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Sample records for aa-stacked bilayer graphene

  1. AA-stacked bilayer square ice between graphene layers

    NASA Astrophysics Data System (ADS)

    Sobrino Fernandez Mario, M.; Neek-Amal, M.; Peeters, F. M.

    2015-12-01

    Water confined between two graphene layers with a separation of a few Å forms a layered two-dimensional ice structure. Using large scale molecular dynamics simulations with the adoptable ReaxFF interatomic potential we found that flat monolayer ice with a rhombic-square structure nucleates between the graphene layers which is nonpolar and nonferroelectric. We provide different energetic considerations and H-bonding results that explain the interlayer and intralayer properties of two-dimensional ice. The controversial AA stacking found experimentally [Algara-Siller et al., Nature (London) 519, 443 (2015), 10.1038/nature14295] is consistent with our minimum-energy crystal structure of bilayer ice. Furthermore, we predict that an odd number of layers of ice has the same lattice structure as monolayer ice, while an even number of ice layers exhibits the square ice AA stacking of bilayer ice.

  2. Gapped phase in AA-stacked bilayer graphene

    NASA Astrophysics Data System (ADS)

    Brey, L.; Fertig, H. A.

    2013-03-01

    AA-stacked bilayer graphene supports Fermi circles in its bonding and antibonding bands, which coincide exactly, leading to symmetry breaking in the presence of electron-electron interactions. We analyze a continuum model of this system in the Hartree-Fock approximation, using a self-consistently screened interaction that accounts for the gap in the spectrum in the broken symmetry state. The order parameter in the ground state is shown to be of the Ising type, involving transfer of charge between the layers in opposite directions for different sublattices. We analyze the Ising phase transition for the system and argue that it continuously evolves into a Kosterlitz-Thouless transition in the limit of vanishing interlayer separation d. The transition temperature is shown to depend only on the effective spin stiffness of the system even for d>0, and an estimate of its value suggests that the transition temperature is of the order of a few degrees Kelvin.

  3. Periodic barrier structure in AA-stacked bilayer graphene

    NASA Astrophysics Data System (ADS)

    Redouani, Ilham; Jellal, Ahmed

    2016-06-01

    We study the charge carriers transport in an AA-stacked bilayer graphene modulated by a lateral one-dimensional multibarrier structure. We investigate the band structures of our system, that is made up of two shifted Dirac cones, for finite and zero gap. We use the boundary conditions to explicitly determine the transmission probability of each individual cone (τ =+/- 1) for single, double and finite periodic barrier structure. We find that the Klein tunneling is only possible when the band structure is gapless and can occur at normal incidence as a result of the Dirac nature of the quasiparticles. We observe that the band structure of the barriers can have more than one Dirac points for finite periodic barrier. The resonance peaks appear in the transmission probability, which correspond to the positions of new cones index like associated with τ =+/- 1. Two conductance channels through different cones (τ =+/- 1) are found where the total conductance has been studied and compared to the cases of single layer and AB-stacked bilayer graphene.

  4. AA-stacked bilayer graphene quantum dots in magnetic field

    NASA Astrophysics Data System (ADS)

    Belouad, Abdelhadi; Zahidi, Youness; Jellal, Ahmed

    2016-05-01

    By applying the infinite-mass boundary condition, we analytically calculate the confined states and the corresponding wave functions of AA-stacked bilayer graphene (BLG) quantum dots (QDs) in the presence of an uniform magnetic field B. It is found that the energy spectrum shows two set of levels, which are the double copies of the energy spectrum for single layer graphene, shifted up–down by +γ and -γ , respectively. However, the obtained spectrum exhibits different symmetries between the electron and hole states as well as the intervalley symmetries. It is noticed that, the applied magnetic field breaks all symmetries, except one related to the intervalley electron–hole symmetry, i.e. {E}{{e}}(τ ,m)=-{E}{{h}}(τ ,m). Two different regimes of confinement are found: the first one is due to the infinite-mass barrier at weak B and the second is dominated by the magnetic field as long as B is large. We numerically investigated the basics features of the energy spectrum to show the main similarities and differences with respect to monolayer graphene, AB-stacked BLG and semiconductor QDs. Dedicated to Professor Dr Hachim A Yamani on the occasion of his 70th birthday.

  5. Dynamical thermoelectric properties of doped AA-stacked bilayer graphene

    NASA Astrophysics Data System (ADS)

    Rezania, Hamed; Yarmohammadi, Mohsen

    2016-01-01

    The frequency dependence of thermoelectric properties of doped biased bilayer graphene are investigated using the Green's function approach in the context of tight-binding model. We find that the thermoelectric figure of merit (ZT) can be remarkably enhanced by electronic chemical potential, temperature, bias voltage and frequency. The electronic contribution to thermal conductivity of doped materials is dominant and therefore we have considered this contribution. The improvement due to the combined increase in the Seebeck coefficient and the reduction in the thermal conductivity outweighing the decrease in the electrical conductance is studied. We have found a good ZT value for normal conditions in the lab, i.e, for room temperature (RT), high bias voltages and low frequencies. We have found the temperature dependence of ZT for different values of frequency, bias voltage and chemical potential. Also the dependence of ZT on the chemical potential and bias voltage has been investigated in details. The calculated ZT values qualify bilayer graphene as a very promising material for thermoelectric applications.

  6. Microscopic theoretical model study of band gap opening in AA-stacked bi-layer graphene

    NASA Astrophysics Data System (ADS)

    Sahu, Sivabrata; Parashar, S. K. S.; Rout, G. C.

    2016-05-01

    We address here a tight-binding theoretical model calculation for AA-stacked bi-layer graphene taking into account of a biased potential between two layers to study the density of states and the band dispersion within the total Brillouin zone. We have calculated the electronic Green's function for electron operator corresponding to A and B sub lattices by Zubarev's Green's function technique from which the electronic density of states and the electron band energy dispersion are calculated. The numerically computed density of states and band energy dispersions are investigated by tuning the biased potential to exhibit the band gap by varying the different physical parameters.

  7. Goos-Hänchen shifts in AA-stacked bilayer graphene superlattices

    NASA Astrophysics Data System (ADS)

    Zahidi, Youness; Redouani, Ilham; Jellal, Ahmed

    2016-07-01

    The quantum Goos-Hänchen shifts of the transmitted electron beam through an AA-stacked bilayer graphene superlattices are investigated. We found that the band structures of graphene superlattices can have more than one Dirac point, their locations do not depend on the number of barriers. It was revealed that any n-barrier structure is perfectly transparent at normal incidence around the Dirac points created in the superlattices. We showed that the Goos-Hänchen shifts display sharp peaks inside the transmission gap around two Dirac points (E =VB + τ, E =VW + τ), which are equal to those of transmission resonances. The obtained Goos-Hänchen shifts are exhibiting negative as well as positive behaviors and strongly depending on the location of Dirac points. It is observed that the maximum absolute values of the shifts increase as long as the number of barriers is increased. Our analysis is done by considering four cases: single, double barriers, superlattices without and with defect.

  8. Charge screening and carrier transport in AA-stacked bilayer graphene: Tuning via a perpendicular electric field

    NASA Astrophysics Data System (ADS)

    Mohammadi, Yawar

    2015-01-01

    The static dielectric function in AA-stacked bilayer graphene (BLG), subjected to an electric field applied perpendicular to layers, is calculated analytically within the random phase approximation (RPA). This result is used to calculate the screened Coulomb interaction and the electrical conductivity. The screened Coulomb interaction, which here can be tuned by the perpendicular electric field, shows a power-law decay as 1 /(γ2 +V2) at long-distance limit where V and γ are the electrical potential and the inter-layer hopping energy respectively, indicating that the Coulomb interaction is suppressed at high perpendicular electric fields. Furthermore, our results for the effect of the short-range and the long-range (Coulomb) scattering on the electrical conductivity show that the short-range scattering yields a constant electrical conductivity which is not affected by the perpendicular electric filed. While the electrical conductivity limited by the Coulomb scattering is enhanced by the perpendicular electric field and increases linearly in V2 at small V with a finite value at V=0, indicating that we can tune the electrical conductivity in AA-stacked BLG by applying a perpendicular electric field.

  9. Structural and electronic properties of AB- and AA-stacking bilayer-graphene intercalated by Li, Na, Ca, B, Al, Si, Ge, Ag, and Au atoms

    NASA Astrophysics Data System (ADS)

    Tayran, Ceren; Aydin, Sezgin; Çakmak, Mehmet; Ellialtıoğlu, Şinasi

    2016-04-01

    The structural and electronic properties of X (=Li, Na, Ca, B, Al, Si, Ge, Ag, and Au)-intercalated AB- and AA-stacking bilayer-graphene have been investigated by using ab initio density functional theory. It is shown that Boron (Lithium)-intercalated system is energetically more stable than the others for the AB (AA) stacking bilayer-graphene systems. The structural parameters, electronic band structures, and orbital nature of actual interactions are studied for the relaxed stable geometries. It is seen that the higher the binding energy, the smaller is the distance between the layers, in these systems. The electronic band structures for these systems show that different intercalated atoms can change the properties of bilayer-graphene differently. For qualitative description of the electronic properties, the metallicities of the systems are also calculated and compared with each other. The Mulliken analysis and electron density maps clearly indicate that the interactions inside a single layer (intralayer interactions) are strong and highly covalent, while the interactions between the two layers (interlayer interactions) are much weaker.

  10. Self healing nature of bilayer graphene

    NASA Astrophysics Data System (ADS)

    Debroy, Sanghamitra; Pavan Kumar Miriyala, V.; Vijaya Sekhar, K.; Acharyya, Swati Ghosh; Acharyya, Amit

    2016-08-01

    The phenomenon of self healing of cracks in bilayer graphene sheet has been studied using molecular dynamics simulations. The bilayer graphene sheet was subjected to uniaxial tensile load resulting in initiation and propagation of cracks on exceeding the ultimate tensile strength. Subsequently, all forces acting on the sheet were removed and sheet was relaxed. The cracks formed in the graphene sheet healed without any external aid within 0.4 ps The phenomenon of self healing of the cracks in graphene sheet was found to be independent of the length of the crack, but occurred for critical crack opening distance less than 5 Å for AA stacked sheet and 13 Å for AB stacked bilayer graphene sheet. Self healing was observed for both AB (mixed stacking of armchair and zigzag graphene sheet) and AA (both sheets of similar orientation i.e. either armchair-armchair or zigzag-zigzag) stacking of bilayer graphene sheet.

  11. Localized plasmons in bilayer graphene nanodisks

    NASA Astrophysics Data System (ADS)

    Wang, Weihua; Xiao, Sanshui; Mortensen, N. Asger

    2016-04-01

    We study localized plasmonic excitations in bilayer graphene (BLG) nanodisks, comparing AA-stacked and AB-stacked BLG and contrasting the results to the case of two monolayers without electronic hybridization. The electrodynamic response of the BLG electron gas is described in terms of a spatially homogeneous surface conductivity, and an efficient alternative two-dimensional electrostatic approach is employed to carry out all the numerical calculations of plasmon resonances. Due to unique electronic band structures, the resonance frequency of the traditional dipolar plasmonic mode in the AA-stacked BLG nanodisk is roughly doping independent in the low-doping regime, while the mode is highly damped as the Fermi level approaches the interlayer hopping energy γ associated with tunneling of electrons between the two layers. In addition to the traditional dipolar mode, we find that the AB-stacked BLG nanodisk also hosts a new plasmonic mode with energy larger than γ . This mode can be tuned by either the doping level or structural size, and, furthermore, this mode can dominate the plasmonic response for realistic structural conditions.

  12. Theoretical investigation of structural and optical properties of semi-fluorinated bilayer graphene

    NASA Astrophysics Data System (ADS)

    Xiao-Jiao, San; Bai, Han; Jing-Geng, Zhao

    2016-03-01

    We have studied the structural and optical properties of semi-fluorinated bilayer graphene using density functional theory. When the interlayer distance is 1.62 Å, the two graphene layers in AA stacking can form strong chemical bonds. Under an in-plane stress of 6.8 GPa, this semi-fluorinated bilayer graphene becomes the energy minimum. Our calculations indicate that the semi-fluorinated bilayer graphene with the AA stacking sequence and rectangular fluorinated configuration is a nonmagnetic semiconductor (direct gap of 3.46 eV). The electronic behavior at the vicinity of the Fermi level is mainly contributed by the p electrons of carbon atoms forming C=C double bonds. We compare the optical properties of the semi-fluorinated bilayer graphene with those of bilayer graphene stacked in the AA sequence and find that the semi-fluorinated bilayer graphene is anisotropic for the polarization vector on the basal plane of graphene and a red shift occurs in the [010] polarization, which makes the peak at the low-frequency region located within visible light. This investigation is useful to design polarization-dependence optoelectronic devices. Project supported by the Program of Educational Commission of Heilongjiang Province, China (Grant No. 12541131).

  13. Dynamical thermal conductivity of bilayer graphene in the presence of bias voltage

    NASA Astrophysics Data System (ADS)

    Rezania, H.; Yarmohammadi, M.

    2016-01-01

    We study dynamical thermal conductivity of doped biased bilayer graphene for both AA and AB-stacking in the context of tight binding model Hamiltonian. The effects of bias voltage and chemical potential on the behavior of dynamical thermal conductivity are discussed for different stacking of bilayer graphene. Green's function approach has been implemented to find the behavior of thermal conductivity of bilayer graphene within linear response theory. We have found that thermal conductivity decreases with chemical potential for different values of temperature and frequency. Also thermal conductivity of AB stacked bilayer graphene versus bias voltage includes a peak for each value of chemical potential. Furthermore we study the frequency dependence of thermal conductivity of AA stacked bilayer graphene for different values of temperature and bias voltage.

  14. Controlling dynamical thermal transport of biased bilayer graphene by impurity atoms

    NASA Astrophysics Data System (ADS)

    Rezania, Hamed; Yarmohammadi, Mohsen

    2016-07-01

    We address the dynamical thermal conductivity of biased bilayer graphene doped with acceptor impurity atoms for AA-stacking in the context of tight binding model Hamiltonian. The effect of scattering by dilute charged impurities is discussed in terms of the self-consistent Born approximation. Green's function approach has been exploited to find the behavior of thermal conductivity of bilayer graphene within the linear response theory. We have found the frequency dependence of thermal conductivity for different values of concentration and scattering strength of dopant impurity. Also the dependence of thermal conductivity on the impurity concentration and bias voltage has been investigated in details.

  15. Tunneling Plasmonics in Bilayer Graphene.

    PubMed

    Fei, Z; Iwinski, E G; Ni, G X; Zhang, L M; Bao, W; Rodin, A S; Lee, Y; Wagner, M; Liu, M K; Dai, S; Goldflam, M D; Thiemens, M; Keilmann, F; Lau, C N; Castro-Neto, A H; Fogler, M M; Basov, D N

    2015-08-12

    We report experimental signatures of plasmonic effects due to electron tunneling between adjacent graphene layers. At subnanometer separation, such layers can form either a strongly coupled bilayer graphene with a Bernal stacking or a weakly coupled double-layer graphene with a random stacking order. Effects due to interlayer tunneling dominate in the former case but are negligible in the latter. We found through infrared nanoimaging that bilayer graphene supports plasmons with a higher degree of confinement compared to single- and double-layer graphene, a direct consequence of interlayer tunneling. Moreover, we were able to shut off plasmons in bilayer graphene through gating within a wide voltage range. Theoretical modeling indicates that such a plasmon-off region is directly linked to a gapped insulating state of bilayer graphene, yet another implication of interlayer tunneling. Our work uncovers essential plasmonic properties in bilayer graphene and suggests a possibility to achieve novel plasmonic functionalities in graphene few-layers. PMID:26222509

  16. Bilayer Graphene Electromechanical Systems

    NASA Astrophysics Data System (ADS)

    Champagne, Alexandre; Storms, Matthew; Yigen, Serap; Reulet, Bertrand

    Bilayer graphene is an outstanding electromechanical system, and its electronic and mechanical properties, as well as their coupling, are widely tunable. To the best of our knowledge, simultaneous charge transport and mechanical spectroscopy (via RF mixing) has not been realized in bilayer graphene. We present data showing clear electromechanical resonances in three suspended bilayer devices whose length range from 1 to 2 microns. We first describe the low-temperature current annealing of the devices which is crucial to achieve the transconductance, I -VG , necessary to implement a RF mixing detection method. We describe our RF mixing circuit and data. We measure clear mechanical resonances ranging in frequency from 50 to 140 MHz. We show that we can smoothly tune the resonance frequencies of our bilayer resonators with mechanical strain applied via a backgate voltage. We measure quality factors up to 4000. We briefly discuss the effects of the RF driving power on the dispersion of the mechanical resonance. We aim to use these high quality mechanical resonance as a mechanical sensor of the bilayer quantum Hall phase transitions. We show initial data of a bilayer mechanical resonance as a function of magnetic field and quantum Hall phase transitions.

  17. Molecular dynamics simulations on deformation and fracture of bi-layer graphene with different stacking pattern under tension

    NASA Astrophysics Data System (ADS)

    Jiao, M. D.; Wang, L.; Wang, C. Y.; Zhang, Q.; Ye, S. Y.; Wang, F. Y.

    2016-02-01

    Based on AIREBO (Adaptive Intermolecular Reactive Empirical Bond Order) potential, molecular dynamics simulations (MDs) are performed to study the mechanical behavior of AB- and AA-stacked bi-layer graphene films (BGFs) under tension. Stress-strain relationship is established and deformation mechanism is investigated via morphology analysis. It is found that AA-stacked BGFs show wavy folds, i.e. the structural instability, and the local structure of AB-stacked BGFs transforms into AA-stacked ones during free relaxation. The values of the Young's modulus obtained for AA-stacked zigzag and armchair BGFs are 797.2 GPa and 727.4 GPa, and those of their AB-stacked counterparts are 646.7 GPa and 603.5 GPa, respectively. In comparison with single-layer graphene, low anisotropy is observed for BGFs, especially AB-stacked ones. During the tensile deformation, hexagonal cells at the edge of BGFs are found to transform into pentagonal rings and the number of such defects increases with the rise of tensile strain.

  18. Electromechanical oscillations in bilayer graphene.

    PubMed

    Benameur, Muhammed M; Gargiulo, Fernando; Manzeli, Sajedeh; Autès, Gabriel; Tosun, Mahmut; Yazyev, Oleg V; Kis, Andras

    2015-01-01

    Nanoelectromechanical systems constitute a class of devices lying at the interface between fundamental research and technological applications. Realizing nanoelectromechanical devices based on novel materials such as graphene allows studying their mechanical and electromechanical characteristics at the nanoscale and addressing fundamental questions such as electron-phonon interaction and bandgap engineering. In this work, we realize electromechanical devices using single and bilayer graphene and probe the interplay between their mechanical and electrical properties. We show that the deflection of monolayer graphene nanoribbons results in a linear increase in their electrical resistance. Surprisingly, we observe oscillations in the electromechanical response of bilayer graphene. The proposed theoretical model suggests that these oscillations arise from quantum mechanical interference in the transition region induced by sliding of individual graphene layers with respect to each other. Our work shows that bilayer graphene conceals unexpectedly rich and novel physics with promising potential in applications based on nanoelectromechanical systems. PMID:26481767

  19. Electromechanical oscillations in bilayer graphene

    PubMed Central

    Benameur, Muhammed M.; Gargiulo, Fernando; Manzeli, Sajedeh; Autès, Gabriel; Tosun, Mahmut; Yazyev, Oleg V.; Kis, Andras

    2015-01-01

    Nanoelectromechanical systems constitute a class of devices lying at the interface between fundamental research and technological applications. Realizing nanoelectromechanical devices based on novel materials such as graphene allows studying their mechanical and electromechanical characteristics at the nanoscale and addressing fundamental questions such as electron–phonon interaction and bandgap engineering. In this work, we realize electromechanical devices using single and bilayer graphene and probe the interplay between their mechanical and electrical properties. We show that the deflection of monolayer graphene nanoribbons results in a linear increase in their electrical resistance. Surprisingly, we observe oscillations in the electromechanical response of bilayer graphene. The proposed theoretical model suggests that these oscillations arise from quantum mechanical interference in the transition region induced by sliding of individual graphene layers with respect to each other. Our work shows that bilayer graphene conceals unexpectedly rich and novel physics with promising potential in applications based on nanoelectromechanical systems. PMID:26481767

  20. Electromechanical oscillations in bilayer graphene

    NASA Astrophysics Data System (ADS)

    Benameur, Muhammed M.; Gargiulo, Fernando; Manzeli, Sajedeh; Autès, Gabriel; Tosun, Mahmut; Yazyev, Oleg V.; Kis, Andras

    2015-10-01

    Nanoelectromechanical systems constitute a class of devices lying at the interface between fundamental research and technological applications. Realizing nanoelectromechanical devices based on novel materials such as graphene allows studying their mechanical and electromechanical characteristics at the nanoscale and addressing fundamental questions such as electron-phonon interaction and bandgap engineering. In this work, we realize electromechanical devices using single and bilayer graphene and probe the interplay between their mechanical and electrical properties. We show that the deflection of monolayer graphene nanoribbons results in a linear increase in their electrical resistance. Surprisingly, we observe oscillations in the electromechanical response of bilayer graphene. The proposed theoretical model suggests that these oscillations arise from quantum mechanical interference in the transition region induced by sliding of individual graphene layers with respect to each other. Our work shows that bilayer graphene conceals unexpectedly rich and novel physics with promising potential in applications based on nanoelectromechanical systems.

  1. Supercurrent reversal in Josephson junctions based on bilayer graphene flakes

    NASA Astrophysics Data System (ADS)

    Rameshti, Babak Zare; Zareyan, Malek; Moghaddam, Ali G.

    2015-08-01

    We investigate the Josephson effect in a bilayer graphene flake contacted by two monolayer sheets deposited by superconducting electrodes. It is found that when the electrodes are attached to the different layers of the bilayer, the Josephson current is in a π state, if the bilayer region is undoped and there is no vertical bias. Applying doping or bias to the junction reveals π -0 transitions which can be controlled by varying the temperature and the junction length. The supercurrent reversal here is very different from the ferromagnetic Josephson junctions where the spin degree of freedom plays the key role. We argue that the scattering processes accompanied by layer and sublattice index change give rise to the scattering phases, the effect of which varies with doping and bias. Such scattering phases are responsible for the π -0 transitions. On the other hand, if both of the electrodes are coupled to the same layer of the flake or the flake has AA stacking instead of common AB, the junction will be always in 0 state since the layer or sublattice index is not changed.

  2. The effects of impurity doping on the optical properties of biased bilayer graphene

    NASA Astrophysics Data System (ADS)

    Rezania, Hamed; Yarmohammadi, Mohsen

    2016-07-01

    We address the optical conductivity of doped AA-stacked bilayer graphene in the presence of a finite bias voltage at finite temperature. The effect of scattering by dilute charged impurities is discussed in terms of the self-consistent Born approximation. Green's function approach has been implemented to find the behavior of optical conductivity of bilayer graphene within linear response theory. We have found the frequency dependence of optical conductivity for different values of concentration and scattering strength of dopant impurity. Also the dependence of optical conductivity on the impurity concentration and bias voltage has been investigated in details. A peak appears in the plot of optical conductivity versus impurity concentration for different values of chemical potential. Furthermore we find optical conductivity reduces with frequency for any impurity concentration and scattering strength.

  3. Graphene Monolayer Rotation on Ni(111) Facilities Bilayer Graphene Growth

    SciTech Connect

    Batzill M.; Sutter P.; Dahal, A.; Addou, R.

    2012-06-11

    Synthesis of bilayer graphene by chemical vapor deposition is of importance for graphene-based field effect devices. Here, we demonstrate that bilayer graphene preferentially grows by carbon-segregation under graphene sheets that are rotated relative to a Ni(111) substrate. Rotated graphene monolayer films can be synthesized at growth temperatures above 650 C on a Ni(111) thin-film. The segregated second graphene layer is in registry with the Ni(111) substrate and this suppresses further C-segregation, effectively self-limiting graphene formation to two layers.

  4. The magnetic ratchet effect in bilayer graphene

    NASA Astrophysics Data System (ADS)

    McCann, Edward; Kheirabadi, Narjes; Fal'Ko, Vladimir

    Experiments have measured a magnetic ratchet effect for electrons in hydrogenated monolayer graphene, an effect in which a d.c. electric current is generated from an a.c. electric field in the presence of an in-plane magnetic field and spatial asymmetry. Here, we describe the theory of the magnetic ratchet effect in bilayer graphene. The Boltzmann kinetic equation is used to relate the d.c. current to the scattering probability of electrons in bilayer graphene. Taking into account details of the low-energy band structure of bilayer graphene, including interlayer hopping parameters, we compare contributions arising from gate- and disorder-induced spatial asymmetry, illustrating that bilayer and multilayer graphenes are natural candidates for the study of non-linear transport effects.

  5. Negative Coulomb Drag in Double Bilayer Graphene.

    PubMed

    Li, J I A; Taniguchi, T; Watanabe, K; Hone, J; Levchenko, A; Dean, C R

    2016-07-22

    We report on an experimental measurement of Coulomb drag in a double quantum well structure consisting of bilayer-bilayer graphene, separated by few layer hexagonal boron nitride. At low temperatures and intermediate densities, a novel negative drag response with an inverse sign is observed, distinct from the momentum and energy drag mechanisms previously reported in double monolayer graphene. By varying the device aspect ratio, the negative drag component is suppressed and a response consistent with pure momentum drag is recovered. In the momentum drag dominated regime, excellent quantitative agreement with the density and temperature dependence predicted for double bilayer graphene is found. PMID:27494491

  6. Temperature effect on plasmons in bilayer graphene

    SciTech Connect

    Patel, Digish K. Sharma, A. C.; Ashraf, S. S. Z.; Ambavale, S. K.

    2015-06-24

    We have theoretically investigated the plasmon dispersion and damping rate of doped bilayer graphene (BLG) at finite temperatures within the random phase approximation. Our computed results on plasmon dispersion show that plasmon frequency enhances with increasing temperatures in contrast to single layer graphene where it is suppressed. This can be attributed to the fact that the dynamic response of the electron gas or screening in bilayer graphene is different from that of single layer graphene. Further the temperature effect on damping rate is also discussed.

  7. Electronic multicriticality in bilayer graphene

    NASA Astrophysics Data System (ADS)

    Cvetkovic, Vladimir; Throckmorton, Robert E.; Vafek, Oskar

    2012-08-01

    We map out the possible ordered states in bilayer graphene at the neutrality point by extending the previous renormalization group treatment of many-body instabilities to finite temperature, trigonal warping and externally applied perpendicular electric field. We were able to analytically determine all outcomes of the RG flow equations for the nine four-fermion coupling constants. While the full phase diagram exhibits a rich structure, we confirm that when forward scattering dominates, the only ordering tendency with divergent susceptibility at finite temperature is the nematic. At finite temperature, this result is stable with respect to small back and layer imbalance scattering; further increasing their strength leads to the layer antiferromagnet. We also determine conditions for other ordered states to appear and compare our results to the special cases of attractive and repulsive Hubbard models where exact results are available.

  8. RKKY interaction in bilayer graphene

    NASA Astrophysics Data System (ADS)

    Mohammadi, Yawar; Moradian, Rostam

    2015-12-01

    We study the RKKY interaction between two magnetic impurities located on the same layer (intralayer case) or on different layers (interlayer case) in undoped bilayer graphene (BLG) in the four-bands model, by directly calculating the Green functions in the eigenvalues and eigenvectors representation. Our results show that both intra- and interlayer RKKY interactions between two magnetic impurities located on the same (opposite) sublattice are always ferromagnetic (antiferromagnetic). Furthermore we find unusual long-distance decay of the RKKY interaction in BLG. The intralyer RKKY interactions between two magnetic impurities located on the same sublattice, J AnAn(R) and J BnBn(R), decay closely as 1 /R6 and 1 /R2 at large impurity distances respectively, but when they are located on opposite sublattices the RKKY interactions exhibit 1 /R4 decays approximately. In the interlayer case, the RKKY interactions between two magnetic impurities located on the same sublattice show a decay close to 1 /R4 at large impurity distances, but if two magnetic impurities be on opposite sublattices the RKKY interactions, J A1B2(R) and J B1A2(R), decay closely as 1 /R6 and 1 /R2 respectively. Both intra- and interlayer RKKY interactions have anisotropic oscillatory factors which for intralayer case is equal to that for single layer graphene (SLG). Our results at weak and strong interlayer coupling limits reduce to the RKKY interaction of SLG and that of BLG in the two-bands approximation respectively.

  9. How Bilayer Graphene Got a Bandgap

    SciTech Connect

    Wang, Feng

    2009-01-01

    Graphene is the two-dimensional crystalline form of carbon, whose extraordinary electron mobility and other unique features hold great promise for nanoscale electronics and photonics. But theres a catch: graphene has no bandgap. Now Feng Wang and his colleagues at Berkeley Lab and UC Berkeley have engineered a bandgap in bilayer graphene that can be precisely controlled from 0 to 250 milli-electron volts, which is the energy of infrared radiation.

  10. How Bilayer Graphene Got a Bandgap

    ScienceCinema

    Wang, Feng

    2013-05-29

    Graphene is the two-dimensional crystalline form of carbon, whose extraordinary electron mobility and other unique features hold great promise for nanoscale electronics and photonics. But theres a catch: graphene has no bandgap. Now Feng Wang and his colleagues at Berkeley Lab and UC Berkeley have engineered a bandgap in bilayer graphene that can be precisely controlled from 0 to 250 milli-electron volts, which is the energy of infrared radiation.

  11. How Bilayer Graphene Got a Bandgap

    ScienceCinema

    Feng Wang

    2010-01-08

    Graphene is the two-dimensional crystalline form of carbon, whose extraordinary electron mobility and other unique features hold great promise for nanoscale electronics and photonics. But theres a catch: graphene has no bandgap. Now Feng Wang and his colleagues at Berkeley Lab and UC Berkeley have engineered a bandgap in bilayer graphene that can be precisely controlled from 0 to 250 milli-electron volts, which is the energy of infrared radiation.

  12. How Bilayer Graphene Got a Bandgap

    SciTech Connect

    Feng Wang

    2009-06-02

    Graphene is the two-dimensional crystalline form of carbon, whose extraordinary electron mobility and other unique features hold great promise for nanoscale electronics and photonics. But theres a catch: graphene has no bandgap. Now Feng Wang and his colleagues at Berkeley Lab and UC Berkeley have engineered a bandgap in bilayer graphene that can be precisely controlled from 0 to 250 milli-electron volts, which is the energy of infrared radiation.

  13. Bandgap scaling in bilayer graphene antidot lattices.

    PubMed

    Petersen, René; Pedersen, Thomas Garm

    2015-06-10

    On the basis of a tight binding model we reveal how the bandgap in bilayer graphene antidot lattices (GALs) follows a different scaling law than in monolayer GALs and we provide an explanation using the Dirac model. We show that previous findings regarding the criteria for the appearance of a bandgap in monolayer GALs are equally applicable to the bilayer case. Furthermore, we briefly investigate the optical properties of bilayer GALs and show that estimates of the bandgap using optical methods could lead to overestimates due to weak oscillator strength of the lowest transitions. Finally, we investigate the effect of imposing an electric field perpendicular to the bilayer GAL structure and find that the bandgap tunability may be extended as compared to pristine bilayer graphene. PMID:25989621

  14. Thermally activated conductivity in gapped bilayer graphene

    NASA Astrophysics Data System (ADS)

    Trushin, Maxim

    2012-05-01

    This is a theoretical study of electron transport in gated bilayer graphene —a novel semiconducting material with a tunable band gap. It is shown that the which-layer pseudospin coherence enhances the subgap conductivity and facilitates the thermally activated transport. The mechanism proposed can also lead to the non-monotonic conductivity vs. temperature dependence at a band gap size of the order of 10 meV. The effect can be observed in gapped bilayer graphene sandwiched in boron nitride where the electron-hole puddles and flexural phonons are strongly suppressed.

  15. Screened energy loss rate in bilayer graphene

    NASA Astrophysics Data System (ADS)

    Ansari, Meenhaz; Ashraf, S. S. Z.; Ahmad, Afzal

    2016-05-01

    We investigate the energy relaxation of hot carriers in bilayer graphene through coupling to acoustic phonons interacting via the Deformation potential in the Boltzmann transport equation approach. We incorporate static screening in the estimation of the power loss rate as screening has a more functional role in bilayer graphene. It is observed that on the incorporation of screening the magnitude as well as the power exponent both is affected with the power exponent changed from T4 to T5.92 in the lower temperature range upto 3K and to T1.04 dependence in the higher temperature range that is 170-300K.

  16. Bilayer graphene quantum dot defined by topgates

    SciTech Connect

    Müller, André; Kaestner, Bernd; Hohls, Frank; Weimann, Thomas; Pierz, Klaus; Schumacher, Hans W.

    2014-06-21

    We investigate the application of nanoscale topgates on exfoliated bilayer graphene to define quantum dot devices. At temperatures below 500 mK, the conductance underneath the grounded gates is suppressed, which we attribute to nearest neighbour hopping and strain-induced piezoelectric fields. The gate-layout can thus be used to define resistive regions by tuning into the corresponding temperature range. We use this method to define a quantum dot structure in bilayer graphene showing Coulomb blockade oscillations consistent with the gate layout.

  17. Chiral electron transport in CVD bilayer graphene

    NASA Astrophysics Data System (ADS)

    Lee, Kyunghoon; Eo, Yun Suk; Kurdak, Cagliyan; Zhong, Zhaohui

    2014-03-01

    Charge carriers in bilayer graphene have a parabolic energy spectrum. Due to this band structure they are massive quasiparticles having a finite density of state at zero energy like other non-relativistic charge carriers in conventional two dimensional materials. However, they are massive Dirac fermions which have a chiral nature similar to the case of massless Dirac fermions in single layer graphene. Coupling of pseudospin and motion of charge carrier via chirality can result in dramatic consequence for transport in bipolar regime like Klein tunneling, Fabry-Perot interference, collimation of charge carrier, Veslago lens, etc. However, little attention has been paid to chiral dependent electron transport in bilayer graphene. Here we study these properties by probing phase coherent transport behavior in CVD bilayer graphene devices with sub-200nm channel length. Complex Fabry-Perot interference patterns are observed in resonant cavities defined by local gating. By applying Fourier analysis technique, we successfully analyze and identify the origin of each individual interference pattern in bipolar and monopolar regime. Our initial results also hint at the observation of cloaking of electronic states against chiral electrons in bilayer graphene.

  18. Berry phase transition in twisted bilayer graphene

    NASA Astrophysics Data System (ADS)

    Rode, Johannes C.; Smirnov, Dmitri; Schmidt, Hennrik; Haug, Rolf J.

    2016-09-01

    The electronic dispersion of a graphene bilayer is highly dependent on rotational mismatch between layers and can be further manipulated by electrical gating. This allows for an unprecedented control over electronic properties and opens up the possibility of flexible band structure engineering. Here we present novel magnetotransport data in a twisted bilayer, crossing the energetic border between decoupled monolayers and coupled bilayer. In addition a transition in Berry phase between π and 2π is observed at intermediate magnetic fields. Analysis of Fermi velocities and gate induced charge carrier densities suggests an important role of strong layer asymmetry for the observed phenomena.

  19. Layer resolved capacitive probing of graphene bilayers

    NASA Astrophysics Data System (ADS)

    Zibrov, Alexander; Parmentier, François; Li, Jia; Wang, Lei; Hunt, Benjamin; Dean, Cory; Hone, James; Taniguchi, Takashi; Watanabe, Kenji; Young, Andrea

    Compared to single layer graphene, graphene bilayers have an additional ``which-layer'' degree of freedom that can be controlled by an external electric field in a dual-gated device geometry. We describe capacitance measurements capable of directly probing this degree of freedom. By performing top gate, bottom gate, and penetration field capacitance measurements, we directly extract layer polarization of both Bernal and twisted bilayers. We will present measurements of hBN encapsulated bilayers at both zero and high magnetic field, focusing on the physics of the highly degenerate zero-energy Landau level in the high magnetic field limit where spin, valley, and layer degeneracy are all lifted by electronic interactions.

  20. Self-folding graphene-polymer bilayers

    NASA Astrophysics Data System (ADS)

    Deng, Tao; Yoon, ChangKyu; Jin, Qianru; Li, Mingen; Liu, Zewen; Gracias, David H.

    2015-05-01

    In order to incorporate the extraordinary intrinsic thermal, electrical, mechanical, and optical properties of graphene with three dimensional (3D) flexible substrates, we introduce a solvent-driven self-folding approach using graphene-polymer bilayers. A polymer (SU-8) film was spin coated atop chemically vapor deposited graphene films on wafer substrates and graphene-polymer bilayers were patterned with or without metal electrodes using photolithography, thin film deposition, and etching. After patterning, the bilayers were released from the substrates and they self-folded to form fully integrated, curved, and folded structures. In contrast to planar graphene sensors on rigid substrates, we assembled curved and folded sensors that are flexible and they feature smaller form factors due to their 3D geometry and large surface areas due to their multiple rolled architectures. We believe that this approach could be used to assemble a range of high performance 3D electronic and optical devices of relevance to sensing, diagnostics, wearables, and energy harvesting.

  1. Self-folding graphene-polymer bilayers

    SciTech Connect

    Deng, Tao; Yoon, ChangKyu; Jin, Qianru; Li, Mingen; Liu, Zewen; Gracias, David H.

    2015-05-18

    In order to incorporate the extraordinary intrinsic thermal, electrical, mechanical, and optical properties of graphene with three dimensional (3D) flexible substrates, we introduce a solvent-driven self-folding approach using graphene-polymer bilayers. A polymer (SU-8) film was spin coated atop chemically vapor deposited graphene films on wafer substrates and graphene-polymer bilayers were patterned with or without metal electrodes using photolithography, thin film deposition, and etching. After patterning, the bilayers were released from the substrates and they self-folded to form fully integrated, curved, and folded structures. In contrast to planar graphene sensors on rigid substrates, we assembled curved and folded sensors that are flexible and they feature smaller form factors due to their 3D geometry and large surface areas due to their multiple rolled architectures. We believe that this approach could be used to assemble a range of high performance 3D electronic and optical devices of relevance to sensing, diagnostics, wearables, and energy harvesting.

  2. Electronic properties of graphene-based bilayer systems

    NASA Astrophysics Data System (ADS)

    Rozhkov, A. V.; Sboychakov, A. O.; Rakhmanov, A. L.; Nori, Franco

    2016-08-01

    This article reviews the theoretical and experimental work related to the electronic properties of bilayer graphene systems. Three types of bilayer stackings are discussed: the AA, AB, and twisted bilayer graphene. This review covers single-electron properties, effects of static electric and magnetic fields, bilayer-based mesoscopic systems, spin-orbit coupling, dc transport and optical response, as well as spontaneous symmetry violation and other interaction effects. The selection of the material aims to introduce the reader to the most commonly studied topics of theoretical and experimental research in bilayer graphene.

  3. Giant magnetoresistance in bilayer graphene nanoflakes

    NASA Astrophysics Data System (ADS)

    Farghadan, Rouhollah; Farekiyan, Marzieh

    2016-09-01

    Coherent spin transport through bilayer graphene (BLG) nanoflakes sandwiched between two electrodes made of single-layer zigzag graphene nanoribbon was investigated by means of Landauer-Buttiker formalism. Application of a magnetic field only on BLG structure as a channel produces a perfect spin polarization in a large energy region. Moreover, the conductance could be strongly modulated by magnetization of the zigzag edge of AB-stacked BLG, and the junction, entirely made of carbon, produces a giant magnetoresistance (GMR) up to 100%. Intestinally, GMR and spin polarization could be tuned by varying BLG width and length. Generally, MR in a AB-stacked BLG strongly increases (decreases) with length (width).

  4. Synthesis and sensing application of large scale bilayer graphene

    NASA Astrophysics Data System (ADS)

    Hong, Sung Ju; Yoo, Jung Hoon; Baek, Seung Jae; Park, Yung Woo

    2012-02-01

    We have synthesized large scale bilayer graphene by using Chemical Vapor Deposition (CVD) in atmospheric pressure. Bilayer graphene was grown by using CH4, H2 and Ar gases. The growth temperature was 1050^o. Conventional FET measurement shows ambipolar transfer characteristics. Results of Raman spectroscopy, Atomic Force microscope (AFM) and Transmission Electron Microscope (TEM) indicate the film is bilayer graphene. Especially, adlayer structure which interrupt uniformity was reduced in low methane flow condition. Furthermore, large size CVD bilayer graphene film can be investigated to apply sensor devices. By using conventional photolithography process, we have fabricated device array structure and studied sensing behavior.

  5. The electronic properties of bilayer graphene

    NASA Astrophysics Data System (ADS)

    McCann, Edward; Koshino, Mikito

    2013-05-01

    We review the electronic properties of bilayer graphene, beginning with a description of the tight-binding model of bilayer graphene and the derivation of the effective Hamiltonian describing massive chiral quasiparticles in two parabolic bands at low energies. We take into account five tight-binding parameters of the Slonczewski-Weiss-McClure model of bulk graphite plus intra- and interlayer asymmetry between atomic sites which induce band gaps in the low-energy spectrum. The Hartree model of screening and band-gap opening due to interlayer asymmetry in the presence of external gates is presented. The tight-binding model is used to describe optical and transport properties including the integer quantum Hall effect, and we also discuss orbital magnetism, phonons and the influence of strain on electronic properties. We conclude with an overview of electronic interaction effects.

  6. Incoherent interlayer conduction in twisted bilayer graphene

    NASA Astrophysics Data System (ADS)

    Kim, Youngwook; Nam, S.-G.; Lee, H.-J.; Kim, Jun Sung; Yun, H.; Lee, S. W.; Son, M.; Choi, H. C.; Lee, D. S.; Kim, D. C.; Seo, S.

    2014-03-01

    Coherent motion of the electrons in the Bloch states often breaks down for the interlayer conduction in layered materials where the interlayer coupling is significantly reduced by e.g. large interlayer separation. Here, we report complete suppression of coherent conduction in twisted bilayer graphene even with an atomic length scale of layer separation. The interlayer conduction were investigated using a cross junction of monolayer graphene layers. The interlayer resistivity is much higher than the c-axis resistivity of Bernal-stacked graphite and exhibits strong dependence on temperature as well as on external electric fields. These results suggest that the graphene layers are significantly decoupled by rotation, and the incoherent electron tunneling is the main interlayer conduction channel. In this regime, the interlayer conduction is determined by the overlap of the Dirac Fermi surfaces (FS) from each layer. The angle dependence of the interlayer resistivity is found to be relatively strong at low temperatures, while it becomes moderate and monotonous at high temperatures. This demonstrates the importance of phonon-mediated conduction at high temperatures, which enhances the overlap between the momentum-mismatched FS's in twisted bilayer graphene.

  7. Energy levels of hybrid monolayer-bilayer graphene quantum dots

    NASA Astrophysics Data System (ADS)

    Mirzakhani, M.; Zarenia, M.; Ketabi, S. A.; da Costa, D. R.; Peeters, F. M.

    2016-04-01

    Often real samples of graphene consist of islands of both monolayer and bilayer graphene. Bound states in such hybrid quantum dots are investigated for (i) a circular single-layer graphene quantum dot surrounded by an infinite bilayer graphene sheet and (ii) a circular bilayer graphene quantum dot surrounded by an infinite single-layer graphene. Using the continuum model and applying zigzag boundary conditions at the single-layer-bilayer graphene interface, we obtain analytical results for the energy levels and the corresponding wave spinors. Their dependence on perpendicular magnetic and electric fields are studied for both types of quantum dots. The energy levels exhibit characteristics of interface states, and we find anticrossings and closing of the energy gap in the presence of a bias potential.

  8. Atomistic mechanisms for bilayer growth of graphene on metal substrates

    NASA Astrophysics Data System (ADS)

    Chen, Wei; Cui, Ping; Zhu, Wenguang; Kaxiras, Efthimios; Gao, Yanfei; Zhang, Zhenyu

    2015-01-01

    Epitaxial growth on metal substrates has been shown to be the most powerful approach in producing large-scale high-quality monolayer graphene, yet it remains a major challenge to realize uniform bilayer graphene growth. Here we carry out a comparative study of the atomistic mechanisms for bilayer graphene growth on the (111) surfaces of Cu and Ni, using multiscale approaches combining first-principles calculations and rate-equation analysis. We first show that the relatively weak graphene-Cu interaction enhances the lateral diffusion and effective nucleation of C atoms underneath the graphene island, thereby making it more feasible to grow bilayer graphene on Cu. In contrast, the stronger graphene-Ni interaction suppresses the lateral mobility and dimerization of C atoms underneath the graphene, making it unlikely to achieve controlled growth of bilayer graphene on Ni. We then determine the critical graphene size beyond which nucleation of the second layer will take place. Intriguingly, the critical size exhibits an effective inverse "Ehrlich-Schwoebel barrier" effect, becoming smaller for faster C migration from the Cu surface to the graphene-Cu interface sites across the graphene edge. These findings allow us to propose a novel alternating growth scheme to realize mass production of bilayer graphene.

  9. Atomistic mechanisms for bilayer growth of graphene on metal substrates

    SciTech Connect

    Chen, Wei; Cui, Ping; Zhu, Wenguang; Kaxiras, Efthimios; Gao, Yanfei; Zhang, Zhenyu

    2015-01-08

    Epitaxial growth on metal substrates has been shown to be the most powerful approach in producing large-scale high-quality monolayer graphene, yet it remains a major challenge to realize uniform bilayer graphene growth. Here we carry out a comparative study of the atomistic mechanisms for bilayer graphene growth on the (111) surfaces of Cu and Ni, using multiscale approaches combining first-principles calculations and rate-equation analysis. We first show that the relatively weak graphene-Cu interaction enhances the lateral diffusion and effective nucleation of C atoms underneath the graphene island, thereby making it more feasible to grow bilayer graphene on Cu. In contrast, the stronger graphene-Ni interaction suppresses the lateral mobility and dimerization of C atoms underneath the graphene, making it unlikely to achieve controlled growth of bilayer graphene on Ni. We then determine the critical graphene size beyond which nucleation of the second layer will take place. Intriguingly, the critical size exhibits an effective inverse "Ehrlich-Schwoebel barrier" effect, becoming smaller for faster C migration from the Cu surface to the graphene-Cu interface sites across the graphene edge. Lastly, these findings allow us to propose a novel alternating growth scheme to realize mass production of bilayer graphene.

  10. Atomistic mechanisms for bilayer growth of graphene on metal substrates

    DOE PAGESBeta

    Chen, Wei; Cui, Ping; Zhu, Wenguang; Kaxiras, Efthimios; Gao, Yanfei; Zhang, Zhenyu

    2015-01-08

    Epitaxial growth on metal substrates has been shown to be the most powerful approach in producing large-scale high-quality monolayer graphene, yet it remains a major challenge to realize uniform bilayer graphene growth. Here we carry out a comparative study of the atomistic mechanisms for bilayer graphene growth on the (111) surfaces of Cu and Ni, using multiscale approaches combining first-principles calculations and rate-equation analysis. We first show that the relatively weak graphene-Cu interaction enhances the lateral diffusion and effective nucleation of C atoms underneath the graphene island, thereby making it more feasible to grow bilayer graphene on Cu. In contrast,more » the stronger graphene-Ni interaction suppresses the lateral mobility and dimerization of C atoms underneath the graphene, making it unlikely to achieve controlled growth of bilayer graphene on Ni. We then determine the critical graphene size beyond which nucleation of the second layer will take place. Intriguingly, the critical size exhibits an effective inverse "Ehrlich-Schwoebel barrier" effect, becoming smaller for faster C migration from the Cu surface to the graphene-Cu interface sites across the graphene edge. Lastly, these findings allow us to propose a novel alternating growth scheme to realize mass production of bilayer graphene.« less

  11. Twisted bilayer graphene with interlayer potential asymmetry

    NASA Astrophysics Data System (ADS)

    Moon, Pilkyung; Son, Young-Woo; Koshino, Mikito

    A twisted stack of two graphene layers (twisted bilayer graphene) exhibits an extremely long potential period arising from the moiré interference between the layers. We investigate the band structure and optical absorption spectrum of twisted bilayer graphenes with changing interlayer bias and Fermi energy simultaneously. We show that the interlayer bias lifts the degeneracy of the superlattice Dirac point, while the amount of the Dirac point shift is significantly suppressed in small rotation angles, and even becomes opposite to the applied bias, by the interlayer interaction. In addition, we show that the spectroscopic features are highly sensitive to the interlayer bias and the Fermi energy, and widely tunable by the external field effect. P.M. acknowledges the support of NYU Shanghai and the NYU-ECNU Institute of Physics at NYU Shanghai. Y.-W.S. was supported by the NRF of Korea grant funded by the MSIP. M.K. was funded by JSPS Grantin-Aid for Scientific Research.

  12. Molecular Dynamics Study of Ripples in Graphene and Bilayer Graphene

    NASA Astrophysics Data System (ADS)

    Singh, Arunima; Hennig, Richard G.

    2012-02-01

    Transmission electron microscopy experiments have shown that suspended graphene is not perfectly flat, but displays ripples such that the surface normal of graphene varies by several degrees [1,2]. For multi-layered graphene, the ripples are suppressed with increasing numbers of layers. Recent experiments demonstrated that ripples in suspended graphene can also be controlled by mechanical and thermally induced strain [3]. Knowledge of and control over the ripples in graphene is desirable for fabricating and designing of strain-based devices. We show using molecular dynamics simulation that thermally induced ripples in suspended single and multi-layer graphene at room temperature result in deviations of the local surface normal by ± 7 ^o and ± 4 ^o for single and bilayer graphene, respectively. These angular deviations are in excellent agreement with transmission electron microscopy results [2] and confirm that these ripples can be dynamic and thermally induced. We also study how these angles change as a function of applied tensile and shear strain. [1] Meyer J. C., Geim A. K., et al. Solid State Communications, 143, 101 (2007). [2] Meyer J.C., Geim A.K., et al. Nature, 446, 60 (2007). [3] Bao W., Miao F., et al. Nature Nanotechnology, 4 (9), 562 (2009).

  13. Superlubricity in quasicrystalline twisted bilayer graphene

    NASA Astrophysics Data System (ADS)

    Koren, Elad; Duerig, Urs

    2016-05-01

    The unique atomic positions in quasicrystals lead to peculiar self-similarity and fractal-like structural morphology. Accordingly, many of the material properties are supposed to manifest exceptional characteristics. In this Rapid Communication, we explain through numerical simulations the fundamental and peculiar aspects of quasicrystals wearless friction manifested in a 30° twisted bilayer graphene system. In particular, the sliding force exhibits a fractal structure with distinct area correlations due to the natural mixture between both periodic and aperiodic lateral modulations. In addition, zero power scaling of the sliding force with respect to the contact area is demonstrated for a geometric sequence of dodecagonal elements.

  14. Twisted bi-layer graphene: microscopic rainbows.

    PubMed

    Campos-Delgado, J; Algara-Siller, G; Santos, C N; Kaiser, U; Raskin, J-P

    2013-10-11

    Blue, pink, and yellow colorations appear from twisted bi-layer graphene (tBLG) when transferred to a SiO2 /Si substrate (SiO2 = 100 nm-thick). Raman and electron microscope studies reveal that these colorations appear for twist angles in the 9-15° range. Optical contrast simulations confirm that the observed colorations are related to the angle-dependent electronic properties of tBLG combined with the reflection that results from the layered structure tBLG/100 nm-thick SiO2 /Si. PMID:23606323

  15. Terahertz conductivity of twisted bilayer graphene.

    PubMed

    Zou, Xingquan; Shang, Jingzhi; Leaw, Jianing; Luo, Zhiqiang; Luo, Liyan; La-o-Vorakiat, Chan; Cheng, Liang; Cheong, S A; Su, Haibin; Zhu, Jian-Xin; Liu, Yanpeng; Loh, Kian Ping; Castro Neto, A H; Yu, Ting; Chia, Elbert E M

    2013-02-01

    Using terahertz time-domain spectroscopy, the real part of optical conductivity [σ(1)(ω)] of twisted bilayer graphene was obtained at different temperatures (10-300 K) in the frequency range 0.3-3 THz. On top of a Drude-like response, we see a strong peak in σ(1)(ω) at ~2.7 THz. We analyze the overall Drude-like response using a disorder-dependent (unitary scattering) model, then attribute the peak at 2.7 THz to an enhanced density of states at that energy, which is caused by the presence of a van Hove singularity arising from a commensurate twisting of the two graphene layers. PMID:23432306

  16. Interaction driven quantum Hall effect in artificially stacked graphene bilayers.

    PubMed

    Iqbal, Muhammad Zahir; Iqbal, Muhammad Waqas; Siddique, Salma; Khan, Muhammad Farooq; Ramay, Shahid Mahmood; Nam, Jungtae; Kim, Keun Soo; Eom, Jonghwa

    2016-01-01

    The honeycomb lattice structure of graphene gives rise to its exceptional electronic properties of linear dispersion relation and its chiral nature of charge carriers. The exceptional electronic properties of graphene stem from linear dispersion relation and chiral nature of charge carries, originating from its honeycomb lattice structure. Here, we address the quantum Hall effect in artificially stacked graphene bilayers and single layer graphene grown by chemical vapor deposition. The quantum Hall plateaus started to appear more than 3 T and became clearer at higher magnetic fields up to 9 T. Shubnikov-de Hass oscillations were manifestly observed in graphene bilayers texture. These unusual plateaus may have been due to the layers interaction in artificially stacked graphene bilayers. Our study initiates the understanding of interactions between artificially stacked graphene layers. PMID:27098387

  17. Interaction driven quantum Hall effect in artificially stacked graphene bilayers

    PubMed Central

    Iqbal, Muhammad Zahir; Iqbal, Muhammad Waqas; Siddique, Salma; Khan, Muhammad Farooq; Ramay, Shahid Mahmood; Nam, Jungtae; Kim, Keun Soo; Eom, Jonghwa

    2016-01-01

    The honeycomb lattice structure of graphene gives rise to its exceptional electronic properties of linear dispersion relation and its chiral nature of charge carriers. The exceptional electronic properties of graphene stem from linear dispersion relation and chiral nature of charge carries, originating from its honeycomb lattice structure. Here, we address the quantum Hall effect in artificially stacked graphene bilayers and single layer graphene grown by chemical vapor deposition. The quantum Hall plateaus started to appear more than 3 T and became clearer at higher magnetic fields up to 9 T. Shubnikov-de Hass oscillations were manifestly observed in graphene bilayers texture. These unusual plateaus may have been due to the layers interaction in artificially stacked graphene bilayers. Our study initiates the understanding of interactions between artificially stacked graphene layers. PMID:27098387

  18. Interaction driven quantum Hall effect in artificially stacked graphene bilayers

    NASA Astrophysics Data System (ADS)

    Iqbal, Muhammad Zahir; Iqbal, Muhammad Waqas; Siddique, Salma; Khan, Muhammad Farooq; Ramay, Shahid Mahmood; Nam, Jungtae; Kim, Keun Soo; Eom, Jonghwa

    2016-04-01

    The honeycomb lattice structure of graphene gives rise to its exceptional electronic properties of linear dispersion relation and its chiral nature of charge carriers. The exceptional electronic properties of graphene stem from linear dispersion relation and chiral nature of charge carries, originating from its honeycomb lattice structure. Here, we address the quantum Hall effect in artificially stacked graphene bilayers and single layer graphene grown by chemical vapor deposition. The quantum Hall plateaus started to appear more than 3 T and became clearer at higher magnetic fields up to 9 T. Shubnikov-de Hass oscillations were manifestly observed in graphene bilayers texture. These unusual plateaus may have been due to the layers interaction in artificially stacked graphene bilayers. Our study initiates the understanding of interactions between artificially stacked graphene layers.

  19. A circuit model for defective bilayer graphene transistors

    NASA Astrophysics Data System (ADS)

    Umoh, Ime J.; Moktadir, Zakaria; Hang, Shuojin; Kazmierski, Tom J.; Mizuta, Hiroshi

    2016-05-01

    This paper investigates the behaviour of a defective single-gate bilayer graphene transistor. Point defects were introduced into pristine graphene crystal structure using a tightly focused helium ion beam. The transfer characteristics of the exposed transistors were measured ex-situ for different defect concentrations. The channel peak resistance increased with increasing defect concentration whilst the on-off ratio showed a decreasing trend for both electrons and holes. To understand the electrical behaviour of the transistors, a circuit model for bilayer graphene is developed which shows a very good agreement when validated against experimental data. The model allowed parameter extraction of bilayer transistor and can be implemented in circuit level simulators.

  20. Electron diffraction studies on CVD grown bi-layered graphene

    NASA Astrophysics Data System (ADS)

    Lingam, Kiran; Karakaya, Mehmet; Podila, Ramakrishna; Quin, Haijun; Rao, Apparao; Dept. of Physics and Astronomy, Clemson University, Clemson, SC USA 29634. Team; Advanced Materials Research Laboratories, Clemson University, Anderson, SC USA 29625 Collaboration

    2013-03-01

    Graphene has generated enormous interest in the scientific community due to its peculiar properties like electron mobility, thermal conductivity etc. Several recent reports on exfoliated graphene emphasized the role of layer stacking on the electronic and optical properties of graphene in case of bi-layered and few layered graphene and several synthesis techniques like chemical vapor deposition (CVD) on Copper foils are employed to prepare graphene for applications at a large scale. However, a correlated study pertinent to the stacking order in CVD grown graphene is still unclear. In this work, using a combination of Raman spectroscopy and selected area electron diffraction analysis we analyzed the preferred misorientation angles in a CVD grown bi-layered graphene and also the role of Cu crystal facets on the graphene stacking order will be presented.

  1. Detection of bilayer lipid with graphene nanoribbon

    NASA Astrophysics Data System (ADS)

    Akbari, Elnaz; Buntat, Zolkafle; Afroozeh, Abdolkarim; Zeinalinezhad, Alireza; Nilashi, Mehrbakhsh

    2015-09-01

    Single-layer graphene consists of sp 2-bonded carbon atoms arranged in a two-dimensional (2D) hexagonal lattice comprising a thin layer of single carbon atoms. Owing to its special characteristics including electrical, physical, and optical properties, graphene is considered more suitable for sensor applications than other materials. Moreover, it is possible to produce biosensors using electrolyte-gated field-effect transistors based on graphene (GFETs) to identify the alterations in charged lipid membrane properties. This paper illustrates how membrane thickness and electrical charge can result in a monolayer GFET, with emphasis on conductance variation. It is proposed that the thickness and electrical charge of the lipid bilayer are functions of carrier density, and equations relating these suitable control parameters were derived. Adaptive neuro fuzzy inference system (ANFIS) has been incorporated to obtain other model for conductance characteristic. The comparison between the analytical models and ANFIS with the experimental data extracted from previous work show an acceptable agreement. [Figure not available: see fulltext.

  2. Robustly Engineering Thermal Conductivity of Bilayer Graphene by Interlayer Bonding

    NASA Astrophysics Data System (ADS)

    Zhang, Xiaoliang; Gao, Yufei; Chen, Yuli; Hu, Ming

    2016-02-01

    Graphene and its bilayer structure are the two-dimensional crystalline form of carbon, whose extraordinary electron mobility and other unique features hold great promise for nanoscale electronics and photonics. Their realistic applications in emerging nanoelectronics usually call for thermal transport manipulation in a controllable and precise manner. In this paper we systematically studied the effect of interlayer covalent bonding, in particular different interlay bonding arrangement, on the thermal conductivity of bilayer graphene using equilibrium molecular dynamics simulations. It is revealed that, the thermal conductivity of randomly bonded bilayer graphene decreases monotonically with the increase of interlayer bonding density, however, for the regularly bonded bilayer graphene structure the thermal conductivity possesses unexpectedly non-monotonic dependence on the interlayer bonding density. The results suggest that the thermal conductivity of bilayer graphene depends not only on the interlayer bonding density, but also on the detailed topological configuration of the interlayer bonding. The underlying mechanism for this abnormal phenomenon is identified by means of phonon spectral energy density, participation ratio and mode weight factor analysis. The large tunability of thermal conductivity of bilayer graphene through rational interlayer bonding arrangement paves the way to achieve other desired properties for potential nanoelectronics applications involving graphene layers.

  3. Robustly Engineering Thermal Conductivity of Bilayer Graphene by Interlayer Bonding

    PubMed Central

    Zhang, Xiaoliang; Gao, Yufei; Chen, Yuli; Hu, Ming

    2016-01-01

    Graphene and its bilayer structure are the two-dimensional crystalline form of carbon, whose extraordinary electron mobility and other unique features hold great promise for nanoscale electronics and photonics. Their realistic applications in emerging nanoelectronics usually call for thermal transport manipulation in a controllable and precise manner. In this paper we systematically studied the effect of interlayer covalent bonding, in particular different interlay bonding arrangement, on the thermal conductivity of bilayer graphene using equilibrium molecular dynamics simulations. It is revealed that, the thermal conductivity of randomly bonded bilayer graphene decreases monotonically with the increase of interlayer bonding density, however, for the regularly bonded bilayer graphene structure the thermal conductivity possesses unexpectedly non-monotonic dependence on the interlayer bonding density. The results suggest that the thermal conductivity of bilayer graphene depends not only on the interlayer bonding density, but also on the detailed topological configuration of the interlayer bonding. The underlying mechanism for this abnormal phenomenon is identified by means of phonon spectral energy density, participation ratio and mode weight factor analysis. The large tunability of thermal conductivity of bilayer graphene through rational interlayer bonding arrangement paves the way to achieve other desired properties for potential nanoelectronics applications involving graphene layers. PMID:26911859

  4. Effect of impurity doping in gapped bilayer graphene

    SciTech Connect

    Han, Qi; Yan, Baoming; Jia, Zhenzhao; Niu, Jingjing; Yu, Dapeng; Wu, Xiaosong

    2015-10-19

    Impurity doping plays a pivotal role in semiconductor electronics. We study the doping effect in a two-dimensional semiconductor, gapped bilayer graphene. By employing in situ deposition of calcium on the bilayer graphene, dopants are controllably introduced. Low temperature transport results show a variable range hopping conduction near the charge neutrality point persisting up to 50 K, providing evidence for the impurity levels inside the gap. Our experiment confirms a predicted peculiar effect in the gapped bilayer graphene, i.e., formation of in-gap states even if the bare impurity level lies in the conduction band. The result provides perspective on the effect of doping and impurity levels in semiconducting bilayer graphene.

  5. Sub-wavelength antenna enhanced bilayer graphene tunable photodetector

    DOEpatents

    Beechem, III, Thomas Edwin; Howell, Stephen W.; Peters, David W.; Davids, Paul; Ohta, Taisuke

    2016-03-22

    The integration of bilayer graphene with an absorption enhancing sub-wavelength antenna provides an infrared photodetector capable of real-time spectral tuning without filters at nanosecond timescales.

  6. Terahertz conductivity of twisted bilayer graphene

    NASA Astrophysics Data System (ADS)

    Chia, Elbert E. M.; Zou, Xingquan; Shang, Jingzhi; Leaw, Jianing; Luo, Zhiqiang; Luo, Liyan; Cheong, Siew Ann; Su, Haibin; Zhu, Jian-Xin; Castro Neto, A. H.; Yu, Ting

    2013-03-01

    Using terahertz time-domain spectroscopy, the real part of optical conductivity [σ1 (ω) ] of twisted bilayer graphene was obtained at different temperatures (10 - 300 K) in the frequency range 0.3 - 3 THz. On top of a Drude-like response, we see a strong and narrow peak in σ1 (ω) at ~2.7 THz. We analyze the overall Drude-like response using a disorder-dependent (unitary scattering) model, then attribute the peak at 2.7 THz to an enhanced density of states at that energy, that is caused by the presence of van Hove singularities arising from a commensurate twisting of the two graphene layers. Singapore MOE AcRF Tier 2 (ARC 23/08), NRF-CRP (NRF-CRP4-2008-04), NNSA of the U.S. DOE at LANL (DE-AC52-06NA25396), LANL LDRD Program, NRF-CRP (R-144-000-295-281), DOE DE-FG02-08ER46512, ONR MURI N00014-09-1-1063.

  7. High-Precision Twist-Controlled Bilayer and Trilayer Graphene.

    PubMed

    Chen, Xu-Dong; Xin, Wei; Jiang, Wen-Shuai; Liu, Zhi-Bo; Chen, Yongsheng; Tian, Jian-Guo

    2016-04-01

    Twist-controlled bilayer graphene (tBLG) and double-twisted trilayer graphene (DTTG) with high precision are fabricated and their controllable optoelectronic properties are investigated for the first time. The successful fabrication of tBLG and DTTG with designated θ provides an attractive starting point for systematic studies of interlayer coupling in misoriented few-layer graphene systems with well-defined geometry. PMID:26822255

  8. Transfer matrix theory of monolayer graphene/bilayer graphene heterostructure superlattice

    SciTech Connect

    Wang, Yu

    2014-10-28

    We have formulated a transfer matrix method to investigate electronic properties of graphene heterostructure consisting of monolayer graphene and bilayer counterpart. By evaluating transmission, conductance, and band dispersion, we show that, irrespective of the different carrier chiralities in monolayer graphene and bilayer graphene, superlattice consisting of biased bilayer graphene barrier and monolayer graphene well can mimic the electronic properties of conventional semiconductor superlattice, displaying the extended subbands in the quantum tunneling regime and producing anisotropic minigaps for the classically allowed transport. Due to the lateral confinement, the lowest mode has shifted away from the charge neutral point of monolayer graphene component, opening a sizeable gap in concerned structure. Following the gate-field and geometry modulation, all electronic states and gaps between them can be externally engineered in an electric-controllable strategy.

  9. Twinning and twisting of tri- and bilayer graphene.

    PubMed

    Brown, Lola; Hovden, Robert; Huang, Pinshane; Wojcik, Michal; Muller, David A; Park, Jiwoong

    2012-03-14

    The electronic, optical, and mechanical properties of bilayer and trilayer graphene vary with their structure, including the stacking order and relative twist, providing novel ways to realize useful characteristics not available to single layer graphene. However, developing controlled growth of bilayer and trilayer graphene requires efficient large-scale characterization of multilayer graphene structures. Here, we use dark-field transmission electron microscopy for rapid and accurate determination of key structural parameters (twist angle, stacking order, and interlayer spacing) of few-layer CVD graphene. We image the long-range atomic registry for oriented bilayer and trilayer graphene, find that it conforms exclusively to either Bernal or rhombohedral stacking, and determine their relative abundances. In contrast, our data on twisted multilayers suggest the absence of such long-range atomic registry. The atomic registry and its absence are consistent with the two different strain-induced deformations we observe; by tilting the samples to break mirror symmetry, we find a high density of twinned domains in oriented multilayer graphene, where multiple domains of two different stacking configurations coexist, connected by discrete twin boundaries. In contrast, individual layers in twisted regions continuously stretch and shear independently, forming elaborate Moiré patterns. These results, and the twist angle distribution in our CVD graphene, can be understood in terms of an angle-dependent interlayer potential model. PMID:22329410

  10. Thermoelectric power in a bilayer graphene device

    NASA Astrophysics Data System (ADS)

    Yung-Yu, Chien; Hongtao, Yuan; Chang-Ran, Wang; Chun-Hsuan, Lin; Wei-Li, Lee; Geballe LaboratoryAdvanced Materials Collaboration; Institute of Physics, Academia Sinica, Taipei, Taiwan Team

    2014-03-01

    There have been great interests on band gap engineering in a bilayer graphene (BLG) device, where inversion symmetry breaking by a perpendicular electric field can give rise to a sizable band gap. In our previous works, we have demonstrated a large enhancement in the thermoelectric power (TEP) associated with the band gap opening in a dual-gated BLG device. It is, therefore, an interesting question to ask whether even larger TEP can be achieved with a larger perpendicular electric field applied. We explored such possibility by utilizing the ionic liquid gating technique in BLG devices. By controlling the side gate voltage of ionic liquid and the bottom gate voltage via SiO2/Si substrate, large increase of the sheet resistance at charge neutral point was observed suggesting the opening of a band gap. At T = 120 K, TEP increases by more than 44% with a side gate voltage of ~ 1V. The influence of charge puddles to TEP using ionic liquid gating will be discussed.

  11. Hot carrier relaxation of Dirac fermions in bilayer epitaxial graphene

    NASA Astrophysics Data System (ADS)

    Huang, J.; Alexander-Webber, J. A.; Janssen, T. J. B. M.; Tzalenchuk, A.; Yager, T.; Lara-Avila, S.; Kubatkin, S.; Myers-Ward, R. L.; Wheeler, V. D.; Gaskill, D. K.; Nicholas, R. J.

