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Sample records for 500-terawatt ultraviolet laser

  1. Line Tunable Ultraviolet Laser

    NASA Technical Reports Server (NTRS)

    Walsh, Brian M.; Barnes, Norman P.

    2004-01-01

    An ultraviolet laser is demonstrated using a dual wavelength Nd:YAG oscillator, sum frequency and second harmonic process. Synchronous pulses at 1.052 and 1.319 micrometers are amplified, mixed and subsequently doubled, producing pulses at 0.293 micrometers.

  2. Compact ultraviolet laser

    NASA Astrophysics Data System (ADS)

    Baird, Brian Walter

    1997-09-01

    This dissertation presents theoretical analysis and experimental investigation of a compact ultraviolet laser, comprising an unstable resonator semiconductor (URSL) laser-pumped potassium titanyl phosphate (KTP) periodically segmented waveguide (PSW) laser. A comprehensive survey of existing short wavelength visible and near ultraviolet laser technologies suitable for the development of compact ultraviolet lasers is presented. This survey establishes the suitability of a diode-pumped KTP PSW laser as an attractive approach for developing a compact ultraviolet laser. Requirements for an efficient diode-pumped KTP PSW laser are given, leading to the selection of a frequency-stabilized URSL and hydrothermal KTP PSWs as the component technologies to be developed and integrated. Since the design requirements for the URSL and KTP PSW are critically dependent on a thorough understanding of the spatial mode properties of KTP PSWs, analyses and modeling of the spatial mode properties of these devices is presented using effective index method (EIM) and beam propagation method (BPM) models. In addition, a new expression for the normalized conversion efficiency is presented which explicitly incorporates the dependence of this important parameter on the lateral variation of the refractive index and d coefficient. To assess the theoretical performance of an URSL-pumped KTP PSW, the BPM model was extended to incorporate second harmonic generation. This represents an important contribution to the development of numerical methods for modeling nonlinear waveguides, in general, and provides important information on the cooperative effects of diffraction and spatial mode beating on the SHG output from KTP PSWs. Extensive optical characterization of NUV SHG in hydrothermal KTP PSWs using an argon-ion laser-pumped Ti:Sapphire laser as the infrared laser pump source is presented. Spectral characterization, spatial mode characterization, and the temperature dependence of the QPM

  3. Ultraviolet radiation induced discharge laser

    DOEpatents

    Gilson, Verle A.; Schriever, Richard L.; Shearer, James W.

    1978-01-01

    An ultraviolet radiation source associated with a suitable cathode-anode electrode structure, disposed in a gas-filled cavity of a high pressure pulsed laser, such as a transverse electric atmosphere (TEA) laser, to achieve free electron production in the gas by photoelectric interaction between ultraviolet radiation and the cathode prior to the gas-exciting cathode-to-anode electrical discharge, thereby providing volume ionization of the gas. The ultraviolet radiation is produced by a light source or by a spark discharge.

  4. Vacuum ultraviolet laser

    DOEpatents

    Berkowitz, J.; Ruscic, B.M.; Greene, J.P.

    1984-07-06

    Transitions from the 2p/sup 4/(/sup 1/S/sub 0/)3s /sup 2/S/sub 1/2/ state of atomic fluorine to all allowed loser states produces laser emission at six new wavelengths: 680.7A, 682.6A, 3592.7A, 3574.1A, 6089.2A, and 6046.8A. Coherent radiation at these new wavelengths can be generated in an atomic fluorine laser operated as an amplifier or as an oscillator.

  5. Vacuum ultraviolet laser

    DOEpatents

    Berkowitz, Joseph; Ruscic, Branko M.; Greene, John P.

    1986-01-01

    Transitions from the 2p.sup.4 (.sup.1 S.sub.0)3s .sup.2 S.sub.1/2 state of atomic fluorine to all allowed lower states produces laser emission at six new wavelengths: 680.7 .ANG., 682.6 .ANG., 3592.7 .ANG., 3574.1 .ANG., 6089.2 .ANG., and 6046.8 .ANG.. Coherent radiation at these new wavelengths can be generated in an atomic fluorine laser operated as an amplifier or as an oscillator.

  6. Ultraviolet lasers. Citations from the International Aerospace Abstracts data base

    NASA Technical Reports Server (NTRS)

    Mauk, S. C.

    1980-01-01

    Reports cited from the international literature describe various aspects of ultraviolet lasers including laser output, far ultraviolet radiation, electron pumping, optical pumping, and laser materials. Gas lasers, pulsed lasers, dye lasers, CO2 lasers, xenon fluoride lasers, and transversely excited atmospheric (TEA) lasers are considered. This updated bibliography contains 283 citations, 66 of which are new additions to the previous edition.

  7. Near-ultraviolet laser diodes for brilliant ultraviolet fluorophore excitation.

    PubMed

    Telford, William G

    2015-12-01

    Although multiple lasers are now standard equipment on most modern flow cytometers, ultraviolet (UV) lasers (325-365 nm) remain an uncommon excitation source for cytometry. Nd:YVO4 frequency-tripled diode pumped solid-state lasers emitting at 355 nm are now the primary means of providing UV excitation on multilaser flow cytometers. Although a number of UV excited fluorochromes are available for flow cytometry, the cost of solid-state UV lasers remains prohibitively high, limiting their use to all but the most sophisticated multilaser instruments. The recent introduction of the brilliant ultraviolet (BUV) series of fluorochromes for cell surface marker detection and their importance in increasing the number of simultaneous parameters for high-dimensional analysis has increased the urgency of including UV sources in cytometer designs; however, these lasers remain expensive. Near-UV laser diodes (NUVLDs), a direct diode laser source emitting in the 370-380 nm range, have been previously validated for flow cytometric analysis of most UV-excited probes, including quantum nanocrystals, the Hoechst dyes, and 4',6-diamidino-2-phenylindole. However, they remain a little-used laser source for cytometry, despite their significantly lower cost. In this study, the ability of NUVLDs to excite the BUV dyes was assessed, along with their compatibility with simultaneous brilliant violet (BV) labeling. A NUVLD emitting at 375 nm was found to excite most of the available BUV dyes at least as well as a UV 355 nm source. This slightly longer wavelength did produce some unwanted excitation of BV dyes, but at sufficiently low levels to require minimal additional compensation. NUVLDs are compact, relatively inexpensive lasers that have higher power levels than the newest generation of small 355 nm lasers. They can, therefore, make a useful, cost-effective substitute for traditional UV lasers in multicolor analysis involving the BUV and BV dyes. PMID:25930008

  8. Ultraviolet laser treatment of titanium surface

    NASA Astrophysics Data System (ADS)

    Balchev, Ivaylo; Minkovski, Nikolai; Dimitrov, Krasimir; Shipochka, Maria; Barbucha, Robert

    2016-02-01

    Interaction of a third harmonic of DPSS laser, wavelength 355 nm and pulse duration of 30 ns with titanium wafers was studied. It was investigated the structure of laser ablated titanium surface, depending on the laser beam scanning speed, and laser pulse frequency. The titanium surface modification was studied by scanning electron microscopy (SEM) and XPS (X- ray Photoelectron Spectroscopy). Nanosecond irradiation with ultraviolet light of Ti plate led to the formation of high porous granular structures consisting of agglomerated micro- and submicro- particles.

  9. Ultraviolet femtosecond laser ionization mass spectrometry.

    PubMed

    Imasaka, Totaro

    2008-01-01

    For this study, multiphoton ionization/mass spectrometry using an ultraviolet (UV) femtosecond laser was employed for the trace analysis of organic compounds. Some of the molecules, such as dioxins, contain several chlorine atoms and have short excited-state lifetimes due to a "heavy atom" effect. A UV femtosecond laser is, then, useful for efficient resonance excitation and subsequent ionization. A technique of multiphoton ionization using an extremely short laser pulse (e.g., <10 fs), referred to as "impulsive ionization," may have a potential for use in fragmentation-free ionization, thus providing information on molecular weight in mass spectrometry. PMID:18302290

  10. Deep ultraviolet diamond Raman laser.

    PubMed

    Granados, Eduardo; Spence, David J; Mildren, Richard P

    2011-05-23

    We present a synchronously pumped diamond Raman laser operating at 275.7 nm pumped by the 4th harmonic of a mode locked Nd:YVO4 laser. The laser had a threshold pump pulse energy of 5.8 nJ and generated up to 0.96 nJ pulses at 10.3% conversion efficiency. The results agree well with a numerical model that includes two-photon absorption of the pump and Stokes beams and uses a Raman gain coefficient of diamond of 100 cm/GW. We also report on the observation of nanometer scale two-photon assisted etching of the diamond crystal surfaces. PMID:21643343

  11. Vacuum-ultraviolet laser uses superfluid helium

    NASA Technical Reports Server (NTRS)

    Zmuidzinas, J. S.

    1979-01-01

    Vacuum ultra violet laser in wavelength around 0.800 microns is produced by using optical pumping to increase lifetimes of excited metastable molecules in super fluid helium. In method, super fluid helium is pumped electronically to produce excited HE2, and then pumped by circularly polarized 0.9096 - micron radiation to aline excited HE2 molecular spins. High power ultraviolet radiation has potential applications in molecular reaction studies, power transmission in space, and biomedical research.

  12. Ultraviolet laser beam monitor using radiation responsive crystals

    DOEpatents

    McCann, Michael P.; Chen, Chung H.

    1988-01-01

    An apparatus and method for monitoring an ultraviolet laser beam includes disposing in the path of an ultraviolet laser beam a substantially transparent crystal that will produce a color pattern in response to ultraviolet radiation. The crystal is exposed to the ultraviolet laser beam and a color pattern is produced within the crystal corresponding to the laser beam intensity distribution therein. The crystal is then exposed to visible light, and the color pattern is observed by means of the visible light to determine the characteristics of the laser beam that passed through crystal. In this manner, a perpendicular cross sectional intensity profile and a longitudinal intensity profile of the ultraviolet laser beam may be determined. The observation of the color pattern may be made with forward or back scattered light and may be made with the naked eye or with optical systems such as microscopes and television cameras.

  13. Laser zona dissection using short-pulse ultraviolet lasers

    NASA Astrophysics Data System (ADS)

    Neev, Joseph; Tadir, Yona; Ho, Peter D.; Whalen, William E.; Asch, Richardo H.; Ord, Teri; Berns, Michael W.

    1992-06-01

    The interaction of pulsed ultraviolet radiation with the zona pellucida of human oocytes which had failed to fertilize in standard IVF cycles, was investigated. Two lasers were studied: a 100 ps pulsed Nd:YAG with a nonlinear crystal emitting light at 266 nm, and a 15 ns XeCl excimer laser with 308 nm radiation. Incisions in the zona were made by aiming the beam tangentially to the oocyte. The results indicate superior, high precision performance by the excimer laser creating trenches as narrow as 1 micrometers and as shallow as 1 micrometers . The incision size was found to be sensitive to the laser's energy and to the position of the microscope's objective focal plane, but relatively insensitive to the laser pulse repetition rate. Once the minimum spot size was defined by the system parameters, the laser beam was used to curve out any desired zona shape. This laser microsurgery technique as applied to partial zone dissection or zona drilling could prove very useful as a high-precision, non-contact method for treatments of low fertilization rate and for enhancing embryo implantation rates in patients undergoing IVF treatments.

  14. Biological applications of ultraviolet free-electron lasers

    SciTech Connect

    Sutherland, J.C.

    1997-10-01

    This review examines the possibilities for biological research using the three ultraviolet free-electron lasers that are nearing operational status in the US. The projected operating characteristics of major interest in biological research of the free-electron lasers at Brookhaven National Laboratory, the Thomas Jefferson National Accelerator Facility, and Duke University are presented. Experimental applications in the areas of far- and vacuum ultraviolet photophysics and photochemistry, structural biology, environmental photobiology, and medical research are discussed and the prospects for advances in these areas, based upon the characteristics of the new ultraviolet free-electron lasers, are evaluated.

  15. Vacuum ultraviolet laser induced fluorescence on a Si atomic beam

    NASA Technical Reports Server (NTRS)

    O'Brian, T. R.; Lawler, J. E.

    1991-01-01

    A broadly applicable vacuum ultraviolet experiment is described for measuring radiative lifetimes of neutral and singly-ionized atoms in a beam environment to 5-percent accuracy using laser induced fluorescence. First results for neutral Si are reported.

  16. Tunable ultraviolet laser source from a frequency doubled Alexandrite laser

    NASA Astrophysics Data System (ADS)

    Liu, Shuhang; Liu, Jingjiao; Wang, Lijun

    2007-11-01

    A tunable ultraviolet laser source in the spectrum range of 0.36-0.388 μm was obtained as second harmonics from a frequency doubled Alexandrite laser whose output covers the wave range over 0.72-0.78 μm. A LBO crystal was used as frequency doubling crystal. The phase mateching angle in the wide spectrum range of the crystal was calculated, and the crystal was cut in the way that the normal incidence at the center wavelength of the fundamental wave at the crystal. The output spectrum line was measured and the highest second harmonics conversion efficiency reached 1.2% from long pulse fundamental wave at the center wavelength.

  17. Ultraviolet laser effects on the cornea

    NASA Astrophysics Data System (ADS)

    Zuclich, Joseph A.

    1990-07-01

    Ultraviolet radiation in the ambient environment or from artificial sources may pose both acute and chronic hazards to the skin and the ocular tissues. In general terrestrial conditions have evolved such that there are only narrow safety margins between ambient UV levels and exposure levels harmful to the human. Obvious examples of acute consequences ofUV overexposure are sunburn and snowblindness as well as analogous conditions induced by artificial sources such as the welder''s arc mercury vapor lamps and UV-emitting lasers. Further chronic UV exposure is strongly implicated as a causative agent in certain types of cataract and skin cancer. This presentation will summarize a number of specific cases where UV radiation affected the primate cornea. Data presented will include the action spectra for far- and near-UV induced ocular damage the pulsewidth and total energy dependencies of ocular thresholds studies of cumulative effects of repeated UV exposures and quantitative determinations of tissue repair or recovery rates. Depending on the exposure parameters utilized photochemical thermal or photoablative damage mechanisms may prevail. 1.

  18. High intensity vacuum ultraviolet and extreme ultraviolet production by noncollinear mixing in laser vaporized media

    NASA Astrophysics Data System (ADS)

    Todt, Michael A.; Albert, Daniel R.; Davis, H. Floyd

    2016-06-01

    A method is described for generating intense pulsed vacuum ultraviolet (VUV) and extreme ultraviolet (XUV) laser radiation by resonance enhanced four-wave mixing of commercial pulsed nanosecond lasers in laser vaporized mercury under windowless conditions. By employing noncollinear mixing of the input beams, the need of dispersive elements such as gratings for separating the VUV/XUV from the residual UV and visible beams is eliminated. A number of schemes are described, facilitating access to the 9.9-14.6 eV range. A simple and convenient scheme for generating wavelengths of 125 nm, 112 nm, and 104 nm (10 eV, 11 eV, and 12 eV) using two dye lasers without the need for dye changes is described.

  19. A compact efficient deep ultraviolet laser at 266 nm

    NASA Astrophysics Data System (ADS)

    Zhai, S. Y.; Wang, X. L.; Wei, Y.; Chen, W. D.; Zhuang, F. J.; Xu, S.; Li, B. X.; Fu, J. J.; Chen, Z. Q.; Wang, H. W.; Huang, C. H.; Zhang, G.

    2013-04-01

    We present a highly efficient and cost-effective watt-level deep-ultraviolet laser operating at 266 nm. Type-I phase-matching LBO crystals and type-I phase-matching BBO crystals were used for frequency doubling and fourth-harmonic generation, respectively. The highest 1.82 W average power of the 266 nm laser was obtained from nonlinear frequency conversion at a repetition rate of 30 kHz and a pump power of 18.8 W. The conversion efficiency from the diode to the deep-ultraviolet laser scales up to 10.7%. This is, to our knowledge, the highest efficiency ever reported generated from a laser diode single-end-pumped acousto-optic Q-switched system.

  20. Ultraviolet laser deposition of graphene thin films without catalytic layers

    NASA Astrophysics Data System (ADS)

    Sarath Kumar, S. R.; Alshareef, H. N.

    2013-01-01

    In this letter, the formation of nanostructured graphene by ultraviolet laser ablation of a highly ordered pyrolytic graphite target under optimized conditions is demonstrated, without a catalytic layer, and a model for the growth process is proposed. Previously, graphene film deposition by low-energy laser (2.3 eV) was explained by photo-thermal models, which implied that graphene films cannot be deposited by laser energies higher than the C-C bond energy in highly ordered pyrolytic graphite (3.7 eV). Here, we show that nanostructured graphene films can in fact be deposited using ultraviolet laser (5 eV) directly over different substrates, without a catalytic layer. The formation of graphene is explained by bond-breaking assisted by photoelectronic excitation leading to formation of carbon clusters at the target and annealing out of defects at the substrate.

  1. Chemical-ionization visible and ultraviolet gas lasers: A concept

    NASA Technical Reports Server (NTRS)

    Laudenslager, J. B.

    1975-01-01

    Charge-transfer reactions or Penning ionization reactions are used to produce population inversions between electronic states of molecular ions which should result in stimulated emission in ultraviolet and visible regions. Such lasers could be used in study of short-lived reaction intermediates, crystal structure and scattering, and photolysis.

  2. Classifying the Basic Parameters of Ultraviolet Copper Bromide Laser

    NASA Astrophysics Data System (ADS)

    Gocheva-Ilieva, S. G.; Iliev, I. P.; Temelkov, K. A.; Vuchkov, N. K.; Sabotinov, N. V.

    2009-10-01

    The performance of deep ultraviolet copper bromide lasers is of great importance because of their applications in medicine, microbiology, high-precision processing of new materials, high-resolution laser lithography in microelectronics, high-density optical recording of information, laser-induced fluorescence in plasma and wide-gap semiconductors and more. In this paper we present a statistical study on the classification of 12 basic lasing parameters, by using different agglomerative methods of cluster analysis. The results are based on a big amount of experimental data for UV Cu+ Ne-CuBr laser with wavelengths 248.6 nm, 252.9 nm, 260.0 nm and 270.3 nm, obtained in Georgi Nadjakov Institute of Solid State Physics, Bulgarian Academy of Sciences. The relevant influence of parameters on laser generation is also evaluated. The results are applicable in computer modeling and planning the experiments and further laser development with improved output characteristics.

  3. Ultraviolet Lasers Realized via Electrostatic Doping Method

    PubMed Central

    Liu, X. Y.; Shan, C. X.; Zhu, H.; Li, B. H.; Jiang, M. M.; Yu, S. F.; Shen, D. Z.

    2015-01-01

    P-type doping of wide-bandgap semiconductors has long been a challenging issue for the relatively large activation energy and strong compensation of acceptor states in these materials, which hinders their applications in ultraviolet (UV) optoelectronic devices drastically. Here we show that by employing electrostatic doping method, hole-dominant region can be formed in wide bandgap semiconductors, and UV lasing has been achieved through the external injection of electrons into the hole-dominant region, confirming the applicability of the p-type wide bandgap semiconductors realized via the electrostatic doping method in optoelectronic devices. PMID:26324054

  4. Picosecond pumping of extreme-ultraviolet lasers using preformed laser plasmas

    NASA Astrophysics Data System (ADS)

    Yamakoshi, H.; Herman, P. R.; Le Flohic, M. P.; Xiao, B.; Zhao, L.; Kulcsar, G.; Budnik, F. W.; Marjoribanks, R. S.

    1996-02-01

    Weak laser prepulses were used for the first time with picosecond-duration laser light to enhance laser-target absorption for efficient excitation of extreme-ultraviolet lasers. A traveling-wave excitation geometry and a self-healing mercury-wetted target were used with 300-ps prepulses to pump the photoionization Xe III laser at 109-nm wavelength. Fully saturated laser gain was demonstrated for both 32-ps and 1.4-ps small-signal gain coefficients exceeded 2 cm -1 for on-target laser fluences of only 4 J / cm2.

  5. Ultraviolet laser patterning of porous silicon

    SciTech Connect

    Vega, Fidel; Peláez, Ramón J.; Kuhn, Timo; Afonso, Carmen N.; Recio-Sánchez, Gonzalo; Martín-Palma, Raúl J.

    2014-05-14

    This work reports on the fabrication of 1D fringed patterns on nanostructured porous silicon (nanoPS) layers (563, 372, and 290 nm thick). The patterns are fabricated by phase-mask laser interference using single pulses of an UV excimer laser (193 nm, 20 ns pulse duration). The method is a single-step and flexible approach to produce a large variety of patterns formed by alternate regions of almost untransformed nanoPS and regions where its surface has melted and transformed into Si nanoparticles (NPs). The role of laser fluence (5–80 mJ cm{sup −2}), and pattern period (6.3–16 μm) on pattern features and surface structuring are discussed. The results show that the diameter of Si NPs increases with fluence up to a saturation value of 75 nm for a fluence ≈40 mJ cm{sup −2}. In addition, the percentage of transformed to non-transformed region normalized to the pattern period follows similar fluence dependence regardless the period and thus becomes an excellent control parameter. This dependence is fitted within a thermal model that allows for predicting the in-depth profile of the pattern. The model assumes that transformation occurs whenever the laser-induced temperature increase reaches the melting temperature of nanoPS that has been found to be 0.7 of that of crystalline silicon for a porosity of around 79%. The role of thermal gradients across the pattern is discussed in the light of the experimental results and the calculated temperature profiles, and shows that the contribution of lateral thermal flow to melting is not significant for pattern periods ≥6.3 μm.

  6. Pulsed-ultraviolet laser Raman diagnostics of plasma processing discharges

    SciTech Connect

    Hargis P.J. Jr.; Greenberg, K.E.

    1988-11-07

    Spontaneous Raman spectroscopy with pulsed-ultraviolet laser excitation of the Stokes vibrational Raman lines was used to measure the percent dissociation of nitrogen and sulfur hexafluoride in low-pressure radio refrequency discharges of the type used for processing semiconductor materials. Measurements of the percent dissociation of sulfur hexafluoride, at pressures between 200 and 600 mTorr, show a strong pressure dependence which is consistent with recombination playing an important role in sulfur hexafluoride discharge kinetics.

  7. Ne-like ion lasers in the extreme ultraviolet region

    SciTech Connect

    Li, Y.; Pretzler, G.; Fill, E.E.

    1995-11-01

    We report strong {ital J}=0--1, 3{ital p}-3{ital s} lasing in Ne-like scandium, calcium, potassium, and chlorine at wavelengths ranging from 35.3 nm in scandium to 52.9 nm in chlorine. The experiments were carried out with the ASTERIX IV iodine laser using a 15% prepulse 5.2 ns before the main pulse. These results extend the range of laser plasma x-ray lasers into the extreme ultraviolet region. Gain lengths between 7 and 11 were measured for the different lines. The 38.3-nm laser in calcium lased at an intensity as low as 5{times}10{sup 12} W/cm{sup {minus}2}.

  8. Ultraviolet Laser-induced ignition of RDX single crystal

    NASA Astrophysics Data System (ADS)

    Yan, Zhonghua; Zhang, Chuanchao; Liu, Wei; Li, Jinshan; Huang, Ming; Wang, Xuming; Zhou, Guorui; Tan, Bisheng; Yang, Zongwei; Li, Zhijie; Li, Li; Yan, Hongwei; Yuan, Xiaodong; Zu, Xiaotao

    2016-02-01

    The RDX single crystals are ignited by ultraviolet laser (355 nm, 6.4 ns) pulses. The laser-induced damage morphology consisted of two distinct regions: a core region of layered fracture and a peripheral region of stripped material surrounding the core. As laser fluence increases, the area of the whole crack region increases all the way, while both the area and depth of the core region increase firstly, and then stay stable over the laser fluence of 12 J/cm2. The experimental details indicate the dynamics during laser ignition process. Plasma fireball of high temperature and pressure occurs firstly, followed by the micro-explosions on the (210) surface, and finally shock waves propagate through the materials to further strip materials outside and yield in-depth cracks in larger surrounding region. The plasma fireball evolves from isotropic to anisotropic under higher laser fluence resulting in the damage expansion only in lateral direction while maintaining the fixed depth. The primary insights into the interaction dynamics between laser and energetic materials can help developing the superior laser ignition technique.

  9. Ultraviolet Laser-induced ignition of RDX single crystal.

    PubMed

    Yan, Zhonghua; Zhang, Chuanchao; Liu, Wei; Li, Jinshan; Huang, Ming; Wang, Xuming; Zhou, Guorui; Tan, Bisheng; Yang, Zongwei; Li, Zhijie; Li, Li; Yan, Hongwei; Yuan, Xiaodong; Zu, Xiaotao

    2016-01-01

    The RDX single crystals are ignited by ultraviolet laser (355 nm, 6.4 ns) pulses. The laser-induced damage morphology consisted of two distinct regions: a core region of layered fracture and a peripheral region of stripped material surrounding the core. As laser fluence increases, the area of the whole crack region increases all the way, while both the area and depth of the core region increase firstly, and then stay stable over the laser fluence of 12 J/cm(2). The experimental details indicate the dynamics during laser ignition process. Plasma fireball of high temperature and pressure occurs firstly, followed by the micro-explosions on the (210) surface, and finally shock waves propagate through the materials to further strip materials outside and yield in-depth cracks in larger surrounding region. The plasma fireball evolves from isotropic to anisotropic under higher laser fluence resulting in the damage expansion only in lateral direction while maintaining the fixed depth. The primary insights into the interaction dynamics between laser and energetic materials can help developing the superior laser ignition technique. PMID:26847854

  10. Ultraviolet Laser-induced ignition of RDX single crystal

    PubMed Central

    Yan, Zhonghua; Zhang, Chuanchao; Liu, Wei; Li, Jinshan; Huang, Ming; Wang, Xuming; Zhou, Guorui; Tan, Bisheng; Yang, Zongwei; Li, Zhijie; Li, Li; Yan, Hongwei; Yuan, Xiaodong; Zu, Xiaotao

    2016-01-01

    The RDX single crystals are ignited by ultraviolet laser (355 nm, 6.4 ns) pulses. The laser-induced damage morphology consisted of two distinct regions: a core region of layered fracture and a peripheral region of stripped material surrounding the core. As laser fluence increases, the area of the whole crack region increases all the way, while both the area and depth of the core region increase firstly, and then stay stable over the laser fluence of 12 J/cm2. The experimental details indicate the dynamics during laser ignition process. Plasma fireball of high temperature and pressure occurs firstly, followed by the micro-explosions on the (210) surface, and finally shock waves propagate through the materials to further strip materials outside and yield in-depth cracks in larger surrounding region. The plasma fireball evolves from isotropic to anisotropic under higher laser fluence resulting in the damage expansion only in lateral direction while maintaining the fixed depth. The primary insights into the interaction dynamics between laser and energetic materials can help developing the superior laser ignition technique. PMID:26847854

  11. Palomar Ultraviolet Laser for the Study of Exoplanets

    NASA Astrophysics Data System (ADS)

    Baranec, C.; Dekany, R.; van Dam, M.; Burruss, R.

    2013-09-01

    PULSE is a new concept to augment the currently operating 5.1-m Hale PALM-3000 exoplanet adaptive optics system with an ultraviolet Rayleigh laser and associated wavefront sensor. By using an ultraviolet laser to measure the high spatial and temporal order turbulence near the telescope aperture, where it dominates, one can extend the faintness limit of natural guide stars needed by PALM-3000. Initial simulations indicate that very-high infrared contrast ratios and good visible-light adaptive optics performance will be achieved by such an upgraded system on stars as faint as mV = 16-17 using an optimized low-order NGS sensor. This will enable direct imaging searches for, and subsequent characterization of, companions around cool, low-mass stars for the first time, as well as routine visible-light imaging twice as sharp as HST for fainter targets. PULSE will reuse the laser and wavefront sensor technology developed for the automated Robo-AO laser system currently operating at the Palomar 60-inch telescope, as well as take advantage of pending optimization of low-order NGS wavefront sensing and planned new interfaces to the PALM-3000 real-time reconstruction computer. A copy of the Robo-AO laser will be installed in the prime focus cage of the 5.1-m, and a new ultraviolet high-order wavefront sensor, fed by an ultraviolet dichroic, will be installed in the space above the PALM-3000 optical bench near the calibration sources. The laser measurements will drive the 3,388 active element high-order deformable mirror in open-loop, while an adaptive optics sharpened faint natural source will be measured by the current PALM-3000 wavefront sensor in its lowest spatial sampling mode, with commands sent in closed-loop to the 241 active element low-order deformable mirror. The natural guide star loop corrects for both the relatively weak low-order high-altitude turbulence as well as functioning as both the tip-tilt and low-bandwidth `truth' sensor loops in a traditional laser

  12. Ultraviolet photoionization in CO2 TEA lasers

    NASA Astrophysics Data System (ADS)

    Scott, S. J.; Smith, A. L. S.

    1988-07-01

    The effects of gas composition and spark parameters on the UV emission in CO2 TEA laser gas mixtures were investigated together with the nature of photoionization process and the photoelectron-loss mechanism. A linear relationship was found between N2 concentration and photoionization (with no such dependence on C concentration, from CO and CO2), but the increases in photoionization that could be effected by optimizing the spark discharge circuit parameters were much higher than those produced by changes in gas composition. UV emission was directly proportional to the amount of stored electrical energy in the spark-discharge circuit and to the cube of the peak current produced in the spark by the discharge of this energy. Photoionization was also found to be proportional to the spark electrode gap. It was found that free-space sparks gave a considerably broader emission pattern than a surface-guided notched spark.

  13. Multifunctional optical correlator for picosecond ultraviolet laser pulse measurement

    DOE PAGESBeta

    Rakhman, Abdurahim; Wang, Yang; Garcia, Frances; Long, Cary D.; Huang, Chunning; Takeda, Yasuhiro; Liu, Yun

    2014-01-01

    A compact optical correlator system that measures both the autocorrelation between two infrared (IR) lights and the cross-correlation between an IR and an ultraviolet (UV) light using a single nonlinear optical crystal has been designed and experimentally demonstrated. The rapid scanning of optical delay line, switching between auto and cross-correlations, crystal angle tuning, and data acquisition and processing are all computer controlled. Pulse widths of an IR light from a mode-locked laser are measured by the correlator and the results are compared with a direct measurement using a high-speed photodetector system. The correlator has been used to study the parametermore » dependence of the pulse width of a macropulse UV laser designed for laser-assisted hydrogen ion (H-) beam stripping for the Spallation Neutron Source at Oak Ridge National Laboratory.« less

  14. Multifunctional optical correlator for picosecond ultraviolet laser pulse measurement

    SciTech Connect

    Rakhman, Abdurahim; Wang, Yang; Garcia, Frances; Long, Cary D.; Huang, Chunning; Takeda, Yasuhiro; Liu, Yun

    2014-01-01

    A compact optical correlator system that measures both the autocorrelation between two infrared (IR) lights and the cross-correlation between an IR and an ultraviolet (UV) light using a single nonlinear optical crystal has been designed and experimentally demonstrated. The rapid scanning of optical delay line, switching between auto and cross-correlations, crystal angle tuning, and data acquisition and processing are all computer controlled. Pulse widths of an IR light from a mode-locked laser are measured by the correlator and the results are compared with a direct measurement using a high-speed photodetector system. The correlator has been used to study the parameter dependence of the pulse width of a macropulse UV laser designed for laser-assisted hydrogen ion (H-) beam stripping for the Spallation Neutron Source at Oak Ridge National Laboratory.

  15. Ultraviolet femtosecond and nanosecond laser ablation of silicon: Ablation efficiency and laser-induced plasma expansion

    SciTech Connect

    Zeng, Xianzhong; Mao, Xianglei; Greif, Ralph; Russo, Richard E.

    2004-03-23

    Femtosecond laser ablation of silicon in air was studied and compared with nanosecond laser ablation at ultraviolet wavelength (266 nm). Laser ablation efficiency was studied by measuring crater depth as a function of pulse number. For the same number of laser pulses, the fs-ablated crater was about two times deeper than the ns-crater. The temperature and electron number density of the pulsed laser-induced plasma were determined from spectroscopic measurements. The electron number density and temperature of fs-pulse plasmas decreased faster than ns-pulse plasmas due to different energy deposition mechanisms. Images of the laser-induced plasma were obtained with femtosecond time-resolved laser shadowgraph imaging. Plasma expansion in both the perpendicular and the lateral directions to the laser beam were compared for femtosecond and nanosecond laser ablation.

  16. Analysis of fabric materials cut using ultraviolet laser ablation

    NASA Astrophysics Data System (ADS)

    Tsai, Hsin-Yi; Yang, Chih-Chung; Hsiao, Wen-Tse; Huang, Kuo-Cheng; Andrew Yeh, J.

    2016-04-01

    Laser ablation technology has widely been applied in the clothing industry in recent years. However, the laser mechanism would affect the quality of fabric contours and its components. Hence, this study examined carbonization and oxidation conditions and contour variation in nonwoven, cotton, and composite leather fabrics cut by using an ultraviolet laser at a wavelength of 355 nm. Processing parameters such as laser power, pulse frequency, scanning speed, and number of pulses per spot were adjusted to investigate component variation of the materials and to determine suitable cutting parameters for the fabrics. The experimental results showed that the weights of the component changed substantially by pulse frequency but slightly by laser power, so pulse frequency of 100 kHz and laser power of 14 W were the approximate parameters for three fabrics for the smaller carbonization and a sufficient energy for rapidly cutting, which the pulse duration of laser system was fixed at 300 μs and laser irradiance was 0.98 J/mm2 simultaneously. In addition, the etiolate phenomenon of nonwoven was reduced, and the component weight of cotton and composite leather was closed to the value of knife-cut fabric as the scanning speed increased. The approximate scanning speed for nonwoven and composite leather was 200 mm/s, and one for cotton was 150 mm/s, respectively. The sharper and firmer edge is obtained by laser ablation mechanism in comparison with traditional knife cutting. Experimental results can serve as the reference for laser cutting in the clothing industry, for rapidly providing smoother patterns with lower carbonization and oxidation edge in the fashion industry.

  17. High power, short pulses ultraviolet laser for the development of a new x-ray laser

    SciTech Connect

    Meixler, L.; Nam, C.H.; Robinson, J.; Tighe, W.; Krushelnick, K.; Suckewer, S.; Goldhar, J.; Seely, J.; Feldman, U.

    1989-04-01

    A high power, short pulse ultraviolet laser system (Powerful Picosecond-Laser) has been developed at the Princeton Plasma Physics Laboratory (PPPL) as part of experiments designed to generate shorter wavelength x-ray lasers. With the addition of pulse compression and a final KrF amplifier the laser output is expected to have reached 1/3-1/2 TW (10/sup 12/ watts) levels. The laser system, particularly the final amplifier, is described along with some initial soft x-ray spectra from laser-target experiments. The front end of the PP-Laser provides an output of 20--30 GW (10/sup 9/ watts) and can be focussed to intensities of /approximately/10/sup 16/ W/cm/sup 2/. Experiments using this output to examine the effects of a prepulse on laser-target interaction are described. 19 refs., 14 figs.

  18. Ultraviolet laser ablation of polycarbonate and glass in air

    SciTech Connect

    Bormotova, T. A.; Blumenthal, R.

    2009-02-01

    The fundamental physical processes that follow ultraviolet laser ablation of polycarbonate and borosilicate glass in air have been investigated using photodeflection as a function of the distance from the surface to probe laser. Four features were observed in the data sets for each material. Two of these features correlate well with gas dynamical predictions for the expansion of the shock wave and gas plume. The third feature is consistent with the propagation of the popping sound of the laser ablation event. The final feature, which occurs at very early times and does not shift significantly in time as the surface to probe distance is increased from 0 to greater than 6 mm, has been tentatively ascribed to the ejection of fast electrons. The final significant observation is complete blocking of the probe laser, only observed during borosilicate ablation, which is attributed to scattering of the probe laser light by macroscopic SiO{sub x} particles that grow in the final stages of plume expansion and cooling.

  19. Laser plasma formation assisted by ultraviolet pre-ionization

    SciTech Connect

    Yalin, Azer P. Dumitrache, Ciprian; Wilvert, Nick; Joshi, Sachin; Shneider, Mikhail N.

    2014-10-15

    We present experimental and modeling studies of air pre-ionization using ultraviolet (UV) laser pulses and its effect on laser breakdown of an overlapped near-infrared (NIR) pulse. Experimental studies are conducted with a 266 nm beam (fourth harmonic of Nd:YAG) for UV pre-ionization and an overlapped 1064 nm NIR beam (fundamental of Nd:YAG), both having pulse duration of ∼10 ns. Results show that the UV beam produces a pre-ionized volume which assists in breakdown of the NIR beam, leading to reduction in NIR breakdown threshold by factor of >2. Numerical modeling is performed to examine the ionization and breakdown of both beams. The modeled breakdown threshold of the NIR, including assist by pre-ionization, is in reasonable agreement with the experimental results.

  20. PULSE: the Palomar Ultraviolet Laser for the Study of Exoplanets

    NASA Astrophysics Data System (ADS)

    Bottom, Michael; Dekany, R.; Bowler, B. P.; Baranec, C.; Burruss, R.

    2014-01-01

    PULSE is a project to augment the currently operating 5.1-m Hale PALM-3000 exoplanet adaptive optics system with an ultraviolet Rayleigh laser and associated wavefront sensor. By using a bright (U ~ 7) ultraviolet laser to measure the high spatial and temporal order turbulence near the telescope aperture, where it dominates, one can extend the faintness limit of natural guide stars needed by PALM-3000. Initial simulations indicate that very-high infrared contrast ratios and good visible-light adaptive optics performance will be achieved by such an upgraded system on stars as faint as mV = 16-17 using an optimized low-order NGS sensor. This will enable direct imaging searches for, and subsequent characterization of, companions around cool, low-mass stars for the first time, as well as routine visible-light imaging twice as sharp as HST for fainter targets. PULSE will reuse the laser and wavefront sensor technology developed for the automated Robo-AO laser system currently operating at the Palomar 60-inch telescope, as well as take advantage of pending optimization of low-order NGS wavefront sensing and planned new interfaces to the PALM-3000 real-time reconstruction computer. PULSE will dramatically extend the AO sky coverage of the telescope from 1% to 50%. More specifically, this will boost the yield from a number of operational exoplanet instruments at Palomar including PHARO, a NIR imager, spectrograph, and coronagraph; a fiber nulling interferometer; and Project 1640, a coronagraph and IFS. Two additional funded instruments expected to benefit from PULSE in the coming years are the SDC; a NIR/visible self-calibrating vector vortex coronagraph, and DARKNESS; an energy-resolving, photon counting MKIDS camera.

  1. Injection locking of a high power ultraviolet laser diode for laser cooling of ytterbium atoms

    SciTech Connect

    Hosoya, Toshiyuki; Miranda, Martin; Inoue, Ryotaro; Kozuma, Mikio

    2015-07-15

    We developed a high-power laser system at a wavelength of 399 nm for laser cooling of ytterbium atoms with ultraviolet laser diodes. The system is composed of an external cavity laser diode providing frequency stabilized output at a power of 40 mW and another laser diode for amplifying the laser power up to 220 mW by injection locking. The systematic method for optimization of our injection locking can also be applied to high power light sources at any other wavelengths. Our system does not depend on complex nonlinear frequency-doubling and can be made compact, which will be useful for providing light sources for laser cooling experiments including transportable optical lattice clocks.

  2. Ultraviolet Free Electron Laser Facility preliminary design report

    SciTech Connect

    Ben-Zvi, I.

    1993-02-01

    This document, the Preliminary Design Report (PDR) for the Brookhaven Ultraviolet Free Electron Laser (UV FEL) facility, describes all the elements of a facility proposed to meet the needs of a research community which requires ultraviolet sources not currently available as laboratory based lasers. Further, for these experiments, the requisite properties are not extant in either the existing second or upcoming third generation synchrotron light sources. This document is the result of our effort at BNL to identify potential users, determine the requirements of their experiments, and to design a facility which can not only satisfy the existing need, but have adequate flexibility for possible future extensions as need dictates and as evolving technology allows. The PDR is comprised of three volumes. In this, the first volume, background for the development of the proposal is given, including descriptions of the UV FEL facility, and representative examples of the science it was designed to perform. Discussion of the limitations and potential directions for growth are also included. A detailed description of the facility design is then provided, which addresses the accelerator, optical, and experimental systems. Information regarding the conventional construction for the facility is contained in an addendum to volume one (IA).

  3. Laser produced plasma for efficient extreme ultraviolet light sources

    SciTech Connect

    Donnelly, Tony; Cummins, Thomas; O' Gorman, Colm; Li Bowen; Harte, Colm S.; O'Reilly, Fergal; Sokell, Emma; Dunne, Padraig; O'Sullivan, Gerry

    2012-05-25

    Extreme ultraviolet emission from laser produced plasma and their relevance to EUV source development is discussed. The current state of the field for Sn LPP sources operating at 13.5 nm is described and initial results are given for EUV emission from CO{sub 2} laser irradiation of a bulk Sn target. A maximum conversion efficiency of 1.7% has been measured and the influence of the CO{sub 2} laser temporal profile on the CE is discussed. A double pulse irradiation scheme is shown to increase CE up to a maximum value of 2.1% for an optimum prepulse - pulse delay of 150 ns. The emergence of a new EUVL source wavelength at 6.7 nm based on Gd and Tb LPPs has been outlined. An initial experiment investigating picosecond laser irradiation as a means to produce strong 6.7 nm emission from a Gd{sub 2}O{sub 3} target has been performed and verified.

  4. Method and apparatus for producing durationally short ultraviolet or x-ray laser pulses

    DOEpatents

    MacGowan, B.J.; Matthews, D.L.; Trebes, J.E.

    1987-05-05

    A method and apparatus is disclosed for producing ultraviolet or x- ray laser pulses of short duration. An ultraviolet or x-ray laser pulse of long duration is progressively refracted, across the surface of an opaque barrier, by a streaming plasma that is produced by illuminating a solid target with a pulse of conventional line focused high power laser radiation. The short pulse of ultraviolet or x-ray laser radiation, which may be amplified to high power, is separated out by passage through a slit aperture in the opaque barrier.

  5. Method and apparatus for producing durationally short ultraviolet or X-ray laser pulses

    DOEpatents

    MacGowan, Brian J.; Matthews, Dennis L.; Trebes, James E.

    1988-01-01

    A method and apparatus is disclosed for producing ultraviolet or X-ray laser pulses of short duration (32). An ultraviolet or X-ray laser pulse of long duration (12) is progressively refracted, across the surface of an opaque barrier (28), by a streaming plasma (22) that is produced by illuminating a solid target (16, 18) with a pulse of conventional line focused high power laser radiation (20). The short pulse of ultraviolet or X-ray laser radiation (32), which may be amplified to high power (40, 42), is separated out by passage through a slit aperture (30) in the opaque barrier (28).

  6. Diode-laser-based ultraviolet absorption sensor for nitric oxide

    NASA Astrophysics Data System (ADS)

    Hanna, S. F.; Barron-Jimenez, R.; Anderson, T. N.; Lucht, R. P.; Caton, J. A.; Walther, T.

    2002-07-01

    An all-solid-state continuous-wave laser system for ultraviolet absorption measurements of the nitric oxide (NO) molecule has been developed and demonstrated. The single-mode, tunable output of a 10-mW, 395-nm external-cavity diode laser (ECDL) is sum-frequency-mixed with the output of a 115-mW, frequency-doubled, diode-pumped Nd:YAG laser in a beta-barium-borate crystal to produce 40 nW of tunable radiation at 226.8 nm. The wavelength of the 395-nm ECDL is then scanned over NO absorption lines to produce fully resolved absorption spectra. Initial results from mixtures of NO in nitrogen in a room-temperature gas cell are discussed. The estimated NO detection limit of the system for a demonstrated absorption sensitivity of 2×10-3 is 0.2 ppm per meter of path length for 300 K gas. The estimated accuracy of the measurements is ±10%.

  7. Colliding laser-produced plasmas as targets for laser-generated extreme ultraviolet sources

    SciTech Connect

    Cummins, T.; O'Gorman, C.; Dunne, P.; Sokell, E.; O'Sullivan, G.; Hayden, P.

    2014-07-28

    Colliding plasmas produced by neodymium-doped yttrium aluminium garnet (Nd:YAG) laser illumination of tin wedge targets form stagnation layers, the physical parameters of which can be controlled to optimise coupling with a carbon dioxide (CO{sub 2}) heating laser pulse and subsequent extreme ultraviolet (EUV) production. The conversion efficiency (CE) of total laser energy into EUV emission at 13.5 nm ± 1% was 3.6%. Neglecting both the energy required to form the stagnation layer and the EUV light produced before the CO{sub 2} laser pulse is incident results in a CE of 5.1% of the CO{sub 2} laser energy into EUV light.

  8. CO2 laser drives extreme ultraviolet nano-lithography — second life of mature laser technology

    NASA Astrophysics Data System (ADS)

    Nowak, K. M.; Ohta, T.; Suganuma, T.; Fujimoto, J.; Mizoguchi, H.; Sumitani, A.; Endo, A.

    2013-12-01

    It was shown both theoretically and experimentally that nanosecond order laser pulses at 10.6 micron wavelength were superior for driving the Sn plasma extreme ultraviolet (EUV) source for nano-lithography for the reasons of higher conversion efficiency, lower production of debris and higher average power levels obtainable in CO2 media without serious problems of beam distortions and nonlinear effects occurring in competing solid-state lasers at high intensities. The renewed interest in such pulse format, wavelength, repetition rates in excess of 50 kHz and average power levels in excess of 18 kiloWatt has sparked new opportunities for a matured multi-kiloWatt CO2 laser technology. The power demand of EUV source could be only satisfied by a Master-Oscillator-Power-Amplifier system configuration, leading to a development of a new type of hybrid pulsed CO2 laser employing a whole spectrum of CO2 technology, such as fast flow systems and diffusion-cooled planar waveguide lasers, and relatively recent quantum cascade lasers. In this paper we review briefly the history of relevant pulsed CO2 laser technology and the requirements for multi-kiloWatt CO2 laser, intended for the laser-produced plasma EUV source, and present our recent advances, such as novel solid-state seeded master oscillator and efficient multi-pass amplifiers built on planar waveguide CO2 lasers.

  9. Analysis of extreme ultraviolet spectra from laser produced rhenium plasmas

    NASA Astrophysics Data System (ADS)

    Wu, Tao; Higashiguchi, Takeshi; Li, Bowen; Suzuki, Yuhei; Arai, Goki; Dinh, Thanh-Hung; Dunne, Padraig; O'Reilly, Fergal; Sokell, Emma; Liu, Luning; O'Sullivan, Gerry

    2015-08-01

    Extreme ultraviolet spectra of highly-charged rhenium ions were observed in the 1-7 nm region using two Nd:YAG lasers with pulse lengths of 150 ps and 10 ns, respectively, operating at a number of laser power densities. The maximum focused peak power density was 2.6 × 1014 W cm-2 for the former and 5.5 × 1012 W cm-2 for the latter. The Cowan suite of atomic structure codes and unresolved transition array (UTA) approach were used to calculate and interpret the emission properties of the different spectra obtained. The results show that n = 4-n = 4 and n = 4-n = 5 UTAs lead to two intense quasi-continuous emission bands in the 4.3-6.3 nm and 1.5-4.3 nm spectral regions. As a result of the different ion stage distributions in the plasmas induced by ps and ns laser irradiation the 1.5-4.3 nm UTA peak moves to shorter wavelength in the ps laser produced plasma spectra. For the ns spectrum, the most populated ion stage during the lifetime of this plasma that could be identified from the n = 4-n = 5 transitions was Re23+ while for the ps plasma the presence of significantly higher stages was demonstrated. For the n = 4-n = 4 4p64dN-4p54dN+1 + 4p64dN-14f transitions, the 4d-4f transitions contribute mainly in the most intense 4.7-5.5 nm region while the 4p-4d subgroup gives rise to a weaker feature in the 4.3-4.7 nm region. A number of previously unidentified spectral features produced by n = 4-n = 5 transitions in the spectra of Re XVI to Re XXXIX are identified.

  10. Study on the Pr:KYF ultraviolet laser at 305 nm pumped by blue laser

    NASA Astrophysics Data System (ADS)

    Ni, Tian-yi; Li, Yong-liang; Zhang, Tian-yi; Ruan, Ren-qiu

    2012-09-01

    An all-solid-state Pr:KY3F10 (Pr:KYF) laser pumped by blue laser (471 nm) has been demonstrated. With the incident pump power of 2.6 W, the maximum output power at 610 nm is 213 mW. Moreover, the intracavity second-harmonic generation (SHG) is also achieved with the maximum ultraviolet (UV) power at 305 nm of 11 mW by using a β-BaB2O4 (BBO) nonlinear crystal.

  11. Laser-assisted vacuum arc extreme ultraviolet source: a comparison of picosecond and nanosecond laser triggering

    NASA Astrophysics Data System (ADS)

    Beyene, Girum A.; Tobin, Isaac; Juschkin, Larissa; Hayden, Patrick; O’Sullivan, Gerry; Sokell, Emma; Zakharov, Vassily S.; Zakharov, Sergey V.; O’Reilly, Fergal

    2016-06-01

    Extreme ultraviolet (EUV) light generation by hybrid laser-assisted vacuum arc discharge plasmas, utilizing Sn-coated rotating-disc-electrodes, was investigated. The discharge was initiated by localized ablation of the liquid tin coating of the cathode disc by a laser pulse. The laser pulse, at 1064 nm, was generated by Nd:YAG lasers with variable energy from 1 to 100 mJ per pulse. The impact of shortening the laser pulse from 7 ns to 170 ps on the EUV generation has been investigated in detail. The use of ps pulses resulted in an increase in emission of EUV radiation. With a fixed discharge energy of ~4 J, the EUV conversion efficiency tends to plateau at ~2.4  ±  0.25% for the ps laser pulses, while for the ns pulses, it saturates at ~1.7  ±  0.3%. Under similar discharge and laser energy conditions, operating the EUV source with the ps-triggering resulted also in narrower spectral profiles of the emission in comparison to ns-triggering. The results indicate an advantage in using ps-triggering in laser-assisted discharges to produce brighter plasmas required for applications such as metrology.

  12. Can free-electron lasers answer critical questions in ultraviolet photobiology?

    NASA Astrophysics Data System (ADS)

    Sutherland, John C.

    2000-04-01

    This paper will evaluate the potential of ultraviolet free electron lasers, and particularly the soon to be available UV-FEL at the Thomas Jefferson National Accelerator Facility for such experiments.

  13. Angular distribution of ions and extreme ultraviolet emission in laser-produced tin droplet plasma

    NASA Astrophysics Data System (ADS)

    Chen, Hong; Wang, Xinbing; Duan, Lian; Lan, Hui; Chen, Ziqi; Zuo, Duluo; Lu, Peixiang

    2015-05-01

    Angular-resolved ion time-of-flight spectra as well as extreme ultraviolet radiation in laser-produced tin droplet plasma are investigated experimentally and theoretically. Tin droplets with a diameter of 150 μm are irradiated by a pulsed Nd:YAG laser. The ion time-of-flight spectra measured from the plasma formed by laser irradiation of the tin droplets are interpreted in terms of a theoretical elliptical Druyvesteyn distribution to deduce ion density distributions including kinetic temperatures of the plasma. The opacity of the plasma for extreme ultraviolet radiation is calculated based on the deduced ion densities and temperatures, and the angular distribution of extreme ultraviolet radiation is expressed as a function of the opacity using the Beer-Lambert law. Our results show that the calculated angular distribution of extreme ultraviolet radiation is in satisfactory agreement with the experimental data.

  14. Angular distribution of ions and extreme ultraviolet emission in laser-produced tin droplet plasma

    SciTech Connect

    Chen, Hong; Duan, Lian; Lan, Hui; Wang, Xinbing Chen, Ziqi; Zuo, Duluo; Lu, Peixiang

    2015-05-21

    Angular-resolved ion time-of-flight spectra as well as extreme ultraviolet radiation in laser-produced tin droplet plasma are investigated experimentally and theoretically. Tin droplets with a diameter of 150 μm are irradiated by a pulsed Nd:YAG laser. The ion time-of-flight spectra measured from the plasma formed by laser irradiation of the tin droplets are interpreted in terms of a theoretical elliptical Druyvesteyn distribution to deduce ion density distributions including kinetic temperatures of the plasma. The opacity of the plasma for extreme ultraviolet radiation is calculated based on the deduced ion densities and temperatures, and the angular distribution of extreme ultraviolet radiation is expressed as a function of the opacity using the Beer–Lambert law. Our results show that the calculated angular distribution of extreme ultraviolet radiation is in satisfactory agreement with the experimental data.

  15. An ultraviolet laser source and spectral imaging filters for non-intrusive laser-based diagnostics

    NASA Astrophysics Data System (ADS)

    Finkelstein, Noah D. M.

    1998-05-01

    This dissertation details the development of new state- of-the-art tools which enable ultraviolet non-intrusive laser based diagnostics. A laser source and three new optical filters are developed, characterized, and demonstrated in application to flowfield diagnostics. The laser produces high power (50mJ/pulse), spectrally near transform limited, spatially near diffraction limited, tunable output in the vicinity of 250 nm. A notch absorption band and two narrow passband spectral filters feature exceptional spectral resolution, high throughput, and maintain imaging capabilities. Pairing the laser and filters makes possible unique spatially resolved flowfield measurements via ultraviolet Rayleigh and Raman scattering based techniques. The laser source is an injection-seeded, frequency- tripled, cavity-locked, titanium:sapphire source. It features a new cavity locking scheme, which allows it to be tuned rapidly and discontinuously without losing its narrowband spectral profile. The first spectral filter is a narrow band, notch absorption filter that is based upon a ground state absorption of mercury. The filter acts to strongly suppress a narrow spectral band (on a GHz scale), while efficiently passing light spectrally shifted by a GHz or less. The filter is characterized, modeled, and combined with the laser to demonstrate ultraviolet filtered Rayleigh scattering for flowfield visualization and velocity measurements of a Mach 2 free jet. The second filter is a narrow passband imaging filter, designed for rotational Raman scattering based measurements. It features an ultranarrow passband (less than 1cm-1) and has the ability to suppress strong background scattering (Rayleigh scattering and surface reflections) while maintaining 2-D imaging capabilities. This filter is characterized, modeled, and applied in measurements of individual pure rotational Raman lines of oxygen and nitrogen in room air. The third filter, also for rotational Raman imaging, simultaneously

  16. New powerful metal vapor lasers oscillating in deep ultraviolet and middle infrared spectral ranges

    NASA Astrophysics Data System (ADS)

    Temelkov, K. A.; Vuchkov, N. K.; Sabotinov, N. V.

    2010-09-01

    Middle infrared and deep ultraviolet laser systems, which are based on high-power high-beam-quality stable-operating He-SrBr2 and Cu+ Ne-CuBr lasers excited in nanosecond pulsed longitudinal discharge, are developed, patented and studied. Optimal discharge conditions, such as active zone diameter, vapor pressure, buffer-gas pressure, electrical excitation scheme parameters, average input power, pulse repetition frequency, are found. The highest output laser parameters are obtained for the Sr atom and Cu+ lasers, respectively. These lasers equipped with optical systems for control of laser radiation parameters, such as laser beam divergence, laser intensity distribution, etc. are used in a large variety of applications, such as precise material microprocessing, including biological tissues, determination of linear optical properties of different materials newly developed, laser-induced modification of conductive polymers, laserinduced fluorescence in wide-gap semiconductors, instead of free electron and excimer lasers, respectively.

  17. Energy transport in short-pulse-laser-heated targets measured using extreme ultraviolet laser backlighting.

    PubMed

    Wilson, L A; Tallents, G J; Pasley, J; Whittaker, D S; Rose, S J; Guilbaud, O; Cassou, K; Kazamias, S; Daboussi, S; Pittman, M; Delmas, O; Demailly, J; Neveu, O; Ros, D

    2012-08-01

    The accurate characterization of thermal electron transport and the determination of heating by suprathermal electrons in laser driven solid targets are both issues of great importance to the current experiments being performed at the National Ignition Facility, which aims to achieve thermonuclear fusion ignition using lasers. Ionization, induced by electronic heat conduction, can cause the opacity of a material to drop significantly once bound-free photoionization is no longer energetically possible. We show that this drop in opacity enables measurements of the transmission of extreme ultraviolet (EUV) laser pulses at 13.9 nm to act as a signature of the heating of thin (50 nm) iron layers with a 50-nm thick parylene-N (CH) overlay irradiated by 35-fs pulses at irradiance 3×10(16) Wcm(-2). Comparing EUV transmission measurements at different times after irradiation to fluid code simulations shows that the target is instantaneously heated by hot electrons (with approximately 10% of the laser energy), followed by thermal conduction with a flux limiter of ≈0.05. PMID:23005868

  18. A long-term frequency stabilized deep ultraviolet laser for Mg+ ions trapping experiments

    NASA Astrophysics Data System (ADS)

    Zhang, J.; Yuan, W. H.; Deng, K.; Deng, A.; Xu, Z. T.; Qin, C. B.; Lu, Z. H.; Luo, J.

    2013-12-01

    As many precision laser spectroscopy experiments require frequency stabilized lasers, development of long-term stabilized lasers is of great interest. In this work, we report long-term frequency stabilization of a 280 nm deep ultraviolet laser to a high precision wavemeter with digital servo control such that the long-term drift of the laser frequency was greatly reduced. Long-term laser frequency drift was measured with a fiber frequency comb system over 8 h. After locking, the maximum drift rate of the 280 nm laser was lowered from 576 MHz/h to 6.4 MHz/h. With proper environment control of the wavemeter, the maximum drift rate of the 280 nm laser was further lowered to less than 480 kHz/h. The locked laser system was successfully used in a Mg+ ions trapping experiment, which was also discussed in this work.

  19. Comparison of laser and ultraviolet techniques used in the detection of body secretions.

    PubMed

    Auvdel, M J

    1987-03-01

    Evaluation of the detection capabilities of both laser and ultraviolet light sources was performed. The Spectra-Physics Model 171-19 argon ion laser was used in a comparison with the hand held Mineralight multiband ultraviolet lamp, Model UVSL-58 and the Fotodyne Foto UV 410, Model 3-4100. Both techniques were evaluated as to their detection limits for various biological stains. A serial dilution was made from semen, saliva, and sweat samples and their corresponding stains were examined under laser and ultraviolet light sources. The techniques were also evaluated as to possible interferences which may arise based on the type of fabric the stains were made on. The advantages and disadvantages of each technique in relationship to their initial costs are discussed. PMID:3572332

  20. Measurement of temperature and density fluctuations in turbulence using an ultraviolet laser

    NASA Technical Reports Server (NTRS)

    Massey, G. A.

    1984-01-01

    Noninvasive measurement of density and temperature fluctuations in turbulent air flow was examined. The approach used fluorescence of oxygen molecules which are selectively excited by a tunable vacuum ultraviolet laser beam. The strength of the fluorescence signal and its dependence on laser wavelength vary with the density and temperature of the air in the laser beam. Because fluorescence can be detected at 90 degrees from the beam propagation direction, spatial resolution in three dimensions, rather than path-integrated measurements can be achieved. With spatial resolutions of the order of a millimeter and at supersonic air velocities it is necessary to perform each measurement in a time of the order of a microsecond; this is possible by by using laser pulses of ten nanosecond duration. In this method atmospheric O2 is excited by the emission of a tunable ArF excimer laser, and the fluorescence, which spans the 210 to 420 range, is detected by an ultraviolet phototube.

  1. High-energy, efficient, 30-Hz ultraviolet laser sources for airborne ozone-lidar systems.

    PubMed

    Elsayed, Khaled A; Chen, Songsheng; Petway, Larry B; Meadows, Byron L; Marsh, Waverly D; Edwards, William C; Barnes, James C; DeYoung, Russell J

    2002-05-20

    Two compact, high-pulse-energy, injection-seeded, 30-Hz frequency-doubled Nd:YAG-laser-pumped Ti: sapphire lasers were developed and operated at infrared wavelengths of 867 and 900 nm. Beams with laser pulse energy >30 mJ at ultraviolet wavelengths of 289 and 300 nm were generated through a tripling of the frequencies of these Ti:sapphire lasers. This work is directed at the replacement of dye lasers for use in an airborne ozone differential absorption lidar system. The ultraviolet pulse energy at 289 and 300 nm had 27% and 31% absolute optical energy conversion efficiencies from input pulse energies at 867 and 900 nm, respectively. PMID:12027160

  2. Extreme ultraviolet source using a forced recombination process in lithium plasma generated by a pulsed laser

    NASA Astrophysics Data System (ADS)

    Nagano, Akihisa; Inoue, Takahiro; Nica, Petru-Edward; Amano, Sho; Miyamoto, Shuji; Mochizuki, Takayasu

    2007-04-01

    An extreme ultraviolet source having a tamper has been studied. This target scheme recombines forcedly lithium ions by low temperature electrons from the tamper, converting Li3+ rapidly to excited Li2+ which emit intense 1s-2p Lyman α emissions at 13.5nm. A strong 13.5nm emission appeared at 20-30ns after the time of laser peak within a small space volume near the tamper. The authors obtained an enhancement of extreme ultraviolet conversion efficiency by a factor of about 2 with the tamper against that of a target without the tamper at the same laser irradiation condition.

  3. Diode pumped Pr3+:LiYF4-BBO ultraviolet laser at 320 nm

    NASA Astrophysics Data System (ADS)

    Li, J. H.; Liu, X. H.; Wu, J. B.; Zhang, X.; Li, Y. L.

    2012-03-01

    A diode pumped Pr3+:LiYF4 laser at 639.5 nm has been demonstrated. With an incident pump power of 920 mW, the maximum red output power was 272 mW. Moreover, intracavity second-harmonic generation (SHG) has also been achieved with a maximum ultraviolet power of 23 mW by using a β-BaB2O4 (BBO) nonlinear crystal. To the best of our knowledge, this is the first report on continuous-wave ultraviolet generation by intracavity frequency doubling Pr3+:LiYF4 laser.

  4. Passive intrinsic-linewidth narrowing of ultraviolet extended-cavity diode laser by weak optical feedback

    NASA Astrophysics Data System (ADS)

    Samutpraphoot, Polnop; Weber, Sophie; Lin, Qian; Gangloff, Dorian; Bylinskii, Alexei; Braverman, Boris; Kawasaki, Akio; Raab, Christoph; Kaenders, Wilhelm; Vuletić, Vladan

    2014-05-01

    We present a simple method for narrowing the intrinsic Lorentzian linewidth of a commercial ultraviolet grating extended-cavity diode laser (TOPTICA DL Pro) using weak optical feedback from a long external cavity. We achieve a suppression in frequency noise spectral density of 20 dB measured at frequencies around 1 MHz, corresponding to the narrowing of the intrinsic Lorentzian linewidth from 200 kHz to 2 kHz. The system is suitable for experiments requiring a tunable ultraviolet laser with narrow linewidth and low high-frequency noise, such as precision spectroscopy, optical clocks, and quantum information science experiments.

  5. Synthesis of materials with infrared and ultraviolet lasers

    SciTech Connect

    Lyman, J.L.

    1988-01-01

    This paper discusses three divergent examples of synthesis of materials with lasers. The three techniques are: (1) infrared (CO/sub 2/) laser synthesis of silane (SiH/sub 4/) from disilane (Si/sub 2/H/sub 6/); (2) excimer (ArF) laser production of fine silicon powders from methyl- and chloro-substituted silanes; and, (3) excimer (KrF) laser production of fine metallic powders by laser ablation. The mechanism for each process is discussed along with some conclusions about the features of the laser radiation that enable each application. 19 refs., 12 figs., 2 tabs.

  6. Tunable ultraviolet co-doped dye laser of Pyrromethene 597 and Rhodamine 610

    NASA Astrophysics Data System (ADS)

    Lu, Zhenzhong; Sun, Yanling; Ma, Lin; Liu, Jifang

    2015-12-01

    The laser performance of Pyrromethene 597 (PM597) and Rhodamine 610 mixture is studied. A wide tuning range from 580 to 655 nm is achieved. The laser linewidth obtained is less than 0.1 nm. The highest conversion efficiency of 42.5% is obtained at 600 nm. Using a beta-BaB2O4 (BBO) crystal to frequency double the dye laser into ultraviolet (UV), a tuning range from 296 to 324 nm is obtained. The peak conversion efficiency from the dye laser to the UV laser is 9.7% and the highest UV laser output energy is 9.51 mJ at 301.25 nm. To the best of our knowledge, the tuning range and the conversion efficiency are the best under the same condition so far. All our results indicate that high laser performance can be achieved using a laser dyes’ mixture.

  7. Ordered many-electron motions in atoms and x-ray lasers. [Subpicosecond ultraviolet laser radiation

    SciTech Connect

    Rhodes, C.K.

    1986-01-01

    Subpicosecond ultraviolet laser technology is enabling the exploration of nonlinear atomic interactions with electric field strengths considerably in excess of an atomic unit. As this regime is approached, experiments studying multiple ionization, photoelectron energy spectra, and harmonically produced radiation all exhibit strong nonlinear coupling. Peak total energy transfer rates on the order of approx.2 x 10/sup -4/ W/atom have been observed at an intensity of approx.10/sup 16/ W/cm/sup 2/, and it is expected that energy transfer rates approaching approx.0.1 to 1 W/atom will occur under more extreme conditions for which the ultraviolet electric field E is significantly greater than e/a/sub 0//sup 2/. In this high intensity regime, a wide range of new nonlinear phenomena will be open to study. These will include the possibility of ordered driven motions in atoms, molecules, and plasmas, mechanisms involving collisions, and relativistic processes such as electron-positron pair production. An understanding of these physical interactions may provide a basis for the generation of stimulated emission in the x-ray range. 100 refs., 8 figs.

  8. Numerical simulation of temperature field in K9 glass irradiated by ultraviolet pulse laser

    NASA Astrophysics Data System (ADS)

    Wang, Xi; Fang, Xiaodong

    2015-10-01

    The optical component of photoelectric system was easy to be damaged by irradiation of high power pulse laser, so the effect of high power pulse laser irradiation on K9 glass was researched. A thermodynamic model of K9 glass irradiated by ultraviolet pulse laser was established using the finite element software ANSYS. The article analyzed some key problems in simulation process of ultraviolet pulse laser damage of K9 glass based on ANSYS from the finite element models foundation, meshing, loading of pulse laser, setting initial conditions and boundary conditions and setting the thermal physical parameters of material. The finite element method (FEM) model was established and a numerical analysis was performed to calculate temperature field in K9 glass irradiated by ultraviolet pulse laser. The simulation results showed that the temperature of irradiation area exceeded the melting point of K9 glass, while the incident laser energy was low. The thermal damage dominated in the damage mechanism of K9 glass, the melting phenomenon should be much more distinct.

  9. A comparison of gas temperatures measured by ultraviolet laser scattering in atmospheric plasma sources

    NASA Astrophysics Data System (ADS)

    Sommers, Bradley S.; Adams, Steven F.

    2015-12-01

    A laser scattering system utilizing an ultraviolet laser with a triple grating spectrometer has been assembled in order to measure gas temperature in atmospheric plasma sources. Such laser scattering interactions offer a non-invasive technique for investigating atmospheric microplasma sources, which have potential applications in remote optical sensing, materials processing, and environmental decontamination. This particular system is unique in that it utilizes a ultraviolet laser line (266 nm), which increases the cross section for Rayleigh and Raman scattering by a factor of 16 in comparison to the more common 532 nm laser operating in the visible range. In this work, the laser scattering system is used to directly compare the rotational gas temperature (T r) and gas kinetic temperature (T g) in two different atmospheric plasma sources [1]: a direct current plasma jet operating on nitrogen and [2] a conventional pin-pin glow microdischarge in air. Results show agreement between T r and T g both in the low temperature afterglow of the plasma jet (300-700 K) and the hot center of the atmospheric glow (1500-2000 K). These observations lend credence to the common assumption of rotational relaxation in atmospheric plasmas and validate the ultraviolet laser diagnostic for future application in atmospheric microplasma sources.

