. Analysis of waste treatment requirements for DOE mixed wastes: Technical basis

    SciTech Connect

    1995-02-01

    The risks and costs of managing DOE wastes are a direct function of the total quantities of 3wastes that are handled at each step of the management process. As part of the analysis of the management of DOE low-level mixed wastes (LLMW), a reference scheme has been developed for the treatment of these wastes to meet EPA criteria. The treatment analysis in a limited form was also applied to one option for treatment of transuranic wastes. The treatment requirements in all cases analyzed are based on a reference flowsheet which provides high level treatment trains for all LLMW. This report explains the background and basis for that treatment scheme. Reference waste stream chemical compositions and physical properties including densities were established for each stream in the data base. These compositions are used to define the expected behavior for wastes as they pass through the treatment train. Each EPA RCRA waste code was reviewed, the properties, chemical composition, or characteristics which are of importance to waste behavior in treatment were designated. Properties that dictate treatment requirements were then used to develop the treatment trains and identify the unit operations that would be included in these trains. A table was prepared showing a correlation of the waste physical matrix and the waste treatment requirements as a guide to the treatment analysis. The analysis of waste treatment loads is done by assigning wastes to treatment steps which would achieve RCRA compliant treatment. These correlation`s allow one to examine the treatment requirements in a condensed manner and to see that all wastes and contaminant sets are fully considered.

  2. Treatment method for metal bearing oily waste

    SciTech Connect

    Most, I.G.; Hubble, W.S.

    1984-04-10

    A continuous process and system for treatment of oily waste products and heavy sludge resulting from the washing of scrap metal fragments bathed in oil. The sludge and oily waste both include a mixture of water, ferrous containing particulates and a hydrocarbon liquid. The process of this invention includes feeding the heavy sludge and oily waste into an incinerator, incinerating the hydrocarbon liquid contained therein at conditions such that the metal contained therein is recovered as particulate ash, and venting the resulting combustion gases to the atmosphere. The system of this invention includes an incinerator, an auger for transporting heavy sludge from the scrap washer to the incinerator, a pump and storage tank for feeding oily waste from the scrap wash water to the incinerator, and a baghouse for filtering the combustion gases and exhausting them to the atmosphere. A second auger may be provided for transporting sludge from a sludge storage tank, and a water heater may be provided for passing the combustion gases in heat exchange relationship with wash water. The incinerator utilizes a starved air principle and includes a primary chamber and a secondary chamber where temperatures and oxygen levels are carefully controlled. The ferromagnetic ash from the incinerator and the particulates recovered in the baghouse can be sold for scrap.

  3. Treatment methods for radioactive mixed wastes in commercial low-level wastes: technical considerations

    SciTech Connect

    MacKenzie, D.R.; Kempf, C.R.

    1986-01-01

    Treatment options for the management of three generic categories of radioactive mixed waste in commercial low-level wastes (LLW) have been identified and evaluated. These wastes were characterized as part of a BNL study in which LLW generators were surveyed for information on potential chemical hazards in their wastes. The general treatment options available for mixed wastes are destruction, immobilization, and reclamation. Solidification, absorption, incineration, acid digestion, wet-air oxidation, distillation, liquid-liquid wastes. Containment, segregation, decontamination, and solidification or containment of residues, have been considered for lead metal wastes which have themselves been contaminated and are not used for purposes of waste disposal shielding, packaging, or containment. For chromium-containing wastes, solidification, incineration, wet-air oxidation, acid digestion, and containment have been considered. For each of these wastes, the management option evaluation has included an assessment of testing appropriate to determine the effect of the option on both the radiological and potential chemical hazards present.

  4. Waste treatment by selective mineral ion exchanger

    SciTech Connect

    Polito, Aurelie

    2007-07-01

    STMI, subsidiary company of the AREVA Group with over 40 years in the D and D business, has been continuously innovating and developing new decontamination techniques, with the objectives of achieving more efficient decontaminations on a growing spectrum of media. In the field of liquid waste treatment, STMI manufactures uses and commercialises selective inorganic ion exchangers (RAN). These are hydrated synthetic inorganic compounds prepared from very pure raw materials. Different types of RANs (POLYAN, OXTAIN, Fe-Cu, Fe-CoK, Si-Fe-CoK) can be used to trap a large number of radioactive elements in contaminated effluents. Different implementations could be applied depending on technical conditions. STMI's offers consist in building global solution and preliminary design of installation either in dispersed form (batch) or in column (cartridge filtration). Those products are used all over the world not only in the nuclear business (Canada, US, Belgium, France...) but also in other fields. Indeed, it provides competitive solutions to many domains of application especially water pollution control, liquid waste treatment in the nuclear business by decreasing the activity level of waste. The following paper will focus on the theoretical principle of the mineral exchanger, its implementation and the feed back collected by STMI. (author)

  5. 40 CFR 35.925-15 - Treatment of industrial wastes.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 1 2012-07-01 2012-07-01 false Treatment of industrial wastes. 35.925... § 35.925-15 Treatment of industrial wastes. That the allowable project costs do not include (a) costs... pollutants introduced from nonindustrial sources. The project must be included in a complete waste...

  6. 40 CFR 35.925-15 - Treatment of industrial wastes.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 1 2014-07-01 2014-07-01 false Treatment of industrial wastes. 35.925... § 35.925-15 Treatment of industrial wastes. That the allowable project costs do not include (a) costs... pollutants introduced from nonindustrial sources. The project must be included in a complete waste...

  7. Membrane technologies for liquid radioactive waste treatment

    NASA Astrophysics Data System (ADS)

    Chmielewski, A. G.; Harasimowicz, M.; Zakrzewska-Trznadel, G.

    1999-01-01

    The paper deals with some problems concerning reduction of radioactivity of liquid low-level nuclear waste streams (LLLW). The membrane processes as ultrafiltration (UF), seeded ultrafiltration (SUF), reverse osmosis (RO) and membrane distillation (MD) were examined. Ultrafiltration enables the removal of particles with molecular weight above cut-off of UF membranes and can be only used as a pre-treatment stage. The improvement of removal is achieved by SUF, employing macromolecular ligands binding radioactive ions. The reduction of radioactivity in LLLW to very low level were achieved with RO membranes. The results of experiments led the authors to the design and construction of UF+2RO pilot plant. The development of membrane distillation improve the selectivity of membrane process in some cases. The possibility of utilisation of waste heat from cooling system of nuclear reactors as a preferable energy source can significantly reduce the cost of operation.

  8. Bulky waste quantities and treatment methods in Denmark.

    PubMed

    Larsen, Anna W; Petersen, Claus; Christensen, Thomas H

    2012-02-01

    Bulky waste is a significant and increasing waste stream in Denmark. However, only little research has been done on its composition and treatment. In the present study, data about collection methods, waste quantities and treatment methods for bulky waste were obtained from two municipalities. In addition a sorting analysis was conducted on combustible waste, which is a major fraction of bulky waste in Denmark. The generation of bulky waste was found to be 150-250 kg capita(-1) year(-1), and 90% of the waste was collected at recycling centres; the rest through kerbside collection. Twelve main fractions were identified of which ten were recyclable and constituted 50-60% of the total quantity. The others were combustible waste for incineration (30-40%) and non-combustible waste for landfilling (10%). The largest fractions by mass were combustible waste, bricks and tile, concrete, non-combustible waste, wood, and metal scrap, which together made up more than 90% of the total waste amounts. The amount of combustible waste could be significantly reduced through better sorting. Many of the waste fractions consisted of composite products that underwent thorough separation before being recycled. The recyclable materials were in many cases exported to other countries which made it difficult to track their destination and further treatment.

  9. Evaluation of Biodegradability of Waste Before and After Aerobic Treatment

    NASA Astrophysics Data System (ADS)

    Suchowska-Kisielewicz, Monika; Jędrczak, Andrzej; Sadecka, Zofia

    2014-12-01

    An important advantage of use of an aerobic biostabilization of waste prior to its disposal is that it intensifies the decomposition of the organic fraction of waste into the form which is easily assimilable for methanogenic microorganisms involved in anaerobic decomposition of waste in the landfill. In this article it is presented the influence of aerobic pre-treatment of waste as well as leachate recirculation on susceptibility to biodegradation of waste in anaerobic laboratory reactors. The research has shown that in the reactor with aerobically treated waste stabilized with recilculation conversion of the organic carbon into the methane is about 45% higher than in the reactor with untreated waste stabilized without recirculation.

  10. 50. NORTHERN VIEW OF NONEVAPORATIVE WASTE WATER TREATMENT COOLING TOWERS ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    50. NORTHERN VIEW OF NON-EVAPORATIVE WASTE WATER TREATMENT COOLING TOWERS IN CENTER, AND EVAPORATIVE WASTE WATER COOLING TOWERS ON RIGHT. (Jet Lowe) - U.S. Steel Duquesne Works, Blast Furnace Plant, Along Monongahela River, Duquesne, Allegheny County, PA

  11. Treatment of halogen-containing waste and other waste materials

    DOEpatents

    Forsberg, Charles W.; Beahm, Edward C.; Parker, George W.

    1997-01-01

    A process for treating a halogen-containing waste material. The process provides a bath of molten glass containing a sacrificial metal oxide capable of reacting with a halogen in the waste material. The sacrificial metal oxide is present in the molten glass in at least a stoichiometric amount with respect to the halogen in the waste material. The waste material is introduced into the bath of molten glass to cause a reaction between the halogen in the waste material and the sacrificial metal oxide to yield a metal halide. The metal halide is a gas at the temperature of the molten glass. The gaseous metal halide is separated from the molten glass and contacted with an aqueous scrubber solution of an alkali metal hydroxide to yield a metal hydroxide or metal oxide-containing precipitate and a soluble alkali metal halide. The precipitate is then separated from the aqueous scrubber solution. The molten glass containing the treated waste material is removed from the bath as a waste glass. The process of the invention can be used to treat all types of waste material including radioactive wastes. The process is particularly suited for separating halogens from halogen-containing wastes.

  12. Treatment of halogen-containing waste and other waste materials

    DOEpatents

    Forsberg, C.W.; Beahm, E.C.; Parker, G.W.

    1997-03-18

    A process is described for treating a halogen-containing waste material. The process provides a bath of molten glass containing a sacrificial metal oxide capable of reacting with a halogen in the waste material. The sacrificial metal oxide is present in the molten glass in at least a stoichiometric amount with respect to the halogen in the waste material. The waste material is introduced into the bath of molten glass to cause a reaction between the halogen in the waste material and the sacrificial metal oxide to yield a metal halide. The metal halide is a gas at the temperature of the molten glass. The gaseous metal halide is separated from the molten glass and contacted with an aqueous scrubber solution of an alkali metal hydroxide to yield a metal hydroxide or metal oxide-containing precipitate and a soluble alkali metal halide. The precipitate is then separated from the aqueous scrubber solution. The molten glass containing the treated waste material is removed from the bath as a waste glass. The process of the invention can be used to treat all types of waste material including radioactive wastes. The process is particularly suited for separating halogens from halogen-containing wastes. 3 figs.

  13. Cerebral salt wasting: pathophysiology, diagnosis, and treatment.

    PubMed

    Yee, Alan H; Burns, Joseph D; Wijdicks, Eelco F M

    2010-04-01

    Cerebral salt wasting (CSW) is a syndrome of hypovolemic hyponatremia caused by natriuresis and diuresis. The mechanisms underlying CSW have not been precisely delineated, although existing evidence strongly implicates abnormal elevations in circulating natriuretic peptides. The key in diagnosis of CSW lies in distinguishing it from the more common syndrome of inappropriate secretion of antidiuretic hormone. Volume status, but not serum and urine electrolytes and osmolality, is crucial for making this distinction. Volume and sodium repletion are the goals of treatment of patients with CSW, and this can be performed using some combination of isotonic saline, hypertonic saline, and mineralocorticoids.

  14. Mixed and low-level waste treatment facility project. Volume 3, Waste treatment technologies (Draft)

    SciTech Connect

    Not Available

    1992-04-01

    The technology information provided in this report is only the first step toward the identification and selection of process systems that may be recommended for a proposed mixed and low-level waste treatment facility. More specific information on each technology will be required to conduct the system and equipment tradeoff studies that will follow these preengineering studies. For example, capacity, maintainability, reliability, cost, applicability to specific waste streams, and technology availability must be further defined. This report does not currently contain all needed information; however, all major technologies considered to be potentially applicable to the treatment of mixed and low-level waste are identified and described herein. Future reports will seek to improve the depth of information on technologies.

  15. Waste treatment at the La Hague and Marcoule sites

    SciTech Connect

    1995-04-01

    In this report, an overview of waste treatment and solidification facilities located at the La Hague and Marcoule sites, which are owned and/or operated by Cogema, provided. The La Hague facilities described in this report include the following: The STE3 liquid effluent treatment facility (in operation); the AD2 solid waste processing facility (also in operation); and the UCD alpha waste treatment facility (under construction). The Marcoule facilities described in this report, both of which are in operation, include the following: The STEL-EVA liquid effluent treatment facilities for the entire site; and the alpha waste incinerator of the UPI plant. This report is organized into four sections: this introduction, low-level waste treatment at La Hague, low-level waste treatment at Marcoule, and new process development. including the solvent pyrolysis process currently in the development stage for Cogema`s plants.

  16. Mixed and Low-Level Waste Treatment Facility project

    SciTech Connect

    Not Available

    1992-04-01

    Mixed and low-level wastes generated at the Idaho National Engineering Laboratory (INEL) are required to be managed according to applicable State and Federal regulations, and Department of Energy Orders that provide for the protection of human health and the environment. The Mixed and Low-Level Waste Treatment Facility Project was chartered in 1991, by the Department of Energy to provide treatment capability for these mixed and low-level waste streams. The first project task consisted of conducting engineering studies to identify the waste streams, their potential treatment strategies, and the requirements that would be imposed on the waste streams and the facilities used to process them. The engineering studies, initiated in July 1991, identified 37 mixed waste streams, and 55 low-level waste streams. This report documents the waste stream information and potential treatment strategies, as well as the regulatory requirements for the Department of Energy-owned treatment facility option. The total report comprises three volumes and two appendices. This report consists of Volume 1, which explains the overall program mission, the guiding assumptions for the engineering studies, and summarizes the waste stream and regulatory information, and Volume 2, the Waste Stream Technical Summary which, encompasses the studies conducted to identify the INEL's waste streams and their potential treatment strategies.

  17. Hanford Site waste treatment/storage/disposal integration

    SciTech Connect

    MCDONALD, K.M.

    1999-02-24

    In 1998 Waste Management Federal Services of Hanford, Inc. began the integration of all low-level waste, mixed waste, and TRU waste-generating activities across the Hanford site. With seven contractors, dozens of generating units, and hundreds of waste streams, integration was necessary to provide acute waste forecasting and planning for future treatment activities. This integration effort provides disposition maps that account for waste from generation, through processing, treatment and final waste disposal. The integration effort covers generating facilities from the present through the life-cycle, including transition and deactivation. The effort is patterned after the very successful DOE Complex EM Integration effort. Although still in the preliminary stages, the comprehensive onsite integration effort has already reaped benefits. These include identifying significant waste streams that had not been forecast, identifying opportunities for consolidating activities and services to accelerate schedule or save money; and identifying waste streams which currently have no path forward in the planning baseline. Consolidation/integration of planned activities may also provide opportunities for pollution prevention and/or avoidance of secondary waste generation. A workshop was held to review the waste disposition maps, and to identify opportunities with potential cost or schedule savings. Another workshop may be held to follow up on some of the long-term integration opportunities. A change to the Hanford waste forecast data call would help to align the Solid Waste Forecast with the new disposition maps.

  18. 40 CFR 268.37 - Waste specific prohibitions-ignitable and corrosive characteristic wastes whose treatment...

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 28 2012-07-01 2012-07-01 false Waste specific prohibitions-ignitable and corrosive characteristic wastes whose treatment standards were vacated. 268.37 Section 268.37 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) LAND...

  19. Mixed waste characterization, treatment, and disposal focus area. Technology summary

    SciTech Connect

    1995-06-01

    This paper presents details about the technology development programs of the Department of Energy. In this document, waste characterization, thermal treatment processes, non-thermal treatment processes, effluent monitors and controls, development of on-site innovative technologies, and DOE business opportunities are applied to environmental restoration. The focus areas for research are: contaminant plume containment and remediation; mixed waste characterization, treatment, and disposal; high-level waste tank remediation; landfill stabilization; and decontamination and decommissioning.

  20. Treatment for hydrazine-containing waste water solution

    NASA Technical Reports Server (NTRS)

    Yade, N.

    1986-01-01

    The treatment for waste solutions containing hydrazine is presented. The invention attempts oxidation and decomposition of hydrazine in waste water in a simple and effective processing. The method adds activated charcoal to waste solutions containing hydrazine while maintaining a pH value higher than 8, and adding iron salts if necessary. Then, the solution is aerated.

  1. Global Nuclear Energy Partnership Waste Treatment Baseline

    SciTech Connect

    Dirk Gombert; William Ebert; James Marra; Robert Jubin; John Vienna

    2008-05-01

    The Global Nuclear Energy Partnership program (GNEP) is designed to demonstrate a proliferation-resistant and sustainable integrated nuclear fuel cycle that can be commercialized and used internationally. Alternative stabilization concepts for byproducts and waste streams generated by fuel recycling processes were evaluated and a baseline of waste forms was recommended for the safe disposition of waste streams. Waste forms are recommended based on the demonstrated or expected commercial practicability and technical maturity of the processes needed to make the waste forms, and performance of the waste form materials when disposed. Significant issues remain in developing technologies to process some of the wastes into the recommended waste forms, and a detailed analysis of technology readiness and availability may lead to the choice of a different waste form than what is recommended herein. Evolving regulations could also affect the selection of waste forms.

  2. 40 CFR 35.925-15 - Treatment of industrial wastes.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 1 2010-07-01 2010-07-01 false Treatment of industrial wastes. 35.925... FEDERAL ASSISTANCE STATE AND LOCAL ASSISTANCE Grants for Construction of Treatment Works-Clean Water Act § 35.925-15 Treatment of industrial wastes. That the allowable project costs do not include (a)...

  3. Chemical treatment of mixed waste at the FEMP

    SciTech Connect

    Honigford, L.; Sattler, J.; Dilday, D.; Cook, D.

    1996-05-01

    The Chemical Treatment Project is one in a series of projects implemented by the Fernald Environmental Management Project (FEMP) to treat mixed waste. The projects were initiated to address concerns regarding treatment capacity for mixed waste and to comply with requirements established by the Federal Facility Compliance Act. The Chemical Treatment Project is designed to utilize commercially available mobile technologies to perform treatment at the FEMP site. The waste in the Project consists of a variety of waste types with a wide range of hazards and physical characteristics. The treatment processes to be established for the waste types will be developed by a systematic approach including waste streams evaluation, projectization of the waste streams, and categorization of the stream. This information is utilized to determine the proper train of treatment which will be required to lead the waste to its final destination (i.e., disposal). This approach allows flexibility to manage a wide variety of waste in a cheaper, faster manner than designing a single treatment technology diverse enough to manage all the waste streams.

  4. Chemical treatment of mixed waste can be done.....Today!

    SciTech Connect

    Honigford, L.; Dilday, D.; Cook, D.; Sattler, J.

    1996-02-01

    The Chemical Treatment Project is one in a series of projects implemented by the FEMP to treat mixed waste. The projects were initiated to address concerns regarding treatment capacity for mixed waste and to comply with requirements established by the Federal Facility Compliance Act. The Chemical Treatment Project is designed to utilize commercially available mobile technologies to perform treatment at the FEMP site. The waste in the Project consists of a variety of waste types with a wide range of hazards and physical characteristics. The treatment processes to be established for the waste types will be developed by a systematic approach including waste streams evaluation, projectization of the waste streams, and categorization of the stream. This information is utilized to determine the proper train of treatment which will be required to lead the waste to its final destination (i.e., disposal). This approach allows flexibility to manage a wide variety of waste in a cheaper, faster manner than designing a single treatment technology diverse enough to manage all the waste streams.

  5. Hanford facility dangerous waste permit application, 325 hazardous waste treatment units. Revision 1

    SciTech Connect

    1997-07-01

    This report contains the Hanford Facility Dangerous Waste Permit Application for the 325 Hazardous Waste Treatment Units (325 HWTUs) which consist of the Shielded Analytical Laboratory, the 325 Building, and the 325 Collection/Loadout Station Tank. The 325 HWTUs receive, store, and treat dangerous waste generated by Hanford Facility programs. Routine dangerous and/or mixed waste treatment that will be conducted in the 325 HWTUs will include pH adjustment, ion exchange, carbon absorption, oxidation, reduction, waste concentration by evaporation, precipitation, filtration, solvent extraction, solids washing, phase separation, catalytic destruction, and solidification/stabilization.

  6. Sodium-Bearing Waste Treatment Alternatives Implementation Study

    SciTech Connect

    Charles M. Barnes; James B. Bosley; Clifford W. Olsen

    2004-07-01

    The purpose of this document is to discuss issues related to the implementation of each of the five down-selected INEEL/INTEC radioactive liquid waste (sodium-bearing waste - SBW) treatment alternatives and summarize information in three main areas of concern: process/technical, environmental permitting, and schedule. Major implementation options for each treatment alternative are also identified and briefly discussed. This report may touch upon, but purposely does not address in detail, issues that are programmatic in nature. Examples of these include how the SBW will be classified with respect to the Nuclear Waste Policy Act (NWPA), status of Waste Isolation Pilot Plant (WIPP) permits and waste storage availability, available funding for implementation, stakeholder issues, and State of Idaho Settlement Agreement milestones. It is assumed in this report that the SBW would be classified as a transuranic (TRU) waste suitable for disposal at WIPP, located in New Mexico, after appropriate treatment to meet transportation requirements and waste acceptance criteria (WAC).

  7. Microwave treatment of industrial waste water sludge

    SciTech Connect

    Goodwill, J.E.

    1995-12-31

    Steel mills in the US generate approximately 1 million tons of sludge annually. This is mainly a residue of cooling water, lubricating oils, and metallic fines from hot strip rolling mills and other operations. At present the separation of sludge from the liquid requires large settling tanks, takes several hours of time, and produces a residue that must be disposed of at high cost. The EPRI Center for Materials Production, sponsored by the Electric Power Research Institute (EPRI), has supported development of a microwave based treatment system. This new process, developed by Carnegie Mellon Research Institute of Carnegie Mellon University, and patented by EPRI is 30 times faster, requires 90% less space, and eliminates land-filling by producing materials of value. Electricity usage is only 0.5 kWh per gallon. A review by the American Iron and Steel Institute (AISI) Waste Recycle Technology Task Force of this and various other approaches, concluded that further work on the microwave technology was justified. Subsequently additional work was undertaken toward optimizing the process for treating metallic waste sludges containing lime and polymers. This effort cofunded by EPRI and the AISI was successfully concluded in late 1994. Next a two phase program is being developed to commercialize the process. Phase 1 will demonstrate the technology in a large scale batch mode. Phase 2 will be a commercial scale continuous installation at a steel mill site projected for 1996.

  8. Waste Treatment in the Urban Society

    PubMed Central

    Jones, Philip H.

    1965-01-01

    Domestic and industrial wastes are treated for two distinct purposes: (1) separation of water from the putrescible organic material, dissolved and particulates; (2) disinfection of the water to prevent the transmission of water-borne pathogens. Currently, in North America, disinfection is accomplished by the addition of a powerful oxidizing chemical such as chlorine or a related compound. Separation of solids from liquid is achieved by flocculation followed by sedimentation. Flocculation may be biologically or chemically induced, the former being more economical where practical. Methods of bioflocculation described include the following processes: (1) activated sludge, (2) contact stabilization, (3) tapered aeration, (4) step aeration, (5) total oxidation, and (6) trickling filter. Non-mechanical processes of sewage treatment are economically and technically sound in many rural and semi-rural applications. The oxidation pond ((lagoon) is not mechanical, but this consideration must not lead rural municipalities to a program of neglect. All plants treating human wastes should provide a disinfection process at the effluent. PMID:14308906

  9. Evaluation of alternative treatments for spent fuel rod consolidation wastes and other miscellaneous commercial transuranic wastes

    SciTech Connect

    Ross, W.A.; Schneider, K.J.; Oma, K.H.; Smith, R.I.; Bunnell, L.R.

    1986-05-01

    Eight alternative treatments (and four subalternatives) are considered for both existing commercial transuranic wastes and future wastes from spent fuel consolidation. Waste treatment is assumed to occur at a hypothetical central treatment facility (a Monitored Retrieval Storage facility was used as a reference). Disposal in a geologic repository is also assumed. The cost, process characteristics, and waste form characteristics are evaluated for each waste treatment alternative. The evaluation indicates that selection of a high-volume-reduction alternative can save almost $1 billion in life-cycle costs for the management of transuranic and high-activity wastes from 70,000 MTU of spent fuel compared to the reference MRS process. The supercompaction, arc pyrolysis and melting, and maximum volume reduction alternatives are recommended for further consideration; the latter two are recommended for further testing and demonstration.

  10. Hanford Tank Waste Treatment and Immobilization Plant (WTP) Waste Feed Qualification Program Development Approach - 13114

    SciTech Connect

    Markillie, Jeffrey R.; Arakali, Aruna V.; Benson, Peter A.; Halverson, Thomas G.; Adamson, Duane J.; Herman, Connie C.; Peeler, David K.

    2013-07-01

    The Hanford Tank Waste Treatment and Immobilization Plant (WTP) is a nuclear waste treatment facility being designed and constructed for the U.S. Department of Energy by Bechtel National, Inc. and subcontractor URS Corporation (under contract DE-AC27-01RV14136 [1]) to process and vitrify radioactive waste that is currently stored in underground tanks at the Hanford Site. A wide range of planning is in progress to prepare for safe start-up, commissioning, and operation. The waste feed qualification program is being developed to protect the WTP design, safety basis, and technical basis by assuring acceptance requirements can be met before the transfer of waste. The WTP Project has partnered with Savannah River National Laboratory to develop the waste feed qualification program. The results of waste feed qualification activities will be implemented using a batch processing methodology, and will establish an acceptable range of operator controllable parameters needed to treat the staged waste. Waste feed qualification program development is being implemented in three separate phases. Phase 1 required identification of analytical methods and gaps. This activity has been completed, and provides the foundation for a technically defensible approach for waste feed qualification. Phase 2 of the program development is in progress. The activities in this phase include the closure of analytical methodology gaps identified during Phase 1, design and fabrication of laboratory-scale test apparatus, and determination of the waste feed qualification sample volume. Phase 3 will demonstrate waste feed qualification testing in support of Cold Commissioning. (authors)

  11. Method for aqueous radioactive waste treatment

    DOEpatents

    Bray, Lane A.; Burger, Leland L.

    1994-01-01

    Plutonium, strontium, and cesium found in aqueous waste solutions resulting from nuclear fuel processing are removed by contacting the waste solutions with synthetic zeolite incorporating up to about 5 wt % titanium as sodium titanate in an ion exchange system. More than 99.9% of the plutonium, strontium, and cesium are removed from the waste solutions.

  12. Method for aqueous radioactive waste treatment

    DOEpatents

    Bray, L.A.; Burger, L.L.

    1994-03-29

    Plutonium, strontium, and cesium found in aqueous waste solutions resulting from nuclear fuel processing are removed by contacting the waste solutions with synthetic zeolite incorporating up to about 5 wt % titanium as sodium titanate in an ion exchange system. More than 99.9% of the plutonium, strontium, and cesium are removed from the waste solutions. 3 figures.

  13. Challenges when performing economic optimization of waste treatment: A review

    SciTech Connect

    Juul, N.; Münster, M.; Ravn, H.; Söderman, M. Ljunggren

    2013-09-15

    Highlights: • Review of main optimization tools in the field of waste management. • Different optimization methods are applied. • Different fractions are analyzed. • There is focus on different parameters in different geographical regions. • More research is needed which encompasses both recycling and energy solutions. - Abstract: Strategic and operational decisions in waste management, in particular with respect to investments in new treatment facilities, are needed due to a number of factors, including continuously increasing amounts of waste, political demands for efficient utilization of waste resources, and the decommissioning of existing waste treatment facilities. Optimization models can assist in ensuring that these investment strategies are economically feasible. Various economic optimization models for waste treatment have been developed which focus on different parameters. Models focusing on transport are one example, but models focusing on energy production have also been developed, as well as models which take into account a plant’s economies of scale, environmental impact, material recovery and social costs. Finally, models combining different criteria for the selection of waste treatment methods in multi-criteria analysis have been developed. A thorough updated review of the existing models is presented, and the main challenges and crucial parameters that need to be taken into account when assessing the economic performance of waste treatment alternatives are identified. The review article will assist both policy-makers and model-developers involved in assessing the economic performance of waste treatment alternatives.

  14. 40 CFR 266.235 - What waste treatment does the storage and treatment conditional exemption allow?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR THE MANAGEMENT OF SPECIFIC HAZARDOUS WASTES AND SPECIFIC TYPES OF HAZARDOUS WASTE MANAGEMENT FACILITIES Conditional Exemption for Low... 40 Protection of Environment 27 2011-07-01 2011-07-01 false What waste treatment does the...

  15. 40 CFR 266.235 - What waste treatment does the storage and treatment conditional exemption allow?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR THE MANAGEMENT OF SPECIFIC HAZARDOUS WASTES AND SPECIFIC TYPES OF HAZARDOUS WASTE MANAGEMENT FACILITIES Conditional Exemption for Low... 40 Protection of Environment 26 2010-07-01 2010-07-01 false What waste treatment does the...

  16. 300 Area waste acid treatment system closure plan

    SciTech Connect

    LUKE, S.N.

    1999-05-17

    The Hanford Facility Dangerous Waste Permit Application is considered to be a single application organized into a General Information Portion (document number DOERL-91-28) and a Unit-Specific Portion. The scope of the Unit-Specific Portion includes closure plan documentation submitted for individual, treatment, storage, and/or disposal units undergoing closure, such as the 300 Area Waste Acid Treatment System. Documentation contained in the General Information Portion is broader in nature and could be used by multiple treatment, storage, and/or disposal units (e.g., the glossary provided in the General Information Portion). Whenever appropriate, 300 Area Waste Acid Treatment System documentation makes cross-reference to the General Information Portion, rather than duplicating text. This 300 Area Waste Acid Treatment System Closure Plan (Revision 2) includes a Hanford Facility Dangerous Waste Permit Application, Part A, Form 3. Information provided in this closure plan is current as of April 1999.

  17. Industrial waste treatment process engineering. Volume 2: Biological processes

    SciTech Connect

    Celenza, G.J.

    1999-11-01

    Industrial Waste Treatment Process Engineering is a step-by-step implementation manual in three volumes, detailing the selection and design of industrial liquid and solid waste treatment systems. It consolidates all the process engineering principles required to evaluate a wide range of industrial facilities, starting with pollution prevention and source control and ending with end-of-pipe treatment technologies. This three-volume set is a practical guide for environmental engineers with process implementation responsibilities; a one-stop resource for process engineering requirements--from plant planning to implementing specific treatment technologies for unit operations; a comprehensive reference for industrial waste treatment technologies; and includes calculations and worked problems based on industry cases. The contents of Volume 2 include: aeration; aerobic biological oxidation; activated sludge system; biological oxidation: lagoons; biological oxidation: fixed film processes; aerobic digesters; anaerobic waste treatment, anaerobic sludge treatment; and sedimentation.

  18. Nuclear waste treatment program: Annual report for FY 1987

    SciTech Connect

    Brouns, R.A.; Powell, J.A.

    1988-09-01

    Two of the US Department of Energy's (DOE) nuclear waste management-related goals are to ensure that waste management is not an obstacle to the further development of light-water reactors and the closure of the nuclear fuel cycle and to fulfill its institutional responsibility for providing safe storage and disposal of existing and future nuclear wastes. As part of its approach to achieving these goals, the Office of Remedial Action and Waste Technology of DOE established what is now called the Nuclear Waste Treatment Program (NWTP) at the Pacific Northwest Laboratory during the second half of FY 1982. To support DOE's attainment of its goals, the NWTP is to provide technology necessary for the design and operation of nuclear waste treatment facilities by commercial enterprises as part of a licensed waste management system and problem-specific treatment approaches, waste form and treatment process adaptations, equipment designs, and trouble-shooting assistance, as required to treat existing wastes. This annual report describes progress during FY 1987 towards meeting these two objectives. 24 refs., 59 figs., 24 tabs.

  19. Westinghouse Cementation Facility of Solid Waste Treatment System - 13503

    SciTech Connect

    Jacobs, Torsten; Aign, Joerg

    2013-07-01

    During NPP operation, several waste streams are generated, caused by different technical and physical processes. Besides others, liquid waste represents one of the major types of waste. Depending on national regulation for storage and disposal of radioactive waste, solidification can be one specific requirement. To accommodate the global request for waste treatment systems Westinghouse developed several specific treatment processes for the different types of waste. In the period of 2006 to 2008 Westinghouse awarded several contracts for the design and delivery of waste treatment systems related to the latest CPR-1000 nuclear power plants. One of these contracts contains the delivery of four Cementation Facilities for waste treatment, s.c. 'Follow on Cementations' dedicated to three locations, HongYanHe, NingDe and YangJiang, of new CPR-1000 nuclear power stations in the People's Republic of China. Previously, Westinghouse delivered a similar cementation facility to the CPR-1000 plant LingAo II, in Daya Bay, PR China. This plant already passed the hot functioning tests successfully in June 2012 and is now ready and released for regular operation. The 'Follow on plants' are designed to package three 'typical' kind of radioactive waste: evaporator concentrates, spent resins and filter cartridges. The purpose of this paper is to provide an overview on the Westinghouse experience to design and execution of cementation facilities. (authors)

  20. Mixed Waste Treatment Project: Computer simulations of integrated flowsheets

    SciTech Connect

    Dietsche, L.J.

    1993-12-01

    The disposal of mixed waste, that is waste containing both hazardous and radioactive components, is a challenging waste management problem of particular concern to DOE sites throughout the United States. Traditional technologies used for the destruction of hazardous wastes need to be re-evaluated for their ability to handle mixed wastes, and in some cases new technologies need to be developed. The Mixed Waste Treatment Project (MWTP) was set up by DOE`s Waste Operations Program (EM30) to provide guidance on mixed waste treatment options. One of MWTP`s charters is to develop flowsheets for prototype integrated mixed waste treatment facilities which can serve as models for sites developing their own treatment strategies. Evaluation of these flowsheets is being facilitated through the use of computer modelling. The objective of the flowsheet simulations is to provide mass and energy balances, product compositions, and equipment sizing (leading to cost) information. The modelled flowsheets need to be easily modified to examine how alternative technologies and varying feed streams effect the overall integrated process. One such commercially available simulation program is ASPEN PLUS. This report contains details of the Aspen Plus program.

  1. A process for treatment of mixed waste containing chemical plating wastes

    SciTech Connect

    Anast, K.R.; Dziewinski, J.; Lussiez, G.

    1995-02-01

    The Waste Treatment and Minimization Group at Los Alamos National Laboratory has designed and will be constructing a transportable treatment system to treat low-level radioactive mixed waste generated during plating operations. The chemical and plating waste treatment system is composed of two modules with six submodules, which can be trucked to user sites to treat a wide variety of aqueous waste solutions. The process is designed to remove the hazardous components from the waste stream, generating chemically benign, disposable liquids and solids with low level radioactivity. The chemical and plating waste treatment system is designed as a multifunctional process capable of treating several different types of wastes. At this time, the unit has been the designated treatment process for these wastes: Destruction of free cyanide and metal-cyanide complexes from spent plating solutions; destruction of ammonia in solution from spent plating solutions; reduction of Cr{sup VI} to Cr{sup III} from spent plating solutions, precipitation, solids separation, and immobilization; heavy metal precipitation from spent plating solutions, solids separation, and immobilization, and acid or base neutralization from unspecified solutions.

  2. Disposition of Tank 48H Organics By Fluidized Bed Steam Reforming (FBSR) (U)

    SciTech Connect

    JANTZEN, CAROLM.

    2004-03-29

    An In Tank Processing (ITP) technology was developed at the Savannah River Site to remove Cs-137 from high-level waste supernates. During the ITP process monosodium titanate and sodium tetraphenylborate (NaTPB) were added to the salt supernate to adsorb Sr-90/Pu-238 and precipitate Cs-137 as CsTPB, respectively. This process was demonstrated at the SRS in 1983. The demonstration produced 53,000 gallons of 2.5 weight per cent Cs rich precipitate containing TPB, which was later washed and diluted to 250,000 gallons. This material is currently stored in SRS tanks. The washed precipitate was to ultimately be disposed in borosilicate glass in the Defense Waste Processing Facility. Due to safety concerns the ITP process was abandoned in 1998, and new technologies are being researched for Cs-137 removal. In order to make space in the SRS Tank farm, the tank waste must be removed. Therefore, the tank waste must be processed to reduce or eliminate levels of nitrates, nitrites, and sodium tetra phenylborate (NaTPB) in order to reduce impacts of these species before it is vitrified at the DWPF. Fluidized Bed Steam Reforming (FBSR) is being considered as a candidate technology for destroying the nitrates and the NaTPB prior to melting. The purposes of the current study, organic destruction and downstream processing of T48H waste slurry were fulfilled. TPB was destroyed in all 19 samples tested with the simulated FBSR process at operational temperatures 650-725 degrees Celsius.

  3. Hydrometallurgical Treatment for Mixed Waste Battery Material

    NASA Astrophysics Data System (ADS)

    Ma, L. W.; Xi, X. L.; Zhang, Z. Z.; Huang, Z. Q.; Chen, J. P.

    2017-02-01

    Hydrometallurgical experiments are generally required to assess the appropriate treatment process before the establishment of the industrial recovery process for waste battery materials. The effects of acid systems and oxidants in metal leaching were studied. The comprehensive leaching effects of the citric acid were superior to the sulfuric acid. The potassium permanganate inhibits the dissolution of metals. Thermodynamic calculations showed that metals precipitate more easily in sulfuric acid system than in citric acid system. The Fe precipitation efficiency in sulfuric acid system was 90% at pH 3.5, but with considerable losses of Co (30%) and Ni (40%). The proper pH and organic/aqueous (O/A) ratio for Fe and Zn removal with Di-(2-ethylhexyl) phosphoric acid extraction were 2 and 0.5, respectively; while for the removal of Cu and Mn, the best pH and O/A ratio were 3 and 0.75, respectively. Crude manganese carbonate and a cobalt-nickel enriched liquid were obtained by selective precipitation in raffinate using an ammonium bicarbonate solution. In citric acid systems, the precipitation efficiency of Co, Ni, Mn, Fe, Cu and Zn were less than 20% at pH 7. The proper pH and O/A ratio for the separation of the metals in two groups (Ni/Co/Cu and Mn/Fe/Zn) were 1.5 and 2. The cobalt-nickel-copper enriched liquid was finally obtained.

  4. GUIDE TO TREATMENT TECHNOLOGIES FOR HAZARDOUS WASTES AT SUPERFUND SITES

    EPA Science Inventory

    Over the past fewyears, it has become increasinsly evident that land disposal of hazardous wastes is at least only a temporary solution for much of the wastes present at Superfund sites. The need for more Iong-term, permanent "treatment solutions as alternatives to land disposal ...

  5. Measurement of urinary copper excretion after 48-h d-penicillamine cessation as a compliance assessment in Wilson's disease.

    PubMed

    Dzieżyc, Karolina; Litwin, Tomasz; Chabik, Grzegorz; Członkowska, Anna

    2015-01-01

    Treatment of Wilson's disease (WD) with anti-copper agents is effective in most compliant patients. During long-term treatment with chelating agents, a two-day interruption of the treatment should result in normal urinary copper concentrations (<50 μg/dl). The aim of this study was to establish the usefulness of this method as a compliance assessment in these patients. We examined consecutive patients treated with d-penicillamine (DPA) undergoing routine follow-up studies at our center. We performed 24-h urinary copper excretion analysis 48 h after interruption of chelating therapy. Thirty-two patients were enrolled. After DPA cessation, normalization of copper excretion was observed in 91% of reportedly compliant patients. The specificity and sensitivity values of this test were 87% and 77%, respectively. Measurement of 24-h urinary copper excretion after a 48-h interruption of DPA therapy in patients with WD is a reliable method for confirming patients' compliance.

  6. Air pollutants emissions from waste treatment and disposal facilities.

    PubMed

    Hamoda, Mohamed F

    2006-01-01

    This study examined the atmospheric pollution created by some waste treatment and disposal facilities in the State of Kuwait. Air monitoring was conducted in a municipal wastewater treatment plant, an industrial wastewater treatment plant established in a petroleum refinery, and at a landfill site used for disposal of solid wastes. Such plants were selected as models for waste treatment and disposal facilities in the Arabian Gulf region and elsewhere. Air measurements were made over a period of 6 months and included levels of gaseous emissions as well as concentrations of volatile organic compounds (VOCs). Samples of gas and bioaerosols were collected from ambient air surrounding the treatment facilities. The results obtained from this study have indicated the presence of VOCs and other gaseous pollutants such as methane, ammonia, and hydrogen sulphide in air surrounding the waste treatment and disposal facilities. In some cases the levels exceeded the concentration limits specified by the air quality standards. Offensive odors were also detected. The study revealed that adverse environmental impact of air pollutants is a major concern in the industrial more than in the municipal waste treatment facilities but sitting of municipal waste treatment and disposal facilities nearby the urban areas poses a threat to the public health.

  7. Prospects of effective microorganisms technology in wastes treatment in Egypt

    PubMed Central

    Shalaby, Emad A

    2011-01-01

    Sludge dewatering and treatment may cost as much as the wastewater treatment. Usually large proportion of the pollutants in wastewater is organic. They are attacked by saprophytic microorganisms, i.e. organisms that feed upon dead organic matter. Activity of organisms causes decomposition of organic matter and destroys them, where the bacteria convert the organic matter or other constituents in the wastewater to new cells, water, gases and other products. Demolition activities, including renovation/remodeling works and complete or selective removal/demolishing of existing structures either by man-made processes or by natural disasters, create an extensive amount of wastes. These demolition wastes are characterized as heterogeneous mixtures of building materials that are usually contaminated with chemicals and dirt. In developing countries, it is estimated that demolition wastes comprise 20% to 30% of the total annual solid wastes. In Egypt, the daily quantity of construction and demolition (C&D) waste has been estimated as 10 000 tones. That is equivalent to one third of the total daily municipal solid wastes generated per day in Egypt. The zabbaliin have since expanded their activities and now take the waste they collect back to their garbage villages where it is sorted into recyclable components: paper, plastics, rags, glass, metal and food. The food waste is fed to pigs and the other items are sold to recycling centers. This paper summarizes the wastewater and solid wastes management in Egypt now and future. PMID:23569767

  8. Thermal Treatment of Solid Wastes Using the Electric Arc Furnace

    SciTech Connect

    O'Connor, W.K.; Turner, P.C.

    1999-09-01

    A thermal waste treatment facility has been developed at the Albany Research Center (ARC) over the past seven years to process a wide range of heterogeneous mixed wastes, on a scale of 227 to 907 kg/h (500 to 2,000 lb/h). The current system includes a continuous feed system, a 3-phase AC, 0.8 MW graphite electrode arc furnace, and a dedicated air pollution control system (APCS) which includes a close-coupled thermal oxidizer, spray cooler, baghouse, and wet scrubber. The versatility of the complete system has been demonstrated during 5 continuous melting campaigns, ranging from 11 to 25 mt (12 to 28 st) of treated wastes per campaign, which were conducted on waste materials such as (a) municipal incinerator ash, (b) simulated low-level radioactive, high combustible-bearing mixed wastes, (c) simulated low-level radioactive liquid tank wastes, (d) heavy metal contaminated soils, and (e) organic-contaminated dredging spoils. In all cases, the glass or slag products readily passed the U.S. Environmental Protection Agency (EPA) Toxicity Characteristic Leachability Program (TCLP) test. Additional studies are currently under way on electric utility wastes, steel and aluminum industry wastes, as well as zinc smelter residues. Thermal treatment of these solid waste streams is intended to produce a metallic product along with nonhazardous glass or slag products.

  9. 300 Area waste acid treatment system closure plan. Revision 1

    SciTech Connect

    1996-03-01

    This section provides a description of the Hanford Site, identifies the proposed method of 300 Area Waste Acid Treatment System (WATS) closure, and briefly summarizes the contents of each chapter of this plan.

  10. WASTE MINIMIZATION PRACTICES AT TWO CCA WOOD TREATMENT PLANTS

    EPA Science Inventory

    Two chromated copper arsenate (CCA) wood-treatment plants were assessed for their waste minimization practices. These practices have been reflected in several areas, including facility designs, process controls, and management practices. he objectives were to estimate the amount...

  11. Mixed Waste Encapsulation in Polyester Resins. Treatment for Mixed Wastes Containing Salts. Mixed Waste Focus Area. OST Reference #1685

    SciTech Connect

    None, None

    1999-09-01

    Throughout the Department of Energy (DOE) complex there are large inventories of homogeneous solid mixed wastes, such as treatment residues, fly ashes, and sludges that contain relatively high concentrations (greater than 15% by weight) of salts. The inherent solubility of nitrate, sulfate, and chloride salts makes traditional cement stabilization of these waste streams difficult, expensive, and challenging. Salts can effect the setting rate of cements and can react with cement hydration products to form expansive and cement damaging compounds. Many of these salt wastes are in a dry granular form and are the by-product of treating spent acidic and metal solutions used to recover and reformulate nuclear weapons materials over the past 50 years. At the Idaho National Engineering and Environmental Laboratory (INEEL) alone, there is approximately 8,000 cubic meters of nitrate salts (potassium and sodium nitrate) stored above ground with an earthen cover. Current estimates indicate that over 200 million kg of contaminated salt wastes exist at various DOE sites. Continued primary treatment of waste water coupled with the use of mixed waste incinerators may generate an additional 5 million kg of salt-containing, mixed waste residues each year. One of the obvious treatment solutions for these salt-containing wastes is to immobilize the hazardous components to meet Environmental Protection Agency/Resource Conservation and Recovery Act (EPA/RCRA) Land Disposal Restrictions (LDR), thus rendering the mixed waste to a radioactive waste only classification. One proposed solution is to use thermal treatment via vitrification to immobilize the hazardous component and thereby substantially reduce the volume, as well as provide exceptional durability. However, these melter systems involve expensive capital apparatus with complicated off-gas systems. In addition, the vitrification of high salt waste may cause foaming and usually requires extensive development to specify glass

  12. Sodium Recycle Economics for Waste Treatment Plant Operations

    SciTech Connect

    Sevigny, Gary J.; Poloski, Adam P.; Fountain, Matthew S.

    2008-03-01

    Sodium recycle at the Hanford Waste Treatment Plant (WTP) would reduce the number of glass canisters produced, and has the potential to save the U.S. Department of Energy (DOE) tens of millions of dollars. The sodium, added in the form of sodium hydroxide, was originally added to minimize corrosion of carbon-steel storage tanks from acidic reprocessing wastes. In the baseline Hanford treatment process, sodium hydroxide is required to leach gibbsite and boehmite from the high level waste (HLW) sludge. In turn, this reduces the amount of HLW glass produced. Currently, a significant amount of additional sodium hydroxide will be added to the process to maintain aluminate solubility at ambient temperatures during ion exchange of cesium. The vitrification of radioactive waste is limited by sodium content, and this additional sodium mass will increase low-activity waste-glass mass.

  13. Safety Evaluation for Hull Waste Treatment Process in JNC

    SciTech Connect

    Kojima, H.; Kurakata, K.

    2002-02-26

    Hull wastes and some scrapped equipment are typical radioactive wastes generated from reprocessing process in Tokai Reprocessing Plant (TRP). Because hulls are the wastes remained in the fuel shearing and dissolution, they contain high radioactivity. Japan Nuclear Cycle Development Institute (JNC) has started the project of Hull Waste Treatment Facility (HWTF) to treat these solid wastes using compaction and incineration methods since 1993. It is said that Zircaloy fines generated from compaction process might burn and explode intensely. Therefore explosive conditions of the fines generated in compaction process were measured. As these results, it was concluded that the fines generated from the compaction process were not hazardous material. This paper describes the outline of the treatment process of hulls and results of safety evaluation.

  14. A bio-hybrid anaerobic treatment of papaya processing wastes

    SciTech Connect

    Yang, P.Y.; Chou, C.Y.

    1987-01-01

    Hybrid anaerobic treatment of papaya processing wastes is technically feasible. At 30/sup 0/C, the optimal organic loading rates for maximizing organic removal efficiency and methane production are 1.3 and 4.8 g TCOD/1/day, respectively. Elimination of post-handling and treatment of digested effluent can also be achieved. The system is more suitable for those processing plants with a waste amount of more than 3,000 metric tons per year.

  15. Development and testing of a wet oxidation waste processing system. [for waste treatment aboard manned spacecraft

    NASA Technical Reports Server (NTRS)

    Weitzmann, A. L.

    1977-01-01

    The wet oxidation process is considered as a potential treatment method for wastes aboard manned spacecraft for these reasons: (1) Fecal and urine wastes are processed to sterile water and CO2 gas. However, the water requires post-treatment to remove salts and odor; (2) the residual ash is negligible in quantity, sterile and easily collected; and (3) the product CO2 gas can be processed through a reduction step to aid in material balance if needed. Reaction of waste materials with oxygen at elevated temperature and pressure also produces some nitrous oxide, as well as trace amounts of a few other gases.

  16. Audits of hazardous waste TSDFs let generators sleep easy. [Hazardous waste treatment, storage and disposal facility

    SciTech Connect

    Carr, F.H.

    1990-02-01

    Because of the increasingly strict enforcement of the Comprehensive Environmental Response, Compensation and Liability Act (CERCLA) and the Resource Conservation and Recovery Act (RCRA), generators of hazardous waste are compelled to investigate the hazardous waste treatment, storage and disposal facility (TSDF) they use. This investigation must include an environmental and a financial audit. Simple audits may be performed by the hazardous waste generator, while more thorough ones such as those performed for groups of generators are more likely to be conducted by environmental consultants familiar with treatment, storage, and disposal techniques and the regulatory framework that guides them.

  17. 40 CFR 35.925-15 - Treatment of industrial wastes.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... sources or (b) costs allocable to the treatment for control or removal of pollutants in wastewater... FEDERAL ASSISTANCE STATE AND LOCAL ASSISTANCE Grants for Construction of Treatment Works-Clean Water Act § 35.925-15 Treatment of industrial wastes. That the allowable project costs do not include (a)...

  18. Membrane permeation employed for radioactive wastes treatment

    SciTech Connect

    Chmielewski, A.G.; Harasimowicz, M.; Zakrzewska-Trznadel, G.

    1996-12-31

    In the paper certain aspects of development process aiming at reducing the radioactivity of liquid low-level waste streams (LLLW) are presented. The influence of gamma and electron radiation on ultrafiltration membranes has been studied and changes of their transport properties have been determined at different doses. Membrane processes: ultrafiltration (UF), seeded ultrafiltration (SUF), low-pressure reverse osmosis (LPRO) and membrane distillation (MD) have been examined. The UF/RO pilot plant for purification/concentration of low-level liquid waste is described. 4 refs., 2 figs.

  19. TASK TECHNICAL AND QUALITY ASSURANCE PLAN FOR THE CHARACTERIZATION AND LEACHING OF A THERMOWELL AND CONDUCTIVITY PROBE PIPE SAMPLE FROM TANK 48H

    SciTech Connect

    Fondeur, F

    2005-11-02

    A key component for the accelerated implementation and operation of the Salt Waste Processing Facility (SWPF) is the recovery of Tank 48H. Tank 48H is a type IIIA tank with a maximum capacity of 1.3 million gallons. The material on the Tank 48H internal tank surfaces is estimated to have a total volume of approximately 115 gallons consisting of mostly water soluble solids with approximately 20 wt% insoluble solids (33 Kg TPB). This film is assumed to be readily removable. The material on the internal equipment/surfaces of Tank 48H is presumed to be easily removed by slurry pump operation. For Tank 49H, the slurry pumps were operated almost continuously for approximately 6 months after which time the tank was inspected and the film was found to be removed. The major components of the Tank 49H film were soluble solids--Na{sub 3}H(CO){sub 2}, Al(OH){sub 3}, NaTPB, NaNO{sub 3} and NaNO{sub 2}. Although the Tank 48H film is expected to be primarily soluble solids, it may not behave the same as the Tank 49H film. Depending on when the Recycle material or inhibited water can be added to Tank 48H, the tank may not be allowed to agitate for this same amount of time. The tank will be filled above 150 inches and agitated at least once during the Aggregation process. If the material cannot be removed after completion of these batches, the material may be removed with additional fill and agitation operations. There is a risk that this will not remove the material from the internal surfaces. As a risk mitigation activity, properties of the film and the ease of removing the film from the tank will be evaluated prior to initiating Aggregation. This task will investigate the dissolution of Tank 48H solid deposits in inhibited water and DWPF recycle. To this end, tank personnel plan to cut and remove a thermowell pipe from Tank 48H and submit the cut pieces to SRNL for both characterization and leaching behavior. A plan for the removal, packaging and transport of the thermowell pipe

  20. An overview of in situ waste treatment technologies

    SciTech Connect

    Walker, S.; Hyde, R.A.; Piper, R.B.; Roy, M.W.

    1992-01-01

    In situ technologies are becoming an attractive remedial alternative for eliminating environmental problems. In situ treatments typically reduce risks and costs associated with retrieving, packaging, and storing or disposing-waste and are generally preferred over ex situ treatments. Each in situ technology has specific applications, and, in order to provide the most economical and practical solution to a waste problem, these applications must be understood. This paper presents an overview of thirty different in situ remedial technologies for buried wastes or contaminated soil areas. The objective of this paper is to familiarize those involved in waste remediation activities with available and emerging in situ technologies so that they may consider these options in the remediation of hazardous and/or radioactive waste sites. Several types of in situ technologies are discussed, including biological treatments, containment technologies, physical/chemical treatments, solidification/stabilization technologies, and thermal treatments. Each category of in situ technology is briefly examined in this paper. Specific treatments belonging to these categories are also reviewed. Much of the information on in situ treatment technologies in this paper was obtained directly from vendors and universities and this information has not been verified.