    2015-04-01

    Energy relaxation of hot Dirac fermions in bilayer epitaxial graphene is experimentally investigated by magnetotransport measurements on Shubnikov-de Haas oscillations and weak localization. The hot-electron energy loss rate is found to follow the predicted Bloch-Grüneisen power-law behaviour of T4 at carrier temperatures from 1.4 K up to ˜100 K, due to electron-acoustic phonon interactions with a deformation potential coupling constant of 22 eV. A carrier density dependence n_e-1.5 in the scaling of the T4 power law is observed in bilayer graphene, in contrast to the n_e-0.5 dependence in monolayer graphene, leading to a crossover in the energy loss rate as a function of carrier density between these two systems. The electron-phonon relaxation time in bilayer graphene is also shown to be strongly carrier density dependent, while it remains constant for a wide range of carrier densities in monolayer graphene. Our results and comparisons between the bilayer and monolayer exhibit a more comprehensive picture of hot carrier dynamics in graphene systems.

  12. Negative terahertz conductivity in disordered graphene bilayers with population inversion

    SciTech Connect

    Svintsov, D.; Otsuji, T.; Ryzhii, V.; Mitin, V.; Shur, M. S.

    2015-03-16

    The gapless energy band spectra make the structures based on graphene and graphene bilayer with the population inversion to be promising media for the interband terahertz (THz) lasing. However, a strong intraband absorption at THz frequencies still poses a challenge for efficient THz lasing. In this paper, we show that in the pumped graphene bilayer, the indirect interband radiative transitions accompanied by scattering of carriers by disorder can provide a substantial negative contribution to the THz conductivity (together with the direct interband transitions). In the graphene bilayer on high-κ substrates with point charged defects, these transitions substantially compensate the losses due to the intraband (Drude) absorption. We also demonstrate that the indirect interband contribution to the THz conductivity in a graphene bilayer with the extended defects (such as the charged impurity clusters) can surpass by several times the fundamental limit associated with the direct interband transitions, and the Drude conductivity as well. These predictions can affect the strategy of the graphene-based THz laser implementation.

  13. Observation of Low Energy Raman Modes in Twisted Bilayer Graphene

    NASA Astrophysics Data System (ADS)

    He, Rui; Chung, Ting-Fung; Delaney, Conor; Keiser, Courtney; Jauregui, Luis A.; Shand, Paul M.; Chancey, C. C.; Wang, Yanan; Bao, Jiming; Chen, Yong P.

    2013-08-01

    Two new Raman modes below 100 cm^-1 are observed in twisted bilayer graphene grown by chemical vapor deposition. The two modes are observed in a small range of twisting angle at which the intensity of the G Raman peak is strongly enhanced, indicating that these low energy modes and the G Raman mode share the same resonance enhancement mechanism, as a function of twisting angle. The 94 cm^-1 mode (measured with a 532 nm laser excitation) is assigned to the fundamental layer breathing vibration (ZO (prime) mode) mediated by the twisted bilayer graphene lattice, which lacks long-range translational symmetry. The dependence of this modes frequency and linewidth on the rotational angle can be explained by the double resonance Raman process which is different from the previously-identified Raman processes activated by twisted bilayer graphene superlattice. The dependence also reveals the strong impact of electronic-band overlaps of the two graphene layers. Another new mode at 52 cm^-1, not observed previously in the bilayer graphene system, is tentatively attributed to a torsion mode in which the bottom and top graphene layers rotate out-of-phase in the plane.

  14. Electronic properties of asymmetrically doped twisted graphene bilayers

    NASA Astrophysics Data System (ADS)

    Trambly de Laissardière, Guy; Namarvar, Omid Faizy; Mayou, Didier; Magaud, Laurence

    2016-06-01

    Rotated graphene bilayers form an exotic class of nanomaterials with fascinating electronic properties governed by the rotation angle θ . For large rotation angles, the electron eigenstates are restricted to one layer and the bilayer behaves like two decoupled graphene layers. At intermediate angles, Dirac cones are preserved but with a lower velocity and van Hove singularities are induced at energies where the two Dirac cones intersect. At very small angles, eigenstates become localized in peculiar moiré zones. We analyze here the effect of an asymmetric doping for a series of commensurate rotated bilayers on the basis of tight-binding calculations of their band dispersions, density of states, participation ratio, and diffusive properties. While a small doping level preserves the θ dependence of the rotated bilayer electronic structure, larger doping induces a further reduction of the band velocity in the same way as a further reduction of the rotation angle.

  15. Anomalous Spectral Features of a Neutral Bilayer Graphene

    PubMed Central

    Cheng, C.-M.; Xie, L.F.; Pachoud, A.; Moser, H.O.; Chen, W.; Wee, A.T.S.; Castro Neto, A.H.; Tsuei, K.-D.; Özyilmaz, B.

    2015-01-01

    Graphene and its bilayer are two-dimensional systems predicted to show exciting many-body effects near the neutrality point. The ideal tool to investigate spectrum reconstruction effects is angle-resolved photoemission spectroscopy (ARPES) as it probes directly the band structure with information about both energy and momentum. Here we reveal, by studying undoped exfoliated bilayer graphene with ARPES, two essential aspects of its many-body physics: the electron-phonon scattering rate has an anisotropic k-dependence and the type of electronic liquid is non-Fermi liquid. The latter behavior is evident from an observed electron-electron scattering rate that scales linearly with energy from 100 meV to 600 meV and that is associated with the proximity of bilayer graphene to a two-dimensional quantum critical point of competing orders. PMID:25985064

  16. Electro-absorption of silicene and bilayer graphene quantum dots

    NASA Astrophysics Data System (ADS)

    Abdelsalam, Hazem; Talaat, Mohamed H.; Lukyanchuk, Igor; Portnoi, M. E.; Saroka, V. A.

    2016-07-01

    We study numerically the optical properties of low-buckled silicene and AB-stacked bilayer graphene quantum dots subjected to an external electric field, which is normal to their surface. Within the tight-binding model, the optical absorption is calculated for quantum dots, of triangular and hexagonal shapes, with zigzag and armchair edge terminations. We show that in triangular silicene clusters with zigzag edges a rich and widely tunable infrared absorption peak structure originates from transitions involving zero energy states. The edge of absorption in silicene quantum dots undergoes red shift in the external electric field for triangular clusters, whereas blue shift takes place for hexagonal ones. In small clusters of bilayer graphene with zigzag edges the edge of absorption undergoes blue/red shift for triangular/hexagonal geometry. In armchair clusters of silicene blue shift of the absorption edge takes place for both cluster shapes, while red shift is inherent for both shapes of the bilayer graphene quantum dots.

  17. Anomalous spectral features of a neutral bilayer graphene.

    PubMed

    Cheng, C-M; Xie, L F; Pachoud, A; Moser, H O; Chen, W; Wee, A T S; Castro Neto, A H; Tsuei, K-D; Özyilmaz, B

    2015-01-01

    Graphene and its bilayer are two-dimensional systems predicted to show exciting many-body effects near the neutrality point. The ideal tool to investigate spectrum reconstruction effects is angle-resolved photoemission spectroscopy (ARPES) as it probes directly the band structure with information about both energy and momentum. Here we reveal, by studying undoped exfoliated bilayer graphene with ARPES, two essential aspects of its many-body physics: the electron-phonon scattering rate has an anisotropic k-dependence and the type of electronic liquid is non-Fermi liquid. The latter behavior is evident from an observed electron-electron scattering rate that scales linearly with energy from 100 meV to 600 meV and that is associated with the proximity of bilayer graphene to a two-dimensional quantum critical point of competing orders. PMID:25985064

  18. Nonlocal transport in dual-gated bilayer graphene

    NASA Astrophysics Data System (ADS)

    Shimazaki, Yuya; Yamamoto, Michihisa; Watanabe, Kenji; Taniguchi, Takashi; Tarucha, Seigo

    2014-03-01

    We report nonlocal transport measurement of biased bilayer graphene. Dual gated bilayer graphene Hall bars sandwiched between two h-BN insulating layers were prepared using the transfer technique with PMMA thin flims. We measured both local and non-local transport at temperatures between 1.5 K and 200 K. We found enhancement of the nonlocal resistance near the charge neutrality point when we increase the perpendicular electric field. Observed nonlocal resistance at 70K is much larger than what is expected as the Ohmic contribution from van der Pauw formula with measured local resistivity. This observation indicates additional contribution to the nonlocal transport in biased bilayer graphene. We present temperature and displacement field dependence of the nonlocal resistance and discuss its origin in terms of valley Hall effect and transport through disordered edge states.

  19. Linear magnetoresistance in mosaic-like bilayer graphene

    NASA Astrophysics Data System (ADS)

    Kisslinger, Ferdinand; Ott, Christian; Heide, Christian; Kampert, Erik; Butz, Benjamin; Spiecker, Erdmann; Shallcross, Sam; Weber, Heiko B.

    2015-08-01

    The magnetoresistance of conductors usually has a quadratic dependence on magnetic field, however, examples exist of non-saturating linear behaviour in diverse materials. Assigning a specific microscopic mechanism to this unusual phenomenon is obscured by the co-occurrence and interplay of doping, mobility fluctuations and a polycrystalline structure. Bilayer graphene has virtually no doping fluctuations, yet provides a built-in mosaic tiling due to the dense network of partial dislocations. We present magnetotransport measurements of epitaxial bilayer graphene that exhibits a strong and reproducible linear magnetoresistance that persists to B = 62 T at and above room temperature, decorated by quantum interference effects at low temperatures. Partial dislocations thus have a profound impact on the transport properties in bilayer graphene, a system that is frequently assumed to be dislocation-free. It further provides a clear and tractable model system for studying the unusual properties of mosaic conductors.

  20. Anomalous conductivity noise in gapped bilayer graphene heterostructure

    NASA Astrophysics Data System (ADS)

    Aamir, Mohammed Ali; Karnatak, Paritosh; Sai, T. Phanindra; Ghosh, Arindam

    Bilayer graphene has unique electronic properties - it has a tunable band gap and also, valley symmetry and pseudospin degree of freedom like its single layer counterpart. In this work, we present a study of conductance fluctuations in dual gated bilayer graphene heterostructures by varying the Fermi energy and the band gap independently. At a fixed band gap, we find that the conductance fluctuations obtained by Fermi energy ensemble sampling increase rapidly as the Fermi energy is tuned to charge neutrality point (CNP) whereas the time-dependent conductance fluctuations diminish rapidly. This discrepancy is completely absent at higher number densities, where the transport is expected to be through the 2D bulk of the bilayer system. This observation indicates that near the CNP, electrical transport is highly sensitive to Fermi energy, but becomes progressively immune to time-varying disorder. A possible explanation may involve transport via edge states which becomes the dominant conduction mechanism when the bilayer graphene is gapped and Fermi energy is situated close to the CNP, thereby causing a dimensional crossover from 2D to 1D transport. Our experiment outlines a possible experimental protocol to probe intrinsic topological states in gapped bilayer graphene.

  1. Electronic band structure of magnetic bilayer graphene superlattices

    SciTech Connect

    Pham, C. Huy; Nguyen, T. Thuong

    2014-09-28

    Electronic band structure of the bilayer graphene superlattices with δ-function magnetic barriers and zero average magnetic flux is studied within the four-band continuum model, using the transfer matrix method. The periodic magnetic potential effects on the zero-energy touching point between the lowest conduction and the highest valence minibands of pristine bilayer graphene are exactly analyzed. Magnetic potential is shown also to generate the finite-energy touching points between higher minibands at the edges of Brillouin zone. The positions of these points and the related dispersions are determined in the case of symmetric potentials.

  2. Wrinkled bilayer graphene with wafer scale mechanical strain

    NASA Astrophysics Data System (ADS)

    Mikael, Solomon; Seo, Jung-Hun; Javadi, Alireza; Gong, Shaoqin; Ma, Zhenqiang

    2016-05-01

    Wafer-scale strained bilayer graphene is demonstrated by employing a silicon nitride (Si3N4) stressor layer. Different magnitudes of compressive stress up to 840 MPa were engineered by adjusting the Si3N4 deposition recipes, and different strain conditions were analyzed using Raman spectroscopy. The strained graphene displayed significant G peak shifts and G peak splitting with 16.2 cm-1 and 23.0 cm-1 of the G band and two-dimensional band shift, which corresponds to 0.26% of strain. Raman mapping of large regions of the graphene films found that the largest shifts/splitting occurred near the bilayer regions of the graphene films. The significance of our approach lies in the fact that it can be performed in a conventional microfabrication process, i.e., the plasma enhanced chemical vapor deposition system, and thus easily implemented for large scale production.

  3. Nonlinear optical properties of nitrogen-doped bilayer graphene

    NASA Astrophysics Data System (ADS)

    Anand, Benoy; Podila, Ramakrishna; Rao, Apparao M.; Philip, Reji; Sai, S. Siva Sankara

    2013-06-01

    The electronic properties of graphene can be controlled by substitutional doping to obtain p-type or n-type characteristics. To this end, bilayer graphene films are synthesized using CVD method and substitutionally doped with Nitrogen (N). Previously, XPS measurements done in tandem with Raman spectroscopy revealed that the rich chemistry between carbon and nitrogen can result in pyridinic, pyrrolic, or graphitic configurations. The nonlinear optical properties (NLO) of both pristine and N-doped graphene samples are studied in both nanosecond and femtosecond excitation regimes using open aperture Z-scan method. Similar to the previous observations with Raman spectroscopy, we see that the NLO properties are more sensitive to the local bonding environments which determine the defect density in the graphene lattice, rather than just the dopant percentage. Our results give more insights into the effect of defects on the NLO properties of doped graphene which help in tailor making graphene samples for applications like modelocking and optical switching.

  4. Soliton-dependent plasmon reflection at bilayer graphene domain walls

    NASA Astrophysics Data System (ADS)

    Jiang, Lili; Shi, Zhiwen; Zeng, Bo; Wang, Sheng; Kang, Ji-Hun; Joshi, Trinity; Jin, Chenhao; Ju, Long; Kim, Jonghwan; Lyu, Tairu; Shen, Yuen-Ron; Crommie, Michael; Gao, Hong-Jun; Wang, Feng

    2016-08-01

    Layer-stacking domain walls in bilayer graphene are emerging as a fascinating one-dimensional system that features stacking solitons structurally and quantum valley Hall boundary states electronically. The interactions between electrons in the 2D graphene domains and the one-dimensional domain-wall solitons can lead to further new quantum phenomena. Domain-wall solitons of varied local structures exist along different crystallographic orientations, which can exhibit distinct electrical, mechanical and optical properties. Here we report soliton-dependent 2D graphene plasmon reflection at different 1D domain-wall solitons in bilayer graphene using near-field infrared nanoscopy. We observe various domain-wall structures in mechanically exfoliated graphene bilayers, including network-forming triangular lattices, individual straight or bent lines, and even closed circles. The near-field infrared contrast of domain-wall solitons arises from plasmon reflection at domain walls, and exhibits markedly different behaviours at the tensile- and shear-type domain-wall solitons. In addition, the plasmon reflection at domain walls exhibits a peculiar dependence on electrostatic gating. Our study demonstrates the unusual and tunable coupling between 2D graphene plasmons and domain-wall solitons.

  5. High Yield Chemical Vapor Deposition Growth of High Quality Large-Area AB Stacked Bilayer Graphene

    PubMed Central

    Liu, Lixin; Zhou, Hailong; Cheng, Rui; Yu, Woo Jong; Liu, Yuan; Chen, Yu; Shaw, Jonathan; Zhong, Xing; Huang, Yu; Duan, Xiangfeng

    2012-01-01

    Bernal stacked (AB stacked) bilayer graphene is of significant interest for functional electronic and photonic devices due to the feasibility to continuously tune its band gap with a vertical electrical field. Mechanical exfoliation can be used to produce AB stacked bilayer graphene flakes but typically with the sizes limited to a few micrometers. Chemical vapor deposition (CVD) has been recently explored for the synthesis of bilayer graphene but usually with limited coverage and a mixture of AB and randomly stacked structures. Herein we report a rational approach to produce large-area high quality AB stacked bilayer graphene. We show that the self-limiting effect of graphene growth on Cu foil can be broken by using a high H2/CH4 ratio in a low pressure CVD process to enable the continued growth of bilayer graphene. A high temperature and low pressure nucleation step is found to be critical for the formation of bilayer graphene nuclei with high AB stacking ratio. A rational design of a two-step CVD process is developed for the growth of bilayer graphene with high AB stacking ratio (up to 90 %) and high coverage (up to 99 %). The electrical transport studies demonstrated that devices made of the as-grown bilayer graphene exhibit typical characteristics of AB stacked bilayer graphene with the highest carrier mobility exceeding 4,000 cm2/V·s at room temperature, comparable to that of the exfoliated bilayer graphene. PMID:22906199

  6. Strain solitons and topological defects in bilayer graphene.

    PubMed

    Alden, Jonathan S; Tsen, Adam W; Huang, Pinshane Y; Hovden, Robert; Brown, Lola; Park, Jiwoong; Muller, David A; McEuen, Paul L

    2013-07-01

    Bilayer graphene has been a subject of intense study in recent years. The interlayer registry between the layers can have dramatic effects on the electronic properties: for example, in the presence of a perpendicular electric field, a band gap appears in the electronic spectrum of so-called Bernal-stacked graphene [Oostinga JB, et al. (2007) Nature Materials 7:151-157]. This band gap is intimately tied to a structural spontaneous symmetry breaking in bilayer graphene, where one of the graphene layers shifts by an atomic spacing with respect to the other. This shift can happen in multiple directions, resulting in multiple stacking domains with soliton-like structural boundaries between them. Theorists have recently proposed that novel electronic states exist at these boundaries [Vaezi A, et al. (2013) arXiv:1301.1690; Zhang F, et al. (2013) arXiv:1301.4205], but very little is known about their structural properties. Here we use electron microscopy to measure with nanoscale and atomic resolution the widths, motion, and topological structure of soliton boundaries and related topological defects in bilayer graphene. We find that each soliton consists of an atomic-scale registry shift between the two graphene layers occurring over 6-11 nm. We infer the minimal energy barrier to interlayer translation and observe soliton motion during in situ heating above 1,000 °C. The abundance of these structures across a variety of samples, as well as their unusual properties, suggests that they will have substantial effects on the electronic and mechanical properties of bilayer graphene. PMID:23798395

  7. Strain solitons and topological defects in bilayer graphene

    PubMed Central

    Alden, Jonathan S.; Tsen, Adam W.; Huang, Pinshane Y.; Hovden, Robert; Brown, Lola; Park, Jiwoong; Muller, David A.; McEuen, Paul L.

    2013-01-01

    Bilayer graphene has been a subject of intense study in recent years. The interlayer registry between the layers can have dramatic effects on the electronic properties: for example, in the presence of a perpendicular electric field, a band gap appears in the electronic spectrum of so-called Bernal-stacked graphene [Oostinga JB, et al. (2007) Nature Materials 7:151–157]. This band gap is intimately tied to a structural spontaneous symmetry breaking in bilayer graphene, where one of the graphene layers shifts by an atomic spacing with respect to the other. This shift can happen in multiple directions, resulting in multiple stacking domains with soliton-like structural boundaries between them. Theorists have recently proposed that novel electronic states exist at these boundaries [Vaezi A, et al. (2013) arXiv:1301.1690; Zhang F, et al. (2013) arXiv:1301.4205], but very little is known about their structural properties. Here we use electron microscopy to measure with nanoscale and atomic resolution the widths, motion, and topological structure of soliton boundaries and related topological defects in bilayer graphene. We find that each soliton consists of an atomic-scale registry shift between the two graphene layers occurring over 6–11 nm. We infer the minimal energy barrier to interlayer translation and observe soliton motion during in situ heating above 1,000 °C. The abundance of these structures across a variety of samples, as well as their unusual properties, suggests that they will have substantial effects on the electronic and mechanical properties of bilayer graphene. PMID:23798395

  8. Addressing Raman features of individual layers in isotopically labeled Bernal stacked bilayer graphene

    NASA Astrophysics Data System (ADS)

    Costa, Sara D.; Weis, Johan Ek; Frank, Otakar; Fridrichová, Michaela; Kalbac, Martin

    2016-06-01

    In this report important Raman modes for the evaluation of strain in graphene (the 2D and 2D‧) are analyzed. The isotope labeling is used to disentangle contribution of individual graphene layers of graphene bilayer to the studied Raman modes. It is shown that for Bernal-stacked bilayers, the 2D and the 2D‧ Raman modes have three distinct components that can be assigned to processes originating solely from the top graphene layer, bottom graphene layer, and from a combination of processes originating both from the top and bottom layers. The reported results thus enable addressing the properties of individual graphene layers in graphene bilayer by Raman spectroscopy.

  9. Dielectric screening and plasmon resonances in bilayer graphene

    NASA Astrophysics Data System (ADS)

    Pisarra, M.; Sindona, A.; Gravina, M.; Silkin, V. M.; Pitarke, J. M.

    2016-01-01

    The plasmon structure of intrinsic and extrinsic bilayer graphene is investigated in the framework of ab initio time-dependent density-functional theory (TDDFT) at the level of the random-phase approximation (RPA). A two-step scheme is adopted, where the electronic ground state of a periodically repeated slab of bilayer graphene is first determined with full inclusion of the anisotropic band structure and the interlayer interaction; a Dyson-like equation is then solved self-consistently in order to calculate the so-called density-response function of the many-electron system. A two-dimensional correction is subsequently applied in order to eliminate the artificial interaction between the replicas. The energy range below ˜30 eV is explored, focusing on the spectrum of single-particle excitations and plasmon resonances induced by external electrons or photons. The high-energy loss features of the π and σ +π plasmons, particularly their anisotropic dispersions, are predicted and discussed in relation with previous calculations and experiments performed on monolayer and bilayer graphene. At the low-energy end, the energy-loss function is found to be (i) very sensitive to the injected charge carrier density in doped bilayer graphene and (ii) highly anisotropic. Furthermore, various plasmon modes are predicted to exist and are analyzed with reference to the design of novel nanodevices.

  10. Electronic transport in B-N substituted bilayer graphene nanojunctions

    NASA Astrophysics Data System (ADS)

    Giofré, Daniele; Ceresoli, Davide; Fratesi, Guido; Trioni, Mario I.

    2016-05-01

    We investigated a suspended bilayer graphene where the bottom/top layer is doped by boron/nitrogen substitutional atoms. By using density functional theory calculations, we found that at high dopant concentration (one B-N pair every 32 C atoms), the electronic structure of the bilayer does not depend on the B-N distance but on the relative occupation of the bilayer graphene sublattices by B and N. The presence of the dopants and the consequent charge transfer establish a built-in electric field between the layers, giving rise to an energy gap. We further investigated the electronic transport properties and found that intralayer current is weakly influenced by the presence of these dopants while the interlayer one is enhanced for biases, allowing an easy tunneling between layers. This effect leads to current rectification in asymmetric junctions.

  11. Manipulating interface states in monolayer–bilayer graphene planar junctions

    NASA Astrophysics Data System (ADS)

    Zhao, Fang; Xu, Lei; Zhang, Jun

    2016-05-01

    We report on transport properties of monolayer–bilayer graphene planar junctions in a magnetic field. Due to its unique geometry, the edge and interface states can be independently manipulated by either interlayer potential or Zeeman field, and the conductance exhibits interesting quantized behaviors. In the hybrid graphene junction, the quantum Hall (QH) conductance is no longer antisymmetric with respect to the charge neutrality point. When the Zeeman field is considered, a quantum spin Hall (QSH) phase is found in the monolayer region while the weak-QSH phase stays in the bilayer region. In the presence of both interlayer potential and Zeeman field, the bilayer region hosts a QSH phase, whereas the monolayer region is still in a QH phase, leading to a spin-polarized current in the interface. In particular, the QSH phase remains robust against the disorder.

  12. Bilayer graphene: physics and application outlook in photonics

    NASA Astrophysics Data System (ADS)

    Yan, Hugen

    2015-05-01

    Layered materials, such as graphene, transition metal dichacogenides and black phosphorus have attracted lots of attention recently. They are emerging novel materials in electronics and photonics, with tremendous potential in revolutionizing the traditional electronics and photonics industry. Marrying layered material to the nanophotonics is being proved fruitful. With the recent emphasis and development of metasurfaces in nanophotonics, atomically thin materials can find their unique position and strength in this field. In this article, I will focus on one specific two dimensional material: bilayer graphene. Basic physics will be reviewed, such as band-gap opening, electron-phonon interaction, phonon-plasmon interaction and Fano resonances in the optical response. Moreover, I will review the application of bilayer graphene as a sensitive and fast photodetector. An outlook will be given in the final part of the paper.

  13. Asymmetric bilayer graphene nanoribbon MOSFETs for analog and digital electronics

    NASA Astrophysics Data System (ADS)

    Dinarvand, A.; Ahmadi, V.; Darvish, Gh.

    2016-05-01

    In this paper, a new structure was proposed for bilayer graphene nanoribbon field-effect transistor (BGNFET) mainly to enhance the electrical characteristics in analog and digital applications. The proposed device uses two metallic gates on the top and bottom of a bilayer graphene nanoribbon, which is surrounded by SiO2 and connected to heavily doped source/drain contacts. Electrical properties of the proposed device were explored using fully self-consistent solution of Poisson and Schrödinger equations based on the nonequilibrium Green's function (NEGF) formalism. Significant improvements in the electrical behavior was seen in the simulation results for gates asymmetrically biased. The comparison with graphene nanoribbon FET showed that the proposed structure benefited from higher intrinsic voltage gain and cut-off frequency and improved switching characteristics such as delay and Ion/Ioff ratio.

  14. Spatially Indirect Exciton Condensates in Double Bilayer Graphene

    NASA Astrophysics Data System (ADS)

    Su, Jung-Jung; MacDonald, Allan H.

    Many-body interaction effects have a strong influence on the low-energy electronic properties of graphene bilayers because of the nearly quadratic dispersion at the K/K' band-crossing points. In the single graphene bilayer systems, the ground state has an energy gap thought to be a consequence of spin-density wave order and other competing ordered states are believed to be nearby in energy. In systems with two closely spacing bilayer, spatially indirect exciton states are expected in neutral systems with inter-bilayer charge transfer. This transfer can be achieved by applying either a vertical electrical displacement fields or an interbilayer potential bias. Here we report that the different combinations of displacement field and potential bias can give rise to different types of indirect exciton condensate states that are distinguished by the two-dimensional momentum dependence of the spontaneous inter-bilayer coherence. In general a displacement field prefers an excitonic condensate in which the phase coherence between the inner two layers of the four layer system, while the potential bias prefers momentum-independent coherence between remote layers. The complete phase diagram reported exhibits excitonic coherence states mentioned above, and more interestingly, their mixtures.

  15. Thermoelectric Power in Bilayer Graphene Device with Ionic Liquid Gating

    NASA Astrophysics Data System (ADS)

    Chien, Yung-Yu; Yuan, Hongtao; Wang, Chang-Ran; Lee, Wei-Li

    2016-02-01

    The quest for materials showing large thermoelectric power has long been one of the important subjects in material science and technology. Such materials have great potential for thermoelectric cooling and also high figure of merit ZT thermoelectric applications. We have fabricated bilayer graphene devices with ionic-liquid gating in order to tune its band gap via application of a perpendicular electric field on a bilayer graphene. By keeping the Fermi level at charge neutral point during the cool-down, we found that the charge puddles effect can be greatly reduced and thus largely improve the transport properties at low T in graphene-based devices using ionic liquid gating. At (Vig, Vbg) = (-1 V, +23 V), a band gap of about 36.6 ± 3 meV forms, and a nearly 40% enhancement of thermoelectric power at T = 120 K is clearly observed. Our works demonstrate the feasibility of band gap tuning in a bilayer graphene using ionic liquid gating. We also remark on the significant influence of the charge puddles effect in ionic-liquid-based devices.

  16. Thermoelectric Power in Bilayer Graphene Device with Ionic Liquid Gating

    PubMed Central

    Chien, Yung-Yu; Yuan, Hongtao; Wang, Chang-Ran; Lee, Wei-Li

    2016-01-01

    The quest for materials showing large thermoelectric power has long been one of the important subjects in material science and technology. Such materials have great potential for thermoelectric cooling and also high figure of merit ZT thermoelectric applications. We have fabricated bilayer graphene devices with ionic-liquid gating in order to tune its band gap via application of a perpendicular electric field on a bilayer graphene. By keeping the Fermi level at charge neutral point during the cool-down, we found that the charge puddles effect can be greatly reduced and thus largely improve the transport properties at low T in graphene-based devices using ionic liquid gating. At (Vig, Vbg) = (−1 V, +23 V), a band gap of about 36.6 ± 3 meV forms, and a nearly 40% enhancement of thermoelectric power at T = 120 K is clearly observed. Our works demonstrate the feasibility of band gap tuning in a bilayer graphene using ionic liquid gating. We also remark on the significant influence of the charge puddles effect in ionic-liquid-based devices. PMID:26852799

  17. Towards Tunable Band Gap and Tunable Dirac Point in Bilayer Graphene with Molecular Doping

    PubMed Central

    Yu, Woo Jong; Liao, Lei; Chae, Sang Hoon; Lee, Young Hee; Duan, Xiangfeng

    2011-01-01

    The bilayer graphene has attracted considerable attention for potential applications in future electronics and optoelectronics because of the feasibility to tune its band gap with a vertical displacement field to break the inversion symmetry. Surface chemical doping in bilayer graphene can induce an additional offset voltage to fundamentally affect the vertical displacement field and band-gap opening in bilayer graphene. In this study, we investigate the effect of chemical molecular doping on band-gap opening in bilayer graphene devices with single or dual gate modulation. Chemical doping with benzyl viologen molecules modulates the displacement field to allow the opening of a transport band gap and the increase of the on/off ratio in the bilayer graphene transistors. Additionally, Fermi energy level in the opened gap can be rationally controlled by the amount of molecular doping to obtain bilayer graphene transistors with tunable Dirac points, which can be readily configured into functional devices such as complementary inverters. PMID:21985035

  18. van der Waals bilayer energetics: Generalized stacking-fault energy of graphene, boron nitride, and graphene/boron nitride bilayers

    NASA Astrophysics Data System (ADS)

    Zhou, Songsong; Han, Jian; Dai, Shuyang; Sun, Jianwei; Srolovitz, David J.

    2015-10-01

    The structure, thermodynamics, and band gaps in graphene/graphene, boron nitride/boron nitride, and graphene/boron nitride bilayers are determined using several different corrections to first-principles approaches to account for the dispersion interactions. While the density functional dispersion correction, van der Waals density functional, meta-generalized gradient approximation, and adiabatic fluctuation-dissipation theorem methods (ACFDT-RPA) all lead to qualitatively similar predictions, the best accuracy is obtained through the application of the computationally expensive ACFDT-RPA method. We present an accurate ACFDT-RPA-based method to determine bilayer structure, generalized stacking-fault energy (GSFE), and band gaps as a function of the relative translation states of the two layers. The GSFE data clearly identify all of the stable and metastable bilayer translations as well as the barriers between them. This is key for predicting the sliding, formation, and adhesion energies for homo- and hetero-bilayers, as well as for the determination of defects in such multilayer van der Waals systems. These, in turn, provide an accurate approach for determining and manipulating the spatial variation of electronic structure.

  19. Bandgap opening in bilayer graphene via molecular doping

    NASA Astrophysics Data System (ADS)

    Carey, David; Samuels, Alexander

    2013-03-01

    We report the emergence of an electronic bandgap in bilayer graphene through the interaction with physisorbed molecules. The bandgap is found to scale linearly with induced carrier density though a slight asymmetry is found between n-type dopants where the bandgap varies as 47 meV/1013 cm-2 and p-type dopants where the bandgap varies as 38 meV/1013 cm-2. The n-type dopant molecules include tetrathiafulvalene (TTF), cobaltocene and decamethylcobaltocene (DMC) and p-type dopant molecules include NO2, 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) and 3,6-difluoro-2,5,7,7,8,8-hexacyano-quinodimethane (F2-HCNQ). Ammonia is found to be weak amphoteric dopant on bilayer graphene, as it is on single layer graphene, where the charge transfer depends on the orientation of the N atom relative to the upper graphene layer. The bandgap opening is explained in terms of the asymmetric charge distributions on the upper graphene layer which is in contact with the molecules. The high binding energy found upon adsorption of some of these molecules results in an attractive way to a permanent bandgap and when combined with a variable external electric field can either close the gap or widen it still further. Support from the EPSRC is gratefully acknowledged

  20. Band Structure Asymmetry of Bilayer Graphene Revealed by Infrared Spectroscopy

    SciTech Connect

    Li, Z.Q.; Henriksen, E.A.; Jiang, Z.; Hao, Zhao; Martin, Michael C.; Kim, P.; Stormer, H.L.; Basov, Dimitri N.

    2008-12-10

    We report on infrared spectroscopy of bilayer graphene integrated in gated structures. We observe a significant asymmetry in the optical conductivity upon electrostatic doping of electrons and holes. We show that this finding arises from a marked asymmetry between the valence and conduction bands, which is mainly due to the inequivalence of the two sublattices within the graphene layer and the next-nearest-neighbor interlayer coupling. From the conductivity data, the energy difference of the two sublattices and the interlayer coupling energy are directly determined.

  1. From helical state to chiral state in ferromagnetic bilayer graphene

    NASA Astrophysics Data System (ADS)

    Xu, Lei; Zhou, Yuan; Zhang, Jun

    2015-06-01

    We explore topological phases in biased ferromagnetic bilayer graphene, formed by bilayer graphene subjected to an external ferromagnetic exchange field, under a magnetic field. The most likely way to obtain a variety of distinct broken symmetry topological phases is proposed by means of ferromagnetic exchange field. Both spin-filtered quantum Hall and quantum spin Hall (QSH) phases are found. Edge modes in this QSH phase carry charge, spin and valley currents. When both time reversal and inversion symmetries are broken, the QSH phase remains robust against weak disorder. Moreover, topological phase transition from helical phase to chiral phase can be driven by simply tuning bias voltage or Fermi energy. A few possible experimental realizations are also discussed.

  2. The induced nontrivial Z 2 topological phase in graphene sandwiched by pnictogen bilayers

    NASA Astrophysics Data System (ADS)

    Shu, Cheng; Qu, Jinfeng; Peng, Xiangyang; Yang, Hong; Liu, Wenliang; Wei, Xiaolin; Zhang, Kaiwang; Zhong, Jianxin

    2016-06-01

    By performing first-principles calculations, we find that graphene with nearly zero spin orbit coupling can be turned into a topological insulator after being sandwiched between pnictogen bilayers. It is found that a dipole field is induced between graphene and pnictogen bilayers, which will significantly pull down the Dirac point of graphene. Depending on the initial position of the Dirac point of graphene with respect to the energy gap of the pnictogen bilayers, Bi/graphene/Bi is found to be a metallic system while Sb/graphene/Sb a topological insulator. In Sb/graphene/Sb, a sizable gap is opened at the Dirac point of graphene. The strong spin–orbit coupling in Sb bilayers leads to a band inversion in the gapped Dirac cones of graphene via the proximity effect and the calculated Z 2 topological index further confirms that a nontrivial topological phase is induced in graphene. By applying longitudinal or lateral strains to Sb/graphene/Sb, topological phase transition occurs based on the change of the thickness of the Sb bilayer instead of the change of the separation between graphene and Sb bilayers.

  3. The induced nontrivial Z 2 topological phase in graphene sandwiched by pnictogen bilayers.

    PubMed

    Shu, Cheng; Qu, Jinfeng; Peng, Xiangyang; Yang, Hong; Liu, Wenliang; Wei, Xiaolin; Zhang, Kaiwang; Zhong, Jianxin

    2016-06-15

    By performing first-principles calculations, we find that graphene with nearly zero spin orbit coupling can be turned into a topological insulator after being sandwiched between pnictogen bilayers. It is found that a dipole field is induced between graphene and pnictogen bilayers, which will significantly pull down the Dirac point of graphene. Depending on the initial position of the Dirac point of graphene with respect to the energy gap of the pnictogen bilayers, Bi/graphene/Bi is found to be a metallic system while Sb/graphene/Sb a topological insulator. In Sb/graphene/Sb, a sizable gap is opened at the Dirac point of graphene. The strong spin-orbit coupling in Sb bilayers leads to a band inversion in the gapped Dirac cones of graphene via the proximity effect and the calculated Z 2 topological index further confirms that a nontrivial topological phase is induced in graphene. By applying longitudinal or lateral strains to Sb/graphene/Sb, topological phase transition occurs based on the change of the thickness of the Sb bilayer instead of the change of the separation between graphene and Sb bilayers. PMID:27160385

  4. Dual-gated bilayer graphene hot-electron bolometer.

    PubMed

    Yan, Jun; Kim, M-H; Elle, J A; Sushkov, A B; Jenkins, G S; Milchberg, H M; Fuhrer, M S; Drew, H D

    2012-07-01

    Graphene is an attractive material for use in optical detectors because it absorbs light from mid-infrared to ultraviolet wavelengths with nearly equal strength. Graphene is particularly well suited for bolometers-devices that detect temperature-induced changes in electrical conductivity caused by the absorption of light-because its small electron heat capacity and weak electron-phonon coupling lead to large light-induced changes in electron temperature. Here, we demonstrate a hot-electron bolometer made of bilayer graphene that is dual-gated to create a tunable bandgap and electron-temperature-dependent conductivity. The bolometer exhibits a noise-equivalent power (33 fW Hz(-1/2) at 5 K) that is several times lower, and intrinsic speed (>1 GHz at 10 K) three to five orders of magnitude higher than commercial silicon bolometers and superconducting transition-edge sensors at similar temperatures. PMID:22659611

  5. Direct transfer and Raman characterization of twisted graphene bilayer

    NASA Astrophysics Data System (ADS)

    Othmen, R.; Arezki, H.; Ajlani, H.; Cavanna, A.; Boutchich, M.; Oueslati, M.; Madouri, A.

    2015-03-01

    Twisted bilayer graphene (tBLG) is constituted of a two-graphene layer with a mismatch angle θ between the two hexagonal structures. It has recently attracted much attention—thanks to its diverse electronic and optical properties. Here, we study the tBLG fabricated by the direct transfer of graphene monolayer prepared by chemical vapor deposition (CVD) onto another CVD graphene layer remaining attached to the copper foil. We show that high quality and homogeneous tBLG can be obtained by the direct transfer which prevents interface contamination. In this situation, the top graphene layer plays a supporting mechanical role to the bottom graphene layer as confirmed by optical microscopy, scanning electron microscopy, and Raman spectroscopy measurements. The effect of annealing tBLG was also investigated using micro-Raman spectroscopy. The Raman spectra exhibit a splitting of the G peak as well as a change in the 2D band shape indicating a possible decoupling of the two monolayers. We attribute these changes to the different interactions of the top and bottom layers with the substrate.

  6. Direct transfer and Raman characterization of twisted graphene bilayer

    SciTech Connect

    Othmen, R.; Ajlani, H.; Oueslati, M.; Cavanna, A.; Madouri, A.

    2015-03-09

    Twisted bilayer graphene (tBLG) is constituted of a two-graphene layer with a mismatch angle θ between the two hexagonal structures. It has recently attracted much attention—thanks to its diverse electronic and optical properties. Here, we study the tBLG fabricated by the direct transfer of graphene monolayer prepared by chemical vapor deposition (CVD) onto another CVD graphene layer remaining attached to the copper foil. We show that high quality and homogeneous tBLG can be obtained by the direct transfer which prevents interface contamination. In this situation, the top graphene layer plays a supporting mechanical role to the bottom graphene layer as confirmed by optical microscopy, scanning electron microscopy, and Raman spectroscopy measurements. The effect of annealing tBLG was also investigated using micro-Raman spectroscopy. The Raman spectra exhibit a splitting of the G peak as well as a change in the 2D band shape indicating a possible decoupling of the two monolayers. We attribute these changes to the different interactions of the top and bottom layers with the substrate.

  7. Study on temperature-dependent carrier transport for bilayer graphene

    NASA Astrophysics Data System (ADS)

    Liu, Yali; Li, Weilong; Qi, Mei; Li, Xiaojun; Zhou, Yixuan; Ren, Zhaoyu

    2015-05-01

    In order to investigate the temperature-dependent carrier transport property of the bilayer graphene, graphene films were synthesized on Cu foils by a home-built chemical vapor deposition (CVD) with C2H2. Samples regularity, transmittance (T) and layer number were analyzed by transmission electron microscope (TEM) images, transmittance spectra and Raman spectra. Van Der Pauw method was used for resistivity measurements and Hall measurements at different temperatures. The results indicated that the sheet resistance (Rs), carrier density (n), and mobility (μ) were 1096.20 Ω/sq, 0.75×1012 cm-2, and 7579.66 cm2 V-1 s-1 at room temperature, respectively. When the temperature increased from 0 °C to 240 °C, carrier density (n) increased from 0.66×1012 cm-2 to 1.55×1012 cm-2, sheet resistance (Rs) decreased from 1215.55 Ω/sq to 560.77 Ω/sq, and mobility (μ) oscillated around a constant value 7773.99 cm2 V-1 s-1. The decrease of the sheet resistance (Rs) indicated that the conductive capability of the bilayer graphene film increased with the temperature. The significant cause of the increase of carrier density (n) was the thermal activation of carriers from defects and unconscious doping states. Because the main influence on the carrier mobility (μ) was the lattice defect scattering and a small amount of impurity scattering, the carrier mobility (μ) was temperature-independent for the bilayer graphene.

  8. Optical rectification at visible frequency in biased bilayer graphene

    NASA Astrophysics Data System (ADS)

    Hipolito, F.; Pereira, Vitor M.

    2015-03-01

    The second order response of the electrical current to an electromagnetic field is analyzed within the framework of non-equilibrium many-body perturbation theory for the case of a two-dimensional electronic system such as graphene and its bilayer. The absence of inversion symmetry in a biased graphene bilayer allows a finite DC response in second order to an AC electromagnetic wave. The induced DC current is evaluated for biased bilayer at finite temperature, and its tunability is analyzed as a function of electron density, which can be experimentally varied by means of a global gate voltage applied to the sample. Both intrinsic and photon drag microscopic processes are considered, as they contribute on similar footing to the photocurrent in general. However, the dependencies of these two contributions on the polarization state of the incident light are different, which allows the manipulation of the relative contribution of intrinsic versus photon drag contributions by tuning the experimental parameters. For example, the photocurrent emerging from circularly polarized light stems entirely from photon drag, as the circular photogalvanic effect is forbidden by the C3 rotation symmetry of the honeycomb lattice.

  9. Graphene homojunction: closed-edge bilayer graphene by pseudospin interaction

    NASA Astrophysics Data System (ADS)

    Yan, Jiaxu; Li, Chao; Zhan, Da; Liu, Lei; Shen, Dezhen; Kuo, Jer-Lai; Chen, Shoushun; Shen, Zexiang

    2016-04-01

    Depending on the sublattices they are propagated in, low-energy electrons or holes are labeled with pseudospin. By engineering pseudospin interactions, we propose that two critical features of a junction, i.e., band gap opening and spatial charge separation, can be realized in graphene layers with proper stacking. We also demonstrate theoretically that such a graphene diode may play a role in future pseudospin electronics such as for harvesting solar energy.

  10. Graphene homojunction: closed-edge bilayer graphene by pseudospin interaction.

    PubMed

    Yan, Jiaxu; Li, Chao; Zhan, Da; Liu, Lei; Shen, Dezhen; Kuo, Jer-Lai; Chen, Shoushun; Shen, Zexiang

    2016-04-28

    Depending on the sublattices they are propagated in, low-energy electrons or holes are labeled with pseudospin. By engineering pseudospin interactions, we propose that two critical features of a junction, i.e., band gap opening and spatial charge separation, can be realized in graphene layers with proper stacking. We also demonstrate theoretically that such a graphene diode may play a role in future pseudospin electronics such as for harvesting solar energy. PMID:26809883

  11. Specific heat of twisted bilayer graphene: Engineering phonons by atomic plane rotations

    SciTech Connect

    Nika, Denis L.; Cocemasov, Alexandr I.; Balandin, Alexander A.

    2014-07-21

    We have studied the phonon specific heat in single-layer, bilayer, and twisted bilayer graphene. The calculations were performed using the Born-von Karman model of lattice dynamics for intralayer atomic interactions and spherically symmetric interatomic potential for interlayer interactions. We found that at temperature T < 15 K, specific heat varies with temperature as T{sup n}, where n = 1 for graphene, n = 1.6 for bilayer graphene, and n = 1.3 for the twisted bilayer graphene. The phonon specific heat reveals an intriguing dependence on the twist angle in bilayer graphene, which is particularly pronounced at low temperature. The results suggest a possibility of phonon engineering of thermal properties of layered materials by twisting the atomic planes.

  12. Graphene bilayer structures with superfluid magnetoexcitons

    PubMed Central

    2012-01-01

    In this article, we study superfluid behavior of a gas of spatially indirect magnetoexcitons with reference to a system of two graphene layers embedded in a multilayer dielectric structure. The system is considered as an alternative of a double quantum well in a GaAs heterostructure. We determine a range of parameters (interlayer distance, dielectric constant, magnetic field, and gate voltage) where magnetoexciton superfluidity can be achieved. Temperature of superfluid transition is computed. A reduction of critical parameters caused by impurities is evaluated and critical impurity concentration is determined. PMID:22353230

  13. Graphene quantum dots: localized states, edges and bilayer systems

    NASA Astrophysics Data System (ADS)

    Ensslin, Klaus

    2014-03-01

    Graphene quantum dots show Coulomb blockade, excited states and their orbital and spin properties have been investigated in high magnetic fields. Most quantum dots fabricated to date are fabricated with electron beam lithography and dry etching which generally leads to uncontrolled and probably rough edges. We demonstrate that devices with reduced bulk disorder fabricated on BN substrates display similar localized states as those fabricated on the more standard SiO2 substrates. For a highly symmetric quantum dot with short tunnel barriers the experimentally detected transport features can be explained by three localized states, 1 in the dot and 2 in the constrictions. A way to overcome edge roughness and the localized states related to this are bilayer devices where a band gap can be induced by suitable top and back gate voltages. By placing bilayer graphene between two BN layers high electronic quality can be achieved as documented by the observation of broken symmetry states in the quantum Hall regime. We discuss how this method can be exploited to achieve smoother and better tunable graphene quantum devices. This work was done in collaboration with D. Bischoff, P. Simonet, A. Varlet, Y. Tian, and T. Ihn.

  14. van Hove Singularity Enhanced Photochemical Reactivity of Twisted Bilayer Graphene.

    PubMed

    Liao, Lei; Wang, Huan; Peng, Han; Yin, Jianbo; Koh, Ai Leen; Chen, Yulin; Xie, Qin; Peng, Hailin; Liu, Zhongfan

    2015-08-12

    Twisted bilayer graphene (tBLG) exhibits van Hove singularities (VHSs) in the density of states that can be tuned by changing the twist angle (θ), sparking various novel physical phenomena. Much effort has been devoted to investigate the θ-dependent physical properties of tBLG. Yet, the chemical properties of tBLG with VHSs, especially the chemical reactivity, remain unexplored. Here we report the first systematic study on the chemistry of tBLG through the photochemical reaction between graphene and benzoyl peroxide. Twisted bilayer graphene exhibits θ-dependent reactivity, and remarkably enhanced reactivity is obtained when the energy of incident laser matches with the energy interval of the VHSs of tBLG. This work provides an insight on the chemistry of tBLG, and the successful enhancement of chemical reactivity derived from VHS is highly beneficial for the controllable chemical modification of tBLG as well as the development of tBLG based devices. PMID:26151687

  15. Optical Determination of Gate--Tunable Bandgap in Bilayer Graphene

    SciTech Connect

    Zhang, Yuanbo; Tang, Tsung-Ta; Girit, Caglar; Hao, Zhao; Martin, Michael C.; Zettl, Alex; Crommie, Michael F.; Shen, Y. Ron; Wang, Feng

    2009-08-11

    The electronic bandgap is an intrinsic property of semiconductors and insulators that largely determines their transport and optical properties. As such, it has a central role in modern device physics and technology and governs the operation of semiconductor devices such as p-n junctions, transistors, photodiodes and lasers. A tunable bandgap would be highly desirable because it would allow great flexibility in design and optimization of such devices, in particular if it could be tuned by applying a variable external electric field. However, in conventional materials, the bandgap is fixed by their crystalline structure, preventing such bandgap control. Here we demonstrate the realization of a widely tunable electronic bandgap in electrically gated bilayer graphene. Using a dual-gate bilayer graphene field-effect transistor (FET) and infrared microspectroscopy, we demonstrate a gate-controlled, continuously tunable bandgap of up to 250 meV. Our technique avoids uncontrolled chemical doping and provides direct evidence of a widely tunable bandgap -- spanning a spectral range from zero to mid-infrared -- that has eluded previous attempts. Combined with the remarkable electrical transport properties of such systems, this electrostatic bandgap control suggests novel nanoelectronic and nanophotonic device applications based on graphene.

  16. Physics and applications of novel structures with CVD graphene: edges, grain boundaries, twisted bilayers, and hybrids

    NASA Astrophysics Data System (ADS)

    Chen, Yong P.

    2014-03-01

    In this talk, I will discuss experimental studies (including electronic transport, optical/Raman, and STM) of physical properties of various novel synthetic graphene structures formed in CVD graphene grown on Cu, including edges of graphene single crystals, grain boundaries between such single crystals, and twisted bilayer graphene. Such synthetic graphene structures could be used as playground to explore novel physics and engineer new functionalities in graphene based electronic devices. Furthermore, I will discuss graphene based ``hybrid'' materials combining CVD graphene with semiconductor and metallic nanostructures for potential optoelectronic and plasmonics applications.

  17. Electronic Bloch oscillation in bilayer graphene gradient superlattices

    SciTech Connect

    Cheng, Hemeng; Li, Changan; Song, Yun; Ma, Tianxing; Wang, Li-Gang; Lin, Hai-Qing

    2014-08-18

    We investigate the electronic Bloch oscillation in bilayer graphene gradient superlattices using transfer matrix method. By introducing two kinds of gradient potentials of square barriers along electrons propagation direction, we find that Bloch oscillations up to terahertz can occur. Wannier-Stark ladders, as the counterpart of Bloch oscillation, are obtained as a series of equidistant transmission peaks, and the localization of the electronic wave function is also signature of Bloch oscillation. Furthermore, the period of Bloch oscillation decreases linearly with increasing gradient of barrier potentials.

  18. Negative terahertz conductivity in remotely doped graphene bilayer heterostructures

    SciTech Connect

    Ryzhii, V.; Ryzhii, M.; Mitin, V.; Shur, M. S.; Otsuji, T.

    2015-11-14

    Injection or optical generation of electrons and holes in graphene bilayers (GBLs) can result in the interband population inversion enabling the terahertz (THz) radiation lasing. The intraband radiative processes compete with the interband transitions. We demonstrate that remote doping enhances the indirect interband generation of photons in the proposed GBL heterostructures. Therefore, such remote doping helps to surpass the intraband (Drude) absorption, and results in large absolute values of the negative dynamic THz conductivity in a wide range of frequencies at elevated (including room) temperatures. The remotely doped GBL heterostructure THz lasers are expected to achieve higher THz gain compared with previously proposed GBL-based THz lasers.

  19. Giant Frictional Drag in Double Bilayer Graphene Heterostructures

    NASA Astrophysics Data System (ADS)

    Lee, Kayoung; Xue, Jiamin; Dillen, David C.; Watanabe, Kenji; Taniguchi, Takashi; Tutuc, Emanuel

    2016-07-01

    We study the frictional drag between carriers in two bilayer graphene flakes separated by a 2-5 nm thick hexagonal boron nitride dielectric. At temperatures (T ) lower than ˜10 K , we observe a large anomalous negative drag emerging predominantly near the drag layer charge neutrality. The anomalous drag resistivity increases dramatically with reducing T , and becomes comparable to the layer resistivity at the lowest T =1.5 K . At low T the drag resistivity exhibits a breakdown of layer reciprocity. A comparison of the drag resistivity and the drag layer Peltier coefficient suggests a thermoelectric origin of this anomalous drag.

  20. Giant Frictional Drag in Double Bilayer Graphene Heterostructures.

    PubMed

    Lee, Kayoung; Xue, Jiamin; Dillen, David C; Watanabe, Kenji; Taniguchi, Takashi; Tutuc, Emanuel

    2016-07-22

    We study the frictional drag between carriers in two bilayer graphene flakes separated by a 2-5 nm thick hexagonal boron nitride dielectric. At temperatures (T) lower than ∼10  K, we observe a large anomalous negative drag emerging predominantly near the drag layer charge neutrality. The anomalous drag resistivity increases dramatically with reducing T, and becomes comparable to the layer resistivity at the lowest T=1.5  K. At low T the drag resistivity exhibits a breakdown of layer reciprocity. A comparison of the drag resistivity and the drag layer Peltier coefficient suggests a thermoelectric origin of this anomalous drag. PMID:27494492

  1. Quantum Hall States and Phase Diagram of Bilayer Graphene

    NASA Astrophysics Data System (ADS)

    Jia, Junji

    2013-03-01

    The quantum Hall states of bilayer graphene for filling factor ν from 0 to 4 are investigated using lowest Landau level approximation. A critical line in the E⊥B plane for both the ν = 0 and 1 case is found. This line separates the (partially) spin polarized and (partially) layer polarized phases in the ν = 0 (1) case. The gaps for all ν are found to scale linearly with B. The existence of phase separation line, the linearity of the gaps, and the hierarchy for gaps of different ν agree well with experiments.

  2. The Coulomb excitations of Bernal bilayer graphene under external fields

    SciTech Connect

    Wu, Jhao-Ying; Lin, Ming-Fa

    2014-03-31

    We study the field effects on the Coulomb excitation spectrum of Bernal bilayer graphene by using the tight-binding model and the random-phase approximation. The electric field opens the band gap and creates the saddle points, the latter brings about a prominent interband plasmon. On the other hand, the magnetic field induces the dispersionless Landau levels (LLs) that causes the inter-LL plasmons. The two kinds of field-induced plasmon modes can be further tuned by the magnitude of momentum transfer and the field strength. The predicted results may be further validated by the inelastic light-scattering or high-resolution electron-energy-loss spectroscopy (HREELLS)

  3. Feature-Rich Magnetic Quantization in Sliding Bilayer Graphenes

    NASA Astrophysics Data System (ADS)

    Huang, Yao-Kung; Chen, Szu-Chao; Ho, Yen-Hung; Lin, Chiun-Yan; Lin, Ming-Fa

    2014-12-01

    The generalized tight-binding model, based on the subenvelope functions of distinct sublattices, is developed to investigate the magnetic quantization in sliding bilayer graphenes. The relative shift of two graphene layers induces a dramatic transformation between the Dirac-cone structure and the parabolic band structure, and thus leads to drastic changes of Landau levels (LLs) in the spatial symmetry, initial formation energy, intergroup anti-crossing, state degeneracy and semiconductor-metal transition. There exist three kinds of LLs, i.e., well-behaved, perturbed and undefined LLs, which are characterized by a specific mode, a main mode plus side modes, and a disordered mode, respectively. Such LLs are clearly revealed in diverse magneto-optical selection rules. Specially, the undefined LLs frequently exhibit intergroup anti-crossings in the field-dependent energy spectra, and show a large number of absorption peaks without optical selection rules.

  4. Tight-binding study of bilayer graphene Josephson junctions

    NASA Astrophysics Data System (ADS)

    Muñoz, W. A.; Covaci, L.; Peeters, F. M.

    2012-11-01

    Using highly efficient simulations of the tight-binding Bogoliubov-de-Gennes model, we solved self-consistently for the pair correlation and the Josephson current in a superconducting-bilayer graphene-superconducting Josephson junction. Different doping levels for the non-superconducting link are considered in the short- and long-junction regimes. Self-consistent results for the pair correlation and superconducting current resemble those reported previously for single-layer graphene except at the Dirac point, where remarkable differences in the proximity effect are found, as well as a suppression of the superconducting current in the long-junction regime. Inversion symmetry is broken by considering a potential difference between the layers and we found that the supercurrent can be switched if the junction length is larger than the Fermi length.

  5. Low temperature edge dynamics of AB-stacked bilayer graphene: naturally favored closed zigzag edges.

    PubMed

    Zhan, Da; Liu, Lei; Xu, Ya Nan; Ni, Zhen Hua; Yan, Jia Xu; Zhao, Chun; Shen, Ze Xiang

    2011-01-01

    Closed edges bilayer graphene (CEBG) is a recent discovered novel form of graphene structures, whose regulated edge states may critically change the overall electronic behaviors. If stacked properly with the AB style, the bilayer graphene with closed zigzag edges may even present amazing electronic properties of bandgap opening and charge separation. Experimentally, the CEBG has been confirmed recently with HRTEM observations after extremely high temperature annealing (2000 °C). From the application point of view, the low temperature closing of the graphene edges would be much more feasible for large-scale graphene-based electronic devices fabrication. Here, we demonstrate that the zigzag edges of AB-stacked bilayer graphene will form curved close structure naturally at low annealing temperature (< 500 °C) based on Raman observation and first principles analysis. Such findings may illuminate a simple and easy way to engineer graphene electronics. PMID:22355531

  6. Analytical investigation of bilayer lipid biosensor based on graphene.

    PubMed

    Akbari, Elnaz; Buntat, Zolkafle; Shahraki, Elmira; Parvaz, Ramtin; Kiani, Mohammad Javad

    2016-01-01

    Graphene is another allotrope of carbon with two-dimensional monolayer honeycomb. Owing to its special characteristics including electrical, physical and optical properties, graphene is known as a more suitable candidate compared to other materials to be used in the sensor application. It is possible, moreover, to use biosensor by using electrolyte-gated field effect transistor based on graphene (GFET) to identify the alterations in charged lipid membrane properties. The current article aims to show how thickness and charges of a membrane electric can result in a monolayer graphene-based GFET while the emphasis is on the conductance variation. It is proposed that the thickness and electric charge of the lipid bilayer (LLP and QLP) are functions of carrier density, and to find the equation relating these suitable control parameters are introduced. Artificial neural network algorithm as well as support vector regression has also been incorporated to obtain other models for conductance characteristic. The results comparison between analytical models, artificial neural network and support vector regression with the experimental data extracted from previous work show an acceptable agreement. PMID:26024896

  7. Gate-defined Quantum Confinement in Suspended Bilayer Graphene

    NASA Astrophysics Data System (ADS)

    Allen, Monica

    2013-03-01

    Quantum confined devices in carbon-based materials offer unique possibilities for applications ranging from quantum computation to sensing. In particular, nanostructured carbon is a promising candidate for spin-based quantum computation due to the ability to suppress hyperfine coupling to nuclear spins, a dominant source of spin decoherence. Yet graphene lacks an intrinsic bandgap, which poses a serious challenge for the creation of such devices. We present a novel approach to quantum confinement utilizing tunnel barriers defined by local electric fields that break sublattice symmetry in suspended bilayer graphene. This technique electrostatically confines charges via band structure control, thereby eliminating the edge and substrate disorder that hinders on-chip etched nanostructures to date. We report clean single electron tunneling through gate-defined quantum dots in two regimes: at zero magnetic field using the energy gap induced by a perpendicular electric field and at finite magnetic fields using Landau level confinement. The observed Coulomb blockade periodicity agrees with electrostatic simulations based on local top-gate geometry, a direct demonstration of local control over the band structure of graphene. This technology integrates quantum confinement with pristine device quality and access to vibrational modes, enabling wide applications from electromechanical sensors to quantum bits. More broadly, the ability to externally tailor the graphene bandgap over nanometer scales opens a new unexplored avenue for creating quantum devices.

  8. Low-field carrier transport properties in biased bilayer graphene

    NASA Astrophysics Data System (ADS)

    Hu, Bo

    2014-07-01

    Based on a semiclassical Boltzmann transport equation in random phase approximation, we develop a theoretical model to understand low-field carrier transport in biased bilayer graphene, which takes into account the charged impurity scattering, acoustic phonon scattering, and surface polar phonon scattering as three main scattering mechanisms. The surface polar optical phonon scattering of carriers in supported bilayer graphene is thoroughly studied using the Rode iteration method. By considering the metal-BLG contact resistance as the only one free fitting parameter, we find that the carrier density dependence of the calculated total conductivity agrees well with that observed in experiment under different temperatures. The conductivity results also suggest that in high carrier density range, the metal-BLG contact resistance can be a significant factor in determining the BLG conductivity at low temperature, and both acoustic phonon scattering and surface polar phonon scattering play important roles at higher temperature, especially for BLG samples with a low doping concentration, which can compete with charged impurity scattering.

  9. Scaling laws of van Hove singularities in twisted bilayer graphene

    NASA Astrophysics Data System (ADS)

    Jung, Jeil; Dasilva, Ashley; Wang, Yang; Wong, Dillon; Crommie, Michael; Adam, Shaffique; MacDonald, Allan H.

    2014-03-01

    Van Hove singularities (vHS) appear in twisted coupled bilayer graphene at saddle points in the band structure. The lowest energy vHS can be associated with the overlap between the displaced Dirac cones of the top and bottom layers, resulting in an approximately linear increase of its position in energy with increasing twist angle. This picture, which is applicable in the perturbative regime for moderately large twist angles, sees departures in the small angle limit due to non-perturbative coupling between the layers. Using a theory for twisted bilayer graphene [1] that incorporates all the relevant interlayer coupling compatible with momentum conservation of k-vectors of the top and bottom layers we explore the scaling laws of the vHS for sufficiently small twist angles and long period moire superlattices. We analyze the localization properties of their wave functions through their local density of states (LDOS) paying particular attention to the behavior of the states corresponding to higher energy van Hove singularities. We comment on our results in light of the experimental DOS and LDOS maps obtained through scanning tunneling microscopy. This work is supported by the Singapore National Research Foundation under its Fellowship program (NRF-NRFF2012-01).

  10. Electronic compressibility of layer-polarized bilayer graphene

    NASA Astrophysics Data System (ADS)

    Young, A. F.; Dean, C. R.; Meric, I.; Sorgenfrei, S.; Ren, H.; Watanabe, K.; Taniguchi, T.; Hone, J.; Shepard, K. L.; Kim, P.

    2012-06-01

    We report on a capacitance study of dual gated bilayer graphene. The measured capacitance allows us to probe the electronic compressibility as a function of carrier density, temperature, and applied perpendicular electrical displacement D¯. As a band gap is induced with increasing D¯, the compressibility minimum at charge neutrality becomes deeper but remains finite, suggesting the presence of localized states within the energy gap. Temperature dependent capacitance measurements show that compressibility is sensitive to the intrinsic band gap. For large displacements, an additional peak appears in the compressibility as a function of density, corresponding to the presence of a one-dimensional van Hove singularity (vHs) at the band edge arising from the quartic bilayer graphene band structure. For D¯>0, the additional peak is observed only for electrons, while for D¯<0 the peak appears only for holes. This asymmetry can be understood in terms of the finite interlayer separation and may be useful as a direct probe of the layer polarization.

  11. Local compressibility of bilayer graphene in the quantum hall regime

    NASA Astrophysics Data System (ADS)

    Levin, Andrei; Kou, Angela; Feldman, Benjamin; Halperin, Bertrand; Watanabe, Kenji; Taniguchi, Takashi; Yacoby, Amir

    2014-03-01

    In the presence of a strong magnetic field, the charge carriers in bilayer graphene (BLG) condense into a set of flat energy bands called Landau levels (LLs). Electronic compressibility measurements have historically been a powerful tool in studying the physics of partially filled LLs in two-dimensional electronic systems. In particular, electron-electron correlations arising from Coulomb interactions can introduce a negative component to the compressibility. Here we present measurements of electronic compressibility in BLG, performed locally using a scanning single electron transistor. We find that while the inverse compressibility is close to zero for 4 < | ν | < 8 , it is markedly more negative in the lowest LL, | ν | < 4 . Moreover, within the lowest LL, the background inverse compressibility between integer filling also exhibits a stark even-odd asymmetry. It is more negative when starting to fill from an even filling factor than when starting to fill from an odd filling factor, exhibiting a ν --> ν + 2 symmetry and indicating the important role of the orbital degeneracy uniquely present in bilayer graphene.

  12. Conductance and shot noise in strained bilayer graphene.

    PubMed

    Pearce, Alexander J; Cavaliere, Fabio; Mariani, Eros

    2013-09-18

    We explore the effect of trigonal warping and of elastic deformations on the electronic spectrum of bilayer graphene devices, on their ballistic conductance as well as on the shot noise. Uniaxial strain distorts the lattice creating a uniform fictitious gauge field in the electronic Dirac Hamiltonian which ultimately causes a dramatic reconstruction in the trigonally warped electronic spectrum, inducing topological transitions in the Fermi surface. In this paper we present results of ballistic transport in bilayer graphene in the absence and presence of strain, with particular focus on noise and the Fano factor F. The inclusion of trigonal warping preserves the pseudo-diffusive value of F = 1/3 at the Dirac point, as calculated in the absence of trigonal warping terms. However, the range of energies which show pseudo-diffusive transport increases by orders of magnitude compared to the results stemming out of a parabolic spectrum and the applied strain acts to increase this energy range further. PMID:23963478

  13. Graphene-silicene bilayer: A nanocapacitor with permanent dipole and piezoelectricity effect

    NASA Astrophysics Data System (ADS)

    Peymanirad, F.; Neek-Amal, M.; Beheshtian, J.; Peeters, F. M.

    2015-10-01

    Using density functional theory, we study the electronic properties of a graphene-silicene bilayer (GSB). A single layer of silicene binds to the graphene layer with adhesion energy of about 25 meV/atom. This adhesion energy between the two layers follows accurately the well-known -1 /z2 dispersion energy as found between two infinite parallel plates. In small flakes of GSB with hydrogenated edges, negative charge is transferred from the graphene layer to the silicene layer, producing a permanent and a switchable polar bilayer, while in an infinite GSB, the negative charge is transferred from the silicene layer to the graphene layer. The graphene-silicene bilayer is a good candidate for a nanocapacitor with piezoelectric capabilities. We found that the permanent dipole of the bilayer can be tuned by an external perpendicular electric field.

  14. Low-energy theory for the graphene twist bilayer

    NASA Astrophysics Data System (ADS)

    Weckbecker, D.; Shallcross, S.; Fleischmann, M.; Ray, N.; Sharma, S.; Pankratov, O.

