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Sample records for 500-terawatt ultraviolet laser

  1. Development of ultraviolet lasers

    NASA Technical Reports Server (NTRS)

    Walters, G. K.

    1974-01-01

    The pulsed electron accelerator selected for use in the development of ultraviolet laser capability suitable for use in photoexcitation and photoionization studies of the upper atmosphere is reported. Performance figures, installation specifications, and total cost of the equipment are briefly shown, and plans for further studies are outlined.

  2. Ultraviolet laser excitation source

    NASA Technical Reports Server (NTRS)

    Lee, J. H.; Mcfarland, D. R.; Hohl, F.

    1980-01-01

    A new intense ultraviolet light source has been developed from an array of hypocycloidal pinch (HCP) devices. The basic unit of the array is constructed with three disk electrodes and is capable of producing dense plasmas at temperatures up to 10,000,000 K. Very high input power levels to the array are possible without significantly shortening its useful life, in strong contrast with conventional xenon flashlamps. The new light source, when operated with Ar and Xe gas mixtures at high pressures (approximately 5 x 10 to the 4th Pa), produced a light output of over 100 MW in the near-UV spectral range and successfully pumped an iodine photodissociation laser at 1.315 microns. A xenon recombination laser at 2.027 microns was also pumped in the HCP array.

  3. Ultraviolet radiation induced discharge laser

    DOEpatents

    Gilson, Verle A.; Schriever, Richard L.; Shearer, James W.

    1978-01-01

    An ultraviolet radiation source associated with a suitable cathode-anode electrode structure, disposed in a gas-filled cavity of a high pressure pulsed laser, such as a transverse electric atmosphere (TEA) laser, to achieve free electron production in the gas by photoelectric interaction between ultraviolet radiation and the cathode prior to the gas-exciting cathode-to-anode electrical discharge, thereby providing volume ionization of the gas. The ultraviolet radiation is produced by a light source or by a spark discharge.

  4. Vacuum ultraviolet laser

    DOEpatents

    Berkowitz, Joseph; Ruscic, Branko M.; Greene, John P.

    1986-01-01

    Transitions from the 2p.sup.4 (.sup.1 S.sub.0)3s .sup.2 S.sub.1/2 state of atomic fluorine to all allowed lower states produces laser emission at six new wavelengths: 680.7 .ANG., 682.6 .ANG., 3592.7 .ANG., 3574.1 .ANG., 6089.2 .ANG., and 6046.8 .ANG.. Coherent radiation at these new wavelengths can be generated in an atomic fluorine laser operated as an amplifier or as an oscillator.

  5. Vacuum ultraviolet laser

    DOEpatents

    Berkowitz, J.; Ruscic, B.M.; Greene, J.P.

    1984-07-06

    Transitions from the 2p/sup 4/(/sup 1/S/sub 0/)3s /sup 2/S/sub 1/2/ state of atomic fluorine to all allowed loser states produces laser emission at six new wavelengths: 680.7A, 682.6A, 3592.7A, 3574.1A, 6089.2A, and 6046.8A. Coherent radiation at these new wavelengths can be generated in an atomic fluorine laser operated as an amplifier or as an oscillator.

  6. Ultraviolet lasers. Citations from the International Aerospace Abstracts data base

    NASA Technical Reports Server (NTRS)

    Mauk, S. C.

    1980-01-01

    Reports cited from the international literature describe various aspects of ultraviolet lasers including laser output, far ultraviolet radiation, electron pumping, optical pumping, and laser materials. Gas lasers, pulsed lasers, dye lasers, CO2 lasers, xenon fluoride lasers, and transversely excited atmospheric (TEA) lasers are considered. This updated bibliography contains 283 citations, 66 of which are new additions to the previous edition.

  7. Near-ultraviolet laser diodes for brilliant ultraviolet fluorophore excitation.

    PubMed

    Telford, William G

    2015-12-01

    Although multiple lasers are now standard equipment on most modern flow cytometers, ultraviolet (UV) lasers (325-365 nm) remain an uncommon excitation source for cytometry. Nd:YVO4 frequency-tripled diode pumped solid-state lasers emitting at 355 nm are now the primary means of providing UV excitation on multilaser flow cytometers. Although a number of UV excited fluorochromes are available for flow cytometry, the cost of solid-state UV lasers remains prohibitively high, limiting their use to all but the most sophisticated multilaser instruments. The recent introduction of the brilliant ultraviolet (BUV) series of fluorochromes for cell surface marker detection and their importance in increasing the number of simultaneous parameters for high-dimensional analysis has increased the urgency of including UV sources in cytometer designs; however, these lasers remain expensive. Near-UV laser diodes (NUVLDs), a direct diode laser source emitting in the 370-380 nm range, have been previously validated for flow cytometric analysis of most UV-excited probes, including quantum nanocrystals, the Hoechst dyes, and 4',6-diamidino-2-phenylindole. However, they remain a little-used laser source for cytometry, despite their significantly lower cost. In this study, the ability of NUVLDs to excite the BUV dyes was assessed, along with their compatibility with simultaneous brilliant violet (BV) labeling. A NUVLD emitting at 375 nm was found to excite most of the available BUV dyes at least as well as a UV 355 nm source. This slightly longer wavelength did produce some unwanted excitation of BV dyes, but at sufficiently low levels to require minimal additional compensation. NUVLDs are compact, relatively inexpensive lasers that have higher power levels than the newest generation of small 355 nm lasers. They can, therefore, make a useful, cost-effective substitute for traditional UV lasers in multicolor analysis involving the BUV and BV dyes.

  8. Ultraviolet laser beam monitor using radiation responsive crystals

    DOEpatents

    McCann, Michael P.; Chen, Chung H.

    1988-01-01

    An apparatus and method for monitoring an ultraviolet laser beam includes disposing in the path of an ultraviolet laser beam a substantially transparent crystal that will produce a color pattern in response to ultraviolet radiation. The crystal is exposed to the ultraviolet laser beam and a color pattern is produced within the crystal corresponding to the laser beam intensity distribution therein. The crystal is then exposed to visible light, and the color pattern is observed by means of the visible light to determine the characteristics of the laser beam that passed through crystal. In this manner, a perpendicular cross sectional intensity profile and a longitudinal intensity profile of the ultraviolet laser beam may be determined. The observation of the color pattern may be made with forward or back scattered light and may be made with the naked eye or with optical systems such as microscopes and television cameras.

  9. Laser zona dissection using short-pulse ultraviolet lasers

    NASA Astrophysics Data System (ADS)

    Neev, Joseph; Tadir, Yona; Ho, Peter D.; Whalen, William E.; Asch, Richardo H.; Ord, Teri; Berns, Michael W.

    1992-06-01

    The interaction of pulsed ultraviolet radiation with the zona pellucida of human oocytes which had failed to fertilize in standard IVF cycles, was investigated. Two lasers were studied: a 100 ps pulsed Nd:YAG with a nonlinear crystal emitting light at 266 nm, and a 15 ns XeCl excimer laser with 308 nm radiation. Incisions in the zona were made by aiming the beam tangentially to the oocyte. The results indicate superior, high precision performance by the excimer laser creating trenches as narrow as 1 micrometers and as shallow as 1 micrometers . The incision size was found to be sensitive to the laser's energy and to the position of the microscope's objective focal plane, but relatively insensitive to the laser pulse repetition rate. Once the minimum spot size was defined by the system parameters, the laser beam was used to curve out any desired zona shape. This laser microsurgery technique as applied to partial zone dissection or zona drilling could prove very useful as a high-precision, non-contact method for treatments of low fertilization rate and for enhancing embryo implantation rates in patients undergoing IVF treatments.

  10. Tunable ultraviolet laser source from a frequency doubled Alexandrite laser

    NASA Astrophysics Data System (ADS)

    Liu, Shuhang; Liu, Jingjiao; Wang, Lijun

    2007-11-01

    A tunable ultraviolet laser source in the spectrum range of 0.36-0.388 μm was obtained as second harmonics from a frequency doubled Alexandrite laser whose output covers the wave range over 0.72-0.78 μm. A LBO crystal was used as frequency doubling crystal. The phase mateching angle in the wide spectrum range of the crystal was calculated, and the crystal was cut in the way that the normal incidence at the center wavelength of the fundamental wave at the crystal. The output spectrum line was measured and the highest second harmonics conversion efficiency reached 1.2% from long pulse fundamental wave at the center wavelength.

  11. Mid-ultraviolet pulsed laser micromachining of SiC

    NASA Astrophysics Data System (ADS)

    Qi, Litao; Li, Mingxing; Lin, Haipeng; Hu, Jinping; Tang, Qingju; Liu, Chunsheng

    2014-11-01

    This paper provides an investigation of the ablation behavior of single crystal 4H-SiC and 6H-SiC wafer to improve the manufacturability and high-temperature performance of SiC using laser applications. 266nm pulsed laser micromachining of SiC was investigated. The purpose is to establish suitable laser parametric regime for the fabrication of high accuracy, high spatial resolution and thin diaphragms for high-temperature MEMS pressure sensor applications. Etch rate, ablation threshold and quality of micromachined features were evaluated. The governing ablation mechanisms, such as thermal vaporization, phase explosion, and photomechanical fragmentation, were correlated with the effects of pulse energy. The ablation threshold is obtained with ultraviolet pulsed laser ablation. The results suggested ultraviolet pulsed laser's potential for rapid manufacturing. Excellent quality of machined features with little collateral thermal damage was obtained in the lower pulse energy range. The leading material removal mechanisms under these conditions were discussed.

  12. High intensity vacuum ultraviolet and extreme ultraviolet production by noncollinear mixing in laser vaporized media

    NASA Astrophysics Data System (ADS)

    Todt, Michael A.; Albert, Daniel R.; Davis, H. Floyd

    2016-06-01

    A method is described for generating intense pulsed vacuum ultraviolet (VUV) and extreme ultraviolet (XUV) laser radiation by resonance enhanced four-wave mixing of commercial pulsed nanosecond lasers in laser vaporized mercury under windowless conditions. By employing noncollinear mixing of the input beams, the need of dispersive elements such as gratings for separating the VUV/XUV from the residual UV and visible beams is eliminated. A number of schemes are described, facilitating access to the 9.9-14.6 eV range. A simple and convenient scheme for generating wavelengths of 125 nm, 112 nm, and 104 nm (10 eV, 11 eV, and 12 eV) using two dye lasers without the need for dye changes is described.

  13. High intensity vacuum ultraviolet and extreme ultraviolet production by noncollinear mixing in laser vaporized media.

    PubMed

    Todt, Michael A; Albert, Daniel R; Davis, H Floyd

    2016-06-01

    A method is described for generating intense pulsed vacuum ultraviolet (VUV) and extreme ultraviolet (XUV) laser radiation by resonance enhanced four-wave mixing of commercial pulsed nanosecond lasers in laser vaporized mercury under windowless conditions. By employing noncollinear mixing of the input beams, the need of dispersive elements such as gratings for separating the VUV/XUV from the residual UV and visible beams is eliminated. A number of schemes are described, facilitating access to the 9.9-14.6 eV range. A simple and convenient scheme for generating wavelengths of 125 nm, 112 nm, and 104 nm (10 eV, 11 eV, and 12 eV) using two dye lasers without the need for dye changes is described.

  14. Ultraviolet 320 nm laser excitation for flow cytometry.

    PubMed

    Telford, William; Stickland, Lynn; Koschorreck, Marco

    2017-02-27

    Although multiple lasers and high-dimensional analysis capability are now standard on advanced flow cytometers, ultraviolet (UV) lasers (usually 325-365 nm) remain an uncommon excitation source for cytometry. This is primarily due to their cost, and the small number of applications that require this wavelength. The development of the Brilliant Ultraviolet (BUV fluorochromes, however, has increased the importance of this formerly niche excitation wavelength. Historically, UV excitation was usually provided by water-cooled argon- and krypton-ion lasers. Modern flow cytometers primary rely on diode pumped solid state lasers emitting at 355 nm. While useful for all UV-excited applications, DPSS UV lasers are still large by modern solid state laser standards, and remain very expensive. Smaller and cheaper near UV laser diodes (NUVLDs) emitting at 375 nm make adequate substitutes for 355 nm sources in many situations, but do not work as well with very short wavelength probes like the fluorescent calcium chelator indo-1. In this study, we evaluate a newly available UV 320 nm laser for flow cytometry. While shorter in wavelength that conventional UV lasers, 320 is close to the 325 nm helium-cadmium wavelength used in the past on early benchtop cytometers. A UV 320 nm laser was found to excite almost all Brilliant Ultraviolet dyes to nearly the same level as 355 nm sources. Both 320 nm and 355 nm sources worked equally well for Hoechst and DyeCycle Violet side population analysis of stem cells in mouse hematopoetic tissue. The shorter wavelength UV source also showed excellent excitation of indo-1, a probe that is not compatible with NUVLD 375 nm sources. In summary, a 320 nm laser module made a suitable substitute for conventional 355 nm sources. This laser technology is available in a smaller form factor than current 355 nm units, making it useful for small cytometers with space constraints. © 2017 International Society for Advancement of Cytometry.

  15. Ultraviolet laser deposition of graphene thin films without catalytic layers

    NASA Astrophysics Data System (ADS)

    Sarath Kumar, S. R.; Alshareef, H. N.

    2013-01-01

    In this letter, the formation of nanostructured graphene by ultraviolet laser ablation of a highly ordered pyrolytic graphite target under optimized conditions is demonstrated, without a catalytic layer, and a model for the growth process is proposed. Previously, graphene film deposition by low-energy laser (2.3 eV) was explained by photo-thermal models, which implied that graphene films cannot be deposited by laser energies higher than the C-C bond energy in highly ordered pyrolytic graphite (3.7 eV). Here, we show that nanostructured graphene films can in fact be deposited using ultraviolet laser (5 eV) directly over different substrates, without a catalytic layer. The formation of graphene is explained by bond-breaking assisted by photoelectronic excitation leading to formation of carbon clusters at the target and annealing out of defects at the substrate.

  16. Classifying the Basic Parameters of Ultraviolet Copper Bromide Laser

    NASA Astrophysics Data System (ADS)

    Gocheva-Ilieva, S. G.; Iliev, I. P.; Temelkov, K. A.; Vuchkov, N. K.; Sabotinov, N. V.

    2009-10-01

    The performance of deep ultraviolet copper bromide lasers is of great importance because of their applications in medicine, microbiology, high-precision processing of new materials, high-resolution laser lithography in microelectronics, high-density optical recording of information, laser-induced fluorescence in plasma and wide-gap semiconductors and more. In this paper we present a statistical study on the classification of 12 basic lasing parameters, by using different agglomerative methods of cluster analysis. The results are based on a big amount of experimental data for UV Cu+ Ne-CuBr laser with wavelengths 248.6 nm, 252.9 nm, 260.0 nm and 270.3 nm, obtained in Georgi Nadjakov Institute of Solid State Physics, Bulgarian Academy of Sciences. The relevant influence of parameters on laser generation is also evaluated. The results are applicable in computer modeling and planning the experiments and further laser development with improved output characteristics.

  17. Analysis of Ultraviolet and Visible Laser Effects

    DTIC Science & Technology

    1981-01-01

    Schriempf, J.T., Cronburg, T.L., Eninger , J.E., and Woodroffe, J.A., "Pulsed CO 2 Laser Interaction with a Metal Surface at Oblique Incidence," Appl...REFERENCES 1. McKay, J.A., Schriempf, J.T., Cronburg, T.L., Eninger , J.E., and Woodroffe, J.A., "Pulsed CO2 Laser Interaction with a Metal Surface at...McKay, J.A., Schriempf, J.T., Cronburg, T.L., Eninger , J.E., and Woodroffe, J.A., Appi. Phys. Lett. 36, 125 (1980). 2. Jacob, J.H., Hsia, J.C., Mangano

  18. Deep ultraviolet laser micromachining of novel fibre optic devices

    NASA Astrophysics Data System (ADS)

    Li, J.; Dou, J.; Herman, P. R.; Fricke-Begemann, T.; Ihlemann, J.; Marowsky, G.

    2007-04-01

    A deep ultraviolet F2 laser, with output at 157-nm wavelength, has been adopted for micro-shaping the end facets of single and multi-mode silica optical fibres. The high energy 7.9-eV photons drive strong interactions in the wide-bandgap silica fibres to enable the fabrication of surface-relief microstructures with high spatial resolution and smooth surface morphology. Diffraction gratings, focusing lenses, and Mach-Zehnder interferometric structures have been micromachined onto the cleaved-fibre facets and optically characterized. F2-laser micromachining is shown to be a rapid and facile means for direct-writing of novel infibre photonic components.

  19. Ultraviolet Laser-induced ignition of RDX single crystal

    PubMed Central

    Yan, Zhonghua; Zhang, Chuanchao; Liu, Wei; Li, Jinshan; Huang, Ming; Wang, Xuming; Zhou, Guorui; Tan, Bisheng; Yang, Zongwei; Li, Zhijie; Li, Li; Yan, Hongwei; Yuan, Xiaodong; Zu, Xiaotao

    2016-01-01

    The RDX single crystals are ignited by ultraviolet laser (355 nm, 6.4 ns) pulses. The laser-induced damage morphology consisted of two distinct regions: a core region of layered fracture and a peripheral region of stripped material surrounding the core. As laser fluence increases, the area of the whole crack region increases all the way, while both the area and depth of the core region increase firstly, and then stay stable over the laser fluence of 12 J/cm2. The experimental details indicate the dynamics during laser ignition process. Plasma fireball of high temperature and pressure occurs firstly, followed by the micro-explosions on the (210) surface, and finally shock waves propagate through the materials to further strip materials outside and yield in-depth cracks in larger surrounding region. The plasma fireball evolves from isotropic to anisotropic under higher laser fluence resulting in the damage expansion only in lateral direction while maintaining the fixed depth. The primary insights into the interaction dynamics between laser and energetic materials can help developing the superior laser ignition technique. PMID:26847854

  20. Palomar Ultraviolet Laser for the Study of Exoplanets

    NASA Astrophysics Data System (ADS)

    Baranec, C.; Dekany, R.; van Dam, M.; Burruss, R.

    2013-09-01

    PULSE is a new concept to augment the currently operating 5.1-m Hale PALM-3000 exoplanet adaptive optics system with an ultraviolet Rayleigh laser and associated wavefront sensor. By using an ultraviolet laser to measure the high spatial and temporal order turbulence near the telescope aperture, where it dominates, one can extend the faintness limit of natural guide stars needed by PALM-3000. Initial simulations indicate that very-high infrared contrast ratios and good visible-light adaptive optics performance will be achieved by such an upgraded system on stars as faint as mV = 16-17 using an optimized low-order NGS sensor. This will enable direct imaging searches for, and subsequent characterization of, companions around cool, low-mass stars for the first time, as well as routine visible-light imaging twice as sharp as HST for fainter targets. PULSE will reuse the laser and wavefront sensor technology developed for the automated Robo-AO laser system currently operating at the Palomar 60-inch telescope, as well as take advantage of pending optimization of low-order NGS wavefront sensing and planned new interfaces to the PALM-3000 real-time reconstruction computer. A copy of the Robo-AO laser will be installed in the prime focus cage of the 5.1-m, and a new ultraviolet high-order wavefront sensor, fed by an ultraviolet dichroic, will be installed in the space above the PALM-3000 optical bench near the calibration sources. The laser measurements will drive the 3,388 active element high-order deformable mirror in open-loop, while an adaptive optics sharpened faint natural source will be measured by the current PALM-3000 wavefront sensor in its lowest spatial sampling mode, with commands sent in closed-loop to the 241 active element low-order deformable mirror. The natural guide star loop corrects for both the relatively weak low-order high-altitude turbulence as well as functioning as both the tip-tilt and low-bandwidth `truth' sensor loops in a traditional laser

  1. Multifunctional optical correlator for picosecond ultraviolet laser pulse measurement

    DOE PAGES

    Rakhman, Abdurahim; Wang, Yang; Garcia, Frances; ...

    2014-01-01

    A compact optical correlator system that measures both the autocorrelation between two infrared (IR) lights and the cross-correlation between an IR and an ultraviolet (UV) light using a single nonlinear optical crystal has been designed and experimentally demonstrated. The rapid scanning of optical delay line, switching between auto and cross-correlations, crystal angle tuning, and data acquisition and processing are all computer controlled. Pulse widths of an IR light from a mode-locked laser are measured by the correlator and the results are compared with a direct measurement using a high-speed photodetector system. The correlator has been used to study the parametermore » dependence of the pulse width of a macropulse UV laser designed for laser-assisted hydrogen ion (H-) beam stripping for the Spallation Neutron Source at Oak Ridge National Laboratory.« less

  2. Multifunctional optical correlator for picosecond ultraviolet laser pulse measurement

    SciTech Connect

    Rakhman, Abdurahim; Wang, Yang; Garcia, Frances; Long, Cary D.; Huang, Chunning; Takeda, Yasuhiro; Liu, Yun

    2014-01-01

    A compact optical correlator system that measures both the autocorrelation between two infrared (IR) lights and the cross-correlation between an IR and an ultraviolet (UV) light using a single nonlinear optical crystal has been designed and experimentally demonstrated. The rapid scanning of optical delay line, switching between auto and cross-correlations, crystal angle tuning, and data acquisition and processing are all computer controlled. Pulse widths of an IR light from a mode-locked laser are measured by the correlator and the results are compared with a direct measurement using a high-speed photodetector system. The correlator has been used to study the parameter dependence of the pulse width of a macropulse UV laser designed for laser-assisted hydrogen ion (H-) beam stripping for the Spallation Neutron Source at Oak Ridge National Laboratory.

  3. Analysis of fabric materials cut using ultraviolet laser ablation

    NASA Astrophysics Data System (ADS)

    Tsai, Hsin-Yi; Yang, Chih-Chung; Hsiao, Wen-Tse; Huang, Kuo-Cheng; Andrew Yeh, J.

    2016-04-01

    Laser ablation technology has widely been applied in the clothing industry in recent years. However, the laser mechanism would affect the quality of fabric contours and its components. Hence, this study examined carbonization and oxidation conditions and contour variation in nonwoven, cotton, and composite leather fabrics cut by using an ultraviolet laser at a wavelength of 355 nm. Processing parameters such as laser power, pulse frequency, scanning speed, and number of pulses per spot were adjusted to investigate component variation of the materials and to determine suitable cutting parameters for the fabrics. The experimental results showed that the weights of the component changed substantially by pulse frequency but slightly by laser power, so pulse frequency of 100 kHz and laser power of 14 W were the approximate parameters for three fabrics for the smaller carbonization and a sufficient energy for rapidly cutting, which the pulse duration of laser system was fixed at 300 μs and laser irradiance was 0.98 J/mm2 simultaneously. In addition, the etiolate phenomenon of nonwoven was reduced, and the component weight of cotton and composite leather was closed to the value of knife-cut fabric as the scanning speed increased. The approximate scanning speed for nonwoven and composite leather was 200 mm/s, and one for cotton was 150 mm/s, respectively. The sharper and firmer edge is obtained by laser ablation mechanism in comparison with traditional knife cutting. Experimental results can serve as the reference for laser cutting in the clothing industry, for rapidly providing smoother patterns with lower carbonization and oxidation edge in the fashion industry.

  4. Deep ultraviolet light-emitting and laser diodes

    NASA Astrophysics Data System (ADS)

    Khan, Asif; Asif, Fatima; Muhtadi, Sakib

    2016-02-01

    Nearly all the air-water purification/polymer curing systems and bio-medical instruments require 250-300 nm wavelength ultraviolet light for which mercury lamps are primarily used. As a potential replacement for these hazardous mercury lamps, several global research teams are developing AlGaN based Deep Ultraviolet (DUV) light emitting diodes (LEDs) and DUV LED Lamps and Laser Diodes over Sapphire and AlN substrates. In this paper, we review the current research focus and the latest device results. In addition to the current results we also discuss a new quasipseudomorphic device design approach. This approach which is much easier to integrate in a commercial production setting was successfully used to demonstrate UVC devices on Sapphire substrates with performance levels equal to or better than the conventional relaxed device designs.

  5. High power, short pulses ultraviolet laser for the development of a new x-ray laser

    SciTech Connect

    Meixler, L.; Nam, C.H.; Robinson, J.; Tighe, W.; Krushelnick, K.; Suckewer, S.; Goldhar, J.; Seely, J.; Feldman, U.

    1989-04-01

    A high power, short pulse ultraviolet laser system (Powerful Picosecond-Laser) has been developed at the Princeton Plasma Physics Laboratory (PPPL) as part of experiments designed to generate shorter wavelength x-ray lasers. With the addition of pulse compression and a final KrF amplifier the laser output is expected to have reached 1/3-1/2 TW (10/sup 12/ watts) levels. The laser system, particularly the final amplifier, is described along with some initial soft x-ray spectra from laser-target experiments. The front end of the PP-Laser provides an output of 20--30 GW (10/sup 9/ watts) and can be focussed to intensities of /approximately/10/sup 16/ W/cm/sup 2/. Experiments using this output to examine the effects of a prepulse on laser-target interaction are described. 19 refs., 14 figs.

  6. Injection locking of a high power ultraviolet laser diode for laser cooling of ytterbium atoms

    SciTech Connect

    Hosoya, Toshiyuki; Miranda, Martin; Inoue, Ryotaro; Kozuma, Mikio

    2015-07-15

    We developed a high-power laser system at a wavelength of 399 nm for laser cooling of ytterbium atoms with ultraviolet laser diodes. The system is composed of an external cavity laser diode providing frequency stabilized output at a power of 40 mW and another laser diode for amplifying the laser power up to 220 mW by injection locking. The systematic method for optimization of our injection locking can also be applied to high power light sources at any other wavelengths. Our system does not depend on complex nonlinear frequency-doubling and can be made compact, which will be useful for providing light sources for laser cooling experiments including transportable optical lattice clocks.

  7. Far-ultraviolet laser ablation of the cornea: photoacoustic studies

    SciTech Connect

    Srinivasan, R.; Dyer, P.E.; Braren, B.

    1987-01-01

    Wide bandwidth piezoelectric transducers made of thin (9 microns) polyvinylidene fluoride film have been used to make time-resolved measurements of the stress-wave generated by far-ultraviolet (193 nm) laser ablation in corneal tissue in vitro. At high fluence (approximately 250 mJ/cm2), ablation commences within 10 ns (+/- 5 ns) of the laser pulse and generates short acoustic impulses (approximately 30 ns). The time profile of the ablation, when coupled to the energy requirements for ablation from earlier work, allows the estimation of a temperature and a half-life for the thermal decomposition of the collagen in cornea. These values do not support a photothermal mechanism for the ablation under the experimental conditions.

  8. Laser plasma formation assisted by ultraviolet pre-ionization

    SciTech Connect

    Yalin, Azer P. Dumitrache, Ciprian; Wilvert, Nick; Joshi, Sachin; Shneider, Mikhail N.

    2014-10-15

    We present experimental and modeling studies of air pre-ionization using ultraviolet (UV) laser pulses and its effect on laser breakdown of an overlapped near-infrared (NIR) pulse. Experimental studies are conducted with a 266 nm beam (fourth harmonic of Nd:YAG) for UV pre-ionization and an overlapped 1064 nm NIR beam (fundamental of Nd:YAG), both having pulse duration of ∼10 ns. Results show that the UV beam produces a pre-ionized volume which assists in breakdown of the NIR beam, leading to reduction in NIR breakdown threshold by factor of >2. Numerical modeling is performed to examine the ionization and breakdown of both beams. The modeled breakdown threshold of the NIR, including assist by pre-ionization, is in reasonable agreement with the experimental results.

  9. PULSE: the Palomar Ultraviolet Laser for the Study of Exoplanets

    NASA Astrophysics Data System (ADS)

    Bottom, Michael; Dekany, R.; Bowler, B. P.; Baranec, C.; Burruss, R.

    2014-01-01

    PULSE is a project to augment the currently operating 5.1-m Hale PALM-3000 exoplanet adaptive optics system with an ultraviolet Rayleigh laser and associated wavefront sensor. By using a bright (U ~ 7) ultraviolet laser to measure the high spatial and temporal order turbulence near the telescope aperture, where it dominates, one can extend the faintness limit of natural guide stars needed by PALM-3000. Initial simulations indicate that very-high infrared contrast ratios and good visible-light adaptive optics performance will be achieved by such an upgraded system on stars as faint as mV = 16-17 using an optimized low-order NGS sensor. This will enable direct imaging searches for, and subsequent characterization of, companions around cool, low-mass stars for the first time, as well as routine visible-light imaging twice as sharp as HST for fainter targets. PULSE will reuse the laser and wavefront sensor technology developed for the automated Robo-AO laser system currently operating at the Palomar 60-inch telescope, as well as take advantage of pending optimization of low-order NGS wavefront sensing and planned new interfaces to the PALM-3000 real-time reconstruction computer. PULSE will dramatically extend the AO sky coverage of the telescope from 1% to 50%. More specifically, this will boost the yield from a number of operational exoplanet instruments at Palomar including PHARO, a NIR imager, spectrograph, and coronagraph; a fiber nulling interferometer; and Project 1640, a coronagraph and IFS. Two additional funded instruments expected to benefit from PULSE in the coming years are the SDC; a NIR/visible self-calibrating vector vortex coronagraph, and DARKNESS; an energy-resolving, photon counting MKIDS camera.

  10. Ultraviolet Free Electron Laser Facility preliminary design report

    SciTech Connect

    Ben-Zvi, I.

    1993-02-01

    This document, the Preliminary Design Report (PDR) for the Brookhaven Ultraviolet Free Electron Laser (UV FEL) facility, describes all the elements of a facility proposed to meet the needs of a research community which requires ultraviolet sources not currently available as laboratory based lasers. Further, for these experiments, the requisite properties are not extant in either the existing second or upcoming third generation synchrotron light sources. This document is the result of our effort at BNL to identify potential users, determine the requirements of their experiments, and to design a facility which can not only satisfy the existing need, but have adequate flexibility for possible future extensions as need dictates and as evolving technology allows. The PDR is comprised of three volumes. In this, the first volume, background for the development of the proposal is given, including descriptions of the UV FEL facility, and representative examples of the science it was designed to perform. Discussion of the limitations and potential directions for growth are also included. A detailed description of the facility design is then provided, which addresses the accelerator, optical, and experimental systems. Information regarding the conventional construction for the facility is contained in an addendum to volume one (IA).

  11. Method and apparatus for producing durationally short ultraviolet or X-ray laser pulses

    DOEpatents

    MacGowan, Brian J.; Matthews, Dennis L.; Trebes, James E.

    1988-01-01

    A method and apparatus is disclosed for producing ultraviolet or X-ray laser pulses of short duration (32). An ultraviolet or X-ray laser pulse of long duration (12) is progressively refracted, across the surface of an opaque barrier (28), by a streaming plasma (22) that is produced by illuminating a solid target (16, 18) with a pulse of conventional line focused high power laser radiation (20). The short pulse of ultraviolet or X-ray laser radiation (32), which may be amplified to high power (40, 42), is separated out by passage through a slit aperture (30) in the opaque barrier (28).

  12. Method and apparatus for producing durationally short ultraviolet or x-ray laser pulses

    DOEpatents

    MacGowan, B.J.; Matthews, D.L.; Trebes, J.E.

    1987-05-05

    A method and apparatus is disclosed for producing ultraviolet or x- ray laser pulses of short duration. An ultraviolet or x-ray laser pulse of long duration is progressively refracted, across the surface of an opaque barrier, by a streaming plasma that is produced by illuminating a solid target with a pulse of conventional line focused high power laser radiation. The short pulse of ultraviolet or x-ray laser radiation, which may be amplified to high power, is separated out by passage through a slit aperture in the opaque barrier.

  13. Xe capillary target for laser-plasma extreme ultraviolet source

    SciTech Connect

    Inoue, Takahiro; Okino, Hideyasu; Nica, Petru Edward; Amano, Sho; Miyamoto, Shuji; Mochizuki, Takayasu

    2007-10-15

    A cryogenic Xe jet system with an annular nozzle has been developed in order to continuously fast supply a Xe capillary target for generating a laser-plasma extreme ultraviolet (EUV) source. The cooling power of the system was evaluated to be 54 W, and the temperature stability was {+-}0.5 K at a cooling temperature of about 180 K. We investigated experimentally the influence of pressure loss inside an annular nozzle on target formation by shortening the nozzle length. Spraying caused by cavitation was mostly suppressed by mitigating the pressure loss, and a focused jet was formed. Around a liquid-solid boundary, a solid-Xe capillary target (100/70 {mu}m {phi}) was formed with a velocity of {<=}0.01 m/s. Laser-plasma EUV generation was tested by focusing a Nd:YAG laser beam on the target. The results suggested that an even thinner-walled capillary target is required to realize the inertial confinement effect.

  14. Colliding laser-produced plasmas as targets for laser-generated extreme ultraviolet sources

    SciTech Connect

    Cummins, T.; O'Gorman, C.; Dunne, P.; Sokell, E.; O'Sullivan, G.; Hayden, P.

    2014-07-28

    Colliding plasmas produced by neodymium-doped yttrium aluminium garnet (Nd:YAG) laser illumination of tin wedge targets form stagnation layers, the physical parameters of which can be controlled to optimise coupling with a carbon dioxide (CO{sub 2}) heating laser pulse and subsequent extreme ultraviolet (EUV) production. The conversion efficiency (CE) of total laser energy into EUV emission at 13.5 nm ± 1% was 3.6%. Neglecting both the energy required to form the stagnation layer and the EUV light produced before the CO{sub 2} laser pulse is incident results in a CE of 5.1% of the CO{sub 2} laser energy into EUV light.

  15. Multifunctional optical correlator for picosecond ultraviolet laser pulse measurement.

    PubMed

    Rakhman, Abdurahim; Wang, Yang; Garcia, Frances; Long, Cary; Huang, Chunning; Takeda, Yasuhiro; Liu, Yun

    2014-11-01

    A compact multifunctional optical correlator system for pulse width measurement of ultrashort ultraviolet (UV) pulses has been designed and experimentally demonstrated. Both autocorrelation and cross-correlation functions are measured using a single nonlinear crystal, and the switching between two measurements requires no adjustment of phase matching and detector. The system can measure UV pulse widths from sub-picoseconds to 100 ps, and it involves no auxiliary pulse in the measurement. The measurement results on a burst-mode picosecond UV laser show a high-quality performance on speed, accuracy, resolution, and dynamic range. The proposed correlator can be applied to measure any ultrashort UV pulses produced through sum-frequency generation or second-harmonic generation.

  16. Study on the Pr:KYF ultraviolet laser at 305 nm pumped by blue laser

    NASA Astrophysics Data System (ADS)

    Ni, Tian-yi; Li, Yong-liang; Zhang, Tian-yi; Ruan, Ren-qiu

    2012-09-01

    An all-solid-state Pr:KY3F10 (Pr:KYF) laser pumped by blue laser (471 nm) has been demonstrated. With the incident pump power of 2.6 W, the maximum output power at 610 nm is 213 mW. Moreover, the intracavity second-harmonic generation (SHG) is also achieved with the maximum ultraviolet (UV) power at 305 nm of 11 mW by using a β-BaB2O4 (BBO) nonlinear crystal.

  17. High-energy, efficient, 30-Hz ultraviolet laser sources for airborne ozone-lidar systems.

    PubMed

    Elsayed, Khaled A; Chen, Songsheng; Petway, Larry B; Meadows, Byron L; Marsh, Waverly D; Edwards, William C; Barnes, James C; DeYoung, Russell J

    2002-05-20

    Two compact, high-pulse-energy, injection-seeded, 30-Hz frequency-doubled Nd:YAG-laser-pumped Ti: sapphire lasers were developed and operated at infrared wavelengths of 867 and 900 nm. Beams with laser pulse energy >30 mJ at ultraviolet wavelengths of 289 and 300 nm were generated through a tripling of the frequencies of these Ti:sapphire lasers. This work is directed at the replacement of dye lasers for use in an airborne ozone differential absorption lidar system. The ultraviolet pulse energy at 289 and 300 nm had 27% and 31% absolute optical energy conversion efficiencies from input pulse energies at 867 and 900 nm, respectively.

  18. Laser-assisted vacuum arc extreme ultraviolet source: a comparison of picosecond and nanosecond laser triggering

    NASA Astrophysics Data System (ADS)

    Beyene, Girum A.; Tobin, Isaac; Juschkin, Larissa; Hayden, Patrick; O'Sullivan, Gerry; Sokell, Emma; Zakharov, Vassily S.; Zakharov, Sergey V.; O'Reilly, Fergal

    2016-06-01

    Extreme ultraviolet (EUV) light generation by hybrid laser-assisted vacuum arc discharge plasmas, utilizing Sn-coated rotating-disc-electrodes, was investigated. The discharge was initiated by localized ablation of the liquid tin coating of the cathode disc by a laser pulse. The laser pulse, at 1064 nm, was generated by Nd:YAG lasers with variable energy from 1 to 100 mJ per pulse. The impact of shortening the laser pulse from 7 ns to 170 ps on the EUV generation has been investigated in detail. The use of ps pulses resulted in an increase in emission of EUV radiation. With a fixed discharge energy of ~4 J, the EUV conversion efficiency tends to plateau at ~2.4  ±  0.25% for the ps laser pulses, while for the ns pulses, it saturates at ~1.7  ±  0.3%. Under similar discharge and laser energy conditions, operating the EUV source with the ps-triggering resulted also in narrower spectral profiles of the emission in comparison to ns-triggering. The results indicate an advantage in using ps-triggering in laser-assisted discharges to produce brighter plasmas required for applications such as metrology.

  19. Temperature measurement using ultraviolet laser absorption of carbon dioxide behind shock waves.

    PubMed

    Oehlschlaeger, Matthew A; Davidson, David F; Jeffries, Jay B

    2005-11-01

    A diagnostic for microsecond time-resolved temperature measurements behind shock waves, using ultraviolet laser absorption of vibrationally hot carbon dioxide, is demonstrated. Continuous-wave laser radiation at 244 and 266 nm was employed to probe the spectrally smooth CO2 ultraviolet absorption, and an absorbance ratio technique was used to determine temperature. Measurements behind shock waves in both nonreacting and reacting (ignition) systems were made, and comparisons with isentropic and constant-volume calculations are reported.

  20. Local ultraviolet laser irradiation for gradients on biocompatible polymer surfaces.

    PubMed

    Nottrodt, Nadine; Leonhäuser, Dorothea; Bongard, Yvonne; Bremus-Köbberling, Elke; Gillner, Arnold

    2014-04-01

    Generation of supporting structures, which guide cell growth, is a challenging task in the field of tissue engineering. Cell guidance properties of a scaffold are important in the field of neuronal regeneration. Those guiding structures can provide guidance just by mechanical stimulus or by chemical stimuli like cell signaling molecules. For an enhanced guidance, chemical gradients are under investigation. With this study, we show that ultraviolet laser irradiation is a useful tool to activate polymer surfaces with a high temporal and spatial resolution. We demonstrated that poly(methyl methacrylate) (PMMA) and poly-ε-caprolactone (PCL) can be locally activated and functionalized with amine groups that can be used for immobilization of arginine-glycine-aspartic acid (RGD) peptide. The immobilized RGD was detected by neuronal B35 cells. By defined pulse accumulation functionalization density on the surface can be varied for the generation of gradients. We demonstrated that PMMA and PCL have different process windows for functionalization. Although PMMA has a very small process window for activation, PCL allows the generation of stepwise functionalization. The presented technology can help to develop assays for the analysis of cell migration and neuronal regeneration due to flexible patterning easily realized by changing the irradiation parameters.

  1. Angular distribution of ions and extreme ultraviolet emission in laser-produced tin droplet plasma

    SciTech Connect

    Chen, Hong; Duan, Lian; Lan, Hui; Wang, Xinbing Chen, Ziqi; Zuo, Duluo; Lu, Peixiang

    2015-05-21

    Angular-resolved ion time-of-flight spectra as well as extreme ultraviolet radiation in laser-produced tin droplet plasma are investigated experimentally and theoretically. Tin droplets with a diameter of 150 μm are irradiated by a pulsed Nd:YAG laser. The ion time-of-flight spectra measured from the plasma formed by laser irradiation of the tin droplets are interpreted in terms of a theoretical elliptical Druyvesteyn distribution to deduce ion density distributions including kinetic temperatures of the plasma. The opacity of the plasma for extreme ultraviolet radiation is calculated based on the deduced ion densities and temperatures, and the angular distribution of extreme ultraviolet radiation is expressed as a function of the opacity using the Beer–Lambert law. Our results show that the calculated angular distribution of extreme ultraviolet radiation is in satisfactory agreement with the experimental data.

  2. Study on damage of K9 glass under 248nm ultraviolet pulsed laser irradiation

    NASA Astrophysics Data System (ADS)

    Wang, Xi; Fang, Xiaodong

    2015-04-01

    The damage of K9 glass under 248nm ultraviolet pulsed laser irradiation was studied. The laser pulse energy was kept within the range of 60mJ to 160mJ, and the repetition rate was adjusted within the range of 1Hz to 40Hz. The damage morphologies of single-pulse and multi-pulse laser irradiation were characterized by optical microscope, and the damage mechanism was discussed. The experimental results indicated that the damage of K9 glass irradiated by 248nm ultraviolet laser mainly followed the thermal-mechanical coupling mechanism and the damage threshold of K9 glass was 2.8J/cm2. The intensity of damage area increased gradually with the increase of the laser pulse number. It was shown that accumulation effect of laser induced damage to K9 glass was obvious.

  3. A long-term frequency stabilized deep ultraviolet laser for Mg+ ions trapping experiments

    NASA Astrophysics Data System (ADS)

    Zhang, J.; Yuan, W. H.; Deng, K.; Deng, A.; Xu, Z. T.; Qin, C. B.; Lu, Z. H.; Luo, J.

    2013-12-01

    As many precision laser spectroscopy experiments require frequency stabilized lasers, development of long-term stabilized lasers is of great interest. In this work, we report long-term frequency stabilization of a 280 nm deep ultraviolet laser to a high precision wavemeter with digital servo control such that the long-term drift of the laser frequency was greatly reduced. Long-term laser frequency drift was measured with a fiber frequency comb system over 8 h. After locking, the maximum drift rate of the 280 nm laser was lowered from 576 MHz/h to 6.4 MHz/h. With proper environment control of the wavemeter, the maximum drift rate of the 280 nm laser was further lowered to less than 480 kHz/h. The locked laser system was successfully used in a Mg+ ions trapping experiment, which was also discussed in this work.

  4. Measurement of temperature and density fluctuations in turbulence using an ultraviolet laser

    NASA Technical Reports Server (NTRS)

    Massey, G. A.

    1984-01-01

    Noninvasive measurement of density and temperature fluctuations in turbulent air flow was examined. The approach used fluorescence of oxygen molecules which are selectively excited by a tunable vacuum ultraviolet laser beam. The strength of the fluorescence signal and its dependence on laser wavelength vary with the density and temperature of the air in the laser beam. Because fluorescence can be detected at 90 degrees from the beam propagation direction, spatial resolution in three dimensions, rather than path-integrated measurements can be achieved. With spatial resolutions of the order of a millimeter and at supersonic air velocities it is necessary to perform each measurement in a time of the order of a microsecond; this is possible by by using laser pulses of ten nanosecond duration. In this method atmospheric O2 is excited by the emission of a tunable ArF excimer laser, and the fluorescence, which spans the 210 to 420 range, is detected by an ultraviolet phototube.

  5. Extreme ultraviolet source using a forced recombination process in lithium plasma generated by a pulsed laser

    SciTech Connect

    Nagano, Akihisa; Inoue, Takahiro; Nica, Petru-Edward; Amano, Sho; Miyamoto, Shuji; Mochizuki, Takayasu

    2007-04-09

    An extreme ultraviolet source having a tamper has been studied. This target scheme recombines forcedly lithium ions by low temperature electrons from the tamper, converting Li{sup 3+} rapidly to excited Li{sup 2+} which emit intense 1s-2p Lyman {alpha} emissions at 13.5 nm. A strong 13.5 nm emission appeared at 20-30 ns after the time of laser peak within a small space volume near the tamper. The authors obtained an enhancement of extreme ultraviolet conversion efficiency by a factor of about 2 with the tamper against that of a target without the tamper at the same laser irradiation condition00.

  6. Investigation of the ageing effects exhibited by AR coatings exposed to ultraviolet laser irradiation

    NASA Astrophysics Data System (ADS)

    Botha, Roelene; Bischof, David; Vetsch, Bernhard; Scherrer, Ueli; Michler, Markus; Rinner, Stefan J.; Ettemeyer, Andreas; Ziolek, Carsten

    2016-12-01

    Optical coatings used in ultraviolet applications are often exposed to harsh environments operating at elevated temperatures. In order to study the impact of the ageing effects optical coatings experience at various operating temperatures, an ultraviolet laser-induced degradation test system has been developed. It allows for flexible use in both a long-term stability test bench as well as in an LIDT measurement system. This work contains the preliminary results of optical degradation tests at 355 nm performed on anti-reflective coatings. As a subsequent step, the LIDT of the samples were measured using a Q-Switched Nd:YAG laser operating at 1064nm.

  7. Tunable ultraviolet co-doped dye laser of Pyrromethene 597 and Rhodamine 610

    NASA Astrophysics Data System (ADS)

    Lu, Zhenzhong; Sun, Yanling; Ma, Lin; Liu, Jifang

    2015-12-01

    The laser performance of Pyrromethene 597 (PM597) and Rhodamine 610 mixture is studied. A wide tuning range from 580 to 655 nm is achieved. The laser linewidth obtained is less than 0.1 nm. The highest conversion efficiency of 42.5% is obtained at 600 nm. Using a beta-BaB2O4 (BBO) crystal to frequency double the dye laser into ultraviolet (UV), a tuning range from 296 to 324 nm is obtained. The peak conversion efficiency from the dye laser to the UV laser is 9.7% and the highest UV laser output energy is 9.51 mJ at 301.25 nm. To the best of our knowledge, the tuning range and the conversion efficiency are the best under the same condition so far. All our results indicate that high laser performance can be achieved using a laser dyes’ mixture.

  8. Ordered many-electron motions in atoms and x-ray lasers. [Subpicosecond ultraviolet laser radiation

    SciTech Connect

    Rhodes, C.K.

    1986-01-01

    Subpicosecond ultraviolet laser technology is enabling the exploration of nonlinear atomic interactions with electric field strengths considerably in excess of an atomic unit. As this regime is approached, experiments studying multiple ionization, photoelectron energy spectra, and harmonically produced radiation all exhibit strong nonlinear coupling. Peak total energy transfer rates on the order of approx.2 x 10/sup -4/ W/atom have been observed at an intensity of approx.10/sup 16/ W/cm/sup 2/, and it is expected that energy transfer rates approaching approx.0.1 to 1 W/atom will occur under more extreme conditions for which the ultraviolet electric field E is significantly greater than e/a/sub 0//sup 2/. In this high intensity regime, a wide range of new nonlinear phenomena will be open to study. These will include the possibility of ordered driven motions in atoms, molecules, and plasmas, mechanisms involving collisions, and relativistic processes such as electron-positron pair production. An understanding of these physical interactions may provide a basis for the generation of stimulated emission in the x-ray range. 100 refs., 8 figs.

  9. Numerical simulation of temperature field in K9 glass irradiated by ultraviolet pulse laser

    NASA Astrophysics Data System (ADS)

    Wang, Xi; Fang, Xiaodong

    2015-10-01

    The optical component of photoelectric system was easy to be damaged by irradiation of high power pulse laser, so the effect of high power pulse laser irradiation on K9 glass was researched. A thermodynamic model of K9 glass irradiated by ultraviolet pulse laser was established using the finite element software ANSYS. The article analyzed some key problems in simulation process of ultraviolet pulse laser damage of K9 glass based on ANSYS from the finite element models foundation, meshing, loading of pulse laser, setting initial conditions and boundary conditions and setting the thermal physical parameters of material. The finite element method (FEM) model was established and a numerical analysis was performed to calculate temperature field in K9 glass irradiated by ultraviolet pulse laser. The simulation results showed that the temperature of irradiation area exceeded the melting point of K9 glass, while the incident laser energy was low. The thermal damage dominated in the damage mechanism of K9 glass, the melting phenomenon should be much more distinct.

  10. Coherent Extreme Ultraviolet Generation and Surface Studies Using Ultraviolet Excimer Lasers.

    DTIC Science & Technology

    1986-02-10

    are detected by a two-stage multi-channel plate detector, (MCP-Chevron type), which is connected to a transient digitizer (Tektronix 7912 AD). The...Supplement). 43. "Ultraviolet Excitation of Cryogenic Rare-Gas Chlorine Solutions ," H. Jara, M. Shahidi, H. Pummer, H. Egger, akd C. K. Rhodes, in...like core. In principle, these equations are nonlinear in the applied electromagnetic field. We observe that the incident electromagentic field has a

  11. A simplified scheme for generating narrow-band mid-ultraviolet laser radiation

    SciTech Connect

    Almog, G.; Scholz, M. Weber, W.; Leisching, P.; Kaenders, W.; Udem, Th.

    2015-03-15

    We report on the development and characterization of continuous, narrow-band, and tunable laser systems that use direct second-harmonic generation from blue and green diode lasers with an output power level of up to 11.1 mW in the mid-ultraviolet. One of our laser systems was tuned to the mercury 6{sup 1}S{sub 0} → 6{sup 3}P{sub 1} intercombination line at 253.7 nm. We could perform Doppler-free saturation spectroscopy on this line and were able to lock our laser to the transition frequency on long time scales.

  12. Absolute calibration of an ultraviolet spectrometer using a stabilized laser and a cryogenic cavity radiometer

    NASA Technical Reports Server (NTRS)

    Jauniskis, L.; Foukal, P.; Kochling, H.

    1992-01-01

    We carry out the calibration of an ultraviolet spectrometer by using a cryogenic electrical-substitution radiometer and intensity-stabilized laser sources. A comparison of the error budgets for the laser-based calibration described here and for a calibration using a type-FEL tungsten spectral-irradiance standard indicates that this technique could provide an improvement of a factor of about three in the uncertainty of the spectrometer calibration, resulting in an absolute accuracy (standard deviation of three) of about 1 percent at 257 nm. The technique described here might significantly improve the accuracy of calibrations on NASA ozone-monitoring and solar ultraviolet-monitoring spectrophotometers when used to complement present procedures that employ lamps and the SURF II synchrotron ultraviolet radiation facility at the National Institute of Standards and Technology.

  13. Absolute calibration of an ultraviolet spectrometer using a stabilized laser and a cryogenic cavity radiometer.

    PubMed

    Jauniskis, L; Foukal, P; Kochling, H

    1992-09-20

    We carry out the calibration of an ultraviolet spectrometer by using a cryogenic electrical-substitution radiometer and intensity-stabilized laser sources. A comparison of the error budgets for the laser-based calibration described here and for a calibration using a type-FEL tungsten spectral-irradiance standard indicates that this technique could provide an improvement of a factor of ~3 in the uncertainty of the spectrometer calibration, resulting in an absolute accuracy (standard deviation of 3) of ~1% at 257 nm. The technique described here might significantly improve the accuracy of calibrations on NASA ozone-monitoring and solar ultraviolet-monitoring spectrophotometers when used to complement present procedures that employ lamps and the SURF II synchrotron ultraviolet radiation facility at the National Institute of Standards and Technology.

  14. All-solid-state blue laser pumped Pr:KY3F10-BBO ultraviolet laser at 305 nm All-solid-state blue laser

    NASA Astrophysics Data System (ADS)

    Dong, Y.; Li, S. T.; Zhang, X. H.

    2012-02-01

    An all-solid-state blue laser pumped Pr:KY3F10 (Pr:KYF) laser at 610 nm has been demonstrated. With an incident pump power of 2.6 W, the maximum output power was 213 mW. Moreover, intracavity second-harmonic generation (SHG) has also been achieved with a maximum ultraviolet power of 11 mW by using a β-BaB2O4 (BBO) nonlinear crystal. To the best of our knowledge, this is the first report on continuous-wave ultraviolet generation by intracavity frequency doubling Pr:KYF laser.

  15. Comparing Vacuum and Extreme Ultraviolet Radiation for Postionization of Laser Desorbed Neutrals from Bacterial Biofilms and Organic Fullerene

    SciTech Connect

    Gaspera, Gerald L.; Takahashi, Lynelle K.; Zhou, Jia; Ahmed, Musahid; Moored, Jerry F.; Hanley, Luke

    2010-12-08

    Vacuum and extreme ultraviolet radiation from 8 - 24 eV generated at a synchrotron was used to postionize laser desorbed neutrals of antibiotic-treated biofilms and a modified fullerene using laser desorption postionization mass spectrometry (LDPI-MS). Results show detection of the parent ion, various fragments, and extracellular material from biofilms using LDPI-MS with both vacuum and extreme ultraviolet photons. Parent ions were observed for both cases, but extreme ultraviolet photons (16-24 eV) induced more fragmentation than vacuum ultraviolet (8-14 eV) photons.

  16. Integrated ultraviolet and tunable mid-infrared laser source for analyses of proteins

    NASA Astrophysics Data System (ADS)

    Hazama, Hisanao; Takatani, Yoshiaki; Awazu, Kunio

    2007-02-01

    Mass spectrometry using matrix-assisted laser desorption/ionization (MALDI) technique is one of the most widely used method to analyze proteins in biological research fields. However, it is difficult to analyze insoluble proteins which have important roles in researches on disease mechanisms or in developments of drugs by using ultraviolet (UV) lasers which have commonly been used for MALDI. Recently, a significant improvement in MALDI process of insoluble proteins using a combination of a UV nitrogen laser and a tunable mid-infrared (MIR) free electron laser (FEL) was reported. Since the FEL is a very large and expensive equipment, we have developed a tabletop laser source which can generate both UV and tunable MIR lasers. A tunable MIR laser (5.5-10 μm) was obtained by difference frequency generation (DFG) between a Nd:YAG and a tunable Cr:forsterite lasers using two AgGaS II crystals. The MIR laser can generate pulses with an energy of up to 1.4 mJ at a repetition rate of 10 Hz. A UV laser was obtained by third harmonic generation of a Nd:YAG laser splitted from that used for DFG. A time interval between the UV and the MIR laser pulses can be adjusted with a variable optical delay.

  17. Infrared and ultraviolet laser removal of crustose lichens on dolomite heritage stone

    NASA Astrophysics Data System (ADS)

    Sanz, Mikel; Oujja, Mohamed; Ascaso, Carmen; de los Ríos, Asunción; Pérez-Ortega, Sergio; Souza-Egipsy, Virginia; Wierzchos, Jacek; Speranza, Mariela; Cañamares, Maria Vega; Castillejo, Marta

    2015-08-01

    Laser removal of biodeteriogen layers warrants detailed studies due to the advantages it brings with respect to mechanical elimination or the use of biocides. We have investigated elimination of biological crusts on dolomite stones from heritage sites in central Spain. The samples were colonized by epilithic crustose lichens of different species, such as Caloplaca sp. and Verrucaria nigrescens. A comparative study was carried out by applying infrared (1064 nm) and ultraviolet (355 nm) nanosecond laser pulses and sequences pulses of the two wavelengths using a Q-switched Nd:YAG system. To detect anatomical and ultrastructural damage to the lichens, and to assess possible morphological and chemical changes on the underlying stone induced by laser irradiation, we used stereomicroscopy, scanning electron microscopy with backscattered electron imaging and Fourier transform Raman spectroscopy. The optimal conditions for removal of the colonization crust, while ensuring preservation of the lithic substrate, were obtained for dual infrared-ultraviolet sequential irradiation.

  18. Sub-surface channels in sapphire made by ultraviolet picosecond laser irradiation and selective etching.

    PubMed

    Moser, Rüdiger; Ojha, Nirdesh; Kunzer, Michael; Schwarz, Ulrich T

    2011-11-21

    We demonstrate the realization of sub-surface channels in sapphire prepared by ultraviolet picosecond laser irradiation and subsequent selective wet etching. By optimizing the pulse energy and the separation between individual laser pulses, an optimization of channel length can be achieved with an aspect ratio as high as 3200. Due to strong variation in channel length, further investigation was done to improve the reproducibility. By multiple irradiations the standard deviation of the channel length could be reduced to 2.2%. The achieved channel length together with the high reproducibility and the use of a commercial picosecond laser system makes the process attractive for industrial application.

  19. Heating dynamics and extreme ultraviolet radiation emission of laser-produced Sn plasmas

    SciTech Connect

    Yuspeh, S.; Sequoia, K. L.; Tao, Y.; Tillack, M. S.; Burdt, R. A.; Najmabadi, F.

    2010-06-28

    The impact of 1.064 mum laser absorption depth on the heating and in-band (2% bandwidth) 13.5 nm extreme ultraviolet emissions in Sn plasmas is investigated experimentally and numerically. In-band emission lasting longer than the laser pulse and separation between the laser absorption and in-band emission region are observed. Maximum efficiency is achieved by additional heating of the core of the plasma to allow the optimal temperature to expand to a lower and more optically thin density. This leads to higher temperature plasma that emits less in-band light as compared to CO{sub 2} produced plasma sources for the same application.

  20. Laser-based ultraviolet absorption detection in capillary electrophoresis

    SciTech Connect

    Xue, Y.; Yeung, E.S. )

    1994-04-01

    Laser-based UV absorption in capillary electrophoresis is demonstrated. The use of vacuum photodiodes and an all-electronic noise canceller provides adequate baseline stability despite the large inherent intensity noise in UV lasers. A 4-fold improvement in the detection limit is achieved in comparison to that of commercial instruments. The main advantage here is the better optical coupling with small capillary tubes, maximizing the available optical pathlength for absorption.

  1. Second Topical Meeting on Laser Techniques in the Extreme Ultraviolet.

    DTIC Science & Technology

    1985-01-10

    lasers. Cenfined Plasma Column, S. Suckewer, C. Keane, H. .-Milchborg, C. H. Skinner , and D. Voorhees, Plasma Physics-- 1&.30 AM COFFEE BREAK...and Cr) and carbon (2d = 150 ,) from 80 to 350 eV. Spectrometer configurations composed of variable-line-space IT. J. Watson Research Center, IBM...EUV Une I (Poster Paper) Intensities in Co,.-Laser-Produced Plasmas, C. H. Skinner , C. lent Generation of Tunable Radiation below 100 nm In Keane, H

  2. Large-solid-angle illuminators for extreme ultraviolet lithography with laser plasmas

    SciTech Connect

    Kubiak, G.D.; Tichenor, D.A.; Sweatt, W.C.; Chow, W.W.

    1995-06-01

    Laser Plasma Sources (LPSS) of extreme ultraviolet radiation are an attractive alternative to synchrotron radiation sources for extreme ultraviolet lithography (EUVL) due to their modularity, brightness, and modest size and cost. To fully exploit the extreme ultraviolet power emitted by such sources, it is necessary to capture the largest possible fraction of the source emission half-sphere while simultaneously optimizing the illumination stationarity and uniformity on the object mask. In this LDRD project, laser plasma source illumination systems for EUVL have been designed and then theoretically and experimentally characterized. Ellipsoidal condensers have been found to be simple yet extremely efficient condensers for small-field EUVL imaging systems. The effects of aberrations in such condensers on extreme ultraviolet (EUV) imaging have been studied with physical optics modeling. Lastly, the design of an efficient large-solid-angle condenser has been completed. It collects 50% of the available laser plasma source power at 14 nm and delivers it properly to the object mask in a wide-arc-field camera.

  3. Communication: vacuum ultraviolet laser photodissociation studies of small molecules by the vacuum ultraviolet laser photoionization time-sliced velocity-mapped ion imaging method.

    PubMed

    Pan, Yang; Gao, Hong; Yang, Lei; Zhou, Jingang; Ng, C Y; Jackson, William M

    2011-08-21

    We demonstrate that the vacuum ultraviolet (VUV) photodissociation dynamics of N(2) and CO(2) can be studied using VUV photoionization with time-sliced velocity-mapped ion imaging (VUV-PI-VMI) detection. The VUV laser light is produced by resonant sum frequency mixing in Kr. N(2) is used to show that when the photon energy of the VUV laser is above the ionization energy of an allowed transition of one of the product atoms it can be detected and characterized as the wavelength is varied. In this case a β parameter = 0.57 for the N((2)D°) was measured after exciting N(2)(o(1)Π(u), v(') = 2, J(') = 2) ← N(2)(X(1)Σ(g) (+), v(") = 0, J(") = 1). Studies with CO(2) show that when there is no allowed transition, an autoionization resonance can be used for the detection of a product atom. In this case it is shown for the first time that the O((1)D) atom is produced with CO((1)Σ(+)) at 92.21 nm. These results indicate that the VUV laser photodissociation combined with the VUV-PI-VMI detection is a viable method for studying the one-photon photodissociation from the ground state of simple molecules in the extreme ultraviolet and VUV spectral regions.

  4. Radiative lifetimes in B I using ultraviolet and vacuum-ultraviolet laser-induced fluorescence

    NASA Technical Reports Server (NTRS)

    O'Brian, T. R.; Lawler, J. E.

    1992-01-01

    Radiative lifetimes of the eight lowest even parity levels in the doublet system of B I are measured using time-resolved laser-induced fluorescence in the UV and VUV on an atomic beam of boron. The accurate lifetimes provide a base for improved determination of absolute transition probabilities in B I. The techniques described are broadly applicable to measurement of lifetimes of levels with transitions in the visible, UV, and VUV in almost any element.

  5. Interaction of nanosecond ultraviolet laser pulses with reactive dusty plasma

    NASA Astrophysics Data System (ADS)

    van de Wetering, F. M. J. H.; Oosterbeek, W.; Beckers, J.; Nijdam, S.; Gibert, T.; Mikikian, M.; Rabat, H.; Kovačević, E.; Berndt, J.

    2016-05-01

    Even though UV laser pulses that irradiate a gas discharge are small compared to the plasma volume (≲3%) and plasma-on time (≲6 × 10-6%), they are found to dramatically change the discharge characteristics on a global scale. The reactive argon-acetylene plasma allows the growth of nanoparticles with diameters up to 1 μm, which are formed inside the discharge volume due to spontaneous polymerization reactions. It is found that the laser pulses predominantly accelerate and enhance the coagulation phase and are able to suppress the formation of a dust void.

  6. High power tunable femtosecond ultraviolet laser source based on an Yb-fiber-laser pumped optical parametric oscillator.

    PubMed

    Gu, Chenglin; Hu, Minglie; Fan, Jintao; Song, Youjian; Liu, Bowen; Chai, Lu; Wang, Chingyue; Reid, Derryck T

    2015-03-09

    We report a high average power tunable 51 MHz femtosecond ultraviolet (UV) laser source based on an intra-cavity sum frequency mixing optical parametric oscillator (OPO) pumped by a fiber laser. The UV laser is generated by sum frequency generation (SFG) between the second harmonic of a mode-locked Yb-fiber laser and the signal of the OPO. A non-collinear configuration is used in the SFG to compensate the group velocity mismatch, and to increase the SFG conversion efficiency dramatically. Tunable ultraviolet pulses within the wavelength range from 385 to 400 nm have been produced with a maximum average power of 402 mW and a pulse width of 286 fs at 2 W Yb-fiber laser pump, corresponding to 20.1% near-infrared to UV conversion efficiency at 387 nm. To our knowledge, this is the first demonstration of tunable femtosecond UV pulse generation from a fiber laser pumped OPO, and is also the highest average power tunable UV femtosecond pulses from an OPO.

  7. Compact high-pulse-energy ultraviolet laser source for ozone lidar measurements.

    PubMed

    Elsayed, Khaled A; DeYoung, Russell J; Petway, Larry B; Edwards, William C; Barnes, James C; Elsayed-Ali, Hani E

    2003-11-20

    An all solid-state Ti:sapphire laser differential absorption lidar transmitter was developed. This all-solid-state laser provides a compact, robust, and highly reliable laser transmitter for potential application in differential absorption lidar measurements of atmospheric ozone. Two compact, high-energy-pulsed, and injection-seeded Ti:sapphire lasers operating at a pulse repetition frequency of 30 Hz and wavelengths of 867 and 900 nm, with M2 of 1.3, have been experimentally demonstrated and their properties compared with model results. The output pulse energy was 115 mJ at 867 nm and 105 mJ at 900 nm, with a slope efficiency of 40% and 32%, respectively. At these energies, the beam quality was good enough so that we were able to achieve 30 mJ of ultraviolet laser output at 289 and 300 nm after frequency tripling with two lithium triborate nonlinear crystals.

  8. Solid-State Laser Source of Tunable Narrow-Bandwidth Ultraviolet Radiation

    NASA Technical Reports Server (NTRS)

    Goldberg, Lew; Kliner, Dahv A.; Koplow, Jeffrey P.

    1998-01-01

    A solid-state laser source of tunable and narrow-bandwidth UV light is disclosed. The system relies on light from a diode laser that preferably generates light at infrared frequencies. The light from the seed diode laser is pulse amplified in a light amplifier, and converted into the ultraviolet by frequency tripling, quadrupling, or quintupling the infrared light. The narrow bandwidth, or relatively pure light, of the seed laser is preserved, and the pulse amplifier generates high peak light powers to increase the efficiency of the nonlinear crystals in the frequency conversion stage. Higher output powers may be obtained by adding a fiber amplifier to power amplify the pulsed laser light prior to conversion.

  9. The development of a tunable, single-frequency ultraviolet laser source for UV filtered Rayleigh scattering

    NASA Technical Reports Server (NTRS)

    Finkelstein, N.; Gambogi, J.; Lempert, Walter R.; Miles, Richard B.; Rines, G. A.; Finch, A.; Schwarz, R. A.

    1995-01-01

    We present the development of a flexible, high power, narrow line width, tunable ultraviolet source for diagnostic application. By frequency tripling the output of a pulsed titanium-sapphire laser, we achieve broadly tunable (227-360 nm) ultraviolet light with high quality spatial and spectral resolution. We also present the characterization of a mercury vapor cell which provides a narrow band, sharp edge absorption filter at 253.7 nm. These two components form the basis for the extension of the Filtered Rayleigh Scattering technique into the ultraviolet. The UV-FRS system is comprised of four pieces: a single frequency, cw tunable Ti:Sapphire seeding source; a high-powered pulsed Ti:Sapphire oscillator; a third harmonic generator system; and an atomic mercury vapor filter. In this paper we discuss the development and characterization of each of these elements.

  10. Laser triggered Z-pinch broadband extreme ultraviolet source for metrology

    SciTech Connect

    Tobin, I.; Lunney, J. G.; Juschkin, L.; Sidelnikov, Y.; O'Reilly, F.; Sokell, E.; Sheridan, P.

    2013-05-20

    We compare the extreme ultraviolet emission characteristics of tin and galinstan (atomic %: Ga: 78.35, In: 14.93, Sn: 6.72) between 10 nm and 18 nm in a laser-triggered discharge between liquid metal-coated electrodes. Over this wavelength range, the energy conversion efficiency for galinstan is approximately half that of tin, but the spectrum is less strongly peaked in the 13-15 nm region. The extreme ultraviolet source dimensions were 110 {+-} 25 {mu}m diameter and 500 {+-} 125 {mu}m length. The flatter spectrum, and -19 Degree-Sign C melting point, makes this galinstan discharge a relatively simple high radiance extreme ultraviolet light source for metrology and scientific applications.

  11. Extreme ultraviolet emission from laser-induced plasma relevance to neutral gas environment simulation in LEO

    NASA Astrophysics Data System (ADS)

    Tagawa, Masahito; Kimoto, Yugo; Yokota, Kumiko; Ohira, Junki; Watanabe, Daiki; Nishimura, Hiroaki

    The reaction mechanism of atomic oxygen (AO) in low Earth orbit (LEO) with spacecraft materials has been studied by ground-based experiments using laser-detonation hyperthermal beam source, which enables to accelerate the electrically neutral AO up to 8 km/s. However, the beam conditions in the laser-detonation sources could not fully duplicate the AO environment in space. The difference in beam condition including side products leads to the different material responses. The light emission from the laser-induced oxygen plasma may affect the erosion of ultraviolet (UV)-sensitive materials. However, the light emission could also be used as a diagnostic tool to understand the molecular processes in plasma. In this presentation, extreme ultraviolet (EUV) emission from the laser-induced plasma during AO test was evaluated by the flat field EUV spectrometer. Many emission lines between 25-40 nm originated from OII and OIII were observed from the laser-induced oxygen plasma. This result suggested multiple-charged O ions are generated in the laser-induced plasma. Promotion of oxygen dissociation effect by adding Ar in the target gas was explained by the energy transfer processes from Ar to O2 in the plasma. From the viewpoint of reducing the side products in the AO exposure tests, a method to reduce the EUV emission will also be investigated. These results could be used for establishing more accurate ground-based natural gas simulations on the space environmental effect of materials.