  1. An overview of in situ waste treatment technologies

    SciTech Connect

    Walker, S.; Hyde, R.A.; Piper, R.B.; Roy, M.W.

    1992-08-01

    In situ technologies are becoming an attractive remedial alternative for eliminating environmental problems. In situ treatments typically reduce risks and costs associated with retrieving, packaging, and storing or disposing-waste and are generally preferred over ex situ treatments. Each in situ technology has specific applications, and, in order to provide the most economical and practical solution to a waste problem, these applications must be understood. This paper presents an overview of thirty different in situ remedial technologies for buried wastes or contaminated soil areas. The objective of this paper is to familiarize those involved in waste remediation activities with available and emerging in situ technologies so that they may consider these options in the remediation of hazardous and/or radioactive waste sites. Several types of in situ technologies are discussed, including biological treatments, containment technologies, physical/chemical treatments, solidification/stabilization technologies, and thermal treatments. Each category of in situ technology is briefly examined in this paper. Specific treatments belonging to these categories are also reviewed. Much of the information on in situ treatment technologies in this paper was obtained directly from vendors and universities and this information has not been verified.

  2. Radioactive Liquid Waste Treatment Facility: Environmental Information Document

    SciTech Connect

    Haagenstad, H.T.; Gonzales, G.; Suazo, I.L.

    1993-11-01

    At Los Alamos National Laboratory (LANL), the treatment of radioactive liquid waste is an integral function of the LANL mission: to assure U.S. military deterrence capability through nuclear weapons technology. As part of this mission, LANL conducts nuclear materials research and development (R&D) activities. These activities generate radioactive liquid waste that must be handled in a manner to ensure protection of workers, the public, and the environment. Radioactive liquid waste currently generated at LANL is treated at the Radioactive Liquid Waste Treatment Facility (RLWTF), located at Technical Area (TA)-50. The RLWTF is 30 years old and nearing the end of its useful design life. The facility was designed at a time when environmental requirements, as well as more effective treatment technologies, were not inherent in engineering design criteria. The evolution of engineering design criteria has resulted in the older technology becoming less effective in treating radioactive liquid wastestreams in accordance with current National Pollutant Discharge Elimination System (NPDES) and Department of Energy (DOE) regulatory requirements. Therefore, to support ongoing R&D programs pertinent to its mission, LANL is in need of capabilities to efficiently treat radioactive liquid waste onsite or to transport the waste off site for treatment and/or disposal. The purpose of the EID is to provide the technical baseline information for subsequent preparation of an Environmental Impact Statement (EIS) for the RLWTF. This EID addresses the proposed action and alternatives for meeting the purpose and need for agency action.

  3. Disposal of water treatment wastes containing arsenic - a review.

    PubMed

    Sullivan, Colin; Tyrer, Mark; Cheeseman, Christopher R; Graham, Nigel J D

    2010-03-15

    Solid waste management in developing countries is often unsustainable, relying on uncontrolled disposal in waste dumps. Particular problems arise from the disposal of treatment residues generated by removing arsenic (As) from drinking water because As can be highly mobile and has the potential to leach back to ground and surface waters. This paper reviews the disposal of water treatment wastes containing As, with a particular emphasis on stabilisation/solidification (S/S) technologies which are currently used to treat industrial wastes containing As. These have been assessed for their appropriateness for treating As containing water treatment wastes. Portland cement/lime mixes are expected (at least in part) to be appropriate for wastes from sorptive filters, but may not be appropriate for precipitative sludges, because ferric flocs often used to sorb As can retard cement hydration. Brine resulting from the regeneration of activated alumina filters is likely to accelerate cement hydration. Portland cement can immobilize soluble arsenites and has been successfully used to stabilise As-rich sludges and it may also be suitable for treating sludges generated from precipitative removal units. Oxidation of As(III) to As(V) and the formation of calcium-arsenic compounds are important immobilisation mechanisms for As in cements. Geopolymers are alternative binder systems that are effective for treating wastes rich in alumina and metal hydroxides and may have potential for As wastes generated using activated alumina. The long-term stability of cemented, arsenic-bearing wastes is however uncertain, as like many cements, they are susceptible to carbonation effects which may result in the subsequent re-release of As.

  4. LANL Waste acceptance criteria, Chapter 3, radioactive liquid waste treatment facility

    SciTech Connect

    McClenahan, Robert L.

    2006-08-01

    The Radioactive Liquid Waste Treatment Facility (RLWTF) receives and treats aqueous radioactive wastewater generated at Los Alamos National Laboratory (LANL) to meet he discharge criteria specified in a National Pollution Discharge Elimination System (NPDES) permit. The majority of this wastewater is received at the RLWTF through a network of buried pipelines, known as the Radioactive Liquid Waste Collection System (RLWCS). Other wastewater is transported to the RLWTF by truck. The Waste Acceptance Criteria (WAC) outlined in this Chapter are applicable to all radioactive wastewaters which are conveyed to the Technical Area 50(T A-50), RL WTF by the RLWCS or by truck.

  5. Guide to land treatment of municipal waste water in Illinois

    SciTech Connect

    Skelton, L.W.; Hinesly, T.D.; John, S.F.

    1989-01-01

    Waste water is a recyclable commodity. Organic matter, nitrogen, phosphorus, and micronutrients in waste water are generally harmful when discharged to lakes and streams, but these constituents have a positive economic value when applied under properly controlled conditions to vegetated soils. The guide provides an overview of planning for a land-treatment system. It first discusses the potential for land treatment in Illinois, how to modify lagoons for land treatment, economic considerations, health and environmental concerns, regulatory requirements, and public education. It then provides more technical information on land-treatment processes, site and waste-load evaluation, systems for agricultural production, the potential for supplemental irrigation in Illinois, general site management, and system monitoring.

  6. Waste Water Management and Infectious Disease. Part II: Impact of Waste Water Treatment

    ERIC Educational Resources Information Center

    Cooper, Robert C.

    1975-01-01

    The ability of various treatment processes, such as oxidation ponds, chemical coagulation and filtration, and the soil mantle, to remove the agents of infectious disease found in waste water is discussed. The literature concerning the efficiency of removal of these organisms by various treatment processes is reviewed. (BT)

  7. Hybrid Microwave Treatment of SRS TRU and Mixed Wastes

    SciTech Connect

    Wicks, G.G.

    1999-11-18

    A new process, using hybrid microwave energy, has been developed as part of the Strategic Research and Development program and successfully applied to treatment of a wide variety of non-radioactive materials, representative of SRS transuranic (TRU) and mixed wastes. Over 35 simulated (non-radioactive) TRU and mixed waste materials were processed individually, as well as in mixed batches, using hybrid microwave energy, a new technology now being patented by Westinghouse Savannah River Company (WSRC).

  8. Reliability analysis of common hazardous waste treatment processes

    SciTech Connect

    Waters, Robert D.

    1993-05-01

    Five hazardous waste treatment processes are analyzed probabilistically using Monte Carlo simulation to elucidate the relationships between process safety factors and reliability levels. The treatment processes evaluated are packed tower aeration, reverse osmosis, activated sludge, upflow anaerobic sludge blanket, and activated carbon adsorption.

  9. Novel Electrochemical Process for Treatment of Perchlorate in Waste Water

    DTIC Science & Technology

    2011-03-06

    ESIX technology is effective and selective for perchlorate removal and can potentially be used for large-scale treatment of wastewater . vii 1...Final Report Novel Electrochemical Process for Treatment of Perchlorate in Waste Water SERDP Project ER-1433 MARCH 2011 Yuehe Lin...

  10. Mixed and Low-Level Waste Treatment Facility project

    SciTech Connect

    Not Available

    1992-04-01

    Mixed and low-level wastes generated at the Idaho National Engineering Laboratory (INEL) are required to be managed according to applicable State and Federal regulations, and Department of Energy Orders that provide for the protection of human health and the environment. The Mixed and Low-Level Waste Treatment Facility Project was chartered in 1991, by the Department of Energy to provide treatment capability for these mixed and low-level waste streams. The first project task consisted of conducting engineering studies to identify the waste streams, their potential treatment strategies, and the requirements that would be imposed on the waste streams and the facilities used to process them. This report, Appendix A, Environmental Regulatory Planning Documentation, identifies the regulatory requirements that would be imposed on the operation or construction of a facility designed to process the INEL's waste streams. These requirements are contained in five reports that discuss the following topics: (1) an environmental compliance plan and schedule, (2) National Environmental Policy Act requirements, (3) preliminary siting requirements, (4) regulatory justification for the project, and (5) health and safety criteria.

  11. Mixed and Low-Level Treatment Facility Project. Appendix B, Waste stream engineering files, Part 1, Mixed waste streams

    SciTech Connect

    Not Available

    1992-04-01

    This appendix contains the mixed and low-level waste engineering design files (EDFS) documenting each low-level and mixed waste stream investigated during preengineering studies for Mixed and Low-Level Waste Treatment Facility Project. The EDFs provide background information on mixed and low-level waste generated at the Idaho National Engineering Laboratory. They identify, characterize, and provide treatment strategies for the waste streams. Mixed waste is waste containing both radioactive and hazardous components as defined by the Atomic Energy Act and the Resource Conservation and Recovery Act, respectively. Low-level waste is waste that contains radioactivity and is not classified as high-level waste, transuranic waste, spent nuclear fuel, or 11e(2) byproduct material as defined by DOE 5820.2A. Test specimens of fissionable material irradiated for research and development only, and not for the production of power or plutonium, may be classified as low-level waste, provided the concentration of transuranic is less than 100 nCi/g. This appendix is a tool that clarifies presentation format for the EDFS. The EDFs contain waste stream characterization data and potential treatment strategies that will facilitate system tradeoff studies and conceptual design development. A total of 43 mixed waste and 55 low-level waste EDFs are provided.

  12. RESULTS OF COPPER CATALYZED PEROXIDE OXIDATION (CCPO) OF TANK 48H SIMULANTS

    SciTech Connect

    Peters, T.; Pareizs, J.; Newell, J.; Fondeur, F.; Nash, C.; White, T.; Fink, S.

    2012-08-14

    Savannah River National Laboratory (SRNL) performed a series of laboratory-scale experiments that examined copper-catalyzed hydrogen peroxide (H{sub 2}O{sub 2}) aided destruction of organic components, most notably tetraphenylborate (TPB), in Tank 48H simulant slurries. The experiments were designed with an expectation of conducting the process within existing vessels of Building 241-96H with minimal modifications to the existing equipment. Results of the experiments indicate that TPB destruction levels exceeding 99.9% are achievable, dependent on the reaction conditions. The following observations were made with respect to the major processing variables investigated. A lower reaction pH provides faster reaction rates (pH 7 > pH 9 > pH 11); however, pH 9 reactions provide the least quantity of organic residual compounds within the limits of species analyzed. Higher temperatures lead to faster reaction rates and smaller quantities of organic residual compounds. Higher concentrations of the copper catalyst provide faster reaction rates, but the highest copper concentration (500 mg/L) also resulted in the second highest quantity of organic residual compounds. Faster rates of H{sub 2}O{sub 2} addition lead to faster reaction rates and lower quantities of organic residual compounds. Testing with simulated slurries continues. Current testing is examining lower copper concentrations, refined peroxide addition rates, and alternate acidification methods. A revision of this report will provide updated findings with emphasis on defining recommended conditions for similar tests with actual waste samples.

  13. The use of fly larvae for organic waste treatment.

    PubMed

    Čičková, Helena; Newton, G Larry; Lacy, R Curt; Kozánek, Milan

    2015-01-01

    The idea of using fly larvae for processing of organic waste was proposed almost 100 years ago. Since then, numerous laboratory studies have shown that several fly species are well suited for biodegradation of organic waste, with the house fly (Musca domestica L.) and the black soldier fly (Hermetia illucens L.) being the most extensively studied insects for this purpose. House fly larvae develop well in manure of animals fed a mixed diet, while black soldier fly larvae accept a greater variety of decaying organic matter. Blow fly and flesh fly maggots are better suited for biodegradation of meat processing waste. The larvae of these insects have been successfully used to reduce mass of animal manure, fecal sludge, municipal waste, food scrapes, restaurant and market waste, as well as plant residues left after oil extraction. Higher yields of larvae are produced on nutrient-rich wastes (meat processing waste, food waste) than on manure or plant residues. Larvae may be used as animal feed or for production of secondary products (biodiesel, biologically active substances). Waste residue becomes valuable fertilizer. During biodegradation the temperature of the substrate rises, pH changes from neutral to alkaline, ammonia release increases, and moisture decreases. Microbial load of some pathogens can be substantially reduced. Both larvae and digested residue may require further treatment to eliminate pathogens. Facilities utilizing natural fly populations, as well as pilot and full-scale plants with laboratory-reared fly populations have been shown to be effective and economically feasible. The major obstacles associated with the production of fly larvae from organic waste on an industrial scale seem to be technological aspects of scaling-up the production capacity, insufficient knowledge of fly biology necessary to produce large amounts of eggs, and current legislation. Technological innovations could greatly improve performance of the biodegradation facilities and

  14. Radiological, physical, and chemical characterization of additional alpha contaminated and mixed low-level waste for treatment at the advanced mixed waste treatment project

    SciTech Connect

    Hutchinson, D.P.

    1995-07-01

    This document provides physical, chemical, and radiological descriptive information for a portion of mixed waste that is potentially available for private sector treatment. The format and contents are designed to provide treatment vendors with preliminary information on the characteristics and properties for additional candidate portions of the Idaho National Engineering Laboratory (INEL) and offsite mixed wastes not covered in the two previous characterization reports for the INEL-stored low-level alpha-contaminated and transuranic wastes. This report defines the waste, provides background information, briefly reviews the requirements of the Federal Facility Compliance Act (P.L. 102-386), and relates the Site Treatment Plans developed under the Federal Facility Compliance Act to the waste streams described herein. Each waste is summarized in a Waste Profile Sheet with text, charts, and tables of waste descriptive information for a particular waste stream. A discussion of the availability and uncertainty of data for these waste streams precedes the characterization descriptions.

  15. Treatment of mixed radioactive liquid wastes at Argonne National Laboratory

    SciTech Connect

    Vandegrift, G.F.; Chamberlain, D.B.; Conner, C.

    1994-03-01

    Aqueous mixed waste at Argonne National Laboratory (ANL) is traditionally generated in small volumes with a wide variety of compositions. A cooperative effort at ANL between Waste Management (WM) and the Chemical Technology Division (CMT) was established, to develop, install, and implement a robust treatment operation to handle the majority of such wastes. For this treatment, toxic metals in mixed-waste solutions are precipitated in a semiautomated system using Ca(OH){sub 2} and, for some metals, Na{sub 2}S additions. This step is followed by filtration to remove the precipitated solids. A filtration skid was built that contains several filter types which can be used, as appropriate, for a variety of suspended solids. When supernatant liquid is separated from the toxic-metal solids by decantation and filtration, it will be a low-level waste (LLW) rather than a mixed waste. After passing a Toxicity Characteristic Leaching Procedure (TCLP) test, the solids may also be treated as LLW.

  16. Pilot studies to achieve waste minimization and enhance radioactive liquid waste treatment at the Los Alamos National Laboratory Radioactive Liquid Waste Treatment Facility

    SciTech Connect

    Freer, J.; Freer, E.; Bond, A.

    1996-07-01

    The Radioactive and Industrial Wastewater Science Group manages and operates the Radioactive Liquid Waste Treatment Facility (RLWTF) at the Los Alamos National Laboratory (LANL). The RLWTF treats low-level radioactive liquid waste generated by research and analytical facilities at approximately 35 technical areas throughout the 43-square-mile site. The RLWTF treats an average of 5.8 million gallons (21.8-million liters) of liquid waste annually. Clarifloculation and filtration is the primary treatment technology used by the RLWTF. This technology has been used since the RLWTF became operable in 1963. Last year the RLWTF achieved an average of 99.7% removal of gross alpha activity in the waste stream. The treatment process requires the addition of chemicals for the flocculation and subsequent precipitation of radionuclides. The resultant sludge generated during this process is solidified in drums and stored or disposed of at LANL.

  17. Toxic wastes treatment using different configurations of plasma torches

    NASA Astrophysics Data System (ADS)

    Torres, C.; Pacheco, J.; Pacheco, M.; Ramos, F.; Cruz, A.; Durán, M.; Hidalgo, M.

    2008-10-01

    Plasma technologies for waste treatment are rapidly emerging due to their effectiveness in destroying organic compounds, since they present a very high power density, enthalpy and chemical reactivity employed in the process. In this work, different configurations of plasma torches and their application in waste treatments are examined. The plasma discharge process was characterized by optical emission spectroscopy (OES) for obtaining some plasma parameters like temperature distribution in the plasma column. Efficiency in the waste degradation, for several experimental conditions, was also studied besides important electrical parameters normally linked to the mechanisms through which plasma discharge gains or loses energy are also presented. In addition, the principal characteristics of the plasma torch power supply are also described.

  18. Mixed and low-level waste treatment facility project

    SciTech Connect

    Not Available

    1992-04-01

    The technology information provided in this report is only the first step toward the identification and selection of process systems that may be recommended for a proposed mixed and low-level waste treatment facility. More specific information on each technology will be required to conduct the system and equipment tradeoff studies that will follow these preengineering studies. For example, capacity, maintainability, reliability, cost, applicability to specific waste streams, and technology availability must be further defined. This report does not currently contain all needed information; however, all major technologies considered to be potentially applicable to the treatment of mixed and low-level waste are identified and described herein. Future reports will seek to improve the depth of information on technologies.

  19. Sodium-Bearing Waste Treatment, Applied Technology Plan

    SciTech Connect

    Lance Lauerhass; Vince C. Maio; S. Kenneth Merrill; Arlin L. Olson; Keith J. Perry

    2003-06-01

    Settlement Agreement between the Department of Energy and the State of Idaho mandates treatment of sodium-bearing waste at the Idaho Nuclear Technology and Engineering Center within the Idaho National Engineering and Environmental Laboratory. One of the requirements of the Settlement Agreement is to complete treatment of sodium-bearing waste by December 31, 2012. Applied technology activities are required to provide the data necessary to complete conceptual design of four identified alternative processes and to select the preferred alternative. To provide a technically defensible path forward for the selection of a treatment process and for the collection of needed data, an applied technology plan is required. This document presents that plan, identifying key elements of the decision process and the steps necessary to obtain the required data in support of both the decision and the conceptual design. The Sodium-Bearing Waste Treatment Applied Technology Plan has been prepared to provide a description/roadmap of the treatment alternative selection process. The plan details the results of risk analyzes and the resulting prioritized uncertainties. It presents a high-level flow diagram governing the technology decision process, as well as detailed roadmaps for each technology. The roadmaps describe the technical steps necessary in obtaining data to quantify and reduce the technical uncertainties associated with each alternative treatment process. This plan also describes the final products that will be delivered to the Department of Energy Idaho Operations Office in support of the office's selection of the final treatment technology.

  20. 20. VIEW OF WASTE TREATMENT CONTROL ROOM IN BUILDING 374. ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    20. VIEW OF WASTE TREATMENT CONTROL ROOM IN BUILDING 374. THE BUILDING 371/374 COMPLEX WAS DESIGNED TO EMPHASIZE AUTOMATICALLY CONTROLLED, REMOTELY OPERATED PROCESSES. (1/80) - Rocky Flats Plant, Plutonium Recovery Facility, Northwest portion of Rocky Flats Plant, Golden, Jefferson County, CO

  1. Mine Waste Technology Program. Passive Treatment for Reducing Metal Loading

    EPA Science Inventory

    This report summarizes the results of Mine Waste Technology Program (MWTP) Activity III, Project 48, Passive Treatment Technology Evaluation for Reducing Metal Loading, funded by the U.S. Environmental Protection Agency (EPA) and jointly administered by EPA and the U.S. Departmen...

  2. An Analysis of the Waste Water Treatment Operator Occupation.

    ERIC Educational Resources Information Center

    Clark, Anthony B.; And Others

    The occupational analysis contains a brief job description for the waste water treatment occupations of operator and maintenance mechanic and 13 detailed task statements which specify job duties (tools, equipment, materials, objects acted upon, performance knowledge, safety considerations/hazards, decisions, cues, and errors) and learning skills…

  3. An Analysis of the Waste Water Treatment Maintenance Mechanic Occupation.

    ERIC Educational Resources Information Center

    Clark, Anthony B.; And Others

    The general purpose of the occupational analysis is to provide workable, basic information dealing with the many and varied duties performed in the waste water treatment mechanics occupation. The document opens with a brief introduction followed by a job description. The bulk of the document is presented in table form. Twelve duties are broken…

  4. BIOLOGICAL WASTE AIR TREATMENT IN BIOTRICKLING FILTERS. (R825392)

    EPA Science Inventory

    Abstract

    Recent studies in the area of biological waste air treatment in biotrickling filters have addressed fundamental key issues, such as biofilm architecture, microbiology of the process culture and means to control accumulation of biomass. The results from these s...

  5. 52. NORTHEASTERN EXTERIOR VIEW OF DOOROLIVER WAST WATER TREATMENT THICKENER ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    52. NORTHEASTERN EXTERIOR VIEW OF DOOR-OLIVER WAST WATER TREATMENT THICKENER No. 1. ELECTRIC POWERHOUSE No. 2 AND BLOW ENGINE HOUSE No. 3 IS IN THE BACKGROUND. (Jet Lowe) - U.S. Steel Duquesne Works, Blast Furnace Plant, Along Monongahela River, Duquesne, Allegheny County, PA

  6. 49. LOOKING NORTH AT EVAPORATIVE WASTE WATER TREATMENT COOLING TOWERS, ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    49. LOOKING NORTH AT EVAPORATIVE WASTE WATER TREATMENT COOLING TOWERS, WITH BLOW ENGINE HOUSE No. 3 ON RIGHT, AND FILTER CAKE HOUSE IN FOREGROUND. (Jet Lowe) - U.S. Steel Duquesne Works, Blast Furnace Plant, Along Monongahela River, Duquesne, Allegheny County, PA

  7. Treatment of Radioactive Organic Wastes by an Electrochemical Oxidation

    SciTech Connect

    Kim, K.H.; Ryue, Y.G.; Kwak, K.K.; Hong, K.P.; Kim, D.H.

    2007-07-01

    A waste treatment system by using an electrochemical oxidation (MEO, Mediated Electrochemical Oxidation) was installed at KAERI (Korea Atomic Energy Research Institute) for the treatment of radioactive organic wastes, especially EDTA (Ethylene Diamine Tetraacetic Acid) generated during the decontamination activity of nuclear installations. A cerium and silver mediated electrochemical oxidation technique method has been developed as an alternative for an incineration process. An experiment to evaluate the applicability of the above two processes and to establish the conditions to operate the pilot-scale system has been carried out by changing the concentration of the catalyst and EDTA, the operational current density, the operating temperature, and the electrolyte concentration. As for the results, silver mediated oxidation was more effective in destructing the EDTA wastes than the cerium mediated oxidation process. For a constant volume of the EDTA wastes, the treatment time for the cerium-mediated oxidation was 9 hours and its conversion ratio of EDTA to water and CO{sub 2} was 90.2 % at 80 deg. C, 10 A, but the treatment time for the silver-mediated oxidation was 3 hours and its conversion ratio was 89.2 % at 30 deg. C, 10 A. (authors)

  8. Steel wastes as versatile materials for treatment of biorefractory wastewaters.

    PubMed

    Dos Santos, Sara V; Amorim, Camila C; Andrade, Luiza N; Calixto, Natália C Z; Henriques, Andréia B; Ardisson, José D; Leão, Mônica M D

    2015-01-01

    Recent research on novel cost-effective adsorbent materials suggests potential use of industrial wastes for effluent treatment, with the added benefit of reuse of the wastes. Waste steel materials, including blast oxygen furnace sludge (BOFS), blast furnace sludge (BFS), and blast furnace dust (BFD), were investigated as low-cost adsorbents for removal of an oil emulsion and RR195 dye. The residues were characterized by X-ray diffraction, Brunauer-Emmett-Teller area, volume and distribution of pore diameters, Mössbauer spectroscopy, X-ray fluorescence, granulometry, scanning electron microscopy/energy dispersive spectroscopy, and pHpzc. Adsorption kinetics data were obtained by UV-vis spectrophotometry at the maximum absorption wavelength of the dye solution and crude oil emulsion. The use of waste as an adsorbent was more efficient for treatment of the oil emulsion than the dye solution. BOFS had higher total organic carbon (TOC) removal efficiency than the other waste materials. For the RR195 dye, good color removal was observed for all adsorbents, >90 % within 24 h. TOC removal was poor, <10 % for BFD and BFS and a maximum of 37 % for BOFS. For the oil emulsion, 97 % TOC removal was obtained by adsorption onto BOFS and 87 % onto BFS.

  9. Waste treatment at the Radiochemical Engineering Development Center

    SciTech Connect

    Brunson, R.R.; Bond, W.D.; Chattin, F.R.; Collins, R.T.; Sullivan, G.R.; Wiles, R.H.

    1997-12-31

    At the Radiochemical Engineering Development Center (REDC) irradiated targets are processed for the recovery of valuable radioisotopes, principally transuranium nuclides. A system was recently installed for treating the various liquid alkaline waste streams for removal of excess radioactive contaminants at the REDC. Radionuclides that are removed will be stored as solids and thus the future discharge of radionuclides to liquid low level waste tank storage will be greatly reduced. The treatment system is of modular design and is installed in a hot cell (Cubicle 7) in Building 7920 at the REDC where preliminary testing is in progress. The module incorporates the following: (1) a resorcinol-formaldehyde resin column for Cs removal, (2) a cross flow filtration unit for removal of rare earths and actinides as hydroxide, and (3) a waste solidification unit. Process flowsheets for operation of the module, key features of the module design, and its computer-assisted control system are presented. Good operability of the cross flow filter system is mandatory to the successful treatment of REDC wastes. Results of tests to date on the operation of the filter in its slurry collection mode and its slurry washing mode are presented. These tests include the effects of entrained organic solvent in the waste stream feed to the filter.

  10. Hazardous waste treatment using fungus enters marketplace

    SciTech Connect

    Illman, D.L.

    1993-07-01

    When the announcement was made eight years ago that a common fungus had been found that could degrade a variety of environmental pollutants, the news stirred interest in the scientific community, the private sector, and the general public. Here was the promise of a new technology that might be effective and economical in treating hazardous waste, especially the most recalcitrant of toxic pollutants. Today, commercialization is beginning amid a mixture of optimism and skepticism. The organism in question is white rot fungus, or Phanerochaete chrysosporium, and it belongs to a family of woodrotting fungi common all over North America. The fungi secrete enzymes that break down lignin in wood to carbon dioxide and water--a process called mineralization. These lignin-degrading enzymes are not very discriminating, however. The white rot fungi have been shown to degrade such materials as DDT, the herbicide (2,4,5-trichlorophenoxy)acetic acid (2,4,5-T), 2,4,6-trinitrotoluene (TNT), pentachlorophenol (PCP), creosote, coal tars, and heavy fuels, in many cases mineralizing these pollutants to a significant extent.

  11. [Yeasts in waste water from sewage treatment plants].

    PubMed

    Hinzelin, F; Lectard, P

    1979-11-30

    The authors have studied the influence of sewage treatment plants over the yeast population in the waste waters coming from towns. Quantitatively, the number of microorganisms shows a 90% decrease in the process of the treatment. 49 different species have been identified. Evidence of pollution coming from human being has been particularly looked for. The authors point out the different ways of detecting the Candida albicans.

  12. Comparative environmental analysis of waste brominated plastic thermal treatments

    SciTech Connect

    Bientinesi, M. Petarca, L.

    2009-03-15

    The aim of this research activity is to investigate the environmental impact of different thermal treatments of waste electric and electronic equipment (WEEE), applying a life cycle assessment methodology. Two scenarios were assessed, which both allow the recovery of bromine: (A) the co-combustion of WEEE and green waste in a municipal solid waste combustion plant, and (B) the staged-gasification of WEEE and combustion of produced syngas in gas turbines. Mass and energy balances on the two scenarios were set and the analysis of the life cycle inventory and the life cycle impact assessment were conducted. Two impact assessment methods (Ecoindicator 99 and Impact 2002+) were slightly modified and then used with both scenarios. The results showed that scenario B (staged-gasification) had a potentially smaller environmental impact than scenario A (co-combustion). In particular, the thermal treatment of staged-gasification was more energy efficient than co-combustion, and therefore scenario B performed better than scenario A, mainly in the impact categories of 'fossil fuels' and 'climate change'. Moreover, the results showed that scenario B allows a higher recovery of bromine than scenario A; however, Br recovery leads to environmental benefits for both the scenarios. Finally the study demonstrates that WEEE thermal treatment for energy and matter recovery is an eco-efficient way to dispose of this kind of waste.

  13. Radiological Monitoring of Waste Treatment Plant

    SciTech Connect

    Amin, Y. M.; Nik, H. W.

    2011-03-30

    Scheduled waste in West Malaysia is handled by Concession Company and is stored and then is incinerated. It is known that incineration process may result in naturally occurring radioactive materials (NORM) to be concentrated. In this study we have measured three samples consist of by-product from the operation process such as slag, filter cake and fly ash. Other various environmental media such as air, surface water, groundwater and soil within and around the plant have also been analysed for their radioactivity levels. The concentration of Ra-226, Ac-228 and K-40 in slag are 0.062 Bq/g, 0.016 Bq/g and 0.19 Bq/g respectively. The total activity (Ra{sub eq}) in slag is 99.5 Bq/kg. The concentration in fly ash is 0.032 Bq/g, 0.16 Bq/g and 0.34 Bq/g for Ra-226, Ac-228 and K-40 respectively resulting in Raeq of 287.0 Bq/kg. For filter cake, the concentration is 0.13 Bq/g, 0.031 Bq/g and 0.33 Bq/g for Ra-226, Ac-228 and K-40 respectively resulting in Raeq of 199.7 Bq/kg. The external radiation level ranges from 0.08 {mu}Sv/h (Administrative building) to 0.35 {mu}Sv/h (TENORM storage area). The concentration level of radon and thoron progeny varies from 0.0001 to 0.0016 WL and 0.0006 WL to 0.002 WL respectively. For soil samples, the activity ranges from 0.11 Bq/g to 0.29 Bq/g, 0.06 Bq/g to 0.18 Bq/g and 0.065 Bq/g to 0.38 Bq/g for Ra-226, Ac-228 and K-40 respectively. While activity in water, except for a trace of K-40, it is non-detectable.

  14. Development of glass vitrification at SRL as a waste treatment technique for nuclear weapon components

    SciTech Connect

    Coleman, J.T.; Bickford, D.F.

    1991-01-01

    This report discusses the development of vitrification for the waste treatment of nuclear weapons components at the Savannah River Site. Preliminary testing of surrogate nuclear weapon electronic waste shows that glass vitrification is a viable, robust treatment method.

  15. Development of glass vitrification at SRL as a waste treatment technique for nuclear weapon components

    SciTech Connect

    Coleman, J.T.; Bickford, D.F.

    1991-12-31

    This report discusses the development of vitrification for the waste treatment of nuclear weapons components at the Savannah River Site. Preliminary testing of surrogate nuclear weapon electronic waste shows that glass vitrification is a viable, robust treatment method.

  16. Remote handling equipment at the hanford waste treatment plant

    SciTech Connect

    Bardal, M.A.; Roach, J.D.

    2007-07-01

    Cold war plutonium production led to extensive amounts of radioactive waste stored in tanks at the Department of Energy's Hanford Waste Treatment Plant. The storage tanks could potentially leak into the ground water and into the Columbia River. The solution for this risk of the leaking waste is vitrification. Vitrification is a process of mixing molten glass with radioactive waste to form a stable condition for storage. The Department of Energy has contracted Bechtel National, Inc. to build facilities at the Hanford site to process the waste. The waste will be separated into high and low level waste. Four major systems will process the waste, two pretreatment and two high level. Due to the high radiation levels, high integrity custom cranes have been designed to remotely maintain the hot cells. Several critical design parameters were implemented into the remote machinery design, including radiation limitations, remote operations, Important to Safety features, overall equipment effectiveness, minimum wall approaches, seismic constraints, and recovery requirements. Several key pieces of equipment were designed to meet these design requirements - high integrity crane bridges, trolleys, main hoists, mast hoists, slewing hoists, a monorail hoist, and telescoping mast deployed tele-robotic manipulator arms. There were unique and challenging design features and equipment needed to provide the remotely operated high integrity crane/manipulator systems for the Hanford Waste Treatment Plant. The cranes consist of a double girder bridge with various main hoist capacities ranging from one to thirty ton and are used for performing routine maintenance. A telescoping mast mounted tele-robotic manipulator arm with a one-ton hook is deployed from the trolley to perform miscellaneous operations in-cell. A dual two-ton slewing jib hoist is mounted to the bottom of the trolley and rotates 360 degrees around the mast allowing the closest hook wall approaches. Each of the two hoists on

  17. Catalytic dry reforming of waste plastics from different waste treatment plants for production of synthesis gases.

    PubMed

    Saad, Juniza Md; Williams, Paul T

    2016-12-01

    Catalytic dry reforming of mixed waste plastics, from a range of different municipal, commercial and industrial sources, were processed in a two-stage fixed bed reactor. Pyrolysis of the plastics took place in the first stage and dry (CO2) reforming of the evolved pyrolysis gases took place in the second stage in the presence of Ni/Al2O3 and Ni-Co/Al2O3 catalysts in order to improve the production of syngas from the dry reforming process. The results showed that the highest amount of syngas yield was obtained from the dry reforming of plastic waste from the agricultural industry with the Ni/Al2O3 catalyst, producing 153.67mmolsyngasg(-1)waste. The addition of cobalt metal as a promoter to the Ni/Al2O3 catalyst did not have a major influence on syngas yield. Overall, the catalytic-dry reforming of waste plastics from various waste treatment plants showed great potential towards the production of synthesis gases.

  18. Approximate cost functions for solid waste treatment facilities.

    PubMed

    Tsilemou, Konstantinia; Panagiotakopoulos, Demetrios

    2006-08-01

    Cost estimation is a basic requirement for planning municipal solid waste management systems. The variety of organizational, financial and management schemes and the continuously developing technological advancements render the economic analysis a complex task, made more complex by the scarcity of real cost data. The objectives of this paper were: (1) to explore the problems arising in getting cost estimates from scattered and limited published data; (2) to suggest a procedure for generating cost functions relating initial set-up cost and operating cost with facility size; and (3) to present such cost functions, relevant to European states, for selected types of solid waste treatment and disposal facilities. Regarding the problems of available scarce data, one needs to deal with cost figures which correspond to facilities with variations in size, technology, year of construction, working conditions, level of technological automation, environmental impacts, social acceptance, capacity utilization rate, composition of inflowing waste, waste management policies, degree of compliance with quality standards, etc. The paper addresses this issue and discusses the proper use of statistical analyses in such cases of fragmented data; moreover, it points out some usual misuses of statistics by analysts and the danger of getting erroneous results. The suggested process for generating cost functions acceptable to the decision-makers is pivoted around the question of acceptable approximation level. Finally, approximate cost curves are suggested for waste-to-energy facilities, landfilling facilities, anaerobic digestion facilities and composting facilities.

  19. Characterization of the solid low level mixed waste inventory for the solid waste thermal treatment activity - III

    SciTech Connect

    Place, B.G., Westinghouse Hanford

    1996-09-24

    The existing thermally treatable, radioactive mixed waste inventory is characterized to support implementation of the commercial, 1214 thermal treatment contract. The existing thermally treatable waste inventory has been identified using a decision matrix developed by Josephson et al. (1996). Similar to earlier waste characterization reports (Place 1993 and 1994), hazardous materials, radionuclides, physical properties, and waste container data are statistically analyzed. In addition, the waste inventory data is analyzed to correlate waste constituent data that are important to the implementation of the commercial thermal treatment contract for obtaining permits and for process design. The specific waste parameters, which were analyzed, include the following: ``dose equivalent`` curie content, polychlorinated biphenyl (PCB) content, identification of containers with PA-related mobile radionuclides (14C, 12 79Se, 99Tc, and U isotopes), tritium content, debris and non-debris content, container free liquid content, fissile isotope content, identification of dangerous waste codes, asbestos containers, high mercury containers, beryllium dust containers, lead containers, overall waste quantities, analysis of container types, and an estimate of the waste compositional split based on the thermal treatment contractor`s proposed process. A qualitative description of the thermally treatable mixed waste inventory is also provided.

  20. 40 CFR 403.19 - Provisions of specific applicability to the Owatonna Waste Water Treatment Facility.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... the Owatonna Waste Water Treatment Facility. 403.19 Section 403.19 Protection of Environment... Owatonna Waste Water Treatment Facility. (a) For the purposes of this section, the term “Participating... Industrial User discharging to the Owatonna Waste Water Treatment Facility in Owatonna, Minnesota, when...

  1. 40 CFR 403.19 - Provisions of specific applicability to the Owatonna Waste Water Treatment Facility.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... the Owatonna Waste Water Treatment Facility. 403.19 Section 403.19 Protection of Environment... Owatonna Waste Water Treatment Facility. (a) For the purposes of this section, the term “Participating... Industrial User discharging to the Owatonna Waste Water Treatment Facility in Owatonna, Minnesota, when...

  2. 40 CFR 403.19 - Provisions of specific applicability to the Owatonna Waste Water Treatment Facility.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... the Owatonna Waste Water Treatment Facility. 403.19 Section 403.19 Protection of Environment... Owatonna Waste Water Treatment Facility. (a) For the purposes of this section, the term “Participating... Industrial User discharging to the Owatonna Waste Water Treatment Facility in Owatonna, Minnesota, when...

  3. 40 CFR 403.19 - Provisions of specific applicability to the Owatonna Waste Water Treatment Facility.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... to the Owatonna Waste Water Treatment Facility. 403.19 Section 403.19 Protection of Environment... Owatonna Waste Water Treatment Facility. (a) For the purposes of this section, the term “Participating... Industrial User discharging to the Owatonna Waste Water Treatment Facility in Owatonna, Minnesota, when...

  4. 40 CFR 403.19 - Provisions of specific applicability to the Owatonna Waste Water Treatment Facility.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... the Owatonna Waste Water Treatment Facility. 403.19 Section 403.19 Protection of Environment... Owatonna Waste Water Treatment Facility. (a) For the purposes of this section, the term “Participating... Industrial User discharging to the Owatonna Waste Water Treatment Facility in Owatonna, Minnesota, when...

  5. 40 CFR 721.10667 - Slimes and sludges, aluminum and iron casting, wastewater treatment, solid waste.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... casting, wastewater treatment, solid waste. 721.10667 Section 721.10667 Protection of Environment... iron casting, wastewater treatment, solid waste. (a) Chemical substance and significant new uses... and iron casting, wastewater treatment, solid waste (PMN P-12-560; CAS No. 1391739-82-4;...

  6. 40 CFR 721.10667 - Slimes and sludges, aluminum and iron casting, wastewater treatment, solid waste.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... casting, wastewater treatment, solid waste. 721.10667 Section 721.10667 Protection of Environment... iron casting, wastewater treatment, solid waste. (a) Chemical substance and significant new uses... and iron casting, wastewater treatment, solid waste (PMN P-12-560; CAS No. 1391739-82-4;...

  7. Raw Liquid Waste Treatment System and Process

    NASA Technical Reports Server (NTRS)

    Humphrey, M. F. (Inventor)

    1974-01-01

    A raw sewage treatment process is disclosed in which substantially all the non-dissolved matter, suspended in the sewage water is first separated from the water, in which at least organic matter remains dissolved. The non-dissolved material is pyrolyzed to form an activated carbon and ash material without the addition of any conditioning agents. The activated carbon and ash material is added to the water from which the non-dissolved matter was removed. The activated carbon and ash material adsorbs the organic matter dissolved in the water and is thereafter supplied in a counter flow direction and combined with the incoming raw sewage to at least facilitate the separation of the non-dissolved settleable materials from the sewage water. Carbon and ash material together with the non-dissolved matter which was separated from the sewage water are pyrolyzed to form the activated carbon and ash material.

  8. Waste Water Treatment Apparatus and Methods

    NASA Technical Reports Server (NTRS)

    Littman, Howard (Inventor); Plawsky, Joel L. (Inventor); Paccione, John D. (Inventor)

    2014-01-01

    An improved draft tube spout fluid bed (DTSFB) mixing, handling, conveying, and treating apparatus and systems, and methods for operating are provided. The apparatus and systems can accept particulate material and pneumatically or hydraulically conveying the material to mix and/or treat the material. In addition to conveying apparatus, a collection and separation apparatus adapted to receive the conveyed particulate material is also provided. The collection apparatus may include an impaction plate against which the conveyed material is directed to improve mixing and/or treatment. The improved apparatus are characterized by means of controlling the operation of the pneumatic or hydraulic transfer to enhance the mixing and/or reacting by controlling the flow of fluids, for example, air, into and out of the apparatus. The disclosed apparatus may be used to mix particulate material, for example, mortar; react fluids with particulate material; coat particulate material, or simply convey particulate material.

  9. Hazardous Waste/Mixed Waste Treatment Building Safety Information Document (SID)

    SciTech Connect

    Fatell, L.B.; Woolsey, G.B.

    1993-04-15

    This Safety Information Document (SID) provides a description and analysis of operations for the Hazardous Waste/Mixed Waste Disposal Facility Treatment Building (the Treatment Building). The Treatment Building has been classified as a moderate hazard facility, and the level of analysis performed and the methodology used are based on that classification. Preliminary design of the Treatment Building has identified the need for two separate buildings for waste treatment processes. The term Treatment Building applies to all these facilities. The evaluation of safety for the Treatment Building is accomplished in part by the identification of hazards associated with the facility and the analysis of the facility`s response to postulated events involving those hazards. The events are analyzed in terms of the facility features that minimize the causes of such events, the quantitative determination of the consequences, and the ability of the facility to cope with each event should it occur. The SID presents the methodology, assumptions, and results of the systematic evaluation of hazards associated with operation of the Treatment Building. The SID also addresses the spectrum of postulated credible events, involving those hazards, that could occur. Facility features important to safety are identified and discussed in the SID. The SID identifies hazards and reports the analysis of the spectrum of credible postulated events that can result in the following consequences: Personnel exposure to radiation; Radioactive material release to the environment; Personnel exposure to hazardous chemicals; Hazardous chemical release to the environment; Events leading to an onsite/offsite fatality; and Significant damage to government property. The SID addresses the consequences to the onsite and offsite populations resulting from postulated credible events and the safety features in place to control and mitigate the consequences.

  10. Treatment technology analysis for mixed waste containers and debris

    SciTech Connect

    Gehrke, R.J.; Brown, C.H.; Langton, C.A.; Askew, N.M.; Kan, T.; Schwinkendorf, W.E.

    1994-03-01

    A team was assembled to develop technology needs and strategies for treatment of mixed waste debris and empty containers in the Department of Energy (DOE) complex, and to determine the advantages and disadvantages of applying the Debris and Empty Container Rules to these wastes. These rules issued by the Environmental Protection Agency (EPA) apply only to the hazardous component of mixed debris. Hazardous debris that is subjected to regulations under the Atomic Energy Act because of its radioactivity (i.e., mixed debris) is also subject to the debris treatment standards. The issue of treating debris per the Resource Conservation and Recovery Act (RCRA) at the same time or in conjunction with decontamination of the radioactive contamination was also addressed. Resolution of this issue requires policy development by DOE Headquarters of de minimis concentrations for radioactivity and release of material to Subtitle D landfills or into the commercial sector. The task team recommends that, since alternate treatment technologies (for the hazardous component) are Best Demonstrated Available Technology (BDAT): (1) funding should focus on demonstration, testing, and evaluation of BDAT on mixed debris, (2) funding should also consider verification of alternative treatments for the decontamination of radioactive debris, and (3) DOE should establish criteria for the recycle/reuse or disposal of treated and decontaminated mixed debris as municipal waste.

  11. Sodium Recycle Economics for Waste Treatment Plant Operations

    SciTech Connect

    Sevigny, Gary J.; Poloski, Adam P.; Fountain, Matthew S.

    2008-08-31

    Sodium recycle at the Hanford Waste Treatment Plant (WTP) would reduce the number of glass canisters produced, and has the potential to significantly reduce the cost to the U.S. Department of Energy (DOE) of treating the tank wastes by hundreds of millions of dollars. The sodium, added in the form of sodium hydroxide, was originally added to minimize corrosion of carbon-steel storage tanks from acidic reprocessing wastes. In the baseline Hanford treatment process, sodium hydroxide is required to leach gibbsite and boehmite from the high level waste (HLW) sludge. In turn, this reduces the amount of HLW glass produced. Currently, a significant amount of additional sodium hydroxide will be added to the process to maintain aluminate solubility at ambient temperatures during ion exchange of cesium. The vitrification of radioactive waste is limited by sodium content, and this additional sodium mass will increase low-activity waste-glass mass. An electrochemical salt-splitting process, based on sodium-ion selective ceramic membranes, is being developed to recover and recycle sodium hydroxide from high-salt radioactive tank wastes in DOE’s complex. The ceramic membranes are from a family of materials known as sodium (Na)—super-ionic conductors (NaSICON)—and the diffusion of sodium ions (Na+) is allowed, while blocking other positively charged ions. A cost/benefit evaluation was based on a strategy that involves a separate caustic-recycle facility based on the NaSICON technology, which would be located adjacent to the WTP facility. A Monte Carlo approach was taken, and several thousand scenarios were analyzed to determine likely economic results. The cost/benefit evaluation indicates that 10,000–50,000 metric tons (MT) of sodium could be recycled, and would allow for the reduction of glass production by 60,000–300,000 MT. The cost of the facility construction and operation was scaled to the low-activity waste (LAW) vitrification facility, showing cost would be

  12. Estimation of marginal costs at existing waste treatment facilities.

    PubMed

    Martinez-Sanchez, Veronica; Hulgaard, Tore; Hindsgaul, Claus; Riber, Christian; Kamuk, Bettina; Astrup, Thomas F

    2016-04-01

    address and include costs in existing waste facilities in decision-making may unintendedly lead to higher overall costs at societal level. To avoid misleading conclusions, economic assessment of alternative SWM solutions should not only consider potential costs associated with alternative treatment but also include marginal costs associated with existing facilities.

  13. Overview of non-thermal mixed waste treatment technologies: Treatment of mixed waste (ex situ); Technologies and short descriptions

    SciTech Connect

    1995-07-01

    This compendium contains brief summaries of new and developing non- thermal treatment technologies that are candidates for treating hazardous or mixed (hazardous plus low-level radioactive) wastes. It is written to be all-encompassing, sometimes including concepts that presently constitute little more than informed ``ideas``. It bounds the universe of existing technologies being thought about or considered for application on the treatment of such wastes. This compendium is intended to be the very first step in a winnowing process to identify non-thermal treatment systems that can be fashioned into complete ``cradle-to-grave`` systems for study. The purpose of the subsequent systems paper studies is to investigate the cost and likely performance of such systems treating a representative sample of U.S. Department of Energy (DOE) mixed low level wastes (MLLW). The studies are called Integrated Non-thermal Treatment Systems (INTS) Studies and are being conducted by the Office of Science and Technology (OST) of the Environmental Management (EM) of the US Department of Energy. Similar studies on Integrated Thermal Treatment Systems have recently been published. These are not designed nor intended to be a ``downselection`` of such technologies; rather, they are simply a systems evaluation of the likely costs and performance of various non- thermal technologies that have been arranged into systems to treat sludges, organics, metals, soils, and debris prevalent in MLLW.

  14. HIGH ALUMINUM HLW (HIGH LEVEL WASTE ) GLASSES FOR HANFORDS WTP (WASTE TREATMENT PROJECT)

    SciTech Connect

    KRUGER AA; BOWAN BW; JOSEPH I; GAN H; KOT WK; MATLACK KS; PEGG IL

    2010-01-04

    This paper presents the results of glass formulation development and melter testing to identify high waste loading glasses to treat high-Al high level waste (HLW) at Hanford. Previous glass formulations developed for this HLW had high waste loadings but their processing rates were lower that desired. The present work was aimed at improving the glass processing rate while maintaining high waste loadings. Glass formulations were designed, prepared at crucible-scale and characterized to determine their properties relevant to processing and product quality. Glass formulations that met these requirements were screened for melt rates using small-scale tests. The small-scale melt rate screening included vertical gradient furnace (VGF) and direct feed consumption (DFC) melter tests. Based on the results of these tests, modified glass formulations were developed and selected for larger scale melter tests to determine their processing rate. Melter tests were conducted on the DuraMelter 100 (DMIOO) with a melt surface area of 0.11 m{sup 2} and the DuraMelter 1200 (DMI200) HLW Pilot Melter with a melt surface area of 1.2 m{sup 2}. The newly developed glass formulations had waste loadings as high as 50 wt%, with corresponding Al{sub 2}O{sub 3} concentration in the glass of 26.63 wt%. The new glass formulations showed glass production rates as high as 1900 kg/(m{sup 2}.day) under nominal melter operating conditions. The demonstrated glass production rates are much higher than the current requirement of 800 kg/(m{sup 2}.day) and anticipated future enhanced Hanford Tank Waste Treatment and Immobilization Plant (WTP) requirement of 1000 kg/(m{sup 2}.day).

  15. Treatment of waste printed wire boards in electronic waste for safe disposal.

    PubMed

    Niu, Xiaojun; Li, Yadong

    2007-07-16

    The printed wire boards (PWBs) in electronic waste (E-waste) have been found to contain large amounts of toxic substances. Studies have concluded that the waste PWBs are hazardous wastes because they fails the toxicity characteristic leaching procedure (TCLP) test with high level of lead (Pb) leaching out. In this study, two treatment methods - high-pressure compaction and cement solidification - were explored for rendering the PWBs into non-hazardous forms so that they may be safely disposed or used. The high-pressure compaction method could turn the PWBs into high-density compacts with significant volume reduction, but the impact resistance of the compacts was too low to keep them intact in the environment for a long run. In contrast, the cement solidification could turn the PWBs into strong monoliths with high impact resistance and relatively high compressive strength. The leaching of the toxic heavy metal Pb from the solidified samples was evaluated by both a dynamic leaching test and the TCLP test. The dynamic leaching results revealed that Pb could be effectively confined in the solidified products under very harsh environmental conditions. The TCLP test results showed that the leaching level of Pb was far below the regulatory level of 5mg/L, suggesting that the solidified PWBs are no longer hazardous. It was concluded that the cement solidification is an effective way to render the waste PWBs into environmentally benign forms so that they can be disposed of as ordinary solid wastes or beneficially used in the place of concrete in some applications.

  16. Treatment of waste thermal waters by ozonation and nanofiltration.

    PubMed

    Kiss, Z L; Szép, A; Kertész, S; Hodúr, C; László, Z

    2013-01-01

    After their use for heating, e.g. in greenhouses, waste thermal waters may cause environmental problems due to their high contents of ions, and in some cases organic matter (associated with an oxygen demand) or toxic compounds. The aims of this work were to decrease the high organic content of waste thermal water by a combination of ozone treatment and membrane separation, and to investigate the accompanying membrane fouling. The results demonstrated that the chemical oxygen demand and the total organic content can be effectively decreased by a combination of ozone pretreatment and membrane filtration. Ozone treatment is more effective for phenol elimination than nanofiltration alone: with a combination of the two processes, 100% elimination efficiency can be achieved. The fouling index b proved to correlate well with the fouling and polarization layer resistances.

  17. Hazardous solid waste from domestic wastewater treatment plants.

    PubMed Central

    Harrington, W M

    1978-01-01

    The treatment of liquid wastes in municipal sewage treatment plants creates significant quantities of solid residue for disposal. The potential hazard from these wastes requires that their characteristics be determined accurately to develop environmentally sound management criteria. It is readily recognized that the sludge characteristics vary with the type and degree of industrial activity within a wastewater collection system and that these characteristics play a significant role in determining whether the material has potential for beneficial reuse or if it must be directed to final disposal. This paper offers an overview of past and present practices of sewage sludge disposal, an indication of quantities produced, and experience with beneficial reuse. An estimated range of costs involved, expected environmental effects and potential for continued use is offered for each disposal or reuse system discussed. PMID:738239

  18. CHARACTERIZATION OF DEFENSE NUCLEAR WASTE USING HAZARDOUS WASTE GUIDANCE. APPLICATIONS TO HANFORD SITE ACCELERATED HIGH-LEVEL WASTE TREATMENT AND DISPOSAL MISSION0

    SciTech Connect

    Hamel, William; Huffman, Lori; Lerchen, Megan; Wiemers, Karyn

    2003-02-27

    Federal hazardous waste regulations were developed for management of industrial waste. These same regulations are also applicable for much of the nation's defense nuclear wastes. At the U.S. Department of Energy's (DOE) Hanford Site in southeast Washington State, one of the nation's largest inventories of nuclear waste remains in storage in large underground tanks. The waste's regulatory designation and its composition and form constrain acceptable treatment and disposal options. Obtaining detailed knowledge of the tank waste composition presents a significant portion of the many challenges in meeting the regulatory-driven treatment and disposal requirements for this waste. Key in applying the hazardous waste regulations to defense nuclear wastes is defining the appropriate and achievable quality for waste feed characterization data and the supporting evidence demonstrating that applicable requirements have been met at the time of disposal. Application of a performance-based approach to demonstrating achievable quality standards will be discussed in the context of the accelerated high-level waste treatment and disposal mission at the Hanford Site.