    2016-01-01

    The graphene twist bilayer represents the prototypical system for investigating the stacking degree of freedom in few-layer graphenes. The electronic structure of this system changes qualitatively as a function of angle, from a large-angle limit in which the two layers are essentially decoupled—with the exception of a 28-atom commensuration unit cell for which the layers are coupled on an energy scale of ≈8 meV —to a small-angle strong-coupling limit. Despite sustained investigation, a fully satisfactory theory of the twist bilayer remains elusive. The outstanding problems are (i) to find a theoretically unified description of the large- and small-angle limits, and (ii) to demonstrate agreement between the low-energy effective Hamiltonian and, for instance, ab initio or tight-binding calculations. In this article, we develop a low-energy theory that in the large-angle limit reproduces the symmetry-derived Hamiltonians of Mele [Phys. Rev. B 81, 161405 (2010), 10.1103/PhysRevB.81.161405], and in the small-angle limit shows almost perfect agreement with tight-binding calculations. The small-angle effective Hamiltonian is that of Bistritzer and MacDonald [Proc. Natl. Acad. Sci. (U.S.A.) 108, 12233 (2011), 10.1073/pnas.1108174108], but with the momentum scale Δ K , the difference of the momenta of the unrotated and rotated special points, replaced by a coupling momentum scale g(c )=8/π √{3 }a sinθ/2 . Using this small-angle Hamiltonian, we are able to determine the complete behavior as a function of angle, finding a complex small-angle clustering of van Hove singularities in the density of states (DOS) that after a "zero-mode" peak regime between 0 .90°<θ <0 .15° limits θ <0 .05° to a DOS that is essentially that of a superposition DOS of all bilayer stacking possibilities. In this regime, the Dirac spectrum is entirely destroyed by hybridization for -0.25 graphene

  15. High-yield chemical vapor deposition growth of high-quality large-area AB-stacked bilayer graphene.

    PubMed

    Liu, Lixin; Zhou, Hailong; Cheng, Rui; Yu, Woo Jong; Liu, Yuan; Chen, Yu; Shaw, Jonathan; Zhong, Xing; Huang, Yu; Duan, Xiangfeng

    2012-09-25

    Bernal-stacked (AB-stacked) bilayer graphene is of significant interest for functional electronic and photonic devices due to the feasibility to continuously tune its band gap with a vertical electric field. Mechanical exfoliation can be used to produce AB-stacked bilayer graphene flakes but typically with the sizes limited to a few micrometers. Chemical vapor deposition (CVD) has been recently explored for the synthesis of bilayer graphene but usually with limited coverage and a mixture of AB- and randomly stacked structures. Herein we report a rational approach to produce large-area high-quality AB-stacked bilayer graphene. We show that the self-limiting effect of graphene growth on Cu foil can be broken by using a high H(2)/CH(4) ratio in a low-pressure CVD process to enable the continued growth of bilayer graphene. A high-temperature and low-pressure nucleation step is found to be critical for the formation of bilayer graphene nuclei with high AB stacking ratio. A rational design of a two-step CVD process is developed for the growth of bilayer graphene with high AB stacking ratio (up to 90%) and high coverage (up to 99%). The electrical transport studies demonstrate that devices made of the as-grown bilayer graphene exhibit typical characteristics of AB-stacked bilayer graphene with the highest carrier mobility exceeding 4000 cm(2)/V · s at room temperature, comparable to that of the exfoliated bilayer graphene. PMID:22906199

  16. Electronic properties and the quantum Hall effect in bilayer graphene.

    PubMed

    Fal'ko, Vladimir I

    2008-01-28

    In this paper, I review the quantum Hall effect (QHE) and far-infra red (FIR) absorption properties of bilayer graphene in a strong magnetic field. This includes a derivation of the effective low-energy Hamiltonian for this system and the consequences of this Hamiltonian for the sequencing of the Landau levels in the material: the form of this effective Hamiltonian gives rise to the presence of a level with doubled degeneracy at zero energy. The effect of a potential difference between the layer of a bilayer is also investigated. It is found that there is a density-dependent gap near the K points in the band structure. The consequences of this gap on the QHE are then described. Also, the magneto-absorption spectrum is investigated and an experiment proposed to distinguish between model groundstates of the bilayer QHE system based on the different absorption characteristics of right- and left-handed polarization of FIR light. Finally, the effects of trigonal warping are taken into account in the absorption picture. PMID:18024357

  17. Buckling failure of square ice-nanotube arrays constrained in graphene nanocapillaries

    NASA Astrophysics Data System (ADS)

    Zhu, YinBo; Wang, FengChao; Wu, HengAn

    2016-08-01

    Graphene confinement provides a new physical and mechanical environment with ultrahigh van der Waals pressure, resulting in new quasi-two-dimensional phases of few-layer ice. Polymorphic transition can occur in bilayer constrained water/ice system. Here, we perform a comprehensive study of the phase transition of AA-stacked bilayer water constrained within a graphene nanocapillary. The compression-limit and superheating-limit (phase) diagrams are obtained, based on the extensive molecular-dynamics simulations at numerous thermodynamic states. Liquid-to-solid, solid-to-solid, and solid-to-liquid-to-solid phase transitions are observed in the compression and superheating of bilayer water. Interestingly, there is a temperature threshold (˜275 K) in the compression-limit diagram, which indicates that the first-order and continuous-like phase transitions of bilayer water depend on the temperature. Two obviously different physical processes, compression and superheating, display similar structural evolution; that is, square ice-nanotube arrays (BL-VHDI) will bend first and then transform into bilayer triangular AA stacking ice (BL-AAI). The superheating limit of BL-VHDI exhibits local maxima, while that of BL-AAI increases monotonically. More importantly, from a mechanics point of view, we propose a novel mechanism of the transformation from BL-VHDI to BL-AAI, both for the compression and superheating limits. This structural transformation can be regarded as the "buckling failure" of the square-ice-nanotube columns, which is dominated by the lateral pressure.

  18. Hexagonal-shaped monolayer-bilayer quantum disks in graphene: A tight-binding approach

    NASA Astrophysics Data System (ADS)

    da Costa, D. R.; Zarenia, M.; Chaves, Andrey; Pereira, J. M.; Farias, G. A.; Peeters, F. M.

    2016-07-01

    Using the tight-binding approach, we investigate confined states in two different hybrid monolayer-bilayer systems: (i) a hexagonal monolayer area surrounded by bilayer graphene in the presence of a perpendicularly applied electric field and (ii) a hexagonal bilayer graphene dot surrounded by monolayer graphene. The dependence of the energy levels on dot size and external magnetic field is calculated. We find that the energy spectrum for quantum dots with zigzag edges consists of states inside the gap which range from dot-localized states, edge states, to mixed states coexisting together, whereas for dots with armchair edges, only dot-localized states are observed.

  19. Helium isotope enrichment by resonant tunneling through nanoporous graphene bilayers.

    PubMed

    Mandrà, Salvatore; Schrier, Joshua; Ceotto, Michele

    2014-08-21

    Graphene is impermeable to gases, but introducing subnanometer pores can allow for selective gas separation. Because graphene is only one atom thick, tunneling can play an important role, especially for low-mass gases such as helium, and this has been proposed as a means of separating (3)He from (4)He. In this paper, we consider the possibility of utilizing resonant tunneling of helium isotopes through nanoporous graphene bilayers. Using a model potential fit to previously reported DFT potential energy surfaces, we calculate the thermal rate constant as a function of interlayer separation using a recently described time-independent method for arbitrary multibarrier potentials. Resonant transmission allows for the total flux rate of (3)He to remain the same as the best-known single-barrier pores but doubles the selectivity with respect to (4)He when the optimal interlayer spacing of 4.6 Å is used. The high flux rate and selectivity are robust against variations of the interlayer spacing and asymmetries in the potential that may occur in experiment. PMID:24854987

  20. Ruderman-Kittel-Kasuya-Yosida interaction at finite temperature: Graphene and bilayer graphene

    NASA Astrophysics Data System (ADS)

    Klier, N.; Shallcross, S.; Sharma, S.; Pankratov, O.

    2015-11-01

    We investigate the Ruderman-Kittel-Kasuya-Yosida (RKKY) interaction between magnetic impurities in both single layer and Bernal stacked bilayer graphene, finding a number of striking anomalies in the temperature dependence of this interaction. In undoped single layer graphene the strength of the RKKY interaction for substitutional impurities anomalously increases upon increasing temperature, an effect that persists up to and beyond room temperature. For impurities intercalated in the Bernal stacked bilayer and a doping that places the chemical potential near the antibonding band edge, a qualitative change of the RKKY interaction with temperature occurs: a low-temperature oscillatory interaction develops into a high-temperature antiferromagnetic coupling, accompanied by an overall increase of the interaction strength. The origin of the temperature anomalies can be traced back to specific features of the density of states: the vanishing density of states at the apex of the Dirac cone in single layer graphene, and the "kink" in the density of states at the antibonding band edge in the case of the Bernal bilayer.

  1. Tuning the Band Gap of Bilayer Graphene by Sandwich-Like Stacking

    NASA Astrophysics Data System (ADS)

    Hu, Zhenpeng

    As far as we know, graphene has been taken as a potential host material for next-generation electric devices. However, this attractive prospect has been blocked by the metallic character of graphene. Although many methods have been proposed to get a moderate energy gap, such as hydrogenated graphene (graphane), but all the intrinsic advantages (carrier's mobility, etc...) of graphene have been destroyed. Here, we report that a large energy gap of graphene bilayer can be opened without breaking its natural characters by sandwiching it between functionalized BN substrates. Also, we show that the band gap of graphene bilayer can be tuned from 0.35 eV to 0.50 eV, depending on the substrates. The gap value is much larger than any other methods, and the structure of graphene bilayer is perfectly kept. And the energy gap is robust, namely, once the sandwiched substrates are selected, the relative position of substrates and graphene bilayer hardly changes the energy gap. Since the proposed way is easy to be realized in experiments, our results will hopefully accelerate the application of graphene in semiconductor devices and promote the development of the graphene technology. This work is supported by NSFC 21203099.

  2. Semiconducting properties of bilayer graphene modulated by an electric field for next-generation atomic-film electronics

    NASA Astrophysics Data System (ADS)

    Tsukagoshi, K.; Li, S.-L.; Miyazaki, H.; Aparecido-Ferreira, A.; Nakaharai, S.

    2014-03-01

    A practical wide bandgap was induced in bilayer graphene using a perpendicular electric field. A self-assembled gate insulator was used to apply a large electric field. The wide bandgap allows the operation of fundamental logic gates composed of bilayer graphene transistors. The results reviewed here indicate the potential for graphene electronics to be realized as emerging transistors with an atomically thin semiconductor.

  3. Enhanced sensitivity of a microfabricated resonator using a graphene-polystyrene bilayer membrane

    SciTech Connect

    Yun, Minhyuk; Lee, Eunho; Cho, Kilwon; Jeon, Sangmin

    2014-08-18

    A graphene layer was synthesized using chemical vapor deposition methods and a polystyrene solution was spin-cast onto the graphene film. The graphene-polystyrene bilayer membrane was attached between the two tines of a microfabricated quartz tuning fork (QTF). The modulus of the graphene-polystyrene bilayer was measured to be twice that of a pristine polystyrene membrane. Exposure of the membrane-coated QTF to ethanol vapor decreased the resonance frequency of the microresonator. The bilayer membrane-coated QTF produced a frequency change that was three times the change obtained using a polystyrene membrane-coated QTF, with a lower degree of degradation in the Q factor. The limit of detection of the bilayer membrane-coated QTF to ethanol vapor was determined to be 20 ppm.

  4. Electric gating induced bandgaps and enhanced Seebeck effect in zigzag bilayer graphene ribbons

    NASA Astrophysics Data System (ADS)

    Vu, Thanh-Tra; Tran, Van-Truong

    2016-08-01

    We theoretically investigate the effect of a transverse electric field generated by side gates and a vertical electric field generated by top/back gates on energy bands and transport properties of zigzag bilayer graphene ribbons (Bernal stacking). Using atomistic tight binding calculations and Green’s function formalism we demonstrate that a bandgap is opened when either field is applied and even enlarged under simultaneous influence of the two fields. Interestingly, although vertical electric fields are widely used to control the bandgap in bilayer graphene, here we show that transverse fields exhibit a more positive effect in terms of modulating a larger range of bandgap and retaining good electrical conductance. The Seebeck effect is also demonstrated to be enhanced strongly—by about 13 times for a zigzag bilayer graphene ribbon with 16 chain lines. These results may motivate new designs of devices made of bilayer graphene ribbons using electric gates.

  5. Generation of valley-polarized electron beam in bilayer graphene

    SciTech Connect

    Park, Changsoo

    2015-12-28

    We propose a method to produce valley-polarized electron beams using a bilayer graphene npn junction. By analyzing the transmission properties of electrons through the junction with zigzag interface in the presence of trigonal warping, we observe that there exist a range of incident energies and barrier heights in which transmitted electrons are well polarized and collimated. From this observation and by performing numerical simulations, it is demonstrated that valley-dependent electronic currents with nearly perfect polarization can be generated. We also show that the peak-to-peak separation angle between the polarized currents is tunable either by incident energy or by barrier height each of which is controlled by using top and back gate voltages. The results can be used for constructing an electron beam splitter to produce valley-polarized currents.

  6. Excitonic gap formation and condensation in the bilayer graphene structure

    NASA Astrophysics Data System (ADS)

    Apinyan, V.; Kopeć, T. K.

    2016-09-01

    We have studied the excitonic gap formation in the Bernal Stacked, bilayer graphene (BLG) structures at half-filling. Considering the local Coulomb interaction between the layers, we calculate the excitonic gap parameter and we discuss the role of the interlayer and intralayer Coulomb interactions and the interlayer hopping on the excitonic pair formation in the BLG. Particularly, we predict the origin of excitonic gap formation and condensation, in relation to the furthermost interband optical transition spectrum. The general diagram of excitonic phase transition is given, explaining different interlayer correlation regimes. The temperature dependence of the excitonic gap parameter is shown and the role of the chemical potential, in the BLG, is discussed in details.

  7. Magneto-optical transitions in bilayer graphene nanoribbons

    NASA Astrophysics Data System (ADS)

    Chung, Hsien-Ching; Lin, Ming-Fa

    We utilize the tight-binding theory to study the magneto-optical transitions in bilayer graphene nanoribbons. The magneto-absorption spectra highly depend on the stacking, edge orientation, ribbon width, and strength of magnetic field. The competition between the magnetic quantization and lateral confinement results in the coexistence of edge-dependent selection rules and magneto-absorption selection rule. The magneto-electronic properties, including energy dispersions, density of states, and wave functions, are also discussed in detail. One of us (Hsien-Ching Chung) thanks Ming-Hui Chung and Su-Ming Chen for financial support. This work was supported in part by the National Science Council of Taiwan under Grant Number NSC 102-2112-M-006-007-MY3.

  8. Controllable poly-crystalline bilayered and multilayered graphene film growth by reciprocal chemical vapor deposition

    NASA Astrophysics Data System (ADS)

    Wu, Qinke; Jung, Seong Jun; Jang, Sung Kyu; Lee, Joohyun; Jeon, Insu; Suh, Hwansoo; Kim, Yong Ho; Lee, Young Hee; Lee, Sungjoo; Song, Young Jae

    2015-06-01

    We report the selective growth of large-area bilayered graphene film and multilayered graphene film on copper. This growth was achieved by introducing a reciprocal chemical vapor deposition (CVD) process that took advantage of an intermediate h-BN layer as a sacrificial template for graphene growth. A thin h-BN film, initially grown on the copper substrate using CVD methods, was locally etched away during the subsequent graphene growth under residual H2 and CH4 gas flows. Etching of the h-BN layer formed a channel that permitted the growth of additional graphene adlayers below the existing graphene layer. Bilayered graphene typically covers an entire Cu foil with domain sizes of 10-50 μm, whereas multilayered graphene can be epitaxially grown to form islands a few hundreds of microns in size. This new mechanism, in which graphene growth proceeded simultaneously with h-BN etching, suggests a potential approach to control graphene layers for engineering the band structures of large-area graphene for electronic device applications.We report the selective growth of large-area bilayered graphene film and multilayered graphene film on copper. This growth was achieved by introducing a reciprocal chemical vapor deposition (CVD) process that took advantage of an intermediate h-BN layer as a sacrificial template for graphene growth. A thin h-BN film, initially grown on the copper substrate using CVD methods, was locally etched away during the subsequent graphene growth under residual H2 and CH4 gas flows. Etching of the h-BN layer formed a channel that permitted the growth of additional graphene adlayers below the existing graphene layer. Bilayered graphene typically covers an entire Cu foil with domain sizes of 10-50 μm, whereas multilayered graphene can be epitaxially grown to form islands a few hundreds of microns in size. This new mechanism, in which graphene growth proceeded simultaneously with h-BN etching, suggests a potential approach to control graphene layers for

  9. Growth of ultra-uniform graphene using a Ni/W bilayer metal catalyst

    SciTech Connect

    Yang, Jae Hoon; Hwang, Jae Seok; Yang, Hyoung Woo; Kang, Dae Joon; Jang, A-Rang; Shin, Hyeon Suk; Jang, Jae-Eun

    2015-01-26

    We investigated a bilayer catalyst system consisting of polycrystalline Ni and W films for growing mono-layer graphene over large areas. Highly uniform graphene was grown on Ni/W bilayer film with 100% coverage. The graphene grown on Ni/W bilayer film and transferred onto an insulating substrate exhibited average hole and electron mobilities of 727 and 340 cm{sup 2}V{sup −1}s{sup −1}, respectively. A probable growth mechanism is proposed based on X-ray diffractometry and transmission electron microscopy, which suggests that the reaction between diffused carbon and tungsten atoms results in formation of tungsten carbides. This reaction allows the control of carbon precipitation and prevents the growth of non-uniform multilayer graphene on the Ni surface; this has not been straightforwardly achieved before. These results could be of importance in better understanding mono-layer graphene growth, and suggest a facile fabrication route for electronic applications.

  10. Conductance fluctuations in chaotic bilayer graphene quantum dots.

    PubMed

    Bao, Rui; Huang, Liang; Lai, Ying-Cheng; Grebogi, Celso

    2015-07-01

    Previous studies of quantum chaotic scattering established a connection between classical dynamics and quantum transport properties: Integrable or mixed classical dynamics can lead to sharp conductance fluctuations but chaos is capable of smoothing out the conductance variations. Relativistic quantum transport through single-layer graphene systems, for which the quasiparticles are massless Dirac fermions, exhibits, due to scarring, this classical-quantum correspondence, but sharp conductance fluctuations persist to a certain extent even when the classical system is fully chaotic. There is an open issue regarding the effect of finite mass on relativistic quantum transport. To address this issue, we study quantum transport in chaotic bilayer graphene quantum dots for which the quasiparticles have a finite mass. An interesting phenomenon is that, when traveling along the classical ballistic orbit, the quasiparticle tends to hop back and forth between the two layers, exhibiting a Zitterbewegung-like effect. We find signatures of abrupt conductance variations, indicating that the mass has little effect on relativistic quantum transport. In solid-state electronic devices based on Dirac materials, sharp conductance fluctuations are thus expected, regardless of whether the quasiparticle is massless or massive and whether there is chaos in the classical limit. PMID:26274258

  11. Crossover from retro to specular Andreev reflections in bilayer graphene

    NASA Astrophysics Data System (ADS)

    Efetov, Dmitri K.; Efetov, Konstantin B.

    2016-08-01

    Ongoing experimental progress in the preparation of ultraclean graphene/superconductor (SC) interfaces enabled the recent observation of specular interband Andreev reflections (ARs) at bilayer graphene (BLG )/NbSe2 van der Waals interfaces [Efetov et al., Nat. Phys. 12, 328 (2016), 10.1038/nphys3583]. Motivated by this experiment we theoretically study the differential conductance across a BLG/SC interface at the continuous transition from high to ultralow Fermi energies EF in BLG. Using the Bogoliubov-de Gennes equations and the Blonder-Tinkham-Klapwijk formalism we derive analytical expressions for the differential conductance across the BLG/SC interface. We find a characteristic signature of the crossover from intraband retro (high EF) to interband specular (low EF) ARs that manifests itself in a strongly suppressed interfacial conductance when the excitation energy |ɛ |=| EF|<Δ (the SC gap). The sharpness of these conductance dips is strongly dependent on the size of the potential step at the BLG/SC interface U0.

  12. Conductance fluctuations in chaotic bilayer graphene quantum dots

    NASA Astrophysics Data System (ADS)

    Bao, Rui; Huang, Liang; Lai, Ying-Cheng; Grebogi, Celso

    2015-07-01

    Previous studies of quantum chaotic scattering established a connection between classical dynamics and quantum transport properties: Integrable or mixed classical dynamics can lead to sharp conductance fluctuations but chaos is capable of smoothing out the conductance variations. Relativistic quantum transport through single-layer graphene systems, for which the quasiparticles are massless Dirac fermions, exhibits, due to scarring, this classical-quantum correspondence, but sharp conductance fluctuations persist to a certain extent even when the classical system is fully chaotic. There is an open issue regarding the effect of finite mass on relativistic quantum transport. To address this issue, we study quantum transport in chaotic bilayer graphene quantum dots for which the quasiparticles have a finite mass. An interesting phenomenon is that, when traveling along the classical ballistic orbit, the quasiparticle tends to hop back and forth between the two layers, exhibiting a Zitterbewegung-like effect. We find signatures of abrupt conductance variations, indicating that the mass has little effect on relativistic quantum transport. In solid-state electronic devices based on Dirac materials, sharp conductance fluctuations are thus expected, regardless of whether the quasiparticle is massless or massive and whether there is chaos in the classical limit.

  13. Layer-selective half-metallicity in bilayer graphene nanoribbons

    PubMed Central

    Jeon, Gi Wan; Lee, Kyu Won; Lee, Cheol Eui

    2015-01-01

    Half-metallicity recently predicted in the zigzag-edge graphene nanoribbons (ZGNRs) and the hydrogenated carbon nanotubes (CNTs) enables fully spin-polarized electric currents, providing a basis for carbon-based spintronics. In both carbon systems, the half-metallicity arises from the edge-localized electron states under an electric field, lowering the critical electric field Dc for the half-metallicity being an issue in recent works on ZGNRs. A properly chosen direction of the electric field alone has been predicted to significantly reduce Dc in the hydrogenated CNTs, which in this work turned out to be the case in narrow bilayer ZGNRs (biZGNRs). Here, our simple model based on the electrostatic potential difference between the edges predicts that for wide biZGNRs of width greater than ~2.0 nm (10 zigzag carbon chains), only one layer of the biZGNRs becomes half-metallic leaving the other layer insulating as confirmed by our density functional theory (DFT) calculations. The electric field-induced switching of the spin-polarized current path is believed to open a new route to graphene-based spintronics applications. PMID:25950724

  14. Nitrogen-Doped Graphene and Twisted Bilayer Graphene via Hyperthermal Ion Implantation with Depth Control.

    PubMed

    Cress, Cory D; Schmucker, Scott W; Friedman, Adam L; Dev, Pratibha; Culbertson, James C; Lyding, Joseph W; Robinson, Jeremy T

    2016-03-22

    We investigate hyperthermal ion implantation (HyTII) as a means for substitutionally doping layered materials such as graphene. In particular, this systematic study characterizes the efficacy of substitutional N-doping of graphene using HyTII over an N(+) energy range of 25-100 eV. Scanning tunneling microscopy results establish the incorporation of N substituents into the graphene lattice during HyTII processing. We illustrate the differences in evolution of the characteristic Raman peaks following incremental doses of N(+). We use the ratios of the integrated D and D' peaks, I(D)/I(D') to assess the N(+) energy-dependent doping efficacy, which shows a strong correlation with previously reported molecular dynamics (MD) simulation results and a peak doping efficiency regime ranging between approximately 30 and 50 eV. We also demonstrate the inherent monolayer depth control of the HyTII process, thereby establishing a unique advantage over other less-specific methods for doping. We achieve this by implementing twisted bilayer graphene (TBG), with one layer of isotopically enriched (13)C and one layer of natural (12)C graphene, and modify only the top layer of the TBG sample. By assessing the effects of N-HyTII processing, we uncover dose-dependent shifts in the transfer characteristics consistent with electron doping and we find dose-dependent electronic localization that manifests in low-temperature magnetotransport measurements. PMID:26910346

  15. Raman spectroscopy of graphene and bilayer under biaxial strain: bubbles and balloons.

    PubMed

    Zabel, Jakob; Nair, Rahul R; Ott, Anna; Georgiou, Thanasis; Geim, Andre K; Novoselov, Kostya S; Casiraghi, Cinzia

    2012-02-01

    We use graphene bubbles to study the Raman spectrum of graphene under biaxial (e.g., isotropic) strain. Our Gruneisen parameters are in excellent agreement with the theoretical values. Discrepancy in the previously reported values is attributed to the interaction of graphene with the substrate. Bilayer balloons (intentionally pressurized membranes) have been used to avoid the effect of the substrate and to study the dependence of strain on the interlayer interactions. PMID:22149458

  16. Experimental observation of surface states and Landau levels bending in bilayer graphene

    NASA Astrophysics Data System (ADS)

    Yin, Long-Jing; Zhang, Yu; Qiao, Jia-Bin; Li, Si-Yu; He, Lin

    2016-03-01

    We report on microscopic measurements of the low-energy electronic structures both at the zigzag and armchair edges of bilayer graphene using scanning tunneling microscopy and spectroscopy (STM and STS). We have found that, both in the absence and in the presence of a magnetic field, an almost zero-energy peak in the density of states was localized at the zigzag edges, as expected for the surface states at the zigzag edges of bilayer graphene. In the quantum Hall regime, we have clearly observed Landau levels bending away from the charge neutrality point near both the zigzag and armchair edges. Such a result is direct evidence for the evolution of Landau levels into quantum Hall edge states in graphene bilayers. Our experiment indicates that it is possible to explore rich quantum Hall physics in graphene systems using STM and STS.

  17. Effects of alloying 30 at. % Ni using a Cu catalyst on the growth of bilayer graphene

    NASA Astrophysics Data System (ADS)

    Lee, Wan-Gyu; Kim, Eunho; Jung, Jongwan

    2012-12-01

    A small percentage graphene bilayer where the first layer was fully covered with a graphene sheet was grown on alloy foils via an inductively coupled plasma-chemical vapor deposition chamber. Compared with Cu foils, the alloy foils led to faster growth of the graphene film, while maintaining the same quality, homogeneity, and thickness uniformity over the whole area synthesized as the growth characteristics of a monolayer graphene grown on Cu. Moreover, the combined catalyst had a graphene film simultaneously grown with a metallic compound of magnesium silicate in some regions and of 200 nm Cu2.4S in other regions. Nevertheless, graphene was grown continuously and highly homogenously over the entire large area synthesized without boundaries between regions. Thus the resulting graphene growth is affected primarily by the Cu catalyst and partly by the Ni and that the quality of the graphene is dependent on the Cu catalyst.

  18. Quantum multicriticality in bilayer graphene with a tunable energy gap

    NASA Astrophysics Data System (ADS)

    Throckmorton, Robert E.; Das Sarma, S.

    2014-11-01

    We develop a theory for quantum phases and quantum multicriticality in bilayer graphene in the presence of an explicit energy gap in the noninteracting spectrum by extending previous renormalization group (RG) analyses of electron-electron interactions in gapless bilayer graphene at finite temperature to include the effect of an electric field applied perpendicular to the sample, which produces an energy gap in the single-particle electron-hole dispersion. We determine the possible outcomes of the resulting RG equations, represented by "fixed rays" along which ratios of the coupling constants remain constant and map out the leading instabilities of the system for an interaction of the form of a Coulomb interaction that is screened by two parallel conducting plates placed equidistant from the electron. We find that some of the fixed rays on the "target plane" found in the zero-field case are no longer valid fixed rays, but that all four of the isolated rays are still valid. We also find five additional fixed rays that are not present in the zero-field case. We then construct maps of the leading instability (or instabilities) of the system for the screened Coulomb-like interaction as a function of the overall interaction strength and interaction range for four values of the applied electric field. We find that the pattern of leading instabilities is the same as that found in the zero-field case, namely, that the system is unstable to a layer antiferromagnetic state for short-ranged interactions, to a nematic state for long-ranged interactions, and to both for intermediate-ranged interactions. However, if the interaction becomes too long ranged or too weak, then the system will exhibit no instabilities. The ranges at which the nematic instability first appears, the antiferromagnetic instability disappears, and the nematic instability disappears all decrease with increasing applied electric field. Our main qualitative finding, that the applied electric field opposes

  19. Controllable poly-crystalline bilayered and multilayered graphene film growth by reciprocal chemical vapor deposition.

    PubMed

    Wu, Qinke; Jung, Seong Jun; Jang, Sung Kyu; Lee, Joohyun; Jeon, Insu; Suh, Hwansoo; Kim, Yong Ho; Lee, Young Hee; Lee, Sungjoo; Song, Young Jae

    2015-06-21

    We report the selective growth of large-area bilayered graphene film and multilayered graphene film on copper. This growth was achieved by introducing a reciprocal chemical vapor deposition (CVD) process that took advantage of an intermediate h-BN layer as a sacrificial template for graphene growth. A thin h-BN film, initially grown on the copper substrate using CVD methods, was locally etched away during the subsequent graphene growth under residual H2 and CH4 gas flows. Etching of the h-BN layer formed a channel that permitted the growth of additional graphene adlayers below the existing graphene layer. Bilayered graphene typically covers an entire Cu foil with domain sizes of 10-50 μm, whereas multilayered graphene can be epitaxially grown to form islands a few hundreds of microns in size. This new mechanism, in which graphene growth proceeded simultaneously with h-BN etching, suggests a potential approach to control graphene layers for engineering the band structures of large-area graphene for electronic device applications. PMID:26006180

  20. Two-photon absorption in gapped bilayer graphene with a tunable chemical potential.

    PubMed

    Brinkley, M K; Abergel, D S L; Clader, B D

    2016-09-14

    Despite the now vast body of two-dimensional materials under study, bilayer graphene remains unique in two ways: it hosts a simultaneously tunable band gap and electron density; and stems from simple fabrication methods. These two advantages underscore why bilayer graphene is critical as a material for optoelectronic applications. In the work that follows, we calculate the one- and two-photon absorption coefficients for degenerate interband absorption in a graphene bilayer hosting an asymmetry gap and adjustable chemical potential-all at finite temperature. Our analysis is comprehensive, characterizing one- and two-photon absorptive behavior over wide ranges of photon energy, gap, chemical potential, and thermal broadening. The two-photon absorption coefficient for bilayer graphene displays a rich structure as a function of photon energy and band gap due to the existence of multiple absorption pathways and the nontrivial dispersion of the low energy bands. This systematic work will prove integral to the design of bilayer-graphene-based nonlinear optical devices. PMID:27392275

  1. Two-photon absorption in gapped bilayer graphene with a tunable chemical potential

    NASA Astrophysics Data System (ADS)

    Brinkley, M. K.; Abergel, D. S. L.; Clader, B. D.

    2016-09-01

    Despite the now vast body of two-dimensional materials under study, bilayer graphene remains unique in two ways: it hosts a simultaneously tunable band gap and electron density; and stems from simple fabrication methods. These two advantages underscore why bilayer graphene is critical as a material for optoelectronic applications. In the work that follows, we calculate the one- and two-photon absorption coefficients for degenerate interband absorption in a graphene bilayer hosting an asymmetry gap and adjustable chemical potential—all at finite temperature. Our analysis is comprehensive, characterizing one- and two-photon absorptive behavior over wide ranges of photon energy, gap, chemical potential, and thermal broadening. The two-photon absorption coefficient for bilayer graphene displays a rich structure as a function of photon energy and band gap due to the existence of multiple absorption pathways and the nontrivial dispersion of the low energy bands. This systematic work will prove integral to the design of bilayer-graphene-based nonlinear optical devices.

  2. Coexisting massive and massless Dirac fermions in symmetry-broken bilayer graphene.

    PubMed

    Kim, Keun Su; Walter, Andrew L; Moreschini, Luca; Seyller, Thomas; Horn, Karsten; Rotenberg, Eli; Bostwick, Aaron

    2013-10-01

    Charge carriers in bilayer graphene are widely believed to be massive Dirac fermions that have a bandgap tunable by a transverse electric field. However, a full transport gap, despite its importance for device applications, has not been clearly observed in gated bilayer graphene, a long-standing puzzle. Moreover, the low-energy electronic structure of bilayer graphene is widely held to be unstable towards symmetry breaking either by structural distortions, such as twist, strain, or electronic interactions that can lead to various ground states. Which effect dominates the physics at low energies is hotly debated. Here we show both by direct band-structure measurements and by calculations that a native imperfection of bilayer graphene, a distribution of twists whose size is as small as ~0.1°, is sufficient to generate a completely new electronic spectrum consisting of massive and massless Dirac fermions. The massless spectrum is robust against strong electric fields, and has a unusual topology in momentum space consisting of closed arcs having an exotic chiral pseudospin texture, which can be tuned by varying the charge density. The discovery of this unusual Dirac spectrum not only complements the framework of massive Dirac fermions, widely relevant to charge transport in bilayer graphene, but also supports the possibility of valley Hall transport. PMID:23892785

  3. Graphene Monoxide Bilayer As a High-Performance on/off Switching Media for Nanoelectronics.

    PubMed

    Woo, Jungwook; Yun, Kyung-Han; Chung, Yong-Chae

    2016-04-27

    The geometries and electronic characteristics of the graphene monoxide (GMO) bilayer are predicted via density functional theory (DFT) calculations. All the possible sequences of the GMO bilayer show the typical interlayer bonding characteristics of two-dimensional bilayer systems with a weak van der Waals interaction. The band gap energies of the GMO bilayers are predicted to be adequate for electronic device application, indicating slightly smaller energy gaps (0.418-0.448 eV) compared to the energy gap of the monolayer (0.536 eV). Above all, in light of the band gap engineering, the band gap of the GMO bilayer responds to the external electric field sensitively. As a result, a semiconductor-metal transition occurs at a small critical electric field (EC = 0.22-0.30 V/Å). It is therefore confirmed that the GMO bilayer is a strong candidate for nanoelectronics. PMID:27046262

  4. Incremental oxidation of the surface of monolayer and bilayer graphene: A computational study

    NASA Astrophysics Data System (ADS)

    Lawson, Daniel B.; Beregszaszy, Erich J.

    2015-04-01

    We report the binding energies for a monolayer and bilayer graphene sheet coated with up to 24 oxygen atoms added sequentially to one surface of a monolayer and bilayer. Our graphene/graphite system consists of an arrangement of 3×5 phenyl rings or 48 carbon atoms in the monolayer and 96 carbon atoms in the bilayer. Geometries were energy optimized using the RM1 semiempirical method employing Periodic Boundary Conditions (PBC) followed by single point PBE and HSE06, all with the 6-31g* basis and PBC. Results indicate that the first O atom bound to pure graphene has a binding energy 2.16 eV on the monolayer and 2.14 eV on the bilayer. As O atoms are added the binding energy increases to 2.61 eV when the surface coverage on the monolayer reaches 45.8% or 11 O atoms on the unit cell, and for the bilayer this maximum occurs with 45.8% coverage or 11 O atoms on the top of the bilayer. The binding energy then gradually declines to 2.41 eV for the monolayer and to 1.93 eV for the bilayer with 100% coverage or 24 O atoms covering the top of the surface. Oxygen atoms added in close proximity to one another have a greater binding energy than O atoms added with larger separations relative to the unit cell. The difference in O binding energy between the monolayer system and the bilayer system is on average 0.02 eV less for the bilayer, the second, and as the number of O atoms are increased, the binding energy between the graphene layers falls to zero after 45.8% coverage or with 11 O atoms.

  5. The possibility of superconductivity in twisted bilayer graphene

    SciTech Connect

    Manaf, Muhamad Nasruddin Santoso, Iman Hermanto, Arief

    2015-09-30

    We discuss the possibility of superconductivity in Twisted Bilayer Graphene (TBG). In this study we use TBG model with commensurate rotation θ=1.16° in which the van-Hove singularities (VHS) arise at 6 meV from the Fermi level. We use BCS standard formula that include Density of States (DOS) to calculate the critical temperature (T{sub C}). Based on our calculation we predict that superconductivity will not arise in Pristine TBG because pairing potential has infinity value. In this situation, Dirac Fermions do not interact with each other since they do not form the bound states. Superconductvity may arise when the Fermi level is shifted towards the VHS. Based on this calculation, we predict that T{sub C} has value between 0.04 K and 0.12 K. The low value of T{sub C} is due to highly energetic of in plane phonon vibration which reduce the effective electron-phonon coupling. We conclude that doped TBG is candidate for Dirac Fermion superconductor.

  6. The possibility of superconductivity in twisted bilayer graphene

    NASA Astrophysics Data System (ADS)

    Manaf, Muhamad Nasruddin; Santoso, Iman; Hermanto, Arief

    2015-09-01

    We discuss the possibility of superconductivity in Twisted Bilayer Graphene (TBG). In this study we use TBG model with commensurate rotation θ=1.16° in which the van-Hove singularities (VHS) arise at 6 meV from the Fermi level. We use BCS standard formula that include Density of States (DOS) to calculate the critical temperature (TC). Based on our calculation we predict that superconductivity will not arise in Pristine TBG because pairing potential has infinity value. In this situation, Dirac Fermions do not interact with each other since they do not form the bound states. Superconductvity may arise when the Fermi level is shifted towards the VHS. Based on this calculation, we predict that TC has value between 0.04 K and 0.12 K. The low value of TC is due to highly energetic of in plane phonon vibration which reduce the effective electron-phonon coupling. We conclude that doped TBG is candidate for Dirac Fermion superconductor.

  7. Study of the optical phonons on gated twisted bilayer graphene

    NASA Astrophysics Data System (ADS)

    Chung, Ting Fung; He, Rui; Wu, Tai-Lung; Chen, Yong P.

    2015-03-01

    In twisted bilayer graphene (tBLG), the low-energy van-Hove singularities (vHs) in the density of states (DOS) can be continuously tuned by twisting the two layers, leading to distinct electronic and optical properties compared to Bernal-stacked BLG (AB-BLG). This effect has been explored using resonance Raman scattering, showing enhanced Raman G and ZO' (low frequency, layer breathing vibration) bands when the vHs energy resonates with excitation laser energy. We have studied the influence on vHs and Raman bands in gated tBLG devices (at resonant twist angle ~13° under a 532 nm laser light). We observed that the G band splits with increasing doping, attributed to asymmetric doping of charge carriers in the two layers. The strongly quenched G band intensity at high doping level is ascribed to the suppression of resonant interband transitions between the two saddle points (in conduction and valence bands) which are displaced in the momentum space by gate-tuning. We have also measured the doping dependence of ZO' band and R band in tBLG. Our results demonstrate that electric-field can be used to tune the optoelectronic and vibrational properties in tBLG devices.

  8. Quantum multicriticality in bilayer graphene with a tunable energy gap

    NASA Astrophysics Data System (ADS)

    Throckmorton, Robert

    2015-03-01

    We extend previous renormalization group (RG) analyses of electron-electron interactions in gapless bilayer graphene at finite temperature to include the effect of an electric field applied perpendicular to the sample. We determine the possible outcomes of the resulting RG equations, represented by ``fixed rays'' along which ratios of the coupling constants remain constant and map out the leading instabilities of the system for an interaction of the form of a Coulomb interaction that is screened by two parallel conducting plates placed equidistant from the electron. We then construct maps of the leading instability (or instabilities) of the system for the screened Coulomb-like interaction as a function of the overall interaction strength and interaction range for four values of the applied electric field. We find that the pattern of leading instabilities is the same as that found in the zero-field case, namely that the system is unstable to a layer antiferromagnetic state for short-ranged interactions, to a nematic state for long-ranged interactions, and to both for intermediate-ranged interactions. However, if the interaction becomes too long-ranged or too weak, then the system will exhibit no instabilities. Supported by LPS-CMTC and ARO-MURI.

  9. Doping efficiency of single and randomly stacked bilayer graphene by iodine adsorption

    SciTech Connect

    Kim, HoKwon; Renault, Olivier; Rouchon, Denis; Mariolle, Denis; Chevalier, Nicolas; Tyurnina, Anastasia; Simonato, Jean-Pierre; Dijon, Jean

    2014-07-07

    We report on the efficiency and thermal stability of p-doping by iodine on single and randomly stacked, weakly coupled bilayer polycrystalline graphene, as directly measured by photoelectron emission microscopy. The doping results in work function value increase of 0.4–0.5 eV, with a higher degree of iodine uptake by the bilayer (2%) as compared to the single layer (1%) suggesting iodine intercalation in the bilayer. The chemistry of iodine is identified accordingly as I{sub 3}{sup −} and I{sub 5}{sup −} poly iodide anionic complexes with slightly higher concentration of I{sub 5}{sup −} in bilayer than monolayer graphene, likely attributed to differences in doping mechanisms. Temperature dependent in-situ annealing of the doped films demonstrated that the doping remains efficient up to 200 °C.

  10. Bound and free self-interstitial defects in graphite and bilayer graphene: A computational study

    SciTech Connect

    Gulans, Andris; Puska, Martti J.; Nieminen, Risto M.

    2011-07-01

    The role of self-interstitials in the response of layered carbon materials such as graphite, bilayer graphene and multiwalled carbon nanotubes to irradiation has long remained a puzzle. Using density-functional-theory methods with an exchange and correlation functional which takes into account the interlayer van der Waals interaction in these systems without any material-specific empirical parameters, we study the energetics and migration of single- and di-interstitials in graphite and bilayer graphene. We show that two classes of interstitials, ''bound'' and ''free,'' can coexist. The latter are mobile at room and lower temperatures, which explains the experimental data and reconciles them with the results of atomistic simulations. Our results shed light on the behavior of graphite and carbon nanotubes under irradiation and have implications for irradiation-mediated processing of bilayer graphene.

  11. Electronic band gaps and transport properties in periodically alternating mono- and bi-layer graphene superlattices

    NASA Astrophysics Data System (ADS)

    Fan, Xiong; Huang, Wenjun; Ma, Tianxing; Wang, Li-Gang; Lin, Hai-Qing

    2015-12-01

    We investigate the electronic band structure and transport properties of periodically alternating mono- and bi-layer graphene superlattices (MBLG SLs). In such MBLG SLs, there exists a zero-averaged wave vector (zero-\\overline{k} ) gap that is insensitive to the lattice constant. This zero-\\overline{k} gap can be controlled by changing both the ratio of the potential widths and the interlayer coupling coefficient of the bilayer graphene. We also show that there exist extra Dirac points; the conditions for these extra Dirac points are presented analytically. Lastly, we demonstrate that the electronic transport properties and the energy gap of the first two bands in MBLG SLs are tunable through adjustment of the interlayer coupling and the width ratio of the periodic mono- and bi-layer graphene.

  12. Electronic band gaps and transport properties in periodically alternating mono- and bi-layer graphene superlattices

    NASA Astrophysics Data System (ADS)

    Fan, Xiong; Huang, Wenjun; Ma, Tianxing; Wang, Li-Gang; Lin, Hai-Qing

    We investigated electronic band structure and transport properties of periodically alternating mono- and bi-layer graphene superlattices (MBLG SLs). In such MBLG SLs, there exists the zero-averaged wave vector (zero- k) gap, which is insensitive to the lattice constant, and this zero- k gap can be controlled via changing both the ratio of potentials' widths and the interlayer coupling coefficient of bilayer graphene. It is also found that there exist the extra Dirac points and their conditions are analytically presented. Lastly, it shows that the electronic transport properties and the energy gap (Eg) of the first two bands in MBLG SLs are tunable by the interlayer coupling and the widths' ratio of the periodic mono- and bi-layer graphene.

  13. Electronic Structure of Bilayer Graphene Nanoribbon and Its Device Application: A Computational Study

    NASA Astrophysics Data System (ADS)

    Lam, Kai-Tak; Liang, Gengchiau

    Two-dimensional monolayer graphene has the unique electrical and physical properties which can be exploited in new device structures. However, its application in field-effect device structure is limited due to its semi-metal nature. Therefore, a lot of research efforts have been focussed on introducing an energy bandgap in the electronic structure. For example, a commonly studied method involves cutting two-dimensional graphene into one-dimensional narrow ribbons (graphene nanoribbons), where the spatial quantum confinement introduced by the physical edges generates an energy bandgap that is closely related to the width and edge configurations of the ribbon. Similarly for a bilayer graphene, an energy bandgap can also be obtained like the monolayer graphene nanoribbons, and be further controlled by varying its interlayer distance. In this chapter, a review of the electronic structure of monolayer graphene nanoribbon is presented and the study on the bilayer counterpart is subsequently discussed. Furthermore, based on the electrical properties of the bilayer graphene nanoribbon, the device performance of the Schottky barrier diode is investigated. Lastly, a nanoelectromechanical (NEM) switch based on the floating gate design is presented and discussed.

  14. Nonlinear optical conductivity of bilayer graphene with Rashba spin-orbit interaction in the terahertz regime

    SciTech Connect

    Liu, Zheng; Cao, J. C.; Sanderson, Matthew; Zhang, Chao

    2015-07-28

    The effect of Rashba spin-orbit coupling on the nonlinear optical conductivity in a bilayer graphene is investigated. We demonstrate the very different role played by the Rashba term and interlayer hopping; in some cases, the two roles can be quite opposite. It is found that the Rashba term can either enhance or suppress the nonlinear effect in a bilayer graphene, depending on the strength of the interlayer hopping. For a weak interlayer hopping, the Rashba term can significantly enhance the nonlinear effect. An analytical result was derived, showing the interplay of the Rashba effect and the interlayer hopping effect.

  15. Phase boundary of spin-polarized-current state of electrons in bilayer graphene

    NASA Astrophysics Data System (ADS)

    Yan, Xin-Zhong; Ma, Yinfeng; Ting, C. S.

    2016-06-01

    Using a four-band Hamiltonian, we study the phase boundary of spin-polarized-current state (SPCS) of interacting electrons in bilayer graphene. The model of spin-polarized-current state has previously been shown to resolve a number of experimental puzzles in bilayer graphene. The phase boundaries of the SPCS with and without the external voltage between the two layers are obtained in this work. An unusual phase boundary where there are two transition temperatures for a given carrier concentration is found at finite external voltage. The physics of this phenomenon is explained.

  16. Effect of strain on the electronic transport properties of mono- and bilayer graphene

    NASA Astrophysics Data System (ADS)

    Guan, Fen; Du, Xu

    It has been theoretically proposed that strain can have a significant impact on the electronic and charge transport properties of mono- and bilayer graphene. Experimental study of such ''strain engineering'' in field effect devices has been limited, mainly due to the challenge in creating an effective tuning knob of strain. Here we report the fabrication and characterization of suspended graphene field effect transistor (FET) on a Polyimide substrate, where uniaxial strain is applied by bending the substrate. Magnetotransport measurement of both mono- and bilayer graphene FETs are carried out with variable strain, from compressive to tensile, over wide range of temperature (4.2-300K). The impact of the strain on the conductivity of graphene will be discussed and compared to the theoretical predictions on strain-induced gauge field and flexural phonon scatterings.

  17. Dual doped monolayer and bilayer graphene: The case of 4p and 2p elements

    NASA Astrophysics Data System (ADS)

    Denis, Pablo A.; Iribarne, Federico

    2016-08-01

    4p/2p dual-doped monolayer and bilayer graphene were studied via first principle calculations. Generally, dopants prefer to be agglomerated. A second dopant significantly reduces formation energies. Thus, partially reduced graphene oxide would favor substitutional doping by facilitating the introduction of the 4p dopants. Dual-doping can tune the band gap from 0.1 to 0.8 eV. For bilayer graphene, large atomic radii elements (Gallium and Germanium) form interlayer bonds with the undoped sheet. For some dual-doped graphenes, interlayer GaC and GeC bonds were formed, increasing the chemical reactivity of the undoped layer and affecting its electronic structure, with metallic or semiconducting characters observed.

  18. Analysis of ballistic monolayer and bilayer graphene field-effect transistors

    NASA Astrophysics Data System (ADS)

    Ouyang, Yijian; Campbell, Paul; Guo, Jing

    2008-02-01

    We examine and compare ballistic performance limits of metal-oxide-semiconductor field-effect transistors with monolayer and bilayer graphene channels. Under low source-drain biases and cryogenic temperatures, the leakage current of the bilayer device is orders of magnitude smaller than that of the monolayer device. The advantage lowers at raised temperatures and source-drain biases. The bilayer device, however, still has qualitatively different and more favorable I-V characteristics. We find the ballistic on-state channel conductance and the minimum channel conductance have distinctly different dependences on the channel length.

  19. Raman spectra of bilayer graphene covered with Poly(methyl methacrylate) thin film

    SciTech Connect

    Xia Minggang; Su Zhidan; Zhang Shengli

    2012-09-15

    The Raman spectra of bilayer graphene covered with poly(methyl methacrylate) (PMMA) were investigated. Both the G and 2D peaks of PMMA-coated graphene were stiff and broad compared with those of uncovered graphene. This could be attributed to the residual strain induced by high-temperature baking during fabrication of the nanodevice. Furthermore, the two 2D peaks stiffened and broadened with increasing laser power, which is just the reverse to uncovered graphene. The stiffness is likely caused by graphene compression induced by the circular bubble of the thin PMMA film generated by laser irradiation. Our findings may contribute to the application of PMMA in the strain engineering of graphene nanodevices.

  20. Oxygen-Activated Growth and Bandgap Tunability of Large Single-Crystal Bilayer Graphene

    NASA Astrophysics Data System (ADS)

    Hao, Yufeng; Hone, James; Ruoff, Rodney; Colombo, Luigi; the Hone group Team

    Distinct from zero-bandgap single-layer graphene, Bernal-stacked bilayer graphene (BLG) is a semiconductor whose bandgap can be tuned by a transverse electric field, making it a unique material for a number of electronic and photonic devices. In this presentation, we will focus on the most recent progress in the identification of new growth mechanisms towards large-area single-layer BLG on Copper: multiple control experiments and first-principles calculations are used to support the proposed mechanisms. We emphasize that trace amount of impurities on metal surface are critical to initiate graphene growth and affect the growth kinetics. Furthermore, contrary to the traditional viewpoint that graphene growth is always surface-limited process, our new observations strongly suggest that metal bulk plays a role to feed carbon species for graphene growth. State-of-the-art structural characterizations and electrical transport measurements of the CVD graphene layers will be presented as well.

  1. Electronic band structure effects in monolayer, bilayer, and hybrid graphene structures

    NASA Astrophysics Data System (ADS)

    Puls, Conor

    Since its discovery in 2005, graphene has been the focus of intense theoretical and experimental study owing to its unique two-dimensional band structure and related electronic properties. In this thesis, we explore the electronic properties of graphene structures from several perspectives including the magnetoelectrical transport properties of monolayer graphene, gap engineering and measurements in bilayer graphene, and anomalous quantum oscillation in the monolayer-bilayer graphene hybrids. We also explored the device implications of our findings, and the application of some experimental techniques developed for the graphene work to the study of a complex oxide, Ca3Ru2O7, exhibiting properties of strongly correlated electrons. Graphene's high mobility and ballistic transport over device length scales, make it suitable for numerous applications. However, two big challenges remain in the way: maintaining high mobility in fabricated devices, and engineering a band gap to make graphene compatible with logical electronics and various optical devices. We address the first challenge by experimentally evaluating mobilities in scalable monolayer graphene-based field effect transistors (FETs) and dielectric-covered Hall bars. We find that the mobility is limited in these devices, and is roughly inversely proportional to doping. By considering interaction of graphene's Dirac fermions with local charged impurities at the interface between graphene and the top-gate dielectric, we find that Coulomb scattering is responsible for degraded mobility. Even in the cleanest devices, a band gap is still desirable for electronic applications of graphene. We address this challenge by probing the band structure of bilayer graphene, in which a field-tunable energy band gap has been theoretically proposed. We use planar tunneling spectroscopy of exfoliated bilayer graphene flakes demonstrate both measurement and control of the energy band gap. We find that both the Fermi level and

  2. Preparation and electrical transport properties of quasi free standing bilayer graphene on SiC (0001) substrate by H intercalation

    SciTech Connect

    Yu, Cui; Liu, Qingbin; Li, Jia; Lu, Weili; He, Zezhao; Cai, Shujun; Feng, Zhihong

    2014-11-03

    We investigate the temperature dependent electrical transport properties of quasi-free standing bilayer graphene on 4H-SiC (0001) substrate. Three groups of monolayer epitaxial graphene and corresponding quasi-free standing bilayer graphene with different crystal quality and layer number homogeneity are prepared. Raman spectroscopy and atomic-force microscopy are used to obtain their morphologies and layer number, and verify the complete translation of buffer layer into graphene. The highest room temperature mobility reaches 3700 cm{sup 2}/V·s for the quasi-free standing graphene. The scattering mechanism analysis shows that poor crystal quality and layer number inhomogeneity introduce stronger interacting of SiC substrate to the graphene layer and more impurities, which limit the carrier mobility of the quasi-free standing bilayer graphene samples.

  3. Controlling the Formation of Phospholipid Monolayer, Bilayer, and Intact Vesicle Layer on Graphene.

    PubMed

    Tabaei, Seyed R; Ng, Wei Beng; Cho, Sang-Joon; Cho, Nam-Joon

    2016-05-11

    Exciting progress has been made in the use of graphene for bio- and chemical sensing applications. In this regard, interfacing lipid membranes with graphene provides a high-sealing interface that is resistant to nonspecific protein adsorption and suitable for measuring biomembrane-associated interactions. However, a controllable method to form well-defined lipid bilayer coatings remains elusive, and there are varying results in the literature. Herein, we demonstrate how design strategies based on molecular self-assembly and surface chemistry can be employed to coat graphene surface with different classes of lipid membrane architectures. We characterize the self-assembly of lipid membranes on CVD-graphene using quartz crystal microbalance with dissipation, field-effect transistor, and Raman spectroscopy. By employing the solvent-assisted lipid bilayer (SALB) method, a lipid monolayer and bilayer were formed on pristine and oxygen-plasma-treated CVD-graphene, respectively. On these surfaces, vesicle fusion method resulted in formation of a lipid monolayer and intact vesicle layer, respectively. Collectively, these findings provide the basis for improved surface functionalization strategies on graphene toward bioelectronic applications. PMID:27092949

  4. Soliton-dependent plasmon reflection at bilayer graphene domain walls.

    PubMed

    Jiang, Lili; Shi, Zhiwen; Zeng, Bo; Wang, Sheng; Kang, Ji-Hun; Joshi, Trinity; Jin, Chenhao; Ju, Long; Kim, Jonghwan; Lyu, Tairu; Shen, Yuen-Ron; Crommie, Michael; Gao, Hong-Jun; Wang, Feng

    2016-08-01

    Layer-stacking domain walls in bilayer graphene are emerging as a fascinating one-dimensional system that features stacking solitons structurally and quantum valley Hall boundary states electronically. The interactions between electrons in the 2D graphene domains and the one-dimensional domain-wall solitons can lead to further new quantum phenomena. Domain-wall solitons of varied local structures exist along different crystallographic orientations, which can exhibit distinct electrical, mechanical and optical properties. Here we report soliton-dependent 2D graphene plasmon reflection at different 1D domain-wall solitons in bilayer graphene using near-field infrared nanoscopy. We observe various domain-wall structures in mechanically exfoliated graphene bilayers, including network-forming triangular lattices, individual straight or bent lines, and even closed circles. The near-field infrared contrast of domain-wall solitons arises from plasmon reflection at domain walls, and exhibits markedly different behaviours at the tensile- and shear-type domain-wall solitons. In addition, the plasmon reflection at domain walls exhibits a peculiar dependence on electrostatic gating. Our study demonstrates the unusual and tunable coupling between 2D graphene plasmons and domain-wall solitons. PMID:27240109

  5. Coupled Dirac fermions and neutrino-like oscillations in twisted bilayer graphene.

    PubMed

    Xian, Lede; Wang, Z F; Chou, M Y

    2013-11-13

    The low-energy quasiparticles in graphene can be described by a Dirac-Weyl Hamiltonian for massless fermions, hence graphene has been proposed to be an effective medium to study exotic phenomena originally predicted for relativistic particle physics, such as Klein tunneling and Zitterbewegung. In this work, we show that another important particle-physics phenomenon, the neutrino oscillation, can be studied and observed in a particular graphene system, namely, twisted bilayer graphene. It has been found that graphene layers grown epitaxially on SiC or by the chemical vapor deposition method on metal substrates display a stacking pattern with adjacent layers rotated by an angle with respect to each other. The quasiparticle states in two distinct graphene layers act as neutrinos with two flavors, and the interlayer interaction between them induces an appreciable coupling between these two "flavors" of massless fermions, leading to neutrino-like oscillations. In addition, our calculation shows that anisotropic transport properties manifest in a specific energy window, which is accessible experimentally in twisted bilayer graphene. Combining two graphene layers enables us to probe the rich physics involving multiple interacting Dirac fermions. PMID:24079848

  6. Large-signal model of the bilayer graphene field-effect transistor targeting radio-frequency applications: Theory versus experiment

    NASA Astrophysics Data System (ADS)

    Pasadas, Francisco; Jiménez, David

    2015-12-01

    Bilayer graphene is a promising material for radio-frequency transistors because its energy gap might result in a better current saturation than the monolayer graphene. Because the great deal of interest in this technology, especially for flexible radio-frequency applications, gaining control of it requires the formulation of appropriate models for the drain current, charge, and capacitance. In this work, we have developed them for a dual-gated bilayer graphene field-effect transistor. A drift-diffusion mechanism for the carrier transport has been considered coupled with an appropriate field-effect model taking into account the electronic properties of the bilayer graphene. Extrinsic resistances have been included considering the formation of a Schottky barrier at the metal-bilayer graphene interface. The proposed model has been benchmarked against experimental prototype transistors, discussing the main figures of merit targeting radio-frequency applications.

  7. Large-signal model of the bilayer graphene field-effect transistor targeting radio-frequency applications: Theory versus experiment

    SciTech Connect

    Pasadas, Francisco Jiménez, David

    2015-12-28

    Bilayer graphene is a promising material for radio-frequency transistors because its energy gap might result in a better current saturation than the monolayer graphene. Because the great deal of interest in this technology, especially for flexible radio-frequency applications, gaining control of it requires the formulation of appropriate models for the drain current, charge, and capacitance. In this work, we have developed them for a dual-gated bilayer graphene field-effect transistor. A drift-diffusion mechanism for the carrier transport has been considered coupled with an appropriate field-effect model taking into account the electronic properties of the bilayer graphene. Extrinsic resistances have been included considering the formation of a Schottky barrier at the metal-bilayer graphene interface. The proposed model has been benchmarked against experimental prototype transistors, discussing the main figures of merit targeting radio-frequency applications.

  8. Basal-plane dislocations in bilayer graphene - Peculiarities in a quasi-2D material

    NASA Astrophysics Data System (ADS)

    Butz, Benjamin

    2015-03-01

    Dislocations represent one of the most fascinating and fundamental concepts in materials science. First and foremost, they are the main carriers of plastic deformation in crystalline materials. Furthermore, they can strongly alter the local electronic or optical properties of semiconductors and ionic crystals. In layered crystals like graphite dislocation movement is restricted to the basal plane. Thus, those basal-plane dislocations cannot escape enabling their confinement in between only two atomic layers of the material. So-called bilayer graphene is the thinnest imaginable quasi-2D crystal to explore the nature and behavior of dislocations under such extreme boundary conditions. Robust graphene membranes derived from epitaxial graphene on SiC provide an ideal platform for their investigation. The presentation will give an insight in the direct observation of basal-plane partial dislocations by transmission electron microscopy and their detailed investigation by diffraction contrast analysis and atomistic simulations. The investigation reveals striking size effects. First, the absence of stacking fault energy, a unique property of bilayer graphene, leads to a characteristic dislocation pattern, which corresponds to an alternating AB <--> BA change of the stacking order. Most importantly, our experiments in combination with atomistic simulations reveal a pronounced buckling of the bilayer graphene membrane, which directly results from accommodation of strain. In fact, the buckling completely changes the strain state of the bilayer graphene and is of key importance for its electronic/spin transport properties. Due to the high degree of disorder in our quasi-2D material it is one of the very few examples for a perfect linear magnetoresistance, i.e. the linear dependency of the in-plane electrical resistance on a magnetic field applied perpendicular to the graphene sheet up to field strengths of more than 60 T. This research is financed by the German Research

  9. Synthesis of quasi-free-standing bilayer graphene nanoribbons on SiC surfaces

    NASA Astrophysics Data System (ADS)

    Oliveira, Myriano H., Jr.; Lopes, Joao Marcelo J.; Schumann, Timo; Galves, Lauren A.; Ramsteiner, Manfred; Berlin, Katja; Trampert, Achim; Riechert, Henning

    2015-07-01

    Scaling graphene down to nanoribbons is a promising route for the implementation of this material into devices. Quantum confinement of charge carriers in such nanostructures, combined with the electric field-induced break of symmetry in AB-stacked bilayer graphene, leads to a band gap wider than that obtained solely by this symmetry breaking. Consequently, the possibility of fabricating AB-stacked bilayer graphene nanoribbons with high precision is very attractive for the purposes of applied and basic science. Here we show a method, which includes a straightforward air annealing, for the preparation of quasi-free-standing AB-bilayer nanoribbons with different widths on SiC(0001). Furthermore, the experiments reveal that the degree of disorder at the edges increases with the width, indicating that the narrower nanoribbons are more ordered in their edge termination. In general, the reported approach is a viable route towards the large-scale fabrication of bilayer graphene nanostructures with tailored dimensions and properties for specific applications.

  10. Energy spectrum and Landau levels in bilayer graphene with spin-orbit interaction

    NASA Astrophysics Data System (ADS)

    Mireles, Francisco; Schliemann, John

    2012-09-01

    We present a theoretical study of the band structure and Landau levels in bilayer graphene at low energies in the presence of a transverse magnetic field and Rashba spin-orbit interaction in the regime of negligible trigonal distortion. Within an effective low-energy approach the (Löwdin partitioning theory), we derive an effective Hamiltonian for bilayer graphene that incorporates the influence of the Zeeman effect, the Rashba spin-orbit interaction and, inclusively, the role of the intrinsic spin-orbit interaction on the same footing. Particular attention is paid to the energy spectrum and Landau levels. Our modeling unveils the strong influence of the Rashba coupling λR in the spin splitting of the electron and hole bands. Graphene bilayers with weak Rashba spin-orbit interaction show a spin splitting linear in momentum and proportional to λR, but scaling inversely proportional to the interlayer hopping energy γ1. However, at robust spin-orbit coupling λR, the energy spectrum shows a strong warping behavior near the Dirac points. We find that the bias-induced gap in bilayer graphene decreases with increasing Rashba coupling, a behavior resembling a topological insulator transition. We further predict an unexpected asymmetric spin splitting and crossings of the Landau levels due to the interplay between the Rashba interaction and the external bias voltage. Our results are of relevance for interpreting magnetotransport and infrared cyclotron resonance measurements, including situations of comparatively weak spin-orbit coupling.

  11. Wavevector filtering through single-layer and bilayer graphene with magnetic barrier structures

    NASA Astrophysics Data System (ADS)

    Masir, M. Ramezani; Vasilopoulos, P.; Peeters, F. M.

    2008-12-01

    We show that the angular range of the transmission through magnetic barrier structures can be efficiently controlled in single-layer and bilayer graphenes and this renders the structure's efficient wavevector filters. As the number of magnetic barriers increases, this range shrinks, the gaps in the transmission versus energy become wider, and the conductance oscillates with the Fermi energy.

  12. Determination of the electronic structure of bilayer graphene from infrared spectroscopy results

    SciTech Connect

    Zhang, L. M.; Li, Z. Q.; Basov, D. N.; Fogler, M. M.; Hao, Z.; Martin, Michael C.

    2008-11-12

    We present an experimental study of the infrared conductivity, transmission, and reflection of a gated bilayer graphene and their theoretical analysis within the Slonczewski-Weiss-McClure (SWMc) model. The infrared response is shown to be governed by the interplay of the interband and the intraband transitions among the four bands of the bilayer. The position of the main conductivity peak at thecharge-neutrality point is determined by the interlayer tunneling frequency. The shift of this peak as a function of the gate voltage gives information about less known parameters of the SWMc model such as those responsible for the electron-hole and sublattice asymmetries. These parameter values are shown to be consistent with recent electronic structure calculations for the bilayer graphene and the SWMc parameters commonly used for the bulk graphite.

  13. Asymptotic discontinuities in the RKKY interaction in the graphene Bernal bilayer

    NASA Astrophysics Data System (ADS)

    Klier, N.; Shallcross, S.; Pankratov, O.

    2014-12-01

    We derive the asymptotics of the Ruderman-Kittel-Kasuya-Yosida (RKKY) interaction between magnetic impurities in the graphene Bernal bilayer using a four-band model of the bilayer spectrum. We find three distinct regimes depending on the position of the Fermi energy in the bilayer spectrum: in the bonding-antibonding gap, at the gap edge, and outside the gap. In particular, for impurities on the bilayer bonding sublattice (the "A " sublattice) and Fermi energies close to the bonding-antibonding gap edge Eg, we identify a (integrable) logarithmic divergence of the integrand of the RKKY exchange integral. This divergence drives a number of novel RKKY effects for impurities on the A sublattice: (i) an asymptotic R-5 /2 term at the gap edge and (ii) a derivative discontinuity in RKKY interaction as a function of the Fermi energy at the gap edge. In the case of intercalated impurities (impurities between the two layers of the bilayer), we find a remarkable discontinuity in the period of the RKKY oscillation at the gap edge. The period of the oscillation limits to λ =√{2 }π ℏ vF/t⊥ as EF→Eg from below the gap edge, while it limits to λ →∞ if EF→Eg from above the gap edge (t⊥ is the interlayer coupling, vF the Fermi velocity of graphene). The origin of this discontinuity we attribute to (i) the A sublattice divergence and (ii) interference effects driven by the intrinsic valley degree of freedom of graphene. On this basis, we predict that the magnetic response of intercalated bilayer graphene will show a profound sensitivity to doping for Fermi energies near the bonding-antibonding gap edge.

  14. Structure and electronic properties of bilayer graphene functionalized with half-sandwiched transition metal-cyclopentadienyl complexes.

    PubMed

    Yao, Xiaojing; Zhang, Xiuyun; Ye, Xiaoshan; Wang, Jinlan

    2016-08-10

    Tuning the electronic and magnetic properties of graphene is a crucial problem in the design of practical on-off electronic devices. Using density functional theory calculations, we explore the electronic and magnetic properties of bilayer graphene functionalized by cyclopentadienyl (Cp = cyclopentadienyl, C5H5) based half-sandwich ligands, CpTM (TM = Sc-Ni). It is found that the adsorption of CpTM ligands can introduce high magnetic moments and open the band gap of bilayer graphene, due to the electron doping as well as the asymmetric charge distribution between two graphene layers. Furthermore, the p-n doping of bilayer graphene by co-binding F/NO2 and CpTM on two external sides of BLG can further widen the band gap up to 366.1 meV. This study proposes an effective way to the modulation of the electronic and magnetic properties of graphene. PMID:27464257

  15. Angle-Dependent van Hove Singularities in a Slightly Twisted Graphene Bilayer

    NASA Astrophysics Data System (ADS)

    Yan, Wei; Liu, Mengxi; Dou, Rui-Fen; Meng, Lan; Feng, Lei; Chu, Zhao-Dong; Zhang, Yanfeng; Liu, Zhongfan; Nie, Jia-Cai; He, Lin

    2012-09-01

    Recent studies show that two low-energy van Hove singularities (VHSs) seen as two pronounced peaks in the density of states could be induced in a twisted graphene bilayer. Here, we report angle-dependent VHSs of a slightly twisted graphene bilayer studied by scanning tunneling microscopy and spectroscopy. We show that energy difference of the two VHSs follows ΔEvhs˜ℏνFΔK between 1.0° and 3.0° [here νF˜1.1×106m/s is the Fermi velocity of monolayer graphene, and ΔK=2Ksin⁡(θ/2) is the shift between the corresponding Dirac points of the twisted graphene bilayer]. This result indicates that the rotation angle between graphene sheets does not result in a significant reduction of the Fermi velocity, which quite differs from that predicted by band structure calculations. However, around a twisted angle θ˜1.3°, the observed ΔEvhs˜0.11eV is much smaller than the expected value ℏνFΔK˜0.28eV at 1.3°. The origin of the reduction of ΔEvhs at 1.3° is discussed.

  16. Magnetism of Adatom on Bilayer Graphene and its Control: A First-principles Perspective

    NASA Astrophysics Data System (ADS)

    Saha-Dasgupta, Tanusri; Nafday, Dhani

    2014-03-01

    We present first-principles investigation of the electronic and magnetic properties of adatom on bilayer graphene within the framework of density functional theory. In particular, we study the influence of an applied gate-voltage which modifies the electronic states of the bilayer graphene as well as shifts the adatom energy states relative to that of the graphene energy states. Our study carried out for a choice of three different adatoms, Na, Cu and Fe, shows that the nature of adatom-graphene bonding evolves from ionic to covalent, in moving from alkali metal, Na to transition metal, Cu or Fe. This leads to the formation of magnetic moments in the latter cases (Cu, Fe) and its absence in the former (Na). Application of an external electric field to bilayer graphene, completely changes the scenario, switching on a magnetic moment for Na adatom, and switching off the magnetic moments for Cu, and Fe adatoms. Our results have important implications for fundamental studies of controlled adatom magnetism and spintronics application in nanotechnology. The authors thank Ministry of Earth Science and Department of Science and Technology, India for financial support.

  17. Spatially resolving unconventional interface Landau quantization in a graphene monolayer-bilayer planar junction

    NASA Astrophysics Data System (ADS)

    Yan, Wei; Li, Si-Yu; Yin, Long-Jing; Qiao, Jia-Bin; Nie, Jia-Cai; He, Lin

    2016-05-01

    Hybrid quantum Hall (QH) junctions have been extensively studied by transport measurements due to their exciting physics and device applications. Here we report on spatially resolving electronic properties of such a junction on the nanoscale. We present a subnanometer-resolved scanning tunneling microscopy (STM) and scanning tunneling spectroscopy study of a monolayer-bilayer graphene planar junction in the QH regime. The atomically well-defined interface of such a junction allows us to spatially resolve the interface electronic properties. Around the interface, we detect Landau quantization of massless Dirac fermions as expected in the graphene monolayer for filled states of the junction, whereas unexpectedly, only Landau quantization of massive Dirac fermions as expected in the graphene bilayer is observed for empty states. The observed unconventional interface Landau quantization arises from the fact that the quantum conductance across the interface is solely determined by the minimum filling factors (number of edge modes) in the graphene monolayer and bilayer regions of the junction. Our finding opens the way to spatially explore the QH effect of different graphene hybrid structures only using a STM.