  10. A simplified scheme for generating narrow-band mid-ultraviolet laser radiation

    SciTech Connect

    Almog, G.; Scholz, M. Weber, W.; Leisching, P.; Kaenders, W.; Udem, Th.

    2015-03-15

    We report on the development and characterization of continuous, narrow-band, and tunable laser systems that use direct second-harmonic generation from blue and green diode lasers with an output power level of up to 11.1 mW in the mid-ultraviolet. One of our laser systems was tuned to the mercury 6{sup 1}S{sub 0} → 6{sup 3}P{sub 1} intercombination line at 253.7 nm. We could perform Doppler-free saturation spectroscopy on this line and were able to lock our laser to the transition frequency on long time scales.

  11. A simplified scheme for generating narrow-band mid-ultraviolet laser radiation.

    PubMed

    Almog, G; Scholz, M; Weber, W; Leisching, P; Kaenders, W; Udem, Th

    2015-03-01

    We report on the development and characterization of continuous, narrow-band, and tunable laser systems that use direct second-harmonic generation from blue and green diode lasers with an output power level of up to 11.1 mW in the mid-ultraviolet. One of our laser systems was tuned to the mercury 6(1)S0 → 6(3)P1 intercombination line at 253.7 nm. We could perform Doppler-free saturation spectroscopy on this line and were able to lock our laser to the transition frequency on long time scales. PMID:25832214

  12. Spectroscopic measurements of ablation plasma generated with laser-driven intense extreme ultraviolet (EUV) light

    NASA Astrophysics Data System (ADS)

    Tanaka, N.; Hane, K.; Shikata, H.; Masuda, M.; Nagatomi, K.; Sunahara, A.; Yoshida, M.; Fujioka, S.; Nishimura, H.

    2016-03-01

    Material ablation by a focused Extreme ultraviolet (EUV) light is studied by comparing expanding ion properties and plasma parameters with laser ablation. The kinetic energy distributions of expanding ions from EUV and laser ablation showed different spectra implying different geometries of plasma expansion. The calculation results of plasma parameters showed that EUV energy is mostly deposited in high electron density region close to the solid density, while laser energy is deposited in low energy density region. Plasma parameters experimentally obtained from visible spectra did not show noticeable difference between EUV and laser ablation due to the corresponding low cut off density.

  13. Ultraviolet continuous-wave laser source at 205 nm for hydrogen spectroscopy

    NASA Astrophysics Data System (ADS)

    Galtier, Sandrine; Nez, François; Julien, Lucile; Biraben, François

    This paper reports on the generation of 15 mW of continuous narrow-band laser source at 205 nm. The infra-red light source provided by a Titanium-Sapphire (TiSa) laser is mixed with the fourth harmonic of a Nd:YVO4 laser by the use of a β-barium borate (BBO) non-linear crystal. This highly reliable and powerful ultraviolet (UV) source is an ideal tool for the 1S-3S hydrogen spectroscopy. Moreover, the wide tunability of the TiSa laser combined with this experimental set up makes the generation of bright deep ultra-violet (D-UV) sources possible. In particular, we plan to produce a 194 nm continuous light beam which is necessary to perform the 1S-4S transition in hydrogen.

  14. Multiple pulse thermal damage thresholds of materials for x-ray free electron laser optics investigated with an ultraviolet laser

    SciTech Connect

    Hau-Riege, Stefan P.; London, Richard A.; Bionta, Richard M.; Soufli, Regina; Ryutov, Dmitri; Shirk, Michael; Baker, Sherry L.; Smith, Patrick M.; Nataraj, Pradeep

    2008-11-17

    Optical elements to be used for x-ray free electron lasers (XFELs) must withstand multiple high-fluence pulses. We have used an ultraviolet laser to study the damage of two candidate materials, crystalline Si and B{sub 4}C-coated Si, emulating the temperature profile expected to occur in optics exposed to XFEL pulses. We found that the damage threshold for 10{sup 5} pulses is {approx}20% to 70% lower than the melting threshold.

  15. All-solid-state blue laser pumped Pr:KY3F10-BBO ultraviolet laser at 305 nm All-solid-state blue laser

    NASA Astrophysics Data System (ADS)

    Dong, Y.; Li, S. T.; Zhang, X. H.

    2012-02-01

    An all-solid-state blue laser pumped Pr:KY3F10 (Pr:KYF) laser at 610 nm has been demonstrated. With an incident pump power of 2.6 W, the maximum output power was 213 mW. Moreover, intracavity second-harmonic generation (SHG) has also been achieved with a maximum ultraviolet power of 11 mW by using a β-BaB2O4 (BBO) nonlinear crystal. To the best of our knowledge, this is the first report on continuous-wave ultraviolet generation by intracavity frequency doubling Pr:KYF laser.

  16. Comparing Vacuum and Extreme Ultraviolet Radiation for Postionization of Laser Desorbed Neutrals from Bacterial Biofilms and Organic Fullerene

    SciTech Connect

    Gaspera, Gerald L.; Takahashi, Lynelle K.; Zhou, Jia; Ahmed, Musahid; Moored, Jerry F.; Hanley, Luke

    2010-12-08

    Vacuum and extreme ultraviolet radiation from 8 - 24 eV generated at a synchrotron was used to postionize laser desorbed neutrals of antibiotic-treated biofilms and a modified fullerene using laser desorption postionization mass spectrometry (LDPI-MS). Results show detection of the parent ion, various fragments, and extracellular material from biofilms using LDPI-MS with both vacuum and extreme ultraviolet photons. Parent ions were observed for both cases, but extreme ultraviolet photons (16-24 eV) induced more fragmentation than vacuum ultraviolet (8-14 eV) photons.

  17. Infrared and ultraviolet laser removal of crustose lichens on dolomite heritage stone

    NASA Astrophysics Data System (ADS)

    Sanz, Mikel; Oujja, Mohamed; Ascaso, Carmen; de los Ríos, Asunción; Pérez-Ortega, Sergio; Souza-Egipsy, Virginia; Wierzchos, Jacek; Speranza, Mariela; Cañamares, Maria Vega; Castillejo, Marta

    2015-08-01

    Laser removal of biodeteriogen layers warrants detailed studies due to the advantages it brings with respect to mechanical elimination or the use of biocides. We have investigated elimination of biological crusts on dolomite stones from heritage sites in central Spain. The samples were colonized by epilithic crustose lichens of different species, such as Caloplaca sp. and Verrucaria nigrescens. A comparative study was carried out by applying infrared (1064 nm) and ultraviolet (355 nm) nanosecond laser pulses and sequences pulses of the two wavelengths using a Q-switched Nd:YAG system. To detect anatomical and ultrastructural damage to the lichens, and to assess possible morphological and chemical changes on the underlying stone induced by laser irradiation, we used stereomicroscopy, scanning electron microscopy with backscattered electron imaging and Fourier transform Raman spectroscopy. The optimal conditions for removal of the colonization crust, while ensuring preservation of the lithic substrate, were obtained for dual infrared-ultraviolet sequential irradiation.

  18. Ablation and transmission of thin solid targets irradiated by intense extreme ultraviolet laser radiation

    NASA Astrophysics Data System (ADS)

    Aslanyan, V.; Kuznetsov, I.; Bravo, H.; Woolston, M. R.; Rossall, A. K.; Menoni, C. S.; Rocca, J. J.; Tallents, G. J.

    2016-09-01

    The interaction of an extreme ultraviolet (EUV) laser beam with a parylene foil was studied by experiments and simulation. A single EUV laser pulse of nanosecond duration focused to an intensity of 3 × 1010 W cm-2 perforated micrometer thick targets. The same laser pulse was simultaneously used to diagnose the interaction by a transmission measurement. A combination of 2-dimensional radiation-hydrodynamic and diffraction calculations was used to model the ablation, leading to good agreement with experiment. This theoretical approach allows predictive modelling of the interaction with matter of intense EUV beams over a broad range of parameters.

  19. Heating dynamics and extreme ultraviolet radiation emission of laser-produced Sn plasmas

    SciTech Connect

    Yuspeh, S.; Sequoia, K. L.; Tao, Y.; Tillack, M. S.; Burdt, R. A.; Najmabadi, F.

    2010-06-28

    The impact of 1.064 mum laser absorption depth on the heating and in-band (2% bandwidth) 13.5 nm extreme ultraviolet emissions in Sn plasmas is investigated experimentally and numerically. In-band emission lasting longer than the laser pulse and separation between the laser absorption and in-band emission region are observed. Maximum efficiency is achieved by additional heating of the core of the plasma to allow the optimal temperature to expand to a lower and more optically thin density. This leads to higher temperature plasma that emits less in-band light as compared to CO{sub 2} produced plasma sources for the same application.

  20. Large-solid-angle illuminators for extreme ultraviolet lithography with laser plasmas

    SciTech Connect

    Kubiak, G.D.; Tichenor, D.A.; Sweatt, W.C.; Chow, W.W.

    1995-06-01

    Laser Plasma Sources (LPSS) of extreme ultraviolet radiation are an attractive alternative to synchrotron radiation sources for extreme ultraviolet lithography (EUVL) due to their modularity, brightness, and modest size and cost. To fully exploit the extreme ultraviolet power emitted by such sources, it is necessary to capture the largest possible fraction of the source emission half-sphere while simultaneously optimizing the illumination stationarity and uniformity on the object mask. In this LDRD project, laser plasma source illumination systems for EUVL have been designed and then theoretically and experimentally characterized. Ellipsoidal condensers have been found to be simple yet extremely efficient condensers for small-field EUVL imaging systems. The effects of aberrations in such condensers on extreme ultraviolet (EUV) imaging have been studied with physical optics modeling. Lastly, the design of an efficient large-solid-angle condenser has been completed. It collects 50% of the available laser plasma source power at 14 nm and delivers it properly to the object mask in a wide-arc-field camera.

  1. Radiative lifetimes in B I using ultraviolet and vacuum-ultraviolet laser-induced fluorescence

    NASA Technical Reports Server (NTRS)

    O'Brian, T. R.; Lawler, J. E.

    1992-01-01

    Radiative lifetimes of the eight lowest even parity levels in the doublet system of B I are measured using time-resolved laser-induced fluorescence in the UV and VUV on an atomic beam of boron. The accurate lifetimes provide a base for improved determination of absolute transition probabilities in B I. The techniques described are broadly applicable to measurement of lifetimes of levels with transitions in the visible, UV, and VUV in almost any element.

  2. Interaction of nanosecond ultraviolet laser pulses with reactive dusty plasma

    NASA Astrophysics Data System (ADS)

    van de Wetering, F. M. J. H.; Oosterbeek, W.; Beckers, J.; Nijdam, S.; Gibert, T.; Mikikian, M.; Rabat, H.; Kovačević, E.; Berndt, J.

    2016-05-01

    Even though UV laser pulses that irradiate a gas discharge are small compared to the plasma volume (≲3%) and plasma-on time (≲6 × 10-6%), they are found to dramatically change the discharge characteristics on a global scale. The reactive argon-acetylene plasma allows the growth of nanoparticles with diameters up to 1 μm, which are formed inside the discharge volume due to spontaneous polymerization reactions. It is found that the laser pulses predominantly accelerate and enhance the coagulation phase and are able to suppress the formation of a dust void.

  3. New solid state lasers from the ultraviolet to the mid-infrared

    SciTech Connect

    Payne, S.A.; Krupke, W.F.; Beach, R.J.

    1995-08-15

    The authors discuss three new laser materials that offer improved access to the ultraviolet, near infrared and mid-infrared spectral regions. In order for each of these materials to have been identified, a particular hurdle needed to be overcome with respect to the fundamental laser physics impacting the material. In the case of the 280-320nm Ce:LiSAF laser, the main issue is the need to reduce the loss associated with excited state absorption, while for 1047nm Yb:S-FAP it is the ground state absorption at the laser wavelength that must be minimized. Cr:ZnSe has been down-selected from a number of potential candidates which could lase in the 2200-3000nm region, in order to mitigate the detrimental impact of nonradiative decay. In all three cases the authors discuss how appropriate consideration of fundamental concerns has led to the identification and understanding of the new laser system.

  4. Solid-State Laser Source of Tunable Narrow-Bandwidth Ultraviolet Radiation

    NASA Technical Reports Server (NTRS)

    Goldberg, Lew; Kliner, Dahv A.; Koplow, Jeffrey P.

    1998-01-01

    A solid-state laser source of tunable and narrow-bandwidth UV light is disclosed. The system relies on light from a diode laser that preferably generates light at infrared frequencies. The light from the seed diode laser is pulse amplified in a light amplifier, and converted into the ultraviolet by frequency tripling, quadrupling, or quintupling the infrared light. The narrow bandwidth, or relatively pure light, of the seed laser is preserved, and the pulse amplifier generates high peak light powers to increase the efficiency of the nonlinear crystals in the frequency conversion stage. Higher output powers may be obtained by adding a fiber amplifier to power amplify the pulsed laser light prior to conversion.

  5. Laser triggered Z-pinch broadband extreme ultraviolet source for metrology

    SciTech Connect

    Tobin, I.; Lunney, J. G.; Juschkin, L.; Sidelnikov, Y.; O'Reilly, F.; Sokell, E.; Sheridan, P.

    2013-05-20

    We compare the extreme ultraviolet emission characteristics of tin and galinstan (atomic %: Ga: 78.35, In: 14.93, Sn: 6.72) between 10 nm and 18 nm in a laser-triggered discharge between liquid metal-coated electrodes. Over this wavelength range, the energy conversion efficiency for galinstan is approximately half that of tin, but the spectrum is less strongly peaked in the 13-15 nm region. The extreme ultraviolet source dimensions were 110 {+-} 25 {mu}m diameter and 500 {+-} 125 {mu}m length. The flatter spectrum, and -19 Degree-Sign C melting point, makes this galinstan discharge a relatively simple high radiance extreme ultraviolet light source for metrology and scientific applications.

  6. The development of a tunable, single-frequency ultraviolet laser source for UV filtered Rayleigh scattering

    NASA Technical Reports Server (NTRS)

    Finkelstein, N.; Gambogi, J.; Lempert, Walter R.; Miles, Richard B.; Rines, G. A.; Finch, A.; Schwarz, R. A.

    1995-01-01

    We present the development of a flexible, high power, narrow line width, tunable ultraviolet source for diagnostic application. By frequency tripling the output of a pulsed titanium-sapphire laser, we achieve broadly tunable (227-360 nm) ultraviolet light with high quality spatial and spectral resolution. We also present the characterization of a mercury vapor cell which provides a narrow band, sharp edge absorption filter at 253.7 nm. These two components form the basis for the extension of the Filtered Rayleigh Scattering technique into the ultraviolet. The UV-FRS system is comprised of four pieces: a single frequency, cw tunable Ti:Sapphire seeding source; a high-powered pulsed Ti:Sapphire oscillator; a third harmonic generator system; and an atomic mercury vapor filter. In this paper we discuss the development and characterization of each of these elements.

  7. Ultralow-threshold electrically injected AlGaN nanowire ultraviolet lasers on Si operating at low temperature.

    PubMed

    Li, K H; Liu, X; Wang, Q; Zhao, S; Mi, Z

    2015-02-01

    Ultraviolet laser radiation has been adopted in a wide range of applications as diverse as water purification, flexible displays, data storage, sterilization, diagnosis and bioagent detection. Success in developing semiconductor-based, compact ultraviolet laser sources, however, has been extremely limited. Here, we report that defect-free disordered AlGaN core-shell nanowire arrays, formed directly on a Si substrate, can be used to achieve highly stable, electrically pumped lasers across the entire ultraviolet AII (UV-AII) band (∼320-340 nm) at low temperatures. The laser threshold is in the range of tens of amps per centimetre squared, which is nearly three orders of magnitude lower than those of previously reported quantum-well lasers. This work also reports the first demonstration of electrically injected AlGaN-based ultraviolet lasers monolithically grown on a Si substrate, and offers a new avenue for achieving semiconductor lasers in the ultraviolet B (UV-B) (280-320 nm) and ultraviolet C (UV-C) (<280 nm) bands. PMID:25599190

  8. Ultralow-threshold electrically injected AlGaN nanowire ultraviolet lasers on Si operating at low temperature

    NASA Astrophysics Data System (ADS)

    Li, K. H.; Liu, X.; Wang, Q.; Zhao, S.; Mi, Z.

    2015-02-01

    Ultraviolet laser radiation has been adopted in a wide range of applications as diverse as water purification, flexible displays, data storage, sterilization, diagnosis and bioagent detection. Success in developing semiconductor-based, compact ultraviolet laser sources, however, has been extremely limited. Here, we report that defect-free disordered AlGaN core-shell nanowire arrays, formed directly on a Si substrate, can be used to achieve highly stable, electrically pumped lasers across the entire ultraviolet AII (UV-AII) band (˜320-340 nm) at low temperatures. The laser threshold is in the range of tens of amps per centimetre squared, which is nearly three orders of magnitude lower than those of previously reported quantum-well lasers. This work also reports the first demonstration of electrically injected AlGaN-based ultraviolet lasers monolithically grown on a Si substrate, and offers a new avenue for achieving semiconductor lasers in the ultraviolet B (UV-B) (280-320 nm) and ultraviolet C (UV-C) (<280 nm) bands.

  9. Influence of laser pulse duration on extreme ultraviolet and ion emission features from tin plasmas

    SciTech Connect

    Roy, A. E-mail: aroy@barc.gov.in; Harilal, S. S.; Polek, M. P.; Hassan, S. M.; Hassanein, A.; Endo, A.

    2014-03-15

    We investigated the role of laser pulse duration and intensity on extreme ultraviolet (EUV) generation and ion emission from a laser produced Sn plasma. For producing plasmas, planar slabs of pure Sn were irradiated with 1064 nm Nd:YAG laser pulses with varying pulse duration (5–20 ns) and intensity. Experimental results performed at CMUXE indicate that the conversion efficiency (CE) of the EUV radiation strongly depend on laser pulse width and intensity, with a maximum CE of ∼2.0% measured for the shortest laser pulse width used (5 ns). Faraday Cup ion analysis of Sn plasma showed that the ion flux kinetic profiles are shifted to higher energy side with the reduction in laser pulse duration and narrower ion kinetic profiles are obtained for the longest pulse width used. However, our initial results showed that at a constant laser energy, the ion flux is more or less constant regardless of the excitation laser pulse width. The enhanced EUV emission obtained at shortest laser pulse duration studied is related to efficient laser-plasma reheating supported by presence of higher energy ions at these pulse durations.

  10. Alterations of platelet aggregation kinetics with ultraviolet laser emission: the "stunned platelet" phenomenon.

    PubMed

    Topaz, O; Minisi, A J; Bernardo, N L; McPherson, R A; Martin, E; Carr, S L; Carr, M E

    2001-10-01

    Platelets, a major constituent of thrombus, play a crucial role in the pathogenesis of acute ischemic coronary syndromes. The effect of ultraviolet laser emission on platelets within thrombi is unknown. The effects of increasing levels of laser energy on platelets in whole blood were investigated. Blood samples were obtained by aseptic venipuncture and anticoagulated with 3.8% sodium citrate. Samples were exposed to increased levels (0, 30, 45, 60 mJ/mm2; 25 Hz) of ultraviolet excimer laser fluence (308 nm wave-length) and then tested for ADP and collagen induced platelet aggregation, platelet concentration, and for platelet contractile force (PCF) development. Scanning electron microscopy was used to detect laser induced morphologic changes of platelets and by flow cytometric analysis to detect changes in expression of platelet surface antigens p-selectin (CD 62) and glycoprotein IIb/IIIa (CD 43). Exposure to excimer laser energy produced dose dependent suppression of platelet aggregation and force development ("stunned platelets"). ADP aggregation decreased from 8.0+/-1.1 Ohms (mean+/-SEM) to 3.7+/-0.8 Ohms (p<0.001) to 2.7+/-0.6 Ohms (p <0.001) and to 1.8+/-0.5 Ohms (p <0.001) as the laser energy increased from 0 to 30 to 45 to 60 mJ/mm2, respectively. Collagen induced aggregation decreased from 21.4+/-1.4 Ohms to 15.7+/-1.2 Ohms (p <0.001) to 11.7+/-1.1 Ohms (p <0.001) and to 9.9+/-1.0 Ohms (p <0.001), in response to the same incremental range of laser energy. Platelet contractile forces declined from 34,500+/-3700 to 27.800+/-2700 dynes as laser energy increased from 0 to 60 mJ/mm2 (p <0.03). Platelet concentration did not change with increasing laser energy. The expression of platelet surface antigen p-selectin (CD 62) remained stable through increasing levels of laser energy exposures while the percentage of CD 43 positive platelets significantly increased with exposure to laser energy, yet the level of expression did not exceed 0.5% of cells. Thus

  11. Bombyx mori silk protein films microprocessing with a nanosecond ultraviolet laser and a femtosecond laser workstation: theory and experiments

    NASA Astrophysics Data System (ADS)

    Lazare, S.; Sionkowska, A.; Zaborowicz, M.; Planecka, A.; Lopez, J.; Dijoux, M.; Louména, C.; Hernandez, M.-C.

    2012-01-01

    Laser microprocessing of several biopolymers from renewable resources is studied. Three proteinic materials were either extracted from the extracellular matrix like Silk Fibroin/Sericin and collagen, or coming from a commercial source like gelatin. All can find future applications in biomedical experimentation, in particular for cell scaffolding. Films of ˜hundred of microns thick were made by aqueous solution drying and laser irradiation. Attention is paid to the properties making them processable with two laser sources: the ultraviolet and nanosecond (ns) KrF (248 nm) excimer and the infrared and femtosecond (fs) Yb:KGW laser. The UV radiation is absorbed in a one-photon resonant process to yield ablation and the surface foaming characteristics of a laser-induced pressure wave. To the contrary, resonant absorption of the IR photons of the fs laser is not possible and does not take place. However, the high field of the intense I>˜1012 W/cm2 femtosecond laser pulse ionizes the film by the multiphoton absorption followed by the electron impact mechanism, yielding a dense plasma capable to further absorb the incident radiation of the end of the pulse. The theoretical model of this absorption is described in detail, and used to discuss the presented experimental effects (cutting, ablation and foaming) of the fs laser. The ultraviolet laser was used to perform simultaneous multiple spots experiments in which energetic foaming yields melt ejection and filament spinning. Airborne nanosize filaments "horizontally suspended by both ends" (0.25 μm diameter and 10 μm length) of silk biopolymer were observed upon irradiation with large fluences.

  12. Passive intrinsic-linewidth narrowing of ultraviolet extended-cavity diode laser by weak optical feedback.

    PubMed

    Samutpraphoot, Polnop; Weber, Sophie; Lin, Qian; Gangloff, Dorian; Bylinskii, Alexei; Braverman, Boris; Kawasaki, Akio; Raab, Christoph; Kaenders, Wilhelm; Vuletić, Vladan

    2014-05-19

    We present a simple method for narrowing the intrinsic Lorentzian linewidth of a commercial ultraviolet grating extended-cavity diode laser (TOPTICA DL Pro) using weak optical feedback from a long external cavity. We achieve a suppression in frequency noise spectral density of 20 dB measured at frequencies around 1 MHz, corresponding to the narrowing of the intrinsic Lorentzian linewidth from 200 kHz to 2 kHz. Provided additional active low-frequency noise suppression and long-term drift compensation, the system is suitable for experiments requiring a tunable ultraviolet laser with narrow linewidth and low high-frequency noise, such as precision spectroscopy, optical clocks, and quantum information science experiments. PMID:24921280

  13. Investigations into ultraviolet matrix-assisted laser desorption

    SciTech Connect

    Heise, T.W.

    1993-07-01

    Matrix-assisted laser desorption (MALD) is a technique for converting large biomolecules into gas phase ions. Some characteristics of the commonly used uv matrices are determined. Solubilities in methanol range from 0.1 to 0.5 M. Solid phase absorption spectra are found to be similar to solution, but slightly red-shifted. Acoustic and quartz crystal microbalance signals are investigated as possible means of uv-MALD quantitation. Evidence for the existence of desorption thresholds is presented. Threshold values are determined to be in the range of 2 to 3 MW/cm{sup 2}. A transient imaging technique based on laser-excited fluorescence for monitoring MALD plumes is described. Sensitivity is well within the levels required for studying matrix-assisted laser desorption, where analyte concentrations are significantly lower than those in conventional laser desorption. Results showing the effect of film morphology, particularly film thickness, on plume dynamics are presented. In particular, MALD plumes from thicker films tend to exhibit higher axial velocities. Fluorescent labeling of protein and of DNA is used to allow imaging of their uv-MALD generated plumes. Integrated concentrations are available with respect to time, making it possible to assess the rate of fragmentation. The spatial and temporal distributions are important for the design of secondary ionization schemes to enhance ion yields and for the optimization of ion collection in time-of-flight MS instruments to maximize resolution. Such information could also provide insight into whether ionization is closely associated with the desorption step or whether it is a result of subsequent collisions with the matrix gas (e.g., proton transfer). Although the present study involves plumes in a normal atmosphere, adaptation to measurements in vacuum (e.g., inside a mass spectrometer) should be straightforward.

  14. The Laser-assisted photoelectric effect of He, Ne, Ar and Xe in intense extreme ultraviolet and infrared laser fields

    NASA Astrophysics Data System (ADS)

    Hayden, P.; Dardis, J.; Hough, P.; Richardson, V.; Kennedy, E. T.; Costello, J. T.; Düsterer, S.; Redlin, H.; Feldhaus, J.; Li, W. B.; Cubaynes, D.; Meyer, M.

    2016-02-01

    In this paper, we report results on two-colour above-threshold ionisation, where extreme ultraviolet pulses of femtosecond duration were synchronised to intense infrared laser pulses of picosecond duration, in order to study the laser-assisted photoelectric effect of atomic helium, neon, krypton and xenon which leads to the appearance of characteristic sidebands in the photoelectron spectra. The observed trends are found to be well described by a simple model based on the soft-photon approximation, at least for the relatively low optical intensities of up to ? employed in these early experiments.

  15. Laser-induced two-photon blackbody radiation in the vacuum ultraviolet

    NASA Technical Reports Server (NTRS)

    Zych, L. J.; Young, J. F.; Harris, S. E.; Lukasik, J.

    1978-01-01

    Experimental measurements of a new type of vacuum-ultraviolet radiation source are reported. It is shown that the maximum source brightness, within its narrow linewidth, is that of a blackbody at the temperature of a metastable storage level. The laser-induced emission at 569 A from a He glow discharge corresponded to a metastable temperature of 22,700 K and was over 100 times brighter than the 584-A He resonance line.

  16. Cooperative effect of ultraviolet and near-infrared beams in laser-induced condensation

    SciTech Connect

    Matthews, M.; Henin, S.; Pomel, F.; Kasparian, J.; Wolf, J.-P.; Théberge, F.; Daigle, J.-F.; Lassonde, P.; Kieffer, J.-C.

    2013-12-23

    We demonstrate the cooperative effect of near infrared (NIR) and ultraviolet (UV) beams on laser-induced condensation. Launching a UV laser after a NIR pulse yields up to a 5-fold increase in the production of nanoparticles (25–300 nm) as compared to a single NIR beam. This cooperative effect exceeds the sum of those from the individual beams and occurs for delays up to 1 μs. We attribute it to the UV photolysis of ozone created by the NIR pulses. The resulting OH radicals oxidize NO{sub 2} and volatile organic compounds, producing condensable species.

  17. Invited Article: Progress in coherent lithography using table-top extreme ultraviolet lasers

    NASA Astrophysics Data System (ADS)

    Li, W.; Urbanski, L.; Marconi, M. C.

    2015-12-01

    Compact (table top) lasers emitting at wavelengths below 50 nm had expanded the spectrum of applications in the extreme ultraviolet (EUV). Among them, the high-flux, highly coherent laser sources enabled lithographic approaches with distinctive characteristics. In this review, we will describe the implementation of a compact EUV lithography system capable of printing features with sub-50 nm resolution using Talbot imaging. This compact system is capable of producing consistent defect-free samples in a reliable and effective manner. Examples of different patterns and structures fabricated with this method will be presented.

  18. Invited Article: Progress in coherent lithography using table-top extreme ultraviolet lasers.

    PubMed

    Li, W; Urbanski, L; Marconi, M C

    2015-12-01

    Compact (table top) lasers emitting at wavelengths below 50 nm had expanded the spectrum of applications in the extreme ultraviolet (EUV). Among them, the high-flux, highly coherent laser sources enabled lithographic approaches with distinctive characteristics. In this review, we will describe the implementation of a compact EUV lithography system capable of printing features with sub-50 nm resolution using Talbot imaging. This compact system is capable of producing consistent defect-free samples in a reliable and effective manner. Examples of different patterns and structures fabricated with this method will be presented. PMID:26723999

  19. Evolution of laser-produced Sn extreme ultraviolet source diameter for high-brightness source

    SciTech Connect

    Roy, Amitava E-mail: aroy@barc.gov.in; Arai, Goki; Hara, Hiroyuki; Higashiguchi, Takeshi; Ohashi, Hayato; Sunahara, Atsushi; Li, Bowen; Dunne, Padraig; O'Sullivan, Gerry; Miura, Taisuke; Mocek, Tomas; Endo, Akira

    2014-08-18

    We have investigated the effect of irradiation of solid Sn targets with laser pulses of sub-ns duration and sub-mJ energy on the diameter of the extreme ultraviolet (EUV) emitting region and source conversion efficiency. It was found that an in-band EUV source diameter as low as 18 μm was produced due to the short scale length of a plasma produced by a sub-ns laser. Most of the EUV emission occurs in a narrow region with a plasma density close to the critical density value. Such EUV sources are suitable for high brightness and high repetition rate metrology applications.

  20. Optimizing laser produced plasmas for efficient extreme ultraviolet and soft X-ray light sources

    SciTech Connect

    Sizyuk, Tatyana; Hassanein, Ahmed

    2014-08-15

    Photon sources produced by laser beams with moderate laser intensities, up to 10{sup 14 }W/cm{sup 2}, are being developed for many industrial applications. The performance requirements for high volume manufacture devices necessitate extensive experimental research supported by theoretical plasma analysis and modeling predictions. We simulated laser produced plasma sources currently being developed for several applications such as extreme ultraviolet lithography using 13.5% ± 1% nm bandwidth, possibly beyond extreme ultraviolet lithography using 6.× nm wavelengths, and water-window microscopy utilizing 2.48 nm (La-α) and 2.88 nm (He-α) emission. We comprehensively modeled plasma evolution from solid/liquid tin, gadolinium, and nitrogen targets as three promising materials for the above described sources, respectively. Results of our analysis for plasma characteristics during the entire course of plasma evolution showed the dependence of source conversion efficiency (CE), i.e., laser energy to photons at the desired wavelength, on plasma electron density gradient. Our results showed that utilizing laser intensities which produce hotter plasma than the optimum emission temperatures allows increasing CE for all considered sources that, however, restricted by the reabsorption processes around the main emission region and this restriction is especially actual for the 6.× nm sources.

  1. Particle generation by ultraviolet-laser ablation during surface decontamination.

    PubMed

    Lee, Doh-Won; Cheng, Meng-Dawn

    2006-11-01

    A novel photonic decontamination method was developed for removal of pollutants from material surfaces. Such a method relies on the ability of a high-energy laser beam to ablate materials from a contaminated surface layer, thus producing airborne particles. In this paper, the authors presented the results obtained using a scanning mobility particle sizer (SMPS) system and an aerosol particle sizer (APS). Particles generated by laser ablation from the surfaces of cement, chromium-embedded cement, and alumina were experimentally investigated. Broad particle distributions from nanometer to micrometer in size were measured. For stainless steel, virtually no particle > 500 nm in aerodynamic size was detected. The generated particle number concentrations of all three of the materials were increased as the 266-nm laser fluence (millijoules per square centimeter) increased. Among the three materials tested, cement was found to be the most favorable for particle removal, alumina next, and stainless steel the least. Chromium (dropped in cement) showed almost no effects on particle production. For all of the materials tested except for stainless steel, bimodal size distributions were observed; a smaller mode peaked at approximately 50-70 nm was detected by SMPS and a larger mode (peaked at approximately 0.70-0.85 microm) by APS. Based on transmission electron microscopy observations, the authors concluded that particles in the range of 50-70 nm were aggregates of primary particles, and those of size larger than a few hundred nanometers were produced by different mechanisms, for example, massive object ejection from the material surfaces. PMID:17117745

  2. Erosion resistant nozzles for laser plasma extreme ultraviolet (EUV) sources

    DOEpatents

    Kubiak, Glenn D.; Bernardez, II, Luis J.

    2000-01-04

    A gas nozzle having an increased resistance to erosion from energetic plasma particles generated by laser plasma sources. By reducing the area of the plasma-facing portion of the nozzle below a critical dimension and fabricating the nozzle from a material that has a high EUV transmission as well as a low sputtering coefficient such as Be, C, or Si, it has been shown that a significant reduction in reflectance loss of nearby optical components can be achieved even after exposing the nozzle to at least 10.sup.7 Xe plasma pulses.

  3. Low-level red laser therapy alters effects of ultraviolet C radiation on Escherichia coli cells.

    PubMed

    Canuto, K S; Sergio, L P S; Guimarães, O R; Geller, M; Paoli, F; Fonseca, A S

    2015-10-01

    Low-level lasers are used at low power densities and doses according to clinical protocols supplied with laser devices or based on professional practice. Although use of these lasers is increasing in many countries, the molecular mechanisms involved in effects of low-level lasers, mainly on DNA, are controversial. In this study, we evaluated the effects of low-level red lasers on survival, filamentation, and morphology of Escherichia colicells that were exposed to ultraviolet C (UVC) radiation. Exponential and stationary wild-type and uvrA-deficientE. coli cells were exposed to a low-level red laser and in sequence to UVC radiation. Bacterial survival was evaluated to determine the laser protection factor (ratio between the number of viable cells after exposure to the red laser and UVC and the number of viable cells after exposure to UVC). Bacterial filaments were counted to obtain the percentage of filamentation. Area-perimeter ratios were calculated for evaluation of cellular morphology. Experiments were carried out in duplicate and the results are reported as the means of three independent assays. Pre-exposure to a red laser protected wild-type and uvrA-deficient E. coli cells against the lethal effect of UVC radiation, and increased the percentage of filamentation and the area-perimeter ratio, depending on UVC fluence and physiological conditions in the cells. Therapeutic, low-level red laser radiation can induce DNA lesions at a sub-lethal level. Consequences to cells and tissues should be considered when clinical protocols based on this laser are carried out. PMID:26445338

  4. Low-level red laser therapy alters effects of ultraviolet C radiation on Escherichia coli cells

    PubMed Central

    Canuto, K.S.; Sergio, L.P.S.; Guimarães, O.R.; Geller, M.; Paoli, F.; Fonseca, A.S.

    2015-01-01

    Low-level lasers are used at low power densities and doses according to clinical protocols supplied with laser devices or based on professional practice. Although use of these lasers is increasing in many countries, the molecular mechanisms involved in effects of low-level lasers, mainly on DNA, are controversial. In this study, we evaluated the effects of low-level red lasers on survival, filamentation, and morphology of Escherichia colicells that were exposed to ultraviolet C (UVC) radiation. Exponential and stationary wild-type and uvrA-deficientE. coli cells were exposed to a low-level red laser and in sequence to UVC radiation. Bacterial survival was evaluated to determine the laser protection factor (ratio between the number of viable cells after exposure to the red laser and UVC and the number of viable cells after exposure to UVC). Bacterial filaments were counted to obtain the percentage of filamentation. Area-perimeter ratios were calculated for evaluation of cellular morphology. Experiments were carried out in duplicate and the results are reported as the means of three independent assays. Pre-exposure to a red laser protected wild-type and uvrA-deficient E. coli cells against the lethal effect of UVC radiation, and increased the percentage of filamentation and the area-perimeter ratio, depending on UVC fluence and physiological conditions in the cells. Therapeutic, low-level red laser radiation can induce DNA lesions at a sub-lethal level. Consequences to cells and tissues should be considered when clinical protocols based on this laser are carried out. PMID:26445338

  5. The thermodynamic response of soft biological tissues to pulsed ultraviolet laser irradiation.

    PubMed Central

    Venugopalan, V; Nishioka, N S; Mikić, B B

    1995-01-01

    The physical mechanisms that enable short pulses of high-intensity ultraviolet laser radiation to remove tissue, in a process known as laser ablation, remain obscure. The thermodynamic response of biological tissue to pulsed laser irradiation was investigated by measuring and subsequently analyzing the stress transients generated by pulsed argon fluorine (ArF, lambda = 193 nm) and krypton fluorine (KrF, lambda = 248 nm) excimer laser irradiation of porcine dermis using thin-film piezoelectric transducers. For radiant exposures that do not cause material removal, the stress transients are consistent with rapid thermal expansion of the tissue. At the threshold radiant exposure for ablation, the peak stress amplitude generated by 248 nm irradiation is more than an order of magnitude larger than that produced by 193 nm irradiation. For radiant exposures where material removal is achieved, the temporal structure of the stress transient indicates that the onset of material removal occurs during irradiation. In this regime, the variation of the peak compressive stress with radiant exposure is consistent with laser-induced rapid surface vaporization. For 193 nm irradiation, ionization of the ablated material occurs at even greater radiant exposures and is accompanied by a change in the variation of peak stress with radiant exposure consistent with a plasma-mediated ablation process. These results suggest that absorption of ultraviolet laser radiation by the extracellular matrix of tissue leads to decomposition of tissue on the time scale of the laser pulse. The difference in volumetric energy density at ablation threshold between the two wavelengths indicates that the larger stresses generated by 248 nm irradiation may facilitate the onset of material removal. However, once material removal is achieved, the stress measurements demonstrate that energy not directly responsible for target decomposition contributes to increasing the specific energy of the plume (and plasma

  6. Complementary ion and extreme ultra-violet spectrometer for laser-plasma diagnosis

    SciTech Connect

    Ter-Avetisyan, S.; Ramakrishna, B.; Doria, D.; Sarri, G.; Zepf, M.; Borghesi, M.; Ehrentraut, L.; Stiel, H.; Steinke, S.; Schnuerer, M.; Nickles, P. V.; Sandner, W.; Priebe, G.

    2009-10-15

    Simultaneous detection of extreme ultra-violet (XUV) and ion emission along the same line of sight provides comprehensive insight into the evolution of plasmas. This type of combined spectroscopy is applied to diagnose laser interaction with a spray target. The use of a micro-channel-plate detector assures reliable detection of both XUV and ion signals in a single laser shot. The qualitative analysis of the ion emission and XUV spectra allows to gain detailed information about the plasma conditions, and a correlation between the energetic proton emission and the XUV plasma emission can be suggested. The measured XUV emission spectrum from water spray shows efficient deceleration of laser accelerated electrons with energies up to keV in the initially cold background plasma and the collisional heating of the plasma.

  7. Structural modifications in fused silica induced by ultraviolet fs laser filaments

    NASA Astrophysics Data System (ADS)

    Zergioti, I.; Kyrkis, K. D.; Papazoglou, D. G.; Tzortzakis, S.

    2007-07-01

    It is shown that the tight focusing of short ultraviolet laser pulses (248 nm, 450 fs) in the bulk of high bandgap transparent solids (fused silica) can result in structural modifications in the material. These can vary from small changes of the refractive index to birefringence, cracks and voids. This restructuring of the medium is due to the high laser intensities attained, and the plasma that is generated through multi-photon processes. The restructuring comes in the form of a string, which is the result of the nonlinear propagation of the laser beam in the medium as a self-trapped filament. We resume the conditions for the generation of the different types of modifications and comment on the temporal evolution and the role of the plasma strings at the trail of the light filaments.

  8. Sub-picosecond ultraviolet laser filamentation-induced bulk modifications in fused silica

    NASA Astrophysics Data System (ADS)

    Papazoglou, D. G.; Zergioti, I.; Tzortzakis, S.; Sgouros, G.; Maravelias, G.; Christopoulos, S.; Fotakis, C.

    2005-07-01

    We present experiments with sub-picosecond ultraviolet laser pulses (248 nm, 450 fs) tightly focused in the bulk of fused-silica samples. The high laser intensities attained generate plasma through multi-photon absorption and electron avalanche processes in the bulk of the material. Depending on the initial experimental conditions three distinct types of structural changes in the material are observed, from small changes of the refractive index to birefringence, and even cracks and voids. We also observe the creation of micro-channels, up to 115 μm in length, inside the material due to self-guiding and filamentation of the laser pulses in the transparent material. The selective change of the refractive index is a promising method for the fabrication of photonic structures such as waveguides and three-dimensional integrated optical devices.

  9. Tunable vacuum ultraviolet laser based spectrometer for angle resolved photoemission spectroscopy

    SciTech Connect

    Jiang, Rui; Mou, Daixiang; Wu, Yun; Huang, Lunan; Kaminski, Adam; McMillen, Colin D.; Kolis, Joseph; Giesber, Henry G.; Egan, John J.

    2014-03-15

    We have developed an angle-resolved photoemission spectrometer with tunable vacuum ultraviolet laser as a photon source. The photon source is based on the fourth harmonic generation of a near IR beam from a Ti:sapphire laser pumped by a CW green laser and tunable between 5.3 eV and 7 eV. The most important part of the set-up is a compact, vacuum enclosed fourth harmonic generator based on potassium beryllium fluoroborate crystals, grown hydrothermally in the US. This source can deliver a photon flux of over 10{sup 14} photon/s. We demonstrate that this energy range is sufficient to measure the k{sub z} dispersion in an iron arsenic high temperature superconductor, which was previously only possible at synchrotron facilities.

  10. High-intensity coherent vacuum ultraviolet source using unfocussed commercial dye lasers

    NASA Astrophysics Data System (ADS)

    Albert, Daniel R.; Proctor, David L.; Floyd Davis, H.

    2013-06-01

    Using two or three commercial pulsed nanosecond dye lasers pumped by a single 30 Hz Nd:YAG laser, generation of 0.10 mJ pulses at 125 nm (6 × 1013 photons/pulse) has been demonstrated by resonance enhanced four-wave mixing of collimated (unfocussed) laser beams in mercury (Hg) vapor. Phase matching at various vacuum ultraviolet (VUV) wavelengths is achieved by tuning one laser in the vicinity of the 6 1S0 → 6 3P1 resonance near 253.1 nm. A number of different mixing schemes are characterized. Our observations using broadband lasers (˜0.15 cm-1 bandwidths) are compared to previous calculations pertaining to four-wave mixing of low intensity narrowband laser beams. Prospects for further increases in pulse energies are discussed. We find that VUV tuning curves and intensities are in good agreement with theoretical predictions. The utility of the VUV light source is demonstrated by "soft universal" single-photon VUV ionization in crossed molecular beam studies and for generation of light at 130.2 nm for oxygen atom Rydberg time-of-flight experiments.

  11. Laser Desorption Postionization Mass Spectrometry of Antibiotic-Treated Bacterial Biofilms using Tunable Vacuum Ultraviolet Radiation

    SciTech Connect

    Gasper, Gerald L; Takahashi, Lynelle K; Zhou, Jia; Ahmed, Musahid; Moore, Jerry F; Hanley, Luke

    2010-08-04

    Laser desorption postionization mass spectrometry (LDPI-MS) with 8.0 ? 12.5 eV vacuum ultraviolet synchrotron radiation is used to single photon ionize antibiotics andextracellular neutrals that are laser desorbed both neat and from intact bacterial biofilms. Neat antibiotics are optimally detected using 10.5 eV LDPI-MS, but can be ionized using 8.0 eV radiation, in agreement with prior work using 7.87 eV LDPI-MS. Tunable vacuum ultraviolet radiation also postionizes laser desorbed neutrals of antibiotics and extracellular material from within intact bacterial biofilms. Different extracellular material is observed by LDPI-MS in response to rifampicin or trimethoprim antibiotic treatment. Once again, 10.5 eV LDPI-MS displays the optimum trade-off between improved sensitivity and minimum fragmentation. Higher energy photons at 12.5 eV produce significant parent ion signal, but fragment intensity and other low mass ions are also enhanced. No matrix is added to enhance desorption, which is performed at peak power densities insufficient to directly produce ions, thus allowing observation of true VUV postionization mass spectra of antibiotic treated biofilms.

  12. Laser Desorption Postionization Mass Spectrometry of Antibiotic-Treated Bacterial Biofilms using Tunable Vacuum Ultraviolet Radiation

    PubMed Central

    Gasper, Gerald L.; Takahashi, Lynelle K.; Zhou, Jia; Ahmed, Musahid; Moore, Jerry F.; Hanley, Luke

    2010-01-01

    Laser desorption postionization mass spectrometry (LDPI-MS) with 8.0 – 12.5 eV vacuum ultraviolet synchrotron radiation is used to single photon ionize antibiotics and extracellular neutrals that are laser desorbed both neat and from intact bacterial biofilms. Neat antibiotics are optimally detected using 10.5 eV LDPI-MS, but can be ionized using 8.0 eV radiation, in agreement with prior work using 7.87 eV LDPI-MS. Tunable vacuum ultraviolet radiation also postionizes laser desorbed neutrals of antibiotics and extracellular material from within intact bacterial biofilms. Different extracellular material is observed by LDPI-MS in response to rifampicin or trimethoprim antibiotic treatment. Once again, 10.5 eV LDPI-MS displays the optimum trade-off between improved sensitivity and minimum fragmentation. Higher energy photons at 12.5 eV produce significant parent ion signal, but fragment intensity and other low mass ions are also enhanced. No matrix is added to enhance desorption, which is performed at peak power densities insufficient to directly produce ions, thus allowing observation of true VUV postionization mass spectra of antibiotic treated biofilms. PMID:20712373

  13. Generation of intense attosecond x-ray pulses using ultraviolet laser induced microbunching in electron beams

    NASA Astrophysics Data System (ADS)

    Xiang, D.; Huang, Z.; Stupakov, G.

    2009-06-01

    We propose a scheme that combines the echo-enabled harmonic generation technique with the bunch compression and allows one to generate harmonic numbers of a few hundred in a microbunched beam through up-conversion of the frequency of an ultraviolet seed laser. A few-cycle intense laser is used to generate the required energy chirp in the beam for bunch compression and for selection of an attosecond x-ray pulse. Sending this beam through a short undulator results in an intense isolated attosecond x-ray pulse. Using a representative realistic set of parameters, we show that 1 nm x-ray pulse with peak power of a few hundred MW and duration as short as 20 attoseconds (FWHM) can be generated from a 200 nm ultraviolet seed laser. The proposed scheme may enable the study of electronic dynamics with a resolution beyond the atomic unit of time (˜24 attoseconds) and may open a new regime of ultrafast sciences.

  14. Single shot extreme ultraviolet laser imaging of nanostructures with wavelength resolution

    SciTech Connect

    Jones, Juanita; Brewer, Courtney A.; Brizuela, Fernando; Wachulak, Przemyslaw; Martz, Dale H.; Chao, Weilun; Anderson, Erik H.; Attwood, David T.; Vinogradov, Alexander V.; Artyukov, Igor A.; Ponomareko, Alexander G.; Kondratenko, Valeriy V.; Marconi, Mario C.; Rocca, Jorge J.; Menoni, Carmen S.

    2008-01-07

    We have demonstrated near-wavelength resolution microscopy in the extreme ultraviolet. Images of 50 nm diameter nanotubes were obtained with a single {approx}1 ns duration pulse from a desk-top size 46.9 nm laser. We measured the modulation transfer function of the microscope for three different numerical aperture zone plate objectives, demonstrating that 54 nm half-period structures can be resolved. The combination of near-wavelength spatial resolution and high temporal resolution opens myriad opportunities in imaging, such as the ability to directly investigate dynamics of nanoscale structures.

  15. Note: Enhancement of the extreme ultraviolet emission from a potassium plasma by dual laser irradiation

    SciTech Connect

    Higashiguchi, Takeshi Yamaguchi, Mami; Otsuka, Takamitsu; Nagata, Takeshi; Ohashi, Hayato; Li, Bowen; D’Arcy, Rebekah; Dunne, Padraig; O’Sullivan, Gerry

    2014-09-15

    Emission spectra from multiply charged potassium ions ranging from K{sup 3+} to K{sup 5+} have been obtained in the extreme ultraviolet (EUV) spectral region. A strong emission feature peaking around 38 nm, corresponding to a photon energy of 32.6 eV, is the dominant spectral feature at time-averaged electron temperatures in the range of 8−12 eV. The variation of this emission with laser intensity and the effects of pre-pulses on the relative conversion efficiency (CE) have been explored experimentally and indicate that an enhancement of about 30% in EUV CE is readily attainable.

  16. Molecular photoelectron momentum distributions by intense orthogonally polarized attosecond ultraviolet laser pulses

    NASA Astrophysics Data System (ADS)

    Yuan, Kai-Jun; Chelkowski, Szczepan; Bandrauk, André D.

    2015-10-01

    We study molecular photoelectron momentum distributions (MPMDs) of aligned H2+ by intense orthogonally polarized attosecond ultraviolet laser pulses. Photoionization is simulated by numerically solving corresponding three-dimensional time dependent Schrödinger equations with static nuclei. It is found that altering pulse phases ϕ varies the structure of MPMDs, which is attributed to the interference effect between orthogonal polarization ionizations. The phase ϕ dependent MPMDs are also a function of molecular alignment and pulse wavelengths. Altering the symmetry of initial electronic states offers the possibility of imaging molecular orbitals by orthogonal polarization attosecond MPMDs.

  17. Direct writing of ferroelectric domains on strontium barium niobate crystals using focused ultraviolet laser light

    SciTech Connect

    Boes, Andreas; Crasto, Tristan; Steigerwald, Hendrik; Mitchell, Arnan; Wade, Scott; Frohnhaus, Jakob; Soergel, Elisabeth

    2013-09-30

    We report ferroelectric domain inversion in strontium barium niobate (SBN) single crystals by irradiating the surface locally with a strongly focused ultraviolet (UV) laser beam. The generated domains are investigated using piezoresponse force microscopy. We propose a simple model that allows predicting the domain width as a function of the irradiation intensity, which indeed applies for both SBN and LiNbO{sub 3}. Evidently, though fundamentally different, the domain structure of both SBN and LiNbO{sub 3} can be engineered through similar UV irradiation.

  18. Application of MARS for modeling local nonlinear relationships in data on ultraviolet copper ion lasers

    NASA Astrophysics Data System (ADS)

    Gocheva-Ilieva, Snezhana Georgieva; Voynikova, Desislava Stoyanova; Iliev, Iliycho Petkov

    2012-11-01

    When analyzing experiment data, the main statistical procedure is finding relationships in the data and developing models to describe them. Modeling is a powerful means of estimation, simulation, and prediction of the experiment and an indispensable tool in practical engineering. This paper considers the use of the multivariate adaptive regression splines (MARS) method to describe local relationships in the experiment data for several types of metal vapor lasers. The investigated data has been collected from patented UV ion lasers developed at the Bulgarian Academy of Sciences in the last ten years. A short description of MARS is provided. Specific MARS models have been developed describing the efficiency of an ultraviolet ion copper bromide vapor laser dependent on the change of 9 main input physical laser characteristics. The models are of linear and nonlinear type. It has been established that the best statistical indices and model fit are those of nonlinear models which contain second order local terms. The models account for about 95% of the data. The models are used to analyze the local behavior of the efficiency of various devices from the types of lasers under investigation. Graphs illustrating the established relationships are provided. The ability to predict future experiments is demonstrated.

  19. Studying Laser-Induced Spin Currents Using Ultrafast Extreme Ultraviolet Light

    NASA Astrophysics Data System (ADS)

    Turgut, Emrah

    Next-generation magnetic-memory devices and heat-assisted magnetic-recording applications will require a better understanding of magnetic multilayers and their interactions with optical-laser pulses. In this thesis, by combining the advantages of ultrabroad-band extreme-ultraviolet light including ultrafast time resolution, element selectivity and tabletop easy access, I report three findings in the study of ultrafast magnetization dynamics in itinerant ferromagnets. First, I experimentally prove that the transverse magneto-optical Kerr response with extreme-ultraviolet light has a purely magnetic origin and that our experimental technique is an artifact-free ultrafast magnetic probe. Second, I demonstrate the first ultrafast magnetization enhancement driven by ultrafast spin currents in Ni/Ru/Fe multilayers. Third, I engineer the sample system by choosing either insulating or spin-scattering spacer layers between the Ni and Fe magnetic layers and by structural ordering. Then, I control the competition between ultrafast spin-flip scattering and superdiffusive spin-current mechanisms; either of these processes may to be the dominant mechanism in ultrafast demagnetization. Finally, I report two continuing experiments that are promising for future ultrafast magnetization studies with extreme-ultraviolet sources. These experiments are resonant-magnetic small-angle-scattering and the generation of bright circularly polarized high harmonics accompanied by a demonstration of the first x-ray magnetic circular dichroism with a tabletop system.

  20. Two-laser infrared and ultraviolet matrix-assisted laser desorption/ionization.

    PubMed

    Little, Mark W; Kim, Jae-Kuk; Murray, Kermit K

    2003-07-01

    Matrix-assisted laser desorption/ionization (MALDI) was performed using two pulsed lasers with wavelengths in the IR and UV regions. A 10.6 micro m pulsed CO(2) laser was used to irradiate a MALDI target, followed after an adjustable delay by a 337 nm pulsed nitrogen laser. The sample consisted of a 2,5-dihydroxybenzoic acid matrix and bovine insulin guest molecule. The pulse energy for both of the lasers was adjusted so that the ion of interest, either the matrix or guest ion, was not produced by either of the lasers alone. The delay time for maximum ion yield occurs at 1 micro s for matrix and guest ions and the signal decayed to zero in approximately 400 micro s. A mechanism is presented for enhanced UV MALDI ion yield following the IR laser pulse based on transient heating. PMID:12898657

  1. Three-dimensional extreme ultraviolet emission from a droplet-based laser-produced plasma

    SciTech Connect

    Giovannini, A. Z.; Abhari, Reza S.

    2013-07-21

    The emission of extreme ultraviolet radiation in a 2% bandwidth centered at 13.5 nm (in-band) is measured in one hemisphere. The targets of the laser are tin droplets. In-band emission is measured at angles from the laser axis larger than 120 Degree-Sign . Analytical models representing the physical processes are developed and calibrated with the experimental data. In the models two assumptions are investigated, isentropic and isothermal 2D-axisymmetric expansion. The parameters of the models are the density distribution of the plasma and the location where the EUV emission is centered. The parameters are inferred by the calibration of the models with the experimental data. The predictions of the models are validated with experiments where slab targets were used.

  2. Evidence of partial temporal coherence effects in the linear autocorrelation of extreme ultraviolet laser pulses.

    PubMed

    Le Marec, Andréa; Guilbaud, Olivier; Larroche, Olivier; Klisnick, Annie

    2016-07-15

    We study how the degree of temporal coherence of plasma-based extreme ultraviolet lasers operated in the amplification of the spontaneous emission mode is encoded in the shape of the linear autocorrelation function, which is obtained from the variation of the fringe visibility while varying the delay in a variable path-difference interferometer. We discuss the implications of this effect when the technique is used to infer the spectral properties of the source. Our numerical simulations, based on a partial coherence model developed by other authors for x-ray free electron lasers, are in good agreement with previously reported sets of measurements, illustrating similar statistical properties for both sources. PMID:27420542

  3. Enhanced nonlinear double excitation of He in intense extreme ultraviolet laser fields.

    PubMed

    Hishikawa, A; Fushitani, M; Hikosaka, Y; Matsuda, A; Liu, C-N; Morishita, T; Shigemasa, E; Nagasono, M; Tono, K; Togashi, T; Ohashi, H; Kimura, H; Senba, Y; Yabashi, M; Ishikawa, T

    2011-12-01

    Nonlinear, three-photon double excitation of He in intense extreme ultraviolet free-electron laser fields (∼24.1  eV, ∼5  TW/cm2) is presented. Resonances to the doubly excited states converging to the He+ N=3 level are revealed by the shot-by-shot photoelectron spectroscopy and identified by theoretical calculations based on the time-dependent Schrödinger equation for the two-electron atom under a laser field. It is shown that the three-photon double excitation is enhanced by intermediate Rydberg states below the first ionization threshold, giving a greater contribution to the photoionization yields than the two-photon process by more than 1 order of magnitude. PMID:22242995

  4. The expansion velocities of laser-produced plasmas determined from extreme ultraviolet spectral line profiles

    NASA Technical Reports Server (NTRS)

    Feldman, U.; Doschek, G. A.; Behring, W. E.; Cohen, L.

    1977-01-01

    The expansion of laser-produced plasma is determined from the shapes of spectral lines of highly ionized iron emitted in the extreme ultraviolet. The plasmas were produced by focusing the pulse from a Nd:glass laser onto solid planar targets, and spectra were recorded with a high-resolution grazing-incidence spectrograph. From the Doppler broadening of lines of Fe XX and Fe XXI, expansion velocities of about 830 km/s were determined. The relative time-averaged ion abundances of Fe XVIII, Fe XIX, Fe XX, and Fe XXI are estimated for three different spectra. The abundances do not differ by more than a factor of 4 for any of the spectra.

  5. Cluster beam targets for laser plasma extreme ultraviolet and soft x-ray sources

    DOEpatents

    Kublak, G.D.; Richardson, M.C.

    1996-11-19

    Method and apparatus for producing extreme ultraviolet (EUV) and soft x-ray radiation from an ultra-low debris plasma source are disclosed. Targets are produced by the free jet expansion of various gases through a temperature controlled nozzle to form molecular clusters. These target clusters are subsequently irradiated with commercially available lasers of moderate intensity (10{sup 11}--10{sup 12} watts/cm{sup 2}) to produce a plasma radiating in the region of 0.5 to 100 nanometers. By appropriate adjustment of the experimental conditions the laser focus can be moved 10--30 mm from the nozzle thereby eliminating debris produced by plasma erosion of the nozzle. 5 figs.

  6. Three-dimensional nanoscale molecular imaging by extreme ultraviolet laser ablation mass spectrometry

    PubMed Central

    Kuznetsov, Ilya; Filevich, Jorge; Dong, Feng; Woolston, Mark; Chao, Weilun; Anderson, Erik H.; Bernstein, Elliot R.; Crick, Dean C.; Rocca, Jorge J.; Menoni, Carmen S.

    2015-01-01

    Analytical probes capable of mapping molecular composition at the nanoscale are of critical importance to materials research, biology and medicine. Mass spectral imaging makes it possible to visualize the spatial organization of multiple molecular components at a sample's surface. However, it is challenging for mass spectral imaging to map molecular composition in three dimensions (3D) with submicron resolution. Here we describe a mass spectral imaging method that exploits the high 3D localization of absorbed extreme ultraviolet laser light and its fundamentally distinct interaction with matter to determine molecular composition from a volume as small as 50 zl in a single laser shot. Molecular imaging with a lateral resolution of 75 nm and a depth resolution of 20 nm is demonstrated. These results open opportunities to visualize chemical composition and chemical changes in 3D at the nanoscale. PMID:25903827

  7. Electron temperature and average density in spherical laser-produced plasmas - Ultraviolet plasma spectroscopy

    NASA Technical Reports Server (NTRS)

    Goldsmith, S.; Seely, J. F.; Feldman, U.; Behring, W. E.; Cohen, L.

    1985-01-01

    The average values of the electron temperature Te and the electron density Ne in the corona plasmas of spherically irradiated high-Z targets have been estimated. Targets composed of the elements Cu through Br, Rb, and Mo were irradiated using the fundamental (1.06 microns) and the frequency-tripled (351 nm) output of the Omega laser system. Spectra were recorded in the wavelength region 15-200 A. Using various extreme ultraviolet spectroscopic techniques, it is found that for the case of a Mo plasma produced by frequency-tripled laser irradiation, Te = 2600 + or - 600 eV and Ne is greater than 6 x 10 to the 20th/cu cm. This is consistent with a 'flux limit' smaller than 0.1. The estimated values of Te and Ne are lower in the corona plasmas produced using the fundamental (1.06 micron) irradiation.

  8. Vacuum ultraviolet circularly polarized coherent femtosecond pulses from laser seeded relativistic electrons

    NASA Astrophysics Data System (ADS)

    Čutić, N.; Lindau, F.; Thorin, S.; Werin, S.; Bahrdt, J.; Eberhardt, W.; Holldack, K.; Erny, C.; L'Huillier, A.; Mansten, E.

    2011-03-01

    We have demonstrated the generation of circularly polarized coherent light pulses at 66 nm wavelength by combining laser seeding at 263 nm of a 375 MeV relativistic electron bunch with subsequent coherent harmonic generation from an elliptical undulator of APPLE-II type. Coherent pulses at higher harmonics in linear polarization have been produced and recorded up to the sixth order (44 nm). The duration of the generated pulses depends on the temporal overlap of the initial seed laser pulse and the electron bunch and was on the order of 200 fs. Currently, this setup is the only source worldwide producing coherent fs-light pulses with variable polarization in the vacuum ultraviolet.

  9. Breaking DNA strands by extreme-ultraviolet laser pulses in vacuum

    NASA Astrophysics Data System (ADS)

    Nováková, Eva; Vyšín, Luděk; Burian, Tomáš; Juha, Libor; Davídková, Marie; Múčka, Viliam; Čuba, Václav; Grisham, Michael E.; Heinbuch, Scott; Rocca, Jorge J.

    2015-04-01

    Ionizing radiation induces a variety of DNA damages including single-strand breaks (SSBs), double-strand breaks (DSBs), abasic sites, modified sugars, and bases. Most theoretical and experimental studies have been focused on DNA strand scissions, in particular production of DNA double-strand breaks. DSBs have been proven to be a key damage at a molecular level responsible for the formation of chromosomal aberrations, leading often to cell death. We have studied the nature of DNA damage induced directly by the pulsed 46.9-nm (26.5 eV) radiation provided by an extreme ultraviolet (XUV) capillary-discharge Ne-like Ar laser (CDL). Doses up to 45 kGy were delivered with a repetition rate of 3 Hz. We studied the dependence of the yield of SSBs and DSBs of a simple model of DNA molecule (pBR322) on the CDL pulse fluence. Agarose gel electrophoresis method was used for determination of both SSB and DSB yields. The action cross sections of the single- and double-strand breaks of pBR322 plasmid DNA in solid state were determined. We observed an increase in the efficiency of strand-break induction in the supercoiled DNA as a function of laser pulse fluence. Results are compared to those acquired at synchrotron radiation facilities and other sources of extreme-ultraviolet and soft x-ray radiation.

  10. Breaking DNA strands by extreme-ultraviolet laser pulses in vacuum.

    PubMed

    Nováková, Eva; Vyšín, Luděk; Burian, Tomáš; Juha, Libor; Davídková, Marie; Múčka, Viliam; Čuba, Václav; Grisham, Michael E; Heinbuch, Scott; Rocca, Jorge J

    2015-04-01

    Ionizing radiation induces a variety of DNA damages including single-strand breaks (SSBs), double-strand breaks (DSBs), abasic sites, modified sugars, and bases. Most theoretical and experimental studies have been focused on DNA strand scissions, in particular production of DNA double-strand breaks. DSBs have been proven to be a key damage at a molecular level responsible for the formation of chromosomal aberrations, leading often to cell death. We have studied the nature of DNA damage induced directly by the pulsed 46.9-nm (26.5 eV) radiation provided by an extreme ultraviolet (XUV) capillary-discharge Ne-like Ar laser (CDL). Doses up to 45 kGy were delivered with a repetition rate of 3 Hz. We studied the dependence of the yield of SSBs and DSBs of a simple model of DNA molecule (pBR322) on the CDL pulse fluence. Agarose gel electrophoresis method was used for determination of both SSB and DSB yields. The action cross sections of the single- and double-strand breaks of pBR322 plasmid DNA in solid state were determined. We observed an increase in the efficiency of strand-break induction in the supercoiled DNA as a function of laser pulse fluence. Results are compared to those acquired at synchrotron radiation facilities and other sources of extreme-ultraviolet and soft x-ray radiation. PMID:25974538

  11. Sub-micron period metal lattices fabricated by interfering ultraviolet femtosecond laser processing

    NASA Astrophysics Data System (ADS)

    Nakata, Yoshiki; Matsuba, Yoshiki; Miyanaga, Noriaki

    2016-05-01

    The interference pattern of a femtosecond laser has been utilized to fabricate nanostructures in the lattice. In this paper, SH (second-harmonic) waves (λ = 392.5 {{nm}}) of a femtosecond laser were applied to four beams interfering laser processing using a demagnification system as a beam correlator. The lattice constant of the resultant matrix was shortened to 760 nm. The unit structures fabricated on gold thin films were nanoholes, nanobumps, nanodrops or nanowhiskers, and their unit size was minimized compared to the case with a greater lattice constant formed by fundamental wavelengths. The radius of a nanoball on top of a nanodrop was between 42 and 76 nm, and the radius of metallic hole arrays (MHA) was 220 nm. The energy efficiency of the laser increased by 4.79 times due to better absorption coefficient of gold at ultraviolet wavelengths. In addition, the smallest lattice constant was estimated with the use of a commercial plano-convex fused-silica lens and a NIR (near-infrared) achromatic lens.

  12. Characterization of material ablation driven by laser generated intense extreme ultraviolet light

    NASA Astrophysics Data System (ADS)

    Tanaka, Nozomi; Masuda, Masaya; Deguchi, Ryo; Murakami, Masakatsu; Sunahara, Atsushi; Fujioka, Shinsuke; Yogo, Akifumi; Nishimura, Hiroaki

    2015-09-01

    We present a comparative study on the hydrodynamic behaviour of plasmas generated by material ablation by the irradiation of nanosecond extreme ultraviolet (EUV or XUV) or infrared laser pulses on solid samples. It was clarified that the difference in the photon energy deposition and following material heating mechanism between these two lights result in the difference in the plasma parameters and plasma expansion characteristics. Silicon plate was ablated by either focused intense EUV pulse (λ = 9-25 nm, 10 ns) or laser pulse (λ = 1064 nm, 10 ns), both with an intensity of ˜109 W/cm2. Both the angular distributions and energy spectra of the expanding ions revealed that the photoionized plasma generated by the EUV light differs significantly from that produced by the laser. The laser-generated plasma undergoes spherical expansion, whereas the EUV-generated plasma undergoes planar expansion in a comparatively narrow angular range. It is presumed that the EUV radiation is transmitted through the expanding plasma and directly photoionizes the samples in the solid phase, consequently forming a high-density and high-pressure plasma. Due to a steep pressure gradient along the direction of the target normal, the EUV plasma expands straightforward resulting in the narrower angular distribution observed.

  13. Chemical transformations of the polyimide Kapton brought about by ultraviolet laser radiation

    NASA Astrophysics Data System (ADS)

    Srinivasan, R.; Hall, R. R.; Loehle, W. D.; Wilson, W. D.; Allbee, D. C.

    1995-10-01

    By the use of ultraviolet laser pulses of microsecond and millisecond duration it is shown that the chemistry of the transformations of Kapton by UV laser radiation is strongly dependent on the intensity (power/unit area) of the laser beam. With these long pulses, the polymer was not ablated. The decomposition resulted in 51% of the polymer weight being converted to gaseous products consisting mostly of CO (67%), HCN (15%), C2H2 (12%), and some (<5%) CO2. The major solid product that remained was ``glassy'' carbon which was identified from its Raman spectrum. This material can be viewed as the product of the secondary addition reactions of the residue that is left after the loss of the gaseous products listed above. With 20 ms pulses, the evolution of the gaseous products increased linearly with intensity and the product composition was constant within the experimental uncertainty over a 12-fold range of intensity up to 50 kW/cm2 (≡1 kJ/cm2). These results show that pulses of duration much greater than ns do not lead to ablation even at fluences that are 104 greater than the threshold for ablation using nanosecond pulses. It is therefore more appropriate to view the ablation of this polymer by UV laser pulses of nanosecond duration as being due to the scaling of an intensity threshold rather than a fluence threshold as has become the practice.