  19. US - European Workshop on Thermal Waste Treatment for Naval Vessels

    DTIC Science & Technology

    1997-01-01

    CONCEPT PROCESS ENERGY CARRIER Biological Heat Anaerobic Biogas conversion Bg digestion Boa Starved I Low quality Ar d Gasification syngas 4.11 MJIm3...Hazardous Materials by Dan D. Jensen, General Atomics, USA d. Hydrothermal Conversion of Wastes by Frangois Cansell, University of Bordeaux, France 2...Supercritical Water Oxidation for the On-Board Treatment of Naval Excess Hazardous Materials by Dan D. Jensen, General Atomics, USA 16.45-17.30 Hydrothermal

  20. Fate of metals contained in waste electrical and electronic equipment in a municipal waste treatment process

    SciTech Connect

    Oguchi, Masahiro; Sakanakura, Hirofumi; Terazono, Atsushi; Takigami, Hidetaka

    2012-01-15

    Highlights: Black-Right-Pointing-Pointer The fate of 55 metals during shredding and separation of WEEE was investigated. Black-Right-Pointing-Pointer Most metals were mainly distributed to the small-grain fraction. Black-Right-Pointing-Pointer Much of metals in WEEE being treated as municipal waste in Japan end up in landfills. Black-Right-Pointing-Pointer Pre-sorting of small digital products reduces metals to be landfilled at some level. Black-Right-Pointing-Pointer Consideration of metal recovery from other middle-sized WEEE is still important. - Abstract: In Japan, waste electrical and electronic equipment (WEEE) that is not covered by the recycling laws are treated as municipal solid waste. A part of common metals are recovered during the treatment; however, other metals are rarely recovered and their destinations are not clear. This study investigated the distribution ratios and substance flows of 55 metals contained in WEEE during municipal waste treatment using shredding and separation techniques at a Japanese municipal waste treatment plant. The results revealed that more than half of Cu and most of Al contained in WEEE end up in landfills or dissipate under the current municipal waste treatment system. Among the other metals contained in WEEE, at least 70% of the mass was distributed to the small-grain fraction through the shredding and separation and is to be landfilled. Most kinds of metals were concentrated several fold in the small-grain fraction through the process and therefore the small-grain fraction may be a next target for recovery of metals in terms of both metal content and amount. Separate collection and pre-sorting of small digital products can work as effective way for reducing precious metals and less common metals to be landfilled to some extent; however, much of the total masses of those metals would still end up in landfills and it is also important to consider how to recover and utilize metals contained in other WEEE such as audio

  1. Karlsruhe Database for Radioactive Wastes (KADABRA) - Accounting and Management System for Radioactive Waste Treatment - 12275

    SciTech Connect

    Himmerkus, Felix; Rittmeyer, Cornelia

    2012-07-01

    The data management system KADABRA was designed according to the purposes of the Cen-tral Decontamination Department (HDB) of the Wiederaufarbeitungsanlage Karlsruhe Rueckbau- und Entsorgungs-GmbH (WAK GmbH), which is specialized in the treatment and conditioning of radioactive waste. The layout considers the major treatment processes of the HDB as well as regulatory and legal requirements. KADABRA is designed as an SAG ADABAS application on IBM system Z mainframe. The main function of the system is the data management of all processes related to treatment, transfer and storage of radioactive material within HDB. KADABRA records the relevant data concerning radioactive residues, interim products and waste products as well as the production parameters relevant for final disposal. Analytical data from the laboratory and non destructive assay systems, that describe the chemical and radiological properties of residues, production batches, interim products as well as final waste products, can be linked to the respective dataset for documentation and declaration. The system enables the operator to trace the radioactive material through processing and storage. Information on the actual sta-tus of the material as well as radiological data and storage position can be gained immediately on request. A variety of programs accessed to the database allow the generation of individual reports on periodic or special request. KADABRA offers a high security standard and is constantly adapted to the recent requirements of the organization. (authors)

  2. Leucine as a treatment for muscle wasting: a critical review.

    PubMed

    Ham, Daniel J; Caldow, Marissa K; Lynch, Gordon S; Koopman, René

    2014-12-01

    Amino acids are potent modulators of protein turnover and skeletal muscle cells are highly sensitive to changes in amino acid availability. During amino acid abundance increased activity of mTORC1 drives protein synthesis and growth. In skeletal muscle, it has been clearly demonstrated that of all the amino acids, leucine is the most potent stimulator of mTORC1 and protein synthesis in vitro and in vivo. As such, leucine has received considerable attention as a potential pharmaconutrient for the treatment of numerous muscle wasting conditions. However, despite a multitude of studies showing enhanced acute protein synthesis with leucine or leucine-rich supplements in healthy individuals, additional leucine intake does not necessarily enhance protein synthesis during muscle wasting conditions. In addition, long-term, placebo controlled, iso-caloric studies in humans consistently show no beneficial effect of leucine supplementation on skeletal muscle mass or function. This review, critically evaluates the therapeutic potential of leucine to attenuate the skeletal muscle wasting associated with ageing, cancer and immobilization/bed rest. It also highlights the impact of inflammation on amino acid sensing, mTORC1 activation and stimulation of protein synthesis and challenges the underlying hypothesis that the acute activation of mTORC1 and stimulation of protein synthesis by leucine increases in muscle mass over time. We conclude that leucine, as a standalone nutritional intervention, is not effective in the prevention of muscle wasting. Future work should focus on identifying and utilizing other nutrients or treatments that sensitize skeletal muscle to leucine, thereby enhancing its therapeutic potential for muscle wasting conditions.

  3. Stabilization Using Phosphate Bonded Ceramics. Salt Containing Mixed Waste Treatment. Mixed Waste Focus Area. OST Reference No. 117

    SciTech Connect

    None, None

    1999-09-01

    Throughout the Department of Energy (DOE) complex there are large inventories of homogeneous mixed waste solids, such as wastewater treatment residues, fly ashes, and sludges that contain relatively high concentrations (greater than 15% by weight) of salts. The inherent solubility of salts (e.g., nitrates, chlorides, and sulfates) makes traditional treatment of these waste streams difficult, expensive, and challenging. One alternative is low-temperature stabilization by chemically bonded phosphate ceramics (CBPCs). The process involves reacting magnesium oxide with monopotassium phosphate with the salt waste to produce a dense monolith. The ceramic makes a strong environmental barrier, and the metals are converted to insoluble, low-leaching phosphate salts. The process has been tested on a variety of surrogates and actual mixed waste streams, including soils, wastewater, flyashes, and crushed debris. It has also been demonstrated at scales ranging from 5 to 55 gallons. In some applications, the CBPC technology provides higher waste loadings and a more durable salt waste form than the baseline method of cementitious grouting. Waste form test specimens were subjected to a variety of performance tests. Results of waste form performance testing concluded that CBPC forms made with salt wastes meet or exceed both RCRA and recommended Nuclear Regulatory Commission (NRC) low-level waste (LLW) disposal criteria. Application of a polymer coating to the CBPC may decrease the leaching of salt anions, but continued waste form evaluations are needed to fully assess the deteriorating effects of this leaching, if any, over time.

  4. Radioactive Bench-scale Steam Reformer Demonstration of a Monolithic Steam Reformed Mineralized Waste Form for Hanford Waste Treatment Plant Secondary Waste - 12306

    SciTech Connect

    Evans, Brent; Olson, Arlin; Mason, J. Bradley; Ryan, Kevin; Jantzen, Carol; Crawford, Charles

    2012-07-01

    Hanford currently has 212,000 m{sup 3} (56 million gallons) of highly radioactive mixed waste stored in the Hanford tank farm. This waste will be processed to produce both high-level and low-level activity fractions, both of which are to be vitrified. Supplemental treatment options have been under evaluation for treating portions of the low-activity waste, as well as the liquid secondary waste from the low-activity waste vitrification process. One technology under consideration has been the THOR{sup R} fluidized bed steam reforming process offered by THOR Treatment Technologies, LLC (TTT). As a follow-on effort to TTT's 2008 pilot plant FBSR non-radioactive demonstration for treating low-activity waste and waste treatment plant secondary waste, TTT, in conjunction with Savannah River National Laboratory, has completed a bench scale evaluation of this same technology on a chemically adjusted radioactive surrogate of Hanford's waste treatment plant secondary waste stream. This test generated a granular product that was subsequently formed into monoliths, using a geo-polymer as the binding agent, that were subjected to compressibility testing, the Product Consistency Test and other leachability tests, and chemical composition analyses. This testing has demonstrated that the mineralized waste form, produced by co-processing waste with kaolin clay using the TTT process, is as durable as low-activity waste glass. Testing has shown the resulting monolith waste form is durable, leach resistant, and chemically stable, and has the added benefit of capturing and retaining the majority of Tc-99, I-129, and other target species at high levels. (authors)

  5. Low level mixed waste thermal treatment technical basis report

    SciTech Connect

    Place, B.G.

    1994-12-01

    Detailed characterization of the existing and projected Hanford Site Radioactive Mixed Waste (RMW) inventory was initiated in 1993 (Place 1993). This report presents an analysis of the existing and projected RMW inventory. The subject characterization effort continues to be in support of the following engineering activities related to thermal treatment of Hanford Site RMW: (1) Contracting for commercial thermal treatment; (2) Installation and operation of an onsite thermal treatment facility (Project W-242); (3) Treatment at another Department of Energy (DOE) site. The collation of this characterization information (data) has emphasized the establishment of a common data base for the entire existing RMW inventory so that the specification of feed streams destined for different treatment facilities can be coordinated.

  6. Secondary Low-Level Waste Treatment Strategy Analysis

    SciTech Connect

    D.M. LaRue

    1999-05-25

    The objective of this analysis is to identify and review potential options for processing and disposing of the secondary low-level waste (LLW) that will be generated through operation of the Monitored Geologic Repository (MGR). An estimate of annual secondary LLW is generated utilizing the mechanism established in ''Secondary Waste Treatment Analysis'' (Reference 8.1) and ''Secondary Low-Level Waste Generation Rate Analysis'' (Reference 8.5). The secondary LLW quantities are based on the spent fuel and high-level waste (HLW) arrival schedule as defined in the ''Controlled Design Assumptions Document'' (CDA) (Reference 8.6). This analysis presents estimates of the quantities of LLW in its various forms. A review of applicable laws, codes, and standards is discussed, and a synopsis of those applicable laws, codes, and standards and their impacts on potential processing and disposal options is presented. The analysis identifies viable processing/disposal options in light of the existing laws, codes, and standards, and then evaluates these options in regard to: (1) Process and equipment requirements; (2) LLW disposal volumes; and (3) Facility requirements.

  7. Treatment of Difficult Wastes with Molten Salt Oxidation

    SciTech Connect

    Hsu, P C; Kwak, S

    2003-02-21

    Molten salt oxidation (MSO) is a good alternative to incineration for the treatment of a variety of organic wastes such as explosives, low-level mixed waste streams, PCB contaminated oils, spent resins and carbon. Since mid-1990s, the U.S. Army Defense Ammunition Center (DAC) and the Department of Energy (DOE) have jointly invested in MSO development at the Lawrence Livermore National Laboratory (LLNL). LLNL first demonstrated the MSO process for the effective destruction of explosives, explosives-contaminated materials, and other wastes on a 1.5-kg/hr bench-scale unit, and then in an integrated MSO facility capable of treating 8 kg/hr of low-level radioactive mixed wastes. Several MSO systems have been built with sizes up to 10 ft in height and 16 inches in diameter. LLNL in 2001 completed a MSO plant for DAC for the destruction of explosives-contaminated sludge and explosives-contaminated carbon. We will present in this paper our latest demonstration data and our operational experience with MSO.

  8. Thermal plasma technology for the treatment of wastes: a critical review.

    PubMed

    Gomez, E; Rani, D Amutha; Cheeseman, C R; Deegan, D; Wise, M; Boccaccini, A R

    2009-01-30

    This review describes the current status of waste treatment using thermal plasma technology. A comprehensive analysis of the available scientific and technical literature on waste plasma treatment is presented, including the treatment of a variety of hazardous wastes, such as residues from municipal solid waste incineration, slag and dust from steel production, asbestos-containing wastes, health care wastes and organic liquid wastes. The principles of thermal plasma generation and the technologies available are outlined, together with potential applications for plasma vitrified products. There have been continued advances in the application of plasma technology for waste treatment, and this is now a viable alternative to other potential treatment/disposal options. Regulatory, economic and socio-political drivers are promoting adoption of advanced thermal conversion techniques such as thermal plasma technology and these are expected to become increasingly commercially viable in the future.

  9. STATUS OF EPA/DOE MOU TECHNICAL WORKGROUP ACTIVITIES: HG WASTE TREATMENT

    EPA Science Inventory

    EPA's Land Disposal Restrictions program currently has technology-specific treatment standards for hazardous wastes containing greater than or equal to 260ppm total mercury (Hg) (i.e., high Hg subcategory wastes). The treatment standards specify RMERC for high Hg subcategory wast...

  10. Implementation of Treatment Systems for Low and Intermediate Radioactive Waste at Site Radwaste Treatment Facility (SRTF), PR China - 12556

    SciTech Connect

    Lohmann, Peter; Nasarek, Ralph; Aign, Joerg

    2012-07-01

    The AP1000 reactors being built in the People's Republic of China require a waste treatment facility to process the low and intermediate radioactive waste produced by these nuclear power stations. Westinghouse Electric Germany GmbH was successful in being awarded a contract as to the planning, delivery and commissioning of such a waste treatment facility. The Site Radwaste Treatment Facility (SRTF) is a waste treatment facility that can meet the AP1000 requirements and it will become operational in the near future. The SRTF is situated at the location of Sanmen, People's Republic of China, next to one of the AP1000 and is an adherent building to the AP1000 comprising different waste treatment processes for radioactive spent filter cartridges, ion-exchange resins and radioactive liquid and solid waste. The final product of the SRTF-treatment is a 200 l drum with cemented waste or grouted waste packages for storage in a local storage facility. The systems used in the SRTF are developed for these special requirements, based on experience from similar systems in the German nuclear industry. The main waste treatment systems in the SRTF are: - Filter Cartridge Processing System (FCS); - HVAC-Filter and Solid Waste Treatment Systems (HVS); - Chemical Liquid Treatment Systems (CTS); - Spent Resin Processing Systems (RES); - Mobile Treatment System (MBS). (authors)

  11. On-Line Learning Modules For Waste Treatment, Waste Disposal and Waste Recycling

    NASA Astrophysics Data System (ADS)

    O'Callaghan, Paul; Soos, Lubomir; Brokes, Peter

    2011-12-01

    This contribution is devoted to the development of an advanced vocational education and training system for professionals working in (or intending to enter) the waste management industry realized through the Leonardo project WASTRE. The consortium of the Project WASTRE includes 3 well known Technical Universities in Central Europe (TU Vienna, CVUT Prague and STU Bratislava). The project implements new didactical tools from projects EDUET, ELEVATE, RESNET and MENUET developed by MultiMedia SunShine, headed by Prof. Paul Callaghan for this education and training system. This system will be tested within courses organized by at least 3 institutions of vocational education and training: the Technical and vocational secondary school Tlmace, CHEWCON Humenne and the Union of Chambers of Craftsmen and Tradesmen of ESKISEHIR. The faculty of Mechanical Engineering (FME) of STU will coordinate the project WASTRE and will participate in the preparation of e-learning materials, organization of the courses and in the design of syllabuses, curricula, assessment and evaluation methods for the courses, the testing of developed learning materials, evaluating experiences from a pilot course and developing the e-learning materials according to the needs of end-users.

  12. Treatment Technologies for Hazardous Ashes Generated from Possible Incineration of Navy Waste

    DTIC Science & Technology

    1990-10-01

    Hazardous and Solid Waste Amendments of 1984 HW - Hazardous Waste HWM - Hazardous Waste Minimization IWTP - Industrial wastewater treatment piant...Resource Conservation and Recovery Act of 1976 (RCRA) and the Hazardous and Solid Waste Amendments of 1984 (HSWA) will eventually prohibit land disposal of...Conservation and Recovery Act of 1976, as amended, PL 94-580, 42 USC 6901. 3. Hazardous and Solid Waste Amendments

  13. Treatment of oilfield produced water by waste stabilization ponds.

    PubMed

    Shpiner, R; Vathi, S; Stuckey, D C

    2007-01-01

    Produced water (PW) from oil wells can serve as an alternative water resource for agriculture if the main pollutants (hydrocarbons and heavy metals) can be removed to below irrigation standards. Waste stabilization ponds seem like a promising solution for PW treatment, especially in the Middle East where solar radiation is high and land is available. In this work, hydrocarbon removal from PW in a biological waste stabilization pond was examined at lab-scale followed by an intermittent slow sand filter. The system was run for 300 days and removed around 90% of the oil in the pond, and 95% after the sand filter. COD removal was about 80% in the pond effluent, and 85% after the filter. The system was tested under various operational modes and found to be stable to shock loads. Installation of oil booms and decantation of surface oil seem to be important in order to maintain good system performance over time.

  14. Advancements in stem cells treatment of skeletal muscle wasting

    PubMed Central

    Meregalli, Mirella; Farini, Andrea; Sitzia, Clementina; Torrente, Yvan

    2014-01-01

    Muscular dystrophies (MDs) are a heterogeneous group of inherited disorders, in which progressive muscle wasting and weakness is often associated with exhaustion of muscle regeneration potential. Although physiological properties of skeletal muscle tissue are now well known, no treatments are effective for these diseases. Muscle regeneration was attempted by means transplantation of myogenic cells (from myoblast to embryonic stem cells) and also by interfering with the malignant processes that originate in pathological tissues, such as uncontrolled fibrosis and inflammation. Taking into account the advances in the isolation of new subpopulation of stem cells and in the creation of artificial stem cell niches, we discuss how these emerging technologies offer great promises for therapeutic approaches to muscle diseases and muscle wasting associated with aging. PMID:24575052

  15. Greenhouse gas emissions from mechanical and biological waste treatment of municipal waste.

    PubMed

    Clemens, J; Cuhls, C

    2003-06-01

    The mechanical and biological waste treatment (MBT) is an increasingly important technology for the treatment of municipal solid waste (MSW) before landfilling. This process includes composting of the material with intensive aeration in order to minimize the organic fraction that may induce methane and leachate emissions after landfilling. The exhaust air is treated by biofilters to remove odorous and volatile organic compounds. The emission of direct and indirect greenhouse gases, namely methane (CH4), carbon dioxide (CO2), ammonia (NH3), nitric (NO) and nitrous oxide (N2O) was studied in four existing treatment plants. All gases except NO were emitted from the composting material. The emission factors were 12 to 185 kg ton(-1) substrate for CO2, 6-12 x 10(3) g ton(-1) substrate for CH4, 1.44 to 378 g ton(-1) substrate for N2O and 18-1150 g ton(-1) for NH3. In general, emission factors increased with increasing treatment time. The biofilters had no net effect on CH4, but removed 13-89% of the NH3. For CO2 the biofilters were a small, for N2O a major and for NO the exclusive source. Approximately 26% of the NH3-N that was removed in the biofilter was transformed into N2O when NH3 was the exclusive nitrogen source. Assuming that all municipal waste was treated by MBT, the emissions would account for 0.3 to 5% of the N2O and for 0.1 to 3% of the CH4 emissions in Germany, respectively. Optimising aeration and removing NH3 before the exhaust gas enters the biofilter could lead to reduced greenhouse gas emissions.

  16. Ground Water Monitoring Requirements for Hazardous Waste Treatment, Storage and Disposal Facilities

    EPA Pesticide Factsheets

    The groundwater monitoring requirements for hazardous waste treatment, storage and disposal facilities (TSDFs) are just one aspect of the Resource Conservation and Recovery Act (RCRA) hazardous waste management strategy for protecting human health and the

  17. Hanford Waste Simulants Created to Support the Research and Development on the River Protection Project - Waste Treatment Plant

    SciTech Connect

    Eibling, R.E.

    2001-07-26

    The development of nonradioactive waste simulants to support the River Protection Project - Waste Treatment Plant bench and pilot-scale testing is crucial to the design of the facility. The report documents the simulants development to support the SRTC programs and the strategies used to produce the simulants.

  18. ANALYSIS OF TANK 48H SAMPLE HTF-E-05-021

    SciTech Connect

    Fondeur, F

    2005-10-03

    Due to the need for additional HLW storage, successful disposition of the material in Tank 48H and return of the tank to routine service are two critically needed activities. As an initial step in the process, SRNL compositionally characterized the components of the Tank 48H slurry. Previously, a Tank 48H slurry sample was collected on August 23, 2004 (HTF-E-04-049 and HTF-E-04-050). The August 23, 2004 sample contained approximately 2 Liters of Tank 48H slurry. In December 7, 2004, Tank farm personnel added 3,019 gallons of 50 wt% caustic solution to Tank 48H. On March 6, 2005, about of 4L of slurry was pulled from Tank 48H sample using a new 4.2 L sampler and sent to SRNL. Part of this sample was used for saltstone aggregation studies. The remaining Tank 48H sample was placed in a carboy for future analysis. Small portions of this sample were analyzed and the results are reported in this document. This document provides the chemical and radiological characterization of a Tank 48H slurry sample as defined in the Technical Task Request Plan and task technical and quality assurance plan. At the time of the sampling, the Tank 48H volume was 242,190 gallons (69 inches from the bottom of the tank) and the pumps were ran for 27 hours prior to sampling. The sample was collected within approximately 10 minutes of pump shutdown. A description of the sampler and method is given in Appendix A. This report compares results with those reported elsewhere (WSRC-TR-2004-00514 [HTF-E-04-049 and HTF-E-04-050] analysis), CBU-PIT-2005-00066 [Tank 48 Best Estimate Chemical Characterization as of March 17, 2005] and CBU-PIT-2005-00046 [Tank 48 Radionuclide Characterization to Support Material Disposition]. Since there was addition of 3,019 gallons of 50 wt% caustic solution to Tank 48H after issuing the WSRCTR-2004-00514 characterization report, the data from WSRC-TR-2004-00514 needs to be adjusted by dividing the results by a factor of 1.013. This adjustment is necessary to ensure

  19. Assessment of incineration and melting treatment technologies for RWMC buried waste

    SciTech Connect

    Geimer, R.; Hertzler, T.; Gillins, R. ); Anderson, G.L. )

    1992-02-01

    This report provides an identification, description, and ranking evaluation of the available thermal treatment technologies potentially capable of treating the Idaho National Engineering Laboratory Radioactive Waste Management Complex (RWMC) buried mixed waste. The ranking evaluation focused separately upon incinerators for treatment of combustible wastes and melters for noncombustible wastes. The highest rank incinerators are rotary kilns and controlled air furnaces, while the highest rank melters are the hearth configuration plasma torch, graphite electrode arc, and joule-heated melters. 4 refs.

  20. Energy and nutrient recovery from anaerobic treatment of organic wastes

    NASA Astrophysics Data System (ADS)

    Henrich, Christian-Dominik

    The objective of the research was to develop a complete systems design and predictive model framework of a series of linked processes capable of providing treatment of landfill leachate while simultaneously recovering nutrients and bioenergy from the waste inputs. This proposed process includes an "Ammonia Recovery Process" (ARP) consisting of: (1) ammonia de-sorption requiring leachate pH adjustment with lime or sodium hydroxide addition followed by, (2) ammonia re-absorption into a 6-molar sulfuric acid spray-tower followed by, (3) biological activated sludge treatment of soluble organic residuals (BOD) followed by, (4) high-rate algal post-treatment and finally, (5) an optional anaerobic digestion process for algal and bacterial biomass, and/or supplemental waste fermentation providing the potential for additional nutrient and energy recovery. In addition, the value provided by the waste treatment function of the overall processes, each of the sub-processes would provide valuable co-products offering potential GHG credit through direct fossil-fuel replacement, or replacement of products requiring fossil fuels. These valuable co-products include, (1) ammonium sulfate fertilizer, (2) bacterial biomass, (3) algal biomass providing, high-protein feeds and oils for biodiesel production and, (4) methane bio-fuels. Laboratory and pilot reactors were constructed and operated, providing data supporting the quantification and modeling of the ARP. Growth parameters, and stoichiometric coefficients were determined, allowing for design of the leachate activated sludge treatment sub-component. Laboratory and pilot algal reactors were constructed and operated, and provided data that supported the determination of leachate organic/inorganic-nitrogen ratio, and loading rates, allowing optimum performance of high-rate algal post-treatment. A modular and expandable computer program was developed, which provided a systems model framework capable of predicting individual component

  1. 40 CFR 265.383 - Interim status thermal treatment devices burning particular hazardous waste.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 26 2011-07-01 2011-07-01 false Interim status thermal treatment... OPERATORS OF HAZARDOUS WASTE TREATMENT, STORAGE, AND DISPOSAL FACILITIES Thermal Treatment § 265.383 Interim status thermal treatment devices burning particular hazardous waste. (a) Owners or operators of...

  2. Waste form development and characterization in pyrometallurgical treatment of spent nuclear fuel.

    SciTech Connect

    Ackerman, J.

    1998-04-16

    Electrometallurgical treatment is a compact, inexpensive method that is being developed at Argonne National Laboratory to deal with spent nuclear fuel, primarily metallic and oxide fuels. In this method, metallic nuclear fuel constituents are electrorefined in a molten salt to separate uranium from the rest of the spent fuel. Oxide and other fuels are subjected to appropriate head end steps to convert them to metallic form prior to electrorefining. The treatment process generates two kinds of high-level waste--a metallic and a ceramic waste. Isolation of these wastes has been developed as an integral part of the process. The wastes arise directly from the electrorefiner, and waste streams do not contain large quantities of solvent or other process fluids. Consequently, waste volumes are small and waste isolation processes can be compact and rapid. This paper briefly summarizes waste isolation processes then describes development and characterization of the two waste forms in more detail.

  3. Evaluation of prospective hazardous waste treatment technologies for use in processing low-level mixed wastes at Rocky Flats

    SciTech Connect

    McGlochlin, S.C.; Harder, R.V.; Jensen, R.T.; Pettis, S.A.; Roggenthen, D.K.

    1990-09-18

    Several technologies for destroying or decontaminating hazardous wastes were evaluated (during early 1988) as potential processes for treating low-level mixed wastes destined for destruction in the Fluidized Bed Incinerator. The processes that showed promise were retained for further consideration and placed into one (or more) of three categories based on projected availability: short, intermediate, and long-term. Three potential short-term options were identified for managing low-level mixed wastes generated or stored at the Rocky Flats Plant (operated by Rockwell International in 1988). These options are: (1) Continue storing at Rocky Flats, (2) Ship to Nevada Test Site for landfill disposal, or (3) Ship to the Idaho National Engineering Laboratory for incineration in the Waste Experimental Reduction Facility. The third option is preferable because the wastes will be destroyed. Idaho National Engineering Laboratory has received interim status for processing solid and liquid low-level mixed wastes. However, low-level mixed wastes will continue to be stored at Rocky Flats until the Department of Energy approval is received to ship to the Nevada Test Site or Idaho National Engineering Laboratory. Potential intermediate and long-term processes were identified; however, these processes should be combined into complete waste treatment systems'' that may serve as alternatives to the Fluidized Bed Incinerator. Waste treatment systems will be the subject of later work. 59 refs., 2 figs.

  4. Thermal treatment of medical waste in a rotary kiln.

    PubMed

    Bujak, J

    2015-10-01

    This paper presents the results of a study of an experimental system with thermal treatment (incineration) of medical waste conducted at a large complex of hospital facilities. The studies were conducted for a period of one month. The processing system was analysed in terms of the energy, environmental and economic aspects. A rotary combustion chamber was designed and built with the strictly assumed length to inner diameter ratio of 4:1. In terms of energy, the temperature distribution was tested in the rotary kiln, secondary combustion (afterburner) chamber and heat recovery system. Calorific value of medical waste was 25.0 MJ/kg and the thermal efficiency of the entire system equalled 66.8%. Next, measurements of the pollutant emissions into the atmosphere were performed. Due to the nature of the disposed waste, particular attention was paid to the one-minute average values of carbon oxide and volatile organic compounds as well as hydrochloride, hydrogen fluoride, sulphur dioxide and total dust. Maximum content of non-oxidized organic compounds in slag and bottom ash were also verified during the analyses. The best rotary speed for the combustion chamber was selected to obtain proper afterburning of the bottom slag. Total organic carbon content was 2.9%. The test results were used to determine the basic economic indicators of the test system for evaluating the profitability of its construction. Simple payback time (SPB) for capital expenditures on the implementation of the project was 4 years.

  5. Quantifying capital goods for biological treatment of organic waste.

    PubMed

    Brogaard, Line K; Petersen, Per H; Nielsen, Peter D; Christensen, Thomas H

    2015-02-01

    Materials and energy used for construction of anaerobic digestion (AD) and windrow composting plants were quantified in detail. The two technologies were quantified in collaboration with consultants and producers of the parts used to construct the plants. The composting plants were quantified based on the different sizes for the three different types of waste (garden and park waste, food waste and sludge from wastewater treatment) in amounts of 10,000 or 50,000 tonnes per year. The AD plant was quantified for a capacity of 80,000 tonnes per year. Concrete and steel for the tanks were the main materials for the AD plant. For the composting plants, gravel and concrete slabs for the pavement were used in large amounts. To frame the quantification, environmental impact assessments (EIAs) showed that the steel used for tanks at the AD plant and the concrete slabs at the composting plants made the highest contribution to Global Warming. The total impact on Global Warming from the capital goods compared to the operation reported in the literature on the AD plant showed an insignificant contribution of 1-2%. For the composting plants, the capital goods accounted for 10-22% of the total impact on Global Warming from composting.

  6. Sodium-bearing Waste Treatment Technology Evaluation Report

    SciTech Connect

    Charles M. Barnes; Arlin L. Olson; Dean D. Taylor

    2004-05-01

    Sodium-bearing waste (SBW) disposition is one of the U.S. Department of Energy (DOE) Idaho Operation Office’s (NE-ID) and State of Idaho’s top priorities at the Idaho National Engineering and Environmental Laboratory (INEEL). The INEEL has been working over the past several years to identify a treatment technology that meets NE-ID and regulatory treatment requirements, including consideration of stakeholder input. Many studies, including the High-Level Waste and Facilities Disposition Environmental Impact Statement (EIS), have resulted in the identification of five treatment alternatives that form a short list of perhaps the most appropriate technologies for the DOE to select from. The alternatives are (a) calcination with maximum achievable control technology (MACT) upgrade, (b) steam reforming, (c) cesium ion exchange (CsIX) with immobilization, (d) direct evaporation, and (e) vitrification. Each alternative has undergone some degree of applied technical development and preliminary process design over the past four years. This report presents a summary of the applied technology and process design activities performed through February 2004. The SBW issue and the five alternatives are described in Sections 2 and 3, respectively. Details of preliminary process design activities for three of the alternatives (steam reforming, CsIX, and direct evaporation) are presented in three appendices. A recent feasibility study provides the details for calcination. There have been no recent activities performed with regard to vitrification; that section summarizes and references previous work.

  7. Sampling and Analysis Plan - Waste Treatment Plant Seismic Boreholes Project

    SciTech Connect

    Reidel, Steve P.

    2006-05-26

    This sampling and analysis plan (SAP) describes planned data collection activities for four entry boreholes through the sediment overlying the basalt, up to three new deep rotary boreholes through the basalt and sedimentary interbeds, and one corehole through the basalt and sedimentary interbeds at the Waste Treatment Plant (WTP) site. The SAP will be used in concert with the quality assurance plan for the project to guide the procedure development and data collection activities needed to support borehole drilling, geophysical measurements, and sampling. This SAP identifies the American Society of Testing Materials standards, Hanford Site procedures, and other guidance to be followed for data collection activities.

  8. Tank waste remediation system optimized processing strategy with an altered treatment scheme

    SciTech Connect

    Slaathaug, E.J.

    1996-03-01

    This report provides an alternative strategy evolved from the current Hanford Site Tank Waste Remediation System (TWRS) programmatic baseline for accomplishing the treatment and disposal of the Hanford Site tank wastes. This optimized processing strategy with an altered treatment scheme performs the major elements of the TWRS Program, but modifies the deployment of selected treatment technologies to reduce the program cost. The present program for development of waste retrieval, pretreatment, and vitrification technologies continues, but the optimized processing strategy reuses a single facility to accomplish the separations/low-activity waste (LAW) vitrification and the high-level waste (HLW) vitrification processes sequentially, thereby eliminating the need for a separate HLW vitrification facility.

  9. Microbial treatment of sulfur-contaminated industrial wastes.

    PubMed

    Gómez-Ramírez, Marlenne; Zarco-Tovar, Karina; Aburto, Jorge; de León, Roberto García; Rojas-Avelizapa, Norma G

    2014-01-01

    The present study evaluated the microbial removal of sulfur from a solid industrial waste in liquid culture under laboratory conditions. The study involved the use of two bacteria Acidithiobacillus ferrooxidans ATCC 53987 and Acidithiobacillus thiooxidans AZCT-M125-5 isolated from a Mexican soil. Experimentation for industrial waste biotreatment was done in liquid culture using 125-mL Erlenmeyer flasks containing 30 mL Starkey modified culture medium and incubated at 30°C during 7 days. The industrial waste was added at different pulp densities (8.25-100% w/v) corresponding to different sulfur contents from 0.7 to 8.63% (w/w). Sulfur-oxidizing activity of the strain AZCT-M125-5 produced 281 and 262 mg/g of sulfate and a sulfur removal of 60% and 45.7% when the pulp density was set at 8.25 and 16.5% (w/v), respectively. In comparison, the strain A. ferrooxidans ATCC 53987 showed a lower sulfur-oxidizing activity with a sulfate production of 25.6 and 12.7 mg/g and a sulfur removal of 6% and 2.5% at the same pulp densities, respectively. Microbial growth was limited by pulp densities higher than 25% (w/v) of industrial waste with minimal sulfur-oxidizing activity and sulfur removal. The rate of sulfur removal for Acidithiobacillus thioxidans AZCT-M125-5 and Acidithiobacillus ferrooxidans ATCC 53987 was 0.185 and 0.0159 mg S g(-1) h(-1) with a pulp density of 16.5% (w/v), respectively. This study demonstrated that Acidithiobacillus thiooxidans AZCT-M125-5 possesses a high sulfur-oxidizing activity, even at high sulfur concentration, which allows the treatment of hazardous materials.

  10. Caffeine and modafinil promote adult neuronal cell proliferation during 48 h of total sleep deprivation in rat dentate gyrus.

    PubMed

    Sahu, Surajit; Kauser, Hina; Ray, Koushik; Kishore, Krishna; Kumar, Sanjeev; Panjwani, Usha

    2013-10-01

    It has been established that sleep deprivation (SD) reduces the proliferation of neuronal precursors in the adult hippocampus. It has also been reported that psychostimulant drugs modulate adult neurogenesis. We examined the modulatory role of two psychostimulant drugs modafinil and caffeine on adult neuronal cell proliferation (NCP) during 48 h of total SD. A novel automated cage shaking stimulus was used to induce SD based on animal activity. 5-Bromo-2″-deoxyuridine (BrdU; 50mg/kg/day i.p.) was injected at the onset of the light phase for two days. Rats were successfully sleep deprived for 85-94% of total time. Stereological analysis showed that both caffeine and modafinil treatments during SD improved the number of BrdU positive cells as compared to the SD group. Caffeine treatment during SD, significantly increased early proliferative and post-mitotic stages of doublecortin (DCX) positive cells while modafinil treatment during SD, increased intermediate and post-mitotic stages of DCX positive cells compared to SD+Vehicle group. Brain-Derived Neurotrophic Factor (BDNF) expression on BrdU positive cells as well as in the dentate gyrus (DG) region was decreased significantly after sleep deprivation. Both caffeine and modafinil significantly improved BDNF expression in the DG region. Modafinil, but not caffeine, significantly decreased hippocampal adenosine level during SD in comparison to the SD+Vehicle group. It may be concluded that caffeine or modafinil treatment during 48 h of SD prevents the SD induced decline in neuronal proliferation and differentiation. Caffeine and modafinil induced alterations of NCP during SD may involve modulation of BDNF and adenosine levels.

  11. RADIOACTIVE DEMONSTRATIONS OF FLUIDIZED BED STEAM REFORMING AS A SUPPLEMENTARY TREATMENT FOR HANFORD'S LOW ACTIVITY WASTE AND SECONDARY WASTES

    SciTech Connect

    Jantzen, C.; Crawford, C.; Cozzi, A.; Bannochie, C.; Burket, P.; Daniel, G.

    2011-02-24

    The U.S. Department of Energy's Office of River Protection (ORP) is responsible for the retrieval, treatment, immobilization, and disposal of Hanford's tank waste. Currently there are approximately 56 million gallons of highly radioactive mixed wastes awaiting treatment. A key aspect of the River Protection Project (RPP) cleanup mission is to construct and operate the Waste Treatment and Immobilization Plant (WTP). The WTP will separate the tank waste into high-level and low-activity waste (LAW) fractions, both of which will subsequently be vitrified. The projected throughput capacity of the WTP LAW Vitrification Facility is insufficient to complete the RPP mission in the time frame required by the Hanford Federal Facility Agreement and Consent Order, also known as the Tri-Party Agreement (TPA), i.e. December 31, 2047. Therefore, Supplemental Treatment is required both to meet the TPA treatment requirements as well as to more cost effectively complete the tank waste treatment mission. The Supplemental Treatment chosen will immobilize that portion of the retrieved LAW that is not sent to the WTP's LAW Vitrification facility into a solidified waste form. The solidified waste will then be disposed on the Hanford site in the Integrated Disposal Facility (IDF). In addition, the WTP LAW vitrification facility off-gas condensate known as WTP Secondary Waste (WTP-SW) will be generated and enriched in volatile components such as Cs-137, I-129, Tc-99, Cl, F, and SO4 that volatilize at the vitrification temperature of 1150 C in the absence of a continuous cold cap. The current waste disposal path for the WTP-SW is to recycle it to the supplemental LAW treatment to avoid a large steady state accumulation in the pretreatment-vitrification loop. Fluidized Bed Steam Reforming (FBSR) offers a moderate temperature (700-750 C) continuous method by which LAW and/or WTP-SW wastes can be processed irrespective of whether they contain organics, nitrates, sulfates/sulfides, chlorides

  12. 48-h glucose infusion in humans: effect on hormonal responses, hunger and food intake.

    PubMed

    Teff, Karen L; Petrova, Maja; Havel, Peter J; Townsend, Raymond R

    2007-04-23

    Experimentally-induced hyperglycemia by prolonged glucose infusion allows investigation of the effects of sustained stimulation of the pancreatic beta-cell on insulin secretion and sensitivity. Hormonal responses to a meal following prolonged glucose infusions have not been investigated. To determine if a 48-h glucose infusion alters hormonal responses to a test meal as well as food intake and hunger in normal weight individuals, 16 subjects (8 men, 8 women, age 18-30 years, mean BMI=21.7+/-1.6 kg/m2) were infused for 48 h with either saline (50 ml/h) or 15% glucose (200 mg/m2/min). Subjects ingested a 600 kcal mixed nutrient meal 3 h after infusion termination. Blood samples were taken during the 48 h and for 4 h following food ingestion. The 48-h glucose infusion elicited a metabolic profile of a glucose intolerant obese subjects, with increased plasma glucose, insulin and leptin (all P<0.01) and increased HOMA-IR (P<0.001). During meal ingestion, early insulin secretion was increased (P<0.05) but post-prandial glucose (P<0.01) and insulin (P<0.01) excursions were lower following the glucose infusion. Post-prandial plasma triglyceride concentrations were increased after glucose compared with saline. Food intake and hunger ratings were not different between the two conditions. Plasma leptin levels were inversely correlated with hunger (P<0.03) in both conditions and with food intake (P<0.003) during the glucose condition only. Thus, a 48-h glucose infusion does not impair post-prandial hormonal responses, alter food intake or hunger in normal weight subjects. The glucose-induced increases in plasma leptin result in a stronger inverse relationship between plasma leptin and hunger as well as food intake. These data are the first to demonstrate a relationship between leptin and hunger in normal weight, non-calorically restricted human subjects.

  13. Advanced Off-Gas Control System Design For Radioactive And Mixed Waste Treatment

    SciTech Connect

    Nick Soelberg

    2005-09-01

    Treatment of radioactive and mixed wastes is often required to destroy or immobilize hazardous constituents, reduce waste volume, and convert the waste to a form suitable for final disposal. These kinds of treatments usually evolve off-gas. Air emission regulations have become increasingly stringent in recent years. Mixed waste thermal treatment in the United States is now generally regulated under the Hazardous Waste Combustor (HWC) Maximum Achievable Control Technology (MACT) standards. These standards impose unprecedented requirements for operation, monitoring and control, and emissions control. Off-gas control technologies and system designs that were satisfactorily proven in mixed waste operation prior to the implementation of new regulatory standards are in some cases no longer suitable in new mixed waste treatment system designs. Some mixed waste treatment facilities have been shut down rather than have excessively restrictive feed rate limits or facility upgrades to comply with the new standards. New mixed waste treatment facilities in the U. S. are being designed to operate in compliance with the HWC MACT standards. Activities have been underway for the past 10 years at the INL and elsewhere to identify, develop, demonstrate, and design technologies for enabling HWC MACT compliance for mixed waste treatment facilities. Some specific off-gas control technologies and system designs have been identified and tested to show that even the stringent HWC MACT standards can be met, while minimizing treatment facility size and cost.

  14. Waste treatment and optimal degree of pollution abatement

    SciTech Connect

    Romero-Hernandez, O.; Pistikopoulos, E.N.; Livingston, A.G.

    1998-12-31

    Environmental impacts of industrial production processes are usually estimated by considering the emissions leaving the process. These emissions are often reduced using abatement processes, such as wastewater treatment technologies, in the belief that reducing emissions will reduce the environmental impact. Typical legislation focuses on reducing discharge levels, without considering the impact on the environment of the additional inputs required by the abatement process to achieve this reduction. This leads to the possibility that some waste streams may be over treated. In other words, industry might be devoting increased resources to reducing discharges and at the same time be worsening the environment. This paper presents a framework for the analysis of wastewater treatment technologies from an economic and environmental point of view. The work examines trade-offs in abatement processes between higher inputs (energy consumption and raw material) and lower discharge quantities (pollutant flow). As a result, an optimal degree of pollution abatement (ODPA), at which environmental impact is minimized, is identified. This value could act as a guideline to legislators who are setting discharge limits and to chemical engineers with waste discharge responsibilities. Case studies on two different abatement technologies, steam stripping and pervaporation, are presented to illustrate this framework.

  15. Integrated Waste Treatment Unit GFSI Risk Management Plan

    SciTech Connect

    W. A. Owca

    2007-06-21

    This GFSI Risk Management Plan (RMP) describes the strategy for assessing and managing project risks for the Integrated Waste Treatment Unit (IWTU) that are specifically within the control and purview of the U.S. Department of Energy (DOE), and identifies the risks that formed the basis for the DOE contingency included in the performance baseline. DOE-held contingency is required to cover cost and schedule impacts of DOE activities. Prior to approval of the performance baseline (Critical Decision-2) project cost contingency was evaluated during a joint meeting of the Contractor Management Team and the Integrated Project Team for both contractor and DOE risks to schedule and cost. At that time, the contractor cost and schedule risk value was $41.3M and the DOE cost and schedule risk contingency value is $39.0M. The contractor cost and schedule risk value of $41.3M was retained in the performance baseline as the contractor's management reserve for risk contingency. The DOE cost and schedule risk value of $39.0M has been retained in the performance baseline as the DOE Contingency. The performance baseline for the project was approved in December 2006 (Garman 2006). The project will continue to manage to the performance baseline and change control thresholds identified in PLN-1963, ''Idaho Cleanup Project Sodium-Bearing Waste Treatment Project Execution Plan'' (PEP).

  16. Croatian refiner meets waste water treatment standards, reduces fines

    SciTech Connect

    Meier, A.L.; Nikolic, O.

    1995-11-27

    A new approach to waste water treatment at a refinery in Croatia produces effluent that not only meets the region`s regulations for disposal into the Adriatic Sea, but also surpasses the refinery`s specifications for recycling process water. Key to the dramatic reduction in pollutants was the installation of a Sandfloat unit developed by Krofta Engineering Corp. The Sandfloat unit is a dissolved air flotation clarifier that combines flocculation, flotation, and multilayer filtration to produce high-quality effluent. In fact, the effluent from the unit has a lower hydrocarbon concentration than water from the underground wells that supply process water to the refinery. While similar systems have been used for decades in industrial applications, this is the first time a Sandfloat unit has been installed in an oil refinery. The article describes the problem, refinery operations, treatment costs, and effluent recycling.

  17. 40 CFR 268.41 - Treatment standards expressed as concentrations in waste extract.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... concentrations in waste extract. 268.41 Section 268.41 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... standards expressed as concentrations in waste extract. For the requirements previously found in this section and for treatment standards in Table CCWE—Constituent Concentrations in Waste Extracts, refer...

  18. 40 CFR 268.41 - Treatment standards expressed as concentrations in waste extract.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... concentrations in waste extract. 268.41 Section 268.41 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... standards expressed as concentrations in waste extract. For the requirements previously found in this section and for treatment standards in Table CCWE—Constituent Concentrations in Waste Extracts, refer...

  19. 40 CFR 268.41 - Treatment standards expressed as concentrations in waste extract.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... concentrations in waste extract. 268.41 Section 268.41 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... standards expressed as concentrations in waste extract. For the requirements previously found in this section and for treatment standards in Table CCWE—Constituent Concentrations in Waste Extracts, refer...

  20. 40 CFR 268.41 - Treatment standards expressed as concentrations in waste extract.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... concentrations in waste extract. 268.41 Section 268.41 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... standards expressed as concentrations in waste extract. For the requirements previously found in this section and for treatment standards in Table CCWE—Constituent Concentrations in Waste Extracts, refer...

  1. 40 CFR 268.41 - Treatment standards expressed as concentrations in waste extract.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... concentrations in waste extract. 268.41 Section 268.41 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... standards expressed as concentrations in waste extract. For the requirements previously found in this section and for treatment standards in Table CCWE—Constituent Concentrations in Waste Extracts, refer...

  2. Waste Management, Treatment, and Disposal for the Food Processing Industry. Special Circular 113.

    ERIC Educational Resources Information Center

    Wooding, N. Henry

    This publication contains information relating to waste prevention, treatment and disposal, and waste product utilization. Its primary purpose is to provide information that will help the food industry executive recognize waste problems and make wise management decisions. The discussion of the methods, techniques, and the state-of-the-art is…

  3. MOBILITY AND DEGRADATION OF RESIDUES AT HAZARDOUS WASTE LAND TREATMENT SITES AT CLOSURE

    EPA Science Inventory

    Soil treatment systems that are designed and managed based on a knowledge of soil-waste interactions may represent a significant technology for simultaneous treatment and ultimate disposal of selected hazardous wastes in an environmentally acceptable manner. hese soil treatment s...

  4. Mixed Waste Focus Area mercury contamination product line: An integrated approach to mercury waste treatment and disposal

    SciTech Connect

    Hulet, G.A.; Conley, T.B.; Morris, M.I.

    1998-07-01

    The US Department of Energy (DOE) Mixed Waste Focus Area (MWFA) is tasked with ensuring that solutions are available for the mixed waste treatment problems of the DOE complex. During the MWFA`s initial technical baseline development process, three of the top four technology deficiencies identified were related to the need for amalgamation, stabilization, and separation/removal technologies for the treatment of mercury and mercury-contaminated mixed waste. The focus area grouped mercury-waste-treatment activities into the mercury contamination product line under which development, demonstration, and deployment efforts are coordinated to provide tested technologies to meet the site needs. The Mercury Working Group (HgWG), a selected group of representatives from DOE sites with significant mercury waste inventories, is assisting the MWFA in soliciting, identifying, initiating, and managing efforts to address these areas. Based on the scope and magnitude of the mercury mixed waste problem, as defined by HgWG, solicitations and contract awards have been made to the private sector to demonstrate amalgamation and stabilization processes using actual mixed wastes. Development efforts are currently being funded under the product line that will address DOE`s needs for separation/removal processes. This paper discusses the technology selection process, development activities, and the accomplishments of the MWFA to date through these various activities.

  5. Treatment studies at the Process Waste Treatment Plant at Oak Ridge National Laboratory

    SciTech Connect

    Robinson, S.M.; Begovich, J.M.

    1991-03-01

    Precipitation and ion-exchange methods are being developed to decontaminate Oak Ridge National Laboratory process wastewaters containing small amounts of {sup 90}Sr and {sup 137}Cs while minimizing waste generation. Many potential processes have been examined in laboratory-scale screening tests. Based on these data, five process flowsheets were developed and are being evaluated under pilot- and full-scale operating conditions. Improvements in the existing treatment system based on this study have resulted in a 66 vol % reduction in waste generation. 19 refs., 26 figs., 45 tabs.

  6. Evaporation Of Hanford Waste Treatment Plant Direct Feed Low Activity Waste Effluent Management Facility Core Simulant

    SciTech Connect

    Adamson, D.; Nash, C.; Mcclane, D.; McCabe, D.

    2016-09-01

    The Hanford Waste Treatment and Immobilization Plant (WTP) Low Activity Waste (LAW) vitrification facility will generate an aqueous condensate recycle stream (LAW Melter Off-Gas Condensate, LMOGC) from the off-gas system. The baseline plan for disposition of this stream during full WTP operations is to send it to the WTP Pretreatment Facility, where it will be blended with LAW, concentrated by evaporation, and recycled to the LAW vitrification facility. However, during the Direct Feed LAW (DFLAW) scenario, planned disposition of this stream is to evaporate it in a new evaporator, in the Effluent Management Facility (EMF), and then return it to the LAW melter. It is important to understand the composition of the effluents from the melter and new evaporator, so that the disposition of these streams can be accurately planned and accommodated. Furthermore, alternate disposition of the LMOGC stream would eliminate recycling of problematic components, and would reduce the need for closely integrated operation of the LAW melter and the Pretreatment Facilities. Long-term implementation of this option after WTP start-up would decrease the LAW vitrification mission duration and quantity of glass waste, amongst the other operational complexities such a recycle stream presents. In order to accurately plan for the disposition path, it is key to experimentally determine the fate of contaminants. To do this, testing is needed to accurately account for the buffering chemistry of the components, determine the achievable evaporation end point, identify insoluble solids that form, and determine the distribution of key regulatory-impacting constituents. The LAW Melter Off-Gas Condensate stream will contain components that are volatile at melter temperatures, have limited solubility in the glass waste form, and represent a materials corrosion concern, such as halides and sulfate. Because this stream will recycle within WTP, these components will accumulate in the Melter Condensate

  7. Separation technologies for the treatment of Idaho National Engineering Laboratory Wastes

    SciTech Connect

    Todd, T.; Herbst, S.

    1996-10-01

    The Idaho National Engineering Laboratory (INEL) is collaborating with several DOE and international organizations to develop and evaluate: technologies for the treatment of acidic high-level radioactive wastes. The focus on the treatment of high-level radioactive wastes is on the removal of cesium and strontium from wastes typically 1 to 3 M in acidity. Technologies to treat groundwater contaminated with radionuclides and/or toxic metals. Technologies to remove toxic metals from hazardous or mixed waste streams, for neutral pH to 3 M acidic waste streams.

  8. The 1996 meeting of the national technical workgroup on mixed waste thermal treatment

    SciTech Connect

    1996-12-31

    The National Technical Workgroup on Mixed Waste Thermal Treatment held its annual meeting in Atlanta Georgia on March 12-14, 1996. The National Technical Workgroup (NTW) and this meeting were sponsored under an interagency agreement between EPA and DOE. The 1996 Annual Meeting was hosted by US DOE Oak Ridge Operations in conjunction with Lockheed Martin Energy Systems - Center for Waste Management. A new feature of the annual meeting was the Permit Writer Panel Session which provided an opportunity for the state and federal permit writers to discuss issues and potential solutions to permitting mixed waste treatment systems. In addition, there was substantial discussion on the impacts of the Waste Combustion Performance Standards on mixed waste thermal treatment which are expected to proposed very soon. The 1996 meeting also focussed on two draft technical resource documents produced by NTW on Waste Analysis Plans and Compliance Test Procedures. Issues discussed included public involvement, waste characterization, and emission issues.

  9. Options assessment report: Treatment of nitrate salt waste at Los Alamos National Laboratory

    SciTech Connect

    Robinson, Bruce Alan; Stevens, Patrice Ann

    2015-09-16

    This report documents the methodology used to select a method of treatment for the remediated nitrate salt (RNS) and unremediated nitrate salt (UNS) waste containers at Los Alamos National Laboratory (LANL). The method selected should treat the containerized waste in a manner that renders the waste safe and suitable for transport and final disposal in the Waste Isolation Pilot Plant (WIPP) repository, under specifications listed in the WIPP Waste Acceptance Criteria (DOE/CBFO, 2013). LANL recognized that the results must be thoroughly vetted with the New Mexico Environment Department (NMED) and the a modification to the LANL Hazardous Waste Facility Permit is a necessary step before implementation of this or any treatment option. Likewise, facility readiness and safety basis approvals must be received from the Department of Energy (DOE). This report presents LANL's preferred option, and the documentation of the process for reaching the recommended treatment option for RNS and UNS waste, and is presented for consideration by NMED and DOE.

  10. RADIOACTIVE DEMONSTRATION OF FINAL MINERALIZED WASTE FORMS FOR HANFORD WASTE TREATMENT PLANT SECONDARY WASTE BY FLUIDIZED BED STEAM REFORMING USING THE BENCH SCALE REFORMER PLATFORM

    SciTech Connect

    Crawford, C.; Burket, P.; Cozzi, A.; Daniel, W.; Jantzen, C.; Missimer, D.

