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Sample records for abandoned peat extraction

  1. Life-cycle assessment of a reed canary grass plantation in an abandoned peat extraction area to mitigate GHG emission

    NASA Astrophysics Data System (ADS)

    Mander, Ülo

    2013-04-01

    Abandoned peat extraction areas are continuous emitters of greenhouse gases (GHG); hence, abandonment of peat extraction areas should immediately be followed by conversion to an appropriate after-use. Our primary aim was to clarify the atmospheric impact of reed canary grass (RCG, Phalaris arundinacea L.) cultivation on an abandoned peat extraction area and to compare it to other after-treatment alternatives. In addition to measurement of GHGs using the closed chamber and gas-chromatograph method, measuring C and N balance in study plots and aboveground and belowground biomass of RCG for the period April 2009-September 2011, we performed a life-cycle assessment for five different after-use options for a drained organic soil withdrawn from peat extraction: (I) bare peat soil (no management), (II) non-fertilised Phalaris cultivation, (III) fertilized Phalaris cultivation, (IV) afforestation, and (V) rewetting. Our results showed that on average the non-fertilised and fertilised Phalaris alternatives had a cooling effect on the atmosphere, whereas afforestation, rewetting, and no management alternatives contributed to global warming. The main components influencing the global warming potential of different after-use alternatives were site GHG emissions, carbon assimilation by plants, and emissions from combustion, while management-related emissions played a relatively minor role. The results of this study indicate that, from the perspective of atmospheric impact during following 10 years, the most suitable after-use option for an abandoned peat extraction area is cultivation of RCG. For the long term effect, dynamics of Phalaris production and carbon sequestration in soil must be taken into the consideration.

  2. Impact of Reed Canary Grass Cultivation and Mineral Fertilisation on the Microbial Abundance and Genetic Potential for Methane Production in Residual Peat of an Abandoned Peat Extraction Area.

    PubMed

    Espenberg, Mikk; Truu, Marika; Truu, Jaak; Maddison, Martin; Nõlvak, Hiie; Järveoja, Järvi; Mander, Ülo

    This study examined physiochemical conditions and prokaryotic community structure (the bacterial and archaeal 16S rRNA genes and mcrA gene abundances and proportions), and evaluated the effect of reed canary grass cultivation and mineral fertilisation on these factors, in the 60 cm thick residual peat layer of experimental plots located on an abandoned peat extraction area. The archaeal proportion was 0.67-39.56% in the prokaryotic community and the methanogens proportion was 0.01-1.77% in the archaeal community. When bacterial abundance was higher in the top 20 cm of peat, the archaea were more abundant in the 20-60 cm layer and methanogens in the 40-60 cm layer of the residual peat. The bacterial abundance was significantly increased, but archaeal abundance was not affected by cultivation. The fertiliser application had a slight effect on peat properties and on archaeal and methanogen abundances in the deeper layer of cultivated peat. The CH4 emission was positively related to mcrA abundance in the 20-60 cm of the bare peat, while in case of reed canary grass cultivation these two parameters were not correlated. Reed canary grass cultivation mitigated CH4 emission, although methanogen abundance remained approximately the same or even increased in different layers of residual peat under cultivated sites over time. This study supports the outlook of using abandoned peat extraction areas to produce reed canary grass for energy purposes as an advisable land-use practice from the perspective of atmospheric impact in peatland-rich Northern Europe.

  3. Impact of Reed Canary Grass Cultivation and Mineral Fertilisation on the Microbial Abundance and Genetic Potential for Methane Production in Residual Peat of an Abandoned Peat Extraction Area

    PubMed Central

    Espenberg, Mikk; Truu, Marika; Truu, Jaak; Maddison, Martin; Nõlvak, Hiie; Järveoja, Järvi; Mander, Ülo

    2016-01-01

    This study examined physiochemical conditions and prokaryotic community structure (the bacterial and archaeal 16S rRNA genes and mcrA gene abundances and proportions), and evaluated the effect of reed canary grass cultivation and mineral fertilisation on these factors, in the 60 cm thick residual peat layer of experimental plots located on an abandoned peat extraction area. The archaeal proportion was 0.67–39.56% in the prokaryotic community and the methanogens proportion was 0.01–1.77% in the archaeal community. When bacterial abundance was higher in the top 20 cm of peat, the archaea were more abundant in the 20–60 cm layer and methanogens in the 40–60 cm layer of the residual peat. The bacterial abundance was significantly increased, but archaeal abundance was not affected by cultivation. The fertiliser application had a slight effect on peat properties and on archaeal and methanogen abundances in the deeper layer of cultivated peat. The CH4 emission was positively related to mcrA abundance in the 20–60 cm of the bare peat, while in case of reed canary grass cultivation these two parameters were not correlated. Reed canary grass cultivation mitigated CH4 emission, although methanogen abundance remained approximately the same or even increased in different layers of residual peat under cultivated sites over time. This study supports the outlook of using abandoned peat extraction areas to produce reed canary grass for energy purposes as an advisable land-use practice from the perspective of atmospheric impact in peatland-rich Northern Europe. PMID:27684377

  4. Revegetation processes and environmental conditions in abandoned peat production fields in Estonia

    NASA Astrophysics Data System (ADS)

    Orru, M.; Orru, H.

    2009-04-01

    As a result of peat extraction, peat production has been finished in Estonia at different times in 154 peat production areas and 9,500 ha (~1% of peatlands) are abandoned, although the peat reserves are not exhausted yet; besides, several areas are not properly recultivated. In addition 12,000 ha of fens (oligotrophic peat layers) are drained and used as grasslands. If the abandoned and non-recultivated peat production areas are not vegetated, their CO2 emission is considerable and peat mineralises in such areas. The aim of the study was to find out specific ecological and geological factors, which affect recovering of peatlands and influence the recultivation. During the revision the amount and quality of the remained reserves, as well as the state of water regime, drainage network and revegetation was assessed in all 154 abandoned peat production areas. The study showed that the state of them is very variable. Some of them are covered with forest, prevailingly with birches at former drainage ditches, later supplemented by pine trees. In the others predominate grasses among plants, and various species of moss (Cladonia rei, Bryum caespiticum, Sphagnum ripariuma, Sphagnum squarrosum) occur as well. Besides, some abandoned areas are completely overgrown with cotton grass. Open abandoned peat areas, which are not covered by vegetation, are much rarer. We found out, that water regime among the factors plays most important role. Moreover abandoned peat production fields, where the environmental conditions have changed - are appropriate for growth of several moss species, which cannot inhabit the areas already occupied by other species. The most interesting discovers were: second growing site of Polia elongata in West-Estonia and Ephemerum serratum, last found in Estonia in the middle of the 19th century, was identified in central Estonia. Also Campylopus introflexus, what was unknown in Estonia. However, the changes in environmental conditions influence the peat layers

  5. Peat

    USGS Publications Warehouse

    Apodaca, Lori E.

    2013-01-01

    The article looks at the U.S. peat market as of July 2013. Peat is produced from deposits of plant organic materials in wetlands and includes varieties such as reed-sedge, sphagnum moss, and humus. Use for peat include horticultural soil additives, filtration, and adsorbents. Other topics include effects of environmental protection regulations on peat extraction, competition from products such as coir, composted organic waste, and wood products, and peatland carbon sinks.

  6. Peat

    USGS Publications Warehouse

    Jasinski, S.M.

    2006-01-01

    In 2005, peat was harvested in 15 US states. Florida, Michigan and Minnesota accounted for more than 80% of the US production. Reed-sedge was the dominant variety of peat harvested in the United States. More than 56% of all peat used in the US was imported from Canada. With the growing interest in gardening, landscaping related to home construction and golf courses, peat usage is expected to remain near current levels during the next several years.

  7. Peat

    USGS Publications Warehouse

    Apodaca, L.E.

    2011-01-01

    In 2010, domestic production of peat, excluding Alaska, was estimated to be 612 kt (674,600 st), compared with 609 kt (671,300 st) in 2009. In 2010, imports increased to 947 kt (1.04 million st), compared with 906 kt (998,600 st) in 2009. Exports were estimated to have decreased to 69 kt (76,000 st) in 2010. U.S. apparent consumption for 2010 was estimated to have increased to 1.5 Mt (1.65 million st). World production was estimated to be about 23 Mt (25 million st) in 2010, which is 8 percent lower than in 2009.

  8. Peat

    USGS Publications Warehouse

    Apodaca, L.E.

    2013-01-01

    In 2012, domestic production of peat, excluding Alaska, was estimated to be 560 kt (617,000 st), compared with 568 kt (626,000 st) in 2011. In 2012, imports decreased to 940 kt (1 million st) compared with 982 kt (1.1 million st) in 2011, and exports were estimated to have increased to 75 kt (82,600 st) in 2012. U.S. apparent consumption for 2012 was estimated to have remained the same as that of 2011. World production was estimated to be about 27 Mt (30 million st) in 2012, which was slightly higher than 2011.

  9. Peat

    USGS Publications Warehouse

    Apodaca, L.E.

    2012-01-01

    In 2011, domestic production of peat, excluding Alaska, was estimated to be 605 kt (667,000 st), compared with 628 kt (629,000 st) in 2010. In 2011, imports increased to 1.1. Mt (1.2 million st) compared with 947 kt (1 million st) in 2010, and exports were estimated to have decreased to 39 kt (43,000 st) in 2011. U.S. apparent consumption for 2011 was estimated to have increased to 1.6 Mt (1.7 million st). World production was estimated to be about 22 Mt (24 million st) in 2011, which was 6 percent lower than 2010.

  10. Peat

    USGS Publications Warehouse

    Apodaca, L.E.

    2010-01-01

    In 2009, domestic production of peat, excluding Alaska, was estimated to be 610 kt (672,000 st), compared with 615 kt (678,000 st) in 2008. In 2009, imports decreased to 906 kt (999,000 st) compared with 936 kt (1 million st) in 2008, and exports were estimated to have increased to 77 kt (85,000 st) in 2009. U.S. apparent consumption for 2009 was estimated to be about the same as in 2008. World production was estimated to be about 25 Mt (27.5 million st) in 2009, which is about the same as 2008.

  11. Physiological changes in rhizobia after growth in peat extract may be related to improved desiccation tolerance.

    PubMed

    Casteriano, Andrea; Wilkes, Meredith A; Deaker, Rosalind

    2013-07-01

    Improved survival of peat-cultured rhizobia compared to survival of liquid-cultured cells has been attributed to cellular adaptations during solid-state fermentation in moist peat. We have observed improved desiccation tolerance of Rhizobium leguminosarum bv. trifolii TA1 and Bradyrhizobium japonicum CB1809 after aerobic growth in water extracts of peat. Survival of TA1 grown in crude peat extract was 18-fold greater than that of cells grown in a defined liquid medium but was diminished when cells were grown in different-sized colloidal fractions of peat extract. Survival of CB1809 was generally better when grown in crude peat extract than in the control but was not statistically significant (P > 0.05) and was strongly dependent on peat extract concentration. Accumulation of intracellular trehalose by both TA1 and CB1809 was higher after growth in peat extract than in the defined medium control. Cells grown in water extracts of peat exhibit morphological changes similar to those observed after growth in moist peat. Electron microscopy revealed thickened plasma membranes, with an electron-dense material occupying the periplasmic space in both TA1 and CB1809. Growth in peat extract also resulted in changes to polypeptide expression in both strains, and peptide analysis by liquid chromatography-mass spectrometry indicated increased expression of stress response proteins. Our results suggest that increased capacity for desiccation tolerance in rhizobia is multifactorial, involving the accumulation of trehalose together with increased expression of proteins involved in protection of the cell envelope, repair of DNA damage, oxidative stress responses, and maintenance of stability and integrity of proteins.

  12. Long-term purification efficiency of a wetland constructed to treat runoff from peat extraction.

    PubMed

    Karjalainen, Satu M; Heikkinen, Kaisa; Ihme, Raimo; Kløve, Bjørn

    2016-01-01

    Peat extraction increases the phosphorus, nitrogen, organic matter, suspended solids, and iron concentrations in runoff, resulting in negative effects on downstream water bodies. Wetlands are commonly used as natural cost-effective solutions to mitigate these negative effects. This study analyzed changes in the quality of runoff water from peat extraction areas and the long-term efficiency of constructed wetlands. The results indicate that the quality of runoff water changed after the initial drainage and during peat extraction. Nitrogen leached at high concentrations in the early stages of peat extraction following drainage, whereas the leaching of iron and phosphorus increased after peat extraction from deeper layers. Comparison of water quality and impurities retained immediately after treatment wetland construction and 14 years later showed that the treatment wetland remained functional, with good retention capacity, over a long period.

  13. Effects of peat fires on the characteristics of humic acid extracted from peat soil in Central Kalimantan, Indonesia.

    PubMed

    Yustiawati; Kihara, Yusuke; Sazawa, Kazuto; Kuramitz, Hideki; Kurasaki, Masaaki; Saito, Takeshi; Hosokawa, Toshiyuki; Syawal, M Suhaemi; Wulandari, Linda; Hendri I; Tanaka, Shunitz

    2015-02-01

    When peat forest fires happen, it leads to burn soil and also humic acids as a dominant organic matter contained in peat soil as well as the forest. The structure and properties of humic acids vary depending on their origin and environment, therefore the transformation of humic acid is also diverse. The impacts of the peat fires on peat soil from Central Kalimantan, Indonesia were investigated through the characterization of humic acids, extracted from soil in burnt and unburnt sites. The characterization of humic acids was performed by elemental composition, functional groups, molecular weight by HPSEC, pyrolysate compounds by pyrolysis-GC/MS, fluorescence spectrum by 3DEEM spectrofluorometer, and thermogravimetry. The elemental composition of each humic substance indicated that the value of H/C and O/C of humic acids from burnt sites were lower than that from unburnt sites. The molecular weight of humic acids from burnt sites was also lower than that from unburnt sites. Pyrolysate compounds of humic acids from unburnt sites differed from those of humic acids from burnt soil. The heating experiment showed that burning process caused the significant change in the properties of humic acids such as increasing the aromaticity and decreasing the molecular weight.

  14. Peat Processing

    NASA Technical Reports Server (NTRS)

    1986-01-01

    Humics, Inc. already had patented their process for separating wet peat into components and processing it when they consulted NERAC regarding possible applications. The NERAC search revealed numerous uses for humic acid extracted from peat. The product improves seed germination, stimulates root development, and improves crop yields. There are also potential applications in sewage disposal and horticultural peat, etc.

  15. Impact of water table level on annual carbon and greenhouse gas balances of a restored peat extraction area

    NASA Astrophysics Data System (ADS)

    Järveoja, Järvi; Peichl, Matthias; Maddison, Martin; Soosaar, Kaido; Vellak, Kai; Karofeld, Edgar; Teemusk, Alar; Mander, Ülo

    2016-05-01

    Peatland restoration may provide a potential after-use option to mitigate the negative climate impact of abandoned peat extraction areas; currently, however, knowledge about restoration effects on the annual balances of carbon (C) and greenhouse gas (GHG) exchanges is still limited. The aim of this study was to investigate the impact of contrasting mean water table levels (WTLs) on the annual C and GHG balances of restoration treatments with high (ResH) and low (ResL) WTL relative to an unrestored bare peat (BP) site. Measurements of carbon dioxide (CO2), methane (CH4) and nitrous oxide (N2O) fluxes were conducted over a full year using the closed chamber method and complemented by measurements of abiotic controls and vegetation cover. Three years following restoration, the difference in the mean WTL resulted in higher bryophyte and lower vascular plant cover in ResH relative to ResL. Consequently, greater gross primary production and autotrophic respiration associated with greater vascular plant cover were observed in ResL compared to ResH. However, the means of the measured net ecosystem CO2 exchanges (NEE) were not significantly different between ResH and ResL. Similarly, no significant differences were observed in the respective means of CH4 and N2O exchanges. In comparison to the two restored sites, greater net CO2, similar CH4 and greater N2O emissions occurred in BP. On the annual scale, ResH, ResL and BP were C sources of 111, 103 and 268 g C m-2 yr-1 and had positive GHG balances of 4.1, 3.8 and 10.2 t CO2 eq ha-1 yr-1, respectively. Thus, the different WTLs had a limited impact on the C and GHG balances in the two restored treatments 3 years following restoration. However, the C and GHG balances in ResH and ResL were considerably lower than in BP due to the large reduction in CO2 emissions. This study therefore suggests that restoration may serve as an effective method to mitigate the negative climate impacts of abandoned peat extraction areas.

  16. Only low methane production and emission in degraded peat extraction sites after rewetting

    NASA Astrophysics Data System (ADS)

    Agethen, Svenja; Waldemer, Carolin; Knorr, Klaus-Holger

    2015-04-01

    In Central Europe rewetting of bogs after peat extraction is a wide spread technique to halt secondary aerobic decomposition and to reestablish plant species such as Sphagnum spp. and Eriophorum spp. that initialize accumulation of organic carbon in peat. Before extraction, such sites are often used for agriculture causing the aerobic degradation of peat and mobilization of phosphorus, ammonia, and dissolved organic matter (DOM). In nutrient poor ecosystems such as bogs, additional supply of P and N does not only trigger the establishment of uncharacteristic vegetation but also the formation of more labile plant litter and DOM that is readily degradable. Therefore, after rewetting and the development of anoxic conditions especially in initial stages high methane (CH4) emissions are reported for these systems compared to pristine bogs. Regarding the potential of methane production and emissions we investigated three common practices to prepare extraction fields for restoration (years since rewetting): i) Filling of drainage ditches, passive rewetting (1 site, Altendorfer Moor, Stade, NW-Germany, ca. 20 yr.), ii) Removal of upper 30 cm peat layer, removed peat used for construction of polder dikes (2 sites, Königsmoor, Leer, NW-Germany, 2 and 3 yr.), iii) Removal upper peat layer down to 50 cm grown peat, not extracted peat used as polder walls (2 sites, Benthullener Moor, Wardenburg, NW-Germany, 3 and 7 yr.). In each site two vegetated replicate mesocosms (diam. 30 cm, depth 40 cm) were sampled and placed in a greenhouse from May-October 2014 to maintain the water table at surface level. Pore water concentrations of ions, fermentation products and DOM, DOM electron acceptor capacity (EAC), soil gas concentrations of CO2, CH4 and H2, gas fluxes as well as element composition and organic matter quality of DOM and SOM were analyzed. We found out that practice i) with least efforts of nutrient removal in the peat produced the highest CH4 emissions (3.5 mmol m-2 d-1

  17. Distribution of toxic elements in the products of the extraction of bitumens from coal and peat

    SciTech Connect

    S.I. Zherebtsov; M.Yu. Klimovich; A.I. Moiseev

    2008-06-15

    The effect of bitumen extraction conditions on the behavior of a number of toxic trace elements (V, Cr, Ni, Cu, Zn, As, Sb, and Pb) in solid fossil fuel samples was studied. It was found that the capacity of fossil fuels to concentrate trace elements can be monitored and the type of compound can be determined based on the dimensionless quantities of carbophilicity and concentration factors of the trace elements in coal and peat. The types of compounds in fossil fuels were found and graphically represented for the test trace elements.

  18. Transvenous extraction of an abandoned endocardial pacemaker lead in a dog.

    PubMed

    LeBlanc, Nicole; Scollan, Katherine; Sisson, David

    2014-03-01

    A 6-year-old male castrated labrador retriever presented with endocardial pacemaker infection following migration and subsequent repositioning of the pulse generator. An epicardial lead and pulse generator were surgically implanted and the endocardial lead could not be removed with manual traction. The endocardial lead was severed, anchored, and abandoned at the thoracic inlet. The patient presented 4 months later with endocardial lead migration, bacteremia, and suspected glomerulonephritis. The endocardial pacemaker lead was transvenously extracted using a mechanical dilator sheath and locking stylet. This report of transvenous pacemaker lead extraction in a dog addresses the challenges and describes recent advances in extraction devices.

  19. [Extraction of Cd by ramie from soils as affected by applications of chelators and peat].

    PubMed

    Shen, Li-Ping; Zong, Liang-Gang; Jiang, Pei; Liu, Wei-Xing; Jiang, Bo; Chen, Ya-Hua

    2009-09-15

    Pot experiments were performed to study the effectiveness of chelators (EDTA, citric acid) and peat in enhancing phyremediation of heavy metal Cd by ramie. The results showed that peat increased the ramie's biomass by improving soil's physical and chemical properties, and the relative yields of peat alone, chelators(EDTA, citric acid) combined with peat were 1.23, 1.13 and 1.41 respectively. So the combination of citric acid and peat was more useful for growth of the ramie. As far as improving Cd uptake was concerned, it seemed that the combination of chelators with peat significantly promoted Cd uptake by the plant, and the percent of changeable Cd in soil were 61.6% and 58.3% . In addition, it had better bioaccumulation effects to combine with chelators and peat, of which Cd bioaccumulation coefficients were 1.33 and 1.32, compared to 1.11, 1.11 and 1.05 in application of peat, EDTA and citric acid respectively. What's more, cadmium removal rates in soil were up to 1.13% and 1.22% respectively in applications of two kinds of chleators (EDTA, citric acid) combined with peat. Therefore, it had better effects of phytoremediation to accumulate more cadmium amounts by combining with citric acid and peat because of more biomass. In conclusion, the phytoremediation by ramie can be more effective when chelators and peat were combined and added to soils.

  20. Case study: purification efficiency of a treatment wetland used at a peat extraction area

    NASA Astrophysics Data System (ADS)

    Eskelinen, Riku; Ronkanen, Anna-Kaisa; Marttila, Hannu; Kløve, Bjørn

    2014-05-01

    The inflow and outflow of a treatment wetland was intensively monitored between March 2012 and October 2012. Sampling was done with automated sampling equipment bidaily during the snowmelt period and daily for the rest of the study period. The treatment wetland is located downstream of a peat extraction area with a surface area of 208 ha. Drainage network at the peat extraction area has been fitted with peak flow control structures and a sedimentation basin from which the water is pumped to the treatment wetland. The treatment wetland has a surface area of 11 ha of peatland soil and is covered by grassy vegetation during the summer season. After flowing through the wetland water is discharging to a small stream through a v-notch weir. All samples were analysed for electric conductivity (EC), suspended solids (SS), Colour, Turbidity and pH. Additional analyses for various elements and nutrients were done for samples selected on the basis of hydrology. Results of the additional analyses represent the dissolved fraction of analysed elements as the samples were first filtrated with 0.45 µm filter for SS. Our results show that the purification efficiency varies during the measurement period. For example, to SS the overall purification efficiency was 62 %. However during the spring flood the purification efficiency is negative which can be caused by snowmelt water flushing previous year's dead vegetation or particulate matter accumulated during the winter period. After midsummer we can observe drastic increase in the retention of SS. Similar pattern can be seen in the retention of phosphorous with overall retention of 11 % of the total phosphorous. In the case of nitrogen the overall performance for the wetland is poor. Some of this can be explained by poor retention of NO2-3-N due to cold weather during spring melt season. However during the summer time denitrification process seems to be working as the retention of N improves. Retention of dissolved organic carbon

  1. Trialling a novel peat fuel extraction and reclamation technique: Vegetation recovery and peatland-atmosphere carbon fluxes

    NASA Astrophysics Data System (ADS)

    Morris, Paul J.; Wihelm, Lana P.; Solondz, Danielle M.; Waddington, J. Mike

    2013-04-01

    Most existing methods for peat extraction are highly environmentally damaging and commonly convert extracted peatlands from slow but persistent sinks of atmospheric carbon to strong sources. Furthermore, the removal of the live moss surface during peat extraction greatly reduces these ecosystems' resilience and often prevents the successful re-establishment of peatland plants. We describe an experimental trial of a new extraction method, called the peat-block reclamation (PBR) method (also known as wet harvesting, the floating-block method, and the acrotelm-transplant method) that is designed to be less environmentally damaging. The PBR method involves removing the upper 0.3 to 0.5 m of peat, including the live vegetation mat, and setting it aside. Peat is then extracted from below this depth and removed for processing. The conserved surficial peat blocks and the live vegetation are then immediately transplanted back into the extraction pit. We performed a small (12 × 12 m) experimental trial of PBR at a poor fen in northern Ontario, Canada. Usually the extraction pit is drained or pumped of soil water; instead we left the pit inundated so that the transplanted blocks float low in a shallow pool. We wished to investigate whether this alteration to the method would promote the post-extraction maintenance of a healthy moss layer and the re-establishment of vascular plants. We also monitored peatland-atmosphere carbon gas fluxes from the plot and compared them to a nearby unaltered reference plot. Our measurements over two summers indicate mixed results. The wet conditions in the extraction pit appear to have suppressed CO2 fluxes from the experimental plot (average net ecosystem exchange of 1.4 g CO2 m-2 d-1), which were intermediate between those from hummocks (-1.5 g CO2 m-2 d-1) and hollows (2.8 g CO2 m-2 d-1) in the reference plot. The low CO2 fluxes represent a major potential advantage for PBR over existing techniques, which commonly cause large increases in

  2. CO2 exchange following peat extraction - a comparison of two paired restored/unrestored peatlands

    NASA Astrophysics Data System (ADS)

    Strachan, Ian; Strack, Maria; Pelletier, Luc; Nugent, Kelly; Rankin, Tracy

    2016-04-01

    Peat extraction is an important industry in parts of Canada and elsewhere globally. The resulting disturbance from drainage and vacuum-harvesting is mitigated through best practices which now incorporate restoration intended to return the peatland's biodiversity and greenhouse gas (GHG) exchange to that resembling the pre-disturbance state. We examine the net ecosystem exchange of CO2 (NEE) in two sets of paired peatlands. Within each pair, the extraction year was the same and the sites were treated identically post-extraction in terms of management (blocking drains or leveling as applicable). The first pair is located in the vicinity of Rivière-du-Loup, Québec, Canada and were harvested in 1980. The Bois-des-Bel (BDB) site was restored in 1999 following the methods of Quinty and Rochefort (2003). GHG fluxes have been studied at various points since restoration (e.g. Strack and Zuback, 2013) largely using chamber measurements. The site now hosts a thriving bog ecosystem with Sphagnum, Eriophorum and shrub communities. A site 30 km away near Saint-Alexandre de Kamouraska (SAK) was managed post-harvest as BDB with drains blocked but was left unrestored and now has only sparse Eriophorum with invasive species. The second pair of peatlands represents a newly extracted site near Seba Beach, Alberta, Canada. One field was restored (SBR) in autumn 2012 as per the Québec sites but with ditches infilled when the fields were levelled while the other (SBU) was left unrestored. In the summer of 2013, eddy covariance towers were installed at each location and measured NEE continuously at 10Hz throughout the subsequent periods. BDB and SBR remain operational today while SBU was removed in fall 2014 and SAK in fall 2015. In this presentation, we will focus on the coincident years of operation. After 15 years, BDB has measured NEE in the range of that observed at natural peatlands. A summer sink and winter release lead to annual uptake of CO2. At SAK, the lack of establishment

  3. Peat surface GHG fluxes related to peat hydrology in various tropical peat land uses

    NASA Astrophysics Data System (ADS)

    Jauhiainen, Jyrki; Silvennoinen, Hanna; Limin, Suwido; Vasander, Harri

    2010-05-01

    peat on tropical peat carbon dynamics is very difficult because of variations in environmental conditions (especially peat hydrology), peat and vegetation that are not collected systematically or reported adequately in studies. In this paper we (i.) compare the most important greenhouse gases, i.e. CO2, CH4, and N2O, related to peatland hydrology in typical land use types and peat drainage intensities, and (ii.) assess gaps existing in currently available GHG data collected from tropical peat in South-East Asia. Presented information is derived from our established GHG flux monitoring programs and reviewed values from literature. Land use types in GHG comparisons include selectively logged non-drained and drainage affected peat swamp forests, plantations, agricultural peat, and mismanaged abandoned peatlands. The results are discussed on basis of GHG dynamics controlling factors in various tropical peat land uses.

  4. Artificial radioactivity in fuel peat and peat ash in Finland after the Chernobyl accident

    SciTech Connect

    Mustonen, R.A.; Reponen, A.R.; Jantunen, M.J.

    1989-04-01

    The accident at the Chernobyl nuclear power plant in April 1986 caused very uneven deposition of radionuclides in Finland. The deposited radionuclides were found in relatively high concentrations in fuel peat and especially in peat ash because a thin surface layer of peat-production bogs was extracted as fuel peat soon after the fallout occurred. Concentrations of artificial radionuclides in fuel peat and peat ash were measured at six peat-fired power plants in Finland throughout the heating season 1986-87. Concentrations of /sup 137/Cs in composite peat samples varied between 30 and 3600 Bq kg-1 dry weight and in ash samples between 600 and 68,000 Bq kg-1. High concentrations in peat ash caused some restrictions to the utilization of peat ash for various purposes.

  5. Determination of low methylmercury concentrations in peat soil samples by isotope dilution GC-ICP-MS using distillation and solvent extraction methods.

    PubMed

    Pietilä, Heidi; Perämäki, Paavo; Piispanen, Juha; Starr, Mike; Nieminen, Tiina; Kantola, Marjatta; Ukonmaanaho, Liisa

    2015-04-01

    Most often, only total mercury concentrations in soil samples are determined in environmental studies. However, the determination of extremely toxic methylmercury (MeHg) in addition to the total mercury is critical to understand the biogeochemistry of mercury in the environment. In this study, N2-assisted distillation and acidic KBr/CuSO4 solvent extraction methods were applied to isolate MeHg from wet peat soil samples collected from boreal forest catchments. Determination of MeHg was performed using a purge and trap GC-ICP-MS technique with a species-specific isotope dilution quantification. Distillation is known to be more prone to artificial MeHg formation compared to solvent extraction which may result in the erroneous MeHg results, especially with samples containing high amounts of inorganic mercury. However, methylation of inorganic mercury during the distillation step had no effect on the reliability of the final MeHg results when natural peat soil samples were distilled. MeHg concentrations determined in peat soil samples after distillation were compared to those determined after the solvent extraction method. MeHg concentrations in peat soil samples varied from 0.8 to 18 μg kg(-1) (dry weight) and the results obtained with the two different methods did not differ significantly (p=0.05). The distillation method with an isotope dilution GC-ICP-MS was shown to be a reliable method for the determination of low MeHg concentrations in unpolluted soil samples. Furthermore, the distillation method is solvent-free and less time-consuming and labor-intensive when compared to the solvent extraction method.