  14. Experimental investigation of ultraviolet laser induced plasma density and temperature evolution in air

    SciTech Connect

    Thiyagarajan, Magesh; Scharer, John

    2008-07-01

    We present measurements and analysis of laser induced plasma neutral densities and temperatures in dry air by focusing 200 mJ, 10 MW high power, 193 nm ultraviolet ArF (argon fluoride) laser radiation to a 30 {mu}m radius spot size. We examine these properties that result from multiphoton and collisional cascade processes for pressures ranging from 40 Torr to 5 atm. A laser shadowgraphy diagnostic technique is used to obtain the plasma electron temperature just after the shock front and this is compared with optical emission spectroscopic measurements of nitrogen rotational and vibrational temperatures. Two-color laser interferometry is employed to measure time resolved spatial electron and neutral density decay in initial local thermodynamic equilibrium (LTE) and non-LTE conditions. The radiating species and thermodynamic characteristics of the plasma are analyzed by means of optical emission spectroscopy (OES) supported by SPECAIR, a special OES program for air constituent plasmas. Core plasma rotational and vibrational temperatures are obtained from the emission spectra from the N{sub 2}C-B(2+) transitions by matching the experimental spectrum results with the SPECAIR simulation results and the results are compared with the electron temperature just behind the shock wave. The plasma density decay measurements are compared with a simplified electron density decay model that illustrates the dominant three-and two-body recombination terms with good correlation.

  15. Experimental investigation of ultraviolet laser induced plasma density and temperature evolution in air

    NASA Astrophysics Data System (ADS)

    Thiyagarajan, Magesh; Scharer, John

    2008-07-01

    We present measurements and analysis of laser induced plasma neutral densities and temperatures in dry air by focusing 200 mJ, 10 MW high power, 193 nm ultraviolet ArF (argon fluoride) laser radiation to a 30 μm radius spot size. We examine these properties that result from multiphoton and collisional cascade processes for pressures ranging from 40 Torr to 5 atm. A laser shadowgraphy diagnostic technique is used to obtain the plasma electron temperature just after the shock front and this is compared with optical emission spectroscopic measurements of nitrogen rotational and vibrational temperatures. Two-color laser interferometry is employed to measure time resolved spatial electron and neutral density decay in initial local thermodynamic equilibrium (LTE) and non-LTE conditions. The radiating species and thermodynamic characteristics of the plasma are analyzed by means of optical emission spectroscopy (OES) supported by SPECAIR, a special OES program for air constituent plasmas. Core plasma rotational and vibrational temperatures are obtained from the emission spectra from the N2C-B(2+) transitions by matching the experimental spectrum results with the SPECAIR simulation results and the results are compared with the electron temperature just behind the shock wave. The plasma density decay measurements are compared with a simplified electron density decay model that illustrates the dominant three-and two-body recombination terms with good correlation.

  16. Diagnosis of energy transport in iron buried layer targets using an extreme ultraviolet laser

    SciTech Connect

    Shahzad, M.; Culfa, O.; Rossall, A. K.; Tallents, G. J.; Wilson, L. A.; Guilbaud, O.; Kazamias, S.; Delmas, O.; Demailly, J.; Maitrallain, A.; Pittman, M.; Baynard, E.; Farjardo, M.

    2015-02-15

    We demonstrate the use of extreme ultra-violet (EUV) laboratory lasers in probing energy transport in laser irradiated solid targets. EUV transmission through targets containing a thin layer of iron (50 nm) encased in plastic (CH) after irradiation by a short pulse (35 fs) laser focussed to irradiances 3 × 10{sup 16} Wcm{sup −2} is measured. Heating of the iron layer gives rise to a rapid decrease in EUV opacity and an increase in the transmission of the 13.9 nm laser radiation as the iron ionizes to Fe{sup 5+} and above where the ion ionisation energy is greater than the EUV probe photon energy (89 eV). A one dimensional hydrodynamic fluid code HYADES has been used to simulate the temporal variation in EUV transmission (wavelength 13.9 nm) using IMP opacity values for the iron layer and the simulated transmissions are compared to measured transmission values. When a deliberate pre-pulse is used to preform an expanding plastic plasma, it is found that radiation is important in the heating of the iron layer while for pre-pulse free irradiation, radiation transport is not significant.

  17. Characterization of material ablation driven by laser generated intense extreme ultraviolet light

    SciTech Connect

    Tanaka, Nozomi Masuda, Masaya; Deguchi, Ryo; Murakami, Masakatsu; Fujioka, Shinsuke; Yogo, Akifumi; Nishimura, Hiroaki; Sunahara, Atsushi

    2015-09-14

    We present a comparative study on the hydrodynamic behaviour of plasmas generated by material ablation by the irradiation of nanosecond extreme ultraviolet (EUV or XUV) or infrared laser pulses on solid samples. It was clarified that the difference in the photon energy deposition and following material heating mechanism between these two lights result in the difference in the plasma parameters and plasma expansion characteristics. Silicon plate was ablated by either focused intense EUV pulse (λ = 9–25 nm, 10 ns) or laser pulse (λ = 1064 nm, 10 ns), both with an intensity of ∼10{sup 9 }W/cm{sup 2}. Both the angular distributions and energy spectra of the expanding ions revealed that the photoionized plasma generated by the EUV light differs significantly from that produced by the laser. The laser-generated plasma undergoes spherical expansion, whereas the EUV-generated plasma undergoes planar expansion in a comparatively narrow angular range. It is presumed that the EUV radiation is transmitted through the expanding plasma and directly photoionizes the samples in the solid phase, consequently forming a high-density and high-pressure plasma. Due to a steep pressure gradient along the direction of the target normal, the EUV plasma expands straightforward resulting in the narrower angular distribution observed.

  18. Tunable near ultraviolet laser system from a frequency doubled alexandrite laser

    SciTech Connect

    Barnes, N.P.; Gettemy, D.J.; Johnson, T.M.

    1983-09-01

    A laser system which is capable of producing radiation tunable over the region from approximately 0.36-0.40 ..mu.. is described. The laser produces in excess of 5.0 mJ per pulse in a about 0.1 ..mu..s pulse length.

  19. Extreme-ultraviolet radiation transport in small scale length laser-produced tin plasmas

    NASA Astrophysics Data System (ADS)

    Sequoia, Kevin Lamar Williams

    The majority of the studies on laser-produced plasmas as an efficient extreme ultraviolet (EUV) light source have focused on relatively large plasmas produced at large laser facilities. However, to develop a commercially viable light source for EUV lithography, much smaller lasers and hence much smaller plasmas must be employed. Smaller plasmas behave quite differently than large plasmas in that the temperature and density are less uniform, and lateral expansion is more important. These differences affect the energy transport and, in particular, the radiation transport. This work studies the EUV radiation transport in small scale length tin plasmas, focusing on the effects of target geometry and laser pulse duration. Both planar and spherical tin targets were irradiated with an Nd:YAG laser operating at 1.064 microm. Conversion efficiency of laser light to 13.5 nm radiation (in-band), EUV emission spectrum, two-dimensional in-band emission profile, and the plasma electron density were measured experimentally. These measurements provide insight into where the laser is absorbed, where the in-band emission is produced, and how the radiation is transmitted. The plasma evolution in these experiments were simulated with a two-dimensional radiation hydrodynamic code, while the radiation transport and atomic kinetics where modeled with a collisional radiative code. Additional experiments were conducted using planar targets where the pulse duration was varied from 0.5 ns to 16 ns to understand the effects of laser pulse duration. It was found that the optimum plasma temperature for efficient generation and transmission of in-band emission is 20 eV. This is lower than the previously reported optimum temperature of 30 eV. The use of a 1.064 microm heating laser results in overheating of the plasma in a region that is much too dense to transmit the in-band emission. This overheating is necessary for the plasma to reach the optimum temperature in the region where the density is

  20. FAST TRACK COMMUNICATION: Inhomogeneous charge redistribution in Xe clusters exposed to an intense extreme ultraviolet free electron laser

    NASA Astrophysics Data System (ADS)

    Iwayama, H.; Sugishima, A.; Nagaya, K.; Yao, M.; Fukuzawa, H.; Motomura, K.; Liu, X.-J.; Yamada, A.; Wang, C.; Ueda, K.; Saito, N.; Nagasono, M.; Tono, K.; Yabashi, M.; Ishikawa, T.; Ohashi, H.; Kimura, H.; Togashi, T.

    2010-08-01

    The emission of highly charged ions from Xe clusters exposed to intense extreme ultraviolet laser pulses (λ ~ 52 nm) from the free electron laser in Japan was investigated using ion momentum spectroscopy. With increasing average cluster size, we observed multiply charged ions Xez + up to z = 3. From kinetic energy distributions, we found that multiply charged ions were generated near the cluster surface. Our results suggest that charges are inhomogeneously redistributed in the cluster to lower the total energy stored in the clusters.

  1. Simulation of ultraviolet laser-induced fluorescence LIDAR for detecting bioaerosol

    NASA Astrophysics Data System (ADS)

    Liu, Peng; Zhang, Yinchao; Chen, Siying; Lan, Tian; Wang, Yuzhao; Qiu, Zongjia; Kong, Weiguo; Ni, Guoqiang

    2009-11-01

    The biological warfare agent (BWA) is a kind of terrible threat during the war or raid from the terrorist. Last decade, the interest in utilizing ultraviolet laser-induced fluorescence (UV-LIF) LIDAR to detect the bioaerosol cloud has risen in order to measure the distribution of the bioaerosol particle. The UV-LIF LIDAR system can remotely detect and classify the bioaerosol agents and it is an active detecting system. As the infrared absorbing in the atmosphere is less, the range of infrared remote sensing is very far. The infrared laser at 1064 nm wavelength firstly begins to work in the UV-LIF LIDAR system and the aerosol cloud can be detected at very long range through the elastic backscattering signal from aerosol irradiated by infrared laser. But the category of aerosol can't be identified yet. If the infrared elastic backscattering level exceeds a threshold, UV laser at 355 nm wavelength will be triggered and induce the fluorescence. The excitated spectra of fluorescence can be used for discrimination of different aerosol species and particle concentration. This paper put forward for a UV-LIF LIDAR system model and the principle of the model is described summarily. Then the system parameters are presented and the simulation and analysis of the infrared elastic backscattering and laser-induced fluorescence are made, which is based on these parameters. Raman backscattering signal of Nitrogen gas in the atmosphere generally is taken to reduce measuring error, so the article also simulates this Raman backscatter signal at 387 nm wavelength. The studies above may provide some valuable instructions to the design of a real UV-LIF LIDAR system.

  2. All-solid-state deep ultraviolet laser for single-photon ionization mass spectrometry.

    PubMed

    Yuan, Chengqian; Liu, Xianhu; Zeng, Chenghui; Zhang, Hanyu; Jia, Meiye; Wu, Yishi; Luo, Zhixun; Fu, Hongbing; Yao, Jiannian

    2016-02-01

    We report here the development of a reflectron time-of-flight mass spectrometer utilizing single-photon ionization based on an all-solid-state deep ultraviolet (DUV) laser system. The DUV laser was achieved from the second harmonic generation using a novel nonlinear optical crystal KBe2BO3F2 under the condition of high-purity N2 purging. The unique property of this laser system (177.3-nm wavelength, 15.5-ps pulse duration, and small pulse energy at ∼15 μJ) bears a transient low power density but a high single-photon energy up to 7 eV, allowing for ionization of chemicals, especially organic compounds free of fragmentation. Taking this advantage, we have designed both pulsed nanospray and thermal evaporation sources to form supersonic expansion molecular beams for DUV single-photon ionization mass spectrometry (DUV-SPI-MS). Several aromatic amine compounds have been tested revealing the fragmentation-free performance of the DUV-SPI-MS instrument, enabling applications to identify chemicals from an unknown mixture. PMID:26931868

  3. Ultraviolet light and laser irradiation enhances the antibacterial activity of glucosamine-functionalized gold nanoparticles

    PubMed Central

    Govindaraju, Saravanan; Ramasamy, Mohankandhasamy; Baskaran, Rengarajan; Ahn, Sang Jung; Yun, Kyusik

    2015-01-01

    Here we report a novel method for the synthesis of glucosamine-functionalized gold nanoparticles (GlcN-AuNPs) using biocompatible and biodegradable glucosamine for antibacterial activity. GlcN-AuNPs were prepared using different concentrations of glucosamine. The synthesized AuNPs were characterized for surface plasmon resonance, surface morphology, fluorescence spectroscopy, and antibacterial activity. The minimum inhibitory concentrations (MICs) of the AuNPs, GlcN-AuNPs, and GlcN-AuNPs when irradiated by ultraviolet light and laser were investigated and compared with the MIC of standard kanamycin using Escherichia coli by the microdilution method. Laser-irradiated GlcN-AuNPs exhibited significant bactericidal activity against E. coli. Flow cytometry and fluorescence microscopic analysis supported the cell death mechanism in the presence of GlcN-AuNP-treated bacteria. Further, morphological changes in E. coli after laser treatment were investigated using atomic force microscopy and transmission electron microscopy. The overall results of this study suggest that the prepared nanoparticles have potential as a potent antibacterial agent for the treatment of a wide range of disease-causing bacteria. PMID:26345521

  4. All-solid-state deep ultraviolet laser for single-photon ionization mass spectrometry

    NASA Astrophysics Data System (ADS)

    Yuan, Chengqian; Liu, Xianhu; Zeng, Chenghui; Zhang, Hanyu; Jia, Meiye; Wu, Yishi; Luo, Zhixun; Fu, Hongbing; Yao, Jiannian

    2016-02-01

    We report here the development of a reflectron time-of-flight mass spectrometer utilizing single-photon ionization based on an all-solid-state deep ultraviolet (DUV) laser system. The DUV laser was achieved from the second harmonic generation using a novel nonlinear optical crystal KBe2BO3F2 under the condition of high-purity N2 purging. The unique property of this laser system (177.3-nm wavelength, 15.5-ps pulse duration, and small pulse energy at ˜15 μJ) bears a transient low power density but a high single-photon energy up to 7 eV, allowing for ionization of chemicals, especially organic compounds free of fragmentation. Taking this advantage, we have designed both pulsed nanospray and thermal evaporation sources to form supersonic expansion molecular beams for DUV single-photon ionization mass spectrometry (DUV-SPI-MS). Several aromatic amine compounds have been tested revealing the fragmentation-free performance of the DUV-SPI-MS instrument, enabling applications to identify chemicals from an unknown mixture.

  5. Infrared-laser-assisted photoionization of helium by coherent extreme ultraviolet light

    SciTech Connect

    Tong Xiaomin; Toshima, Nobuyuki

    2010-04-15

    We investigate the infrared (IR)-laser-assisted photoionization of He by a coherent extreme ultraviolet (euv) light solving the time-dependent Schroedinger equation. A combined field of the 13th and 15th harmonics created from the same IR laser source is used to ionize He atoms coherently. We show that the ionization probabilities oscillate as a function of the time delay between the IR and the euv pulses. On the other hand, the oscillation amplitude increases as the IR intensity increases, reaches a maximum when the IR intensity is around 6x10{sup 12} W/cm{sup 2}, and then decreases as the IR intensity increases further. Decomposing the ionization probabilities by the 13th and 15th harmonics, we illustrate that the oscillation amplitude is small for a lower IR laser intensity due to the fact that the transition strength by the 13th harmonic is much smaller than the one by the 15th harmonic. When the IR intensity increases further above 6x10{sup 12} W/cm{sup 2}, the transition strength by the 13th harmonic becomes larger than the one by the 15th harmonic and the oscillation amplitude is reduced again. By tuning the relative field strengths of the 13th and 15th harmonics or the IR intensity, we can control the oscillation amplitude.

  6. Characterization of gas targets for laser produced extreme ultraviolet plasmas with a Hartmann-Shack sensor

    SciTech Connect

    Peth, Christian; Kranzusch, Sebastian; Mann, Klaus; Vioel, Wolfgang

    2004-10-01

    A table top extreme ultraviolet (EUV)-source was developed at Laser-Laboratorium Goettingen for the characterization of optical components and sensoric devices in the wavelength region from 11 to 13 nm. EUV radiation is generated by focusing the beam of a Q-switched Nd:YAG laser into a pulsed xenon gas jet. Since a directed gas jet with a high number density is needed for an optimal performance of the source, conical nozzles with different cone angles were drilled with an excimer laser to produce a supersonic gas jet. The influence of the nozzle geometry on the gas jet was characterized with a Hartmann-Shack wave front sensor. The deformation of a planar wave front after passing the gas jet was analyzed with this sensor, allowing a reconstruction of the gas density distribution. Thus, the gas jet was optimized resulting in an increase of EUV emission by a factor of two and a decrease of the plasma size at the same time.

  7. On the role of chemical reactions in initiating ultraviolet laser ablation in poly(methyl methacrylate)

    SciTech Connect

    Prasad, Manish; Conforti, Patrick F.; Garrison, Barbara J.

    2007-05-15

    The role of chemical reactions is investigated versus the thermal and mechanical processes occurring in a polymer substrate during irradiation by a laser pulse and subsequent ablation. Molecular dynamics simulations with an embedded Monte Carlo based reaction scheme were used to study ultraviolet ablation of poly(methyl methacrylate) at 157 nm. We discuss the onset of ablation, the mechanisms leading to ablation, and the role of stress relaxation of the polymer matrix during ablation. Laser induced heating and chemical decomposition of the polymer substrate are considered as ablation pathways. It is shown that heating the substrate can set off ablation via mechanical failure of the material only for very short laser pulses. For longer pulses, the mechanism of ejection is thermally driven limited by the critical number of bonds broken in the substrate. Alternatively, if the photon energy goes towards direct bond breaking, it initiates chemical reactions, polymer unzipping, and formation of gaseous products, leading to a nearly complete decomposition of the top layers of substrates. The ejection of small molecules has a hollowing out effect on the weakly connected substrates which can lead to lift-off of larger chunks. Excessive pressure buildup upon the creation of gaseous molecules does not lead to enhanced yield. The larger clusters are thermally ejected, and an entrainment of larger polymer fragments in gaseous molecules is not observed.

  8. Simulation of particle velocity in a laser-produced tin plasma extreme ultraviolet source

    SciTech Connect

    Masnavi, Majid; Nakajima, Mitsuo; Horioka, Kazuhiko; Araghy, Homaira Parchamy; Endo, Akira

    2011-06-15

    In connection with fast heating in a laser produced plasma (LPP) extreme ultraviolet (EUV) source, the superheating behavior of bulk tin (Sn) at high heating rates is investigated. A constant temperature and pressure molecular dynamics simulation using modified Lennard-Jones and Coulomb potentials suitable for studying the liquid structure of Sn is employed in order to derive the caloric curves of the solid and liquid phases. The results have shown transient effects on the phase transitions. Superheating is observed during the melting and vaporizing processes. The velocity distribution of Sn particles against typical laser fluence in a LPP EUV light source has been numerically investigated using a simplified method including a one-dimensional, two-temperature, molecular dynamics, and steady-state ionization model. In the framework of our model, it was found that ejected Sn particles have a maximum velocity on the order of 10 to 40 km/s in plasma created using a nanosecond pre-pulse neodymium-doped yttrium aluminum garnet (Nd:YAG, 1.06 {mu}m) laser in EUV lithography experiments.

  9. Comparison of high repetition rate Q-switched 355nm ultraviolet lasers with EOM and AOM

    NASA Astrophysics Data System (ADS)

    Lu, Tingting; Li, Xiaolei; Zang, Huaguo; Zhu, Xiaolei

    2013-05-01

    Two kinds of Q-switched ultraviolet lasers using an acousto-optic modulator and an electro-optic modulator in the same cavity structure are demonstrated, with type I phase-matched LBO as second harmonic generation crystal and type II phase-matched LBO as third harmonic generation crystal. For acousto-optic Q-switched UV laser-a maximum average power of 6.3W with the shortest pulse width of 12 ns was obtained at the repetition rate of 22 kHz when the pump power reached 52.4 W. The optical conversion efficiency was up to 12%. Then we used a La3Ga5SiO14 crystal electro-optic modulator to replace the acousto-optic modulator. The 1.29W output power at 355nm wavelength was obtained at the repetition rate of 10 kHz when the pump power was increased to 20.4W, and the UV laser pulse width was as short as 9.6ns.The optical conversion efficiency was up to 6.3%.

  10. Resonant two-photon absorption of extreme-ultraviolet free-electron-laser radiation in helium

    SciTech Connect

    Nagasono, Mitsuru; Suljoti, Edlira; Pietzsch, Annette; Hennies, Franz; Wellhoefer, Michael; Hoeft, Jon-Tobias; Martins, Michael; Wurth, Wilfried; Foehlisch, Alexander; Treusch, Rolf; Feldhaus, Josef; Schneider, Jochen R.

    2007-05-15

    We have investigated the nonlinear response of helium to intense extreme-ultraviolet radiation from the free-electron laser in Hamburg (FLASH). We observe a spectral feature between 24 and 26 eV electron kinetic energy in photoemission which shows a quadratic fluence dependence. The feature is explained as a result of subsequent processes involving a resonant two-photon absorption process into doubly excited levels of even parity (N=5 and 6), radiative decay to the doubly excited states in the vicinity of the He{sup +} (N=2) ionization threshold and finally the photoionization of the inner electron by the radiation of the next microbunches. This observation suggests that even-parity states, which have been elusive to be measured with the low pulse energy of synchrotron radiation sources, can be investigated with the intense radiation of FLASH. This also demonstrates a first step to bring nonlinear spectroscopy into the xuv and soft-x-ray regime.

  11. Extreme ultraviolet emission from dense plasmas generated with sub-10-fs laser pulses

    SciTech Connect

    Osterholz, J.; Brandl, F.; Cerchez, M.; Fischer, T.; Hemmers, D.; Hidding, B.; Pipahl, A.; Pretzler, G.; Willi, O.; Rose, S. J.

    2008-10-15

    The extreme ultraviolet (XUV) emission from dense plasmas generated with sub-10-fs laser pulses with varying peak intensities up to 3x10{sup 16} W/cm{sup 2} is investigated for different target materials. K shell spectra are obtained from low Z targets (carbon and boron nitride). In the spectra, a series limit for the hydrogen- and helium-like resonance lines is observed, indicating that the plasma is at high density and that pressure ionization has removed the higher levels. In addition, L shell spectra from titanium targets were obtained. Basic features of the K and L shell spectra are reproduced with computer simulations. The calculations include hydrodynamic simulation of the plasma expansion and collisional radiative calculations of the XUV emission.

  12. Ultraviolet Laser Raman Scattering for Temperature Measurement in Atmospheric Air Microdischarges

    NASA Astrophysics Data System (ADS)

    Caplinger, James; Adams, Steven; Williamson, James; Clark, Jerry

    2011-10-01

    Vibrational Raman scattering for temperature measurement within a dc microdischarge in atmospheric pressure air has been investigated using a pulsed ultraviolet laser. The Raman signal analysis method involved monitoring Q-branch signals originating from multiple N2(X) vibrational states populated in the microdischarge. The translational temperature of N2(X) in the microdischarge was calculated using the total Raman signal intensity calibrated with room temperature air. Also, the distribution of Q-branch intensities among vibrational states allowed for direct measurement of the vibrational temperature of N2(X). Raman scattering results are compared to passive optical emission spectral analyses of the N2 second positive system from which the rotational and vibrational temperatures of the N2(C) excited state were also calculated. A comparison of the N2(X) and N2(C) temperatures derived from Raman scattering and emission spectroscopy, respectively, is presented. This work was supported by the Air Force Office of Scientific Research.

  13. Ultraviolet laser spectroscopy of neutral mercury in a one-dimensional optical lattice

    SciTech Connect

    Mejri, S.; McFerran, J. J.; Yi, L.; Le Coq, Y.; Bize, S.

    2011-09-15

    We present details on the ultraviolet lattice spectroscopy of the (6s{sup 2}) {sup 1}S{sub 0}{r_reversible} (6s6p) {sup 3}P{sub 0} transition in neutral mercury, specifically {sup 199}Hg. Mercury atoms are loaded into a one-dimensional vertically aligned optical lattice from a magneto-optical trap with an rms temperature of {approx}60 {mu}K. We describe aspects of the magneto-optical trapping, the lattice cavity design, and the techniques employed to trap and detect mercury in an optical lattice. The clock-line frequency dependence on lattice depth is measured at a range of lattice wavelengths. We confirm the magic wavelength to be 362.51(0.16) nm. Further observations to those reported by Yi et al.[Phys. Rev. Lett. 106, 073005 (2011)] are presented regarding the laser excitation of a Wannier-Stark ladder of states.

  14. High-power 355 nm ultraviolet lasers operating at ultrahigh repetition rate

    NASA Astrophysics Data System (ADS)

    Chen, H.; Liu, Q.; Yan, P.; Gong, M.

    2013-02-01

    In this letter, we demonstrate a novel 355 nm ultraviolet (UV) laser operating at ultrahigh repetition rate from 300 kHz to 1 MHz. The hybrid fiber-MOPA-bulk amplifiers based IR source exhibits a high average power of 105 W with near-diffraction-limited beam quality, narrow linewidth and high polarization extinction ratio. Two-cascaded LBO crystals are employed for high efficiency frequency tripling, and a maximum 43.7 W of average UV power is achieved at 400 kHz, corresponding to a conversion efficiency as high as 41.6%. The pulse duration of the UV pulse can be tuned from 5 to 10 ns with good pulse peak stability (better than 2.2% (RMS)).

  15. An ultraviolet laser communication system using frequency-shift keying modulation scheme

    NASA Astrophysics Data System (ADS)

    Peng, Di-yong; Shi, Jun; Peng, Guang-hui; Xiao, Sha-li; Xu, Shan-he; Wang, Shan; Liu, Feng

    2015-01-01

    A communication system based on an ultraviolet (UV) laser at 266 nm is presented to improve the communication distance. The pulse frequency-shift keying (FSK) modulation scheme is studied and improved in order to reduce the bit error rate (BER), and is put into practice on a field programmable gate array (FPGA). The mathematical models of the modulation and demodulation are established. A test platform is set up to measure the energy density and pulse response under different distances and receiver elevation angles. It is shown that the omnibearing communication can be realized, and the bit rate is limited to 12.5 Mbit/s. The BER is estimated to be less than 10-7 at distance of 300 m in line-of-sight (LOS) communication model and to be less than 10-6 at distance of 80 m in non-line-of-sight (NLOS) communication model.

  16. Free-electron laser sources of extreme-ultraviolet radiation and their vacuum requirements

    SciTech Connect

    Newnam, B.E.

    1990-01-01

    Recent development of free-electron laser (FEL) component technologies should enable these devices to operate in the extreme-ultraviolet, well below 100 nm. When fully developed, FELs represent the next generation of coherent-radiation sources with peak- and average-power outputs surpassing those of any existing, continuously tunable photon source by many orders of magnitude. An rf-linac-based, multiple-FEL facility, spanning the spectral range from 1 nm to 100 {mu}m, is proposed. To enable such a facility to operate without significant degradation over long periods, contamination of certain of the FEL components must be prevented. Requirements for ultra-high vacuum and restricted contamination from outgassing from chamber walls are discussed. 73 refs., 11 figs., 4 tabs.

  17. Vacuum ultraviolet spectral emission properties of Ga, In and Sn droplet-based laser produced plasmas

    NASA Astrophysics Data System (ADS)

    Gambino, Nadia; Rollinger, Bob; Brandstätter, Markus; Abhari, Reza S.

    2016-08-01

    The Emission Spectra of gallium, indium and tin droplet-based laser produced plasmas are presented in the Vacuum Ultraviolet (VUV) emission range from 30 nm to 160 nm. The Ga ion transitions are investigated in detail as a function of background pressure level and laser irradiance. Different wavelength emission regions were detected according to the level of background gas. At short wavelengths (i.e. 30-50 nm) the line emission from the higher charge states is reduced with increasing pressure, while at longer wavelengths (i.e. 100-160 nm) the trend is inverted, as the plasma emission intensity of the lower charge states increases with higher background gas pressure level. The emitted lines are fitted with Voigt profiles to determine the electron density. The electron temperature is obtained from a fit based on the Planck distribution. These estimations are then used to identify the relevant processes that lead to the different charge state emissions as a function of background gas. Langmuir Probe measurements are also reported for evaluating the ion kinetic energy as a function of background gas. The gallium spectra are calibrated in units of spectral radiance, together with spectra from indium and tin. This calibration allows absolute power estimations from the light source in the VUV region. The presented experimental results are relevant as fundamental plasma emission spectroscopic measurements in an almost unexplored wavelength region as well as for applications such as Extreme Ultraviolet Lithography to determine the so-called Out-of-Band (OoB) radiation emission and for metrology applications for future inspection tools.

  18. Effects of the dynamics of droplet-based laser-produced plasma on angular extreme ultraviolet emission profile

    SciTech Connect

    Giovannini, Andrea Z.; Abhari, Reza S.

    2014-05-12

    The emission distribution of extreme ultraviolet (EUV) radiation from droplet targets is dependent on the dynamics of the laser-produced plasma. The EUV emission is measured on a 2% bandwidth centered at 13.5 nm (in-band). The targets of the laser are small (sub-50 μm) tin droplets, and the in-band emission distribution is measured for different laser irradiances and droplet sizes at various angular positions. Larger droplets lead to a faster decay of EUV emission at larger angles with respect to the laser axis. A decrease in laser irradiance has the opposite effect. The measurements are used together with an analytical model to estimate plume dynamics. Additionally, the model is used to estimate EUV emission distribution for a desired droplet diameter and laser irradiance.

  19. Efficient extreme ultraviolet plasma source generated by a CO2 laser and a liquid xenon microjet target

    NASA Astrophysics Data System (ADS)

    Ueno, Yoshifumi; Ariga, Tatsuya; Soumagne, George; Higashiguchi, Takeshi; Kubodera, Shoichi; Pogorelsky, Igor; Pavlishin, Igor; Stolyarov, Daniil; Babzien, Marcus; Kusche, Karl; Yakimenko, Vitaly

    2007-05-01

    We demonstrated efficacy of a CO2-laser-produced xenon plasma in the extreme ultraviolet (EUV) spectral region at 13.5nm at variable laser pulse widths between 200ps and 25ns. The plasma target was a 30μm liquid xenon microjet. To ensure the optimum coupling of CO2 laser energy with the plasma, they applied a prepulse yttrium aluminum garnet laser. The authors measured the conversion efficiency (CE) of the 13.5nm EUV emission for different pulse widths of the CO2 laser. A maximum CE of 0.6% was obtained for a CO2 laser pulse width of 25ns at an intensity of 5×1010W/cm2.

  20. Finite element simulation for ultraviolet excimer laser processing of patterned Si/SiGe/Si(100) heterostructures

    SciTech Connect

    Conde, J. C.; Chiussi, S.; Gontad, F.; Gonzalez, P.; Martin, E.; Serra, C.

    2010-07-05

    Ultraviolet (UV) Excimer laser assisted processing is an alternative strategy for producing patterned silicon germanium heterostructures. We numerically analyzed the effects caused by pulsed 193 Excimer laser radiation impinging on patterned amorphous hydrogenated silicon (a-Si:H) and germanium (a-Ge:H) bilayers deposited on a crystalline silicon substrate [Si(100)]. The proposed two dimensional axisymmetric numerical model allowed us to estimate the temperature and concentration gradients caused by the laser induced rapid melting and solidification processes. Energy density dependence of maximum melting depth and melting time evolution as well as three dimensional temperature and element distribution have been simulated and compared with experimentally obtained results.

  1. Development of a collective Thomson scattering system for laser-produced tin plasmas for extreme-ultraviolet light sources

    NASA Astrophysics Data System (ADS)

    Tomita, Kentaro; Sato, Yuta; Nishikawa, Kazutaka; Uchino, Kiichiro; Yanagida, Tatsuya; Tomuro, Hiroaki; Wada, Yasunori; Kunishima, Masahito; Kodama, Takeshi; Mizoguchi, Hakaru; Sunahara, Atsushi

    2015-12-01

    Spatial profiles of electron density (ne) and electron temperature (Te) of laser-produced Sn plasmas for extreme-ultraviolet (EUV) light sources have been obtained using a new collective Thomson scattering system, which has been optimized for the measurement of the ion feature spectrum. The system has an 18 pm spectral resolution, a 5 ns temporal resolution, a 50 µm spatial resolution, and sufficient stray-light rejection near the probing laser wavelength. With this system, measurements of the laser-produced Sn plasmas in the parameter ranges of 3 × 1023 < ne < 1025 m-3 and 10 < Te < 20 eV have been performed.

  2. Proposal and physics of AlInN-delta-GaN quantum well ultraviolet lasers

    NASA Astrophysics Data System (ADS)

    Liu, Cheng; Ooi, Yu Kee; Zhang, Jing

    2016-02-01

    The use of AlInN-delta-GaN quantum wells (QWs) active region for ultraviolet (UV) laser with wavelength (λ) ˜ 250-300 nm was proposed and investigated in this work. The design of active region consists of 24 Å staggered Al0.91In0.09N/Al0.82In0.18N layers with a 3 Å lattice-matched GaN delta layer, which enables dominant conduction band (C) to heavy hole (HH) subband transition. In addition, the insertion of the ultra-thin delta GaN layer will strongly localize the electron-hole wave functions toward the center of the QW, which leads to large transverse electric (TE) polarized optical gain. In comparison to the use of a conventional AlGaN QW system, the proposed AlInN-delta-GaN QW structure results in ˜3 times improvement in TE-gain at 255 nm. By tuning the delta-GaN thickness, the TE-polarized optical gain up to 3700 cm-1 can be obtained for λ ˜ 280-300 nm, which is very promising to serve as an alternative active region for high-efficiency UV lasers.

  3. Quantitative deuterium analysis of titanium samples in ultraviolet laser-induced low-pressure helium plasma.

    PubMed

    Abdulmadjid, Syahrun Nur; Lie, Zener Sukra; Niki, Hideaki; Pardede, Marincan; Hedwig, Rinda; Lie, Tjung Jie; Jobiliong, Eric; Kurniawan, Koo Hendrik; Fukumoto, Ken-Ichi; Kagawa, Kiichiro; Tjia, May On

    2010-04-01

    An experimental study of ultraviolet (UV) laser-induced plasma spectroscopy (LIPS) on Ti samples with low-pressure surrounding He gas has been carried out to demonstrate its applicability to quantitative micro-analysis of deuterium impurities in titanium without the spectral interference from the ubiquitous surface water. This was achieved by adopting the optimal experimental condition ascertained in this study, which is specified by 5 mJ laser energy, 10 Torr helium pressure, and 1-50 mus measurement window, which resulted in consistent D emission enhancement and effective elimination of spectral interference from surface water. As a result, a linear calibration line exhibiting a zero intercept was obtained from Ti samples doped with various D impurity concentrations. An additional measurement also yielded a detection limit of about 40 ppm for D impurity, well below the acceptable threshold of damaging H concentration in Ti and its alloys. Each of these measurements was found to produce a crater size of only 25 mum in diameter, and they may therefore qualify as nondestructive measurements. The result of this study has therefore paved the way for conducting further experiments with hydrogen-doped Ti samples and the technical implementation of quantitative micro-analysis of detrimental hydrogen impurity in Ti metal and its alloys, which is the ultimate goal of this study. PMID:20412619

  4. Considerations for a free-electron laser-based extreme-ultraviolet lithography program

    NASA Astrophysics Data System (ADS)

    Hosler, Erik R.; Wood, Obert R.; Barletta, William A.; Mangat, Pawitter J. S.; Preil, Moshe E.

    2015-03-01

    Recent years have seen great strides in the development of extreme ultraviolet (EUV) laser-produced plasma sources. Field deployed EUV exposure tools are now capable of facilitating advanced technology node development. Nevertheless, as the required manufacturing exposure dose scales, EUV sources must follow suit and provide 500- 1000 W to maintain production throughputs. A free-electron laser (FEL) offers a cost effective, single-source alternative for powering an entire EUV lithography program. FEL integration into semiconductor fab architecture will require both unique facility considerations as well as a paradigm shift in lithography operations. Critical accelerator configurations relating to energy recovery, multi-turn acceleration, and operational mode are discussed from engineering/scientific, cost-minimization, and safety perspectives. Furthermore, the individual components of a FEL (electron injector, RF systems, undulator, etc.) are examined with respect to both design and cost, considering existing technology as well as prospective innovations. Finally, FEL development and deployment roadmaps are presented, focusing on manufacturer deployment for the 5 nm or 3 nm technology nodes.[1-3

  5. Simple locking of infrared and ultraviolet diode lasers to a visible laser using a LabVIEW proportional-integral-derivative controller on a Fabry-Perot signal

    NASA Astrophysics Data System (ADS)

    Kwolek, J. M.; Wells, J. E.; Goodman, D. S.; Smith, W. W.

    2016-05-01

    Simultaneous laser locking of infrared (IR) and ultraviolet lasers to a visible stabilized reference laser is demonstrated via a Fabry-Perot (FP) cavity. LabVIEW is used to analyze the input, and an internal proportional-integral-derivative algorithm converts the FP signal to an analog locking feedback signal. The locking program stabilized both lasers to a long term stability of better than 9 MHz, with a custom-built IR laser undergoing significant improvement in frequency stabilization. The results of this study demonstrate the viability of a simple, computer-controlled, non-temperature-stabilized FP locking scheme for our applications, laser cooling of Ca+ ions, and its use in other applications with similar modest frequency stabilization requirements.

  6. High-power metal halide vapour lasers oscillating in deep ultraviolet, visible and middle infrared spectral ranges

    NASA Astrophysics Data System (ADS)

    Temelkov, K. A.; Slaveeva, S. I.; Kirilov, V. I.; Kostadinov, I. K.; Vuchkov, N. K.

    2012-05-01

    Middle infrared and deep ultraviolet high-power high-beam-quality stable-operating He-SrBr2 and Cu+ Ne-CuBr lasers excited in nanosecond pulsed longitudinal discharge are developed, patented and studied. Optimal discharge conditions, such as active zone diameter, vapour pressure, buffer-gas pressure, electrical excitation scheme parameters, average input power and pulse repetition frequency, are found. The highest output laser parameters are obtained for the Sr atom and Cu+ lasers, respectively. These lasers equipped with optical systems for the control of laser radiation parameters are used in a large variety of applications, such as precise material microprocessing, including biological tissues, determination of linear optical properties of different newly developed materials, laser-induced modification of conductive polymers and laser-induced fluorescence in wide-gap semiconductors, instead of free electron and excimer lasers, respectively. A master oscillator-power amplifier system, which is based on a high-beam-quality high-power CuBr vapour laser and is equipped with an optic system for laser beam control and with the X-Y stage controlled by adequate software as well, is developed and used in high-precision micromachining of samples made of nickel and tool steel.

  7. Measurements of electron and proton heating temperatures from extreme-ultraviolet light images at 68 eV in petawatt laser experiments

    SciTech Connect

    Gu Peimin; Zhang, B.; Key, M. H.; Hatchett, S. P.; Barbee, T.; Freeman, R. R.; Akli, K.; Hey, D.; King, J. A.; Mackinnon, A. J.; Snavely, R. A.; Stephens, R. B.

    2006-11-15

    A 68 eV extreme-ultraviolet light imaging diagnostic measures short pulse isochoric heating by electrons and protons in petawatt laser experiments. Temperatures are deduced from the absolute intensities and comparison with modeling using a radiation hydrodynamics code.

  8. Nonthermal phase transitions in semiconductors induced by a femtosecond extreme ultraviolet laser pulse

    NASA Astrophysics Data System (ADS)

    Medvedev, Nikita; Jeschke, Harald O.; Ziaja, Beata

    2013-01-01

    In this paper, we present a novel theoretical approach, which allows the study of nonequilibrium dynamics of both electrons and atoms/ions within free-electron laser excited semiconductors at femtosecond time scales. The approach consists of the Monte-Carlo method treating photoabsorption, high-energy-electron and core-hole kinetics and relaxation processes. Low-energy electrons localized within the valence and conduction bands of the target are treated with a temperature equation, including source terms, defined by the exchange of energy and particles with high-energy electrons and atoms. We follow the atomic motion with the molecular dynamics method on the changing potential energy surface. The changes of the potential energy surface and of the electron band structure are calculated at each time step with the help of the tight-binding method. Such a combination of methods enables investigation of nonequilibrium structural changes within materials under extreme ultraviolet (XUV) femtosecond irradiation. Our analysis performed for diamond irradiated with an XUV femtosecond laser pulse predicts for the first time in this wavelength regime the nonthermal phase transition from diamond to graphite. Similar to the case of visible light irradiation, this transition takes place within a few tens of femtoseconds and is caused by changes of the interatomic potential induced by ultrafast electronic excitations. It thus occurs well before the heating stimulated by electron-phonon coupling starts to play a role. This allows us to conclude that this transition is nonthermal and represents a general mechanism of the response of solids to ultrafast electron excitations.

  9. Control of the polarization of a vacuum-ultraviolet, high-gain, free-electron laser

    DOE PAGESBeta

    Allaria, Enrico; Diviacco, Bruno; Callegari, Carlo; Finetti, Paola; Mahieu, Benoît; Viefhaus, Jens; Zangrando, Marco; De Ninno, Giovanni; Lambert, Guillaume; Ferrari, Eugenio; et al

    2014-12-02

    The two single-pass, externally seeded free-electron lasers (FELs) of the FERMI user facility are designed around Apple-II-type undulators that can operate at arbitrary polarization in the vacuum ultraviolet-to-soft x-ray spectral range. Furthermore, within each FEL tuning range, any output wavelength and polarization can be set in less than a minute of routine operations. We report the first demonstration of the full output polarization capabilities of FERMI FEL-1 in a campaign of experiments where the wavelength and nominal polarization are set to a series of representative values, and the polarization of the emitted intense pulses is thoroughly characterized by three independentmore » instruments and methods, expressly developed for the task. The measured radiation polarization is consistently >90% and is not significantly spoiled by the transport optics; differing, relative transport losses for horizontal and vertical polarization become more prominent at longer wavelengths and lead to a non-negligible ellipticity for an originally circularly polarized state. The results from the different polarimeter setups validate each other, allow a cross-calibration of the instruments, and constitute a benchmark for user experiments.« less

  10. Control of the polarization of a vacuum-ultraviolet, high-gain, free-electron laser

    SciTech Connect

    Allaria, Enrico; Diviacco, Bruno; Callegari, Carlo; Finetti, Paola; Mahieu, Benoît; Viefhaus, Jens; Zangrando, Marco; De Ninno, Giovanni; Lambert, Guillaume; Ferrari, Eugenio; Buck, Jens; Ilchen, Markus; Vodungbo, Boris; Mahne, Nicola; Svetina, Cristian; Spezzani, Carlo; Di Mitri, Simone; Penco, Giuseppe; Trovó, Mauro; Fawley, William M.; Rebernik, Primoz R.; Gauthier, David; Grazioli, Cesare; Coreno, Marcello; Ressel, Barbara; Kivimäki, Antti; Mazza, Tommaso; Glaser, Leif; Scholz, Frank; Seltmann, Joern; Gessler, Patrick; Grünert, Jan; De Fanis, Alberto; Meyer, Michael; Knie, André; Moeller, Stefan P.; Raimondi, Lorenzo; Capotondi, Flavio; Pedersoli, Emanuele; Plekan, Oksana; Danailov, Miltcho B.; Demidovich, Alexander; Nikolov, Ivaylo; Abrami, Alessandro; Gautier, Julien; Lüning, Jan; Zeitoun, Philippe; Giannessi, Luca

    2014-12-02

    The two single-pass, externally seeded free-electron lasers (FELs) of the FERMI user facility are designed around Apple-II-type undulators that can operate at arbitrary polarization in the vacuum ultraviolet-to-soft x-ray spectral range. Furthermore, within each FEL tuning range, any output wavelength and polarization can be set in less than a minute of routine operations. We report the first demonstration of the full output polarization capabilities of FERMI FEL-1 in a campaign of experiments where the wavelength and nominal polarization are set to a series of representative values, and the polarization of the emitted intense pulses is thoroughly characterized by three independent instruments and methods, expressly developed for the task. The measured radiation polarization is consistently >90% and is not significantly spoiled by the transport optics; differing, relative transport losses for horizontal and vertical polarization become more prominent at longer wavelengths and lead to a non-negligible ellipticity for an originally circularly polarized state. The results from the different polarimeter setups validate each other, allow a cross-calibration of the instruments, and constitute a benchmark for user experiments.

  11. Growth of calcium phosphate thin films by in situ assisted ultraviolet pulsed laser deposition

    NASA Astrophysics Data System (ADS)

    Nelea, V.; Craciun, V.; Iliescu, M.; Mihailescu, I. N.; Pelletier, H.; Mille, P.; Werckmann, J.

    2003-03-01

    Calcium phosphate (CaP) thin films including hydroxyapatite were intensively studied in order to optimize the technology of the bone prostheses manufacturing. A drawback in the CaP films processing is the poor mechanical characteristics, especially hardness, tensile strength and adherence to the metallic substrate. We report a new method for the growth of high quality CaP films with substantial improvement of the mechanical properties: pulsed laser deposition (PLD) assisted by in situ ultraviolet (UV) radiation emitted by a low pressure Hg lamp. The depositions were made on Si and Ti-5Al-2.5Fe alloys in very low ambient oxygen at pressures of 10 -2 to 10 -1 Pa with the substrates maintained at 500-600 °C temperature. The films were analyzed by electron microscopy, white light confocal microscopy (WLCM), grazing incidence X-ray diffraction and Berkovich nanoindentation. The films were crystalline and exhibited remarkable mechanical characteristics with values of hardness and Young modulus of 6-8 and 150-170 GPa, respectively, which are uncommonly high for the CaP ceramics. The UV lamp radiation enhanced the gas reactivity and atoms mobility during processing, while the tensile strength between the film's grains and the bonding strength at the CaP film-substrate interface were increased.

  12. Effective interface state effects in hydrogenated amorphous-crystalline silicon heterostructures using ultraviolet laser photocarrier radiometry

    SciTech Connect

    Melnikov, A.; Mandelis, A.; Halliop, B.; Kherani, N. P.

    2013-12-28

    Ultraviolet photocarrier radiometry (UV-PCR) was used for the characterization of thin-film (nanolayer) intrinsic hydrogenated amorphous silicon (i-a-Si:H) on c-Si. The small absorption depth (approximately 10 nm at 355 nm laser excitation) leads to strong influence of the nanolayer parameters on the propagation and recombination of the photocarrier density wave (CDW) within the layer and the substrate. A theoretical PCR model including the presence of effective interface carrier traps was developed and used to evaluate the transport parameters of the substrate c-Si as well as those of the i-a-Si:H nanolayer. Unlike conventional optoelectronic characterization methods such as photoconductance, photovoltage, and photoluminescence, UV-PCR can be applied to more complete quantitative characterization of a-Si:H/c-Si heterojunction solar cells, including transport properties and defect structures. The quantitative results elucidate the strong effect of a front-surface passivating nanolayer on the transport properties of the entire structure as the result of effective a-Si:H/c-Si interface trap neutralization through occupation. A further dramatic improvement of those properties with the addition of a back-surface passivating nanolayer is observed and interpreted as the result of the interaction of the increased excess bulk CDW with, and more complete occupation and neutralization of, effective front interface traps.

  13. Mitigation of ion and particulate emission from laser-produced plasmas used for extreme ultraviolet lithography

    NASA Astrophysics Data System (ADS)

    Di Lazzaro, Paolo; Bollanti, Sarah; Flora, Francesco; Mezi, Luca; Murra, Daniele; Torre, Amalia

    2013-05-01

    While developing a laboratory-scale micro-exposure tool for extreme ultraviolet (EUV) projection lithography which uses a laser-produced plasma emitting EUV pulsed radiation, we faced the problem of suppressing the various debris (ions, neutrals, particulate, clusters, droplets) emitted by the plasma target. The suppression of debris is a crucial task in the frame of EUV projection lithography, mainly because debris seriously limit both lifetime and performance of the expensive optics and filters put close to the plasma source. In this paper we present the experimental measurements of main debris characteristics (velocity, size, charge, momentum, spectral energy, spatial distribution). Then, we present the operating results of a patented debris mitigation systems (DMS) specifically designed to suppress debris with the measured characteristics. We achieved reduction factors ˜800 for atoms and nm-size clusters, and ˜1600 for particles larger than 500 nm. These results are at the forefront in this field. The excellent performance of our DMS was a breakthrough to achieve a 90-nm patterning on commercial resists by our micro-exposure tool EUV projection lithography.

  14. Continuous-wave operation of ultraviolet InGaN/InAlGaN multiple-quantum-well laser diodes

    NASA Astrophysics Data System (ADS)

    Kneissl, Michael; Treat, David W.; Teepe, Mark; Miyashita, Naoko; Johnson, Noble M.

    2003-04-01

    We demonstrate ultraviolet InGaN/InAlGaN multiple-quantum-well laser diodes operating under continuous-wave (cw) conditions. The laser diodes were grown on sapphire substrates by metalorganic chemical vapor deposition. Under pulsed bias conditions, we have achieved threshold current densities as low as 5 kA/cm2 for laser diodes with emission wavelengths between 368 nm and 378 nm and have demonstrated lasing at 363.2 nm at room temperature, the shortest wavelength yet reported for a semiconductor laser diode. The cw operation up to a heat sink temperature of 40 °C was demonstrated on a series of narrow ridge-waveguide devices processed with chemically assisted ion beam etched mirrors and high reflective coating on both facets. The shortest wavelength emission under cw operation conditions was 373.5 nm with output powers of more than 1 mW.

  15. Viability of Cladosporium herbarum spores under 157 nm laser and vacuum ultraviolet irradiation, low temperature (10 K) and vacuum

    NASA Astrophysics Data System (ADS)

    Sarantopoulou, E.; Stefi, A.; Kollia, Z.; Palles, D.; Petrou, P. S.; Bourkoula, A.; Koukouvinos, G.; Velentzas, A. D.; Kakabakos, S.; Cefalas, A. C.

    2014-09-01

    Ultraviolet photons can damage microorganisms, which rarely survive prolonged irradiation. In addition to the need for intact DNA, cell viability is directly linked to the functionality of the cell wall and membrane. In this work, Cladosporium herbarum spore monolayers exhibit high viability (7%) when exposed to 157 nm laser irradiation (412 kJm-2) or vacuum-ultraviolet irradiation (110-180 nm) under standard pressure and temperature in a nitrogen atmosphere. Spore viability can be determined by atomic-force microscopy, nano-indentation, mass, μ-Raman and attenuated reflectance Fourier-transform far-infrared spectroscopies and DNA electrophoresis. Vacuum ultraviolet photons cause molecular damage to the cell wall, but radiation resistance in spores arises from the activation of a photon-triggered signaling reaction, expressed via the exudation of intracellular substances, which, in combination with the low penetration depth of vacuum-ultraviolet photons, shields DNA from radiation. Resistance to phototoxicity under standard conditions was assessed, as was resistance to additional environmental stresses, including exposure in a vacuum, under different rates of change of pressure during pumping time and low (10 K) temperatures. Vacuum conditions were far more destructive to spores than vacuum-ultraviolet irradiation, and UV-B photons were two orders of magnitude more damaging than vacuum-ultraviolet photons. The viability of irradiated spores was also enhanced at 10 K. This work, in addition to contributing to the photonic control of the viability of microorganisms exposed under extreme conditions, including decontamination of biological warfare agents, outlines the basis for identifying bio-signaling in vivo using physical methodologies.

  16. Viability of Cladosporium herbarum spores under 157 nm laser and vacuum ultraviolet irradiation, low temperature (10 K) and vacuum

    SciTech Connect

    Sarantopoulou, E. Stefi, A.; Kollia, Z.; Palles, D.; Cefalas, A. C.; Petrou, P. S.; Bourkoula, A.; Koukouvinos, G.; Kakabakos, S.; Velentzas, A. D.

    2014-09-14

    Ultraviolet photons can damage microorganisms, which rarely survive prolonged irradiation. In addition to the need for intact DNA, cell viability is directly linked to the functionality of the cell wall and membrane. In this work, Cladosporium herbarum spore monolayers exhibit high viability (7%) when exposed to 157 nm laser irradiation (412 kJm⁻²) or vacuum-ultraviolet irradiation (110–180 nm) under standard pressure and temperature in a nitrogen atmosphere. Spore viability can be determined by atomic-force microscopy, nano-indentation, mass, μ-Raman and attenuated reflectance Fourier-transform far-infrared spectroscopies and DNA electrophoresis. Vacuum ultraviolet photons cause molecular damage to the cell wall, but radiation resistance in spores arises from the activation of a photon-triggered signaling reaction, expressed via the exudation of intracellular substances, which, in combination with the low penetration depth of vacuum-ultraviolet photons, shields DNA from radiation. Resistance to phototoxicity under standard conditions was assessed, as was resistance to additional environmental stresses, including exposure in a vacuum, under different rates of change of pressure during pumping time and low (10 K) temperatures. Vacuum conditions were far more destructive to spores than vacuum-ultraviolet irradiation, and UV-B photons were two orders of magnitude more damaging than vacuum-ultraviolet photons. The viability of irradiated spores was also enhanced at 10 K. This work, in addition to contributing to the photonic control of the viability of microorganisms exposed under extreme conditions, including decontamination of biological warfare agents, outlines the basis for identifying bio-signaling in vivo using physical methodologies.

  17. Measurement of CO2 laser absorption by tin plasma emanating extreme ultraviolet light for photo-lithography

    NASA Astrophysics Data System (ADS)

    Matsukuma, Hiraku; Yoshida, Kensuke; Hosoda, Tatsuya; Yogo, Akifumi; Fujioka, Shinsuke; Nishihara, Katsunobu; Sunahara, Atsushi; Somekawa, Toshihiro; Nishimura, Hiroaki

    2014-10-01

    Laser-driven tin plasma has been studied as a light source of extreme ultraviolet (EUV) at 13.5 nm (+/- 1% in-band width) for the next-generation semiconductor manufacturing. By using CO2 laser as a driver, high conversion efficiency (CE) has been attained in previous works by optimizing optical thickness for EUV radiation. Radiation hydorodynamic simulation predicts, however, that absorption coefficient for CO2 laser is as high as 50% for a tin plasma generated with a single laser pulse mainly due to short plasma scale. The relatively low absorption is a crucial problem for efficient generation of EUV light. In order to solve this problem and to increase the energy absorption, a double pulse method has been proposed where plasma scale length is extended by pre-pulse irradiation. Therefore, it is important to measure CO2 laser absorption rate precisely in order to optimize plasma conditions. For this purpose we designed an integrating sphere for CO2 laser. Laser absorption was measured for tin plasmas generated under various conditions including target geometries. We will show experimental results and discuss on guidelines for getting higher CE. This study has been partly supported by Strategic Innovation Program for Energy Conservation Technologies in 2013 from New Energy and Industrial Technology Development Organization (NEDO) of Japan.

  18. Desorption Dynamics, Internal Energies and Imaging of Organic Molecules from Surfaces with Laser Desorption and Vacuum Ultraviolet (VUV) Photoionization

    SciTech Connect

    Kostko, Oleg; Takahashi, Lynelle K.; Ahmed, Musahid

    2011-04-05

    There is enormous interest in visualizing the chemical composition of organic material that comprises our world. A convenient method to obtain molecular information with high spatial resolution is imaging mass spectrometry. However, the internal energy deposited within molecules upon transfer to the gas phase from a surface can lead to increased fragmentation and to complications in analysis of mass spectra. Here it is shown that in laser desorption with postionization by tunable vacuum ultraviolet (VUV) radiation, the internal energy gained during laser desorption leads to minimal fragmentation of DNA bases. The internal temperature of laser-desorbed triacontane molecules approaches 670 K, whereas the internal temperature of thymine is 800 K. A synchrotron-based VUV postionization technique for determining translational temperatures reveals that biomolecules have translational temperatures in the range of 216-346 K. The observed low translational temperatures, as well as their decrease with increased desorption laser power is explained by collisional cooling. An example of imaging mass spectrometry on an organic polymer, using laser desorption VUV postionization shows 5 mu m feature details while using a 30 mu m laser spot size and 7 ns duration. Applications of laser desorption postionization to the analysis of cellulose, lignin and humic acids are briefly discussed.

  19. Low-debris, efficient laser-produced plasma extreme ultraviolet source by use of a regenerative liquid microjet target containing tin dioxide (SnO2) nanoparticles

    NASA Astrophysics Data System (ADS)

    Higashiguchi, Takeshi; Dojyo, Naoto; Hamada, Masaya; Sasaki, Wataru; Kubodera, Shoichi

    2006-05-01

    We demonstrated a low-debris, efficient laser-produced plasma extreme ultraviolet (EUV) source by use of a regenerative liquid microjet target containing tin-dioxide (SnO2) nanoparticles. By using a low SnO2 concentration (6%) solution and dual laser pulses for the plasma control, we observed the EUV conversion efficiency of 1.2% with undetectable debris.

  20. Generation of an extreme ultraviolet supercontinuum and isolated sub-50 as pulse in a two-colour laser field

    NASA Astrophysics Data System (ADS)

    Zhang, Gang-Tai; Liu, Xue-Shen

    2009-06-01

    We theoretically study high-order harmonic generation when a helium ion is exposed to a two-colour laser field, which is synthesized by a 5 fs/800 nm laser pulse and a 64 fs/2400 nm laser pulse. Our numerical results show that the harmonic spectrum exhibits an ultrabroad extreme ultraviolet supercontinuum when the initial state is prepared as a coherent superposition of the ground state and the first excited state. By superposing a series of properly selected harmonics, an isolated attosecond pulse with a duration of 47 as is obtained. Compared with the case of the ground state in a one-colour field, the intensity of this isolated attosecond pulse is six orders of magnitude higher. We also demonstrate these results in terms of the time-frequency analysis and the semiclassical three-step model.

  1. Isolated short attosecond pulse produced by using an intense few-cycle shaped laser and an ultraviolet attosecond pulse

    NASA Astrophysics Data System (ADS)

    Zhao, Song-Feng; Zhou, Xiao-Xin; Li, Peng-Cheng; Chen, Zhangjin

    2008-12-01

    An efficient method to generate a short attosecond pulse is presented by using intense few-cycle shaped infrared (ir) laser in combination with an ultraviolet (uv) attosecond (as) pulse. We show that high-order harmonic generation (HHG) plateau near the cutoff is enhanced by one order of magnitude compared with the shaped laser case and the HHG supercontinuum spectrum is generated by adding a uv attosecond pulse to the few-cycle shaped ir laser at a proper time. By enhancing the long quantum path and suppressing the short one corresponding to one major return, an isolated 57-as pulse with a bandwidth of 62eV is obtained directly. The time-frequency characteristics of the HHG are analyzed in detail by means of the wavelet transform of the time-dependent induced dipole acceleration. In addition, we also perform classical trajectory simulation of the strong-field electron dynamics and electron return map.

  2. Optimization of the size ratio of Sn sphere and laser focal spot for an extreme ultraviolet light source

    SciTech Connect

    Yuspeh, S.; Sequoia, K. L.; Tao, Y.; Tillack, M. S.; Burdt, R.; Najmabadi, F.

    2008-12-01

    The effect of the ratio of Sn sphere diameter to laser focal spot size (SD/FSS) on conversion efficiency (CE) from laser to in-band (2%) 13.5 nm extreme ultraviolet (EUV) light was investigated by fixing the laser spot size and irradiating variable diameter spheres. It was found that a minimum SD/FSS, i.e., 2.5, is necessary to produce high in-band CE, which is 15% higher than planar targets. Two-dimensional plasma density profile maps showed that the density of the dominant in-band EUV emission region and the size of the surrounding absorbing plasma can be manipulated by geometric effects of the SD/FSS ratio.

  3. MRF Applications: On the Road to Making Large-Aperture Ultraviolet Laser Resistant Continuous Phase Plates for High-Power Lasers

    SciTech Connect

    Menapace, J A; Davis, P J; Steele, W A; Hachkowski, M R; Nelson, A; Xin, K

    2006-10-26

    Over the past two years we have developed MRF tools and procedures to manufacture large-aperture (430 X 430 mm) continuous phase plates (CPPs) that are capable of operating in the infrared portion (1053 nm) of high-power laser systems. This is accomplished by polishing prescribed patterns of continuously varying topographical features onto finished plano optics using MRF imprinting techniques. We have been successful in making, testing, and using large-aperture CPPs whose topography possesses spatial periods as low as 4 mm and surface peak-to-valleys as high as 8.6 {micro}m. Combining this application of MRF technology with advanced MRF finishing techniques that focus on ultraviolet laser damage resistance makes it potentially feasible to manufacture large-aperture CPPs that can operate in the ultraviolet (351 nm) without sustaining laser-induced damage. In this paper, we will discuss the CPP manufacturing process and the results of 351-nm/3-nsec equivalent laser performance experiments conducted on large-aperture CPPs manufactured using advanced MRF protocols.

  4. Investigation of optical fibers for gas-phase, ultraviolet laser-induced-fluorescence (UV-LIF) spectroscopy.

    PubMed

    Hsu, Paul S; Kulatilaka, Waruna D; Jiang, Naibo; Gord, James R; Roy, Sukesh

    2012-06-20

    We investigate the feasibility of transmitting high-power, ultraviolet (UV) laser pulses through long optical fibers for laser-induced-fluorescence (LIF) spectroscopy of the hydroxyl radical (OH) and nitric oxide (NO) in reacting and non-reacting flows. The fundamental transmission characteristics of nanosecond (ns)-duration laser pulses are studied at wavelengths of 283 nm (OH excitation) and 226 nm (NO excitation) for state-of-the-art, commercial UV-grade fibers. It is verified experimentally that selected fibers are capable of transmitting sufficient UV pulse energy for single-laser-shot LIF measurements. The homogeneous output-beam profile resulting from propagation through a long multimode fiber is ideal for two-dimensional planar-LIF (PLIF) imaging. A fiber-coupled UV-LIF system employing a 6 m long launch fiber is developed for probing OH and NO. Single-laser-shot OH- and NO-PLIF images are obtained in a premixed flame and in a room-temperature NO-seeded N(2) jet, respectively. Effects on LIF excitation lineshapes resulting from delivering intense UV laser pulses through long fibers are also investigated. Proof-of-concept measurements demonstrated in the current work show significant promise for fiber-coupled UV-LIF spectroscopy in harsh diagnostic environments such as gas-turbine test beds. PMID:22722279

  5. Scaling-up a liquid water jet laser plasma source to high average power for extreme-ultraviolet lithography

    NASA Astrophysics Data System (ADS)

    Vogt, Ulrich; Stiel, Holger; Will, Ingo; Wieland, Marek; Wilhein, Thomas; Nickles, Peter V.; Sandner, Wolfgang

    2001-08-01

    In this article we describe a laser plasma source for Extreme Ultraviolet Lithography (EUVL) based on a liquid water jet target. Although jet targets are known for some time now, no attempts have been made to prove the functionality of the target under conditions similar to an EUVL production-line facility, that means illumination with high average power laser systems (in the multi-kW regime) at repetition rates in the kHz region. Such systems are currently under development. We used the MBI-burst laser to simulate these extreme illumination conditions. We examined the hydrodynamic stability of the target as a function of the laser repetition rate at different average laser powers (0.6kW and 5kW per burst). Additionally, the dependence of the conversion efficiency on pulse duration in the range from 30ps to 3ns was investigated. From our results one can conclude parameters for future design of driver lasers for EUVL systems.

  6. Low thermal budget n-type doping into Ge(001) surface using ultraviolet laser irradiation in phosphoric acid solution

    NASA Astrophysics Data System (ADS)

    Takahashi, Kouta; Kurosawa, Masashi; Ikenoue, Hiroshi; Sakashita, Mitsuo; Takeuchi, Wakana; Nakatsuka, Osamu; Zaima, Shigeaki

    2016-02-01

    We have investigated phosphorus (P) doping into Ge(001) surfaces by using ultraviolet laser irradiation in phosphoric acid solution at room temperature. We demonstrated that the diffusion depth of P in Ge and the concentration of electrically activated P can be controlled by the number of laser shots. Indeed, a high concentration of electrically activated P of 2.4 × 1019 cm-3 was realized by 1000-times laser shots at a laser energy of 1.0 J/cm2, which is comparable or better than the counterparts of conventional n-type doping using a high thermal budget over 600 °C. The generation current is dominant in the reverse bias condition for the laser-doped pn-junction diodes independent on the number of laser shots, thus indicating low-damage during the pn-junction formation. These results open up the possibility for applicable low thermal budget doping process for Ge-based devices fabricated on flexible substrates as well as Si electronics.

  7. Laser plasma sources of soft x-rays and extreme ultraviolet (EUV) for application in science and technology

    NASA Astrophysics Data System (ADS)

    Bartnik, Andrzej; Wachulak, Przemysław; Jarocki, Roman; Kostecki, Jerzy; Szczurek, Mirosław; Adjei, Daniel; Ahad, Inam Ul; Ayele, Mesfin G.; Fok, Tomasz; Szczurek, Anna; Torrisi, Alfio; Wegrzyński, Łukasz; Fiedorowicz, Henryk

    2015-05-01

    Laser plasma sources of soft x-rays and extreme ultraviolet (EUV) developed in our laboratory for application in various areas of technology and science are presented. The sources are based on a laser-irradiated gas puff target approach. The targets formed by pulsed injection of gas under high-pressure are irradiated with nanosecond laser pulses from Nd:YAG lasers. We use commercial lasers generating pulses with time duration from 1ns to 10ns and energies from 0.5J to 10J at 10Hz repetition rate. The gas puff targets are produced using a double valve system equipped with a special nozzle to form a double-stream gas puff target which secures high conversion efficiency without degradation of the nozzle. The use of a gas puff target instead of a solid target makes generation of laser plasmas emitting soft x-rays and EUV possible without target debris production. The sources are equipped with various optical systems, including grazing incidence axisymmetric ellipsoidal mirrors, a "lobster eye" type grazing incidence multi-foil mirror, and an ellipsoidal mirror with Mo/Si multilayer coating, to collect soft x-ray and EUV radiation and form the radiation beams. In this paper new applications of these sources in various fields, including soft x-ray and EUV imaging in nanoscale, EUV radiography and tomography, EUV materials processing and modification of polymer surfaces, EUV photoionization of gases, radiobiology and soft x-ray contact microscopy are reviewed.

  8. Near-ultraviolet absorption annealing in hafnium oxide thin films subjected to continuous-wave laser radiation

    NASA Astrophysics Data System (ADS)

    Papernov, Semyon; Kozlov, Alexei A.; Oliver, James B.; Kessler, Terrance J.; Shvydky, Alexander; Marozas, Brendan

    2014-12-01

    Hafnium oxide (HfO2) is the most frequently used high-index material in multilayer thin-film coatings for high-power laser applications ranging from near-infrared to near-ultraviolet (UV). Absorption in this high-index material is also known to be responsible for nanosecond-pulse laser-damage initiation in multilayers. In this work, modification of the near-UV absorption of HfO2 monolayer films subjected to irradiation by continuous-wave (cw), 355-nm or 351-nm laser light focused to produce power densities of the order of ˜100 kW/cm2 is studied. Up to a 70% reduction in absorption is found in the areas subjected to irradiation. Temporal behavior of absorption is characterized by a rapid initial drop on the few-tens-of-seconds time scale, followed by a longer-term decline to a steady-state level. Absorption maps generated by photothermal heterodyne imaging confirm the permanent character of the observed effect. Nanosecond-pulse, 351-nm and 600-fs, 1053-nm laser-damage tests performed on these cw laser-irradiated areas confirm a reduction of absorption by measuring up to 25% higher damage thresholds. We discuss possible mechanisms responsible for near-UV absorption annealing and damage-threshold improvement resulting from irradiation by near-UV cw laser light.