  18. Uniformity of large-area bilayer graphene grown by chemical vapor deposition

    NASA Astrophysics Data System (ADS)

    Sheng, Yuewen; Rong, Youmin; He, Zhengyu; Fan, Ye; Warner, Jamie H.

    2015-10-01

    Graphene grown by chemical vapor deposition (CVD) on copper foils is a viable method for large area films for transparent conducting electrode (TCE) applications. We examine the spatial uniformity of large area films on the centimeter scale when transferred onto both Si substrates with 300 nm oxide and flexible transparent polyethylene terephthalate substrates. A difference in the quality of graphene, as measured by the sheet resistance and transparency, is found for the areas at the edges of large sheets that depends on the supporting boat used for the CVD growth. Bilayer graphene is grown with uniform properties on the centimeter scale when a flat support is used for CVD growth. The flat support provides consistent delivery of precursor to the copper catalyst for graphene growth. These results provide important insights into the upscaling of CVD methods for growing high quality graphene and its transfer onto flexible substrates for potential applications as a TCE.

  19. Selectively enhanced photocurrent generation in twisted bilayer graphene with van Hove singularity.

    PubMed

    Yin, Jianbo; Wang, Huan; Peng, Han; Tan, Zhenjun; Liao, Lei; Lin, Li; Sun, Xiao; Koh, Ai Leen; Chen, Yulin; Peng, Hailin; Liu, Zhongfan

    2016-01-01

    Graphene with ultra-high carrier mobility and ultra-short photoresponse time has shown remarkable potential in ultrafast photodetection. However, the broad and weak optical absorption (∼ 2.3%) of monolayer graphene hinders its practical application in photodetectors with high responsivity and selectivity. Here we demonstrate that twisted bilayer graphene, a stack of two graphene monolayers with an interlayer twist angle, exhibits a strong light-matter interaction and selectively enhanced photocurrent generation. Such enhancement is attributed to the emergence of unique twist-angle-dependent van Hove singularities, which are directly revealed by spatially resolved angle-resolved photoemission spectroscopy. When the energy interval between the van Hove singularities of the conduction and valance bands matches the energy of incident photons, the photocurrent generated can be significantly enhanced (up to ∼ 80 times with the integration of plasmonic structures in our devices). These results provide valuable insight for designing graphene photodetectors with enhanced sensitivity for variable wavelength. PMID:26948537

  20. Selectively enhanced photocurrent generation in twisted bilayer graphene with van Hove singularity

    PubMed Central

    Yin, Jianbo; Wang, Huan; Peng, Han; Tan, Zhenjun; Liao, Lei; Lin, Li; Sun, Xiao; Koh, Ai Leen; Chen, Yulin; Peng, Hailin; Liu, Zhongfan

    2016-01-01

    Graphene with ultra-high carrier mobility and ultra-short photoresponse time has shown remarkable potential in ultrafast photodetection. However, the broad and weak optical absorption (∼2.3%) of monolayer graphene hinders its practical application in photodetectors with high responsivity and selectivity. Here we demonstrate that twisted bilayer graphene, a stack of two graphene monolayers with an interlayer twist angle, exhibits a strong light–matter interaction and selectively enhanced photocurrent generation. Such enhancement is attributed to the emergence of unique twist-angle-dependent van Hove singularities, which are directly revealed by spatially resolved angle-resolved photoemission spectroscopy. When the energy interval between the van Hove singularities of the conduction and valance bands matches the energy of incident photons, the photocurrent generated can be significantly enhanced (up to ∼80 times with the integration of plasmonic structures in our devices). These results provide valuable insight for designing graphene photodetectors with enhanced sensitivity for variable wavelength. PMID:26948537

  1. The effect of spin-orbit coupling in band structure and edge states of bilayer graphene

    SciTech Connect

    Sahdan, Muhammad Fauzi; Darma, Yudi

    2015-04-16

    Topological insulators are predicted to be useful ranging from spintronics to quantum computation. Graphene was first predicted to be the precursor of topological insulator by Kane-Mele. They developed a Hamiltonian model to describe the gap opening in graphene. In this work, we investigate the band structure of bilayer grapheme and also its edge states by using this model with analytical approach. The results of our calculation show that the gap opening occurs at K and K’ point in bilayer graphene.In addition, a pair of gapless edge modes occurs both in the zigzag and arm-chair configurations are no longer exist. There are gap created at the edge even though thery are very small.

  2. Direct imaging of topological edge states at a bilayer graphene domain wall.

    PubMed

    Yin, Long-Jing; Jiang, Hua; Qiao, Jia-Bin; He, Lin

    2016-01-01

    The AB-BA domain wall in gapped graphene bilayers is a rare naked structure hosting topological electronic states. Although it has been extensively studied in theory, a direct imaging of its topological edge states is still missing. Here we image the topological edge states at the graphene bilayer domain wall by using scanning tunnelling microscope. The simultaneously obtained atomic-resolution images of the domain wall provide us unprecedented opportunities to measure the spatially varying edge states within it. The one-dimensional conducting channels are observed to be mainly located around the two edges of the domain wall, which is reproduced quite well by our theoretical calculations. Our experiment further demonstrates that the one-dimensional topological states are quite robust even in the presence of high magnetic fields. The result reported here may raise hopes of graphene-based electronics with ultra-low dissipation. PMID:27312315

  3. Direct imaging of topological edge states at a bilayer graphene domain wall

    NASA Astrophysics Data System (ADS)

    Yin, Long-Jing; Jiang, Hua; Qiao, Jia-Bin; He, Lin

    2016-06-01

    The AB-BA domain wall in gapped graphene bilayers is a rare naked structure hosting topological electronic states. Although it has been extensively studied in theory, a direct imaging of its topological edge states is still missing. Here we image the topological edge states at the graphene bilayer domain wall by using scanning tunnelling microscope. The simultaneously obtained atomic-resolution images of the domain wall provide us unprecedented opportunities to measure the spatially varying edge states within it. The one-dimensional conducting channels are observed to be mainly located around the two edges of the domain wall, which is reproduced quite well by our theoretical calculations. Our experiment further demonstrates that the one-dimensional topological states are quite robust even in the presence of high magnetic fields. The result reported here may raise hopes of graphene-based electronics with ultra-low dissipation.

  4. Theoretical study of electronic transport properties of a graphene-silicene bilayer

    SciTech Connect

    Berdiyorov, G. R.; Bahlouli, H.; Peeters, F. M.

    2015-06-14

    Electronic transport properties of a graphene-silicene bilayer system are studied using density-functional theory in combination with the nonequilibrium Green's function formalism. Depending on the energy of the electrons, the transmission can be larger in this system as compared to the sum of the transmissions of separated graphene and silicene monolayers. This effect is related to the increased electron density of states in the bilayer sample. At some energies, the electronic states become localized in one of the layers, resulting in the suppression of the electron transmission. The effect of an applied voltage on the transmission becomes more pronounced in the layered sample as compared to graphene due to the larger variation of the electrostatic potential profile. Our findings will be useful when creating hybrid nanoscale devices where enhanced transport properties will be desirable.

  5. Conductance and Fano factor in normal/ferromagnetic/normal bilayer graphene junction.

    PubMed

    Rashidian, Z; Mojarabian, F M; Bayati, P; Rashedi, G; Ueda, A; Yokoyama, T

    2014-06-25

    We theoretically investigate the transport properties of bilayer graphene junctions, where the ferromagnetic strips are attached to the middle region of the graphene sheet. In these junctions, we can control the band gap and the band structure of the bilayer graphene by using the bias voltage between the layers and the exchange field induced on the layers. The conductance and Fano factor (F ) are calculated by the Landauer–Büttiker formula. It is found that when the voltage between the layers or the exchange field are tuned, the pseudodiffusive (F = 1/3) transport turns into tunneling (F = 1) or ballistic transport (F = 0). By tuning the potential difference between the layers, one can control the spin polarization of the current. PMID:24891499

  6. Superconductivity of electron-hole pairs in a bilayer graphene system in a quantizing magnetic field

    NASA Astrophysics Data System (ADS)

    Fil', D. V.; Kravchenko, L. Yu.

    2009-08-01

    A state with spontaneous interlayer phase coherence in a bilayer quantum Hall system based on graphene is studied. This state can be regarded as a gas of superfluid electron-hole pairs whose components belong to different layers. A superfluid flow of such pairs is equivalent to two electric supercurrents in the layers. It is shown that in a graphene system a state with interlayer phase coherence arises if a definite unbalance of the filling factors of the Landau levels in neighboring layers is created. The temperature of the transition into a superfluid state, the maximum interlayer distance for which phase coherence is possible, and the critical values of the supercurrent are found. The advantages of using graphene systems instead of GaAs heterostructures to realize bilayer electron-hole superconductivity are discussed.

  7. Direct imaging of topological edge states at a bilayer graphene domain wall

    PubMed Central

    Yin, Long-Jing; Jiang, Hua; Qiao, Jia-Bin; He, Lin

    2016-01-01

    The AB–BA domain wall in gapped graphene bilayers is a rare naked structure hosting topological electronic states. Although it has been extensively studied in theory, a direct imaging of its topological edge states is still missing. Here we image the topological edge states at the graphene bilayer domain wall by using scanning tunnelling microscope. The simultaneously obtained atomic-resolution images of the domain wall provide us unprecedented opportunities to measure the spatially varying edge states within it. The one-dimensional conducting channels are observed to be mainly located around the two edges of the domain wall, which is reproduced quite well by our theoretical calculations. Our experiment further demonstrates that the one-dimensional topological states are quite robust even in the presence of high magnetic fields. The result reported here may raise hopes of graphene-based electronics with ultra-low dissipation. PMID:27312315

  8. Enhanced current-rectification in bilayer graphene with an electrically tuned sloped bandgap

    NASA Astrophysics Data System (ADS)

    Aparecido-Ferreira, Alex; Miyazaki, Hisao; Li, Song-Lin; Komatsu, Katsuyoshi; Nakaharai, Shu; Tsukagoshi, Kazuhito

    2012-11-01

    We propose a novel sloped dielectric geometry in graphene as a band engineering method for widening the depletion region and increasing the electrical rectification effect in graphene pn junctions. Enhanced current-rectification was achieved in a bilayer graphene with a sloped dielectric top gate and a normal back gate. A bias was applied to the top gate to induce a spatially modulated and sloped band configuration, while a back-gate bias was applied to open a bandgap. The sloped band can be tuned to separate n- and p-type regions in the bilayer graphene, depending on a suitable choice of gate voltage. The effective depletion region between the n- and p-type regions can be spatially enlarged due to the proposed top-gate structure. As a result, a strong non-linear electric current was observed during drain bias sweeping, demonstrating the expected rectification behavior with an on/off ratio higher than all previously reported values for graphene pn junctions. The observed rectification was modified to a linear current-voltage relationship by adjusting the biases of both gates to form an nn- or pp-type junction configuration. These results demonstrate that an external voltage can control the current flow in atomic film diodes.We propose a novel sloped dielectric geometry in graphene as a band engineering method for widening the depletion region and increasing the electrical rectification effect in graphene pn junctions. Enhanced current-rectification was achieved in a bilayer graphene with a sloped dielectric top gate and a normal back gate. A bias was applied to the top gate to induce a spatially modulated and sloped band configuration, while a back-gate bias was applied to open a bandgap. The sloped band can be tuned to separate n- and p-type regions in the bilayer graphene, depending on a suitable choice of gate voltage. The effective depletion region between the n- and p-type regions can be spatially enlarged due to the proposed top-gate structure. As a result, a

  9. Topological phase transition in hexagonal boron-nitride bilayers modulated by gate voltage

    NASA Astrophysics Data System (ADS)

    Jin, Guojun; Zhai, Xuechao

    2013-03-01

    We study the gate-voltage modulated electronic properties of hexagonal boron-nitride bilayers with two different stacking structures in the presence of intrinsic and Rashba spin-orbit interactions. Our analytical results show that there are striking cooperation effects arising from the spin-orbit interactions and the interlayer bias voltage. For realizing topological phase transition, in contrast to a gated graphene bilayer for increasing its energy gap, the energy gap of a boron-nitride bilayer is significantly reduced by an applied gate voltage. For the AA stacking-bilayer which has the inversion symmetry, a strong topological phase is found, and there is an interesting reentrant behavior from a normal phase to a topological phase and then to a normal phase again, characterized by the topological index. Therefore, the gate voltage modulated AA-boron nitride bilayer can be taken as a newcomer of the topological insulator family. For the AB stacking-bilayer which is lack of the inversion symmetry, it is always topologically trivial, but exhibits an unusual quantum Hall phase with four degenerate low-energy states localized at a single edge. It is suggested that these theoretical findings could be verified experimentally in the transport properties of boron-nitride bylayers. This research was supported by the NSFC (Nos. 60876065, 11074108), PAPD, and NBRPC (Nos. 2009CB929504, 2011CB922102).

  10. Chemically enhanced double-gate bilayer graphene field-effect transistor with neutral channel for logic applications.

    PubMed

    Nourbakhsh, Amirhasan; Agarwal, Tarun K; Klekachev, Alexander; Asselberghs, Inge; Cantoro, Mirco; Huyghebaert, Cedric; Heyns, Marc; Verhelst, Marian; Thean, Aaron; De Gendt, Stefan

    2014-08-29

    In this article, we present the simulation, fabrication, and characterization of a novel bilayer graphene field-effect transistor exhibiting electron mobility up to ~1600 cm(2) V(-1) s(-1), a room temperature I on/I off ≈ 60, and the lowest total charge (~10(11) cm(-2)) reported to date. This is achieved by combined electrostatic and chemical doping of bilayer graphene, which enables one to switch off the device at zero top-gate voltage. Using density functional theory and atomistic simulations, we obtain physical insight into the impact of chemical and electrostatic doping on bandgap opening of bilayer graphene and the effect of metal contacts on the operation of the device. Our results represent a step forward in the use of bilayer graphene for high-performance logic devices in the beyond-complementary metal-oxide-semiconductor (CMOS) technology paradigm. PMID:25101635

  11. Chemically enhanced double-gate bilayer graphene field-effect transistor with neutral channel for logic applications

    NASA Astrophysics Data System (ADS)

    Nourbakhsh, Amirhasan; Agarwal, Tarun K.; Klekachev, Alexander; Asselberghs, Inge; Cantoro, Mirco; Huyghebaert, Cedric; Heyns, Marc; Verhelst, Marian; Thean, Aaron; De Gendt, Stefan

    2014-08-01

    In this article, we present the simulation, fabrication, and characterization of a novel bilayer graphene field-effect transistor exhibiting electron mobility up to ˜1600 cm2 V-1 s-1, a room temperature I on/I off ≈ 60, and the lowest total charge (˜1011 cm-2) reported to date. This is achieved by combined electrostatic and chemical doping of bilayer graphene, which enables one to switch off the device at zero top-gate voltage. Using density functional theory and atomistic simulations, we obtain physical insight into the impact of chemical and electrostatic doping on bandgap opening of bilayer graphene and the effect of metal contacts on the operation of the device. Our results represent a step forward in the use of bilayer graphene for high-performance logic devices in the beyond-complementary metal-oxide-semiconductor (CMOS) technology paradigm.

  12. Experimental evidence for non-Abelian gauge potentials in twisted graphene bilayers

    NASA Astrophysics Data System (ADS)

    Yin, Long-Jing; Qiao, Jia-Bin; Zuo, Wei-Jie; Li, Wen-Tian; He, Lin

    2015-08-01

    Non-Abelian gauge potentials are quite relevant in subatomic physics, but they are relatively rare in a condensed matter context. Here we report the experimental evidence for non-Abelian gauge potentials in twisted graphene bilayers by scanning tunneling microscopy and spectroscopy. At a magic twisted angle, θ ≈(1.11±0.05 ) ∘ , a pronounced sharp peak, which arises from the nondispersive flat bands at the charge neutrality point, is observed in the tunneling density of states due to the action of the non-Abelian gauge fields. Moreover, we observe confined electronic states in the twisted bilayer, as manifested by regularly spaced tunneling peaks with energy spacing δ E ≈vF/D ≈70 meV (here vF is the Fermi velocity of graphene and D is the period of the moiré patterns). This indicates that the non-Abelian gauge potentials in twisted graphene bilayers confine low-energy electrons into a triangular array of quantum dots following the modulation of the moiré patterns. Our results also directly demonstrate that the Fermi velocity in twisted bilayers can be tuned from about 106m /s to zero by simply reducing the twisted angle of about 2∘.

  13. A Unified Description of the DC Conductivity of Monolayer and Bilayer Graphene Based on Resonant Scatterers

    NASA Astrophysics Data System (ADS)

    Ferreira, Aires; Viana-Gomes, J.; Nilsson, Johan; Mucciolo, Eduardo R.; Peres, Nuno M. R.; Castro Neto, Antonio H.

    2011-03-01

    We show that a coherent picture for the dc conductivity of monolayer and bilayer graphene emerges from considering that strong short-range potentials are the main source of scattering in these two systems. The origin of the strong short range potentials may lie in adsorbed hydrocarbons at the surface of graphene. The equivalence between results based on the partial wave description of scattering, the Lippmann-Schwinger equation, and the T-matrix approach is established. Scattering due to resonant impurities close to the neutrality point is investigated via a numerical computation of the Kubo formula using a kernel polynomial method. We find that realistic adsorbates originate impurity bands in monolayer and bilayer graphene close to the Dirac point. In the midgap region, a plateau of minimum conductivity of about e2 / h (per layer) is induced by the resonant disorder. In bilayer graphene, a large adsorbate concentration can develop an energy gap between midgap states and high energy states. As a consequence, the conductivity plateau is supressed near the edges and a ``conductivity gap'' takes place.

  14. Stacking order dependent mechanical properties of graphene/MoS{sub 2} bilayer and trilayer heterostructures

    SciTech Connect

    Elder, Robert M. E-mail: mahesh.neupane.ctr@mail.mil; Neupane, Mahesh R. E-mail: mahesh.neupane.ctr@mail.mil; Chantawansri, Tanya L.

    2015-08-17

    Transition metal dichalcogenides (TMDC) such as molybdenum disulfide (MoS{sub 2}) are two-dimensional materials that show promise for flexible electronics and piezoelectric applications, but their weak mechanical strength is a barrier to practical use. In this work, we perform nanoindentation simulations using atomistic molecular dynamics to study the mechanical properties of heterostructures formed by combining MoS{sub 2} with graphene. We consider both bi- and tri-layer heterostructures formed with MoS{sub 2} either supported or encapsulated by graphene. Mechanical properties, such as Young's modulus, bending modulus, ultimate tensile strength, and fracture strain, are extracted from nanoindentation simulations and compared to the monolayer and homogeneous bilayer systems. We observed that the heterostructures, regardless of the stacking order, are mechanically more robust than the mono- and bi-layer MoS{sub 2}, mainly due to the mechanical reinforcement provided by the graphene layer. The magnitudes of ultimate strength and fracture strain are similar for both the bi- and tri-layer heterostructures, but substantially larger than either the mono- and bi-layer MoS{sub 2}. Our results demonstrate the potential of graphene-based heterostructures to improve the mechanical properties of TMDC materials.

  15. Ca intercalated bilayer graphene as a thinnest limit of superconducting C6Ca

    PubMed Central

    Kanetani, Kohei; Sugawara, Katsuaki; Sato, Takafumi; Shimizu, Ryota; Iwaya, Katsuya; Hitosugi, Taro; Takahashi, Takashi

    2012-01-01

    Success in isolating a 2D graphene sheet from bulky graphite has triggered intensive studies of its physical properties as well as its application in devices. Graphite intercalation compounds (GICs) have provided a platform of exotic quantum phenomena such as superconductivity, but it is unclear whether such intercalation is feasible in the thinnest 2D limit (i.e., bilayer graphene). Here we report a unique experimental realization of 2D GIC, by fabricating calcium-intercalated bilayer graphene C6CaC6 on silicon carbide. We have investigated the structure and electronic states by scanning tunneling microscopy and angle-resolved photoemission spectroscopy. We observed a free-electron–like interlayer band at the Brillouin-zone center, which is thought to be responsible for the superconductivity in 3D GICs, in addition to a large π* Fermi surface at the zone boundary. The present success in fabricating Ca-intercalated bilayer graphene would open a promising route to search for other 2D superconductors as well as to explore its application in devices. PMID:23139407

  16. Switchable magnetic moment in cobalt-doped graphene bilayer on Cu(111): An ab initio study

    NASA Astrophysics Data System (ADS)

    Souza, Everson S.; Scopel, Wanderlã L.; Miwa, R. H.

    2016-06-01

    In this work, we have performed an ab initio theoretical investigation of substitutional cobalt atoms in the graphene bilayer supported on the Cu(111) surface (Co/GBL/Cu). Initially, we examined the separated systems, namely, graphene bilayer adsorbed on Cu(111) (GBL/Cu) and a free standing Co-doped GBL (Co/GBL). In the former system, the GBL becomes n -type doped, where we map the net electronic charge density distribution along the GBL-Cu(111) interface. The substitutional Co atom in Co/GBL lies between the graphene layers, and present a net magnetic moment mostly due to the unpaired Co-3 dz2 electrons. In Co/GBL/Cu, we found that the Cu(111) substrate rules (i) the energetic stability, and (ii) the magnetic properties of substitutional Co atoms in the graphene bilayer. In (i), the substitutional Co atom becomes energetically more stable lying on the GBL surface, and in (ii), the magnetic moment of Co/GBL has been quenched due to the Cu(111) → Co/GBL electronic charge transfer. We verify that such a charge transfer can be tuned upon the application of an external electric field, and thus mediated by a suitable change on the electronic occupation of the Co-dz2 orbitals, we found a way to switch-on and -off the magnetization of the Co-doped GBL adsorbed on the Cu(111) surface.

  17. Effect of radical fluorination on mono- and bi-layer graphene in Ar/F{sub 2} plasma

    SciTech Connect

    Tahara, K.; Iwasaki, T.; Hatano, M.; Matsutani, A.

    2012-10-15

    Fluorinated graphene has the possibility to achieve unique properties and functions in graphene. We propose a highly controlled fluorination method utilizing fluorine radicals in Ar/F{sub 2} plasma. To suppress ion bombardments and improve the reaction with fluorine radicals on graphene, the substrate was placed 'face down' in the plasma chamber. Although monolayer graphene was more reactive than bilayer, fluorination of bilayer reached the level of I{sub D}/I{sub G} {approx} 0.5 in Raman D peak intensity at 532 nm excitation. Annealing fluorinated samples proved reversibility of radical fluorination for both mono- and bi-layer graphenes. X-ray photoelectron spectroscopy showed the existence of carbon-fluorine bonding.

  18. Theoretical Study of All-Electrical Quantum Wire Valley Filters in Bilayer Graphene

    NASA Astrophysics Data System (ADS)

    Wu, Yu-Shu; Lue, Ning-Yuan; Chen, Yen-Chun; Jiang, Jia-Huei; Chou, Mei-Yin

    Graphene electrons carry valley pseudospin, due to the double valley degeneracy in graphene band structure. In gapped graphene, the pseudospin is coupled to an in-plane electric field, through the mechanism of valley-orbit interaction (VOI), Based on the VOI, a family of electrically-controlled valleytronic devices have been proposed. Here, we report the theoretical study of a recently proposed valley filter consisting of a Q1D channel in bilayer graphene defined and controlled by electrical gates. We discuss two types of calculations - those of energy subband structure in the channel and electron transmission through a valley valve consisting of two proposed filters. For the former, we have developed a tight binding formulation in the continuum limit. For the latter, we employ the recursive Green's function method. Results from the calculations will be presented. Financial support by MoST, Taiwan, ROC is acknowledged.

  19. Buckling failure of square ice-nanotube arrays constrained in graphene nanocapillaries.

    PubMed

    Zhu, YinBo; Wang, FengChao; Wu, HengAn

    2016-08-01

    Graphene confinement provides a new physical and mechanical environment with ultrahigh van der Waals pressure, resulting in new quasi-two-dimensional phases of few-layer ice. Polymorphic transition can occur in bilayer constrained water/ice system. Here, we perform a comprehensive study of the phase transition of AA-stacked bilayer water constrained within a graphene nanocapillary. The compression-limit and superheating-limit (phase) diagrams are obtained, based on the extensive molecular-dynamics simulations at numerous thermodynamic states. Liquid-to-solid, solid-to-solid, and solid-to-liquid-to-solid phase transitions are observed in the compression and superheating of bilayer water. Interestingly, there is a temperature threshold (∼275 K) in the compression-limit diagram, which indicates that the first-order and continuous-like phase transitions of bilayer water depend on the temperature. Two obviously different physical processes, compression and superheating, display similar structural evolution; that is, square ice-nanotube arrays (BL-VHDI) will bend first and then transform into bilayer triangular AA stacking ice (BL-AAI). The superheating limit of BL-VHDI exhibits local maxima, while that of BL-AAI increases monotonically. More importantly, from a mechanics point of view, we propose a novel mechanism of the transformation from BL-VHDI to BL-AAI, both for the compression and superheating limits. This structural transformation can be regarded as the "buckling failure" of the square-ice-nanotube columns, which is dominated by the lateral pressure. PMID:27497569

  20. Highly ordered growth of PTCDA on epitaxial bilayer graphene

    NASA Astrophysics Data System (ADS)

    Meissner, Matthias; Gruenewald, Marco; Sojka, Falko; Udhardt, Christian; Forker, Roman; Fritz, Torsten

    2012-11-01

    For using the unique electronic properties of graphene in future nanoelectronic devices, control of the band structure is essential. While it has been shown already in the literature that this can be achieved by the deposition of organic molecules, little attention has been paid so far to the precise structural characterization of the interface. Here, we report on the epitaxial growth of 3,4,9,10-perylenetetracarboxylic dianhydride (PTCDA) layers on graphene, epitaxially grown on silicon carbide (SiC). The description of low energy electron diffraction (LEED) patterns of graphene on SiC by multiscattering is revisited. By means of a home-made algorithm used to correct radial distortions of the LEED images we are able to provide precise structural data of the PTCDA layers. By that, two different point-on-line types of PTCDA could be identified, one of which has neither been reported on graphite nor on graphene before.

  1. Incorporating isolated molybdenum (Mo) atoms into Bilayer Epitaxial Graphene on 4H-SiC(0001)

    NASA Astrophysics Data System (ADS)

    Huang, Han; Wan, Wen; Li, Hui; Wong, Swee Liang; Lv, Lu; Gao, Yongli; Wee, Andrew T. S.

    2014-03-01

    The atomic structures and electronic properties of isolated Mo atoms in bilayer epitaxial graphene (BLEG) on 4H-SiC(0001) are investigated by low temperature scanning tunneling microscopy (LT-STM). LT-STM results reveal that isolated Mo dopants prefer to substitute C atoms at α-sites, and preferentially locate between the graphene bilayers. First-principles calculations confirm that the embedding of single Mo dopants within BLEG is energetically favorable as compared to monolayer graphene. The calculated bandstructures show that Mo-doped BLEG is n-doped, and each Mo atom introduces a local magnetic moment of 1.81 μB. Our findings demonstrate a simple and stable method to incorporate single transition metal dopants into the graphene lattice to tune its electronic and magnetic properties for possible use in graphene spin devices. NRF-CRP (Singapore) grants R-143-000-360-281and R-144-000-295-281. ``Shenghua Professorship'' startup funding from CSU and the support from the NSF of China (Grant No.11304398).

  2. Electron dynamics of the buffer layer and bilayer graphene on SiC

    SciTech Connect

    Shearer, Alex J.; Caplins, Benjamin W.; Suich, David E.; Harris, Charles B.; Johns, James E.; Hersam, Mark C.

    2014-06-09

    Angle- and time-resolved two-photon photoemission (TPPE) was used to investigate electronic states in the buffer layer of 4H-SiC(0001). An image potential state (IPS) series was observed on this strongly surface-bound buffer layer, and dispersion measurements indicated free-electron-like behavior for all states in this series. These results were compared with TPPE taken on bilayer graphene, which also show the existence of a free-electron-like IPS series. Lifetimes for the n = 2, and n = 3 states were obtained from time-resolved TPPE; slightly increased lifetimes were observed in the bilayer graphene sample for the n = 2 the n = 3 states. Despite the large band gap of graphene at the center of the Brillouin zone, the lifetime results demonstrate that the graphene layers do not behave as a simple tunneling barrier, suggesting that the buffer layer and graphene overlayers play a direct role in the decay of IPS electrons.

  3. Electronic properties of bilayer graphenes strongly coupled to interlayer stacking and an external field

    DOE PAGESBeta

    Park, Changwon; Ryou, Junga; Hong, Suklyun; Sumpter, Bobby G.; Kim, Gunn; Yoon, Mina

    2015-07-02

    Bilayer graphene (BLG) with a tunable band gap appears interesting as an alternative to graphene for practical applications; thus, its transport properties are being actively pursued. Using density functional theory and perturbation analysis, we investigated, under an external electric field, the electronic properties of BLG in various stackings relevant to recently observed complex structures. We established the first phase diagram summarizing the stacking-dependent gap openings of BLG for a given field. Lastly, we further identified high-density midgap states, localized on grain boundaries, even under a strong field, which can considerably reduce the overall transport gap.

  4. Theory of resonant tunneling in bilayer-graphene/hexagonal-boron-nitride heterostructures

    SciTech Connect

    Barrera, Sergio C. de la; Feenstra, Randall M.

    2015-03-02

    A theory is developed for calculating vertical tunneling current between two sheets of bilayer graphene separated by a thin, insulating layer of hexagonal boron nitride, neglecting many-body effects. Results are presented using physical parameters that enable comparison of the theory with recently reported experimental results. Observed resonant tunneling and negative differential resistance in the current–voltage characteristics are explained in terms of the electrostatically-induced band gap, gate voltage modulation, density of states near the band edge, and resonances with the upper sub-band. These observations are compared to ones from similar heterostructures formed with monolayer graphene.

  5. Valley filter from magneto-tunneling between single and bi-layer graphene

    SciTech Connect

    Pratley, L.; Zülicke, U.

    2014-02-24

    We consider tunneling transport between two parallel graphene sheets; where one is a single-layer sample and the other one a bi-layer. In the presence of an in-plane magnetic field, the interplay between combined energy and momentum conservation in a tunneling event and the distinctive chiral nature of charge carriers in the two systems turns out to favor tunneling of electrons from one of the two valleys in the graphene Brillouin zone. Adjusting the field strength enables manipulation of the valley polarization of the current, which reaches its maximum value of 100% concomitantly with a maximum of the tunneling conductance.

  6. A promising way to open an energy gap in bilayer graphene

    NASA Astrophysics Data System (ADS)

    Hao, Jialei; Huang, Chengxi; Wu, Haiping; Qiu, Yuhao; Gao, Qian; Hu, Zhenpeng; Kan, Erjun; Zhang, Lixin

    2015-10-01

    There has been huge research interest in the energy gap problem of monolayer and bilayer graphene due to their great potential in practical applications. Herein, based on first-principles calculations, we report a promising way to open a large band gap in bilayer graphene (BLG) by sandwiching it between two substrates, although this is not usually expected to occur due to the weak interlayer interactions dominated by van der Waals forces. Taking surface-functionalized boron-nitrides as substrates, we predict from first-principles calculations that BLG can have energy gaps ranging from 0.35 eV to 0.55 eV, depending on the substrates and stacking order. Compared to other methods of band-gap manipulation in BLG, the structural integrity of BLG is well-preserved in our study, and the predicted energy gap is suitable for electric devices. Since the proposed method is easily realized in experiments, our results will hopefully accelerate the application of graphene in semiconductor devices and promote the development of graphene technology.There has been huge research interest in the energy gap problem of monolayer and bilayer graphene due to their great potential in practical applications. Herein, based on first-principles calculations, we report a promising way to open a large band gap in bilayer graphene (BLG) by sandwiching it between two substrates, although this is not usually expected to occur due to the weak interlayer interactions dominated by van der Waals forces. Taking surface-functionalized boron-nitrides as substrates, we predict from first-principles calculations that BLG can have energy gaps ranging from 0.35 eV to 0.55 eV, depending on the substrates and stacking order. Compared to other methods of band-gap manipulation in BLG, the structural integrity of BLG is well-preserved in our study, and the predicted energy gap is suitable for electric devices. Since the proposed method is easily realized in experiments, our results will hopefully accelerate the

  7. Perfect Spin-filtering in graphene monolayer-bilayer superlattice with zigzag boundaries

    NASA Astrophysics Data System (ADS)

    Yu, Hang; Liu, Jun-Feng

    2016-05-01

    We show that the spontaneous magnetization is formed at the zigzag boundary between monolayer and bilayer graphene by the self-consistent calculation based on Hubbard model. In a monolayer- bilayer graphene superlattice with zigzag boundaries, it is surprising that nearly 100% spin polarization is achieved in the energy window around the Dirac point, no matter the magnetization configuration at two boundaries is parallel or antiparallel. The reason is that the low-energy transport is only influenced by the magnetization at one edge, but not by that at the other. The underlying physics is unveiled by the spin-split band structure and the distribution of the wave-function pertaining to the lowest (highest) subband of electron (hole).

  8. Perfect Spin-filtering in graphene monolayer-bilayer superlattice with zigzag boundaries.

    PubMed

    Yu, Hang; Liu, Jun-Feng

    2016-01-01

    We show that the spontaneous magnetization is formed at the zigzag boundary between monolayer and bilayer graphene by the self-consistent calculation based on Hubbard model. In a monolayer- bilayer graphene superlattice with zigzag boundaries, it is surprising that nearly 100% spin polarization is achieved in the energy window around the Dirac point, no matter the magnetization configuration at two boundaries is parallel or antiparallel. The reason is that the low-energy transport is only influenced by the magnetization at one edge, but not by that at the other. The underlying physics is unveiled by the spin-split band structure and the distribution of the wave-function pertaining to the lowest (highest) subband of electron (hole). PMID:27140666

  9. Fractal butterflies of chiral fermions in bilayer graphene: Phase transitions and emergent properties

    NASA Astrophysics Data System (ADS)

    Ghazaryan, Areg; Chakraborty, Tapash

    2015-12-01

    We have studied the influence of electron-electron interaction on the fractal butterfly spectrum of Dirac fermions in biased bilayer graphene in the fractional quantum Hall effect (FQHE) regime. We demonstrate that the butterfly spectrum exhibits remarkable phase transitions between the FQHE gap and the butterfly gap for chiral electrons in bilayer graphene, when the periodic potential strength or the bias voltage is varied. We also find that, in addition to those phase transitions, by varying the bias voltage one can effectively control the periodic potential strength experienced by the electrons. The electron-electron interaction causes the butterfly spectrum to exhibit new gaps inside the Bloch sub-bands not found in the single-particle case. We expect that both the observed phase transition and other new features in the butterfly spectrum of interacting Dirac fermions will be of great interest to researchers from diverse fields.

  10. Unipolar transport in bilayer graphene controlled by multiple p-n interfaces

    NASA Astrophysics Data System (ADS)

    Miyazaki, Hisao; Li, Song-Lin; Nakaharai, Shu; Tsukagoshi, Kazuhito

    2012-04-01

    Unipolar transport is demonstrated in a bilayer graphene with a series of p-n junctions and is controlled by electrostatic biasing by a comb-shaped top gate. The OFF state is induced by multiple barriers in the p-n junctions, where the band gap is generated by applying a perpendicular electric field to the bilayer graphene, and the ON state is induced by the p-p or n-n configurations of the junctions. As the number of the junction increases, current suppression in the OFF state is pronounced. The multiple p-n junctions also realize the saturation of the drain current under relatively high source-drain voltages.

  11. Energy Gaps and Layer Polarization of Integer and Fractional Quantum Hall States in Bilayer Graphene.

    PubMed

    Shi, Yanmeng; Lee, Yongjin; Che, Shi; Pi, Ziqi; Espiritu, Timothy; Stepanov, Petr; Smirnov, Dmitry; Lau, Chun Ning; Zhang, Fan

    2016-02-01

    Owing to the spin, valley, and orbital symmetries, the lowest Landau level in bilayer graphene exhibits multicomponent quantum Hall ferromagnetism. Using transport spectroscopy, we investigate the energy gaps of integer and fractional quantum Hall (QH) states in bilayer graphene with controlled layer polarization. The state at filling factor ν=1 has two distinct phases: a layer polarized state that has a larger energy gap and is stabilized by high electric field, and a hitherto unobserved interlayer coherent state with a smaller gap that is stabilized by large magnetic field. In contrast, the ν=2/3 quantum Hall state and a feature at ν=1/2 are only resolved at finite electric field and large magnetic field. These results underscore the importance of controlling layer polarization in understanding the competing symmetries in the unusual QH system of BLG. PMID:26894724

  12. Conductivity and scattering in graphene bilayers: Numerically exact results versus Boltzmann approach

    NASA Astrophysics Data System (ADS)

    Xu, Hengyi; Heinzel, T.; Zozoulenko, I. V.

    2011-09-01

    We derive analytical expressions for the conductivity of bilayer graphene (BLG) using the Boltzmann approach within the the Born approximation for a model of Gaussian disorders describing both short- and long-range impurity scattering. The range of validity of the Born approximation is established by comparing the analytical results to exact tight-binding numerical calculations. A comparison of the obtained density dependencies of the conductivity with experimental data shows that the BLG samples investigated experimentally so far are in the quantum scattering regime where the Fermi wavelength exceeds the effective impurity range. In this regime both short- and long-range scattering lead to the same linear density dependence of the conductivity. Our calculations imply that bilayer and single-layer graphene have the same scattering mechanisms. We also provide an upper limit for the effective, density-dependent spatial extension of the scatterers present in the experiments.

  13. Perfect Spin-filtering in graphene monolayer-bilayer superlattice with zigzag boundaries

    PubMed Central

    Yu, Hang; Liu, Jun-Feng

    2016-01-01

    We show that the spontaneous magnetization is formed at the zigzag boundary between monolayer and bilayer graphene by the self-consistent calculation based on Hubbard model. In a monolayer- bilayer graphene superlattice with zigzag boundaries, it is surprising that nearly 100% spin polarization is achieved in the energy window around the Dirac point, no matter the magnetization configuration at two boundaries is parallel or antiparallel. The reason is that the low-energy transport is only influenced by the magnetization at one edge, but not by that at the other. The underlying physics is unveiled by the spin-split band structure and the distribution of the wave-function pertaining to the lowest (highest) subband of electron (hole). PMID:27140666

  14. Raman spectroscopy measurement of bilayer graphene's twist angle to boron nitride

    SciTech Connect

    Cheng, Bin; Wang, Peng; Pan, Cheng; Miao, Tengfei; Wu, Yong; Lau, C. N.; Bockrath, M.; Taniguchi, T.; Watanabe, K.

    2015-07-20

    When graphene is placed on hexagonal boron nitride with a twist angle, new properties develop due to the resulting moiré superlattice. Here, we report a method using Raman spectroscopy to make rapid, non-destructive measurements of the twist angle between bilayer graphene and hexagonal boron nitride. The lattice orientation is determined by using flakes with both bilayer and monolayer regions, and using the known Raman signature for the monolayer to measure the twist angle of the entire flake. The widths of the second order Raman peaks are found to vary linearly in the superlattice period and are used to determine the twist angle. The results are confirmed by using transport measurements to infer the superlattice period by the charge density required to reach the secondary resistance peaks. Small twist angles are also found to produce a significant modification of the first order Raman G band peak.

  15. High temperature characteristics of bilayer epitaxial graphene field-effect transistors on SiC Substrate

    NASA Astrophysics Data System (ADS)

    Ze-Zhao, He; Ke-Wu, Yang; Cui, Yu; Qing-Bin, Liu; Jing-Jing, Wang; Jia, Li; Wei-Li, Lu; Zhi-Hong, Feng; Shu-Jun, Cai

    2016-06-01

    In this paper, high temperature direct current (DC) performance of bilayer epitaxial graphene device on SiC substrate is studied in a temperature range from 25 °C to 200 °C. At a gate voltage of ‑8 V (far from Dirac point), the drain-source current decreases obviously with increasing temperature, but it has little change at a gate bias of +8 V (near Dirac point). The competing interactions between scattering and thermal activation are responsible for the different reduction tendencies. Four different kinds of scatterings are taken into account to qualitatively analyze the carrier mobility under different temperatures. The devices exhibit almost unchanged DC performances after high temperature measurements at 200 °C for 5 hours in air ambience, demonstrating the high thermal stabilities of the bilayer epitaxial graphene devices. Project supported by the National Natural Science Foundation of China (Grant No. 61306006).

  16. Simultaneous investigation of magnetoresistance (MR) and twisted angle of twisted bilayer graphene

    NASA Astrophysics Data System (ADS)

    Hong, Sung Ju; Manzo, Julio; Kim, Kyung Ho; Park, Min; Baek, Seung Jae; Kholin, Dmitry; Lee, Min Woo; Choi, Eun Sang; Jeong, Dae Hong; Yurgens, August; Drndic, Maria; Johnson, Alan; Park, Yung Woo

    2013-03-01

    We have measured magnetoresistance (MR) and twisted angle of twisted bilayer graphene, simultaneously. Twisted angle was measured by transmission electron microscopy (TEM) diffraction experiment on SiNx substrate. We performed Raman spectroscopy experiment and observed enhanced G mode which results from double resonance scattering process near van Hove singularity (vHs). MR shows superposition of two Shubnikov de Haas (SdH) oscillations and is analyzed by Landau fan diagram.

  17. AB-stacked square-like bilayer ice in graphene nanocapillaries.

    PubMed

    Zhu, YinBo; Wang, FengChao; Bai, Jaeil; Zeng, Xiao Cheng; Wu, HengAn

    2016-08-10

    Water, when constrained between two graphene sheets and under ultrahigh pressure, can manifest dramatic differences from its bulk counterparts such as the van der Waals pressure induced water-to-ice transformation, known as the metastability limit of two-dimensional (2D) liquid. Here, we present result of a new crystalline structure of bilayer ice with the AB-stacking order, observed from molecular dynamics simulations of constrained water. This AB-stacked bilayer ice (BL-ABI) is transformed from the puckered monolayer square-like ice (pMSI) under higher lateral pressure in the graphene nanocapillary at ambient temperature. BL-ABI is a proton-ordered ice with square-like pattern. The transition from pMSI to BL-ABI is through crystal-to-amorphous-to-crystal pathway with notable hysteresis-loop in the potential energy during the compression/decompression process, reflecting the compression/tensile limit of the 2D monolayer/bilayer ice. In a superheating process, the BL-ABI transforms into the AB-stacked bilayer amorphous ice with the square-like pattern. PMID:27468430

  18. Gap state analysis in electric-field-induced band gap for bilayer graphene.

    PubMed

    Kanayama, Kaoru; Nagashio, Kosuke

    2015-01-01

    The origin of the low current on/off ratio at room temperature in dual-gated bilayer graphene field-effect transistors is considered to be the variable range hopping in gap states. However, the quantitative estimation of gap states has not been conducted. Here, we report the systematic estimation of the energy gap by both quantum capacitance and transport measurements and the density of states for gap states by the conductance method. An energy gap of ~ 250 meV is obtained at the maximum displacement field of ~ 3.1 V/nm, where the current on/off ratio of ~ 3 × 10(3) is demonstrated at 20 K. The density of states for the gap states are in the range from the latter half of 10(12) to 10(13) eV(-1) cm(-2). Although the large amount of gap states at the interface of high-k oxide/bilayer graphene limits the current on/off ratio at present, our results suggest that the reduction of gap states below ~ 10(11) eV(-1) cm(-2) by continual improvement of the gate stack makes bilayer graphene a promising candidate for future nanoelectronic device applications. PMID:26511395

  19. Giant Faraday rotation induced by the Berry phase in bilayer graphene under strong terahertz fields

    NASA Astrophysics Data System (ADS)

    Yang, Fan; Xu, Xiaodong; Liu, Ren-Bao

    2014-04-01

    High-order terahertz (THz) sideband generation in semiconductors is a phenomenon with physics similar to that of high-order harmonic generation but in a regime of much lower frequency. Our previous paper [1] found that the electron-hole pair excited by a weak optical laser can accumulate a Berry phase along a cyclic trajectory under the driving of a strong elliptically polarized THz field. Furthermore, the Berry phase appears as the Faraday rotation angle of the emission signal under short-pulse excitation in monolayer MoS_{2}. In this paper, the theory of the Berry phase in THz extreme nonlinear optics is applied to biased bilayer graphene with Bernal stacking, which has similar Bloch band features and optical properties to monolayer MoS_{2}, such as the time-reversal related valleys and the valley contrasting optical selection rule. However, the biased bilayer graphene has much larger Berry curvature than monolayer MoS_{2}, which leads to a large Berry phase of the quantum trajectory and in turn a giant Faraday rotation of the optical emission (˜1 rad for a THz field with frequency 1 THz and strength 8 kV cm-1). This surprisingly big angle shows that the Faraday rotation can be induced more efficiently by the Berry curvature in momentum space than by the magnetic field in real space. It provides opportunities to use bilayer graphene and THz lasers for ultrafast electro-optical devices.

  20. Transport properties of monolayer and bilayer graphene supported by hexagonal boron nitride

    NASA Astrophysics Data System (ADS)

    Li, Jing; Zou, Ke; Seiwell, Donald; Zhu, Jun

    2013-03-01

    We present transport studies on hexagonal boron nitride (h-BN) supported monolayer and bilayer graphene. Following the method introduced by Dean et al, we first exfoliate thin sheets of h-BN (15-20 nm) to SiO2/Si substrate then align and transfer exfoliated graphene flakes onto the h-BN sheets. E-beam lithography is used to process the samples into Hall bar devices. We find that current annealing at low temperature can increase the mobility of as-fabricated devices but often introduces large density inhomogeneity at the same time. AFM images of annealed devices reveal the limitations of this technique. In comparison, thermal annealing is much more reliable in improving the sample quality. Bilayer devices annealed in a flow of Ar/H2 at 450C for 5 hours show high mobility of 30,000 cm2/Vs at low temperature. We observe high-quality Shubnikov-de Hass (SdH) oscillations and degeneracy-lifted Landau levels in these samples. We extend existing measurements of the electron and hole effective mass in bilayer graphene to lower carrier density regimes and discuss the implications of the results. Department of Applied Physics, Yale University

  1. Electron-hole asymmetric fractional quantum Hall effect in bilayer graphene

    NASA Astrophysics Data System (ADS)

    Feldman, Ben; Kou, Angela; Levin, Andrei; Halperin, Bertrand; Watanabe, Kenji; Taniguchi, Takashi; Yacoby, Amir

    2014-03-01

    At zero magnetic field, the electronic spectrum of bilayer graphene is electron-hole symmetric to first order. In a magnetic field, the lowest two orbital states occur at zero energy, and they combine with the spin and valley degrees of freedom to yield an eightfold degenerate lowest Landau level. Both external fields and electron-electron interactions can break these symmetries, leading to a uniquely rich and tunable phase diagram of many-body states. In this talk, I will present local electronic compressibility measurements of high quality bilayer graphene performed using a scanning single-electron transistor. We observe clear fractional quantum Hall states at filling factors ν = -10/3, -4/3, 2/3 and 8/3, with additional states appearing at ν = -17/5, -7/5, 3/5 and 13/5. Remarkably, this sequence breaks electron-hole symmetry and instead follows an even-odd pattern between integer quantum Hall states. Our results highlight the key role played by the orbital degree of freedom in the many-body physics of bilayer graphene.

  2. Anomalous sequence of quantum Hall liquids revealing a tunable Lifshitz transition in bilayer graphene.

    PubMed

    Varlet, Anastasia; Bischoff, Dominik; Simonet, Pauline; Watanabe, Kenji; Taniguchi, Takashi; Ihn, Thomas; Ensslin, Klaus; Mucha-Kruczyński, Marcin; Fal'ko, Vladimir I

    2014-09-12

    Bilayer graphene is a unique system where both the Fermi energy and the low-energy electron dispersion can be tuned. This is brought about by an interplay between trigonal warping and the band gap opened by a transverse electric field. Here, we drive the Lifshitz transition in bilayer graphene to experimentally controllable carrier densities by applying a large transverse electric field to a h-BN-encapsulated bilayer graphene structure. We perform magnetotransport measurements and investigate the different degeneracies in the Landau level spectrum. At low magnetic fields, the observation of filling factors -3 and -6 quantum Hall states reflects the existence of three maxima at the top of the valence-band dispersion. At high magnetic fields, all integer quantum Hall states are observed, indicating that deeper in the valence band the constant energy contours are singly connected. The fact that we observe ferromagnetic quantum Hall states at odd-integer filling factors testifies to the high quality of our sample. This enables us to identify several phase transitions between correlated quantum Hall states at intermediate magnetic fields, in agreement with the calculated evolution of the Landau level spectrum. The observed evolution of the degeneracies, therefore, reveals the presence of a Lifshitz transition in our system. PMID:25259994

  3. Gap state analysis in electric-field-induced band gap for bilayer graphene

    PubMed Central

    Kanayama, Kaoru; Nagashio, Kosuke

    2015-01-01

    The origin of the low current on/off ratio at room temperature in dual-gated bilayer graphene field-effect transistors is considered to be the variable range hopping in gap states. However, the quantitative estimation of gap states has not been conducted. Here, we report the systematic estimation of the energy gap by both quantum capacitance and transport measurements and the density of states for gap states by the conductance method. An energy gap of ~250 meV is obtained at the maximum displacement field of ~3.1 V/nm, where the current on/off ratio of ~3 × 103 is demonstrated at 20 K. The density of states for the gap states are in the range from the latter half of 1012 to 1013 eV−1cm−2. Although the large amount of gap states at the interface of high-k oxide/bilayer graphene limits the current on/off ratio at present, our results suggest that the reduction of gap states below ~1011 eV−1cm−2 by continual improvement of the gate stack makes bilayer graphene a promising candidate for future nanoelectronic device applications. PMID:26511395

  4. Existence of nontrivial topologically protected states at grain boundaries in bilayer graphene: signatures and electrical switching

    NASA Astrophysics Data System (ADS)

    Jaskólski, W.; Pelc, M.; Chico, Leonor; Ayuela, A.

    2016-03-01

    Recent experiments [L. Ju, et al., Nature, 2015, 520, 650] confirm the existence of gapless states at domain walls created in gated bilayer graphene, when the sublattice stacking is changed from AB to BA. These states are significant because they are topologically protected, valley-polarized and give rise to conductance along the domain wall. Current theoretical models predict the appearance of such states only at domain walls, which preserve the sublattice order. Here we show that the appearance of the topologically protected states in stacking domain walls can be much more common in bilayer graphene, since they can also emerge in unexpected geometries, e.g., at grain boundaries with atomic-scale topological defects. We focus on a bilayer system in which one of the layers contains a line of octagon-double pentagon defects that mix graphene sublattices. We demonstrate that gap states are preserved even with pentagonal defects. Remarkably, unlike previous predictions, the number of gap states changes by inverting the gate polarization, yielding an asymmetric conductance along the grain boundary under gate reversal. This effect, linked to defect states, should be detectable in transport measurements and could be exploited in electrical switches.

  5. Existence of nontrivial topologically protected states at grain boundaries in bilayer graphene: signatures and electrical switching.

    PubMed

    Jaskólski, W; Pelc, M; Chico, Leonor; Ayuela, A

    2016-03-21

    Recent experiments [L. Ju, et al., Nature, 2015, 520, 650] confirm the existence of gapless states at domain walls created in gated bilayer graphene, when the sublattice stacking is changed from AB to BA. These states are significant because they are topologically protected, valley-polarized and give rise to conductance along the domain wall. Current theoretical models predict the appearance of such states only at domain walls, which preserve the sublattice order. Here we show that the appearance of the topologically protected states in stacking domain walls can be much more common in bilayer graphene, since they can also emerge in unexpected geometries, e.g., at grain boundaries with atomic-scale topological defects. We focus on a bilayer system in which one of the layers contains a line of octagon-double pentagon defects that mix graphene sublattices. We demonstrate that gap states are preserved even with pentagonal defects. Remarkably, unlike previous predictions, the number of gap states changes by inverting the gate polarization, yielding an asymmetric conductance along the grain boundary under gate reversal. This effect, linked to defect states, should be detectable in transport measurements and could be exploited in electrical switches. PMID:26931739

  6. Gate-Tunable Superconductor-Insulator Transition in Bilayer-Graphene Josephson Junctions

    NASA Astrophysics Data System (ADS)

    Jeong, Dongchan; Lee, Gil-Ho; Doh, Yong-Joo; Lee, Hu-Jong

    2012-02-01

    Bilayer graphene shows opening of electric-field-induced band gap, the size of which is proportional to the intensity of the electric field. We report electronic transport measurements on superconducting proximity effect in planar dual-gated bilayer-graphene Josephson junction with Pb0.93In0.07 (PbIn) electrodes (δPbIn ˜ 1.1meV, Tc = 7.0 K). The junction resistance along the charge-neutral point (CNP) increases as we modulate top- and back-gate voltages away from the zero-gap CNP. The resistive state near the CNP shows a variable-range-hopping-type insulating behavior in R-T curve with lowering temperature crossing the superconducting transition of PbIn electrodes. However, a highly doped regime shows metallic R-T behavior and junction becomes superconducting below Tc. Moreover, magnetic-field-induced Fraunhofer supercurrent modulation, microwave-induced Shapiro steps, and multiple Andreev reflection (MAR) are observed, which indicate the formation of genuine Josephson coupling across the planar junctions below Tc with sufficiently transparent superconductor-bilayer graphene interface. The separatrix of the superconductor-insulator transition corresponds to the square junction conductance of Gsq˜ 6-8e^2/h.

  7. Anomalous Sequence of Quantum Hall Liquids Revealing a Tunable Lifshitz Transition in Bilayer Graphene

    NASA Astrophysics Data System (ADS)

    Varlet, Anastasia; Bischoff, Dominik; Simonet, Pauline; Watanabe, Kenji; Taniguchi, Takashi; Ihn, Thomas; Ensslin, Klaus; Mucha-Kruczyński, Marcin; Fal'ko, Vladimir I.

    2014-09-01

    Bilayer graphene is a unique system where both the Fermi energy and the low-energy electron dispersion can be tuned. This is brought about by an interplay between trigonal warping and the band gap opened by a transverse electric field. Here, we drive the Lifshitz transition in bilayer graphene to experimentally controllable carrier densities by applying a large transverse electric field to a h-BN-encapsulated bilayer graphene structure. We perform magnetotransport measurements and investigate the different degeneracies in the Landau level spectrum. At low magnetic fields, the observation of filling factors -3 and -6 quantum Hall states reflects the existence of three maxima at the top of the valence-band dispersion. At high magnetic fields, all integer quantum Hall states are observed, indicating that deeper in the valence band the constant energy contours are singly connected. The fact that we observe ferromagnetic quantum Hall states at odd-integer filling factors testifies to the high quality of our sample. This enables us to identify several phase transitions between correlated quantum Hall states at intermediate magnetic fields, in agreement with the calculated evolution of the Landau level spectrum. The observed evolution of the degeneracies, therefore, reveals the presence of a Lifshitz transition in our system.

  8. Bilayer insulator tunnel barriers for graphene-based vertical hot-electron transistors.

    PubMed

    Vaziri, S; Belete, M; Dentoni Litta, E; Smith, A D; Lupina, G; Lemme, M C; Östling, M

    2015-08-14

    Vertical graphene-based device concepts that rely on quantum mechanical tunneling are intensely being discussed in the literature for applications in electronics and optoelectronics. In this work, the carrier transport mechanisms in semiconductor-insulator-graphene (SIG) capacitors are investigated with respect to their suitability as electron emitters in vertical graphene base transistors (GBTs). Several dielectric materials as tunnel barriers are compared, including dielectric double layers. Using bilayer dielectrics, we experimentally demonstrate significant improvements in the electron injection current by promoting Fowler-Nordheim tunneling (FNT) and step tunneling (ST) while suppressing defect mediated carrier transport. High injected tunneling current densities approaching 10(3) A cm(-2) (limited by series resistance), and excellent current-voltage nonlinearity and asymmetry are achieved using a 1 nm thick high quality dielectric, thulium silicate (TmSiO), as the first insulator layer, and titanium dioxide (TiO2) as a high electron affinity second layer insulator. We also confirm the feasibility and effectiveness of our approach in a full GBT structure which shows dramatic improvement in the collector on-state current density with respect to the previously reported GBTs. The device design and the fabrication scheme have been selected with future CMOS process compatibility in mind. This work proposes a bilayer tunnel barrier approach as a promising candidate to be used in high performance vertical graphene-based tunneling devices. PMID:26176739

  9. Spin dynamics in bilayer graphene: Role of electron-hole puddles and Dyakonov-Perel mechanism

    NASA Astrophysics Data System (ADS)

    Van Tuan, Dinh; Adam, Shaffique; Roche, Stephan

    2016-07-01

    We report on spin transport features which are unique to high quality bilayer graphene, in the absence of magnetic contaminants and strong intervalley mixing. The time-dependent spin polarization of a propagating wave packet is computed using an efficient quantum transport method. In the limit of vanishing effects of substrate and disorder, the energy dependence of the spin lifetime is similar to monolayer graphene with an M -shaped profile and minimum value at the charge neutrality point, but with an electron-hole asymmetry fingerprint. In sharp contrast, the incorporation of substrate-induced electron-hole puddles (characteristics of supported graphene either on SiO2 or hBN ) surprisingly results in a large enhancement of the low-energy spin lifetime and a lowering of its high-energy values. Such a feature, unique to the bilayer, is explained in terms of a reinforced Dyakonov-Perel mechanism at the Dirac point, whereas spin relaxation at higher energies is driven by pure dephasing effects. This suggests further electrostatic control of the spin transport length scales in graphene devices.

  10. Probing moiré physics in low angle twisted bilayer graphene

    NASA Astrophysics Data System (ADS)

    Cao, Yuan; Luo, Jason; Sanchez-Yamagishi, Javier D.; Watanabe, Kenji; Taniguchi, Takashi; Jarillo-Herrero, Pablo

    When two sheets of honeycomb structured graphene are stacked together, a moiré pattern that depend on the twist angle forms. A gapped superlattice band structure is resulted when this angle is small enough so that the energy of moiré modulated hybridization between wave functions on the two sheets that are separated by only 0.34nm is low enough. Apart from the energy gaps, the superlattice band structure also manifests reduced Fermi velocity which implies comparatively higher density of states, multiple van Hove singularities below and above the gaps, and Hofstadter butterfly physics when magnetic field is applied. We show electronic transport measurements of high-quality low-angle twist bilayer graphene devices fabricated by a novel tear-and-stack technique, at zero, low and high magnetic fields. We also present angle dependence of the electronic structure along with magneto-transport features that possibly imply electron-electron interactions. A brief discussion about the transition between the low-twist and high-twist bilayer graphene, the physics of the latter of which is believed to be essentially based on decoupled monolayer graphene according to our previous work, is included.

  11. Bilayer insulator tunnel barriers for graphene-based vertical hot-electron transistors

    NASA Astrophysics Data System (ADS)

    Vaziri, S.; Belete, M.; Dentoni Litta, E.; Smith, A. D.; Lupina, G.; Lemme, M. C.; Östling, M.

    2015-07-01

    Vertical graphene-based device concepts that rely on quantum mechanical tunneling are intensely being discussed in the literature for applications in electronics and optoelectronics. In this work, the carrier transport mechanisms in semiconductor-insulator-graphene (SIG) capacitors are investigated with respect to their suitability as electron emitters in vertical graphene base transistors (GBTs). Several dielectric materials as tunnel barriers are compared, including dielectric double layers. Using bilayer dielectrics, we experimentally demonstrate significant improvements in the electron injection current by promoting Fowler-Nordheim tunneling (FNT) and step tunneling (ST) while suppressing defect mediated carrier transport. High injected tunneling current densities approaching 103 A cm-2 (limited by series resistance), and excellent current-voltage nonlinearity and asymmetry are achieved using a 1 nm thick high quality dielectric, thulium silicate (TmSiO), as the first insulator layer, and titanium dioxide (TiO2) as a high electron affinity second layer insulator. We also confirm the feasibility and effectiveness of our approach in a full GBT structure which shows dramatic improvement in the collector on-state current density with respect to the previously reported GBTs. The device design and the fabrication scheme have been selected with future CMOS process compatibility in mind. This work proposes a bilayer tunnel barrier approach as a promising candidate to be used in high performance vertical graphene-based tunneling devices.

  12. Periodic arrays of intercalated atoms in twisted bilayer graphene: An ab initio investigation

    NASA Astrophysics Data System (ADS)

    Miwa, R. H.; Venezuela, P.; Morell, Eric Suárez

    2015-09-01

    We have performed an ab initio investigation of transition metals (TMs =Mo ,Ru ,Co ,andPt ) embedded in twisted bilayer graphene (tBG) layers. Our total energy results reveal that, triggered by the misalignment between the graphene layers, Mo and Ru atoms may form a quasiperiodic (triangular) array of intercalated atoms. In contrast, the formation of those structures is not expected for the other TMs, the Co and Pt atoms. The net magnetic moment (m ) of Mo and Ru atoms may be quenched upon intercalation, depending on the stacking region (AA or AB). For instance, we find a magnetic moment of 0.3 μB(1.8 μB) for Ru atoms intercalated between the AA (AB) regions of the stacked twisted layers. Through simulated scanning tunneling microscopy (STM) images, we verify that the presence of intercalated TMs can be identified by the formation of bright (hexagonal) spots lying on the graphene surface.

  13. Asymmetric Electron Transport at Monolayer-Bilayer Heterojunctions of Epitaxial Graphene

    SciTech Connect

    Li, An-Ping; Clark, Kendal W; Zhang, Xiaoguang; Gu, Gong; He, Guowei; Feenstra, Randall

    2014-01-01

    The symmetry of the graphene honeycomb lattice is a key element determining many of graphene s unique electronic properties, such as the linear energy-momentum dispersion and the suppressed backscattering 1,2. However, line defects in large-scale epitaxial graphene films, such as grain boundaries, edges, surface steps, and changes in layer thickness, often break the sublatttice symmetry and can impact transport properties of graphene profoundly 3-6. Here we report asymmetric electron transport upon polarity reversal at individual monolayer-bilayer (ML-BL) boundaries in epitaxial graphene on SiC (0001), revealed by scanning tunneling potentiometry. A greater voltage drop is observed when the current flows from BL to ML graphene than in the reverse direction, and the difference remains nearly unchanged with increasing current. This is not a typical nonlinear conductance due to electron transmission through an asymmetric potential. Rather, it indicates the opening of a dynamic energy gap at the Fermi energy due to the Coulomb interaction between the injected nonequilibrium electron density and the pseudospin polarized Friedel oscillation charge density at the boundary. This intriguing heterojunction transport behavior opens a new avenue towards novel quantum functions such as quantum switching.

  14. Excitonic condensation of massless fermions in graphene bilayers

    SciTech Connect

    Zhang, C.-H.; Joglekar, Yogesh N.

    2008-06-15

    Graphene, a single sheet of graphite with honeycomb lattice structure, has massless carriers with tunable density and polarity. We investigate the ground-state phase diagram of two graphene sheets (embedded in a dielectric), separated by distance d where the top layer has electrons and the bottom layer has holes, using mean-field theory. We find that a uniform excitonic condensate occurs over a large range of carrier densities and is weakly dependent on the relative orientation of the two sheets. We obtain the excitonic gap, quasiparticle energy, and the density of states. We show that both the condensate phase stiffness and the mass of the excitons with massless particles as constituents, vary as the square root of the carrier density, and predict that the condensate will not undergo Wigner crystallization.

  15. Theoretical study of polyiodide formation and stability on monolayer and bilayer graphene.

    PubMed

    Tristant, Damien; Puech, Pascal; Gerber, Iann C

    2015-11-28

    The presence of polyiodide complexes have been reported several times when carbon-based materials were doped by iodine molecules, but their formation mechanism remains unclear. By using first-principles calculations that include nonlocal correlation effects by means of a van der Waals density functional approach, we propose that the formation of triiodide (I3(-)) and pentaiodide (I5(-)) is due to a large density of iodine molecules (I2) in interaction with a carbonaceous substrate. As soon as the concentration of surface iodine reaches a threshold value of 12.5% for a graphene monolayer and 6.25% for a bilayer, these complexes spontaneously appear. The corresponding structural and energetic aspects, electronic structures and vibrational frequencies support this statement. An upshift of the Dirac point from the Fermi level with values of 0.45 and 0.52 eV is observed for adsorbed complexes on graphene and intercalated complexes between two layers, respectively. For doped-graphene, it corresponds to a graphene hole density of around 1.1 × 10(13) cm(-2), in quantitative agreement with experiments. Additionally, we have studied the thermal stability at room temperature of these adsorbed ions on graphene by means of ab initio molecular dynamics, which also shows successful p-doping with polyiodide complexes. PMID:26497888

  16. Proposal for realizing the quantum spin Hall phase in a gapped graphene bilayer

    NASA Astrophysics Data System (ADS)

    Zhai, Xuechao; Jin, Guojun

    2016-05-01

    Quantum spin Hall (QSH) insulators with gapless edge states have potential applications in designing low-dissipation devices. In spite of many predictions, to verify the QSH phase in graphene layered materials experimentally is still difficult due to the obstacle in achieving spin-orbit coupling strong enough. We propose a Rashba system of graphene bilayer gapped by dielectric layers and show it can host a valley-polarized QSH phase even when the Rashba interaction approached zero. Such a system exhibits asymmetric topological quantum phase transitions under opposite interlayer biases, due to the dielectric-potential induced inversion asymmetry in the absence of interlayer bias. Specifically, the quantum valley Hall phase exists in zigzag-edged nanoribbons under the bias in one direction but is absent under the reverse bias. These topological phenomena can be well understood by the competition among the dielectric-induced potential, Rashba interaction, and interlayer bias in modulating the bulk band gap. Moreover, the phase diagram is given and the corresponding phase boundaries are derived analytically. Our findings provide a possible way to detect the QSH-related asymmetric topological quantum phenomena in graphene bilayer based on the current experimental technology.

  17. Common-path interference and oscillatory Zener tunneling in bilayer graphene p-n junctions

    PubMed Central

    Nandkishore, Rahul; Levitov, Leonid

    2011-01-01

    Interference and tunneling are two signature quantum effects that are often perceived as the yin and yang of quantum mechanics: a particle simultaneously propagating along several distinct classical paths versus a particle penetrating through a classically inaccessible region via a single least-action path. Here we demonstrate that the Dirac quasiparticles in graphene provide a dramatic departure from this paradigm. We show that Zener tunneling in gapped bilayer graphene, which governs transport through p-n heterojunctions, exhibits common-path interference that takes place under the tunnel barrier. Due to a symmetry peculiar to the gapped bilayer graphene bandstructure, interfering tunneling paths form conjugate pairs, giving rise to high-contrast oscillations in transmission as a function of the gate-tunable bandgap and other control parameters of the junction. The common-path interference is solely due to forward-propagating waves; in contrast to Fabry–Pérot-type interference in resonant-tunneling structures, it does not rely on multiple backscattering. The oscillations manifest themselves in the junction I–V characteristic as N-shaped branches with negative differential conductivity. The negative dI/dV, which arises solely due to under-barrier interference, can enable new high-speed active-circuit devices with architectures that are not available in electronic semiconductor devices. PMID:21825159

  18. Comment on "Creating in-plane pseudomagnetic fields in excess of 1000 T by misoriented stacking in a graphene bilayer"

    NASA Astrophysics Data System (ADS)

    Van der Donck, M.; Peeters, F. M.; Van Duppen, B.

    2016-06-01

    In a recent paper [Phys. Rev. B 89, 125418 (2014), 10.1103/PhysRevB.89.125418], the authors argue that it is possible to map the electronic properties of twisted bilayer graphene to those of bilayer graphene in an in-plane magnetic field. However, their description of the low-energy dynamics of twisted bilayer graphene is restricted to the extended zone scheme and therefore neglects the effects of the superperiodic structure. If the energy spectrum is studied in the supercell Brillouin zone, we find that the comparison with an in-plane magnetic field fails because (i) the energy spectra of the two situations exhibit different symmetries and (ii) the low-energy spectra are very different.

