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Sample records for 50wx2 nafion-h microsaddles

  1. Characterization and performance of WO{sub 3}:Mo/Nafion-H{trademark} electrochromic device

    SciTech Connect

    Pennisi, A.; Simone, F.

    1994-12-31

    Here are presented the results of electrochemical and optical measurements on tungsten trioxide, molybdenum doped (WO{sub 3}:Mo) thin films, electrochemically deposited, assembled with Nafion-H in order to realize an electrochromic (EC) device. The polymer that permits the ionic exchange has a residual viscosity, so that the authors` device cannot be defined as a really solid state device. A good reason for the use of this polymer is its very high proton storage capability, so that, in their devices, it is possible to avoid the presence of a specific ion storage counterelectrode. In this work the authors compare also the electrochromic behavior of devices in dependence on the thermal treatment operated on the electrochemical films after deposition. Analysis has been carried on to reveal morphological characteristics of surface, thickness and stoichiometry of EC compound. Particular attention is paid to the potential waveform used to bias the devices, in order to optimize their performance and to avoid problems of stability and degradation.

  2. Heterogeneous catalysis by solid superacids--14. Perfluorinated resinsulfonic acid (nafion-h) catalyzed Friedel-crafts alkylation of toluene and phenol with alkyl chloroformates and oxalates

    SciTech Connect

    Olah, G.A.; Meidar, D.; Malhotra, R.; Olah, J.A.; Narang, S.C.

    1980-01-01

    Product distributions obtained in the alkylation of toluene with methyl, ethyl, and isopropyl chloroformate and dimethyl oxalate and of phenol with methyl and ethyl chloroformate and dimethyl- and diethyloxalate.

  3. Sulfonic acid resin-catalyzed addition of phenols, carboxylic acids, and water to olefins: Model reactions for catalytic upgrading of bio-oil.

    PubMed

    Zhang, Zhi-Jun; Wang, Qing-Wen; Yang, Xu-Lai; Chatterjee, Sabornie; Pittman, Charles U

    2010-05-01

    Acid-catalyzed 1-octene reactions with phenol and mixtures of phenol with water, acetic acid and 1-butanol were studied as partial bio-oil upgrading models. Bio-oil from fast biomass pyrolysis has poor fuel properties due to the presence of substantial amounts of water, carboxylic acid, phenolic derivatives and other hydroxyl-containing compounds. Additions across olefins offer a route to simultaneously lower water content and acidity while increasing hydrophobicity, stability and heating value. Amberlyst15, Dowex50WX2 and Dowex50WX4 effectively catalyzed phenol O- and C-alkylation from 65 to 120 degrees C, giving high O-alkylation selectivities in the presence of water, acetic acid and 1-butanol. Octanols and dioctyl ethers were formed from water and octyl acetates and phenol acetates from acetic acid. Phenol alkylation slowed in the presence of water. Dowex50WX2 and Dowex50WX4 were more stable in the presence of water than Amberlyst15 and were successfully recycled. Adding 1-butanol to phenol/water/1-octene, gave emulsion-like mixtures which improved phenol conversion and olefin hydration.

  4. Perfluorinated resinsulfonic acid--a catalyst for certain organic reactions

    SciTech Connect

    Etlis, V.S.; Beshenova, E.P.; Semenova, E.A.; Shomina, F.N.; Dreiman, N.A.; Balaev, G.A.

    1986-09-10

    The purpose of this work was to examine the possibility of using, as a catalyst in certain organic reactions, the perfluorinated resinsulfonic acid F-4SK in the H form, which is an analog of the perfluorinated resinsulfonic acid Nafion-H.

  5. Fractionation of sulphite spent liquor for biochemical processing using ion exchange resins.

    PubMed

    Fernandes, D L A; Silva, C M; Xavier, A M R B; Evtuguin, D V

    2012-12-31

    Sulphite spent liquor (SSL) is a side product from acidic sulphite pulping of wood, which organic counterpart is composed mainly by lignosulphonates (LS) and sugars. The last are a prominent substrate for the bioprocessing although a previous purification step is necessary to eliminate microbial inhibitors. In this study a fractionation of hardwood SSL (HSSL) has been accomplished employing ion exchange resins in order to separate sugars fraction from concomitant inhibitors: LS, acetic acid, furan derivatives, phenolics, acetic acid and excess of inorganic salts. The fractionation of HSSL has been carried out using two fixed-bed ion exchangers in series (cationic+anionic). The first cation exchange column packed with Dowex 50WX2 resin was able to eliminate free cations and partially separate sugars from high molecular weight LS and furan derivatives. The second anion exchange column packed with Amberlite IRA-96 sorbed remaining LS, phenolics and acetic acid. Overall, the series arrangement under investigation has removed 99.99% of Mg(2+), 99.0% of Ca(2+), 99.6% of LS, and 100% of acetic acid, whereas the yield of recovered sugars was at least 72% of their total amount in HSSL.

  6. Incorporation of zero valent iron nanoparticles in the matrix of cationic resin beads for the remediation of Cr(VI) contaminated waters.