    2012-02-02

    The U.S. Department of Energy's Office of River Protection (ORP) is responsible for the retrieval, treatment, immobilization, and disposal of Hanford's tank waste. Currently there are approximately 56 million gallons of highly radioactive mixed wastes awaiting treatment. A key aspect of the River Protection Project (RPP) cleanup mission is to construct and operate the Waste Treatment and Immobilization Plant (WTP). The WTP will separate the tank waste into high-level and low-activity waste (LAW) fractions, both of which will subsequently be vitrified. The projected throughput capacity of the WTP LAW Vitrification Facility is insufficient to complete the RPP mission in the time frame required by the Hanford Federal Facility Agreement and Consent Order, also known as the Tri-Party Agreement (TPA), i.e. December 31, 2047. Therefore, Supplemental Treatment is required both to meet the TPA treatment requirements as well as to more cost effectively complete the tank waste treatment mission. In addition, the WTP LAW vitrification facility off-gas condensate known as WTP Secondary Waste (WTP-SW) will be generated and enriched in volatile components such as {sup 137}Cs, {sup 129}I, {sup 99}Tc, Cl, F, and SO{sub 4} that volatilize at the vitrification temperature of 1150 C in the absence of a continuous cold cap (that could minimize volatilization). The current waste disposal path for the WTP-SW is to process it through the Effluent Treatment Facility (ETF). Fluidized Bed Steam Reforming (FBSR) is being considered for immobilization of the ETF concentrate that would be generated by processing the WTP-SW. The focus of this current report is the WTP-SW. FBSR offers a moderate temperature (700-750 C) continuous method by which WTP-SW wastes can be processed irrespective of whether they contain organics, nitrates, sulfates/sulfides, chlorides, fluorides, volatile radionuclides or other aqueous components. The FBSR technology can process these wastes into a crystalline ceramic

  11. Thermal treatment of historical radioactive solid and liquid waste into the CILVA incinerator

    SciTech Connect

    Deckers, Jan; Mols, Ludo

    2007-07-01

    Since the very beginning of the nuclear activities in Belgium, the incineration of radioactive waste was chosen as a suitable technique for achieving an optimal volume reduction of the produced waste quantities. Based on the 35 years experience gained by the operation of the old incinerator, a new industrial incineration plant started nuclear operation in May 1995, as a part of the Belgian Centralized Treatment/Conditioning Facility named CILVA. Up to the end of 2006, the CILVA incinerator has burnt 1660 tonne of solid waste and 419 tonne of liquid waste. This paper describes the type and allowable radioactivity of the waste, the incineration process, heat recovery and the air pollution control devices. Special attention is given to the treatment of several hundreds of tonne historical waste from former reprocessing activities such as alpha suspected solid waste, aqueous and organic liquid waste and spent ion exchange resins. The capacity, volume reduction, chemical and radiological emissions are also evaluated. BELGOPROCESS, a company set up in 1984 at Dessel (Belgium) where a number of nuclear facilities were already installed is specialized in the processing of radioactive waste. It is a subsidiary of ONDRAF/NIRAS, the Belgian Nuclear Waste Management Agency. According to its mission statement, the activities of BELGOPROCESS focus on three areas: treatment, conditioning and interim storage of radioactive waste; decommissioning of shut-down nuclear facilities and cleaning of contaminated buildings and land; operating of storage sites for conditioned radioactive waste. (authors)

  12. A preliminary evaluation of alternatives for treatment of INEL Low-Level Waste and low-level mixed waste

    SciTech Connect

    Smith, T.H.; Roesener, W.S.; Jorgensen-Waters, M.J.; Edinborough, C.R.

    1992-06-01

    The Mixed and Low-Level Waste Treatment Facility (MLLWTF) project was established in 1991 by the US Department of Energy Idaho Field Office to provide treatment capabilities for Idaho National Engineering Laboratory (INEL) low-level mixed waste and low-level waste. This report identifies and evaluates the alternatives for treating that waste. Twelve treatment alternatives, ranging from ``no-action`` to constructing and operating the MLLWTF, are identified and evaluated. Evaluations include facility performance, environmental, safety, institutional, schedule, and rough order-of-magnitude cost comparisons. The performance of each alternative is evaluated against lists of ``musts`` and ``wants.`` Also included is a discussion of other key considerations for decision making. Analysis of results indicated further study is necessary to obtain the best estimate of future waste volumes and characteristics from the expanded INEL Decontamination and Decommissioning Program. It is also recommended that conceptual design begin as scheduled on the MLLWTF, maximum treatment alternative while re-evaluating the waste volume projections.

  13. High level nuclear waste treatment in the Defense Waste Processing Facility: Overview and integrated flowsheet model

    SciTech Connect

    Choi, A.S.; Fowler, J.R.; Edwards, R.E. Jr.; Randall, C.T.

    1991-01-01

    Design and construction of the world's largest vitrification facility for high level nuclear waste has been nearly completed at the US Department of Energy's Savannah River Site. Equipment testing and calibration are currently being performed in preparation for the nonradioactive Chemical Runs in the late 1991. In 1993, the Defense Waste Processing Facility (DWPF) will begin producing 100 kg/hr of radioactive waste glass at 28 wt% waste oxide loading. This paper describes all phases of waste processing operations in DWPF and waste tank farms using the integrated flowsheet modeling approach. Particular emphases are given to recent developments in the DWPF processes and design.

  14. High level nuclear waste treatment in the Defense Waste Processing Facility: Overview and integrated flowsheet model

    SciTech Connect

    Choi, A.S.; Fowler, J.R.; Edwards, R.E. Jr.; Randall, C.T.

    1991-12-31

    Design and construction of the world`s largest vitrification facility for high level nuclear waste has been nearly completed at the US Department of Energy`s Savannah River Site. Equipment testing and calibration are currently being performed in preparation for the nonradioactive Chemical Runs in the late 1991. In 1993, the Defense Waste Processing Facility (DWPF) will begin producing 100 kg/hr of radioactive waste glass at 28 wt% waste oxide loading. This paper describes all phases of waste processing operations in DWPF and waste tank farms using the integrated flowsheet modeling approach. Particular emphases are given to recent developments in the DWPF processes and design.

  15. Biofilm treatment of soil for waste containment and remediation

    SciTech Connect

    Turner, J.P.; Dennis, M.L.; Osman, Y.A.; Chase, J.; Bulla, L.A.

    1997-12-31

    This paper examines the potential for creating low-permeability reactive barriers for waste treatment and containment by treating soils with Beijerinckia indica, a bacterium which produces an exopolysaccharide film. The biofilm adheres to soil particles and causes a decrease in soil hydraulic conductivity. In addition, B. Indica biodegrades a variety of polycyclic aromatic hydrocarbons and chemical carcinogens. The combination of low soil hydraulic conductivity and biodegradation capabilities creates the potential for constructing reactive biofilm barriers from soil and bacteria. A laboratory study was conducted to evaluate the effects of B. Indica on the hydraulic conductivity of a silty sand. Soil specimens were molded with a bacterial and nutrient solution, compacted at optimum moisture content, permeated with a nutrient solution, and tested for k{sub sat} using a flexible-wall permeameter. Saturated hydraulic conductivity (k{sub sat}) was reduced from 1 x 10{sup -5} cm/sec to 2 x 10{sup -8} cm/sec: by biofilm treatment. Permeation with saline, acidic, and basic solutions following formation of a biofilm was found to have negligible effect on the reduced k{sub sat}, for up to three pore volumes of flow. Applications of biofilm treatment for creating low-permeability reactive barriers are discussed, including compacted liners for bottom barriers and caps and creation of vertical barriers by in situ treatment.

  16. High-level-waste treatment at West Valley: integrated radwaste treatment system

    SciTech Connect

    Baker, M.N. )

    1992-01-01

    The West Valley Site was the location of the only operating nuclear fuel reprocessing plant in the United States. A private firm operated the facility from 1966 to 1972, processing 640 tonnes of commercial and defense fuels using the plutonium uranium reduction extraction (Purex) process. Approximately 2.1 million liters of liquid reprocessing waste resulted from this operation. These wastes were stored in an underground storage tank. The integrated radwaste treatment system (IRTS) began operation in May 1988. This is a liquid waste pretreatment system designated to decontaminate the high-level liquid waste (HLLW), forming a low-level liquid waste (LLLW). The LLLW is encapsulated in cement, poured into 71-gal square drums and stored in a remotely operated shielded retrievable storage location. From May 1988 through November 1990, the IRTS decontaminated 450,000 gal of HLLW, encapsulating the resulting concentrates into 10,393, 71-gal square drums. All of the technical difficulties encountered during 2 1/2 yr of processing were resolved using available technology without compromising safety or product quality. There was no abnormal or unacceptable personnel exposure during this processing period.

  17. Flowsheet simulation for better operation of waste treatment systems

    SciTech Connect

    Zullo, L.C.

    1995-12-31

    The oil and chemical processing industry has often perceived waste treatment facilities as unavoidable additional costs of its manufacturing cycle. Because of this the industry has been slow in applying to these units the same technological approaches now common for revenue generating plants. It is often felt, that once regulatory compliance is achieved, any further effort would add to the costs without substantial return. To the contrary, modern modeling tools and a systematic approach to plant design and operation can help in reducing the cost of running these units without compromising regulatory compliance. A particularly common operation involves the destruction by combustion of solvent and other unrecoverable organic products. Typically, a chemical firm may cope with several compounds that may be present in mixtures of varying composition. The ignition takes place using auxiliary fuel (methane) to maintain desired temperature levels in the combustor. Combustion oxygen is provided by blowing air with large fans into the combustor. The combustion temperature needs to be high enough as to minimize the amount of NO{sub x} released. Excess of methane is expensive and not effective because when all the available oxygen is consumed, the temperature does not any longer increase (overfiring) and residual methane is release in the atmosphere, thereby compromising regulatory compliance. In this work we show how commercial simulation tools allow the engineer to optimize the auxiliary fuel consumption and, given a varying diet of organic wastes, to organize combustion campaigns that achieve minimum operating costs and fully satisfy environmental regulations.

  18. Innovative Process for Comprehensive Treatment of Liquid Radioactive Waste - 12551

    SciTech Connect

    Penzin, R.A.; Sarychev, G.A.

    2012-07-01

    the necessity to take emergency measures and to use marine water for cooling of reactor zone in contravention of the technological regulations. In these cases significant amount of liquid radioactive wastes of complex physicochemical composition is being generated, the purification of which by traditional methods is close to impossible. According to the practice of elimination of the accident after-effects at NPP 'Fukushima' there are still no technical means for the efficient purification of liquid radioactive wastes of complex composition like marine water from radionuclides. Therefore development of state-of-the-art highly efficient facilities capable of fast and safe purification of big amounts of liquid radioactive wastes of complex physicochemical composition from radionuclides turns to be utterly topical problem. Cesium radionuclides, being extremely dangerous for the environment, present over 90% of total radioactivity contained in liquid radioactive wastes left as a result of accidents at nuclear power objects. For the purpose of radiation accidents aftereffects liquidation VNIIHT proposes to create a plant for LRW reprocessing, consisting of 4 major technological modules: Module of LRW pretreatment to remove mechanical and organic impurities including oil products; Module of sorption purification of LWR by means of selective inorganic sorbents; Module of reverse osmotic purification and desalination; Module of deep evaporation of LRW concentrates. The first free modules are based on completed technological and designing concepts implemented by VNIIHT in the framework of LLRW Project in the period of 2000-2001 in Russia for comprehensive treatment of LWR of atomic fleet. These industrial plants proved to be highly efficient and secure during their long operation life. Module of deep evaporation is a new technological development. It will ensure conduction of evaporation and purification of LRW of different physicochemical composition, including those

  19. Mixed Waste Focus Area Working Group: An Integrated Approach to Mercury Waste Treatment and Disposal. Revision 1

    SciTech Connect

    Morris, M.I.; Conley, T.B.; Osborne-Lee, I.W.

    1997-09-08

    May 1996, the U.S. Department of Energy (DOE) Mixed Waste Focus Area (MWFA) initiated the Mercury Work Group (HgWG). The HgWG was established to address and resolve the issues associated with Mercury- contaminated mixed wastes (MWs). During the initial technical baseline development process of the MWFA, three of the top four technology deficiencies identified were related to (1) amalgamation, (2) stabilization, and (3) separation and removal for the treatment of mercury and mercury-contaminated mixed waste (MW). The HgWG is assisting the MWFA in soliciting, identifying, initiating, and managing efforts to address these needs.

  20. Laboratory optimization tests of technetium decontamination of Hanford Waste Treatment Plant low activity waste melter off-gas condensate simulant

    SciTech Connect

    Taylor-Pashow, Kathryn M.L.; McCabe, Daniel J.

    2015-11-01

    The Hanford Waste Treatment and Immobilization Plant (WTP) Low Activity Waste (LAW) vitrification facility will generate an aqueous condensate recycle stream (LAW Off-Gas Condensate) from the off-gas system. The baseline plan for disposition of this stream is to send it to the WTP Pretreatment Facility, where it will be blended with LAW, concentrated by evaporation and recycled to the LAW vitrification facility again. Alternate disposition of this stream would eliminate recycling of problematic components, and would enable simplified operation of the LAW melter and the Pretreatment Facilities. Eliminating this stream from recycling within WTP would also decrease the LAW vitrification mission duration and quantity of glass waste.

  1. Persistent digital hyperthermia over a 48 h period does not induce laminitis in horses.

    PubMed

    de Laat, Melody A; Pollitt, Christopher C; Walsh, Donald M; McGowan, Catherine M; Sillence, Martin N

    2012-06-01

    Persistent digital hyperthermia, presumably due to vasodilation, occurs during the developmental and acute stages of insulin-induced laminitis. The objectives of this study were to determine if persistent digital hyperthermia is the principal pathogenic mechanism responsible for the development of laminitis. The potent vasodilator, ATP-MgCl(2) was infused continuously into the distal phalanx of the left forefoot of six Standardbred racehorses for 48 h via intra-osseous infusion to promote persistent digital hyperthermia. The right forefoot was infused with saline solution and acted as an internal control. Clinical signs of lameness at the walk were not detected at 0 h, 24h or 48 h post-infusion. Mean ± SE hoof wall temperatures of the left forefoot (29.4 ± 0.25°C) were higher (P<0.05) than those on the right (27.5 ± 0.38°C). Serum insulin (15.0 ± 2.89 μIU/mL) and blood glucose (5.4 ± 0.22 mM) concentrations remained unchanged during the experiment. Histopathological evidence of laminitis was not detected in any horse. The results demonstrated that digital vasodilation up to 30°C for a period of 48 h does not trigger laminitis in the absence of hyperinsulinaemia. Thus, although digital hyperthermia may play a role in the pathogenesis of laminitis, it is not the sole mechanism involved.

  2. Aerobic biological treatment of leachates from municipal solid waste landfill.

    PubMed

    Andrés, P; Gutierrez, F; Arrabal, C; Cortijo, M

    2004-01-01

    The main objective of the study was to improve chemical oxygen demand (COD) elimination by secondary biological treatment from leachate of municipal solid waste landfill. This effluent was a supernatant liquid obtained after physicochemical processes and coagulating with Al3+ followed by ammoniacal stripping. First, respirometric assays were carried out to determine the substrate biodegradability. Specific sludge respiration rate (R(s)) vs. concentration of substrate (S), showed an increasing specific rate of assimilation of substrate (Rs), which reached the highest value, when the substrate concentration (COD) was between 75 and 200 mg O2 L(-1). Second, continuous experiments were made in an aerobic digester to test the previous respirometric data and the results showed removal efficiency of COD between 83 and 69%, and a substrate assimilation rate between 1.3 and 3.1 g COD g(-1) volatile suspended solids d(-1).

  3. Gasifier waste water treatment: Phase I cooling tower assessment

    SciTech Connect

    Mann, M.D.; Willson, W.G.; Hendrikson, J.G.; Winton, S.L.

    1985-02-01

    Details of an advanced study of the treatability of waste waters from the fixed-bed gasification of lignite describe the test equipment and results at a pilot plant in North Dakota using stripped-gas liquor (SGL) as cooling tower makeup. Ammonia, alkalinity, phenol, and other non-hydantoin organics were removed from the cooling water by stripping and/or biological degradation, with the phenol concentration in the exhaust air exceeding the odor threshold. It will be necessary to control foaming of the circulating water, but both glycol and silicon based agents performed well during the test. It will also be necessary to reduce the high level of biofouling on heat transfer surfaces, although stainless steel fouling was not a major problem. The conclusion is that SGL is limited by potentially serious operating problems without additional treatment. 5 references, 4 figures, 7 tables.

  4. Results Of Copper Catalyzed Peroxide Oxidation (CCPO) Of Tank 48H Simulants

    SciTech Connect

    Peters, T. B.; Pareizs, J. M.; Newell, J. D.; Fondeur, F. F.; Nash, C. A.; White, T. L.; Fink, S. D.

    2012-12-13

    Savannah River National Laboratory (SRNL) performed a series of laboratory-scale experiments that examined copper-catalyzed hydrogen peroxide (H{sub 2}O{sub 2}) aided destruction of organic components, most notably tetraphenylborate (TPB), in Tank 48H simulant slurries. The experiments were designed with an expectation of conducting the process within existing vessels of Building 241-96H with minimal modifications to the existing equipment. Results of the experiments indicate that TPB destruction levels exceeding 99.9% are achievable, dependent on the reaction conditions. A lower reaction pH provides faster reaction rates (pH 7 > pH 9 > pH 11); however, pH 9 reactions provide the least quantity of organic residual compounds within the limits of species analyzed. Higher temperatures lead to faster reaction rates and smaller quantities of organic residual compounds. A processing temperature of 50°C as part of an overall set of conditions appears to provide a viable TPB destruction time on the order of 4 days. Higher concentrations of the copper catalyst provide faster reaction rates, but the highest copper concentration (500 mg/L) also resulted in the second highest quantity of organic residual compounds. The data in this report suggests 100-250 mg/L as a minimum. Faster rates of H{sub 2}O{sub 2} addition lead to faster reaction rates and lower quantities of organic residual compounds. An addition rate of 0.4 mL/hour, scaled to the full vessel, is suggested for the process. SRNL recommends that for pH adjustment, an acid addition rate 42 mL/hour, scaled to the full vessel, is used. This is the same addition rate used in the testing. Even though the TPB and phenylborates can be destroyed in a relative short time period, the residual organics will take longer to degrade to <10 mg/L. Low level leaching on titanium occurred, however, the typical concentrations of released titanium are very low (~40 mg/L or less). A small amount of leaching under these conditions is not

  5. Implementing separate waste collection and mechanical biological waste treatment in South Africa: a comparison with Austria and England.

    PubMed

    Trois, Cristina; Simelane, Oscar T

    2010-01-01

    The degradation of organic compounds found in municipal solid waste (MSW) under the anaerobic landfill conditions produces gas and liquid emissions that can protract well into the landfill after-care period. The European Landfill Directives regulate the amount and nature of the organic compounds disposed into landfills. In South Africa and other developing countries, MSW is still landfilled without any kind of pre-treatment. This paper presents a pilot project of mechanical biological waste treatment (MBWT) in South Africa implemented at municipal level in the city of Durban using passively aerated open windrows. Based on case studies from Austria, England and South Africa, a waste minimisation model which can facilitate full-scale implementation of MBWT in developing countries is presented. MSW was treated in open windrows for 8 weeks. Composting temperature reached a maximum of 65 degrees C in less than 10 days. The results of eluate tests on waste samples from the windrows at the end of composting show a reduction of BOD(5) and BOD(5)/COD ratios equal to 35.7% and 16.7%, respectively. The percent waste composition of the treated MSW was 28.3% putrescibles, 17.4% garden refuse, 13.3% plastic, 12.4% fabrics, 12% paper and other elements. The waste composition shows that more than 40% of un-treated organic material and also more than 40% non-biodegradable and recyclable materials are still landfilled without any form of biological treatment or resource recovery. A simple wet and dry waste collection model can promote recycling, treatment of biological waste before landfilling, resource recovery, labour intensive jobs and hence sustainable landfilling in the South African scenario as well as in similar developing countries.

  6. State-of-the-art report on low-level radioactive waste treatment

    SciTech Connect

    Kibbey, A.H.; Godbee, H.W.

    1980-09-01

    An attempt is made to identify the main sources of low-level radioactive wastes that are generated in the United States. To place the waste problem in perspective, rough estimates are given of the annual amounts of each generic type of waste that is generated. Most of the wet solid wastes arise from the cleanup of gaseous and liquid radioactive streams prior to discharge or recycle. The treatment of the process streams and the secondary wet solid wastes thus generated is described for each type of government or fuel cycle installation. Similarly, the institutional wet wastes are also described. The dry wastes from all sources have smilar physical and chemical characteristics in that they can be classified as compactible, noncompactible, combustible, noncombustible, or combinations thereof. The various treatment options for concentrated or solid wet wastes and for dry wastes are discussed. Among the dry-waste treatment methods are compaction, baling, and incineration, as well as chopping, cutting, and shredding. Organic materials can usually be incinerated or, in some cases, biodegraded. The filter sludges, spent resins, incinerator ashes, and concentrated liquids are usually solidified in cement, urea-formaldehyde, or unsaturated polyester resins prior to burial. Asphalt has not yet been used as a solidificaton agent in the United States, but it probably will be used in the near future. The treatment of radioactive medical and bioresearch wastes is described, but the waste from radiochenmical, pharmaceutical, and other industries is not well defined at the present time. Recovery of waste metals and treatment of hazardous contaminated wastes are discussed briefly. Some areas appearing to need more research, development, and demonstration are specifically pointed out.

  7. Does improved waste treatment have demonstrable biological benefits?

    NASA Astrophysics Data System (ADS)

    Seagle, Henry H.; Hendricks, Albert C.; Cairns, John

    1980-01-01

    Since 1972, 10 benthic surveys and 9 static fish bioassays have been conducted to assess the impact of AVTEX Fibers, Inc. effluent on the lower South Fork of the Shenandoah River. AVTEX (formerly FMC Corp.) is a rayon and polyester fibers plant located in Front Royal, Virginia. Benthic samples were taken at four stations, one above and three below the plant discharges. Single surveys in 1972 and 1973 indicated a severe impact on the benthic community along the right side of the river, below the plant, as a result of the channelized effluent. Diversity values (¯ d) were low (0 2.42) and numbers of taxa and organisms were reduced. A fish bioassay in 1973 indicated the effluent to be acutely toxic at the 34.5% level (mixture of effluent and river water). In early 1974, FMC Corp. constructed an activated sludge treatment system to reduce BOD and supplement the neutralization and chemical precipitation (zinc hydroxide and liquid-solid separation) facilities that had been used to treat waste waters since 1948. After the new equipment was placed in operation, the previously stressed area became more stable. In 1975 and 1976 the stressed area exhibited greater ¯ d values (1.19 3.39) and an increased number of taxa and organisms. Bioassays showed the effluent to be acutely toxic to fish only once since 1973. The major improvements in the effluent were a 70% reduction in BOD5 and a 60% reduction in the amount of zinc entering the river. Community conditions in 1977 indicated a partial remission of improvement, probably due to drought conditions. The rehabilitation of damaged ecosystems is a process important to all biologists. An important factor in encouraging industry to participate in this activity is evidence that improved waste treatment will often have demonstrable biological benefits rather soon. As data accumulate on the recovery process it may be possible to predict the degree of rehabilitation and time required more precisely.

  8. Decommissioning and Dismantling of Liquid Waste Storage and Liquid Waste Treatment Facility from Paldiski Nuclear Site, Estonia

    SciTech Connect

    Varvas, M.; Putnik, H.; Johnsson, B.

    2006-07-01

    The Paldiski Nuclear Facility in Estonia, with two nuclear reactors was owned by the Soviet Navy and was used for training the navy personnel to operate submarine nuclear reactors. After collapse of Soviet Union the Facility was shut down and handed over to the Estonian government in 1995. In co-operation with the Paldiski International Expert Reference Group (PIERG) decommission strategy was worked out and started to implement. Conditioning of solid and liquid operational waste and dismantling of contaminated installations and buildings were among the key issues of the Strategy. Most of the liquid waste volume, remained at the Facility, was processed in the frames of an Estonian-Finnish co-operation project using a mobile wastewater purification unit NURES (IVO International OY) and water was discharged prior to the site take-over. In 1999-2002 ca 120 m{sup 3} of semi-liquid tank sediments (a mixture of ion exchange resins, sand filters, evaporator and flocculation slurry), remained after treatment of liquid waste were solidified in steel containers and stored into interim storage. The project was carried out under the Swedish - Estonian co-operation program on radiation protection and nuclear safety. Contaminated installations in buildings, used for treatment and storage of liquid waste (Liquid Waste Treatment Facility and Liquid Waste Storage) were then dismantled and the buildings demolished in 2001-2004. (authors)

  9. Characterization and electrical properties of chitosan for waste water treatment

    NASA Astrophysics Data System (ADS)

    Saengkaew, Phannee; Chantanachai, Kanittha; Cheewajaroen, Kulthawat; Nimsiri, Woraporn

    2016-05-01

    Chitosan extracted from shrimp shell waste was characterized in order to use for the industrial wastewater treatment. By XRF technique, the qualitative and semi-quantitative analyses of pure chitosan were performed with the relative compositions of Ca, Mg, Si, Fe, Al, and Na of 0.321%, 0.738%, 0.713%, 0.363%, 0.338%, and 3.858%, respectively. In the case of two types of the contaminated chitosan from the wastewater treatment before and after a process of a primary H2O2-treatment, the relative compositions of Ca, Mg, Si and Fe were obtained with an increasing of 0.356%, 1.321%, 1.536%, 0.451% and 0.406%, 1.105%, 1.178%, 0.591%, respectively. This shows that the suspended materials in the wastewater were absorbed by chitosan. By I-V Measurements, the across-through voltage of the pure chitosan disc was 0.245V±0.053 at the applied voltage of 17V, and resistance of 53.9MΩ ±10.3 at the applied voltage of 590V. After the utilization for the wastewater treatment, the across voltage of chitosan discs from two cases were 0.133V±0.047 and 0.223V±0.063, and the resistance of 122.8MΩ ±16.1 and 24.8MΩ ±5.1. The used chitosan has a lower conductivity because of a decreasing in the chitosan's electrical dipoles by combining with the suspended ions in the wastewater. Moreover, the adsorption efficiencies of chitosan for formaldehyde in the wastewater of two cases were 31.08% and 25.40%. In summary, chitosan is efficiently utilized in the wastewater treatment by absorption of the suspended materials and formaldehyde due to its molecular structure providing a good electrical property.

  10. Waste treatment by reverse osmosis and membrane processing. (Latest citations from the NTIS Bibliographic database). Published Search

    SciTech Connect

    Not Available

    1994-11-01

    The bibliography contains citations concerning the technology of reverse osmosis and membrane processing in sewage and industrial waste treatment. Citations discuss ultrafiltration, industrial water reuse, hazardous waste treatment, municipal wastes, and materials recovery. Waste reduction and recycling in electroplating, metal finishing, and circuit board manufacturing are considered. (Contains 250 citations and includes a subject term index and title list.)

  11. Waste treatment by reverse osmosis and membrane processing. (Latest citations from the NTIS bibliographic database). Published Search

    SciTech Connect

    Not Available

    1994-03-01

    The bibliography contains citations concerning the technology of reverse osmosis and membrane processing in sewage and industrial waste treatment. Citations discuss ultrafiltration, industrial water reuse, hazardous waste treatment, municipal wastes, and materials recovery. Waste reduction and recycling in electroplating, metal finishing, and circuit board manufacturing are considered. (Contains a minimum of 245 citations and includes a subject term index and title list.)

  12. 40 CFR 721.10636 - Slimes and sludges, automotive coating, wastewater treatment, solid waste.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ..., wastewater treatment, solid waste. 721.10636 Section 721.10636 Protection of Environment ENVIRONMENTAL..., wastewater treatment, solid waste. (a) Chemical substance and significant new uses subject to reporting. (1) The chemical substance identified as slimes and sludges, automotive coating, wastewater...

  13. 40 CFR 721.10636 - Slimes and sludges, automotive coating, wastewater treatment, solid waste.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ..., wastewater treatment, solid waste. 721.10636 Section 721.10636 Protection of Environment ENVIRONMENTAL..., wastewater treatment, solid waste. (a) Chemical substance and significant new uses subject to reporting. (1) The chemical substance identified as slimes and sludges, automotive coating, wastewater...

  14. Pyrolysis/Steam Reforming Technology for Treatment of TRU Orphan Wastes

    SciTech Connect

    Mason, J. B.; McKibbin, J.; Schmoker, D.; Bacala, P.

    2003-02-27

    Certain transuranic (TRU) waste streams within the Department of Energy (DOE) complex cannot be disposed of at the Waste Isolation Pilot Plant (WIPP) because they do not meet the shipping requirements of the TRUPACT-II or the disposal requirements of the Waste Analysis Plan (WAP) in the WIPP RCRA Part B Permit. These waste streams, referred to as orphan wastes, cannot be shipped or disposed of because they contain one or more prohibited items, such as liquids, volatile organic compounds (VOCs), hydrogen gas, corrosive acids or bases, reactive metals, or high concentrations of polychlorinated biphenyl (PCB), etc. The patented, non-incineration, pyrolysis and steam reforming processes marketed by THOR Treatment Technologies LLC removes all of these prohibited items from drums of TRU waste and produces a dry, inert, inorganic waste material that meets the existing TRUPACT-II requirements for shipping, as well as the existing WAP requirements for disposal of TRU waste at WIPP. THOR Treatment Technologies is a joint venture formed in June 2002 by Studsvik, Inc. (Studsvik) and Westinghouse Government Environmental Services Company LLC (WGES) to further develop and deploy Studsvik's patented THORSM technology within the DOE and Department of Defense (DoD) markets. The THORSM treatment process is a commercially proven system that has treated over 100,000 cu. ft. of nuclear waste from commercial power plants since 1999. Some of this waste has had contact dose rates of up to 400 R/hr. A distinguishing characteristic of the THORSM process for TRU waste treatment is the ability to treat drums of waste without removing the waste contents from the drum. This feature greatly minimizes criticality and contamination issues for processing of plutonium-containing wastes. The novel features described herein are protected by issued and pending patents.

  15. DEMONSTRATION OF SIMULATED WASTE TRANSFERS FROM TANK AY-102 TO THE HANFORD WASTE TREATMENT FACILITY

    SciTech Connect

    Adamson, D.; Poirier, M.; Steeper, T.

    2009-12-03

    In support of Hanford's AY-102 Tank waste certification and delivery of the waste to the Waste Treatment and Immobilization Plant (WTP), Savannah River National Laboratory (SRNL) was tasked by the Washington River Protection Solutions (WRPS) to evaluate the effectiveness of mixing and transferring the waste in the Double Shell Tank (DST) to the WTP Receipt Tank. This work is a follow-on to the previous 'Demonstration of Internal Structures Impacts on Double Shell Tank Mixing Effectiveness' task conducted at SRNL 1. The objective of these transfers was to qualitatively demonstrate how well waste can be transferred out of a mixed DST tank and to provide insights into the consistency between the batches being transferred. Twelve (12) different transfer demonstrations were performed, varying one parameter at a time, in the Batch Transfer Demonstration System. The work focused on visual comparisons of the results from transferring six batches of slurry from a 1/22nd scale (geometric by diameter) Mixing Demonstration Tank (MDT) to six Receipt Tanks, where the consistency of solids in each batch could be compared. The simulant used in this demonstration was composed of simulated Hanford Tank AZ-101 supernate, gibbsite particles, and silicon carbide particles, the same simulant/solid particles used in the previous mixing demonstration. Changing a test parameter may have had a small impact on total solids transferred from the MDT on a given test, but the data indicates that there is essentially no impact on the consistency of solids transferred batch to batch. Of the multiple parameters varied during testing, it was found that changing the nozzle velocity of the Mixer Jet Pumps (MJPs) had the biggest impact on the amount of solids transferred. When the MJPs were operating at 8.0 gpm (22.4 ft/s nozzle velocity, U{sub o}D=0.504 ft{sup 2}/s), the solid particles were more effectively suspended, thus producing a higher volume of solids transferred. When the MJP flow rate was

  16. Importance of biological systems in industrial waste treatment potential application to the space station

    NASA Technical Reports Server (NTRS)

    Revis, Nathaniel; Holdsworth, George

    1990-01-01

    In addition to having applications for waste management issues on planet Earth, microbial systems have application in reducing waste volumes aboard spacecraft. A candidate for such an application is the space station. Many of the planned experiments generate aqueous waste. To recycle air and water the contaminants from previous experiments must be removed before the air and water can be used for other experiments. This can be achieved using microorganisms in a bioreactor. Potential bioreactors (inorganics, organics, and etchants) are discussed. Current technologies that may be applied to waste treatment are described. Examples of how biological systems may be used in treating waste on the space station.

  17. Advanced waste form and Melter development for treatment of troublesome high-level wastes

    SciTech Connect

    Marra, James; Kim, Dong -Sang; Maio, Vincent

    2015-10-01

    A number of waste components in US defense high level radioactive wastes (HLW) have proven challenging for current Joule heated ceramic melter (JHCM) operations and have limited the ability to increase waste loadings beyond already realized levels. Many of these “troublesome" waste species cause crystallization in the glass melt that can negatively impact product quality or have a deleterious effect on melter processing. Recent efforts at US Department of Energy laboratories have focused on understanding crystallization behavior within HLW glass melts and investigating approaches to mitigate the impacts of crystallization so that increases in waste loading can be realized. Advanced glass formulations have been developed to highlight the unique benefits of next-generation melter technologies such as the Cold Crucible Induction Melter (CCIM). Crystal-tolerant HLW glasses have been investigated to allow sparingly soluble components such as chromium to crystallize in the melter but pass out of the melter before accumulating.The Hanford site AZ-101 tank waste composition represents a waste group that is waste loading limited primarily due to high concentrations of Fe2O3 (also with high Al2O3 concentrations). Systematic glass formulation development utilizing slightly higher process temperatures and higher tolerance to spinel crystals demonstrated that an increase in waste loading of more than 20% could be achieved for this waste composition, and by extension higher loadings for wastes in the same group. An extended duration CCIM melter test was conducted on an AZ-101 waste simulant using the CCIM platform at the Idaho National Laboratory (INL). The melter was continually operated for approximately 80 hours demonstrating that the AZ-101 high waste loading glass composition could be readily processed using the CCIM technology. The resulting glass was close to the targeted composition and exhibited excellent durability in both

  18. Characterisation and evaluation of wastes for treatment in the batch pyrolysis plant in Studsvik, Sweden

    SciTech Connect

    Lindberg, Maria; Osterberg, Carl; Vernersson, Thomas

    2013-07-01

    The new batch pyrolysis plant in Studsvik is built primarily for treatment of uranium containing dry active waste, 'DAW'. Several other waste types have been identified that are considered or assumed suitable for treatment in the pyrolysis plant because of the possibility to carefully control the atmosphere and temperature of the thermal treatment. These waste types must be characterised and an evaluation must be made with a BAT (Best Available Technology) perspective. Studsvik have performed or plan to perform lab scale pyrolysis tests on a number of different waste types. These include - Pyrophoric materials (uranium shavings) - Uranium chemicals that must be oxidised prior to being deposited in repository - Sludges and oil soaks (this category includes NORM materials) - Ion exchange resins (both 'free' and solidified/stabilised) - Bitumen solidified waste Methodology and assessment criteria for various waste types, together with results obtained for the lab scale tests that have been performed, are described. (authors)

  19. Nutrient fate in aquacultural systems for waste treatment

    SciTech Connect

    Dontje, J.H.; Clanton, C.J.

    1999-08-01

    Twelve small, recirculating aquacultural systems were operated for livestock waste treatment to determine nutrient fate. Each system consisted of a 730-L fish tank coupled in a recirculating loop with three sand beds (serving as biofilters) in parallel. Fish (Tilapia species) were grown in the tanks while cattails, reed canary grass, and tomatoes were grown in separate sand beds. Swine waste was added to the fish tanks every other day at average rates of 50, 72, 95, and 118 kg-COD/ha/day of fish tank surface (three replications of each loading rate). Water from the fish tanks was filtered through the sand beds three times per day with 20% of the tank volume passing through the sand each day. The systems were operated in a greenhouse for eight months (21 July to 8 March). Aboveground plant matter was harvested at eight-week intervals. The fish were removed after four months and the tanks were restocked with fingerlings. Initial and final nitrogen (N), phosphorus (P), and potassium (K) contents of the system components, as well as that of the harvested plants and fish, were determined. Nutrient balance calculations revealed that 30 to 68% of added N was lost from the systems, probably via denitrification. Nutrient removal by plants was 6 to 18% for N, 8 to 21% for P, and 25 to 71% for K, with tomatoes (foliage and fruit) accounting for the majority of the removal. Plant growth was limited by growing conditions (particularly day length), not be nutrient availability. Fish growth was limited by temperature; thus nutrient extraction by the fish was minimal. Under the conditions of this experiment, the system required supplemental aeration.

  20. Geothermal waste treatment biotechnology: Progress and advantages to the utilities

    SciTech Connect

    Premuzic, E.T.; Lin, M.S.; Jin, J.

    1992-03-01

    Development of biotechnology for treatment of geothermal residual waste is aimed at the application of low-cost biochemical processes for the surface treatment and disposal of residual geothermal sludges. These processes, in addition to the lowering of disposal cost, are designed to be environmentally acceptable. Recent studies at Brookhaven National Laboratory (BNL) have shown that optimization of several process variables results in fast rates (<24h) of metal removal from residual sludges at acidic pH ({minus}1--2). Optimization of the process variables also enables the removal of radioactive isotopes. In addition, the aqueous phase produced during the bioprocessing which contains solubilized metals can be further treated in a manner which precipitates out the metals and renders the aqueous effluent toxic metal free. In this paper, the various process options will be discussed in terms of biotreatment variables. Chemical composition before and after biotreatment will also be discussed in terms of long-range effects, quality assurance and potential disposal costs.

  1. Geothermal Waste Treatment Biotechnology: Progress and Advantages to the Utilities

    SciTech Connect

    Premuzic, E.T.; Lin, M.S.; Jin, J.

    1992-03-24

    Development of biotechnology for treatment of geothermal residual waste is aimed at the application of low-cost biochemical processes for the surface treatment and disposal of residual geothermal sludges. These processes, in addition to the lowering of disposal cost, are designed to be environmentally acceptable. Recent studies at Brookhaven National Laboratory (BNL) have shown that optimization of several process variables results in fast rates (<24h) of metal removal from residual sludges at acidic pH ({approx}1-2). Optimization of the process variables also enables the removal of radioactive isotopes. In addition, the aqueous phase produced during the bioprocessing which contains solubilized metals can be further treated in a manner which precipitates out the metals and renders the aqueous effluent toxic metal free. In this paper, the various process options will be discussed in terms of biotreatment variables. Chemical composition before and after biotreatment will also be discussed in terms of long-range effects, quality assurance and potential disposal costs.

  2. Recycling of PVC Waste via Environmental Friendly Vapor Treatment

    NASA Astrophysics Data System (ADS)

    Cui, Xin; Jin, Fangming; Zhang, Guangyi; Duan, Xiaokun

    2010-11-01

    This paper focused on the dechlorination of polyvinyl chloride (PVC), a plastic which is widely used in the human life and thereby is leading to serious "white pollution", via vapor treatment process to recycle PVC wastes. In the process, HCl emitted was captured into water solution to avoid hazardous gas pollution and corruption, and remaining polymers free of chlorine could be thermally degraded for further energy recovery. Optimal conditions for the dechlorination of PVC using vapor treatment was investigated, and economic feasibility of this method was also analyzed based on the experimental data. The results showed that the efficiency of dechlorination increased as the temperature increased from 200° C to 250° C, and the rate of dechlorination up to 100% was obtained at the temperature near 250° C. Meanwhile, about 12% of total organic carbon was detected in water solution, which indicated that PVC was slightly degraded in this process. The main products in solution were identified to be acetone, benzene and toluene. In addition, the effects of alkali catalysis on dechlorination were also studied in this paper, and it showed that alkali could not improve the efficiency of the dechlorination of PVC.

  3. Biological treatment of distillery waste for pollution-remediation.

    PubMed

    Fitzgibbon, F J; Nigam, P; Singh, D; Marchant, R

    1995-01-01

    The biological treatment of spent wash from molasses distilleries was investigated. Analysis of raw spent wash showed it to be a recalcitrant waste, with a high COD of 85,170 mg/l and containing inhibitory phenolic compounds. Reverse phase thin layer chromatography identified gallic and vanillic acid present in spent wash. The fungi Geotrichum candidum, Coriolus versicolor, Phanerochaete chrysosporium and Mycelia sterilia were screened for their ability to decolourize spent wash and to reduce the COD level. A 10 day pretreatment with Geotrichum candidum at 30 degrees C resulted in reducing the COD by 53.17% and total phenols by 47.82%, enabling other bioremediating organisms to grow. Coriolus versicolor immobilized in a packed-bed reactor reduced the COD of spent wash by a further 50.3%, giving an overall reduction in COD of 77% to 15,780 mg/l. A small amount of decolourization was achieved (4.2%), although the spent wash was still coloured. Present studies are encouraging and indicate that it is possible to bioremediate spent wash using a multi-stage treatment process involving an initial pretreatment step with Geotrichum candidum.

  4. Redox alloy media as a water treatment technology for the removal and minimization of waste

    SciTech Connect

    Al-Kharusy, I.S.

    1996-12-31

    Oxidation/reduction (REDOX) alloy media, as used in wastewater treatment, is founded on the exchange of electrons. Because of this electron exchange, many contaminants are converted to harmless components which require no further treatment. Other types of contaminants are removed from the waste stream by electrochemically bonding to the alloy medium. This paper discusses the REDOX reactions, the role of the alloy medium in various treatment processes, and describes specific applications of REDOX alloy media for the removal and minimization of waste. The characteristics and handling of spent treatment media is also reviewed as a further consideration in waste minimization.

  5. The status and developments of leather solid waste treatment: A mini-review.

    PubMed

    Jiang, Huiyan; Liu, Junsheng; Han, Wei

    2016-05-01

    Leather making is one of the most widespread industries in the world. The production of leather goods generates different types of solid wastes and wastewater. These wastes will pollute the environment and threat the health of human beings if they are not well treated. Consequently, the treatment of pollution caused by the wastes from leather tanning is really important. In comparison with the disposal of leather wastewater, the treatment of leather solid wastes is more intractable. Hence, the treatment of leather solid wastes needs more innovations. To keep up with the rapid development of the modern leather industry, various innovative techniques have been newly developed. In this mini-review article, the major achievements in the treatment of leather solid wastes are highlighted. Emphasis will be placed on the treatment of chromium-tanned solid wastes; some new approaches are also discussed. We hope that this mini-review can provide some valuable information to promote the broad understanding and effective treatment of leather solid wastes in the leather industry.

  6. Report: transboundary hazardous waste management. part II: performance auditing of treatment facilities in importing countries.

    PubMed

    Chang, Tien-Chin; Ni, Shih-Piao; Fan, Kuo-Shuh; Lee, Ching-Hwa

    2006-06-01

    Before implementing the self-monitoring model programme of the Basel Convention in the Asia, Taiwan has conducted a comprehensive 4-year follow-up project to visit the governmental authorities and waste-disposal facilities in the countries that import waste from Taiwan. A total of nine treatment facilities, six of which are reported in this paper, and the five countries where the plants are located were visited in 2001-2002. France, Belgium and Finland primarily handled polychlorinated biphenyl capacitors, steel mill dust and metal waste. The United States accepted metal sludge, mainly electroplating sludge, from Taiwan. Waste printed circuit boards, waste wires and cables, and a mixture of waste metals and electronics were the major items exported to China. Relatively speaking, most treatment plants for hazardous waste paid close attention to environmental management, such as pollution control and monitoring, site zoning, system management regarding occupational safety and hygiene, data management, permits application, and image promotion. Under the tight restrictions formulated by the central environment agency, waste treatment plants in China managed the environmental issues seriously. For example, one of the treatment plants had ISO 14001 certification. It is believed that with continuous implementation of regulations, more improvement is foreseeable. Meanwhile, Taiwan and China should also continuously enhance their collaboration regarding the transboundary management of hazardous waste.

  7. Characterization of oil and gas waste disposal practices and assessment of treatment costs. Final report

    SciTech Connect

    Bedient, P.B.

    1995-01-16

    This study examines wastes associated with the onshore exploration and production of crude oil and natural gas in the US. The objective of this study was to update and enhance the current state of knowledge with regard to oil and gas waste quantities, the potential environmental impact of these wastes, potential methods of treatment, and the costs associated with meeting various degrees of treatment. To meet this objective, the study consisted of three tasks: (1) the development of a production Environmental Database (PED) for the purpose of assessing current oil and gas waste volumes by state and for investigating the potential environmental impacts associated with current waste disposal practices on a local scale; (2) the evaluation of available and developing technologies for treating produced water waste streams and the identification of unit process configurations; and (3) the evaluation of the costs associated with various degrees of treatment achievable by different treatment configurations. The evaluation of feasible technologies for the treatment of produced water waste streams was handled in the context of comparing the level of treatment achievable with the associated cost of treatment. Treatment processes were evaluated for the removal of four categories of produced water contaminants: particulate material, volatile organic compounds, adsorbable organic compounds, and dissolved inorganic species. Results showed dissolved inorganic species to be the most costly to remove. The potential cost of treating all 18.3 billion barrels of produced water generated in a year amounts to some 15 billion dollars annually.

  8. Sample Results From Tank 48H Samples HTF-48-14-158, -159, -169, and -170

    SciTech Connect

    Peters, T.; Hang, T.

    2015-04-28

    Savannah River National Laboratory (SRNL) analyzed samples from Tank 48H in support of determining the cause for the unusually high dose rates at the sampling points for this tank. A set of two samples was taken from the quiescent tank, and two additional samples were taken after the contents of the tank were mixed. The results of the analyses of all the samples show that the contents of the tank have changed very little since the analysis of the previous sample in 2012. The solids are almost exclusively composed of tetraphenylborate (TPB) salts, and there is no indication of acceleration in the TPB decomposition. The filtrate composition shows a moderate increase in salt concentration and density, which is attributable to the addition of NaOH for the purposes of corrosion control. An older modeling simulation of the TPB degradation was updated, and the supernate results from a 2012 sample were run in the model. This result was compared to the results from the 2014 recent sample results reported in this document. The model indicates there is no change in the TPB degradation from 2012 to 2014. SRNL measured the buoyancy of the TPB solids in Tank 48H simulant solutions. It was determined that a solution of density 1.279 g/mL (~6.5M sodium) was capable of indefinitely suspending the TPB solids evenly throughout the solution. A solution of density 1.296 g/mL (~7M sodium) caused a significant fraction of the solids to float on the solution surface. As the experiments could not include the effect of additional buoyancy elements such as benzene or hydrogen generation, the buoyancy measurements provide an upper bound estimate of the density in Tank 48H required to float the solids.

  9. Fluid dynamic demonstrations for waste retrieval and treatment

    SciTech Connect

    Youngblood, E.L. Jr.; Hylton, T.D.; Berry, J.B.; Cummins, R.L.; Ruppel, F.R.; Hanks, R.W.

    1994-02-01

    The objective of this study was to develop or identify flow correlations for predicting the flow parameters needed for the design and operation of slurry pipeline systems for transporting radioactive waste of the type stored in the Hanford single-shell tanks and the type stored at the Oak Ridge National Laboratory (ORNL). This was done by studying the flow characteristics of simulated waste with rheological properties similar to those of the actual waste. Chemical simulants with rheological properties similar to those of the waste stored in the Hanford single-shell tanks were developed by Pacific Northwest Laboratories, and simulated waste with properties similar to those of ORNL waste was developed at ORNL for use in the tests. Rheological properties and flow characteristics of the simulated slurry were studied in a test loop in which the slurry was circulated through three pipeline viscometers (constructed of 1/2-, 3/4-, and 1-in. schedule 40 pipe) at flow rates up to 35 gal/min. Runs were made with ORNL simulated waste at 54 wt % to 65 wt % total solids and temperatures of 25{degree}C and 55{degree}C. Grinding was done prior to one run to study the effect of reduced particle size. Runs were made with simulated Hanford single-shell tank waste at approximately 43 wt % total solids and at temperatures of 25{degree}C and 50{degree}C. The rheology of simulated Hanford and ORNL waste supernatant liquid was also measured.

  10. One System Integrated Project Team: Retrieval and Delivery of Hanford Tank Wastes for Vitrification in the Waste Treatment Plant - 13234

    SciTech Connect

    Harp, Benton J.; Kacich, Richard M.; Skwarek, Raymond J.

    2013-07-01

    The One System Integrated Project Team (IPT) was formed in late 2011 as a way for improving the efficiency of delivery and treatment of highly radioactive waste stored in underground tanks at the U.S. Department of Energy's (DOE's) 586-square-mile Hanford Site in southeastern Washington State. The purpose of the One System IPT is to improve coordination and integration between the Hanford's Waste Treatment Plant (WTP) contractor and the Tank Operations Contractor (TOC). The vision statement is: One System is a WTP and TOC safety-conscious team that, through integrated management and implementation of risk-informed decision and mission-based solutions, will enable the earliest start of safe and efficient treatment of Hanford's tank waste, to protect the Columbia River, environment and public. The IPT is a formal collaboration between Bechtel National, Inc. (BNI), which manages design and construction of the WTP for the U.S. Department of Energy's Office of River Protection (DOEORP), and Washington River Protection Solutions (WRPS), which manages the TOC for ORP. More than fifty-six (56) million gallons of highly radioactive liquid waste are stored in one hundred seventy-seven (177) aging, underground tanks. Most of Hanford's waste tanks - one hundred forty-nine (149) of them - are of an old single-shell tank (SST) design built between 1944 and 1964. More than sixty (60) of these tanks have leaked in the past, releasing an estimated one million gallons of waste into the soil and threatening the nearby Columbia River. There are another twenty-eight (28) new double-shelled tanks (DSTs), built from 1968 to 1986, that provide greater protection to the environment. In 1989, DOE, the U.S. Environmental Protection Agency (EPA), and the Washington State Department of Ecology (Ecology) signed a landmark agreement that required Hanford to comply with federal and state environmental standards. It also paved the way for agreements that set deadlines for retrieving the tank

  11. One System Integrated Project Team: Retrieval And Delivery Of The Hanford Tank Wastes For Vitrification In The Waste Treatment Plant

    SciTech Connect

    Harp, Benton J.; Kacich, Richard M.; Skwarek, Raymond J.

    2012-12-20

    The One System Integrated Project Team (IPT) was formed in late 2011 as a way for improving the efficiency of delivery and treatment of highly radioactive waste stored in underground tanks at the U.S. Department of Energy's (DOE's) 586-square-mile Hanford Site in southeastern Washington State. The purpose of the One System IPT is to improve coordination and integration between the Hanford's Waste Treatment Plant (WTP) contractor and the Tank Operations Contractor (TOC). The vision statement is: One System is a WTP and TOC safety conscious team that, through integrated management and implementation of risk-informed decision and mission-based solutions, will enable the earliest start of safe and efficient treatment of Hanford's tank waste, to protect the Columbia River, environment and public. The IPT is a formal collaboration between Bechtel National, Inc. (BNI), which manages design and construction of the WTP for the U.S. Department of Energy's Office of River Protection (DOEORP), and Washington River Protection Solutions (WRPS), which manages the TOC for ORP. More than fifty-six (56) million gallons of highly radioactive liquid waste are stored in one hundred seventy-seven (177) aging, underground tanks. Most of Hanford's waste tanks - one hundred forty-nine (149) of them - are of an old single-shell tank (SST) design built between 1944 and 1964. More than sixty (60) of these tanks have leaked in the past, releasing an estimated one million gallons of waste into the soil and threatening the nearby Columbia River. There are another twenty-eight (28) new double-shelled tanks (DSTs), built from 1968 to 1986, that provide greater protection to the environment. In 1989, DOE, the U.S. Environmental Protection Agency (EPA), and the Washington State Department of Ecology (Ecology) signed a landmark agreement that required Hanford to comply with federal and state environmental standards. It also paved the way for agreements that set deadlines for retrieving the tank

  12. The relationship of total copper 48-h LC50s to Daphnia magna dry weight

    SciTech Connect

    Lazorchak, J.M. ); Waller, W.T. )

    1993-05-01

    A study was conducted with Daphnia magna to determine the effect of neonate weight loss or lack of weight gain on experimentally derived copper 48-h LC50s. Standard unfed tests as well as algal-fed (Selenastrum capricornutum) tests were used to look at weight loss and gain. No significant relationship was found between amount of weight loss and copper LC50s. However, dry weight of unfed and algal-fed control organisms could be used to predict total copper LC50s.

  13. Second international symposium on extraction and processing for the treatment and minimization of wastes - 1996

    SciTech Connect

    Ramachandran, V.; Nesbitt, C.C.

    1996-12-31

    This volume contains 71 papers presented at the Second International symposium on Extraction and Processing for the Treatment and Minimization of Wastes. 21 papers were selected for the database. The papers selected covered topics in chemical, environmental, and mechanical engineering related to radioactive and nonradioactive wastes. Specific topics include spent catalyst processing of petroleum refinery wastes; redox alloy for water treatment; thermodynamic modeling of uranium fluoride waste processing; calcination of radioactive wastes; geochemical modeling of radioactive waste processing; removal and/or stabilization of arsenic, selenium, mercury, lead and other metals from soils and ground water; pond dredging and dewatering; options for complying with water quality based metal limitations; removal of thorium from ilmenite; and electroslag remelting of fusion reactor vanadium alloy.

  14. US Department of Energy interim mixed waste inventory report: Waste streams, treatment capacities and technologies: Volume 2, Site specific---California through Idaho. [Waste mixtures of hazardous materials and low-level radioactive wastes or transuranic wastes

    SciTech Connect

    Not Available

    1993-04-01

    The Department of Energy (DOE) has prepared this report to provide an inventory of its mixed wastes and treatment capacities and technologies in response to Section 105(a) of the Federal Facility Compliance act (FFCAct) of 1992 (Pub. L. No. 102-386). As required by the FFCAct-1992, this report provide site-specific information on DOE's mixed waste streams and a general review of available and planned treatment facilities for mixed wastes for the following sites: eight California facilities which are Energy Technology engineering Center, General Atomics, General Electric Vallecitos Nuclear Center, Lawrence Berkeley Laboratory, Lawrence Livermore National Laboratory, Laboratory for Energy-Related Health Research, Mare Island Naval Shipyard, and Sandia national Laboratories; Grand Junction Project Office; Rocky Flats Plant; Knolls Atomic Power Laboratory-Windsor Site; Pinellas Plant; Pearl Harbor Naval Shipyard; Argonne National Laboratory-West; and Idaho National Engineering Laboratory.