  19. Defects in bilayer silica and graphene: common trends in diverse hexagonal two-dimensional systems

    PubMed Central

    Björkman, Torbjörn; Kurasch, Simon; Lehtinen, Ossi; Kotakoski, Jani; Yazyev, Oleg V.; Srivastava, Anchal; Skakalova, Viera; Smet, Jurgen H.; Kaiser, Ute; Krasheninnikov, Arkady V.

    2013-01-01

    By combining first-principles and classical force field calculations with aberration-corrected high-resolution transmission electron microscopy experiments, we study the morphology and energetics of point and extended defects in hexagonal bilayer silica and make comparison to graphene, another two-dimensional (2D) system with hexagonal symmetry. We show that the motifs of isolated point defects in these 2D structures with otherwise very different properties are similar, and include Stone-Wales-type defects formed by structural unit rotations, flower defects and reconstructed double vacancies. The morphology and energetics of extended defects, such as grain boundaries have much in common as well. As both sp2-hybridised carbon and bilayer silica can also form amorphous structures, our results indicate that the morphology of imperfect 2D honeycomb lattices is largely governed by the underlying symmetry of the lattice. PMID:24336488

  20. The diversity of friction behavior between bi-layer graphenes.

    PubMed

    Liu, Ze

    2014-02-21

    For relative sliding between two rigid graphene sheets that are interacted on by a van der Waals force, we show that the friction behavior is significantly dependent on the interlayer separation distance h. Around the equilibrium interlayer distance he, the friction behavior exactly obeys a linear law. When h is far smaller than he, the linear friction behavior transforms to overlinear behavior. On the other hand, when h is larger than he, there is another critical value of the interlayer distance, hc; when h is larger than he and smaller than hc, the friction behavior transforms from linear to sublinear behavior; however, when h is larger than hc, the coefficient of friction becomes negative. Further, the different friction behaviors are found to be well described by a universal power law, τ = μ*(σ + σ0)(n). PMID:24457559

  1. Electron-phonon interaction and pairing mechanism in superconducting Ca-intercalated bilayer graphene.

    PubMed

    Margine, E R; Lambert, Henry; Giustino, Feliciano

    2016-01-01

    Using the ab initio anisotropic Eliashberg theory including Coulomb interactions, we investigate the electron-phonon interaction and the pairing mechanism in the recently-reported superconducting Ca-intercalated bilayer graphene. We find that C6CaC6 can support phonon-mediated superconductivity with a critical temperature Tc = 6.8-8.1 K, in good agreement with experimental data. Our calculations indicate that the low-energy Caxy vibrations are critical to the pairing, and that it should be possible to resolve two distinct superconducting gaps on the electron and hole Fermi surface pockets. PMID:26892805

  2. Electron-phonon interaction and pairing mechanism in superconducting Ca-intercalated bilayer graphene

    PubMed Central

    Margine, E. R.; Lambert, Henry; Giustino, Feliciano

    2016-01-01

    Using the ab initio anisotropic Eliashberg theory including Coulomb interactions, we investigate the electron-phonon interaction and the pairing mechanism in the recently-reported superconducting Ca-intercalated bilayer graphene. We find that C6CaC6 can support phonon-mediated superconductivity with a critical temperature Tc = 6.8–8.1 K, in good agreement with experimental data. Our calculations indicate that the low-energy Caxy vibrations are critical to the pairing, and that it should be possible to resolve two distinct superconducting gaps on the electron and hole Fermi surface pockets. PMID:26892805

  3. Electron-phonon interaction and pairing mechanism in superconducting Ca-intercalated bilayer graphene

    NASA Astrophysics Data System (ADS)

    Margine, E. R.; Lambert, Henry; Giustino, Feliciano

    2016-02-01

    Using the ab initio anisotropic Eliashberg theory including Coulomb interactions, we investigate the electron-phonon interaction and the pairing mechanism in the recently-reported superconducting Ca-intercalated bilayer graphene. We find that C6CaC6 can support phonon-mediated superconductivity with a critical temperature Tc = 6.8-8.1 K, in good agreement with experimental data. Our calculations indicate that the low-energy Caxy vibrations are critical to the pairing, and that it should be possible to resolve two distinct superconducting gaps on the electron and hole Fermi surface pockets.

  4. Tunable van Hove Singularities and Optical Absorption of Twisted Bilayer Graphene

    NASA Astrophysics Data System (ADS)

    Liang, Yufeng; Yang, Li

    2013-03-01

    We perform the first-principles GW-Bethe-Salpeter Equation (BSE) simulation to study the optical absorption spectra of isolated twisted bilayer graphene (TBLG). The twisting generates new van Hove singularities (VHS), and these VHSs and corresponding optical absorption peaks can be tuned in a wide range by the twist angle. Enhanced electron-electron and electron-hole interactions are shown to be important to understand both optical absorption peak positions and their lineshapes. With these many-electron effects included, our calculation satisfactorily explains recent experimental measurements.

  5. In-Plane Electric Polarization of Bilayer Graphene Nanoribbons Induced by an Interlayer Bias Voltage.

    PubMed

    Okugawa, Ryo; Tanaka, Junya; Koretsune, Takashi; Saito, Susumu; Murakami, Shuichi

    2015-10-01

    We theoretically show that an interlayer bias voltage in the AB-stacked bilayer graphene nanoribbons with armchair edges induces an electric polarization along the ribbon. Both tight-binding and ab initio calculations consistently indicate that when the bias voltage is weak, the polarization shows opposite signs depending on the ribbon width modulo three. This nontrivial dependence is explained using a two-band effective model. A strong limit of the bias voltage in the tight-binding model shows either one-third or zero polarization, which agrees with the topological argument. PMID:26550741

  6. Variation of electronic and magnetic properties of bilayer zigzag graphene nanoribbons by sliding and electric field

    NASA Astrophysics Data System (ADS)

    Senger, Ramazan Tugrul; Yagmurcukardes, Mehmet

    2014-03-01

    Structural, electronic and magnetic properties of bilayer zigzag graphene nanoribbons (BZGNR) are studied using density functional theory methods. We find that ground state stacking geometry of the layers depends on the width of BZGNR. Energy bandgap , edge-localized magnetic moments and the magnetic ordering are all modified by mechanical sliding of the layers and/or by external applied electric fields. These effects can be utilized in design of electro-mechanical and magneto-mechanical nano devices. We acknowledge financial support by TUBITAK through grant 111T318.

  7. Spin-Polarized Transport on Photo-Asisted Bilayer Graphene Ribbons

    NASA Astrophysics Data System (ADS)

    Zambrano, David; Rosales, Luis; Orellana, Pedro; Latgé, Andrea

    We show how both transmission and spin polarization behave in bilayer graphene ribbons in contact with a ferromagnetic insulator while a laser is applied to the ribbon. Using a π-orbital tight-binding model as a low energy approximation and the Tien-Gordon [3] formalism we explore how these systems behave when the ribbon is photo-assisted with a laser. For particular values of the laser parameters, the Fano antiresonance are removed enhancing the transmission while for others spin-polarized transport will arise. The authors acknowledge financial support from FONDECYT, under Grant 1140571 & 1140388 and from CONICYT, under Grant PAI-79140064.

  8. Spin relaxation in bilayer graphene: the role of electron-electron scattering

    NASA Astrophysics Data System (ADS)

    Katiyar, Saurabh; Ghosh, Bahniman; Salimath, Akshay Kumar

    2016-02-01

    This paper investigates the influence of electron-electron scattering on spin relaxation length in bilayer graphene using semiclassical Monte Carlo simulation. Both D'yakonov-P'erel and Elliot-Yafet mechanisms are considered for spin relaxation. It is shown that spin relaxation length decreases by 17 % at 300 K on including electron-electron scattering. The reason of this variation in spin relaxation length is that the ensemble spin is modified upon an e-e collision, and also e-e scattering rate is greater than phonon scattering rate which causes change in spin transport profile.

  9. Unified description of the dc conductivity of monolayer and bilayer graphene at finite densities based on resonant scatterers

    NASA Astrophysics Data System (ADS)

    Ferreira, Aires; Viana-Gomes, J.; Nilsson, Johan; Mucciolo, E. R.; Peres, N. M. R.; Castro Neto, A. H.

    2011-04-01

    We show that a coherent picture of the dc conductivity of monolayer and bilayer graphene at finite electronic densities emerges upon considering that strong short-range potentials are the main source of scattering in these two systems. The origin of the strong short-range potentials may lie in adsorbed hydrocarbons at the surface of graphene. The equivalence among results based on the partial-wave description of scattering, the Lippmann-Schwinger equation, and the T-matrix approach is established. Scattering due to resonant impurities close to the neutrality point is investigated via a numerical computation of the Kubo formula using a kernel polynomial method. We find that relevant adsorbate species originate impurity bands in monolayer and bilayer graphene close to the Dirac point. In the midgap region, a plateau of minimum conductivity of about e2/h (per layer) is induced by the resonant disorder. In bilayer graphene, a large adsorbate concentration can develop an energy gap between midgap and high-energy states. As a consequence, the conductivity plateau is supressed near the edges and a “conductivity gap” takes place. Finally, a scattering formalism for electrons in biased bilayer graphene, taking into account the degeneracy of the spectrum, is developed and the dc conductivity of that system is studied.

  10. Hybrid matrix method for stable numerical analysis of the propagation of Dirac electrons in gapless bilayer graphene superlattices

    NASA Astrophysics Data System (ADS)

    Briones-Torres, J. A.; Pernas-Salomón, R.; Pérez-Álvarez, R.; Rodríguez-Vargas, I.

    2016-05-01

    Gapless bilayer graphene (GBG), like monolayer graphene, is a material system with unique properties, such as anti-Klein tunneling and intrinsic Fano resonances. These properties rely on the gapless parabolic dispersion relation and the chiral nature of bilayer graphene electrons. In addition, propagating and evanescent electron states coexist inherently in this material, giving rise to these exotic properties. In this sense, bilayer graphene is unique, since in most material systems in which Fano resonance phenomena are manifested an external source that provides extended states is required. However, from a numerical standpoint, the presence of evanescent-divergent states in the eigenfunctions linear superposition representing the Dirac spinors, leads to a numerical degradation (the so called Ωd problem) in the practical applications of the standard Coefficient Transfer Matrix (K) method used to study charge transport properties in Bilayer Graphene based multi-barrier systems. We present here a straightforward procedure based in the hybrid compliance-stiffness matrix method (H) that can overcome this numerical degradation. Our results show that in contrast to standard matrix method, the proposed H method is suitable to study the transmission and transport properties of electrons in GBG superlattice since it remains numerically stable regardless the size of the superlattice and the range of values taken by the input parameters: the energy and angle of the incident electrons, the barrier height and the thickness and number of barriers. We show that the matrix determinant can be used as a test of the numerical accuracy in real calculations.

  11. Interaction between the intrinsic edge state and the helical boundary state of topological insulator phase in bilayer graphene

    NASA Astrophysics Data System (ADS)

    Lü, Xiaoling; Jiang, Liwei; Zheng, Yisong

    2016-04-01

    Graphene has intrinsic edge states localized at zigzag edge or lattice defect. Helical boundary states can also be established in such a two-dimensional carbon material at the boundary of topological insulator (TI) phase realized by the extrinsic Rashba spin-orbital coupling (SOC) in gated bilayer graphene. We theoretically investigate the interaction between these two kinds of edge (boundary) states when they coexist in a bilayer graphene. We find that this interaction gives rise to some very interesting results. In a zigzag edged nanoribbon of bilayer graphene, it is possible that the TI helical state does not localize at the TI phase boundary. Instead it moves to the nanoribbon edge even though the SOC is absent therein. In a bulk lattice of bilayer graphene embedded with two line defects, the numbers of helical state subbands at the two line defects are not equal to each other. In such a case, the backscattering lacking is still forbidden since the Kramers pairs are valley polarized.

  12. Transport properties of AB stacked (Bernal) bilayer graphene on and without substrate within 2- and 4-band approximations

    SciTech Connect

    Gusynin, V. P. Sharapov, S. G.; Reshetnyak, A. A.

    2015-10-27

    We present the results of the calculations of longitudinal and Hall conductivities of AB-stacked bilayer graphene as a function of frequency, finite chemical potential, temperature both with and without magnetic fields on a base of 2- and 4-band effective models. The limited cases of the conductivities for direct current are derived. The relations being important for optoelectronic among Hall conductivities and Faraday, Kerr angles in the AB-bilayers samples in the electric and magnetic fields when the radiation passes across bilayer sheets on different kinds a substrate are obtained.

  13. Bilayer graphene formed by passage of current through graphite: evidence for a three-dimensional structure.

    PubMed

    Harris, Peter J F; Slater, Thomas J A; Haigh, Sarah J; Hage, Fredrik S; Kepaptsoglou, Despoina M; Ramasse, Quentin M; Brydson, Rik

    2014-11-21

    The passage of an electric current through graphite or few-layer graphene can result in a striking structural transformation, but there is disagreement about the precise nature of this process. Some workers have interpreted the phenomenon in terms of the sublimation and edge reconstruction of essentially flat graphitic structures. An alternative explanation is that the transformation actually involves a change from a flat to a three-dimensional structure. Here we describe detailed studies of carbon produced by the passage of a current through graphite which provide strong evidence that the transformed carbon is indeed three-dimensional. The evidence comes primarily from images obtained in the scanning transmission electron microscope using the technique of high-angle annular dark-field imaging, and from a detailed analysis of electron energy loss spectra. We discuss the possible mechanism of the transformation, and consider potential applications of 'three-dimensional bilayer graphene'. PMID:25354780

  14. Unraveling the interlayer-related phonon self-energy renormalization in bilayer graphene

    PubMed Central

    Araujo, Paulo T.; Mafra, Daniela L.; Sato, Kentaro; Saito, Riichiro; Kong, Jing; Dresselhaus, Mildred S.

    2012-01-01

    In this letter, we present a step towards understanding the bilayer graphene (2LG) interlayer (IL)-related phonon combination modes and overtones as well as their phonon self-energy renormalizations by using both gate-modulated and laser-energy dependent inelastic scattering spectroscopy. We show that although the IL interactions are weak, their respective phonon renormalization response is significant. Particularly special, the IL interactions are mediated by Van der Waals forces and are fundamental for understanding low-energy phenomena such as transport and infrared optics. Our approach opens up a new route to understanding fundamental properties of IL interactions which can be extended to any graphene-like material, such as MoS2, WSe2, oxides and hydroxides. Furthermore, we report a previously elusive crossing between IL-related phonon combination modes in 2LG, which might have important technological applications. PMID:23264879

  15. Switchable photovoltaic effect in bilayer graphene/BiFeO3/Pt heterostructures

    NASA Astrophysics Data System (ADS)

    Katiyar, Rajesh K.; Misra, Pankaj; Mendoza, Frank; Morell, Gerardo; Katiyar, Ram S.

    2014-10-01

    We report the switchable photovoltaic effects in graphene/BiFeO3/Pt heterostructures. Pure phase polycrystalline BiFeO3 films were deposited on Pt/TiO2/SiO2/Si substrates by pulse laser deposition. A bilayer graphene was transferred onto the BiFeO3 film which serves as transparent conducting electrodes. The heterostructures showed switchable photovoltaic effect depending on ferroelectric polarization directions indicating depolarization field induced separation of photo-generated carriers. The open circuit voltage (VOC) and short circuit current density (JSC) were measured to be ˜110 mV, ˜92 μA/cm2 in positive polarity and similar values were obtained when the polarity was reversed. The JSC and VOC also showed rapid response (<100 ms) as a function of light exposure time.

  16. Epitaxial growth of large-area bilayer graphene on Ru(0001)

    SciTech Connect

    Que, Yande; Xiao, Wende E-mail: hjgao@iphy.ac.cn; Fei, Xiangmin; Chen, Hui; Du, S. X.; Gao, H.-J. E-mail: hjgao@iphy.ac.cn; Huang, Li

    2014-03-03

    Large-area bilayer graphene (BG) is grown epitaxially on Ru(0001) surface and characterized by low temperature scanning tunneling microscopy. The lattice of the bottom layer of BG is stretched by 1.2%, while strain is absent from the top layer. The lattice mismatch between the two layers leads to the formation of a moiré pattern with a periodicity of ∼21.5 nm and a mixture of AA- and AB-stacking. The √3 × √3 superstructure around atomic defects is attributed to the inter-valley scattering of the delocalized π-electrons, demonstrating that the as-grown BG behaves like intrinsic free-standing graphene.

  17. Landau-level dispersion and the quantum Hall plateaus in bilayer graphene

    SciTech Connect

    Zarenia, M.; Peeters, F. M.; Vasilopoulos, P.; Pourtolami, N.

    2013-12-04

    We study the quantum Hall effect (QHE) in bilayer graphene using the Kubo-Greenwood formula. At zero temperature the Hall conductivity σ{sub yx} is given by σ{sub yx} = 4(N+1)e{sup 2}/h with N the index of the highest occupied Landau level (LL). Including the dispersion of the LLs and their width, due to e.g. scattering by impurities, produces the plateau of the n = 0 LL in agreement with experimental results on doped samples and similar theoretical results on single-layer graphene plateaus widen with impurity concentration. Further, the evaluated resistivity ρ{sub xx} exhibits a strong, oscillatory dependence on the electron concentration. Explicit results are obtained for δ-function impurities.

  18. Sandwich beam model for free vibration analysis of bilayer graphene nanoribbons with interlayer shear effect

    SciTech Connect

    Nazemnezhad, Reza E-mail: rnazemnezhad@du.ac.ir; Shokrollahi, Hassan; Hosseini-Hashemi, Shahrokh

    2014-05-07

    In this study, sandwich beam model (SM) is proposed for free vibration analysis of bilayer graphene nanoribbons (BLGNRs) with interlayer shear effect. This model also takes into account the intralayer (in-plane) stretch of graphene nanoribbons. The molecular dynamics (MD) simulations using the software LAMMPS and Adaptive Intermolecular Reactive Empirical Bond Order (AIREBO) potential are done to validate the accuracy of the sandwich model results. The MD simulation results include the two first frequencies of cantilever BLGNRs with different lengths and two interlayer shear moduli, i.e., 0.25 and 4.6 GPa. These two interlayer shear moduli, 0.25 and 4.6 GPa, can be obtained by sliding a small flake of graphene on a large graphene substrate when the parameter of E-LJ term in AIREBO potential, epsilon-CC, is set to be 2.84 and 45.44 meV, respectively. The SM results for a wide range of bending rigidity values show that the proposed model, i.e., the SM, predicts much better than the previous beam model in which the intralayer stretch is ignored. In addition, it is observed that the model can properly predict the natural frequencies of BLGNRs for various values of the bending rigidity and the interlayer shear modulus.

  19. Oxygen-activated growth and bandgap tunability of large single-crystal bilayer graphene.

    PubMed

    Hao, Yufeng; Wang, Lei; Liu, Yuanyue; Chen, Hua; Wang, Xiaohan; Tan, Cheng; Nie, Shu; Suk, Ji Won; Jiang, Tengfei; Liang, Tengfei; Xiao, Junfeng; Ye, Wenjing; Dean, Cory R; Yakobson, Boris I; McCarty, Kevin F; Kim, Philip; Hone, James; Colombo, Luigi; Ruoff, Rodney S

    2016-05-01

    Bernal (AB)-stacked bilayer graphene (BLG) is a semiconductor whose bandgap can be tuned by a transverse electric field, making it a unique material for a number of electronic and photonic devices. A scalable approach to synthesize high-quality BLG is therefore critical, which requires minimal crystalline defects in both graphene layers and maximal area of Bernal stacking, which is necessary for bandgap tunability. Here we demonstrate that in an oxygen-activated chemical vapour deposition (CVD) process, half-millimetre size, Bernal-stacked BLG single crystals can be synthesized on Cu. Besides the traditional 'surface-limited' growth mechanism for SLG (1st layer), we discovered new microscopic steps governing the growth of the 2nd graphene layer below the 1st layer as the diffusion of carbon atoms through the Cu bulk after complete dehydrogenation of hydrocarbon molecules on the Cu surface, which does not occur in the absence of oxygen. Moreover, we found that the efficient diffusion of the carbon atoms present at the interface between Cu and the 1st graphene layer further facilitates growth of large domains of the 2nd layer. The CVD BLG has superior electrical quality, with a device on/off ratio greater than 10(4), and a tunable bandgap up to ∼100 meV at a displacement field of 0.9 V nm(-1). PMID:26828845

  20. Oxygen-activated growth and bandgap tunability of large single-crystal bilayer graphene

    NASA Astrophysics Data System (ADS)

    Hao, Yufeng; Wang, Lei; Liu, Yuanyue; Chen, Hua; Wang, Xiaohan; Tan, Cheng; Nie, Shu; Suk, Ji Won; Jiang, Tengfei; Liang, Tengfei; Xiao, Junfeng; Ye, Wenjing; Dean, Cory R.; Yakobson, Boris I.; McCarty, Kevin F.; Kim, Philip; Hone, James; Colombo, Luigi; Ruoff, Rodney S.

    2016-05-01

    Bernal (AB)-stacked bilayer graphene (BLG) is a semiconductor whose bandgap can be tuned by a transverse electric field, making it a unique material for a number of electronic and photonic devices. A scalable approach to synthesize high-quality BLG is therefore critical, which requires minimal crystalline defects in both graphene layers and maximal area of Bernal stacking, which is necessary for bandgap tunability. Here we demonstrate that in an oxygen-activated chemical vapour deposition (CVD) process, half-millimetre size, Bernal-stacked BLG single crystals can be synthesized on Cu. Besides the traditional ‘surface-limited’ growth mechanism for SLG (1st layer), we discovered new microscopic steps governing the growth of the 2nd graphene layer below the 1st layer as the diffusion of carbon atoms through the Cu bulk after complete dehydrogenation of hydrocarbon molecules on the Cu surface, which does not occur in the absence of oxygen. Moreover, we found that the efficient diffusion of the carbon atoms present at the interface between Cu and the 1st graphene layer further facilitates growth of large domains of the 2nd layer. The CVD BLG has superior electrical quality, with a device on/off ratio greater than 104, and a tunable bandgap up to ∼100 meV at a displacement field of 0.9 V nm‑1.

  1. Schottky barrier contrasts in single and bi-layer graphene contacts for MoS2 field-effect transistors

    NASA Astrophysics Data System (ADS)

    Du, Hyewon; Kim, Taekwang; Shin, Somyeong; Kim, Dahye; Kim, Hakseong; Sung, Ji Ho; Lee, Myoung Jae; Seo, David H.; Lee, Sang Wook; Jo, Moon-Ho; Seo, Sunae

    2015-12-01

    We have investigated single- and bi-layer graphene as source-drain electrodes for n-type MoS2 transistors. Ti-MoS2-graphene heterojunction transistors using both single-layer MoS2 (1M) and 4-layer MoS2 (4M) were fabricated in order to compare graphene electrodes with commonly used Ti electrodes. MoS2-graphene Schottky barrier provided electron injection efficiency up to 130 times higher in the subthreshold regime when compared with MoS2-Ti, which resulted in VDS polarity dependence of device parameters such as threshold voltage (VTH) and subthreshold swing (SS). Comparing single-layer graphene (SG) with bi-layer graphene (BG) in 4M devices, SG electrodes exhibited enhanced device performance with higher on/off ratio and increased field-effect mobility (μFE) due to more sensitive Fermi level shift by gate voltage. Meanwhile, in the strongly accumulated regime, we observed opposing behavior depending on MoS2 thickness for both SG and BG contacts. Differential conductance (σd) of 1M increases with VDS irrespective of VDS polarity, while σd of 4M ceases monotonic growth at positive VDS values transitioning to ohmic-like contact formation. Nevertheless, the low absolute value of σd saturation of the 4M-graphene junction demonstrates that graphene electrode could be unfavorable for high current carrying transistors.

  2. Bilayer graphene spectral function in the random phase approximation and self-consistent GW approximation

    NASA Astrophysics Data System (ADS)

    Sabashvili, Andro; Östlund, Stellan; Granath, Mats

    2013-08-01

    We calculate the single-particle spectral function for doped bilayer graphene in the low energy limit, described by two parabolic bands with zero band gap and long range Coulomb interaction. Calculations are done using thermal Green's functions in both the random phase approximation (RPA) and the fully self-consistent GW approximation. Consistent with previous studies RPA yields a spectral function which, apart from the Landau quasiparticle peaks, shows additional coherent features interpreted as plasmarons, i.e., composite electron-plasmon excitations. In the GW approximation the plasmaron becomes incoherent and peaks are replaced by much broader features. The deviation of the quasiparticle weight and mass renormalization from their noninteracting values is small which indicates that bilayer graphene is a weakly interacting system. The electron energy loss function, Im[-ɛq-1(ω)] shows a sharp plasmon mode in RPA which in the GW approximation becomes less coherent and thus consistent with the weaker plasmaron features in the corresponding single-particle spectral function.

  3. Bilayer Graphene-Hexagonal Boron Nitride Heterostructure Negative Differential Resistance Interlayer Tunnel FETs

    NASA Astrophysics Data System (ADS)

    Kang, Sangwoo; Fallahazad, Babak; Lee, Kayoung; Movva, Hema; Kim, Kyounghwan; Corbet, Chris; Taniguchi, Takashi; Watanabe, Kenji; Colombo, Luigi; Register, Leonard; Tutuc, Emanuel; Banerjee, Sanjay

    2015-03-01

    We present the operation of a vertical tunneling field effect transistor using a stacked double bilayer graphene (BLG) and hexagonal boron nitride (hBN) heterostructure. The device is fabricated with the so-called Van der Waals transfer method with the edges of the top and bottom BLG flakes being rotationally aligned to roughly 60°. The device shows multiple negative differential resistance (NDR) peaks which can be adjusted through the gate bias. Temperature dependent measurements show that the peak width of the differential conductance broadens and the height lowered when the temperature is increased, which is indicative of resonant tunneling. Through electrostatic calculations, it is shown that the multiple peaks occur when the two conduction bands at the K-point of the top and bottom bilayer graphene become aligned at certain bias conditions. It is also shown that by adjusting the rotational alignment of the bands of the top and bottom BLG through an in-plane magnetic field, the conductance peaks can be broadened. In addition, utilizing the NDR characteristic of the device, one-transistor latch or SRAM operation is demonstrated.

  4. Dislocations in stacking and commensurate-incommensurate phase transition in bilayer graphene and hexagonal boron nitride

    NASA Astrophysics Data System (ADS)

    Lebedeva, Irina V.; Lebedev, Alexander V.; Popov, Andrey M.; Knizhnik, Andrey A.

    2016-06-01

    Dislocations corresponding to a change of stacking in two-dimensional hexagonal bilayers, graphene and boron nitride, and associated with boundaries between commensurate domains are investigated using the two-chain Frenkel-Kontorova model on top of ab initio calculations. Structural transformations of bilayers in which the bottom layer is stretched and the upper one is left to relax freely are considered for gradually increased elongation of the bottom layer. Formation energies of dislocations, dislocation width, and orientation of the boundary between commensurate domains are analyzed depending on the magnitude and direction of elongation. The second-order phase transition from the commensurate phase to the incommensurate one with multiple dislocations is predicted to take place at some critical elongation. The order parameter for this transition corresponds to the density of dislocations, which grows continuously upon increasing the elongation of the bottom layer above the critical value. In graphene and metastable boron nitride with the layers aligned in the same direction, where elementary dislocations are partial, this transition, however, is preceded by formation of the first dislocation at the elongation smaller than the critical one. The phase diagrams including this intermediate state are plotted in coordinates of the magnitude and direction of elongation of the bottom layer.

  5. Continuous and reversible tuning of the disorder-driven superconductor–insulator transition in bilayer graphene

    PubMed Central

    Lee, Gil-Ho; Jeong, Dongchan; Park, Kee-Su; Meir, Yigal; Cha, Min-Chul; Lee, Hu-Jong

    2015-01-01

    The influence of static disorder on a quantum phase transition (QPT) is a fundamental issue in condensed matter physics. As a prototypical example of a disorder-tuned QPT, the superconductor–insulator transition (SIT) has been investigated intensively over the past three decades, but as yet without a general consensus on its nature. A key element is good control of disorder. Here, we present an experimental study of the SIT based on precise in-situ tuning of disorder in dual-gated bilayer graphene proximity-coupled to two superconducting electrodes through electrical and reversible control of the band gap and the charge carrier density. In the presence of a static disorder potential, Andreev-paired carriers formed close to the Fermi level in bilayer graphene constitute a randomly distributed network of proximity-induced superconducting puddles. The landscape of the network was easily tuned by electrical gating to induce percolative clusters at the onset of superconductivity. This is evidenced by scaling behavior consistent with the classical percolation in transport measurements. At lower temperatures, the solely electrical tuning of the disorder-induced landscape enables us to observe, for the first time, a crossover from classical to quantum percolation in a single device, which elucidates how thermal dephasing engages in separating the two regimes. PMID:26310774

  6. Continuous and reversible tuning of the disorder-driven superconductor-insulator transition in bilayer graphene.

    PubMed

    Lee, Gil-Ho; Jeong, Dongchan; Park, Kee-Su; Meir, Yigal; Cha, Min-Chul; Lee, Hu-Jong

    2015-01-01

    The influence of static disorder on a quantum phase transition (QPT) is a fundamental issue in condensed matter physics. As a prototypical example of a disorder-tuned QPT, the superconductor-insulator transition (SIT) has been investigated intensively over the past three decades, but as yet without a general consensus on its nature. A key element is good control of disorder. Here, we present an experimental study of the SIT based on precise in-situ tuning of disorder in dual-gated bilayer graphene proximity-coupled to two superconducting electrodes through electrical and reversible control of the band gap and the charge carrier density. In the presence of a static disorder potential, Andreev-paired carriers formed close to the Fermi level in bilayer graphene constitute a randomly distributed network of proximity-induced superconducting puddles. The landscape of the network was easily tuned by electrical gating to induce percolative clusters at the onset of superconductivity. This is evidenced by scaling behavior consistent with the classical percolation in transport measurements. At lower temperatures, the solely electrical tuning of the disorder-induced landscape enables us to observe, for the first time, a crossover from classical to quantum percolation in a single device, which elucidates how thermal dephasing engages in separating the two regimes. PMID:26310774

  7. Continuous and reversible tuning of the disorder-driven superconductor-insulator transition in bilayer graphene

    NASA Astrophysics Data System (ADS)

    Lee, Gil-Ho; Jeong, Dongchan; Park, Kee-Su; Meir, Yigal; Cha, Min-Chul; Lee, Hu-Jong

    2015-08-01

    The influence of static disorder on a quantum phase transition (QPT) is a fundamental issue in condensed matter physics. As a prototypical example of a disorder-tuned QPT, the superconductor-insulator transition (SIT) has been investigated intensively over the past three decades, but as yet without a general consensus on its nature. A key element is good control of disorder. Here, we present an experimental study of the SIT based on precise in-situ tuning of disorder in dual-gated bilayer graphene proximity-coupled to two superconducting electrodes through electrical and reversible control of the band gap and the charge carrier density. In the presence of a static disorder potential, Andreev-paired carriers formed close to the Fermi level in bilayer graphene constitute a randomly distributed network of proximity-induced superconducting puddles. The landscape of the network was easily tuned by electrical gating to induce percolative clusters at the onset of superconductivity. This is evidenced by scaling behavior consistent with the classical percolation in transport measurements. At lower temperatures, the solely electrical tuning of the disorder-induced landscape enables us to observe, for the first time, a crossover from classical to quantum percolation in a single device, which elucidates how thermal dephasing engages in separating the two regimes.

  8. Van Hove singularities in doped twisted graphene bilayers studied by scanning tunneling spectroscopy

    NASA Astrophysics Data System (ADS)

    Cherkez, V.; de Laissardière, G. Trambly; Mallet, P.; Veuillen, J.-Y.

    2015-04-01

    The effect of electron doping on the van Hove singularities (vHs) which develop in twisted graphene bilayers (tBLs) is studied for a broad range of rotation angles θ (1 .5∘<θ <15∘) by means of scanning tunneling microscopy and spectroscopy. Bilayer and trilayer graphene islands were grown on the 6H-SiC(000-1) (3 ×3 ) surface, which results in tBLs doped in the 1012cm-2 range by charge transfer from the substrate. For large angles, doping manifests in a strong asymmetry of the positions of the upper (in empty states) and lower (in occupied states) vHs with respect to the Fermi level. The splitting of these vHs energies is found essentially independent of doping for the whole range of θ values, but the center of theses vHs shifts towards negative energies with increasing electron doping. Consequently, the upper vHs crosses the Fermi level for smaller angles (around 3∘ ). The analysis of the data performed using tight-binding calculations and simple electrostatic considerations shows that the interlayer bias remains small (<100 mV ) for the doping level resulting from the interfacial charge transfer (≃5 ×1012cm-2) .

  9. Synthesis of twisted bilayer graphene and studies of its low energy Raman modes

    NASA Astrophysics Data System (ADS)

    Chung, Ting Fung; He, Rui; Delaney, Conor; Keiser, Courtney; Jauregui, Luis A.; Shand, Paul M.; Chancey, C. C.; Wang, Yanan; Bao, Jiming; Chen, Yong P.

    2014-03-01

    We have synthesized bilayer graphene on copper foils with different twist angles and stacking orders using chemical vapor deposition. Raman spectroscopy has been used to study twisted bilayer graphene (tBLG) transferred on Si/SiO2 substrate, focusing on low frequency Raman modes below 200 cm-1. The modes are found in a small range of twist angle at which the G Raman peak is under resonance conditions with corresponding laser energy. The ~ 94 cm-1 mode (ZO'L) and ~ 160 cm-1 (ZO'H) modes (measured with a 532 nm laser) are assigned to the fundamental layer breathing vibration (ZO' mode) associated with different phonon wavenumbers, indicating different phonon scattering processes. We identify that the ZO'L mode shares the same resonance enhancement mechanism as G Raman mode arising from van Hove singularities (vHs) in the band structure of tBLG. The ZO'H mode was previously observed, related to the superlattice induced wavevector. The dependence of ZO'L mode frequency and line width on the twist angle can be understood by the double-resonance Raman scattering. We also observe another lower energy Raman mode at ~ 52 cm-1, whose origin is yet to be understood. We have also measured the doping dependence of Raman modes in tBLG. Our results probe the interlayer coupling and phonon dispersions in tBLG.

  10. Semiconductor-halfmetal-metal transition and magnetism of bilayer graphene nanoribbons/hexagonal boron nitride heterostructure

    NASA Astrophysics Data System (ADS)

    Ilyasov, V. V.; Meshi, B. C.; Nguyen, V. C.; Ershov, I. V.; Nguyen, D. C.

    2014-12-01

    The paper presents the results of ab initio study of electronic structure modulation and edge magnetism in the antiferromagnetic (AF) bilayer zigzag graphene nanoribbons (AF-BZGNR)/hexagonal boron nitride (h-BN(0001)) semiconductor heterostructure induced with transverse external electric field (Eext) and nanomechanical compression (extension), performed within the framework of the density functional theory using Grimme's DFT(PBE)-D2 scheme. For the first time we established critical values of Eext and interlayer distance in the bilayer for the BZGNR/h-BN(0001) heterostructure providing for semiconductor-halfmetal-metal phase transition for one of the electron spin configurations. We discovered the effect of preserved local magnetic moment (0.3μB) of edge carbon atoms of the lower (buffer) graphene nanoribbon during nanomechanical uniaxial compression (or extension) of the BZGNR/h-BN(0001) semiconductor heterostructure. It has been demonstrated that magnetic properties of the AF-BZGNR/h-BN(0001) semiconductor heterostructure can be controlled using Eext. In particular, the local magnetic moment of edge carbon atoms decreases by 10% at a critical value of the positive potential. We have established that local magnetic moments and band gaps can be altered in a wide range using nanomechanical uniaxial compression and Eext, thus making the AF-BZGNR/h-BN(0001) semiconductor heterostructure potentially promising for nanosensors, spin filters, and spintronics applications.

  11. Experimental realization of gate controlled topological conducting channels in bilayer graphene

    NASA Astrophysics Data System (ADS)

    Li, J.; McFaul, K. J.; Zern, Z.; Zhu, J.; Wang, K.; Ren, Y. F.; Qiao, Z. H.; Watanabe, K.; Taniguchi, T.

    Manipulating the valley degree of freedom in two-dimensional honeycomb lattices can potentially lead to a new type of electronics called valleytronics. In electrically gapped bilayer graphene, the broken inversion symmetry leads to non-zero and asymmetric Berry curvature Ω in the K and K' valleys of the Brillouin zone. Reversing the sign of Ω at the internal line junction of two oppositely gated bilayer graphene is predicted to yield counter-propagating edge modes, the so-called kink states, with quantized conductance of 4e2 / h in the absence of valley mixing. We have overcome fabrication challenges to implement high-quality hBN encapsulated, dual-split-gates structures necessary to observe the kink states. Here I present experimental evidences of the kink states. In the absence of a magnetic field, the kink states have a mean free path of a few hundred nm. Ballistic conductance of 4e2 / h is achieved in a perpendicular magnetic field. We discuss the potential valley-mixing mechanisms and the role of the magnetic field. Experimental results are supported by numerical studies. We will also discuss ongoing efforts in realizing valley-controlled transmission and guiding of the kink states, which is a significant step towards the development of valleytronics.

  12. Even-denominator fractional quantum Hall effect in multi-terminal suspended bilayer graphene

    NASA Astrophysics Data System (ADS)

    Morpurgo, Alberto

    2015-03-01

    I will discuss magneto-transport experiments through multi-terminal suspended bilayer graphene devices of very high quality (mean-free path larger than the device size; density of charge inhomogeneity 109 cm-2) . The multi-terminal geometry enables independent measurements of the longitudinal and transverse magneto resistance, which are essential to properly measure quantum Hall states. At high magnetic field, different fractional states emerge on the hole side, including states at ν = -4/3 and ν = -1/2 that are fully developed (plateau in Rxy quantized with an accuracy better than 0.5%, and a concomitant minimum in Rxx) and other states (e.g., at -5/2, -2/3, -8/5), which manifest themselves through a clear minimum in Rxx occurring at a fixed value of filling factor. The more pronounced states are consistent with predictions of a recent theory by Papic and Abanin, that describes the mixing of the degenerate, zero-energy N =0 and N =1 Landau levels of graphene bilayers due to e-e interactions, and which indicates that the even denominator ν = -1/2 state is of the Moore-Read type. If time allows, I will also discuss our recent experiments of suspended multi-terminal 4-layer graphene, on which we made different interesting observations. One is an integer quantum Hall effect consistent with an even larger degeneracy of the E =0 Landau levels, for which it may be interesting to start exploring theoretically possible new physics in the fractional regime. The second is the occurrence of an unexpected gapped insulating state at zero magnetic field. Together with previous experiments on suspended mono, bi, and trilayers, this observation points to an even-odd effect of e-e interaction (at zero magnetic field) in graphene multilayers: even layers are gapped by e-e interactions while odd layers stay conducting, due to the presence of a Dirac-like band in their electronic structure. A comparison of the gapped state in bilayers and four-layers show that the magnitude of the

  13. Step-edge-induced resistance anisotropy in quasi-free-standing bilayer chemical vapor deposition graphene on SiC

    SciTech Connect

    Ciuk, Tymoteusz; Cakmakyapan, Semih; Ozbay, Ekmel; Caban, Piotr; Grodecki, Kacper; Pasternak, Iwona; Strupinski, Wlodek; Krajewska, Aleksandra; Szmidt, Jan

    2014-09-28

    The transport properties of quasi-free-standing (QFS) bilayer graphene on SiC depend on a range of scattering mechanisms. Most of them are isotropic in nature. However, the SiC substrate morphology marked by a distinctive pattern of the terraces gives rise to an anisotropy in graphene's sheet resistance, which may be considered an additional scattering mechanism. At a technological level, the growth-preceding in situ etching of the SiC surface promotes step bunching which results in macro steps ~10 nm in height. In this report, we study the qualitative and quantitative effects of SiC steps edges on the resistance of epitaxial graphene grown by chemical vapor deposition. We experimentally determine the value of step edge resistivity in hydrogen-intercalated QFS-bilayer graphene to be ~190 Ωμm for step height hS = 10 nm and provide proof that it cannot originate from mechanical deformation of graphene but is likely to arise from lowered carrier concentration in the step area. Our results are confronted with the previously reported values of the step edge resistivity in monolayer graphene over SiC atomic steps. In our analysis, we focus on large-scale, statistical properties to foster the scalable technology of industrial graphene for electronics and sensor applications.

  14. Theoretical assessment of feasibility to sequence DNA through interlayer electronic tunneling transport at aligned nanopores in bilayer graphene

    PubMed Central

    Prasongkit, Jariyanee; Feliciano, Gustavo T.; Rocha, Alexandre R.; He, Yuhui; Osotchan, Tanakorn; Ahuja, Rajeev; Scheicher, Ralph H.

    2015-01-01

    Fast, cost effective, single-shot DNA sequencing could be the prelude of a new era in genetics. As DNA encodes the information for the production of proteins in all known living beings on Earth, determining the nucleobase sequences is the first and necessary step in that direction. Graphene-based nanopore devices hold great promise for next-generation DNA sequencing. In this work, we develop a novel approach for sequencing DNA using bilayer graphene to read the interlayer conductance through the layers in the presence of target nucleobases. Classical molecular dynamics simulations of DNA translocation through the pore were performed to trace the nucleobase trajectories and evaluate the interaction between the nucleobases and the nanopore. This interaction stabilizes the bases in different orientations, resulting in smaller fluctuations of the nucleobases inside the pore. We assessed the performance of a bilayer graphene nanopore setup for the purpose of DNA sequencing by employing density functional theory and non-equilibrium Green’s function method to investigate the interlayer conductance of nucleobases coupling simultaneously to the top and bottom graphene layers. The obtained conductance is significantly affected by the presence of DNA in the bilayer graphene nanopore, allowing us to analyze DNA sequences. PMID:26634811

  15. Theoretical assessment of feasibility to sequence DNA through interlayer electronic tunneling transport at aligned nanopores in bilayer graphene

    NASA Astrophysics Data System (ADS)

    Prasongkit, Jariyanee; Feliciano, Gustavo T.; Rocha, Alexandre R.; He, Yuhui; Osotchan, Tanakorn; Ahuja, Rajeev; Scheicher, Ralph H.

    2015-12-01

    Fast, cost effective, single-shot DNA sequencing could be the prelude of a new era in genetics. As DNA encodes the information for the production of proteins in all known living beings on Earth, determining the nucleobase sequences is the first and necessary step in that direction. Graphene-based nanopore devices hold great promise for next-generation DNA sequencing. In this work, we develop a novel approach for sequencing DNA using bilayer graphene to read the interlayer conductance through the layers in the presence of target nucleobases. Classical molecular dynamics simulations of DNA translocation through the pore were performed to trace the nucleobase trajectories and evaluate the interaction between the nucleobases and the nanopore. This interaction stabilizes the bases in different orientations, resulting in smaller fluctuations of the nucleobases inside the pore. We assessed the performance of a bilayer graphene nanopore setup for the purpose of DNA sequencing by employing density functional theory and non-equilibrium Green’s function method to investigate the interlayer conductance of nucleobases coupling simultaneously to the top and bottom graphene layers. The obtained conductance is significantly affected by the presence of DNA in the bilayer graphene nanopore, allowing us to analyze DNA sequences.

  16. Theoretical assessment of feasibility to sequence DNA through interlayer electronic tunneling transport at aligned nanopores in bilayer graphene.

    PubMed

    Prasongkit, Jariyanee; Feliciano, Gustavo T; Rocha, Alexandre R; He, Yuhui; Osotchan, Tanakorn; Ahuja, Rajeev; Scheicher, Ralph H

    2015-01-01

    Fast, cost effective, single-shot DNA sequencing could be the prelude of a new era in genetics. As DNA encodes the information for the production of proteins in all known living beings on Earth, determining the nucleobase sequences is the first and necessary step in that direction. Graphene-based nanopore devices hold great promise for next-generation DNA sequencing. In this work, we develop a novel approach for sequencing DNA using bilayer graphene to read the interlayer conductance through the layers in the presence of target nucleobases. Classical molecular dynamics simulations of DNA translocation through the pore were performed to trace the nucleobase trajectories and evaluate the interaction between the nucleobases and the nanopore. This interaction stabilizes the bases in different orientations, resulting in smaller fluctuations of the nucleobases inside the pore. We assessed the performance of a bilayer graphene nanopore setup for the purpose of DNA sequencing by employing density functional theory and non-equilibrium Green's function method to investigate the interlayer conductance of nucleobases coupling simultaneously to the top and bottom graphene layers. The obtained conductance is significantly affected by the presence of DNA in the bilayer graphene nanopore, allowing us to analyze DNA sequences. PMID:26634811

  17. Reply to "Comment on `Creating in-plane pseudomagnetic fields in excess of 1000 T by misoriented stacking in a graphene bilayer' "

    NASA Astrophysics Data System (ADS)

    He, Wen-Yu; Su, Ying; Yang, Mudan; He, Lin

    2016-06-01

    In the Comment, the authors argue that due to the different symmetry properties, the comparison between the twisting and in-plane magnetic field in bilayer graphene fails. However, we do not think it addresses the main result of our work. Here from the perspective of tunable chirality and quantum transmission signature, we review the feature shared by twisting and in-plane magnetic field in bilayer graphene and show that the Comment does not contradict our main results.

  18. Phase diagram of the Kohn-Luttinger superconducting state for bilayer graphene

    NASA Astrophysics Data System (ADS)

    Kagan, Maxim Yu.; Mitskan, Vitaly A.; Korovushkin, Maxim M.

    2015-06-01

    The effect of Coulomb interaction between Dirac fermions on the formation of the Kohn-Luttinger superconducting state in bilayer doped graphene is studied disregarding of the effect of the van der Waals potential of the substrate and impurities. The phase diagram determining the boundaries of superconductive domains with different types of symmetry of the order parameter is built using the extended Hubbard model in the Born weak-coupling approximation with allowance for the intratomic, interatomic, and interlayer Coulomb interactions between electrons. It is shown that the Kohn-Luttinger polarization contributions up to the second order of perturbation theory in the Coulomb interaction inclusively and an account for the long-range intraplane Coulomb interactions significantly affect the competition between the superconducting phases with the f-, p + ip-, and d + id-wave symmetries of the order parameter. It is demonstrated that the account for the interlayer Coulomb interaction enhances the critical temperature of the transition to the superconducting phase.

  19. Periodic Landau gauge and quantum Hall effect in twisted bilayer graphene

    NASA Astrophysics Data System (ADS)

    Hasegawa, Yasumasa; Kohmoto, Mahito

    2013-09-01

    Energy versus magnetic field (Hofstadter butterfly diagram) in twisted bilayer graphene is studied theoretically. If we take the usual Landau gauge, we cannot take a finite periodicity even when the magnetic flux through a supercell is a rational number. We show that the periodic Landau gauge, which has the periodicity in one direction, makes it possible to obtain the Hofstadter butterfly diagram. Since a supercell can be large, magnetic flux through a supercell normalized by the flux quantum can be a fractional number with a small denominator, even when a magnetic field is not extremely strong. As a result, quantized Hall conductance can be a solution of the Diophantine equation which cannot be obtained by the approximation of the linearized energy dispersion near the Dirac points.

  20. Impurity effects on electrical conductivity of doped bilayer graphene in the presence of a bias voltage

    NASA Astrophysics Data System (ADS)

    E, Lotfi; H, Rezania; B, Arghavaninia; M, Yarmohammadi

    2016-07-01

    We address the electrical conductivity of bilayer graphene as a function of temperature, impurity concentration, and scattering strength in the presence of a finite bias voltage at finite doping, beginning with a description of the tight-binding model using the linear response theory and Green’s function approach. Our results show a linear behavior at high doping for the case of high bias voltage. The effects of electron doping on the electrical conductivity have been studied via changing the electronic chemical potential. We also discuss and analyze how the bias voltage affects the temperature behavior of the electrical conductivity. Finally, we study the behavior of the electrical conductivity as a function of the impurity concentration and scattering strength for different bias voltages and chemical potentials respectively. The electrical conductivity is found to be monotonically decreasing with impurity scattering strength due to the increased scattering among electrons at higher impurity scattering strength.

  1. Superfluid-insulator transition of quantum Hall domain walls in bilayer graphene

    NASA Astrophysics Data System (ADS)

    Mazo, Victoria; Huang, Chia-Wei; Shimshoni, Efrat; Carr, Sam T.; Fertig, H. A.

    2014-03-01

    We consider the ν =0 quantum Hall ferromagnetic state of bilayer graphene subject to a kinklike perpendicular electric field, which generates domain walls in the electronic state and low-energy collective modes confined to move along them. In particular, it is shown that two pairs of collective helical modes are formed at opposite sides of the kink, each pair consisting of modes with identical helicities. We derive an effective field-theoretical model of these modes in terms of two weakly coupled anisotropic quantum spin ladders, with parameters tunable through control of the electric and magnetic fields. This yields a rich phase diagram, where, due to the helical nature of the modes, distinct phases possess very different charge conduction properties. Most notably, this system can potentially exhibit a transition from a superfluid to an insulating phase.

  2. Bilayer graphene under pressure: Electron-hole symmetry breaking, valley Hall effect, and Landau levels

    NASA Astrophysics Data System (ADS)

    Munoz, F.; Collado, H. P. Ojeda; Usaj, Gonzalo; Sofo, Jorge O.; Balseiro, C. A.

    2016-06-01

    The electronic structure of bilayer graphene under pressure develops very interesting features with an enhancement of the trigonal warping and a splitting of the parabolic touching bands at the K point of the reciprocal space into four Dirac cones, one at K and three along the T symmetry lines. As pressure is increased, these cones separate in reciprocal space and in energy, breaking the electron-hole symmetry. Due to their energy separation, their opposite Berry curvature can be observed in valley Hall effect experiments and in the structure of the Landau levels. Based on the electronic structure obtained by density functional theory, we develop a low energy Hamiltonian that describes the effects of pressure on measurable quantities such as the Hall conductivity and the Landau levels of the system.

  3. Chirality-assisted electronic cloaking of confined States in bilayer graphene.

    PubMed

    Gu, Nan; Rudner, Mark; Levitov, Leonid

    2011-10-01

    We show that the strong coupling of pseudospin orientation and charge carrier motion in bilayer graphene has a drastic effect on transport properties of ballistic p-n-p junctions. Electronic states with zero momentum parallel to the barrier are confined under it for one pseudospin orientation, whereas states with the opposite pseudospin tunnel through the junction totally uninfluenced by the presence of confined states. We demonstrate that the junction acts as a cloak for confined states, making them nearly invisible to electrons in the outer regions over a range of incidence angles. This behavior is manifested in the two-terminal conductance as transmission resonances with non-Lorentzian, singular peak shapes. The response of these phenomena to a weak magnetic field or electric-field-induced interlayer gap can serve as an experimental fingerprint of electronic cloaking. PMID:22107310

  4. Strong interaction effects at a Fermi surface in a model for voltage-biased bilayer graphene

    NASA Astrophysics Data System (ADS)

    Armour, Wes; Hands, Simon; Strouthos, Costas

    2015-12-01

    Monte Carlo simulation of a 2+1 dimensional model of voltage-biased bilayer graphene, consisting of relativistic fermions with chemical potential μ coupled to charged excitations with opposite sign on each layer, has exposed noncanonical scaling of bulk observables near a quantum critical point found at strong coupling. We present a calculation of the quasiparticle dispersion relation E (k ) as a function of exciton source j in the same system, employing partially twisted boundary conditions to boost the number of available momentum modes. The Fermi momentum kF and superfluid gap Δ are extracted in the j →0 limit for three different values of μ , and support a strongly interacting scenario at the Fermi surface with Δ ˜O (μ ) . We propose an explanation for the observation μ

  5. Spin- and valley-coupled electronic states in monolayer WSe{sub 2} on bilayer graphene

    SciTech Connect

    Sugawara, K.; Souma, S.; Sato, T.; Tanaka, Y.; Takahashi, T.

    2015-08-17

    We have fabricated a high-quality monolayer WSe{sub 2} film on bilayer graphene by epitaxial growth and revealed the electronic states by spin- and angle-resolved photoemission spectroscopy. We observed a direct energy gap at the Brillouin-zone corner in contrast to the indirect nature of gap in bulk WSe{sub 2}, which is attributed to the lack of interlayer interaction and the breaking of space-inversion symmetry in monolayer film. A giant spin splitting of ∼0.5 eV, which is the largest among known monolayer transition-metal dichalcogenides, is observed in the energy band around the zone corner. The present results suggest a high potential applicability of WSe{sub 2} to develop advanced devices based with the coupling of spin- and valley-degrees of freedom.

  6. Highly bendable bilayer-type photo-actuators comprising of reduced graphene oxide dispersed in hydrogels

    PubMed Central

    Kim, Dowan; Lee, Heon Sang; Yoon, Jinhwan

    2016-01-01

    To avoid the problem of reduced graphene oxide (rGO) restacking in aqueous solution, the preparation of light-responsive poly(N-isopropylacrylamide) incorporating rGO (PNIPAm/rGO) was achieved by the chemical reduction of GO dispersed in the hydrogel matrix. Due to the enhanced photothermal efficiency of the rGO, the prepared PNIPAm/rGO underwent large volume reductions in response to irradiation by visible light of modest intensity. With respect to potential applications, bilayer-type photo-actuators comprising a PNIPAm/rGO active layer and poly(acrylamide) passive layer were fabricated; these achieved a full bending motion upon visible-light exposure. Adjusting the swelling ratio of each layer in the initial state yielded bidirectional photo-actuators that showed the active motion of turning inside out. Furthermore, we demonstrated that the fabricated actuation system would exhibit controlled bending motion in response to solar radiation. PMID:26865239

  7. Highly bendable bilayer-type photo-actuators comprising of reduced graphene oxide dispersed in hydrogels

    NASA Astrophysics Data System (ADS)

    Kim, Dowan; Lee, Heon Sang; Yoon, Jinhwan

    2016-02-01

    To avoid the problem of reduced graphene oxide (rGO) restacking in aqueous solution, the preparation of light-responsive poly(N-isopropylacrylamide) incorporating rGO (PNIPAm/rGO) was achieved by the chemical reduction of GO dispersed in the hydrogel matrix. Due to the enhanced photothermal efficiency of the rGO, the prepared PNIPAm/rGO underwent large volume reductions in response to irradiation by visible light of modest intensity. With respect to potential applications, bilayer-type photo-actuators comprising a PNIPAm/rGO active layer and poly(acrylamide) passive layer were fabricated; these achieved a full bending motion upon visible-light exposure. Adjusting the swelling ratio of each layer in the initial state yielded bidirectional photo-actuators that showed the active motion of turning inside out. Furthermore, we demonstrated that the fabricated actuation system would exhibit controlled bending motion in response to solar radiation.

  8. Fast pick up technique for high quality heterostructures of bilayer graphene and hexagonal boron nitride

    SciTech Connect

    Zomer, P. J. Guimarães, M. H. D.; Brant, J. C.; Tombros, N.; Wees, B. J. van

    2014-07-07

    We present a fast method to fabricate high quality heterostructure devices by picking up crystals of arbitrary sizes. Bilayer graphene is encapsulated with hexagonal boron nitride to demonstrate this approach, showing good electronic quality with mobilities ranging from 17 000 cm{sup 2} V{sup −1} s{sup −1} at room temperature to 49 000 cm{sup 2} V{sup −1} s{sup −1} at 4.2 K, and entering the quantum Hall regime below 0.5 T. This method provides a strong and useful tool for the fabrication of future high quality layered crystal devices.

  9. Chirality-Assisted Electronic Cloaking of Confined States in Bilayer Graphene

    NASA Astrophysics Data System (ADS)

    Gu, Nan; Rudner, Mark; Levitov, Leonid

    2011-10-01

    We show that the strong coupling of pseudospin orientation and charge carrier motion in bilayer graphene has a drastic effect on transport properties of ballistic p-n-p junctions. Electronic states with zero momentum parallel to the barrier are confined under it for one pseudospin orientation, whereas states with the opposite pseudospin tunnel through the junction totally uninfluenced by the presence of confined states. We demonstrate that the junction acts as a cloak for confined states, making them nearly invisible to electrons in the outer regions over a range of incidence angles. This behavior is manifested in the two-terminal conductance as transmission resonances with non-Lorentzian, singular peak shapes. The response of these phenomena to a weak magnetic field or electric-field-induced interlayer gap can serve as an experimental fingerprint of electronic cloaking.

  10. Magnetic field dependence of energy levels in biased bilayer graphene quantum dots

    NASA Astrophysics Data System (ADS)

    da Costa, D. R.; Zarenia, M.; Chaves, Andrey; Farias, G. A.; Peeters, F. M.

    2016-02-01

    Using the tight-binding approach, we study the influence of a perpendicular magnetic field on the energy levels of hexagonal, triangular, and circular bilayer graphene (BLG) quantum dots (QDs) with zigzag and armchair edges. We obtain the energy levels for AB (Bernal)-stacked BLG QDs in both the absence and the presence of a perpendicular electric field (i.e., biased BLG QDs). We find different regions in the spectrum of biased QDs with respect to the crossing point between the lowest-electron and -hole Landau levels of a biased BLG sheet. Those different regions correspond to electron states that are localized at the center, edge, or corner of the BLG QD. Quantum Hall corner states are found to be absent in circular BLG QDs. The spatial symmetry of the carrier density distribution is related to the symmetry of the confinement potential, the position of zigzag edges, and the presence or absence of interlayer inversion symmetry.

  11. Electronic triple-dot transport through a bilayer graphene island with ultrasmall constrictions

    NASA Astrophysics Data System (ADS)

    Bischoff, D.; Varlet, A.; Simonet, P.; Ihn, T.; Ensslin, K.

    2013-08-01

    A quantum dot has been etched in bilayer graphene connected by two small constrictions to the leads. We show that this structure does not behave like a single quantum dot but consists of at least three sites of localized charge in series. The high symmetry and electrical stability of the device allowed us to triangulate the positions of the different sites of localized charge and find that one site is located in the island and one in each of the constrictions. Nevertheless we measure many consecutive non-overlapping Coulomb-diamonds in series. In order to describe these findings, we treat the system as a strongly coupled serial triple quantum dot. We find that the non-overlapping Coulomb diamonds arise due to higher order cotunneling through the outer dots located in the constrictions. We extract all relevant capacitances, simulate the measured data with a capacitance model and discuss its implications on electrical transport.

  12. Electric-field-dependent electronic structure of graphene bilayer: from the Bernal stacking to the unconventional orthorhombic stacking

    NASA Astrophysics Data System (ADS)

    Kim, Gunn; Park, Changwon; Yoon, Mina

    2014-03-01

    In this presentation, we report the electronic properties of bilayer graphene structures with various stackings, which can be formed, for instance, during the structural transition from graphite-to-diamond at high pressure, or at boundaries of stacking domains or at diamond surfaces. We performed ab initio calculations and the Wannier interpolations for accurate two-dimensional band structure with extremely dense (1600 ×1600) k-point grid. Using tight-binding parameters obtained from maximally localized Wanneir function analysis, we also constructed the effective Hamiltonian for the graphene bilayer with various stacking. The overall electronic structures can be described by the relative shift and the coupling of two Dirac cones, depending on their stacking geometry. Our results reveal that external electric field is another parameter to control the electronic properties of the bilayer-graphene. In particular, the external fields significantly enhance the coupling of two Dirac cones, which result in additional or new van Hove singularities near the Fermi level. We compared the electronic structure of the orthorhombic stacking with those of AA and AB stackings. Our study may provide a deeper understanding of sliding effects of multilayer graphene. This work was supported by the Priority Research Center Program (2011-0018395) and the Basic Science Research Program through MEST/NRF (2013R1A1A2009131). This research was conducted at the Center for Nanophase Materials Sciences, which is sponsored at Oak Ridge National Laboratory by the Office of Basic Energy Sciences, U.S. Department of Energy.

  13. Interactions of Graphene Oxide with Model Cell Membranes: Probing Nanoparticle Attachment and Lipid Bilayer Disruption.

    PubMed

    Liu, Xitong; Chen, Kai Loon

    2015-11-10

    With the rapid growth in the application of graphene oxide (GO) in diverse fields, the toxicity of GO toward bacterial and mammalian cells has recently attracted extensive research attention. While several mechanisms have been proposed for the cytotoxicity of GO, the attachment of GO to cell membranes is expected to be the key initial process that precedes these mechanisms. In this study, we investigate the propensity for GO to attach to and disrupt model cell membranes using supported lipid bilayers (SLBs) and supported vesicular layers (SVLs) that are composed of zwitterionic 1,2-dioleoyl-sn-glycero-3-phosphocholine (DOPC). The deposition kinetics of GO on SLBs were determined using quartz crystal microbalance with dissipation monitoring and were observed to increase with increasing electrolyte (NaCl and CaCl2) concentrations, indicating that GO attachment to SLBs was controlled by electrostatic interactions. The GO deposition kinetics measured at elevated electrolyte concentrations were lower than mass-transfer-limited kinetics, likely due to the presence of hydration forces between GO and SLBs. Upon the attachment of GO to supported vesicles that were encapsulated with a fluorescent dye, dye leakage was detected, thus indicating that the lipid vesicles were disrupted. When the exposure of the SVL to the GO suspension was terminated, the leakage of dye decreased significantly, demonstrating that the pores on the lipid bilayers have a self-healing ability. PMID:26466194

  14. Interfacial thermal conductance of a silicene/graphene bilayer heterostructure and the effect of hydrogenation.

    PubMed

    Liu, Bo; Baimova, Julia A; Reddy, Chilla D; Law, Adrian Wing-Keung; Dmitriev, Sergey V; Wu, Hong; Zhou, Kun

    2014-10-22

    van der Waals heterostructures, obtained by stacking layers of isolated two-dimensional atomic crystals like graphene (GE) and silicene (SE), are one of emerging nanomaterials for the development of future multifunctional devices. Thermal transport behaviors at the interface of these heterostructures play a pivotal role in determining their thermal properties and functional performance. Using molecular dynamics simulations, the interfacial thermal conductance G of an SE/GE bilayer heterostructure is studied. Simulations show that G of a pristine SE/GE bilayer at room temperature is 11.74 MW/m(2)K when heat transfers from GE to SE, and is 9.52 MW/m(2)K for a reverse heat transfer, showing apparent thermal rectification effects. In addition, G increases monotonically with both the temperature and the interface coupling strength. Furthermore, hydrogenation of GE is efficient in enhancing G if an optimum hydrogenation pattern is adopted. By changing the hydrogen coverage f, G can be controllably manipulated and maximized up to five times larger than that of pristine SE/GE. This study is helpful for understanding the interface thermal transport behaviors of novel van der Waals heterostructures and provides guidance for the design and control of their thermal properties. PMID:25308778

  15. Interaction-Induced Dirac Fermions from Quadratic Band Touching in Bilayer Graphene.

    PubMed

    Pujari, Sumiran; Lang, Thomas C; Murthy, Ganpathy; Kaul, Ribhu K

    2016-08-19

    We revisit the effect of local interactions on the quadratic band touching (QBT) of the Bernal honeycomb bilayer model using renormalization group (RG) arguments and quantum Monte Carlo (QMC) simulations. We present a RG argument which predicts, contrary to previous studies, that weak interactions do not flow to strong coupling even if the free dispersion has a QBT. Instead, they generate a linear term in the dispersion, which causes the interactions to flow back to weak coupling. Consistent with this RG scenario, in unbiased QMC simulations of the Hubbard model we find compelling evidence that antiferromagnetism turns on at a finite U/t despite the U=0 hopping problem having a QBT. The onset of antiferromagnetism takes place at a continuous transition which is consistent with (2+1)D Gross-Neveu criticality. We conclude that generically in models of bilayer graphene, even if the free dispersion has a QBT, small local interactions generate a Dirac phase with no symmetry breaking and that there is a finite-coupling transition out of this phase to a symmetry-broken state. PMID:27588872

  16. Josephson coupling between superconducting islands on single- and bi-layer graphene

    NASA Astrophysics Data System (ADS)

    Mancarella, Francesco; Fransson, Jonas; Balatsky, Alexander

    2016-05-01

    We study the Josephson coupling of superconducting (SC) islands through the surface of single-layer graphene (SLG) and bilayer graphene (BLG) in the long-junction regime, as a function of the distance between the grains, temperature, chemical potential and external (transverse) gate-voltage. For SLG, we provide a comparison with existing literature. The proximity effect is analyzed through a Matsubara Green’s function approach. This represents the first step in a discussion of the conditions for the onset of a granular superconductivity within the film, made possible by Josephson currents flowing between superconductors. To ensure phase coherence over the 2D sample, a random spatial distribution can be assumed for the SC islands on the SLG sheet (or intercalating the BLG sheets). The tunable gate-voltage-induced band gap of BLG affects the asymptotic decay of the Josephson coupling-distance characteristic for each pair of SC islands in the sample, which results in a qualitatively strong field dependence of the relation between Berezinskii–Kosterlitz–Thouless transition critical temperature and gate voltage.

  17. Nonlinear dynamics of bi-layered graphene sheet, double-walled carbon nanotube and nanotube bundle

    NASA Astrophysics Data System (ADS)

    Gajbhiye, Sachin O.; Singh, S. P.

    2016-05-01

    Due to strong van der Waals (vdW) interactions, the graphene sheets and nanotubes stick to each other and form clusters of these corresponding nanostructures, viz. bi-layered graphene sheet (BLGS), double-walled carbon nanotube (DWCNT) and nanotube bundle (NB) or ropes. This research work is concerned with the study of nonlinear dynamics of BLGS, DWCNT and NB due to nonlinear interlayer vdW forces using multiscale atomistic finite element method. The energy between two adjacent carbon atoms is represented by the multibody interatomic Tersoff-Brenner potential, whereas the nonlinear interlayer vdW forces are represented by Lennard-Jones 6-12 potential function. The equivalent nonlinear material model of carbon-carbon bond is used to model it based on its force-deflection relation. Newmark's algorithm is used to solve the nonlinear matrix equation governing the motion of the BLGS, DWCNT and NB. An impulse and harmonic excitations are used to excite these nanostructures under cantilevered, bridged and clamped boundary conditions. The frequency responses of these nanostructures are computed, and the dominant resonant frequencies are identified. Along with the forced vibration of these structures, the eigenvalue extraction problem of armchair and zigzag NB is also considered. The natural frequencies and corresponding mode shapes are extracted for the different length and boundary conditions of the nanotube bundle.

  18. Strain-induced modulation of Dirac cones and van Hove singularities in a twisted graphene bilayer

    NASA Astrophysics Data System (ADS)

    Nguyen, V. Hung; Dollfus, P.

    2015-09-01

    By means of atomistic calculations, we investigate the effects of uniaxial strain on the electronic bandstructure of a twisted graphene bilayer (T-GBL). We find that the bandstructure is dramatically deformed and the degeneracy of the bands around the Dirac points is broken by strain. As a consequence, the number of valleys in the bandstructure can double and the van Hove singularity (VHS) points are separated in energy. The dependence of these effects on the magnitude of strain, its applied direction and the twist angle is carefully examined and clarified. As an important result, we demonstrate that the position of VHSs can be modulated by strain, suggesting the possibility of observing this peculiar feature of the bandstructure at low energy in a large range of twist angles (i.e., larger than 10°). These phenomena could not be detected within the continuum approximation used in previous works. While they are in good agreement with available experimental data, our results provide a detailed understanding of the strain effects on the electronic properties of T-GBLs and may motivate further investigations of electronic transport in this type of graphene lattice.