  12. Ultralow-threshold electrically injected AlGaN nanowire ultraviolet lasers on Si operating at low temperature.

    PubMed

    Li, K H; Liu, X; Wang, Q; Zhao, S; Mi, Z

    2015-02-01

    Ultraviolet laser radiation has been adopted in a wide range of applications as diverse as water purification, flexible displays, data storage, sterilization, diagnosis and bioagent detection. Success in developing semiconductor-based, compact ultraviolet laser sources, however, has been extremely limited. Here, we report that defect-free disordered AlGaN core-shell nanowire arrays, formed directly on a Si substrate, can be used to achieve highly stable, electrically pumped lasers across the entire ultraviolet AII (UV-AII) band (∼320-340 nm) at low temperatures. The laser threshold is in the range of tens of amps per centimetre squared, which is nearly three orders of magnitude lower than those of previously reported quantum-well lasers. This work also reports the first demonstration of electrically injected AlGaN-based ultraviolet lasers monolithically grown on a Si substrate, and offers a new avenue for achieving semiconductor lasers in the ultraviolet B (UV-B) (280-320 nm) and ultraviolet C (UV-C) (<280 nm) bands.

  13. Bombyx mori silk protein films microprocessing with a nanosecond ultraviolet laser and a femtosecond laser workstation: theory and experiments

    NASA Astrophysics Data System (ADS)

    Lazare, S.; Sionkowska, A.; Zaborowicz, M.; Planecka, A.; Lopez, J.; Dijoux, M.; Louména, C.; Hernandez, M.-C.

    2012-01-01

    Laser microprocessing of several biopolymers from renewable resources is studied. Three proteinic materials were either extracted from the extracellular matrix like Silk Fibroin/Sericin and collagen, or coming from a commercial source like gelatin. All can find future applications in biomedical experimentation, in particular for cell scaffolding. Films of ˜hundred of microns thick were made by aqueous solution drying and laser irradiation. Attention is paid to the properties making them processable with two laser sources: the ultraviolet and nanosecond (ns) KrF (248 nm) excimer and the infrared and femtosecond (fs) Yb:KGW laser. The UV radiation is absorbed in a one-photon resonant process to yield ablation and the surface foaming characteristics of a laser-induced pressure wave. To the contrary, resonant absorption of the IR photons of the fs laser is not possible and does not take place. However, the high field of the intense I>˜1012 W/cm2 femtosecond laser pulse ionizes the film by the multiphoton absorption followed by the electron impact mechanism, yielding a dense plasma capable to further absorb the incident radiation of the end of the pulse. The theoretical model of this absorption is described in detail, and used to discuss the presented experimental effects (cutting, ablation and foaming) of the fs laser. The ultraviolet laser was used to perform simultaneous multiple spots experiments in which energetic foaming yields melt ejection and filament spinning. Airborne nanosize filaments "horizontally suspended by both ends" (0.25 μm diameter and 10 μm length) of silk biopolymer were observed upon irradiation with large fluences.

  14. Investigations into ultraviolet matrix-assisted laser desorption

    SciTech Connect

    Heise, T.W.

    1993-07-01

    Matrix-assisted laser desorption (MALD) is a technique for converting large biomolecules into gas phase ions. Some characteristics of the commonly used uv matrices are determined. Solubilities in methanol range from 0.1 to 0.5 M. Solid phase absorption spectra are found to be similar to solution, but slightly red-shifted. Acoustic and quartz crystal microbalance signals are investigated as possible means of uv-MALD quantitation. Evidence for the existence of desorption thresholds is presented. Threshold values are determined to be in the range of 2 to 3 MW/cm{sup 2}. A transient imaging technique based on laser-excited fluorescence for monitoring MALD plumes is described. Sensitivity is well within the levels required for studying matrix-assisted laser desorption, where analyte concentrations are significantly lower than those in conventional laser desorption. Results showing the effect of film morphology, particularly film thickness, on plume dynamics are presented. In particular, MALD plumes from thicker films tend to exhibit higher axial velocities. Fluorescent labeling of protein and of DNA is used to allow imaging of their uv-MALD generated plumes. Integrated concentrations are available with respect to time, making it possible to assess the rate of fragmentation. The spatial and temporal distributions are important for the design of secondary ionization schemes to enhance ion yields and for the optimization of ion collection in time-of-flight MS instruments to maximize resolution. Such information could also provide insight into whether ionization is closely associated with the desorption step or whether it is a result of subsequent collisions with the matrix gas (e.g., proton transfer). Although the present study involves plumes in a normal atmosphere, adaptation to measurements in vacuum (e.g., inside a mass spectrometer) should be straightforward.

  15. Investigations of Vacuum Ultraviolet and Soft X-Ray Lasers.

    DTIC Science & Technology

    1984-03-01

    state vector g>, which is a solution of the Schr & dinger equation a I - > -> (2.4) , depends on the gauge. The wave function in a gauge g is...instantaneous cross section of decay rate which depends on the value of the laser field at a given time . Since this instantaneous rate is, in principle, a...34 . . . . . , . . .... r. - " . .** .* *. ** - - S." 3 . 4 integral with respect to time over an instantaneous-decay rate which depends on - the instantaneous

  16. Pulsed laser ablation of dental calculus in the near ultraviolet.

    PubMed

    Schoenly, Joshua E; Seka, Wolf; Rechmann, Peter

    2014-02-01

    Pulsed lasers emitting wavelengths near 400 nm can selectively ablate dental calculus without damaging underlying and surrounding sound dental hard tissue. Our results indicate that calculus ablation at this wavelength relies on the absorption of porphyrins endogenous to oral bacteria commonly found in calculus. Sub- and supragingival calculus on extracted human teeth, irradiated with 400-nm, 60-ns laser pulses at ≤8  J/cm2, exhibits a photobleached surface layer. Blue-light microscopy indicates this layer highly scatters 400-nm photons, whereas fluorescence spectroscopy indicates that bacterial porphyrins are permanently photobleached. A modified blow-off model for ablation is proposed that is based upon these observations and also reproduces our calculus ablation rates measured from laser profilometry. Tissue scattering and a stratified layering of absorbers within the calculus medium explain the gradual decrease in ablation rate from successive pulses. Depending on the calculus thickness, ablation stalling may occur at <5  J/cm2 but has not been observed above this fluence.

  17. The Laser-assisted photoelectric effect of He, Ne, Ar and Xe in intense extreme ultraviolet and infrared laser fields

    NASA Astrophysics Data System (ADS)

    Hayden, P.; Dardis, J.; Hough, P.; Richardson, V.; Kennedy, E. T.; Costello, J. T.; Düsterer, S.; Redlin, H.; Feldhaus, J.; Li, W. B.; Cubaynes, D.; Meyer, M.

    2016-02-01

    In this paper, we report results on two-colour above-threshold ionisation, where extreme ultraviolet pulses of femtosecond duration were synchronised to intense infrared laser pulses of picosecond duration, in order to study the laser-assisted photoelectric effect of atomic helium, neon, krypton and xenon which leads to the appearance of characteristic sidebands in the photoelectron spectra. The observed trends are found to be well described by a simple model based on the soft-photon approximation, at least for the relatively low optical intensities of up to ? employed in these early experiments.

  18. Laser-induced two-photon blackbody radiation in the vacuum ultraviolet

    NASA Technical Reports Server (NTRS)

    Zych, L. J.; Young, J. F.; Harris, S. E.; Lukasik, J.

    1978-01-01

    Experimental measurements of a new type of vacuum-ultraviolet radiation source are reported. It is shown that the maximum source brightness, within its narrow linewidth, is that of a blackbody at the temperature of a metastable storage level. The laser-induced emission at 569 A from a He glow discharge corresponded to a metastable temperature of 22,700 K and was over 100 times brighter than the 584-A He resonance line.

  19. Extreme Ultraviolet Imaging of Electron Heated Targets in Petawatt Laser Experiments

    SciTech Connect

    Ma, T; MacPhee, A; Key, M; Akli, K; Mackinnon, A; Chen, C; Barbee, T; Freeman, R; King, J; Link, A; Offermann, D; Ovchinnikov, V; Patel, P; Stephens, R; VanWoerkom, L; Zhang, B; Beg, F

    2007-11-29

    The study of the transport of electrons, and the flow of energy into a solid target or dense plasma, is instrumental in the development of fast ignition inertial confinement fusion. An extreme ultraviolet (XUV) imaging diagnostic at 256 eV and 68 eV provides information about heating and energy deposition within petawatt laser-irradiated targets. XUV images of several irradiated solid targets are presented.

  20. Pump-probe photoelectron spectroscopy by a high-power 90 nm vacuum-ultraviolet laser

    NASA Astrophysics Data System (ADS)

    Sato, Motoki; Suzuki, Yoshi-ichi; Suzuki, Toshinori; Adachi, Shunsuke

    2016-02-01

    We present pump-probe photoelectron spectroscopy of Kr and NO using a high-power vacuum-ultraviolet (VUV) laser at a wavelength of 90 nm. Clear quantum beats are observed in the photoelectron angular distributions as well as in the photoelectron yields, resulting from the coherent excitation of two Kr Rydberg states by the VUV pump. The entire Franck-Condon envelope of the NO A(2Σ+) excited state is also successfully captured by the VUV probe.

  1. Evolution of laser-produced Sn extreme ultraviolet source diameter for high-brightness source

    SciTech Connect

    Roy, Amitava E-mail: aroy@barc.gov.in; Arai, Goki; Hara, Hiroyuki; Higashiguchi, Takeshi; Ohashi, Hayato; Sunahara, Atsushi; Li, Bowen; Dunne, Padraig; O'Sullivan, Gerry; Miura, Taisuke; Mocek, Tomas; Endo, Akira

    2014-08-18

    We have investigated the effect of irradiation of solid Sn targets with laser pulses of sub-ns duration and sub-mJ energy on the diameter of the extreme ultraviolet (EUV) emitting region and source conversion efficiency. It was found that an in-band EUV source diameter as low as 18 μm was produced due to the short scale length of a plasma produced by a sub-ns laser. Most of the EUV emission occurs in a narrow region with a plasma density close to the critical density value. Such EUV sources are suitable for high brightness and high repetition rate metrology applications.

  2. Note: Measurement of saturable absorption by intense vacuum ultraviolet free electron laser using fluorescent material.

    PubMed

    Inubushi, Y; Yoneda, H; Higashiya, A; Ishikawa, T; Kimura, H; Kumagai, T; Morimoto, S; Nagasono, M; Ohashi, H; Sato, F; Tanaka, T; Togashi, T; Tono, K; Yabashi, M; Yamaguchi, Y; Kodama, R

    2010-03-01

    Advances in free electron lasers (FELs) which generate high energy photons are expected to open novel nonlinear optics in the x-ray and vacuum ultraviolet (VUV) regions. In this paper, we report a new method for performing VUV-FEL focusing experiments. A VUV-FEL was focused with Kirkpatrick-Baez optics on a multilayer target, which contains fused silica as a fluorescent material. By measuring the fluorescence, a 5.6x4.9 microm(2) focal spot was observed in situ. Fluorescence was used to measure the saturable absorption of VUV pulses in the tin layer. The transmission increases nonlinearly higher with increasing laser intensity.

  3. Evaluation of a hydrogen laser vacuum ultraviolet source for photoionization mass spectrometry of pharmaceuticals.

    PubMed

    Finch, Jeffrey W; Toerne, Kevin A; Schram, Karl H; Denton, M Bonner

    2005-01-01

    A photoionization hydrogen laser time-of-flight mass spectrometer system (H2-TOFMS) has been evaluated for the rapid analysis of drugs of abuse and pharmaceutical agents extracted from prescription tablets and spiked urine samples. The spectra obtained using the H2-TOFMS showed primarily intact molecular ions (M+*) after introduction by a heated probe and irradiation with vacuum ultraviolet (VUV) photons from the laser. Samples analyzed by this technique required only a simple solid-phase extraction step; no chromatographic separation or derivatization was necessary to identify the drugs of abuse or pharmaceutical agents.

  4. Cooperative effect of ultraviolet and near-infrared beams in laser-induced condensation

    SciTech Connect

    Matthews, M.; Henin, S.; Pomel, F.; Kasparian, J.; Wolf, J.-P.; Théberge, F.; Daigle, J.-F.; Lassonde, P.; Kieffer, J.-C.

    2013-12-23

    We demonstrate the cooperative effect of near infrared (NIR) and ultraviolet (UV) beams on laser-induced condensation. Launching a UV laser after a NIR pulse yields up to a 5-fold increase in the production of nanoparticles (25–300 nm) as compared to a single NIR beam. This cooperative effect exceeds the sum of those from the individual beams and occurs for delays up to 1 μs. We attribute it to the UV photolysis of ozone created by the NIR pulses. The resulting OH radicals oxidize NO{sub 2} and volatile organic compounds, producing condensable species.

  5. Invited Article: Progress in coherent lithography using table-top extreme ultraviolet lasers.

    PubMed

    Li, W; Urbanski, L; Marconi, M C

    2015-12-01

    Compact (table top) lasers emitting at wavelengths below 50 nm had expanded the spectrum of applications in the extreme ultraviolet (EUV). Among them, the high-flux, highly coherent laser sources enabled lithographic approaches with distinctive characteristics. In this review, we will describe the implementation of a compact EUV lithography system capable of printing features with sub-50 nm resolution using Talbot imaging. This compact system is capable of producing consistent defect-free samples in a reliable and effective manner. Examples of different patterns and structures fabricated with this method will be presented.

  6. Vacuum ultraviolet fluorine laser formation of corrosion-resistant iron thin films

    NASA Astrophysics Data System (ADS)

    Okoshi, Masayuki; Awaihara, Yuta; Yamashita, Tsugito; Inoue, Narumi

    2015-06-01

    Corrosion-, chemical-resistant pure iron thin films were formed by the vacuum ultraviolet fluorine laser of 157 nm wavelength induced surface modification of 30- to 50-nm-thick iron thin films. Transmission electron microscope and electron energy-loss spectroscopy were conducted to analyze structure and oxidation state of the thin modified layer of iron thin films. No rust was observed on the surface of the fluorine laser-irradiated iron thin films in air for 2 years. The samples also showed high chemical resistance to a HNO3 aqueous solution to fabricate a micropattern of pure iron thin films.

  7. Optimizing laser produced plasmas for efficient extreme ultraviolet and soft X-ray light sources

    SciTech Connect

    Sizyuk, Tatyana; Hassanein, Ahmed

    2014-08-15

    Photon sources produced by laser beams with moderate laser intensities, up to 10{sup 14 }W/cm{sup 2}, are being developed for many industrial applications. The performance requirements for high volume manufacture devices necessitate extensive experimental research supported by theoretical plasma analysis and modeling predictions. We simulated laser produced plasma sources currently being developed for several applications such as extreme ultraviolet lithography using 13.5% ± 1% nm bandwidth, possibly beyond extreme ultraviolet lithography using 6.× nm wavelengths, and water-window microscopy utilizing 2.48 nm (La-α) and 2.88 nm (He-α) emission. We comprehensively modeled plasma evolution from solid/liquid tin, gadolinium, and nitrogen targets as three promising materials for the above described sources, respectively. Results of our analysis for plasma characteristics during the entire course of plasma evolution showed the dependence of source conversion efficiency (CE), i.e., laser energy to photons at the desired wavelength, on plasma electron density gradient. Our results showed that utilizing laser intensities which produce hotter plasma than the optimum emission temperatures allows increasing CE for all considered sources that, however, restricted by the reabsorption processes around the main emission region and this restriction is especially actual for the 6.× nm sources.

  8. Erosion resistant nozzles for laser plasma extreme ultraviolet (EUV) sources

    DOEpatents

    Kubiak, Glenn D.; Bernardez, II, Luis J.

    2000-01-04

    A gas nozzle having an increased resistance to erosion from energetic plasma particles generated by laser plasma sources. By reducing the area of the plasma-facing portion of the nozzle below a critical dimension and fabricating the nozzle from a material that has a high EUV transmission as well as a low sputtering coefficient such as Be, C, or Si, it has been shown that a significant reduction in reflectance loss of nearby optical components can be achieved even after exposing the nozzle to at least 10.sup.7 Xe plasma pulses.

  9. A Plasma Ultraviolet Source for Short Wavelength Lasers.

    DTIC Science & Technology

    1988-04-15

    Iodine photodissociation laser pumped with radiation from magnetoplasma compressions", G. N . Kashikov, V. K. Orlov, A. N . Panin, A. K. Piskunov and V. A...H DAAL3-86-G-0ee3 UNCLASIFIED F.’G 9/3 W EEEEEEEEEEommoiE EEEEEEEEEEEE Eu.... N ’ "’ II~ N .’ 1-0 L; 7, 1,,- / 41 5 u 1-25 IllII4 UNCLASSIFIED...REPORT NUMBER 2. GOVT ACCESSION NO. 3. RECIPIENT’S CATALOG NUMBER %Id AA6. ~-/h N /A N /ACo0 S TITLE (and Subtitle) S. TYPE OF REPORT & PERIOD COVERED

  10. An Ultraviolet X-Ray Laser Source for Core Level Spectroscopy and Dynamics of Metal Cluster/Ceramic Chemistry

    DTIC Science & Technology

    2007-11-02

    TYPE AND DATES COVERED Final Rpnnrt. 3/1/97 - 5/31/98 4. TITLE AND SUBTITLE An Ultraviolet X-ray Laser Source for Core Level Spectroscopy and...DISTRIBUTION CODE 13. ABSTRACT (Maximum 200 words) A99B0722 A titanium sapphire ultrafast laser system was procured and merged with a high repetition rate...pulsed valve to produce higher harmonic light output in a rare gas jet. The ultrafast laser system consists of a seed laser , a regenerative amplifier

  11. Low-level red laser therapy alters effects of ultraviolet C radiation on Escherichia coli cells.

    PubMed

    Canuto, K S; Sergio, L P S; Guimarães, O R; Geller, M; Paoli, F; Fonseca, A S

    2015-07-10

    Low-level lasers are used at low power densities and doses according to clinical protocols supplied with laser devices or based on professional practice. Although use of these lasers is increasing in many countries, the molecular mechanisms involved in effects of low-level lasers, mainly on DNA, are controversial. In this study, we evaluated the effects of low-level red lasers on survival, filamentation, and morphology of Escherichia coli cells that were exposed to ultraviolet C (UVC) radiation. Exponential and stationary wild-type and uvrA-deficient E. coli cells were exposed to a low-level red laser and in sequence to UVC radiation. Bacterial survival was evaluated to determine the laser protection factor (ratio between the number of viable cells after exposure to the red laser and UVC and the number of viable cells after exposure to UVC). Bacterial filaments were counted to obtain the percentage of filamentation. Area-perimeter ratios were calculated for evaluation of cellular morphology. Experiments were carried out in duplicate and the results are reported as the means of three independent assays. Pre-exposure to a red laser protected wild-type and uvrA-deficient E. coli cells against the lethal effect of UVC radiation, and increased the percentage of filamentation and the area-perimeter ratio, depending on UVC fluence and physiological conditions in the cells. Therapeutic, low-level red laser radiation can induce DNA lesions at a sub-lethal level. Consequences to cells and tissues should be considered when clinical protocols based on this laser are carried out.

  12. Low-level red laser therapy alters effects of ultraviolet C radiation on Escherichia coli cells.

    PubMed

    Canuto, K S; Sergio, L P S; Guimarães, O R; Geller, M; Paoli, F; Fonseca, A S

    2015-10-01

    Low-level lasers are used at low power densities and doses according to clinical protocols supplied with laser devices or based on professional practice. Although use of these lasers is increasing in many countries, the molecular mechanisms involved in effects of low-level lasers, mainly on DNA, are controversial. In this study, we evaluated the effects of low-level red lasers on survival, filamentation, and morphology of Escherichia colicells that were exposed to ultraviolet C (UVC) radiation. Exponential and stationary wild-type and uvrA-deficientE. coli cells were exposed to a low-level red laser and in sequence to UVC radiation. Bacterial survival was evaluated to determine the laser protection factor (ratio between the number of viable cells after exposure to the red laser and UVC and the number of viable cells after exposure to UVC). Bacterial filaments were counted to obtain the percentage of filamentation. Area-perimeter ratios were calculated for evaluation of cellular morphology. Experiments were carried out in duplicate and the results are reported as the means of three independent assays. Pre-exposure to a red laser protected wild-type and uvrA-deficient E. coli cells against the lethal effect of UVC radiation, and increased the percentage of filamentation and the area-perimeter ratio, depending on UVC fluence and physiological conditions in the cells. Therapeutic, low-level red laser radiation can induce DNA lesions at a sub-lethal level. Consequences to cells and tissues should be considered when clinical protocols based on this laser are carried out.

  13. Low-level red laser therapy alters effects of ultraviolet C radiation on Escherichia coli cells

    PubMed Central

    Canuto, K.S.; Sergio, L.P.S.; Guimarães, O.R.; Geller, M.; Paoli, F.; Fonseca, A.S.

    2015-01-01

    Low-level lasers are used at low power densities and doses according to clinical protocols supplied with laser devices or based on professional practice. Although use of these lasers is increasing in many countries, the molecular mechanisms involved in effects of low-level lasers, mainly on DNA, are controversial. In this study, we evaluated the effects of low-level red lasers on survival, filamentation, and morphology of Escherichia colicells that were exposed to ultraviolet C (UVC) radiation. Exponential and stationary wild-type and uvrA-deficientE. coli cells were exposed to a low-level red laser and in sequence to UVC radiation. Bacterial survival was evaluated to determine the laser protection factor (ratio between the number of viable cells after exposure to the red laser and UVC and the number of viable cells after exposure to UVC). Bacterial filaments were counted to obtain the percentage of filamentation. Area-perimeter ratios were calculated for evaluation of cellular morphology. Experiments were carried out in duplicate and the results are reported as the means of three independent assays. Pre-exposure to a red laser protected wild-type and uvrA-deficient E. coli cells against the lethal effect of UVC radiation, and increased the percentage of filamentation and the area-perimeter ratio, depending on UVC fluence and physiological conditions in the cells. Therapeutic, low-level red laser radiation can induce DNA lesions at a sub-lethal level. Consequences to cells and tissues should be considered when clinical protocols based on this laser are carried out. PMID:26445338

  14. Capillary discharge extreme ultraviolet lasers. [Colorado State Univ. , Ft. Collins

    SciTech Connect

    Rocca, J.J.

    1992-08-01

    The project objective is to explore the generation of soft X-ray laser radiation in a plasma column created by a fast capillary discharge. The proposed capillary lasing scheme offers the potential for compact, simple and efficient soft X-ray laser sources. For this purpose a compact, fast pulse generator which produces 100 kA current pulses with a risetime of 11 ns was constructed. Initial experiments were conducted in evacuated capillaries, in which the plasma is produced by ablation of the capillary walls. The soft X-ray emission from discharges in polyethylene capillary channels was studied to investigate the possibility of amplification in the 3-2 transition of C VI, at {lambda} = 18.2 nm. Time-resolved spectra in which this transition appears anomalously intense with respect to the 4--2 transition of the same ion were obtained. To date, however, this phenomenoa could not be confirmed as gain, as the intensity of the 18.2 nm line has not been observed to increase exponentially as a function of the capillary length. Encouraging results were obtained by fast pulse discharge excitation of capillaries filled with preionized gas. High temperature (Te > 150 eV), small diameter ({approximately}200 {mu}m) plasma columns were efficiently generated. Fast current pulse excitation of a selected low mass density of uniformly preionized material Mag the capillary was observed to detach rapidly the plasma from the capillary walls, and form a plasma channel of a diameter much smaller and significantly hotter than those produced by a similar current pulse in evacuated capillaries of the same size. Discharges in argon-filled capillaries at currents between 20 and 60 kA produced plasmas with ArX-Ar{sub XIV} line emission, and with spectra that are similar to those of plasmas generated by > I MA current implosions in large pulsed power machines. The characteristic of these plasmas approach those necessary for soft X-ray amplification in low Z elements.

  15. Chlorpromazine transformation by exposure to ultraviolet laser beams in droplet and bulk.

    PubMed

    Andrei, Ionut Relu; Tozar, Tatiana; Dinache, Andra; Boni, Mihai; Nastasa, Viorel; Pascu, Mihail Lucian

    2016-01-01

    Multiple drug resistance requires a flexible approach to find medicines able to overcome it. One method could be the exposure of existing medicines to ultraviolet laser beams to generate photoproducts that are efficient against bacteria and/or malignant tumors. This can be done in droplets or bulk volumes. In the present work are reported results about the interaction of 266nm and 355nm pulsed laser radiation with microdroplets and bulk containing solutions of 10mg/ml Chlorpromazine Hydrochloride (CPZ) in ultrapure water. The irradiation effects on CPZ solution at larger time intervals (more than 30min) are similar in terms of generated photoproducts if the two ultraviolet wavelengths are utilized. The understanding of the CPZ parent compound transformation may be better evidenced, as shown in this paper, if studies at shorter than 30minute exposure times are made coupled with properly chosen volumes to irradiate. We show that at exposure to a 355nm laser beam faster molecular modifications of CPZ in ultrapure water solution are produced than at irradiation with 266nm, for both microdroplet and bulk volume samples. These effects are evidenced by thin layer chromatography technique and laser induced fluorescence measurements.

  16. Laser spectroscopy of CdKr molecules in ultraviolet region

    NASA Astrophysics Data System (ADS)

    Koperski, J.; Łukomski, M.; Czajkowski, M.

    2002-10-01

    Excitation spectra of the A0 +(5 3P 1)←X0 +(5 1S 0), B1(5 3P 1)←X0 + and D1(5 1P 1)←X0 + transitions as well as a fluorescence spectrum of the D1 v'=16 →X0 + transition in CdKr van der Waals molecule has been recorded in an experiment of a continuous supersonic molecular beam crossed with a pulsed dye laser beam. A rigorous analysis of the excitation spectra based on Birge-Sponer and LeRoy-Bernstein methods aided with a computer calculation, utilizing a program of near dissociation expansion lead to the X0 +- and improved A0 +-, B1- and D1-state characterizations. Evidence of a theoretically predicted potential barrier within the B1-state well was found and discussed with regard to the latest result of ab initio calculation. An analysis of bound-bound and bound-free parts of the fluorescence spectrum confirmed a v'-assignment and indicated that Morse and Maitland-Smith M-S ( n0, n1) functions are adequate representations of the bound well and repulsive wall of the X0 +-state potential energy curve, respectively. All spectroscopic characteristics obtained in this work are compared with newest theoretical studies of this complex.

  17. Development and characterization of a 22 W narrow-linewidth 3186 nm ultraviolet laser

    NASA Astrophysics Data System (ADS)

    Wang, Jieying; Bai, Jiandong; He, Jun; Wang, Junmin

    2016-10-01

    We demonstrate a high-power narrow-linewidth ultraviolet (UV) laser system at 318.6 nm for direct 6S1/2-nP (n = 70 to 100) Rydberg excitation of cesium atoms. Based on commercial fiber lasers and efficient nonlinear frequency conversion technology, 2.26 W of tunable UV laser power is obtained from cavity-enhanced second harmonic generation following sum-frequency generation of two infrared lasers at 1560.5 nm and 1076.9 nm to 637.2 nm. The maximum doubling efficiency is 57.3%. The typical UV laser power root-mean-square fluctuation is less than 0.87% over 30 minutes, and the continuously tunable range of the UV laser frequency is more than 6 GHz. Its beam quality factors M2 X and M2 Y are 1.16 and 1.48, respectively. This high-performance UV laser has significant potential use in quantum optics and cold atom physics.

  18. The thermodynamic response of soft biological tissues to pulsed ultraviolet laser irradiation.

    PubMed Central

    Venugopalan, V; Nishioka, N S; Mikić, B B

    1995-01-01

    The physical mechanisms that enable short pulses of high-intensity ultraviolet laser radiation to remove tissue, in a process known as laser ablation, remain obscure. The thermodynamic response of biological tissue to pulsed laser irradiation was investigated by measuring and subsequently analyzing the stress transients generated by pulsed argon fluorine (ArF, lambda = 193 nm) and krypton fluorine (KrF, lambda = 248 nm) excimer laser irradiation of porcine dermis using thin-film piezoelectric transducers. For radiant exposures that do not cause material removal, the stress transients are consistent with rapid thermal expansion of the tissue. At the threshold radiant exposure for ablation, the peak stress amplitude generated by 248 nm irradiation is more than an order of magnitude larger than that produced by 193 nm irradiation. For radiant exposures where material removal is achieved, the temporal structure of the stress transient indicates that the onset of material removal occurs during irradiation. In this regime, the variation of the peak compressive stress with radiant exposure is consistent with laser-induced rapid surface vaporization. For 193 nm irradiation, ionization of the ablated material occurs at even greater radiant exposures and is accompanied by a change in the variation of peak stress with radiant exposure consistent with a plasma-mediated ablation process. These results suggest that absorption of ultraviolet laser radiation by the extracellular matrix of tissue leads to decomposition of tissue on the time scale of the laser pulse. The difference in volumetric energy density at ablation threshold between the two wavelengths indicates that the larger stresses generated by 248 nm irradiation may facilitate the onset of material removal. However, once material removal is achieved, the stress measurements demonstrate that energy not directly responsible for target decomposition contributes to increasing the specific energy of the plume (and plasma

  19. Extended temperature tuning of an ultraviolet diode laser for trapping and cooling single Yb+ ions.

    PubMed

    Nguyen, A-T; Wang, L-B; Schauer, M M; Torgerson, J R

    2010-05-01

    We describe an ultraviolet (uv) diode laser system for cooling trapped Yb(+) ions. Using four stages of thermoelectric cooling, 10 mW of light at 369.5 nm is obtained by cooling a 373.4-nm uv diode to approximately -20 degrees C. Frequency stabilization is provided by a diffraction grating mounted in the Littrow configuration which allows for a mode-hop free tuning range of approximately 25 GHz. In order to avoid water condensation, the diode laser and associated optics are placed inside an evacuated chamber. Saturated absorption spectroscopy utilizing an Yb hollow cathode lamp is performed. This laser system is currently being used to cool single ions in an experiment whose ultimate goal is to look for modern variation of the fine-structure constant.

  20. Tunable vacuum ultraviolet laser based spectrometer for angle resolved photoemission spectroscopy

    NASA Astrophysics Data System (ADS)

    Jiang, Rui; Mou, Daixiang; Wu, Yun; Huang, Lunan; McMillen, Colin D.; Kolis, Joseph; Giesber, Henry G.; Egan, John J.; Kaminski, Adam

    2014-03-01

    We have developed an angle-resolved photoemission spectrometer with tunable vacuum ultraviolet laser as a photon source. The photon source is based on the fourth harmonic generation of a near IR beam from a Ti:sapphire laser pumped by a CW green laser and tunable between 5.3 eV and 7 eV. The most important part of the set-up is a compact, vacuum enclosed fourth harmonic generator based on potassium beryllium fluoroborate crystals, grown hydrothermally in the US. This source can deliver a photon flux of over 1014 photon/s. We demonstrate that this energy range is sufficient to measure the kz dispersion in an iron arsenic high temperature superconductor, which was previously only possible at synchrotron facilities.

  1. Tunable vacuum ultraviolet laser based spectrometer for angle resolved photoemission spectroscopy

    SciTech Connect

    Jiang, Rui; Mou, Daixiang; Wu, Yun; Huang, Lunan; Kaminski, Adam; McMillen, Colin D.; Kolis, Joseph; Giesber, Henry G.; Egan, John J.

    2014-03-15

    We have developed an angle-resolved photoemission spectrometer with tunable vacuum ultraviolet laser as a photon source. The photon source is based on the fourth harmonic generation of a near IR beam from a Ti:sapphire laser pumped by a CW green laser and tunable between 5.3 eV and 7 eV. The most important part of the set-up is a compact, vacuum enclosed fourth harmonic generator based on potassium beryllium fluoroborate crystals, grown hydrothermally in the US. This source can deliver a photon flux of over 10{sup 14} photon/s. We demonstrate that this energy range is sufficient to measure the k{sub z} dispersion in an iron arsenic high temperature superconductor, which was previously only possible at synchrotron facilities.

  2. Studies of extreme ultraviolet emission from laser produced plasmas, as sources for next generation lithography

    NASA Astrophysics Data System (ADS)

    Cummins, Thomas

    The work presented in this thesis is primarily concerned with the optimisation of extreme ultraviolet (EUV) photoemission around 13.5 nm, from laser produced tin (Sn) plasmas. EUV lithography has been identified as the leading next generation technology to take over from the current optical lithography systems, due to its potential of printing smaller feature sizes on integrated circuits. Many of the problems hindering the implementation of EUV lithography for high volume manufacturing have been overcome during the past 20 years of development. However, the lack of source power is a major concern for realising EUV lithography and remains a major roadblock that must be overcome. Therefore in order to optimise and improve the EUV emission from Sn laser plasma sources, many parameters contributing to the make-up of an EUV source are investigated. Chapter 3 presents the results of varying several different experimental parameters on the EUV emission from Sn laser plasmas. Several of the laser parameters including the energy, gas mixture, focusing lens position and angle of incidence are changed, while their effect on the EUV emission is studied. Double laser pulse experiments are also carried out by creating plasma targets for the main laser pulse to interact with. The resulting emission is compared to that of a single laser pulse on solid Sn. Chapter 4 investigates tailoring the CO2 laser pulse duration to improve the efficiency of an EUV source set-up. In doing so a new technique for shortening the time duration of the pulse is described. The direct effects of shortening the CO2 laser pulse duration on the EUV emission from Sn are then studied and shown to improve the efficiency of the source. In Chapter 5 a new plasma target type is studied and compared to the previous dual laser experiments. Laser produced colliding plasma jet targets form a new plasma layer, with densities that can be optimised for re-heating with the main CO2 laser pulse. Chapter 6 will present

  3. High-intensity coherent vacuum ultraviolet source using unfocussed commercial dye lasers.

    PubMed

    Albert, Daniel R; Proctor, David L; Davis, H Floyd

    2013-06-01

    Using two or three commercial pulsed nanosecond dye lasers pumped by a single 30 Hz Nd:YAG laser, generation of 0.10 mJ pulses at 125 nm (6 × 10(13) photons∕pulse) has been demonstrated by resonance enhanced four-wave mixing of collimated (unfocussed) laser beams in mercury (Hg) vapor. Phase matching at various vacuum ultraviolet (VUV) wavelengths is achieved by tuning one laser in the vicinity of the 6 (1)S0 → 6 (3)P1 resonance near 253.1 nm. A number of different mixing schemes are characterized. Our observations using broadband lasers (~0.15 cm(-1) bandwidths) are compared to previous calculations pertaining to four-wave mixing of low intensity narrowband laser beams. Prospects for further increases in pulse energies are discussed. We find that VUV tuning curves and intensities are in good agreement with theoretical predictions. The utility of the VUV light source is demonstrated by "soft universal" single-photon VUV ionization in crossed molecular beam studies and for generation of light at 130.2 nm for oxygen atom Rydberg time-of-flight experiments.

  4. Laser Desorption Postionization Mass Spectrometry of Antibiotic-Treated Bacterial Biofilms using Tunable Vacuum Ultraviolet Radiation

    SciTech Connect

    Gasper, Gerald L; Takahashi, Lynelle K; Zhou, Jia; Ahmed, Musahid; Moore, Jerry F; Hanley, Luke

    2010-08-04

    Laser desorption postionization mass spectrometry (LDPI-MS) with 8.0 ? 12.5 eV vacuum ultraviolet synchrotron radiation is used to single photon ionize antibiotics andextracellular neutrals that are laser desorbed both neat and from intact bacterial biofilms. Neat antibiotics are optimally detected using 10.5 eV LDPI-MS, but can be ionized using 8.0 eV radiation, in agreement with prior work using 7.87 eV LDPI-MS. Tunable vacuum ultraviolet radiation also postionizes laser desorbed neutrals of antibiotics and extracellular material from within intact bacterial biofilms. Different extracellular material is observed by LDPI-MS in response to rifampicin or trimethoprim antibiotic treatment. Once again, 10.5 eV LDPI-MS displays the optimum trade-off between improved sensitivity and minimum fragmentation. Higher energy photons at 12.5 eV produce significant parent ion signal, but fragment intensity and other low mass ions are also enhanced. No matrix is added to enhance desorption, which is performed at peak power densities insufficient to directly produce ions, thus allowing observation of true VUV postionization mass spectra of antibiotic treated biofilms.

  5. Laser desorption postionization mass spectrometry of antibiotic-treated bacterial biofilms using tunable vacuum ultraviolet radiation.

    PubMed

    Gasper, Gerald L; Takahashi, Lynelle K; Zhou, Jia; Ahmed, Musahid; Moore, Jerry F; Hanley, Luke

    2010-09-01

    Laser desorption postionization mass spectrometry (LDPI-MS) with 8.0-12.5 eV vacuum ultraviolet synchrotron radiation is used to single photon ionize antibiotics and extracellular neutrals that are laser desorbed both from neat and intact bacterial biofilms. Neat antibiotics are optimally detected using 10.5 eV LDPI-MS but can be ionized using 8.0 eV radiation, in agreement with prior work using 7.87 eV LDPI-MS. Tunable vacuum ultraviolet radiation also postionizes laser desorbed neutrals of antibiotics and extracellular material from within intact bacterial biofilms. Different extracellular material is observed by LDPI-MS in response to rifampicin or trimethoprim antibiotic treatment. Once again, 10.5 eV LDPI-MS displays the optimum trade-off between improved sensitivity and minimum fragmentation. Higher energy photons at 12.5 eV produce significant parent ion signal, but fragment intensity and other low mass ions are also enhanced. No matrix is added to enhance desorption, which is performed at peak power densities insufficient to directly produce ions, thus allowing observation of true VUV postionization mass spectra of antibiotic treated biofilms.

  6. a Comparison of Different Coherent Deep Ultraviolet Generations Using Second Harmonic Generation with Blue Laser Diode Excitation

    NASA Astrophysics Data System (ADS)

    Tangtrongbenchasil, C.; Nonaka, K.

    2008-11-01

    Nano-focus beam applications of short wavelength approximately 220 nm now play important roles in engineering and industrial sections. At present, light sources at approximately 220 nm are commercially available but large size, difficult to maintain, and expensive. Compact wavelength tunable and cost effective light sources at approximately 220 nm are required. Laser diode with sum-frequency generation methods are employed to generated the shorter wavelength approximately 220 nm. This paper presents comparison of second harmonic generation schemes using a nonlinear optic crystal and two types of laser diode, which are a 440 nm single mode blue laser diode and a 450 nm multimode Fabry-Perot blue laser diode, has potential to generate wide tunable coherent deep ultraviolet-c at approximately 220 nm. Using the blue laser diode with the sum-frequency technique, a high second harmonic power is hardly observed due to low conversion efficiency. The best performance of second harmonic generation using blue laser diode, nonlinear optic crystal, and an high-Q external cavity laser diode was observed as 1.1 μW second harmonic ultraviolet-c power at 224.45 nm ultraviolet-c wavelength and 5.75 nm ultraviolet wavelength tunability. In addition, the improvement of increasing second harmonic power approximately 220 nm and the limitation of wavelength tuning of short wavelength are also theoretically discussed in this paper.

  7. Wavefront control to generate ultraviolet supercontinuum by filamentation of few-cycle laser pulses in argon.

    PubMed

    Wang, Zhanxin; Liu, Jiansheng; Li, Ruxin; Xu, Zhizhan

    2010-01-15

    We numerically demonstrated the filamentation dynamics of a 6 fs, 800 nm pulse focused in argon at atmospheric pressure by a zone plate and a concave mirror. In comparison with a concave mirror, the zone plate has a frequency-dependent focal length and can be used to control the wavefront of the laser beam in the frequency domain. A separate supercontinuum in the ultraviolet region extending from 250 to 300 nm and peaked at ~280 nm can be generated by using a proper zone plate.

  8. Note: Enhancement of the extreme ultraviolet emission from a potassium plasma by dual laser irradiation

    SciTech Connect

    Higashiguchi, Takeshi Yamaguchi, Mami; Otsuka, Takamitsu; Nagata, Takeshi; Ohashi, Hayato; Li, Bowen; D’Arcy, Rebekah; Dunne, Padraig; O’Sullivan, Gerry

    2014-09-15

    Emission spectra from multiply charged potassium ions ranging from K{sup 3+} to K{sup 5+} have been obtained in the extreme ultraviolet (EUV) spectral region. A strong emission feature peaking around 38 nm, corresponding to a photon energy of 32.6 eV, is the dominant spectral feature at time-averaged electron temperatures in the range of 8−12 eV. The variation of this emission with laser intensity and the effects of pre-pulses on the relative conversion efficiency (CE) have been explored experimentally and indicate that an enhancement of about 30% in EUV CE is readily attainable.

  9. Single shot extreme ultraviolet laser imaging of nanostructures with wavelength resolution

    SciTech Connect

    Jones, Juanita; Brewer, Courtney A.; Brizuela, Fernando; Wachulak, Przemyslaw; Martz, Dale H.; Chao, Weilun; Anderson, Erik H.; Attwood, David T.; Vinogradov, Alexander V.; Artyukov, Igor A.; Ponomareko, Alexander G.; Kondratenko, Valeriy V.; Marconi, Mario C.; Rocca, Jorge J.; Menoni, Carmen S.

    2008-01-07

    We have demonstrated near-wavelength resolution microscopy in the extreme ultraviolet. Images of 50 nm diameter nanotubes were obtained with a single {approx}1 ns duration pulse from a desk-top size 46.9 nm laser. We measured the modulation transfer function of the microscope for three different numerical aperture zone plate objectives, demonstrating that 54 nm half-period structures can be resolved. The combination of near-wavelength spatial resolution and high temporal resolution opens myriad opportunities in imaging, such as the ability to directly investigate dynamics of nanoscale structures.

  10. Direct writing of ferroelectric domains on strontium barium niobate crystals using focused ultraviolet laser light

    SciTech Connect

    Boes, Andreas; Crasto, Tristan; Steigerwald, Hendrik; Mitchell, Arnan; Wade, Scott; Frohnhaus, Jakob; Soergel, Elisabeth

    2013-09-30

    We report ferroelectric domain inversion in strontium barium niobate (SBN) single crystals by irradiating the surface locally with a strongly focused ultraviolet (UV) laser beam. The generated domains are investigated using piezoresponse force microscopy. We propose a simple model that allows predicting the domain width as a function of the irradiation intensity, which indeed applies for both SBN and LiNbO{sub 3}. Evidently, though fundamentally different, the domain structure of both SBN and LiNbO{sub 3} can be engineered through similar UV irradiation.

  11. Self-optimization of optical confinement in an ultraviolet photonic crystal slab laser.

    PubMed

    Yamilov, A; Wu, X; Liu, X; Chang, R P H; Cao, H

    2006-03-03

    We studied numerically and experimentally the effects of structural disorder on the performance of ultraviolet photonic crystal slab lasers. Optical gain selectively amplifies the high-quality modes of the passive system. For these modes, the in-plane and out-of-plane leakage rates may be automatically balanced in the presence of disorder. The spontaneous optimization of in-plane and out-of-plane confinement of light in a photonic crystal slab may lead to a reduction of the lasing threshold.

  12. Chirped pulse amplification in an extreme-ultraviolet free-electron laser

    PubMed Central

    Gauthier, David; Allaria, Enrico; Coreno, Marcello; Cudin, Ivan; Dacasa, Hugo; Danailov, Miltcho Boyanov; Demidovich, Alexander; Di Mitri, Simone; Diviacco, Bruno; Ferrari, Eugenio; Finetti, Paola; Frassetto, Fabio; Garzella, David; Künzel, Swen; Leroux, Vincent; Mahieu, Benoît; Mahne, Nicola; Meyer, Michael; Mazza, Tommaso; Miotti, Paolo; Penco, Giuseppe; Raimondi, Lorenzo; Ribič, Primož Rebernik; Richter, Robert; Roussel, Eléonore; Schulz, Sebastian; Sturari, Luca; Svetina, Cristian; Trovò, Mauro; Walker, Paul Andreas; Zangrando, Marco; Callegari, Carlo; Fajardo, Marta; Poletto, Luca; Zeitoun, Philippe; Giannessi, Luca; De Ninno, Giovanni

    2016-01-01

    Chirped pulse amplification in optical lasers is a revolutionary technique, which allows the generation of extremely powerful femtosecond pulses in the infrared and visible spectral ranges. Such pulses are nowadays an indispensable tool for a myriad of applications, both in fundamental and applied research. In recent years, a strong need emerged for light sources producing ultra-short and intense laser-like X-ray pulses, to be used for experiments in a variety of disciplines, ranging from physics and chemistry to biology and material sciences. This demand was satisfied by the advent of short-wavelength free-electron lasers. However, for any given free-electron laser setup, a limit presently exists in the generation of ultra-short pulses carrying substantial energy. Here we present the experimental implementation of chirped pulse amplification on a seeded free-electron laser in the extreme-ultraviolet, paving the way to the generation of fully coherent sub-femtosecond gigawatt pulses in the water window (2.3–4.4 nm). PMID:27905401

  13. Chirped pulse amplification in an extreme-ultraviolet free-electron laser

    NASA Astrophysics Data System (ADS)

    Gauthier, David; Allaria, Enrico; Coreno, Marcello; Cudin, Ivan; Dacasa, Hugo; Danailov, Miltcho Boyanov; Demidovich, Alexander; di Mitri, Simone; Diviacco, Bruno; Ferrari, Eugenio; Finetti, Paola; Frassetto, Fabio; Garzella, David; Künzel, Swen; Leroux, Vincent; Mahieu, Benoît; Mahne, Nicola; Meyer, Michael; Mazza, Tommaso; Miotti, Paolo; Penco, Giuseppe; Raimondi, Lorenzo; Ribič, Primož Rebernik; Richter, Robert; Roussel, Eléonore; Schulz, Sebastian; Sturari, Luca; Svetina, Cristian; Trovò, Mauro; Walker, Paul Andreas; Zangrando, Marco; Callegari, Carlo; Fajardo, Marta; Poletto, Luca; Zeitoun, Philippe; Giannessi, Luca; de Ninno, Giovanni

    2016-12-01

    Chirped pulse amplification in optical lasers is a revolutionary technique, which allows the generation of extremely powerful femtosecond pulses in the infrared and visible spectral ranges. Such pulses are nowadays an indispensable tool for a myriad of applications, both in fundamental and applied research. In recent years, a strong need emerged for light sources producing ultra-short and intense laser-like X-ray pulses, to be used for experiments in a variety of disciplines, ranging from physics and chemistry to biology and material sciences. This demand was satisfied by the advent of short-wavelength free-electron lasers. However, for any given free-electron laser setup, a limit presently exists in the generation of ultra-short pulses carrying substantial energy. Here we present the experimental implementation of chirped pulse amplification on a seeded free-electron laser in the extreme-ultraviolet, paving the way to the generation of fully coherent sub-femtosecond gigawatt pulses in the water window (2.3-4.4 nm).

  14. Chirped pulse amplification in an extreme-ultraviolet free-electron laser.

    PubMed

    Gauthier, David; Allaria, Enrico; Coreno, Marcello; Cudin, Ivan; Dacasa, Hugo; Danailov, Miltcho Boyanov; Demidovich, Alexander; Di Mitri, Simone; Diviacco, Bruno; Ferrari, Eugenio; Finetti, Paola; Frassetto, Fabio; Garzella, David; Künzel, Swen; Leroux, Vincent; Mahieu, Benoît; Mahne, Nicola; Meyer, Michael; Mazza, Tommaso; Miotti, Paolo; Penco, Giuseppe; Raimondi, Lorenzo; Ribič, Primož Rebernik; Richter, Robert; Roussel, Eléonore; Schulz, Sebastian; Sturari, Luca; Svetina, Cristian; Trovò, Mauro; Walker, Paul Andreas; Zangrando, Marco; Callegari, Carlo; Fajardo, Marta; Poletto, Luca; Zeitoun, Philippe; Giannessi, Luca; De Ninno, Giovanni

    2016-12-01

    Chirped pulse amplification in optical lasers is a revolutionary technique, which allows the generation of extremely powerful femtosecond pulses in the infrared and visible spectral ranges. Such pulses are nowadays an indispensable tool for a myriad of applications, both in fundamental and applied research. In recent years, a strong need emerged for light sources producing ultra-short and intense laser-like X-ray pulses, to be used for experiments in a variety of disciplines, ranging from physics and chemistry to biology and material sciences. This demand was satisfied by the advent of short-wavelength free-electron lasers. However, for any given free-electron laser setup, a limit presently exists in the generation of ultra-short pulses carrying substantial energy. Here we present the experimental implementation of chirped pulse amplification on a seeded free-electron laser in the extreme-ultraviolet, paving the way to the generation of fully coherent sub-femtosecond gigawatt pulses in the water window (2.3-4.4 nm).

  15. The expansion velocities of laser-produced plasmas determined from extreme ultraviolet spectral line profiles

    NASA Technical Reports Server (NTRS)

    Feldman, U.; Doschek, G. A.; Behring, W. E.; Cohen, L.

    1977-01-01

    The expansion of laser-produced plasma is determined from the shapes of spectral lines of highly ionized iron emitted in the extreme ultraviolet. The plasmas were produced by focusing the pulse from a Nd:glass laser onto solid planar targets, and spectra were recorded with a high-resolution grazing-incidence spectrograph. From the Doppler broadening of lines of Fe XX and Fe XXI, expansion velocities of about 830 km/s were determined. The relative time-averaged ion abundances of Fe XVIII, Fe XIX, Fe XX, and Fe XXI are estimated for three different spectra. The abundances do not differ by more than a factor of 4 for any of the spectra.

  16. Cluster beam targets for laser plasma extreme ultraviolet and soft x-ray sources

    DOEpatents

    Kublak, G.D.; Richardson, M.C.

    1996-11-19

    Method and apparatus for producing extreme ultraviolet (EUV) and soft x-ray radiation from an ultra-low debris plasma source are disclosed. Targets are produced by the free jet expansion of various gases through a temperature controlled nozzle to form molecular clusters. These target clusters are subsequently irradiated with commercially available lasers of moderate intensity (10{sup 11}--10{sup 12} watts/cm{sup 2}) to produce a plasma radiating in the region of 0.5 to 100 nanometers. By appropriate adjustment of the experimental conditions the laser focus can be moved 10--30 mm from the nozzle thereby eliminating debris produced by plasma erosion of the nozzle. 5 figs.

  17. Three-dimensional nanoscale molecular imaging by extreme ultraviolet laser ablation mass spectrometry

    PubMed Central

    Kuznetsov, Ilya; Filevich, Jorge; Dong, Feng; Woolston, Mark; Chao, Weilun; Anderson, Erik H.; Bernstein, Elliot R.; Crick, Dean C.; Rocca, Jorge J.; Menoni, Carmen S.

    2015-01-01

    Analytical probes capable of mapping molecular composition at the nanoscale are of critical importance to materials research, biology and medicine. Mass spectral imaging makes it possible to visualize the spatial organization of multiple molecular components at a sample's surface. However, it is challenging for mass spectral imaging to map molecular composition in three dimensions (3D) with submicron resolution. Here we describe a mass spectral imaging method that exploits the high 3D localization of absorbed extreme ultraviolet laser light and its fundamentally distinct interaction with matter to determine molecular composition from a volume as small as 50 zl in a single laser shot. Molecular imaging with a lateral resolution of 75 nm and a depth resolution of 20 nm is demonstrated. These results open opportunities to visualize chemical composition and chemical changes in 3D at the nanoscale. PMID:25903827

  18. Electron temperature and average density in spherical laser-produced plasmas - Ultraviolet plasma spectroscopy

    NASA Technical Reports Server (NTRS)

    Goldsmith, S.; Seely, J. F.; Feldman, U.; Behring, W. E.; Cohen, L.

    1985-01-01

    The average values of the electron temperature Te and the electron density Ne in the corona plasmas of spherically irradiated high-Z targets have been estimated. Targets composed of the elements Cu through Br, Rb, and Mo were irradiated using the fundamental (1.06 microns) and the frequency-tripled (351 nm) output of the Omega laser system. Spectra were recorded in the wavelength region 15-200 A. Using various extreme ultraviolet spectroscopic techniques, it is found that for the case of a Mo plasma produced by frequency-tripled laser irradiation, Te = 2600 + or - 600 eV and Ne is greater than 6 x 10 to the 20th/cu cm. This is consistent with a 'flux limit' smaller than 0.1. The estimated values of Te and Ne are lower in the corona plasmas produced using the fundamental (1.06 micron) irradiation.

  19. Ultraviolet laser and photodetector of CdZnS/ZnS multiple quantum wells

    NASA Astrophysics Data System (ADS)

    Tauchi, T.; Yamada, Y.; Ohno, T.; Mullins, J. T.; Masumoto, Y.

    1993-09-01

    Ultraviolet (UV) lasers have been constructed for the first time from multiple quantum well (MQW) heterostructures of CdxZn1-xS/ZnS (x=0.11-0.31) strained-layer superlattices. Stimulated emission can be observed either under optical pumping at RT or under pulsed injection at 30 K in the spectral range of 357-390 nm. Structures of the laser were fabricated by the gaseous low-pressure MOCVD method. A spectral narrowing in the emission spectrum with increasing current in the UV injection diode was clearly observed in the vicinity of 375 nm at 30 K. An UV photodetector has been successfully prepared from this MQW system, in which a spectral responsivity at 366 nm exhibits a high efficiency of about 60 mA/W.

  20. Ultraviolet laser and photodetector of CdZnS/ZnS multiple quantum wells

    NASA Astrophysics Data System (ADS)

    Tauchi, T.; Yamada, Y.; Ohno, T.; Mullins, J. T.; Masumoto, Y.

    1993-09-01

    Ultraviolet (UV) lasers have been constructed for the first time from multiple quantum well (MQW) heterostructures of Cd xZn 1- xS/ZnS ( x=0.11-0.31) strained-layer superlattices. Stimulated emission can be observed either under optical pumping at RT or under pulsed injection at 30 K in the spectral range of 357-390 nm. Structures of the laser were fabricated by the gaseous low-pressure MOCVD method. A spectral narrowing in the emission spectrum with increasing current in the UV injection diode was clearly observed in the vicinity of 375 nm at 30 K. An UV photodetector has been successfully prepared from this MQW system, in which a spectral responsivity at 366 nm exhibits a high efficiency of about 60 mA/W.

  1. Determination of Nerve Agent Metabolites by Ultraviolet Femtosecond Laser Ionization Mass Spectrometry.

    PubMed

    Hamachi, Akifumi; Imasaka, Tomoko; Nakamura, Hiroshi; Li, Adan; Imasaka, Totaro

    2017-04-04

    Nerve agent metabolites, i.e., isopropyl methylphosphonic acid (IMPA) and pinacolyl methylphosphonic acid (PMPA), were derivatized by reacting them with 2,3,4,5,6-pentafluorobenzyl bromide (PFBBr) and were determined by mass spectrometry using an ultraviolet femtosecond laser emitting at 267 and 200 nm as the ionization source. The analytes of the derivatized compounds, i.e., IMPA-PFB and PMPA-PFB, contain a large side-chain, and molecular ions are very weak or absent in electron ionization mass spectrometry. The use of ultraviolet femtosecond laser ionization mass spectrometry, however, resulted in the formation of a molecular ion, even for compounds such as these that contain a highly-bulky functional group. The signal intensity was larger at 200 nm due to resonance-enhanced two-photon ionization. In contrast, fragmentation was suppressed at 267 nm (non-resonant two-photon ionization) especially for PMPA-PFB, thus resulting in a lower background signal. This favorable result can be explained by the small excess energy in ionization at 267 nm and by the low-frequency vibrational mode of a bulky trimethylpropyl group in PMPA.

  2. Breaking DNA strands by extreme-ultraviolet laser pulses in vacuum

    NASA Astrophysics Data System (ADS)

    Nováková, Eva; Vyšín, Luděk; Burian, Tomáš; Juha, Libor; Davídková, Marie; Múčka, Viliam; Čuba, Václav; Grisham, Michael E.; Heinbuch, Scott; Rocca, Jorge J.

    2015-04-01

    Ionizing radiation induces a variety of DNA damages including single-strand breaks (SSBs), double-strand breaks (DSBs), abasic sites, modified sugars, and bases. Most theoretical and experimental studies have been focused on DNA strand scissions, in particular production of DNA double-strand breaks. DSBs have been proven to be a key damage at a molecular level responsible for the formation of chromosomal aberrations, leading often to cell death. We have studied the nature of DNA damage induced directly by the pulsed 46.9-nm (26.5 eV) radiation provided by an extreme ultraviolet (XUV) capillary-discharge Ne-like Ar laser (CDL). Doses up to 45 kGy were delivered with a repetition rate of 3 Hz. We studied the dependence of the yield of SSBs and DSBs of a simple model of DNA molecule (pBR322) on the CDL pulse fluence. Agarose gel electrophoresis method was used for determination of both SSB and DSB yields. The action cross sections of the single- and double-strand breaks of pBR322 plasmid DNA in solid state were determined. We observed an increase in the efficiency of strand-break induction in the supercoiled DNA as a function of laser pulse fluence. Results are compared to those acquired at synchrotron radiation facilities and other sources of extreme-ultraviolet and soft x-ray radiation.

  3. Tunable near ultraviolet laser system from a frequency doubled alexandrite laser

    SciTech Connect

    Barnes, N.P.; Gettemy, D.J.; Johnson, T.M.

    1983-09-01

    A laser system which is capable of producing radiation tunable over the region from approximately 0.36-0.40 ..mu.. is described. The laser produces in excess of 5.0 mJ per pulse in a about 0.1 ..mu..s pulse length.

  4. Basic investigation of laser therapy for the ureteral stricture using ultraviolet argon laser and multifiber catheter

    NASA Astrophysics Data System (ADS)

    Daidoh, Yuichiro; Arai, Tsunenori; Murai, Masaru; Suda, Akira; Kikuchi, Makoto; Nakamura, Hiroshi; Komime, Yukikuni; Utsumi, Atsushi

    1992-06-01

    In order to develop new, easy, and safe treatment for urinary tract stricture, we investigated the laser plasty using a combination of an uv Ar laser for ablation and a novel multi-fiber catheter for laser delivery. To investigate the characteristics of the uv Ar laser ablation to ureteral tissue, the experiment in vitro was performed. The ureter was clearly ablated with sufficient thin coagulation layer. The proper laser power for the tissue ablation was about 0.5 W for 0.4 mm core-diameter fiber. The multi-fiber catheter (1.6 mm in outer diameter) consisted of 13 pixels of silica glass fibers (0.2 mm in core diameter) for laser delivery and a through lumen (0.9 mm in inner diameter) for guidewire. The catheter was inserted into a canine ureter under the general anesthesia. The ureter and urinary tract were irradiated using about 0.6 W of laser power at the catheter tip with 40s duration. The irradiated urinary tract tissues were histologically investigated. The ureter was ablated up to the submucosa layer. The urinary tract endotherium was eliminated by the laser ablation without the carbonization. No perforation was found at various irradiation conditions. To investigate the ureteral tissue damage of the uv Ar laser irradiation, the serosa temperature was measured by a thermocouple. The temperature elevation of the serosa could be restricted up to 60 degree(s)C, at which the protein was not coagulated. We concluded that the combination of uv Ra laser and multi-fiber catheter offered easy, reliable therapy for coronary structure.

  5. Droplet-based, high-brightness extreme ultraviolet laser plasma source for metrology

    NASA Astrophysics Data System (ADS)

    Vinokhodov, A. Yu.; Krivokorytov, M. S.; Sidelnikov, Yu. V.; Krivtsun, V. M.; Medvedev, V. V.; Koshelev, K. N.

    2016-10-01

    We report on the development of a high brightness source of extreme ultraviolet radiation (EUV) with a working wavelength of 13.5 nm. The source is based on a laser-produced plasma driven by pulsed radiation of a Nd:YAG laser system. Liquid droplets of Sn-In eutectic alloy were used as the source fuel. The droplets were created by a droplet generator operating in the jet break-up regime. The EUV emission properties of the plasma, including the emission spectrum, time profile, and conversion efficiency of laser radiation into useful 13.5 nm photons, have been characterized. Using the shadowgraphy technique, we demonstrated the production of corpuscular debris by the plasma source and the influence of the plasma on the neighboring droplet targets. The high-frequency laser operation was simulated by usage of the dual pulse regime. Based on the experimental results, we discuss the physical phenomena that could affect the source operation at high repetition rates. Finally, we estimate that an average source brightness of 1.2 kW/mm2 sr is feasible at a high repetition rate.

  6. Diagnosis of energy transport in iron buried layer targets using an extreme ultraviolet laser

    NASA Astrophysics Data System (ADS)

    Shahzad, M.; Culfa, O.; Rossall, A. K.; Wilson, L. A.; Guilbaud, O.; Kazamias, S.; Delmas, O.; Demailly, J.; Maitrallain, A.; Pittman, M.; Baynard, E.; Farjardo, M.; Tallents, G. J.

    2015-02-01

    We demonstrate the use of extreme ultra-violet (EUV) laboratory lasers in probing energy transport in laser irradiated solid targets. EUV transmission through targets containing a thin layer of iron (50 nm) encased in plastic (CH) after irradiation by a short pulse (35 fs) laser focussed to irradiances 3 × 1016 Wcm-2 is measured. Heating of the iron layer gives rise to a rapid decrease in EUV opacity and an increase in the transmission of the 13.9 nm laser radiation as the iron ionizes to Fe5+ and above where the ion ionisation energy is greater than the EUV probe photon energy (89 eV). A one dimensional hydrodynamic fluid code HYADES has been used to simulate the temporal variation in EUV transmission (wavelength 13.9 nm) using IMP opacity values for the iron layer and the simulated transmissions are compared to measured transmission values. When a deliberate pre-pulse is used to preform an expanding plastic plasma, it is found that radiation is important in the heating of the iron layer while for pre-pulse free irradiation, radiation transport is not significant.

  7. Sub-micron period metal lattices fabricated by interfering ultraviolet femtosecond laser processing

    NASA Astrophysics Data System (ADS)

    Nakata, Yoshiki; Matsuba, Yoshiki; Miyanaga, Noriaki

    2016-05-01

    The interference pattern of a femtosecond laser has been utilized to fabricate nanostructures in the lattice. In this paper, SH (second-harmonic) waves (λ = 392.5 {{nm}}) of a femtosecond laser were applied to four beams interfering laser processing using a demagnification system as a beam correlator. The lattice constant of the resultant matrix was shortened to 760 nm. The unit structures fabricated on gold thin films were nanoholes, nanobumps, nanodrops or nanowhiskers, and their unit size was minimized compared to the case with a greater lattice constant formed by fundamental wavelengths. The radius of a nanoball on top of a nanodrop was between 42 and 76 nm, and the radius of metallic hole arrays (MHA) was 220 nm. The energy efficiency of the laser increased by 4.79 times due to better absorption coefficient of gold at ultraviolet wavelengths. In addition, the smallest lattice constant was estimated with the use of a commercial plano-convex fused-silica lens and a NIR (near-infrared) achromatic lens.

  8. Characterization of material ablation driven by laser generated intense extreme ultraviolet light

    SciTech Connect

    Tanaka, Nozomi Masuda, Masaya; Deguchi, Ryo; Murakami, Masakatsu; Fujioka, Shinsuke; Yogo, Akifumi; Nishimura, Hiroaki; Sunahara, Atsushi

    2015-09-14

    We present a comparative study on the hydrodynamic behaviour of plasmas generated by material ablation by the irradiation of nanosecond extreme ultraviolet (EUV or XUV) or infrared laser pulses on solid samples. It was clarified that the difference in the photon energy deposition and following material heating mechanism between these two lights result in the difference in the plasma parameters and plasma expansion characteristics. Silicon plate was ablated by either focused intense EUV pulse (λ = 9–25 nm, 10 ns) or laser pulse (λ = 1064 nm, 10 ns), both with an intensity of ∼10{sup 9 }W/cm{sup 2}. Both the angular distributions and energy spectra of the expanding ions revealed that the photoionized plasma generated by the EUV light differs significantly from that produced by the laser. The laser-generated plasma undergoes spherical expansion, whereas the EUV-generated plasma undergoes planar expansion in a comparatively narrow angular range. It is presumed that the EUV radiation is transmitted through the expanding plasma and directly photoionizes the samples in the solid phase, consequently forming a high-density and high-pressure plasma. Due to a steep pressure gradient along the direction of the target normal, the EUV plasma expands straightforward resulting in the narrower angular distribution observed.

  9. Diagnosis of energy transport in iron buried layer targets using an extreme ultraviolet laser

    SciTech Connect

    Shahzad, M.; Culfa, O.; Rossall, A. K.; Tallents, G. J.; Wilson, L. A.; Guilbaud, O.; Kazamias, S.; Delmas, O.; Demailly, J.; Maitrallain, A.; Pittman, M.; Baynard, E.; Farjardo, M.

    2015-02-15

    We demonstrate the use of extreme ultra-violet (EUV) laboratory lasers in probing energy transport in laser irradiated solid targets. EUV transmission through targets containing a thin layer of iron (50 nm) encased in plastic (CH) after irradiation by a short pulse (35 fs) laser focussed to irradiances 3 × 10{sup 16} Wcm{sup −2} is measured. Heating of the iron layer gives rise to a rapid decrease in EUV opacity and an increase in the transmission of the 13.9 nm laser radiation as the iron ionizes to Fe{sup 5+} and above where the ion ionisation energy is greater than the EUV probe photon energy (89 eV). A one dimensional hydrodynamic fluid code HYADES has been used to simulate the temporal variation in EUV transmission (wavelength 13.9 nm) using IMP opacity values for the iron layer and the simulated transmissions are compared to measured transmission values. When a deliberate pre-pulse is used to preform an expanding plastic plasma, it is found that radiation is important in the heating of the iron layer while for pre-pulse free irradiation, radiation transport is not significant.

  10. Extreme-ultraviolet polarimeter utilizing laser-generated high-order harmonics.

    PubMed

    Brimhall, Nicole; Turner, Matthew; Herrick, Nicholas; Allred, David D; Turley, R Steven; Ware, Michael; Peatross, Justin

    2008-10-01

    We describe an extreme-ultraviolet (EUV) polarimeter that employs laser-generated high-order harmonics as the light source. The polarimeter is designed to characterize materials and thin films for use with EUV light. Laser high harmonics are highly directional with easily rotatable linear polarization, not typically available with other EUV sources. The harmonics have good wavelength coverage, potentially spanning the entire EUV from a few to a hundred nanometers. Our instrument is configured to measure reflectances from 14 to 30 nm and has approximately 180 spectral resolution (lambda/Delta lambda). The reflection from a sample surface can be measured over a continuous range of incident angles (5 degrees-75 degrees). A secondary 14 cm gas cell attenuates the harmonics in a controlled way to keep signals within the linear dynamic range of the detector, comprised of a microchannel plate coupled to a phosphorous screen and charge coupled device camera. The harmonics are produced using approximately 10 mJ, approximately 35 fs, and approximately 800 nm laser pulses with a repetition rate of 10 Hz. Per-shot energy monitoring of the laser discriminates against fluctuations. The polarimeter reflectance data agree well with data obtained at the Advanced Light Source Synchrotron (Beamline 6.3.2).

  11. Two-photon excited whispering-gallery mode ultraviolet laser from an individual ZnO microneedle

    NASA Astrophysics Data System (ADS)

    Zhu, G. P.; Xu, C. X.; Zhu, J.; Lv, C. G.; Cui, Y. P.

    2009-02-01

    Wurtzite structural ZnO microneedles with hexagonal cross section were fabricated by vapor-phase transport method and an individual microneedle was employed as a lasing microcavity. Under excitation of a femtosecond pulse laser with 800 nm wavelength, the ultraviolet (UV) laser emission was obtained, which presented narrow linewidth and high Q value. The UV emission, resonant mechanism, and laser mode characteristics were discussed in detail. The results demonstrated that the UV laser originated from the whispering-gallery mode induced by two-photon absorption assisted by Rabi oscillation.

  12. Optimization of microcrystalline silicon thin film solar cell isolation processing parameters using ultraviolet laser

    NASA Astrophysics Data System (ADS)

    Kuo, Chung-Feng Jeffery; Tu, Hung-Min; Liang, Shin-Wei; Tsai, Wei-Lun

    2010-09-01

    This study used ultraviolet laser to perform the microcrystalline silicon thin film solar cell isolation scribing process, and applied the Taguchi method and an L 18 orthogonal array to plan the experiment. The isolation scribing materials included ZnO:Al, AZO transparent conductive film with a thickness of 200 nm, microcrystalline silicon thin film at 38% crystallinity and of thickness of 500 nm, and the aluminum back contact layer with a thickness of 300 nm. The main objective was to ensure the success of isolation scribing. After laser scribing isolation, using the minimum scribing line width, the flattest trough bottom, and the minimum processing edge surface bumps as the quality characteristics, this study performed main effect analysis and applied the ANOVA (analysis of variance) theory of the Taguchi method to identify the single quality optimal parameter. It then employed the hierarchical structure of the AHP (analytic hierarchy process) theory to establish the positive contrast matrix. After consistency verification, global weight calculation, and priority sequencing, the optimal multi-attribute parameters were obtained. Finally, the experimental results were verified by a Taguchi confirmation experiment and confidence interval calculation. The minimum scribing line width of AZO (200 nm) was 45.6 μm, the minimum scribing line width of the microcrystalline silicon (at 38% crystallinity) was 50.63 μm and the minimum line width of the aluminum thin film (300 nm) was 30.96 μm. The confirmation experiment results were within the 95% confidence interval, verifying that using ultraviolet laser in the isolation scribing process for microcrystalline silicon thin film solar cell has high reproducibility.

