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Sample records for abandoned carbonate reservoir

  1. REVIVING ABANDONED RESERVOIRS WITH HIGH-PRESSURE AIR INJECTION: APPLICATION IN A FRACTURED AND KARSTED DOLOMITE RESERVOIR

    SciTech Connect

    Robert Loucks; Steve Ruppel; Julia Gale; Jon Holder; Jon Olsen; Deanna Combs; Dhiraj Dembla; Leonel Gomez

    2003-06-01

    The Bureau of Economic Geology and Goldrus Producing Company have assembled a multidisciplinary team of geoscientists and engineers to evaluate the applicability of high-pressure air injection (HPAI) in revitalizing a nearly abandoned carbonate reservoir in the Permian Basin of West Texas. The characterization phase of the project is utilizing geoscientists and petroleum engineers from the bureau of Economic Geology and the Department of Petroleum Engineering (both at The University of Texas at Austin) to define the controls on fluid flow in the reservoir as a basis for developing a reservoir model. This model will be used to define a field deployment plant that Goldrus, a small independent oil company, will implement by drilling both vertical and horizontal wells during the demonstration phase of the project. Additional reservoir data are being gathered during the demonstration phase to improve the accuracy of the reservoir model. The results of the demonstration are being closely monitored to provide a basis for improving the design of the HPAI field deployment plan. The results of the reservoir characterization field demonstration and monitoring program will be documented and widely disseminated to facilitate adoption of this technology by oil operators in the Permian Basin and elsewhere in the US.

  2. Reviving Abandoned Reservoirs with High-Pressure Air Injection: Application in a Fractured and Karsted Dolomite Reservoir

    SciTech Connect

    Robert Loucks; Stephen C. Ruppel; Dembla Dhiraj; Julia Gale; Jon Holder; Jeff Kane; Jon Olson; John A. Jackson; Katherine G. Jackson

    2006-09-30

    Despite declining production rates, existing reservoirs in the United States contain vast volumes of remaining oil that is not being effectively recovered. This oil resource constitutes a huge target for the development and application of modern, cost-effective technologies for producing oil. Chief among the barriers to the recovery of this oil are the high costs of designing and implementing conventional advanced recovery technologies in these mature, in many cases pressure-depleted, reservoirs. An additional, increasingly significant barrier is the lack of vital technical expertise necessary for the application of these technologies. This lack of expertise is especially notable among the small operators and independents that operate many of these mature, yet oil-rich, reservoirs. We addressed these barriers to more effective oil recovery by developing, testing, applying, and documenting an innovative technology that can be used by even the smallest operator to significantly increase the flow of oil from mature U.S. reservoirs. The Bureau of Economic Geology and Goldrus Producing Company assembled a multidisciplinary team of geoscientists and engineers to evaluate the applicability of high-pressure air injection (HPAI) in revitalizing a nearly abandoned carbonate reservoir in the Permian Basin of West Texas. The Permian Basin, the largest oil-bearing basin in North America, contains more than 70 billion barrels of remaining oil in place and is an ideal venue to validate this technology. We have demonstrated the potential of HPAI for oil-recovery improvement in preliminary laboratory tests and a reservoir pilot project. To more completely test the technology, this project emphasized detailed characterization of reservoir properties, which were integrated to access the effectiveness and economics of HPAI. The characterization phase of the project utilized geoscientists and petroleum engineers from the Bureau of Economic Geology and the Department of Petroleum

  3. Carbonate petroleum reservoirs

    SciTech Connect

    Roehl, P.O.; Choquette, P.W.

    1985-01-01

    This book presents papers on the geology of petroleum deposits. Topics considered include diagenesis, porosity, dolomite reservoirs, deposition, reservoir rock, reefs, morphology, fracture-controlled production, Cenozoic reservoirs, Mesozoic reservoirs, and Paleozoic reservoirs.

  4. Tertiary carbonate reservoirs in Indonesia

    SciTech Connect

    Nayoan, G.A.S.; Arpandi; Siregar, M.

    1981-01-01

    Hydrocarbon production from Tertiary carbonate reservoirs accounted for ca. 10% of daily Indonesian production at the beginning of 1978. Environmentally, the reservoirs appear as parts of reef complexes and high-energy carbonate deposits within basinal areas situated mainly in the back arc of the archipelago. Good porosities of the reservoirs are represented by vugular/moldic and intergranular porosity types. The reservoirs are capable of producing prolific amounts of hydrocarbons: production tests in Salawati-Irian Jaya reaches maximum values of 32,000 bpd, and in Arun-North Sumatra tests recorded 200 MMCF gas/day. Significant hydrocarbon accumulations are related to good reservoir rocks in carbonates deposited as patch reefs, pinnacle reefs, and platform complexes. Exploration efforts expand continuously within carbonate formations which are extensive horizontally as well as vertically in the Tertiary stratigraphic column.

  5. REVIVING ABANDONED RESERVOIRS WITH HIGH-PRESSURE AIR INJECTION: APPLICATION IN A FRACTURED AND KARSTED DOLOMITE RESERVOIR

    SciTech Connect

    Robert Loucks; Steve Ruppel; Julia Gale; Jon Holder; Jon Olson; Deanna Combs; Dhiraj Dembla

    2004-06-01

    The Bureau of Economic Geology (BEG) and Goldrus Producing Company have assembled a multidisciplinary team of geoscientists and engineers to evaluate the applicability of high-pressure air injection (HPAI) in revitalizing a nearly abandoned carbonate reservoir in the Permian Basin of West Texas. The characterization phase of the project is utilizing geoscientists and petroleum engineers from the Bureau of Economic Geology (BEG) and the Department of Petroleum and Geosystems Engineering (both at The University of Texas at Austin) to define the controls on fluid flow in the reservoir as a basis for developing a reservoir model. This model will be used to define a field deployment plan that Goldrus, a small independent oil company, will implement by drilling both vertical and horizontal wells during the demonstration phase of the project. Additional reservoir data were to be generated during the demonstration phase to improve the accuracy of the reservoir model. The demonstration phase has been delayed by Goldrus because of funding problems. Since the first of the year, Goldrus has been active in searching for partners to help finance the project. To this end it has commissioned several small consulting studies to technically support its effort to secure a partner. After financial support is obtained, the demonstration phase of the project will proceed. Since just after the beginning of the year, BEG has curtailed project activities and spending of DOE funds except for the continued support of one engineering student. This student has now completed his work and has written a thesis describing his research (titled ''Stimulating enhanced oil recovery (EOR) by high-pressure air injection (HPAI) in west Texas light oil reservoir''). We plan to recommence our work on the project as soon as the operator obtains necessary funding to carry out the demonstration phase of the project. In order to complete all activities specified in the proposal, it will be necessary to request

  6. Functional wettability in carbonate reservoirs

    DOE PAGES

    Brady, Patrick V.; Thyne, Geoffrey

    2016-10-11

    Oil adsorbs to carbonate reservoirs indirectly through a relatively thick separating water layer, and directly to the surface through a relatively thin intervening water layer. Whereas directly sorbed oil desorbs slowly and incompletely in response to changes in reservoir conditions, indirectly sorbed oil can be rapidly desorbed by changing the chemistry of the separating water layer. The additional recovery might be as much as 30% original oil in place (OOIP) above the ~30% OOIP recovered from carbonates through reservoir depressurization (primary production) and viscous displacement (waterflooding). Electrostatic adhesive forces are the dominant control over carbonate reservoir wettability. A surface complexationmore » model that quantifies electrostatic adhesion accurately predicts oil recovery trends for carbonates. Furthermore, the approach should therefore be useful for estimating initial wettability and designing fluids that improve oil recovery.« less

  7. Functional wettability in carbonate reservoirs

    SciTech Connect

    Brady, Patrick V.; Thyne, Geoffrey

    2016-10-11

    Oil adsorbs to carbonate reservoirs indirectly through a relatively thick separating water layer, and directly to the surface through a relatively thin intervening water layer. Whereas directly sorbed oil desorbs slowly and incompletely in response to changes in reservoir conditions, indirectly sorbed oil can be rapidly desorbed by changing the chemistry of the separating water layer. The additional recovery might be as much as 30% original oil in place (OOIP) above the ~30% OOIP recovered from carbonates through reservoir depressurization (primary production) and viscous displacement (waterflooding). Electrostatic adhesive forces are the dominant control over carbonate reservoir wettability. A surface complexation model that quantifies electrostatic adhesion accurately predicts oil recovery trends for carbonates. Furthermore, the approach should therefore be useful for estimating initial wettability and designing fluids that improve oil recovery.

  8. REVIVING ABANDONED RESERVOIRS WITH HIGH-PRESSURE AIR INJECTION: APPLICATION IN A FRACTURED AND KARSTED DOLOMITE RESERVOIR

    SciTech Connect

    Robert Loucks; Steve Ruppel; Julia Gale; Jon Holder; Jon Olson

    2005-01-01

    The Bureau of Economic Geology (BEG) and Goldrus Producing Company have assembled a multidisciplinary team of geoscientists and engineers to evaluate the applicability of high-pressure air injection (HPAI) in revitalizing a nearly abandoned carbonate reservoir in the Permian Basin of West Texas. The characterization phase of the project is utilizing geoscientists and petroleum engineers from the Bureau of Economic Geology (BEG) and the Department of Petroleum and Geosystems Engineering (both at The University of Texas at Austin) to define the controls on fluid flow in the reservoir as a basis for developing a reservoir model. This model will be used to define a field deployment plan that Goldrus, a small independent oil company, will implement by drilling both vertical and horizontal wells during the demonstration phase of the project. Additional reservoir data were to be generated during the demonstration phase to improve the accuracy of the reservoir model. The demonstration phase has been delayed by Goldrus because of funding problems. Since the first of the year, Goldrus has been active in searching for partners to help finance the project. After financial support is obtained, the demonstration phase of the project will proceed. Since just after the beginning of the year, BEG has curtailed project activities and spending of DOE funds except for the continued support of one engineering student. This student has now completed his work and his thesis was reported on in the last semi-annual report. We plan to recommence our work on the project as soon as the operator obtains necessary funding to carry out the demonstration phase of the project. In order to complete all activities specified in the proposal, we requested and received an extension of the project to September 30, 2005. We are confident that Goldrus will obtain the necessary funding to continue and that we can complete the project by the end of the extension data. We strongly believe that the results of

  9. Carbon content of sediments of small reservoirs

    SciTech Connect

    Ritchie, J.C. )

    1989-04-01

    Carbon content was measured in sediments deposited in 58 small reservoirs across the US. Reservoirs varied from 0.2 to 4,000 km{sup 2} in surface area. The carbon content of sediment ranged from 0.3 to 5.6 percent, with a mean of 1.9 {plus minus} 1.1 percent. No significant differences between the soil and sediment carbon content were found using a paired t-test or ANOVA. The carbon content of sediments in reservoirs was similar to the carbon content of surface soils in the watershed, except in watersheds with shrub or steppe (desert) vegetation. Based on the sediment accumulation rates measured in each reservoir, the calculated organic carbon accumulation rates among reservoirs ranged from 26 to 3,700 gC m{sup {minus}2} yr{sup {minus}1}, with a mean of 675 {plus minus} 739 gC m{sup {minus}2} yr{sup {minus}1}. The carbon content and accumulation rates were highest in sediments from grassland watersheds. High variability was found in carbon content, carbon accumulation, and sediment accumulation rates due to individual watershed and reservoir characteristics rather than to any broad physiographic patterns. The carbon accumulation rates in these reservoir sediments indicate that reservoir sediments could be a significant sink of organic carbon.

  10. Hydrogeological definition and applicability of abandoned coal mines as water reservoirs.

    PubMed

    Ordóñez, A; Jardón, S; Álvarez, R; Andrés, C; Pendás, F

    2012-08-01

    Hydrogeologically, the Central Coal Basin (Asturias, Spain) is characterized by predominantly low-permeability materials that make up a multilayer aquifer with very low porosity and permeability values, where the sandstones act as limited aquifers, and wackes, mudstones, shales and coal seams act as confining levels. Preferential groundwater flow paths are open fractures and zones of decompression associated with them, so the hydraulic behaviour of the system is more associated with fracturing than lithology. Thus, abandoned and flooded mines in the area acquire an important role in the management of water resources, setting up an artificial "pseudo-karst" aquifer. This paper evaluates the potential application of the abandoned mines as underground reservoirs, both for water supply and energetic use, mainly through heat pumps and small hydropower plants. In particular, the groundwater reservoir shaped by the connected shafts Barredo and Figaredo has been chosen, and a detailed and multifaceted study has been undertaken in the area. The exposed applications fit with an integrated management of water resources and contribute to improve economic and social conditions of a traditional mining area in gradual decline due to the cessation of such activity.

  11. Bioaccumulation of cesium-137 in yellow bullhead catfish (Ameiurus natalis) inhabiting an abandoned nuclear reactor reservoir

    SciTech Connect

    McCreedy, C.D.; Glickman, L.T.; Jagoe, C.H.; Brisbin, I.L. Jr.

    1997-02-01

    Bioaccumulation of {sup 137}Cs was investigated in yellow bullhead catfish (Ameiurus natalis) inhabiting an abandoned reactor reservoir, Pond B, Savannah River Site, Barnwell Co., South Carolina. The authors collected fish by trap-netting, and determined ages from pectoral spines. Muscle and other tissues were assayed for {sup 137}Cs by NaI-scintillation. Music {sup 137}Cs was unrelated to sex or mass of fish, but was related to age. Examination of least-squares means suggested that {sup 137}Cs in muscle increased up to about age 3, but did not increase with greater age. A modified Richards model showed equilibrium {sup 137}Cs concentration in muscle was acquired in approximately 2.4 years. Growth differed between sexes and the time to asymptotic body mass was longer than the time to attain equilibrium {sup 137}Cs concentration. Males attained an asymptotic mass of 577 g in approximately 6.3 years; females attained an asymptotic mass of 438 g in approximately 5.9 years. The cumulative {sup 137}Cs burden of the population was 4.9 {times} 10{sup 6} Bq, representing <0.001% of the {sup 137}Cs inventory of the reservoir. Concentration of {sup 137}Cs varied among tissues with gill and muscle the lowest and highest. Concentration of {sup 137}Cs in ovaries declined with increasing ovary mass. Until equilibrium is attained in these fish, {sup 137}Cs concentration is directly related to increasing age rather than size.

  12. Carbon emission from global hydroelectric reservoirs revisited.

    PubMed

    Li, Siyue; Zhang, Quanfa

    2014-12-01

    Substantial greenhouse gas (GHG) emissions from hydropower reservoirs have been of great concerns recently, yet the significant carbon emitters of drawdown area and reservoir downstream (including spillways and turbines as well as river reaches below dams) have not been included in global carbon budget. Here, we revisit GHG emission from hydropower reservoirs by considering reservoir surface area, drawdown zone and reservoir downstream. Our estimates demonstrate around 301.3 Tg carbon dioxide (CO2)/year and 18.7 Tg methane (CH4)/year from global hydroelectric reservoirs, which are much higher than recent observations. The sum of drawdown and downstream emission, which is generally overlooked, represents 42 % CO2 and 67 % CH4 of the total emissions from hydropower reservoirs. Accordingly, the global average emissions from hydropower are estimated to be 92 g CO2/kWh and 5.7 g CH4/kWh. Nonetheless, global hydroelectricity could currently reduce approximate 2,351 Tg CO2eq/year with respect to fuel fossil plant alternative. The new findings show a substantial revision of carbon emission from the global hydropower reservoirs.

  13. Post-Soviet cropland abandonment and carbon sequestration in European Russia, Ukraine, and Belarus

    NASA Astrophysics Data System (ADS)

    Schierhorn, Florian; Müller, Daniel; Beringer, Tim; Prishchepov, Alexander V.; Kuemmerle, Tobias; Balmann, Alfons

    2013-12-01

    Widespread cropland abandonment occurred after the collapse of socialism across the former Soviet Union, but the rates and spatial patterns of abandoned lands are not well known. As a result, the potential of this region to contribute to global food production and estimates of the carbon sink developing on currently idle lands are highly uncertain. We developed a spatial allocation model that distributes yearly and subnational sown area statistics to the most agriculturally suitable plots. This approach resulted in new, high-resolution (1 km2) annual time series of cropland and abandoned lands in European Russia, Ukraine, and Belarus from 1990 to 2009. A quantitative validation of the cropland map confirms the reliability of this data set, especially for the most important agricultural areas of the study region. Overall, we found a total of 87 Mha of cropland and 31 Mha of abandoned cropland in European Russia, Ukraine, and Belarus combined, suggesting that abandonment has been severely underestimated in the past. The abandonment rates were highest in European Russia. Feeding our new map data set into the dynamic vegetation model LPJmL revealed that cropland abandonment resulted in a net carbon sink of 470 TgC for 1990 to 2009. Carbon sequestration was generally slow in the early years after abandonment, but carbon uptake increased significantly after approximately 10 years. Recultivation of older abandoned lands would be associated with high carbon emissions and lead to substantial amounts of carbon not being sequestered in vegetation formations currently developing on idle croplands. Our spatially and temporally explicit cropland abandonment data improve the estimation of trade-offs involved in reclaiming abandoned croplands and thus in increasing agricultural production in this globally important agricultural region.

  14. Quantification of geologic descriptions for reservoir characterization in carbonate reservoirs

    SciTech Connect

    Lucia, F.J.; Vander Stoep, G.W. )

    1990-05-01

    Recognition that a large volume of oil remains in carbonate reservoirs at the end of primary depletion and waterflooding has prompted the reevaluation of the reserve-growth potential of many existing carbonate reservoirs. Types of numerical data required include porosity, absolute permeability, relative permeability, fluid saturation, and capillary pressure, all of which are related to the size and distribution of pore space. Rock fabrics control the size and distribution of pore space and define facies that best characterize carbonate reservoirs. Thus, the link between facies descriptions and numerical engineering data is the relationship between pore-size distribution and present carbonate rock fabric. The most effective way to convert facies descriptions into engineering parameters is by considering three basic rock-fabric categories. The first category is interparticle pore space (both intergranular and intercrystalline pore types) with pore-size distribution controlled primarily by the size and shape of grains or crystals. Grain or crystal size is the key geologic measurement and, along with porosity, provides the basis for converting geologic descriptions into values for permeability, saturation, and capillarity. The second category is separate-vug pore space, such as moldic or intraparticle pore space. Separate-vug pore space adds porosity but little permeability to the reservoir rock. The contribution to saturation and capillarity depends upon the size of the separate-vug pore space. For example, moldic separate vugs will be saturated with oil, whereas microporous grains will be saturated with water. The third category is touching-vug pore space, which is vuggy pore space that is interconnected on a reservoir scale. The engineering parameters for this category are related to three diagenetic and tectonic factors.

  15. C02 Huff-n-Puff Process in a Light Oil Shallow Shelf Carbonate Reservoir

    SciTech Connect

    Mark Kovar; Scott Wehner

    1998-01-31

    The principal objective of this CO2 Huf-n-Puff (H-n-P) project is to determine the feasibility and practicality of the technology in a waterflooded shallow shelf carbonate environment. The results of parametric simulation of the CO2 H-n-P process, coupled with reservoir characterization components are to be used to determine if this process is technically and economically feasible for field implementation. The technology transfer objective of the project is to disseminate the knowledge gained through an innovative plan of increasing oil production and deferring abandonment of shallow shelf carbonate reservoirs.

  16. Design and Implementation of a CO2 Flood Utilizing Advanced Reservoir Characterization and Horizontal Injection Wells In a Shallow Shelf Carbonate Approaching Waterflood Depletion, Class II

    SciTech Connect

    Wier, Don R. Chimanhusky, John S.; Czirr, Kirk L.; Hallenbeck, Larry; Gerard, Matthew G.; Dollens, Kim B.; Owen, Rex; Gaddis, Maurice; Moshell, M.K.

    2002-11-18

    The purpose of this project was to economically design an optimum carbon dioxide (CO2) flood for a mature waterflood nearing its economic abandonment. The original project utilized advanced reservoir characterization and CO2 horizontal injection wells as the primary methods to redevelop the South Cowden Unit (SCU). The development plans; project implementation and reservoir management techniques were to be transferred to the public domain to assist in preventing premature abandonment of similar fields.

  17. Land abandonment, fire recurrence and soil carbon content in the Macizo del Caroig, Eastern Spain

    NASA Astrophysics Data System (ADS)

    Cerdá, A.; González Peñaloza, F.; Santín, C.; Doerr, S. H.

    2012-04-01

    During the last 50 years two main forces have driven the fate of Mediterranean landscapes: land abandonment and forest fires (MacDonald et al., 2000; Moreira et al., 2001). Due to the economical changes suffered by the of the Mediterranean countries after the Second World War, the population migrated from the rural to the urban areas, and from South to North Europe. The land abandonment allowed the vegetation to recover and, as a consequence, an increase in forest fire took place. The soils of the abandoned land recovered the vegetation and litter layers, and consequently changes in soil properties have being found. One of these changes is the increase of soil carbon content, which is due both to vegetation recovery and to fire occurrence that increases the ash and pyrogenic carbon content in soils. Twenty plots were selected in the Macizo del Caroig in Eastern Spain on soils developed on limestone. The period of abandonment and the forest fires that had affected each plot were determined by interviews with the owners, farmers and shepherds. In addition, six (three + three) plots were selected as forest (no plough) and cultivated control plots. Each plot was sampled (10 random samples) and the organic carbon content determined. The results show that the cultivated plots have organic matter contents of 1.02 %, and the forest (Quercus ilex sp.) plots reach the highest value: 14.98 %. Within those we found values that range from 2.34 %, in the recently abandoned plots (10 year abandonment), to values of 8.23 % in the 50 year old abandoned fields.The results demonstrate that there is a recovery of the organic carbon in abandoned soils and that the forest fires do no affect this trend. The increase of soil organic matter after abandonment is a result of the recovery of vegetation(Debussche et al., 2001), which is the consequence of the end of the disturbance of forest that have affected the Mediterranean for millennia (Barbero et al., 1990). The colonization of the

  18. Models for naturally fractured, carbonate reservoir simulations

    SciTech Connect

    Tuncay, K.; Park, A.; Ozkan, G.; Zhan, X.; Ortoleva, P.; Hoak, T.; Sundberg, K.

    1998-12-31

    This report outlines the need for new tools for the simulation of fractured carbonate reservoirs. Several problems are identified that call for the development of new reservoir simulation physical models and numerical techniques. These include: karst and vuggy media wherein Darcy`s and traditional multi-phase flow laws do not apply; the need for predicting the preproduction state of fracturing and stress so that the later response of effective stress-dependent reservoirs can be predicted; and methods for predicting the fracturing and collapse of vuggy and karst reservoirs in response to draw-down pressure created during production. Specific research directions for addressing each problem are outlined and preliminary results are noted.

  19. Fate of Organic Carbon Deposited in Reservoirs

    NASA Astrophysics Data System (ADS)

    Huntington, T. G.; Rhoton, F. E.; Bennett, S. J.; Hudnall, W. H.

    2002-05-01

    Sedimentation of soil organic carbon (SOC) eroded from uplands and deposited in reservoirs could be an important mechanism for carbon sequestration provided that it is conserved during transport and burial and that uplands are not experiencing net loss. There are uncertainties in both these assumptions and gaining a better understanding of these processes is a key objective of ongoing carbon-cycle investigations. The U.S. Geological Survey, the U. S. Department of Agriculture, and Louisiana State University Agricultural Center are collaborating on an investigation of soils and sediments in the Yalobusha River Basin in Mississippi. Sediment cores were collected from upland soils and from Grenada Lake, a flood control reservoir, in the basin. Suspended sediments have been collected from the Yalobusha River and one of its tributaries upstream of the lake. We are measuring carbon mineralization potential in conjunction with carbon and nitrogen concentrations, 13C, mineralogy, and texture on sediments and upland soils to determine whether eroding SOC is conserved or oxidized during transport and burial. Differences in mineralization potential and other chemical and physical properties are used to infer net changes in the original eroding SOC. Autochthonous production of SOC within reservoirs could replace labile SOC oxidized during transport and burial thereby masking losses due to oxidation. Autochthonous sources can be evaluated by chemical and physical characterization of the sediments. Stable carbon isotope (13C) geochemistry provides a tool for distinguishing the two primary sources of organic carbon incorporated in lake sediments because allochthonous SOC from the surrounding watershed is, in general, less depleted in stable 13C than autochthonous SOC produced in the lake by aquatic organisms such as macrophytes and phytoplankton. The integration of the 13C signature recorded in the organic fraction of the lake sediments with total organic carbon, C/N ratio

  20. Post-Soviet farmland abandonment, forest recovery, and carbon storage potential in Ukraine

    NASA Astrophysics Data System (ADS)

    Olofsson, P.; Kuemmerle, T.; Baumann, M.; Radeloff, V. C.; Woodcock, C. E.; Hostert, P.

    2010-12-01

    Land use is a critical factor in the global carbon cycle, but land use effects on carbon fluxes are poorly understood in many regions. One such region is the former Eastern Bloc, where land use intensity decreased substantially after the collapse of the Soviet Union, resulting in widespread farmland abandonment and forest regrowth. The aim of this study was to examine how land use trends altered net carbon fluxes in Western Ukraine (57,000 km2) for the communist (1945-1991) and the post-communist period (1991-2007), and to assess the regions’ future carbon sequestration potential. Forest disturbance and farmland abandonment between 1988 to 2007 was estimated from Landsat imagery in former study. Historical land use change rates were obtained from forest inventories to reconstruct forest trends back to the mid-1800s. Using a carbon book-keeping model, we quantified net carbon fluxes from land use change and assessed potential future carbon fluxes for a range of reforestation and logging scenarios. Our results suggest that the low-point in forest cover occurred in the 1920s. Forest expansion in the second half of the 20th century turned the region from a carbon source to a sink, despite heavy logging during Soviet times. The current land-use related sink strength is about 1.5 Tg of carbon per year. Sequestration potential on abandoned farmland is enormous, even when assuming that only a minor fraction of the currently abandoned land will revert to forests. Beyond our study area, farmland abandonment has been widespread throughout Eastern Europe and the former Soviet Union, suggesting that a substantial proportion of the regions’ industrial carbon emissions may be offset by reforesting farmland.

  1. Agricultural land abandonment in Mediterranean environment provides ecosystem services via soil carbon sequestration.

    PubMed

    Novara, Agata; Gristina, Luciano; Sala, Giovanna; Galati, Antonino; Crescimanno, Maria; Cerdà, Artemi; Badalamenti, Emilio; La Mantia, Tommaso

    2017-01-15

    Abandonment of agricultural land leads to several consequences for ecosystem functions. Agricultural abandonment may be a significant and low cost strategy for carbon sequestration and mitigation of anthropogenic CO2 emissions due to the vegetation recovery and increase in soil organic matter. The aim of this study was to: (i) estimate the influence of different Soil Regions (areas characterized by a typical climate and parent material association) and Bioclimates (zones with homogeneous climatic regions and thermotype indices) on soil organic carbon (SOC) dynamics after agricultural land abandonment; and (ii) to analyse the efficiency of the agri-environment policy (agri-environment measures) suggested by the European Commission in relation to potential SOC stock ability in the Sicilian Region (Italy). In order to quantify the effects of agricultural abandonment on SOC, a dataset with original data that was sampled in Sicily and existing data from the literature were analysed according to the IPCC (Intergovernmental Panel on Climate Change) methodology. Results showed that abandonment of cropland soils increased SOC stock by 9.03MgCha(-1) on average, ranging from 5.4MgCha(-1) to 26.7MgCha(-1) in relation to the Soil Region and Bioclimate. The estimation of SOC change after agricultural use permitted calculation of the payments for ecosystem service (PES) of C sequestration after agricultural land abandonment in relation to environmental benefits, increasing in this way the efficiency of PES. Considering the 14,337ha of abandoned lands in Sicily, the CO2 emission as a whole was reduced by 887,745Mg CO2. Therefore, it could be concluded that abandoned agricultural fields represents a valid opportunity to mitigate agriculture sector emissions in Sicily.

  2. Microbial enhancement of oil production from carbonate reservoirs

    SciTech Connect

    Tanner, R.S.; Knapp, R.M.; McInerney, M.J.; Udegbunam, E.O.

    1991-01-01

    The goal of this work is to evaluate the potential for Microbial Enhanced Oil Recovery (MEOR) in carbonate reservoirs. Specific objectives include: review of the literature pertinent to MEOR in carbonate reservoirs, a study of the microbial ecology of carbonate reservoirs, isolation of microorganisms and their end-products of metabolism on carbonate pore structure, the recovery of residual oil from carbonates in model core systems, and development of models to examine and predict MEOR processes in carbonate reservoirs. 1 ref., 3 figs., 1 tab.

  3. Advances in carbonate exploration and reservoir analysis

    USGS Publications Warehouse

    Garland, J.; Neilson, J.; Laubach, S.E.; Whidden, Katherine J.

    2012-01-01

    The development of innovative techniques and concepts, and the emergence of new plays in carbonate rocks are creating a resurgence of oil and gas discoveries worldwide. The maturity of a basin and the application of exploration concepts have a fundamental influence on exploration strategies. Exploration success often occurs in underexplored basins by applying existing established geological concepts. This approach is commonly undertaken when new basins ‘open up’ owing to previous political upheavals. The strategy of using new techniques in a proven mature area is particularly appropriate when dealing with unconventional resources (heavy oil, bitumen, stranded gas), while the application of new play concepts (such as lacustrine carbonates) to new areas (i.e. ultra-deep South Atlantic basins) epitomizes frontier exploration. Many low-matrix-porosity hydrocarbon reservoirs are productive because permeability is controlled by fractures and faults. Understanding basic fracture properties is critical in reducing geological risk and therefore reducing well costs and increasing well recovery. The advent of resource plays in carbonate rocks, and the long-standing recognition of naturally fractured carbonate reservoirs means that new fracture and fault analysis and prediction techniques and concepts are essential.

  4. Litter contribution to soil organic carbon in the agriculture abandons processes

    NASA Astrophysics Data System (ADS)

    Novara, A.; Rühl, J.; La Mantia, T.; Gristina, L.; La Bella, S.; Tuttolomondo, T.

    2015-02-01

    Mechanisms of litter decomposition, translocation and stabilization into soil layers are fundamental processes in ecosystem functioning as it regulates the cycle of soil organic matter (SOM), CO2 emission into the atmosphere, carbon sequestration into the soil. In this study, it was investigated the contribution of litters of different stages of Mediterranean secondary succession on Carbon sequestration, analyzing the role of earthworms on translocation of SOM into soil profile. For this purpose δ13C difference between meadow C4-Csoil and C3-Clitter were used in a field experiment. Four undisturbed litters of different stages of succession were collected (45, 70, 100 and 120 since agriculture abandon) and placed on the top of isolated soil cores. The litter contribution to C stock was affected by plant species and increased with the age of the stage of secondary succession. The soil organic carbon after 1 year since litter position increased up to 40% in comparison to no litter treatment in soil with litter of 120 years since abandon. The new carbon derived from C3-litter was decomposed and transferred into soil profile thanks to earthworms and dissolved organic carbon leaching. After 1 years the carbon increase attributed to earthworm activity ranged from 6 to 13% in soil under litter in field abandoned since 120 and 45 years, respectively.

  5. Litter contribution to soil organic carbon in the agriculture abandons processes

    NASA Astrophysics Data System (ADS)

    Novara, Agata; Francaviglia, Dario; La Mantia, tommaso; Gristina, Luciano; La Bella, Salvatore; Tuttolomondo, Teresa

    2015-04-01

    Mechanisms of litter decomposition, translocation and stabilization into soil layers are fundamental processes in ecosystem functioning as it regulates the cycle of soil organic matter (SOM), CO2 emission into the atmosphere, carbon sequestration into the soil. In this study, it was investigated the contribution of litters of different stages of Mediterranean secondary succession on Carbon sequestration, analyzing the role of earthworms on translocation of SOM into soil profile. For this purpose δ13C difference between meadow C4-C soil and C3-C litter were used in a field experiment. Four undisturbed litters of different stages of succession were collected (45, 70, 100 and 120 since agriculture abandon) and placed on the top of isolated soil cores. The litter contribution to C stock was affected by plant species and increased with the age of the stage of secondary succession. The soil organic carbon after 1 year since litter position increased up to 40% in comparison to no litter treatment in soil with litter of 120 years since abandon. The new carbon derived from C3-litter was decomposed and transferred into soil profile thanks to earthworms and dissolved organic carbon leaching. After 1 years the carbon increase attributed to earthworm activity ranged from 6% to 13% in soil under litter in field abandoned since 120 and 45 years, respectively.

  6. Soil, vegetation and total organic carbon stock development in self-restoring abandoned vineyards

    NASA Astrophysics Data System (ADS)

    József Novák, Tibor; Incze, József; Spohn, Marie; Giani, Luise

    2016-04-01

    Abandoned vineyard's soil and vegetation development was studied on Tokaj Nagy-Hill, which is one of the traditional wine-producing regions of Hungary, it is declared as UNESCO World Heritage site as cultural landscape. Spatial distribution and pattern of vineyards were changing during the last several hundreds of years, therefore significant part of abandoned vineyards were subjected to long-term spontaneous secondary succession of vegetation and self-restoration of soils in absence of later cultivation. Two chronosequences of spontaneously regenerating vineyard abandonments, one on south (S-sequence) and one on southwest (SW-sequence) slope with differing times since their abandonment (193, 142, 101, 63, 39 and 14 years), were compiled and studied. The S-sequence was 25-35% sloped and strongly eroded, and the SW-sequence was 17-25% sloped and moderately eroded. The sites were investigated in respect of vegetation characteristics, soil physico-chemical characteristics, total organic carbon stocks (TOC stocks), accumulation rates of total organic carbon (TOC accumulation rates), and soil profiles, which were classified according to the World Reference Base (WRB) 2014. Vegetation development resulted in shrub-grassland mosaics, supplemented frequently by protected forb species and forest development at the earliest abandonment in S-sequence, and predominantly to forest vegetation in SW-sequence, where trees were only absent at the 63 and 14 years old abandonment sites. In all sites soils on level of reference groups according to WRB were classified, and Cambisols, Regosols, Calcisols, Leptosols, Chernozems and Phaeozems were found. Soils of the S-sequence show shallow remnants of loess cover with colluvic and redeposited soil materials containing 15-65% skeletal volcanic rock of weathering products coated by secondary calcium carbonates. The SW-sequence profiles are developed on deep loess or loess derivatives. The calcium-carbonate content was higher in profiles of

  7. Litter contribution to soil organic carbon in the processes of agriculture abandon

    NASA Astrophysics Data System (ADS)

    Novara, A.; Rühl, J.; La Mantia, T.; Gristina, L.; La Bella, S.; Tuttolomondo, T.

    2015-04-01

    The mechanisms of litter decomposition, translocation and stabilization into soil layers are fundamental processes in the functioning of the ecosystem, as they regulate the cycle of soil organic matter (SOM) and CO2 emission into the atmosphere. In this study the contribution of litters of different stages of Mediterranean secondary succession on carbon sequestration was investigated, analyzing the role of earthworms in the translocation of SOM into the soil profile. For this purpose the δ13C difference between meadow C4-C soil and C3-C litter was used in a field experiment. Four undisturbed litters of different stages of succession (45, 70, 100 and 120 since agriculture abandon) were collected and placed on the top of isolated C4 soil cores. The litter contribution to C stock was affected by plant species and it increased with the age of the stage of secondary succession. One year after the litter position, the soil organic carbon increased up to 40% in comparison to soils not treated with litter after 120 years of abandon. The new carbon derived from C3 litter was decomposed and transferred into soil profile thanks to earthworms and the leaching of dissolved organic carbon. After 1 year the carbon increase attributed to earthworm activity was 6 and 13% in the soils under litter of fields abandoned for 120 and 45 years, respectively.

  8. Diagenetic capping of carbonate reservoir facies

    SciTech Connect

    Lighty, R.G.

    1984-04-01

    The diagenetic model proposed involves the effect of submarine cementation on previously lithified carbonates, such as submerged relict shelf-margin buildups (e.g., drowned reefs, ooid shoals) or previously subaerially exposed formations (e.g., dune ridges) that were submerged by later sea level rise. These deposits generally have pronounced topographic relief (visible on seismic), good reservoir geometries, and high internal porosity of either primary or secondary origin. Petrologic studies on examples of both of these situations, a submerged early Holocene barrier reef off Florida and a 175-km (110-m) long submerged Pleistocene eolian ridge in the Bahamas, show that their exposed surface and uppermost facies (0.1 m, or 0.3 ft, below top) are further infilled and cemented, creating an extensively lithified, low porosity/low permeability zone or diagenetic cap rock. Quantitative mineralogic studies of occluding cements reveal an exponential reduction in porosity while moving upward into the seal zone. Submarine cements effectively infill and form a surficial permeability barrier that acts to impede further diagenesis and porosity reduction within underlying potential reservoir facies. To form this diagenetic seal only requires that the original carbonate buildup be resubmerged for some brief period of time prior to subsequent burial by sediments. If buildup accumulation later resumes without intermediate sediment burial, a common stratigraphic situation, the diagenetic seal would represent a disconformity separating two similar facies. The early formation of a diagenetic cap rock lends support to models of early hydrocarbon migration and emplacement. Prediction and recognition of submarine diagenetic seals will aid in exploration and development of obvious buildup reservoirs as well as subtle intraformational traps.

  9. REVIVING ABANDONED RESERVOIRS WITH HIGH-PRESSURE AIR INJECTION: APPLICATION IN A FRACTURED AND KARSTED DOLOMITE RESERVOIR

    SciTech Connect

    Robert Loucks; Stephen C. Ruppel

    2006-02-01

    The field operator, Goldrus Producing Company, has been unable to secure funding needed to continue the field demonstration phase of the project. Accordingly, we have temporarily halted all project activities until necessary funding is obtained. Goldrus felt confident that funds could be acquired by third quarter 2005 at which time it would have been necessary to request a project extension to complete the originally designed study. A project extension was granted but it appears Goldrus will have difficulty securing funds. We Bureau of Economic Geology are investigating a new approach on how to fulfill our initial objectives of promoting high-pressure air injection of Ellenburger reservoirs.

  10. C02 Huff-n-Puff Process in a Light Oil shallow Shelf Carbonate Reservoir

    SciTech Connect

    Kovar, Mark; Wehner, Scott

    1997-06-30

    The principal objective of this CO2 Huff-n-Puff (H-n-P) project is to determine the feasibility and practicality of the technology in a waterflooded shallow shelf carbonate environment. The results of parametric simulation of the CO2 H-n-P process, coupled with the Central Vacuum Unit (CVU) reservoir characterization components will be used to determine if this process is technically and economically feasible for field implementation. The technology transfer objective of the project is to disseminate the knowledge gained through an innovative plan in support of the Department of Energy's (DOE) objective of increasing domestic oil production and deferring the abandonment of shallow shelf carbonate (SSC) reservoirs. Tasks associated with this objective are carried out in what is considered a timely effort for near-term goals.

  11. How do soil properties and soil carbon stocks change after land abandonment in Mediterranean mountain areas?

    NASA Astrophysics Data System (ADS)

    Nadal Romero, Estela; Cammeraat, Erik; Pérez Cardiel, Estela; Lasanta, Teodoro

    2016-04-01

    Land abandonment and subsequent revegetation processes (due to secondary succession and afforestation practices) are global issues with important implications in Mediterranean mountain areas. Moreover, the effects of land use changes on soil carbon stocks are a matter of concern stated in international policy agendas on the mitigation of greenhouse emissions, and afforestation practices are increasingly viewed as an environmental restorative land use change prescription and are considered one of the most efficient carbon sequestration strategies currently available. The MED-AFFOREST project aims to gain more insight into the discussion by exploring the following central research questions: (i) what is the impact of land abandonment on soil properties? and (ii) how do soil organic carbon change after land abandonment? The main objective of this study is to assess the effects of land abandonment, land use change and afforestation practices on soil properties and soil organic carbon (SOC) dynamics. For this aim, five different land covers (bare soil, meadows, secondary succession, Pinus sylvestris (PS) and Pinus nigra (PN) afforestation), in the Central Spanish Pyrenees were analysed. Results showed that changes in soil properties after land abandonment were limited, even if afforestation practices were carried out and no differences were observed between natural succession and afforestation. The results on SOC dynamics showed that: (i) SOC contents were higher in the PN sites in the topsoil (10 cm), (ii) when all the profile was considered no significant differences were observed between meadows and PN, (iii) SOC accumulation under secondary succession is a slow process, and (iv) meadows should also be considered due to the relative importance in SOC stocks. The first step of SOC stabilization after afforestation is the formation of macro-aggregates promoted by large inputs of SOC, with a high contribution of labile organic matter. However, our respiration

  12. Pennsylvanian carbonate buildups, Paradox basin: Increasing reserves in heterogeneous, shallow-shelf reservoirs

    USGS Publications Warehouse

    Montgomery, S.L.; Chidsey, T.C.; Eby, D.E.; Lorenz, D.M.; Culham, W.E.

    1999-01-01

    Productive carbonate buildups of Pennsylvanian age in the southern Paradox basin, Utah, contain up to 200 million bbl remaining oil potentially recoverable by enhanced recovery methods. These buildups comprise over 100 satellite fields to the giant Greater Aneth field, where secondary recovery operations thus far have been concentrated. Several types of satellite buildups exist and produce oil from the Desert Creek zone of the Paradox Formation. Many of the relevant fields have undergone early abandonment; wells in Desert Creek carbonate mounds commonly produce at very high initial rates (>1000 bbl/day) and then suffer precipitous declines. An important new study focused on the detailed characterization of five separate reservoirs has resulted in significant information relevant to their future redevelopment. Completed assessment of Anasazi field suggests that phylloid algal mounds, the major productive buildup type in this area, consist of ten separate lithotypes and can be described in terms of a two-level reservoir system with an underlying high-permeability mound-core interval overlain by a lower permeability but volumetrically larger supramound (mound capping) interval. Reservoir simulations and related performance predictions indicate that CO2 flooding of these reservoirs should have considerable success in recovering remaining oil reserves.Productive carbonate buildups of Pennsylvanian age in the southern Paradox basin, Utah, contain up to 200 million bbl remaining oil potentially recoverable by enhanced recovery methods. These buildups comprise over 100 satellite fields to the giant Greater Aneth field, where secondary recovery operations thus far have been concentrated. Several types of satellite buildups exist and produce oil from the Desert Creek zone of the Paradox Formation. Many of the relevant fields have undergone early abandonment; wells in Desert Creek carbonate mounds commonly produce at very high initial rates (>1000 bbl/day) and then suffer

  13. Quantification of functional soil organic carbon pools in a chronosequence of land abandonment in southern Spain.

    NASA Astrophysics Data System (ADS)

    Trigalet, Sylvain; Gabarrón-Galeote, Miguel A.; Van Oost, Kristof; van Wesemael, Bas

    2015-04-01

    Land abandonment is the dominant land use change in the Mediterranean, and determines the soil organic carbon (SOC) as the vegetation recovers during secondary succession. The rate of SOC recovery is influenced by environmental factors such as precipitation, soil properties or other local factors. Using aerial photographs taken in 1956, 1977, 1984, 1998, 2001 and 2009, a chronosequence of crop land abandonment was designed and topsoil samples were taken at each stage of recovery in a region North of Málaga. As SOC is a mixture of functional pools, it is important to isolate organic carbon with distinct functional properties to better understand the overall dynamic over decades. Using fractionation scheme introduced by Zimmermann et al. (2007), five fractions were isolated based on particle size, density and resistance: particulate organic matter (POM), dissolved organic carbon (DOC), SOC linked to silt and clay (s & c), SOC attached to sand particles or occluded in aggregates (S+A) and a chemically resistant fraction obtained by NaOCl oxidation (rSOC). Although there were no significant changes in particle-size distribution between the recovery stages (except for the croplands), there was a significant increase of S+A fraction over time (16 to 38%) at the expense of the s & c fraction (84 to 58%), indicating aggregation processes. Carbon concentrations within fractions S+A or rSOC did not change over time. Rather, carbon associated with silt and clay particles (s &c) was significantly affected after a few decades of abandonment. It increased from 5.7 gC.kg-1 in croplands to 10.3 gC.kg-1 in semi-natural plots. The chronosequence showed that carbon can be stored in more stable fractions. Taking into account active carbon (DOC + POM) and intermediate carbon (s & c, S+A) as indicators for carbon dynamics, we showed that the proportion of active carbon increased from 11% to 34% within the chronosequence. On the other hand, the proportion of slow cycling carbon

  14. Soil organic carbon accumulation in afforested/abandoned arable fields in Taiwan

    NASA Astrophysics Data System (ADS)

    Lin, Yi-Han; Cheng, Chih-Hsin; Huang, Yu-Hsuan

    2016-04-01

    Afforestation or abandonment of arable fields has been proposed as a way to increase terrestrial carbon storage and mitigate anthropogenic carbon emissions. When the arable fields are afforested or abandoned, the accumulation in soil organic carbon (SOC) is a key pool to sequestrate carbon. However, high uncertainties still exist in the tropics and subtropics because of fast SOC turnover rates and variable land use managements in these areas. In this study, a total of eleven sites with afforested/abandoned age over 15 years and elevation ranging from 16 to 2,056 m were investigated. We examined the increments of SOC by comparing with the adjacent tilled (e.g. croplands) and non-tilled (e.g. tea plantation or orchards) fields in two sampling layers, 0 - 10 and 10 - 20 cm in depth. In addition, density fractionation of SOC was also conducted in order to differentiate SOC into light fraction, intra-aggregate fraction, and heavy fraction to gain more information about the mechanism of SOC sequestration. Our results indicated that the increments of SOC concentration and stock varied with elevation, land use management, and soil depth. For the sites with elevation below 500 m, the SOC concentration and stock in the abandoned fields were 14.3 ± 0.9 mg C g-1 and 14.6 ± 4.6 Mg C ha-1 higher than the adjacent tilled fields, and 10.2 ± 6.3 mg C g-1and 6.4 ± 6.2 Mg C ha-1 higher than the adjacent non-tilled fields for surface 0-10 cm. For the sites with elevation above 500 m, the SOC concentration in the abandoned arable fields were 22.8 ± 12.8 mg C g-1 higher than the adjacent tilled fields, but the SOC stock might not be different due to high stone content in abandoned field. Moreover, the SOC concentration and stock in abandoned field were not different or even less than non-tilled fields where organic amendments were frequently applied. The increments of SOC for 10-20 cm soils were less evident than those for surface 0-10 cm soils, and the differences were only

  15. [Effects of land use and abandonment on soil labile organic carbon in the Karst region of southwest China].

    PubMed

    Liao, Hong-Kai; Li, Juan; Long, Jian; Zhang, Wen-Juan; Liu, Ling-Fei

    2014-01-01

    Effects of land use and land abandonment on labile organic carbon (LOC) in whole soils and different aggregate sizes were studied by sampling analysis of the soils in some typical land uses of the Karst region, southwest China. Results showed that the content and degree of dispersion of labile organic carbon decreased with soil depth, and the content of LOC was highly significant (P < 0.01) in 0-10 cm than in 10-20 cm and 20-30 cm. In the 0-10 cm soil layer, the content of LOC distribution in different aggregates was higher in the < 0.25 mm size, while no obvious changes of LOC among aggregates were found in the 10-20 cm and 20-30 cm depths. In different land use patterns, the LOC was the highest in paddy whether in whole soils or aggregates, followed by shrub, and the lowest in abandoned 3 years grassland. Within-between principal component analysis showed that the accumulation characters between land use and LOC were in the order of paddy > shrub > abandoned 15 years grassland = dry land > abandoned 3 years grassland, the content of LOC increased by 20.3% as compared to dryland, and had reached 80% of the content of shrub in abandoned 15 years grassland at the 0-10 cm depth, indicating that at the early stage of land abandonment, the natural recovery of carbon is relatively slow, while with the abandonment time increase, the carbon sink effect gradually appear.

  16. Reservoirs as hotspots of fluvial carbon cycling in peatland catchments.

    PubMed

    Stimson, A G; Allott, T E H; Boult, S; Evans, M G

    2017-02-15

    Inland water bodies are recognised as dynamic sites of carbon processing, and lakes and reservoirs draining peatland soils are particularly important, due to the potential for high carbon inputs combined with long water residence times. A carbon budget is presented here for a water supply reservoir (catchment area~9km(2)) draining an area of heavily eroded upland peat in the South Pennines, UK. It encompasses a two year dataset and quantifies reservoir dissolved organic carbon (DOC), particulate organic carbon (POC) and aqueous carbon dioxide (CO2(aq)) inputs and outputs. The budget shows the reservoir to be a hotspot of fluvial carbon cycling, as with high levels of POC influx it acts as a net sink of fluvial carbon and has the potential for significant gaseous carbon export. The reservoir alternates between acting as a producer and consumer of DOC (a pattern linked to rainfall and temperature) which provides evidence for transformations between different carbon species. In particular, the budget data accompanied by (14)C (radiocarbon) analyses provide evidence that POC-DOC transformations are a key process, occurring at rates which could represent at least ~10% of the fluvial carbon sink. To enable informed catchment management further research is needed to produce carbon cycle models more applicable to these environments, and on the implications of high POC levels for DOC composition.

  17. Stratigraphy of Carbon Preservation in Reservoir Sediments, Elwha River, Washington

    NASA Astrophysics Data System (ADS)

    Stratton, L. E.; Wing, S.; Ritchie, A.; Grant, G.

    2015-12-01

    Dam removal revealed the facies architecture and distribution of detrital carbon in the sediments of two former large reservoirs, providing an unparalleled opportunity to develop a stratigraphic framework for understanding processing and storage of organic carbon in reservoir sediments. Incision following the 2011-2014 removal of Elwha (34 m high; Lake Aldwell reservoir) and Glines Canyon (64 m; Lake Mills reservoir) Dams on the Elwha River in Washington State exposed 85+ years accumulation of reservoir sediment in cross section, creating the first known opportunity to characterize post-impoundment sediments of a large reservoir in situ. In Lake Mills, the upstream reservoir, the Elwha River deposited an estimated 1.56x106 m3 sediment primarily in a steep-fronted, Gilbert-style delta, while deposition in downstream Lake Aldwell comprised only ~3.0x106 m3 sediment, deposited broadly in an elongate, low-angle delta. Allochthonous carbon is primarily preserved in delta foresets and complexly-bedded prodelta sands, with secondary lenses of coarse-grained organics deposited as channel-lag in migrating topset channels. Organic units tend to be coarse-grained, open-framework lenses and beds consisting of well-preserved branches, cones, and needles in the topset and foreset beds, while prodelta sands consist of well-sorted, well-preserved needles and leaves associated with fine sands and silts. Compared to Lake Mills, Lake Aldwell's delta deposits are lower angle and have finer, more organic-rich topset beds. Lacustrine beds in the main body of the reservoir are dominated by mineral sediments. Taking the average total organic carbon (TOC) content and geometry of individual facies provides a first-order estimate of the total organic carbon load in the reservoir sediments, and provides insight into the spatial variability of carbon deposition, a key challenge in understanding the carbon footprint of large water reservoirs.

  18. How do soil organic carbon stocks change after cropland abandonment in Mediterranean humid mountain areas?

    PubMed

    Nadal-Romero, E; Cammeraat, E; Pérez-Cardiel, E; Lasanta, T

    2016-10-01

    The effects of land use changes on soil carbon stocks are a matter of concern stated in international policy agendas on the mitigation of greenhouse emissions. Afforestation is increasingly viewed as an environmental restorative land use change prescription and is considered one of the most efficient carbon sequestration strategies currently available. Given the large quantity of CO2 that soils release annually, it is important to understand disturbances in vegetation and soil resulting from land use changes. The main objective of this study is to assess the effects of land abandonment, land use change and afforestation practices on soil organic carbon (SOC) dynamics. For this aim, five different land covers (bare soil, permanent pastureland, secondary succession, Pinus sylvestris (PS) and Pinus nigra (PN) afforestation), in the Central Spanish Pyrenees, were analysed. SOC dynamics have been studied in the bulk soil, and in the fractions separated according to two methodologies: (i) aggregate size distribution, and (ii) density fractionation, and rates of carbon mineralization have been determined by measuring CO2 evolution using an automated respirometer. The results showed that: (i) SOC contents were higher in the PN sites in the topsoil (10cm), (ii) when all the profiles were considered no significant differences were observed between pastureland and PN, (iii) SOC accumulation under secondary succession is a slow process, and (iv) pastureland should also be considered due to the relative importance in SOC stocks. The first step of SOC stabilization after afforestation is the formation of macro-aggregates promoted by large inputs of SOC, with a high contribution of labile organic matter. However, our respiration experiments did not show evidence of SOC stabilization. SOC mineralization was higher in the top layers and values decreased with depth. These results gain insights into which type of land management is most appropriate after land abandonment for SOC.

  19. Soil carbon sequestration due to post-Soviet cropland abandonment: estimates from a large-scale soil organic carbon field inventory.

    PubMed

    Wertebach, Tim-Martin; Hölzel, Norbert; Kämpf, Immo; Yurtaev, Andrey; Tupitsin, Sergey; Kiehl, Kathrin; Kamp, Johannes; Kleinebecker, Till

    2017-02-04

    The break-up of the Soviet Union in 1991 triggered cropland abandonment on a continental scale, which in turn led to carbon accumulation on abandoned land across Eurasia. Previous studies have estimated carbon accumulation rates across Russia based on large-scale modelling. Studies that assess carbon sequestration on abandoned land based on robust field sampling are rare. We investigated soil organic carbon (SOC) stocks using a randomized sampling design along a climatic gradient from forest steppe to Sub-Taiga in Western Siberia (Tyumen Province). In total, SOC contents were sampled on 470 plots across different soil and land-use types. The effect of land use on changes in SOC stock was evaluated, and carbon sequestration rates were calculated for different age stages of abandoned cropland. While land-use type had an effect on carbon accumulation in the topsoil (0-5 cm), no independent land-use effects were found for deeper SOC stocks. Topsoil carbon stocks of grasslands and forests were significantly higher than those of soils managed for crops and under abandoned cropland. SOC increased significantly with time since abandonment. The average carbon sequestration rate for soils of abandoned cropland was 0.66 Mg C ha(-1)  yr(-1) (1-20 years old, 0-5 cm soil depth), which is at the lower end of published estimates for Russia and Siberia. There was a tendency towards SOC saturation on abandoned land as sequestration rates were much higher for recently abandoned (1-10 years old, 1.04 Mg C ha(-1)  yr(-1) ) compared to earlier abandoned crop fields (11-20 years old, 0.26 Mg C ha(-1)  yr(-1) ). Our study confirms the global significance of abandoned cropland in Russia for carbon sequestration. Our findings also suggest that robust regional surveys based on a large number of samples advance model-based continent-wide SOC prediction.

  20. Estimation of Carbon Dioxide Storage Capacity for Depleted Gas Reservoirs

    NASA Astrophysics Data System (ADS)

    Lai, Yen Ting; Shen, Chien-Hao; Tseng, Chi-Chung; Fan, Chen-Hui; Hsieh, Bieng-Zih

    2015-04-01

    A depleted gas reservoir is one of the best options for CO2 storage for many reasons. First of all, the storage safety or the caprock integrity has been proven because the natural gas was trapped in the formation for a very long period of time. Also the formation properties and fluid flow characteristics for the reservoir have been well studied since the discovery of the gas reservoir. Finally the surface constructions and facilities are very useful and relatively easy to convert for the use of CO2 storage. The purpose of this study was to apply an analytical approach to estimate CO2 storage capacity in a depleted gas reservoir. The analytical method we used is the material balance equation (MBE), which have been widely used in natural gas storage. We proposed a modified MBE for CO2 storage in a depleted gas reservoir by introducing the z-factors of gas, CO2 and the mixture of the two. The MBE can be derived to a linear relationship between the ratio of pressure to gas z-factor (p/z) and the cumulative term (Gp-Ginj, where Gp is the cumulative gas production and Ginj is the cumulative CO2 injection). The CO2 storage capacity can be calculated when constraints of reservoir recovery pressure are adopted. The numerical simulation was also used for the validation of the theoretical estimation of CO2 storage capacity from the MBE. We found that the quantity of CO2 stored is more than that of gas produced when the reservoir pressure is recovered from the abandon pressure to the initial pressure. This result was basically from the fact that the gas- CO2 mixture z-factors are lower than the natural gas z-factors in reservoir conditions. We also established a useful p/z plot to easily observe the pressure behavior of CO2 storage and efficiently calculate the CO2 storage capacity. The application of the MBE we proposed was demonstrated by a case study of a depleted gas reservoir in northwestern Taiwan. The estimated CO2 storage capacities from conducting reservoir simulation

  1. Effect of land abandonment on soil organic carbon fractions along a precipitation gradient in Mediterranean conditions

    NASA Astrophysics Data System (ADS)

    Gabarron-Galeote, Miguel A.; Trigalet, Sylvain; van Wesemael, Bas

    2015-04-01

    Land abandonment has been the main land use change in rural European Mediterranean areas over the last decades. The secondary succession process following land abandonment is strongly affected by precipitation, which in consequence determines the parallel change of soil organic carbon (SOC) and other soil properties. SOC is usually assumed to increase due to the intensification of plant residues inputs to soil, above as well below ground. However, SOC is composed of different fractions with contrasting resistance to decomposition that can have different responses to land abandonment. The objectives of this study are: i) to determine the net effect of land abandonment on the different soil organic carbon fractions; ii) to assess the relation between vegetation evolution and SOC fractions; iii) to establish the conditions with the greater potential to store stable SOC along a precipitation gradient. Three field sites with contrasting annual precipitation (GAU: 1080.5 mm yr-1- ALM: 650 mm yr-1- GER: 350 mm yr-1) were selected. On each site Fields abandoned in different periods, as verified on aerial photographs taken in 1956, 1977, 1984, 1998, 2001, 2004 and 2009, were selected using a chronosequence approach. The fractionation protocol implemented was based on the separation of different soil particle sizes, which are associated to SOC pools with different degree of stability. Samples of the first 10 cm of soil were added to a sodium-hexametaphosphate (HMP) solution (40 g L-1) and shaken horizontally for 1h (150 r.p.m.). The soil solution was then sieved consecutively through two meshes of 250 µm and 50 µm, obtaining the following fractions: i) >250 µm (coarse fraction), it contains coarse particles (coarse sand) and plant residues (particulate organic matter, POM), easily decomposable, that constitute the more labile SOC pool; ii) 50 - 250 µm (mid fraction), it contains fine sand, fine POM easily decomposable and stable microaggregates, that contains SOC

  2. Dynamics of soil organic carbon and nitrogen following agricultural abandonment in a karst region

    NASA Astrophysics Data System (ADS)

    Li, Dejun; Wen, Li; Yang, Liqiong; Luo, Pan; Xiao, Kongcao; Chen, Hao; Zhang, Wei; He, Xunyang; Chen, Hongsong; Wang, Kelin

    2017-01-01

    Agricultural abandonment is regarded as a major driver of soil organic carbon (C) dynamics, but the mechanisms underlying the direction and magnitude of soil C dynamics following agricultural abandonment are poorly understood. Here dynamics of soil C and N contents during postagricultural succession were investigated in areas underlain by dolomite or limestone by using a space-for-time substitution approach in a karst region, southwest China. One hundred twenty-five sites from cropland, grassland, shrubland, and secondary forest were selected to represent different succession stages. Overall, soil C and N contents were greater (P < 0.05) over limestone than over dolomite mainly due to significantly greater contents of soil C and N in the cropland and grassland underlain by limestone. Both soil C and N contents were lowest in the cropland while highest in the forest. Further analysis indicated that the patterns of soil C and N dynamics differed between the two lithology types. Soil C and N contents increased significantly from cropland to forest over dolomite, while varied insignificantly among succession stages over limestone. Exchangeable calcium explained most of soil C and N variance. We proposed that higher dissolution rate of limestone could replenish the lost calcium so that the calcium levels, and in turn soil C and N contents, were stable from the cropland to the forest. Nevertheless, due to relatively low dissolution rate for dolomite, the calcium level was depleted in the cropland. Following agricultural abandonment, calcium level recovered due to decreased loss, which in turn resulted in recovery of soil C and N.

  3. Carbon Storage in Biologic and Oceanic Reservoirs: Issues and Opportunities

    NASA Astrophysics Data System (ADS)

    Caldeira, K.

    2007-12-01

    Most discussion of carbon capture and storage have focused on geologic reservoirs because these are the reservoirs most likely to provide for long-term storage with a minimum of adverse environmental consequences. Nevertheless, there is interest in storage in other reservoirs such as the biosphere or the oceans. Storage in biological reservoirs such as forests or agricultural soils may in many cases be relatively inexpensive. Because this biological storage involves carbon dioxide removal from the atmosphere, it can potentially offset emissions from the transportation sector. Biological storage can be politically popular because it can be deployed with simple technologies, can be deployed in developing countries, and in many cases involves other environmental co-benefits. However, total capacity is limited. Furthermore, biological storage is temporary unless the store is actively maintained forever. Such temporary storage can be valuable, although it is clearly not as valuable as the quasi-permanent storage offered by good geologic storage reservoirs Ocean storage options fall into two main classes. The first involves conventional separation and compression of carbon dioxide from large point sources which would then be piped into the deep ocean and released either into the water or as a lake on the sea floor. In either case, the carbon dioxide would eventually interact with the atmosphere and contribute to ocean acidification. However, there is potential for the development of long-term engineered containment of carbon dioxide on or in the sea floor. The second main ocean storage option involves increasing ocean alkalinity, probably by dissolving carbonate minerals. This approach may offer safe, quasi- permanent, and cost-effective storage in settings where coastal carbon dioxide point sources are co-located with carbonate mineral deposits. Not every location or carbon dioxide source is suitable for geologic storage of carbon dioxide. At this early stage, it is

  4. CO2 Huff-n-Puff Process in a Light Oil Shallow Shelf Carbonate Reservoir

    SciTech Connect

    John Prieditis; Mark Kovar; Roger Cole; Scott Wehner

    1998-02-02

    The principal objective of the Sundown Slaughter Unit (SSU) CO2 Huff- n- Puff (H- n- P) project is to determine the feasibility and practicality of the technology in a waterflooded shallow shelf carbonate environment. Sundown Slaughter Unit is the second demonstration site associated with this project, following the unsuccessful test at Central Vacuum Unit. The ultimate goal will be to develop guidelines based on commonly available data that other operators in the industry can use to investigate the applicability of the process within other fields. The technology transfer objective of the project is to disseminate the knowledge gained through an innovative plan in support of the Department of Energy's (DOE) objective of increasing domestic oil production and deferring the abandonment of shallow shelf carbonate (SSC) reservoirs. Tasks associated with this objective are carried out in what is a timely effort for near- term goals. The goal of this Sundown Slaughter Unit Project is to demonstrate the CO2 Huff- n- Puff process in a waterflooded, light oil, shallow shelf carbonate reservoir within the Permian Basin. The CO2 Huff- n- Puff process is a proven enhanced oil recovery technology for Louisiana- Texas gulf coast sandstone reservoirs. The reader is referred to three Society of Petroleum Engineer (SPE) papers, No. 15502, No. 16720 & No. 20208 for a review of the theory, mechanics of the process, and several case histories. The process has even been shown to be moderately effective in conjunction with steam on heavy California crude oils. Although the technology is proven in gulf coast sandstones, it continues to be a very underutilized enhanced recovery option for carbonates. The goal of this technology demonstration is to gain an overall understanding of the reservoir qualities that influence CO2 Huff- n- Puff production responses within a heterogeneous reservoir such as the shallow shelf carbonate environment of the Sundown Slaughter Unit. A generalized

  5. Organic carbon burial efficiency in a subtropical hydroelectric reservoir

    NASA Astrophysics Data System (ADS)

    Mendonça, Raquel; Kosten, Sarian; Sobek, Sebastian; Jaqueline Cardoso, Simone; Figueiredo-Barros, Marcos Paulo; Henrique Duque Estrada, Carlos; Roland, Fábio

    2016-06-01

    Hydroelectric reservoirs bury significant amounts of organic carbon (OC) in their sediments. Many reservoirs are characterized by high sedimentation rates, low oxygen concentrations in bottom water and a high share of terrestrially derived OC, and all of these factors have been linked to a high efficiency of OC burial. However, investigations of OC burial efficiency (OCBE, i.e., the ratio between buried and deposited OC) in reservoirs are limited to a few studies, none of which include spatially resolved analyses. In this study we determined the spatial variation in OCBE in a large subtropical reservoir and related it to sediment characteristics. Our results show that the sediment accumulation rate explains up to 92 % of the spatial variability in OCBE, outweighing the effect of other variables, such as OC source and oxygen exposure time. OCBE at the pelagic sites varied from 48 to 86 % (mean 67 %) and decreased towards the dam. At the margins, OCBE was lower (9-17 %) due to the low sediment accumulation in shallow areas. Our data show that the variability in OCBE both along the rivers-dam and the margin-pelagic axes must be considered in whole-reservoir assessments. Combining these results with a spatially resolved assessment of sediment accumulation and OC burial in the studied reservoir, we estimated a spatially resolved mean OC burial efficiency of 57 %. Being the first assessment of OCBE with such a high spatial resolution in a reservoir, these results suggest that reservoirs may bury OC more efficiently than natural lakes.

  6. Carbon dioxide concentration dictates alternative methanogenic pathways in oil reservoirs.

    PubMed

    Mayumi, Daisuke; Dolfing, Jan; Sakata, Susumu; Maeda, Haruo; Miyagawa, Yoshihiro; Ikarashi, Masayuki; Tamaki, Hideyuki; Takeuchi, Mio; Nakatsu, Cindy H; Kamagata, Yoichi

    2013-01-01

    Deep subsurface formations (for example, high-temperature oil reservoirs) are candidate sites for carbon capture and storage technology. However, very little is known about how the subsurface microbial community would respond to an increase in CO2 pressure resulting from carbon capture and storage. Here we construct microcosms mimicking reservoir conditions (55 °C, 5 MPa) using high-temperature oil reservoir samples. Methanogenesis occurs under both high and low CO2 conditions in the microcosms. However, the increase in CO2 pressure accelerates the rate of methanogenesis to more than twice than that under low CO2 conditions. Isotope tracer and molecular analyses show that high CO2 conditions invoke acetoclastic methanogenesis in place of syntrophic acetate oxidation coupled with hydrogenotrophic methanogenesis that typically occurs in this environment (low CO2 conditions). Our results present a possibility of carbon capture and storage for enhanced microbial energy production in deep subsurface environments that can mitigate global warming and energy depletion.

  7. CARVE: The Carbon in Arctic Reservoirs Vulnerability Experiment

    NASA Technical Reports Server (NTRS)

    Miller, Charles E.; Dinardo, Steven J.

    2012-01-01

    The Carbon in Arctic Reservoirs Vulnerability Experiment (CARVE) is a NASA Earth Ventures (EV-1) investigation designed to quantify correlations between atmospheric and surface state variables for the Alaskan terrestrial ecosystems through intensive seasonal aircraft campaigns, ground-based observations, and analysis sustained over a 5-year mission. CARVE bridges critical gaps in our knowledge and understanding of Arctic ecosystems, linkages between the Arctic hydrologic and terrestrial carbon cycles, and the feedbacks from fires and thawing permafrost. CARVE's objectives are to: (1) Directly test hypotheses attributing the mobilization of vulnerable Arctic carbon reservoirs to climate warming; (2) Deliver the first direct measurements and detailed maps of CO2 and CH4 sources on regional scales in the Alaskan Arctic; and (3) Demonstrate new remote sensing and modeling capabilities to quantify feedbacks between carbon fluxes and carbon cycle-climate processes in the Arctic (Figure 1). We describe the investigation design and results from 2011 test flights in Alaska.

  8. Electrolyte reservoir for carbonate fuel cells

    DOEpatents

    Iacovangelo, Charles D.; Shores, David A.

    1985-01-01

    An electrode for a carbonate fuel cell and method of making same wherein a substantially uniform mixture of an electrode-active powder and porous ceramic particles suitable for a carbonate fuel cell are formed into an electrode with the porous ceramic particles having pores in the range of from about 1 micron to about 3 microns, and a carbonate electrolyte is in the pores of the ceramic particles.

  9. Electrolyte reservoir for carbonate fuel cells

    DOEpatents

    Iacovangelo, C.D.; Shores, D.A.

    1984-05-23

    An electrode for a carbonate fuel cell and method of making same are described wherein a substantially uniform mixture of an electrode-active powder and porous ceramic particles suitable for a carbonate fuel cell are formed into an electrode with the porous ceramic particles having pores in the range of from about 1 micron to about 3 microns, and a carbonate electrolyte is in the pores of the ceramic particles.

  10. Carbonate reservoir plays in the South Atlantic and worldwide analogs

    NASA Astrophysics Data System (ADS)

    Mohriak, Webster

    2015-04-01

    This work presents a summary of the geological, geophysical and petrophysical challenges for interpretation of post-salt and presalt carbonate rocks that constitute one of the main reservoirs in the hydrocarbon accumulations in the South Atlantic, particularly in the Campos and Santos basins offshore Brazil and in the Angola -Gabon conjugate margins. Carbonate rocks associated with salt tectonics constitute one of the main exploratory plays in several basins worldwide, and recently have yielded large petroleum discoveries in the southeastern Brazilian continental margin (Santos Basin) and also in Angola (Kwanza Basin) . The presalt microbialite reservoirs are sealed by evaporites and the origin of these rocks is still controversial. One current of interpretation assumes they are associated with reefs and carbonate buildups formed during periods of sea-level rises in a desiccating basin. Other currents of interpretation assume that these rocks might be associated with hydrothermal fluids and chemical precipitation of carbonates in a basin affected by volcanic episodes, resulting in travertine deposits with secondary biogenic growth. We present examples of post-salt oil fields involving Albian carbonates in the South Atlantic, and also discuss the presalt plays recently drilled in ultradeep waters. The presalt carbonate reservoirs are compared with possible microbialite analogs in the sedimentary basins of Brazil dating from Neoproterozoic to Recent, and their similarities and differences in terms of depositional setting and petrophysical parameters from the Late Aptian presalt carbonate rocks that have been sampled in the Santos and Kwanza basins.

  11. ENHANCEMENT OF TERRESTRIAL CARBON SINKS THROUGH RECLAMATION OF ABANDONED MINE LANDS IN THE APPALACHIAN REGION

    SciTech Connect

    Gary D. Kronrad

    2002-12-01

    The U.S.D.I. Office of Surface Mining (OSM) estimates that there are approximately 1 million acres of abandoned mine land (AML) in the Appalachian region. AML lands are classified as areas that were inadequately reclaimed or were left unreclaimed prior to the passage of the 1977 Surface Mining Control and Reclamation Act, and where no federal or state laws require any further reclamation responsibility to any company or individual. Reclamation and afforestation of these sites have the potential to provide landowners with cyclical timber revenues, generate environmental benefits to surrounding communities, and sequester carbon in the terrestrial ecosystem. Through a memorandum of understanding, the OSM and the U.S. Department of Energy (DOE) have decided to investigate reclaiming and afforesting these lands for the purpose of mitigating the negative effects of anthropogenic carbon dioxide in the atmosphere. This study determined the carbon sequestration potential of northern red oak (Quercus rubra L.), one of the major reclamation as well as commercial species, planted on West Virginia AML sites. Analyses were conducted to (1) calculate the total number of tons that can be stored, (2) determine the cost per ton to store carbon, and (3) calculate the profitability of managing these forests for timber production alone and for timber production and carbon storage together. The Forest Management Optimizer (FORMOP) was used to simulate growth data on diameter, height, and volume for northern red oak. Variables used in this study included site indices ranging from 40 to 80 (base age 50), thinning frequencies of 0, 1, and 2, thinning percentages of 20, 25, 30, 35, and 40, and a maximum rotation length of 100 years. Real alternative rates of return (ARR) ranging from 0.5% to 12.5% were chosen for the economic analyses. A total of 769,248 thinning and harvesting combinations, net present worths, and soil expectation values were calculated in this study. Results indicate that

  12. Calculation of petrophysical properties for Mishrif carbonate reservoir

    NASA Astrophysics Data System (ADS)

    Kadhim, Fadhil Sarhan; Samsuri, Ariffin; Idris, Ahmad Kamal

    2014-10-01

    The accurate calculations of petrophysical properties in carbonate reservoirs are the most challenging aspects of well log analysis. Many equations have been developed over the years based on known physical principles or on empirically derived relationships, which are used to calculate carbonate rock petrophysical properties. Carbonate reservoirs in the Middle East are very heterogeneous in terms of rock types. Therefore the reservoir should be split into layers on the basis of the dominant rock type in order to define average values and trends of petrophysical parameters in the reservoir rock. The saturation exponent (n) and cementation exponent (m) are calculated from well log data using Pickett method. The study made across the Mishrif carbonate formation, which is the shallowest formation of the hydrocarbon bearing zone in the NS oil field in the Middle East. Results show that the average formation water resistivity (Rw= 0.0243), average mud filtrate resistivity (Rmf= 0.199), Irreducible Water Saturation (Swi=0. 18), and Archie's parameters (m=1. 78, n= 2, and a=1). While porosity, true resistivity, and water saturation values with depth of formation were calculated by using Interactive Petrophysics software (IP V3.5, 2008). The computer process interpretation (CPI) illustrates that the shale member splits the Mishrif formation into two parts; Upper and Lower Mishrif. This study is a step to investigate petrophysical properties, which used to calculate water saturation that should use to estimate original oil in place and detected the perforation zones.

  13. MULTIDISCIPLINARY IMAGING OF ROCK PROPERTIES IN CARBONATE RESERVOIRS FOR FLOW-UNIT TARGETING

    SciTech Connect

    Stephen C. Ruppel

    2005-02-01

    Despite declining production rates, existing reservoirs in the US contain large quantities of remaining oil and gas that constitute a huge target for improved diagnosis and imaging of reservoir properties. The resource target is especially large in carbonate reservoirs, where conventional data and methodologies are normally insufficient to resolve critical scales of reservoir heterogeneity. The objectives of the research described in this report were to develop and test such methodologies for improved imaging, measurement, modeling, and prediction of reservoir properties in carbonate hydrocarbon reservoirs. The focus of the study is the Permian-age Fullerton Clear Fork reservoir of the Permian Basin of West Texas. This reservoir is an especially appropriate choice considering (a) the Permian Basin is the largest oil-bearing basin in the US, and (b) as a play, Clear Fork reservoirs have exhibited the lowest recovery efficiencies of all carbonate reservoirs in the Permian Basin.

  14. CO{sub 2} HUFF-n-PUFF process in a light oil shallow shelf carbonate reservoir. Quarterly technical progress report, [January 1, 1995--March 31, 1995

    SciTech Connect

    Cole, R.; Prieditis, J.; Vogt, J.; Wehner, S.

    1995-04-21

    The principal objective of the Central Vacuum Unit (CVU) CO{sub 2} Huff-n-Puff (H-n-P) project is to determine the feasibility and practicality of the technology in a waterflooded shallow shelf carbonate environment. The results of parametric simulation of the CO{sub 2} H-n-P process, coupled with the CVU reservoir characterization components will determine if this process is technically and economically feasible for field implementation. The technology transfer objective of the project is to disseminate the knowledge gained through an innovative plan in support of the Department of Energy`s (DOE) objective of increasing domestic oil production and deferring the abandonment of shallow shelf carbonate (SSC) reservoirs. Technical progress is reported for geostatitical realizations; paramatric simulation; waterflood review; and reservoir characterization.

  15. CO{sub 2} Huff-n-Puff process in a light oil shallow shelf carbonate reservoir. Second quarterly technical progress report, [April 1995--June 1995

    SciTech Connect

    Cole, R.; Prieditis, J.; Vogt, J.; Wehner, S.

    1995-07-11

    The principal objective of the Central Vacuum Unit (CVU) CO{sub 2} Huff-n-Puff (H-n-P) project is to determine the feasibility and practicality of the technology in a waterflooded shallow shelf carbonate environment. The results of parametric simulation of the CO{sub 2} H-n-P process, coupled with the CVU reservoir characterization components will determine if this process is technically and economically feasible for field implementation. The technology transfer objective of the project is to disseminate the knowledge gained through an innovative plan in support of the Department of Energy`s (DOE) objective of increasing domestic oil production and deferring the abandonment of shallow shelf carbonate (SSC) reservoirs. Tasks associated with this objective are carried out in what is considered a timely effort for near-term goals. Technical progress is summarized for; geostatistical realizations; site-specific simulation;waterflood review; and reservoir characterization.

  16. Carbon Sequestration in Unconventional Reservoirs: Geophysical, Geochemical and Geomechanical Considerations

    NASA Astrophysics Data System (ADS)

    Zakharova, Natalia V.