  15. Mixed and Low-Level Waste Treatment Facility project. Executive summary: Volume 1, Program summary information; Volume 2, Waste stream technical summary: Draft

    SciTech Connect

    Not Available

    1992-04-01

    Mixed and low-level wastes generated at the Idaho National Engineering Laboratory (INEL) are required to be managed according to applicable State and Federal regulations, and Department of Energy Orders that provide for the protection of human health and the environment. The Mixed and Low-Level Waste Treatment Facility Project was chartered in 1991, by the Department of Energy to provide treatment capability for these mixed and low-level waste streams. The first project task consisted of conducting engineering studies to identify the waste streams, their potential treatment strategies, and the requirements that would be imposed on the waste streams and the facilities used to process them. The engineering studies, initiated in July 1991, identified 37 mixed waste streams, and 55 low-level waste streams. This report documents the waste stream information and potential treatment strategies, as well as the regulatory requirements for the Department of Energy-owned treatment facility option. The total report comprises three volumes and two appendices. This report consists of Volume 1, which explains the overall program mission, the guiding assumptions for the engineering studies, and summarizes the waste stream and regulatory information, and Volume 2, the Waste Stream Technical Summary which, encompasses the studies conducted to identify the INEL`s waste streams and their potential treatment strategies.

  16. Nutrient abatement potential and abatement costs of waste water treatment plants in the Baltic Sea region.

    PubMed

    Hautakangas, Sami; Ollikainen, Markku; Aarnos, Kari; Rantanen, Pirjo

    2014-04-01

    We assess the physical potential to reduce nutrient loads from waste water treatment plants in the Baltic Sea region and determine the costs of abating nutrients based on the estimated potential. We take a sample of waste water treatment plants of different size classes and generalize its properties to the whole population of waste water treatment plants. Based on a detailed investment and operational cost data on actual plants, we develop the total and marginal abatement cost functions for both nutrients. To our knowledge, our study is the first of its kind; there is no other study on this issue which would take advantage of detailed data on waste water treatment plants at this extent. We demonstrate that the reduction potential of nutrients is huge in waste water treatment plants. Increasing the abatement in waste water treatment plants can result in 70 % of the Baltic Sea Action Plan nitrogen reduction target and 80 % of the Baltic Sea Action Plan phosphorus reduction target. Another good finding is that the costs of reducing both nutrients are much lower than previously thought. The large reduction of nitrogen would cost 670 million euros and of phosphorus 150 million euros. We show that especially for phosphorus the abatement costs in agriculture would be much higher than in waste water treatment plants.

  17. Utilization of Waste Materials for Microbial Carrier in Wastewater Treatment

    PubMed Central

    Le, H. T.; Jantarat, N.

    2016-01-01

    This research focused on the ammonium-nitrogen (NH4-N) removal from the domestic wastewater using the attached growth reactors. Two types of waste material of corncob (biodegradable material) and concrete (nonbiodegradable material) were used as the carrier for microorganisms' attachment. During operation, both reactors achieved absolutely high performance of ammonium removal (up to 99%) and total nitrogen removal (up to 95%). The significant advantage of corncob carrier was that the corncob was able to be a source of carbon for biological denitrification, leading to no external carbon requirement for operating the system. However, the corncob caused an increasing turbidity of the effluent. On the other hand, the concrete carrier required the minimal external carbon of 3.5 C/N ratio to reach the good performance. Moreover, a longer period for microorganisms' adaptation was found in the concrete carrier rather than the corncob carrier. Further, the same physiological and biochemical characteristics of active bacteria were found at the two carriers, which were negative gram, cocci shape, and smooth and white-turbid colony. Due to the effluent quality, the concrete was more appropriate carrier than the corncob for wastewater treatment. PMID:27525274

  18. Radioactive Liquid Waste Treatment Facility Discharges in 2011

    SciTech Connect

    Del Signore, John C.

    2012-05-16

    This report documents radioactive discharges from the TA50 Radioactive Liquid Waste Treatment Facilities (RLWTF) during calendar 2011. During 2011, three pathways were available for the discharge of treated water to the environment: discharge as water through NPDES Outfall 051 into Mortandad Canyon, evaporation via the TA50 cooling towers, and evaporation using the newly-installed natural-gas effluent evaporator at TA50. Only one of these pathways was used; all treated water (3,352,890 liters) was fed to the effluent evaporator. The quality of treated water was established by collecting a weekly grab sample of water being fed to the effluent evaporator. Forty weekly samples were collected; each was analyzed for gross alpha, gross beta, and tritium. Weekly samples were also composited at the end of each month. These flow-weighted composite samples were then analyzed for 37 radioisotopes: nine alpha-emitting isotopes, 27 beta emitters, and tritium. These monthly analyses were used to estimate the radioactive content of treated water fed to the effluent evaporator. Table 1 summarizes this information. The concentrations and quantities of radioactivity in Table 1 are for treated water fed to the evaporator. Amounts of radioactivity discharged to the environment through the evaporator stack were likely smaller since only entrained materials would exit via the evaporator stack.

  19. Utilization of Waste Materials for Microbial Carrier in Wastewater Treatment.

    PubMed

    Le, H T; Jantarat, N; Khanitchaidecha, W; Ratananikom, K; Nakaruk, A

    2016-01-01

    This research focused on the ammonium-nitrogen (NH4-N) removal from the domestic wastewater using the attached growth reactors. Two types of waste material of corncob (biodegradable material) and concrete (nonbiodegradable material) were used as the carrier for microorganisms' attachment. During operation, both reactors achieved absolutely high performance of ammonium removal (up to 99%) and total nitrogen removal (up to 95%). The significant advantage of corncob carrier was that the corncob was able to be a source of carbon for biological denitrification, leading to no external carbon requirement for operating the system. However, the corncob caused an increasing turbidity of the effluent. On the other hand, the concrete carrier required the minimal external carbon of 3.5 C/N ratio to reach the good performance. Moreover, a longer period for microorganisms' adaptation was found in the concrete carrier rather than the corncob carrier. Further, the same physiological and biochemical characteristics of active bacteria were found at the two carriers, which were negative gram, cocci shape, and smooth and white-turbid colony. Due to the effluent quality, the concrete was more appropriate carrier than the corncob for wastewater treatment.

  20. Treatment of phosphogypsum waste using suitable organic extractants.

    PubMed

    El-Didamony, H; Ali, M M; Awwad, N S; Fawzy, M M; Attallah, M F

    Phosphogypsum (PG) is a residue of the phosphate fertilizer industry that has relatively high concentrations of harmful radioactive materials. The reduction in concentration of the radionuclides from PG was investigated. The removal process is based on leaching of radionuclides using suitable organic extractants. The studied radionuclides were (226)Ra, (210)Pb, (238)U and (40)K. The factors affect the leaching process such as type of leaching materials, contact time, concentration of the desired solvent, liquid to solid ratio, and temperature were studied. Based on the experimental results, about 71.1, 76.4, 62.4, and 75.7% of (226)Ra, (210)Pb, (238)U and (40)K respectively were successfully removed from the PG. The reduction in the concentration of radionuclides was accompanied by reduction in the concentration of rare earth elements (∑REE) equals to 69.8%. Using the desired organic extractant under optimum conditions for treatment of the PG waste leads to obtain a decontaminated product that can be safely used in many industrial applications.

  1. Treatment of phosphogypsum waste produced from phosphate ore processing.

    PubMed

    El-Didamony, H; Gado, H S; Awwad, N S; Fawzy, M M; Attallah, M F

    2013-01-15

    Phosphogypsum (PG), primary byproduct from phosphoric acid production, is accumulated in large stockpiles and occupies vast areas of land. Phosphogypsum is a technologically enhanced naturally occurring radioactive material (TE-NORM) that contains radionuclides from (238)U and (232)Th decay series which are of most radio-toxicity. The reduction in concentration of radionuclides content from PG was based on leaching of (226)Ra, (210)Pb, (238)U and (40)K using tri-butyl phosphate (TBP) and tri-octyl phosphine oxide (TOPO) in kerosene. The factors which affect the leaching process such as contact time, concentration of the solvent and temperature were optimized. Based on the experimental results, about 92.1, 88.9, 83.4, 94.6% of (226)Ra, (210)Pb, (238)U and (40)K respectively were successfully removed from the PG. The reduction in the concentration of radionuclides was accompanied by reduction in the concentration of rare earth elements (∑REE) equals to 80.1%. Using the desired organic extractant under optimum conditions for treatment of the PG waste leads to obtain a decontaminated product that can be safely used in many industrial applications.

  2. Evaluation of pristine lignin for hazardous-waste treatment

    SciTech Connect

    O'Neil, D.J.; Newman, C.J.; Chian, E.S.K.; Gao, H.

    1987-05-01

    A feasibility study was conducted to assess the utilization of lignin, isolated from a steam-exploded hardwood (Tulip poplar) with 95% ethanol and 0.1n NaOH, as a potential adsorbent for hazardous-waste treatment. Eight organic compounds and two heavy metals were selected to allow comparison of lignin isolates with activated carbon. It was found that the adsorption capacity of lignin for heavy metals (chromium and lead) is comparable to activated carbon, despite a huge divergence in surface area (0.1 mS/g vs. 1000 mS/g). The surface area discrepancy and the extensive aromatic substitution in lignin macromolecule impeded the achievement of an adsorption capacity of lignin for polar organic compounds which would allow it to be cost-competitive with activated carbon although results with phenol and, to a lesser degree, naphthalene indicate significant potential for achieving competitive capacities. A recommended plan for surface area and structural enhancement is presented on the basis that lignin can be developed as an effective and low-cost adsorbent for polar priority pollutants and/or as an ion-exchange resins for heavy-metal wastewater clean-up.

  3. Sampling and Analysis Plan Waste Treatment Plant Seismic Boreholes Project.

    SciTech Connect

    Brouns, Thomas M.

    2007-07-15

    This sampling and analysis plan (SAP) describes planned data collection activities for four entry boreholes through the sediment overlying the Saddle Mountains Basalt, up to three new deep rotary boreholes through the Saddle Mountains Basalt and sedimentary interbeds, and one corehole through the Saddle Mountains Basalt and sedimentary interbeds at the Waste Treatment Plant (WTP) site. The SAP will be used in concert with the quality assurance plan for the project to guide the procedure development and data collection activities needed to support borehole drilling, geophysical measurements, and sampling. This SAP identifies the American Society of Testing Materials standards, Hanford Site procedures, and other guidance to be followed for data collection activities. Revision 3 incorporates all interim change notices (ICN) that were issued to Revision 2 prior to completion of sampling and analysis activities for the WTP Seismic Boreholes Project. This revision also incorporates changes to the exact number of samples submitted for dynamic testing as directed by the U.S. Army Corps of Engineers. Revision 3 represents the final version of the SAP.

  4. Advanced waste form and melter development for treatment of troublesome high-level wastes

    SciTech Connect

    Marra, James; Kim, Dong -Sang; Maio, Vincent

    2015-09-02

    A number of waste components in US defense high level radioactive wastes (HLW) have proven challenging for current Joule heated ceramic melter (JHCM) operations and have limited the ability to increase waste loadings beyond already realized levels. Many of these "troublesome" waste species cause crystallization in the glass melt that can negatively impact product quality or have a deleterious effect on melter processing. Recent efforts at US Department of Energy laboratories have focused on understanding crystallization behavior within HLW glass melts and investigating approached to mitigate the impacts of crystallization so that increases in waste loading can be realized. Advanced glass formulations have been developed to highlight the unique benefits of next-generation melter technologies such as the Cold Crucible Induction Melter (CCIM). Crystal-tolerant HLW glasses have been investigated to allow sparingly soluble components such as chromium to crystallize in the melter but pass out of the melter before accumulating.

  5. Effect of co-managing organic waste using municipal wastewater and solid waste treatment systems in megacities.

    PubMed

    Takaoka, Masaki; Oshita, Kazuyuki; Iwamoto, Takahiro; Mizuno, Tadao

    2014-01-01

    A model was developed to calculate the mass and heat balances of wastewater and municipal solid waste treatment plants when these plants operate either separately or together with a mutual dependence on mass and energy. Then the energy consumption, life cycle costs (LCCs), greenhouse gas (GHG) emissions and effluent quality were evaluated under various scenarios to identify the most effective co-management and treatment system. The results indicated that co-digestion of kitchen waste and sewage sludge, and their co-combustion reduced LCCs by 30%, energy consumption by 54% and GHG emissions by 41% compared to the base case. However, co-digestion increased the total nitrogen load in the wastewater treatment plant effluent. Even if an advanced wastewater treatment system was applied to improve total nitrogen concentration, the above indicators were affected but still reduced compared to the base case. Therefore, it was confirmed that the integrated system was beneficial for megacities.

  6. HIGH TEMPERATURE TREATMENT OF INTERMEDIATE-LEVEL RADIOACTIVE WASTES - SIA RADON EXPERIENCE

    SciTech Connect

    Sobolev, I.A.; Dmitriev, S.A.; Lifanov, F.A.; Kobelev, A.P.; Popkov, V.N.; Polkanov, M.A.; Savkin, A.E.; Varlakov, A.P.; Karlin, S.V.; Stefanovsky, S.V.; Karlina, O.K.; Semenov, K.N.

    2003-02-27

    This review describes high temperature methods of low- and intermediate-level radioactive waste (LILW) treatment currently used at SIA Radon. Solid and liquid organic and mixed organic and inorganic wastes are subjected to plasma heating in a shaft furnace with formation of stable leach resistant slag suitable for disposal in near-surface repositories. Liquid inorganic radioactive waste is vitrified in a cold crucible based plant with borosilicate glass productivity up to 75 kg/h. Radioactive silts from settlers are heat-treated at 500-700 0C in electric furnace forming cake following by cake crushing, charging into 200 L barrels and soaking with cement grout. Various thermochemical technologies for decontamination of metallic, asphalt, and concrete surfaces, treatment of organic wastes (spent ion-exchange resins, polymers, medical and biological wastes), batch vitrification of incinerator ashes, calcines, spent inorganic sorbents, contaminated soil, treatment of carbon containing 14C nuclide, reactor graphite, lubricants have been developed and implemented.

  7. Modeling Hydrogen Generation Rates in the Hanford Waste Treatment and Immobilization Plant

    SciTech Connect

    Camaioni, Donald M.; Bryan, Samuel A.; Hallen, Richard T.; Sherwood, David J.; Stock, Leon M.

    2004-03-29

    This presentation describes a project in which Hanford Site and Environmental Management Science Program investigators addressed issues concerning hydrogen generation rates in the Hanford waste treatment and immobilization plant. The hydrogen generation rates of radioactive wastes must be estimated to provide for safe operations. While an existing model satisfactorily predicts rates for quiescent wastes in Hanford underground storage tanks, pretreatment operations will alter the conditions and chemical composition of these wastes. Review of the treatment process flowsheet identified specific issues requiring study to ascertain whether the model would provide conservative values for waste streams in the plant. These include effects of adding hydroxide ion, alpha radiolysis, saturation with air (oxygen) from pulse-jet mixing, treatment with potassium permanganate, organic compounds from degraded ion exchange resins and addition of glass-former chemicals. The effects were systematically investigated through literature review, technical analyses and experimental work.

  8. Application of transformational roasting to the treatment of metallurgical wastes

    NASA Astrophysics Data System (ADS)

    Holloway, Preston Carl

    Transformational roasting involves the heating of a material along with specific additives to induce mineralogical changes in the starting material. By controlling the chemical composition, roasting atmosphere, temperature and time of reaction, the mineral transformations induced during roasting can be engineered to control the distribution of valuable or harmful metals and to produce new mineral assemblages that are more amenable to conventional methods of metals recovery or to environmentally safe disposal. However, to date, transformational roasting processes have only been applied to the recovery of a limited number of metals from a limited number of materials. A generalized procedure for the application of transformational roasting techniques to the treatment of new materials was proposed that utilized a combination of thermodynamic analysis, scoping tests, Design of Experiments (DOE) testing, mineralogical studies, process optimization and analysis of the deportment of minor elements to identify promising roasting systems for further study. This procedure was developed, tested and refined through the application of these techniques to four different industrial metallurgical wastes, including oil sands fly ash from Suncor in northern Alberta, zinc ferrite residue from Doe Run Peru, electric are furnace (EAF) dust from Altasteel's operations in Edmonton, Alberta, and copper-nickel-arsenic sulphide residue from Inco's refinery in Thompson, Manitoba. A large number of potential reagents were identified and tested for the latter three materials and transformational roasting was effectively used to induce mineral transformations during the roasting of these wastes which increased the solubility of valuable elements, decreased the solubility of major impurities, produced a differential solubility between valuable and harmful elements or controlled the volatilization of harmful elements. Comprehensive studies of these mineralogical transformations and the solubility

  9. Radioactive Waste Evaporation: Current Methodologies Employed for the Development, Design, and Operation of Waste Evaporators at the Savannah River Site and Hanford Waste Treatment Plant

    SciTech Connect

    Calloway, T.B.

    2003-09-11

    Evaporation of High level and Low Activity (HLW and LAW) radioactive wastes for the purposes of radionuclide separation and volume reduction has been conducted at the Savannah River and Hanford Sites for more than forty years. Additionally, the Savannah River Site (SRS) has used evaporators in preparing HLW for immobilization into a borosilicate glass matrix. This paper will discuss the methodologies, results, and achievements of the SRTC evaporator development program that was conducted in support of the SRS and Hanford WTP evaporator processes. The cross pollination and application of waste treatment technologies and methods between the Savannah River and Hanford Sites will be highlighted. The cross pollination of technologies and methods is expected to benefit the Department of Energy's Mission Acceleration efforts by reducing the overall cost and time for the development of the baseline waste treatment processes.

  10. Laboratory Evaporation Testing Of Hanford Waste Treatment Plant Low Activity Waste Off-Gas Condensate Simulant

    SciTech Connect

    Adamson, Duane J.; Nash, Charles A.; McCabe, Daniel J.; Crawford, Charles L.; Wilmarth, William R.

    2014-01-27

    The Hanford Waste Treatment and Immobilization Plant (WTP) Low Activity Waste (LAW) vitrification facility will generate an aqueous condensate recycle stream, LAW Off-Gas Condensate, from the off-gas system. The baseline plan for disposition of this stream is to send it to the WTP Pretreatment Facility, where it will be blended with LAW, concentrated by evaporation and recycled to the LAW vitrification facility again. Alternate disposition of this stream would eliminate recycling of problematic components, and would enable de-coupled operation of the LAW melter and the Pretreatment Facilities. Eliminating this stream from recycling within WTP would also decrease the LAW vitrification mission duration and quantity of canistered glass waste forms. This LAW Off-Gas Condensate stream contains components that are volatile at melter temperatures and are problematic for the glass waste form. Because this stream recycles within WTP, these components accumulate in the Condensate stream, exacerbating their impact on the number of LAW glass containers that must be produced. Approximately 32% of the sodium in Supplemental LAW comes from glass formers used to make the extra glass to dilute the halides to be within acceptable concentration ranges in the LAW glass. Diverting the stream reduces the halides in the recycled Condensate and is a key outcome of this work. Additionally, under possible scenarios where the LAW vitrification facility commences operation prior to the WTP Pretreatment facility, identifying a disposition path becomes vitally important. This task examines the impact of potential future disposition of this stream in the Hanford tank farms, and investigates auxiliary evaporation to enable another disposition path. Unless an auxiliary evaporator is used, returning the stream to the tank farms would require evaporation in the 242-A evaporator. This stream is expected to be unusual because it will be very high in corrosive species that are volatile in the melter

  11. 40 CFR 268.43 - Treatment standards expressed as waste concentrations.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... concentrations. 268.43 Section 268.43 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID... as waste concentrations. For the requirements previously found in this section and for treatment standards in Table CCW—Constituent Concentrations in Wastes, refer to § 268.40....

  12. 40 CFR 268.43 - Treatment standards expressed as waste concentrations.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... concentrations. 268.43 Section 268.43 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID... as waste concentrations. For the requirements previously found in this section and for treatment standards in Table CCW—Constituent Concentrations in Wastes, refer to § 268.40....

  13. 40 CFR 268.43 - Treatment standards expressed as waste concentrations.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... concentrations. 268.43 Section 268.43 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID... as waste concentrations. For the requirements previously found in this section and for treatment standards in Table CCW—Constituent Concentrations in Wastes, refer to § 268.40....

  14. 40 CFR 268.43 - Treatment standards expressed as waste concentrations.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... concentrations. 268.43 Section 268.43 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID... as waste concentrations. For the requirements previously found in this section and for treatment standards in Table CCW—Constituent Concentrations in Wastes, refer to § 268.40....

  15. 40 CFR 268.43 - Treatment standards expressed as waste concentrations.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... concentrations. 268.43 Section 268.43 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID... as waste concentrations. For the requirements previously found in this section and for treatment standards in Table CCW—Constituent Concentrations in Wastes, refer to § 268.40....

  16. Project Execution Plan for the River Protection Project Waste Treatment & Immobilization Plant

    SciTech Connect

    MELLINGER, G.B.

    2003-05-03

    The Waste Treatment and Immobilization Plant (WTP), Project W-530, is the cornerstone in the mission of the Hanford Site's cleanup of more than 50 million gallons of highly toxic, high-level radioactive waste contained in aging underground storage tanks.

  17. Alternatives for the treatment and disposal of healthcare wastes in developing countries

    SciTech Connect

    Diaz, L.F. . E-mail: ludiaz@calrecovery.com; Savage, G.M.; Eggerth, L.L.

    2005-07-01

    Waste production in healthcare facilities in developing countries has brought about a variety of concerns due to the use of inappropriate methods of managing the wastes. Inappropriate treatment and final disposal of the wastes can lead to adverse impacts to public health, to occupational health and safety, and to the environment. Unfortunately, most economically developing countries suffer a variety of constraints to adequately managing these wastes. Generally in developing countries, few individuals in the staff of the healthcare facility are familiar with the procedures required for a proper waste management program. Furthermore, the management of wastes usually is delegated to poorly educated laborers who perform most activities without proper guidance and insufficient protection. This paper presents some of the most common treatment and disposal methods utilized in the management of infectious healthcare wastes in developing countries. The methods discussed include: autoclave; microwave; chemical disinfection; combustion (low-, medium-, and high-technology); and disposal on the ground (dump site, controlled landfill, pits, and sanitary landfill). Each alternative for treatment and disposal is explained, including a description of the types of wastes that can and cannot be treated. Background information on the technologies also is included in order to provide information to those who may not be familiar with the details of each alternative. In addition, a brief presentation of some of the emissions from each of the treatment and disposal alternatives is presented.

  18. A&M. Hot liquid waste treatment building (TAN616). Camera facing southwest. ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    A&M. Hot liquid waste treatment building (TAN-616). Camera facing southwest. Oblique view of east and north walls. Note three corrugated pipes at lower left indicating location of underground hot waste storage tanks. Photographer: Ron Paarmann. Date: September 22, 1997. INEEL negative no. HD-20-1-4 - Idaho National Engineering Laboratory, Test Area North, Scoville, Butte County, ID

  19. 76 FR 35861 - Safety Culture at the Waste Treatment and Immobilization Plant

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-06-20

    ... Doc No: 2011-15146] DEFENSE NUCLEAR FACILITIES SAFETY BOARD [Recommendation 2011-1] Safety Culture at... Board has made a recommendation to the Secretary of Energy concerning the safety culture at the Waste... Safety Culture at the Waste Treatment and Immobilization Plant Pursuant to 42 U.S.C. Sec....

  20. On-site or off-site treatment of medical waste: a challenge.

    PubMed

    Taghipour, Hassan; Mohammadyarei, Taher; Asghari Jafarabadi, Mohamad; Asl Hashemi, Ahmad

    2014-01-01

    Treating hazardous-infectious medical waste can be carried out on-site or off-site of health-care establishments. Nevertheless, the selection between on-site and off-site locations for treating medical waste sometimes is a controversial subject. Currently in Iran, due to policies of Health Ministry, the hospitals have selected on-site-treating method as the preferred treatment. The objectives of this study were to assess the current condition of on-site medical waste treatment facilities, compare on-site medical waste treatment facilities with off-site systems and find the best location of medical waste treatment. To assess the current on-site facilities, four provinces (and 40 active hospitals) were selected to participate in the survey. For comparison of on-site and off-site facilities (due to non availability of an installed off-site facility) Analytical Hierarchy Process (AHP) was employed. The result indicated that most on-site medical waste treating systems have problems in financing, planning, determining capacity of installations, operation and maintenance. AHP synthesis (with inconsistency ratio of 0.01 < 0.1) revealed that, in total, the off-site treatment of medical waste was in much higher priority than the on-site treatment (64.1% versus 35.9%). According to the results of study it was concluded that the off-site central treatment can be considered as an alternative. An amendment could be made to Iran's current medical waste regulations to have infectious-hazardous waste sent to a central off-site installation for treatment. To begin and test this plan and also receive the official approval, a central off-site can be put into practice, at least as a pilot in one province. Next, if it was practically successful, it could be expanded to other provinces and cities.

  1. Removal of contaminants in leachate from landfill by waste steel scrap and converter slag.

    PubMed

    Oh, Byung-Taek; Lee, Jai-Young; Yoon, Jeyong

    2007-08-01

    This study may be the first investigation to be performed into the potential benefits of recycling industrial waste in controlling contaminants in leachate. Batch reactors were used to evaluate the efficacy of waste steel scrap and converter slag to treat mixed contaminants using mimic leachate solution. The waste steel scrap was prepared through pre-treatment by an acid-washed step, which retained both zero-valent iron site and iron oxide site. Extensive trichloroethene (TCE) removal (95%) occurred by acid-washed steel scrap within 48 h. In addition, dehalogenation (Cl(-) production) was observed to be above 7.5% of the added TCE on a molar basis for 48 h. The waste steel scrap also removed tetrachloroethylene (PCE) through the dehalogenation process although to a lesser extent than TCE. Heavy metals (Cr, Mn, Cu, Zn, As, Cd, and Pb) were extensively removed by both acid-washed steel scrap and converter slag through the adsorption process. Among salt ions (NH (4)(+) , NO (3)(-) , and PO (4)(3-) ), PO (4)(3-) was removed by both waste steel scrap (100% within 8 h) and converter slag (100% within 20 min), whereas NO (3)(-) and NH (4)(+ ) were removed by waste steel scrap (100% within 7 days) and converter slag (up to 50% within 4 days) respectively. This work suggests that permeable reactive barriers (PRBs) with waste steel scrap and converter slag might be an effective approach to intercepting mixed contaminants in leachate from landfill.

  2. Mixed Waste Treatment Cost Analysis for a Range of GeoMelt Vitrification Process Configurations

    SciTech Connect

    Thompson, L. E.

    2002-02-27

    GeoMelt is a batch vitrification process used for contaminated site remediation and waste treatment. GeoMelt can be applied in several different configurations ranging from deep subsurface in situ treatment to aboveground batch plants. The process has been successfully used to treat a wide range of contaminated wastes and debris including: mixed low-level radioactive wastes; mixed transuranic wastes; polychlorinated biphenyls; pesticides; dioxins; and a range of heavy metals. Hypothetical cost estimates for the treatment of mixed low-level radioactive waste were prepared for the GeoMelt subsurface planar and in-container vitrification methods. The subsurface planar method involves in situ treatment and the in-container vitrification method involves treatment in an aboveground batch plant. The projected costs for the subsurface planar method range from $355-$461 per ton. These costs equate to 18-20 cents per pound. The projected cost for the in-container method is $1585 per ton. This cost equates to 80 cents per pound. These treatment costs are ten or more times lower than the treatment costs for alternative mixed waste treatment technologies according to a 1996 study by the US Department of Energy.

  3. Biological-mechanical waste treatment tests at a landfill in East Germany

    SciTech Connect

    Wotte, J.; Brummack, J.; Paar, S.; Gemende, B.

    1996-11-01

    The paper begins by describing the present situation in East Germany with regard to sanitary landfills, that is, there is very limited space for new landfills. The paper discusses the new German waste act amendments, special waste management problems in East Germany, and the combination biological and mechanical waste treatment (BMT) method proposed to help solve these problems. In general terms the BMT method would use a combination of composting, fermentation, separation, mixing, and crushing processes to minimize the waste to be disposed of and to render it harmless to further degradation which leads to emission of methane and contaminated leachates from the landfills.

  4. Caffeine and modafinil given during 48 h sleep deprivation modulate object recognition memory and synaptic proteins in the hippocampus of the rat.

    PubMed

    Wadhwa, M; Sahu, S; Kumari, P; Kauser, H; Ray, K; Panjwani, U

    2015-11-01

    We aimed to evaluate the effect of caffeine/modafinil on sleep deprivation (SD) induced alterations in recognition memory and synaptic proteins. The data revealed a beneficial effect of caffeine/modafinil against deficit in the familiar object retrieval performance and object exploration ratio after 48 h SD. Caffeine treatment prevented the SD induced down-regulation of synaptophysin and synapsin I proteins with no change in PSD-95 protein in hippocampus. However, modafinil administration improved the down-regulation of synaptophysin, synapsin I and PSD-95 proteins in hippocampus. Hence, caffeine/modafinil can serve as counter measures in amelioration of SD induced consequences at behavioural and protein levels.

  5. Mixed and low-level waste treatment project: Appendix C, Health and safety criteria for the mixed and low-level waste treatment facility at the Idaho National Engineering Laboratory. Part 1, Waste streams and treatment technologies

    SciTech Connect

    Neupauer, R.M.; Thurmond, S.M.

    1992-09-01

    This report describes health and safety concerns associated with the Mixed and Low-level Waste Treatment Facility at the Idaho National Engineering Laboratory. Various hazards are described such as fire, electrical, explosions, reactivity, temperature, and radiation hazards, as well as the potential for accidental spills, exposure to toxic materials, and other general safety concerns.

  6. Treatment of Asbestos Wastes Using the GeoMelt Vitrification Process

    SciTech Connect

    Finucane, K.G.; Thompson, L.E.; Abuku, T.; Nakauchi, H.

    2008-07-01

    The disposal of waste asbestos from decommissioning activities is becoming problematic in countries which have limited disposal space. A particular challenge is the disposal of asbestos wastes from the decommissioning of nuclear sites because some of it is radioactively contaminated or activated and disposal space for such wastes is limited. GeoMelt{sup R} vitrification is being developed as a treatment method for volume and toxicity minimization and radionuclide immobilization for UK radioactive asbestos mixed waste. The common practice to date for asbestos wastes is disposal in licensed landfills. In some cases, compaction techniques are used to minimize the disposal space requirements. However, such practices are becoming less practical. Social pressures have resulted in changes to disposal regulations which, in turn, have resulted in the closure of some landfills and increased disposal costs. In the UK, tens of thousands of tonnes of asbestos waste will result from the decommissioning of nuclear sites over the next 20 years. In Japan, it is estimated that over 40 million tonnes of asbestos materials used in construction will require disposal. Methods for the safe and cost effective volume reduction of asbestos wastes are being evaluated for many sites. The GeoMelt{sup R} vitrification process is being demonstrated at full-scale in Japan for the Japan Ministry of Environment and plans are being developed for the GeoMelt treatment of UK nuclear site decommissioning-related asbestos wastes. The full-scale treatment operations in Japan have also included contaminated soils and debris. The GeoMelt{sup R} vitrification process result in the maximum possible volume reduction, destroys the asbestos fibers, treats problematic debris associated with asbestos wastes, and immobilizes radiological contaminants within the resulting glass matrix. Results from recent full-scale treatment operations in Japan are discussed and plans for GeoMelt treatment of UK nuclear site

  7. Biological treatment of concentrated hazardous, toxic, andradionuclide mixed wastes without dilution

    SciTech Connect

    Stringfellow, William T.; Komada, Tatsuyuki; Chang, Li-Yang

    2004-06-15

    Approximately 10 percent of all radioactive wastes produced in the U. S. are mixed with hazardous or toxic chemicals and therefore can not be placed in secure land disposal facilities. Mixed wastes containing hazardous organic chemicals are often incinerated, but volatile radioactive elements are released directly into the biosphere. Some mixed wastes do not currently have any identified disposal option and are stored locally awaiting new developments. Biological treatment has been proposed as a potentially safer alternative to incineration for the treatment of hazardous organic mixed wastes, since biological treatment would not release volatile radioisotopes and the residual low-level radioactive waste would no longer be restricted from land disposal. Prior studies have shown that toxicity associated with acetonitrile is a significant limiting factor for the application of biotreatment to mixed wastes and excessive dilution was required to avoid inhibition of biological treatment. In this study, we demonstrate that a novel reactor configuration, where the concentrated toxic waste is drip-fed into a complete-mix bioreactor containing a pre-concentrated active microbial population, can be used to treat a surrogate acetonitrile mixed waste stream without excessive dilution. Using a drip-feed bioreactor, we were able to treat a 90,000 mg/L acetonitrile solution to less than 0.1 mg/L final concentration using a dilution factor of only 3.4. It was determined that the acetonitrile degradation reaction was inhibited at a pH above 7.2 and that the reactor could be modeled using conventional kinetic and mass balance approaches. Using a drip-feed reactor configuration addresses a major limiting factor (toxic inhibition) for the biological treatment of toxic, hazardous, or radioactive mixed wastes and suggests that drip-feed bioreactors could be used to treat other concentrated toxic waste streams, such as chemical warfare materiel.

  8. Proposal of an environmental performance index to assess solid waste treatment technologies

    SciTech Connect

    Goulart Coelho, Hosmanny Mauro; Lange, Lisete Celina; Coelho, Lineker Max Goulart

    2012-07-15

    Highlights: Black-Right-Pointing-Pointer Proposal of a new concept in waste management: Cleaner Treatment. Black-Right-Pointing-Pointer Development of an index to assess quantitatively waste treatment technologies. Black-Right-Pointing-Pointer Delphi Method was carried out so as to define environmental indicators. Black-Right-Pointing-Pointer Environmental performance evaluation of waste-to-energy plants. - Abstract: Although the concern with sustainable development and environment protection has considerably grown in the last years it is noted that the majority of decision making models and tools are still either excessively tied to economic aspects or geared to the production process. Moreover, existing models focus on the priority steps of solid waste management, beyond waste energy recovery and disposal. So, in order to help the lack of models and tools aiming at the waste treatment and final disposal, a new concept is proposed: the Cleaner Treatment, which is based on the Cleaner Production principles. This paper focuses on the development and validation of the Cleaner Treatment Index (CTI), to assess environmental performance of waste treatment technologies based on the Cleaner Treatment concept. The index is formed by aggregation (summation or product) of several indicators that consists in operational parameters. The weights of the indicator were established by Delphi Method and Brazilian Environmental Laws. In addition, sensitivity analyses were carried out comparing both aggregation methods. Finally, index validation was carried out by applying the CTI to 10 waste-to-energy plants data. From sensitivity analysis and validation results it is possible to infer that summation model is the most suitable aggregation method. For summation method, CTI results were superior to 0.5 (in a scale from 0 to 1) for most facilities evaluated. So, this study demonstrates that CTI is a simple and robust tool to assess and compare the environmental performance of different

  9. Biological Information Document, Radioactive Liquid Waste Treatment Facility

    SciTech Connect

    Biggs, J.

    1995-12-31

    This document is intended to act as a baseline source material for risk assessments which can be used in Environmental Assessments and Environmental Impact Statements. The current Radioactive Liquid Waste Treatment Facility (RLWTF) does not meet current General Design Criteria for Non-reactor Nuclear Facilities and could be shut down affecting several DOE programs. This Biological Information Document summarizes various biological studies that have been conducted in the vicinity of new Proposed RLWTF site and an Alternative site. The Proposed site is located on Mesita del Buey, a mess top, and the Alternative site is located in Mortandad Canyon. The Proposed Site is devoid of overstory species due to previous disturbance and is dominated by a mixture of grasses, forbs, and scattered low-growing shrubs. Vegetation immediately adjacent to the site is a pinyon-juniper woodland. The Mortandad canyon bottom overstory is dominated by ponderosa pine, willow, and rush. The south-facing slope was dominated by ponderosa pine, mountain mahogany, oak, and muhly. The north-facing slope is dominated by Douglas fir, ponderosa pine, and oak. Studies on wildlife species are limited in the vicinity of the proposed project and further studies will be necessary to accurately identify wildlife populations and to what extent they utilize the project area. Some information is provided on invertebrates, amphibians and reptiles, and small mammals. Additional species information from other nearby locations is discussed in detail. Habitat requirements exist in the project area for one federally threatened wildlife species, the peregrine falcon, and one federal candidate species, the spotted bat. However, based on surveys outside of the project area but in similar habitats, these species are not expected to occur in either the Proposed or Alternative RLWTF sites. Habitat Evaluation Procedures were used to evaluate ecological functioning in the project area.

  10. Geology of the Waste Treatment Plant Seismic Boreholes

    SciTech Connect

    Barnett, D. BRENT; Bjornstad, Bruce N.; Fecht, Karl R.; Lanigan, David C.; Reidel, Steve; Rust, Colleen F.

    2007-02-28

    In 2006, DOE-ORP initiated the Seismic Boreholes Project (SBP) to emplace boreholes at the Waste Treatment Plant (WTP) site in order to obtain direct Vs measurements and other physical property measurements in Columbia River basalt and interbedded sediments of the Ellensburg Formation. The goal was to reduce the uncertainty in the response spectra and seismic design basis, and potentially recover design margin for the WTP. The characterization effort within the deep boreholes included 1) downhole measurements of the velocity properties of the suprabasalt, basalt, and sedimentary interbed sequences, 2) downhole measurements of the density of the subsurface basalt and sediments, and 3) confirmation of the geometry of the contact between the various basalt and interbedded sediments through examination of retrieved core from the corehole and data collected through geophysical logging of each borehole. This report describes the results of the geologic studies from three mud-rotary boreholes and one cored borehole at the WTP. All four boreholes penetrated the entire Saddle Mountains Basalt and the upper part of the Wanapum Basalt where thick sedimentary interbeds occur between the lava flows. The basalt flows penetrated in Saddle Mountains Basalt included the Umatilla Member, Esquatzel Member, Pomona Member and the Elephant Mountain Member. The underlying Priest Rapids Member of the Wanapum Basalt was also penetrated. The Ellensburg Formation sediments consist of the Mabton Interbed, the Cold Creek Interbed, the Selah Interbed and the Rattlesnake Ridge Interbed; the Byron Interbed occurs between two flows of the Priest Rapids Member. The Mabton Interbed marks the contact between the Wanapum and Saddle Mountains Basalts. The thicknesses of the basalts and interbedded sediments were within expected limits. However, a small reverse fault was found in the Pomona Member flow top. This fault has three periods of movement and less than 15 feet of repeated section. Most of the

  11. Nitric-phosphoric acid treatment of TRU wastes

    SciTech Connect

    Smith, J.R.; Pierce, R.A.; Sturcken, E.F.

    1993-09-30

    A general process is being developed for the treatment of solid TRU and hazardous organic waste. Experimental data indicates that 100 lb/hr of aliphatic organic (plastics) and 1,000 lb/hr of non-aliphatic organic compounds can be quantitatively oxidized in a 1,000 gallon reaction vessel. The process uses dilute nitric acid in a concentrated phosphoric acid media as the main oxidant for the organic compounds. Phosphoric acid allows oxidation at temperatures up to 200{degrees}C and is relatively non-corrosive on 304-L stainless steel, especially at room temperature. Many organic materials have been completely oxidized to CO{sub 2}, CO, and inorganic acids in a 0.1M HNO{sub 3}/14.8M H{sub 3}PO{sub 4} solution. Addition of 0.001M Pd{sup 2+} reduces the CO to near 1% of the released carbon gases. To accomplish complete oxidation the solution temperature must be maintained above 130--150{degrees}C. Organic materials quantitatively destroyed include neoprene, cellulose, EDTA, TBP, tartaric acid, and nitromethane. The oxidation is usually complete in a few hours for soluble organic materials. The oxidation rate for non-aliphatic organic solids is moderately fast and surface area dependent. Polyethylene is quantitatively oxidized in 1.0M HNO{sub 3}/13.8M H{sub 3}PO{sub 4} solution while contained in pressure vessels heated with microwave energy. This is probably due to the high concentrations of NO{sub 2}{center_dot} obtained in the reaction environment.

  12. Histological Evaluation of Prostate Tissue Response to Image-Guided Transurethral Thermal Therapy After a 48h Recovery Period

    NASA Astrophysics Data System (ADS)

    Boyes, Aaron; Tang, Kee; Chopra, Rajiv; Bronskill, Michael

    2009-04-01

    Image-guided transurethral ultrasound thermal therapy shows strong potential for sparing of critical adjacent structures during prostate cancer treatment. Preclinical experiments were conducted to provide further information on the extent of the treatment margin. Four experiments were carried out in a canine model to investigate the pathology of this margin during the early stages of recovery and were compared to previous results obtained immediately post-treatment. Sedated animals were placed in a 1.5T clinical MRI, and the heating device was positioned accurately within the prostatic urethra with image guidance. Using an MRI-compatible system, the ultrasound device was rotated 365° treating a prescribed volume contained within the gland. Quantitative temperature maps were acquired throughout the treatment, providing feedback information for device control. Animals were allowed to recover and, after 48h, an imaging protocol including T2 and contrast enhanced (CE) MRI was repeated before the animals were sacrificed. Prostate sections were stained with H&E. Careful slice alignment methods during histological procedures and image registration were employed to ensure good correspondence between MR images and microscopy. Although T2 MRI revealed no lesion acutely, a hypo-intense region was clearly visible 2 days post-treatment. The lesion volume defined by CE-MRI increased appreciably during this time. Whole-mount H&E sections showed that the margin between coagulated and normal-appearing cells narrowed during recovery, typically to a width of under 1mm compared to 3mm acutely. These results illustrate the high level of precision achievable with transurethral thermal therapy and suggest methods to monitor the physiological response non-invasively.

  13. Technology for Waste Treatment at Remote Army Sites

    DTIC Science & Technology

    1986-09-01

    vent supportU T box - slip joint K’ - urinal 15 fan housing white fiberglass S.... • >toilet ___ _ toilet chute __________toilet connector plate ...vent connector plate tank topC;ý tank 1 S• , ’-,waste waste access door Stank compost bottom lcced-- •-II .lid Figure 5. Compostlng latrine. Figure 6...Perspective on Composting Toilets and Alternate Greywater Systems," Compost Science (July/August, 1977). Van der Ryn, Situ, ’The Farallones Composting

  14. Treatment and geological disposal of waste from NET pre-design

    NASA Astrophysics Data System (ADS)

    Brodén, Karin; Aggeryd, Ingrid; Lindberg, Maria; Olsson, Gunnar

    1993-06-01

    Within the European Fusion Technology programs Studsvik RadWaste AB has performed studies on fusion waste treatment and disposal for several years. This paper deals with the treatment and geological disposal of radioactive waste from NET operation and decommissioning. Results from calculations on radioactive waste fluxes for the operation and decommissioning of NET are reported. The calculations are based on the NET predesign report published 1993 and include results for the exchangeable in-vessel and external parts of the machine as well as permanent reactor components. Different aspects of treatment, packaging, transportation, and interim storage of the waste are discussed. The volumes of waste conditioned for final disposal are preliminarily quantified, according to German and Swedish scenarios for radioactive waste disposal. A total repository volume of approximately 45,000 m3 is required in the German Scenario and 35,000 m3 is required in the Swedish Scenario. Results from dose rate calculations for NET waste in final repositories are presented for the Swedish Scenario. This work was financially supported by the Swedish Natural Science Research Council (NFR) and the European Atomic Energy Community, under an association contract between Euratom and Sweden.

  15. Modelling of environmental impacts from biological treatment of organic municipal waste in EASEWASTE.

    PubMed

    Boldrin, Alessio; Neidel, Trine Lund; Damgaard, Anders; Bhander, Gurbakhash S; Møller, Jacob; Christensen, Thomas H

    2011-04-01

    The waste-LCA model EASEWASTE quantifies potential environmental effects from biological treatment of organic waste, based on mass and energy flows, emissions to air, water, soil and groundwater as well as effects from upstream and downstream processes. Default technologies for composting, anaerobic digestion and combinations hereof are available in the model, but the user can change all key parameters in the biological treatment module so that specific local plants and processes can be modelled. EASEWASTE is one of the newest waste LCA models and the biological treatment module was built partly on features of earlier waste-LCA models, but offers additional facilities, more flexibility, transparency and user-friendliness. The paper presents the main features of the module and provides some examples illustrating the capability of the model in environmentally assessing and discriminating the environmental performance of alternative biological treatment technologies in relation to their mass flows, energy consumption, gaseous emissions, biogas recovery and compost/digestate utilization.

  16. Integrated Passive Biological Treatment System/ Mine Waste Technology Program Report #16

    EPA Science Inventory

    This report summarizes the results of the Mine Waste Technology Program (MWTP) Activity III, Project 16, Integrated, Passive Biological Treatment System, funded by the United States Environmental Protection Agency (EPA) and jointly administered by EPA and the United States Depar...

  17. Department of Energy treatment capabilities for greater-than-Class C low-level radioactive waste

    SciTech Connect

    Morrell, D.K.; Fischer, D.K.

    1995-01-01

    This report provides brief profiles for 26 low-level and high-level waste treatment capabilities available at the Idaho National Engineering Laboratory (INEL), Lawrence Livermore National Laboratory (LLNL), Los Alamos National Laboratory (LANL), Oak Ridge National Laboratory (ORNL), Pacific Northwest Laboratory (PNL), Rocky Flats Plant (RFP), Savannah River Site (SRS), and West Valley Demonstration Plant (WVDP). Six of the treatments have potential use for greater-than-Class C low-level waste (GTCC LLW). They include: (a) the glass ceramic process and (b) the Waste Experimental Reduction Facility incinerator at INEL; (c) the Super Compaction and Repackaging Facility and (d) microwave melting solidification at RFP; (e) the vitrification plant at SRS; and (f) the vitrification plant at WVDP. No individual treatment has the capability to treat all GTCC LLW streams. It is recommended that complete physical and chemical characterizations be performed for each GTCC waste stream, to permit using multiple treatments for GTCC LLW.

  18. FY 1995 separation studies for liquid low-level waste treatment at Oak Ridge National Laboratory

    SciTech Connect

    Bostick, D.T.; Arnold, W.D.; Burgess, M.W.

    1995-01-01

    During FY 1995, studies were continued to develop improved methods for centralized treatment of liquid low-level waste (LLLW) at Oak Ridge National Laboratory (ORNL). Focus in this reporting period was on (1) identifying the parameters that affect the selective removal of {sup 90}Sr and {sup 137}Cs, two of the principal radioactive contaminants expected in the waste; (2) validating the effectiveness of the treatment methods by testing an ac Melton Valley Storage Tank (MVST) supernate; (3) evaluating the optimum solid/liquid separation techniques for the waste; (4) identifying potential treatment methods for removal of technetium from LLLW; and (5) identifying potential methods for stabilizing the high-activity secondary solid wastes generated by the treatment.

  19. Notification: Preliminary Research to Evaluate Hazardous Waste Passing Through Publicly Owned Treatment Works

    EPA Pesticide Factsheets

    March 13, 2013. The EPA's OIG plans to start preliminary research to evaluate the effectiveness of the EPA’s programs in preventing and addressing contamination of surface water from hazardous wastes passing through publicly owned treatment works.

  20. Site-Specific Seismic Site Response Model for the Waste Treatment Plant, Hanford, Washington

    SciTech Connect

    Rohay, Alan C.; Reidel, Steve P.

    2005-02-24

    This interim report documents the collection of site-specific geologic and geophysical data characterizing the Waste Treatment Plant site and the modeling of the site-specific structure response to earthquake ground motions.

  1. TOXICITY APPROACHES TO ASSESSING MINING IMPACTS AND MINE WASTE TREATMENT EFFECTIVENESS

    EPA Science Inventory

    The USEPA Office of Research and Development's National Exposure Research Laboratory and National Risk Management Research Laboratory have been evaluating the impact of mining sites on receiving streams and the effectiveness of waste treatment technologies in removing toxicity fo...

  2. CONTROL OF CHELATOR-BASED UPSETS IN SURFACE FINISHING SHOP WASTE WATER TREATMENT SYSTEMS

    EPA Science Inventory

    Actual surface finishing shop examples are used to illustrate the use of process chemistry understanding and analyses to identify immediate, interim and permanent response options for industrial waste water treatment plant (IWTP) upset problems caused by chelating agents. There i...

  3. Treatment Study Plan for Nitrate Salt Waste Remediation Revision 1.0

    SciTech Connect

    Juarez, Catherine L.; Funk, David John; Vigil-Holterman, Luciana R.; Naranjo, Felicia Danielle

    2016-03-07

    The two stabilization treatment methods that are to be examined for their effectiveness in the treatment of both the unremediated and remediated nitrate salt wastes include (1) the addition of zeolite and (2) cementation. Zeolite addition is proposed based on the results of several studies and analyses that specifically examined the effectiveness of this process for deactivating nitrate salts. Cementation is also being assessed because of its prevalence as an immobilization method used for similar wastes at numerous facilities around the DOE complex, including at Los Alamos. The results of this Treatment Study Plan will be used to provide the basis for a Resource Conservation and Recovery Act (RCRA) permit modification request of the LANL Hazardous Waste Facility Permit for approval by the New Mexico Environment Department-Hazardous Waste Bureau (NMED-HWB) of the proposed treatment process and the associated facilities.

  4. SELENIUM TREATMENT/REMOVAL ALTERNATIVES DEMONSTRATION PROJECT - MINE WASTE TECHNOLOGY PROGRAM ACTIVITY III, PROJECT 20

    EPA Science Inventory

    This document is the final report for EPA's Mine WAste Technology Program (MWTP) Activity III, Project 20--Selenium Treatment/Removal Alternatives Demonstration project. Selenium contamination originates from many sources including mining operations, mineral processing, abandoned...

  5. Leaching characteristics of the metal waste form from the electrometallurgical treatment process: Product consistency testing

    SciTech Connect

    Johnson, S. G.; Keiser, D. D.; Frank, S. M.; DiSanto, T.; Noy, M.

    1999-11-11

    Argonne National Laboratory is developing an electrometallurgical treatment for spent fuel from the experimental breeder reactor II. A product of this treatment process is a metal waste form that incorporates the stainless steel cladding hulls, zirconium from the fuel and the fission products that are noble to the process, i.e., Tc, Ru, Nb, Pd, Rh, Ag. The nominal composition of this waste form is stainless steel/15 wt% zirconium/1--4 wt% noble metal fission products/1--2 wt % U. Leaching results are presented from several tests and sample types: (1) 2 week monolithic immersion tests on actual metal waste forms produced from irradiated cladding hulls, (2) long term (>2 years) pulsed flow tests on samples containing technetium and uranium and (3) crushed sample immersion tests on cold simulated metal waste form samples. The test results will be compared and their relevance for waste form product consistency testing discussed.

  6. Feasibility Study for the Upgrade of the Process Waste Treatment System

    SciTech Connect

    Dean, R.A.; Peet, M.R.

    1999-05-01

    The following study presents the technical basis for combining the functions of the current Process Waste Treatment Complex--Building 3544 (PWTC-3544) with current operations at the Process Waste Treatment Complex--Building 3608 (PWTC-3608) at Oak Ridge National Laboratory (ORNL). Two of the current granular-activated carbon (GAC) columns at PWTC-3608 would be converted to zeolite columns, and PWTC-3608 would be operated such that the process waste stream would flow through the zeolite columns for removal of 137Cs and 90Sr after the process waste stream passes through a clarifier at PWTC-3608. This would modify the current operation: pumping process waste from the clarifier at PWTC-308 to PWTC-3544 for the removal of radiological constituents using ion exchange. PWTC-3544 could then be taken out of operation, which is projected to generate significant cost savings.

  7. Life Cycle Analysis for Treatment and Disposal of PCB Waste at Ashtabula and Fernald

    SciTech Connect

    Morris, M.I.

    2001-01-11

    This report presents the use of the life cycle analysis (LCA) system developed at Oak Ridge National Laboratory (ORNL) to assist two U.S. Department of Energy (DOE) sites in Ohio--the Ashtabula Environmental Management Project near Cleveland and the Fernald Environmental Management Project near Cincinnati--in assessing treatment and disposal options for polychlorinated biphenyl (PCB)-contaminated low-level radioactive waste (LLW) and mixed waste. We will examine, first, how the LCA process works, then look briefly at the LCA system's ''toolbox,'' and finally, see how the process was applied in analyzing the options available in Ohio. As DOE nuclear weapons facilities carry out planned decontamination and decommissioning (D&D) activities for site closure and progressively package waste streams, remove buildings, and clean up other structures that have served as temporary waste storage locations, it becomes paramount for each waste stream to have a prescribed and proven outlet for disposition. Some of the most problematic waste streams throughout the DOE complex are PCB low-level radioactive wastes (liquid and solid) and PCB low-level Resource Conservation and Recovery Act (RCRA) liquid and solid wastes. Several DOE Ohio Field Office (OH) sites have PCB disposition needs that could have an impact on the critical path of the decommissioning work of these closure sites. The Ashtabula Environmental Management Project (AEMP), an OH closure site, has an urgent problem with disposition of soils contaminated by PCB and low-level waste at the edge of the site. The Fernald Environmental Management Project (FEMP), another OH closure site, has difficulties in timely disposition of its PCB-low-level sludges and its PCB low-level RCRA sludges in order to avoid impacting the critical path of its D&D activities. Evaluation of options for these waste streams is the subject of this report. In the past a few alternatives for disposition of PCB low-level waste and PCB low-level RCRA

  8. A Database for Reviewing and Selecting Radioactive Waste Treatment Technologies and Vendors

    SciTech Connect

    Schwinkendorf, William Erich; Marushia, Patrick Charles

    1999-07-01

    Several attempts have been made in past years to collate and present waste management technologies and solutions to waste generators. These efforts have been manifested as reports, buyers’ guides, and databases. While this information is helpful at the time it is assembled, their principal weakness is maintaining the timeliness and accuracy of the information over time. In many cases, updates have to be published or developed as soon as the product is disseminated. The recently developed National Low-Level Waste Management Program’s Technologies Database is a vendor-updated Internet based database designed to overcome this problem. The National Low-Level Waste Management Program’s Technologies Database contains information about waste types, treatment technologies, and vendor information. Information is presented about waste types, typical treatments, and the vendors who provide those treatment methods. The vendors who provide services update their own contact information, their treatment processes, and the types of wastes for which their treatment process is applicable. This information is queriable by a generator of low-level or mixed low-level radioactive waste who is seeking information on waste treatment methods and the vendors who provide them. Timeliness of the information in the database is assured using time clocks and automated messaging to remind featured vendors to keep their information current. Failure to keep the entries current results in a vendor being warned and then ultimately dropped from the database. This assures that the user is dealing with the most current information available and the vendors who are active in reaching and serving their market.