  13. Simulation of ultraviolet laser-induced fluorescence LIDAR for detecting bioaerosol

    NASA Astrophysics Data System (ADS)

    Liu, Peng; Zhang, Yinchao; Chen, Siying; Lan, Tian; Wang, Yuzhao; Qiu, Zongjia; Kong, Weiguo; Ni, Guoqiang

    2009-11-01

    The biological warfare agent (BWA) is a kind of terrible threat during the war or raid from the terrorist. Last decade, the interest in utilizing ultraviolet laser-induced fluorescence (UV-LIF) LIDAR to detect the bioaerosol cloud has risen in order to measure the distribution of the bioaerosol particle. The UV-LIF LIDAR system can remotely detect and classify the bioaerosol agents and it is an active detecting system. As the infrared absorbing in the atmosphere is less, the range of infrared remote sensing is very far. The infrared laser at 1064 nm wavelength firstly begins to work in the UV-LIF LIDAR system and the aerosol cloud can be detected at very long range through the elastic backscattering signal from aerosol irradiated by infrared laser. But the category of aerosol can't be identified yet. If the infrared elastic backscattering level exceeds a threshold, UV laser at 355 nm wavelength will be triggered and induce the fluorescence. The excitated spectra of fluorescence can be used for discrimination of different aerosol species and particle concentration. This paper put forward for a UV-LIF LIDAR system model and the principle of the model is described summarily. Then the system parameters are presented and the simulation and analysis of the infrared elastic backscattering and laser-induced fluorescence are made, which is based on these parameters. Raman backscattering signal of Nitrogen gas in the atmosphere generally is taken to reduce measuring error, so the article also simulates this Raman backscatter signal at 387 nm wavelength. The studies above may provide some valuable instructions to the design of a real UV-LIF LIDAR system.

  14. Simulation of particle velocity in a laser-produced tin plasma extreme ultraviolet source

    SciTech Connect

    Masnavi, Majid; Nakajima, Mitsuo; Horioka, Kazuhiko; Araghy, Homaira Parchamy; Endo, Akira

    2011-06-15

    In connection with fast heating in a laser produced plasma (LPP) extreme ultraviolet (EUV) source, the superheating behavior of bulk tin (Sn) at high heating rates is investigated. A constant temperature and pressure molecular dynamics simulation using modified Lennard-Jones and Coulomb potentials suitable for studying the liquid structure of Sn is employed in order to derive the caloric curves of the solid and liquid phases. The results have shown transient effects on the phase transitions. Superheating is observed during the melting and vaporizing processes. The velocity distribution of Sn particles against typical laser fluence in a LPP EUV light source has been numerically investigated using a simplified method including a one-dimensional, two-temperature, molecular dynamics, and steady-state ionization model. In the framework of our model, it was found that ejected Sn particles have a maximum velocity on the order of 10 to 40 km/s in plasma created using a nanosecond pre-pulse neodymium-doped yttrium aluminum garnet (Nd:YAG, 1.06 {mu}m) laser in EUV lithography experiments.

  15. All-solid-state deep ultraviolet laser for single-photon ionization mass spectrometry.

    PubMed

    Yuan, Chengqian; Liu, Xianhu; Zeng, Chenghui; Zhang, Hanyu; Jia, Meiye; Wu, Yishi; Luo, Zhixun; Fu, Hongbing; Yao, Jiannian

    2016-02-01

    We report here the development of a reflectron time-of-flight mass spectrometer utilizing single-photon ionization based on an all-solid-state deep ultraviolet (DUV) laser system. The DUV laser was achieved from the second harmonic generation using a novel nonlinear optical crystal KBe2BO3F2 under the condition of high-purity N2 purging. The unique property of this laser system (177.3-nm wavelength, 15.5-ps pulse duration, and small pulse energy at ∼15 μJ) bears a transient low power density but a high single-photon energy up to 7 eV, allowing for ionization of chemicals, especially organic compounds free of fragmentation. Taking this advantage, we have designed both pulsed nanospray and thermal evaporation sources to form supersonic expansion molecular beams for DUV single-photon ionization mass spectrometry (DUV-SPI-MS). Several aromatic amine compounds have been tested revealing the fragmentation-free performance of the DUV-SPI-MS instrument, enabling applications to identify chemicals from an unknown mixture.

  16. Spectroscopic study of debris mitigation with minimum-mass Sn laser plasma for extreme ultraviolet lithography

    SciTech Connect

    Namba, S.; Fujioka, S.; Nishimura, H.; Yasuda, Y.; Nagai, K.; Miyanaga, N.; Izawa, Y.; Mima, K.; Takiyama, K.

    2006-04-24

    An experimental study was made of a target consisting of the minimum mass of pure tin (Sn) necessary for the highest conversion to extreme ultraviolet (EUV) light while minimizing the generation of plasma debris. The minimum-mass target comprised a thin Sn layer coated on a plastic shell and was irradiated with a Nd:YAG laser pulse. The expansion behavior of neutral atoms and singly charged ions emanating from the Sn plasma were investigated by spatially resolved visible spectroscopy. A remarkable reduction of debris emission in the backward direction with respect to the incident laser beam was demonstrated with a decrease in the thickness of the Sn layer. The optimal thickness of the Sn layer for a laser pulse of 9 ns at 7x10{sup 10} W/cm{sup 2} was found to be 40 nm, at which low-debris emission in the backward direction and a high conversion to 13.5 nm EUV radiation were simultaneously attained.

  17. On the role of chemical reactions in initiating ultraviolet laser ablation in poly(methyl methacrylate)

    SciTech Connect

    Prasad, Manish; Conforti, Patrick F.; Garrison, Barbara J.

    2007-05-15

    The role of chemical reactions is investigated versus the thermal and mechanical processes occurring in a polymer substrate during irradiation by a laser pulse and subsequent ablation. Molecular dynamics simulations with an embedded Monte Carlo based reaction scheme were used to study ultraviolet ablation of poly(methyl methacrylate) at 157 nm. We discuss the onset of ablation, the mechanisms leading to ablation, and the role of stress relaxation of the polymer matrix during ablation. Laser induced heating and chemical decomposition of the polymer substrate are considered as ablation pathways. It is shown that heating the substrate can set off ablation via mechanical failure of the material only for very short laser pulses. For longer pulses, the mechanism of ejection is thermally driven limited by the critical number of bonds broken in the substrate. Alternatively, if the photon energy goes towards direct bond breaking, it initiates chemical reactions, polymer unzipping, and formation of gaseous products, leading to a nearly complete decomposition of the top layers of substrates. The ejection of small molecules has a hollowing out effect on the weakly connected substrates which can lead to lift-off of larger chunks. Excessive pressure buildup upon the creation of gaseous molecules does not lead to enhanced yield. The larger clusters are thermally ejected, and an entrainment of larger polymer fragments in gaseous molecules is not observed.

  18. Infrared-laser-assisted photoionization of helium by coherent extreme ultraviolet light

    SciTech Connect

    Tong Xiaomin; Toshima, Nobuyuki

    2010-04-15

    We investigate the infrared (IR)-laser-assisted photoionization of He by a coherent extreme ultraviolet (euv) light solving the time-dependent Schroedinger equation. A combined field of the 13th and 15th harmonics created from the same IR laser source is used to ionize He atoms coherently. We show that the ionization probabilities oscillate as a function of the time delay between the IR and the euv pulses. On the other hand, the oscillation amplitude increases as the IR intensity increases, reaches a maximum when the IR intensity is around 6x10{sup 12} W/cm{sup 2}, and then decreases as the IR intensity increases further. Decomposing the ionization probabilities by the 13th and 15th harmonics, we illustrate that the oscillation amplitude is small for a lower IR laser intensity due to the fact that the transition strength by the 13th harmonic is much smaller than the one by the 15th harmonic. When the IR intensity increases further above 6x10{sup 12} W/cm{sup 2}, the transition strength by the 13th harmonic becomes larger than the one by the 15th harmonic and the oscillation amplitude is reduced again. By tuning the relative field strengths of the 13th and 15th harmonics or the IR intensity, we can control the oscillation amplitude.

  19. Simulation of particle velocity in a laser-produced tin plasma extreme ultraviolet source

    NASA Astrophysics Data System (ADS)

    Masnavi, Majid; Nakajima, Mitsuo; Horioka, Kazuhiko; Araghy, Homaira Parchamy; Endo, Akira

    2011-06-01

    In connection with fast heating in a laser produced plasma (LPP) extreme ultraviolet (EUV) source, the superheating behavior of bulk tin (Sn) at high heating rates is investigated. A constant temperature and pressure molecular dynamics simulation using modified Lennard-Jones and Coulomb potentials suitable for studying the liquid structure of Sn is employed in order to derive the caloric curves of the solid and liquid phases. The results have shown transient effects on the phase transitions. Superheating is observed during the melting and vaporizing processes. The velocity distribution of Sn particles against typical laser fluence in a LPP EUV light source has been numerically investigated using a simplified method including a one-dimensional, two-temperature, molecular dynamics, and steady-state ionization model. In the framework of our model, it was found that ejected Sn particles have a maximum velocity on the order of 10 to 40 km/s in plasma created using a nanosecond pre-pulse neodymium-doped yttrium aluminum garnet (Nd:YAG, 1.06 μm) laser in EUV lithography experiments.

  20. All-solid-state deep ultraviolet laser for single-photon ionization mass spectrometry

    NASA Astrophysics Data System (ADS)

    Yuan, Chengqian; Liu, Xianhu; Zeng, Chenghui; Zhang, Hanyu; Jia, Meiye; Wu, Yishi; Luo, Zhixun; Fu, Hongbing; Yao, Jiannian

    2016-02-01

    We report here the development of a reflectron time-of-flight mass spectrometer utilizing single-photon ionization based on an all-solid-state deep ultraviolet (DUV) laser system. The DUV laser was achieved from the second harmonic generation using a novel nonlinear optical crystal KBe2BO3F2 under the condition of high-purity N2 purging. The unique property of this laser system (177.3-nm wavelength, 15.5-ps pulse duration, and small pulse energy at ˜15 μJ) bears a transient low power density but a high single-photon energy up to 7 eV, allowing for ionization of chemicals, especially organic compounds free of fragmentation. Taking this advantage, we have designed both pulsed nanospray and thermal evaporation sources to form supersonic expansion molecular beams for DUV single-photon ionization mass spectrometry (DUV-SPI-MS). Several aromatic amine compounds have been tested revealing the fragmentation-free performance of the DUV-SPI-MS instrument, enabling applications to identify chemicals from an unknown mixture.

  1. Ultraviolet light and laser irradiation enhances the antibacterial activity of glucosamine-functionalized gold nanoparticles

    PubMed Central

    Govindaraju, Saravanan; Ramasamy, Mohankandhasamy; Baskaran, Rengarajan; Ahn, Sang Jung; Yun, Kyusik

    2015-01-01

    Here we report a novel method for the synthesis of glucosamine-functionalized gold nanoparticles (GlcN-AuNPs) using biocompatible and biodegradable glucosamine for antibacterial activity. GlcN-AuNPs were prepared using different concentrations of glucosamine. The synthesized AuNPs were characterized for surface plasmon resonance, surface morphology, fluorescence spectroscopy, and antibacterial activity. The minimum inhibitory concentrations (MICs) of the AuNPs, GlcN-AuNPs, and GlcN-AuNPs when irradiated by ultraviolet light and laser were investigated and compared with the MIC of standard kanamycin using Escherichia coli by the microdilution method. Laser-irradiated GlcN-AuNPs exhibited significant bactericidal activity against E. coli. Flow cytometry and fluorescence microscopic analysis supported the cell death mechanism in the presence of GlcN-AuNP-treated bacteria. Further, morphological changes in E. coli after laser treatment were investigated using atomic force microscopy and transmission electron microscopy. The overall results of this study suggest that the prepared nanoparticles have potential as a potent antibacterial agent for the treatment of a wide range of disease-causing bacteria. PMID:26345521

  2. Amplification properties of vacuum ultraviolet Ar2* produced by infrared high-intensity laser

    NASA Astrophysics Data System (ADS)

    Kaku, Masanori; Harano, Shinya; Matsumoto, Ryota; Katto, Masahito; Kubodera, Shoichi

    2011-07-01

    We report optical amplification of Ar2* at 126nm, pumped by optical-field-induced ionization (OFI) created by an infrared high-intensity laser. A gain--length product of 0.84 was obtained by using multipass amplification with a vacuum ultraviolet (VUV) cavity. The gain--length product was increased up to 4.3 through the use of single-pass amplification with a VUV reflector and a hollow 5.0cm-long fiber. Similar small signal gain coefficients of 0.84 and 0.86cm-1 were obtained in two different experiments, in which OFI Ar plasma gain media were produced in free space filled with Ar and inside an Ar-filled hollow fiber.

  3. Ultraviolet laser spectroscopy of neutral mercury in a one-dimensional optical lattice

    SciTech Connect

    Mejri, S.; McFerran, J. J.; Yi, L.; Le Coq, Y.; Bize, S.

    2011-09-15

    We present details on the ultraviolet lattice spectroscopy of the (6s{sup 2}) {sup 1}S{sub 0}{r_reversible} (6s6p) {sup 3}P{sub 0} transition in neutral mercury, specifically {sup 199}Hg. Mercury atoms are loaded into a one-dimensional vertically aligned optical lattice from a magneto-optical trap with an rms temperature of {approx}60 {mu}K. We describe aspects of the magneto-optical trapping, the lattice cavity design, and the techniques employed to trap and detect mercury in an optical lattice. The clock-line frequency dependence on lattice depth is measured at a range of lattice wavelengths. We confirm the magic wavelength to be 362.51(0.16) nm. Further observations to those reported by Yi et al.[Phys. Rev. Lett. 106, 073005 (2011)] are presented regarding the laser excitation of a Wannier-Stark ladder of states.

  4. Resonant two-photon absorption of extreme-ultraviolet free-electron-laser radiation in helium

    SciTech Connect

    Nagasono, Mitsuru; Suljoti, Edlira; Pietzsch, Annette; Hennies, Franz; Wellhoefer, Michael; Hoeft, Jon-Tobias; Martins, Michael; Wurth, Wilfried; Foehlisch, Alexander; Treusch, Rolf; Feldhaus, Josef; Schneider, Jochen R.

    2007-05-15

    We have investigated the nonlinear response of helium to intense extreme-ultraviolet radiation from the free-electron laser in Hamburg (FLASH). We observe a spectral feature between 24 and 26 eV electron kinetic energy in photoemission which shows a quadratic fluence dependence. The feature is explained as a result of subsequent processes involving a resonant two-photon absorption process into doubly excited levels of even parity (N=5 and 6), radiative decay to the doubly excited states in the vicinity of the He{sup +} (N=2) ionization threshold and finally the photoionization of the inner electron by the radiation of the next microbunches. This observation suggests that even-parity states, which have been elusive to be measured with the low pulse energy of synchrotron radiation sources, can be investigated with the intense radiation of FLASH. This also demonstrates a first step to bring nonlinear spectroscopy into the xuv and soft-x-ray regime.

  5. A desktop extreme ultraviolet microscope based on a compact laser-plasma light source

    NASA Astrophysics Data System (ADS)

    Wachulak, P. W.; Torrisi, A.; Bartnik, A.; Węgrzyński, Ł.; Fok, T.; Fiedorowicz, H.

    2017-01-01

    A compact, desktop size microscope, based on laser-plasma source and equipped with reflective condenser and diffractive Fresnel zone plate objective, operating in the extreme ultraviolet (EUV) region at the wavelength of 13.8 nm, was developed. The microscope is capable of capturing magnified images of objects with 95-nm full-pitch spatial resolution (48 nm 25-75% KE) and exposure time as low as a few seconds, combining reasonable acquisition conditions with stand-alone desktop footprint. Such EUV microscope can be regarded as a complementary imaging tool to already existing, well-established ones. Details about the microscope, characterization, resolution estimation and real sample images are presented and discussed.

  6. Vacuum ultraviolet spectral emission properties of Ga, In and Sn droplet-based laser produced plasmas

    NASA Astrophysics Data System (ADS)

    Gambino, Nadia; Rollinger, Bob; Brandstätter, Markus; Abhari, Reza S.

    2016-08-01

    The Emission Spectra of gallium, indium and tin droplet-based laser produced plasmas are presented in the Vacuum Ultraviolet (VUV) emission range from 30 nm to 160 nm. The Ga ion transitions are investigated in detail as a function of background pressure level and laser irradiance. Different wavelength emission regions were detected according to the level of background gas. At short wavelengths (i.e. 30-50 nm) the line emission from the higher charge states is reduced with increasing pressure, while at longer wavelengths (i.e. 100-160 nm) the trend is inverted, as the plasma emission intensity of the lower charge states increases with higher background gas pressure level. The emitted lines are fitted with Voigt profiles to determine the electron density. The electron temperature is obtained from a fit based on the Planck distribution. These estimations are then used to identify the relevant processes that lead to the different charge state emissions as a function of background gas. Langmuir Probe measurements are also reported for evaluating the ion kinetic energy as a function of background gas. The gallium spectra are calibrated in units of spectral radiance, together with spectra from indium and tin. This calibration allows absolute power estimations from the light source in the VUV region. The presented experimental results are relevant as fundamental plasma emission spectroscopic measurements in an almost unexplored wavelength region as well as for applications such as Extreme Ultraviolet Lithography to determine the so-called Out-of-Band (OoB) radiation emission and for metrology applications for future inspection tools.

  7. Effects of the dynamics of droplet-based laser-produced plasma on angular extreme ultraviolet emission profile

    SciTech Connect

    Giovannini, Andrea Z.; Abhari, Reza S.

    2014-05-12

    The emission distribution of extreme ultraviolet (EUV) radiation from droplet targets is dependent on the dynamics of the laser-produced plasma. The EUV emission is measured on a 2% bandwidth centered at 13.5 nm (in-band). The targets of the laser are small (sub-50 μm) tin droplets, and the in-band emission distribution is measured for different laser irradiances and droplet sizes at various angular positions. Larger droplets lead to a faster decay of EUV emission at larger angles with respect to the laser axis. A decrease in laser irradiance has the opposite effect. The measurements are used together with an analytical model to estimate plume dynamics. Additionally, the model is used to estimate EUV emission distribution for a desired droplet diameter and laser irradiance.

  8. Comparison of ultraviolet femtosecond and nanosecond laser ablation inductively coupled plasma mass spectrometry analysis in glass, monazite, and zircon.

    PubMed

    Poitrasson, Franck; Mao, Xianglei; Mao, Samuel S; Freydier, Rémi; Russo, Richard E

    2003-11-15

    We compared the analytical performance of ultraviolet femtosecond and nanosecond laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS). The benefit of ultrafast lasers was evaluated regarding thermal-induced chemical fractionation, that is otherwise well known to limit LA-ICPMS. Both lasers had a Gaussian beam energy profile and were tested using the same ablation system and ICPMS analyzer. Resulting crater morphologies and analytical signals showed more straightforward femtosecond laser ablation processes, with minimal thermal effects. Despite a less stable energy output, the ultrafast laser yielded elemental (Pb/U, Pb/Th) and Pb isotopic ratios that were more precise, repeatable, and accurate, even when compared to the best analytical conditions for the nanosecond laser. Measurements on NIST glasses, monazites, and zircon also showed that femtosecond LA-ICPMS calibration was less matrix-matched dependent and therefore more versatile.

  9. Efficient extreme ultraviolet plasma source generated by a CO{sub 2} laser and a liquid xenon microjet target

    SciTech Connect

    Ueno, Yoshifumi; Ariga, Tatsuya; Soumagne, George; Higashiguchi, Takeshi; Kubodera, Shoichi; Pogorelsky, Igor; Pavlishin, Igor; Stolyarov, Daniil; Babzien, Marcus; Kusche, Karl; Yakimenko, Vitaly

    2007-05-07

    We demonstrated efficacy of a CO{sub 2}-laser-produced xenon plasma in the extreme ultraviolet (EUV) spectral region at 13.5 nm at variable laser pulse widths between 200 ps and 25 ns. The plasma target was a 30 {mu}m liquid xenon microjet. To ensure the optimum coupling of CO{sub 2} laser energy with the plasma, they applied a prepulse yttrium aluminum garnet laser. The authors measured the conversion efficiency (CE) of the 13.5 nm EUV emission for different pulse widths of the CO{sub 2} laser. A maximum CE of 0.6% was obtained for a CO{sub 2} laser pulse width of 25 ns at an intensity of 5x10{sup 10} W/cm{sup 2}.

  10. Spatial characterization of extreme ultraviolet plasmas generated by laser excitation of xenon gas targets

    NASA Astrophysics Data System (ADS)

    Kranzusch, Sebastian; Peth, Christian; Mann, Klaus

    2003-02-01

    At Laser-Laboratorium Göttingen laser-plasma sources were tested, which are going to be used for characterization of optical components and sensoric devices in the wavelength region from 11 to 13 nm. In all cases extreme ultraviolet (EUV) radiation is generated by focusing a Q-switched Nd:YAG laser into a pulsed gas puff target. By the use of xenon or oxygen as target gas, broadband as well as narrowband EUV radiation is obtained, respectively. Different types of valves and nozzles were tested in order to optimize the emitted radiation with respect to maximum EUV intensities, small source diameters, and positional stability. The investigation of these crucial source parameters was performed with specially designed EUV pinhole cameras, utilizing evaluation algorithms developed for standardized laser beam characterization. In addition, a rotatable pinhole camera was developed which allows both spatially and angular resolved monitoring of the soft x-ray emission characteristics. With the help of this camera a strong angular dependence of the EUV intensity was found. The data were compared with fluorescence measurements for visualization of the target gas jet. The experimental observations can be explained by reabsorption of the generated EUV radiation in the surrounding target gas, as supported by semiempirical model calculations based on the attenuation in the three-dimensional gas density according to Lambert-Beer's law. As a consequence of the presented investigations, an optimization of the EUV source with respect to intensity, plasma shape, and angular dependence is achieved, resulting in a spherical plasma of 200 μm diameter and a 50% increase of the EUV pulse energy.

  11. Finite element simulation for ultraviolet excimer laser processing of patterned Si/SiGe/Si(100) heterostructures

    SciTech Connect

    Conde, J. C.; Chiussi, S.; Gontad, F.; Gonzalez, P.; Martin, E.; Serra, C.

    2010-07-05

    Ultraviolet (UV) Excimer laser assisted processing is an alternative strategy for producing patterned silicon germanium heterostructures. We numerically analyzed the effects caused by pulsed 193 Excimer laser radiation impinging on patterned amorphous hydrogenated silicon (a-Si:H) and germanium (a-Ge:H) bilayers deposited on a crystalline silicon substrate [Si(100)]. The proposed two dimensional axisymmetric numerical model allowed us to estimate the temperature and concentration gradients caused by the laser induced rapid melting and solidification processes. Energy density dependence of maximum melting depth and melting time evolution as well as three dimensional temperature and element distribution have been simulated and compared with experimentally obtained results.

  12. Acceleration of a solid-density plasma projectile to ultrahigh velocities by a short-pulse ultraviolet laser

    SciTech Connect

    Badziak, J.; Jablonski, S.

    2011-08-15

    It is shown by means of particle-in-cell simulations that a high-fluence ({>=}1 GJ/cm{sup 2}) solid-density plasma projectile can be accelerated up to sub-relativistic velocities by radiation pressure of an ultraviolet (UV) picosecond laser pulse of moderate values of dimensionless laser amplitude a{sub 0}{approx}10. The efficiency of acceleration by the UV laser is significantly higher than in the case of long-wavelength ({lambda} {approx} 1 {mu}m) driver of a comparable value of a{sub 0}, and the motion of the projectile is fairly well described by the ''Light Sail'' acceleration model.

  13. Considerations for a free-electron laser-based extreme-ultraviolet lithography program

    NASA Astrophysics Data System (ADS)

    Hosler, Erik R.; Wood, Obert R.; Barletta, William A.; Mangat, Pawitter J. S.; Preil, Moshe E.

    2015-03-01

    Recent years have seen great strides in the development of extreme ultraviolet (EUV) laser-produced plasma sources. Field deployed EUV exposure tools are now capable of facilitating advanced technology node development. Nevertheless, as the required manufacturing exposure dose scales, EUV sources must follow suit and provide 500- 1000 W to maintain production throughputs. A free-electron laser (FEL) offers a cost effective, single-source alternative for powering an entire EUV lithography program. FEL integration into semiconductor fab architecture will require both unique facility considerations as well as a paradigm shift in lithography operations. Critical accelerator configurations relating to energy recovery, multi-turn acceleration, and operational mode are discussed from engineering/scientific, cost-minimization, and safety perspectives. Furthermore, the individual components of a FEL (electron injector, RF systems, undulator, etc.) are examined with respect to both design and cost, considering existing technology as well as prospective innovations. Finally, FEL development and deployment roadmaps are presented, focusing on manufacturer deployment for the 5 nm or 3 nm technology nodes.[1-3

  14. Simple locking of infrared and ultraviolet diode lasers to a visible laser using a LabVIEW proportional-integral-derivative controller on a Fabry-Perot signal.

    PubMed

    Kwolek, J M; Wells, J E; Goodman, D S; Smith, W W

    2016-05-01

    Simultaneous laser locking of infrared (IR) and ultraviolet lasers to a visible stabilized reference laser is demonstrated via a Fabry-Perot (FP) cavity. LabVIEW is used to analyze the input, and an internal proportional-integral-derivative algorithm converts the FP signal to an analog locking feedback signal. The locking program stabilized both lasers to a long term stability of better than 9 MHz, with a custom-built IR laser undergoing significant improvement in frequency stabilization. The results of this study demonstrate the viability of a simple, computer-controlled, non-temperature-stabilized FP locking scheme for our applications, laser cooling of Ca(+) ions, and its use in other applications with similar modest frequency stabilization requirements.

  15. Simple locking of infrared and ultraviolet diode lasers to a visible laser using a LabVIEW proportional-integral-derivative controller on a Fabry-Perot signal

    NASA Astrophysics Data System (ADS)

    Kwolek, J. M.; Wells, J. E.; Goodman, D. S.; Smith, W. W.

    2016-05-01

    Simultaneous laser locking of infrared (IR) and ultraviolet lasers to a visible stabilized reference laser is demonstrated via a Fabry-Perot (FP) cavity. LabVIEW is used to analyze the input, and an internal proportional-integral-derivative algorithm converts the FP signal to an analog locking feedback signal. The locking program stabilized both lasers to a long term stability of better than 9 MHz, with a custom-built IR laser undergoing significant improvement in frequency stabilization. The results of this study demonstrate the viability of a simple, computer-controlled, non-temperature-stabilized FP locking scheme for our applications, laser cooling of Ca+ ions, and its use in other applications with similar modest frequency stabilization requirements.

  16. Electronic sideband locking of a broadly tunable 318.6 nm ultraviolet laser to an ultra-stable optical cavity

    NASA Astrophysics Data System (ADS)

    Bai, Jiandong; Wang, Jieying; He, Jun; Wang, Junmin

    2017-04-01

    We demonstrate frequency stabilization of a tunable 318.6 nm ultraviolet (UV) laser system using electronic sideband locking. By indirectly changing the frequency of a broadband electro-optic phase modulator, the laser can be continuously tuned over 4 GHz, while a 637.2 nm laser is directly stabilized to a high-finesse ultra-stable optical cavity. The doubling cavity also remains locked to the 637.2 nm light. We show that the tuning range depends mainly on the gain-flattening region of the modulator and the piezo-tunable range of the seed laser. The frequency-stabilized tunable UV laser system is able to compensate for the offset between reference and target frequencies, and has potential applications in precision spectroscopy of cold atoms.

  17. Progress in coherent lithography using table-top extreme ultraviolet lasers

    NASA Astrophysics Data System (ADS)

    Li, Wei

    Nanotechnology has drawn a wide variety of attention as interesting phenomena occurs when the dimension of the structures is in the nanometer scale. The particular characteristics of nanoscale structures had enabled new applications in different fields in science and technology. Our capability to fabricate these nanostructures routinely for sure will impact the advancement of nanoscience. Apart from the high volume manufacturing in semiconductor industry, a small-scale but reliable nanofabrication tool can dramatically help the research in the field of nanotechnology. This dissertation describes alternative extreme ultraviolet (EUV) lithography techniques which combine table-top EUV laser and various cost-effective imaging strategies. For each technique, numerical simulations, system design, experiment result and its analysis will be presented. In chapter II, a brief review of the main characteristics of table-top EUV lasers will be addressed concentrating on its high power and large coherence radius that enable the lithography application described herein. The development of a Talbot EUV lithography system which is capable of printing 50nm half pitch nanopatterns will be illustrated in chapter III. A detailed discussion of its resolution limit will be presented followed by the development of X-Y-Z positioning stage, the fabrication protocol for diffractive EUV mask, and the pattern transfer using self- developed ion beam etching, and the dose control unit. In addition, this dissertation demonstrated the capability to fabricate functional periodic nanostructures using Talbot EUV lithography. After that, resolution enhancement techniques like multiple exposure, displacement Talbot EUV lithography, fractional Talbot EUV lithography, and Talbot lithography using 18.9nm amplified spontaneous emission laser will be demonstrated. Chapter IV will describe a hybrid EUV lithography which combines the Talbot imaging and interference lithography rendering a high resolution

  18. High stable, high efficient ultraviolet laser with angle-phase-mismatching compensation by adjusting temperature of the nonlinear crystals

    NASA Astrophysics Data System (ADS)

    Yang, Houwen; Wang, Bo; Wang, Junhua; Li, Xiaofang; Liu, Zhaojun; Cheng, Wenyong

    2017-03-01

    We demonstrated an ultraviolet laser at 355 nm using a type-I and a type-II phase-matching nonlinear optical crystal of LiB3O5 (LBO). A method of adjusting temperature for compensation is presented. The crystal temperature is controlled by proportional integral derivative (PID) thermal controllers with a  ±0.01 °C resolution. The value of wave vector mismatch, distance of light propagation in nonlinear crystals, effective nonlinear coefficient, theoretical analysis and calculation of conversion efficiency versus temperature are discussed. The experimental results show that the average output power of the 355 nm laser is 1.24 W with the pump power of 13.33 W, when the repetition frequency is 15 kHz. The pulse duration is 9.8 ns, and the beam quality factors are of Mx2   =  1.8, My2   =  1.7. The conversion efficiency from 808 nm to 355 nm laser is 9.3%, which nearly reaches the optimum value reported so far and is limited by the wavelength mismatch between the pumping and absorbing lasers. The 355 nm output power instability of the laser device is 0.45% in 2 h. A compact no-water-cooling ultraviolet laser with high stability and high efficiency is obtained.

  19. Measurements of electron and proton heating temperatures from extreme-ultraviolet light images at 68 eV in petawatt laser experiments

    SciTech Connect

    Gu Peimin; Zhang, B.; Key, M. H.; Hatchett, S. P.; Barbee, T.; Freeman, R. R.; Akli, K.; Hey, D.; King, J. A.; Mackinnon, A. J.; Snavely, R. A.; Stephens, R. B.

    2006-11-15

    A 68 eV extreme-ultraviolet light imaging diagnostic measures short pulse isochoric heating by electrons and protons in petawatt laser experiments. Temperatures are deduced from the absolute intensities and comparison with modeling using a radiation hydrodynamics code.

  20. Laser-produced lithium plasma as a narrow-band extended ultraviolet radiation source for photoelectron spectroscopy.

    PubMed

    Schriever, G; Mager, S; Naweed, A; Engel, A; Bergmann, K; Lebert, R

    1998-03-01

    Extended ultraviolet (EUV) emission characteristics of a laser-produced lithium plasma are determined with regard to the requirements of x-ray photoelectron spectroscopy. The main features of interest are spectral distribution, photon flux, bandwidth, source size, and emission duration. Laser-produced lithium plasmas are characterized as emitters of intense narrow-band EUV radiation. It can be estimated that the lithium Lyman-alpha line emission in combination with an ellipsoidal silicon/molybdenum multilayer mirror is a suitable EUV source for an x-ray photoelectron spectroscopy microscope with a 50-meV energy resolution and a 10-mum lateral resolution.

  1. Nonthermal phase transitions in semiconductors induced by a femtosecond extreme ultraviolet laser pulse

    NASA Astrophysics Data System (ADS)

    Medvedev, Nikita; Jeschke, Harald O.; Ziaja, Beata

    2013-01-01

    In this paper, we present a novel theoretical approach, which allows the study of nonequilibrium dynamics of both electrons and atoms/ions within free-electron laser excited semiconductors at femtosecond time scales. The approach consists of the Monte-Carlo method treating photoabsorption, high-energy-electron and core-hole kinetics and relaxation processes. Low-energy electrons localized within the valence and conduction bands of the target are treated with a temperature equation, including source terms, defined by the exchange of energy and particles with high-energy electrons and atoms. We follow the atomic motion with the molecular dynamics method on the changing potential energy surface. The changes of the potential energy surface and of the electron band structure are calculated at each time step with the help of the tight-binding method. Such a combination of methods enables investigation of nonequilibrium structural changes within materials under extreme ultraviolet (XUV) femtosecond irradiation. Our analysis performed for diamond irradiated with an XUV femtosecond laser pulse predicts for the first time in this wavelength regime the nonthermal phase transition from diamond to graphite. Similar to the case of visible light irradiation, this transition takes place within a few tens of femtoseconds and is caused by changes of the interatomic potential induced by ultrafast electronic excitations. It thus occurs well before the heating stimulated by electron-phonon coupling starts to play a role. This allows us to conclude that this transition is nonthermal and represents a general mechanism of the response of solids to ultrafast electron excitations.

  2. Extreme ultraviolet spectroscopy and modeling of Cu on the SSPX Spheromak and laser plasma 'Sparky'

    SciTech Connect

    Weller, M. E.; Safronova, A. S.; Kantsyrev, V. L.; Safronova, U. I.; Petkov, E. E.; Wilcox, P. G.; Osborne, G. C.; Clementson, J.; Beiersdorfer, P.

    2012-10-15

    Impurities play a critical role in magnetic fusion research. In large quantities, impurities can cool and dilute plasma creating problems for achieving ignition and burn; however in smaller amounts the impurities could provide valuable information about several plasma parameters through the use of spectroscopy. Many impurity ions radiate within the extreme ultraviolet (EUV) range. Here, we report on spectra from the silver flat field spectrometer, which was implemented at the Sustained Spheromak Physics experiment (SSPX) to monitor ion impurity emissions. The chamber within the SSPX was made of Cu, which makes M-shell Cu a prominent impurity signature. The Spect3D spectral analysis code was utilized to identify spectral features in the range of 115-315 A and to more fully understand the plasma conditions. A second set of experiments was carried out on the compact laser-plasma x-ray/EUV facility 'Sparky' at UNR, with Cu flat targets used. The EUV spectra were recorded between 40-300 A and compared with results from SSPX.

  3. Effective interface state effects in hydrogenated amorphous-crystalline silicon heterostructures using ultraviolet laser photocarrier radiometry

    SciTech Connect

    Melnikov, A.; Mandelis, A.; Halliop, B.; Kherani, N. P.

    2013-12-28

    Ultraviolet photocarrier radiometry (UV-PCR) was used for the characterization of thin-film (nanolayer) intrinsic hydrogenated amorphous silicon (i-a-Si:H) on c-Si. The small absorption depth (approximately 10 nm at 355 nm laser excitation) leads to strong influence of the nanolayer parameters on the propagation and recombination of the photocarrier density wave (CDW) within the layer and the substrate. A theoretical PCR model including the presence of effective interface carrier traps was developed and used to evaluate the transport parameters of the substrate c-Si as well as those of the i-a-Si:H nanolayer. Unlike conventional optoelectronic characterization methods such as photoconductance, photovoltage, and photoluminescence, UV-PCR can be applied to more complete quantitative characterization of a-Si:H/c-Si heterojunction solar cells, including transport properties and defect structures. The quantitative results elucidate the strong effect of a front-surface passivating nanolayer on the transport properties of the entire structure as the result of effective a-Si:H/c-Si interface trap neutralization through occupation. A further dramatic improvement of those properties with the addition of a back-surface passivating nanolayer is observed and interpreted as the result of the interaction of the increased excess bulk CDW with, and more complete occupation and neutralization of, effective front interface traps.

  4. Stable droplet generator for a high brightness laser produced plasma extreme ultraviolet source

    NASA Astrophysics Data System (ADS)

    Vinokhodov, A.; Krivokorytov, M.; Sidelnikov, Yu.; Krivtsun, V.; Medvedev, V.; Bushuev, V.; Koshelev, K.; Glushkov, D.; Ellwi, S.

    2016-10-01

    We present the results of the low-melting liquid metal droplets generation based on excited Rayleigh jet breakup. We discuss on the operation of the industrial and in-house designed and manufactured dispensing devices for the droplets generation. Droplet diameter can be varied in the range of 30-90 μm. The working frequency of the droplets, velocity, and the operating temperature were in the ranges of 20-150 kHz, 4-15 m/s, and up to 250 °C, respectively. The standard deviations for the droplet center of mass position both their diameter σ < 1 μm at the distance of 45 mm from the nozzle. Stable operation in the long-term (over 1.5 h) was demonstrated for a wide range of the droplet parameters: diameters, frequencies, and velocities. Physical factors affecting the stability of the generator operation have been identified. The technique for droplet synchronization, allowing using the droplet as a target for laser produced plasma, has been created; in particular, the generator has been successfully used in a high brightness extreme ultraviolet (EUV) light source. The operation with frequency up to 8 kHz was demonstrated as a result of the experimental simulation, which can provide an average brightness of the EUV source up to ˜1.2 kW/mm2 sr.

  5. Control of the polarization of a vacuum-ultraviolet, high-gain, free-electron laser

    DOE PAGES

    Allaria, Enrico; Diviacco, Bruno; Callegari, Carlo; ...

    2014-12-02

    The two single-pass, externally seeded free-electron lasers (FELs) of the FERMI user facility are designed around Apple-II-type undulators that can operate at arbitrary polarization in the vacuum ultraviolet-to-soft x-ray spectral range. Furthermore, within each FEL tuning range, any output wavelength and polarization can be set in less than a minute of routine operations. We report the first demonstration of the full output polarization capabilities of FERMI FEL-1 in a campaign of experiments where the wavelength and nominal polarization are set to a series of representative values, and the polarization of the emitted intense pulses is thoroughly characterized by three independentmore » instruments and methods, expressly developed for the task. The measured radiation polarization is consistently >90% and is not significantly spoiled by the transport optics; differing, relative transport losses for horizontal and vertical polarization become more prominent at longer wavelengths and lead to a non-negligible ellipticity for an originally circularly polarized state. The results from the different polarimeter setups validate each other, allow a cross-calibration of the instruments, and constitute a benchmark for user experiments.« less

  6. Control of the polarization of a vacuum-ultraviolet, high-gain, free-electron laser

    SciTech Connect

    Allaria, Enrico; Diviacco, Bruno; Callegari, Carlo; Finetti, Paola; Mahieu, Benoît; Viefhaus, Jens; Zangrando, Marco; De Ninno, Giovanni; Lambert, Guillaume; Ferrari, Eugenio; Buck, Jens; Ilchen, Markus; Vodungbo, Boris; Mahne, Nicola; Svetina, Cristian; Spezzani, Carlo; Di Mitri, Simone; Penco, Giuseppe; Trovó, Mauro; Fawley, William M.; Rebernik, Primoz R.; Gauthier, David; Grazioli, Cesare; Coreno, Marcello; Ressel, Barbara; Kivimäki, Antti; Mazza, Tommaso; Glaser, Leif; Scholz, Frank; Seltmann, Joern; Gessler, Patrick; Grünert, Jan; De Fanis, Alberto; Meyer, Michael; Knie, André; Moeller, Stefan P.; Raimondi, Lorenzo; Capotondi, Flavio; Pedersoli, Emanuele; Plekan, Oksana; Danailov, Miltcho B.; Demidovich, Alexander; Nikolov, Ivaylo; Abrami, Alessandro; Gautier, Julien; Lüning, Jan; Zeitoun, Philippe; Giannessi, Luca

    2014-12-02

    The two single-pass, externally seeded free-electron lasers (FELs) of the FERMI user facility are designed around Apple-II-type undulators that can operate at arbitrary polarization in the vacuum ultraviolet-to-soft x-ray spectral range. Furthermore, within each FEL tuning range, any output wavelength and polarization can be set in less than a minute of routine operations. We report the first demonstration of the full output polarization capabilities of FERMI FEL-1 in a campaign of experiments where the wavelength and nominal polarization are set to a series of representative values, and the polarization of the emitted intense pulses is thoroughly characterized by three independent instruments and methods, expressly developed for the task. The measured radiation polarization is consistently >90% and is not significantly spoiled by the transport optics; differing, relative transport losses for horizontal and vertical polarization become more prominent at longer wavelengths and lead to a non-negligible ellipticity for an originally circularly polarized state. The results from the different polarimeter setups validate each other, allow a cross-calibration of the instruments, and constitute a benchmark for user experiments.

  7. Viability of Cladosporium herbarum spores under 157 nm laser and vacuum ultraviolet irradiation, low temperature (10 K) and vacuum

    NASA Astrophysics Data System (ADS)

    Sarantopoulou, E.; Stefi, A.; Kollia, Z.; Palles, D.; Petrou, P. S.; Bourkoula, A.; Koukouvinos, G.; Velentzas, A. D.; Kakabakos, S.; Cefalas, A. C.

    2014-09-01

    Ultraviolet photons can damage microorganisms, which rarely survive prolonged irradiation. In addition to the need for intact DNA, cell viability is directly linked to the functionality of the cell wall and membrane. In this work, Cladosporium herbarum spore monolayers exhibit high viability (7%) when exposed to 157 nm laser irradiation (412 kJm-2) or vacuum-ultraviolet irradiation (110-180 nm) under standard pressure and temperature in a nitrogen atmosphere. Spore viability can be determined by atomic-force microscopy, nano-indentation, mass, μ-Raman and attenuated reflectance Fourier-transform far-infrared spectroscopies and DNA electrophoresis. Vacuum ultraviolet photons cause molecular damage to the cell wall, but radiation resistance in spores arises from the activation of a photon-triggered signaling reaction, expressed via the exudation of intracellular substances, which, in combination with the low penetration depth of vacuum-ultraviolet photons, shields DNA from radiation. Resistance to phototoxicity under standard conditions was assessed, as was resistance to additional environmental stresses, including exposure in a vacuum, under different rates of change of pressure during pumping time and low (10 K) temperatures. Vacuum conditions were far more destructive to spores than vacuum-ultraviolet irradiation, and UV-B photons were two orders of magnitude more damaging than vacuum-ultraviolet photons. The viability of irradiated spores was also enhanced at 10 K. This work, in addition to contributing to the photonic control of the viability of microorganisms exposed under extreme conditions, including decontamination of biological warfare agents, outlines the basis for identifying bio-signaling in vivo using physical methodologies.

  8. Viability of Cladosporium herbarum spores under 157 nm laser and vacuum ultraviolet irradiation, low temperature (10 K) and vacuum

    SciTech Connect

    Sarantopoulou, E. Stefi, A.; Kollia, Z.; Palles, D.; Cefalas, A. C.; Petrou, P. S.; Bourkoula, A.; Koukouvinos, G.; Kakabakos, S.; Velentzas, A. D.

    2014-09-14

    Ultraviolet photons can damage microorganisms, which rarely survive prolonged irradiation. In addition to the need for intact DNA, cell viability is directly linked to the functionality of the cell wall and membrane. In this work, Cladosporium herbarum spore monolayers exhibit high viability (7%) when exposed to 157 nm laser irradiation (412 kJm⁻²) or vacuum-ultraviolet irradiation (110–180 nm) under standard pressure and temperature in a nitrogen atmosphere. Spore viability can be determined by atomic-force microscopy, nano-indentation, mass, μ-Raman and attenuated reflectance Fourier-transform far-infrared spectroscopies and DNA electrophoresis. Vacuum ultraviolet photons cause molecular damage to the cell wall, but radiation resistance in spores arises from the activation of a photon-triggered signaling reaction, expressed via the exudation of intracellular substances, which, in combination with the low penetration depth of vacuum-ultraviolet photons, shields DNA from radiation. Resistance to phototoxicity under standard conditions was assessed, as was resistance to additional environmental stresses, including exposure in a vacuum, under different rates of change of pressure during pumping time and low (10 K) temperatures. Vacuum conditions were far more destructive to spores than vacuum-ultraviolet irradiation, and UV-B photons were two orders of magnitude more damaging than vacuum-ultraviolet photons. The viability of irradiated spores was also enhanced at 10 K. This work, in addition to contributing to the photonic control of the viability of microorganisms exposed under extreme conditions, including decontamination of biological warfare agents, outlines the basis for identifying bio-signaling in vivo using physical methodologies.

  9. Fluorescence and Raman spectra on surface of K9 glass by high fluence ultraviolet laser irradiation at 355 nm

    NASA Astrophysics Data System (ADS)

    Zhang, Zhen; Huang, Jin; Geng, Feng; Zhou, Xiaoyan; Feng, Shiquan; Ren, Dahua; Cheng, Xinlu; Jiang, Xiaodong; Wu, Weidong; Zheng, Wanguo; Tang, Yongjian

    2013-11-01

    In order to explore the damage mechanisms of K9 glass irradiated by high energy density ultraviolet laser, laser-induced fluorescence and Raman spectra were investigated. Compared the fluorescence spectra of damaged area, undamaged area and sub-damaged area, it can be conclude that the fluorescence spectrum of sub-damaged area is different from the structure of the other two areas. Especially, the main peak of the spectra at 415 nm reveals the unique characteristics of K9 glass. The structure at the sub-damaged area enhances intensity of the Raman scattering spectra. Three peaks of the spectra at about 500 nm and two characteristic peaks at about 550 nm exhibit the characterization of damaged area. A peak of the Raman scattering spectra at 350 nm which related to water can be observed. The relationship between intensity of Raman scattering and laser intensity at 355 nm is investigated by confocal Raman microscopy. At sub-damage area, signal of Raman scattering is rather high and decreased dramatically with respect to energy density. The major band at about 1470 cm-1 sharpened and moved to higher frequency with densification. These phenomena demonstrate that the structure of sub-damaged area has some characterization compared with the damaged area. The investigation of defect induced fluorescence and Raman spectra on surface of K9 glass is important to explore the damage mechanisms of optical materials irradiated by ultraviolet laser irradiation at 355 nm.

  10. Plasma ultraviolet source for short-wavelength lasers. Final report, 15 January 1986-29 February 1988

    SciTech Connect

    Han, K.S.

    1988-04-15

    A dense plasma focus (DPF) device was evaluated for the feasibility of blue-green and near-ultraviolet laser pumping. As the result of optimizing the operating conditions of DPF and laser system, the maximum untuned laser output exceeded 4.0 mJ corresponding to the energy density 8.3 J/liter which is much higher than the typical flashlamp dye laser. The spectral irradiance of DPF at the absorption bands for LD390 and LD490 were 5.5 W/sq cm-nm, 0.3 W.sq cm-nm, respectively. Due to the lower pump power of DPF at 355 nm than the threshold of LD390, the laser pumping of LD390 dye was not achieved. A hard-core flashlamp (HCF) which has a coaxial geometry and array of inverse pinches was also evaluated for blue-green and near uv laser excitation. The short pulse (>0.5us) surface discharges were produced across the core insulator of alumina. The spectral irradiance of the HCF depends on argon fill-gas pressure and the core insulating material. The maximum radiative output of the HCF lie in the region of 340-400 nm (absorption band of LD490). A LD490 dye laser pumped by a HCF prototype device had an output of 0.9 mJ with a pulse of 0.5 microsec (full width at half maximum).

  11. Desorption dynamics, internal energies, and imaging of organic molecules from surfaces with laser desorption and vacuum ultraviolet (VUV) photoionization.

    PubMed

    Kostko, Oleg; Takahashi, Lynelle K; Ahmed, Musahid

    2011-11-04

    There is enormous interest in visualizing the chemical composition of organic material that comprises our world. A convenient method to obtain molecular information with high spatial resolution is imaging mass spectrometry. However, the internal energy deposited within molecules upon transfer to the gas phase from a surface can lead to increased fragmentation and to complications in analysis of mass spectra. Here it is shown that in laser desorption with postionization by tunable vacuum ultraviolet (VUV) radiation, the internal energy gained during laser desorption leads to minimal fragmentation of DNA bases. The internal temperature of laser-desorbed triacontane molecules approaches 670 K, whereas the internal temperature of thymine is 800 K. A synchrotron-based VUV postionization technique for determining translational temperatures reveals that biomolecules have translational temperatures in the range of 216-346 K. The observed low translational temperatures as well as their decrease with increased desorption laser power is explained by collisional cooling. An example of imaging mass spectrometry on an organic polymer by using laser-desorption VUV postionization shows 5 μm feature details while using a 30 μm laser spot size and 7 ns pulse duration. Applications of laser-desorption postionization to the analysis of cellulose, lignin, and humic acids are briefly discussed.

  12. Desorption Dynamics, Internal Energies and Imaging of Organic Molecules from Surfaces with Laser Desorption and Vacuum Ultraviolet (VUV) Photoionization

    SciTech Connect

    Kostko, Oleg; Takahashi, Lynelle K.; Ahmed, Musahid

    2011-04-05

    There is enormous interest in visualizing the chemical composition of organic material that comprises our world. A convenient method to obtain molecular information with high spatial resolution is imaging mass spectrometry. However, the internal energy deposited within molecules upon transfer to the gas phase from a surface can lead to increased fragmentation and to complications in analysis of mass spectra. Here it is shown that in laser desorption with postionization by tunable vacuum ultraviolet (VUV) radiation, the internal energy gained during laser desorption leads to minimal fragmentation of DNA bases. The internal temperature of laser-desorbed triacontane molecules approaches 670 K, whereas the internal temperature of thymine is 800 K. A synchrotron-based VUV postionization technique for determining translational temperatures reveals that biomolecules have translational temperatures in the range of 216-346 K. The observed low translational temperatures, as well as their decrease with increased desorption laser power is explained by collisional cooling. An example of imaging mass spectrometry on an organic polymer, using laser desorption VUV postionization shows 5 mu m feature details while using a 30 mu m laser spot size and 7 ns duration. Applications of laser desorption postionization to the analysis of cellulose, lignin and humic acids are briefly discussed.

  13. Microscopic and macroscopic material property effects on ultraviolet-laser-induced flashover of angled insulators in vacuum

    SciTech Connect

    Enloe, C.L.; Gilgenbach, R.M.

    1988-06-01

    Flashover of electrically stressed polymeric insulators in vacuum has been induced by ultraviolet radiation from an excimer laser (KrF). Flashover behavior is a relatively strong function of integrated fluence up to the time of flashover initiation, and virtually independent of applied power or pulse time. Flashover is induced by moderate fluence (10 - 150 mJ/cm/sup 2/) of intense (0.4 - 6 MW/cm/sup 2/) ultraviolet at 248 nm at electric field stress considerably below the static breakdown stress. The critical fluence required to initiate flashover is a function of the electric field stress, the insulating material, and the geometry of the dielectric/vacuum interface. The unconventional insulator geometry (in which electrons are accelerated toward the insulator surface) is more tolerant than the conventional geometry by nearly a factor of 2 in fluence. Insulator materials tested were polyethylene, polystyrene, acrylic, nylon-6, acetal, PVC, and teflon. The critical fluence is correlated to the microscopic and macroscopic material properties; results show that insulating materials with high dielectric constants and low secondary electron emission coefficients exhibit superior tolerance to ultraviolet radiation. Of the materials tested, nylon exhibited the highest critical fluence in both the conventional and the unconventional geometries. A theory of ultraviolet-induced insulator flashover is developed.

  14. Studies of bimolecular reaction dynamics using pulsed high-intensity vacuum-ultraviolet lasers for photoionization detection.

    PubMed

    Albert, Daniel R; Davis, H Floyd

    2013-09-21

    This article describes recent progress on the development and application of pulsed high-intensity (~0.1 mJ per pulse) vacuum-ultraviolet (VUV) radiation produced by commercial tabletop lasers for studies of gas phase chemical reaction dynamics involving polyatomic free radicals. Our approach employs near-triply resonant four-wave mixing of unfocussed nanosecond dye lasers in an atomic gas as an alternative to the use of synchrotron light sources for sensitive universal soft photoionization detection of reaction products using a rotatable source crossed molecular beams apparatus with fixed detector. We illustrate this approach in studies of the reactions of phenyl radicals with molecular oxygen and with propene. Future prospects for the use of tabletop laser-based VUV sources for studies of chemical reaction dynamics are discussed.

  15. Optimization of the size ratio of Sn sphere and laser focal spot for an extreme ultraviolet light source

    SciTech Connect

    Yuspeh, S.; Sequoia, K. L.; Tao, Y.; Tillack, M. S.; Burdt, R.; Najmabadi, F.

    2008-12-01

    The effect of the ratio of Sn sphere diameter to laser focal spot size (SD/FSS) on conversion efficiency (CE) from laser to in-band (2%) 13.5 nm extreme ultraviolet (EUV) light was investigated by fixing the laser spot size and irradiating variable diameter spheres. It was found that a minimum SD/FSS, i.e., 2.5, is necessary to produce high in-band CE, which is 15% higher than planar targets. Two-dimensional plasma density profile maps showed that the density of the dominant in-band EUV emission region and the size of the surrounding absorbing plasma can be manipulated by geometric effects of the SD/FSS ratio.

  16. Multiple-shot ultraviolet laser damage resistance of nonquarterwave reflector designs for 248 NM

    SciTech Connect

    Newnam, B.E.; Foltyn, S.R.; Jolin, L.J.

    1982-01-01

    The damage resistance of multilayer dielectric reflectors designed for 248 nm has been substantially increased by use of nonquarterwave (QW) thicknesses for the top few layers. These designs minimize the peak standing-wave electric field in the high-index layers, which have proven to be weaker than the low-index components. Previous damage tests of infrared- and visible-wavelength reflectors based on these designs have produced variable results. However, at the ultraviolet wavelength of 248 nm, 99% reflectors of Sc/sub 2/O/sub 3/, MgF/sub 2/, and SiO/sub 2/ strongly demonstrated the merit of non-QW designs. Four sets of reflectors of each of four designs (all QW thickness; one modified-pair substitution; two modified-pair substitution; one modified pair plus an extra half-wave layer of Sc/sub 2/O/sub 3/) were tested for damage resistance with a KrF laser operating at 35 pps with a pulsewidth of 8 ns and spot-size diameter of 0.6 mm. Each of 50 sites were irradiated for 1000 shots or until damage occurred. On the average, the reflectors with one-modified-thickness pair had a 50% higher threshold (10 to 10 sites survived) than the all-quarterwave design. Addition of a second modified-layer pair resulted in no further increase in threshold but the saturation fluence (10 of 10 sites damage) was 110% higher. Reflectors with an additional half-wave of Sc/sub 2/O/sub 3/ had lower thresholds of the order of 10% as expected. The thresholds correlated best with peak-field models, whereas the best model correlating the saturation fluences involved the sum of the upper two scandia layer thicknesses.

  17. MRF Applications: On the Road to Making Large-Aperture Ultraviolet Laser Resistant Continuous Phase Plates for High-Power Lasers

    SciTech Connect

    Menapace, J A; Davis, P J; Steele, W A; Hachkowski, M R; Nelson, A; Xin, K

    2006-10-26

    Over the past two years we have developed MRF tools and procedures to manufacture large-aperture (430 X 430 mm) continuous phase plates (CPPs) that are capable of operating in the infrared portion (1053 nm) of high-power laser systems. This is accomplished by polishing prescribed patterns of continuously varying topographical features onto finished plano optics using MRF imprinting techniques. We have been successful in making, testing, and using large-aperture CPPs whose topography possesses spatial periods as low as 4 mm and surface peak-to-valleys as high as 8.6 {micro}m. Combining this application of MRF technology with advanced MRF finishing techniques that focus on ultraviolet laser damage resistance makes it potentially feasible to manufacture large-aperture CPPs that can operate in the ultraviolet (351 nm) without sustaining laser-induced damage. In this paper, we will discuss the CPP manufacturing process and the results of 351-nm/3-nsec equivalent laser performance experiments conducted on large-aperture CPPs manufactured using advanced MRF protocols.

  18. Damage Free Particle Removal from Extreme Ultraviolet Lithography Mask Layers by High Energy Laser Shock Wave Cleaning

    NASA Astrophysics Data System (ADS)

    Kim, Tae-Gon; Yoo, Young-Sam; Kim, Tae-Geun; Ahn, Jinho; Lee, Jong-Myoung; Choi, Jae-Sung; Busnaina, Ahmed A.; Park, Jin-Goo

    2008-06-01

    Plasma shock waves induced by focusing a Q-switched Nd:YAG laser at a maximum energy of 1.8 J in air were characterized by a laser beam deflection method and were applied to 50 nm silica particle removal from a Al2O3/TaN/Ru/MoSi 40 pairs as the extreme ultraviolet lithography (EUVL) mask layers on silicon wafer. A high energy laser induced shock wave effectively removed 50 nm silica particles from the EUVL mask layers. The change of sample topography before and after laser shock cleaning was measured by an atomic force microscope. Surface damage was observed at a gap distance of 1.5 mm. The dimensions of the plasma plume were characterized as a function of the laser energy and focus-to-surface gap distance. The plasma plume was the main source for damaging the surface. A high energy laser induced shock wave with a gap distance of over 3 mm achieved damage-free sub-100 nm particle removal.

  19. Laser plasma sources of soft x-rays and extreme ultraviolet (EUV) for application in science and technology

    NASA Astrophysics Data System (ADS)

    Bartnik, Andrzej; Wachulak, Przemysław; Jarocki, Roman; Kostecki, Jerzy; Szczurek, Mirosław; Adjei, Daniel; Ahad, Inam Ul; Ayele, Mesfin G.; Fok, Tomasz; Szczurek, Anna; Torrisi, Alfio; Wegrzyński, Łukasz; Fiedorowicz, Henryk

    2015-05-01

    Laser plasma sources of soft x-rays and extreme ultraviolet (EUV) developed in our laboratory for application in various areas of technology and science are presented. The sources are based on a laser-irradiated gas puff target approach. The targets formed by pulsed injection of gas under high-pressure are irradiated with nanosecond laser pulses from Nd:YAG lasers. We use commercial lasers generating pulses with time duration from 1ns to 10ns and energies from 0.5J to 10J at 10Hz repetition rate. The gas puff targets are produced using a double valve system equipped with a special nozzle to form a double-stream gas puff target which secures high conversion efficiency without degradation of the nozzle. The use of a gas puff target instead of a solid target makes generation of laser plasmas emitting soft x-rays and EUV possible without target debris production. The sources are equipped with various optical systems, including grazing incidence axisymmetric ellipsoidal mirrors, a "lobster eye" type grazing incidence multi-foil mirror, and an ellipsoidal mirror with Mo/Si multilayer coating, to collect soft x-ray and EUV radiation and form the radiation beams. In this paper new applications of these sources in various fields, including soft x-ray and EUV imaging in nanoscale, EUV radiography and tomography, EUV materials processing and modification of polymer surfaces, EUV photoionization of gases, radiobiology and soft x-ray contact microscopy are reviewed.

  20. Low thermal budget n-type doping into Ge(001) surface using ultraviolet laser irradiation in phosphoric acid solution

    SciTech Connect

    Takahashi, Kouta E-mail: kurosawa@alice.xtal.nagoya-u.ac.jp; Sakashita, Mitsuo; Takeuchi, Wakana; Nakatsuka, Osamu; Kurosawa, Masashi E-mail: kurosawa@alice.xtal.nagoya-u.ac.jp; Ikenoue, Hiroshi; Zaima, Shigeaki

    2016-02-01

    We have investigated phosphorus (P) doping into Ge(001) surfaces by using ultraviolet laser irradiation in phosphoric acid solution at room temperature. We demonstrated that the diffusion depth of P in Ge and the concentration of electrically activated P can be controlled by the number of laser shots. Indeed, a high concentration of electrically activated P of 2.4 × 10{sup 19} cm{sup −3} was realized by 1000-times laser shots at a laser energy of 1.0 J/cm{sup 2}, which is comparable or better than the counterparts of conventional n-type doping using a high thermal budget over 600 °C. The generation current is dominant in the reverse bias condition for the laser-doped pn-junction diodes independent on the number of laser shots, thus indicating low-damage during the pn-junction formation. These results open up the possibility for applicable low thermal budget doping process for Ge-based devices fabricated on flexible substrates as well as Si electronics.

  1. The mechanism underlying calcium phosphate precipitation on titanium via ultraviolet, visible, and near infrared laser-assisted biomimetic process

    NASA Astrophysics Data System (ADS)

    Mahanti, Moumita; Nakamura, Maki; Pyatenko, Alexander; Sakamaki, Ikuko; Koga, Kenji; Oyane, Ayako

    2016-08-01

    We recently developed a rapid single-step calcium phosphate (CaP) precipitation technique on several substrates using a laser-assisted biomimetic process (LAB process). In this process, ultraviolet (UV, λ  =  355 nm) pulsed laser irradiation has been applied to a substrate that is immersed in a supersaturated CaP solution. In the present study, the LAB process for CaP precipitation on a titanium substrate was successfully expanded to include not only UV but also visible (VIS, λ  =  532 nm) and near infrared (NIR, λ  =  1064 nm) lasers. Surface heating and plasma-mediated surface reactions (micro-deformation, oxidization, photoexcitation, and wetting) generated by UV, VIS, or NIR lasers are considered to be involved in the CaP precipitation on the titanium surface in the LAB process. The kinetics of these reactions and consequently of CaP precipitation were dependent on the laser wavelength and fluence. The higher laser fluence did not always accelerate CaP precipitation on the substrate; rather, it was found that an optimal range of fluence exists for each laser wavelength. These results suggest that for efficient CaP precipitation, a suitable laser wavelength should be selected according to the optical absorption properties of the substrate material and the laser fluence should also be adjusted to induce surface heating and plasma-mediated surface reactions that are favorable for CaP precipitation.

  2. Spatio-temporal coherence of free-electron laser radiation in the extreme ultraviolet determined by a Michelson interferometer

    NASA Astrophysics Data System (ADS)

    Hilbert, V.; Rödel, C.; Brenner, G.; Döppner, T.; Düsterer, S.; Dziarzhytski, S.; Fletcher, L.; Förster, E.; Glenzer, S. H.; Harmand, M.; Hartley, N. J.; Kazak, L.; Komar, D.; Laarmann, T.; Lee, H. J.; Ma, T.; Nakatsutsumi, M.; Przystawik, A.; Redlin, H.; Skruszewicz, S.; Sperling, P.; Tiggesbäumker, J.; Toleikis, S.; Zastrau, U.

    2014-09-01

    A key feature of extreme ultraviolet (XUV) radiation from free-electron lasers (FELs) is its spatial and temporal coherence. We measured the spatio-temporal coherence properties of monochromatized FEL pulses at 13.5 nm using a Michelson interferometer. A temporal coherence time of (59±8) fs has been determined, which is in good agreement with the spectral bandwidth given by the monochromator. Moreover, the spatial coherence in vertical direction amounts to about 15% of the beam diameter and about 12% in horizontal direction. The feasibility of measuring spatio-temporal coherence properties of XUV FEL radiation using interferometric techniques advances machine operation and experimental studies significantly.

  3. Spatio-temporal coherence of free-electron laser radiation in the extreme ultraviolet determined by a Michelson interferometer

    SciTech Connect

    Hilbert, V.; Rödel, C.; Zastrau, U.; Brenner, G.; Düsterer, S.; Dziarzhytski, S.; Harmand, M.; Przystawik, A.; Redlin, H.; Toleikis, S.; Döppner, T.; Ma, T.; Fletcher, L.; Förster, E.; Glenzer, S. H.; Lee, H. J.; Hartley, N. J.; Kazak, L.; Komar, D.; Skruszewicz, S.; and others

    2014-09-08

    A key feature of extreme ultraviolet (XUV) radiation from free-electron lasers (FELs) is its spatial and temporal coherence. We measured the spatio-temporal coherence properties of monochromatized FEL pulses at 13.5 nm using a Michelson interferometer. A temporal coherence time of (59±8) fs has been determined, which is in good agreement with the spectral bandwidth given by the monochromator. Moreover, the spatial coherence in vertical direction amounts to about 15% of the beam diameter and about 12% in horizontal direction. The feasibility of measuring spatio-temporal coherence properties of XUV FEL radiation using interferometric techniques advances machine operation and experimental studies significantly.

  4. Combined vacuum ultraviolet laser and synchrotron pulsed field ionization study of CH2BrCl.

    PubMed

    Li, Juan; Yang, Jie; Mo, Yuxiang; Lau, K C; Qian, X M; Song, Y; Liu, Jianbo; Ng, C Y

    2007-05-14

    The pulsed field ionization-photoelectron (PFI-PE) spectrum of bromochloromethane (CH2BrCl) in the region of 85,320-88,200 cm-1 has been measured using vacuum ultraviolet laser. The vibrational structure resolved in the PFI-PE spectrum was assigned based on ab initio quantum chemical calculations and Franck-Condon factor predictions. At energies 0-1400 cm-1 above the adiabatic ionization energy (IE) of CH2BrCl, the Br-C-Cl bending vibration progression (nu1+=0-8) of CH2BrCl+ is well resolved and constitutes the major structure in the PFI-PE spectrum, whereas the spectrum at energies 1400-2600 cm-1 above the IE(CH2BrCl) is found to exhibit complex vibrational features, suggesting perturbation by the low lying excited CH2BrCl+(A 2A") state. The assignment of the PFI-PE vibrational bands gives the IE(CH2BrCl)=85,612.4+/-2.0 cm-1 (10.6146+/-0.0003 eV) and the bending frequencies nu1+(a1')=209.7+/-2.0 cm-1 for CH2BrCl+(X2A'). We have also examined the dissociative photoionization process, CH2BrCl+hnu-->CH2Cl++Br+e-, in the energy range of 11.36-11.57 eV using the synchrotron based PFI-PE-photoion coincidence method, yielding the 0 K threshold or appearance energy AE(CH2Cl+)=11.509+/-0.002 eV. Combining the 0 K AE(CH2Cl+) and IE(CH2BrCl) values obtained in this study, together with the known IE(CH2Cl), we have determined the 0 K bond dissociation energies (D0) for CH2Cl+-Br (0.894+/-0.002 eV) and CH2Cl-Br (2.76+/-0.01 eV). We have also performed CCSD(T, full)/complete basis set (CBS) calculations with high-level corrections for the predictions of the IE(CH2BrCl), AE(CH2Cl+), IE(CH2Cl), D0(CH2Cl+-Br), and D0(CH2Cl-Br). The comparison between the theoretical predictions and experimental determinations indicates that the CCSD(T, full)/CBS calculations with high-level corrections are highly reliable with estimated error limits of <17 meV.

  5. A High-resolution Vacuum Ultraviolet Laser Photoionization and Photoelectron Study of the Co Atom

    NASA Astrophysics Data System (ADS)

    Huang, Huang; Wang, Hailing; Luo, Zhihong; Shi, Xiaoyu; Chang, Yih-Chung; Ng, C. Y.

    2016-12-01

    We have measured the vacuum ultraviolet-photoionization efficiency (VUV-PIE) spectrum of Co in the energy range of 63,500-67,000 cm-1, which covers the photoionization transitions of Co(3d74s2 4F9/2) \\to Co+(3d8 3F4), Co(3d74s2 4F7/2) \\to Co+(3d8 3F3), Co(3d74s2 4F9/2) \\to Co+(3d8 3F3), Co(3d74s2 4F9/2) \\to Co+(3d8 3F2), and Co(3d74s2 4F9/2) \\to Co+(3d74s1 5F5). We have also recorded the pulsed field ionization photoelectron spectrum of Co in the same energy range, allowing accurate determinations of ionization energies (IEs) for the photoionization transitions from the Co(3d74s2 4F9/2) ground neutral state to the Co+(3F J ) (J = 4 and 3) and Co+(5F5) ionic states, as well as from the Co(3d74s2 4F7/2) excited neural state to the Co+(3d8 3F3) ionic state. The high-resolution nature of the VUV laser used has allowed the observation of many well-resolved autoionizing resonances in the VUV-PIE spectrum, among which an autoionizing Rydberg series, 3d74s1(5F5)np (n = 19-38), converging to the Co+(3d74s1 5F5) ionic state from the Co(3d74s2 4F9/2) ground neutral state is identified. The fact that no discernible step-like structures are present at these ionization thresholds in the VUV-PIE spectrum indicates that direct photoionization of Co is minor compared to autoionization in this energy range. The IE values, the autoionizing Rydberg series, and the photoionization cross sections obtained in this experiment are valuable for understanding the VUV opacity and abundance measurement of the Co atom in stars and solar atmospheres, as well as for benchmarking the theoretical results calculated in the Opacity Project and the IRON Project, and thus are of relevance to astrophysics.