    In the face of the environmental challenges presented by the acceleration of global warming, carbon capture and storage, also called carbon sequestration, may provide a vital option to reduce anthropogenic carbon dioxide emissions, while meeting the world's energy demands. To operate on a global scale, carbon sequestration would require thousands of geologic repositories that could accommodate billions of tons of carbon dioxide per year. In order to reach such capacity, various types of geologic reservoirs should be considered, including unconventional reservoirs such as volcanic rocks, fractured formations, and moderate-permeability aquifers. Unconventional reservoirs, however, are characterized by complex pore structure, high heterogeneity, and intricate feedbacks between physical, chemical and mechanical processes, and their capacity to securely store carbon emissions needs to be confirmed. In this dissertation, I present my contribution toward the understanding of geophysical, geochemical, hydraulic, and geomechanical properties of continental basalts and fractured sedimentary formations in the context of their carbon storage capacity. The data come from two characterization projects, in the Columbia River Flood Basalt in Washington and the Newark Rift Basin in New York, funded by the U.S. Department of Energy through Big Sky Carbon Sequestration Partnerships and TriCarb Consortium for Carbon Sequestration. My work focuses on in situ analysis using borehole geophysical measurements that allow for detailed characterization of formation properties on the reservoir scale and under nearly unaltered subsurface conditions. The immobilization of injected CO2 by mineralization in basaltic rocks offers a critical advantage over sedimentary reservoirs for long-term CO2 storage. Continental flood basalts, such as the Columbia River Basalt Group, possess a suitable structure for CO2 storage, with extensive reservoirs in the interflow zones separated by massive impermeable

  17. The accumulation of organic carbon in mineral soils by afforestation of abandoned farmland.

    PubMed

    Wei, Xiaorong; Qiu, Liping; Shao, Mingan; Zhang, Xingchang; Gale, William J

    2012-01-01

    The afforestation of abandoned farmland significantly influences soil organic carbon (OC). However, the dynamics between OC inputs after afforestation and the original OC are not well understood. To learn more about soil OC dynamics after afforestation of farmland, we measured the soil OC content in paired forest and farmland plots in Shaanxi Province, China. The forest plots had been established on farmland 18, 24, 48, 100, and 200 yr previously. The natural (13)C abundance of soil organic matter was also analyzed to distinguish between crop- and forest-derived C in the afforested soils. We observed a nonlinear accumulation of total OC in the 0-80 cm depth of the mineral soil across time. Total soil OC accumulated more rapidly under forest stands aged 18 to 48 yr than under forest stands aged 100 or 200 yrs. The rate of OC accumulation was also greater in the 0-10 cm depth than in the 10-80 cm depth. Forest-derived OC in afforested soils also accumulated nonlinearly across time, with the greatest increase in the 0-20 cm depth. Forest-derived OC in afforest soils accounted for 52-86% of the total OC in the 0-10 cm depth, 36-61% of the total OC in the 10-20 cm depth, and 11-50% of the total OC in the 20-80 cm depth. Crop-derived OC concentrations in the 0-20 cm depth decreased slightly after afforestation, but there was no change in crop-derived OC concentrations in the 20-80 cm depth. The results of our study support the claim that afforestation of farmland can sequester atmospheric CO(2) by increasing soil OC stocks. Changes in the OC stocks of mineral soils after afforestation appear to be influenced mainly by the input of forest-derived C rather than by the loss of original OC.

  18. Vertical stacking of reservoirs in Silurian carbonates of Appalachian basin

    SciTech Connect

    Smosna, R.; Conrad, J.M.; Maxwell, T.C.

    1988-08-01

    The distribution of modern reefs and oolites is controlled to a large degree by sea-floor topography. Likewise, paleotopographic highs in the Silurian Lockport Dolomite and underlying Keefer Sandstone provided optimum sites for the deposition of boundstone and grainstone reservoir facies. The Keefer Sandstone in western West Virginia was deposited as a series of subtidal sand waves with a relief of a few meters. During initial Lockport sedimentation, the turbulence, water chemistry, and light intensity were most favorable in shallow water over the Keefer sand waves, encouraging growth of coral-stromatoporoid patch reefs. Skeletal banks in the upper Lockport of eastern Kentucky also were established over topographic highs of earlier Lockport mounds. In a similar fashion, the upper Lockport of West Virginia was deposited as oolitic shoals that formed atop exposed mud mounds in the middle member. A slight rise of sea level created the agitated subtidal environment above the now-submerged mud mounds, and oolite bars developed. The reef, skeletal-bank, and oolite facies of the Lockport, and the Keefer Sandstone, are all petroleum reservoirs. Carbonate reservoirs can be identified in the subsurface by thicks on isopach maps, by their clean gamma-ray signature, and by a relatively high log porosity. Based on these criteria, seven potential fairways have been mapped in Kentucky. Because the distribution of buildups was greatly influenced by that of their predecessors, five of the fairways contain vertically stacked reservoir facies. These are particularly attractive because they can be drilled as multistory targets.

  19. Carbonate reservoirs at the Mesozoic-Tertiary unconformity, northeast Spain

    SciTech Connect

    Esteban, M.

    1988-08-01

    Carbonates at the Mesozoic-Tertiary unconformity in northeast Spain show four types/stages of evolution of reservoir properties: karstification, coastal reworking, Miocene organic buildups, and Pliocene burial. Subaerial exposure during Paleogene-early Miocene rifting developed a complex fracture-controlled paleokrast facies, showing up to three evolution levels with well-developed cavern and vuggy porosity (1). During the Miocene, the paleokrast profile was intensively reworked into a variety of breccias, conglomerates, and calcarenites in both alluvial and coastal depositional settings. Gravitational displacement of largely karstified hillsides was common. These reworked paleokarst deposits (2) present excellent reservoir properties. The Miocene formations onlap the karstified Mesozoic and the reworked facies; these formations include coral reefs and foramalgal buildups (3) with primary and secondary porosity. Finally, a late fracture event (attributed to the Pliocene) affected the buried and lithified paleokarst deposits and lower-middle Miocene formations (4). This fracture event is associated with vuggy corrosion, dolomitization, ore mineralization, and leaching of Mesozoic to middle Miocene carbonates. Several horizons with chalky microporosity are also tentatively related to this Pliocene event. These four phases of reservoir evolution are also recognized in northern Morocco and southern Italy.

  20. Changes in soil carbon and nitrogen following land abandonment of farmland on the Loess Plateau, China.

    PubMed

    Deng, Lei; Shangguan, Zhou-Ping; Sweeney, Sandra

    2013-01-01

    The revegetation of abandoned farmland significantly influences soil organic C (SOC) and total N (TN). However, the dynamics of both soil OC and N storage following the abandonment of farmland are not well understood. To learn more about soil C and N storages dynamics 30 years after the conversion of farmland to grassland, we measured SOC and TN content in paired grassland and farmland sites in the Zhifanggou watershed on the Loess Plateau, China. The grassland sites were established on farmland abandoned for 1, 7, 13, 20, and 30 years. Top soil OC and TN were higher in older grassland, especially in the 0-5 cm soil depths; deeper soil OC and TN was lower in younger grasslands (<20 yr), and higher in older grasslands (30 yr). Soil OC and N storage (0-100 cm) was significantly lower in the younger grasslands (<20 yr), had increased in the older grasslands (30 yr), and at 30 years SOC had increased to pre-abandonment levels. For a thirty year period following abandonment the soil C/N value remained at 10. Our results indicate that soil C and TN were significantly and positively correlated, indicating that studies on the storage of soil OC and TN needs to focus on deeper soil and not be restricted to the uppermost (0-30 cm) soil levels.

  1. Changes in Soil Carbon and Nitrogen following Land Abandonment of Farmland on the Loess Plateau, China

    PubMed Central

    Deng, Lei; Shangguan, Zhou-Ping; Sweeney, Sandra

    2013-01-01

    The revegetation of abandoned farmland significantly influences soil organic C (SOC) and total N (TN). However, the dynamics of both soil OC and N storage following the abandonment of farmland are not well understood. To learn more about soil C and N storages dynamics 30 years after the conversion of farmland to grassland, we measured SOC and TN content in paired grassland and farmland sites in the Zhifanggou watershed on the Loess Plateau, China. The grassland sites were established on farmland abandoned for 1, 7, 13, 20, and 30 years. Top soil OC and TN were higher in older grassland, especially in the 0–5 cm soil depths; deeper soil OC and TN was lower in younger grasslands (<20 yr), and higher in older grasslands (30 yr). Soil OC and N storage (0–100 cm) was significantly lower in the younger grasslands (<20 yr), had increased in the older grasslands (30 yr), and at 30 years SOC had increased to pre-abandonment levels. For a thirty year period following abandonment the soil C/N value remained at 10. Our results indicate that soil C and TN were significantly and positively correlated, indicating that studies on the storage of soil OC and TN needs to focus on deeper soil and not be restricted to the uppermost (0–30 cm) soil levels. PMID:23940793

  2. Characterization of diagenetically altered carbonate reservoirs, South Cowden Grayburg Reservoir, West Texas

    SciTech Connect

    Lucia, F.J.; Ruppel, S.C.

    1996-12-31

    Much of the difficulty in constructing carbonate reservoir models for fluid-flow simulation results from diagenetic overprinting of depositional permeability patterns. In the South Cowden field, diagenetic effects result in (1) low porosity and permeability in the western and northern areas due to reduction of porosity by means of dolomitization and post-dolomitization compaction, (2) elimination of the petrophysical effects of depositional texture resulting from changes in particle size due to dolomitization, and (3) creation of a touching-vug pore system due to anhydrite dissolution. The extent of anhydrite alteration can be mapped to show three distinct diagenetic areas: those dominated by unaltered, altered, or dissolved anhydrite. Each alteration type has a unique acoustic-porosity transform that can be used to map the diagenetic areas and to calculate porosity when only acoustic logs are available. A single porosity-permeability transform characterizes the areas having unaltered and altered anhydrite, and the depositional stratigraphy is useful in constructing a reservoir model. A more favorable transform characterizes the area of dissolved anhydrite, and depositional stratigraphy is not useful in constructing a reservoir model because of the large effect of the diagenetic overprint.

  3. Superimposed multiple orders of sequences predict reservoir migration and thickness in stratigraphy trapped Haynesville carbonate reservoirs

    SciTech Connect

    Neuhart, D.; Hwang, D. )

    1991-08-01

    The Upper Jurassic Haynesville Formation is part of the Louark group located on the east flank of the East Texas salt basin. Haynesville gas production is from ooid grainstones which formed on a gently dipping carbonate ramp. Hydrocarbon was sourced from the underlying Smackover Formation basinal deposits and trapped stratigraphically by multiple ooid shoal pinch-outs. Therefore, an essential tool in prospecting for Haynesville gas is an understanding of Haynesville stratigraphy. Toward that end, the authors placed the formation into a sequence stratigraphic framework. Haynesville stratal-stacking patterns and lithology distribution result from the superimposition of three orders of cyclicity. Evidence of second order, third order, and fourth order sequences are found within the Haynesville data. The entire Haynesville Formation lies within a second-order transgressive systems tract, which is expresses in facies as an overall deepening event. The superimposition of second-order extreme retrograde deposition during periods of in-phase second- and third- order transgression. The results were large shifts in deposition centers and additional reservoir thickness due to increased accommodation. Fourth -order sequences exerted the greatest control an ooid reservoir distribution due to shoal progradation. By superimposing the observed multiple orders of sequences into the Haynesville geologic model, the top of Haynesville becomes both a sequence boundary in the third order and a maximum flooding surface in the second order. Together, fourth-order flooding surface in the second order. Together, fourth-order and third order sequences indicate the direction of reservoir migration as well as areas of maximum reservoir thickness.

  4. Effect of trans-reservoir water supply on carbon and nitrogen stable isotope composition in hydrologically connected reservoirs in China

    NASA Astrophysics Data System (ADS)

    Zhang, Huajun; Peng, Liang; Gu, Binhe; Han, Bo-Ping

    2016-10-01

    Dajingshan, Fenghuangshan and Meixi reservoirs are located in Zhuhai, a coastal city in southern China, and they function to supply drinking water to Zhuhai and Macau. For effectively supplying waster, they are hydrologically connected and Dajingshan Reservoir first receives the water pumped from the river at Guangchang Pumping Station, and then feeds Fenghuangshan Reservoir, and the two well-connected reservoirs are mesotrophic. Meixi Reservoir is a small and oligotrophic water body and feeds Dajingshan Reservoir only in wet seasons when overflow occurs. Particulate organic matter (POM) was collected from three hydrologically connected water supply reservoirs, and seasonal variations of POM were ascertained from stable carbon and nitrogen isotopes in wet and dry seasons, and the effects of pumping water and reservoir connectivity on POM variations and composition were demonstrated by the relationships of the stable isotope ratios of POM. Seasonality and similarity of stable carbon and nitrogen isotopes of POM varied with hydrodynamics, connectivity and trophic states of the four studied water bodies. The two well-connected reservoirs displayed more similar seasonality for δ13CPOM than those between the river station and the two reservoirs. However, the opposite seasonality appeared for δ15NPOM between the above waters and indicates different processes affecting the stable carbon and nitrogen isotopes of POM. δ13CPOM and δ15NPOM changed little between wet and dry seasons in Meixi Reservoir-a low productive and rain-driven system, suggesting little POM response to environmental changes in that water system. As expected, connectivity enhanced the similarity of the stable isotope ratios of POM between the water bodies.

  5. Carbon pool and biomass dynamics associated with deforestation, land use, and agricultural abandonment in the neotropics.

    PubMed

    Kauffman, J Boone; Hughes, R Flint; Heider, Chris

    2009-07-01

    Current rates of deforestation and the resulting C emissions in the tropics exceed those of secondary forest regrowth and C sequestration. Changing land-use strategies that would maintain standing forests may be among the least expensive of climate change mitigation options. Further, secondary tropical forests have been suggested to have great value for their potential to sequester atmospheric C. These options require an understanding of and capability to quantify C dynamics at landscape scales. Because of the diversity of physical and biotic features of tropical forests as well as approaches and intensities of land uses within the neotropics, there are tremendous differences in the capacity of different landscapes to store and sequester C. Major gaps in our current knowledge include quantification of C pools, rates and patterns of biomass loss following land-cover change, and quantification of the C storage potential of secondary forests following abandonment. In this paper we present a synthesis and further analyses from recent studies that describe C pools, patterns of C decline associated with land use, and rates of C accumulation following secondary-forest establishment--all information necessary for climate-change mitigation options. Ecosystem C pools of Neotropical primary forests minimally range from approximately 141 to 571 Mg/ha, demonstrating tremendous differences in the capacity of different forests to store C. Most of the losses in C and nutrient pools associated with conversion occur when fires are set to remove the slashed forest to prepare sites for crop or pasture establishment. Fires burning slashed primary forests have been found to result in C losses of 62-80% of prefire aboveground pools in dry (deciduous) forest landscapes and 29-57% in wet (evergreen) forest landscapes. Carbon emissions equivalent to the aboveground primary-forest pool arise from repeated fires occurring in the first 4 to 10 years following conversion. Feedbacks of climate

  6. Soil Inorganic Carbon in Deserts: Active Carbon Sink or Inert Reservoir?

    NASA Astrophysics Data System (ADS)

    Monger, H. C.; Cole, D. R.

    2011-12-01

    Soil inorganic carbon is the third largest C pool in the active global carbon cycle, containing at least 800 petagrams of carbon. Although carbonate dissolution-precipitation reactions have been understood for over a century, the role of soil inorganic carbon in carbon sequestration, and in particular pedogenic carbonate, is a deceptively complex process because it involves interdependent connections among climate, plants, microorganisms, silicate minerals, soil moisture, pH, and Ca supply via rain, dust, or in situ weathering. An understanding of soil inorganic carbon as a sink or reservoir also requires examination of the system at local to continental scales and at seasonal to millennial time scales. In desert soils studied in North America, carbon isotope ratios and radiocarbon dates were measured in combination with electron microscopy, lab and field experiments with biological calcite formation, and field measurements of carbon dioxide emissions. These investigations reveal that soil inorganic carbon is both an active sink and a inert reservoir depending on the spatial and temporal scale and source of calcium.

  7. Lawn soil carbon storage in abandoned residential properties: an examination of ecosystem structure and function following partial human-natural decoupling.

    PubMed

    Gough, Christopher M; Elliott, Hunter L

    2012-05-15

    Residential abandonment is on the rise in many urban areas, with unknown implications for ecosystem structure and function on land slated for partial or full restoration to native habitat. Partial decoupling of human and natural systems could reduce disturbance (e.g., trampling, recreational traffic) and modify vegetation structure in a way that alters soil carbon storage, an ecosystem function that many municipalities consider a management objective of growing importance. We quantified soil carbon percent and mass to 10 cm depth and examined vegetation structure in 50 vacant and 10 occupied residential lawns located in Richmond, VA, with the principal objective of determining whether occupancy status alters trajectories of soil carbon storage or its correspondence with household economic/demographic indicators and vegetation cover. Abandoned residential lawns supported significantly less grass cover, but these declines were largely offset by increases in emergent overstory (>1 m height) vegetation cover. Soil carbon percent and mass did not differ between lawns of occupied and abandoned residences, even though significant, but highly uncertain, increases in soil carbon mass occurred in the first decade following vacancy. Instead, all residential lawns exhibited similar significant increases in soil carbon percent and mass with increasing residence age and neighborhood affluence, the former indicating annual carbon accretion rates of 20 g m(-2). We conclude that in this early stage of vacancy, soil carbon storage is already subtly responding to declines in human intervention, with reduced soil disturbance and sustained vegetation cover in abandoned lawns playing likely roles in emerging soil carbon storage trajectories.

  8. Acid Fluid-Rock Interactions with Shales Comprising Unconventional Hydrocarbon Reservoirs and with Shale Capping Carbon Storage Reservoirs: Experimental Insights

    NASA Astrophysics Data System (ADS)

    Kaszuba, J. P.; Bratcher, J.; Marcon, V.; Herz-Thyhsen, R.

    2015-12-01

    Injection of HCl is often a first stage in the hydraulic fracturing process. These acidic fluids react with marls or shales in unconventional reservoirs, reactions generally comparable to reaction between shale caprocks and acidic, carbonated formation waters in a carbon storage reservoir. Hydrothermal experiments examine acid fluid-rock interaction with 1) an unconventional shale reservoir and 2) a model shale capping a carbon storage reservoir. In the former, unconventional reservoir rock and hydraulic fracturing fluid possessing a range of ionic strengths (I = 0.01, 0.15) and initial pH values (2.5 and 7.3) reacted at 115°C and 35 MPa for 28 days. In the latter, a model carbon storage reservoir (Fe-rich dolomite), shale caprock (illite), and shale-reservoir mixture each reacted with formation water (I = 0.1 and pH 6.3) at 160°C and 25 MPa for ~15 days. These three experiments were subsequently injected with sufficient CO2 to maintain CO2 saturation in the water and allowed to react for ~40 additional days. Acidic frac fluid was rapidly buffered (from pH 2.5 to 6.2 after 38 hrs) by reaction with reservoir rock whereas the pH of near-neutral frac fluid decreased (from 7.3 to 6.9) after 47 hrs. Carbonate dissolution released Ca and Sr into solution and feldspar dissolution released SiO2 and Li; the extent of reaction was greater in the experiment containing acidic frac fluid. All three carbon storage experiments displayed a similar pH decrease of 1.5 units after the addition of CO2. The pH remained low for the duration of the experiments because the immiscible supercritical CO2 phase provided an infinite reservoir of carbonic acid that could not be consumed by reaction with the rock. In all three experiments, Ca, Fe, Mg, Mn and SO4 increase with injection, but slowly decline through termination of the experiments. This trend suggests initial dissolution followed by re-precipitation of carbonates, which can be seen in modeling and SEM results. New clay minerals

  9. Carbon implications of Virgin Lands Campaign cropland expansion and post-Soviet agricultural land abandonment in Russia and Kazakhstan

    NASA Astrophysics Data System (ADS)

    Prishchepov, A. V.; Kurganova, I.; Schierhorn, F.; Lopes de Gerenyu, V.; Müller, D.; Kuzyakov, Y.

    2015-12-01

    Political economy and institutional changes regarding land use play crucial role in shaping land cover worldwide. Among such events was the Soviet Virgin Lands Campaign, when 45.2 million ha of virgin steppes were ploughed up from 1954 to 1963 in northern Eurasia. We took opportunity to evaluate carbon (C) costs of this Campaign, particularly with the account of massive cropland abandonment in the former Campaign area after demise of the Soviet Union in 1991. Within cropland mask produced with remotely sensed data, we spatially disaggregated historical annual sown area statistics at the provincial level for Russia and Kazakhstan based on cropland suitability assessment. We also adjusted our cropland allocation model with the use of 1:3,000,000 map depicting cropland expansion in Northern Kazakhstan. We used C bookkeeping approach to assess C dynamics based on soil stratification and C field measurements. The Campaign resulted in huge C losses from soils, which accounted for 611±47 Mt C in Russia and 241±11 Mt C in Kazakhstan for upper 0-50 cm soil layer during the first 20 years of cultivation. Such C losses could be compared with C losses due to plowing up the prairies in the mid-1930s in USA. Despite the huge C losses from soils during the Campaign, the total C budget in soils of both countries at national level was positive after 1991 due to sequestered C on abandoned lands, albeit the patterns of C loss during the Campaign and C sink in post-Soviet period differed. The C sink from 1991 to 2010 on abandoned croplands in Russia (45.5Mha) comprised 976±108Mt C and Kazakhstan (12.9Mha) comprised 240±34Mt C. However, already ongoing recultivation of abandoned cropland in Kazakhstan and already planned such activities in Russia, can release stored C on abandoned lands. Our study highlights the importance of environmental evaluation of such governmental programs and their alternatives, particularly, since such programs are not rare events in modern land

  10. An Integrated Approach to Predicting Carbon Dioxide Storage Capacity in Carbonate Reservoirs

    NASA Astrophysics Data System (ADS)

    Smith, M. M.; Hao, Y.; Mason, H. E.; Carroll, S.

    2015-12-01

    Carbonate reservoirs are widespread globally but pose unique challenges for geologic carbon dioxide (CO2) storage due to the reactive nature of carbonate minerals and the inherently heterogeneous pore structures of these rock types. Carbonate mineral dissolution resulting from CO2-acidified fluids may actually create new storage capacity, but predicting the extent and location of enhanced storage is complicated by the presence of pore size distributions spanning orders of magnitude as well as common microfractures. To address this issue, core samples spanning a wide range of depths and predicted permeabilities were procured from wells drilled into the Weyburn-Midale reservoir from the IEA GHG's CO2 Monitoring and Storage Project, Saskatchewan, Canada; and from the Arbuckle dolomite at the Kansas Geological Survey's South-central Kansas CO2 Project. Our approach integrated non-invasive characterization, complex core-flooding experiments, and 3-D reactive transport simulations to calibrate relevant CO2 storage relationships among fluid flow, porosity, permeability, and chemical reactivity. The resulting observations from this work permit us to constrain (and place uncertainty limits on) some of the model parameters needed for estimating evolving reservoir CO2 storage capacity. The challenge remains, however, as to how to best interpret and implement these observations at the actual reservoir scale. We present our key findings from these projects and recommendations for storage capacity predictions. This work was performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344.

  11. Wellbore stability analysis in carbonate reservoir considering anisotropic behaviour

    NASA Astrophysics Data System (ADS)

    Alves, José; Guevara, Nestor; Coelho, Lucia; Baud, Patrick

    2010-05-01

    Carbonate reservoirs represent a major part of the world oil and gas reserves. In particular, recent discoveries in the pre-salt offshore Brazil place big challenges to exploration and production under high temperatures and pressures (HTHP). During production, the extraction of hydrocarbons reduces pore pressure and thus causes an increase in the effective stress and mechanical compaction in the reservoir. The compactive deformation and failure may be spatially extensive or localized to the vicinity of the wellbore, but in either case the consequences can be economically severe involving surface subsidence, well failure and various production problems. The analysis of wellbore stability and more generally of deformation and failure in carbonate environments hinges upon a relevant constitutive modeling of carbonate rocks over a wide range of porosities, in particular, observed microstructure of samples suggests anisotropic behaviour. In this study, we performed a wellbore stability analysis for a lateral wellbore junction in three dimensions. The complex geometry for the wellbore junction was modeled with tetrahedral finite elements considering a rate independent elastic-plastic isotropic material that presented linear behavior during elastic strain and associated flow rule. A finite element model simulating drilling and production phases were done for field conditions from a deep water reservoir in Campos basin, offshore Brazil. In this context, several scenarios were studied considering true 3D orientation for both in situ stresses and geometry of the wellbore junction itself. We discussed the impact of constitutive modeling, considering anisotropic ductile damage and pressure sensitiveness on the wellbore stability. Parameter values for the analysis were based based on experimental data on two micritic porous carbonates. Series of conventional triaxial experiments were performed at room temperature in dry and wet conditions on samples of Comiso and Tavel

  12. CO{sub 2} Huff-n-Puff process in a light oil shallow shelf carbonate reservoir. Topical report No. 1

    SciTech Connect

    Cole, R.; Prieditis, J.; Vogt, J.; Wehner, S.

    1995-10-01

    The principle objective of the Central Vacuum Unit (CVU) CO{sub 2} Huff-n-Puff (H-n-P) project is to determine the feasibility and practicality of the technology in a waterflooded shallow shelf carbonate environment. The results of parametric simulation of the CO{sub 2} H-n-P process coupled with the CVU reservoir characterization components will determine if this process is technically and economic for field implementation. The ultimate goal will be to develop guidelines based on commonly available data that other operators in the industry can use to investigate the applicability of the process within other field. The technology transfer objective of the project is to disseminate the knowledge gained through an innovative plan in support of the Department of Energy`s objective to increasing domestic oil production and deferring the abandonment of shallow shelf carbonate reservoirs. Accomplishments to date are described in this report.

  13. CO[sub]2 huff-n-puff process in a light oil shallow shelf carbonate reservoir, quarterly technical progress report, January--March, 1997

    SciTech Connect

    Wehner, S.C., Kovar, M., Casteel, J.

    1997-03-31

    The principal objective of the Central Vacuum Unit (CVU) C0{sub 2} Huff-n-Puff (H-n-P) project is to determine the feasibility and practicality of the technology in a waterflooded shallow shelf carbonate environment. The results of parametric simulation of the C0{sub 2} H-n-P process, coupled with the CVU reservoir characterization components will be used to determine if this process is technically and economically feasible for field implementation. The technology transfer objective of the project is to disseminate the knowledge gained through an innovative plan in support of the Department of Energy`s (DOE) objective of increasing domestic oil production and detecting the abandonment of shallow shelf carbonate (SSC) reservoirs. Tasks associated with this objective are carried out in what is considered a timely effort for near-term goals.

  14. CO{sub 2} Huff-n-Puff process in a light oil shallow shelf carbonate reservoir. Quarterly technical progress report, July--September, 1995

    SciTech Connect

    Cole, R.; Prieditis, J.; Vogt, J. Wehner, S.

    1995-10-15

    The principal objective of the Central Vacuum Unit (CVU) CO{sub 2} Huff-n-Puff (H-n-P) project is to determine the feasibility and practicality of the technology in a waterflooded shallow shelf carbonate environment. The results of parametric simulation of the CO{sub 2} H-n-P process, coupled with the CVU reservoir characterization components will determine if this process is technically and economically feasible for field implementation. The technology transfer objective of the project is to disseminate the knowledge gained through an innovative plan in support of the Department of Energy`s (DOE) objective of increasing domestic oil production and deferring the abandonment of shallow shelf carbonate (SSC) reservoirs. Tasks associated with this objective are carried out in what is considered a timely effort for near-term goals.

  15. CO{sub 2} Hugg-n-Puff process in a light oil shallow shelf carbonate reservoir. Quarterly technical progress report, 2nd quarter 1996

    SciTech Connect

    1996-07-25

    The principal objective of the Central Vacuum Unit (CVU) CO{sub 2} Huff-n-Puff (H-n-P) project is to determine the feasibility and practicality of the technology in a waterflooded shallow shelf carbonate environment. The results of parametric simulation of the CO{sub 2} H-n-P process, coupled with the CVU reservoir characterization components will determine if this process is technically and economically feasible for field implementation. The technology transfer objective of the project is to disseminate the knowledge gained through an innovative plan in support of the Department of Energy`s (DOE) objective of increasing domestic oil production and deferring the abandonment of shallow shelf carbonate (SSC) reservoirs. Tasks associated with this objective are carried out in what is considered a timely effort for near-term goals.

  16. Investigating physical controls on methane and carbon dioxide fluxes over reservoirs using the eddy covariance method

    EPA Science Inventory

    Reservoirs are a globally important source of carbon to the atmosphere. Several recent studies have found that both carbon dioxide (CO2) and methane (CH4) emissions from reservoirs are currently being underestimated by up to 50%. This underestimation is due to inadequate characte...

  17. Carbon reservoirs in temperate South American Nothofagus forests.

    PubMed

    Böswald, Klaus; Lencinas, José D; Loguercio, Gabriel

    2002-01-08

    Humans are influencing the global carbon (C) cycle due to the combustion of fossil fuels and due to changes in land use management. These activities are fostering the manmade greenhouse effect and thus global climate change. Negative effects for life on earth are accounted for. Among others the international climate debate focused attention on forests and forestry, knowing about their considerable influence on global climate change. Whilst the global C budget is described fairly well, there is a lack of regional data describing the C reservoirs and flows in detail. This has to be constituted especially for forests in developing countries. This paper presents an investigation at regional scale of the C reservoirs in a South American forest ecosystem. The investigation puts emphasis on the area and stand volume estimation and the development of expansion and reduction factors. Vegetation types are classified and stratified, determining the corresponding areas and estimating the stand volume. Converting factors are developed to calculate C in branches and roots as a percentage of standing wood measured by inventories.

  18. Soil organic carbon response to land abandonment along a pluviometric gradient in Mediterranean conditions (South of Spain).

    NASA Astrophysics Data System (ADS)

    Gabarron-Galeote, Miguel A.; Trigalet, Sylvain; van Wesemael, Bas

    2014-05-01

    Land abandonment has been the most important land use change in Mediterranean region over the last decades. After this conversion, a secondary succession process begins, during which soil organic carbon (SOC) is usually assumed to increase. However, the rate of accumulation strongly depends on climatic conditions and the extent to which precipitation and temperature determine SOC dynamics is largely unknown. The objective of this study is the estimation of SOC dynamic after land abandonment along a pluviometric gradient (1085-650-350 mm y-1). Plots abandoned in different periods (chronosequence) were selected on each site. SOC was determined using a spectrometer and dry combustion, vegetation cover was described, and NDVI, used as indicator of organic matter input to soils, was calculated from LANDSAT images. SOC increased following a logistic model in the two wettest sites, with decreasing accumulation rates as SOC stock approached a plateau. Accumulation rates were proportional to precipitation, being 0.16 for the wettest and 0.03 kg C m-2 y-1 for the intermediate site until reaching the long-term state, in 8 and 49 years respectively. In the driest site no SOC accumulation was measured. SOC and NDVI followed parallel trends along the gradient, so SOC stocks were mainly driven by inputs from vegetation. In addition, on the driest extreme of the gradient, another chronosequence was sampled at high altitude and low temperature. In this case, NDVI evolved following a logistic function but values were not high enough and organic matter input to soil did not trigger SOC accumulation.

  19. The formation of the ocean’s anthropogenic carbon reservoir

    PubMed Central

    Iudicone, Daniele; Rodgers, Keith B.; Plancherel, Yves; Aumont, Olivier; Ito, Takamitsu; Key, Robert M.; Madec, Gurvan; Ishii, Masao

    2016-01-01

    The shallow overturning circulation of the oceans transports heat from the tropics to the mid-latitudes. This overturning also influences the uptake and storage of anthropogenic carbon (Cant). We demonstrate this by quantifying the relative importance of ocean thermodynamics, circulation and biogeochemistry in a global biochemistry and circulation model. Almost 2/3 of the Cant ocean uptake enters via gas exchange in waters that are lighter than the base of the ventilated thermocline. However, almost 2/3 of the excess Cant is stored below the thermocline. Our analysis shows that subtropical waters are a dominant component in the formation of subpolar waters and that these water masses essentially form a common Cant reservoir. This new method developed and presented here is intrinsically Lagrangian, as it by construction only considers the velocity or transport of waters across isopycnals. More generally, our approach provides an integral framework for linking ocean thermodynamics with biogeochemistry. PMID:27808101

  20. The formation of the ocean’s anthropogenic carbon reservoir

    NASA Astrophysics Data System (ADS)

    Iudicone, Daniele; Rodgers, Keith B.; Plancherel, Yves; Aumont, Olivier; Ito, Takamitsu; Key, Robert M.; Madec, Gurvan; Ishii, Masao

    2016-11-01

    The shallow overturning circulation of the oceans transports heat from the tropics to the mid-latitudes. This overturning also influences the uptake and storage of anthropogenic carbon (Cant). We demonstrate this by quantifying the relative importance of ocean thermodynamics, circulation and biogeochemistry in a global biochemistry and circulation model. Almost 2/3 of the Cant ocean uptake enters via gas exchange in waters that are lighter than the base of the ventilated thermocline. However, almost 2/3 of the excess Cant is stored below the thermocline. Our analysis shows that subtropical waters are a dominant component in the formation of subpolar waters and that these water masses essentially form a common Cant reservoir. This new method developed and presented here is intrinsically Lagrangian, as it by construction only considers the velocity or transport of waters across isopycnals. More generally, our approach provides an integral framework for linking ocean thermodynamics with biogeochemistry.

  1. Field Demonstration of Horizontal Infill Drilling Using Cost-effective Integrated Reservoir Modeling--Mississippian Carbonates, Central Kansas

    SciTech Connect

    Saibal Bhattacharya

    2005-08-31

    Mississippian carbonate reservoirs have produced in excess of 1 billion barrels of oil in Kansas accounting for over 16% of the state's production. With declining production from other age reservoirs, the contribution of Mississippian reservoirs to Kansas's oil production has risen to 43% as of 2004. However, solution-enhanced features such as vertical shale intervals extending from the karst erosional surface at the top introduce complexities/compartmentalizations in Mississippian carbonate reservoirs. Coupled with this, strong water drives charge many of these reservoirs resulting in limited drainage from vertical wells due to high water cuts after an initial period of low water production. Moreover, most of these fields are operated by small independent operators without access to the knowledge bank of modern research in field characterization and exploitation/development practices. Thus, despite increasing importance of Mississippian fields to Kansas production, these fields are beset with low recovery factors and high abandonment rates leaving significant resources in the ground. Worldwide, horizontal infill wells have been successful in draining compartmentalized reservoirs with limited pressure depletion. The intent of this project was to demonstrate the application of horizontal wells to successfully exploit the remaining potential in mature Mississippian fields of the mid-continent. However, it is of critical importance that for horizontal wells to be economically successful, they must be selectively targeted. This project demonstrated the application of initial and secondary screening methods, based on publicly available data, to quickly shortlist fields in a target area for detailed studies to evaluate their potential to infill horizontal well applications. Advanced decline curve analyses were used to estimate missing well-level production data and to verify if the well produced under unchanging bottom-hole conditions--two commonly occurring data

  2. CO2 Huff-n-Puff process in a light oil shallow shelf carbonate reservoir. Annual report, January 1, 1995--December 31, 1995

    SciTech Connect

    Wehner, S.C.; Boomer, R.J.; Cole, R.; Preiditus, J.; Vogt, J.

    1996-09-01

    The application of cyclic CO{sub 2}, often referred to as the CO{sub 2} Huff-n-Puff process, may find its niche in the maturing waterfloods of the Permian Basin. Coupling the CO{sub 2} H-n-P process to miscible flooding applications could provide the needed revenue to sufficiently mitigate near-term negative cash flow concerns in the capital intensive miscible projects. Texaco Exploration & Production Inc. and the U.S. Department of Energy have teamed up in an attempt to develop the CO{sub 2} Huff-n-Puff process in the Grayburg/San Andres formation; a light oil, shallow shelf carbonate reservoir within the Permian Basin. This cost-shared effort is intended to demonstrate the viability of this underutilized technology in a specific class of domestic reservoir. A significant amount of oil reserves are located in carbonate reservoirs. Specifically, the carbonates deposited in shallow shelf (SSC) environments make up the largest percentage of known reservoirs within the Permian Basin of North America. Many of these known resources have been under waterflooding operations for decades and are at risk of abandonment if crude oil recoveries cannot be economically enhanced. The selected site for this demonstration project is the Central Vacuum Unit waterflood in Lea County, New Mexico.

  3. Distinguishing Carbonate Reservoir Pore Facies with Nuclear Magnetic Resonance Measurements

    SciTech Connect

    Genty, Coralie; Jensen, Jerry L. Ahr, Wayne M.

    2007-03-15

    Characterization of carbonate rocks may involve identifying the important pore types which are present. In the past, this task has required detailed petrographic analysis of many core samples. Here, we describe a method which uses nuclear magnetic resonance (NMR) measurements to reduce the amount of petrographic analysis needed for porosity typing of carbonate reservoir rocks.For a rock sample which has been measured with NMR, our method decomposes the log(T{sub 2}) spectrum into at most three Gaussian-shaped components and gives a set of nine parameters. Two characteristic quantities having geological significance are extracted from the nine parameters. Values of the two quantities are compared with a reference set, established from samples having both NMR and petrographic evaluations of porosity types. We use a Bayesian approach to the classification of the dominant porosity type.Tests of our method on 103 samples show a correct prediction in 60 to 90 percent of the samples. The lower success rate was obtained for samples with five porosity types from three fields; the higher success rate obtained with samples with three porosity types from one well. The use of geologically significant quantities extracted from the decomposition gives comparable success rate to those obtained using a standard, non-geological approach such as canonical variates.

  4. Enhancement of Terrestrial Carbon Sinks through the Reclamation of Abandoned Mined Lands

    SciTech Connect

    Gary Kronrad

    2004-10-31

    This project will determine the optimal forest management method to employ for each of the major commercial tree species so that profitability of timber production only or the combination of timber production and carbon sequestration is maximized. The goal of this project is to achieve DOE's long-term cost goal of sequestering carbon at $10 or less per ton. Because the potential of a forest ecosystem to sequester carbon depends on the species, site quality and management regimes utilized, this project will determine how to optimize carbon sequestration by determining how to optimally manage each species, given a range of site qualities and economic variables. This project also will determine the effects of a carbon credit market on the method and profitability of forest management, the cost of sequestering carbon, and the amount of carbon that can be sequestered. Information from this project will be used to produce user-friendly manuals which will contain economic and biological data for each of the species. These manuals will inform landowners and forest managers how to manage forests for timber and/or carbon credits, how to maximize financial returns, how much money can be earned, and how much carbon can be stored. Manuals will be disseminated through state and federal agricultural extension services and the forest service of each state, and will be published in forest landowner magazines.

  5. Enhancement of Terrestrial Carbon Sinks through the Reclamation of Abandoned Mined Lands

    SciTech Connect

    Gary Kronrad

    2006-01-31

    This project will determine the optimal forest management method to employ for each of the major commercial tree species so that profitability of timber production only or the combination of timber production and carbon sequestration is maximized. The goal of this project is to achieve DOE's long-term cost goal of sequestering carbon at $10 or less per ton. Because the potential of a forest ecosystem to sequester carbon depends on the species, site quality and management regimes utilized, this project will determine how to optimize carbon sequestration by determining how to optimally manage each species, given a range of site qualities and economic variables. This project also will determine the effects of a carbon credit market on the method and profitability of forest management, the cost of sequestering carbon, and the amount of carbon that can be sequestered. Information from this project will be used to produce user-friendly manuals which will contain economic and biological data for each of the species. These manuals will inform landowners and forest managers how to manage forests for timber and/or carbon credits, how to maximize financial returns, how much money can be earned, and how much carbon can be stored. Manuals will be disseminated through state and federal agricultural extension services and the forest service of each state, and will be published in forest landowner magazines.

  6. Enhancement of Terrestrial Carbon Sinks through the Reclamation of Abandoned Mined Lands

    SciTech Connect

    Gary Kronrad

    2005-04-30

    This project will determine the optimal forest management method to employ for each of the major commercial tree species so that profitability of timber production only or the combination of timber production and carbon sequestration is maximized. The goal of this project is to achieve DOE's long-term cost goal of sequestering carbon at $10 or less per ton. Because the potential of a forest ecosystem to sequester carbon depends on the species, site quality and management regimes utilized, this project will determine how to optimize carbon sequestration by determining how to optimally manage each species, given a range of site qualities and economic variables. This project also will determine the effects of a carbon credit market on the method and profitability of forest management, the cost of sequestering carbon, and the amount of carbon that can be sequestered. Information from this project will be used to produce user-friendly manuals which will contain economic and biological data for each of the species. These manuals will inform landowners and forest managers how to manage forests for timber and/or carbon credits, how to maximize financial returns, how much money can be earned, and how much carbon can be stored. Manuals will be disseminated through state and federal agricultural extension services and the forest service of each state, and will be published in forest landowner magazines.

  7. Enhancement of Terrestrial Carbon Sinks throught the Reclamation of Abandoned Mined Lands

    SciTech Connect

    Gary Kronrad

    2006-06-30

    This project will determine the optimal forest management method to employ for each of the major commercial tree species so that profitability of timber production only or the combination of timber production and carbon sequestration is maximized. The goal of this project is to achieve DOE's long-term cost goal of sequestering carbon at $10 or less per ton. Because the potential of a forest ecosystem to sequester carbon depends on the species, site quality and management regimes utilized, this project will determine how to optimize carbon sequestration by determining how to optimally manage each species, given a range of site qualities and economic variables. This project also will determine the effects of a carbon credit market on the method and profitability of forest management, the cost of sequestering carbon, and the amount of carbon that can be sequestered. Information from this project will be used to produce user-friendly manuals which will contain economic and biological data for each of the species. These manuals will inform landowners and forest managers how to manage forests for timber and/or carbon credits, how to maximize financial returns, how much money can be earned, and how much carbon can be stored. Manuals will be disseminated through state and federal agricultural extension services and the forest service of each state, and will be published in forest landowner magazines.

  8. Developing the aquatic-coupled reservoir model to simulate carbon dioxide emission from a young boreal hydroelectric reservoir

    NASA Astrophysics Data System (ADS)

    Kim, Y.; Roulet, N. T.; Strachan, I. B.; Tremblay, A.

    2013-12-01

    We developed a process-based biogeochemical reservoir model, called AF-DNDC (Aquatic-coupled Forest-DNDC), to project carbon (C) flux from water surface of a recently created hydro-electric reservoir that flooded a boreal landscape. The basis of the reservoir model is Forest-DNDC, a biogeochemical model for C and nitrogen cycling in forests and wetlands. AF-DNDC was developed by coupling a lake C model to a flooded version of Forest-DNDC. AF-DNDC includes the C cycling through the aquatic carbon pools, such as DIC (dissolved inorganic C), DOC (dissolved organic C), and planktonic community as well as C exchange between air, water, and sediment. AF-DNDC was used to examine the net change in carbon dioxide (CO2) exchange between the surface and the atmosphere over the first seven years post flooding of the Eastmain-1 reservoir in northern Quebec. With present day climate and environmental conditions, simulated daily CO2 emissions from the flooded forest averaged 1.69 g C m-2 d-1 (range 0 to 20.49), and from the flooded peatland averaged 0.87 g C m-2 d-1 (range 0 to 6.86). Simulated CO2 emissions decreased with the age of reservoir. They were larger than eddy-covariance measured CO2 fluxes from the water surface over flooded forests, but compared well to the eddy-covariance fluxes during the open-water period. The simulated emissions were significantly correlated with the measured fluxes from the flooded forest (r2 = 0.33; p < 0.01) and flooded peatland (r2 = 0.41; p < 0.01). The patterns over the year were similar. AF-DNDC is suitable for use to assess the major changes in CO2 exchange due to the creation of reservoirs in boreal regions.

  9. Temperature-pressure conditions in coalbed methane reservoirs of the Black Warrior basin: Implications for carbon sequestration and enhanced coalbed methane recovery

    USGS Publications Warehouse

    Pashin, J.C.; McIntyre, M.R.

    2003-01-01

    equilibrate toward a normal hydrostatic pressure gradient after abandonment. Coal can hold large quantities of carbon dioxide under supercritical conditions, and supercritical isotherms indicate non-Langmiur conditions under which some carbon dioxide may remain mobile in coal or may react with formation fluids or minerals. Hence, carbon sequestration and enhanced coalbed methane recovery show great promise in subcritical reservoirs, and additional research is required to assess the behavior of carbon dioxide in coal under supercritical conditions where additional sequestration capacity may exist. ?? 2003 Elsevier Science B.V. All rights reserved.

  10. Application of Reservoir Characterization and Advanced Technology to Improve Recovery and Economics in a Lower Quality Shallow Shelf Carbonate Reservoir, Class II

    SciTech Connect

    Hickman, T. Scott; Justice, James J.; Egg, Rebecca

    2001-08-07

    The Oxy operated Class 2 Project at West Welch Project is designed to demonstrate how the use of advanced technology can improve the economics of miscible CO2 injection projects in lower quality Shallow Shelf Carbonate reservoirs. The research and design phase (Budget Period 1) primarily involved advanced reservoir demonstration characterization. The current demonstration phase (Budget Period 2) is the implementation of the reservoir management plan for an optimum miscible CO2 flood design based on the reservoir characterization.

  11. Flood-related, organic-carbon anomalies as possible temporal markers in reservoir bottom sediments

    USGS Publications Warehouse

    Juracek, K.E.

    2004-01-01

    Results of a study of sediment cores from four reservoirs in the upper Mississippi River Basin, USA, indicated that anomalous organic carbon concentrations associated with flood deposits may provide detectable temporal markers in reservoir bottom sediments. Temporal markers are needed for reservoir sediment studies to date sediment layers deposited between the 1963-64 cesium-137 peak and the present. For two of four reservoirs studied, anomalously low organic carbon concentrations were measured for a sample interval in the upper part of a sediment core. The anomalous interval was interpreted to have been deposited during the July 1993 flood that affected a large area of the upper Mississippi River Basin. Potentially, the July 1993 flood deposit may be used as a temporal marker in reservoir bottom sediments in parts of the basin affected by the flood. Several uncertainties remain regarding the viability of organic carbon as a temporal marker including the combination of flood, basin, and reservoir characteristics required to produce a recognizable organic carbon marker in the bottom sediment and the optimal sampling strategy needed to detect the marker in a sediment core. It is proposed that flood duration and basin size may be important factors as to whether or not an anomalous and detectable organic carbon layer is deposited in a reservoir. ?? Copyright by the North American Lake Management Society 2004.

  12. CO2 Huff-n-Puff Process in a Light Oil Shallow Shelf Carbonate Reservoir

    SciTech Connect

    Kovar, Mark; Wehner, Scott

    1998-01-13

    The application of cyclic CO2, often referred to as the CO2 Huff-n-Puff process, may find its niche in the maturing waterfloods of the Permian Basin. Coupling the CO2 Huff-n-Puff process to miscible flooding applications could provide the needed revenue to sufficiently mitigate near-term negative cash flow concerns in the capital-intensive miscible projects. Texaco Exploration & Production Inc. and the U. S. Department of Energy have teamed up in an attempt to develop the CO2 Huff-n-Puff process in the Grayburg and San Andres formations which are light oil, shallow shelf carbonate reservoirs that exist throughout the Permian Basin. This cost-shared effort is intended to demonstrate the viability of this underutilized technology in a specific class of domestic reservoir. A significant amount of oil reserves are located in carbonate reservoirs. Specifically, the carbonates deposited in shallow shelf (SSC) environments make up the largest percentage of known reservoirs within the Permian Basin of North America. Many of these known resources have been under waterflooding operations for decades and are at risk of abandonment if crude oil recoveries cannot be economically enhanced. The selected sites for this demonstration project are the Central Vacuum Unit waterflood in Lea County, New Mexico and the Sundown Slaughter Field in Hockley County, Texas. Miscible CO2 flooding is the process of choice for enhancing recovery of light oils and already accounts for over 12% of the Permian Basin's daily production. There are significant probable reserves associated with future miscible CO2 projects. However, many are marginally economic at current market conditions due to large up-front capital commitments for a peak response, which may be several years in the future. The resulting negative cash-flow is sometimes too much for an operator to absorb. The CO2 Huff-n-Puff process is being investigated as a near

  13. Application of Reservoir Characterization and Advanced Technology to Improve Recovery and Economics in a Lower Quality Shallow Shelf Carbonate Reservoir

    SciTech Connect

    Rebecca Egg

    2002-09-30

    The OXY-operated Class 2 Project at West Welch is designed to demonstrate how the use of advanced technology can improve the economics of miscible CO{sub 2} injection projects in lower quality Shallow Shelf Carbonate reservoirs. The research and design phase (Budget Period 1) primarily involved advanced reservoir characterization. The current demonstration phase (Budget Period 2) is the implementation of the reservoir management plan for an optimum miscible CO{sub 2} flood design based on the reservoir characterization. Although Budget Period 1 for the Project officially ended 12/31/96, reservoir characterization and simulation work continued during the Budget Period 2. During the fifth and sixth annual reporting periods (8/3/98-8/2/00) covered by this report, work continued on interpretation of the cross well seismic data to create porosity and permeability profiles which were distributed into the reservoir geostatistically. The initial interwell seismic CO{sub 2} monitor survey was conducted, the acquired data processed and interpretation started. Only limited well work and facility construction was conducted in the project area. The CO{sub 2} injection initiated in October 1997 was continued, although the operator had to modify the operating plan in response to low injection rates, well performance and changes in CO{sub 2} supply. CO{sub 2} injection was focused in a smaller area to increase the reservoir processing rate. By the end of the reporting period three producers had shown sustained oil rate increases and ten wells had experienced gas (CO{sub 2}) breakthrough.

  14. FOREST ECOSYSTEM CARBON AND NITROGEN ACCUMULATION DURING THE FIRST CENTURY AFTER AGRICULTURAL ABANDONMENT

    EPA Science Inventory

    Forests of the northeastern U.S. are expected to serve as a substantial sink for carbon (C) and nitrogen (N) as they recover from extensive clearing and agriculture. However, questions remain concerning the rate, distribution and duration of this potential sink. We used a chron...

  15. Carbon Dioxide Emissions from Reservoirs in the Lower Jordan Watershed

    PubMed Central

    Alshboul, Zeyad; Lorke, Andreas

    2015-01-01

    We have analyzed monthly hydrological, meteorological and water quality data from three irrigation and drinking water reservoirs in the lower Jordan River basin and estimated the atmospheric emission rates of CO2. The data were collected between 2006 and 2013 and show that the reservoirs, which differ in size and age, were net sources of CO2. The estimated surface fluxes were comparable in magnitude to those reported for hydroelectric reservoirs in the tropical and sub-tropical zones. Highest emission rates were observed for a newly established reservoir, which was initially filled during the sampling period. In the two older reservoirs, CO2 partial pressures and fluxes were significantly decreasing during the observation period, which could be related to simultaneously occurring temporal trends in water residence time and chemical composition of the water. The results indicate a strong influence of water and reservoir management (e.g. water consumption) on CO2 emission rates, which is affected by the increasing anthropogenic pressure on the limited water resources in the study area. The low wind speed and relatively high pH favored chemical enhancement of the CO2 gas exchange at the reservoir surfaces, which caused on average a four-fold enhancement of the fluxes. A sensitivity analysis indicates that the uncertainty of the estimated fluxes is, besides pH, mainly affected by the poorly resolved wind speed and resulting uncertainty of the chemical enhancement factor. PMID:26588241

  16. Carbon Dioxide Emissions from Reservoirs in the Lower Jordan Watershed.

    PubMed

    Alshboul, Zeyad; Lorke, Andreas

    2015-01-01

    We have analyzed monthly hydrological, meteorological and water quality data from three irrigation and drinking water reservoirs in the lower Jordan River basin and estimated the atmospheric emission rates of CO2. The data were collected between 2006 and 2013 and show that the reservoirs, which differ in size and age, were net sources of CO2. The estimated surface fluxes were comparable in magnitude to those reported for hydroelectric reservoirs in the tropical and sub-tropical zones. Highest emission rates were observed for a newly established reservoir, which was initially filled during the sampling period. In the two older reservoirs, CO2 partial pressures and fluxes were significantly decreasing during the observation period, which could be related to simultaneously occurring temporal trends in water residence time and chemical composition of the water. The results indicate a strong influence of water and reservoir management (e.g. water consumption) on CO2 emission rates, which is affected by the increasing anthropogenic pressure on the limited water resources in the study area. The low wind speed and relatively high pH favored chemical enhancement of the CO2 gas exchange at the reservoir surfaces, which caused on average a four-fold enhancement of the fluxes. A sensitivity analysis indicates that the uncertainty of the estimated fluxes is, besides pH, mainly affected by the poorly resolved wind speed and resulting uncertainty of the chemical enhancement factor.

  17. Carbon dioxide storage in unconventional reservoirs workshop: summary of recommendations

    USGS Publications Warehouse

    Jones, Kevin B.; Blondes, Madalyn S.

    2015-01-01

    The storage capacity for all unconventional reservoirs may be modeled using a volumetric equation starting with the extent of the rock unit and adjusted using these key factors and reaction terms. The ideas that were developed during this workshop can be used by USGS scientists to develop a methodology to assess the CO2 storage resource in unconventional reservoirs. This methodology could then be released for public comment and peer review. After completing this development process, the USGS could then use the methodology to assess the CO2 storage resource in unconventional reservoirs.

  18. How 3-D, 3-C seismic characterized a carbonate reservoir

    SciTech Connect

    Arestad, J.F.; Mattocks, B.W.; Davis, T.L.; Benson, R.D.

    1995-04-01

    The Reservoir Characterization Project (RCP) at the Colorado School of Mines has pioneered research into 3-D, 3-C (multicomponent) reflection seismology for nearly a decade utilizing both P-wave and S-wave sources. Multicomponent-seismic surveys provide significantly more information about petroleum reservoirs than compressional-wave surveys. Initial 3-D, 3-C surveys acquired by RCP were targeted at characterizing naturally fractured reservoirs. The current phase of the project is oriented towards utilizing shear waves to discriminate lithologic and diagenetic changes within stratigraphic reservoirs where compressional-seismic data has not be effective. The Joffre field, Nisku reservoir, is the site of RCP`s ongoing multidisciplinary research effort in Western Canada. The research team is directed by Colorado School of Mines faculty with graduate team members from geology, geophysics and petroleum engineering departments. While this study is still in progress, some key findings and directions of this research are reported here. The following topics will be discussed: Joffre field 3-D, 3-C survey; compressional wave 3-D technique; shear-wave 3-D technique; converted-wave 3-D technique; reservoir characterization, and future directions.

  19. Imaging and characterization of a carbonate hydrocarbon reservoir analogue using GPR attributes

    NASA Astrophysics Data System (ADS)

    Forte, E.; Pipan, M.; Casabianca, D.; Di Cuia, R.; Riva, A.

    2012-06-01

    We adapt and test seismic attributes techniques on a 2-D and 3-D multi-frequency GPR dataset recorded in an abandoned limestone quarry, analogous to a specific set of hydrocarbon reservoirs. Our main objective was to image the vertical and lateral lithological variations, the network of stratigraphic joints and fractures and to characterize the rock mass based on the radar response. We apply semi-automatic horizon mapping techniques using manually picked seeds (control points) on selected attributes, and automatic extrapolation both on in-line and cross-line, starting from seed positions. We also apply Principal Component Analysis (PCA) and cluster analysis on group data with similar multi-attribute response to reduce the total number of calculated attributes by minimizing the interpreter's bias. We compare and validate the results with direct outcrop measures, imaging a hydrocarbon reservoir analogue in 3-D to over 10 m beneath the topographic surface.

  20. Reservoir zonation in Silurian-Devonian carbonates of Wells field, Dawson County, Texas

    SciTech Connect

    Mazzullo, L.J. )

    1992-04-01

    Wells field in Dawson County, Texas, has produced over 7.5 million bbl since 1955 from Silurian-Devonian carbonates. Although originally classified as a Devonian field, production there actually is out of the Silurian Wristen and Fusselman formations. Wells field is an extremely complex system of structured and stratigraphic reservoirs not easily characterized by traditional subsurface mapping techniques. Detailed lithologic analyses of well cuttings from 29 wells in and around this field were done to evaluate reservoir zonation and potentials for either new field development wells, or recompletions from existing well bores. These analyses have shown that paleotopographic highs on the Fusselman unconformity across the field created optimum sites for Fusselman dolomite reservoir development, and collateral development of Wristen reservoirs. The Wristen reservoirs are in the form of porous carbonate mounds that grew adjacent to the paleotopographically high areas, or simple compactionally fractured cherty carbonates over these highs. The recognition of Fusselman paleotopography in most wells is implied by thickness and facies changes in the overlying Wristen section. A certain amount of structure and facies-induced reservoir separation has been documented. The results of this study have been used to identify several areas of the field where each of the three reservoirs could be exploited for underdeveloped reserves.

  1. IMPACT OF FOREST HARVESTING ON RESERVOIRS AND LAKES: CARBON DYNAMICS AND MICROBIAL CYCLING

    NASA Astrophysics Data System (ADS)

    Ouellet, A.; Tremblay, L.; Lucotte, M. M.; Gelinas, Y.

    2009-12-01

    Boreal lakes and reservoirs are net heterotrophic systems. Differences in dissolved CO2 concentrations between man-made reservoirs and natural lakes suggest higher CO2 fluxes to the atmosphere from reservoirs than from lakes; human-induced perturbations such as deforestation also induce changes to the carbon cycle in aquatic systems. We used bulk analytical techniques to better characterize the impact of reservoir formation and deforestation on the processes controlling the cycling of organic carbon in boreal aquatic systems. The water column of natural and deforested lakes and reservoirs was analyzed for dissolved and particulate organic matter (DOM and POM, respectively), dissolved inorganic carbon (DIC), oxygen saturation and CO2. Atomic C:N ratios, δ13Corg, δ15Ntot and amino acids biomarkers analyses were also carried out on DOM and POM. Differences in carbon concentration, atomic C/N ratios and δ13Corg reflect the impact of deforestation on the quality and quantity of OM found in lakes and reservoirs. Water-column profiles of δ13C-DIC and δ13C-POM show large variability with perturbation indicating that there are differences in the biogeochemical processes that control carbon cycling in the different environments. These findings along with amino acids analyses show that inputs of terrestrial dissolved organic nitrogen and carbon better stimulates bacterial growth than algal activities, which results in increased aqueous CO2 concentrations and fluxes to the atmosphere. A statistical analysis of the biomarkers suggests contrasting DOM/POM sources and degradation pathways with wood harvesting and reservoir operation. Human-induced land use and hydrological modifications drive the carbon cycle of fresh water systems, which in turn modulates green house gas emissions to the atmosphere.

  2. IMPROVED OIL RECOVERY IN MISSISSIPPIAN CARBONATE RESERVOIRS OF KANSAS - NEAR TERM - CLASS 2

    SciTech Connect

    Timothy R. Carr; Don W. Green; G. Paul Willhite

    2000-04-30

    This annual report describes progress during the final year of the project entitled ''Improved Oil Recovery in Mississippian Carbonate Reservoirs in Kansas''. This project funded under the Department of Energy's Class 2 program targets improving the reservoir performance of mature oil fields located in shallow shelf carbonate reservoirs. The focus of the project was development and demonstration of cost-effective reservoir description and management technologies to extend the economic life of mature reservoirs in Kansas and the mid-continent. As part of the project, tools and techniques for reservoir description and management were developed, modified and demonstrated, including PfEFFER spreadsheet log analysis software. The world-wide-web was used to provide rapid and flexible dissemination of the project results through the Internet. A summary of demonstration phase at the Schaben and Ness City North sites demonstrates the effectiveness of the proposed reservoir management strategies and technologies. At the Schaben Field, a total of 22 additional locations were evaluated based on the reservoir characterization and simulation studies and resulted in a significant incremental production increase. At Ness City North Field, a horizontal infill well (Mull Ummel No.4H) was planned and drilled based on the results of reservoir characterization and simulation studies to optimize the location and length. The well produced excellent and predicted oil rates for the first two months. Unexpected presence of vertical shale intervals in the lateral resulted in loss of the hole. While the horizontal well was not economically successful, the technology was demonstrated to have potential to recover significant additional reserves in Kansas and the Midcontinent. Several low-cost approaches were developed to evaluate candidate reservoirs for potential horizontal well applications at the field scale, lease level, and well level, and enable the small independent producer to identify

  3. Jurassic carbonate reservoirs of the Amu Darya Basin, Uzbekistan and Turkmenistan

    SciTech Connect

    Shein, V.S.; Fortunatova, N.K.; Neilson, J.E.

    1995-08-01

    The Amu Darya Basin is a world class hydrocarbon province. Current reserves estimates are 220 TCF of gas and 800 MMbbl of oil and condensate, 50% of which is reservoired in Late Jurassic carbonates. Exploration opportunities still exist in large parts of the basin which are relatively undrilled. Within the 100-600m thick carbonate sequence, reservoir facies include reefs, shelf grainstones and turbidite fares. The major seal are Kimmeridgian - Tithonian evaporates which are up to 1600m thick in the basin centre. Stratigraphic trapping is common and often enhanced by structural modifications. The reservoirs are in communication with a major gas-prone Early-Middle Jurassic source rock. Oil-prone source rocks are thought to occur in basinal sediments which are coeval with the Late Jurassic reservoirs. Carbonate sedimentation commenced during the Late Jurassic with the development of a ramp complex. This evolved into a rimmed shelf with barrier and pinnacle reefs. Several cycles of relative sea-level change (largely eustatic?) influence the carbonate ramp/shelf systems and effect the distribution of reservoir facies. Numerous empirical observations by VNIGNI scientists on carbonate successions have enabled them to develop mathematically calculated indices for facies and reservoir prediction, which have been applied successfully in the Amu Darya Basin. Reservoir quality in the limestones is strongly controlled by primary facies. Reefs and shelf grainstones display the best reservoir characteristics. Whilst many facies have good total porosity, it is only the reef and grainstone belts where connected porosity (with pore throats greater than 10um) becomes effective. Burial cements are rare. Freshwater solution and cementation has often improved or preserved primary porosity.

  4. The lower Miocene Liuhua carbonate reservoir, Pearl River Mouth basin, offshore People's Republic of China

    SciTech Connect

    Turner, N.L. )

    1990-06-01

    Since the drilling in January 1987 of the Amoco Liuhua 11-1-1A discovery well located 220 km southeast of Hong Kong, five additional wells have drilled and tested this lower Miocene Zhujiang Formation carbonate reservoir. Deposition of upper Zhujiang carbonates in the Liuhua area took place in an isolated platform environment. Major facies are (1) a platform-rim reef composed of red algae and coral boundstones, (2) a back-reef lagoon of fine-grained carbonates, (3) a large interior platform bank dominated by red algae but with a red algal-coral fringe on the south and southwest sides, (4) platform grainrocks, and (5) platform to lagoonal mud-supported carbonates. A paleo-water table surface present in every well represents a time of regional exposure. The reservoir is subdivided into five diagenetic carbonate units that are correlated across the platform and that cross facies boundaries and inferred time lines. The uppermost unit is a thin, tightly cemented carbonate formed at the time of drowning of the platform. Two thick highly leached carbonate units with porosities and permeabilities as high as 30% and several darcys comprise most of the reservoir. They are separated by a thin (7 m) tighter interval that formed by cementation below the water table of an exposure surface. The less porous unit at the base of the reservoir formed as a result of interaction between oil and water causing calcite cementation. Leaching continued in the carbonate below the reservoir and biodegradation occurred after oil had filled the structure. Further drilling and testing will determine the limits of the diagenetic units and whether the reservoir has commercial potential.

  5. Modeling dolomitized carbonate-ramp reservoirs: A case study of the Seminole San Andres unit. Part 2 -- Seismic modeling, reservoir geostatistics, and reservoir simulation

    SciTech Connect

    Wang, F.P.; Dai, J.; Kerans, C.

    1998-11-01

    In part 1 of this paper, the authors discussed the rock-fabric/petrophysical classes for dolomitized carbonate-ramp rocks, the effects of rock fabric and pore type on petrophysical properties, petrophysical models for analyzing wireline logs, the critical scales for defining geologic framework, and 3-D geologic modeling. Part 2 focuses on geophysical and engineering characterizations, including seismic modeling, reservoir geostatistics, stochastic modeling, and reservoir simulation. Synthetic seismograms of 30 to 200 Hz were generated to study the level of seismic resolution required to capture the high-frequency geologic features in dolomitized carbonate-ramp reservoirs. Outcrop data were collected to investigate effects of sampling interval and scale-up of block size on geostatistical parameters. Semivariogram analysis of outcrop data showed that the sill of log permeability decreases and the correlation length increases with an increase of horizontal block size. Permeability models were generated using conventional linear interpolation, stochastic realizations without stratigraphic constraints, and stochastic realizations with stratigraphic constraints. Simulations of a fine-scale Lawyer Canyon outcrop model were used to study the factors affecting waterflooding performance. Simulation results show that waterflooding performance depends strongly on the geometry and stacking pattern of the rock-fabric units and on the location of production and injection wells.

  6. Calculation of hydrocarbon-in-place in gas and gas-condensate reservoirs - Carbon dioxide sequestration

    USGS Publications Warehouse

    Verma, Mahendra K.

    2012-01-01

    The Energy Independence and Security Act of 2007 (Public Law 110-140) authorized the U.S. Geological Survey (USGS) to conduct a national assessment of geologic storage resources for carbon dioxide (CO2), requiring estimation of hydrocarbon-in-place volumes and formation volume factors for all the oil, gas, and gas-condensate reservoirs within the U.S. sedimentary basins. The procedures to calculate in-place volumes for oil and gas reservoirs have already been presented by Verma and Bird (2005) to help with the USGS assessment of the undiscovered resources in the National Petroleum Reserve, Alaska, but there is no straightforward procedure available for calculating in-place volumes for gas-condensate reservoirs for the carbon sequestration project. The objective of the present study is to propose a simple procedure for calculating the hydrocarbon-in-place volume of a condensate reservoir to help estimate the hydrocarbon pore volume for potential CO2 sequestration.

  7. Major influencing factors of water flooding in abnormally high-pressure carbonate reservoir

    NASA Astrophysics Data System (ADS)

    Qingying, Hou; Kaiyuan, Chen; Zifei, Fan; Libing, Fu; Yefei, Chen

    2017-01-01

    The higher pressure coefficient is the major characteristics of the abnormal high pressure carbonate reservoirs, which the pressure coefficient generally exceeds 1.2 and the initial formation pressure is higher than normal sandstone reservoirs. Due to the large pressure difference between initial formation and saturated pressure, oil wells are capable to production with high flow rate by the natural energy at early production stage. When the formation pressure drops to the saturation pressure, the water or gas is usually injected to stabilize the well productivity and sustain the formation pressure. Based on the characteristics of Kenkiak oilfield, a typical abnormal high pressure carbonate reservoir, a well group model is designed to simulate and analyze the influence factors on water flooding. The conclusion is that permeability, interlayer difference and reserve abundance are the main three factors on the water flooding development in these reservoirs.

  8. Seasonal Changes in Plankton Food Web Structure and Carbon Dioxide Flux from Southern California Reservoirs

    PubMed Central

    Adamczyk, Emily M.; Shurin, Jonathan B.

    2015-01-01

    Reservoirs around the world contribute to cycling of carbon dioxide (CO2) with the atmosphere, but there is little information on how ecosystem processes determine the absorption or emission of CO2. Reservoirs are the most prevalent freshwater systems in the arid southwest of North America, yet it is unclear whether they sequester or release CO2 and therefore how water impoundment impacts global carbon cycling. We sampled three reservoirs in San Diego, California, weekly for one year. We measured seasonal variation in the abundances of bacteria, phytoplankton, and zooplankton, as well as water chemistry (pH, nutrients, ions, dissolved organic carbon [DOC]), which were used to estimate partial pressure of CO2 (pCO2), and CO2 flux. We found that San Diego reservoirs are most often undersaturated with CO2 with respect to the atmosphere and are estimated to absorb on average 3.22 mmol C m-2 day-1. pCO2 was highest in the winter and lower in the summer, indicating seasonal shifts in the magnitudes of photosynthesis and respiration associated with day length, temperature and water inputs. Abundances of microbes (bacteria) peaked in the winter along with pCO2, while phytoplankton, nutrients, zooplankton and DOC were all unrelated to pCO2. Our data indicate that reservoirs of semi-arid environments may primarily function as carbon sinks, and that carbon flux varies seasonally but is unrelated to nutrient or DOC availability, or the abundances of phytoplankton or zooplankton. PMID:26473601

  9. Seasonal Changes in Plankton Food Web Structure and Carbon Dioxide Flux from Southern California Reservoirs.

    PubMed

    Adamczyk, Emily M; Shurin, Jonathan B

    2015-01-01

    Reservoirs around the world contribute to cycling of carbon dioxide (CO2) with the atmosphere, but there is little information on how ecosystem processes determine the absorption or emission of CO2. Reservoirs are the most prevalent freshwater systems in the arid southwest of North America, yet it is unclear whether they sequester or release CO2 and therefore how water impoundment impacts global carbon cycling. We sampled three reservoirs in San Diego, California, weekly for one year. We measured seasonal variation in the abundances of bacteria, phytoplankton, and zooplankton, as well as water chemistry (pH, nutrients, ions, dissolved organic carbon [DOC]), which were used to estimate partial pressure of CO2 (pCO2), and CO2 flux. We found that San Diego reservoirs are most often undersaturated with CO2 with respect to the atmosphere and are estimated to absorb on average 3.22 mmol C m(-2) day(-1). pCO2 was highest in the winter and lower in the summer, indicating seasonal shifts in the magnitudes of photosynthesis and respiration associated with day length, temperature and water inputs. Abundances of microbes (bacteria) peaked in the winter along with pCO2, while phytoplankton, nutrients, zooplankton and DOC were all unrelated to pCO2. Our data indicate that reservoirs of semi-arid environments may primarily function as carbon sinks, and that carbon flux varies seasonally but is unrelated to nutrient or DOC availability, or the abundances of phytoplankton or zooplankton.

  10. Karst-controlled reservoir heterogeneity in Ellenburger group carbonates of west Texas

    SciTech Connect

    Kerans, C.

    1988-10-01

    Petroleum production from restricted shelf carbonates of the Lower Ordovician Ellenburger group is commonly considered to have been a result of a pervasive, relatively homogeneous tectonic fracture system within the reservoir rock. However, regional facies and diagenetic (paleokarst) studies of Ellenburger strata, based on cores and wireline logs, have demonstrated that significant reservoir compartmentalization was caused by karst modification in the upper part of the unit. 19 figures.

  11. Improved Oil Recovery in Mississippian Carbonate Reservoirs of Kansas -- Near-Term -- Class 2

    SciTech Connect

    Carr, Timothy R.; Green, Don W.; Willhite, G. Paul

    1999-07-08

    This report describes progress during the third year of the project entitled ''Improved Oil Recovery in Mississippian Carbonate Reservoirs in Kansas''. This project funded under the Department of Energy's Class 2 program targets improving the reservoir performance of mature oil fields located in shallow shelf carbonate reservoirs. The focus of this project is development and demonstration of cost-effective reservoir description and management technologies to extend the economic life of mature reservoirs in Kansas and mid-continent. The project introduced a number of potentially useful technologies, and demonstrated these technologies in actual oil field operations. Advanced technology was tailored specifically to the scale appropriate to the operations of Kansas producers. An extensive technology transfer effort is ongoing. Traditional technology transfer methods (e.g., publications and workshops) are supplemented with a public domain relational database and an online package of project results that is available through the Internet. The goal is to provide the independent complete access to project data, project results and project technology on their desktop. Included in this report is a summary of significant project results at the demonstration site (Schaben Field, Ness County, Kansas). The value of cost-effective techniques for reservoir characterization and simulation at Schaben Field were demonstrated to independent operators. All major operators at Schaben have used results of the reservoir management strategy to locate and drill additional infill locations. At the Schaben Demonstration Site, the additional locations resulted in incremental production increases of 200 BOPD from a smaller number of wells.

  12. IMPROVED OIL RECOVERY IN MISSISSIPPIAN CARBONATE RESERVOIRS OF KANSAS--NEAR TERM--CLASS 2

    SciTech Connect

    Timothy R. Carr; Don W. Green; G. Paul Willhite

    1999-06-01

    This annual report describes progress during the third year of the project entitled ''Improved Oil Recovery in Mississippian Carbonate Reservoirs in Kansas''. This project funded under the Department of Energy's Class 2 program targets improving the reservoir performance of mature oil fields located in shallow shelf carbonate reservoirs. The focus of this project is development and demonstration of cost-effective reservoir description and management technologies to extend the economic life of mature reservoirs in Kansas and the mid-continent. The project introduced a number of potentially useful technologies, and demonstrated these technologies in actual oil field operations. Advanced technology was tailored specifically to the scale appropriate to the operations of Kansas producers. An extensive technology transfer effort is ongoing. Traditional technology transfer methods (e.g., publications and workshops) are supplemented with a public domain relational database and an online package of project results that is available through the Internet. The goal is to provide the independent complete access to project data, project results and project technology on their desktop. Included in this report is a summary of significant project results at the demonstration site (Schaben Field, Ness County, Kansas). The value of cost-effective techniques for reservoir characterization and simulation at Schaben Field were demonstrated to independent operators. All major operators at Schaben have used results of the reservoir management strategy to locate and drill additional infill locations. At the Schaben Demonstration Site, the additional locations resulted in incremental production increases of 200 BOPD from a smaller number of wells.

  13. Probe imaging studies of magnetic susceptibility and permeability for sensitive characterisation of carbonate reservoir rocks

    NASA Astrophysics Data System (ADS)

    Ivakhnenko, Aleksandr; Bigaliyeva, Akmaral; Dubinin, Vladislav

    2016-04-01

    In this study were disclosed the main principals of identifying petrophysical properties of carbonate reservoirs such as porosity, permeability and magnetic susceptibility. While exploring and developing reservoir there are significant diversity of tasks that can be solved by appropriate knowledge of properties which are listed above. Behavior of fluid flow, distribution of hydrocarbons and other various industrial applications can be solved by measuring areal distribution of these petrophysical parameters. The results demonstrate how magnetic probe and hysteresis measurements correlate with petrophysical parameters in carbonate reservoirs. We made experimental measurements and theoretical calculations of how much magnetic susceptibility depends on the porosity of the rocks and analyzed data with graphics. In theoretical model of the carbonate rocks we considered calcite, dolomite, quartz and combinations of calcite and dolomite, calcite and Fe-dolomite, calcite and quartz, calcite and aragonite with increasing concentrations of the dolomite, Fe-dolomite, quartz and aragonite up to 50% with step of 5%. Here we defined dependence of magnetic susceptibility from the porosity: the higher porosity measurements, the less slope of magnetic susceptibility, consequently mass magnetization is higher for diamagnetic and lower for paramagnetic carbonate rocks, but in the both cases magnetic susceptibility tries to reach zero with increasing of the total porosity. Rock measurements demonstrate that reservoir zones of the low diamagnetic magnetic susceptibility are generally correlated with higher permeability and also porosity distribution. However for different carbonate reservoirs we establish different relationships depending on the complexity of their mineralogy and texture. Application of integral understanding in distribution of permeability, porosity and mineral content in heterogeneous carbonates represented by this approach can be useful tool for carbonate reservoir

  14. Soil carbon sequestration or biofuel production: new land-use opportunities for mitigating climate over abandoned Soviet farmlands.

    PubMed

    Vuichard, Nicolas; Ciais, Philippe; Wolf, Adam

    2009-11-15

    Although the CO(2) mitigation potential of biofuels has been studied by extrapolation of small-scale studies, few estimates exist of the net regional-scale carbon balance implications of biofuel cultivations programs, either growing conventional biofuel crops or applying new advanced technologies. Here we used a spatially distributed process-driven model over the 20 Mha of recently abandoned agricultural lands of the Former Soviet Union to quantify the GHG mitigation by biofuel production from Low Input/High Diversity (LIHD) grass-legume prairies and to compare this GHG mitigation with the one of soil C sequestration as it currently occurs. LIHD has recently received a lot of attention as an emerging opportunity to produce biofuels over marginal lands leading to a good energy efficiency with minimal adverse consequences on food security and ecosystem services. We found that, depending on the time horizon over which one seeks to maximize the GHG benefit, the optimal time for implementing biofuel production shifts from "never" (short-term horizon) to "as soon as possible" (longer-term horizon). These results highlight the importance of reaching agreement a priori on the target time interval during which biofuels are expected to play a role within the global energy system, to avoid deploying biofuel technology over a time interval for which it has a detrimental impact on the GHG mitigation objective. The window of opportunity for growing LIHD also stresses the need to reduce uncertainties in soil C inputs, turnover, and soil organic matter stability under current and future climate and management practices.

  15. CO{sub 2} Huff-n-Puff process in a light oil shallow shelf carbonate reservoir. Quarterly technical progress report, 3rd quarter, 1994

    SciTech Connect

    Wehner, S.; Smith, V.; Cole, R.; Brugman, B.; Vogt, J.

    1994-10-18

    The principal objective of the Central Vacuum Unit (CVU) CO{sub 2} Huff-n-Puff (H-n-P) project is to determine the feasibility and practicality of the technology in a waterflooded shallow shelf carbonate environment. The results of parametric simulation of the CO{sub 2} H-n-P process, coupled with the CVU reservoir characterization components will determine if this process is technically and economically feasible for field implementation. The technology transfer objective of the project is to disseminate the knowledge gained through an innovative plan in support of the Department of Energy`s (DOE) objective of increasing domestic oil production and deferring the abandonment of shallow shelf carbonate (SSC) reservoirs. Texaco Exploration and Production Inc`s. (TEPI) long-term plans are to implement a full-scale miscible CO{sub 2} project in the CVU. However, the current market precludes acceleration of such a capital intensive project. The DOE partnership provides some relief to the associated R and D risks, allowing TEPI to evaluate a proven Gulf-coast sandstone technology in a waterflooded carbonate environment. Technical progress is described on the following studies: Porosity and permeability relationships; Initial water saturation and oil-water contact; Geostatistical realization; and Parametric simulation.

  16. The use of coiled tubing during matrix acidizing of carbonate reservoirs

    SciTech Connect

    Thomas, R.L.; Milne, A.