  6. Greenhouse gas exchange of rewetted bog peat extraction sites and a Sphagnum cultivation site in northwest Germany

    NASA Astrophysics Data System (ADS)

    Beyer, C.; Höper, H.

    2015-04-01

    During the last decades an increasing area of drained peatlands has been rewetted. Especially in Germany, rewetting is the principal treatment on cutover sites when peat extraction is finished. The objectives are bog restoration and the reduction of greenhouse gas (GHG) emissions. The first sites were rewetted in the 1980s. Thus, there is a good opportunity to study long-term effects of rewetting on greenhouse gas exchange, which has not been done so far on temperate cutover peatlands. Moreover, Sphagnum cultivating may become a new way to use cutover peatlands and agriculturally used peatlands as it permits the economical use of bogs under wet conditions. The climate impact of such measures has not been studied yet. We conducted a field study on the exchange of carbon dioxide, methane and nitrous oxide at three rewetted sites with a gradient from dry to wet conditions and at a Sphagnum cultivation site in NW Germany over the course of more than 2 years. Gas fluxes were measured using transparent and opaque closed chambers. The ecosystem respiration (CO2) and the net ecosystem exchange (CO2) were modelled at a high temporal resolution. Measured and modelled values fit very well together. Annually cumulated gas flux rates, net ecosystem carbon balances (NECB) and global warming potential (GWP) balances were determined. The annual net ecosystem exchange (CO2) varied strongly at the rewetted sites (from -201.7 ± 126.8 to 29.7± 112.7g CO2-C m-2 a-1) due to differing weather conditions, water levels and vegetation. The Sphagnum cultivation site was a sink of CO2 (-118.8 ± 48.1 and -78.6 ± 39.8 g CO2-C m-2 a-1). The annual CH4 balances ranged between 16.2 ± 2.2 and 24.2 ± 5.0g CH4-C m-2 a-1 at two inundated sites, while one rewetted site with a comparatively low water level and the Sphagnum farming site show CH4 fluxes close to 0. The net N2O fluxes were low and not significantly different between the four sites. The annual NECB was between -185.5 ± 126.9 and 49

  7. Abandoned Mine Lands

    EPA Pesticide Factsheets

    Abandoned Mine Lands are those lands, waters, and surrounding watersheds where extraction, beneficiation, or processing of ores and minerals (excluding coal) has occurred. These lands also include areas where mining or processing activity is inactive.

  8. Content of lipids in finnish peat mires

    SciTech Connect

    Fagernaes, L.; Ekman, R.

    1985-01-01

    Peat is a potential raw material for chemical products. Peat extracts, bitumens, obtained from peat with neutral organic solvents, and, in particular, their wax fractions have been of interest with regard to their substituting for other natural waxes. Yields and characteristics of peat extracts have been studied by numerous researchers and acid and saponification values, molecular weights and elements analyses have been determined since the 1930s. New analytical methods have recently been introduced and made it possible to determine the amount and detailed composition of the lipid components of peat extracts by capillary gas chromatography (GC) and mass spectrometry. The aim of this study was to determine the yield and lipid composition of extracts from peat samples collected from different mires in Finland.

  9. Anti-inflammatory potential of peat moss extracts in lipopolysaccharide-stimulated RAW 264.7 macrophages.

    PubMed

    Choi, Woo-Suk; Jeong, Jin-Woo; Kim, Sung Ok; Kim, Gi-Young; Kim, Byung-Woo; Kim, Cheol Min; Seo, Yong-Bae; Kim, Woe-Yeon; Lee, Sang-Yeol; Jo, Kwon-Ho; Choi, Young Ju; Choi, Yung Hyun; Kim, Gun-Do

    2014-10-01

    The aim of the present study was to identify the anti-inflammatory and anti-oxidative effects of peat moss aqueous extract (PME) on lipopolysaccharide (LPS)-stimulated RAW 264.7 macrophages. To demonstrate the anti-inflammatory and antioxidant effects of PME, the levels of nitric oxide (NO) and cytokines were measured using Griess reagent and cytokine ELISA kits, respectively. Reverse transcriptase-polymerase chain reaction (RT-PCR) and western blot analysis were conducted to evaluate the expression of genes and proteins. Immunofluorescence was used to measure the expression and translocation of transcription factors. Pre-treatment with PME inhibited the production of prostaglandin E(2) and NO by suppressing the gene expression of cyclooxygenase-2 and inducible NO synthase, respectively. The LPS-stimulated gene expression and the production of tumor necrosis factor-α and interleukin-1β were significantly reduced by PME. In the LPS-stimulated RAW 264.7 cells, nuclear factor‑κB (NF-κB) translocated from the cytosol to the nucleus, while pre-treatment with PME induced the sequestration of NF-κB in the cytosol through the inhibition of IκBα degradation. In the same manner, PME contributed to the inhibition of the activation of mitogen-activated protein kinases. In addition, the PME-treated RAW 264.7 cells facilitated the activation of nuclear factor-like 2 (Nrf2) , and in turn, enhanced heme oxygenase-1 (HO-1) expression. These results indicate that PME exerts anti-inflammatory and antioxidant effects, and suggest that PME may neutralize inflammation and prevent cellular damage by oxidative stress.

  10. Supplementation with a proprietary blend of ancient peat and apple extract may improve body composition without affecting hematology in resistance-trained men.

    PubMed

    Joy, Jordan M; Falcone, Paul H; Vogel, Roxanne M; Mosman, Matt M; Kim, Michael P; Moon, Jordan R

    2015-11-01

    Adenosine-5'-triphosphate (ATP) is primarily known as a cellular source of energy. Increased ATP levels may have the potential to enhance body composition. A novel, proprietary blend of ancient peat and apple extracts has been reported to increase ATP levels, potentially by enhancing mitochondrial ATP production. Therefore, the purpose of this investigation was to determine the supplement's effects on body composition when consumed during 12 weeks of resistance training. Twenty-five healthy, resistance-trained, male subjects (age, 27.7 ± 4.8 years; height, 176.0 ± 6.5 cm; body mass, 83.2 ± 12.1 kg) completed this study. Subjects supplemented once daily with either 1 serving (150 mg) of a proprietary blend of ancient peat and apple extracts (TRT) or placebo (PLA). Supervised resistance training consisted of 8 weeks of daily undulating periodized training followed by a 2-week overreach and a 2-week taper phase. Body composition was assessed using dual-energy X-ray absorptiometry and ultrasound at weeks 0, 4, 8, 10, and 12. Vital signs and blood markers were assessed at weeks 0, 8, and 12. Significant group × time (p < 0.05) interactions were present for ultrasound-determined cross-sectional area, which increased in TRT (+0.91 cm(2)) versus PLA (-0.08 cm(2)), as well as muscle thickness (TRT: +0.46; PLA: +0.04 cm). A significant group × time (p < 0.05) interaction existed for creatinine (TRT: +0.06; PLA: +0.15 mg/dL), triglycerides (TRT: +24.1; PLA: -20.2 mg/dL), and very-low-density lipoprotein (TRT: +4.9; PLA: -3.9 mg/dL), which remained within clinical ranges. Supplementation with a proprietary blend of ancient peat and apple extracts may enhance resistance training-induced skeletal muscle hypertrophy without affecting fat mass or blood chemistry in healthy males.

  11. A Study on Extraction Method of Inorganic Arsenic Species in Abandoned Mine Soils of Korea

    NASA Astrophysics Data System (ADS)

    Shin, M.; Yoon, H.; Suh, J.

    2006-12-01

    It is important to determine the concentration of many toxic elements in environmental samples. However, the total concentration provides no information concerning the fate of the elements. Environmental fate, behavior, bioavailability, and toxicity of metals often vary dramatically with the chemical forms (species) in which metals exist. For example, inorganic arsenite [As (III)] and arsenate [As (V)] are toxic while methylarsonic acid [MMA(V)] and dimethylarseinic acid [DMA(V)] are less toxic. Thus, the assessments of environmental impact and human health risk solely based on the measurements of total element concentration become no longer reliable. It is important to identify and quantify individual chemical species of the element. A method to separate two inorganic arsenic species As(III) and As(V) by SPE HG-ICP-AES has been developed, based on extraction with a mixture of 1 mol phosphoric acid and 0.1 mol ascorbic acid. Hydride generation method by ICP-AES improved effectively the detection limit of the arsenic. Extraction instruments used in this study were the microwave system (Milestone 1200 Mega) and the ultrasound extraction method (Sonic Dismembrator 500, Fisher scientific). The separation of arsenic species was achieved on the anion exchange cartridge (Accell Plus QMA, Waters) with ammonium dihydrogen phosphate as mobile phase. SPE HG--ICP-AES coupled technique was applied to analyzed extracts of contaminated soil and SRM 2710. Analysis is performed as soon as possible (approximately within 1hour) after extraction. SPE HG--ICP-AES analysis showed the majority of solid phase arsenic to be arsenate (AsV), with AsIII accounting for <3% of extracted total inorganic arsenic. SRM 2710 (Montana soil) is not detected the AsIII. Both arsenite (AsIII) and arsenate (AsV) is increasing, according as size decreases (<64μm, 64-200μm, 2mm- 200μm). The extraction efficiency of contaminated soil samples, relative to the total arsenic concentration, varied from 15 to

  12. An attempt to extract climatic factors from δ13C record of sphagnum peat cores in both the hemispheres

    NASA Astrophysics Data System (ADS)

    Akagi, T.; Ooki, S.; Franzen, L.; McCulloch, R.

    2009-12-01

    The reconstruction of the atmospheric CO2 concentration of the near past less than 10,000 years ago is still poorly established, mainly because of the low time-resolution of the analysis of the air trapped in ice cores. To discuss the recent rapid change of the global climate, the CO2 record with time resolution as high as several tens years is needed. Carbon isotope ratio of sphagnum tissues may change depending on many factors. White et al. (1994) reconstructed the atmospheric CO2 concentration from δ13C data of sphagnum after the correction for a moisture condition using δ13C of carex. The work evoked the skepticism on the method from some scientists: for instance Price et al. (1997) reported that δ13C of sphagnum responded to a moisture condition parabolically, which cast a doubt on the correction method for moistness of White et al. (1994). However, our preliminary study of δ13C record of a mid-latitudal peat core from Japan presented an interesting δ13C profile resembling a high resolution record of sea level (Akagi et al., 2004), implying that the above-mentioned effects may not impose a serious constant influence over several tens of years on peat cores. To reevaluate the effectiveness of peat cores as a proxy of the atmospheric CO2, we have approached the problem from an opposite direction. Our hypothesis is that similar isotopic signals must be observed in any peat cores from the world, if the δ13C of sphagnum reflects the CO2 concentration in the atmosphere. In this paper the δ13C signals of the sphagnum collected from two high-latitudal peat cores (Farahogy, Northern Island, and Herberton, Argentine) from both the hemispheres are compared. The similarity and differences are discussed separately. The difference may be attributable to the temperature difference in both the hemispheres, and the similarity possibly to the atmospheric CO2 concentration, as the similarity again shows the fluctuation resembling the sea level fluctuation.

  13. Simulating the long-term response of peatlands to extraction and post-extraction management strategies

    NASA Astrophysics Data System (ADS)

    Quillet, Anne; Roulet, Nigel; Wu, Jianghua

    2016-04-01

    Peatlands have been and remain exploited either for agricultural purposes, forestry, peat extraction or infrastructure development in the northern latitudes as well as in the tropics. Modelling current and future carbon exchanges in peatlands thus requires further understanding of carbon dynamics in drained, exploited and restored peatlands. This study aimed at quantifying the centennial to millennial carbon balance in extracted and restored peatlands. On-site data measurements only started recently and only cover up to 15 years. The chosen approach was thus based on modelling. We modified the Holocene Peat Model (Frolking et al. 2010) to simulate peat extraction and restoration and calculate the carbon balance at different stages of exploitation and restoration. The model simulates drainage occurring prior to and during peat extraction, changes in peat bulk density and the specific vegetation succession occurring during the restoration process. As in the previous version of HPM, vegetation dynamics and interactions between vegetation and ecohydrology were included in the simulations. Simulation results offered an estimate of the amount of carbon accumulated in the peatland prior to exploitation as well as the carbon loss during exploitation. Estimates of current and future net carbon accumulation/loss, associated with different management scenarios, such as state-of-the-art restoration, drainage blocking or abandonment, gave an insight into the benefits of restoration and moreover into the millennial scale impact of peat extraction.

  14. Towards a conceptual model of hydrological change on an abandoned cutover bog, Quebec

    NASA Astrophysics Data System (ADS)

    van Seters, Tim E.; Price, Jonathan S.

    2002-07-01

    Cutover bogs do not return to functional peatland ecosystems after abandonment because re-establishment of peat-forming mosses is poor. This paper presents a conceptual model of bog disturbance caused by peat harvesting (1942-1972), and the hydrological evolution that occurred after abandonment (1973-1998). Two adjacent bogs of similar size and origin, one harvested and the other essentially undisturbed, provide the basis for understanding what changes occurred. The model is based on historical trends evident from previous surveys of land-use, bog ecology and resource mapping; and from recent hydrological and ecological data that characterize the current condition. Water balance data and historical information suggest that runoff increased and evapotranspiration decreased following drainage, but tended towards pre-disturbance levels following abandonment, as vegetation recolonized the surface and drainage became less efficient over time. Dewatering of soil pores after drainage caused shrinkage and oxidation of the peat and surface subsidence of approximately 80 cm over 57 years. Comparisons with a nearby natural bog suggest that bulk density in the upper 50 cm of cutover peat increased from 0·07 to 0·13 g cm-3, specific yield declined from 0·14 to 0·07, water table fluctuations were 67% greater, and mean saturated hydraulic conductivity declined from 4·1 × 10-5 to 1·3 × 10-5 cm s-1. More than 25 years after abandonment, Sphagnum mosses were distributed over broad areas but covered less than 15% of the surface. Areas with good Sphagnum regeneration (>10% cover) were strongly correlated with high water tables (mean -22 cm), especially in zones of seasonal groundwater discharge, artefacts of the extraction history. Forest cover expanded from 5 to 20% of the study area following abandonment. The effect of forest growth (transpiration and interception) and drainage on lowering water levels eventually will be countered by slower water movement through the

  15. Greenhouse gas emissions from rewetted bog peat extraction sites and a Sphagnum cultivation site in Northwest Germany

    NASA Astrophysics Data System (ADS)

    Beyer, C.; Höper, H.

    2014-03-01

    . The yearly GWP100 balances ranged from -280.5 ± 465.2 to 644.5 ± 413.6 g CO2-eq. m-2 a-1 at the rewetted sites. In contrast, the Sphagnum farming site had a cooling impact on the climate in both years (-356.8 ± 176.5 and -234.9 ± 145.9 g CO2-C m-2 a-1). If the exported carbon through the harvest of the Sphagnum biomass and the additional CO2 emission from the decay of the organic material is considered, the NECB and GWP100 balances are near neutral. Peat mining sites are likely to become net carbon sinks and a peat accumulating ("growing") peatland within 30 years after rewetting, but the GWP100 balance may still be positive. A recommended measure for rewetting is to achieve a water level of a few centimetres below ground surface. Sphagnum farming is a climate friendly alternative to conventional commercial use of bogs. A year round constant water level of a few centimetres below ground level should be maintained.

  16. Inorganic contents of peats

    SciTech Connect

    Raymond, R. Jr.; Bish, D.L.; Cohen, A.D.

    1988-02-01

    Peat, the precursor of coal, is composed primarily of plant components and secondarily of inorganic matter derived from a variety of sources. The elemental, mineralogic, and petrographic composition of a peat is controlled by a combination of both its botanical and depositional environment. Inorganic contents of peats can vary greatly between geographically separated peat bogs as well as vertially and horizontally within an individual bog. Predicting the form and distribution of inorganic matter in a coal deposit requires understanding the distribution and preservation of inorganic matter in peat-forming environments and diagenetic alterations affecting such material during late-stage peatification and coalification processes. 43 refs., 4 figs., 3 tabs.

  17. The Cultivation of Arabidopsis for Experimental Research Using Commercially Available Peat-Based and Peat-Free Growing Media.

    PubMed

    Drake, Tiffany; Keating, Mia; Summers, Rebecca; Yochikawa, Aline; Pitman, Tom; Dodd, Antony N

    2016-01-01

    Experimental research involving Arabidopsis thaliana often involves the quantification of phenotypic traits during cultivation on compost or other growing media. Many commercially-available growing media contain peat, but peat extraction is not sustainable due to its very slow rate of formation. Moreover, peat extraction reduces peatland biodiversity and releases stored carbon and methane into the atmosphere. Here, we compared the experimental performance of Arabidopsis on peat-based and several types of commercially-available peat-free growing media (variously formed from coir, composted bark, wood-fibre, and domestic compost), to provide guidance for reducing peat use in plant sciences research with Arabidopsis. Arabidopsis biomass accumulation and seed yield were reduced by cultivation on several types of peat-free growing media. Arabidopsis performed extremely poorly on coir alone, presumably because this medium was completely nitrate-free. Some peat-free growing media were more susceptible to fungal contamination. We found that autoclaving of control (peat-based) growing media had no effect upon any physiological parameters that we examined, compared with non-autoclaved control growing media, under our experimental conditions. Overall, we conclude that Arabidopsis performs best when cultivated on peat-based growing media because seed yield was almost always reduced when peat-free media were used. This may be because standard laboratory protocols and growth conditions for Arabidopsis are optimized for peat-based media. However, during the vegetative growth phase several phenotypic traits were comparable between plants cultivated on peat-based and some peat-free media, suggesting that under certain circumstances peat-free media can be suitable for phenotypic analysis of Arabidopsis.

  18. The Cultivation of Arabidopsis for Experimental Research Using Commercially Available Peat-Based and Peat-Free Growing Media

    PubMed Central

    Drake, Tiffany; Keating, Mia; Summers, Rebecca; Yochikawa, Aline; Pitman, Tom

    2016-01-01

    Experimental research involving Arabidopsis thaliana often involves the quantification of phenotypic traits during cultivation on compost or other growing media. Many commercially-available growing media contain peat, but peat extraction is not sustainable due to its very slow rate of formation. Moreover, peat extraction reduces peatland biodiversity and releases stored carbon and methane into the atmosphere. Here, we compared the experimental performance of Arabidopsis on peat-based and several types of commercially-available peat-free growing media (variously formed from coir, composted bark, wood-fibre, and domestic compost), to provide guidance for reducing peat use in plant sciences research with Arabidopsis. Arabidopsis biomass accumulation and seed yield were reduced by cultivation on several types of peat-free growing media. Arabidopsis performed extremely poorly on coir alone, presumably because this medium was completely nitrate-free. Some peat-free growing media were more susceptible to fungal contamination. We found that autoclaving of control (peat-based) growing media had no effect upon any physiological parameters that we examined, compared with non-autoclaved control growing media, under our experimental conditions. Overall, we conclude that Arabidopsis performs best when cultivated on peat-based growing media because seed yield was almost always reduced when peat-free media were used. This may be because standard laboratory protocols and growth conditions for Arabidopsis are optimized for peat-based media. However, during the vegetative growth phase several phenotypic traits were comparable between plants cultivated on peat-based and some peat-free media, suggesting that under certain circumstances peat-free media can be suitable for phenotypic analysis of Arabidopsis. PMID:27088495

  19. DOC export from a peat extraction site in transition to managed restoration - preliminary results of a long-term research project

    NASA Astrophysics Data System (ADS)

    Rüggen, Norman; Kutzbach, Lars; Kopelke, Susanne; Pfeiffer, Eva-Maria

    2013-04-01

    Peatlands play a major role in the global cycles of water and carbon. Budgeting carbon fluxes of temperate man-managed peatlands is limited by few available data. The main carbon compounds exported from such sites are CO2, CH4 and laterally exported C compounds (dissolved organic carbon (DOC) and gases). Without reliable estimates of laterally exported carbon from managed peatlands, overall carbon balances of such geoecosystems remain obscure. The Himmelmoor peatland in Schleswig-Holstein is subject to horticultural peat extraction in transition towards managed restoration. One-third of 130 ha of peatland area are already subject to managed restoration, the remaining part is still intensively used as a peat extraction site. Surface water discharge rates are measured by a water head sensor in combination with a rectangular-shaped weir. An October-November data set (54 days period, 2012) shows a distinct base-flow and precipitation-dependent discharge peaks, which were up to five times higher than the base-flow. The observations indicate a poor water storing capacity of the intensively used areas. During this first observation period, almost 65,000 tons of peatland-DOC-bearing water have been discharged into the adjacent river system. DOC concentrations in the discharge water have been measured every 6-12 days with a Total Carbon Analyzer TOC-L (Shimadzu, Japan). Additionally, a field spectrophotometer (spectro::lyser,s-can, Austria) has been employed, for measuring quasi-continuous concentrations of DOC. During the 54 day period, approximately 1.75 g DOC m-2 (or about 1750 kg DOC km-2) has been laterally exported from the peatland. Average DOC concentration was 35.1 ± 4 g l-1. These values range in the same order of magnitude that have been published from managed UK peatlands (Armstrong et al., 2010; Wilson et al., 2011). Preliminary data evaluation of the in-situ field spectrophotometer show that DOC concentrations of discharge water varied up to 1.5 mg L-1 in

  20. Inhibitory effect of fulvic acid extracted from Canadian sphagnum peat on chemical mediator release by RBL-2H3 and KU812 cells.

    PubMed

    Yamada, Parida; Isoda, Hiroko; Han, Jun Kyu; Talorete, Terence P N; Abe, Yukuo

    2007-05-01

    Fulvic acid (FA) was extracted and purified from Canadian Sphagnum peat (CP-FA) and characterized by using an element analysis meter, Fourier transform infrared (FT-IR) spectroscopy, electron spin resonance (ESR) spectroscopy, and (13)C-nuclear magnetic resonance ((13)C-NMR) spectroscopy. To investigate the antiallergic effect of CP-FA, we incubated rat basophilic leukemia (RBL-2H3) cells with 0.001-10.0 microg/ml of CP-FA and determined the beta-hexosaminidase release inhibition at different response stages. The intracellular calcium [Ca(2+)](i) level was also determined by using Fluo 3-AM, a calcium-specific fluorescent probe, and the cytotoxicity of CP-FA was determined by the 3-(4,5-dimethythiazol-2-yl)-2,5-diphenyl-tetrazolium bromide (MTT) assay. The results revealed that RBL-2H3 cells incubated for 48 h with 0.001-10.0 microg/ml of CP-FA did not show any decreased viability. CP-FA inhibited the beta-hexosaminidase release by IgE-sensitized, antigen-stimulated RBL-2H3 cells at the antigen-antibody binding stage and the antibody-receptor binding stage. CP-FA also inhibited histamine release from A23187 plus PMA- or compound 48/80-stimulated KU812 cells. Furthermore, there was a decrease in the intracellular [Ca(2+)](i) level in IgE-sensitized cells incubated with CP-FA and stimulated with antigen. Our results show that CP-FA may be useful for the treatment or prevention of allergic diseases.

  1. Chlorinated hydrocarbons in peat

    SciTech Connect

    Rapaport, R.A.

    1985-01-01

    Concentrations (ng/g), accumulation rates (ug/m/sup 2/=yr) and burdens were determined for DDT (1,1,1-trichlorophenyl2-2'bis(p-chlorophenyl)ethane), polychlorinated biphenyls. Toxaphene, hexachlorobenzene (HCB) and a,b,g-hexachlorocyclohexanes (HCHs) in peat cores taken across the mid-latitudes of North America. Because peat bogs are ombrotrophic, thereby receiving all contaminant inputs from the atmosphere and because peat cores were dated, atmospheric input functions were constructed for all of the compounds listed above excepting the HCHs. Compound inventories (burdens) in peat cores of PCBs, HCB, HCHs, Toxaphene, DDT, Pb and Zn were compared, indicating a strong influence from areas proximate to industrial sources and the atmospheric transport from source regions. Untransformed parent DDT (p,p' and o,p'-DDT) in surface peat and in precipitation provides evidence for the long range transport of DDT from neighboring countries where use has increased over the past 10-15 years. Present accumulation rates of DDT in peat are about 10-20% of maximum levels associated with peak use in the US around 1960. The DDT input function that was developed can be used to date peat cores. Transformations of DDT and PCBs were also examined in peat cores. First order transformation rates of DDT (p,p' and o,p') to DDD in anaerobic peat core environments ranged from 0.03 to 0.09 yr/sup -1/ with differences related to temperature. Aerobic transformation of PCB congeners in peat cores and microcosms was rapid for 2,3 and several 4 chlorinated congeners (T/sub 1/2 less than or equal to 0.2 to 3 years) and declined with increasing chlorine number.

  2. Third technical contractors' conference on peat

    SciTech Connect

    Not Available

    1981-01-01

    The conference dealt with the estimation of US peat reserves, methods for the gasification of peat, including biogasification, techniques for dewatering peat, and the harvesting of peat. Separate abstracts were prepared for the individual papers. (CKK)

  3. Fourth technical contractors' conference on peat

    SciTech Connect

    Not Available

    1981-01-01

    This conference reported the status of the US Department of Energy Peat Program. The papers presented dealt with peat dewatering, international peat programs, environmental and socio-economic factors, peat gasification, peat harvesting, and the state peat surveys for 14 states. Separate abstracts were prepared for the individual papers. (CKK)

  4. The Impact of Tropical Peat Fire on Termite Assemblage in Sumatra, Indonesia: Reduced Complexity of Community Structure and Survival Strategies.

    PubMed

    Neoh, Kok-Boon; Bong, Lee-Jin; Muhammad, Ahmad; Itoh, Masayuki; Kozan, Osamu; Takematsu, Yoko; Yoshimura, Tsuyoshi

    2016-10-01

    Tropical peat swamp forests in Southeast Asia account for approximately 72% of global peatland. However, extensive forest exploitation following peat drainage for agricultural expansion has been leading to catastrophic peat fires. In this study, we compared the termite assemblage in burnt and unburnt peats in Sumatra, Indonesia. We also identified which taxonomic group is particularly resistant to fire disturbance and the traits that correlate with its persistence in fire-impacted peatlands. Overall, the termite species richness in fire-impacted peats was up to 40% lower than that of the total species found in peat swamp forests. Although the estimated species richness values in fire-impacted peats and peat swamp forests were not significantly different, fire changed termite community structure significantly. Only termites of the family Rhinotermitidae survived in the fire event, whereas members of the Termitidae that were reportedly resilient to fire and open habitats elsewhere disappeared during the fire events. The rhinotermitids found in the burnt sites were exclusively wood nesters. This suggests that the desiccation tolerance of termites in open habitat is not the simple underlying survival strategy, but tree branches and barks might have provided a refuge from heat during fire. The result also suggests that the high similarity in species composition in recently burnt peats and long burnt peats implies low species turnover. Thus, regardless of how much time had passed since the fire-impacted peats were abandoned or cultivated, the increase in habitat complexity did not favor colonization by the forest-dependent group.

  5. The peats of Costa Rica

    SciTech Connect

    Thayer, G.R.

    1991-01-01

    Peat has been identified in Cost Rica, and an economic analysis of energy applications for peat has been done. About 1000 km{sup 2} of Cost Rica has the potential of being covered by peat. The Talamanca Mountains and the northeastern plains contain most of the Costa Rican peat. Specific bogs have been identified by the Medio Queso River in north-central Costa Rica and near El Cairo, Moin, and the Limon airport in northeastern Costa Rica. The Medio Queso bog, which is supplying peat for use as a carrier for nitrogen-fixing bacteria, and the El Cairo bog, which has been identified as a source of horticultural peat for nearby ornamental plant farms, are of special interest. The economics of three energy applications of peat were examined -- as a fuel in large boilers, as a fuel in small boilers, and as an oil substitute in a cement plant. A facility using coal would have the same total costs as one using peat if coal prices were $45 and $30 per metric ton (used for large boilers and a cement plant, respectively). A facility using Bunker C or diesel would have the same total cost as one using peat if oil prices were $0.11, $0.08, and $0.06 per liter (used for large boilers, small boilers, and a cement plant, respectively). In all three cases, the costs for peat were comparable or less than the costs for coal and oil at 1987 prices. 6 refs., 8 figs.

  6. Sensitivity of blanket peat vegetation and hydrochemistry to local disturbances.

    PubMed

    Robroek, Bjorn J M; Smart, Richard P; Holden, Joseph

    2010-10-01

    At the ecosystem scale, peatlands can be extremely resilient to perturbations. Yet, they are very sensitive to local disturbances, especially mechanical perturbations (e.g. trampling). The effects of these disturbances on vegetation, and potential effects on hydrochemical conditions along the peat surface, however, are largely unknown. We used three research tracks (paths researchers use to access their study sites) differing in time of abandonment to investigate the impact of local disturbance (trampling) on the vegetation and its short-term (< or = 2 year) recovery in a flagship research blanket peatland. Additionally, we examined the effects of local disturbance on fluvial runoff events and the concentrations of dissolved organic carbon (DOC) and particulate organic carbon (POC) in runoff water. Local disturbance heavily impacted peat vegetation, resulting in large areas of scarred and churned peat. Recovery of vascular plants along abandoned tracks was slow, but a functional Sphagnum layer re-established after just one year. The absence of vegetation elicited an increase in the number of runoff events along the tracks, by which POC runoff from the tracks increased. POC concentrations were highest in the surface water from the recently abandoned track, while they were low in the runoff water from the track abandoned longest and the undisturbed control track. We attribute this to the relatively fast recovery of the Sphagnum vegetation. DOC concentrations did not differ significantly either spatially or temporally in surface runoff or soil solution waters. While at an ecosystem scale local disturbances may be negligible in terms of carbon loss, our data points to the need for further research on the potential long-term effects of local disturbance on the vegetation, and significant effects on local scale carbon fluxes. Moreover, the effects of disturbances could be long-lasting and their role on ecosystem processes should not be underestimated.