  6. High-resolution three-dimensional spin- and angle-resolved photoelectron spectrometer using vacuum ultraviolet laser light

    NASA Astrophysics Data System (ADS)

    Yaji, Koichiro; Harasawa, Ayumi; Kuroda, Kenta; Toyohisa, Sogen; Nakayama, Mitsuhiro; Ishida, Yukiaki; Fukushima, Akiko; Watanabe, Shuntaro; Chen, Chuangtian; Komori, Fumio; Shin, Shik

    2016-05-01

    We describe a spin- and angle-resolved photoelectron spectroscopy (SARPES) apparatus with a vacuum-ultraviolet (VUV) laser (hν = 6.994 eV) developed at the Laser and Synchrotron Research Center at the Institute for Solid State Physics, The University of Tokyo. The spectrometer consists of a hemispherical photoelectron analyzer equipped with an electron deflector function and twin very-low-energy-electron-diffraction-type spin detectors, which allows us to analyze the spin vector of a photoelectron three-dimensionally with both high energy and angular resolutions. The combination of the high-performance spectrometer and the high-photon-flux VUV laser can achieve an energy resolution of 1.7 meV for SARPES. We demonstrate that the present laser-SARPES machine realizes a quick SARPES on the spin-split band structure of a Bi(111) film even with 7 meV energy and 0.7∘ angular resolutions along the entrance-slit direction. This laser-SARPES machine is applicable to the investigation of spin-dependent electronic states on an energy scale of a few meV.

  7. High-resolution three-dimensional spin- and angle-resolved photoelectron spectrometer using vacuum ultraviolet laser light.

    PubMed

    Yaji, Koichiro; Harasawa, Ayumi; Kuroda, Kenta; Toyohisa, Sogen; Nakayama, Mitsuhiro; Ishida, Yukiaki; Fukushima, Akiko; Watanabe, Shuntaro; Chen, Chuangtian; Komori, Fumio; Shin, Shik

    2016-05-01

    We describe a spin- and angle-resolved photoelectron spectroscopy (SARPES) apparatus with a vacuum-ultraviolet (VUV) laser (hν = 6.994 eV) developed at the Laser and Synchrotron Research Center at the Institute for Solid State Physics, The University of Tokyo. The spectrometer consists of a hemispherical photoelectron analyzer equipped with an electron deflector function and twin very-low-energy-electron-diffraction-type spin detectors, which allows us to analyze the spin vector of a photoelectron three-dimensionally with both high energy and angular resolutions. The combination of the high-performance spectrometer and the high-photon-flux VUV laser can achieve an energy resolution of 1.7 meV for SARPES. We demonstrate that the present laser-SARPES machine realizes a quick SARPES on the spin-split band structure of a Bi(111) film even with 7 meV energy and 0.7(∘) angular resolutions along the entrance-slit direction. This laser-SARPES machine is applicable to the investigation of spin-dependent electronic states on an energy scale of a few meV.

  8. Investigation of the interaction of a laser pulse with a preformed Gaussian Sn plume for an extreme ultraviolet lithography source

    SciTech Connect

    Tao, Y.; Tillack, M. S.; Harilal, S. S.; Sequoia, K. L.; Najmabadi, F.

    2007-01-15

    The interaction of a laser pulse with a Sn preplasma formed by a low energy prepulse was investigated for an extreme ultraviolet (EUV) lithography light source. A much lower ion kinetic energy and nearly the same conversion efficiency from laser to in-band (2% bandwidth) 13.5 nm EUV light were simultaneously observed as compared with those from the direct interaction with a solid surface. The reason comes from the interaction of the laser pulse with a smooth preplume induced by the prepulse. The density profile of the preplume was measured with time-resolved shadowgraphy and could be fitted with a Gaussian function. The energy of the ions located at the flux peak E{sub p} scales with the length of the preplume l{sub s} as E{sub p}{proportional_to}1/l{sub s}. Laser absorption in the low-density preplume and ion acceleration during plasma expansion are discussed. This result provides a general way to control particle energy from a laser plasma interaction.

  9. Size control and vacuum-ultraviolet fluorescence of nanosized KMgF3 single crystals prepared using femtosecond laser pulses

    PubMed Central

    Muramatsu, Sotaro; Yanagihara, Masahiro; Asaka, Toru; Ono, Shingo; Nagami, Tomohito; Fukuda, Kentaro; Suyama, Toshihisa; Yokota, Yuui; Yanagida, Takayuki; Yoshikawa, Akira

    2016-01-01

    Abstract We fabricated nanosized KMgF3 single crystals via a dry pulsed laser ablation process using femtosecond laser pulses. The sizes, shapes, and crystallographic properties of the crystals were evaluated by transmission electron microscopy (TEM). Almost all of the particles were spherical with diameters of less than 100 nm, and they were not highly agglomerated. Selected-area electron diffraction and high-resolution TEM analyses showed that the particles were single crystals. Particle diameter was controlled within a wide range by adjusting the Ar ambient gas pressure. Under low gas pressures (1 and 10 Pa), relatively small particles (primarily 10 nm or less) were observed with a high number density. With increasing pressure, the mean diameter increased and the number density drastically decreased. Vacuum-ultraviolet cathodoluminescence was observed at 140–230 nm with blue shift and broadening of spectrum. PMID:27877915

  10. Molecular beam epitaxial growth and characterization of Al(Ga)N nanowire deep ultraviolet light emitting diodes and lasers

    NASA Astrophysics Data System (ADS)

    Mi, Z.; Zhao, S.; Woo, S. Y.; Bugnet, M.; Djavid, M.; Liu, X.; Kang, J.; Kong, X.; Ji, W.; Guo, H.; Liu, Z.; Botton, G. A.

    2016-09-01

    We report on the detailed molecular beam epitaxial growth and characterization of Al(Ga)N nanowire heterostructures on Si and their applications for deep ultraviolet light emitting diodes and lasers. The nanowires are formed under nitrogen-rich conditions without using any metal catalyst. Compared to conventional epilayers, Mg-dopant incorporation is significantly enhanced in nearly strain- and defect-free Al(Ga)N nanowire structures, leading to efficient p-type conduction. The resulting Al(Ga)N nanowire LEDs exhibit excellent performance, including a turn-on voltage of ∼5.5 V for an AlN nanowire LED operating at 207 nm. The design, fabrication, and performance of an electrically injected AlGaN nanowire laser operating in the UV-B band is also presented.

  11. Scanning ultraviolet two-step laser mass spectroscopy of polycyclic aromatic hydrocarbon distributions on creosote-contaminated soil particles.

    PubMed

    Fye, J L; Nelson, H H; Mowery, R L; Baronavski, A P; Callahan, J H

    2002-07-01

    The distribution of polycyclic aromatic hydrocarbons (PAHs) on creosote-contaminated soil has been examined with scanning ultraviolet two-step laser desorption/laser ionization mass spectroscopy (UV-L2MS). The instrument has been constructed in-house by modifying a reflectron time-of-flight mass spectrometer. Two-dimensional chemical maps were accurately generated from model patterned PAH distributions. From examination of three-dimensional substrates, the depth of field of the experiment allows surfaces with roughness of up to 120 microm to be treated as a two-dimensional system and still achieve an accurate representation of the surface deposits. Soil was obtained from a former wood treatment facility. Individual particles of 100-1000 microm were mounted on indexed sample plates and examined by reflectance infrared microscopy, optical microscopy, and imaging UV-L2MS. The most intense PAH signals were associated with regions on the particles where clay/organic carbon deposits were found.

  12. Size control and vacuum-ultraviolet fluorescence of nanosized KMgF3 single crystals prepared using femtosecond laser pulses.

    PubMed

    Muramatsu, Sotaro; Yanagihara, Masahiro; Asaka, Toru; Ono, Shingo; Nagami, Tomohito; Fukuda, Kentaro; Suyama, Toshihisa; Yokota, Yuui; Yanagida, Takayuki; Yoshikawa, Akira

    2016-01-01

    We fabricated nanosized KMgF3 single crystals via a dry pulsed laser ablation process using femtosecond laser pulses. The sizes, shapes, and crystallographic properties of the crystals were evaluated by transmission electron microscopy (TEM). Almost all of the particles were spherical with diameters of less than 100 nm, and they were not highly agglomerated. Selected-area electron diffraction and high-resolution TEM analyses showed that the particles were single crystals. Particle diameter was controlled within a wide range by adjusting the Ar ambient gas pressure. Under low gas pressures (1 and 10 Pa), relatively small particles (primarily 10 nm or less) were observed with a high number density. With increasing pressure, the mean diameter increased and the number density drastically decreased. Vacuum-ultraviolet cathodoluminescence was observed at 140-230 nm with blue shift and broadening of spectrum.

  13. Briefing paper for the proposed ultraviolet free-electron laser (UV- FEL) facility at Brookhaven National Laboratory

    SciTech Connect

    Johnson, E.D.

    1992-07-15

    The proposed Brookhaven National Laboratory ultraviolet free-electron laser (UV-FEL) user facility will provide picosecond and sub-picosecond pulses of coherent ultraviolet radiation for wavelengths from 300 to 75 nm. Pulse width will be variable from about 7 ps to {approx} 200 fs, with repetition rates as high as l0{sup 4}Hz, single pulse energies > 1 NJ and hence peak pulse power > 200 MW and average beam power > 10 W. The facility will be capable of ``pump-probe`` experiments utilizing the FEL radiation with: (1) synchronized auxiliary lasers, (2) a second, independently tunable FEL beam, or (3) broad-spectrum, high-intensity x-rays from an insertion device in the x-ray ring of the adjacent National Synchrotron Light Source. The UV-FEL consists of a high repetition rate recirculating superconducting linear accelerator which feeds pulses of electrons to two magnetic wigglers. Within these two devices, photons from tunable ``conventional`` lasers are frequency multiplied and amplified. By synchronously tuning the seed laser and modulating the energy of the electron beam, tuning of as much as 60% in wavelength is possible between alternating pulses supplied to different experimental stations, with Fourier transform limited resolution. Thus, up to four independent experiments may operate at one time, each with independent control of the wavelength and pulse duration. A total of eight experimental stations are planned, with two currently assigned to general users, two each for solid state and chemical physics, and one each for atomic physics and biology. This document provides a few representative examples of experiments in these fields, as well as an introduction to the facility, its limitations, and its potential for future growth.

  14. Briefing paper for the proposed ultraviolet free-electron laser (UV- FEL) facility at Brookhaven National Laboratory

    SciTech Connect

    Johnson, E.D.

    1992-07-15

    The proposed Brookhaven National Laboratory ultraviolet free-electron laser (UV-FEL) user facility will provide picosecond and sub-picosecond pulses of coherent ultraviolet radiation for wavelengths from 300 to 75 nm. Pulse width will be variable from about 7 ps to {approx} 200 fs, with repetition rates as high as l0{sup 4}Hz, single pulse energies > 1 NJ and hence peak pulse power > 200 MW and average beam power > 10 W. The facility will be capable of pump-probe'' experiments utilizing the FEL radiation with: (1) synchronized auxiliary lasers, (2) a second, independently tunable FEL beam, or (3) broad-spectrum, high-intensity x-rays from an insertion device in the x-ray ring of the adjacent National Synchrotron Light Source. The UV-FEL consists of a high repetition rate recirculating superconducting linear accelerator which feeds pulses of electrons to two magnetic wigglers. Within these two devices, photons from tunable conventional'' lasers are frequency multiplied and amplified. By synchronously tuning the seed laser and modulating the energy of the electron beam, tuning of as much as 60% in wavelength is possible between alternating pulses supplied to different experimental stations, with Fourier transform limited resolution. Thus, up to four independent experiments may operate at one time, each with independent control of the wavelength and pulse duration. A total of eight experimental stations are planned, with two currently assigned to general users, two each for solid state and chemical physics, and one each for atomic physics and biology. This document provides a few representative examples of experiments in these fields, as well as an introduction to the facility, its limitations, and its potential for future growth.

  15. Electron localization of {{{\\rm{H}}}_{3}}^{+} and {{\\rm{HeH}}}^{2+} in an ultrashort ultraviolet laser field

    NASA Astrophysics Data System (ADS)

    Jia, Z. M.; Tang, W. T.; Zeng, Z. N.; Li, R. X.; Xu, Z. Z.

    2017-02-01

    Electron localization in the dissociation of the molecular ions {{{{H}}}3}+ and HeH2+ in an intense ultrashort ultraviolet laser pulse is studied with the Schrödinger equation. Two different dissociation channels, {{{{H}}}3}+ + nγ → H2 + p and {{{{H}}}3}+ + nγ → {{{{H}}}2}++ H, and HeH2+ + nγ → He+ + p and HeH2+ + nγ → α + H, for {{{{H}}}3}+ and HeH2+, are investigated, respectively. The numerical and analytical results both show that, for a molecular ion with an asymmetric double-well Coulomb potential, most electrons of the 1s{σ }g state are localized at the potential well with lower energies. For electrons of the 2p{σ }u state, most are localized at the potential well with higher energies when in a single ultraviolet laser pulse. Therefore, for {{{{H}}}3}+, most electrons of the dissociation state are stabilized at the potential well with higher energies (H+), for the lowest dissociation state is the 2p{σ }u state. Most of the electrons of the dissociation state of HeH2+ are captured by the potential well with lower energies (He2+), because the lowest dissociation state is the 1s{σ }g state and the 2p{σ }u state is bounded.

  16. Ultrafast, high repetition rate, ultraviolet, fiber-laser-based source: application towards Yb+ fast quantum-logic.

    PubMed

    Hussain, Mahmood Irtiza; Petrasiunas, Matthew Joseph; Bentley, Christopher D B; Taylor, Richard L; Carvalho, André R R; Hope, Joseph J; Streed, Erik W; Lobino, Mirko; Kielpinski, David

    2016-07-25

    Trapped ions are one of the most promising approaches for the realization of a universal quantum computer. Faster quantum logic gates could dramatically improve the performance of trapped-ion quantum computers, and require the development of suitable high repetition rate pulsed lasers. Here we report on a robust frequency upconverted fiber laser based source, able to deliver 2.5 ps ultraviolet (UV) pulses at a stabilized repetition rate of 300.00000 MHz with an average power of 190 mW. The laser wavelength is resonant with the strong transition in Ytterbium (Yb+) at 369.53 nm and its repetition rate can be scaled up using high harmonic mode locking. We show that our source can produce arbitrary pulse patterns using a programmable pulse pattern generator and fast modulating components. Finally, simulations demonstrate that our laser is capable of performing resonant, temperature-insensitive, two-qubit quantum logic gates on trapped Yb+ ions faster than the trap period and with fidelity above 99%.

  17. Low absorption loss p-AlGaN superlattice cladding layer for current-injection deep ultraviolet laser diodes

    NASA Astrophysics Data System (ADS)

    Martens, M.; Kuhn, C.; Ziffer, E.; Simoneit, T.; Kueller, V.; Knauer, A.; Rass, J.; Wernicke, T.; Einfeldt, S.; Weyers, M.; Kneissl, M.

    2016-04-01

    Current injection into AlGaN-based laser diode structures with high aluminum mole fractions for deep ultraviolet emission is investigated. The electrical characteristics of laser diode structures with different p-AlGaN short period superlattice (SPSL) cladding layers with various aluminum mole fractions are compared. The heterostructures contain all elements that are needed for a current-injection laser diode including cladding and waveguide layers as well as an AlGaN quantum well active region emitting near 270 nm. We found that with increasing aluminum content in the p-AlGaN cladding, the diode turn-on voltage increases, while the series resistance slightly decreases. By introducing an SPSL instead of bulk layers, the operating voltage is significantly reduced. A gain guided broad area laser diode structure with transparent p-Al0.70Ga0.30N waveguide layers and a transparent p-cladding with an average aluminum content of 81% was designed for strong confinement of the transverse optical mode and low optical losses. Using an optimized SPSL, this diode could sustain current densities of more than 4.5 kA/cm2.

  18. Two-colour pump–probe experiments with a twin-pulse-seed extreme ultraviolet free-electron laser

    PubMed Central

    Allaria, E.; Bencivenga, F.; Borghes, R.; Capotondi, F.; Castronovo, D.; Charalambous, P.; Cinquegrana, P.; Danailov, M. B.; De Ninno, G.; Demidovich, A.; Di Mitri, S.; Diviacco, B.; Fausti, D.; Fawley, W. M.; Ferrari, E.; Froehlich, L.; Gauthier, D.; Gessini, A.; Giannessi, L.; Ivanov, R.; Kiskinova, M.; Kurdi, G.; Mahieu, B.; Mahne, N.; Nikolov, I.; Masciovecchio, C.; Pedersoli, E.; Penco, G.; Raimondi, L.; Serpico, C.; Sigalotti, P.; Spampinati, S.; Spezzani, C.; Svetina, C.; Trovò, M.; Zangrando, M.

    2013-01-01

    Exploring the dynamics of matter driven to extreme non-equilibrium states by an intense ultrashort X-ray pulse is becoming reality, thanks to the advent of free-electron laser technology that allows development of different schemes for probing the response at variable time delay with a second pulse. Here we report the generation of two-colour extreme ultraviolet pulses of controlled wavelengths, intensity and timing by seeding of high-gain harmonic generation free-electron laser with multiple independent laser pulses. The potential of this new scheme is demonstrated by the time evolution of a titanium-grating diffraction pattern, tuning the two coherent pulses to the titanium M-resonance and varying their intensities. This reveals that an intense pulse induces abrupt pattern changes on a time scale shorter than hydrodynamic expansion and ablation. This result exemplifies the essential capabilities of the jitter-free multiple-colour free-electron laser pulse sequences to study evolving states of matter with element sensitivity. PMID:24048228

  19. Ultraviolet pulsed laser irradiation of multi-walled carbon nanotubes in nitrogen atmosphere

    SciTech Connect

    Pérez del Pino, Ángel Cabana, Laura; Tobias, Gerard; György, Enikö; Ballesteros, Belén

    2014-03-07

    Laser irradiation of randomly oriented multi-walled carbon nanotube (MWCNT) networks has been carried out using a pulsed Nd:YAG UV laser in nitrogen gas environment. The evolution of the MWCNT morphology and structure as a function of laser fluence and number of accumulated laser pulses has been studied using electron microscopies and Raman spectroscopy. The observed changes are discussed and correlated with thermal simulations. The obtained results indicate that laser irradiation induces very fast, high temperature thermal cycles in MWCNTs which produce the formation of different nanocarbon forms, such as nanodiamonds. Premelting processes have been observed in localized sites by irradiation at low number of laser pulses and low fluence values. The accumulation of laser pulses and the increase in the fluence cause the full melting and amorphization of MWCNTs. The observed structural changes differ from that of conventional high temperature annealing treatments of MWCNTs.

  20. The effects of pulsed ultraviolet and infra-red lasers on dental enamel.

    PubMed

    Frentzen, M; Winkelsträter, C; van Benthem, H; Koort, H J

    1996-09-01

    To evaluate micromorphological changes seen in enamel following irradiation with pulsed lasers, extracted human teeth were treated with a TEA-CO2, an Er:YAG and an ArF laser systems. Light and scanning electron microscopic studies demonstrate that the Er:YAG laser produces a zone of microcracks in the subsurface area. While TEA-CO2 laser irradiation results mostly in surface melting, the Er:YAG laser produces a roughened enamel surface. After ArF laser irradiation a retentive surface appears, accompanied by some melting effects and an increased porosity. The observed results of all the employed laboratory type lasers varied over a wide range due to the widespread biologic differences in tooth structures.

  1. High-space resolution imaging plate analysis of extreme ultraviolet (EUV) light from tin laser-produced plasmas

    NASA Astrophysics Data System (ADS)

    Musgrave, Christopher S. A.; Murakami, Takehiro; Ugomori, Teruyuki; Yoshida, Kensuke; Fujioka, Shinsuke; Nishimura, Hiroaki; Atarashi, Hironori; Iyoda, Tomokazu; Nagai, Keiji

    2017-03-01

    With the advent of high volume manufacturing capabilities by extreme ultraviolet lithography, constant improvements in light source design and cost-efficiency are required. Currently, light intensity and conversion efficiency (CE) measurments are obtained by charged couple devices, faraday cups etc, but also phoshpor imaging plates (IPs) (BaFBr:Eu). IPs are sensitive to light and high-energy species, which is ideal for studying extreme ultraviolet (EUV) light from laser produced plasmas (LPPs). In this work, we used IPs to observe a large angular distribution (10°-90°). We ablated a tin target by high-energy lasers (1064 nm Nd:YAG, 1010 and 1011 W/cm2) to generate the EUV light. The europium ions in the IP were trapped in a higher energy state from exposure to EUV light and high-energy species. The light intensity was angular dependent; therefore excitation of the IP depends on the angle, and so highly informative about the LPP. We obtained high-space resolution (345 μm, 0.2°) angular distribution and grazing spectrometer (5-20 nm grate) data simultaneously at different target to IP distances (103 mm and 200 mm). Two laser systems and IP types (BAS-TR and BAS-SR) were also compared. The cosine fitting values from the IP data were used to calculate the CE to be 1.6% (SD ± 0.2) at 13.5 nm 2% bandwidth. Finally, a practical assessment of IPs and a damage issue are disclosed.

  2. Dynamics of defects in Ce³⁺ doped silica affecting its performance as protective filter in ultraviolet high-power lasers.

    PubMed

    Demos, Stavros G; Ehrmann, Paul R; Qiu, S Roger; Schaffers, Kathleen I; Suratwala, Tayyab I

    2014-11-17

    We investigate defects forming in Ce³⁺-doped fused silica samples following exposure to nanosecond ultraviolet laser pulses and their relaxation as a function of time and exposure to low intensity light at different wavelengths. A subset of these defects are responsible for inducing absorption in the visible and near infrared spectral range, which is of critical importance for the use of this material as ultraviolet light absorbing filter in high power laser systems. The dependence of the induced absorption as a function of laser fluence and methods to most efficiently mitigate this effect are presented. Experiments simulating the operation of the material as a UV protection filter for high power laser systems were performed in order to determine limitations and practical operational conditions.

  3. Simulation of Temperature Field Distribution for Cutting the Temperated Glass by Ultraviolet Laser

    NASA Astrophysics Data System (ADS)

    Yang, B. J.; He, Y. C.; Dai, F.; Lin, X. C.

    2017-03-01

    The finite element software ANSYS was adopted to simulate the temperature field distribution for laser cutting tempered glass, and the influence of different process parameters, including laser power, glass thickness and cutting speed, on temperature field distribution was studied in detail. The results show that the laser power has a greater influence on temperature field distribution than other paremeters, and when the laser power gets to 60W, the highest temperature reaches 749°C, which is higher than the glass softening temperature. It reflects the material near the laser spot is melted and the molten slag is removed by the high-energy water beam quickly. Finally, through the water guided laser cutting tempered glass experiment the FEM theoretical analysis was verified.

  4. High-resolution imaging spectrometer for recording absolutely calibrated far ultraviolet spectra from laser-produced plasmas

    SciTech Connect

    Brown, Charles M.; Seely, John F.; Feldman, Uri; Holland, Glenn E.; Weaver, James L.; Obenschain, Steven P.; Kjornrattanawanich, Benjawan; Fielding, Drew

    2008-10-15

    An imaging spectrometer was designed and fabricated for recording far ultraviolet spectra from laser-produced plasmas with wavelengths as short as 155 nm. The spectrometer implements a Cassegrain telescope and two gratings in a tandem Wadsworth optical configuration that provides diffraction limited resolution. Spectral images were recorded from plasmas produced by the irradiation of various target materials by intense KrF laser radiation with 248 nm wavelength. Two pairs of high-resolution gratings can be selected for the coverage of two wavebands, one grating pair with 1800 grooves/mm and covering approximately 155-175 nm and another grating pair with 1200 grooves/mm covering 230-260 nm. The latter waveband includes the 248 nm KrF laser wavelength, and the former waveband includes the wavelength of the two-plasmon decay instability at (2/3) the KrF laser wavelength (165 nm). The detection media consist of a complementary metal oxide semiconductor imager, photostimulable phosphor image plates, and a linear array of 1 mm{sup 2} square silicon photodiodes with 0.4 ns rise time. The telescope mirrors, spectrometer gratings, and 1 mm{sup 2} photodiode were calibrated using synchrotron radiation, and this enables the measurement of the absolute emission from the laser-produced plasmas with temporal, spatial, and spectral resolutions. The spectrometer is capable of measuring absolute spectral emissions at 165 nm wavelength as small as 5x10{sup -7} J/nm from a plasma source area of 0.37 mm{sup 2} and with 0.4 ns time resolution.

  5. Development of Extreme Ultraviolet Radiation Source using Laser Triggered Vacuum Spark Discharge Plasma

    SciTech Connect

    Watanabe, Masato; Yamada, Junzaburo; Zhu Qiushi; Hotta, Eiki

    2009-01-21

    A laser triggerd discharge produced Sn plasma light source has been developed. Experimental parameters such as electrode separation and laser irradiation power are varied to optimize EUV emission power. It is clear that the maximum EUV radiation was occurred in the position where the pinch was observed.

  6. Laser Raman Spectroscopy of Ultraviolet-Induced Cataracts in Rabbits and Monkeys.

    DTIC Science & Technology

    1979-12-01

    and release of thermal energy that is enough to disrupt the protein- water network . Usually, thermal mechanism is meant to imply thermal denaturation...involved in suprathreshold laser UV cataractogenesis is thermal in nature--a heat-disruptive effect of the laser beam on the protein- water network , with

  7. Periodic nanostructuring of Er/Yb-codoped IOG1 phosphate glass by using ultraviolet laser-assisted selective chemical etching

    SciTech Connect

    Pappas, C.; Pissadakis, S.

    2006-12-01

    The patterning of submicron period ({approx_equal}500 nm) Bragg reflectors in the Er/Yb-codoped IOG1 Schott, phosphate glass is demonstrated. A high yield patterning technique is presented, wherein high volume damage is induced into the glass matrix by exposure to intense ultraviolet 213 nm, 150 ps Nd:YAG laser radiation and, subsequently, a chemical development in potassium hydroxide (KOH)/ethylenediamine tetra-acetic acid (EDTA) aqueous solution selectively etches the exposed areas. The electronic changes induced by the 213 nm ultraviolet irradiation are examined by employing spectrophotometric measurements, while an estimation of the refractive index changes recorded is provided by applying Kramers-Kronig transformation to the absorption change data. In addition, real time diffraction efficiency measurements were obtained during the formation of the volume damage grating. After the exposure, the growth of the relief grating pattern in time was measured at fixed time intervals and the dependence of the grating depth on the etching time and exposure conditions is presented. The gratings fabricated are examined by atomic and scanning electron microscopies to reveal the relief topology of the structures. Gratings with average depth of 120 nm and excellent surface quality were fabricated by exposing the IOG1 phosphate glass to 36 000 pulses of 208 mJ/cm{sup 2} energy density, followed by developing in the KOH/EDTA agent for 6 min.

  8. Operation of a free electron laser in the wavelength range from the extreme ultraviolet to the water window

    SciTech Connect

    Ackermann, W.; Asova, G.; Ayvazyan, V.; Azima, A.; Baboi, N.; Bahr, J.; Balandin, V.; Beutner, B.; Brandt, A.; Bolzmann, A.; Brinkmann, R.; /DESY /Dubna, JINR

    2007-01-01

    We report results on the performance of a free-electron laser operating at a wavelength of 13.7 nm where unprecedented peak and average powers for a coherent extreme-ultraviolet radiation source have been measured. In the saturation regime, the peak energy approached 170 J for individual pulses, and the average energy per pulse reached 70 J. The pulse duration was in the region of 10 fs, and peak powers of 10 GW were achieved. At a pulse repetition frequency of 700 pulses per second, the average extreme-ultraviolet power reached 20 mW. The output beam also contained a significant contribution from odd harmonics of approximately 0.6% and 0.03% for the 3rd (4.6 nm) and the 5th (2.75 nm) harmonics, respectively. At 2.75 nm the 5th harmonic of the radiation reaches deep into the water window, a wavelength range that is crucially important for the investigation of biological samples.

  9. Direct micro-patterning of biodegradable polymers using ultraviolet and femtosecond lasers.

    PubMed

    Aguilar, Carlos A; Lu, Yi; Mao, Samuel; Chen, Shaochen

    2005-12-01

    Thin films of biodegradable polymeric materials, poly(epsilon-caprolactone) (PCL) and poly(glycolic acid) (PGA) were micro-patterned using a Ti-sapphire femtosecond pulsed laser and ArF excimer UV laser in ambient conditions. The laser-patterned polymers were characterized using a scanning electron microscope (SEM), Fourier transform infrared spectroscopy in attenuated total reflectance mode (FTIR-ATR) and X-ray photoelectron spectroscopy (XPS). In-vitro degradation tests were performed and the laser-patterned samples showed to be within one standard deviation of the control samples. Our results demonstrate that both lasers are excellent tools for micro-patterning biodegradable polymers since the bulk properties of the material can remain intact and because the direct-write method is rapid, flexible, and a chemical-free process.

  10. Characteristics of ultraviolet-assisted pulsed-laser-deposited Y{sub 2}O{sub 3} thin films

    SciTech Connect

    Cracium, V.; Lambers, E. S.; Bassim, N. D.; Singh, R. K.; Craciun, D.

    2000-02-01

    The properties of thin Y{sub 2}O{sub 3} films grown using an in situ ultraviolet (UV)-assisted pulsed laser deposition (PLD) technique were studied. With respect to Y{sub 2}O{sub 3} films grown by conventional PLD under similar conditions but without UV illumination, the UVPLD-grown films exhibited better structural and optical properties, especially for lower substrate temperatures, from 340 to 400 degree sign C. These layers were highly crystalline and textured along the (111) direction, and their refractive index values were similar to those of reference Y{sub 2}O{sub 3} layers. They also exhibited a better stoichiometry and contained less physisorbed oxygen than the conventional PLD-grown layers. (c) 2000 Materials Research Society.

  11. Large TE polarized optical gain from AlInN-delta-GaN quantum well for ultraviolet lasers

    NASA Astrophysics Data System (ADS)

    Liu, Cheng; Ooi, Yu Kee; Zhang, Jing

    2016-03-01

    Ultraviolet (UV) lasers with wavelength (λ) < 300 nm have important applications in free-space communication, water/air purification, and biochemical agent detection. Conventionally, AlGaN quantum wells (QWs) are widely used as active region for UV lasers. However, high-efficiency electrically injected mid-UV lasers with λ ~ 250-300 nm are still very challenging as the corresponding AlGaN QWs suffer from severe band-mixing effect due to the presence of the valence sub-band crossover between the heavy-hole (HH) and crystal-field split off (CH) sub-bands, which would result in very low optical gain in such wavelength regime. Therefore, in this work, we propose and investigate the use of AlInN material system as an alternative for mid-UV lasers. Nanostructure engineering by the use of AlInN-delta-GaN QW has been performed to enable dominant conduction band - HH sub-band transition as well as optimized electron-hole wave function overlap. The insertion of the ultra-thin delta-GaN layer, which is lattice-matched to Al0.82In0.18N layer, would localize the wave functions strongly toward the center of the active region, leading to large transverse electric (TE) polarized optical gain (gTE) for λ~ 250- 300 nm. From our finding, the use of AlInN-delta-GaN QW resulted in ~ 3-times enhancement in TE-polarized optical gain, in comparison to that of conventional AlGaN QW, for gain media emitting at ~ 255 nm. The peak emission wavelength can be tuned by varying the delta layer thickness while maintaining large TE gain. Specifically, gTE ~ 3700 cm-1 was obtained for λ ~ 280-300 nm, which are very challenging for conventional AlGaN QW active region.

  12. Fabrication of electrodes on the aluminum doped zinc oxide thin films using an ultraviolet laser direct-patterning technology

    NASA Astrophysics Data System (ADS)

    Hsiao, Wen-Tse; Tseng, Shih-Feng; Kuo, Chao-Hui; Huang, Kuo-Cheng; Chiang, Donyau; Yao, Pin-Chiun; Chen, Ming-Fei

    Because transparent conductive oxide (TCO) thin films have more than 80% transmittance in visible spectrum, and high electrical conductivity, the TCO films are widely applied to flat panel displays and solar cells as transparent electrode materials. This study aims to develop a direct patterning technology on ZnO:Al (AZO) thin films by a diode-pumped solid state ultraviolet laser. The electrode patterns with array structures on AZO thin films were generated by a high-speed galvanometric scanning system. The optoelectronic properties of a patterned electrode have strong relation with the laser pulse frequency, the scan speed, and the patterning time. The surface morphology and roughness of patterned electrode were measured by three dimension confocal microscope and field emission scanning electron microscope, respectively. The resistivity of AZO thin films before and after laser patterning was measured by a four point probe instrument. The optical transmittance was recorded by a UV/VIS/NIR spectrophotometer. The experimental results indicated that the edge line width and depth decreased with increasing the scan speed. After the array patterns structure were formed by laser dry etching, the roughness Ra values of patterned area increased from 0.06 μm to 0.16 μm. These transmittances of patterned structure from 400 nm to 800 nm wavelengths averagely reached to 82%. The measured results of electrical conductively revealed that the resistivity gradually increased with increasing the pulse repetition frequency. In addition, surface morphologic examination on the straight lines, corners, and etched regions of patterned films revealed no micro-cracks observed which meant the patterned surface had a better surface quality.

  13. Efficient 13.5 nm extreme ultraviolet emission from Sn plasma irradiated by a long CO{sub 2} laser pulse

    SciTech Connect

    Tao, Y.; Tillack, M. S.; Sequoia, K. L.; Burdt, R. A.; Yuspeh, S.; Najmabadi, F.

    2008-06-23

    The effect of pulse duration on in-band (2% bandwidth) conversion efficiency (CE) from a CO{sub 2} laser to 13.5 nm extreme ultraviolet (EUV) light was investigated for Sn plasma. It was found that high in-band CE, 2.6%, is consistently obtained using a CO{sub 2} laser with pulse durations from 25 to 110 ns. Employing a long pulse, for example, 110 ns, in a CO{sub 2} laser system used in an EUV lithography source could make the system significantly more efficient, simpler, and cheaper as compared to that using a short pulse of 25 ns or shorter.

  14. Effects of ultraviolet nanosecond laser irradiation on structural modification and optical transmission of single layer graphene

    NASA Astrophysics Data System (ADS)

    Li, Chunhong; Kang, Xiaoli; Zhu, Qihua; Zheng, Wanguo

    2017-03-01

    Structural modifications and optical transmission change of single layer graphene (SLG) on transparent SiO2 substrate induced by nanosecond 355 nm laser irradiation were systematically studied by scanning electron microscopy (SEM), laser-excited Raman, X-ray photon spectroscopy (XPS) and UV-vis transmission spectra. In this study, to avoid damage to graphene, the selected irradiation fluence was set to be smaller than the laser damage threshold of SLG. Laser-driven formation of nano-dots, carbon clusters and spherical carbon morphologies were clearly presented using SEM magnification images, and the formation mechanism of such structures were discussed. Raman spectra revealed formation of D' peak and the continuously increasing of ID/IG intensity ratio with the concurrent increase of laser fluence, indicating the increase in amount of structural defects and disordering in SLG. XPS results disclosed that the oxygen content in SLG increases with laser fluence. The formation and relative content increase of Cdbnd O, Csbnd Osbnd C and Osbnd Cdbnd O bonds in SLG induced by laser irradiation were also revealed by XPS. Laser-driven micro-structure modifications of crystalline graphene to nano-crystalline graphene and photo-chemical reactions between graphene and O2 and H2O in air environment were suggested to be responsible for the Raman and XPS revealed modifications in SLG. It is worthy to point out that the above mentioned structural modifications only caused a slight decrease (<2% @ 550 nm) in the optical transmittance of SLG. These results may provide more selections for the batch processing of large scale graphene aiming at modifying its structure and thus taiorling its properties.

  15. Different dynamics of ultraviolet upconversion in Tm3+:ZBLAN glass under blue laser excitation

    NASA Astrophysics Data System (ADS)

    Yang, Haigui; Gao, Jinsong

    2013-10-01

    Ultraviolet upconversion luminescence around 292 nm, 350 nm and 363 nm in Tm3+:ZBLAN glass was observed clearly by pulsed excitation at 464 nm. Upconversion dynamics was discussed in detail by an analysis of the measured intensity dependence, decay curves and excitation spectra of upconversion luminescence, from which it was clarified that upconversion luminescence around 292 nm and 350 nm from 1I6 level was attributed to excited state absorption, while that around 363 nm from 1D2 level was attributed to energy transfer process.

  16. Fiber-laser-based, high-repetition-rate, picosecond ultraviolet source tunable across 329-348  nm.

    PubMed

    Devi, Kavita; Chaitanya Kumar, S; Ebrahim-Zadeh, M

    2016-10-15

    We report a compact, fiber-laser-based, high-repetition-rate picosecond source for the ultraviolet (UV), providing multi-tens of milliwatt of average power across 329-348 nm. The source is based on internal sum-frequency-generation (SFG) in a singly resonant optical parametric oscillator (OPO), synchronously pumped at 532 nm by the second harmonic of a picosecond Yb-fiber laser at 80 MHz repetition rate. Using a 30-mm-long single-grating MgO:sPPLT crystal for the OPO and a 5-mm-long BiB3O6 crystal for intracavity SFG, we generate up to 115 mW of average UV power at 339.9 nm, with >50  mW over 73% of the tuning range, for 1.6 W of input pump power. The UV output exhibits a passive rms power stability of ∼2.9% rms over 1 min and 6.5% rms over 2 h in high beam quality. Angular acceptance bandwidth and cavity detuning effects have also been studied.

  17. Green and ultraviolet pulse generation with a compact, fiber laser, chirped-pulse amplification system for aerosol fluorescence measurements

    NASA Astrophysics Data System (ADS)

    Lou, Janet W.; Currie, Marc; Sivaprakasam, Vasanthi; Eversole, Jay D.

    2010-10-01

    We use a compact chirped-pulse amplified system to harmonically generate ultrashort pulses for aerosol fluorescence measurements. The seed laser is a compact, all-normal dispersion, mode-locked Yb-doped fiber laser with a 1050 nm center wavelength operating at 41 MHz. Average powers of more than 1.2 W at 525 nm and 350 mW at 262 nm are generated with <500 fs pulse durations. The pulses are time-stretched with high-dispersion fiber, amplified by a high-power, large-mode-area fiber amplifier, and recompressed using a chirped volume holographic Bragg grating. The resulting high-peak-power pulses allow for highly efficient harmonic generation. We also demonstrate for the first time to our knowledge, the use of a mode-locked ultraviolet source to excite individual biological particles and other calibration particles in an inlet air flow as they pass through an optical chamber. The repetition rate is ideal for biofluorescence measurements as it allows faster sampling rates as well as the higher peak powers as compared to previously demonstrated Q-switched systems while maintaining a pulse period that is longer than the typical fluorescence lifetimes. Thus, the fluorescence excitation can be considered to be quasicontinuous and requires no external synchronization and triggering.

  18. Time-resolved detection of aromatic compounds on planetary surfaces by ultraviolet laser induced fluorescence and Raman spectroscopy

    NASA Astrophysics Data System (ADS)

    Eshelman, E.; Daly, M. G.; Slater, G.; Cloutis, E.

    2015-12-01

    Raman spectroscopic instruments are highly capable in the search for organics on Mars due to the potential to perform rapid and nondestructive measurements on unprepared samples. Upcoming and future Raman instruments are likely to also incorporate laser-induced fluorescence (LIF) capabilities, which can be added for modest cost and complexity. We demonstrate that it is possible to obtain sub-ns fluorescence lifetime measurements of Mars-relevant organics and minerals if a fast time-gating capability is used with an intensified detector and a short ultraviolet laser pulse. This serves a primary purpose of discriminating mineral from short-lived (less than 10 ns) organic fluorescence, considered a potential biosignature. Additionally, lifetime measurements may assist in determining if more than one fluorescing species is present and provide information concerning the molecular structure as well as the local environment. Fast time-gating is also useful at longer visible or near-IR wavelengths, as this approach increases the sensitivity of the instrument to organic material by removing the majority of the fluorescence background from the Raman signal and reducing the effect of ambient light.

  19. Characterization of electrically-active defects in ultraviolet light-emitting diodes with laser-based failure analysis techniques

    SciTech Connect

    Miller, Mary A.; Tangyunyong, Paiboon; Cole, Edward I.

    2016-01-14

    Laser-based failure analysis techniques demonstrate the ability to quickly and non-intrusively screen deep ultraviolet light-emitting diodes (LEDs) for electrically-active defects. In particular, two laser-based techniques, light-induced voltage alteration and thermally-induced voltage alteration, generate applied voltage maps (AVMs) that provide information on electrically-active defect behavior including turn-on bias, density, and spatial location. Here, multiple commercial LEDs were examined and found to have dark defect signals in the AVM indicating a site of reduced resistance or leakage through the diode. The existence of the dark defect signals in the AVM correlates strongly with an increased forward-bias leakage current. This increased leakage is not present in devices without AVM signals. Transmission electron microscopy analysis of a dark defect signal site revealed a dislocation cluster through the pn junction. The cluster included an open core dislocation. Even though LEDs with few dark AVM defect signals did not correlate strongly with power loss, direct association between increased open core dislocation densities and reduced LED device performance has been presented elsewhere [M. W. Moseley et al., J. Appl. Phys. 117, 095301 (2015)].

  20. Green and ultraviolet pulse generation with a compact, fiber laser, chirped-pulse amplification system for aerosol fluorescence measurements.

    PubMed

    Lou, Janet W; Currie, Marc; Sivaprakasam, Vasanthi; Eversole, Jay D

    2010-10-01

    We use a compact chirped-pulse amplified system to harmonically generate ultrashort pulses for aerosol fluorescence measurements. The seed laser is a compact, all-normal dispersion, mode-locked Yb-doped fiber laser with a 1050 nm center wavelength operating at 41 MHz. Average powers of more than 1.2 W at 525 nm and 350 mW at 262 nm are generated with <500 fs pulse durations. The pulses are time-stretched with high-dispersion fiber, amplified by a high-power, large-mode-area fiber amplifier, and recompressed using a chirped volume holographic Bragg grating. The resulting high-peak-power pulses allow for highly efficient harmonic generation. We also demonstrate for the first time to our knowledge, the use of a mode-locked ultraviolet source to excite individual biological particles and other calibration particles in an inlet air flow as they pass through an optical chamber. The repetition rate is ideal for biofluorescence measurements as it allows faster sampling rates as well as the higher peak powers as compared to previously demonstrated Q-switched systems while maintaining a pulse period that is longer than the typical fluorescence lifetimes. Thus, the fluorescence excitation can be considered to be quasicontinuous and requires no external synchronization and triggering.

  1. Characterization of electrically-active defects in ultraviolet light-emitting diodes with laser-based failure analysis techniques

    SciTech Connect

    Miller, Mary A.; Tangyunyong, Paiboon; Edward I. Cole, Jr.

    2016-01-12

    In this study, laser-based failure analysis techniques demonstrate the ability to quickly and non-intrusively screen deep ultraviolet light-emitting diodes(LEDs) for electrically-active defects. In particular, two laser-based techniques, light-induced voltage alteration and thermally-induced voltage alteration, generate applied voltage maps (AVMs) that provide information on electrically-active defect behavior including turn-on bias, density, and spatial location. Here, multiple commercial LEDs were examined and found to have dark defect signals in the AVM indicating a site of reduced resistance or leakage through the diode. The existence of the dark defect signals in the AVM correlates strongly with an increased forward-bias leakage current. This increased leakage is not present in devices without AVM signals. Transmission electron microscopyanalysis of a dark defect signal site revealed a dislocation cluster through the pn junction. The cluster included an open core dislocation. Even though LEDs with few dark AVM defect signals did not correlate strongly with power loss, direct association between increased open core dislocation densities and reduced LED device performance has been presented elsewhere [M. W. Moseley et al., J. Appl. Phys. 117, 095301 (2015)].

  2. Characterization of electrically-active defects in ultraviolet light-emitting diodes with laser-based failure analysis techniques

    DOE PAGES

    Miller, Mary A.; Tangyunyong, Paiboon; Edward I. Cole, Jr.

    2016-01-12

    In this study, laser-based failure analysis techniques demonstrate the ability to quickly and non-intrusively screen deep ultraviolet light-emitting diodes(LEDs) for electrically-active defects. In particular, two laser-based techniques, light-induced voltage alteration and thermally-induced voltage alteration, generate applied voltage maps (AVMs) that provide information on electrically-active defect behavior including turn-on bias, density, and spatial location. Here, multiple commercial LEDs were examined and found to have dark defect signals in the AVM indicating a site of reduced resistance or leakage through the diode. The existence of the dark defect signals in the AVM correlates strongly with an increased forward-bias leakage current. This increasedmore » leakage is not present in devices without AVM signals. Transmission electron microscopyanalysis of a dark defect signal site revealed a dislocation cluster through the pn junction. The cluster included an open core dislocation. Even though LEDs with few dark AVM defect signals did not correlate strongly with power loss, direct association between increased open core dislocation densities and reduced LED device performance has been presented elsewhere [M. W. Moseley et al., J. Appl. Phys. 117, 095301 (2015)].« less

  3. Characterization of electrically-active defects in ultraviolet light-emitting diodes with laser-based failure analysis techniques

    NASA Astrophysics Data System (ADS)

    Miller, Mary A.; Tangyunyong, Paiboon; Cole, Edward I.

    2016-01-01

    Laser-based failure analysis techniques demonstrate the ability to quickly and non-intrusively screen deep ultraviolet light-emitting diodes (LEDs) for electrically-active defects. In particular, two laser-based techniques, light-induced voltage alteration and thermally-induced voltage alteration, generate applied voltage maps (AVMs) that provide information on electrically-active defect behavior including turn-on bias, density, and spatial location. Here, multiple commercial LEDs were examined and found to have dark defect signals in the AVM indicating a site of reduced resistance or leakage through the diode. The existence of the dark defect signals in the AVM correlates strongly with an increased forward-bias leakage current. This increased leakage is not present in devices without AVM signals. Transmission electron microscopy analysis of a dark defect signal site revealed a dislocation cluster through the pn junction. The cluster included an open core dislocation. Even though LEDs with few dark AVM defect signals did not correlate strongly with power loss, direct association between increased open core dislocation densities and reduced LED device performance has been presented elsewhere [M. W. Moseley et al., J. Appl. Phys. 117, 095301 (2015)].

  4. Surface patterning of multilayer graphene by ultraviolet laser irradiation in biomolecule sensing devices

    NASA Astrophysics Data System (ADS)

    Chang, Tien-Li; Chen, Zhao-Chi

    2015-12-01

    The study presents a direct process for surface patterning of multilayer graphene on the glass substrate as a biosensing device. In contrast to lithography with etching, the proposed process provides simultaneous surface patterning of multilayer graphene through nanosecond laser irradiation. In this study, the multilayer graphene was prepared by a screen printing process. Additionally, the wavelength of the laser beam was 355 nm. To perform the effective laser process with the small heat affected zone, the surface patterns on the sensing devices could be directly fabricated using the laser with optimal control of the pulse overlap at a fluence threshold of 0.63 J/cm2. The unique patterning of the laser-ablated surface exhibits their electrical and hydrophilic characteristics. The hydrophilic surface of graphene-based sensing devices was achieved in the process with the pulse overlap of 90%. Furthermore, the sensing devices for controlling the electrical response of glucose by using glucose oxidase can be used in sensors in commercial medical applications.

  5. Positive ion emission from oxidized aluminum during ultraviolet excimer laser irradiation

    SciTech Connect

    Khan, Enamul; Langford, S. C.; Dickinson, J. T.

    2011-07-15

    We report quadrupole mass-selected time-of-flight measurements of positive ions from oxidized aluminum metal (and for comparison, single-crystal sapphire) during pulsed excimer laser irradiation at 193 and 248 nm. This work focuses on laser fluences well below onset of rapid etching or optical breakdown. By far the most intense emissions are due to Al{sup +}. On previously unexposed material, the ion kinetic energies are initially well above the photon energy, consistent with the ejection of Al{sup +} sorbed at surface electron traps. During prolonged irradiation, the emission intensities and kinetic energies gradually fall. Emission from patches of oxide would account for previous reports of laser-induced Al{sup +} emission from metallic aluminum surfaces cleaned by ion etching if patches of thin oxide were to survive the etching treatment.

  6. Ultraviolet conical emission produced by high-power femtosecond laser pulse in transparent media

    NASA Astrophysics Data System (ADS)

    Liu, Z.; Lu, X.; Liu, Q.; Sun, S.; Li, L.; Liu, X.; Ding, B.; Hu, B.

    2012-09-01

    In this work, supercontinuum conical emission (SC CE) accompanying the filamentation of powerful ultrashort laser pulse in BK7 glass and fused silica is studied. The SC CE is controlled by the laser power density and the sample thickness, and the minimum SC CE cut-off wavelength is about 309 nm in the BK7 glass and 237 nm in the fused silica. The angular distributions of the SC CE in the wavelength range less than 510 nm are measured by using a new method, and it cannot be explained by the Cerenkov emission theory but the unabridged X-Waves solution theory. Meanwhile numerical simulations of the propagation of femtosecond laser pulse in sample are performed to provide theoretical support to our results.

  7. Evidence of liquid phase during laser-induced periodic surface structures formation induced by accumulative ultraviolet picosecond laser beam

    SciTech Connect

    Huynh, T. T. D.; Petit, A.; Semmar, N.

    2015-11-09

    Laser-induced periodic surface structures (LIPSS) were formed on Cu/Si or Cu/glass thin films using Nd:YAG laser beam (40 ps, 10 Hz, and 30 mJ/cm{sup 2}). The study of ablation threshold is always achieved over melting when the variation of the number of pulses increases from 1 to 1000. But the incubation effect is leading to reduce the threshold of melting as increasing the number of laser pulse. Also, real time reflectivity signals exhibit typical behavior to stress the formation of a liquid phase during the laser-processing regime and helps to determine the threshold of soft ablation. Atomic Force Microscopy (AFM) analyses have shown the topology of the micro-crater containing regular spikes with different height. Transmission Electron Microscopy (TEM) allows finally to show three distinguished zones in the close region of isolated protrusions. The central zone is a typical crystallized area of few nanometers surrounded by a mixed poly-crystalline and amorphous area. Finally, in the region far from the protrusion zone, Cu film shows an amorphous structure. The real time reflectivity, AFM, and HR-TEM analyses evidence the formation of a liquid phase during the LIPSS formation in the picosecond regime.

  8. Ultraviolet and infrared femtosecond laser induced periodic surface structures on thin polymer films

    SciTech Connect

    Rebollar, Esther; Castillejo, Marta; Vazquez de Aldana, Javier R.; Moreno, Pablo

    2012-01-23

    This work demonstrates the formation of femtosecond laser induced periodic surface structures (LIPSS) by multipulse irradiation with the fundamental and 3rd harmonic of a linearly polarized Ti:sapphire laser (795 and 265 nm) on thin films of the polymers poly (ethylene terephthalate), poly (trimethylene terephthalate), and poly (carbonate bisphenol A) prepared by spin-coating. LIPSS, inspected by atomic force microscopy, are formed upon multiple pulse UV and IR irradiation with wavelength-sized period in a narrow range of fluences below the ablation threshold. Control and tunability of the size and morphology of the periodic structures become thus possible ensuring photochemical integrity of polymer films.

  9. High-resolution threshold photoelectron study of the propargyl radical by the vacuum ultraviolet laser velocity-map imaging method.

    PubMed

    Gao, Hong; Xu, Yuntao; Yang, Lei; Lam, Chow-Shing; Wang, Hailing; Zhou, Jingang; Ng, C Y

    2011-12-14

    By employing the vacuum ultraviolet (VUV) laser velocity-map imaging (VMI) photoelectron scheme to discriminate energetic photoelectrons, we have measured the VUV-VMI-threshold photoelectrons (VUV-VMI-TPE) spectra of propargyl radical [C(3)H(3)(X̃(2)B(1))] near its ionization threshold at photoelectron energy bandwidths of 3 and 7 cm(-1) (full-width at half-maximum, FWHM). The simulation of the VUV-VMI-TPE spectra thus obtained, along with the Stark shift correction, has allowed the determination of a precise value 70 156 ± 4 cm(-1) (8.6982 ± 0.0005 eV) for the ionization energy (IE) of C(3)H(3). In the present VMI-TPE experiment, the Stark shift correction is determined by comparing the VUV-VMI-TPE and VUV laser pulsed field ionization-photoelectron (VUV-PFI-PE) spectra for the origin band of the photoelectron spectrum of the X̃(+)-X̃ transition of chlorobenzene. The fact that the FWHMs for this origin band observed using the VUV-VMI-TPE and VUV-PFI-PE methods are nearly the same indicates that the energy resolutions achieved in the VUV-VMI-TPE and VUV-PFI-PE measurements are comparable. The IE(C(3)H(3)) value obtained based on the VUV-VMI-TPE measurement is consistent with the value determined by the VUV laser PIE spectrum of supersonically cooled C(3)H(3)(X̃(2)B(1)) radicals, which is also reported in this article.

  10. A 7.81 W 355 nm ultraviolet picosecond laser using La2CaB10O19 as a nonlinear optical crystal.

    PubMed

    Zhang, Ling; Li, Kai; Xu, Degang; Yu, Haijuan; Zhang, Guochun; Wang, Yuye; Wang, Lirong; Shan, Faxian; Yan, Chao; Yang, Yingying; Wang, Baohua; Wang, Nan; Lin, Xuechun; Wu, Yicheng; Yao, Jianquan

    2014-07-14

    We demonstrate high-power 355 nm ultraviolet (UV) picosecond (ps) laser using a type I phase-matching nonlinear optical crystal of La(2)CaB(10)O(19) (LCB), which possesses the characteristic of non-hygroscopicity. The high-power third harmonic generation was successfully achieved from two types of 1064 nm ps fundamental lasers. The maximum output power of 7.81 W of 355 nm UV laser was obtained with a pump of 35.2 W 1064 nm ps laser (80 MHz repetition rate, 10 ps pulse width) with optical conversion efficiency of 22.2%. The experimental results show that the LCB crystal is a promising candidate for generating high-power UV laser.

  11. Far-infrared-light shadowgraphy for high extraction efficiency of extreme ultraviolet light from a CO2-laser-generated tin plasma

    NASA Astrophysics Data System (ADS)

    Matsukuma, Hiraku; Hosoda, Tatsuya; Suzuki, Yosuke; Yogo, Akifumi; Yanagida, Tatsuya; Kodama, Takeshi; Nishimura, Hiroaki

    2016-08-01

    The two-color, double-pulse method is an efficient scheme to generate extreme ultraviolet light for fabricating the next generation semiconductor microchips. In this method, a Nd:YAG laser pulse is used to expand a several-tens-of-micrometers-scale tin droplet, and a CO2 laser pulse is subsequently directed at the expanded tin vapor after an appropriate delay time. We propose the use of shadowgraphy with a CO2 laser probe-pulse scheme to optimize the CO2 main-drive laser. The distribution of absorption coefficients is derived from the experiment, and the results are converted to a practical absorption rate for the CO2 main-drive laser.

  12. The use of ultraviolet Thomson scattering as a versatile diagnostic for detailed measurements of a collisional laser produced plasma

    SciTech Connect

    Tracy, Mark David

    1993-01-08

    Collective Thomson scattering from ion-acoustic waves at 266nm is used to obtain spatially resolved, two-dimensional electron density, sound speed, and radial drift profiles of a collisional laser plasma. An ultraviolet diagnostic wavelength minimizes the complicating effects of inverse bremsstrahlung and refractive turning in the coronal region of interest, where the electron densities approach nc/10. Laser plasmas of this type are important because they model some of the aspects of the plasmas found in high-gain laser-fusion pellets irradiated by long pulse widths where the laser light is absorbed mostly in the corona. The experimental results and LASNEX simulations agree within a percent standard deviation of 40% for the electron density and 50% for the sound speed and radial drift velocity. Thus it is shown that the hydrodynamics equations with classical coefficients and the numerical approximations in LASNEX are valid models of laser-heated, highly collisional plasmas. The versatility of Thomson scattering is expanded upon by extending existing theory with a Fokker-Planck based model to include plasmas that are characterized by (0 ≤ kiaλii ≤ ∞) and ZTe/Ti, where kia is the ion- acoustic wave number, λii is the ion-ion mean free path, Z is the ionization state of the plasma, and Te. Ti are the electron and ion temperatures in electron volts respectively. The model is valid for plasmas in which the electrons are approximately collisionless, (kiaλei, kiaλee ≥ 1), and quasineutrality holds, (α ≥1), where α = 1/kλDE and λDe is the electron Debye length. This newly developed model predicts the lineshape of the ion-acoustic Thomson spectra and when fit to experimental data provides a direct measurement of the relative thermal flow velocity between the electrons and ions.

  13. Selective removal of composite sealants with near-ultraviolet laser pulses of nanosecond duration.

    PubMed

    Louie, Tiffany M; Jones, Robert S; Sarma, Anupama V; Fried, Daniel

    2005-01-01

    It is often necessary to replace pit and fissure sealants and composite restorations. This task is complicated by the necessity for complete removal of the remaining composite to enable suitable adhesion of new composite. Previous studies have shown that 355-nm laser pulses from a frequency-tripled Nd:YAG laser can selectively remove residual composite after orthodontic bracket removal on enamel surfaces. Our objective is to determine if such laser pulses are suitable for selective removal of composite pit and fissure sealants and restorations. Optical coherence tomography is used to acquire optical cross sections of the occlusal topography nondestructively before sealant application, after sealant application, and after sealant removal. Thermocouples are used to monitor the temperature in the pulp chamber during composite removal under clinically relevant ablation rates, i.e., 30 Hz and 30 mJ/pulse. At an irradiation intensity of 1.3 J/cm2, pit and fissure sealants are completely removed without visible damage to the underlying enamel. At intensities above 1.5 J/cm2, incident laser pulses remove the resin layer while at the same time preferentially etching the surface of the enamel. Temperature excursions in the pulp chamber of extracted teeth are limited to less than 5 degrees C if air-cooling is used during the rapid removal (1 to 2 min) of sealants, water-cooling is not necessary. Selective removal of composite restorative materials is possible without damage to the underlying sound tooth structure.

  14. Wavefront measurement of single-mode quantum cascade laser beam for seed application in laser-produced plasma extreme ultraviolet system.

    PubMed

    Nowak, Krzysztof M; Ohta, Takeshi; Suganuma, Takashi; Yokotsuka, Toshio; Fujimoto, Junichi; Mizoguchi, Hakaru

    2012-12-01

    Quantum cascade laser (QCL) is a very attractive seed source for a multikilowatt pulsed CO2 lasers applied for driving extreme ultraviolet emitting plasmas. In this Letter, we investigate output beam properties of a QCL designed to address P18 and P20 lines of 10.6 micron band of CO2 molecule. In particular, output beam quality and stability are investigated for the first time. A well-defined linear polarization and a single-mode operation enabled a use of phase retrieval method for full description of QCL output beam. A direct, multi-image numerical phase retrieval technique was developed and successfully applied to the measured intensity patterns of a QCL beam. Very good agreement between the measured and reconstructed beam profiles was observed at distances ranging from QCL aperture to infinity, proving a good understanding of the beam propagation. The results also confirm a high spatial coherence and high stability of the beam parameters, the features expected from an excellent seed source.

  15. An extreme ultraviolet Michelson interferometer for experiments at free-electron lasers

    NASA Astrophysics Data System (ADS)

    Hilbert, Vinzenz; Blinne, Alexander; Fuchs, Silvio; Feigl, Torsten; Kämpfer, Tino; Rödel, Christian; Uschmann, Ingo; Wünsche, Martin; Paulus, Gerhard G.; Förster, Eckhart; Zastrau, Ulf

    2013-09-01

    We present a Michelson interferometer for 13.5 nm soft x-ray radiation. It is characterized in a proof-of-principle experiment using synchrotron radiation, where the temporal coherence is measured to be 13 fs. The curvature of the thin-film beam splitter membrane is derived from the observed fringe pattern. The applicability of this Michelson interferometer at intense free-electron lasers is investigated, particularly with respect to radiation damage. This study highlights the potential role of such Michelson interferometers in solid density plasma investigations using, for instance, extreme soft x-ray free-electron lasers. A setup using the Michelson interferometer for pseudo-Nomarski-interferometry is proposed.

  16. The effect of quantum correction on plasma electron heating in ultraviolet laser interaction

    SciTech Connect

    Zare, S.; Sadighi-Bonabi, R. Anvari, A.; Yazdani, E.; Hora, H.

    2015-04-14

    The interaction of the sub-picosecond UV laser in sub-relativistic intensities with deuterium is investigated. At high plasma temperatures, based on the quantum correction in the collision frequency, the electron heating and the ion block generation in plasma are studied. It is found that due to the quantum correction, the electron heating increases considerably and the electron temperature uniformly reaches up to the maximum value of 4.91 × 10{sup 7 }K. Considering the quantum correction, the electron temperature at the laser initial coupling stage is improved more than 66.55% of the amount achieved in the classical model. As a consequence, by the modified collision frequency, the ion block is accelerated quicker with higher maximum velocity in comparison with the one by the classical collision frequency. This study proves the necessity of considering a quantum mechanical correction in the collision frequency at high plasma temperatures.

  17. Cluster beam targets for laser plasma extreme ultraviolet and soft x-ray sources

    DOEpatents

    Kublak, Glenn D.; Richardson, Martin C. (CREOL

    1996-01-01

    Method and apparatus for producing extreme ultra violet (EUV) and soft x-ray radiation from an ultra-low debris plasma source are disclosed. Targets are produced by the free jet expansion of various gases through a temperature controlled nozzle to form molecular clusters. These target clusters are subsequently irradiated with commercially available lasers of moderate intensity (10.sup.11 -10.sup.12 watts/cm.sup.2) to produce a plasma radiating in the region of 0.5 to 100 nanometers. By appropriate adjustment of the experimental conditions the laser focus can be moved 10-30 mm from the nozzle thereby eliminating debris produced by plasma erosion of the nozzle.

  18. Ultraviolet laser treatment of multiwall carbon nanotubes grown at low temperature

    NASA Astrophysics Data System (ADS)

    Kim, J. S.; Ahn, K. S.; Kim, C. O.; Hong, J. P.

    2003-03-01

    Simple laser irradiation of well-aligned multiwall carbon nanotubes (MWCNTs) was performed to intentionally modify structural defects and to ablate possible contamination of the MWCNTs. Scanning electron microscopy and transmission electron microscopy confirmed the clear presence of the MWCNTs with open tips. A Raman spectra exhibited a decrease in an intensity ratio (ID/IG) of 1352 cm-1 (D band) over 1583 cm-1 (G band) peaks by significantly reducing the amorphous carbon phases of D band peaks. The structural improvement in the MWCNTs after optimum laser exposure resulted in a reduction of the turn-on voltage from 1.0 to 0.6 V/μm and an increase in the emission current.

  19. An extreme ultraviolet Michelson interferometer for experiments at free-electron lasers.

    PubMed

    Hilbert, Vinzenz; Blinne, Alexander; Fuchs, Silvio; Feigl, Torsten; Kämpfer, Tino; Rödel, Christian; Uschmann, Ingo; Wünsche, Martin; Paulus, Gerhard G; Förster, Eckhart; Zastrau, Ulf

    2013-09-01

    We present a Michelson interferometer for 13.5 nm soft x-ray radiation. It is characterized in a proof-of-principle experiment using synchrotron radiation, where the temporal coherence is measured to be 13 fs. The curvature of the thin-film beam splitter membrane is derived from the observed fringe pattern. The applicability of this Michelson interferometer at intense free-electron lasers is investigated, particularly with respect to radiation damage. This study highlights the potential role of such Michelson interferometers in solid density plasma investigations using, for instance, extreme soft x-ray free-electron lasers. A setup using the Michelson interferometer for pseudo-Nomarski-interferometry is proposed.

  20. Solid-state laser source of narrowband ultraviolet B light for skin disease care

    NASA Astrophysics Data System (ADS)

    Tarasov, Aleksandr A.; Chu, Hong

    2013-03-01

    We report about the development of all-solid-state laser source of narrowband UV-B light for medical applications. The device is based on a gain-switched Ti: Sapphire laser with volume Bragg grating, pumped at 532 nm and operating at 931.8 nm, followed by a third harmonic generator and a fiber optic beam homogenizer. The maximum available pulse energy exceeded 5 mJ at 310.6 nm, with a pulse repetition rates of 50 Hz. The output characteristics satisfy the medical requirements for psoriasis and vitiligo treatment. A new optical scheme for third harmonic generation enhancement at moderate levels of input intensities is proposed and investigated. As a result, 40% harmonic efficiency was obtained, when input pulse power was only 300 kW.

  1. An extreme ultraviolet Michelson interferometer for experiments at free-electron lasers

    SciTech Connect

    Hilbert, Vinzenz; Fuchs, Silvio; Paulus, Gerhard G.; Zastrau, Ulf; Blinne, Alexander; Feigl, Torsten; Kämpfer, Tino; Rödel, Christian; Uschmann, Ingo; Wünsche, Martin; Förster, Eckhart

    2013-09-15

    We present a Michelson interferometer for 13.5 nm soft x-ray radiation. It is characterized in a proof-of-principle experiment using synchrotron radiation, where the temporal coherence is measured to be 13 fs. The curvature of the thin-film beam splitter membrane is derived from the observed fringe pattern. The applicability of this Michelson interferometer at intense free-electron lasers is investigated, particularly with respect to radiation damage. This study highlights the potential role of such Michelson interferometers in solid density plasma investigations using, for instance, extreme soft x-ray free-electron lasers. A setup using the Michelson interferometer for pseudo-Nomarski-interferometry is proposed.

  2. Cryogenic Yb:YAG picosecond laser with high average power visible and ultraviolet harmonic generation

    NASA Astrophysics Data System (ADS)

    Brown, D. C.; Kowalewski, K.; Envid, V.; Zembek, J.; Canale, B.; Kolis, J. W.; McMillen, C. D.; Geisber, H.

    2012-06-01

    Cryogenic Yb:YAG lasers operating at 1029 nm have been demonstrated at Snake Creek Lasers with high average power CW and ultrafast output powers, and provide near diffraction-limited output beams that are ideal for applications in harmonic generation. We describe experiments that have produced high average power green output power at 515 nm as well as preliminary experiments producing UV output power at 257.25 nm. Frequency doubling experiments used a 20 mm long non-critically phase-matched LBO crystal mounted in a constant temperature oven. A mode-locked Yb fiber laser operating at 50 MHz was used to drive a two Yb:YAG cryogenic amplifier system, producing hundreds of watts of average power output with a FWHM pulsewidth of 12 ps. Doubling efficiencies of > 50 % have been observed. For frequency quadrupling, we have used hydrothermally grown KTTP crystals grown at Clemson University and Advanced Photonic Crystals. KBBF offers unprecedented UV transmission down to 155 nm, and was used in a Type I phasematching configuration. The properties of KBBF will be discussed, as well as the experimental results observed and conversion efficiency.

  3. Photoionization in the Precursor of Laser Supported Detonation by Ultraviolet Radiation

    SciTech Connect

    Shimamura, Kohei; Michigami, Keisuke; Wang, Bin; Komurasaki, Kimiya; Arakawa, Yoshihiro

    2011-11-10

    The propagation mechanism of laser-supported detonation (LSD) is important for designing laser propulsion for a detonation type thruster. The purpose of this work to was to confirm that photo-ionization in precursor is the predominant LSD sustainment mechanism. First of all, we tried to investigate the dependency of LSD duration on ambient gas species, air and argon. We took a series of high-speed images using the laser shadow-graphy. Besides, to estimate the UV photons emitted from the plasma, we used plasma emission spectroscopy and determined the electron temperature and density. As a result, the LSD duration of argon plasma and air plasma are 0.7 {mu}s and 0.3 {mu}s, resp. Besides, argon plasma emitted 10{sup 10} to 10{sup 14} photons/seconds, which was higher than air plasma. These results reveal that LSD propagation depends on the photon-contributing photoionization. The threshold photon-emission rate of LSD termination gives the elucidation of the LSD termination condition.