  9. A Database for Reviewing and Selecting Radioactive Waste Treatment Technologies and Vendors

    SciTech Connect

    P. C. Marushia; W. E. Schwinkendorf

    1999-07-01

    Several attempts have been made in past years to collate and present waste management technologies and solutions to waste generators. These efforts have been manifested as reports, buyers' guides, and databases. While this information is helpful at the time it is assembled, the principal weakness is maintaining the timeliness and accuracy of the information over time. In many cases, updates have to be published or developed as soon as the product is disseminated. The recently developed National Low-Level Waste Management Program's Technologies Database is a vendor-updated Internet based database designed to overcome this problem. The National Low-Level Waste Management Program's Technologies Database contains information about waste types, treatment technologies, and vendor information. Information is presented about waste types, typical treatments, and the vendors who provide those treatment methods. The vendors who provide services update their own contact information, their treatment processes, and the types of wastes for which their treatment process is applicable. This information is queriable by a generator of low-level or mixed low-level radioactive waste who is seeking information on waste treatment methods and the vendors who provide them. Timeliness of the information in the database is assured using time clocks and automated messaging to remind featured vendors to keep their information current. Failure to keep the entries current results in a vendor being warned and then ultimately dropped from the database. This assures that the user is dealing with the most current information available and the vendors who are active in reaching and serving their market.

  10. Mechanical-biological waste treatment and the associated occupational hygiene in Finland

    SciTech Connect

    Tolvanen, Outi K. . E-mail: outolvan@bytl.jyu.fi; Haenninen, Kari I.

    2006-07-01

    A special feature of waste management in Finland has been the emphasis on the source separation of kitchen biowaste (catering waste); more than two-thirds of the Finnish population participates in this separation. Source-separated biowaste is usually treated by composting. The biowaste of about 5% of the population is handled by mechanical-biological treatment. A waste treatment plant at Mustasaari is the only plant in Finland using digestion for kitchen biowaste. For the protection of their employees, the plant owners commissioned a study on environmental factors and occupational hygiene in the plant area. During 1998-2000 the concentrations of dust, microbes and endotoxins and noise levels were investigated to identify possible problems at the plant. Three different work areas were investigated: the pre-processing and crushing hall, the bioreactor hall and the drying hall. Employees were asked about work-related health problems. Some problems with occupational hygiene were identified: concentrations of microbes and endotoxins may increase to levels harmful to health during waste crushing and in the bioreactor hall. Because employees complained of symptoms such as dry cough and rash or itching appearing once or twice a month, it is advisable to use respirator masks (class P3) during dusty working phases. The noise level in the drying hall exceeded the Finnish threshold value of 85 dBA. Qualitatively harmful factors for the health of employees are similar in all closed waste treatment plants in Finland. Quantitatively, however, the situation at the Mustasaari treatment plant is better than at some Finnish dry waste treatment plants. Therefore is reasonable to conclude that mechanical sorting, which produces a dry waste fraction for combustion and a biowaste fraction for anaerobic treatment, is in terms of occupational hygiene better for employees than combined aerobic treatment and dry waste treatment.

  11. Mixed waste treatment using the ChemChar thermolytic detoxification technique

    SciTech Connect

    Kuchynka, D.

    1995-10-01

    The diversity of mixed waste matrices contained at Department of Energy sites that require treatment preclude a single, universal treatment technology capable of handling sludges, solids, heterogeneous debris, aqueous and organic liquids and soils. This report describes the ChemChar thermolytic detoxification process. The process is a thermal, chemically reductive technology that converts the organic portion of mixed wastes to a synthesis gas, while simultaneously absorbing volatile inorganics on a carbon-based char.

  12. Waste treatment by dialysis. (Latest citations from Pollution abstracts). Published Search

    SciTech Connect

    1996-02-01

    The bibliography contains citations concerning the use of dialysis in the treatment of wastewaters. Techniques for the removal of metals, ammonia, waste acids, nitrates, and phosphates are described. Special attention is given to the desalination of liquid wastes. Applications of this technology to the treatment of effluent from the agrochemical, petrochemical, tanning, and electroplating industries are discussed. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  13. Waste treatment by dialysis. (Latest citations from Pollution abstracts). Published Search

    SciTech Connect

    1995-01-01

    The bibliography contains citations concerning the use of dialysis in the treatment of wastewaters. Techniques for the removal of metals, ammonia, waste acids, nitrates, and phosphates are described. Special attention is given to the desalination of liquid wastes. Applications of this technology to the treatment of effluent from the agrochemical, petrochemical, tanning, and electroplating industries are discussed. (Contains a minimum of 60 citations and includes a subject term index and title list.)

  14. Development of an Alternative Treatment Scheme for Sr/TRU Removal: Permanganate Treatment of AN-107 Waste

    SciTech Connect

    RT Hallen; SA Bryan; FV Hoopes

    2000-08-04

    A number of Hanford tanks received waste containing organic complexants, which increase the volubility of Sr-90 and transuranic (TRU) elements. Wastes from these tanks require additional pretreatment to remove Sr-90 and TRU for immobilization as low activity waste (Waste Envelope C). The baseline pretreatment process for Sr/TRU removal was isotopic exchange and precipitation with added strontium and iron. However, studies at both Battelle and Savannah River Technology Center (SRTC) have shown that the Sr/Fe precipitates were very difficult to filter. This was a result of the formation of poor filtering iron solids. An alternate treatment technology was needed for Sr/TRU removal. Battelle had demonstrated that permanganate treatment was effective for decontaminating waste samples from Hanford Tank SY-101 and proposed that permanganate be examined as an alternative Sr/TRU removal scheme for complexant-containing tank wastes such as AW107. Battelle conducted preliminary small-scale experiments to determine the effectiveness of permanganate treatment with AN-107 waste samples that had been archived at Battelle from earlier studies. Three series of experiments were performed to evaluate conditions that provided adequate Sr/TRU decontamination using permanganate treatment. The final series included experiments with actual AN-107 diluted feed that had been obtained specifically for BNFL process testing. Conditions that provided adequate Sr/TRU decontamination were identified. A free hydroxide concentration of 0.5M provided adequate decontamination with added Sr of 0.05M and permanganate of 0.03M for archived AN-107. The best results were obtained when reagents were added in the sequence Sr followed by permanganate with the waste at ambient temperature. The reaction conditions for Sr/TRU removal will be further evaluated with a 1-L batch of archived AN-107, which will provide a large enough volume of waste to conduct crossflow filtration studies (Hallen et al. 2000a).

  15. Solid waste treatment and disposal: effects on public health and environmental safety.

    PubMed

    Hamer, Geoffrey

    2003-12-01

    The safety and acceptability of many widely used solid waste management practices are of serious concern from the public health point of view. Such concern stems from both distrust of policies and solutions proposed by all tiers of government for the management of solid waste and a perception that many solid waste management facilities use poor operating procedures. Waste management practice that currently encompasses disposal, treatment, reduction, recycling, segregation and modification has developed over the past 150 years. Before that and in numerous more recent situations, all wastes produced were handled by their producers using simple disposal methods, including terrestrial dumping, dumping into both fresh and marine waters and uncontrolled burning. In spite of ever-increasing industrialisation and urbanisation, the dumping of solid waste, particularly in landfills, remains a prominent means of disposal and implied treatment. Major developments have occurred with respect to landfill technology and in the legislative control of the categories of wastes that can be subject to disposal by landfilling. Even so, many landfills remain primitive in their operation. Alternative treatment technologies for solid waste management include incineration with heat recovery and waste gas cleaning and accelerated composting, but both of these technologies are subject to criticism either by environmentalists on the grounds of possible hazardous emissions, failure to eliminate pathogenic agents or failure to immobilise heavy metals, or by landfill operators and contractors on the basis of waste management economics, while key questions concerning the effects of the various practices on public health and environmental safety remain unanswered. The probable and relative effects on both public health and environmental safety of tradition and modern landfill technologies will be evaluated with respect to proposed alternative treatment technologies.

  16. High Level Waste Remote Handling Equipment in the Melter Cave Support Handling System at the Hanford Waste Treatment Plant

    SciTech Connect

    Bardal, M.A.; Darwen, N.J.

    2008-07-01

    Cold war plutonium production led to extensive amounts of radioactive waste stored in tanks at the Department of Energy's (DOE) Hanford site. Bechtel National, Inc. is building the largest nuclear Waste Treatment Plant in the world located at the Department of Energy's Hanford site to immobilize the millions of gallons of radioactive waste. The site comprises five main facilities; Pretreatment, High Level Waste vitrification, Low Active Waste vitrification, an Analytical Lab and the Balance of Facilities. The pretreatment facilities will separate the high and low level waste. The high level waste will then proceed to the HLW facility for vitrification. Vitrification is a process of utilizing a melter to mix molten glass with radioactive waste to form a stable product for storage. The melter cave is designated as the High Level Waste Melter Cave Support Handling System (HSH). There are several key processes that occur in the HSH cell that are necessary for vitrification and include: feed preparation, mixing, pouring, cooling and all maintenance and repair of the process equipment. Due to the cell's high level radiation, remote handling equipment provided by PaR Systems, Inc. is required to install and remove all equipment in the HSH cell. The remote handling crane is composed of a bridge and trolley. The trolley supports a telescoping tube set that rigidly deploys a TR 4350 manipulator arm with seven degrees of freedom. A rotating, extending, and retracting slewing hoist is mounted to the bottom of the trolley and is centered about the telescoping tube set. Both the manipulator and slewer are unique to this cell. The slewer can reach into corners and the manipulator's cross pivoting wrist provides better operational dexterity and camera viewing angles at the end of the arm. Since the crane functions will be operated remotely, the entire cell and crane have been modeled with 3-D software. Model simulations have been used to confirm operational and maintenance

  17. Mercury emissions control technologies for mixed waste thermal treatment

    SciTech Connect

    Chambers, A.; Knecht, M.; Soelberg, N.; Eaton, D.; Roberts, D.; Broderick, T.

    1997-12-31

    EPA has identified wet scrubbing at low mercury feedrates, as well as carbon adsorption via carbon injection into the offgas or via flow through fixed carbon beds, as control technologies that can be used to meet the proposed Maximum Achievable Control Technology (MACT) rule limit for mercury emissions from hazardous waste incinerators. DOE is currently funding demonstrations of gold amalgamation that may also control mercury to the desired levels. Performance data from a variety of sources was reviewed to determine ranges of achievable mercury control. Preliminary costs were estimated for using these technologies to control mercury emissions from mixed waste incineration. Mercury emissions control for mixed waste incineration may need to be more efficient than for incineration of other hazardous wastes because of higher mercury concentrations in some mixed waste streams. However, mercury control performance data for wet scrubbing and carbon adsorption is highly variable. More information is needed to demonstrate control efficiencies that are achievable under various design and operating conditions for wet scrubbing, carbon adsorption, and gold amalgamation technologies. Given certain assumptions made in this study, capital costs, operating costs, and lifecycle costs for carbon injection, carbon beds, and gold amalgamation generally vary for different assumed mercury feedrates and for different offgas flowrates. Assuming that these technologies can in fact provide the necessary mercury control performance, each of these technologies may be less costly than the others for certain mercury feedrates and the offgas flowrates.

  18. Environmental evaluation of waste treatment scenarios for the towns Khanty-Mansiysk and Surgut, Russia.

    PubMed

    Kaazke, Julia; Meneses, Montse; Wilke, Berndt-Michael; Rotter, Vera Susanne

    2013-03-01

    Khanty-Mansiysk Autonomous Okrug - Ugra in Siberia has recently started to play a major role in the Russian economy because key oil and gas extraction sites are located in this region. As a result, the extensions of infrastructure and higher incomes have been leading to an accelerated population growth and consequent increase in the generation of solid household waste. The current methods of waste disposal have now reached their limits, especially in the towns Khanty-Mansiysk and Surgut. The key objectives of this study were to identify the influence of waste composition and transport routes on the life cycle assessment (LCA) results and to assess the current waste treatment option for solid household waste and to compare it with proposed scenarios. Furthermore, recommendations for an optimal use of LCA within a decision-making process for a waste management plan are presented. LCA methodology was used to evaluate different waste management scenarios such as landfilling and incineration. One result was that the options 'incineration with recycling' and 'anaerobic mechanical-biological treatment with recycling' demonstrated lower environmental impact in both Khanty-Mansiysk and Surgut. Another finding was that there were hardly any differences in the ranking of the scenarios for Surgut and Khanty-Mansiysk. However, the special socio-cultural circumstances and location of each town have to be considered seriously in the development of a sustainable waste management plan.

  19. Survey of carbonization facilities for municipal solid waste treatment in Japan

    SciTech Connect

    Hwang, In-Hee; Kawamoto, Katsuya

    2010-07-15

    The operations of carbonization facilities for municipal solid waste treatment in Japan were examined. Input waste, system processes, material flows, quality of char and its utilization, fuel and chemical consumption, control of facility emissions, and trouble areas in facility operation were investigated and analyzed. Although carbonization is a technically available thermochemical conversion method for municipal solid waste treatment, problems of energy efficiency and char utilization must be solved for carbonization to be competitive. Possible solutions include (1) optimizing the composition of input waste, treatment scale, organization of unit processes, operational methods, and quality and yield of char on the basis of analysis and feedback of long-term operating data of present operating facilities and (2) securing stable char demands by linking with local industries such as thermal electric power companies, iron manufacturing plants, and cement production plants.

  20. Geology of the Waste Treatment Plant Seismic Boreholes

    SciTech Connect

    Barnett, D. Brent; Fecht, Karl R.; Reidel, Stephen P.; Bjornstad, Bruce N.; Lanigan, David C.; Rust, Colleen F.

    2007-05-11

    In 2006, the U.S. Department of Energy initiated the Seismic Boreholes Project (SBP) to emplace boreholes at the Waste Treatment Plant (WTP) site in order to obtain direct shear wave velocity (Vs) measurements and other physical property measurements in Columbia River basalt and interbedded sediments of the Ellensburg Formation. The goal was to reduce the uncertainty in the response spectra and seismic design basis, and potentially recover design margin for the WTP. The characterization effort within the deep boreholes included 1) downhole measurements of the velocity properties of the suprabasalt, basalt, and sedimentary interbed sequences, 2) downhole measurements of the density of the subsurface basalt and sediments, and 3) geologic studies to confirm the geometry of the contact between the various basalt and interbedded sediments through examination of retrieved core from the core hole and data collected through geophysical logging of each borehole. This report describes the results of the geologic studies from three mud-rotary boreholes and one cored borehole at the WTP. All four boreholes penetrated the entire Saddle Mountains Basalt and the upper part of the Wanapum Basalt where thick sedimentary interbeds occur between the lava flows. The basalt flows penetrated in Saddle Mountains Basalt included the Umatilla Member, Esquatzel Member, Pomona Member, and the Elephant Mountain Member. The underlying Priest Rapids Member of the Wanapum Basalt also was penetrated. The Ellensburg Formation sediments consist of the Mabton Interbed, the Cold Creek Interbed, the Selah Interbed, and the Rattlesnake Ridge Interbed; the Byron Interbed occurs between two flows of the Priest Rapids Member. The Mabton Interbed marks the contact between the Wanapum and Saddle Mountains Basalts. The thicknesses of the basalts and interbedded sediments were within expected limits. However, a small reverse fault was found in the Pomona Member flow top. This fault has three periods of

  1. Hydrothermal treatment for inactivating some hygienic microbial indicators from food waste-amended animal feed.

    PubMed

    Jin, Yiying; Chen, Ting; Li, Huan

    2012-07-01

    To achieve the hygienic safety of food waste used as animal feed, a hydrothermal treatment process of 60-110 degrees C for 10-60 min was applied on the separated food waste from a university canteen. Based on the microbial analysis of raw waste, the inactivation of hygienic indicators of Staphylococcus aureus (SA), total coliform (TC), total aerobic plate counts (TPC), and molds and yeast (MY) were analyzed during the hydrothermal process. Results showed that indicators' concentrations were substantially reduced after hydrothermal treatment, with a greater reduction observed when the waste was treated with a higher temperature and pressure and a longer ramping time. The 110 degrees C hydrothermal treatment for 60 min was sufficient to disinfect food waste as animal feed from the viewpoint of hygienic safety. Results obtained so far indicate that hydrothermal treatment can significantly decrease microbial indicators' concentrations but does not lead to complete sterilization, because MY survived even after 60 min treatment at 110 degrees C. The information from the present study will contribute to the microbial risk control of food waste-amended animal feed, to cope with legislation on food or feed safety.

  2. Hanford Facility Dangerous Waste Permit Application, 200 Area Effluent Treatment Facility

    SciTech Connect

    Not Available

    1993-08-01

    The 200 Area Effluent Treatment Facility Dangerous Waste Permit Application documentation consists of both Part A and a Part B permit application documentation. An explanation of the Part A revisions associated with this treatment and storage unit, including the current revision, is provided at the beginning of the Part A section. Once the initial Hanford Facility Dangerous Waste Permit is issued, the following process will be used. As final, certified treatment, storage, and/or disposal unit-specific documents are developed, and completeness notifications are made by the US Environmental Protection Agency and the Washington State Department of Ecology, additional unit-specific permit conditions will be incorporated into the Hanford Facility Dangerous Waste Permit through the permit modification process. All treatment, storage, and/or disposal units that are included in the Hanford Facility Dangerous Waste Permit Application will operate under interim status until final status conditions for these units are incorporated into the Hanford Facility Dangerous Waste Permit. The Hanford Facility Dangerous Waste Permit Application, 200 Area Effluent Treatment Facility contains information current as of May 1, 1993.

  3. Photocatalytic post-treatment in waste water reclamation systems

    NASA Technical Reports Server (NTRS)

    Cooper, Gerald; Ratcliff, Matthew A.; Verostko, Charles E.

    1989-01-01

    A photocatalytic water purification process is described which effectively oxidizes organic impurities common to reclaimed waste waters and humidity condensates to carbon dioxide at ambient temperatures. With this process, total organic carbon concentrations below 500 ppb are readily achieved. The temperature dependence of the process is well described by the Arrhenius equation and an activation energy barrier of 3.5 Kcal/mole. The posttreatment approach for waste water reclamation described here shows potential for integration with closed-loop life support systems.

  4. Wet Oxidation as a Waste Treatment Method in Closed Systems

    NASA Technical Reports Server (NTRS)

    Onisko, B. L.; Wydeven, T.

    1982-01-01

    The chemistry of the wet oxidation process was investigated in relation to production of plant nutrients from plant and human waste materials as required for a closed life support system. Hydroponically grown lettuce plants were used as a model plant waste, and oxygen gas was used as an oxidant. Organic nitrogen content was decreased 88-100%, depending on feed material. Production of ammonia and nitrogen gas accounted for all of the observed decrease in organic nitrogen content. No nitrous oxide (N2O) was detected. The implications of these results for closed life support systems are discussed.

  5. Wet oxidation as a waste treatment in closed systems

    NASA Technical Reports Server (NTRS)

    Onisko, B. L.; Wydeven, T.

    1981-01-01

    The chemistry of the wet oxidation process has been investigated in relation to production of plant nutrients from plant and human waste materials as required for a closed life-support system. Hydroponically grown lettuce plants were used as a model plant waste and oxygen gas was used as oxidant. Organic nitrogen content was decreased 88-100% depending on feed material. Production of ammonia and nitrogen gas account for all of the observed decrease in organic nitrogen content. No nitrous oxide (N2O) was detected. The implications of these results for closed life-support systems are discussed.

  6. Treatment of radioactive wastes from DOE underground storage tanks

    SciTech Connect

    Collins, J.L.; Egan, B.Z.; Spencer, B.B.; Chase, C.W.; Anderson, K.K.; Bell, J.T.

    1994-06-01

    Bench-scale batch tests have been conducted with sludge and supernate tank waste from the Melton Valley Storage Tank (MVST) Facility at Oak Ridge National Laboratory (ORNL) to evaluate separation technology process for use in a comprehensive sludge processing flow sheet as a means of concentrating the radionuclides and reducing the volumes of storage tank waste at national sites for final disposal. This paper discusses the separation of the sludge solids and supernate, the basic washing of the sludge solids, the acidic dissolution of the sludge solids, and the removal of the radionuclides from the supernate.

  7. Non-Thermal Treatment of Hanford Site Low-Level Mixed Waste

    SciTech Connect

    1998-09-01

    DOE proposes to transport contact-handled LLMW from the Hanford Site to the Allied Technology Group (ATG) Mixed Waste Facility (MWF) in Richland, Washington, for non-thermal treatment and to return the treated waste to the Hanford Site for eventual land disposal. Over a 3-year period the waste would be staged to the ATG MWF, and treated waste would be returned to the Hanford Site. The ATG MWF would be located on an 18 hectare (ha) (45 acre [at]) ATG Site adjacent to ATG's licensed low-level waste processing facility at 2025 Battelle Boulevard. The ATG MWF is located approximately 0.8 kilometers (km) (0.5 miles [mi]) south of Horn Rapids Road and 1.6 km (1 mi) west of Stevens Drive. The property is located within the Horn Rapids triangle in northern Richland (Figure 2.1). The ATG MWF is to be located on the existing ATG Site, near the DOE Hanford Site, in an industrial area in the City of Richland. The effects of siting, construction, and overall operation of the MWF have been evaluated in a separate State Environmental Policy Act (SEPA) EIS (City of Richland 1998). The proposed action includes transporting the LLMW from the Hanford Site to the ATG Facility, non-thermal treatment of the LLMW at the ATG MWF, and transporting the waste from ATG back to the Hanford Site. Impacts fi-om waste treatment operations would be bounded by the ATG SEPA EIS, which included an evaluation of the impacts associated with operating the non-thermal portion of the MWF at maximum design capacity (8,500 metric tons per year) (City of Richland 1998). Up to 50 employees would be required for non-thermal treatment portion of the MWF. This includes 40 employees that would perform waste treatment operations and 10 support staff. Similar numbers were projected for the thermal treatment portion of the MWF (City of Richland 1998).

  8. Waste treatment by reverse osmosis and membrane processing. (Latest citations from the NTIS bibliographic database). Published Search

    SciTech Connect

    1996-10-01

    The bibliography contains citations concerning the technology of reverse osmosis and membrane processing in sewage and industrial waste treatment. Citations discuss ultrafiltration, industrial water reuse, hazardous waste treatment, municipal wastes, and materials recovery. Waste reduction and recycling in electroplating, metal finishing, and circuit board manufacturing are considered. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  9. Waste treatment by reverse osmosis and membrane processing. (Latest citations from the NTIS bibliographic database). Published Search

    SciTech Connect

    1995-09-01

    The bibliography contains citations concerning the technology of reverse osmosis and membrane processing in sewage and industrial waste treatment. Citations discuss ultrafiltration, industrial water reuse, hazardous waste treatment, municipal wastes, and materials recovery. Waste reduction and recycling in electroplating, metal finishing, and circuit board manufacturing are considered. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  10. Diversity and antibiotic resistance of Aeromonas spp. in drinking and waste water treatment plants.

    PubMed

    Figueira, Vânia; Vaz-Moreira, Ivone; Silva, Márcia; Manaia, Célia M

    2011-11-01

    The taxonomic diversity and antibiotic resistance phenotypes of aeromonads were examined in samples from drinking and waste water treatment plants (surface, ground and disinfected water in a drinking water treatment plant, and raw and treated waste water) and tap water. Bacteria identification and intra-species variation were determined based on the analysis of the 16S rRNA, gyrB and cpn60 gene sequences. Resistance phenotypes were determined using the disc diffusion method. Aeromonas veronii prevailed in raw surface water, Aeromonas hydrophyla in ozonated water, and Aeromonas media and Aeromonas puntacta in waste water. No aeromonads were detected in ground water, after the chlorination tank or in tap water. Resistance to ceftazidime or meropenem was detected in isolates from the drinking water treatment plant and waste water isolates were intrinsically resistant to nalidixic acid. Most of the times, quinolone resistance was associated with the gyrA mutation in serine 83. The gene qnrS, but not the genes qnrA, B, C, D or qepA, was detected in both surface and waste water isolates. The gene aac(6')-ib-cr was detected in different waste water strains isolated in the presence of ciprofloxacin. Both quinolone resistance genes were detected only in the species A. media. This is the first study tracking antimicrobial resistance in aeromonads in drinking, tap and waste water and the importance of these bacteria as vectors of resistance in aquatic environments is discussed.

  11. Options Assessment Report: Treatment of Nitrate Salt Waste at Los Alamos National Laboratory

    SciTech Connect

    Robinson, Bruce Alan; Stevens, Patrice Ann

    2015-12-17

    This report documents the methodology used to select a method of treatment for the remediated nitrate salt (RNS) and unremediated nitrate salt (UNS) waste containers at Los Alamos National Laboratory (LANL). The method selected should treat the containerized waste in a manner that renders the waste safe and suitable for transport and final disposal in the Waste Isolation Pilot Plant (WIPP) repository, under specifications listed in the WIPP Waste Acceptance Criteria (DOE/CBFO, 2013). LANL recognizes that the results must be thoroughly vetted with the New Mexico Environment Department (NMED) and that a modification to the LANL Hazardous Waste Facility Permit is a necessary step before implementation of this or any treatment option. Likewise, facility readiness and safety basis approvals must be received from the Department of Energy (DOE). This report presents LANL’s preferred option, and the documentation of the process for reaching the recommended treatment option for RNS and UNS waste, and is presented for consideration by NMED and DOE.

  12. Treatment plan for aqueous/organic/decontamination wastes under the Oak Ridge Reservation FFCA Development, Demonstration, Testing, and Evaluation Program

    SciTech Connect

    Backus, P.M.; Benson, C.E.; Gilbert, V.P.

    1994-08-01

    The U.S. Department of Energy (DOE) Oak Ridge Operations Office and the U.S. Environmental Protection Agency (EPA)-Region IV have entered into a Federal Facility Compliance Agreement (FFCA) which seeks to facilitate the treatment of low-level mixed wastes currently stored at the Oak Ridge Reservation (ORR) in violation of the Resource, Conservation and Recovery Act Land Disposal Restrictions. The FFCA establishes schedules for DOE to identify treatment for wastes, referred to as Appendix B wastes, that current have no identified or existing capacity for treatment. A development, demonstration, testing, and evaluation (DDT&E) program was established to provide the support necessary to identify treatment methods for mixed was meeting the Appendix B criteria. The Program has assembled project teams to address treatment development needs for major categories of the Appendix B wastes based on the waste characteristics and possible treatment technologies. The Aqueous, Organic, and Decontamination (A/O/D) project team was established to identify pretreatment options for aqueous and organic wastes which will render the waste acceptable for treatment in existing waste treatment facilities and to identify the processes to decontaminate heterogeneous debris waste. In addition, the project must also address the treatment of secondary waste generated by other DDT&E projects. This report details the activities to be performed under the A/O/D Project in support of the identification, selection, and evaluation of treatment processes. The goals of this plan are (1) to determine the major aqueous and organic waste streams requiring treatment, (2) to determine the treatment steps necessary to make the aqueous and organic waste acceptable for treatment in existing treatment facilities on the ORR or off-site, and (3) to determine the processes necessary to decontaminate heterogeneous wastes that are considered debris.

  13. MWIP: Surrogate formulations for thermal treatment of low-level mixed waste. Part 4, Wastewater treatment sludges

    SciTech Connect

    Bostick, W.D.; Hoffmann, D.P.; Stevenson, R.J.; Richmond, A.A.; Bickford, D.F.

    1994-01-01

    The category of sludges, filter cakes, and other waste processing residuals represent the largest volume of low-level mixed (hazardous and radioactive) wastes within the US Department of Energy (DOE) complex. Treatment of these wastes to minimize the mobility of contaminants, and to eliminate the presence of free water, is required under the Federal Facility Compliance Act agreements between DOE and the Environmental Protection Agency. In the text, we summarize the currently available data for several of the high priority mixed-waste sludge inventories within DOE. Los Alamos National Laboratory TA-50 Sludge and Rocky Flats Plant By-Pass Sludge are transuranic (TRU)-contaminated sludges that were isolated with the use of silica-based filter aids. The Oak Ridge Y-12 Plant West End Treatment Facility Sludge is predominantly calcium carbonate and biomass. The Oak Ridge K-25 Site Pond Waste is a large-volume waste stream, containing clay, silt, and other debris in addition to precipitated metal hydroxides. We formulate ``simulants`` for the waste streams described above, using cerium oxide as a surrogate for the uranium or plutonium present in the authentic material. Use of nonradiological surrogates greatly simplifies material handling requirements for initial treatability studies. The use of synthetic mixtures for initial treatability testing will facilitate compositional variation for use in conjunction with statistical design experiments; this approach may help to identify any ``operating window`` limitations. The initial treatability testing demonstrations utilizing these ``simulants`` will be based upon vitrification, although the materials are also amenable to testing grout-based and other stabilization procedures. After the feasibility of treatment and the initial evaluation of treatment performance has been demonstrated, performance must be verified using authentic samples of the candidate waste stream.

  14. Inventory and treatment of compost maturation emissions in a municipal solid waste treatment facility.

    PubMed

    Dorado, Antonio D; Husni, Shafik; Pascual, Guillem; Puigdellivol, Carles; Gabriel, David

    2014-02-01

    Emissions of volatile organic compounds (VOCs) from the compost maturation building in a municipal solid waste treatment facility were inventoried by solid phase microextraction and gas chromatography-mass spectrometry. A large diversity of chemical classes and compounds were found. The highest concentrations were found for n-butanol, methyl ethyl ketone and limonene (ppmv level). Also, a range of compounds exceeded their odor threshold evidencing that treatment was needed. Performance of a chemical scrubber followed by two parallel biofilters packed with an advanced packing material and treating an average airflow of 99,300 m(3) h(-1) was assessed in the treatment of the VOCs inventoried. Performance of the odor abatement system was evaluated in terms of removal efficiency by comparing inlet and outlet abundances. Outlet concentrations of selected VOCs permitted to identify critical odorants emitted to the atmosphere. In particular, limonene was found as the most critical VOC in the present study. Only six compounds from the odorant group were removed with efficiencies higher than 90%. Low removal efficiencies were found for most of the compounds present in the emission showing a significant relation with their chemical properties (functionality and solubility) and operational parameters (temperature, pH and inlet concentration). Interestingly, benzaldehyde and benzyl alcohol were found to be produced in the treatment system.

  15. Development of a Waste Treatment Process to Deactivate Reactive Uranium Metal and Produce a Stable Waste Form

    SciTech Connect

    Gates-Anderson, D D; Laue, C A; Fitch, T E

    2002-01-17

    This paper highlights the results of initial investigations conducted to support the development of an integrated treatment process to convert pyrophoric metallic uranium wastes to a non-pyrophoric waste that is acceptable for land disposal. Several dissolution systems were evaluated to determine their suitability to dissolve uranium metal and that yield a final waste form containing uranium specie(s) amenable to precipitation, stabilization, adsorption, or ion exchange. During initial studies, one gram aliquots of uranium metal or the uranium alloy U-2%Mo were treated with 5 to 60 mL of selected reagents. Treatment systems screened included acids, acid mixtures, and bases with and without addition of oxidants. Reagents used included hydrochloric, sulfuric, nitric, and phosphoric acids, sodium hypochlorite, sodium hydroxide and hydrogen peroxide. Complete dissolution of the uranium turnings was achieved with the H{sub 3}PO{sub 4}/HCI system at room temperature within minutes. The sodium hydroxide/hydrogen peroxide, and sodium hypochlorite systems achieved complete dissolution but required elevated temperatures and longer reaction times. A ranking system based on criteria, such as corrosiveness, temperature, dissolution time, off-gas type and amount, and liquid to solid ratio, was designed to determine the treatment systems that should be developed further for a full-scale process. The highest-ranking systems, nitric acid/sulfuric acid and hydrochloric acid/phosphoric acid, were given priority in our follow-on investigations.

  16. Considerations for Net Zero Waste Installations: Treatment of Municipal Solid Waste

    DTIC Science & Technology

    2015-09-01

    of reducing paper use from this is to encourage two-sided ERDC/CERL TR-15-21 8 printing by setting printer defaults to this format. Another means...interactive html ------------. 2006. Solid Waste Management and Greenhouse Gases: A Life-Cycle Assessment of Emissions and Sinks, 3d ed. Washington, DC

  17. Effect of microwave pre-treatment of thickened waste activated sludge on biogas production from co-digestion of organic fraction of municipal solid waste, thickened waste activated sludge and municipal sludge.

    PubMed

    Ara, E; Sartaj, M; Kennedy, K

    2014-12-01

    Anaerobic co-digestion of organic fraction of municipal solid waste, with thickened waste activated sludge and primary sludge has the potential to enhance biodegradation of solid waste, increase longevity of existing landfills and lead to more sustainable development by improving waste to energy production. This study reports on mesophilic batch and continuous studies using different concentrations and combinations (ratios) of organic fraction of municipal solid waste, thickened waste activated sludge (microwave pre-treated and untreated) and primary sludge to assess the potential for improved biodegradability and specific biogas production. Improvements in specific biogas production for batch assays, with concomitant improvements in total chemical oxygen demand and volatile solid removal, were obtained with organic fraction of municipal solid waste:thickened waste activated sludge:primary sludge mixtures at a ratio of 50:25:25 (with and without thickened waste activated sludge microwave pre-treatment). This combination was used for continuous digester studies. At 15 d hydraulic retention times, the co-digestion of organic fraction of municipal solid waste:organic fraction of municipal solid waste:primary sludge and organic fraction of municipal solid waste:thickened waste activated sludge microwave:primary sludge resulted in a 1.38- and 1.46-fold increase in biogas production and concomitant waste stabilisation when compared with thickened waste activated sludge:primary sludge (50:50) and thickened waste activated sludge microwave:primary sludge (50:50) digestion at the same hydraulic retention times and volumetric volatile solid loading rate, respectively. The digestion of organic fraction of municipal solid waste with primary sludge and thickened waste activated sludge provides beneficial effects that could be implemented at municipal wastewater treatment plants that are operating at loading rates of less than design capacity.

  18. ADVERSE IMPACTS OF WASTE WATER TREATMENT ­ A CASE STUDY

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Industrial metal plating processes coat materials with metals, such as chromium, copper and nickel. After the plating process, excess metals are rinsed off and the rinse water is collected and then treated to remove metals prior to discharge of the rinse water into rivers. This waste water is typica...

  19. Electrochemical and photochemical treatment of aqueous waste streams

    SciTech Connect

    Farmer, J.C.; Pekala, R.W.; Wang, F.T.; Fix, D.V.; Volpe, A.M.; Dietrich, D.D.; Siegel, W.H.; Carley, J.F.

    1996-03-01

    Carbon aerogel electrodes have been used to remove NH{sub 4}ClO{sub 4} and heavy metals from aqueous waste streams. Photochemical oixdation with H{sub 2}O{sub 2} has been used to destroy organic contamination and is proposed as a means of avoiding the fouling of carbon aerogel electrodes.

  20. Assessing Waste Water Treatment Plant Effluent for Thyroid Hormone Disruption

    EPA Science Inventory

    Much information has been coming to light on the estrogenic and androgenic activity of chemicals present in the waste water stream and in surface waters, but much less is known about the presence of chemicals with thyroid activity. To address this issue, we have utilized two assa...

  1. Mixed Waste Treatment Using the ChemChar Thermolytic Detoxification Technique

    SciTech Connect

    Kuchynka, D.J.

    1997-01-01

    This R and D program addresses the treatment of mixed waste employing the ChemChar Thermolytic Detoxification process. Surrogate mixed waste streams will be treated in a four inch diameter, continuous feed, adiabatic reactor with the goal of meeting all regulatory treatment levels for the contaminants in the surrogates with the concomitant production of contaminant free by-products. Successful completion of this program will show that organic contaminants in mixed waste surrogates will be converted to a clean, energy rich synthesis gas capable of being used, without further processing, for power or heat generation. The inorganic components in the surrogates will be found to be adsorbed on a macroporous coal char activated carbon substrate which is mixed with the waste prior to treatment. These contaminants include radioactive metal surrogate species, RCRA hazardous metals and any acid gases formed during the treatment process. The program has three main tasks that will be performed to meet the above objectives. The first task is the design and construction of the four inch reactor at Mirage Systems in Sunnyvale, CA. The second task is production and procurement of the activated carbon char employed in the ChemChartest runs and identification of two surrogate mixed wastes. The last task is testing and operation of the reactor on char/surrogate waste mixtures to be performed at the University of Missouri. The deliverables for the project are a Design Review Report, Operational Test Plan, Topical Report and Final Report. This report contains only the results of the design and construction carbon production-surrogate waste identification tasks.Treatment of the surrogate mixed wastes has just begun and will not be reported in this version of the Final Report. The latter will be reported in the final version of the Final Report.

  2. Assessing the impacts of changes in treatment technology on energy and greenhouse gas balances for organic waste and wastewater treatment using historical data.

    PubMed

    Poulsen, Tjalfe G; Hansen, Jens Aage

    2009-11-01

    Historical data on organic waste and wastewater treatment during the period of 1970-2020 were used to assess the impact of treatment on energy and greenhouse gas (GHG) balances. The assessment included the waste fractions: Sewage sludge, food waste, yard waste and other organic waste (paper, plastic, etc.). Data were collected from Aalborg, a municipality located in Northern Denmark. During the period from 1970-2005, Aalborg Municipality has changed its waste treatment strategy from landfilling of all wastes toward composting of yard waste and incineration with combined heat and power production from the remaining organic municipal waste. Wastewater treatment has changed from direct discharge of untreated wastewater to full organic matter and nutrient (N, P) removal combined with anaerobic digestion of the sludge for biogas production with power and heat generation. These changes in treatment technology have resulted in the waste and wastewater treatment systems in Aalborg progressing from being net consumers of energy and net emitters of GHG, to becoming net producers of energy and net savers of GHG emissions (due to substitution of fossil fuels elsewhere). If it is assumed that the organic waste quantity and composition is the same in 1970 and 2005, the technology change over this time period has resulted in a progression from a net annual GHG emission of 200 kg CO( 2)-eq. capita(-1) in 1970 to a net saving of 170 kg CO(2)-eq. capita(-1) in 2005 for management of urban organic wastes.

  3. Application of analytic hierarchy process in a waste treatment technology assessment in Mexico.

    PubMed

    Taboada-González, Paul; Aguilar-Virgen, Quetzalli; Ojeda-Benítez, Sara; Cruz-Sotelo, Samantha

    2014-09-01

    The high per capita generation of solid waste and the environmental problems in major rural communities of Ensenada, Baja California, have prompted authorities to seek alternatives for waste treatment. In the absence of a selection methodology, three technologies of waste treatment with energy recovery (an anaerobic digester, a downdraft gasifier, and a plasma gasifier) were evaluated, taking the broader social, political, economic, and environmental issues into considerations. Using the scientific literature as a baseline, interviews with experts, decision makers and the community, and waste stream studies were used to construct a hierarchy that was evaluated by the analytic hierarchy process. In terms of the criteria, judgments, and assumptions made in the model, the anaerobic digester was found to have the highest rating and should consequently be selected as the waste treatment technology for this area. The study results showed low sensitivity, so alternative scenarios were not considered. The methodology developed in this study may be useful for other governments who wish to assess technologies to select waste treatment.

  4. Innovative systems for mixed waste retrieval and/or treatment in confined spaces

    SciTech Connect

    Fekete, L.J.; Ghusn, A.E.

    1993-03-01

    Fernald established operations in 1951 and produced uranium and other metals for use at other DOE facilities. A part of the sitewide remediation effort is the removal, treatment, and disposal of the K-65 wastes from Silos 1 and 2. These silos contain radium-bearing residues from the processing of pitchblende ore. An Engineering Evaluation/Cost Analysis was prepared to evaluate the removal action alternatives using the preliminary characterization data and select a preferred alternative. The selected alternative consisted of covering the K-65 residues and the silo dome. The remediation of the K-65 wastes consists of the retrieval and treatment of the wastes prior to final disposal, which has not yet been determined. Treatment will be performed in a new facility to be built adjacent to the silos. The wastes must be retrieved from silos in an efficient and reliable way and delivered to the treatment facility. The first challenge of covering the wastes with bentonite has been successfully met. The second phase of retrieving the wastes from the silos is not due for a few years. However, conceptual design and configuration of the retrieval system have been developed as part of the Conceptual Design Report. The system is based on the utilization of hydraulic mining techniques, and is based on similar successful applications. This report describes the emplacement of the bentonite grant and the design for the slurry retrieval system.

  5. Development of a processing and treatment solution for a thoria waste stream

    SciTech Connect

    Anderson, Andy; Mitchell, Charles; Jenkins, Jon; Simmons, Richard

    2007-07-01

    Waste Management Technology Ltd (WMT) has developed the optimal process for immobilizing a solid waste contaminated with thorium dioxide (thoria). The physical and chemical characteristics of the waste present challenges to producing a wasteform acceptable for disposal. Also, high-energy radiation from thorium's decay progeny requires a treatment plant with shielding and remote handling facilities. Key points of the paper are as follows. 1. Treatment options were investigated and the best practicable means identified as intimate mixing of the waste with cementitious grout. 2. Samples were analysed for particle size and organic contamination. 3. Small-scale active mixes resulted in a single treatment formulation for all the waste. Leach tests confirmed that the organic material is adequately retained within the immobilised waste provided activated carbon is included in the formulation. 4. Active mixes at the two litre scale confirmed that the formulation is mixable and the product acceptable and consistent with expectations from the earlier work. 5. WMT is constructing a treatment plant at its Winfrith site, based on remote grouting in a 200 litre drum with a sacrificial mixer. Inactive full-scale trials with such 200 litre drums were carried out after selection of simulants with the appropriate physical properties. (authors)

  6. Integrated demonstration of molten salt oxidation with salt recycle for mixed waste treatment

    SciTech Connect

    Hsu, P.C.

    1997-11-01

    Molten Salt Oxidation (MSO) is a thermal, nonflame process that has the inherent capability of completely destroying organic constituents of mixed wastes, hazardous wastes, and energetic materials while retaining inorganic and radioactive constituents in the salt. For this reason, MSO is considered a promising alternative to incineration for the treatment of a variety of organic wastes. Lawrence Livermore National Laboratory (LLNL) has prepared a facility and constructed an integrated pilot-scale MSO treatment system in which tests and demonstrations are performed under carefully controlled (experimental) conditions. The system consists of a MSO processor with dedicated off-gas treatment, a salt recycle system, feed preparation equipment, and equipment for preparing ceramic final waste forms. This integrated system was designed and engineered based on laboratory experience with a smaller engineering-scale reactor unit and extensive laboratory development on salt recycle and final forms preparation. In this paper we present design and engineering details of the system and discuss its capabilities as well as preliminary process demonstration data. A primary purpose of these demonstrations is identification of the most suitable waste streams and waste types for MSO treatment.

  7. Advanced Mixed Waste Treatment Project melter system preliminary design technical review meeting

    SciTech Connect

    Eddy, T.L.; Raivo, B.D.; Soelberg, N.R.; Wiersholm, O.

    1995-02-01

    The Idaho National Engineering Laboratory Advanced Mixed Waste Treatment Project sponsored a plasma are melter technical design review meeting to evaluate high-temperature melter system configurations for processing heterogeneous alpha-contaminated low-level radioactive waste (ALLW). Thermal processing experts representing Department of Energy contractors, the Environmental Protection Agency, and private sector companies participated in the review. The participants discussed issues and evaluated alternative configurations for three areas of the melter system design: plasma torch melters and graphite arc melters, offgas treatment options, and overall system configuration considerations. The Technical Advisory Committee for the review concluded that graphite arc melters are preferred over plasma torch melters for processing ALLW. Initiating involvement of stakeholders was considered essential at this stage of the design. For the offgas treatment system, the advisory committee raised the question whether to a use wet-dry or a dry-wet system. The committee recommended that the waste stream characterization, feed preparation, and the control system are essential design tasks for the high-temperature melter treatment system. The participants strongly recommended that a complete melter treatment system be assembled to conduct tests with nonradioactive surrogate waste material. A nonradioactive test bed would allow for inexpensive design and operational changes prior to assembling a system for radioactive waste treatment operations.

  8. Tank Waste Treatment Science Task quarterly report for January--March 1995

    SciTech Connect

    LaFemina, J.P.; Anderson, G.S.; Blanchard, D.L.

    1995-04-01

    The pretreatment Technology Development Project is one of seven Tank Waste Remediation (TWRS) System projects being conducted at the Pacific Northwest Laboratory. A key objective of this Project, and of the Tank Waste Treatment Science Task within it, is to provide the technical basis and scientific understanding to support TWRS baseline decisions and actions; in particular, TPA Milestone M50-03, the 1998 sludge pretreatment decision regarding the level of pretreatment to be incorporated into the tank waste process flowsheets. Work performed by this task during the second quarter of FY 1995 (January--March 1995) is detailed in this report. Work for the first quarter reported in Tank Waste Treatment Science Task, Quarterly Report for October--December 1994.

  9. Emissions model of waste treatment operations at the Idaho Chemical Processing Plant

    SciTech Connect

    Schindler, R.E.

    1995-03-01

    An integrated model of the waste treatment systems at the Idaho Chemical Processing Plant (ICPP) was developed using a commercially-available process simulation software (ASPEN Plus) to calculate atmospheric emissions of hazardous chemicals for use in an application for an environmental permit to operate (PTO). The processes covered by the model are the Process Equipment Waste evaporator, High Level Liquid Waste evaporator, New Waste Calcining Facility and Liquid Effluent Treatment and Disposal facility. The processes are described along with the model and its assumptions. The model calculates emissions of NO{sub x}, CO, volatile acids, hazardous metals, and organic chemicals. Some calculated relative emissions are summarized and insights on building simulations are discussed.

  10. Oak Ridge National Lebroatory Liquid&Gaseous Waste Treatment System Strategic Plan

    SciTech Connect

    Van Hoesen, S.D.

    2003-09-09

    Excellence in Laboratory operations is one of the three key goals of the Oak Ridge National Laboratory (ORNL) Agenda. That goal will be met through comprehensive upgrades of facilities and operational approaches over the next few years. Many of ORNL's physical facilities, including the liquid and gaseous waste collection and treatment systems, are quite old, and are reaching the end of their safe operating life. The condition of research facilities and supporting infrastructure, including the waste handling facilities, is a key environmental, safety and health (ES&H) concern. The existing infrastructure will add considerably to the overhead costs of research due to increased maintenance and operating costs as these facilities continue to age. The Liquid Gaseous Waste Treatment System (LGWTS) Reengineering Project is a UT-Battelle, LLC (UT-B) Operations Improvement Program (OIP) project that was undertaken to develop a plan for upgrading the ORNL liquid and gaseous waste systems to support ORNL's research mission.

  11. Thermal treatment and utilization of Al-rich waste in high calcium fly ash geopolymeric materials

    NASA Astrophysics Data System (ADS)

    Chindaprasirt, Prinya; Rattanasak, Ubolluk; Vongvoradit, Pimdao; Jenjirapanya, Supichart

    2012-09-01

    The Al-rich waste with aluminium and hydrocarbon as the major contaminant is generated at the wastewater treatment unit of a polymer processing plant. In this research, the heat treatment of this Al-rich waste and its use to adjust the silica/alumina ratio of the high calcium fly ash geopolymer were studied. To recycle the raw Al-rich waste, the waste was dried at 110°C and calcined at 400 to 1000°C. Mineralogical analyses were conducted using X-ray diffraction (XRD) to study the phase change. The increase in calcination temperature to 600, 800, and 1000°C resulted in the phase transformation. The more active alumina phase of active γ-Al2O3 was obtained with the increase in calcination temperature. The calcined Al-rich waste was then used as an additive to the fly ash geopolymer by mixing with high calcium fly ash, water glass, 10 M sodium hydroxide (NaOH), and sand. Test results indicated that the calcined Al-rich waste could be used as an aluminium source to adjust the silica/alumina ratio and the strength of geopolymeric materials. The fly ash geopolymer mortar with 2.5wt% of the Al-rich waste calcined at 1000°C possessed the 7-d compressive strength of 34.2 MPa.

  12. Treatment of copper industry waste and production of sintered glass-ceramic.

    PubMed

    Coruh, Semra; Ergun, Osman Nuri; Cheng, Ta-Wui

    2006-06-01

    Copper waste is iron-rich hazardous waste containing heavy metals such as Cu, Zn, Co, Pb. The results of leaching tests show that the concentration of these elements exceeds the Turkish and EPA regulatory limits. Consequently, this waste cannot be disposed of in its present form and therefore requires treatment to stabilize it or make it inert prior to disposal. Vitrification was selected as the technology for the treatment of the toxic waste under investigation. During the vitrification process significant amounts of the toxic organic and inorganic chemical compounds could be destroyed, and at the same time, the metal species are immobilized as they become an integral part of the glass matrix. The copper flotation waste samples used in this research were obtained from the Black Sea Copper Works of Samsun, Turkey. The samples were vitrified after being mixed with other inorganic waste and materials. The copper flotation waste and their glass-ceramic products were characterized by X-ray analysis (XRD), scanning electron microscopy and by the toxicity characteristic leaching procedure test. The products showed very good chemical durability. The glass-ceramics fabricated at 850 degrees C/2 h have a large application potential especially as construction and building materials.

  13. Mechanical Treatment of Raw Waste Lumber an Effective Way to Preserve the Ecology and Resources

    NASA Astrophysics Data System (ADS)

    Fomin, Anatoly A.; Gusev, Vladimir G.; Yudin, Roman V.; Timerbaev, Nail F.; Retyunskiy, Oleg Yu

    2016-08-01

    Alternative process flowsheet machining of the machining of raw waste lumber were analysed, and it was implemented in a real machine model based on the chosen scheme. The forming process of the treated surface of the stock material was examined, and consequently the mathematical models of the geometric errors in terms of independent factors of the profile milling process were defined. Based on these models is possible to construct a treatment process of the raw waste lumber with minimal errors on the surfaces which were treated. The manufacturing of products from raw waste lumber allows to reduce the volume of deforestation and helps to preserve the ecology and economize the material resources.

  14. Anaerobic treatment of aircraft deicing wastes: A technology assessment. Final report

    SciTech Connect

    1998-09-01

    The work contained in the study documents the fact that deicing wastes containing ethylene glycol (EG) and propylene glycol (PG) may be effectively treated using an anaerobic biological process. In the report, the treatment of aircraft deicing wastes under anaerobic methanogenic conditions is examined in detail. The major project tasks were: airport sampling to define the characteristics of waste from deicing operations; testing of EG and PG degradation using laboratory-scale reactors and then by means of serum bottle tests; operation of an anaerobic fluidized bed reactor (AFBR); and analysis of the energy aspects of anaerobic processes with cost comparisons to traditional aerobic processes.

  15. Life cycle comparison of waste-to-energy alternatives for municipal waste treatment in Chilean Patagonia.

    PubMed

    Bezama, Alberto; Douglas, Carla; Méndez, Jacqueline; Szarka, Nóra; Muñoz, Edmundo; Navia, Rodrigo; Schock, Steffen; Konrad, Odorico; Ulloa, Claudia

    2013-10-01

    The energy system in the Region of Aysén, Chile, is characterized by a strong dependence on fossil fuels, which account for up to 51% of the installed capacity. Although the implementation of waste-to-energy concepts in municipal waste management systems could support the establishment of a more fossil-independent energy system for the region, previous studies have concluded that energy recovery systems are not suitable from an economic perspective in Chile. Therefore, this work intends to evaluate these technical options from an environmental perspective, using life cycle assessment as a tool for a comparative analysis, considering Coyhaique city as a case study. Three technical alternatives were evaluated: (i) landfill gas recovery and flaring without energy recovery; (ii) landfill gas recovery and energy use; and (iii) the implementation of an anaerobic digestion system for the organic waste fraction coupled with energy recovery from the biogas produced. Mass and energy balances of the three analyzed alternatives have been modeled. The comparative LCA considered global warming potential, abiotic depletion and ozone layer depletion as impact categories, as well as required raw energy and produced energy as comparative regional-specific indicators. According to the results, the use of the recovered landfill gas as an energy source can be identified as the most environmentally appropriate solution for Coyhaique, especially when taking into consideration the global impact categories.

  16. Tank waste treatment science task quarterly report, April 1995--June 1995

    SciTech Connect

    LaFemina, J.P.

    1995-07-01

    This report describes the work performed by the Pacific Northwest Laboratory (PNL) during the third quarter of FY 1995 under the Tank Waste Treatment Science Task of the Tank Waste Remediation System (TWRS) Pretreatment Technology Development Project. Work was performed in the following areas: (1) analytical methods development, (2) sludge dissolution modeling, (3) sludge characterization studies, (4) sludge component speciation, (5) pretreatment chemistry evaluation, and (6) colloidal studies for solid-liquid separations.