    1995-10-01

    A laboratory and field study directed at improved well performance of horizontal wells is discussed. During the study, several wells were matrix acidized using bullhead and coiled tubing placement techniques. The study performed in carbonate reservoirs indicates acid placed with coiled tubing diverted with foam provides excellent zone coverage and damage removal. Conventional bullhead techniques do not result in effective damage removal. The study emphasizes the evaluation of the treatment results and the development of improved acidizing techniques. Laboratory simulations of matrix acidizing indicate proper placement techniques are essential. This observation is supported by field data in oil wells completed in carbonate reservoirs. The key to successful damage removal is (1) the placement of acid via coiled tubing and (2) proper diversion. Production logging and well performance data support this claim. The proposed treatment is applicable in both horizontal and vertical wells completed in carbonate reservoirs.

  17. Facies dimensions within carbonate reservoirs - guidelines from satellite images of modern analogs

    SciTech Connect

    Harris, P.M.; Kowalik, W.S.

    1995-08-01

    Modern analogs illustrate the distribution of carbonate facies within an overall depositional setting and can be an integral part of a subsurface geologic model in indicating the dimensions, trend, and interrelationships of facies that might be related to reservoir and non-reservoir distribution. Satellite images from several modern carbonate areas depict the geologic characteristics that can be expected in ancient shallow-water settings. Isolated carbonate platforms- the Bahamas, Caicos Platform in the British West Indies, Chinchorro Bank offshore of Yucatan, and portions of the Belize area; Ramp-style shelf-to-basin transitions - Abu Dhabi and northern Yucatan; Rimmed shelf margins - South Florida, portions of Belize, and the Great Barrier Reef of Australia; Broad, deep shelf lagoons - the Great Barrier Reef and Belize; Reef variability - South Florida, the Bahamas, Caicos, Northern Yucatan, and Abu Dhabi; Shallow lagoon/tidal flat settings - South Florida, the Bahamas, Caicos, Northern Yucatan, Shark Bay in Western Australia, Abu Dhabi; Mixed carbonate and siliciclastic depostion - South Florida, Belize, the Great Barrier Reef, Shark Bay and Abu Dhabi. The geologic framework as illustrated by these areas is important at the development scale where lateral variation of porosity and permeability, i.e. reservoir quality, is commonly tied to facies changes and facies dimensions are required as input to reservoir models. The geologic framework is essential at the exploration scale for reservoir facies prediction and stratigraphic play concepts which are related directly to depositional facies patterns.

  18. Organic carbon isotope constraints on the dissolved organic carbon (DOC) reservoir at the Cryogenian-Ediacaran transition

    NASA Astrophysics Data System (ADS)

    Jiang, Ganqing; Wang, Xinqiang; Shi, Xiaoying; Zhang, Shihong; Xiao, Shuhai; Dong, Jin

    2010-10-01

    Prominent negative carbonate carbon isotope (δ 13C carb) anomalies from some Ediacaran successions are accompanied by invariant or decoupled organic carbon isotope (δ 13C org) values and have been interpreted as resulting from the remineralization of a large dissolved organic carbon (DOC) reservoir capable of buffering carbon isotopes of organic matter. This inferred oceanic DOC reservoir was thought to have initiated with the onset of Cryogenian glaciations (ca. 720 Ma) and lasted for millions of years until the late Ediacaran Period (< 560 Ma). Carbon isotope analyses of the basal Doushantuo Formation (ca. 635 Ma) in south China reveal that (1) the cap carbonate has δ 13C org around -26‰ (VPDB) and relatively low Δδ 13C (22 ± 2‰) and (2) the overlying organic-rich black shale and shaly dolostone have more negative δ 13C org (-28‰ to -35‰) and higher Δδ 13C (28‰-30‰). Both δ 13C carb and δ 13C org show a + 6‰ shift within a 4-m-thick interval overlying the Doushantuo cap carbonate. The δ 13C org values of the cap carbonate are associated with low TOC (mostly < 0.1%); their paleoceanographic significance requires further tests in other Ediacaran basins. The co-varying positive shift in δ 13C carb and δ 13C org following cap carbonate deposition is best interpreted as resulting from a rapid increase in organic carbon burial, which may have resulted in the rise of oxygen and heralded the first appearance of animals a few meters above the Doushantuo cap carbonate. The data suggest that a large oceanic DOC reservoir did not exist in the early Ediacaran ocean. Excess oceanic DOC required to explain the Ediacaran Shuram and upper Doushantuo δ 13C excursions, if it existed, had to be developed during the Ediacaran Period after cap carbonate deposition.

  19. Observational evidence for an active surface reservoir of solid carbon dioxide on Mars.

    PubMed

    Malin, M C; Caplinger, M A; Davis, S D

    2001-12-07

    High-resolution images of the south polar residual cap of Mars acquired in 1999 and 2001 show changes in the configuration of pits, intervening ridges, and isolated mounds. Escarpments have retreated 1 to 3 meters in 1 martian year, changes that are an order of magnitude larger than can be explained by the sublimation of water ice, but close to what is expected for sublimation of carbon dioxide ice. These observations support a 35-year-old conjecture that Mars has a large surface reservoir of solid carbon dioxide. The erosion implies that this reservoir is not in equilibrium with the present environment and that global climate change is occurring on Mars.

  20. Advanced Characterization of Fractured Reservoirs in Carbonate Rocks: The Michigan Basin

    SciTech Connect

    Wood, J.R.; Harrison, W.B.

    2001-01-22

    The main objective of this project is for a university-industry consortium to develop a comprehensive model for fracture carbonate reservoirs based on the ''data cube'' concept using the Michigan Basin as a prototype. This project combined traditional historical data with 2D and 3D seismic data as well as data from modern logging tools in a novel way to produce a new methodology for characterizing fractured reservoirs in carbonate rocks. Advanced visualization software was used to fuse the data and to image it on a variety of scales, ranging from basin-scale to well-scales.

  1. Advanced Characterization of Fractured Reservoirs in Carbonate Rocks: The Michigan Basin

    SciTech Connect

    Wood, James R.; Harrison, William B.

    2000-10-24

    The main objective of this project is for a university-industry consortium to develop a comprehensive model for fracture carbonate reservoirs based on the ''data cube'' concept using the Michigan Basin as a prototype. This project combined traditional historical data with 2D and 3D seismic data as well as data from modern logging tools in a novel way to produce a new methodology for characterizing fractured reservoirs in carbonate rocks. Advanced visualization software was used to fuse the data and to image it on a variety of scales, ranging from basin-scale to well-scales.

  2. Reservoir potential of carbonate rocks in the Kutai Basin region, East Kalimantan, Indonesia

    NASA Astrophysics Data System (ADS)

    Alam, H.; Paterson, D. W.; Syarifuddin, N.; Busono, I.; Corbin, S. G.

    1999-04-01

    Fifteen percent of the exploration wells drilled in the Kutai Basin region were targeted for stratigraphic play-types. Carbonate reservoirs comprise almost 70% of the objectives in these stratigraphic plays. There was need for a better understanding of the carbonate reservoir potential in the region. Accordingly, this study was carried out. The distribution, depositional environment as well as factors controlling the quality of carbonate reservoirs are reviewed and analyzed. Carbonate reservoirs in the study area can be found sparsely throughout the Kutai Basin. Carbonates range in age from Oligocene (Bebulu limestone) to Late Miocene (Dian limestone). The main constituents of these carbonate build-ups are platy-corals, encrusting red algae and larger benthonic foraminifera. Most of the carbonates were deposited in a shallow marine environment (inner to middle shelf) during rises in relative sea level. Highstand system tracts are characterized by well-developed carbonate facies-belts. The carbonate build-ups generally occur as isolated bedded mounds, from a few feet up to 1000 ft in thickness. The preservation of primary porosity is generally poor due to diagenetic processes during burial history, particularly the infilling of pores by non-ferroan calcite cement. The development of secondary porosity is limited, due to the retardation of subsurface fluid flow by non-permeable layers, and the absence of solution effects due to sub-aerial exposure and karstification. Preserved porosities are mainly present as vugs, best developed in coarse-grained shelf-margin facies, which may not have subsequently been completely filled by calcite cement. Early hydrocarbon migration may retard the diagenetic processes and preserve the primary carbonate porosity.

  3. Geological and reservoir characterization of shallow-shelf carbonate fields, Southern Paradox Basin, Utah

    SciTech Connect

    Chidsey, T.C. Jr.; Eby, D.E.

    1996-12-31

    The Paradox basin of Utah, Colorado, and Arizona contains nearly 100 small oil fields producing from carbonate mounds within the Pennsylvanian (Desmoinesian) Paradox Formation. These fields typically have one to three wells with primary per field production ranging from 700 MBO to 2 MMBO at a 15-20% recovery rate. Five fields (Anasazi, Mule, Blue Hogan, Heron North, and Runway) within the Navajo Nation of southeastern Utah have been evaluated for CO{sub 2}-flood projects based upon geological characterization and reservoir modeling. Conventional cores from the five fields show that three compositional reservoir types are present: (1) phylloid algal, (2) bioclastic calcarenite, and (3) bryozoan-dominated. Phylloid algal mounds are abundant in four of the five fields, and exhibit the best overall porosity and permeability. This mound type developed where shallow water depths and low energy allowed establishment of calcareous algal colonies possibly on paleohighs. The principal reservoir rock is algal bafflestone composed mostly of the phylloid Ivanovia and occasionally dolomitized. The Heron North field is a bioclastic calcarenite reservoir. It represents high-energy conditions resulting in carbonate beaches developed over foreshore carbonate rubble. The principal reservoir rocks are grainstones and rudstones having grain-selective dissolution and complete dolomitization. Bryozoan-dominated mounds present in Runway field developed in quiet, below wave-base settings that appear to be localized along Mississippian fault blocks trends. The principal reservoir rocks are bindstone and framestone with no dolomitization. The resulting model suggests that CO{sub 2} miscible flooding of these and other small carbonate reservoirs in the Paradox basin could significantly increase ultimate recovery of oil.

  4. Geological and reservoir characterization of shallow-shelf carbonate fields, Southern Paradox Basin, Utah

    SciTech Connect

    Chidsey, T.C. Jr. ); Eby, D.E. )

    1996-01-01

    The Paradox basin of Utah, Colorado, and Arizona contains nearly 100 small oil fields producing from carbonate mounds within the Pennsylvanian (Desmoinesian) Paradox Formation. These fields typically have one to three wells with primary per field production ranging from 700 MBO to 2 MMBO at a 15-20% recovery rate. Five fields (Anasazi, Mule, Blue Hogan, Heron North, and Runway) within the Navajo Nation of southeastern Utah have been evaluated for CO[sub 2]-flood projects based upon geological characterization and reservoir modeling. Conventional cores from the five fields show that three compositional reservoir types are present: (1) phylloid algal, (2) bioclastic calcarenite, and (3) bryozoan-dominated. Phylloid algal mounds are abundant in four of the five fields, and exhibit the best overall porosity and permeability. This mound type developed where shallow water depths and low energy allowed establishment of calcareous algal colonies possibly on paleohighs. The principal reservoir rock is algal bafflestone composed mostly of the phylloid Ivanovia and occasionally dolomitized. The Heron North field is a bioclastic calcarenite reservoir. It represents high-energy conditions resulting in carbonate beaches developed over foreshore carbonate rubble. The principal reservoir rocks are grainstones and rudstones having grain-selective dissolution and complete dolomitization. Bryozoan-dominated mounds present in Runway field developed in quiet, below wave-base settings that appear to be localized along Mississippian fault blocks trends. The principal reservoir rocks are bindstone and framestone with no dolomitization. The resulting model suggests that CO[sub 2] miscible flooding of these and other small carbonate reservoirs in the Paradox basin could significantly increase ultimate recovery of oil.

  5. A method for the assessment of long-term changes in carbon stock by construction of a hydropower reservoir.

    PubMed

    Bernardo, Julio Werner Yoshioka; Mannich, Michael; Hilgert, Stephan; Fernandes, Cristovão Vicente Scapulatempo; Bleninger, Tobias

    2017-01-10

    Sustainability of hydropower reservoirs has been questioned since the detection of their greenhouse gas (GHG) emissions which are mainly composed of carbon dioxide and methane. A method to assess the impact on the carbon cycle caused by the transition from a natural river system into a reservoir is presented and discussed. The method evaluates the long term changes in carbon stock instead of the current approach of monitoring and integrating continuous short term fluxes. A case study was conducted in a subtropical reservoir in Brazil, showing that the carbon content within the reservoir exceeds that of the previous landuse. The average carbon sequestration over 43 years since damming was 895 mg C m[Formula: see text] and found to be mainly due to storage of carbon in sediments. These results demonstrate that reservoirs have two opposite effects on the balance of GHGs. By storing organic C in sediments, reservoirs are an important carbon sink. On the other hand, reservoirs increase the flux of methane into the atmosphere. If the sediments of reservoirs could be used for long term C storage, reservoirs might have a positive effect on the balance of GHGs.

  6. Seismic estimation of porosity in the Permian San Andres carbonate reservoir, Welch Field, Dawson, County, Texas

    SciTech Connect

    Watts, G.P.; Hinterlong, G.D.

    1996-12-31

    OXY and the DOE Are partners in a advanced technology demonstration project at OXY`s West Welch Unit. Production is from a low permeability San Andres reservoir of Permian age similar to many shallow shelf carbonate reservoirs in the Permian Basin. The project involves the construction of a detailed geological model for numerical simulation to design and then conduct a CO{sub 2} flood of the reservoir. Depositional textures of the reservoir rock are highly variable from diagenesis, mostly anhydritic cementing, creating a highly complex pore system. Identification of the interwell reservoir continuity and flow units present the greatest challenge to the reservoir description. A 1993 vintage 3-D seismic survey with a bin spacing of 110{prime} by 165{prime} has been used to assist with the interwell reservoir description. The structure definition at the top and base of the reservoir have been accurately mapped with respect to the well data. Core and well log measurements of porosity, permeability and water saturation were computed and summed across the seismic reservoir interval. Measurements of amplitude, frequency and phase within the 3-D volume were summed across the reservoir interval. All seismic attributes were sampled to the wells and compared through scatterplots to the well log and core measurements. Excellent correlation between three seismic attributes and porosity has been documented. A deterministic method has been used to estimate porosity values at each seismic bin location. The method uses the seismic measurements to shape the geology between the wells while maintaining agreement with the well data at the well locations.

  7. Seismic estimation of porosity in the Permian San Andres carbonate reservoir, Welch Field, Dawson, County, Texas

    SciTech Connect

    Watts, G.P.; Hinterlong, G.D. )

    1996-01-01

    OXY and the DOE Are partners in a advanced technology demonstration project at OXY's West Welch Unit. Production is from a low permeability San Andres reservoir of Permian age similar to many shallow shelf carbonate reservoirs in the Permian Basin. The project involves the construction of a detailed geological model for numerical simulation to design and then conduct a CO[sub 2] flood of the reservoir. Depositional textures of the reservoir rock are highly variable from diagenesis, mostly anhydritic cementing, creating a highly complex pore system. Identification of the interwell reservoir continuity and flow units present the greatest challenge to the reservoir description. A 1993 vintage 3-D seismic survey with a bin spacing of 110[prime] by 165[prime] has been used to assist with the interwell reservoir description. The structure definition at the top and base of the reservoir have been accurately mapped with respect to the well data. Core and well log measurements of porosity, permeability and water saturation were computed and summed across the seismic reservoir interval. Measurements of amplitude, frequency and phase within the 3-D volume were summed across the reservoir interval. All seismic attributes were sampled to the wells and compared through scatterplots to the well log and core measurements. Excellent correlation between three seismic attributes and porosity has been documented. A deterministic method has been used to estimate porosity values at each seismic bin location. The method uses the seismic measurements to shape the geology between the wells while maintaining agreement with the well data at the well locations.

  8. Seagrass meadows as a globally significant carbonate reservoir

    NASA Astrophysics Data System (ADS)

    Mazarrasa, I.; Marbà, N.; Lovelock, C. E.; Serrano, O.; Lavery, P. S.; Fourqurean, J. W.; Kennedy, H.; Mateo, M. A.; Krause-Jensen, D.; Steven, A. D. L.; Duarte, C. M.

    2015-03-01

    There has been a growing interest in quantifying the capacity of seagrass ecosystems to act as carbon sinks as a natural way of offsetting anthropogenic carbon emissions to the atmosphere. However, most of the efforts have focused on the organic carbon (POC) stocks and accumulation rates and ignored the inorganic carbon (PIC) fraction, despite important carbonate pools associated with calcifying organisms inhabiting the meadows, such as epiphytes and benthic invertebrates, and despite the relevance that carbonate precipitation and dissolution processes have in the global carbon cycle. This study offers the first assessment of the global PIC stocks in seagrass sediments using a synthesis of published and unpublished data on sediment carbonate concentration from 402 vegetated and 34 adjacent un-vegetated sites. PIC stocks in the top 1 m sediments ranged between 3 and 1660 Mg PIC ha-1, with an average of 654 ± 24 Mg PIC ha-1, exceeding about 5 fold those of POC reported in previous studies. Sedimentary carbonate stocks varied across seagrass communities, with meadows dominated by Halodule, Thalassia or Cymodocea supporting the highest PIC stocks, and tended to decrease polewards at a rate of -8 ± 2 Mg PIC ha-1 degree-1 of latitude (GLM, p < 0.0003). Using PIC concentration and estimates of sediment accretion in seagrass meadows, mean PIC accumulation rates in seagrass sediments is 126.3 ± 0.7 g PIC m-2 y-1. Based on the global extent of seagrass meadows (177 000 to 600 000 km2), these ecosystems globally store between 11 and 39 Pg of PIC in the top meter of sediment and accumulate between 22 and 76 Tg PIC y-1, representing a significant contribution to the carbonate dynamics of coastal areas. Despite that these high rates of carbonate accumulation imply CO2 emissions from precipitation, seagrass meadows are still strong CO2 sinks as demonstrates the comparison of carbon (POC and POC) stocks between vegetated and adjacent un-vegetated sediments.

  9. Investigating physical controls on methane and carbon dioxide fluxes over reservoirs using the eddy covariance method-abstract

    EPA Science Inventory

    Reservoirs are a globally important source of carbon to the atmosphere. Several recent studies have found that both carbon dioxide (CO2) and methane (CH4) emissions from reservoirs are currently being underestimated by up to 50%. This underestimation is due to inadequate characte...

  10. Reservoir characters of the Ypresian carbonates, Western Libyan Offshore, Central Mediterranean Sea

    SciTech Connect

    Mriheel, I.Y.

    1995-08-01

    Significant hydrocarbon accumulations have been discovered in Western Libyan offshore in the Ypresian carbonate reservoirs of Jdeir Formation and Jirani Dolomite. The discoveries of hydrocarbons are mainly in structural traps where the Jdeir nummulitic facies and Jirani dolomitic facies B have been structured by salt domes or underlying positive fault blocks. This study investigates the relationship between environments of deposition, diagenesis and reservoir characters of the two main hydrocarbon producing units of the Jdeir and Jirani formations. Petrographic and petrophysical studies indicate that porosity in the Jirani Dolomite is related to diagenesis in meteoric environments, while in the Jdeir reservoir is the result of the environment of deposition and diagenesis. Excellent reservoir porosity of Jdeir nummulitic facies and Jirani dolomitic facies B is related to diagenesis in meteoric water during exposure to subaerial conditions which is considered to be due to lowering of sea level and possibly local uplifting.

  11. Characterization of a Miocene carbonate reservoir analog in Southern Mallorca (Balearic Islands, Spain)

    NASA Astrophysics Data System (ADS)

    Vandeginste, V.; Camoin, G.; Eisenhauer, A.; Pézard, P.; Lapointe, P.

    2009-04-01

    Carbonate reservoirs contain more than half the world's oil reserves, including highly productive reservoirs in Cretaceous and Cenozoic carbonates from the Middle East and Southeastern Asia. They are usually characterized by the complexity both of their internal architecture and of the distribution of their diagenetic fabrics which hampers crosshole correlations at various scales, and predictions regarding flow paths and volumes of fluids. Reservoir analogs can have the advantage of easier accessibility and sampling and less severe diagenetic alteration. Their study often provides information complementary to the knowledge of hydrocarbon reservoirs and it leads to a better understanding of carbonate systems, important to make better predictions on other potential reservoirs. Significant advances can be made from joint research in natural laboratories integrating outcrops and shallow boreholes, with extensive control on geophysical, geological and petrophysical parameters. The southern part of the island of Mallorca appears as a natural laboratory where a direct comparison between outcrop and shallow subsurface datasets is the objective of the current study. This region is characterized both by spectacular outcrops, especially in the Cabo Blanco area, which were previously studied [e.g. 1], and by shallow holes, 100 m deep on average, that have been drilled especially at Can Roses, Ses Pastores and Ses Sitjoles, from west to east. This geographical extension of the study area provides the opportunity to better explore and understand the Miocene carbonate complex which comprises the Llucmajor platform. This study incorporates a wide range of analytical techniques to characterize the reservoir aspects, such as conventional microscopy of thin sections, XRD analysis, isotopic carbon and oxygen analysis, isotopic strontium dating analysis, petrophysical measurements, high-resolution borehole images and CT scan data. These techniques are used to unravel the sedimentology

  12. CO{sub 2} Huff-n-Puff process in a light oil shallow shelf carbonate reservoir. Quarterly technical progress report, Fourth quarter 1995

    SciTech Connect

    Wehner, S.; Prieditis, J.

    1996-02-05

    The principle objective of the Central Vacuum Unit (CVU) CO{sub 2} Huff-n-Puff (H-n-P) project is to determine the feasibility and practicality of the technology in a waterflooded shallow shelf carbonate environment. The results of parametric simulation of the CO{sub 2} H-n-P process, coupled with the CVU reservoir characterization components will determine if this process is technically and economically feasible for field implementation. The technology transfer objective of the project is to disseminate the knowledge gained through an innovative plan in support of the Department of Energy`s objective of increasing domestic oil production and deferring the abandonment of shallow shelf carbonate (SSC) reservoirs. Texaco Exploration and Production Inc`s. (TEPI) mid-term plans are to implement a full-scale miscible CO{sub 2} project in the CVU. TEPI has concluded all of the Tasks associated with the First Budget Period. The DOE approved the TEPI continuation application. Budget Period No. 2 is now in progress. Initial injection of CO{sub 2} began in November, and after a short shut-in period for the soak, the well was returned to production in late December, 1995.

  13. Seagrass meadows as a globally significant carbonate reservoir

    NASA Astrophysics Data System (ADS)

    Mazarrasa, I.; Marbà, N.; Lovelock, C. E.; Serrano, O.; Lavery, P. S.; Fourqurean, J. W.; Kennedy, H.; Mateo, M. A.; Krause-Jensen, D.; Steven, A. D. L.; Duarte, C. M.

    2015-08-01

    There has been growing interest in quantifying the capacity of seagrass ecosystems to act as carbon sinks as a natural way of offsetting anthropogenic carbon emissions to the atmosphere. However, most of the efforts have focused on the particulate organic carbon (POC) stocks and accumulation rates and ignored the particulate inorganic carbon (PIC) fraction, despite important carbonate pools associated with calcifying organisms inhabiting the meadows, such as epiphytes and benthic invertebrates, and despite the relevance that carbonate precipitation and dissolution processes have in the global carbon cycle. This study offers the first assessment of the global PIC stocks in seagrass sediments using a synthesis of published and unpublished data on sediment carbonate concentration from 403 vegetated and 34 adjacent un-vegetated sites. PIC stocks in the top 1 m of sediment ranged between 3 and 1660 Mg PIC ha-1, with an average of 654 ± 24 Mg PIC ha-1, exceeding those of POC reported in previous studies by about a factor of 5. Sedimentary carbonate stocks varied across seagrass communities, with meadows dominated by Halodule, Thalassia or Cymodocea supporting the highest PIC stocks, and tended to decrease polewards at a rate of -8 ± 2 Mg PIC ha-1 per degree of latitude (general linear model, GLM; p < 0.0003). Using PIC concentrations and estimates of sediment accretion in seagrass meadows, the mean PIC accumulation rate in seagrass sediments is found to be 126.3 ± 31.05 g PIC m-2 yr-1. Based on the global extent of seagrass meadows (177 000 to 600 000 km2), these ecosystems globally store between 11 and 39 Pg of PIC in the top metre of sediment and accumulate between 22 and 75 Tg PIC yr-1, representing a significant contribution to the carbonate dynamics of coastal areas. Despite the fact that these high rates of carbonate accumulation imply CO2 emissions from precipitation, seagrass meadows are still strong CO2 sinks as demonstrated by the comparison of carbon (PIC

  14. Carbon stock estimation in the catchment of Kotli Bhel 1A hydroelectric reservoir, Uttarakhand, India.

    PubMed

    Kumar, Amit; Sharma, M P

    2016-12-01

    Constructions of dams/reservoirs all over the world are reported to emit significant amount of greenhouse gases (GHGs) and are considered as environmental polluters. Organic carbon is contributed by the forest in the catchment, part of soil organic carbon is transported through the runoffs to the reservoir and undergoes aerobic and anaerobic degradation with time to release GHGs to the atmosphere. Literature reveals that no work is available on the estimation of 'C' stock of trees of forest catchment for assessing/predicting the GHGs emissions from the reservoirs to atmosphere. To assess the GHGs emission potential of the reservoir, an attempt is made in the study to estimate the 'C' stock in the forest catchment of Kotli Bhel 1A hydroelectric reservoir located in Tehri Garhwal district of Uttarakhand, India. For this purpose, the selected area was categorized into the site-I, II and III along the Bhagirathi River based on type of forest available in the catchment. The total carbon density (TCD) of tree species of different forest types was calculated using diameter at breast height (dbh) and trees height. The results found that the TCD of forest catchment was found 76.96MgCha(-1) as the highest at the site-II and 29.93MgCha(-1) as lowest at site-I with mean of 51.50MgCha(-1). The estimated forest 'C' stock shall be used to know the amount of carbon present before and after construction of the dam and to predict net GHGs emissions. The results may be helpful to study the potential of a given reservoir to release GHG and its subsequent impacts on global warming/climate challenges.

  15. Dam tailwaters compound the effects of reservoirs on the longitudinal transport of organic carbon in an arid river

    NASA Astrophysics Data System (ADS)

    Ulseth, A. J.; Hall, R. O., Jr.

    2015-04-01

    Reservoirs on rivers can disrupt organic carbon (OC) transport and transformation, but less is known how downstream river reaches directly below dams contribute to OC processing than reservoirs alone. We compared how reservoirs and their associated tailwaters affected OC quantity and quality by calculating particulate (P) OC and dissolved (D) OC fluxes, and measuring composition and bioavailability of DOC. We sampled the Yampa River near Maybell, Colorado, USA and the Green River above and below Fontenelle and Flaming Gorge reservoirs, and their respective tailwaters from early snowmelt to base flow hydrological conditions. In unregulated reaches (Yampa River, Green River above Fontenelle reservoir), DOC and POC concentrations increased with snowmelt discharge. POC and DOC concentrations also increased with stream discharge below Fontenelle reservoir, but there was no relationship between DOC and stream flow below Flaming Gorge reservoir. The annual load of POC was 3-fold lower below Fontenelle Reservoir and nearly 7-fold lower below Flaming Gorge reservoir, compared to their respective upstream sampling sites. DOC exported to downstream reaches from both reservoirs was less bioavailable, as measured with bioassays, than DOC upriver of the reservoirs. Lastly, tailwater reaches below the reservoirs generated OC, exporting 1.6-2.2 g C m-2 d-1 of OC to downstream ecosystems. Changes in total fluxes from upstream to downstream of reservoirs and their tailwaters do not represent the simultaneous transformation and production of OC, which may lead to the underestimation of the quantity of OC mineralized, transformed, or retained in coupled river-reservoir-tailwater ecosystems.

  16. CO{sub 2} huff-n-puff process in a light oil shallow carbonate reservoir. Annual report, January 1, 1996--December 31, 1996

    SciTech Connect

    Prieditis, J.; Wehner, S.

    1998-01-01

    The application of cyclic CO{sub 2}, often referred to as the CO{sub 2} Huff-n-Puff process, may find its niche in the maturing waterfloods of the Permian Basin. Coupling the CO{sub 2} H-n-P process to miscible flooding applications could provide the needed revenue to sufficiently mitigate near-term negative cash flow concerns in the capital intensive miscible projects. Texaco Exploration & Production Inc. and the U.S. Department of Energy have teamed up in an attempt to develop the CO{sub 2} Huff-n-Puff process in the Grayburg and San Andres formations; a light oil, shallow shelf carbonate reservoir that exists throughout the Permian Basin. A significant amount of oil reserves are located in carbonate reservoirs. Specifically, the carbonates deposited in shallow shelf (SSC) environments make up the largest percentage of known reservoirs within the Permian Basin of North America. Many of these known resources have been under waterflooding operations for decades and are at risk of abandonment if crude oil recoveries cannot be economically enhanced. The selected site for this demonstration project is the Central Vacuum Unit waterflood in Lea County, New Mexico. Miscible CO{sub 2} flooding is the process of choice for enhancing recovery of light oils and already accounts for over 12% of the Permian Basin`s daily production. There are significant probable reserves associated with future miscible CO{sub 2} projects. However, many are marginally economic at current market conditions due to large up-front capital commitments for a peak response which may be several years in the future. The resulting negative cash-flow is sometimes too much for an operator to absorb. The CO{sub 2} H-n-P process is being investigated as a near-term option to mitigate the negative cash-flow situation--allowing acceleration of inventoried miscible CO{sub 2} projects when coupled together.

  17. APPLICATION OF RESERVOIR CHARACTERIZATION AND ADVANCED TECHNOLOGY TO IMPROVE RECOVERY AND ECONOMICS IN A LOWER QUALITY SHALLOW SHELF SANANDRES RESERVOIR

    SciTech Connect

    Unknown

    2003-01-15

    The Class 2 Project at West Welch was designed to demonstrate the use of advanced technologies to enhance the economics of improved oil recovery (IOR) projects in lower quality Shallow Shelf Carbonate (SSC) reservoirs, resulting in recovery of additional oil that would otherwise be left in the reservoir at project abandonment. Accurate reservoir description is critical to the effective evaluation and efficient design of IOR projects in the heterogeneous SSC reservoirs. Therefore, the majority of Budget Period 1 was devoted to reservoir characterization. Technologies being demonstrated include: (1) Advanced petrophysics; (2) Three-dimensional (3-D) seismic; (3) Crosswell bore tomography; (4) Advanced reservoir simulation; (5) Carbon dioxide (CO{sub 2}) stimulation treatments; (6) Hydraulic fracturing design and monitoring; (7) Mobility control agents.

  18. Dam tailwaters compound the effects of reservoirs on the longitudinal transport of organic carbon in an arid river

    NASA Astrophysics Data System (ADS)

    Ulseth, A. J.; Hall, R. O., Jr.

    2015-07-01

    Reservoirs on rivers can disrupt organic carbon (OC) transport and transformation, but less is known how river reaches directly below dams contribute to OC processing. We compared how reservoirs and their associated tailwaters affected OC quantity and quality by calculating particulate OC (POC) and dissolved OC (DOC) fluxes, and measuring composition and bioavailability of DOC. We sampled the Yampa River near Maybell, Colorado, USA, and the Green River above and below Fontenelle and Flaming Gorge reservoirs as well as their respective tailwaters from early snowmelt to base flow hydrological conditions. In unregulated reaches (Yampa River, Green River above Fontenelle reservoir), DOC and POC concentrations increased with snowmelt discharge. POC and DOC concentrations also increased with stream discharge below Fontenelle reservoir, but there was no relationship between DOC and stream flow below Flaming Gorge reservoir. The annual load of POC was 3-fold lower below Fontenelle Reservoir and nearly 7-fold lower below Flaming Gorge reservoir, compared to their respective upstream sampling sites. DOC exported to downstream reaches from both reservoirs was less bioavailable, as measured with bioassays, than DOC upriver of the reservoirs. Lastly, tailwater reaches below the reservoirs generated OC, exporting potentially 1.6-2.2 g C m-2 d-1 of OC to downstream ecosystems. Therefore, the effect of impounding rivers on C fluxes is greater than the impact of the reservoirs alone given the additive effect of tailwater reaches below dams, which may produce and export comparable amounts of likely autochthonous carbon to downstream reaches.

  19. Active CO2 Reservoir Management for Carbon Capture, Utilization, and Sequestration: Impact on Permitting, Monitoring, and Public Acceptance

    NASA Astrophysics Data System (ADS)

    Buscheck, T. A.; Chen, M.; Sun, Y.; Hao, Y.; Court, B.; Celia, M. A.; Wolery, T.; Aines, R. D.

    2011-12-01

    CO2 capture and sequestration (CCS) integrated with geothermal energy production in deep geological formations can play an important role in reducing CO2 emissions to the atmosphere and thereby mitigate global climate change. For industrial-scale CO2 injection in saline formations, pressure buildup can limit storage capacity and security. Active CO2 Reservoir Management (ACRM) combines brine production with CO2 injection to relieve pressure buildup, increase injectivity, manipulate CO2 migration, constrain brine leakage, and enable beneficial utilization of produced brine. Therefore, ACRM can be an enabler of carbon capture, utilization, and sequestration (CCUS). Useful products may include freshwater, cooling water, make-up water for pressure support in oil, gas, and geothermal reservoir operations, and geothermal energy production. Implementation barriers to industrial-scale CCS include concerns about (1) CO2 sequestration security and assurance, (2) pore-space competition with neighboring subsurface activities, (3) CO2 capture costs, and (4) water-use demands imposed by CCS operations, which is particularly important where water resources are already scarce. CCUS, enabled by ACRM, has the potential of addressing these barriers. Pressure relief from brine production can substantially reduce the driving force for potential CO2 and brine migration, as well as minimize interference with neighboring subsurface activities. Electricity generated from geothermal energy can offset a portion of the parasitic energy and financial costs of CCS. Produced brine can be used to generate freshwater by desalination technologies, such as RO, provide a source for saltwater cooling systems or be used as make-up water for oil, gas, or geothermal reservoir operations, reducing the consumption of valuable freshwater resources. We examine the impact of brine production on reducing CO2 and brine leakage. A volumetric balance between injected and produced fluids minimizes the spatial

  20. Tectonic control of the crustal organic carbon reservoir during the Precambrian.

    PubMed

    Des Marais, D J

    1994-01-01

    Carbon isotopic trends indicate that the crustal reservoir of reduced, organic carbon increased during the Proterozoic, particularly during periods of widespread continental rifting and orogeny. No long-term trends are apparent in the concentration of organic carbon in shales, cherts and carbonates. The age distribution of 261 sample site localities sampled for well-preserved sedimentary rocks revealed a 500-700-Ma periodicity which coincided with tectonic cycles. It is assumed that the numbers of sites are a proxy for mass of sediments. A substantial increase in the number of sites in the late Archean correlates with the first appearance between 2.9 and 2.5 Ga of extensive continental platforms and their associated sedimentation. It is proposed that the size of the Proterozoic crustal organic carbon reservoir has been modulated by tectonic control of the volume of sediments deposited in environments favorable for the burial and preservation of organic matter. Stepwise increases in this reservoir would have caused the oxidation state of the Proterozoic environment to increase in a stepwise fashion.

  1. Tectonic control of the crustal organic carbon reservoir during the Precambrian

    NASA Technical Reports Server (NTRS)

    Des Marais, D. J.

    1994-01-01

    Carbon isotopic trends indicate that the crustal reservoir of reduced, organic carbon increased during the Proterozoic, particularly during periods of widespread continental rifting and orogeny. No long-term trends are apparent in the concentration of organic carbon in shales, cherts and carbonates. The age distribution of 261 sample site localities sampled for well-preserved sedimentary rocks revealed a 500-700-Ma periodicity which coincided with tectonic cycles. It is assumed that the numbers of sites are a proxy for mass of sediments. A substantial increase in the number of sites in the late Archean correlates with the first appearance between 2.9 and 2.5 Ga of extensive continental platforms and their associated sedimentation. It is proposed that the size of the Proterozoic crustal organic carbon reservoir has been modulated by tectonic control of the volume of sediments deposited in environments favorable for the burial and preservation of organic matter. Stepwise increases in this reservoir would have caused the oxidation state of the Proterozoic environment to increase in a stepwise fashion.

  2. Calibration of NMR well logs from carbonate reservoirs with laboratory NMR measurements and μXRCT

    DOE PAGES

    Mason, Harris E.; Smith, Megan M.; Hao, Yue; ...

    2014-12-31

    The use of nuclear magnetic resonance (NMR) well log data has the potential to provide in-situ porosity, pore size distributions, and permeability of target carbonate CO₂ storage reservoirs. However, these methods which have been successfully applied to sandstones have yet to be completely validated for carbonate reservoirs. Here, we have taken an approach to validate NMR measurements of carbonate rock cores with independent measurements of permeability and pore surface area to volume (S/V) distributions using differential pressure measurements and micro X-ray computed tomography (μXRCT) imaging methods, respectively. We observe that using standard methods for determining permeability from NMR data incorrectlymore » predicts these values by orders of magnitude. However, we do observe promise that NMR measurements provide reasonable estimates of pore S/V distributions, and with further independent measurements of the carbonate rock properties that universally applicable relationships between NMR measured properties may be developed for in-situ well logging applications of carbonate reservoirs.« less

  3. Injection of liquid carbon dioxide into a reservoir partially saturated with methane hydrate

    NASA Astrophysics Data System (ADS)

    Shagapov, V. Sh.; Khasanov, M. K.; Musakaev, N. R.

    2016-11-01

    A mathematical model is proposed to describe methane-carbon dioxide replacement in gas hydrate by injecting liquid carbon dioxide into a porous medium initially saturated with methane and its hydrate. Self-similar solutions of the axisymmetric problems are constructed that describe the distribution of the main parameters of the reservoir. It is shown that there exist solutions according to which the process can occur both with and without boiling of carbon dioxide. Diagrams of the existence of each type of solution are constructed.

  4. SCREENING METHODS FOR SELECTION OF SURFACTANT FORMULATIONS FOR IOR FROM FRACTURED CARBONATE RESERVOIRS

    SciTech Connect

    William A. Goddard III; Yongchun Tang; Patrick Shuler; Mario Blanco; Yongfu Wu; Seung Soon Jang

    2005-07-01

    This topical report presents details of the laboratory work performed to complete Task 1 of this project; developing rapid screening methods to assess surfactant performance for IOR (Improved Oil Recovery) from fractured carbonate reservoirs. The desired outcome is to identify surfactant formulations that increase the rate and amount of aqueous phase imbibition into oil-rich, oil-wet carbonate reservoir rock. Changing the wettability from oil-wet to water-wet is one key to enhancing this water-phase imbibition process that in turn recovers additional oil from the matrix portion of a carbonate reservoir. The common laboratory test to evaluate candidate surfactant formulations is to measure directly the aqueous imbibition rate and oil recovery from small outcrop or reservoir cores, but this procedure typically requires several weeks. Two methods are presented here for the rapid screening of candidate surfactant formulations for their potential IOR performance in carbonate reservoirs. One promising surfactant screening protocol is based on the ability of a surfactant solution to remove aged crude oil that coats a clear calcite crystal (Iceland Spar). Good surfactant candidate solutions remove the most oil the quickest from the chips, plus change the apparent contact angle of the remaining oil droplets on the surface that thereby indicate increased water-wetting. The other fast surfactant screening method is based on the flotation behavior of powdered calcite in water. In this test protocol, first the calcite power is pre-treated to make the surface oil-wet. The next step is to add the pre-treated powder to a test tube and add a candidate aqueous surfactant formulation; the greater the percentage of the calcite that now sinks to the bottom rather than floats, the more effective the surfactant is in changing the solids to become now preferentially water-wet. Results from the screening test generally are consistent with surfactant performance reported in the literature.

  5. Pore Type Classification on Carbonate Reservoir in Offshore Sarawak using Rock Physics Model and Rock Digital Images

    NASA Astrophysics Data System (ADS)

    Lubis, L. A.; Harith, Z. Z. T.

    2014-03-01

    It has been recognized that carbonate reservoirs are one of the biggest sources of hydrocarbon. Clearly, the evaluation of these reservoirs is important and critical. For rigorous reservoir characterization and performance prediction from geophysical measurements, the exact interpretation of geophysical response of different carbonate pore types is crucial. Yet, the characterization of carbonate reservoir rocks is difficult due to their complex pore systems. The significant diagenesis process and complex depositional environment makes pore systems in carbonates far more complicated than in clastics. Therefore, it is difficult to establish rock physics model for carbonate rock type. In this paper, we evaluate the possible rock physics model of 20 core plugs of a Miocene carbonate platform in Central Luconia, Sarawak. The published laboratory data of this area were used as an input to create the carbonate rock physics models. The elastic properties were analyzed to examine the validity of an existing analytical carbonate rock physics model. We integrate the Xu-Payne Differential Effective Medium (DEM) Model and the elastic modulus which was simulated from a digital carbonate rock image using Finite Element Modeling. The results of this integration matched well for the separation of carbonate pore types and sonic P-wave velocity obtained from laboratory measurement. Thus, the results of this study show that the integration of rock digital image and theoretical rock physics might improve the elastic properties prediction and useful for more advance geophysical techniques (e.g. Seismic Inversion) of carbonate reservoir in Sarawak.

  6. Val Verde Basin: Thrusted Strawn (Pennsylvanian) carbonate reservoirs, Pakenham Field area

    SciTech Connect

    Montgomery, S.L.

    1996-07-01

    An important target of recent exploration in the Val Verde basin of southwestern Texas has been thrusted Pennsylvanian (Desmoinesian) carbonates along the leading edge of the Ouachita front. These reservoirs produce gas and condensate at significant rates from fractured limestones, which were deposited in a variety of environments and later complexly juxtaposed during thrusting. Improvements in seismic imaging capabilities, particularly associated with the introduction of two-dimension (2-D) swath and three-dimensional (3-D) surveys, have allowed accurate mapping of the thrust front and have resulted in revised interpretations of basin structure and history. These data highlight the existence of multiple reservoirs at separate structural levels. Strawn reservoirs are discussed in relation to the Pakenham field area, northwestern Terrell County.

  7. Amplitude map analysis using forward modeling in sandstone and carbonate reservoirs

    SciTech Connect

    Neff, D.B. )

    1993-10-01

    The extent to which seismic amplitude maps can contribute to the analysis of hydrocarbon reservoirs was investigated for clastic and carbonate reservoirs worldwide. By using a petrophysical-based, forward modeling process called incremental pay thickness (IPT) modeling, five lithology types were quantitatively analyzed for the interplay of seismic amplitude versus lithology, porosity, hydrocarbon pore fluid saturation, bedding geometries, and reservoir thickness. The studies identified three common tuning curve shapes (concave, convex, and bilinear) that were primarily dependent upon the lithology model type and the average net porosity therein. While the reliability of pay and porosity predictions from amplitude maps varied for each model type, all analyses showed a limited thickness range for which amplitude data could successfully predict net porosity thickness or hydrocarbon pore volume. The investigation showed that systematic forward modeling is required before amplitude maps can be properly interpreted.

  8. Exploration model for shallow Silurian (Kankakee) carbonate reservoirs in western Illinois

    SciTech Connect

    Crockett, J.E.; Seyler, B.J.; Whitaker, S.

    1987-09-01

    Reservoirs in shallow (600-650 ft deep) basal Silurian Kankakee carbonates at Buckhorn consolidated, Siloam, and Kellerville oil fields in western Illinois have produced nearly 2 million bbl of oil, but were developed essentially by random drilling. A new exploration model that combines lithologic studies and isopach mapping has been developed at the Illinois State Geological Survey. Isopach mapping of Silurian and Devonian rocks between an organic facies in the Mississippian-Devonian New Albany Shale and the top of the Ordovician Maquoketa Shale reveals thickened sequences that coincide with most of the oil fields. These thickened intervals apparently reflect subtle paleovalleys eroded into the Maquoketa shale during the Ordovician-Silurian hiatus. During the initial Silurian marine transgression, these paleovalleys at the base of the Kankakee were filled with carbonates to form the thickened sequences. Differential erosion at the top of the Kankakee does not satisfactorily explain the locally thickened sequences in the Kankakee. Lithologic studies suggest that subsurface fluid flows concentrated along these paleovalleys contributed to subsequent diagenesis of valleyfill carbonates. Diagenetic alteration of these carbonates resulted in development of basal Kankakee reservoirs within the paleovalleys. This concept of Kankakee reservoirs occurring within paleovalleys at the Ordovician-Silurian unconformity is a new exploration model that can aid in the search for similar traps in western Illinois.

  9. Intrashelf basins: A geologic model for source-bed and reservoir facies deposition within carbonate shelves

    SciTech Connect

    Grover, G. Jr. )

    1993-09-01

    Intrashelf basins (moats, inshore basins, shelf basins, differentiated shelf, and deep-water lagoons of others) are depressions of varying sizes and shapes that occur within tectonically passive and regionally extensive carbonate shelves. Intrashelf basins grade laterally and downdip (seaward) into shallow-water carbonates of the regional shelf, are separated from the open marine basin by the shelf margin, and are largely filled by fine-grained subtidal sediments having attributes of shallow- and deeper water sedimentation. These basins are commonly fringed or overlain by carbonate sands, reefs, or buildups. These facies may mimic those that occur along the regional shelf margin, and they can have trends that are at a high angle to that of the regional shelf. Intrashelf basins are not intracratonic basins. The history of most intrashelf basins is a few million to a few tens of million of years. Examples of intrashelf basins are known throughout the Phanerozoic; the southern portion of the Holocene Belize shelf is a modern example of an intrashelf basin. Two types of intrashelf basins are recognized. Coastal basins pass updip into coastal clastics of the craton with the basin primarily filled by fine clastics. Shelf basins occur on the outer part of the shelf, are surrounded by shallow-water carbonate facies, and are filled by peloidal lime mud, pelagics, and argillaceous carbonates. Intrashelf basins are commonly the site of organic-rich, source-bed deposition, resulting in the close proximity of source beds and reservoir facies that may fringe or overlie the basin. Examples of hydrocarbon-charged reservoirs that were sourced by an intrashelf basin include the Miocene Bombay High field, offshore India; the giant Jurassic (Arab-D) and Cretaceous (Shuaiba) reservoirs of the Arabian Shelf; the Lower Cretaceous Sunniland trend, South Florida basin; and the Permian-Pennsylvanian reservoirs surrounding the Tatum basin in southeastern New Mexico.

  10. Differential Effects of Legume Species on the Recovery of Soil Microbial Communities, and Carbon and Nitrogen Contents, in Abandoned Fields of the Loess Plateau, China

    NASA Astrophysics Data System (ADS)

    Li, Jin Hua; Jiao, Shu Mei; Gao, Rong Qing; Bardgett, Richard D.

    2012-12-01

    Plant-soil interactions are known to influence a wide range of ecosystem-level functions. Moreover, the recovery of these functions is of importance for the successful restoration of soils that have been degraded through intensive and/or inappropriate land use. Here, we assessed the effect of planting treatments commonly used to accelerate rates of grassland restoration, namely introduction of different legume species Medicago sativa, Astragalus adsurgens, Melilotus suaveolens, on the recovery of soil microbial communities and carbon and nitrogen contents in abandoned fields of the Loess Plateau, China. The results showed effects were species-specific, and either positive, neutral or negative depending on the measure and time-scale. All legumes increased basal respiration and metabolic quotient and had a positive effect on activity and functional diversity of the soil microbial community, measured using Biolog EcoPlate. However, soil under Astragalus adsurgens had the highest activity and functional diversity relative to the other treatments. Soil carbon and nitrogen content and microbial biomass were effectively restored in 3-5 years by introducing Medicago sativa and Astragalus adsurgens into early abandoned fields. Soil carbon and nitrogen content were retarded in 3-5 years and microbial biomass was retarded in the fifth year by introducing Melilotus suaveolens. Overall, the restoration practices of planting legumes can significantly affect soil carbon and nitrogen contents, and the biomass, activity, and functional diversity of soil microbial community. Therefore, we propose certain legume species could be used to accelerate ecological restoration of degraded soils, hence assist in the protection and preservation of the environment.

  11. Stable isotope mass balances versus concentration differences of dissolved inorganic carbon - implications for tracing carbon turnover in reservoirs.

    PubMed

    Barth, Johannes A C; Mader, Michael; Nenning, Franziska; van Geldern, Robert; Friese, Kurt

    2017-02-13

    The aim of this study was to identify sources of carbon turnover using stable isotope mass balances. For this purpose, two pre-reservoirs in the Harz Mountains (Germany) were investigated for their dissolved and particulate carbon contents (dissolved inorganic carbon (DIC), dissolved organic carbon, particulate organic carbon) together with their stable carbon isotope ratios. DIC concentration depth profiles from March 2012 had an average of 0.33 mmol L(-1). Increases in DIC concentrations later on in the year often corresponded with decreases in its carbon isotope composition (δ(13)CDIC) with the most negative value of -18.4 ‰ in September. This led to a carbon isotope mass balance with carbon isotope inputs of -28.5 ‰ from DOC and -23.4, -31.8 and -30.7 ‰ from algae, terrestrial and sedimentary matter, respectively. Best matches between calculated and measured DIC gains were achieved when using the isotope composition of algae. This shows that this type of organic material is most likely responsible for carbon additions to the DIC pool when its concentrations and δ(13)CDIC values correlate negatively. The presented isotope mass balance is transferable to other surface water and groundwater systems for quantification of organic matter turnover.

  12. High-Throughput Carbon Substrate Profiling of Mycobacterium ulcerans Suggests Potential Environmental Reservoirs

    PubMed Central

    Militello, Muriel; Drancourt, Michel

    2017-01-01

    Background Mycobacterium ulcerans is a close derivative of Mycobacterium marinum and the agent of Buruli ulcer in some tropical countries. Epidemiological and environmental studies pointed towards stagnant water ecosystems as potential sources of M. ulcerans, yet the ultimate reservoirs remain elusive. We hypothesized that carbon substrate determination may help elucidating the spectrum of potential reservoirs. Methodology/Principal findings In a first step, high-throughput phenotype microarray Biolog was used to profile carbon substrates in one M. marinum and five M. ulcerans strains. A total of 131/190 (69%) carbon substrates were metabolized by at least one M. ulcerans strain, including 28/190 (15%) carbon substrates metabolized by all five M. ulcerans strains of which 21 substrates were also metabolized by M. marinum. In a second step, 131 carbon substrates were investigated, through a bibliographical search, for their known environmental sources including plants, fruits and vegetables, bacteria, algae, fungi, nematodes, mollusks, mammals, insects and the inanimate environment. This analysis yielded significant association of M. ulcerans with bacteria (p = 0.000), fungi (p = 0.001), algae (p = 0.003) and mollusks (p = 0.007). In a third step, the Medline database was cross-searched for bacteria, fungi, mollusks and algae as potential sources of carbon substrates metabolized by all tested M. ulcerans; it indicated that 57% of M. ulcerans substrates were associated with bacteria, 18% with alga, 11% with mollusks and 7% with fungi. Conclusions This first report of high-throughput carbon substrate utilization by M. ulcerans would help designing media to isolate and grow this pathogen. Furthermore, the presented data suggest that potential M. ulcerans environmental reservoirs might be related to micro-habitats where bacteria, fungi, algae and mollusks are abundant. This should be followed by targeted investigations in Buruli ulcer endemic regions. PMID:28095422

  13. Carbon capture and storage reservoir properties from poroelastic inversion: A numerical evaluation

    NASA Astrophysics Data System (ADS)

    Lepore, Simone; Ghose, Ranajit

    2015-11-01

    We investigate the prospect of estimating carbon capture and storage (CCS) reservoir properties from P-wave intrinsic attenuation and velocity dispersion. Numerical analogues for two CCS reservoirs are examined: the Utsira saline formation at Sleipner (Norway) and the coal-bed methane basin at Atzbach-Schwanestadt (Austria). P-wave intrinsic dispersion curves in the field-seismic frequency band, obtained from theoretical studies based on simulation of oscillatory compressibility and shear tests upon representative rock samples, are considered as observed data. We carry out forward modelling using poroelasticity theories, making use of previously established empirical relations, pertinent to CCS reservoirs, to link pressure, temperature and CO2 saturation to other properties. To derive the reservoir properties, poroelastic inversions are performed through a global multiparameter optimization using simulated annealing. We find that the combination of attenuation and velocity dispersion in the error function helps significantly in eliminating the local minima and obtaining a stable result in inversion. This is because of the presence of convexity in the solution space when an integrated error function is minimized, which is governed by the underlying physics. The results show that, even in the presence of fairly large model discrepancies, the inversion provides reliable values for the reservoir properties, with the error being less than 10% for most of them. The estimated values of velocity and attenuation and their sensitivity to effective stress and CO2 saturation generally agree with the earlier experimental observation. Although developed and tested for numerical analogues of CCS reservoirs, the approach presented here can be adapted in order to predict key properties in a fluid-bearing porous reservoir, in general.

  14. Characterization of facies and permeability patterns in carbonate reservoirs based on outcrop analogs. Final report

    SciTech Connect

    Kerans, C.; Lucia, F.J.; Senger, R.K.; Fogg, G.E.; Nance, H.S.; Hovorka, S.D.

    1993-07-01

    The primary objective of this research is to develop methods for better describing the three-dimensional geometry of carbonate reservoir flow units as related to conventional or enhanced recovery of oil. San Andres and Grayburg reservoirs were selected for study because of the 13 Bbbl of remaining mobile oil and 17 Bbbl of residual oil in these reservoirs. The key data base is provided by detailed characterization of geologic facies and rock permeability in reservior-scale outcrops of the Permian San Andres Formation in the Guadalupe Mountains of New Mexico. Emphasis is placed on developing an outcrop analog for San Andres strata that can be used as (1) a guide to interpreting the regional and local geologic framework of the subsurface reservoirs (2) a data source illustrating the scales and patterns of variability of rock-fabric facies and petrophysical properties, particularly in lateral dimension, and on scales that cannot be studied during subsurface reservoir characterization. The research approach taken to achieve these objectives utilizes the integration of geologic description, geostatistical techniques, and reservoir flow simulation experiments. Results from this research show that the spatial distribution of facies relative to the waterflood direction can significantly affect how the reservoir produces. Bypassing of unswept oil occurs due to cross flow of injected water from high permeability zones into lower permeability zones were high permeability zones terminate. An area of unswept oil develops because of the slower advance of the water-injection front in the lower permeability zones. When the injection pattern is reversed, the cross-flow effect changes due to the different arrangements of rock-fabric flow units relative to the flow of injected water, and the sweep efficiency is significantly different. Flow across low-permeability mudstones occurs showing that these layers do not necessarily represent flow barriers.

  15. Oil Recovery Enhancement from Fractured, Low Permeability Reservoirs. [Carbonated Water

    DOE R&D Accomplishments Database

    Poston, S. W.

    1991-01-01

    The results of the investigative efforts for this jointly funded DOE-State of Texas research project achieved during the 1990-1991 year may be summarized as follows: Geological Characterization - Detailed maps of the development and hierarchical nature the fracture system exhibited by Austin Chalk outcrops were prepared. The results of these efforts were directly applied to the development of production decline type curves applicable to a dual-fracture-matrix flow system. Analysis of production records obtained from Austin Chalk operators illustrated the utility of these type curves to determine relative fracture/matrix contributions and extent. Well-log response in Austin Chalk wells has been shown to be a reliable indicator of organic maturity. Shear-wave splitting concepts were used to estimate fracture orientations from Vertical Seismic Profile, VSP data. Several programs were written to facilitate analysis of the data. The results of these efforts indicated fractures could be detected with VSP seismic methods. Development of the EOR Imbibition Process - Laboratory displacement as well as Magnetic Resonance Imaging, MRI and Computed Tomography, CT imaging studies have shown the carbonated water-imbibition displacement process significantly accelerates and increases recovery from oil saturated, low permeability rocks. Field Tests - Two operators amenable to conducting a carbonated water flood test on an Austin Chalk well have been identified. Feasibility studies are presently underway.

  16. Recognition and significance of parasequences and parasequence sets in Leonard carbonate reservoirs, west Texas

    SciTech Connect

    Ruppel, S.C. )

    1991-03-01

    Although hydrocarbon production from reservoirs of Leonardian age is sizable (cumulative production from the Leonardian on the Central Basin Platform (CBP) alone totals 1.4 billion bbls), recovery efficiencies from these restricted, shallow-water platform carbonate deposits are among the lowest in west Texas, averaging only about 19%. Detailed examination of the Leonard section in the Dollarhide and Monahans fields on the CBP indicates that poor recovery from these reservoirs is a function of extreme vertical heterogeneity produced by high-order oscillations of relative sea level. The Leonard sequence is composed of thin (1- to 2-m thick), upward-shallowing parasequences, each of which is marked at its base by a prominent marine flooding surface. Parasequences are, in turn, packaged into 15- to 20-m parasequence set defined by variations in parasequence facies stacking patterns. Reservoir porosity is typically preferentially developed in very thin (less than 1 m) zones of grain-rich subtidal facies within parasequences, although porosity may also be encountered in capping tidal-flat deposits. Because these facies display distinct pore and permeability characteristics, with subtidal facies usually exhibiting the highest permeabilities, development of accurate reservoir models for simulation and exploitation depends on the ability to distinguish and map these deposits. Recognition and correlation of parasequences and parasequence stacking patterns in parasequence sets provide a powerful tool for more accurate mapping of facies and attendant porosity development and facilitate development of improved models necessary for efficient exploitation of these highly heterogeneous reservoirs.

  17. Modelling the effect of wettability distributions on oil recovery from microporous carbonate reservoirs

    NASA Astrophysics Data System (ADS)

    Kallel, W.; van Dijke, M. I. J.; Sorbie, K. S.; Wood, R.; Jiang, Z.; Harland, S.

    2016-09-01

    Carbonate-hosted hydrocarbon reservoirs are known to be weakly- to moderately oil-wet, but the pore-scale wettability distribution is poorly understood. Moreover, micropores, which often dominate in carbonate reservoirs, are usually assumed to be water-wet and their role in multi-phase flow is neglected. Modelling the wettability of carbonates using pore network models is challenging, because of our inability to attribute appropriate chemical characteristics to the pore surfaces and over-simplification of the pore shapes. Here, we implement a qualitatively plausible wettability alteration scenario in a two-phase flow network model that captures a diversity of pore shapes. The model qualitatively reproduces patterns of wettability alteration recently observed in microporous carbonates via high-resolution imaging. To assess the combined importance of pore-space structure and wettability on petrophysical properties, we consider a homogeneous Berea sandstone network and a heterogeneous microporous carbonate network, whose disconnected coarse-scale pores are connected through a sub-network of fine-scale pores. Results demonstrate that wettability effects are significantly more profound in the carbonate network, as the wettability state of the micropores controls the oil recovery.

  18. Carbon dioxide-water clathrate as a reservoir of CO2 on Mars

    NASA Technical Reports Server (NTRS)

    Dobrovolskis, A.; Ingersell, A. P.

    1975-01-01

    It has been suggested that the residual polar caps of Mars contain a resorvoir of permanently frozen carbon dioxide which is controlling the atmospheric pressure. However, observational data and models of the polar heat balance suggest that the temperatures of the Martian poles are too high for solid CO2 to survive permanently. On the other hand, the icelike compound carbon dioxide-water clathrate could function as a CO2 reservoir instead of solid CO2, because it is stable at higher temperatures. This paper shows that the permanent polar caps may contain several millibars of CO2 in the form of clathrate, and discusses the implications of this permanent clathrate reservoir for the present and past atmospheric pressure on Mars.

  19. Predicting phase behavior of mixtures of reservoir fluids with carbon dioxide

    SciTech Connect

    Grigg, R.B.; Lingane, P.J.

    1983-01-01

    The use of an equation of state to predict phase behavior during carbon dioxide flooding is well established. The characterization of the C/sub 7/ fraction and the selection of interaction parameters are the most important variables. Single-contact phase behavior is presented for mixtures of Ford Geraldine (Delaware), Maljamar (Grayburg), West Sussex (Shannon), and Reservoir D reservoir fluids, and of a synthetic oil with carbon dioxide. The phase behavior of these mixtures can be reproduced using 3 to 5 pseudo components and common interaction parameters. The critical properties of the pseudo components are calculated from detailed oil characterizations. Because the parameters are not further adjusted, this approach reduces the empiricism in fitting phase data and may result in a more accurate representation of the system as the composition of the oil changes during the approach to miscibility. 21 references.

  20. Integrated core-log petrofacies analysis in the construction of a reservoir geomodel: A case study of a mature Mississippian carbonate reservoir using limited data

    USGS Publications Warehouse

    Bhattacharya, S.; Doveton, J.H.; Carr, T.R.; Guy, W.R.; Gerlach, P.M.

    2005-01-01

    Small independent operators produce most of the Mississippian carbonate fields in the United States mid-continent, where a lack of integrated characterization studies precludes maximization of hydrocarbon recovery. This study uses integrative techniques to leverage extant data in an Osagian and Meramecian (Mississippian) cherty carbonate reservoir in Kansas. Available data include petrophysical logs of varying vintages, limited number of cores, and production histories from each well. A consistent set of assumptions were used to extract well-level porosity and initial saturations, from logs of different types and vintages, to build a geomodel. Lacking regularly recorded well shut-in pressures, an iterative technique, based on material balance formulations, was used to estimate average reservoir-pressure decline that matched available drillstem test data and validated log-analysis assumptions. Core plugs representing the principal reservoir petrofacies provide critical inputs for characterization and simulation studies. However, assigning plugs among multiple reservoir petrofacies is difficult in complex (carbonate) reservoirs. In a bottom-up approach, raw capillary pressure (Pc) data were plotted on the Super-Pickett plot, and log- and core-derived saturation-height distributions were reconciled to group plugs by facies, to identify core plugs representative of the principal reservoir facies, and to discriminate facies in the logged interval. Pc data from representative core plugs were used for effective pay evaluation to estimate water cut from completions, in infill and producing wells, and guide-selective perforations for economic exploitation of mature fields. The results from this study were used to drill 22 infill wells. Techniques demonstrated here can be applied in other fields and reservoirs. Copyright ?? 2005. The American Association of Petroleum Geologists. All rights reserved.

  1. Thermal regime of the deep carbonate reservoir of the Po Plain (Italy)

    NASA Astrophysics Data System (ADS)

    Pasquale, V.; Chiozzi, P.; Verdoya, M.

    2012-04-01

    Italy is one of the most important countries in the world with regard to high-medium enthalpy geothermal resources, a large part of which is already extracted at relatively low cost. High temperatures at shallow to medium depth occur within a wide belt, several hundred kilometre long, west of the Apennines mountain chain. This belt, affected by recent lithosphere extension, includes several geothermal fields, which are largely exploited for electricity generation. Between the Alps and Apennines ranges, the deeper aquifer, occurring in carbonate rocks of the Po Plain, can host medium enthalpy fluids, which are exploited for district heating. Such a general picture of the available geothermal resources has been well established through several geophysical investigations and drillings. Nevertheless, additional studies are necessary to evaluate future developments, especially with reference to the deep carbonate aquifer of the Po Plain. In this paper, we focus on the eastern sector of the plain and try to gain a better understanding of the thermal regime by using synergically geothermal methodologies and geological information. The analysis of the temperatures recorded to about 6 km depth in hydrocarbon wells supplies basic constraints to outline the thermal regime of the sedimentary basin and to investigate the occurrence and importance of hydrothermal processes in the carbonate layer. After correction for drilling disturbance, temperatures were analysed, together with geological information, through an inversion technique based on a laterally constant thermal gradient model. The inferred thermal gradient changes with depth; it is quite low within the carbonate layer, while is larger in the overlying, practically impermeable formations. As the thermal conductivity variation does not justify such a thermal gradient difference, the vertical change can be interpreted as due to convective processes occurring in the carbonate layer, acting as thermal reservoir. The

  2. Reservoir-Condition Pore-Scale Imaging of Reaction in Carbonates using Synchrotron Fast Tomography

    NASA Astrophysics Data System (ADS)

    Menke, H. P.; Andrew, M. G.; Bijeljic, B.; Blunt, M. J.

    2015-12-01

    Carbon capture and storage in carbonate reservoirs is essential for mitigating climate change. Supercritical CO2 mixed with host brine is acidic and can dissolve the surrounding pore structure and change flow dynamics. However, the type, speed, and magnitude of the dissolution are dependent on both the reactive transport properties of the pore-fluid and the intrinsic properties of the rock. Understanding how changes in the pore structure, chemistry, and flow properties affect dissolution is vital for successful predictive modelling both on the pore-scale and for up-scaled reservoir simulations. Reaction in carbonates has been studied at the pore-scale but has never been imaged dynamically in situ. We present an experimental method whereby both lab-based benchtop instruments and 'Pink Beam' synchrotron radiation are used in X-ray microtomography to investigate pore structure changes during supercritical CO2 injection at reservoir conditions. Three types of pure limestone rock with broadly varying rock topology were imaged under the same reservoir conditions. Flow-rate and brine acidity was varied in successive experiments by half an order of magnitude to gain insight into the impact of flow, transport, and physical heterogeneity. The images were binarized and the magnitude of dissolution was identified on a voxel-by-voxel basis to extract pore-by-pore dissolution data. The impact of dissolution on flow characteristics was studied by computing the evolution of the pore-scale velocity fields with a flow solver. We found that increasing rock heterogeneity increased channelized flow [Figure 1] through preferential pathways and that higher flow rate increased total dissolution. Additionally, decreasing reaction rate lowered overall reaction rate and made axial flow less uniform. Experimentally measured reaction rates in real rocks are at least an order of magnitude lower when compared to batch experiments. We provide evidence that this can be due to transport limitations

  3. Capillarity and wetting of carbon dioxide and brine during drainage in Berea sandstone at reservoir conditions

    NASA Astrophysics Data System (ADS)

    Al-Menhali, Ali; Niu, Ben; Krevor, Samuel

    2015-10-01

    The wettability of CO2-brine-rock systems will have a major impact on the management of carbon sequestration in subsurface geological formations. Recent contact angle measurement studies have reported sensitivity in wetting behavior of this system to pressure, temperature, and brine salinity. We report observations of the impact of reservoir conditions on the capillary pressure characteristic curve and relative permeability of a single Berea sandstone during drainage—CO2 displacing brine—through effects on the wetting state. Eight reservoir condition drainage capillary pressure characteristic curves were measured using CO2 and brine in a single fired Berea sandstone at pressures (5-20 MPa), temperatures (25-50°C), and ionic strengths (0-5 mol kg-1 NaCl). A ninth measurement using a N2-water system provided a benchmark for capillarity with a strongly water wet system. The capillary pressure curves from each of the tests were found to be similar to the N2-water curve when scaled by the interfacial tension. Reservoir conditions were not found to have a significant impact on the capillary strength of the CO2-brine system during drainage through a variation in the wetting state. Two steady-state relative permeability measurements with CO2 and brine and one with N2 and brine similarly show little variation between conditions, consistent with the observation that the CO2-brine-sandstone system is water wetting and multiphase flow properties invariant across a wide range of reservoir conditions.

  4. Solid hydrocarbon: a migration-of-fines problem in carbonate reservoirs

    SciTech Connect

    Lomando, A.J.

    1986-05-01

    The most familiar example of a migration-of-fines problem is authigenic kaolinite, which can detach, migrate through a pore system, and bridge pore throats, thus reducing permeability. under certain conditions, a similar problem is caused by solid hydrocarbon, independent of a mode of origin, which has precipitated in carbonate pore systems. Cores from several reservoirs in the Lower Cretaceous of east Texas were used as the data base in this study. Three morphotypes of solid hydrocarbon have been identified from thin-section and scanning electron microscope observations: droplets, peanut brittle, and carpets. Droplets are small, individual, rounded particles scattered on pore walls. Peanut brittle ranges from a continuous to discontinuous thin coating with random rounded lumps that probably have droplet precursors. Carpets are thick, continuous coatings and, at the extreme, can effectively occlude whole pores. Initially, solid hydrocarbon reduces permeability without necessarily decreasing porosity significantly. Likewise, solid hydrocarbon cannot be detected directly from wireline logs. Acidizing to enhance communication to the well bore is a common completion procedure in limestone and calcareous sandstone reservoirs. In reservoirs containing solid hydrocarbon, acid etches the substrate and releases solid hydrocarbon, which migrates in the pore system and bridges pore throats. Differential well-bore pressure also may cause solid hydrocarbon to migrate. Therefore, wettability, which controls hydrocarbon adhesion to the pore walls, and the dominant morphotype are important factors in the extent of reservoir damage.

  5. Diagenetic overprint of original depositional architecture in a shallow water carbonate reservoir, Permian Basin, Texas

    SciTech Connect

    Ruppel, S.C.; Lucia, F.J.

    1996-12-31

    Permian shallow-water carbonate reservoirs are highly heterogeneous because of complex variations in depositional facies produced by high-frequency sea level rise and fall. Accordingly, establishment of a cycle stratigraphic framework is fundamental to defining reservoir heterogeneity. Because nearly all of these reservoirs have experienced multiple episodes of dolomitization and sulfate emplacement, however, permeability is a n of diagenetic overprint. The extent to which diagenesis can affect permeability development is dramatically displayed in the Grayburg Formation (middle Permian) at South Cowden field, Weit Texas. Three scales of cyclicity contribute to original depositional facies heterogeneity in the Grayburg; high-frequency cycles, averaging 3 meters in thickness, constitute the fundamental architectural element in the main reservoir interval. Despite original depositional heterogeneity due to this cyclicity, however, permeability development is substantially the result of two diagenetic events: (1) dolomite diagenesis in vertically burrowed wackestones and packstones and (2) late alteration and removal of anhydrite. Dolomite diagenesis in vertically burrowed wackestones and packstones has produced irregular vertical zones of higher permeability in mud-dominated bases of high-frequency cycles in leeward ramp-crest highstand successions. Because dolomite diagenesis is concentrated in burrowed highstand successions, the distribution of resultant permeability trends is partly constrained by patterns of longterm accommodation and high frequency cyclicity. Anhydrite diagenesis, which is characterized by conversion to gypsum or by complete removal of sulfate, is developed along basinward margins of the field and cross cuts original depositional framework.

  6. Diagenetic overprint of original depositional architecture in a shallow water carbonate reservoir, Permian Basin, Texas

    SciTech Connect

    Ruppel, S.C.; Lucia, F.J. )

    1996-01-01

    Permian shallow-water carbonate reservoirs are highly heterogeneous because of complex variations in depositional facies produced by high-frequency sea level rise and fall. Accordingly, establishment of a cycle stratigraphic framework is fundamental to defining reservoir heterogeneity. Because nearly all of these reservoirs have experienced multiple episodes of dolomitization and sulfate emplacement, however, permeability is a n of diagenetic overprint. The extent to which diagenesis can affect permeability development is dramatically displayed in the Grayburg Formation (middle Permian) at South Cowden field, Weit Texas. Three scales of cyclicity contribute to original depositional facies heterogeneity in the Grayburg; high-frequency cycles, averaging 3 meters in thickness, constitute the fundamental architectural element in the main reservoir interval. Despite original depositional heterogeneity due to this cyclicity, however, permeability development is substantially the result of two diagenetic events: (1) dolomite diagenesis in vertically burrowed wackestones and packstones and (2) late alteration and removal of anhydrite. Dolomite diagenesis in vertically burrowed wackestones and packstones has produced irregular vertical zones of higher permeability in mud-dominated bases of high-frequency cycles in leeward ramp-crest highstand successions. Because dolomite diagenesis is concentrated in burrowed highstand successions, the distribution of resultant permeability trends is partly constrained by patterns of longterm accommodation and high frequency cyclicity. Anhydrite diagenesis, which is characterized by conversion to gypsum or by complete removal of sulfate, is developed along basinward margins of the field and cross cuts original depositional framework.

  7. Viral Regulation of Prokaryotic Carbon Metabolism in a Hypereutrophic Freshwater Reservoir Ecosystem (Villerest, France)

    PubMed Central

    Pradeep Ram, Angia Sriram; Colombet, Jonathan; Perriere, Fanny; Thouvenot, Antoine; Sime-Ngando, Télesphore

    2016-01-01

    The current consensus concerning the viral regulation of prokaryotic carbon metabolism is less well-studied, compared to substrate availability. We explored the seasonal and vertical distribution of viruses and its relative influence on prokaryotic carbon metabolism in a hypereutrophic reservoir, Lake Villerest (France). Flow cytometry and transmission electron microscopy (TEM) analyses to determine viral abundance (VA; range = 6.1–63.5 × 107 ml-1) and viral infection rates of prokaryotes (range = 5.3–32%) respectively suggested that both the parameters varied more significantly with depths than with seasons. Prokaryotic growth efficiency (PGE, considered as a proxy of prokaryotic carbon metabolism) calculated from prokaryotic production and respiration measurements (PGE = prokaryotic production/[prokaryotic production + prokaryotic respiration] × 100) varied from 14 to 80% across seasons and depths. Viruses through selective lyses had antagonistic impacts on PGE by regulating key prokaryotic metabolic processes (i.e., production and respiration). Higher viral lysis accompanied by higher respiration rates and lower PGE in the summer (mean = 22.9 ± 10.3%) than other seasons (mean = 59.1 ± 18.6%), led to significant loss of carbon through bacterial-viral loop and shifted the reservoir system to net heterotrophy. Our data therefore suggests that the putative adverse impact of viruses on the growth efficiency of the prokaryotic community can have strong implications on nutrient flux patterns and on the overall ecosystem metabolism in anthropogenic dominated aquatic systems such as Lake Villerest. PMID:26903963

  8. Dynamic Pore-scale Reservoir-condition Imaging of Reaction in Carbonates Using Synchrotron Fast Tomography.

    PubMed

    Menke, Hannah P; Andrew, Matthew G; Vila-Comamala, Joan; Rau, Christoph; Blunt, Martin J; Bijeljic, Branko

    2017-02-21

    Underground storage permanence is a major concern for carbon capture and storage. Pumping CO2 into carbonate reservoirs has the potential to dissolve geologic seals and allow CO2 to escape. However, the dissolution processes at reservoir conditions are poorly understood. Thus, time-resolved experiments are needed to observe and predict the nature and rate of dissolution at the pore scale. Synchrotron fast tomography is a method of taking high-resolution time-resolved images of complex pore structures much more quickly than traditional µ-CT. The Diamond Lightsource Pink Beam was used to dynamically image dissolution of limestone in the presence of CO2-saturated brine at reservoir conditions. 100 scans were taken at a 6.1 µm resolution over a period of 2 hours. The images were segmented and the porosity and permeability were measured using image analysis and network extraction. Porosity increased uniformly along the length of the sample; however, the rate of increase of both porosity and permeability slowed at later times.

  9. APPLICATION OF RESERVOIR CHARACTERIZATION AND ADVANCED TECHNOLOGY TO IMPROVE RECOVERY AND ECONOMICS IN A LOWER QUALITY SHALLOW SHELF SAN ANDRES RESERVOIR

    SciTech Connect

    Raj Kumar; Keith Brown; T. Scott Hickman; James J. Justice

    2000-04-27

    The Class 2 Project at West Welch was designed to demonstrate the use of advanced technologies to enhance the economics of improved oil recovery (IOR) projects in lower quality Shallow Shelf Carbonate (SSC) reservoirs, resulting in recovery of additional oil that would otherwise be left in the reservoir at project abandonment. Accurate reservoir description is critical to the effective evaluation and efficient design of IOR projects in the heterogeneous SSC reservoirs. Therefore, the majority of Budget Period 1 was devoted to reservoir characterization. Technologies being demonstrated include: (1) Advanced petrophysics; (2) Three-dimensional (3-D) seismic; (3) Crosswell bore tomography; (4) Advanced reservoir simulation; (5) Carbon dioxide (CO{sub 2}) stimulation treatments; (6) Hydraulic fracturing design and monitoring; and (7) Mobility control agents.

  10. APPLICATION OF RESERVOIR CHARACTERIZATION AND ADVANCED TECHNOLOGY TO IMPROVE RECOVERY AND ECONOMICS IN A LOWER QUALITY SHALLOW SHELF SAN ANDRES RESERVOIR

    SciTech Connect

    T. Scott Hickman; James J. Justice

    2001-12-11

    The Class 2 Project at West Welch was designed to demonstrate the use of advanced technologies to enhance the economics of improved oil recovery (IOR) projects in lower quality Shallow Shelf Carbonate (SSC) reservoirs, resulting in recovery of additional oil that would otherwise be left in the reservoir at project abandonment. Accurate reservoir description is critical to the effective evaluation and efficient design of IOR projects in the heterogeneous SSC reservoirs. Therefore, the majority of Budget Period 1 was devoted to reservoir characterization. Technologies being demonstrated include: (1) Advanced petrophysics; (2) Three-dimensional (3-D) seismic; (3) Crosswell bore tomography; (4) Advanced reservoir simulation; (5) Carbon dioxide (CO{sub 2}) stimulation treatments; (6) Hydraulic fracturing design and monitoring; and (7) Mobility control agents.