  9. The mechanism underlying calcium phosphate precipitation on titanium via ultraviolet, visible, and near infrared laser-assisted biomimetic process

    NASA Astrophysics Data System (ADS)

    Mahanti, Moumita; Nakamura, Maki; Pyatenko, Alexander; Sakamaki, Ikuko; Koga, Kenji; Oyane, Ayako

    2016-08-01

    We recently developed a rapid single-step calcium phosphate (CaP) precipitation technique on several substrates using a laser-assisted biomimetic process (LAB process). In this process, ultraviolet (UV, λ  =  355 nm) pulsed laser irradiation has been applied to a substrate that is immersed in a supersaturated CaP solution. In the present study, the LAB process for CaP precipitation on a titanium substrate was successfully expanded to include not only UV but also visible (VIS, λ  =  532 nm) and near infrared (NIR, λ  =  1064 nm) lasers. Surface heating and plasma-mediated surface reactions (micro-deformation, oxidization, photoexcitation, and wetting) generated by UV, VIS, or NIR lasers are considered to be involved in the CaP precipitation on the titanium surface in the LAB process. The kinetics of these reactions and consequently of CaP precipitation were dependent on the laser wavelength and fluence. The higher laser fluence did not always accelerate CaP precipitation on the substrate; rather, it was found that an optimal range of fluence exists for each laser wavelength. These results suggest that for efficient CaP precipitation, a suitable laser wavelength should be selected according to the optical absorption properties of the substrate material and the laser fluence should also be adjusted to induce surface heating and plasma-mediated surface reactions that are favorable for CaP precipitation.

  10. Wavebreaking-associated transmitted emission of attosecond extreme-ultraviolet pulses from laser-driven overdense plasmas

    NASA Astrophysics Data System (ADS)

    Chen, Zi-Yu; Cherednychek, Mykyta; Pukhov, Alexander

    2016-06-01

    We present a new mechanism of attosecond extreme-ultraviolet (XUV) pulses generation from a relativistic laser-driven overdense plasma surfaces in the wavebreaking regime. Through particle-in-cell simulations and analysis, we demonstrate that the observed ultrashort XUV emission for the parameters we considered is predominantly due to a strong plasma-density oscillation subsequent to wavebreaking. The coupling of the strong density variation and the transverse fields in the front surface layer gives rise to the transmitted emission with frequencies mainly around the local plasma frequency. This mechanism provides new insights into the scenarios of XUV generation from solid surfaces and the dynamics of laser–plasma interactions.

  11. Spatio-temporal coherence of free-electron laser radiation in the extreme ultraviolet determined by a Michelson interferometer

    SciTech Connect

    Hilbert, V.; Rödel, C.; Zastrau, U.; Brenner, G.; Düsterer, S.; Dziarzhytski, S.; Harmand, M.; Przystawik, A.; Redlin, H.; Toleikis, S.; Döppner, T.; Ma, T.; Fletcher, L.; Förster, E.; Glenzer, S. H.; Lee, H. J.; Hartley, N. J.; Kazak, L.; Komar, D.; Skruszewicz, S.; and others

    2014-09-08

    A key feature of extreme ultraviolet (XUV) radiation from free-electron lasers (FELs) is its spatial and temporal coherence. We measured the spatio-temporal coherence properties of monochromatized FEL pulses at 13.5 nm using a Michelson interferometer. A temporal coherence time of (59±8) fs has been determined, which is in good agreement with the spectral bandwidth given by the monochromator. Moreover, the spatial coherence in vertical direction amounts to about 15% of the beam diameter and about 12% in horizontal direction. The feasibility of measuring spatio-temporal coherence properties of XUV FEL radiation using interferometric techniques advances machine operation and experimental studies significantly.

  12. Development of a liquid tin microjet target for an efficient laser-produced plasma extreme ultraviolet source.

    PubMed

    Higashiguchi, Takeshi; Hamada, Masaya; Kubodera, Shoichi

    2007-03-01

    A regenerative tin liquid microjet target was developed for a high average power extreme ultraviolet (EUV) source. The diameter of the target was smaller than 160 microm and good vacuum lower than 0.5 Pa was maintained during the operation. A maximum EUV conversion efficiency of 1.8% at the Nd:yttrium-aluminum-garnet laser intensity of around 2 x 10(11) Wcm(2) with a spot diameter of 175 microm (full width at half maximum) was observed. The angular distribution of the EUV emission remained almost isotropic, whereas suprathermal ions mainly emerged toward the target normal. PMID:17411231

  13. Development of a liquid tin microjet target for an efficient laser-produced plasma extreme ultraviolet source

    NASA Astrophysics Data System (ADS)

    Higashiguchi, Takeshi; Hamada, Masaya; Kubodera, Shoichi

    2007-03-01

    A regenerative tin liquid microjet target was developed for a high average power extreme ultraviolet (EUV) source. The diameter of the target was smaller than 160 μm and good vacuum lower than 0.5 Pa was maintained during the operation. A maximum EUV conversion efficiency of 1.8% at the Nd:yttrium-aluminum-garnet laser intensity of around 2×1011 W/cm2 with a spot diameter of 175 μm (full width at half maximum) was observed. The angular distribution of the EUV emission remained almost isotropic, whereas suprathermal ions mainly emerged toward the target normal.

  14. Ultraviolet versus infrared: Effects of ablation laser wavelength on the expansion of laser-induced plasma into one-atmosphere argon gas

    NASA Astrophysics Data System (ADS)

    Ma, Qianli; Motto-Ros, Vincent; Laye, Fabrice; Yu, Jin; Lei, Wenqi; Bai, Xueshi; Zheng, Lijuan; Zeng, Heping

    2012-03-01

    Laser-induced plasma from an aluminum target in one-atmosphere argon background has been investigated with ablation using nanosecond ultraviolet (UV: 355 nm) or infrared (IR: 1064 nm) laser pulses. Time- and space-resolved emission spectroscopy was used as a diagnostics tool to have access to the plasma parameters during its propagation into the background, such as optical emission intensity, electron density, and temperature. The specific feature of nanosecond laser ablation is that the pulse duration is significantly longer than the initiation time of the plasma. Laser-supported absorption wave due to post-ablation absorption of the laser radiation by the vapor plume and the shocked background gas plays a dominant role in the propagation and subsequently the behavior of the plasma. We demonstrate that the difference in absorption rate between UV and IR radiations leads to different propagation behaviors of the plasma produced with these radiations. The consequence is that higher electron density and temperature are observed for UV ablation. While for IR ablation, the plasma is found with lower electron density and temperature in a larger and more homogenous axial profile. The difference is also that for UV ablation, the background gas is principally evacuated by the expansion of the vapor plume as predicted by the standard piston model. While for IR ablation, the background gas is effectively mixed to the ejected vapor at least hundreds of nanoseconds after the initiation of the plasma. Our observations suggest a description by laser-supported combustion wave for the propagation of the plasma produced by UV laser, while that by laser-supported detonation wave for the propagation of the plasma produced by IR laser. Finally, practical consequences of specific expansion behavior for UV or IR ablation are discussed in terms of analytical performance promised by corresponding plasmas for application with laser-induced breakdown spectroscopy.

  15. Airborne intercomparison of vacuum ultraviolet fluorescence and tunable diode laser absorption measurements of tropospheric carbon monoxide

    NASA Astrophysics Data System (ADS)

    Holloway, John S.; Jakoubek, Roger O.; Parrish, David D.; Gerbig, Christoph; Volz-Thomas, Andreas; Schmitgen, Sandra; Fried, Alan; Wert, Brian; Henry, Bruce; Drummond, James R.

    2000-01-01

    During the fall 1997 North Atlantic Regional Experiment (NARE 97), two separate intercomparisons of aircraft-based carbon monoxide measurement instrumentation were conducted. On September 2, CO measurements were simultaneously made aboard the National Oceanic and Atmospheric Administration (NOAA) WP-3 by vacuum ultraviolet (VUV) fluorescence and by tunable diode laser absorption spectroscopy (TDLAS). On September 18, an intercomparison flight was conducted between two separate instruments, both employing the VUV fluorescence method, on the NOAA WP-3 and the U.K. Meteorological Office C-130 Hercules. The results indicate that both of the VUV fluorescence instruments and the TDLAS system are capable of measuring ambient CO accurately and precisely with no apparent interferences in 5 s. The accuracy of the measurements, based upon three independent calibration systems, is indicated by the agreement to within 11% with systematic offsets of less than 1 ppbv. In addition, one of the groups participated in the Measurement of Air Pollution From Satellite (MAPS) intercomparison [Novelli et al., 1998] with a different measurement technique but very similar calibration system, and agreed with the accepted analysis to within 5%. The precision of the measurements is indicated by the variability of the ratio of simultaneous measurements from the separate instruments. This variability is consistent with the estimated precisions of 1.5 ppbv and 2.2 ppbv for the 5 s average results of the C-130 and the WP-3 instruments, respectively, and indicates a precision of approximately 3.6% for the TDLAS instrument. The excellent agreement of the instruments in both intercomparisons demonstrates that significant interferences in the measurements are absent in air masses that ranged from 7 km in the midtroposphere to boundary layer conditions including subtropical marine air and continental outflow with embedded urban plumes. The intercomparison of the two VUV instruments that differed widely

  16. 300-mW narrow-linewidth deep-ultraviolet light generation at 193 nm by frequency mixing between Yb-hybrid and Er-fiber lasers.

    PubMed

    Xuan, Hongwen; Zhao, Zhigang; Igarashi, Hironori; Ito, Shinji; Kakizaki, Kouji; Kobayashi, Yohei

    2015-04-20

    A narrow-linewidth, high average power deep-ultraviolet (DUV) coherent laser emitting at 193 nm is demonstrated by frequency mixing a Yb-hybrid laser with an Er-fiber laser. The Yb-hybrid laser consists of Yb-fiber lasers and an Yb:YAG amplifier. The average output power of the 193 nm laser is 310 mW at 6 kHz, which corresponds to a pulse energy of 51 μJ. To the best of our knowledge, this is the highest average power and pulse energy ever reported for a narrow-linewidth 193 nm light generated by a combination of solid-state and fiber lasers with frequency mixing. We believe this laser will be beneficial for the application of interference lithography by seeding an injection-locking ArF eximer laser. PMID:25969096

  17. High-resolution three-dimensional spin- and angle-resolved photoelectron spectrometer using vacuum ultraviolet laser light

    NASA Astrophysics Data System (ADS)

    Yaji, Koichiro; Harasawa, Ayumi; Kuroda, Kenta; Toyohisa, Sogen; Nakayama, Mitsuhiro; Ishida, Yukiaki; Fukushima, Akiko; Watanabe, Shuntaro; Chen, Chuangtian; Komori, Fumio; Shin, Shik

    2016-05-01

    We describe a spin- and angle-resolved photoelectron spectroscopy (SARPES) apparatus with a vacuum-ultraviolet (VUV) laser (hν = 6.994 eV) developed at the Laser and Synchrotron Research Center at the Institute for Solid State Physics, The University of Tokyo. The spectrometer consists of a hemispherical photoelectron analyzer equipped with an electron deflector function and twin very-low-energy-electron-diffraction-type spin detectors, which allows us to analyze the spin vector of a photoelectron three-dimensionally with both high energy and angular resolutions. The combination of the high-performance spectrometer and the high-photon-flux VUV laser can achieve an energy resolution of 1.7 meV for SARPES. We demonstrate that the present laser-SARPES machine realizes a quick SARPES on the spin-split band structure of a Bi(111) film even with 7 meV energy and 0.7∘ angular resolutions along the entrance-slit direction. This laser-SARPES machine is applicable to the investigation of spin-dependent electronic states on an energy scale of a few meV.

  18. High-resolution three-dimensional spin- and angle-resolved photoelectron spectrometer using vacuum ultraviolet laser light.

    PubMed

    Yaji, Koichiro; Harasawa, Ayumi; Kuroda, Kenta; Toyohisa, Sogen; Nakayama, Mitsuhiro; Ishida, Yukiaki; Fukushima, Akiko; Watanabe, Shuntaro; Chen, Chuangtian; Komori, Fumio; Shin, Shik

    2016-05-01

    We describe a spin- and angle-resolved photoelectron spectroscopy (SARPES) apparatus with a vacuum-ultraviolet (VUV) laser (hν = 6.994 eV) developed at the Laser and Synchrotron Research Center at the Institute for Solid State Physics, The University of Tokyo. The spectrometer consists of a hemispherical photoelectron analyzer equipped with an electron deflector function and twin very-low-energy-electron-diffraction-type spin detectors, which allows us to analyze the spin vector of a photoelectron three-dimensionally with both high energy and angular resolutions. The combination of the high-performance spectrometer and the high-photon-flux VUV laser can achieve an energy resolution of 1.7 meV for SARPES. We demonstrate that the present laser-SARPES machine realizes a quick SARPES on the spin-split band structure of a Bi(111) film even with 7 meV energy and 0.7(∘) angular resolutions along the entrance-slit direction. This laser-SARPES machine is applicable to the investigation of spin-dependent electronic states on an energy scale of a few meV. PMID:27250396

  19. Investigation of the interaction of a laser pulse with a preformed Gaussian Sn plume for an extreme ultraviolet lithography source

    SciTech Connect

    Tao, Y.; Tillack, M. S.; Harilal, S. S.; Sequoia, K. L.; Najmabadi, F.

    2007-01-15

    The interaction of a laser pulse with a Sn preplasma formed by a low energy prepulse was investigated for an extreme ultraviolet (EUV) lithography light source. A much lower ion kinetic energy and nearly the same conversion efficiency from laser to in-band (2% bandwidth) 13.5 nm EUV light were simultaneously observed as compared with those from the direct interaction with a solid surface. The reason comes from the interaction of the laser pulse with a smooth preplume induced by the prepulse. The density profile of the preplume was measured with time-resolved shadowgraphy and could be fitted with a Gaussian function. The energy of the ions located at the flux peak E{sub p} scales with the length of the preplume l{sub s} as E{sub p}{proportional_to}1/l{sub s}. Laser absorption in the low-density preplume and ion acceleration during plasma expansion are discussed. This result provides a general way to control particle energy from a laser plasma interaction.

  20. Picosesond pulses in deep ultraviolet produced by a 100 kHz solid-state thin disk laser

    NASA Astrophysics Data System (ADS)

    Turčičová, H.; Novák, O.; Smrž, M.; Miura, T.; Endo, A.; Mocek, T.

    2015-05-01

    We report on the generation of 100 kHz 0.1mJ-level deep ultraviolet pulses based on frequency-quadrupled (257.5 nm) beam of a diode pumped Yb:YAG thin disk laser at the HiLASE Centre. The 100-kHz beamline used for the generation of the harmonic frequencies is operated at an average output power of 100 W level and 2 picosecond duration of pulses. The amplification of the oscillator beam is performed in a regenerative amplifier where the thin disk serves as an active mirror. The CPA technique is used for achieving high average output power of the whole system. The outcoming laser beam at 1030 nm wavelength is frequency-doubled in an LBO crystal and then frequency-quadrupled in BBO crystal, conversion efficiencies being 40% and 19%, resp. The basic characteristics of the harmonics generation in both crystals are given.

  1. Improved beam profile of a 266 nm deep ultraviolet laser employing a multi-mirror-reflected cavity

    NASA Astrophysics Data System (ADS)

    Yang, Houwen; Cheng, Wenyong; Wang, Junhua; Zhang, Yaguang; Wang, Xiaoqian; Zhang, Lijie

    2016-04-01

    A 266 nm deep ultraviolet (DUV) laser with a good Gaussian profile is reported employing a multi-mirror-reflected cavity. A type-I LiB3O5 (LBO) crystal is used to double the fundamental-light (1064 nm) wavelength generated by an actively Q-switched Nd:YVO4 laser with an intra-cavity configuration. A fourth harmonic generation (FHG) wavelength is obtained by a type-I β-BaB2O4 (BBO) crystal. The output power as high as 440 mW at 266 nm is generated under an incident power of 2.26 W at 532 nm, corresponding to the conversion efficiency of 532 nm-266 nm up to 19.5% with a repetition rate of 15 kHz and the pulse duration of 266 nm is 10.7 ns.

  2. Ultraviolet laser quantum well intermixing based prototyping of bandgap tuned heterostructures for the fabrication of superluminescent diodes

    NASA Astrophysics Data System (ADS)

    Beal, Romain; Moumanis, Khalid; Aimez, Vincent; Dubowski, Jan J.

    2016-04-01

    The ultraviolet laser induced quantum well intermixing process has been investigated for prototyping of multiple bandgap quantum well (QW) wafers designed for the fabrication of superluminescent diodes (SLDs). The process takes advantage of a krypton fluoride excimer laser (λ=248 nm) that by irradiating an InP layer capping GaInAs/GaInAsP QW heterostructure leads to the modification of its surface chemical composition and formation of point defects. A subsequent rapid thermal annealing step results in the selective area intermixing of the investigated heterostructures achieving a high quality bandgap tuned material for the fabrication of broad spectrum SLDs. The devices made from a 3-bandgap material are characterized by ~100 nm wide emission spectra with relatively flat profiles and emission exceeding 1 mW.

  3. Projected performance of rf-linac-driven free-electron lasers in the extreme-ultraviolet spectral region

    SciTech Connect

    Newman, B.E.

    1988-01-01

    A free-electron laser user facility for scientific experimentation in the vacuum-ultraviolet and soft x-ray spectral regions (together termed the XUV) is being developed at Los Alamos. The design includes a series of laser oscillators and amplifiers, driven by a single, rf-linear accelerator, that will generate broadly tunable, picosecond-pulse, coherent radiation from 1 to 400 nm. Below 300 nm, the peak- and average-power output of these FEL devices should surpass the capabilities of any existing, continuously tunable photon sources by many orders of magnitude. The design and output parameters of this facility will be described, including comparison with synchrotron radiation sources, and recent progress in developing the three primary components (electron beam, magnetic undulator, and resonator mirrors) will be reviewed. 23 refs., 2 figs., 2 tabs.

  4. Development of matrix-assisted ultraviolet laser desorption/ionization mass spectrometry for the structural analysis of glycoproteins

    SciTech Connect

    Chevrier, M.R.

    1993-01-01

    This thesis describes the design, construction and characterization of an ultraviolet laser desorption time-of-flight [TOF] mass spectrometer and its subsequent application to glycoprotein structural analysis utilizing matrix-assisted laser desorption/ionization [MALDI] mass spectrometry. At the inception of this work, commercial mass spectrometers utilizing MALDI were not available, and most reports of the phenomena utilized the 266 nm wavelength provided by frequency-quadrupled Nd:YAG lasers. This work involved the design and construction of a high-voltage-extraction linear TOF mass analyzer equipped with a multiple sample inlet system and a 337 manometer, 600 picosecond pulsed nitrogen laser. In MALDI the [open quotes]matrix[close quotes], a strong absorber of a laser wavelength, is co-crystallized with the analyte. The laser photons absorbed by the matrix lead to ionization of the analyte and subsequent desorption from the surface into the gas phase. While nicotinic acid and caffeic acid were reported as effective matrices at 266 and 355 nm, respectively, several other matrices were examined for their efficiency at 337 nm, including [alpha]-cyano-4-hydroxy cinnamic acid and gentisic acid, which proved to be advantageous for glycoconjugate analysis. Glycoproteins, phosphoproteins, nucleic acids, and proteolytic digests were all successfully analyzed using the pulsed nitrogen laser. Analysis of numerous peptides and proteins demonstrated femtomolar sensitivity, mass range in excess of 350 kiloDaltons, mass resolution circa 700, and mass accuracy better than 0.1%. The completed instrument was utilized to analyze glycopeptides for carbohydrate sites and microheterogeneity, by performing MALDI mass spectrometry [MALDI/MS] following enzymatic and chemical reactions. In many cases, unfractionated or partially fractionated mixtures were analyzed directly thereby reducing preparative chromatography.

  5. Model calculations of extreme ultraviolet gain from laser-irradiated aluminium foils

    NASA Astrophysics Data System (ADS)

    Pert, G. J.; Tallents, G. J.

    1981-05-01

    Calculations are presented on the development of gain in expanding aluminum plasmas produced by the irradiation of thin foil targets with laser radiation. The atomic physics of the expanding aluminum plasma is also considered together with the question of whether such plasmas can indeed be generated by laser irradiation of foil targets. Two-dimensional fluid code calculations are discussed to demonstrate that the model used in the atomic calculations gives a reasonable representation of the expanding laser plasma. It is pointed out that the development of the hydrogen-like ion recombination laser as an X-ray laser requires the use of ions with Z of about 25. Laser action with aluminum at 38.7 A would be an encouraging step towards X-ray laser action, being about mid-way between the current carbon fiber experiments at 182 A and true X-ray laser action at about 10 A.

  6. Two-colour pump–probe experiments with a twin-pulse-seed extreme ultraviolet free-electron laser

    PubMed Central

    Allaria, E.; Bencivenga, F.; Borghes, R.; Capotondi, F.; Castronovo, D.; Charalambous, P.; Cinquegrana, P.; Danailov, M. B.; De Ninno, G.; Demidovich, A.; Di Mitri, S.; Diviacco, B.; Fausti, D.; Fawley, W. M.; Ferrari, E.; Froehlich, L.; Gauthier, D.; Gessini, A.; Giannessi, L.; Ivanov, R.; Kiskinova, M.; Kurdi, G.; Mahieu, B.; Mahne, N.; Nikolov, I.; Masciovecchio, C.; Pedersoli, E.; Penco, G.; Raimondi, L.; Serpico, C.; Sigalotti, P.; Spampinati, S.; Spezzani, C.; Svetina, C.; Trovò, M.; Zangrando, M.

    2013-01-01

    Exploring the dynamics of matter driven to extreme non-equilibrium states by an intense ultrashort X-ray pulse is becoming reality, thanks to the advent of free-electron laser technology that allows development of different schemes for probing the response at variable time delay with a second pulse. Here we report the generation of two-colour extreme ultraviolet pulses of controlled wavelengths, intensity and timing by seeding of high-gain harmonic generation free-electron laser with multiple independent laser pulses. The potential of this new scheme is demonstrated by the time evolution of a titanium-grating diffraction pattern, tuning the two coherent pulses to the titanium M-resonance and varying their intensities. This reveals that an intense pulse induces abrupt pattern changes on a time scale shorter than hydrodynamic expansion and ablation. This result exemplifies the essential capabilities of the jitter-free multiple-colour free-electron laser pulse sequences to study evolving states of matter with element sensitivity. PMID:24048228

  7. Low absorption loss p-AlGaN superlattice cladding layer for current-injection deep ultraviolet laser diodes

    NASA Astrophysics Data System (ADS)

    Martens, M.; Kuhn, C.; Ziffer, E.; Simoneit, T.; Kueller, V.; Knauer, A.; Rass, J.; Wernicke, T.; Einfeldt, S.; Weyers, M.; Kneissl, M.

    2016-04-01

    Current injection into AlGaN-based laser diode structures with high aluminum mole fractions for deep ultraviolet emission is investigated. The electrical characteristics of laser diode structures with different p-AlGaN short period superlattice (SPSL) cladding layers with various aluminum mole fractions are compared. The heterostructures contain all elements that are needed for a current-injection laser diode including cladding and waveguide layers as well as an AlGaN quantum well active region emitting near 270 nm. We found that with increasing aluminum content in the p-AlGaN cladding, the diode turn-on voltage increases, while the series resistance slightly decreases. By introducing an SPSL instead of bulk layers, the operating voltage is significantly reduced. A gain guided broad area laser diode structure with transparent p-Al0.70Ga0.30N waveguide layers and a transparent p-cladding with an average aluminum content of 81% was designed for strong confinement of the transverse optical mode and low optical losses. Using an optimized SPSL, this diode could sustain current densities of more than 4.5 kA/cm2.

  8. Ultrafast, high repetition rate, ultraviolet, fiber-laser-based source: application towards Yb+ fast quantum-logic.

    PubMed

    Hussain, Mahmood Irtiza; Petrasiunas, Matthew Joseph; Bentley, Christopher D B; Taylor, Richard L; Carvalho, André R R; Hope, Joseph J; Streed, Erik W; Lobino, Mirko; Kielpinski, David

    2016-07-25

    Trapped ions are one of the most promising approaches for the realization of a universal quantum computer. Faster quantum logic gates could dramatically improve the performance of trapped-ion quantum computers, and require the development of suitable high repetition rate pulsed lasers. Here we report on a robust frequency upconverted fiber laser based source, able to deliver 2.5 ps ultraviolet (UV) pulses at a stabilized repetition rate of 300.00000 MHz with an average power of 190 mW. The laser wavelength is resonant with the strong transition in Ytterbium (Yb+) at 369.53 nm and its repetition rate can be scaled up using high harmonic mode locking. We show that our source can produce arbitrary pulse patterns using a programmable pulse pattern generator and fast modulating components. Finally, simulations demonstrate that our laser is capable of performing resonant, temperature-insensitive, two-qubit quantum logic gates on trapped Yb+ ions faster than the trap period and with fidelity above 99%. PMID:27464118

  9. Ultraviolet pulsed laser irradiation of multi-walled carbon nanotubes in nitrogen atmosphere

    SciTech Connect

    Pérez del Pino, Ángel Cabana, Laura; Tobias, Gerard; György, Enikö; Ballesteros, Belén

    2014-03-07

    Laser irradiation of randomly oriented multi-walled carbon nanotube (MWCNT) networks has been carried out using a pulsed Nd:YAG UV laser in nitrogen gas environment. The evolution of the MWCNT morphology and structure as a function of laser fluence and number of accumulated laser pulses has been studied using electron microscopies and Raman spectroscopy. The observed changes are discussed and correlated with thermal simulations. The obtained results indicate that laser irradiation induces very fast, high temperature thermal cycles in MWCNTs which produce the formation of different nanocarbon forms, such as nanodiamonds. Premelting processes have been observed in localized sites by irradiation at low number of laser pulses and low fluence values. The accumulation of laser pulses and the increase in the fluence cause the full melting and amorphization of MWCNTs. The observed structural changes differ from that of conventional high temperature annealing treatments of MWCNTs.

  10. Crystallization of fused silica surfaces by ultra-violet laser irradiation

    NASA Astrophysics Data System (ADS)

    Hirata, Kazuya; Haraguchi, Koshi

    2012-07-01

    In recent years, the increased use of high power lasers has created problems in optical elements due to laser damage. The International Organization for Standardization (ISO) describes in a publication ISO 11254 a laser-power resilience (LPR) test which we used to verify that by flattening the glass substrate of an optical element, we could improve the resistance to laser damage. We report on an evaluation of two types of samples of fused silica substrate whose surface roughness differed (Ra = 0.20 nm and Ra = 0.13 nm) using customized on-line laser damage testing. To induce laser damage to samples, we used the fifth harmonic generation from a Nd:YAG pulse laser (wavelength: 213 nm, pulse width: 4 ns, repetition frequency: 20 Hz). Results show that flattening reduced the progression of laser damage in the meta-phase laser damage phase by 1/3 of that without flattening. However, pro-phase laser damage which started at fluence 2.39 J/cm2 was unrelated to surface roughness. To analyze the pro-phase laser damage, we used x-ray diffraction (XRD), Raman spectroscopy, and variable pressure-type scanning electron microscopy (VP-SEM). From XRD data, we observed XRD patterns of cristobalite (111), cristobalite (102), α-quartz (111), and β-quartz (102). Raman spectrum data showed an increase in the three-membered ring vibration (600 cm-1), four-membered ring vibration (490 cm-1), and many-membered ring vibration (450 cm-1, 390 cm-1, and 300 cm-1). We observed patchy crystallized areas on the sample surfaces in the VP-SEM images. Based on these experimental results, we believe that the dominant factors in pro-phase laser damage are their physical properties. Substrate and thin film material must be appropriately selected in producing an optical element with a high level of resilience to laser exposure.

  11. Low-debris efficient laser-produced plasma extreme ultraviolet source by use of a regenerative liquid microtarget containing tin nanoparticles

    NASA Astrophysics Data System (ADS)

    Higashiguchi, Takeshi; Dojyo, Naoto; Senba, Yusuke; Suetake, Sumihiro; Katto, Masahito; Kubodera, Shoichi

    2007-05-01

    We demonstrated a debris-free, efficient laser-produced plasma extreme ultraviolet (EUV) source by use of a regenerative liquid microjet target containing tin-dioxide (SnO II) nano-particles. By using a low SnO II concentration (6%) solution and dual laser pulses for the plasma control, we observed the EUV conversion efficiency of 1.2% with undetectable debris.

  12. Enhancement of conversion efficiency of extreme ultraviolet radiation from a liquid aqueous solution microjet target by use of dual laser pulses

    NASA Astrophysics Data System (ADS)

    Higashiguchi, Takeshi; Dojyo, Naoto; Hamada, Masaya; Kawasaki, Keita; Sasaki, Wataru; Kubodera, Shoichi

    2006-03-01

    We demonstrated a debris-free, efficient laser-produced plasma extreme ultraviolet (EUV) source by use of a regenerative liquid microjet target containing tin-dioxide (SnO II) nano-particles. By using a low SnO II concentration (6%) solution and dual laser pulses for the plasma control, we observed the EUV conversion efficiency of 1.2% with undetectable debris.

  13. Theoretical evaluation of electron-beam-excited vacuum-ultraviolet F2 lasers

    NASA Astrophysics Data System (ADS)

    Kim, Y.-P.; Obara, M.; Suzuki, T.

    1986-03-01

    A theoretical kinetic model for an electron-beam-excited F2 laser (157 nm) was successfully developed to evaluate the performance characteristics in terms of electron-beam excitation rate, pumping pulse width, and total operating pressure. As a result, it is made clear that a high excitation rate (above 0.2 MW/cu cm atm) is essential to obtain efficient laser operation. An intrinsic laser efficiency of 4.3 percent is obtainable when a 6.5-atm mixture of He-F2 = 1000/1 is pumped at an excitation rate of 0.5 MW/cu cm atm, giving a laser output of over 4 J/l. It is also found that a higher laser output is obtainable with increasing total operating pressure, while the intrinsic laser efficiency slowly decreases.

  14. Optical injection and spectral filtering of high-power ultraviolet laser diodes.

    PubMed

    Schäfer, V M; Ballance, C J; Tock, C J; Lucas, D M

    2015-09-15

    We demonstrate injection locking of high-power laser diodes operating at 397 nm. We achieve stable operation with an injection power of ∼100  μW and a slave laser output power of up to 110 mW. We investigate the spectral purity of the slave laser light via photon scattering experiments on a single trapped (40)Ca(+) ion. We show that it is possible to achieve a scattering rate indistinguishable from that of monochromatic light by filtering the laser light with a diffraction grating to remove amplified spontaneous emission. PMID:26371912

  15. Angular ion emission characteristics of a laser triggered tin vacuum arc as light source for extreme ultraviolet lithography

    NASA Astrophysics Data System (ADS)

    Verbraak, Harald; Küpper, Felix; Jonkers, Jeroen; Bergmann, Klaus

    2010-11-01

    The angular resolved emission of tin ions from a laser triggered vacuum arc to be used as light source for extreme ultraviolet lithography is presented. Ion energies of more than 200 keV for emission angles up to 50° with respect to the optical axis are observed. The angular emission characteristic is strongly anisotropic with a pronounced peak for fast ions into a cone with an opening angle of roughly 10° at an angle of 35° with respect to the optical axis. These ions also exhibit a distinct energy distribution function compared to the more isotropic emitted bulk of ions, which can be referred to different mechanisms of production. Looking at the discharge current parameters, the production of the directed fast ions can be connected with a peaked increase in the impedance, which gives hint to a plasma instability as origin of those ions. The emission of isotropic emitted ions is in agreement with a model of plasma expansion into vacuum. The emission characteristic is also strongly dependent on the parameter of the trigger laser. It is shown that using a double trigger laser pulse the fast ion production can be suppressed by more than one order of magnitude.

  16. Characterization of extreme ultraviolet light-emitting plasmas from a laser-excited fluorine containing liquid polymer jet target

    NASA Astrophysics Data System (ADS)

    Abel, B.; Assmann, J.; Faubel, M.; Gäbel, K.; Kranzusch, S.; Lugovoj, E.; Mann, K.; Missalla, T.; Peth, Ch.

    2004-06-01

    The operation of a liquid polymer jet laser-plasma target and the characterization of the absolute x-ray emission in the extreme ultraviolet wavelength window from 9-19 nm is reported. The target is a liquid polymer (perfluoro-polyether) that is exposed to pulsed and focused laser light at 532 nm in the form of a thin, liquid microjet (d=40 to 160 μm) in vacuum. The spectral brightness of the source in the 13 nm range is relatively high because a large fraction of radiative energy is emitted in one single line only, which is assigned to be the 2p-3d FVII doublet at 12.8 nm, with a laser energy conversion efficiency of 0.45% (2π sr, 2% bandwidth) in our initial experiment. A further increase of the relative emission has been found in the wavelength range between 7 and 17 nm when the jet diameter was increased from 40 to 160 μm. The two-dimensional spatial profile of the source plasma (d=40 to 50 μm) has been analyzed with a pinhole camera.

  17. Chlorine detection in cement with laser-induced breakdown spectroscopy in the infrared and ultraviolet spectral range

    NASA Astrophysics Data System (ADS)

    Gehlen, Christoph Dominic; Wiens, Eugen; Noll, Reinhard; Wilsch, Gerd; Reichling, Kenji

    2009-10-01

    A significant parameter to monitor the status of concrete buildings like bridges or parking garages is the determination of the depth profile of the chlorine concentration below the exposed concrete surface. This information is required to define the needed volume of restoration for a construction. Conventional methods like wet chemical analysis are time- and cost-intensive so an alternative method is developed using laser-induced breakdown spectroscopy (LIBS). The idea is to deploy LIBS to analyze drill cores by scanning the sample surface with laser pulses. Chlorine spectral lines in the infrared (IR) and ultraviolet (UV)-range were studied for chlorine detection in hydrated cement samples. The excitation energies of these spectral lines are above 9.2 eV. Hence high plasma temperatures and pulse energies in the range of some hundred millijoules are needed to induce sufficient line intensity levels at the required working distance. To further increase the line intensity and to lower the detection limit (LOD) of chlorine a measuring chamber is used where different ambient pressures and gases can be chosen for the measurements. The influences on the line intensity for pressures between 5 mbar and 400 mbar using helium as process gas and the influence of different laser burst modi like single and collinear double pulses are investigated. For the first time a LOD according to DIN 32 645 of 0.1 mass% was achieved for chlorine in hydrated cement using the UV line 134.72 nm.

  18. Ultraviolet nanosecond laser-assisted micro-modifications in lithium niobate monitored by Nd3+ luminescence

    NASA Astrophysics Data System (ADS)

    Ródenas, A.; Jaque, D.; Molpeceres, C.; Lauzurica, S.; Ocaña, J. L.; Torchia, G. A.; Agulló-Rueda, F.

    2007-04-01

    This work reports on the microstructural modifications produced by nanosecond ultraviolet ablation in neodymium doped lithium niobate crystals. The neodymium ions have been used as optical probes to determine the extension and nature of the modified bulk material. From micro-luminescence experiments we have been able to determine the spatial distribution of the UV ablation induced material densification, local disorder and defect creation. Results have been compared to those previously obtained from femtosecond irradiated lithium niobate crystals.

  19. Operation of a free electron laser in the wavelength range from the extreme ultraviolet to the water window

    SciTech Connect

    Ackermann, W.; Asova, G.; Ayvazyan, V.; Azima, A.; Baboi, N.; Bahr, J.; Balandin, V.; Beutner, B.; Brandt, A.; Bolzmann, A.; Brinkmann, R.; /DESY /Dubna, JINR

    2007-01-01

    We report results on the performance of a free-electron laser operating at a wavelength of 13.7 nm where unprecedented peak and average powers for a coherent extreme-ultraviolet radiation source have been measured. In the saturation regime, the peak energy approached 170 J for individual pulses, and the average energy per pulse reached 70 J. The pulse duration was in the region of 10 fs, and peak powers of 10 GW were achieved. At a pulse repetition frequency of 700 pulses per second, the average extreme-ultraviolet power reached 20 mW. The output beam also contained a significant contribution from odd harmonics of approximately 0.6% and 0.03% for the 3rd (4.6 nm) and the 5th (2.75 nm) harmonics, respectively. At 2.75 nm the 5th harmonic of the radiation reaches deep into the water window, a wavelength range that is crucially important for the investigation of biological samples.

  20. Pulse laser deposition of epitaxial TiO2 thin films for high-performance ultraviolet photodetectors

    NASA Astrophysics Data System (ADS)

    Zhang, Zifeng; Wong, Lai Mun; Zhang, Zhiwei; Wu, Zhengyun; Wang, Shijie; Chi, Dongzhi; Hong, Rongdun; Yang, Weifeng

    2015-11-01

    The authors report on high quality TiO2 epilayers grown on lattice-matched LaAlO3 substrates by pulsed laser deposition. A prototype of metal-semiconductor-metal ultraviolet (UV) photodetector based on TiO2 was fabricated by employing Au as the Schottky contact metal. The UV-visible transmittance spectrum of the TiO2 epilayer and the spectral response of the photodetector reveal that the deposited anatase TiO2 thin film exhibits excellent visible-blind UV characteristics with an optical bandgap of 3.25 eV. In addition, the fabricated photodetector exhibits a high UV-to-visible rejection ratio (R270 nm/R400 nm) of 105 while displaying a low dark current of 0.25 pA under 5 V bias and a high responsivity of 0.21 A/W, suggesting a potential application in UV photodetection.

  1. Transient charge dynamics in argon-cluster nanoplasmas created by intense extreme-ultraviolet free-electron-laser irradiation

    NASA Astrophysics Data System (ADS)

    Iwayama, H.; Harries, J. R.; Shigemasa, E.

    2015-02-01

    We present extreme-ultraviolet (EUV) fluorescence spectra of Ar clusters irradiated by intense EUV free-electron-laser (FEL) pulses focused to intensities of up to 3 ×1013W /cm2 at a wavelength of 51 nm. The spectra reveal fluorescence at wavelengths shorter than that of the incident radiation, which can be assigned to EUV fluorescence lines from excited multiply charged ions A rz +* with z as high as 6. This demonstrates that charge states as high as 7+ are produced by the FEL irradiation. The dependence of the spectra on cluster size shows that the highly charged ions are generated at the cluster surface, indicating inhomogeneous charging. The FEL power dependencies of the spectral features suggest that the inhomogeneous distribution of charge within the clusters reduces ionization thresholds at the cluster surface.

  2. Ionization of pesticides using a far-ultraviolet femtosecond laser in gas chromatography/time-of-flight mass spectrometry.

    PubMed

    Hashiguchi, Yuichi; Zaitsu, Shin-ichi; Imasaka, Totaro

    2013-09-01

    The fourth harmonic emission (200 nm) of a femtosecond Ti:sapphire laser (35 fs) was generated and used in the multiphoton ionization of 49 pesticides in gas chromatography/time-of-flight mass spectrometry. The limit of detection was improved when the ionization source from the third harmonic emission (267 nm) was replaced with the fourth harmonic emission for several pesticide molecules that contained no conjugated double bonds since their absorption bands are located in the far-ultraviolet region. This analytical instrument was used in the analysis of a series of real samples including potatoes, carrots, and cabbage, and a signal suspected to arise from di-allate was observed for the potato sample. ᅟ PMID:23624954

  3. Development of Extreme Ultraviolet Radiation Source using Laser Triggered Vacuum Spark Discharge Plasma

    SciTech Connect

    Watanabe, Masato; Yamada, Junzaburo; Zhu Qiushi; Hotta, Eiki

    2009-01-21

    A laser triggerd discharge produced Sn plasma light source has been developed. Experimental parameters such as electrode separation and laser irradiation power are varied to optimize EUV emission power. It is clear that the maximum EUV radiation was occurred in the position where the pinch was observed.

  4. Fabrication of electrodes on the aluminum doped zinc oxide thin films using an ultraviolet laser direct-patterning technology

    NASA Astrophysics Data System (ADS)

    Hsiao, Wen-Tse; Tseng, Shih-Feng; Kuo, Chao-Hui; Huang, Kuo-Cheng; Chiang, Donyau; Yao, Pin-Chiun; Chen, Ming-Fei

    Because transparent conductive oxide (TCO) thin films have more than 80% transmittance in visible spectrum, and high electrical conductivity, the TCO films are widely applied to flat panel displays and solar cells as transparent electrode materials. This study aims to develop a direct patterning technology on ZnO:Al (AZO) thin films by a diode-pumped solid state ultraviolet laser. The electrode patterns with array structures on AZO thin films were generated by a high-speed galvanometric scanning system. The optoelectronic properties of a patterned electrode have strong relation with the laser pulse frequency, the scan speed, and the patterning time. The surface morphology and roughness of patterned electrode were measured by three dimension confocal microscope and field emission scanning electron microscope, respectively. The resistivity of AZO thin films before and after laser patterning was measured by a four point probe instrument. The optical transmittance was recorded by a UV/VIS/NIR spectrophotometer. The experimental results indicated that the edge line width and depth decreased with increasing the scan speed. After the array patterns structure were formed by laser dry etching, the roughness Ra values of patterned area increased from 0.06 μm to 0.16 μm. These transmittances of patterned structure from 400 nm to 800 nm wavelengths averagely reached to 82%. The measured results of electrical conductively revealed that the resistivity gradually increased with increasing the pulse repetition frequency. In addition, surface morphologic examination on the straight lines, corners, and etched regions of patterned films revealed no micro-cracks observed which meant the patterned surface had a better surface quality.

  5. Large TE polarized optical gain from AlInN-delta-GaN quantum well for ultraviolet lasers

    NASA Astrophysics Data System (ADS)

    Liu, Cheng; Ooi, Yu Kee; Zhang, Jing

    2016-03-01

    Ultraviolet (UV) lasers with wavelength (λ) < 300 nm have important applications in free-space communication, water/air purification, and biochemical agent detection. Conventionally, AlGaN quantum wells (QWs) are widely used as active region for UV lasers. However, high-efficiency electrically injected mid-UV lasers with λ ~ 250-300 nm are still very challenging as the corresponding AlGaN QWs suffer from severe band-mixing effect due to the presence of the valence sub-band crossover between the heavy-hole (HH) and crystal-field split off (CH) sub-bands, which would result in very low optical gain in such wavelength regime. Therefore, in this work, we propose and investigate the use of AlInN material system as an alternative for mid-UV lasers. Nanostructure engineering by the use of AlInN-delta-GaN QW has been performed to enable dominant conduction band - HH sub-band transition as well as optimized electron-hole wave function overlap. The insertion of the ultra-thin delta-GaN layer, which is lattice-matched to Al0.82In0.18N layer, would localize the wave functions strongly toward the center of the active region, leading to large transverse electric (TE) polarized optical gain (gTE) for λ~ 250- 300 nm. From our finding, the use of AlInN-delta-GaN QW resulted in ~ 3-times enhancement in TE-polarized optical gain, in comparison to that of conventional AlGaN QW, for gain media emitting at ~ 255 nm. The peak emission wavelength can be tuned by varying the delta layer thickness while maintaining large TE gain. Specifically, gTE ~ 3700 cm-1 was obtained for λ ~ 280-300 nm, which are very challenging for conventional AlGaN QW active region.

  6. Quantitative Detection of Combustion Species using Ultra-Violet Diode Lasers

    NASA Technical Reports Server (NTRS)

    Pilgrim, J. S.; Peterson, K. A.

    2001-01-01

    Southwest Sciences is developing a new microgravity combustion diagnostic based on UV diode lasers. The instrument will allow absolute concentration measurements of combustion species on a variety of microgravity combustion platforms including the Space Station. Our approach uses newly available room temperature UV diode lasers, thereby keeping the instrument compact, rugged and energy efficient. The feasibility of the technique was demonstrated by measurement of CH radicals in laboratory flames. Further progress in fabrication technology of UV diode lasers at shorter wavelengths and higher power will result in detection of transient species in the deeper UV. High sensitivity detection of combustion radicals is provided with wavelength modulation absorption spectroscopy.

  7. Photosensitive GeO2-SiO2 films for ultraviolet laser writing of channel waveguides and bragg gratings with Cr-loaded waveguide structure.

    PubMed

    Takahashi, Masahide; Sakoh, Akifumi; Ichii, Kentaro; Tokuda, Yomei; Yoko, Toshinobu; Nishii, Junji

    2003-08-01

    Irradiation with intense ultraviolet laser pulses induced a large refractive-index change in 30GeO2-70SiO2 waveguide-grade thin films prepared by the plasma-enhanced chemical vapor deposition method, which contained a large amount of photoactive Ge2+ defects. The maximum index change in the as-deposited films by KrF and XeF excimer laser irradiation was estimated to be 1.2 x 10(-3) and 0.28 x 10(-3), respectively. These results clearly indicate that the photorefractivity of GeO2-SiO2 glasses is due to a Ge2+ defect in origin. The channel waveguide and the planar Bragg gratings were directly written in the photoactive Ge(2+)-enriched GeOs-SiO2 thin films by pulsed ultraviolet laser irradiation with a Cr-metal-loaded-type waveguide structure. PMID:12916627

  8. Efficient 13.5 nm extreme ultraviolet emission from Sn plasma irradiated by a long CO{sub 2} laser pulse

    SciTech Connect

    Tao, Y.; Tillack, M. S.; Sequoia, K. L.; Burdt, R. A.; Yuspeh, S.; Najmabadi, F.

    2008-06-23

    The effect of pulse duration on in-band (2% bandwidth) conversion efficiency (CE) from a CO{sub 2} laser to 13.5 nm extreme ultraviolet (EUV) light was investigated for Sn plasma. It was found that high in-band CE, 2.6%, is consistently obtained using a CO{sub 2} laser with pulse durations from 25 to 110 ns. Employing a long pulse, for example, 110 ns, in a CO{sub 2} laser system used in an EUV lithography source could make the system significantly more efficient, simpler, and cheaper as compared to that using a short pulse of 25 ns or shorter.

  9. Study of superalloy topography during ultrahigh intensity nanosecond ultraviolet laser ablation

    NASA Astrophysics Data System (ADS)

    Wu, Qihong; Jie, Jiansheng; Ma, Yurong; Yu, Qingxuan; Miao, Bin; Wang, Guanzhong; Liao, Yuan; Fang, Rongchuan; Chen, Xiangli; Wang, Kelvin

    2002-05-01

    We report on the topography of holes ablated by an ultrahigh intensity 355 and 266 nm laser with 8 ns pulse width in Ni-base superalloy Inconel 718. The origin of droplets, micropores, and microcracks on the surface of hole is identified. Qualitative differences in the characteristics of microcracks indicate that the dominant continuous microcracks result from thermal effects in 355 nm laser ablation, and the dominant island-chain microcrack result from photochemical effects in 266 nm laser ablation. In ultrahigh intensity laser ablation (>200 GW/cm2), the mechanical load on the surface is very significant to the resulting topography, and the grain boundary plays an important role in the origin of the micropores.

  10. Intense Underwater Laser Propagation and Ionization at Visible and Ultraviolet Wavelengths

    NASA Astrophysics Data System (ADS)

    Jones, Ted; Kaganovich, Dmitri; Helle, Mike; Ting, Tony; Palastro, John; Hafizi, Bahman; Gordon, Dan; Penano, Joe; Chen, Yu-Hsin

    2015-11-01

    Intense underwater laser propagation, filamentation, and ionization are under investigation at NRL for applications including remote laser acoustic generation for low-frequency sonar. Time-resolved absorption spectroscopy of fs underwater laser ionization revealed hydrated electron density of 5.4 x 1018 cm-3 and lifetime of 350 ps. In addition, high-resolution fluorescence imaging of ns underwater laser propagation using two-photon absorbing dye, independently confirmed previous measurements of 100 micron diameter filament structures [Helle et al., Appl. Phys. Lett. 103, 121101]. A patented scheme for generating an elongated, meter-scale, high energy density underwater plasma [USP 9,088,123] is under study, in which such a filament structure could serve as a target for a second energetic ``heater'' laser pulse. Early experiments suggested improved ionization efficiency using the current configuration, with a 266 nm filament pulse, and a 532 nm heater pulse. 1- and 2-D simulations using a nonlinear laser propagation code are underway to predict beam envelope propagation, filamentation, and stimulated Raman and Brillouin scattering behavior. Results from recent experiments and simulations will be presented. This work is supported by NRL Base Funds.

  11. Characterization of electrically-active defects in ultraviolet light-emitting diodes with laser-based failure analysis techniques

    NASA Astrophysics Data System (ADS)

    Miller, Mary A.; Tangyunyong, Paiboon; Cole, Edward I.

    2016-01-01

    Laser-based failure analysis techniques demonstrate the ability to quickly and non-intrusively screen deep ultraviolet light-emitting diodes (LEDs) for electrically-active defects. In particular, two laser-based techniques, light-induced voltage alteration and thermally-induced voltage alteration, generate applied voltage maps (AVMs) that provide information on electrically-active defect behavior including turn-on bias, density, and spatial location. Here, multiple commercial LEDs were examined and found to have dark defect signals in the AVM indicating a site of reduced resistance or leakage through the diode. The existence of the dark defect signals in the AVM correlates strongly with an increased forward-bias leakage current. This increased leakage is not present in devices without AVM signals. Transmission electron microscopy analysis of a dark defect signal site revealed a dislocation cluster through the pn junction. The cluster included an open core dislocation. Even though LEDs with few dark AVM defect signals did not correlate strongly with power loss, direct association between increased open core dislocation densities and reduced LED device performance has been presented elsewhere [M. W. Moseley et al., J. Appl. Phys. 117, 095301 (2015)].

  12. A Study of the Laser-Induced Breakdown Spectroscopy of Carbon in the Ultraviolet Wavelength Range Under Vacuum Conditions

    NASA Astrophysics Data System (ADS)

    Pan, Congyuan; Du, Xuewei; Zeng, Qiang; Yu, Yunsi; Wang, Shengbo; Wang, Qiuping

    2015-08-01

    The influence of a vacuum on the laser-induced breakdown spectroscopy (LIBS) of carbon in the ultraviolet wavelength range is studied. Experiments are performed with graphite using a LIBS system, which consists of a 1064 nm Nd:YAG laser, a vacuum pump, a spectrometer and a vacuum chamber. The vacuum varies from 10 Pa to 1 atm. Atomic lines as well as singly and doubly charged ions are confirmed under the vacuums. A temporal evolution analysis of intensity is performed for the atomic lines of C I 193.09 nm and C I 247.86 nm under different vacuum conditions. Both time-integrated and time-resolved intensity evolutions under vacuums are achieved. The lifetimes of the two atomic lines have similar trends, which supports the point of view of a ‘soft spot’. Variations of plasma temperature and electron density under different vacuums are measured. This study is helpful for research on carbon detection using LIBS under vacuum conditions. supported by the National Special Fund for the Development of Major Research Equipment and Instruments of China (No. 2014YQ120351)

  13. Characterization of electrically-active defects in ultraviolet light-emitting diodes with laser-based failure analysis techniques

    DOE PAGESBeta

    Miller, Mary A.; Tangyunyong, Paiboon; Edward I. Cole, Jr.

    2016-01-12

    In this study, laser-based failure analysis techniques demonstrate the ability to quickly and non-intrusively screen deep ultraviolet light-emitting diodes(LEDs) for electrically-active defects. In particular, two laser-based techniques, light-induced voltage alteration and thermally-induced voltage alteration, generate applied voltage maps (AVMs) that provide information on electrically-active defect behavior including turn-on bias, density, and spatial location. Here, multiple commercial LEDs were examined and found to have dark defect signals in the AVM indicating a site of reduced resistance or leakage through the diode. The existence of the dark defect signals in the AVM correlates strongly with an increased forward-bias leakage current. This increasedmore » leakage is not present in devices without AVM signals. Transmission electron microscopyanalysis of a dark defect signal site revealed a dislocation cluster through the pn junction. The cluster included an open core dislocation. Even though LEDs with few dark AVM defect signals did not correlate strongly with power loss, direct association between increased open core dislocation densities and reduced LED device performance has been presented elsewhere [M. W. Moseley et al., J. Appl. Phys. 117, 095301 (2015)].« less

  14. Time-resolved detection of aromatic compounds on planetary surfaces by ultraviolet laser induced fluorescence and Raman spectroscopy

    NASA Astrophysics Data System (ADS)

    Eshelman, E.; Daly, M. G.; Slater, G.; Cloutis, E.

    2015-12-01

    Raman spectroscopic instruments are highly capable in the search for organics on Mars due to the potential to perform rapid and nondestructive measurements on unprepared samples. Upcoming and future Raman instruments are likely to also incorporate laser-induced fluorescence (LIF) capabilities, which can be added for modest cost and complexity. We demonstrate that it is possible to obtain sub-ns fluorescence lifetime measurements of Mars-relevant organics and minerals if a fast time-gating capability is used with an intensified detector and a short ultraviolet laser pulse. This serves a primary purpose of discriminating mineral from short-lived (less than 10 ns) organic fluorescence, considered a potential biosignature. Additionally, lifetime measurements may assist in determining if more than one fluorescing species is present and provide information concerning the molecular structure as well as the local environment. Fast time-gating is also useful at longer visible or near-IR wavelengths, as this approach increases the sensitivity of the instrument to organic material by removing the majority of the fluorescence background from the Raman signal and reducing the effect of ambient light.

  15. Surface patterning of multilayer graphene by ultraviolet laser irradiation in biomolecule sensing devices

    NASA Astrophysics Data System (ADS)

    Chang, Tien-Li; Chen, Zhao-Chi

    2015-12-01

    The study presents a direct process for surface patterning of multilayer graphene on the glass substrate as a biosensing device. In contrast to lithography with etching, the proposed process provides simultaneous surface patterning of multilayer graphene through nanosecond laser irradiation. In this study, the multilayer graphene was prepared by a screen printing process. Additionally, the wavelength of the laser beam was 355 nm. To perform the effective laser process with the small heat affected zone, the surface patterns on the sensing devices could be directly fabricated using the laser with optimal control of the pulse overlap at a fluence threshold of 0.63 J/cm2. The unique patterning of the laser-ablated surface exhibits their electrical and hydrophilic characteristics. The hydrophilic surface of graphene-based sensing devices was achieved in the process with the pulse overlap of 90%. Furthermore, the sensing devices for controlling the electrical response of glucose by using glucose oxidase can be used in sensors in commercial medical applications.

  16. Increased wavelength options in the visible and ultraviolet for Raman lasers operating on dual Raman modes.

    PubMed

    Mildren, R P; Piper, J A

    2008-03-01

    We report increased wavelength options from Raman lasers for Raman media having two Raman modes of similar gain coefficient. For an external-cavity potassium gadolinium tungstate Raman laser pumped at 532 nm, we show that two sets of Stokes orders are generated simultaneously by appropriate orientation of the Raman crystal, and also wavelengths that correspond to sums of the two Raman modes. Up to 14 visible Stokes lines were observed in the wavelength range 555-675 nm. The increase in Stokes wavelengths also enables a much greater selection of wavelengths to be accessed via intracavity nonlinear sum frequency and difference frequency mixing. For example, we demonstrate 30 output wavelength options for a wavelength-selectable 271-321 nm Raman laser with intracavity sum frequency mixing in BBO. We also present a theoretical analysis that enables prediction of wavelength options for dual Raman mode systems. PMID:18542414

  17. Experimental station to study the interaction of intense femtosecond vacuum ultraviolet pulses with matter at TTF1 free electron laser

    NASA Astrophysics Data System (ADS)

    Sobierajski, R.; Krzywinski, J.; Andrejczuk, A.; Hahn, U.; Treusch, R.; Jurek, M.; Klinger, D.; Nietubyć, R.; Pełka, J. B.; Reniewicz, H.; Sikora, M.; Sobala, W.

    2005-01-01

    An experimental station to study the interaction of intense femtosecond vacuum ultraviolet pulses generated by the TTF1 free electron laser (FEL) (DESY, Germany) with solids was developed. The vacuum chamber, the sample holder and the detectors had been designed to fulfill strong constraints caused both by the unique properties of the interacting radiation and by TTF1 FEL innovative design. The applied mounting system allowed one to move and rotate the samples precisely with 4degrees of freedom and to heat them up to the maximal temperature of 1000K. In order to accomplish the in situ growth of thin metallic layers on the sample surfaces, evaporation cells had been installed in the vacuum chamber. A time-of-flight apparatus capable of recording both electrons and ions excited on the solid surfaces by the laser pulses had been included in the chamber design. A pulse energy monitor had been placed in the laser beam outside the experimental chamber. A second energy detector had been mounted inside the chamber on a rotational arm, permitting the angular resolved reflectivity measurements. The detectors placed in the chamber enabled a real-time study both of the ionized damage products and the reflected light from the interaction place on the sample surfaces. The measurements were made with respect to the primary beam incident angle and energy. Examples of the experimental results as well as an off-line analysis are presented. The usability of constructed experimental system to study of the interaction of intense, femtosecond pulses with solid matter is demonstrated.

  18. Ultraviolet and infrared femtosecond laser induced periodic surface structures on thin polymer films

    NASA Astrophysics Data System (ADS)

    Rebollar, Esther; Vázquez de Aldana, Javier R.; Pérez-Hernández, José A.; Ezquerra, Tiberio A.; Moreno, Pablo; Castillejo, Marta

    2012-01-01

    This work demonstrates the formation of femtosecond laser induced periodic surface structures (LIPSS) by multipulse irradiation with the fundamental and 3rd harmonic of a linearly polarized Ti:sapphire laser (795 and 265 nm) on thin films of the polymers poly (ethylene terephthalate), poly (trimethylene terephthalate), and poly (carbonate bisphenol A) prepared by spin-coating. LIPSS, inspected by atomic force microscopy, are formed upon multiple pulse UV and IR irradiation with wavelength-sized period in a narrow range of fluences below the ablation threshold. Control and tunability of the size and morphology of the periodic structures become thus possible ensuring photochemical integrity of polymer films.

  19. Superficial and Shroud-like coloration of linen by short laser pulses in the vacuum ultraviolet.

    PubMed

    Di Lazzaro, Paolo; Murra, Daniele; Nichelatti, Enrico; Santoni, Antonino; Baldacchini, Giuseppe

    2012-12-20

    We present a survey on five years of experiments of excimer laser irradiation of linen fabrics, seeking a coloration mechanism able to reproduce the microscopic complexity of the body image embedded onto the Shroud of Turin. We achieved a superficial, Shroud-like coloration in a narrow range of irradiation parameters. We also obtained latent coloration that appears after artificial or natural aging of linen following laser irradiations that, at first, did not generate any visible effect. Most importantly, we have recognized photochemical processes that account for both coloration and latent coloration. PMID:23262596

  20. Efficient pulse amplification using a transverse-flow CO2 laser for extreme ultraviolet light source.

    PubMed

    Tanino, Yoichi; Yamamoto, Tatsuya; Nishimae, Junichi; Fujikawa, Shuichi

    2012-08-15

    We constructed a master oscillator power amplifier CO2 laser system using a transverse-flow, RF-pumped CW CO2 laser. We carried out an amplification test at a 100% duty cycle of pumping discharge with the electrical input for the discharge up to 60 kW. An output power of 1.90 kW was achieved at the oscillator repetition rate of 100 kHz and the optical input power of 13 W. The electrical-to-optical efficiency was 3.1%. PMID:23381237

  1. Ultraviolet and infrared femtosecond laser induced periodic surface structures on thin polymer films

    SciTech Connect

    Rebollar, Esther; Castillejo, Marta; Vazquez de Aldana, Javier R.; Moreno, Pablo

    2012-01-23

    This work demonstrates the formation of femtosecond laser induced periodic surface structures (LIPSS) by multipulse irradiation with the fundamental and 3rd harmonic of a linearly polarized Ti:sapphire laser (795 and 265 nm) on thin films of the polymers poly (ethylene terephthalate), poly (trimethylene terephthalate), and poly (carbonate bisphenol A) prepared by spin-coating. LIPSS, inspected by atomic force microscopy, are formed upon multiple pulse UV and IR irradiation with wavelength-sized period in a narrow range of fluences below the ablation threshold. Control and tunability of the size and morphology of the periodic structures become thus possible ensuring photochemical integrity of polymer films.

  2. Effect of Relativistic Plasma on Extreme-Ultraviolet Harmonic Emission from Intense Laser-Matter Interactions

    SciTech Connect

    Krushelnick, K.; Dangor, A. E.; Mangles, S. P. D.; Rozmus, W.; Wagner, U.; Habara, H.; Norreys, P. A.; Beg, F. N.; Wei, M. S.; Bochkarev, S. G.; Clark, E. L.; Gopal, A.; Evans, R. G.; Robinson, A. P. L.; Tatarakis, M.; Zepf, M.

    2008-03-28

    Experiments were performed in which intense laser pulses (up to 9x10{sup 19} W/cm{sup 2}) were used to irradiate very thin (submicron) mass-limited aluminum foil targets. Such interactions generated high-order harmonic radiation (greater than the 25th order) which was detected at the rear of the target and which was significantly broadened, modulated, and depolarized because of passage through the dense relativistic plasma. The spectral modifications are shown to be due to the laser absorption into hot electrons and the subsequent sharply increasing relativistic electron component within the dense plasma.

  3. Far-infrared-light shadowgraphy for high extraction efficiency of extreme ultraviolet light from a CO2-laser-generated tin plasma

    NASA Astrophysics Data System (ADS)

    Matsukuma, Hiraku; Hosoda, Tatsuya; Suzuki, Yosuke; Yogo, Akifumi; Yanagida, Tatsuya; Kodama, Takeshi; Nishimura, Hiroaki

    2016-08-01

    The two-color, double-pulse method is an efficient scheme to generate extreme ultraviolet light for fabricating the next generation semiconductor microchips. In this method, a Nd:YAG laser pulse is used to expand a several-tens-of-micrometers-scale tin droplet, and a CO2 laser pulse is subsequently directed at the expanded tin vapor after an appropriate delay time. We propose the use of shadowgraphy with a CO2 laser probe-pulse scheme to optimize the CO2 main-drive laser. The distribution of absorption coefficients is derived from the experiment, and the results are converted to a practical absorption rate for the CO2 main-drive laser.

  4. Evidence of liquid phase during laser-induced periodic surface structures formation induced by accumulative ultraviolet picosecond laser beam

    SciTech Connect

    Huynh, T. T. D.; Petit, A.; Semmar, N.

    2015-11-09

    Laser-induced periodic surface structures (LIPSS) were formed on Cu/Si or Cu/glass thin films using Nd:YAG laser beam (40 ps, 10 Hz, and 30 mJ/cm{sup 2}). The study of ablation threshold is always achieved over melting when the variation of the number of pulses increases from 1 to 1000. But the incubation effect is leading to reduce the threshold of melting as increasing the number of laser pulse. Also, real time reflectivity signals exhibit typical behavior to stress the formation of a liquid phase during the laser-processing regime and helps to determine the threshold of soft ablation. Atomic Force Microscopy (AFM) analyses have shown the topology of the micro-crater containing regular spikes with different height. Transmission Electron Microscopy (TEM) allows finally to show three distinguished zones in the close region of isolated protrusions. The central zone is a typical crystallized area of few nanometers surrounded by a mixed poly-crystalline and amorphous area. Finally, in the region far from the protrusion zone, Cu film shows an amorphous structure. The real time reflectivity, AFM, and HR-TEM analyses evidence the formation of a liquid phase during the LIPSS formation in the picosecond regime.

  5. Ultrafast dynamics of uracil and thymine studied using a sub-10 fs deep ultraviolet laser.

    PubMed

    Xue, Bing; Yabushita, Atsushi; Kobayashi, Takayoshi

    2016-06-22

    Single 9.6 fs deep ultraviolet pulses with a spectral range of 255-290 nm are generated by a chirped-pulse four-wave mixing technique for use as pump and probe pulses. The electronic excited state and vibrational dynamics are simultaneously observed for an aqueous solution of uracil and thymine over the full spectral range using a 128-channel lock-in amplifier detector. Two probe photon energy-dependent lifetimes gradually increasing with the probe photon energy are obtained from the decay dynamics data. Ultrafast decay dynamics through the conical intersection is assigned from the first excited ππ* to the final ground state involving the nπ* states. Vibrational modes of the electronic ground state and excited states can be observed, which are strongly coupled to the decay dynamics of the electronic excited state. PMID:27299165

  6. Effect of ambient conditions on ultraviolet femtosecond pulse laser induced breakdown spectra

    NASA Astrophysics Data System (ADS)

    Mateo, M. P.; Piñon, V.; Anglos, D.; Nicolas, G.

    2012-08-01

    In this work, the results of a study on the influence of buffer gas and pressure on the LIBS spectrum characteristics are reported. Ultraviolet femtosecond pulses were employed in the analysis of several solid samples including brass, copper, aluminum and silicon under different buffer gasses: air, argon and helium. Given a buffer gas, ambient pressure was varied and its effect on the intensity and broadening of the spectral emission lines and on the background of the spectra was evaluated. A maximum emission intensity of the lines was observed at 500 hPa in helium or argon and at 30 hPa in air. Line broadening, attributed to the Stark effect, was found to be negligible in spectra acquired with helium as a buffer gas compared to spectra recorded under air or argon atmosphere, which showed noticeable line broadening particularly at high ambient pressure.

  7. The use of ultraviolet Thomson scattering as a versatile diagnostic for detailed measurements of a collisional laser produced plasma

    SciTech Connect

    Tracy, M.D.

    1993-01-08

    Collective Thomson scattering from ion-acoustic waves at 266nm is used to obtain spatially resolved, two-dimensional electron density, sound speed, and radial drift profiles of a collisional laser plasma. An ultraviolet diagnostic wavelength minimizes the complicating effects of inverse bremsstrahlung and refractive turning in the coronal region of interest, where the electron densities approach n{sub c}/10. Laser plasmas of this type are important because they model some of the aspects of the plasmas found in high-gain laser-fusion pellets irradiated by long pulse widths where the laser light is absorbed mostly in the corona. The experimental results and LASNEX simulations agree within a percent standard deviation of 40% for the electron density and 50% for the sound speed and radial drift velocity. Thus it is shown that the hydrodynamics equations with classical coefficients and the numerical approximations in LASNEX are valid models of laser-heated, highly collisional plasmas. The versatility of Thomson scattering is expanded upon by extending existing theory with a Fokker-Planck based model to include plasmas that are characterized by (0 {le} k{sub ia}{lambda}{sub ii} {le} {infinity}) and ZT{sub e}/T{sub i}, where k{sub ia} is the ion- acoustic wave number, {lambda}{sub ii} is the ion-ion mean free path, Z is the ionization state of the plasma, and T{sub e}, T{sub i} are the electron and ion temperatures in electron volts respectively. The model is valid for plasmas in which the electrons are approximately collisionless, (k{sub ia}{lambda}{sub ei}, k{sub ia}{lambda}{sub ee} {ge} 1), and quasineutrality holds, ({alpha} {much_gt}1), where {alpha} = 1/k{lambda}{sub DE} and {lambda}{sub DE} is the electron Debye length. This newly developed model predicts the lineshape of the ion-acoustic Thomson spectra and when fit to experimental data provides a direct measurement of the relative thermal flow velocity between the electrons and ions.

  8. Extreme-ultraviolet aluminum spectra emitted from a laser-produced plasma.

    NASA Technical Reports Server (NTRS)

    Williams, M. D.

    1972-01-01

    Five new aluminum lines in the region from 35 to 50 A have been produced by focusing the radiation of a 460-MW, Q-spoiled ruby laser on an aluminum target. Characteristics of the new lines, including their observed and predicted wavelength, intensity, and transition, are tabulated.

  9. Pulsed ultraviolet laser irradiation produces endothelium-independent relaxation of vascular smooth muscle

    SciTech Connect

    Steg, P.G.; Rongione, A.J.; Gal, D.; DeJesus, S.T.; Clarke, R.H.; Isner, J.M.

    1989-07-01

    Recent studies have shown that continuous wave laser irradiation induces contraction of vascular smooth muscle, except at powers far below the threshold for tissue ablation. To determine the corresponding effects of pulsed laser irradiation on vascular smooth muscle tone, vascular rings of rabbit thoracic aorta were mounted isometrically with 1 g tension in Krebs-bicarbonate buffer and irradiated with 308 or 351 nm from an excimer laser through a 400-microns optical fiber. A total of 250 exposures were performed with 1-6.5 mJ/pulse (fluence = 0.8-5.5 J/cm2), 10-50 Hz, and cumulative exposures of 10-120 seconds. Excimer laser irradiation in combinations of pulse energy (PE), repetition rate (RR), and cumulative exposure below, at, or above threshold for tissue ablation consistently produced relaxation unassociated with contraction in each of the 250 exposures. For the total 250 exposures, the magnitude of relaxation (reduction in recorded tension, Rmax) was 55 +/- 4% (mean +/- SEM) of maximum vasomotor reactivity recorded in the specimen in response to administration of serotonin. Rmax varied directly with both PE and RR. When PE was increased from 1 to 5 mJ/pulse (n = 13), Rmax increased from 57 +/- 19% to 80 +/- 19% (p less than 0.0001); when RR was increased from 10 to 50 Hz (n = 10), Rmax increased from 27 +/- 8 to 46 +/- 8 (p less than 0.0001). Rmax varied independently of endothelial integrity (assessed anatomically and pharmacologically) and wavelength (308 vs. 351 nm). Simultaneously recorded tissue-temperature profiles disclosed that during pulsed laser irradiation, tissue temperature rise did not exceed 5/degree/C.