  7. The peats of Costa Rica

    SciTech Connect

    Obando A, L.; Malavassi R, L.; Ramirez E, O. ); Cohen, A. . Dept. of Geological Sciences); Raymond, R. Jr.; Thayer, G.R. )

    1991-04-01

    The objectives of this investigation were: (1) to locate potential peat deposits in Costa Rica; (2) to estimate as closely as possible by representative sampling the amount of peat present in each deposit, and (3) to make a preliminary evaluation of the quality of the peat in each deposit. With information from soil maps and a 3-week survey of Costa Rica, it is estimated that a potential area of about 1000 km{sup 2} is covered by peat. Most of the peat area (about 830 km{sup 2}) is in northeastern Costa Rica in the Tortuguero area. An aerial survey identified the potential peat areas by the exclusive presence of the Yolillo palm. The next largest potential area of peat (about 175 km{sup 2}) is in the cloud-covered areas of the Talamanca Mountains. Some reconnaissance has been done in the Talamanca Mountains, and samples of the peat indicate that it is very similar to the sphagnum peat moss found in Canada and the northern US. Smaller bogs have been discovered at Medio Queso, El Cairo, Moin, and the Limon airport. Two bogs of immediate interest are Medio Queso and El Cairo. The Medio Queso bog has been extensively sampled and contains about 182,000 metric tons (dry) of highly decomposed peat, which is being used as a carrier for nitrogen-fixing bacteria. The El Cairo bog is sparsely sampled and contains about 1,300,000 metric tons of slightly decomposed dry peat. Plans are to use this peat in horticultural applications on nearby farms. 10 refs., 11 figs., 7 tabs.

  8. Abandoned Texas oil fields

    SciTech Connect

    Not Available

    1980-12-01

    Data for Texas abandoned oil fields were primarily derived from two sources: (1) Texas Railroad Commission (TRRC), and (2) Dwight's ENERGYDATA. For purposes of this report, abandoned oil fields are defined as those fields that had no production during 1977. The TRRC OILMASTER computer tapes were used to identify these abandoned oil fields. The tapes also provided data on formation depth, gravity of oil production, location (both district and county), discovery date, and the cumulative production of the field since its discovery. In all, the computer tapes identified 9211 abandoned fields, most of which had less than 250,000 barrel cumulative production. This report focuses on the 676 abandoned onshore Texas oil fields that had cumulative production of over 250,000 barrels. The Dwight's ENERGYDATA computer tapes provided production histories for approximately two-thirds of the larger fields abandoned in 1966 and thereafter. Fields which ceased production prior to 1966 will show no production history nor abandonment date in this report. The Department of Energy hopes the general availability of these data will catalyze the private sector recovery of this unproduced resource.

  9. Drained peatlands used for extraction and agriculture: biogeochemical status with special attention to greenhouse gas fluxes and rewetting

    NASA Astrophysics Data System (ADS)

    Sirin, Andrey; Chistotin, Maxim; Suvorov, Gennady; Glagolev, Mikhail; Kravchenko, Irina; Minaeva, Tatiana

    2010-05-01

    Many peatlands previously drained for peat extraction or utilized for agriculture (directly or after partial cutoff) are left abandoned during last decades in Europe, and especially in its eastern part. In the European part of Russia alone, several million hectares of peatlands have been modified for peat extraction and agriculture by direct water level draw-down and nowadays are not under use by economic reasons. This makes up one of the most serious and urgent problems of wise use and management of peatlands in these regions with serious feedback to people, environment and economy (Quick Scan of Peatlands in Central and Eastern Europe, 2009). Drainage for agriculture leads to peat oxidation resulting in substantial emissions of greenhouse gases (carbon dioxide and sometimes nitrous oxide) to the atmosphere. Together with peat fires this is the most significant negative input of peatland degradation to climate change (Assessment on Peatlands Biodiversity and Climate Change, 2008; Peatlands and Climate Change, 2008). Besides that, dehydrated peatlands often release methane. Starting from 2003, the effect of drainage and subsequent utilization of peatlands on the emissions of carbon dioxide and methane was studied in Tomsk region (West Siberia) during the summer-fall periods (Glagolev et al. 2008). The measurements were conducted by chamber method at peatlands drained for use as croplands (now partly being fallows) and peat cutting (currently abandoned or reclaimed for forest planting, haying, or pasturing), as well as at a wide range of undrained oligotrophic, mesotrophic, and eutrophic mires and burnt mire areas of different regeneration stages. The statistical analysis of data from a large number of study sites indicated a higher release of carbon dioxide from disturbed peatlands compared to undrained ones. At the same time some drained peatlands had considerable methane emission rates, additionally enhanced by the intensive efflux from the surface of drainage

  10. Low-rank coal study: national needs for resource development. Volume 6. Peat

    SciTech Connect

    Not Available

    1980-11-01

    The requirements and potential for development of US peat resources for energy use are reviewed. Factors analyzed include the occurrence and properties of major peat deposits; technologies for extraction, dewatering, preparation, combustion, and conversion of peat to solid, liquid, or gaseous fuels; environmental, regulatory, and market constraints; and research, development, and demonstration (RD and D) needs. Based on a review of existing research efforts, recommendations are made for a comprehensive national RD and D program to enhance the use of peat as an energy source.

  11. Abandoning wells working group

    SciTech Connect

    1997-03-01

    The primary objective of this working group is to identify major technical, regulatory, and environmental issues that are relevant to the abandonment of offshore wellbores. Once the issues have been identified, the working group also has the objective of making recommendations or providing potential solutions for consideration. Areas for process improvement will be identified and {open_quotes}best practices{close_quotes} will be discussed and compared to {open_quotes}minimum standards.{close_quotes} The working group will primarily focus on wellbore abandonment in the Gulf of Mexico. However, workshop participants are encouraged to discuss international issues which may be relevant to wellbore abandonment practices in the Gulf of Mexico. The Abandoning Wells Group has identified several major areas for discussion that have concerns related to both operators and service companies performing wellbore abandonments in the Gulf of Mexico. The following broad topics were selected for the agenda: (1) MMS minimum requirements and state regulations. (2) Co-existence of best practices, new technology, and P & A economics. (3) Liability and environmental issues relating to wellbore abandonment.

  12. 46 CFR 148.290 - Peat moss.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 46 Shipping 5 2012-10-01 2012-10-01 false Peat moss. 148.290 Section 148.290 Shipping COAST GUARD... SPECIAL HANDLING Special Requirements for Certain Materials § 148.290 Peat moss. (a) Before shipment, peat... handling or coming into contact with peat moss must wear gloves, a dust mask, and goggles....

  13. 46 CFR 148.290 - Peat moss.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 46 Shipping 5 2013-10-01 2013-10-01 false Peat moss. 148.290 Section 148.290 Shipping COAST GUARD... SPECIAL HANDLING Special Requirements for Certain Materials § 148.290 Peat moss. (a) Before shipment, peat... handling or coming into contact with peat moss must wear gloves, a dust mask, and goggles....

  14. 46 CFR 148.290 - Peat moss.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 46 Shipping 5 2014-10-01 2014-10-01 false Peat moss. 148.290 Section 148.290 Shipping COAST GUARD... SPECIAL HANDLING Special Requirements for Certain Materials § 148.290 Peat moss. (a) Before shipment, peat... handling or coming into contact with peat moss must wear gloves, a dust mask, and goggles....

  15. 46 CFR 148.290 - Peat moss.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 46 Shipping 5 2011-10-01 2011-10-01 false Peat moss. 148.290 Section 148.290 Shipping COAST GUARD... SPECIAL HANDLING Special Requirements for Certain Materials § 148.290 Peat moss. (a) Before shipment, peat... handling or coming into contact with peat moss must wear gloves, a dust mask, and goggles....

  16. Second technical contractors' conference on peat

    SciTech Connect

    Not Available

    1980-01-01

    This conference reported the status of the US Department of Energy Peat Program. The program includes peat resource surveys of eleven states, peat gasification process and equipment studies, dewatering studies, and environmental and socioeconomic factors in the development of peat technology. Separate abstracts were prepared for selected papers. (CKK)

  17. Peat as an energy alternative

    SciTech Connect

    Punwani, D.V.

    1980-07-01

    The importance of developing alternative energy sources to augment supplies of fossil fuels is growing all over the world. Coal, oil shale, tar sands, biomass, solar, geothermal, nuclear, and hydroelectric power have received considerable attention as alternative energy sources. One large energy resource, however, has received little attention until recently. That resource is peat. Although peat is used as an energy source in some countries such as Russia, Ireland, and Finland, it is virtually unexploited in many countries including the United States. This paper provides an understanding of peat: its varieties, abundance, and distribution; its value as an energy alternative; its current and future role as an energy alternative; and the environmental and socioeconomic impacts of large-scale peat utilization.

  18. Dewatering Peat With Activated Carbon

    NASA Technical Reports Server (NTRS)

    Rohatgi, N. K.

    1984-01-01

    Proposed process produces enough gas and carbon to sustain itself. In proposed process peat slurry is dewatered to approximately 40 percent moisture content by mixing slurry with activated carbon and filtering with solid/liquid separation techniques.

  19. Abandoning the mentally ill.

    PubMed

    Barton, R

    1975-12-01

    Mentally ill people have been avoided and abandoned by their families and public authorities for hundreds of years. Present day abandonment includes the deployment of professionals from patients to paper; the destruction of availability and effectiveness of institutional facilities; the obfuscation of mental illness by captious, sematic criticism; the aspirations of paramedical and paraprofessional groups; and the subordination of the primary purpose of institutions and physicians to other objectives. The nature of authority is discussed and the need for the treatment of mentally ill people to be based on the art and science of medicine, rather than the pretension and advocacy of the gullible, unqualified or unscrupulous, is noted.

  20. Peat fires and air quality: volatile organic compounds and particulates.

    PubMed

    Blake, D; Hinwood, A L; Horwitz, P

    2009-07-01

    There are numerous localized peat deposits on the Swan Coastal Plain, an urban and rural bioregion otherwise dominated by wetland ecosystems in southwestern Australia. Hydrological change is significant in the bioregion: urban development encroaches on wetlands, groundwater extraction provides the city population with most of its water, and rainfall declines will not recharge aquifers in the future. The wetland processes which contribute to the formation of these peat deposits have therefore changed and are becoming vulnerable to fire events with residents increasingly exposed to peat smoke. There is an imperative to characterise this peat smoke to determine if exposures are harmful or toxic, and opportunities to do so in this setting arise due to the absence of bushfire smoke which has confounded other international studies. We have measured volatile organic compounds (VOCs) and particulate concentrations from an opportunistic assessment of two peat fires. SUMMA canister grab samples and a portable GCMS were used to determine the VOCs with high 1h benzene concentrations of 16 and 30 ppm v/v. PM10 and PM2.5 particulate data were collected using an Osiris continuous analyser with 24h concentrations recorded at varying time periods (within a 5 months timeframe) ranging from 1h maximums of between 23-37 microgm(-3) for PM10 and 50.5-106 microgm(-3) for PM2.5. While the 24h averages were generally below national air quality standards, elevated 1h concentrations were observed on numerous occasions and on most days. Given the proximity of residential development to many peat deposits, a drying climate and the increased risk of arson in peri-urban environments, the health impacts of exposure to peat smoke need to be determined and if necessary measures developed to prevent exposure (which would include maintaining wetland sediment integrity so as to reduce its vulnerability to fire).

  1. Alkylation of lignites and peat in low-temperature plasma

    SciTech Connect

    L.I. Shchukin; S.I. Zherebtsov; M.V. Kornievich; O.A. Skutina

    2007-02-15

    The alkylation of lignites and peat was carried out at 50-270{sup o}C in different plasmas. The degree of conversion determined as the yield of the alcohol-benzene extract increases on passing from methane to alcohol plasma. The dependence of the extract yield on the plasma temperature, treatment time, and sample grinding degree was studied. 5 refs., 4 figs., 2 tabs.

  2. Preliminary evaluation of environmental issues on the use of peat as an energy source

    SciTech Connect

    King, R.; Richardson, S.; Walters, A.; Boesch, L.; Thomson, W.; Irons, J.

    1980-03-14

    A study to characterize the environmental issues, that would arise from an extensive peat utilization program has been initiated. The objectives of this preliminary report are to: identify the environmental issues and potential problems; examine the significance of issues in the geographical regions where peat use could be developed; and establish a methodology by which issues can be resolved or clarified through future coordinated private, state, and federal programs. An overview of peat development including discussions on conversion technologies, extraction and harvesting procedures, and land reclamation is presented. Environmental concerns are in the areas of water resources and quality, air quality, health and safety issues, solid waste management, and land reclamation. The general environmental issues, resource availability, and attitudes associated with potential peat development in ten states, containing an estimated 90 percent of US peat resources were described. The ten states reviewed are Alaska, Minnesota, Michigan, Maine, North and South Carolina, Wisconsin, New York, Florida, and Louisiana. (DMC)

  3. Inventory of peat resources, Koochiching County, Minnesota

    SciTech Connect

    Severson, L.S.; Mooers, H.D.; Malterer, T.J.

    1980-01-01

    The subject of this report is the reconnaissance-level peatland survey of Koochiching County, Minnesota. Discussed are: geological setting; peat formation; and peat properties and classification. Included are maps and a list of selected DOE sampling sites. Distribution, tonnages, and energy value analysis of peat are described. (DMC)

  4. [The release of biologically active compounds from peat peloids].

    PubMed

    Babaskin, D V

    2011-01-01

    This work had the objective to study kinetics of the release of flavonoides from peat peloid compositions containing extracts of medicinal herbs in model systems.The key parameters of the process are defined. The rate of liberation of flavonoides is shown to depend on their initial concentration in the compositions being used. The influence of the flavonoide composition of the tested extracts and dimethylsulfoxide on the release of biologically active compounds contained in the starting material in the model environment is estimated. The possibility of the layer-by-layer deposition of the compositions and peat peloids in order to increase the efficacy of flavonoide release from the starting composition and to ensure more rational utilization of the extracts of medicinal plants is demonstrated.

  5. Stable Isotope Probing of Peat and Forest Floor Amendments

    NASA Astrophysics Data System (ADS)

    Quideau, Sylvie; Béasse, Mark

    2013-04-01

    In Alberta, Canada, land reclamation efforts utilize peat as an organic amendment to help reclaim decommissioned oil sands mine sites to upland boreal forests. This study investigates the rhizosphere microbial communities of two pioneer species, aspen (Populus tremuloides Michx.), a species not known for strong associations with the soil microbial community, and alder (Alnus crispa Ait.), a species well known for mutualism with actinomycetes. Specifically, the objective was to determine how different organic amendments (peat versus forest floor) influenced the rhizosphere microbial communities and how this could be linked to plant growth. Seedlings were grown for 20 weeks in forest floor material, peat, and a combination of both. They were pulse labelled with 13CO2 (g) and subsequently harvested for plant growth measurements. While analysis of plant growth attributes did not indicate any effect of the organic amendment on aspen growth, alder reported significantly less growth in peat treatments. The rhizosphere soils were extracted for compound-specific analysis of δ13C in microbial phospholipid fatty acids. Stable isotope probing showed greater carbon flow between trees and their rhizosphere communities when seedlings were grown in forest floor material.

  6. Utilization of peat as a fuel

    SciTech Connect

    Clemens, D.F.; Evans, G.O. II; Whitehurst, B.M.

    1981-10-01

    This work has dealt primarily with the development and evaluation of peat/No. 2 fuel oil mixtures (POM) and peat/methanol mixtures (PAM). POM and PAM slurries with varied peat loadings, peat moisture contents, and peat particle sizes have been studied by measuring slurry sedimentation ratios in jacketed glass tubes and slurry drain times from the tubes along with the slurry viscosities. The peat moisture content was found to be especially critical in forming stable slurries. Also, in both the PAM and POM systems, it was found that use of the more finely ground peat led to significantly higher sedimentation ratios than the use of coarse peat. Numerous additives selected to improve slurry suspension and flow characteristics have been evaluated. Cab-O-Sil M-5 and Cab-O-Sil PTG were most effective in the POM systems while Attagel X-2059 and Bentone 27 were most effective in the PAM systems. Viscosities have been measured for slurries of varied particle size and modified by selected additives. Viscosities in the PAM system were lower using the coarser peat with higher moisture content while viscosities in the POM system seemed to be lower using the finer, drier peat. Calorimetric studies of powdered peat as well as PAM and POM slurries, with and without additives, were completed. Combustion tests of POM and PAM slurries were carried out using a salamander type shop heater. Successful burns of the POM slurry were accomplished when the slurries were heated to reduce viscosities and the peat was prescreened to remove large wood fibers to avoid plugging of the small burner nozzle. Since the toxicity and low flash point of methanol precluded heating of the PAM slurries, plugging of the small burner routinely occurred. It was also demonstrated that ground peat could be burned by using an eductor connector to a compressed air line.

  7. Liquefaction Potential of Adiyaman Peat

    NASA Astrophysics Data System (ADS)

    Karaca, Huseyin; Depci, Tolga; Karta, Mesut; Coskun, M. Ali

    2016-10-01

    In the present study, liquefaction potential of Adiyaman peat was studied by direct liquefaction technique to obtain oil as a fuel purposes due to its high carbon and hydrogen content and low sulphur ratio. The peat and liquefaction products, named char, asphaltene, preasphaltene and oil, were characterized by XRD, FTIR, SEM, DTA/TG and elemental analysis. The compositions of the obtained oil were also identified by GC/MS. The results indicated that the obtained oil was paraffinic-low waxy oil with 21.73 MJ/kg of calorific value and 0.93 g/cm3 density and it was composed of naphthalene and phenolic groups. The oil conversion ratio was found to be 29 %.

  8. The Abandonment of Social Studies?

    ERIC Educational Resources Information Center

    Griffith, Bryant

    1991-01-01

    Addresses the question of whether the social studies should be abandoned. Discusses Kieran Egan's analysis of the importance of storytelling and Egan's proposal to abandon the social studies curriculum in favor of a pedagogy more consistent with the way children think. Critiques Egan's view and examines implications for educators. (SG)

  9. PwC's 3-Peat

    ERIC Educational Resources Information Center

    Freifeld, Lorri

    2010-01-01

    PricewaterhouseCoopers (PwC) is giving the Chicago Bulls a run for their money when it comes to three-peats. The professional services firm scored the top spot on the Training Top 125 for a record third year in a row. So, just how did PwC nail No. 1 again? For starters, it met and exceeded a hefty challenge in fiscal year 2009: cutting training…

  10. Impact of subjacent rocks at the water and air regime of the depleted peat deposits

    NASA Astrophysics Data System (ADS)

    Rakovich, V. A.

    2009-04-01

    At the depleted peat deposits (after peat extraction), where the residual layer of peat with the thickness of about 0,5 meters is laid at the well water permeable rocks, vegetation typical for dry conditions is developed in case of good drainage conditions; birch trees, willow, alder-trees and buckthorn prevail in this vegetation. Water and air regime is characterized here by good aeration with prevailing of oxidative processes. If water regime is regulated, these depleted peat areas are suitable for agricultural and forest lands; however, necessity of transformation of these depleted lands into forest and agricultural lands must be ecologically and economically justified. If the residual layer of peat with the thickness of 0,05-0,3 m is based at the sapropel or peat sapropel, contrast amphibiotic water and air regime with strong fluctuation of oxidative and restoration process depending on the weather conditions is formed; this regime is formed without artificial increase of the ground waters level. This does not allow bog vegetation or vegetation typical for dry conditions to develop. Thus, within 20 and more years after completion of peat extraction, such areas are not covered by vegetation in spite of favorable agro-chemical qualities of peat layer and favorable for vegetation chemical composition of soil and ground waters. Depleted peat deposits, that are based at the sapropel, are not suitable for agricultural use, because agricultural vegetation requires stable water and air regime with good aeration and oxidative and restoration potential within 400-750 mV. Contrast amphibiotic water and air regime of the depleted peat deposits that are based at sapropel excludes possibility to use them as agricultural lands. Because of this reason, areas with residual peat layer that are based at sapropel are not suitable for forest planting. Due to periodic increase of ground waters level, rot systems of the plants can not penetrate into the required depth, and mechanical

  11. Pressate from peat dewatering as a substrate for bacterial growth. [Rhizopus arrhizus; Xanthomonas campestris; Aureobasidium

    SciTech Connect

    Mulligan, C.N.; Cooper, D.G.

    1985-07-01

    This study considered the possibility of using water expressed during the drying of fuel-grade peat as a substrate for microbial growth. Highly humified peat pressed for 2.5 min at 1.96 MPa produced water with a chemical oxygen demand of 690 mg/liter. Several biological compounds could be produced by using the organic matter inexpressed peat water as a substrate. These included polymers such as chitosan, contained in the cell wall of Rhizopus arrhizus, and two extracellular polysaccharides, xanthan gum and pullulan, produced by Bacillus subtilis grown in the expressed water. Small additions of nutrients to the peat pressate were necessary to obtain substantial yields of products. The addition of peptone, yeast extract, and glucose improved production of the various compounds. Biological treatment improved the quality of the expressed water to the extent that in an industrial process it could be returned to the environment.

  12. Environmental aspects of alternative wet technologies for producing energy/fuel from peat. Final report

    SciTech Connect

    Smith, R.T.

    1981-05-01

    Peat in situ contains up to 90% moisture, with about 50% of this moisture trapped as a colloidal gel. This colloidal moisture cannot be removed by conventional dewatering methods (filter presses, etc.) and must be removed by thermal drying, solvent extraction, or solar drying before the peat can be utilized as a fuel feedstock for direct combustion or gasification. To circumvent the drying problem, alternative technologies such as wet oxidation, wet carbonization, and biogasification are possible for producing energy or enhanced fuel from peat. This report describes these three alternative technologies, calculates material balances for given raw peat feed rates of 1000 tph, and evaluates the environmental consequences of all process effluent discharges. Wastewater discharges represent the most significant effluent due to the relatively large quantities of water removed during processing. Treated process water returned to the harvested bog may force in situ, acidic bog water into recieving streams, disrupting local aquatic ecosystems.

  13. Microbial activity and dissolved organic carbon production in drained and rewetted blanket peat

    NASA Astrophysics Data System (ADS)

    Wallage, Z. E.; Holden, J.; Jones, T.; McDonald, A. T.

    2009-04-01

    Heightened levels of degradation in response to environmental change have resulted in an increased loss of dissolved organic carbon (DOC) in the drainage waters of many peatland catchments across Europe and North America. One significant threat to peatland sustainability has been the installation of artificial drainage ditches, and although recent restoration schemes have pursued drain blocking as a possible strategy for reducing degradation and fluvial carbon losses, little is known about how such processes influence the intimate biological systems operating within these soils. This paper investigates how disturbance, in the form of drainage and drain blocking, influences the rate of microbial activity within a peat soil, and the subsequent impact this has on DOC production potential. Peat samples were extracted from three treatment sites (intact peat, drained peat and drain-blocked peat) in an upland blanket peat catchment in the UK. Microbial activity was measured via laboratory experimentation that incorporated the use of an INT-Formazan dehydrogenase enzyme assay to assess the level of electron transport system (ETS) activity occurring within each treatment. Drainage significantly lowered the height of the water table relative to the intact peat, whilst drain blocking successfully rewetted the peat, having raised the height of the water table relative to the drained site. Mean microbial activity rates at the drained site were found to be 33 % greater than the undisturbed intact peat and almost double that of the restored, drain-blocked site. These results correspond well with previously published data observing significantly greater DOC concentrations in the pore waters of the drained site and significantly lower concentrations at the blocked site, relative to the intact peat. Data from the drain-blocked treatment also provides evidence contrary to the commonly quoted hypothesis that an enzyme-latch reaction may be sustained in drained peat, even once it has

  14. Mineral resource of the month: peat

    USGS Publications Warehouse

    Jasinski, Stephen M.

    2008-01-01

    Peat is a natural organic material of botanical origin, harvested from deposits in bogs and fens. Commercial deposits form from the incomplete decomposition of plant matter under anaerobic conditions and gradually accumulate to form peat over about a 5,000-year period.

  15. 23 CFR 752.10 - Abandoned vehicles.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 23 Highways 1 2010-04-01 2010-04-01 false Abandoned vehicles. 752.10 Section 752.10 Highways... ROADSIDE DEVELOPMENT § 752.10 Abandoned vehicles. (a) Abandoned motor vehicles may be removed from the... collection of abandoned motor vehicles from within the right-of-way must be a development project and not...

  16. 23 CFR 752.10 - Abandoned vehicles.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 23 Highways 1 2013-04-01 2013-04-01 false Abandoned vehicles. 752.10 Section 752.10 Highways... ROADSIDE DEVELOPMENT § 752.10 Abandoned vehicles. (a) Abandoned motor vehicles may be removed from the... collection of abandoned motor vehicles from within the right-of-way must be a development project and not...

  17. 23 CFR 752.10 - Abandoned vehicles.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 23 Highways 1 2014-04-01 2014-04-01 false Abandoned vehicles. 752.10 Section 752.10 Highways... ROADSIDE DEVELOPMENT § 752.10 Abandoned vehicles. (a) Abandoned motor vehicles may be removed from the... collection of abandoned motor vehicles from within the right-of-way must be a development project and not...

  18. 23 CFR 752.10 - Abandoned vehicles.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 23 Highways 1 2012-04-01 2012-04-01 false Abandoned vehicles. 752.10 Section 752.10 Highways... ROADSIDE DEVELOPMENT § 752.10 Abandoned vehicles. (a) Abandoned motor vehicles may be removed from the... collection of abandoned motor vehicles from within the right-of-way must be a development project and not...

  19. 23 CFR 752.10 - Abandoned vehicles.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 23 Highways 1 2011-04-01 2011-04-01 false Abandoned vehicles. 752.10 Section 752.10 Highways... ROADSIDE DEVELOPMENT § 752.10 Abandoned vehicles. (a) Abandoned motor vehicles may be removed from the... collection of abandoned motor vehicles from within the right-of-way must be a development project and not...

  20. Using Peat Archives to Quantify Relative Sea-Level Change and Coastal Subsidence

    NASA Astrophysics Data System (ADS)

    Tornqvist, T. E.

    2008-12-01

    Building on a long tradition, peat records continue to play a critical role in reconstructions of Holocene relative sea-level change along the Earth's low-energy shorelines. In many cases, rates of coastal subsidence can be extracted from such relative sea-level data. Recent years have seen considerable attention being focused on refining the paleoenvironmental significance of coastal peat beds by means of a variety of biological and geochemical proxies. The principal goal is to reduce the vertical indicative range of peat samples with respect to tide levels. Geochronolology constitutes the other key element in studies of peat records. The advent of accelerator mass spectrometry in radiocarbon dating has significantly improved age models. The use of plant macrofossils, combined with dating uncertainties now as little as 2 to 3 per mil, makes it possible to develop chronologies with 100-year resolution and sometimes better (calibration uncertainties are typically the limiting factor). Examples are provided of sea-level studies from the US Gulf Coast where the indicative range of brackish to saline marsh peat is on the order of a few decimeters only. This effectively sets the limit of the vertical resolution that can currently be attained. However, this level of resolution does allow differential crustal movements over millennial timescales to be reconstructed with a precision of fractions of millimeters per year. In addition, peat-based relative sea-level records play a crucial role in quantifying compaction rates, as illustrated by a case study from the Mississippi Delta.

  1. Appraisal of peat thickness using combined GPR and terrestrial lidar survey

    NASA Astrophysics Data System (ADS)

    Vsemirnova, Ekaterina; Wilkinson, Maxwell; Carle, Joël; Jarvis, Zak; Miller, Chris; Jones, Richard; Warburton, Jeff

    2013-04-01

    Estimating the depth of peat cover has traditionally been carried out manually using hand-held probe rods, and more recently using methods of near surface geophysics, principally ground-penetrating radar (GPR). These studies provide an important basis for evaluating carbon storage in organic mire ecosystems. However, peatlands often represent a challenge when acquiring GPR over large areas (on the order of 100s ha) of rough terrain; processing of GPR data is also often difficult due to local variations in topography. Little Woolden Moss is > 100 ha peatland site west of Manchester, UK. The site is crossed with numerous shallow ditches and some deeper drainage ditches, and a number of linear raised areas of peat. Peat extraction has taken place on the site over many years, and still being actively worked. A detailed study of peat thickness and base-peat topography was carried out in late 2012. The site was surveyed using a MALÅ RAMAC GPR and 200 MHz unshielded antenna linked to differential GPS. The antennae were housed within a bespoke rough terrain sledge. The data, collected along over 40 profiles with length between 200 and 600 m, were post-processed using MALÅ RadExplorer and Seismic Unix software, including digitising of peat depth layers. Static terrain corrections were derived from terrestrial lidar data acquired at the site using a Riegl LMS-Z40i scanner, integrated with GPS readings provided at the time of GPR survey. The survey enabled detailed maps of base peat elevation and terrain corrected peat thickness to be produced in ArcGIS.

  2. Degradation of drained peat soils in Belarus

    NASA Astrophysics Data System (ADS)

    Bambalov, N. N.