  11. APPLICATION OF RESERVOIR CHARACTERIZATION AND ADVANCED TECHNOLOGY TO IMPROVE RECOVERY AND ECONOMICS IN A LOWER QUALITY SHALLOW SHELF SAN ANDRES RESERVOIR

    SciTech Connect

    T. Scott Hickman

    2003-01-17

    The Class 2 Project at West Welch was designed to demonstrate the use of advanced technologies to enhance the economics of improved oil recovery (IOR) projects in lower quality Shallow Shelf Carbonate (SSC) reservoirs, resulting in recovery of additional oil that would otherwise be left in the reservoir at project abandonment. Accurate reservoir description is critical to the effective evaluation and efficient design of IOR projects in the heterogeneous SSC reservoirs. Therefore, the majority of Budget Period 1 was devoted to reservoir characterization. Technologies being demonstrated include: (1) Advanced petrophysics; (2) Three-dimensional (3-D) seismic; (3) Crosswell bore tomography; (4) Advanced reservoir simulation; (5) Carbon dioxide (CO{sub 2}) stimulation treatments; (6) Hydraulic fracturing design and monitoring; and (7) Mobility control agents.

  12. APPLICATION OF RESERVOIR CHARACTERIZATION AND ADVANCED TECHNOLOGY TO IMPROVE RECOVERY AND ECONOMICS IN A LOWER QUALITY SHALLOW SHELF SAN ANDRES RESERVOIR

    SciTech Connect

    T. Scott Hickman; James J. Justice

    2001-08-10

    The Class 2 Project at West Welch was designed to demonstrate the use of advanced technologies to enhance the economics of improved oil recovery (IOR) projects in lower quality Shallow Shelf Carbonate (SSC) reservoirs, resulting in recovery of additional oil that would otherwise be left in the reservoir at project abandonment. Accurate reservoir description is critical to the effective evaluation and efficient design of IOR projects in the heterogeneous SSC reservoirs. Therefore, the majority of Budget Period 1 was devoted to reservoir characterization. Technologies being demonstrated include: (1) Advanced petrophysics; (2) Three-dimensional (3-D) seismic; (3) Crosswell bore tomography; (4) Advanced reservoir simulation; (5) Carbon dioxide (CO{sub 2}) stimulation treatments; (6) Hydraulic fracturing design and monitoring; and (7) Mobility control agents.

  13. APPLICATION OF RESERVOIR CHARACTERIZATION AND ADVANCED TECHNOLOGY TO IMPROVE RECOVERY AND ECONOMICS IN A LOWER QUALITY SHALLOW SHELF SAN ANDRES RESERVOIR

    SciTech Connect

    T. Scott Hickman; James J. Justice

    2001-06-16

    The Class 2 Project at West Welch was designed to demonstrate the use of advanced technologies to enhance the economics of improved oil recovery (IOR) projects in lower quality Shallow Shelf Carbonate (SSC) reservoirs, resulting in recovery of additional oil that would otherwise be left in the reservoir at project abandonment. Accurate reservoir description is critical to the effective evaluation and efficient design of IOR projects in the heterogeneous SSC reservoirs. Therefore, the majority of Budget Period 1 was devoted to reservoir characterization. Technologies being demonstrated include: (1) Advanced petrophysics; (2) Three-dimensional (3-D) seismic; (3) Crosswell bore tomography; (4) Advanced reservoir simulation; (5) Carbon dioxide (CO{sub 2}) stimulation treatments; (6) Hydraulic fracturing design and monitoring; and (7) Mobility control agents.

  14. INTEGRATED OUTCROP AND SUBSURFACE STUDIES OF THE INTERWELL ENVIRONMENT OF CARBONATE RESERVOIRS: CLEAR FORK (LEONARDIAN-AGE) RESERVOIRS, WEST TEXAS AND NEW MEXICO

    SciTech Connect

    F. Jerry Lucia

    2002-01-31

    This is the final report of the project ''Integrated Outcrop and Subsurface Studies of the Interwell Environment of Carbonate Reservoirs: Clear Fork (Leonardian-Age) Reservoirs, West Texas and New Mexico'', Department of Energy contract no. DE-AC26-98BC15105 and is the third in a series of similar projects funded jointly by the U.S. Department of Energy and The University of Texas at Austin, Bureau of Economic Geology, Reservoir Characterization Research Laboratory for Carbonates. All three projects focus on the integration of outcrop and subsurface data for the purpose of developing improved methods for modeling petrophysical properties in the interwell environment. The first project, funded by contract no. DE-AC22-89BC14470, was a study of San Andres outcrops in the Algerita Escarpment, Guadalupe Mountains, Texas and New Mexico, and the Seminole San Andres reservoir, Permian Basin. This study established the basic concepts for constructing a reservoir model using sequence-stratigraphic principles and rock-fabric, petrophysical relationships. The second project, funded by contract no. DE-AC22-93BC14895, was a study of Grayburg outcrops in the Brokeoff Mountains, New Mexico, and the South Cowden Grayburg reservoir, Permian Basin. This study developed a sequence-stratigraphic succession for the Grayburg and improved methods for locating remaining hydrocarbons in carbonate ramp reservoirs. The current study is of the Clear Fork Group in Apache Canyon, Sierra Diablo Mountains, West Texas, and the South Wasson Clear Fork reservoir, Permian Basin. The focus was on scales of heterogeneity, imaging high- and low-permeability layers, and the impact of fractures on reservoir performance. In this study (1) the Clear Fork cycle stratigraphy is defined, (2) important scales of petrophysical variability are confirmed, (3) a unique rock-fabric, petrophysical relationship is defined, (4) a porosity method for correlating high-frequency cycles and defining rock-fabric flow layers

  15. CO2 Huff-n-Puff Process in a Light Oil Shallow Shelf Carbonate Reservoir

    SciTech Connect

    Boomer, R.J.; Cole, R.; Kovar, M.; Prieditis, J.; Vogt, J.; Wehner, S.

    1999-02-24

    The application cyclic CO2, often referred to as the CO2 Huff-n-Puff process, may find its niche in the maturing waterfloods of the Permian Basin. Coupling the CO2 Huff-n-Puff process to miscible flooding applications could provide the needed revenue to sufficiently mitigate near-term negative cash flow concerns in capital-intensive miscible projects. Texaco Exploration and Production Inc. and the US Department of Energy have teamed up in a attempt to develop the CO2 Huff-n-Puff process in the Grayburg and San Andres formations which are light oil, shallow shelf carbonate reservoirs that exist throughout the Permian Basin. This cost-shared effort is intended to demonstrate the viability of this underutilized technology in a specific class of domestic reservoir.

  16. Karst-controlled reservoir heterogeneity in Ellenburger group carbonates of west Texas: Discussion

    SciTech Connect

    Mazzullo, S.J. )

    1990-07-01

    A discussion is presented on a paper by Charles Kerans (AAPG Bull. 1988). The paper dealt with karst-associated porosity and hydrocarbon reservoir heterogenity in Ellengurger (Lower Ordovician) carbonates in the Permian basin of west Texas. The purpose of this paper is not to dispute the model presented by Kerans, but instead to present some alternative models of reservoir occurrence that are not considered in his paper and that are also widely applicable to the Ellenburger and correlative strata in the Mid-Continent. The discussion is based on regional lithostratigraphy and subsurface mapping studies of the Ellenburger in the southern Midland basin, specifically in Irion, Reagan, Crockett, Schleicher, and Sterling counties (Texas).

  17. CO{sub 2} Huff-n-Puff process in a light oil shallow shelf carbonate reservoir. Quarterly technical progress report, October--December 1996

    SciTech Connect

    Wehner, S.; Prieditis, J.

    1996-12-31

    The principal objective of the Central Vacuum Unit (CVU) CO{sub 2} Huff-n-Puff (H-n-P) project is to determine the feasibility and practicality of the technology in a waterflooded shallow shelf carbonate environment. The results of parametric simulation of the CO{sub 2} H-n-P process, coupled with the CVU reservoir characterization components will be used to determine if this process is technically and economically feasible for field implementation. The technology transfer objective of the project is to disseminate the knowledge gained through an innovative plan in support of the Department of energy`s (DOE) objective of increasing domestic oil production and deferring the abandonment of shallow shelf carbonate reservoirs. Texaco Exploration and Production Inc`s. (TEPI) mid-term plans are to implement a full-scale miscible CO{sub 2} project in the CVU. TEPI concluded all of the tasks associated with the First Budget Period by October, 1995. The DOE approved the TEPI continuation application. Budget Period No. 2 is in progress. Initial injection of CO{sub 2} began in November, and after a short shut-in period for the soak, the well was returned to production in late December, 1995. This report, covers TEPI`s efforts at history matching the results of the field demonstration. Costs and economics of the work are presented. The majority of effort during the fourth quarter has revolved around the selection of a new project site and refinement of the demonstration design and well selection.

  18. Geochemical modeling of scale formation, and formation damage during production from sulfate and carbonate mineral-bearing reservoirs

    SciTech Connect

    Macgowan, D.B.; Dunn, T.L.; Surdam, R.C. )

    1991-03-01

    The physical and chemical processes that affect reservoir fluids during production can be modeled by methodologies similar to those used for modeling clastic diagenesis. That these processes may result in formation damage and scale formation make them of interest to production geologists and engineers. Pathway modeling, based upon a series of critical divides, predicts which reactions are likely to occur between formation, production tubing, and reservoir fluids. Thermodynamic equilibria modeling calculates direction and magnitude of possible reactions. Integration of these approaches with observations of patterns of scale formation, production line, and formation damage yield a model capable of predicting the magnitude and direction of reactions that may produce negative impacts on reservoir production. Critical divides characterizing these processes in carbonate and sulfate mineral-bearing reservoirs include: (1) presence or absence of sulfate-bearing minerals within the production volume; (2) presence of iron within production line or formation; (3) ratio of concentration of bicarbonate to hydrogen sulfide; (4) capacity of aqueous and solid phases to buffer formation fluid pH; and (5) magnitude of pressure and temperature drops during production. The model qualitatively predicts: (1) likelihood of sulfide, sulfate, or carbonate mineral precipitation during production; (2) souring of the reservoir; and (3) corrosion of production tubing. The model has been developed from production histories for Weber Sandstone reservoirs, Colorado and Wyoming, and has been applied to examples of reservoir production from Tensleep and Minnelusa reservoirs in Wyoming.

  19. Integrative analysis of a lacustrine carbonate reservoir, Kambala field, Cabinda, Angola

    SciTech Connect

    Lomando, A.J.; Griscom, M. )

    1993-09-01

    The presalt lacustrine rift basins of west Africa are the continued focus of exploration and development in this prolific petroleum province. Kambala field produces from the Barremian-Aptian lacustrine carbonates of the TOCA Formation. Source rocks are the rich lacustrine shales of the Bucomazi Formation. TOCA carbonates were deposited along major shorelines and around islands in large lake systems. Reservoir studies provide the necessary models and analogs to guide exploration and evaluation efforts. The TOCA reservoirs in Kambala field have been subdivided into two units. The lower TOCA is characterized by limestones and cherty dolomites, which range texturally from high-energy ooid and oncoid grainstones and packstones to lower energy ostracod wackestones and marls. The upper and lower TOCA are separated by a unit of middle Bucomazi shale. The upper TOCA is composed of thin beds of low-energy facies and thick porous carbonate units, which are pervasively dolomitized. Kambala field sits over a northwest-southeast-trending basement high. The field is bounded by intense faulting on the west and dips gently to the northeast. The faults on the eastern side are more widely spaced and have less throw than the ones on the west. Seismic amplitude maps on the upper TOCA show markedly higher amplitudes on the western and southern edges of the field. The high seismic amplitudes and intense faulting generally correlate with the zone of porous dolomite.

  20. A light carbon reservoir recorded in zircon-hosted diamond from the Jack Hills.

    PubMed

    Nemchin, Alexander A; Whitehouse, Martin J; Menneken, Martina; Geisler, Thorsten; Pidgeon, Robert T; Wilde, Simon A

    2008-07-03

    The recent discovery of diamond-graphite inclusions in the Earth's oldest zircon grains (formed up to 4,252 Myr ago) from the Jack Hills metasediments in Western Australia provides a unique opportunity to investigate Earth's earliest known carbon reservoir. Here we report ion microprobe analyses of the carbon isotope composition of these diamond-graphite inclusions. The observed delta(13)C(PDB) values (expressed using the PeeDee Belemnite standard) range between -5 per mil and -58 per mil with a median of -31 per mil. This extends beyond typical mantle values of around -6 per mil to values observed in metamorphic and some eclogitic diamonds that are interpreted to reflect deep subduction of low-delta(13)C(PDB) biogenic surface carbon. Low delta(13)C(PDB) values may also be produced by inorganic chemical reactions, and therefore are not unambiguous evidence for life on Earth as early as 4,250 Myr ago. Regardless, our results suggest that a low-delta(13)C(PDB) reservoir may have existed on the early Earth.

  1. The identification of multi-cave combinations in carbonate reservoirs based on sparsity constraint inverse spectral decomposition

    NASA Astrophysics Data System (ADS)

    Li, Qian; Di, Bangrang; Wei, Jianxin; Yuan, Sanyi; Si, Wenpeng

    2016-12-01

    Sparsity constraint inverse spectral decomposition (SCISD) is a time-frequency analysis method based on the convolution model, in which minimizing the l1 norm of the time-frequency spectrum of the seismic signal is adopted as a sparsity constraint term. The SCISD method has higher time-frequency resolution and more concentrated time-frequency distribution than the conventional spectral decomposition methods, such as short-time Fourier transformation (STFT), continuous-wavelet transform (CWT) and S-transform. Due to these good features, the SCISD method has gradually been used in low-frequency anomaly detection, horizon identification and random noise reduction for sandstone and shale reservoirs. However, it has not yet been used in carbonate reservoir prediction. The carbonate fractured-vuggy reservoir is the major hydrocarbon reservoir in the Halahatang area of the Tarim Basin, north-west China. If reasonable predictions for the type of multi-cave combinations are not made, it may lead to an incorrect explanation for seismic responses of the multi-cave combinations. Furthermore, it will result in large errors in reserves estimation of the carbonate reservoir. In this paper, the energy and phase spectra of the SCISD are applied to identify the multi-cave combinations in carbonate reservoirs. The examples of physical model data and real seismic data illustrate that the SCISD method can detect the combination types and the number of caves of multi-cave combinations and can provide a favourable basis for the subsequent reservoir prediction and quantitative estimation of the cave-type carbonate reservoir volume.

  2. FMS/FMI borehole imaging of carbonate gas reservoirs, Central Luconia Province, offshore Sarawak, Malaysia

    SciTech Connect

    Singh, U.; Van der Baan, D. )

    1994-07-01

    The Central Luconia Province, offshore Sarawak, is a significant gas province characterized by extensive development of late Miocene carbonate buildups. Some 200 carbonate structures have been seismically mapped of which 70 have been drilled. FMS/FMI borehole images were obtained from three appraisal wells drilled in the [open quotes]M[close quotes] cluster gas fields situated in the northwestern part of the province. The [open quotes]M[close quotes] cluster fields are currently part of an upstream gas development project to supply liquefied natural gas. Log facies recognition within these carbonate gas reservoirs is problematic due mainly to the large gas effect. This problem is being addressed by (1) application of neural network techniques and (2) using borehole imaging tools. Cores obtained from the M1, M3, and M4 gas fields were calibrated with the FMS/FMI images. Reservoir characterization was obtained at two different scales. The larger scale (i.e., 1:40 and 1:200) involved static normalized images where the vertical stacking pattern was observed based on recognition of bed boundaries. In addition, the greater vertical resolution of the FMS/FMI images allowed recognition of thin beds. For recognition of specific lithofacies, dynamically normalized images were used to highlight lithofacies-specific sedimentary features, e.g., clay seams/stylolites, vugs, and breccia zones. In general, the FMS/FMI images allowed (1) easier recognition of reservoir features, e.g., bed boundaries, and (2) distinction between lithofacies that are difficult to characterize on conventional wireline logs.

  3. Layer definition and pressure buildup case histories in a carbonate reservoir

    SciTech Connect

    Vadgama, U.N.; Arifi, N.A.

    1981-01-01

    This paper presents case histories of pressure buildup analysis in a layered carbonate reservoir (Zella/Aswad Fields in the Socialist People's Libyan Arab Jamahiria). The productive formation consists of several dolomite and limestone layers separated by thin tight streaks. Lack of pressure communication between layers has been determined by pressure measurements in the individual layers using the Repeat Formation Tester (RFT). Results of the two-dimensional radial model simulated pressure buildup performance are compared to the actual measured pressure buildup data. 14 refs.

  4. Methane hydrate - A major reservoir of carbon in the shallow geosphere?

    USGS Publications Warehouse

    Kvenvolden, K.A.

    1988-01-01

    Methane hydrates are solids composed of rigid cages of water molecules that enclose methane. Sediment containing methane hydrates is found within specific pressure-temperature conditions that occur in regions of permafrost and beneath the sea in outer continental margins. Because methane hydrates are globally widespread and concentrate methane within the gas-hydrate structure, the potential amount of methane present in the shallow geosphere at subsurface depths of < ???2000 m is very large. However, estimates of the amount are speculative and range over about three orders of magnitude, from 2 ?? 103 to 4 ?? 106 Gt (gigatons = 1015 g) of carbon, depending on the assumptions made. The estimate I favor is ??? 1 ?? 104 Gt of carbon. The estimated amount of organic carbon in the methane-hydrate reservoir greatly exceeds that in many other reservoirs of the global carbon cycle - for example, the atmosphere (3.6 Gt); terrestrial biota (830 Gt); terrestrial soil, detritus and peat (1960 Gt); marine biota (3 Gt); and marine dissolved materials (980 Gt). In fact, the amount of carbon may exceed that in all fossil fuel deposits (5 ?? 103 Gt). Because methane hydrates contain so much methane and occur in the shallow geosphere, they are of interest as a potential resource of natural gas and as a possible source of atmospheric methane released by global warming. As a potential resource, methane hydrates pose both engineering and production problems. As a contributor to a changing global climate, destabilized methane hydrates, particularly those in shallow, nearshore regions of the Arctic Ocean, may have some effect, but this effect will probably be minimal, at least during the next 100 years. ?? 1988.

  5. A Constrained Differential Evolution Algorithm for Reservoir Management: Optimal Placement and Control of Wells for Geological Carbon Storage with Uncertainty in Reservoir Properties

    NASA Astrophysics Data System (ADS)

    Cihan, A.; Birkholzer, J. T.; Bianchi, M.

    2014-12-01

    Injection of large volume of CO2 into deep geological reservoirs for geologic carbon sequestration (GCS) is expected to cause significant pressure perturbations in subsurface. Large-scale pressure increases in injection reservoirs during GCS operations, if not controlled properly, may limit dynamic storage capacity and increase risk of environmental impacts. The high pressure may impact caprock integrity, induce fault slippage, and cause leakage of brine and/or CO2 into shallow fresh groundwater resources. Thus, monitoring and controlling pressure buildup are critically important for environmentally safe implementation of GCS projects. Extraction of native brine during GCS operations is a pressure management approach to reduce significant pressure buildup. Extracted brine can be transferred to the surface for utilization or re-injected into overlying/underlying saline aquifers. However, pumping, transportation, treatment and disposal of extracted brine can be challenging and costly. Therefore, minimizing volume of extracted brine, while maximizing CO2 storage, is an essential objective of the pressure management with brine extraction schemes. Selection of optimal well locations and extraction rates are critical for maximizing storage and minimizing brine extraction during GCS. However, placing of injection and extraction wells is not intuitive because of heterogeneity in reservoir properties and complex reservoir geometry. Efficient computerized algorithms combining reservoir models and optimization methods are needed to make proper decisions on well locations and control parameters. This study presents a global optimization methodology for pressure management during geologic CO2 sequestration. A constrained differential evolution (CDE) algorithm is introduced for solving optimization problems involving well placement and injection/extraction control. The CDE methodology is tested and applied for realistic CO2 storage scenarios with the presence of uncertainty in

  6. From the pore scale to reservoir scale: Lithohydraulic flow unit characterization of a shallow shelf carbonate reservoir, North Robertson Unit, West Texas

    SciTech Connect

    Vessell, R.K.; Davies, D.K. )

    1996-01-01

    This paper presents the results of integrated geological-petrophysical reservoir characterization performed as part of the US Department of Energy Class II reservoir program. Petrographic image analysis, using a specially equipped SEM, allowed for the identification of 8 petrophysical rock types at the North Robertson Unit. Detailed log analysis resulted in the development of algorithms for the log-based identification of these rock types in 109 wells. Porosity was related to permeability for each Rock Type: thus permeability is determined from well log data. Evaluation of porosity, permeability, Sw and HPV distribution has allowed for the identification of 12 lithohydraulic flow units. These flow units have been mapped across the unit. The technique allows for the development of log-based reservoir models that are simulator-ready. The results of this study have application to all heterogeneous, shallow shelf carbonate reservoirs, they demonstrate that large fields can be successfully characterized using few cores and emphasize the importance of integrated geological-engineering analysis in reservoir characterization.

  7. From the pore scale to reservoir scale: Lithohydraulic flow unit characterization of a shallow shelf carbonate reservoir, North Robertson Unit, West Texas

    SciTech Connect

    Vessell, R.K.; Davies, D.K.

    1996-12-31

    This paper presents the results of integrated geological-petrophysical reservoir characterization performed as part of the US Department of Energy Class II reservoir program. Petrographic image analysis, using a specially equipped SEM, allowed for the identification of 8 petrophysical rock types at the North Robertson Unit. Detailed log analysis resulted in the development of algorithms for the log-based identification of these rock types in 109 wells. Porosity was related to permeability for each Rock Type: thus permeability is determined from well log data. Evaluation of porosity, permeability, Sw and HPV distribution has allowed for the identification of 12 lithohydraulic flow units. These flow units have been mapped across the unit. The technique allows for the development of log-based reservoir models that are simulator-ready. The results of this study have application to all heterogeneous, shallow shelf carbonate reservoirs, they demonstrate that large fields can be successfully characterized using few cores and emphasize the importance of integrated geological-engineering analysis in reservoir characterization.

  8. Role of sediments for dissolved organic carbon (DOC) in lakes and reservoirs

    NASA Astrophysics Data System (ADS)

    Dadi, Tallent; Wendt-Potthoff, Katrin; Friese, Kurt; Koschorreck, Matthias

    2016-04-01

    Increasing dissolved organic carbon (DOC) concentrations have been observed in many surface waters and the increasing trend is expected to continue in the future. This leads to higher water treatment costs to remove the DOC, and to potential formation of toxic, carcinogenic disinfection by-products like trihalomethanes. Ecological status can also be affected since DOC will alter the under water light regime. The sediment water interface is a potential hot spot of DOC turnover in aquatic systems. We investigated benthic DOC exchange for a complete year in two similar reservoirs (Hassel and Rappbode pre-dams, Germany) located in catchments with different land use patterns. We quantified seasonal DOC and other solute fluxes in both the riverine and lacustrine zones of the reservoirs by sediment incubation at in situ conditions. This allowed us to assess the effect of redox conditions and temperature on benthic matter fluxes. Redox conditions appeared to be the primary regulator of DOC exchange, with uptake of DOC under oxic conditions and release of DOC under anoxic conditions. Temperature effects were appararent by the increased DOC fluxes in summer, in the lacustrine zones. The benthic flux of DOC was closely linked to the fluxes of iron and phosphorus, suggesting that adsorption of DOC to Fe mineral surfaces was the major regulating mechanism behind the observed results. The DOC fluxes seem not to be influenced by the trophic state of the reservoirs which indicates that land use differences in the catchments have minimal effects on benthic DOC turnover.

  9. A microchip-based endothelium mimic utilizing open reservoirs for cell immobilization and integrated carbon ink microelectrodes for detection.

    PubMed

    Hulvey, Matthew K; Martin, R Scott

    2009-01-01

    This paper describes the fabrication and characterization of a microfluidic device that utilizes a reservoir-based approach for endothelial cell immobilization and integrated embedded carbon ink microelectrodes for the amperometric detection of extracellular nitric oxide (NO) release. The design utilizes a buffer channel to continuously introduce buffer or a plug of stimulant to the reservoir as well as a separate sampling channel that constantly withdraws buffer from the reservoir and over the microelectrode. A steel pin is used for both the fluidic connection to the sampling channel and to provide a quasi-reference electrode for the carbon ink microelectrode. Characterization of the device was performed using NO standards produced from a NONOate salt. Finally, NO release from a layer of immobilized endothelial cells was monitored and quantified using the system. This system holds promise as a means to electrochemically detect extracellular NO release from endothelial cells in either an array of reservoirs or concurrently with fluorescence-based intracellular NO measurements.

  10. Stratigraphic sections showing coal correlations within the lower coal zone of the Paleocene Fort Union Formation, Fillmore Ranch and Seaverson Reservoir quadrangles, Carbon County, Wyoming

    SciTech Connect

    Honey, J.G.; Hettinger, R.D.

    1989-01-01

    Stratigraphic sections showing coal correlations within the lower coal zone of the Paleocene Fort Union Formation, Fillmore Ranch and Seaverson Reservoir quadrangles, Carbon County, Wyoming are presented.

  11. Hydrothermal simulation of a fractured carbonate reservoir in southern Italy and automated detections of optimal positions for geothermal doublet installations

    NASA Astrophysics Data System (ADS)

    Niederau, Jan; Gomez, Sergio; Ebigbo, Anozie; Inversi, Barbara; Marquart, Gabriele; Scrocca, Davide

    2015-04-01

    In this work, we present the results of hydrothermal simulations for assessing the geothermal potential of a fractured carbonate reservoir in Campania (Guardia Lombardi). Local surface heat flows of up to 90 mW/m² suggest that this area is a potential medium-enthalpy geothermal reservoir. The targeted reservoir rocks are fractured shallow-water carbonates (Jurassic to Cretaceous) of the Apulia Platform. During the Apennine orogeny, those carbonates were affected by at least two tectonic phases: Thrust-related folding of the carbonate platform due to compression followed by extension which caused major normal faulting. Based on seismic interpretation, a discretized structural model is set up, comprising the reservoir unit and the overlying sedimentary cover. The model comprises an area of 42 km × 28 km and extends to a depth of about six kilometers. Results of calibrated hydrothermal reservoir simulations suggest that free convection occurs in some parts of the reservoir. For assessing optimal locations for potential hydrothermal doublet systems, a tool was developed which uses the results of the reservoir simulationsin combination with predefined constraints. Those constraints or minimum requirements consider: a) minimum temperature for operating the doublet system, b) minimum matrix permeability allowing for a pumping rate of 40 L/s, and c) social constraints (location of cities or conservation areas, where the construction of a potential geothermal energy plant would be problematic). The optimization tool ranks possible doublet system locations by evaluating an objective function for the minimum requirements. Those locations are further used to extract smaller models from the big reservoir model and simulate the operation of a hypothetical geothermal doublet system. By assessing the optimized results, an optimal location of a geothermal energy plant would produce water with a temperature of 163 °C from a depth of almost 4 km.

  12. The impact of reservoir conditions on the residual trapping of carbon dioxide in Berea sandstone

    NASA Astrophysics Data System (ADS)

    Niu, Ben; Al-Menhali, Ali; Krevor, Samuel C.

    2015-04-01

    The storage of carbon dioxide in deep brine-filled permeable rocks is an important tool for CO2 emissions mitigation on industrial scales. Residual trapping of CO2 through capillary forces within the pore space of the reservoir is one of the most significant mechanisms for storage security and is also a factor determining the ultimate extent of CO2 migration within the reservoir. In this study we have evaluated the impact of reservoir conditions of pressure, temperature, and brine salinity on the residual trapping characteristic curve of a fired Berea sandstone rock. The observations demonstrate that the initial-residual characteristic trapping curve is invariant across a wide range of pressure, temperature, and brine salinities and is also the same for CO2-brine systems as a N2-water system. The observations were made using a reservoir condition core-flooding laboratory that included high-precision pumps, temperature control, the ability to recirculate fluids for weeks at a time, and an X-ray CT scanner. Experimental conditions covered pressures of 5-20 MPa, temperatures of 25-50°C, and 0-5 mol/kg NaCl brine salinity. A novel coreflooding approach was developed, making use of the capillary end effect to create a large range in initial CO2 saturation (0.15-0.6) in a single coreflood. Upon subsequent flooding with CO2-equilibriated brine, the observation of residual saturation corresponded to the wide range of initial saturations before flooding resulting in a rapid construction of the initial-residual curve. For each condition we report the initial-residual curve and the resulting parameterization of the Land hysteresis models.

  13. Mobilization and Transport of Organic Compounds from Reservoir Rock and Caprock in Geological Carbon Sequestration Sites

    SciTech Connect

    Zhong, Lirong; Cantrell, Kirk J.; Mitroshkov, Alexandre V.; Shewell, Jesse L.

    2014-05-06

    Supercritical CO2 (scCO2) is an excellent solvent for organic compounds, including benzene, toluene, ethyl-benzene, and xylene (BTEX), phenols, and polycyclic aromatic hydrocarbons (PAHs). Monitoring results from geological carbon sequestration (GCS) field tests has shown that organic compounds are mobilized following CO2 injection. Such results have raised concerns regarding the potential for groundwater contamination by toxic organic compounds mobilized during GCS. Knowledge of the mobilization mechanism of organic compounds and their transport and fate in the subsurface is essential for assessing risks associated with GCS. Extraction tests using scCO2 and methylene chloride (CH2Cl2) were conducted to study the mobilization of volatile organic compounds (VOCs, including BTEX), the PAH naphthalene, and n-alkanes (n-C20 – n-C30) by scCO2 from representative reservoir rock and caprock obtained from depleted oil reservoirs and coal from an enhanced coal-bed methane recovery site. More VOCs and naphthalene were extractable by scCO2 compared to the CH2Cl2 extractions, while scCO2 extractable alkane concentrations were much lower than concentrations extractable by CH2Cl2. In addition, dry scCO2 was found to extract more VOCs than water saturated scCO2, but water saturated scCO2 mobilized more naphthalene than dry scCO2. In sand column experiments, moisture content was found to have an important influence on the transport of the organic compounds. In dry sand columns the majority of the compounds were retained in the column except benzene and toluene. In wet sand columns the mobility of the BTEX was much higher than that of naphthalene. Based upon results determined for the reservoir rock, caprock, and coal samples studied here, the risk to aquifers from contamination by organic compounds appears to be relatively low; however, further work is necessary to fully evaluate risks from depleted oil reservoirs.

  14. Reservoir uncertainty, Precambrian topography, and carbon sequestration in the Mt. Simon Sandstone, Illinois Basin

    USGS Publications Warehouse

    Leetaru, H.E.; McBride, J.H.

    2009-01-01

    Sequestration sites are evaluated by studying the local geological structure and confirming the presence of both a reservoir facies and an impermeable seal not breached by significant faulting. The Cambrian Mt. Simon Sandstone is a blanket sandstone that underlies large parts of Midwest United States and is this region's most significant carbon sequestration reservoir. An assessment of the geological structure of any Mt. Simon sequestration site must also include knowledge of the paleotopography prior to deposition. Understanding Precambrian paleotopography is critical in estimating reservoir thickness and quality. Regional outcrop and borehole mapping of the Mt. Simon in conjunction with mapping seismic reflection data can facilitate the prediction of basement highs. Any potential site must, at the minimum, have seismic reflection data, calibrated with drill-hole information, to evaluate the presence of Precambrian topography and alleviate some of the uncertainty surrounding the thickness or possible absence of the Mt. Simon at a particular sequestration site. The Mt. Simon is thought to commonly overlie Precambrian basement granitic or rhyolitic rocks. In places, at least about 549 m (1800 ft) of topographic relief on the top of the basement surface prior to Mt. Simon deposition was observed. The Mt. Simon reservoir sandstone is thin or not present where basement is topographically high, whereas the low areas can have thick Mt. Simon. The paleotopography on the basement and its correlation to Mt. Simon thickness have been observed at both outcrops and in the subsurface from the states of Illinois, Ohio, Wisconsin, and Missouri. ?? 2009. The American Association of Petroleum Geologists/Division of Environmental Geosciences. All rights reserved.

  15. Controls on reservoir development in a shelf carbonate: Upper Jurassic smackover formation of Alabama

    SciTech Connect

    Kopaska-Merkel, D.C.; Mann, S.D.; Schmoker, J.W.

    1994-06-01

    Hydrocarbon reservoirs of the Upper Jurassic Smackover Formation in Alabama are predominately oolitic and pelletal dolostone. Pore systems are dominated by moldic and secondary intraparticle pores, intercrystalline pores, or mixtures of these pore types. All Smackover reservoirs in Alabama have been strongly affected by early cementation, dissolution of calcium-carbonate allochems, and dolomitization. Dolomitization of the Smackover in Alabama included penecontemporaneous, early burial, and late (deep) burial episodes. Fabric-selective dolomitization yielded reservoirs strongly influenced by both depositional fabric and diagenesis. Nonselective dolomitization yielded reservoirs with intercrystalline pore systems shaped primarily by diagenesis. Thermal exposure is inversely related to porosity, but the relationship is weak (r{sup 2} < 0.5). Fabric-selective dolostone is slightly more porous than nonselective dolostone when averaged over the entire study area (averages of 18.1% and 15.1%, respectively; p = 0.0001), but nonselective dolostone is more porous at a given level of equivalent vitrinite reflectance. Smackover fields on the north flank of the Wiggins arch are unusually porous given their level of thermal maturity, and are unusual in other ways as well. Local porosity variation was controlled by depositional fabric, early cementation, dissolution, and burial compaction and cementation. Regional permeability variation cannot be explained using existing data. Permeability is locally controlled by pore-throat size, the effects of dolomite crystal-size distribution, early cementation, fracturing, and burial compaction and cementation. Pore-throat size exhibits the strongest overall correlation with permeability (r{sup 2} = 0.54). Permeability and porosity are strongly correlated locally, but the regional correlation is weak.

  16. High Primary Production Contrasts with Intense Carbon Emission in a Eutrophic Tropical Reservoir.

    PubMed

    Almeida, Rafael M; Nóbrega, Gabriel N; Junger, Pedro C; Figueiredo, Aline V; Andrade, Anízio S; de Moura, Caroline G B; Tonetta, Denise; Oliveira, Ernandes S; Araújo, Fabiana; Rust, Felipe; Piñeiro-Guerra, Juan M; Mendonça, Jurandir R; Medeiros, Leonardo R; Pinheiro, Lorena; Miranda, Marcela; Costa, Mariana R A; Melo, Michaela L; Nobre, Regina L G; Benevides, Thiago; Roland, Fábio; de Klein, Jeroen; Barros, Nathan O; Mendonça, Raquel; Becker, Vanessa; Huszar, Vera L M; Kosten, Sarian

    2016-01-01

    Recent studies from temperate lakes indicate that eutrophic systems tend to emit less carbon dioxide (CO2) and bury more organic carbon (OC) than oligotrophic ones, rendering them CO2 sinks in some cases. However, the scarcity of data from tropical systems is critical for a complete understanding of the interplay between eutrophication and aquatic carbon (C) fluxes in warm waters. We test the hypothesis that a warm eutrophic system is a source of both CO2 and CH4 to the atmosphere, and that atmospheric emissions are larger than the burial of OC in sediments. This hypothesis was based on the following assumptions: (i) OC mineralization rates are high in warm water systems, so that water column CO2 production overrides the high C uptake by primary producers, and (ii) increasing trophic status creates favorable conditions for CH4 production. We measured water-air and sediment-water CO2 fluxes, CH4 diffusion, ebullition and oxidation, net ecosystem production (NEP) and sediment OC burial during the dry season in a eutrophic reservoir in the semiarid northeastern Brazil. The reservoir was stratified during daytime and mixed during nighttime. In spite of the high rates of primary production (4858 ± 934 mg C m(-2) d(-1)), net heterotrophy was prevalent due to high ecosystem respiration (5209 ± 992 mg C m(-2) d(-1)). Consequently, the reservoir was a source of atmospheric CO2 (518 ± 182 mg C m(-2) d(-1)). In addition, the reservoir was a source of ebullitive (17 ± 10 mg C m(-2) d(-1)) and diffusive CH4 (11 ± 6 mg C m(-2) d(-1)). OC sedimentation was high (1162 mg C m(-2) d(-1)), but our results suggest that the majority of it is mineralized to CO2 (722 ± 182 mg C m(-2) d(-1)) rather than buried as OC (440 mg C m(-2) d(-1)). Although temporally resolved data would render our findings more conclusive, our results suggest that despite being a primary production and OC burial hotspot, the tropical eutrophic system studied here was a stronger CO2 and CH4 source than a C

  17. High Primary Production Contrasts with Intense Carbon Emission in a Eutrophic Tropical Reservoir

    PubMed Central

    Almeida, Rafael M.; Nóbrega, Gabriel N.; Junger, Pedro C.; Figueiredo, Aline V.; Andrade, Anízio S.; de Moura, Caroline G. B.; Tonetta, Denise; Oliveira, Ernandes S.; Araújo, Fabiana; Rust, Felipe; Piñeiro-Guerra, Juan M.; Mendonça, Jurandir R.; Medeiros, Leonardo R.; Pinheiro, Lorena; Miranda, Marcela; Costa, Mariana R. A.; Melo, Michaela L.; Nobre, Regina L. G.; Benevides, Thiago; Roland, Fábio; de Klein, Jeroen; Barros, Nathan O.; Mendonça, Raquel; Becker, Vanessa; Huszar, Vera L. M.; Kosten, Sarian

    2016-01-01

    Recent studies from temperate lakes indicate that eutrophic systems tend to emit less carbon dioxide (CO2) and bury more organic carbon (OC) than oligotrophic ones, rendering them CO2 sinks in some cases. However, the scarcity of data from tropical systems is critical for a complete understanding of the interplay between eutrophication and aquatic carbon (C) fluxes in warm waters. We test the hypothesis that a warm eutrophic system is a source of both CO2 and CH4 to the atmosphere, and that atmospheric emissions are larger than the burial of OC in sediments. This hypothesis was based on the following assumptions: (i) OC mineralization rates are high in warm water systems, so that water column CO2 production overrides the high C uptake by primary producers, and (ii) increasing trophic status creates favorable conditions for CH4 production. We measured water-air and sediment-water CO2 fluxes, CH4 diffusion, ebullition and oxidation, net ecosystem production (NEP) and sediment OC burial during the dry season in a eutrophic reservoir in the semiarid northeastern Brazil. The reservoir was stratified during daytime and mixed during nighttime. In spite of the high rates of primary production (4858 ± 934 mg C m-2 d-1), net heterotrophy was prevalent due to high ecosystem respiration (5209 ± 992 mg C m-2 d-1). Consequently, the reservoir was a source of atmospheric CO2 (518 ± 182 mg C m-2 d-1). In addition, the reservoir was a source of ebullitive (17 ± 10 mg C m-2 d-1) and diffusive CH4 (11 ± 6 mg C m-2 d-1). OC sedimentation was high (1162 mg C m-2 d-1), but our results suggest that the majority of it is mineralized to CO2 (722 ± 182 mg C m-2 d-1) rather than buried as OC (440 mg C m-2 d-1). Although temporally resolved data would render our findings more conclusive, our results suggest that despite being a primary production and OC burial hotspot, the tropical eutrophic system studied here was a stronger CO2 and CH4 source than a C sink, mainly because of high

  18. Multicomponent geothermometry applied to a medium-low enthalpy carbonate-evaporite geothermal reservoir

    NASA Astrophysics Data System (ADS)

    Battistel, Maria; Barbieri, Maurizio; Hurwitz, Shaul; Eavans, William; Chiodini, Giovanni

    2014-05-01

    In order to improve the knowledge of the thermal state of medium to low-enthalpy thermal systems hosted in carbonate-evaporite rocks, a mineral-solution equilibrium model was compared to other theoretical geothermoters. We use the GeoT code (Spycher et al., 2014) which calculates reservoir temperatures based on a statistical evaluation of mineral saturation indices. The calculations were applied to study the medium and low enthalpy geothermal systems in the Tyrrhenian-Apennine area (central Italy). The study area is mainly characterized by Paleozoic metamorphic basement and a Mesozoic carbonate-evaporite sequence overlain by Oligocene-Mid Miocene flysch formations and Quaternary volcanic complexes associated with crustal extension in the Tyrrhenian area. A regional aquifer is hosted in the carbonate-evaporate formations, and smaller aquifers are hosted in the volcanic rocks. For reservoir temperature calculations the chemical composition of 58 springs and wells with a temperature between 22° and 65°C was taken into account. The waters are classified as Ca-HCO3 waters with low TDS, Ca-SO4 waters with high TDS and few HCO3-NaK type waters. The calculated reservoir temperatures of the medium-low enthalpy hydrothermal systems in Tyrrhenian-Apennine area range between 40 and 100°C. As expected, cation geothermometers provide unrealistic values of equilibrium temperature. Calculations based on the chalcedony geothermeter provide more realistic temperatures than the quartz geothermometers because silica solubility at temperatures <180°C is controlled by amorphous silica or chalcedony. GeoT simulation results show that all the considered mineral phases are either near saturation or oversaturated and the equilibrium temperatures range between 48° and 116°C. The statistical approach of "best clustering minerals", used in this model, solves the problems related to cation or single component geothermometers. For these cases, multicomponent geothermometry coupled with

  19. Predicting phase behavior of mixtures of reservoir fluids with carbon dioxide

    SciTech Connect

    Grigg, R.B.; Lingane, P.J.

    1983-10-01

    The use of an equation of state to predict phase behavior during carbon dioxide flooding is well established. There is consensus that the characterization of the C fraction, the grouping of this fraction into ''pseudo components'', and the selection of interaction parameters are the most important variables. However, the literature is vague as to how to best select the pseudo components, especially when aiming for a few-component representation as for a field scale compositional simulation. Single-contact phase behavior is presented for mixtures of Ford Geraldine (Delaware), Maljamar (Grayburg), West Sussex (Shannon), and Reservoir D reservoir fluids, and of a synthetic oil C/C/C, with carbon dioxide. One can reproduce the phase behavior of these mixtures using 3-5 pseudo components and common interaction parameters. The critical properties of the pseudo components are calculated from detailed oil characterizations. Because the parameters are not further adjusted, this approach reduces the empiricism in fitting phase data and may result in a more accurate representation of the system as the composition of the oil changes during the approach to miscibility.

  20. Lagoa Feia Formation (Lower Cretaceous), Campos basin, offshore Brazil - Rift-Valley-Stage Lacustrine carbonate reservoirs

    SciTech Connect

    Bertani, R.; Petrobras, T.; Carozzi, A.V.

    1985-02-01

    The Lagoa Feia Formation, buried in excess of 3000 m, is the exploration frontier of the prolific Campos basin. It contains the source beds of all the basin's oil in addition to having its own potential carbonate reservoirs. The faulted margins of the basin fed a system of alluvial fans, sand flats, and mud flats. Alternating dry and rainy period regulated the size and nature of contemporaneous basinal alkaline lakes. Dry periods corresponded to contracted playa lakes with ostracod carbonates and euxinic shales; rainy periods corresponded to expanded pluvial lakes with pelecypod banks. Subaqueous intrusions of basaltic magma generated hyaloclastites with kerolitic ooids and hyalotuffs. Petrographic analysis reveals 5 diagenetic stages: (1) syndepositional alteration of lithoclasts to trioctahedral smectites; (2) early dolomitization, early silicification, and cementation by bladed-rim calcite and zeolites; (3) freshwater-vadose dissolution of bioclasts and lithoclasts, freshwater-phreatic sparite cementation, and neomorphism; (4) mixed saline-freshwater silicification; and (5) burial with compaction, late dolomitization, and partial conversion of smectites to illite. Pelecypod limestones with primary interparticle, secondary intraparticle, moldic, and moldic-enlarged porosities are the potential reservoirs. Ideal conditions for porosity generation and preservation were subaerial exposure followed by rapid lake expansion and burial.

  1. Mineral Dissolution and Precipitation due to Carbon Dioxide-Water-Rock Interactions: The Significance of Accessory Minerals in Carbonate Reservoirs (Invited)

    NASA Astrophysics Data System (ADS)

    Kaszuba, J. P.; Marcon, V.; Chopping, C.

    2013-12-01

    Accessory minerals in carbonate reservoirs, and in the caprocks that seal these reservoirs, can provide insight into multiphase fluid (CO2 + H2O)-rock interactions and the behavior of CO2 that resides in these water-rock systems. Our program integrates field data, hydrothermal experiments, and geochemical modeling to evaluate CO2-water-rock reactions and processes in a variety of carbonate reservoirs in the Rocky Mountain region of the US. These studies provide insights into a wide range of geologic environments, including natural CO2 reservoirs, geologic carbon sequestration, engineered geothermal systems, enhanced oil and gas recovery, and unconventional hydrocarbon resources. One suite of experiments evaluates the Madison Limestone on the Moxa Arch, Southwest Wyoming, a sulfur-rich natural CO2 reservoir. Mineral textures and geochemical features developed in the experiments suggest that carbonate minerals which constitute the natural reservoir will initially dissolve in response to emplacement of CO2. Euhedral, bladed anhydrite concomitantly precipitates in response to injected CO2. Analogous anhydrite is observed in drill core, suggesting that secondary anhydrite in the natural reservoir may be related to emplacement of CO2 into the Madison Limestone. Carbonate minerals ultimately re-precipitate, and anhydrite dissolves, as the rock buffers the acidity and reasserts geochemical control. Another suite of experiments emulates injection of CO2 for enhanced oil recovery in the Desert Creek Limestone (Paradox Formation), Paradox Basin, Southeast Utah. Euhedral iron oxyhydroxides (hematite) precipitate at pH 4.5 to 5 and low Eh (approximately -0.1 V) as a consequence of water-rock reaction. Injection of CO2 decreases pH to approximately 3.5 and increases Eh by approximately 0.1 V, yielding secondary mineralization of euhedral pyrite instead of iron oxyhydroxides. Carbonate minerals also dissolve and ultimately re-precipitate, as determined by experiments in the

  2. Holocene siliciclastic-carbonate facies mosaics, Northern Belize: Exploration analog to some midcontinent Pennsylvanian (Morrowan) reservoirs

    SciTech Connect

    Lowe, D.B.; Mazzullo, S.J.

    1995-09-01

    Midwinter Lagoon is a large, shallow coastal lagoon, bordered on its seaward side by a barrier, along the mainland coast of northern Belize. As much as 19 ft of Holocene sediments, deposited on karsted Tertiary limestones during the Flandrian transgression, consist of a complex mosaic of mixed siliciclastic and carbonate facies. Basal transgressive marine, intra-lagoonal facies are variously siliciclastic-rich carbonates to carbonate-rich siliciclastics, locally with layers of shoreline mangrove peat. These facies shallow-upward to either siliciclastic or carbonate-dominated sands or muds. Lagoonal facies were deposited within a broad topographic low, locally punctuated by bedrock highs, on the underlying limestone. The seaward edge of the barrier bar complex, which was deposited on a linear topographic high, consists mostly of quartz sands, whereas the lagoonal side is a mixture of quartzose and carbonate sediments (sands and muds). The barrier bar appears to have accreted southward in response to southerly longshore drift as a tidal inlet-spit complex; quartz sands are being transported into the lagoon from its seaward side. In terms of geometry, modern and buried, intra-lagoonal carbonate sands occur as lobes deposited proximal to extant and older tidal inlets. Either carbonate or siliciclastic sands variously occur as erratically distributed, anastomosing beach deposits around small mangrove islands and along the irregular mainland coast. In contrast, siliciclastic sands on the seaward side of the barrier define a narrow but areally persistent linear trend. Similar complex facies associations and geometries are typical of many Pennsylvanian (Morrowan) reservoirs in the midcontinent US.

  3. Play-level distributions of estimates of recovery factors for a miscible carbon dioxide enhanced oil recovery method used in oil reservoirs in the conterminous United States

    USGS Publications Warehouse

    Attanasi, E.D.; Freeman, P.A.

    2016-03-02

    The retention factor is the percentage of injected CO2 that is naturally retained in the reservoir. Retention factors were also estimated in this study. For clastic reservoirs, 90 percent of the estimated retention factors were between 21.7 and 32.1 percent, and for carbonate reservoirs, 90 percent were between 23.7 and 38.2 percent. The respective median values were 22.9 for clastic reservoirs and 26.1 for carbonate reservoirs. Both distributions were right skewed. The recovery and retention factors that were calculated are consistent with the corresponding factors reported in the literature.

  4. Carbon cycling and net ecosystem production at an early stage of secondary succession in an abandoned coppice forest.

    PubMed

    Ohtsuka, Toshiyuki; Shizu, Yoko; Nishiwaki, Ai; Yashiro, Yuichiro; Koizumi, Hiroshi

    2010-07-01

    Secondary mixed forests are one of the dominant forest cover types in human-dominated temperate regions. However, our understanding of how secondary succession affects carbon cycling and carbon sequestration in these ecosystems is limited. We studied carbon cycling and net ecosystem production (NEP) over 4 years (2004-2008) in a cool-temperate deciduous forest at an early stage of secondary succession (18 years after clear-cutting). Net primary production of the 18-year-old forest in this study was 5.2 tC ha(-1 )year(-1), including below-ground coarse roots; this was partitioned into 2.5 tC ha(-1 )year(-1) biomass increment, 1.6 tC ha(-1 )year(-1) foliage litter, and 1.0 tC ha(-1 )year(-1) other woody detritus. The total amount of annual soil surface CO(2) efflux was 6.8 tC ha(-1 )year(-1), which included root respiration (1.9 tC ha(-1 )year(-1)) and heterotrophic respiration (RH) from soils (4.9 tC ha(-1 )year(-1)). The 18-year forest at this study site exhibited a great increase in biomass pool as a result of considerable total tree growth and low mortality of tree stems. In contrast, the soil organic matter (SOM) pool decreased markedly (-1.6 tC ha(-1 )year(-1)), although further study of below-ground detritus production and RH of SOM decomposition is needed. This young 18-year forest was a weak carbon sink (0.9 tC ha(-1 )year(-1)) at this stage of secondary succession. The NEP of this 18-year forest is likely to increase gradually because biomass increases with tree growth and with the improvement of the SOM pool through increasing litter and dead wood production with stand development.

  5. Kinetics of carbonate mineral dissolution in CO2-acidified brines at storage reservoir conditions.

    PubMed

    Peng, Cheng; Anabaraonye, Benaiah U; Crawshaw, John P; Maitland, Geoffrey C; Trusler, J P Martin

    2016-10-20

    We report experimental measurements of the dissolution rate of several carbonate minerals in CO2-saturated water or brine at temperatures between 323 K and 373 K and at pressures up to 15 MPa. The dissolution kinetics of pure calcite were studied in CO2-saturated NaCl brines with molalities of up to 5 mol kg(-1). The results of these experiments were found to depend only weakly on the brine molality and to conform reasonably well with a kinetic model involving two parallel first-order reactions: one involving reactions with protons and the other involving reaction with carbonic acid. The dissolution rates of dolomite and magnesite were studied in both aqueous HCl solution and in CO2-saturated water. For these minerals, the dissolution rates could be explained by a simpler kinetic model involving only direct reaction between protons and the mineral surface. Finally, the rates of dissolution of two carbonate-reservoir analogue minerals (Ketton limestone and North-Sea chalk) in CO2-saturated water were found to follow the same kinetics as found for pure calcite. Vertical scanning interferometry was used to study the surface morphology of unreacted and reacted samples. The results of the present study may find application in reactive-flow simulations of CO2-injection into carbonate-mineral saline aquifers.

  6. Geoscience/engineering characterization of the interwell environment in carbonate reservoirs based on outcrop analogs, Permian Basin, West Texas and New Mexico - petrophysical characterization of the South Cowden Grayburg Reservoir, Ector County, Texas. Final report

    SciTech Connect

    Lucia, F.J.

    1997-06-01

    Reservoir performance of the South Cowden Grayburg field suggests that only 21 percent of the original oil in place has been recovered. The purpose of this study is to construct a realistic reservoir model to be used to predict the location of the remaining mobile oil. Construction of reservoir models for fluid-flow simulation of carbonate reservoirs is difficult because they typically have complicated and unpredictable permeability patterns. Much of the difficulty results from the degree to which diagenetic overprinting masks depositional textures and patterns. For example, the task of constructing a reservoir model of a limestone reservoir that has undergone only cementation and compaction is easier than constructing a model of a karsted reservoir that has undergone cavern formation and collapse as well as cementation and compaction. The Permian-age carbonate-ramp reservoirs in the Permian Basin, West Texas and New Mexico, are typically anhydritic dolomitized limestone. Because the dolomitization occurred soon after deposition, depositional fabrics and patterns are often retained, and a reservoir model can be constructed using depositional concepts. Recent studies of the San Andres outcrop in the Guadalupe Mountains and the Seminole San Andres reservoir in the Permian Basin illustrate how depositional fabrics and patterns can be used to construct a reservoir model when depositional features are retained.

  7. Analytical solution of geological carbon sequestration under constant pressure injection into a horizontal radial reservoir

    NASA Astrophysics Data System (ADS)

    Jhang, R.; Liou, T.

    2013-12-01

    Carbon capture and sequestration (CCS) is believed to be an economically feasible technology to mitigate global warming by capturing carbon dioxide (CO2), the major component of greenhouse gases, from the atmosphere and injecting it into deep geological formations.Several mechanisms can help trap CO2 in the pore space of a geological reservoir, stratigraphic and structural trapping, hydrodynamic trapping, and geochemical trapping.Besides these trapping mechanisms, another important issue that deserves careful attention is the risk of CO2 leakage. The common ';constant injection rate' scenario may induce high pressure buildup that will endanger the mechanical integrity as well as the sealing capability of the cap rock. Instead of injecting CO2 at a constant mass rate, CO2 can be injected into the reservoir by fixing the pressure (usually the bottom-hole pressure) in the injection borehole. By doing so, the inevitable pressure buildup associated with the constant injection scheme can be completely eliminated in the constant pressure injection scheme. In this paper, a semi-analytical solution for CO2 injection with constant pressure was developed. For simplicity, structural and geochemical trapping mechanisms were not considered. Therefore, a horizontal reservoir with infinite radial extent was considered. Prior to injection, the reservoir is fully saturated with the formation brine. It is assumed that CO2 does not mix with brine such that a sharp interface is formed once CO2 invades the brine-saturated pores. Because of the density difference between CO2 and brine, CO2 resides above the interface. Additional assumptions were also made when building up the brine and CO2 mass balance equations: (1) both of the fluids and the geological formations are incompressible, (2) capillary pressure is neglected, (3)there is no fluid flow in the vertical direction, and the horizontal flow satisfies the Darcy's law.In order to solve for the height of brine-CO2 interface, the two

  8. Characterization from borehole wall and X-ray scan images of heterogeneities in carbonate reservoirs

    NASA Astrophysics Data System (ADS)

    Hébert, V.; Pezard, P. A.; Garing, C.; Gouze, P.; Camoin, G.; Lapointe, P.

    2009-12-01

    Salt water intrusion in coastal reservoirs is highly influenced by geological and petrophysical structures. In particular, heterogeneities and anisotropy in porous media (karst, vug) control fluid transport and dispersion. To develop new strategies for the quantitative description and analysis of fluid flow and salt transport in coastal aquifers, a new experimental site was developed in SE Mallorca (Spain) in the context of the ALIANCE EC project (2002-2005). Multi-scalar quantitative and descriptive methods (from µm to m) are developed to identify and map microstructures, heterogeneities and their hydrogeological impact on the reservoir. The objective of this study is to better understand the link between geological and hydrogeological properties of heterogeneous reservoir. The Mallorcan site cuts the Miocene carbonate reef platform and is located 6 km inland, where a salt wedge transition is found from 60 to 80 m depth. The geological structure includes large multi-scale heterogeneities, often bound to lateral facies variations. This experimental site provides thus a unique laboratory to study saltwater intrusion processes and develop new downhole investigation methods. This study focuses on borehole geophysical measurements and images, and X-ray core scan images. New image analysis methods have been developed to better characterize heterogeneities in terms of size distribution, aspect ratio and porosity. Optical and acoustic borehole wall images offer a continuous insight into meso-scale porosity (such as karstic channels and megapores) from mm to 100 m scale. X-ray cores scans were obtained from a tomography scanner by TOTAL. These two methodologies from RX tomography scans and borehole wall images are compared and discussed. Petrophysical parameters were extracted from X-ray images with a dedicated 3D data analysis software. The scan images lead to the identification and quantification of the micro- and vuggy porosity. It is found that the distribution of

  9. DESIGN AND IMPLEMENTATION OF A CO2 FLOOD UTILIZING ADVANCED RESERVOIR CHARACTERIZATION AND HORIZONTAL INJECTION WELLS IN A SHALLOW SHELF CARBONATE APPROACHING WATERFLOOD DEPLETION

    SciTech Connect

    K.J. Harpole; Ed G. Durrett; Susan Snow; J.S. Bles; Carlon Robertson; C.D. Caldwell; D.J. Harms; R.L. King; B.A. Baldwin; D. Wegener; M. Navarrette

    2002-09-01

    The purpose of this project was to economically design an optimum carbon dioxide (CO{sub 2}) flood for a mature waterflood nearing its economic abandonment. The original project utilized advanced reservoir characterization and CO{sub 2} horizontal injection wells as the primary methods to redevelop the South Cowden Unit (SCU). The development plans; project implementation and reservoir management techniques were to be transferred to the public domain to assist in preventing premature abandonment of similar fields. The Unit was a mature waterflood with water cut exceeding 95%. Oil must be mobilized through the use of a miscible or near-miscible fluid to recover significant additional reserves. Also, because the unit was relatively small, it did not have the benefit of economies of scale inherent in normal larger scale projects. Thus, new and innovative methods were required to reduce investment and operating costs. Two primary methods used to accomplish improved economics were use of reservoir characterization to restrict the flood to the higher quality rock in the unit and use of horizontal injection wells to cut investment and operating costs. The project consisted of two budget phases. Budget Phase I started in June 1994 and ended late June 1996. In this phase Reservoir Analysis, Characterization Tasks and Advanced Technology Definition Tasks were completed. Completion enabled the project to be designed, evaluated, and an Authority for Expenditure (AFE) for project implementation submitted to working interest owners for approval. Budget Phase II consisted of the implementation and execution of the project in the field. Phase II was completed in July 2001. Performance monitoring, during Phase II, by mid 1998 identified the majority of producing wells which under performed their anticipated withdrawal rates. Newly drilled and re-activated wells had lower offtake rates than originally forecasted. As a result of poor offtake, higher reservoir pressure was a concern

  10. Predicting the natural state of fractured carbonate reservoirs: An Andector Field, West Texas test of a 3-D RTM simulator

    SciTech Connect

    Tuncay, K.; Romer, S.; Ortoleva, P.; Hoak, T.; Sundberg, K.

    1998-12-31

    The power of the reaction, transport, mechanical (RTM) modeling approach is that it directly uses the laws of geochemistry and geophysics to extrapolate fracture and other characteristics from the borehole or surface to the reservoir interior. The objectives of this facet of the project were to refine and test the viability of the basin/reservoir forward modeling approach to address fractured reservoir in E and P problems. The study attempts to resolve the following issues: role of fracturing and timing on present day location and characteristics; clarifying the roles and interplay of flexure dynamics, changing rock rheological properties, fluid pressuring and tectonic/thermal histories on present day reservoir location and characteristics; and test the integrated RTM modeling/geological data approach on a carbonate reservoir. Sedimentary, thermal and tectonic data from Andector Field, West Texas, were used as input to the RTM basin/reservoir simulator to predict its preproduction state. The results were compared with data from producing reservoirs to test the RTM modeling approach. The effects of production on the state of the field are discussed in a companion report. The authors draw the following conclusions: RTM modeling is an important new tool in fractured reservoir E and P analysis; the strong coupling of RTM processes and the geometric and tensorial complexity of fluid flow and stresses require the type of fully coupled, 3-D RTM model for fracture analysis as pioneered in this project; flexure analysis cannot predict key aspects of fractured reservoir location and characteristics; fracture history over the lifetime of a basin is required to understand the timing of petroleum expulsion and migration and the retention properties of putative reservoirs.

  11. Cretaceous tide-dominated carbonate ramp: Comparison of reservoir hetergeneity in tide-versus wave-dominated carbonate ramp systems

    SciTech Connect

    Kerans, C.

    1995-08-01

    Cretaceous (upper Albian) carbonate ramp strata, Pecos River Canyon, Texas, provide a uniquely continuous exposure of a tide-dominated ramp reservoir analog. The continuous 100-km shelf-to-basin outcrop begins in inner ramp mud-rich facies that record both high-frequency (20-100 ky) and intermediate frequency (>200 ky) cyclicity. The ramp-crest is up to 40 km across depositional dip. Intermediate-scale cycles in the ramp crest include basal oyster and toucasid wackestones, chondrodontid-rudist packstones, rudist-skeletal grainstones, and caprinid biostromes. Ramp-crest grainstones are 4-23 m in thickness and extend more than 20 km in a shelf to basin direction. Rudist biostromes are 3-7 m in thickness and are up to several kilometers in dip continuity except in deeper outer ramp settings where 100-200 m wide mounds are more common. The ramp crest is dominated by grain-rich facies with moderate to high permeability. Toucasid wackestones and oyster marls are 1-5 m in thickness and extend tens of kilometers in a dip direction, representing potential fluid flow barriers. Wave-dominated ramp systems of the Permian of West Texas provide a contrast to the Cretaceous tide-dominated setting. Low-permeability high-frequency cycle base mudstones and high-permeability cycle-top grainstones are preserved in both inner ramp and ramp crest settings. Fluid-flow modeling of these Permian wave-dominated reservoir strata illustrates that the intercalation of thin high- and low-permeability layers result in crossflow trapping and thief zones controlling the position and amount of remaining oil saturation. The depositional homogeneity of the Cretaceous tide-dominated ramp indicates that diagenetic heterogeneities and gravitational effects are potentially dominant controls on reservoir performance for these strata.

  12. Abandoned Channel Fill Sequences in Tidal Estuaries

    NASA Astrophysics Data System (ADS)

    Gray, A. B.; Pasternack, G. B.; Goni, M. A.; Watson, E. B.

    2014-12-01

    This study proposes a modification of the current model for abandoned channel fill stratigraphy produced in unidirectional flow river reaches to incorporate seasonal tidal deposition. Evidence supporting this concept came from a study of two consecutive channel abandonment sequences in Ropers Slough of the lower Eel River Estuary in northern California. Aerial photographs showed that Ropers Slough was abandoned around 1943, reoccupied after the 1964 flood, and abandoned again in 1974 with fill continuing to the present. Planform geomorphic characteristics derived from these images were used in conjunction with sub-cm resolution stratigraphic analyses to describe the depositional environment processes and their resultant sedimentary deposits. Results showed that both abandonment sequences recorded quasi-annual scale fluvial/tidal deposition couplets. In both cases tidal deposits contained very little sand, and were higher in organic and inorganic carbon content than the sandier fluvial through-flow deposits. However, the two abandonment fills differed significantly in terms of the temporal progression of channel narrowing and fluvial sediment deposition characteristics. The first abandonment sequence led to a more rapid narrowing of Ropers Slough and produced deposits with a positive relationship between grain size/deposit thickness and discharge. The second abandonment resulted in a much slower narrowing of Ropers Slough and generally thinner fluvial deposits with no clear relationship between grain size/deposit thickness and discharge. The δ13C values and organic nitrogen to organic carbon ratios of deposits from the first phase overlapped with Eel River suspended sediment characteristics found for low flows (1-5 times mean discharge), while those of the second phase were consistent suspended sediment from higher flows (7-10 times mean discharge). The abandoned channel fill sequences appeared to differ due to the topographic steering of bed sediment transport and

  13. Carbon Reservoir History of Mars Constrained by Atmospheric Isotopic Measurements and Carbonate Remote Sensing

    NASA Astrophysics Data System (ADS)

    Hu, R.; Kass, D. M.; Ehlmann, B. L.; Yung, Y. L.

    2015-12-01

    The evolution of the atmosphere on Mars is one of the most intriguing problems in the exploration of the Solar System, and the climate of Mars may have evolved from a warmer, wetter early state to the cold, dry current state. Because CO2 is the major constituent of Mars's atmosphere, its isotopic signatures offer a unique window to trace the evolution of climate on Mars. We derive new quantitative constraints on the amount of carbonate deposition and the atmospheric pressure of Mars through time, extending into the Noachian, ~3.8 Gyr before present. This determination is based on recent Mars Science Laboratory (MSL) isotopic measurements of Mars's atmosphere, recent orbiter, lander, and rover measurements of Mars's surface, and a newly identified mechanism (photodissociation of CO) that efficiently enriches the heavy carbon isotope. In particular, we find that escape via CO photodissociation on Mars has a fractionation factor of 0.6 and hence, photochemical escape processes can effectively enrich 13C in the Mars's atmosphere during the Amazonian. This enrichment is partially compensated by moderate carbonate precipitation during the late Noachian and/or Hesperian. The current atmospheric 13C/12C and rock and soil carbonate measurements indicate an early atmosphere with a surface pressure less than 1 bar. Only scenarios with large amounts of carbonate formation in open lakes permit higher values up to 1.8 bars. The evolutionary scenarios are fully testable with data from the MAVEN mission and further studies of the isotopic composition of carbonate in the Martian rock record through time.

  14. Baca geothermal demonstration project. Equation-of-state for water-carbon dioxide mixtures: implications for Baca reservoir

    SciTech Connect

    Pritchett, J.W.; Rice, M.H.; Riney, T.D.

    1981-02-01

    An equation-of-state package for water-carbon dioxide mixtures has been constructed from available thermodynamic data that covers the range of interest to the Baca reservoir system. The package has been used to examine the thermodynamic state of the Baca reservoir fluid for conditions of temperature, pressure and CO/sub 2/ content believed to bracket conditions existing at the production depth of the wells in the Redondo Creek area. It is shown that the reservoir fluid may be either all-liquid or two-phase at various well locations and depths, depending on the CO/sub 2/ content. It is also shown that the CO/sub 2/ content at reservoir conditions cannot be reliably inferred from pressure/temperature measurements made on flowing wells. The equation-of-state package has been incorporated into a general purpose geothermal reservoir simulator and a series of calculations made which show that the CO/sub 2/ content of the produced fluid may be less than or greater than that of the reservoir fluid. The characteristics of the produced fluid are sensitive to the CO/sub 2/ content in the reservoir.

  15. Design and Implementation of a CO2 Flood Utilizing Advanced Reservoir Characterization and Horizontal Injection Wells In a Shallow Shelf Carbonate Approaching Waterflood Depletion, Class II

    SciTech Connect

    Czirr, K.L.; Gaddis, M.P.; Moshell, M.K.

    2002-02-21

    The principle objective of this project is to demonstrate the economic viability and widespread applicability of an innovative reservoir management and carbon dioxide (CO2) flood project development approach for improving CO2 flood project economics in shallow shelf carbonate (SSC) reservoirs.

  16. INTEGRATED OUTCROP AND SUBSURFACE STUDIES OF THE INTERWELL ENVIRONMENT OF CARBONATE RESERVOIRS: CLEAR FORK (LEONARADIAN AGE) RESERVOIRS, WEST TEXAS AND NEW MEXICO

    SciTech Connect

    James W. Jennings, Jr.; F. Jerry Lucia

    2001-10-01

    Petrophysical heterogeneity in the South Wasson Clear Fork (SWCF) reservoir and other shallow-water platform carbonates in the Permian Basin and elsewhere is composed of a large-scale stratigraphically controlled component and a small-scale poorly correlated component. The large-scale variability exists as a flow-unit scale petrophysical layering that is laterally persistent at interwell scales and produces highly stratified reservoir behavior. Capturing the rate-enhancing effect of the small-scale variability requires carefully controlled averaging procedures at four levels of scaleup. Porosity can be easily scaled using arithmetic averaging procedures. Permeability, however, requires carefully controlled power-averaging procedures. Effective permeability is increased at every scaleup level.

  17. Geostatistical reservoir characterization of complex lateral and vertical sequences in a mixed carbonate platform

    SciTech Connect

    Norris, R.J.; Alabert, F.G.; Massonnat, G.J. )

    1994-07-01

    In recent years reservoir characterization through the use of geostatistics has become an almost routine part of production geology. Many techniques are available within the broad title of geostatistics, having been developed in response to many types of problem. One characteristic feature of almost all techniques (Stochastic Indicator Simulation, Boolean [open quotes]object[close quotes] Modeling, Gaussian [and Truncated Gaussian] methods and Optimized Markov-fields) is their reliance on the concept of quantifiable correlations, which reflect some aspect of the shape of [open quotes]objects.[close quotes] For example, almost any of the above noted techniques, and their variants, could be used to model fluvial, deltaic, or turbiditic reservoirs because in each case facies can be described in terms of geometries (channels, lobes, etc.). This study considers the complex lateral and vertical variations of a mixed carbonate platform environment, where facies cannot be easily characterized by simple geometries. The complex heterogeneities are a function of changes in sea level, representing fluctuations over several orders of cyclicity. Given facies have no characteristic form, being the product of the interplay between sediment supply and sea level change. This type of environment is, therefore, characterized by a good deal of information concerning trends in the data, while correlations and geometries are almost meaningless. Associated with the concepts of cyclicity, rules concerning the reappearance of facies, or otherwise, were developed. For example, minor recurrences of maximum flooding surfaces could be tolerated within individual units but other specified recurrences need to be excluded.

  18. Experiments and modeling of variably permeable carbonate reservoir samples in contact with CO₂-acidified brines

    SciTech Connect

    Smith, Megan M.; Hao, Yue; Mason, Harris E.; Carroll, Susan A.

    2014-12-31

    Reactive experiments were performed to expose sample cores from the Arbuckle carbonate reservoir to CO₂-acidified brine under reservoir temperature and pressure conditions. The samples consisted of dolomite with varying quantities of calcite and silica/chert. The timescales of monitored pressure decline across each sample in response to CO₂ exposure, as well as the amount of and nature of dissolution features, varied widely among these three experiments. For all samples cores, the experimentally measured initial permeability was at least one order of magnitude or more lower than the values estimated from downhole methods. Nondestructive X-ray computed tomography (XRCT) imaging revealed dissolution features including “wormholes,” removal of fracture-filling crystals, and widening of pre-existing pore spaces. In the injection zone sample, multiple fractures may have contributed to the high initial permeability of this core and restricted the distribution of CO₂-induced mineral dissolution. In contrast, the pre-existing porosity of the baffle zone sample was much lower and less connected, leading to a lower initial permeability and contributing to the development of a single dissolution channel. While calcite may make up only a small percentage of the overall sample composition, its location and the effects of its dissolution have an outsized effect on permeability responses to CO₂ exposure. The XRCT data presented here are informative for building the model domain for numerical simulations of these experiments but require calibration by higher resolution means to confidently evaluate different porosity-permeability relationships.

  19. Seasonal patterns in carbon dioxide in 15 mid-continent (USA) reservoirs

    USGS Publications Warehouse

    Jones, John R.; Obrecht, Daniel V.; Graham, Jennifer; Balmer, Michelle B.; Filstrup, Christopher T.; Downing, John A.

    2016-01-01

    Evidence suggests that lakes are important sites for atmospheric CO2 exchange and so play a substantial role in the global carbon budget. Previous research has 2 weaknesses: (1) most data have been collected only during the open-water or summer seasons, and (2) data are concentrated principally on natural lakes in northern latitudes. Here, we report on the full annual cycle of atmospheric CO2 exchanges of 15 oligotrophic to eutrophic reservoirs in the Glacial Till Plains of the United States. With one exception, these reservoirs showed an overall loss of CO2 during the year, with most values within the lower range reported for temperate lakes. There was a strong cross-system seasonal pattern: an average of 70% of total annual CO2 efflux occurred by the end of spring mixis; some 20% of annual flux was reabsorbed during summer stratification; and the remaining 50% of efflux was lost during autumnal mixing. Net annual flux was negatively correlated with depth and positively correlated with both water residence time and DOC, with the smallest annual CO2 efflux measured in shallow fertile impoundments. Strong correlations yield relationships allowing regional up-scaling of CO2 evasion. Understanding lacustrine CO2 uptake and evasion requires seasonal analyses across the full range of lake trophic states and morphometric attributes.

  20. Carbon dioxide-brine-rock interactions in a carbonate reservoir capped by shale: Experimental insights regarding the evolution of trace metals

    NASA Astrophysics Data System (ADS)

    Marcon, Virginia; Kaszuba, John P.

    2015-11-01

    Trace metal behavior provides important information regarding fluid-rock interactions in CO2-charged water-rock systems and constrains potential environmental impacts. Hydrothermal experiments evaluated mechanisms of release, evolution, and subsequent scavenging of trace metals at 160 °C and 25 MPa. Experiments were designed to simulate two theoretical locations within a CO2-charged reservoir: (1) at the contact between a shale caprock and carbonate reservoir and (2) deeper within a carbonate reservoir, away from the shale. CO2 injection into brine (ionic strength = 3.3 mol/kg) decreased the pH by 1-2 units; concomitant mineral dissolution elevated Ba, Co, Cu, Pb, and V concentrations in the brine at both simulated locations within the reservoir. Additionally, Fe, Ni, and Zn concentrations increased in the mixed shale-carbonate experiment; Ba and Cd concentrations increased in the carbonate-only experiment. However, concentrations of Fe, Ba, Cr, and Pb in the mixed shale-carbonate experiment and Cr, Pb, V, and Zn within the carbonate-only experiment subsequently decreased as a result of precipitation of sulfides (Fe and Co sulfides), oxides, and clays. At the conclusion of the experiments, Fe, Pb, and Cr exceeded U.S. Environmental Protection Agency maximum contaminant limits in both experiments. In addition, zinc exceeded the limits at the simulated shale-carbonate contact and Ba, Cu, and Cd exceeded the limits in the simulated carbonate reservoir. Experimentally observed trends of decreasing Fe and Pb concentrations suggest these trace metals become less of an environmental concern as CO2-water-rock reactions evolve with time. The shale caprock plays an active role in trace metal evolution. The shale is a large source of metals, but also provides metal sinks such as primary clays, secondary smectites, and other silicates that are not found deeper within the carbonate reservoir, away from the shale. This potential mechanism of self-healing mitigates, but does not

  1. Organic Carbon Burial in Lakes and Reservoirs of the Conterminous United States.

    PubMed

    Clow, David W; Stackpoole, Sarah M; Verdin, Kristine L; Butman, David E; Zhu, Zhiliang; Krabbenhoft, David P; Striegl, Robert G

    2015-07-07

    Organic carbon (OC) burial in lacustrine sediments represents an important sink in the global carbon cycle; however, large-scale OC burial rates are poorly constrained, primarily because of the sparseness of available data sets. Here we present an analysis of OC burial rates in water bodies of the conterminous U.S. (CONUS) that takes advantage of recently developed national-scale data sets on reservoir sedimentation rates, sediment OC concentrations, lake OC burial rates, and water body distributions. We relate these data to basin characteristics and land use in a geostatistical analysis to develop an empirical model of OC burial in water bodies of the CONUS. Our results indicate that CONUS water bodies sequester 20.8 (95% CI: 9.4-65.8) Tg C yr(-1), and spatial patterns in OC burial are strongly influenced by water body type, size, and abundance; land use; and soil and vegetation characteristics in surrounding areas. Carbon burial is greatest in the central and southeastern regions of the CONUS, where cultivation and an abundance of small water bodies enhance accumulation of sediment and OC in aquatic environments.

  2. Organic carbon burial in lakes and reservoirs of the conterminous United States

    USGS Publications Warehouse

    Clow, David W.; Stackpoole, Sarah M.; Verdin, Kristine L.; Butman, David E.; Zhu, Zhi-Liang; Krabbenhoft, David P.; Striegl, Robert G.

    2015-01-01

    Organic carbon (OC) burial in lacustrine sediments represents an important sink in the global carbon cycle; however, large-scale OC burial rates are poorly constrained, primarily because of the sparseness of available data sets. Here we present an analysis of OC burial rates in water bodies of the conterminous U.S. (CONUS) that takes advantage of recently developed national-scale data sets on reservoir sedimentation rates, sediment OC concentrations, lake OC burial rates, and water body distributions. We relate these data to basin characteristics and land use in a geostatistical analysis to develop an empirical model of OC burial in water bodies of the CONUS. Our results indicate that CONUS water bodies sequester 20.8 (95% CI: 9.4–65.8) Tg C yr–1, and spatial patterns in OC burial are strongly influenced by water body type, size, and abundance; land use; and soil and vegetation characteristics in surrounding areas. Carbon burial is greatest in the central and southeastern regions of the CONUS, where cultivation and an abundance of small water bodies enhance accumulation of sediment and OC in aquatic environments.

  3. Development of a combined isotopic and mass-balance approach to determine dissolved organic carbon sources in eutrophic reservoirs.

    PubMed

    Pierson-Wickmann, Anne-Catherine; Gruau, Gérard; Jardé, Emilie; Gaury, Nicolas; Brient, Luc; Lengronne, Marion; Crocq, André; Helle, Daniel; Lambert, Thibault

    2011-04-01

    A combined mass-balance and stable isotope approach was set up to identify and quantify dissolved organic carbon (DOC) sources in a DOC-rich (9mgL(-1)) eutrophic reservoir located in Western France and used for drinking water supply (so-called Rophemel reservoir). The mass-balance approach consisted in measuring the flux of allochthonous DOC on a daily basis, and in comparing it with the effective (measured) DOC concentration of the reservoir. The isotopic approach consisted, for its part, in measuring the carbon isotope ratios (δ(13)C values) of both allochthonous and autochthonous DOC sources, and comparing these values with the δ(13)C values of the reservoir DOC. Results from both approaches were consistent pointing out for a DOC of 100% allochthonous origin. In particular, the δ(13)C values of the DOC recovered in the reservoir (-28.5±0.2‰; n=22) during the algal bloom season (May-September) showed no trace of an autochthonous contribution (δ(13)C in algae=-30.1±0.3‰; n=2) being indistinguishable from the δ(13)C values of allochthonous DOC from inflowing rivers (-28.6±0.1‰; n=8). These results demonstrate that eutrophication is not responsible for the high DOC concentrations observed in the Rophemel reservoir and that limiting eutrophication of this reservoir will not reduce the potential formation of disinfection by-products during water treatment. The methodology developed in this study based on a complementary isotopic and mass-balance approach provides a powerful tool, suitable to identify and quantify DOC sources in eutrophic, DOC-contaminated reservoirs.