  4. Interaction of extreme ultraviolet laser radiation with solid surface: ablation, desorption, nanostructuring

    NASA Astrophysics Data System (ADS)

    Kolacek, Karel; Schmidt, Jiri; Straus, Jaroslav; Frolov, Oleksandr; Juha, Libor; Chalupsky, Jaromir

    2015-02-01

    The area, where interaction of focused XUV laser radiation with solid surface takes place, can be divided according to local fluency into desorption region (if fluency is larger than zero and smaller than ablation threshold) and ablation region (if fluency is equal or larger than this threshold). It turned out that a direct nanostructuring (e.g. imprinting diffraction pattern created on edges of windows of proximity standing grid) is possible in the desorption region only. While for femtosecond pulses the particle (atom/molecule) removal-efficiency η in the desorption region is very small (η < 10%), and hence, it can be easily distinguished from the ablation region with η ~ 100%, for nanosecond pulses in desorption region this η rises at easily ablated materials from 0% at the periphery up to ~90% at the ablation contour and, therefore, the boundary between these two regions can be found with the help of nanostructuring only. This rise of removal efficiency could be explained by gradually increased penetration depth (due to gradually removed material) during laser pulse. This is a warning against blind using crater shape for fluency mapping in the case of long laser pulses. On the other hand it is a motivation to study an ablation plum (or ablation jet) and to create a knowledge bank to be used at future numerical modeling of this process.

  5. Time resolved metal line profile by near-ultraviolet tunable diode laser absorption spectroscopy

    NASA Astrophysics Data System (ADS)

    Vitelaru, C.; de Poucques, L.; Minea, T. M.; Popa, G.

    2011-03-01

    Pulsed systems are extensively used to produce active species such as atoms, radicals, excited states, etc. The tunable diode laser absorption spectroscopy (TD-LAS) is successfully used to quantify the density of absorbing species, but especially for stationary or slow changing systems. The time resolved-direct absorption profile (TR-DAP) measurement method by TD-LAS, with time resolution of μs is proposed here as an extension of the regular use of diode laser absorption spectroscopy. The spectral narrowness of laser diodes, especially in the blue range (˜0.01 pm), combined with the nanosecond fast trigger of the magnetron pulsed plasma and long trace recording on the oscilloscope (period of second scale) permit the detection of the sputtered titanium metal evolution in the afterglow (˜ms). TR-DAP method can follow the time-dependence of the temperature (Doppler profile) and the density (deduced from the absorbance) of any medium and heavy species in a pulsed system.

  6. III-Nitride-on-silicon microdisk lasers from the blue to the deep ultra-violet

    NASA Astrophysics Data System (ADS)

    Sellés, J.; Crepel, V.; Roland, I.; El Kurdi, M.; Checoury, X.; Boucaud, P.; Mexis, M.; Leroux, M.; Damilano, B.; Rennesson, S.; Semond, F.; Gayral, B.; Brimont, C.; Guillet, T.

    2016-12-01

    We present a series of microdisk lasers realized within the same GaN-on-Si photonic platform scheme, and operating at room temperature under pulsed optical pumping over a broad spectral range extending over λ = 275 nm-470 nm. The III-nitride microdisks embed either binary GaN/AlN multiple quantum wells (MQWs) for UV operation, or ternary InGaN/GaN MQWs for violet and blue operation. This demonstrates the versatility of this nitride-on-silicon platform, and the realization on this platform of efficient active layers for lasing action over a 200 nm broad UV to visible spectral range. We probe the lasing threshold carrier density over the whole spectral range and found that it is similar whatever the emission wavelength for these Q > 1000 microdisk resonators with a constant material quality until quantum confined Stark effect takes over. The threshold is also found independent of microdisk diameters from 3 to 12 μm, with a β factor intermediate between the one of vertical cavity lasers and the one of small modal volume "thresholdless" lasers.

  7. L'ADROIT - A spaceborne ultraviolet laser system for space debris clearing

    NASA Astrophysics Data System (ADS)

    Phipps, Claude R.

    2014-11-01

    Small (1-10 cm) debris in low Earth orbit (LEO) are extremely dangerous, because they spread the breakup cascade. Pulsed laser active debris removal using laser ablation jets on target is the most cost-effective way to re-enter the small debris. No other solutions address the whole problem of large ( 100 cm, 1 t) as well as small debris. Physical removal of small debris (by nets, tethers and so on) is uneconomical because of the energy cost of matching orbits. In this paper, we present a completely new proposal relative to our earlier work. This new approach uses rapid, head-on interaction in 10-40 s rather than 4 minutes, using 20-40 kW bursts of 100 ps, 355 nm UV pulses from a 1.5 m diameter aperture on a space-based station in LEO. The station employs “heat-capacity” laser mode with low duty cycle to create an adaptable, robust, dual-mode system which can lower or raise large derelict objects into less dangerous orbits, as well as clear out the small debris in a 400-km thick LEO band. Time-average laser optical power is less than 15 kW. The combination of short pulses and UV wavelength gives lower required fluence on target as well as higher momentum coupling coefficient. An orbiting system can have short range because of high interaction rate deriving from its velocity through the debris field. This leads to much smaller mirrors and lower average power than the ground-based systems we have considered previously. Our system also permits strong defense of specific assets. Analysis gives an estimated cost less than 1 k each to re-enter most small debris in a few months, and about 280 k each to raise or lower 1-ton objects by 40 km. We believe it can do this for 2000 such large objects in about four years. Laser ablation is one of the few interactions in nature that propel a distant object without any significant reaction on the source.

  8. High-Power UV Lasers: Tunable Ultraviolet Burst-Mode Laser System Produces High-Energy Pulses

    DTIC Science & Technology

    2008-08-01

    typically Nd:YAG) that is “sliced” into a burst train using either a pair of electro- optic Pockels cells or an acousto - optic deflector . 1-5 In one exception...JOSEPH D . MILLER, TERRENCE R. MEYER, AND JAMES R. GORD While planar laser-induced-fluorescence (PLIF) imaging of aerodynamic and combustion flows...pumped optical - parametric-oscillator (OPO) systems operated in what has come to be known as “pulse-burst” mode. In combination with sum-frequency

  9. Improved characteristics of ultraviolet AlGaN multiple-quantum-well laser diodes with step-graded quantum barriers close to waveguide layers

    NASA Astrophysics Data System (ADS)

    Cai, Xuefen; Li, Shuping; Kang, Junyong

    2016-09-01

    Ultraviolet AlGaN multiple-quantum-well laser diodes (LDs) with step-graded quantum barriers (QBs) instead of conventional first and last QBs close to waveguide layers are proposed. The characteristics of this type of laser diodes are numerically investigated by using the software PICS3D and it is found that the performances of these LDs are greatly improved. The results indicates that the structure with step-graded QBs exhibits higher output light power, slope efficiency and emission intensity, as well as lower series resistance and threshold current density under the identical condition, compared with conventional LD structure.

  10. Self-organized micro-holes on titania based sol-gel films under continuous direct writing with a continuous wave ultraviolet laser

    SciTech Connect

    Bakhti, S.; Destouches, N.; Gamet, E.; Reynaud, S.; Balan, L.

    2013-05-27

    The microstructuring of titania based sol-gel films is investigated by direct writing with a continuous wave ultraviolet laser beam emitting at 244 nm. Depending on the exposure conditions, the films exhibit a volume expansion, a volume shrinkage, a self-shaped delamination, or are damaged. This paper is mainly focused on the regime where spontaneous local delamination occurs, which corresponds to a narrow range of laser irradiances and writing speeds. In this regime, self-organized round-shape micro-holes opened on the substrate are generated.

  11. Compact Solid-State 213 nm Laser Enables Standoff Deep Ultraviolet Raman Spectrometer: Measurements of Nitrate Photochemistry.

    PubMed

    Bykov, Sergei V; Mao, Michael; Gares, Katie L; Asher, Sanford A

    2015-08-01

    We describe a new compact acousto-optically Q-switched diode-pumped solid-state (DPSS) intracavity frequency-tripled neodymium-doped yttrium vanadate laser capable of producing ~100 mW of 213 nm power quasi-continuous wave as 15 ns pulses at a 30 kHz repetition rate. We use this new laser in a prototype of a deep ultraviolet (UV) Raman standoff spectrometer. We use a novel high-throughput, high-resolution Echelle Raman spectrograph. We measure the deep UV resonance Raman (UVRR) spectra of solid and solution sodium nitrate (NaNO3) and ammonium nitrate (NH4NO3) at a standoff distance of ~2.2 m. For this 2.2 m standoff distance and a 1 min spectral accumulation time, where we only monitor the symmetric stretching band, we find a solid state NaNO3 detection limit of ~100 μg/cm(2). We easily detect ~20 μM nitrate water solutions in 1 cm path length cells. As expected, the aqueous solutions UVRR spectra of NaNO3 and NH4NO3 are similar, showing selective resonance enhancement of the nitrate (NO3(-)) vibrations. The aqueous solution photochemistry is also similar, showing facile conversion of NO3(-) to nitrite (NO2(-)). In contrast, the observed UVRR spectra of NaNO3 and NH4NO3 powders significantly differ, because their solid-state photochemistries differ. Whereas solid NaNO3 photoconverts with a very low quantum yield to NaNO2, the NH4NO3 degrades with an apparent quantum yield of ~0.2 to gaseous species.

  12. A vacuum-ultraviolet laser pulsed field ionization-photoelectron study of sulfur monoxide (SO) and its cation (SO+).

    PubMed

    Lam, Chow-Shing; Wang, Hailing; Xu, Yuntao; Lau, Kai-Chung; Ng, C Y

    2011-04-14

    Vacuum ultraviolet (VUV) laser pulsed field ionization-photoelectron (PFI-PE) spectroscopy has been applied to the study of the sulfur monoxide radical (SO) prepared by using a supersonically cooled radical beam source based on the 193 nm excimer laser photodissociation of SO(2). The vibronic VUV-PFI-PE bands for the photoionization transitions SO(+)(X(2)Π(1∕2); v(+) = 0) ← SO(X(3)Σ(-); v = 0); and SO(+)((2)Π(3∕2); v(+) = 0) ← SO(X(3)Σ(-); v = 0) have been recorded. On the basis of the semiempirical simulation of rotational branch contours observed in these PFI-PE bands, we have obtained highly precise ionization energies (IEs) of 83,034.2 ± 1.7 cm(-1) (10.2949 ± 0.0002 eV) and 83,400.4 ± 1.7 cm(-1) (10.3403 ± 0.0002 eV) for the formation of SO(+)(X(2)Π(1∕2); v(+) = 0) and SO(+)((2)Π(3∕2); v(+) = 0), respectively. The present VUV-PFI-PE measurement has enabled the direct determination of the spin-orbit coupling constant (A(0)) for SO(+)(X(2)Π(1∕2,3∕2)) to be 365.36 ± 0.12 cm(-1). We have also performed high-level ab initio quantum chemical calculations at the coupled-cluster level up to full quadruple excitations and complete basis set (CBS) extrapolation. The zero-point vibrational energy correction, the core-valence electronic correction, the spin-orbit coupling, and the high-level correction are included in the calculation. The IE[SO(+)(X(2)Π(1∕2,3∕2))] and A(0) predictions thus obtained are found to be in remarkable agreement with the experimental determinations.

  13. Communication: A vibrational study of titanium dioxide cation using the vacuum ultraviolet laser pulsed field ionization-photoelectron method.

    PubMed

    Chang, Yih-Chung; Huang, Huang; Luo, Zhihong; Ng, C Y

    2013-01-28

    We have successfully measured the vacuum ultraviolet (VUV) laser photoionization efficiency and pulsed field ionization-photoelectron (PFI-PE) spectra of cold titanium dioxide (TiO(2)) prepared by a supersonically cooled laser ablation source. The VUV-PFI-PE spectrum thus obtained exhibits long progressions of the v(2)(+)(a(1)) bending and the combination of v(1)(+)(a(1)) stretching and v(2)(+)(a(1)) bending vibrational modes of the TiO(2)(+)(X(2)B(2)) ion. The pattern of Franck-Condon factors observed indicates that the O-Ti-O bond angle of the TiO(2)(+)(X(2)B(2)) ion is significantly different from that of the TiO(2)(X(1)A(1)) neutral, whereas the change of the Ti-O bond distance is very minor upon the photoionization transition. The analysis of the PFI-PE bands has made possible the determination of the adiabatic ionization energy for TiO(2), IE(TiO(2)) = 77215.9 ± 1.2 cm(-1) (9.57355 ± 0.00015 eV), the harmonic vibrational frequencies, ω(1)(+) = 829.1 ± 2.0 cm(-1) and ω(2)(+) = 248.7 ± 0.6 cm(-1), and the anharmonic coefficients, χ(11)(+) = 5.57 ± 0.65 cm(-1), χ(22)(+) = 0.08 ± 0.06 cm(-1), and χ(12)(+) = -4.51 ± 0.30 cm(-1) for the TiO(2)(+)(X(2)B(2)) ground state.

  14. Ultraviolet Raman Spectral Signatures in Support of Lisa (Laser Interrogation of Surface Agents)

    DTIC Science & Technology

    2003-07-01

    is a schematic diagram of the experimental apparatus used to measure Raman cross sections. A Spectra- Physics MOPO -730 system generates continuously...tunable radiation from 410 nm to 2000 nm. The MOPO -730 is a BBO-based optical parametric oscillator (OPO) pumped by the third harmonic ~355 nm of a...30 Hz Nd:YAG laser. The UV light (210–400 nm) is obtained by doubling either the signal or the idler beam from the MOPO . The pulse width of the UV

  15. Pollution Encrustation Removal by Means of Combined Ultraviolet and Infrared Laser Radiation: The Application of this Innovative Methodology on the Surface of the Parthenon West Frieze

    NASA Astrophysics Data System (ADS)

    Pouli, P.; Frantzikinaki, K.; Papakonstantinou, E.; Zafiropulos, V.; Fotakis, C.

    This study refers to the innovative laser cleaning methodology developed at FORTH IESL on the combination of ultraviolet and infrared laser radiation emitted from a Q-switched Nd:YAG laser for the successful removal of pollution encrustation from marble substrates. The above-mentioned methodology is presented as regards its successful application on the fragile and demanding surface of the Parthenon West Frieze in collaboration with the Committee for the Preservation of the Acropolis Monuments. The aim of this intervention was to remove encrustation, accumulated on the stone due to the atmospheric pollution, without any discoloration or structural alteration to the original surface. The preliminary experiments on all the possible substrates and encrustations present on the surface of the Acropolis monuments and the laser cleaning parameters are presented in detail.

  16. Double-pulse laser induced breakdown spectroscopy with ambient gas in the vacuum ultraviolet: Optimization of parameters for detection of carbon and sulfur in steel

    NASA Astrophysics Data System (ADS)

    Jiang, X.; Hayden, P.; Costello, J. T.; Kennedy, E. T.

    2014-11-01

    Laser induced breakdown spectroscopy (LIBS) in the vacuum ultraviolet (VUV) has been applied to calibrated steel samples for the low concentration level detection of the light elements, carbon and sulfur in steel. Experimental optimization parameters, aimed at enhancing the sensitivity of the technique, included short wavelength spectral detection, double-pulse (DP) operation, variable focusing conditions and different ambient environments in terms of gas type and pressure. Two lasers were employed respectively as an ablation laser (Spectron: 1.06 μm/200 mJ/15 ns) and a reheating laser (Surelite: 1.06 μm/665 mJ/6 ns) in a collinear geometry. The results include insight into the most salient experimental variables and limits of detection in the parts per million range.

  17. Development of a vacuum ultraviolet laser-based angle-resolved photoemission system with a superhigh energy resolution better than 1 meV.

    PubMed

    Liu, Guodong; Wang, Guiling; Zhu, Yong; Zhang, Hongbo; Zhang, Guochun; Wang, Xiaoyang; Zhou, Yong; Zhang, Wentao; Liu, Haiyun; Zhao, Lin; Meng, Jianqiao; Dong, Xiaoli; Chen, Chuangtian; Xu, Zuyan; Zhou, X J

    2008-02-01

    The design and performance of the first vacuum ultraviolet (VUV) laser-based angle-resolved photoemission (ARPES) system are described. The VUV laser with a photon energy of 6.994 eV and bandwidth of 0.26 meV is achieved from the second harmonic generation using a novel nonlinear optical crystal KBe2BO3F2. The new VUV laser-based ARPES system exhibits superior performance, including superhigh energy resolution better than 1 meV, high momentum resolution, superhigh photon flux, and much enhanced bulk sensitivity, which are demonstrated from measurements on a typical Bi2Sr2CaCu2O8 high temperature superconductor. Issues and further development related to the VUV laser-based photoemission technique are discussed.

  18. Extreme ultraviolet and soft X-ray imaging with compact, table top laser plasma EUV and SXR sources

    NASA Astrophysics Data System (ADS)

    Wachulak, P. W.; Bartnik, A.; Kostecki, J.; Wegrzynski, L.; Fok, T.; Jarocki, R.; Szczurek, M.; Fiedorowicz, H.

    2015-12-01

    We present a few examples of imaging experiments, which were possible using a compact laser-plasma extreme ultraviolet (EUV) and soft X-ray (SXR) source, based on a double stream gas puff target. This debris-free source was used in full-field EUV imaging to obtain magnified images of test samples, ZnO nanofibers and images of the membranes coated with salt crystals. The source was also employed for SXR microscopy in the "water-window" spectral range using grazing incidence Wolter type-I objective to image test samples and to perform the initial studies of biological objects. Gas puff target EUV source, spectrally tuned for 13.5 nm wavelength with multilayer mirror and thin film filters, was also used in variety of shadowgraphy experiments to study the density of newly developed modulated density gas puff targets. Finally, the source was also employed in EUV tomography experiments of low density objects with the goal to measure and optimize the density of the targets dedicated to high harmonic generation.

  19. Yb-fiber-laser-based, 1.8 W average power, picosecond ultraviolet source at 266 nm.

    PubMed

    Chaitanya Kumar, S; Canals Casals, J; Sanchez Bautista, E; Devi, K; Ebrahim-Zadeh, M

    2015-05-15

    We report a compact, stable, high-power, picosecond ultraviolet (UV) source at 266 nm based on simple single-pass two-step fourth-harmonic generation (FHG) of a mode-locked Yb-fiber laser at 79.5 MHz in LiB3O5 (LBO) and β-BaB2O4. Using a 30-mm-long LBO crystal for single-pass second-harmonic generation, we achieve up to 9.1 W of average green power at 532 nm for 16.8 W of Yb-fiber power at a conversion efficiency of 54% in 16.2 ps pulses with a TEM00 spatial profile and passive power stability better than 0.5% rms over 16 h. The generated green radiation is then used for single-pass FHG into the UV, providing as much as 1.8 W of average power at 266 nm under the optimum focusing condition in the presence of spatial walk-off, at an overall FHG conversion efficiency of ∼11%. The generated UV output exhibits passive power stability better than 4.6% rms over 1.5 h and beam pointing stability better than 84 μrad over 1 h. The UV output beam has a circularity of >80% in high beam quality with the TEM00 mode profile. To the best of our knowledge, this is the first report of picosecond UV generation at 266 nm at megahertz repetition rates.

  20. Yb-fiber-laser-pumped, high-repetition-rate picosecond optical parametric oscillator tunable in the ultraviolet.

    PubMed

    Samanta, G K; Kumar, S Chaitanya; Aadhi, A; Ebrahim-Zadeh, M

    2014-05-19

    We report a compact tunable 240-MHz picosecond source for the ultraviolet based on intra-cavity frequency doubling of a signal-resonant MgO:sPPLT optical parametric oscillator (OPO), synchronously pumped at 532 nm in the green by the second harmonic of a mode-locked Yb-fiber laser at 80-MHz repetition rate. By deploying a 30-mm-long multi-grating MgO:sPPLT crystal for the OPO and a 5-mm-long BiB(3)O(6) crystal for internal doubling, we have generated tunable UV radiation across 317-340.5 nm, with up to 30 mW at 334.5 nm. The OPO also provides tunable visible signal in the red, across 634-681 nm, and mid-infrared idler radiation over 2429-3298 nm, with as maximum signal power of 800 mW at 642 nm. The signal pulses have a temporal duration of 12 ps at 665 nm and exhibit high spatial beam quality with Gaussian profile. The signal power is recorded to be naturally stable with a fluctuation of 1.4% rms over 14 hours, while UV power degradation has been observed and studied.

  1. Temperature-dependent evaluation of Nd:LiCAF optical properties as potential vacuum ultraviolet laser material

    NASA Astrophysics Data System (ADS)

    Minami, Yuki; Arita, Ren; Cadatal-Raduban, Marilou; Pham, Minh Hong; Empizo, Melvin John Fernandez; Luong, Mui Viet; Hori, Tatsuhiro; Takabatake, Masahiro; Fukuda, Kazuhito; Mori, Kazuyuki; Yamanoi, Kohei; Shimizu, Toshihiko; Sarukura, Nobuhiko; Fukuda, Kentaro; Kawaguchi, Noriaki; Yokota, Yuui; Yoshikawa, Akira

    2016-08-01

    We investigate the temperature-dependent optical properties of Nd3+-doped LiCaAlF6 (Nd:LiCAF) in the vacuum ultraviolet (VUV) region. The 172-nm absorption edge does not seem to experience any significant blue shift as temperature is decreased from room temperature down to 30 K. This is confirmed by excitation spectra for the same temperature range. Several energy levels in the excited state configuration are observed. Based on these energy levels, the dominant emission peak at 177 nm is assigned to the allowed dipole transition from the 4f25d configuration of Nd3+ and the 4I11/2 level of the 4f3 ground state configuration. The position of the dominant 177-nm emission peak appears to be fixed across the temperature range considered. Our results suggest that the spectral overlap between the excitation and emission spectra should not increase as temperature is raised, possibly making Nd:LiCAF a potential VUV laser gain medium operating at room temperature.

  2. Tunable ultraviolet and blue light generation from Nd:YAB random laser bolstered by second-order nonlinear processes

    PubMed Central

    Moura, André L.; Carreño, Sandra J. M.; Pincheira, Pablo I. R.; Fabris, Zanine V.; Maia, Lauro J. Q.; Gomes, Anderson S. L.; de Araújo, Cid B.

    2016-01-01

    Ultraviolet and blue light were obtained by nonlinear frequency conversion in a random laser (RL) based on Nd0.10Y0.90Al3(BO3)4 nanocrystalline powder. RL operation at 1062 nm, due to the 4F3/2 → 4I11/2 transition of neodymium ions (Nd3+), was achieved by exciting the Nd3+ with a tunable beam from 680 to 920 nm covering the ground state absorption transitions to the 4F9/2, (4F7/2,4S3/2), (4F5/2,2H9/2), and 4F3/2 states. Light from 340 to 460 nm was obtained via the second-harmonic generation of the excitation beam while tunable blue light, from 417 to 486 nm, was generated by self-sum-frequency mixing between the excitation beam and the RL emission. PMID:27250647

  3. Tunable ultraviolet and blue light generation from Nd:YAB random laser bolstered by second-order nonlinear processes

    NASA Astrophysics Data System (ADS)

    Moura, André L.; Carreño, Sandra J. M.; Pincheira, Pablo I. R.; Fabris, Zanine V.; Maia, Lauro J. Q.; Gomes, Anderson S. L.; de Araújo, Cid B.

    2016-06-01

    Ultraviolet and blue light were obtained by nonlinear frequency conversion in a random laser (RL) based on Nd0.10Y0.90Al3(BO3)4 nanocrystalline powder. RL operation at 1062 nm, due to the 4F3/2 → 4I11/2 transition of neodymium ions (Nd3+), was achieved by exciting the Nd3+ with a tunable beam from 680 to 920 nm covering the ground state absorption transitions to the 4F9/2, (4F7/2,4S3/2), (4F5/2,2H9/2), and 4F3/2 states. Light from 340 to 460 nm was obtained via the second-harmonic generation of the excitation beam while tunable blue light, from 417 to 486 nm, was generated by self-sum-frequency mixing between the excitation beam and the RL emission.

  4. Photoluminescence performance enhancement of ZnO/MgO heterostructured nanowires and their applications in ultraviolet laser diodes.

    PubMed

    Shi, Zhi-Feng; Zhang, Yuan-Tao; Cui, Xi-Jun; Zhuang, Shi-Wei; Wu, Bin; Chu, Xian-Wei; Dong, Xin; Zhang, Bao-Lin; Du, Guo-Tong

    2015-06-07

    Vertically aligned ZnO/MgO coaxial nanowire (NW) arrays were prepared on sapphire substrates by metal-organic chemical vapor deposition combined with a sputtering system. We present a comparative investigation of the morphological and optical properties of the produced heterostructures with different MgO layer thicknesses. Photoluminescence measurements showed that the optical performances of ZnO/MgO coaxial NWs were strongly dependent on the MgO layer thickness. The intensity of deep-level emission (DLE) decreased monotonously with the increase of MgO thickness, while the enhancement of ultraviolet (UV) emission showed a critical thickness of 15 nm, achieving a maximum intensity ratio (∼226) of IUV/IDLE at the same time. The significantly improved exciton emission efficiency of the coaxial NW structures allows us to study the surface passivation effect, photogenerated carrier confinement and transfer in terms of energy band theory. More importantly, we achieved an ultralow threshold (4.5 mA, 0.58 A cm(-2)) electrically driven UV lasing action based on the ZnO/MgO NW structures by constructing an Au/MgO/ZnO metal/insulator/semiconductor diode, and the continuous-current-driven diode shows a good temperature tolerance. The results obtained on the unique optical properties of ZnO/MgO coaxial NWs shed light on the design and development of ZnO-based UV laser diodes assembled with nanoscale building blocks.

  5. Inspection of transparent polymers by photothermal detection of ultraviolet-laser generated thermal waves

    NASA Astrophysics Data System (ADS)

    Eickmeier, Achim; Bahners, Thomas; Schollmeyer, Eckhard

    1991-11-01

    The concept of photothermal wave imaging has been adapted to the nondestructive inspection of transparent polymeric samples by specific generation of thermal waves. Utilization of light sources according to the absorption properties of the material secured pure surface heating which is necessary for sensible measurements. Thickness profiles of thin films made of poly(ethylene terephthalate), which are transparent in the visible spectrum, could be measured using a pulsed KrF laser. Examples for the nondestructive inspection of complex textile samples such as coated fabrics are presented.The photothermal analysis (PTA) of optically generated thermal waves is a powerful tool for nondestructive, contactless inspection and evaluation of intrinsic properties of a sample.1,2 The method has been used for the observation of dynamic processes in adhesives, for the inspection of coatings on metal and of carbon fiber composites. A modulated light source, e.g., a chopped HeNe- or Ar+ laser, is used for local, modulated heating at the sample's surface resulting in a time- and space-dependent temperature modulation which propagates through the material. In the case of a homogeneous layer heated only in a small volume at the surface the solution of the heat diffusion equation gives a heavily damped thermal wave T(x,y,z;t). In a one-dimensional model3 only the direction z perpendicular to the surface is considered and we obtain

  6. Ultraviolet Thomson Scattering from Two-Plasmon-Decay Electron Plasma Waves Driven by Multiple Laser Beams

    NASA Astrophysics Data System (ADS)

    Follett, R. K.; Henchen, R. J.; Hu, S. X.; Katz, J.; Michel, D. T.; Myatt, J. F.; Wen, H.; Froula, D. H.

    2014-10-01

    Thomson scattering is used to probe electron plasma waves (EPW's) driven by the common-wave two-plasmon-decay (TPD) instability near the quarter-critical density. Between two and five laser beams (λ3 ω = 351 nm) illuminated planar CH targets with 300- μm-diam (FWHM) laser spots with overlapped intensities ~1015 W/cm2. A 263-nm Thomson-scattering beam was used to probe densities ranging from 0.2 to 0.25 nc while k matching the TPD common wave. The Thomson-scattering spectra show two spectral peaks consistent with scattering from forward-scattered TPD common-wave EPW's and Langmuir decay of backscattered TPD waves. Broad TPD driven spectral features were observed in an alternate scattering configuration probing EPW k vectors that do not lie along a TPD maximum-growth hyperbola, consistent with TPD k-space saturation. Experimental results are compared to ZAK3D simulations. This material is based upon work supported by the Department of Energy National Nuclear Security Administration under Award Number DE-NA0001944.

  7. Tunable ultraviolet laser-induced fluorescence detection of trace plastics and dissolved organic compounds in water.

    PubMed

    Sivaprakasam, Vasanthi; Killinger, Dennis K

    2003-11-20

    We developed a tunable (220-285-nm) UV and fixed 266-nm laser-induced fluorescence (LIF) system using a spectrometer and a cooled CCD imaging detector to measure the excitation-emission matrix spectra of various compounds in water, including quinine sulfate and plastic compound bisphenol-A. The LIF instrument was used for the fast, nonspecific determination of trace amounts of dissolved organic compounds present in natural water supplies and various brand name bottled distilled water and bottled drinking water. Plastic-related compounds that leached out of plastic utensils and containers were also detected with this instrument. The sensitivity of the system was approximately 1-2 orders of magnitude better than that for a commercial system.

  8. Tunable ultraviolet laser-induced fluorescence detection of trace plastics and dissolved organic compounds in water

    NASA Astrophysics Data System (ADS)

    Sivaprakasam, Vasanthi; Killinger, Dennis K.

    2003-11-01

    We developed a tunable (220-285-nm) UV and fixed 266-nm laser-induced fluorescence (LIF) system using a spectrometer and a cooled CCD imaging detector to measure the excitation-emission matrix spectra of various compounds in water, including quinine sulfate and plastic compound bisphenol-A. The LIF instrument was used for the fast, nonspecific determination of trace amounts of dissolved organic compounds present in natural water supplies and various brand name bottled distilled water and bottled drinking water. Plastic-related compounds that leached out of plastic utensils and containers were also detected with this instrument. The sensitivity of the system was approximately 1-2 orders of magnitude better than that for a commercial system.

  9. A method of atmospheric density measurements during space shuttle entry using ultraviolet-laser Rayleigh scattering

    NASA Technical Reports Server (NTRS)

    Mckenzie, Robert L.

    1988-01-01

    An analytical study and its experimental verification are described which show the performance capabilities and the hardware requirements of a method for measuring atmospheric density along the Space Shuttle flightpath during entry. Using onboard instrumentation, the technique relies on Rayleigh scattering of light from a pulsed ArF excimer laser operating at a wavelength of 193 nm. The method is shown to be capable of providing density measurements with an uncertainty of less than 1 percent and with a spatial resolution along the flightpath of 1 km, over an altitude range from 50 to 90 km. Experimental verification of the signal linearity and the expected signal-to-noise ratios is demonstrated in a simulation facility at conditions that duplicate the signal levels of the flight environment.

  10. Capillary discharge extreme ultraviolet lasers. Progress report, December 15, 1991--December 14, 1992

    SciTech Connect

    Rocca, J.J.

    1992-08-01

    The project objective is to explore the generation of soft X-ray laser radiation in a plasma column created by a fast capillary discharge. The proposed capillary lasing scheme offers the potential for compact, simple and efficient soft X-ray laser sources. For this purpose a compact, fast pulse generator which produces 100 kA current pulses with a risetime of 11 ns was constructed. Initial experiments were conducted in evacuated capillaries, in which the plasma is produced by ablation of the capillary walls. The soft X-ray emission from discharges in polyethylene capillary channels was studied to investigate the possibility of amplification in the 3-2 transition of C VI, at {lambda} = 18.2 nm. Time-resolved spectra in which this transition appears anomalously intense with respect to the 4--2 transition of the same ion were obtained. To date, however, this phenomenoa could not be confirmed as gain, as the intensity of the 18.2 nm line has not been observed to increase exponentially as a function of the capillary length. Encouraging results were obtained by fast pulse discharge excitation of capillaries filled with preionized gas. High temperature (Te > 150 eV), small diameter ({approximately}200 {mu}m) plasma columns were efficiently generated. Fast current pulse excitation of a selected low mass density of uniformly preionized material Mag the capillary was observed to detach rapidly the plasma from the capillary walls, and form a plasma channel of a diameter much smaller and significantly hotter than those produced by a similar current pulse in evacuated capillaries of the same size. Discharges in argon-filled capillaries at currents between 20 and 60 kA produced plasmas with ArX-Ar{sub XIV} line emission, and with spectra that are similar to those of plasmas generated by > I MA current implosions in large pulsed power machines. The characteristic of these plasmas approach those necessary for soft X-ray amplification in low Z elements.

  11. Photoelectrolysis of water at high current density - Use of ultraviolet laser excitation

    NASA Technical Reports Server (NTRS)

    Bocarsly, A. B.; Bolts, J. M.; Cummins, P. G.; Wrighton, M. S.

    1977-01-01

    The behavior of TiO2 and SrTiO3 photoanodes in cells for the photoelectrolysis of H2O has been investigated for high-intensity 351-,364-nm excitation from an Ar ion laser. Intensities up to 380 W/sq cm have been used. For TiO2 a small amount of surface decomposition is found after irradiation at high intensity, whereas SrTiO3 undergoes no detectable changes. Current-voltage properties for both electrodes are essentially independent of light intensity up to the level of 380 W/sq cm, and there is little if any change in quantum efficiency for electron flow. Photocurrent densities have been shown to exceed 5 A/sq cm for O2 evolution. Data show that the energy storage rate associated with the SrTiO3 photoelectrolysis can exceed 30 W/sq cm; this represents the highest demonstrated rate of sustained optical-to-chemical energy conversion.

  12. Laser desorption time-of-flight mass spectrometry of ultraviolet photo-processed ices

    SciTech Connect

    Paardekooper, D. M. Bossa, J.-B.; Isokoski, K.; Linnartz, H.

    2014-10-01

    A new ultra-high vacuum experiment is described that allows studying photo-induced chemical processes in interstellar ice analogues. MATRI²CES - a Mass Analytical Tool to study Reactions in Interstellar ICES applies a new concept by combining laser desorption and time-of-flight mass spectrometry with the ultimate goal to characterize in situ and in real time the solid state evolution of organic compounds upon UV photolysis for astronomically relevant ice mixtures and temperatures. The performance of the experimental setup is demonstrated by the kinetic analysis of the different photoproducts of pure methane (CH₄) ice at 20 K. A quantitative approach provides formation yields of several new species with up to four carbon atoms. Convincing evidence is found for the formation of even larger species. Typical mass resolutions obtained range from M/ΔM ~320 to ~400 for CH₄ and argon, respectively. Additional tests show that the typical detection limit (in monolayers) is ⩽0.02 ML, substantially more sensitive than the regular techniques used to investigate chemical processes in interstellar ices.

  13. Extreme ultraviolet resonant inelastic X-ray scattering (RIXS) at a seeded free-electron laser

    PubMed Central

    Dell’Angela, M.; Hieke, F.; Malvestuto, M.; Sturari, L.; Bajt, S.; Kozhevnikov, I. V.; Ratanapreechachai, J.; Caretta, A.; Casarin, B.; Glerean, F.; Kalashnikova, A. M.; Pisarev, R. V.; Chuang, Y.-D.; Manzoni, G.; Cilento, F.; Mincigrucci, R.; Simoncig, A.; Principi, E.; Masciovecchio, C.; Raimondi, L.; Mahne, N.; Svetina, C.; Zangrando, M.; Passuello, R.; Gaio, G.; Prica, M.; Scarcia, M.; Kourousias, G.; Borghes, R.; Giannessi, L.; Wurth, W.; Parmigiani, F.

    2016-01-01

    In the past few years, we have been witnessing an increased interest for studying materials properties under non-equilibrium conditions. Several well established spectroscopies for experiments in the energy domain have been successfully adapted to the time domain with sub-picosecond time resolution. Here we show the realization of high resolution resonant inelastic X-ray scattering (RIXS) with a stable ultrashort X-ray source such as an externally seeded free electron laser (FEL). We have designed and constructed a RIXS experimental endstation that allowed us to successfully measure the d-d excitations in KCoF3 single crystals at the cobalt M2,3-edge at FERMI FEL (Elettra-Sincrotrone Trieste, Italy). The FEL-RIXS spectra show an excellent agreement with the ones obtained from the same samples at the MERIXS endstation of the MERLIN beamline at the Advanced Light Source storage ring (Berkeley, USA). We established experimental protocols for performing time resolved RIXS experiments at a FEL source to avoid X ray-induced sample damage, while retaining comparable acquisition time to the synchrotron based measurements. Finally, we measured and modelled the influence of the FEL mixed electromagnetic modes, also present in externally seeded FELs, and the beam transport with ~120 meV experimental resolution achieved in the presented RIXS setup. PMID:27941842

  14. Extreme ultraviolet resonant inelastic X-ray scattering (RIXS) at a seeded free-electron laser

    NASA Astrophysics Data System (ADS)

    Dell’Angela, M.; Hieke, F.; Malvestuto, M.; Sturari, L.; Bajt, S.; Kozhevnikov, I. V.; Ratanapreechachai, J.; Caretta, A.; Casarin, B.; Glerean, F.; Kalashnikova, A. M.; Pisarev, R. V.; Chuang, Y.-D.; Manzoni, G.; Cilento, F.; Mincigrucci, R.; Simoncig, A.; Principi, E.; Masciovecchio, C.; Raimondi, L.; Mahne, N.; Svetina, C.; Zangrando, M.; Passuello, R.; Gaio, G.; Prica, M.; Scarcia, M.; Kourousias, G.; Borghes, R.; Giannessi, L.; Wurth, W.; Parmigiani, F.

    2016-12-01

    In the past few years, we have been witnessing an increased interest for studying materials properties under non-equilibrium conditions. Several well established spectroscopies for experiments in the energy domain have been successfully adapted to the time domain with sub-picosecond time resolution. Here we show the realization of high resolution resonant inelastic X-ray scattering (RIXS) with a stable ultrashort X-ray source such as an externally seeded free electron laser (FEL). We have designed and constructed a RIXS experimental endstation that allowed us to successfully measure the d-d excitations in KCoF3 single crystals at the cobalt M2,3-edge at FERMI FEL (Elettra-Sincrotrone Trieste, Italy). The FEL-RIXS spectra show an excellent agreement with the ones obtained from the same samples at the MERIXS endstation of the MERLIN beamline at the Advanced Light Source storage ring (Berkeley, USA). We established experimental protocols for performing time resolved RIXS experiments at a FEL source to avoid X ray-induced sample damage, while retaining comparable acquisition time to the synchrotron based measurements. Finally, we measured and modelled the influence of the FEL mixed electromagnetic modes, also present in externally seeded FELs, and the beam transport with ~120 meV experimental resolution achieved in the presented RIXS setup.

  15. A cross sectional study on the crystallization of amorphous Ge2Sb2Te5 films induced by a single-pulse ultraviolet laser

    NASA Astrophysics Data System (ADS)

    Zhu, Z.; Liu, F. R.; Yang, J. F.; Fan, Z. K.; Liu, F.; Sun, N. X.

    2016-07-01

    In this paper, the crystallization along the film thickness of amorphous Ge2Sb2Te5 (a-GST) films induced by a single-pulse ultraviolet laser was investigated by using transmission electron microscopy (TEM) integrated with SAED. TEM observations showed that the crystalline GST (c-GST) was composed of columnar grains at the top surface and equaixed grains inside the film. Moreover, the columnar grains became larger with the increase of laser fluence. A three-dimensional finite element method simulation was further used to elucidate the temperature field by a nanosecond excimer laser in the cross section of the a-GST film. A big temperature gradient obtained at the top surface in the cooling process caused the formation of columnar grains, while columnar grains were gradually substituted by small equaixed grains with the decrease of temperature gradient downwards the film interior.

  16. 167.75-nm vacuum-ultraviolet ps laser by eighth-harmonic generation of a 1342-nm Nd:YVO4 amplifier in KBBF.

    PubMed

    Dai, Shi-Bo; Zong, Nan; Yang, Feng; Zhang, Shen-Jin; Wang, Zhi-Min; Zhang, Feng-Feng; Tu, Wei; Shang, Lin-Qiao; Liu, Li-Juan; Wang, Xiao-Yang; Zhang, Jing-Yuan; Cui, Da-Fu; Peng, Qin-Jun; Li, Ru-Kang; Chen, Chuang-Tian; Xu, Zu-Yan

    2015-07-15

    We demonstrate a ps 167.75-nm vacuum-ultraviolet (VUV) laser by cascaded second-harmonic generation (SHG). The VUV laser is produced by eighth-harmonic generation (EHG) of a mode-locked ps 1342-nm Nd:YVO4 amplifier through three stages cascaded SHG with two LiB3O5 crystals and one KBe2BO3F2 crystal, successively. The 167.75-nm laser provides up to 65-μW output power, and the corresponding photon flux and photon flux density are 5.5×10(13)  s(-1) and 1.6×10(18)  s(-1)·cm(-2), respectively.

  17. Communication: A vibrational study of propargyl cation using the vacuum ultraviolet laser velocity-map imaging photoelectron method.

    PubMed

    Gao, Hong; Lu, Zhou; Yang, Lei; Zhou, Jingang; Ng, C Y

    2012-10-28

    By employing the vacuum ultraviolet (VUV) laser velocity-map imaging photoelectron (VUV-VMI-PE) method, we have obtained a vibrationally resolved photoelectron spectrum of gaseous propargyl radical [C(3)H(3)(X(2)B(1))] in the energy range of 0-4600 cm(-1) above its ionization energy. The cold C(3)H(3) radicals were produced from a supersonically cooled radical beam source based on 193 nm ArF photodissociation of C(3)H(3)Cl. The VUV-VMI-PE spectrum of C(3)H(3) thus obtained reveals a Franck-Condon factor (FCF) pattern with a highly dominant origin band along with weak vibrational progressions associated with excitations of the C-C ν(5)(+)(a(1)) and C≡C ν(3)(+)(a(1)) symmetric stretching modes and the CCH ν(7)(+)(b(1)) out-of-plane bending mode of C(3)H(3)(+)(X(1)A(1)). The ν(5)(+)(a(1)) vibrational frequency of 1120 cm(-1) determined in the present study is lower than the value deduced from the recent Ar-tagged infrared photodissociation study by 102 cm(-1), confirming the highly accurate vibrational frequency predictions obtained by the most recent state-of-the-art ab initio quantum calculations. The observation of the FCF disallowed ν(7)(+)(b(1)) mode is indicative of vibronic interactions. The discrepancy observed between the FCF pattern determined in the present study and that predicted by a recent high-level quantum theoretical investigation can be taken as evidence that the potential energy surfaces used in the latter theoretical study are in need of improvement in order to provide a reliable FCF prediction for the C(3)H(3)/C(3)H(3)(+) photoionization system.

  18. High-resolution Rydberg tagging time-of-flight measurements of atomic photofragments by single-photon vacuum ultraviolet laser excitation

    SciTech Connect

    Jones, Brant; Zhou Jingang; Yang Lei; Ng, C. Y.

    2008-12-15

    By coupling a comprehensive tunable vacuum ultraviolet (VUV) laser system to a velocity-mapped ion imaging apparatus, we show that high-resolution high-n Rydberg tagging time-of-flight (TOF) measurements of nascent atomic photofragments formed by laser photodissociation can be made using single-photon VUV laser photoexcitation. To illustrate this single-photon Rydberg tagging TOF method, we present here the results of the VUV laser high-n Rydberg tagging TOF measurements of O({sup 3}P{sub 2}) and S({sup 3}P{sub 2}) formed in the photodissociation of SO{sub 2} and CS{sub 2} at 193.3 and 202.3 nm, respectively. These results are compared to those obtained by employing the VUV laser photoionization time-sliced velocity-mapped ion imaging technique. The fact that the kinetic energy resolutions achieved in the VUV laser high-n Rydberg tagging TOF measurements of O and S atoms are found to be higher than those observed in the VUV laser photoionization, time-sliced velocity-mapped ion imaging studies show that the single-photon VUV laser high-n Rydberg tagging TOF method is useful and complementary to state-of-the-art time-sliced velocity-mapped ion imaging measurements of heavier atomic photofragments, such as O and S atoms. Furthermore, the general agreement observed between the VUV laser high-n Rydberg tagging TOF and velocity-mapped ion imaging experiments supports the conclusion that the lifetimes of the tagged Rydberg states of O and S atoms are sufficiently long to allow the reliable determination of state-resolved UV photodissociation cross sections of SO{sub 2} and CS{sub 2} by using the VUV laser high-n Rydberg tagging TOF method.

  19. High-resolution Rydberg tagging time-of-flight measurements of atomic photofragments by single-photon vacuum ultraviolet laser excitation.

    PubMed

    Jones, Brant; Zhou, Jingang; Yang, Lei; Ng, C Y

    2008-12-01

    By coupling a comprehensive tunable vacuum ultraviolet (VUV) laser system to a velocity-mapped ion imaging apparatus, we show that high-resolution high-n Rydberg tagging time-of-flight (TOF) measurements of nascent atomic photofragments formed by laser photodissociation can be made using single-photon VUV laser photoexcitation. To illustrate this single-photon Rydberg tagging TOF method, we present here the results of the VUV laser high-n Rydberg tagging TOF measurements of O((3)P(2)) and S((3)P(2)) formed in the photodissociation of SO(2) and CS(2) at 193.3 and 202.3 nm, respectively. These results are compared to those obtained by employing the VUV laser photoionization time-sliced velocity-mapped ion imaging technique. The fact that the kinetic energy resolutions achieved in the VUV laser high-n Rydberg tagging TOF measurements of O and S atoms are found to be higher than those observed in the VUV laser photoionization, time-sliced velocity-mapped ion imaging studies show that the single-photon VUV laser high-n Rydberg tagging TOF method is useful and complementary to state-of-the-art time-sliced velocity-mapped ion imaging measurements of heavier atomic photofragments, such as O and S atoms. Furthermore, the general agreement observed between the VUV laser high-n Rydberg tagging TOF and velocity-mapped ion imaging experiments supports the conclusion that the lifetimes of the tagged Rydberg states of O and S atoms are sufficiently long to allow the reliable determination of state-resolved UV photodissociation cross sections of SO(2) and CS(2) by using the VUV laser high-n Rydberg tagging TOF method.

  20. NEW ACTIVE MEDIA AND ELEMENTS OF LASER SYSTEMS: Selection of the discharge-tube material for a nitrogen longitudinal-discharge ultraviolet laser to ensure the maximum average radiation power

    NASA Astrophysics Data System (ADS)

    Il'yushko, V. G.; Kravchenko, Viktor F.

    1987-11-01

    A theoretical and experimental analysis was made of the influence of the material of the surface of a discharge tube on the frequency characteristics of a molecular nitrogen laser emitting ultraviolet radiation under conditions when the influence of the translational temperature of the gas could be ignored. The experimental dependences of the average output power on the repetition frequency of the excitation pulses yielded the rate constants of the deactivation of vibrationally excited molecules and the accommodation coefficients of different surfaces. It was found that the discharge tube materials ensuring the maximum average output power and the highest repetition frequency of the excitation pulses in the case of lasers utilizing ultraviolet transitions in nitrogen molecules are substances with the highest accommodation coefficients and thermal diffusivity. These requirements were satisfied best by copper, aluminum, and graphite. The advantages of these materials were utilized in segmented metal discharge tubes.

  1. Infrared laser desorption/vacuum ultraviolet photoionization mass spectrometry of petroleum saturates: a new experimental approach for the analysis of heavy oils.

    PubMed

    Guo, Wenyue; Bi, Yucheng; Guo, Huijun; Pan, Yang; Qi, Fei; Deng, Wenan; Shan, Honghong

    2008-12-01

    A novel method combining infrared (IR) laser desorption with tunable synchrotron vacuum ultraviolet (VUV) photoionization mass spectrometry (LD/VUV PIMS) is applied to characterize a number of petroleum saturates samples from Lungu atmospheric residue (LGAR) under different treatment procedures. The mass spectra of these saturates are well resolved with even masses as the dominant ions and are clearly sample-dependent. In order to assess the ability of IR LD/VUV PIMS to determine the average molecular weight of heavy oils, the dependence of the measured molecular weight distributions on the VUV ionization photon energies is also discussed.

  2. Two dimensional expansion effects on angular distribution of 13.5 nm in-band extreme ultraviolet emission from laser-produced Sn plasma

    SciTech Connect

    Sequoia, K. L.; Tao, Y.; Yuspeh, S.; Burdt, R.; Tillack, M. S.

    2008-06-02

    The angular distribution of extreme ultraviolet emission at 13.5 nm within 2% bandwidth was characterized for laser irradiated, planar, Sn targets at prototypic conditions for a lithography system. We have found that two dimensional plasma expansion plays a key role in the distribution of in-band 13.5 nm emission under these conditions. The angular distribution was found to have two peaks at 45 deg. and 15 deg. This complex angular distribution arises from the shape of both the emitting plasma and the surrounding absorbing plasma. This research reveals that the detailed angular distribution can be important to the deduction of conversion efficiency.

  3. Communication: A vibrational study of propargyl cation using the vacuum ultraviolet laser velocity-map imaging photoelectron method

    SciTech Connect

    Gao Hong; Lu Zhou; Yang Lei; Zhou Jingang; Ng, C. Y.

    2012-10-28

    By employing the vacuum ultraviolet (VUV) laser velocity-map imaging photoelectron (VUV-VMI-PE) method, we have obtained a vibrationally resolved photoelectron spectrum of gaseous propargyl radical [C{sub 3}H{sub 3}(X{sup 2}B{sub 1})] in the energy range of 0-4600 cm{sup -1} above its ionization energy. The cold C{sub 3}H{sub 3} radicals were produced from a supersonically cooled radical beam source based on 193 nm ArF photodissociation of C{sub 3}H{sub 3}Cl. The VUV-VMI-PE spectrum of C{sub 3}H{sub 3} thus obtained reveals a Franck-Condon factor (FCF) pattern with a highly dominant origin band along with weak vibrational progressions associated with excitations of the C-C {nu}{sub 5}{sup +}(a{sub 1}) and C{identical_to}C {nu}{sub 3}{sup +}(a{sub 1}) symmetric stretching modes and the CCH {nu}{sub 7}{sup +}(b{sub 1}) out-of-plane bending mode of C{sub 3}H{sub 3}{sup +}(X{sup 1}A{sub 1}). The {nu}{sub 5}{sup +}(a{sub 1}) vibrational frequency of 1120 cm{sup -1} determined in the present study is lower than the value deduced from the recent Ar-tagged infrared photodissociation study by 102 cm{sup -1}, confirming the highly accurate vibrational frequency predictions obtained by the most recent state-of-the-art ab initio quantum calculations. The observation of the FCF disallowed {nu}{sub 7}{sup +}(b{sub 1}) mode is indicative of vibronic interactions. The discrepancy observed between the FCF pattern determined in the present study and that predicted by a recent high-level quantum theoretical investigation can be taken as evidence that the potential energy surfaces used in the latter theoretical study are in need of improvement in order to provide a reliable FCF prediction for the C{sub 3}H{sub 3}/C{sub 3}H{sub 3}{sup +} photoionization system.

  4. Controlled p-type to n-type conductivity transformation in NiO thin films by ultraviolet-laser irradiation

    SciTech Connect

    Gupta, Pranav; Dutta, Titas; Mal, Siddhartha; Narayan, Jagdish

    2012-01-01

    We report the systematic changes in structural, electrical, and optical properties of NiO thin films on c-sapphire introduced by nanosecond ultraviolet excimer laser pulses. Epitaxial nature of as deposited NiO was determined by x-ray diffraction phi scans and transmission electron microscopy (TEM) and it was established that NiO film growth takes place with twin domains on sapphire where two types of domains have 60 deg. in-plane rotation with respect to each other about the [111] growth direction. We determined that at pulsed laser energy density of 0.275 J/cm{sup 2}, NiO films exhibited conversion from p-type semiconducting to n-type conductive behavior with three orders of magnitude decrease in resistivity, while maintaining its cubic crystal structure and good epitaxial relationship. Our TEM and electron-energy-loss spectroscopy studies conclusively ruled out the presence of any Ni clustering or precipitation due to the laser treatment. The laser-induced n-type carrier transport and conductivity enhancement were shown to be reversible through subsequent thermal annealing in oxygen. This change in conductivity behavior was correlated with the nonequilibrium concentration of laser induced Ni{sup 0}-like defect states.

  5. A model Ni-Al-Mo superalloy studied by ultraviolet pulsed-laser-assisted local-electrode atom-probe tomography.

    PubMed

    Tu, Yiyou; Plotnikov, Elizaveta Y; Seidman, David N

    2015-04-01

    This study investigates the effects of the charge-state ratio of evaporated ions on the accuracy of local-electrode atom-probe (LEAP) tomographic compositional and structural analyses, which employs a picosecond ultraviolet pulsed laser. Experimental results demonstrate that the charge-state ratio is a better indicator of the best atom-probe tomography (APT) experimental conditions compared with laser pulse energy. The thermal tails in the mass spectra decrease significantly, and the mass resolving power (m/Δm) increases by 87.5 and 185.7% at full-width half-maximum and full-width tenth-maximum, respectively, as the laser pulse energy is increased from 5 to 30 pJ/pulse. The measured composition of this alloy depends on the charge-state ratio of the evaporated ions, and the most accurate composition is obtained when Ni2+/Ni+ is in the range of 0.3-20. The γ(f.c.c.)/γ'(L12) interface is quantitatively more diffuse when determined from the measured concentration profiles for higher laser pulse energies. Conclusions of the APT compositional and structural analyses utilizing the same suitable charge-state ratio are more comparable than those collected with the same laser pulse energy.

  6. Determination of polycyclic aromatic hydrocarbons and their nitro-, amino-derivatives absorbed on particulate matter 2.5 by multiphoton ionization mass spectrometry using far-, deep-, and near-ultraviolet femtosecond lasers.

    PubMed

    Tang, Yuanyuan; Imasaka, Tomoko; Yamamoto, Shigekazu; Imasaka, Totaro

    2016-06-01

    Multiphoton ionization processes of parent-polycyclic aromatic hydrocarbons (PPAHs), nitro-PAHs (NPAHs), and amino-PAHs (APAHs) were examined by gas chromatography combined with time-of-flight mass spectrometry using a femtosecond Ti:sapphire laser as the ionization source. The efficiency of multiphoton ionization was examined using lasers emitting in the far-ultraviolet (200 nm), deep-ultraviolet (267 nm), and near-ultraviolet (345 nm) regions. The largest signal intensities were obtained when the far-ultraviolet laser was employed. This favorable result can be attributed to the fact that these compounds have the largest molar absorptivities in the far-ultraviolet region. On the other hand, APAHs were ionized more efficiently than NPAHs in the near-ultraviolet region because of their low ionization energies. A sample extracted from a real particulate matter 2.5 (PM2.5) sample was measured, and numerous signal peaks arising from PAH and its analogs were observed at 200 nm. On the other hand, only a limited number of signed peaks were observed at 345 nm, some of which were signed to PPAHs, NPAHs, and APAHs. Thus, multiphoton ionization mass spectrometry has potential for the use in comprehensive analysis of toxic environmental pollutants.

  7. Detection of polychlorinated biphenyls in transformer oils in Vietnam by multiphoton ionization mass spectrometry using a far-ultraviolet femtosecond laser as an ionization source.

    PubMed

    Vu, Thi Thuy Duong; Vu, Duong; Nghiem, Thi Ha Lien; Imasaka, Tomoko; Tang, Yuanyuan; Shibuta, Shinpei; Hamachi, Akifumi; Do, Quang Hoa; Imasaka, Totaro

    2016-03-01

    Polychlorinated biphenyls (PCBs) in transformer and food oils were measured using gas chromatography combined with multiphoton ionization mass spectroscopy. An ultrashort laser pulse emitting in the far-ultraviolet region was utilized for efficient ionization of the analytes. Numerous signal peaks were clearly observed for a standard sample mixture of PCBs when the third and fourth harmonic emissions (267 and 200nm) of a femtosecond Ti:sapphire laser (800nm) were employed. The signal intensities were found to be greater when measured at 200nm compared with those measured at 267nm, providing lower detection limits especially for highly chlorinated PCBs at shorter wavelengths. After simple pretreatment using disposable columns, PCB congeners were measured and found to be present in the transformer oils used in Vietnam.

  8. Triple combination treatment with fractional CO2 laser plus topical betamethasone solution and narrowband ultraviolet B for refractory vitiligo: a prospective, randomized half-body, comparative study.

    PubMed

    Li, Lu; Wu, Yan; Li, Li; Sun, Yan; Qiu, Li; Gao, Xing-Hua; Chen, Hong-Duo

    2015-01-01

    Vitiligo on extremities and/or bony prominences is very resistant to treatment. Twenty-five patients with symmetrical and stable vitiligo on extremities and/or bony prominences were enrolled. The treatment side received fractional carbon dioxide laser followed by topical compound betamethasone solution and narrowband ultraviolet B phototherapy. The control side received laser treatment plus phototherapy. The result of treatment side showed that 44% patients achieved over 50% re-pigmentation and patient satisfaction score was 5.12 ± 3.23, higher than those of control (p < 0.05). Adverse events were slight and tolerable. The triple combination treatment could be used as an alternative modality for refractory vitiligo.

  9. Ultraviolet Waves

    ERIC Educational Resources Information Center

    Molde, Trevor

    1973-01-01

    Outlines the discovery and nature of ultraviolet light, discusses some applications for these wavelengths, and describes a number of experiments with ultraviolet radiation suitable for secondary school science classes. (JR)

  10. Photoionized plasmas induced in neon with extreme ultraviolet and soft X-ray pulses produced using low and high energy laser systems

    SciTech Connect

    Bartnik, A.; Wachulak, P.; Fok, T.; Węgrzyński, Ł.; Fiedorowicz, H.; Pisarczyk, T.; Chodukowski, T.; Kalinowska, Z.; Dudzak, R.; Dostal, J.; Krousky, E.; Skala, J.; Ullschmied, J.; Hrebicek, J.; Medrik, T.

    2015-04-15

    A comparative study of photoionized plasmas created by two soft X-ray and extreme ultraviolet (SXR/EUV) laser plasma sources with different parameters is presented. The two sources are based on double-stream Xe/He gas-puff targets irradiated with high (500 J/0.3 ns) and low energy (10 J/1 ns) laser pulses. In both cases, the SXR/EUV beam irradiated the gas stream, injected into a vacuum chamber synchronously with the radiation pulse. Irradiation of gases resulted in formation of photoionized plasmas emitting radiation in the SXR/EUV range. The measured Ne plasma radiation spectra are dominated by emission lines corresponding to radiative transitions in singly charged ions. A significant difference concerns origin of the lines: K-shell or L-shell emissions occur in case of the high and low energy irradiating system, respectively. In high energy system, the electron density measurements were also performed by laser interferometry, employing a femtosecond laser system. A maximum electron density for Ne plasma reached the value of 2·10{sup 18 }cm{sup −3}. For the low energy system, a detection limit was too high for the interferometric measurements, thus only an upper estimation for electron density could be made.

  11. Demonstration of transverse-magnetic deep-ultraviolet stimulated emission from AlGaN multiple-quantum-well lasers grown on a sapphire substrate

    SciTech Connect

    Li, Xiao-Hang E-mail: dupuis@gatech.edu; Kao, Tsung-Ting; Satter, Md. Mahbub; Shen, Shyh-Chiang; Yoder, P. Douglas; Detchprohm, Theeradetch; Dupuis, Russell D. E-mail: dupuis@gatech.edu; Wei, Yong O.; Wang, Shuo; Xie, Hongen; Fischer, Alec M.; Ponce, Fernando A.

    2015-01-26

    We demonstrate transverse-magnetic (TM) dominant deep-ultraviolet (DUV) stimulated emission from photo-pumped AlGaN multiple-quantum-well lasers grown pseudomorphically on an AlN/sapphire template by means of photoluminescence at room temperature. The TM-dominant stimulated emission was observed at wavelengths of 239, 242, and 243 nm with low thresholds of 280, 250, and 290 kW/cm{sup 2}, respectively. In particular, the lasing wavelength of 239 nm is shorter compared to other reports for AlGaN lasers grown on foreign substrates including sapphire and SiC. The peak wavelength difference between the transverse-electric (TE)-polarized emission and TM-polarized emission was approximately zero for the lasers in this study, indicating the crossover of crystal-field split-off hole and heavy-hole valence bands. The rapid variation of polarization between TE- and TM-dominance versus the change in lasing wavelength from 243 to 249 nm can be attributed to a dramatic change in the TE-to-TM gain coefficient ratio for the sapphire-based DUV lasers in the vicinity of TE-TM switch.

  12. The National Ignition Facility: Status and Plans for Laser Fusion and High-Energy-Density Experimental Studies

    SciTech Connect

    Moses, E I

    2002-01-11

    The National Ignition Facility (NIF), currently under construction at the University of California's Lawrence Livermore National Laboratory is a $2.25B stadium-sized facility containing a 192-beam, 1.8-Megajoule, 500-Terawatt, 351-nm laser system. NIF is being built by the National Nuclear Security Agency and when completed will be the world's largest laser system, providing a national center to study inertial confinement fusion and the physics of extreme energy densities and pressures. In NIF up to 192 energetic laser beams will compress small fusion targets to conditions where they will ignite and burn, liberating more energy than is required to initiate the fusion reactions. NIF experiments will allow the study of physical processes at temperatures approaching 100 million K and 100 billion times atmospheric pressure. These conditions exist naturally only in the interior of stars and in nuclear weapons explosions. In the course of designing the world's most energetic laser system, a number of significant technology breakthroughs have been achieved. Research is also underway to develop a shorter pulse capability on NIF for high power applications. We discuss here the technology challenges and solutions that have made NIF possible along with enhancements to NIF's design that could lead to exawatt power levels.

  13. The National Ignition Facility: Status and Plans for Laser Fusion and High-Energy-Density Experimental Studies

    SciTech Connect

    Moses, E I; Wuest, C R

    2002-10-16

    The National Ignition Facility (NIF), currently under construction at the University of California's Lawrence Livermore National Laboratory, is a stadium-sized facility containing a 192-beam, 1.8-Megajoule, 500-Terawatt, 351-nm laser system and a 10-meter diameter target chamber with room for nearly 100 experimental diagnostics. NIF is being built by the National Nuclear Security Administration and when completed will be the world's largest laser experimental system, providing a national center to study inertial confinement fusion and the physics of matter at extreme energy densities and pressures. NIF will provide 192 energetic laser beams that will compress small fusion targets to conditions where they will ignite and burn, liberating more energy than is required to initiate the fusion reactions. NIF experiments will allow the study of physical processes at temperatures approaching 100 million K and 100 billion times atmospheric pressure. These conditions exist naturally only in the interior of stars and in nuclear weapons explosions. In the course of designing the world's most energetic laser system, a number of significant technology breakthroughs have been achieved. Research is also underway to develop a shorter pulse capability on NIF for very high power and extreme electromagnetic field research and applications. We discuss here the technology challenges and solutions that have made NIF possible, along with enhancements to NIF's design that could lead to near-exawatt power levels.

  14. A comparative study of corneal incisions induced by diamond and steel knives and two ultraviolet radiations from an excimer laser.

    PubMed Central

    Marshall, J; Trokel, S; Rothery, S; Krueger, R R

    1986-01-01

    This paper reviews the potential role of excimer lasers in corneal surgery. The morphology of incisions induced by two wavelengths of excimer laser radiation, 193 nm and 248 nm, are compared with the morphology of incisions produced by diamond and steel knives. Analysis suggests that ablation induced by excimer laser results from highly localised photochemical reactions and that 193 nm is the optimal wavelength for surgery. The only significant complication of laser surgery is loss of endothelial cells when incisions are within 40 micron of Descemet's membrane. Images PMID:3013283

  15. Formation of a fine-dispersed liquid-metal target under the action of femto- and picosecond laser pulses for a laser-plasma radiation source in the extreme ultraviolet range

    SciTech Connect

    Vinokhodov, A Yu; Krivokorytov, M S; Koshelev, K N; Krivtsun, V M; Sidelnikov, Yu V; Medvedev, V V; Kompanets, V O; Melnikov, A A; Chekalin, S V

    2016-01-31

    We report the results of studying the dynamics of deformation and fragmentation of liquid-metal droplets under the action of ultrashort laser pulses. The experiments have been performed to optimise the shape of the droplet target used in extreme ultraviolet (EUV) radiation sources based on the laser-produced plasma using the pre-pulse technology. The pre-pulse is generated by a system incorporating a master Ti : sapphire oscillator and a regenerative amplifier, allowing one to vary the pulse duration from 50 fs to 50 ps. The power density of laser radiation at the droplet target, averaged over the pulse duration and spatial coordinates, has reached 3 × 10{sup 15} W cm{sup -2}. The production of liquid-metal droplets has been implemented by means of a droplet generator based on a nozzle with a ring piezoceramic actuator. The droplet material is the eutectic indium – tin alloy. The droplet generator could operate in the droplet and jet regime with a maximal rate of stable operation 5 and 150 kHz, respectively. The spatial stability of droplet position σ = 1% – 2% of its diameter is achieved. The size of the droplets varied within 30 – 70 μm, their velocity was 2 – 8 m s{sup -1} depending on the operation regime. (interaction of laser radiation with matter. laser plasma)

  16. Room-temperature deep-ultraviolet lasing at 241.5 nm of AlGaN multiple-quantum-well laser

    NASA Astrophysics Data System (ADS)

    Takano, Takayoshi; Narita, Yoshinobu; Horiuchi, Akihiko; Kawanishi, Hideo

    2004-05-01

    Room-temperature deep-ultraviolet lasing of AlxGa1-xN multiple-quantum-well lasers with an Al composition x of 0.66 was achieved at 241.5 nm under pulsed optical pumping. The threshold pumping power was approximately 1200 kW/cm2 at room temperature. The shortest lasing wavelength was 231.8 nm at 20 K. The laser structure was grown on a high-quality AlN layer, which was grown on a 4H-SiC substrate by inserting an AlN/GaN multibuffer-layer structure between the substrate and the AlN layer. Temperature dependence of lasing wavelength was also estimated to be 0.01 and 0.03 nm/K in the temperature region from 20 to 150 K and from 160 K to room temperature, respectively. The laser cavity was made of a cleaved facet of AlGaN epitaxial layers and a SiC substrate. For this purpose, it was necessary to polish the wafer to a thickness of less than 100 μm. The optimal wafer thickness for cleaving in our experiments was 60-70 μm.

  17. Real-time monitoring of benzene, toluene, and p-xylene in a photoreaction chamber with a tunable mid-infrared laser and ultraviolet differential optical absorption spectroscopy.

    PubMed

    Parsons, Matthew T; Sydoryk, Ihor; Lim, Alan; McIntyre, Thomas J; Tulip, John; Jäger, Wolfgang; McDonald, Karen

    2011-02-01

    We describe the implementation of a mid-infrared laser-based trace gas sensor with a photoreaction chamber, used for reproducing chemical transformations of benzene, toluene, and p-xylene (BTX) gases that may occur in the atmosphere. The system performance was assessed in the presence of photoreaction products including aerosol particles. A mid-infrared external cavity quantum cascade laser (EC-QCL)-tunable from 9.41-9.88 μm (1012-1063 cm(-1))-was used to monitor gas phase concentrations of BTX simultaneously and in real time during chemical processing of these compounds with hydroxyl radicals in a photoreaction chamber. Results are compared to concurrent measurements using ultraviolet differential optical absorption spectroscopy (UV DOAS). The EC-QCL based system provides quantitation limits of approximately 200, 200, and 600 parts in 10(9) (ppb) for benzene, toluene, and p-xylene, respectively, which represents a significant improvement over our previous work with this laser system. Correspondingly, we observe the best agreement between the EC-QCL measurements and the UV DOAS measurements with benzene, followed by toluene, then p-xylene. Although BTX gas-detection limits are not as low for the EC-QCL system as for UV DOAS, an unidentified by-product of the photoreactions was observed with the EC-QCL, but not with the UV DOAS system.

  18. On the maximum conversion efficiency into the 13.5-nm extreme ultraviolet emission under a steady-state laser ablation of tin microspheres

    NASA Astrophysics Data System (ADS)

    Basko, M. M.

    2016-08-01

    Theoretical investigation has been performed on the conversion efficiency (CE) into the 13.5-nm extreme ultraviolet (EUV) radiation in a scheme where spherical microspheres of tin (Sn) are simultaneously irradiated by two laser pulses with substantially different wavelengths. The low-intensity short-wavelength pulse is used to control the rate of mass ablation and the size of the EUV source, while the high-intensity long-wavelength pulse provides efficient generation of the EUV light at λ=13.5 nm. The problem of full optimization for maximizing the CE is formulated and solved numerically by performing two-dimensional radiation-hydrodynamics simulations with the RALEF-2D code under the conditions of steady-state laser illumination. It is shown that, within the implemented theoretical model, steady-state CE values approaching 9% are feasible; in a transient peak, the maximum instantaneous CE of 11.5% was calculated for the optimized laser-target configuration. The physical factors, bringing down the fully optimized steady-state CE to about one half of the absolute theoretical maximum of CE≈20 % for the uniform static Sn plasma, are analyzed in detail.