  17. The National Shipbuilding Research Program. Waste Water Treatment Technology Survey

    DTIC Science & Technology

    1998-05-18

    clearwell . From this clearwell , the contaminated water is transferred to the induced air flotation process. The influent water is chemically pretreated to...stream is directed to a waste oil storage tank while the contaminated water flows into the equalization clearwell . From this clearwell , the...contaminated water flows into the equalization clearwell . From this clearwell , the contaminated water is transferred to the Induced Air Flotation

  18. Waste water treatment: Chemical industry. (Latest citations from Pollution Abstracts). Published Search

    SciTech Connect

    Not Available

    1992-05-01

    The bibliography contains citations concerning wastewater treatment of industrial pollutants. The use and effectiveness of biological treatments and carbon additives are examined. References also discuss problems and recommendations for the removal of mercury and its compounds, fertilizers, and pesticides from polluted waste water. (Contains 250 citations and includes a subject term index and title list.)

  19. Plasma-chemical technology of treatment of halogen-containing waste including polychlorinated biphenyls

    NASA Astrophysics Data System (ADS)

    Gusarov, E. E.; Malkov, Yu. P.; Stepanov, S. G.; Troshchinenko, G. A.; Zasypkin, I. M.

    2010-12-01

    We consider the developed plasma-chemical technology of halogen-containing substances treatment. The paper contains the experimental plant schematic and the positive results obtained after the treatment of tetrafluoromethane, ozone-damaging freon 12, polychlorinated biphenyls (PCB), the waste containing fluoride and chloride organics. The technology is proposed for industrial application.

  20. 76 FR 34200 - Land Disposal Restrictions: Revision of the Treatment Standards for Carbamate Wastes

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-06-13

    ... AGENCY 40 CFR Parts 268 and 271 RIN 2050-AG65 Land Disposal Restrictions: Revision of the Treatment...) treatment standards for hazardous wastes from the production of carbamates and carbamate commercial chemical... action proposes to remove the carbamate Regulated Constituents from the table of Universal...

  1. LAND TREATMENT AND THE TOXICITY RESPONSE OF SOIL CONTAMINATED WITH WOOD PRESERVING WASTE

    EPA Science Inventory

    Soils contaminated with wood preserving wastes, including pentachlo-rophenol (PCP) and creosote, are treated at field-scale in an engineered prepared-bed system consisting of two one-acre land treatment units (LTUs). The concentration of selected indicator compounds of treatment ...

  2. Biotechnological possibilities for waste tyre-rubber treatment.

    PubMed

    Holst, O; Stenberg, B; Christiansson, M

    1998-01-01

    Every year large amounts of spent rubber material, mainly from rubber tyres, are discarded. Of the annual total global production of rubber material, which amounts to 16-17 million tonnes, approximately 65% is used for the production of tyres. About 250 millions spent car tyres are generated yearly in USA only. This huge amount of waste rubber material is an environmental problem of great concern. Various ways to remediate the problem have been proposed. Among these are road fillings and combustion in kilns. Spent tyres, however, comprise valuable material that could be recycled if a proper technique can be developed. One way of recycling old tyres is to blend ground spent rubber with virgin material followed by vulcanization. The main obstacle to this recycling is bad adhesion between the crumb and matrix of virgin rubber material due to little formation of interfacial sulphur crosslinks. Micro-organisms able to break sulphur-sulphur and sulphur-carbon bonds can be used to devulcanize waste rubber in order to make polymer chains on the surface more flexible and facilitate increased binding upon vulcanization. Several species belonging to both Bacteria and Archaea have this ability. Mainly sulphur oxidizing species, such as different species of the genus Thiobacillus and thermoacidophiles of the order of Sulfolobales, have been studied in this context. The present paper will give a background to the problem and an overview of the biotechnological possibilities for solutions of waste rubber as an environmental problem, focusing on microbial desulphurization.

  3. TREATMENT OF METAL-LADEN HAZARDOUS WASTES WITH ADVANCED CLEAN COAL TECHNOLOGY BY-PRODUCTS

    SciTech Connect

    James T. Cobb, Jr.

    2003-09-12

    Metal-laden wastes can be stabilized and solidified using advanced clean coal technology by-products (CCTBs)--fluid bed combustor ash and spray drier solids. These utility-generated treatment chemicals are available for purchase through brokers, and commercial applications of this process are being practiced by treaters of metal-laden hazardous waste. A complex of regulations governs this industry, and sensitivities to this complex has discouraged public documentation of treatment of metal-laden hazardous wastes with CCTBs. This report provides a comprehensive public documentation of laboratory studies that show the efficacy of the stabilization and solidification of metal-laden hazardous wastes--such as lead-contaminated soils and sandblast residues--through treatment with CCTBs. It then describes the extensive efforts that were made to obtain the permits allowing a commercial hazardous waste treater to utilize CCTBs as treatment chemicals and to install the equipment required to do so. It concludes with the effect of this lengthy process on the ability of the treatment company to realize the practical, physical outcome of this effort, leading to premature termination of the project.

  4. Integrated process analysis of treatment systems for mixed low level waste

    SciTech Connect

    Cooley, C.R.; Schwinkendorf, W.E. |; Bechtold, T.E.

    1997-10-01

    Selection of technologies to be developed for treatment of DOE`s mixed low level waste (MLLW) requires knowledge and understanding of the expected costs, schedules, risks, performance, and reliability of the total engineered systems that use these technologies. Thus, an integrated process analysis program was undertaken to identify the characteristics and needs of several thermal and nonthermal systems. For purposes of comparison, all systems were conceptually designed for a single facility processing the same amount of waste at the same rate. Thirty treatment systems were evaluated ranging from standard incineration to innovative thermal systems and innovative nonthermal chemical treatment. Treating 236 million pounds of waste in 20 years through a central treatment was found to be the least costly option with total life cycle cost ranging from $2.1 billion for a metal melting system to $3.9 billion for a nonthermal acid digestion system. Little cost difference exists among nonthermal systems or among thermal systems. Significant cost savings could be achieved by working towards maximum on line treatment time per year; vitrifying the final waste residue; decreasing front end characterization segregation and sizing requirements; using contaminated soil as the vitrifying agent; and delisting the final vitrified waste form from Resource Conservation and Recovery Act (RCRA) Land Disposal Restriction (LDR) requirements.

  5. Energy performance of an integrated bio-and-thermal hybrid system for lignocellulosic biomass waste treatment.

    PubMed

    Kan, Xiang; Yao, Zhiyi; Zhang, Jingxin; Tong, Yen Wah; Yang, Wenming; Dai, Yanjun; Wang, Chi-Hwa

    2017-03-01

    Lignocellulosic biomass waste, a heterogeneous complex of biodegradables and non-biodegradables, accounts for large proportion of municipal solid waste. Due to limitation of single-stage treatment, a two-stage hybrid AD-gasification system was proposed in this work, in which AD acted as pre-treatment to convert biodegradables into biogas followed by gasification converting solid residue into syngas. Energy performance of single and two-stage systems treating 3 typical lignocellulosic wastes was studied using both experimental and numerical methods. In comparison with conventional single-stage gasification treatment, this hybrid system could significantly improve the quality of produced gas for all selected biomass wastes and show its potential in enhancing total gas energy production by a maximum value of 27% for brewer's spent grain treatment at an organic loading rate (OLR) of 3gVS/L/day. The maximum overall efficiency of the hybrid system for horticultural waste treatment was 75.2% at OLR of 11.3gVS/L/day, 5.5% higher than conventional single-stage system.

  6. Exergy analysis in the assessment of the sustainability of waste gas treatment systems.

    PubMed

    Dewulf, J; Van Langenhove, H; Dirckx, J

    2001-06-12

    This study focuses on the sustainability of different technological options for the treatment of waste gases from a waste water treatment plant loaded with volatile organic compounds. The options considered are biofiltration, active carbon adsorption and catalytic and thermal oxidation. The amount of resources and utilities to construct and operate each system have been investigated from the point of view of the Second Law of thermodynamics. The unit in which all resources are treated is Joules of exergy. It was concluded that biofiltration was the most exergetically efficient system. The cumulative exergy consumption of the resources and utilities for construction and operation have been quantified in exergy terms. Further on, the requirements for the abatement of emissions generated by operating the waste gas treatment systems and the amount of renewables have been taken into account in the assessment of the sustainability of the waste gas treatment technologies. Finally, a comparison between exergy analysis and life cycle analysis in assessing the sustainability of the waste gas treatment options, is presented.

  7. Treatment of M-area mixed wastes at the Savannah River Site

    SciTech Connect

    Not Available

    1994-06-01

    The Department of Energy has prepared this environmental assessment, DOE/EA-0918, to assess the potential environmental impacts of the treatment of mixed wastes currently stored in the M-Area at the Savannah River Site, near Aiken, South Carolina. DOE is proposing to treat and stabilize approximately 700,000 gallons of mixed waste currently stored in the Interim Treatment/Storage Facility (IT/SF) and Mixed Waste Storage Shed (MWSS). This waste material is proposed to be stabilized using a vitrification process and temporarily stored until final disposal is available by the year 2005. This document has been prepared to assess the potential environmental impacts attributable to the treatment and stabilization of M-area mixed wastes, the closure of the interim storage area, and storage of the vitrified waste until disposal in onsite RCRA vaults. Based on the analyses in the environmental assessment, the Department of Energy has determined that the proposed action is not a major Federal action significantly affecting the quality of the human environment within the meaning of the National Environmental Policy Act (NEPA) of 1969. Therefore, the preparation of an environmental impact statement is not required, and the Department of Energy is issuing this finding of no significant impact.

  8. Treatment of Bottled Liquid Waste During Remediation of the Hanford 618-10 Burial Ground - 13001

    SciTech Connect

    Faulk, Darrin E.; Pearson, Chris M.; Vedder, Barry L.; Martin, David W.

    2013-07-01

    A problematic waste form encountered during remediation of the Hanford Site 618-10 burial ground consists of bottled aqueous waste potentially contaminated with regulated metals. The liquid waste requires stabilization prior to landfill disposal. Prior remediation activities at other Hanford burial grounds resulted in a standard process for sampling and analyzing liquid waste using manual methods. Due to the highly dispersible characteristics of alpha contamination, and the potential for shock sensitive chemicals, a different method for bottle processing was needed for the 618-10 burial ground. Discussions with the United States Department of Energy (DOE) and United States Environmental Protection Agency (EPA) led to development of a modified approach. The modified approach involves treatment of liquid waste in bottles, up to one gallon per bottle, in a tray or box within the excavation of the remediation site. Bottles are placed in the box, covered with soil and fixative, crushed, and mixed with a Portland cement grout. The potential hazards of the liquid waste preclude sampling prior to treatment. Post treatment verification sampling is performed to demonstrate compliance with land disposal restrictions and disposal facility acceptance criteria. (authors)

  9. Application of thermal plasma technology for the treatment of solid wastes in China: An overview.

    PubMed

    Li, Jun; Liu, Kou; Yan, Shengjun; Li, Yaojian; Han, Dan

    2016-12-01

    With its enormous social and economical development, China is now experiencing a rapid increase in solid wastes generation and growing pressure for solid wastes management. Today solid wastes in China are mainly managed by a combination of landfill, incineration, and composting. Within different possible treatment routes, thermal plasma technology (TPT) offers the advantages of efficiently gasifying the organic contents of solid wastes into syngas that can be used for heat and power generation, and vitrifying the inorganics simultaneously into glassy slag with very low leachabilities. This process makes it feasible for near-zero emission into the environment while making use of all the useful components. Encouraged by the industrial operations of solid wastes treatment plants using TPT in some countries, several plasma demonstration projects have already been undertaken in China. This paper provides a preliminary overview of the current laboratory researches and industrial developments status of TPT for the treatment of solid wastes in China and analyzes the existing challenges. Furthermore, the future prospects for TPT in China are also discussed.

  10. Mixed-waste treatment -- What about the residuals? A comparative analysis of MSO and incineration

    SciTech Connect

    1993-06-01

    This report examines the issues concerning final waste forms, or residuals, that result from the treatment of mixed waste in molten salt oxidation (MSO) and incinerator systems. MSO is a technology with the potential to treat a certain segment of the waste streams at US Department of Energy (DOE) sites. MSO was compared with incineration because incineration is the best demonstrated available technology (BDAT) for the same waste streams. The Grand Junction Projects Office (GJPO) and Oak Ridge National Laboratory (ORNL) prepared this report for the DOE Office of Environmental Restoration (OER). The goals of this study are to objectively evaluate the anticipated residuals from MSO and incineration, examine regulatory issues for these final waste forms, and determine secondary treatment options. This report, developed to address concerns that MSO residuals present unique disposal difficulties, is part of a larger effort to successfully implement MSO as a treatment technology for mixed and hazardous waste. A Peer Review Panel reviewed the MSO technology in November 1991, and the implementation effort is ongoing under the guidance of the MSO Task Force.

  11. Characterizing the transformation and transfer of nitrogen during the aerobic treatment of organic wastes and digestates

    SciTech Connect

    Zeng Yang; Guardia, Amaury de; Daumoin, Mylene; Benoist, Jean-Claude

    2012-12-15

    Highlights: Black-Right-Pointing-Pointer Ammonia emissions varied depending on the nature of wastes and the treatment conditions. Black-Right-Pointing-Pointer Nitrogen losses resulted from ammonia emissions and nitrification-denitrification. Black-Right-Pointing-Pointer Ammonification can be estimated from biodegradable carbon and carbon/nitrogen ratio. Black-Right-Pointing-Pointer Ammonification was the main process contributing to N losses. Black-Right-Pointing-Pointer Nitrification rate was negatively correlated to stripping rate of ammonia nitrogen. - Abstract: The transformation and transfer of nitrogen during the aerobic treatment of seven wastes were studied in ventilated air-tight 10-L reactors at 35 Degree-Sign C. Studied wastes included distinct types of organic wastes and their digestates. Ammonia emissions varied depending on the kind of waste and treatment conditions. These emissions accounted for 2-43% of the initial nitrogen. Total nitrogen losses, which resulted mainly from ammonia emissions and nitrification-denitrification, accounted for 1-76% of the initial nitrogen. Ammonification was the main process responsible for nitrogen losses. An equation which allows estimating the ammonification flow of each type of waste according to its biodegradable carbon and carbon/nitrogen ratio was proposed. As a consequence of the lower contribution of storage and leachate rates, stripping and nitrification rates of ammonia nitrogen were negatively correlated. This observation suggests the possibility of promotingnitrification in order to reduce ammonia emissions.

  12. Overview of a conceptualized waste water treatment facility for the Consolidated Incinerator Facility

    SciTech Connect

    McCabe, D.J.

    1992-02-07

    The offgas system in the Consolidated Incinerator Facility (CIF) will generate an aqueous waste stream which is expected to contain hazardous, nonhazardous, and radioactive components. The actual composition of this waste stream will not be identified until startup of the facility, and is expected to vary considerably. Wastewater treatment is being considered as a pretreatment to solidification in order to make a more stable final waste form and to reduce disposal costs. A potential treatment scenario has been defined which may allow disposition of this waste in compliance with all applicable regulations. The conceptualized wastewater treatment plant is based on literature evaluations for treating hazardous metals. Laboratory tests hwill be run to verify the design for its ability to remove the hazardous and radioactive components from this waste stream. The predominant mechanism employed for removal of the hazardous and radioactive metal ions is coprecipitation. The literature indicates that reasonably low quantities of hazardous metals can be achieved with this technique. The effect on the radioactive metal ions is not predictable and has not been tested. The quantity of radioactive metal ions predicted to be present in the waste is significantly less than the solubility limit of those ions, but is higher than the discharge guidelines established by DOE Order 5400.5.

  13. The greenhouse gas and energy balance of different treatment concepts for bio-waste.

    PubMed

    Ortner, Maria E; Müller, Wolfgang; Bockreis, Anke

    2013-10-01

    The greenhouse gas (GHG) and energy performance of bio-waste treatment plants been investigated for three characteristic bio-waste treatment concepts: composting; biological drying for the production of biomass fuel fractions; and anaerobic digestion. Compared with other studies about the environmental impacts of bio-waste management, this study focused on the direct comparison of the latest process concepts and state-of-the-art emission control measures. To enable a comparison, the mass balance and products were modelled for all process concepts assuming the same bio-waste amounts and properties. In addition, the value of compost as a soil improver was included in the evaluation, using straw as a reference system. This aspect has rarely been accounted for in other studies. The study is based on data from operational facilities combined with literature data. The results show that all three concepts contribute to a reduction of GHG emissions and show a positive balance for cumulated energy demand. However, in contrast to other studies, the advantage of anaerobic digestion compared with composting is smaller as a result of accounting for the soil improving properties of compost. Still, anaerobic digestion is the environmentally superior solution. The results are intended to inform decision makers about the relevant aspects of bio-waste treatment regarding the environmental impacts of different bio-waste management strategies.

  14. Analysis of accident sequences and source terms at treatment and storage facilities for waste generated by US Department of Energy waste management operations

    SciTech Connect

    Mueller, C.; Nabelssi, B.; Roglans-Ribas, J.; Folga, S.; Policastro, A.; Freeman, W.; Jackson, R.; Mishima, J.; Turner, S.

    1996-12-01

    This report documents the methodology, computational framework, and results of facility accident analyses performed for the US Department of Energy (DOE) Waste Management Programmatic Environmental Impact Statement (WM PEIS). The accident sequences potentially important to human health risk are specified, their frequencies assessed, and the resultant radiological and chemical source terms evaluated. A personal-computer-based computational framework and database have been developed that provide these results as input to the WM PEIS for the calculation of human health risk impacts. The WM PEIS addresses management of five waste streams in the DOE complex: low-level waste (LLW), hazardous waste (HW), high-level waste (HLW), low-level mixed waste (LLMW), and transuranic waste (TRUW). Currently projected waste generation rates, storage inventories, and treatment process throughputs have been calculated for each of the waste streams. This report summarizes the accident analyses and aggregates the key results for each of the waste streams. Source terms are estimated, and results are presented for each of the major DOE sites and facilities by WM PEIS alternative for each waste stream. Key assumptions in the development of the source terms are identified. The appendices identify the potential atmospheric release of each toxic chemical or radionuclide for each accident scenario studied. They also discuss specific accident analysis data and guidance used or consulted in this report.

  15. Environmental assessment for the Waste Water Treatment Facility at the West Valley Demonstration Project and finding of no significant impact

    SciTech Connect

    Not Available

    1992-12-31

    The possible environmental impacts from the construction and operation of a waste water treatment facility for the West Valley Demonstration Project are presented. The West Valley Project is a demonstration project on the solidification of high-level radioactive wastes. The need for the facility is the result of a rise in the work force needed for the project which rendered the existing sewage treatment plant incapable of meeting the nonradioactive waste water treatment needs.

  16. 40 CFR 262.212 - Making the hazardous waste determination at an on-site interim status or permitted treatment...

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... permitted treatment, storage or disposal facility. (e) If the unwanted material is a hazardous waste, the... 40 Protection of Environment 26 2011-07-01 2011-07-01 false Making the hazardous waste... 262.212 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES...

  17. 40 CFR 262.212 - Making the hazardous waste determination at an on-site interim status or permitted treatment...

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... permitted treatment, storage or disposal facility. (e) If the unwanted material is a hazardous waste, the... 40 Protection of Environment 27 2013-07-01 2013-07-01 false Making the hazardous waste... 262.212 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES...

  18. 77 FR 50622 - Land Disposal Restrictions: Site-Specific Treatment Variance for Hazardous Selenium-Bearing Waste...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-08-22

    ... Selenium-Bearing Waste Treated by U.S. Ecology Nevada in Beatty, NV AGENCY: Environmental Protection Agency... of a hazardous selenium- bearing waste generated by the Owens-Brockway Glass Container Company in... Land Disposal Restrictions treatment standard for selenium-bearing wastes, and as such cannot...

  19. Assessment of natural gas technology opportunities in the treatment of selected metals containing wastes. Topical report, June 1994-August 1995

    SciTech Connect

    McGervey, J.; Holmes, J.G.; Bluestein, J.

    1995-08-01

    The report analyzes the disposal of certain waste streams that contain heavy metals, as determined by Resource Conservation and Recovery Act (RCRA) regulations. Generation of the wastes, the regulatory status of the wastes, and current treatment practices are characterized, and the role of natural gas is determined. The four hazardous metal waste streams addressed in this report are electric arc furnace (EAF) dust, electroplating sludge wastes, used and off-specification circuit boards and cathode ray tubes, and wastes from lead manufacturing. This report assesses research and development opportunities relevant to natural gas technologies that may result from current and future enviromental regulations.

  20. Comparison of steam sterilization conditions efficiency in the treatment of Infectious Health Care Waste.

    PubMed

    Maamari, Olivia; Mouaffak, Lara; Kamel, Ramza; Brandam, Cedric; Lteif, Roger; Salameh, Dominique

    2016-03-01

    Many studies show that the treatment of Infectious Health Care Waste (IHCW) in steam sterilization devices at usual operating standards does not allow for proper treatment of Infectious Health Care Waste (IHCW). Including a grinding component before sterilization allows better waste sterilization, but any hard metal object in the waste can damage the shredder. The first objective of the study is to verify that efficient IHCW treatment can occur at standard operating parameters defined by the contact time-temperature couple in steam treatment systems without a pre-mixing/fragmenting or pre-shredding step. The second objective is to establish scientifically whether the standard operation conditions for a steam treatment system including a step of pre-mixing/fragmenting were sufficient to destroy the bacterial spores in IHCW known to be the most difficult to treat. Results show that for efficient sterilization of dialysis cartridges in a pilot 60L steam treatment system, the process would require more than 20 min at 144°C without a pre-mixing/fragmenting step. In a 720L steam treatment system including pre-mixing/fragmenting paddles, only 10 min at 144°C are required to sterilize IHCW proved to be sterilization challenges such as dialysis cartridges and diapers in normal conditions of rolling.

  1. Integrated gasification and plasma cleaning for waste treatment: A life cycle perspective

    SciTech Connect

    Evangelisti, Sara; Tagliaferri, Carla; Clift, Roland; Lettieri, Paola; Taylor, Richard; Chapman, Chris

    2015-09-15

    Highlights: • A life cycle assessment of an advanced two-stage process is undertaken. • A comparison of the impacts of the process when fed with 7 feedstock is presented. • Sensitivity analysis on the system is performed. • The treatment of RDF shows the lowest impact in terms of both GWP and AP. • The plasma shows a small contribution to the overall impact of the plant. - Abstract: In the past, almost all residual municipal waste in the UK was landfilled without treatment. Recent European waste management directives have promoted the uptake of more sustainable treatment technologies, especially for biodegradable waste. Local authorities have started considering other options for dealing with residual waste. In this study, a life cycle assessment of a future 20 MWe plant using an advanced two-stage gasification and plasma technology is undertaken. This plant can thermally treat waste feedstocks with different composition and heating value to produce electricity, steam and a vitrified product. The objective of the study is to analyse the environmental impacts of the process when fed with seven different feedstocks (including municipal solid waste, solid refuse fuel, reuse-derived fuel, wood biomass and commercial & industrial waste) and identify the process steps which contribute more to the environmental burden. A scenario analysis on key processes, such as oxygen production technology, metal recovery and the appropriate choice for the secondary market aggregate material, is performed. The influence of accounting for the biogenic carbon content in the waste from the calculations of the global warming potential is also shown. Results show that the treatment of the refuse-derived fuel has the lowest impact in terms of both global warming potential and acidification potential because of its high heating value. For all the other impact categories analysed, the two-stage gasification and plasma process shows a negative impact for all the waste streams

  2. Evaluation of pre-treatment processes for increasing biodegradability of agro-food wastes.

    PubMed

    Hidalgo, D; Sastre, E; Gómez, M; Nieto, P

    2012-01-01

    Anaerobic digestion (AD) technology can be employed for treating sewage sludge, livestock waste or food waste. Generally, the hydrolysis stage is the rate-limiting step of the AD processes for solid waste degradation. Therefore, physical, chemical and biological pre-treatment methods or their combination are required, in order to reduce the rate of such a limiting step. In this study, four methods (mechanical shredding, acid hydrolysis, alkaline hydrolysis and sonication) were tested to improve methane production and anaerobic biodegradability of different agro-food wastes and their mixtures. The kinetics of anaerobic degradation and methane production ofpre-treated individual wastes and selected mixtures were investigated with batch tests. Sonication at lower frequencies (37 kHz) proved to give the best results with methane productivity enhancements of over 100% in the case of pig manure and in the range of 10-47% for the other wastes assayed. Furthermore, the ultimate methane production was proportional, in all the cases, to the specific energy input applied (Es). Sonication can, thus, enhance waste digestion and the rate and quantity of biogas generated. The behaviour of the other pre-treatments under the conditions assayed is not significant. Only a slight enhancement of biogas production (around 10%) was detected for whey and waste activated sludge (WAS) after mechanical shredding. The lack of effectiveness of chemical pre-treatments (acid and alkaline hydrolysis) can be justified by the inhibition of the methanogenic process due to the presence of high concentrations of sodium (up to 8 g l(-1) in some tests). Only in the case of WAS did the acid hydrolysis considerably increase the biodegradability of the sample (79%), because in this case no inhibition by sodium took place. Some hints of a synergistic effect have been observed when co-digestion of the mixtures was performed.

  3. Technical Safety Requirements for the B695 Segment of the Decontamination and Waste Treatment Facility

    SciTech Connect

    Larson, H L

    2007-09-07

    This document contains Technical Safety Requirements (TSRs) for the Radioactive and Hazardous Waste Management (RHWM) Division's B695 Segment of the Decontamination and Waste Treatment Facility (DWTF) at Lawrence Livermore National Laboratory (LLNL). The TSRs constitute requirements regarding the safe operation of the B695 Segment of the DWTF. The TSRs are derived from the Documented Safety Analysis (DSA) for the B695 Segment of the DWTF (LLNL 2004). The analysis presented there determined that the B695 Segment of the DWTF is a low-chemical hazard, Hazard Category 3, nonreactor nuclear facility. The TSRs consist primarily of inventory limits as well as controls to preserve the underlying assumptions in the hazard analyses. Furthermore, appropriate commitments to safety programs are presented in the administrative controls section of the TSRs. The B695 Segment of the DWTF (B695 and the west portion of B696) is a waste treatment and storage facility located in the northeast quadrant of the LLNL main site. The approximate area and boundary of the B695 Segment of the DWTF are shown in the B695 Segment of the DWTF DSA. Activities typically conducted in the B695 Segment of the DWTF include container storage, lab-packing, repacking, overpacking, bulking, sampling, waste transfer, and waste treatment. B695 is used to store and treat radioactive, mixed, and hazardous waste, and it also contains equipment used in conjunction with waste processing operations to treat various liquid and solid wastes. The portion of the building called Building 696 Solid Waste Processing Area (SWPA), also referred to as B696S in this report, is used primarily to manage solid radioactive waste. Operations specific to the SWPA include sorting and segregating low-level waste (LLW) and transuranic (TRU) waste, lab-packing, sampling, and crushing empty drums that previously contained LLW. A permit modification for B696S was submitted to DTSC in January 2004 to store and treat hazardous and mixed

  4. Treatment and recycling of asbestos-cement containing waste.

    PubMed

    Colangelo, F; Cioffi, R; Lavorgna, M; Verdolotti, L; De Stefano, L

    2011-11-15

    The remediation of industrial buildings covered with asbestos-cement roofs is one of the most important issues in asbestos risk management. The relevant Italian Directives call for the above waste to be treated prior to disposal on landfill. Processes able to eliminate the hazard of these wastes are very attractive because the treated products can be recycled as mineral components in building materials. In this work, asbestos-cement waste is milled by means of a high energy ring mill for up to 4h. The very fine powders obtained at all milling times are characterized to check the mineralogical and morphological transformation of the asbestos phases. Specifically, after 120 min of milling, the disappearance of the chrysotile OH stretching modes at 3690 cm(-1), of the main crystalline chrysotile peaks and of the fibrous phase are detected by means of infrared spectroscopy and X-ray diffraction and scanning electron microscopy analyses, respectively. The hydraulic behavior of the milled powders in presence of lime is also tested at different times. The results of thermal analyses show that the endothermic effects associated to the neo-formed binding phases significantly increase with curing time. Furthermore, the technological efficacy of the recycling process is evaluated by preparing and testing hydraulic lime and milled powder-based mortars. The complete test set gives good results in terms of the hydration kinetics and mechanical properties of the building materials studied. In fact, values of reacted lime around 40% and values of compressive strength in the range of 2.17 and 2.29 MPa, are measured.

  5. Waste disposal and treatment in the food processing industry. (Latest citations from the Biobusiness database). Published Search

    SciTech Connect

    Not Available

    1994-02-01

    The bibliography contains citations concerning waste treatment and disposal in the food processing industry. Methods, equipment, and technology are considered. References discuss waste heat recovery and examine treatment of wastes resulting from meat and seafood processing, dairy and beverage production, and fruit and vegetable processing. The citations explore conversion of the treated waste to fertilizer and for use in animal feeds, combustion for energy production, biogas production, and composting. The recovery and recycling of usable chemicals from the food waste are also covered. Food packaging recycling is considered in a related bibliography. (Contains 250 citations and includes a subject term index and title list.)

  6. Treatment of low level radioactive liquid waste containing appreciable concentration of TBP degraded products.

    PubMed

    Valsala, T P; Sonavane, M S; Kore, S G; Sonar, N L; De, Vaishali; Raghavendra, Y; Chattopadyaya, S; Dani, U; Kulkarni, Y; Changrani, R D

    2011-11-30

    The acidic and alkaline low level radioactive liquid waste (LLW) generated during the concentration of high level radioactive liquid waste (HLW) prior to vitrification and ion exchange treatment of intermediate level radioactive liquid waste (ILW), respectively are decontaminated by chemical co-precipitation before discharge to the environment. LLW stream generated from the ion exchange treatment of ILW contained high concentrations of carbonates, tributyl phosphate (TBP) degraded products and problematic radio nuclides like (106)Ru and (99)Tc. Presence of TBP degraded products was interfering with the co-precipitation process. In view of this a modified chemical treatment scheme was formulated for the treatment of this waste stream. By mixing the acidic LLW and alkaline LLW, the carbonates in the alkaline LLW were destroyed and the TBP degraded products got separated as a layer at the top of the vessel. By making use of the modified co-precipitation process the effluent stream (1-2 μCi/L) became dischargeable to the environment after appropriate dilution. Based on the lab scale studies about 250 m(3) of LLW was treated in the plant. The higher activity of the TBP degraded products separated was due to short lived (90)Y isotope. The cement waste product prepared using the TBP degraded product was having good chemical durability and compressive strength.

  7. Maximizing Production Capacity from an Ultrafiltration Process at the Hanford Department of Waste Treatment Facility

    SciTech Connect

    Foust, Henry C.; Holton, Langdon K.; Demick, Laurence E.

    2005-12-31

    The Department of Energy has contracted Bechtel National, Inc. to design, construct and commission a Waste Treatment and Immobilization Plant (WTP) to treat radioactive slurry currently stored in underground waste storage tanks. A critical element of the waste treatment capacity for the WTP is the proper operation of an ultrafiltration process (UFP). The UFP separates supernate solution from radioactive solids. The solution and solid phases are separately immobilized. An oversight review of the UFP design and operation has identified several methods to improve the capacity of the ultrafiltration process, which will also improve the capacity of the WTP. Areas explored were the basis of design, an analysis of the WTP capacity, process chemistry within the UFP, and UFP process control. This article discusses some of the findings of this oversight review in terms of sodium and solid production, which supports the treatment of low activity waste (LAW) associated with the facility, and solid production, which supports the treatment of high level waste (HLW) associated with the facility.

  8. Assessment of Options for the Treatment of Nitrate Salt Wastes at Los Alamos National Laboratory

    SciTech Connect

    Robinson, Bruce Alan; Funk, David John; Stevens, Patrice Ann

    2016-03-17

    This paper summarizes the methodology used to evaluate options for treatment of the remediated nitrate salt waste containers at Los Alamos National Laboratory. The method selected must enable treatment of the waste drums, which consist of a mixture of complex nitrate salts (oxidizer) improperly mixed with sWheat Scoop®1, an organic kitty litter and absorbent (fuel), in a manner that renders the waste safe, meets the specifications of waste acceptance criteria, and is suitable for transport and final disposal in the Waste Isolation Pilot Plant located in Carlsbad, New Mexico. A Core Remediation Team was responsible for comprehensively reviewing the options, ensuring a robust, defensible treatment recommendation. The evaluation process consisted of two steps. First, a prescreening process was conducted to cull the list on the basis for a decision of feasibility of certain potential options with respect to the criteria. Then, the remaining potential options were evaluated and ranked against each of the criteria in a consistent methodology. Numerical scores were established by consensus of the review team. Finally, recommendations were developed based on current information and understanding of the scientific, technical, and regulatory situation. A discussion of the preferred options and documentation of the process used to reach the recommended treatment options are presented.

  9. Economic analysis of effluent limitation guidelines and standards for the centralized waste treatment industry

    SciTech Connect

    Wheeler, W.

    1998-12-01

    This report estimates the economic and financial effects and the benefits of compliance with the proposed effluent limitations guidelines and standards for the Centralized Waste Treatment (CWT) industry. The Environmental Protection Agency (EPA) has measured these impacts in terms of changes in the profitability of waste treatment operations at CWT facilities, changes in market prices to CWT services, and changes in the quantities of waste management at CWT facilities in six geographic regions. EPA has also examined the impacts on companies owning CWT facilities (including impacts on small entities), on communities in which CWT facilities are located, and on environmental justice. EPA examined the benefits to society of the CWT effluent limitations guidelines and standards by examining cancer and non-cancer health effects of the regulation, recreational benefits, and cost savings to publicly owned treatment works (POTWs) to which indirect-discharging CWT facilities send their wastewater.

  10. Calculation of chemical quantities for the radioactive liquid waste treatment facility

    SciTech Connect

    Del Signore, John C.; McClenahan, Robert L.

    2007-03-01

    The Radioactive Liquid Waste Treatment Facility (RLWTF) receives, stores, and treats both low-level and transuranic radioactive liquid wastes (RLW). Treatment of RLW requires the use of different chemicals. Examples include the use of calcium oxide to precipitate metals and radioactive elements from the radioactive liquid waste, and the use of hydrochloric acid to clean membrane filters that are used in the treatment process. The RL WTF is a Hazard Category 2 nuclear facility, as set forth in the LANL Final Safety Analysis Report of October 1995, and a DOE letter of March 11, 1999. A revised safety basis is being prepared for the RLWTF, and will be submitted to the NNSA in early 2007. This set of calculations establishes maximum chemical quantities that will be used in the 2007 safety basis.

  11. Anaerobic Treatment of Municipal Solid Waste and Sludge for Energy Production and Recycling of Nutrients

    NASA Astrophysics Data System (ADS)

    Leinonen, S.

    This volume contains 18 papers presented at a Nordic workshop dealing with application of anaerobic decomposition processes on various types of organic wastes, held at the Siikasalmi Research and Experimental Station of the University of Joensuu on 1-2 Oct. 1992. Subject coverage of the presentations extends from the biochemical and microbiological principles of organic waste processing to descriptions and practical experiences of various types of treatment plants. The theoretical and experimental papers include studies on anaerobic and thermophilic degradation processes, methanogenesis, effects of hydrogen, treatment of chlorinated and phenolic compounds, and process modeling, while the practical examples range from treatment of various types of municipal, industrial, and mining wastes to agricultural and fish farm effluents. The papers provide technical descriptions of several biogas plants in operation. Geographically, the presentations span the Nordic and Baltic countries.

  12. Constructed wetlands for municipal solid waste landfill leachate treatment. Final report

    SciTech Connect

    Peverly, J.; Sanford, W.E.; Steenhuis, T.S.

    1993-11-01

    In 1989, the US Geological Survey and Cornell University, in cooperation with the New York State Energy Research and Development Authority and the Tompkins County Solid Waste Department, began a three-year study at a municipal solid-waste landfill near Ithaca, New York, to test the effectiveness of leachate treatment with constructed wetlands and to examine the associated treatment processes. Specific objectives of the study were to examine: treatment efficiency as function of substrate composition and grain size, degree of plant growth, and seasonal changes in evapotranspiration rates and microbial activity; effects of leachate and plant growth on the hydraulic characteristics of the substrate; and chemical, biological, and physical processes by which nutrients, metals, and organic compounds are removed from leachate as it flows through the substrate. A parallel study at a municipal solid-waste landfill near Fenton, New York was conducted by researchers at Cornell University, Ithaca College, and Hawk Engineering (Trautmann and others, 1989). Results are described.

  13. The potential role of aerobic biological waste treatment in regenerative life support systems

    NASA Technical Reports Server (NTRS)

    Shuler, M. L.; Nafis, D.; Sze, E.

    1981-01-01

    The purpose of the paper is to make a preliminary assessment of the feasibility of using aerobic biological waste treatment in closed systems. Issues that are addressed in this paper are: (1) how high a degree of material balance is possible, (2) how much might such a system weigh, and (3) how would system closure and weight be affected if animals were included in the system. A computer model has been developed to calculate for different scenarios the compositions and amounts of the streams entering or leaving the waste treatment system and to estimate the launch weight of such a system. A bench scale apparatus has been built to mimic the proposed waste treatment system; the experiments are used to verify model predictions and to improve model parameter estimations.

  14. Potential for polyhydroxyalkanoate production on German or European municipal waste water treatment plants.

    PubMed

    Pittmann, T; Steinmetz, H

    2016-08-01

    Biopolymers, which are made of renewable raw materials and/or biodegradable residual materials present a possible alternative to common plastic. A potential analysis, based on experimental results in laboratory scale and detailed data from German waste water treatment plants, showed that the theoretically possible production of biopolymers in Germany amounts to more than 20% of the 2015 worldwide biopolymer production. In addition a profound estimation regarding all European Union member states showed that theoretically about 115% of the actual worldwide biopolymer production could be produced on European waste water treatment plants. With an upgraded biopolymer production and a theoretically reachable biopolymer proportion of around 60% of the cell dry weight a total of 1,794,656tPHAa or approximately 236% of today's biopolymer production could be produced on waste water treatment plants in the European Union, using primary sludge as raw material only.

  15. Biological treatment of habitation waste streams using full scale MABRs

    NASA Astrophysics Data System (ADS)

    Jackson, William; Barta, Daniel J.; Morse, Audra; Christenson, Dylan; Sevanthi, Ritesh

    Recycling waste water is a critical step to support sustainable long term habitation in space. Water is one of the largest contributors to life support requirements. In closed loop life support systems, membrane aerated biological reactors (MABRs) can reduce the dissolved organic carbon (DOC) and ammonia (NH3) concentration as well as decrease the pH, leading to a more stable solution with less potential to support biological growth or promote carryover of unionized ammonia as well as producing a higher quality brine. Over the last three years we have operated 3 full size MABRs ( 120L) treating a habitation type waste stream composed of urine, hygiene, and laundry water. The reactors varied in the specific surface area (260, 200, and 150 m2/m3) available for biofilm growth and gas transfer. The liquid side system was continually monitored for pH, TDS, and DO, and the influent and effluent monitored daily for DOC, TN, NOx, and NH4. The gas side system was continuously monitored for O2, CO2, and N2O in the effluent gas as well as pressure and flow rates. These systems have all demonstrated greater than 90% DOC reductions and ammonium conversion rates of 50-70% over a range of loading rates with effluent pH from 5-7.5. We have evaluated. In addition, to evaluating the impact of loading rates (10-70 l/d) we have also evaluated the impact of forced hibernation, the use of pure O2 on performance, the impact of pressurize operation to prevent de-gassing of N2 and to promote higher O2 transfer and a discontinuous feeding cycle to allow integration with desalination. Our analysis includes quantification of consumables (power and O2), waste products such as CO2 and N2O as well as solids production. Our results support the use of biological reactors to treat habitation waste streams as an alternative to the use of pretreatment and desalination alone.

  16. Utilization of immobilized urease for waste water treatment

    NASA Technical Reports Server (NTRS)

    Husted, R. R.

    1974-01-01

    The feasibility of using immobilized urease for urea removal from waste water for space system applications is considered, specifically the elimination of the urea toxicity problem in a 30-day Orbiting Frog Otolith (OFO) flight experiment. Because urease catalyzes the hydrolysis of urea to ammonia and carbon dioxide, control of their concentrations within nontoxic limits was also determined. The results of this study led to the use of free urease in lieu of the immobilized urease for controlling urea concentrations. An ion exchange resin was used which reduced the NH3 level by 94% while reducing the sodium ion concentration only 10%.

  17. Ultrafiltration treatment for liquid laundry wastes from nuclear power stations

    SciTech Connect

    Kichik, V.A.; Maslova, M.N.; Svittsov, A.A.; Kuleshov, N.F.

    1988-03-01

    The authors conduct a comprehensive analysis of the waste constituents--radioactive and organic--of the laundry water resulting from the on-site laundering and decontamination of clothing worn in nuclear power plants. The primary isotope contaminants consist of niobium and zirconium 95, manganese 54, cobalt 60, iron 59, and cesium 134 and 137. A variety of filter and adsorbent materials used in an ultrafiltration process are comparatively tested for their effectiveness in removing not only these isotopes but also the organic contaminants in the process of recycling the water. Those materials consist of copper hexacyanoferrate, polyacrylophosphonic acid, and several metal-polymer complexes.

  18. Application of landfill treatment approaches for stabilization of municipal solid waste.

    PubMed

    Bolyard, Stephanie C; Reinhart, Debra R

    2016-09-01

    This research sought to compare the effectiveness of three landfill enhanced treatment approaches aimed at removing releasable carbon and nitrogen after anaerobic landfilling including flushing with clean water (FB 1), leachate recirculation with ex-situ treatment (FB 2), and leachate recirculation with ex-situ treatment and in-situ aeration (FB 3). After extensive treatment of the waste in the FB scenarios, the overall solids and biodegradable fraction were reduced relative to the mature anaerobically treated waste. In terms of the overall degradation, aeration did not provide any advantage over flushing and anaerobic treatment. Flushing was the most effective approach at removing biodegradable components (i.e. cellulose and hemicellulose). Leachate quality improved for all FBs but through different mechanisms. A significant reduction in ammonia-nitrogen occurred in FB 1 and 3 due to flushing and aeration, respectively. The reduction of chemical oxygen demand (COD) in FB 1 was primarily due to flushing. Conversely, the reduction in COD in FBs 2 and 3 was due to oxidation and precipitation during Fenton's Reagent treatment. A mass balance on carbon and nitrogen revealed that a significant fraction still remained in the waste despite the additional treatment provided. Carbon was primarily converted biologically to CH4 and CO2 in the FBs or removed during treatment using Fenton's Reagent. The nitrogen removal occurred through leaching or biological conversion. These results show that under extensive treatment the waste and leachate characteristics did meet published stability values. The minimum stability values achieved were through flushing although FB 2 and 3 were able to improve leachate quality and solid waste characteristics but not to the same extent as FB 1.

  19. Potential of thermal treatment for decontamination of mercury containing wastes from chlor-alkali industry.

    PubMed

    Busto, Y; Cabrera, X; Tack, F M G; Verloo, M G

    2011-02-15

    Old dumps of mercury waste sludges from chlor-alkaline industry are an environmental threat if not properly secured. Thermal retortion can be used to remove mercury from such wastes. This treatment reduces the total mercury content, and also may reduce the leachability of the residual mercury. The effects of treatment temperature and treatment time on both residual mercury levels and mercury leachability according to the US EPA TCLP leaching procedure, were investigated. Treatment for 1h at 800°C allowed to quantitatively remove the mercury. Treatment at 400°C and above allowed to decrease the leachable Hg contents to below the US EPA regulations. The ultimate choice of treatment conditions will depend on requirements of further handling options and cost considerations.

  20. Chemical hazards associated with treatment of waste electrical and electronic equipment

    SciTech Connect

    Tsydenova, Oyuna; Bengtsson, Magnus

    2011-01-15

    This review paper summarizes the existing knowledge on the chemical hazards associated with recycling and other end-of-life treatment options of waste electrical and electronic equipment (e-waste). The hazards arise from the presence of heavy metals (e.g., mercury, cadmium, lead, etc.), flame retardants (e.g., pentabromophenol, polybrominated diphenyl ethers (PBDEs), tetrabromobisphenol-A (TBBPA), etc.) and other potentially harmful substances in e-waste. If improperly managed, the substances may pose significant human and environmental health risks. The review describes the potentially hazardous content of e-waste, examines the existing e-waste management practices and presents scientific data on human exposure to chemicals, workplace and environmental pollution associated with the three major e-waste management options, i.e., recycling, incineration and landfilling. The existing e-waste management practices and associated hazards are reviewed separately for developed and developing countries. Finally, based on this review, the paper identifies gaps in the existing knowledge and makes some recommendations for future research.

  1. Chemical hazards associated with treatment of waste electrical and electronic equipment.

    PubMed

    Tsydenova, Oyuna; Bengtsson, Magnus

    2011-01-01

    This review paper summarizes the existing knowledge on the chemical hazards associated with recycling and other end-of-life treatment options of waste electrical and electronic equipment (e-waste). The hazards arise from the presence of heavy metals (e.g., mercury, cadmium, lead, etc.), flame retardants (e.g., pentabromophenol, polybrominated diphenyl ethers (PBDEs), tetrabromobisphenol-A (TBBPA), etc.) and other potentially harmful substances in e-waste. If improperly managed, the substances may pose significant human and environmental health risks. The review describes the potentially hazardous content of e-waste, examines the existing e-waste management practices and presents scientific data on human exposure to chemicals, workplace and environmental pollution associated with the three major e-waste management options, i.e., recycling, incineration and landfilling. The existing e-waste management practices and associated hazards are reviewed separately for developed and developing countries. Finally, based on this review, the paper identifies gaps in the existing knowledge and makes some recommendations for future research.

  2. Advances in the Glass Formulations for the Hanford Tank Waste Treatment and Immobilization Plant

    SciTech Connect

    Kruger, Albert A.; Vienna, John D.; Kim, Dong Sang

    2015-01-14

    The Department of Energy-Office of River Protection (DOE-ORP) is constructing the Hanford Tank Waste Treatment and Immobilization Plant (WTP) to treat radioactive waste currently stored in underground tanks at the Hanford site in Washington. The WTP that is being designed and constructed by a team led by Bechtel National, Inc. (BNI) will separate the tank waste into High Level Waste (HLW) and Low Activity Waste (LAW) fractions with the majority of the mass (~90%) directed to LAW and most of the activity (>95%) directed to HLW. The pretreatment process, envisioned in the baseline, involves the dissolution of aluminum-bearing solids so as to allow the aluminum salts to be processed through the cesium ion exchange and report to the LAW Facility. There is an oxidative leaching process to affect a similar outcome for chromium-bearing wastes. Both of these unit operations were advanced to accommodate shortcomings in glass formulation for HLW inventories. A by-product of this are a series of technical challenges placed upon materials selected for the processing vessels. The advances in glass formulation play a role in revisiting the flow sheet for the WTP and hence, the unit operations that were being imposed by minimal waste loading requirements set forth in the contract for the design and construction of the plant. Another significant consideration to the most recent revision of the glass models are the impacts on resolution of technical questions associated with current efforts for design completion.

  3. Argonne-West facility requirements for a radioactive waste treatment demonstration

    SciTech Connect

    Dwight, C.C.; Felicione, F.S.; Black, D.B.; Kelso, R.B.; McClellan, G.C.

    1995-03-01

    At Argonne National Laboratory-West (ANL-W), near Idaho Falls, Idaho, facilities that were originally constructed to support the development of liquid-metal reactor technology are being used and/or modified to meet the environmental and waste management research needs of DOE. One example is the use of an Argonne-West facility to conduct a radioactive waste treatment demonstration through a cooperative project with Science Applications International Corporation (SAIC) and Lockheed Idaho Technologies Company. The Plasma Hearth Process (PBP) project will utilize commercially-adapted plasma arc technology to demonstrate treatment of actual mixed waste. The demonstration on radioactive waste will be conducted at Argonne`s Transient Reactor Test Facility (TREAT). Utilization of an existing facility for a new and different application presents a unique set of issues in meeting applicable federal state, and local requirements as well as the additional constraints imposed by DOE Orders and ANL-W site requirements. This paper briefly describes the PHP radioactive demonstrations relevant to the interfaces with the TREAT facility. Safety, environmental design, and operational considerations pertinent to the PHP radioactive demonstration are specifically addressed herein. The personnel equipment, and facility interfaces associated with a radioactive waste treatment demonstration are an important aspect of the demonstration effort. Areas requiring significant effort in preparation for the PBP Project being conducted at the TREAT facility include confinement design, waste handling features, and sampling and analysis considerations. Information about the facility in which a radioactive demonstration will be conducted, specifically Argonne`s TREAT facility in the case of PHP, may be of interest to other organizations involved in developing and demonstrating technologies for mixed waste treatment.

  4. Two Legionnaires' disease cases associated with industrial waste water treatment plants: a case report

    PubMed Central

    2010-01-01

    Background Finnish and Swedish waste water systems used by the forest industry were found to be exceptionally heavily contaminated with legionellae in 2005. Case presentation We report two cases of severe pneumonia in employees working at two separate mills in Finland in 2006. Legionella serological and urinary antigen tests were used to diagnose Legionnaires' disease in the symptomatic employees, who had worked at, or close to, waste water treatment plants. Since the findings indicated a Legionella infection, the waste water and home water systems were studied in more detail. The antibody response and Legionella urinary antigen finding of Case A indicated that the infection had been caused by Legionella pneumophila serogroup 1. Case A had been exposed to legionellae while installing a pump into a post-clarification basin at the waste water treatment plant of mill A. Both the water and sludge in the basin contained high concentrations of Legionella pneumophila serogroup 1, in addition to serogroups 3 and 13. Case B was working 200 meters downwind from a waste water treatment plant, which had an active sludge basin and cooling towers. The antibody response indicated that his disease was due to Legionella pneumophila serogroup 2. The cooling tower was the only site at the waste water treatment plant yielding that serogroup, though water in the active sludge basin yielded abundant growth of Legionella pneumophila serogroup 5 and Legionella rubrilucens. Both workers recovered from the disease. Conclusion These are the first reported cases of Legionnaires' disease in Finland associated with industrial waste water systems. PMID:21126333

  5. Recycling of waste printed circuit boards: a review of current technologies and treatment status in China.

    PubMed

    Huang, Kui; Guo, Jie; Xu, Zhenming

    2009-05-30

    From the use of renewable resources and environmental protection viewpoints, recycling of waste printed circuit boards (PCBs) receives wide concerns as the amounts of scrap PCBs increases dramatically. However, treatment for waste PCBs is a challenge due to the fact that PCBs are diverse and complex in terms of materials and components makeup as well as the original equipment's manufacturing processes. Recycle technology for waste PCBs in China is still immature. Previous studies focused on metals recovery, but resource utilization for nonmetals and further separation of the mixed metals are relatively fewer. Therefore, it is urgent to develop a proper recycle technology for waste PCBs. In this paper, current status of waste PCBs treatment in China was introduced, and several recycle technologies were analyzed. Some advices against the existing problems during recycling process were presented. Based on circular economy concept in China and complete recycling and resource utilization for all materials, a new environmental-friendly integrated recycling process with no pollution and high efficiency for waste PCBs was provided and discussed in detail.

  6. Treatment of oily wastes using high-shear rotary ultrafiltration

    SciTech Connect

    Reed, B.E.; Viadero, R. Jr.; Young, J.; Lin, W.

    1997-12-01

    The high-shear rotary ultrafiltration (UF) system uses membrane rotation to provide the turbulence required to minimize concentration polarization and flux decline. The high-shear UF system was effective in concentrating oily wastes from about 5% to as high as 65%. The decoupling of turbulence promotion from feed pressurization/recirculation by rotating the membrane was the primary reason for the improvement in performance over that observed with conventional UF systems. Transitional and gel layer oil concentrations (20% and 50--59%, respectively) were higher than values reported in the literature. Permeate flux was dependent on the temperature and rotational speed. Flux increased by about 45% when the temperature was increased from 43 to 60 C. A larger decrease in waste viscosity, over that predicted for water alone, and increased oil droplet diffusivity were hypothesized as reasons for the stronger than expected flux-temperature relationship. The flux-rotational speed ({omega}) relationship was described by J = f({omega}){sup 0.90}; however, the gel layer exhibited stability with increasing {omega}. The ceramic membrane was superior to the polymeric membrane in regards to permeate flux and quality as well as cleaning and durability.

  7. Bioreactor landfill technology in municipal solid waste treatment: an overview.

    PubMed

    Kumar, Sunil; Chiemchaisri, Chart; Mudhoo, Ackmez

    2011-03-01

    In recent years, due to an advance in knowledge of landfill behaviour and decomposition processes of municipal solid waste, there has been a strong thrust to upgrade existing landfill technologies for optimizing these degradation processes and thereafter harness a maximum of the useful bioavailable matter in the form of higher landfill gas generation rates. Operating landfills as bioreactors for enhancing the stabilization of wastes is one such technology option that has been recently investigated and has already been in use in many countries. A few full-scale implementations of this novel technology are gaining momentum in landfill research and development activities. The publication of bioreactor landfill research has resulted in a wide pool of knowledge and useful engineering data. This review covers leachate recirculation and stabilization, nitrogen transformation and corresponding extensive laboratory- and pilot-scale research, the bioreactor landfill concept, the benefits to be derived from this bioreactor landfill technology, and the design and operational issues and research trends that form the basis of applied landfill research.

  8. Potable and Waste Water Treatment with Polyelectrolytes Obtained by Radiation Technologies

    NASA Astrophysics Data System (ADS)

    Manaila, Elena N.; Martin, Diana I.; Craciun, Gabriela D.; Ighigeanu, Daniel I.; Matei, Constantin I.; Anton, Anton I.; Vulpasu, Elena D.; Oproiu, Constantin V.; Ighigeanu, Adelina I.