  4. Enhanced carbonate reservoir model for an old reservoir utilizing new techniques: The Schaben Field (Mississippian), Ness County, Kansas

    SciTech Connect

    Carr, T.P.; Guy, W.J.; Franseen, E.K.; Bhattacharya, S.

    1996-12-31

    The Pennsylvanian-Mississippian unconformity is a major stratigraphic event in Kansas that truncates rocks ranging from Precambrian to Mississippian. Many of the 6,000 fields in Kansas are located immediately beneath this unconformity. One example, Schaben Field located in Ness County, Kansas, has produced approximately 9 million barrels since it was discovered in 1963. Production is from the Mississippian (Osagian) cherty dolomites beneath the inconformity. The field was initially developed on a regular forty-acre spacing, but recent drilling has demonstrated the potential for additional targeted infill drilling. To develop an enhanced reservoir model for the Schabin field modern core, log, and well data were integrated with the existing data. New techniques such as {open_quotes}Pseudoseismic{close_quotes} and the {open_quotes}Super{close_quotes} Pickett plot were used to leverage the existing data and provide tools for analysis and 3D visualization. The pseudoseismic approach uses well-logs within a standard 3D seismic visualization system to provide a detailed macroscale view of karst patterns. The petrophysical analyses using the {open_quotes}Super{close_quotes} Pickett plot were used to recognize subtle trends and patterns for each of multiple reservoir intervals. Visual and petrographic examination of core from the field confirms karst development and indicates multiple stages of fracturing, brecciation, and dissolution features that were important in controlling and modifying development of reservoirs. The understanding of the reservoir heterogeneities resulting from the paleokarst model at Schaben field emphasizes the importance of integrating available data with new techniques to provide a predictive tool for discovery of additional pay within existing subunconformity fields in Kansas.

  5. Enhanced carbonate reservoir model for an old reservoir utilizing new techniques: The Schaben Field (Mississippian), Ness County, Kansas

    SciTech Connect

    Carr, T.P.; Guy, W.J.; Franseen, E.K.; Bhattacharya, S. )

    1996-01-01

    The Pennsylvanian-Mississippian unconformity is a major stratigraphic event in Kansas that truncates rocks ranging from Precambrian to Mississippian. Many of the 6,000 fields in Kansas are located immediately beneath this unconformity. One example, Schaben Field located in Ness County, Kansas, has produced approximately 9 million barrels since it was discovered in 1963. Production is from the Mississippian (Osagian) cherty dolomites beneath the inconformity. The field was initially developed on a regular forty-acre spacing, but recent drilling has demonstrated the potential for additional targeted infill drilling. To develop an enhanced reservoir model for the Schabin field modern core, log, and well data were integrated with the existing data. New techniques such as [open quotes]Pseudoseismic[close quotes] and the [open quotes]Super[close quotes] Pickett plot were used to leverage the existing data and provide tools for analysis and 3D visualization. The pseudoseismic approach uses well-logs within a standard 3D seismic visualization system to provide a detailed macroscale view of karst patterns. The petrophysical analyses using the [open quotes]Super[close quotes] Pickett plot were used to recognize subtle trends and patterns for each of multiple reservoir intervals. Visual and petrographic examination of core from the field confirms karst development and indicates multiple stages of fracturing, brecciation, and dissolution features that were important in controlling and modifying development of reservoirs. The understanding of the reservoir heterogeneities resulting from the paleokarst model at Schaben field emphasizes the importance of integrating available data with new techniques to provide a predictive tool for discovery of additional pay within existing subunconformity fields in Kansas.

  6. Ground-Penetrating Radar and Dielectric Characterization of Shallow Reservoir Analogs in Central Texas Carbonates

    NASA Astrophysics Data System (ADS)

    Mukherjee, Damayanti; Heggy, Essam; Khan, Shuhab D.; Sullivan, Charlotte E.

    2007-10-01

    Lake Georgetown Spillway near Georgetown (Williamson County) in Central Texas exposes Albian rudist communities and associated depositional facies of the Edwards Formation, Fredericksburg Group. Capped by younger dolostones of the same group, they form important analogs for highly productive fresh-water aquifers and hydrocarbon reservoirs in carbonate environments. A 2D ground-penetrating radar (GPR) survey was conducted using a 400 MHz antenna with the Subsurface Interface Radar (SIR-3000) System by GSSI and tied to GPS data. Data constituting a grid were processed and numerical simulation performed for 3D visualization using the software REFLEX. Dielectric measurements of field-collected rock samples were carried out initially under vacuum dried condition and then under controlled amounts of moisture content (considering 100% saturation of pores of each sample after 2 hours of water treatment). For each sample, penetration depths were calculated for antenna frequencies of 100 and 400 MHz assuming GPR signal penetration in a homogeneous layer. This was followed by porosity-permeability measurements along with petrographic and X-ray diffraction studies. Real (ɛ1) and imaginary parts (ɛ2) of the dielectric permittivity (ɛ), when plotted against moisture content, demonstrated a greater range of ɛ-values for more permeable samples. The depths of penetration varied inversely with the permeability of the samples. The processed 2D GPR data and 3D simulation revealed mound structures below the spillway floor, each with a diameter of ~15-20m and a thickness of ~5m. Petrographic studies showed the dominance of mouldic porosity in these carbonates while X-ray diffraction results confirmed calcite and dolomite as the dominant mineralogy, although present in varying proportions. Silica peaks were encountered that possibly represented chert replacements seen in the thin-sections. We thus conclude that different carbonate units can be differentiated in the field by the GPR

  7. Chemical and physical characteristics of water and sediment in Scofield Reservoir, Carbon County, Utah

    USGS Publications Warehouse

    Waddell, Kidd M.; Darby, D.W.; Theobald, S.M.

    1985-01-01

    Evaluations based on the nutrient content of the inflow, outflow, water in storage, and the dissolved-oxygen depletion during the summer indicate that the trophic state of Scofield Reservoir is borderline between mesotrophic and eutrophic and may become highly eutrophic unless corrective measures are taken to limit nutrient inflow. Sediment deposition in Scofield Reservoir during 1943-79 is estimated to be 3,000 acre-feet, and has decreased the original storage capacity of the reservoir by 4 percent. The sediment contains some coal, and age dating of those sediments (based on the radioisotope lead-210) indicates that most of the coal was deposited prior to about 1950. Scofield Reservoir is dimictic, with turnovers occurring in the spring and autumn. Water in the reservoir circulates completely to the bottom during turnovers. The concentration of dissolved oxygen decreases with depth except during parts of the turnover periods. Below an altitude of about 7,590 feet, where 20 percent of the water is stored, the concentration of dissolved oxygen was less than 2 milligrams per liter during most of the year. During the summer stratification period, the depletion of dissolved oxygen in the deeper layers is coincident with supersaturated conditions in the shallow layers; this is attributed to plant photosynthesis and bacterial respiration in the reservoir. During October 1,1979-August 31, 1980, the discharge-weighted average concentrations of dissolved solids was 195 milligrams per liter in the combined inflow from Fish, Pondtown, and Mud Creeks, and was 175 milligrams per liter in the outflow (and to the Price River). The smaller concentration in the outflow was due primarily to precipitation of calcium carbonate in the reservoir--about 80 percent of the decrease can be accounted for through loss as calcium carbonate. The estimated discharge-weighted average concentration of total nitrogen (dissolved plus suspended) in the combined inflow of Fish, Pondtown, and Mud

  8. The economics of carbon dioxide transport by pipeline and storage in saline aquifers and oil reservoirs

    NASA Astrophysics Data System (ADS)

    McCoy, Sean T.

    Large reductions in carbon dioxide (CO2) emissions are needed to mitigate the impacts of climate change. One method of achieving such reductions is CO2 capture and storage (CCS). CCS requires the capture of carbon dioxide (CO2) at a large industrial facility, such as a power plant, and its transport to a geological storage site where CO2 is sequestered, if implemented, CCS could allow fossil fuels to be used with little or no CO2 emissions until alternative energy sources are more widely deployed. Large volumes of CO2 are most efficiently transported by pipeline and stored either in deep saline aquifers or in oil reservoirs, where CO2 is used for enhanced oil recovery (EOR). This thesis describes a suite of models developed to estimate the project-specific cost of CO2 transport and storage. Engineering-economic models of pipeline CO2 transport, CO2flood EOR, and aquifer storage were developed for this purpose. The models incorporate a probabilistic analysis capability that is used to quantify the sensitivity of transport and storage cost to variability and uncertainty in the model input parameters. The cost of CO2 pipeline transport is shown to be sensitive to the region of construction, in addition to factors such as the length and design capacity of the pipeline. The cost of CO2 storage in saline aquifers is shown to be most sensitive to factors affecting site characterization cost. For EOR projects, CO2 storage has traditionally been a secondary effect of oil recovery; thus, a levelized cost of CO2 storage cannot be defined. Instead EOR projects were evaluated based on the breakeven price of CO2 (i.e., the price of CO2 at which the project net present value is zero). The breakeven CO2 price is shown to be most sensitive to oil prices, losses of CO2 outside the productive zone of the reservoir, and reservoir pressure. Future research should include collection and aggregation of more specific data characterizing possible sites for aquifer storage and applications

  9. The effects of land abandonment and long-term afforestation practices on the organic carbon and lignin content of a Mediteranean soil

    NASA Astrophysics Data System (ADS)

    Stijsiger, Romy; Nadal-Romero, Estela; Campo, Julian; Cammeraat, Erik

    2016-04-01

    Afforestation is an important strategy that can decrease atmospheric carbon in sequestering it in biomass and soils (Pérez-Crusado et al., 2014). In Spain an active afforestation program was adopted in the 1950s, when after wide spread land abandonment the soils were severely eroded (FAO, 2015). In this research the organic carbon and lignin content of the soils in the Araguás catchment area in the Spanish Pyrenees were examined. This research is part of a larger research examining the effect of afforestation over time (Med Afforest Project, PIEF-GA-2013-624974). The research area was afforested with both the P. sylvestris (Scotts Pine) and the P.nigra (Black Pine). Both sites were compared to bare soil (representing severely eroded soil), natural secondary succession (re-vegetation) and meadows. The method used to assess the lignin content is Curie-point pyrolysis with tetramethylammonium hydroxide (TMAH). The results showed a reducing trend for the soil organic carbon (SOC) content with depth. The highest SOC and lignin contents in the topsoil were found under P.nigra and secondary succession. This decline in lignin content corresponds with a high degradation rate (Ad/Al) in the top soil and lower degradation rates in depths of >20 cm. Meadows showed an increased SOC content in deeper horizons, which corresponds to high lignin content as well. In which the meadows showed an increase in lignin content for the soil depths of >20 cm that was unusual and could not be explained by the S/G and P/G ratios and the degradation ratio (Ad/Al). According to the results, P. nigra was the best afforestation practice for increasing the SOC and lignin contents in the soil. The P. sylvestris was considered but proved to be less successful than natural secondary succession. Acknowledgements This research was supported by a Marie Curie Intra-European Fellowship in the project "MED-AFFOREST" (PIEF-GA-2013-624974). JC also acknowledges the VALi+d postdoctoral contract (APOSTD/2014

  10. the COS-Dwarfs survey: the carbon reservoir around sub-L* galaxies

    SciTech Connect

    Bordoloi, Rongmon; Tumlinson, Jason; Peeples, Molly S.; Fox, Andrew J.; Thom, Christopher; Werk, Jessica K.; Prochaska, J. Xavier; Tripp, Todd M.; Katz, Neal; Burchett, Joseph N.; Davé, Romeel; Ford, Amanda Brady; Weinberg, David H.; Kollmeier, Juna A.

    2014-12-01

    We report new observations of circumgalactic gas from the COS-Dwarfs survey, a systematic investigation of the gaseous halos around 43 low-mass z ≤ 0.1 galaxies using background QSOs observed with the Cosmic Origins Spectrograph. From the projected one-dimensional and two-dimensional distribution of C IV absorption, we find that C IV is detected out to ≈100 kpc (corresponding roughly to ≈0.5 R {sub vir}) of the host galaxies. The C IV absorption strength falls off radially as a power law, and beyond ≈0.5 R {sub vir}, no C IV absorption is detected above our sensitivity limit of ≈50-100 mÅ. We find a tentative correlation between detected C IV absorption strength and star formation, paralleling the strong correlation seen in highly ionized oxygen for L ∼ L* galaxies by the COS-Halos survey. The data imply a large carbon reservoir in the circumgalactic medium (CGM) of these galaxies, corresponding to a minimum carbon mass of ≳ 1.2 × 10{sup 6} M {sub ☉} out to ∼110 kpc. This mass is comparable to the carbon mass in the interstellar medium and exceeds the carbon mass currently in the stars of these galaxies. The C IV absorption seen around these sub-L* galaxies can account for almost two-thirds of all W{sub r} ≥ 100 mÅ C IV absorption detected at low z. Comparing the C IV covering fraction with hydrodynamical simulations, we find that an energy-driven wind model is consistent with the observations whereas a wind model of constant velocity fails to reproduce the CGM or the galaxy properties.

  11. What is below the support layer affects carbon nanotube growth: an iron catalyst reservoir yields taller nanotube carpets.

    PubMed

    Shawat, E; Mor, V; Oakes, L; Fleger, Y; Pint, C L; Nessim, G D

    2014-01-01

    Here we demonstrate an approach to enhance the growth of vertically aligned carbon nanotubes (CNTs) by including a catalyst reservoir underneath the thin-film alumina catalyst underlayer. This reservoir led to enhanced CNT growth due to the migration of catalytic material from below the underlayer up to the surface through alumina pinholes during processing. This led to the formation of large Fe particles, which in turn influenced the morphology evolution of the catalytic iron surface layer through Ostwald ripening. With inclusion of this catalyst reservoir, we observed CNT growth up to 100% taller than that observed without the catalyst reservoir consistently across a wide range of annealing and growth durations. Imaging studies of catalyst layers both for different annealing times and for different alumina support layer thicknesses demonstrate that the surface exposure of metal from the reservoir leads to an active population of smaller catalyst particles upon annealing as opposed to a bimodal catalyst size distribution that appears without inclusion of a reservoir. Overall, the mechanism for growth enhancement we present here demonstrates a new route to engineering efficient catalyst structures to overcome the limitations of CNT growth processes.

  12. Geochemical analysis of atlantic rim water, carbon county, wyoming: New applications for characterizing coalbed natural gas reservoirs

    USGS Publications Warehouse

    McLaughlin, J.F.; Frost, C.D.; Sharma, Shruti

    2011-01-01

    Coalbed natural gas (CBNG) production typically requires the extraction of large volumes of water from target formations, thereby influencing any associated reservoir systems. We describe isotopic tracers that provide immediate data on the presence or absence of biogenic natural gas and the identify methane-containing reservoirs are hydrologically confined. Isotopes of dissolved inorganic carbon and strontium, along with water quality data, were used to characterize the CBNG reservoirs and hydrogeologic systems of Wyoming's Atlantic Rim. Water was analyzed from a stream, springs, and CBNG wells. Strontium isotopic composition and major ion geochemistry identify two groups of surface water samples. Muddy Creek and Mesaverde Group spring samples are Ca-Mg-S04-type water with higher 87Sr/86Sr, reflecting relatively young groundwater recharged from precipitation in the Sierra Madre. Groundwaters emitted from the Lewis Shale springs are Na-HCO3-type waters with lower 87Sr/86Sr, reflecting sulfate reduction and more extensive water-rock interaction. To distinguish coalbed waters, methanogenically enriched ??13CDIC wasused from other natural waters. Enriched ??13CDIC, between -3.6 and +13.3???, identified spring water that likely originates from Mesaverde coalbed reservoirs. Strongly positive ??13CDIC, between +12.6 and +22.8???, identified those coalbed reservoirs that are confined, whereas lower ??13CDIC, between +0.0 and +9.9???, identified wells within unconfined reservoir systems. Copyright ?? 2011. The American Association of Petroleum Geologists. All rights reserved.

  13. Dynamic three-dimensional pore-scale imaging of reaction in a carbonate at reservoir conditions.

    PubMed

    Menke, Hannah P; Bijeljic, Branko; Andrew, Matthew G; Blunt, Martin J

    2015-04-07

    Quantifying CO2 transport and average effective reaction rates in the subsurface is essential to assess the risks associated with underground carbon capture and storage. We use X-ray microtomography to investigate dynamic pore structure evolution in situ at temperatures and pressures representative of underground reservoirs and aquifers. A 4 mm diameter Ketton carbonate core is injected with CO2-saturated brine at 50 °C and 10 MPa while tomographic images are taken at 15 min intervals with a 3.8 μm spatial resolution over a period of 2(1/2) h. An approximate doubling of porosity with only a 3.6% increase in surface area to volume ratio is measured from the images. Pore-scale direct simulation and network modeling on the images quantify an order of magnitude increase in permeability and an appreciable alteration of the velocity field. We study the uniform reaction regime, with dissolution throughout the core. However, at the pore scale, we see variations in the degree of dissolution with an overall reaction rate which is approximately 14 times lower than estimated from batch measurements. This work implies that in heterogeneous rocks, pore-scale transport of reactants limits dissolution and can reduce the average effective reaction rate by an order of magnitude.

  14. Geoscience/Engineering Characterization of the Interwell Environment in Carbonate Reservoirs Based on Outcrop Analogs, Permian Basin, West Texas and New Mexico.

    SciTech Connect

    Lucia, F.J.; Kerans, C.

    1997-05-29

    The objective of this project is to investigate styles of reservoir heterogeneity found in low permeability pelleted wackestone/packstone facies and mixed carbonate/clastic facies found in Permian Basin reservoirs by studying similar facies found in Permian Basin reservoirs by studying similar facies exposed in the Guadalupe Mountains. Specific objectives for the outcrop study include construction of a stratigraphic framework, petrophysical quantification of the framework, and testing the outcrop reservoir model for effects of reservoir heterogeneity on production performance. Specific objectives for the subsurface study parallel objectives for the outcrop study.

  15. Improved Oil Recovery in Mississippian Carbonate Reservoirs of Kansas - Near-Term, Class II

    SciTech Connect

    Carr, Timothy R.; Green, Don W.; Willhite, G. Paul

    2001-10-30

    The focus of this project was development and demonstration of cost-effective reservoir description and management technologies to extend the economic life of mature reservoirs in Kansas and the mid-continent.

  16. 3D modeling of gas/water distribution in water-bearing carbonate gas reservoirs: the Longwangmiao gas field, China

    NASA Astrophysics Data System (ADS)

    Ou, Chenghua; Li, ChaoChun; Ma, Zhonggao

    2016-10-01

    A water-bearing carbonate gas reservoir is an important natural gas resource being developed worldwide. Due to the long-term water/rock/gas interaction during geological evolution, complex gas/water distribution has formed under the superposed effect of sedimentary facies, reservoir space facies and gravity difference of fluid facies. In view of these challenges, on the basis of the conventional three-stage modeling method, this paper presents a modelling method controlled by four-stage facies to develop 3D model of a water-bearing carbonate gas reservoir. Key to this method is the reservoir property modelling controlled by two-stage facies, and the fluid property modelling controlled by another two-stage facies. The prerequisite of this method is a reliable database obtained from solid geological investigation. On the basis of illustrating the principles of the modelling method controlled by four-stage facies, this paper further implements systematically modeling of the heterogeneous gas/water distribution of the Longwangmiao carbonate formation in the Moxi-Gaoshiti area, Sichuan basin, China.

  17. Abandoned Texas oil fields

    SciTech Connect

    Not Available

    1980-12-01

    Data for Texas abandoned oil fields were primarily derived from two sources: (1) Texas Railroad Commission (TRRC), and (2) Dwight's ENERGYDATA. For purposes of this report, abandoned oil fields are defined as those fields that had no production during 1977. The TRRC OILMASTER computer tapes were used to identify these abandoned oil fields. The tapes also provided data on formation depth, gravity of oil production, location (both district and county), discovery date, and the cumulative production of the field since its discovery. In all, the computer tapes identified 9211 abandoned fields, most of which had less than 250,000 barrel cumulative production. This report focuses on the 676 abandoned onshore Texas oil fields that had cumulative production of over 250,000 barrels. The Dwight's ENERGYDATA computer tapes provided production histories for approximately two-thirds of the larger fields abandoned in 1966 and thereafter. Fields which ceased production prior to 1966 will show no production history nor abandonment date in this report. The Department of Energy hopes the general availability of these data will catalyze the private sector recovery of this unproduced resource.

  18. Hydrology of the Valley-fill and carbonate-rock reservoirs, Pahrump Valley, Nevada-California

    USGS Publications Warehouse

    Malmberg, Glenn T.

    1967-01-01

    This is the second appraisal of the water supply of Pahrump Valley, made 15 years after the first cooperative study. In the first report the average recharge was estimated to be 23,000 acre-feet per year, only 1,000 acre-feet more than the estimate made in this report. All this recharge was considered to be available for development. Because of the difficulty in salvaging the subsurface outflow from the deep carbonate-rock reservoir, this report concludes that the perennial yield may be only 25,000 acre-feet. In 1875, Bennetts and Manse Springs reportedly discharged a total of nearly 10,000 acre-feet of water from the valley-fill reservoir. After the construction of several flowing wells in 1910, the spring discharge began to decline. In the mid-1940's many irrigation wells were drilled, and large-capacity pumps were installed. During the 4-year period of this study (1959-62), the net pumping draft averaged about 25,000 acre-feet per year, or about twice the estimated yield. In 1962 Bennetts Spring was dry, and the discharge from Marse Spring was only 1,400 acre-feet. During the period February 1959-February 1962, pumping caused an estimated storage depletion of 45,000 acre-feet, or 15,000 acre-feet per year. If the overdraft is maintained, depletion of stored water will continue and pumping costs will increase. Water levels in the vicinity of the Pahrump, Manse, and Fowler Ranches declined more than ]0 feet in response to the pumping during this period, and they can be expected to continue to decline at ,the projected rate of more than 3 feet per year. The chemical quality of the pumped water has been satisfactory for irrigation and domestic use. Recycling of water pumped or irrigation, however, could result in deterioration of the water quality with time.

  19. Experiments and modeling of variably permeable carbonate reservoir samples in contact with CO₂-acidified brines

    DOE PAGES

    Smith, Megan M.; Hao, Yue; Mason, Harris E.; ...

    2014-12-31

    Reactive experiments were performed to expose sample cores from the Arbuckle carbonate reservoir to CO₂-acidified brine under reservoir temperature and pressure conditions. The samples consisted of dolomite with varying quantities of calcite and silica/chert. The timescales of monitored pressure decline across each sample in response to CO₂ exposure, as well as the amount of and nature of dissolution features, varied widely among these three experiments. For all samples cores, the experimentally measured initial permeability was at least one order of magnitude or more lower than the values estimated from downhole methods. Nondestructive X-ray computed tomography (XRCT) imaging revealed dissolution featuresmore » including “wormholes,” removal of fracture-filling crystals, and widening of pre-existing pore spaces. In the injection zone sample, multiple fractures may have contributed to the high initial permeability of this core and restricted the distribution of CO₂-induced mineral dissolution. In contrast, the pre-existing porosity of the baffle zone sample was much lower and less connected, leading to a lower initial permeability and contributing to the development of a single dissolution channel. While calcite may make up only a small percentage of the overall sample composition, its location and the effects of its dissolution have an outsized effect on permeability responses to CO₂ exposure. The XRCT data presented here are informative for building the model domain for numerical simulations of these experiments but require calibration by higher resolution means to confidently evaluate different porosity-permeability relationships.« less

  20. Soil organic carbon in Apolobamba (Bolivia): Quantity and quality of the reservoir

    NASA Astrophysics Data System (ADS)

    Muñoz, M. Á.; Faz, A.

    2009-04-01

    soluble organic carbon (WSOC) were messure. In addition, 13C MNR technique was used in surface samples in each plot in order to determine the main carbonide groups: alkyl, O-alkyl, aromatic and carboxilic. Results were discussing through statistical analyses. Soil profile datas exhibited very low TOC in Ulla-Ulla zone including the surface horizon. Sampling plot results showed maximum TOC contents in Wakampata and Puyo-Puyo surface samples; on the other hand, Sucondori, Caballchiñuni and Ulla-Ulla presented minimum contents. Generally speaking, low and medium WSOC inputs were determined in surface and subsurface samples, respectively, in studied areas. Moreover, Wakampata and Japu zones presented high O-alkyl percentages; it could be related to highest polysacharide concentrations and the easiest SOM degradation, taking into account alkyl/O-alkyl ratios. On the contrary, Ulla-Ulla and Caballchiñuni exhibited highest carboxilic percentages pointing out a SOM oxidation increase. In conclusion, Apolobamba soils presented different SOC conditions. There were some zones which could be characterized as excellent carbon reservoirs due to high SOM quantity and quality; however, in other census places could be identify a certain soil exhaustion degree, as a consequence to the soil overexploitation due to the cattle camelid concentrations both the natural wind erosion in these zones. It should be carried out conservation actions in order to improve the carbon sink and to preserve the soil and the biodiversity in Apolobamba.

  1. Abandoned Mine Lands

    EPA Pesticide Factsheets

    Abandoned Mine Lands are those lands, waters, and surrounding watersheds where extraction, beneficiation, or processing of ores and minerals (excluding coal) has occurred. These lands also include areas where mining or processing activity is inactive.

  2. Abandoning wells working group

    SciTech Connect

    1997-03-01

    The primary objective of this working group is to identify major technical, regulatory, and environmental issues that are relevant to the abandonment of offshore wellbores. Once the issues have been identified, the working group also has the objective of making recommendations or providing potential solutions for consideration. Areas for process improvement will be identified and {open_quotes}best practices{close_quotes} will be discussed and compared to {open_quotes}minimum standards.{close_quotes} The working group will primarily focus on wellbore abandonment in the Gulf of Mexico. However, workshop participants are encouraged to discuss international issues which may be relevant to wellbore abandonment practices in the Gulf of Mexico. The Abandoning Wells Group has identified several major areas for discussion that have concerns related to both operators and service companies performing wellbore abandonments in the Gulf of Mexico. The following broad topics were selected for the agenda: (1) MMS minimum requirements and state regulations. (2) Co-existence of best practices, new technology, and P & A economics. (3) Liability and environmental issues relating to wellbore abandonment.

  3. Carbonate mound reservoirs in the paradox formation: An outcrop analogue along the San Juan River, Southeastern Utah

    SciTech Connect

    Chidsey, T. C. Jr.; Morgan, C.D.; Eby, D.E.

    1996-06-01

    Carbonate mound reservoirs within the Pennsylvanian (Desmoinesian) Paradox Formation are major producers of oil and gas in the Paradox basin of Utah, Colorado, and Arizona. Outcrops of the Paradox Formation along the San Juan River of southeastern Utah provide small-scale analogues of reservoir heterogeneity, flow barriers and baffles, lithofacies, and geometry. These characteristics can be used in reservoir simulation models for secondary/tertiary recovery of oil from small fields in the basin. Exposures of the Paradox Formation Ismay zone in the Wild Horse Canyon area display lateral facies changes from phylloid algal mounds to off-mound detrital wedges or fans bounded at the top by a flooding surface. The phylloid mounds are composed of bafflestone, skeletal grainstone, packstone, and cementstone. Algal plates, brachiopods, bryozoans, and rugose corals are commonly found in the phylloid mounds. The mound wall is composed of rudstone, lumpstone, and cementstone. The detrital fan consists of transported algal material, grainstone, and mudstone with open-marine fossils. Within the mound complex is an inter-mound trough tentatively interpreted to be a tidal channel. The geometry and composition of the rocks in the trough significantly add to the overall heterogeneity of the mound. Reservoir models are being developed for possible water- and carbon-dioxide floods of small Paradox basin fields to determine the most effective secondary/tertiary recovery method. The models will include lithologic fabrics, flooding surfaces, and inter-mound troughs, based on the mound complex exposed at Wild Horse Canyon. This project may also provide reservoir information for simulation models in small Paleozoic carbonate mound fields in other basins worldwide.

  4. Key factors for determining groundwater impacts due to leakage from geologic carbon sequestration reservoirs

    SciTech Connect

    Carroll, Susan A.; Keating, Elizabeth; Mansoor, Kayyum; Dai, Zhenxue; Sun, Yunwei; Trainor-Guitton, Whitney; Brown, Chris; Bacon, Diana

    2014-09-07

    The National Risk Assessment Partnership (NRAP) is developing a science-based toolset for the analysis of potential impacts to groundwater chemistry from CO2 injection (www.netldoe.gov/nrap). The toolset adopts a stochastic approach in which predictions address uncertainties in shallow groundwater and leakage scenarios. It is derived from detailed physics and chemistry simulation results that are used to train more computationally efficient models, referred to here as reduced-order models (ROMs), for each component system. In particular, these tools can be used to help regulators and operators understand the expected sizes and longevity of plumes in pH, TDS, and dissolved metals that could result from a leakage of brine and/or CO2 from a storage reservoir into aquifers. This information can inform, for example, decisions on monitoring strategies that are both effective and efficient. We have used this approach to develop predictive reduced-order models for two common types of reservoirs, but the approach could be used to develop a model for a specific aquifer or other common types of aquifers. In this paper we describe potential impacts to groundwater quality due to CO2 and brine leakage, discuss an approach to calculate thresholds under which no impact to groundwater occurs, describe the time scale for impact on groundwater, and discuss the probability of detecting a groundwater plume should leakage occur. To facilitate this, multi-phase flow and reactive transport simulations and emulations were developed for two classes of aquifers, considering uncertainty in leakage source terms and aquifer hydrogeology. We targeted an unconfined fractured carbonate aquifer based on the Edwards aquifer in Texas and a confined alluvium aquifer based on the High Plains Aquifer in Kansas, which share characteristics typical of many drinking water aquifers in the United States. The hypothetical leakage scenarios centered on the notion that wellbores

  5. Key factors for determining groundwater impacts due to leakage from geologic carbon sequestration reservoirs

    DOE PAGES

    Carroll, Susan A.; Keating, Elizabeth; Mansoor, Kayyum; ...

    2014-09-07

    The National Risk Assessment Partnership (NRAP) is developing a science-based toolset for the analysis of potential impacts to groundwater chemistry from CO2 injection (www.netldoe.gov/nrap). The toolset adopts a stochastic approach in which predictions address uncertainties in shallow groundwater and leakage scenarios. It is derived from detailed physics and chemistry simulation results that are used to train more computationally efficient models, referred to here as reduced-order models (ROMs), for each component system. In particular, these tools can be used to help regulators and operators understand the expected sizes and longevity of plumes in pH, TDS, and dissolved metals that could resultmore » from a leakage of brine and/or CO2 from a storage reservoir into aquifers. This information can inform, for example, decisions on monitoring strategies that are both effective and efficient. We have used this approach to develop predictive reduced-order models for two common types of reservoirs, but the approach could be used to develop a model for a specific aquifer or other common types of aquifers. In this paper we describe potential impacts to groundwater quality due to CO2 and brine leakage, discuss an approach to calculate thresholds under which no impact to groundwater occurs, describe the time scale for impact on groundwater, and discuss the probability of detecting a groundwater plume should leakage occur. To facilitate this, multi-phase flow and reactive transport simulations and emulations were developed for two classes of aquifers, considering uncertainty in leakage source terms and aquifer hydrogeology. We targeted an unconfined fractured carbonate aquifer based on the Edwards aquifer in Texas and a confined alluvium aquifer based on the High Plains Aquifer in Kansas, which share characteristics typical of many drinking water aquifers in the United States. The hypothetical leakage scenarios centered on the notion that wellbores are the most likely

  6. CO{sub 2} Huff-n-Puff process in a light oil shallow shelf carbonate reservoir

    SciTech Connect

    1998-06-01

    The application of cyclic CO{sub 2}, often referred to as the CO{sub 2} Huff-n-Puff process, may find its niche in the maturing waterfloods of the Permian Basin. Coupling the CO{sub 2} H-n-P process to miscible flooding applications could provide the needed revenue to sufficiently mitigate near-term negative cash flow concerns in the capital intensive miscible projects. Texaco Exploration and Production Inc. and the US Department of Energy have teamed up in an attempt to develop the CO{sub 2} Huff-n-Puff process in the Grayburg and San Andres formations, a light oil, shallow shelf carbonate reservoir that exists throughout the Permian Basin. This cost-shared effort is intended to demonstrate the viability of this underutilized technology in a specific class of domestic reservoir. The selected site for this demonstration project is the Central Vacuum Unit waterflood in Lea County, New Mexico. The goals of the project are the development of guidelines for cost-effective selection of candidate reservoirs and wells, along with estimating recovery potential. This project has two defined budget periods. The first budget period primarily involves tasks associated with reservoir analysis and characterization, characterizing existing producibility problems, and reservoir simulation of the proposed technology. The final budget period covers the actual field demonstration of the proposed technology. Technology transfer spans the entire course of the project. This report covers the concluding tasks performed under the second budget period.

  7. Determining Carbon and Oxygen Stable Isotope Systematics in Brines at Elevated p/T Conditions to Enhance Monitoring of CO2 Induced Processes in Carbon Storage Reservoirs

    NASA Astrophysics Data System (ADS)

    Becker, V.; Myrttinen, A.; Mayer, B.; Barth, J. A.

    2012-12-01

    Stable carbon isotope ratios (δ13C) are a powerful tool for inferring carbon sources and mixing ratios of injected and baseline CO2 in storage reservoirs. Furthermore, CO2 releasing and consuming processes can be deduced if the isotopic compositions of end-members are known. At low CO2 pressures (pCO2), oxygen isotope ratios (δ18O) of CO2 usually assume the δ18O of the water plus a temperature-dependent isotope fractionation factor. However, at very high CO2 pressures as they occur in CO2 storage reservoirs, the δ18O of the injected CO2 may in fact change the δ18O of the reservoir brine. Hence, changing δ18O of brine constitutes an additional tracer for reservoir-internal carbon dynamics and allows the determination of the amount of free phase CO2 present in the reservoir (Johnson et al. 2011). Further systematic research to quantify carbon and oxygen isotope fractionation between the involved inorganic carbon species (CO2, H2CO3, HCO3-, CO32-, carbonate minerals) and kinetic and equilibrium isotope effects during gas-water-rock interactions is necessary because p/T conditions and salinities in CO2 storage reservoirs may exceed the boundary conditions of typical environmental isotope applications, thereby limiting the accuracy of stable isotope monitoring approaches in deep saline formations (Becker et al. 2011). In doing so, it is crucial to compare isotopic patterns observed in laboratory experiments with artificial brines to similar experiments with original fluids from representative field sites to account for reactions of dissolved inorganic carbon (DIC) with minor brine components. In the CO2ISO-LABEL project, funded by the German Ministry for Education and Research, multiple series of laboratory experiments are conducted to determine the influence of pressure, temperature and brine composition on the δ13C of DIC and the δ18O of brines in water-CO2-rock reactions with special focus placed on kinetics and stable oxygen and carbon isotope fractionation

  8. Using Biosurfactants Produced from Agriculture Process Waste Streams to Improve Oil Recovery in Fractured Carbonate Reservoirs

    SciTech Connect

    Stephen Johnson; Mehdi Salehi; Karl Eisert; Sandra Fox

    2009-01-07

    This report describes the progress of our research during the first 30 months (10/01/2004 to 03/31/2007) of the original three-year project cycle. The project was terminated early due to DOE budget cuts. This was a joint project between the Tertiary Oil Recovery Project (TORP) at the University of Kansas and the Idaho National Laboratory (INL). The objective was to evaluate the use of low-cost biosurfactants produced from agriculture process waste streams to improve oil recovery in fractured carbonate reservoirs through wettability mediation. Biosurfactant for this project was produced using Bacillus subtilis 21332 and purified potato starch as the growth medium. The INL team produced the biosurfactant and characterized it as surfactin. INL supplied surfactin as required for the tests at KU as well as providing other microbiological services. Interfacial tension (IFT) between Soltrol 130 and both potential benchmark chemical surfactants and crude surfactin was measured over a range of concentrations. The performance of the crude surfactin preparation in reducing IFT was greater than any of the synthetic compounds throughout the concentration range studied but at low concentrations, sodium laureth sulfate (SLS) was closest to the surfactin, and was used as the benchmark in subsequent studies. Core characterization was carried out using both traditional flooding techniques to find porosity and permeability; and NMR/MRI to image cores and identify pore architecture and degree of heterogeneity. A cleaning regime was identified and developed to remove organic materials from cores and crushed carbonate rock. This allowed cores to be fully characterized and returned to a reproducible wettability state when coupled with a crude-oil aging regime. Rapid wettability assessments for crushed matrix material were developed, and used to inform slower Amott wettability tests. Initial static absorption experiments exposed limitations in the use of HPLC and TOC to determine

  9. Miocene carbonate reservoirs related to tectonic and thermal evolution of southeast Asian marginal basins

    SciTech Connect

    Fulthorpe, C.S.; Brodholt, J.P.; Jurdy, D.M.; Schlanger, S.O.

    1986-05-01

    The early Miocene global sea level rise and oceanic warming period allowed the tropical reef growth belt to expand and fostered the development of major carbonate buildups throughout southeast Asia. A regional paleogeographic reconstruction for 18 m.y. places reefal, shelf, and basinal facies in a tectonic setting of island arcs, subduction zones, and marginal basins. For typical basins, such as the Sulu, Celebes, and South China Sea basins, basin formation and sedimentation models have been developed based on ages inferred from identified marine magnetic anomalies and heat flow data. These basins have many of the attributes needed for hydrocarbon development and maturation. They accumulated sediment from pelagic sources and surrounding island arcs and landmasses fringed by reefs. During the early Miocene, limited water circulation in restricted basins, such as the Sulu and Celebes basins, may have induced dysaerobic conditions that enhanced organic carbon preservation. Models of marginal basin formation provide the basis for studying the time-dependent thermal histories of their sediment sequences. The authors models show that, for example, lower Miocene sediments deposited at a rate of 100 m/m.y. on 20-m.y.-old crust in a typical basin have just entered the oil-generation window. Lower sedimentation rates require deposition on younger crust in order for the sediments to reach an equivalent maturation stage. Estimates of the hydrocarbon potential of such marginal basins should be based on a sequential time-slice analysis of each basin in terms of sediment type, sedimentation rate, sea floor age and thermal regime, and the presence of reservoirs.

  10. Transport of Organic Contaminants Mobilized from Coal through Sandstone Overlying a Geological Carbon Sequestration Reservoir

    SciTech Connect

    Zhong, Lirong; Cantrell, Kirk J.; Bacon, Diana H.; Shewell, Jesse L.

    2014-02-01

    Column experiments were conducted using a wetted sandstone rock installed in a tri-axial core holder to study the flow and transport of organic compounds mobilized by scCO2 under simulated geologic carbon storage (GCS) conditions. The sandstone rock was collected from a formation overlying a deep saline reservoir at a GCS demonstration site. Rock core effluent pressures were set at 0, 500, or 1000 psig and the core temperature was set at 20 or 50°C to simulate the transport to different subsurface depths. The concentrations of the organic compounds in the column effluent and their distribution within the sandstone core were monitored. Results indicate that the mobility though the core sample was much higher for BTEX compounds than for naphthalene. Retention of organic compounds from the vapor phase to the core appeared to be primarily controlled by partitioning from the vapor phase to the aqueous phase. Adsorption to the surfaces of the wetted sandstone was also significant for naphthalene. Reduced temperature and elevated pressure resulted in greater partitioning of the mobilized organic contaminants into the water phase.

  11. CO2 wettability of seal and reservoir rocks and the implications for carbon geo-sequestration

    NASA Astrophysics Data System (ADS)

    Iglauer, Stefan; Pentland, C. H.; Busch, A.

    2015-01-01

    We review the literature data published on the topic of CO2 wettability of storage and seal rocks. We first introduce the concept of wettability and explain why it is important in the context of carbon geo-sequestration (CGS) projects, and review how it is measured. This is done to raise awareness of this parameter in the CGS community, which, as we show later on in this text, may have a dramatic impact on structural and residual trapping of CO2. These two trapping mechanisms would be severely and negatively affected in case of CO2-wet storage and/or seal rock. Overall, at the current state of the art, a substantial amount of work has been completed, and we find that: Sandstone and limestone, plus pure minerals such as quartz, calcite, feldspar, and mica are strongly water wet in a CO2-water system. Oil-wet limestone, oil-wet quartz, or coal is intermediate wet or CO2 wet in a CO2-water system. The contact angle alone is insufficient for predicting capillary pressures in reservoir or seal rocks. The current contact angle data have a large uncertainty. Solid theoretical understanding on a molecular level of rock-CO2-brine interactions is currently limited. In an ideal scenario, all seal and storage rocks in CGS formations are tested for their CO2 wettability. Achieving representative subsurface conditions (especially in terms of the rock surface) in the laboratory is of key importance but also very challenging.

  12. Finite Element Modeling of Water/Steam and Carbon Dioxide Heat and Fluid Transportation in Geothermal Reservoir

    NASA Astrophysics Data System (ADS)

    Zhang, J.; Xing, H.; Zhang, H.

    2009-12-01

    Geothermal energy exploitation and carbon dioxide geosequestration are both attractive topics in renewable clean energy for an environmental society. The enhanced geothermal systems (EGS) have been raised both laboratorially and practically, which employ CO2 instead of water as a heat transmission medium. Our research focuses on numerical simulation of groundwater and carbon dioxide dominated geothermal reservoirs and gives a numerical procedure of coupled heat and fluid flow problems with phase changing by means of finite element method. A few of numerical models are carried out to simulate the drainage of a water/vapor dominated reservoir with CO2 injection. The phase changing of water and CO2 are both monitored as volume saturation or mass fraction, which gives a dynamic concept of the multiphase fluid circulation of CO2-EGS system.

  13. Determination of porosity and facies trends in a complex carbonate reservoir, by using 3-D seismic, borehole tools, and outcrop geology

    SciTech Connect

    Zacharakis, T.G. Jr.; Comet, J.N.; Murillo, A.A.

    1996-08-01

    Mesozoic carbonate reservoirs are found in the Mediterranean Sea, off the east coast of Spain. A wide variation of porosities are found in the core samples and logs: vuggy, breccia, fractures, and cavern porosity. In addition, complex Tertiary carbonate geometries include olistostromes, breccia bodies, and reef buildups, which are found on top of Mesozoic carbonates. Predicting the porosity trends within these oil productive reservoirs requires an understanding of how primary porosity was further enhanced by secondary processes, including fractures, karstification, and dolomitization in burial conditions. Through an extensive investigation of field histories, outcrop geology, and seismic data, a series of basic reservoir styles have been identified and characterized by well log signature and seismic response. The distribution pattern of the different reservoirs styles is highly heterogeneous, but by integrating subsurface data and outcrop analogs, it is possible to distinguish field-scale and local patterns of both vertical and local variations in reservoir properties. Finally, it is important to quantify these reservoir properties through the study of seismic attributes, such as amplitude variations, and log responses at the reservoir interval. By incorporating 3-D seismic data, through the use of seismic inversion, it is possible to predict porosity trends. Further, the use of geostatistics can lead to the prediction of reservoir development within the carbonate facies.

  14. Spatial Risk Analysis of Hydraulic Fracturing near Abandoned and Converted Oil and Gas Wells.

    PubMed

    Brownlow, Joshua W; Yelderman, Joe C; James, Scott C

    2017-03-01

    Interaction between hydraulically generated fractures and existing wells (frac hits) could represent a potential risk to groundwater. In particular, frac hits on abandoned oil and gas wells could lead to upward leakage into overlying aquifers, provided migration pathways are present along the abandoned well. However, potential risk to groundwater is relatively unknown because few studies have investigated the probability of frac hits on abandoned wells. In this study, actual numbers of frac hits were not determined. Rather, the probability for abandoned wells to intersect hypothetical stimulated reservoir sizes of horizontal wells was investigated. Well data were compiled and analyzed for location and reservoir information, and sensitivity analyses were conducted by varying assumed sizes of stimulated reservoirs. This study used public and industry data for the Eagle Ford Shale play in south Texas, with specific attention paid to abandoned oil and gas wells converted into water wells (converted wells). In counties with Eagle Ford Shale activity, well-data analysis identified 55,720 abandoned wells with a median age of 1983, and 2400 converted wells with a median age of 1954. The most aggressive scenario resulted in 823 abandoned wells and 184 converted wells intersecting the largest assumed stimulated reservoir size. Analysis showed abandoned wells have the potential to be intersected by multiple stimulated reservoirs, and risks for intersection would increase if currently permitted horizontal wells in the Eagle Ford Shale are actually completed. Results underscore the need to evaluate historical oil and gas activities in areas with modern unconventional oil and gas activities.

  15. Carbon dioxide emissions from Tucuruí reservoir (Amazon biome): New findings based on three-dimensional ecological model simulations.

    PubMed

    Curtarelli, Marcelo Pedroso; Ogashawara, Igor; de Araújo, Carlos Alberto Sampaio; Lorenzzetti, João Antônio; Leão, Joaquim Antônio Dionísio; Alcântara, Enner; Stech, José Luiz

    2016-05-01

    We used a three-dimensional model to assess the dynamics of diffusive carbon dioxide flux (F(CO2)) from a hydroelectric reservoir located at Amazon rainforest. Our results showed that for the studied periods (2013 summer/wet and winter/dry seasons) the surface averaged F(CO2) presented similar behaviors, with regular emissions peaks. The mean daily surface averaged F(CO2) showed no significant difference between the seasons (p>0.01), with values around -1338mg Cm-2day-1 (summer/wet) and -1395mg Cm-2day-1 (winter/dry). At diel scale, the F(CO2) was large during the night and morning and low during the afternoon in both seasons. Regarding its spatial distribution, the F(CO2) showed to be more heterogeneous during the summer/wet than during the winter/dry season. The highest F(CO2) were observed at transition zone (-300mg Cm-2h-1) during summer and at littoral zone (-55mg Cm-2h-1) during the winter. The total CO2 emitted by the reservoir along 2013 year was estimated to be 1.1Tg C year-1. By extrapolating our results we found that the total carbon emitted by all Amazonian reservoirs can be around 7Tg C year-1, which is 22% lower than the previous published estimate. This significant difference should not be neglected in the carbon inventories since the carbon emission is a key factor when comparing the environmental impacts of different sources of electricity generation and can influences decision makers in the selection of the more appropriate source of electricity and, in case of hydroelectricity, the geographical position of the reservoirs.

  16. Geochemical relationships of petroleum in Mesozoic reservoirs to carbonate source rocks of Jurassic Smackover Formation, southwestern Alabama

    SciTech Connect

    Claypool, G.E.; Mancini, E.A.

    1989-07-01

    Algal carbonate mudstones of the Jurassic Smackover Formation are the main source rocks for oil and condensate in Mesozoic reservoir rocks in southwestern Alabama. This interpretation is based on geochemical analyses of oils, condensates, and organic matter in selected samples of shale (Norphlet Formation, Haynesville Formation, Trinity Group, Tuscaloosa Group) and carbonate (Smackover Formation) rocks. Potential and probable oil source rocks are present in the Tuscaloosa Group and Smackover Formation, respectively. Extractable organic matter from Smackover carbonates has molecular and isotopic similarities to Jurassic oil. Although the Jurassic oils and condensates in southwestern Alabama have genetic similarities, they show significant compositional variations due to differences in thermal maturity and organic facies/lithofacies. Organic facies reflect different depositional conditions for source rocks in the various basins. The Mississippi Interior Salt basin was characterized by more continuous marine to hypersaline conditions, whereas the Manila and Conecuh embayments periodically had lower salnity and greater input of clastic debris and terrestrial organic matter. Petroleum and organic matter in Jurassic rocks of southwestern Alabama show a range of thermal transformations. The gas content of hydrocarbons in reservoirs increases with increasing depth and temperature. In some reservoirs where the temperature is above 266/degrees/F(130/degrees/C), gas-condensate is enriched in isotopically heavy sulfur, apparently derived from thermochemical reduction of Jurassic evaporite sulfate. This process also resulted in increase H/sub 2/S and CO in the gas, and depletion of saturated hydrocarbons in the condensate liquids.

  17. Modeling and optimizing the design of matrix treatments in carbonate reservoirs with self-diverting acid systems

    NASA Astrophysics Data System (ADS)

    Bulgakova, G. T.; Kharisov, R. Ya; Sharifullin, A. R.; Pestrikov, A. V.

    2015-01-01

    Application of a self-diverting-acid based on viscoelastic surfactant (SDVA) is a promising technology for improving the efficacy of acid treatment in oil and gas-bearing carbonate reservoirs. In this study, we present a mathematical model for assessing SDVA flow and reaction with carbonate rock using the SDVA rheological characteristics. The model calculates the technological parameters for acidizing operations and the prediction of well productivity after acid treatment, in addition to technical and economic optimization of the acidizing process by modeling different acid treatment options with varying volumes, injection rates, process fluids stages and initial economic scenarios.

  18. Carbon dioxide and helium emissions from a reservoir of magmatic gas beneath Mammoth Mountain, California

    USGS Publications Warehouse

    Sorey, M.L.; Evans, William C.; Kennedy, B.M.; Farrar, C.D.; Hainsworth, L.J.; Hausback, B.

    1998-01-01

    Carbon dioxide and helium with isotopic compositions indicative of a magmatic source (??13C = -4.5 to -5???, 3He/4He = 4.5 to 6.7 RA) are discharging at anomalous rates from Mammoth Mountain, on the southwestern rim of the Long Valley caldera in eastern California. The gas is released mainly as diffuse emissions from normal-temperature soils, but some gas issues from steam vents or leaves the mountain dissolved in cold groundwater. The rate of gas discharge increased significantly in 1989 following a 6-month period of persistent earthquake swarms and associated strain and ground deformation that has been attributed to dike emplacement beneath the mountain. An increase in the magmatic component of helium discharging in a steam vent on the north side of Mammoth Mountain, which also began in 1989, has persisted until the present time. Anomalous CO2 discharge from soils first occurred during the winter of 1990 and was followed by observations of several areas of tree kill and/or heavier than normal needlecast the following summer. Subsequent measurements have confirmed that the tree kills are associated with CO2 concentrations of 30-90% in soil gas and gas flow rates of up to 31,000 g m-2 d-1 at the soil surface. Each of the tree-kill areas and one area of CO2 discharge above tree line occurs in close proximity to one or more normal faults, which may provide conduits for gas flow from depth. We estimate that the total diffuse CO2 flux from the mountain is approximately 520 t/d, and that 30-50 t/d of CO2 are dissolved in cold groundwater flowing off the flanks of the mountain. Isotopic and chemical analyses of soil and fumarolic gas demonstrate a remarkable homogeneity in composition, suggesting that the CO2 and associated helium and excess nitrogen may be derived from a common gas reservoir whose source is associated with some combination of magmatic degassing and thermal metamorphism of metasedimentary rocks. Furthermore, N2/Ar ratios and nitrogen isotopic values

  19. Geochemical Impacts of Leaking CO2 from Subsurface Storage Reservoirs to an Unconfined Oxidizing Carbonate Aquifer

    SciTech Connect

    Wang, Guohui; Qafoku, Nikolla; Lawter, Amanda R.; Bowden, Mark E.; Harvey, Omar; Sullivan, E. C.; Brown, Christopher F.

    2015-07-15

    A series of batch and column experiments combined with solid phase characterization studies (i.e., quantitative x-ray diffraction and wet chemical extractions) were conducted to address a variety of scientific issues and evaluate the impacts of the potential leakage of carbon dioxide (CO2) from deep subsurface storage reservoirs. The main objective was to gain an understanding of how CO2 gas influences: 1) the aqueous phase pH; and 2) mobilization of major, minor, and trace elements from minerals present in an aquifer overlying potential CO2 sequestration subsurface repositories. Rocks and slightly weathered rocks representative of an unconfined, oxidizing carbonate aquifer within the continental US, i.e., the Edwards aquifer in Texas, were used in these studies. These materials were exposed to a CO2 gas stream or were leached with a CO2-saturated influent solution to simulate different CO2 gas leakage scenarios, and changes in aqueous phase pH and chemical composition were measured in the liquid samples collected at pre-determined experimental times (batch experiments) or continuously (column experiments). The results from the strong acid extraction tests confirmed that in addition to the usual elements present in most soils, rocks, and sediments, the Edward aquifer samples contain As, Cd, Pb, Cu, and occasionally Zn, which may potentially be mobilized from the solid to the aqueous phase during or after exposure to CO2. The results from the batch and column experiments confirmed the release of major chemical elements into the contacting aqueous phase (such as Ca, Mg, Ba, Sr, Si, Na, and K); the mobilization and possible rapid immobilization of minor elements (such as Fe, Al, and Mn), which are able to form highly reactive secondary phases; and sporadic mobilization of only low concentrations of trace elements (such as As, Cd, Pb, Cu, Zn, Mo, etc.). The results from this experimental research effort will help in developing a systematic understanding of how CO2

  20. Design and implementation of a CO{sub 2} flood utilizing advanced reservoir characterization and horizontal injection wells in a shallow shelf carbonate approaching waterflood depletion

    SciTech Connect

    1996-08-09

    The first objective is to utilize reservoir characterization and advanced technologies to optimize the design of a carbon dioxide (CO{sub 2}) project for the South Cowden Unit (SCU) located in Ector County, Texas. The SCU is a mature, relatively small, shallow shelf carbonate unit nearing, waterflood depletion. The second objective is to demonstrate the performance and economic viability of the project in the field. This report includes work on the reservoir characterization and project design objective and the demonstration project objective.

  1. Geoscience/Engineering Characterization of the Interwell Environment in Carbonate Reservoirs Based on Outcrop Analogs, Permian Basin, West Texas and New Mexico.

    SciTech Connect

    Lucia, F.J.; Kerans, C.

    1996-12-31

    The objective of this project is to investigate styles of reservoir heterogeneity found in low permeability pelleted wackestone/packstone facies and mixed carbonate/clastic facies found in Permian Basin reservoirs by studying similar facies exposed in the Guadalupe Mountains. Specific objectives for the outcrop study include construction of a stratigraphic framework, petrophysical quantification of the framework, and testing the outcrop reservoir model for effects of reservoir heterogeneity on production performance. Specific objectives for the subsurface study parallel objectives for the outcrop study.

  2. Cost Effective Surfactant Formulations for Improved Oil Recovery in Carbonate Reservoirs

    SciTech Connect

    William A. Goddard; Yongchun Tang; Patrick Shuler; Mario Blanco; Yongfu Wu

    2007-09-30

    This report summarizes work during the 30 month time period of this project. This was planned originally for 3-years duration, but due to its financial limitations, DOE halted funding after 2 years. The California Institute of Technology continued working on this project for an additional 6 months based on a no-cost extension granted by DOE. The objective of this project is to improve the performance of aqueous phase formulations that are designed to increase oil recovery from fractured, oil-wet carbonate reservoir rock. This process works by increasing the rate and extent of aqueous phase imbibition into the matrix blocks in the reservoir and thereby displacing crude oil normally not recovered in a conventional waterflood operation. The project had three major components: (1) developing methods for the rapid screening of surfactant formulations towards identifying candidates suitable for more detailed evaluation, (2) more fundamental studies to relate the chemical structure of acid components of an oil and surfactants in aqueous solution as relates to their tendency to wet a carbonate surface by oil or water, and (3) a more applied study where aqueous solutions of different commercial surfactants are examined for their ability to recover a West Texas crude oil from a limestone core via an imbibition process. The first item, regarding rapid screening methods for suitable surfactants has been summarized as a Topical Report. One promising surfactant screening protocol is based on the ability of a surfactant solution to remove aged crude oil that coats a clear calcite crystal (Iceland Spar). Good surfactant candidate solutions remove the most oil the quickest from the surface of these chips, plus change the apparent contact angle of the remaining oil droplets on the surface that thereby indicate increased water-wetting. The other fast surfactant screening method is based on the flotation behavior of powdered calcite in water. In this test protocol, first the calcite

  3. Karst-controlled reservoir heterogeneity in Ellenburger group carbonates of west Texas: Reply

    SciTech Connect

    Kerans, C. )

    1990-07-01

    A reply to a comment made on Kerans' paper (AAGP Bull. 1988) by S.J. Mazzullo is presented. The author takes exception that Mazzullo's contention that he left out important types of hydrocarbon reservoirs in the Permian basin of west Texas and points out that his original intention was to model karst-controlled reservoir rocks only.

  4. Co-assessment of biomass and soil organic carbon stocks in a future reservoir area located in Southeast Asia.

    PubMed

    Descloux, Stéphane; Chanudet, Vincent; Poilvé, Hervé; Grégoire, Alain

    2011-02-01

    An assessment of the organic carbon stock present in living or dead vegetation and in the soil on the 450 km2 of the future Nam Theun 2 hydroelectric reservoir in Lao People's Democratic Republic was made. Nine land cover types were defined on the studied area: dense, medium, light, degraded, and riparian forests; agricultural soil; swamps; water; and others (roads, construction sites, and so on). Their geographical distribution was assessed by remote sensing using two 2008 SPOT 5 images. The area is mainly covered by dense and light forests (59%), while agricultural soil and swamps account for 11% and 2%, respectively. For each of these cover types, except water, organic carbon density was measured in the five pools defined by the Intergovernmental Panel on Climate Change: aboveground biomass, litter, deadwood, belowground biomass, and soil organic carbon. The area-weighted mean carbon densities for these pools were estimated at 45.4, 2.0, 2.2, 3.4, and 62.2 tC/ha, respectively, i.e., a total of about 115±15 tC/ha for a soil thickness of 30 cm, corresponding to a total flooded organic carbon stock of 5.1±0.7 MtC. This value is much lower than the carbon density for some South American reservoirs for example where total organic carbon stocks range from 251 to 326 tC/ha. It can be mainly explained by (1) the higher biomass density of South American tropical primary rainforest than of forests in this study and (2) the high proportion of areas with low carbon density, such as agricultural or slash-and-burn zones, in the studied area.

  5. Sedimentary record of water column trophic conditions and sediment carbon fluxes in a tropical water reservoir (Valle de Bravo, Mexico).

    PubMed

    Carnero-Bravo, Vladislav; Merino-Ibarra, Martín; Ruiz-Fernández, Ana Carolina; Sanchez-Cabeza, Joan Albert; Ghaleb, Bassam

    2015-03-01

    Valle de Bravo (VB) is the main water reservoir of the Cutzamala hydraulic system, which provides 40% of the drinking water consumed in the Mexico City Metropolitan Area and exhibits symptoms of eutrophication. Nutrient (C, N and P) concentrations were determined in two sediment cores to reconstruct the water column trophic evolution of the reservoir and C fluxes since its creation in 1947. Radiometric methods ((210)Pb and (137)Cs) were used to obtain sediment chronologies, using the presence of pre-reservoir soil layers in one of the cores as an independent chronological marker. Mass accumulation rates ranged from 0.12 to 0.56 g cm(-2) year(-1) and total organic carbon (TOC) fluxes from 122 to 380 g m(-2) year(-1). Total N ranged 4.9-48 g m(-2) year(-1), and total P 0.6-4.2 g m(-2) year(-1). The sedimentary record shows that all three (C, N and P) fluxes increased significantly after 1991, in good agreement with the assessed trophic evolution of VB and with historic and recent real-time measurements. In the recent years (1992-2006), the TOC flux to the bottom of VB (average 250 g m(-2) year(-1), peaks 323 g m(-2) year(-1)) is similar to that found in highly eutrophic reservoirs and impoundments. Over 1/3 of the total C burial since dam construction, circa 70,000 t, has occurred in this recent period. These results highlight the usefulness of the reconstruction of carbon and nutrient fluxes from the sedimentary record to assess carbon burial and its temporal evolution in freshwater ecosystems.

  6. Diffusive emission of methane and carbon dioxide from two hydropower reservoirs in Brazil.

    PubMed

    Marcelino, A A; Santos, M A; Xavier, V L; Bezerra, C S; Silva, C R O; Amorim, M A; Rodrigues, R P; Rogerio, J P

    2015-05-01

    The role of greenhouse gas emissions from freshwater reservoirs and their contribution to increase greenhouse gas concentrations in the atmosphere is currently under discussion in many parts of the world. We studied CO2 and CH4 diffusive fluxes from two large neotropical hydropower reservoirs with different climate conditions. We used floating closed-chambers to estimate diffusive fluxes of these gaseous species. Sampling campaigns showed that the reservoirs studied were sources of greenhouse gases to the atmosphere. In the Serra da Mesa Reservoir, the CH4 emissions ranged from 0.530 to 396.96 mg.m(-2).d(-1) and CO2 emissions ranged from -1,738.33 to 11,166.61 mg.m(-2).d(-1) and in Três Marias Reservoir the CH4 fluxes ranged 0.720 to 2,578.03 mg.m(-2).d(-1) and CO2 emission ranged from -3,037.80 to 11,516.64 to mg.m(-2).d(-1). There were no statistically significant differences of CH4 fluxes between the reservoirs, but CO2 fluxes from the two reservoirs studied were significantly different. The CO2 emissions measured over the periods studied in Serra da Mesa showed some seasonality with distinctions between the wet and dry transition season. In Três Marias Reservoir the CO2 fluxes showed no seasonal variability. In both reservoirs, CH4 emissions showed a tendency to increase during the study periods but this was not statistically significant. These results contributed to increase knowledge about the magnitude of CO2 and CH4 emission in hydroelectric reservoirs, however due to natural variability of the data future sampling campaigns will be needed to better elucidate the seasonal influences on the fluxes of greenhouse gases.

  7. Subtask 1.17 - Measurement of Hydrocarbon Evolution from Coal and Petroleum Reservoirs Under Carbon Dioxide Floods

    SciTech Connect

    Steven B. Hawthorne

    2006-12-31

    The project developed, built, and tested three apparatuses for studying different interactions of carbon dioxide with geologic materials. In Year 1, an online instrument was constructed by coupling a high-pressure carbon dioxide extraction system with a flame ionization detector that can yield a real-time profile and quantitative measurements of hydrocarbons removed from materials such as coal and petroleum reservoir rock. In Years 2 and 3, one instrument was built to measure the excess sorption of carbon dioxide in geologic materials such as coal and showed that measurable uptake of carbon dioxide into the coal matrix is rapid. The final apparatus was built to expose geologic materials to carbon dioxide for long periods of time (weeks to months) under the range of pressures and temperatures relevant to carbon dioxide sequestration. The apparatus allows as many as twenty gram-sized samples of geologic materials to be exposed simultaneously and can also include exposures with geologic brines. The system was used to demonstrate complete conversion of magnesium silicate to magnesium carbonate in less than 4 weeks when exposed to clean water or brine, compared to no measurable conversion of dry magnesium carbonate.

  8. Abandoning the mentally ill.

    PubMed

    Barton, R

    1975-12-01

    Mentally ill people have been avoided and abandoned by their families and public authorities for hundreds of years. Present day abandonment includes the deployment of professionals from patients to paper; the destruction of availability and effectiveness of institutional facilities; the obfuscation of mental illness by captious, sematic criticism; the aspirations of paramedical and paraprofessional groups; and the subordination of the primary purpose of institutions and physicians to other objectives. The nature of authority is discussed and the need for the treatment of mentally ill people to be based on the art and science of medicine, rather than the pretension and advocacy of the gullible, unqualified or unscrupulous, is noted.

  9. Influence of the timing of HC injection on the preservation of petrophysical properties of carbonate reservoirs at great depth

    NASA Astrophysics Data System (ADS)

    Neveux, Lucille; Grgic, Dragan; Pironon, Jacques; Carpentier, Cédric; Girard, Jean-Pierre

    2013-04-01

    In the oil industry, the preservation of petrophysical properties at great depth may lead to the existence of a deeply buried reservoir (DBR), a favoured target in the field of petroleum exploration and exploitation. The accurate prediction of reservoir quality requires an understanding of the key controlling diagenetic processes. Pressure solution is one of the main processes happening during diagenesis and being responsible for the evolution of porosity and permeability in many reservoirs. However, others processes may potentially act upon carbonate rocks during diagenesis: the timing of oil arrival is one of these processes. The aim of this study is to investigate experimentally the influence of oil injection and timing of this injection on the pressure solution process and thus on carbonate petrophysical properties. The experiments were performed using a subsurface consolidated carbonate rock and a specifically designed experimental apparatus, enabling the simulation of in situ conditions (pressure/stresses and temperature) of deeply buried reservoirs. Three experiments were realised with different fluids and injection conditions, namely meteoric fluid as the interstitial fluid, early saturation in oil of the sample followed by the injection of a meteoric fluid, late injection of oil in a sample initially saturated with a meteoric fluid. The results obtained in this study showed that without oil in the interstitial fluid, the main diagenetic process is the pressure solution creep (PSC). This process reduces by three the initial porosity but don't have any significant influence on permeability. When the sample was initially saturated with oil before the injection of the meteoric fluid, the process of PSC was inhibited. In this case, the porosity showed a slight decrease and the permeability showed a strong decrease from 23 mD to 1 mD. When an initially saturated (with a meteoric fluid) sample undergone a late injection of oil, the porosity was not preserved and

  10. INTEGRATED GEOLOGIC-ENGINEERING MODEL FOR REEF AND CARBONATE SHOAL RESERVOIRS ASSOCIATED WITH PALEOHIGHS: UPPER JURASSIC SMACKOVER FORMATION, NORTHEASTERN GULF OF MEXICO

    SciTech Connect

    Ernest A. Mancini

    2001-09-14

    The University of Alabama in cooperation with Texas A&M University, McGill University, Longleaf Energy Group, Strago Petroleum Corporation, and Paramount Petroleum Company are undertaking an integrated, interdisciplinary geoscientific and engineering research project. The project is designed to characterize and model reservoir architecture, pore systems and rock-fluid interactions at the pore to field scale in Upper Jurassic Smackover reef and carbonate shoal reservoirs associated with varying degrees of relief on pre-Mesozoic basement paleohighs in the northeastern Gulf of Mexico. The project effort includes the prediction of fluid flow in carbonate reservoirs through reservoir simulation modeling which utilizes geologic reservoir characterization and modeling and the prediction of carbonate reservoir architecture, heterogeneity and quality through seismic imaging. The primary objective of the project is to increase the profitability, producibility and efficiency of recovery of oil from existing and undiscovered Upper Jurassic fields characterized by reef and carbonate shoals associated with pre-Mesozoic basement paleohighs. The principal research effort for Year 1 of the project has been reservoir description and characterization. This effort has included four tasks: (1) geoscientific reservoir characterization, (2) the study of rock-fluid interactions, (3) petrophysical and engineering characterization and (4) data integration. This work was scheduled for completion in Year 1. Overall, the project work is on schedule. Geoscientific reservoir characterization is essentially completed. The architecture, porosity types and heterogeneity of the reef and shoal reservoirs at Appleton and Vocation Fields have been characterized using geological and geophysical data. The study of rock-fluid interactions has been initiated. Observations regarding the diagenetic processes influencing pore system development and heterogeneity in these reef and shoal reservoirs have been

  11. INTEGRATED GEOLOGIC-ENGINEERING MODEL FOR REEF AND CARBONATE SHOAL RESERVOIRS ASSOCIATED WITH PALEOHIGHS: UPPER JURASSIC SMACKOVER FORMATION, NORTHEASTERN GULF OF MEXICO

    SciTech Connect

    Ernest A. Mancini

    2002-09-25

    The University of Alabama in cooperation with Texas A&M University, McGill University, Longleaf Energy Group, Strago Petroleum Corporation, and Paramount Petroleum Company are undertaking an integrated, interdisciplinary geoscientific and engineering research project. The project is designed to characterize and model reservoir architecture, pore systems and rock-fluid interactions at the pore to field scale in Upper Jurassic Smackover reef and carbonate shoal reservoirs associated with varying degrees of relief on pre-Mesozoic basement paleohighs in the northeastern Gulf of Mexico. The project effort includes the prediction of fluid flow in carbonate reservoirs through reservoir simulation modeling which utilizes geologic reservoir characterization and modeling and the prediction of carbonate reservoir architecture, heterogeneity and quality through seismic imaging. The primary objective of the project is to increase the profitability, producibility and efficiency of recovery of oil from existing and undiscovered Upper Jurassic fields characterized by reef and carbonate shoals associated with pre-Mesozoic basement paleohighs. The principal research effort for Year 2 of the project has been reservoir characterization, 3-D modeling and technology transfer. This effort has included six tasks: (1) the study of rockfluid interactions, (2) petrophysical and engineering characterization, (3) data integration, (4) 3-D geologic modeling, (5) 3-D reservoir simulation and (6) technology transfer. This work was scheduled for completion in Year 2. Overall, the project work is on schedule. Geoscientific reservoir characterization is essentially completed. The architecture, porosity types and heterogeneity of the reef and shoal reservoirs at Appleton and Vocation Fields have been characterized using geological and geophysical data. The study of rock-fluid interactions is near completion. Observations regarding the diagenetic processes influencing pore system development and

  12. Improved oil recovery in Mississippian carbonate reservoirs of Kansas near term Class 2. Annual report, September 18, 1994--March 15, 1997

    SciTech Connect

    Carr, T.R.; Green, D.W.; Willhite, G.P.

    1998-04-01

    This annual report describes progress during the second year of the project entitled {open_quotes}Improved Oil Recovery in Mississippian Carbonate Reservoirs in Kansas{close_quotes}. This project funded under the Department of Energy`s Class 2 program targets improving the reservoir performance of mature oil fields located in shallow shelf carbonate reservoirs. The focus of this project is development and demonstration of cost-effective reservoir description and management technologies to extend the economic life of mature reservoirs in Kansas and the mid-continent. As part of the project, several tools and techniques for reservoir description and management were developed, modified and demonstrated. These include: (1) a new approach to subsurface visualization using electric logs ({open_quotes}Pseudoseismic{open_quotes}); (2) a low-cost easy-to-use spreadsheet log analysis software (PfEFFER); and (3) an extension of the BOAST-3 computer program for full field reservoir simulation. The world-wide-web was used to provide rapid and flexible dissemination of the project results through the Internet. Included in this report is a summary of significant project results at the demonstration site (Schaben Field, Ness County, Kansas). These results include an outline of the reservoir description based on available and newly acquired data and reservoir simulation results. Detailed information is available on-line through the Internet. Based on the reservoir simulation, three infill wells will be drilled to validate the reservoir description and demonstrate the effectiveness of the proposed reservoir management strategies. The demonstration phase of the project has just begun and will be presented in the next annual report.

  13. Fish mercury development in relation to abiotic characteristics and carbon sources in a six-year-old, Brazilian reservoir.

    PubMed

    Tuomola, Leena; Niklasson, Terese; de Castro E Silva, Edinaldo; Hylander, Lars D

    2008-02-01

    Time series on fish mercury (Hg) development are rare for hydroelectric reservoirs in the tropics. In the central-western part of Brazil, a hydroelectric reservoir, called Lago Manso, was completed in 1999 after that background levels of fish Hg concentrations had been determined. The development for the first 3 years was studied in 2002. The objective of the present study was to determine development of fish Hg concentrations for a second three-year period after flooding. The bioaccumulation factor and certain abiotic and biotic factors, possibly affecting the availability and accumulation of Hg, were also examined. The results show that Hg levels in fish from Lago Manso have increased more than five times compared to the background levels observed before construction of the reservoir. At the same time, dissolved organic carbon has increased while dissolved oxygen has decreased indicating enhanced bioavailability of Hg. In the reservoir, Salminus brasiliensis had in average a Hg content of 1.1 microg g(-1) f.w., Pseudoplatystoma fasciatum 1.2, Serrasalmus marginatus/spilopleura 0.9, and Brycon hilarii 0.6 microg g(-1) f.w. The average fish Hg contents were higher downstream, except for B. hilarii. In the reservoir, the average Hg content of each species was in 2005 always over the consumption limit (0.55 microg total Hg g(-1) f.w.) recommended by WHO. Therefore, the people living around Lago Manso should be informed of the health effects of Hg, and fish consumption recommendations should be carried out. The accumulation of Hg varies widely between species as shown by the bioaccumulation factor which ranges between 5.08 and 5.59 log units. The observed variation is explained by differences in diet and trophic position with piscivorous fish exhibiting the highest mean Hg concentration, followed by carnivorous and omnivorous species. Carbon isotope analyses imply that trophic position is not the only cause of the observed differences in Hg levels between omnivorous B

  14. Ranking of Texas reservoirs for application of carbon dioxide miscible displacement

    SciTech Connect

    Ham, J

    1996-04-01

    Of the 431 reservoirs screened, 211 projected revenue that exceeded cost, ie, were profitable. Only the top 154 reservoirs, however, showed a profit greater than 30%. The top 10 reservoirs predicted a profit of at least 80%. Six of the top ten were Gulf Coast sandstones. The reservoirs are representative of the most productive discoveries in Texas; they account for about 72% of the recorded 52 billion barrels oil production in the State. Preliminary evaluation in this study implied that potential production from CO{sub 2}-EOR could be as much as 4 billion barrels. In order to enhance the chances of achieving this, DOE should consider a targeted outreach program to the specific independent operators controlling the leases. Development of ownership/technical potential maps and an outreach program should be initiated to aid this identification.

  15. Carbonate-platform scale correlation of stacked high-frequency sequences in the Arab-D reservoir, Saudi Arabia

    NASA Astrophysics Data System (ADS)

    Al-Awwad, Saad F.; Collins, Lindsay B.

    2013-08-01

    The Late Jurassic Arab Formation contains a number of hydrocarbon-bearing carbonates, the most important of which is the lowermost Arab-D reservoir. The reservoir lithofacies in Khurais Field are: couplets of 1) lime mud and 2) intraclastic lithofacies representing basinal turbidites; 3) pelletal lithofacies representing lower shoreface sands and silts; 4) stromatoporoid lithofacies representing a reef; 5) Cladocoropsis and 6) dasyclad lithofacies representing a lagoon; 7) peloidal and 8) oolitic lithofacies representing shore-attached sand sheets; 9) cryptomicrobial lithofacies representing supratidal flats; 10) anhydrites representing sabkha followed by salina deposits; and 11) stratigraphically reoccurring dolomite. These are arranged in two, partially preserved, third-order sequences, the upper of which represents the Arab-D Member and the lower of which represents the upper Jubaila Formation. Within these sequences lie six fourth-order high frequency sequences, composed of fifth-order parasequences and parasequence-scale cycles. The preserved upward shallowing trend of the Arab-D reservoir is manifested laterally by a regional eastward thickening interpreted to be the result of an eastward progradation across the shallow Late Jurassic epeiric shelf and into the relatively deep Arabian intrashelf basin. This study presents a correlation model that explains the drastic thickening and downward climb of the reservoir lithofacies that is observed between the outcrops south of Riyadh and the subsurface in Ghawar Field. This model is different from the one currently used and predicts an eastward porosity improvement in the upper part of the reservoir accompanied by a porosity reduction in the lower part, assuming a null diagenetic modification effect.

  16. Carbon dioxide and helium emissions from a reservoir of magmatic gas beneath Mammoth Mountain, California

    SciTech Connect

    Sorey, M.L.; Evans, W.C. Kennedy, B.M. Farrar, C.D. Hainsworth, L.J. Hausback, B.

    1998-07-01

    Carbon dioxide and helium with isotopic compositions indicative of a magmatic source ({delta}thinsp{sup 13}C={minus}4.5 to {minus}5{per_thousand}, {sup 3}He/{sup 4}He=4.5 to 6.7 R{sub A}) are discharging at anomalous rates from Mammoth Mountain, on the southwestern rim of the Long Valley caldera in eastern California. The gas is released mainly as diffuse emissions from normal-temperature soils, but some gas issues from steam vents or leaves the mountain dissolved in cold groundwater. The rate of gas discharge increased significantly in 1989 following a 6-month period of persistent earthquake swarms and associated strain and ground deformation that has been attributed to dike emplacement beneath the mountain. An increase in the magmatic component of helium discharging in a steam vent on the north side of Mammoth Mountain, which also began in 1989, has persisted until the present time. Anomalous CO{sub 2} discharge from soils first occurred during the winter of 1990 and was followed by observations of several areas of tree kill and/or heavier than normal needlecast the following summer. Subsequent measurements have confirmed that the tree kills arc associated with CO{sub 2} concentrations of 30{endash}90{percent} in soil gas and gas flow rates of up to 31,000 gthinspm{sup {minus}2}thinspd{sup {minus}1} at the soil surface. Each of the tree-kill areas and one area of CO{sub 2} discharge above tree line occurs in close proximity to one or more normal faults, which may provide conduits for gas flow from depth. We estimate that the total diffuse CO{sub 2} flux from the mountain is approximately 520 t/d, and that 30{endash}50 t/d of CO{sub 2} are dissolved in cold groundwater flowing off the flanks of the mountain. Isotopic and chemical analyses of soil and fumarolic gas demonstrate a remarkable homogeneity in composition, suggesting that the CO{sub 2} and associated helium and excess nitrogen may be derived from a common gas reservoir whose source is associated with

  17. MULTIDISCIPLINARY IMAGING OF ROCK PROPERTIES IN CARBONATE RESERVOIRS FOR FLOW-UNIT TARGETING

    SciTech Connect

    Stephen C. Ruppel

    2004-07-20

    Our analysis and imaging of reservoir properties at the Fullerton Clear Fork field (Figure 1) is in its final stages. Major accomplishments during the past 6 months include: (1) characterization of facies and cyclicity in cores, (2) correlation of cycles and sequences using core-calibrated wireline logs, (3) calculation and modeling of wireline porosity, (4) analysis of new cores for conventional and special core analysis data, (5) construction of full-field reservoir model, and (6) revision of 3D seismic inversion of reservoir porosity and permeability. One activity has been eliminated from the originally proposed tasks. Task 3 (Characterization and Modeling of Rock Mechanics and Fractures) has been deleted because we have determined that fractures are not significant contributing in the reservoir under study. A second project extension has been asked for to extend the project until 7/31/04. Remaining project activities are: (1) interpretation and synthesis of fieldwide data, (2) preparation of 3D virtual reality demonstrations of reservoir model and attributes, (3) transfer of working data sets to the operator for reservoir implementation and decision-making, and (4) preparation and distribution of final reports.