  19. Solid-state laser source of narrowband ultraviolet B light for skin disease care with advanced performance

    NASA Astrophysics Data System (ADS)

    Tarasov, Aleksandr A.; Chu, Hong; Buchwald, Kristian

    2015-02-01

    Two years ago we reported about the development of solid state laser source for medical skin treatment with wavelength 310.6 nm and average power 200 mW. Here we describe the results of investigation of the advanced version of the laser, which is a more compact device with increased output power and flat top beam profile. Ti: Sapphire laser, the main module of our source, was modified and optimized such, that UV average power of the device was increased 1.7 times. Fiber optic homogenizer was replaced by articulated arm with diffraction diffuser, providing round spot with flat profile at the skin. We investigated and compare characteristics of Ti: Sapphire lasers with volume Bragg grating and with fused silica transmission grating, which was used first time for Ti: Sapphire laser spectral selection and tuning. Promising performance of last gratings is demonstrated.

  20. Picosecond green and deep ultraviolet pulses generated by a high-power 100  kHz thin-disk laser.

    PubMed

    Novák, Ondřej; Turčičová, Hana; Smrž, Martin; Miura, Taisuke; Endo, Akira; Mocek, Tomáš

    2016-11-15

    We report on the generation of the second (515 nm) and fourth (257.5 nm) harmonics from a 100 kHz diode-pumped solid-state laser operating at a wavelength of 1030 nm which uses one Yb:YAG thin disk in the regenerative amplifier and delivers 60 W of the average output power in pulses of 4 ps duration. Thirty-five W in green light and 6 W in deep ultraviolet (DUV) were achieved. The sensitivity of the second harmonic generation efficiency toward the lithium triborate crystal temperature is demonstrated in experiment. The overall conversion efficiency from NIR to DUV of 10% was achieved. The β-barium borate and cesium lithium borate crystals were used as green to DUV convertors and compared regarding the efficiency and spectral bandwidths. The achieved output power is unique for DUV picosecond pulses.

  1. Matrix-assisted ultraviolet laser desorption/ionization time-of-flight (UV-MALDI-TOF) mass spectra of N-acylated and N,O-acylated glycosylamines.

    PubMed

    Sato, Yasuto; Fukuyama, Yuko; Nonami, Hiroshi; Erra-Balsells, Rosa; Stortz, Carlos A; Cerezo, Alberto S; Matulewicz, María C

    2007-12-10

    Matrix-assisted ultraviolet laser desorption/ionization time-of-flight mass spectrometry (UV-MALDI-TOF-MS) has shown to be a very useful technique for the study of the non-volatile and thermally non-stable N-acylated glycopyranosyl- and glycofuranosyl-amines. Of the several matrices tested, 2,5-dihydroxybenzoic acid (DHB) was the most effective giving good spectra in the positive-ion mode. In the linear and reflectron modes, the [M+Na](+) ions appeared with high intensity. Their fragmentation patterns were investigated by post-source decay (PSD) UV-MALDI-TOF-MS showing mainly cross-ring cleavages. In addition, N,O-acylated glycopyranosyl- and glycofuranosyl-amines were also analyzed by this technique. PSD UV-MALDI-TOF-MS gave significant signals for several primary fragment ions, which were proposed but not detected, or observed with very low abundance, in electron ionization mass spectrometry (EI-MS) experiments.

  2. Linkage of oxygen deficiency defects and rare earth concentrations in silica glass optical fiber probed by ultraviolet absorption and laser excitation spectroscopy.

    PubMed

    Liu, Y-S; Galvin, T C; Hawkins, T; Ballato, J; Dong, L; Foy, P R; Dragic, P D; Eden, J G

    2012-06-18

    Ultraviolet absorption measurements and laser excitation spectroscopy in the vicinity of 248 nm provide compelling evidence for linkages between the oxygen deficiency center (ODC) and rare earth concentrations in Yb and Er-doped glass optical fibers. Investigations of YAG-derived and solution-doped glass fibers are described. For both Yb and Er-doped fibers, the dependence of Type II ODC absorption on the rare earth number density is approximately linear, but the magnitude of the effect is greater for Yb-doped fibers. Furthermore, laser excitation spectra demonstrate unambiguously the existence of an energy transfer mechanism coupling an ODC with Yb(3+). Photopumping glass fibers with a Ti:sapphire laser/optical parametric amplifier system, tunable over the 225-265 nm region, or with a KrF laser at 248.4 nm show: 1) emission features in the 200-1100 nm interval attributable only to the ODC (Type II) defect or Yb(3+), and 2) the excitation spectra for ODC (II) emission at ~280 nm and Yb(3+) fluorescence (λ ~1.03 μm) to be, within experimental uncertainty, identical. The latter demonstrates that, when irradiating Yb-doped silica fibers between ~240 and 255 nm, the ODC (II) defect is at least the primary precursor to Yb(3+) emission. Consistent with previous reports in the literature, the data show the ODC (II) absorption spectrum to have a peak wavelength and breadth of ~246 nm and ~19 nm (FWHM). Experiments also reveal that, in the absence of Yb, incorporating either Al(2)O(3) or Y(2)O(3) into glass fibers has a negligible impact on the ODC concentration. Not only do the data reported here demonstrate the relationship between the ODC (II) number density and the Yb doping concentration, but they also suggest that the appearance of ODC defects in the fiber is associated with the introduction of Yb and the process by which the fiber is formed.

  3. A Solid State Ultraviolet Lasers Based on Cerium-Doped LiCaAIF(sub 6) Crystal Resonator

    NASA Technical Reports Server (NTRS)

    Yu, Nan; Le, Thanh; Schowalter, Steven J.; Rellergert, Wade; Jeet, Justin; Lin, Guoping; Hudson, Eric

    2012-01-01

    We report the first demonstration of a UV laser using a high-Q whispering gallery mode (WGM) resonator of Ce+: LiCaAlF6. We show that WGM resonators from LiCaAlF6 can achieve a Q of 2.6 x 10(sup 7) at UV. We demonstrated a UV laser at 290 nm with a pulsed pump laser at 266 nm. The experiments showed the low pump threshold intensity of 7.5 x 10(sup 9) W/m(sup 2) and slope efficiency of 25%. We have also observed lasing delay dynamics. These results are consistent with our modeling and theoretical estimates, and pave the way for a low threshold cw UV laser using WGM resonator cavity.

  4. Ultraviolet filters.

    PubMed

    Shaath, Nadim A

    2010-04-01

    The chemistry, photostability and mechanism of action of ultraviolet filters are reviewed. The worldwide regulatory status of the 55 approved ultraviolet filters and their optical properties are documented. The photostabilty of butyl methoxydibenzoyl methane (avobenzone) is considered and methods to stabilize it in cosmetic formulations are presented.

  5. Femtosecond time-resolved photoelectron spectroscopy with a vacuum-ultraviolet photon source based on laser high-order harmonic generation.

    PubMed

    Wernet, Philippe; Gaudin, Jérôme; Godehusen, Kai; Schwarzkopf, Olaf; Eberhardt, Wolfgang

    2011-06-01

    A laser-based tabletop approach to femtosecond time-resolved photoelectron spectroscopy with photons in the vacuum-ultraviolet (VUV) energy range is described. The femtosecond VUV pulses are produced by high-order harmonic generation (HHG) of an amplified femtosecond Ti:sapphire laser system. Two generations of the same setup and results from photoelectron spectroscopy in the gas phase are discussed. In both generations, a toroidal grating monochromator was used to select one harmonic in the photon energy range of 20-30 eV. The first generation of the setup was used to perform photoelectron spectroscopy in the gas phase to determine the bandwidth of the source. We find that our HHG source has a bandwidth of 140 ± 40 meV. The second and current generation is optimized for femtosecond pump-probe photoelectron spectroscopy with high flux and a small spot size at the sample of the femtosecond probe pulses. The VUV radiation is focused into the interaction region with a toroidal mirror to a spot smaller than 100 × 100 μm(2) and the flux amounts to 10(10) photons/s at the sample at a repetition rate of 1 kHz. The duration of the monochromatized VUV pulses is determined to be 120 fs resulting in an overall pump-probe time resolution of 135 ± 5 fs. We show how this setup can be used to map the transient valence electronic structure in molecular dissociation.

  6. Infrared vacuum-ultraviolet laser pulsed field ionization-photoelectron study of CH3Br+ (X(2)E(3/2)).

    PubMed

    Xing, X; Wang, P; Reed, B; Baek, S-J; Ng, C Y

    2008-10-02

    By preparing methyl bromide (CH3Br) in selected rotational levels of the CH3Br(X(1)A1; v1 = 1) state with infrared (IR) laser excitation prior to vacuum-ultraviolet (VUV) laser pulsed field ionization-photoelectron (PFI-PE) measurements, we have observed rotationally resolved photoionization transitions to the CH3Br(+)(X(2)E(3/2); v1(+) = 1) state, where v1 and v1(+) are the symmetric C-H stretching vibrational mode for the neutral and cation, respectively. The VUV-PFI-PE origin band for CH3Br(+)(X(2)E(3/2)) has also been measured. The simulation of these IR-VUV-PFI-PE and VUV-PFI-PE spectra have allowed the determination of the v1(+) vibrational frequency (2901.8 +/- 0.5 cm(-1)) and the ionization energies of the origin band (85 028.3 +/- 0.5 cm(-1)) and the v1(+) = 1 <-- v1 = 1 band (84 957.9 +/- 0.5 cm(-1)).

  7. Characterization of mixtures of compounds produced in chlorpromazine aqueous solutions by ultraviolet laser irradiation: their applications in antimicrobial assays

    NASA Astrophysics Data System (ADS)

    Alexandru, Tatiana; Staicu, Angela; Pascu, Alexandru; Radu, Elena; Stoicu, Alexandru; Nastasa, Viorel; Dinache, Andra; Boni, Mihai; Amaral, Leonard; Pascu, Mihail Lucian

    2015-05-01

    The study reports an investigation of the photoproducts obtained by exposure of chlorpromazine hydrochloride in ultrapure water (concentration 2 mg/mL) to a 266-nm laser beam obtained by fourth harmonic generation from a Nd:YAG laser (6-ns full time width at half maximum, 10-Hz pulse repetition rate). The photoproducts were analyzed by steady-state UV-Vis absorption, laser-induced fluorescence, Fourier transform infrared spectroscopy, and liquid chromatography-tandem time-of-flight mass spectroscopy. Two figures showing pathways that take place during irradiation for obtaining the final products are shown. The quantum yield of singlet oxygen generation by chlorpromazine (CPZ) was determined relative to standard Zn-phthalocyanine in dimethyl sulfoxide. To outline the role of fluorescence in photoproducts formation rates, fluorescence quantum yield of CPZ during exposure to 355-nm radiation (third harmonic of the fundamental beam of Nd:YAG laser) was investigated relative to standard Coumarin 1 in ethanol. The CPZ solutions exposed 60 and 240 min to 266-nm laser beam, respectively, were tested against Staphylococcus aureus ATCC 25923 strain. For 25 μL of CPZ samples irradiated 240 min, a higher diameter of inhibition has obtained against the tested strain than for the 60-min exposed ones.

  8. Characterization of mixtures of compounds produced in chlorpromazine aqueous solutions by ultraviolet laser irradiation: their applications in antimicrobial assays.

    PubMed

    Alexandru, Tatiana; Staicu, Angela; Pascu, Alexandru; Radu, Elena; Stoicu, Alexandru; Nastasa, Viorel; Dinache, Andra; Boni, Mihai; Amaral, Leonard; Pascu, Mihail Lucian

    2015-05-01

    The study reports an investigation of the photoproducts obtained by exposure of chlorpromazine hydrochloride in ultrapure water (concentration 2 mg/mL) to a 266-nm laser beam obtained by fourth harmonic generation from a Nd:YAG laser (6-ns full time width at half maximum, 10-Hz pulse repetition rate). The photoproducts were analyzed by steady-state UV-Vis absorption, laser-induced fluorescence, Fourier transform infrared spectroscopy, and liquid chromatography-tandem time-of-flight mass spectroscopy. Two figures showing pathways that take place during irradiation for obtaining the final products are shown. The quantum yield of singlet oxygen generation by chlorpromazine (CPZ) was determined relative to standard Zn-phthalocyanine in dimethyl sulfoxide. To outline the role of fluorescence in photoproducts formation rates, fluorescence quantum yield of CPZ during exposure to 355-nm radiation (third harmonic of the fundamental beam of Nd:YAG laser) was investigated relative to standard Coumarin 1 in ethanol. The CPZ solutions exposed 60 and 240 min to 266-nm laser beam, respectively, were tested against Staphylococcus aureus ATCC 25923 strain. For 25 μL of CPZ samples irradiated 240 min, a higher diameter of inhibition has obtained against the tested strain than for the 60-min exposed ones.

  9. Note: deep ultraviolet Raman spectrograph with the laser excitation line down to 177.3 nm and its application.

    PubMed

    Jin, Shaoqing; Fan, Fengtao; Guo, Meiling; Zhang, Ying; Feng, Zhaochi; Li, Can

    2014-04-01

    Deep UV Raman spectrograph with the laser excitation line down to 177.3 nm was developed in this laboratory. An ellipsoidal mirror and a dispersed-subtractive triple monochromator were used to collect and disperse Raman light, respectively. The triple monochromator was arranged in a triangular configuration with only six mirrors used. 177.3 nm laser excited Raman spectrum with cut-off wavenumber down to 200 cm(-1) and spectral resolution of 8.0 cm(-1) can be obtained under the condition of high purity N2 purging. With the C-C σ bond in Teflon selectively excited by the 177.3 nm laser, resonance Raman spectrum of Teflon with good quality was recorded on the home-built instrument and the σ-σ(*) transition of C-C bond was studied. The result demonstrates that deep UV Raman spectrograph is powerful for studying the systems with electronic transition located in the deep UV region.

  10. Note: Deep ultraviolet Raman spectrograph with the laser excitation line down to 177.3 nm and its application

    NASA Astrophysics Data System (ADS)

    Jin, Shaoqing; Fan, Fengtao; Guo, Meiling; Zhang, Ying; Feng, Zhaochi; Li, Can

    2014-04-01

    Deep UV Raman spectrograph with the laser excitation line down to 177.3 nm was developed in this laboratory. An ellipsoidal mirror and a dispersed-subtractive triple monochromator were used to collect and disperse Raman light, respectively. The triple monochromator was arranged in a triangular configuration with only six mirrors used. 177.3 nm laser excited Raman spectrum with cut-off wavenumber down to 200 cm-1 and spectral resolution of 8.0 cm-1 can be obtained under the condition of high purity N2 purging. With the C-C σ bond in Teflon selectively excited by the 177.3 nm laser, resonance Raman spectrum of Teflon with good quality was recorded on the home-built instrument and the σ-σ* transition of C-C bond was studied. The result demonstrates that deep UV Raman spectrograph is powerful for studying the systems with electronic transition located in the deep UV region.

  11. Waveform-controlled near-single-cycle milli-joule laser pulses generate sub-10 nm extreme ultraviolet continua.

    PubMed

    Schweinberger, Wolfgang; Sommer, Annkatrin; Bothschafter, Elisabeth; Li, Jiang; Krausz, Ferenc; Kienberger, Reinhard; Schultze, Martin

    2012-09-01

    We demonstrate the generation of waveform-controlled laser pulses with 1 mJ pulse energy and a full-width-half-maximum duration of ∼4  fs, therefore lasting less than two cycles of the electric field oscillating at their carrier frequency. The laser source is carrier-envelope-phase stabilized and used as the backbone of a kHz repetition rate source of high-harmonic continua with unprecedented flux at photon energies between 100 and 200 eV (corresponding to a wavelength range between 12-6 nm respectively). In combination we use these tools for the complete temporal characterization of the laser pulses via attosecond streaking spectroscopy.

  12. Determination of photophysical parameters of red fluorescent protein mRFP1 under ultraviolet excitation by methods of laser fluorimetry.

    PubMed

    Banishev, Alexandr A; Shirshin, Evgeny A; Fadeev, Victor V

    2010-12-01

    We investigate photophysical processes that take place in macromolecules of a fluorescent protein mRFP1 under UV excitation [when the energy transfer in a localized donor-acceptor (LDA) pair, which is presented in the molecules of the protein, becomes apparent]. We used a special approach based on the fluorescence laser spectroscopy technique. The energy transfer rates in LDA pairs and photophysical parameters of fluorophores (chromophores) of three spectral forms, which coexist in the ensemble of the macromolecules of this protein, were determined under pulse UV laser excitation.

  13. Role of HfO2/SiO2 thin-film interfaces in near-ultraviolet absorption and pulsed laser damage

    SciTech Connect

    Papernov, Semyon; Kozlov, Alexei A.; Oliver, James B.; Smith, Chris; Jensen, Lars; Guenster, Stefan; Maedebach, Heinrich; Ristau, Detlev

    2016-07-15

    Here, the role of thin-film interfaces in the near-ultraviolet (near-UV) absorption and pulsed laser-induced damage was studied for ion-beam-sputtered and electron-beam-evaporated coatings comprised from HfO2 and SiO2 thin-film pairs. To separate contributions from the bulk of the film and from interfacial areas, absorption and damage threshold measurements were performed for a one-wave (355-nm wavelength) thick, HfO2 single-layer film and for a film containing seven narrow HfO2 layers separated by SiO2 layers. The seven-layer film was designed to have a total optical thickness of HfO2 layers, equal to one wave at 355 nm and an E-field peak and average intensity similar to a single-layer HfO2 film. Absorption in both types of films was measured using laser calorimetry and photothermal heterodyne imaging. The results showed a small contribution to total absorption from thin-film interfaces as compared to HfO2 film material. The relevance of obtained absorption data to coating near-UV, nanosecond-pulse laser damage was verified by measuring the damage threshold and characterizing damage morphology. The results of this study revealed a higher damage resistance in the seven-layer coating as compared to the single-layer HfO2 film in both sputtered and evaporated coatings. The results are explained through the similarity of interfacial film structure with structure formed during the codeposition of HfO2 and SiO2 materials.

  14. Role of HfO2/SiO2 thin-film interfaces in near-ultraviolet absorption and pulsed laser damage

    DOE PAGES

    Papernov, Semyon; Kozlov, Alexei A.; Oliver, James B.; ...

    2016-07-15

    Here, the role of thin-film interfaces in the near-ultraviolet (near-UV) absorption and pulsed laser-induced damage was studied for ion-beam-sputtered and electron-beam-evaporated coatings comprised from HfO2 and SiO2 thin-film pairs. To separate contributions from the bulk of the film and from interfacial areas, absorption and damage threshold measurements were performed for a one-wave (355-nm wavelength) thick, HfO2 single-layer film and for a film containing seven narrow HfO2 layers separated by SiO2 layers. The seven-layer film was designed to have a total optical thickness of HfO2 layers, equal to one wave at 355 nm and an E-field peak and average intensity similarmore » to a single-layer HfO2 film. Absorption in both types of films was measured using laser calorimetry and photothermal heterodyne imaging. The results showed a small contribution to total absorption from thin-film interfaces as compared to HfO2 film material. The relevance of obtained absorption data to coating near-UV, nanosecond-pulse laser damage was verified by measuring the damage threshold and characterizing damage morphology. The results of this study revealed a higher damage resistance in the seven-layer coating as compared to the single-layer HfO2 film in both sputtered and evaporated coatings. The results are explained through the similarity of interfacial film structure with structure formed during the codeposition of HfO2 and SiO2 materials.« less

  15. High-power ultraviolet 278 nm laser from fourth-harmonic generation of a Nd:YAG laser in CsB3O5.

    PubMed

    Wang, Zhichao; Yang, Feng; Zhang, Guochun; Bo, Yong; Liu, Shanshan; Xie, Shiyong; Xu, Yiting; Zong, Nan; Li, Fangqin; Liu, Biaolong; Xu, Jialin; Peng, Qinjun; Zhang, Jingyuan; Cui, Dafu; Wu, Yicheng; Xu, Zuyan

    2012-06-15

    We demonstrate a high-power UV 278 nm laser by fourth-harmonic generation (FHG) of a 1112 nm Nd:YAG laser in a nonlinear optical (NLO) crystal CsB3O5 (CBO) for the first time, to our best knowledge. A 30 W level diode-pumped Q-switched Nd:YAG laser at 1112 nm with beam quality factor M2=1.2 was used as the fundamental light source at a pulse width of 500 ns. With an LiB3O5 crystal, the 1112 nm laser was first frequency-doubled to 556 nm with an average output power of 13.5 W. It was then frequency doubled again in a CBO crystal to obtain the FHG output at 278 nm. The maximum average output power of the 278 nm laser is up to 1.5 W. The results demonstrated that CBO crystal is a promising NLO material for UV high-power lasers below 300 nm.

  16. Fabrication of a high-density nano-porous structure on polyimide by using ultraviolet laser irradiation

    NASA Astrophysics Data System (ADS)

    Ma, Yong-Won; Jeong, Myung Yung; Lee, Sang-Mae; Shin, Bo Sung

    2016-03-01

    A new approach for fabricating a high-density nano-porous structure on polyimide (PI) by using a 355-nm UV laser is presented here. When PI was irradiated by using a laser, debris that had electrical conductivity was generated. Accordingly, that debris caused electrical defects in the field of electronics. Thus, many researchers have tried to focus on a clean processing without debris. However, this study focused on forming a high density of debris so as to fabricate a nano-porous structure consisting of nanofibers on the PI film. A PI film with closed pores and open pores was successfully formed by using a chemical blowing agent (azodicarbonamide, CBA) in an oven. Samples were precured at 130 °C and cured at 205 °C in sequence so that the closed pores might not coalesce in the film. When the laser irradiated the PI film with closed pores, nanofibers were generated because polyimide was not completely decomposed by photochemical ablation. Our results indicated that a film with micro-closed pores, in conjunction with a 355-nm pulsed laser, can facilitate the fabrication of a high-density nano-porous structure.

  17. The National Ignition Facility: Status and Plans for Laser Fusion and High-Energy-Density Experimental Studies

    SciTech Connect

    Wuest, C

    2001-10-29

    The National Ignition Facility (NIF) currently under construction at the University of California Lawrence Livermore National Laboratory (LLNL) is a 192-beam, 1.8-megajoule, 500-terawatt, 351-nm laser for inertial confinement fusion (ICF) and high-energy-density experimental studies. NIF is being built by the Department of Energy and the National Nuclear Security Agency (NNSA) to provide an experimental test bed for the U.S. Stockpile Stewardship Program to ensure the country's nuclear deterrent without underground nuclear testing. The experimental program will encompass a wide range of physical phenomena from fusion energy production to materials science. Of the roughly 700 shots available per year, about 10% will be dedicated to basic science research. Laser hardware is modularized into line replaceable units (LRUs) such as deformable mirrors, amplifiers, and multi-function sensor packages that are operated by a distributed computer control system of nearly 60,000 control points. The supervisory control room presents facility-wide status and orchestrates experiments using operating parameters predicted by physics models. A network of several hundred front-end processors (FEPs) implements device control. The object-oriented software system is implemented in the Ada and Java languages and emphasizes CORBA distribution of reusable software objects. NIF is currently scheduled to provide first light in 2004 and will be completed in 2008.

  18. Ultraviolet Extensions

    NASA Technical Reports Server (NTRS)

    2008-01-01

    [figure removed for brevity, see original site] Side-by-Side Comparison Click on image for larger view

    This ultraviolet image from NASA's Galaxy Evolution Explorer shows the Southern Pinwheel galaxy, also know as Messier 83 or M83. It is located 15 million light-years away in the southern constellation Hydra.

    Ultraviolet light traces young populations of stars; in this image, young stars can be seen way beyond the main spiral disk of M83 up to 140,000 light-years from its center. Could life exist around one of these far-flung stars? Scientists say it's unlikely because the outlying regions of a galaxy are lacking in the metals required for planets to form.

    The image was taken at scheduled intervals between March 15 and May 20, 2007. It is one of the longest-exposure, or deepest, images ever taken of a nearby galaxy in ultraviolet light. Near-ultraviolet light (or longer-wavelength ultraviolet light) is colored yellow, and far-ultraviolet light is blue.

    What Lies Beyond the Edge of a Galaxy The side-by-side comparison shows the Southern Pinwheel galaxy, or M83, as seen in ultraviolet light (right) and at both ultraviolet and radio wavelengths (left). While the radio data highlight the galaxy's long, octopus-like arms stretching far beyond its main spiral disk (red), the ultraviolet data reveal clusters of baby stars (blue) within the extended arms.

    The ultraviolet image was taken by NASA's Galaxy Evolution Explorer between March 15 and May 20, 2007, at scheduled intervals. Back in 2005, the telescope first photographed M83 over a shorter period of time. That picture was the first to reveal far-flung baby stars forming up to 63,000 light-years from the edge of the main spiral disk. This came as a surprise to astronomers because a galaxy's outer territory typically lacks high densities of star-forming materials.

    The newest picture of M83 from the Galaxy Evolution Explorer is shown at the right, and was taken over a longer period of

  19. The National Ignition Facility Status and Plans for Laser Fusion and High Energy Density Experimental Studies

    NASA Astrophysics Data System (ADS)

    Wuest, Craig R.

    2001-03-01

    The National Ignition Facility (NIF) currently under construction at the University of California Lawrence Livermore National Laboratory is 192-beam, 1.8 Megajoule, 500 Terawatt, 351 nm laser for inertial confinement fusion and high energy density experimental studies. NIF is being built by the Department of Energy and the National Nuclear Security Agency to provide an experimental test bed for the US Stockpile Stewardship Program to ensure the country’s nuclear deterrent without underground nuclear testing. The experimental program for NIF will encompass a wide range of physical phenomena from fusion energy production to materials science. Of the roughly 700 shots available per year, about 10% of the shots will be dedicated to basic science research. Additionally, most of the shots on NIF will be conducted in unclassified configurations that will allow participation from the greater scientific community in planned applied physics experiments. This presentation will provide a look at the status of the construction project as well as a description of the scientific uses of NIF. NIF is currently scheduled to provide first light in 2004 and will be completed in 2008. This work was performed under the auspices of the U.S. Department of Energy by University of California Lawrence Livermore National Laboratory under contract No. W-7405-Eng-48.

  20. Space-resolved analysis of trace elements in fresh vegetables using ultraviolet nanosecond laser-induced breakdown spectroscopy

    NASA Astrophysics Data System (ADS)

    Juvé, Vincent; Portelli, Richard; Boueri, Myriam; Baudelet, Matthieu; Yu, Jin

    2008-10-01

    Laser-induced breakdown spectroscopy (LIBS) has been applied to analyze trace elements contained in fresh vegetables. A quadrupled Nd:YAG laser is used in the experiments for ablation. Analyzed samples come from local markets and represent frequently consumed vegetables. For a typical root vegetable, such as potato, spectral analysis of the plasma emission reveals more than 400 lines emitted by 27 elements and 2 molecules, C 2 and CN. Among these species, one can find trace as well as ultra-trace elements. A space-resolved analysis of several trace elements with strong emissions is then applied to typical root, stem and fruit vegetables. The results from this study demonstrate the potential of an interesting tool for botanical and agricultural studies as well for food quality/safety and environment pollution assessment and control.

  1. Change of self-focusing behavior of phosphate glass resulting from exposure to ultraviolet nanosecond laser pulses.

    PubMed

    Demos, Stavros G; Ehrmann, Paul R; Johnson, Michael A; Schaffers, Kathleen I; Rubenchik, Alexander M; Feit, Michael D

    2013-02-25

    The self-focusing characteristic of 355 nm, 3.3 ns pulses propagating through phosphate glass samples is found to significantly change during repeated exposure. The results indicate this change is related to the formation of color centers in the material as well as the generation of a transient defect population during exposure to the laser pulses. A model is used to fit the experimental data and obtain an estimated range of values for the modified linear and nonlinear indices of refraction.

  2. Measurements of NO and OH Concentrations in Vitiated Air Using Diode Laser-Based Ultraviolet Absorption Sensors (Postprint)

    DTIC Science & Technology

    2006-12-01

    ITIATION has long been used to simulate high-Mach number flight conditions for ground tests of supersonic propulsion systems . In the vitiation process...been measured in a hypersonic wind tunnel using a cryogenically -cooled lead-salt diode laser.12 However, these previous NO measurements were severely...Wright-Patterson AFB is used to study supersonic fuel injection, flameholding, ignition, and inlet-combustor isolation in scramjet propulsion systems .17

  3. Note: Deep ultraviolet Raman spectrograph with the laser excitation line down to 177.3 nm and its application

    SciTech Connect

    Jin, Shaoqing; Fan, Fengtao; Guo, Meiling; Zhang, Ying; Feng, Zhaochi E-mail: canli@dicp.ac.cn; Li, Can E-mail: canli@dicp.ac.cn

    2014-04-15

    Deep UV Raman spectrograph with the laser excitation line down to 177.3 nm was developed in this laboratory. An ellipsoidal mirror and a dispersed-subtractive triple monochromator were used to collect and disperse Raman light, respectively. The triple monochromator was arranged in a triangular configuration with only six mirrors used. 177.3 nm laser excited Raman spectrum with cut-off wavenumber down to 200 cm{sup −1} and spectral resolution of 8.0 cm{sup −1} can be obtained under the condition of high purity N{sub 2} purging. With the C–C σ bond in Teflon selectively excited by the 177.3 nm laser, resonance Raman spectrum of Teflon with good quality was recorded on the home-built instrument and the σ-σ{sup *} transition of C–C bond was studied. The result demonstrates that deep UV Raman spectrograph is powerful for studying the systems with electronic transition located in the deep UV region.

  4. Développement d'une source plasma-laser pour lalithographie dans l'extrême ultraviolet

    NASA Astrophysics Data System (ADS)

    Soullié, G.; Lafon, C.; Rosch, R.; Babonneau, D.; Garaude, F.; Huelvan, S.; Trublet, T.; Bonnet, L.; Marmoret, R.

    2003-06-01

    Cet article présente notre rôle au sein du projet PREUVE (PRogramme Extrême UV), en particulier, le développement et la caractérisation d'une source EUV plasma-laser. Cette souce est basée sur l'utilisation du rayonnement EUV émis en face arrière d'une cible irradiée par laser. Le laser utilisé possède les caractéristiques suivantes: énergie de 2J, durée d'impulsion de 7ns et taux de répétition de 10Hz. La cible est composée d'étain supporté par un film de mylar. Nous présentons ici les diagnostics développés pour la caractérisation de cette source ainsi que les derniers résultats obtenus.

  5. Laser Induced Desorption Time of Flight Mass Spectrometer Analysis of Adsorbed Contaminants on Vacuum Ultraviolet Lithography Optic Materials

    DTIC Science & Technology

    2004-02-01

    particles or an energy transfer medium absorbed under and around the particles. In the first case, the substrate absorbs the laser energy and causes rapid...when the same areas were reirradiated later. They also observed large site-to-site variation of desorbed fluence from the same sample and under the...efficiency. O. Kreitschitz et al. used TOF-MS to conduct LID of SrF2 , CaF2 and MgO2 to investigate the dependence of yield and kinetic energies of

  6. Initial velocities of positive and negative protein molecule-ions produced in matrix-assisted ultraviolet laser desorption using a liquid matrix

    NASA Astrophysics Data System (ADS)

    Dominic Chan, T.-W.; Thomas, Ioan; Colburn, A. W.; Derrick, Peter J.

    1994-06-01

    The initial axial velocities for the positive and negative cytochrome c molecule-ions desorbed from a liquid matrix (3-nitro-benzyl alcohol) using a 17 ns ultraviolet laser (266 nm) have been determined. The method employed was based upon measurement of ion flight times through a field-free path co-axial with the ion optical axis. The possible interferences, such as energy deficits, due to the presence of electric fields were avoided by using a grid-electrode placed at a very short distance from the sample stage. The potential of this electrode was maintained at the same potential as the sample stage, thereby creating a narrow field-free region within which ion generation took place. Systematic variations of the potential at a second grid-electrode caused a gradual shift of the ion flight times, which could be related to the initial ion velocities. The ion velocities were obtained by correlating the measured time-shifts with values from theoretical analysis. The positive and negative molecule-ions were found to have axial velocities of 840±70 and 750±40 ms -1, respectively.

  7. Measurement of H and H/sub 2/ populations in-situ in a low-temperature plasma by vacuum-ultraviolet laser-absorption spectroscopy

    SciTech Connect

    Schlachter, A.S.; Young, A.T.; Stutzin, G.C.; Stearns, J.W.; Doebele, H.G.; Leung, K.N.; Kunkel, W.B.

    1988-12-01

    A new technique, vacuum-ultraviolet laser-absorption spectroscopy, has been developed to quantitatively determine the absolute density of H and H/sub 2/ within a plasma. The technique is particularly well suited to measurement in a plasma, where high charged particle and photon background complicate other methods of detection. The high selectivity and sensitivity of the technique allows for the measurement of the rotational-vibrational state distribution of H/sub 2/ as well as the translational temperature of the atoms and molecules. The technique has been used to study both pulsed and continuous H/sup /minus// ion-source plasma discharges. H/sub 2/ state distributions in a multicusp ''volume'' H/sup /minus// ion- source plasma show a high degree of internal excitation, with levels up to v = 5 and J = 8 being observed. The method is applicable for a very wide range of plasma conditions. Emission measurements from excited states of H are also reported. 17 refs., 9 figs.

  8. Direct photo-etching of poly(methyl methacrylate) using focused extreme ultraviolet radiation from a table-top laser-induced plasma source

    SciTech Connect

    Barkusky, Frank; Peth, Christian; Bayer, Armin; Mann, Klaus

    2007-06-15

    In order to perform material interaction studies with intense extreme ultraviolet (EUV) radiation, a Schwarzschild mirror objective coated with Mo/Si multilayers was adapted to a compact laser-based EUV plasma source (pulse energy 3 mJ at {lambda}=13.5 nm, plasma diameter {approx}300 {mu}m). By 10x demagnified imaging of the plasma a pulse energy density of {approx}75 mJ/cm{sup 2} at a pulse length of 6 ns can be achieved in the image plane of the objective. As demonstrated for poly(methyl methacrylate) (PMMA), photoetching of polymer surfaces is possible at this EUV fluence level. This paper presents first results, including a systematic determination of PMMA etching rates under EUV irradiation. Furthermore, the contribution of out-of-band radiation to the surface etching of PMMA was investigated by conducting a diffraction experiment for spectral discrimination from higher wavelength radiation. Imaging of a pinhole positioned behind the plasma accomplished the generation of an EUV spot of 1 {mu}m diameter, which was employed for direct writing of surface structures in PMMA.

  9. Infrared-vacuum ultraviolet pulsed field ionization-photoelectron study of C2H4(+) using a high-resolution infrared laser.

    PubMed

    Xing, Xi; Reed, Beth; Bahng, Mi-Kyung; Ng, C Y

    2008-03-27

    The infrared (IR)-vacuum ultraviolet (VUV)-pulsed field ionization-photoelectron (IR-VUV-PFI-PE) spectrum for C2H4(X1A(g), v11 = 1, N'(Ka'Kc') = 3(03)) in the VUV range of 83,000-84,800 cm(-1) obtained using a single mode infrared laser revealed 24 rotationally resolved vibrational bands for the ion C2H4(+)(X2B(3u)) ground state. The frequencies and symmetry of the vibrational bands thus determined, together with the anharmonic frequency predictions calculated at the CCSD(T)/aug-cc-pVQZ level, have allowed the unambiguous assignment of these vibrational bands. These bands are mostly combination bands. The measured frequencies of these bands yield the fundamental frequencies for v8+ = 1103 +/- 10 cm(-1) and v10+ = 813 +/- 10 cm(-1) of C2H4(+)(X2B(3u)), which have not been determined previously. The present IR-VUV-PFI-PE study also provides truly rovibrationally selected and resolved state-to-state cross sections for the photoionization transitions C2H4(X1A(g); v11, N'(Ka'Kc')) --> C2H4(+)(X2B(3u); vi+, N+(Ka+Kc+)), where N'(Ka'Kc') denotes the rotational level of C2H4(X1A(g); v11), and vi+ and N+(Ka+Kc+) represent the vibrational and rotational states of the cation.

  10. The use of laser-induced fluorescence or ultraviolet detectors for sensitive and selective analysis of tobramycin or erythropoietin in complex samples

    NASA Astrophysics Data System (ADS)

    Ahmed, Hytham M.; Ebeid, Wael B.

    2015-05-01

    Complex samples analysis is a challenge in pharmaceutical and biopharmaceutical analysis. In this work, tobramycin (TOB) analysis in human urine samples and recombinant human erythropoietin (rhEPO) analysis in the presence of similar protein were selected as representative examples of such samples analysis. Assays of TOB in urine samples are difficult because of poor detectability. Therefore laser induced fluorescence detector (LIF) was combined with a separation technique, micellar electrokinetic chromatography (MEKC), to determine TOB through derivatization with fluorescein isothiocyanate (FITC). Borate was used as background electrolyte (BGE) with negative-charged mixed micelles as additive. The method was successively applied to urine samples. The LOD and LOQ for Tobramycin in urine were 90 and 200 ng/ml respectively and recovery was >98% (n = 5). All urine samples were analyzed by direct injection without sample pre-treatment. Another use of hyphenated analytical technique, capillary zone electrophoresis (CZE) connected to ultraviolet (UV) detector was also used for sensitive analysis of rhEPO at low levels (2000 IU) in the presence of large amount of human serum albumin (HSA). Analysis of rhEPO was achieved by the use of the electrokinetic injection (EI) with discontinuous buffers. Phosphate buffer was used as BGE with metal ions as additive. The proposed method can be used for the estimation of large number of quality control rhEPO samples in a short period.

  11. The soft-photon approximation in infrared-laser-assisted atomic ionization by extreme-ultraviolet attosecond-pulse trains

    NASA Astrophysics Data System (ADS)

    Jiménez Galán, Álvaro; Argenti, Luca; Martín, Fernando

    2013-11-01

    We use the soft-photon approximation, formulated for finite pulses, to investigate the effects of the dressing pulse duration and intensity on simulated attosecond pump-probe experiments employing trains of attosecond extreme-ultraviolet pulses in conjunction with an IR probe pulse. We illustrate the validity of the approximation by comparing the modelled photoelectron distributions for the helium atom, in the photon energy region close to the N = 2 threshold, to the results from the direct solution of the time-dependent Schrödinger equation for two active electrons. Even in the presence of autoionizing states, the model accurately reproduces most of the background features of the ab initio photoelectron spectrum in the 1s channel. A splitting of the photoelectron harmonic signal along the polarization axis, in particular, is attributed to the finite duration of the probe pulse. Furthermore, we study the dependence of the sideband integrated signal on the pump-probe time delay for increasing IR field strengths. Starting at IR intensities of the order of ˜ 1 TW cm-2, overtones in the sideband oscillations due to the exchange of three or more IR photons start to appear. We derive an analytical expression in the frequency-comb limit of the soft-photon model for the amplitude of all the sideband frequency components and show that these amplitudes oscillate as a function of the intensity of the IR field. In particular, we predict that the amplitude of the fundamental component with frequency 2ωIR, on which the rabitt optical reconstruction technique is based, changes sign periodically.

  12. Numerical and theoretical study of the generation of extreme ultraviolet radiation by relativistic laser interaction with a grating

    SciTech Connect

    Lavocat-Dubuis, X.; Matte, J.-P.

    2010-09-15

    The generation of harmonics by the interaction of a femtosecond, relativistic intensity laser pulse with a grating of subwavelength periodicity was studied numerically and theoretically. For normal incidence, strong, coherent emission at the wavelength of the grating period and its harmonics is obtained, nearly parallel to the target surface, due to relativistic electron bunches emanating from each protuberance. For oblique incidence (30 deg.), only even harmonics of the grating periodicity are seen, but with an even higher intensity. This is due to constructive interference of the emission from the grating protuberances. The emission along the grating surface is composed of trains of attosecond pulses; therefore there is no need to use a filter. An efficiency greater than 10{sup -4} is obtained for the 24th harmonic. The conversion efficiency is fairly constant when the similarity parameter S=n{sub e}/(a{sub 0}n{sub c})({proportional_to}n{sub e{lambda}L}/I{sub L}{sup 1/2}) is held fixed, and is optimum when S{approx_equal}4. Here, n{sub e} and n{sub c} are the electron density and the critical density; a{sub 0}=eE{sub L}/(m{sub e{omega}L}c) is the quiver momentum in the laser field E{sub L} normalized to m{sub e}c.

  13. Transient absorption and luminescence spectra of K9 glass at sub-damage site by ultraviolet laser irradiation

    NASA Astrophysics Data System (ADS)

    Zhang, Z.; Huang, J.; Geng, F.; Zhou, X. Y.; Feng, S. Q.; Cheng, X. L.; Jiang, X. D.; Wu, W. D.; Zheng, W. G.; Tang, Y. J.

    2014-01-01

    Transient absorption and luminescence spectra at sub-damage site of K9 glass by laser irradiation at 355 nm are presented. The dependence of transient absorption on laser energy and number of pulses was investigated. As the energy density increases to 2.54 and 3.18 J/cm2, the transient absorption intensity reaches to about 0.20 range from 400 to 480 nm. With the increase of number of pulses the process of residual absorption appears, which can be used to explain the fatigue effect of K9 glass. The defects in K9 glass were investigated by fluorescence and Raman spectra. The fluorescence band centered at about 410 nm is attributed to oxygen deficiency centers. The mechanism of two-photon ionization plays a critical role at sub-damage site. Compared to the Raman spectra of pristine site, intensity of Raman spectra is very high at a lower energy density, while it decreased at a higher energy density.

  14. Creation of carbon onions and coils at low temperature in near-critical benzene irradiated with an ultraviolet laser

    NASA Astrophysics Data System (ADS)

    Fukuda, Takahiro; Watabe, Nami; Whitby, Raymond; Maekawa, Toru

    2007-10-01

    Gas-liquid coexistence curves terminate at their critical points, where second-order phase transitions occur. The specific heat and compressibility increase greatly as the fluid systems approach their critical points. As a result, thermal diffusion is suppressed and the perturbations of the temperature, pressure and density propagate as acoustic waves. In this paper, we irradiate near-critical benzene with a laser beam of 266 nm in wavelength, the energy flux of which is 1.3 and 3.9 mW mm-2, and show that benzene is dissociated and various carbon nano/microstructures such as carbon onions and coils are created. Carbon onions are produced in both subcritical (200 °C) and supercritical (290 °C) benzene, whereas carbon coils are produced on an alloy catalyst composed of (Fe:Cr:Ni = 74:18:8) in supercritical benzene irradiated with a laser beam of 3.9 mW mm-2. The operational temperature of the present method is much lower than that used in conventional carbon structure synthesizing methods and a large number of carbon structures, such as carbon onions and coils, are produced in supercritical benzene.

  15. Lasers.

    ERIC Educational Resources Information Center

    Schewe, Phillip F.

    1981-01-01

    Examines the nature of laser light. Topics include: (1) production and characteristics of laser light; (2) nine types of lasers; (3) five laser techniques including holography; (4) laser spectroscopy; and (5) laser fusion and other applications. (SK)

  16. Long-Pulse Relativistic Electron Beam Generation and Propagation in Gases and in Ultraviolet Laser Ionized Channels.

    NASA Astrophysics Data System (ADS)

    Lucey, Robert Francis, Jr.

    1988-12-01

    Experiments on the propagation of relativistic electron beams (REB) in the ion-focus regime (IFR) are described. A novel feature of the experiments is the long -pulse nature of the electron beam from the Michigan Electron Long Beam Accelerator (MELBA), a Marx generator with voltage compensation (1 MV, 10 kA, 1 microsecond). The REB is extracted from the diode through a 2.5 cm diameter aperture. A cold cathode is used. To reduce voltage droop from diode gap closure, anode-cathode spacings >7 cm are used. A 7.6 cm dia. cotton velvet cathode provides 300 A of injected current for 800 ns before a rapid increase in injected current, attributed to diode instability. Loss of REB transport accompanies this current increase. Conclusions drawn from the empirical diode study are: (1) successful generation of microsecond electron beams without magnetic insulation from cold cathodes requires diode spacing of ~10 cm, (2) cotton velvet gives improved beam quality over carbon fiber "brush" cathodes, (3) velvet cathodes have slower closure velocity of the cathode plasma. In the IFR regime partial neutralization of the space-charge of an REB by an ion background with the magnetic pinch force of the REB current achieves radial force balance. Experiments are performed in neutral gas, and in diethylaniline (DEA), preionized with a KrF laser. A pressure window for propagation is observed. For helium this window is 50-300 mtorr. The longest propagated pulse is 300 ns with a peak transported efficiency of 80%. In air the pressure window is 5-75 mtorr with similar efficiency. In DEA, fractional ionization of 0.004 has been achieved at a laser fluence of 10 mJ per square cm. To provide sufficient preionization for propagation, pressures where impact ionization is not negligible are required. A pressure window for propagation is again observed. For the current density and laser fluence in this experiment the pressure window is 0.2-2 mTorr. Within the pressure window instability, of the REB

  17. Matrix and energy effects during in-situ determination of Cu isotope ratios by ultraviolet-femtosecond laser ablation multicollector inductively coupled plasma mass spectrometry

    NASA Astrophysics Data System (ADS)

    Lazarov, Marina; Horn, Ingo

    2015-09-01

    Copper isotope compositions in Cu-bearing metals and minerals have been measured by deep (194 nm) ultraviolet femtosecond laser ablation multi-collector inductively coupled plasma mass spectrometry (UV-fsLA-MC-ICP-MS). Pure Cu-metal, brass, and several Cu-rich minerals (chalcopyrite, enargite, covellite, malachite and cuprite) have been investigated. A long-term reproducibility of better than 0.08‰ at the 95% confidence limit on the NIST SRM 976 (National Institute of Standards and Technology) Cu-metal standard has been achieved with this technique. The δ65Cu values for all samples have been calculated by standard-sample-standard bracketing with NIST SRM 976. All analyses have been carried out using Ni as a mass discrimination monitor added by nebulization prior to entering the plasma torch. For further verification samples have been analysed by conventional solution nebulization MC-ICP-MS and the results obtained have been compared with those from UV-fsLA-MC-ICP-MS. Several potential matrix-induced molecular interferences on the mineral copper isotope ratio, such as (32S33S)+ and (32S-16O17O)+ do not affect the Cu isotope measurements on sulfides, while hydrides, such as Zn-H or doubly-charged Sn2 + that interfere Ni isotopes can be either neglected or stripped by calculation. Matrix independent Cu-isotope measurements are sensitive to the energy density (fluence) applied onto the sample and can produce artificial shifts in the obtained δ65Cu values which are on the order of 3‰ for Cu-metal, 0.5‰ for brass and 0.3‰ for malachite when using energy density of up to 2 J/cm2 for ablation. A positive correlation between applied energy density and the magnitude of the isotope ratio shift has been found in the energy density range from 0.2 to 1.3 J/cm2 which is below the ablation threshold for ns-laser ablation. The results demonstrate that by using appropriate low fluence it is possible to measure Cu isotopic ratios in native copper and Cu-bearing sulfides

  18. Infrared spectra and ultraviolet-tunable laser induced photochemistry of matrix-isolated phenol and phenol-d{sub 5}

    SciTech Connect

    Giuliano, Barbara Michela; Reva, Igor; Fausto, Rui; Lapinski, Leszek

    2012-01-14

    Monomers of phenol and its ring-perdeuterated isotopologue phenol-d{sub 5} were isolated in argon matrices at 15 K. The infrared (IR) spectra of these species were recorded and analyzed. In situ photochemical transformations of phenol and phenol-d{sub 5} were induced by tunable UV laser light. The photoproducts have been characterized by IR spectroscopy supported by theoretical calculations of the infrared spectra. The primary product photogenerated from phenol was shown to be the phenoxyl radical. The analysis of the progress of the observed phototransformations led to identification of 2,5-cyclohexadienone as one of the secondary photoproducts. Spectral indications of other secondary products, such as the Dewar isomer and the open-ring ketene, were also detected. Identification of the photoproducts provided a guide for the interpretation of the mechanisms of the observed photoreactions.

  19. Fundamental study on reaction mechanisms in chemically amplified extreme ultraviolet resists by using 61nm free-electron laser

    NASA Astrophysics Data System (ADS)

    Okamoto, Kazumasa; Kozawa, Takahiro; Hatsui, Takaki; Tajima, Yasuharu; Oikawa, Keita; Nagasono, Mitsuru; Kameshima, Takashi; Togashi, Tadashi; Tono, Kensuke; Yabashi, Makina; Kimura, Hiroaki; Senba, Yasunori; Ohashi, Haruhiko; Sumiyoshi, Takashi

    2011-04-01

    For chemically amplified EUV resists, secondary electrons derived from ionization events play a critical role in the sensitization of acid generators. In this study, we show the dependence of acid generation efficiency on dose rate (fluence per pulse duration) by using 61 nm free-electron laser (FEL) light irradiation. The wavelength of 61 nm (20.3 eV) is applied because single incident photon induces only single ionization event, in contrast to the 13.4 nm EUV photon that induces 4.2 ionization events on average. The acid yield efficiency has enhances with decreasing the dose rate. It is suggested that high density ionization enhances the multiple spur effect.

  20. Note: study of extreme ultraviolet and soft x-ray emission of metal targets produced by laser-plasma-interaction.

    PubMed

    Mantouvalou, I; Jung, R; Tuemmler, J; Legall, H; Bidu, T; Stiel, H; Malzer, W; Kanngiesser, B; Sandner, W

    2011-06-01

    Different metal targets were investigated as possible source material for tailored laser-produced plasma-sources. In the wavelength range from 1 to 20 nm, x-ray spectra were collected with a calibrated spectrometer with a resolution of λ/Δλ = 150 at 1 nm up to λ/Δλ = 1100 at 15 nm. Intense line emission features of highly ionized species as well as continuum-like spectra from unresolved transitions are presented. With this knowledge, the optimal target material can be identified for the envisioned application of the source in x-ray spectrometry on the high energy side of the spectra at about 1 keV. This energy is aimed for because 1 keV-radiation is ideally suited for L-shell x-ray spectroscopy with nm-depth resolution.

  1. ZnO films grown by pulsed-laser deposition on soda lime glass substrates for the ultraviolet inactivation of Staphylococcus epidermidis biofilms

    PubMed Central

    Mosnier, Jean-Paul; O’Haire, Richard J; McGlynn, Enda; Henry, Martin O; McDonnell, Stephen J; Boyle, Maria A; McGuigan, Kevin G

    2009-01-01

    We found that a ZnO film of 2 μm thickness which was laser-deposited at room temperature onto a plain soda lime glass substrate, exhibits notable antibacterial activity against a biofilm of Staphylococcus epidermidis when back-illuminated by a UVA light source with a peak emission wavelength of about 365 nm. X-ray diffraction (XRD), scanning electron microscopy (SEM), atomic force microscopy (AFM), UV-visible absorption spectroscopy, Raman spectroscopy and x-ray photoemission spectroscopy (XPS) were used to characterize the ZnO films before and after the interactions with the biofilm and the ultraviolet light, respectively. The as-deposited film was highly textured with the wurtzite (0002) in-plane orientation (c-axis perpendicular to ZnO surface) and had a surface rms roughness of 49.7 nm. In the as-deposited film, the Zn to O ratio was 1 to 0.95. After the UV and biofilm treatments, the ZnO film surface had become rougher (rms roughness 68.1 nm) and presented uniform micron-sized pitting randomly distributed, while the zinc to oxygen ratio had become 1 to 2.2. In this case, both the UV-visible and Raman spectra pointed to degradation of the structural quality of the material. On the strength of these data, we propose a model for the mediation of the bactericidal activity in which the photogeneration of highly oxidizing species and the presence of active surface defect sites both play an important role. This study is of particular interest for the acute problem of disinfection of pathogenic biofilms which form on medical device/implant surfaces. PMID:27877303

  2. Infrared-vacuum ultraviolet-pulsed field ionization-photoelectron study of CH(3)I(+) using a high-resolution infrared laser.

    PubMed

    Xing, Xi; Reed, Beth; Bahng, Mi-Kyung; Baek, S-J; Wang, Peng; Ng, C Y

    2008-03-14

    By using a high-resolution single mode infrared-optical parametric oscillator laser to prepare CH(3)I in single (J,K) rotational levels of the nu(1) (symmetric C-H stretching) =1 vibrational state, we have obtained rovibrationally resolved infrared-vacuum ultraviolet-pulsed field ionization-photoelectron (IR-VUV-PFI-PE) spectra of the CH(3)I(+)(X(2)E(32);nu(1)(+)=1;J(+),P(+)) band, where (J,K) and (J(+),P(+)) represent the respective rotational quantum numbers of CH(3)I and CH(3)I(+). The IR-VUV-PFI-PE spectra observed for K=0 and 1 are found to have nearly identical structures. The IR-VUV-PFI-PE spectra for (J,K)=(5,0) and (7, 0) are also consistent with the previous J-selected IR-VUV-PFI-PE measurements. The analysis of these spectra indicates that the photoionization cross section of CH(3)I depends strongly on DeltaJ(+)=J(+)-J: but not on J and K. This observation lends strong support for the major assumption adopted for the semiempirical simulation scheme, which has been used for the simulation of the origin bands observed in VUV-PFI-PE study of polyatomic molecules. Using the state-to-state photoionization cross sections determined in this IR-VUV study, we have obtained excellent simulation of the VUV-PFI-PE origin band of CH(3)I(+)(X (2)E(32)), yielding more precise IE(CH(3)I)=76 930.7+/-0.5 cm(-1) and nu(1) (+)=2937.8+/-0.2 cm(-1).

  3. Direct measurement of Ar diffusion profiles in a gem-quality Madagascar K-feldspar using the ultra-violet laser ablation microprobe (UVLAMP)

    NASA Astrophysics Data System (ADS)

    Wartho, Jo-Anne; Kelley, Simon P.; Brooker, Richard A.; Carroll, Mike R.; Villa, Igor M.; Lee, Martin R.

    1999-06-01

    Controversy surrounding the mechanisms and controls on argon diffusion in K-feldspar has led us to undertake direct diffusion measurements on a crystal with simple microtextures, over a range of temperatures. Measurements of argon diffusion profiles in a gem-quality iron-rich orthoclase heated in a cold seal apparatus, have been undertaken in situ using an ultra-violet laser ablation microprobe (UVLAMP) technique. The results agree very closely with the previously determined bulk values for Benson Mines orthoclase (activation energy ( E)=43.8±1 kcal mol -1) and vacuum furnace cycle-heating studies of K-feldspars ( E=46±6 kcal mol -1). However, instead of defining a single activation energy ( E) and diffusion coefficient ( Do), the data yield two sets of parameters: a low-temperature (550-720°C) array with an E of 47.2±2.5 kcal mol -1 (198.2±10.5 kJ mol -1) and a Do of 0.0374 +0.1123-0.0281 cm 2 s -1, and a high-temperature (725-1019°C) array with an E of 63.8±3.4 kcal mol -1 (268.0±14.3 kJ mol -1) and a Do of 55.0 +225.5-44.2 cm 2 s -1. The new results closely reproduce two sets of apparent activation energies previously measured in cycle-heating studies of Madagascar K-feldspar (40±3 and 57±3 kcal mol -1). Previous interpretations of the two arrays have included multiple domains with variable activation energies and fast track diffusion. However, the UV depth profile analyses indicate simple diffusion to the grain surface and importantly, diffusion radii calculated by combining the UVLAMP and cycle-heating data, are the same as the physical grain sizes used in the experiments, around 1 mm. Vacuum furnace stepped heating experiments on slowly cooled K-feldspars have been interpreted as showing diffusion radii of around 6 μm and indicate complex populations of sub-grains. This study indicates that Madagascar K-feldspar and thus probably all gem-quality K-feldspars act as single diffusion domains and that short-circuit (or pipe) diffusion was not an

  4. Compact, passively Q-switched, all-solid-state master oscillator-power amplifier-optical parametric oscillator (MOPA-OPO) system pumped by a fiber-coupled diode laser generating high-brightness, tunable, ultraviolet radiation.

    PubMed

    Peuser, Peter; Platz, Willi; Fix, Andreas; Ehret, Gerhard; Meister, Alexander; Haag, Matthias; Zolichowski, Paul

    2009-07-01

    We report on a compact, tunable ultraviolet laser system that consists of an optical parametric oscillator (OPO) and a longitudinally diode-pumped Nd:YAG master oscillator-power amplifier (MOPA). The pump energy for the whole laser system is supplied via a single delivery fiber. Nanosecond pulses are produced by an oscillator that is passively Q-switched by a Cr(4+):YAG crystal. The OPO is pumped by the second harmonic of the Nd:YAG MOPA. Continuously tunable radiation is generated by an intracavity sum-frequency mixing process within the OPO in the range of 245-260 nm with high beam quality. Maximum pulse energies of 1.2 mJ were achieved, which correspond to an optical efficiency of 3.75%, relating to the pulse energy of the MOPA at 1064 nm.

  5. Laser-Bioplasma Interaction: The Epilepsy-Topion-Bioplasma, (the Seizure Onset Area) Upon the Action of the Optical-Fiber-Guided Multi-Ultraviolet-Photon Beams

    NASA Astrophysics Data System (ADS)

    Stefan, V. Alexander

    2016-10-01

    The ultraviolet photons may control the imbalance of sodium and potassium ions in the brain bioplasma and, consequently, may prove to be efficient in the prevention of epileptic seizures. A novel method is based on the multi-ultraviolet-photon beam interaction with the epilepsy-topion-bioplasma, (nonlinear coupling of an ultra high frequency mode to the brain beta phonons). It is hypothesized that epilepsy is a chaotic-dynamics phenomenon: small electrical changes in the epilepsy-topion-bioplasma lead, (within the 10s of milliseconds), to the onset of chaos, (seizure-excessive electrical discharge), and subsequent cascading into adjacent areas.

  6. Ultraviolet fluorescence monitor

    SciTech Connect

    Hargis, P.J. Jr.; Preppernau, B.L.; Aragon, B.P.

    1997-05-01

    A multispectral ultraviolet (UV) fluorescence imaging fluorometer and a pulsed molecular beam laser fluorometer were developed to detect volatile organic compounds of interest in environmental monitoring and drug interdiction applications. The UV fluorescence imaging fluorometer is a relatively simple instrument which uses multiple excitation wavelengths to measure the excitation/emission matrix for irradiated samples. Detection limits in the high part-per-million to low part-per-million range were measured for a number of volatile organic vapors in the atmosphere. Detection limits in the low part-per-million range were obtained using cryogenic cooling to pre-concentrate unknown samples before introducing them into the imaging fluorometer. A multivariate analysis algorithm was developed to analyze the excitation/emission matrix and used to determine the relative concentrations of species in computer synthesized mixtures containing up to five organic compounds. Analysis results demonstrated the utility of multispectral UV fluorescence in analytical measurements. A transportable UV fluorescence imaging fluorometer was used in two field tests. Field test results demonstrated that detection limits in the part-per-billion range were needed to reliably identify volatile organic compounds in realistic field test measurements. The molecular beam laser fluorometer, a more complex instrument with detection limits in the part-per-billion to part-per-trillion range, was therefore developed to satisfy detection sensitivity requirements for field test measurements. High-resolution spectroscopic measurements made with the molecular beam laser fluorometer demonstrated its utility in identifying volatile organic compounds in the atmosphere.

  7. Extreme ultraviolet lithography machine

    DOEpatents

    Tichenor, Daniel A.; Kubiak, Glenn D.; Haney, Steven J.; Sweeney, Donald W.

    2000-01-01

    An extreme ultraviolet lithography (EUVL) machine or system for producing integrated circuit (IC) components, such as transistors, formed on a substrate. The EUVL machine utilizes a laser plasma point source directed via an optical arrangement onto a mask or reticle which is reflected by a multiple mirror system onto the substrate or target. The EUVL machine operates in the 10-14 nm wavelength soft x-ray photon. Basically the EUV machine includes an evacuated source chamber, an evacuated main or project chamber interconnected by a transport tube arrangement, wherein a laser beam is directed into a plasma generator which produces an illumination beam which is directed by optics from the source chamber through the connecting tube, into the projection chamber, and onto the reticle or mask, from which a patterned beam is reflected by optics in a projection optics (PO) box mounted in the main or projection chamber onto the substrate. In one embodiment of a EUVL machine, nine optical components are utilized, with four of the optical components located in the PO box. The main or projection chamber includes vibration isolators for the PO box and a vibration isolator mounting for the substrate, with the main or projection chamber being mounted on a support structure and being isolated.

  8. The role of film interfaces in near-ultraviolet absorption and pulsed-laser damage in ion-beam-sputtered coatings based on HfO2/SiO2 thin-film pairs

    DOE PAGES

    Ristau, Detlev; Papernov, S.; Kozlov, A. A.; ...

    2015-11-23

    The role of thin-film interfaces in the near-ultraviolet absorption and pulsed-laser–induced damage was studied for ion-beam–sputtered and electron-beam–evaporated coatings comprised from HfO2 and SiO2 thin-film pairs. To separate contributions from the bulk of the film and from interfacial areas, absorption and damage-threshold measurements were performed for a one-wave (355-nm wavelength) thick, HfO2 single-layer film and for a film containing seven narrow HfO2 layers separated by SiO2 layers. The seven-layer film was designed to have a total optical thickness of HfO2 layers, equal to one wave at 355 nm and an E-field peak and average intensity similar to a single-layer HfO2more » film. Absorption in both types of films was measured using laser calorimetry and photothermal heterodyne imaging. The results showed a small contribution to total absorption from thin-film interfaces, as compared to HfO2 film material. The relevance of obtained absorption data to coating near-ultraviolet, nanosecond-pulse laser damage was verified by measuring the damage threshold and characterizing damage morphology. The results of this study revealed a higher damage resistance in the seven-layer coating as compared to the single-layer HfO2 film in both sputtered and evaporated coatings. Here, the results are explained through the similarity of interfacial film structure with structure formed during the co-deposition of HfO2 and SiO2 materials.« less

  9. The role of film interfaces in near-ultraviolet absorption and pulsed-laser damage in ion-beam-sputtered coatings based on HfO2/SiO2 thin-film pairs

    SciTech Connect

    Ristau, Detlev; Papernov, S.; Kozlov, A. A.; Oliver, J. B.; Smith, C.; Jensen, L.; Gunster, S.; Madebach, H.

    2015-11-23

    The role of thin-film interfaces in the near-ultraviolet absorption and pulsed-laser–induced damage was studied for ion-beam–sputtered and electron-beam–evaporated coatings comprised from HfO2 and SiO2 thin-film pairs. To separate contributions from the bulk of the film and from interfacial areas, absorption and damage-threshold measurements were performed for a one-wave (355-nm wavelength) thick, HfO2 single-layer film and for a film containing seven narrow HfO2 layers separated by SiO2 layers. The seven-layer film was designed to have a total optical thickness of HfO2 layers, equal to one wave at 355 nm and an E-field peak and average intensity similar to a single-layer HfO2 film. Absorption in both types of films was measured using laser calorimetry and photothermal heterodyne imaging. The results showed a small contribution to total absorption from thin-film interfaces, as compared to HfO2 film material. The relevance of obtained absorption data to coating near-ultraviolet, nanosecond-pulse laser damage was verified by measuring the damage threshold and characterizing damage morphology. The results of this study revealed a higher damage resistance in the seven-layer coating as compared to the single-layer HfO2 film in both sputtered and evaporated coatings. Here, the results are explained through the similarity of interfacial film structure with structure formed during the co-deposition of HfO2 and SiO2 materials.

  10. Method for extreme ultraviolet lithography

    DOEpatents

    Felter, T. E.; Kubiak, G. D.

    2000-01-01

    A method of producing a patterned array of features, in particular, gate apertures, in the size range 0.4-0.05 .mu.m using projection lithography and extreme ultraviolet (EUV) radiation. A high energy laser beam is used to vaporize a target material in order to produce a plasma which in turn, produces extreme ultraviolet radiation of a characteristic wavelength of about 13 nm for lithographic applications. The radiation is transmitted by a series of reflective mirrors to a mask which bears the pattern to be printed. The demagnified focused mask pattern is, in turn, transmitted by means of appropriate optics and in a single exposure, to a substrate coated with photoresists designed to be transparent to EUV radiation and also satisfy conventional processing methods.

  11. Method for extreme ultraviolet lithography

    DOEpatents

    Felter, T. E.; Kubiak, Glenn D.

    1999-01-01

    A method of producing a patterned array of features, in particular, gate apertures, in the size range 0.4-0.05 .mu.m using projection lithography and extreme ultraviolet (EUV) radiation. A high energy laser beam is used to vaporize a target material in order to produce a plasma which in turn, produces extreme ultraviolet radiation of a characteristic wavelength of about 13 nm for lithographic applications. The radiation is transmitted by a series of reflective mirrors to a mask which bears the pattern to be printed. The demagnified focused mask pattern is, in turn, transmitted by means of appropriate optics and in a single exposure, to a substrate coated with photoresists designed to be transparent to EUV radiation and also satisfy conventional processing methods.

  12. Picosecond pulses in deep ultraviolet (257.5 nm and 206 nm) and mid-IR produced by a high-power 100 kHz solid-state thin-disk laser

    NASA Astrophysics Data System (ADS)

    Turčičová, Hana; Novák, Ondřej; Smrž, Martin; Miura, Taisuke; Endo, Akira; Mocek, TomáÅ.¡

    2016-04-01

    We report on the generation of picosecond deep ultraviolet pulses at 257.5 nm and 206 nm produced as the fourth and fifth harmonic frequencies of the diode-pumped Yb:YAG thin-disk laser at the fundamental wavelength of 1030 nm. We present a proposal for a picosecond pulse mid-IR source tunable between 2 and 3 μm. The laser at the fundamental wavelength is based on a chirped-pulse amplification of pulses of a sub-ps laser oscillator in a regenerative amplifier with a thin-disk active medium. The diode pumping at the zero phonon line is used. The output beam is close to the fundamental spatial mode and the pulses are characterized by a 100 kHz repetition frequency, less than 4 ps pulse duration and <=1 mJ pulse energy. The fundamental beam is split and the main part is first frequency doubled in an LBO crystal. Subsequently the fourth harmonic frequency (257.5 nm) is produced by frequency doubling of the second harmonic frequency in BBO/CLBO crystals. The remaining part of the fundamental beam is summed with the fourth harmonic beam in the 1ω+4ω quantum reaction in a further CLBO crystal for the fifth harmonic frequency (206 nm) production. The design for the generation of the mid-IR wavelengths is based on the optical parametric generation and amplification. The first stage contains a temperature tuned PPLN, the following amplification stages are based on KTA crystals tuned by angle. Picosecond output pulses tunable between 2 and 3 μm at an average power of 10 W are proposed.

  13. Molecular photoelectron angular distribution rotations in multi-photon resonant ionization of H{sub 2}{sup +} by circularly polarized ultraviolet laser pulses

    SciTech Connect

    Yuan, Kai-Jun Chelkowski, Szczepan; Bandrauk, André D.

    2015-04-14

    We study effects of pulse durations on molecular photoelectron angular distributions (MPADs) in ultrafast circular polarization ultraviolet resonant ionization processes. Simulations performed on aligned H{sub 2}{sup +} by numerically solving time dependent Schrödinger equations show rotations of MPADs with respect to the molecular symmetry axes. It is found that in multi-photon resonant ionization processes, rotation angles are sensitive to pulse durations, which we attribute to the coherent resonant excitation between the ground state and the intermediate excited electronic state induced by Rabi oscillations. Multi-photon nonresonant and single photon ionization processes are simulated and compared which exhibit a constant rotation angle. An asymmetry parameter is introduced to describe the pulse duration sensitivity by perturbation theory models. Influence of pulse frequency detunings on MPADs is also investigated where oscillations of rotations are absent at long pulse durations due to nonresonance excitation.

  14. Ultraviolet Rayleigh Scatter Imaging for Spatial Temperature Profiles in Atmospheric Microdischarges

    DTIC Science & Technology

    2014-09-01

    laser manufactured by Quantel. This Brilliant laser has a specification output of 330 mJ per pulse at its fundamental 1064 nm, 165 mJ per pulse at...using Rayleigh scattering of a pulsed ultraviolet laser . Scattering intensity images were used to generate a radial profile of translational...agreement with the Rayleigh translational temperature profiles. 15. SUBJECT TERMS ultraviolet laser , Rayleigh scatter microdischarge, translational

  15. Development of Interference Lithography Capability Using a Helium Cadmium Ultraviolet Multimode Laser for the Fabrication of Sub-Micron-Structured Optical Materials

    DTIC Science & Technology

    2011-03-01

    Page 2.20 Transmission Spectra of CdSe and Polymer Photonic Crystals ........................................... 36 2.21 Laser...IL, Divliansky et al. fabricated a 2D CdSe PC by electrodeposition of CdSe in a polymer template. The PC was synthesized from an initial development...scaled for visible wavelengths. The scanning electron microscope (SEM) images of the resulting hexagonal array of PR columns and CdSe holes are shown

  16. Defect-tolerant extreme ultraviolet nanoscale printing.

    PubMed

    Urbanski, L; Isoyan, A; Stein, A; Rocca, J J; Menoni, C S; Marconi, M C

    2012-09-01

    We present a defect-free lithography method for printing periodic features with nanoscale resolution using coherent extreme ultraviolet light. This technique is based on the self-imaging effect known as the Talbot effect, which is produced when coherent light is diffracted by a periodic mask. We present a numerical simulation and an experimental verification of the method with a compact extreme ultraviolet laser. Furthermore, we explore the extent of defect tolerance by testing masks with different defect layouts. The experimental results are in good agreement with theoretical calculations.