    PubMed

    Toli, Aikaterini; Chalastara, Konstantina; Mystrioti, Christiana; Xenidis, Anthimos; Papassiopi, Nymphodora

    2016-07-01

    The objective of present study was to obtain the fixation of nano zero valent iron (nZVI) particles on a permeable matrix and evaluate the performance of this composite material for the removal of Cr(VI) from contaminated waters. The experiments were carried out using the cationic resin Dowex 50WX2 as porous support of the iron nanoparticles. The work was carried out in two phases. The first phase involved the fixation of nZVI on the resin matrix. The resin granules were initially mixed with a FeCl3 solution to obtain the adsorption of Fe(III). Then the Fe(III) loaded resin (RFe) was treated with polyphenol solutions to obtain the reduction of Fe(III) to the elemental state. Two polyphenol solutions were tested as reductants, i.e. green tea extract and gallic acid. Green tea was found to be inefficient, probably due to the relatively big size of the contained polyphenol molecules, but gallic acid molecules were able to reach adsorbed Fe(III) and reduce the cations to the elemental state. The second phase was focused on the investigation of Cr(VI) reduction kinetics using the nanoiron loaded resins (R-nFe). It was found that the reduction follows a kinetic law of first order with respect to Cr(VI) and to the embedded nanoiron. Compared to other similar products, this composite material was found to have comparable performance regarding reaction rates and higher degree of iron utilization. Namely the rate constant for the reduction of Cr(VI), in the presence of 1 mM nZVI, was equivalent to 1.4 h of half-life time at pH 3.2 and increased to 24 h at pH 8.5. The degree of iron utilization was as high as 0.8 mol of reduced Cr(VI) per mole of iron. It was also found that this composite material can be easily regenerated and reused for Cr(VI) reduction without significant loss of efficiency.

  7. Carbonylation of formaldehyde over ion exchange resin catalysts. 1. Batch reactor studies

    SciTech Connect

    Sang Young Lee; Jae Chang Kim; Jae Sung Lee; Young Gul Kim )

    1993-02-01

    Methyl glycolate was synthesized as a precursor to ethylene glycol from the catalytic carbonylation of formaldehyde followed by esterification with methanol. Various cation exchange polystyrene-sulfonic acid resins showed excellent activity and methyl glycolate selectivity. The perfluorinated sulfonic acid resin Nafion-H showed higher activity per proton site, yet was less effective per weight of the catalyst. The effects of process variables such as pressure, temperature, catalyst loading, and solvent were studied. High CO pressures were required to promote formaldehyde carbonylation relative to side reactions between formaldehyde. The presence of water reduced the reaction rate, yet improved the selectivity to methyl glycolate. 1,4-Dioxane was found to be the best solvent in the presence of water. At 135 C, 3,500 psig, and reactant mole ratio of HCHO:H[sub 2]O:H[sup +] = 10:10:1, complete conversion of formaldehyde was achieved in 2-4 h with selectivities of methyl glycolate better than 80%. Catalysts did not show any significant deterioration in performance in repeated use up to 10 batches.

  8. Design and Development of Highly Sulfonated Polymers as Proton Exchange Membranes for High Temperature Fuel Cell Applications

    NASA Astrophysics Data System (ADS)

    Dang, Thuy D.; Bai, Zongwu; Yoonessi, Mitra

    A series of high molecular weight, highly sulfonated poly(arylenethioethersulfone) (SPTES) polymers were synthesized by polycondensation, which allowed controlled sulfonation of up to 100 mol %. The SPTES polymers were prepared via step growth polymerization of sulfonated aromatic difluorosulfone, aromatic difluorosulfone, and 4,4 '-thiobisbenzenthiol in sulfolane solvent at the temperature up to 180 °C. The composition and incorporation of the sulfonated repeat unit into the polymers were confirmed by 1H nuclear magnetic resonance (NMR) and Fourier transform infrared (FTIR) spectroscopy. Solubility tests on the SPTES polymers confirmed that no cross-linking and probably no branching occurred during the polymerizations. The end-capping groups were introduced in the SPTES polymers to control the molecular weight distribution and reduce the water solubility of the polymers. Tough, ductile membranes formed via solvent-casting exhibited increased water absorption with increasing degrees of sulfonation. The polymerizations conducted with the introduction of end-capping groups resulted in a wide variation in polymer proton conductivity, which spanned a range of 100 -300 mS cm-1, measured at 65 °C and 85 % relative humidity. The measured proton conductivities at elevated temperatures and high relative humidities are up to three times higher than that of the state-of-the-art Nafion-H proton exchange membrane under nearly comparable conditions. The thermal and mechanical properties of the SPTES polymers were investigated by TGA, DMA, and tensile measurements. The SPTES polymers show high glass transition temperatures (Tg), ˜220 °C, depending on the degree of sulfonation in polymerization. SPTES-50 polymer shows a Tg of 223 °C, with high tensile modulus, high tensile strengths at break and at yield as well as elongation at break. Wide angle X-ray scattering of the polymers shows two broad scattering features centered at 4.5 Å and 3.3 Å, the latter peak being