  18. Carbonate reservoir characterization using seismic velocity and amplitude variation with offset analysis: Hardeman basin, Texas, test case

    SciTech Connect

    Pigott, J.D.; Shrestha, R.K. ); Warwick, R.A. )

    1991-03-01

    Mississippian bioherms in the Hardeman basin, Texas, produce from dolomitized mud cores with porosities that can vary from 10 to 40%. These carbonate buildups, though often similar in seismic reflector boundary configuration, can vary remarkably in reservoir quality (e.g., porosity) owing to diagenesis. However, imaging these lateral variations of porosity and determining the reservoir pressure is possible with detailed seismic velocity control and amplitude variation with offset (AVO) analysis. The investigated 24-fold seismic profile was acquired by four Vibroseis trucks in the Hardeman basin across two bioherms, one oil-productive and other tight and water-filled. Detailed stacking velocity analyses on the relative amplitude processed line directly delineate areas of increasing and decreasing gross porosity and dramatically differentiate the two mounds. Moreover, the detailed velocity analyses help provide a more accurate stacked section with resultant better definition of the external mound configuration. Analysis of available laboratory compressional and shear wave velocity data for carbonate rocks reveal that Young's modulus in carbonates is a function of porosity and differential pressure. Comparison of the derived Young's modulus from an inversion of the AVO data for the unstacked line with the experimental laboratory data yield porosity and differential pressure estimates over the productive bioherm which are within 18% and 15%, respectively, of those observed in the borehole.

  19. Stable carbon isotope as a proxy for the change of phytoplankton community structure in cascade reservoirs from Wujiang River, China

    NASA Astrophysics Data System (ADS)

    Wang, B.; Liu, C. Q.; Peng, X.; Wang, F.; Chen, C.

    2011-01-01

    Phytoplankton community structure and δ13C of dissolved inorganic carbon (DIC), particulate organic carbon (POC), and phytoplanktonic carbon (PPC), and the related hydro-chemical parameters have been seasonally investigated in the cascade reservoirs from the Wujiang River Basin. Average values of δ13CDIC, δ13CPOC and δ13CPPC were -8.1±1.3‰, -29.6±2.8‰, and -30.9±4.5‰, respectively. Seasonal fluctuation of δ13CPPC was comparable to that of δ13CPOC and larger than that of δ13CDIC. The δ13CPPC values showed a significant linear correlation with δ13CPOC, indicating that endogenetic phytoplankton is the main source of POC in these cascade reservoirs. Compared to environmental factors such as temperature, taxonomic differences are the main factor influencing δ13CPPC in this study. As a result, the contribution of Bacillariophyta to the total phytoplankton showed a significant negative correlation with δ13CPPC and Δδ13C (δ13CPPC-δ13CDIC), respectively, suggesting that δ13CPPC can be used to discern the change of phytoplankton community structure although only two kinds of dominant algae (i.e. Bacillariophyta and Chlorophyta) facilitate achieving this relationship. This relationship will have an important significance in understanding evolvement of phytoplankton community structure with time using geochemical technique once it is confirmed at a larger scale in field study.

  20. [Effects of biological regulated measures on active organic carbon and erosion-resistance in the Three Gorges Reservoir region soil].

    PubMed

    Huang, Ru; Huang, Lin; He, Bing-Hui; Zhou, Li-Jiang; Yu, Chuan; Wang, Feng

    2013-07-01

    To gain a better knowledge of characteristics of soils and provide a scientific basis for soil erosion control in the Three Gorges Reservoir Area, contents of aggregates and total soil organic carbon (SOC), as well as soil active organic carbon fractions including particulate organic carbon (POC), readily oxidized organic carbon (ROC), dissolved organic carbon (DOC), microbial biomass carbon (MBC) in the 0-30 cm soil layer under seven different biological regulated measures were studied by the field investigation combined with the laboratory analysis. Results showed that the content of the SOC and active organic carbon fractions decreased with the increasing soil depth; the content of the SOC and active organic carbon fractions in 0-10 cm was significantly higher than that in 20-30 cm. The stability of soil aggregates were also significantly influenced by biological regulated measures, the content of > 0.25 mm water-stable aggregates in seven types of biological regulated measures was in the order of Koelreuteria bipinnata + Cassia suffruticasa > hedgerows > closed forest > natural restoration > economic forest > traditional planting > control plot, moreover, the content of 0.25 mm water-stable aggregates correlated positively with the content of SOC. Soils under different biological regulated measures all demonstrated fractal features, and soil under the measure of Koelreuteria bipinnata + Cassia suffruticasa was found to have the lowest value of fractal dimension and soil erodiable K, indicating a relatively strong structure stability and erosion-resistant capacity. Negative correlation was observed when compared the content of active organic carbon fractions with the soil erodiable K. It can be concluded that properties of soil can be managed through biological regulated measures; thence had an influence on the soil erosion-resistant capacity.

  1. [Diffusion flux of partial pressure of dissolved carbon dioxide in Wan'an reservoir in spring].

    PubMed

    Mei, Hang-Yuan; Wang, Fu-Shun; Yao, Chen-Chen; Wang, Bao-Li

    2011-01-01

    In order to understand the emission of greenhouse gases (CO2) from the river-type reservoir, this study investigated the partial pressure of CO2 [p(CO2)], in the surface water, inflow waters, outflow waters of the Wan'an reservoir in China in the May 2009. p(CO2) in the inflow water, outflow water were calculated from titration method, and the surface water p(CO2) was measured underway using a continuous measurement system (equilibrator-NDIR system). Results showed that the inflow water from the Zhangshui, Meijiang, Taojiang have higher p(CO2) than atmosphere level, with the values of 211.5, 91.7, 259.7 Pa respectively. p(CO2) in the surface water of the incoming section of Wan'an reservoir was between 180-210 Pa, and in the middle section and central section near the dam, p(CO2) in the surface water were about 140-180 Pa and 70-110 Pa. In the outflow waters, p(CO2) reached to 176.2 Pa, higher than that in central section. As a result, it can be concluded that the surface water, inflow waters, outflow waters in the Wan'an reservoir are all the source to CO2. However there is clear evidence showing that the reservoir indeed has a role in mitigating the CO2 emission in this case.

  2. 3-D seismic evidence of the effects of carbonate karst collapse on overlying clastic stratigraphy and reservoir compartmentalization

    SciTech Connect

    Hardage, B.A.; Carr, D.L.; Simmons, J.L. Jr.; Jons, R.A.; Lancaster, D.E.; Elphick, R.Y.; Pendleton, V.M.

    1996-09-01

    A multidisciplinary team, composed of stratigraphers, petrophysicists, reservoir engineers, and geophysicists, studied a portion of Boonsville gas field in the Fort Worth Basin of north-central Texas to determine how modern techniques can be combined to understand the mechanisms by which fluvio-deltaic depositional processes create reservoir compartmentalization in a low- to moderate-accommodation basin. An extensive database involving well logs, cores, production, and pressure data from more than 200 wells, 26 mi{sup 2} of 3-D seismic data, vertical seismic profiles, and checkshots was assembled to support this investigation. The authors found the most important geologic influence on stratigraphy and reservoir compartmentalization in this basin to be the existence of numerous karst collapse chimneys over the area covered. These near-vertical karst collapses originated in, or near, the deep Ordovician-age Ellenburger carbonate section and created vertical chimneys extending as high as 2,500 ft above their point of origin, causing significant disruptions in the overlying clastic strata.

  3. Keys to evaluating [open quotes]paleokarst[close quotes] reservoirs - guidelines from Quaternary carbonates and enhanced petrography

    SciTech Connect

    Dravis, J.J. )

    1996-01-01

    Paleokarst is often invoked to explain reservoir development in ancient brecciated carbonates. However, the paleokarst model is valid only when fabrics seen in Quaternary cave systems are present and petrography of the non-brecciated zones supports subaerial exposure. Quaternary caves typically exhibit early fractures, microscopic to cavernous secondary porosity, solution collapse and brecciation, cave cements, and reddish-brown cave fill. Inter-cavern rocks show fabric-selective dissolution, porosity inversion, precompaction cements, and capping laminated soil crusts. In brecciated Ellenburger and Upper Elk Point (Devonian, W. Canada) reservoirs, major discrepancies exist between what the paleokarst model predicts and what is actually observed. Reddish calcretes, cavernous porosity and cave cements are absent. Enhanced petrography reveals relict sutured grains, implying burial dolomitization. These same dolomites are brecciated and breccia clasts contain stylolites rotated at different angles to each other and the horizon, implying burial brecciation. Fractures cutting these burial dolomites and stylolites are burial in origin. Preserved secondary porosity is unrelated to brecciated zones and facies controlled. Therefore, brecciation and reservoir quality in both sequences were created by burial dissolution of replacement dolomites and not by subaerial karstification. Brecciation alone does not prove the unconformity-related paleokarst model or the timing of porosity development.

  4. Keys to evaluating {open_quotes}paleokarst{close_quotes} reservoirs - guidelines from Quaternary carbonates and enhanced petrography

    SciTech Connect

    Dravis, J.J.

    1996-12-31

    Paleokarst is often invoked to explain reservoir development in ancient brecciated carbonates. However, the paleokarst model is valid only when fabrics seen in Quaternary cave systems are present and petrography of the non-brecciated zones supports subaerial exposure. Quaternary caves typically exhibit early fractures, microscopic to cavernous secondary porosity, solution collapse and brecciation, cave cements, and reddish-brown cave fill. Inter-cavern rocks show fabric-selective dissolution, porosity inversion, precompaction cements, and capping laminated soil crusts. In brecciated Ellenburger and Upper Elk Point (Devonian, W. Canada) reservoirs, major discrepancies exist between what the paleokarst model predicts and what is actually observed. Reddish calcretes, cavernous porosity and cave cements are absent. Enhanced petrography reveals relict sutured grains, implying burial dolomitization. These same dolomites are brecciated and breccia clasts contain stylolites rotated at different angles to each other and the horizon, implying burial brecciation. Fractures cutting these burial dolomites and stylolites are burial in origin. Preserved secondary porosity is unrelated to brecciated zones and facies controlled. Therefore, brecciation and reservoir quality in both sequences were created by burial dissolution of replacement dolomites and not by subaerial karstification. Brecciation alone does not prove the unconformity-related paleokarst model or the timing of porosity development.

  5. Geoscience/Engineering Characterization of the Interwell Environment in Carbonate Reservoirs Based on Outcrop Analogs, Permian Basin, West Texas and New Mexico.

    SciTech Connect

    Lucia, Jerry F.; Kerans, Charles

    1997-05-29

    The objective of this project is to investigate styles of reservoir heterogeneity found in low permeability pelleted wackestone/packstone facies and mixed carbonate/clastic facies found in Permian Basin reservoirs by studying similar facies exposed in the Guadalupe Mountains. Specific objectives for the outcrop study include construction of a stratigraphic framework, petrophysical quantification of the framework, and testing the outcrop reservoir model for effects of reservoir heterogeneity on production performance. Specific objectives for the subsurface study parallel objectives for the outcrop study. Subsurface Activities - We continue to prepare two final reports that summarize research results of the South Cowden Field study. One report summarizes results of the petrophysical characterization research, and one summarizes results of the fluid-flow modeling research. Outcrop Activities - We also continue to prepare the final report, which summarizes the research results of the Grayburg outcrop reservoir study.

  6. Geoscience/Engineering Characterization of the Interwell Environment in Carbonate Reservoirs Based on Outcrop Analogs, Permian Basin, West Texas and New Mexico.

    SciTech Connect

    Lucia, Jerry F.; Kerans, Charles

    1997-05-19

    The objective of this project is to investigate styles of reservoir heterogeneity found in low permeability pelleted wackestone/packstone facies and mixed carbonate/clastic facies found in Permian Basin reservoirs by studying similar facies exposed in the Guadalupe Mountains. Specific objectives for the outcrop study include construction of a stratigraphic framework, petrophysical quantification of the framework, and testing the outcrop reservoir model for effects of reservoir heterogeneity on production performance. Specific objectives for the subsurface study parallel objectives for the outcrop study. Subsurface Activities - We continue to prepare two final reports that summarize research results of the South Cowden Field study. One report summarizes results of the petrophysical characterization research, and one summarizes results of the fluid-flow modeling research. Outcrop Activities - We also continue to prepare the final report, which summarizes the research results of the Grayburg outcrop reservoir study.

  7. Improved oil recovery in Mississippian carbonate reservoirs of Kansas: Near term, Class 2. [Annual report], September 18, 1994--October 1, 1995. Draft.

    SciTech Connect

    Carr, T.R.; Green, D.W.; Willhite, G.P.

    1996-01-01

    This report represents a summary of the progress during the first year of Budget period 1 of the near term Class 2 project entitled ``Improved Oil Recovery in Mississippian Carbonate Reservoirs of Kansas``. Two examples of advanced technologies developed as part of this project are highlighted along with the use of the Internet to transfer these technologies. The two advanced technologies are a spread-sheet petrophysical analysis and reservoir evaluation (PfEFFER), and a petrophysical/seismic approach to well logs (pseudoseismic). Work continues on multi-disciplinary reservoir characterization at the demonstration site. The potential for incremental primary recovery is being evaluated using the improved reservoir characterization to target infill drilling and evaluate the potential of a horizontal well. The impact of successful incremental primary recovery from sub-Pennsylvanian unconformity Mississippian reservoirs such as are present at the Schaben demonstration site would be significant for Kansas and the US.

  8. Dry Stream Reaches in Carbonate Terranes: Surface Indicators of Ground-Water Reservoirs

    USGS Publications Warehouse

    Brahana, J.V.; Hollyday, E.F.

    1988-01-01

    In areas where dry stream reaches occur, subsurface drainage successfully competes with surface drainage, and sheet-like dissolution openings have developed parallel to bedding creating the ground-water reservoir. Union Hollow in south-central Tennessee is the setting for a case study that illustrates the application of the dry stream reach technique. In this technique, dry stream reach identification is based on two types of readily acquired information: remotely sensed black and white infrared aerial photography; and surface reconnaissance of stream channel characteristics. Test drilling in Union Hollow subsequent to identification of the dry reach proved that a localized ground-water reservoir was present.

  9. MULTIDISCIPLINARY IMAGING OF ROCK PROPERTIES IN CARBONATE RESERVOIRS FOR FLOW-UNIT TARGETING

    SciTech Connect

    Stephen C. Ruppel

    2003-07-01

    Excellent progress continues to be made on most objectives and goals. Primary focus during the past 6 months has been (1) simulation of reservoir performance using the reservoir model constructed for the Phase 1 study area, (2) extension of core and log characterization activities to the Phase 2 study area, (3) development of an initial velocity-based inversion model from the 3-D seismic volume for porosity characterization, (4) continuation of quality-control analysis of wireline logs. Preliminary results of the study were presented at a technology-transfer workshop in May 2003 in Midland/Odessa Texas.

  10. CO{sub 2} Huff-n-Puff process in a light oil shallow shelf carbonate reservoir. 1994 Annual report

    SciTech Connect

    Wehner, S.C.

    1995-05-01

    It is anticipated that this project will show that the application of the CO{sub 2} Huff-n-Puff process in shallow shelf carbonates can be economically implemented to recover appreciable volumes of light oil. The goals of the project are the development of guidelines for cost-effective selection of candidate reservoirs and wells, along with estimating recovery potential. The selected site for the demonstration project is the Central Vacuum Unit waterflood in Lea County, New Mexico. Work is nearing completion on the reservoir characterization components of the project. The near-term emphasis is to, (1) provide an accurate distribution of original oil-in-place on a waterflood pattern entity level, (2) evaluate past recovery efficiencies, (3) perform parametric simulations, and (4) forecast performance for a site specific field demonstration of the proposed technology. Macro zonation now exists throughout the study area and cross-sections are available. The Oil-Water Contact has been defined. Laboratory capillary pressure data was used to define the initial water saturations within the pay horizon. The reservoir`s porosity distribution has been enhanced with the assistance of geostatistical software. Three-Dimensional kriging created the spatial distributions of porosity at interwell locations. Artificial intelligence software was utilized to relate core permeability to core porosity, which in turn was applied to the 3-D geostatistical porosity gridding. An Equation-of-State has been developed and refined for upcoming compositional simulation exercises. Options for local grid-refinement in the model are under consideration. These tasks will be completed by mid-1995, prior to initiating the field demonstrations in the second budget period.

  11. Impact of a large tropical reservoir on riverine transport of sediment, carbon, and nutrients to downstream wetlands

    NASA Astrophysics Data System (ADS)

    Kunz, Manuel J.; Wüest, Alfred; Wehrli, Bernhard; Landert, Jan; Senn, David B.

    2011-12-01

    Large dams can have major ecological and biogeochemical impacts on downstream ecosystems such as wetlands and riparian habitats. We examined sediment removal and carbon (C), nitrogen (N), and phosphorus (P) cycling in Itezhi-Tezhi Reservoir (ITT; area = 364 km2, hydraulic residence time = 0.7 yr), which is located directly upstream of a high ecological value floodplain ecosystem (Kafue Flats) in the Zambezi River Basin. Field investigations (sediment cores, sediment traps, water column samples), mass balance estimates, and a numerical biogeochemical reservoir model were combined to estimate N, P, C, and sediment removal, organic C mineralization, primary production, and N fixation. Since dam completion in 1978, 330 × 103 tons (t) of sediment and 16 × 103, 1.5 × 103, 200 t of C, N, and P, respectively, have accumulated annually in ITT sediments. Approximately 50% of N inputs and 60% of P inputs are removed by the reservoir, illustrating its potential in decreasing nutrients to the downstream Kafue Flats floodplain. The biogeochemical model predicted substantial primary production in ITT (˜280 g C m-2 yr-1), and significant N-fixation (˜30% for the total primary production) was required to support primary production due to marginal inputs of inorganic N. Model simulations indicate that future hydropower development in the reservoir, involving the installation of turbines driven by hypolimnetic water, will likely result in the delivery of low-oxygen waters to downstream ecosystems and increased outputs of dissolved inorganic N and P by a factor of ˜4 and ˜2 compared to current dam management, respectively.

  12. Carboniferous and older carbonate rocks: Lithofacies, extent, and reservoir quality: Chapter CC in The oil and gas resource potential of the Arctic National Wildlife Refuge 1002 area, Alaska

    USGS Publications Warehouse

    Dumoulin, Julie A.

    1999-01-01

    Carboniferous and older carbonate rocks are potential hydrocarbon reservoir facies for four plays in the 1002 area of the Arctic National Wildlife Refuge. These rocks include several units in the pre-Carboniferous basement and the Carboniferous Lisburne Group. Data from exploratory wells west of the 1002 area, outcrops south of the 1002 area, seismic lines, and well logs are synthesized herein to infer carbonate lithofacies, extent, and reservoir character beneath the northeastern Arctic coastal plain.A chiefly shallow-water basement carbonate succession of Late Proterozoic through Early Devonian age (Katakturuk Dolomite, Nanook Limestone, and Mount Copleston Limestone) is interpreted to be present beneath much of the south-central 1002 area; it reaches 3,700 m thick in outcrop and is the primary reservoir for the Deformed Franklinian Play. A more heterogeneous lithologic assemblage of uncertain age forms basement in the northwestern part of the 1002 area; well data define three subunits that contain carbonate intervals 5- 50 m thick. These strata are prospective reservoirs for the Undeformed Franklinian Play and could also be reservoirs for the Niguanak- Aurora Play. Regional lithologic correlations suggest a Cambrian-Late Proterozoic(?) age for subunits one and two, and a slightly younger, later Cambrian-Silurian age for subunit three. Seismic and well data indicate that subunit one overlies subunit two and is overlain by subunit three. The Mississippian and Pennsylvanian Lisburne Group, a predominantly carbonate platform succession as much as 1 km thick, is projected beneath the southernmost part of the 1002 area and is a potential reservoir for the Ellesmerian Thrust-belt and Niguanak-Aurora Plays.Carbonate rocks in the 1002 area probably retain little primary porosity but may have locally well developed secondary porosity. Measured reservoir parameters in basement carbonate strata are low (porosity generally ≤ 5%; permeability ≤ 0.2 md) but drill

  13. Response surfaces for CO2 leakage from geologic storage along abandoned wellbores

    NASA Astrophysics Data System (ADS)

    Jordan, A.; Carey, J. W.; Pawar, R. J.; Stauffer, P. H.

    2011-12-01

    The storage of carbon dioxide (CO2) in geologic reservoirs that have previously been drilled for oil and gas exploration is under investigation worldwide as an option for reducing the amount of anthropogenic carbon introduced to the atmosphere. Reservoirs that have already been tapped for hydrocarbon production have several benefits over development of new sites: they tend to be geologically well-understood, with existing wellbore data to help further characterize the local geologic framework; are known to be conducive to trapping buoyant or pressurized fluids; may have infrastructure in place; and are likely to be already impacted ecologically as compared to pristine sites. One downside to using depleted hydrocarbon reservoirs is the potential for CO2 leakage along pre-existing wellbores that were either not designed for CO2 sequestration or have been improperly plugged and abandoned. The primary goal of this study is to develop estimates of possible wellbore leakage rates of CO2 from storage reservoirs to the surface and/or into overlaying aquifers, as a function of wellbore properties and the surrounding geologic framework. The Finite Element Heat and Mass transfer code (FEHM) was used to perform Monte Carlo simulations of multiphase flow along wellbores across a wide range of geologic and wellbore parameters. Several wellbore scenarios were studied, including a simple wellbore between the CO2 storage reservoir and the surface; a wellbore intersecting a saline aquifer ("thief zone"); and a wellbore intersecting both a thief zone and a freshwater aquifer. The Problem Solving environment for Uncertainty Analysis and Design Exploration (PSUADE) software was used to analyze results and produce response surfaces for the estimation of wellbore flow rate as a function of the primary factors that influence leakage. These results will be used to develop abstractions for leakage rates to be incorporated in performance assessments of geologic CO2 storage, which will help

  14. Impact of stylolitization on diagenesis of a Lower Cretaceous carbonate reservoir from a giant oilfield, Abu Dhabi, United Arab Emirates

    NASA Astrophysics Data System (ADS)

    Paganoni, Matteo; Al Harthi, Amena; Morad, Daniel; Morad, Sadoon; Ceriani, Andrea; Mansurbeg, Howri; Al Suwaidi, Aisha; Al-Aasm, Ihsan S.; Ehrenberg, Stephen N.; Sirat, Manhal

    2016-04-01

    Bed-parallel stylolites are a widespread diagenetic feature in Lower Cretaceous limestone reservoirs, Abu Dhabi, United Arab Emirates (UAE). Diagenetic calcite, dolomite, kaolin and small amounts of pyrite, fluorite, anhydrite and sphalerite occur along and in the vicinity of the stylolites. Petrographic observations, negative δ18OVPDB, fluid inclusion microthermometry, and enrichment in 87Sr suggest that these cements have precipitated from hot basinal brines, which migrated along the stylolites and genetically related microfractures (tension gashes). Fluid migration was presumably related to lateral tectonic compression events related to the foreland basin formation. The low solubility of Al3 + in formation waters suggests that kaolin precipitation was linked to derivation of organic acids during organic matter maturation, probably in siliciclastic source rocks. The mass released from stylolitization was presumably re-precipitated as macro- and microcrystalline calcite cement in the host limestones. The flanks of the oilfield (water zone) display more frequent presence and higher amplitude of stylolites, lower porosity and permeability, higher homogenization temperatures and more radiogenic composition of carbonates compared to the crest (oil zone). This indicates that oil emplacement retards diagenesis. This study demonstrates that stylolitization plays a crucial role in fluid flow and diagenesis of carbonate reservoirs during basin evolution.

  15. Establishment of an oil and gas database for increased recovery and characterization of oil and gas carbonate reservoir heterogeneity. [Jurassic Smackover Formation

    SciTech Connect

    Mancini, E.A.

    1990-01-01

    The objective of this project is to augment the National Reservoir Database (TORIS database), to increase our understanding of geologic heterogeneities that affect the recoveries of oil and gas from carbonate reservoirs in the State of Alabama, and to identify resources that are producible at moderate cost. This objective will be achieved through detailed geological, geostatistical, and engineering characterization of typical Jurassic Smackover Formation hydrocarbon, and engineering characterization of typical Jurassic Smackover Formation hydrocarbon reservoirs in selected productive fields in the state of Alabama. The results of these studies will be used to develop and test mathematical models for prediction of the effects of reservoir heterogeneities in hydrocarbon production. Work to date has focused on completion of Subtasks 1, 2, and 3 of this project. Work on Subtask 4 began in this quarter, and substantial additional work has been accomplished on Subtask 2. Subtask 1 included the survey and tabulation of available reservoir engineering and geological data. Subtask 2 comprises the geologic and engineering characterization of smackover reservoir lithofacies. Subtask 3 includes the geologic modeling of reservoir heterogeneities. Subtask 4 includes the development of reservoir exploitation methodologies for strategic infill drilling. 1 fig.

  16. The Carbon in Arctic Reservoirs Vulnerability Experiment (CARVE): Examining the complex Arctic biological-climatologic-hydrologic system

    NASA Astrophysics Data System (ADS)

    McDonald, K. C.; Podest, E.; Miller, C. E.; Dinardo, S. J.

    2012-12-01

    Fundamental aspects of the complex Arctic biological-climatologic-hydrologic system remain poorly quantified. As a result, significant uncertainties exist in the carbon budget of the Arctic ecosystem. NASA's Carbon in Arctic Reservoirs Vulnerability Experiment (CARVE) is a currently-operational Earth Venture 1 (EV-1) mission that is examining correlations between atmospheric and surface state variables for the Alaskan terrestrial ecosystems. CARVE is conducted through a series of intensive seasonal aircraft campaigns, ground-based observations, and analysis sustained over a 5-year mission timeframe. CARVE employs a C-23 Sherpa aircraft to fly an innovative airborne remote sensing payload. This payload includes an L-band radiometer/radar system and a nadir-viewing spectrometer to deliver simultaneous measurements of land surface state variables that control gas emissions (i.e., soil moisture and inundation, freeze/thaw state, surface temperature) and total atmospheric columns of carbon dioxide, methane, and carbon monoxide. The aircraft payload also includes a gas analyzer that links greenhouse gas measurements directly to World Meteorological Organization standards and provide vertical profile information. CARVE measurement campaigns are scheduled regularly throughout the growing season each year to capture the seasonal variability in Arctic system carbon fluxes associated with the spring thaw, the summer drawdown, and the fall refreeze. Continuous ground-based measurements provide temporal and regional context as well as calibration for CARVE airborne measurements. CARVE bridges critical gaps in our knowledge and understanding of Arctic ecosystems, linkages between the Arctic hydrologic and terrestrial carbon cycles, and the feedbacks from fires and thawing permafrost. Ultimately, CARVE will provide an integrated set of data that will provide unprecedented experimental insights into Arctic carbon cycling. Portions of this work were carried out at the Jet

  17. Quantifying Sources and Fluxes of Aquatic Carbon in U.S. Streams and Reservoirs Using Spatially Referenced Regression Models

    NASA Astrophysics Data System (ADS)

    Boyer, E. W.; Smith, R. A.; Alexander, R. B.; Schwarz, G. E.

    2004-12-01

    Organic carbon (OC) is a critical water quality characteristic in riverine systems that is an important component of the aquatic carbon cycle and energy balance. Examples of processes controlled by OC interactions are complexation of trace metals; enhancement of the solubility of hydrophobic organic contaminants; formation of trihalomethanes in drinking water; and absorption of visible and UV radiation. Organic carbon also can have indirect effects on water quality by influencing internal processes of aquatic ecosystems (e.g. photosynthesis and autotrophic and heterotrophic activity). The importance of organic matter dynamics on water quality has been recognized, but challenges remain in quantitatively addressing OC processes over broad spatial scales in a hydrological context. In this study, we apply spatially referenced watershed models (SPARROW) to statistically estimate long-term mean-annual rates of dissolved- and total- organic carbon export in streams and reservoirs across the conterminous United States. We make use of a GIS framework for the analysis, describing sources, transport, and transformations of organic matter from spatial databases providing characterizations of climate, land use, primary productivity, topography, soils, and geology. This approach is useful because it illustrates spatial patterns of organic carbon fluxes in streamflow, highlighting hot spots (e.g., organic-rich environments in the southeastern coastal plain). Further, our simulations provide estimates of the relative contributions to streams from allochthonous and autochthonous sources. We quantify surface water fluxes of OC with estimates of uncertainty in relation to the overall US carbon budget; our simulations highlight that aquatic sources and sinks of OC may be a more significant component of regional carbon cycling than was previously thought. Further, we are using our simulations to explore the potential role of climate and other changes in the terrestrial environment on

  18. Strontium isotope quantification of siderite, brine and acid mine drainage contributions to abandoned gas well discharges in the Appalachian Plateau

    SciTech Connect

    Chapman, Elizabeth C.; Capo, Rosemary C.; Stewart, Brian W.; Hedin, Robert S.; Weaver, Theodore J.; Edenborn, Harry M.

    2013-04-01

    Unplugged abandoned oil and gas wells in the Appalachian region can serve as conduits for the movement of waters impacted by fossil fuel extraction. Strontium isotope and geochemical analysis indicate that artesian discharges of water with high total dissolved solids (TDS) from a series of gas wells in western Pennsylvania result from the infiltration of acidic, low Fe (Fe < 10 mg/L) coal mine drainage (AMD) into shallow, siderite (iron carbonate)-cemented sandstone aquifers. The acidity from the AMD promotes dissolution of the carbonate, and metal- and sulfate-contaminated waters rise to the surface through compromised abandoned gas well casings. Strontium isotope mixing models suggest that neither upward migration of oil and gas brines from Devonian reservoirs associated with the wells nor dissolution of abundant nodular siderite present in the mine spoil through which recharge water percolates contribute significantly to the artesian gas well discharges. Natural Sr isotope composition can be a sensitive tool in the characterization of complex groundwater interactions and can be used to distinguish between inputs from deep and shallow contamination sources, as well as between groundwater and mineralogically similar but stratigraphically distinct rock units. This is of particular relevance to regions such as the Appalachian Basin, where a legacy of coal, oil and gas exploration is coupled with ongoing and future natural gas drilling into deep reservoirs.

  19. Heavy oil reservoirs recoverable by thermal technology. Annual report

    SciTech Connect

    Kujawa, P.

    1981-02-01

    The purpose of this study was to compile data on reservoirs that contain heavy oil in the 8 to 25/sup 0/ API gravity range, contain at least ten million barrels of oil currently in place, and are non-carbonate in lithology. The reservoirs within these constraints were then analyzed in light of applicable recovery technology, either steam-drive or in situ combustion, and then ranked hierarchically as candidate reservoirs. The study is presented in three volumes. Volume I presents the project background and approach, the screening analysis, ranking criteria, and listing of candidate reservoirs. The economic and environmental aspects of heavy oil recovery are included in appendices to this volume. This study provides an extensive basis for heavy oil development, but should be extended to include carbonate reservoirs and tar sands. It is imperative to look at heavy oil reservoirs and projects on an individual basis; it was discovered that operators, and industrial and government analysts will lump heavy oil reservoirs as poor producers, however, it was found that upon detailed analysis, a large number, so categorized, were producing very well. A study also should be conducted on abandoned reservoirs. To utilize heavy oil, refiners will have to add various unit operations to their processes, such as hydrotreaters and hydrodesulfurizers and will require, in most cases, a lighter blending stock. A big problem in producing heavy oil is that of regulation; specifically, it was found that the regulatory constraints are so fluid and changing that one cannot settle on a favorable recovery and production plan with enough confidence in the regulatory requirements to commit capital to the project.

  20. Uncovering the Minor Contribution of Land-Cover Change in Upland Forests to the Net Carbon Footprint of a Boreal Hydroelectric Reservoir.

    PubMed

    Dessureault, Pierre-Luc; Boucher, Jean-François; Tremblay, Pascal; Bouchard, Sylvie; Villeneuve, Claude

    2015-07-01

    Hydropower in boreal conditions is generally considered the energy source emitting the least greenhouse gas per kilowatt-hour during its life cycle. The purpose of this study was to assess the relative contribution of the land-use change on the modification of the carbon sinks and sources following the flooding of upland forested territories to create the Eastmain-1 hydroelectric reservoir in Quebec's boreal forest using Carbon Budget Model of the Canadian Forest Sector. Results suggest a carbon sink loss after 100 yr of 300,000 ± 100,000 Mg CO equivalents (COe). A wildfire sensitivity analysis revealed that the ecosystem would have acted as a carbon sink as long as <75% of the territory had burned over the 100-yr-long period. Our long-term net carbon flux estimate resulted in emissions of 4 ± 2 g COe kWh as a contribution to the carbon footprint calculation, one-eighth what was obtained in a recent study that used less precise and less sensitive estimates. Consequently, this study significantly reduces the reported net carbon footprint of this reservoir and reveals how negligible the relative contribution of the land-use change in upland forests to the total net carbon footprint of a hydroelectric reservoir in the boreal zone can be.

  1. Water-quality assessment of Francis E Walter reservoir, Luzerne and Carbon counties, Pennsylvania

    USGS Publications Warehouse

    Barker, J.L.

    1983-01-01

    Water-quality data, both past and present, show that the waters of the upper Lehigh River basin are somewhat acidic, but otherwise are generally of good quality. This report contains a summary of all known water-quality data collected by the U.S. Geological Survey and other agencies, as well as a synopsis of current water-quality conditions in the reservoir and its tributaries. Water-quality data collected from June 1981 to May 1982 indicate that raising the pool level from 1,300 to approximately 1,392 feet above sea level (NGVD of 1929) has had some significant, if only temporary, detrimental impacts on the reservoir system and its discharge. Depth profile measurements show that, while the impoindment was thermally stratified for only about 2 weeks, the dissolved oxygen concentrations were depressed to levels critical to fishlife throughout much of the reservoir. Another effect of the raised pool was the lowering of pH in the impoinded water. Median pH values were less than 6.0 throughout the reservoir, whereas they commonly exceeded 6.5 at the normal pool elevation. Tests for fecal coliform and fecal streptococcus indicate the impoinded water is nearly free of enteric bacteria. Algal analyses and nutrient concentrations support the premise that the impoundment is nutrient poor and phosphorus limited. Raising the water level an additional 125 feet should have no permanent detrimental effect upon water quality and will greatly increase available habitat for fish and waterflow. Increased retention time should not alter the current trophic status and may decrease the concentration of available nutrients.

  2. Laboratory measurements of large-scale carbon sequestration flows in saline reservoirs

    SciTech Connect

    Backhaus, Scott N

    2010-01-01

    Brine saturated with CO{sub 2} is slightly denser than the original brine causing it to sink to the bottom of a saline reservoir where the CO{sub 2} is safely sequestered. However, the buoyancy of pure CO{sub 2} relative to brine drives it to the top of the reservoir where it collects underneath the cap rock as a separate phase of supercritical fluid. Without additional processes to mix the brine and CO{sub 2}, diffusion in this geometry is slow and would require an unacceptably long time to consume the pure CO{sub 2}. However, gravity and diffusion-driven convective instabilities have been hypothesized that generate enhanced CO{sub 2}-brine mixing promoting dissolution of CO{sub 2} into the brine on time scale of a hundred years. These flows involve a class of hydrodynamic problems that are notoriously difficult to simulate; the simultaneous flow of mUltiple fluids (CO{sub 2} and brine) in porous media (rock or sediment). The hope for direct experimental confirmation of simulations is dim due to the difficulty of obtaining high resolution data from the subsurface and the high pressures ({approx}100 bar), long length scales ({approx}100 meters), and long time scales ({approx}100 years) that are characteristic of these flows. We have performed imaging and mass transfer measurements in similitude-scaled laboratory experiments that provide benchmarks to test reservoir simulation codes and enhance their predictive power.

  3. Dolomite reservoirs: Porosity evolution and reservoir characteristics

    SciTech Connect

    Sun, S.Q.

    1995-02-01

    Systematic analyses of the published record of dolomite reservoirs worldwide reveal that the majority of hydrocarbon-producing dolomite reservoirs occurs in (1) peritidal-dominated carbonate, (2) subtidal carbonate associated with evaporitic tidal flat/lagoon, (3) subtidal carbonate associated with basinal evaporite, and (4) nonevaporitic carbonate sequence associated with topographic high/unconformity, platform-margin buildup or fault/fracture. Reservoir characteristics vary greatly from one dolomite type to another depending upon the original sediment fabric, the mechanism by which dolomite was formed, and the extent to which early formed dolomite was modified by post-dolomitization diagenetic processes (e.g., karstification, fracturing, and burial corrosion). This paper discusses the origin of dolomite porosity and demonstrates the porosity evolution and reservoir characteristics of different dolomite types.

  4. An Evaluation of the Carbon Sequestration Potential of the Cambro-Ordovician Strata of the Illinois and Michigan Basins. Part 1. Evaluation of Phase 2 CO2 Injection Testing in the Deep Saline Gunter Sandstone Reservoir (Cambro-Ordovician Knox Group), Marvin Blan No. 1 Hancock County, Kentucky Part 2. Time-lapse Three-Dimensional Vertical Seismic Profile (3D-VSP) of Sequestration Target Interval with Injected Fluids

    SciTech Connect

    Bowersox, Richard; Hickman, John; Leetaru, Hannes

    2012-12-20

    Part 1 of this report focuses on results of the western Kentucky carbon storage test, and provides a basis for evaluating injection and storage of supercritical CO2 in Cambro-Ordovician carbonate reservoirs throughout the U.S. Midcontinent. This test demonstrated that the Cambro- Ordovician Knox Group, including the Beekmantown Dolomite, Gunter Sandstone, and Copper Ridge Dolomite in stratigraphic succession from shallowest to deepest, had reservoir properties suitable for supercritical CO2 storage in a deep saline reservoir hosted in carbonate rocks, and that strata with properties sufficient for long-term confinement of supercritical CO2 were present in the deep subsurface. Injection testing with brine and CO2 was completed in two phases. The first phase, a joint project by the Kentucky Geological Survey and the Western Kentucky Carbon Storage Foundation, drilled the Marvin Blan No. 1 carbon storage research well and tested the entire Knox Group section in the open borehole – including the Beekmantown Dolomite, Gunter Sandstone, and Copper Ridge Dolomite – at 1152–2255 m, below casing cemented at 1116 m. During Phase 1 injection testing, most of the 297 tonnes of supercritical CO2 was displaced into porous and permeable sections of the lowermost Beekmantown below 1463 m and Gunter. The wellbore was then temporarily abandoned with a retrievable bridge plug in casing at 1105 m and two downhole pressure-temperature monitoring gauges below the bridge plug pending subsequent testing. Pressure and temperature data were recorded every minute for slightly more than a year, providing a unique record of subsurface reservoir conditions in the Knox. In contrast, Phase 2 testing, this study, tested a mechanically-isolated dolomitic-sandstone interval in the Gunter.

  5. Elevated carbon dioxide flux at the Dixie Valley geothermal field, Nevada; relations between surface phenomena and the geothermal reservoir

    USGS Publications Warehouse

    Bergfeld, D.; Goff, F.; Janik, C.J.

    2001-01-01

    In the later part of the 1990s, a large die-off of desert shrubs occurred over an approximately 1 km2 area in the northwestern section of the Dixie Valley (DV) geothermal field. This paper reports results from accumulation-chamber measurements of soil CO2 flux from locations in the dead zone and stable isotope and chemical data on fluids from fumaroles, shallow wells, and geothermal production wells within and adjacent to the dead zone. A cumulative probability plot shows three types of flux sites within the dead zone: Locations with a normal background CO2 flux (7 g m-2 day-1); moderate flux sites displaying "excess" geothermal flux; and high flux sites near young vents and fumaroles. A maximum CO2 flux of 570 g m-2 day-1 was measured at a location adjacent to a fumarole. Using statistical methods appropriate for lognormally distributed populations of data, estimates of the geothermal flux range from 7.5 t day-1 from a 0.14-km2 site near the Stillwater Fault to 0.1 t day-1 from a 0.01 -km2 location of steaming ground on the valley floor. Anomalous CO2 flux is positively correlated with shallow temperature anomalies. The anomalous flux associated with the entire dead zone area declined about 35% over a 6-month period. The decline was most notable at a hot zone located on an alluvial fan and in the SG located on the valley floor. Gas geochemistry indicates that older established fumaroles along the Stillwater Fault and a 2-year-old vent in the lower section of the dead zone discharge a mixture of geothermal gases and air or gases from air-saturated meteoric water (ASMW). Stable isotope data indicate that steam from the smaller fumaroles is produced by ??? 100??C boiling of these mixed fluids and reservoir fluid. Steam from the Senator fumarole (SF) and from shallow wells penetrating the dead zone are probably derived by 140??C to 160??C boiling of reservoir fluid. Carbon-13 isotope data suggest that the reservoir CO2 is produced mainly by thermal decarbonation of

  6. INTEGRATED GEOLOGIC-ENGINEERING MODEL FOR REEF AND CARBONATE SHOAL RESERVOIRS ASSOCIATED WITH PALEOHIGHS: UPPER JURASSIC SMACKOVER FORMATION, NORTHEASTERN GULF OF MEXICO

    SciTech Connect

    Ernest A. Mancini

    2003-09-25

    The University of Alabama in cooperation with Texas A&M University, McGill University, Longleaf Energy Group, Strago Petroleum Corporation, and Paramount Petroleum Company are undertaking an integrated, interdisciplinary geoscientific and engineering research project. The project is designed to characterize and model reservoir architecture, pore systems and rock-fluid interactions at the pore to field scale in Upper Jurassic Smackover reef and carbonate shoal reservoirs associated with varying degrees of relief on pre-Mesozoic basement paleohighs in the northeastern Gulf of Mexico. The project effort includes the prediction of fluid flow in carbonate reservoirs through reservoir simulation modeling that utilizes geologic reservoir characterization and modeling and the prediction of carbonate reservoir architecture, heterogeneity and quality through seismic imaging. The primary objective of the project is to increase the profitability, producibility and efficiency of recovery of oil from existing and undiscovered Upper Jurassic fields characterized by reef and carbonate shoals associated with pre-Mesozoic basement paleohighs. The principal research effort for Year 3 of the project has been reservoir characterization, 3-D modeling, testing of the geologic-engineering model, and technology transfer. This effort has included six tasks: (1) the study of seismic attributes, (2) petrophysical characterization, (3) data integration, (4) the building of the geologic-engineering model, (5) the testing of the geologic-engineering model and (6) technology transfer. This work was scheduled for completion in Year 3. Progress on the project is as follows: geoscientific reservoir characterization is completed. The architecture, porosity types and heterogeneity of the reef and shoal reservoirs at Appleton and Vocation Fields have been characterized using geological and geophysical data. The study of rock-fluid interactions has been completed. Observations regarding the diagenetic

  7. LOSCAR: Long-term Ocean-atmosphere-Sediment CArbon cycle Reservoir Model

    NASA Astrophysics Data System (ADS)

    Zeebe, R. E.

    2011-06-01

    The LOSCAR model is designed to efficiently compute the partitioning of carbon between ocean, atmosphere, and sediments on time scales ranging from centuries to millions of years. While a variety of computationally inexpensive carbon cycle models are already available, many are missing a critical sediment component, which is indispensable for long-term integrations. One of LOSCAR's strengths is the coupling of ocean-atmosphere routines to a computationally efficient sediment module. This allows, for instance, adequate computation of CaCO3 dissolution, calcite compensation, and long-term carbon cycle fluxes, including weathering of carbonate and silicate rocks. The ocean component includes various biogeochemical tracers such as total carbon, alkalinity, phosphate, oxygen, and stable carbon isotopes. We have previously published applications of the model tackling future projections of ocean chemistry and weathering, pCO2 sensitivity to carbon cycle perturbations throughout the Cenozoic, and carbon/calcium cycling during the Paleocene-Eocene Thermal Maximum. The focus of the present contribution is the detailed description of the model including numerical architecture, processes and parameterizations, tuning, and examples of input and output. Typical CPU integration times of LOSCAR are of order seconds for several thousand model years on current standard desktop machines. The LOSCAR source code in C can be obtained from the author by sending a request to loscar.model@gmail.com.

  8. Fracture system influence on the reservoirs rock formation of Ordovician-Devonian carbonates in West Siberia tectonic depression

    NASA Astrophysics Data System (ADS)

    Koveshnikov, A. E.; Nesterova, A. C.; Dolgaya, T. F.

    2016-09-01

    During the Paleozoic period from the beginning of the Cambrian to the end of the Carboniferous in the boundaries of the West Siberia tectonic depression there occurred the sea, where the carbonate platforms were formed by the limestones accumulation. All the area at the end of the Carboniferous period was turned to land. Resulting from Gertsynskaya folding in the times of Permian - Triassic the formed deposits were folded and denudated to a considerable extent. Besides, the reservoir rocks of the crust of weathering including redeposited one, were formed as a result of hypergenesis, during the continental stand of the area in the near-surface zone. A new geological prospecting unit has been suggested which underlies these crusts of weathering and formed during fracture tectonic processes with hydrothermal-metasomatic limestones reworking and the processes of hydrothermal leaching and dolomitization. So, in the carbonate platforms the system of fissure zones related to tectonic disturbance was formed. This has a dendrite profile where the series of tangential, more thinned fractures deviate from the stem and finish in pores and caverns. The carbonate platforms formation in the West Siberia tectonic depression has been analyzed, their dynamics and gradual increasing from the minimal in Ordovician and Silurian to maximal at the end of the Late Devonian has been shown.

  9. 4D seismic to image a thin carbonate reservoir during a miscible C02 flood: Hall-Gurney Field, Kansas, USA

    USGS Publications Warehouse

    Raef, A.E.; Miller, R.D.; Franseen, E.K.; Byrnes, A.P.; Watney, W.L.; Harrison, W.E.

    2005-01-01

    The movement of miscible CO2 injected into a shallow (900 m) thin (3.6-6m) carbonate reservoir was monitored using the high-resolution parallel progressive blanking (PPB) approach. The approach concentrated on repeatability during acquisition and processing, and use of amplitude envelope 4D horizon attributes. Comparison of production data and reservoir simulations to seismic images provided a measure of the effectiveness of time-lapse (TL) to detect weak anomalies associated with changes in fluid concentration. Specifically, the method aided in the analysis of high-resolution data to distinguish subtle seismic characteristics and associated trends related to depositional lithofacies and geometries and structural elements of this carbonate reservoir that impact fluid character and EOR efforts.

  10. The self-similar solutions of the problem of carbon dioxide injection into the reservoir saturated with methane and its hydrate

    NASA Astrophysics Data System (ADS)

    Musakaev, N. G.; Khasanov, M. K.

    2016-10-01

    In this paper the research of carbon dioxide injection into a porous medium initially saturated with methane and its hydrate was performed. The mathematical model of heat and mass transfer in a porous media, accompanied by the formation of carbon dioxide hydrate, is presented. The self-similar solutions, for the axisymmetric problem definition, were built. These solutions describe the distribution of the fluid parameters in a reservoir.

  11. Design and Implementation of a CO2 Flood Utilizing Advanced Reservoir Characterization and Horizontal Injection Wells In a Shallow Shelf Carbonate Approaching Waterflood Depletion

    SciTech Connect

    Czirr, Kirk

    1999-10-28

    The first project objective is to utilize reservoir characterization and advanced technologies to optimize the design of a carbon dioxide (CO2) project for the South Cowden Unit (SCU) located in Ector County, Texas. The SCU is a mature, relatively small, shallow shelf carbonate unit nearing waterflood depletion. The second project objective is to demonstrate the performance and economic viability of the project in the field. All work during the second quarter falls within the demonstration project.

  12. The Abandonment of Social Studies?

    ERIC Educational Resources Information Center

    Griffith, Bryant

    1991-01-01

    Addresses the question of whether the social studies should be abandoned. Discusses Kieran Egan's analysis of the importance of storytelling and Egan's proposal to abandon the social studies curriculum in favor of a pedagogy more consistent with the way children think. Critiques Egan's view and examines implications for educators. (SG)

  13. Amplitude-versus-angle analysis and wide-angle-inversion of crosswell seismic data in a carbonate reservoir

    NASA Astrophysics Data System (ADS)

    Ibrahim, Mohamed S.

    pronounced for thinner reservoirs, particularly those beyond the vertical resolution of the seismic. For any interface imaged from above and from beneath, the results AVA characters must result from identical contrasts in elastic properties in the two sets of images, albeit in reverse order. An inversion approach to handle both datasets simultaneously, at pre-critical angles, is demonstrated in this work. The main exploration problem for carbonate reefs is determining the porosity distribution. Images of elastic properties, obtained from deterministic and geostatistical simultaneous inversion of a high-resolution crosswell seismic survey were used to obtain the internal structure and reservoir properties (porosity) of Niagaran Michigan reef. The images obtained are the best of any Niagaran pinnacle reef to date.

  14. Seismic amplitude variation with offset: Its effects on weighted stacking, and its uses in characterization of sandstone and carbonate reservoirs

    NASA Astrophysics Data System (ADS)

    Madiba, Gislain Bolouvi

    An algorithm for weighted stacking, which is not particularly expensive in terms of computer time or memory and can be easily incorporated into routine processing is proposed. A comprehensive comparison of the proposed weighted stacking algorithm and the conventional stacking algorithm is conducted through testing on synthetics and a real data set from New Mexico, USA. This weighted stacking algorithm achieves the primary goal of signal-to-noise ratio improvement while at the same time providing better resolution, wider bandwidth, and a higher signal-to-noise ratio than the conventional stack. A novel hydrocarbon indicator [the water-filled porosity (S wv)], which is estimated from the ratio of P-velocity to S-velocity (Vp/Vs), is proposed and applied to characterize clastic hydrocarbon reservoirs in the North Sea. The separation between pore fluids and lithologies is enhanced by mapping from V p/Vs to Swv using an empirical crossplot-derived relationship. The Swv-V p/Vs plane still does not produce unique interpretations in many situations. However, the critical distinction, which is between hydrocarbon-bearing sands and all other geologic/reservoir configurations, is defined. Porosity is the dominant factor controlling reservoir signature for carbonate rocks. Acoustic impedance and seismic amplitudes are porosity and lithology indicators. Angle-dependent reflectivity effects are introduced for determination of fluid charactersitics by simultaneous elastic impedance inversion of three non-overlapping migrated common-angle stacked sections for P- and S-impedance (Ip and Is). Deviations of points from a water-filled baseline in the Ip-I s plane define a gas potential section that is used for direct identification of gas zones in the dolomitized limestone reservoirs of the Turner Valley Formation in southern Alberta, Canada. There is consistency with the known gas production at a well and agreement with gas index sections obtained through the use of Lame parameter

  15. INTEGRATED GEOLOGIC-ENGINEERING MODEL FOR REEF AND CARBONATE SHOAL RESERVOIRS ASSOCIATED WITH PALEOHIGHS: UPPER JURASSIC SMACKOVER FORMATION, NORTHEASTERN GULF OF MEXICO

    SciTech Connect

    Ernest A. Mancini

    2004-02-25

    The University of Alabama, in cooperation with Texas A&M University, McGill University, Longleaf Energy Group, Strago Petroleum Corporation, and Paramount Petroleum Company, has undertaken an integrated, interdisciplinary geoscientific and engineering research project. The project is designed to characterize and model reservoir architecture, pore systems and rock-fluid interactions at the pore to field scale in Upper Jurassic Smackover reef and carbonate shoal reservoirs associated with varying degrees of relief on pre-Mesozoic basement paleohighs in the northeastern Gulf of Mexico. The project effort includes the prediction of fluid flow in carbonate reservoirs through reservoir simulation modeling which utilizes geologic reservoir characterization and modeling and the prediction of carbonate reservoir architecture, heterogeneity and quality through seismic imaging. The primary goal of the project is to increase the profitability, producibility and efficiency of recovery of oil from existing and undiscovered Upper Jurassic fields characterized by reef and carbonate shoals associated with pre-Mesozoic basement paleohighs. Geoscientific reservoir property, geophysical seismic attribute, petrophysical property, and engineering property characterization has shown that reef (thrombolite) and shoal reservoir lithofacies developed on the flanks of high-relief crystalline basement paleohighs (Vocation Field example) and on the crest and flanks of low-relief crystalline basement paleohighs (Appleton Field example). The reef thrombolite lithofacies have higher reservoir quality than the shoal lithofacies due to overall higher permeabilities and greater interconnectivity. Thrombolite dolostone flow units, which are dominated by dolomite intercrystalline and vuggy pores, are characterized by a pore system comprised of a higher percentage of large-sized pores and larger pore throats. Rock-fluid interactions (diagenesis) studies have shown that although the primary control on

  16. Key Factors for Determining Risk of Groundwater Impacts Due to Leakage from Geologic Carbon Sequestration Reservoirs

    SciTech Connect

    Carroll, Susan; Keating, Elizabeth; Mansoor, Kayyum; Dai, Zhenue; Sun, Yunwei; Trainor-Guitton, Whitney; Brown, Chris; Bacon, Diana

    2014-01-06

    The National Risk Assessment Partnership (NRAP) is developing a science-based toolset for the analysis of potential impacts to groundwater chemistry from CO2 injection (www.netldoe.gov/nrap). The toolset adopts a stochastic approach in which predictions address uncertainties in shallow underwater and leakage scenarios. It is derived from detailed physics and chemistry simulation results that are used to train more computationally efficient models,l referred to here as reduced-order models (ROMs), for each component system. In particular, these tools can be used to help regulators and operators understand the expected sizes and longevity of plumes in pH, TDS, and dissolved metals that could result from a leakage of brine and/or CO2 from a storage reservoir into aquifers. This information can inform, for example, decisions on monitoring strategies that are both effective and efficient. We have used this approach to develop predictive reduced-order models for two common types of reservoirs, but the approach could be used to develop a model for a specific aquifer or other common types of aquifers. In this paper we describe potential impacts to groundwater quality due to CO2 and brine leakage, discuss an approach to calculate thresholds under which "no impact" to groundwater occurs, describe the time scale for impact on groundwater, and discuss the probability of detecting a groundwater plume should leakage occur.

  17. Reduced sulfur-carbon-water systems on Mars may yield shallow methane hydrate reservoirs

    NASA Astrophysics Data System (ADS)

    Elwood Madden, M. E.; Leeman, J. R.; Root, M. J.; Gainey, S.

    2011-02-01

    Methane clathrate hydrate reservoirs capped by overlying permafrost have been proposed as potential sources of atmospheric methane plumes on Mars. However, the surface flux of methane from hydrate dissociation is limited by the diffusion rate of methane through the overlying ice. Assuming hydrates underlay the entire plume footprint, the maximum diffusion path length is expected to be less than 15 m, depths too shallow to stabilize pure methane hydrates under Mars geothermal and lithostatic conditions at low to mid latitudes. Therefore, pure methane hydrates confined within permafrost could not produce methane surface fluxes of the magnitude observed near the equator. However, the addition of 10% H 2S, a secondary gas commonly associated with methane production on Earth, expands the hydrate stability field, with clathrates expected within 10 m of the surface at the equator and at depths less than 1 m at higher latitudes. This indicates that H 2S would also be expected to be released as well as methane if the plumes have a confined hydrate reservoir source.

  18. Organic matter turnover in reservoirs of the Harz Mountains (Germany): evidence from 13C/12C changes in dissolved inorganic carbon

    NASA Astrophysics Data System (ADS)

    Barth, Johannes A. C.; Nenning, Franziska; van Geldern, Robert; Mader, Michael; Friese, Kurt

    2014-05-01

    The Harz Mountains in Germany host several reservoirs for drinking water and electricity supply, the largest of which is the Rappbode System with its two pre-reservoirs. They are the Hassel and the Rappbode pre-reservoirs that have about the same size. These pre-reservoirs were investigated in a comparative study in order to quantify turnover of dissolved organic carbon (DOC) as a representative for organic matter. The objective was to find out how organic matter turnover in these reservoirs may affect dissolved inorganic carbon (DIC) and related CO2 dynamics. Depth profiles of dissolved organic and inorganic carbon (DOC and DIC) were established together with their carbon stable isotope distributions (expressed as δ13CDIC and δ13CDOC). Our results showed up to 104 % increase of DIC contents by organic matter turnover when calculated via isotope mass balances. This contrasted observations of DIC concentration differences between waters collected at the surface and at 12 m depth. These concentration comparisons showed much less DIC increases, and in some cases even decreases, between surface and bottom waters. Such discrepancies could be explained by formation of CO2 at depths below the photic zone that reached calculated values above 7000 ppmV. Such high CO2 concentrations may have reduced the DIC pool by upwards migration. Despite such a concentration decrease, turnover of organic matter has likely incorporated its isotope signal into the DIC pool. While not all DOC present was transposed to DIC, other forms of organic matter from sediments may also have transferred their isotope ratio on the DIC pool. However, with its stable isotope ratio of -28.5 permille the measured DOC was representative of C3 plants and can be assumed as a proxy for other forms of sedimentary carbon including carbon from pore waters and particulate organic matter. Other carbon turnover, including DOC leaching, increased import to the reservoirs after precipitation events and

  19. Miscibility study of carbon dioxide injection to enhance oil recovery from Abu-Dhabi oil field Thani reservoire

    NASA Astrophysics Data System (ADS)

    Aljarwan, Abdulla Humaid Saif Saeed

    The subject field in this study has been recognized among the largest offshore oil fields in the world, located in the Arabian Gulf 63 kilometers to the Northwest of Abu Dhabi, producing large quantities of crude oil and associated gas from three different carbonate reservoirs, Thani-I, II and IIII since 1963. In the early 1970's peripheral water injection scheme was adopted to maintain the reservoir pressure and sustain production. Simultaneously, partial waterflooding was applied to one sector of the field, but stopped soon after implementation shadowed by poor sweep efficiency and dramatic escalation of water-cut. Furthermore, hydrocarbon miscible gas injection was implemented in the year 2000 but stopped seven years later, due to high gas oil ratio and aspheltene deposition. In light of such recovery complications, management is considering serious recovery measures to extend plateau production and meet long-term production from this field. Post initial screening phase, it became evident that CO 2 miscible injection is the most suitable way forward. Characteristics of the Thani-III reservoir are within the favorable range for both immiscible and miscible CO2 injection criteria set by Taber, Martine and Serigh. Thani-III reservoir is considered more homogenous, less fractured and with higher production potential than Thani-I and II, hence promoted to be the target of CO2 miscible gas injection. This thesis aims to study the miscibility features of CO2 miscible injecton to enhanced oil recovery from Thani-III reservoir. Comprehensive simulation model is used to determine multi contact miscibility and suitable equation of state with CO2 as a separate pseudo component using one of the industry standard simulation software. Experimental PVT data for bottom hole and separator samples including compositional analysis, differential liberation test, separator tests, constant composition expansion, viscosity measurements and swelling tests for pure CO2 were used to

  20. Capillary pressure-saturation relations for supercritical CO2 and brine in limestone/dolomite sands: implications for geologic carbon sequestration in carbonate reservoirs.

    PubMed

    Wang, Shibo; Tokunaga, Tetsu K

    2015-06-16

    In geologic carbon sequestration, capillary pressure (Pc)-saturation (Sw) relations are needed to predict reservoir processes. Capillarity and its hysteresis have been extensively studied in oil-water and gas-water systems, but few measurements have been reported for supercritical (sc) CO2-water. Here, Pc-Sw relations of scCO2 displacing brine (drainage), and brine rewetting (imbibition) were studied to understand CO2 transport and trapping behavior under reservoir conditions. Hysteretic drainage and imbibition Pc-Sw curves were measured in limestone sands at 45 °C under elevated pressures (8.5 and 12.0 MPa) for scCO2-brine, and in limestone and dolomite sands at 23 °C (0.1 MPa) for air-brine using a new computer programmed porous plate apparatus. scCO2-brine drainage and imbibition curves shifted to lower Pc relative to predictions based on interfacial tension, and therefore deviated from capillary scaling predictions for hydrophilic interactions. Fitting universal scaled drainage and imbibition curves show that wettability alteration resulted from scCO2 exposure over the course of months-long experiments. Residual trapping of the nonwetting phases was determined at Pc = 0 during imbibition. Amounts of trapped scCO2 were significantly larger than for those for air, and increased with pressure (depth), initial scCO2 saturation, and time. These results have important implications for scCO2 distribution, trapping, and leakage potential.

  1. MULTIDISCIPLINARY IMAGING OF ROCK PROPERTIES IN CARBONATE RESERVOIRS FOR FLOW-UNIT TARGETING

    SciTech Connect

    Stephen C. Ruppel

    2003-01-01

    Excellent progress has been made on all project objectives and goals. All tasks have been completed in the Phase 1 study area, the initial area of project focus. Primary elements of this work include the following: The stratigraphic architecture has been established through correlation of wireline logs guided by core and outcrop studies of facies and cyclicity. A porosity model has been developed that creates a basis for calculation of porosity for wells in the study area. Rock fabrics have been defined by sampling, analysis, and description of cores and used to create transforms for calculating permeability and oil saturation from porosity data. Finally, a preliminary 3-D model has been constructed that incorporates stratigraphic architecture, rock-fabric data, and petrophysical data. Reservoir volumetrics calculated from the model show that a very large fraction of the original oil in place remains.

  2. Simulation study to determine the feasibility of injecting hydrogen sulfide, carbon dioxide and nitrogen gas injection to improve gas and oil recovery oil-rim reservoir

    NASA Astrophysics Data System (ADS)

    Eid, Mohamed El Gohary

    This study is combining two important and complicated processes; Enhanced Oil Recovery, EOR, from the oil rim and Enhanced Gas Recovery, EGR from the gas cap using nonhydrocarbon injection gases. EOR is proven technology that is continuously evolving to meet increased demand and oil production and desire to augment oil reserves. On the other hand, the rapid growth of the industrial and urban development has generated an unprecedented power demand, particularly during summer months. The required gas supplies to meet this demand are being stretched. To free up gas supply, alternative injectants to hydrocarbon gas are being reviewed to support reservoir pressure and maximize oil and gas recovery in oil rim reservoirs. In this study, a multi layered heterogeneous gas reservoir with an oil rim was selected to identify the most optimized development plan for maximum oil and gas recovery. The integrated reservoir characterization model and the pertinent transformed reservoir simulation history matched model were quality assured and quality checked. The development scheme is identified, in which the pattern and completion of the wells are optimized to best adapt to the heterogeneity of the reservoir. Lateral and maximum block contact holes will be investigated. The non-hydrocarbon gases considered for this study are hydrogen sulphide, carbon dioxide and nitrogen, utilized to investigate miscible and immiscible EOR processes. In November 2010, re-vaporization study, was completed successfully, the first in the UAE, with an ultimate objective is to examine the gas and condensate production in gas reservoir using non hydrocarbon gases. Field development options and proces schemes as well as reservoir management and long term business plans including phases of implementation will be identified and assured. The development option that maximizes the ultimate recovery factor will be evaluated and selected. The study achieved satisfactory results in integrating gas and oil

  3. 4-D High-Resolution Seismic Reflection Monitoring of Miscible CO2 Injected into a Carbonate Reservoir

    SciTech Connect

    Richard D. Miller; Abdelmoneam E. Raef; Alan P. Byrnes; William E. Harrison

    2007-06-30

    The objective of this research project was to acquire, process, and interpret multiple high-resolution 3-D compressional wave and 2-D, 2-C shear wave seismic data in the hopes of observing changes in fluid characteristics in an oil field before, during, and after the miscible carbon dioxide (CO{sub 2}) flood that began around December 1, 2003, as part of the DOE-sponsored Class Revisit Project (DOE No.DE-AC26-00BC15124). Unique and key to this imaging activity is the high-resolution nature of the seismic data, minimal deployment design, and the temporal sampling throughout the flood. The 900-m-deep test reservoir is located in central Kansas oomoldic limestones of the Lansing-Kansas City Group, deposited on a shallow marine shelf in Pennsylvanian time. After 30 months of seismic monitoring, one baseline and eight monitor surveys clearly detected changes that appear consistent with movement of CO{sub 2} as modeled with fluid simulators and observed in production data. Attribute analysis was a very useful tool in enhancing changes in seismic character present, but difficult to interpret on time amplitude slices. Lessons learned from and tools/techniques developed during this project will allow high-resolution seismic imaging to be routinely applied to many CO{sub 2} injection programs in a large percentage of shallow carbonate oil fields in the midcontinent.

  4. Role of parasequence-scale sequence stratigraphic analysis in integrated reservoir characterization and modeling of shallow-water carbonate strata

    SciTech Connect

    Kerans, C.; Lucia, F.J.; Bebout, D.G.; Major, R.P.; Ruppel, S.C. )

    1991-03-01

    The predictable stacking patterns of parasequences within different systems tracts of a sequence and of facies and rock-fabric successions within parasequences provide a powerful conceptual framework for integrated analysis of carbonate reservoirs. Stratigraphic analysis using a parasequence approach emphasizes correlation through comparative mapping of genetically related facies successions rather than the classic marker bed approach. The basic shallow-water carbonate parasequence is the upward-shallowing cycle ({approximately}fifth-order cycle, average period {minus}20,000 yr) that records a single progradational event represented most often by an upward-coarsening facies/rock-fabric succession. Interpretation of depositional environment is best accomplished at the parasequence scale because lateral facies relationships within these units best approximate time-equivalent genetically related deposits. The upward-shallowing facies succession that forms a parasequence provides a natural framework for quantification of geologic descriptions through rock-fabric-oriented petrophysical analysis. Permeability and saturation are directly related to sediment grain size, sorting, and interparticle porosity. Grain-dominated rocks have higher permeability and oil-saturation values than do mud-dominated rocks with the same interparticle porosity. Grain size and sorting occur systematically and predictably in the upward-shallowing parasequences. Porosity, grain size, and sorting can be significantly altered by diagenetic processes such as dolomitization, cementation, and dissolution. Diagenetic overprints are, however, commonly controlled by the depositional textures and thus also are predictable.

  5. Sedimentological cross section of Cambro-Ordovician carbonate shelf (Knox group, Conassauga Formation) in central Alabama: facies, diagenesis, potential reservoirs

    SciTech Connect

    Sternbach, L.R.

    1984-04-01

    Cambro-Ordovician thrust-imbricated carbonates in central Alabama are the focus of renewed exploration interest. Samples from east-west-trending core holes within the surface-most thrust plates reconstruct the carbonate shelf and shelf-edge facies before deformation. The Upper Cambrian shelf margin now is in the subsurface of Talledega County; coeval dolostones in the western part of the state represent the former shelf interior. Rock analogs to former environments include the following. (1) Barrier shoals (Conasauga Formation) - dark colored, partially dolomitized ooid and skeletal grainstones. (2) Submerged back-barrier and offshelf dolomitized sediments (lower Knox Group) - western belt: finely crystalline algal thrombolites, fenestral dolopelmicrites, rippled beds; eastern belt: finely laminated dolostones, slope-derived pebbles and graded beds. (3) Tidal flats (upper Knox Group) - light-colored, crystalline dolostones, dolomitized pellet grainstones, algal laminites, pseudomorphs after sulfates and early diagenetic chertification. (4) Former emergent shelf -(Knox unconformity)-pelmicrite, skeletal wackestones, erosional chert pebble conglomerate. Multiple possibilities for hydrocarbon reservoirs appear throughout the sequence. Vuggy and intercrystalline dolostone porosity is primarily in the lower Knox formations. Primary interparticle pores are retained in lower Knox algal buildups. Breccia porosity occurs in the strata below the Knox unconformity through solution of the underlying Knox Group. Fractures in the subsurface are believed to enhance permeability in all porosity types.

  6. Sedimentological cross section of Cambro-Ordovician carbonate shelf (Knox group, Conasauga Formation) in central Alabama: facies, diagenesis, potential reservoirs

    SciTech Connect

    Sternbach, L.R.

    1984-04-01

    Cambro-Ordovician thrust-imbricated carbonates in central Alabama are the focus of renewed exploration interest. Samples from east-west-trending core holes within the surface-most thrust plates reconstruct the carbonate shelf and shelf-edge facies before deformation. The Upper Cambrian shelf margin now is in the subsurface of Talledega County; coeval dolostones in the western part of the state represent the former shelf interior. Rock analogs to former environments include the following. (1) Barrier shoals (Conasauga Formation) - dark colored, partially dolomitized ooid and skeletal grainstones. (2) Submerged back-barrier and offshelf dolomitized sediments (lower Knox Group) - western belt: finely crystalline algal thrombolites, fenestral dolopelmicrites, rippled beds; eastern belt: finely laminated dolostones, slope-derived pebbles and graded beds. (3) Tidal flats (upper Knox Group) - light-colored, crystalline dolostones, dolomitized pellet grainstones, algal laminites, pseudomorphs after sulfates and early diagenetic chertification. (4) Former emergent shelf -(Knox unconformity)-pelmicrite, skeletal wackestones, erosional chert pebble conglomerate. Multiple possibilities for hydrocarbon reservoirs appear throughout the sequence. Vuggy and intercrystalline dolostone porosity is primarily in the lower Knox formations. Primary interparticle pores are retained in lower Knox algal buildups. Breccia porosity occurs in the strata below the Knox unconformity through solution of the underlying Knox Group. Fractures in the subsurface are believed to enhance permeability in all porosity types.

  7. Integrated Outcrop and Subsurface Studies of the Interwell Environment of Carbonate Reservoirs: Clear Fork (Leonaradian Age) Reservoirs, West Texas and New Mexico

    SciTech Connect

    Lucia, F. Jerry; Jennings, Jr., James W.

    2001-05-08

    A preliminary reservoir model was constructed for the Lower Clear Fork of the South Wasson Clear Fork reservoir. The model was constructed by calibrating high-frequency cycles observed in cores to the porosity log. The rock fabrics mostly fall in petrophysical class 1, and cross plots of porosity and water saturation could not be used to identify rock fabrics. Data from two limestone fields and one dolostone field were presented to support the contention that grain-dominated fabrics have higher porosity than mud-dominated fabrics do and that this difference is retained when the limestone is dolomitized.

  8. ADVANCED CHARACTERIZATION OF FRACTURED RESERVOIRS IN CARBONATE ROCKS: THE MICHIGAN BASIN

    SciTech Connect

    James R. Wood; William B. Harrison

    2002-12-01

    The purpose of the study was to collect and analyze existing data on the Michigan Basin for fracture patterns on scales ranging form thin section to basin. The data acquisition phase has been successfully concluded with the compilation of several large digital databases containing nearly all the existing information on formation tops, lithology and hydrocarbon production over the entire Michigan Basin. These databases represent the cumulative result of over 80 years of drilling and exploration. Plotting and examination of these data show that contrary to most depictions, the Michigan Basin is in fact extensively faulted and fractured, particularly in the central portion of the basin. This is in contrast to most of the existing work on the Michigan Basin, which tends to show relatively simple structure with few or minor faults. It also appears that these fractures and faults control the Paleozoic sediment deposition, the subsequent hydrocarbon traps and very likely the regional dolomitization patterns. Recent work has revealed that a detailed fracture pattern exists in the interior of the Central Michigan Basin, which is related to the mid-continent gravity high. The inference is that early Precambrian, ({approx}1 Ga) rifting events presumed by many to account for the gravity anomaly subsequently controlled Paleozoic sedimentation and later hydrocarbon accumulation. There is a systematic relationship between the faults and a number of gas and oil reservoirs: major hydrocarbon accumulations consistently occur in small anticlines on the upthrown side of the faults. The main tools used in this study to map the fault/fracture patterns are detailed, close-interval (CI = 10 feet) contouring of the formation top picks accompanied by a new way of visualizing the data using a special color spectrum to bring out the third dimension. In addition, recent improvements in visualization and contouring software were instrumental in the study. Dolomitization is common in the

  9. Maximizing Storage Rate and Capacity and Insuring the Environmental Integrity of Carbon Dioxide Sequestration in Geological Reservoirs

    SciTech Connect

    L.A. Davis; A.L. Graham; H.W. Parker; J.R. Abbott; M.S. Ingber; A.A. Mammoli; L.A. Mondy; Quanxin Guo; Ahmed Abou-Sayed

    2005-12-07

    Maximizing Storage Rate and Capacity and Insuring the Environmental Integrity of Carbon Dioxide Sequestration in Geological Formations The U.S. and other countries may enter into an agreement that will require a significant reduction in CO2 emissions in the medium to long term. In order to achieve such goals without drastic reductions in fossil fuel usage, CO2 must be removed from the atmosphere and be stored in acceptable reservoirs. The research outlined in this proposal deals with developing a methodology to determine the suitability of a particular geologic formation for the long-term storage of CO2 and technologies for the economical transfer and storage of CO2 in these formations. A novel well-logging technique using nuclear-magnetic resonance (NMR) will be developed to characterize the geologic formation including the integrity and quality of the reservoir seal (cap rock). Well-logging using NMR does not require coring, and hence, can be performed much more quickly and efficiently. The key element in the economical transfer and storage of the CO2 is hydraulic fracturing the formation to achieve greater lateral spreads and higher throughputs of CO2. Transport, compression, and drilling represent the main costs in CO2 sequestration. The combination of well-logging and hydraulic fracturing has the potential of minimizing these costs. It is possible through hydraulic fracturing to reduce the number of injection wells by an order of magnitude. Many issues will be addressed as part of the proposed research to maximize the storage rate and capacity and insure the environmental integrity of CO2 sequestration in geological formations. First, correlations between formation properties and NMR relaxation times will be firmly established. A detailed experimental program will be conducted to determine these correlations. Second, improved hydraulic fracturing models will be developed which are suitable for CO2 sequestration as opposed to enhanced oil recovery (EOR

  10. The Carbon in Arctic Reservoirs Vulnerability Experiment (CARVE) FTS: Results From the 2012/13 Alaska Campaigns

    NASA Astrophysics Data System (ADS)

    Kurosu, Thomas P.; Miller, Charles E.; Dinardo, Stephen J.

    2014-05-01

    The Carbon in Arctic Reservoirs Vulnerability Experiment (CARVE) is an aircraft-based Earth Venture 1 mission to study the carbon balance of the Alaskan Arctic ecosystem, with a particular focus on carbon release from melting permafrost. Operating from its base in Fairbanks, AK, the CARVE aircraft covers a range of principle flight paths in the Alaskan interior, the Yukon River valley, and the northern Alaska coast around Barrow and Dead Horse. Flight paths are chosen to maximize ecosystem variability and cover burn-recovery/regrowth sequences. CARVE observations cover the Arctic Spring/Summer/Fall seasons, with multiple flights per season and principle flight path. Science operations started in May 2012 and are currently envisaged to continue until 2015. The CARVE suite of instruments includes flask measurements, in situ gas analyzers for CO2, CH4 and CO observations, and a three-band polarizing Fourier Transform Spectrometer (FTS) for column measurements of CO2, CH4, CO, their interfering species (e.g., H2O), and O2. The FTS covers the spectral regions of 4,200-4,900 cm-1, 5,800-6,400 cm-1, and 12,900-13,200 cm-1, with a spectral resolution of 0.2 cm-1. Aircraft-based FTS science observations in Alaska have been performed since 23-05-2012. First-version data products from all CARVE instruments derived from observations during the 2012 campaign were publicly released earlier in 2013. The FTS has performed well during flight conditions, particularly with respect to vibration damping. Outstanding challenges include the need for improved spectral and radiometric calibration, as well as compensating for low signal-to-noise spectra acquired under Alaskan flight conditions. We present results from FTS column observations of CO2, CH4, and CO, observed during the 2012 and 2013 campaigns, including preliminary comparisons of CARVE FTS measurements with satellite observations of CO2 from TANSO/GOSAT and CO from MOPITT.

  11. TSR versus non-TSR processes and their impact on gas geochemistry and carbon stable isotopes in Carboniferous, Permian and Lower Triassic marine carbonate gas reservoirs in the Eastern Sichuan Basin, China

    NASA Astrophysics Data System (ADS)

    Liu, Q. Y.; Worden, R. H.; Jin, Z. J.; Liu, W. H.; Li, J.; Gao, B.; Zhang, D. W.; Hu, A. P.; Yang, C.