    2009-04-01

    According to Belarusian classification, the drained peat soils with peat layer less then 30 cm and containing organic substance less then 50% are degraded soils. Degraded peat soils made up 190.2 thousand hectares in 2001 from a total area of 1062,2 thousand hectares of drained peat soils for agriculture in Belarus, but the process of degradation is prolonging now and it is expected, that their area will be extended additionally on 12 % till 2020. The degradation of peat soils is most widespread in the region of Polesie, where the area of degraded soils makes up already several thousand hectares in some administrative districts. The degradation of peat soils takes place jet locally on the comparatively not big plots but on the very many places. There is the threat of joining up of the existing now spots of degraded soils in the near future, and the new spots of degraded soils will appear in a very big amount as well. The large tracts of land will appear in the nearest 20-30 years and may be earlier. The degradation of drained peat soils proceeds step by step, and three morphological groups of new soils are forming depending on degree of humification of organic matter, namely: raw humic, humus-fibrous and humus peat soils. The complicated soil complexes with many alternating soil plots containing organic substance both more than 50 % and from 2 till 50 % are forming within one field in result of degradation. For the reason given above a rather not uniform structure of soil cover with unsatisfactory micro relief, big differences of aquatic, thermal and nutritious regimes is forming on agricultural fields, that leads to the substantial decrease of their productivity. In this connection big expanses will require to the rearrangement of drainage systems and leveling of soil fertility within every such field. A fertility of drained peat soils with the depth of peat layer more then 1 m has been estimated as 69 points, with the depth of peat layer 0.3-0.5 m as 62 points

  3. Inventory of peat resources, Aitkin County, Minnesota

    SciTech Connect

    Not Available

    1982-01-01

    The subject of this report is the Minnesota Peat Inventory Project (MPIP) reconnaissance-level peatland survey of Aitkin County, which contains 170,050 ha (420,160 ac) of peatland. The main objectives of this study were to map the resource and to determine the quality, quantity, and energy potential of peat in the county. The report consists of (1) a text that discusses the resource and the survey; and (2) a map of the peat resources in Aitkin County. Over 700 sites were visited by the MPIP to determine peat type and depth. Samples were obtained from 188 selected representative sites for MPIP laboratory analysis. Peatlands cover 170,050 ha (420,160 ac) or 33% of the total area of Aitkin County. Total oven-dried tons of peat amount to 246,414,000 metric tons (276,237,000 US short tons). The peatlands meeting the DOE criteria for fuel-grade peat cover 30,390 ha (75,080 ac) or 18% of the county's lands is 98,134,000 oven-dried metric tons (110,012,000 oven-dried US short tons). These peatlands cover at least 80 contiguous acres and are composed of peat that (1) has an average energy value of 8,874 Btu/lb (moisture-free), (2) has an average ash content of 10.6%, and (3) is at least 150 cm (5 ft) deep. The estimated potential energy of these peat deposits is 1.97 x 10/sup 15/ Btu (1.97 quads of energy) if all three peat types, fibric, hemic, and sapric, in deposits greater than 150 cm deep are considered.

  4. HYDRAULIC CONDUCTIVITY OF ESSENTIALLY SATURATED PEAT

    SciTech Connect

    Nichols, R

    2008-02-27

    The Savannah River National Laboratory measured the hydraulic conductivity of peat samples using method ASTM D4511-00. Four samples of peat were packed into 73mm diameter plastic tubes and saturated from the bottom up with water. The columns were packed with Premier ProMoss III TBK peat to a dry density of approximately 0.16 gm/cc (10 lb/ft3). One column was packed using oven dried peat and the other 3 were packed using as delivered peat. The oven dried sample was the most difficult to saturate. All of the peat samples expanded during saturation resulting in a sample length (L) that was longer than when the sample was initially packed. Table 1 contains information related to the column packing. After saturation the hydraulic conductivity test was conducted using the apparatus shown in Figure 1. Three of the samples were tested at 2 different flow conductions, 1 high and 1 low. Table 2 and Figure 2 contain the results of the hydraulic conductivity testing. Each test was run for a minimum of 40 minutes to allow the test conditions to stabilize. The hydraulic conductivity at the end of each test is reported as the hydraulic conductivity for that test. The hydraulic conductivity of the 4 peat samples is 0.0052 {+-} 0.0009 cm/sec. This result compares well with the hydraulic conductivity measured in the pilot scale peat bed after approximately 2 months of operation. The similarity in results between the dry pack sample and moist pack samples shows the moisture content at the time of packing had a minimal effect on the hydraulic conductivity. Additionally, similarity between the results shows the test is reproducible. The hydraulic conductivity results are similar to those reported by other tests of peat samples reported in the literature.

  5. Some peat deposits in Penobscot County, Maine

    USGS Publications Warehouse

    Cameron, Cornelia Clermont; Anderson, Walter A.

    1979-01-01

    Twenty of the peat deposits in Penobscot County, Maine contain an estimated 29,282,000 short tons air-dried peat. The peat is chiefly sphagnum moss and reed-sedge of high quality according to ASTM standards for agricultural and horticultural use. Analyses show that this same volume has high fuel value, low sulfur and high hydrogen contents compared with lignite and sub-bituminous coal, which may indicate that it also has potential for fuel use. On the basis of the metallic trace element content, one area within the region containing the 20 deposits has been delineated for further bedrock studies.

  6. Trace element content of northern Ontario peat

    SciTech Connect

    Glooschenko, W.A.; Capoblanco, J.A.

    1982-03-01

    Peat samples were collected at 0-20- and 20-40-cm depths from several peatland ecosystems located in northern Ontario, Canada. Analysis was made for the trace metals Zn, Pb, Cu, Cr, Cd, and Hg. Concentration values in general were in the low ppm range and did not significantly differ in terms of peatland type or depth except for Pb. This element was signficantly higher in surface peats in bogs and fens. Concentration of metals in peats found in the study were equivalent to those in US coals, suggesting caution during combustion in terms of potential atmospheric input of metals.

  7. Interdependence of peat and vegetation in a tropical peat swamp forest.

    PubMed Central

    Page, S E; Rieley, J O; Shotyk, W; Weiss, D

    1999-01-01

    The visual uniformity of tropical peat swamp forest masks the considerable variation in forest structure that has evolved in response to differences and changes in peat characteristics over many millennia. Details are presented of forest structure and tree composition of the principal peat swamp forest types in the upper catchment of Sungai Sebangau, Central Kalimantan, Indonesia, in relation to thickness and hydrology of the peat. Consideration is given to data on peat geochemistry and age of peat that provide evidence of the ombrotrophic nature of this vast peatland and its mode of formation. The future sustainability of this ecosystem is predicted from information available on climate change and human impact in this region. PMID:11605630

  8. Influence of peat-bog fire on physical properties of peat-mull soils

    NASA Astrophysics Data System (ADS)

    Stabryla, J.; Lipka, K.

    2009-04-01

    In recent years in Poland disseminated the curse of grassland (either peat meadows) burning. Peat-bogs drained long time ago, where peat-mull soils occur are subjected on fire in particular, because they are often dried. After burned peat remain pits various depth and land irregularity. The aim of the work is morphological characteristics of soil profiles and comparison of chosen physical properties of peat-mull soils on former fire and adjacent area. Research was carried out on the mid-forest peat-bog Wielkie Bloto in Puszcza Niepolomicka. The method used in the work is routinely accepted in soil science. The results show that values of ash content, density and moisture are higher than the ones for soils of adjacent areas. In top stratum of post fire soils bulk density is lower in comparison with upper layers of adjacent soils. Contractility of soils degraded by fire is lower than for soils of adjacent areas.

  9. Inactive and abandoned noncoal mines

    SciTech Connect

    Not Available

    1991-08-01

    Volume 1 outlines the environmental, health and safety problems at IAMS (Inactive, Abandoned Mine Sites), remediation technologies, remediation costs, the methodology states used in preparing state reports, and state summary tables. It also describes the broad range of policy options for remediation of problems associated with IAMS. Volume 2 gives state reports for inactive and abandoned noncoal mines for the following states: Alaska, Arizona, California, Colorado, Florida, Idaho, Minnesota, Missouri, Montana, Nevada, New Mexico, Oregon, South Carolina, South Dakota, Utah, Washington, Wisconsin and Wyoming. Volume 3 lists the State reports for the inactive and abandoned noncoal mines for the following states: Alabama, Arkansas, Illinois, Indiana, Iowa, Louisiana, Maine, Maryland, Mississippi, New York, North Carolina, Ohio, Oklahoma, Pennsylvania, Texas, and Virginia. A separate abstract is included for each of the 3 volumes of this set.

  10. Peat deposits of the Carolina Bays of North Carolina

    SciTech Connect

    Ingram, R.L.; Otte, L.J.; Witner, T.W.

    1983-11-01

    Of the approximately 500 Carolina Bays larger than 100 acres (3,000 ft. long) in the Coastal Plain of North Carolina, 96 contained at least 1 ft of peat. The 96 bays have a total of 35,000 acres of peatland containing 15 millions tons of moisture-free peat. Of these 96 bays, 43 have peat greater than 4 ft thick totaling 8,000 acres with 8 million tons of peat. The largest single deposit of peat greater than 4 ft thick contains 1.1 million tons in a 1,000 acre area. Two main types of peat are present: (1) a black, fine-grained, highly decomposed peat, and (2) a brownish, decomposed somewhat fibrous peat usually found at the base of the thicker peats. An average peat has 84% moisture, 6% ash, 0.2% sulfur, and a heating value of 10,000 Btu/lb.

  11. Extraction, drainage, rewetting, flooding - Patterns of greenhouse gas turnover in restoring temperate peatlands

    NASA Astrophysics Data System (ADS)

    Glatzel, Stephan

    2016-04-01

    The disturbance of natural peatlands destroys carbon sink and is often associated with nitrous oxide emissions. Therefore, the general efforts to mitigate greenhouse gas sources and to create carbon sinks also include peatland restoration. The variety of peatland type (most importantly bog or fen), use (extraction or agriculture), and restoration technique (rewetting or flooding) result in specific patterns of greenhouse gas uptake or emission. Based on examples from own work, I present an overview of the greenhouse gas turnover of following sites: • Cutover peat bogs in Eastern Canada and following rewetting, flooding, and abandonment • Drained cutover and agriculturally used peat bogs in Northern Germany and following extensive agricultural management, paludiculture, rewetting, flooding, and abandonment • Drained agriculturally used fens in Northern Germany and following flooding and paludiculture I show that rewetting, but not flooding may succeed in re-establishing long-term carbon sinks with low methane release rates comparable to the greenhouse gas turnover known from natural peatlands. Flooding risks creating, at least in the short term, extremely strong methane sources. Extensive agricultural management and paludiculture may result in low methane, carbon dioxide and nitrous oxide release rates and could be a sensible option when aiming at reconciling peatland use and protection.

  12. Early Herrin coal-swamp vegetation: Inferences from miospore floras in an abandoned paleochannel

    SciTech Connect

    Willard, D.A. )

    1991-01-01

    A small paleochannel abandoned shortly prior to accumulation of peat to form the Herrin Coal was mapped and sampled in central Illinois. Spore floras from underclays and from incremental coal samples collected within and around the paleochannel were quantified to assess vegetational responses to topographic changes. In the paleochannel, underclay floras are diverse and dominated by miospores of cordaites, with miospores of tree ferns, small ferns, and sphenopsids common. In contrast, underclays outside the paleochannel are dominated strongly by lycopod miospores. The earliest coal in the paleochannel is dominated by tree-fern miospores with subdominant cordaites; subsequent increments exhibit alternating dominance of tree-fern and lycopod miospores. Outside the paleochannel, all increments of coal are dominated by tree-fern or lycopod miospores. Underclay miospore floras indicate that a more diverse, cordaitean-rich assemblage grew along the paleochannel flanks prior to peat accumulation, rather than the lycopod-dominated flora found elsewhere. Unlike the surrounding swamp, the earliest coal in the paleochannel has an unusual miospore assemblage for the Herrin Coal. Miospore and coal compaction data both indicate that peat accumulation began in the paleochannel before extending across a broader area. These differences in miospore composition and abundance suggest that changes in topography and water-table level exerted strong control on vegetational composition of the coal swamp. This unusual exposure provides evidence that edaphic factors related to topography influenced vegetational composition in both clastic and peat-accumulating swamps.

  13. Influence of peat formation conditions on the transformation of peat deposit organic matter

    NASA Astrophysics Data System (ADS)

    Serebrennikova, O. V.; Strelnikova, E. B.; Preis, Yu I.; Duchko, M. A.

    2015-11-01

    The paper studies the individual composition of n-alkanes, polycycloaromatic hydrocarbons, steroids, bi-, tri-, and pentacyclic terpenoids of two peat deposits of rich fen Kirek located in Western Siberia. Considering the individual n-alkanes concentrations, some indexes were calculated to estimate the humidity during peat formation. It was shown that the pH of peat medium primarily affects steroids, tri- and pentacyclic terpenoids transformations.

  14. Metal sorption by peat and algae treated peat: kinetics and factors affecting the process.

    PubMed

    Lourie, Elena; Gjengedal, Elin

    2011-10-01

    The article presents a new approach that can be used for the purification of water contaminated by heavy metals. The treatment of peat with microalgae showed to be an effective way of increasing metal uptake by peat. Metal sorption was studied for a multimetal solution containing Cu, Cd, Ni, Zn, Cd, and Pb. Cu and Pb were found to be the metals having the highest affinity to peat. Water hardness has a strong effect on the uptake of borderline metals (Cd, Ni, Zn, Cd) from a solution. The use of algae for peat treatment resulted in less time to reach an equilibrium (24 h vs. 72 h for pure peat), and the effect of water hardness (Ca²⁺) on metal uptake was considerably reduced. Both peat and algal-treated peat were able to take up metals from rather acidic solutions (pH 3.0). pH had less influence on the metal uptake compared with water hardness. The affinity of heavy metals to peat was the following: Pb>Cu>Ni>Cd>Zn>Co. It slightly changed to Pb>Cu>Ni>Cd≈Co≈Zn when the combined sorbent, peat treated with microalga, was applied.

  15. Radioactivity of peat mud used in therapy.

    PubMed

    Karpińska, Maria; Mnich, Krystian; Kapała, Jacek; Bielawska, Agnieszka; Kulesza, Grzegorz; Mnich, Stanisław

    2016-02-01

    The aim of the study was to determine the contents of natural and artificial isotopes in peat mud and to estimate the radiation dose absorbed via skin in patients during standard peat mud treatment. The analysis included 37 samples collected from 8 spas in Poland. The measurements of isotope concentration activity were conducted with the use of gamma spectrometry methods. The skin dose in a standard peat mud bath therapy is approximately 300 nSv. The effective dose of such therapy is considered to be 22 nSv. The doses absorbed during peat mud therapy are 5 orders of magnitude lower than effective annual dose absorbed from the natural radiation background by a statistical Pole (3.5 mSv). Neither therapeutic nor harmful effect is probable in case of such a small dose of ionising radiation.

  16. The effect of pore structure on ebullition from peat

    NASA Astrophysics Data System (ADS)

    Ramirez, Jorge A.; Baird, Andy J.; Coulthard, Tom J.

    2016-06-01

    The controls on methane (CH4) bubbling (ebullition) from peatlands are uncertain, but evidence suggests that physical factors related to gas transport and storage within the peat matrix are important. Variability in peat pore size and the permeability of layers within peat can produce ebullition that ranges from steady to erratic in time and can affect the degree to which CH4 bubbles bypass consumption by methanotrophic bacteria and enter the atmosphere. Here we investigate the role of peat structure on ebullition in structurally different peats using a physical model that replicates bubble production using air injection into peat. We find that the frequency distributions of number of ebullition events per time and the magnitude of bubble loss from the physical model were similar in shape to ebullition from peatlands and incubated peats. This indicates that the physical model could be a valid proxy for naturally occurring ebullition from peat. For the first time, data on bubble sizes from peat were collected to conceptualize ebullition, and we find that peat structure affects bubble sizes. Using a new method to measure peat macrostructure, we collected evidence that supports the hypothesis that structural differences in peat determine if bubble release is steady or erratic and extreme. Collected pore size data suggest that erratic ebullition occurs when large amounts of gas stored at depth easily move through shallower layers of open peat. In contrast, steady ebullition occurs when dense shallower layers of peat regulate the flow of gas emitted from peat.

  17. Biochar as a Substitute for Peat in Greenhouse Growing Media: Soil Water Characteristics and Carbon Leaching Dynamics

    NASA Astrophysics Data System (ADS)

    Johnson, M. S.; Hilbert, I.; Jollymore, A. J.

    2012-12-01

    Biochar (charcoal derived from waste biomass via pyrolysis) has the potential to be used as part of regional scale carbon sequestration strategies. By providing a stable form of carbon that is resistant to decay in soils, biochar can be utilized in a wide range of applications to improve the sustainability of land use management practices. Due to its high water holding capacity, surface area and charge density, it could provide a substitute for peat that is widely used in horticultural activities. Globally, peat production in 2010 amounted to 23.4 Mt, with more than a third of this used for horticulture. In Canada, essentially all peat produced is used for horticulture, with each ton of peat extracted also contributing about 0.7 t CO2e in combined greenhouse gas emissions related to production, transportation and use of peat. We evaluated biochar produced on farm from red alder as a peat substitute in terms of soil water characteristics and carbon leaching in greenhouse growing media (e.g. potting mix). Biochar mixing ratios of 10% (v/v) and greater provided water holding capacity equivalent to peat-based potting mixes. We also present results from a laboratory wetting experiment in which we characterized leachate for dissolved organic carbon (DOC) concentration and DOC characteristics using spectral methods (uV-Vis and fluorescence spectroscopy).

  18. Complexity Analysis of Peat Soil Density Distribution

    NASA Astrophysics Data System (ADS)

    Sampurno, Joko; Diah Faryuni, Irfana; Dzar Eljabbar Latief, Fourier; Srigutomo, Wahyu

    2016-08-01

    The distributions of peat soil density have been identified using fractal analysis method. The study was conducted on 5 peat soil samples taken from a ground field in Pontianak, West Kalimantan, at the coordinates (0 ° 4 '2:27 "S, 109 ° 18' 48.59" E). In this study, we used micro computerized tomography (pCT Scanner) at 9.41 micro meter per pixel resolution under peat soil samples to provide 2-D high-resolution images L1-L5 (200 200 pixels) that were used to detect the distribution of peat soil density. The method for determining the fractal dimension and intercept was the 2-D Fourier analysis method. The method was used to obtain the log log-plot of magnitude with frequency. Fractal dimension was obtained from the straight regression line that interpolated the points in the interval with the largest coefficient determination. Intercept defined by the point of intersection on the -axis. The conclusion was that the distributions of peat soil density showing the fractal behaviour with the heterogeneity of the samples from the highest to the lowest were L5, L1, L4, L3 and L2. Meanwhile, the range of density values of the samples from the highest to the lowest was L3, L2, L4, L5 and L1. The study also concluded that the behaviour of the distribution of peat soil density was a weakly anisotropic.

  19. Bearing the risk of abandonment

    SciTech Connect

    Attanasio, Donna M.

    2010-05-15

    In Order Nos. 679 and 679-A, FERC adopted a policy of authorizing rate incentives for new transmission early in the development process to encourage transmission investment. The abandoned-plant cost recovery incentive creates a tension between ratepayer and investor interests, which is increasingly reflected in FERC's orders. (author)

  20. Peat resource definition and utilization in Massachusetts. Final report, Phase One

    SciTech Connect

    Brenninkmeyer, B.M.; Russo, J.S.

    1984-10-01

    To data less than five percent of Massachusetts peatlands have been developed. Ninety percent of the developed peatlands are located in the southeastern section of Massachusetts. Seventy-five percent of the developed peatlands are used for cranberry bogs. The remainder is used for horticultural peak extraction. At the present time peatland uses can be grouped into two types, consumptive and nonconsumptive. The primary consumptive uses are: (1) extraction of peat for use as or with industrial chemicals, (2) use by the horticultural industry and (3) most important under the DOE/MEOER Program, the use of peak as a fuel. The three uses of peat under consumptive usage will require extraction or harvesting of peatlands. The main nonconsumptive uses are: (1) preservation of peatlands for conservation lands, (2) biomass production, (3) timber production and (4) the most important under the title of nonconsumptive uses is peatlands for agricultural crop production. These four uses require little or no peat extraction, harvesting or alteration of the wetlands. The selection and feasibility of one particular use over another is influenced by the significance of the economics and environmental concerns as well as the types and volumes of peat. 55 figures, 12 tables.

  1. Carbon dioxide emissions through oxidative peat decomposition on a burnt tropical peatland.

    PubMed

    Hirano, Takashi; Kusin, Kitso; Limin, Suwido; Osaki, Mitsuru

    2014-02-01

    In Southeast Asia, a huge amount of peat has accumulated under swamp forests over millennia. Fires have been widely used for land clearing after timber extraction, thus land conversion and land management with logging and drainage are strongly associated with fire activity. During recent El Niño years, tropical peatlands have been severely fire-affected and peatland fires enlarged. To investigate the impact of peat fires on the regional and global carbon balances, it is crucial to assess not only direct carbon emissions through peat combustion but also oxidative peat decomposition after fires. However, there is little information on the carbon dynamics of tropical peat damaged by fires. Therefore, we continuously measured soil CO2 efflux [peat respiration (RP)] through oxidative peat decomposition using six automated chambers on a burnt peat area, from which about 0.7 m of the upper peat had been lost during two fires, in Central Kalimantan, Indonesia. The RP showed a clear seasonal variation with higher values in the dry season. The RP increased logarithmically as groundwater level (GWL) lowered. Temperature sensitivity or Q10 of RP decreased as GWL lowered, mainly because the vertical distribution of RP would shift downward with the expansion of an unsaturated soil zone. Although soil temperature at the burnt open area was higher than that in a near peat swamp forest, model simulation suggests that the effect of temperature rise on RP is small. Annual gap-filled RP was 382 ± 82 (the mean ± 1 SD of six chambers) and 362 ± 74 gC m(-2)  yr(-1) during 2004-2005 and during 2005-2006 years, respectively. Simulated RP showed a significant negative relationship with GWL on an annual basis, which suggests that every GWL lowering by 0.1 m causes additional RP of 89 gC m(-2)  yr(-1) . The RP accounted for 21-24% of ecosystem respiration on an annual basis.

  2. Drainage and land use impacts on changes in selected peat properties and peat degradation in West Kalimantan Province, Indonesia

    NASA Astrophysics Data System (ADS)

    Anshari, G. Z.; Afifudin, M.; Nuriman, M.; Gusmayanti, E.; Arianie, L.; Susana, R.; Nusantara, R. W.; Sugardjito, J.; Rafiastanto, A.

    2010-11-01

    Degradation of tropical peats is a global concern due to large Carbon emission and loss of biodiversity. The degradation of tropical peats usually starts when the government drains and clears peat forests into open peats used for food crops, oil palm and industrial timber plantations. Major properties of tropical peat forests are high in Water Contents (WC), Loss on Ignition (LOI) and Total Organic Carbon (TOC), and low in peat pH, Dry Bulk Density (DBD), and Total Nitrogen (TN). In this study, we investigated impacts of drainage and land use change on these properties. We collected peat samples from peat forests, logged over peat forest, industrial timber plantation, community agriculture, and oil palms. We used independent t-tests and oneway ANOVA to analyze mean differences of the research variables. We found that peat pH, DBD, and TN tend to increase. A significant decrease of C/N ratio in oil palm and agriculture sites importantly denotes a high rate of peat decompositions. Water contents, LOI, and TOC are relatively constants. We suggest that changes in pH, DBD, TN and atomic C/N ratio are important indicators for assessing tropical peat degradation. We infer that land use change from tropical peat forests into cleared and drained peats used for intensive timber harvesting, oil palms and industrial timber plantations in Indonesia has greatly degraded major ecological function of tropical peats as Carbon storage.

  3. Postglacial climate-change record in biomarker lipid compositions of the Hani peat sequence, Northeastern China

    NASA Astrophysics Data System (ADS)

    Zhou, Weijian; Zheng, Yanhong; Meyers, Philip A.; Jull, A. J. Timothy; Xie, Shucheng

    2010-05-01

    The peat sequence at Hani in northeastern China accumulated over the past 16 cal kyr in a percolation mire in which rain water and ground water seeped through the peat system. The molecular compositions of n-alkanes, n-alkanols, and n-alkanoic acids extracted from the Hani peat sequence reveal different responses to the progressive evolution of climate and changes in the nature of the peat-forming vegetation. Long chain length components that originate from the waxy coatings of subaerial vascular plants dominate the n-alkane distributions throughout the Hani peat sequence. The paleoclimate integrity of these biomarker molecules appears to be well preserved. Most of the n-alkanol distributions are similarly dominated by long chain components that indicate their origins from subaerial plants. In contrast, n-alkanoic acid distributions are dominated by secondary components that record the importance of post-depositional microbial activity in this peat sequence, which evidently can be extensive in a percolation mire. Elevated n-alkane Paq values and C 23/C 29 ratios, which are both molecular proxies for water-loving plants, record an especially moist local climate in the Bølling-Allerød (14.5 to 12.9 ka), Younger Dryas (12.9 to 11.5 ka), and Pre-Boreal (11.5 to 10.5 ka) portions of the Hani peat sequence. Depressed Paq values and C 23/C 29 ratios and larger n-alkane average chain length values indicate that the Holocene Climatic Optimum (10.5 to 6 ka) was a period of warmer climate with lower effective precipitation, which contrasts with evidence of wetter climates in most of East Asia.

  4. Biomarkers of peat-forming plants and their signal in tidal flat sediments of the german bight

    NASA Astrophysics Data System (ADS)

    Wöstmann, R.; Köller, C.; Rullkötter, J.

    2003-04-01

    Induced by the Holocene sea level rise a number of different peat layers developed in the surface of today´s Wadden Sea of NW Germany. Furthermore, lipid analysis of Wadden Sea sediments showed a significant component of terrestrial organic matter derived from erosion of peat layers in this highly dynamic area. In order to characterise these peats and their remnants in tidal flat sediments in a paleochemotaxonomical way, recent plant material as well as different types of peats were selected for biomarker investigation. Recent plant material was linked paleochemotaxonomically to deposited peats and Wadden Sea sediments by means of selected biomarkers. A significant variation of the n-alkane distribution pattern between raised bog plants and fen plants was detected. The raised bog plants showed an n-alkane maximum at n-C31, the fen plants at n-C27 and n-C29. This is in agreement with results of the botanical and geochemical analysis of different types of Holocene peat layers in this area. In the selected Wadden Sea sediment core the n-alkane distribution showed an odd over even carbon number predominance with maxima at n-C27, n-C29 or n-C31, indicating an origin from different peat types. In addition, pentacyclic triterpenoids are characteristic biomarkers for bog and fen plant communities. Their distribution patterns and total amounts allow a clear distinction between raised-bog-forming plants and fen-peat-forming plants. Whereas all analysed fen-peat-forming plants were barren of triterpenoids, raised-bog-forming plants like Erica tetralix contain triterpenoids at a level of more than 10% of the total lipid extract. All other bog-forming plants also contain high amounts of triterpenoids like a-amyrin, ß-amyrin, friedelin, lupeol, multiflorenon and taraxerol. However, individual triterpenoids are not plant-specific biomarkers because of possible diagenetic effects. When triterpenoids are found in fen peats they are due to the influence of non-peat-forming plant

  5. 7 CFR 767.51 - Property abandonment.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 7 Agriculture 7 2010-01-01 2010-01-01 false Property abandonment. 767.51 Section 767.51... AGRICULTURE SPECIAL PROGRAMS INVENTORY PROPERTY MANAGEMENT Property Abandonment and Personal Property Removal § 767.51 Property abandonment. The Agency will take actions necessary to secure, maintain,...

  6. 7 CFR 767.51 - Property abandonment.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 7 Agriculture 7 2011-01-01 2011-01-01 false Property abandonment. 767.51 Section 767.51... AGRICULTURE SPECIAL PROGRAMS INVENTORY PROPERTY MANAGEMENT Property Abandonment and Personal Property Removal § 767.51 Property abandonment. The Agency will take actions necessary to secure, maintain,...

  7. 32 CFR 644.496 - Abandonment.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 32 National Defense 4 2010-07-01 2010-07-01 true Abandonment. 644.496 Section 644.496 National... HANDBOOK Disposal Disposal of Buildings and Other Improvements (without the Related Land) § 644.496 Abandonment. Abandonment, as used herein, has reference to cases where the lessor or a permittor...

  8. Contrasting denitrifier communities relate to contrasting N2O emission patterns from acidic peat soils in arctic tundra.

    PubMed

    Palmer, Katharina; Biasi, Christina; Horn, Marcus A

    2012-05-01

    Cryoturbated peat circles (that is, bare surface soil mixed by frost action; pH 3-4) in the Russian discontinuous permafrost tundra are nitrate-rich 'hotspots' of nitrous oxide (N(2)O) emissions in arctic ecosystems, whereas adjacent unturbated peat areas are not. N(2)O was produced and subsequently consumed at pH 4 in unsupplemented anoxic microcosms with cryoturbated but not in those with unturbated peat soil. Nitrate, nitrite and acetylene stimulated net N(2)O production of both soils in anoxic microcosms, indicating denitrification as the source of N(2)O. Up to 500 and 10 μM nitrate stimulated denitrification in cryoturbated and unturbated peat soils, respectively. Apparent maximal reaction velocities of nitrite-dependent denitrification were 28 and 18 nmol N(2)O g(DW)(-1) h(-1), for cryoturbated and unturbated peat soils, respectively. Barcoded amplicon pyrosequencing of narG, nirK/nirS and nosZ (encoding nitrate, nitrite and N(2)O reductases, respectively) yielded ≈49 000 quality-filtered sequences with an average sequence length of 444 bp. Up to 19 species-level operational taxonomic units were detected per soil and gene, many of which were distantly related to cultured denitrifiers or environmental sequences. Denitrification-associated gene diversity in cryoturbated and in unturbated peat soils differed. Quantitative PCR (inhibition-corrected per DNA extract) revealed higher copy numbers of narG in cryoturbated than in unturbated peat soil. Copy numbers of nirS were up to 1000 × higher than those of nirK in both soils, and nirS nirK(-1) copy number ratios in cryoturbated and unturbated peat soils differed. The collective data indicate that the contrasting N(2)O emission patterns of cryoturbated and unturbated peat soils are associated with contrasting denitrifier communities.