  10. An ultrashort pulse ultra-violet radiation undulator source driven by a laser plasma wakefield accelerator

    SciTech Connect

    Anania, M. P.; Brunetti, E.; Wiggins, S. M.; Grant, D. W.; Welsh, G. H.; Issac, R. C.; Cipiccia, S.; Shanks, R. P.; Manahan, G. G.; Aniculaesei, C.; Jaroszynski, D. A.; Geer, S. B. van der; Loos, M. J. de; Poole, M. W.; Shepherd, B. J. A.; Clarke, J. A.; Gillespie, W. A.; MacLeod, A. M.

    2014-06-30

    Narrow band undulator radiation tuneable over the wavelength range of 150–260 nm has been produced by short electron bunches from a 2 mm long laser plasma wakefield accelerator based on a 20 TW femtosecond laser system. The number of photons measured is up to 9 × 10{sup 6} per shot for a 100 period undulator, with a mean peak brilliance of 1 × 10{sup 18} photons/s/mrad{sup 2}/mm{sup 2}/0.1% bandwidth. Simulations estimate that the driving electron bunch r.m.s. duration is as short as 3 fs when the electron beam has energy of 120–130 MeV with the radiation pulse duration in the range of 50–100 fs.

  11. Cluster beam targets for laser plasma extreme ultraviolet and soft x-ray sources

    DOEpatents

    Kublak, Glenn D.; Richardson, Martin C. (CREOL

    1996-01-01

    Method and apparatus for producing extreme ultra violet (EUV) and soft x-ray radiation from an ultra-low debris plasma source are disclosed. Targets are produced by the free jet expansion of various gases through a temperature controlled nozzle to form molecular clusters. These target clusters are subsequently irradiated with commercially available lasers of moderate intensity (10.sup.11 -10.sup.12 watts/cm.sup.2) to produce a plasma radiating in the region of 0.5 to 100 nanometers. By appropriate adjustment of the experimental conditions the laser focus can be moved 10-30 mm from the nozzle thereby eliminating debris produced by plasma erosion of the nozzle.

  12. Ultraviolet laser treatment of multiwall carbon nanotubes grown at low temperature

    NASA Astrophysics Data System (ADS)

    Kim, J. S.; Ahn, K. S.; Kim, C. O.; Hong, J. P.

    2003-03-01

    Simple laser irradiation of well-aligned multiwall carbon nanotubes (MWCNTs) was performed to intentionally modify structural defects and to ablate possible contamination of the MWCNTs. Scanning electron microscopy and transmission electron microscopy confirmed the clear presence of the MWCNTs with open tips. A Raman spectra exhibited a decrease in an intensity ratio (ID/IG) of 1352 cm-1 (D band) over 1583 cm-1 (G band) peaks by significantly reducing the amorphous carbon phases of D band peaks. The structural improvement in the MWCNTs after optimum laser exposure resulted in a reduction of the turn-on voltage from 1.0 to 0.6 V/μm and an increase in the emission current.

  13. Charge transfer processes and ultraviolet induced absorption in Yb:YAG single crystal laser materials

    NASA Astrophysics Data System (ADS)

    Rydberg, S.; Engholm, M.

    2013-06-01

    Charge transfer (CT) transitions and UV induced color centers in Yb:YAG single crystals have been investigated. A simultaneous pair formation of a stable Yb2+ ion and a hole related (O-) color center (hole polaron) are observed through a CT-process. Slightly different types of hole related color centers are formed in Yb:YAG crystals containing small levels of iron impurities. Furthermore, excitation spectroscopy on the UV irradiated Yb:YAG samples could confirm an energy transfer process between Yb3+ and Yb2+ ions. The findings are important for an increased knowledge of the physical loss mechanisms observed in Yb-doped laser materials, such as the nonlinear decay process in Yb:YAG crystals as well as the photodarkening phenomenon in Yb-doped fiber lasers.

  14. The effect of quantum correction on plasma electron heating in ultraviolet laser interaction

    SciTech Connect

    Zare, S.; Sadighi-Bonabi, R. Anvari, A.; Yazdani, E.; Hora, H.

    2015-04-14

    The interaction of the sub-picosecond UV laser in sub-relativistic intensities with deuterium is investigated. At high plasma temperatures, based on the quantum correction in the collision frequency, the electron heating and the ion block generation in plasma are studied. It is found that due to the quantum correction, the electron heating increases considerably and the electron temperature uniformly reaches up to the maximum value of 4.91 × 10{sup 7 }K. Considering the quantum correction, the electron temperature at the laser initial coupling stage is improved more than 66.55% of the amount achieved in the classical model. As a consequence, by the modified collision frequency, the ion block is accelerated quicker with higher maximum velocity in comparison with the one by the classical collision frequency. This study proves the necessity of considering a quantum mechanical correction in the collision frequency at high plasma temperatures.

  15. An extreme ultraviolet Michelson interferometer for experiments at free-electron lasers

    SciTech Connect

    Hilbert, Vinzenz; Fuchs, Silvio; Paulus, Gerhard G.; Zastrau, Ulf; Blinne, Alexander; Feigl, Torsten; Kämpfer, Tino; Rödel, Christian; Uschmann, Ingo; Wünsche, Martin; Förster, Eckhart

    2013-09-15

    We present a Michelson interferometer for 13.5 nm soft x-ray radiation. It is characterized in a proof-of-principle experiment using synchrotron radiation, where the temporal coherence is measured to be 13 fs. The curvature of the thin-film beam splitter membrane is derived from the observed fringe pattern. The applicability of this Michelson interferometer at intense free-electron lasers is investigated, particularly with respect to radiation damage. This study highlights the potential role of such Michelson interferometers in solid density plasma investigations using, for instance, extreme soft x-ray free-electron lasers. A setup using the Michelson interferometer for pseudo-Nomarski-interferometry is proposed.

  16. Solid-state laser source of narrowband ultraviolet B light for skin disease care

    NASA Astrophysics Data System (ADS)

    Tarasov, Aleksandr A.; Chu, Hong

    2013-03-01

    We report about the development of all-solid-state laser source of narrowband UV-B light for medical applications. The device is based on a gain-switched Ti: Sapphire laser with volume Bragg grating, pumped at 532 nm and operating at 931.8 nm, followed by a third harmonic generator and a fiber optic beam homogenizer. The maximum available pulse energy exceeded 5 mJ at 310.6 nm, with a pulse repetition rates of 50 Hz. The output characteristics satisfy the medical requirements for psoriasis and vitiligo treatment. A new optical scheme for third harmonic generation enhancement at moderate levels of input intensities is proposed and investigated. As a result, 40% harmonic efficiency was obtained, when input pulse power was only 300 kW.

  17. Optically pumped ultraviolet and infrared lasers driven by exploding metal films and wires

    SciTech Connect

    Jones, C.R.; Ware, K.D.

    1983-01-01

    The 342-nm molecular iodine and 1315-nm atomic iodine lasers have been optically pumped by intense light from exploding-metal-film and exploding-wire discharges. Brightness temperatures for the exploding-film discharges were approx. 25,000 K and for the wire discharges were approx. 30,000 K. For the I/sub 2/ laser the 3.5-cm-diameter by 40-cm-long pumped volume lies adjacent to the wire or film of the same length. Pressures of 1 to 6 torr I/sub 2/ and 1 to 3 atm SF, CF/sub 4/, or Ar were used in the stainless-steel cell. Using 20-..mu..F capacitance charged to 40 kV, a 0.25-mm tungsten wire, 3-torr I/sub 2/, and a 2-atm SF/sub 6/, an energy of 2 J was obtained from the laser in a pulse of 8-..mu..s duration. The specific output energy was 7 J/l. Substitution of a cylindrical Al film for the wire, under otherwise similar conditions, led to a X10 output energies and efficiencies were obtained with similar input energy. An output pulse of 12 J and 12-..mu..s duration was measured for a specific output energy of 18 J/l. A laser energy of 110 J in a 20-us-long pulse has been measured from atomic iodine using a wire discharge along the axis of a larger cell. The active volume available was 20 cm in diameter and 80 cm in length. Input energy was 32 kJ. In similar measurements using a cylindrical Al film for discharge initiation, the measured output energy was 40 J.

  18. Photoionization in the Precursor of Laser Supported Detonation by Ultraviolet Radiation

    NASA Astrophysics Data System (ADS)

    Shimamura, Kohei; Michigami, Keisuke; Wang, Bin; Komurasaki, Kimiya; Arakawa, Yoshihiro

    2011-11-01

    The propagation mechanism of laser-supported detonation (LSD) is important for designing laser propulsion for a detonation type thruster. The purpose of this work to was to confirm that photo-ionization in precursor is the predominant LSD sustainment mechanism. First of all, we tried to investigate the dependency of LSD duration on ambient gas species, air and argon. We took a series of high-speed images using the laser shadow-graphy. Besides, to estimate the UV photons emitted from the plasma, we used plasma emission spectroscopy and determined the electron temperature and density. As a result, the LSD duration of argon plasma and air plasma are 0.7 μs and 0.3 μs, resp. Besides, argon plasma emitted 1010 to 1014 photons/seconds, which was higher than air plasma. These results reveal that LSD propagation depends on the photon-contributing photoionization. The threshold photon-emission rate of LSD termination gives the elucidation of the LSD termination condition.

  19. Interaction of extreme ultraviolet laser radiation with solid surface: ablation, desorption, nanostructuring

    NASA Astrophysics Data System (ADS)

    Kolacek, Karel; Schmidt, Jiri; Straus, Jaroslav; Frolov, Oleksandr; Juha, Libor; Chalupsky, Jaromir

    2015-02-01

    The area, where interaction of focused XUV laser radiation with solid surface takes place, can be divided according to local fluency into desorption region (if fluency is larger than zero and smaller than ablation threshold) and ablation region (if fluency is equal or larger than this threshold). It turned out that a direct nanostructuring (e.g. imprinting diffraction pattern created on edges of windows of proximity standing grid) is possible in the desorption region only. While for femtosecond pulses the particle (atom/molecule) removal-efficiency η in the desorption region is very small (η < 10%), and hence, it can be easily distinguished from the ablation region with η ~ 100%, for nanosecond pulses in desorption region this η rises at easily ablated materials from 0% at the periphery up to ~90% at the ablation contour and, therefore, the boundary between these two regions can be found with the help of nanostructuring only. This rise of removal efficiency could be explained by gradually increased penetration depth (due to gradually removed material) during laser pulse. This is a warning against blind using crater shape for fluency mapping in the case of long laser pulses. On the other hand it is a motivation to study an ablation plum (or ablation jet) and to create a knowledge bank to be used at future numerical modeling of this process.

  20. Cryogenic Yb:YAG picosecond laser with high average power visible and ultraviolet harmonic generation

    NASA Astrophysics Data System (ADS)

    Brown, D. C.; Kowalewski, K.; Envid, V.; Zembek, J.; Canale, B.; Kolis, J. W.; McMillen, C. D.; Geisber, H.

    2012-06-01

    Cryogenic Yb:YAG lasers operating at 1029 nm have been demonstrated at Snake Creek Lasers with high average power CW and ultrafast output powers, and provide near diffraction-limited output beams that are ideal for applications in harmonic generation. We describe experiments that have produced high average power green output power at 515 nm as well as preliminary experiments producing UV output power at 257.25 nm. Frequency doubling experiments used a 20 mm long non-critically phase-matched LBO crystal mounted in a constant temperature oven. A mode-locked Yb fiber laser operating at 50 MHz was used to drive a two Yb:YAG cryogenic amplifier system, producing hundreds of watts of average power output with a FWHM pulsewidth of 12 ps. Doubling efficiencies of > 50 % have been observed. For frequency quadrupling, we have used hydrothermally grown KTTP crystals grown at Clemson University and Advanced Photonic Crystals. KBBF offers unprecedented UV transmission down to 155 nm, and was used in a Type I phasematching configuration. The properties of KBBF will be discussed, as well as the experimental results observed and conversion efficiency.

  1. Photoionization in the Precursor of Laser Supported Detonation by Ultraviolet Radiation

    SciTech Connect

    Shimamura, Kohei; Michigami, Keisuke; Wang, Bin; Komurasaki, Kimiya; Arakawa, Yoshihiro

    2011-11-10

    The propagation mechanism of laser-supported detonation (LSD) is important for designing laser propulsion for a detonation type thruster. The purpose of this work to was to confirm that photo-ionization in precursor is the predominant LSD sustainment mechanism. First of all, we tried to investigate the dependency of LSD duration on ambient gas species, air and argon. We took a series of high-speed images using the laser shadow-graphy. Besides, to estimate the UV photons emitted from the plasma, we used plasma emission spectroscopy and determined the electron temperature and density. As a result, the LSD duration of argon plasma and air plasma are 0.7 {mu}s and 0.3 {mu}s, resp. Besides, argon plasma emitted 10{sup 10} to 10{sup 14} photons/seconds, which was higher than air plasma. These results reveal that LSD propagation depends on the photon-contributing photoionization. The threshold photon-emission rate of LSD termination gives the elucidation of the LSD termination condition.

  2. A HIGH-RESOLUTION PHOTOIONIZATION AND PHOTOELECTRON STUDY OF {sup 58}Ni USING A VACUUM ULTRAVIOLET LASER

    SciTech Connect

    Shi Xiaoyu; Huang Huang; Jacobson, Brian; Chang, Yih-Chung; Ng, C. Y.; Yin Qingzhu

    2012-03-01

    In order to provide high-resolution spectroscopic data of nickel ({sup 58}Ni) and its cation ({sup 58}Ni{sup +}) for the assignment of vacuum ultraviolet (VUV) stellar spectra, we have obtained the photoionization efficiency (PIE) spectra of {sup 58}Ni by using a supersonically cooled laser ablation transition-metal beam source and a broadly tunable VUV laser in the range of 61,100-73,600 cm{sup -1}, covering the photoionization transitions: Ni{sup +} (3d{sup 92} D) <- Ni (3d{sup 8}4s{sup 23} D), Ni{sup +}(3d{sup 92} D) <- Ni(3d{sup 8}4s{sup 23} F), and Ni{sup +} (3d{sup 8}4s{sup 4} F) <- Ni(3d{sup 8}4s{sup 23} F). We have also measured the VUV laser pulsed-field-ionization-photoelectron (PFI-PE) spectra of {sup 58}Ni in these regions. The VUV-PFI-PE measurement has allowed the determination of a precise value of 61,619.89 {+-} 0.8 cm{sup -1} (7.6399 {+-} 0.0001 eV) for the ionization energy (IE) of {sup 58}Ni. Due to the narrow VUV laser optical bandwidth of 0.4 cm{sup -1} used in the present study, many complex autoionizing resonances exhibiting Fano line shape profiles are resolved in the PIE spectra. Four autoionizing Rydberg series originating from two-electron and one-electron excitations from the Ni(3d{sup 8}4s{sup 23} F{sub 4}) ground state to converge to the respective Ni{sup +}({sup 2} D{sub 3/2}) and Ni{sup +}({sup 4} F{sub J} ) (J = 9/2, 7/2, and 5/2) ion states are identified. The Rydberg analysis, along with VUV-PFI-PE measurements, has yielded highly precise IE values for the formation of these excited ionic states from the Ni(3d{sup 8}4s{sup 23} F{sub 4}) ground state. The IE values, relative photoionization cross sections, and autoionizing Rydberg resonances observed in the present study are relevant to astrophysics by enhancing the atomic database of iron group transition metal atoms and for understanding the Ni and Ni{sup +} contribution to the VUV opacity in the solar atmosphere.

  3. Self-organized micro-holes on titania based sol-gel films under continuous direct writing with a continuous wave ultraviolet laser

    SciTech Connect

    Bakhti, S.; Destouches, N.; Gamet, E.; Reynaud, S.; CNRS, UMR 5516, Laboratoire Hubert Curien, 18 Rue Pr. Lauras F-42000 Saint-Etienne; University of Saint-Etienne, Jean Monnet, F-42000 Saint-Etienne ; Balan, L.

    2013-05-27

    The microstructuring of titania based sol-gel films is investigated by direct writing with a continuous wave ultraviolet laser beam emitting at 244 nm. Depending on the exposure conditions, the films exhibit a volume expansion, a volume shrinkage, a self-shaped delamination, or are damaged. This paper is mainly focused on the regime where spontaneous local delamination occurs, which corresponds to a narrow range of laser irradiances and writing speeds. In this regime, self-organized round-shape micro-holes opened on the substrate are generated.

  4. Improved characteristics of ultraviolet AlGaN multiple-quantum-well laser diodes with step-graded quantum barriers close to waveguide layers

    NASA Astrophysics Data System (ADS)

    Cai, Xuefen; Li, Shuping; Kang, Junyong

    2016-09-01

    Ultraviolet AlGaN multiple-quantum-well laser diodes (LDs) with step-graded quantum barriers (QBs) instead of conventional first and last QBs close to waveguide layers are proposed. The characteristics of this type of laser diodes are numerically investigated by using the software PICS3D and it is found that the performances of these LDs are greatly improved. The results indicates that the structure with step-graded QBs exhibits higher output light power, slope efficiency and emission intensity, as well as lower series resistance and threshold current density under the identical condition, compared with conventional LD structure.

  5. Extreme ultraviolet and soft X-ray imaging with compact, table top laser plasma EUV and SXR sources

    NASA Astrophysics Data System (ADS)

    Wachulak, P. W.; Bartnik, A.; Kostecki, J.; Wegrzynski, L.; Fok, T.; Jarocki, R.; Szczurek, M.; Fiedorowicz, H.

    2015-12-01

    We present a few examples of imaging experiments, which were possible using a compact laser-plasma extreme ultraviolet (EUV) and soft X-ray (SXR) source, based on a double stream gas puff target. This debris-free source was used in full-field EUV imaging to obtain magnified images of test samples, ZnO nanofibers and images of the membranes coated with salt crystals. The source was also employed for SXR microscopy in the "water-window" spectral range using grazing incidence Wolter type-I objective to image test samples and to perform the initial studies of biological objects. Gas puff target EUV source, spectrally tuned for 13.5 nm wavelength with multilayer mirror and thin film filters, was also used in variety of shadowgraphy experiments to study the density of newly developed modulated density gas puff targets. Finally, the source was also employed in EUV tomography experiments of low density objects with the goal to measure and optimize the density of the targets dedicated to high harmonic generation.

  6. Tunable ultraviolet and blue light generation from Nd:YAB random laser bolstered by second-order nonlinear processes

    PubMed Central

    Moura, André L.; Carreño, Sandra J. M.; Pincheira, Pablo I. R.; Fabris, Zanine V.; Maia, Lauro J. Q.; Gomes, Anderson S. L.; de Araújo, Cid B.

    2016-01-01

    Ultraviolet and blue light were obtained by nonlinear frequency conversion in a random laser (RL) based on Nd0.10Y0.90Al3(BO3)4 nanocrystalline powder. RL operation at 1062 nm, due to the 4F3/2 → 4I11/2 transition of neodymium ions (Nd3+), was achieved by exciting the Nd3+ with a tunable beam from 680 to 920 nm covering the ground state absorption transitions to the 4F9/2, (4F7/2,4S3/2), (4F5/2,2H9/2), and 4F3/2 states. Light from 340 to 460 nm was obtained via the second-harmonic generation of the excitation beam while tunable blue light, from 417 to 486 nm, was generated by self-sum-frequency mixing between the excitation beam and the RL emission. PMID:27250647

  7. Temperature-dependent evaluation of Nd:LiCAF optical properties as potential vacuum ultraviolet laser material

    NASA Astrophysics Data System (ADS)

    Minami, Yuki; Arita, Ren; Cadatal-Raduban, Marilou; Pham, Minh Hong; Empizo, Melvin John Fernandez; Luong, Mui Viet; Hori, Tatsuhiro; Takabatake, Masahiro; Fukuda, Kazuhito; Mori, Kazuyuki; Yamanoi, Kohei; Shimizu, Toshihiko; Sarukura, Nobuhiko; Fukuda, Kentaro; Kawaguchi, Noriaki; Yokota, Yuui; Yoshikawa, Akira

    2016-08-01

    We investigate the temperature-dependent optical properties of Nd3+-doped LiCaAlF6 (Nd:LiCAF) in the vacuum ultraviolet (VUV) region. The 172-nm absorption edge does not seem to experience any significant blue shift as temperature is decreased from room temperature down to 30 K. This is confirmed by excitation spectra for the same temperature range. Several energy levels in the excited state configuration are observed. Based on these energy levels, the dominant emission peak at 177 nm is assigned to the allowed dipole transition from the 4f25d configuration of Nd3+ and the 4I11/2 level of the 4f3 ground state configuration. The position of the dominant 177-nm emission peak appears to be fixed across the temperature range considered. Our results suggest that the spectral overlap between the excitation and emission spectra should not increase as temperature is raised, possibly making Nd:LiCAF a potential VUV laser gain medium operating at room temperature.

  8. Tunable ultraviolet and blue light generation from Nd:YAB random laser bolstered by second-order nonlinear processes.

    PubMed

    Moura, André L; Carreño, Sandra J M; Pincheira, Pablo I R; Fabris, Zanine V; Maia, Lauro J Q; Gomes, Anderson S L; de Araújo, Cid B

    2016-01-01

    Ultraviolet and blue light were obtained by nonlinear frequency conversion in a random laser (RL) based on Nd0.10Y0.90Al3(BO3)4 nanocrystalline powder. RL operation at 1062 nm, due to the (4)F3/2 → (4)I11/2 transition of neodymium ions (Nd(3+)), was achieved by exciting the Nd(3+) with a tunable beam from 680 to 920 nm covering the ground state absorption transitions to the (4)F9/2, ((4)F7/2,(4)S3/2), ((4)F5/2,(2)H9/2), and (4)F3/2 states. Light from 340 to 460 nm was obtained via the second-harmonic generation of the excitation beam while tunable blue light, from 417 to 486 nm, was generated by self-sum-frequency mixing between the excitation beam and the RL emission. PMID:27250647

  9. X-ray characterization of GaN/AlGaN multiple quantum wells for ultraviolet laser diodes

    NASA Astrophysics Data System (ADS)

    Korakakis, D.; Ludwig, K. F.; Moustakas, T. D.

    1998-03-01

    GaN/Al0.20Ga0.80N (50 Å/50 Å) multiple quantum wells (MQW) with 15 periods were grown on (0001) sapphire substrates by molecular beam epitaxy and evaluated by x-ray diffraction. To simulate an ultraviolet laser diode structure, the substrate was coated first with n-GaN as the bottom contact layer and n-Al0.25Ga0.75N as the corresponding cladding layer. The crystal structure of this system was investigated by studying the reciprocal lattice map of off-axis diffraction peaks as well as the θ-2θ pattern around the (0002) reflection. The MQW was found to be coherent and has the a-lattice parameter of the underlying Al0.25Ga0.75N. The good agreement between experimental and theoretical data in the relative intensity of up to third-order satellite peaks supports that the interfaces of the MQW are abrupt, and thus, interdiffusion of Ga and Al atoms at the growth temperature was negligible.

  10. Characterization of phosphor materials for use in plasma display panel by time-resolved vacuum-ultraviolet laser spectrometry.

    PubMed

    Hirakawa, Y; Nakamura, K; Imasaka, T

    2001-11-15

    Phosphor materials that were manufactured for use in a plasma display panel (PDP) were investigated by employing a newly designed time-resolved vacuum-ultraviolet (VUV) spectrometer, which consists of a pulsed VUV laser and a fast photodetector. The VUV spectrometer was used to collect quantum efficiency data as well as the rise and decay times for the PDP phosphor luminescence. Both the rise and decay times increased with decreasing excitation wavelength in the VUV region. This result can be explained by a change in the mechanisms of photoexcitation and luminescence, that is, from charge-transfer excitation to host-lattice excitation below 200 nm. The present instrument was also used for an evaluation of the phosphor materials (Ba(1 - x)MgAl10O17:Eu2+(x)) by changing the Eu2+ concentration. The obtained data suggest that the impurities and defects are located inside the host crystal. Thus, the VUV spectrometer constructed in this study has considerable potential for use in investigating the nature of PDP phosphor materials. PMID:11816576

  11. Rotationally Resolved Vacuum Ultraviolet Laser Spectra of the 37Cl 21 1Σ +u← X1Σ +gTransition

    NASA Astrophysics Data System (ADS)

    Wang, P.; Okuda, I. V.; Dimov, S. S.; Lipson, R. H.

    1998-08-01

    Rotationally and isotopically resolved single-photon excitation spectra of jet-cooled Cl2in the wavelength region between 133 and 138 nm were recorded using a tunable vacuum ultraviolet "laser" generated by two-photon resonantly enhanced four-wave difference mixing in Kr gas. The dominant transition (11Σ+u←X1Σ+g) is well known theoretically and experimentally to involve a double-well excited state potential energy curve formed by a strong homogeneous Rydberg-state/ion-pair state avoided crossing. In this work, single isotopomer spectra were obtained by dispersing and detecting ions produced by (1 + 1‧) resonance-enhanced multiphoton ionization in a time-of-flight mass spectrometer. In this way, rotational constants were deduced for the first time for many v‧ levels of the least abundant molecular isotope,37Cl2, which are both localized in the Rydberg well, and delocalized in the ion-pair portion of the 1-state potential energy curve. Our experimentally derived band origins andB‧vvalues test the practical validity of an analytical 11Σ+upotential energy function which is a modified version of the one first proposed by J. Wörmer, T. Möller, J. Stapelfeldt, G. Zimmerer, D. Haaks, S. Kampf, J. Le Calvé, and M. C. Castex (1988. Z. Phys. D,7,383-395).

  12. Photoluminescence performance enhancement of ZnO/MgO heterostructured nanowires and their applications in ultraviolet laser diodes.

    PubMed

    Shi, Zhi-Feng; Zhang, Yuan-Tao; Cui, Xi-Jun; Zhuang, Shi-Wei; Wu, Bin; Chu, Xian-Wei; Dong, Xin; Zhang, Bao-Lin; Du, Guo-Tong

    2015-06-01

    Vertically aligned ZnO/MgO coaxial nanowire (NW) arrays were prepared on sapphire substrates by metal-organic chemical vapor deposition combined with a sputtering system. We present a comparative investigation of the morphological and optical properties of the produced heterostructures with different MgO layer thicknesses. Photoluminescence measurements showed that the optical performances of ZnO/MgO coaxial NWs were strongly dependent on the MgO layer thickness. The intensity of deep-level emission (DLE) decreased monotonously with the increase of MgO thickness, while the enhancement of ultraviolet (UV) emission showed a critical thickness of 15 nm, achieving a maximum intensity ratio (∼226) of IUV/IDLE at the same time. The significantly improved exciton emission efficiency of the coaxial NW structures allows us to study the surface passivation effect, photogenerated carrier confinement and transfer in terms of energy band theory. More importantly, we achieved an ultralow threshold (4.5 mA, 0.58 A cm(-2)) electrically driven UV lasing action based on the ZnO/MgO NW structures by constructing an Au/MgO/ZnO metal/insulator/semiconductor diode, and the continuous-current-driven diode shows a good temperature tolerance. The results obtained on the unique optical properties of ZnO/MgO coaxial NWs shed light on the design and development of ZnO-based UV laser diodes assembled with nanoscale building blocks. PMID:25803480

  13. Tunable ultraviolet and blue light generation from Nd:YAB random laser bolstered by second-order nonlinear processes

    NASA Astrophysics Data System (ADS)

    Moura, André L.; Carreño, Sandra J. M.; Pincheira, Pablo I. R.; Fabris, Zanine V.; Maia, Lauro J. Q.; Gomes, Anderson S. L.; de Araújo, Cid B.

    2016-06-01

    Ultraviolet and blue light were obtained by nonlinear frequency conversion in a random laser (RL) based on Nd0.10Y0.90Al3(BO3)4 nanocrystalline powder. RL operation at 1062 nm, due to the 4F3/2 → 4I11/2 transition of neodymium ions (Nd3+), was achieved by exciting the Nd3+ with a tunable beam from 680 to 920 nm covering the ground state absorption transitions to the 4F9/2, (4F7/2,4S3/2), (4F5/2,2H9/2), and 4F3/2 states. Light from 340 to 460 nm was obtained via the second-harmonic generation of the excitation beam while tunable blue light, from 417 to 486 nm, was generated by self-sum-frequency mixing between the excitation beam and the RL emission.

  14. Pollution Encrustation Removal by Means of Combined Ultraviolet and Infrared Laser Radiation: The Application of this Innovative Methodology on the Surface of the Parthenon West Frieze

    NASA Astrophysics Data System (ADS)

    Pouli, P.; Frantzikinaki, K.; Papakonstantinou, E.; Zafiropulos, V.; Fotakis, C.

    This study refers to the innovative laser cleaning methodology developed at FORTH IESL on the combination of ultraviolet and infrared laser radiation emitted from a Q-switched Nd:YAG laser for the successful removal of pollution encrustation from marble substrates. The above-mentioned methodology is presented as regards its successful application on the fragile and demanding surface of the Parthenon West Frieze in collaboration with the Committee for the Preservation of the Acropolis Monuments. The aim of this intervention was to remove encrustation, accumulated on the stone due to the atmospheric pollution, without any discoloration or structural alteration to the original surface. The preliminary experiments on all the possible substrates and encrustations present on the surface of the Acropolis monuments and the laser cleaning parameters are presented in detail.

  15. An electrically injected AlGaN nanowire laser operating in the ultraviolet-C band

    SciTech Connect

    Zhao, S.; Liu, X.; Kang, J.; Mi, Z.; Woo, S. Y.; Botton, G. A.

    2015-07-27

    We have investigated the molecular beam epitaxial growth and characterization of nearly defect-free AlGaN nanowire heterostructures grown directly on Si substrate. By exploiting the Anderson localization of light, we have demonstrated electrically injected AlGaN nanowire lasers that can operate at 262.1 nm. The threshold current density is 200 A/cm{sup 2} at 77 K. The relatively low threshold current is attributed to the high Q-factor of the random cavity and the three-dimensional quantum confinement offered by the atomic-scale composition modulation in self-organized AlGaN nanowires.

  16. Longitudinal coherence measurements of an extreme-ultraviolet free-electron laser.

    PubMed

    Schlotter, W F; Sorgenfrei, F; Beeck, T; Beye, M; Gieschen, S; Meyer, H; Nagasono, M; Föhlisch, A; Wurth, W

    2010-02-01

    We have measured the average single-pulse longitudinal coherence characteristics of FLASH, a self amplified spontaneous emission free electron laser, at extreme UV wavelengths. Electric field autocorrelation measurements in the time domain were enabled by a wavefront division beam splitter applied to a tunable delay Mach-Zehnder interferometer. These data agree with the spectral bandwidth measurements made in the frequency domain. They exhibit two correlation time scales and the measured coherence curves have relevant implications for single-shot measurements. PMID:20125725

  17. In vivo selective cytoskeleton dynamics quantification in interphase cells induced by pulsed ultraviolet laser nanosurgery.

    PubMed

    Colombelli, Julien; Reynaud, Emmanuel G; Rietdorf, Jens; Pepperkok, Rainer; Stelzer, Ernst H K

    2005-12-01

    We report on the manipulation of intracellular filaments using a nanosurgery system based on a subnanosecond pulsed UV laser optimized for the localized severing of biological polymers. By inducing artificial catastrophe of selected microtubules (MTs), we perform shrinkage-rate measurements in interphase Ptk-2 cells throughout the entire cell. We quantify the impact of two labeling methods and three fluorescent markers, showing a 25% faster depolymerization with Alexa-488 tubulin compared with Rhodamine and yellow fluorescent protein (YFP) tubulins and a 20% higher variability induced by microinjection compared with stable transfection. Using EB3-GFP as a tip marker, we establish a new protocol to measure shrinkage rate, growth rate and rescue frequency simultaneously with high temporal and spatial specificity in live cells. As our analysis shows, laser-induced MT dynamics are physiologically relevant. The high statistical efficiency that the method offers in terms of numbers of measured events and therefore reduced standard deviations represents an important quantitative improvement in the measurement of dynamic instability parameters in vivo. We extend the application of the method by demonstrating induced dynamic behavior of actin-stress fibers after severing. This new method enables the quantitative investigation of cytoskeleton dynamics in a local confinement. PMID:16262721

  18. Analysis of plume following ultraviolet laser ablation of doped polymers: Dependence on polymer molecular weight

    SciTech Connect

    Rebollar, Esther; Oujja, Mohamed; Bounos, Giannis; Kolloch, Andreas; Georgiou, Savas; Castillejo, Marta

    2007-02-01

    This work investigates the effect of polymer molecular weight M{sub W} on the plume characteristics of poly(methyl methacrylate) (PMMA) and polystyrene (PS) films doped with iodonaphthalene (NapI) and iodophenanthrene (PhenI) following irradiation in vacuum at 248 nm. Laser-induced fluorescence probing of the plume reveals the presence of ArH products (NapH and PhenH from, respectively, NapI- and PhenI-doped films). While a bimodal translational distribution of these products is observed in all cases, on average, a slower translational distribution is observed in the low M{sub W} system. The extent of the observed dependence is reduced as the optical absorption coefficient of the film increases, i.e., in the sequence NapI/PMMA, PhenI/PMMA, and PS-doped films. Further confirmation of the bimodal translational distributions is provided by monitoring in situ the temporally resolved attenuation by the plume as it expands in vacuum of a continuous wave helium-neon laser propagating parallel to the substrate. Results are discussed in the framework of the bulk photothermal model, according to which ejection requires that a critical number of bonds are broken.

  19. Inspection of transparent polymers by photothermal detection of ultraviolet-laser generated thermal waves

    NASA Astrophysics Data System (ADS)

    Eickmeier, Achim; Bahners, Thomas; Schollmeyer, Eckhard

    1991-11-01

    The concept of photothermal wave imaging has been adapted to the nondestructive inspection of transparent polymeric samples by specific generation of thermal waves. Utilization of light sources according to the absorption properties of the material secured pure surface heating which is necessary for sensible measurements. Thickness profiles of thin films made of poly(ethylene terephthalate), which are transparent in the visible spectrum, could be measured using a pulsed KrF laser. Examples for the nondestructive inspection of complex textile samples such as coated fabrics are presented.The photothermal analysis (PTA) of optically generated thermal waves is a powerful tool for nondestructive, contactless inspection and evaluation of intrinsic properties of a sample.1,2 The method has been used for the observation of dynamic processes in adhesives, for the inspection of coatings on metal and of carbon fiber composites. A modulated light source, e.g., a chopped HeNe- or Ar+ laser, is used for local, modulated heating at the sample's surface resulting in a time- and space-dependent temperature modulation which propagates through the material. In the case of a homogeneous layer heated only in a small volume at the surface the solution of the heat diffusion equation gives a heavily damped thermal wave T(x,y,z;t). In a one-dimensional model3 only the direction z perpendicular to the surface is considered and we obtain

  20. Influence of pulse width on ultraviolet laser ablation of poly(methyl methacrylate)

    NASA Astrophysics Data System (ADS)

    Srinivasan, R.; Braren, Bodil

    1988-10-01

    The etching of poly(methyl methacrylate) using pulses of 248 nm laser radiation which had a full width at half maximum (FWHM) of 40-100 ns is reported. These pulses were created by combining two identical pulses, each of 40 ns FWHM, with a set time delay. The etch depth/pulse is sensitive to the pulse width and, therefore, the power density in this polymer. It can be explained by the changes in absorptivity during a pulse that have been reported by G. M. Davis and M. C. Gower [J. Appl. Phys. 61, 2090 (1987)]. The shape of the pulse was also found to influence the etch depth/pulse. The etching of polyimide by these extended pulses shows trends that are opposite to those observed in poly(methyl methacrylate). In this instance, the shielding of the latter portion of the incoming pulse by the products that are ablated by the front portion is probably a serious effect.

  1. A method of atmospheric density measurements during space shuttle entry using ultraviolet-laser Rayleigh scattering

    NASA Technical Reports Server (NTRS)

    Mckenzie, Robert L.

    1988-01-01

    An analytical study and its experimental verification are described which show the performance capabilities and the hardware requirements of a method for measuring atmospheric density along the Space Shuttle flightpath during entry. Using onboard instrumentation, the technique relies on Rayleigh scattering of light from a pulsed ArF excimer laser operating at a wavelength of 193 nm. The method is shown to be capable of providing density measurements with an uncertainty of less than 1 percent and with a spatial resolution along the flightpath of 1 km, over an altitude range from 50 to 90 km. Experimental verification of the signal linearity and the expected signal-to-noise ratios is demonstrated in a simulation facility at conditions that duplicate the signal levels of the flight environment.

  2. Tunable ultraviolet laser-induced fluorescence detection of trace plastics and dissolved organic compounds in water

    NASA Astrophysics Data System (ADS)

    Sivaprakasam, Vasanthi; Killinger, Dennis K.

    2003-11-01

    We developed a tunable (220-285-nm) UV and fixed 266-nm laser-induced fluorescence (LIF) system using a spectrometer and a cooled CCD imaging detector to measure the excitation-emission matrix spectra of various compounds in water, including quinine sulfate and plastic compound bisphenol-A. The LIF instrument was used for the fast, nonspecific determination of trace amounts of dissolved organic compounds present in natural water supplies and various brand name bottled distilled water and bottled drinking water. Plastic-related compounds that leached out of plastic utensils and containers were also detected with this instrument. The sensitivity of the system was approximately 1-2 orders of magnitude better than that for a commercial system.

  3. Tunable ultraviolet laser-induced fluorescence detection of trace plastics and dissolved organic compounds in water.

    PubMed

    Sivaprakasam, Vasanthi; Killinger, Dennis K

    2003-11-20

    We developed a tunable (220-285-nm) UV and fixed 266-nm laser-induced fluorescence (LIF) system using a spectrometer and a cooled CCD imaging detector to measure the excitation-emission matrix spectra of various compounds in water, including quinine sulfate and plastic compound bisphenol-A. The LIF instrument was used for the fast, nonspecific determination of trace amounts of dissolved organic compounds present in natural water supplies and various brand name bottled distilled water and bottled drinking water. Plastic-related compounds that leached out of plastic utensils and containers were also detected with this instrument. The sensitivity of the system was approximately 1-2 orders of magnitude better than that for a commercial system. PMID:14658478

  4. Comparative study on crystallization characteristics of amorphous Ge2Sb2Te5 films by an ultraviolet laser radiation and isothermal annealing

    NASA Astrophysics Data System (ADS)

    Zhu, Z.; Liu, F. R.; Wang, Z. M.; Fan, Z. K.; Liu, F.; Sun, N. X.

    2015-04-01

    A comparative study on crystallization characteristics of amorphous Ge2Sb2Te5 (GST) films induced by an ultraviolet pulse laser and isothermal annealing was carried out by using transmission electron microscopy (TEM) and Raman scattering. TEM observations showed that the mean grain size induced by a pulse laser was in the nanoscale. A more complete crystallization in the 50 nm thick GST film was obtained which was ascribed to the effect of thermal convection produced in a thinner GST film, however, when the film thickness was over 70 nm, no significant decrease in the mean grain size was found because of the effect of heating mode, where a surface heat source by the ultraviolet laser radiation caused a quick temperature drop. The body heating mode at the isothermal annealing condition made the mean grain size increase remarkably with the increase of film thickness, which could be up to the submicron scale, relative to the size of film thickness. The Raman spectrum analysis showed that a red shift was observed in laser induced Ge2Sb2Te5 films as compared to the isothermal annealing samples, which was caused by the resultant stress of the thermal stress and phase transformation stress.

  5. Photoelectrolysis of water at high current density - Use of ultraviolet laser excitation

    NASA Technical Reports Server (NTRS)

    Bocarsly, A. B.; Bolts, J. M.; Cummins, P. G.; Wrighton, M. S.

    1977-01-01

    The behavior of TiO2 and SrTiO3 photoanodes in cells for the photoelectrolysis of H2O has been investigated for high-intensity 351-,364-nm excitation from an Ar ion laser. Intensities up to 380 W/sq cm have been used. For TiO2 a small amount of surface decomposition is found after irradiation at high intensity, whereas SrTiO3 undergoes no detectable changes. Current-voltage properties for both electrodes are essentially independent of light intensity up to the level of 380 W/sq cm, and there is little if any change in quantum efficiency for electron flow. Photocurrent densities have been shown to exceed 5 A/sq cm for O2 evolution. Data show that the energy storage rate associated with the SrTiO3 photoelectrolysis can exceed 30 W/sq cm; this represents the highest demonstrated rate of sustained optical-to-chemical energy conversion.

  6. Laser desorption time-of-flight mass spectrometry of ultraviolet photo-processed ices

    SciTech Connect

    Paardekooper, D. M. Bossa, J.-B.; Isokoski, K.; Linnartz, H.

    2014-10-01

    A new ultra-high vacuum experiment is described that allows studying photo-induced chemical processes in interstellar ice analogues. MATRI²CES - a Mass Analytical Tool to study Reactions in Interstellar ICES applies a new concept by combining laser desorption and time-of-flight mass spectrometry with the ultimate goal to characterize in situ and in real time the solid state evolution of organic compounds upon UV photolysis for astronomically relevant ice mixtures and temperatures. The performance of the experimental setup is demonstrated by the kinetic analysis of the different photoproducts of pure methane (CH₄) ice at 20 K. A quantitative approach provides formation yields of several new species with up to four carbon atoms. Convincing evidence is found for the formation of even larger species. Typical mass resolutions obtained range from M/ΔM ~320 to ~400 for CH₄ and argon, respectively. Additional tests show that the typical detection limit (in monolayers) is ⩽0.02 ML, substantially more sensitive than the regular techniques used to investigate chemical processes in interstellar ices.

  7. Yb-fiber-laser-based, 1.8 W average power, picosecond ultraviolet source at 266 nm.

    PubMed

    Chaitanya Kumar, S; Canals Casals, J; Sanchez Bautista, E; Devi, K; Ebrahim-Zadeh, M

    2015-05-15

    We report a compact, stable, high-power, picosecond ultraviolet (UV) source at 266 nm based on simple single-pass two-step fourth-harmonic generation (FHG) of a mode-locked Yb-fiber laser at 79.5 MHz in LiB3O5 (LBO) and β-BaB2O4. Using a 30-mm-long LBO crystal for single-pass second-harmonic generation, we achieve up to 9.1 W of average green power at 532 nm for 16.8 W of Yb-fiber power at a conversion efficiency of 54% in 16.2 ps pulses with a TEM00 spatial profile and passive power stability better than 0.5% rms over 16 h. The generated green radiation is then used for single-pass FHG into the UV, providing as much as 1.8 W of average power at 266 nm under the optimum focusing condition in the presence of spatial walk-off, at an overall FHG conversion efficiency of ∼11%. The generated UV output exhibits passive power stability better than 4.6% rms over 1.5 h and beam pointing stability better than 84 μrad over 1 h. The UV output beam has a circularity of >80% in high beam quality with the TEM00 mode profile. To the best of our knowledge, this is the first report of picosecond UV generation at 266 nm at megahertz repetition rates. PMID:26393749

  8. Transmission electron microscopy study of amorphous Ge2Sb2Te5 films induced by an ultraviolet single-pulse laser

    NASA Astrophysics Data System (ADS)

    Zhao, J. J.; Liu, F. R.; Han, X. X.; Zhu, Z.; Lin, X.; Liu, F.; Sun, N. X.

    2014-08-01

    Crystallization behaviors of α-GST films with the thickness of 80 and 30 nm induced by an ultraviolet pulse laser were investigated by using TEM integrated with SAED. Firstly, crystalline phase morphologies were shown and analyzed. Both plate grains and spherical grains were found for 80 nm thick film, while only plate grains were found for 30 nm thick film. Then the relationship between the grain size and laser fluence for the 80 nm thick film was studied and the effects of film thickness on crystallization morphology were analyzed. Finally a crystallization process model based on the relationship of the crystallization starting temperature and heating temperature was constructed to elucidate how the solid-phase crystallization and melt-cooling crystallization occurred and developed. It also unified the crystallization starting temperature under static conditions and the crystallization starting temperature under laser inducing conditions.

  9. A cross sectional study on the crystallization of amorphous Ge2Sb2Te5 films induced by a single-pulse ultraviolet laser

    NASA Astrophysics Data System (ADS)

    Zhu, Z.; Liu, F. R.; Yang, J. F.; Fan, Z. K.; Liu, F.; Sun, N. X.

    2016-07-01

    In this paper, the crystallization along the film thickness of amorphous Ge2Sb2Te5 (a-GST) films induced by a single-pulse ultraviolet laser was investigated by using transmission electron microscopy (TEM) integrated with SAED. TEM observations showed that the crystalline GST (c-GST) was composed of columnar grains at the top surface and equaixed grains inside the film. Moreover, the columnar grains became larger with the increase of laser fluence. A three-dimensional finite element method simulation was further used to elucidate the temperature field by a nanosecond excimer laser in the cross section of the a-GST film. A big temperature gradient obtained at the top surface in the cooling process caused the formation of columnar grains, while columnar grains were gradually substituted by small equaixed grains with the decrease of temperature gradient downwards the film interior.

  10. 2.14 mW deep-ultraviolet laser at 165 nm by eighth-harmonic generation of a 1319 nm Nd:YAG laser in KBBF

    NASA Astrophysics Data System (ADS)

    Dai, Shi-Bo; Chen, Ming; Zhang, Shen-Jin; Wang, Zhi-Min; Zhang, Feng-Feng; Yang, Feng; Wang, Zhi-Chao; Zong, Nan; Liu, Li-Juan; Wang, Xiao-Yang; Zhang, Jing-Yuan; Bo, Yong; Cui, Da-Fu; Peng, Qin-Jun; Li, Ru-Kang; Chen, Chuang-Tian; Xu, Zu-Yan

    2016-03-01

    We report a nanosecond (ns) 165 nm deep-ultraviolet (DUV) laser with a maximum average power of 2.14 mW by eighth-harmonic generation (EHG) of a homemade ns 1319 nm Nd:YAG laser. The EHG was performed by cascaded second-harmonic generation (SHG) through successive stages of two LiB3O5 crystals and one KBe2BO3F2 crystal. The generated radiation at 165 nm is the shortest DUV wavelength ever generated through SHG method and the highest average power of all solid state lasers below 170 nm to our knowledge. Such a ns DUV laser at 165 nm is of great interest for photoemission spectroscopy and Raman spectroscopy.

  11. Two dimensional expansion effects on angular distribution of 13.5 nm in-band extreme ultraviolet emission from laser-produced Sn plasma

    SciTech Connect

    Sequoia, K. L.; Tao, Y.; Yuspeh, S.; Burdt, R.; Tillack, M. S.

    2008-06-02

    The angular distribution of extreme ultraviolet emission at 13.5 nm within 2% bandwidth was characterized for laser irradiated, planar, Sn targets at prototypic conditions for a lithography system. We have found that two dimensional plasma expansion plays a key role in the distribution of in-band 13.5 nm emission under these conditions. The angular distribution was found to have two peaks at 45 deg. and 15 deg. This complex angular distribution arises from the shape of both the emitting plasma and the surrounding absorbing plasma. This research reveals that the detailed angular distribution can be important to the deduction of conversion efficiency.

  12. Determination of polycyclic aromatic hydrocarbons and their nitro-, amino-derivatives absorbed on particulate matter 2.5 by multiphoton ionization mass spectrometry using far-, deep-, and near-ultraviolet femtosecond lasers.

    PubMed

    Tang, Yuanyuan; Imasaka, Tomoko; Yamamoto, Shigekazu; Imasaka, Totaro

    2016-06-01

    Multiphoton ionization processes of parent-polycyclic aromatic hydrocarbons (PPAHs), nitro-PAHs (NPAHs), and amino-PAHs (APAHs) were examined by gas chromatography combined with time-of-flight mass spectrometry using a femtosecond Ti:sapphire laser as the ionization source. The efficiency of multiphoton ionization was examined using lasers emitting in the far-ultraviolet (200 nm), deep-ultraviolet (267 nm), and near-ultraviolet (345 nm) regions. The largest signal intensities were obtained when the far-ultraviolet laser was employed. This favorable result can be attributed to the fact that these compounds have the largest molar absorptivities in the far-ultraviolet region. On the other hand, APAHs were ionized more efficiently than NPAHs in the near-ultraviolet region because of their low ionization energies. A sample extracted from a real particulate matter 2.5 (PM2.5) sample was measured, and numerous signal peaks arising from PAH and its analogs were observed at 200 nm. On the other hand, only a limited number of signed peaks were observed at 345 nm, some of which were signed to PPAHs, NPAHs, and APAHs. Thus, multiphoton ionization mass spectrometry has potential for the use in comprehensive analysis of toxic environmental pollutants. PMID:26971178

  13. Detection of polychlorinated biphenyls in transformer oils in Vietnam by multiphoton ionization mass spectrometry using a far-ultraviolet femtosecond laser as an ionization source.

    PubMed

    Vu, Thi Thuy Duong; Vu, Duong; Nghiem, Thi Ha Lien; Imasaka, Tomoko; Tang, Yuanyuan; Shibuta, Shinpei; Hamachi, Akifumi; Do, Quang Hoa; Imasaka, Totaro

    2016-03-01

    Polychlorinated biphenyls (PCBs) in transformer and food oils were measured using gas chromatography combined with multiphoton ionization mass spectroscopy. An ultrashort laser pulse emitting in the far-ultraviolet region was utilized for efficient ionization of the analytes. Numerous signal peaks were clearly observed for a standard sample mixture of PCBs when the third and fourth harmonic emissions (267 and 200nm) of a femtosecond Ti:sapphire laser (800nm) were employed. The signal intensities were found to be greater when measured at 200nm compared with those measured at 267nm, providing lower detection limits especially for highly chlorinated PCBs at shorter wavelengths. After simple pretreatment using disposable columns, PCB congeners were measured and found to be present in the transformer oils used in Vietnam. PMID:26717841

  14. High-Beam-Quality All-Solid-State 355 nm Ultraviolet Pulsed Laser Based on a Master-Oscillator Power-Amplifier System Pumped at 888 nm

    NASA Astrophysics Data System (ADS)

    Hong, Hailong; Liu, Qiang; Huang, Lei; Gong, Mali

    2012-09-01

    An efficient all-solid-state 355 nm ultraviolet laser based on an 888 nm pumped master-oscillator power-amplifier (MOPA) system is presented. Due to the high beam quality of the fundamental wave being superior to 1.15 (M2) under all pump powers and pulse repetition frequencies (PRFs), the UV laser has the advantage of being able to operate continuously from zero to maximum power. The maximum green and UV output powers were 45.9 W at 50 kHz and 24.3 W at 65 kHz with the corresponding conversion efficiencies from IR-to-green and IR-to-UV of 66.0% and 34.1%, respectively.

  15. Ultraviolet Waves

    ERIC Educational Resources Information Center

    Molde, Trevor

    1973-01-01

    Outlines the discovery and nature of ultraviolet light, discusses some applications for these wavelengths, and describes a number of experiments with ultraviolet radiation suitable for secondary school science classes. (JR)

  16. Two mechanisms of crater formation in ultraviolet-pulsed-laser irradiated SiO{sub 2} thin films with artificial defects

    SciTech Connect

    Papernov, S.; Schmid, A.W.

    2005-06-01

    Atomic force microscopy was employed to investigate the morphology of ultraviolet nanosecond-pulsed-laser damage in SiO{sub 2} thin films. Gold nanoparticles, 18.5-nm diameter, embedded in the film were used as calibrated absorbing defects. Damage-crater diameter, depth, and cross-sectional profiles were measured as a function of laser fluence and the lodging depth of gold nanoparticles. The results indicate that, at laser fluences close to the crater-formation threshold and for lodging depths of a few particle diameters, the dominating regime of the material removal is melting and evaporation. The morphology of craters initiated by deep absorbing defects, with a lodging depth larger than {approx}10 particle diameters, clearly points to a two-stage material-removal mechanism. The process starts with the material melting within the narrow channel volume and, upon temperature and pressure buildup, film fracture takes place. Crater-diameter variation with lodging depth and laser fluence is compared with theoretical predictions.

  17. Absolutely calibrated vacuum ultraviolet spectra in the 150-250-nm range from plasmas generated by the NIKE KrF laser

    NASA Astrophysics Data System (ADS)

    Seely, J. F.; Feldman, Uri; Holland, G. E.; Weaver, J. L.; Mostovych, A. N.; Obenschain, S. P.; Schmitt, A. J.; Lehmberg, R.; Kjornarattanawanich, Benjawan; Back, C. A.

    2005-06-01

    High-resolution vacuum ultraviolet (VUV) spectra were recorded from plasmas generated by the NIKE KrF laser for the purpose of observing emission from the two-plasmon decay instability (TPDI) at 2/3 the NIKE wavelength (165nm). The targets were irradiated by up to 43 overlapping beams with intensity up to ≈1014W/cm2 and with beam smoothing by induced spatial incoherence (ISI). The targets consisted of planar foils of CH, BN, Al, Si, S, Ti, Pd, and Au. Titanium-doped silica aerogels in Pyrex cylinders were also irradiated. The spectra of the target elements were observed from charge states ranging from the neutral atoms to five times ionized. The spectrometer was absolutely calibrated using synchrotron radiation, and absolute VUV plasma emission intensities were determined. Emission from the TPDI at 165-nm wavelength was not observed from any of the irradiated targets. An upper bound on the possible TPDI emission was less than 4×10-8 the incident NIKE laser energy. The NIKE laser radiation backscattered from the silica aerogel targets at 248nm was typically 6×10-6 the incident NIKE laser energy, and the spectral broadening corresponded to the 1-THz bandwidth of the ISI smoothing. The spectra from the moderately charged plasma ions (up to five times ionized), spectral linewidths, absolute continuum emission level, and slope of the continuum were consistent with plasma temperatures in the 100-300-eV range.

  18. Demonstration of transverse-magnetic deep-ultraviolet stimulated emission from AlGaN multiple-quantum-well lasers grown on a sapphire substrate

    SciTech Connect

    Li, Xiao-Hang E-mail: dupuis@gatech.edu; Kao, Tsung-Ting; Satter, Md. Mahbub; Shen, Shyh-Chiang; Yoder, P. Douglas; Detchprohm, Theeradetch; Dupuis, Russell D. E-mail: dupuis@gatech.edu; Wei, Yong O.; Wang, Shuo; Xie, Hongen; Fischer, Alec M.; Ponce, Fernando A.

    2015-01-26

    We demonstrate transverse-magnetic (TM) dominant deep-ultraviolet (DUV) stimulated emission from photo-pumped AlGaN multiple-quantum-well lasers grown pseudomorphically on an AlN/sapphire template by means of photoluminescence at room temperature. The TM-dominant stimulated emission was observed at wavelengths of 239, 242, and 243 nm with low thresholds of 280, 250, and 290 kW/cm{sup 2}, respectively. In particular, the lasing wavelength of 239 nm is shorter compared to other reports for AlGaN lasers grown on foreign substrates including sapphire and SiC. The peak wavelength difference between the transverse-electric (TE)-polarized emission and TM-polarized emission was approximately zero for the lasers in this study, indicating the crossover of crystal-field split-off hole and heavy-hole valence bands. The rapid variation of polarization between TE- and TM-dominance versus the change in lasing wavelength from 243 to 249 nm can be attributed to a dramatic change in the TE-to-TM gain coefficient ratio for the sapphire-based DUV lasers in the vicinity of TE-TM switch.

  19. A study on the crystallization behavior of Sn-doped amorphous Ge2Sb2Te5 by ultraviolet laser radiation

    NASA Astrophysics Data System (ADS)

    Bai, N.; Liu, F. R.; Han, X. X.; Zhu, Z.; Liu, F.; Lin, X.; Sun, N. X.

    2014-10-01

    In this paper, the influence of Sn doping (0%, 8% and 14%) on the crystallization of Ge2Sb2Te5 was studied with the aid of an ultraviolet laser. The XRD analyses revealed that the addition of Sn maintained the NaCl-type structure of Ge2Sb2Te5 after crystallization but expanded the lattice parameter due to the smaller atomic radii of Ge replaced by Sn. Raman peaks (123, 150 and 110 cm-1) moved towards lower wavenumbers (118, 137 and 104 cm-1), which can be explained by the remarkable decrease of the binding energy from Ge-Te to Sn-Te. A remarkable increase in optical contrast from 15% to 40% was observed in the Sn-doped Ge2Sb2Te5 film after crystallization with both the isothermal annealing and laser radiance. While the optical contrast changed little for a fixed volume fraction of Sn-doped sample with the variation of laser fluence which is attributed to the crystallization mechanism induced by laser under different fluences is the same.

  20. Photoionized plasmas induced in neon with extreme ultraviolet and soft X-ray pulses produced using low and high energy laser systems

    SciTech Connect

    Bartnik, A.; Wachulak, P.; Fok, T.; Węgrzyński, Ł.; Fiedorowicz, H.; Pisarczyk, T.; Chodukowski, T.; Kalinowska, Z.; Dudzak, R.; Dostal, J.; Krousky, E.; Skala, J.; Ullschmied, J.; Hrebicek, J.; Medrik, T.

    2015-04-15

    A comparative study of photoionized plasmas created by two soft X-ray and extreme ultraviolet (SXR/EUV) laser plasma sources with different parameters is presented. The two sources are based on double-stream Xe/He gas-puff targets irradiated with high (500 J/0.3 ns) and low energy (10 J/1 ns) laser pulses. In both cases, the SXR/EUV beam irradiated the gas stream, injected into a vacuum chamber synchronously with the radiation pulse. Irradiation of gases resulted in formation of photoionized plasmas emitting radiation in the SXR/EUV range. The measured Ne plasma radiation spectra are dominated by emission lines corresponding to radiative transitions in singly charged ions. A significant difference concerns origin of the lines: K-shell or L-shell emissions occur in case of the high and low energy irradiating system, respectively. In high energy system, the electron density measurements were also performed by laser interferometry, employing a femtosecond laser system. A maximum electron density for Ne plasma reached the value of 2·10{sup 18 }cm{sup −3}. For the low energy system, a detection limit was too high for the interferometric measurements, thus only an upper estimation for electron density could be made.

  1. Phosphate laser glass for NIF: production status, slab selection, and recent technical advances

    NASA Astrophysics Data System (ADS)

    Suratwala, Tayyab I.; Campbell, John H.; Miller, Philip E.; Thorsness, Charles B.; Riley, Michael O.; Ehrmann, Paul R.; Steele, Rusty A.

    2004-05-01

    The National Ignition Facility (NIF) at the Lawrence Livermore National Laboratory is a stadium-sized high-energy (1.8 megajoule) / high-peak power (500 terawatt) laser system, which will utilize over 3000 meter-size Nd-doped metaphosphate glasses as its gain media. The current production status, the selection criteria of individual slabs for specific beam line locations, and some recent technical advances are reviewed. The glass blanks are manufactured by a novel continuous glass melting process, and the finished slabs are then prepared by epoxy bonding a Cu-doped phosphate glass edge cladding and by advanced finishing techniques. To date, nearly 3400 slab equivalents have been melted, 2600 have been rough-cut to blanks, 1200 have been finished, and 144 have been installed in NIF. A set of selection rules, which are designed to optimize laser performance (e.g., maintain gain balance between beam lines and minimize beam walkoff) and to maximize glass lifetime with respect to Pt damage site growth, have been established for assigning individual slabs to specific beam line locations. Recent technical advances for amplifier slab production, which include: 1) minimizing surface pitting (hazing) after final finishing; 2) minimizing humidity-induced surface degradation (weathering) upon storage and use; and 3) preventing mounting-induced surface fractures upon installation, have contributed in improving the laser glass quality.

  2. A comparative study of corneal incisions induced by diamond and steel knives and two ultraviolet radiations from an excimer laser.

    PubMed Central

    Marshall, J; Trokel, S; Rothery, S; Krueger, R R

    1986-01-01

    This paper reviews the potential role of excimer lasers in corneal surgery. The morphology of incisions induced by two wavelengths of excimer laser radiation, 193 nm and 248 nm, are compared with the morphology of incisions produced by diamond and steel knives. Analysis suggests that ablation induced by excimer laser results from highly localised photochemical reactions and that 193 nm is the optimal wavelength for surgery. The only significant complication of laser surgery is loss of endothelial cells when incisions are within 40 micron of Descemet's membrane. Images PMID:3013283

  3. The National Ignition Facility: Status and Plans for Laser Fusion and High-Energy-Density Experimental Studies

    SciTech Connect

    Moses, E I; Wuest, C R

    2002-10-16

    The National Ignition Facility (NIF), currently under construction at the University of California's Lawrence Livermore National Laboratory, is a stadium-sized facility containing a 192-beam, 1.8-Megajoule, 500-Terawatt, 351-nm laser system and a 10-meter diameter target chamber with room for nearly 100 experimental diagnostics. NIF is being built by the National Nuclear Security Administration and when completed will be the world's largest laser experimental system, providing a national center to study inertial confinement fusion and the physics of matter at extreme energy densities and pressures. NIF will provide 192 energetic laser beams that will compress small fusion targets to conditions where they will ignite and burn, liberating more energy than is required to initiate the fusion reactions. NIF experiments will allow the study of physical processes at temperatures approaching 100 million K and 100 billion times atmospheric pressure. These conditions exist naturally only in the interior of stars and in nuclear weapons explosions. In the course of designing the world's most energetic laser system, a number of significant technology breakthroughs have been achieved. Research is also underway to develop a shorter pulse capability on NIF for very high power and extreme electromagnetic field research and applications. We discuss here the technology challenges and solutions that have made NIF possible, along with enhancements to NIF's design that could lead to near-exawatt power levels.

  4. The National Ignition Facility: Status and Plans for Laser Fusion and High-Energy-Density Experimental Studies

    SciTech Connect

    Moses, E I

    2002-01-11

    The National Ignition Facility (NIF), currently under construction at the University of California's Lawrence Livermore National Laboratory is a $2.25B stadium-sized facility containing a 192-beam, 1.8-Megajoule, 500-Terawatt, 351-nm laser system. NIF is being built by the National Nuclear Security Agency and when completed will be the world's largest laser system, providing a national center to study inertial confinement fusion and the physics of extreme energy densities and pressures. In NIF up to 192 energetic laser beams will compress small fusion targets to conditions where they will ignite and burn, liberating more energy than is required to initiate the fusion reactions. NIF experiments will allow the study of physical processes at temperatures approaching 100 million K and 100 billion times atmospheric pressure. These conditions exist naturally only in the interior of stars and in nuclear weapons explosions. In the course of designing the world's most energetic laser system, a number of significant technology breakthroughs have been achieved. Research is also underway to develop a shorter pulse capability on NIF for high power applications. We discuss here the technology challenges and solutions that have made NIF possible along with enhancements to NIF's design that could lead to exawatt power levels.

  5. Structural characterisation of tyrosine-nitrated peptides by ultraviolet and infrared matrix-assisted laser desorption/ionisation Fourier transform ion cyclotron resonance mass spectrometry.

    PubMed

    Petre, Brínduşa-Alina; Youhnovski, Nikolay; Lukkari, Juho; Weber, Reinhold; Przybylski, Michael

    2005-01-01

    Nitration of tyrosine residues in proteins may occur in cells upon oxidative stress and inflammation processes mediated through generation of reactive nitroxyl from peroxynitrite. Tyrosine nitration from oxidative pathways may generate cytotoxic species that cause protein dysfunction and pathogenesis. A number of protein nitrations in vivo have been reported and some specific Tyrosine nitration sites have been recently identified using mass spectrometric methods. High-resolution Fourier transform ion cyclotron resonance mass spectrometry (MALDI) FT-ICR-MS) is shown here to be a highly efficient method in the determination of protein nitrations. Following the identification of nitration of the catalytic site Tyr-430 residue of bovine prostacyclin synthase, we synthesised several model peptides containing both unmodified tyrosine and 3-nitro-tyrosine residues, using solid-phase peptide synthesis (SPPS). The structures of the nitrotyrosine peptides were characterised both by ESI- and by matrix-assisted laser desorption/ionisation (MALDI)-FT-ICR-MS, using a standard ultraviolet (UV) nitrogen nitrogen laser and a 2.97 microm Nd-YAG infrared laser. Using UV-MALDI-MS, 3-nitrotyrosyl-peptides were found to undergo extensive photochemical fragmentation at the nitrophenyl group, which may hamper or prevent the unequivocal identification of Tyr-nitrations in cellular proteins. In contrast, infrared-MALDI-FT-ICR-MS did not produce fragmentation of molecular ions of Tyr-nitrated peptides. PMID:16322657

  6. Real-time monitoring of benzene, toluene, and p-xylene in a photoreaction chamber with a tunable mid-infrared laser and ultraviolet differential optical absorption spectroscopy.

    PubMed

    Parsons, Matthew T; Sydoryk, Ihor; Lim, Alan; McIntyre, Thomas J; Tulip, John; Jäger, Wolfgang; McDonald, Karen

    2011-02-01

    We describe the implementation of a mid-infrared laser-based trace gas sensor with a photoreaction chamber, used for reproducing chemical transformations of benzene, toluene, and p-xylene (BTX) gases that may occur in the atmosphere. The system performance was assessed in the presence of photoreaction products including aerosol particles. A mid-infrared external cavity quantum cascade laser (EC-QCL)-tunable from 9.41-9.88 μm (1012-1063 cm(-1))-was used to monitor gas phase concentrations of BTX simultaneously and in real time during chemical processing of these compounds with hydroxyl radicals in a photoreaction chamber. Results are compared to concurrent measurements using ultraviolet differential optical absorption spectroscopy (UV DOAS). The EC-QCL based system provides quantitation limits of approximately 200, 200, and 600 parts in 10(9) (ppb) for benzene, toluene, and p-xylene, respectively, which represents a significant improvement over our previous work with this laser system. Correspondingly, we observe the best agreement between the EC-QCL measurements and the UV DOAS measurements with benzene, followed by toluene, then p-xylene. Although BTX gas-detection limits are not as low for the EC-QCL system as for UV DOAS, an unidentified by-product of the photoreactions was observed with the EC-QCL, but not with the UV DOAS system. PMID:21283225

  7. Gas phase ultraviolet and infrared spectroscopy on a partial peptide of β2-adrenoceptor SIVSF-NH2 by a laser desorption supersonic jet technique.