    2013-01-01

    The Palaeozoic and lowermost Mesozoic marine carbonate reservoirs of the Sichuan Basin in China contain variably sour and very dry gas. The source of the gas in the Carboniferous, Permian and Lower Triassic reservoirs is not known for certain and it has proved difficult to discriminate and differentiate the effects of thermal cracking- and TSR-related processes for these gases. Sixty-three gas samples were collected and analysed for their composition and carbon stable isotope values. The gases are all typically very dry (alkane gases being >97.5% methane), with low (<1%) nitrogen and highly variable H2S and CO2. Carboniferous gas is negligibly sour while the Lower Triassic gas tends to be most sour. The elevated H2S (up to 62%) is due to thermochemical sulphate reduction with the most sour Triassic and Permian reservoirs being deeper than 4800 m. The non-TSR affected Carboniferous gas is a secondary gas that was derived from the cracking of sapropelic kerogen-derived oil and primary gas and is highly mature. Carboniferous (and non-sour Triassic and Permian) gas has unusual carbon isotopes with methane and propane being isotopically heavier than ethane (a reversal of typical low- to moderate-maturity patterns). The gas in the non-sour Triassic and Permian reservoirs has the same geochemical and isotopic characteristics (and therefore the same source) as the Carboniferous gas. TSR in the deepest Triassic reservoirs altered the gas composition reaching 100% dryness in the deepest, most sour reservoirs showing that ethane and propane react faster than methane during TSR. Ethane evolves to heavier carbon isotope values than methane during TSR leading to removal of the reversed alkane gas isotope trend found in the Carboniferous and non-sour Triassic and Permian reservoirs. However, methane was directly involved in TSR as shown by the progressive increase in its carbon isotope ratio as gas souring proceeded. CO2 increased in concentration as gas souring proceeded, but

  12. Ordovician carbonate buildups: Potential gas reservoirs in the Ordos basin, central China

    SciTech Connect

    Huaida Hsu )

    1991-03-01

    The Ordos basin of central China covers an area of about 25,000 km{sup 2}. A series of eastward moving overthrusts developed along its western flank, but most of the basin consists of a stable slope that dips westward less than one degree. The basin contains sediments from Sinian to Middle Ordovician and from the Middle Carboniferous to Cretaceous. Its evolutionary history is similar to that of the Alberta basin. Recently drilled wildcat wells have produced commercial gas flows that are closely associated with Ordovician carbonate buildups and a weathered surface between the Ordovician and Carboniferous. Most of the buildups consist of agal mounds; however, some Middle Ordovician reefs developed in the western portion and along the southern margin of the Ordos basin. More than 200 buildups were delineated using seismic stratigraphic techniques. They can be divided into four distinct types. The growth and distribution of buildups were controlled by sea-level fluctuations. The interpretations made in this study were based on the integration of results from a variety of analyses including vertical profiling, differential interformational velocity analysis, amplitude versus offset comparisons, G-log analysis, seismic modeling techniques, and high-precision gravity surveys. The best gas prospects are the Ordovician carbonate buildups distributed around the basin's central uplift. The delineation of carbonate buildups and the demonstration that they are associated with commercial gas flows open the gate for future gas exploration in this area.

  13. Drake passage and central american seaway controls on the distribution of the oceanic carbon reservoir

    SciTech Connect

    Fyke, Jeremy G.; D'Orgeville, Marc; Weaver, Andrew J.

    2015-05-01

    A coupled carbon/climate model is used to explore the impact of Drake Passage opening and Central American Seaway closure on the distribution of carbon in the global oceans. We find that gateway evolution likely played an important role in setting the modern day distribution of oceanic dissolved inorganic carbon (DIC), which is currently characterized by relatively low concentrations in the Atlantic ocean, and high concentrations in the Southern, Indian, and Pacific oceans. In agreement with previous studies, we find a closed Drake Passage in the presence of an open Central American Seaway results in suppressed Atlantic meridional overturning and enhanced southern hemispheric deep convection. Opening of the Drake Passage triggers Antarctic Circumpolar Current flow and a weak Atlantic meridional overturning circulation (AMOC). Subsequent Central American Seaway closure reinforces the AMOC while also stagnating equatorial Pacific subsurface waters. These gateway-derived oceanographic changes are reflected in large shifts to the global distribution of DIC. An initially closed Drake Passage results in high DIC concentrations in the Atlantic and Arctic oceans, and lower DIC concentrations in the Pacific/Indian/Southern oceans. Opening Drake Passage reverses this gradient by lowering mid-depth Atlantic and Arctic DIC concentrations and raising deep Pacific/Indian/Southern Ocean DIC concentrations. Central American Seaway closure further reinforces this trend through additional Atlantic mid-depth DIC decreases, as well as Pacific mid-depth DIC concentration increases, with the net effect being a transition to a modern distribution of oceanic DIC.

  14. Drake passage and central american seaway controls on the distribution of the oceanic carbon reservoir

    DOE PAGES

    Fyke, Jeremy G.; D'Orgeville, Marc; Weaver, Andrew J.

    2015-05-01

    A coupled carbon/climate model is used to explore the impact of Drake Passage opening and Central American Seaway closure on the distribution of carbon in the global oceans. We find that gateway evolution likely played an important role in setting the modern day distribution of oceanic dissolved inorganic carbon (DIC), which is currently characterized by relatively low concentrations in the Atlantic ocean, and high concentrations in the Southern, Indian, and Pacific oceans. In agreement with previous studies, we find a closed Drake Passage in the presence of an open Central American Seaway results in suppressed Atlantic meridional overturning and enhancedmore » southern hemispheric deep convection. Opening of the Drake Passage triggers Antarctic Circumpolar Current flow and a weak Atlantic meridional overturning circulation (AMOC). Subsequent Central American Seaway closure reinforces the AMOC while also stagnating equatorial Pacific subsurface waters. These gateway-derived oceanographic changes are reflected in large shifts to the global distribution of DIC. An initially closed Drake Passage results in high DIC concentrations in the Atlantic and Arctic oceans, and lower DIC concentrations in the Pacific/Indian/Southern oceans. Opening Drake Passage reverses this gradient by lowering mid-depth Atlantic and Arctic DIC concentrations and raising deep Pacific/Indian/Southern Ocean DIC concentrations. Central American Seaway closure further reinforces this trend through additional Atlantic mid-depth DIC decreases, as well as Pacific mid-depth DIC concentration increases, with the net effect being a transition to a modern distribution of oceanic DIC.« less

  15. The impact of climate and reservoirs on longitudinal riverine carbon fluxes from two major watersheds in the Central and Intermontane West

    USGS Publications Warehouse

    Stackpoole, Sarah M.; Stets, Edward G.; Striegl, Robert G.

    2014-01-01

    A nested sampling network on the Colorado (CR) and Missouri Rivers (MR) provided data to assess impacts of large-scale reservoir systems and climate on carbon export. The Load Estimator (LOADEST) model was used to estimate both dissolved inorganic and organic carbon (DIC and DOC) fluxes for a total of 22 sites along the main stems of the CR and MR. Both the upper CR and MR DIC and DOC fluxes increased longitudinally, but the lower CR fluxes decreased while the lower MRs continued to increase. We examined multiple factors through space and time that help explain these flux patterns. Seasonal variability in precipitation and temperature, along with site-level concentration versus discharge relationships proved to be significant factors explaining much of the difference among sites located below reservoirs as compared to sites located in more free-flowing segments of the river. The characterization of variability in carbon exports over space and time provides a basis for understanding carbon cycling and transport within river basins affected by large reservoir systems, particular in arid-to semi-arid ecosystems.

  16. The Carbon in Arctic Reservoirs Vulnerability Experiment (CARVE): Five Years of Insights into the High Latitude Carbon Cycle

    NASA Astrophysics Data System (ADS)

    Miller, C. E.

    2015-12-01

    CARVE is a NASA Earth Ventures (EV-1) investigation designed to quantify correlations between atmospheric and surface state variables for the Alaskan terrestrial ecosystems through intensive seasonal aircraft campaigns, ground-based observations, and analysis. In 2015 CARVE completed its 5-year mission. CARVE campaigns across the 2012-2015 growing seasons have established a baseline for monthly, regional scale estimates for surface-atmosphere fluxes of carbon dioxide (CO2) and methane (CH4), and begun to elucidate their environmental and biogeochemical controls. We find that large interannual variability in biogenic CH4 and CO2 fluxes, fire, and significant cold season fluxes complicate attempts to estimate accurate annual C budgets or C balance trends for high latitude ecosystems. We discuss our current estimates for seasonal to interannual CH4 and CO2 fluxes as well as lessons learned from CARVE to guide future investigations of carbon cycling and ecosystem vulnerability in the Arctic-Boreal region with particular emphasis on NGEE-Arctic and ABoVE.

  17. 23 CFR 752.10 - Abandoned vehicles.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 23 Highways 1 2010-04-01 2010-04-01 false Abandoned vehicles. 752.10 Section 752.10 Highways... ROADSIDE DEVELOPMENT § 752.10 Abandoned vehicles. (a) Abandoned motor vehicles may be removed from the... collection of abandoned motor vehicles from within the right-of-way must be a development project and not...

  18. 23 CFR 752.10 - Abandoned vehicles.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 23 Highways 1 2013-04-01 2013-04-01 false Abandoned vehicles. 752.10 Section 752.10 Highways... ROADSIDE DEVELOPMENT § 752.10 Abandoned vehicles. (a) Abandoned motor vehicles may be removed from the... collection of abandoned motor vehicles from within the right-of-way must be a development project and not...

  19. 23 CFR 752.10 - Abandoned vehicles.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 23 Highways 1 2014-04-01 2014-04-01 false Abandoned vehicles. 752.10 Section 752.10 Highways... ROADSIDE DEVELOPMENT § 752.10 Abandoned vehicles. (a) Abandoned motor vehicles may be removed from the... collection of abandoned motor vehicles from within the right-of-way must be a development project and not...

  20. 23 CFR 752.10 - Abandoned vehicles.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 23 Highways 1 2012-04-01 2012-04-01 false Abandoned vehicles. 752.10 Section 752.10 Highways... ROADSIDE DEVELOPMENT § 752.10 Abandoned vehicles. (a) Abandoned motor vehicles may be removed from the... collection of abandoned motor vehicles from within the right-of-way must be a development project and not...

  1. 23 CFR 752.10 - Abandoned vehicles.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 23 Highways 1 2011-04-01 2011-04-01 false Abandoned vehicles. 752.10 Section 752.10 Highways... ROADSIDE DEVELOPMENT § 752.10 Abandoned vehicles. (a) Abandoned motor vehicles may be removed from the... collection of abandoned motor vehicles from within the right-of-way must be a development project and not...

  2. High H2S contents and other effects of thermochemical sulfate reduction in deeply buried carbonate reservoirs: a review

    NASA Astrophysics Data System (ADS)

    Nöth, S.

    The accumulation of high H2S concentrations in oil and gas fields is usually associated with deeply buried high-temperature carbonate reservoirs and is attributed to the abiological oxidation of hydrocarbons by sulfate - thermochemical sulfate reduction (TSR). This review aims at providing an overview of the literature and assessing existing uncertainties in the current understanding of TSR processes and their geological significance. Reaction pathways, various reaction products, the autocatalytic nature of TSR, and reaction kinetics are discussed. Furthermore, various criteria for recognizing TSR effects, such as petrographic/diagenetic alterations and stable isotope geochemistry of the inorganic as well as the organic reactants, are summarized and evaluated. There is overwhelming geological evidence of TSR taking place at a minimum temperature of 110-140°C, but the temperature discrepancy between experimental data and nature still exists. However, the exact nature and mechanisms of catalysts which influence TSR are not known. Local H2S variations may reflect steady-state conditions dominated by H2S buildups and flux out of the system. The latter is controlled by lithological and geological factors.

  3. Assessing spatial uncertainty in reservoir characterization for carbon sequestration planning using public well-log data: A case study

    USGS Publications Warehouse

    Venteris, E.R.; Carter, K.M.

    2009-01-01

    Mapping and characterization of potential geologic reservoirs are key components in planning carbon dioxide (CO2) injection projects. The geometry of target and confining layers is vital to ensure that the injected CO2 remains in a supercritical state and is confined to the target layer. Also, maps of injection volume (porosity) are necessary to estimate sequestration capacity at undrilled locations. Our study uses publicly filed geophysical logs and geostatistical modeling methods to investigate the reliability of spatial prediction for oil and gas plays in the Medina Group (sandstone and shale facies) in northwestern Pennsylvania. Specifically, the modeling focused on two targets: the Grimsby Formation and Whirlpool Sandstone. For each layer, thousands of data points were available to model structure and thickness but only hundreds were available to support volumetric modeling because of the rarity of density-porosity logs in the public records. Geostatistical analysis based on this data resulted in accurate structure models, less accurate isopach models, and inconsistent models of pore volume. Of the two layers studied, only the Whirlpool Sandstone data provided for a useful spatial model of pore volume. Where reliable models for spatial prediction are absent, the best predictor available for unsampled locations is the mean value of the data, and potential sequestration sites should be planned as close as possible to existing wells with volumetric data. ?? 2009. The American Association of Petroleum Geologists/Division of Environmental Geosciences. All rights reserved.

  4. 4-D High-Resolution Seismic Reflection Monitoring of Miscible CO2 Injected into a Carbonate Reservoir

    SciTech Connect

    Richard D. Miller; Abdelmoneam E. Raef; Alan P. Byrnes; William E. Harrison

    2005-09-01

    The objective of this research project is to acquire, process, and interpret multiple high-resolution 3-D compressional wave and 2-D, 2-C shear wave seismic data to observe changes in fluid characteristics in an oil field before, during, and after the miscible carbon dioxide (CO{sub 2}) flood that began around December 1, 2003, as part of the DOE-sponsored Class Revisit Project (DOE DE-AC26-00BC15124). Unique and key to this imaging activity is the high-resolution nature of the seismic data, minimal deployment design, and the temporal sampling throughout the flood. The 900-m-deep test reservoir is located in central Kansas oomoldic limestones of the Lansing-Kansas City Group, deposited on a shallow marine shelf in Pennsylvanian time. After 18 months of seismic monitoring, one baseline and six monitor surveys clearly imaged changes that appear consistent with movement of CO{sub 2} as modeled with fluid simulators.

  5. 4-D High-Resolution Seismic Reflection Monitoring of Miscible CO2 Injected into a Carbonate Reservoir

    SciTech Connect

    Richard D. Miller; Abdelmoneam E. Raef; Alan P. Byrnes; William E. Harrison

    2006-08-31

    The objective of this research project is to acquire, process, and interpret multiple high-resolution 3-D compressional wave and 2-D, 2-C shear wave seismic data in an attempt to observe changes in fluid characteristics in an oil field before, during, and after the miscible carbon dioxide (CO{sub 2}) flood that began around December 1, 2003, as part of the DOE-sponsored Class Revisit Project (DOE DE-AC26-00BC15124). Unique and key to this imaging activity is the high-resolution nature of the seismic data, minimal deployment design, and the temporal sampling throughout the flood. The 900-m-deep test reservoir is located in central Kansas oomoldic limestones of the Lansing-Kansas City Group, deposited on a shallow marine shelf in Pennsylvanian time. After 30 months of seismic monitoring, one baseline and eight monitor surveys clearly detected changes that appear consistent with movement of CO{sub 2} as modeled with fluid simulators and observed in production data.

  6. Western Sicily (Italy), a key area for understanding geothermal system within carbonate reservoirs

    NASA Astrophysics Data System (ADS)

    Montanari, D.; Bertini, G.; Botteghi, S.; Catalano, R.; Contino, A.; Doveri, M.; Gennaro, C.; Gianelli, G.; Gola, G.; Manzella, A.; Minissale, A.; Montegrossi, G.; Monteleone, S.; Trumpy, E.

    2012-12-01

    Oil exploration in western Sicily started in the late 1950s when several exploration wells were drilled, and continued with the acquisition of many seismic reflection profiles and the drilling of new wells in the1980s. The geological interpretation of these data mainly provided new insights for the definition of geometric relationships between tectonic units and structural reconstruction at depth. Although it has not produced completely satisfactory results for oil industry, this hydrocarbon exploration provided a great amount of data, resulting very suitable for geothermal resource assessment. From a geothermal point of view western Sicily is, indeed, a very promising area, with the manifestation at surface of several thermal springs, localized areas of high heat flux and thick carbonates units uninterruptedly developing from surface up top great depths. These available data were often collected with the modalities and purposes typical of oil exploration, not always the finest for geothermal exploration as in the case of temperature measurements. The multidisciplinary and integrated review of these data, specifically corrected for geothermal purposes, and the integration with new data acquired in particular key areas such as the Mazara Del Vallo site in the southern part of western Sicily, allowed us to better understand this medium-enthalpy geothermal system, to reconstruct the modalities and peculiarities of fluids circulation, and to evaluate the geothermal potentialities of western Sicily. We suggest that western Sicily can be taken as a reference for the understanding of geothermal systems developed at a regional scale within carbonate rocks. This study was performed within the framework of the VIGOR project (http://www.vigor-geotermia.it).

  7. Improved oil recovery in Mississippian carbonate reservoirs of Kansas -- near term -- Class 2. Quarterly report, April 1--June 30, 1995

    SciTech Connect

    Carr, T.; Green, D.W.; Willhite, G.P.; Schoeling, L.; Reynolds, R.

    1995-07-01

    The objective of this project is to demonstrate incremental reserves from Osagian and Meramecian (Mississippian) dolomite reservoirs in western Kansas through application of reservoir characterization to identify areas of unrecovered mobile oil. The project addresses producibility problems in two fields: specific reservoirs target the Schaben Field in Ness County, Kansas, and the Bindley Field in Hodgeman County, Kansas. The producibility problems to be addressed include inadequate reservoir characterization, drilling and completion design problems, non-optimum recovery efficiency. The results of this project will be disseminated through various technology transfer activities. General overview--progress is reported for the period from 1 April 1995 to 30 June 1995. Work in this quarter has concentrated on reservoir characterization with the initiation of technology transfer. Difficulties still remain in the drilling of the final two wells. Some preliminary work on reservoir characterization has been completed, and related technology transfer has been initiated.

  8. ADVANCED CHARACTERIZATION OF FRACTURED RESERVOIRS IN CARBONATE ROCKS: THE MICHIGAN BASIN

    SciTech Connect

    James R. Wood; William B. Harrison

    2001-04-01

    Among the accomplishments of this past reporting period are obtaining a complete landgrid for the State of Michigan and the digital processing of the high and medium resolution DEM files. We can now extract lineations from the DEMs automatically using machine algorithms. One tentative result that may be very significant is that we may be seeing manifestations of buried structures in the DEM data. We are looking at a set of extracted lineations in the northern lower peninsula that appear to follow the trend of the pinnacle reefs (Silurian) which had relief approaching 300 feet but are now buried to greater than 3000 feet. We have also extracted the dolomite alteration data from all fields and can show that this is mainly confined to the basin center. It may be related to the paleo-rift suggested by the paleomagnetic and gravity data. As reported last time, the acquisition of a 3D seismic dataset over Stoney Point Field from Marathon Oil Company, is complete and attention is being devoted to incorporating the data into the project database and utilizing it. The surface lineation study is focusing on Stoney Point Field using the high-resolution DEM data and plotting of subsurface formation top data for the main reservoir, the Trenton (Ordovician) Formation. The fault pattern at Stoney Point is well documented by Marathon and we are looking for any manifestations on the surface. The main project database is now about as complete as it will be for this project. The main goals have been met, although the scanning of the paper records will have to continue beyond the scheduled end of the project due to the sheer number of records and the increased donations of data from companies as word spread of the project. One of the unanticipated benefits of the project has been the cooperation of gas and oil companies that are or were active in the Michigan Basin in donating material to the project. Both Michigan Tech and Western Michigan continue to receive donations at an

  9. Source Term Modeling for Evaluating the Potential Impacts to Groundwater of Fluids Escaping from a Depleted Oil Reservoir Used for Carbon Sequestration

    SciTech Connect

    Cantrell, Kirk J.; Brown, Christopher F.

    2014-06-13

    In recent years depleted oil reservoirs have received special interest as carbon storage reservoirs because of their potential to offset costs through collaboration with enhanced oil recovery projects. Modeling is currently being conducted to evaluate potential risks to groundwater associated with leakage of fluids from depleted oil reservoirs used for storage of CO2. Modeling results reported here focused on understanding how toxic organic compounds found in oil will distribute between the various phases within a storage reservoir after introduction of CO2, understanding the migration potential of these compounds, and assessing potential groundwater impacts should leakage occur. Two model scenarios were conducted to evaluate how organic components in oil will distribute among the phases of interest (oil, CO2, and brine). The first case consisted of 50 wt.% oil and 50 wt.% water; the second case was 90 wt.% CO2 and 10 wt.% oil. Several key organic compounds were selected for special attention in this study based upon their occurrence in oil at significant concentrations, relative toxicity, or because they can serve as surrogate compounds for other more highly toxic compounds for which required input data are not available. The organic contaminants of interest (COI) selected for this study were benzene, toluene, naphthalene, phenanthrene, and anthracene. Partitioning of organic compounds between crude oil and supercritical CO2 was modeled using the Peng-Robinson equation of state over temperature and pressure conditions that represent the entire subsurface system (from those relevant to deep geologic carbon storage environments to near surface conditions). Results indicate that for a typical set of oil reservoir conditions (75°C, and 21,520 kPa) negligible amounts of the COI dissolve into the aqueous phase. When CO2 is introduced into the reservoir such that the final composition of the reservoir is 90 wt.% CO2 and 10 wt.% oil, a significant fraction of the oil

  10. In-filled reservoirs serving as sediment archives to analyse soil organic carbon erosion - Taking a closer look at the Karoo rangelands

    NASA Astrophysics Data System (ADS)

    Krenz, Juliane; Greenwood, Philip; Kuhn, Brigitte; Heckrath, Goswin; Foster, Ian; Boardman, John; Meadows, Michael; Kuhn, Nikolaus

    2016-04-01

    The semi-arid rangelands of the Great Karoo region in South Africa, which are nowadays characterized by badlands on the foot slopes of upland areas and complex gully systems in valley bottoms, have experienced a number of environmental changes. With the settlement of European farmers in the late 18th century agricultural activities increased, leading to overgrazing which probably acted as a trigger to land degradation. As a consequence of higher water demands and shifting rainfall patterns, many dams and small reservoirs have been constructed to provide drinking water for cattle or to facilitate irrigation during dry periods. Most of these dams are now filled with sediment and many have become breached, revealing sediment archives that can be used to analyse land use changes as well as carbon erosion and deposition during the last ca. 100 years. In this ongoing project, a combination of analytical methods that include drone imagery, landscape mapping, erosion modelling and sediment analysis have been employed to trace back the sediment origin and redistribution within the catchment, setting a special focus on the carbon history. Sediment deposits from a silted-up reservoir were analysed for varying physicochemical parameters, in order to analyse erosional and depositional patterns. A sharp decrease in total carbon content with decreasing depth suggests that land degradation during and after the post-European settlement most likely triggered erosion of the relatively fertile surface soils which presumably in-filled the reservoirs. It is assumed that the carbon-rich bottom layers of the dam deposits originate from these eroded surface soils. A combination of erosion modelling and sediment analysis will be used to determine the source areas of the depositional material and might clarify the question if land degradation in the Karoo has resulted in its return from being a net sink of carbon into a net source of carbon.

  11. Influence of Hydraulic Fracturing on Overlying Aquifers in the Presence of Leaky Abandoned Wells.

    PubMed

    Brownlow, Joshua W; James, Scott C; Yelderman, Joe C

    2016-11-01

    The association between hydrocarbon-rich reservoirs and organic-rich source rocks means unconventional oil and gas plays usually occur in mature sedimentary basins-where large-scale conventional development has already taken place. Abandoned wells in proximity to hydraulic fracturing could be affected by increased fluid pressures and corresponding newly generated fractures that directly connect (frac hit) to an abandoned well or to existing fractures intersecting an abandoned well. If contaminants migrate to a pathway hydraulically connected to an abandoned well, upward leakage may occur. Potential effects of hydraulic fracturing on upward flow through a particular type of leaky abandoned well-abandoned oil and gas wells converted into water wells were investigated using numerical modeling. Several factors that affect flow to leaky wells were considered including proximity of a leaky well to hydraulic fracturing, flowback, production, and leaky well abandonment methods. The numerical model used historical records and available industry data for the Eagle Ford Shale play in south Texas. Numerical simulations indicate that upward contaminant migration could occur through leaky converted wells if certain spatial and hydraulic conditions exist. Upward flow through leaky converted wells increased with proximity to hydraulic fracturing, but decreased when flowback and production occurred. Volumetric flow rates ranged between 0 and 0.086 m(3) /d for hydraulic-fracturing scenarios. Potential groundwater impacts should be paired with plausible transport mechanisms, and upward flow through leaky abandoned wells could be unrelated to hydraulic fracturing. The results also underscore the need to evaluate historical activities.

  12. Application of reservoir characterization and advanced technology to improve recovery and economics in a lower quality shallow shelf carbonate reservoir. End of budget period report, August 3, 1994--December 31, 1996

    SciTech Connect

    Taylor, A.R.; Hinterlong, G.; Watts, G.; Justice, J.; Brown, K.; Hickman, T.S.

    1997-12-01

    The Oxy West Welch project is designed to demonstrate how the use of advanced technology can improve the economics of miscible CO{sub 2} injection projects in a lower quality shallow shelf carbonate reservoir. The research and design phase primarily involves advanced reservoir characterization and accelerating the production response. The demonstration phase will implement the reservoir management plan based on an optimum miscible CO{sub 2} flood as designed in the initial phase. During Budget Period 1, work was completed on the CO{sub 2} stimulation treatments and the hydraulic fracture design. Analysis of the CO{sub 2} stimulation treatment provided a methodology for predicting results. The hydraulic fracture treatment proved up both the fracture design approach a and the use of passive seismic for mapping the fracture wing orientation. Although the 3-D seismic interpretation is still being integrated into the geologic model and interpretation of borehole seismic is still underway, the simulator has been enhanced to the point of giving good waterflood history matches. The simulator-forecasted results for an optimal designed miscible CO{sub 2} flood in the demonstration area gave sufficient economics to justify continuation of the project into Budget Period 2.

  13. Topographic controls on the propagation of carbon dioxide in geological reservoirs

    NASA Astrophysics Data System (ADS)

    Pegler, Sam; Huppert, Herbert; Neufeld, Jerome

    2014-05-01

    The propagation of carbon dioxide (CO2) in saline aquifers can be controlled by the topography of the caprock along which it flows. The influence of topographic trapping in basin-like structures, such as that of the Sleipner Field, is central to understanding the long-term flow and containment of CO2. We present a theoretical and experimental study of the flow of gravity currents in porous media with variations in the topography along which they flow. Our results provide a general assessment of the role of topography in the entrapment of CO2. We consider cases where the height of the topography forms an anticline from a line or point source. In all cases, it is found that the flow of CO2 transitions towards a long-term regime controlled by the shape of the caprock. We identify an intrinsic time scale before which the flow is controlled by gravitational spreading due to gradients in hydrostatic pressure, and beyond which the variations in topography are dominant. Our theoretical predictions compare well with data from a new series of laboratory experiments. Comparison between our mathematical solutions and seismic data gathered from the Sleipner Field indicates that topographic control is unlikely to explain the observed non-axisymmetric flow of CO2 plumes.

  14. Using Carbon Dioxide to Enhance Recovery of Methane from Gas Hydrate Reservoirs: Final Summary Report

    SciTech Connect

    McGrail, B. Peter; Schaef, Herbert T.; White, Mark D.; Zhu, Tao; Kulkarni, Abhijeet S.; Hunter, Robert B.; Patil, Shirish L.; Owen, Antionette T.; Martin, P F.

    2007-09-01

    Carbon dioxide sequestration coupled with hydrocarbon resource recovery is often economically attractive. Use of CO2 for enhanced recovery of oil, conventional natural gas, and coal-bed methane are in various stages of common practice. In this report, we discuss a new technique utilizing CO2 for enhanced recovery of an unconventional but potentially very important source of natural gas, gas hydrate. We have focused our attention on the Alaska North Slope where approximately 640 Tcf of natural gas reserves in the form of gas hydrate have been identified. Alaska is also unique in that potential future CO2 sources are nearby, and petroleum infrastructure exists or is being planned that could bring the produced gas to market or for use locally. The EGHR (Enhanced Gas Hydrate Recovery) concept takes advantage of the physical and thermodynamic properties of mixtures in the H2O-CO2 system combined with controlled multiphase flow, heat, and mass transport processes in hydrate-bearing porous media. A chemical-free method is used to deliver a LCO2-Lw microemulsion into the gas hydrate bearing porous medium. The microemulsion is injected at a temperature higher than the stability point of methane hydrate, which upon contacting the methane hydrate decomposes its crystalline lattice and releases the enclathrated gas. Small scale column experiments show injection of the emulsion into a CH4 hydrate rich sand results in the release of CH4 gas and the formation of CO2 hydrate

  15. Fossil fuel burning in Taylor Valley, southern Victoria Land, Antarctica: Estimating the role of scientific activities on carbon and nitrogen reservoirs and fluxes

    SciTech Connect

    Lyons, W.B.; Nezat, C.A.; Welch, K.A.; Kottmeier, S.T.; Doran, P.T.

    2000-05-01

    Particulate organic and elemental carbon and nitrogen as well as NO{sub x} fluxes from scientific activities have been computed for Taylor Valley, Antarctica ({approximately}78{degree} S). These authropogenic fluxes have been compared to both the natural fluxes and landscape reservoirs as determined from Long-Term Ecological Research (LTER) investigations in the valley. The anthropogenic, nongaseous carbon fluxes are minor compared to the natural fluxes, while the anthropogenic NO{sub x} flux may be potentially important over decadal time scales.

  16. The Carbon in Arctic Reservoirs Vulnerability Experiment (CARVE) FTS: Results From the 2012/13 Alaska Campaigns

    NASA Astrophysics Data System (ADS)

    kurosu, T. P.; Miller, C. E.; Dinardo, S.

    2013-12-01

    The Carbon in Arctic Reservoirs Vulnerability Experiment (CARVE) is an aircraft-based Earth Venture 1 mission to study the carbon balance of the Alaskan Arctic ecosystem, with a particular focus on carbon release from melting permafrost. Operating from its base in Fairbanks, AK, the CARVE aircraft covers a range of principle flight paths in the Alaskan interior, the Yukon River valley, and northern Alaska coast around Barrow and Dead Horse. Flight paths are chosen to maximize ecosystem variability and and cover burn-recovery/regrowth sequences. CARVE observations cover the Arctic Spring/Summer/Fall seasons, with multiple flights per season and principle flight paths. Science operations started in 05/2012 and are currently envisaged to continue until 2015. The CARVE suite of instruments includes flask measurements and in situ gas analyzers for CO2, CH4 and CO observations, an active/passive L-band radar for surface conditions (freeze/thaw state), and a three-band polarizing Fourier Transform Spectrometer (FTS) for column measurements of CO2, CH4, CO, and interfering species (e.g., H2O). The FTS covers the spectral regions of 4,200-4,900 cm-1 (CH4, CO), 5,800-6,400 cm-1 (CO2), and 12,900-13,200 cm-1 (O2), with a spectral resolution of 0.2 cm-1. Aircraft-based FTS science observations in Alaska have been performed since 23-05-2012. First-version data products from all CARVE instruments derived from observations during the 2012 campaign were publicly released earlier in 2013. The FTS has performed well during flight conditions, particularly with respect to vibration damping. Outstanding challenges include the need for improved spectral and radiometric calibration, as well as compensating for low signal-to-noise spectra acquired under Alaskan flight conditions. We present results from FTS column observations of CO2, CH4, and CO, observed during the 2012 and 2013 campaigns, including preliminary comparisons of CARVE FTS measurements with satellite observations of CO2

  17. The Robustness of Clumped Isotope Temperatures to Bond Reordering: Evidence from Deeply Buried Carbonate Reservoirs

    NASA Astrophysics Data System (ADS)

    MacDonald, J.; John, C. M.; Girard, J. P.

    2014-12-01

    Numerous studies have shown that clumped isotope thermometry records the temperature of precipitation for carbonate minerals in surface and near-surface environments. However, the ability of a mineral to retain its clumped isotope signature at deeper, hotter burial conditions is still debated. Dolomite has been shown to be more robust to clumped isotope bond reordering than calcite. In this contribution we measure clumped isotopes in calcite veins from Southern Europe that have been buried to up to 7 km to test the robustness of calcite and dolomite to bond reordering. First, we analysed finely crystalline dolostone matrix samples collected in industry wells from Southwest France and buried to between 2 and 5.5 km, Results indicated a temperatures of ~40-60 °C, interpreted to represent formation in an early burial environment. By contrast, coarser dolomite crystals that are petrographically distinct from the fine-grained dolomite record higher temperatures and are interpreted to reflect a deeper, hotter phase of dolomite formation. Preliminary analysis of a calcite vein from a Cretaceous dolostone in Southern Europe buried to 6.3 km records a temperature of 41±3 °C; the calcite matrix around this records a similarly low temperature. This is well below the present-day well temperature of 130-140 °C. Our results indicate that both calcite and dolomite are not affected by bond reordering at the range of depths and temperatures investigated here. Furthermore, this suggests that clumped isotope thermometry can be applied to deeply-buried samples (i.e. >5km).

  18. Geoscience/engineering characterization of the interwell environment in carbonate reservoirs based on outcrop analogs, Permian Basin, West Texas and New Mexico. Quarterly technical progress report, April 1, 1995--June 1, 1995

    SciTech Connect

    Lucia, F.J.; Kerans, C.

    1995-09-01

    The objective of this project is to investigate styles of reservoir heterogeneity that occur in low permeability pelleted wackestone/packstone facies and mixed carbonate/clastic facies found in Permian Basin reservoirs by studying similar facies exposed in the Guadalupe mountains. Specific objectives for the outcrop study include construction of a stratigraphic framework, petrophysical quantification of the framework, and testing the outcrop reservoir model for effects of reservoir heterogeneity on production performance. Specific objectives for the subsurface study parallel objectives for the outcrop study. Technical progress is reported for outcrop activities and subsurface activities.

  19. Geoscience/engineering characterization of the interwell environment in carbonate reservoirs based on outcrop analogs, Permian Basin, West Texas and New Mexico. Quarterly report, January 1--April 30, 1996

    SciTech Connect

    Lucia, F.J.; Kerans, C.

    1996-04-30

    The objective of this project is to investigate styles of reservoir heterogeneity found in low-permeability pelleted wackestone/packstone facies and mixed carbonate/clastic facies found in Permian Basin reservoirs by studying similar facies exposed in the Guadalupe Mountains. Specific objectives for the outcrop study include construction of a stratigraphic framework, petrophysical quantification of the framework, and testing the outcrop reservoir model for effects of reservoir heterogeneity on production performance. Specific objectives for the subsurface study parallel objectives for the outcrop study.

  20. Use of 3D Seismic Azimuthal Iso-Frequency Volumes for the Detection and Characterization of High Porosity/Permeability Zones in Carbonate Reservoirs

    NASA Astrophysics Data System (ADS)

    Toelle, Brian E.

    Among the most important properties controlling the production from conventional oil and gas reservoirs is the distribution of porosity and permeability within the producing geologic formation. The geometry of the pore space within these reservoirs, and the permeability associated with this pore space geometry, impacts not only where production can occur and at what flow rates but can also have significant influence on many other rock properties. Zones of high matrix porosity can result in an isotropic response for certain reservoir properties whereas aligned porosity/permeability, such as open, natural fracture trends, have been shown to result in reservoirs being anisotropic in many properties. The ability to identify zones within a subsurface reservoir where porosity/permeability is significantly higher and to characterize them according to their geometries would be of great significance when planning where new boreholes, particularly horizontal boreholes, should be drilled. The detection and characterization of these high porosity/permeability zones using their isotropic and anisotropic responses may be possible through the analysis of azimuthal (also referred to as azimuth-limited) 3D seismic volumes. During this study the porosity/permeability systems of a carbonate, pinnacle reef within the northern Michigan Basin undergoing enhanced oil recovery were investigated using selected seismic attributes extracted from azimuthal 3D seismic volumes. Based on the response of these seismic attributes an interpretation of the geometry of the porosity/permeability system within the reef was made. This interpretation was supported by well data that had been obtained during the primary production phase of the field. Additionally, 4D seismic data, obtained as part of the CO2 based EOR project, supported reservoir simulation results that were based on the porosity/permeability interpretation.

  1. Brazilian inland water bio-optical dataset to support carbon budget studies in reservoirs as well as anthropogenic impacts in Amazon floodplain lakes: Preliminary results

    NASA Astrophysics Data System (ADS)

    Barbosa, C.; Novo, E.; Ferreira, R.; Carvalho, L.; Cairo, C.; Lopes, F.; Stech, J.; Alcantara, E.

    2015-04-01

    This work presents ongoing efforts and preliminary results for building a dataset that represents the first and most comprehensive bio-optical information available on Brazilian inland waters to support the development of remote sensing algorithms for monitoring aquatic systems. From 2012 to 2014 optical and limnological data was gathered along thirteen field campaigns in five Brazilian reservoirs, in an irrigation and domestic water supply reservoir located in semi-arid northeast of the country and in Amazonian floodplain lakes, thus covering the diversity of Brazilian inland waters. At each site 20 stations, on average, were sampled to acquire profiles of the following optical variables: absorption, attenuation, scattering, and backscattering coefficients and radiances/irradiances spectra above and in-water. Alongside these measurements, water samples were collected for determining concentrations of chlorophyll-a (Chl-a), Total Suspended Solid (TSS), Total Dissolved Carbon (TDC) and its organic/inorganic fractions, CDOM absorption, phytoplankton specific absorption [aph*] and Non-Algal Particles absorption [aNAP*]. Preliminary results show that Chl-a concentrations ranged from 0.6 to 243μg/L in reservoirs and 0.90 to 92μg/L in Amazonian lakes, while TSS concentrations ranged from 0.3 to 31mg/L in reservoirs and 0.5 to 162mg/L in Amazonian lakes. In situ beam attenuation coefficients ranged from 1.4 to 16m-1 in reservoirs and 12.5 to 38m-1 in Amazonian lakes, while diffuse attenuation coefficients of downwelling irradiance over the Photosynthetically Active Radiation (Kd(PAR)) extended from 0.35 to 4.5m-1 in reservoirs and 1.69 to 13.30m-1 in Amazonian lakes. Our research group is building this dataset anticipating future demands for algorithm validation regarding OLI/Landsat8 data and ESA Sentinel missions to be launched as of 2015.

  2. Inactive and abandoned noncoal mines

    SciTech Connect

    Not Available

    1991-08-01

    Volume 1 outlines the environmental, health and safety problems at IAMS (Inactive, Abandoned Mine Sites), remediation technologies, remediation costs, the methodology states used in preparing state reports, and state summary tables. It also describes the broad range of policy options for remediation of problems associated with IAMS. Volume 2 gives state reports for inactive and abandoned noncoal mines for the following states: Alaska, Arizona, California, Colorado, Florida, Idaho, Minnesota, Missouri, Montana, Nevada, New Mexico, Oregon, South Carolina, South Dakota, Utah, Washington, Wisconsin and Wyoming. Volume 3 lists the State reports for the inactive and abandoned noncoal mines for the following states: Alabama, Arkansas, Illinois, Indiana, Iowa, Louisiana, Maine, Maryland, Mississippi, New York, North Carolina, Ohio, Oklahoma, Pennsylvania, Texas, and Virginia. A separate abstract is included for each of the 3 volumes of this set.

  3. HIGH-PRESSURE AIR INJECTION: APPLICATION IN A FRACTURED AND KARSTED DOLOMITE RESERVOIR

    SciTech Connect

    Robert Loucks; Steve Ruppel; Julia Gale; Jon Holder; Jon Olsen; Deanna Combs; Dhiraj Dembla; Leonel Gomez

    2003-12-10

    The Bureau of Economic Geology and Goldrus Producing Company have assembled a multidisciplinary team of geoscientists and engineers to evaluate the applicability of high-pressure air injection (HPAI) in revitalizing a nearly abandoned carbonate reservoir in the Permian Basin of West Texas. The characterization phase of the project is utilizing geoscientists and petroleum engineers from the Bureau of Economic Geology and the Department of Petroleum Engineering (both at The University of Texas at Austin) to define the controls on fluid flow in the reservoir as a basis for developing a reservoir model. This model will be used to define a field deployment plan that Goldrus, a small independent oil company, will implement by drilling both vertical and horizontal wells during the demonstration phase of the project. Additional reservoir data are being gathered during the demonstration phase to improve the accuracy of the reservoir model. The results of the demonstration will being closely monitored to provide a basis for improving the design of the HPAI field deployment plan. The results of the reservoir characterization field demonstration and monitoring program will be documented and widely disseminated to facilitate adoption of this technology by oil operators in the Permian Basin and elsewhere in the U.S.

  4. Effect of water-sediment regulation of the Xiaolangdi reservoir on the concentrations, characteristics, and fluxes of suspended sediment and organic carbon in the Yellow River.

    PubMed

    Xia, Xinghui; Dong, Jianwei; Wang, Minghu; Xie, Hui; Xia, Na; Li, Husheng; Zhang, Xiaotian; Mou, Xinli; Wen, Jiaojiao; Bao, Yimeng

    2016-11-15

    Water-sediment regulation (WSR) of the Xiaolangdi Reservoir in the Yellow River is different from other water conservancy projects, with sediment resuspending along the river downstream of the reservoir during water regulation while some suspended sediment depositing during sediment regulation. In this study, samples were collected before, during, and after WSR to investigate the effect of WSR on the suspended sediment and organic carbon downstream of the reservoir. The suspended sediment concentration ([SPS]) increased with the river flow velocity (V) as a power function ([SPS]=1.348V(2.519)) during the three periods. The suspended sediment grain size decreased along the river during water and sediment regulations and after WSR; they were generally below 200μm with the fine particles (<50μm) of 68.0%-93.7% and positively correlated with the flow velocity. The black carbon content in suspended sediment elevated along the river during both water and sediment regulations, and it increased with 2-50μm fraction during water regulation and with <2μm fraction during sediment regulation, suggesting that black carbon mainly exists in fine particles and is influenced by both suspended sediment source and characteristics. There was no significant difference in dissolved organic carbon (DOC) concentration during water regulation, sediment regulation, and after WSR, inferring that the effect of sediment resuspension/deposition on DOC concentration was insignificant. The contribution of DOC flux (27.3%) during WSR period to the annual flux was comparable to that (22.6%) of water, but lower than the sediment (32.5%) and particulate organic carbon (POC) (49.5%). This study suggests that WSR will exert significant influence on the concentrations, characteristics and fluxes of POC (p<0.05) and sediment (p<0.05) but have no significant influence on DOC (p>0.1) of the Yellow River.

  5. Seasonal energy storage using bioenergy production from abandoned croplands

    NASA Astrophysics Data System (ADS)

    Campbell, J. Elliott; Lobell, David B.; Genova, Robert C.; Zumkehr, Andrew; Field, Christopher B.

    2013-09-01

    Bioenergy has the unique potential to provide a dispatchable and carbon-negative component to renewable energy portfolios. However, the sustainability, spatial distribution, and capacity for bioenergy are critically dependent on highly uncertain land-use impacts of biomass agriculture. Biomass cultivation on abandoned agriculture lands is thought to reduce land-use impacts relative to biomass production on currently used croplands. While coarse global estimates of abandoned agriculture lands have been used for large-scale bioenergy assessments, more practical technological and policy applications will require regional, high-resolution information on land availability. Here, we present US county-level estimates of the magnitude and distribution of abandoned cropland and potential bioenergy production on this land using remote sensing data, agriculture inventories, and land-use modeling. These abandoned land estimates are 61% larger than previous estimates for the US, mainly due to the coarse resolution of data applied in previous studies. We apply the land availability results to consider the capacity of biomass electricity to meet the seasonal energy storage requirement in a national energy system that is dominated by wind and solar electricity production. Bioenergy from abandoned croplands can supply most of the seasonal storage needs for a range of energy production scenarios, regions, and biomass yield estimates. These data provide the basis for further down-scaling using models of spatially gridded land-use areas as well as a range of applications for the exploration of bioenergy sustainability.

  6. Integrated Outcrop and Subsurface Studies of the Interwell Environment of Carbonate Reservoirs: Clear Fork (Leonaradian Age) Reservoirs, West Texas and New Mexico, Semi-Annual

    SciTech Connect

    Ruppel, Stephen C.; Jennings, James W.; Laubach, Stephen E.

    2001-11-29

    Outcrop studies include stratigraphic and petrophysical analysis. Analysis of the detailed sequence- and cycle-scale architecture of the Clear Fork reservoir-equivalent outcrops in Apache Canyon is nearly complete. This work reveals two high-frequency transgressive-regressive sequences (HFS) in the lower Clear Fork composite depositional sequence and three HFS in the basal middle Clear Fork composite depositional sequence. A 1,800-ft transect of 1-inch-diameter samples was collected from one cycle at the Apache Canyon outcrop. The transect was sampled with 5-ft spacing, but there were some gaps due to cover and cliff, resulting in 181 samples. Permeability, porosity, and grain density were measured, and the spatial statistics are being analyzed geostatistically.

  7. High resolution reservoir architecture of late Jurassic Haynesville ramp carbonates in the Gladewater field, East Texas Salt Basin

    SciTech Connect

    Goldhammer, R.K.

    1996-12-31

    The East Texas Salt Basin contains numerous gas fields within Upper Jurassic Haynesville ramp-complex reservoirs. A sequenced-keyed, high-resolution zonation scheme was developed for the Haynesville Formation in Gladewater field by integrating core description, well-log, seismic, porosity and permeability data. The Haynesville at Gladewater represents a high-energy ramp system, localized on paleotopographic highs induced by diapirism of Callovian Age Salt (Louann). Ramp crest grainstones serve as reservoirs. We have mapped the distribution of reservoir facies within a hierarchy of upward-shallowing parasequences grouped into low-frequency sequences. The vertical stacking patterns of parasequences and sequences reflect the interplay of eustasy, sediment accumulation patterns, and local subsidence (including salt movement and compaction). In this study we draw on regional relations from analogous, Jurassic systems in Mexico to constrain the stratigraphic architecture, age model, and facies model. Additionally, salt-cored Holocene, grain-rich shoals from the Persian Gulf provide excellent facies analogs. The result is a new high-resolution analysis of reservoir architecture at a parasequence scale that links reservoir facies to depositional facies. The new stratigraphy scheme demonstrates that different geographic portions of the field have markedly distinct reservoir intervals, both in terms of total pay and the sequence-stratigraphic interval within which it occurs. Results from this study are used to evaluate infill drill well potential, in well planning, for updating reservoir models, and in refining field reserve estimates.

  8. High resolution reservoir architecture of late Jurassic Haynesville ramp carbonates in the Gladewater field, East Texas Salt Basin

    SciTech Connect

    Goldhammer, R.K. )

    1996-01-01

    The East Texas Salt Basin contains numerous gas fields within Upper Jurassic Haynesville ramp-complex reservoirs. A sequenced-keyed, high-resolution zonation scheme was developed for the Haynesville Formation in Gladewater field by integrating core description, well-log, seismic, porosity and permeability data. The Haynesville at Gladewater represents a high-energy ramp system, localized on paleotopographic highs induced by diapirism of Callovian Age Salt (Louann). Ramp crest grainstones serve as reservoirs. We have mapped the distribution of reservoir facies within a hierarchy of upward-shallowing parasequences grouped into low-frequency sequences. The vertical stacking patterns of parasequences and sequences reflect the interplay of eustasy, sediment accumulation patterns, and local subsidence (including salt movement and compaction). In this study we draw on regional relations from analogous, Jurassic systems in Mexico to constrain the stratigraphic architecture, age model, and facies model. Additionally, salt-cored Holocene, grain-rich shoals from the Persian Gulf provide excellent facies analogs. The result is a new high-resolution analysis of reservoir architecture at a parasequence scale that links reservoir facies to depositional facies. The new stratigraphy scheme demonstrates that different geographic portions of the field have markedly distinct reservoir intervals, both in terms of total pay and the sequence-stratigraphic interval within which it occurs. Results from this study are used to evaluate infill drill well potential, in well planning, for updating reservoir models, and in refining field reserve estimates.

  9. Bearing the risk of abandonment

    SciTech Connect

    Attanasio, Donna M.

    2010-05-15

    In Order Nos. 679 and 679-A, FERC adopted a policy of authorizing rate incentives for new transmission early in the development process to encourage transmission investment. The abandoned-plant cost recovery incentive creates a tension between ratepayer and investor interests, which is increasingly reflected in FERC's orders. (author)

  10. Life in the slow lane; biogeochemistry of biodegraded petroleum containing reservoirs and implications for energy recovery and carbon management

    PubMed Central

    Head, Ian M.; Gray, Neil D.; Larter, Stephen R.

    2014-01-01

    Our understanding of the processes underlying the formation of heavy oil has been transformed in the last decade. The process was once thought to be driven by oxygen delivered to deep petroleum reservoirs by meteoric water. This paradigm has been replaced by a view that the process is anaerobic and frequently associated with methanogenic hydrocarbon degradation. The thermal history of a reservoir exerts a fundamental control on the occurrence of biodegraded petroleum, and microbial activity is focused at the base of the oil column in the oil water transition zone, that represents a hotspot in the petroleum reservoir biome. Here we present a synthesis of new and existing microbiological, geochemical, and biogeochemical data that expands our view of the processes that regulate deep life in petroleum reservoir ecosystems and highlights interactions of a range of biotic and abiotic factors that determine whether petroleum is likely to be biodegraded in situ, with important consequences for oil exploration and production. Specifically we propose that the salinity of reservoir formation waters exerts a key control on the occurrence of biodegraded heavy oil reservoirs and introduce the concept of palaeopickling. We also evaluate the interaction between temperature and salinity to explain the occurrence of non-degraded oil in reservoirs where the temperature has not reached the 80–90°C required for palaeopasteurization. In addition we evaluate several hypotheses that might explain the occurrence of organisms conventionally considered to be aerobic, in nominally anoxic petroleum reservoir habitats. Finally we discuss the role of microbial processes for energy recovery as we make the transition from fossil fuel reliance, and how these fit within the broader socioeconomic landscape of energy futures. PMID:25426105

  11. Analysis of reservoir heterogeneities due to shallowing-upward cycles in carbonate rocks of the Pennsylvanian Wahoo Limestone of Northeastern Alaska. Annual report, October 1990--September 1991

    SciTech Connect

    Watts, K.

    1992-09-01

    The primary objective of this project is to develop an integrated database to characterize reservoir heterogeneities resulting from numerous small-scale shallowing-upward cycles (parasequences) comprising the carboniferous Pennsylvanian Wahoo Limestone. The Wahoo Limestone is the upper formation of an extensive carbonate platform sequence of the Carboniferous Lisburne Group which is widely exposed in the Brooks Range and is a widespread hydrocarbon reservoir unit in the subsurface of the North Slope of Alaska. A principal goal is to determine lateral and vertical variations in the complex mosaic of carbonate facies comprising the Wahoo Limestone. This report presents the preliminary results of research accomplished by a team of specialists in carbonate petrology, biostratigraphy, and diagenesis during the 1990--1991 fiscal year.It includes a summary of regional geological framework studies, a discussion conodont analyses, an overview of diagenetic studies, a brief description of progress in computerized database development, and appendices containing some of the new data on petrographic analyses, conodont analyses, and locality and sample information. Our correlation scheme, which uses cyclic stratigraphy, biostratigraphy, and cement stratigraphy, will allow interpretation of the depositional history and paleogeographic evolution of the region. We have developed predictive facies models and will make paleogeographic maps to illustrate different stages in the history of the Wahoo carbonate ramp. Our detailed analyses of the Wahoo Limestone will provide a basis for interpreting correlative rocks in the adjacent subsurface of the coastal plain of ANWR, a potential hydrocarbon lease-sale area. In a broader sense, our work will provide an excellent generic example of carbonate shallowing-upward cycles which typify carbonate sediments.

  12. Analysis of reservoir heterogeneities due to shallowing-upward cycles in carbonate rocks of the Pennsylvanian Wahoo Limestone of Northeastern Alaska

    SciTech Connect

    Watts, K.

    1992-09-01

    The primary objective of this project is to develop an integrated database to characterize reservoir heterogeneities resulting from numerous small-scale shallowing-upward cycles (parasequences) comprising the carboniferous Pennsylvanian Wahoo Limestone. The Wahoo Limestone is the upper formation of an extensive carbonate platform sequence of the Carboniferous Lisburne Group which is widely exposed in the Brooks Range and is a widespread hydrocarbon reservoir unit in the subsurface of the North Slope of Alaska. A principal goal is to determine lateral and vertical variations in the complex mosaic of carbonate facies comprising the Wahoo Limestone. This report presents the preliminary results of research accomplished by a team of specialists in carbonate petrology, biostratigraphy, and diagenesis during the 1990--1991 fiscal year.It includes a summary of regional geological framework studies, a discussion conodont analyses, an overview of diagenetic studies, a brief description of progress in computerized database development, and appendices containing some of the new data on petrographic analyses, conodont analyses, and locality and sample information. Our correlation scheme, which uses cyclic stratigraphy, biostratigraphy, and cement stratigraphy, will allow interpretation of the depositional history and paleogeographic evolution of the region. We have developed predictive facies models and will make paleogeographic maps to illustrate different stages in the history of the Wahoo carbonate ramp. Our detailed analyses of the Wahoo Limestone will provide a basis for interpreting correlative rocks in the adjacent subsurface of the coastal plain of ANWR, a potential hydrocarbon lease-sale area. In a broader sense, our work will provide an excellent generic example of carbonate shallowing-upward cycles which typify carbonate sediments.

  13. 7 CFR 767.51 - Property abandonment.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 7 Agriculture 7 2010-01-01 2010-01-01 false Property abandonment. 767.51 Section 767.51... AGRICULTURE SPECIAL PROGRAMS INVENTORY PROPERTY MANAGEMENT Property Abandonment and Personal Property Removal § 767.51 Property abandonment. The Agency will take actions necessary to secure, maintain,...

  14. 7 CFR 767.51 - Property abandonment.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 7 Agriculture 7 2011-01-01 2011-01-01 false Property abandonment. 767.51 Section 767.51... AGRICULTURE SPECIAL PROGRAMS INVENTORY PROPERTY MANAGEMENT Property Abandonment and Personal Property Removal § 767.51 Property abandonment. The Agency will take actions necessary to secure, maintain,...

  15. 32 CFR 644.496 - Abandonment.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 32 National Defense 4 2010-07-01 2010-07-01 true Abandonment. 644.496 Section 644.496 National... HANDBOOK Disposal Disposal of Buildings and Other Improvements (without the Related Land) § 644.496 Abandonment. Abandonment, as used herein, has reference to cases where the lessor or a permittor...

  16. Application of Integrated Reservoir Management and Reservoir Characterization to Optimize Infill Drilling

    SciTech Connect

    1998-01-01

    Infill drilling if wells on a uniform spacing without regard to reservoir performance and characterization foes not optimize reservoir development because it fails to account for the complex nature of reservoir heterogeneities present in many low permeability reservoirs, and carbonate reservoirs in particular. New and emerging technologies, such as geostatistical modeling, rigorous decline curve analysis, reservoir rock typing, and special core analysis can be used to develop a 3-D simulation model for prediction of infill locations.

  17. Application of Integrated Reservoir management and Reservoir Characterization to Optimize Infill Drilling

    SciTech Connect

    B. Pregger; D. Davies; D. Moore; G. Freeman; J. Callard; J.W. Nevans; L. Doublet; R. Vessell; T. Blasingame

    1997-08-31

    Infill drilling if wells on a uniform spacing without regard to reservoir performance and characterization foes not optimize reservoir development because it fails to account for the complex nature of reservoir heterogeneities present in many low permeability reservoirs, and carbonate reservoirs in particular. New and emerging technologies, such as geostatistical modeling, rigorous decline curve analysis, reservoir rock typing, and special core analysis can be used to develop a 3-D simulation model for prediction of infill locations.

  18. Application of Integrated Reservoir Management and Reservoir Characterization to Optimize Infill Drilling

    SciTech Connect

    1998-03-12

    Infill drilling if wells on a uniform spacing without regard to reservoir performance and characterization foes not optimize reservoir development because it fails to account for the complex nature of reservoir heterogeneities present in many low permeability reservoirs, and carbonate reservoirs in particular. New and emerging technologies, such as geostatistical modeling, rigorous decline curve analysis, reservoir rock typing, and special core analysis can be used to develop a 3-D simulation model for prediction of infill locations.

  19. Area of Interest 1, CO2 at the Interface. Nature and Dynamics of the Reservoir/Caprock Contact and Implications for Carbon Storage Performance

    SciTech Connect

    Mozley, Peter; Evans, James; Dewers, Thomas

    2014-10-31

    Formation reservoir/caprock interface in order to extend our work to a reservoir/caprock pair this is currently being assessed for long-term carbon storage. These analyses indicate that interface features similar to those observed at the Utah sites 3 were not observed. Although not directly related to our main study topic, one byproduct of our investigation is documentation of exceptionally high degrees of heterogeneity in the pore-size distribution of the Mount Simon Sandstone. This suggests that the unit has a greater-than-normal potential for residual trapping of supercritical CO2.

  20. Multi-scale reservoir modeling as an integrated assessment tool for geo-sequestration in the San Juan Basin

    USGS Publications Warehouse

    Young, G.; Haerer, D.; Bromhal, G.; Reeves, S.

    2007-01-01

    The Southwestern Regional Partnership on CO2 Sequestration conducted an Enhanced Coalbed Methane (ECBM)/Carbon Storage Pilot in the San Juan Basin as part of the ongoing DOE/NETL Carbon Capture and Storage Program. The primary goal of this pilot is to demonstrate the efficacy of using CO2 to enhance coalbed methane recovery particularly near reservoir abandonment pressure while also evaluating the suitability of coal seams for longer-term carbon storage. Basic geologic models of the coal seams were developed from well logs in the area. Production histories from several surrounding CBM wells were shown. To monitor the injection of up to 75,000 ton of CO2 beginning September 2007, seismic surveys and tiltmeter arrays were utilized. Larger-scale geo-hydrodynamic simulations were used to develop a regional model for the fluid dynamics of the northern San Juan Basin. Smaller-scale reservoir simulations, incorporating available laboratory and field data, were used to develop an improved understanding of reservoir dynamics within the specific 640-acre pilot area. Both modeling scales were critical to assessing the suitability of deploying commercial carbon storage programs throughout the basin. Reservoir characterization results on the optimization of total CO2 injection volume, injection rate over time, and how CO2 is expected to disperse after injection are presented. This is an abstract of a paper presented at the 2007 AIChE Annual Meeting (Salt Lake City, UT 11/4-9/2007).

  1. The bacterial flora of non-carbonated, natural mineral water from the springs to reservoir and glass and plastic bottles.

    PubMed

    Bischofberger, T; Cha, S K; Schmitt, R; König, B; Schmidt-Lorenz, W

    1990-08-01

    Quantitative and qualitative determinations of the bacterial flora of non-carbonated natural mineral water at the most important steps during bottling at a large water source yielded the following results: (i) Colony counts (on 1:10 diluted plate count agar, incubated at 20 degrees C for 14 days) for water of the five springs and the mixed water were less than 1 to 4 cfu ml-1. The Gram-negative bacterial flora (n = 50 isolates) showed a very different but constant spring specific species distributions with predominance of either eutrophic fluorescent pseudomonads, oligotrophic non-fluorescent pseudomonads or oligotrophic yellow bacteria. (ii) In the reservoir and immediately after bottling the counts were in the range of 10 cfu ml-1. But nearly 30% of the species of the spring water were no longer detectable and there was a significant increase of Gram-positive bacteria. (iii) After 1 week of storage at 20 degrees C colony counts of more than 10(5) cfu ml-1 were found in plastic bottles, but only about 10(4) cfu ml-1 in glass bottles. Besides, a very distinct change of the composition of the microflora occurred. In glass bottles slow-growing oligotrophic non-fluorescent pseudomonads, yellow bacteria and Acinetobacter predominated. In plastic bottles fast-growing eutrophic and mesotrophic fluorescent pseudomonads, Flexibacter and Acinetobacter were dominating. In mineral water, bottled into thoroughly cleaned glass bottles, colony counts of more than 10(5) cfu ml-1 were found within 4 days. In bottles, cleaned mechanically as usual, the increase was significantly slower with a maximum of only 5 x 10(3) cfu ml-1 after 8 days. The results of inoculation experiments in sterile filtered mineral and distilled water led to the suggestion that the difference between the two types of bottles is caused firstly by an inhibition of growth due to residues of cleaning detergents in the glass bottles. Growth promotion by dissolved organic substances in the plastic bottles only

  2. Petrophysical approach for S-wave velocity prediction based on brittleness index and total organic carbon of shale gas reservoir: A case study from Horn River Basin, Canada

    NASA Astrophysics Data System (ADS)

    Kim, Taeyoun; Hwang, Seho; Jang, Seonghyung

    2017-01-01

    When finding the "sweet spot" of a shale gas reservoir, it is essential to estimate the brittleness index (BI) and total organic carbon (TOC) of the formation. Particularly, the BI is one of the key factors in determining the crack propagation and crushing efficiency for hydraulic fracturing. There are several methods for estimating the BI of a formation, but most of them are empirical equations that are specific to particular rock types. We estimated the mineralogical BI based on elemental capture spectroscopy (ECS) log and elastic BI based on well log data, and we propose a new method for predicting S-wave velocity (VS) using mineralogical BI and elastic BI. The TOC is related to the gas content of shale gas reservoirs. Since it is difficult to perform core analysis for all intervals of shale gas reservoirs, we make empirical equations for the Horn River Basin, Canada, as well as TOC log using a linear relation between core-tested TOC and well log data. In addition, two empirical equations have been suggested for VS prediction based on density and gamma ray log used for TOC analysis. By applying the empirical equations proposed from the perspective of BI and TOC to another well log data and then comparing predicted VS log with real VS log, the validity of empirical equations suggested in this paper has been tested.

  3. Application of reservoir characterization and advanced technology to improve recovery and economics in a lower quality shallow shelf San Andres reservoir. Quarterly progress report, April 1--June 30, 1997

    SciTech Connect

    Taylor, A.R.; Hickman, T.S.; Justice, J.J.

    1997-07-30

    The Class 2 Project at West Welch was designed to demonstrate the use of advanced technologies to enhance the economics of improved oil recovery (IOR) projects in lower quality Shallow Shelf Carbonate (SSC) reservoirs, resulting in recovery of additional oil that would otherwise be left in the reservoir at project abandonment. Accurate reservoir description is critical to the effective evaluation and efficient design of IOR projects in the heterogeneous SSC reservoirs. Therefore, the majority of Budget Period 1 was devoted to reservoir characterization. Technologies being demonstrated include: advanced petrophysics; three-dimensional seismic; cross-well bore tomography; advanced reservoir simulation; CO{sub 2} stimulation treatments; hydraulic fracturing design and monitoring; and mobility control agents. During the quarter, cross well seismic work continued, using the revised processing software. The validity of the seismic-guided mapping was confirmed by the drilling of a well. Revised CO{sub 2} performance projects were run using the enhanced geologic model in which the seismic data had been incorporated. Facilities for supplying and distributing CO{sub 2} to the area were designed and bids solicited for the materials and construction.

  4. Spatio-temporal variations of carbon dioxide and its gross emission regulated by artificial operation in a typical hydropower reservoir in China.

    PubMed

    Li, Zhe; Zhang, Zengyu; Xiao, Yan; Guo, Jinsong; Wu, Shengjun; Liu, Jing

    2014-05-01

    Supersaturation and excess emission of greenhouse gases in freshwater reservoirs have received a great deal of attention in recent years. Although impoundment of reservoirs has been shown to contribute to the net emission of greenhouse gases, reservoir age, geographical distribution, submerged soil type and artificial regulation also have a great impact on their emissions. To examine how large scale reservoir operation impact the water column CO2 and its air-water interface flux, a field study was conducted in 2010 to evaluate potential ecological processes that regulate the partial pressure of CO2 (pCO2) in the water column in the Pengxi River backwater area (PBA), a typical tributary in the Three Gorges Reservoir, China. Measurements of total alkalinity (TA), pH and water temperature were applied to compute the pCO2. And this approach was also validated by calculation of pCO2 from the dissolved inorganic carbon data of samples. Partial least squares (PLS) regression was used to determine how the dynamics of the water pCO2 were related to the available variables. The estimated pCO2 in our sample ranged from 26 to 4,087 μatm in the surface water. During low water operation from July to early September, there was an obvious pCO2 stratification, and pCO2 in the surface was almost unsaturated. This phenomenon was also observed in the spring bloom during discharge period. Conversely, there was no significant pCO2 stratification and the entire water column was supersaturated during high water operation from November to the following February. Significant correlation was observed between the magnitude of pCO2, DO and chlorophyll a, suggesting that phytoplankton dynamics regulate pCO2 in the PBA. The average areal rate of CO2 emissions from the Pengxi River ranged from 18.06 to 48.09 mmol m(-2) day(-1), with an estimated gross CO2 emission from the water surface of 14-37 t day(-1) in this area in 2010. Photosynthesis and respiration rates by phytoplankton might be the

  5. Role of sea-level change in deep water deposition along a carbonate shelf margin, Early and Middle Permian, Delaware Basin: implications for reservoir characterization

    NASA Astrophysics Data System (ADS)

    Li, Shunli; Yu, Xinghe; Li, Shengli; Giles, Katherine A.

    2015-04-01

    The architecture and sedimentary characteristics of deep water deposition can reflect influences of sea-level change on depositional processes on the shelf edge, slope, and basin floor. Outcrops of the northern slope and basin floor of the Delaware Basin in west Texas are progressively exposed due to canyon incision and road cutting. The outcrops in the Delaware Basin were measured to characterize gravity flow deposits in deep water of the basin. Subsurface data from the East Ford and Red Tank fields in the central and northeastern Delaware Basin were used to study reservoir architectures and properties. Depositional models of deep water gravity flows at different stages of sea-level change were constructed on the basis of outcrop and subsurface data. In the falling-stage system tracts, sandy debris with collapses of reef carbonates are deposited on the slope, and high-density turbidites on the slope toe and basin floor. In the low-stand system tracts, deep water fans that consist of mixed sand/mud facies on the basin floor are comprised of high- to low-density turbidites. In the transgression and high-stand system tracts, channel-levee systems and elongate lobes of mud-rich calciturbidite deposits formed as a result of sea level rise and scarcity of sandy sediment supply. For the reservoir architecture, the fan-like debris and high-density turbidites show high net-to-gross ratio of 62 %, which indicates the sandiest reservoirs for hydrocarbon accumulation. Lobe-like deep water fans with net-to-gross ratio of 57 % facilitate the formation of high quality sandy reservoirs. The channel-levee systems with muddy calciturbidites have low net-to-gross ratio of 30 %.

  6. Application of Integrated Reservoir Management and Reservoir Characterization to Optimize Infill Drilling

    SciTech Connect

    P. K. Pande

    1998-10-29

    Initial drilling of wells on a uniform spacing, without regard to reservoir performance and characterization, must become a process of the past. Such efforts do not optimize reservoir development as they fail to account for the complex nature of reservoir heterogeneities present in many low permeability reservoirs, and carbonate reservoirs in particular. These reservoirs are typically characterized by: o Large, discontinuous pay intervals o Vertical and lateral changes in reservoir properties o Low reservoir energy o High residual oil saturation o Low recovery efficiency

  7. Secondary Forests from Agricultural Abandonment in Amazonia 2000-2009

    NASA Technical Reports Server (NTRS)

    Morton, Douglas

    2010-01-01

    Ongoing negotiations to include reducing emissions from tropical deforestation and forest degradation (REDD+) in a post-Kyoto climate agreement highlight the critical role of satellite data for accurate and transparent accounting of forest cover changes. In addition to deforestation and degradation, knowledge of secondary forest dynamics is essential for full carbon accounting under REDD+. Land abandonment to secondary forests also frames one of the key tradeoffs for agricultural production in tropical forest countries-whether to incentivize secondary forest growth (for carbon sequestration and biodiversity conservation) or low-carbon expansion of agriculture or biofuels production in areas of secondary forests. We examined patterns of land abandonment to secondary forest across the arc of deforestation in Brazil and Bolivia using time series of annual Landsat and MODIS data from 2000-2009. Rates of land abandonment to secondary forest during 2002-2006 were less than 5% of deforestation rates in these years. Small areas of new secondary forest were scattered across the entire arc of deforestation, rather than concentrated in any specific region of the basin. Taken together, our analysis of the satellite data record emphasizes the difficulties of addressing the pool of new secondary forests in the context of REDD+ in Amazonia. Due to the small total area of secondary forests, land sparing through agricultural intensification will be an important element of efforts to reduce deforestation rates under REDD+ while improving agricultural productivity in Amazonia.

  8. Multiple factors drive regional agricultural abandonment.

    PubMed

    Osawa, Takeshi; Kohyama, Kazunori; Mitsuhashi, Hiromune

    2016-01-15

    An understanding of land-use change and its drivers in agroecosystems is important when developing adaptations to future environmental and socioeconomic pressures. Agricultural abandonment occurs worldwide with multiple potentially positive and negative consequences; however, the main factors causing agricultural abandonment in a country i.e., at the macro scale, have not been identified. We hypothesized that socio-environmental factors driving agricultural abandonment could be summarized comprehensively into two, namely "natural" and "social", and the relative importance of these differs among regions. To test this postulate, we analyzed the factors currently leading to agricultural abandonment considering ten natural environment variables (e.g., temperature) and five social variables (e.g., number of farmers) using the random forest machine learning method after dividing Japan into eight regions. Our results showed that agricultural abandonment was driven by various socio-environmental factors, and the main factors leading to agricultural abandonment differed among regions, especially in Hokkaido in northern Japan. Hokkaido has a relatively large area of concentrated farmland, and abandonment might have resulted from the effectiveness of cultivation under specific climate factors, whereas the other regions have relatively small areas of farmland with many elderly part-time farmers. In such regions, abandonment might have been caused by the decreasing numbers of potential farmers. Thus, two different drivers of agricultural abandonment were found: inefficient cultivation and decreasing numbers of farmers. Therefore, agricultural abandonment cannot be prevented by adopting a single method or policy. Agricultural abandonment is a significant problem not only for food production but also for several ecosystem services. Governments and decision-makers should develop effective strategies to prevent further abandonment to ensure sustainable future management of agro-ecosystems.

  9. Reservoir-scale stratigraphic controls on the distribution of vertical fractures: insights from a 200-m thick carbonate platform exposure (Sorrento peninsula, Italy)

    NASA Astrophysics Data System (ADS)

    Corradetti, Amerigo; Tavani, Stefano; Iannace, Alessandro; Vinci, Francesco; Pirmez, Carlos; Torrieri, Stefano; Giorgioni, Maurizio; Strauss, Christoph; Pignalosa, Antonio; Mazzoli, Stefano

    2016-04-01

    Through-going fractures cutting across numerous beds are often invoked to match large-scale permeability patterns in tight carbonate reservoirs. Despite the importance of these structures for fluid flow simulations, there are only few field analogues allowing estimating many of their parameters, including spacing and vertical extent, which are instead required to populate reservoir models. This is mostly due to the fact that the study of these reservoir-scale fractures requires very wide outcrops that for several reasons, including logistics, are rarely analysed. Nevertheless, recent improvements in the construction of digital models of outcrops can greatly help to overcome many logistic issues. In this work, we present the results obtained from combined field and remote sensing observations of a 300-meters wide and 200-meters high carbonate platform reservoir analogue in the Sorrento peninsula (Italy). The outcrop consists of a nearly vertical cliff exposing alternating gently-dipping shallow-water limestones and dolomites characterized by the presence of several vertical fractures of different size and hence with different vertical connectivity. In order to gather both stratigraphic and structural (i.e. fracture) data, we integrated field measurements and stratigraphic logs with a remote sensing study carried out on a digital model of the cliff, made by means of multi-view stereo-photogrammetry. This combined field and remote sensing study has allowed us to recognize that major bed-perpendicular through-going fractures are vertically discontinuous due to variable segmentation and fracture distribution within the country rock. In particular, we observed that large (i.e. tens of meters in height) fractures pass across medium to thick beds (bed thickness > 30 cm), while they arrest against packages made of thinly stratified layers of dolomites. In essence, through-going fractures arrest on weak levels, consisting of thinly bedded layers interposed between packages

  10. Experimental and molecular modeling study of the three-phase behavior of (n-decane + carbon dioxide + water) at reservoir conditions.

    PubMed

    Forte, Esther; Galindo, Amparo; Trusler, J P Martin

    2011-12-15

    Knowledge of the phase behavior of mixtures of oil with carbon dioxide and water is essential for reservoir engineering, especially in the processes of enhanced oil recovery and geological storage of carbon dioxide. However, for a comprehensive understanding, the study of simpler systems needs to be completed. In this work the system (n-decane + carbon dioxide + water) was studied as a model (oil + carbon dioxide + water) mixture. To accomplish our aim, a new analytical apparatus to measure phase equilibria at high pressure was designed with maximum operating temperature and pressure of 423 K and 45 MPa, respectively. The equipment relies on recirculation of two coexisting phases using a two-channel magnetically operated micropump designed during this work, with sampling and online compositional analysis by gas chromatography. The apparatus has been validated by comparison with published isothermal vapor-liquid equilibrium data for the binary system (n-decane + carbon dioxide). New experimental data have been measured for the system (n-decane + carbon dioxide + water) under conditions of three-phase equilibria. Data for the three coexisting phases have been obtained on five isotherms at temperatures from 323 to 413 K and at pressures up to the point at which two of the phases become critical. The experimental work is complemented here with a theoretical effort in which we developed models for these molecules within the framework of the statistical associating fluid theory for potentials of variable range (SAFT-VR). The phase behavior of the three binary subsystems was calculated using this theory, and where applicable, a modification of the Hudson and McCoubrey combining rules was used to treat the systems predictively. The experimental data obtained for the ternary mixture are compared to the predictions of the theory. Furthermore, a detailed analysis of the ternary mixture is carried out based on comparison with available data for the constituent binary

  11. Meandering stream reservoirs

    SciTech Connect

    Richardson, J.G.; Sangree, J.B.; Sneider, R.M.

    1987-12-01

    Braided stream deposits, described in a previous article in this series, and meandering stream deposits commonly are excellent reservoirs. Meandering high-sinuousity channels are found on flat alluvial plains with slopes less than 1 1/2/sup 0/ (0.026 rad). These rivers have wide ranges of discharges from low-water flow to flood stage. Two main processes are responsible for development of sand bodies. These are point-bar deposits left by channel migration, and oxbow-lake deposits left in loops of the river course abandoned when the stream cuts a new course during flooding. Extremely high floods spill over the banks and deposit sheets of very fine sand, silt, and clay onto the flood plain.

  12. Incidence of Candidatus Liberibacter asiaticus infection in abandoned citrus occurring in proximity to commercially managed groves.

    PubMed

    Tiwari, Siddharth; Lewis-Rosenblum, Hannah; Pelz-Stelinski, Kirsten; Stelinski, Lukasz L

    2010-12-01

    Huanglongbing is one of the most devastating diseases of citrus (Citrus spp.). One management tactic against huanglongbing is aggressive management of the vector, the Asian citrus psyllid (Diaphorina citri Kuwayama), with insecticide applications. However, D. citri in abandoned groves are not controlled and therefore pose a risk of reinfestation for nearby commercial citrus. These abandoned groves could serve as a reservoir for the vector, as well as a source of the presumed causal agent for huanglongbing in Florida, Candidatus Liberibacter asiaticus (Las). The current study was conducted to determine the degree to which Las is present in abandoned Florida citrus groves and to compare relative inoculum levels in nearby managed and abandoned groves during times of the year when D. citri are abundant (June, July, and August). In addition, the movement of Las by dispersing D. citri adults from inner and edge rows of abandoned grove plots to the corresponding rows of managed plots was quantified during the same 3 mo. The results of the current study confirmed the presence of Las in both D. citri and plant tissue in abandoned groves at statistically equivalent levels to those in nearby managed groves. The mean number of D. citri adults dispersing from abandoned to managed grove plots ranged from 7.25 +/- 1.70 to 70.25 +/- 21.25 per 4-d intervals. Of those, the mean number of dispersing D. citri adults that were carrying the Las pathogen ranged from 1.00 +/- 0.58 to 1.50 +/- 0.50. Our results indicate that abandoned citrus groves are a significant source of Ca. Las and that dispersing D. citri move this pathogen into nearby managed groves.

  13. An integrated approach for determination of pore-type distribution in carbonate-siliciclastic Asmari Reservoir, Cheshmeh-Khosh Oilfield, SW Iran

    NASA Astrophysics Data System (ADS)

    Gharechelou, Sajjad; Amini, Abdolhossein; Kadkhodaie-Ilkhchi, Ali; Moradi, Babak

    2015-10-01

    This paper presents an integrated pore type study at microscopic (core data), mesoscopic (well logs) and megascopic scales (3D seismic data) in the mixed carbonate-siliciclastic Asmari Reservoir of the Cheshmeh-Khosh Oilfield, SW Iran. Firstly, pore types are determined in a microscopic scale based on petrographic studies of thin sections. Well logs and nuclear magnetic resonance (NMR) log data are employed for pore type determination based on a velocity deviation log (mesoscopic scale). For each pore type subclass, a suite of physical rock properties including average poroperm values, T2 distribution, capillary pressure, pore size distribution and depositional texture are calculated. For this purpose, the NMR log, mercury injection capillary pressure data and core descriptions are interpreted in an integrated approach. Capillary pressure and pore size distribution in each pore type class are determined by mercury injection capillary pressure tests and synthesis of a continuous capillary pressure log from the NMR log (pseudo Pc curves). For dynamic behavior examination of the reservoir, the pore types are analysed in the framework of hydraulic flow units. Finally, 3D post-stacked seismic data are converted to a cube of pore types based on acoustic impedance inversion and seismic attributes. The methodology of this study is accomplished by using core and log data from three key wells and a 3D post-stack seismic data from the studied field. Lastly, a map of pore type distribution is established to provide a clue on the high and low permeable zones of the field. The presented methodology signifies reservoir anatomy on micro to mega scales.