    2007-04-01

    Comparative results obtained for potable and waste water treatment with electrolytes and combined treatment with electrolytes and polyelectrolytes obtained by radiation technologies are presented. These polyelectrolyte mixtures have the capability to provide measurable improvements in potable water quality, especially leading to a considerable decrease of the ``turbidity'' (T < 1 NTU), ``organic matters'' (OM<4 mg KMnO4/l) and ``total organic carbon'' (TOC<4 mg C/l) indicators, as compared with the classical treatments.

  9. Integrated gasification and plasma cleaning for waste treatment: A life cycle perspective.

    PubMed

    Evangelisti, Sara; Tagliaferri, Carla; Clift, Roland; Lettieri, Paola; Taylor, Richard; Chapman, Chris

    2015-09-01

    In the past, almost all residual municipal waste in the UK was landfilled without treatment. Recent European waste management directives have promoted the uptake of more sustainable treatment technologies, especially for biodegradable waste. Local authorities have started considering other options for dealing with residual waste. In this study, a life cycle assessment of a future 20MWe plant using an advanced two-stage gasification and plasma technology is undertaken. This plant can thermally treat waste feedstocks with different composition and heating value to produce electricity, steam and a vitrified product. The objective of the study is to analyse the environmental impacts of the process when fed with seven different feedstocks (including municipal solid waste, solid refuse fuel, reuse-derived fuel, wood biomass and commercial & industrial waste) and identify the process steps which contribute more to the environmental burden. A scenario analysis on key processes, such as oxygen production technology, metal recovery and the appropriate choice for the secondary market aggregate material, is performed. The influence of accounting for the biogenic carbon content in the waste from the calculations of the global warming potential is also shown. Results show that the treatment of the refuse-derived fuel has the lowest impact in terms of both global warming potential and acidification potential because of its high heating value. For all the other impact categories analysed, the two-stage gasification and plasma process shows a negative impact for all the waste streams considered, mainly due to the avoided burdens associated with the production of electricity from the plant. The plasma convertor, key characteristic of the thermal process investigated, although utilising electricity shows a relatively small contribution to the overall environmental impact of the plant. The results do not significantly vary in the scenario analysis. Accounting for biogenic carbon

  10. Simultaneous treatment of graywater and waste gas in a biological trickling filter.

    PubMed

    McLamore, Eric; Sharvelle, Sybil; Huang, Zhen; Banks, Kathy

    2008-11-01

    Biological processors are typically used in liquid- and gas-phase remediation as separately staged systems. This research presents a novel application of a biotrickling filter operated for simultaneous treatment of contaminants present in graywater and waste gas (ammonia and hydrogen sulfide). Liquid- and gas-phase contaminants were monitored via bioreactor influent/effluent samples over the course of a 300-day study. An oxygen-based bioassay was used to determine spatial location of the functional groups involved in the biodegradation of surfactants, dissolved hydrogen sulfide, and ammonium. Results indicated that a biotrickling filter is able to support the wide range of microbial species required to degrade the compounds found in graywater and waste gas, maintaining conversion efficiencies greater than 90% for parent surfactant compounds and waste gas constituents. These results provide evidence of an operational scheme that potentially reduces footprint size and cost of graywater/waste gas biotreatment.

  11. Audit of the radioactive liquid waste treatment facility operations at the Los Alamos National Laboratory

    SciTech Connect

    1997-11-19

    Los Alamos National Laboratory (Los Alamos) generates radioactive and liquid wastes that must be treated before being discharged to the environment. Presently, the liquid wastes are treated in the Radioactive Liquid Waste Treatment Facility (Treatment Facility), which is over 30 years old and in need of repair or replacement. However, there are various ways to satisfy the treatment need. The objective of the audit was to determine whether Los Alamos cost effectively managed its Treatment Facility operations. The audit determined that Los Alamos` treatment costs were significantly higher when compared to similar costs incurred by the private sector. This situation occurred because Los Alamos did not perform a complete analysis of privatization or prepare a {open_quotes}make-or-buy{close_quotes} plan for its treatment operations, although a {open_quotes}make-or-buy{close_quotes} plan requirement was incorporated into the contract in 1996. As a result, Los Alamos may be spending $2.15 million more than necessary each year and could needlessly spend $10.75 million over the next five years to treat its radioactive liquid waste. In addition, Los Alamos has proposed to spend $13 million for a new treatment facility that may not be needed if privatization proves to be a cost effective alternative. We recommended that the Manager, Albuquerque Operations Office (Albuquerque), (1) require Los Alamos to prepare a {open_quotes}make-or-buy{close_quotes} plan for its radioactive liquid waste treatment operations, (2) review the plan for approval, and (3) direct Los Alamos to select the most cost effective method of operations while also considering other factors such as mission support, reliability, and long-term program needs. Albuquerque concurred with the recommendations.

  12. From Centralized Disassembly to Life Cycle Management: Status and Progress of E-waste Treatment System in China

    NASA Astrophysics Data System (ADS)

    Song, Xiaolong; Yang, Jianxin; Lu, Bin; Yang, Dong

    2017-01-01

    China is now facing e-waste problems from both growing domestic generation and illegal imports. Many stakeholders are involved in the e-waste treatment system due to the complexity of e-waste life cycle. Beginning with the state of the e-waste treatment industry in China, this paper summarizes the latest progress in e-waste management from such aspects as the new edition of the China RoHS Directive, new Treatment List, new funding subsidy standard, and eco-design pilots. Thus, a conceptual model for life cycle management of e-waste is generalized. The operating procedure is to first identify the life cycle stages of the e-waste and extract the important life cycle information. Then, life cycle tools can be used to conduct a systematic analysis to help decide how to maximize the benefits from a series of life cycle engineering processes. Meanwhile, life cycle thinking is applied to improve the legislation relating to e-waste so as to continuously improve the sustainability of the e-waste treatment system. By providing an integrative framework, the life cycle management of e-waste should help to realize sustainable management of e-waste in developing countries.

  13. Effect of the presence of the antimicrobial tylosin in swine waste on anaerobic treatment.

    PubMed

    Angenent, Largus T; Mau, Margit; George, Usha; Zahn, James A; Raskin, Lutgarde

    2008-05-01

    An anaerobic sequencing batch reactor (ASBR), seeded with a biomass inoculum that previously had not been exposed to the macrolide antimicrobial tylosin (mixture of Tylosin A, B, C, and D), was operated for 3 months with swine waste without Tylosin A and for 9 months with swine waste containing Tylosin A at an average concentration of 1.6 mg/L. When swine waste with tylosin was fed to the ASBR, methane production and volatile solids removal did not appear to be inhibited and a methane yield of 0.47 L methane per gram volatile solids fed to the ASBR was observed. Throughout the operating period, Tylosin A levels in ASBR biomass and effluent were below the detection limit of 0.01 mg/L. However, during the first 3 months of operation, the levels of macrolide-lincosamide-streptogramin B (MLSB)-resistant bacteria in the ASBR biomass increased substantially as determined by hybridizations with oligonucleotide probes designed to target MLSB-resistant bacteria. Since no Tylosin A was present in the swine waste during the initial 3 months, the presence of MLSB-resistant bacteria in the swine waste was likely the reason for the increase in resistance. Subsequently, the levels of MLSB-resistant bacteria in ASBR biomass stabilized with an average of 44.9% for the 9 months of operation with swine waste containing Tylosin A. The level of MLSB-resistant bacteria in the swine waste fed to the ASBR during this period averaged 18.0%. The results indicate that anaerobic treatment of a waste stream containing tylosin was effective (based on reactor performance) and that the level of resistant bacteria in the ASBR was substantially higher than in the waste stream fed to this system.

  14. The newest achievements of studies on the reutilization, treatment, and disposal technology of hazardous wastes

    SciTech Connect

    Liu Peizhe

    1996-12-31

    From 1991 to 1996, key studies on the reutilization, treatment, and disposal technology of hazardous wastes have been incorporated into the national plan for environmental protection science and technology. At present, the research achievements have been accomplished, have passed national approval, and have been accepted. The author of this paper, as leader of the national group for this research work, expounds the newest achievements of the studies involving four parts: (1) the reutilization technology of electroplating sludge, including the ion-exchange process for recovering the sludge and waste liquor for producing chromium tanning agent and extracting chromium and colloidal protein from tanning waste residue; on the recovery of heavy metals from the electroplating waste liquor with microbic purification; on the demonstration project of producing modified plastics from the sludge and the waste plastics; and on the demonstration of the recovery of heavy metals from waste electroplating sludge by using the ammonia-leaching process; (2) the demonstrative research of reutilization technology of chromium waste residues, including production of self-melting ore and smelting of chromium-containing pig iron, and of pyrolytic detoxification of the residue with cyclone furnace; (3) the incineration technology of hazardous wastes with successful results of the industrial incinerator system for polychlorinated biphenyls; and (4) the safety landfill technology for disposal of hazardous wastes, with a complete set of technology for pretreatment, selection of the site, development of the antipercolating materials, and design and construction of the landfill. Only a part of the achievements is introduced in this paper, most of which has been built and is being operated for demonstration to further spreading application and accumulate experience. 6 refs., 7 figs., 6 tabs.

  15. Separation technologies for the treatment of Idaho National Engineering Laboratory wastes

    SciTech Connect

    Todd, T.A.

    1997-10-01

    Currently about 6.8 million L of acidic, radioactive liquid waste that is not amenable to calcination, and about 3800 m{sup 3} of calcine exist at the ICPP. Legal drivers (court orders) and agreements between the state of Idaho, the U.S. Navy, and DOE exist that obligate INEL to develop, demonstrate, and implement technologies for treatment and interim storage of the radioactive liquid and calcine wastes. Per these agreements, all tank waste must be removed from the underground liquid storage tanks by the year 2012, and high-level radioactive waste must be treated and removed from INEL by 2035. Separation of the radionuclides from the wastes, followed by immobilization of the high-activity and low-activity fractions in glass and grout, respectively, is the approach preferred by INEL. Technologies to remove actinides (U, Np, Pu, and Am), Cs, Sr, and possibly Tc from highly acidic solutions are required to process INEL wastes. Decontamination of the wastes to NRC Class A low-level waste (LLW) is planned. Separation and isolation of Resource Conservation and Recovery Act (RCRA) metals (Hg, Pb, Cd, and Cr) from the highly radioactive waste streams may also be required. Remediation efforts will begin in FY 1997 to remove volatile organic compounds (VOCs) and radionuclides (Cs and Sr) from groundwater located at the Test Area North facility at INEL. A plume of VOCs and radionuclides has spread from the former TSF-05 injection well, and a Comprehensive Environmental Response, Conservation, and Liability Act (CERCLA) remediation action is under way. A Record of Decision was signed in August 1995 that commits INEL to remediate the plume from TSF-05. Removal of Sr and Cs from the groundwater using commercially available ion-exchange resins has been unsuccessful at meeting maximum contaminant levels, which are 119 pCi/L and 8 pCi/L for Cs and Sr, respectively. Cesium and Sr are the major contaminants that must be removed from the groundwater.

  16. Big waste-treatment job for water hyacinths

    SciTech Connect

    Parkinson, G.

    1981-05-04

    Studies indicate that water hyacinths are at least 50% cheaper for the secondary treatment of sewage compared with activated-sludge plants, not taking into account the potential production of methane from the crop. Ultimately it is hoped that hyacinth aquaculture will permit tertiary treatment of sewage for recovery of potable water. Existing and planned water hyacinth treatment processes in the U.S. are reviewed.

  17. Toxicity reduction in the treatment of refinery waste water

    SciTech Connect

    Eckenfelder, W.W. Jr.

    1995-12-31

    Aquatic Toxicity in refinery and petrochemical wastewaters may result from chemicals present in the feedstock, chemicals added or generated in the process, or chemicals generated during the wastewater treatment process, usually referred to as soluble microbial products (SMP). In most cases, the chemicals originally present or generated are biodegradable and can be removed in the biological treatment process. In some cases, a physical-chemical source treatment may be required. SMP generated through the wastewater treatment process are non-biodegradable and are best handled by the application of powdered activated carbon (PAC) integrated into the activated sludge process. This paper describes toxicity reduction in refinery effluents.

  18. An overview of regulatory issues that affect the development of new waste treatment technologies

    SciTech Connect

    Kuusinen, T L; Siegel, M R; Williams, T A; Powell, J A

    1991-07-01

    The development of new and innovative waste treatment technologies can significantly benefit the U.S. Department of Energy's (DOE) environmental restoration and waste management program. New technologies are expected to facilitate faster, better, cheaper, and safer remediation of existing waste problems. To encourage and direct the development of new waste treatment and management technologies, DOE established a research, development, demonstration, testing, and evaluation (RDDT E) program. The RDDT E program is managed by DOE's Office of Technology Development. The development, acceptance, and application of new technologies involves more than simply technical problems. If the best new technologies are to be applied in the fastest and most cost-effective manner possible, DOE must consider regulatory factors early and often in the technology development process. This report presents a number of regulatory issues that are relevant to any program intended to encourage the development of new waste treatment and management technologies. The report was prepared by Pacific Northwest Laboratory. 38 refs., 6 figs., 2 tabs.

  19. Method and apparatus for treatment of oily waste

    SciTech Connect

    Bazell, G. C.

    1985-02-26

    Oily waste is separated by gravity settling into a light oil phase forming an upper layer and a heavy phase forming a lower layer. An overflow stream of oil passes from the upper layer to a raw fuel storage tank while an underflow from the lower layer, after addition of diesel oil, is centrifugally separated into a light component of oil with some water which is returned to the gravity settling, an intermediate component of clarified water which is discharged to a sewer, and a heavy sludge component which is fed to a second centrifuge for separation into substantially dry solids and a mixture of water and residual oil which is returned to the gravity settling.

  20. Fuel cells for power generation and waste treatment

    NASA Astrophysics Data System (ADS)

    Gair, S.; Cruden, A.; McDonald, J.; Hegarty, T.; Chesshire, M.

    It is now becoming increasingly clear that the in situ use of biomass and organic waste streams are likely to provide the key to energy self sustainability for islands and remote communities. Traditionally biofuels have been used in combustion engines for electric power generation, however, when replaced by fuel cells there is the prospect of achieving higher generating efficiencies, coupled with, in some instances, the opportunity to produce biofuel at a cheaper rate than conventional fuels. Additionally, important environmental benefits can be achieved by way of mitigating greenhouse gas emissions, whilst providing a carbon sink. This paper presents the design details of such an installation that will provide a practical solution on an island (and be applicable in other remote and rural areas) where connection to the grid can be expensive, and where biofuels can be produced on site at no significant extra cost.

  1. Pyrolysis process for the treatment of food waste.

    PubMed

    Grycová, Barbora; Koutník, Ivan; Pryszcz, Adrian

    2016-10-01

    Different waste materials were pyrolysed in the laboratory pyrolysis unit to the final temperature of 800°C with a 10min delay at the final temperature. After the pyrolysis process a mass balance of the resulting products, off-line analysis of the pyrolysis gas and evaluation of solid and liquid products were carried out. The gas from the pyrolysis experiments was captured discontinuously into Tedlar gas sampling bags and the selected components were analyzed by gas chromatography (methane, ethene, ethane, propane, propene, hydrogen, carbon monoxide and carbon dioxide). The highest concentration of measured hydrogen (WaCe 61%vol.; WaPC 66%vol.) was analyzed at the temperature from 750 to 800°C. The heating values of the solid and liquid residues indicate the possibility of its further use for energy recovery.

  2. A review of technologies and performances of thermal treatment systems for energy recovery from waste.

    PubMed

    Lombardi, Lidia; Carnevale, Ennio; Corti, Andrea

    2015-03-01

    The aim of this work is to identify the current level of energy recovery through waste thermal treatment. The state of the art in energy recovery from waste was investigated, highlighting the differences for different types of thermal treatment, considering combustion/incineration, gasification and pyrolysis. Also different types of wastes - Municipal Solid Waste (MSW), Refuse Derived Fuel (RDF) or Solid Refuse Fuels (SRF) and some typologies of Industrial Waste (IW) (sludge, plastic scraps, etc.) - were included in the analysis. The investigation was carried out mainly reviewing papers, published in scientific journals and conferences, but also considering technical reports, to gather more information. In particular the goal of this review work was to synthesize studies in order to compare the values of energy conversion efficiencies measured or calculated for different types of thermal processes and different types of waste. It emerged that the dominant type of thermal treatment is incineration associated to energy recovery in a steam cycle. When waste gasification is applied, the produced syngas is generally combusted in a boiler to generate steam for energy recovery in a steam cycle. For both the possibilities--incineration or gasification--co-generation is the mean to improve energy recovery, especially for small scale plants. In the case of only electricity production, the achievable values are strongly dependent on the plant size: for large plant size, where advanced technical solutions can be applied and sustained from an economic point of view, net electric efficiency may reach values up to 30-31%. In small-medium plants, net electric efficiency is constrained by scale effect and remains at values around 20-24%. Other types of technical solutions--gasification with syngas use in internally fired devices, pyrolysis and plasma gasification--are less common or studied at pilot or demonstrative scale and, in any case, offer at present similar or lower levels

  3. Savannah River Site mixed waste Proposed Site Treatment Plan (PSTP). Volumes 1 and 2 and reference document: Revision 2

    SciTech Connect

    Helmich, E.; Noller, D.K.; Wierzbicki, K.S.; Bailey, L.L.

    1995-07-13

    The DOE is required by the Resource Conservation and Recovery Act to prepare site treatment plans describing the development of treatment capacities and technologies for treating mixed waste. This proposed plan contains Savannah River Site`s preferred options and schedules for constructing new facilities, and otherwise obtaining treatment for mixed wastes. The proposed plan consists of 2 volumes. Volume 1, Compliance Plan, identifies the capacity to be developed and the schedules as required. Volume 2, Background, provides a detailed discussion of the preferred options with technical basis, plus a description of the specific waste streams. Chapters are: Introduction; Methodology; Mixed low level waste streams; Mixed transuranic waste; High level waste; Future generation of mixed waste streams; Storage; Process for evaluation of disposal issues in support of the site treatment plans discussions; Treatment facilities and treatment technologies; Offsite waste streams for which SRS treatment is the Preferred Option (Naval reactor wastes); Summary information; and Acronyms and glossary. This revision does not contain the complete revised report, but only those pages that have been revised.

  4. Wastewater treatment with multilayer media of waste and natural indigenous materials.

    PubMed

    Rahman, Mohammad Arifur; Ahsan, Shamim; Kaneco, Satoshi; Katsumata, Hideyuki; Suzuki, Tohru; Ohta, Kiohisa

    2005-01-01

    Wastewater treatment using waste materials (refuse concrete, waste paper and charcoal) and natural indigenous rocks (andesite, limestone, granite and nitrolite) in the form of multilayer media was investigated. The removal of suspended solids (SS), phosphate ion, nitrate ion, ammonium ion, toxic metals and chemical oxygen demand (COD) were evaluated for the multilayer wastewater treatment system. Effective removal of heavy metals such as cadmium, chromium, mercury and lead was demonstrated. SS and phosphate ion were removed with relatively high efficiency and the COD after treatment was lessened using certain combinations of media. The present wastewater treatment system is simple, convenient and low cost. Therefore, this method can be applied in small scale plants for wastewater treatment in local and nonexclusive areas.

  5. Dissolved air flotation primary clarifier improves performance of biological waste treatment at a latex manufacturing facility

    SciTech Connect

    Miller, D.R.; Kerecz, B.J.; Davis, M.N.

    1996-12-31

    Air Products and Chemicals, Inc. operates a chemical manufacturing facility in Piedmont, SC which generates a high strength COD emulsion wastewater from latex manufacturing. The on-site wastewater treatment facility consisted of flow equalization, activated sludge treatment and gravity clarification. The inability of the biological system to assimilate the high strength emulsion wastwater loadings led to incomplete conversion within the activated sludge process and poor settling waste sludge with turbid final effluent high in COD, BOD and TSS. The facility installed a dissolved air flotation (DAF) clarifier to effectively remove greater than 99 percent of the wastewater emulsion solids ahead of the activated sludge system. An organic coagulant is used for emulsion destabilization instead of iron or aluminum metal coagulants, improving DAF clarifier performance and minimizing operational cost and system complexity. An innovative DAF float solids collection and handling system produces disposal solids concentrations of 50 - 60% total solids resulting in further waste disposal cost savings. By removing more than 99 percent of the emulsion solids with the DAF clarifier ahead of the activated sludge process, the waste-water treatment facility now consistently produces a high quality effluent low in COD, BOD, TSS and turbidity. Wastewater treatment performance improved dramatically, as evident by the facility receiving the Western Carolina Regional Sewer Authority`s {open_quotes}Best Pollution Prevention Program{close_quotes} award. In addition, the wastewater treatment facility can now process three times the pre-DAF waste loads.

  6. Proposal of an environmental performance index to assess solid waste treatment technologies.

    PubMed

    Coelho, Hosmanny Mauro Goulart; Lange, Liséte Celina; Coelho, Lineker Max Goulart

    2012-07-01

    Although the concern with sustainable development and environment protection has considerably grown in the last years it is noted that the majority of decision making models and tools are still either excessively tied to economic aspects or geared to the production process. Moreover, existing models focus on the priority steps of solid waste management, beyond waste energy recovery and disposal. So, in order to help the lack of models and tools aiming at the waste treatment and final disposal, a new concept is proposed: the Cleaner Treatment, which is based on the Cleaner Production principles. This paper focuses on the development and validation of the Cleaner Treatment Index (CTI), to assess environmental performance of waste treatment technologies based on the Cleaner Treatment concept. The index is formed by aggregation (summation or product) of several indicators that consists in operational parameters. The weights of the indicator were established by Delphi Method and Brazilian Environmental Laws. In addition, sensitivity analyses were carried out comparing both aggregation methods. Finally, index validation was carried out by applying the CTI to 10 waste-to-energy plants data. From sensitivity analysis and validation results it is possible to infer that summation model is the most suitable aggregation method. For summation method, CTI results were superior to 0.5 (in a scale from 0 to 1) for most facilities evaluated. So, this study demonstrates that CTI is a simple and robust tool to assess and compare the environmental performance of different treatment plants being an excellent quantitative tool to support Cleaner Treatment implementation.

  7. Co-digestion of organic solid waste and sludge from sewage treatment.

    PubMed

    Edelmann, W; Engeli, H; Gradenecker, M

    2000-01-01

    Solid organic wastes were codigested together with sludge of a sewage treatment plant (STP). In the practical part of the study, a plant to pretreat the organic solid wastes provided by local super markets was constructed at the STP of Frutigen, Switzerland. Up to more than 1 cubic metre of wastes was added to the fermenter of the STP every day. Data collected during 14 months of practical works, showed that for raw fruit and vegetable wastes a two step pretreatment is necessary: First the wastes were chopped and afterwards reduced to a size of 1-2 millimetres, in order to get a homogeneous suspension together with the primary sludge. The vegetable wastes showed excellent digestibility: They seemed to accelerate the digestion process as well as to increase the degree of the anaerobic degradation of the sludge. The energy demand for both, pretreatment and digestion, was 85 kWh/ton of fresh wastes. 20% of the energy was used for the hygienization, a step which does not seem to be necessary for this kind of waste in most of the cases, however. After using the gas for energy conversion, a net yield of 65 kWh/ton of electricity and 166 kWh/ton of heat was measured. Treating cooked kitchen wastes, the net energy production will be higher, because in this case a one step pretreatment will be sufficient. The pretreatment and treatment costs for codigestion on STP's were calculated to be in the range of 55 US$/ton treating half a ton per day and 39 US$/ton treating one ton, respectively. A theoretical feasibility study showed that in Switzerland there is a short term potential on STP's for the codigestion of about 120,000 tons of biogenic wastes per year without big investments. Economic studies about codigestion on agricultural biogas plants showed that the codigestion is a must at the current energy prices, which are far too low for agricultural AD without an additional income by treating solid wastes for third parties.

  8. Simultaneous stack-gas scrubbing and waste water treatment

    NASA Technical Reports Server (NTRS)

    Poradek, J. C.; Collins, D. D.

    1980-01-01

    Simultaneous treatment of wastewater and S02-laden stack gas make both treatments more efficient and economical. According to results of preliminary tests, solution generated by stack gas scrubbing cycle reduces bacterial content of wastewater. Both processess benefit by sharing concentrations of iron.

  9. US Department of Energy interim mixed waste inventory report: Waste streams, treatment capacities and technologies: Volume 4, Site specific---Ohio through South Carolina

    SciTech Connect

    Not Available

    1993-04-01

    The Department of Energy (DOE) has prepared this report to provide an inventory of its mixed wastes and treatment capacities and technologies in response to Section 105(a) of the Federal Facility Compliance Act (FFCAct) of 1992 (Pub. L. No. 102-386). As required by the FFCAct-1992, this report provides site-specific information on DOE`s mixed waste streams and a general review of available and planned treatment facilities for mixed wastes at the following five Ohio facilities: Battelle Columbus Laboratories; Fernald Environmental Management Project; Mound Plant; Portsmouth Gaseous Diffusion Plant; and RMI, Titanium Company.

  10. Composting of sugar-cane waste by-products through treatment with microorganisms and subsequent vermicomposting.

    PubMed

    Kumar, Rahul; Verma, Deepshikha; Singh, Bhanu L; Kumar, Umesh; Shweta

    2010-09-01

    The waste by-products of the sugar-cane industry, bagasse (b), pressmud (p) and trash (t) have been subjected to bioinoculation followed by vermicomposting to shorten stabilization time and improve product quality. Press-mud alone and in combination with other by-products of sugar processing industries was pre-decomposed for 30 days by inoculation with combination of Pleurotus sajorcaju, Trichoderma viridae, Aspergillus niger and Pseudomonas striatum. This treatment was followed by vermicomposting for 40 days with the native earthworm, Drawida willsi. The combination of both treatments reduced the overall time required for composting to 20 days and accelerated the degradation process of waste by-products of sugar processing industry, thereby producing a nutrient-enriched compost product useful for sustaining high crop yield, minimizing soil depletion and value added disposal of waste materials.

  11. Saponification pretreatment and solids recirculation as a new anaerobic process for the treatment of slaughterhouse waste.

    PubMed

    Affes, R; Palatsi, J; Flotats, X; Carrère, H; Steyer, J P; Battimelli, A

    2013-03-01

    Different configurations of anaerobic process, adapted to the treatment of solid slaughterhouse fatty waste, were proposed and evaluated in this study. The tested configurations are based on the combination of anaerobic digestion with/without waste saponification pretreatment (70 °C during 60 min) and with/without recirculation of the digestate solid fraction (ratio=20% w/w). After an acclimation period of substrate pulses-feeding cycles, the reactors were operated in a semi-continuous feeding mode, increasing organic loading rates along experimental time. The degradation of the raw substrate was shown to be the bottleneck of the whole process, obtaining the best performance and process yields in the reactor equipped with waste pretreatment and solids recirculation. Saponification promoted the emulsification and bioavailability of solid fatty residues, while recirculation of solids minimized the substrate/biomass wash-out and induced microbial adaptation to the treatment of fatty substrates.

  12. Volatilization of selected organic compounds from a creosote-waste land-treatment facility. Master's thesis

    SciTech Connect

    Scott, E.J.

    1989-01-01

    The purpose of this research was to evaluate the emissions of volatile and semi-volatile compounds which are constituents of a complex creosote waste from laboratory simulations of a land treatment system to assess the potential human exposure to hazardous compounds from this source. In addition, the Thibodeaux-Hwang Air Emission Release Rate (AERR) model was evaluated for its use in predicting emission rates of hazardous constituents of creosote wood preservative waste from land treatment facilities. A group of hazardous volatile and semi-volatile constituents present in the creosote waste was selected for evaluation in this study and included a variety of polynuclear aromatic hydrocarbons (PNA's), phenol, and chlorinated and substituted phenols.

  13. Changes in the ecological properties of organic wastes during their biological treatment.

    PubMed

    Kuryntseva, P; Galitskaya, P; Selivanovskaya, S

    2016-12-01

    Organic wastes, such as the organic fractions of municipal solid waste (OFMSW) or sewage sludge (SS), have become a serious environmental problem in Russia as well as in other countries. The use of these wastes as soil amendments allows their negative impact on the environment to be minimized. However, before these wastes can be used, they need to be treated appropriately in order to decrease their level of hazard. In this study, composting of raw SS, OFMSW, a mixture of these two wastes (OFMSW+SS) at a ratio 1:2 as well as the anaerobically digested variants of these wastes (SSd, OFMSWd and OFMSWd+SSd) mixed with oiled sawdust was performed. Composting was conducted in the containers containing 20kg of the wastes. The results of three elutriate bioassays (with water flea Daphnia magna, infusoria Paramecium caudatum and radish plant, Raphanus sativus) and one contact bioassay (with oat plant Avena sativa) were used to indirectly estimate changes in the hazardous properties of the biological treatments. Besides, Corg, Ntot content and pH were analyzed in the process of composting. Within the study stability tests to determine maturation process completion were not carried out. It was revealed, that in the process of anaerobic pretreatment for 15days, the toxicity increased by a mean of 1.3-, 1.9- and 1.1-fold for OFMSW, SS and OFMSW+SS, respectively. During composting, the toxicity level of these pretreated samples decreased more rapidly as compared with those which were not pretreated. As a result, the toxicity levels of the elutriates from the final composts made of pretreated wastes OFMSW, SS and OFMSW+SS were three-, two- and 17-fold lower for D. magna and 15-, 21- and 12-fold lower for P. caudatum. As follows from phytotoxicity estimations, composts from digested substrates became mature on the 60th day and had a stimulation effect on the plants after the 90th day of incubation. For the composts prepared from raw substrates, a significantly longer period was

  14. State waste discharge permit application for the 200 Area Effluent Treatment Facility and the State-Approved Land Disposal Site

    SciTech Connect

    Not Available

    1993-08-01

    Application is being made for a permit pursuant to Chapter 173--216 of the Washington Administrative Code (WAC), to discharge treated waste water and cooling tower blowdown from the 200 Area Effluent Treatment Facility (ETF) to land at the State-Approved Land Disposal Site (SALDS). The ETF is located in the 200 East Area and the SALDS is located north of the 200 West Area. The ETF is an industrial waste water treatment plant that will initially receive waste water from the following two sources, both located in the 200 Area on the Hanford Site: (1) the Liquid Effluent Retention Facility (LERF) and (2) the 242-A Evaporator. The waste water discharged from these two facilities is process condensate (PC), a by-product of the concentration of waste from DSTs that is performed in the 242-A Evaporator. Because the ETF is designed as a flexible treatment system, other aqueous waste streams generated at the Hanford Site may be considered for treatment at the ETF. The origin of the waste currently contained in the DSTs is explained in Section 2.0. An overview of the concentration of these waste in the 242-A Evaporator is provided in Section 3.0. Section 4.0 describes the LERF, a storage facility for process condensate. Attachment A responds to Section B of the permit application and provides an overview of the processes that generated the wastes, storage of the wastes in double-shell tanks (DST), preliminary treatment in the 242-A Evaporator, and storage at the LERF. Attachment B addresses waste water treatment at the ETF (under construction) and the addition of cooling tower blowdown to the treated waste water prior to disposal at SALDS. Attachment C describes treated waste water disposal at the proposed SALDS.

  15. Conceptual Evaluation for the Installation of Treatment Capability for Mixed Low Level Waste at the Nevada National Security Site

    SciTech Connect

    NSTec Environmental Management

    2010-11-24

    National Security Technologies, LLC, initiated an evaluation of treatment technologies that they would manage and operate as part of the mixed low-level waste (MLLW) disposal facilities at the Nevada National Security Site (NNSS). The NNSS Disposal Facility has been receiving radioactive waste from the U.S. Department of Energy (DOE) complex since the 1960s, and since 2005 the NNSS Disposal Facility has been receiving radioactive and MLLW for disposal only. In accordance with the Resource Conservation and Recovery Act (RCRA), all mixed waste must meet land disposal restrictions (LDRs) prior to disposal. Compliance with LDRs is attained through treatment of the waste to mitigate the characteristics of the listed waste hazard. Presently, most generators utilize commercial capacity for waste treatment prior to shipment to the NNSS Disposal Facility. The objectives of this evaluation are to provide a conceptual study of waste treatment needs (i.e., demand), identify potential waste treatment technologies to meet demand, and analyze implementation considerations for initiating MLLW treatment capacity at the NNSS Disposal Facility. A review of DOE complex waste generation forecast data indicates that current and future Departmental demand for mixed waste treatment capacity will remain steady and strong. Analysis and screening of over 30 treatment technologies narrowed the field of treatment technologies to four: • Macroencapsulation • Stabilization/microencapsulation • Sort and segregation • Bench-scale mercury amalgamation The analysis of treatment technologies also considered existing permits, current the NNSS Disposal Facility infrastructure such as utilities and procedures, and past experiences such as green-light and red-light lessons learned. A schedule duration estimate has been developed for permitting, design, and construction of onsite treatment capability at the NNSS Disposal Facility. Treatment capability can be ready in 20 months.

  16. A review of technologies and performances of thermal treatment systems for energy recovery from waste

    SciTech Connect

    Lombardi, Lidia; Carnevale, Ennio; Corti, Andrea

    2015-03-15

    Highlights: • The topic of energy recovery from waste by thermal treatment is reviewed. • Combustion, gasification and pyrolysis were considered. • Data about energy recovery performances were collected and compared. • Main limitations to high values of energy performances were illustrated. • Diffusion of energy recovery from waste in EU, USA and other countries was discussed. - Abstract: The aim of this work is to identify the current level of energy recovery through waste thermal treatment. The state of the art in energy recovery from waste was investigated, highlighting the differences for different types of thermal treatment, considering combustion/incineration, gasification and pyrolysis. Also different types of wastes – Municipal Solid Waste (MSW), Refuse Derived Fuel (RDF) or Solid Refuse Fuels (SRF) and some typologies of Industrial Waste (IW) (sludge, plastic scraps, etc.) – were included in the analysis. The investigation was carried out mainly reviewing papers, published in scientific journals and conferences, but also considering technical reports, to gather more information. In particular the goal of this review work was to synthesize studies in order to compare the values of energy conversion efficiencies measured or calculated for different types of thermal processes and different types of waste. It emerged that the dominant type of thermal treatment is incineration associated to energy recovery in a steam cycle. When waste gasification is applied, the produced syngas is generally combusted in a boiler to generate steam for energy recovery in a steam cycle. For both the possibilities – incineration or gasification – cogeneration is the mean to improve energy recovery, especially for small scale plants. In the case of only electricity production, the achievable values are strongly dependent on the plant size: for large plant size, where advanced technical solutions can be applied and sustained from an economic point of view, net

  17. Utilization of Waste Materials for the Treatment of Waste Water Contaminated with Sulphamethoxazole.

    PubMed

    Kurup, Lisha

    2014-01-01

    The activities were carried out to develop potential adsorbents from waste material and employ them for the removal of hazardous antibacterial, Sulphamethoxazole from the wastewater by adsorption technique. The selection of this method was done because of its economic viability. The method has the potency of eradicating the perilous chemicals which make their appearance in water and directly or indirectly into the whole biological system, through the ejection of effluents by the industries in flowing water. The adsorption technique was used to impound the precarious antibiotics from wastewater using Deoiled Soya an agricultural waste and Water Hyacinth a prolific colonizer. The adsorption capacity of these adsorbents was further enhanced by treating them with sodium hydroxide solution and it was seen that the adsorption capacity increases by 10% to 25%. Hence a comparative account of the adsorption studies of all the four adsorbents i.e. Deoiled Soya, Alkali treated Deoiled Soya, Water Hyacinth and Alkali treated Water Hyacinth has been discussed in this paper. Different isotherms like Freundlich, Langmuir and Dubinin Radushkevich were also deduced from the adsorption data. Isotherm studies were in turn used in estimating the thermodynamic parameters. Deoiled Soya (DOS) showed sorption capacity of 0.0007 mol g(-1) while Alkali treated Deoiled Soya (ADOS) exhibited 0.0011 mol g(-1) of sorption capacity which reveals that the adsorption is higher in case of alkali treated adsorbent. The mean sorption energy (E) was obtained between 9 to 12 kJ/mol which shows that the reaction proceeds by ion exchange reaction. Various kinetic studies like order of reaction, mass transfer studies, mechanism of diffusion were also performed for the ongoing processes. The mass transfer coefficient obtained for alkali treated moieties was higher than the parent moieties. The breakthrough curves plotted from the column studies show percentage saturation of 90% to 98%. Moreover the

  18. Handling and Treatment of Uranium Contaminated Combustible Radioactive Low Level Waste (LLW)

    SciTech Connect

    Lorenzen, J,; Lindberg, M.; Luvstrand, J.

    2002-02-26

    Studsvik RadWaste in Sweden has many years of experience in handling of low-level radioactive waste, such as burnable waste for incineration and scrap metal for melting. In Erwin, TN, in the USA, Studsvik Inc also operates a THOR (pyrolysis) facility for treatment of various kinds of ion-exchange resins. The advantage of incineration of combustible waste as well as of ion-exchange resins by pyrolysis, is the vast volume reduction which minimizes the cost for final storage and results in an inert end-product which is feasible for safe final disposal. The amount of uranium in the incinerable waste has impact on the quality of the resulting ash. The quality improves with lower U-content. One way of reducing the Ucontent is leaching using a chemical process before and if necessary also after the incineration. Ranstad Mineral AB has been established in the 1960s to support the Swedish national program for uranium mining in southern Sweden. Ranstad Mineral works among others wit h chemical processes to reduce uranium content by leaching. During 1998-2000 about 150 tons/year have been processed. The goal was to reach uranium residues of less than 0.02% for disposal on the municipal waste disposal.

  19. SUMMARY REPORT: SMALL COMMUNITY WATER AND WASTE- WATER TREATMENT

    EPA Science Inventory

    This summary report presents information on the unique needs of small communities facing new water and wastewater treatment requirements. t contains three main sections: technology overviews (each presents a process description, O&M requirements, technology limitations, and finan...

  20. Technology assessment of aquaculture systems for municipal waste water treatment

    SciTech Connect

    Hyde, H.C.; Ross, R.S.; Sturmer, L.

    1984-08-01

    The innovative and alternative technology provisions of the Clean Water Act of 1977 (PL 95-217) provide financial incentives to communities that use wastewater treatment alternatives to reduce costs or energy consumption over conventional systems. Some of these technologies have been only recently developed and are not in widespread use in the United States. This document discusses the applicability and technical and economic feasibility of using aquaculture systems for municipal wastewater treatment facilities.

  1. Terrestrial physical and chemical processes for liquid waste treatment.

    PubMed

    McCarty, P L

    1991-10-01

    Experiences gained from full-scale evaluation of advanced treatment processes used for reclaiming wastewaters should help in the evaluation of potential treatment systems for treatment and reuse of water in space. Water Factory 21 is a 0.66 m3 s-1 (15 million gallons per day) water reclamation plant in California that has been in operation since 1976. The plant receives biologically treated wastewater. Lime treatment is effective for removal of heavy metals. Volatile organic constitutes are efficiently removed by air stripping. Non-volatile organic constituents are removed by activated carbon adsorption and reverse osmosis (RO). RO is a highly effective polishing step, and removes most of the remaining materials including inorganic salts, heavy metals, and organics. RO removed 85% of the total organic carbon, down to about 1 mg l-1, which is lower than in many treated drinking waters. The series of treatment processes used insured virus and pathogen removal, with lime treatment and chlorination together proving highly effective. Sufficient data has been collected to provide statistically reliable confidence limits to be set on the performance of each unit process.

  2. Evaluation of the transport and resuspension of a simulated nuclear waste slurry: Nuclear Waste Treatment Program

    SciTech Connect

    Carleson, T.E.; Drown, D.C.; Hart, R.E.; Peterson, M.E.

    1987-09-01

    The Department of Chemical Engineering at the University of Idaho conducted research on the transport and resuspension of a simulated high-level nuclear waste slurry. In the United States, the reference process for treating both defense and civilian HLLW is vitrification using the liquid-fed ceramic melter process. The non-Newtonian behavior of the slurry complicates the evaluation of the transport and resuspension characteristics of the slurry. The resuspension of a simulated (nonradioactive) melter feed slurry was evaluated using a slurry designated as WV-205. The simulated slurry was developed for the West Valley Demonstration Project and was used during a pilot-scale ceramic melter (PSCM) experiment conducted at PNL in July 1985 (PSCM-21). This study involved determining the transport characteristics of a fully suspended slurry and the resuspension characteristics of settled solids in a pilot-scale pipe loop. The goal was to predict the transport and resuspension of a full-scale system based on rheological data for a specific slurry. The rheological behavior of the slurry was evaluated using a concentric cylinder rotational viscometer, a capillary tube viscometer, and the pilot-scale pipe loop. The results obtained from the three approaches were compared. 40 refs., 74 figs., 15 tabs.

  3. Environmental Assessment Offsite Thermal Treatment of Low-Level Mixed Waste

    SciTech Connect

    N /A

    1999-05-06

    The U.S. Department of Energy (DOE), Richland Operations Office (RL) needs to demonstrate the economics and feasibility of offsite commercial treatment of contact-handled low-level mixed waste (LLMW), containing polychlorinated biphenyls (PCBS) and other organics, to meet existing regulatory standards for eventual disposal.

  4. USEPA'S SITE PROGRAM IMPACT ON THE DEVELOPMENT AND USE OF INNOVATIVE HAZARDOUS WASTE TREATMENT

    EPA Science Inventory

    The USEPA's SITE Program was created to meet the increased demand for innovative technologies for hazardous waste treatment. The primary mission of the SITe Program is to expedite the cleanup of sites on the NPL. The SITE Program has two components: The Demonstration Program and ...

  5. A&M. Liquid waste treatment plant, TAN616. Plan, elevations, sections, and ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    A&M. Liquid waste treatment plant, TAN-616. Plan, elevations, sections, and details. Evaporator pit. Pump room. Room names and numbers. Ralph M. Parsons 902-3-ANP-616-A 297. Date: December 1952. Approved by INEEL Classification Office for public release. INEEL index no. 034-0616-00-693-106889 - Idaho National Engineering Laboratory, Test Area North, Scoville, Butte County, ID

  6. A&M. Hot liquid waste treatment building (TAN616). Camera facing northeast. ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    A&M. Hot liquid waste treatment building (TAN-616). Camera facing northeast. South wall with oblique views of west sides of structure. Photographer: Ron Paarmann. Date: September 22, 1997. INEEL negative no. HD-20-1-2 - Idaho National Engineering Laboratory, Test Area North, Scoville, Butte County, ID

  7. A&M. Hot liquid waste treatment building (TAN616). Camera facing east. ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    A&M. Hot liquid waste treatment building (TAN-616). Camera facing east. Showing west facades of structure. Photographer: Ron Paarmann. Date: September 22, 1997. INEEL negative no. HD-20-1-1 - Idaho National Engineering Laboratory, Test Area North, Scoville, Butte County, ID

  8. A&M. Hot liquid waste treatment building (TAN616). Camera facing north. ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    A&M. Hot liquid waste treatment building (TAN-616). Camera facing north. Detail of personnel entrance door, stoop, and stairway. Photographer: Ron Paarmann. Date: September 22, 1997. INEEL negative no. HD-20-2-1 - Idaho National Engineering Laboratory, Test Area North, Scoville, Butte County, ID

  9. Food processing waste treatment. (Latest citations from the NTIS database). Published Search

    SciTech Connect

    Not Available

    1993-07-01

    The bibliography contains citations concerning methods and equipment used in the treatment of food processing wastes. Specific food industries include meatpacking, fruits and vegetables, seafood, and poultry. Processes and equipment used in the dairy industry are also discussed. (Contains 250 citations and includes a subject term index and title list.)

  10. Food processing waste treatment. (Latest citations from the NTIS bibliographic database). Published Search

    SciTech Connect

    Not Available

    1994-12-01

    The bibliography contains citations concerning methods and equipment used in the treatment of food processing wastes. Specific food industries include meatpacking, fruits and vegetables, seafood, and poultry. Processes and equipment used in the dairy industry are also discussed. (Contains 250 citations and includes a subject term index and title list.)

  11. Borehole Summary Report for Core Hole C4998 – Waste Treatment Plant Seismic Boreholes Project

    SciTech Connect

    Barnett, D. BRENT; Garcia, Benjamin J.

    2006-12-15

    Seismic borehole C4998 was cored through the upper portion of the Columbia River Basalt Group and Ellensburg Formation to provide detailed lithologic information and intact rock samples that represent the geology at the Waste Treatment Plant. This report describes the drilling of borehole C4998 and documents the geologic data collected during the drilling of the cored portion of the borehole.

  12. Method and apparatus for treating gaseous effluents from waste treatment systems

    DOEpatents

    Flannery, Philip A.; Kujawa, Stephan T.

    2000-01-01

    Effluents from a waste treatment operation are incinerated and oxidized by passing the gases through an inductively coupled plasmas arc torch. The effluents are transformed into plasma within the torch. At extremely high plasma temperatures, the effluents quickly oxidize. The process results in high temperature oxidation of the gases without addition of any mass flow for introduction of energy.

  13. Surrogate formulations for thermal treatment of low-level mixed waste. Part 1: Radiological surrogates

    SciTech Connect

    Stockdale, J.A.D.; Bostick, W.D.; Hoffmann, D.P.; Lee, H.T.

    1994-01-01

    The evaluation and comparison of proposed thermal treatment systems for mixed wastes can be expedited by tests in which the radioactive components of the wastes are replaced by surrogate materials chosen to mimic, as far as is possible, the chemical and physical properties of the radioactive materials of concern. In this work, sponsored by the Mixed Waste Integrated Project of the US Department of Energy, the authors have examined reported experience with such surrogates and suggest a simplified standard list of materials for use in tests of thermal treatment systems. The chief radioactive nuclides of concern in the treatment of mixed wastes are {sup 239}Pu, {sup 238}U, {sup 235}U, {sup 137}Cs, {sup 103}Ru, {sup 99}Tc, and {sup 90}Sr. These nuclides are largely by-products of uranium enrichment, reactor fuel reprocessing, and weapons program activities. Cs, Ru, and Sr all have stable isotopes that can be used as perfect surrogates for the radioactive forms. Technetium exists only in radioactive form, as do plutonium and uranium. If one wishes to preclude radioactive contamination of the thermal treatment system under trial burn, surrogate elements must be chosen for these three. For technetium, the authors suggest the use of natural ruthenium, and for both plutonium and uranium, they recommend cerium. The seven radionuclides listed can therefore be simulated by a surrogate package containing stable isotopes of ruthenium, strontium, cesium, and cerium.

  14. CAST STONE TECHNOLOGY FOR THE TREATMENT AND IMMOBILIZATION OF LOW-ACTIVITY WASTE

    SciTech Connect

    MINWALL HJ

    2011-04-08

    Cast stone technology is being evaluated for potential application in the treatment and immobilization of Hanford low-activity waste. The purpose of this document is to provide background information on cast stone technology. The information provided in the report is mainly based on a pre-conceptual design completed in 2003.

  15. A&M. Hot liquid waste treatment building (TAN616), south side. Camera ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    A&M. Hot liquid waste treatment building (TAN-616), south side. Camera facing north. Personnel door at left side of wall. Partial view of outdoor stairway to upper level platform. Note concrete construction. Photographer: Ron Paarmann. Date: September 22, 1997. INEEL negative no. HD-20-1-3 - Idaho National Engineering Laboratory, Test Area North, Scoville, Butte County, ID

  16. Remotely controlled reagent feed system for mixed waste treatment Tank Farm

    SciTech Connect

    Dennison, D.K.; Bowers, J.S.; Reed, R.K.

    1995-02-01

    LLNL has developed and installed a large-scale. remotely controlled, reagent feed system for use at its existing aqueous low-level radioactive and mixed waste treatment facility (Tank Farm). LLNL`s Tank Farm is used to treat aqueous low-level and mixed wastes prior to vacuum filtration and to remove the hazardous and radioactive components before it is discharged to the City of Livermore Water Reclamation Plant (LWRP) via the sanitary sewer in accordance with established limits. This reagent feed system was installed to improve operational safety and process efficiency by eliminating the need for manual handling of various reagents used in the aqueous waste treatment processes. This was done by installing a delivery system that is controlled either remotely or locally via a programmable logic controller (PLC). The system consists of a pumping station, four sets of piping to each of six 6,800-L (1,800-gal) treatment tanks, air-actuated discharge valves at each tank, a pH/temperature probe at each tank, and the PLC-based control and monitoring system. During operation, the reagents are slowly added to the tanks in a preprogrammed and controlled manner while the pH, temperature, and liquid level are continuously monitored by the PLC. This paper presents the purpose of this reagent feed system, provides background related to LLNL`s low-level/mixed waste treatment processes, describes the major system components, outlines system operation, and discusses current status and plans.

  17. Removal of two antibacterial compounds triclocarban and triclosan in a waste water treatment plant

    Technology Transfer Automated Retrieval System (TEKTRAN)

    This study investigates the fate of Triclocarban (TCC) and Triclosan (TCS) in a waste water treatment plant (WWTP). Our goal was to identify the most effective removal step and to determine the amount on the solid phase versus degraded. Our influent contained higher TCS than TCC concentrations (8....

  18. RADIOACTIVE DEMONSTRATIONS OF FLUIDIZED BED STEAM REFORMING WITH ACUTAL HANFORD LOW ACTIVITY WASTES VERIFYING FBSR AS A SUPPLEMENTARY TREATMENT

    SciTech Connect

    Jantzen, C.; Crawford, C.; Burket, P.; Bannochie, C.; Daniel, G.; Nash, C.; Cozzi, A.; Herman, C.

    2012-01-12

    The U.S. Department of Energy's Office of River Protection is responsible for the retrieval, treatment, immobilization, and disposal of Hanford's tank waste. Currently there are approximately 56 million gallons of highly radioactive mixed wastes awaiting treatment. A key aspect of the River Protection Project cleanup mission is to construct and operate the Waste Treatment and Immobilization Plant (WTP). The WTP will separate the tank waste into high-level waste (HLW) and low-activity waste (LAW) fractions, both of which will subsequently be vitrified. The projected throughput capacity of the WTP LAW Vitrification Facility is insufficient to complete the cleanup mission in the time frame required by the Hanford Federal Facility Agreement and Consent Order, also known as the Tri-Party Agreement (TPA). Therefore, Supplemental Treatment is required both to meet the TPA treatment requirements as well as to more cost effectively complete the tank waste treatment mission. Fluidized Bed Steam Reforming (FBSR) is one of the supplementary treatments being considered. FBSR offers a moderate temperature (700-750 C) continuous method by which LAW and other secondary wastes can be processed irrespective of whether they contain organics, nitrates/nitrites, sulfates/sulfides, chlorides, fluorides, and/or radio-nuclides like I-129 and Tc-99. Radioactive testing of Savannah River LAW (Tank 50) shimmed to resemble Hanford LAW and actual Hanford LAW (SX-105 and AN-103) have produced a ceramic (mineral) waste form which is the same as the non-radioactive waste simulants tested at the engineering scale. The radioactive testing demonstrated that the FBSR process can retain the volatile radioactive components that cannot be contained at vitrification temperatures. The radioactive and nonradioactive mineral waste forms that were produced by co-processing waste with kaolin clay in an FBSR process are shown to be as durable as LAW glass.

  19. Independent review of inappropriate identification, storage and treatment methods of polychlorinated biphenyl waste streams

    SciTech Connect

    1997-07-01

    The purpose of the review was to evaluate incidents involving the inappropriate identification, storage, and treatment methods associated with polychlorinated biphenyl (PCB) waste streams originating from the V-tank system at the Test Area North (TAN). The team was instructed to perform a comprehensive review of Lockheed Martin Idaho Technologies Company (LMITCO`s) compliance programs related to these incidents to assess the adequacy and effectiveness of the management program in all respects including: adequacy of the waste management program in meeting all LMITCO requirements and regulations; adequacy of policies, plans, and procedures in addressing and implementing all federal and state requirements and regulations; and compliance status of LMITCO, LMITCO contract team members, and LMITCO contract/team member subcontractor personnel with established PCB management policies, plans, and procedures. The V-Tanks are part of an intermediate waste disposal system and are located at the Technical Support Facility (TSF) at TAN at the Idaho National Engineering and Environmental Laboratory (INEEL). The IRT evaluated how a waste was characterized, managed, and information was documented; however, they did not take control of wastes or ensure followup was performed on all waste streams that may have been generated from the V-Tanks. The team has also subsequently learned that the Environmental Restoration (ER) program is revising the plans for the decontamination and decommissioning of the intermediate waste disposal system based on new information listed and PCB wastes. The team has not reviewed those in-process changes. The source of PCB in the V-Tank is suspected to be a spill of hydraulic fluid in 1968.

  20. Geographic information system-based healthcare waste management planning for treatment site location and optimal transportation routeing.

    PubMed

    Shanmugasundaram, Jothiganesh; Soulalay, Vongdeuane; Chettiyappan, Visvanathan

    2012-06-01

    In Lao People's Democratic Republic (Lao PDR), a growth of healthcare centres, and the environmental hazards and public health risks typically accompanying them, increased the need for healthcare waste (HCW) management planning. An effective planning of an HCW management system including components such as the treatment plant siting and an optimized routeing system for collection and transportation of waste is deemed important. National government offices at developing countries often lack the proper tools and methodologies because of the high costs usually associated with them. However, this study attempts to demonstrate the use of an inexpensive GIS modelling tool for healthcare waste management in the country. Two areas were designed for this study on HCW management, including: (a) locating centralized treatment plants and designing optimum travel routes for waste collection from nearby healthcare facilities; and (b) utilizing existing hospital incinerators and designing optimum routes for collecting waste from nearby healthcare facilities. Spatial analysis paved the way to understand the spatial distribution of healthcare wastes and to identify hotspots of higher waste generating locations. Optimal route models were designed for collecting and transporting HCW to treatment plants, which also highlights constraints in collecting and transporting waste for treatment and disposal. The proposed model can be used as a decision support tool for the efficient management of hospital wastes by government healthcare waste management authorities and hospitals.