    PubMed

    Ishiuchi, Shun-Ichi; Yamada, Kohei; Oba, Hikari; Wako, Hiromichi; Fujii, Masaaki

    2016-08-17

    Laser desorption supersonic jet laser spectroscopy has been applied to a penta-peptide, Ser-Ile-Val-Ser-Phe-NH2 (SIVSF-NH2), which is a partial sequence of a binding site in a β2-adrenaline receptor protein. By comparing the resonance enhanced multiphoton ionization spectrum with the ultraviolet-ultraviolet hole burning (HB) spectrum, it is concluded that only a single conformer exists. The infrared (IR) spectrum of the X-H stretching region, measured by IR dip spectroscopy, shows that all of the OH and NH groups form hydrogen bonds. The structure of SIVSF-NH2 is assigned by the combination of a force field calculation (CONFLEX) and quantum chemical calculations both in S0 and S1. Over 20 000 stable conformations, given by CONFLEX, are classified into 6987 groups and 1068 groups in which all of the NH and OH bonds are hydrogen-bonded are selected. The most stable structure in each group was geometrically optimized by density functional theory (DFT) calculations, and theoretical IR spectra were calculated for the conformers for which the energies are within 10 kJ mol(-1) of the most stable one. It has been found that the most stable and the secondmost stable conformers well-reproduce the observed IR spectrum. The vibrational frequencies in S1 were also calculated for these two conformers. According to the reproduction of the vibrational frequencies in the HB spectrum, the structure of SIVSF-NH2 is assigned to the most stable conformer, which forms a hydrogen-bonded structure corresponding to a compact, distorted version of the beta hairpin of peptides and proteins. PMID:27498750

  8. Solid-state laser source of narrowband ultraviolet B light for skin disease care with advanced performance

    NASA Astrophysics Data System (ADS)

    Tarasov, Aleksandr A.; Chu, Hong; Buchwald, Kristian

    2015-02-01

    Two years ago we reported about the development of solid state laser source for medical skin treatment with wavelength 310.6 nm and average power 200 mW. Here we describe the results of investigation of the advanced version of the laser, which is a more compact device with increased output power and flat top beam profile. Ti: Sapphire laser, the main module of our source, was modified and optimized such, that UV average power of the device was increased 1.7 times. Fiber optic homogenizer was replaced by articulated arm with diffraction diffuser, providing round spot with flat profile at the skin. We investigated and compare characteristics of Ti: Sapphire lasers with volume Bragg grating and with fused silica transmission grating, which was used first time for Ti: Sapphire laser spectral selection and tuning. Promising performance of last gratings is demonstrated.

  9. The damage repair role of He-Ne laser on plants exposed to different intensities of ultraviolet-B radiation.

    PubMed

    Qi, Zhi; Yue, Ming; Han, Rong; Wang, Xun-Ling

    2002-06-01

    Light-grown broad bean (Vicia faba L.) seedlings were subjected to different intensities of UV-B radiation (0, 0.05, 0.15, 0.45, 0.90, 1.45 and 1.98 W m(-2)) for 7 h under photosynthetically active radiation (70 micromol m(-2) s(-1)) and then exposed to He-Ne laser (632.8 nm, 5.43 mW mm(-2)) radiation for 5 min or red light radiation for 4 h without ambient light radiation. When He-Ne laser radiated leaves were treated using lower intensity UV-B, the activities of superoxide dismutase (EC 1.15.1.1), ascorbate peroxidase (EC 1.11.1.11) and catalase (EC 1.11.1.6) improved significantly. Moreover, the UV-B-injured plants treated with laser light recovered faster from UV-B treatment because the concentration of malondialdehyde and the rate of electrolyte leakage from leaf disks reached control levels (no UV-B or laser treatment) early compared with those exposed only to ambient light or in dark conditions. Laser treatment, however, had no repair effect on seedling damage induced by higher UV-B radiation (1.45 and 1.98 W m(-2)), even with higher laser flux rates and longer laser treatment. In addition, the red light treatment had no repair effect on UV-B-induced damage. Meanwhile, the long-term physiological effect of He-Ne laser treatment on UV-B damaged plants was presented and evaluated. The results showed that the laser had a long-term positive physiological effect on the growth of UV-B-damaged plants. With the exception of the severe damage caused by higher UV-B radiation, a laser with the proper flux rate and treatment time can repair UV-B-induced damage and shorten the recovery time. PMID:12081332

  10. Effects of macro- and micro-hole milling parameters on Al2O3 ceramics using an ultraviolet laser system

    NASA Astrophysics Data System (ADS)

    Hsiao, W. T.; Tseng, S. F.; Chung, C. K.; Huang, K. C.; Chen, M. F.

    2013-06-01

    Ceramics are commonly used as substrates in electrically insulated integrated circuit, printed circuit board, and lightemitting diode industries because of their excellent dielectric and thermal properties. However, brittle materials (e.q., ceramic alumina, sapphire, glass, and silicon wafer) are difficult to fabricate using wheel tools. Laser material processes are preferred over traditional methods because they allow noncontact processing, avoid tool wear problems, and achieve high speed, high accuracy, and high resolution. Laser material processes also exhibit minimal residual thermal effects and residual stress. This study investigated the laser drilling of Al2O3 ceramic material (with a thickness of 380 μm and hole diameters of 200, 300, and 500 μm, respectively) by using a laser milling method. The macro- and micro-hole milling performance depended on various parameters including the galvanometric scan speed and milling time. A 3D confocal laser scanning microscope and a field-emission scanning electron microscope were used to measure the surface morphology, taper angle, and melted residual height of the machined surface after laser milling. The edge quality and roundness of laser milling were also observed using image-processing edge-detection technology.

  11. A universal value of effective annealing time for rapid oxide nucleation and growth under pulsed ultraviolet laser irradiation.

    PubMed

    Nakajima, Tomohiko; Shinoda, Kentaro; Tsuchiya, Tetsuo

    2013-09-14

    The effective annealing times (t(eff)) for nucleating various oxides from an amorphous matrix under nanosecond pulsed laser irradiation have been determined. The oxides, which had perovskite, bixbyite, anatase, and pyrochlore structures, showed similar t(eff) values for crystal nucleation of around 60 ns. This indicates that the effective annealing time is a good universal value for evaluating pulsed laser-induced oxide nucleation. Time-resolved resistance measurements of tin-doped In2O3 thin films under pulsed laser irradiation showed that crystal nucleation and rapid growth proceeded spontaneously with an instantaneous temperature rise. PMID:23881113

  12. A Solid State Ultraviolet Lasers Based on Cerium-Doped LiCaAIF(sub 6) Crystal Resonator

    NASA Technical Reports Server (NTRS)

    Yu, Nan; Le, Thanh; Schowalter, Steven J.; Rellergert, Wade; Jeet, Justin; Lin, Guoping; Hudson, Eric

    2012-01-01

    We report the first demonstration of a UV laser using a high-Q whispering gallery mode (WGM) resonator of Ce+: LiCaAlF6. We show that WGM resonators from LiCaAlF6 can achieve a Q of 2.6 x 10(sup 7) at UV. We demonstrated a UV laser at 290 nm with a pulsed pump laser at 266 nm. The experiments showed the low pump threshold intensity of 7.5 x 10(sup 9) W/m(sup 2) and slope efficiency of 25%. We have also observed lasing delay dynamics. These results are consistent with our modeling and theoretical estimates, and pave the way for a low threshold cw UV laser using WGM resonator cavity.

  13. Morphology And Microstructure in Fused Silica Induced By High Fluence Ultraviolet 3omega (355 Nm) Laser Pulses

    SciTech Connect

    Wong, J.; Ferriera, J.L.; Lindsey, E.F.; Haupt, D.L.; Hutcheon, I.D.; Kinney, J.H.

    2007-08-08

    The morphology and microstructure induced in high quality fused silica by UV (355 nm) laser pulses at high fluence (10-45 J/cm{sup 2}) have been investigated using a suite of microscopic and spectroscopic tools. The laser beam has a near-Gaussian profile with a 1/e{sup 2} diameter of 0.98 mm at the sample plane and a pulse length FWHM (full width at half maximum) of 7.5 ns. The damage craters consist of a molten core region (thermal explosion), surrounded by a near concentric region of fractured material. The latter arises from propagation of lateral cracks induced by the laser-generated shock waves, which also compact the crater wall, {approx} 10 {micro}m thick and {approx} 20% higher in density. The size of the damage crater varies with laser fluence, number of pulses, and laser irradiation history. In the compaction layer, there is no detectable change in the Si/O stoichiometry to within {+-} 1.6% and no crystalline nano-particles of Si were observed. Micro- (1-10 {micro}m) and nano- (20-200 nm) cracks are found, however. A lower valence Si{sup 3+} species on the top 2-3 nm of the compaction layer is evident from the Si 2p XPS. The results are used to construct a physical model of the damage crater and to gain critical insight into laser damage process.

  14. Infrared Vacuum-Ultraviolet Laser Pulsed Field Ionization-Photoelectron Study of CH₃Br⁺(X˜ 2E3/2)

    SciTech Connect

    Xing, X.; Wang, P.; Reed, Beth; Baek, Sun-Jong; Ng, Cheuk-Yiu

    2008-10-02

    The research described in this product was performed in part in the Environmental Molecular Sciences Laboratory, a national scientific user facility sponsored by the Department of Energy's Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory. By preparing methyl bromide (CH₃Br) in selected rotational levels of the CH₃Br(X˜ 1A1; V1 = 1) state with infrared (IR) laser excitation prior to vacuum-ultraviolet (VUV) laser pulsed field ionization-photoelectron (PFI-PE) measurements, we have observed rotationally resolved photoionization transitions to the CH₃Br⁺(X˜ 2E3/2; V1 + = 1) state, where V1 and V1 + are the symmetric C-H stretching vibrational mode for the neutral and cation, respectively. The VUV-PFI-PE origin band for CH₃Br⁺(X˜ 2E3/2) has also been measured. The simulation of these IR-VUV-PFI-PE and VUV-PFI-PE spectra have allowed the determination of the V1 + vibrational frequency (2901.8 ( 0.5 cm-1) and the ionization energies of the origin band (85 028.3 ( 0.5 cm-1) and the V1 + ) 1 r V1 ) 1 band (84 957.9 ( 0.5 cm-1).

  15. Surface modification of bisphenol A polycarbonate material by ultraviolet Nd:YVO4 laser high-speed microprocessing technology

    NASA Astrophysics Data System (ADS)

    Liu, Jianguo; Wang, Suhuan; Lv, Ming; Zeng, Xiaoyan

    2014-08-01

    In this paper, a low-cost and high-efficiency microprocessing modification technology for the surface of bisphenol A polycarbonate (BAPC) material was achieved (in particular, from hydrophilicity to hydrophobicity) at high laser scanning speeds (600-1000 mm s - 1) and using an all-solid state, Q-switched, high-average power and nanosecond pulse Nd:YVO4 laser (355 nm wavelength). During the modification, it was found that the laser fluence and pulse width were the two main parameters affecting the modification effect. Moreover, the modification had a significant effect on the water contact angle, wetting behavior, microstructure, average roughness and chemical composition of the surface. When the laser fluences applied were low (i.e., less than the so-called critical fluence of the UV laser modification of the BAPC material), the water contact angle was found to be a little less than the original, the hydrophilicity was slightly improved, the relative content of the oxygen-containing groups (e.g. O-C and COO - ) increased, the microstructure and average roughness only had a very slight change, and the wetting behavior complied with the Wenzel regime. On the other hand, when the laser fluences applied were high, the water contact angle significantly increased, the hydrophilicity markedly decreased and the relative content of the oxygen-containing groups also increased. Here, a porous microstructure with periodical v-type grooves was generated and the average roughness had an obvious increase. In this case, the wetting behavior could be explained by the Cassie-Baxter regime, i.e., the microstructure and average roughness change played a deciding role. The reason for this might be that different laser parameters result in different material deformation and removal processes, thereby resulting in different surface chemical compositions, microstructures, roughnesses and wetting properties.

  16. Ultraviolet Extensions

    NASA Technical Reports Server (NTRS)

    2008-01-01

    [figure removed for brevity, see original site] Side-by-Side Comparison Click on image for larger view

    This ultraviolet image from NASA's Galaxy Evolution Explorer shows the Southern Pinwheel galaxy, also know as Messier 83 or M83. It is located 15 million light-years away in the southern constellation Hydra.

    Ultraviolet light traces young populations of stars; in this image, young stars can be seen way beyond the main spiral disk of M83 up to 140,000 light-years from its center. Could life exist around one of these far-flung stars? Scientists say it's unlikely because the outlying regions of a galaxy are lacking in the metals required for planets to form.

    The image was taken at scheduled intervals between March 15 and May 20, 2007. It is one of the longest-exposure, or deepest, images ever taken of a nearby galaxy in ultraviolet light. Near-ultraviolet light (or longer-wavelength ultraviolet light) is colored yellow, and far-ultraviolet light is blue.

    What Lies Beyond the Edge of a Galaxy The side-by-side comparison shows the Southern Pinwheel galaxy, or M83, as seen in ultraviolet light (right) and at both ultraviolet and radio wavelengths (left). While the radio data highlight the galaxy's long, octopus-like arms stretching far beyond its main spiral disk (red), the ultraviolet data reveal clusters of baby stars (blue) within the extended arms.

    The ultraviolet image was taken by NASA's Galaxy Evolution Explorer between March 15 and May 20, 2007, at scheduled intervals. Back in 2005, the telescope first photographed M83 over a shorter period of time. That picture was the first to reveal far-flung baby stars forming up to 63,000 light-years from the edge of the main spiral disk. This came as a surprise to astronomers because a galaxy's outer territory typically lacks high densities of star-forming materials.

    The newest picture of M83 from the Galaxy Evolution Explorer is shown at the right, and was taken over a longer period of

  17. Characterization of mixtures of compounds produced in chlorpromazine aqueous solutions by ultraviolet laser irradiation: their applications in antimicrobial assays.

    PubMed

    Alexandru, Tatiana; Staicu, Angela; Pascu, Alexandru; Radu, Elena; Stoicu, Alexandru; Nastasa, Viorel; Dinache, Andra; Boni, Mihai; Amaral, Leonard; Pascu, Mihail Lucian

    2015-05-01

    The study reports an investigation of the photoproducts obtained by exposure of chlorpromazine hydrochloride in ultrapure water (concentration 2 mg/mL) to a 266-nm laser beam obtained by fourth harmonic generation from a Nd:YAG laser (6-ns full time width at half maximum, 10-Hz pulse repetition rate). The photoproducts were analyzed by steady-state UV-Vis absorption, laser-induced fluorescence, Fourier transform infrared spectroscopy, and liquid chromatography-tandem time-of-flight mass spectroscopy. Two figures showing pathways that take place during irradiation for obtaining the final products are shown. The quantum yield of singlet oxygen generation by chlorpromazine (CPZ) was determined relative to standard Zn-phthalocyanine in dimethyl sulfoxide. To outline the role of fluorescence in photoproducts formation rates, fluorescence quantum yield of CPZ during exposure to 355-nm radiation (third harmonic of the fundamental beam of Nd:YAG laser) was investigated relative to standard Coumarin 1 in ethanol. The CPZ solutions exposed 60 and 240 min to 266-nm laser beam, respectively, were tested against Staphylococcus aureus ATCC 25923 strain. For 25 μL of CPZ samples irradiated 240 min, a higher diameter of inhibition has obtained against the tested strain than for the 60-min exposed ones. PMID:25365041

  18. Characterization of mixtures of compounds produced in chlorpromazine aqueous solutions by ultraviolet laser irradiation: their applications in antimicrobial assays

    NASA Astrophysics Data System (ADS)

    Alexandru, Tatiana; Staicu, Angela; Pascu, Alexandru; Radu, Elena; Stoicu, Alexandru; Nastasa, Viorel; Dinache, Andra; Boni, Mihai; Amaral, Leonard; Pascu, Mihail Lucian

    2015-05-01

    The study reports an investigation of the photoproducts obtained by exposure of chlorpromazine hydrochloride in ultrapure water (concentration 2 mg/mL) to a 266-nm laser beam obtained by fourth harmonic generation from a Nd:YAG laser (6-ns full time width at half maximum, 10-Hz pulse repetition rate). The photoproducts were analyzed by steady-state UV-Vis absorption, laser-induced fluorescence, Fourier transform infrared spectroscopy, and liquid chromatography-tandem time-of-flight mass spectroscopy. Two figures showing pathways that take place during irradiation for obtaining the final products are shown. The quantum yield of singlet oxygen generation by chlorpromazine (CPZ) was determined relative to standard Zn-phthalocyanine in dimethyl sulfoxide. To outline the role of fluorescence in photoproducts formation rates, fluorescence quantum yield of CPZ during exposure to 355-nm radiation (third harmonic of the fundamental beam of Nd:YAG laser) was investigated relative to standard Coumarin 1 in ethanol. The CPZ solutions exposed 60 and 240 min to 266-nm laser beam, respectively, were tested against Staphylococcus aureus ATCC 25923 strain. For 25 μL of CPZ samples irradiated 240 min, a higher diameter of inhibition has obtained against the tested strain than for the 60-min exposed ones.

  19. Photoionization of helium atoms irradiated with intense vacuum ultraviolet free-electron laser light. Part I. Experimental study of multiphoton and single-photon processes

    SciTech Connect

    Laarmann, T.; Guertler, P.; Laasch, W.; Schulz, J.; Wabnitz, H.; Moeller, T.; Castro, A.R.B. de

    2005-08-15

    The interaction of He atoms with intense vacuum-ultraviolet light of a free-electron laser is investigated using time-of-flight mass spectroscopy and photoelectron spectroscopy. The atoms were irradiated with 100 fs pulses at 95 nm wavelength, which corresponds to {approx}13 eV photon energy. The ionization of He atoms is observed at a peak intensity of 10{sup 10}-10{sup 13} W/cm{sup 2}, which is due both to nonlinear multiphoton ionization with the fundamental wavelength and single-photon ionization with third harmonic radiation of the free-electron laser. The observation of two sharp photoelectron peaks in the kinetic energy spectra, that are separated by the photon energy, is in agreement with the numerical solution of the time-dependent Schroedinger equation. The calculation was done using the fully quantized field and a limited but representative set of basis states. The ionization rate dependence on the laser peak intensity indicates that: (a) The low-energy peak in the photoelectron spectra is mainly due to two-photon absorption of the fundamental, but (b) the high-energy peak at 15.4 eV is probably due to third harmonic FEL radiation. The theoretically predicted contribution from three-photon absorption of the fundamental is of about the same order of magnitude and could not be separated from the third harmonic background signal. Particularly, the photoelectron spectra and He{sup +} time-of-flight data give evidence that the intensity of third harmonic light is high enough to perform single-shot spectroscopy on gas phase samples.

  20. Multiline short-pulse solid-state seeded carbon dioxide laser for extreme ultraviolet employing multipass radio frequency excited slab amplifier.

    PubMed

    Nowak, Krzysztof M; Ohta, Takeshi; Suganuma, Takashi; Fujimoto, Junichi; Mizoguchi, Hakaru

    2013-03-15

    In this Letter we describe in more detail a solid-state seeded, nanosecond pulse, multiline CO(2) oscillator designed and built for the extreme ultraviolet (EUV) laser-produced-plasma (LPP) source. Our oscillator featured quantum cascade laser seeders, a diffraction-type seed beam combiner, and a radio-frequency-discharge-excited, diffusion-cooled, slab-waveguide CO(2) gain cell in a compact multipass regenerative amplifier configuration. The oscillator generated pulses of exceptional stability in terms of envelope, energy, and spectrum. Excellent stability of output was achieved without any additional techniques. The output spectrum consisted of two laser lines of a 00(0)1-10(0)0 band of a CO(2) molecule, P20 and P22, with a target of four lines P18-P24. The pulse duration was electronically adjustable between 11 and 35 ns at a repetition frequency from a few hertz to hundreds of kilohertz. Electronic adjustment of the pulse duration was achieved by relative timing offsets of individual seeders, opening an avenue to a range of on-line adjustments of pulse shape and spectral content timing. The jitter-tolerant operation allows for easy synchronization with an external event, such as a droplet target in an EUV LPP source. A resistance to parasitic seeding of more than 40 dB was recorded. The oscillator produced up to 20 W of average output power at a repetition rate of 100 kHz in a near-diffraction-limited beam of M(2)<1.3 and a pointing stability below 50 μrad. PMID:23503247

  1. Role of HfO2/SiO2 thin-film interfaces in near-ultraviolet absorption and pulsed laser damage

    DOE PAGESBeta

    Papernov, Semyon; Kozlov, Alexei A.; Oliver, James B.; Smith, Chris; Jensen, Lars; Guenster, Stefan; Maedebach, Heinrich; Ristau, Detlev

    2016-07-15

    Here, the role of thin-film interfaces in the near-ultraviolet (near-UV) absorption and pulsed laser-induced damage was studied for ion-beam-sputtered and electron-beam-evaporated coatings comprised from HfO2 and SiO2 thin-film pairs. To separate contributions from the bulk of the film and from interfacial areas, absorption and damage threshold measurements were performed for a one-wave (355-nm wavelength) thick, HfO2 single-layer film and for a film containing seven narrow HfO2 layers separated by SiO2 layers. The seven-layer film was designed to have a total optical thickness of HfO2 layers, equal to one wave at 355 nm and an E-field peak and average intensity similarmore » to a single-layer HfO2 film. Absorption in both types of films was measured using laser calorimetry and photothermal heterodyne imaging. The results showed a small contribution to total absorption from thin-film interfaces as compared to HfO2 film material. The relevance of obtained absorption data to coating near-UV, nanosecond-pulse laser damage was verified by measuring the damage threshold and characterizing damage morphology. The results of this study revealed a higher damage resistance in the seven-layer coating as compared to the single-layer HfO2 film in both sputtered and evaporated coatings. The results are explained through the similarity of interfacial film structure with structure formed during the codeposition of HfO2 and SiO2 materials.« less

  2. Spectral modulation of ultraviolet femtosecond laser pulse by molecular alignment of CO2, O2, and N2

    NASA Astrophysics Data System (ADS)

    Wang, Yongdong; Dai, Xiaomin; Wu, Jian; Ding, Liang'en; Zeng, Heping

    2010-01-01

    We demonstrate efficient third harmonic generation of a near infrared femtosecond pulse through cascaded frequency doubling and sum-frequency generation processes, where the group velocity mismatching between the involved fundamental and generated second harmonic pulses, before they are sent to frequency mixing, are precompensated with a properly inserted nonlinear crystal. The spectrum of the generated third harmonic pulse with energy of 1.1 mJ is further modulated by using impulsive molecular alignments of CO2, O2, and N2, where significantly broadened spectrum in the ultraviolet spectral region is observed due to the additional cross-focusing effect from the parallel aligned molecules and the consequently enhanced self-phase modulation.

  3. Fabrication of a high-density nano-porous structure on polyimide by using ultraviolet laser irradiation

    NASA Astrophysics Data System (ADS)

    Ma, Yong-Won; Jeong, Myung Yung; Lee, Sang-Mae; Shin, Bo Sung

    2016-03-01

    A new approach for fabricating a high-density nano-porous structure on polyimide (PI) by using a 355-nm UV laser is presented here. When PI was irradiated by using a laser, debris that had electrical conductivity was generated. Accordingly, that debris caused electrical defects in the field of electronics. Thus, many researchers have tried to focus on a clean processing without debris. However, this study focused on forming a high density of debris so as to fabricate a nano-porous structure consisting of nanofibers on the PI film. A PI film with closed pores and open pores was successfully formed by using a chemical blowing agent (azodicarbonamide, CBA) in an oven. Samples were precured at 130 °C and cured at 205 °C in sequence so that the closed pores might not coalesce in the film. When the laser irradiated the PI film with closed pores, nanofibers were generated because polyimide was not completely decomposed by photochemical ablation. Our results indicated that a film with micro-closed pores, in conjunction with a 355-nm pulsed laser, can facilitate the fabrication of a high-density nano-porous structure.

  4. High-power ultraviolet 278 nm laser from fourth-harmonic generation of a Nd:YAG laser in CsB3O5.

    PubMed

    Wang, Zhichao; Yang, Feng; Zhang, Guochun; Bo, Yong; Liu, Shanshan; Xie, Shiyong; Xu, Yiting; Zong, Nan; Li, Fangqin; Liu, Biaolong; Xu, Jialin; Peng, Qinjun; Zhang, Jingyuan; Cui, Dafu; Wu, Yicheng; Xu, Zuyan

    2012-06-15

    We demonstrate a high-power UV 278 nm laser by fourth-harmonic generation (FHG) of a 1112 nm Nd:YAG laser in a nonlinear optical (NLO) crystal CsB3O5 (CBO) for the first time, to our best knowledge. A 30 W level diode-pumped Q-switched Nd:YAG laser at 1112 nm with beam quality factor M2=1.2 was used as the fundamental light source at a pulse width of 500 ns. With an LiB3O5 crystal, the 1112 nm laser was first frequency-doubled to 556 nm with an average output power of 13.5 W. It was then frequency doubled again in a CBO crystal to obtain the FHG output at 278 nm. The maximum average output power of the 278 nm laser is up to 1.5 W. The results demonstrated that CBO crystal is a promising NLO material for UV high-power lasers below 300 nm. PMID:22739922

  5. The National Ignition Facility: Status and Plans for Laser Fusion and High-Energy-Density Experimental Studies

    SciTech Connect

    Wuest, C

    2001-10-29

    The National Ignition Facility (NIF) currently under construction at the University of California Lawrence Livermore National Laboratory (LLNL) is a 192-beam, 1.8-megajoule, 500-terawatt, 351-nm laser for inertial confinement fusion (ICF) and high-energy-density experimental studies. NIF is being built by the Department of Energy and the National Nuclear Security Agency (NNSA) to provide an experimental test bed for the U.S. Stockpile Stewardship Program to ensure the country's nuclear deterrent without underground nuclear testing. The experimental program will encompass a wide range of physical phenomena from fusion energy production to materials science. Of the roughly 700 shots available per year, about 10% will be dedicated to basic science research. Laser hardware is modularized into line replaceable units (LRUs) such as deformable mirrors, amplifiers, and multi-function sensor packages that are operated by a distributed computer control system of nearly 60,000 control points. The supervisory control room presents facility-wide status and orchestrates experiments using operating parameters predicted by physics models. A network of several hundred front-end processors (FEPs) implements device control. The object-oriented software system is implemented in the Ada and Java languages and emphasizes CORBA distribution of reusable software objects. NIF is currently scheduled to provide first light in 2004 and will be completed in 2008.

  6. Electron-Heated Target Temperature Measurements in Petawatt Laser Experiments Based on Extreme Ultraviolet Imaging and Spectroscopy

    SciTech Connect

    Ma, T; Beg, F; Macphee, A; Chung, H; Key, M; Mackinnon, A; Patel, P; Hatchett, S; Akli, K; Stephens, R; Chen, C; Freeman, R; Link, A; Offermann, D; Ovchinnikov, V; VanWoerkom, L; Zhang, B

    2008-05-02

    Three independent methods (XUV spectroscopy, imaging at 68 eV and 256 eV) have been used to measure planar target rear surface plasma temperature due to heating by hot electrons. The hot electrons are produced by ultra-intense laser plasma interactions using the 150 J, 0.5 ps Titan laser. Soft x-ray spectroscopy in the 50-400 eV region and imaging at the 68 eV and 256 eV photon energies were used to determine the rear surface temperature of planar CD targets. Temperatures were found to be in the 60-150 eV range, with good agreement between the three diagnostics.

  7. Space-resolved analysis of trace elements in fresh vegetables using ultraviolet nanosecond laser-induced breakdown spectroscopy

    NASA Astrophysics Data System (ADS)

    Juvé, Vincent; Portelli, Richard; Boueri, Myriam; Baudelet, Matthieu; Yu, Jin

    2008-10-01

    Laser-induced breakdown spectroscopy (LIBS) has been applied to analyze trace elements contained in fresh vegetables. A quadrupled Nd:YAG laser is used in the experiments for ablation. Analyzed samples come from local markets and represent frequently consumed vegetables. For a typical root vegetable, such as potato, spectral analysis of the plasma emission reveals more than 400 lines emitted by 27 elements and 2 molecules, C 2 and CN. Among these species, one can find trace as well as ultra-trace elements. A space-resolved analysis of several trace elements with strong emissions is then applied to typical root, stem and fruit vegetables. The results from this study demonstrate the potential of an interesting tool for botanical and agricultural studies as well for food quality/safety and environment pollution assessment and control.

  8. Tunable ultraviolet output from an intracavity frequency-doubled red vertical-external-cavity surface-emitting laser

    NASA Astrophysics Data System (ADS)

    Hastie, Jennifer E.; Morton, Lynne G.; Kemp, Alan J.; Dawson, Martin D.; Krysa, Andrey B.; Roberts, John S.

    2006-08-01

    An optically pumped red vertical-external-cavity surface-emitting laser with an AlInGaP gain region produced more than 1W of continuous-wave output power at a wavelength of 675nm. Frequency doubling in a beta-barium borate crystal placed at an intracavity beam waist generated 120mW of total output power at 338nm. Using an intracavity birefringent filter a second harmonic tuning range of ˜5nm was achieved.

  9. Optimization of extreme ultraviolet photons emission and collection in mass-limited laser produced plasmas for lithography application

    SciTech Connect

    Sizyuk, T.; Hassanein, A.

    2012-08-01

    The progress in development of commercial system for next generation EUV lithography requires, among other factors, significant improvement in EUV photon sources such as discharge produced plasma (DPP) and laser produced plasma (LPP) devices. There are still many uncertainties in determining the optimum device since there are many parameters for the suitable and efficient energy source and target configuration and size. Complex devices with trigger lasers in DPP or with pre-pulsing in LPP provide wide area for optimization in regards to conversion efficiency (CE) and components lifetime. We considered in our analysis a promising LPP source configuration using 10-30 {mu}m tin droplet targets, and predicted conditions for the most efficient EUV radiation output and collection as well as calculating photons source location and size. We optimized several parameters of dual-beam lasers and their relationship to target size. We used our HEIGHTS comprehensive and integrated full 3D simulation package to study and optimize LPP processes with various target sizes to maximize the CE of the system.

  10. Note: Deep ultraviolet Raman spectrograph with the laser excitation line down to 177.3 nm and its application

    SciTech Connect

    Jin, Shaoqing; Fan, Fengtao; Guo, Meiling; Zhang, Ying; Feng, Zhaochi E-mail: canli@dicp.ac.cn; Li, Can E-mail: canli@dicp.ac.cn

    2014-04-15

    Deep UV Raman spectrograph with the laser excitation line down to 177.3 nm was developed in this laboratory. An ellipsoidal mirror and a dispersed-subtractive triple monochromator were used to collect and disperse Raman light, respectively. The triple monochromator was arranged in a triangular configuration with only six mirrors used. 177.3 nm laser excited Raman spectrum with cut-off wavenumber down to 200 cm{sup −1} and spectral resolution of 8.0 cm{sup −1} can be obtained under the condition of high purity N{sub 2} purging. With the C–C σ bond in Teflon selectively excited by the 177.3 nm laser, resonance Raman spectrum of Teflon with good quality was recorded on the home-built instrument and the σ-σ{sup *} transition of C–C bond was studied. The result demonstrates that deep UV Raman spectrograph is powerful for studying the systems with electronic transition located in the deep UV region.

  11. Understanding lasers

    SciTech Connect

    Gibilisco, S.

    1989-01-01

    Covering all different types of laser applications-Gibilisco offers an overview of this fascinating phenomenon of light. Here he describes what lasers are and how they work and examines in detail the different kinds of lasers in use today. Topics of particular interest include: the way lasers work; the different kinds of lasers; infrared, ultraviolet and x-ray lasers; use of lasers in industry and manufacturing; use of lasers for long-distance communications; fiberoptic communications; the way laser shows work; the reality of Star Wars; lasers in surgical and medical applications; and holography and the future of laser technology.

  12. Early plume and shock wave dynamics in atmospheric-pressure ultraviolet-laser ablation of different matrix-assisted laser ablation matrices

    SciTech Connect

    Schmitz, Thomas A.; Koch, Joachim; Guenther, Detlef; Zenobi, Renato

    2011-06-15

    Pulsed laser ablation of molecular solids is important for identification and quantification in (bio-)organic mass spectrometry, for example using matrix-assisted laser desorption/ionization (MALDI). Recently, there has been a major shift to using MALDI and related laser ablation/post-ionization methods at atmospheric pressure. However, the underlying laser ablation processes, in particular early plume formation and expansion, are still poorly understood. Here, we present a study of the early ablation processes on the ns-time scale in atmospheric pressure UV-laser ablation of anthracene as well as of different common MALDI matrices such as 2,5-dihydroxybenzoic acid (2,5-DHB), {alpha}-cyano-4-hydroxycinnamic acid and sinapinic acid. Material release as well as the formation and expansion of hemi-spherical shock waves were studied by shadowgraphy with high temporal resolution ({approx}5 ns). The applicability of the classical Taylor-Sedov model for expansion of strong shock waves ('point-blast model'), as well as the drag force model, were evaluated to mathematically describe the observed shock wave propagation. The time- and energy-dependent expansion of the shock waves could be described using a Taylor-Sedov scaling law of the form R {proportional_to} t{sup q}, when a q-exponent of {approx}0.5 instead of the theoretical value of q 0.4 was found, indicating a faster expansion than expected. The deviations from the ideal value of q were attributed to the non-negligible influence of ambient pressure, a weak versus strong shock regime, and additional acceleration processes present in laser ablation that surpass the limit of the point-blast model. The onset of shock wave formation at a fluence of {approx}15-30 mJ/cm{sup 2} for the compounds investigated coincides with the onset of bulk material release, whereas, pure desorption below this fluence threshold did not lead to features visible in shadowgraphy.

  13. Formation and direct writing of color centers in LiF using a laser-induced extreme ultraviolet plasma in combination with a Schwarzschild objective

    SciTech Connect

    Barkusky, Frank; Peth, Christian; Mann, Klaus; Feigl, Torsten; Kaiser, Norbert

    2005-10-15

    In order to generate high-energy densities of 13.5 nm radiation, an extreme ultraviolet (EUV) Schwarzschild mirror objective with a numerical aperture of 0.44 and a demagnification of 10 was developed and adapted to a compact laser-based EUV source. The annular spherical mirror substrates were coated with Mo/Si multilayer systems. With a single mirror reflectance of more than 65% the total transmittance of the Schwarzschild objective exceeds 40% at 13.5 nm. From the properties of the EUV source (pulse energy 3 mJ at 13.5 nm and plasma diameter approximately 300 {mu}m), energy densities of 73 mJ/cm{sup 2} at a pulse length of 6 ns can be estimated in the image plane of the objective. As a first application, the formation of color centers in lithium fluoride crystals by EUV radiation was investigated. F{sub 2}, F{sub 3}, and F{sub 3}{sup +} color centers could be identified by absorption spectroscopy. The formation dynamics was studied as a function of the EUV dose. By imaging of a pinhole positioned behind the plasma, an EUV spot of 5 {mu}m diameter was generated, which accomplishes direct writing of color centers with micrometer resolution.

  14. The use of laser-induced fluorescence or ultraviolet detectors for sensitive and selective analysis of tobramycin or erythropoietin in complex samples

    NASA Astrophysics Data System (ADS)

    Ahmed, Hytham M.; Ebeid, Wael B.

    2015-05-01

    Complex samples analysis is a challenge in pharmaceutical and biopharmaceutical analysis. In this work, tobramycin (TOB) analysis in human urine samples and recombinant human erythropoietin (rhEPO) analysis in the presence of similar protein were selected as representative examples of such samples analysis. Assays of TOB in urine samples are difficult because of poor detectability. Therefore laser induced fluorescence detector (LIF) was combined with a separation technique, micellar electrokinetic chromatography (MEKC), to determine TOB through derivatization with fluorescein isothiocyanate (FITC). Borate was used as background electrolyte (BGE) with negative-charged mixed micelles as additive. The method was successively applied to urine samples. The LOD and LOQ for Tobramycin in urine were 90 and 200 ng/ml respectively and recovery was >98% (n = 5). All urine samples were analyzed by direct injection without sample pre-treatment. Another use of hyphenated analytical technique, capillary zone electrophoresis (CZE) connected to ultraviolet (UV) detector was also used for sensitive analysis of rhEPO at low levels (2000 IU) in the presence of large amount of human serum albumin (HSA). Analysis of rhEPO was achieved by the use of the electrokinetic injection (EI) with discontinuous buffers. Phosphate buffer was used as BGE with metal ions as additive. The proposed method can be used for the estimation of large number of quality control rhEPO samples in a short period.

  15. Direct photo-etching of poly(methyl methacrylate) using focused extreme ultraviolet radiation from a table-top laser-induced plasma source

    SciTech Connect

    Barkusky, Frank; Peth, Christian; Bayer, Armin; Mann, Klaus

    2007-06-15

    In order to perform material interaction studies with intense extreme ultraviolet (EUV) radiation, a Schwarzschild mirror objective coated with Mo/Si multilayers was adapted to a compact laser-based EUV plasma source (pulse energy 3 mJ at {lambda}=13.5 nm, plasma diameter {approx}300 {mu}m). By 10x demagnified imaging of the plasma a pulse energy density of {approx}75 mJ/cm{sup 2} at a pulse length of 6 ns can be achieved in the image plane of the objective. As demonstrated for poly(methyl methacrylate) (PMMA), photoetching of polymer surfaces is possible at this EUV fluence level. This paper presents first results, including a systematic determination of PMMA etching rates under EUV irradiation. Furthermore, the contribution of out-of-band radiation to the surface etching of PMMA was investigated by conducting a diffraction experiment for spectral discrimination from higher wavelength radiation. Imaging of a pinhole positioned behind the plasma accomplished the generation of an EUV spot of 1 {mu}m diameter, which was employed for direct writing of surface structures in PMMA.

  16. Inscription of long period gratings using an ultraviolet laser beam in the diffusion-doped microstructured polymer optical fiber.

    PubMed

    Kowal, Dominik; Statkiewicz-Barabach, Gabriela; Mergo, Pawel; Urbanczyk, Waclaw

    2015-07-10

    We show that diffusion of azobenzene from the solution in methanol into a cladding of a polymer fiber facilitates fabrication of long period gratings by the use of a He-Cd focused laser beam. We have measured a diffusion rate into PMMA cladding of the microstructured fibers annealed in advance at different temperatures and showed that the diffusion rate is strongly affected by temperature treatment of the fiber. We have also investigated an impact of the azobenzene diffusion on fiber spectral loss and cladding surface quality. Furthermore, we have examined a temporal stability of the fabricated long period gratings and their response to temperature and tensile strain. PMID:26193411

  17. Ultraviolet laser-induced poling inhibition produces bulk domains in MgO-doped lithium niobate crystals

    SciTech Connect

    Boes, Andreas Steigerwald, Hendrik; Sivan, Vijay; Mitchell, Arnan; Yudistira, Didit; Wade, Scott; Mailis, Sakellaris; Soergel, Elisabeth

    2014-09-01

    We report the realization of high-resolution bulk domains achieved using a shallow, structured, domain inverted surface template obtained by UV laser-induced poling inhibition in MgO-doped lithium niobate. The quality of the obtained bulk domains is compared to those of the template and their application for second harmonic generation is demonstrated. The present method enables domain structures with a period length as small as 3 μm to be achieved. Furthermore, we propose a potential physical mechanism that leads to the transformation of the surface template into bulk domains.

  18. A two-color infrared-vacuum ultraviolet laser pulsed field ionization photoelectron study of NH3.

    PubMed

    Bahng, Mi-Kyung; Xing, Xi; Baek, Sun Jong; Ng, C Y

    2005-08-22

    We have observed fully rotationally resolved transitions of the photoelectron vibrational bands 2(4), 2(5), 1(1)2(1), and 1(1)2(3) for ammonia cation (NH3+) by two-color infrared (IR)-vacuum ultraviolet (VUV)- pulsed field-ionization photoelectron (PFI-PE) measurements. By preparing an intermediate rovibrational state of neutral NH(3) with a known parity by IR excitation followed by VUV-PFI-PE measurements, we show that the photoelectron parity can be determined unambiguously. The IR-VUV-PFI-PE measurement of the 2(4) band clearly reveals the formation of both even and odd l states for the photoelectrons, where l is the orbital angular momentum quantum number. This observation is consistent with the conclusion that the lack of inversion symmetry for NH3 and NH3+ allows odd/even l mixings, rendering the production of both odd and even l states for the photoelectrons. Evidence is also found, indicating that the photoionization transitions with DeltaK=0 are strongly favored compared to that with DeltaK=3. For the 2(5), 1(1)2(1), and 1(1)2(3) bands, only DeltaK=0 transitions for the production of even l photoelectron states from the J'K'=2(0) rotational level of NH3(nu1=1) are observed. The preferential formation of even l photoelectron states for these vibrational bands is attributed to the fact that the DeltaK=0 transitions for the formation of odd l photoelectron states from the 2(0) rotational level of NH3(nu1=1) are suppressed by the constraint of nuclear-spin statistics. In addition to information obtained on the photoionization dynamics of NH3, this experiment also provides a more precise value of 3232+/-10 cm-1 for the nu1+ (N-H stretch) vibrational frequency of NH3+. PMID:16164295

  19. Ionization of organic molecules with ultraviolet lasers: A technique for generating large, well-defined ionized volumes

    NASA Astrophysics Data System (ADS)

    Woodworth, J. R.; Green, T. A.; Frost, C. A.

    1985-03-01

    In this paper we report a technique for generating a large, homogeneous volume of ionized gas and for making time-resolved measurements of its electron density. We also report absolute photoionization coefficients for a number of molecules. These coefficients will allow calculation of peak electron densities obtained in other ionization-related experiments. In our technique, the beam from a rare-gas halogen laser photoionizes organic molecules that have been seeded into a buffer gas. Ionization is accomplished by the absorption of two photons. We have analyzed the electron densities produced by photoionization with a microwave interferometer that measures the electron density in the ionized gas with a time-resolution of a few nanoseconds. Some of the organic molecules photoionized in this work produce electron-ion pairs with an efficiency more than five orders of magnitude higher than commonly used laboratory ionization sources such as ArF laser photoionization of NO. We have also studied the effect of attaching gases on the ionized mixtures and have demonstrated that addition of as little as 10 Torr of SF6 can reduce the peak electron density observed by a factor of 103.

  20. Analysis of free fatty acids by ultraviolet laser desorption ionization mass spectrometry using insect wings as hydrophobic sample substrates.

    PubMed

    Pirkl, Alexander; Meier, Martin; Popkova, Yulia; Letzel, Matthias; Schnapp, Andreas; Schiller, Jürgen; Dreisewerd, Klaus

    2014-11-01

    Physiologically relevant free fatty acids (FFAs) were analyzed by UV-laser desorption/ionization orthogonal extracting time-of-flight mass spectrometry (LDI-oTOF-MS). Dissected wings from Drosophila melanogaster fruit flies were used as the hydrophobic, laser energy strongly absorbing sample substrates. Using untreated substrates produces predominantly molecular [M + K](+) ions of the FFAs, whereas other alkali metal adducts can be generated by treating the wings with the corresponding alkali hydroxide before spotting of analyte. Limits of detection for the positive ion mode were determined for mixtures of isolated FFAs to values in the low 10 pmol range. Specific values depend on chain length and degree of unsaturation. R(2) coefficients for the analysis of saturated FFAs were found to be generally close to 0.98 over about 3 orders of magnitude if an internal standard (15:0 FFA) was added. Semiquantitative analyses of mixtures containing unsaturated FFAs are also possible but require more effort on the calibration strategy. Notably, both saturated and (poly-)unsaturated FFAs are detected sensitively in the presence of relatively high concentrations of other physiologically abundant lipids (phospholipids and triacyclglycerols). This simplifies screening of the FFA composition in crude tissue extracts. This feature is demonstrated by the analysis of a crude liver extract and that of fingermarks. PMID:25268473

  1. Coherent x-rays and vacuum-ultraviolet radiation from storage-ring-based undulators and free electron lasers

    SciTech Connect

    Kim, K.J.

    1984-12-01

    High-brightness electron storage rings and permanent-magnet technology provide a basis for the development of coherent radiation in the 10- to 1000-A (xuv) spectral range. The most assured route to the production of coherent x-rays and vuv is the simple interaction between properly constrained relativistic electrons and permanent-magnet undulators, a subject that is already well understood and where technology is well advanced. Other techniques are less well developed, but with increasing degrees of technical challenge they will provide additional coherence properties. Transverse optical klystrons (TOKs) provide an opportunity for additional coherence at certain harmonics of longer-wavelength lasers. Free electron lasers (FELs) extend coherence capabilities substantially through two possible routes: one is the development of suitable mirror coatings. Both FEL techniques would provide vuv radiation and soft x rays with extremely narrow spectral content. Research on all of these techniques (undulators, TOKs, and FELs) is possible in a single facility based on a high-brightness electron storage ring, referred to herein as a Coherent xuv Facility (CXF). Individual items from the report were prepared separately for the data base.

  2. Matrix and energy effects during in-situ determination of Cu isotope ratios by ultraviolet-femtosecond laser ablation multicollector inductively coupled plasma mass spectrometry

    NASA Astrophysics Data System (ADS)

    Lazarov, Marina; Horn, Ingo

    2015-09-01

    Copper isotope compositions in Cu-bearing metals and minerals have been measured by deep (194 nm) ultraviolet femtosecond laser ablation multi-collector inductively coupled plasma mass spectrometry (UV-fsLA-MC-ICP-MS). Pure Cu-metal, brass, and several Cu-rich minerals (chalcopyrite, enargite, covellite, malachite and cuprite) have been investigated. A long-term reproducibility of better than 0.08‰ at the 95% confidence limit on the NIST SRM 976 (National Institute of Standards and Technology) Cu-metal standard has been achieved with this technique. The δ65Cu values for all samples have been calculated by standard-sample-standard bracketing with NIST SRM 976. All analyses have been carried out using Ni as a mass discrimination monitor added by nebulization prior to entering the plasma torch. For further verification samples have been analysed by conventional solution nebulization MC-ICP-MS and the results obtained have been compared with those from UV-fsLA-MC-ICP-MS. Several potential matrix-induced molecular interferences on the mineral copper isotope ratio, such as (32S33S)+ and (32S-16O17O)+ do not affect the Cu isotope measurements on sulfides, while hydrides, such as Zn-H or doubly-charged Sn2 + that interfere Ni isotopes can be either neglected or stripped by calculation. Matrix independent Cu-isotope measurements are sensitive to the energy density (fluence) applied onto the sample and can produce artificial shifts in the obtained δ65Cu values which are on the order of 3‰ for Cu-metal, 0.5‰ for brass and 0.3‰ for malachite when using energy density of up to 2 J/cm2 for ablation. A positive correlation between applied energy density and the magnitude of the isotope ratio shift has been found in the energy density range from 0.2 to 1.3 J/cm2 which is below the ablation threshold for ns-laser ablation. The results demonstrate that by using appropriate low fluence it is possible to measure Cu isotopic ratios in native copper and Cu-bearing sulfides

  3. Infrared spectra and ultraviolet-tunable laser induced photochemistry of matrix-isolated phenol and phenol-d5

    NASA Astrophysics Data System (ADS)

    Giuliano, Barbara Michela; Reva, Igor; Lapinski, Leszek; Fausto, Rui

    2012-01-01

    Monomers of phenol and its ring-perdeuterated isotopologue phenol-d5 were isolated in argon matrices at 15 K. The infrared (IR) spectra of these species were recorded and analyzed. In situ photochemical transformations of phenol and phenol-d5 were induced by tunable UV laser light. The photoproducts have been characterized by IR spectroscopy supported by theoretical calculations of the infrared spectra. The primary product photogenerated from phenol was shown to be the phenoxyl radical. The analysis of the progress of the observed phototransformations led to identification of 2,5-cyclohexadienone as one of the secondary photoproducts. Spectral indications of other secondary products, such as the Dewar isomer and the open-ring ketene, were also detected. Identification of the photoproducts provided a guide for the interpretation of the mechanisms of the observed photoreactions.

  4. Extreme ultraviolet absorption measurements of low Z, low density, low temperature plasmas at the Orion Laser Facility

    NASA Astrophysics Data System (ADS)

    Hobbs, Lauren; Brown, Colin; Hoarty, David; Hill, Matthew; James, Steven; Allan, Peter; Orion Laser Team

    2015-11-01

    Experiments have been carried out to demonstrate a platform on the Orion laser to study the equation of state of low Z elements in a low density, low temperature regime (around mg/cc, 10s eV). In this regime equation of state models based on Thomas-Fermi ion cell predict significant departure from ideal-gas + ionization predictions. In these experiments absorption measurements using point-projection backlighting aim to determine the change in ionisation as a function of material density at constant temperature to test model prediction. Initial work reported has shown that absorption data can be taken from X-ray heated samples with sufficient accuracy; short-pulse, high-contrast pulses can be used to explode the sample foil to the required low density, and a new XUV grating spectrometer has been commissioned and used for absorption measurements.

  5. Ultraviolet photodegradation of tris(8-hydroxy-quinolinate) aluminum (Alq3) thin films studied by electron and laser stimulated desorption

    NASA Astrophysics Data System (ADS)

    Brito, W. R.; Quirino, W. G.; Legnani, C.; Ponciano, C. R.; Cremona, M.; Rocco, M. L. M.

    2012-11-01

    Alq3 has been the reference material used widely in the fabrication and characterization of efficient OLEDs due to its good properties as electroluminescent and electron transporting layer. Although the inclusion of these devices in commercial displays and lighting devices represents many benefits, the knowledge about the progressive loss of performance and efficiency with time for such devices is still limited. Therefore, it is an incentive to understand the mechanisms of Alq3 degradation when it is subjected to the influence of various extrinsic factors such as UV radiation. In the present work the degradation processes of Alq3 thin films as a result of 254 nm UV light irradiation are presented and discussed. The degradation products produced by the action of UV light were evaluated by time-of-flight mass spectrometry using electron stimulated ion desorption and laser desorption ionization techniques. Strong evidence for carboxylic acid formation after photodegradation was observed by the electron desorption technique.

  6. Wavelength conversion of quadrupled Nd:YAG laser radiation to the vacuum ultraviolet by anti-stokes stimulated Raman scattering

    NASA Astrophysics Data System (ADS)

    Moriwaki, Hiroki; Wada, Satoshi; Tashiro, Hideo; Toyoda, Koichi; Kasai, Akinari; Nakamura, Akira

    1993-08-01

    The observations from the beam property measurements of anti-Stokes (AS) pulses produced form AS Raman scattering (ASRS) using a quadrupled Nd:YAG laser were presented. The beam profiles of each AS wave were photographically examined. The beam pattern did not always exhibit a ring shape, but became tophatlike shaped or Gaussian-like shaped, provided the hydrogen pressure was kept lower than 0.39 MPa. The beam divergence of the AS ring radiation was elucidated using a model in which the wave front of the pump beam was considered as a plane within the Rayleigh region. The output energies of AS beams up to the ninth order were also estimated. The well-defined coherent vuv radiation produced by a tabletop ASRS system can be a fitting source for different application such as ablation of polymer films.

  7. Infrared spectra and ultraviolet-tunable laser induced photochemistry of matrix-isolated phenol and phenol-d{sub 5}

    SciTech Connect

    Giuliano, Barbara Michela; Reva, Igor; Fausto, Rui; Lapinski, Leszek

    2012-01-14

    Monomers of phenol and its ring-perdeuterated isotopologue phenol-d{sub 5} were isolated in argon matrices at 15 K. The infrared (IR) spectra of these species were recorded and analyzed. In situ photochemical transformations of phenol and phenol-d{sub 5} were induced by tunable UV laser light. The photoproducts have been characterized by IR spectroscopy supported by theoretical calculations of the infrared spectra. The primary product photogenerated from phenol was shown to be the phenoxyl radical. The analysis of the progress of the observed phototransformations led to identification of 2,5-cyclohexadienone as one of the secondary photoproducts. Spectral indications of other secondary products, such as the Dewar isomer and the open-ring ketene, were also detected. Identification of the photoproducts provided a guide for the interpretation of the mechanisms of the observed photoreactions.

  8. Dual wavelength laser-induced damage threshold measurements of alumina/silica and hafnia/silica ultraviolet antireflective coatings.

    PubMed

    Mrohs, Marius; Jensen, Lars; Günster, Stefan; Alig, Thimotheus; Ristau, Detlev

    2016-01-01

    An approach for the measurement of the laser-induced damage threshold with two wavelengths combined was made while testing antireflective coatings for the wavelengths 266 and 532 nm. Samples were made of Al2O3/SiO2 and HfO2/SiO2 ion beam sputtered films. The results show that adding radiation of a second wavelength might lead to a significant reduction of the threshold. The damage morphology of single and dual wavelength tests is very similar and does not suggest an altered damage mechanism. Further investigations indicated that the dual wavelength threshold is a function of the temporal delay of the two pulses. PMID:26835628

  9. Laser-ultraviolet-A induced ultra weak photon emission in human skin cells: A biophotonic comparison between keratinocytes and fibroblasts.

    PubMed

    Niggli, Hugo J; Tudisco, Salvatore; Lanzanò, Luca; Applegate, Lee Ann; Scordino, Agata; Musumeci, Francesco

    2008-05-01

    Photons participate in many atomic and molecular interactions and processes. Recent biophysical research has discovered an ultraweak radiation in biological tissues. It is now recognized that plants, animal and human cells emit this very weak biophotonic emission which can be readily measured with a sensitive photomultiplier system. UVA laser induced biophotonic emission of cultured cells was used in this report with the intention to detect biophysical changes between young and adult fibroblasts as well as between fibroblasts and keratinocytes. With suspension densities ranging from 1-8 x 106 cells/ml, it was evident that an increase of the UVA-laser-light induced photon emission intensity could be observed in young as well as adult fibroblastic cells. By the use of this method to determine ultraweak light emission, photons in cell suspensions in low volumes (100 microl) could be detected, in contrast to previous procedures using quantities up to 10 ml. Moreover, the analysis has been further refined by turning off the photomultiplier system electronically during irradiation leading to the first measurements of induced light emission in the cells after less than 10 micros instead of more than 100 milliseconds. These significant changes lead to an improvement factor up to 106 in comparison to classical detection procedures. In addition, different skin cells as fibroblasts and keratinocytes stemming from the same donor were measured using this new highly sensitive method in order to find new biophysical insight of light pathways. This is important in view to develop new strategies in biophotonics especially for use in alternative therapies. PMID:18697620

  10. Lasers.

    ERIC Educational Resources Information Center

    Schewe, Phillip F.

    1981-01-01

    Examines the nature of laser light. Topics include: (1) production and characteristics of laser light; (2) nine types of lasers; (3) five laser techniques including holography; (4) laser spectroscopy; and (5) laser fusion and other applications. (SK)

  11. Study of polymer ablation products obtained by ultraviolet laser ablation — inductively coupled plasma atomic emission spectrometry

    NASA Astrophysics Data System (ADS)

    Todolí, J.-L.; Mermet, J.-M.

    1998-10-01

    A study of the nature of aerosols following polymer laser ablation was performed. A glass sample was used for comparison. Aerosol fractions were analyzed by using simple methods based on transport efficiency and filters. Three different tube lengths, i.e. 4, 29 and 54 m, were inserted between the ablation cell and the inductively coupled plasma atomic emission spectrometry (ICP-AES) injector. For the glass sample, 10 elements were studied. Only Na and K exhibited different results as the particle size, i.e. tube length, was varied. The polymers used were poly(vinyl chloride), PVC, and poly(ethylene), PE. Three elements (Ca, Ti and Sn) under different chemical forms were measured. Unlike Ti and Sn the ablated aerosol particle size (mass) seemed to depend on the Ca chemical form. Another PVC sample containing 11 elements was also studied. Na, Al and C exhibited a different behavior with particle size with respect to the remaining elements. Then, the carbon signal was studied after a 0.3 μm pore size filter had been placed between the ablation cell and the ICP torch. The results indicated that carbon was mainly present under gaseous form and particles smaller than 0.3 μm size. The analysis of the aerosol gaseous phase by thermal desorption GC-MS confirmed the presence of polymer volatile thermal degradation products. These results explained why carbon could not be applied as an efficient internal standard.

  12. Laser plasma sources of soft x-rays and extreme ultraviolet (EUV) for technology, biomedical, and metrology applications

    NASA Astrophysics Data System (ADS)

    Bartnik, Andrzej; Fiedorowicz, Henryk; Jarocki, Roman; Kostecki, Jerzy; Rakowski, Rafał; Sawicka, Magdalena; Szczurek, Mirosław

    2008-12-01

    In this paper some results of investigations concerning interaction of EUV radiation with inorganic and organic materials were presented. Samples of different materials were irradiated with a 10 Hz laser - plasma EUV source based on a gas puff target. The source was equipped with grazing incidence and multilayer collecting mirrors. The grazing incidence collector was used in experiments concerning surface modification and micromachining of different materials. The micromachining experiments were performed for different polymers that were irradiated through a fine metal grid as a contact mask. For fluoropolymers, EUV radiation with fluence of 10 mJ/cm2 was enough for efficient photo-etching. The photo-etching speed was maximal for polytetrafluoroethylene (PTFE) reaching 30nm per shot. It was shown that using such a method microstructures with high aspect ratio could be produced. Experiments connected with surface modification were performed either with organic or inorganic materials. Different kinds of surface structures were obtained depending on irradiated materials and irradiation parameters. The Mo/Si collector together with argon plasma was used for obtaining a quasi-monochromatic radiation for EUV microscopy and some metrological applications.

  13. Infrared-Vacuum Ultraviolet Pulsed Field Ionization-Photoelectron Study of C₂H₄ + Using a High-Resolution Infrared Laser

    SciTech Connect

    Xing, Xi; Reed, Beth; Bahng, Mi-Kyung; Ng, Cheuk-Yiu

    2008-02-20

    The research described in this product was performed in part in the Environmental Molecular Sciences Laboratory, a national scientific user facility sponsored by the Department of Energy's Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory. The infrared (IR)-vacuum ultraviolet (VUV)-pulsed field ionization-photoelectron (IR-VUV-PFI-PE) spectrum for C₂H₄(X 1Ag, V11 = 1, N'Ka'Kc'=3₀₃) in the VUV range of 83 000-84 800 cm-1 obtained using a single mode infrared laser revealed 24 rotationally resolved vibrational bands for the ion C₂H₄ +(X 2B3u) ground state. The frequencies and symmetry of the vibrational bands thus determined, together with the anharmonic frequency predictions calculated at the CCSD(T)/aug-cc-pVQZ level, have allowed the unambiguous assignment of these vibrational bands. These bands are mostly combination bands. The measured frequencies of these bands yield the fundamental frequencies for V8 + ) 1103± ( 10 cm-1 and V10 + ) 813 ( 10 cm-1 of C₂H₄ +(X 2B3u), which have not been determined previously. The present IR-VUV-PFI-PE study also provides truly rovibrationally selected and resolved state-to-state cross sections for the photoionization transitions C₂H₄(X~1Ag; V11, N'Ka'Kc') → C₂H₄ +(X~ 2B3u; Vi +, N+ Ka +Kc +), where N'Ka'Kc' denotes the rotational level of C₂H₄(X~ 1Ag; V11), and Vi + and N+ Ka +Kc + represent the vibrational and rotational states of the cation.

  14. Compact, passively Q-switched, all-solid-state master oscillator-power amplifier-optical parametric oscillator (MOPA-OPO) system pumped by a fiber-coupled diode laser generating high-brightness, tunable, ultraviolet radiation.

    PubMed

    Peuser, Peter; Platz, Willi; Fix, Andreas; Ehret, Gerhard; Meister, Alexander; Haag, Matthias; Zolichowski, Paul

    2009-07-01

    We report on a compact, tunable ultraviolet laser system that consists of an optical parametric oscillator (OPO) and a longitudinally diode-pumped Nd:YAG master oscillator-power amplifier (MOPA). The pump energy for the whole laser system is supplied via a single delivery fiber. Nanosecond pulses are produced by an oscillator that is passively Q-switched by a Cr(4+):YAG crystal. The OPO is pumped by the second harmonic of the Nd:YAG MOPA. Continuously tunable radiation is generated by an intracavity sum-frequency mixing process within the OPO in the range of 245-260 nm with high beam quality. Maximum pulse energies of 1.2 mJ were achieved, which correspond to an optical efficiency of 3.75%, relating to the pulse energy of the MOPA at 1064 nm. PMID:19571944

  15. Ultraviolet fluorescence monitor

    SciTech Connect

    Hargis, P.J. Jr.; Preppernau, B.L.; Aragon, B.P.

    1997-05-01

    A multispectral ultraviolet (UV) fluorescence imaging fluorometer and a pulsed molecular beam laser fluorometer were developed to detect volatile organic compounds of interest in environmental monitoring and drug interdiction applications. The UV fluorescence imaging fluorometer is a relatively simple instrument which uses multiple excitation wavelengths to measure the excitation/emission matrix for irradiated samples. Detection limits in the high part-per-million to low part-per-million range were measured for a number of volatile organic vapors in the atmosphere. Detection limits in the low part-per-million range were obtained using cryogenic cooling to pre-concentrate unknown samples before introducing them into the imaging fluorometer. A multivariate analysis algorithm was developed to analyze the excitation/emission matrix and used to determine the relative concentrations of species in computer synthesized mixtures containing up to five organic compounds. Analysis results demonstrated the utility of multispectral UV fluorescence in analytical measurements. A transportable UV fluorescence imaging fluorometer was used in two field tests. Field test results demonstrated that detection limits in the part-per-billion range were needed to reliably identify volatile organic compounds in realistic field test measurements. The molecular beam laser fluorometer, a more complex instrument with detection limits in the part-per-billion to part-per-trillion range, was therefore developed to satisfy detection sensitivity requirements for field test measurements. High-resolution spectroscopic measurements made with the molecular beam laser fluorometer demonstrated its utility in identifying volatile organic compounds in the atmosphere.

  16. JPL Fourier transform ultraviolet spectrometer

    NASA Technical Reports Server (NTRS)

    Cageao, R. P.; Friedl, R. R.; Sander, Stanley P.; Yung, Y. L.

    1994-01-01

    The Fourier Transform Ultraviolet Spectrometer (FTUVS) is a new high resolution interferometric spectrometer for multiple-species detection in the UV, visible and near-IR. As an OH sensor, measurements can be carried out by remote sensing (limb emission and column absorption), or in-situ sensing (long-path absorption or laser-induced fluorescence). As a high resolution detector in a high repetition rate (greater than 10 kHz) LIF system, OH fluorescence can be discriminated against non-resonant background emission and laser scatter, permitting (0, 0) excitation.

  17. Extreme ultraviolet lithography machine

    DOEpatents

    Tichenor, Daniel A.; Kubiak, Glenn D.; Haney, Steven J.; Sweeney, Donald W.

    2000-01-01

    An extreme ultraviolet lithography (EUVL) machine or system for producing integrated circuit (IC) components, such as transistors, formed on a substrate. The EUVL machine utilizes a laser plasma point source directed via an optical arrangement onto a mask or reticle which is reflected by a multiple mirror system onto the substrate or target. The EUVL machine operates in the 10-14 nm wavelength soft x-ray photon. Basically the EUV machine includes an evacuated source chamber, an evacuated main or project chamber interconnected by a transport tube arrangement, wherein a laser beam is directed into a plasma generator which produces an illumination beam which is directed by optics from the source chamber through the connecting tube, into the projection chamber, and onto the reticle or mask, from which a patterned beam is reflected by optics in a projection optics (PO) box mounted in the main or projection chamber onto the substrate. In one embodiment of a EUVL machine, nine optical components are utilized, with four of the optical components located in the PO box. The main or projection chamber includes vibration isolators for the PO box and a vibration isolator mounting for the substrate, with the main or projection chamber being mounted on a support structure and being isolated.

  18. The role of film interfaces in near-ultraviolet absorption and pulsed-laser damage in ion-beam-sputtered coatings based on HfO2/SiO2 thin-film pairs

    DOE PAGESBeta

    Ristau, Detlev; Papernov, S.; Kozlov, A. A.; Oliver, J. B.; Smith, C.; Jensen, L.; Gunster, S.; Madebach, H.

    2015-11-23

    The role of thin-film interfaces in the near-ultraviolet absorption and pulsed-laser–induced damage was studied for ion-beam–sputtered and electron-beam–evaporated coatings comprised from HfO2 and SiO2 thin-film pairs. To separate contributions from the bulk of the film and from interfacial areas, absorption and damage-threshold measurements were performed for a one-wave (355-nm wavelength) thick, HfO2 single-layer film and for a film containing seven narrow HfO2 layers separated by SiO2 layers. The seven-layer film was designed to have a total optical thickness of HfO2 layers, equal to one wave at 355 nm and an E-field peak and average intensity similar to a single-layer HfO2more » film. Absorption in both types of films was measured using laser calorimetry and photothermal heterodyne imaging. The results showed a small contribution to total absorption from thin-film interfaces, as compared to HfO2 film material. The relevance of obtained absorption data to coating near-ultraviolet, nanosecond-pulse laser damage was verified by measuring the damage threshold and characterizing damage morphology. The results of this study revealed a higher damage resistance in the seven-layer coating as compared to the single-layer HfO2 film in both sputtered and evaporated coatings. Here, the results are explained through the similarity of interfacial film structure with structure formed during the co-deposition of HfO2 and SiO2 materials.« less

  19. The role of film interfaces in near-ultraviolet absorption and pulsed-laser damage in ion-beam-sputtered coatings based on HfO2/SiO2 thin-film pairs

    SciTech Connect

    Ristau, Detlev; Papernov, S.; Kozlov, A. A.; Oliver, J. B.; Smith, C.; Jensen, L.; Gunster, S.; Madebach, H.

    2015-11-23

    The role of thin-film interfaces in the near-ultraviolet absorption and pulsed-laser–induced damage was studied for ion-beam–sputtered and electron-beam–evaporated coatings comprised from HfO2 and SiO2 thin-film pairs. To separate contributions from the bulk of the film and from interfacial areas, absorption and damage-threshold measurements were performed for a one-wave (355-nm wavelength) thick, HfO2 single-layer film and for a film containing seven narrow HfO2 layers separated by SiO2 layers. The seven-layer film was designed to have a total optical thickness of HfO2 layers, equal to one wave at 355 nm and an E-field peak and average intensity similar to a single-layer HfO2 film. Absorption in both types of films was measured using laser calorimetry and photothermal heterodyne imaging. The results showed a small contribution to total absorption from thin-film interfaces, as compared to HfO2 film material. The relevance of obtained absorption data to coating near-ultraviolet, nanosecond-pulse laser damage was verified by measuring the damage threshold and characterizing damage morphology. The results of this study revealed a higher damage resistance in the seven-layer coating as compared to the single-layer HfO2 film in both sputtered and evaporated coatings. Here, the results are explained through the similarity of interfacial film structure with structure formed during the co-deposition of HfO2 and SiO2 materials.

  20. The role of film interfaces in near-ultraviolet absorption and pulsed-laser damage in ion-beam-sputtered coatings based on HfO2/SiO2 thin-films pairs

    SciTech Connect

    Papernov, S.; Kozlov, A. A.; Oliver, J. B.; Smith, C.; Jensen, L.; Ristau, D.; Gunster, S.; Madebach, H.

    2015-11-23

    Here, the role of thin-film interfaces in the near-ultraviolet absorption and pulsed-laser–induced damage was studied for ion-beam–sputtered and electron-beam–evaporated coatings comprised from HfO2 and SiO2 thin-film pairs. To separate contributions from the bulk of the film and from interfacial areas, absorption and damage-threshold measurements were performed for a one-wave (355-nm wavelength) thick, HfO2 single-layer film and for a film containing seven narrow HfO2 layers separated by SiO2 layers. The seven-layer film was designed to have a total optical thickness of HfO2 layers, equal to one wave at 355 nm and an E-field peak and average intensity similar to a single-layer HfO2 film. Absorption in both types of films was measured using laser calorimetry and Photothermal heterodyne imaging. The results showed a small contribution to total absorption from thin-film interfaces, as compared to HfO2 film material. The relevance of obtained absorption data to coating near-ultraviolet, nanosecond-pulse laser damage was verified by measuring the damage threshold and characterizing damage morphology. The results of this study revealed a higher damage resistance in the seven-layer coating as compared to the single-layer HfO2 film in both sputtered and evaporated coatings. The results are explained through the similarity of interfacial film structure with structure formed during the co-deposition of HfO2 and SiO2 materials.

  1. The role of film interfaces in near-ultraviolet absorption and pulsed-laser damage in ion-beam-sputtered coatings based on HfO2/SiO2 thin-films pairs

    DOE PAGESBeta

    Papernov, S.; Kozlov, A. A.; Oliver, J. B.; Smith, C.; Jensen, L.; Ristau, D.; Gunster, S.; Madebach, H.