  9. Contrasting denitrifier communities relate to contrasting N2O emission patterns from acidic peat soils in arctic tundra

    PubMed Central

    Palmer, Katharina; Biasi, Christina; Horn, Marcus A

    2012-01-01

    Cryoturbated peat circles (that is, bare surface soil mixed by frost action; pH 3–4) in the Russian discontinuous permafrost tundra are nitrate-rich ‘hotspots' of nitrous oxide (N2O) emissions in arctic ecosystems, whereas adjacent unturbated peat areas are not. N2O was produced and subsequently consumed at pH 4 in unsupplemented anoxic microcosms with cryoturbated but not in those with unturbated peat soil. Nitrate, nitrite and acetylene stimulated net N2O production of both soils in anoxic microcosms, indicating denitrification as the source of N2O. Up to 500 and 10 μ nitrate stimulated denitrification in cryoturbated and unturbated peat soils, respectively. Apparent maximal reaction velocities of nitrite-dependent denitrification were 28 and 18 nmol N2O gDW−1 h−1, for cryoturbated and unturbated peat soils, respectively. Barcoded amplicon pyrosequencing of narG, nirK/nirS and nosZ (encoding nitrate, nitrite and N2O reductases, respectively) yielded ≈49 000 quality-filtered sequences with an average sequence length of 444 bp. Up to 19 species-level operational taxonomic units were detected per soil and gene, many of which were distantly related to cultured denitrifiers or environmental sequences. Denitrification-associated gene diversity in cryoturbated and in unturbated peat soils differed. Quantitative PCR (inhibition-corrected per DNA extract) revealed higher copy numbers of narG in cryoturbated than in unturbated peat soil. Copy numbers of nirS were up to 1000 × higher than those of nirK in both soils, and nirS nirK−1 copy number ratios in cryoturbated and unturbated peat soils differed. The collective data indicate that the contrasting N2O emission patterns of cryoturbated and unturbated peat soils are associated with contrasting denitrifier communities. PMID:22134649

  10. Peat biogasification development program. Quarterly progress report No. 2, January 1-March 31, 1980

    SciTech Connect

    Wise, Donald L.; Buivid, Michael G.

    1980-01-01

    Batch experiments have been performed to determine the effects of different alkalis, temperatures, retention times, solids loading, and oxygen partial pressures on the solubility of peat organic material. Oxidation experiments have been performed simultaneously with and separately from solubilization. In both cases kinetic information has been developed based on oxygen consumption. Kinetics based on fermentable product formation are dependent on satisfactory identification methods. Development of analytical procedures for product identification have included: Gel Permeation Chromatography (GPC), solvent extraction, aldehyde precipitation, and Thin Layer Chromatography (TLC). Microorganisms from three inoculation sources are being grown anaerobically using a growth medium containing a standard nutrient and a specific substrate, one of twelve aromatic compounds. The concentration of aromatic compound was increased gradually in order that bacteria acclimate for future use as inocula with pretreated peat liquors. Acids and methane production are being monitored for pretreated peat liquor fermentations using an acclimated microorganism inocula. Apparent viscosity and apparent heat transfer coefficient data are being obtained at three peat slurry solids concentrations (3-5, 10, 15% total solids). A 75% heat recovery would give a positive energy balance around the pretreatment reactor. Development has continued in regards to full scale peat biogasification design (75 x 10/sup 6/ SCFD, pipeline quality methane). The information necessary for continuous PDU scale operation is being evaluated in terms of what processing information may be obtained from various scale units, batch and continuous.

  11. Sources of variability in peat composition and the role of peat age

    NASA Astrophysics Data System (ADS)

    Leifeld, Jens

    2016-04-01

    During peat formation decaying plant material undergoes partial decomposition that continuously transform its organic matter. As part of this transformation, aromatic moieties such as plant-borne polyphenols are considered to accumulate relative to more labile compounds such as carbohydrates. Here, 13C CPMAS-NMR data from 71 peat samples from sites across Europe (61°48' N - 46°49' N) are analyzed for their variability. Sites differ in their degree of peat disturbance and range from natural to long-term drained and thus strongly degraded. Application of a molecular mixing model to the NMR data indicated that, on average, peat consists by 27, 22, 21, 18, and 11 % of carbohydrates, aliphatics, aromatics, proteins, and char, respectively. Compositional variability was most pronounced for aromatics and carbohydrates. So far, half of the samples was age-dated using 14C. Calibrated 14C ages in the data set range from recent to c. 10000 years BP. Relationships between peat composition and age were non-linear and highly significant. Aromatic moieties accumulated with increasing peat age whereas O-containing moieties relatively declined, in line with a decrease in molar O/C ratios. The relative accumulation of aromatics was 250 % during 10000 years whereas O-containing moieties declined relatively by 65 %. About half of this selective accumulation and degradation occurred during the first 2000 years of peat accumulation, thereby reflecting higher microbial transformation rates during initial phases of built-up. Char content increased with peat age, possibly indicating selective preservation of char during peat formation. C/N ratios correlated significantly but bi-modal with age. The analysis shows that peat age is a reliable proxy for organic matter transformation in peatlands. Because rates and degree of transformation are derived from multiple sites, the found relationships seem to reveal a general pattern, at least for the studied boreal and temperate systems.

  12. Selected Trace Element Concentrations in Peat Used for Cosmetic Production - A Case Study from Southern Poland

    NASA Astrophysics Data System (ADS)

    Glina, Bartłomiej

    2016-12-01

    The aim of the study was to assess the concentration of selected trace elements in organic soils used as a source to obtain a unique peat extract for cosmetics production. Peat material for laboratory analysis were collected from fen peatland located in the Prosna River Valley (Borek village). Studied peatland is managed by "Torf Corporation" company as a source of material to obtain peat extract for cosmetics production. In the collected soil samples (four soil profiles) Zn, Cu and Pb concentrations were determined by using atomic absorption spectrometer SpectraAA 220 (Varian), after acid digestion. Obtained results showed that the highest concentrations of selected trace elements were recorded in the surface horizons of organic soils. This fact might be the results of Prosna river flooding or air deposition. Howevere, according to the new Polish regulations (Ordinance of the Minister for Environment 01.09.2016 - the way of conducting contamination assessment of the earth surface), the content of trace elements in the examined soils was greatly belowe the permissible limit for areas from group IV (mine lands). Thus, described soils are proper to obtain peat extract used as a component in cosmetic production.

  13. Abandoned Mine Detection in Western Pennsylvania Using Surface Wave Data

    NASA Astrophysics Data System (ADS)

    Miller, B.

    2015-12-01

    Abandoned mines throughout the Appalachian region of the United States have been recognized as problematic. Resource extraction from these mines has long ceased and few, if any, documents pertaining to these operations exist. Over time support structures internal to the mines may collapse and lead to subsidence, potentially damaging surface structures. A non-invasive, surface deployed seismic method to detect undisclosed, abandoned near-surface mines would be beneficial as a first step to remediation. The use of seismic surface waves to analyze the upper several tens of meters of the subsurface has become an important technique for near-surface investigations and may provide a method for detection of near-surface, abandoned mine shafts. While there are many undocumented abandoned mines throughout the Appalachians one known example exists within Butler County, Pennsylvania. Although little is known about the overall operation there is limited documentation which provides information as to the location of the mine tunnels. Currently there is no recognized surface subsidence associated with the mine however documents indicate that the abandoned mining operations have an estimated depth ranging from twenty to fifty feet. To assist with acquisition a seismic land streamer was constructed. Use of a land streamer increases the speed, ease and efficiency required to perform a seismic survey. Additionally the land streamer allows for the acquisition of seismic surface waves which were analyzed using the Multichannel Analysis of Surface Waves (MASW) method. Data were acquired by conducting multiple, adjacent surveys perpendicular to the suspected location of abandoned mine tunnels. Throughout the survey area to a depth of approximately 15 meters, shear wave velocities range between approximately 200-1200 m/s. Based upon shear wave velocity changes within the profile anomalies have been identified corresponding to the contrast between the suspected mined, and unmined, areas.

  14. A Few Issues on the Peat Research in the Altai Mountains

    NASA Astrophysics Data System (ADS)

    Inisheva, Lydia I.; Larina, Galina; Shurova, Maya

    2010-05-01

    At the present time we carry out complex research of marsh ecosystems in various areas of Gorny Altai to reveal the perspective deposits of peat in the Altai Mountains with the purpose of its use in the medical and recreational spheres. The peat deposits of the Northeastern Altai, Central Altai, and Southeastern Altai are surveyed; the selective chemical analysis of peat and marsh waters is carried out. The group structure of organic substance of various samples of peat is investigated by the method of Institutes of Peat. The toxic metals of Cd, Pb, Hg, Cu, Zn, and As were defined by the method of stripping voltammetry. The region of the Altai Mountains is characterized by the contrastive distribution of some heavy metals and arsenic in a soil cover. This is caused by a variety of petrography and granulometry of soil forming material, and also by a landscape and geochemical situation in the system of vertical zoning. The sources of natural accumulation of heavy metals in the ground might be the deposits of polymetals. In this connection the content of the specified toxic elements in the peat under research has been identified. The peat of the Turochak deposit is characterized by a significant ash content - up to 41,9%; the increased ash content is typical of the Kutyush deposit: from 6,1% up to 19, %. The peat of the Northeastern Altai is referred to non-bitumunous: the content of bitumen makes up less than 5%. In comparison with the European peat the peat under study of the transitive and lowland type is characterized by the significant content of easy hydrolysable substances in the amount of 24,8-41,1%. The amount of the non-hydrolysable rest makes up around 4,3 - 7,4 %. The total content of fulvic acids is less than the content of humic acids by 2,9 - 5,8 times. The high content of humic acids which can reach up to 58 % is characteristic of certain deposits. Humic acids extracted from the peat are characterized, as a rule, by similar IR-spectra. The distinctions

  15. Chemical properties of peat used in balneology

    NASA Astrophysics Data System (ADS)

    Szajdak, L.; Hładoń, T.

    2009-04-01

    The physiological activity of peats is observed in human peat-bath therapy and in the promotion of growth in some plants. Balneological peat as an ecologically clean and natural substance is perceived as being more 'human friendly' than synthetic compounds. Poland has a long tradition of using balneological peat for therapeutic purposes. Balneological peat reveals a physical effect by altering temperature and biochemical effects through biologically active substances. It is mainly used for the treatment of rheumatic diseases that are quite common in Poland. Peat represents natural product. Physico-chemical properties of peat in particular surface-active, sorption and ion exchanges, defining their biological function, depend mainly on the chemical composition and molecular structure of humic substances representing the major constituent of organic soil (peat). The carbon of organic matter of peats is composed of 10 to 20% carbohydrates, primarily of microbial origin; 20% nitrogen-containing constituents, such as amino acids and amino sugars; 10 to 20% aliphatic fatty acids, alkanes, etc.; with the rest of carbon being aromatic. For balneology peat should be highly decomposed (preferably H8), natural and clean. The content of humic acids should exceed 20% of dry weight, ash content will be less than 15 15% of dry weight, sulphur content less than 0.3% of dry weight and the amount of water more than 85%. It will not contain harmful bacteria and heavy metals. Humic substances (HS) of peat are known to be macromolecular polydisperse biphyllic systems including both hydrophobic domains (saturated hydrocarbon chains, aromatic structural units) and hydrophilic functional groups, i. e having amphiphilic character. Amphiphilic properties of FA are responsible for their solubility, viscosity, conformation, surfactant-like character and a variety of physicochemical properties of considerable biologically practical significance. The chemical composition of peats depends

  16. Fiber Effects on Compressibility of Peat

    NASA Astrophysics Data System (ADS)

    Johari, N. N.; Bakar, I.; Razali, S. N. M.; Wahab, N.

    2016-07-01

    Fibers found in the soil, especially in peaty soil play an important role in the determination of soil compressibility. Peat soils are the results from the decomposition of organic matter and the type of peat can be classified based on the fibrous material in the soil. In the engineering field, peat soil was mostly known as soils that has a serious settlement with high compressibility index. From the previous research, fibers in the soil were influenced in compressibility in terms of size, shape, fibric, soil arrangement and etc. Hence, this study attempts the determination of fibers effects on the compressibility of peat using a 1-D oedometer consolidation test. The reconstituted peat samples of different particle sizes were used to determine the consolidation parameters and the results obtained from reconstituted samples were also compared with the undisturbed sample. 1-D oedometer consolidation tests were performed on the samples by using the load increment method. The results shows, the higher particle size (R3.35), give higher moisture content (w = 401.20%) and higher initial void ratio (eo = 5.74). In settlement prediction, the higher the fiber content will results the higher the compression index, therefore, it will cause high of settlement.

  17. Long-period astronomically forced peat deposits

    NASA Astrophysics Data System (ADS)

    Valero, Luis; Garcés, Miguel; Cabrera, Lluís; Sáez, Alberto

    2016-04-01

    Organic matter sequestration by peat accumulation constitutes a primary sink for carbon in the global carbon cycle. Disclosing the processes that control the formation and storage of peat at time scales ranging from 103-106 years is a non-solved issue important for understanding the global climate system. We analyzed a 7 million years long terrestrial record of Late Oligocene age from the coal-bearing As Pontes Basin in Northwestern Spain. Biochronological constraints were included in order to refine a former magnetostratigraphy, giving rise a robust age model. This data was used to perform a cyclostratigraphic analysis. The obtained results show that minima in the 405-kyr and 2.4-Myr eccentricity cycles play a key role in peat formation. Such nodes exhibit reduced precession amplitudes, thus avoiding extremes in seasons and seasonal contrast for a prolonged period of time. In the As Pontes Basin, this orbital configuration is associated with a decrease in siliciclastic sedimentation and enhanced peat formation. Feedbacks between equilibrium landscapes and ecosystem stability will lead to a deceleration of weathering and erosion rates in catchment areas and to minimize and stabilize the sediment flux along the sediment routing system. Mid-latitude peat burial could contribute to disturb the carbon cycle by removing (atmospheric) carbon at times of minimum eccentricity.

  18. Mechanisms controlling Cu, Fe, Mn, and Co profiles in peat of the Filson Creek Fen, northeastern Minnesota

    USGS Publications Warehouse

    Walton-Day, K.; Filipek, L.H.; Papp, C.S.E.

    1990-01-01

    Filson Creek Fen, located in northeastern Minnesota, overlies a Cu-Ni sulfide deposit. A site in the fen was studied to evaluate the hydrogeochemical mechanisms governing the development of Fe, Mn, Co, and Cu profiles in the peat. At the study site, surface peat approximately 1 m thick is separated from the underlying mineralized bedrock by a 6-12 m thickness of lake and glaciofluvial sediments and till. Concentrations of Fe, Mn, Co, and Cu in peat and major elements in pore water delineate a shallow, relatively oxidized, Cu-rich zone overlying a deeper, reduced, Fe-, Mn-, and Co-rich zone within the peat. Sequential metal extractions from peat samples reveal that 40-55% of the Cu in the shallow zone is associated with organic material, whereas the remaining Cu is distributed between iron-oxide, sulfide, and residual fractions. Sixty to seventy percent of the Fe, Mn, and Co concentrated in the deeper zone occur in the residual phase. The metal profiles and associations probably result from non-steady-state input of metals and detritus into the fen during formation of the peat column. The enrichment of organic-associated Cu in the upper, oxidized zone represents a combination of Cu transported into the fen with detrital plant fragments and soluble Cu, derived from weathering of outcrop and subcrop of the mineral deposit, transported into the fen, and fixed onto organic matter in the peat. The variable stratigraphy of the peat indicates that weathering processes and surface vegetation have changed through time in the fen. The Fe, Mn, and Co maxima at the base of the peat are associated with a maximum in detrital matter content of the peat resulting from a transition between the underlying inorganic sedimentary environment to an organic sedimentary environment. The chemistry of sediments and ground water collected beneath the peat indicate that mobilization of metals from sulfide minerals in the buried mineral deposit or glacial deposits is minimal. Therefore, the

  19. Fixed-bed gasification research using US coals. Volume 11. Gasification of Minnesota peat. [Peat pellets and peat sods

    SciTech Connect

    Thimsen, D.; Maurer, R.E.; Pooler, A.R.; Pui, D.; Liu, B.; Kittelson, D.

    1985-05-01

    A single-staged, fixed-bed Wellman-Galusha gasifier coupled with a hot, raw gas combustion system and scrubber has been used to gasify numerous coals from throughout the United States. The gasification test program is organized as a coooperative effort by private industrial participants and governmental agencies. The consortium of participants is organized under the Mining and Industrial Fuel Gas (MIFGa) Group. This report is the eleventh volume in a series of reports describing the atmospheric pressure, fixed-bed gasification of US coals. This specific report describes the gasification of peat pellets and peat sods during 3 different test periods. 2 refs., 20 figs., 13 tabs.

  20. Immunomodulative properties of humic peat preparations

    NASA Astrophysics Data System (ADS)

    Stepchenko, L. M.; Syedykh, N. J.

    2010-05-01

    It is proved, that the humic peat preparations promote the resistance of plants, animals and poultry to the influence of both abyotyc and byotyc extreme factors of external environment, to action. It was shown by us before, that biologically active compounds from peat promote stability against different diseases of agricultural animals and poultry. We conducted researches of humic preparations influence (hydrohumate and oxyhumate) on several indexes of immunoreactivity of the organisms of chickens broilers, ostriches, cows and laboratory rats. It is found out, that adding of humic preparations to forage or drinking water results in the normalization of immunity indexes; in particular, leucocytes level, in the increase of the level of some classes of immunoglobuline in blood, of haemoglobin level, T- and B-lymphocytes level, as well as common unspecific resistance - lyzocymic, phagocytic and bactericidic activity. These results allow to suggest that the peat humic preparations show immunomodulative activity, influencing both on humoral and cel immunity links.

  1. Alternative to peat for Agaricus brasiliensis yield.

    PubMed

    Colauto, Nelson Barros; da Silveira, Adriano Reis; da Eira, Augusto Ferreira; Linde, Giani Andrea

    2010-01-01

    Casing layer is one of the most important components of Agaricus spp. production and it directly affects mushroom productivity, size and mass. The aim of this study was to evaluate potential raw materials as a casing layer and their effect on Agaricus brasiliensis productivity. Raw materials from Brazil with potential use were selected and characterized, and the most promising ones were tested as casing layers for mushroom yield. Evaluated raw materials included lime schist, vermiculite, eucalyptus sawdust, sand, São Paulo peat, Santa Catarina peat, subsoil and charcoal. Particle size, porosity and water absorption in relation to mushroom yield for casing layers were determined. Lime schist, an alternate casing layer to peat, is presented and the effects of the casing layer on the mushroom yield are discussed.

  2. Oxidative ratio (OR) of UK peats

    NASA Astrophysics Data System (ADS)

    Clay, G. D.; Worrall, F.; Masiello, C. A.

    2012-04-01

    The oxidative ratio (OR) is the amount of CO2 sequestered in the terrestrial biosphere for each mol of O2 produced. The OR governs the effectiveness of a terrestrial biome to mitigate the impact of anthropogenic CO2 emissions and it has been used to calculate the balance of terrestrial and oceanic carbon sinks across the globe. However, few studies have investigated the controls of the variability in OR. What factors affect OR - climate? Soil type? Vegetation type? N deposition? Land use? Land use change? Small shifts in OR could have important implications in the global partitioning of CO2 between the atmosphere, biosphere, and oceans. This study looks at peat soils (Histosols) from a series of sites representing a climatic transect across the UK. Duplicate peat cores were taken, along with samples of above-ground vegetation and litter, from sites in northern Scotland (Forsinard), southern Scotland (Auchencorth), northern England (Moor House; Thorne Moor) through the Welsh borders (Whixhall Moss) and Somerset levels (Westhay Moor) to Dartmoor and Bodmin Moor in the south west of England. Sub-samples of the cores were analysed for their CHNO concentrations using a Costech ECS 4010 Elemental combustion system. Using the method of Masiello et al. (2008), OR values could be calculated from these elemental concentrations. Initial results show that OR values of UK peats varied between 0.94 and 1.1 with a median value of 1.05 which similar to the median value of World soils but the range is at the more reduced end. There was significant variation between peat cores, even between peat cores on the same site and the peat showed significant reduction in OR with depth in the core.

  3. Emission factors for smouldering peat megafires

    NASA Astrophysics Data System (ADS)

    Hadden, Rory; Santamaria, Simon; Pironi, Paolo; Rein, Guillermo

    2016-04-01

    Smouldering wildfires occur in large deposits of peat across the globe in boreal and temperate regions. These fires are the most persistent fires on earth and consume large quantities of biomass which can take centuries or longer to regenerate. Recently large peat fires in Indonesia have caused significant health issues across a large geographic area in south east Asia. A similar event that occurred in 1997 was estimated to have released up to 13.7Gt of carbon to the atmosphere. Globally, the carbon stored in peatlands is greater than that stored in vegetation and is similar to that stored in the atmosphere. One of the major threats to these ecosystems is smouldering megafires which can be ignited easily in peat with the resulting fire persisting for extended periods of time (often many weeks or months). Given the potential impact on global carbon balances, it is essential to have accurate estimates of carbon emitted from these fires. Is is established that the emissions from any combustion process are strongly dependent on the combustion conditions these include the temperature (energy balance), availability of oxygen and the fuel composition. Because smouldering is a persistent form of combustion, it can occur over a wide range of conditions. This necessitates an understanding of emission factors linked to the burning dynamics. To allow for controlled, repeatable burning conditions across this range of conditions, a series of laboratory scale experiments were undertaken to identify the carbon dioxide, carbon monoxide and methane flux from samples of smouldering sphagnum moss peat. This peat is used as it has been extensively studied experimentally and numerically. By using repeatable experimental conditions delivered by the FM Global Fire Propagation Apparatus, the flux of CO, CO2 and methane can be linked to the smouldering fire dynamics. Smouldering in shallow fronts is represented by burning in ambient oxygen concentration while deep fronts are simulated using

  4. Properties and structure of raised bog peat humic acids

    NASA Astrophysics Data System (ADS)

    Klavins, Maris; Purmalis, Oskars

    2013-10-01

    Humic substances form most of the organic components of soil, peat and natural waters, and their structure and properties differ very much depending on their source. The aims of this study are to characterize humic acids (HAs) from raised bog peat, to evaluate the homogeneity of peat HAs within peat profiles, and to study peat humification impact on properties of HAs. A major impact on the structure of peat HAs have lignin-free raised bog biota (dominantly represented by bryophytes of different origin). On diagenesis scale, peat HAs have an intermediate position between the living organic matter and coal organic matter, and their structure is formed in a process in which more labile structures (carbohydrates, amino acids, etc.) are destroyed, while thermodynamically more stable aromatic and polyaromatic structures emerge as a result of abiotic synthesis. However, in comparison with soil, aquatic and other HAs, aromaticity of peat HAs is much lower. Comparatively, the raised bog peat HAs are at the beginning of the transformation process of living organic matter. Concentrations of carboxyl and phenolic hydroxyl groups change depending on the peat age and decomposition degree from where HAs have been isolated, and carboxylic acidity of peat HAs increases with peat depth and humification degree.

  5. [Application of the differential absorption UV-VIS spectrum to assay some of humic compounds in therapeutic peats].

    PubMed

    Drobnik, Michał; Latour, Teresa

    2009-01-01

    Delineated were differential 4th degree absorption spectrum UV-VIS range for standardized humid acids produced by "Fluka". These acids were separated through selective extraction (acid, alcoholic, alkaline). Determined was wavelength for which distinct, well separated, symmetrical peaks characteristic for particular compounds were found. The similar procedure were applied to separate the same sort of acids extracted from 4 Polish peat deposits. Certified are the presence of hymatomelanoic acid, fulvic acid, humic acid in examined peat of low type. These acids occurred in different quantity and proportions.

  6. Peat formation concentrates arsenic within sediment deposits of the Mekong Delta

    NASA Astrophysics Data System (ADS)

    Stuckey, Jason W.; Schaefer, Michael V.; Kocar, Benjamin D.; Dittmar, Jessica; Pacheco, Juan Lezama; Benner, Shawn G.; Fendorf, Scott

    2015-01-01

    Mekong River Delta sediment bears arsenic that has been released to groundwater under anaerobic conditions over the past several thousand years. The oxidation state, speciation, and distribution of arsenic and the associated iron bearing phases are crucial determinants of As reactivity in sediments. Peat from buried mangrove swamps in particular may be an important host, source, or sink of arsenic in the Mekong Delta. The total concentration, speciation, and reactivity of arsenic and iron were examined in sediments in a Mekong Delta wetland by X-ray fluorescence spectrometry (XRF), X-ray absorption spectroscopy (XAS), and selective chemical extractions. Total solid-phase arsenic concentrations in a peat layer at a depth of 6 m below ground increased 10-fold relative to the overlying sediment. Extended X-ray absorption fine structure (EXAFS) spectroscopy revealed that arsenic in the peat was predominantly in the form of arsenian pyrite. Arsenic speciation in the peat was examined further at the micron-scale using μXRF and μX-ray absorption near-edge structure (XANES) spectroscopy coupled with principal component analysis. The multiple energy μXRF mapping and μXANES routine was repeated for both iron and sulfur phase analyses. Our μXRF/μXANES analyses confirm arsenic association with pyrite - a less reactive host phase than iron (hydr)oxides under anaerobic conditions. The arsenian pyrite likely formed upon deposition/formation of the peat in a past estuarine environment (∼5.5 ka BP), a process that is not expected under current geochemical conditions. Presently, arsenian pyrite is neither a detectable source nor a sink for aqueous arsenic in our sediment profile, and under present geochemical conditions represents a stable host of As under the reducing aquifer conditions of the Mekong Delta. Furthermore, organic carbon within the peat is unable to fuel Fe(III) reduction, as noted by the persistence of goethite which can be reduced microbially with the

  7. The Lipid Biomarker Holocene Paleoclimate Record of West China in the Zoige-Hongyuan Peat Deposit

    NASA Astrophysics Data System (ADS)

    Zhou, W.; Zheng, Y.; Meyers, P.; Xie, S.

    2006-12-01

    Paleoclimate reconstructions based on lipid biomarkers from peat bogs are relatively uncommon, although this approach has been widely applied to lake sediments where it yields histories of climate-related changes in types of vegetation and organic matter preservation. We describe stratigraphic patterns in peat lipid biomarker distributions extracted from a well-dated peat core from the Zoige-Hongyuan peat bog. The bog is on the Qinghai-Xizang Plateau of west China on the northeast edge of the Tibetan Plateau and has accumulated a continuous deposit of peat during the latest Pleistocene and the Holocene. A period of warmer climate corresponding to the Holocene Optimum between 9 ka to 5 ka is evident in greater alterations of n-alkanoic acids and n-alkanols and in the appearance of biomarkers diagnostic of greater microbial activity. Changes in local precipitation that modified the water level of the peat bog are indicated by increases in the proportions of C23 and C25 n-alkanes that are mainly derived from submerged/floating plants. Alternations in submergent and emergent plant n-alkane proxies reveal millennial scale rises and falls of the bog water level in the Tibetan Plateau, thereby reflecting variations in Asian monsoon precipitation during the Holocene. Major low water level events occurred around 12.6, 11.3, 10.7, 9.4, 8.3, 6.0, 4.5, 3.1, 2.1, and 1.0 ka. These events correlate well with cold-dry events recorded in same region by other climatic proxies. These results reflect Holocene instability in the Asian monsoon system. Our results indicate that millennial-scale variability in precipitation is more sensitive than temperature in reflecting Asian monsoon climatic dynamics on the Tibetan Plateau.

  8. Evaluation of diverse methods for measuring humification index of ombrotrophic peats

    NASA Astrophysics Data System (ADS)

    Zaccone, Claudio; Plaza, Cesar; Ciavatta, Claudio; Miano, Teodoro M.; Shotyk, William

    2014-05-01

    Structural changes of organic matter occurring in peat during the humification process have been generally evaluated by indirect measurements of the degree of humification. Besides traditional and (more or less) objective and reproducible methods, such as the von Post humification scale or the visual estimation of the relative proportions of fiber structures, several other methods have been published and a wide variety of geochemical, spectroscopic and molecular techniques used in humification studies. Among them, thermogravimetric methods, the relative proportion of carboxyl and hydroxyl groups, atomic ratios, absorbance measurements of alkaline peat extracts, the abundance of free radicals, and the fluorescence properties of bulk peat and corresponding humic macromolecules have been used as a descriptor of the humification process, often providing contrasting results. To answer fundamental questions about humification, and to be able to compare data, it is very important to determine what is the best humification index able to quantify the humification degree and the evolution of peat humification along vertical profiles. The possibility to better understand the extent to which bogs may serve as reliable geochemical archives is of paramount importance, especially considering that ombrotrophic cores from bogs have been and are often used to reconstruct environmental changes over time (decades to millennia). Nine bogs from four continents, and 4-5 peat samples from each core collected at different depths, have been selected for this study. Then, each peat sample has been tested using several physical, chemical and spectroscopic approaches in order to identify the simplest, most valid and cost-effective method to be applied in geochemical and paleoenvironmental studies.

  9. Nitrosation and Nitration of Fulvic Acid, Peat and Coal with Nitric Acid

    PubMed Central

    Thorn, Kevin A.; Cox, Larry G.