  19. Enhancement of electron-phonon coupling in Cs-overlayered intercalated bilayer graphene.

    PubMed

    Kleeman, J; Sugawara, K; Sato, T; Takahashi, T

    2016-05-25

    We have performed high-resolution angle-resolved photoemission spectroscopy (ARPES) on cesium (Cs) intercalated bilayer graphene with a Cs overlayer (Cs-C8CsC8). Low-energy electron diffraction shows a (2  ×  2) pattern consistent with intercalation of a Cs layer similar to bulk C8Cs, in addition to the signature of a nearly commensurate superstructure created by the Cs overlayer. ARPES results reveal folding of the π bands due to the periodic (2  ×  2) potential of the intercalated Cs atoms, together with a free-electron-like state at the [Formula: see text] point. Significant mass renormalization is observed in the band dispersion near the Fermi level, indicative of strong electron-phonon coupling. Based on analysis of the self-energy, we find anisotropic electron-phonon coupling with an estimated strength of [Formula: see text]  ±  0.02 in the K-[Formula: see text] direction, and [Formula: see text] in the K-M direction. This coupling is much larger than that of other doped graphenes, and comparable to superconducting bulk GICs. We attribute this large electron-phonon coupling constant to the presence of the Cs overlayer, which highly dopes [Formula: see text] bands, and creates a structure similar to stage-I graphite intercalation compounds. PMID:27094681

  20. Building Large-Domain Twisted Bilayer Graphene with van Hove Singularity.

    PubMed

    Tan, Zhenjun; Yin, Jianbo; Chen, Cheng; Wang, Huan; Lin, Li; Sun, Luzhao; Wu, Jinxiong; Sun, Xiao; Yang, Haifeng; Chen, Yulin; Peng, Hailin; Liu, Zhongfan

    2016-07-26

    Twisted bilayer graphene (tBLG) with van Hove Singularity (VHS) has exhibited novel twist-angle-dependent chemical and physical phenomena. However, scalable production of high-quality tBLG is still in its infancy, especially lacking the angle controlled preparation methods. Here, we report a facile approach to prepare tBLG with large domain sizes (>100 μm) and controlled twist angles by a clean layer-by-layer transfer of two constituent graphene monolayers. The whole process without interfacial polymer contamination in two monolayers guarantees the interlayer interaction of the π-bond electrons, which gives rise to the existence of minigaps in electronic structures and the consequent formation of VHSs in density of state. Such perturbation on band structure was directly observed by angle-resolved photoemission spectroscopy with submicrometer spatial resolution (micro-ARPES). The VHSs lead to a strong light-matter interaction and thus introduce ∼20-fold enhanced intensity of Raman G-band, which is a characteristic of high-quality tBLG. The as-prepared tBLG with strong light-matter interaction was further fabricated into high-performance photodetectors with selectively enhanced photocurrent generation (up to ∼6 times compared with monolayer in our device). PMID:27163879

  1. High-coverage stable structures of 3d transition metal intercalated bilayer graphene.

    PubMed

    Liao, Ji-Hai; Zhao, Yu-Jun; Tang, Jia-Jun; Yang, Xiao-Bao; Xu, Hu

    2016-06-01

    Alkali-metal intercalated graphite and graphene have been intensively studied for decades, where alkali-metal atoms are found to form ordered structures at the hollow sites of hexagonal carbon rings. Using first-principles calculations, we have predicted various stable structures of high-coverage 3d transition metal (TM) intercalated bilayer graphene (BLG) stabilized by the strain. Specifically, with reference to the bulk metal, Sc and Ti can form stable TM-intercalated BLG without strain, while the stabilization of Fe, Co, and Ni intercalated BLG requires the biaxial strain of over 7%. Under the biaxial strain ranging from 0% to 10%, there are four ordered sandwich structures for Sc with the coverage of 0.25, 0.571, 0.684, and 0.75, in which the Sc atoms are all distributed homogenously instead of locating at the hollow sites. According to the phase diagram, a homogenous configuration of C8Ti3C8 with the coverage of 0.75 and another inhomogeneous structure with the coverage of 0.692 were found. The electronic and magnetic properties as a function of strain were also analyzed to indicate that the strain was important for the stabilities of the high-coverage TM-intercalated BLG. PMID:27167998

  2. Enhancement of electron–phonon coupling in Cs-overlayered intercalated bilayer graphene

    NASA Astrophysics Data System (ADS)

    Kleeman, J.; Sugawara, K.; Sato, T.; Takahashi, T.

    2016-05-01

    We have performed high-resolution angle-resolved photoemission spectroscopy (ARPES) on cesium (Cs) intercalated bilayer graphene with a Cs overlayer (Cs-C8CsC8). Low-energy electron diffraction shows a (2  ×  2) pattern consistent with intercalation of a Cs layer similar to bulk C8Cs, in addition to the signature of a nearly commensurate superstructure created by the Cs overlayer. ARPES results reveal folding of the π bands due to the periodic (2  ×  2) potential of the intercalated Cs atoms, together with a free-electron-like state at the Γ point. Significant mass renormalization is observed in the band dispersion near the Fermi level, indicative of strong electron–phonon coupling. Based on analysis of the self-energy, we find anisotropic electron–phonon coupling with an estimated strength of λ =0.38   ±  0.02 in the K-Γ direction, and λ =0.60+/- 0.02 in the K-M direction. This coupling is much larger than that of other doped graphenes, and comparable to superconducting bulk GICs. We attribute this large electron–phonon coupling constant to the presence of the Cs overlayer, which highly dopes {π\\ast} bands, and creates a structure similar to stage-I graphite intercalation compounds.

  3. NanoARPES of twisted bilayer graphene on SiC: absence of velocity renormalization for small angles

    PubMed Central

    Razado-Colambo, I.; Avila, J.; Nys, J.-P.; Chen, C.; Wallart, X.; Asensio, M.-C.; Vignaud, D.

    2016-01-01

    The structural and electronic properties of twisted bilayer graphene (TBG) on SiC(000) grown by Si flux-assisted molecular beam epitaxy were investigated using scanning tunneling microscopy (STM) and angle-resolved photoelectron spectroscopy with nanometric spatial resolution. STM images revealed a wide distribution of twist angles between the two graphene layers. The electronic structure recorded in single TBG grains showed two closely-spaced Dirac π bands associated to the two stacked layers with respective twist angles in the range 1–3°. The renormalization of velocity predicted in previous theoretical calculations for small twist angles was not observed. PMID:27264791

  4. NanoARPES of twisted bilayer graphene on SiC: absence of velocity renormalization for small angles.

    PubMed

    Razado-Colambo, I; Avila, J; Nys, J-P; Chen, C; Wallart, X; Asensio, M-C; Vignaud, D

    2016-01-01

    The structural and electronic properties of twisted bilayer graphene (TBG) on SiC(000) grown by Si flux-assisted molecular beam epitaxy were investigated using scanning tunneling microscopy (STM) and angle-resolved photoelectron spectroscopy with nanometric spatial resolution. STM images revealed a wide distribution of twist angles between the two graphene layers. The electronic structure recorded in single TBG grains showed two closely-spaced Dirac π bands associated to the two stacked layers with respective twist angles in the range 1-3°. The renormalization of velocity predicted in previous theoretical calculations for small twist angles was not observed. PMID:27264791

  5. NanoARPES of twisted bilayer graphene on SiC: absence of velocity renormalization for small angles

    NASA Astrophysics Data System (ADS)

    Razado-Colambo, I.; Avila, J.; Nys, J.-P.; Chen, C.; Wallart, X.; Asensio, M.-C.; Vignaud, D.

    2016-06-01

    The structural and electronic properties of twisted bilayer graphene (TBG) on SiC(000) grown by Si flux-assisted molecular beam epitaxy were investigated using scanning tunneling microscopy (STM) and angle-resolved photoelectron spectroscopy with nanometric spatial resolution. STM images revealed a wide distribution of twist angles between the two graphene layers. The electronic structure recorded in single TBG grains showed two closely-spaced Dirac π bands associated to the two stacked layers with respective twist angles in the range 1–3°. The renormalization of velocity predicted in previous theoretical calculations for small twist angles was not observed.

  6. Bilayer graphene with parallel magnetic field and twisting: Phases and phase transitions in a highly tunable Dirac system

    NASA Astrophysics Data System (ADS)

    Yang, Kun; Roy, Bitan

    2014-03-01

    The effective theory for bi-layer graphene, subject to parallel/in-plane magnetic fields is discussed. We show that with a sizable in-plane magnetic field the trigonal warping becomes irrelevant, and one ends up with two Dirac points in the vicinity of each valleys in the low-energy limit, similar to the twisted bi-layer graphene. Combining twisting and parallel field thus gives rise to a Dirac system with tunable Fermi velocity and ultra violet cutoff. If the interactions are sufficiently strong, several fully gapped states can be realized in these systems, in addition to the ones in pristine setup. Symmetry based classification of the order parameters will be discussed. We also present the quantum critical behavior of various phase transitions driven by the twisting and the magnetic field. Effects of an additional perpendicular fields, and possible ways to realize the some of the new massive phases will be highlighted.

  7. In Situ Tuning of Switching Window in a Gate-Controlled Bilayer Graphene-Electrode Resistive Memory Device.

    PubMed

    Tian, He; Zhao, Haiming; Wang, Xue-Feng; Xie, Qian-Yi; Chen, Hong-Yu; Mohammad, Mohammad Ali; Li, Cheng; Mi, Wen-Tian; Bie, Zhi; Yeh, Chao-Hui; Yang, Yi; Wong, H-S Philip; Chiu, Po-Wen; Ren, Tian-Ling

    2015-12-16

    A resistive random access memory (RRAM) device with a tunable switching window is demonstrated for the first time. The SET voltage can be continuously tuned from 0.27 to 4.5 V by electrical gating from -10 to +35 V. The gate-controlled bilayer graphene-electrode RRAM can function as 1D1R and potentially increase the RRAM density. PMID:26500160

  8. Perfect spin filtering controlled by an electric field in a bilayer graphene junction: Effect of layer-dependent exchange energy

    NASA Astrophysics Data System (ADS)

    Kitakorn, Jatiyanon; I-Ming, Tang; Bumned, Soodchomshom

    2016-07-01

    Magneto transport of carriers with a spin-dependent gap in a ferromagnetic-gated bilayer of graphene is investigated. We focus on the effect of an energy gap induced by the mismatch of the exchange fields in the top and bottom layers of an AB-stacked graphene bilayer. The interplay of the electric and exchange fields causes the electron to acquire a spin-dependent energy gap. We find that, only in the case of the anti-parallel configuration, the effect of a magnetic-induced gap will give rise to perfect spin filtering controlled by the electric field. The resolution of the spin filter may be enhanced by varying the bias voltage. Perfect switching of the spin polarization from + 100% to ‑100% by reversing the direction of electric field is predicted. Giant magnetoresistance is predicted to be easily realized when the applied electric field is smaller than the magnetic energy gap. It should be pointed out that the perfect spin filter is due to the layer-dependent exchange energy. This work points to the potential application of bilayer graphene in spintronics. Project supported by the Kasetsart University Research and Development Institute (KURDI) and Thailand Research Fund (TRF) (Grant No. TRG5780274).

  9. Large-Scale Synthesis of a Uniform Film of Bilayer MoS2 on Graphene for 2D Heterostructure Phototransistors.

    PubMed

    Chen, Chuanmeng; Feng, Zhihong; Feng, Yiyu; Yue, Yuchen; Qin, Chengqun; Zhang, Daihua; Feng, Wei

    2016-07-27

    The large-scale synthesis of atomically thin, layered MoS2/graphene heterostructures is of great interest in optoelectronic devices because of their unique properties. Herein, we present a scalable synthesis method to prepare centimeter-scale, continuous, and uniform films of bilayer MoS2 using low-pressure chemical vapor deposition. This growth process was utilized to assemble a heterostructure by growing large-scale uniform films of bilayer MoS2 on graphene (G-MoS2/graphene). Atomic force microscopy, Raman spectra, and transmission electron microscopy characterization demonstrated that the large-scale bilayer MoS2 film on graphene exhibited good thickness uniformity and a polycrystalline nature. A centimeter-scale phototransistor prepared using the G-MoS2/graphene heterostructure exhibited a high responsivity of 32 mA/W with good cycling stability; this value is 1 order of magnitude higher than that of transferred MoS2 on graphene (2.5 mA/W). This feature results from efficient charge transfer at the interface enabled by intimate contact between the grown bilayer MoS2 (G-MoS2) and graphene. The ability to integrate multilayer materials into atomically thin heterostructures paves the way for fabricating multifunctional devices by controlling their layer structure. PMID:27381011

  10. Doping and Field Dependent Electrical Conductivity of Angle-Resolved Twisted Bilayer Graphene

    NASA Astrophysics Data System (ADS)

    Huang, Lujie; Kim, Cheol-Joo; Tsen, Adam Wei; Brown, Lola; Park, Jiwoong

    2015-03-01

    In twisted bilayer graphene (tBLG), the interlayer interaction induces additional van Hove singularities (VHS) and mini-gaps near the intersections between the Dirac cones of the two layers; this results in several electrical and optical phenomena at an energy level that monotonically increases with the twist angle θ. While there exist previous studies on the electrical and optical properties of tBLG, the electrical conductivity of tBLG and its dependence on the overall doping and interlayer potential (field) have not been measured using tBLG samples with known θ. Here, we report the electrical conductivity of θ-resolved tBLG in a dual-gate field effect transistor geometry which allows an independent control of the doping and interlayer potential. In large θ tBLG, the total conductivity is approximately proportional to the total carrier density (the sum of the carrier number densities from the top and the bottom layers), indicating that large θ tBLG acts as two independent single layers carrying the electrical current in parallel. Among tBLG samples with a small θ, however, we observe an extra resistance peak besides the Dirac point, which may correspond to the minigap near the VHS. In order to perform further experiments for this small- θ tBLG samples, we use a doubletransfer of CVD grown graphene films with a uniform lattice orientation over a large scale. This allows a direct optical characterization in the relevant IR wavelengths, a critical capability for determining and the twist angle θ.

  11. Angle dependent phonon spectra and thermal properties of misoriented bilayer graphene

    NASA Astrophysics Data System (ADS)

    Neupane, Mahesh; Ramnani, Pankaj; Ge, Supeng; Mulchandani, Ashok; Lake, Roger

    2015-03-01

    The Raman spectra of misoriented bilayer graphene (MBG) show angle dependent signatures of the misorientation angle (θ) in the low frequency breathing modes. We investigate these low frequency modes using molecular dynamics including temperature dependent phonon anharmonicity. The calculated vibrational and thermal properties are compared against our experimental data. Our theoretical investigations reveal that the layer breathing mode (LBM) frequencies at 100 +/- 10 cm-1 for angles 6° <= θ <= 30° are consistent with the observed frequencies of ZO modes in the Raman spectrum. For the smaller θ (or larger L), the reduced BZ leads to the zone-folding of the phonon spectrum at the zone center, and leads to broadened optical phonons width in the vibrational density of states. Finally, increasing θ in the MBG leads to a reduction in the lattice specific heat capacity. This work is supported in part by the National Science Foundation (NSF) Grant No: 1307671, and FAME, one of six centers of STARnet, a SRC program sponsored by MARCO and DARPA, and a U.S. Dept. of Education GAANN Fellowship.

  12. Room temperature detection of individual molecular physisorption using suspended bilayer graphene.

    PubMed

    Sun, Jian; Muruganathan, Manoharan; Mizuta, Hiroshi

    2016-04-01

    Detection of individual molecular adsorption, which represents the ultimate resolution of gas sensing, has rarely been realized with solid-state devices. So far, only a few studies have reported detection of individual adsorption by measuring the variation of electronic transport stemming from the charge transfer of adsorbate. We report room-temperature detection of the individual physisorption of carbon dioxide molecules with suspended bilayer graphene (BLG) based on a different mechanism. An electric field introduced by applying back-gate voltage is used to effectively enhance the adsorption rate. A unique device architecture is designed to induce tensile strain in the BLG to prevent its mechanical deflection onto the substrate by electrostatic force. Despite the negligible charge transfer from a single physisorbed molecule, it strongly affects the electronic transport in suspended BLG by inducing charged impurity, which can shut down part of the conduction of the BLG with Coulomb impurity scattering. Accordingly, we can detect each individual physisorption as a step-like resistance change with a quantized value in the BLG. We use density functional theory simulation to theoretically estimate the possible resistance response caused by Coulomb scattering of one adsorbed CO2 molecule, which is in agreement with our measurement. PMID:27152344

  13. Abrupt current switching in graphene bilayer tunnel transistors enabled by van Hove singularities

    PubMed Central

    Alymov, Georgy; Vyurkov, Vladimir; Ryzhii, Victor; Svintsov, Dmitry

    2016-01-01

    In a continuous search for the energy-efficient electronic switches, a great attention is focused on tunnel field-effect transistors (TFETs) demonstrating an abrupt dependence of the source-drain current on the gate voltage. Among all TFETs, those based on one-dimensional (1D) semiconductors exhibit the steepest current switching due to the singular density of states near the band edges, though the current in 1D structures is pretty low. In this paper, we propose a TFET based on 2D graphene bilayer which demonstrates a record steep subthreshold slope enabled by van Hove singularities in the density of states near the edges of conduction and valence bands. Our simulations show the accessibility of 3.5 × 104 ON/OFF current ratio with 150 mV gate voltage swing, and a maximum subthreshold slope of (20 μV/dec)−1 just above the threshold. The high ON-state current of 0.8 mA/μm is enabled by a narrow (~0.3 eV) extrinsic band gap, while the smallness of the leakage current is due to an all-electrical doping of the source and drain contacts which suppresses the band tailing and trap-assisted tunneling. PMID:27098051

  14. Room temperature detection of individual molecular physisorption using suspended bilayer graphene

    PubMed Central

    Sun, Jian; Muruganathan, Manoharan; Mizuta, Hiroshi

    2016-01-01

    Detection of individual molecular adsorption, which represents the ultimate resolution of gas sensing, has rarely been realized with solid-state devices. So far, only a few studies have reported detection of individual adsorption by measuring the variation of electronic transport stemming from the charge transfer of adsorbate. We report room-temperature detection of the individual physisorption of carbon dioxide molecules with suspended bilayer graphene (BLG) based on a different mechanism. An electric field introduced by applying back-gate voltage is used to effectively enhance the adsorption rate. A unique device architecture is designed to induce tensile strain in the BLG to prevent its mechanical deflection onto the substrate by electrostatic force. Despite the negligible charge transfer from a single physisorbed molecule, it strongly affects the electronic transport in suspended BLG by inducing charged impurity, which can shut down part of the conduction of the BLG with Coulomb impurity scattering. Accordingly, we can detect each individual physisorption as a step-like resistance change with a quantized value in the BLG. We use density functional theory simulation to theoretically estimate the possible resistance response caused by Coulomb scattering of one adsorbed CO2 molecule, which is in agreement with our measurement. PMID:27152344

  15. Theory of low-power ultra-broadband terahertz sideband generation in bi-layer graphene

    PubMed Central

    Crosse, J. A.; Xu, Xiaodong; Sherwin, Mark S.; Liu, R. B.

    2014-01-01

    In a semiconductor illuminated by a strong terahertz (THz) field, optically excited electron–hole pairs can recombine to emit light in a broad frequency comb evenly spaced by twice the THz frequency. Such high-order THz sideband generation is of interest both as an example of extreme nonlinear optics and also as a method for ultrafast electro-optical modulation. So far, this phenomenon has only been observed with large field strengths (~10 kV cm−1), an obstacle for technological applications. Here we predict that bi-layer graphene generates high-order sidebands at much weaker THz fields. We find that a THz field of strength 1 kV cm−1 can produce a high-sideband spectrum of about 30 THz, 100 times broader than in GaAs. The sidebands are generated despite the absence of classical collisions, with the quantum coherence of the electron–hole pairs enabling recombination. These remarkable features lower the barrier to desktop electro-optical modulation at THz frequencies, facilitating ultrafast optical communications. PMID:25249245

  16. Abrupt current switching in graphene bilayer tunnel transistors enabled by van Hove singularities

    NASA Astrophysics Data System (ADS)

    Alymov, Georgy; Vyurkov, Vladimir; Ryzhii, Victor; Svintsov, Dmitry

    2016-04-01

    In a continuous search for the energy-efficient electronic switches, a great attention is focused on tunnel field-effect transistors (TFETs) demonstrating an abrupt dependence of the source-drain current on the gate voltage. Among all TFETs, those based on one-dimensional (1D) semiconductors exhibit the steepest current switching due to the singular density of states near the band edges, though the current in 1D structures is pretty low. In this paper, we propose a TFET based on 2D graphene bilayer which demonstrates a record steep subthreshold slope enabled by van Hove singularities in the density of states near the edges of conduction and valence bands. Our simulations show the accessibility of 3.5 × 104 ON/OFF current ratio with 150 mV gate voltage swing, and a maximum subthreshold slope of (20 μV/dec)‑1 just above the threshold. The high ON-state current of 0.8 mA/μm is enabled by a narrow (~0.3 eV) extrinsic band gap, while the smallness of the leakage current is due to an all-electrical doping of the source and drain contacts which suppresses the band tailing and trap-assisted tunneling.

  17. Abrupt current switching in graphene bilayer tunnel transistors enabled by van Hove singularities.

    PubMed

    Alymov, Georgy; Vyurkov, Vladimir; Ryzhii, Victor; Svintsov, Dmitry

    2016-01-01

    In a continuous search for the energy-efficient electronic switches, a great attention is focused on tunnel field-effect transistors (TFETs) demonstrating an abrupt dependence of the source-drain current on the gate voltage. Among all TFETs, those based on one-dimensional (1D) semiconductors exhibit the steepest current switching due to the singular density of states near the band edges, though the current in 1D structures is pretty low. In this paper, we propose a TFET based on 2D graphene bilayer which demonstrates a record steep subthreshold slope enabled by van Hove singularities in the density of states near the edges of conduction and valence bands. Our simulations show the accessibility of 3.5 × 10(4) ON/OFF current ratio with 150 mV gate voltage swing, and a maximum subthreshold slope of (20 μV/dec)(-1) just above the threshold. The high ON-state current of 0.8 mA/μm is enabled by a narrow (~0.3 eV) extrinsic band gap, while the smallness of the leakage current is due to an all-electrical doping of the source and drain contacts which suppresses the band tailing and trap-assisted tunneling. PMID:27098051

  18. Electronic properties of bilayer graphenes strongly coupled to interlayer stacking and an external electric field

    NASA Astrophysics Data System (ADS)

    Park, Changwon; Ryu, Junga; Hong, Suklyun; Sumpter, Bobby; Kim, Gunn; Yoon, Mina

    2015-03-01

    In the design of bilayer graphene (BLG)-based switching devices, it is critical to understand the complex stacking structures observed experimentally and their impact on the overall electronic properties. Using a maximally localized Wannier function, a highly accurate tight-binding Hamiltonian based on density functional theory was constructed and the stacking-dependent evolution of BLGs electronic band structures and their response to an external electric field were systematically investigated. Although the crossing band structures remain at any stacking configurations (i.e., no energy gap opens), the wavefunction characteristics around the Fermi level can differ qualitatively for different stackings. This difference is conveyed to energy gap opening properties in the presence of an external electric field. We, for the first time, established a phase diagram summarizing the stacking-dependent electronic structures of BLG, separating metallic and semiconducting characteristics for a given external field. The research was conducted at the Center for Nanophase Materials Sciences, which is a DOE Office of Science User Facility.

  19. Realizing 1-D conducting channel between oppositely gated regions in bilayer graphene

    NASA Astrophysics Data System (ADS)

    Lee, Janghee; Watanabe, Kenji; Taniguchi, Takashi; Lee, Hu-Jong

    The band gap of bilayer graphene (BLG) can be tuned by applying an external electric field perpendicular to the plane of a BLG sheet. If direction of the electric fields in two adjacent regions in BLG are opposite, one-dimensional (1-D) conducting channel emerges at the boundary between two regions with chiral nature. In this presentation, we introduce a method for fabricating two pairs of split-gates attached to BLG, which is sandwiched between two atomically clean hexagonal boron nitride (h-BN) single crystals and thus allows ballistic transport of carriers at least within the device size. Current-voltage characteristics show a large transport gap, which is comparable to the results obtained from optical measurements and numerical calculations. Opening the band gap in two adjacent regions of the BLG flake by oppositely gated electric fields, we observed metallic behavior in transport characteristics along the boundary between the two regions although the resistance of two gapped regions are a few hundreds of k Ω. These results indicate that a 1-D conducting channel formed between the two regions where the induced band gaps were inverted to each other. The formation of this 1-D conducting channel mimics the topological edge conducting channels emerging at the boundary of a two-dimensional topological insulator and may be utilized for applying BLG to valleytronics

  20. Electromagnetic absorption and Kerr effect in quantum Hall ferromagnetic states of bilayer graphene

    NASA Astrophysics Data System (ADS)

    Côté, R.; Barrette, Manuel; Bouffard, Élie

    2015-09-01

    In a quantizing magnetic field, the chiral two-dimensional electron gas in Landau level N =0 of bilayer graphene goes through a series of phase transitions at integer filling factors ν ∈[-3 ,3 ] when the strength of an electric field applied perpendicularly to the layers is increased. At filling factor ν =3 , the electron gas can be described by a simple two-level system where layer and spin degrees of freedom are frozen. The gas then behaves as an orbital quantum Hall ferromagnet. A Coulomb-induced Dzyaloshinskii-Moriya term in the orbital pseudospin Hamiltonian is responsible for a series of transitions first to a Wigner crystal state and then to a spiral state as the electric field is increased. Both states have a nontrivial orbital pseudospin texture. In this work, we study how the phase diagram at ν =3 is modified by an electric field applied in the plane of the layers and then derive several experimental signatures of the uniform and nonuniform states in the phase diagram. In addition to the transport gap, we study the electromagnetic absorption and the Kerr rotation due to the excitations of the orbital pseudospin-wave modes in the broken-symmetry states.

  1. Detecting zero-line mode in bilayer graphene via the quantum Hall effect

    NASA Astrophysics Data System (ADS)

    Zhang, Ying-Tao; Qiao, Zhenhua; Sun, Qing-Feng

    2013-06-01

    The zero-line mode can be produced in AB-stacking bilayer graphene under a spatially varying electric field. We investigate the transport properties of the zero-line mode in a six-terminal Hall bar system in the presence of a uniform magnetic field. We find that the Hall resistance is zero and the longitudinal resistance exhibits a plateau with 1/2(h/2e2), when the Fermi level lies between the lowest conduction and highest valence Landau levels, which corresponds to the zero-line modes. Since the zero-line mode propagates along the domain wall separating opposite valley-Hall topologies, we also numerically measure the currents between source and drain and the conductance between two of the transversal terminals. Our finding shows that the current between source and drain is due to the existence of kink state, which can serve as a scheme to detect the zero-line mode. We further show that the zero-line mode under strong magnetic field is robust against disorders.

  2. Retro reflection of electrons at the interface of bilayer graphene and superconductor

    PubMed Central

    Ang, Yee Sin; Ma, Zhongshui; Zhang, C.

    2012-01-01

    Electron reflection at an interface is a fundamental quantum transport phenomenon. The most famous electron reflection is the electron→hole Andreev reflection (AR) at a metal/superconductor interface. While AR can be either specular or retro-type, electron→electron reflection is limited to only the specular type. Here we show that electrons can undergo retro-reflection in bilayer graphene (BLG). The underlying mechanism for this previously unknown process is the anisotropic constant energy band contour of BLG. The electron group velocity is fully reversed upon reflection, causing electrons to be retro-reflected. Utilizing a BLG/superconductor junction (BLG/S) as a model structure, we show that the unique low energy quasiparticle nature of BLG results in two striking features: (1) AR is completely absent, making BLG/S 100% electron reflective; (2) electrons are valley-selectively focused upon retro-reflection. Our results suggest that BLG/S is a valley-selective Veselago electron focusing mirror which can be useful in valleytronic applications. PMID:23264876

  3. Phase transitions in two tunnel-coupled HgTe quantum wells: Bilayer graphene analogy and beyond.

    PubMed

    Krishtopenko, S S; Knap, W; Teppe, F

    2016-01-01

    HgTe quantum wells possess remarkable physical properties as for instance the quantum spin Hall state and the "single-valley" analog of graphene, depending on their layer thicknesses and barrier composition. However, double HgTe quantum wells yet contain more fascinating and still unrevealed features. Here we report on the study of the quantum phase transitions in tunnel-coupled HgTe layers separated by CdTe barrier. We demonstrate that this system has a 3/2 pseudo spin degree of freedom, which features a number of particular properties associated with the spin-dependent coupling between HgTe layers. We discover a specific metal phase arising in a wide range of HgTe and CdTe layer thicknesses, in which a gapless bulk and a pair of helical edge states coexist. This phase holds some properties of bilayer graphene such as an unconventional quantum Hall effect and an electrically-tunable band gap. In this "bilayer graphene" phase, electric field opens the band gap and drives the system into the quantum spin Hall state. Furthermore, we discover a new type of quantum phase transition arising from a mutual inversion between second electron- and hole-like subbands. This work paves the way towards novel materials based on multi-layered topological insulators. PMID:27476745

  4. Characterization and physical modeling of MOS capacitors in epitaxial graphene monolayers and bilayers on 6H-SiC

    NASA Astrophysics Data System (ADS)

    Winters, M.; Sveinbjörnsson, E. Ö.; Melios, C.; Kazakova, O.; Strupiński, W.; Rorsman, N.

    2016-08-01

    Capacitance voltage (CV) measurements are performed on planar MOS capacitors with an Al2O3 dielectric fabricated in hydrogen intercalated monolayer and bilayer graphene grown on 6H-SiC as a function of frequency and temperature. Quantitative models of the CV data are presented in conjunction with the measurements in order to facilitate a physical understanding of graphene MOS systems. An interface state density of order 2 ṡ 1012 eV-1 cm-2 is found in both material systems. Surface potential fluctuations of order 80-90meV are also assessed in the context of measured data. In bilayer material, a narrow bandgap of 260meV is observed consequent to the spontaneous polarization in the substrate. Supporting measurements of material anisotropy and temperature dependent hysteresis are also presented in the context of the CV data and provide valuable insight into measured and modeled data. The methods outlined in this work should be applicable to most graphene MOS systems.

  5. The effect of the dopant nature on the reactivity, interlayer bonding and electronic properties of dual doped bilayer graphene.

    PubMed

    Denis, Pablo A; Iribarne, Federico

    2016-09-21

    Herein, we report on the structural, chemical reactivity and electronic properties of dual-doped bilayer graphene (DDBG). Only one of the layers was doped with a pair of 3p-2p elements. Aluminum was the only dopant which prefers to interact with the undoped layer. The interlayer interaction energies of DDBG are smaller than those determined for bilayer graphene, except for AlN and AlO DDBG. This effect is due to the presence of weak Al-C interlayer bonds. The dopants increase the reactivity of both the doped and undoped layers. Interestingly, we found that hydrogenation is a method that can be used to switch on/off the interlayer bonding, as it controlled the X-C interlayer distance (X = Al, Si, P, S). The magnetic moment of the systems can be adjusted by the position of the 3p dopant. In effect, when X interacts with the doped layer, the magnetic moment is reduced, while it is maintained when X fails to interact. Finally, we found that the doped layer is able to break the symmetry of the undoped sheet and small gaps can be opened in the band structure of the undoped layer. As observed for single doped monolayer graphene, the most effective element for such purposes is P, which opened gaps close to 0.2 eV. For SiN DDBG, the spin filtering properties are enhanced with respect to the monolayered structure. PMID:27545204

  6. A dilute Cu(Ni) alloy for synthesis of large-area Bernal stacked bilayer graphene using atmospheric pressure chemical vapour deposition

    NASA Astrophysics Data System (ADS)

    Madito, M. J.; Bello, A.; Dangbegnon, J. K.; Oliphant, C. J.; Jordaan, W. A.; Momodu, D. Y.; Masikhwa, T. M.; Barzegar, F.; Fabiane, M.; Manyala, N.

    2016-01-01

    A bilayer graphene film obtained on copper (Cu) foil is known to have a significant fraction of non-Bernal (AB) stacking and on copper/nickel (Cu/Ni) thin films is known to grow over a large-area with AB stacking. In this study, annealed Cu foils for graphene growth were doped with small concentrations of Ni to obtain dilute Cu(Ni) alloys in which the hydrocarbon decomposition rate of Cu will be enhanced by Ni during synthesis of large-area AB-stacked bilayer graphene using atmospheric pressure chemical vapour deposition. The Ni doped concentration and the Ni homogeneous distribution in Cu foil were confirmed with inductively coupled plasma optical emission spectrometry and proton-induced X-ray emission. An electron backscatter diffraction map showed that Cu foils have a single (001) surface orientation which leads to a uniform growth rate on Cu surface in early stages of graphene growth and also leads to a uniform Ni surface concentration distribution through segregation kinetics. The increase in Ni surface concentration in foils was investigated with time-of-flight secondary ion mass spectrometry. The quality of graphene, the number of graphene layers, and the layers stacking order in synthesized bilayer graphene films were confirmed by Raman and electron diffraction measurements. A four point probe station was used to measure the sheet resistance of graphene films. As compared to Cu foil, the prepared dilute Cu(Ni) alloy demonstrated the good capability of growing large-area AB-stacked bilayer graphene film by increasing Ni content in Cu surface layer.

  7. High-temperature quantum anomalous Hall effect in honeycomb bilayer consisting of Au atoms and single-vacancy graphene

    PubMed Central

    Han, Yan; Wan, Jian-Guo; Ge, Gui-Xian; Song, Feng-Qi; Wang, Guang-Hou

    2015-01-01

    The quantum anomalous Hall effect (QAHE) is predicted to be realized at high temperature in a honeycomb bilayer consisting of Au atoms and single-vacancy graphene (Au2-SVG) based on the first-principles calculations. We demonstrate that the ferromagnetic state in the Au2-SVG can be maintained up to 380 K. The combination of spatial inversion symmetry and the strong SOC introduced by the Au atoms causes a topologically nontrivial band gap as large as 36 meV and a QAHE state with Chern number C = −2. The analysis of the binding energy proved that the honeycomb bilayer is stable and feasible to be fabricated in experiment. The QAHEs in Ta2-SVG and other TM2-SVGs are also discussed. PMID:26574924

  8. High-temperature quantum anomalous Hall effect in honeycomb bilayer consisting of Au atoms and single-vacancy graphene

    NASA Astrophysics Data System (ADS)

    Han, Yan; Wan, Jian-Guo; Ge, Gui-Xian; Song, Feng-Qi; Wang, Guang-Hou

    2015-11-01

    The quantum anomalous Hall effect (QAHE) is predicted to be realized at high temperature in a honeycomb bilayer consisting of Au atoms and single-vacancy graphene (Au2-SVG) based on the first-principles calculations. We demonstrate that the ferromagnetic state in the Au2-SVG can be maintained up to 380 K. The combination of spatial inversion symmetry and the strong SOC introduced by the Au atoms causes a topologically nontrivial band gap as large as 36 meV and a QAHE state with Chern number C = -2. The analysis of the binding energy proved that the honeycomb bilayer is stable and feasible to be fabricated in experiment. The QAHEs in Ta2-SVG and other TM2-SVGs are also discussed.

  9. Monte Carlo study of internal energy and specific heat of a nano-graphene bilayer in a longitudinal magnetic field

    NASA Astrophysics Data System (ADS)

    Luo, Xiao-hong; Wang, Wei; Chen, Dong-dong; Xu, Si-yuan

    2016-06-01

    The thermodynamic properties of a nano-graphene bilayer, consisting of the upper layer A of spin-3/2 with antiferromagnetic intralayer exchange coupling and the bottom layer B of spin-5/2 with ferromagnetic intralayer exchange coupling, have been studied by the use of Monte Carlo simulation. We find a number of characteristic phenomena. The effects of the exchange coupling, the single-ion anisotropy and the longitudinal magnetic field on the internal energy, the specific heat and the blocking temperature of the mixed-spin bilayer system have been investigated in detail. The internal energy and the specific heat profiles are clarified. In particular, we have found that the specific heat curve may show two peaks phenomenon for appropriate values of the system parameters.

  10. Structural and electronic properties of Li-intercalated graphene on SiC(0001)

    NASA Astrophysics Data System (ADS)

    Caffrey, Nuala M.; Johansson, Leif I.; Xia, Chao; Armiento, Rickard; Abrikosov, Igor A.; Jacobi, Chariya

    2016-05-01

    We investigate the structural and electronic properties of Li-intercalated monolayer graphene on SiC(0001) using combined angle-resolved photoemission spectroscopy and first-principles density functional theory. Li intercalates at room temperature both at the interface between the buffer layer and SiC and between the two carbon layers. The graphene is strongly n -doped due to charge transfer from the Li atoms and two π bands are visible at the K ¯ point. After heating the sample to 300 ∘C , these π bands become sharp and have a distinctly different dispersion to that of Bernal-stacked bilayer graphene. We suggest that the Li atoms intercalate between the two carbon layers with an ordered structure, similar to that of bulk LiC6. An AA stacking of these two layers becomes energetically favourable. The π bands around the K ¯ point closely resemble the calculated band structure of a C6LiC6 system, where the intercalated Li atoms impose a superpotential on the graphene electronic structure that opens gaps at the Dirac points of the two π cones.

  11. Charge Inversion and Topological Phase Transition at a Twist Angle Induced van Hove Singularity of Bilayer Graphene

    NASA Astrophysics Data System (ADS)

    Kim, Youngwook; Herlinger, Patrick; Moon, Pilkyung; Koshino, Mikito; Taniguchi, Takashi; Watanabe, Kenji; Smet, Jurgen H.

    2016-08-01

    Van Hove singularities (VHS's) in the density of states play an outstanding and diverse role for the electronic and thermodynamic properties of crystalline solids. At the critical point the Fermi surface connectivity changes and topological properties undergo a transition. Opportunities to systematically pass a VHS at the turn of a voltage knob and study its diverse impact are however rare. With the advent of van der Waals heterostructures, control over the atomic registry of neigbouring graphene layers offers an unprecedented tool to generate a low energy VHS easily accessible with conventional gating. Here we have addressed magnetotransport when the chemical potential crosses the twist angle induced VHS in twisted bilayer graphene. A topological phase transition is experimentally disclosed in the abrupt conversion of electrons to holes or vice versa, a loss of a non-zero Berry phase and distinct sequences of integer quantum Hall states above and below the singularity.

  12. Charge Inversion and Topological Phase Transition at a Twist Angle Induced van Hove Singularity of Bilayer Graphene.

    PubMed

    Kim, Youngwook; Herlinger, Patrick; Moon, Pilkyung; Koshino, Mikito; Taniguchi, Takashi; Watanabe, Kenji; Smet, Jurgen H

    2016-08-10

    van Hove singularities (VHS's) in the density of states play an outstanding and diverse role for the electronic and thermodynamic properties of crystalline solids. At the critical point the Fermi surface connectivity changes, and topological properties undergo a transition. Opportunities to systematically pass a VHS at the turn of a voltage knob and study its diverse impact are however rare. With the advent of van der Waals heterostructures, control over the atomic registry of neighboring graphene layers offers an unprecedented tool to generate a low energy VHS easily accessible with conventional gating. Here we have addressed magnetotransport when the chemical potential crosses the twist angle induced VHS in twisted bilayer graphene. A topological phase transition is experimentally disclosed in the abrupt conversion of electrons to holes or vice versa, a loss of a nonzero Berry phase and distinct sequences of integer quantum Hall states above and below the singularity. PMID:27387484

  13. Extreme sensitivity of the electric-field-induced band gap to the electronic topological transition in sliding bilayer graphene

    PubMed Central

    Lee, Kyu Won; Lee, Cheol Eui

    2015-01-01

    We have investigated the effect of electronic topological transition on the electric field-induced band gap in sliding bilayer graphene by using the density functional theory calculations. The electric field-induced band gap was found to be extremely sensitive to the electronic topological transition. At the electronic topological transition induced by layer sliding, four Dirac cones in the Bernal-stacked bilayer graphene reduces to two Dirac cones with equal or unequal Dirac energies depending on the sliding direction. While the critical electric field required for the band gap opening increases with increasing lateral shift for the two Dirac cones with unequal Dirac energies, the critical field is essentially zero with or without a lateral shift for the two Dirac cones with equal Dirac energies. The critical field is determined by the Dirac energy difference and the electronic screening effect. The electronic screening effect was also found to be enhanced with increasing lateral shift, apparently indicating that the massless helical and massive chiral fermions are responsible for the perfect and imperfect electronic screening, respectively. PMID:26635178

  14. Phase transitions in two tunnel-coupled HgTe quantum wells: Bilayer graphene analogy and beyond

    PubMed Central

    Krishtopenko, S. S.; Knap, W.; Teppe, F.

    2016-01-01

    HgTe quantum wells possess remarkable physical properties as for instance the quantum spin Hall state and the “single-valley” analog of graphene, depending on their layer thicknesses and barrier composition. However, double HgTe quantum wells yet contain more fascinating and still unrevealed features. Here we report on the study of the quantum phase transitions in tunnel-coupled HgTe layers separated by CdTe barrier. We demonstrate that this system has a 3/2 pseudo spin degree of freedom, which features a number of particular properties associated with the spin-dependent coupling between HgTe layers. We discover a specific metal phase arising in a wide range of HgTe and CdTe layer thicknesses, in which a gapless bulk and a pair of helical edge states coexist. This phase holds some properties of bilayer graphene such as an unconventional quantum Hall effect and an electrically-tunable band gap. In this “bilayer graphene” phase, electric field opens the band gap and drives the system into the quantum spin Hall state. Furthermore, we discover a new type of quantum phase transition arising from a mutual inversion between second electron- and hole-like subbands. This work paves the way towards novel materials based on multi-layered topological insulators. PMID:27476745

  15. Phase transitions in two tunnel-coupled HgTe quantum wells: Bilayer graphene analogy and beyond

    NASA Astrophysics Data System (ADS)

    Krishtopenko, S. S.; Knap, W.; Teppe, F.

    2016-08-01

    HgTe quantum wells possess remarkable physical properties as for instance the quantum spin Hall state and the “single-valley” analog of graphene, depending on their layer thicknesses and barrier composition. However, double HgTe quantum wells yet contain more fascinating and still unrevealed features. Here we report on the study of the quantum phase transitions in tunnel-coupled HgTe layers separated by CdTe barrier. We demonstrate that this system has a 3/2 pseudo spin degree of freedom, which features a number of particular properties associated with the spin-dependent coupling between HgTe layers. We discover a specific metal phase arising in a wide range of HgTe and CdTe layer thicknesses, in which a gapless bulk and a pair of helical edge states coexist. This phase holds some properties of bilayer graphene such as an unconventional quantum Hall effect and an electrically-tunable band gap. In this “bilayer graphene” phase, electric field opens the band gap and drives the system into the quantum spin Hall state. Furthermore, we discover a new type of quantum phase transition arising from a mutual inversion between second electron- and hole-like subbands. This work paves the way towards novel materials based on multi-layered topological insulators.

  16. Analytical Calculation of Energy levels of mono- and bilayer Graphene Quantum Dots Used as Light Absorber in Solar Cells

    NASA Astrophysics Data System (ADS)

    Tamandani, Shahryar; Darvish, Ghafar; Faez, Rahim

    2016-01-01

    In this paper by solving Dirac equation, we present an analytical solution to calculate energy levels and wave functions of mono- and bilayer graphene quantum dots. By supposing circular quantum dots, we solve Dirac equation and obtain energy levels and band gap with relations in a new closed and practical form. The energy levels are correlated with a radial quantum number and radius of quantum dots. In addition to monolayer quantum dots, AA- and AB-stacked bilayer quantum dots are investigated and their energy levels and band gap are calculated as well. Also, we analyze the influence of the quantum dots size on their energy spectrum. It can be observed that the band gap decreases as quantum dots' radius increases. On the other hand, increase in the band gap is more in AB-stacked bilayer quantum dots. Using the obtained relations, the band gap is obtained in each state. Comparing the energy spectra obtained from the tight-binding approximation with those of our obtained relations shows that the behavior of the energies as function of the dot size is qualitatively similar, but in some cases, quantitative differences can be seen. As quantum dots radius increases, the analytical results approach to the tight-binding method results.

  17. ZnO Nanoparticles/Reduced Graphene Oxide Bilayer Thin Films for Improved NH3-Sensing Performances at Room Temperature

    NASA Astrophysics Data System (ADS)

    Tai, Huiling; Yuan, Zhen; Zheng, Weijian; Ye, Zongbiao; Liu, Chunhua; Du, Xiaosong

    2016-03-01

    ZnO nanoparticles and graphene oxide (GO) thin film were deposited on gold interdigital electrodes (IDEs) in sequence via simple spraying process, which was further restored to ZnO/reduced graphene oxide (rGO) bilayer thin film by the thermal reduction treatment and employed for ammonia (NH3) detection at room temperature. rGO was identified by UV-vis absorption spectra and X-ray photoelectron spectroscope (XPS) analyses, and the adhesion between ZnO nanoparticles and rGO nanosheets might also be formed. The NH3-sensing performances of pure rGO film and ZnO/rGO bilayer films with different sprayed GO amounts were compared. The results showed that ZnO/rGO film sensors exhibited enhanced response properties, and the optimal GO amount of 1.5 ml was achieved. Furthermore, the optimal ZnO/rGO film sensor showed an excellent reversibility and fast response/recovery rate within the detection range of 10-50 ppm. Meanwhile, the sensor also displayed good repeatability and selectivity to NH3. However, the interference of water molecules on the prepared sensor is non-ignorable; some techniques should be researched to eliminate the effect of moisture in the further work. The remarkably enhanced NH3-sensing characteristics were speculated to be attributed to both the supporting role of ZnO nanoparticles film and accumulation heterojunction at the interface between ZnO and rGO. Thus, the proposed ZnO/rGO bilayer thin film sensor might give a promise for high-performance NH3-sensing applications.

  18. ZnO Nanoparticles/Reduced Graphene Oxide Bilayer Thin Films for Improved NH3-Sensing Performances at Room Temperature.

    PubMed

    Tai, Huiling; Yuan, Zhen; Zheng, Weijian; Ye, Zongbiao; Liu, Chunhua; Du, Xiaosong

    2016-12-01

    ZnO nanoparticles and graphene oxide (GO) thin film were deposited on gold interdigital electrodes (IDEs) in sequence via simple spraying process, which was further restored to ZnO/reduced graphene oxide (rGO) bilayer thin film by the thermal reduction treatment and employed for ammonia (NH3) detection at room temperature. rGO was identified by UV-vis absorption spectra and X-ray photoelectron spectroscope (XPS) analyses, and the adhesion between ZnO nanoparticles and rGO nanosheets might also be formed. The NH3-sensing performances of pure rGO film and ZnO/rGO bilayer films with different sprayed GO amounts were compared. The results showed that ZnO/rGO film sensors exhibited enhanced response properties, and the optimal GO amount of 1.5 ml was achieved. Furthermore, the optimal ZnO/rGO film sensor showed an excellent reversibility and fast response/recovery rate within the detection range of 10-50 ppm. Meanwhile, the sensor also displayed good repeatability and selectivity to NH3. However, the interference of water molecules on the prepared sensor is non-ignorable; some techniques should be researched to eliminate the effect of moisture in the further work. The remarkably enhanced NH3-sensing characteristics were speculated to be attributed to both the supporting role of ZnO nanoparticles film and accumulation heterojunction at the interface between ZnO and rGO. Thus, the proposed ZnO/rGO bilayer thin film sensor might give a promise for high-performance NH3-sensing applications. PMID:26956599

  19. Enhanced Configurational Entropy in High-Density Nanoconfined Bilayer Ice.

    PubMed

    Corsetti, Fabiano; Zubeltzu, Jon; Artacho, Emilio

    2016-02-26

    A novel kind of crystal order in high-density nanoconfined bilayer ice is proposed from molecular dynamics and density-functional theory simulations. A first-order transition is observed between a low-temperature proton-ordered solid and a high-temperature proton-disordered solid. The latter is shown to possess crystalline order for the oxygen positions, arranged on a close-packed triangular lattice with AA stacking. Uniquely among the ice phases, the triangular bilayer is characterized by two levels of disorder (for the bonding network and for the protons) which results in a configurational entropy twice that of bulk ice. PMID:26967426

  20. Collapsed armchair single-walled carbon nanotubes as an analog of closed-edged bilayer graphene nanoribbons

    NASA Astrophysics Data System (ADS)

    Hasegawa, Masayuki; Nishidate, Kazume; Yoshimoto, Noriyuki

    2015-12-01

    Recently, radially collapsed single-walled carbon nanotubes (SWCNTs) have been recognized as an analog of closed-edged bilayer graphene nanoribbons (GNRs). To explore this analogy, we first make detailed analyses of the radial deformation and collapse of armchair SWCNTs using the density functional theory with van der Waals corrections. The traditional threshold diameters dividing SWCNTs into the three regimes are obtained as Dmeta=2.2 nm and Dabs=5.1 nm , where deformed configurations can be stabilized (metastable) for tubes with diameter D >Dmeta and are energetically more favorable than the cylindrical tube for D >Dabs (absolute stability). We find that the present result for Dabs is marginally in excellent agreement with the most plausible experimental result. We also identify, for the first time, other threshold diameters given by Dflat 1=3.3 nm and Dflat 2=4.4 nm in between Dmeta and Dabs, where the cross-sectional shape of a collapsed SWCNT is peanutlike for D Dflat 2. This bistability for tubes with D between Dflat 1 and Dflat 2 implies that the most stable configuration of these collapsed tubes cannot necessarily be achieved by molecular dynamics simulation. Electronic structures of collapsed armchair SWCNTs are also investigated to find that substantial band gaps develop in the flattened armchair tubes with Bernal stacked opposing faces. These band gap openings of flattened SWCNTs are explored by exploiting their analogies to bilayer graphene and bilayer GNRs. We find in particular that band gaps of flattened armchair SWCNTs with dumbbell-like cross sections, whose width is denoted W , show a scale behavior, ˜1 /Wflat , with Wflat=W -3.38 (nm ) , where Wflat is found to be the width of the flat region, consistent with recent theoretical analyses for a model of collapsed SWCNTs [T. Nakanishi and T. Ando, Phys. Rev. B 91, 155420 (2015), 10.1103/PhysRevB.91

  1. Sandwich nanoarchitecture of Si/reduced graphene oxide bilayer nanomembranes for Li-ion batteries with long cycle life.

    PubMed

    Liu, Xianghong; Zhang, Jun; Si, Wenping; Xi, Lixia; Eichler, Barbara; Yan, Chenglin; Schmidt, Oliver G

    2015-02-24

    The large capacity loss and huge volume change of silicon anodes severely restricts their practical applications in lithium ion batteries. In this contribution, the sandwich nanoarchitecture of rolled-up Si/reduced graphene oxide bilayer nanomembranes was designed via a strain released strategy. Within this nanoarchitecture, the inner void space and the mechanical feature of nanomembranes can help to buffer the strain during lithiation/delithiation; the alternately stacked conductive rGO layers can protect the Si layers from excessive formation of SEI layers. As anodes for lithium-ion batteries, the sandwiched Si/rGO nanoarchitecture demonstrates long cycling life of 2000 cycles at 3 A g(-1) with a capacity degradation of only 3.3% per 100 cycles. PMID:25646575

  2. Electronic transport and shot noise in a Thue-Morse bilayer graphene superlattice with interlayer potential bias

    NASA Astrophysics Data System (ADS)

    Li, Yuanqiao; Zhang, Hongmei; Liu, De

    2016-06-01

    In this paper, we evaluate the transport properties of a Thue-Morse AB-stacked bilayer graphene superlattice with different interlayer potential biases. Based on the transfer matrix method, the transmission coefficient, the conductance, and the Fano factor are numerically calculated and discussed. We find that the symmetry of the transmission coefficient with respect to normal incidence depends on the structural symmetry of the system and the new transmission peak appears in the energy band gap opening region. The conductance and the Fano factor can be greatly modulated not only by the Fermi energy and the interlayer potential bias but also by the generation number. Interestingly, the conductance exhibits the plateau of almost zero conductance and the Fano factor plateaus with Poisson value occur in the energy band gap opening region for large interlayer potential bias.

  3. Bilayer graphene with parallel magnetic field and twisting: Phases and phase transitions in a highly tunable Dirac system

    NASA Astrophysics Data System (ADS)

    Roy, Bitan; Yang, Kun

    2013-12-01

    The effective theory for bilayer graphene (BLG), subject to parallel/in-plane magnetic fields, is derived. With a sizable magnetic field the trigonal warping becomes irrelevant, and one ends up with two Dirac points in the vicinity of each valley in the low-energy limit, similar to the twisted BLG. Combining twisting and parallel field thus gives rise to a Dirac system with tunable Fermi velocity and cutoff. If the interactions are sufficiently strong, several fully gapped states can be realized in these systems, in addition to the ones in a pristine setup. Transformations of the order parameters under various symmetry operations are analyzed. The quantum critical behavior of various phase transitions driven by the twisting and the magnetic field is reported. The effects of an additional perpendicular field and possible ways to realize the new massive phases are highlighted.

  4. Raman enhancement by graphene-Ga2O3 2D bilayer film

    PubMed Central

    2014-01-01

    2D β-Ga2O3 flakes on a continuous 2D graphene film were prepared by a one-step chemical vapor deposition on liquid gallium surface. The composite was characterized by optical microscopy, scanning electron microscopy, Raman spectroscopy, energy dispersive spectroscopy, and X-ray photoelectron spectroscopy (XPS). The experimental results indicate that Ga2O3 flakes grew on the surface of graphene film during the cooling process. In particular, tenfold enhancement of graphene Raman scattering signal was detected on Ga2O3 flakes, and XPS indicates the C-O bonding between graphene and Ga2O3. The mechanism of Raman enhancement was discussed. The 2D Ga2O3-2D graphene structure may possess potential applications. PMID:24472433

  5. Trigonal warping, pseudodiffusive transport, and finite-system version of the Lifshitz transition in magnetoconductance of bilayer graphene Corbino disks

    NASA Astrophysics Data System (ADS)

    Rut, Grzegorz; Rycerz, Adam

    2016-02-01

    Using the transfer matrix in the angular-momentum space we investigate the impact of trigonal warping on magnetotransport and scaling properties of a ballistic bilayer graphene in the Corbino geometry. Although the conductivity at the charge-neutrality point and zero magnetic field exhibits a one-parameter scaling, the shot-noise characteristics, quantified by the Fano factor F and the third charge-transfer cumulant R , remain pseudodiffusive. This shows that the pseudodiffusive transport regime in bilayer graphene is not related to the universal value of the conductivity but can be identified by higher charge-transfer cumulants. For Corbino disks with larger radii ratios, the conductivity is suppressed by the trigonal warping, mainly because the symmetry reduction amplifies backscattering for normal modes corresponding to angular-momentum eigenvalues ± 2 ℏ . Weak magnetic fields enhance the conductivity, reaching the maximal value near the crossover field BL=4/3 √{3 }(ℏ /e ) t't⊥[t02a (Ro-Ri) ]-1 , where t0 (t⊥) is the nearest-neighbor intralayer (interlayer) hopping integral, t' is the skew-interlayer hopping integral, and Ro (Ri) is the outer (inner) disk radius. For magnetic fields B ≳ BL we observe quasiperiodic conductance oscillations characterized by the decreasing mean value <σ > -σ0∝ BL/B , where σ0=(8 /π ) e2/h . The conductivity, as well as higher charge-transfer cumulants, show beating patterns with an envelope period proportional to √{B /BL }. This constitutes a qualitative difference between the high-field (B ≫ BL ) magnetotransport in the t'=0 case [earlier discussed in Rut and Rycerz, J. Phys.: Condens. Matter 26, 485301 (2014), 10.1088/0953-8984/26/48/485301] and in the t'≠ 0 case, providing a finite-system analog of the Lifshitz transition.

  6. Nuclear magnetic resonance in optimally-doped YBCO and the electronic phases of bilayer graphene

    NASA Astrophysics Data System (ADS)

    Throckmorton, Robert E.

    We treat two different problems in condensed matter physics. The first concerns nuclear magnetic resonance (NMR) in optimally-doped YBCO in the mixed state. We show that the line shape is broadened due to the fact that the Knight shift becomes position-dependent in the mixed state. We also identify a second mechanism, in which a pair of spin up quasiparticles is emitted or absorbed, by which the nuclear spins can relax in the presence of a magnetic field, and show that this second mechanism dominates at low temperatures. We then compare our results to experimental data on 17O NMR and show that it is possible to explain the data without invoking the presence of antiferromagnetic correlations in the vortex cores. In fact, we show that the effects of such correlations on the 17O relaxation rates are suppressed in the mixed state, as they are in the normal state. The second problem concerns the electronic phases of bilayer graphene at half filling. Using finite-temperature weak-coupling RG methods, we are able to analytically determine all possible outcomes of the RG flow equations for the nine coupling constants. From this, we are able to determine all of the possible leading instabilities that the system may exhibit as its temperature is lowered. We find that the full phase diagram exhibits a very rich structure, with many different possible instabilities. We then specialize to the case of finite range density-density interactions. We introduce such an interaction into the microscopic tight-binding model and show how it can be related to the coupling constants in the lowenergy effective theory, and apply these results to determine the leading instabilities of the system as a function of the range of the interaction. We consider two forms of the interaction, both motivated by experimental setups, namely a potential like that produced by an electron in the presence of an infinite conducting plate, and like that produced by an electron situated exactly halfway between

  7. Schottky barrier contrasts in single and bi-layer graphene contacts for MoS{sub 2} field-effect transistors

    SciTech Connect

    Du, Hyewon; Kim, Taekwang; Shin, Somyeong; Kim, Dahye; Seo, Sunae; Kim, Hakseong; Lee, Sang Wook; Sung, Ji Ho; Jo, Moon-Ho; Lee, Myoung Jae; Seo, David H.

    2015-12-07

    We have investigated single- and bi-layer graphene as source-drain electrodes for n-type MoS{sub 2} transistors. Ti-MoS{sub 2}-graphene heterojunction transistors using both single-layer MoS{sub 2} (1M) and 4-layer MoS{sub 2} (4M) were fabricated in order to compare graphene electrodes with commonly used Ti electrodes. MoS{sub 2}-graphene Schottky barrier provided electron injection efficiency up to 130 times higher in the subthreshold regime when compared with MoS{sub 2}-Ti, which resulted in V{sub DS} polarity dependence of device parameters such as threshold voltage (V{sub TH}) and subthreshold swing (SS). Comparing single-layer graphene (SG) with bi-layer graphene (BG) in 4M devices, SG electrodes exhibited enhanced device performance with higher on/off ratio and increased field-effect mobility (μ{sub FE}) due to more sensitive Fermi level shift by gate voltage. Meanwhile, in the strongly accumulated regime, we observed opposing behavior depending on MoS{sub 2} thickness for both SG and BG contacts. Differential conductance (σ{sub d}) of 1M increases with V{sub DS} irrespective of V{sub DS} polarity, while σ{sub d} of 4M ceases monotonic growth at positive V{sub DS} values transitioning to ohmic-like contact formation. Nevertheless, the low absolute value of σ{sub d} saturation of the 4M-graphene junction demonstrates that graphene electrode could be unfavorable for high current carrying transistors.

  8. Dissimilar stability of proteins in graphene bilayer: a molecular dynamics study

    NASA Astrophysics Data System (ADS)

    Sun, Tiedong; Kiong Chan, Kwok; Su, Haibin; Zhang, Dawei

    2013-02-01

    In order to study protein stability on graphene surface and in a confined space simultaneously, two parallel graphene single layers were built and two structurally dissimilar protein molecules were placed in between. Molecular dynamics simulation results showed a significant denaturing effect of graphene layers on GA module, a 3-α helices bundle protein, while another α/β structure protein, protein G, kept its NMR structure intact throughout all simulations. Such extremely different denaturation behaviours of the proteins offer a good chance to investigate the mechanism of graphene toxicity. Further analysis showed Van der Waals interaction could be the main cause of the denaturing effect. Although the solvation effect can contribute, its contribution is not comparable with the Van der Waals interaction.

  9. Label-Free Electrochemiluminescence Aptasensor for 2,4,6-Trinitrotoluene Based on Bilayer Structure of Luminescence Functionalized Graphene Hybrids.

    PubMed

    Li, Guixin; Yu, Xiuxia; Liu, Danqing; Liu, Xiaoying; Li, Fang; Cui, Hua

    2015-11-01

    The electrochemiluminescence (ECL) behavior of N-(aminobutyl)-N-(ethylisoluminol)/hemin dual-functionalized graphene hybrids (A-H-GNs) and luminol-functionalized silver/graphene oxide composite (luminol-AgNPs-GO) was investigated under cyclic voltammetry and pulse potential. It was found that A-H-GNs and luminol-AgNPs-GO exhibited excellent ECL activity. On this basis, a label-free ECL aptasensor for 2,4,6-trinitrotoluene (TNT) detection was developed based on bilayer structure of luminescence functionalized graphene hybrids consisting of A-H-GNs and luminol-AgNPs-GO. First, positively charged chitosan-coated A-H-GNs were modified on the surface of indium-doped tin oxide electrode by simple dripping and drying in the air; after that, the modified electrode was immersed in negatively charged luminol-AgNPs-GO modified with aptamer (apta-biotin-SA-luminol-AgNPs-GO) to form apta-biotin-SA-luminol-AgNPs-GO/CS-A-H-GNs/ITO electrode (i.e., aptasensor) by electrostatic interaction. In the presence of TNT, a remarkable decrease in ECL signals was observed due to the formation of aptamer-TNT complex. TNT could be detected based on the inhibition effect. The aptasensor exhibits a wide dynamic range from 1.0 × 10(-12) to 1.0 × 10(-9) g/mL, with a low detection limit of 6.3 × 10(-13) g/mL for the determination of TNT, which is superior to most previously reported bioassays for TNT. Moreover, the proposed aptasensor has been successfully applied to the detection of TNT in environmental water. It is sensitive, selective, and simple, avoiding complicated labeling and purification procedures. Due to the wide target recognition range of aptamer, this strategy provides a promising way to develop new aptasensor for other analytes. PMID:26463226

  10. Interaction-driven capacitance in graphene electron-hole bilayer in the quantum Hall regime

    NASA Astrophysics Data System (ADS)

    Roostaei, Bahman; Joglekar, Yogesh

    2014-03-01

    Fabrication of devices made by isolated Graphene or Graphene-like single layers (such as h-BN) has opened up possibility of examining highly correlated states of electron systems in parts of their phase diagram that is impossible to access in their counterpart devices such as semiconductor heterostructures. An example of such states are Graphene (or Graphene like) double layer electron-hole systems under strong magnetic fields where the separation between layers can be of the order of one magnetic length with interlayer tunneling still suppressed. In those separations correlations between electrons and holes are of crucial importance and must be included in determination of observables. Here we report a thorough mean-field study of the coherent and crystalline ground states of the interacting balanced electron-hole Graphene systems in small and intermediate separations with each layer occupying up to four lowest lying Landau levels. We calculate the capacitance of such states as a function of layer separation and filling factor. Our calculations show significant enhancement of the capacitance compared to geometrical value due to quantum mechanical corrections. US nsf-dmr 1054020

  11. Liquid-assisted tip manipulation: fabrication of twisted bilayer graphene superlattices on HOPG

    NASA Astrophysics Data System (ADS)

    Yin, Long Jing; Wang, Wen Xiao; Feng, Ke Ke; Nie, Jia-Cai; Xiong, Chang Min; Dou, Rui-Fen; Naugle, Donald G.

    2015-09-01

    We use the tip of a scanning tunneling microscope (STM) to manipulate single weakly bound nanometer-sized sheets on a highly oriented pyrolytic graphite (HOPG) surface through artificially increasing the tip and sample interaction by pretreatment of the surface using a liquid thiol molecule. By this means it is possible to tear apart a graphite sheet against a step and fold this part onto the HOPG surface and thus generate graphene superlattices with hexagonal symmetry. The tip and sample surface interactions, including the van der Waals force, electrostatic force and capillary attraction force originating from the Laplace pressure due to the formation of a highly curved fluid meniscus connecting the tip and sample, are discussed quantitatively to understand the formation mechanism of a graphene superlattice induced by the STM tip. The capillary force plays a key role in manipulating the graphite surface sheet under humid conditions. Our approach provides a simple and feasible route to prepare controllable superlattices and graphene nanoribbons and also to better understand the process of generation of a graphene superlattice on the surface of HOPG with the tip.We use the tip of a scanning tunneling microscope (STM) to manipulate single weakly bound nanometer-sized sheets on a highly oriented pyrolytic graphite (HOPG) surface through artificially increasing the tip and sample interaction by pretreatment of the surface using a liquid thiol molecule. By this means it is possible to tear apart a graphite sheet against a step and fold this part onto the HOPG surface and thus generate graphene superlattices with hexagonal symmetry. The tip and sample surface interactions, including the van der Waals force, electrostatic force and capillary attraction force originating from the Laplace pressure due to the formation of a highly curved fluid meniscus connecting the tip and sample, are discussed quantitatively to understand the formation mechanism of a graphene superlattice

  12. Liquid-assisted tip manipulation: fabrication of twisted bilayer graphene superlattices on HOPG.

    PubMed

    Yin, Long Jing; Wang, Wen Xiao; Feng, Ke Ke; Nie, Jia-Cai; Xiong, Chang Min; Dou, Rui-Fen; Naugle, Donald G

    2015-09-28

    We use the tip of a scanning tunneling microscope (STM) to manipulate single weakly bound nanometer-sized sheets on a highly oriented pyrolytic graphite (HOPG) surface through artificially increasing the tip and sample interaction by pretreatment of the surface using a liquid thiol molecule. By this means it is possible to tear apart a graphite sheet against a step and fold this part onto the HOPG surface and thus generate graphene superlattices with hexagonal symmetry. The tip and sample surface interactions, including the van der Waals force, electrostatic force and capillary attraction force originating from the Laplace pressure due to the formation of a highly curved fluid meniscus connecting the tip and sample, are discussed quantitatively to understand the formation mechanism of a graphene superlattice induced by the STM tip. The capillary force plays a key role in manipulating the graphite surface sheet under humid conditions. Our approach provides a simple and feasible route to prepare controllable superlattices and graphene nanoribbons and also to better understand the process of generation of a graphene superlattice on the surface of HOPG with the tip. PMID:26290114

  13. Organosilane-functionalized graphene quantum dots and their encapsulation into bi-layer hollow silica spheres for bioimaging applications.

    PubMed

    Wen, Ting; Yang, Baocheng; Guo, Yanzhen; Sun, Jing; Zhao, Chunmei; Zhang, Shouren; Zhang, Miao; Wang, Yonggang

    2014-11-14

    Graphene quantum dots (GQDs) represent an important class of luminescent quantum dots owing to their low toxicity and superior biocompatibility. Chemical functionalization of GQDs and subsequent combination with other materials further provide attractive techniques for advanced bioapplications. Herein, we report the facile fabrication of fluorescent organosilane-functionalized graphene quantum dots (Si-GQDs) and their embedding into mesoporous hollow silica spheres as a biolabel for the first time. Well-proportioned Si-GQDs with bright and excitation dependent tunable emissions in the visible region were obtained via a simple and economical solvothermal route adopting graphite oxide as a carbon source and 3-(2-aminoethylamino)-propyltrimethoxysilane as a surface modifier. The as-synthesized Si-GQDs can be well dispersed and stored in organic solvents, easily manufactured into transparent film and bulk form, and particularly provide great potential to be combined with other materials. As a proof-of-principle experiment, we demonstrate the successful incorporation of Si-GQDs into hollow mesoporous silica spheres and conduct preliminary cellular imaging experiments. Interestingly, the Si-GQDs not only serve as fluorescent chromophores in the composite material, but also play a crucial role in the formation of mesoporous hollow silica spheres with a distinctive bi-layer architecture. The layer thickness and optical properties can be precisely controlled by simply adjusting the silane coupling agent addition procedure in the preparation process. Our demonstration of low-cost Si-GQDs and their encapsulation into multifunctional composites may expand the applications of carbon-based nanomaterials for future biomedical imaging and other optoelectronic applications. PMID:25255171

  14. Effect of impurity doping on tunneling conductance in AB-stacked bi-layer graphene: A tight-binding study

    NASA Astrophysics Data System (ADS)

    Rout, G. C.; Sahu, Sivabrata; Panda, S. K.

    2016-04-01

    We report here a microscopic tight-binding model calculation for AB-stacked bilayer graphene in presence of biasing potential between the two layers and the impurity effects to study the evolution of the total density of states with special emphasis on opening of band gap near Dirac point. We have calculated the electron Green's functions for both the A and B sub-lattices by Zubarev technique. The imaginary part of the Green's function gives the partial and total density of states of electrons. The density of states are computed numerically for 1000 × 1000 grid points of the electron momentum. The evolution of the opening of band gap near van-Hove singularities as well as near Dirac point is investigated by varying the different interlayer hoppings and the biasing potentials. The inter layer hopping splits the density of states at van-Hove singularities and produces a V-shaped gap near Dirac point. Further the biasing potential introduces a U shaped gap near Dirac point with a density minimum at the applied potential(i.e. at V/2).