    2015-11-23

    Here, the role of thin-film interfaces in the near-ultraviolet absorption and pulsed-laser–induced damage was studied for ion-beam–sputtered and electron-beam–evaporated coatings comprised from HfO2 and SiO2 thin-film pairs. To separate contributions from the bulk of the film and from interfacial areas, absorption and damage-threshold measurements were performed for a one-wave (355-nm wavelength) thick, HfO2 single-layer film and for a film containing seven narrow HfO2 layers separated by SiO2 layers. The seven-layer film was designed to have a total optical thickness of HfO2 layers, equal to one wave at 355 nm and an E-field peak and average intensity similar to a single-layermore » HfO2 film. Absorption in both types of films was measured using laser calorimetry and Photothermal heterodyne imaging. The results showed a small contribution to total absorption from thin-film interfaces, as compared to HfO2 film material. The relevance of obtained absorption data to coating near-ultraviolet, nanosecond-pulse laser damage was verified by measuring the damage threshold and characterizing damage morphology. The results of this study revealed a higher damage resistance in the seven-layer coating as compared to the single-layer HfO2 film in both sputtered and evaporated coatings. The results are explained through the similarity of interfacial film structure with structure formed during the co-deposition of HfO2 and SiO2 materials.« less

  2. Method for extreme ultraviolet lithography

    DOEpatents

    Felter, T. E.; Kubiak, G. D.

    2000-01-01

    A method of producing a patterned array of features, in particular, gate apertures, in the size range 0.4-0.05 .mu.m using projection lithography and extreme ultraviolet (EUV) radiation. A high energy laser beam is used to vaporize a target material in order to produce a plasma which in turn, produces extreme ultraviolet radiation of a characteristic wavelength of about 13 nm for lithographic applications. The radiation is transmitted by a series of reflective mirrors to a mask which bears the pattern to be printed. The demagnified focused mask pattern is, in turn, transmitted by means of appropriate optics and in a single exposure, to a substrate coated with photoresists designed to be transparent to EUV radiation and also satisfy conventional processing methods.

  3. Method for extreme ultraviolet lithography

    DOEpatents

    Felter, T. E.; Kubiak, Glenn D.

    1999-01-01

    A method of producing a patterned array of features, in particular, gate apertures, in the size range 0.4-0.05 .mu.m using projection lithography and extreme ultraviolet (EUV) radiation. A high energy laser beam is used to vaporize a target material in order to produce a plasma which in turn, produces extreme ultraviolet radiation of a characteristic wavelength of about 13 nm for lithographic applications. The radiation is transmitted by a series of reflective mirrors to a mask which bears the pattern to be printed. The demagnified focused mask pattern is, in turn, transmitted by means of appropriate optics and in a single exposure, to a substrate coated with photoresists designed to be transparent to EUV radiation and also satisfy conventional processing methods.

  4. Molecular photoelectron angular distribution rotations in multi-photon resonant ionization of H{sub 2}{sup +} by circularly polarized ultraviolet laser pulses

    SciTech Connect

    Yuan, Kai-Jun Chelkowski, Szczepan; Bandrauk, André D.

    2015-04-14

    We study effects of pulse durations on molecular photoelectron angular distributions (MPADs) in ultrafast circular polarization ultraviolet resonant ionization processes. Simulations performed on aligned H{sub 2}{sup +} by numerically solving time dependent Schrödinger equations show rotations of MPADs with respect to the molecular symmetry axes. It is found that in multi-photon resonant ionization processes, rotation angles are sensitive to pulse durations, which we attribute to the coherent resonant excitation between the ground state and the intermediate excited electronic state induced by Rabi oscillations. Multi-photon nonresonant and single photon ionization processes are simulated and compared which exhibit a constant rotation angle. An asymmetry parameter is introduced to describe the pulse duration sensitivity by perturbation theory models. Influence of pulse frequency detunings on MPADs is also investigated where oscillations of rotations are absent at long pulse durations due to nonresonance excitation.

  5. Ultraviolet characterization of integrating spheres.

    PubMed

    Shaw, Ping-Shine; Li, Zhigang; Arp, Uwe; Lykke, Keith R

    2007-08-01

    We have studied the performance of polytetrafluoroethylene integrating spheres in the ultraviolet (UV) region with wavelengths as short as 200 nm. Two techniques were used for this study; first, the spectral throughput of an integrating sphere irradiated by a deuterium lamp was analyzed by a monochromator. Second, a UV laser beam was directed into an integrating sphere, and spectrally dispersed laser induced fluorescence was studied. Significant absorption and fluorescence features were observed in the UV region and attributed to the contamination in the integrating sphere. We demonstrate that integrating spheres are easily contaminated by environmental pollutants such as polycyclic aromatic hydrocarbons emitted from engine exhaust. Baking of the contaminated integrating sphere can reverse some but not all of the effects caused by contaminants. The implications for using integrating spheres for UV measurement are discussed. PMID:17676122

  6. Ultraviolet characterization of integrating spheres

    NASA Astrophysics Data System (ADS)

    Shaw, Ping-Shine; Li, Zhigang; Arp, Uwe; Lykke, Keith R.

    2007-08-01

    We have studied the performance of polytetrafluoroethylene integrating spheres in the ultraviolet (UV) region with wavelengths as short as 200 nm. Two techniques were used for this study; first, the spectral throughput of an integrating sphere irradiated by a deuterium lamp was analyzed by a monochromator. Second, a UV laser beam was directed into an integrating sphere, and spectrally dispersed laser induced fluorescence was studied. Significant absorption and fluorescence features were observed in the UV region and attributed to the contamination in the integrating sphere. We demonstrate that integrating spheres are easily contaminated by environmental pollutants such as polycyclic aromatic hydrocarbons emitted from engine exhaust. Baking of the contaminated integrating sphere can reverse some but not all of the effects caused by contaminants. The implications for using integrating spheres for UV measurement are discussed.

  7. Ultrafast electronic dynamics in polyatomic molecules studied using femtosecond vacuum ultraviolet and x-ray pulses

    NASA Astrophysics Data System (ADS)

    Suzuki, Toshinori

    2014-06-01

    Time-resolved velocity map photoelectron imaging is performed using sub-20 fs deep ultraviolet and vacuum ultraviolet pulses to study electronic dynamics of isolated polyatomic molecules. The non-adiabatic dynamics of pyrazine, furan and carbon disulfide (CS2) are described as examples. Also described is sub-picosecond time-resolved x-ray direct absorption spectroscopy using a hard x-ray free electron laser (SACLA) and a synchronous near ultraviolet laser to study ultrafast electronic dynamics in solutions.

  8. Optical emission spectroscopy and time-of-flight investigations of plasmas generated from AlN targets in cases of pulsed laser deposition with sub-ps and ns ultraviolet laser pulses

    NASA Astrophysics Data System (ADS)

    Ristoscu, Carmen; Mihailescu, Ion N.; Velegrakis, Michalis; Massaouti, Maria; Klini, Argyro; Fotakis, Costas

    2003-02-01

    We performed a comparative study of the plasma generated from AlN targets under sub-ps vs ns UV (λ=248 nm) excimer laser pulses. Optical emission and time-of-flight spectra recorded in cases of samples irradiated with ns laser pulses showed the presence of Al lines, which became prevalent after the first laser pulse was incident on the target. These observations are congruent with the metallization of AlN targets inside each crater under multipulse ns laser action at laser fluences above the ablation threshold, observed by visual inspection and optical microscopy. Metallization was not observed when working with sub-ps laser pulses. Moreover, our studies confirmed the predominant presence of AlN positive molecular ions in the plasma generated in front of AlN targets submitted to sub-ps multipulse laser irradiation. The optical emission data are in good agreement with time-of-flight mass analysis. We emphasize that all investigations support the experimental evidence reported by György et al. [E. György et al., J. Appl. Phys. 90, 456 (2001)], according to which thin films obtained by pulsed laser deposition with ns laser pulses contain a significant amount of metallic Al, while only AlN is detected in films obtained with sub-ps laser pulses. Measurements of the velocity and kinetic energy distributions of AlN+ indicate that in the case of ns-laser ablation the ions are emitted with thermal energy, while in the case of sub-ps-laser ablation a bimodal distribution exists and has thermal (1 eV) and hyperthermal (10 eV) energy components. This points to different plasma formation mechanisms for the two cases.

  9. High-sensitivity detection of CH radicals in flames by use of a diode-laser-based near-ultraviolet light source.

    PubMed

    Peterson, K A; Oh, D B

    1999-05-15

    CH radical distributions in ethylene-air and methane-air diffusion flames are mapped by wavelength-modulation absorption spectroscopy (WMS). Tunable, wavelength-modulated 426-nm light is generated by frequency doubling of a modulated 852-nm distributed Bragg reflector diode laser. Absorbances of 5 x 10(-5) are measured with second-harmonic (2f) WMS with a signal-to-noise ratio of 3:1 in a 3-Hz measurement bandwidth. The feasibility of simultaneous line-of-sight absorption and spatially resolved laser-induced-fluorescence detection with a single excitation beam is also demonstrated. This near-UV source is suitable for microgravity drop-tower experiments and other applications in which compact, rugged, energy-efficient instrumentation is required. PMID:18073817

  10. Volume growth initiated by point-to-point ultraviolet-laser direct writing in hybrid solgel glass for three-dimensional microfabrication.

    PubMed

    Yu, Weixing; Yuan, X C

    2003-09-01

    Volume-growth solgel glass acting as self-developing material is used for three-dimensional (3D) fabrication of micro-optical elements. The solgel glass is exposed to a focused laser beam (lambda = 325 nm), and surface corrugation is created as a result of surface expansion in the exposed area. The profile depth is related to the laser beam intensity, which is controlled by an acousto-optic modulator, which makes it possible to fabricate 3D structures in the material. Preliminary results show that the controllable volume-growth effect will be of considerable use for production of 3D micro-optical elements with excellent surface smoothness in solgel materials. PMID:12956383

  11. 750 mW continuous-wave solid-state deep ultraviolet laser source at the 253.7 nm transition in mercury.

    PubMed

    Scheid, Martin; Markert, Frank; Walz, Jochen; Wang, Jiayu; Kirchner, Martin; Hänsch, Theodor W

    2007-04-15

    A high-power continuous-wave coherent light source at 253.7 nm is described. It is based on a solid-state Yb:YAG disk laser with two successive frequency doubling stages and is capable of generating stable output powers of up to 750 mW. Spectroscopy of the 6 (1)S(0)-6 (3)P(1) transition of mercury has been demonstrated. PMID:17375166

  12. Deep ultraviolet laser direct write for patterning sol-gel InGaZnO semiconducting micro/nanowires and improving field-effect mobility.

    PubMed

    Lin, Hung-Cheng; Stehlin, Fabrice; Soppera, Olivier; Zan, Hsiao-Wen; Li, Chang-Hung; Wieder, Fernand; Ponche, Arnaud; Berling, Dominique; Yeh, Bo-Hung; Wang, Kuan-Hsun

    2015-01-01

    Deep-UV (DUV) laser was used to directly write indium-gallium-zinc-oxide (IGZO) precursor solution and form micro and nanoscale patterns. The directional DUV laser beam avoids the substrate heating and suppresses the diffraction effect. A IGZO precursor solution was also developed to fulfill the requirements for direct photopatterning and for achieving semi-conducting properties with thermal annealing at moderate temperature. The DUV-induced crosslinking of the starting material allows direct write of semi-conducting channels in thin-film transistors but also it improves the field-effect mobility and surface roughness. Material analysis has been carried out by XPS, FTIR, spectroscopic ellipsometry and AFM and the effect of DUV on the final material structure is discussed. The DUV irradiation step results in photolysis and a partial condensation of the inorganic network that freezes the sol-gel layer in a homogeneous distribution, lowering possibilities of thermally induced reorganization at the atomic scale. Laser irradiation allows high-resolution photopatterning and high-enough field-effect mobility, which enables the easy fabrication of oxide nanowires for applications in solar cell, display, flexible electronics, and biomedical sensors. PMID:26014902

  13. Deep ultraviolet laser direct write for patterning sol-gel InGaZnO semiconducting micro/nanowires and improving field-effect mobility

    PubMed Central

    Lin, Hung-Cheng; Stehlin, Fabrice; Soppera, Olivier; Zan, Hsiao-Wen; Li, Chang-Hung; Wieder, Fernand; Ponche, Arnaud; Berling, Dominique; Yeh, Bo-Hung; Wang, Kuan-Hsun

    2015-01-01

    Deep-UV (DUV) laser was used to directly write indium-gallium-zinc-oxide (IGZO) precursor solution and form micro and nanoscale patterns. The directional DUV laser beam avoids the substrate heating and suppresses the diffraction effect. A IGZO precursor solution was also developed to fulfill the requirements for direct photopatterning and for achieving semi-conducting properties with thermal annealing at moderate temperature. The DUV-induced crosslinking of the starting material allows direct write of semi-conducting channels in thin-film transistors but also it improves the field-effect mobility and surface roughness. Material analysis has been carried out by XPS, FTIR, spectroscopic ellipsometry and AFM and the effect of DUV on the final material structure is discussed. The DUV irradiation step results in photolysis and a partial condensation of the inorganic network that freezes the sol-gel layer in a homogeneous distribution, lowering possibilities of thermally induced reorganization at the atomic scale. Laser irradiation allows high-resolution photopatterning and high-enough field-effect mobility, which enables the easy fabrication of oxide nanowires for applications in solar cell, display, flexible electronics, and biomedical sensors. PMID:26014902

  14. Ultraviolet laser crystallized ZnO:Al films on sapphire with high Hall mobility for simultaneous enhancement of conductivity and transparency

    SciTech Connect

    Nian, Qiong; Zhang, Martin Y.; Schwartz, Bradley D.; Cheng, Gary J.

    2014-05-19

    One of the most challenging issues in transparent conductive oxides (TCOs) is to improve their conductivity without compromising transparency. High conductivity in TCO films often comes from a high carrier concentration, which is detrimental to transparency due to free carrier absorption. Here we show that UV laser crystallization (UVLC) of aluminum-doped ZnO (AZO) films prepared by pulsed laser deposition on sapphire results in much higher Hall mobility, allowing relaxation of the constraints of the conductivity/transparency trade-off. X-ray diffraction patterns and morphological characterizations show grain growth and crystallinity enhancement during UVLC, resulting in less film internal imperfections. Optoelectronic measurements show that UVLC dramatically improves the electron mobility, while the carrier concentration decreases which in turn simultaneously increases conductivity and transparency. AZO films under optimized UVLC achieve the highest electron mobility of 79 cm{sup 2}/V s at a low carrier concentration of 7.9 × 10{sup +19} cm{sup −3}. This is realized by a laser crystallization induced decrease of both grain boundary density and electron trap density at grain boundaries. The infrared (IR) to mid-IR range transmittance spectrum shows UVLC significantly enhances the AZO film transparency without compromising conductivity.

  15. Diode-pumped continuous-wave and femtosecond Cr:LiCAF lasers with high average power in the near infrared, visible and near ultraviolet.

    PubMed

    Demirbas, Umit; Baali, Ilyes; Acar, Durmus Alp Emre; Leitenstorfer, Alfred

    2015-04-01

    We demonstrate continuous-wave (cw), cw frequency-doubled, cw mode-locked and Q-switched mode-locked operation of multimode diode-pumped Cr:LiCAF lasers with record average powers. Up to 2.54 W of cw output is obtained around 805 nm at an absorbed pump power of 5.5 W. Using intracavity frequency doubling with a BBO crystal, 0.9 W are generated around 402 nm, corresponding to an optical-to-optical conversion efficiency of 12%. With an intracavity birefringent tuning plate, the fundamental and frequency-doubled laser output is tuned continuously in a broad wavelength range from 745 nm to 885 nm and from 375 to 440 nm, respectively. A saturable Bragg reflector is used to initiate and sustain mode locking. In the cw mode-locked regime, the Cr:LiCAF laser produces 105-fs long pulses near 810 nm with an average power of 0.75 W. The repetition rate is 96.4 MHz, resulting in pulse energies of 7.7 nJ and peak powers of 65 kW. In Q-switched mode-locked operation, pulses with energies above 150 nJ are generated. PMID:25968727

  16. Photoresist composition for extreme ultraviolet lithography

    DOEpatents

    Felter, T. E.; Kubiak, G. D.

    1999-01-01

    A method of producing a patterned array of features, in particular, gate apertures, in the size range 0.4-0.05 .mu.m using projection lithography and extreme ultraviolet (EUV) radiation. A high energy laser beam is used to vaporize a target material in order to produce a plasma which in turn, produces extreme ultraviolet radiation of a characteristic wavelength of about 13 nm for lithographic applications. The radiation is transmitted by a series of reflective mirrors to a mask which bears the pattern to be printed. The demagnified focused mask pattern is, in turn, transmitted by means of appropriate optics and in a single exposure, to a substrate coated with photoresists designed to be transparent to EUV radiation and also satisfy conventional processing methods. A photoresist composition for extreme ultraviolet radiation of boron carbide polymers, hydrochlorocarbons and mixtures thereof.

  17. Ultraviolet laser desorption/ionization mass spectrometry of single-core and multi-core polyaromatic hydrocarbons under variable conditions of collisional cooling: insights into the generation of molecular ions, fragments and oligomers.

    PubMed

    Gámez, Francisco; Hortal, Ana R; Martínez-Haya, Bruno; Soltwisch, Jens; Dreisewerd, Klaus

    2014-11-01

    The ultraviolet laser desorption/ionization of polyaromatic hydrocarbons (PAHs) has been investigated under different background pressures of an inert gas (up to 1.2 mbar of N2) in the ion source of a hybrid, orthogonal-extracting time-of-flight mass spectrometer (oTOF-MS). The study includes an ensemble of six model PAHs with isolated single polyaromatic cores and four ones with multiple cross-linked aromatic and polyaromatic cores. In combination with a weak ion extraction field, the variation of the buffer gas pressure allowed to control the degree of collisional cooling of the desorbed PAHs and, thus, to modulate their decomposition into fragments. The dominant fragmentation channels observed are related to dehydrogenation of the PAHs, in most cases through the cleavage of even numbers of C-H bonds. Breakage of C-C bonds leading to the fragmentation of rings, side chains and core linkages is also observed, in particular, at low buffer gas pressures. The precise patterns of the combined fragmentation processes vary significantly between the PAHs. The highest abundances of molecular PAH ions and cleanest mass spectra were consistently obtained at the highest buffer gas pressure of 1.2 mbar. The effective quenching of the fragmentation pathways at this elevated pressure improves the sensitivity and data interpretation for analytical applications, although the fragmentation of side chains and of bonds between (poly)aromatic cores is not completely suppressed in all cases. Moreover, these results suggest that the detected fragments are generated through thermal equilibrium processes rather than as a result of rapid photolysis. This assumption is further corroborated by a laser desorption/ionization post-source decay analysis using an axial time-of-flight MS. In line with these findings, covalent oligomers of the PAHs, which are presumably formed by association of two or more dehydrogenated fragments, are detected with higher abundances at the lower buffer gas

  18. Ultraviolet photochemical reaction of [Fe(III)(C2O4)3]3− in aqueous solutions studied by femtosecond time-resolved X-ray absorption spectroscopy using an X-ray free electron laser

    PubMed Central

    Ogi, Y.; Obara, Y.; Katayama, T.; Suzuki, Y.-I.; Liu, S. Y.; Bartlett, N. C.-M.; Kurahashi, N.; Karashima, S.; Togashi, T.; Inubushi, Y.; Ogawa, K.; Owada, S.; Rubešová, M.; Yabashi, M.; Misawa, K.; Slavíček, P.; Suzuki, T.

    2015-01-01

    Time-resolved X-ray absorption spectroscopy was performed for aqueous ammonium iron(III) oxalate trihydrate solutions using an X-ray free electron laser and a synchronized ultraviolet laser. The spectral and time resolutions of the experiment were 1.3 eV and 200 fs, respectively. A femtosecond 268 nm pulse was employed to excite [Fe(III)(C2O4)3]3− in solution from the high-spin ground electronic state to ligand-to-metal charge transfer state(s), and the subsequent dynamics were studied by observing the time-evolution of the X-ray absorption spectrum near the Fe K-edge. Upon 268 nm photoexcitation, the Fe K-edge underwent a red-shift by more than 4 eV within 140 fs; however, the magnitude of the redshift subsequently diminished within 3 ps. The Fe K-edge of the photoproduct remained lower in energy than that of [Fe(III)(C2O4)3]3−. The observed red-shift of the Fe K-edge and the spectral feature of the product indicate that Fe(III) is upon excitation immediately photoreduced to Fe(II), followed by ligand dissociation from Fe(II). Based on a comparison of the X-ray absorption spectra with density functional theory calculations, we propose that the dissociation proceeds in two steps, forming first [(CO2•)Fe(II)(C2O4)2]3− and subsequently [Fe(II)(C2O4)2]2−. PMID:26798796

  19. Ultra-violet and resonant laser ablation coupled with microwave induced plasma atomic emission spectrometry and determination of tin in nickel based alloys by electrothermal atomizer atomic absorption and laser excited atomic fluorescence spectrometry

    NASA Astrophysics Data System (ADS)

    Yang, Xiaodong

    Chapter 1 reviews laser ablation in analytical atomic spectrometry. Laser ablation is categorized into two functions: one is used as a sample introduction method, the other function is used as a microprobe analysis method. Both fundamental and applicational aspects are reviewed with the citations of related papers. This chapter also serves as an introduction to the work which is described in chapter 2 and chapter 3 as laser ablation is a relatively new research area for the research group. In chapter 2, instrumentation for excimer (308nm) laser ablation of samples was coupled with a microwave induced plasma (MLP), and evaluated for its potential as an approach to solid sampling for atomic emission spectrometry. Operating parameters were optimized, and the effects of laser repetition rate and number of laser shots on the emission signal were investigated. The UV excimer laser removed more material than would be expected of an infrared laser of similar energy. The chromium detection limit in the solid steel sample was estimated to be about 500 mug/g. In chapter 3, a wavelength tunable optical parametric oscillator (OPO) laser was used to ablate a steel sample into the same apparatus described in chapter 2. The emission signal for the elements was selectively enhanced when the ablation wavelength was tuned to be in resonance with any atomic transition of that element. This was the first report of the observation of resonant ablation by use of optical detection, as prior reports of resonant ablation have used mass spectrometric detectors. Chapter 4 reviews the publications in laser excited atomic fluorescence spectrometry in recent eight years. The focus of the review is on recent development on new instruments and applications of this technique. Chapter 5 studies the determination of tin in nickel-based alloys with laser excited atomic fluorescence in a graphite furnace. Zeeman electrothermal atomizer atomic absorption spectrometry and inductively coupled plasma mass

  20. Atmospheric ultraviolet remote sensing

    NASA Astrophysics Data System (ADS)

    Huffman, Robert E.

    Techniques and applications of the ultraviolet wavelength region are examined. The topics addressed include: radiometry, sensors, space operations, the earth's atmosphere, solar photoabsorption, photon cross sections, airglow, aurora, scattering and fluorescence, atmospheric ultraviolet backgrounds, radiance and transmission codes, ozone and lower atmospheric composition, upper atmospheric composition and density, global auroral imaging, and ionospheric electron density.

  1. Communication: Rovibrationally selected study of the N{sub 2}{sup +}(X; v{sup +}= 1, N{sup +}= 0-8) + Ar charge transfer reaction using the vacuum ultraviolet laser pulsed field ionization-photoion method

    SciTech Connect

    Chang, Yih Chung; Xu Hong; Xu Yuntao; Lu Zhou; Ng, C. Y.; Chiu, Yu-Hui; Levandier, Dale J.

    2011-05-28

    By employing an electric field pulsing scheme for vacuum ultraviolet laser pulsed field ionization-photoion (PFI-PI) measurements, we have been able to prepare a rovibrationally selected PFI-PI beam of N{sub 2}{sup +}(v{sup +}= 1, N{sup +}) with not only high intensity and high quantum state purity, but also high kinetic energy resolution, allowing absolute total cross sections [{sigma}(v{sup +}= 1, N{sup +})] for the N{sub 2}{sup +}(X; v{sup +}= 1, N{sup +}) + Ar, N{sup +}= 0-8 charge transfer reaction to be measured at center-of-mass collision energies (E{sub cm}) down to thermal energies. The {sigma}(v{sup +}= 1, N{sup +}= 0-8) values determined at E{sub cm}= 0.04-10.00 eV are in good agreement with the theoretical predictions based on the Landau-Zener-Stueckelberg formulism. Taking into account the experimental uncertainties, the {sigma}(v{sup +}= 1, N{sup +}), N{sup +}= 0-8, measured at E{sub cm}= 1.56 eV are found to be independent of N{sup +}.

  2. Communication: rovibrationally selected study of the N2+(X; v+=1, N+= 0-8) + Ar charge transfer reaction using the vacuum ultraviolet laser pulsed field ionization-photoion method.

    PubMed

    Chang, Yih Chung; Xu, Hong; Xu, Yuntao; Lu, Zhou; Chiu, Yu-Hui; Levandier, Dale J; Ng, C Y

    2011-05-28

    By employing an electric field pulsing scheme for vacuum ultraviolet laser pulsed field ionization-photoion (PFI-PI) measurements, we have been able to prepare a rovibrationally selected PFI-PI beam of N(2)(+)(v(+) = 1, N(+)) with not only high intensity and high quantum state purity, but also high kinetic energy resolution, allowing absolute total cross sections [σ(v(+) = 1, N(+))] for the N(2)(+)(X; v(+) = 1, N(+)) + Ar, N(+) = 0-8 charge transfer reaction to be measured at center-of-mass collision energies (E(cm)) down to thermal energies. The σ(v(+) = 1, N(+) = 0-8) values determined at E(cm) = 0.04-10.00 eV are in good agreement with the theoretical predictions based on the Landau-Zener-Stückelberg formulism. Taking into account the experimental uncertainties, the σ(v(+) = 1, N(+)), N(+) = 0-8, measured at E(cm) = 1.56 eV are found to be independent of N(+). PMID:21639416

  3. Tracing direct and sequential two-photon double ionization of D{sub 2} in femtosecond extreme-ultraviolet laser pulses

    SciTech Connect

    Jiang, Y. H.; Kurka, M.; Kuehnel, K. U.; Ergler, Th.; Schroeter, C. D.; Moshammer, R.; Rudenko, A.; Foucar, L.; Plesiat, E.; Perez-Torres, J. F.; Martin, F.; Herrwerth, O.; Lezius, M.; Kling, M. F.; Titze, J.; Jahnke, T.; Doerner, R.; Sanz-Vicario, J. L.; Schoeffler, M.; Tilborg, J. van

    2010-02-15

    Two-photon double ionization (TPDI) of D{sub 2} is studied for 38-eV photons at the Free Electron Laser in Hamburg (FLASH). Based on model calculations, instantaneous and sequential absorption pathways are identified as separated peaks in the measured D{sup +}+D{sup +} fragment kinetic energy release (KER) spectra. The instantaneous process appears at high KER, corresponding to ionization at the molecule's equilibrium distance, in contrast to sequential ionization mainly leading to low-KER contributions. Measured fragment angular distributions are in good agreement with theory.

  4. Time-resolved spatial distribution of plasma in the ablation of a Ba₀.₆Sr₀.₄TiO₃ target by 25 ns KrF ultraviolet laser

    SciTech Connect

    Lagrange, J. F.; Wolfman, J.; Motret, O.; Hermann, J.

    2014-10-07

    We performed radially and longitudinally time-resolved plasma analysis during pulsed laser deposition of Ba₀.₆Sr₀.₄TiO₃ thin films. The plasma is shown to be optically thick and strongly non-uniform during the early expansion phase and the resonance line Ba II (455.4 nm) is strongly self-reversed during this time. Plasma temperature and electron density were obtained by comparing experimental emission spectra with the spectral radiance computed for a non-uniform plasma in local thermal equilibrium.

  5. Excimer Lasers In Medicine

    NASA Astrophysics Data System (ADS)

    Tittel, Frank K.; Saidi, Iyad S.; Pettit, George H.; Wisoff, P. J.; Sauerbrey, Roland A.

    1989-06-01

    Excimer lasers emit light energy, short optical pulses at ultraviolet wavelengths, that results in a unique laser tissue interaction. This has led to an increasing number of studies into medical applications of these lasers in fields such as ophthalmology, urology, cardiology and neurology.

  6. Effect of hydrogen bonding on far-ultraviolet water absorption and potential implications for 193-nm ArF excimer laser-tissue interaction

    NASA Astrophysics Data System (ADS)

    Walsh, Joseph T., Jr.; Staveteig, Paul T.

    1995-05-01

    The mechanisms causing transient 193-nm optical absorption of collagen during ablative-fluence ArF excimer pulses are poorly understood. The preponderance of hypotheses proposed to explain this phenomenon, such as ultrafast secondary-structure denaturation of proteins and transient free radical formation, focus on the protein matrix and ignore potential contributions from other tissue components such as water. A substantial body of spectroscopic literature places 193 nm adjacent to a steep absorption edge of water that rises to 60,000 cm-1 at 163 nm; other evidence shows that this absorption edge shifts toward 193 nm upon hydrogen-bond breakage. In this paper we show that heating of water from 20-100°C increases the liquid's absorption coefficient. Further investigations using an infrared pump laser show a significant increase in absorption by water of a 193-nm probe beam. Based on this evidence, we speculate that 193-nm laser ablation of tissue may contain a photothermal component related to dynamic absorption of incident radiation by water.

  7. Strain dependence on polarization properties of AlGaN and AlGaN-based ultraviolet lasers grown on AlN substrates

    SciTech Connect

    Bryan, Zachary Bryan, Isaac; Sitar, Zlatko; Collazo, Ramón; Mita, Seiji; Tweedie, James

    2015-06-08

    Since the band ordering in AlGaN has a profound effect on the performance of UVC light emitting diodes (LEDs) and even determines the feasibility of surface emitting lasers, the polarization properties of emitted light from c-oriented AlGaN and AlGaN-based laser structures were studied over the whole composition range, as well as various strain states, quantum confinements, and carrier densities. A quantitative relationship between the theoretical valence band separation, determined using k•p theory, and the experimentally measured degree of polarization is presented. Next to composition, strain was found to have the largest influence on the degree of polarization while all other factors were practically insignificant. The lowest crossover point from the transverse electric to transverse magnetic polarized emission of 245 nm was found for structures pseudomorphically grown on AlN substrates. This finding has significant implications toward the efficiency and feasibility of surface emitting devices below this wavelength.

  8. Pyroelectric field assisted ion migration induced by ultraviolet laser irradiation and its impact on ferroelectric domain inversion in lithium niobate crystals

    SciTech Connect

    Ying, C. Y. J.; Mailis, S.; Daniell, G. J.; Steigerwald, H.; Soergel, E.

    2013-08-28

    The impact of UV laser irradiation on the distribution of lithium ions in ferroelectric lithium niobate single crystals has been numerically modelled. Strongly absorbed UV radiation at wavelengths of 244–305 nm produces steep temperature gradients which cause lithium ions to migrate and result in a local variation of the lithium concentration. In addition to the diffusion, here the pyroelectric effect is also taken into account which predicts a complex distribution of lithium concentration along the c-axis of the crystal: two separated lithium deficient regions on the surface and in depth. The modelling on the local lithium concentration and the subsequent variation of the coercive field are used to explain experimental results on the domain inversion of such UV treated lithium niobate crystals.

  9. Low-threshold ultraviolet solid-state laser based on a Ce3+:LiCaAlF6 crystal resonator.

    PubMed

    Le, Thanh; Schowalter, Steven J; Rellergert, Wade; Jeet, Justin; Lin, Guoping; Yu, Nan; Hudson, Eric R

    2012-12-01

    A low-threshold solid-state UV laser using a whispering gallery mode (WGM) resonator constructed from UV transparent crystalline material is demonstrated. Using a Ce3+:LiCaAlF6 resonator, we observe broad bandwidth lasing (280-330 nm) with a low threshold intensity of 7.5×10(9) W/m(2) and an effective slope efficiency of ~25%. The lasing time delay dynamics in the pulsed operation mode are also observed and analyzed. Additionally, a LiCaAlF(6) WGM resonator with Q=2×10(7) at 370 nm is realized. The combination of this high Q and the small WGM mode volume significantly lowers the pump power threshold compared to traditional cavity designs, opening the door for both tunable continuous-wave and mode-locked operation. PMID:23202104

  10. Ultraviolet photochemistry of buta-1,3- and buta-1,2-dienes: Laser spectroscopic absolute hydrogen atom quantum yield and translational energy distribution measurements

    SciTech Connect

    Hanf, A.; Volpp, H.-R.; Sharma, P.; Mittal, J. P.; Vatsa, R. K.

    2010-07-14

    Using pulsed H-atom Lyman-{alpha} laser-induced fluorescence spectroscopy along with a photolytic calibration approach, absolute H-atom product quantum yields of {phi}{sub H-b13d}=(0.32{+-}0.04) and {phi}{sub H-b12d}=(0.36{+-}0.04) were measured under collision-free conditions for the 193 nm gas-phase laser flash photolysis of buta-1,3- and buta-1,2-diene at room temperature, which demonstrate that nascent H-atom formation is of comparable importance for both parent molecules. Comparison of the available energy fraction, f{sub T-b13d}=(0.22{+-}0.03) and f{sub T-b12d}=(0.13{+-}0.01), released as H+C{sub 4}H{sub 5} product translational energy with results of impulsive and statistical energy partitioning modeling calculations indicates that for both, buta-1,3- and buta-1,2-diene, H-atom formation is preceded by internal conversion to the respective electronic ground state (S{sub 0}) potential energy surfaces. In addition, values of {sigma}{sub b-1,3-d-L{alpha}=}(3.5{+-}0.2)x10{sup -17} cm{sup 2} and {sigma}{sub b-1,2-d-L{alpha}=}(4.4{+-}0.2)x10{sup -17} cm{sup 2} for the previously unknown Lyman-{alpha} (121.6 nm) radiation photoabsorption cross sections of buta-1,3- and buta-1,2-diene in the gas-phase were determined.

  11. The formation of an intense filament controlled by interference of ultraviolet femtosecond pulses

    SciTech Connect

    Wang Yongdong; Zhang Yisan; Chen Peng; Shi Liping; Lu Xin; Wu Jian; Ding Liang'en; Zeng Heping

    2011-03-14

    We experimentally investigated the formation of a wavelength-scale photonic plasma grating induced by interference-assisted coalescence of two noncollinear ultraviolet femtosecond laser pulses. The period of the created plasma grating decreased with the crossing angle of the interacting laser pulses. For a proper small crossing angle, the noncollinear ultraviolet filaments were coalesced and an intense single ultraviolet filament was formed with a diameter of 5 {mu}m which was below the focused limitation. This may provide a way to control ultraviolet femtosecond filamentation.

  12. Ultraviolet absorption hygrometer

    DOEpatents

    Gersh, M.E.; Bien, F.; Bernstein, L.S.

    1986-12-09

    An ultraviolet absorption hygrometer is provided including a source of pulsed ultraviolet radiation for providing radiation in a first wavelength region where water absorbs significantly and in a second proximate wavelength region where water absorbs weakly. Ultraviolet radiation in the first and second regions which has been transmitted through a sample path of atmosphere is detected. The intensity of the radiation transmitted in each of the first and second regions is compared and from this comparison the amount of water in the sample path is determined. 5 figs.

  13. Ultraviolet absorption hygrometer

    DOEpatents

    Gersh, Michael E.; Bien, Fritz; Bernstein, Lawrence S.

    1986-01-01

    An ultraviolet absorption hygrometer is provided including a source of pulsed ultraviolet radiation for providing radiation in a first wavelength region where water absorbs significantly and in a second proximate wavelength region where water absorbs weakly. Ultraviolet radiation in the first and second regions which has been transmitted through a sample path of atmosphere is detected. The intensity of the radiation transmitted in each of the first and second regions is compared and from this comparison the amount of water in the sample path is determined.

  14. Revelation of the Technological Versatility of the Eu(TTA)3Phen Complex by Demonstrating Energy Harvesting, Ultraviolet Light Detection, Temperature Sensing, and Laser Applications.

    PubMed

    Shahi, Praveen Kumar; Singh, Akhilesh Kumar; Singh, Sunil Kumar; Rai, Shyam Bahadur; Ullrich, Bruno

    2015-08-26

    We synthesized the Eu(TTA)3Phen complex and present herein a detailed study of its photophysics. The investigations encompass samples dispersed in poly(vinyl alcohol) and in ethanol in order to explore the versatile applicability of these lanthanide-based materials. Details upon the interaction between Eu, TTA, and the Phen ligands are revealed by Fourier transform infrared and UV-visible absorption, complemented by steady state and temporally resolved emission studies, which provide evidence of an efficient energy transfer from the organic ligands to the central Eu(3+) ion. The material produces efficient emission even under sunlight exposure, a feature pointing toward suitability for luminescent solar concentrators and UV light sensing, which is demonstrated for intensities as low as 200 nW/cm(2). The paper further promotes the complex's capability to be used as luminescence-based temperature sensor demonstrated by the considerable emission intensity changes of ∼4.0% per K in the temperature range of 50-305 K and ∼7% per K in the temeperature range 305-340 K. Finally, increasing the optical excitation causes both spontaneous emission amplification and emission peak narrowing in the Eu(TTA)3Phen complex dispersed in poly(vinyl alcohol) - features indicative of stimulated emission. These findings in conjunction with the fairly large stimulated emission cross-section of 4.29 × 10(-20) cm(2) demonstrate that the Eu(TTA)3Phen complex dispersed in poly(vinyl alcohol) could be a very promising material choice for lanthanide-polymer based laser architectures. PMID:26238311

  15. Proposal for Testing and Validation of Vacuum Ultra-Violet Atomic Laser-Induced Fluorescence as a Method to Analyze Carbon Grid Erosion in Ion Thrusters

    NASA Technical Reports Server (NTRS)

    Stevens, Richard

    2003-01-01

    Previous investigation under award NAG3-25 10 sought to determine the best method of LIF to determine the carbon density in a thruster plume. Initial reports from other groups were ambiguous as to the number of carbon clusters that might be present in the plume of a thruster. Carbon clusters would certainly affect the ability to LIF; if they were the dominant species, then perhaps the LIF method should target clusters. The results of quadrupole mass spectroscopy on sputtered carbon determined that minimal numbers of clusters were sputtered from graphite under impact from keV Krypton. There were some investigations in the keV range by other groups that hinted at clusters, but at the time the proposal was presented to NASA, there was no data from low-energy sputtering available. Thus, the proposal sought to develop a method to characterize the population only of atoms sputtered from a graphite target in a test cell. Most of the ground work had been established by the previous two years of investigation. The proposal covering 2003 sought to develop an anti-Stokes Raman shifting cell to generate VUW light and test this cell on two different laser systems, ArF and YAG- pumped dye. The second goal was to measure the lowest detectable amounts of carbon atoms by 156.1 nm and 165.7 nm LIF. If equipment was functioning properly, it was expected that these goals would be met easily during the timeframe of the proposal, and that is the reason only modest funding was requested. The PI was only funded at half- time by Glenn during the summer months. All other work time was paid for by Whitworth College. The college also funded a student, Charles Shawley, who worked on the project during the spring.

  16. DIRECT DETECTION OF COMPLEX ORGANIC PRODUCTS IN ULTRAVIOLET (Lyα) AND ELECTRON-IRRADIATED ASTROPHYSICAL AND COMETARY ICE ANALOGS USING TWO-STEP LASER ABLATION AND IONIZATION MASS SPECTROMETRY

    SciTech Connect

    Henderson, Bryana L.; Gudipati, Murthy S.

    2015-02-10

    As discovery of complex molecules and ions in our solar system and the interstellar medium has proliferated, several groups have turned to laboratory experiments in an effort to simulate and understand these chemical processes. So far only infrared (IR) and ultraviolet (UV) spectroscopy has been able to directly probe these reactions in ices in their native, low-temperature states. Here we report for the first time results using a complementary technique that harnesses two-step two-color laser ablation and ionization to measure mass spectra of energetically processed astrophysical and cometary ice analogs directly without warming the ices—a method for hands-off in situ ice analysis. Electron bombardment and UV irradiation of H{sub 2}O, CH{sub 3}OH, and NH{sub 3} ices at 5 K and 70 K led to complex irradiation products, including HCO, CH{sub 3}CO, formamide, acetamide, methyl formate, and HCN. Many of these species, whose assignment was also strengthened by isotope labeling studies and correlate with IR-based spectroscopic studies of similar irradiated ices, are important ingredients for the building blocks of life. Some of them have been detected previously via astronomical observations in the interstellar medium and in cometary comae. Other species such as CH{sub 3}CO (acetyl) are yet to be detected in astrophysical ices or interstellar medium. Our studies suggest that electron and UV photon processing of astrophysical ice analogs leads to extensive chemistry even in the coldest reaches of space, and lend support to the theory of comet-impact-induced delivery of complex organics to the inner solar system.

  17. Direct Detection of Complex Organic Products in Ultraviolet (Lyα) and Electron-irradiated Astrophysical and Cometary Ice Analogs Using Two-step Laser Ablation and Ionization Mass Spectrometry

    NASA Astrophysics Data System (ADS)

    Henderson, Bryana L.; Gudipati, Murthy S.

    2015-02-01

    As discovery of complex molecules and ions in our solar system and the interstellar medium has proliferated, several groups have turned to laboratory experiments in an effort to simulate and understand these chemical processes. So far only infrared (IR) and ultraviolet (UV) spectroscopy has been able to directly probe these reactions in ices in their native, low-temperature states. Here we report for the first time results using a complementary technique that harnesses two-step two-color laser ablation and ionization to measure mass spectra of energetically processed astrophysical and cometary ice analogs directly without warming the ices—a method for hands-off in situ ice analysis. Electron bombardment and UV irradiation of H2O, CH3OH, and NH3 ices at 5 K and 70 K led to complex irradiation products, including HCO, CH3CO, formamide, acetamide, methyl formate, and HCN. Many of these species, whose assignment was also strengthened by isotope labeling studies and correlate with IR-based spectroscopic studies of similar irradiated ices, are important ingredients for the building blocks of life. Some of them have been detected previously via astronomical observations in the interstellar medium and in cometary comae. Other species such as CH3CO (acetyl) are yet to be detected in astrophysical ices or interstellar medium. Our studies suggest that electron and UV photon processing of astrophysical ice analogs leads to extensive chemistry even in the coldest reaches of space, and lend support to the theory of comet-impact-induced delivery of complex organics to the inner solar system.

  18. Ultraviolet and infrared laser-induced fragmentation of free (CF{sub 3}I){sub n} clusters in a molecular beam and (CF{sub 3}I){sub n} clusters inside or on the surface of large (Xe){sub m} clusters

    SciTech Connect

    Apatin, V. M.; Lokhman, V. N.; Makarov, G. N. Ogurok, N.-D. D.; Petin, A. N.; Ryabov, E. A.

    2015-02-15

    The fragmentation of free homogeneous (CF{sub 3}I){sub n} clusters in a molecular beam (n ≤ 45 is the average number of molecules in the cluster) and (CF{sub 3}I){sub n} clusters inside or on the surface of large (Xe){sub m} clusters (m ≥ 100 is the average number of atoms in the cluster) by ultraviolet and infrared laser radiations has been studied. These three types of (CF{sub 3}I){sub n} clusters are shown to have different stabilities with respect to fragmentation by both ultraviolet and infrared radiations and completely different dependences of the fragmentation probability on the energy of ultraviolet and infrared radiations. When exposed to ultraviolet radiation, the free (CF{sub 3}I){sub n} clusters fragment at comparatively low fluences (Φ{sub UV} ≤ 0.15 J cm{sup −2}) and the weakest energy dependence of the fragmentation probability is observed for them. A stronger energy dependence of the fragmentation probability is observed for the (CF{sub 3}I){sub n} clusters localized inside (Xe){sub m} clusters, and the strongest dependence is observed for the (CF{sub 3}I){sub n} clusters located on the surface of (Xe){sub m} clusters. When the clusters are exposed to infrared radiation, the homogeneous (CF{sub 3}I){sub n} clusters efficiently fragment at low fluences (Φ{sub IR} ≤ 25 mJ cm{sup −2}), higher fluences (Φ{sub IR} ≈ 75 mJ cm{sup −2}) are needed for the fragmentation of the (CF{sub 3}I){sub n} localized inside (Xe){sub m} clusters, and even higher fluences (Φ{sub IR} ≈ 150 mJ cm{sup −2}) are needed for the fragmentation of the (CF{sub 3}I){sub n} clusters located on the surface of (Xe){sub m} clusters. It has been established that small (CF{sub 3}I){sub n} clusters located on the surface of (Xe){sub m} clusters do not fragment up to fluences Φ{sub IR} ≈ 250 mJ cm{sup −2}. The fragmentation efficiency of (CF{sub 3}I){sub n} clusters is shown to be the same (at the same fluence) when they are excited by both pulsed (τ{sub p}

  19. International Ultraviolet Explorer (IUE)

    NASA Technical Reports Server (NTRS)

    Boehm, Karl-Heinz

    1992-01-01

    The observation, data reduction, and interpretation of ultraviolet spectra (obtained with the International Ultraviolet Explorer) of Herbig-Haro objects, stellar jets, and (in a few cases) reflection nebulae in star-forming regions is discussed. Intermediate results have been reported in the required semi-annual reports. The observations for this research were obtained in 23 (US1) IUE shifts. The spectra were taken in the low resolution mode with the large aperture. The following topics were investigated: (1) detection of UV spectra of high excitation Herbig-Haro (HH) objects, identification of emission lines, and a preliminary study of the energy distribution of the ultraviolet continuum; (2) details of the continuum energy distribution of these spectra and their possible interpretation; (3) the properties of the reddening (extinction) of HH objects; (4) the possible time variation of strong emission lines in high excitation HH objects; (5) the ultraviolet emission of low excitation HH objects, especially in the fluorescent lines of the H2 molecule; (6) the ultraviolet emission in the peculiar object HH24; (7) the spatial emission distribution of different lines and different parts of the continuum in different HH objects; and (8) some properties of reflection nebula, in the environment of Herbig-Haro objects. Each topic is discussed.

  20. New Standards for Ultraviolet Radiation

    NASA Technical Reports Server (NTRS)

    Sliney, D. H.

    1971-01-01

    Guidelines covering safe levels for exposure to ultraviolet radiation in an occupational environment are reported. The guidelines clarify the spectral radiant exposure doses and relative spectral effectiveness of ultraviolet radiation required to elicit adverse biologic effects.

  1. Laser Safety Device

    NASA Technical Reports Server (NTRS)

    1992-01-01

    A major focus of work done at Air Products and Chemicals' Laser Application Laboratory is on use of ultraviolet radiation using high energy excimer lasers. Because light within the wavelength of excimer lasers is invisible, it can cause serious damage to eyes and tissue. To contain the laser beam, Air Products Incorporated a Jet Propulsion Laboratory invention described in a technical support package into its beam stops. The technology interrupts the laser pathway and allows workers to remain in the target area without shutting off the laser.

  2. Green pumped Alexandrite lasers

    NASA Astrophysics Data System (ADS)

    Kuper, Jerry W.; Brown, David C.

    2005-04-01

    Initial experiments with pulsed and CW pumping an alexandrite laser rod at 532 nm are presented. This pumping architecture holds promise for the production of scalable diode-pumped, tunable alexandrite laser systems operating in the near infrared (750 nm), and the ultraviolet (375 and 250 nm) spectral regions.

  3. Free-Electron Lasers.

    ERIC Educational Resources Information Center

    Brau, Charles A.

    1988-01-01

    Describes the use of free-electron lasers as a source of coherent radiation over a broad range of wavelengths from the far-infrared to the far-ultraviolet regions of the spectrum. Discusses some applications of these lasers, including medicine and strategic defense. (TW)

  4. Laser nitriding and laser carburizing of surfaces

    NASA Astrophysics Data System (ADS)

    Schaaf, Peter

    2003-11-01

    Laser irradiation of surfaces with short pulses in reactive atmospheres (nitrogen, methane) can lead to very effective nitrification and carburization via complicated laser-surface-gas-plasma-interactions. This laser nitriding and laser carburizing and their basic underlying phenomena will be presented and partly explained by results of example materials (iron, titanium, aluminum, silicon) where nitride and carbide coatings can be formed by fast and easily by Excimer Laser, Nd:YAG laser, Free Electron Laser and also by femtosecond Ti:sapphire laser. This implies laser pulse durations from the nanosecond to the femtosecond regime and wavelengths from ultra-violet to infrared. The resulting surfaces, thin films, coatings and their properties are investigated by combining Mossbauer Spectroscopy, x-ray diffraction, x-ray absorption spectroscopy, Nanoindentation, Resonant Nuclear Reaction Analysis, and Rutherford Backscattering Spectroscopy.

  5. Vacuum ultraviolet holography

    NASA Technical Reports Server (NTRS)

    Bjorklund, G. C.; Harris, S. E.; Young, J. F.

    1974-01-01

    We report the first demonstration of holographic techniques in the vacuum ultraviolet spectral region. Holograms were produced with coherent 1182-A radiation. The holograms were recorded in polymethyl methacrylate and examined with an electron microscope. A holographic grating with a fringe spacing of 386 A was produced and far-field Fraunhofer holograms of submicron particles were recorded.

  6. International Ultraviolet Explorer

    NASA Technical Reports Server (NTRS)

    1997-01-01

    This report is the November 6, 1996 - October 9, 1997, IUE Final Report for the International Ultraviolet Explorer Final Archive contract. The ultimate objective of this contract is the completion of the archival reprocessing of all IUE data obtained at GSFC between 1978 and 1995.

  7. Vacuum ultraviolet holography

    NASA Technical Reports Server (NTRS)

    Bjorklund, G. C.; Harris, S. E.; Young, J. F.

    1974-01-01

    The authors report the first demonstration of holographic techniques in the vacuum ultraviolet spectral region. Holograms were produced with coherent 1182 A radiation. The holograms were recorded in polymethyl methacrylate and read out with an electron microscope. A holographic grating with a fringe spacing of 836 A was produced and far-field Fraunhofer holograms of sub-micron particles were recorded.

  8. Ultraviolet radiation changes

    NASA Technical Reports Server (NTRS)

    Mckenzie, Richard L.; Frederick, John E.; Ilyas, Mohammad; Filyushkin, V.; Wahner, Andreas; Stamnes, K.; Muthusubramanian, P.; Blumthaler, M.; Roy, Colin E.; Madronich, Sasha

    1991-01-01

    A major consequence of ozone depletion is an increase in solar ultraviolet (UV) radiation received at the Earth's surface. This chapter discusses advances that were made since the previous assessment (World Meteorological Organization (WMO)) to our understanding of UV radiation. The impacts of these changes in UV on the biosphere are not included, because they are discussed in the effects assessment.

  9. Psoriasis and ultraviolet radiation

    SciTech Connect

    Farber, E.M.; Nall, L. )

    1993-09-01

    Prevention and detection screening programs as a public health service in curtailing the ever-increasing incidence of all forms of skin cancer are reviewed. The effect of solar and artificial ultraviolet radiation on the general population and persons with psoriasis is examined. 54 refs.

  10. Rovibrationally selected ion-molecule collision study using the molecular beam vacuum ultraviolet laser pulsed field ionization-photoion method: charge transfer reaction of N2(+)(X 2Σg+; v+ = 0-2; N+ = 0-9) + Ar.

    PubMed

    Chang, Yih Chung; Xu, Yuntao; Lu, Zhou; Xu, Hong; Ng, C Y

    2012-09-14

    We have developed an ion-molecule reaction apparatus for state-selected absolute total cross section measurements by implementing a high-resolution molecular beam vacuum ultraviolet (VUV) laser pulsed field ionization-photoion (PFI-PI) ion source to a double-quadrupole double-octopole ion-guide mass spectrometer. Using the total cross section measurement of the state-selected N(2)(+)(v(+), N(+)) + Ar charge transfer (CT) reaction as an example, we describe in detail the design of the VUV laser PFI-PI ion source used, which has made possible the preparation of reactant N(2)(+)(X (2)Σ(g)(+), v(+) = 0-2, N(+) = 0-9) PFI-PIs with high quantum state purity, high intensity, and high kinetic energy resolution. The PFI-PIs and prompt ions produced in the ion source are shown to have different kinetic energies, allowing the clean rejection of prompt ions from the PFI-PI beam by applying a retarding potential barrier upstream of the PFI-PI source. By optimizing the width and amplitude of the pulsed electric fields employed to the VUV-PFI-PI source, we show that the reactant N(2)(+) PFI-PI beam can be formed with a laboratory kinetic energy resolution of ΔE(lab) = ± 50 meV. As a result, the total cross section measurement can be conducted at center-of-mass kinetic energies (E(cm)'s) down to thermal energies. Absolute total rovibrationally selected cross sections σ(v(+) = 0-2, N(+) = 0-9) for the N(2)(+)(X (2)Σ(g)(+); v(+) = 0-2, N(+) = 0-9) + Ar CT reaction have been measured in the E(cm) range of 0.04-10.0 eV, revealing strong vibrational enhancements and E(cm)-dependencies of σ(v(+) = 0-2, N(+) = 0-9). The thermochemical threshold at E(cm) = 0.179 eV for the formation of Ar(+) from N(2)(+)(X; v(+) = 0, N(+)) + Ar was observed by the measured σ(v(+) = 0), confirming the narrow ΔE(cm) spread achieved in the present study. The σ(v(+) = 0-2; N(+)) values obtained here are compared with previous experimental and theoretical results. The theoretical predictions

  11. Programmable femtosecond laser pulses in the ultraviolet

    SciTech Connect

    Hacker, M.; Feurer, T.; Sauerbrey, R.; Lucza, T.; Szabo, G.

    2001-06-01

    Using a combination of a zero-dispersion compressor and spectrally compensated sum-frequency generation, we have produced amplitude-modulated femtosecond pulses in the UV at 200 nm. {copyright} 2001 Optical Society of America

  12. Tunable lasers- an overview

    SciTech Connect

    Guenther, B.D.; Buser, R.G.

    1982-08-01

    This overview of tunable lasers describes their applicability to spectroscopy in the ultraviolet and middle infrared ranges; to rapid on-line diagnostics by ultrashort cavity lasers; to exploration, by the free electron laser, for its wide tuning in the far infrared to submillimeter region; to remote detection, in areas such as portable pollution monitors, on-line chemical analyzers, auto exhaust analyzers, and production line controls; to photochemistry; and to other potential areas in diagnostics, communications, and medical and biological sciences. The following lasers are characterized by their tunability: solid state lasers, primarily alexandrite, with a tuning range of ca 1000 Angstroms; color center lasers; semiconductor lasers; dye lasers; gas lasers, where high-pressure CO/sub 2/ discharges are the best known example for a wide tunability range, and research is continuing in systems such as the alkali dimers; and, at wavelengths beyond 10 micrometers, the possibilities beyond Cerenkov and free electron lasers.

  13. Coherent sub-aperture ultraviolet imagery

    NASA Astrophysics Data System (ADS)

    Morton, R. G.; Connally, W. J.; Avicola, K.; Monjo, D.; Olson, T.

    1989-09-01

    Laboratory targets have been imaged by a multi-sub-aperture, coherent receiver technique in which a common local oscillator illuminates the sub-aperture array to preserve both phase and intensity information. The target, receiver and range dimensions were chosen such that each sub-aperture was smaller than the speckle size. Various targets were illuminated by microsecond pulses from an e-beam pumped XeF power amplifier, which was seeded by a coherent ultraviolet beam generated with a frequency doubled visible dye laser. Data is presented showing comparisons between the coherent multi-sub-aperture approach and conventional, full aperture photography of the same traget(s).

  14. Extreme ultraviolet photoionization of aldoses and ketoses

    NASA Astrophysics Data System (ADS)

    Shin, Joong-Won; Dong, Feng; Grisham, Michael E.; Rocca, Jorge J.; Bernstein, Elliot R.

    2011-04-01

    Gas phase monosaccharides (2-deoxyribose, ribose, arabinose, xylose, lyxose, glucose galactose, fructose, and tagatose), generated by laser desorption of solid sample pellets, are ionized with extreme ultraviolet photons (EUV, 46.9 nm, 26.44 eV). The resulting fragment ions are analyzed using a time of flight mass spectrometer. All aldoses yield identical fragment ions regardless of size, and ketoses, while also generating same ions as aldoses, yields additional features. Extensive fragmentation of the monosaccharides is the result the EUV photons ionizing various inner valence orbitals. The observed fragmentation patterns are not dependent upon hydrogen bonding structure or OH group orientation.

  15. Ultraviolet phototherapy for pruritus.

    PubMed

    Rivard, Jennifer; Lim, Henry W

    2005-01-01

    Ultraviolet-based therapy has been used to treat various pruritic conditions including pruritus in chronic renal failure, atopic dermatitis, HIV, aquagenic pruritus and urticaria, solar, chronic, and idiopathic urticaria, urticaria pigmentosa, polycythemia vera, pruritic folliculitis of pregnancy, breast carcinoma skin infiltration, Hodgkin's lymphoma, chronic liver disease, and acquired perforating dermatosis, among others. Various mechanisms of action for phototherapy have been posited. Treatment limitations, side effects, and common dosing protocols are reviewed. PMID:16297008

  16. Ultraviolet Raman scattering from persistent chemical warfare agents

    NASA Astrophysics Data System (ADS)

    Kullander, Fredrik; Wästerby, Pär.; Landström, Lars

    2016-05-01

    Laser induced Raman scattering at excitation wavelengths in the middle ultraviolet was examined using a pulsed tunable laser based spectrometer system. Droplets of chemical warfare agents, with a volume of 2 μl, were placed on a silicon surface and irradiated with sequences of laser pulses. The Raman scattering from V-series nerve agents, Tabun (GA) and Mustard gas (HD) was studied with the aim of finding the optimum parameters and the requirements for a detection system. A particular emphasis was put on V-agents that have been previously shown to yield relatively weak Raman scattering in this excitation band.

  17. Research in extreme ultraviolet and far ultraviolet astronomy

    NASA Technical Reports Server (NTRS)

    Labov, S. E.

    1985-01-01

    Instruments designed to explore different aspects of far and extreme ultraviolet cosmic radiation were studied. The far ultraviolet imager (FUVI) was flown on the Aries sounding rocket. Its unique large format 75mm detector mapped out the far ultraviolet background radiation with a resolution of only a few arc minutes. Analysis of this data indicates to what extent the FUVI background is extra galactic in origin. A power spectrum of the spatial fluctuations will have direct consequences for galactic evolution.

  18. Femtosecond transparency in the extreme ultraviolet

    NASA Astrophysics Data System (ADS)

    Tarana, Michal; Greene, Chris H.

    2012-06-01

    Electromagnetically induced transparency-like behavior in the extreme ultraviolet (XUV) is studied theoretically, including the effect of intense 800nm laser dressing of He 2s2p(^1P^o) and 2p^2(^2S^e) autoionizing states. We present an ab initio solution of the time-dependent Schr"odinger equation in an LS-coupling configuration interaction basis set. The method enables a rigorous treatment of optical field ionization of these coupled autoionizing states into the N = 2 continuum in addition to N = 1. Our calculated transient absorption spectra show the formation of the Autler-Townes doublet in the presence of the dressing laser field. The presented results are in encouraging agreement with experiment [1]. [4pt] [1] Z.H. Loh, C.H. Greene, and S. R. Leone, Chem. Phys. 350, 7 (2008)

  19. Mars ultraviolet reflectance compared with imaging, topography and geology

    NASA Astrophysics Data System (ADS)

    Simmons, K. E.; Mankoff, K. D.; Hendrix, A. R.; Barth, C. A.

    2003-04-01

    We compare ultraviolet reflectance spectra from the Mariner Mars 1971 (MM71) Ultraviolet Spectrometer (UVS) with imaging data from the Viking Mars Digital Image Model (MDIM), with surface topography from the Mars Global Surveyor (MGS) Mars Orbiter Laser Altimeter (MOLA), and with geology from the USGS Survey Atlas of Mars digital maps. We use a new web-accessible database of MM71 UVS Reflectances and two software tools: 1) a surface and atmosphere database visualization tool called Albatross and 2) a web-based Mars data comparison tool called MDC. See http://lasp.colorado.edu/software_tools/. We present several examples, including the northern polar region and Lyot Crater.

  20. Detecting contaminants by ultraviolet photography

    NASA Technical Reports Server (NTRS)

    Neiswander, D. W.

    1980-01-01

    Relatively high ultraviolet absorptivity of most organics as compared to metal is suggested as basis for detecting traces of contamination. By photographing metal surface in ultraviolet light, contaminants that might otherwise interfere with adhesion of surface coatings, or with welding or brazing, could be detected and removed. Real time monitoring of cleaning process is also possible if ultraviolet sensitive television camera is used instead of photographic film.

  1. Ultraviolet-renormalon calculus

    SciTech Connect

    Vainshtein, A.I. Budker Institute of Nuclear Physics, 630090 Novosibirsk ); Zakharov, V.I. )

    1994-08-29

    We consider the status of the so-called ultraviolet (UV) renormalon which contributes to large order divergences of perturbative expansions in quantum chromodynamics. We argue that although the renormalon is associated with short distance dynamics, the class of renormalon graphs is not well defined and its overall weight is not controlled by theory. From this point of view there is not much difference from the case of Borel nonsummable singularities. Phenomenologically the UV renormalon is related to an effective four-fermion interaction originating within fundamental QCD.

  2. Ultraviolet atomic emission detector

    NASA Technical Reports Server (NTRS)

    Braun, W.; Peterson, N. C.; Bass, A. M.; Kurylo, M. J., III (Inventor)

    1972-01-01

    A device and method are provided for performing qualitative and quantitative elemental analysis through the utilization of a vacuum UV chromatographic detector. The method involves the use of a carrier gas at low pressure. The gas carries a sample to a gas chromatograph column; the column output is directed to a microwave cavity. In this cavity, a low pressure microwave discharge produces fragmentation of the compounds present and generates intense atomic emissions in the vacuum ultraviolet. These emissions are isolated by a monochromator and measured by photometer to establish absolute concentration for the elements.

  3. Transparent ultraviolet photovoltaic cells.

    PubMed

    Yang, Xun; Shan, Chong-Xin; Lu, Ying-Jie; Xie, Xiu-Hua; Li, Bing-Hui; Wang, Shuang-Peng; Jiang, Ming-Ming; Shen, De-Zhen

    2016-02-15

    Photovoltaic cells have been fabricated from p-GaN/MgO/n-ZnO structures. The photovoltaic cells are transparent to visible light and can transform ultraviolet irradiation into electrical signals. The efficiency of the photovoltaic cells is 0.025% under simulated AM 1.5 illumination conditions, while it can reach 0.46% under UV illumination. By connecting several such photovoltaic cells in a series, light-emitting devices can be lighting. The photovoltaic cells reported in this Letter may promise the applications in glass of buildings to prevent UV irradiation and produce power for household appliances in the future. PMID:26872163

  4. Circuit mapping by ultraviolet uncaging of glutamate.

    PubMed

    Shepherd, Gordon M G

    2012-09-01

    In laser photostimulation, small clusters of neurons in brain slices are induced to fire action potentials by focal glutamate uncaging, and synaptic connectivity between photoexcited presynaptic neurons and individual postsynaptic neurons is assessed by intracellular recording of synaptic events. With a scanner, this process can be repeated sequentially across a patterned array of stimulus locations, generating maps of neurons' local sources of synaptic inputs. Laser scanning photostimulation (LSPS) based on patterned glutamate uncaging offers an efficient, quantitative, optical-electrophysiological way to map synaptic circuits in brain slices. The efficacy of glutamate-based photostimulation for circuit mapping (in contrast to electrical stimulation) derives from the ability to stimulate neurons with high precision and speed, and without stimulating axons of passage. This protocol describes the components, assembly, and operation of a laser scanning microscope for ultraviolet (UV) uncaging, along with experimental methods for circuit mapping in brain slices. It presents a general approach and a set of guidelines for quantitative circuit mapping using "standard" LSPS methods based on single-photon glutamate uncaging using a UV laser, a pair of scanning mirror galvanometers, a patch-clamp setup, and open-source data acquisition software. PMID:22949715

  5. Investigation of ultraviolet interstellar extinction

    NASA Technical Reports Server (NTRS)

    Payne, C.; Haramundanis, K. L.

    1973-01-01

    Results concerning interstellar extinction in the ultraviolet are reported. These results were initially obtained by using data from main-sequence stars and were extended to include supergiants and emission stars. The principal finding of the analysis of ultraviolet extinction is not only that it is wavelength dependent, but that if changes with galactic longitude in the U3 passband (lambda sub eff = 1621 A); it does not change significantly in the U2 passband (lambda sub eff = 2308 A). Where data are available in the U4 passband (lambda sub eff = 1537 A), they confirm the rapid rise of extinction in the ultraviolet found by other investigators. However, in all cases, emission stars must be used with great caution. It is important to realize that while extinction continues to rise toward shorter wavelengths in the ultraviolet, including the shortest ultraviolet wavelengths measured (1100 A), it no longer plays an important role in the X-ray region (50 A).

  6. Laser-assisted solar-cell metallization processing

    NASA Technical Reports Server (NTRS)

    Dutta, S.

    1984-01-01

    A photolytic metal deposition system using a focused continuous wave ultraviolet laser, a photolytic metal deposition system using a mask and ultraviolet flood illumination, and a pyrolytic metal deposition system using a focused continuous wave laser were studied. Fabrication of solar cells, as well as characterization to determine the effects of transient heat on solar cell junctions were investigated.

  7. Ultraviolet radiation effects

    NASA Technical Reports Server (NTRS)

    Slemp, Wayne S.

    1989-01-01

    Solar ultraviolet testing was not developed which will provide highly accelerated (20 to 50X) exposures that correlate to flight test data. Additional studies are required to develop an exposure methodology which will assure that accelerated testing can be used for qualification of materials and coatings for long duration space flight. Some conclusions are listed: Solar UV radiation is present in all orbital environments; Solar UV does not change in flux with orbital altitude; UV radiation can degrade most coatings and polymeric films; Laboratory UV simulation methodology is needed for accelerated testing to 20 UV solar constants; Simulation of extreme UV (below 200 nm) is needed to evaluate requirements for EUV in solar simulation.

  8. Ultraviolet observations of comets

    NASA Technical Reports Server (NTRS)

    Code, A. D.; Houck, T. E.; Lillie, C. F.

    1972-01-01

    The first observations of a comet in the vacuum ultraviolet were obtained on January 14, 1970, when OAO-2 recorded the spectrum of the bright comet Tago-Sato-Kosaka (1969g). The observations revealed, among other things, the predicted extensive hydrogen Lyman alpha halo. OAO-2 continued to collect spectrophotometric measurements of this comet throughout January of that year; a photograph of the nucleus in Lyman alpha revealed finer scale structures. In February of 1970, the bright comet Bennet (1969i) became favorable for space observations. On the basis of the OAO discovery, OGO-V made several measurements of comet Bennet with low spatial resolution photometers. Comet Enke was detected by OGO in January of 1971 at a large heliocentric distance from its Lyman alpha emission.

  9. Grating configurations to compress extreme-ultraviolet ultrashort pulses.

    PubMed

    Frassetto, Fabio; Poletto, Luca

    2015-09-10

    It is here discussed the design of ultrafast extreme-ultraviolet (XUV) grating compressors that can be used to condition the spectral phase of ultrashort chirped pulses to compensate for the phase chirp and get closer to the Fourier limit. We discuss the two configurations that can be used to realize the compressor, the classical diffraction mount, and the off-plane one. The concept is applied to the realization of a XUV compressor with applications to free-electron lasers. PMID:26368974

  10. ULTRAVIOLET PROTECTIVE COMPOUNDS AS A RESPONSE TO ULTRAVIOLET RADIATION EXPOSURE

    EPA Science Inventory

    Life on Earth has evolved adaptations to many environmental stresses over the epochs. One consistent stress has been exposure to ultraviolet radiation. In response to UVR organisms have adapted myriad responses; behavioral, morphological and physiological. Behaviorally, some orga...

  11. Battlefield laser wavemeter

    SciTech Connect

    Reiser, C. ); Jensen, C.C. )

    1990-01-01

    In this paper we present a summary of the specifications and architecture for a ruggedized laser wavemeter. This wavemeter is about the size of a pocket calculator and has a wavelength resolution of one part per million. The detectable wavelength range is from the near infrared to the near ultraviolet. The wavemeter is specifically designed to distinguish laser threats from incoherent light sources and measure multiple wavelengths simultaneously. The information update rate is greater than ten readings per second. 1 fig.