    2016-01-01

    Nitrohumic acids, produced from base extraction of coals and peats oxidized with nitric acid, have received considerable attention as soil ammendments in agriculture. The nitration chemistry however is incompletely understood. Moreover, there is a need to understand the reaction of nitric acid with natural organic matter (NOM) in general, in the context of a variety of environmental and biogeochemical processes. Suwannee River NOM, Suwannee River fulvic acid, and Pahokee Peat fulvic acid were treated with 15N-labeled nitric acid at concentrations ranging from 15% to 22% and analyzed by liquid and solid state 15N NMR spectroscopy. Bulk Pahokee peat and Illinois #6 coal were also treated with nitric acid, at 29% and 40% respectively, and analyzed by solid state 15N NMR spectroscopy. In addition to nitro groups from nitration of aromatic carbon, the 15N NMR spectra of all five samples exhibited peaks attributable to nitrosation reactions. These include nitrosophenol peaks in the peat fulvic acid and Suwannee River samples, from nitrosation of phenolic rings, and N-nitroso groups in the peat samples, from nitrosation of secondary amides or amines, the latter consistent with the peat samples having the highest naturally abundant nitrogen contents. Peaks attributable to Beckmann and secondary reactions of the initially formed oximes were present in all spectra, including primary amide, secondary amide, lactam, and nitrile nitrogens. The degree of secondary reaction product formation resulting from nitrosation reactions appeared to correlate inversely with the 13C aromaticities of the samples. The nitrosation reactions are most plausibly effected by nitrous acid formed from the reduction of nitric acid by oxidizable substrates in the NOM and coal samples. PMID:27175784

  10. Nitrosation and nitration of fulvic acid, peat and coal with nitric acid

    USGS Publications Warehouse

    Thorn, Kevin A.; Cox, Larry G.

    2016-01-01

    Nitrohumic acids, produced from base extraction of coals and peats oxidized with nitric acid, have received considerable attention as soil ammendments in agriculture. The nitration chemistry however is incompletely understood. Moreover, there is a need to understand the reaction of nitric acid with natural organic matter (NOM) in general, in the context of a variety of environmental and biogeochemical processes. Suwannee River NOM, Suwannee River fulvic acid, and Pahokee Peat fulvic acid were treated with 15N-labeled nitric acid at concentrations ranging from 15% to 22% and analyzed by liquid and solid state 15N NMR spectroscopy. Bulk Pahokee peat and Illinois #6 coal were also treated with nitric acid, at 29% and 40% respectively, and analyzed by solid state 15N NMR spectroscopy. In addition to nitro groups from nitration of aromatic carbon, the 15N NMR spectra of all five samples exhibited peaks attributable to nitrosation reactions. These include nitrosophenol peaks in the peat fulvic acid and Suwannee River samples, from nitrosation of phenolic rings, and N-nitroso groups in the peat samples, from nitrosation of secondary amides or amines, the latter consistent with the peat samples having the highest naturally abundant nitrogen contents. Peaks attributable to Beckmann and secondary reactions of the initially formed oximes were present in all spectra, including primary amide, secondary amide, lactam, and nitrile nitrogens. The degree of secondary reaction product formation resulting from nitrosation reactions appeared to correlate inversely with the 13C aromaticities of the samples. The nitrosation reactions are most plausibly effected by nitrous acid formed from the reduction of nitric acid by oxidizable substrates in the NOM and coal samples.

  11. The Limits to Peat Bog Growth

    NASA Astrophysics Data System (ADS)

    Clymo, R. S.

    1984-01-01

    Not less than 2% of the Earth's land surface is peat-covered, so it is important to try to understand the dynamics of peat accumulation. Peat-forming systems (mires) accumulate peat because conditions within them impede the decay of the plant material produced by their surface vegetation. This paper concerns the rate of peat production and some unexpected consequences of the processes of decay. These consequences are likely to be of interest to those concerned with mire ecology and with the history of vegetation during Flandrian times. Most peat-forming systems consist of two layers: an upper 10-50 cm deep aerobic layer of high hydraulic conductivity, the acrotelm, in which the rate of decay is relatively high; and a thicker, usually anaerobic, lower layer, the catotelm, of low conductivity and with a much lower rate of decay. Plant structure at the base of the acrotelm collapses as a consequence of aerobic decay, and the hydraulic conductivity consequently decreases. As long as precipitation continues the water table therefore rises to this level, thus engulfing material at the base of the acrotelm. The rate, p_c, of this input to the catotelm is exactly analogous to the rate, p_a, of input to the acrotelm i.e. of primary productivity of the vegetation. During passage through the acrotelm the peat becomes richer in the more slowly decaying components. The depth of, and the time for transit through, the acrotelm thus control p_c. The catotelm, however, usually forms much the largest part of the peat mass. Selective decay may continue in the catotelm. The specific composition of the peat thus becomes a progressively poorer indicator of the surface vegetation that formed it, and to a degree that is not generally realized: reconstructions of the past surface vegetation may become very inaccurate. If p_c were constant and there were no decay in the catotelm then for the centre of a peat bog the profile of age against depth (measured as cumulative mass below the surface

  12. Fate of silicate minerals in a peat bog

    USGS Publications Warehouse

    Bennett, Philip C.; Siegel, Donald I.; Hillier, Barbara M.; Glaser, Paul H.

    1991-01-01

    An investigation of silicate weathering in a Minnesota mire indicates that quartz and aluminosilicates rapidly dissolve in anoxic, organic-rich, neutral- pH environments. Vertical profiles of pH, dissolved silicon, and major cations were obtained at a raised bog and a spring fen and compared. Profiles of readily extractable silicon, diatom abundance, ash mineralogy, and silicate surface texture were determined from peat cores collected at each site.In the bog, normally a recharge mound, dissolved silicon increases with depth as pH increases, exceeding the background silicon concentration by a factor of two. Silicate grain surfaces, including quartz, are chemically etched at this location, despite being in contact with pore water at neutral pH with dissolved silicon well above the equilibrium solubility of quartz. The increasing silica concentrations at circum-neutral pH are consistent with a system where silicate solubility is influenced by silica-organic-acid complexes. Silica-organic-acid complexes therefore may be the cause of the almost complete absence of diatoms in decomposed peat and contribute to the formation of silica-depleted underclays commonly found beneath coal.

  13. The importance of pH and sand substrate in the revegetation of saline non-waterlogged peat fields.

    PubMed

    Montemayor, Marilou B; Price, Jonathan; Rochefort, Line

    2015-11-01

    A partially peat-extracted coastal bog contaminated by seawater was barren and required revegetation as a wetland. Peat fields were rectangular in shape, cambered in cross-section profile, and separated by drainage ditches. Common to all peat fields were symmetrical patterns in micro-topography with slopes between differences in elevation. Saline non-waterlogged slopes of ∼5% occurred as a symmetrical pair on each side of the crest of the cambered profile, at one end of each peat field. Three rows were laid across this slope (Top, Middle, and Bottom rows) and transplanted with naturally-growing plant species with their sand substrate, in three experiments, and grown for a year. In the Spartina pectinata experiment, bare root stem sections were also planted. Another experiment was conducted to determine changes in the characteristics of a volume of sand when incubated in saline peat fields. We found the salinity of peat increased with moisture downslope, and pH decreased with increase in salinity. S. pectinata grew best when planted with its sand substrate compared with bare root stem section, and when planted in Bottom rows. Juncus balticus had excellent growth in all rows. Unexpectedly, Festuca rubra that was inconspicuous beneath the J. balticus canopy in the natural donor site grew densely within the J. balticus sods. Agrostis stolonifera grew well but seemed to show intolerance to the surrounding acidic peat by curling up its stolons. The pH of the incubated sand volume was much higher than the surrounding peat. These studies suggest that recognition of plant niches and pH manipulation are important in the revegetation of disturbed Sphagnum peatlands that are found abundantly in the northern hemisphere. Results are also relevant to the reclamation of other disturbed lands.

  14. Ombrotrophic peat bogs are not suited as natural archives to investigate the historical atmospheric deposition of perfluoroalkyl substances.

    PubMed

    Dreyer, Annekatrin; Thuens, Sabine; Kirchgeorg, Torben; Radke, Michael

    2012-07-17

    As ombrotrophic peat bogs receive only atmospheric input of contaminants, they have been identified as suitable natural archives for investigating historical depositions of airborne pollutants. To elucidate their suitability for determining the historical atmospheric contamination with perfluoroalkyl substances (PFAS), two peat cores were sampled at Mer Bleue, a bog located close to Ottawa, Canada. Peat cores were segmented, dried, and analyzed in duplicate for 25 PFASs (5 perfluororalkyl sulfonates (PFSAs), 13 perfluoroalkyl carboxylates (PFCAs), 7 perfluororalkyl sulfonamido substances). Peat samples were extracted by ultrasonication, cleaned up using a QuEChERS method, and PFASs were measured by HPLC-MS/MS. Twelve PFCAs and PFSAs were detected regularly in peat samples with perfluorooctane sulfonate (85-655 ng kg(-1)), perfluorooctanoate (150-390 ng kg(-1)), and perfluorononanoate (45-320 ng kg(-1)) at highest concentrations. Because of post depositional relocation processes within the peat cores, true or unbiased deposition fluxes (i.e., not affected by post depositional changes) could not be calculated. Apparent or biased deposition rates (i.e., affected by post depositional changes) were lower than measured/calculated deposition rates for similar urban or near-urban sites. Compared to PFAS production, PFAS concentration and deposition maxima were shifted about 30 years toward the past and some analytes were detected even in the oldest segments from the beginning of the 20th century. This was attributed to PFAS mobility in the peat profile. Considerable differences were observed between both peat cores and different PFASs. Overall, this study demonstrates that ombrotrophic bogs are not suited natural archives to provide authentic and reliable temporal trend data of historical atmospheric PFAS deposition.

  15. Development of a new peat-based oil sorbent using peat pyrolysis.

    PubMed

    Klavins, Maris; Porshnov, Dmitry

    2013-01-01

    The growing use and transport of crude oil and oil products has led to increasing numbers of oil spillages of various scales. Oil sorbents have been extensively used for remediation of the consequences of such accidents. The aim of this study is to investigate the possible use of peat and its thermal treatment products for oil sorption. Peat as an oil sorbent has poor buoyancy characteristics, relatively low oil sorption capacity and low hydrophobicity. However, thermal treatment (low-temperature pyrolysis and synthesis of peat-based activated coal) helps to significantly improve its sorptive characteristics. Peat is a potential material for oil sorption because it has such advantages as low cost, biodegradability and relatively high parameters of specific surface area and porosity. The processes and structural changes taking place during low-temperature pyrolysis have been studied by means of IR spectroscopy, thermogravimetry and scanning electron microscopy.

  16. Changes in vegetation, peat properties and peat accumulation in Swedish peatlands as revealed by archive data.

    NASA Astrophysics Data System (ADS)

    Schoning, Kristian; Sohlenius, Gustav

    2016-04-01

    In this investigation we have studied patterns in peat accumulation and changes in mire status since the early 1900s for two areas in Sweden. In the early 1900s the Geological Survey of Sweden collected a vast amount of peat and peatland data, including information on vegetation and land-use. We have used this archive data to evaluate changes in mire vegetation, mire wetness and surface peat properties, rates of peat accumulation, succession in young wetlands and the effects of cultivation on peatlands. In total 156 mires in an uplift area of eastern middle Sweden were included in the data-set, including both pristine mires and peatlands used for agricultural purposes. In this area new peatlands have continuously been formed during the past 7 000 years making it possible to evaluate changes in peat accumulation over time. The other study area is situated in the south Swedish Uplands where we have revisited some larger bogs. The results from our investigation show that many of the peatlands have underwent major changes since the early 1900s. In most of the small peatlands we have found important changes in vegetation where mire vegetation has been replaced by nutrient demanding and/or dry species flora while the tree stand on large mires in south Sweden have increased. In some mires humification has increased in the uppermost peat-layers and the mire surface have become drier compared to the early 1900s. In eastern middle Sweden there are indications that the peat accumulation is lower 0,5 mm/year in older peatlands compared with younger ones 1,2 mm/year, although the mire vegetation in the older peatlands is dominated by sphagnum. The peat depth of the cultivated mires in this area shows a mean decrease of 40 cm since the early 1900s.

  17. Feasibility of a peat biogasification process

    NASA Astrophysics Data System (ADS)

    Buivid, M. G.; Wise, D. L.; Rader, A. M.; McCarty, P. L.; Owen, W. F.

    1980-07-01

    The feasibility of a two-stage biogasification process for the conversion of peat reserves, the energy content of which in the United States is greater than that of uranium, shale oil or petroleum and natural gas combined, into pipeline-quality methane is investigated. Samples of wet-harvested reed-sedge peat were pretreated in alkaline and nonalkaline conditions in the presence and absence of oxidation in order to determine the most favorable conditions for the conversion of cellulosic and lignaceous fractions to water-soluble, fermentable compounds, and the resulting products were subjected to anaerobic fermentation to methane. Conversion efficiencies obtained reveal that up to 26% of the initial heat content of peat was converted to methane when alkaline heat pretreatment was employed. Analysis of the process parameters by a computer model to determine equipment sizes, mass and energy balances and costs indicates that for a 79,200 GJ/day plant the total capital requirement would be $323,000,000, annual operating costs would be $44,000,000 and average SNG cost would be $3.16/GJ, assuming a 90% stream factor with a delivered peat slurry costing $0.0033/kg.

  18. CO2 Efflux from Cleared Mangrove Peat

    PubMed Central

    Lovelock, Catherine E.; Ruess, Roger W.; Feller, Ilka C.

    2011-01-01

    Background CO2 emissions from cleared mangrove areas may be substantial, increasing the costs of continued losses of these ecosystems, particularly in mangroves that have highly organic soils. Methodology/Principal Findings We measured CO2 efflux from mangrove soils that had been cleared for up to 20 years on the islands of Twin Cays, Belize. We also disturbed these cleared peat soils to assess what disturbance of soils after clearing may have on CO2 efflux. CO2 efflux from soils declines from time of clearing from ∼10 600 tonnes km−2 year−1 in the first year to 3000 tonnes km2 year−1 after 20 years since clearing. Disturbing peat leads to short term increases in CO2 efflux (27 umol m−2 s−1), but this had returned to baseline levels within 2 days. Conclusions/Significance Deforesting mangroves that grow on peat soils results in CO2 emissions that are comparable to rates estimated for peat collapse in other tropical ecosystems. Preventing deforestation presents an opportunity for countries to benefit from carbon payments for preservation of threatened carbon stocks. PMID:21738628

  19. Equivalent weight of humic acid from peat

    USGS Publications Warehouse

    Pommer, A.M.; Breger, I.A.

    1960-01-01

    By means of discontinuous titration, the equivalent weight of humic acid isolated from a peat was found to increase from 144 to 183 between the third and fifty-second day after the humic acid was dissolved. Infra-red studies showed that the material had probably condensed with loss of carbonyl groups. ?? 1960.

  20. INFLUENCE OF PEAT ON FENTON OXIDATION

    EPA Science Inventory

    A diagnostic probe was used to estimate the activity of Fenton-derived hydroxyl radicals (@OH), reaction kinetics, and oxidation efficiency in batch suspensions comprised of silica sand, crushed goethite ("-FeOOH) ore, peat, and H2O2 (0.13 mM). A simple method of kinetic analysi...

  1. Multiple factors drive regional agricultural abandonment.

    PubMed

    Osawa, Takeshi; Kohyama, Kazunori; Mitsuhashi, Hiromune

    2016-01-15

    An understanding of land-use change and its drivers in agroecosystems is important when developing adaptations to future environmental and socioeconomic pressures. Agricultural abandonment occurs worldwide with multiple potentially positive and negative consequences; however, the main factors causing agricultural abandonment in a country i.e., at the macro scale, have not been identified. We hypothesized that socio-environmental factors driving agricultural abandonment could be summarized comprehensively into two, namely "natural" and "social", and the relative importance of these differs among regions. To test this postulate, we analyzed the factors currently leading to agricultural abandonment considering ten natural environment variables (e.g., temperature) and five social variables (e.g., number of farmers) using the random forest machine learning method after dividing Japan into eight regions. Our results showed that agricultural abandonment was driven by various socio-environmental factors, and the main factors leading to agricultural abandonment differed among regions, especially in Hokkaido in northern Japan. Hokkaido has a relatively large area of concentrated farmland, and abandonment might have resulted from the effectiveness of cultivation under specific climate factors, whereas the other regions have relatively small areas of farmland with many elderly part-time farmers. In such regions, abandonment might have been caused by the decreasing numbers of potential farmers. Thus, two different drivers of agricultural abandonment were found: inefficient cultivation and decreasing numbers of farmers. Therefore, agricultural abandonment cannot be prevented by adopting a single method or policy. Agricultural abandonment is a significant problem not only for food production but also for several ecosystem services. Governments and decision-makers should develop effective strategies to prevent further abandonment to ensure sustainable future management of agro-ecosystems.

  2. Peat resource estimation in Minnesota: Final report

    SciTech Connect

    Not Available

    1987-06-01

    The Minnesota Department of Natural Resources (DNR) completed and published reconnaissance-level investigations for four areas in Minnesota. Approximately 1,061,000 ha (2,622,000 ac) of peatland were surveyed in Aitkan, northern Beltrami Koochiching Lake of the Woods, and southwestern St. Louis counties. Within these areas, approximately 812,000 ha (2,007,000 ac) of peatland are administratively available. And, based on DOE's criteria, approximately 276,000 ha (681,900 ac) of peatland are fuel-grade resources. Calculated in terms of the higher heating value, the energy value of these deposits is 16.47 quads. Reconnaissance investigations were completed for Carlton and Itasca counties and portions of Cass, Lake, and St. Louis counties, but because of the minimal interest in fuel peat, reports were not published. These investigations examined approximately 346,600 ha (856,500 ac) of peatland, of which 191,940 ha (474,280 ac) are administratively available. The results of the investigations are recorded on file maps and stored in the state's computer system. The DNR completed four detailed investigations at peatland sites thought to have high fuel peat potential. As a pilot project, peat sods were produced from the Fens Peatland. Peatland surveys for Boise Cascade, International Falls and the Hibbing Public Utility have produced encouraging results in conjunction with modeling that projected fuel costs. The cost of milled peat production in Minnesota can be competitive with the cost of western coal in certain production scenarios. The principles in the study have plans to continue engineering studies on conversion to fuel peat. 32 refs., 5 figs. 17 tabs.

  3. Biogeochemistry of Metalliferous Peats: Sulfur Speciation and Depth Distributions of dsrAB Genes and Cd, Fe, Mn, S, and Zn in Soil Cores

    SciTech Connect

    Martinez,C.; Yanez, C.; Yoon, S.; Bruns, M.

    2007-01-01

    Spatial relationships between concentrations of Cd, Fe, Mn, S, and Zn and bacterial genes for dissimilatory sulfate reduction were studied in soils of the Manning peatland region in western New York. Peat cores were collected within a field exhibiting areas of Zn phytotoxicity, and pH and elemental concentrations were determined with depth. The oxidation states of S were estimated using S-XANES spectroscopy. Soil microbial community DNA was extracted from peat soils for ribosomal RNA intergenic spacer analysis (RISA) of diversity profiles with depth. To assess the presence of sulfate-reducing microorganisms (SRM), DNA extracts were also used as templates for PCR detection of dsrAB genes coding for dissimilatory (bi)sulfite reductase. Elemental distributions, S redox speciation, and detection of dsrAB genes varied with depth and water content. The pH of peat soils increased with depth. The highest concentrations of Zn, Cd, and S occurred at intermediate depths, whereas Mn concentrations were highest in the topmost peat layers. Iron showed a relatively uniform distribution with depth. Concentrations of redox sensitive elements, S and Mn, but not Fe, seemed to respond to variations in water content and indicated vertical redox stratification in peat cores where topmost peats were typically acidic and oxidizing and deeper peats were typically circumneutral and reducing. Even then, S-XANES analyses showed that surface peats contained >50% of the total S in reduced forms while deep peats contained generally <5% of the total S in oxidized forms. While bacterial RISA profiles of the peats were diverse, dsrAB gene detection followed redox stratification chemistry closely. For the most part, dsrAB genes were detected in deeper peats, where S accumulation was evident, while they were not detected in topmost peat layers where Mn accumulation indicated oxic conditions. Combined chemical, spectroscopic, and microbiological analyses indicated that prolonged exposure to dry

  4. Biogeochemistry of metalliferous peats: sulfur speciation and depth distributions of dsrAB genes and Cd, Fe, Mn, S, and Zn in soil cores.

    PubMed

    Martínez, Carmen Enid; Yáñez, Carolina; Yoon, Soh-Joung; Bruns, Mary Ann

    2007-08-01

    Spatial relationships between concentrations of Cd, Fe, Mn, S, and Zn and bacterial genes for dissimilatory sulfate reduction were studied in soils of the Manning peatland region in western New York. Peat cores were collected within a field exhibiting areas of Zn phytotoxicity, and pH and elemental concentrations were determined with depth. The oxidation states of S were estimated using S-XANES spectroscopy. Soil microbial community DNA was extracted from peat soils for ribosomal RNA intergenic spacer analysis (RISA) of diversity profiles with depth. To assess the presence of sulfate-reducing microorganisms (SRM), DNA extracts were also used as templates for PCR detection of dsrAB genes coding for dissimilatory (bi)-sulfite reductase. Elemental distributions, S redox speciation, and detection of dsrAB genes varied with depth and water content. The pH of peat soils increased with depth. The highest concentrations of Zn, Cd, and S occurred at intermediate depths, whereas Mn concentrations were highest in the topmost peat layers. Iron showed a relatively uniform distribution with depth. Concentrations of redox sensitive elements, S and Mn, but not Fe, seemed to respond to variations in water content and indicated vertical redox stratification in peat cores where topmost peats were typically acidic and oxidizing and deeper peats were typically circumneutral and reducing. Even then, S-XANES analyses showed that surface peats contained >50% of the total S in reduced forms while deep peats contained generally <5% of the total S in oxidized forms. While bacterial RISA profiles of the peats were diverse, dsrAB gene detection followed redox stratification chemistry closely. For the most part, dsrAB genes were detected in deeper peats, where S accumulation was evident, while they were not detected in topmost peat layers where Mn accumulation indicated oxic conditions. Combined chemical, spectroscopic, and microbiological analyses indicated that prolonged exposure to dry

  5. Late-Holocene Climate Change and Human Impact; Palaeoecological Evidence From Peat Deposits in Sweden and Germany

    NASA Astrophysics Data System (ADS)

    van der Linden, M.; van Geel, B.

    2006-12-01

    With the aim of investigating the effects of climate change and human impact on vegetation and carbon accumulation, we took peat cores of ca. 1 meter depth from four raised bogs situated on a North-South transect, at intervals of c. 500 km, Umeå in Sweden to Angermünde in northern Germany. A number of analyses were conducted (plant macrofossils, pollen/non-pollen microfossils, colorimetric humification, carbon/nitrogen ratios, bulk densities, loss on ignition), and 14C wiggle-match dating was applied to obtain a fine-resolution chronology. The cores from the northern and southern site encompass ca. 1000 years of vegetation history, showing evidence for the end of the Medieval Warm Period (MWP), the Little Ice Age (LIA) and the twentieth century warming. The middle Swedish and German sites are high resolution records of the last 400 years. The end of the MWP and the cooling at the start of the LIA are reflected by a decline in thermophilous tree species. Changes in the macrofossil composition may also represent changes in climate. Shifts in Sphagnum composition, the dominant peat former, reflect changes in precipitation. Evidence for wet conditions and increased carbon accumulation is found during the Little Ice Age. Human activities affected the peat bog and the surrounding vegetation. Sweden suffered many wars during the 16^{th} and 17^{th} century, which caused a decline in population density. Diseases such as the plague and famines caused by crop failures fastened the population decrease. As a consequence, agricultural land was abandoned, resulting in reforestation by Betula. Later, in the modern part of the records, land-use change and planting of trees comprised the major regional vegetation changes. In the southern site, human activities (drainage to facilitate peat cutting) affected the raised bog itself. A part of the peat archive was lost owing to secondary decomposition which resulted in very low carbon accumulation.

  6. Peat resources of North Carolina. A progress report

    SciTech Connect

    Ingram, R.L.; Otte, L.J.

    1980-10-01

    This progress report has a summary of the final report on the Light Ground Pocosin work. It is the description of the location of peat deposits, the types of peat found, and their composition and heating values. On other pocosin peat, field data are still being collected on the Pamlimarle peninsula, Dismal Swamp, and Croatan Forest. Preliminary estimates show that there are 360 square miles containing 210 million tons of moisture-free peat in the Pamlimarle peninsula, which is the largest peat reserve in North Carolina. Most of this peat is moderately to highly decomposed with low ash content and with heating values averaging over 10,000 Btu/lb. The Dismal Swamp has about 100 square miles of peatland containing 50 to 75 million tons of moisture-free peat with average thickness of 4 to 5 ft. The Croatan Forest is estimated to have 40 to 50 square miles of peatland containing 25 to 30 million tons of moisture-free peat with an average thickness of 4 to 5 ft. Limited field work has discovered some peat deposits of unknown extent along the lower parts of the Chowan, Roanoke, and Cape Fear rivers. Floodplain peats are often covered by several feet of alluvial sand and mud and often grade laterally into alluvial sand and clays. Ash content is higher than in the pocosin peats. Preliminary work on Carolina Bay Peats shows that many of these bays contain high quality peat up to a maximum thickness of 15 ft. Ash content averages about 4%, and the heating value averages about 10,000 Btu/lb. New figures in this report are two graphs which show the relation of moisture content to bulk density, and the relation of bulk density to depth of selected peats.

  7. Peat resources of North Carolina. A progress report

    SciTech Connect

    Ingram, R.L.; Otte, L.J.

    1980-10-01

    This progress report has a summary of the final report on the Light Ground Pocosin work. It is the description of the location of peat deposits, the types of peat found, and their composition and heating values. On other pocosin peat, field data are still being collected on the Pamlimarle Peninsula, Dismal Swamp, and Croatan Forest. Preliminary estimates show that there are 360 square miles containing 210 million tons of moisture-free peat in the Pamlimarle peninsula, which is the largest peat reserve in North Carolina. Most of this peat is moderately to highly decomposed with low ash content and with heating values averaging over 10,000 Btu/lb. The Dismal Swamp has about 100 square miles of peatland conaining 50 to 75 million tons of moisture-free peat with average thickness of 4 to 5 ft. The Croatan Forest is estimated to have 40 to 50 square miles of peatland containing 25 to 30 million tons of moisture-free peat with an average thickness of 4 to 5 ft. Limited field work has discovered some peat deposits of unknown extent along the lower parts of the Chowan, Roanoke, and Cape Fear rivers. Floodplain peats are often covered by several feet of alluvial sand and mud and often grade laterally into alluvial sand and clays. Ash content is higher than in the pocosin peats. Preliminary work on Carolina Bay Peats shows that many of these bays contain high quality peat up to a maximum thickness of 15 ft. Ash content averages about 4%, and the heating value averages about 10,000 Btu/lb. New figures in this report are two graphs which show the relation of moisture content to bulk density, and the relation of bulk density to depth of selected peats.

  8. Rapid development of an unusual peat-accumulating ecosystem in the Chilean Altiplano

    NASA Astrophysics Data System (ADS)

    Earle, Lisa R.; Warner, Barry G.; Aravena, Ramon

    2003-01-01

    Stratigraphic relationships, radiocarbon dating, sediment and peat characteristics, and rates of peat and carbon accumulation from a soligenous peatland, or "bofedal," in the Chilean Altiplano shows the peatland to be unusually young, dynamic, and sensitive to environmental changes. The site lies in the National Park Nevado de Tres Cruces in the puna desert grassland at an elevation of 4300 m a.s.l. Eight peat cores were extracted from a 1.75-km transect yielding a maximum of 3.6 m of organic sediment. Organic matter began to accumulate 1700-1100 cal yr B.P. under a progressively arid local climate, after a period when regional climate is believed to have been more humid than at present. Areas of greater relief and better drainage in the valley bottom eventually fostered the growth of a riparian cushion plant community after water flowing down the valley began to diminish. This led to rapid lateral expansion of the riparian peatland communities over open water in topographic depressions at a rate heretofore unprecedented in the peatland literature. It appears that development of the peatland has been encouraged by autoregulation of internal hydrology. The drainage impediment created by organic mass accumulation in lower-relief areas probably reduced the amount of water arriving at the lower reaches of the peatland. These areas have become progressively drier and have since died and oxidized. Through endogenous peat accumulation and a concomitant drainage impediment, the ecosystem has been migrating upstream over the past 50 years.

  9. 32 CFR 636.31 - Abandoned vehicles.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 32 National Defense 4 2012-07-01 2011-07-01 true Abandoned vehicles. 636.31 Section 636.31... CRIMINAL INVESTIGATIONS MOTOR VEHICLE TRAFFIC SUPERVISION (SPECIFIC INSTALLATIONS) Fort Stewart, Georgia § 636.31 Abandoned vehicles. (a) Any MP or DOD police officer who finds or has knowledge of a...

  10. 32 CFR 636.31 - Abandoned vehicles.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 32 National Defense 4 2013-07-01 2013-07-01 false Abandoned vehicles. 636.31 Section 636.31... CRIMINAL INVESTIGATIONS MOTOR VEHICLE TRAFFIC SUPERVISION (SPECIFIC INSTALLATIONS) Fort Stewart, Georgia § 636.31 Abandoned vehicles. (a) Any MP or DOD police officer who finds or has knowledge of a...