  17. Diode-pumped continuous-wave and femtosecond Cr:LiCAF lasers with high average power in the near infrared, visible and near ultraviolet.

    PubMed

    Demirbas, Umit; Baali, Ilyes; Acar, Durmus Alp Emre; Leitenstorfer, Alfred

    2015-04-06

    We demonstrate continuous-wave (cw), cw frequency-doubled, cw mode-locked and Q-switched mode-locked operation of multimode diode-pumped Cr:LiCAF lasers with record average powers. Up to 2.54 W of cw output is obtained around 805 nm at an absorbed pump power of 5.5 W. Using intracavity frequency doubling with a BBO crystal, 0.9 W are generated around 402 nm, corresponding to an optical-to-optical conversion efficiency of 12%. With an intracavity birefringent tuning plate, the fundamental and frequency-doubled laser output is tuned continuously in a broad wavelength range from 745 nm to 885 nm and from 375 to 440 nm, respectively. A saturable Bragg reflector is used to initiate and sustain mode locking. In the cw mode-locked regime, the Cr:LiCAF laser produces 105-fs long pulses near 810 nm with an average power of 0.75 W. The repetition rate is 96.4 MHz, resulting in pulse energies of 7.7 nJ and peak powers of 65 kW. In Q-switched mode-locked operation, pulses with energies above 150 nJ are generated.

  18. Deep ultraviolet laser direct write for patterning sol-gel InGaZnO semiconducting micro/nanowires and improving field-effect mobility

    PubMed Central

    Lin, Hung-Cheng; Stehlin, Fabrice; Soppera, Olivier; Zan, Hsiao-Wen; Li, Chang-Hung; Wieder, Fernand; Ponche, Arnaud; Berling, Dominique; Yeh, Bo-Hung; Wang, Kuan-Hsun

    2015-01-01

    Deep-UV (DUV) laser was used to directly write indium-gallium-zinc-oxide (IGZO) precursor solution and form micro and nanoscale patterns. The directional DUV laser beam avoids the substrate heating and suppresses the diffraction effect. A IGZO precursor solution was also developed to fulfill the requirements for direct photopatterning and for achieving semi-conducting properties with thermal annealing at moderate temperature. The DUV-induced crosslinking of the starting material allows direct write of semi-conducting channels in thin-film transistors but also it improves the field-effect mobility and surface roughness. Material analysis has been carried out by XPS, FTIR, spectroscopic ellipsometry and AFM and the effect of DUV on the final material structure is discussed. The DUV irradiation step results in photolysis and a partial condensation of the inorganic network that freezes the sol-gel layer in a homogeneous distribution, lowering possibilities of thermally induced reorganization at the atomic scale. Laser irradiation allows high-resolution photopatterning and high-enough field-effect mobility, which enables the easy fabrication of oxide nanowires for applications in solar cell, display, flexible electronics, and biomedical sensors. PMID:26014902

  19. Ultraviolet laser crystallized ZnO:Al films on sapphire with high Hall mobility for simultaneous enhancement of conductivity and transparency

    SciTech Connect

    Nian, Qiong; Zhang, Martin Y.; Schwartz, Bradley D.; Cheng, Gary J.

    2014-05-19

    One of the most challenging issues in transparent conductive oxides (TCOs) is to improve their conductivity without compromising transparency. High conductivity in TCO films often comes from a high carrier concentration, which is detrimental to transparency due to free carrier absorption. Here we show that UV laser crystallization (UVLC) of aluminum-doped ZnO (AZO) films prepared by pulsed laser deposition on sapphire results in much higher Hall mobility, allowing relaxation of the constraints of the conductivity/transparency trade-off. X-ray diffraction patterns and morphological characterizations show grain growth and crystallinity enhancement during UVLC, resulting in less film internal imperfections. Optoelectronic measurements show that UVLC dramatically improves the electron mobility, while the carrier concentration decreases which in turn simultaneously increases conductivity and transparency. AZO films under optimized UVLC achieve the highest electron mobility of 79 cm{sup 2}/V s at a low carrier concentration of 7.9 × 10{sup +19} cm{sup −3}. This is realized by a laser crystallization induced decrease of both grain boundary density and electron trap density at grain boundaries. The infrared (IR) to mid-IR range transmittance spectrum shows UVLC significantly enhances the AZO film transparency without compromising conductivity.

  20. Excimer Lasers In Medicine

    NASA Astrophysics Data System (ADS)

    Tittel, Frank K.; Saidi, Iyad S.; Pettit, George H.; Wisoff, P. J.; Sauerbrey, Roland A.

    1989-06-01

    Excimer lasers emit light energy, short optical pulses at ultraviolet wavelengths, that results in a unique laser tissue interaction. This has led to an increasing number of studies into medical applications of these lasers in fields such as ophthalmology, urology, cardiology and neurology.

  1. Vacuum Ultraviolet Laser Photoion and Pulsed Field Ionization-Photoion Study of Rydberg Series of Chlorine Atoms Prepared in the 2PJ (J = 3/2 and 1/2) Fine-structure States

    NASA Astrophysics Data System (ADS)

    Yang, Lei; Gao, Hong; Zhou, Jingang; Ng, C. Y.

    2015-09-01

    We have measured the high-resolution vacuum ultraviolet (VUV) photoion (VUV-PI) and VUV pulsed-field ionization-photoion (VUV-PFI-PI) spectra of chlorine atoms (Cl) in the VUV energy range 103,580-105,600 cm-1 (12.842-13.093 eV) using a tunable VUV laser as the photoexcitation and photoionization source. Here, Cl atoms are prepared in the Cl(2P3/2) and Cl(2P1/2) fine-structure states by 193.3 nm laser photodissociation of chlorobenzene. The employment of VUV-PFI-PI detection has allowed the identification of Rydberg transitions that are not observed in VUV-PI measurements. More than 180 new Rydberg transition lines with principal quantum number up to n = 61 have been identified and assigned to members of nine Rydberg series originating from the neutral Cl(2P3/2) and Cl(2P1/2) fine-structure states. Two of these Rydberg series are found to converge to the Cl+(3P2), four to the Cl+(3P1), and three to the Cl+(3P0) ionization limits. Based on the convergence limits determined by least-squares fits of the observed Rydberg transitions to the modified Ritz formula, we have obtained a more precise ionization energy (IE) for the formation of the ionic Cl+(3P2) from the ground Cl(2P3/2) state to be 104,591.01 ± 0.13 cm-1. This is consistent with previous IE measurements, but has a smaller uncertainty. The analysis of the quantum defects obtained for the Rydberg transitions reveals that many high-n Rydberg transitions are perturbed.

  2. Ultraviolet laser desorption/ionization mass spectrometry of single-core and multi-core polyaromatic hydrocarbons under variable conditions of collisional cooling: insights into the generation of molecular ions, fragments and oligomers.

    PubMed

    Gámez, Francisco; Hortal, Ana R; Martínez-Haya, Bruno; Soltwisch, Jens; Dreisewerd, Klaus

    2014-11-01

    The ultraviolet laser desorption/ionization of polyaromatic hydrocarbons (PAHs) has been investigated under different background pressures of an inert gas (up to 1.2 mbar of N2) in the ion source of a hybrid, orthogonal-extracting time-of-flight mass spectrometer (oTOF-MS). The study includes an ensemble of six model PAHs with isolated single polyaromatic cores and four ones with multiple cross-linked aromatic and polyaromatic cores. In combination with a weak ion extraction field, the variation of the buffer gas pressure allowed to control the degree of collisional cooling of the desorbed PAHs and, thus, to modulate their decomposition into fragments. The dominant fragmentation channels observed are related to dehydrogenation of the PAHs, in most cases through the cleavage of even numbers of C-H bonds. Breakage of C-C bonds leading to the fragmentation of rings, side chains and core linkages is also observed, in particular, at low buffer gas pressures. The precise patterns of the combined fragmentation processes vary significantly between the PAHs. The highest abundances of molecular PAH ions and cleanest mass spectra were consistently obtained at the highest buffer gas pressure of 1.2 mbar. The effective quenching of the fragmentation pathways at this elevated pressure improves the sensitivity and data interpretation for analytical applications, although the fragmentation of side chains and of bonds between (poly)aromatic cores is not completely suppressed in all cases. Moreover, these results suggest that the detected fragments are generated through thermal equilibrium processes rather than as a result of rapid photolysis. This assumption is further corroborated by a laser desorption/ionization post-source decay analysis using an axial time-of-flight MS. In line with these findings, covalent oligomers of the PAHs, which are presumably formed by association of two or more dehydrogenated fragments, are detected with higher abundances at the lower buffer gas

  3. Ultraviolet photochemical reaction of [Fe(III)(C2O4)3]3− in aqueous solutions studied by femtosecond time-resolved X-ray absorption spectroscopy using an X-ray free electron laser

    PubMed Central

    Ogi, Y.; Obara, Y.; Katayama, T.; Suzuki, Y.-I.; Liu, S. Y.; Bartlett, N. C.-M.; Kurahashi, N.; Karashima, S.; Togashi, T.; Inubushi, Y.; Ogawa, K.; Owada, S.; Rubešová, M.; Yabashi, M.; Misawa, K.; Slavíček, P.; Suzuki, T.

    2015-01-01

    Time-resolved X-ray absorption spectroscopy was performed for aqueous ammonium iron(III) oxalate trihydrate solutions using an X-ray free electron laser and a synchronized ultraviolet laser. The spectral and time resolutions of the experiment were 1.3 eV and 200 fs, respectively. A femtosecond 268 nm pulse was employed to excite [Fe(III)(C2O4)3]3− in solution from the high-spin ground electronic state to ligand-to-metal charge transfer state(s), and the subsequent dynamics were studied by observing the time-evolution of the X-ray absorption spectrum near the Fe K-edge. Upon 268 nm photoexcitation, the Fe K-edge underwent a red-shift by more than 4 eV within 140 fs; however, the magnitude of the redshift subsequently diminished within 3 ps. The Fe K-edge of the photoproduct remained lower in energy than that of [Fe(III)(C2O4)3]3−. The observed red-shift of the Fe K-edge and the spectral feature of the product indicate that Fe(III) is upon excitation immediately photoreduced to Fe(II), followed by ligand dissociation from Fe(II). Based on a comparison of the X-ray absorption spectra with density functional theory calculations, we propose that the dissociation proceeds in two steps, forming first [(CO2•)Fe(II)(C2O4)2]3− and subsequently [Fe(II)(C2O4)2]2−. PMID:26798796

  4. Lasers.

    PubMed

    Passeron, T

    2012-12-01

    Lasers are a very effective approach for treating many hyperpigmented lesions. They are the gold standard treatment for actinic lentigos and dermal hypermelanocytosis, such as Ota nevus. Becker nevus, hyperpigmented mosaicisms, and lentigines can also be successfully treated with lasers, but they could be less effective and relapses can be observed. However, lasers cannot be proposed for all types of hyperpigmentation. Thus, freckles and café-au-lait macules should not be treated as the relapses are nearly constant. Due to its complex pathophysiology, melasma has a special place in hyperpigmented dermatoses. Q-switched lasers (using standard parameters or low fluency) should not be used because of consistent relapses and the high risk of post-inflammatory hyperpigmentation. Paradoxically, targeting the vascular component of the melasma lesion with lasers could have a beneficial effect. However, these results have yet to be confirmed. In all cases, a precise diagnosis of the type of hyperpigmentation is mandatory before any laser treatment, and the limits and the potential side effects of the treatment must be clearly explained to patients.

  5. [Lasers].

    PubMed

    Passeron, T

    2012-11-01

    Lasers are a very effective approach for treating many hyperpigmented lesions. They are the gold standard treatment for actinic lentigos and dermal hypermelanocytosis, such as Ota nevus. Becker nevus, hyperpigmented mosaicisms, and lentigines can also be successfully treated with lasers, but they could be less effective and relapses can be observed. However, lasers cannot be proposed for all types of hyperpigmentation. Thus, freckles and café-au-lait macules should not be treated as the relapses are nearly constant. Due to its complex pathophysiology, melasma has a special place in hyperpigmented dermatoses. Q-switched lasers (using standard parameters or low fluency) should not be used because of consistent relapses and the high risk of post-inflammatory hyperpigmentation. Paradoxically, targeting the vascular component of the melasma lesion with lasers could have a beneficial effect. However, these results have yet to be confirmed. In all cases, a precise diagnosis of the type of hyperpigmentation is mandatory before any laser treatment, and the limits and the potential side effects of the treatment must be clearly explained to patients.

  6. Tracing direct and sequential two-photon double ionization of D{sub 2} in femtosecond extreme-ultraviolet laser pulses

    SciTech Connect

    Jiang, Y. H.; Kurka, M.; Kuehnel, K. U.; Ergler, Th.; Schroeter, C. D.; Moshammer, R.; Rudenko, A.; Foucar, L.; Plesiat, E.; Perez-Torres, J. F.; Martin, F.; Herrwerth, O.; Lezius, M.; Kling, M. F.; Titze, J.; Jahnke, T.; Doerner, R.; Sanz-Vicario, J. L.; Schoeffler, M.; Tilborg, J. van

    2010-02-15

    Two-photon double ionization (TPDI) of D{sub 2} is studied for 38-eV photons at the Free Electron Laser in Hamburg (FLASH). Based on model calculations, instantaneous and sequential absorption pathways are identified as separated peaks in the measured D{sup +}+D{sup +} fragment kinetic energy release (KER) spectra. The instantaneous process appears at high KER, corresponding to ionization at the molecule's equilibrium distance, in contrast to sequential ionization mainly leading to low-KER contributions. Measured fragment angular distributions are in good agreement with theory.

  7. Absolutely Calibrated Vacuum Ultraviolet Spectra in the 150 nm to 250 nm Range from Plasmas Generated by the NIKE KrF Laser

    DTIC Science & Technology

    2005-03-25

    BN, Al, Si, S, Ti, Pd, and Au. Titanium-doped silica aerogels in pyrex cylinders were also irradiated. Spectra of the target elements were observed...silica aerogel targets at 248 nm was typically 6x10-6 the incident NIKE laser energy, and the spectral broadening corresponded to the 1 THz bandwidth of...targets consisted of planar foils of CH, BN, Al, Si, S, Ti, Pd, and Au. Titanium-doped silica aerogels in pyrex cylinders were also irradiated. Spectra of

  8. Time-resolved spatial distribution of plasma in the ablation of a Ba₀.₆Sr₀.₄TiO₃ target by 25 ns KrF ultraviolet laser

    SciTech Connect

    Lagrange, J. F.; Wolfman, J.; Motret, O.; Hermann, J.

    2014-10-07

    We performed radially and longitudinally time-resolved plasma analysis during pulsed laser deposition of Ba₀.₆Sr₀.₄TiO₃ thin films. The plasma is shown to be optically thick and strongly non-uniform during the early expansion phase and the resonance line Ba II (455.4 nm) is strongly self-reversed during this time. Plasma temperature and electron density were obtained by comparing experimental emission spectra with the spectral radiance computed for a non-uniform plasma in local thermal equilibrium.

  9. Communication: Rovibrationally selected study of the N{sub 2}{sup +}(X; v{sup +}= 1, N{sup +}= 0-8) + Ar charge transfer reaction using the vacuum ultraviolet laser pulsed field ionization-photoion method

    SciTech Connect

    Chang, Yih Chung; Xu Hong; Xu Yuntao; Lu Zhou; Ng, C. Y.; Chiu, Yu-Hui; Levandier, Dale J.

    2011-05-28

    By employing an electric field pulsing scheme for vacuum ultraviolet laser pulsed field ionization-photoion (PFI-PI) measurements, we have been able to prepare a rovibrationally selected PFI-PI beam of N{sub 2}{sup +}(v{sup +}= 1, N{sup +}) with not only high intensity and high quantum state purity, but also high kinetic energy resolution, allowing absolute total cross sections [{sigma}(v{sup +}= 1, N{sup +})] for the N{sub 2}{sup +}(X; v{sup +}= 1, N{sup +}) + Ar, N{sup +}= 0-8 charge transfer reaction to be measured at center-of-mass collision energies (E{sub cm}) down to thermal energies. The {sigma}(v{sup +}= 1, N{sup +}= 0-8) values determined at E{sub cm}= 0.04-10.00 eV are in good agreement with the theoretical predictions based on the Landau-Zener-Stueckelberg formulism. Taking into account the experimental uncertainties, the {sigma}(v{sup +}= 1, N{sup +}), N{sup +}= 0-8, measured at E{sub cm}= 1.56 eV are found to be independent of N{sup +}.

  10. Strain dependence on polarization properties of AlGaN and AlGaN-based ultraviolet lasers grown on AlN substrates

    SciTech Connect

    Bryan, Zachary Bryan, Isaac; Sitar, Zlatko; Collazo, Ramón; Mita, Seiji; Tweedie, James

    2015-06-08

    Since the band ordering in AlGaN has a profound effect on the performance of UVC light emitting diodes (LEDs) and even determines the feasibility of surface emitting lasers, the polarization properties of emitted light from c-oriented AlGaN and AlGaN-based laser structures were studied over the whole composition range, as well as various strain states, quantum confinements, and carrier densities. A quantitative relationship between the theoretical valence band separation, determined using k•p theory, and the experimentally measured degree of polarization is presented. Next to composition, strain was found to have the largest influence on the degree of polarization while all other factors were practically insignificant. The lowest crossover point from the transverse electric to transverse magnetic polarized emission of 245 nm was found for structures pseudomorphically grown on AlN substrates. This finding has significant implications toward the efficiency and feasibility of surface emitting devices below this wavelength.

  11. Ultraviolet/matrix-assisted laser desorption/ionization mass spectrometric characterization of 2,5-dihydroxybenzoic acid-induced reductive hydrogenation of oligonucleotides on cytosine residues.

    PubMed

    Koomen, J M; Russell, D H

    2000-08-01

    The changes in the ion signals in the isotope cluster, mass resolution, signal-to-noise ratio and mass accuracy for matrix-assisted laser desorption/ionization (MALDI) of DNA oligonucleotides (dGGATC, dCAGCt, and dAACCGTT) and their fragment ions were evaluated, and these data were compared with those obtained using 3-hydroxypicolinic acid. Mass spectra obtained by using 2,5-dihydroxybenzoic acid (2,5-DHB) appear to have differences from the theoretical isotopic clusters, which arise by reductive hydrogenation producing a second peak at the M + 2 isotope of the native oligonucleotide. Based on the patterns of the isotopic envelope observed in the in-source decay fragments, we propose that cytosine is the site of reduction. We do not find evidence of reduction of oligonucleotides, viz. dTGGGGTT, that do not contain cytosine; however, 2'-deoxycytidine and 2'-deoxycytidine-5'-monophosphate undergo reductive hydrogenation. Several experiments were carried out in an effort to determine whether the reductive hydrogenation occurs during sample preparation or as a result of laser irradiation. The results of these experiments suggest that it occurs during sample preparation. The relative intensities of ion signals corresponding to the reduced base can be altered by using different matrix additives (aminonaphthalenes) or a different substrate (copper). Also, the oxidized form of 2,5-DHB is trapped by reaction with the side chain of cysteine in glutathione, providing evidence that the reaction occurs in solution as the matrix crystallizes.

  12. Photoresist composition for extreme ultraviolet lithography

    DOEpatents

    Felter, T. E.; Kubiak, G. D.

    1999-01-01

    A method of producing a patterned array of features, in particular, gate apertures, in the size range 0.4-0.05 .mu.m using projection lithography and extreme ultraviolet (EUV) radiation. A high energy laser beam is used to vaporize a target material in order to produce a plasma which in turn, produces extreme ultraviolet radiation of a characteristic wavelength of about 13 nm for lithographic applications. The radiation is transmitted by a series of reflective mirrors to a mask which bears the pattern to be printed. The demagnified focused mask pattern is, in turn, transmitted by means of appropriate optics and in a single exposure, to a substrate coated with photoresists designed to be transparent to EUV radiation and also satisfy conventional processing methods. A photoresist composition for extreme ultraviolet radiation of boron carbide polymers, hydrochlorocarbons and mixtures thereof.

  13. Photoresist composition for extreme ultraviolet lithography

    SciTech Connect

    Felter, T.E.; Kubiak, G.D.

    1999-11-23

    A method of producing a patterned array of features, in particular, gate apertures, in the size range 0.4--0.05 {mu}m using projection lithography and extreme ultraviolet (EUV) radiation is disclosed. A high energy laser beam is used to vaporize a target material in order to produce a plasma which in turn, produces extreme ultraviolet radiation of a characteristic wavelength of about 13 nm for lithographic applications. The radiation is transmitted by a series of reflective mirrors to a mask which bears the pattern to be printed. The demagnified focused mask pattern is, in turn, transmitted by means of appropriate optics and in a single exposure, to a substrate coated with photoresists designed to be transparent to EUV radiation and also satisfy conventional processing methods. A photoresist composition for extreme ultraviolet radiation of boron carbide polymers, hydrochlorocarbons and mixtures thereof.

  14. Creation of metal-containing carbon onions via self-assembly in metallocene/benzene solution irradiated with an ultraviolet laser

    NASA Astrophysics Data System (ADS)

    Hayasaki, Yasuhiro; Fukuda, Takahiro; Hasumura, Takashi; Maekawa, Toru

    2012-09-01

    We irradiate sub- and super-critical benzene, in which metallocene such as ferrocene or cobaltocene is dissolved, with a UV laser of 266 nm wavelength, and show that benzene and metallocenes are dissociated and iron- and cobalt-containing carbon onions (Fe@C and Co@C) are created. The operational temperature of the present method is much lower than that of conventional ones for the growth of nanomaterials and therefore coagulation among metal-containing carbon onions is avoided. The average diameters of the core iron and cobalt nanoparticles are, respectively, 7.5 and 7.2 nm, whereas the thickness of the layers of carbon onions surrounding the core metal particles is 3.2 nm in both Fe@C and Co@C cases. The metal-containing carbon onions show superparamagnetic characteristics.

  15. Pyroelectric field assisted ion migration induced by ultraviolet laser irradiation and its impact on ferroelectric domain inversion in lithium niobate crystals

    SciTech Connect

    Ying, C. Y. J.; Mailis, S.; Daniell, G. J.; Steigerwald, H.; Soergel, E.

    2013-08-28

    The impact of UV laser irradiation on the distribution of lithium ions in ferroelectric lithium niobate single crystals has been numerically modelled. Strongly absorbed UV radiation at wavelengths of 244–305 nm produces steep temperature gradients which cause lithium ions to migrate and result in a local variation of the lithium concentration. In addition to the diffusion, here the pyroelectric effect is also taken into account which predicts a complex distribution of lithium concentration along the c-axis of the crystal: two separated lithium deficient regions on the surface and in depth. The modelling on the local lithium concentration and the subsequent variation of the coercive field are used to explain experimental results on the domain inversion of such UV treated lithium niobate crystals.

  16. Channel-specific photoelectron angular distribution in laboratory and molecular frames for dissociative ionization of methanol in intense ultraviolet laser fields

    NASA Astrophysics Data System (ADS)

    Fukahori, Shinichi; Nakano, Motoyoshi; Yamanouchi, Kaoru; Itakura, Ryuji

    2017-03-01

    We investigate dissociative ionization of CH3OH in an intense laser field (398 nm, 76 fs, 8.9 × 1012 W/cm2) by photoelectron-photoion coincidence momentum imaging. It is revealed from the analysis of the channel-specific photoelectron angular distributions that CH3OH is decomposed into CH2OH+ + H after the four-photon ionization to the vibrationally highly excited states of the electronic ground state of CH3OH+ and into CH3+ + OH after the five-photon ionization to the second electronically excited state of CH3OH+, and that these two channels are also opened after CH3OH+, prepared by the four-photon ionization, is photoexcited further into the electronically excited states.

  17. Ultraviolet laser damage and optical properties of high-refractive-index single layers, multiple layers, and high/low index multilayer stacks

    NASA Astrophysics Data System (ADS)

    McInnes, Hazel A.; Andrew, James E.; Bazin, Nicholas J.; Morris, A. J.; Porter, K. J.

    1998-04-01

    Laser induced damage thresholds, measured using N-on-1 and R-on-1 testing, of single layer high index zirconia and hafnia coatings, derived from nitric or acetic acid stabilized sol-gel processing, are reported. Single layer acetic acid, nitric acid and base catalyzed silica sol-gel coatings have also been tested. The sol-gels were dip coated onto fused silica substrates at a rate of 3mm/s. The refractive index of the materials were measured using transmission spectra of multiple pairs of high and low refractive index materials. Absorption in the UV region was similarly measured with multiple layers of the same material and fitting to a Beer's law behavior. The high index materials used were zirconia or hafnia, the low index material was silica. The compatibility of the various combinations of high and low index materials for physical stacking without cracking, achieving high reflectivity and high damage thresholds are discussed and compared.

  18. Control and elimination of cracking in aluminum(0.20) gallium(0.80) nitrogen using aluminum(x) gallium(1-x) nitrogen interlayers and application toward a near ultraviolet vertical cavity surface emitting laser

    NASA Astrophysics Data System (ADS)

    Waldrip, Karen Elizabeth

    -continuous wave optically pumped near ultraviolet vertical cavity surface emitting laser operating at 384 nm. This device employs a crack-free epitaxially grown mirror that consists of 120 pairs of Al 0.20Ga0.80N/GaN and is over five microns thick.

  19. Ultraviolet absorption hygrometer

    DOEpatents

    Gersh, Michael E.; Bien, Fritz; Bernstein, Lawrence S.

    1986-01-01

    An ultraviolet absorption hygrometer is provided including a source of pulsed ultraviolet radiation for providing radiation in a first wavelength region where water absorbs significantly and in a second proximate wavelength region where water absorbs weakly. Ultraviolet radiation in the first and second regions which has been transmitted through a sample path of atmosphere is detected. The intensity of the radiation transmitted in each of the first and second regions is compared and from this comparison the amount of water in the sample path is determined.

  20. Ultraviolet absorption hygrometer

    DOEpatents

    Gersh, M.E.; Bien, F.; Bernstein, L.S.

    1986-12-09

    An ultraviolet absorption hygrometer is provided including a source of pulsed ultraviolet radiation for providing radiation in a first wavelength region where water absorbs significantly and in a second proximate wavelength region where water absorbs weakly. Ultraviolet radiation in the first and second regions which has been transmitted through a sample path of atmosphere is detected. The intensity of the radiation transmitted in each of the first and second regions is compared and from this comparison the amount of water in the sample path is determined. 5 figs.

  1. Revelation of the Technological Versatility of the Eu(TTA)3Phen Complex by Demonstrating Energy Harvesting, Ultraviolet Light Detection, Temperature Sensing, and Laser Applications.

    PubMed

    Shahi, Praveen Kumar; Singh, Akhilesh Kumar; Singh, Sunil Kumar; Rai, Shyam Bahadur; Ullrich, Bruno

    2015-08-26

    We synthesized the Eu(TTA)3Phen complex and present herein a detailed study of its photophysics. The investigations encompass samples dispersed in poly(vinyl alcohol) and in ethanol in order to explore the versatile applicability of these lanthanide-based materials. Details upon the interaction between Eu, TTA, and the Phen ligands are revealed by Fourier transform infrared and UV-visible absorption, complemented by steady state and temporally resolved emission studies, which provide evidence of an efficient energy transfer from the organic ligands to the central Eu(3+) ion. The material produces efficient emission even under sunlight exposure, a feature pointing toward suitability for luminescent solar concentrators and UV light sensing, which is demonstrated for intensities as low as 200 nW/cm(2). The paper further promotes the complex's capability to be used as luminescence-based temperature sensor demonstrated by the considerable emission intensity changes of ∼4.0% per K in the temperature range of 50-305 K and ∼7% per K in the temeperature range 305-340 K. Finally, increasing the optical excitation causes both spontaneous emission amplification and emission peak narrowing in the Eu(TTA)3Phen complex dispersed in poly(vinyl alcohol) - features indicative of stimulated emission. These findings in conjunction with the fairly large stimulated emission cross-section of 4.29 × 10(-20) cm(2) demonstrate that the Eu(TTA)3Phen complex dispersed in poly(vinyl alcohol) could be a very promising material choice for lanthanide-polymer based laser architectures.

  2. Proposal for Testing and Validation of Vacuum Ultra-Violet Atomic Laser-Induced Fluorescence as a Method to Analyze Carbon Grid Erosion in Ion Thrusters

    NASA Technical Reports Server (NTRS)

    Stevens, Richard

    2003-01-01

    Previous investigation under award NAG3-25 10 sought to determine the best method of LIF to determine the carbon density in a thruster plume. Initial reports from other groups were ambiguous as to the number of carbon clusters that might be present in the plume of a thruster. Carbon clusters would certainly affect the ability to LIF; if they were the dominant species, then perhaps the LIF method should target clusters. The results of quadrupole mass spectroscopy on sputtered carbon determined that minimal numbers of clusters were sputtered from graphite under impact from keV Krypton. There were some investigations in the keV range by other groups that hinted at clusters, but at the time the proposal was presented to NASA, there was no data from low-energy sputtering available. Thus, the proposal sought to develop a method to characterize the population only of atoms sputtered from a graphite target in a test cell. Most of the ground work had been established by the previous two years of investigation. The proposal covering 2003 sought to develop an anti-Stokes Raman shifting cell to generate VUW light and test this cell on two different laser systems, ArF and YAG- pumped dye. The second goal was to measure the lowest detectable amounts of carbon atoms by 156.1 nm and 165.7 nm LIF. If equipment was functioning properly, it was expected that these goals would be met easily during the timeframe of the proposal, and that is the reason only modest funding was requested. The PI was only funded at half- time by Glenn during the summer months. All other work time was paid for by Whitworth College. The college also funded a student, Charles Shawley, who worked on the project during the spring.

  3. A dense plasma ultraviolet source

    NASA Technical Reports Server (NTRS)

    Lee, J. H.; Mcfarland, D. R.

    1978-01-01

    The intense ultraviolet emission from the NASA Hypocycloidal-Pinch (HCP) plasma is investigated. The HCP consists of three disk electrodes whose cross section has a configuration similar to the cross section of a Mather-type plasma focus. Plasma foci were produced in deuterium, helium, xenon, and krypton gases in order to compare their emission characteristics. Time-integrated spectra in the wavelength range from 200 nm to 350 nm and temporal variations of the uv emission were obtained with a uv spectrometer and a photomultiplier system. Modifications to enhance uv emission in the iodine-laser pump band (250 to 290 nm) and preliminary results produced by these modifications are presented. Finally, the advantages of the HCP as a uv over use of conventional xenon lamps with respect to power output limit, spectral range, and lifetime are discussed.

  4. DIRECT DETECTION OF COMPLEX ORGANIC PRODUCTS IN ULTRAVIOLET (Lyα) AND ELECTRON-IRRADIATED ASTROPHYSICAL AND COMETARY ICE ANALOGS USING TWO-STEP LASER ABLATION AND IONIZATION MASS SPECTROMETRY

    SciTech Connect

    Henderson, Bryana L.; Gudipati, Murthy S.

    2015-02-10

    As discovery of complex molecules and ions in our solar system and the interstellar medium has proliferated, several groups have turned to laboratory experiments in an effort to simulate and understand these chemical processes. So far only infrared (IR) and ultraviolet (UV) spectroscopy has been able to directly probe these reactions in ices in their native, low-temperature states. Here we report for the first time results using a complementary technique that harnesses two-step two-color laser ablation and ionization to measure mass spectra of energetically processed astrophysical and cometary ice analogs directly without warming the ices—a method for hands-off in situ ice analysis. Electron bombardment and UV irradiation of H{sub 2}O, CH{sub 3}OH, and NH{sub 3} ices at 5 K and 70 K led to complex irradiation products, including HCO, CH{sub 3}CO, formamide, acetamide, methyl formate, and HCN. Many of these species, whose assignment was also strengthened by isotope labeling studies and correlate with IR-based spectroscopic studies of similar irradiated ices, are important ingredients for the building blocks of life. Some of them have been detected previously via astronomical observations in the interstellar medium and in cometary comae. Other species such as CH{sub 3}CO (acetyl) are yet to be detected in astrophysical ices or interstellar medium. Our studies suggest that electron and UV photon processing of astrophysical ice analogs leads to extensive chemistry even in the coldest reaches of space, and lend support to the theory of comet-impact-induced delivery of complex organics to the inner solar system.

  5. Direct Detection of Complex Organic Products in Ultraviolet (Lyα) and Electron-irradiated Astrophysical and Cometary Ice Analogs Using Two-step Laser Ablation and Ionization Mass Spectrometry

    NASA Astrophysics Data System (ADS)

    Henderson, Bryana L.; Gudipati, Murthy S.

    2015-02-01

    As discovery of complex molecules and ions in our solar system and the interstellar medium has proliferated, several groups have turned to laboratory experiments in an effort to simulate and understand these chemical processes. So far only infrared (IR) and ultraviolet (UV) spectroscopy has been able to directly probe these reactions in ices in their native, low-temperature states. Here we report for the first time results using a complementary technique that harnesses two-step two-color laser ablation and ionization to measure mass spectra of energetically processed astrophysical and cometary ice analogs directly without warming the ices—a method for hands-off in situ ice analysis. Electron bombardment and UV irradiation of H2O, CH3OH, and NH3 ices at 5 K and 70 K led to complex irradiation products, including HCO, CH3CO, formamide, acetamide, methyl formate, and HCN. Many of these species, whose assignment was also strengthened by isotope labeling studies and correlate with IR-based spectroscopic studies of similar irradiated ices, are important ingredients for the building blocks of life. Some of them have been detected previously via astronomical observations in the interstellar medium and in cometary comae. Other species such as CH3CO (acetyl) are yet to be detected in astrophysical ices or interstellar medium. Our studies suggest that electron and UV photon processing of astrophysical ice analogs leads to extensive chemistry even in the coldest reaches of space, and lend support to the theory of comet-impact-induced delivery of complex organics to the inner solar system.

  6. Ultraviolet and infrared laser-induced fragmentation of free (CF{sub 3}I){sub n} clusters in a molecular beam and (CF{sub 3}I){sub n} clusters inside or on the surface of large (Xe){sub m} clusters

    SciTech Connect

    Apatin, V. M.; Lokhman, V. N.; Makarov, G. N. Ogurok, N.-D. D.; Petin, A. N.; Ryabov, E. A.

    2015-02-15

    The fragmentation of free homogeneous (CF{sub 3}I){sub n} clusters in a molecular beam (n ≤ 45 is the average number of molecules in the cluster) and (CF{sub 3}I){sub n} clusters inside or on the surface of large (Xe){sub m} clusters (m ≥ 100 is the average number of atoms in the cluster) by ultraviolet and infrared laser radiations has been studied. These three types of (CF{sub 3}I){sub n} clusters are shown to have different stabilities with respect to fragmentation by both ultraviolet and infrared radiations and completely different dependences of the fragmentation probability on the energy of ultraviolet and infrared radiations. When exposed to ultraviolet radiation, the free (CF{sub 3}I){sub n} clusters fragment at comparatively low fluences (Φ{sub UV} ≤ 0.15 J cm{sup −2}) and the weakest energy dependence of the fragmentation probability is observed for them. A stronger energy dependence of the fragmentation probability is observed for the (CF{sub 3}I){sub n} clusters localized inside (Xe){sub m} clusters, and the strongest dependence is observed for the (CF{sub 3}I){sub n} clusters located on the surface of (Xe){sub m} clusters. When the clusters are exposed to infrared radiation, the homogeneous (CF{sub 3}I){sub n} clusters efficiently fragment at low fluences (Φ{sub IR} ≤ 25 mJ cm{sup −2}), higher fluences (Φ{sub IR} ≈ 75 mJ cm{sup −2}) are needed for the fragmentation of the (CF{sub 3}I){sub n} localized inside (Xe){sub m} clusters, and even higher fluences (Φ{sub IR} ≈ 150 mJ cm{sup −2}) are needed for the fragmentation of the (CF{sub 3}I){sub n} clusters located on the surface of (Xe){sub m} clusters. It has been established that small (CF{sub 3}I){sub n} clusters located on the surface of (Xe){sub m} clusters do not fragment up to fluences Φ{sub IR} ≈ 250 mJ cm{sup −2}. The fragmentation efficiency of (CF{sub 3}I){sub n} clusters is shown to be the same (at the same fluence) when they are excited by both pulsed (τ{sub p}

  7. Laser nitriding and laser carburizing of surfaces

    NASA Astrophysics Data System (ADS)

    Schaaf, Peter

    2003-11-01

    Laser irradiation of surfaces with short pulses in reactive atmospheres (nitrogen, methane) can lead to very effective nitrification and carburization via complicated laser-surface-gas-plasma-interactions. This laser nitriding and laser carburizing and their basic underlying phenomena will be presented and partly explained by results of example materials (iron, titanium, aluminum, silicon) where nitride and carbide coatings can be formed by fast and easily by Excimer Laser, Nd:YAG laser, Free Electron Laser and also by femtosecond Ti:sapphire laser. This implies laser pulse durations from the nanosecond to the femtosecond regime and wavelengths from ultra-violet to infrared. The resulting surfaces, thin films, coatings and their properties are investigated by combining Mossbauer Spectroscopy, x-ray diffraction, x-ray absorption spectroscopy, Nanoindentation, Resonant Nuclear Reaction Analysis, and Rutherford Backscattering Spectroscopy.

  8. Free-Electron Lasers.

    ERIC Educational Resources Information Center

    Brau, Charles A.

    1988-01-01

    Describes the use of free-electron lasers as a source of coherent radiation over a broad range of wavelengths from the far-infrared to the far-ultraviolet regions of the spectrum. Discusses some applications of these lasers, including medicine and strategic defense. (TW)

  9. Green pumped Alexandrite lasers

    NASA Astrophysics Data System (ADS)

    Kuper, Jerry W.; Brown, David C.

    2005-04-01

    Initial experiments with pulsed and CW pumping an alexandrite laser rod at 532 nm are presented. This pumping architecture holds promise for the production of scalable diode-pumped, tunable alexandrite laser systems operating in the near infrared (750 nm), and the ultraviolet (375 and 250 nm) spectral regions.

  10. Ultraviolet Excitation Photothermal Spectroscopy of Non-Labeled Amino Acids and Visible Light-Induced Signal Enhancement

    NASA Astrophysics Data System (ADS)

    Hirashima, Satoshi; Harata, Akira

    2008-05-01

    A measurement system for ultraviolet-laser excitation photothermal lens spectroscopy has been designed and constructed for measuring dilute amino acids in liquid solutions. An ultraviolet laser beam is generated as the fourth harmonic of a Ti:sapphire laser in the wavelength range of 212 to 220 nm. Photothermal lens spectra of alanine, phenylalanine, serine, and tryptophan are observed. Photothermal lens spectra of these samples are coincident with their absorption spectra. It is demonstrated that photothermal lens signals of the amino acids can be amplified by simultaneous excitation with a visible laser. This ultraviolet-excitation visible-enhancement system is applicable to photoacoustic detection.

  11. Tunable lasers- an overview

    SciTech Connect

    Guenther, B.D.; Buser, R.G.

    1982-08-01

    This overview of tunable lasers describes their applicability to spectroscopy in the ultraviolet and middle infrared ranges; to rapid on-line diagnostics by ultrashort cavity lasers; to exploration, by the free electron laser, for its wide tuning in the far infrared to submillimeter region; to remote detection, in areas such as portable pollution monitors, on-line chemical analyzers, auto exhaust analyzers, and production line controls; to photochemistry; and to other potential areas in diagnostics, communications, and medical and biological sciences. The following lasers are characterized by their tunability: solid state lasers, primarily alexandrite, with a tuning range of ca 1000 Angstroms; color center lasers; semiconductor lasers; dye lasers; gas lasers, where high-pressure CO/sub 2/ discharges are the best known example for a wide tunability range, and research is continuing in systems such as the alkali dimers; and, at wavelengths beyond 10 micrometers, the possibilities beyond Cerenkov and free electron lasers.

  12. Ultraviolet Mars Reveals Cloud Formation

    NASA Video Gallery

    Images from MAVEN's Imaging UltraViolet Spectrograph were used to make this movie of rapid cloud formation on Mars on July 9-10, 2016. The ultraviolet colors of the planet have been rendered in fal...

  13. Rovibrationally selected ion-molecule collision study using the molecular beam vacuum ultraviolet laser pulsed field ionization-photoion method: charge transfer reaction of N2(+)(X 2Σg+; v+ = 0-2; N+ = 0-9) + Ar.

    PubMed

    Chang, Yih Chung; Xu, Yuntao; Lu, Zhou; Xu, Hong; Ng, C Y

    2012-09-14

    We have developed an ion-molecule reaction apparatus for state-selected absolute total cross section measurements by implementing a high-resolution molecular beam vacuum ultraviolet (VUV) laser pulsed field ionization-photoion (PFI-PI) ion source to a double-quadrupole double-octopole ion-guide mass spectrometer. Using the total cross section measurement of the state-selected N(2)(+)(v(+), N(+)) + Ar charge transfer (CT) reaction as an example, we describe in detail the design of the VUV laser PFI-PI ion source used, which has made possible the preparation of reactant N(2)(+)(X (2)Σ(g)(+), v(+) = 0-2, N(+) = 0-9) PFI-PIs with high quantum state purity, high intensity, and high kinetic energy resolution. The PFI-PIs and prompt ions produced in the ion source are shown to have different kinetic energies, allowing the clean rejection of prompt ions from the PFI-PI beam by applying a retarding potential barrier upstream of the PFI-PI source. By optimizing the width and amplitude of the pulsed electric fields employed to the VUV-PFI-PI source, we show that the reactant N(2)(+) PFI-PI beam can be formed with a laboratory kinetic energy resolution of ΔE(lab) = ± 50 meV. As a result, the total cross section measurement can be conducted at center-of-mass kinetic energies (E(cm)'s) down to thermal energies. Absolute total rovibrationally selected cross sections σ(v(+) = 0-2, N(+) = 0-9) for the N(2)(+)(X (2)Σ(g)(+); v(+) = 0-2, N(+) = 0-9) + Ar CT reaction have been measured in the E(cm) range of 0.04-10.0 eV, revealing strong vibrational enhancements and E(cm)-dependencies of σ(v(+) = 0-2, N(+) = 0-9). The thermochemical threshold at E(cm) = 0.179 eV for the formation of Ar(+) from N(2)(+)(X; v(+) = 0, N(+)) + Ar was observed by the measured σ(v(+) = 0), confirming the narrow ΔE(cm) spread achieved in the present study. The σ(v(+) = 0-2; N(+)) values obtained here are compared with previous experimental and theoretical results. The theoretical predictions

  14. Programmable femtosecond laser pulses in the ultraviolet

    SciTech Connect

    Hacker, M.; Feurer, T.; Sauerbrey, R.; Lucza, T.; Szabo, G.

    2001-06-01

    Using a combination of a zero-dispersion compressor and spectrally compensated sum-frequency generation, we have produced amplitude-modulated femtosecond pulses in the UV at 200 nm. {copyright} 2001 Optical Society of America

  15. Deep Ultraviolet Laser Imaging for Biology

    DTIC Science & Technology

    2008-08-15

    average 466 amino acid protein,( Lodish , 2004) and the tryptophan, tyrosine, and phenylalanine frequencies (1.4%, 3.2%, and 3.9%).(Voet, 1995...average molar mass of 52,728 Da for protein( Lodish , 2004) and of 330 Da for nucleic acid(Berg, 2002) yields the mass of each. Displaying this value at

  16. Ultraviolet reflective coating

    NASA Technical Reports Server (NTRS)

    Schutt, J. B.

    1974-01-01

    Composition consists of dispersion of barium sulphate in aqueous solution of water-soluble inorganic binder. Binder is selected from group consisting of alkali metal sulphates. Coating exhibits high reflectance of ultraviolet light to wavelengths of approximately 200.0 nm, which compares favorably with high reflectance of virgin barium sulphate power.

  17. Ultraviolet radiation changes

    NASA Technical Reports Server (NTRS)

    Mckenzie, Richard L.; Frederick, John E.; Ilyas, Mohammad; Filyushkin, V.; Wahner, Andreas; Stamnes, K.; Muthusubramanian, P.; Blumthaler, M.; Roy, Colin E.; Madronich, Sasha

    1991-01-01

    A major consequence of ozone depletion is an increase in solar ultraviolet (UV) radiation received at the Earth's surface. This chapter discusses advances that were made since the previous assessment (World Meteorological Organization (WMO)) to our understanding of UV radiation. The impacts of these changes in UV on the biosphere are not included, because they are discussed in the effects assessment.

  18. Psoriasis and ultraviolet radiation

    SciTech Connect

    Farber, E.M.; Nall, L. )

    1993-09-01

    Prevention and detection screening programs as a public health service in curtailing the ever-increasing incidence of all forms of skin cancer are reviewed. The effect of solar and artificial ultraviolet radiation on the general population and persons with psoriasis is examined. 54 refs.

  19. International Ultraviolet Explorer

    NASA Technical Reports Server (NTRS)

    1997-01-01

    This report is the November 6, 1996 - October 9, 1997, IUE Final Report for the International Ultraviolet Explorer Final Archive contract. The ultimate objective of this contract is the completion of the archival reprocessing of all IUE data obtained at GSFC between 1978 and 1995.

  20. Extreme ultraviolet photoionization of aldoses and ketoses

    NASA Astrophysics Data System (ADS)

    Shin, Joong-Won; Dong, Feng; Grisham, Michael E.; Rocca, Jorge J.; Bernstein, Elliot R.

    2011-04-01

    Gas phase monosaccharides (2-deoxyribose, ribose, arabinose, xylose, lyxose, glucose galactose, fructose, and tagatose), generated by laser desorption of solid sample pellets, are ionized with extreme ultraviolet photons (EUV, 46.9 nm, 26.44 eV). The resulting fragment ions are analyzed using a time of flight mass spectrometer. All aldoses yield identical fragment ions regardless of size, and ketoses, while also generating same ions as aldoses, yields additional features. Extensive fragmentation of the monosaccharides is the result the EUV photons ionizing various inner valence orbitals. The observed fragmentation patterns are not dependent upon hydrogen bonding structure or OH group orientation.

  1. Vacuum-ultraviolet frequency-modulation spectroscopy.

    PubMed

    Hollenstein, U; Schmutz, H; Agner, J A; Sommavilla, M; Merkt, F

    2017-01-07

    Frequency-modulation (FM) spectroscopy has been extended to the vacuum-ultraviolet (VUV) range of the electromagnetic spectrum. Coherent VUV laser radiation is produced by resonance-enhanced sum-frequency mixing (νVUV=2νUV+ν2) in Kr and Xe using two near-Fourier-transform-limited laser pulses of frequencies νUV and ν2. Sidebands generated in the output of the second laser (ν2) using an electro-optical modulator operating at the frequency νmod are directly transferred to the VUV and used to record FM spectra. Demodulation is demonstrated both at νmod and 2νmod. The main advantages of the method compared to VUV absorption spectroscopy are its background-free nature, the fact is that its implementation using table-top laser equipment is straightforward and that it can be used to record VUV absorption spectra of cold samples in skimmed supersonic beams simultaneously with laser-induced-fluorescence and photoionization spectra. To illustrate these advantages, we present VUV FM spectra of Ar, Kr, and N2 in selected regions between 105000 cm(-1) and 122000 cm(-1).

  2. Far ultraviolet instrument technology

    NASA Astrophysics Data System (ADS)

    Paxton, Larry J.; Schaefer, Robert K.; Zhang, Yongliang; Kil, Hyosub

    2017-02-01

    The far ultraviolet (FUV) spectral range (from about 115 nm to 180 nm) is one of the most useful spectral regions for characterizing the upper atmosphere (thermosphere and ionosphere). The principal advantages are that there are FUV signatures of the major constituents of the upper atmosphere as well as the signatures of the high-latitude energy inputs. Because of the absorption by thermospheric O2, the FUV signatures are seen against a "black" background, i.e., one that is not affected by ground albedo or clouds and, as a consequence, can make useful observations of the aurora during the day or when the Moon is above the horizon. In this paper we discuss the uses of FUV remote sensing, summarize the various techniques, and discuss the technological challenges. Our focus is on a particular type of FUV instrument, the scanning imaging spectrograph or SIS: an instrument exemplified by the Defense Meteorological Satellite Program Special Sensor Ultraviolet Imager and Thermosphere Ionosphere Mesosphere Energetics and Dynamics Global Ultraviolet Imager. The SIS combines spatial imaging of the disk with limb profiles as well as spectral information at each point in the scan.

  3. Ultraviolet Raman scattering from persistent chemical warfare agents

    NASA Astrophysics Data System (ADS)

    Kullander, Fredrik; Wästerby, Pär.; Landström, Lars

    2016-05-01

    Laser induced Raman scattering at excitation wavelengths in the middle ultraviolet was examined using a pulsed tunable laser based spectrometer system. Droplets of chemical warfare agents, with a volume of 2 μl, were placed on a silicon surface and irradiated with sequences of laser pulses. The Raman scattering from V-series nerve agents, Tabun (GA) and Mustard gas (HD) was studied with the aim of finding the optimum parameters and the requirements for a detection system. A particular emphasis was put on V-agents that have been previously shown to yield relatively weak Raman scattering in this excitation band.

  4. Rabi oscillations in extreme ultraviolet ionization of atomic argon

    NASA Astrophysics Data System (ADS)

    Flögel, Martin; Durá, Judith; Schütte, Bernd; Ivanov, Misha; Rouzée, Arnaud; Vrakking, Marc J. J.

    2017-02-01

    We demonstrate Rabi oscillations in nonlinear ionization of argon by an intense femtosecond extreme ultraviolet (XUV) laser field produced by high-harmonic generation. We monitor the formation of A r2 + as a function of the time delay between the XUV pulse and an additional near-infrared (NIR) femtosecond laser pulse, and show that the population of an A r+* intermediate resonance exhibits strong modulations both due to an NIR laser-induced Stark shift and XUV-induced Rabi cycling between the ground state of A r+ and the A r+* excited state. Our experiment represents a direct experimental observation of a Rabi-cycling process in the XUV regime.

  5. Laser-assisted photoelectric effect from surfaces.

    PubMed

    Miaja-Avila, L; Lei, C; Aeschlimann, M; Gland, J L; Murnane, M M; Kapteyn, H C; Saathoff, G

    2006-09-15

    We report the first observation of the laser-assisted photoelectric effect from a solid surface. By illuminating a Pt(111) sample simultaneously with ultrashort 1.6 eV and 42 eV pulses, we observe sidebands in the extreme ultraviolet photoemission spectrum. The magnitude of these sidebands as a function of time delay between the laser and extreme ultraviolet pulses represents a cross-correlation measurement of the extreme ultraviolet pulse. This effect promises to be useful to extend extreme ultraviolet pulse duration measurements to higher photon energies, as well as opening up femtosecond-to-attosecond time-scale electron dynamics in solid and surface-adsorbate systems.

  6. Femtosecond transparency in the extreme ultraviolet

    NASA Astrophysics Data System (ADS)

    Tarana, Michal; Greene, Chris H.

    2012-06-01

    Electromagnetically induced transparency-like behavior in the extreme ultraviolet (XUV) is studied theoretically, including the effect of intense 800nm laser dressing of He 2s2p(^1P^o) and 2p^2(^2S^e) autoionizing states. We present an ab initio solution of the time-dependent Schr"odinger equation in an LS-coupling configuration interaction basis set. The method enables a rigorous treatment of optical field ionization of these coupled autoionizing states into the N = 2 continuum in addition to N = 1. Our calculated transient absorption spectra show the formation of the Autler-Townes doublet in the presence of the dressing laser field. The presented results are in encouraging agreement with experiment [1]. [4pt] [1] Z.H. Loh, C.H. Greene, and S. R. Leone, Chem. Phys. 350, 7 (2008)

  7. Research in extreme ultraviolet and far ultraviolet astronomy

    NASA Technical Reports Server (NTRS)

    Labov, S. E.

    1985-01-01

    Instruments designed to explore different aspects of far and extreme ultraviolet cosmic radiation were studied. The far ultraviolet imager (FUVI) was flown on the Aries sounding rocket. Its unique large format 75mm detector mapped out the far ultraviolet background radiation with a resolution of only a few arc minutes. Analysis of this data indicates to what extent the FUVI background is extra galactic in origin. A power spectrum of the spatial fluctuations will have direct consequences for galactic evolution.

  8. The National Ignition Facility

    SciTech Connect

    Miller, G H; Moses, E I; Wuest, C R

    2004-02-06

    The National Ignition Facility (NIF) at Lawrence Livermore National Laboratory is a stadium-sized facility containing a 192-beam, 1.8-Megajoule, 500-Terawatt, ultraviolet laser system together with a 10-meter-diameter target chamber and room for 100 diagnostics. NIF is the world's largest and most energetic laser experimental system, providing a scientific center to study inertial confinement fusion and matter at extreme energy densities and pressures. NIF's energetic laser beams will compress fusion targets to conditions required for thermonuclear burn, liberating more energy than required to initiate the fusion reactions. Other NIF experiments will study physical processes at temperatures approaching 10{sup 8} K and 10{sup 11} bar; conditions that exist naturally only in the interior of stars and planets. NIF has completed the first phases of its laser commissioning program. The first four beams of NIF have generated 106 kilojoules in 23-ns pulses of infrared light and over 16 kJ in 3.5-ns pulses at the third harmonic (351 nm). NIF's target experimental systems are being commissioned and experiments have begun. This paper provides a detailed look the NIF laser systems, laser and optical performance, and results from recent laser commissioning shots. We follow this with a discussion of NIF's high-energy-density and inertial fusion experimental capabilities, the first experiments on NIF, and plans for future capabilities of this unique facility.

  9. Mars ultraviolet reflectance compared with imaging, topography and geology

    NASA Astrophysics Data System (ADS)

    Simmons, K. E.; Mankoff, K. D.; Hendrix, A. R.; Barth, C. A.

    2003-04-01

    We compare ultraviolet reflectance spectra from the Mariner Mars 1971 (MM71) Ultraviolet Spectrometer (UVS) with imaging data from the Viking Mars Digital Image Model (MDIM), with surface topography from the Mars Global Surveyor (MGS) Mars Orbiter Laser Altimeter (MOLA), and with geology from the USGS Survey Atlas of Mars digital maps. We use a new web-accessible database of MM71 UVS Reflectances and two software tools: 1) a surface and atmosphere database visualization tool called Albatross and 2) a web-based Mars data comparison tool called MDC. See http://lasp.colorado.edu/software_tools/. We present several examples, including the northern polar region and Lyot Crater.

  10. Galileo Ultraviolet Spectrometer experiment

    NASA Technical Reports Server (NTRS)

    Hord, C. W.; Mcclintock, W. E.; Stewart, A. I. F.; Barth, C. A.; Esposito, L. W.; Thomas, G. E.; Sandel, B. R.; Hunten, D. M.; Broadfoot, A. L.; Shemansky, D. E.

    1992-01-01

    The Galileo ultraviolet spectrometer experiment uses data obtained by the Ultraviolet Spectrometer (UVS) mounted on the pointed orbiter scan platform and from the Extreme Ultraviolet Spectrometer (EUVS) mounted on the spinning part of the orbiter with the field of view perpendicular to the spin axis. The UVS is a Ebert-Fastie design that covers the range 113-432 nm with a wavelength resolution of 0.7 nm below 190 and 1.3 nm at longer wavelengths. The UVS spatial resolution is 0.4 deg x 0.1 deg for illuminated disk observations and 1 deg x 0.1 deg for limb geometries. The EUVS is a Voyager design objective grating spectrometer, modified to cover the wavelength range from 54 to 128 nm with wavelength resolution 3.5 nm for extended sources and 1.5 nm for point sources and spatial resolution of 0.87 deg x 0.17 deg. The EUVS instrument will follow up on the many Voyager UVS discoveries, particularly the sulfur and oxygen ion emissions in the Io torus and molecular and atomic hydrogen auroral and airglow emissions from Jupiter. The UVS will obtain spectra of emission, absorption, and scattering features in the unexplored, by spacecraft, 170-432 nm wavelength region. The UVS and EUVS instruments will provide a powerful instrument complement to investigate volatile escape and surface composition of the Galilean satellites, the Io plasma torus, micro- and macro-properties of the Jupiter clouds, and the composition structure and evolution of the Jupiter upper atmosphere.

  11. Ultraviolet Background Radiation (Preprint)

    DTIC Science & Technology

    1991-03-01

    5.4 Apollo-Soyuz 3 5 5.5 Evidence for Scattering From Dust ? 3 8 5.6 More Evidence For Scattering From Dust ? 4 0 5.7 More Observations 4 2...Emission from cold interstellar dust . This has been observed by IRAS as the 100 u.m cosmic cirrus (64). The existence of such dust at moderate and... DUST 4 6 CONCLUSIONS 4 7 6.1 Spectral Structure in the Diffuse 4 7 Ultraviolet Background 6.2 Is There Light Scattered From Dust ? 4 7 6.3

  12. Ultraviolet atomic emission detector

    NASA Technical Reports Server (NTRS)

    Braun, W.; Peterson, N. C.; Bass, A. M.; Kurylo, M. J., III (Inventor)

    1972-01-01

    A device and method are provided for performing qualitative and quantitative elemental analysis through the utilization of a vacuum UV chromatographic detector. The method involves the use of a carrier gas at low pressure. The gas carries a sample to a gas chromatograph column; the column output is directed to a microwave cavity. In this cavity, a low pressure microwave discharge produces fragmentation of the compounds present and generates intense atomic emissions in the vacuum ultraviolet. These emissions are isolated by a monochromator and measured by photometer to establish absolute concentration for the elements.

  13. Transparent ultraviolet photovoltaic cells.

    PubMed

    Yang, Xun; Shan, Chong-Xin; Lu, Ying-Jie; Xie, Xiu-Hua; Li, Bing-Hui; Wang, Shuang-Peng; Jiang, Ming-Ming; Shen, De-Zhen

    2016-02-15

    Photovoltaic cells have been fabricated from p-GaN/MgO/n-ZnO structures. The photovoltaic cells are transparent to visible light and can transform ultraviolet irradiation into electrical signals. The efficiency of the photovoltaic cells is 0.025% under simulated AM 1.5 illumination conditions, while it can reach 0.46% under UV illumination. By connecting several such photovoltaic cells in a series, light-emitting devices can be lighting. The photovoltaic cells reported in this Letter may promise the applications in glass of buildings to prevent UV irradiation and produce power for household appliances in the future.

  14. Development and Application of XUV Lasers

    DTIC Science & Technology

    1993-01-01

    The focus of this program is the development of extreme ultraviolet (XUV) lasers and their application to scientific problems. Laser development concentrates...techniques. Such techniques should have a number of applications and be particularly useful in the life sciences. This report presents recent progress on XUV laser development

  15. Investigation of ultraviolet interstellar extinction

    NASA Technical Reports Server (NTRS)

    Payne, C.; Haramundanis, K. L.

    1973-01-01

    Results concerning interstellar extinction in the ultraviolet are reported. These results were initially obtained by using data from main-sequence stars and were extended to include supergiants and emission stars. The principal finding of the analysis of ultraviolet extinction is not only that it is wavelength dependent, but that if changes with galactic longitude in the U3 passband (lambda sub eff = 1621 A); it does not change significantly in the U2 passband (lambda sub eff = 2308 A). Where data are available in the U4 passband (lambda sub eff = 1537 A), they confirm the rapid rise of extinction in the ultraviolet found by other investigators. However, in all cases, emission stars must be used with great caution. It is important to realize that while extinction continues to rise toward shorter wavelengths in the ultraviolet, including the shortest ultraviolet wavelengths measured (1100 A), it no longer plays an important role in the X-ray region (50 A).

  16. The National Ignition Facility

    SciTech Connect

    Miller, G H

    2003-12-19

    The National Ignition Facility (NIF) at Lawrence Livermore National Laboratory is a stadium-sized facility containing a 192-beam, 1.8-Megajoule, 500-Terawatt, ultraviolet laser system together with a 10-meter diameter target chamber and room for 100 diagnostics. NIF is the world's largest and most energetic laser experimental system, providing a scientific center to study inertial confinement fusion and matter at extreme energy densities and pressures. NIF's energetic laser beams will compress fusion targets to conditions required for thermonuclear burn, liberating more energy than required to initiate the fusion reactions. Other NIF experiments will study physical processes at temperatures approaching 10{sup 8} K and 10'' bar; conditions that exist naturally only in the interior of stars and planets. NIF has completed the first phases of its laser commissioning program. The first four beams of NIF have generated 106 kilojoules in 23-ns pulses of infrared light and over 16 kJ in 3.5 ns pulses at the third harmonic (351 nm). NIF's target experimental systems are being commissioned and experiments have begun. This paper discusses NIF's current and future experimental capability, plans for diagnostics, cryogenic target systems, specialized optics for experiments, and potential enhancements to NIF such as multi-color laser operation and high-energy short pulse operation.

  17. Mars ultraviolet simulation facility.

    PubMed

    Zill, L P; Mack, R; DeVincenzi, D L

    1979-12-01

    A facility was established for long-duration ultraviolet (UV) radiation exposure of natural and synthetic materials in order to test hypotheses concerning Martian soil chemistry observed by the Viking Mars landers. The system utilized a 2500 watt xenon lamp as the radiation source, with the beam passing through a heat-dissipating water filter before impinging upon an exposure chamber containing the samples to be irradiated. The chamber was designed to allow for continuous tumbling of the samples, maintenance of temperatures below 0 degrees C during exposure, and monitoring of beam intensity. The facility also provided for sample preparation under a variety of atmospheric conditions, in addition to the Mars nominal. As many as 33 sealed sample ampules have been irradiated in a single exposure. Over 100 samples have been irradiated for approximately 100 to 700 h. The facility has performed well in providing continuous UV irradiation of multiple samples for long periods of time under simulated Mars atmospheric and thermal conditions.

  18. Ultraviolet observations of comets

    NASA Technical Reports Server (NTRS)

    Code, A. D.; Houck, T. E.; Lillie, C. F.

    1972-01-01

    The first observations of a comet in the vacuum ultraviolet were obtained on January 14, 1970, when OAO-2 recorded the spectrum of the bright comet Tago-Sato-Kosaka (1969g). The observations revealed, among other things, the predicted extensive hydrogen Lyman alpha halo. OAO-2 continued to collect spectrophotometric measurements of this comet throughout January of that year; a photograph of the nucleus in Lyman alpha revealed finer scale structures. In February of 1970, the bright comet Bennet (1969i) became favorable for space observations. On the basis of the OAO discovery, OGO-V made several measurements of comet Bennet with low spatial resolution photometers. Comet Enke was detected by OGO in January of 1971 at a large heliocentric distance from its Lyman alpha emission.

  19. Ultraviolet radiation effects

    NASA Technical Reports Server (NTRS)

    Slemp, Wayne S.

    1989-01-01

    Solar ultraviolet testing was not developed which will provide highly accelerated (20 to 50X) exposures that correlate to flight test data. Additional studies are required to develop an exposure methodology which will assure that accelerated testing can be used for qualification of materials and coatings for long duration space flight. Some conclusions are listed: Solar UV radiation is present in all orbital environments; Solar UV does not change in flux with orbital altitude; UV radiation can degrade most coatings and polymeric films; Laboratory UV simulation methodology is needed for accelerated testing to 20 UV solar constants; Simulation of extreme UV (below 200 nm) is needed to evaluate requirements for EUV in solar simulation.

  20. Xenon clusters in intense VUV laser fields.

    PubMed

    Santra, Robin; Greene, Chris H

    2003-12-05

    A simple model is developed that quantitatively describes intense interactions of a vacuum ultraviolet (VUV) laser pulse with a xenon cluster. We find good agreement with a recent experiment [Nature (London) 420, 482 (2002)

  1. An enhanced multiwavelength ultraviolet biological trigger lidar

    NASA Astrophysics Data System (ADS)

    Achey, Alexander; Bufton, Jack; Dawson, Jeffrey; Huang, Wen; Lee, Sangmin; Mehta, Nikhil; Prasad, Coorg R.

    2004-12-01

    A compact Ultraviolet Biological Trigger Lidar (UBTL) instrument for detection and discrimination of bio-warfare-agent (BWA) simulant aerosol clouds was developed by us [Prasad, et al, 2004] using a 5mW, 375nm semiconductor UV optical source (SUVOS) laser diode. It underwent successful field tests at Dugway Proving Ground and demonstrated measurement ranges of over 300m for elastic scattering and >100m for fluorescence. The UBTL was modified during mid-2004 to enhance its detection and discrimination performance with increased range of operation and sensitivity. The major optical modifications were: 1. increase in telescope collection aperture to 200 mm diameter: 2. addition of 266nm and 977nm laser transmitters: 3. addition of three detection channels for 266nm and 977nm elastic backscatter and fluorescence centered at 330nm. Also the commercial electronics of the original UBTL were replaced with a multi-channel field programmable gate array (FPGA) chip for laser diode modulation and data acquisition that allowed simultaneous and continuous operation of the UBTL sensor on all of its transmitter and receiver wavelengths. A notebook computer was added for data display and storage. Field tests were performed during July 2004 at the Edgewood Chemical and Biological Center in Maryland to establish the enhanced performance of UBTL subsystems. Results of these tests are presented and discussed.

  2. ULTRAVIOLET PROTECTIVE COMPOUNDS AS A RESPONSE TO ULTRAVIOLET RADIATION EXPOSURE

    EPA Science Inventory

    Life on Earth has evolved adaptations to many environmental stresses over the epochs. One consistent stress has been exposure to ultraviolet radiation. In response to UVR organisms have adapted myriad responses; behavioral, morphological and physiological. Behaviorally, some orga...

  3. Rhodium nanoparticles for ultraviolet plasmonics.

    PubMed

    Watson, Anne M; Zhang, Xiao; Alcaraz de la Osa, Rodrigo; Marcos Sanz, Juan; González, Francisco; Moreno, Fernando; Finkelstein, Gleb; Liu, Jie; Everitt, Henry O

    2015-02-11

    The nonoxidizing catalytic noble metal rhodium is introduced for ultraviolet plasmonics. Planar tripods of 8 nm Rh nanoparticles, synthesized by a modified polyol reduction method, have a calculated local surface plasmon resonance near 330 nm. By attaching p-aminothiophenol, local field-enhanced Raman spectra and accelerated photodamage were observed under near-resonant ultraviolet illumination, while charge transfer simultaneously increased fluorescence for up to 13 min. The combined local field enhancement and charge transfer demonstrate essential steps toward plasmonically enhanced ultraviolet photocatalysis.

  4. Research in extreme ultraviolet and far ultraviolet astronomy

    NASA Technical Reports Server (NTRS)

    Bowyer, C. S.

    1985-01-01

    The Far Ultraviolet imager (FUVI) was flown on the Aries class sounding rocket 24.015, producing outstanding results. The diffuse extreme ultraviolet (EUV) background spectrometer which is under construction is described. It will be launched on the Black Brant sounding rocket flight number 27.086. Ongoing design studies of a high resolution spectrometer are discussed. This instrument incorporates a one meter normal incidence mirror and will be suitable for an advanced Spartan mission.

  5. Ablation of (GeS{sub 2}){sub 0.3}(Sb{sub 2}S{sub 3}){sub 0.7} glass with an ultra-violet nano-second laser

    SciTech Connect

    Knotek, P.; Navesnik, J.; Cernohorsky, T.; Kincl, M.; Vlcek, M.; Tichy, L.

    2015-04-15

    Highlights: • The interaction of (GeS{sub 2}){sub 0.3}(Sb{sub 2}S{sub 3}){sub 0.7} bulk glass and film with UV nanosecond laser. • Ablation process, topography of crater and structure of the material were studied. • Ablation threshold fluencies changed with the spot diameter and number of pulses. • The photo-thermal expansion of the material occurred for low laser fluency. • Laser direct writing process applicable for fabrication of passive optical elements. - Abstract: The results of an experimental study of the laser ablation of bulk and thin films of a GeSbS chalcogenide glass using UV nanosecond pulses are reported. The response of the samples to illumination conditions was studied through the use of atomic force spectroscopy, digital holographic microscopy, Raman scattering and scanning electron microscopy. The multi-pulse ablation thresholds were determined for both the bulk and thin film samples for varying number of pulses and illuminated spot diameter. The possible application of direct laser writing into the bulk and thin films of this material is presented.