  15. An exact solution of the linearized Boltzmann transport equation and its application to mobility calculations in graphene bilayers

    NASA Astrophysics Data System (ADS)

    Paussa, A.; Esseni, D.

    2013-03-01

    This paper revisits the problem of the linearized Boltzmann transport equation (BTE), or, equivalently, of the momentum relaxation time, momentum relaxation time (MRT), for the calculation of low field mobility, which in previous works has been almost universally solved in approximated forms. We propose an energy driven discretization method that allows an exact determination of the relaxation time by solving a linear, algebraic problem, where multiple scattering mechanisms are naturally accounted for by adding the corresponding scattering rates before the calculation of the MRT, and without resorting to the semi-empirical Matthiessen's rule for the relaxation times. The application of our rigorous solution of the linearized BTE to a graphene bilayer reveals that, for a non monotonic energy relation, the relaxation time can legitimately take negative values with no unphysical implications. We finally compare the mobility calculations provided by an exact solution of the MRT problem with the results obtained with some of the approximations most frequently employed in the literature and so discuss their accuracy.

  16. Moiré scaling of the sliding force in twisted bilayer graphene

    NASA Astrophysics Data System (ADS)

    Koren, E.; Duerig, U.

    2016-07-01

    The weak interlayer binding in two-dimensional layered materials such as graphite gives rise to distinguished low-friction properties if the atomic lattices at the interface are rotated with respect to one another. The lack of crystal symmetry leads to poorly understood correlations and cancelations of the interlayer atomic forces. Here we report on a powerful tiling method based on the moiré superstructure which allows us to study the intricate interplay of the interlayer forces in a systematic manner. Based on numerical simulation data for a circular graphene flake on an infinite graphene substrate, it is shown that the sliding force is dominated by a rim area consisting of incomplete moiré tiles. This rim force, which scales with the number of atoms in a moiré tile and as the radius to the power of 0.5, is minimal whenever the sliding structure can be approximated by a hexagon composed of an integer number Nt of moiré tiles. Intriguingly, the corresponding area force scales as Nt to the power of 0.25, i.e., it increases with size, whereas it has been often argued that interlayer forces should add up to a zero value for large twisted systems. However, at specific twist angles the moiré structure is commensurate with the graphene lattice, leading to a perfect force correlation in the moiré tiles. Correspondingly, the area force becomes dominant and scales as Nt, i.e., as the radius to the power of 2.

  17. Protein-Based Graphene Biosensors: Optimizing Artificial Chemoreception in Bilayer Lipid Membranes.

    PubMed

    Siontorou, Christina G; Georgopoulos, Konstantinos N; Nikoleli, Georgia-Paraskevi; Nikolelis, Dimitrios P; Karapetis, Stefanos K; Bratakou, Spyridoula

    2016-01-01

    Proteinaceous moieties are critical elements in most detection systems, including biosensing platforms. Their potential is undoubtedly vast, yet many issues regarding their full exploitation remain unsolved. On the other hand, the biosensor formats with the higher marketability probabilities are enzyme in nature and electrochemical in concept. To no surprise, alternative materials for hosting catalysis within an electrode casing have received much attention lately to demonstrate a catalysis-coated device. Graphene and ZnO are presented as ideal materials to modify electrodes and biosensor platforms, especially in protein-based detection. Our group developed electrochemical sensors based on these nanomaterials for the sensitive detection of cholesterol using cholesterol oxidase incorporated in stabilized lipid films. A comparison between the two platforms is provided and discussed. In a broader sense, the not-so-remote prospect of quickly assembling a protein-based flexible biosensing detector to fulfill site-specific requirements is appealing to both university researchers and industry developers. PMID:27618113

  18. Ab-initio calculation of electronic structure and optical properties of AB-stacked bilayer α-graphyne

    NASA Astrophysics Data System (ADS)

    Behzad, Somayeh

    2016-09-01

    Monolayer α-graphyne is a new two-dimensional carbon allotrope with many special features. In this work the electronic properties of AA- and AB-stacked bilayers of this material and then the optical properties are studied, using first principle plane wave method. The electronic spectrum has two Dirac cones for AA stacked bilayer α-graphyne. For AB-stacked bilayer, the interlayer interaction changes the linear bands into parabolic bands. The optical spectra of the most stable AB-stacked bilayer closely resemble to that of the monolayer, except for small shifts of peak positions and increasing of their intensity. For AB-stacked bilayer, a pronounced peak has been found at low energies under the perpendicular polarization. This peak can be clearly ascribed to the transitions at the Dirac point as a result of the small degeneracy lift in the band structure.

  19. Raman spectroscopy and in situ Raman spectroelectrochemistry of isotopically engineered graphene systems.

    PubMed

    Frank, Otakar; Dresselhaus, Mildred S; Kalbac, Martin

    2015-01-20

    beyond the three-layer systems, for example, to heterostructures containing other 2-D materials beyond graphene. Despite a great deal of important results being unraveled so far through the in situ spectroelectrochemistry of graphene based systems, many intriguing challenges still lie immediately ahead. For example, apart from the aforementioned 2-D heterostructures, a substantial effort should be put into a more detailed exploration of misoriented (twisted) bilayer or trilayer graphenes. Marching from the oriented, AB-stacked to AA-stacked, bilayers, every single angular increment of the twist between the layers creates a new system in terms of its electronic properties. Mapping those properties and interlayer interactions dependent on the twist angle represents a sizable task, yet the reward might be the path toward the realization of various types of advanced devices. And last but not least, understanding the electrochemistry of graphene paves the way toward a controlled and targeted functionalization of graphene through redox reactions, especially when equipped with the possibility of an instantaneous monitoring of the thus introduced changes to the electronic structure of the system. PMID:25569178

  20. Zero-energy modes and valley asymmetry in the Hofstadter spectrum of bilayer graphene van der Waals heterostructures with hBN

    NASA Astrophysics Data System (ADS)

    Chen, Xi; Wallbank, J. R.; Mucha-Kruczyński, M.; McCann, E.; Fal'ko, V. I.

    2016-07-01

    We investigate the magnetic minibands of a heterostructure consisting of bilayer graphene (BLG) and hexagonal boron nitride (hBN) by numerically diagonalizing a two-band Hamiltonian that describes electrons in BLG in the presence of a moiré potential. Due to inversion-symmetry breaking characteristic for the moiré potential, the valley symmetry of the spectrum is broken, but despite this, the zero-energy Landau level in BLG survives, albeit with reduced degeneracy. In addition, we derive effective models for the low-energy features in the magnetic minibands and demonstrate the appearance of secondary Dirac points in the valence band, which we confirm by numerical simulations. Then, we analyze how single-particle gaps in the fractal energy spectrum produce a sequence of incompressible states observable under a variation of carrier density and magnetic field.

  1. Eighty-Eight Percent Directional Guiding of Spin Currents with 90 μm Relaxation Length in Bilayer Graphene Using Carrier Drift.

    PubMed

    Ingla-Aynés, Josep; Meijerink, Rick J; Wees, Bart J van

    2016-08-10

    Electrical control of spin signals and long distance spin transport are major requirements in the field of spin electronics. Here, we report the efficient guiding of spin currents at room temperature in high mobility hexagonal boron nitride encapsulated bilayer graphene using carrier drift. Our experiments, together with modeling, show that the spin relaxation length, that is 7.7 μm at zero bias, can be tuned from 0.6 to 90 μm when applying a DC current of ∓90 μA, respectively. Our results also show that we are able to direct spin currents to either side of a spin injection contact. Eighty-eight percent of the injected spins flows to the left when Idc = -90 μA and eighty-two percent flows to the right when the drift current is reversed. These results show the potential of carrier drift for spin-based logic operations and devices. PMID:27399228

  2. The stacking dependent electronic structure and optical properties of bilayer black phosphorus.

    PubMed

    Shu, Huabing; Li, Yunhai; Niu, Xianghong; Wang, Jinlan

    2016-02-17

    By employing density-functional theory, the G0W0 method and Bethe-Salpter equation, we explore quasi-particle energy bands, optical responses and excitons of bilayer black phosphorus (BBP) with four different stacking patterns. All the structures are direct band gap semiconductors and the band gap is highly dependent on the stacking pattern, with a maximum of 1.31 eV for AB-stacking and a minimum of 0.92 eV for AD-stacking. Such dependence can be well understood by the tight-binding model in terms of the interlayer hopping. More interestingly, stacking sensitive optical absorption and exciton binding energy are observed in BBPs. For x-polarized light, more red-shift of optical adsorption appears in AA-stacking and the strong exciton binding energy in the AA-stacking bilayer can be as large as 0.82 eV, that is ∼1.7 times larger than that of AD-stacking bilayer. PMID:26845322

  3. Selective area growth of Bernal bilayer epitaxial graphene on 4H-SiC (0001) substrate by electron-beam irradiation

    SciTech Connect

    Dharmaraj, P.; Jeganathan, K.; Parthiban, S.; Kwon, J. Y.; Gautam, S.; Chae, K. H.; Asokan, K.

    2014-11-03

    We report selective area growth of large area homogeneous Bernal stacked bilayer epitaxial graphene (BLEG) on 4H-SiC (0001) substrate by electron-beam irradiation. Sublimation of Si occurs by energetic electron irradiations on SiC surface via breaking of Si–C bonds in the localized region, which allows the selective growth of graphene. Raman measurements ensure the formation of homogeneous BLEG with weak compressive strain of −0.08%. The carrier mobility of large area BLEG is ∼5100 cm{sup 2} V{sup −1} s{sup −1} with a sheet carrier density of 2.2 × 10{sup 13} cm{sup −2}. Current-voltage measurements reveal that BLEG on 4H-SiC forms a Schottky junction with an operation at mA level. Our study reveals that the barrier height at the Schottky junction is low (∼0.58 eV) due to the Fermi-level pinning above the Dirac point.

  4. Orbital-specific Tunability of Many-Body Effects in Bilayer Graphene by Gate Bias and Metal Contact

    NASA Astrophysics Data System (ADS)

    Fukidome, Hirokazu; Kotsugi, Masato; Nagashio, Kosuke; Sato, Ryo; Ohkochi, Takuo; Itoh, Takashi; Toriumi, Akira; Suemitsu, Maki; Kinoshita, Toyohiko

    2014-01-01

    Graphene, a 2D crystal bonded by π and σ orbitals, possesses excellent electronic properties that are promising for next-generation optoelectronic device applications. For these a precise understanding of quasiparticle behaviour near the Dirac point (DP) is indispensable because the vanishing density of states (DOS) near the DP enhances many-body effects, such as excitonic effects and the Anderson orthogonality catastrophe (AOC) which occur through the interactions of many conduction electrons with holes. These effects renormalize band dispersion and DOS, and therefore affect device performance. For this reason, we have studied the impact of the excitonic effects and the AOC on graphene device performance by using X-ray absorption spectromicroscopy on an actual graphene transistor in operation. Our work shows that the excitonic effect and the AOC are tunable by gate bias or metal contacts, both of which alter the Fermi energy, and are orbital-specific.

  5. Layer-by-layer self-assembled multilayer films composed of graphene/polyaniline bilayers: high-energy electrode materials for supercapacitors.

    PubMed

    Sarker, Ashis K; Hong, Jong-Dal

    2012-08-28

    Multilayer assemblies of uniform ultrathin film electrodes with good electrical conductivity and very large surface areas were prepared for use as electrochemical capacitors. A layer-by-layer self-assembly approach was employed in an effort to improve the processability of highly conducting polyaniline (PANi) and chemically modified graphene. The electrochemical properties of the multilayer film (MF-) electrodes, including the sheet resistance, volumetric capacitance, and charge/discharge ratio, were determined by the morphological modification and the method used to reduce the graphene oxide (GO) to reduced graphene oxide (RGO) in the multilayer films. The PANi and GO concentrations could be modulated to control the morphology of the GO monolayer film in the multilayer assemblies. Optical ellipsometry was used to determine the thickness of the GO film in a single layer (1.32 nm), which agreed well with the literature value (~1.3 nm). Hydroiodic acid (HI), hydrazine, or pyrolysis were tested for the reduction of GO to RGO. HI was found to be the most efficient technique for reducing the GO to RGO in the multilayer assemblies while minimizing damage to the virgin state of the acid-doped PANi. Ultimately, the MF-electrode, which could be optimized by fine-tuning the nanostructure and selecting a suitable reduction method, exhibited an excellent volumetric capacitance, good cycling stability, and a rapid charge/discharge rate, which are required for supercapacitors. A MF-electrode composed of 15 PANi/RGO bilayers yielded a volumetric capacitance of 584 F/cm(3) at a current density of 3.0 A/cm(3). Although this value decreased exponentially as the current density increased, approaching a value of 170 F/cm(3) at 100 A/cm(3), this volumetric capacitance is one of the best yet reported for the other carbon-based materials. The intriguing features of the MF-electrodes composed of PANi/RGO multilayer films offer a new microdimensional design for high energy storage devices

  6. Doping, strain engineering, and interlayer interaction in bilayer hexagonal boron nitride sheets

    NASA Astrophysics Data System (ADS)

    Saito, Susumu; Fujimoto, Yoshitaka

    We study electronic properties of bilayer hexagonal boron nitride (h-BN) sheets with different stacking sequences in the framework of the density-functional theory. The bulk h-BN material usually takes the so-called AA (or AA') stacking, corresponding to the ''non-polar'' bilayer h-BN sheet. On the other hand, the rhombohedral BN takes the ABC stacking, and the corresponding bilayer sheet has ''upper'' and ''lower'' layers which are not equivalent with each other. Interestingly, the energetics of stacking sequences for bilayer h-BN sheets is found to be different from that for bulk h-BN materials. We report that strain engineering for bilayer h-BN sheets can possess much wider possibilities than that for monolayer h-BN due to the modification of the interlayer interaction. We also study the substitutional C doping into bilayer h-BN sheets, and report the energetics and the strain effect for these C-doped sheets. Finally we discuss the similarities and differences between bilayer h-BN sheets and double-wall h-BN nanotubes. This work was partly supported by the MEXT Elements Strategy Initiative to Form Core Research Center, Grant in Aid for Scientific Research, MEXT Japan, ``Science of Atomic Layers'', and JSPS KAKENHI Grant No. 26390062.

  7. Molecular-beam epitaxy and robust superconductivity of stoichiometric FeSe crystalline films on bilayer graphene

    SciTech Connect

    Song Canli; Jiang Yeping; Xue Qikun; Wang Yilin; Li Zhi; Wang Lili; He Ke; Ma Xucun; Chen Xi

    2011-07-01

    We report on molecular beam epitaxy growth of stoichiometric and superconducting FeSe crystalline thin films on double-layer graphene. Layer-by-layer growth of high-quality films has been achieved in a well-controlled manner by using Se-rich condition, which allow us to investigate the thickness-dependent superconductivity of FeSe. In situ low-temperature scanning tunneling spectra reveal that the local superconducting gap in the quasiparticle density of states is visible down to two triple layers for the minimum measurement temperature of 2.2 K, and that the transition temperature T{sub c} scales inversely with film thickness.

  8. Enhanced configurational entropy in high-density nanoconfined bilayer ice

    NASA Astrophysics Data System (ADS)

    Corsetti, Fabiano; Zubeltzu, Jon; Artacho, Emilio

    Understanding the structural tendencies of nanoconfined water is of great interest for nanoscience and biology, where nano/micro-sized objects may be separated by very few layers of water. We present a study of water confined to a 2D geometry by a featureless, chemically neutral potential, in order to characterize its intrinsic behaviour. We use molecular dynamics simulations with the TIP4P/2005 potential, combined with density-functional theory calculations with a non-local van der Waals density functional and an ab initio random structure search procedure. We propose a novel kind of crystal order in high-density nanoconfined bilayer ice. A first-order transition is observed between a low-temperature proton-ordered solid and a high-temperature proton-disordered solid. The latter is shown to possess crystalline order for the oxygen positions, arranged on a close-packed triangular lattice with AA stacking. Uniquely amongst the ice phases, the triangular bilayer is characterized by two levels of disorder (for the bonding network and for the protons) which results in a configurational entropy twice that of bulk ice.

  9. Theory of Bilayer Graphene Spectroscopy

    NASA Astrophysics Data System (ADS)

    Mucha-Kruczyński, Marcin

    With many models in physics, it is much easier to conceive a Gedankenexperiment and analyse it on paper, rather than prepare a real-life experiment. It is definitely the case when imagining a single plane of carbon atoms arranged in a honeycomb (hexagonal) pattern.

  10. Graphene on graphene antidot lattices: Electronic and transport properties

    NASA Astrophysics Data System (ADS)

    Gregersen, Søren Schou; Pedersen, Jesper Goor; Power, Stephen R.; Jauho, Antti-Pekka

    2015-03-01

    Graphene bilayer systems are known to exhibit a band gap when the layer symmetry is broken by applying a perpendicular electric field. The resulting band structure resembles that of a conventional semiconductor with a parabolic dispersion. Here, we introduce a bilayer graphene heterostructure, where single-layer graphene is placed on top of another layer of graphene with a regular lattice of antidots. We dub this class of graphene systems GOAL: graphene on graphene antidot lattice. By varying the structure geometry, band-structure engineering can be performed to obtain linearly dispersing bands (with a high concomitant mobility), which nevertheless can be made gapped with a perpendicular field. We analyze the electronic structure and transport properties of various types of GOALs, and draw general conclusions about their properties to aid their design in experiments.

  11. Monolayer graphene from a green solid precursor

    NASA Astrophysics Data System (ADS)

    Kalita, Golap; Wakita, Koichi; Umeno, Masayoshi

    2011-06-01

    Monolayer and bilayer graphene sheets are synthesized by simple control pyrolysis of solid botanical derivative camphor (C 10H 16O), a green and renewable carbon source. Raman studies show much intense 2D peak than that of G peak, signifying presence of monolayer graphene. Transmission electron microscopic study shows predominately monolayer or bilayer graphene sheets, while trilayer graphene sheet were also observed. Synthesized graphene film on copper foil is transferred to poly(ethylene terephthalate) substrate to fabricate transparent electrode. Electrical and optical measurement shows a sheet resistance of 860 Ω/sq with a transmittance of 91% at 550 nm wavelength of the graphene film. The technique to fabricate monolayer or bilayer graphene based film from camphor is both viable and scalable for potential large area electronic applications.

  12. Electronic structure theory of weakly interacting bilayers

    NASA Astrophysics Data System (ADS)

    Fang, Shiang; Kaxiras, Efthimios

    2016-06-01

    We derive electronic structure models for weakly interacting bilayers such as graphene-graphene and graphene-hexagonal boron nitride, based on density functional theory calculations followed by Wannier transformation of electronic states. These transferable interlayer coupling models can be applied to investigate the physics of bilayers with arbitrary translations and twists. The functional form, in addition to the dependence on the distance, includes the angular dependence that results from higher angular momentum components in the Wannier pz orbitals. We demonstrate the capabilities of the method by applying it to a rotated graphene bilayer, which produces the analytically predicted renormalization of the Fermi velocity, Van Hove singularities in the density of states, and moiré pattern of the electronic localization at small twist angles. We further extend the theory to obtain the effective couplings by integrating out neighboring layers. This approach is instrumental for the design of van der Walls heterostructures with desirable electronic features and transport properties and for the derivation of low-energy theories for graphene stacks, including proximity effects from other layers.

  13. Unraveling the Intrinsic and Robust Nature of van Hove Singularities in Twisted Bilayer Graphene by Scanning Tunneling Microscopy and Theoretical Analysis

    NASA Astrophysics Data System (ADS)

    Brihuega, I.; Mallet, P.; González-Herrero, H.; Trambly de Laissardière, G.; Ugeda, M. M.; Magaud, L.; Gómez-Rodíguez, J. M.; Ynduráin, F.; Veuillen, J.-Y.

    2012-11-01

    Extensive scanning tunneling microscopy and spectroscopy experiments complemented by first-principles and parametrized tight binding calculations provide a clear answer to the existence, origin, and robustness of van Hove singularities (vHs) in twisted graphene layers. Our results are conclusive: vHs due to interlayer coupling are ubiquitously present in a broad range (from 1° to 10°) of rotation angles in our graphene on 6H-SiC(000-1) samples. From the variation of the energy separation of the vHs with the rotation angle we are able to recover the Fermi velocity of a graphene monolayer as well as the strength of the interlayer interaction. The robustness of the vHs is assessed both by experiments, which show that they survive in the presence of a third graphene layer, and by calculations, which test the role of the periodic modulation and absolute value of the interlayer distance. Finally, we clarify the role of the layer topographic corrugation and of electronic effects in the apparent moiré contrast measured on the STM images.

  14. Excitonic condensation in bilayer systems

    NASA Astrophysics Data System (ADS)

    Su, Jung-Jung

    Among the many examples of Bose condensation considered in physics, electron-hole-pair (exciton) condensation has maintained special interest because it has been difficult to realize experimentally, and because of controversy about condensate properties. In this thesis, we studied the various aspects of spontaneous symmetry broken state of exciton in bilayer using mean field theory. We calculated the photoluminescence of excitonic condensation created by laser. We developed a one-dimensional toy model of excitonic supercurrent using mean field theory plus non-equilibrium Green's function (NEGF) which give qualitatively consistent results with experiments. We proposed graphene bilayer as a novel system for excitonic condensation to occur and estimate it to exist even at temperature as high as room temperature.

  15. The selective transfer of patterned graphene

    PubMed Central

    Chen, Xu-Dong; Liu, Zhi-Bo; Jiang, Wen-Shuai; Yan, Xiao-Qing; Xing, Fei; Wang, Peng; Chen, Yongsheng; Tian, Jian-Guo

    2013-01-01

    We demonstrate a selective microcleaving graphene (MG) transfer technique for the transfer of graphene patterns and graphene devices onto chosen targets using a bilayer-polymer structure and femtosecond laser microfabrication. In the bilayer-polymer structure, the first layer is used to separate the target graphene from the other flakes, and the second layer transfers the patterned graphene to the chosen targets. This selective transfer technique, which exactly transfers the patterned graphene onto a chosen target, leaving the other flakes on the original substrate, provides an efficient route for the fabrication of MG for microdevices and flexible electronics and the optimization of graphene's performance. This method will facilitate the preparation of van der Waals heterostructures and enable the optimization of the performance of graphene hybrid devices. PMID:24225593

  16. EDITORIAL: Focus on Graphene

    NASA Astrophysics Data System (ADS)

    Peres, N. M. R.; Ribeiro, Ricardo M.

    2009-09-01

    Graphene physics is currently one of the most active research areas in condensed matter physics. Countless theoretical and experimental studies have already been performed, targeting electronic, magnetic, thermal, optical, structural and vibrational properties. Also, studies that modify pristine graphene, aiming at finding new physics and possible new applications, have been considered. These include patterning nanoribbons and quantum dots, exposing graphene's surface to different chemical species, studying multilayer systems, and inducing strain and curvature (modifying in this way graphene's electronic properties). This focus issue includes many of the latest developments on graphene research. Focus on Graphene Contents Electronic properties of graphene and graphene nanoribbons with 'pseudo-Rashba' spin-orbit coupling Tobias Stauber and John Schliemann Strained graphene: tight-binding and density functional calculations R M Ribeiro, Vitor M Pereira, N M R Peres, P R Briddon and A H Castro Neto The effect of sublattice symmetry breaking on the electronic properties of doped graphene A Qaiumzadeh and R Asgari Interfaces within graphene nanoribbons J Wurm, M Wimmer, I Adagideli, K Richter and H U Baranger Weak localization and transport gap in graphene antidot lattices J Eroms and D Weiss Electronic properties of graphene antidot lattices J A Fürst, J G Pedersen, C Flindt, N A Mortensen, M Brandbyge, T G Pedersen and A-P Jauho Splitting of critical energies in the n=0 Landau level of graphene Ana L C Pereira Double-gated graphene-based devices S Russo, M F Craciun, M Yamamoto, S Tarucha and A F Morpurgo Pinning and switching of magnetic moments in bilayer graphene Eduardo V Castro, M P López-Sancho and M A H Vozmediano Electronic transport properties of graphene nanoribbons Katsunori Wakabayashi, Yositake Takane, Masayuki Yamamoto and Manfred Sigrist Many-body effects on out-of-plane phonons in graphene J González and E Perfetto Graphene zigzag ribbons, square

  17. Induced superconductivity in graphene

    NASA Astrophysics Data System (ADS)

    Heersche, Hubert B.; Jarillo-Herrero, Pablo; Oostinga, Jeroen B.; Vandersypen, Lieven M. K.; Morpurgo, Alberto F.

    2007-07-01

    Graphene layers, prepared by mechanical exfoliation, were contacted by superconducting electrodes consisting of a titanium-aluminium bilayer. Quantum hall measurements in the normal state confirmed the single layer nature of the graphene samples. Proximity induced supercurrents were observed in all samples, below 1 K. Using a backgate, the Fermi energy could be swept from valence to conduction band via the Charge neutrality point, demonstrating supercurrents carried by holes and electrons, respectively. Interestingly, a finite supercurrent was also observed at the charge neutrality (or Dirac) point, where the density of carrier states vanishes. Our results demonstrate phase coherence in graphene.

  18. Graphene/ferroelectrics/graphene hybrid structure: Asymmetric doping of graphene layers

    SciTech Connect

    Duong, Dinh Loc; Lee, Si Young; Kim, Seong Kyu; Lee, Young Hee

    2015-06-15

    We report graphene/ferroelectric/graphene hybrid structure to demonstrate an asymmetrical doping in two graphene layers, one side with electrons and another side with holes. Two ferroelectrics, a poly(vinylidenefluoride) (PVDF) and a hydrofluorinated graphene, were used to demonstrate the concept with density functional calculations, revealing the Fermi level shift of 0.35 and 0.75 eV, respectively. This concept was confirmed by Raman spectroscopy using graphene/poly(vinylidenefluoride-co-trifluoroethylene) (P(VDF-TrFE))/graphene hybrid, which can easily form β-phase close to our simulation model. G-band peak position was downshifted for electron doping and upshifted for hole doping. This hybrid structure opens an opportunity to study bilayer graphene system with a controllable thickness for a wide range of high carrier concentration.

  19. The effect of electron induced hydrogenation of graphene on its electrical transport properties

    SciTech Connect

    Woo, Sung Oh; Teizer, Winfried

    2013-07-22

    We report a deterioration of the electrical transport properties of a graphene field effect transistor due to energetic electron irradiation on a stack of Poly Methyl Methacrylate (PMMA) on graphene (PMMA/graphene bilayer). Prior to electron irradiation, we observed that the PMMA layer on graphene does not deteriorate the carrier transport of graphene but improves its electrical properties instead. As a result of the electron irradiation on the PMMA/graphene bilayer, the Raman “D” band appears after removal of PMMA. We argue that the degradation of the transport behavior originates from the binding of hydrogen generated during the PMMA backbone secession process.

  20. Polycrystalline graphene with single crystalline electronic structure.

    PubMed

    Brown, Lola; Lochocki, Edward B; Avila, José; Kim, Cheol-Joo; Ogawa, Yui; Havener, Robin W; Kim, Dong-Ki; Monkman, Eric J; Shai, Daniel E; Wei, Haofei I; Levendorf, Mark P; Asensio, María; Shen, Kyle M; Park, Jiwoong

    2014-10-01

    We report the scalable growth of aligned graphene and hexagonal boron nitride on commercial copper foils, where each film originates from multiple nucleations yet exhibits a single orientation. Thorough characterization of our graphene reveals uniform crystallographic and electronic structures on length scales ranging from nanometers to tens of centimeters. As we demonstrate with artificial twisted graphene bilayers, these inexpensive and versatile films are ideal building blocks for large-scale layered heterostructures with angle-tunable optoelectronic properties. PMID:25207847

  1. Organic doping of rotated double layer graphene

    NASA Astrophysics Data System (ADS)

    George, Lijin; Jaiswal, Manu

    2016-05-01

    Charge transfer techniques have been extensively used as knobs to tune electronic properties of two- dimensional systems, such as, for the modulation of conductivity mobility of single layer graphene and for opening the bandgap in bilayer graphene. The charge injected into the graphene layer shifts the Fermi level away from the minimum density of states point (Dirac point). In this work, we study charge transfer in rotated double-layer graphene achieved by the use of organic dopant, Tetracyanoquinodimethane. Naturally occurring bilayer graphene has a well-defined A-B stacking whereas in rotated double-layer the two graphene layers are randomly stacked with different rotational angles. This rotation is expected to significantly alter the interlayer interaction. Double-layer samples are prepared using layer-by-layer assembly of chemical vapor deposited single-layer graphene and they are identified by characteristic resonance in the Raman spectrum. The charge transfer and distribution of charges between the two graphene layers is studied using Raman spectroscopy and the results are compared with that for single-layer and A-B stacked bilayer graphene doped under identical conditions.

  2. Evolution of interlayer coupling in twisted molybdenum disulfide bilayers

    NASA Astrophysics Data System (ADS)

    Liu, Kaihui; Zhang, Liming; Cao, Ting; Jin, Chenhao; Qiu, Diana; Zhou, Qin; Zettl, Alex; Yang, Peidong; Louie, Steve G.; Wang, Feng

    2014-09-01

    Van der Waals coupling is emerging as a powerful method to engineer physical properties of atomically thin two-dimensional materials. In coupled graphene-graphene and graphene-boron nitride layers, interesting physical phenomena ranging from Fermi velocity renormalization to Hofstadter’s butterfly pattern have been demonstrated. Atomically thin transition metal dichalcogenides, another family of two-dimensional-layered semiconductors, can show distinct coupling phenomena. Here we demonstrate the evolution of interlayer coupling with twist angles in as-grown molybdenum disulfide bilayers. We find that the indirect bandgap size varies appreciably with the stacking configuration: it shows the largest redshift for AA- and AB-stacked bilayers, and a significantly smaller but constant redshift for all other twist angles. Our observations, together with ab initio calculations, reveal that this evolution of interlayer coupling originates from the repulsive steric effects that leads to different interlayer separations between the two molybdenum disulfide layers in different stacking configurations.

  3. Supercurrent in Graphene Josephson Transistors

    NASA Astrophysics Data System (ADS)

    Bao, Wenzhong; Miao, Feng; Liu, Gang; Lau, Chunning

    2008-03-01

    We investigate electrical transport in single or bi-layer graphene devices coupled to superconducting electrodes. In these two-dimensional Josephson junctions, we observed gate tunable supercurrent, multiple Andreev reflections and hysteretic current-voltage characteristics. Latest experimental progress on dependence of supercurrent on temperature, number of layers and source-drain separation will be discussed.

  4. Large-scale real-space density-functional calculations: Moiré-induced electron localization in graphene

    SciTech Connect

    Oshiyama, Atsushi Iwata, Jun-Ichi; Uchida, Kazuyuki; Matsushita, Yu-Ichiro

    2015-03-21

    We show that our real-space finite-difference scheme allows us to perform density-functional calculations for nanometer-scale targets containing more than 100 000 atoms. This real-space scheme is applied to twisted bilayer graphene, clarifying that Moiré pattern induced in the slightly twisted bilayer graphene drastically modifies the atomic and electronic structures.

  5. Modeling vitreous silica bilayers

    NASA Astrophysics Data System (ADS)

    Kumar, Avishek; Wilson, Mark; Sherrington, David; Thorpe, Michael

    2014-03-01

    The recent synthesis and imaging of bilayers of vitreous silica has led to a wealth of new information. We have modeled the experimentally-observed bilayer using a computer assembly procedure to form a network of corner-sharing tetrahedra, which is then mirror-reflected to form a bilayer. We show that the vitreous silica bilayer has additional macroscopic degrees of freedom iff there is a symmetry plane through the center of the bilayer going through the central layer of oxygen ions that join the upper and lower monolayers. We have computer-refined the experimental coordinates to determine the density, and other structural characteristics such as the Si-Si pair distribution function, Si-O-Si bond angle distribution and the Aboav-Weaire law.

  6. Growth mechanism of graphene on graphene films grown by chemical vapor deposition.

    PubMed

    Kang, Cheong; Jung, Da Hee; Lee, Jin Seok

    2015-03-01

    We report an approach for the synthesis of mono- or bilayer graphene films by atmospheric-pressure chemical vapor deposition that can achieve a low defect density through control over the growth time. Different heating ramp rates were found to lead to variation in the smoothness and grain size of the Cu foil substrate, which directly influenced the density of the graphene domains. The rough Cu surface induced by rapid heating creates a high density of graphene domains in the initial stage, ultimately resulting in a graphene film with a high defect density due to an increased overlap between domains. Conversely, a slow heating rate resulted in a smooth and flat Cu surface, thereby lowering the density of the initial graphene domains and ensuring a uniform monolayer film. From this, we demonstrate that the growth mechanism of graphene on existing graphene films is dependent on the density of the initial graphene domains, which is affected by the heating ramp rate. PMID:25655906

  7. Substrate-Sensitive Graphene Oxidation.

    PubMed

    Zhang, Zhuhua; Yin, Jun; Liu, Xiaofei; Li, Jidong; Zhang, Jiahuan; Guo, Wanlin

    2016-03-01

    The inertness of graphene toward reaction with ambient molecules is essential for realizing durable devices with stable performance. Many device applications require graphene to contact with substrates, but whose impact on the chemical property of graphene has been largely overlooked. Here, we combine comprehensive first-principles analyses with experiments to show that graphene oxidation is highly sensitive to substrates. Graphene remains inert on SiO2 and hexagonal boron nitride but becomes increasingly weak against oxidation on metal substrates because of enhanced charge transfer and chemical interaction between them. In particular, Ni and Co substrates lead to spontaneous oxidation of graphene, while a Cu substrate maximally promotes the oxygen diffusion on graphene, with an estimated diffusivity 13 orders of magnitude higher than that on freestanding graphene. Bilayer graphene is revealed to have high oxidation resistance independent of substrate and thus is a better choice for high-performance nanoelectronics. Our findings should be extendable to a wide spectrum of chemical functionalizations of two-dimensional materials mediated by substrates. PMID:26884318

  8. Control of layer stacking in CVD graphene under quasi-static condition.

    PubMed

    Subhedar, Kiran M; Sharma, Indu; Dhakate, Sanjay R

    2015-09-14

    The type of layer stacking in bilayer graphene has a significant influence on its electronic properties because of the contrast nature of layer coupling. Herein, different geometries of the reaction site for the growth of bilayer graphene by the chemical vapor deposition (CVD) technique and their effects on the nature of layer stacking are investigated. Micro-Raman mapping and curve fitting analysis confirmed the type of layer stacking for the CVD grown bilayer graphene. The samples grown with sandwiched structure such as quartz/Cu foil/quartz along with a spacer, between the two quartz plates to create a sealed space, resulted in Bernal or AB stacked bilayer graphene while the sample sandwiched without a spacer produced the twisted bilayer graphene. The contrast difference in the layer stacking is a consequence of the difference in the growth mechanism associated with different geometries of the reaction site. The diffusion dominated process under quasi-static control is responsible for the growth of twisted bilayer graphene in sandwiched geometry while surface controlled growth with ample and continual supply of carbon in sandwiched geometry along with a spacer, leads to AB stacked bilayer graphene. Through this new approach, an efficient technique is presented to control the nature of layer stacking. PMID:26245487

  9. Structure of lipid bilayers

    PubMed Central

    Nagle, John F.; Tristram-Nagle, Stephanie

    2009-01-01

    The quantitative experimental uncertainty in the structure of fully hydrated, biologically relevant, fluid (Lα) phase lipid bilayers has been too large to provide a firm base for applications or for comparison with simulations. Many structural methods are reviewed including modern liquid crystallography of lipid bilayers that deals with the fully developed undulation fluctuations that occur in the Lα phase. These fluctuations degrade the higher order diffraction data in a way that, if unrecognized, leads to erroneous conclusions regarding bilayer structure. Diffraction measurements at high instrumental resolution provide a measure of these fluctuations. In addition to providing better structural determination, this opens a new window on interactions between bilayers, so the experimental determination of interbilayer interaction parameters is reviewed briefly. We introduce a new structural correction based on fluctuations that has not been included in any previous studies. Updated measurements, such as for the area compressibility modulus, are used to provide adjustments to many of the literature values of structural quantities. Since the gel (Lβ′) phase is valuable as a stepping stone for obtaining fluid phase results, a brief review is given of the lower temperature phases. The uncertainty in structural results for lipid bilayers is being reduced and best current values are provided for bilayers of five lipids. PMID:11063882

  10. Molecular memory with atomically smooth graphene contacts

    PubMed Central

    2013-01-01

    We report the use of bilayer graphene as an atomically smooth contact for nanoscale devices. A two-terminal bucky-ball (C60) based molecular memory is fabricated with bilayer graphene as a contact on the polycrystalline nickel electrode. Graphene provides an atomically smooth covering over an otherwise rough metal surface. The use of graphene additionally prohibits the electromigration of nickel into the C60 layer. The devices exhibit a low-resistance state in the first sweep cycle and irreversibly switch to a high-resistance state at 0.8 to 1.2 V bias. In the subsequent cycles, the devices retain the high-resistance state, thus making it write-once read-many memory. PMID:24225345

  11. Optical characterization of directly deposited graphene on a dielectric substrate.

    PubMed

    Kaplas, Tommi; Karvonen, Lasse; Ahmadi, Sepehr; Amirsolaimani, Babak; Mehravar, Soroush; Peyghambarian, Nasser; Kieu, Khanh; Honkanen, Seppo; Lipsanen, Harri; Svirko, Yuri

    2016-02-01

    By using scanning multiphoton microscopy we compare the nonlinear optical properties of the directly deposited and transferred to the dielectric substrate graphene. The direct deposition of graphene on oxidized silicon wafer was done by utilizing sacrificial copper catalyst film. We demonstrate that the directly deposited graphene and bi-layered transferred graphene produce comparable third harmonic signals and have almost the same damage thresholds. Therefore, we believe directly deposited graphene is suitable for the use of e.g. nanofabricated optical setups. PMID:26906863

  12. Optical properties of graphene simulated in MATLAB using scattering matrices

    NASA Astrophysics Data System (ADS)

    Cariappa K., S.; Kumar, Anil

    2016-04-01

    Transmittance and absorbance spectrum of monolayer and bilayer graphene are simulated, in wavelength range 400-900nm, using scattering matrices of graphene and air. MATLAB is used for simulations studies and the results are in good agreement with the experimental values reported in the literature. The high transmittance values exhibited by graphene along with its electrical properties make it a potential alternative to conventional transparent conducting oxides.

  13. Electrical and Mechanical Properties of Graphene

    NASA Astrophysics Data System (ADS)

    Bao, Wenzhong

    Graphene is an exciting new atomically-thin two-dimensional (2D) system of carbon atoms organized in a hexagonal lattice structure. This "wonder material" has been extensively studied in the last few years since it's first isolation in 2004. Its rapid rise to popularity in scientific and technological communities can be attributed to a number of its exceptional properties. In this thesis I will present several topics including fabrication of graphene devices, electrical and mechanical properties of graphene. I will start with a brief introduction of electronic transport in nanosclae system including quantum Hall effect, followed by a discussion of fundamental electrical and mechanical properties of graphene. Next I will describe how graphene devices are produced: from the famous "mechnical exfoliation" to our innovative "scratching exfoliation" method, together with the traditional lithography fabrication for graphene devices. We also developed a lithography-free technique for making electrical contacts to suspended graphene devices. Most of the suspended devices presented in this thesis are fabricated by this technique. Graphene has remarkable electrical properties thanks to its crystal and band structures. In Chapter 3, I will first focus on proximity-induced superconductivity in graphene Josephson transistors. In this section we investigate electronic transport in single layer graphene coupled to superconducting electrodes. We observe significant suppression in the critical current I c and large variation in the product IcR n in comparison to theoretic prediction; both phenomena can be satisfactorily accounted for by premature switching in underdamped Josephson junctions. Another focus of our studies is quantum Hall effect and many body physics in graphene in suspended bilayer and trilayer graphene. We demonstrate that symmetry breaking of the first 3 Landau levels and fractional quantum Hall states are observed in both bilayer and trilayer suspended graphene

  14. Graphene coatings: An efficient protection from oxidation

    NASA Astrophysics Data System (ADS)

    Topsakal, Mehmet; Sahin, Hasan; Ciraci, Salim

    2012-02-01

    We demonstrate that graphene coating can provide an efficient protection from oxidation by posing a high energy barrier to the path of oxygen atom, which could have penetrated from the top of graphene to the reactive surface underneath. Graphene bilayer, which blocks the diffusion of oxygen with a relatively higher energy barrier provides even better protection from oxidation. While an oxygen molecule is weakly bound to bare graphene surface and hence becomes rather inactive, it can easily dissociates into two oxygen atoms adsorbed to low coordinated carbon atoms at the edges of a vacancy. For these oxygen atoms the oxidation barrier is reduced and hence the protection from oxidation provided by graphene coatings is weakened. Our predictions obtained from the state of the art first-principles calculations of electronic structure, phonon density of states and reaction path will unravel how a graphene can be used as a corrosion resistant coating and guide further studies aiming at developing more efficient nanocoating materials.

  15. EDITORIAL: Special issue on Graphene Special issue on Graphene

    NASA Astrophysics Data System (ADS)

    Morpurgo, Alberto F.; Trauzettel, Björn

    2010-03-01

    Since the revolutionary experimental discovery of graphene in the year 2004, research on this new two-dimensional carbon allotrope has progressed at a spectacular pace. The impact of graphene on different areas of research— including physics, chemistry, and applied sciences— is only now starting to be fully appreciated. There are different factors that make graphene a truly impressive system. Regarding nano-electronics and related fields, for instance, it is the exceptional electronic and mechanical properties that yield very high room-temperature mobility values, due to the particular band structure, the material `cleanliness' (very low-concentration of impurities), as well as its stiffness. Also interesting is the possibility to have a high electrical conductivity and optical transparency, a combination which cannot be easily found in other material systems. For other fields, other properties could be mentioned, many of which are currently being explored. In the first years following this discovery, research on graphene has mainly focused on the fundamental physics aspects, triggered by the fact that electrons in graphene behave as Dirac fermions due to their interaction with the ions of the honeycomb lattice. This direction has led to the discovery of new phenomena such as Klein tunneling in a solid state system and the so-called half-integer quantum Hall effect due to a special type of Berry phase that appears in graphene. It has also led to the appreciation of thicker layers of graphene, which also have outstanding new properties of great interest in their own right (e.g., bilayer graphene, which supports chiral quasiparticles that, contrary to Dirac electrons, are not massless). Now the time is coming to deepen our knowledge and improve our control of the material properties, which is a key aspect to take one step further towards applications. The articles in the Semiconductor Science and Technology Graphene special issue deal with a diversity of topics

  16. Quasi-Freestanding multilayer graphene films on the carbon face of SiC

    SciTech Connect

    Siegel, D. A.; Hwang, C. G.; Fedorov, A. V.; Lanzara, A.

    2010-06-30

    The electronic band structure of as-grown and doped graphene grown on the carbon face of SiC is studied by high-resolution angle-resolved photoemission spectroscopy, where we observe both rotations between adjacent layers and AB-stacking. The band structure of quasi-freestanding AB-bilayers is directly compared with bilayer graphene grown on the Si-face of SiC to study the impact of the substrate on the electronic properties of epitaxial graphene. Our results show that the C-face films are nearly freestanding from an electronic point of view, due to the rotations between graphene layers.

  17. THz detection in graphene nanotransistors

    NASA Astrophysics Data System (ADS)

    Tredicucci, Alessandro; Vitiello, Miriam S.; Polini, Marco; Pellegrini, Vittorio

    2014-03-01

    Nanotransistors offer great prospect for the development of innovative THz detectors based on the non-linearity of transport characteristics. Semiconductor nanowires are appealing for their one-dimensional nature and intrinsically low capacitance of the devices, while graphene, with its record-high room-temperature mobility, has the potential to exploit plasma wave resonances in the transistor channel to achieve high-responsivity and tuneable detection. First graphene detectors have been recently demonstrated in both monolayer and bilayer field effect devices performances already suitable for first imaging application. Here will discuss the physics and technology of these devices, their operation, as well as first examples of imaging applications.

  18. Hybridized Graphene Materials

    NASA Astrophysics Data System (ADS)

    Robinson, Jeremy

    2015-03-01

    Graphene's high-quality structure and properties continue to motivate intensive research to mold it into the electronic material of the future. Analogous to other electronic materials, however, defects are a tool to engineer graphene's properties and tune its response to various stimuli. In this talk I discuss our efforts to engineer and manipulate defects in hybrid graphene materials for applications ranging from sensing to nanomechanical structures. First, I will present our results using chemically modified graphene to not only improve chemical sensing, but also achieve new functionality for electronic systems. In particular, we hybridize graphene via the addition of fluorine atoms and show the subsequent formation of nanoribbons and tunnel barriers exploiting property changes from the fluorine adsorbates. Second, I will present results on the electronic hybridization of stacked graphene layers, where the moiré pattern formed by the relative twist between layers is responsible for new properties of the bilayer system. Defects specific to this system include rotational disorder, strain, and chemical doping. These defects modify, but do not destroy the strong interlayer coupling. Finally, I will present results on the influence of chemistry and defects on the properties of graphene nanomechanical systems. By measuring the response of high-quality nanomehcanical resonators, we can extract relevant mechanical properties including tension, yield strength, resilience, and modulus as a function of defect introduction. This work is carried out in collaboration with M. Zalalutdinov, P.E. Sheehan, W.-K. Lee, T. Reinecke, S.W. Schmucker, J.C. Culbertson, and A.L. Friedman at Naval Research Laboratory, and T. Ohta, T.E. Beechem and B. Diaconescu at Sandia National Laboratories.

  19. Graphene: from functionalization to devices

    NASA Astrophysics Data System (ADS)

    Tejeda, Antonio; Soukiassian, Patrick G.

    2014-03-01

    The year 2014 marks the first decade of the rise of graphene. Graphene, a single atomic layer of carbon atoms in sp2 bonding configuration having a honeycomb structure, has now become a well-known and well-established material. Among some of its many outstanding fundamental properties, one can mention a very high carrier mobility, a very large spin diffusion length, unsurpassed mechanical properties as graphene is the strongest material ever measured and an exceptional thermal conductivity scaling more than one order of magnitude above that of copper. After the first years of the graphene rush, graphene growth is now well controlled using various methods like epitaxial growth on silicon carbide substrate, chemical vapour deposition (CVD) or plasma techniques on metal, insulator or semiconductor substrates. More applied research is now taking over the initial studies on graphene production. Indeed, graphene is a promising material for many advanced applications such as, but not limited to, electronic, spintronics, sensors, photonics, micro/nano-electromechanical (MEMS/NEMS) systems, super-capacitors or touch-screen technologies. In this context, this Special Issue of the Journal of Physics D: Applied Physics on graphene reviews some of the recent achievements, progress and prospects in this field. It includes a collection of seventeen invited articles covering the current status and future prospects of some selected topics of strong current interest. This Special Issue is organized in four sections. The first section is dedicated to graphene devices, and opens with an article by de Heer et al on an investigation of integrating graphene devices with silicon complementary metal-oxide-semiconductor (CMOS) technology. Then, a study by Svintsov et al proposes a lateral all-graphene tunnel field-effect transistor (FET) with a high on/off current switching ratio. Next, Tsukagoshi et al present how a band-gap opening occurs in a graphene bilayer by using a perpendicular

  20. Strain-Induced Energy Band Gap Opening in Two-Dimensional Bilayered Silicon Film

    NASA Astrophysics Data System (ADS)

    Ji, Z.; Zhou, R.; Lew Yan Voon, L. C.; Zhuang, Y.

    2016-06-01

    This work presents a theoretical study of the structural and electronic properties of bilayered silicon film (BiSF) under in-plane biaxial strain/stress using density functional theory (DFT). Atomic structures of the two-dimensional (2-D) silicon films are optimized by using both the local-density approximation (LDA) and generalized gradient approximation (GGA). In the absence of strain/stress, five buckled hexagonal honeycomb structures of the BiSF with triangular lattice have been obtained as local energy minima, and their structural stability has been verified. These structures present a Dirac-cone shaped energy band diagram with zero energy band gaps. Applying a tensile biaxial strain leads to a reduction of the buckling height. Atomically flat structures with zero buckling height have been observed when the AA-stacking structures are under a critical biaxial strain. Increase of the strain between 10.7% and 15.4% results in a band-gap opening with a maximum energy band gap opening of ˜0.17 eV, obtained when a 14.3% strain is applied. Energy band diagrams, electron transmission efficiency, and the charge transport property are calculated. Additionally, an asymmetric energetically favorable atomic structure of BiSF shows a non-zero band gap in the absence of strain/stress and a maximum band gap of 0.15 eV as a -1.71% compressive strain is applied. Both tensile and compressive strain/stress can lead to a band gap opening in the asymmetric structure.

  1. Immobilized lipid-bilayer materials

    DOEpatents

    Sasaki, Darryl Y.; Loy, Douglas A.; Yamanaka, Stacey A.

    2000-01-01

    A method for preparing encapsulated lipid-bilayer materials in a silica matrix comprising preparing a silica sol, mixing a lipid-bilayer material in the silica sol and allowing the mixture to gel to form the encapsulated lipid-bilayer material. The mild processing conditions allow quantitative entrapment of pre-formed lipid-bilayer materials without modification to the material's spectral characteristics. The method allows for the immobilization of lipid membranes to surfaces. The encapsulated lipid-bilayer materials perform as sensitive optical sensors for the detection of analytes such as heavy metal ions and can be used as drug delivery systems and as separation devices.

  2. Inelastic vertical tunneling in graphene-based heterostructures

    NASA Astrophysics Data System (ADS)

    de La Barrera, Sergio; Feenstra, Randall

    2015-03-01

    Lateral momentum conservation of tunneling states in graphene / hexagonal boron nitride / graphene heterostructures causes intriguing resonant behavior and negative differential resistance. We explain this phenomenon in terms of a simple model which includes electrostatic gating, rotational alignment between graphene layers, elastic scattering, and inelastic tunneling effects for both monolayer and bilayer graphene. We highlight recent experimental efforts to observe these effects in fabricated devices and compare with theory to validate our theoretical model. In order to improve future fabrication, we discuss disorder mechanisms, the differences between monolayer and bilayer graphene configurations, and the critical parameters which govern the characteristics of these devices. This work was supported in part by the Center for Low Energy Systems Technology (LEAST), one of the six SRC STARnet Centers, sponsored by MARCO and DARPA.

  3. The optical conductivity in double and three layer graphene systems

    NASA Astrophysics Data System (ADS)

    Yang, C. H.; Chen, Y. Y.; Jiang, J. J.; Ao, Z. M.

    2016-02-01

    We investigate the longitudinal optical conductivity in few-layer monolayer graphene systems, which is different from the bilayer or trilayer graphene structures analytically and numerically. Here, few isolated parallel two-dimensional (2D) monolayer graphene are separated by a distance d with no interlayer tunneling, where the finite width thickness has to be taken into account. The carrier's energy structure and states for each layer are unaffected by the others. The carrier density in each layer is assumed to be tuned by the corresponding gate voltage. The optical conductivity depends on the electron density, the number of layer, and the broadening width at low temperature. However, analytical and numerical results show that the optical conductivity has little dependence on the distance between the adjacent layers. It is found that two intra- and inter-band transition channels for optical transition via absorption scattering in each layer can be observed. When the optical energy is larger than two times the kinetic energy at the Fermi energy, the optical conductivity is proportional to the layer numbers of monolayer graphene that can determine the number of the monolayer graphene layer. In sharp contrast to the bilayer or trilayer graphene systems, several turning points can be observed. Increasing the broadening width, the turning area becomes gradual. The main difference on the optical conductivity for double layer graphene and bilayer graphene is in the intermediate energy region where the threshold structure is observed.

  4. Electronic structure and optical properties of graphene/stanene heterobilayer.

    PubMed

    Chen, Xianping; Meng, Ruishen; Jiang, Junke; Liang, Qiuhua; Yang, Qun; Tan, Chunjian; Sun, Xiang; Zhang, Shengli; Ren, Tianling

    2016-06-28

    The structural, electronic and optical properties of the graphene hybrid with stanene, the tin counterpart of graphene, are investigated by means of density functional calculation with the observation of band gap opening and enhanced visible light response. The lattice mismatch between graphene and stanene is taken into consideration and several stacking methods for model construction are proposed to study the possible effects. The Dirac feature can be observed in this bilayer system with relatively stronger interlayer interaction than weak van der Waals forces, which is ascribed to the unsaturated p orbital of stanene. Despite the mutual semi-metal nature of graphene and stanene, it is significant to note a band gap opening and the electrical neutrality of the bilayer. The combination of high carrier mobility of graphene and the excellent spin Hall effect of stanene is expected to coexist in the bilayer structure. In addition, we found that the stanene monolayer has a relatively lower work function than graphene and more importantly, it exhibits more pronounced optical absorption than graphene. The results indicate that a graphene/stanene heterobilayer will facilitate the performance of stanene related spintronic devices and is therefore a good candidate for photoelectronic devices. PMID:27253913

  5. Two-dimensional layered semiconductor/graphene heterostructures for solar photovoltaic applications

    NASA Astrophysics Data System (ADS)

    Shanmugam, Mariyappan; Jacobs-Gedrim, Robin; Song, Eui Sang; Yu, Bin

    2014-10-01

    Schottky barriers formed by graphene (monolayer, bilayer, and multilayer) on 2D layered semiconductor tungsten disulfide (WS2) nanosheets are explored for solar energy harvesting. The characteristics of the graphene-WS2 Schottky junction vary significantly with the number of graphene layers on WS2, resulting in differences in solar cell performance. Compared with monolayer or stacked bilayer graphene, multilayer graphene helps in achieving improved solar cell performance due to superior electrical conductivity. The all-layered-material Schottky barrier solar cell employing WS2 as a photoactive semiconductor exhibits efficient photon absorption in the visible spectral range, yielding 3.3% photoelectric conversion efficiency with multilayer graphene as the Schottky contact. Carrier transport at the graphene/WS2 interface and the interfacial recombination process in the Schottky barrier solar cells are examined.

  6. Two-dimensional layered semiconductor/graphene heterostructures for solar photovoltaic applications.

    PubMed

    Shanmugam, Mariyappan; Jacobs-Gedrim, Robin; Song, Eui Sang; Yu, Bin

    2014-11-01

    Schottky barriers formed by graphene (monolayer, bilayer, and multilayer) on 2D layered semiconductor tungsten disulfide (WS2) nanosheets are explored for solar energy harvesting. The characteristics of the graphene-WS2 Schottky junction vary significantly with the number of graphene layers on WS2, resulting in differences in solar cell performance. Compared with monolayer or stacked bilayer graphene, multilayer graphene helps in achieving improved solar cell performance due to superior electrical conductivity. The all-layered-material Schottky barrier solar cell employing WS2 as a photoactive semiconductor exhibits efficient photon absorption in the visible spectral range, yielding 3.3% photoelectric conversion efficiency with multilayer graphene as the Schottky contact. Carrier transport at the graphene/WS2 interface and the interfacial recombination process in the Schottky barrier solar cells are examined. PMID:25210837

  7. Spin caloritronics in graphene

    SciTech Connect

    Ghosh, Angsula; Frota, H. O.

    2015-06-14

    Spin caloritronics, the combination of spintronics with thermoelectrics, exploiting both the intrinsic spin of the electron and its associated magnetic moment in addition to its fundamental electronic charge and temperature, is an emerging technology mainly in the development of low-power-consumption technology. In this work, we study the thermoelectric properties of a Rashba dot attached to two single layer/bilayer graphene sheets as leads. The temperature difference on the two graphene leads induces a spin current, which depends on the temperature and chemical potential. We demonstrate that the Rashba dot behaves as a spin filter for selected values of the chemical potential and is able to filter electrons by their spin orientation. The spin thermopower has also been studied where the effects of the chemical potential, temperature, and also the Rashba term have been observed.

  8. Cyclotron resonance in graphene

    NASA Astrophysics Data System (ADS)

    Henriksen, Erik Alfred

    We present a study of cyclotron resonance in graphene. Graphene is a novel two-dimensional system consisting of a single sheet of atoms arranged in a honeycomb lattice, and exhibits a unique, linear low-energy dispersion. Bilayer graphene, two sheets stacked together, is an equally interesting system displaying a second unique, but hyperbolic, dispersion. In this work, we study the quantized Landau levels of these systems in strong magnetic fields, via Fourier-transform infrared spectroscopy. We have fabricated large area single layer and bilayer graphene devices on infrared-transparent Si/SiO2 substrates, using standard electron beam lithography and thin-film liftoff techniques. At cryogenic temperatures and high magnetic fields, we measure the infrared transmission through these devices as a function of the back gate voltage, which changes the Fermi level and hence the carrier density. We analyze the normalized transmission traces, assigning the observed minima to the cyclotron resonance wherein carriers are excited between Landau levels. In single layer graphene, we study Landau level transitions near the charge neutral Dirac point, and find a set of particle-hole symmetric transitions, both within the conduction and valence band, and between the bands. These experiments confirm the unusual B- and n -dependencies of the LL energies, where B is the magnetic field and n the LL index. The CR selection rule is determined to be Delta n = |nfinal| -- |n initial| = +/-1. The ratio of the observed interband and intraband transitions exceeds the expected value by 5%, and this excess is interpreted as an additional contribution to the transition energy from many-particle effects. We explore several higher LL transitions for both electron and hole doping of single layer graphene. The data are consistent with a renormalization of the carrier band velocity near the Dirac point, and suggest that impurity scattering strengthens at low energies. We also study the CR at the

  9. Characterizing Edge and Stacking Structures of Exfoliated Graphene by Photoelectron Diffraction

    NASA Astrophysics Data System (ADS)

    Matsui, Fumihiko; Ishii, Ryo; Matsuda, Hiroyuki; Morita, Makoto; Kitagawa, Satoshi; Matsushita, Tomohiro; Koh, Shinji; Daimon, Hiroshi

    2013-11-01

    The two-dimensional C 1s photoelectron intensity angular distributions (PIADs) and spectra of exfoliated graphene flakes and crystalline graphite were measured using a focused soft X-ray beam. Suitable graphene samples were selected by thickness characterization using Raman spectromicroscopy after transferring mechanically exfoliated graphene flakes onto a 90-nm-thick SiO2 film. In every PIAD, a Kagomé interference pattern was observed, particularly clearly in the monolayer graphene PIAD. Its origin is the overlap of the diffraction rings formed by an in-plane C-C bond honeycomb lattice. Thus, the crystal orientation of each sample can be determined. In the case of bilayer graphene, PIAD was threefold-symmetric, while those of monolayer graphene and crystalline graphite were sixfold-symmetric. This is due to the stacking structure of bilayer graphene. From comparisons with the multiple scattering PIAD simulation results, the way of layer stacking as well as the termination types in the edge regions of bilayer graphene flakes were determined. Furthermore, two different C 1s core levels corresponding to the top and bottom layers of bilayer graphene were identified. A chemical shift to a higher binding energy by 0.25 eV for the bottom layer was attributed to interfacial interactions.

  10. Spin-dependent Klein tunneling in graphene: Role of Rashba spin-orbit coupling

    NASA Astrophysics Data System (ADS)

    Liu, Ming-Hao; Bundesmann, Jan; Richter, Klaus

    2012-02-01

    Within an effective Dirac theory the low-energy dispersions of monolayer graphene in the presence of Rashba spin-orbit coupling and spin-degenerate bilayer graphene are described by formally identical expressions. We explore implications of this correspondence for transport by choosing chiral tunneling through pn and pnpjunctions as a concrete example. A real-space Green's function formalism based on a tight-binding model is adopted to perform the ballistic transport calculations, which cover and confirm previous theoretical results based on the Dirac theory. Chiral tunneling in monolayer graphene in the presence of Rashba coupling is shown to indeed behave like in bilayer graphene. Combined effects of a forbidden normal transmission and spin separation are observed within the single-band n↔p transmission regime. The former comes from real-spin conservation, in analogy with pseudospin conservation in bilayer graphene, while the latter arises from the intrinsic spin-Hall mechanism of the Rashba coupling.

  11. Graphene-metal interfaces for biosensors devices

    NASA Astrophysics Data System (ADS)

    Zuppella, Paola; Gerlin, Francesca; Bacco, Davide; Corso, Alain J.; Tessarolo, Enrico; Nardello, Marco; Silvestrini, Simone; Maggini, Michele; Pelizzo, Maria G.

    2015-08-01

    Graphene-metals interfaces are investigated in many subject areas both applicative and speculative. The interest mainly stems from the possibility for CVD synthesis of large area graphene on metals. In this case the metal acts as a catalyst for complete dehydrogenetaion of hydrocarbon precursors that leaves carbon behind at the surface. Such bilayer are also very appealing for surface plasmon resonance devices, since graphene acts both as a protective layer and biorecognition element. Several pairs of graphene-metal interfaces have been studied in terms of SPR performance and physicalchemical properties at the interface. With regard to this last aspect, NEXAFS spectroscopy is a powerful method to study single-, double-, and few- layers graphene and to illustrate any evolution of the electronic states.

  12. Edge states of zigzag bilayer graphite nanoribbons

    NASA Astrophysics Data System (ADS)

    Rhim, Jun-Won; Moon, Kyungsun

    2008-09-01

    The electronic structures of zigzag bilayer graphite nanoribbons (Z-BGNRs) with various ribbon widths N are studied within the tight binding approximation. Neglecting the inter-layer hopping amplitude γ4, which is an order of magnitude smaller than the other inter-layer hopping parameters, there exist two fixed Fermi points ± k* independent of the ribbon width with a peculiar energy dispersion near k* as ɛ(k)~ ± (k-k*)N. By investigating the edge states of Z-BGNRs, we notice that the trigonal warping of the bilayer graphene sheets is reflected in the edge state structure. With the inclusion of γ4, the above two Fermi points are not fixed but drift toward the vicinity of the Dirac point with increasing width N, as shown by the finite scaling method, and the peculiar dispersions change to parabolic ones. The edge magnetism of Z-BGNRs is also examined by solving the half-filled Hubbard Hamiltonian for the ribbon using the Hartree-Fock approximation. We have shown that within the same side of the edges, the edge spins are aligned ferromagnetically for the experimentally relevant set of parameters.

  13. Phase Coherent Charge Transport in Graphene Quantum Billiards

    NASA Astrophysics Data System (ADS)

    Lau, Chun Ning

    2008-03-01

    As an emergent model system for condensed matter physics and a promising electronic material, graphene's electrical transport properties has become a subject of intense focus. Via low temperature transport spectroscopy on single and bi-layer graphene devices, we show that the minimum conductivity value is geometry dependent and approaches the theoretical value of 4e^2/πh only for wide and short graphene strips. Moreover, we observe periodic conductance oscillations with bias and gate voltages, arising from quantum interference of multiply-reflected waves of charges in graphene. When graphene is coupled to superconducting electrodes, we observe gate tunable supercurrent and sub-gap structures, which originate from multiple Andreev reflection at the graphene-superconductor interfaces. Our results demonstrate that graphene can act as a quantum billiard with a long phase coherence length. This work was supported in part by DOD/DMEA-H94003-06-2-0608.

  14. Graphene synthesis and characterization on copper

    NASA Astrophysics Data System (ADS)

    Mohsin, Ali

    Graphene, two dimensional sheet of carbon atoms has recently gained attention as some of its properties are promising for electronics applications e.g. higher mobility that translates to higher operating frequency for devices geared towards radio frequency applications. Excellent optical transmittance combined with its semi metallic behavior makes it an important material for transparent contacts in solar cells. To bring graphene to the production level, synthesis methods are needed for its growth on wafer scale. It has been shown that chemical vapor deposition (CVD) is one of the techniques that can potentially synthesize wafer scale graphene. Recently copper has gained popularity as an important substrate material for graphene growth due to its lower carbon solubility, which allows better control over number of graphene layers. Here we report optimization of graphene growth on copper foils with our home made atmospheric pressure chemical vapor deposition (APCVD) setup. Graphene growth on copper under APCVD was non self-limiting similar to other reports. It was found that apart from growth parameters surface texture plays a very important role in graphene growth. In fact, few layer and bilayer graphene were obtained on the regions where copper surface was not uniform, confirmed by Raman spectroscopy. To improve copper surface texture thin layer of copper film was evaporated by electron beam evaporation before the graphene growth process. After this modification, monolayer graphene was obtained on areas as large as 300 microm x 300 microm confirmed by Raman area maps. Graphene transfer procedure was also optimized so that graphene on metal surface could be transferred to insulating substrate.

  15. Semiconducting Graphene on Silicon from First-Principles Calculations.

    PubMed

    Dang, Xuejie; Dong, Huilong; Wang, Lu; Zhao, Yanfei; Guo, Zhenyu; Hou, Tingjun; Li, Youyong; Lee, Shuit-Tong

    2015-08-25

    Graphene is a semimetal with zero band gap, which makes it impossible to turn electric conduction off below a certain limit. Transformation of graphene into a semiconductor has attracted wide attention. Owing to compatibility with Si technology, graphene adsorbed on a Si substrate is particularly attractive for future applications. However, to date there is little theoretical work on band gap engineering in graphene and its integration with Si technology. Employing first-principles calculations, we study the electronic properties of monolayer and bilayer graphene adsorbed on clean and hydrogen (H)-passivated Si (111)/Si (100) surfaces. Our calculation shows that the interaction between monolayer graphene and a H-passivated Si surface is weak, with the band gap remaining negligible. For bilayer graphene adsorbed onto a H-passivated Si surface, the band gap opens up to 108 meV owing to asymmetry introduction. In contrast, the interaction between graphene and a clean Si surface is strong, leading to formation of chemical bonds and a large band gap of 272 meV. Our results provide guidance for device designs based on integrating graphene with Si technology. PMID:26213346

  16. Role of substrate induced electron–phonon interactions in biased graphitic bilayers

    NASA Astrophysics Data System (ADS)

    Davenport, A. R.; Hague, J. P.

    2016-08-01

    Bilayers of graphitic materials have potential applications in field effect transistors (FETs). A potential difference applied between certain ionic bilayers made from insulating graphitic materials such as BN, ZnO and AlN could reduce gap sizes, turning them into useful semiconductors. On the other hand, opening of a small semiconducting gap occurs in graphene bilayers under applied field. The aim here is to investigate to what extent substrate induced electron–phonon interactions (EPIs) modify this gap change. We examine EPIs in several lattice configurations of graphitic bilayers, using a perturbative approach. The typical effect of EPIs on the ionic bilayers is an undesirable gap widening. The size of this gap change varies considerably with lattice structure and the magnitude of the bias. When bias is larger than the non-interacting gap size, EPIs have the smallest effect on the bandgap, especially in configurations with A{{A}\\prime} and AB structures. Thus careful selection of substrate, lattice configuration and bias strength to minimise the effects of EPIs could be important for optimising the properties of electronic devices. We use parameters related to BN in this article. In practice, the results presented here are broadly applicable to other graphitic bilayers, and are likely to be qualitatively similar in metal dichalcogenide bilayers such as MoS2, which are already of high interest for their use in FETs.

  17. Role of substrate induced electron-phonon interactions in biased graphitic bilayers.

    PubMed

    Davenport, A R; Hague, J P

    2016-08-17

    Bilayers of graphitic materials have potential applications in field effect transistors (FETs). A potential difference applied between certain ionic bilayers made from insulating graphitic materials such as BN, ZnO and AlN could reduce gap sizes, turning them into useful semiconductors. On the other hand, opening of a small semiconducting gap occurs in graphene bilayers under applied field. The aim here is to investigate to what extent substrate induced electron-phonon interactions (EPIs) modify this gap change. We examine EPIs in several lattice configurations of graphitic bilayers, using a perturbative approach. The typical effect of EPIs on the ionic bilayers is an undesirable gap widening. The size of this gap change varies considerably with lattice structure and the magnitude of the bias. When bias is larger than the non-interacting gap size, EPIs have the smallest effect on the bandgap, especially in configurations with [Formula: see text] and AB structures. Thus careful selection of substrate, lattice configuration and bias strength to minimise the effects of EPIs could be important for optimising the properties of electronic devices. We use parameters related to BN in this article. In practice, the results presented here are broadly applicable to other graphitic bilayers, and are likely to be qualitatively similar in metal dichalcogenide bilayers such as MoS2, which are already of high interest for their use in FETs. PMID:27346288

  18. Single-crystalline monolayer and multilayer graphene nano switches

    SciTech Connect

    Li, Peng; Cui, Tianhong; Jing, Gaoshan; Zhang, Bo; Sando, Shota

    2014-03-17

    Growth of monolayer, bi-layer, and tri-layer single-crystalline graphene (SCG) using chemical vapor deposition method is reported. SCG's mechanical properties and single-crystalline nature were characterized and verified by atomic force microscope and Raman spectroscopy. Electro-mechanical switches based on mono- and bi-layer SCG were fabricated, and the superb properties of SCG enable the switches to operate at pull-in voltage as low as 1 V, and high switching speed about 100 ns. These devices exhibit lifetime without a breakdown of over 5000 cycles, far more durable than any other graphene nanoelectromechanical system switches reported.