  11. 32 CFR 636.31 - Abandoned vehicles.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 32 National Defense 4 2014-07-01 2013-07-01 true Abandoned vehicles. 636.31 Section 636.31... CRIMINAL INVESTIGATIONS MOTOR VEHICLE TRAFFIC SUPERVISION (SPECIFIC INSTALLATIONS) Fort Stewart, Georgia § 636.31 Abandoned vehicles. (a) Any MP or DOD police officer who finds or has knowledge of a...

  12. Evolution of abandoned underground hardrock mine closures by the Texas abandoned mine land reclamation program

    SciTech Connect

    Rhodes, M.J.

    1997-12-31

    The Texas Abandoned Mine Land (AML) Reclamation program began investigating, designing and implementing hard rock abandoned underground mine closures, after a young boy fell to his death in an abandoned mine opening in 1982. This paper discusses the evolution of abandoned hard rock mine closures in west Texas, by the Texas AML program in response to the development of abandoned underground mine resource information. Case histories are presented of the Texas AML program`s efforts in west Texas including: mine history summaries; site characterization, environmental assessment; design and construction planning considerations, and construction cost information.

  13. Lifting the Humic Veil: A Novel Approach to Quantitating Occluded Iron in Peat Porewater

    NASA Astrophysics Data System (ADS)

    Veverica, T. J.; Kane, E. S.; Marcarelli, A. M.; Green, S. A.

    2014-12-01

    Anaerobic conditions common in peatlands lead microbes to reduce alternative electron acceptors for respiration in the order of their energetic yield: nitrate, manganese, ferric iron (Fe[III]), sulfate, and CO2. Many studies of peatland respiration report high CO2 fluxes that cannot be completely explained by measured pathways of microbial metabolism: it appears that an unquantified pool of electron acceptors is driving respiration and the efflux of CO2. The notion that undetected iron reduction may be an important contributing factor to these fluxes has been proposed, but has yet to be addressed. Among the possible causes for this anomaly is the widespread use of colorimetric assays for iron quantitation and speciation. Peat porewater contains high concentrations of dissolved humic and fulvic acids that occlude Fe(III), blocking colorimetric complex formation, potentially leading to an underestimate of Fe(III) in these challenging analytical matrices. We evaluated a novel ionic liquid extraction method in a variety of temperate peatland porewater samples and compared these results to data acquired simultaneously using colorimetric methods. We found a >50% average improvement in accuracy for total iron quantitation using ionic liquid extraction. Moreover, ionic liquid extraction of peat porewater consistently recovered Fe(III) whereas colorimetric methods detected 50-100% less, suggesting that DOM bound Fe(III) is not reliably detected using colorimetric assays in these systems and may represent a previously unidentified pool of electron acceptors in peat porewater.

  14. Metatranscriptomic analysis of arctic peat soil microbiota.

    PubMed

    Tveit, Alexander T; Urich, Tim; Svenning, Mette M

    2014-09-01

    Recent advances in meta-omics and particularly metatranscriptomic approaches have enabled detailed studies of the structure and function of microbial communities in many ecosystems. Molecular analyses of peat soils, ecosystems important to the global carbon balance, are still challenging due to the presence of coextracted substances that inhibit enzymes used in downstream applications. We sampled layers at different depths from two high-Arctic peat soils in Svalbard for metatranscriptome preparation. Here we show that enzyme inhibition in the preparation of metatranscriptomic libraries can be circumvented by linear amplification of diluted template RNA. A comparative analysis of mRNA-enriched and nonenriched metatranscriptomes showed that mRNA enrichment resulted in a 2-fold increase in the relative abundance of mRNA but biased the relative distribution of mRNA. The relative abundance of transcripts for cellulose degradation decreased with depth, while the transcripts for hemicellulose debranching increased, indicating that the polysaccharide composition of the peat was different in the deeper and older layers. Taxonomic annotation revealed that Actinobacteria and Bacteroidetes were the dominating polysaccharide decomposers. The relative abundances of 16S rRNA and mRNA transcripts of methanogenic Archaea increased substantially with depth. Acetoclastic methanogenesis was the dominating pathway, followed by methanogenesis from formate. The relative abundances of 16S rRNA and mRNA assigned to the methanotrophic Methylococcaceae, primarily Methylobacter, increased with depth. In conclusion, linear amplification of total RNA and deep sequencing constituted the preferred method for metatranscriptomic preparation to enable high-resolution functional and taxonomic analyses of the active microbiota in Arctic peat soil.

  15. Effect of water-table fluctuations on the degradation of Sphagnum phenols in surficial peats

    NASA Astrophysics Data System (ADS)

    Abbott, Geoffrey D.; Swain, Eleanor Y.; Muhammad, Aminu B.; Allton, Kathryn; Belyea, Lisa R.; Laing, Christopher G.; Cowie, Greg L.

    2013-04-01

    A much improved understanding of how water-table fluctuations near the surface affect decomposition and preservation of peat-forming plant litter and surficial peats is needed in order to predict possible feedbacks between the peatland carbon cycle and the global climate system. In this study peatland plants (bryophytes and vascular plants), their litter and peat cores were collected from the Ryggmossen peatland in the boreonemoral zone of central Sweden. The extracted insoluble residues from whole plant tissues were depolymerized using thermally assisted hydrolysis and methylation (THM) in the presence of both unlabelled and 13C-labelled tetramethylammonium hydroxide (TMAH) which yielded both vascular plant- and Sphagnum-derived phenols. Methylated 4-isopropenylphenol (IUPAC: 1-methoxy-4-(prop-1-en-2-yl)benzene), methylated cis- and trans-3-(4'-hydroxyphen-1-yl)but-2-enoic acid (IUPAC: (E/Z)-methyl 3-(4-methoxyphenyl)but-2-enoate), and methylated 3-(4'-hydroxyphen-1-yl)but-3-enoic acid (IUPAC: methyl 3-(4-methoxyphenyl)but-3-enoate) (van der Heijden et al., 1997) are confirmed as TMAH thermochemolysis products of "bound" sphagnum acid and also as being specific to Sphagnum mosses. These putative biomarkers were also significant components in the unlabelled TMAH thermochemolysis products from the depolymerization of ultrasonically extracted samples from eight peat cores, one from a hummock and one from a hollow at each of the four stages along the bog plateau-to-swamp forest gradient. We have proposed and measured two parameters namely (i) σ which is defined as the total amount of these four molecules normalised to 100 mg of OC; and (ii) an index (SR%) which is the ratio of σ to the Λ parameter giving a measure of the relative amounts of "bound" sphagnum acid to the "bound" vascular plant phenols in peat moss and the surficial peat layers. Changes in σ and SR% down the bog plateau (BP), bog margin (BM) and fen lagg (FL) cores in the Ryggmossen mire indicates

  16. Greenhouse gas emissions from an abandoned peatland in central Belarus during the first year of rewetting

    NASA Astrophysics Data System (ADS)

    Chuvashova, H.; Minke, M.; Burlo, A.; Thiele, A.; Augustin, J.; Yarmashuk, T.; Tichonov, V.; Liashchynskaya, N.; Kuzmin, Vl.

    2012-04-01

    Peatland restoration by inundation of drained fen grasslands can lead to very high methane emissions in the first years (M. Hahn-Schöfl et al, 2011). Due to a lack of other studies on the GHG emissions of fen forbs and meadows during the first years after flooding there is the worry to create methane plants by restoring such sites. Within the BMU-ICI financed project "Restoring Peatlands and applying Concepts for Sustainable Managements in Belarus - Climate Change Mitigation with Economic and Biodiversity Benefits" we selected the mesotrophic fen Bartenikha as a typical petland for central Belarus as study site. The peatland Bartenikha was drained in 1990 and used for peat extraction till 1999. Subsequently the peatland got abandoned and a meadow dominated by Agrostis stolonifera emerged in its SW part. In September 2010 the meadow was unexpectedly flooded by the beaver and the forbs died. During one year the water level changed from nearly 10 cm below surface to nearly 50 cm above surface. In 2011 only detritus was left from the former vegetation, but new species, beside some Chara, were still not established. We studied the effect of rewetting on the emission of carbon dioxide and methane during the period from September 2010 till September 2011 using the closed chamber method. Methane release during autumn, winter and early spring was still low. Substantially higher emissions of Methane are observed since June with highest rates in July when the water level was lower than usually, i.e. 20 cm above the surface and the temperature was high. In total Methane emissions per year were lower as expected. Carbon dioxide release was low during the whole year because of high water level but a dependence of emissions on temperature was detected. Altogether greenhouse gas emissions from the rewetted peatland were not high in the first year of flooding. Hahn-Schöfl M, Zak D., Minke M., Gelbrecht J., Augustin J., and Freibauer A. Organic sediment formed during inundation of

  17. The association of uranium with organic matter in Holocene peat: An experimental leaching study

    USGS Publications Warehouse

    Zielinski, R.A.; Meier, A.L.

    1988-01-01

    Uraniferous peat was sampled from surface layers of a Holocene U deposit in northeastern Washington State. Dried, sized, and homogenized peat that contained 5980 ??307 ppm U was subjected to a variety of leaching conditions to determine the nature and strength of U-organic bonding in recently accumulated organic matter. The results complement previous experimental studies of U uptake on peat and suggest some natural or anthropogenic disturbances that are favorable for remobilizing U. The fraction of U leached in 24 h experiments at 25??C ranged from 0 to 95%. The most effective leach solutions contained anions capable of forming stable dissolved complexes with uranyl (UO2+2) cation. These included H2SO4 (pH = 1.5) and concentrated (>0.01 M) solutions of sodium bicarbonate-carbonate (pH = 7.0-10.0), or sodium pyrophosphate (pH = 10). Effective leaching by carbonate and pyrophosphate in the absence of added oxidant, and the insignificant effect of added oxidant (as pressurized O2) strongly suggest that U is initially fixed on organic matter as an oxidized U(VI) species. Uranium is more strongly bound than some other polyvalent cations, based on its resistance to exchange in the presence of large excesses of dissolved Ca2+ and Cu2+. Measurements of the rate of U leaching indicate faster rates in acid solution compared to carbonate solution, and are consisten with simultaneous attack of sites with different affinities for U. Sulfuric acid appears a good choice for commercial extraction of U from mined peat. In situ disturbances such as overliming of peat soils, addition of fertilizers containing pyrophosphate, or incursions of natural carbonate-rich waters could produce significant remobilization of U, and possibly compromise the quality of local domestic water supplies. ?? 1988.

  18. Abandoned Channel Fill Sequences in Tidal Estuaries

    NASA Astrophysics Data System (ADS)

    Gray, A. B.; Pasternack, G. B.; Goni, M. A.; Watson, E. B.

    2014-12-01

    This study proposes a modification of the current model for abandoned channel fill stratigraphy produced in unidirectional flow river reaches to incorporate seasonal tidal deposition. Evidence supporting this concept came from a study of two consecutive channel abandonment sequences in Ropers Slough of the lower Eel River Estuary in northern California. Aerial photographs showed that Ropers Slough was abandoned around 1943, reoccupied after the 1964 flood, and abandoned again in 1974 with fill continuing to the present. Planform geomorphic characteristics derived from these images were used in conjunction with sub-cm resolution stratigraphic analyses to describe the depositional environment processes and their resultant sedimentary deposits. Results showed that both abandonment sequences recorded quasi-annual scale fluvial/tidal deposition couplets. In both cases tidal deposits contained very little sand, and were higher in organic and inorganic carbon content than the sandier fluvial through-flow deposits. However, the two abandonment fills differed significantly in terms of the temporal progression of channel narrowing and fluvial sediment deposition characteristics. The first abandonment sequence led to a more rapid narrowing of Ropers Slough and produced deposits with a positive relationship between grain size/deposit thickness and discharge. The second abandonment resulted in a much slower narrowing of Ropers Slough and generally thinner fluvial deposits with no clear relationship between grain size/deposit thickness and discharge. The δ13C values and organic nitrogen to organic carbon ratios of deposits from the first phase overlapped with Eel River suspended sediment characteristics found for low flows (1-5 times mean discharge), while those of the second phase were consistent suspended sediment from higher flows (7-10 times mean discharge). The abandoned channel fill sequences appeared to differ due to the topographic steering of bed sediment transport and

  19. Maceral and palynomorph facies from two tertiary peat-forming environments in the Powder River Basin, U.S.A.

    USGS Publications Warehouse

    Moore, T.A.; Stanton, R.W.; Pocknall, D.T.; Glores, R.M.

    1990-01-01

    The differences between the depositional settings of the Smith and Anderson subbituminous coal beds (Paleocene, central Powder River Basin, U.S.A.) are interpreted on the basis of their petrographic composition and palynologic assemblages. The Smith coal bed is relatively thin ( 50 m) sandstone bodies of an abandoned meander-belt complex, the coal bed is generally thicker (> 7 m) and more widespread (> 15 km) in extent than the Smith coal bed. The sands provided a relatively stable, poorly compactable platform that was favorable to the growth of large, arborescent vegetation, such as the dominant ancestral Glyptostrobus, as well as ancestral Nyssa, Carya, and Betulaceae in a well-drained but moist swamp environment. The stability of the peat-forming environment resulted in a raised peat deposit of relatively uniform paleoflora and peat composition. In the thicker areas of the Anderson coal bed, the upward increase in carbonized plant components indicates a progressively drier or better-drained swamp environment. Intervals within the coal bed that overlie or are lateral to crevasse-splay deposits contain a high concentration of pollen attributable to Pterocarya and an absence of carbonized plant remains, an indication that ancestral Pterocarya preferred a water-saturated environment close to the edge of the swamp where detrial influx occurred. ?? 1990.

  20. Isolation of humic acid from peat soil and its application as an adsorbent for AuCl4- in solution

    NASA Astrophysics Data System (ADS)

    Lestari, Puji

    2017-03-01

    Humic acid (HA) has been isolated from South Kalimantan (Indonesia) peat soil using alkali extraction method. The isolated HA then was applied on the adsorption process of AuCl4- in solution. Parameters investigated in the adsorption process consisted of the effect of initial pH, adsorption rate constant (k) and the adsorption capacity of AuCl4- on peat soil HA. The adsorption rate constant was determined according to the kinetic model proposed by Santosa (2007). The adsorption of AuCl4- on peat soil HA was optimum at pH 2. The adsorption rate constant (k) was 1.11 × 10-3 min-1. Adsorption of AuCl4- on peat soil HA fitted the Langmuir isotherm with the adsorption capacity of 90.91 mg.g-1. The adsorption of AuCl4- on peat soil HA was accompanied by the reduction of AuCl4- to Au(0), clarified by the existence of several peaks belonging to Au(0) in the XRD pattern of HA after the adsorption process.

  1. Deformation behaviors of peat with influence of organic matter.

    PubMed

    Yang, Min; Liu, Kan

    2016-01-01

    Peat is a kind of special material rich in organic matter. Because of the high content of organic matter, it shows different deformation behaviors from conventional geotechnical materials. Peat grain has a non-negligible compressibility due to the presence of organic matter. Biogas can generate from peat and can be trapped in form of gas bubbles. Considering the natural properties of peat, a special three-phase composition of peat is described which indicates the existence of organic matter and gas bubbles in peat. A stress-strain-time model is proposed for the compression of organic matter, and the surface tension effect is considered in the compression model of gas bubbles. Finally, a mathematical model has been developed to simulate the deformation behavior of peat considering the compressibility of organic matter and entrapped gas bubbles. The deformation process is the coupling of volume variation of organic matter, gas bubbles and water drainage. The proposed model is used to simulate a series of peat laboratory oedometer tests, and the model can well capture the test results with reasonable model parameters. Effects of model parameters on deformation of peat are also analyzed.

  2. Relationship between peat geochemistry and depositional environments, Cranberry Island, Maine

    USGS Publications Warehouse

    Raymond, R.; Cameron, C.C.; Cohen, A.D.

    1987-01-01

    The Heath, Great Cranberry Island, Maine, offers a unique locality for studying lateral and vertical relationships between radically different peat types within 1 km2. The majority of The Heath is a Sphagnum moss-dominated raised bog. Surrounding the raised bog is a swamp/marsh complex containing grass, sedge, Sphagnum moss, alder, tamarack, and skunk cabbage. Swamp/ marsh-deposited peat occurs both around the margins of The Heath and under Sphagnum-dominated peat, which was deposited within the raised bog. A third peat type, dominated by herbaceous aquatics, is present underlying the swamp/marsh-dominated peat but is not present as a dominant botanical community of The Heath. The three peat types have major differences in petrographic characteristics, ash contents, and associated minerals. Sulfur contents range from a low of 0.19 wt.% (dry) within the raised bog to a high of 4.44 wt% (dry) near the west end of The Heath, where swamp/marsh peat occurring directly behind a storm beach berm has been influenced by marine waters. The presence of major geochemical variations within a 1-km2 peat deposit suggests the need for in-depth characterization of potential peat resources prior to use. ?? 1987.

  3. Field methods for measuring hydraulic properties of peat deposits

    NASA Astrophysics Data System (ADS)

    Hogan, J. M.; van der Kamp, G.; Barbour, S. L.; Schmidt, R.

    2006-11-01

    New field techniques were developed and tested to evaluate peat storativity and hydraulic conductivity in a Boreal fen. Enclosed drainage tests and pumping tests were successfully completed in the thawed peat above an impermeable frozen layer and then repeated when the peat was fully thawed. A loading test experiment constrained values of vertical hydraulic conductivity within an order of magnitude for the peat below a depth of 2 m. An inherent advantage of these tests is that volumes of undisturbed peat on the scale of cubic metres may be characterized. Storativity of the fen peat as determined by enclosed drainage tests ranged from about 1.0 at the peat surface to 0.35 at a water table depth of 0.15 m. Laboratory drainage tests of peat cores gave similar, but widely scattered results. Hydraulic conductivity near the surface was as high as 9.0 × 10-3 ms-1 determined with pumping tests and in the range of 10-6 to 10-5 ms-1 below a depth of 2 m, estimated with the loading test. Slug tests gave similar results. Pumping tests, enclosed storativity tests and loading tests are practical large-scale field tests for determining peat properties. Copyright

  4. Methane Emissions from Abandoned Boreholes in South Eastern Australia

    NASA Astrophysics Data System (ADS)

    Day, S. J.; Fry, R.; Dell'Amico, M.; Williams, D.; Halliburton, B.; Element, A.

    2015-12-01

    The Surat Basin in south-eastern Queensland is one of Australia's main coal bed methane production areas. It has also been subject to coal exploration over many years and consequently there are thousands of abandoned exploration boreholes throughout the region. Here, we present some results of field measurements aimed at locating leaking legacy exploration boreholes in the Surat Basin and to quantify their emission rates. We also discuss emission measurements made on abandoned CBM wells in Queensland and NSW that have been decommissioned according to modern practices. Leaking boreholes were located using a Picarro 2301 CH4 analyser mounted in a vehicle that was driven through gas fields in the Surat Basin. Where surface emissions were indicated by elevated ambient CH4 levels, the emission rate was measured using soil flux chambers at each site. For comparison, soil gas flux measurements were also made on natural surfaces and agricultural land throughout the study areas. Ten borehole sources were located during the surveys, yielding emission rates from less than 0.1 kg CH4 day-1 to more than 100 kg CH4 day-1. A number of other known exploration borehole sites were examined which had no detectable CH4 emissions. Plugged and abandoned CBM wells showed no CH4 emissions except in two cases where emission rates of about 0.07 g CH4 day-1 were detected, which were comparable to natural wetland CH4 emissions. Preliminary results suggest that modern decommissioning practices appear to be effective in preventing CH4 leakage from CBM abandoned wells. However, legacy coal exploration boreholes may represent a significant source of CH4 in the Surat Basin, although the proportion of these holes leaking CH4 is yet to be determined. Moreover, it is not yet clear if emissions from boreholes are affected by changes in groundwater induced by water extraction associated with gas production and agriculture. This is an area requiring further research.

  5. Impact of drainage on wettability of fen peat-moorsh soils

    NASA Astrophysics Data System (ADS)

    Szajdak, L.; Szatyłowicz, J.; Brandyk, T.

    2009-04-01

    High water retention in peat is attributed to structural voids (macro-pores) due to the partial degradation of the structure of peat-forming plants, and molecular absorption sites (micro-pores) associated with the formation of humic substances. Water retention by the heterogeneously-structured system in peat organic matter depends on the chemical structure of solid surfaces. These naturally wet solids, if dried sufficiently, lose the ability to rewet quickly when immersed in water. The ability of peat surfaces to attract and hold water is attributed to hydrophilic functional groups which characterize the organic substances of peat. The investigations of chemical and physical properties were performed for three different peat-moorsh soils located in the Biebrza River Valley in Poland. All examined soils were used as meadow. Soil samples were taken from two depths: 5-10 cm (moorsh) and 50-80 cm (peat). Total organic carbon (TOC), dissolved organic carbon (DOC) and humic acids (HA) extracted from these samples were analysed. Also basic physical properties such as ash content and bulk density were measured. Wetting behavior of soils was quantified using water drop penetration time test (WDPT) and measured values of the soil-water contact angle using sessile drop method. The measurements were conducted on air-dry soil samples which volumetric moisture content was not exceeding 7%. The significant differences in the concentrations of TOC, DOC and properties of HA between two investigated depth of among peat and moorsh samples were observed. The measured concentrations of total organic carbon in the considered soils ranged from 37.2 to 45.6%. Generally, the decrease of total organic carbon concentration with depth of profiles was observed. The contents of dissolved organic carbon in the soils ranged from 5.3 to 19.4%. The quantities of dissolved organic carbon decreased simultaneously with E4/E6 values and with the depth of the soil profiles. For the investigated peat

  6. Navajo Nation: Cleaning Up Abandoned Uranium Mines

    EPA Pesticide Factsheets

    This site provides information about the progress of EPA's cleanup of abandoned uranium mines on Navajo and Hopi lands and in other areas of Arizona and New Mexico, including health impacts, major enforcement and removal milestones, and community actions.

  7. 7 CFR 767.51 - Property abandonment.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ..., manage, and operate the abandoned security property, including marketing perishable security property on behalf of the borrower when such action is in the Agency's financial interest. If the security is...

  8. Asymptomatic bowel perforation by abandoned ventriculoperitoneal shunt.

    PubMed

    Rinker, Eric K; Osborn, Daniel A; Williams, Todd R; Spizarny, David L

    2013-09-01

    We report a case of an abandoned abdominal ventriculoperitoneal shunt that migrated into the gastric antrum, colonic hepatic flexure, and liver parenchyma, which was discovered incidentally on an abdominal CT obtained for renal stones. In regards to the migrated abandoned VP shunt, the patient was asymptomatic. Upon review of prior CT scans, these findings had progressed over approximately 7 years. We describe the case and discuss the clinical and radiologic findings, complications resulting from ventriculoperitoneal shunts, and possible approaches to their management.

  9. Comparative studies of Eocene silicified peat and lignite: transition between peat and lignite

    SciTech Connect

    Ting, F.T.C.

    1985-01-01

    Silicified Eocene peats with excellent preserved cellular structures were found in lignite beds in western North Dakota and were comparatively studied. The well preserved plant tissues resemble that of modern Taxodium peat. The most striking difference between silicified peat and lignite is the disappearance of cell cavities when peat is transformed to lignite, a phenomenon caused primarily by compaction rather than cell wall swelling through humification or gelification. The differences between textinite and ulminite can be traced back to the differences between early wood and late wood of the secondary xylem. What appear to be cutinites in lignite are compressed cortex tissues of young plants. Silicified leaf and cortex tissues contain more visible fluorinite exhibiting brilliant fluorescence. Clustering phloem fibers or stone cells give rise to a material resembling resinite but are more akin to huminite A and/or suberinite. They converge to vitrinite when vitrinite reflectance exceeds 0.6%. Alternating banded phloem fibers and phloem parenchyma give rise to alternating layers of huminite A and huminite B. True micrinite does occur in lignite but in limited quantities.

  10. Short period of oxygenation releases latch on peat decomposition.

    PubMed

    Brouns, Karlijn; Verhoeven, Jos T A; Hefting, Mariet M

    2014-05-15

    Extreme summer droughts are expected to occur more often in the future in NW Europe due to climate change. These droughts might accelerate the rate of peat oxidation in drained peat areas, with impacts on soil subsidence, GHG emission and water quality. This study aimed at providing more insight in the oxidation of deep peat layers that had not previously been exposed to air, the so-called secondary decomposition. We incubated two types of peat (eutrophic and oligotrophic), sampled from permanently anoxic peat layers from nature reserves and agricultural peat meadows. Peat samples were incubated for thirteen weeks under anoxic conditions, but were exposed to air for one to eight weeks. The production of CO2 and CH4 was quantified as a proxy for decomposition; concentrations of soluble nutrients and phenolic compounds were also measured. The results showed that oxygenation led to a steep increase in the rate of decomposition, indicated by higher carbon loss rates during and after oxygenation compared to non-oxygenated samples. Carbon loss rates increased more for eutrophic peat (agricultural area: 352%, nature reserve: 182%) than for oligotrophic peat (83% and 159% respectively). Most peat samples investigated showed higher post-oxygenation CO2 and/or CH4 production compared to the anoxic pre-oxygenation period. This indicates that oxygenation stimulates decomposition, even after anoxic conditions have returned. Contrary to the enzymic latch theory, no effects of oxygenation on the concentrations of soluble or condensed phenolic compounds were detected. Soluble nutrient concentrations did not change due to oxygenation either. Noteworthy is the occurrence of pyrite mineralization and associated acidification in eutrophic peat. Thus, low summer water levels, for example due to climate change, should be avoided in order to limit exceptionally high decomposition rates and associated problems such as increasing subsidence rates, greenhouse gas emission, sulfate release

  11. The rail abandonment process: A southern perspective

    SciTech Connect

    Not Available

    1988-12-01

    One factor in evaluating the desirability of rail transport for high-level radioactive wastes or spent fuels is the frequency, or lack thereof, with which railroad and railroad lines have been, and are, abandoned. If DOE makes a decision to use the rail option and a line is subsequently abandoned, the choice results in increased cost, time delays and possibly safety problems: Information is therefore needed prior to the decision-making process to evaluate the desirability of the rail shipping option. One result of the abandonments mentioned herein, as well as other later abandonments, is the creation of a US rail system undergoing an evolutionary process in the 1980s as far-reaching as the changes that occurred when the industry was in its infancy a century and-a-half ago. The purpose of this paper is to examine the factors leading to some of these changes by tracing the historical development of the rail abandonment process, with particular emphasis on the rise of regional railroads, their problems in the modern era and current trends in rail abandonments as well as their effects on the southeastern United States.

  12. Towards Understanding Methane Emissions from Abandoned ...

    EPA Pesticide Factsheets

    Reconciliation of large-scale top-down methane measurements and bottom-up inventories requires complete accounting of source types. Methane emissions from abandoned oil and gas wells is an area of uncertainty. This presentation reviews progress to characterize the potential inventory impacts of abandoned wells for the U.S. . Available methane emission rate data for abandoned wells is reviewed and some of the ongoing research to better characterize emissions is discussed. Efforts to compile a database of well drilling activities since the 1870’s for each state and each state’s establishment of well plugging standards for abandoned wells is described. Progress towards an estimate of national methane emissions from abandoned wells and major sources of uncertainty are presented. These emissions are put in to context by comparing to other sources of methane emissions from oil and gas production activities. This is an abstract for a presentation at the Natural GasSTAR Annual Implementation Workshop on November 16-18, 2015 in Pittsburgh, PA. The subject is methane emissions fro abandoned wells. This is a report on interim progress on a effort we have with ERG. OAP is involved in the project and will review slides.

  13. Impact of vineyard abandonment and natural recolonization on metal content and availability in Mediterranean soils.

    PubMed

    de Santiago-Martín, Ana; Vaquero-Perea, Cristina; Valverde-Asenjo, Inmaculada; Quintana Nieto, Jose R; González-Huecas, Concepción; Lafuente, Antonio L; Vázquez de la Cueva, Antonio

    2016-05-01

    Abandonment of vineyards after uprooting has dramatically increased in last decades in Mediterranean countries, often followed by vegetation expansion processes. Inadequate management strategies can have negative consequences on soil quality. We studied how the age and type of vegetation cover and several environmental characteristics (lithology, soil properties, vineyard slope and so on) after vineyard uprooting and abandonment contribute to the variation patterns in total, HAc (acetic acid-method, HAc) and EDTA-extractable (ethylenediaminetetraacetic acid-method) concentrations of Cd, Cu, Pb and Zn in soils. We sampled 141 points from vineyards and abandoned vineyard Mediterranean soils recolonized by natural vegetation in recent decades. The contribution of several environmental variables (e.g. age and type of vegetation cover, lithology, soil properties and vineyard slope) to the total and extractable concentrations of metals was evaluated by canonical ordination based on redundancy analysis, considering the interaction between both environmental and response variables. The ranges of total metal contents were: 0.01-0.15 (Cd), 2.6-34 (Cu), 6.6-30 (Pb), and 29-92mgkg(-1) (Zn). Cadmium (11-100%) had the highest relative extractability with both extractants, and Zn and Pb the lowest. The total and EDTA-extractable of Cd, Pb and Zn were positively related to the age of abandonment, to the presence of Agrostis castellana and Retama sphaerocarpa, and to the contents of Fe-oxides, clay and organic matter (OM). A different pattern was noted for Cu, positively related to vineyard soils. Soil properties successfully explained HAc-extractable Cd, Cu, Pb and Zn but the age and type of vegetation cover lost significance. Clay content was negatively related to HAc-extractable Cu and Pb; and OM was positively related to HAc-Cd and Zn. In conclusion, the time elapsed after vineyard uprooting, and subsequent land abandonment, affects the soil content and availability of metals

  14. Evapotranspiration of tropical peat swamp forests.

    PubMed

    Hirano, Takashi; Kusin, Kitso; Limin, Suwido; Osaki, Mitsuru

    2015-05-01

    In Southeast Asia, peatland is widely distributed and has accumulated a massive amount of soil carbon, coexisting with peat swamp forest (PSF). The peatland, however, has been rapidly degraded by deforestation, fires, and drainage for the last two decades. Such disturbances change hydrological conditions, typically groundwater level (GWL), and accelerate oxidative peat decomposition. Evapotranspiration (ET) is a major determinant of GWL, whereas information on the ET of PSF is limited. Therefore, we measured ET using the eddy covariance technique for 4-6 years between 2002 and 2009, including El Niño and La Niña events, at three sites in Central Kalimantan, Indonesia. The sites were different in disturbance degree: a PSF with little drainage (UF), a heavily drained PSF (DF), and a drained burnt ex-PSF (DB); GWL was significantly lowered at DF, especially in the dry season. The ET showed a clear seasonal variation with a peak in the mid-dry season and a large decrease in the late dry season, mainly following seasonal variation in net radiation (Rn ). The Rn drastically decreased with dense smoke from peat fires in the late dry season. Annual ET forced to close energy balance for 4 years was 1636 ± 53, 1553 ± 117, and 1374 ± 75 mm yr(-1) (mean ± 1 standard deviation), respectively, at UF, DF, and DB. The undrained PSF (UF) had high and rather stable annual ET, independently of El Niño and La Niña events, in comparison with other tropical rainforests. The minimum monthly-mean GWL explained 80% of interannual variation in ET for the forest sites (UF and DF); the positive relationship between ET and GWL indicates that drainage by a canal decreased ET at DF through lowering GWL. In addition, ET was decreased by 16% at DB in comparison with UF chiefly because of vegetation loss through fires.