  12. The National Ignition Facility: Experimental Capability

    SciTech Connect

    Miller, G H

    2003-09-22

    The National Ignition Facility (NIF) at the Lawrence Livermore National Laboratory is a stadium-sized facility containing a 192-beam, 1.8-Megajoule, 500-Terawatt, ultraviolet laser system together with a 10-meter diameter target chamber with room for nearly 100 experimental diagnostics. NIF will be the world's largest and most energetic laser experimental system, providing a scientific center to study inertial confinement fusion and matter at extreme energy densities and pressures. NIF's energetic laser beams will compress fusion targets to conditions required for thermonuclear burn, liberating more energy than required to initiate the fusion reactions. Other NIF experiments will study physical processes at temperatures approaching 10{sup 8} K and 10{sup 11} bar, conditions that exist naturally only in the interior of stars, planets and in nuclear weapons. NIF has completed the first phases of its laser commissioning program. The first four beams of NIF have generated 106 kilojoules of infrared light and over 16 kJ at the third harmonic (351 nm). NIF's target experimental systems are being commissioned and experiments have begun. This paper discusses NIF's current and future experimental capability, plans for facility diagnostics, cryogenic target systems, specialized optics for experiments, and potential enhancements to NIF such as green laser operation and high-energy short pulse operation.

  13. The National Ignition Facility

    SciTech Connect

    Miller, G H

    2003-12-19

    The National Ignition Facility (NIF) at Lawrence Livermore National Laboratory is a stadium-sized facility containing a 192-beam, 1.8-Megajoule, 500-Terawatt, ultraviolet laser system together with a 10-meter diameter target chamber and room for 100 diagnostics. NIF is the world's largest and most energetic laser experimental system, providing a scientific center to study inertial confinement fusion and matter at extreme energy densities and pressures. NIF's energetic laser beams will compress fusion targets to conditions required for thermonuclear burn, liberating more energy than required to initiate the fusion reactions. Other NIF experiments will study physical processes at temperatures approaching 10{sup 8} K and 10'' bar; conditions that exist naturally only in the interior of stars and planets. NIF has completed the first phases of its laser commissioning program. The first four beams of NIF have generated 106 kilojoules in 23-ns pulses of infrared light and over 16 kJ in 3.5 ns pulses at the third harmonic (351 nm). NIF's target experimental systems are being commissioned and experiments have begun. This paper discusses NIF's current and future experimental capability, plans for diagnostics, cryogenic target systems, specialized optics for experiments, and potential enhancements to NIF such as multi-color laser operation and high-energy short pulse operation.

  14. An enhanced multiwavelength ultraviolet biological trigger lidar

    NASA Astrophysics Data System (ADS)

    Achey, Alexander; Bufton, Jack; Dawson, Jeffrey; Huang, Wen; Lee, Sangmin; Mehta, Nikhil; Prasad, Coorg R.

    2004-12-01

    A compact Ultraviolet Biological Trigger Lidar (UBTL) instrument for detection and discrimination of bio-warfare-agent (BWA) simulant aerosol clouds was developed by us [Prasad, et al, 2004] using a 5mW, 375nm semiconductor UV optical source (SUVOS) laser diode. It underwent successful field tests at Dugway Proving Ground and demonstrated measurement ranges of over 300m for elastic scattering and >100m for fluorescence. The UBTL was modified during mid-2004 to enhance its detection and discrimination performance with increased range of operation and sensitivity. The major optical modifications were: 1. increase in telescope collection aperture to 200 mm diameter: 2. addition of 266nm and 977nm laser transmitters: 3. addition of three detection channels for 266nm and 977nm elastic backscatter and fluorescence centered at 330nm. Also the commercial electronics of the original UBTL were replaced with a multi-channel field programmable gate array (FPGA) chip for laser diode modulation and data acquisition that allowed simultaneous and continuous operation of the UBTL sensor on all of its transmitter and receiver wavelengths. A notebook computer was added for data display and storage. Field tests were performed during July 2004 at the Edgewood Chemical and Biological Center in Maryland to establish the enhanced performance of UBTL subsystems. Results of these tests are presented and discussed.

  15. Research in extreme ultraviolet and far ultraviolet astronomy

    NASA Technical Reports Server (NTRS)

    Bowyer, C. S.

    1985-01-01

    The Far Ultraviolet imager (FUVI) was flown on the Aries class sounding rocket 24.015, producing outstanding results. The diffuse extreme ultraviolet (EUV) background spectrometer which is under construction is described. It will be launched on the Black Brant sounding rocket flight number 27.086. Ongoing design studies of a high resolution spectrometer are discussed. This instrument incorporates a one meter normal incidence mirror and will be suitable for an advanced Spartan mission.

  16. Critical illumination condenser for extreme ultraviolet projection lithography

    NASA Astrophysics Data System (ADS)

    Cohen, S. J.; Seppala, L. G.

    1995-03-01

    A condenser system couples a radiation source to an imaging system. The authors have designed a critical illumination condenser system which meets the technical challenges of extreme ultraviolet projection lithography based on a ring field imaging system and a laser produced plasma source. The optical system, a three spherical mirror optical design, is capable of illuminating the extent of the mask plane by scanning either the primary mirror or the laser plasma source. This type of condenser optical design is sufficiently versatile to be employed with two distinct systems, one from Lawrence Livermore National Laboratory and one from AT and T/Sandia.

  17. Growth of ferroelectric Ba{sub 0.8}Sr{sub 0.2}TiO{sub 3} epitaxial films by ultraviolet pulsed laser irradiation of chemical solution derived precursor layers

    SciTech Connect

    Queraltó, A.; Pérez del Pino, A. Mata, M. de la; Tristany, M.; Gómez, A.; Obradors, X.; Puig, T.; Arbiol, J.

    2015-06-29

    Highly crystalline epitaxial Ba{sub 0.8}Sr{sub 0.2}TiO{sub 3} (BST) thin-films are grown on (001)-oriented LaNiO{sub 3}-buffered LaAlO{sub 3} substrates by pulsed laser irradiation of solution derived barium-zirconium-titanium precursor layers using a UV Nd:YAG laser source at atmospheric conditions. The structural analyses of the obtained films, studied by X-ray diffractometry and transmission electron microscopy, demonstrate that laser processing allows the growth of tens of nm-thick BST epitaxial films with crystalline structure similar to that of films obtained through conventional thermal annealing methods. However, the fast pulsed nature of the laser employed leads to crystallization kinetic evolution orders of magnitude faster than in thermal treatments. The combination of specific photothermal and photochemical mechanisms is the main responsible for the ultrafast epitaxial laser-induced crystallization. Piezoresponse microscopy measurements demonstrate equivalent ferroelectric behavior in laser and thermally annealed films, being the piezoelectric constant ∼25 pm V{sup −1}.

  18. Multifunctional Deployment Hinges Rigidified by Ultraviolet

    NASA Technical Reports Server (NTRS)

    Kerslake, Thomas W.; Simburger, Edward J.; Matusmoto, James; Giants, Thomas W.; Garcia, Alexander; Perry, Alan; Rawal, Suraj; Marshall, Craig; Lin, John Kun Hung; Day, Jonathan Robert; Scarborough, Stephen Emerson

    2005-01-01

    Multifunctional hinges have been developed for deploying and electrically connecting panels comprising planar arrays of thin-film solar photovoltaic cells. In the original intended application of these hinges, the panels would be facets of a 32-sided (and approximately spherical) polyhedral microsatellite (see figure), denoted a PowerSphere, that would be delivered to orbit in a compact folded configuration, then deployed by expansion of gas in inflation bladders. Once deployment was complete, the hinges would be rigidified to provide structural connections that would hold the panels in their assigned relative positions without backlash. Such hinges could also be used on Earth for electrically connecting and structurally supporting solar panels that are similarly shipped in compact form and deployed at their destinations. As shown in section A-A in the figure, a hinge of this type is partly integrated with an inflation bladder and partly integrated with the frame of a solar panel. During assembly of the hinge, strip extensions from a flexible circuit harness on the bladder are connected to corresponding thin-film conductors on the solar panel by use of laser welding and wrap-around contacts. The main structural component of the hinge is a layer of glass fiber impregnated with an ultraviolet-curable resin. After deployment, exposure to ultraviolet light from the Sun cures the resin, thereby rigidifying the hinge.

  19. 21 CFR 872.6350 - Ultraviolet detector.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 21 Food and Drugs 8 2013-04-01 2013-04-01 false Ultraviolet detector. 872.6350 Section 872.6350...) MEDICAL DEVICES DENTAL DEVICES Miscellaneous Devices § 872.6350 Ultraviolet detector. (a) Identification. An ultraviolet detector is a device intended to provide a source of ultraviolet light which is...

  20. 21 CFR 872.6350 - Ultraviolet detector.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 21 Food and Drugs 8 2010-04-01 2010-04-01 false Ultraviolet detector. 872.6350 Section 872.6350...) MEDICAL DEVICES DENTAL DEVICES Miscellaneous Devices § 872.6350 Ultraviolet detector. (a) Identification. An ultraviolet detector is a device intended to provide a source of ultraviolet light which is...

  1. 21 CFR 872.6350 - Ultraviolet detector.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 21 Food and Drugs 8 2012-04-01 2012-04-01 false Ultraviolet detector. 872.6350 Section 872.6350...) MEDICAL DEVICES DENTAL DEVICES Miscellaneous Devices § 872.6350 Ultraviolet detector. (a) Identification. An ultraviolet detector is a device intended to provide a source of ultraviolet light which is...

  2. The Celescope catalog of ultraviolet observations

    NASA Technical Reports Server (NTRS)

    Davis, R. J.

    1972-01-01

    Data obtained from approximately 7500 ultraviolet television pictures are used to compile a celescope catalog of ultraviolet observations. This catalog lists the magnitude as observed in each of celescope's four ultraviolet color bands, the standard deviations of the observed ultraviolet magnitudes, positions, identifications, and ground based magnitudes, colors, and spectral types for approximately 5000 stars.

  3. Vacuum Ultraviolet Photoionization of Complex Chemical Systems

    NASA Astrophysics Data System (ADS)

    Kostko, Oleg; Bandyopadhyay, Biswajit; Ahmed, Musahid

    2016-05-01

    Tunable vacuum ultraviolet (VUV) radiation coupled to mass spectrometry is applied to the study of complex chemical systems. The identification of novel reactive intermediates and radicals is revealed in flame, pulsed photolysis, and pyrolysis reactors, leading to the elucidation of spectroscopy, reaction mechanisms, and kinetics. Mass-resolved threshold photoelectron photoion coincidence measurements provide unprecedented access to vibrationally resolved spectra of free radicals present in high-temperature reactors. Photoionization measurements in water clusters, nucleic acid base dimers, and their complexes with water provide signatures of proton transfer in hydrogen-bonded and π-stacked systems. Experimental and theoretical methods to track ion-molecule reactions and fragmentation pathways in intermolecular and intramolecular hydrogen-bonded systems in sugars and alcohols are described. Photoionization of laser-ablated molecules, clusters, and their reaction products inform thermodynamics and spectroscopy that are relevant to astrochemistry and catalysis. New directions in coupling VUV radiation to interrogate complex chemical systems are discussed.

  4. Vacuum Ultraviolet Photoionization of Complex Chemical Systems.

    PubMed

    Kostko, Oleg; Bandyopadhyay, Biswajit; Ahmed, Musahid

    2016-05-27

    Tunable vacuum ultraviolet (VUV) radiation coupled to mass spectrometry is applied to the study of complex chemical systems. The identification of novel reactive intermediates and radicals is revealed in flame, pulsed photolysis, and pyrolysis reactors, leading to the elucidation of spectroscopy, reaction mechanisms, and kinetics. Mass-resolved threshold photoelectron photoion coincidence measurements provide unprecedented access to vibrationally resolved spectra of free radicals present in high-temperature reactors. Photoionization measurements in water clusters, nucleic acid base dimers, and their complexes with water provide signatures of proton transfer in hydrogen-bonded and π-stacked systems. Experimental and theoretical methods to track ion-molecule reactions and fragmentation pathways in intermolecular and intramolecular hydrogen-bonded systems in sugars and alcohols are described. Photoionization of laser-ablated molecules, clusters, and their reaction products inform thermodynamics and spectroscopy that are relevant to astrochemistry and catalysis. New directions in coupling VUV radiation to interrogate complex chemical systems are discussed. PMID:26980311

  5. Ultraviolet-Induced Mirror Degradation

    NASA Technical Reports Server (NTRS)

    Bouquet, F. L.; Hasegawa, T. T.; Cleland, E. L.

    1982-01-01

    Recent tests of second-surface mirrors show that ultraviolet radiation penetrates glass and metalized zone and impinges upon backing paint. According to report, many backing materials are degraded by ultraviolet radiation. Mirror corrosion is a serious problem in solar-energy collection systems. Effects of UV on polymeric materials have been studied, and in general, all are degraded by UV. Polymers most resistant to UV radiation are polyimides.

  6. Ultraviolet studies of Cepheids

    NASA Technical Reports Server (NTRS)

    Boehm-Vitense, Erika

    1992-01-01

    We discuss whether with new evolutionary tracks we still have a problem fitting the Cepheids and their evolved companions on the appropriate evolutionary tracks. We find that with the Bertelli et al. tracks with convective overshoot by one pressure scale height the problem is essentially removed, though somewhat more mixing would give a better fit. By using the results of recent nonlinear hydrodynamic calculations, we find that we also have no problem matching the observed pulsation periods of the Cepheids with those expected from their new evolutionary masses, provided that Cepheids with periods less than 9 days are overtone pulsators. We investigate possible mass loss of Cepheids from UV studies of the companion spectrum of S Mus and from the ultraviolet spectra of the long period Cepheid l Carinae. For S Mus with a period of 9.6 days we derive an upper limit for the mass loss of M less than 10(exp -9) solar mass, if a standard velocity law is assumed for the wind. For l Carinae with a period of 35.5 days we find a probable mass loss of M is approximately 10(exp -5+/-2) solar mass.

  7. Higgs ultraviolet softening

    NASA Astrophysics Data System (ADS)

    Brivio, I.; Éboli, O. J. P.; Gavela, M. B.; Gonzalez-García, M. C.; Merlo, L.; Rigolin, S.

    2014-12-01

    We analyze the leading effective operators which induce a quartic momentum dependence in the Higgs propagator, for a linear and for a non-linear realization of electroweak symmetry breaking. Their specific study is relevant for the understanding of the ultraviolet sensitivity to new physics. Two methods of analysis are applied, trading the Lagrangian coupling by: i) a "ghost" scalar, after the Lee-Wick procedure; ii) other effective operators via the equations of motion. The two paths are shown to lead to the same effective Lagrangian at first order in the operator coefficients. It follows a modification of the Higgs potential and of the fermionic couplings in the linear realization, while in the non-linear one anomalous quartic gauge couplings, Higgs-gauge couplings and gauge-fermion interactions are induced in addition. Finally, all LHC Higgs and other data presently available are used to constrain the operator coefficients; the future impact of pp → 4 leptons data via off-shell Higgs exchange and of vector boson fusion data is considered as well. For completeness, a summary of pure-gauge and gauge-Higgs signals exclusive to non-linear dynamics at leading-order is included.

  8. Ultraviolet radiation and cyanobacteria.

    PubMed

    Rastogi, Rajesh Prasad; Sinha, Rajeshwar P; Moh, Sang Hyun; Lee, Taek Kyun; Kottuparambil, Sreejith; Kim, Youn-Jung; Rhee, Jae-Sung; Choi, Eun-Mi; Brown, Murray T; Häder, Donat-Peter; Han, Taejun

    2014-12-01

    Cyanobacteria are the dominant photosynthetic prokaryotes from an ecological, economical, or evolutionary perspective, and depend on solar energy to conduct their normal life processes. However, the marked increase in solar ultraviolet radiation (UVR) caused by the continuous depletion of the stratospheric ozone shield has fueled serious concerns about the ecological consequences for all living organisms, including cyanobacteria. UV-B radiation can damage cellular DNA and several physiological and biochemical processes in cyanobacterial cells, either directly, through its interaction with certain biomolecules that absorb in the UV range, or indirectly, with the oxidative stress exerted by reactive oxygen species. However, cyanobacteria have a long history of survival on Earth, and they predate the existence of the present ozone shield. To withstand the detrimental effects of solar UVR, these prokaryotes have evolved several lines of defense and various tolerance mechanisms, including avoidance, antioxidant production, DNA repair, protein resynthesis, programmed cell death, and the synthesis of UV-absorbing/screening compounds, such as mycosporine-like amino acids (MAAs) and scytonemin. This study critically reviews the current information on the effects of UVR on several physiological and biochemical processes of cyanobacteria and the various tolerance mechanisms they have developed. Genomic insights into the biosynthesis of MAAs and scytonemin and recent advances in our understanding of the roles of exopolysaccharides and heat shock proteins in photoprotection are also discussed. PMID:25463663

  9. The SPARTAN Ultraviolet Coronagraph

    NASA Astrophysics Data System (ADS)

    Gardner, L. D.; Esser, R.; Habbal, S. R.; Hassler, D. M.; Raymond, J. C.; Strachan, L.; van Ballegooijen, A. A.; Kohl, J. L.; Fineschi, S.

    1992-05-01

    An ultraviolet coronagraph (UVC) is being prepared for a series of orbital flights on NASA's Spartan 201 which is deployed and retrieved by Shuttle. The Spartan 201 payload consists of the UVC and a white light coronagraph developed by the High Altitude Observatory. Spartan is expected to provide 26 orbits of solar observations per flight. The first flight is scheduled for May 1993 and subsequent flights are planned to occur at each polar passage of Ulysses (1994 and 1995). The UVC measures the intensity and spectral line profile of resonantly scattered H I Ly-alpha and the intensities of O VI lambda 1032 and lambda 1037 at heliocentric heights between 1.3 and 3.5 solar radii. A description of the UVC instrument, its characteristics, and the observing program for the first flight will be presented. The initial scientific objective is to determine the random velocity distribution and bulk outflow velocity of coronal protons and the density and outflow velocity of O(5+) in polar coronal holes and adjoining high latitude streamers. This work is supported by NASA under Grant No. NAG5-613 to the Smithsonian Astrophysical Observatory.

  10. Light, Including Ultraviolet

    PubMed Central

    Maverakis, Emanual; Miyamura, Yoshinori; Bowen, Michael P.; Correa, Genevieve; Ono, Yoko; Goodarzi, Heidi

    2009-01-01

    Ultraviolet (UV) light is intricately linked to the functional status of the cutaneous immune system. In susceptible individuals, UV radiation can ignite pathogenic inflammatory pathways leading to allergy or autoimmunity. In others, this same UV radiation can be used as a phototherapy to suppress pathogenic cutaneous immune responses. These vastly different properties are a direct result of UV light’s ability to ionize molecules in the skin and thereby chemically alter them. Sometimes these UV-induced chemical reactions are essential, the formation of pre-vitamin D3 from 7-dehydrocholesterol, for example. In other instances they can be potentially detrimental. UV radiation can ionize a cell’s DNA causing adjacent pyrimidine bases to chemically bond to each other. To prevent malignant transformation, a cell may respond to this UV-induced DNA damage by undergoing apoptosis. Although this pathway prevents skin cancer it also has the potential of inducing or exacerbating autoreactive immune responses by exposing the cell’s nuclear antigens. Ultaviolet-induced chemical reactions can activate the immune system by a variety of other mechanisms as well. In response to UV irradiation keratinocytes secrete cytokines and chemokines, which activate and recruit leukocytes to the skin. In some individuals UV-induced chemical reactions can synthesize novel antigens resulting in a photoallergy. Alternatively, photosensitizing molecules can damage cells by initiating sunburn-like phototoxic reactions. Herein we review all types of UV-induced skin reactions, especially those involving the immune system. PMID:20018479

  11. Ultraviolet investigations for lunar missions

    USGS Publications Warehouse

    Hemphill, William R.; Fischer, William A.; Dornbach, J.E.

    1966-01-01

    Preliminary field tests of an active ultraviolet imaging system have shown that it is possible to produce linages of the terrain from distances as great as 75 feet by means of reflected ultraviolet light at wavelengths longer than 3300 A. Minerals that luminesce when exposed to ultraviolet energy have been detected from distances as great as 200 feet. With appropriate design modifications, it may be possible to utilize a similar system in detecting luminescing minerals from greater distances. Also, with a similar system and appropriate auxiliary equipment such as image intensifiers, it may be possible to discriminate between naturally occurring materials on the basis of reflected ultraviolet energy at wavelengths shorter than 3000 A. In this part of the spectrum image contrast for some rock types may exceed that from visible light. Information from these and related ultraviolet spectralanalysis studies may be useful in evaluating data obtained from passive ultraviolet systems in lunar orbit as well as from active systems on the lunar surface.

  12. Ultraviolet flare on Lambda Andromedae

    NASA Technical Reports Server (NTRS)

    Baliunas, S. L.; Guinan, E. F.; Dupree, A. K.

    1984-01-01

    On November 5, 6, 1982, a luminous, flarelike brightening of the ultraviolet emissions was observed with IUE from the active RS CVn type star Lambda And during the phase of rotation period corresponding to maximum area coverage of the visible hemisphere by starspots and active regions. Enhancements during the flare in the ultraviolet emission lines as large as factors of several and in the ultraviolet continuum up to 80 percent persisted for over 5 hours. The bulk of the radiative output of the flare occurred in Mg II h and k and H I Ly-alpha. Because of the long duration and extreme luminosity of the event, the energy radiated by the flare alone is in excess of 10 to the 35th ergs just in the ultraviolet region. This is the most energetic stellar flare ever recorded in the ultraviolet. In addition, it is the first ultraviolet flare observed from a giant star. In comparison to the largest solar flares, the flare on Lambda And is at least three orders of magnitude more energetic in similar emission lines.

  13. Ablation of (GeS{sub 2}){sub 0.3}(Sb{sub 2}S{sub 3}){sub 0.7} glass with an ultra-violet nano-second laser

    SciTech Connect

    Knotek, P.; Navesnik, J.; Cernohorsky, T.; Kincl, M.; Vlcek, M.; Tichy, L.

    2015-04-15

    Highlights: • The interaction of (GeS{sub 2}){sub 0.3}(Sb{sub 2}S{sub 3}){sub 0.7} bulk glass and film with UV nanosecond laser. • Ablation process, topography of crater and structure of the material were studied. • Ablation threshold fluencies changed with the spot diameter and number of pulses. • The photo-thermal expansion of the material occurred for low laser fluency. • Laser direct writing process applicable for fabrication of passive optical elements. - Abstract: The results of an experimental study of the laser ablation of bulk and thin films of a GeSbS chalcogenide glass using UV nanosecond pulses are reported. The response of the samples to illumination conditions was studied through the use of atomic force spectroscopy, digital holographic microscopy, Raman scattering and scanning electron microscopy. The multi-pulse ablation thresholds were determined for both the bulk and thin film samples for varying number of pulses and illuminated spot diameter. The possible application of direct laser writing into the bulk and thin films of this material is presented.

  14. Status Of The National Ignition Campaign And National Ignition Facility Integrated Computer Control System

    SciTech Connect

    Lagin, L; Brunton, G; Carey, R; Demaret, R; Fisher, J; Fishler, B; Ludwigsen, P; Marshall, C; Reed, R; Shelton, R; Townsend, S

    2011-03-18

    The National Ignition Facility (NIF) at the Lawrence Livermore National Laboratory is a stadium-sized facility that will contains a 192-beam, 1.8-Megajoule, 500-Terawatt, ultraviolet laser system together with a 10-meter diameter target chamber with room for multiple experimental diagnostics. NIF is the world's largest and most energetic laser experimental system, providing a scientific center to study inertial confinement fusion (ICF) and matter at extreme energy densities and pressures. NIF's laser beams are designed to compress fusion targets to conditions required for thermonuclear burn. NIF is operated by the Integrated Computer Control System (ICCS) in an object-oriented, CORBA-based system distributed among over 1800 frontend processors, embedded controllers and supervisory servers. In the fall of 2010, a set of experiments began with deuterium and tritium filled targets as part of the National Ignition Campaign (NIC). At present, all 192 laser beams routinely fire to target chamber center to conduct fusion and high energy density experiments. During the past year, the control system was expanded to include automation of cryogenic target system and over 20 diagnostic systems to support fusion experiments were deployed and utilized in experiments in the past year. This talk discusses the current status of the NIC and the plan for controls and information systems to support these experiments on the path to ignition.

  15. Far Ultraviolet Astronomy

    NASA Technical Reports Server (NTRS)

    Sonneborn, George; Rabin, Douglas M. (Technical Monitor)

    2002-01-01

    The Far Ultraviolet Spectroscopic Explorer (FUSE) is studying a wide range of astronomical problems in the 905-1187 Angstrom wavelength region through the use of high resolution spectroscopy. The FUSE bandpass forms a nearly optimal complement to the spectral coverage provided by the Hubble Space Telescope (HST), which extends down to approximately 1170 Angstroms. The photoionization threshold of atomic hydrogen (911 Angstroms) sets a natural short-wavelength limit for the FUV. FUSE was launched in June 1999 from Cape Canaveral, Florida, on a Delta II rocket into a 768 km circular orbit. Scientific observations started later that year. This spectral region is extremely rich in spectral diagnostics of astrophysical gases over a wide range of temperatures (100 K to over 10 million K). Important strong spectral lines in this wavelength range include those of neutral hydrogen, deuterium, nitrogen, oxygen, and argon (H I, D I, N I, O I, and Ar I), molecular hydrogen (H2), five-times ionized oxygen (O VI), and several ionization states of sulfur (S III - S VI). These elements are essential for understanding the origin and evolution of the chemical elements, the formation of stars and our Solar System, and the structure of galaxies, including our Milky Way. FUSE is one of NASA's Explorer missions and a cooperative project of NASA and the space agencies of Canada and France. These missions are smaller, more scientifically focused missions than the larger observatories, like Hubble and Chandra. FUSE was designed, built and operated for NASA by the Department of Physics and Astronomy at Johns Hopkins University. Hundreds of astronomers world-wide are using FUSE for a wide range of scientific research. Some of the important scientific discoveries from the first two years of the mission are described.

  16. Laser-assisted solar cell metallization processing

    NASA Technical Reports Server (NTRS)

    Dutta, S.

    1984-01-01

    Laser-assisted processing techniques utilized to produce the fine line, thin metal grid structures that are required to fabricate high efficiency solar cells are examined. Two basic techniques for metal deposition are investigated; (1) photochemical decomposition of liquid or gas phase organometallic compounds utilizing either a focused, CW ultraviolet laser (System 1) or a mask and ultraviolet flood illumination, such as that provided by a repetitively pulsed, defocused excimer laser (System 2), for pattern definition, and (2) thermal deposition of metals from organometallic solutions or vapors utilizing a focused, CW laser beam as a local heat source to draw the metallization pattern.

  17. Plasmonic enhancement of ultraviolet fluorescence

    NASA Astrophysics Data System (ADS)

    Jiao, Xiaojin

    Plasmonics relates to the interaction between electromagnetic radiation and conduction electrons at metallic interfaces or in metallic nanostructures. Surface plasmons are collective electron oscillations at a metal surface, which can be manipulated by shape, texture and material composition. Plasmonic applications cover a broad spectrum from visible to near infrared, including biosensing, nanolithography, spectroscopy, optoelectronics, photovoltaics and so on. However, there remains a gap in this activity in the ultraviolet (UV, < 400 nm), where significant opportunity exists for both fundamental and application research. Motivating factors in the study of UV Plasmonics are the direct access to biomolecular resonances and native fluorescence, resonant Raman scattering interactions, and the potential for exerting control over photochemical reactions. This dissertation aims to fill in the gap of Plasmonics in the UV with efforts of design, fabrication and characterization of aluminium (Al) and magnesium (Mg) nanostructures for the application of label-free bimolecular detection via native UV fluorescence. The first contribution of this dissertation addresses the design of Al nanostructures in the context of UV fluorescence enhancement. A design method that combines analytical analysis with numerical simulation has been developed. Performance of three canonical plasmonic structures---the dipole antenna, bullseye nanoaperture and nanoaperture array---has been compared. The optimal geometrical parameters have been determined. A novel design of a compound bullseye structure has been proposed and numerically analyzed for the purpose of compensating for the large Stokes shift typical of UV fluorescence. Second, UV lifetime modification of diffusing molecules by Al nanoapertures has been experimentally demonstrated for the first time. Lifetime reductions of ~3.5x have been observed for the high quantum yield (QY) laser dye p-terphenyl in a 60 nm diameter aperture with 50

  18. Future Directions in Ultraviolet Spectroscopy

    NASA Technical Reports Server (NTRS)

    Sonneborn, George (Editor); Moos, Warren; VanSteenberg, Michael

    2009-01-01

    The 'Future Directions in Ultraviolet Spectroscopy' conference was inspired by the accomplishments of the Far Ultraviolet Spectroscopic Explorer (FUSE) Mission. The FUSE mission was launched in June 1999 and spent over eight years exploring the far-ultraviolet universe, gathering over 64 million seconds of high-resolution spectral data on nearly 3000 astronomical targets. The goal of this conference was not only to celebrate the accomplishments of FUSE, but to look toward the future and understand the major scientific drivers for the ultraviolet capabilities of the next generation fo space observatories. Invited speakers presented discussions based on measurements made by FUSE and other ultraviolet instruments, assessed their connection with measurements made with other techniques and, where appropriate, discussed the implications of low-z measurements for high-z phenomena. In addition to the oral presentations, many participants presented poster papers. The breadth of these presentation made it clear that much good science is still in progress with FUSE data and that these result will continue to have relevance in many scientific areas.

  19. Harmful effects of ultraviolet radiation

    SciTech Connect

    Not Available

    1989-07-21

    Tanning for cosmetic purposes by sunbathing or by using artificial tanning devices is widespread. The hazards associated with exposure to ultraviolet radiation are of concern to the medical profession. Depending on the amount and form of the radiation, as well as on the skin type of the individual exposed, ultraviolet radiation causes erythema, sunburn, photodamage (photoaging), photocarcinogenesis, damage to the eyes, alteration of the immune system of the skin, and chemical hypersensitivity. Skin cancers most commonly produced by ultraviolet radiation are basal and squamous cell carcinomas. There also is much circumstantial evidence that the increase in the incidence of cutaneous malignant melanoma during the past half century is related to increased sun exposure, but this has not been proved. Effective and cosmetically acceptable sunscreen preparations have been developed that can do much to prevent or reduce most harmful effects to ultraviolet radiation if they are applied properly and consistently. Other safety measures include (1) minimizing exposure to ultraviolet radiation, (2) being aware of reflective surfaces while in the sun, (3) wearing protective clothing, (4) avoiding use of artificial tanning devices, and (5) protecting infants and children.

  20. Extreme ultraviolet reflector

    DOEpatents

    Newnam, Brian E.

    1990-01-01

    A multi-faceted mirror forms a retroreflector for a resonator loop in a free electron laser (FEL) operating in the XUV (.lambda.=10-100 nm). The number of facets is determined by the angle-of-incidence needed to obtain total external reflectance (TER) from the facet surface and the angle through which the FEL beam is to be turned. Angles-of-incidence greater than the angle for TER may be used to increase the area of the beam incident on the surface and reduce energy absorption density. Suitable surface films having TER in the 10-100 nm range may be formed from a variety of materials, including Al, single-crystal Si, Ag, and Rh. One of the facets is formed as an off-axis conic section to collimate the output beam with minimum astigmatism.

  1. Ultraviolet-radiation-curable paints

    SciTech Connect

    Grosset, A M; Su, W F.A.; Vanderglas, E

    1981-09-30

    In product finishing lines, ultraviolet radiation curing of paints on prefabricated structures could be more energy efficient than curing by natural gas fired ovens, and could eliminate solvent emission. Diffuse ultraviolet light can cure paints on three dimensional metal parts. In the uv curing process, the spectral output of radiation sources must complement the absorption spectra of pigments and photoactive agents. Photosensitive compounds, such as thioxanthones, can photoinitiate unsaturated resins, such as acrylated polyurethanes, by a free radical mechanism. Newly developed cationic photoinitiators, such as sulfonium or iodonium salts (the so-called onium salts) of complex metal halide anions, can be used in polymerization of epoxy paints by ultraviolet light radiation. One-coat enamels, topcoats, and primers have been developed which can be photoinitiated to produce hard, adherent films. This process has been tested in a laboratory scale unit by spray coating these materials on three-dimensional objects and passing them through a tunnel containing uv lamps.

  2. Ultraviolet spectrophotometry of three LINERs

    NASA Technical Reports Server (NTRS)

    Goodrich, R. W.; Keel, W. C.

    1986-01-01

    Three galaxies known to be LINERs were observed spectroscopically in the ultraviolet in an attempt to detect the presumed nonthermal continuum source thought to be the source of photoionization in the nuclei. NGC 4501 was found to be too faint for study with the IUE spectrographs, while NGC 5005 had an extended ultraviolet light profile. Comparison with the optical light profile of NGC 5005 indicates that the ultraviolet source is distributed spatially in the same manner as the optical starlight, probably indicating that the ultraviolet excess is due to a component of hot stars in the nucleus. These stars contribute detectable absorption features longward of 2500 A; together with optical data, the IUE spectra suggest a burst of star formation about 1 billion yr ago, with a lower rate continuing to produce a few OB stars. In NGC 4579, a point source contributing most of the ultraviolet excess is found that is much different than the optical light distribution. Furthermore, the ultraviolet to X-ray spectral index in NGC 4579 is 1.4, compatible with the UV to X-ray indices found for samples of Seyfert galaxies. This provides compelling evidence for the detection of the photoionizing continuum in NGC 4579 and draws the research fields of normal galaxies and active galactic nuclei closer together. The emission-line spectrum of NGC 4579 is compared with calculations from a photoionization code, CLOUDY, and several shock models. The photoionization code is found to give superior results, adding to the increasing weight of evidence that the LINER phenomenon is essentially a scaled-down version of the Seyfert phenomenon.

  3. A Virtualized Computing Platform For Fusion Control Systems

    SciTech Connect

    Frazier, T; Adams, P; Fisher, J; Talbot, A

    2011-03-18

    The National Ignition Facility (NIF) at the Lawrence Livermore National Laboratory is a stadium-sized facility that contains a 192-beam, 1.8-Megajoule, 500-Terawatt, ultraviolet laser system together with a 10-meter diameter target chamber with room for multiple experimental diagnostics. NIF is the world's largest and most energetic laser experimental system, providing a scientific center to study inertial confinement fusion (ICF) and matter at extreme energy densities and pressures. NIF's laser beams are designed to compress fusion targets to conditions required for thermonuclear burn, liberating more energy than required to initiate the fusion reactions. 2,500 servers, 400 network devices and 700 terabytes of networked attached storage provide the foundation for NIF's Integrated Computer Control System (ICCS) and Experimental Data Archive. This talk discusses the rationale & benefits for server virtualization in the context of an operational experimental facility, the requirements discovery process used by the NIF teams to establish evaluation criteria for virtualization alternatives, the processes and procedures defined to enable virtualization of servers in a timeframe that did not delay the execution of experimental campaigns and the lessons the NIF teams learned along the way. The virtualization architecture ultimately selected for ICCS is based on the Open Source Xen computing platform and 802.1Q open networking standards. The specific server and network configurations needed to ensure performance and high availability of the control system infrastructure will be discussed.

  4. National Ignition Facility and Managing Location, Component, and State

    SciTech Connect

    Foxworthy, C; Fung, T; Beeler, R; Li, J; Dugorepec, J; Chang, C

    2011-07-25

    The National Ignition Facility (NIF) at the Lawrence Livermore National Laboratory is a stadium-sized facility that contains a 192-beam, 1.8-Megajoule, 500-Terawatt, ultraviolet laser system coupled with a 10-meter diameter target chamber. There are over 6,200 Line Replaceable Units (LRUs) comprised of more than 104,000 serialized parts that make up the NIF. Each LRU is a modular unit typically composed of a mechanical housing, laser optics (glass, lenses, or mirrors), and utilities. To date, there are more than 120,000 data sets created to characterize the attributes of these parts. Greater than 51,000 Work Permits have been issued to install, maintain, and troubleshoot the components. One integrated system is used to manage these data, and more. The Location Component and State (LoCoS) system is a web application built using Java Enterprise Edition technologies and is accessed by over 1,200 users. It is either directly or indirectly involved with each aspect of NIF work activity, and interfaces with ten external systems including the Integrated Computer Control System (ICCS) and the Laser Performance Operations Model (LPOM). Besides providing business functionality, LoCoS also acts as the NIF enterprise service bus. In this role, numerous integration approaches had to be adopted including: file exchange, database sharing, queuing, and web services in order to accommodate various business, technical, and security requirements. Architecture and implementation decisions are discussed.

  5. Reply to 'Comment on 'Photoionization of helium atoms irradiated with intense vacuum ultraviolet free-electron laser light. Part I. Experimental study of multiphoton and single-photon processes''

    SciTech Connect

    Laarmann, T.; Guertler, P.; Laasch, W.; Schulz, J.; Wabnitz, H.; Moeller, T.; Castro, A. R. B. de

    2006-09-15

    We do not agree with the conclusion of the Comment by Charalambidis et al. questioning our observation of two-photon ionization of helium by intense radiation with 13 eV photons from a vuv free-electron laser. Two-photon ionization is clearly established by the detection of low-energy photoelectrons at {approx}1.7 eV, which agrees very well with the expected energy for a two-photon ionization process.

  6. Ultraviolet corona detection sensor study

    NASA Technical Reports Server (NTRS)

    Schmitt, R. J.; MATHERN

    1976-01-01

    The feasibility of detecting electrical corona discharge phenomena in a space simulation chamber via emission of ultraviolet light was evaluated. A corona simulator, with a hemispherically capped point to plane electrode geometry, was used to generate corona glows over a wide range of pressure, voltage, current, electrode gap length and electrode point radius. Several ultraviolet detectors, including a copper cathode gas discharge tube and a UV enhanced silicon photodiode detector, were evaluated in the course of the spectral intensity measurements. The performance of both silicon target vidicons and silicon intensified target vidicons was evaluated analytically using the data generated by the spectroradiometer scans and the performance data supplied by the manufacturers.

  7. Ultraviolet avalanche photodiodes

    NASA Astrophysics Data System (ADS)

    McClintock, Ryan; Razeghi, Manijeh

    2015-08-01

    The III-Nitride material system is rapidly maturing; having proved itself as a material for LEDs and laser, and now finding use in the area of UV photodetectors. However, many UV applications are still dominated by the use of photomultiplier tubes (PMT). PMTs are capable of obtaining very high sensitivity using internal electron multiplication gain (typically ~106). It is highly desirable to develop a compact semiconductor-based photodetector capable of realizing this level of sensitivity. In principle, this can be obtained in III-Nitrides by taking advantage of avalanche multiplication under high electric fields - typically 2.7 MV/cm, which with proper design can correspond to an external reverse bias of less than 100 volts. In this talk, we review the current state-of-the-art in III-Nitride solar- and visible-blind APDs, and present our latest results on GaN APDs grown on both conventional sapphire and low dislocation density free-standing c- and m-plane GaN substrates. Leakage current, gain, and single photon detection efficiency (SPDE) of these APDs were compared. The spectral response and Geiger-mode photon counting performance of UV APDs are studied under low photon fluxes, with single photon detection capabilities as much as 30% being demonstrated in smaller devices. Geiger-mode operation conditions are optimized for enhanced SPDE.

  8. Bright subcycle extreme ultraviolet bursts from a single dense relativistic electron sheet.

    PubMed

    Ma, W J; Bin, J H; Wang, H Y; Yeung, M; Kreuzer, C; Streeter, M; Foster, P S; Cousens, S; Kiefer, D; Dromey, B; Yan, X Q; Meyer-ter-Vehn, J; Zepf, M; Schreiber, J

    2014-12-01

    Double-foil targets separated by a low density plasma and irradiated by a petawatt-class laser are shown to be a copious source of coherent broadband radiation. Simulations show that a dense sheet of relativistic electrons is formed during the interaction of the laser with the tenuous plasma between the two foils. The coherent motion of the electron sheet as it transits the second foil results in strong broadband emission in the extreme ultraviolet, consistent with our experimental observations. PMID:25526132

  9. Ultraviolet and Light Absorption Spectrometry.

    ERIC Educational Resources Information Center

    Hargis, L. G.; Howell, J. A.

    1984-01-01

    Reviews developments in ultraviolet and light absorption spectrometry from December 1981 through November 1983, focusing on the chemistry involved in developing suitable reagents, absorbing systems, and methods of determination, and on physical aspects of the procedures. Includes lists of spectrophotometric methods for metals, non-metals, and…

  10. 21 CFR 872.6350 - Ultraviolet detector.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 21 Food and Drugs 8 2011-04-01 2011-04-01 false Ultraviolet detector. 872.6350 Section 872.6350 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED.... An ultraviolet detector is a device intended to provide a source of ultraviolet light which is...

  11. 21 CFR 872.6350 - Ultraviolet detector.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 21 Food and Drugs 8 2014-04-01 2014-04-01 false Ultraviolet detector. 872.6350 Section 872.6350 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED.... An ultraviolet detector is a device intended to provide a source of ultraviolet light which is...

  12. Growth and ultraviolet application of Li2B4O7 crystals: Generation of the fourth and fifth harmonics of Nd:Y3Al5O12 lasers

    NASA Astrophysics Data System (ADS)

    Komatsu, R.; Sugawara, T.; Sassa, K.; Sarukura, N.; Liu, Z.; Izumida, S.; Segawa, Y.; Uda, S.; Fukuda, T.; Yamanouchi, K.

    1997-06-01

    A 2 in. diam single crystal of lithium tetraborate (Li2B4O7) was successfully grown by the Czochralski method. The crystal was free from macrodefects and had a dislocation density as low as 100/cm2. It had an excellent homogeneity of the refractive index and a wide transparency down to 170 nm. The optical damage threshold was 40 GW/cm2. Second-harmonic generation and sum frequency generation were investigated in association with the generation of the fourth and fifth harmonics of a Q-switched Nd:YAG laser. The conversion efficiency of the second-harmonic generation from the green (532 nm) light was 20%.

  13. NASA Space Laser Technology

    NASA Technical Reports Server (NTRS)

    Krainak, Michael A.

    2015-01-01

    Over the next two decades, the number of space based laser missions for mapping, spectroscopy, remote sensing and other scientific investigations will increase several fold. The demand for high wall-plug efficiency, low noise, narrow linewidth laser systems to meet different systems requirements that can reliably operate over the life of a mission will be high. The general trends will be for spatial quality very close to the diffraction limit, improved spectral performance, increased wall-plug efficiency and multi-beam processing. Improved spectral performance will include narrower spectral width (very near the transform limit), increased wavelength stability and or tuning (depending on application) and lasers reaching a wider range of wavelengths stretching into the mid-infrared and the near ultraviolet. We are actively developing high efficiency laser transmitter and high-sensitivity laser receiver systems that are suitable for spaceborne applications.

  14. Regulation of keratin expression by ultraviolet radiation: differential and specific effects of ultraviolet B and ultraviolet a exposure.

    PubMed

    Bernerd, F; Del Bino, S; Asselineau, D

    2001-12-01

    Skin, the most superficial tissue of our body, is the first target of environmental stimuli, among which is solar ultraviolet radiation. Very little is known about the regulation of keratin gene expression by ultraviolet radiation, however, although (i) it is well established that ultraviolet exposure is involved in skin cancers and photoaging and (ii) keratins represent the major epidermal proteins. The aim of this study was to analyze the regulation of human keratin gene expression under ultraviolet B (290-320 nm) or ultraviolet A (320-400 nm) irradiation using a panel of constructs comprising different human keratin promoters cloned upstream of a chloramphenicol acetyl transferase reporter gene and transfected into normal epidermal keratinocytes. By this approach, we demonstrated that ultraviolet B upregulated the transcription of keratin 19 gene and to a lesser extent the keratin 6, keratin 5, and keratin 14 genes. The DNA sequence responsible for keratin 19 induction was localized between -130 and +1. In contrast to ultraviolet B, ultraviolet A irradiation induced only an increase in keratin 17, showing a differential gene regulation between these two ultraviolet ranges. The induction of keratin 19 was confirmed by studying the endogenous protein in keratinocytes in classical cultures as well as in skin reconstructed in vitro and normal human skin. These data show for the first time that keratin gene expression is regulated by ultraviolet radiation at the transcriptional level with a specificity regarding the ultraviolet domain of solar light. PMID:11886503

  15. Application of lasers in endodontics

    NASA Astrophysics Data System (ADS)

    Ertl, Thomas P.; Benthin, Hartmut; Majaron, Boris; Mueller, Gerhard J.

    1997-12-01

    Root canal treatment is still a problem in dentistry. Very often the conventional treatment fails and several treatment sessions are necessary to save the tooth from root resection or extraction. Application of lasers may help in this situation. Bacteria reduction has been demonstrated both in vitro and clinically and is either based on laser induced thermal effects or by using an ultraviolet light source. Root canal cleansing is possible by Er:YAG/YSGG-Lasers, using the hydrodynamic motion of a fluid filled in the canals. However root canal shaping using lasers is still a problem. Via falsas and fiber breakage are points of research.

  16. Optical coatings for laser fusion applications

    SciTech Connect

    Lowdermilk, W.H.; Milam, D.; Rainer, F.

    1980-04-24

    Lasers for fusion experiments use thin-film dielectric coatings for reflecting, antireflecting and polarizing surface elements. Coatings are most important to the Nd:glass laser application. The most important requirements of these coatings are accuracy of the average value of reflectance and transmission, uniformity of amplitude and phase front of the reflected or transmitted light, and laser damage threshold. Damage resistance strongly affects the laser's design and performance. The success of advanced lasers for future experiments and for reactor applications requires significant developments in damage resistant coatings for ultraviolet laser radiation.

  17. Tunable, rare earth-doped solid state lasers

    DOEpatents

    Emmett, John L.; Jacobs, Ralph R.; Krupke, William F.; Weber, Marvin J.

    1980-01-01

    Laser apparatus comprising combinations of an excimer pump laser and a rare earth-doped solid matrix, utilizing the 5d-4f radiative transition in a rare earth ion to produce visible and ultra-violet laser radiation with high overall efficiency in selected cases and relatively long radiative lifetimes.

  18. Indirect Ultraviolet-Reactivation of Phage λ

    PubMed Central

    George, Jacqueline; Devoret, Raymond; Radman, Miroslav

    1974-01-01

    When an F- recipient Escherichia coli K12 bacterium receives Hfr or F-lac+ DNA from an ultraviolet-irradiated donor, its capacity to promote DNA repair and mutagenesis of ultraviolet-damaged phage λ is substantially increased. We call this phenomenon indirect ultraviolet-reactivation, since its features are essentially the same as those of ultraviolet-reactivation; this repair process occurs in pyrimidine dimer excision-deficient strains and produces clear plaque mutations of the restored phage. Moreover, this process is similar to indirect ultraviolet-induction of prophage λ, since it is promoted by conjugation. However, contrarily to indirect induction, it is produced by Hfr donors and occurs in recipients restricting the incoming ultraviolet-damaged donor DNA. The occurrence of indirect ultraviolet-reactivation provides evidence for the existence in E. coli of an inducible error-prone mechanism for the repair of DNA. PMID:4589889

  19. Extreme ultraviolet emission spectra of Gd and Tb ions

    SciTech Connect

    Kilbane, D.; O'Sullivan, G.

    2010-11-15

    Theoretical extreme ultraviolet emission spectra of gadolinium and terbium ions calculated with the Cowan suite of codes and the flexible atomic code (FAC) relativistic code are presented. 4d-4f and 4p-4d transitions give rise to unresolved transition arrays in a range of ions. The effects of configuration interaction are investigated for transitions between singly excited configurations. Optimization of emission at 6.775 nm and 6.515 nm is achieved for Gd and Tb ions, respectively, by consideration of plasma effects. The resulting synthetic spectra are compared with experimental spectra recorded using the laser produced plasma technique.

  20. Tabletop Extreme Ultraviolet Spectroscopy of Element-Specific Organometallic Photophysics

    NASA Astrophysics Data System (ADS)

    Vura-Weis, Josh

    High-harmonic extreme ultraviolet (XUV) spectroscopy has the potential to provide the elemental, oxidation-state, and spin-state specificity of core-level spectroscopy with the convenience and ultrafast time resolution of tabletop laser sources. We will show that M-edge spectroscopy of first-row transition metal complexes (3p -->3d excitation) is a sensitive probe of the electronic structure of organometallic complexes in solution. Furthermore, this technique can be used to determine the relaxation dynamics of these molecules in the first few femtoseconds to nanoseconds after photoexcitation.

  1. Characteristics of extreme ultraviolet emission from high-Z plasmas

    NASA Astrophysics Data System (ADS)

    Ohashi, H.; Higashiguchi, T.; Suzuki, Y.; Kawasaki, M.; Suzuki, C.; Tomita, K.; Nishikino, M.; Fujioka, S.; Endo, A.; Li, B.; Otsuka, T.; Dunne, P.; O'Sullivan, G.

    2016-03-01

    We demonstrate the extreme ultraviolet (EUV) and soft x-ray sources in the 2 to 7 nm spectral region related to the beyond EUV (BEUV) question at 6.x nm and the water window source based on laser-produced high-Z plasmas. Resonance emission from multiply charged ions merges to produce intense unresolved transition arrays (UTAs), extending below the carbon K edge (4.37 nm). An outline of a microscope design for single-shot live cell imaging is proposed based on high-Z plasma UTA source, coupled to multilayer mirror optics.

  2. Laser Remote Sensing at NASA

    NASA Technical Reports Server (NTRS)

    Barnes, Norman P.

    2005-01-01

    NASA is developing active remote sensors to monitor the health of Planet Earth and for exploration of other planets. Development and deployment of these remote sensors can have a huge economic impact. Lasers for these active remote sensors span the spectral range from the ultraviolet to the mid infrared spectral regions. Development activities range from quantum mechanical modeling and prediction of new laser materials to the design, development, and demonstration be deployed in the field.

  3. High Power Pulsed Gas Lasers

    NASA Astrophysics Data System (ADS)

    Witteman, W. J.

    1987-09-01

    Gas lasers have shown to be capable of delivering tens of terrawatt aspeak power or tens of kilowatt as average power. The efficiencies of most high power gas lasers are relatively high compared with other types of lasers. For instance molecular lasers, oscillating on low lying vibrational levels, and excimer lasers may have intrinsic efficiencies above 10%.The wavelengths of these gas lasers cover the range from the far infrared to the ultra-violet region, say from 12000 to 193 nm. The most important properties are the scalability, optical homogeneity of the excited medium, and the relatively low price per watt of output power. The disadvantages may be the large size of the systems and the relatively narrow line width with limited tunability compared with solid state systems producing the same peak power. High power gas lasers group into three main categories depending on the waste-heat handling capacity.

  4. Interstellar extinction in the ultraviolet

    NASA Technical Reports Server (NTRS)

    Bless, R. C.; Savage, B. D.

    1972-01-01

    Interstellar extinction curves over the region 3600-1100 A for 17 stars are presented. The observations were made by the two Wisconsin spectrometers onboard the OAO-2 with spectral resolutions of 10 A and 20 A. The extinction curves generally show a pronounced maximum at 2175 plus or minus 25 A, a broad minimum in the region 1800-1350 A, and finally a rapid rise to the far ultraviolet. Large extinction variations from star to star are found, especially in the far ultraviolet; however, with only two possible exceptions in this sample, the wavelength at the maximum of the extinction bump is essentially constant. These data are combined with visual and infrared observations to display the extinction behavior over a range in wavelength of about a factor of 20.

  5. International Ultraviolet Explorer Observatory operations

    NASA Technical Reports Server (NTRS)

    1985-01-01

    This volume contains the final report for the International Ultraviolet Explorer IUE Observatory Operations contract. The fundamental operational objective of the International Ultraviolet Explorer (IUE) program is to translate competitively selected observing programs into IUE observations, to reduce these observations into meaningful scientific data, and then to present these data to the Guest Observer in a form amenable to the pursuit of scientific research. The IUE Observatory is the key to this objective since it is the central control and support facility for all science operations functions within the IUE Project. In carrying out the operation of this facility, a number of complex functions were provided beginning with telescope scheduling and operation, proceeding to data processing, and ending with data distribution and scientific data analysis. In support of these critical-path functions, a number of other significant activities were also provided, including scientific instrument calibration, systems analysis, and software support. Routine activities have been summarized briefly whenever possible.

  6. The Extreme Ultraviolet Explorer mission

    NASA Technical Reports Server (NTRS)

    Welsh, Barry Y.

    1991-01-01

    The Extreme Ultraviolet Explorer (EUVE) is a NASA astronomy mission which will operate in the 70-760A spectral band. The science payload consists of three grazing incidence scanning telescopes and an EUV spectrometer/deep survey instrument. An overview of the planned mission profile is given, and the instrumentation which comprises the science payload is discussed. The EUVE is scheduled for launch in late August 1991.

  7. Search for ultraviolet Shuttle glow

    NASA Technical Reports Server (NTRS)

    Tennyson, P. D.; Feldman, P. D.; Henry, R. C.

    1987-01-01

    In January 1986, the Space Shuttle Columbia carried two ultraviolet experiments (UVX) in an attempt to observe very weak diffuse emission from various astronomical sources at wavelengths below 3200 A with moderate spectral resolution. The experiment attested to the feasibility of low cost astronomy from the Space Shuttle using Get Away Special canisters. Emissions from O2, O, and NO were detected and shown to be consistent with an atmospheric origin.

  8. Far-Ultraviolet Stellar Photometry

    NASA Astrophysics Data System (ADS)

    Schmidt, E. G.; Carruthers, G. R.

    1993-12-01

    During a shuttle flight in May, 1991, wide field images were obtained for 12 star fields with the NRL far-ultraviolet cameras. These cameras provide sensitivity bands with effective wavelengths of lambda eff = 1367 Angstroms and lambda eff = 1702 Angstroms. The properties of the resulting magnitude system will be described and compared with previous photometry from the OAO2, ANS and TD1 satellites. Results from several fields in the vicinity of the galactic center will be discussed.

  9. Ultraviolet-Resistant Bacterial Spores

    NASA Technical Reports Server (NTRS)

    Venkateswaran, Kasthuri; Newcombe, David; LaDuc, Myron T.; Osman, Shariff R.

    2007-01-01

    A document summarizes a study in which it was found that spores of the SAFR-032 strain of Bacillus pumilus can survive doses of ultraviolet (UV) radiation, radiation, and hydrogen peroxide in proportions much greater than those of other bacteria. The study was part of a continuing effort to understand the survivability of bacteria under harsh conditions and develop means of sterilizing spacecraft to prevent biocontamination of Mars that could interfere with the search for life there.

  10. Ultraviolet observations of astronomical sources

    NASA Technical Reports Server (NTRS)

    Eaton, Joel A.

    1994-01-01

    The final report on 'Ultraviolet Observations of Astronomical Sources,' which ran for a total of three years, roughly between 1 July 1988 and 14 Feb. 1993 is presented. During the first year, I worked at Indiana University; since October, 1989, I have been at Tennessee State University. This grant has supported my studies of archival International Ultraviolet Explorer (IUE) observations of zeta Aur binaries, cool stars that are paired with hot stars in binary systems. Such systems are important as a source of detailed knowledge about the structures of chromospheres and winds in cool giant and supergiant stars, since the hot star serves as a probe of many lines of sight through the cool supergiant star's outer atmosphere. By determining the physical conditions along many such lines of sight, a detailed two-dimensional map of the chromosphere and wind may be constructed. The grant grew out of my analysis of archival IUE observations of 31 Cyg in which I analyzed five epochs of an atmospheric eclipse that occurred in 1982. I fit the attenuation spectra of atmospheric eclipse throughout the ultraviolet (lambda(lambda)1175-1950 and lambda(lambda)2500-3100) with theoretically calculated spectra, thereby determining the physical properties of gas (mass column density of absorbers, temperature, and velocity spread) along each observed line of sight. A similar analysis for other such zeta Aur binaries was accomplished and theoretical models for the chromospheres of these stars based on my observations were constructed.

  11. Spectral diversity crystalline fluoride lasers

    SciTech Connect

    Jenssen, H.P.; Gabbe, D.R.; Linz, A.; Naiman, C.S.

    1981-01-01

    Within the realm of crystalline laser materials, the class of fluorides distinguishes itself mostly by the wide variety of laser wavelengths displayed. Laser operation has now been reported from 3.9 micrometers in the infrared to 286 nm in the ultraviolet. Many are operated flash-lamp pumped, while others have shown high utility as linear down conversion lasers and rare earth ion, while others are sensitized by other co-dopants which absorb the pump energy and transfer it to the active laser ions. The potential of large spectral diversity for laser operation is due both to the wide window of transparency that fluorides possess and the lower rates of nonradiative decay. The high band gap in the ultraviolet also leads to low linear absorption, low nonlinear refractive indices and multiphoton absorption. Additionally, the good chemical stability displayed by high-purity stoichiometric fluoride compounds allows their use with ultraviolet pump sources at high energies, without incurring UV-induced damage. The most recent research associated with such materials, particularly the host crystal, lithium yttrium fluoride, LiYF4 (YLF) is reviewed.

  12. Ultraviolet surface plasmon-mediated low temperature hydrazine decomposition

    SciTech Connect

    Peng, Siying; Sheldon, Matthew T.; Atwater, Harry A.; Liu, Wei-Guang; Jaramillo-Botero, Andres; Goddard, William Andrew

    2015-01-12

    Conventional methods require elevated temperatures in order to dissociate high-energy nitrogen bonds in precursor molecules such as ammonia or hydrazine used for nitride film growth. We report enhanced photodissociation of surface-absorbed hydrazine (N{sub 2}H{sub 4}) molecules at low temperature by using ultraviolet surface plasmons to concentrate the exciting radiation. Plasmonic nanostructured aluminum substrates were designed to provide resonant near field concentration at λ = 248 nm (5 eV), corresponding to the maximum optical cross section for hydrogen abstraction from N{sub 2}H{sub 4}. We employed nanoimprint lithography to fabricate 1 mm × 1 mm arrays of the resonant plasmonic structures, and ultraviolet reflectance spectroscopy confirmed resonant extinction at 248 nm. Hydrazine was cryogenically adsorbed to the plasmonic substrate in a low-pressure ambient, and 5 eV surface plasmons were resonantly excited using a pulsed KrF laser. Mass spectrometry was used to characterize the photodissociation products and indicated a 6.2× overall enhancement in photodissociation yield for hydrazine adsorbed on plasmonic substrates compared with control substrates. The ultraviolet surface plasmon enhanced photodissociation demonstrated here may provide a valuable method to generate reactive precursors for deposition of nitride thin film materials at low temperatures.

  13. Ultraviolet surprise: Efficient soft x-ray high-harmonic generation in multiply ionized plasmas

    NASA Astrophysics Data System (ADS)

    Popmintchev, Dimitar; Hernández-García, Carlos; Dollar, Franklin; Mancuso, Christopher; Pérez-Hernández, Jose A.; Chen, Ming-Chang; Hankla, Amelia; Gao, Xiaohui; Shim, Bonggu; Gaeta, Alexander L.; Tarazkar, Maryam; Romanov, Dmitri A.; Levis, Robert J.; Gaffney, Jim A.; Foord, Mark; Libby, Stephen B.; Jaron-Becker, Agnieszka; Becker, Andreas; Plaja, Luis; Murnane, Margaret M.; Kapteyn, Henry C.; Popmintchev, Tenio

    2015-12-01

    High-harmonic generation is a universal response of matter to strong femtosecond laser fields, coherently upconverting light to much shorter wavelengths. Optimizing the conversion of laser light into soft x-rays typically demands a trade-off between two competing factors. Because of reduced quantum diffusion of the radiating electron wave function, the emission from each species is highest when a short-wavelength ultraviolet driving laser is used. However, phase matching—the constructive addition of x-ray waves from a large number of atoms—favors longer-wavelength mid-infrared lasers. We identified a regime of high-harmonic generation driven by 40-cycle ultraviolet lasers in waveguides that can generate bright beams in the soft x-ray region of the spectrum, up to photon energies of 280 electron volts. Surprisingly, the high ultraviolet refractive indices of both neutral atoms and ions enabled effective phase matching, even in a multiply ionized plasma. We observed harmonics with very narrow linewidths, while calculations show that the x-rays emerge as nearly time-bandwidth-limited pulse trains of ~100 attoseconds.

  14. The Ultraviolet Surprise. Efficient Soft X-Ray High Harmonic Generation in Multiply-Ionized Plasmas

    SciTech Connect

    Popmintchev, Dimitar; Hernandez-Garcia, Carlos; Dollar, Franklin; Mancuso, Christopher; Perez-Hernandez, Jose A.; Chen, Ming-Chang; Hankla, Amelia; Gao, Xiaohui; Shim, Bonggu; Gaeta, Alexander L.; Tarazkar, Maryam; Romanov, Dmitri A.; Levis, Robert J.; Gaffney, Jim A.; Foord, Mark; Libby, Stephen B.; Jaron-Becker, Agnieskzka; Becker, Andreas; Plaja, Luis; Muranane, Margaret M.; Kapteyn, Henry C.; Popmintchev, Tenio

    2015-12-04

    High-harmonic generation is a universal response of matter to strong femtosecond laser fields, coherently upconverting light to much shorter wavelengths. Optimizing the conversion of laser light into soft x-rays typically demands a trade-off between two competing factors. Reduced quantum diffusion of the radiating electron wave function results in emission from each species which is highest when a short-wavelength ultraviolet driving laser is used. But, phase matching—the constructive addition of x-ray waves from a large number of atoms—favors longer-wavelength mid-infrared lasers. We identified a regime of high-harmonic generation driven by 40-cycle ultraviolet lasers in waveguides that can generate bright beams in the soft x-ray region of the spectrum, up to photon energies of 280 electron volts. Surprisingly, the high ultraviolet refractive indices of both neutral atoms and ions enabled effective phase matching, even in a multiply ionized plasma. We observed harmonics with very narrow linewidths, while calculations show that the x-rays emerge as nearly time-bandwidth–limited pulse trains of ~100 attoseconds.

  15. The Ultraviolet Surprise. Efficient Soft X-Ray High Harmonic Generation in Multiply-Ionized Plasmas

    DOE PAGESBeta

    Popmintchev, Dimitar; Hernandez-Garcia, Carlos; Dollar, Franklin; Mancuso, Christopher; Perez-Hernandez, Jose A.; Chen, Ming-Chang; Hankla, Amelia; Gao, Xiaohui; Shim, Bonggu; Gaeta, Alexander L.; et al

    2015-12-04

    High-harmonic generation is a universal response of matter to strong femtosecond laser fields, coherently upconverting light to much shorter wavelengths. Optimizing the conversion of laser light into soft x-rays typically demands a trade-off between two competing factors. Reduced quantum diffusion of the radiating electron wave function results in emission from each species which is highest when a short-wavelength ultraviolet driving laser is used. But, phase matching—the constructive addition of x-ray waves from a large number of atoms—favors longer-wavelength mid-infrared lasers. We identified a regime of high-harmonic generation driven by 40-cycle ultraviolet lasers in waveguides that can generate bright beams inmore » the soft x-ray region of the spectrum, up to photon energies of 280 electron volts. Surprisingly, the high ultraviolet refractive indices of both neutral atoms and ions enabled effective phase matching, even in a multiply ionized plasma. We observed harmonics with very narrow linewidths, while calculations show that the x-rays emerge as nearly time-bandwidth–limited pulse trains of ~100 attoseconds.« less

  16. Multistep Ionization of Argon Clusters in Intense Femtosecond Extreme Ultraviolet Pulses

    SciTech Connect

    Bostedt, C.; Thomas, H.; Hoener, M.; Eremina, E.; Fennel, T.; Meiwes-Broer, K.-H.; Wabnitz, H.; Kuhlmann, M.; Ploenjes, E.; Tiedtke, K.; Treusch, R.; Feldhaus, J.; Castro, A. R. B. de; Moeller, T.

    2008-04-04

    The interaction of intense extreme ultraviolet femtosecond laser pulses ({lambda}=32.8 nm) from the FLASH free electron laser (FEL) with clusters has been investigated by means of photoelectron spectroscopy and modeled by Monte Carlo simulations. For laser intensities up to 5x10{sup 13} W/cm{sup 2}, we find that the cluster ionization process is a sequence of direct electron emission events in a developing Coulomb field. A nanoplasma is formed only at the highest investigated power densities where ionization is frustrated due to the deep cluster potential. In contrast with earlier studies in the IR and vacuum ultraviolet spectral regime, we find no evidence for electron emission from plasma heating processes.

  17. Laser dye technology

    SciTech Connect

    Hammond, P R

    1999-09-01

    The author has worked with laser dyes for a number of years. A first interest was in the Navy blue-green program where a flashlamp pumped dye laser was used as an underwater communication and detection device. It made use of the optical window of sea-water--blue for deep ocean, green for coastal water. A major activity however has been with the Atomic Vapor Laser Isotope Separation Program (AVLIS) at the Lawrence Livermore National Laboratory. The aim here has been enriching isotopes for the nuclear fuel cycle. The tunability of the dye laser is utilized to selectively excite one isotope in uranium vapor, and this isotope is collected electrostatically as shown in Figure 1. The interests in the AVLIS program have been in the near ultra-violet, violet, red and deep-red.

  18. Far ultraviolet astronomy using the FAUST telescope

    NASA Technical Reports Server (NTRS)

    Bowyer, C. S.

    1981-01-01

    The Far Ultraviolet Space Telescope (FAUST) a compact, wide field-of-view, far ultraviolet instrument designed for astronomical observations of extended and point sources is discussed. The design and application of the instrument are described. The prime objective is to observe faint astronomical sources with sensitivities higher than previously available. Scientific programs will include: (1) a search for ultraviolet stars which are predicted to exist at the stage of evolution prior to the final death of a star; (2) observations of galaxies and quasars; and (3) joint programs with other Spacelab 1 experiments. The secondary objective is to verify the suitability of the Spacelab as a platform for far ultraviolet astronomy: data will be provided on the ultraviolet background levels due to astronomical, terrestrial, and spacecraft generated sources; the levels of contaminants which affect ultraviolet instruments; and the capability of the Orbiter for stable pointing at celestial sources for useful periods of time.

  19. Sensitivity calibration of an imaging extreme ultraviolet spectrometer-detector system for determining the efficiency of broadband extreme ultraviolet sources

    SciTech Connect

    Fuchs, S.; Roedel, C.; Bierbach, J.; Paz, A. E.; Foerster, E.; Paulus, G. G.; Krebs, M.; Haedrich, S.; Limpert, J.; Kuschel, S.; Wuensche, M.; Hilbert, V.; Zastrau, U.

    2013-02-15

    We report on the absolute sensitivity calibration of an extreme ultraviolet (XUV) spectrometer system that is frequently employed to study emission from short-pulse laser experiments. The XUV spectrometer, consisting of a toroidal mirror and a transmission grating, was characterized at a synchrotron source in respect of the ratio of the detected to the incident photon flux at photon energies ranging from 15.5 eV to 99 eV. The absolute calibration allows the determination of the XUV photon number emitted by laser-based XUV sources, e.g., high-harmonic generation from plasma surfaces or in gaseous media. We have demonstrated high-harmonic generation in gases and plasma surfaces providing 2.3 {mu}W and {mu}J per harmonic using the respective generation mechanisms.

  20. Polymerizable ultraviolet stabilizers for outdoor use

    NASA Technical Reports Server (NTRS)

    Vogl, O.

    1982-01-01

    Polymeric materials that are stable enough to use outdoors without changes in excess of 20 years are investigated. Ultraviolet stabilizers or plastic materials were synthesized, polymerizable ultraviolet stabilizers, particularly of the 2(2-hydroxyphenyl)2H-benzotriazole family were prepared their polymerization, copolymerization and grafting onto other polymers were demonstrated, and ultraviolet stabilizing systems were devised. These materials were evaluated from the photophysical point of view.