  19. Synthesis of few layer graphene by direct exfoliation of graphite and a Raman spectroscopic study

    SciTech Connect

    Gayathri, S.; Jayabal, P.; Ramakrishnan, V.; Kottaisamy, M.

    2014-02-15

    The exfoliation of graphene from pristine graphite in a liquid phase was achieved successfully via sonication followed by centrifugation method. Ultraviolet–visible (UV–vis) spectra of the obtained graphene dispersions at different exfoliation time indicated that the concentration of graphene dispersion increased markedly with increasing exfoliation time. The sheet-like morphology of the exfoliated graphene was revealed by Scanning Electron Microscopy (SEM) image. Further, the morphological change in different exfoliation time was investigated by Atomic Force Microscopy (AFM). A complete structural and defect characterization was probed using micro-Raman spectroscopic technique. The shape and position of the 2D band of Raman spectra revealed the formation of bilayer to few layer graphene. Also, Raman mapping confirmed the presence of uniformly distributed bilayer graphene sheets on the substrate.

  20. Calculation of electron spectra and some problems in the thermodynamics of graphene layers

    NASA Astrophysics Data System (ADS)

    Alisultanov, Z. Z.

    2016-02-01

    The expressions for the energy spectra of monolayer, bilayer, and multilayer graphene, as well as epitaxial graphene, are derived using the quantum Green's functions method. Analytic expressions are obtained for the densities of states of these systems. It is shown that a bandgap can appear the spectrum of an epitaxial graphene bilayer. A number of problems in the thermodynamics of electrons in free and epitaxial graphene layers are considered as applications. Analytic expressions are obtained for the chemical potential and heat capacity in the limiting cases of low and high temperatures. Quantum oscillations of heat capacity in graphene are analyzed taking into account the Coulomb interaction. The Berry phase of epitaxial graphene is investigated.

  1. Synthesis of large-size graphene by chemical vapor deposition

    NASA Astrophysics Data System (ADS)

    Wu, Ruizhe; Ding, Yao; Gan, Lin; Luo, Zhengtang

    2015-09-01

    The requirement for long-range structure coherence and property uniformity for graphene-based electronics are crucial for their applications in electronics. Here, we briefly review our recent progress on synthesis of large-size graphene by seeded growth method. We demonstrate a seeded growth method which allows us to reduce the nucleation density in early stage of Chemical Vapor Deposition (CVD) leading to the production of low density of graphene grains and consequently achieve grain size of sub-centimeter. We further demonstrate that we can amplify the graphene grain size by limiting the second seeded growth only from the graphene seed edges. Moreover, we demonstrate that similar method can be used for the preparation of large-grain bilayer graphene flakes.

  2. Optical and Electrical Characteristics of Graphene Double Layer Formed by a Double Transfer of Graphene Single Layers.

    PubMed

    Kim, Young Jun; Bae, Gi Yoon; Chun, Sungwoo; Park, Wanjun

    2016-03-01

    We demonstrate formation of double layer graphene by means of a double transfer using two single graphene layers grown by a chemical vapor deposition method. It is observed that shiftiness and broadness in the double-resonance of Raman scattering are much weaker than those of bilayer graphene formed naturally. Transport characteristics examined from transmission line measurements and field effect transistors show the similar behavior with those of single layer graphene. It indicates that interlayer separation, in electrical view, is large enough to avoid correlation between layers for the double layer structure. It is also observed from a transistor with the double layer graphene that molecules adsorpted on two inner graphene surfaces in the double layered structure are isolated and conserved from ambient environment. PMID:27455706

  3. Review of bilayer tablet technology.

    PubMed

    Abebe, Admassu; Akseli, Ilgaz; Sprockel, Omar; Kottala, Niranjan; Cuitiño, Alberto M

    2014-01-30

    Therapeutic strategies based on oral delivery of bilayer (and multilayer) tablets are gaining more acceptance among brand and generic products due to a confluence of factors including advanced delivery strategies, patient compliance and combination therapy. Successful manufacturing of these ever more complex systems needs to overcome a series of challenges from formulation design to tablet press monitoring and control. This article provides an overview of the state-of-the-art of bilayer tablet technology, highlighting the main benefits of this type of oral dosage forms while providing a description of current challenges and advances toward improving manufacturing practices and product quality. Several aspects relevant to bilayer tablet manufacturing are addressed including material properties, lubrication, layer ordering, layer thickness, layer weight control, as well as first and final compression forces. A section is also devoted to bilayer tablet characterization that present additional complexities associated with interfaces between layers. The available features of the manufacturing equipment for bilayer tablet production are also described indicating the different strategies for sensing and controls offered by bilayer tablet press manufacturers. Finally, a roadmap for bilayer tablet manufacturing is advanced as a guideline to formulation design and selection of process parameters and equipment. PMID:24370841

  4. Lipid bilayers on nano-templates

    DOEpatents

    Noy, Aleksandr; Artyukhin, Alexander B.; Bakajin, Olgica; Stoeve, Pieter

    2009-08-04

    A lipid bilayer on a nano-template comprising a nanotube or nanowire and a lipid bilayer around the nanotube or nanowire. One embodiment provides a method of fabricating a lipid bilayer on a nano-template comprising the steps of providing a nanotube or nanowire and forming a lipid bilayer around the polymer cushion. One embodiment provides a protein pore in the lipid bilayer. In one embodiment the protein pore is sensitive to specific agents

  5. Hysteresis modeling in graphene field effect transistors

    SciTech Connect

    Winters, M.; Rorsman, N.; Sveinbjörnsson, E. Ö.

    2015-02-21

    Graphene field effect transistors with an Al{sub 2}O{sub 3} gate dielectric are fabricated on H-intercalated bilayer graphene grown on semi-insulating 4H-SiC by chemical vapour deposition. DC measurements of the gate voltage v{sub g} versus the drain current i{sub d} reveal a severe hysteresis of clockwise orientation. A capacitive model is used to derive the relationship between the applied gate voltage and the Fermi energy. The electron transport equations are then used to calculate the drain current for a given applied gate voltage. The hysteresis in measured data is then modeled via a modified Preisach kernel.

  6. Graphene aerogels

    DOEpatents

    Pauzauskie, Peter J; Worsley, Marcus A; Baumann, Theodore F; Satcher, Jr., Joe H; Biener, Juergen

    2015-03-31

    Graphene aerogels with high conductivity and surface areas including a method for making a graphene aerogel, including the following steps: (1) preparing a reaction mixture comprising a graphene oxide suspension and at least one catalyst; (2) curing the reaction mixture to produce a wet gel; (3) drying the wet gel to produce a dry gel; and (4) pyrolyzing the dry gel to produce a graphene aerogel. Applications include electrical energy storage including batteries and supercapacitors.

  7. Cholesterol's location in lipid bilayers

    DOE PAGESBeta

    Marquardt, Drew; Kučerka, Norbert; Wassall, Stephen R.; Harroun, Thad A.; Katsaras, John

    2016-04-04

    It is well known that cholesterol modifies the physical properties of lipid bilayers. For example, the much studied liquid-ordered Lo phase contains rapidly diffusing lipids with their acyl chains in the all trans configuration, similar to gel phase bilayers. Moreover, the Lo phase is commonly associated with cholesterol-enriched lipid rafts, which are thought to serve as platforms for signaling proteins in the plasma membrane. Cholesterol's location in lipid bilayers has been studied extensively, and it has been shown – at least in some bilayers – to align differently from its canonical upright orientation, where its hydroxyl group is in themore » vicinity of the lipid–water interface. In this study we review recent works describing cholesterol's location in different model membrane systems with emphasis on results obtained from scattering, spectroscopic and molecular dynamics studies.« less

  8. Cholesterol's location in lipid bilayers.

    PubMed

    Marquardt, Drew; Kučerka, Norbert; Wassall, Stephen R; Harroun, Thad A; Katsaras, John

    2016-09-01

    It is well known that cholesterol modifies the physical properties of lipid bilayers. For example, the much studied liquid-ordered Lo phase contains rapidly diffusing lipids with their acyl chains in the all trans configuration, similar to gel phase bilayers. Moreover, the Lo phase is commonly associated with cholesterol-enriched lipid rafts, which are thought to serve as platforms for signaling proteins in the plasma membrane. Cholesterol's location in lipid bilayers has been studied extensively, and it has been shown - at least in some bilayers - to align differently from its canonical upright orientation, where its hydroxyl group is in the vicinity of the lipid-water interface. In this article we review recent works describing cholesterol's location in different model membrane systems with emphasis on results obtained from scattering, spectroscopic and molecular dynamics studies. PMID:27056099

  9. Enhancing the thermoelectric figure of merit in engineered graphene nanoribbons

    PubMed Central

    Sangtarash, Sara; Lambert, Colin J

    2015-01-01

    Summary We demonstrate that thermoelectric properties of graphene nanoribbons can be dramatically improved by introducing nanopores. In monolayer graphene, this increases the electronic thermoelectric figure of merit ZT e from 0.01 to 0.5. The largest values of ZT e are found when a nanopore is introduced into bilayer graphene, such that the current flows from one layer to the other via the inner surface of the pore, for which values as high as ZT e = 2.45 are obtained. All thermoelectric properties can be further enhanced by tuning the Fermi energy of the leads. PMID:26171293

  10. Enhancing the thermoelectric figure of merit in engineered graphene nanoribbons.

    PubMed

    Sadeghi, Hatef; Sangtarash, Sara; Lambert, Colin J

    2015-01-01

    We demonstrate that thermoelectric properties of graphene nanoribbons can be dramatically improved by introducing nanopores. In monolayer graphene, this increases the electronic thermoelectric figure of merit ZT e from 0.01 to 0.5. The largest values of ZT e are found when a nanopore is introduced into bilayer graphene, such that the current flows from one layer to the other via the inner surface of the pore, for which values as high as ZT e = 2.45 are obtained. All thermoelectric properties can be further enhanced by tuning the Fermi energy of the leads. PMID:26171293

  11. Self-consistent perturbation theory for two dimensional twisted bilayers

    NASA Astrophysics Data System (ADS)

    Shirodkar, Sharmila N.; Tritsaris, Georgios A.; Kaxiras, Efthimios

    Theoretical modeling and ab-initio simulations of two dimensional heterostructures with arbitrary angles of rotation between layers involve unrealistically large and expensive calculations. To overcome this shortcoming, we develop a methodology for weakly interacting heterostructures that treats the effect of one layer on the other as perturbation, and restricts the calculations to their primitive cells. Thus, avoiding computationally expensive supercells. We start by approximating the interaction potential between the twisted bilayers to that of a hypothetical configuration (viz. ideally stacked untwisted layers), which produces band structures in reasonable agreement with full-scale ab-initio calculations for commensurate and twisted bilayers of graphene (Gr) and Gr/hexagonal boron nitride (h-BN) heterostructures. We then self-consistently calculate the charge density and hence, interaction potential of the heterostructures. In this work, we test our model for bilayers of various combinations of Gr, h-BN and transition metal dichalcogenides, and discuss the advantages and shortcomings of the self-consistently calculated interaction potential. Department of Physics, Harvard University, Cambridge, Massachusetts 02138, USA.

  12. Graphene-multilayer graphene nanocomposites as highly efficient thermal interface materials.

    PubMed

    Shahil, Khan M F; Balandin, Alexander A

    2012-02-01

    We found that the optimized mixture of graphene and multilayer graphene, produced by the high-yield inexpensive liquid-phase-exfoliation technique, can lead to an extremely strong enhancement of the cross-plane thermal conductivity K of the composite. The "laser flash" measurements revealed a record-high enhancement of K by 2300% in the graphene-based polymer at the filler loading fraction f = 10 vol %. It was determined that the relatively high concentration of the single-layer and bilayer graphene flakes (~10-15%) present simultaneously with the thicker multilayers of large lateral size (~1 μm) were essential for the observed unusual K enhancement. The thermal conductivity of the commercial thermal grease was increased from an initial value of ~5.8 W/mK to K = 14 W/mK at the small loading f = 2%, which preserved all mechanical properties of the hybrid. Our modeling results suggest that graphene-multilayer graphene nanocomposite used as the thermal interface material outperforms those with carbon nanotubes or metal nanoparticles owing to graphene's aspect ratio and lower Kapitza resistance at the graphene-matrix interface. PMID:22214526

  13. Large-scale fabrication of BN tunnel barriers for graphene spintronics

    SciTech Connect

    Fu, Wangyang; Makk, Péter; Maurand, Romain; Bräuninger, Matthias; Schönenberger, Christian

    2014-08-21

    We have fabricated graphene spin-valve devices utilizing scalable materials made from chemical vapor deposition (CVD). Both the spin-transporting graphene and the tunnel barrier material are CVD-grown. The tunnel barrier is realized by Hexagonal boron nitride, used either as a monolayer or bilayer and placed over the graphene. Spin transport experiments were performed using ferromagnetic contacts deposited onto the barrier. We find that spin injection is still greatly suppressed in devices with a monolayer tunneling barrier due to resistance mismatch. This is, however, not the case for devices with bilayer barriers. For those devices, a spin relaxation time of ∼260 ps intrinsic to the CVD graphene material is deduced. This time scale is comparable to those reported for exfoliated graphene, suggesting that this CVD approach is promising for spintronic applications which require scalable materials.

  14. Growth of CdTe thin films on graphene by close-spaced sublimation method

    SciTech Connect

    Jung, Younghun; Yang, Gwangseok; Kim, Jihyun; Chun, Seungju; Kim, Donghwan

    2013-12-02

    CdTe thin films grown on bi-layer graphene were demonstrated by using the close-spaced sublimation method, where CdTe was selectively grown on the graphene. The density of the CdTe domains was increased with increasing the number of the defective sites in the graphene, which was controlled by the duration of UV exposure. The CdTe growth rate on the bi-layer graphene electrodes was 400 nm/min with a bandgap energy of 1.45–1.49 eV. Scanning electron microscopy, micro-Raman spectroscopy, micro-photoluminescence, and X-ray diffraction technique were used to confirm the high quality of the CdTe thin films grown on the graphene electrodes.

  15. PREFACE: Graphene Graphene

    NASA Astrophysics Data System (ADS)

    Singleton, John; Ferry, David K.

    2009-08-01

    As is now well known, graphene was made in 2004 by the 'simple' expedient of cleaving a single atomic layer from a sample of graphite using a piece of sticky tape [1, 2]. This discovery stimulated a whirlwind of activity; at last, predictions about the unique behaviour of band electrons in a two-dimensional honeycomb lattice made as early as the 1940s could be verified experimentally [1, 2]. Perhaps the most influential result has been the confirmation that the charge carriers in graphene behave in many ways as 'Dirac fermions', mimicing the dynamics of hyper-relativistic electrons, but with 1/300th of the velocity. Another important pairing of prediction and result has been the observation of carrier mobilities that have an unusual (in)dependence on impurity concentration, suggesting applications in high-speed ballistic transistors and even the eventual part replacement of silicon by graphene as the devices on chips become ever smaller [1, 2]. As a result of the considerable and rapid activity in this field, reviews of the properties of graphene have appeared; a good introduction to the early work at a level appropriate to students is given in [1], whilst [2] covers more recent progress at a more advanced level. However, the field is progressing so rapidly that even good reviews become dated by the time they appear in print, and new work and studies are appearing daily. In this issue, we have tried to pull together a group of papers which examine some of these new areas of work in graphene; these range from low-temperature physics to high electric field transport at room temperature [3]. Given the postulated future use of graphene in ultra-small devices, it is no surprise that quantum dots and wires feature heavily in the articles by Peres et al [4], Huang et al [5] and Sun and Xie [6]. Moreover, applications will inevitably involve graphene in contact with other materials and chemical systems, resulting in modifications to its electronic properties. For example

  16. Monolayer-to-bilayer transformation of silicenes and their structural analysis

    NASA Astrophysics Data System (ADS)

    Yaokawa, Ritsuko; Ohsuna, Tetsu; Morishita, Tetsuya; Hayasaka, Yuichiro; Spencer, Michelle J. S.; Nakano, Hideyuki

    2016-02-01

    Silicene, a two-dimensional honeycomb network of silicon atoms like graphene, holds great potential as a key material in the next generation of electronics; however, its use in more demanding applications is prevented because of its instability under ambient conditions. Here we report three types of bilayer silicenes that form after treating calcium-intercalated monolayer silicene (CaSi2) with a BF4- -based ionic liquid. The bilayer silicenes that are obtained are sandwiched between planar crystals of CaF2 and/or CaSi2, with one of the bilayer silicenes being a new allotrope of silicon, containing four-, five- and six-membered sp3 silicon rings. The number of unsaturated silicon bonds in the structure is reduced compared with monolayer silicene. Additionally, the bandgap opens to 1.08 eV and is indirect; this is in contrast to monolayer silicene which is a zero-gap semiconductor.

  17. Monolayer-to-bilayer transformation of silicenes and their structural analysis.

    PubMed

    Yaokawa, Ritsuko; Ohsuna, Tetsu; Morishita, Tetsuya; Hayasaka, Yuichiro; Spencer, Michelle J S; Nakano, Hideyuki

    2016-01-01

    Silicene, a two-dimensional honeycomb network of silicon atoms like graphene, holds great potential as a key material in the next generation of electronics; however, its use in more demanding applications is prevented because of its instability under ambient conditions. Here we report three types of bilayer silicenes that form after treating calcium-intercalated monolayer silicene (CaSi2) with a BF4(-) -based ionic liquid. The bilayer silicenes that are obtained are sandwiched between planar crystals of CaF2 and/or CaSi2, with one of the bilayer silicenes being a new allotrope of silicon, containing four-, five- and six-membered sp(3) silicon rings. The number of unsaturated silicon bonds in the structure is reduced compared with monolayer silicene. Additionally, the bandgap opens to 1.08 eV and is indirect; this is in contrast to monolayer silicene which is a zero-gap semiconductor. PMID:26847858

  18. Monolayer-to-bilayer transformation of silicenes and their structural analysis

    PubMed Central

    Yaokawa, Ritsuko; Ohsuna, Tetsu; Morishita, Tetsuya; Hayasaka, Yuichiro; Spencer, Michelle J. S.; Nakano, Hideyuki

    2016-01-01

    Silicene, a two-dimensional honeycomb network of silicon atoms like graphene, holds great potential as a key material in the next generation of electronics; however, its use in more demanding applications is prevented because of its instability under ambient conditions. Here we report three types of bilayer silicenes that form after treating calcium-intercalated monolayer silicene (CaSi2) with a BF4− -based ionic liquid. The bilayer silicenes that are obtained are sandwiched between planar crystals of CaF2 and/or CaSi2, with one of the bilayer silicenes being a new allotrope of silicon, containing four-, five- and six-membered sp3 silicon rings. The number of unsaturated silicon bonds in the structure is reduced compared with monolayer silicene. Additionally, the bandgap opens to 1.08 eV and is indirect; this is in contrast to monolayer silicene which is a zero-gap semiconductor. PMID:26847858

  19. Graphene Plasmonics

    NASA Astrophysics Data System (ADS)

    Mou, Shin; Abeysinghe, Don; Nader, Nima; Hendrickson, Joshua; Cleary, Justin; Elhamri, Said

    Plasmon, the collective free charge carrier oscillation, has been a popular research theme recently mostly associated with surface plasmon in metal nanoparticles. After the discovery of graphene, researchers soon began to study plasmonic effects with or within graphene, for instance, decorating graphene with metal nanoparticles to enhance optical processes via plasmonic field enhancement. Following that, people also gained interests in studying the intrinsic plasmon of graphene. Graphene, a tunable semimetal under field effect, demonstrates tunable plasmon resonances at room temperature, which enables new capabilities beyond those of metal-nanoparticle surface plasmons. In this project, we would like to show intrinsic graphene plasmon resonances in that we experimentally demonstrated polarization dependent and gate-bias tunable plasmon-resonance absorption in the mid-infrared regime of 5-14 um by utilizing an array of graphene nanoribbon resonators. By scaling nanoribbon width and charge densities, we probed graphene plasmons with plasmon resonance energy as high as 0.26 meV (2100 cm-1) for 40 nm wide nanoresonators. The result reveals the intriguing nature of graphene plasmon in graphene nanoribbons where the nanoribbon edge plays critical roles by introducing extra doping and damping the graphene plasmon resonance.

  20. Homoepitaxial tunnel barriers with functionalized graphene-on-graphene for charge and spin transport.

    PubMed

    Friedman, Adam L; van 't Erve, Olaf M J; Li, Connie H; Robinson, Jeremy T; Jonker, Berend T

    2014-01-01

    The coupled imperatives for reduced heat dissipation and power consumption in high-density electronics have rekindled interest in devices based on tunnelling. Such devices require mating dissimilar materials, raising issues of heteroepitaxy, layer uniformity, interface stability and electronic states that severely complicate fabrication and compromise performance. Two-dimensional materials such as graphene obviate these issues and offer a new paradigm for tunnel barriers. Here we demonstrate a homoepitaxial tunnel barrier structure in which graphene serves as both the tunnel barrier and the high-mobility transport channel. We fluorinate the top layer of a graphene bilayer to decouple it from the bottom layer, so that it serves as a single-monolayer tunnel barrier for both charge and spin injection into the lower graphene channel. We demonstrate high spin injection efficiency with a tunnelling spin polarization >60%, lateral transport of spin currents in non-local spin-valve structures and determine spin lifetimes with the Hanle effect. PMID:24445349

  1. Electrical tuning of valley magnetic moment through symmetry control in bilayer MoS2

    SciTech Connect

    Wu, Sanfeng; Ross, Jason; Liu, G. B.; Aivazian, Grant; Jones, Aaron; Fei, Zaiyao; Zhu, Wenguang; Xiao, Di; Yao, Wang; Cobden, David; Xu, Xiaodong

    2013-01-01

    Crystal symmetry governs the nature of electronic Bloch states. For example, in the presence of time-reversal symmetry, the orbital magnetic moment and Berry curvature of the Bloch states must vanish unless inversion symmetry is broken1. In certain two-dimensional electron systems such as bilayer graphene, the intrinsic inversion symmetry can be broken simply by applying a perpendicular electric field2,3. In principle, this offers the possibility of switching on/off and continuously tuning the magnetic moment and Berry curvature near the Dirac valleys by reversible electrical control4,5. Here we investigate this possibility using polarization-resolved photoluminescence of bilayer MoS2, which has the same symmetry as bilayer graphene but has a bandgap in the visible spectrum6,7 allowing direct optical probing5,8 12. We find that in bilayer MoS2 the circularly polarized photoluminescence can be continuously tuned from 15% to 15% as a function of gate voltage, whereas in structurally non-centrosymmetric monolayer MoS2 the photoluminescence polarization is gate independent. The observations are well explained as resulting from the continuous variation of orbital magnetic moments between positive and negative values through symmetry control.

  2. Van der Waals correlation between two 4He monolayers on the opposite sides of graphene

    NASA Astrophysics Data System (ADS)

    Kwon, Yongkyung

    2015-06-01

    Path-integral Monte Carlo calculations have been performed to study the correlation between two 4He monolayers adsorbed on opposite sides of a graphene sheet. Here, the 4He-substrate interaction is described by the pairwise sum of the 4He-C interatomic potentials. We employ two different anisotropic 4He-C pair potentials proposed to fit the helium scattering data on a graphite surface, namely, a 6-12 Lennard-Jones potential and a Yukawa-6 potential. With the Lennard-Jones substrate potential, we do not observe any noticeable correlation between two oppositeside 4He monolayers, which is consistent with the prediction of the previous theoretical studies based on the same substrate potential. When the Yukawa-6 substrate potential is used, however, two incommensurate triangular solids, which are realized at the first-layer completion density of 0.12 Å -2, are found to favor an AA stacking order, two triangular lattices on top of each other, over an AB stacking. Finally, the effects of this interlayer correlation on the formation of stable mobile vacancies are discussed.

  3. Final Report on Investigation of the Electron Interactions in Graphene

    SciTech Connect

    Kim, Philip

    2015-02-14

    In graphene, combined with the real spin degree of freedom, which exhibits SU(2) symmetry, the total internal degrees of freedom of graphene carriers is thus described by a larger SU(4) symmetry, which produces a richer space for potential phenomena of emergent correlated electron phenomena. The major part of this proposal is exploring this unique multicomponent correlated system in the quantum limit. In the current period of DOE BES support we have made several key advances that will serve as a foundation for the new studies in this proposal. Employing the high-mobility encapsulated graphene heterostructures developed during the current phase of research, we have investigated spin and valley quantum Hall ferromagnetism in graphene and discovered a spin phase transition leading to a quantum spin Hall analogue. We have also observed the fractal quantum Hall effect arising from the Hofstadter’s butterfly energy spectrum. In addition, we have discovered multiband transport phenomena in bilayer graphene at high carrier densities.

  4. Large-Area Growth of Turbostratic Graphene on Ni(111) via Physical Vapor Deposition.

    PubMed

    Garlow, Joseph A; Barrett, Lawrence K; Wu, Lijun; Kisslinger, Kim; Zhu, Yimei; Pulecio, Javier F

    2016-01-01

    Single-layer graphene has demonstrated remarkable electronic properties that are strongly influenced by interfacial bonding and break down for the lowest energy configuration of stacked graphene layers (AB Bernal). Multilayer graphene with relative rotations between carbon layers, known as turbostratic graphene, can effectively decouple the electronic states of adjacent layers, preserving properties similar to that of SLG. While the growth of AB Bernal graphene through chemical vapor deposition has been widely reported, we investigate the growth of turbostratic graphene on heteroepitaxial Ni(111) thin films utilizing physical vapor deposition. By varying the carbon deposition temperature between 800 -1100 °C, we report an increase in the graphene quality concomitant with a transition in the size of uniform thickness graphene, ranging from nanocrystallites to thousands of square microns. Combination Raman modes of as-grown graphene within the frequency range of 1650 cm(-1) to 2300 cm(-1), along with features of the Raman 2D mode, were employed as signatures of turbostratic graphene. Bilayer and multilayer graphene were directly identified from areas that exhibited Raman characteristics of turbostratic graphene using high-resolution TEM imaging. Raman maps of the pertinent modes reveal large regions of turbostratic graphene on Ni(111) thin films at a deposition temperature of 1100 °C. PMID:26821604

  5. Large-Area Growth of Turbostratic Graphene on Ni(111) via Physical Vapor Deposition

    NASA Astrophysics Data System (ADS)

    Garlow, Joseph A.; Barrett, Lawrence K.; Wu, Lijun; Kisslinger, Kim; Zhu, Yimei; Pulecio, Javier F.

    2016-01-01

    Single-layer graphene has demonstrated remarkable electronic properties that are strongly influenced by interfacial bonding and break down for the lowest energy configuration of stacked graphene layers (AB Bernal). Multilayer graphene with relative rotations between carbon layers, known as turbostratic graphene, can effectively decouple the electronic states of adjacent layers, preserving properties similar to that of SLG. While the growth of AB Bernal graphene through chemical vapor deposition has been widely reported, we investigate the growth of turbostratic graphene on heteroepitaxial Ni(111) thin films utilizing physical vapor deposition. By varying the carbon deposition temperature between 800 -1100 °C, we report an increase in the graphene quality concomitant with a transition in the size of uniform thickness graphene, ranging from nanocrystallites to thousands of square microns. Combination Raman modes of as-grown graphene within the frequency range of 1650 cm-1 to 2300 cm-1, along with features of the Raman 2D mode, were employed as signatures of turbostratic graphene. Bilayer and multilayer graphene were directly identified from areas that exhibited Raman characteristics of turbostratic graphene using high-resolution TEM imaging. Raman maps of the pertinent modes reveal large regions of turbostratic graphene on Ni(111) thin films at a deposition temperature of 1100 °C.

  6. Large-Area Growth of Turbostratic Graphene on Ni(111) via Physical Vapor Deposition

    PubMed Central

    Garlow, Joseph A.; Barrett, Lawrence K.; Wu, Lijun; Kisslinger, Kim; Zhu, Yimei; Pulecio, Javier F.

    2016-01-01

    Single-layer graphene has demonstrated remarkable electronic properties that are strongly influenced by interfacial bonding and break down for the lowest energy configuration of stacked graphene layers (AB Bernal). Multilayer graphene with relative rotations between carbon layers, known as turbostratic graphene, can effectively decouple the electronic states of adjacent layers, preserving properties similar to that of SLG. While the growth of AB Bernal graphene through chemical vapor deposition has been widely reported, we investigate the growth of turbostratic graphene on heteroepitaxial Ni(111) thin films utilizing physical vapor deposition. By varying the carbon deposition temperature between 800 –1100 °C, we report an increase in the graphene quality concomitant with a transition in the size of uniform thickness graphene, ranging from nanocrystallites to thousands of square microns. Combination Raman modes of as-grown graphene within the frequency range of 1650 cm−1 to 2300 cm−1, along with features of the Raman 2D mode, were employed as signatures of turbostratic graphene. Bilayer and multilayer graphene were directly identified from areas that exhibited Raman characteristics of turbostratic graphene using high-resolution TEM imaging. Raman maps of the pertinent modes reveal large regions of turbostratic graphene on Ni(111) thin films at a deposition temperature of 1100 °C. PMID:26821604

  7. Large-Area Growth of Turbostratic Graphene on Ni(111) via Physical Vapor Deposition

    DOE PAGESBeta

    Garlow, Joseph A.; Barrett, Lawrence K.; Wu, Lijun; Kisslinger, Kim; Zhu, Yimei; Pulecio, Javier F.

    2016-01-29

    Single-layer graphene has demonstrated remarkable electronic properties that are strongly influenced by interfacial bonding and break down for the lowest energy configuration of stacked graphene layers (AB Bernal). Multilayer graphene with relative rotations between carbon layers, known as turbostratic graphene, can effectively decouple the electronic states of adjacent layers, preserving properties similar to that of SLG. While the growth of AB Bernal graphene through chemical vapor deposition has been widely reported, we investigate the growth of turbostratic graphene on heteroepitaxial Ni(111) thin films utilizing physical vapor deposition. By varying the carbon deposition temperature between 800–1100°C, we report an increase inmore » the graphene quality concomitant with a transition in the size of uniform thickness graphene, ranging from nanocrystallites to thousands of square microns. Combination Raman modes of as-grown graphene within the frequency range of 1650 cm₋1 to 2300 cm₋1, along with features of the Raman 2D mode, were employed as signatures of turbostratic graphene. Bilayer and multilayer graphene were directly identified from areas that exhibited Raman characteristics of turbostratic graphene using high-resolution TEM imaging. Lastly, Raman maps of the pertinent modes reveal large regions of turbostratic graphene on Ni(111) thin films at a deposition temperature of 1100°C.« less

  8. Effect of non-bonded interactions on failure morphology of a defective graphene sheet

    NASA Astrophysics Data System (ADS)

    Degefe, Muse; Parashar, Avinash

    2016-04-01

    Molecular dynamics based atomistic modeling was performed to predict and quantify the effect of non-bonded interactions on the failure morphology of vacancy-affected sheets of graphene. A defective sheet of graphene containing vacancy defects was simulated in conjunction with the non-bonded interactions experienced due to the presence of a pristine sheet of graphene. In this study, the author revealed the mechanical properties and failure morphology of bilayer graphene sheets under the influence of single, double and multi-vacancy defects. It was concluded on the basis of atomistic simulations that non-bonded interactions as well as the stiffness of the pristine graphene sheet has significant impact on the failure morphology of the accompanied defective sheet of graphene. Non-bonded interactions in conjunction with defects can be further explored for modifying the brittle nature of graphene to ductile.

  9. Life, death and membrane bilayers.

    PubMed

    Hulbert, A J

    2003-07-01

    Membrane bilayers are essential elements of life, and the synthesis of the hydrocarbons that make up membrane bilayers may have preceded the appearance of life on Earth. Membrane-associated processes are significant components of metabolism, and the acyl composition of membrane bilayers is associated with metabolic activity in a predictable manner. This has resulted in the "membrane pacemaker" theory of metabolism, which proposes that the relative balance between monounsaturated and long-chain polyunsaturated acyl chains in membrane bilayers is a fundamental determinant of metabolic rate of a species. The omega-3 polyunsaturated docosahexaenoate is an especially important component of membranes in this regard. Whilst it is suggested that the physical properties of membrane polyunsaturates are important with respect to their influence on metabolic rate, it is their chemistry that is important in aging. Membrane acyl composition is related to maximum lifespan in mammals and birds, probably via their role in lipid peroxidation. Calorie restriction modifies acyl composition of membrane bilayers and is associated with decreased membrane lipid peroxidation and lifespan extension. The membrane pacemaker theory of metabolism has given birth to the membrane pacemaker hypothesis of aging, which will require further investigation. PMID:12796449

  10. Determination of a refractive index and an extinction coefficient of standard production of CVD-graphene

    NASA Astrophysics Data System (ADS)

    Ochoa-Martínez, Efraín; Gabás, Mercedes; Barrutia, Laura; Pesquera, Amaia; Centeno, Alba; Palanco, Santiago; Zurutuza, Amaia; Algora, Carlos

    2015-01-01

    The refractive index and extinction coefficient of chemical vapour deposition grown graphene are determined by ellipsometry analysis. Graphene films were grown on copper substrates and transferred as both monolayers and bilayers onto SiO2/Si substrates by using standard manufacturing procedures. The chemical nature and thickness of residual debris formed after the transfer process were elucidated using photoelectron spectroscopy. The real layered structure so deduced has been used instead of the nominal one as the input in the ellipsometry analysis of monolayer and bilayer graphene, transferred onto both native and thermal silicon oxide. The effect of these contamination layers on the optical properties of the stacked structure is noticeable both in the visible and the ultraviolet spectral regions, thus masking the graphene optical response. Finally, the use of heat treatment under a nitrogen atmosphere of the graphene-based stacked structures, as a method to reduce the water content of the sample, and its effect on the optical response of both graphene and the residual debris layer are presented. The Lorentz-Drude model proposed for the optical response of graphene fits fairly well the experimental ellipsometric data for all the analysed graphene-based stacked structures.The refractive index and extinction coefficient of chemical vapour deposition grown graphene are determined by ellipsometry analysis. Graphene films were grown on copper substrates and transferred as both monolayers and bilayers onto SiO2/Si substrates by using standard manufacturing procedures. The chemical nature and thickness of residual debris formed after the transfer process were elucidated using photoelectron spectroscopy. The real layered structure so deduced has been used instead of the nominal one as the input in the ellipsometry analysis of monolayer and bilayer graphene, transferred onto both native and thermal silicon oxide. The effect of these contamination layers on the optical

  11. Transport properties of graphene and its application

    NASA Astrophysics Data System (ADS)

    Lu, Jianming

    This thesis focuses on the transport properties of graphene, a new emerging atomically thin, two-dimensional material, with and without the application of a magnetic field. Because of its high mobility, graphene is a promising candidate for Extraordinary Magnetoresistance (EMR) devices. The magnetoresistance of an EMR device arises mainly from its geometry rather than the intrinsic response of the material itself to an applied magnetic field. As a result, the geometric parameters play an important role in its performance. Experiments employing various combinations of geometric parameters and graphene of different quality levels were conducted to determine the optimal results. We found that the optimized parameters vary for different applied magnetic fields. In a magnetic field of 9 Tesla, magnetoresistance up to 55,000% was observed. In addition, Finite Element Analysis (FEA) simulations are used to complement the experiments and explain the measured magnetoresistance. The excellent agreement between the simulations and experimental results indicates that theoretical simulation can be used as a convenient method to explore EMR devices with alternative geometries or materials. The anomalous quantum Hall effect is one of the most exciting properties of graphene. The observation of the v=0 state above a critical magnetic field is closely related to the quality of the graphene, where a higher quality reduces the critical field needed. With our high quality graphene sample, the critical field is reduced to 6.75 Tesla. Moreover, from 6.75 T to 9T, the resistance at the cross point of the metal-insulator transition (MIT) is very close to h/2e2, which resembles the case of a disordered two-dimensional electron gas (2DEG) and may indicate a similar physical mechanism. In addition to the magnetotransport measurements, the current saturation of graphene in a high electric field is studied both theoretically and experimentally. This thesis focuses primarily on bilayer graphene

  12. Tunneling spectra of graphene on copper unraveled.

    PubMed

    Zhang, Xin; Stradi, Daniele; Liu, Lei; Luo, Hong; Brandbyge, Mads; Gu, Gong

    2016-06-22

    Scanning tunneling spectroscopy is often employed to study two-dimensional (2D) materials on conductive growth substrates, in order to gain information on the electronic structures of the 2D material-substrate systems, which can lead to insight into 2D material-substrate interactions, growth mechanisms, etc. The interpretation of the spectra can be complicated, however. Specifically for graphene grown on copper, there have been conflicting reports of tunneling spectra. A clear understanding of the mechanisms behind the variability is desired. In this work, we have revealed that the root cause of the variability in tunneling spectra is the variation in graphene-substrate coupling under various experimental conditions, providing a salutary perspective on the important role of 2D material-substrate interactions. The conclusions are drawn from measured data and theoretical calculations for monolayer, AB-stacked bilayer, and twisted bilayer graphene coexisting on the same substrates in areas with and without intercalated oxygen, demonstrating a high degree of consistency. The Van Hove singularities of the twisted graphene unambiguously indicate the Dirac energy between them, lending strong evidence to our assignment of the spectral features. In addition, we have discovered an O-Cu superstructure that has never been observed before. PMID:27297050

  13. Star polymer unimicelles on graphene oxide flakes.

    PubMed

    Choi, Ikjun; Kulkarni, Dhaval D; Xu, Weinan; Tsitsilianis, Constantinos; Tsukruk, Vladimir V

    2013-08-01

    We report the interfacial assembly of amphiphilic heteroarm star copolymers (PSnP2VPn and PSn(P2VP-b-PtBA)n (n = 28 arms)) on graphene oxide flakes at the air-water interface. Adsorption, spreading, and ordering of star polymer micelles on the surface of the basal plane and edge of monolayer graphene oxide sheets were investigated on a Langmuir trough. This interface-mediated assembly resulted in micelle-decorated graphene oxide sheets with uniform spacing and organized morphology. We found that the surface activity of solvated graphene oxide sheets enables star polymer surfactants to subsequently adsorb on the presuspended graphene oxide sheets, thereby producing a bilayer complex. The positively charged heterocyclic pyridine-containing star polymers exhibited strong affinity onto the basal plane and edge of graphene oxide, leading to a well-organized and long-range ordered discrete micelle assembly. The preferred binding can be related to the increased conformational entropy due to the reduction of interarm repulsion. The extent of coverage was tuned by controlling assembly parameters such as concentration and solvent polarity. The polymer micelles on the basal plane remained incompressible under lateral compression in contrast to ones on the water surface due to strongly repulsive confined arms on the polar surface of graphene oxide and a preventive barrier in the form of the sheet edges. The densely packed biphasic tile-like morphology was evident, suggesting the high interfacial stability and mechanically stiff nature of graphene oxide sheets decorated with star polymer micelles. This noncovalent assembly represents a facile route for the control and fabrication of graphene oxide-inclusive ultrathin hybrid films applicable for layered nanocomposites. PMID:23883114

  14. Aromatic graphene

    NASA Astrophysics Data System (ADS)

    Das, D. K.; Sahoo, S.

    2016-04-01

    In recent years graphene attracts the scientific and engineering communities due to its outstanding electronic, thermal, mechanical and optical properties and many potential applications. Recently, Popov et al. [1] have studied the properties of graphene and proved that it is aromatic but without fragrance. In this paper, we present a theory to prepare graphene with fragrance. This can be used as scented pencils, perfumes, room and car fresheners, cosmetics and many other useful household substances.

  15. High-quality thin graphene films from fast electrochemical exfoliation.

    PubMed

    Su, Ching-Yuan; Lu, Ang-Yu; Xu, Yanping; Chen, Fu-Rong; Khlobystov, Andrei N; Li, Lain-Jong

    2011-03-22

    Flexible and ultratransparent conductors based on graphene sheets have been considered as one promising candidate for replacing currently used indium tin oxide films that are unlikely to satisfy future needs due to their increasing cost and losses in conductivity on bending. Here we demonstrate a simple and fast electrochemical method to exfoliate graphite into thin graphene sheets, mainly AB-stacked bilayered graphene with a large lateral size (several to several tens of micrometers). The electrical properties of these exfoliated sheets are readily superior to commonly used reduced graphene oxide, which preparation typically requires many steps including oxidation of graphite and high temperature reduction. These graphene sheets dissolve in dimethyl formamide (DMF), and they can self-aggregate at air-DMF interfaces after adding water as an antisolvent due to their strong surface hydrophobicity. Interestingly, the continuous films obtained exhibit ultratransparency (∼96% transmittance), and their sheet resistance is <1k Ω/sq after a simple HNO3 treatment, superior to those based on reduced graphene oxide or graphene sheets by other exfoliation methods. Raman and STM characterizations corroborate that the graphene sheets exfoliated by our electrochemical method preserve the intrinsic structure of graphene. PMID:21309565

  16. Electromechanical coupling in atomically thin MoS2 and graphene

    NASA Astrophysics Data System (ADS)

    Manzeli, Sajedeh; Benameur, Muhammed Malik; Allain, Adrien; Ghadimi, Amirhossein; Tosun, Mahmut; Kis, Andras; Gargiulo, Fernando; Autès, Gabriel; Yazyev, Oleg V.

    Nanoelectromechanical systems (NEMS) based on novel materials such as graphene and MoS2 allow studying their electromechanical characteristics. Here, we incorporate single and bilayer MoS2 and graphene into NEMS and investigated their electromechanical behavior. We observe a Strain-induced bandgap modulation in atomically thin MoS2 membranes with a thickness dependent modulation rate. Finite element modeling is used to extract the piezoresistive gauge factor for MoS2. In the case of graphene, deflection of monolayer graphene nanoribbons results in a linear increase in their electrical resistance where an upper limit is estimated for the gauge factor. Surprisingly, we observe oscillations in the electromechanical response of bilayer graphene. Our numerical simulations indicate that these oscillations arise from quantum mechanical interference in the transition region induced by sliding of individual graphene layers with respect to each other. Our results reveal that atomically thin MoS2 membranes show strong piezoresistive effect, comparable to the state-of-the-art silicon sensors. Moreover, bilayer graphene conceals unexpectedly novel physics allowing the rare observation of room temperature electronic interference phenomena.

  17. Graphene nanoribbons without cutting graphene

    NASA Astrophysics Data System (ADS)

    Paes Lima, Matheus; Reily Rocha, Alexandre; da Silva, Antônio J. R.; Fazzio, Adalberto

    2010-03-01

    We show that the 2D periodic graphene deposited on Silicon Carbide surface with a trench mimics a grapheme nanoribbon. Our study is carried out with calculations based on Density Functional Theory. In our work, the graphene is deposited at the [0001] and the [0001 = ] surfaces. We investigate the influence of the charge transfer between the graphene and the substrate, the local magnetic moment, as well as the direction of the trench on the electronic properties of such systems. Our results suggest that at the [0001] surface the charge transfer is large resulting in a large change in the Fermi energy. As a consequence, the mimicked armchair graphene nanoribbons turn out to be metallic and the mimicked zigzag graphene nanoribbons are nonmagnetic. These properties are distinct from the corresponding free standing graphene nanoribbons. On the other hand, at the [0001 = ] surface, the charge transfer is small, and the properties of the mimicked ribbons are very similar to the free standing ones.

  18. EDITORIAL: Epitaxial graphene Epitaxial graphene

    NASA Astrophysics Data System (ADS)

    de Heer, Walt A.; Berger, Claire

    2012-04-01

    Graphene is widely regarded as an important new electronic material with interesting two-dimensional electron gas properties. Not only that, but graphene is widely considered to be an important new material for large-scale integrated electronic devices that may eventually even succeed silicon. In fact, there are countless publications that demonstrate the amazing applications potential of graphene. In order to realize graphene electronics, a platform is required that is compatible with large-scale electronics processing methods. It was clear from the outset that graphene grown epitaxially on silicon carbide substrates was exceptionally well suited as a platform for graphene-based electronics, not only because the graphene sheets are grown directly on electronics-grade silicon carbide (an important semiconductor in its own right), but also because these sheets are oriented with respect to the semiconductor. Moreover, the extremely high temperatures involved in production assure essentially defect-free and contamination-free materials with well-defined interfaces. Epitaxial graphene on silicon carbide is not a unique material, but actually a class of materials. It is a complex structure consisting of a reconstructed silicon carbide surface, which, for planar hexagonal silicon carbide, is either the silicon- or the carbon-terminated face, an interfacial carbon rich layer, followed by one or more graphene layers. Consequently, the structure of graphene films on silicon carbide turns out to be a rich surface-science puzzle that has been intensively studied and systematically unravelled with a wide variety of surface science probes. Moreover, the graphene films produced on the carbon-terminated face turn out to be rotationally stacked, resulting in unique and important structural and electronic properties. Finally, in contrast to essentially all other graphene production methods, epitaxial graphene can be grown on structured silicon carbide surfaces to produce graphene

  19. Epitaxial graphene: the material for graphene electronics

    SciTech Connect

    Sprinkle, M.; Soukiassian, P.; de Heer, W.A.; Berger, C.; Conrad, E.H.

    2009-12-10

    The search for an ideal graphene sheet has been a quest driving graphene research. While most research has focused on exfoliated graphene, intrinsic substrate interactions and mechanical disorder have precluded the observation of a number of graphene's expected physical properties in this material. The only graphene candidate that has demonstrated all the essential properties of an ideal sheet is multilayer graphene grown on the SiC(000) surface. Its unique stacking allows nearly all the sheets in the stack to behave like isolated graphene, while the weak graphene-graphene interaction prevents any significant doping or distortion in the band near the Fermi level.

  20. Surfactant transport on viscous bilayers

    NASA Astrophysics Data System (ADS)

    Matar, Omar; Craster, Richard; Warner, Mark

    2001-11-01

    We model the external delivery of surfactant to pulmonary airways, an integral part of Surfactant Replacement Therapy (SRT), a method of treatment of Respiratory Distress Syndrome in neonates. We examine the spreading dynamics of insoluble surfactant by Marangoni stresses along the mucus-perciliary liquid bilayers that line the inside of airways. The bilayer is modelled as a thin highly viscous mucus surface film (mucus) overlying a much less viscous perciliary liquid layer (PCL); this is appropriate for small airways. By exploiting this large viscosity constrast, a variant of standard lubrication theory is adopted wherein terms, which would have otherwise been neglected in the lubrication approximation, are promoted in order to model correctly the presence of the mucus. Inclusion of van der Waals forces in the model permit the study of the effect of this mucus 'skin' on the possibility of bilayer rupture, a potential cause of failure of SRT. We find that increasing the viscosity contrast and initial mucus layer thickness delays the onset of rupture, while increasing the relative significance of Marangoni stresses leads to more marked thinning and rapid bilayer rupture [1]. [1] O. K. Matar, R. V. Craster and M. R. Warner, submitted to J. Fluid Mech. (2001).

  1. Manipulating graphene's lattice to create pseudovector potentials, discover anomalous friction, and measure strain dependent thermal conductivity

    NASA Astrophysics Data System (ADS)

    Kitt, Alexander Luke

    Graphene is a single atomic sheet of graphite that exhibits a diverse range of unique properties. The electrons in intrinsic graphene behave like relativistic Dirac fermions; graphene has a record high Young's modulus but extremely low bending rigidity; and suspended graphene exhibits very high thermal conductivity. These properties are made more intriguing because with a thickness of only a single atomic layer, graphene is both especially affected by its environment and readily manipulated. In this dissertation the interaction between graphene and its environment as well as the exciting new physics realized by manipulating graphene's lattice are investigated. Lattice manipulations in the form of strain cause alterations in graphene's electrical dispersion mathematically analogous to the vector potential associated with a magnetic field. We complete the standard description of the strain-induced vector potential by explicitly including the lattice deformations and find new, leading order terms. Additionally, a strain engineered device with large, localized, plasmonically enhanced pseudomagnetic fields is proposed to couple light to pseudomagnetic fields. Accurate strain engineering requires a complete understanding of the interactions between a two dimensional material and its environment, particularly the adhesion and friction between graphene and its supporting substrate. We measure the load dependent sliding friction between mono-, bi-, and trilayer graphene and the commonly used silicon dioxide substrate by analyzing Raman spectra of circular, graphene sealed microchambers under variable external pressure. We find that the sliding friction for trilayer graphene behaves normally, scaling with the applied load, whereas the friction for monolayer and bilayer graphene is anomalous, scaling with the inverse of the strain in the graphene. Both strain and graphene's environment are expected to affect the quadratically dispersed out of plane acoustic phonon. Although

  2. Infrared spectroscopy of vertical heterostructures of graphene and hexagonal boron nitride

    NASA Astrophysics Data System (ADS)

    Mucha-Kruczyński, Marcin; Abergel, David

    We suggest that optical absorption of monolayer and bilayer graphene on hexagonal boron nitride will provide meaningful information about the moiré characteristics. In particular, study of the absorption spectrum as a function of the doping for an almost completely full first miniband will distinguish between various theoretical proposals for the physically realistic interaction. Also, for bilayer graphene, the ability to compare spectra for the opposite signs of the interlayer asymmetry induced by an external electric field might provide additional information about the moiré parameters. This research was funded by EPSRC Grant No. EP/L013010/1 (MM-K), and ERC project DM-321031 (DSLA),.

  3. Graphene nanomesh

    PubMed Central

    Bai, Jingwei; Zhong, Xing; Jiang, Shan; Huang, Yu; Duan, Xiangfeng

    2010-01-01

    Graphene has significant potential for application in electronics1-5, but cannot be used for effective field-effect transistors operating at room temperature because it is a semimetal with a zero bandgap6,7. Processing graphene sheets into nanoribbons with widths of less than 10nm can open up a bandgap that is large enough for room temperature transistor operation8-19, but nanoribbon devices often have low driving currents or transconductances18,19. Moreover, practical devices and circuits will require the production of dense arrays of ordered nanoribbons, which is of significant challenge20,21. Here we report the production of a new graphene nanostructure - which we call graphene nanomesh - that can open up a band gap in a large sheet of graphene to create a semiconducting thin film. The nanomeshes are prepared with block copolymer lithography and can have variable periodicities and neck widths down to 5 nm. Graphene nanomesh field-effect transistors can support currents nearly 100 times greater than individual graphene nanoribbon devices, and the on-off ratio - which is comparable with the values achieved in individual nanoribbon devices - can be tuned by varying the neck width. The block copolymer lithography approach used to make the nanomesh devices is intrinsically scalable and could allow for the rational design and fabrication of graphene-based devices and circuits with standard semiconductor processing. PMID:20154685

  4. Charging the Quantum Capacitance of Graphene with a Single Biological Ion Channel

    PubMed Central

    2015-01-01

    The interaction of cell and organelle membranes (lipid bilayers) with nanoelectronics can enable new technologies to sense and measure electrophysiology in qualitatively new ways. To date, a variety of sensing devices have been demonstrated to measure membrane currents through macroscopic numbers of ion channels. However, nanoelectronic based sensing of single ion channel currents has been a challenge. Here, we report graphene-based field-effect transistors combined with supported lipid bilayers as a platform for measuring, for the first time, individual ion channel activity. We show that the supported lipid bilayers uniformly coat the single layer graphene surface, acting as a biomimetic barrier that insulates (both electrically and chemically) the graphene from the electrolyte environment. Upon introduction of pore-forming membrane proteins such as alamethicin and gramicidin A, current pulses are observed through the lipid bilayers from the graphene to the electrolyte, which charge the quantum capacitance of the graphene. This approach combines nanotechnology with electrophysiology to demonstrate qualitatively new ways of measuring ion channel currents. PMID:24754625

  5. Large-Scale Graphene Film Deposition for Monolithic Device Fabrication

    NASA Astrophysics Data System (ADS)

    Al-shurman, Khaled

    and on the silicon-based substrate. Large- area bilayer graphene film was formed on silicon based platform. COMSOL Multiphysics was used to investigate the CVD graphene growth on Ni films. Factors affecting CVD graphene synthesis include carbon solubility in Ni, growth time, growth temperature, as well as Ni film thickness. COMSOL model uses transport of diluted species, heat transfer in Ni thin film as well as deformed geometry module. In this particular research, the number of simulated graphene layers on Ni film was compared with experimental data. Also, the effect of many CVD parameters on graphene film fabrication is stated. In conclusion, a novel method for direct large-scale graphene film fabrication on silicon based platform at low temperature was achieved using hot-filament chemical vapor deposition.

  6. Damage evaluation in graphene underlying atomic layer deposition dielectrics

    PubMed Central

    Tang, Xiaohui; Reckinger, Nicolas; Poncelet, Olivier; Louette, Pierre; Ureña, Ferran; Idrissi, Hosni; Turner, Stuart; Cabosart, Damien; Colomer, Jean-François; Raskin, Jean-Pierre; Hackens, Benoit; Francis, Laurent A.

    2015-01-01

    Based on micro-Raman spectroscopy (μRS) and X-ray photoelectron spectroscopy (XPS), we study the structural damage incurred in monolayer (1L) and few-layer (FL) graphene subjected to atomic-layer deposition of HfO2 and Al2O3 upon different oxygen plasma power levels. We evaluate the damage level and the influence of the HfO2 thickness on graphene. The results indicate that in the case of Al2O3/graphene, whether 1L or FL graphene is strongly damaged under our process conditions. For the case of HfO2/graphene, μRS analysis clearly shows that FL graphene is less disordered than 1L graphene. In addition, the damage levels in FL graphene decrease with the number of layers. Moreover, the FL graphene damage is inversely proportional to the thickness of HfO2 film. Particularly, the bottom layer of twisted bilayer (t-2L) has the salient features of 1L graphene. Therefore, FL graphene allows for controlling/limiting the degree of defect during the PE-ALD HfO2 of dielectrics and could be a good starting material for building field effect transistors, sensors, touch screens and solar cells. Besides, the formation of Hf-C bonds may favor growing high-quality and uniform-coverage dielectric. HfO2 could be a suitable high-K gate dielectric with a scaling capability down to sub-5-nm for graphene-based transistors. PMID:26311131

  7. Damage evaluation in graphene underlying atomic layer deposition dielectrics.

    PubMed

    Tang, Xiaohui; Reckinger, Nicolas; Poncelet, Olivier; Louette, Pierre; Ureña, Ferran; Idrissi, Hosni; Turner, Stuart; Cabosart, Damien; Colomer, Jean-François; Raskin, Jean-Pierre; Hackens, Benoit; Francis, Laurent A

    2015-01-01

    Based on micro-Raman spectroscopy (μRS) and X-ray photoelectron spectroscopy (XPS), we study the structural damage incurred in monolayer (1L) and few-layer (FL) graphene subjected to atomic-layer deposition of HfO2 and Al2O3 upon different oxygen plasma power levels. We evaluate the damage level and the influence of the HfO2 thickness on graphene. The results indicate that in the case of Al2O3/graphene, whether 1L or FL graphene is strongly damaged under our process conditions. For the case of HfO2/graphene, μRS analysis clearly shows that FL graphene is less disordered than 1L graphene. In addition, the damage levels in FL graphene decrease with the number of layers. Moreover, the FL graphene damage is inversely proportional to the thickness of HfO2 film. Particularly, the bottom layer of twisted bilayer (t-2L) has the salient features of 1L graphene. Therefore, FL graphene allows for controlling/limiting the degree of defect during the PE-ALD HfO2 of dielectrics and could be a good starting material for building field effect transistors, sensors, touch screens and solar cells. Besides, the formation of Hf-C bonds may favor growing high-quality and uniform-coverage dielectric. HfO2 could be a suitable high-K gate dielectric with a scaling capability down to sub-5-nm for graphene-based transistors. PMID:26311131

  8. Interface structure of epitaxial graphene grown on 4H-SiC(0001)

    SciTech Connect

    Hass, J.; Millán-Otoya, J.E.; First, P.N.; Conrad, E.H.

    2009-06-12

    We present a structural analysis of the graphene-4HSiC(0001) interface using surface x-ray reflectivity. We find that the interface is composed of an extended reconstruction of two SiC bilayers. The interface directly below the first graphene sheet is an extended layer that is more than twice the thickness of a bulk SiC bilayer ({approx}1.7 {angstrom} compared to 0.63 {angstrom}). The distance from this interface layer to the first graphene sheet is much smaller than the graphite interlayer spacing but larger than the same distance measured for graphene grown on the (000{bar 1}) surface, as predicted previously by ab initio calculations.

  9. Spin and valley resolved Landau level crossing in tri-layer ABA stacked graphene

    NASA Astrophysics Data System (ADS)

    Datta, Biswajit; Gupta, Vishakha; Borah, Abhinandan; Watanabe, Kenji; Taniguchi, Takashi; Deshmukh, Mandar

    We present quantum Hall measurements on a high quality encapsulated tri-layer graphene device. Low temperature field effect mobility of this device is around 500,000 cm2/Vs and we see SdH oscillations at a magnetic field as low as 0.3 T. Quantum Hall measurements confirm that the chosen tri layer graphene is Bernal (ABA) stacked. Due to the presence of both mass-less monolayer like Dirac fermions and massive bi-layer like Dirac fermions in Bernal stacked tri-layer graphene, there are Landau level crossings between monolayer and bi-layer bands in quantum Hall regime. Although most of the Landau Level crossings are predominantly present on the electron sides, we also observe signatures of the crossings on the hole side. This behaviour is consistent with the asymmetry of electron and hole in ABA tri-layer graphene. We observe a series of crossings of the spin and valley resolved Landau Levels.

  10. Interlayer Potential for Graphene/h-BN Heterostructures.

    PubMed

    Leven, Itai; Maaravi, Tal; Azuri, Ido; Kronik, Leeor; Hod, Oded

    2016-06-14

    We present a new force-field potential that describes the interlayer interactions in heterojunctions based on graphene and hexagonal boron nitride (h-BN). The potential consists of a long-range attractive term and a short-range anisotropic repulsive term. Its parameters are calibrated against reference binding and sliding energy profiles for a set of finite dimer systems and the periodic graphene/h-BN bilayer, obtained from density functional theory using a screened-exchange hybrid functional augmented by a many-body dispersion treatment of long-range correlation. Transferability of the parametrization is demonstrated by considering the binding energy of bulk graphene/h-BN alternating stacks. Benchmark calculations for the superlattice formed when relaxing the supported periodic heterogeneous bilayer provide good agreement with both experimental results and previous computational studies. For a free-standing bilayer we predict a highly corrugated relaxed structure. This, in turn, is expected to strongly alter the physical properties of the underlying monolayers. Our results demonstrate the potential of the developed force-field to model the structural, mechanical, tribological, and dynamic properties of layered heterostructures based on graphene and h-BN. PMID:27168429

  11. The unexpected non-monotonic inter-layer bonding dependence of the thermal conductivity of bilayered boron nitride

    NASA Astrophysics Data System (ADS)

    Gao, Yufei; Zhang, Xiaoliang; Jing, Yuhang; Hu, Ming

    2015-04-01

    Hexagonal boron nitride (BN) and its bilayer form are very fascinating two-dimensional materials that have attracted tremendous interest recently. Their realistic applications in emerging nanoelectronics usually quest for manipulating the thermal transport properties in a precise manner. Using nonequilibrium molecular dynamics simulations, we herein studied the effect of inter-layer covalent bonding on the thermal conductivity of bilayered BN. We found that the in-plane thermal conductivity of bilayered BN, which can be largely tuned by introducing covalent bonding between the two BN layers, depends not only on the inter-layer bonding density, but also on the detailed topological configuration of the inter-layer bonds. For randomly distributed inter-layer bonding the thermal conductivity of bilayered BN decreases monotonically with inter-layer bonding density, the same behavior already found for bilayered graphene. However, for regularly arranged inter-layer bonding the thermal conductivity of bilayered BN surprisingly possesses a non-monotonic dependence on the inter-layer bonding density. This non-intuitive non-monotonic dependence is further explained by performing spectral energy density analysis, where the peak and valley values of the thermal conductivity are governed by different mechanisms. These results suggest the application of inter-layer covalent bonding in designing nanoscale devices with precisely tunable thermal conductivities.

  12. Folding and stacking defects of graphene flakes probed by electron nanobeam

    SciTech Connect

    Persichetti, L.; Fanfoni, M.; Sgarlata, A.; Balzarotti, A.; Tombolini, F.; Casciardi, S.; Diociaiuti, M.; Palleschi, G.; Valentini, F.

    2011-07-25

    Combining nanoscale imaging with local electron spectroscopy and diffraction has provided direct information on folding and stacking defects of graphene flakes produced by unrolled multi-walled carbon nanotubes. Structural data obtained by nanoarea electron diffraction complemented with systematic electron energy loss spectroscopy measurements of the surface plasmon losses of single flakes show the presence of flat bilayer regions coexisting with folded areas where the topology of buckled graphene resembles that of warped carbon nanostructures.

  13. Controlling graphene plasmons with resonant metal antennas and spatial conductivity patterns.

    PubMed

    Alonso-González, P; Nikitin, A Y; Golmar, F; Centeno, A; Pesquera, A; Vélez, S; Chen, J; Navickaite, G; Koppens, F; Zurutuza, A; Casanova, F; Hueso, L E; Hillenbrand, R

    2014-06-20

    Graphene plasmons promise unique possibilities for controlling light in nanoscale devices and for merging optics with electronics. We developed a versatile platform technology based on resonant optical antennas and conductivity patterns for launching and control of propagating graphene plasmons, an essential step for the development of graphene plasmonic circuits. We launched and focused infrared graphene plasmons with geometrically tailored antennas and observed how they refracted when passing through a two-dimensional conductivity pattern, here a prism-shaped bilayer. To that end, we directly mapped the graphene plasmon wavefronts by means of an imaging method that will be useful in testing future design concepts for nanoscale graphene plasmonic circuits and devices. PMID:24855026

  14. Rivet Graphene.

    PubMed

    Li, Xinlu; Sha, Junwei; Lee, Seoung-Ki; Li, Yilun; Ji, Yongsung; Zhao, Yujie; Tour, James M

    2016-08-23

    Large-area graphene has emerged as a promising material for use in flexible and transparent electronics due to its flexibility and optical and electronic properties. The anchoring of transition metal nanoparticles on large-area single-layer graphene is still a challenge. Here, we report an in situ preparation of carbon nano-onion-encapsulated Fe nanoparticles on rebar graphene, which we term rivet graphene. The hybrid film, which allows for polymer-free transfer and is strong enough to float on water with no added supports, exhibits high optical transparency, excellent electric conductivity, and good hole/electron mobility under certain tensile/compressive strains. The results of contact resistance and transfer length indicate that the current in the rivet graphene transistor does not just flow at the contact edge. Carbon nano-onions encapsulating Fe nanoparticles on the surface enhance the injection of charge between rivet graphene and the metal electrode. The anchoring of Fe nanoparticles encapsulated by carbon nano-onions on rebar graphene will provide additional avenues for applications of nanocarbon-based films in transparent and flexible electronics. PMID:27351673

  15. Graphene Kirigami

    NASA Astrophysics Data System (ADS)

    Blees, Melina; Rose, Peter; Barnard, Arthur; Roberts, Samantha; McEuen, Paul L.

    2014-03-01

    We have developed a powerful new approach to working with graphene by applying the principles of kirigami, the sculptural art of paper cutting. We have release graphene from the surface, allowing us to treat it like a sheet of atom-thick paper. Working in water, we can pull the graphene along the surface or peel it up entirely. Combining this technique with lithographic patterning, we have created a variety of graphene kirigami devices including three-dimensional structures and resilient, atomically-thin hinges. We have also created soft in-plane springs by patterning a series of cuts into the graphene. The spring constants of these devices depend on the pattern of cuts, so the patterned graphene becomes an adjustable mechanical metamaterial. With possible spring constants ranging from 1 N/m to 10-9 N/m, these springs could be used as sensitive force measurement devices. Such kirigami patterning techniques could also be applied to flexible and stretchable electronics, including soft electrodes for biological experiments. This unusual way of interacting with graphene opens up a world of potential applications that we are just beginning to explore.

  16. Controlled formation of closed-edge nanopores in graphene.

    PubMed

    He, Kuang; Robertson, Alex W; Gong, Chuncheng; Allen, Christopher S; Xu, Qiang; Zandbergen, Henny; Grossman, Jeffrey C; Kirkland, Angus I; Warner, Jamie H

    2015-07-21

    Dangling bonds at the edge of a nanopore in monolayer graphene make it susceptible to back-filling at low temperatures from atmospheric hydrocarbons, leading to potential instability for nanopore applications, such as DNA sequencing. We show that closed edge nanopores in bilayer graphene are robust to back-filling under atmospheric conditions for days. A controlled method for closed edge nanopore formation starting from monolayer graphene is reported using an in situ heating holder and electron beam irradiation within an aberration-corrected transmission electron microscopy. Tailoring of closed-edge nanopore sizes is demonstrated from 1.4-7.4 nm. These results should provide mechanisms for improving the stability of nanopores in graphene for a wide range of applications involving mass transport. PMID:26088477

  17. Remarks on the tight-binding model of graphene

    NASA Astrophysics Data System (ADS)

    Bena, Cristina; Montambaux, Gilles

    2009-09-01

    We address a simple but fundamental issue arising in the study of graphene, as well as of other systems that have a crystalline structure with more than one atom per unit cell. For these systems, the choice of the tight-binding basis is not unique. For monolayer graphene two bases are widely used in the literature. While the expectation values of operators describing physical quantities should be independent of basis, the form of the operators may depend on the basis, especially in the presence of disorder or of an applied magnetic field. Using an inappropriate form of certain operators may lead to erroneous physical predictions. We discuss the two bases used to describe monolayer graphene, as well as the form of the most commonly used operators in the two bases. We repeat our analysis for the case of bilayer graphene.

  18. Edge effect on resistance scaling rules in graphene nanostructures.

    PubMed

    Xu, Guangyu; Torres, Carlos M; Tang, Jianshi; Bai, Jingwei; Song, Emil B; Huang, Yu; Duan, Xiangfeng; Zhang, Yuegang; Wang, Kang L

    2011-03-01

    We report an experimental investigation of the edge effect on the room-temperature transport in graphene nanoribbon and graphene sheet (both single-layer and bilayer). By measuring the resistance scaling behaviors at both low- and high-carrier densities, we show that the transport of single-layer nanoribbons lies in a strong localization regime, which can be attributed to an edge effect. We find that this edge effect can be weakened by enlarging the width, decreasing the carrier densities, or adding an extra layer. From graphene nanoribbon to graphene sheet, the data show a dimensional crossover of the transport regimes possibly due to the drastic change of the edge effect. PMID:21322591

  19. Bilayer Effects of Antimalarial Compounds.

    PubMed

    Ramsey, Nicole B; Andersen, Olaf S

    2015-01-01

    Because of the perpetual development of resistance to current therapies for malaria, the Medicines for Malaria Venture developed the Malaria Box to facilitate the drug development process. We tested the 80 most potent compounds from the box for bilayer-mediated effects on membrane protein conformational changes (a measure of likely toxicity) in a gramicidin-based stopped flow fluorescence assay. Among the Malaria Box compounds tested, four compounds altered membrane properties (p< 0.05); MMV007384 stood out as a potent bilayer-perturbing compound that is toxic in many cell-based assays, suggesting that testing for membrane perturbation could help identify toxic compounds. In any case, MMV007384 should be approached with caution, if at all. PMID:26551613

  20. Bilayer Effects of Antimalarial Compounds

    PubMed Central

    Ramsey, Nicole B.; Andersen, Olaf S.

    2015-01-01

    Because of the perpetual development of resistance to current therapies for malaria, the Medicines for Malaria Venture developed the Malaria Box to facilitate the drug development process. We tested the 80 most potent compounds from the box for bilayer-mediated effects on membrane protein conformational changes (a measure of likely toxicity) in a gramicidin-based stopped flow fluorescence assay. Among the Malaria Box compounds tested, four compounds altered membrane properties (p< 0.05); MMV007384 stood out as a potent bilayer-perturbing compound that is toxic in many cell-based assays, suggesting that testing for membrane perturbation could help identify toxic compounds. In any case, MMV007384 should be approached with caution, if at all. PMID:26551613