  14. Discharge determines production of, decomposition of and quality changes in dissolved organic carbon in pre-dams of drinking water reservoirs.

    PubMed

    Morling, Karoline; Herzsprung, Peter; Kamjunke, Norbert

    2017-01-15

    Pre-dams are small reservoirs constructed upstream of the main drinking water reservoirs and are used for nutrient removal and sediment trapping. Little is known about the role of pre-dams regarding the production and decomposition of dissolved organic carbon (DOC) in relation to discharge and how this affects the quality of DOC in the water. We combined quantitative and qualitative investigations under different hydrological conditions at three pre-dams exhibiting a gradient from oligotrophic/high-DOC to eutrophic/low-DOC. All pre-dams were mainly autotrophic in their upper water layers. The ratio of OC production to total gained OC (i.e. OC import+OC production) decreased with increasing discharge. On average, 0-30% of the total gained OC was produced within the pre-dams. The amount of microbially decomposed DOC increased with the average water residence time (WRT) and with the trophic status of the pre-dams. Radiocarbon analyses of respired CO2 revealed that heterotrophic bacteria preferentially utilized old DOC components (195-395years before present) under base flow conditions, whereas younger components (modern, i.e. OC produced after 1950) were utilized at high discharge. DOC quality changed significantly over the year within the pre-dams: High proportions of algae-derived DOC were observed during base flow in summer, and the freshness index (β/α ratio) decreased significantly with higher discharges. DOC production and quality changes in response to hydrological conditions should be considered for future water quality management in reservoirs, as climate scenarios for temperate regions predict decreased runoffs leading to longer WRT and increased eutrophication and production of algae-derived OC.

  15. Interaction Between CO2-Rich Sulfate Solutions and Carbonate Reservoir Rocks from Atmospheric to Supercritical CO2 Conditions: Experiments and Modeling

    NASA Astrophysics Data System (ADS)

    Cama, J.; Garcia-Rios, M.; Luquot, L.; Soler Matamala, J. M.

    2014-12-01

    A test site for CO2 geological storage is situated in Hontomín (Spain) with a reservoir rock that is mainly composed of limestone. During and after CO2 injection, the resulting CO2-rich acid brine gives rise to the dissolution of carbonate minerals (calcite and dolomite) and gypsum (or anhydrite at depth) may precipitate since the reservoir brine contains sulfate. Experiments using columns filled with crushed limestone or dolostone were conducted under different P-pCO2 conditions (atmospheric: 1-10-3.5 bar; subcritical: 10-10 bar; and supercritical: 150-34 bar), T (25, 40 and 60 ºC) and input solution compositions (gypsum-undersaturated and gypsum-equilibrated solutions). We evaluated the effect of these parameters on the coupled reactions of calcite/dolomite dissolution and gypsum/anhydrite precipitation. The CrunchFlow and PhreeqC (v.3) numerical codes were used to perform reactive transport simulations of the experiments. Under the P-pCO2-T conditions, the volume of precipitated gypsum was smaller than the volume of dissolved carbonate minerals, yielding an increase in porosity (Δporosity up to ≈ 4%). A decrease in T favored limestone dissolution regardless of pCO2 owing to increasing undersaturation with decreasing temperature. However, gypsum precipitation was favored at high T and under atmospheric pCO2 conditions but not at high T and under 10 bar of pCO2 conditions. The increase in limestone dissolution with pCO2 was directly attributed to pH, which was more acidic at higher pCO2. Increasing pCO2, carbonate dissolution occurred along the column whereas it was localized in the very inlet under atmospheric conditions. This was due to the buffer capacity of the carbonic acid, which maintains pH at around 5 and keeps the solution undersaturated with respect to calcite and dolomite along the column. 1D reactive transport simulations reproduced the experimental data (carbonate dissolution and gypsum precipitation for different P-pCO2-T conditions). Drawing

  16. LOSCAR: Long-term Ocean-atmosphere-Sediment CArbon cycle Reservoir Model v2.0.4

    NASA Astrophysics Data System (ADS)

    Zeebe, R. E.

    2012-01-01

    The LOSCAR model is designed to efficiently compute the partitioning of carbon between ocean, atmosphere, and sediments on time scales ranging from centuries to millions of years. While a variety of computationally inexpensive carbon cycle models are already available, many are missing a critical sediment component, which is indispensable for long-term integrations. One of LOSCAR's strengths is the coupling of ocean-atmosphere routines to a computationally efficient sediment module. This allows, for instance, adequate computation of CaCO3 dissolution, calcite compensation, and long-term carbon cycle fluxes, including weathering of carbonate and silicate rocks. The ocean component includes various biogeochemical tracers such as total carbon, alkalinity, phosphate, oxygen, and stable carbon isotopes. LOSCAR's configuration of ocean geometry is flexible and allows for easy switching between modern and paleo-versions. We have previously published applications of the model tackling future projections of ocean chemistry and weathering, pCO2 sensitivity to carbon cycle perturbations throughout the Cenozoic, and carbon/calcium cycling during the Paleocene-Eocene Thermal Maximum. The focus of the present contribution is the detailed description of the model including numerical architecture, processes and parameterizations, tuning, and examples of input and output. Typical CPU integration times of LOSCAR are of order seconds for several thousand model years on current standard desktop machines. The LOSCAR source code in C can be obtained from the author by sending a request to loscar.model@gmail.com.

  17. Analysis of real-time reservoir monitoring : reservoirs, strategies, & modeling.

    SciTech Connect

    Mani, Seethambal S.; van Bloemen Waanders, Bart Gustaaf; Cooper, Scott Patrick; Jakaboski, Blake Elaine; Normann, Randy Allen; Jennings, Jim; Gilbert, Bob; Lake, Larry W.; Weiss, Chester Joseph; Lorenz, John Clay; Elbring, Gregory Jay; Wheeler, Mary Fanett; Thomas, Sunil G.; Rightley, Michael J.; Rodriguez, Adolfo; Klie, Hector; Banchs, Rafael; Nunez, Emilio J.; Jablonowski, Chris

    2006-11-01

    survivability issues. Our findings indicate that packaging represents the most significant technical challenge associated with application of sensors in the downhole environment for long periods (5+ years) of time. These issues are described in detail within the report. The impact of successful reservoir monitoring programs and coincident improved reservoir management is measured by the production of additional oil and gas volumes from existing reservoirs, revitalization of nearly depleted reservoirs, possible re-establishment of already abandoned reservoirs, and improved economics for all cases. Smart Well monitoring provides the means to understand how a reservoir process is developing and to provide active reservoir management. At the same time it also provides data for developing high-fidelity simulation models. This work has been a joint effort with Sandia National Laboratories and UT-Austin's Bureau of Economic Geology, Department of Petroleum and Geosystems Engineering, and the Institute of Computational and Engineering Mathematics.

  18. EXPLOITATION AND OPTIMIZATION OF RESERVOIR PERFORMANCE IN HUNTON FORMATION, OKLAHOMA

    SciTech Connect

    Mohan Kelkar

    2002-09-30

    The main objectives of the proposed study are as follows: (1) To understand and evaluate an unusual primary oil production mechanism which results in decreasing (retrograde) oil cut (ROC) behavior as reservoir pressure declines. (2) To improve calculations of initial oil in place so as to determine the economic feasibility of completing and producing a well. (3) To optimize the location of new wells based on understanding of geological and petrophysical properties heterogeneities. (4) To evaluate various secondary recovery techniques for oil reservoirs producing from fractured formations. (5) To enhance the productivity of producing wells by using new completion techniques. These objectives are important for optimizing field performance from West Carney Field located in Lincoln County, Oklahoma. The field, which was discovered in 1980, produces from Hunton Formation in a shallow-shelf carbonate reservoir. The early development in the field was sporadic. Many of the initial wells were abandoned due to high water production and constraints in surface facilities for disposing excess produced water. The field development began in earnest in 1995 by Altex Resources. They had recognized that production from this field was only possible if large volumes of water can be disposed. Being able to dispose large amounts of water, Altex aggressively drilled several producers. With few exceptions, all these wells exhibited similar characteristics. The initial production indicated trace amount of oil and gas with mostly water as dominant phase. As the reservoir was depleted, the oil cut eventually improved, making the overall production feasible. The decreasing oil cut (ROC) behavior has not been well understood. However, the field has been subjected to intense drilling activity because of prior success of Altex Resources. In this work, we will investigate the primary production mechanism by conducting several core flood experiments. After collecting cores from representative

  19. Carbon dioxide emission rate of Kīlauea Volcano: Implications for primary magma and the summit reservoir

    USGS Publications Warehouse

    Gerlach, T.M.; McGee, K.A.; Elias, T.; Sutton, A.J.; Doukas, M.P.

    2002-01-01

     We report a CO2 emission rate of 8500 metric tons per day (t d−1) for the summit of Kīlauea Volcano, several times larger than previous estimates. It is based on three sets of measurements over 4 years of synchronous SO2 emission rates and volcanic CO2/SO2concentration ratios for the summit correlation spectrometer (COSPEC) traverse. Volcanic CO2/SO2 for the traverse is representative of the global ratio for summit emissions. The summit CO2 emission rate is nearly constant, despite large temporal variations in summit CO2/SO2 and SO2 emission rates. Summit CO2 emissions comprise most of Kīlauea's total CO2 output (∼9000 t d−1). The bulk CO2 content of primary magma determined from CO2emission and magma supply rate data is ∼0.70 wt %. Most of the CO2 is present as exsolved vapor at summit reservoir depths, making the primary magma strongly buoyant. Turbulent mixing with resident reservoir magma, however, prevents frequent eruptions of buoyant primary magma in the summit region. CO2 emissions confirm that the magma supply enters the edifice through the summit reservoir. A persistent several hundred parts per million CO2 anomaly arises from the entry of magma into the summit reservoir beneath a square kilometer area east of Halemaumau pit crater. Since most of the CO2 in primary magma is degassed in the summit, the summit CO2 emission rate is an effective proxy for the magma supply rate. Both scrubbing of SO2 and solubility controls on CO2and S in basaltic melt cause high CO2/SO2 in summit emissions and spatially uncorrelated distributions of CO2 and SO2 in the summit plume.

  20. 32 CFR 636.31 - Abandoned vehicles.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 32 National Defense 4 2012-07-01 2011-07-01 true Abandoned vehicles. 636.31 Section 636.31... CRIMINAL INVESTIGATIONS MOTOR VEHICLE TRAFFIC SUPERVISION (SPECIFIC INSTALLATIONS) Fort Stewart, Georgia § 636.31 Abandoned vehicles. (a) Any MP or DOD police officer who finds or has knowledge of a...

  1. 32 CFR 636.31 - Abandoned vehicles.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 32 National Defense 4 2013-07-01 2013-07-01 false Abandoned vehicles. 636.31 Section 636.31... CRIMINAL INVESTIGATIONS MOTOR VEHICLE TRAFFIC SUPERVISION (SPECIFIC INSTALLATIONS) Fort Stewart, Georgia § 636.31 Abandoned vehicles. (a) Any MP or DOD police officer who finds or has knowledge of a...

  2. 32 CFR 636.31 - Abandoned vehicles.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 32 National Defense 4 2014-07-01 2013-07-01 true Abandoned vehicles. 636.31 Section 636.31... CRIMINAL INVESTIGATIONS MOTOR VEHICLE TRAFFIC SUPERVISION (SPECIFIC INSTALLATIONS) Fort Stewart, Georgia § 636.31 Abandoned vehicles. (a) Any MP or DOD police officer who finds or has knowledge of a...

  3. Evolution of abandoned underground hardrock mine closures by the Texas abandoned mine land reclamation program

    SciTech Connect

    Rhodes, M.J.

    1997-12-31

    The Texas Abandoned Mine Land (AML) Reclamation program began investigating, designing and implementing hard rock abandoned underground mine closures, after a young boy fell to his death in an abandoned mine opening in 1982. This paper discusses the evolution of abandoned hard rock mine closures in west Texas, by the Texas AML program in response to the development of abandoned underground mine resource information. Case histories are presented of the Texas AML program`s efforts in west Texas including: mine history summaries; site characterization, environmental assessment; design and construction planning considerations, and construction cost information.

  4. Design and Implementation of a CO(2) Flood Utilizing Advanced Reservoir Characterization and Horizontal Injection Wells in Shallow Shelf Carbonate Approaching Waterflood Depletion

    SciTech Connect

    1997-12-31

    The work reported herein covers select tasks in Budget Phase 11. The principle Task in Budget Phase 11 included in this report is Field Demonstration. Completion of many of the Field Demonstration tasks during the last report period enabled an optimum carbon dioxide (CO{sub 2}) flood project to be designed, economically evaluated, and implemented in the field. Field implementation of the project commenced during late 1995, with actual C0{sub 2} injection commencing in mid-July, 1996. This report summarizes activities incurred following initial project start-up, towards the goal of optimizing project performance. The current project has focused on reducing initial investment cost by utilizing horizontal injection wells and concentrating the project in the best productivity area of the field. An innovative C0{sub 2} purchase agreement (no take-or-pay provisions, C0{sub 2} purchase price tied to West Texas Intermediate (WTI) crude oil price) and gas recycle agreement (expensing costs as opposed to a large upfront capital investment for compression) were negotiated to further improve the project economics. The Grayburg-San Andres section had previously been divided into multiple zones based on the core study and gamma ray markers that correlate wells within the Unit. Each zone was mapped as continuous across the field. Previous core studies concluded that the reservoir quality in the South Cowden Unit (SCU) is controlled primarily by the distribution of a bioturbated and diagenetically-altered rock type with a distinctive chaotic texture. The chaotic modifier is derived from the visual effect of pervasive, small-scale intermixing of tan oil-stained reservoir rock with tight gray non- reservoir rock. The chaotic reservoir rock extends from Zone C (4780`-4800`) to the lower part of Zone F (4640`-4680`). Zones D (4755`-4780`) and E (4680`-4755`) are considered the main floodable zones, though Zone F is also productive and Zone C is productive above the oil- water contact

  5. Comparative modeling of fault reactivation and seismicity in geologic carbon storage and shale-gas reservoir stimulation

    NASA Astrophysics Data System (ADS)

    Rutqvist, Jonny; Rinaldi, Antonio; Cappa, Frederic

    2016-04-01

    The potential for fault reactivation and induced seismicity are issues of concern related to both geologic CO2 sequestration and stimulation of shale-gas reservoirs. It is well known that underground injection may cause induced seismicity depending on site-specific conditions, such a stress and rock properties and injection parameters. To date no sizeable seismic event that could be felt by the local population has been documented associated with CO2 sequestration activities. In the case of shale-gas fracturing, only a few cases of felt seismicity have been documented out of hundreds of thousands of hydraulic fracturing stimulation stages. In this paper we summarize and review numerical simulations of injection-induced fault reactivation and induced seismicity associated with both underground CO2 injection and hydraulic fracturing of shale-gas reservoirs. The simulations were conducted with TOUGH-FLAC, a simulator for coupled multiphase flow and geomechanical modeling. In this case we employed both 2D and 3D models with an explicit representation of a fault. A strain softening Mohr-Coulomb model was used to model a slip-weakening fault slip behavior, enabling modeling of sudden slip that was interpreted as a seismic event, with a moment magnitude evaluated using formulas from seismology. In the case of CO2 sequestration, injection rates corresponding to expected industrial scale CO2 storage operations were used, raising the reservoir pressure until the fault was reactivated. For the assumed model settings, it took a few months of continuous injection to increase the reservoir pressure sufficiently to cause the fault to reactivate. In the case of shale-gas fracturing we considered that the injection fluid during one typical 3-hour fracturing stage was channelized into a fault along with the hydraulic fracturing process. Overall, the analysis shows that while the CO2 geologic sequestration in deep sedimentary formations are capable of producing notable events (e

  6. Crosswell Seismic Amplitude-Versus-Offset for Detailed Imaging of Facies and Fluid Distribution within Carbonate Oil Reservoirs

    SciTech Connect

    Wayne Pennington; Mohamed Ibrahim; Roger Turpening; Sean Trisch; Josh Richardson; Carol Asiala; Walid Mabrouk

    2008-09-30

    Crosswell seismic surveys were conducted at two fields in northern Michigan. One of these, Springdale, included two monitor wells that are located external to the reef, and the other, Coldspring, employed two production wells within the reef. The Springdale wells extended to much greater depths than the reef, and imaging was conducted from above and from beneath the reef. The resulting seismic images provide the best views of pinnacle Niagaran reefs obtained to date. The tops of the reservoirs can be clearly distinguished, and their lateral extent or dipping edges can be observed along the profile. Reflecting events internal to the reef are evident; some of them are fairly continuous across the reef and others are discontinuous. Inversion of the seismic data indicates which events represent zones of higher porosity and which are lower porosity or even anhydrite plugged. The full stacked image includes angles that are beyond critical for many of the interfaces, and some reflections are visible only for a small range of angles, presumably near their critical angle. Stacking these angles in provides an opportunity for these events to be seen on the stacked image, where otherwise they would have been unrecognized. For inversion, however, the complexity associated with phase changes beyond critical can lead to poor results, and elastic inversion of partial angle stacks may be best conducted with restrictions to angles less than critical. Strong apparent attenuation of signals occurs when seismic ray paths pass through the upper part of the Springdale reservoir; this may be due to intrinsic attenuation and/or scattering of events due to the locally strongly varying gas saturation and extremely low fluid pressures. Signal-to-noise limitations become evident far from the source well in the Coldspring study, probably because the raw data were strongly affected by tube-wave noise generated by flow through the perforation of the receiver well. The seismic images obtained, and

  7. [Changes of plant community biomass and soil nutrients during the vegetation succession on abandoned cultivated land in desert steppe region].

    PubMed

    An, Hui; Yang, Xin-Guo; Liu, Bing-Ru; Li, Xue-Bin; He, Xiu-Zhen; Song, Nai-Ping

    2011-12-01

    By the method of substituting temporal serial with spatial serial, and taking five abandoned cultivated lands with different ages (1, 4, 9, 12, and 20 years) in desert steppe region as test objects, this paper studied the change characteristics of plant community biomass and soil nutrients during vegetation succession. With the increasing abandoned years, the plant community aboveground biomass on the abandoned lands increased after an initial decrease, whereas the total nitrogen, total phosphorus, organic carbon contents, and carbon density in 0-60 cm soil layer increased first, decreased then, and increased again, with the maximum values of soil total nitrogen and phosphorus contents appeared on the abandoned lands with the ages 4 and 20 years. During vegetation succession, the effects of soil total nitrogen and organic carbon on plant community biomass were greater than those of soil total phosphorus and soil bulk density.

  8. Reservoir Characterization, Production Characteristics, and Research Needs for Fluvial/Alluvial Reservoirs in the United States

    SciTech Connect

    Cole, E.L.; Fowler, M.L.; Jackson, S.R.; Madden, M.P.; Raw-Schatzinger, V.; Salamy, S.P.; Sarathi, P.; Young, M.A.

    1999-04-28

    The Department of Energy's (DOE's) Oil Recovery Field Demonstration Program was initiated in 1992 to maximize the economically and environmentally sound recovery of oil from known domestic reservoirs and to preserve access to this resource. Cost-shared field demonstration projects are being initiated in geology defined reservoir classes which have been prioritized by their potential for incremental recovery and their risk of abandonment. This document defines the characteristics of the fifth geological reservoir class in the series, fluvial/alluvial reservoirs. The reservoirs of Class 5 include deposits of alluvial fans, braided streams, and meandering streams. Deposit morphologies vary as a complex function of climate and tectonics and are characterized by a high degree of heterogeneity to fluid flow as a result of extreme variations in water energy as the deposits formed.

  9. EOS7C Version 1.0: TOUGH2 Module for Carbon Dioxide or Nitrogen inNatural Gas (Methane) Reservoirs

    SciTech Connect

    Oldenburg, Curtis M.; Moridis,George J.; Spycher, Nicholas; Pruess, Karsten

    2004-06-29

    EOS7C is a TOUGH2 module for multicomponent gas mixtures in the systems methane carbon dioxide (CH4-CO2) or methane-nitrogen (CH4-N2) with or without an aqueous phase and H2O vapor. EOS7C uses a cubic equation of state and an accurate solubility formulation along with a multiphase Darcy s Law to model flow and transport of gas and aqueous phase mixtures over a wide range of pressures and temperatures appropriate to subsurface geologic carbon sequestration sites and natural gas reservoirs. EOS7C models supercritical CO2 and subcritical CO2 as a non-condensible gas, hence EOS7C does not model the transition to liquid or solid CO2 conditions. The components modeled in EOS7C are water, brine, non-condensible gas, gas tracer, methane, and optional heat. The non-condensible gas (NCG) can be selected by the user to be CO2 or N2. The real gas properties module has options for Peng-Robinson, Redlich-Kwong, or Soave-Redlich-Kwong equations of state to calculate gas mixture density, enthalpy departure, and viscosity. Partitioning of the NCG and CH4 between the aqueous and gas phases is calculated using a very accurate chemical equilibrium approach. Transport of the gaseous and dissolved components is by advection and Fickian molecular diffusion. We present instructions for use and example problems to demonstrate the accuracy and practical application of EOS7C.

  10. Characterization of heterogeneities from core X-ray scans and borehole wall images in a reefal carbonate reservoir: influence on the porosity structure.

    NASA Astrophysics Data System (ADS)

    Hebert, V.; Garing, C.; Pezard, P. A.; Gouze, P.; Maria-Sube, Y.; Camoin, G.; Lapointe, P.

    2009-04-01

    Petrophysical properties of rocks can be largely influenced by heterogeneities. This is particularly true in reefal carbonates, with heterogeneities due to the primary structure of the reef, the degradation of that structure into a fossil form, and fluid circulations with associated dissolutions and recrystallization. We report here a study conducted on Miocene reefal carbonates drilled in the context of salt water intrusion in coastal reservoirs. Salt water intrusion along coastlines is highly influenced by geological and petrophysical structures. In particular, heterogeneities and anisotropy in porous media (karsts, vugs…) control fluid flow and dispersion. A new experimental site has been developed in the South East of Mallorca Island (Spain) in the context of the ALIANCE EC project (2002-2005). This project aimed at developing a strategy for the quantitative analysis and description of fluid flow and salt transport in coastal carbonate aquifers. The site drilled the Miocene carbonate reef platform at Ses Sitjoles, 6 km inland, near the city of Campos. Sea water is found there at 60 to 80 m depth. The geological structure present multi-scale heterogeneities, often bound to either lateral variations of geological facies, or dissolution patterns. The Campos site provides a unique laboratory to study the heterogeneities of carbonate rocks with a saltwater intrusion and develop new borehole investigation methods in this context. The present study focuses on borehole geophysical measurements and images, and core scans. New image analysis methods have been developed to better characterize the presence of heterogeneities in terms of grain-size distribution, formation factor changes and porosity. Cores scans from RX tomography can lead to the extraction of petrophysical parameters from 3D images. For this, the AVIZO software was used here to represent the micro-porosity and vuggy porosity structure. Beyond core analyses, the optical and acoustic borehole wall images

  11. Improved oil recovery in Mississippian carbonate reservoirs of Kansas - near term -- Class 2. Quarterly progress report, July 1, 1995--September 30, 1995

    SciTech Connect

    Carr, T.; Green, D.W.; Willhite, G.P.

    1995-11-01

    The objective of this project is to demonstrate incremental reserves from Osagian and Meramecian dolomite reservoirs in western Kansas through application of reservoir characterization to identify areas of unrecovered mobile petroleum. Specific reservoirs targeted are the Schaben Field in Ness County and the Bindley Field in Hodgeman County.

  12. Navajo Nation: Cleaning Up Abandoned Uranium Mines

    EPA Pesticide Factsheets

    This site provides information about the progress of EPA's cleanup of abandoned uranium mines on Navajo and Hopi lands and in other areas of Arizona and New Mexico, including health impacts, major enforcement and removal milestones, and community actions.

  13. 7 CFR 767.51 - Property abandonment.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ..., manage, and operate the abandoned security property, including marketing perishable security property on behalf of the borrower when such action is in the Agency's financial interest. If the security is...

  14. The use of the terrestrial snails of the genera Megalobulimus and Thaumastus as representatives of the atmospheric carbon reservoir

    PubMed Central

    Macario, Kita D.; Alves, Eduardo Q.; Carvalho, Carla; Oliveira, Fabiana M.; Ramsey, Christopher Bronk; Chivall, David; Souza, Rosa; Simone, Luiz Ricardo L.; Cavallari, Daniel C.

    2016-01-01

    In Brazilian archaeological shellmounds, many species of land snails are found abundantly distributed throughout the occupational layers, forming a contextualized set of samples within the sites and offering a potential alternative to the use of charcoal for radiocarbon dating analyses. In order to confirm the effectiveness of this alternative, one needs to prove that the mollusk shells reflect the atmospheric carbon isotopic concentration in the same way charcoal does. In this study, 18 terrestrial mollusk shells with known collection dates from 1948 to 2004 AD, around the nuclear bombs period, were radiocarbon dated. The obtained dates fit the SH1-2 bomb curve within less than 15 years range, showing that certain species from the Thaumastus and Megalobulimus genera are reliable representatives of the atmospheric carbon isotopic ratio and can, therefore, be used to date archaeological sites in South America. PMID:27271349

  15. The use of the terrestrial snails of the genera Megalobulimus and Thaumastus as representatives of the atmospheric carbon reservoir.

    PubMed

    Macario, Kita D; Alves, Eduardo Q; Carvalho, Carla; Oliveira, Fabiana M; Ramsey, Christopher Bronk; Chivall, David; Souza, Rosa; Simone, Luiz Ricardo L; Cavallari, Daniel C

    2016-06-08

    In Brazilian archaeological shellmounds, many species of land snails are found abundantly distributed throughout the occupational layers, forming a contextualized set of samples within the sites and offering a potential alternative to the use of charcoal for radiocarbon dating analyses. In order to confirm the effectiveness of this alternative, one needs to prove that the mollusk shells reflect the atmospheric carbon isotopic concentration in the same way charcoal does. In this study, 18 terrestrial mollusk shells with known collection dates from 1948 to 2004 AD, around the nuclear bombs period, were radiocarbon dated. The obtained dates fit the SH1-2 bomb curve within less than 15 years range, showing that certain species from the Thaumastus and Megalobulimus genera are reliable representatives of the atmospheric carbon isotopic ratio and can, therefore, be used to date archaeological sites in South America.

  16. The use of the terrestrial snails of the genera Megalobulimus and Thaumastus as representatives of the atmospheric carbon reservoir

    NASA Astrophysics Data System (ADS)

    Macario, Kita D.; Alves, Eduardo Q.; Carvalho, Carla; Oliveira, Fabiana M.; Ramsey, Christopher Bronk; Chivall, David; Souza, Rosa; Simone, Luiz Ricardo L.; Cavallari, Daniel C.

    2016-06-01

    In Brazilian archaeological shellmounds, many species of land snails are found abundantly distributed throughout the occupational layers, forming a contextualized set of samples within the sites and offering a potential alternative to the use of charcoal for radiocarbon dating analyses. In order to confirm the effectiveness of this alternative, one needs to prove that the mollusk shells reflect the atmospheric carbon isotopic concentration in the same way charcoal does. In this study, 18 terrestrial mollusk shells with known collection dates from 1948 to 2004 AD, around the nuclear bombs period, were radiocarbon dated. The obtained dates fit the SH1-2 bomb curve within less than 15 years range, showing that certain species from the Thaumastus and Megalobulimus genera are reliable representatives of the atmospheric carbon isotopic ratio and can, therefore, be used to date archaeological sites in South America.

  17. Wettability of supercritical carbon dioxide/water/quartz systems: simultaneous measurement of contact angle and interfacial tension at reservoir conditions.

    PubMed

    Saraji, Soheil; Goual, Lamia; Piri, Mohammad; Plancher, Henry

    2013-06-11

    Injection of carbon dioxide in deep saline aquifers is considered as a method of carbon sequestration. The efficiency of this process is dependent on the fluid-fluid and rock-fluid interactions inside the porous media. For instance, the final storage capacity and total amount of capillary-trapped CO2 inside an aquifer are affected by the interfacial tension between the fluids and the contact angle between the fluids and the rock mineral surface. A thorough study of these parameters and their variations with temperature and pressure will provide a better understanding of the carbon sequestration process and thus improve predictions of the sequestration efficiency. In this study, the controversial concept of wettability alteration of quartz surfaces in the presence of supercritical carbon dioxide (sc-CO2) was investigated. A novel apparatus for measuring interfacial tension and contact angle at high temperatures and pressures based on Axisymmetric Drop Shape Analysis with no-Apex (ADSA-NA) method was developed and validated with a simple system. Densities, interfacial tensions, and dynamic contact angles of CO2/water/quartz systems were determined for a wide range of pressures and temperatures relevant to geological sequestration of CO2 in the subcritical and supercritical states. Image analysis was performed with ADSA-NA method that allows the determination of both interfacial tensions and contact angles with high accuracy. The results show that supercritical CO2 alters the wettability of quartz surface toward less water-wet conditions compared to subcritical CO2. Also we observed an increase in the water advancing contact angles with increasing temperature indicating less water-wet quartz surfaces at higher temperatures.

  18. Asymptomatic bowel perforation by abandoned ventriculoperitoneal shunt.

    PubMed

    Rinker, Eric K; Osborn, Daniel A; Williams, Todd R; Spizarny, David L

    2013-09-01

    We report a case of an abandoned abdominal ventriculoperitoneal shunt that migrated into the gastric antrum, colonic hepatic flexure, and liver parenchyma, which was discovered incidentally on an abdominal CT obtained for renal stones. In regards to the migrated abandoned VP shunt, the patient was asymptomatic. Upon review of prior CT scans, these findings had progressed over approximately 7 years. We describe the case and discuss the clinical and radiologic findings, complications resulting from ventriculoperitoneal shunts, and possible approaches to their management.

  19. Mapping the extent of abandoned farmland in Central and Eastern Europe using MODIS time series satellite data

    NASA Astrophysics Data System (ADS)

    Alcantara, Camilo; Kuemmerle, Tobias; Baumann, Matthias; Bragina, Eugenia V.; Griffiths, Patrick; Hostert, Patrick; Knorn, Jan; Müller, Daniel; Prishchepov, Alexander V.; Schierhorn, Florian; Sieber, Anika; Radeloff, Volker C.

    2013-09-01

    The demand for agricultural products continues to grow rapidly, but further agricultural expansion entails substantial environmental costs, making recultivating currently unused farmland an interesting alternative. The collapse of the Soviet Union in 1991 led to widespread abandonment of agricultural lands, but the extent and spatial patterns of abandonment are unclear. We quantified the extent of abandoned farmland, both croplands and pastures, across the region using MODIS NDVI satellite image time series from 2004 to 2006 and support vector machine classifications. Abandoned farmland was widespread, totaling 52.5 Mha, particularly in temperate European Russia (32 Mha), northern and western Ukraine, and Belarus. Differences in abandonment rates among countries were striking, suggesting that institutional and socio-economic factors were more important in determining the amount of abandonment than biophysical conditions. Indeed, much abandoned farmland occurred in areas without major constraints for agriculture. Our map provides a basis for assessing the potential of Central and Eastern Europe’s abandoned agricultural lands to contribute to food or bioenergy production, or carbon storage, as well as the environmental trade-offs and social constraints of recultivation.

  20. The rail abandonment process: A southern perspective

    SciTech Connect

    Not Available

    1988-12-01

    One factor in evaluating the desirability of rail transport for high-level radioactive wastes or spent fuels is the frequency, or lack thereof, with which railroad and railroad lines have been, and are, abandoned. If DOE makes a decision to use the rail option and a line is subsequently abandoned, the choice results in increased cost, time delays and possibly safety problems: Information is therefore needed prior to the decision-making process to evaluate the desirability of the rail shipping option. One result of the abandonments mentioned herein, as well as other later abandonments, is the creation of a US rail system undergoing an evolutionary process in the 1980s as far-reaching as the changes that occurred when the industry was in its infancy a century and-a-half ago. The purpose of this paper is to examine the factors leading to some of these changes by tracing the historical development of the rail abandonment process, with particular emphasis on the rise of regional railroads, their problems in the modern era and current trends in rail abandonments as well as their effects on the southeastern United States.

  1. Towards Understanding Methane Emissions from Abandoned ...

    EPA Pesticide Factsheets

    Reconciliation of large-scale top-down methane measurements and bottom-up inventories requires complete accounting of source types. Methane emissions from abandoned oil and gas wells is an area of uncertainty. This presentation reviews progress to characterize the potential inventory impacts of abandoned wells for the U.S. . Available methane emission rate data for abandoned wells is reviewed and some of the ongoing research to better characterize emissions is discussed. Efforts to compile a database of well drilling activities since the 1870’s for each state and each state’s establishment of well plugging standards for abandoned wells is described. Progress towards an estimate of national methane emissions from abandoned wells and major sources of uncertainty are presented. These emissions are put in to context by comparing to other sources of methane emissions from oil and gas production activities. This is an abstract for a presentation at the Natural GasSTAR Annual Implementation Workshop on November 16-18, 2015 in Pittsburgh, PA. The subject is methane emissions fro abandoned wells. This is a report on interim progress on a effort we have with ERG. OAP is involved in the project and will review slides.

  2. 37 CFR 2.66 - Revival of abandoned applications.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... application abandoned because the applicant did not timely respond to an Office action or notice of allowance... abandonment, if the applicant did not receive the notice of abandonment, and the applicant was diligent in... for filing a petition to revive an application abandoned because the applicant did not timely...

  3. Design and implementation of a CO{sub 2} flood utilizing advanced reservoir characterization and horizontal injection wells in a shallow shelf carbonate approaching waterflood depletion. Annual report, June 3, 1994--October 31, 1995

    SciTech Connect

    Hallenbeck, L.D.; Harpole, K.J.; Gerard, M.G.

    1996-05-01

    The work reported here covers Budget Phase I of the project. The principal tasks in Budget Phase I are the Reservoir Analysis and Characterization Task and the Advanced Technology Definition Task. Completion of these tasks have enabled an optimum carbon dioxide (CO{sub 2}) flood project to be designed and evaluated from an economic and risk analysis standpoint. Field implementation of the project has been recommended to the working interest owner of the South Cowden Unit (SCU) and approval has been obtained. The current project has focused on reducing initial investment cost by utilizing horizontal injection wells and concentrating the project in the best productivity area of the field. An innovative CO{sub 2} purchase agreement (no take or pay requirements, CO{sub 2} purchase price tied to West Texas Intermediate crude oil price) and gas recycle agreements (expensing cost as opposed to large capital investments for compression) were negotiated to further improve project economics. A detailed reservoir characterization study was completed by an integrated team of geoscientists and engineers. The study consisted of detailed core description, integration of log response to core descriptions, mapping of the major flow units, evaluation of porosity and permeability relationships, geostatistical analysis of permeability trends, and direct integration of reservoir performance with the geological interpretation. The study methodology fostered iterative bidirectional feedback between the reservoir characterization team and the reservoir engineering/simulation team to allow simultaneous refinement and convergence of the geological interpretation with the reservoir model. The fundamental conclusion from the study is that South Cowden exhibits favorable enhanced oil recovery characteristics, particularly reservoir quality and continuity.

  4. Classification and features of single-well flow units in a carbonate reservoir - Taking the NT oil field at the eastern edge of Pre-Caspian Basin as an example

    NASA Astrophysics Data System (ADS)

    Fan, Zifei; Wang, Shuqin; Liu, Lingli; Li, Jianxin; Zhao, Wenqi; Sun, Meng

    2017-01-01

    Identifying the carbonate reservoirs has always been a challenge to geological exploration, while reasonable classification of flow units is the bottleneck in this exploitation. While taking the NT oil field at the eastern edge of Pre-Caspian Basin as an example, this paper proposes the classification of flow units into five categories based on previous flow-unit classification theory and actual oilfield features by using the pore throat radius at the mercury injection saturation of 35% as the main judging criterion. In this paper, the features of various flow units have also been analyzed. The type-I flow units, mainly found in dolomite and algal reef limestone reservoirs, have the highest production capacity. Given the existence of corrosion and dolomitization, they are mainly fracture-cave composite reservoirs or fracture pore reservoirs. As far as the type-I flow units are concerned, the flow index is > 1.42 for KT-I stratum and > 1.55 for KT-II stratum. The production capacity and reservoir quality of type-II-IV flow units would decline in turn. The type-V flow units are argillaceous limestone, with a very low production capacity and a flow index being 0.01-0.05 for KT-I and 0.03-0.05 for KT-II.

  5. Phosphorus availability as a primary control of dissolved organic carbon biodegradation in the tributaries of the Yangtze River in the Three Gorges Reservoir Region.

    PubMed

    Mao, Rong; Chen, Huimin; Li, Siyue

    2017-01-01

    Biodegradability of dissolved organic carbon (DOC) represents a critical component of the riverine C cycle. Current knowledge of DOC biodegradation in rivers is limited, especially in the subtropical regions. Here, we collected 66 water samples from 63 tributaries of the Yangtze River in the Three Gorges Reservoir Region, China, and subsequently examined the biodegradability of DOC and its controlling factors. We found that DOC biodegradation was quite spatially variable within the river networks and ranged from 15.8% to 35.2%, with a mean of 24.5±8.0%. The biodegradability of DOC was positively correlated with the initial dissolved total phosphorus (P) concentration, but was not significantly correlated with the initial DOC and dissolved total nitrogen (N) concentrations. In addition, DOC biodegradation was negatively correlated with the initial C:P and N:P ratios, and exhibited no significant relationship with the initial C:N ratio in these rivers. Our findings suggest that DOC biodegradation is limited by P availability in the subtropical rivers, and also imply that P enrichment induced by anthropogenic activities would enhance the biodegradability of DOC and decrease the spatial heterogeneity of DOC biodegradation in the subtropical river networks.

  6. Linking sedimentary total organic carbon to (210)Pbex chronology from Changshou Lake in the Three Gorges Reservoir Region, China.

    PubMed

    Anjum, Raheel; Gao, Jinzhang; Tang, Qiang; He, Xiubin; Zhang, Xinbao; Long, Yi; Shi, Zhonglin; Wang, Mingfeng

    2017-05-01

    The influences of total organic carbon (TOC) and total nitrogen (TN) on Lead-210 ((210)Pb) dating have recently been of increasing concern in lacustrine research. Sediment core from Changshou Lake in the Longxi catchment was investigated for influence of TOC on (210)Pb dating. Lead-210 excess ((210)Pbex), Cesium-137 ((137)Cs) activities, TOC, TN, and particle size were measured. We proposed a dating index based on (137)Cs chronology and particle size distribution of the lake sediment profile and rainfall erosivities calculated from Longxi catchment metrological records. Increasing trends in TOC and TN were specifically caused by commercial cage fish farming after 1989. The statistically significant correlation between (210)Pbex activity, TOC (0.61, p = 0.04) and TN (0.51, p = 0.04), respectively explained post-1989 (210)Pb scavenging. The (210)Pbex activity was closely related with coupled peaks of TOC and TN from mass depth 5-10 g cm(-2). Higher TOC/TN ratio (8.33) indicated submerged macrophytes and native aquatic algal growth as main source of carbon from enhanced primary productivity because of massive fertilizer use and coherent climate warming. The study supported key hypothesis on vital role of fertilizer usage and algal derived TOC in controlling sedimentary (210)Pbex activity at Changshou Lake sediment. (137)Cs profile and erosive events as time markers provided reliable and consistent sedimentation rate of (1.6 cm y(-1)). (210)Pbex activity decayed exponentially after peak at mass depth 5.68 g cm(-2). Therefore, violation of (210)Pb dating primary assumptions made it inappropriate for sediment dating at Changshou Lake. TOC content must be considered while using (210)Pb as dating tool for lake sediment profiles.

  7. Application of reservoir characterization and advanced technology to improve recovery and economics in a lower quality shallow shelf carbonate reservoir. Quarterly progress report, March 1, 1995--June 30, 1995

    SciTech Connect

    Taylor, A.R.

    1995-09-01

    West Welch Unit is one of four large waterflood units in the Welch Field located in the Northwestern portion of Dawson County, Texas. The Welch Field was discovered in the early 1940`s and produces oil under a solution gas drive mechanism from the San Andres formation at approximately 4800 ft. The field has been under waterflood for 30 years and a significant portion has been infilled drilled on 20-ac density. A 1982--86 pilot CO{sub 2} injection project in the offsetting South Welch Unit yielded positive results.The recent installation of a Co{sub 2} pipeline near the field allowed the phased development of a miscible CO{sub 2} injection project at the South Welch Unit. The reservoir quality is poorer at the West Welch Unit because of its relative location of sea level during deposition. Table I compares reservoir parameters between the two units and shows their ranking in relation to all SSC reservoirs listed in the TORIS database. Because of the proximity of a CO{sub 2} source and the CO{sub 2} operating experience that would be available from the South Welch Unit, West Welch Unit was an ideal location for demonstrating methods for enhancing economics of IOR projects in lower quality SSC reservoirs. This Class 2 project concentrates on the efficient design of a miscible CO{sub 2} project based on detailed reservoir characterization from advanced petrophysics, 3-D seismic interpretations and cross wellbore tomography interpretations.

  8. Relationship between fracturing and porogenesis in a carbonate reservoir: Example from the Middle Turonian Bireno Member in Jebel M'rhila, Central Tunisia

    NASA Astrophysics Data System (ADS)

    Haj Ali, Hajer; Belghithi, Hanen; Ouali, Jamel Abdennaceur; Touir, Jamel

    2016-09-01

    The aim of the present work is to study the Middle Turonian carbonate Bireno Member in Jebel M'rhila area (Central Tunisia). This member mainly consists of dolostones. The sampling of the dolomitic rocks was carried out on both sides of the several fractures affecting the Bireno Member. We also measured the directions and dips of the fractures. The Studied dolomites basically consist of subhedral to euhedral dolospar. The porosity associated to the dolomites show a gradual variation both laterally and vertically. In fact, porosity increases respectively, laterally while going toward the fractures and vertically from the bottom to the top of the dolomitic member. The mineralogical and geochemical analyses of dolomite, carried out respectively by X-Ray Diffraction and Atomic Absorption, show that the studied dolomites broadly range from a sub-stoechiometric dolomite (48% CaCO3) far from the fractures to a dolomitic calcite (84% CaCO3) near the fractures. In the same way, the MgCO3 contents vary from 35% to 11%. Such high contents in Ca against low contents in Mg could probably related to the dilution of the dolomitizing marine waters by meteoric waters which would have been introduced within the platform during the Middle Turonian sea-level fall and the subsequent subaerial exposure of the Bireno platform. The Sr and Na contents (respectively, 4 ppm and 15 ppm in average) are rather low and they gradually decrease while approaching the fractures. Such a gradual decrease in Sr and Na concentrations may be the result of salinity lowering caused by the meteoric waters that would have circulated through the existing fractures networks. The previous analyses were supplemented by the SEM examination of the dolomite and the measurement of porosity and permeability. The SEM allowed us to identify the dolomite petrographic phases and the associated diagenetic products (solution, cementing, dedolomitization.), whereas the porosity and permeability evaluation highlights the

  9. Different carbon reservoirs of auriferous fluids in African Archean and Proterozoic gold deposits? Constraints from stable carbon isotopic compositions of quartz-hosted CO2-rich fluid inclusions

    NASA Astrophysics Data System (ADS)

    Lüders, Volker; Klemd, Reiner; Oberthür, Thomas; Plessen, Birgit

    2015-04-01

    Stable carbon (and when present, nitrogen) isotope ratios of fluid inclusions in quartz from selected gold deposits in Ghana and Zimbabwe have been analyzed using a crushing device interfaced to an isotopic ratio mass spectrometer (IRMS) in order to constrain possible sources of the auriferous fluids. The study revealed a striking difference in stable carbon isotopic compositions of CO2 in quartz-hosted fluid inclusions from Archean and Paleoproterozoic orogenic gold deposits and points to diverse sources of CO2 in the studied deposits. Whether this finding can be generalized for other Archean and Proterozoic orogenic gold deposits worldwide remains open. However, a significant CO2 contribution by mantle degassing can be ruled out for every deposit studied. Devolatilization of greenstone belt rocks is the most likely source for CO2 in some Archean Au deposits in Zimbabwe, whereas CO2 in Proterozoic vein-type Au deposits in the West African Craton is most likely derived from Corg-bearing metasedimentary rocks. The δ13CCO2 values of high-density CO2-rich, water-poor inclusions hosted in quartz pebbles from the world-class Au-bearing conglomerate deposits at Tarkwa (Ghana) differ considerably from the δ13CCO2 values of similar high-density CO2-rich inclusions in vein quartz from the giant Ashanti deposit (Ghana) and disprove the idea of derivation of the Tarkwaian quartz (and gold?) from an older equivalent to the Ashanti vein-type gold deposit.

  10. Which accesses should be abandoned or revised?

    PubMed

    Gibbons, Christopher P

    2014-01-01

    This review considers the factors in deciding whether to abandon a functioning access. Strong indications for ligation or excision of an access are infection or severe early-onset steal. Access ligation may also be required for central vein occlusion or high-output cardiac failure. In general, a failing or thrombosed access should be restored to function unless it is no longer required. For failing or thrombosed distal arteriovenous fistulas, it may be easiest to abandon it and create a new fistula a few centimetres proximally rather than perform angioplasty, which is likely to require repeating. Other accesses may be abandoned after repeated treatment of the same stenosis over a short period provided other options exist.

  11. Soil microbial community of abandoned sand fields.

    PubMed

    Elhottová, D; Szili-Kovács, T; Tríska, J

    2002-01-01

    Microbiological evaluation of sandy grassland soils from two different stages of secondary succession on abandoned fields (4 and 8 years old fallow) was carried out as a part of research focused on restoration of semi-natural vegetation communities in Kiskunság National Park in Hungary. There was an apparent total N and organic C enrichment, stimulation of microbial growth and microbial community structure change on fields abandoned by agricultural practice (small family farm) in comparison with native undisturbed grassland. A successional trend of the microbial community was found after 4 and 8 years of fallow-lying soil. It consisted in a shift of r-survival strategy to more efficient C economy, in a decrease of specific respiration and metabolic activity, forced accumulation of storage bacterial compounds and increased fungal distribution. The composition of microbial phospholipid fatty acids mixture of soils abandoned at various times was significantly different.

  12. Infanticide and illegal infant abandonment in Malaysia.

    PubMed

    Razali, Salmi; Kirkman, Maggie; Ahmad, S Hassan; Fisher, Jane

    2014-10-01

    Infant abandonment and infanticide are poorly understood in Malaysia. The information available in the public arena comes predominantly from anecdotal sources. The aim of this study was to describe the prevalence and characteristics of infanticide and illegal infant abandonment in Malaysia and to estimate annual rates for the most recent decade. Summaries of data about infanticide and illegal infant abandonment were gathered from police records; the annual number of live births was ascertained from the national registry. The estimated inferred infanticide rates for Malaysia were compared with the infanticide rates among countries of very high, high, medium, and low rankings on the Human Development, Gender Inequality, and Gini indices. From 1999 to 2011, 1,069 cases of illegal infant abandonment were recorded and 1,147 people were arrested as suspected perpetrators. The estimated inferred infanticide rate fluctuated between 4.82 and 9.11 per 100,000 live births, a moderate rate relative to the infanticide rates of other countries. There are substantial missing data, with details undocumented for about 78-87% of cases and suspected perpetrators. Of the documented cases, it appeared that more boys than girls were victims and that suspected perpetrators were predominantly Malays who were women, usually mothers of the victim; the possibility of arrest bias must be acknowledged. Economic and social inequality, particularly gender inequality, might contribute to the phenomena of infanticide and abandonment. Strategies to reduce rates of infanticide and illegal infant abandonment in Malaysia will require strengthening of the surveillance system and attention to the gender-based inequalities that underpin human development.

  13. Modeling the Injection of Carbon Dioxide and Nitrogen into a Methane Hydrate Reservoir and the Subsequent Production of Methane Gas on the North Slope of Alaska

    NASA Astrophysics Data System (ADS)

    Garapati, N.; McGuire, P. C.; Liu, Y.; Anderson, B. J.

    2012-12-01

    HydrateResSim (HRS) is an open-source finite-difference reservoir simulation code capable of simulating the behavior of gas hydrate in porous media. The original version of HRS was developed to simulate pure methane hydrates, and the relationship between equilibrium temperature and pressure is given by a simple, 1-D regression expression. In this work, we have modified HydrateResSim to allow for the formation and dissociation of gas hydrates made from gas mixtures. This modification allows one to model the ConocoPhillips Ignik Sikumi #1 field test performed in early 2012 on the Alaska North Slope. The Ignik Sikumi #1 test is the first field-based demonstration of gas production through the injection of a mixture of carbon dioxide and nitrogen gases into a methane hydrate reservoir and thereby sequestering the greenhouse gas CO2 into hydrate form. The primary change to the HRS software is the added capability of modeling a ternary mixture consisting of CH4 + CO2 + N2 instead of only one hydrate guest molecule (CH4), therefore the new software is called Mix3HydrateResSim. This Mix3HydrateResSim upgrade to the software was accomplished by adding primary variables (for the concentrations of CO2 and N2), governing equations (for the mass balances of CO2 and N2), and phase equilibrium data. The phase equilibrium data in Mix3HydrateResSim is given as an input table obtained using a statistical mechanical method developed in our research group called the cell potential method. An additional phase state describing a two-phase Gas-Hydrate (GsH) system was added to consider the possibility of converting all available free water to form hydrate with injected gas. Using Mix3HydrateResSim, a methane hydrate reservoir with coexisting pure-CH4-hydrate and aqueous phases at 7.0 MPa and 5.5°C was modeled after the conditions of the Ignik Sikumi #1 test: (i) 14-day injection of CO2 and N2 followed by (ii) 30-day production of CH4 (by depressurization of the well). During the

  14. Hydroelectric power provides a cheap source of electricity with few carbon emissions. Yet, reservoirs are not operated sustainably, which we define as meeting societal needs for water and power while protecting long-term health of the river ecosystem. Reservoirs that generate hydropower are typically operated with the goal of maximizing energy reve

    SciTech Connect

    Jager, Yetta; Smith, Brennan T

    2008-02-01

    Hydroelectric power provides a cheap source of electricity with few carbon emissions. Yet, reservoirs are not operated sustainably, which we define as meeting societal needs for water and power while protecting long-term health of the river ecosystem. Reservoirs that generate hydropower are typically operated with the goal of maximizing energy revenue, while meeting other legal water requirements. Reservoir optimization schemes used in practice do not seek flow regimes that maximize aquatic ecosystem health. Here, we review optimization studies that considered environmental goals in one of three approaches. The first approach seeks flow regimes that maximize hydropower generation, while satisfying legal requirements, including environmental (or minimum) flows. Solutions from this approach are often used in practice to operate hydropower projects. In the second approach, flow releases from a dam are timed to meet water quality constraints on dissolved oxygen (DO), temperature and nutrients. In the third approach, flow releases are timed to improve the health of fish populations. We conclude by suggesting three steps for bringing multi-objective reservoir operation closer to the goal of ecological sustainability: (1) conduct research to identify which features of flow variation are essential for river health and to quantify these relationships, (2) develop valuation methods to assess the total value of river health and (3) develop optimal control softwares that combine water balance modelling with models that predict ecosystem responses to flow.

  15. Multiphase Flow and Cavern Abandonment in Salt

    SciTech Connect

    Ehgartner, Brian; Tidwell, Vince

    2001-02-13

    This report will explore the hypothesis that an underground cavity in gassy salt will eventually be gas filled as is observed on a small scale in some naturally occurring salt inclusions. First, a summary is presented on what is known about gas occurrences, flow mechanisms, and cavern behavior after abandonment. Then, background information is synthesized into theory on how gas can fill a cavern and simultaneously displace cavern fluids into the surrounding salt. Lastly, two-phase (gas and brine) flow visualization experiments are presented that demonstrate some of the associated flow mechanisms and support the theory and hypothesis that a cavity in salt can become gas filled after plugging and abandonment

  16. Characterizing a Mississippian Carbonate Reservoir for CO2-EOR and Carbon Geosequestration: Applicability of Existing Rock Physics Models and Implications to Feasibility of a Time Lapse Monitoring Program in the Wellington Oil Field, Sumner County, Kansas.

    NASA Astrophysics Data System (ADS)

    Lueck, A. J.; Raef, A. E.

    2015-12-01

    This study will focus on characterizing subsurface rock formations of the Wellington Field, in Sumner County, Kansas, for both geosequestration of carbon dioxide (CO2) in the saline Arbuckle formation and enhanced oil recovery of a depleting Mississippian oil reservoir. Multi-scale data including lithofacies core samples, X-ray diffraction, digital rock physics scans, scanning electron microscope (SEM) imaging, well log data including sonic and dipole sonic, and surface 3D seismic reflection data will be integrated to establish and/or validate a new or existing rock physics model that best represents our reservoir rock types and characteristics. We will acquire compressional wave velocity and shear wave velocity data from Mississippian and Arbuckle cores by running ultrasonic tests using an Ult 100 Ultrasonic System and a 12 ton hydraulic jack located in the geophysics lab in Thompson Hall at Kansas State University. The elastic constants Young's Modulus, Bulk Modulus, Shear (Rigidity) Modulus and Poisson's Ratio will be extracted from these velocity data. Ultrasonic velocities will also be compared to sonic and dipole sonic log data from the Wellington 1-32 well. These data will be integrated to validate a lithofacies classification statistical model, which will be and partially has been applied to the largely unknown saline Arbuckle formation, with hopes for a connection, perhaps via Poisson's ratio, allowing a time-lapse seismic feasibility assessment and potentially developing a transformation of compressional wave sonic velocities to shear wave sonic for all wells, where compressional wave sonic is available. We will also be testing our rock physics model by predicting effects of changing effective (brine + CO2 +hydrocarbon) fluid composition on seismic properties and the implications on feasibility of seismic monitoring. Lessons learned from characterizing the Mississippian are essential to understanding the potential of utilizing similar workflows for the

  17. Application of reservoir characterization and advanced technology to improve recovery and economics in a lower quality shallow shelf San Andres reservoir. Quarterly progress report, October 1--December 31, 1997

    SciTech Connect

    Taylor, A.R.; Hickman, T.S.; Justice, J.J.

    1998-01-31

    West Welch Unit is one of four large waterflood units in the Welch Field in the northwestern portion of Dawson County, Texas. The Welch Field produces oil under a solution gas drive mechanism from the San Andres formation at approximately 4,800 ft. The field has been under waterflood for 30 years and a significant portion has been infill-drilled on 20-ac density. A 1982--86 pilot CO{sub 2} injection project in the offsetting South Welch Unit yielded positive results. Recent installation of a CO{sub 2} pipeline near the field allowed the phased development of a miscible CO{sub 2} injection project at the South Welch Unit. The Class 2 Project at West Welch was designed to demonstrate the use of advanced technologies to enhance the economics of improved oil recovery (IOR) projects in lower quality Shallow Shelf Carbonate (SSC) reservoirs, resulting in recovery of additional oil that would otherwise be left in the reservoir at project abandonment. Accurate reservoir description is critical to the effective evaluation and efficient design of IOR projects in the heterogeneous SSC reservoirs. Therefore, the majority of Budget Period 1 was devoted to reservoir characterization. Technologies being demonstrated include: advanced petrophysics; three-dimensional seismic; cross-well bore tomography; advanced reservoir simulation; CO{sub 2} stimulation treatments; hydraulic fracturing design and monitoring; and mobility control agents. During the quarter, development of the project`s south expansion area was undertaken, work was continued on interpreting the crosswell seismic data and CO{sub 2} injection into 11 wells was initiated.

  18. Impact of CO2 leakage from sub-seabed carbon dioxide capture and storage (CCS) reservoirs on benthic virus-prokaryote interactions and functions.

    PubMed

    Rastelli, Eugenio; Corinaldesi, Cinzia; Dell'Anno, Antonio; Amaro, Teresa; Queirós, Ana M; Widdicombe, Stephen; Danovaro, Roberto

    2015-01-01

    Atmospheric CO2 emissions are a global concern due to their predicted impact on biodiversity, ecosystems functioning, and human life. Among the proposed mitigation strategies, CO2 capture and storage, primarily the injection of CO2 into marine deep geological formations has been suggested as a technically practical option for reducing emissions. However, concerns have been raised that possible leakage from such storage sites, and the associated elevated levels of pCO2 could locally impact the biodiversity and biogeochemical processes in the sediments above these reservoirs. Whilst a number of impact assessment studies have been conducted, no information is available on the specific responses of viruses and virus-host interactions. In the present study, we tested the impact of a simulated CO2 leakage on the benthic microbial assemblages, with specific focus on microbial activity and virus-induced prokaryotic mortality (VIPM). We found that exposure to levels of CO2 in the overlying seawater from 1,000 to 20,000 ppm for a period up to 140 days, resulted in a marked decrease in heterotrophic carbon production and organic matter degradation rates in the sediments, associated with lower rates of VIPM, and a progressive accumulation of sedimentary organic matter with increasing CO2 concentrations. These results suggest that the increase in seawater pCO2 levels that may result from CO2 leakage, can severely reduce the rates of microbial-mediated recycling of the sedimentary organic matter and viral infections, with major consequences on C cycling and nutrient regeneration, and hence on the functioning of benthic ecosystems.

  19. Initial report on methane and carbon dioxide emission dynamics from sub-Antarctic freshwater ecosystems: A seasonal study of a lake and a reservoir.

    PubMed

    Gerardo-Nieto, Oscar; Astorga-España, María Soledad; Mansilla, Andrés; Thalasso, Frederic

    2017-03-22

    The sub-Antarctic Magellanic ecoregion is a part of the world where ecosystems have been understudied and where the CH4 cycling and emissions in lakes has not ever been reported. To fill that knowledge gap, a lake and a reservoir located at 53°S were selected and studied during three campaigns equally distributed over one year. Among the parameters measured were CH4 and CO2 emissions, as well their dissolved concentrations in the water column, which were determined with high spatial resolution. No ebullition was observed and the CH4 flux ranged from 0.0094 to 4.47mmolm(-2)d(-1) while the CO2 flux ranged from -22.95 to 35.68mmolm(-2)d(-1). Dissolved CH4 concentrations varied over more than four orders of magnitude (0.025-128.75μmolL(-1)), and the dissolved carbon dioxide ranged from below the detection limit of our method (i.e., 0.15μmolL(-1)) to 379.09μmolL(-1). The high spatial resolution of the methods used enabled the construction of bathymetric maps, surface contour maps of CH4 and CO2 fluxes, and transect contour maps of dissolved oxygen, temperature, and dissolved greenhouse gases. Overall, both lakes were net greenhouse gas producers and were not significantly different from temperate lakes located at a similar northern latitudes (53°N), except that ebullition was never observed in the studied sub-Antarctic lakes.

  20. The influence of reservoirs, climate, land use and hydrologic conditions on loads and chemical quality of dissolved organic carbon in the Colorado River

    NASA Astrophysics Data System (ADS)

    Miller, Matthew P.

    2012-09-01

    Longitudinal patterns in dissolved organic carbon (DOC) loads and chemical quality were identified in the Colorado River from the headwaters in the Rocky Mountains to the United States-Mexico border from 1994 to 2011. Watershed- and reach-scale climate, land use, river discharge and hydrologic modification conditions that contribute to patterns in DOC were also identified. Principal components analysis (PCA) identified site-specific precipitation and reach-scale discharge as being correlated with sites in the upper basin, where there were increases in DOC load from the upstream to downstream direction. In the lower basin, where DOC load decreased from upstream to downstream, sites were correlated with site-specific temperature and reach-scale population, urban land use and hydrologic modification. In the reaches containing Lakes Powell and Mead, the two largest reservoirs in the United States, DOC quantity decreased, terrestrially derived aromatic DOC was degraded and/or autochthonous less aromatic DOC was produced. Taken together, these results suggest that longitudinal patterns in the relatively unregulated upper basin are influenced by watershed inputs of water and DOC, whereas DOC patterns in the lower basin are reflective of a balance between watershed contribution of water and DOC to the river and loss of water and DOC due to hydrologic modification and/or biogeochemical processes. These findings suggest that alteration of constituent fluxes in rivers that are highly regulated may overshadow watershed processes that would control fluxes in comparable unregulated rivers. Further, these results provide a foundation for detailed assessments of factors controlling the transport and chemical quality of DOC in the Colorado River.

  1. The influence of reservoirs, climate, land use and hydrologic conditions on loads and chemical quality of dissolved organic carbon in the Colorado River

    USGS Publications Warehouse

    Miller, Matthew P.

    2012-01-01

    Longitudinal patterns in dissolved organic carbon (DOC) loads and chemical quality were identified in the Colorado River from the headwaters in the Rocky Mountains to the United States-Mexico border from 1994 to 2011. Watershed- and reach-scale climate, land use, river discharge and hydrologic modification conditions that contribute to patterns in DOC were also identified. Principal components analysis (PCA) identified site-specific precipitation and reach-scale discharge as being correlated with sites in the upper basin, where there were increases in DOC load from the upstream to downstream direction. In the lower basin, where DOC load decreased from upstream to downstream, sites were correlated with site-specific temperature and reach-scale population, urban land use and hydrologic modification. In the reaches containing Lakes Powell and Mead, the two largest reservoirs in the United States, DOC quantity decreased, terrestrially derived aromatic DOC was degraded and/or autochthonous less aromatic DOC was produced. Taken together, these results suggest that longitudinal patterns in the relatively unregulated upper basin are influenced by watershed inputs of water and DOC, whereas DOC patterns in the lower basin are reflective of a balance between watershed contribution of water and DOC to the river and loss of water and DOC due to hydrologic modification and/or biogeochemical processes. These findings suggest that alteration of constituent fluxes in rivers that are highly regulated may overshadow watershed processes that would control fluxes in comparable unregulated rivers. Further, these results provide a foundation for detailed assessments of factors controlling the transport and chemical quality of DOC in the Colorado River.

  2. Development and application of a new biotechnology of the molasses in-situ method; detailed evaluation for selected wells in the Romashkino carbonate reservoir

    SciTech Connect

    Wagner, M.; Lungerhausen, D.; Murtada, H.; Rosenthal, G.

    1995-12-31

    On the basis of different laboratory studies, by which special strains of the type Clostridium tyrobutyricum were found, the application of molasses in-situ method for the enhanced recovery of oil in Romashkino oil field was executed. In an anaerobic, 6%-molasses medium the strains produce about 11,400 mg/l of organic acids (especially butyric acid), 3,200 mg/l ethanol, butanol, etc., and more than 350 ml/g of molasses biogas with a content of 80% C0{sub 2} and 20% H{sub 2}. The metabolics of Clostridium tyrobutyricum depress the growth of SRB, whereas methanogenic bacteria grow in an undiluted fermented molasses medium very well. In this way the dominant final fermentation process is methanogenesis. By laboratory studies with original cores under the conditions of the carbonate reservoir in Bashkir, the recovery of oil increased from 15% after waterflooding to 29% OOIP during the treatment with molasses and bacteria. We developed a new biotechnological method for a self-regulated, automatic continuous culture and constructed a special pilot plant with a high technical standard. The plant produced during the pilot on Romashkino field (September 1992 to August 1994) about 1,000 m{sup 3} of clean inoculum with a content of 3-4 billion cells per ml. This inoculum was injected in slugs together with 15,000 m{sup 3} of molasses medium, first in one, later in five wells. We will demonstrate for two example wells the complex microbiological and chemical changes in the oil, gas, and water phases, and their influences on the recover of oil.

  3. Impact of CO2 leakage from sub-seabed carbon dioxide capture and storage (CCS) reservoirs on benthic virus–prokaryote interactions and functions

    PubMed Central

    Rastelli, Eugenio; Corinaldesi, Cinzia; Dell’Anno, Antonio; Amaro, Teresa; Queirós, Ana M.; Widdicombe, Stephen; Danovaro, Roberto

    2015-01-01

    Atmospheric CO2 emissions are a global concern due to their predicted impact on biodiversity, ecosystems functioning, and human life. Among the proposed mitigation strategies, CO2 capture and storage, primarily the injection of CO2 into marine deep geological formations has been suggested as a technically practical option for reducing emissions. However, concerns have been raised that possible leakage from such storage sites, and the associated elevated levels of pCO2 could locally impact the biodiversity and biogeochemical processes in the sediments above these reservoirs. Whilst a number of impact assessment studies have been conducted, no information is available on the specific responses of viruses and virus–host interactions. In the present study, we tested the impact of a simulated CO2 leakage on the benthic microbial assemblages, with specific focus on microbial activity and virus-induced prokaryotic mortality (VIPM). We found that exposure to levels of CO2 in the overlying seawater from 1,000 to 20,000 ppm for a period up to 140 days, resulted in a marked decrease in heterotrophic carbon production and organic matter degradation rates in the sediments, associated with lower rates of VIPM, and a progressive accumulation of sedimentary organic matter with increasing CO2 concentrations. These results suggest that the increase in seawater pCO2 levels that may result from CO2 leakage, can severely reduce the rates of microbial-mediated recycling of the sedimentary organic matter and viral infections, with major consequences on C cycling and nutrient regeneration, and hence on the functioning of benthic ecosystems. PMID:26441872

  4. 32 CFR 636.31 - Abandoned vehicles.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... § 636.31 Abandoned vehicles. (a) Any MP or DOD police officer who finds or has knowledge of a motor... MP or DOD police officer who, under the provisions of this section, causes any motor vehicle to be... motor vehicle by any MP or DOD police officer should not be within the scope of either that...

  5. Towards Understanding Methane Emissions from Abandoned Wells

    EPA Science Inventory

    Reconciliation of large-scale top-down methane measurements and bottom-up inventories requires complete accounting of source types. Methane emissions from abandoned oil and gas wells is an area of uncertainty. This presentation reviews progress to characterize the potential inv...

  6. 18 CFR 157.216 - Abandonment.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... Interstate Pipeline Blanket Certificates and Authorization Under Section 7 of the Natural Gas Act for Certain... abandon: (1) Any receipt or delivery point if all of the existing customers of the pipeline served through...) showing the location of the proposed facilities and a concise analysis discussing the relevant...

  7. 18 CFR 157.216 - Abandonment.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... Interstate Pipeline Blanket Certificates and Authorization Under Section 7 of the Natural Gas Act for Certain... abandon: (1) Any receipt or delivery point if all of the existing customers of the pipeline served through...) showing the location of the proposed facilities and a concise analysis discussing the relevant...

  8. 18 CFR 157.216 - Abandonment.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... Interstate Pipeline Blanket Certificates and Authorization Under Section 7 of the Natural Gas Act for Certain... abandon: (1) Any receipt or delivery point if all of the existing customers of the pipeline served through...) showing the location of the proposed facilities and a concise analysis discussing the relevant...

  9. 32 CFR 636.31 - Abandoned vehicles.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 32 National Defense 4 2010-07-01 2010-07-01 true Abandoned vehicles. 636.31 Section 636.31 National Defense Department of Defense (Continued) DEPARTMENT OF THE ARMY (CONTINUED) LAW ENFORCEMENT AND CRIMINAL INVESTIGATIONS MOTOR VEHICLE TRAFFIC SUPERVISION (SPECIFIC INSTALLATIONS) Fort Stewart,...

  10. An integrated study of the Grayburg/San Andres Reservoir, Foster and South Cowden Fields, Ector County, Texas. Annual report, August 1, 1996--July 31, 1997

    SciTech Connect

    Trentham, R.C.; Weinbrandt, R.; Robinson, W.

    1997-12-01

    The objective of this two-phase study is to demonstrate an integrated methodology for reservoir characterization of shallow shelf carbonate reservoir that is feasible, and cost effective for the independent operator. Furthermore, it will provide one of the first public demonstrations of the enhancement of reservoir characterization using high-resolution three dimensional (3D) seismic data. This particular project is evaluating the Grayburg and San Andres reservoirs in the Foster and South Cowden Fields, Ector County, Texas. This 68 year old field was approaching its economic limit and the leases evaluated would have been abandoned in 10 years. A multidisciplinary approach to waterflood design and implementation, along with the addition of reserves by selective infill drilling and deepening, is being applied to this field. This approach in reservoir development will be applicable to a wide range of shallow shelf carbonate reservoirs throughout the US. The first phase of the project included the design, acquisition, and interpretation of the 3D seismic survey, the collection and evaluation of geologic (core and log) data, and engineering (historical production, well test, injection) data from a variety of sources. From this work, a geologically based production history model was simulated. Based on the recommendations made at the end of Phase One, three new wells were drilled, one existing well was deepened, two wells were worked over, one TA`d well was re-entered, and one well was converted to injection. In addition, the quality of the injection water was greatly improved, a step necessary prior to increasing injection in the project area. The realignment of the waterflood and all additional well work await the completion of the seismic based history match and engineering simulation.

  11. Opportunities to improve oil productivity in unstructured deltaic reservoirs

    SciTech Connect

    Not Available

    1991-01-01

    This report contains presentations presented at a technical symposium on oil production. Chapter 1 contains summaries of the presentations given at the Department of Energy (DOE)-sponsored symposium and key points of the discussions that followed. Chapter 2 characterizes the light oil resource from fluvial-dominated deltaic reservoirs in the Tertiary Oil Recovery Information System (TORIS). An analysis of enhanced oil recovery (EOR) and advanced secondary recovery (ASR) potential for fluvial-dominated deltaic reservoirs based on recovery performance and economic modeling as well as the potential resource loss due to well abandonments is presented. Chapter 3 provides a summary of the general reservoir characteristics and properties within deltaic deposits. It is not exhaustive treatise, rather it is intended to provide some basic information about geologic, reservoir, and production characteristics of deltaic reservoirs, and the resulting recovery problems.

  12. 4. INTERIOR OF ABANDONED SANTA ANA CANAL TUNNEL, SHOWING CEMENT ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    4. INTERIOR OF ABANDONED SANTA ANA CANAL TUNNEL, SHOWING CEMENT TROUGH FLOOR AND UNFINISHED GRANITE ROOF. VIEW TO SOUTHWEST. - Santa Ana River Hydroelectric System, Abandoned Tunnel, Redlands, San Bernardino County, CA

  13. Trophic status evaluation of TVA reservoirs

    SciTech Connect

    Placke, J.F.

    1983-10-01

    TVA tributary and mainstem reservoirs show generalized differences in morphometry, hydraulics, nutrient loads, and response to nutrient concentrations. Neither type of reservoir is strictly comparable to the natural lakes on which classical eutrophication studies have been based. The majority of published trophic state indices and standards (e.g., hypolimnetic dissolved oxygen depletion, Secchi depth, areas nutrient loading rates, in-reservoir phosphorus concentrations) are inappropriate for evaluation of some or all TVA reservoirs. No single trophic potential or trophic response variable summarizes the mechanisms and manifestations of eutrophication sufficiently to be used as a sole criterion for judging or regulating TVA reservoir water quality. Relative multivariate trophic state indices were developed for mainstem and tributary reservoirs. Ranking of the mainstem reservoirs is based on chlorophyll, macrophyte coverage, hydraulic retention time, reservoir area less than five feet deep, annual pool elevation drawdown, and Secchi depth. Based on available data, the rank from least eutrophic to most eutrophic is: Pickwick, Kentucky, Chickamauga, Nickajack, Wilson, Fort Loudoun, Watts Bar, Wheeler, and Guntersville Reservoirs. Ranking of the tributary reservoirs is based on chlorophyll, total phosphorus and total nitrogen weighted by the N:P ratio, and bio-available inorganic carbon levels. The rank from least eutrophic to most eutrophic is: Hiwassee, Blue Ridge, Chatuge, Norris and Fontana, Watauga, South Holston, Tims Ford, Cherokee, Douglas, and Boone Reservoirs. 130 references, 18 figures, 30 tables.

  14. Geoscience/engineering characterization of the interwell environment in carbonate reservoirs based on outcrop analogs, Permian Basin, West Texas and New Mexico--waterflood performance analysis for the South Cowden Grayburg Reservoir, Ector County, Texas. Final report

    SciTech Connect

    Jennings, J.W. Jr.

    1997-05-01

    A reservoir engineering study was conducted of waterflood performance in the South Cowden field, an Upper Permian Grayburg reservoir on the Central Basin Platform in West Texas. The study was undertaken to understand the historically poor waterflood performance, evaluate three techniques for incorporating petrophysical measurements and geological interpretation into heterogeneous reservoir models, and identify issues in heterogeneity modeling and fluid-flow scaleup that require further research. The approach included analysis of relative permeability data, analysis of injection and production data, heterogeneity modeling, and waterflood simulation. The poor South Cowden waterflood recovery is due, in part, to completion of wells in only the top half of the formation. Recompletion of wells through the entire formation is estimated to improve recovery in ten years by 6 percent of the original oil in place in some areas of the field. A direct three-dimensional stochastic approach to heterogeneity modeling produced the best fit to waterflood performance and injectivity, but a more conventional model based on smooth mapping of layer-averaged properties was almost as good. The results reaffirm the importance of large-scale heterogeneities in waterflood modeling but demonstrate only a slight advantage for stochastic modeling at this scale. All the flow simulations required a reduction to the measured whole-core k{sub v}/k{sub h} to explain waterflood behavior, suggesting the presence of barriers to vertical flow not explicitly accounted for in any of the heterogeneity models. They also required modifications to the measured steady-state relative permeabilities, suggesting the importance of small-scale heterogeneities and scaleup. Vertical flow barriers, small-scale heterogeneity modeling, and relative permeability scaleup require additional research for waterflood performance prediction in reservoirs like South Cowden.

  15. Underground Pumped Storage Hydroelectricity using Abandoned Works (open pits and deep mines)

    NASA Astrophysics Data System (ADS)

    Pujades, E.; Willems, T.; Bodeux, S.; Orban, P.; Dassargues, A.

    2015-12-01

    Pumped Storage Hydroelectricity (PSH) is a good alternative to increase the efficiency of power plants, which cannot regulate the amount of electricity generated according to the demand (wind, solar or even nuclear power plants). PSH plants, which consist in two reservoirs located at different heights (upper and lower), can store energy during low demand periods (pumping water from the lower to the upper reservoir) and generate electricity during the high demand peaks (falling water from the upper to the lower reservoir). Given that the two reservoirs must be located at different heights, PSH plants cannot be constructed in flat regions. Nevertheless, in these regions, an alternative could be to use abandoned underground works (open pits or deep mines) as lower reservoirs to construct Underground Pumped Storage Hydroelectricity (UPSH) plants. To select the best place to construct a plant, two considerations must be taken into account regarding the interaction between UPSH plants and groundwater: 1) the alteration of the natural conditions of aquifers and 2), the efficiency of the plant since the electricity generated depends on the hydraulic head inside the underground reservoir. Obviously, a detailed numerical model must be necessary before to select a location. However, a screening methodology to reject the most disadvantageous sites in a short period of time would be useful. Groundwater flow impacts caused by UPSH plants are analyzed numerically and the main variables involved in the groundwater evolution are identified. The most noticeable effect consists in an oscillation of the groundwater. The hydraulic head around which groundwater oscillates, the magnitude of the oscillations and the time to achieve a "dynamic steady state" depend on the boundaries, the parameters of the aquifer and the characteristics of the underground reservoir. A screening methodology is proposed to assess the main impacts caused in aquifers by UPSH plants. Finally, the efficiency

  16. Improved oil recovery in Mississippian carbonate reservoirs of Kansas -- Near term -- Class 2. Annual report, September 18, 1994--October 1, 1995

    SciTech Connect

    Carr, T.R.; Green, D.W.; Willhite, G.P.

    1996-08-01

    This report represents a summary of the progress during the first year of Budget period 1 of the project. Two examples of advanced technologies developed as part of this project are highlighted along with the use of the Internet to transfer these technologies. The two advanced technologies are a spread-sheet petrophysical analysis and reservoir evaluation (PfEFFER), and a petrophysical/seismic approach to well logs (pseudoseismic). Work continues on multi-disciplinary reservoir characterization at the demonstration site. The potential for incremental primary recovery is being evaluated using the improved reservoir characterization to target infill drilling and evaluate the potential of a horizontal well. The impact of demonstrating additional incremental primary recovery from sub-Pennsylvanian unconformity Mississippian reservoirs would be significant for Kansas and the US.

  17. 30 CFR 256.56 - Lease-specific abandonment accounts.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 2 2010-07-01 2010-07-01 false Lease-specific abandonment accounts. 256.56... OF SULPHUR OR OIL AND GAS IN THE OUTER CONTINENTAL SHELF Bonding § 256.56 Lease-specific abandonment accounts. (a) The Regional Director may authorize you to establish a lease-specific abandonment account...

  18. Non-Abandonment as a Foundation for Inclusive School Practice

    ERIC Educational Resources Information Center

    Razer, Michal; Friedman, Victor J.

    2013-01-01

    The authors of this article describe an essential feature of inclusive educational practice: "non-abandonment". When students' needs and difficult behavior are overwhelming, teachers may abandon them emotionally as a defensive reaction to their own experience of emotional distress and helplessness. Non-abandonment represents a…

  19. 25 CFR 214.29 - Prospecting; abandonment of mines.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... RESERVATION LANDS, OKLAHOMA, FOR MINING, EXCEPT OIL AND GAS § 214.29 Prospecting; abandonment of mines. All prospecting or mining operations or the abandonment of a well or mine shall be subject to the approval of the... 25 Indians 1 2010-04-01 2010-04-01 false Prospecting; abandonment of mines. 214.29 Section...

  20. 19 CFR 18.44 - Abandonment of exportation.