  6. Multifunctional Deployment Hinges Rigidified by Ultraviolet

    NASA Technical Reports Server (NTRS)

    Kerslake, Thomas W.; Simburger, Edward J.; Matusmoto, James; Giants, Thomas W.; Garcia, Alexander; Perry, Alan; Rawal, Suraj; Marshall, Craig; Lin, John Kun Hung; Day, Jonathan Robert; Scarborough, Stephen Emerson

    2005-01-01

    Multifunctional hinges have been developed for deploying and electrically connecting panels comprising planar arrays of thin-film solar photovoltaic cells. In the original intended application of these hinges, the panels would be facets of a 32-sided (and approximately spherical) polyhedral microsatellite (see figure), denoted a PowerSphere, that would be delivered to orbit in a compact folded configuration, then deployed by expansion of gas in inflation bladders. Once deployment was complete, the hinges would be rigidified to provide structural connections that would hold the panels in their assigned relative positions without backlash. Such hinges could also be used on Earth for electrically connecting and structurally supporting solar panels that are similarly shipped in compact form and deployed at their destinations. As shown in section A-A in the figure, a hinge of this type is partly integrated with an inflation bladder and partly integrated with the frame of a solar panel. During assembly of the hinge, strip extensions from a flexible circuit harness on the bladder are connected to corresponding thin-film conductors on the solar panel by use of laser welding and wrap-around contacts. The main structural component of the hinge is a layer of glass fiber impregnated with an ultraviolet-curable resin. After deployment, exposure to ultraviolet light from the Sun cures the resin, thereby rigidifying the hinge.

  7. Vacuum Ultraviolet Photoionization of Complex Chemical Systems

    NASA Astrophysics Data System (ADS)

    Kostko, Oleg; Bandyopadhyay, Biswajit; Ahmed, Musahid

    2016-05-01

    Tunable vacuum ultraviolet (VUV) radiation coupled to mass spectrometry is applied to the study of complex chemical systems. The identification of novel reactive intermediates and radicals is revealed in flame, pulsed photolysis, and pyrolysis reactors, leading to the elucidation of spectroscopy, reaction mechanisms, and kinetics. Mass-resolved threshold photoelectron photoion coincidence measurements provide unprecedented access to vibrationally resolved spectra of free radicals present in high-temperature reactors. Photoionization measurements in water clusters, nucleic acid base dimers, and their complexes with water provide signatures of proton transfer in hydrogen-bonded and π-stacked systems. Experimental and theoretical methods to track ion-molecule reactions and fragmentation pathways in intermolecular and intramolecular hydrogen-bonded systems in sugars and alcohols are described. Photoionization of laser-ablated molecules, clusters, and their reaction products inform thermodynamics and spectroscopy that are relevant to astrochemistry and catalysis. New directions in coupling VUV radiation to interrogate complex chemical systems are discussed.

  8. Long-lived laser dye

    SciTech Connect

    Fletcher, A.N.

    1986-07-29

    A method is described of obtaining in a flashlamp pumped laser system, a long-lived flashpumped laser dye having a low threshold of lasing and a moderate output comprising the steps of: placing a dye solution comprising a laser dye, the N-methyl tosylate salt of 2-(4-pyridyl)-5-(4-methoxphenyl)oxazole, and a solvent into a laser dye cavity; screening the dye solution from ultraviolet light with an optical filter; flushing the dye solution with an inert gas; and optically pumping the dye solution with a flashlamp to produce laser emission.

  9. 21 CFR 872.6350 - Ultraviolet detector.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 21 Food and Drugs 8 2010-04-01 2010-04-01 false Ultraviolet detector. 872.6350 Section 872.6350...) MEDICAL DEVICES DENTAL DEVICES Miscellaneous Devices § 872.6350 Ultraviolet detector. (a) Identification. An ultraviolet detector is a device intended to provide a source of ultraviolet light which is...

  10. 21 CFR 872.6350 - Ultraviolet detector.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 21 Food and Drugs 8 2012-04-01 2012-04-01 false Ultraviolet detector. 872.6350 Section 872.6350...) MEDICAL DEVICES DENTAL DEVICES Miscellaneous Devices § 872.6350 Ultraviolet detector. (a) Identification. An ultraviolet detector is a device intended to provide a source of ultraviolet light which is...

  11. 21 CFR 872.6350 - Ultraviolet detector.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 21 Food and Drugs 8 2014-04-01 2014-04-01 false Ultraviolet detector. 872.6350 Section 872.6350...) MEDICAL DEVICES DENTAL DEVICES Miscellaneous Devices § 872.6350 Ultraviolet detector. (a) Identification. An ultraviolet detector is a device intended to provide a source of ultraviolet light which is...

  12. 21 CFR 872.6350 - Ultraviolet detector.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 21 Food and Drugs 8 2013-04-01 2013-04-01 false Ultraviolet detector. 872.6350 Section 872.6350...) MEDICAL DEVICES DENTAL DEVICES Miscellaneous Devices § 872.6350 Ultraviolet detector. (a) Identification. An ultraviolet detector is a device intended to provide a source of ultraviolet light which is...

  13. 21 CFR 872.6350 - Ultraviolet detector.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 21 Food and Drugs 8 2011-04-01 2011-04-01 false Ultraviolet detector. 872.6350 Section 872.6350...) MEDICAL DEVICES DENTAL DEVICES Miscellaneous Devices § 872.6350 Ultraviolet detector. (a) Identification. An ultraviolet detector is a device intended to provide a source of ultraviolet light which is...

  14. Laser-assisted solar cell metallization processing

    NASA Technical Reports Server (NTRS)

    Dutta, S.

    1984-01-01

    Laser-assisted processing techniques utilized to produce the fine line, thin metal grid structures that are required to fabricate high efficiency solar cells are examined. Two basic techniques for metal deposition are investigated; (1) photochemical decomposition of liquid or gas phase organometallic compounds utilizing either a focused, CW ultraviolet laser (System 1) or a mask and ultraviolet flood illumination, such as that provided by a repetitively pulsed, defocused excimer laser (System 2), for pattern definition, and (2) thermal deposition of metals from organometallic solutions or vapors utilizing a focused, CW laser beam as a local heat source to draw the metallization pattern.

  15. Ultraviolet studies of Cepheids

    NASA Technical Reports Server (NTRS)

    Boehm-Vitense, Erika

    1992-01-01

    We discuss whether with new evolutionary tracks we still have a problem fitting the Cepheids and their evolved companions on the appropriate evolutionary tracks. We find that with the Bertelli et al. tracks with convective overshoot by one pressure scale height the problem is essentially removed, though somewhat more mixing would give a better fit. By using the results of recent nonlinear hydrodynamic calculations, we find that we also have no problem matching the observed pulsation periods of the Cepheids with those expected from their new evolutionary masses, provided that Cepheids with periods less than 9 days are overtone pulsators. We investigate possible mass loss of Cepheids from UV studies of the companion spectrum of S Mus and from the ultraviolet spectra of the long period Cepheid l Carinae. For S Mus with a period of 9.6 days we derive an upper limit for the mass loss of M less than 10(exp -9) solar mass, if a standard velocity law is assumed for the wind. For l Carinae with a period of 35.5 days we find a probable mass loss of M is approximately 10(exp -5+/-2) solar mass.

  16. Light, Including Ultraviolet

    PubMed Central

    Maverakis, Emanual; Miyamura, Yoshinori; Bowen, Michael P.; Correa, Genevieve; Ono, Yoko; Goodarzi, Heidi

    2009-01-01

    Ultraviolet (UV) light is intricately linked to the functional status of the cutaneous immune system. In susceptible individuals, UV radiation can ignite pathogenic inflammatory pathways leading to allergy or autoimmunity. In others, this same UV radiation can be used as a phototherapy to suppress pathogenic cutaneous immune responses. These vastly different properties are a direct result of UV light’s ability to ionize molecules in the skin and thereby chemically alter them. Sometimes these UV-induced chemical reactions are essential, the formation of pre-vitamin D3 from 7-dehydrocholesterol, for example. In other instances they can be potentially detrimental. UV radiation can ionize a cell’s DNA causing adjacent pyrimidine bases to chemically bond to each other. To prevent malignant transformation, a cell may respond to this UV-induced DNA damage by undergoing apoptosis. Although this pathway prevents skin cancer it also has the potential of inducing or exacerbating autoreactive immune responses by exposing the cell’s nuclear antigens. Ultaviolet-induced chemical reactions can activate the immune system by a variety of other mechanisms as well. In response to UV irradiation keratinocytes secrete cytokines and chemokines, which activate and recruit leukocytes to the skin. In some individuals UV-induced chemical reactions can synthesize novel antigens resulting in a photoallergy. Alternatively, photosensitizing molecules can damage cells by initiating sunburn-like phototoxic reactions. Herein we review all types of UV-induced skin reactions, especially those involving the immune system. PMID:20018479

  17. Higgs ultraviolet softening

    NASA Astrophysics Data System (ADS)

    Brivio, I.; Éboli, O. J. P.; Gavela, M. B.; Gonzalez-García, M. C.; Merlo, L.; Rigolin, S.

    2014-12-01

    We analyze the leading effective operators which induce a quartic momentum dependence in the Higgs propagator, for a linear and for a non-linear realization of electroweak symmetry breaking. Their specific study is relevant for the understanding of the ultraviolet sensitivity to new physics. Two methods of analysis are applied, trading the Lagrangian coupling by: i) a "ghost" scalar, after the Lee-Wick procedure; ii) other effective operators via the equations of motion. The two paths are shown to lead to the same effective Lagrangian at first order in the operator coefficients. It follows a modification of the Higgs potential and of the fermionic couplings in the linear realization, while in the non-linear one anomalous quartic gauge couplings, Higgs-gauge couplings and gauge-fermion interactions are induced in addition. Finally, all LHC Higgs and other data presently available are used to constrain the operator coefficients; the future impact of pp → 4 leptons data via off-shell Higgs exchange and of vector boson fusion data is considered as well. For completeness, a summary of pure-gauge and gauge-Higgs signals exclusive to non-linear dynamics at leading-order is included.

  18. Ultraviolet radiation and cyanobacteria.

    PubMed

    Rastogi, Rajesh Prasad; Sinha, Rajeshwar P; Moh, Sang Hyun; Lee, Taek Kyun; Kottuparambil, Sreejith; Kim, Youn-Jung; Rhee, Jae-Sung; Choi, Eun-Mi; Brown, Murray T; Häder, Donat-Peter; Han, Taejun

    2014-12-01

    Cyanobacteria are the dominant photosynthetic prokaryotes from an ecological, economical, or evolutionary perspective, and depend on solar energy to conduct their normal life processes. However, the marked increase in solar ultraviolet radiation (UVR) caused by the continuous depletion of the stratospheric ozone shield has fueled serious concerns about the ecological consequences for all living organisms, including cyanobacteria. UV-B radiation can damage cellular DNA and several physiological and biochemical processes in cyanobacterial cells, either directly, through its interaction with certain biomolecules that absorb in the UV range, or indirectly, with the oxidative stress exerted by reactive oxygen species. However, cyanobacteria have a long history of survival on Earth, and they predate the existence of the present ozone shield. To withstand the detrimental effects of solar UVR, these prokaryotes have evolved several lines of defense and various tolerance mechanisms, including avoidance, antioxidant production, DNA repair, protein resynthesis, programmed cell death, and the synthesis of UV-absorbing/screening compounds, such as mycosporine-like amino acids (MAAs) and scytonemin. This study critically reviews the current information on the effects of UVR on several physiological and biochemical processes of cyanobacteria and the various tolerance mechanisms they have developed. Genomic insights into the biosynthesis of MAAs and scytonemin and recent advances in our understanding of the roles of exopolysaccharides and heat shock proteins in photoprotection are also discussed.

  19. Ultraviolet Communication for Medical Applications

    DTIC Science & Technology

    2015-06-01

    AWARD NUMBER: W81XWH-12-C-0043 TITLE: Ultraviolet Communication for Medical Applications PRINCIPAL INVESTIGATOR Jeff Guy Directed Energy , Inc...SUPPLEMENTARY NOTES Report contains color. 14. ABSTRACT Under this Phase II SBIR effort, Directed Energy Inc.’s (DEI) proprietary ultraviolet (UV...non-line-of-sight (NLOS) optical communication data links operating in the solar blind region (200–280 nm). The intended application is covert

  20. Influence of the active medium composition on the gain in the 00/sup 0/2--(10/sup 0/1, 02/sup 0/1)/sub I/ band for a TEA CO/sub 2/ laser with ultraviolet preionization

    SciTech Connect

    Bertel', I.M.; Petukhov, V.O.; Trushin, S.A.; Churakov, V.V.

    1982-07-01

    An experimental and theoretical investigation was made of the small-signal gains of lines in the second sequence band, and of the temperature of the asymmetric ..nu../sub 3/ mode of the CO/sub 2/ molecule in a TEA CO/sub 2/ amplifier as a function of the composition of the CO/sub 2/--N/sub 2/--He mixture. The optimal partial pressures of the component were determined. In a TEA CO/sub 2/ amplifier with ultraviolet preionization provided by auxiliary lateral discharges it was found that the maximum gain of approx.0.01 cm/sup -1/ for the 10P(19) line of the second sequence band was achieved in a CO/sub 2/:N/sub 2/:He = 1:1:3 mixture.

  1. Ultraviolet investigations for lunar missions

    USGS Publications Warehouse

    Hemphill, William R.; Fischer, William A.; Dornbach, J.E.; Narin, Francis

    1966-01-01

    Preliminary field tests of an active ultraviolet imaging system have shown that it is possible to produce linages of the terrain from distances as great as 75 feet by means of reflected ultraviolet light at wavelengths longer than 3300 A. Minerals that luminesce when exposed to ultraviolet energy have been detected from distances as great as 200 feet. With appropriate design modifications, it may be possible to utilize a similar system in detecting luminescing minerals from greater distances. Also, with a similar system and appropriate auxiliary equipment such as image intensifiers, it may be possible to discriminate between naturally occurring materials on the basis of reflected ultraviolet energy at wavelengths shorter than 3000 A. In this part of the spectrum image contrast for some rock types may exceed that from visible light. Information from these and related ultraviolet spectralanalysis studies may be useful in evaluating data obtained from passive ultraviolet systems in lunar orbit as well as from active systems on the lunar surface.

  2. X-ray lasers. Citations from the International Aerospace Abstracts data base

    NASA Technical Reports Server (NTRS)

    Mauk, S. C.

    1980-01-01

    Various aspects of X-ray lasers are discussed in approximately 122 citations. Included are laser plasmas and outputs, plasma radiation, far ultraviolet radiation, gamma rays, optical pumping, optical resonators, and electron transitions. Laser applications, laser materials, and laser fusion are also included.

  3. Microbiological estimate of parodontitis laser therapy efficiency

    NASA Astrophysics Data System (ADS)

    Mamedova, F. M.; Akbarova, Ju. A.; Bajenov, L. G.; Arslanbekov, T. U.

    1995-04-01

    In this work was carried out microbiological estimate the efficiency of ultraviolet and He-Ne laser radiation at the treatment of parodontitis. 90 persons was investigated with parodontitis of middle serious diagnosis. The optimal regimes of ultraviolet radiation influence on various micro-organisms discharged from pathologic tooth pocket (PTP) were determined. On the base of specils microflora composition study and data of microbic PTP dissemination owe may conclude that the complex He- Ne and ultraviolet laser radiation show the most pronounced antimicrobic effect.

  4. Modelling ultraviolet threats

    NASA Astrophysics Data System (ADS)

    James, I.

    2016-10-01

    Electro-optically (EO) guided surface to air missiles (SAM) have developed to use Ultraviolet (UV) wavebands supplementary to the more common Infrared (IR) wavebands. Missiles such as the US Stinger have been around for some time but are not considered a proliferation risk. The Chinese FN-16 and Russian SA-29 (Verba) are considered a much higher proliferation risk. As a result, models of the missile seekers must be developed to understand the characteristics of the seeker and the potential performance enhancement that are included. Therefore, the purpose of this paper is to introduce the steps that have been taken to characterise and model these missiles. It begins by outlining some of the characteristics of the threats, the key elements of a UV scene, the potential choice of waveband for a detector, the initial modelling work to represent the UV detector of the missile and presents initial results. The modelling shows that the UV detection range of a typical aircraft is dependent on both the size of the aircraft and its reflectivity. However, the strength of this correlation is less than expected. As a result, further work is required to model more seeker types and to investigate what is causing the weak correlations found in these initial investigations. In addition, there needs to be further study of the sensitivities of the model to other variables, such as the modelled detectivity of the detector and the signal to noise ratio assumed. Overall, the outcome of this work will be to provide specifications for aircraft size and reflectivity that limit the effectiveness of the UV channels.

  5. Far Ultraviolet Astronomy

    NASA Technical Reports Server (NTRS)

    Sonneborn, George; Rabin, Douglas M. (Technical Monitor)

    2002-01-01

    The Far Ultraviolet Spectroscopic Explorer (FUSE) is studying a wide range of astronomical problems in the 905-1187 Angstrom wavelength region through the use of high resolution spectroscopy. The FUSE bandpass forms a nearly optimal complement to the spectral coverage provided by the Hubble Space Telescope (HST), which extends down to approximately 1170 Angstroms. The photoionization threshold of atomic hydrogen (911 Angstroms) sets a natural short-wavelength limit for the FUV. FUSE was launched in June 1999 from Cape Canaveral, Florida, on a Delta II rocket into a 768 km circular orbit. Scientific observations started later that year. This spectral region is extremely rich in spectral diagnostics of astrophysical gases over a wide range of temperatures (100 K to over 10 million K). Important strong spectral lines in this wavelength range include those of neutral hydrogen, deuterium, nitrogen, oxygen, and argon (H I, D I, N I, O I, and Ar I), molecular hydrogen (H2), five-times ionized oxygen (O VI), and several ionization states of sulfur (S III - S VI). These elements are essential for understanding the origin and evolution of the chemical elements, the formation of stars and our Solar System, and the structure of galaxies, including our Milky Way. FUSE is one of NASA's Explorer missions and a cooperative project of NASA and the space agencies of Canada and France. These missions are smaller, more scientifically focused missions than the larger observatories, like Hubble and Chandra. FUSE was designed, built and operated for NASA by the Department of Physics and Astronomy at Johns Hopkins University. Hundreds of astronomers world-wide are using FUSE for a wide range of scientific research. Some of the important scientific discoveries from the first two years of the mission are described.

  6. National Ignition Facility and Managing Location, Component, and State

    SciTech Connect

    Foxworthy, C; Fung, T; Beeler, R; Li, J; Dugorepec, J; Chang, C

    2011-07-25

    The National Ignition Facility (NIF) at the Lawrence Livermore National Laboratory is a stadium-sized facility that contains a 192-beam, 1.8-Megajoule, 500-Terawatt, ultraviolet laser system coupled with a 10-meter diameter target chamber. There are over 6,200 Line Replaceable Units (LRUs) comprised of more than 104,000 serialized parts that make up the NIF. Each LRU is a modular unit typically composed of a mechanical housing, laser optics (glass, lenses, or mirrors), and utilities. To date, there are more than 120,000 data sets created to characterize the attributes of these parts. Greater than 51,000 Work Permits have been issued to install, maintain, and troubleshoot the components. One integrated system is used to manage these data, and more. The Location Component and State (LoCoS) system is a web application built using Java Enterprise Edition technologies and is accessed by over 1,200 users. It is either directly or indirectly involved with each aspect of NIF work activity, and interfaces with ten external systems including the Integrated Computer Control System (ICCS) and the Laser Performance Operations Model (LPOM). Besides providing business functionality, LoCoS also acts as the NIF enterprise service bus. In this role, numerous integration approaches had to be adopted including: file exchange, database sharing, queuing, and web services in order to accommodate various business, technical, and security requirements. Architecture and implementation decisions are discussed.

  7. Extreme ultraviolet reflector

    DOEpatents

    Newnam, Brian E.

    1990-01-01

    A multi-faceted mirror forms a retroreflector for a resonator loop in a free electron laser (FEL) operating in the XUV (.lambda.=10-100 nm). The number of facets is determined by the angle-of-incidence needed to obtain total external reflectance (TER) from the facet surface and the angle through which the FEL beam is to be turned. Angles-of-incidence greater than the angle for TER may be used to increase the area of the beam incident on the surface and reduce energy absorption density. Suitable surface films having TER in the 10-100 nm range may be formed from a variety of materials, including Al, single-crystal Si, Ag, and Rh. One of the facets is formed as an off-axis conic section to collimate the output beam with minimum astigmatism.

  8. Future Directions in Ultraviolet Spectroscopy

    NASA Technical Reports Server (NTRS)

    Sonneborn, George (Editor); Moos, Warren; VanSteenberg, Michael

    2009-01-01

    The 'Future Directions in Ultraviolet Spectroscopy' conference was inspired by the accomplishments of the Far Ultraviolet Spectroscopic Explorer (FUSE) Mission. The FUSE mission was launched in June 1999 and spent over eight years exploring the far-ultraviolet universe, gathering over 64 million seconds of high-resolution spectral data on nearly 3000 astronomical targets. The goal of this conference was not only to celebrate the accomplishments of FUSE, but to look toward the future and understand the major scientific drivers for the ultraviolet capabilities of the next generation fo space observatories. Invited speakers presented discussions based on measurements made by FUSE and other ultraviolet instruments, assessed their connection with measurements made with other techniques and, where appropriate, discussed the implications of low-z measurements for high-z phenomena. In addition to the oral presentations, many participants presented poster papers. The breadth of these presentation made it clear that much good science is still in progress with FUSE data and that these result will continue to have relevance in many scientific areas.

  9. Harmful effects of ultraviolet radiation

    SciTech Connect

    Not Available

    1989-07-21

    Tanning for cosmetic purposes by sunbathing or by using artificial tanning devices is widespread. The hazards associated with exposure to ultraviolet radiation are of concern to the medical profession. Depending on the amount and form of the radiation, as well as on the skin type of the individual exposed, ultraviolet radiation causes erythema, sunburn, photodamage (photoaging), photocarcinogenesis, damage to the eyes, alteration of the immune system of the skin, and chemical hypersensitivity. Skin cancers most commonly produced by ultraviolet radiation are basal and squamous cell carcinomas. There also is much circumstantial evidence that the increase in the incidence of cutaneous malignant melanoma during the past half century is related to increased sun exposure, but this has not been proved. Effective and cosmetically acceptable sunscreen preparations have been developed that can do much to prevent or reduce most harmful effects to ultraviolet radiation if they are applied properly and consistently. Other safety measures include (1) minimizing exposure to ultraviolet radiation, (2) being aware of reflective surfaces while in the sun, (3) wearing protective clothing, (4) avoiding use of artificial tanning devices, and (5) protecting infants and children.

  10. NASA Space Laser Technology

    NASA Technical Reports Server (NTRS)

    Krainak, Michael A.

    2015-01-01

    Over the next two decades, the number of space based laser missions for mapping, spectroscopy, remote sensing and other scientific investigations will increase several fold. The demand for high wall-plug efficiency, low noise, narrow linewidth laser systems to meet different systems requirements that can reliably operate over the life of a mission will be high. The general trends will be for spatial quality very close to the diffraction limit, improved spectral performance, increased wall-plug efficiency and multi-beam processing. Improved spectral performance will include narrower spectral width (very near the transform limit), increased wavelength stability and or tuning (depending on application) and lasers reaching a wider range of wavelengths stretching into the mid-infrared and the near ultraviolet. We are actively developing high efficiency laser transmitter and high-sensitivity laser receiver systems that are suitable for spaceborne applications.

  11. Silicon Nanocrystal Laser

    SciTech Connect

    Yu, J

    2005-03-09

    The purpose of this feasibility study project was to attempt to demonstrate the silicon-nanocrystal-based laser. Such a silicon laser (made using conventional silicon-manufacturing technologies) would provide the crucial missing link that would enable a completely-silicon-based photonic system. We prepared thin layers of silicon nanocrystal material by ion-implanting Si in fused silica substrates, followed by a high temperature anneal process. These Si nanocrystals produced intense photoluminescence when optically pumped with ultraviolet light. Laser structures based on Fabry-Perot cavity and distributed feedback (DFB) designs were fabricated using the Si nanocrystals as the ''lasing'' medium. We optically pumped the samples with CW lasers at 413nm wavelength to quickly assess the feasibility of making lasers out of the Nanocrystal Si material and to verify the gain coefficients reported by other research groups.

  12. Ultraviolet-radiation-curable paints

    SciTech Connect

    Grosset, A M; Su, W F.A.; Vanderglas, E

    1981-09-30

    In product finishing lines, ultraviolet radiation curing of paints on prefabricated structures could be more energy efficient than curing by natural gas fired ovens, and could eliminate solvent emission. Diffuse ultraviolet light can cure paints on three dimensional metal parts. In the uv curing process, the spectral output of radiation sources must complement the absorption spectra of pigments and photoactive agents. Photosensitive compounds, such as thioxanthones, can photoinitiate unsaturated resins, such as acrylated polyurethanes, by a free radical mechanism. Newly developed cationic photoinitiators, such as sulfonium or iodonium salts (the so-called onium salts) of complex metal halide anions, can be used in polymerization of epoxy paints by ultraviolet light radiation. One-coat enamels, topcoats, and primers have been developed which can be photoinitiated to produce hard, adherent films. This process has been tested in a laboratory scale unit by spray coating these materials on three-dimensional objects and passing them through a tunnel containing uv lamps.

  13. Ultraviolet spectrophotometry of three LINERs

    NASA Technical Reports Server (NTRS)

    Goodrich, R. W.; Keel, W. C.

    1986-01-01

    Three galaxies known to be LINERs were observed spectroscopically in the ultraviolet in an attempt to detect the presumed nonthermal continuum source thought to be the source of photoionization in the nuclei. NGC 4501 was found to be too faint for study with the IUE spectrographs, while NGC 5005 had an extended ultraviolet light profile. Comparison with the optical light profile of NGC 5005 indicates that the ultraviolet source is distributed spatially in the same manner as the optical starlight, probably indicating that the ultraviolet excess is due to a component of hot stars in the nucleus. These stars contribute detectable absorption features longward of 2500 A; together with optical data, the IUE spectra suggest a burst of star formation about 1 billion yr ago, with a lower rate continuing to produce a few OB stars. In NGC 4579, a point source contributing most of the ultraviolet excess is found that is much different than the optical light distribution. Furthermore, the ultraviolet to X-ray spectral index in NGC 4579 is 1.4, compatible with the UV to X-ray indices found for samples of Seyfert galaxies. This provides compelling evidence for the detection of the photoionizing continuum in NGC 4579 and draws the research fields of normal galaxies and active galactic nuclei closer together. The emission-line spectrum of NGC 4579 is compared with calculations from a photoionization code, CLOUDY, and several shock models. The photoionization code is found to give superior results, adding to the increasing weight of evidence that the LINER phenomenon is essentially a scaled-down version of the Seyfert phenomenon.

  14. Ultraviolet corona detection sensor study

    NASA Technical Reports Server (NTRS)

    Schmitt, R. J.; MATHERN

    1976-01-01

    The feasibility of detecting electrical corona discharge phenomena in a space simulation chamber via emission of ultraviolet light was evaluated. A corona simulator, with a hemispherically capped point to plane electrode geometry, was used to generate corona glows over a wide range of pressure, voltage, current, electrode gap length and electrode point radius. Several ultraviolet detectors, including a copper cathode gas discharge tube and a UV enhanced silicon photodiode detector, were evaluated in the course of the spectral intensity measurements. The performance of both silicon target vidicons and silicon intensified target vidicons was evaluated analytically using the data generated by the spectroradiometer scans and the performance data supplied by the manufacturers.

  15. Application of lasers in endodontics

    NASA Astrophysics Data System (ADS)

    Ertl, Thomas P.; Benthin, Hartmut; Majaron, Boris; Mueller, Gerhard J.

    1997-12-01

    Root canal treatment is still a problem in dentistry. Very often the conventional treatment fails and several treatment sessions are necessary to save the tooth from root resection or extraction. Application of lasers may help in this situation. Bacteria reduction has been demonstrated both in vitro and clinically and is either based on laser induced thermal effects or by using an ultraviolet light source. Root canal cleansing is possible by Er:YAG/YSGG-Lasers, using the hydrodynamic motion of a fluid filled in the canals. However root canal shaping using lasers is still a problem. Via falsas and fiber breakage are points of research.

  16. Ultraviolet avalanche photodiodes

    NASA Astrophysics Data System (ADS)

    McClintock, Ryan; Razeghi, Manijeh

    2015-08-01

    The III-Nitride material system is rapidly maturing; having proved itself as a material for LEDs and laser, and now finding use in the area of UV photodetectors. However, many UV applications are still dominated by the use of photomultiplier tubes (PMT). PMTs are capable of obtaining very high sensitivity using internal electron multiplication gain (typically ~106). It is highly desirable to develop a compact semiconductor-based photodetector capable of realizing this level of sensitivity. In principle, this can be obtained in III-Nitrides by taking advantage of avalanche multiplication under high electric fields - typically 2.7 MV/cm, which with proper design can correspond to an external reverse bias of less than 100 volts. In this talk, we review the current state-of-the-art in III-Nitride solar- and visible-blind APDs, and present our latest results on GaN APDs grown on both conventional sapphire and low dislocation density free-standing c- and m-plane GaN substrates. Leakage current, gain, and single photon detection efficiency (SPDE) of these APDs were compared. The spectral response and Geiger-mode photon counting performance of UV APDs are studied under low photon fluxes, with single photon detection capabilities as much as 30% being demonstrated in smaller devices. Geiger-mode operation conditions are optimized for enhanced SPDE.

  17. Structural characterization of native high-methoxylated pectin using nuclear magnetic resonance spectroscopy and ultraviolet matrix-assisted laser desorption/ionization time-of-flight mass spectrometry. Comparative use of 2,5-dihydroxybenzoic acid and nor-harmane as UV-MALDI matrices.

    PubMed

    Monge, María Eugenia; Negri, R Martín; Kolender, Adriana A; Erra-Balsells, Rosa

    2007-01-01

    The successful analysis by ultraviolet matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (UV-MALDI-TOF MS) of native and hydrolyzed high-methoxylated pectin samples is described. In order to find the optimal conditions for UV-MALDI-TOF MS analysis several experimental variables were studied such as: different UV-MALDI matrices (nor-harmane, 2,5-dihydroxybenzoic acid), sample preparation methods (mixture, sandwich), inorganic salt addition (doping salts, NaCl, KCl, NH(4)Cl), ion mode (positive, negative), linear and reflectron mode, etc. nor-Harmane has never been used as a UV-MALDI matrix for the analysis of pectins but its use avoids pre-treatment of the sample, such as an enzymatic digestion or an acid hydrolysis, and there is no need to add salts, making the analysis easier and faster. This study suggested an alternative way of analyzing native high-methoxylated pectins, with UV-MALDI-TOF MS, by using nor-harmane as the matrix in negative ion mode. The analysis by (1)H and (13)C nuclear magnetic resonance (NMR) spectroscopy of the native and hydrolyzed pectin is also briefly described.

  18. Time-resolved infrared diode laser spectroscopy of the ν3 band of the jet-cooled Fe(CO)2 radical produced by ultraviolet photolysis of Fe(CO)5

    NASA Astrophysics Data System (ADS)

    Tanaka, Keiichi; Tachikawa, Yasuhisa; Sakaguchi, Kouichi; Hikida, Toshihide; Tanaka, Takehiko

    1999-09-01

    The infrared spectrum of the iron dicarbonyl radical Fe(CO)2 produced in a supersonic jet expansion by the excimer laser photolysis of iron pentacarbonyl Fe(CO)5 was observed by time-resolved infrared diode laser spectroscopy. About 170 transitions, each split into one or two fine structure components, were assigned to the ν3 (CO antisymmetric stretch) band of Fe(CO)2. The assignment was greatly facilitated by spectral simplification caused by rotational as well as vibrational cooling in the supersonic jet. It was observed that lines are missing at alternate J quantum numbers in each spin component, which confirmed that Fe(CO)2 is a linear molecule with D∞h symmetry and that the electronic ground state is of 3Σg- symmetry. The rotational and centrifugal distortion constants in the ground state were determined to be B0=1414.675(46) MHz and D0=0.3077(74) kHz, respectively. The spin-spin interaction constants obtained, λ0=655.3(42) GHz, is comparable with that of the FeCO radical, λ0=684.470(51) GHz. The ν3 band origin was determined to be 1928.184335 (82) cm-1. The figures in parentheses are uncertainties (1σ) in units of the last digit.

  19. Bright subcycle extreme ultraviolet bursts from a single dense relativistic electron sheet.

    PubMed

    Ma, W J; Bin, J H; Wang, H Y; Yeung, M; Kreuzer, C; Streeter, M; Foster, P S; Cousens, S; Kiefer, D; Dromey, B; Yan, X Q; Meyer-ter-Vehn, J; Zepf, M; Schreiber, J

    2014-12-05

    Double-foil targets separated by a low density plasma and irradiated by a petawatt-class laser are shown to be a copious source of coherent broadband radiation. Simulations show that a dense sheet of relativistic electrons is formed during the interaction of the laser with the tenuous plasma between the two foils. The coherent motion of the electron sheet as it transits the second foil results in strong broadband emission in the extreme ultraviolet, consistent with our experimental observations.

  20. Tunable, rare earth-doped solid state lasers

    DOEpatents

    Emmett, John L.; Jacobs, Ralph R.; Krupke, William F.; Weber, Marvin J.

    1980-01-01

    Laser apparatus comprising combinations of an excimer pump laser and a rare earth-doped solid matrix, utilizing the 5d-4f radiative transition in a rare earth ion to produce visible and ultra-violet laser radiation with high overall efficiency in selected cases and relatively long radiative lifetimes.

  1. Ultraviolet, visible, and infrared rays

    NASA Technical Reports Server (NTRS)

    Taylor, J. H.; Letavet, A. A.

    1975-01-01

    Sources of infrared, visible and ultraviolet radiation are discussed, and important associated biological and psychophysiological effects are described. The problem of protection from excessively high or low levels of radiant energy in these spectral regions is considered and optimal levels are suggested.

  2. Ultraviolet and Light Absorption Spectrometry.

    ERIC Educational Resources Information Center

    Hargis, L. G.; Howell, J. A.

    1984-01-01

    Reviews developments in ultraviolet and light absorption spectrometry from December 1981 through November 1983, focusing on the chemistry involved in developing suitable reagents, absorbing systems, and methods of determination, and on physical aspects of the procedures. Includes lists of spectrophotometric methods for metals, non-metals, and…

  3. A vacuum ultraviolet spectrophotometric system

    NASA Technical Reports Server (NTRS)

    Spann, James F.; Keffer, Charles E.; Zukic, Muamer

    1993-01-01

    The development of a vacuum ultraviolet spectrophotometric system for measuring transmittance and reflectance at variable angles is presented. Using various detectors and sources, the spectrophotometric system has been used for wavelengths from 80 nm to 300 nm with optical components up to 80 mm in diameter. The capability exists to make measurements through the visible range.

  4. Electrically tunable selective reflection of light from ultraviolet to visible and infrared by heliconical cholesterics.

    PubMed

    Xiang, Jie; Li, Yannian; Li, Quan; Paterson, Daniel A; Storey, John M D; Imrie, Corrie T; Lavrentovich, Oleg D

    2015-05-20

    Electrical tuning of selective reflection of light is achieved in a very broad spectral range from ultraviolet to visible and infrared by an oblique helicoidal state of a cholesteric liquid crystal in a wide temperature range (including room temperature). The phenomenon offers potential applications in tunable smart windows, lasers, optical filters and limiters, as well as in displays.

  5. Design of an ultraviolet fluorescence lidar for biological aerosol detection

    NASA Astrophysics Data System (ADS)

    Rao, Zhimin; Hua, Dengxin; He, Tingyao; Le, Jing

    2016-09-01

    In order to investigate the biological aerosols in the atmosphere, we have designed an ultraviolet laser induced fluorescence lidar based on the lidar measuring principle. The fluorescence lidar employs a Nd:YAG laser of 266 nm as an excited transmitter, and examines the intensity of the received light at 400 nm for biological aerosol concentration measurements. In this work, we firstly describe the designed configuration and the simulation to estimate the measure range and the system resolution of biological aerosol concentration under certain background radiation. With a relative error of less than 10%, numerical simulations show the system is able to monitor biological aerosols within detected distances of 1.8 km and of 7.3 km in the daytime and nighttime, respectively. Simulated results demonstrate the designed fluorescence lidar is capable to identify a minimum concentration of biological aerosols at 5.0×10-5 ppb in the daytime and 1.0×10-7 ppb in the nighttime at the range of 0.1 km. We believe the ultraviolet laser induced fluorescence lidar can be spread in the field of remote sensing of biological aerosols in the atmosphere.

  6. Laser Remote Sensing at NASA

    NASA Technical Reports Server (NTRS)

    Barnes, Norman P.

    2005-01-01

    NASA is developing active remote sensors to monitor the health of Planet Earth and for exploration of other planets. Development and deployment of these remote sensors can have a huge economic impact. Lasers for these active remote sensors span the spectral range from the ultraviolet to the mid infrared spectral regions. Development activities range from quantum mechanical modeling and prediction of new laser materials to the design, development, and demonstration be deployed in the field.

  7. Comparative Study of Ultraviolet Laser-Based Time-Resolved Photoacoustic Fingerprint Spectra and Thermal Decomposition Mechanisms of Energetic 1,2,3-1H-Triazole Derivatives Under Controlled Pyrolysis.

    PubMed

    Rao, Konda Srinivasa; Chaudhary, Anil Kumar

    2017-01-01

    We report the comparative study of photoacoustic (PA) fingerprint spectra, thermal decomposition, and stability mechanism of some phenyl and bis series energetic compounds named 1-(2-methoxy,-3,5-dinitrophenyl)-1H-1,2,3-triazole ( S5), 1-(3-methoxy, 2, 6 dinitrophenyl) 1H-1, 2, 3 triazole ( S10), 1-(4-nitrophenyl)-1H-1,2,3-triazole ( S8), and 2,6-bis ((4-(nitromethyl)-1H-1,2,3-triazol-1-yl)methyl) pyridine ( S9). Fourth harmonic wavelength, i.e., 266 nm of pulse duration 7 ns and 10 Hz repetition rate obtained from Q-switched Nd: YAG laser, was used to record the thermal PA spectra of these compounds under controlled pyrolysis condition in the range of 30-350 ℃. The PA fingerprint spectra are produced due to entire molecule vapor along with principal functional byproduct NO2 molecule. NO2 molecule is a major gas released during thermal decomposition due to weakest nature of C-NO2 bond. Further, NO2 molecules are involved in photodissociation process due to π*← n transition and converted into NO molecules inside the PA cell due to excitation by 266 nm wavelength. The combined results of PA and gas chromatography-mass spectrometry (GC-MS) spectra along with thermo gravimetric-differential thermal analysis (TG-DTA) data confirm the thermal decomposition mechanism process that can be completed in multiple steps. In addition, GC-MS spectra also confirm the release of NO and NO2 molecules. The effect of incident laser energy and data acquisition time has been carried out for understanding the behavior of acoustic modes. Finally, the thermal quality factor "Q" is measured to test the stability of compounds.

  8. Extreme ultraviolet spectrometer based on a transmission electron microscopy grid

    DOE PAGES

    Sistrunk, Emily; Gühr, Markus

    2014-12-12

    Here, we performed extreme ultraviolet spectroscopy using an 80 lines/mm transmission electron microscope mesh as the dispersive element. We also present the usefulness of this instrument for dispersing a high harmonic spectrum from the 13th to the 29th harmonic of a Ti:sapph laser, corresponding to a wavelength range from 60 to 27 nm. The resolution of the instrument is limited by the image size of the high harmonic generation region on the detector. Finally, the resolution in first order diffraction is under 2 nm over the entire spectral range with a resolving power around 30.

  9. Characteristics of extreme ultraviolet emission from high-Z plasmas

    NASA Astrophysics Data System (ADS)

    Ohashi, H.; Higashiguchi, T.; Suzuki, Y.; Kawasaki, M.; Suzuki, C.; Tomita, K.; Nishikino, M.; Fujioka, S.; Endo, A.; Li, B.; Otsuka, T.; Dunne, P.; O'Sullivan, G.

    2016-03-01

    We demonstrate the extreme ultraviolet (EUV) and soft x-ray sources in the 2 to 7 nm spectral region related to the beyond EUV (BEUV) question at 6.x nm and the water window source based on laser-produced high-Z plasmas. Resonance emission from multiply charged ions merges to produce intense unresolved transition arrays (UTAs), extending below the carbon K edge (4.37 nm). An outline of a microscope design for single-shot live cell imaging is proposed based on high-Z plasma UTA source, coupled to multilayer mirror optics.

  10. Laser dye technology

    SciTech Connect

    Hammond, P R

    1999-09-01

    The author has worked with laser dyes for a number of years. A first interest was in the Navy blue-green program where a flashlamp pumped dye laser was used as an underwater communication and detection device. It made use of the optical window of sea-water--blue for deep ocean, green for coastal water. A major activity however has been with the Atomic Vapor Laser Isotope Separation Program (AVLIS) at the Lawrence Livermore National Laboratory. The aim here has been enriching isotopes for the nuclear fuel cycle. The tunability of the dye laser is utilized to selectively excite one isotope in uranium vapor, and this isotope is collected electrostatically as shown in Figure 1. The interests in the AVLIS program have been in the near ultra-violet, violet, red and deep-red.

  11. CHRONICLE: Fifth International Conference on Laser Spectroscopy (Jasper Park Lodge, Canada, June 29-July 3, 1981)

    NASA Astrophysics Data System (ADS)

    Grasyuk, Arkadii Z.; Kryukov, P. G.

    1983-01-01

    A review is given of papers presented at the Fifth International Conference on Laser Spectroscopy. The main topics at the Conference were: fundamental applications of laser spectroscopy; applications of lasers in spectroscopy; double resonance; collisional phenomena; nonlinear processes; Rydberg states; methods for investigating unstable states; cooling, trapping, and control of motion of atoms and molecules; surfaces and solids; vacuum ultraviolet; development of new lasers.

  12. Indirect Ultraviolet-Reactivation of Phage λ

    PubMed Central

    George, Jacqueline; Devoret, Raymond; Radman, Miroslav

    1974-01-01

    When an F- recipient Escherichia coli K12 bacterium receives Hfr or F-lac+ DNA from an ultraviolet-irradiated donor, its capacity to promote DNA repair and mutagenesis of ultraviolet-damaged phage λ is substantially increased. We call this phenomenon indirect ultraviolet-reactivation, since its features are essentially the same as those of ultraviolet-reactivation; this repair process occurs in pyrimidine dimer excision-deficient strains and produces clear plaque mutations of the restored phage. Moreover, this process is similar to indirect ultraviolet-induction of prophage λ, since it is promoted by conjugation. However, contrarily to indirect induction, it is produced by Hfr donors and occurs in recipients restricting the incoming ultraviolet-damaged donor DNA. The occurrence of indirect ultraviolet-reactivation provides evidence for the existence in E. coli of an inducible error-prone mechanism for the repair of DNA. PMID:4589889

  13. Dissociation of biomolecules using a ultraviolet matrix-assisted laser desorption/ionisation time-of-flight/curved field reflectron tandem mass spectrometer equipped with a differential-pumped collision cell.

    PubMed

    Belgacem, Omar; Bowdler, Andrew; Brookhouse, Ian; Brancia, Francesco L; Raptakis, Emmanuel

    2006-01-01

    A commercial matrix-assisted laser desorption/ionisation time-of-flight (MALDI-ToF) instrument equipped with a curved field reflectron (CFR) was modified in order to perform collision-induced dissociation (CID) on a variety of biomolecules. The incorporation of a high-resolution ion gate together with a collision cell within the field-free region allowed tandem mass analysis (MS/MS), without the necessity to decelerate the precursor ions prior to activation. The simultaneous detection of all product ions remained possible by using the CFR. To test the MS/MS performances, ACTH (fragment 1-17), a complex high mannose carbohydrate (Man)(8)(GlcNac)(2) and a lysophosphatidylcholine lipid (18:1) were analysed on the modified instrument. Direct comparison with the low-energy product ion spectra, acquired on a MALDI quadrupole ion trap (QIT) two-stage reflectron time-of flight (ReToF) mass spectrometer, showed significant differences in the types of product ions observed. The additional ions detected were a clear indication of the high-energy fragmentation processes occurring in the collision cell.

  14. Laser Cooling With Ultrafast Pulse Trains

    DTIC Science & Technology

    2005-09-30

    stabilized a high -repetition- rate mode-locked laser appropriate for demonstrating the cooling technique. We searched for the two-photon transition...mode-locked light in the deep ultraviolet to drive two-photon scattering at high rates . Sufficient cooling forces can only be generated at high powers ...low as 270 mK. We also constructed a high -repetition- rate mode-locked laser suitable for demonstrating our cooling technique and stabilized the laser

  15. Ultraviolet photofragmentation of biomolecular ions

    PubMed Central

    Reilly, James P.

    2009-01-01

    Mass spectrometric identification of all types of molecules relies on the observation and interpretation of ion fragmentation patterns. Peptides, proteins, carbohydrates and nucleic acids that are often found as components of complex biological samples represent particularly important challenges. The most common strategies for fragmenting biomolecular ions include low- and high-energy collisional activation, post-source decay, and electron capture or transfer dissociation. Each of these methods has its own idiosyncrasies and advantages but encounters problems with some types of samples. Novel fragmentation methods that can offer improvements are always desirable. One approach that has been under study for years but is not yet incorporated into a commercial instrument is ultraviolet photofragmentation. This review discusses experimental results on various biological molecules that have been generated by several research groups using different light wavelengths and mass analyzers. Work involving short-wavelength vacuum ultraviolet light is particularly emphasized. The characteristics of photofragmentation are examined and its advantages summarized. PMID:19241462

  16. International Ultraviolet Explorer Observatory operations

    NASA Technical Reports Server (NTRS)

    1985-01-01

    This volume contains the final report for the International Ultraviolet Explorer IUE Observatory Operations contract. The fundamental operational objective of the International Ultraviolet Explorer (IUE) program is to translate competitively selected observing programs into IUE observations, to reduce these observations into meaningful scientific data, and then to present these data to the Guest Observer in a form amenable to the pursuit of scientific research. The IUE Observatory is the key to this objective since it is the central control and support facility for all science operations functions within the IUE Project. In carrying out the operation of this facility, a number of complex functions were provided beginning with telescope scheduling and operation, proceeding to data processing, and ending with data distribution and scientific data analysis. In support of these critical-path functions, a number of other significant activities were also provided, including scientific instrument calibration, systems analysis, and software support. Routine activities have been summarized briefly whenever possible.

  17. Interstellar extinction in the ultraviolet

    NASA Technical Reports Server (NTRS)

    Bless, R. C.; Savage, B. D.

    1972-01-01

    Interstellar extinction curves over the region 3600-1100 A for 17 stars are presented. The observations were made by the two Wisconsin spectrometers onboard the OAO-2 with spectral resolutions of 10 A and 20 A. The extinction curves generally show a pronounced maximum at 2175 plus or minus 25 A, a broad minimum in the region 1800-1350 A, and finally a rapid rise to the far ultraviolet. Large extinction variations from star to star are found, especially in the far ultraviolet; however, with only two possible exceptions in this sample, the wavelength at the maximum of the extinction bump is essentially constant. These data are combined with visual and infrared observations to display the extinction behavior over a range in wavelength of about a factor of 20.

  18. Ultraviolet, optical and infrared astronomy

    NASA Astrophysics Data System (ADS)

    Wampler, E. J.

    1982-11-01

    The principal scientific currents in ultraviolet, optical, and infrared astronomy are discussed, with detailed descriptions of the major recommendations of the Panel on Ultraviolet, Optical and Infrared Astronomy of the National Academy of Sciences' Astronomy Survey Committee. The task of this panel was to survey progress and capabilities and to set priorities for new instrumentation in those branches of astronomy devoted to collecting and analyzing the information carried by cosmic photons with wavelengths between about 100 angstroms and 1 mm. It is pointed out that the best astronomical site in the U.S., the 14,000-foot-high summit of Mauna Kea, Hawaii, now has more square meters of telescope aperture operated by French, Canadian, and English groups than by U.S. groups. The panel named two instruments as major components of the programs for the 1980s. These are the Space Telescope and the Shuttle Infrared Telescope Facility.

  19. Ultraviolet-Resistant Bacterial Spores

    NASA Technical Reports Server (NTRS)

    Venkateswaran, Kasthuri; Newcombe, David; LaDuc, Myron T.; Osman, Shariff R.

    2007-01-01

    A document summarizes a study in which it was found that spores of the SAFR-032 strain of Bacillus pumilus can survive doses of ultraviolet (UV) radiation, radiation, and hydrogen peroxide in proportions much greater than those of other bacteria. The study was part of a continuing effort to understand the survivability of bacteria under harsh conditions and develop means of sterilizing spacecraft to prevent biocontamination of Mars that could interfere with the search for life there.

  20. Ultraviolet surprise: Efficient soft x-ray high-harmonic generation in multiply ionized plasmas.

    PubMed

    Popmintchev, Dimitar; Hernández-García, Carlos; Dollar, Franklin; Mancuso, Christopher; Pérez-Hernández, Jose A; Chen, Ming-Chang; Hankla, Amelia; Gao, Xiaohui; Shim, Bonggu; Gaeta, Alexander L; Tarazkar, Maryam; Romanov, Dmitri A; Levis, Robert J; Gaffney, Jim A; Foord, Mark; Libby, Stephen B; Jaron-Becker, Agnieszka; Becker, Andreas; Plaja, Luis; Murnane, Margaret M; Kapteyn, Henry C; Popmintchev, Tenio

    2015-12-04

    High-harmonic generation is a universal response of matter to strong femtosecond laser fields, coherently upconverting light to much shorter wavelengths. Optimizing the conversion of laser light into soft x-rays typically demands a trade-off between two competing factors. Because of reduced quantum diffusion of the radiating electron wave function, the emission from each species is highest when a short-wavelength ultraviolet driving laser is used. However, phase matching--the constructive addition of x-ray waves from a large number of atoms--favors longer-wavelength mid-infrared lasers. We identified a regime of high-harmonic generation driven by 40-cycle ultraviolet lasers in waveguides that can generate bright beams in the soft x-ray region of the spectrum, up to photon energies of 280 electron volts. Surprisingly, the high ultraviolet refractive indices of both neutral atoms and ions enabled effective phase matching, even in a multiply ionized plasma. We observed harmonics with very narrow linewidths, while calculations show that the x-rays emerge as nearly time-bandwidth-limited pulse trains of ~100 attoseconds.

  1. The Ultraviolet Surprise. Efficient Soft X-Ray High Harmonic Generation in Multiply-Ionized Plasmas

    DOE PAGES

    Popmintchev, Dimitar; Hernandez-Garcia, Carlos; Dollar, Franklin; ...

    2015-12-04

    High-harmonic generation is a universal response of matter to strong femtosecond laser fields, coherently upconverting light to much shorter wavelengths. Optimizing the conversion of laser light into soft x-rays typically demands a trade-off between two competing factors. Reduced quantum diffusion of the radiating electron wave function results in emission from each species which is highest when a short-wavelength ultraviolet driving laser is used. But, phase matching—the constructive addition of x-ray waves from a large number of atoms—favors longer-wavelength mid-infrared lasers. We identified a regime of high-harmonic generation driven by 40-cycle ultraviolet lasers in waveguides that can generate bright beams inmore » the soft x-ray region of the spectrum, up to photon energies of 280 electron volts. Surprisingly, the high ultraviolet refractive indices of both neutral atoms and ions enabled effective phase matching, even in a multiply ionized plasma. We observed harmonics with very narrow linewidths, while calculations show that the x-rays emerge as nearly time-bandwidth–limited pulse trains of ~100 attoseconds.« less

  2. The Ultraviolet Surprise. Efficient Soft X-Ray High Harmonic Generation in Multiply-Ionized Plasmas

    SciTech Connect

    Popmintchev, Dimitar; Hernandez-Garcia, Carlos; Dollar, Franklin; Mancuso, Christopher; Perez-Hernandez, Jose A.; Chen, Ming-Chang; Hankla, Amelia; Gao, Xiaohui; Shim, Bonggu; Gaeta, Alexander L.; Tarazkar, Maryam; Romanov, Dmitri A.; Levis, Robert J.; Gaffney, Jim A.; Foord, Mark; Libby, Stephen B.; Jaron-Becker, Agnieskzka; Becker, Andreas; Plaja, Luis; Muranane, Margaret M.; Kapteyn, Henry C.; Popmintchev, Tenio

    2015-12-04

    High-harmonic generation is a universal response of matter to strong femtosecond laser fields, coherently upconverting light to much shorter wavelengths. Optimizing the conversion of laser light into soft x-rays typically demands a trade-off between two competing factors. Reduced quantum diffusion of the radiating electron wave function results in emission from each species which is highest when a short-wavelength ultraviolet driving laser is used. But, phase matching—the constructive addition of x-ray waves from a large number of atoms—favors longer-wavelength mid-infrared lasers. We identified a regime of high-harmonic generation driven by 40-cycle ultraviolet lasers in waveguides that can generate bright beams in the soft x-ray region of the spectrum, up to photon energies of 280 electron volts. Surprisingly, the high ultraviolet refractive indices of both neutral atoms and ions enabled effective phase matching, even in a multiply ionized plasma. We observed harmonics with very narrow linewidths, while calculations show that the x-rays emerge as nearly time-bandwidth–limited pulse trains of ~100 attoseconds.

  3. Multistep Ionization of Argon Clusters in Intense Femtosecond Extreme Ultraviolet Pulses

    SciTech Connect

    Bostedt, C.; Thomas, H.; Hoener, M.; Eremina, E.; Fennel, T.; Meiwes-Broer, K.-H.; Wabnitz, H.; Kuhlmann, M.; Ploenjes, E.; Tiedtke, K.; Treusch, R.; Feldhaus, J.; Castro, A. R. B. de; Moeller, T.

    2008-04-04

    The interaction of intense extreme ultraviolet femtosecond laser pulses ({lambda}=32.8 nm) from the FLASH free electron laser (FEL) with clusters has been investigated by means of photoelectron spectroscopy and modeled by Monte Carlo simulations. For laser intensities up to 5x10{sup 13} W/cm{sup 2}, we find that the cluster ionization process is a sequence of direct electron emission events in a developing Coulomb field. A nanoplasma is formed only at the highest investigated power densities where ionization is frustrated due to the deep cluster potential. In contrast with earlier studies in the IR and vacuum ultraviolet spectral regime, we find no evidence for electron emission from plasma heating processes.

  4. The National Ignition Facility: Enabling Fusion Ignition for the 21st Century

    SciTech Connect

    Moses, E I; Miller, G H; Wuest, C R

    2004-09-17

    The National Ignition Facility (NIF) at Lawrence Livermore National Laboratory, when completed in 2008, will contain a 192-beam, 1.8-Megajoule, 500-Terawatt, ultraviolet laser system together with a 10-meter-diameter target chamber and room for 100 diagnostics. NIF is housed in a 26,000 square meter environmentally controlled building and is the world's largest and most energetic laser experimental system. NIF provides a scientific center for the study of inertial confinement fusion and the physics of matter at extreme energy densities and pressures. NIF's energetic laser beams will compress fusion targets to conditions required for thermonuclear burn, liberating more energy than required to initiate the fusion reactions. Other NIF experiments will study physical processes at temperatures approaching 10{sup 8} K and 10{sup 11} bar; conditions that exist naturally only in the interior of stars and planets. NIF is currently configured with four laser beams activated in late 2002. These beams are being regularly used for laser performance and physics experiments and to date nearly 250 system shots have been conducted. NIF's laser beams have generated 106 kilojoules in 23-ns pulses of infrared light and over 16 kJ in 3.5-ns pulses at the third harmonic (351 nm). A number of target experimental systems are being commissioned in support of experimental campaigns. This paper provides a detailed look the NIF laser systems, laser and optical performance, and results from laser commissioning shots. We also discuss NIF's high -energy density and inertial fusion experimental capabilities, the first experiments on NIF, and plans for future capabilities of this unique facility.

  5. Review of ultraviolet damage threshold measurements at Lawrence Livermore National Laboratory

    SciTech Connect

    Lowdermilk, W.H.; Milam, D.

    1984-01-01

    The results of damage threshold measurements made at LLNL using ultraviolet wavelength laser pulses are reviewed. Measurements were made with pulses from a krypton fluoride laser with wavelength of 248 nm and pulse duration of 20 ns and with Nd-glass laser pulses converted to the third harmonic wavelength of 355 nm with duration of 0.6 ns. Measurements are presented for transparent window materials, crystals and harmonic generation, single layer dielectric films of oxide and fluoride materials and multilayer high reflectivity and antireflective coatings.

  6. Ultraviolet surface plasmon-mediated low temperature hydrazine decomposition

    SciTech Connect

    Peng, Siying; Sheldon, Matthew T.; Atwater, Harry A.; Liu, Wei-Guang; Jaramillo-Botero, Andres; Goddard, William Andrew

    2015-01-12

    Conventional methods require elevated temperatures in order to dissociate high-energy nitrogen bonds in precursor molecules such as ammonia or hydrazine used for nitride film growth. We report enhanced photodissociation of surface-absorbed hydrazine (N{sub 2}H{sub 4}) molecules at low temperature by using ultraviolet surface plasmons to concentrate the exciting radiation. Plasmonic nanostructured aluminum substrates were designed to provide resonant near field concentration at λ = 248 nm (5 eV), corresponding to the maximum optical cross section for hydrogen abstraction from N{sub 2}H{sub 4}. We employed nanoimprint lithography to fabricate 1 mm × 1 mm arrays of the resonant plasmonic structures, and ultraviolet reflectance spectroscopy confirmed resonant extinction at 248 nm. Hydrazine was cryogenically adsorbed to the plasmonic substrate in a low-pressure ambient, and 5 eV surface plasmons were resonantly excited using a pulsed KrF laser. Mass spectrometry was used to characterize the photodissociation products and indicated a 6.2× overall enhancement in photodissociation yield for hydrazine adsorbed on plasmonic substrates compared with control substrates. The ultraviolet surface plasmon enhanced photodissociation demonstrated here may provide a valuable method to generate reactive precursors for deposition of nitride thin film materials at low temperatures.

  7. Photoinjector drive laser of the FLASH FEL.

    PubMed

    Will, Ingo; Templin, Horst I; Schreiber, Siegfried; Sandner, Wolfgang

    2011-11-21

    The upgraded photoinjector drive laser of the free-electron laser facility FLASH at DESY Hamburg is described in this paper. This laser produces trains of 800 and 2400 ultraviolet picosecond pulses at 1 MHz and 3 MHz repetition rate in the trains, respectively. The amplifying elements of the system are Nd:YLF-rods, which are pumped by fiber-coupled semiconductor diodes. Compared to the flashlamp-pumped photocathode laser previously used at FLASH, the new diode-pumped laser features a better reliability and a significantly improved stability of its pulse parameters.

  8. A Rayleigh-Brillouin scattering spectrometer for ultraviolet wavelengths.

    PubMed

    Gu, Ziyu; Vieitez, M Ofelia; van Duijn, Eric-Jan; Ubachs, Wim

    2012-05-01

    A spectrometer for the measurement of spontaneous Rayleigh-Brillouin (RB) scattering line profiles at ultraviolet wavelengths from gas phase molecules has been developed, employing a high-power frequency-stabilized UV-laser with narrow bandwidth (2 MHz). The UV-light from a frequency-doubled titanium:sapphire laser is further amplified in an enhancement cavity, delivering a 5 W UV-beam propagating through the interaction region inside a scattering cell. The design of the RB-scattering cell allows for measurements at gas pressures in the range 0-4 bars and at stably controlled temperatures from -30 °C to 70 °C. A scannable Fabry-Perot analyzer with instrument resolution of 232 MHz probes the RB profiles. Measurements on N(2) and SF(6) gases demonstrate that the high signal-to-noise ratio is achievable with the instrument at the 1% level at the peak amplitude of the scattering profile.

  9. Sensitivity calibration of an imaging extreme ultraviolet spectrometer-detector system for determining the efficiency of broadband extreme ultraviolet sources

    NASA Astrophysics Data System (ADS)

    Fuchs, S.; Rödel, C.; Krebs, M.; Hädrich, S.; Bierbach, J.; Paz, A. E.; Kuschel, S.; Wünsche, M.; Hilbert, V.; Zastrau, U.; Förster, E.; Limpert, J.; Paulus, G. G.

    2013-02-01

    We report on the absolute sensitivity calibration of an extreme ultraviolet (XUV) spectrometer system that is frequently employed to study emission from short-pulse laser experiments. The XUV spectrometer, consisting of a toroidal mirror and a transmission grating, was characterized at a synchrotron source in respect of the ratio of the detected to the incident photon flux at photon energies ranging from 15.5 eV to 99 eV. The absolute calibration allows the determination of the XUV photon number emitted by laser-based XUV sources, e.g., high-harmonic generation from plasma surfaces or in gaseous media. We have demonstrated high-harmonic generation in gases and plasma surfaces providing 2.3 μW and μJ per harmonic using the respective generation mechanisms.

  10. Far ultraviolet astronomy using the FAUST telescope

    NASA Technical Reports Server (NTRS)

    Bowyer, C. S.

    1981-01-01

    The Far Ultraviolet Space Telescope (FAUST) a compact, wide field-of-view, far ultraviolet instrument designed for astronomical observations of extended and point sources is discussed. The design and application of the instrument are described. The prime objective is to observe faint astronomical sources with sensitivities higher than previously available. Scientific programs will include: (1) a search for ultraviolet stars which are predicted to exist at the stage of evolution prior to the final death of a star; (2) observations of galaxies and quasars; and (3) joint programs with other Spacelab 1 experiments. The secondary objective is to verify the suitability of the Spacelab as a platform for far ultraviolet astronomy: data will be provided on the ultraviolet background levels due to astronomical, terrestrial, and spacecraft generated sources; the levels of contaminants which affect ultraviolet instruments; and the capability of the Orbiter for stable pointing at celestial sources for useful periods of time.

  11. Ultraviolet light and hyperpigmentation in healing wounds

    SciTech Connect

    Wiemer, D.R.; Spira, M.

    1983-10-01

    The concept of permanent hyperpigmentation in wounds following ultraviolet light exposure during the postoperative period has found a place in plastic surgical literature but has not been documented. This study evaluates the effect of ultraviolet light on healing wounds in paraplegics. It failed to confirm permanent alteration in pigmentation response to ultraviolet exposure and suggests that other factors are of greater importance in the development of hyperpigmentation in the healing wound.

  12. Polymerizable ultraviolet stabilizers for outdoor use

    NASA Technical Reports Server (NTRS)

    Vogl, O.

    1982-01-01

    Polymeric materials that are stable enough to use outdoors without changes in excess of 20 years are investigated. Ultraviolet stabilizers or plastic materials were synthesized, polymerizable ultraviolet stabilizers, particularly of the 2(2-hydroxyphenyl)2H-benzotriazole family were prepared their polymerization, copolymerization and grafting onto other polymers were demonstrated, and ultraviolet stabilizing systems were devised. These materials were evaluated from the photophysical point of view.

  13. Ultraviolet Radiation and Stratospheric Ozone

    NASA Technical Reports Server (NTRS)

    Stolarski, R.

    2003-01-01

    Ultraviolet radiation from the sun produces ozone in the stratosphere and it participates in the destruction of ozone. Absorption of solar ultraviolet radiation by ozone is the primary heating mechanism leading to the maximum in temperature at the stratopause. Variations of solar ultraviolet radiation on both the 27-day solar rotation period and the 11-year solar cycle affect ozone by several mechanisms. The temperature and ozone in the upper stratosphere respond to solar uv variations as a coupled system. An increase in uv leads to an increase in the production of ozone through the photolysis of molecular oxygen. An increase in uv leads to an increase in temperature through the heating by ozone photolysis. The increase in temperature leads to a partially-offsetting decrease in ozone through temperature-dependent reaction rate coefficients. The ozone variation modulates the heating by ozone photolysis. The increase in ozone at solar maximum enhances the uv heating. The processes are understood and supported by long-term data sets. Variation in the upper stratospheric temperatures will lead to a change in the behavior of waves propagating upward from the troposphere. Changes in the pattern of wave dissipation will lead to acceleration or deceleration of the mean flow and changes in the residual or transport circulation. This mechanism could lead to the propagation of the solar cycle uv variation from the upper stratosphere downward to the lower stratosphere. This process is not well-understood and has been the subject of an increasing number of model studies. I will review the data analyses for solar cycle and their comparison to model results.

  14. Combined ultraviolet studies of astronomical sources

    NASA Technical Reports Server (NTRS)

    Dupree, A. K.; Baliunas, S. L.; Blair, W. P.; Hartmann, L. W.; Huchra, J. P.; Raymond, J. C.; Smith, G. H.; Sonderblom, D. R.

    1985-01-01

    Ultraviolet studies of various astronomical entities are reported. Among the specific phenomena examined were supernova remnants, dwarf novae, red giant stars, stellar winds, binary stars, and galaxies.

  15. Ultraviolet and thermally stable polymer compositions

    NASA Technical Reports Server (NTRS)

    Adamson, M. J.; Gloria, H. R.; Goldsberry, R. E.; Reinisch, R. F.

    1972-01-01

    Copolymers, produced from aromatic substituted aromatic azine-siloxane compositions, are thermally stable, solar ultraviolet light non-degradable by wavelengths shorter than those reaching earth surface.

  16. Microgap ultra-violet detector

    DOEpatents

    Wuest, Craig R.; Bionta, Richard M.

    1994-01-01

    A microgap ultra-violet detector of photons with wavelengths less than 400 run (4000 Angstroms) which comprises an anode and a cathode separated by a gas-filled gap and having an electric field placed across the gap. Either the anode or the cathode is semi-transparent to UV light. Upon a UV photon striking the cathode an electron is expelled and accelerated across the gap by the electric field causing interactions with other electrons to create an electron avalanche which contacts the anode. The electron avalanche is detected and converted to an output pulse.

  17. Microgap ultra-violet detector

    DOEpatents

    Wuest, C.R.; Bionta, R.M.

    1994-09-20

    A microgap ultra-violet detector of photons with wavelengths less than 400 run (4,000 Angstroms) which comprises an anode and a cathode separated by a gas-filled gap and having an electric field placed across the gap is disclosed. Either the anode or the cathode is semi-transparent to UV light. Upon a UV photon striking the cathode an electron is expelled and accelerated across the gap by the electric field causing interactions with other electrons to create an electron avalanche which contacts the anode. The electron avalanche is detected and converted to an output pulse. 2 figs.

  18. Intracavity Optical Damage Due To Electrons, Ions And Ultraviolet Photons

    NASA Astrophysics Data System (ADS)

    Haglund, Richard F.

    1988-06-01

    Many of the damage problems experienced by intracavity laser optics, particularly for discharge-pumped and electron-beam-pumped laser systems, arise from the electronic interactions of low-energy electrons, ions and ultraviolet photons with the surface and near-surface regions of the optical material. We shall describe results of recent experiments which display some of the electronic mechanisms involved in these processes, through which incident electronic energy is absorbed, localized, transformed and ultimately dissipated in ways which change the surface composition and electronic structure of model wide bandgap optical materials. We consider discuss recent experimental results on the metallization of dielectric surfaces, the effects of adsorbed overlayers in inhibiting desorption of excited neutral atoms, and the effects of glass processing on response to electron and ion irradiation. We also point out some of the ways in which the changes in the optical surfaces wrought by the low-energy and low-intensity irradiation arising from the laser pumping mechanism can influence thermal, chemical and plasma properties of the surface in ways which alter the surface response to intense laser radiation.

  19. Ultrafast fibre lasers

    NASA Astrophysics Data System (ADS)

    Fermann, Martin E.; Hartl, Ingmar

    2013-11-01

    Ultrafast fibre lasers are fundamental building blocks of many photonic systems used in industrial and medical applications as well as for scientific research. Here, we review the essential components and operation regimes of ultrafast fibre lasers and discuss how they are instrumental in a variety of applications. In regards to laser technology, we discuss the present state of the art of large-mode-area fibres and their utilization in high-power, chirped-pulse amplification systems. In terms of commercial applications, we introduce industrial micromachining and medical imaging, and describe emerging applications in the mid-infrared and extreme-ultraviolet spectral regions, as facilitated by frequency shifting induced by fibre frequency combs.

  20. Laser and optical system for laser assisted hydrogen ion beam stripping at SNS

    NASA Astrophysics Data System (ADS)

    Liu, Y.; Rakhman, A.; Menshov, A.; Webster, A.; Gorlov, T.; Aleksandrov, A.; Cousineau, S.

    2017-03-01

    Recently, a high-efficiency laser assisted hydrogen ion (H-) beam stripping was successfully carried out in the Spallation Neutron Source (SNS) accelerator. The experiment was not only an important step toward foil-less H- stripping for charge exchange injection, it also set up a first example of using megawatt ultraviolet (UV) laser source in an operational high power proton accelerator facility. This paper reports in detail the design, installation, and commissioning result of a macro-pulsed multi-megawatt UV laser system and laser beam transport line for the laser stripping experiment.