  15. Acidophilic Methanotrophic Communities from Sphagnum Peat Bogs

    PubMed Central

    Dedysh, Svetlana N.; Panikov, Nicolai S.; Tiedje, James M.

    1998-01-01

    Highly enriched methanotrophic communities (>25 serial transfers) were obtained from acidic ombrotrophic peat bogs from four boreal forest sites. The enrichment strategy involved using media conditions that were associated with the highest rates of methane uptake by the original peat samples, namely, the use of diluted mineral medium of low buffering capacity, moderate incubation temperature (20°C), and pH values of 3 to 6. Enriched communities contained a mixture of rod-shaped bacteria arranged in aggregates with a minor contribution of Hyphomicrobium-like cells. The growth stoichiometry of isolates was characteristic of methanotrophic bacteria (CH4/O2/CO2=1:1.1:0.59), with an average apparent yield of 0.41 ± 0.03 g of biomass C/g of CH4-C. DNA from each enrichment yielded a PCR product of the expected size with primers for both mmoX and mmoY genes of soluble methane monooxygenase. Two types of sequences were obtained for PCR-amplified fragments of mmoX. One of them exhibited high identity to the mmoX protein of the Methylocystis-Methylosinus group, whereas the other showed an equal level of divergence from both the Methylosinus-Methylocystis group and Methylococcus capsulatus (Bath) and formed a distinct branch. The pH optimum for growth and for CH4 uptake was 4.5 to 5.5, which is very similar to that for the optimum CH4 uptake observed in the original peat samples. These methanotrophs are moderate acidophiles rather than acidotolerant organisms, since their growth rate and methane uptake were much lower at neutral pH. The growth of the methanotrophic community was enhanced by using media with a very low salt content (20 to 200 mg/liter), more typical of their natural environment. All four enriched communities grew on N-free medium. PMID:9501432

  16. Climate mitigation scenarios of drained peat soils

    NASA Astrophysics Data System (ADS)

    Kasimir Klemedtsson, Åsa; Coria, Jessica; He, Hongxing; Liu, Xiangping; Nordén, Anna

    2014-05-01

    The national inventory reports (NIR) submitted to the UNFCCC show Sweden - which as many other countries has wetlands where parts have been drained for agriculture and forestry purposes, - to annually emit 12 million tonnes carbon dioxide equivalents, which is more GHG'es than industrial energy use release in Sweden. Similar conditions can be found in other northern countries, having cool and wet conditions, naturally promoting peat accumulation, and where land use management over the last centuries have promoted draining activities. These drained peatland, though covering only 2% of the land area, have emissions corresponding to 20% of the total reported NIR emissions. This substantial emission contribution, however, is hidden within the Land Use Land Use Change and Forestry sector (LULUCF) where the forest Carbon uptake is even larger, which causes the peat soil emissions become invisible. The only drained soil emission accounted in the Swedish Kyoto reporting is the N2O emission from agricultural drained organic soils of the size 0.5 million tonnes CO2e yr-1. This lack of visibility has made incentives for land use change and management neither implemented nor suggested, however with large potential. Rewetting has the potential to decrease soil mineralization, why CO2 and N2O emissions are mitigated. However if the soil becomes very wet CH4 emission will increase together with hampered plant growth. By ecological modeling, using the CoupModel the climate change mitigation potential have been estimated for four different land use scenarios; 1, Drained peat soil with Spruce (business as usual scenario), 2, raised ground water level to 20 cm depth and Willow plantation, 3, raised ground water level to 10 cm depth and Reed Canary Grass, and 4, rewetting to an average water level in the soil surface with recolonizing wetland plants and mosses. We calculate the volume of biomass production per year, peat decomposition, N2O emission together with nitrate and DOC

  17. 37 CFR 2.66 - Revival of abandoned applications.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... application abandoned because the applicant did not timely respond to an Office action or notice of allowance... abandonment, if the applicant did not receive the notice of abandonment, and the applicant was diligent in... for filing a petition to revive an application abandoned because the applicant did not timely...

  18. Temperature and peat type control CO2 and CH4 production in Alaskan permafrost peats.

    PubMed

    Treat, C C; Wollheim, W M; Varner, R K; Grandy, A S; Talbot, J; Frolking, S

    2014-08-01

    Controls on the fate of ~277 Pg of soil organic carbon (C) stored in permafrost peatland soils remain poorly understood despite the potential for a significant positive feedback to climate change. Our objective was to quantify the temperature, moisture, organic matter, and microbial controls on soil organic carbon (SOC) losses following permafrost thaw in peat soils across Alaska. We compared the carbon dioxide (CO2 ) and methane (CH4 ) emissions from peat samples collected at active layer and permafrost depths when incubated aerobically and anaerobically at -5, -0.5, +4, and +20 °C. Temperature had a strong, positive effect on C emissions; global warming potential (GWP) was >3× larger at 20 °C than at 4 °C. Anaerobic conditions significantly reduced CO2 emissions and GWP by 47% at 20 °C but did not have a significant effect at -0.5 °C. Net anaerobic CH4 production over 30 days was 7.1 ± 2.8 μg CH4 -C gC(-1) at 20 °C. Cumulative CO2 emissions were related to organic matter chemistry and best predicted by the relative abundance of polysaccharides and proteins (R(2) = 0.81) in SOC. Carbon emissions (CO2 -C + CH4 -C) from the active layer depth peat ranged from 77% larger to not significantly different than permafrost depths and varied depending on the peat type and peat decomposition stage rather than thermal state. Potential SOC losses with warming depend not only on the magnitude of temperature increase and hydrology but also organic matter quality, permafrost history, and vegetation dynamics, which will ultimately determine net radiative forcing due to permafrost thaw.

  19. Sulfur contents of peats at the confluence of carbonate and peat-forming depositional systems, southeastern Florida

    SciTech Connect

    Cohen, A.D. ); Davies, T.D. ); Spackman, W. )

    1993-08-01

    Complex stratigraphic and compositional relationships have been reported by others at sites where coal beds are laterally in contact with marine carbonates (such as in the southern portion of the Illinois basin). These basin edges are important in that they may (1) represent sites of active coal mining, (2) contain important clues as to the development of the basin, and (3) be sources of the dispersed terrestrial organics encountered in nearby marine rocks. This study was undertaken to investigate peat/carbonate relationships in a modern setting, with initial research on sulfur contents relative to stratigraphic/petrographic conditions. Thirty-eight cores were taken along northwest-southeast transects from the mainland to Florida Bay. The most inland cores consist entirely of peat, representing transgression of marine types (mangrove) over freshwater types. Toward the carbonate-rich bay, a more complex stratigraphy exists. Marine carbonates and peats interfinger, with erosional contacts indicating that parts of the peat sequence are missing. At the coastline, most of the peat is replaced by marine carbonate except for thin (1-10 cm) basal (usually overlain by marine carbonates), with the best preserved ranges from 0.6 to 5.0% (dry) at the most inland sites, 2.4 to 7.8% near the coastline, and 1.5 to 5.9% in bay sediments. Total sulfur is higher in marine than freshwater peats, but freshwater peats overlain by marine peats are enriched in sulfur. Freshwater peats beneath marine carbonates are relatively low in sulfur, but are higher if the peat is overlain by a marine peat before being overlain by the carbonate.

  20. Classifications of bog peat sensitivity to anthropogenic impact (Western Siberia)

    NASA Astrophysics Data System (ADS)

    Kramarenko, V. V.; Matveenko, I. A.; Nikitenkov, A. N.; Molokov, V. Y.; Khoroshko, A. P.

    2016-09-01

    The article deals with strength parameters of peats in Western Siberia, evaluates their transformations under the anthropogenic mechanical impact, presents peat classification in terms of sensitivity allowing the forecast of strength loss when destructing their structure in the process of building roads, pipelines. Sensitivity classification also permits predicting roadability for construction design.

  1. Volatile and semivolatile organic compounds in laboratory peat fire emissions

    EPA Science Inventory

    Speciated volatile organic compounds (VOCs) and organic fine particulate matter (PM2.5) mass emission factors were determined from laboratory peat fire experiments. Peat samples originated from two wildlife reserves located near the coast of North Carolina, U.S. Gas and particula...

  2. Biochar as growing media additive and peat substitute

    NASA Astrophysics Data System (ADS)

    Steiner, C.; Harttung, T.

    2014-04-01

    Environmental concerns raised the demand for alternative growing media substituting sphagnum peat. However growing media formulations still depend on peat and alternatives are limited. Biochar is carbonized plant material and could be an appropriate additive or even substitute for sphagnum peat. Freshly produced, it is free from pathogens, has a low nutrient content (if produced from nutrient poor feedstock), a very high structural stability and likely other favourable properties such as air capacity and water holding capacity. Preliminary tests were conducted to compare biochar with other growing media and growing media additives. The growth of a miniature sunflower, pH and electrical conductivity (EC) was measured in different growing media such as biochar, perlite, clay granules, sphagnum peat and peat mixed with biochar in the ratios 1 : 4, 1 : 1 and 4 : 1 (25, 50 and 75%, by volume). Fresh biochar has a similar EC than peat which is even lower after rinsing with water. Due to the relatively high pH of biochar, it could be added to peat instead of lime in a concentration of up to 75%. The growth of the sunflower was similar in all growing media. Only the plant weight was slightly higher of plants that grew in perlite or peat. There is a large potential for optimization such as selection of particle size and feedstock for biochar production and growing media formulations for specific plant requirements.

  3. Biochar as a growing media additive and peat substitute

    NASA Astrophysics Data System (ADS)

    Steiner, C.; Harttung, T.

    2014-09-01

    Environmental concerns raised the demand for alternative growing media substituting Sphagnum peat. However growing media formulations still depend on peat and alternatives are limited. Biochar is carbonized plant material and could be an appropriate additive or even substitute for Sphagnum peat. Freshly produced, it is free from pathogens, has a low nutrient content (if produced from nutrient-poor feedstock), a very high structural stability and likely other favourable properties such as air capacity and water-holding capacity. Preliminary tests were conducted to compare biochar with other growing media and growing media additives. The growth of a miniature sunflower, pH and electrical conductivity (EC) was measured in different growing media such as biochar, perlite, clay granules, Sphagnum peat and peat mixed with biochar in the ratios 1 : 4, 1 : 1 and 4 : 1 (25, 50 and 75%, by volume). Fresh biochar has a similar EC to peat which is even lower after rinsing with water. Due to the relatively high pH of biochar, it could be added to peat instead of lime in a concentration of up to 75%. The growth of the sunflower was similar in all growing media. Only the plant weight was slightly higher of plants that grew in perlite or peat. There is a large potential for optimization such as selection of particle size and feedstock for biochar production and growing media formulations for specific plant requirements.

  4. Isotopic evidence for nitrogen mobility in peat bogs

    NASA Astrophysics Data System (ADS)

    Novak, Martin; Stepanova, Marketa; Jackova, Ivana; Vile, Melanie A.; Wieder, R. Kelman; Buzek, Frantisek; Adamova, Marie; Erbanova, Lucie; Fottova, Daniela; Komarek, Arnost

    2014-05-01

    Elevated nitrogen (N) input may reduce carbon (C) storage in peat. Under low atmospheric deposition, most N is bound in the moss layer. Under high N inputs, Sphagnum is not able to prevent penetration of dissolved N to deeper peat. Nitrogen may become available to the roots of invading vascular plants. The concurrent oxygenation of deeper peat layers, along with higher supply of labile organic C, may enhance microbial decomposition and lead to peat thinning. The resulting higher emissions of greenhouse gases may accelerate global warming. Seepage of N to deeper peat has never been quantified. Here we present evidence for post-depositional mobility of atmogenic N in peat, based on natural-abundance N isotope ratios. We conducted a reciprocal peat transplant experiment between two Sphagnum-dominated peat bogs in the Czech Republic (Central Europe), differing in anthropogenic N inputs. The northern site VJ received as much as 33 kg N ha-1 yr-1 via spruce canopy throughfall. The southern site was less polluted (17.6 kg N ha-1 yr-1). Isotope signatures of living moss differed between the two sites (δ15N of -3‰ and -7‰ at VJ and CB, respectively). After 18 months, an isotope mass balance was constructed. In the CB-to-VJ transplant, a significant portion of original CB nitrogen (98-31%) was removed and replaced by nitrogen of the host site throughout the top 10 cm of the profile. Nitrogen, deposited at VJ, was immobilized in imported CB peat that was up to 20 years old. Additionally, we compared N concentration and N accumulation rates in 210Pb-dated peat profiles with well-constrained data on historical atmospheric N pollution. Nationwide N emissions peaked in 1990, while VJ exhibited the highest N content in peat that formed in 1930. This de-coupling of N inputs and N retention in peat might be interpreted as a result of translocation of dissolved pollutant N downcore, corroborating our δ15N results at VJ and CB. Data from a variety of peat bogs along pollution

  5. Possibilities for detailed dating of peat bog deposits

    SciTech Connect

    Punning, J.; Ilomets, M.; Koff, T. )

    1993-01-01

    Geochemical and palynological data as well as radiocarbon dating were used to study the peat bog deposits in Niinsarre bog, northeast Estonia. The aim of this study was to establish criteria for determining a detailed chronology, which is important, for example, in studying paleoevents and historical monitoring. In some cases, they can use cumulative pollen data, as well as cumulative chemical and peat bulk density data. Material was gathered for [sup 14]C dating from three parallel samples taken from cores ca. 10--20 cm apart using a Russian peat sampler. Samples for peat bulk density, palynological and chemical measurements were taken from the same cores. To measure peat bulk density, the authors used a continuous sampling method. Sampling frequency was calculated to cover layers formed over 50 yr.

  6. Aerobic and microaerophilic actinomycetes of typical agropeat and peat soils

    NASA Astrophysics Data System (ADS)

    Zenova, G. M.; Gryadunova, A. A.; Pozdnyakov, A. I.; Zvyagintsev, D. G.

    2008-02-01

    A high number (from tens of thousands to millions of CFU/g of soil) of actinomycetes and a high diversity of genera were found in typical peat and agropeat soils. Agricultural use increases the number and diversity of the actinomycete complexes of the peat soils. In the peat soils, the actinomycete complex is represented by eight genera: Streptomyces, Micromonospora, Streptosporangium, Actinomadura, Microbispora, Saccharopolyspora, Saccharomonospora, and Microtetraspora. A considerable share of sporangial forms in the actinomycete complex of the peat soils not characteristic of the zonal soils was revealed. The number of actinomycetes that develop under aerobic conditions is smaller by 10-100 times than that of aerobic forms in the peat soils. Among the soil actinomycetes of the genera Streptomyces, Micromonospora, Streptosporangium, Actinomadura, Microbispora, and Microtetraspora, the microaerophilic forms were found; among the Saccharopolyspora and Saccharomonospora, no microaerophilic representatives were revealed.

  7. Mitigating Settlement of Structures founded on Peat

    NASA Astrophysics Data System (ADS)

    Wijeyesekera, D. C.; Numbikannu, L.; Ismail, T. N. H. T.; Bakar, I.

    2016-07-01

    Observations made of two common failures of structures founded on peat/organic soil in Johor, Malaysia is presented. Critical evaluation of current lightweight fill technology to mitigate such settlement is also discussed. Lightweight technology, such as Expanded Polystyrene (EPS), has been used in construction on soft yielding ground for decades. Regrettably, some published information of EPS failures to perform on construction sites are also cited in this paper. This paper outlines some concepts leading to the development of an alternative innovative lightweight fill is that the idealised cellular structure of the GCM permit free flow of water and complemented by the mat structure which evens out any differential settlement A further highlight of this paper is the monitoring of the field performance of this lightweight fill (GCM) as a feasible alternative to fill weight reduction on yielding ground.. Hence, a prime research objective was to compare the fill settlements observed with 1m high fill of surcharge loading on peat ground (comparison of the case of using a partial 0.6m high GCM and that of a total of 1m of conventional sand backfill).

  8. Combined molecular ecological and confocal laser scanning microscopic analysis of peat bog methanogen populations.

    PubMed

    Upton, M; Hill, B; Edwards, C; Saunders, J R; Ritchie, D A; Lloyd, D

    2000-12-15

    Confocal laser scanning microscopy, using fluorescently labelled oligonucleotide probes targeting the 16S rRNA of different physiological groups of methanogens, was used to identify which methanogenic genera were present and to describe their in situ spatial locations in samples taken at different depths from blanket peat bog cores. Total bacterial DNA was also extracted and purified from the samples and used as template for amplification of 16S rRNA and regions of methyl CoM reductase-encoding genes using the polymerase chain reaction, as well as for oligonucleotide hybridisation experiments. These techniques, used in concert, demonstrated that methanogens of several physiological groups were present in highest numbers in the mid regions of 25 cm deep peat cores. Some discrepancies were apparent in the findings of the microscopic and molecular methods, though these may be partially accounted for by the different sensitivities of the techniques employed. The combined approaches used in this study gave an insight into the diversity and distribution of methanogens in peat environments not possible using molecular ecological methods alone.

  9. Innovative biocatalytic production of soil substrate from green waste compost as a sustainable peat substitute.

    PubMed

    Kazamias, Georgios; Roulia, Maria; Kapsimali, Ioanna; Chassapis, Konstantinos

    2016-08-02

    In the present work, a new simple and quick eco-friendly method is discussed to handle effectively the green wastes and produce a sustainable peat substitute of high quality on the large scale. Principal physicochemical parameters, i.e., temperature, moisture, specific weight, pH, electrical conductivity and, also, microorganisms, organic matter, humic substances, total Kjeldahl nitrogen and total organic carbon, C/N ratio, ash, metal content and phytotoxicity, were monitored systematically. Humic substances content values were interrelated to both C/N ratio and pH values and, similarly, bulk density, TOC, TKN, C/N, GI, ash and organic matter were found interconnected to each other. A novel biocatalyst, extremely rich in soil microorganisms, prepared from compost extracts and peaty lignite, accelerated the biotransformation. Zeolite was also employed. The compost does not demonstrate any phytotoxicity throughout the entire biotransformation process and has increased humic substances content. Both humic substances content and germination index can be employed as maturation indices of the compost. Addition of compost, processed for 60 days only, in cultivations of grass plants led to a significant increase in the stem mass and root size, annotating the significant contribution of the compost to both growth and germination. The product obtained is comparable to peat humus, useful as peat substitute and can be classified as a first class soil conditioner suitable for organic farming.

  10. Organic Geochemical Characteristics and Depositional Environment of Aǧaçbaşi Plateau Peat, Köprübaşi/Trabzon, NE Turkey

    NASA Astrophysics Data System (ADS)

    Hoş Çebi, Fatma; Korkmaz, Sadettin

    2013-04-01

    . In the sterane triangle diagram, the extract of the peat sample was plotted in the area of high plant and brown and green alga inputs. Also C30 sterane, which is implication of marine environment, has not been recorded on chromatogram. 22S/(22S+22R) homohopan index, Ts/(Ts+Tm), moretan/hopane, 20S/(20S+20R) sterane and ββ/(ββ+αα) sterane ratios suggest immature level of the organic matter. Key Words: peat, biomarker, sterane, terpane

  11. Which accesses should be abandoned or revised?

    PubMed

    Gibbons, Christopher P

    2014-01-01

    This review considers the factors in deciding whether to abandon a functioning access. Strong indications for ligation or excision of an access are infection or severe early-onset steal. Access ligation may also be required for central vein occlusion or high-output cardiac failure. In general, a failing or thrombosed access should be restored to function unless it is no longer required. For failing or thrombosed distal arteriovenous fistulas, it may be easiest to abandon it and create a new fistula a few centimetres proximally rather than perform angioplasty, which is likely to require repeating. Other accesses may be abandoned after repeated treatment of the same stenosis over a short period provided other options exist.

  12. Soil microbial community of abandoned sand fields.

    PubMed

    Elhottová, D; Szili-Kovács, T; Tríska, J

    2002-01-01

    Microbiological evaluation of sandy grassland soils from two different stages of secondary succession on abandoned fields (4 and 8 years old fallow) was carried out as a part of research focused on restoration of semi-natural vegetation communities in Kiskunság National Park in Hungary. There was an apparent total N and organic C enrichment, stimulation of microbial growth and microbial community structure change on fields abandoned by agricultural practice (small family farm) in comparison with native undisturbed grassland. A successional trend of the microbial community was found after 4 and 8 years of fallow-lying soil. It consisted in a shift of r-survival strategy to more efficient C economy, in a decrease of specific respiration and metabolic activity, forced accumulation of storage bacterial compounds and increased fungal distribution. The composition of microbial phospholipid fatty acids mixture of soils abandoned at various times was significantly different.

  13. Infanticide and illegal infant abandonment in Malaysia.

    PubMed

    Razali, Salmi; Kirkman, Maggie; Ahmad, S Hassan; Fisher, Jane

    2014-10-01

    Infant abandonment and infanticide are poorly understood in Malaysia. The information available in the public arena comes predominantly from anecdotal sources. The aim of this study was to describe the prevalence and characteristics of infanticide and illegal infant abandonment in Malaysia and to estimate annual rates for the most recent decade. Summaries of data about infanticide and illegal infant abandonment were gathered from police records; the annual number of live births was ascertained from the national registry. The estimated inferred infanticide rates for Malaysia were compared with the infanticide rates among countries of very high, high, medium, and low rankings on the Human Development, Gender Inequality, and Gini indices. From 1999 to 2011, 1,069 cases of illegal infant abandonment were recorded and 1,147 people were arrested as suspected perpetrators. The estimated inferred infanticide rate fluctuated between 4.82 and 9.11 per 100,000 live births, a moderate rate relative to the infanticide rates of other countries. There are substantial missing data, with details undocumented for about 78-87% of cases and suspected perpetrators. Of the documented cases, it appeared that more boys than girls were victims and that suspected perpetrators were predominantly Malays who were women, usually mothers of the victim; the possibility of arrest bias must be acknowledged. Economic and social inequality, particularly gender inequality, might contribute to the phenomena of infanticide and abandonment. Strategies to reduce rates of infanticide and illegal infant abandonment in Malaysia will require strengthening of the surveillance system and attention to the gender-based inequalities that underpin human development.

  14. The total phosphorus budget of a peat-covered catchment

    NASA Astrophysics Data System (ADS)

    Worrall, Fred; Moody, Catherine S.; Clay, Gareth D.; Burt, Tim P.; Rose, Rob

    2016-07-01

    Although many studies have considered the carbon or greenhouse gas budgets of peat ecosystems, only a few have considered the nutrient budget of peat soils, and this, in turn, has limited the ability of studies to consider the impact of changes in climate and atmospheric deposition on the phosphorus budget of a peat soil. This study considered the total phosphorus (P) budget of an upland peat-covered catchment over the period 1993 to 2012. The study has shown (i) total atmospheric deposition of phosphorus varied from 62 to 175 kg P/km2/yr; (ii) the carbon:phosphorus ratio of the peat profile declines significantly from values in the litter layer (C:P = 1326) to approximately constant at 30 cm depth (C:P = 4240); (iii) the total fluvial flux of phosphorus varied from 49 to 111 kg P/km2/yr, of which between 45 and 77% was dissolved P; and (iv) the total phosphorus sink varied from -5.6 to +71.7 kg P/km2/yr with a median of +29.4 kg P/km2/yr, which is within the range of the estimated long-term accumulation rate of phosphorus in the peat profile of between 3 and 32 kg P/km2/yr. The phosphorus budget of the peat ecosystem relies on rapid recycling near the soil surface, and this means that any vegetation management may critically deprive the ecosystem of this nutrient.

  15. Multiphase Flow and Cavern Abandonment in Salt

    SciTech Connect

    Ehgartner, Brian; Tidwell, Vince

    2001-02-13

    This report will explore the hypothesis that an underground cavity in gassy salt will eventually be gas filled as is observed on a small scale in some naturally occurring salt inclusions. First, a summary is presented on what is known about gas occurrences, flow mechanisms, and cavern behavior after abandonment. Then, background information is synthesized into theory on how gas can fill a cavern and simultaneously displace cavern fluids into the surrounding salt. Lastly, two-phase (gas and brine) flow visualization experiments are presented that demonstrate some of the associated flow mechanisms and support the theory and hypothesis that a cavity in salt can become gas filled after plugging and abandonment

  16. Organic matter loss from cultivated peat soils in Sweden

    NASA Astrophysics Data System (ADS)

    Berglund, Örjan; Berglund, Kerstin

    2015-04-01

    The degradation of drained peat soils in agricultural use is an underestimated source of loss of organic matter. Oxidation (biological degradation) of agricultural peat soils causes a loss of organic matter (OM) of 11 - 22 t ha-1 y-1 causing a CO2 emission of 20 - 40 t ha-1 y-1. Together with the associated N2O emissions from mineralized N this totals in the EU to about 98.5 Mton CO2 eq per year. Peat soils are very prone to climate change and it is expected that at the end of this century these values are doubled. The degradation products pollute surface waters. Wind erosion of peat soils in arable agriculture can cause losses of 3 - 30 t ha-1 y-1 peat also causing air pollution (fine organic particles). Subsidence rates are 1 - 2 cm per year which leads to deteriorating drainage effect and make peat soils below sea or inland water levels prone to flooding. Flooding agricultural peat soils is in many cases not possible without high costs, high GHG emissions and severe water pollution. Moreover sometimes cultural and historic landscapes are lost and meadow birds areas are lost. In areas where the possibility to regulate the water table is limited the mitigation options are either to increase biomass production that can be used as bioenergy to substitute some fossil fuel, try to slow down the break-down of the peat by different amendments that inhibit microbial activity, or permanent flooding. The negative effects of wind erosion can be mitigated by reducing wind speed or different ways to protect the soil by crops or fiber sheets. In a newly started project in Sweden a typical peat soil with and without amendment of foundry sand is cropped with reed canary grass, tall fescue and timothy to investigate the yield and greenhouse gas emissions from the different crops and how the sand effect the trafficability and GHG emissions.

  17. Peat pyrolysis and the analytical semi-empirical model

    SciTech Connect

    Feng, J.; Green, A.E.S.

    2007-07-01

    Pyrolysis of peat could convert this material into useful fuels and valuable hydrocarbons. A study of peat pyrolysis can also serve as a useful bridge between studies of coal pyrolysis and biomass pyrolysis. Using an analytical model of pyrolysis that has previously been applied to biomass and to coal, we present here the results of applications of this model to a representative peat. The analysis suggests means of organizing and processing rate and yield data that should be useful in applications of pyrolysis for the production of fuels and chemicals.

  18. Speciated organic VOC and PM emissions from peat burns

    EPA Pesticide Factsheets

    Supporting information Tables S3 and S4 list emission factors in g/kg of speciated volatile and particulate organic compounds emitted from peat burning. Peat samples were acquired from Alligator River (AR) and Pocosin Lakes (PL) National Wildlife Refuges. This dataset is associated with the following publication:George , I., R. Black, J. Walker , C. Geron , J. Aurell , M. Hays , W. Preston, and B. Gullett. Volatile and semivolatile organic compounds in laboratory peat fire emissions. ATMOSPHERIC ENVIRONMENT. Elsevier Science Ltd, New York, NY, USA, 132: 163-170, (2016).

  19. Geochemical characteristics of peat from two raised bogs of Germany

    NASA Astrophysics Data System (ADS)

    Mezhibor, A. M.

    2016-11-01

    Peat has a wide range of applications in different spheres of human activity, and this is a reason for a comprehensive study. This research represents the results of an ICP-MS study of moss and peat samples from two raised bogs of Germany. Because of the wide use of sphagnum moss and peat, determining their geochemical characteristics is an important issue. According to the results obtained, we can resume that the moss samples from Germany are rich in Cu, As, Y, Zr, Nb, and REE. The geochemical composition of the bogs reflects the regional environmental features and anthropogenic influence.

  20. Biochemical processes of oligotrophic peat deposits of Vasyugan Mire

    NASA Astrophysics Data System (ADS)

    Inisheva, L. I.; Sergeeva, M. A.

    2009-04-01

    The problem of peat and mire ecosystems functioning and their rational use is the main problem of biosphere study. This problem also refers to forecasting of biosphere changes results which are global and anthropogenic. According to many scientists' research the portion of mires in earth carbon balance is about 15% of world's stock. The aim of this study is to investigate biochemical processes in oligotrophic deposits in North-eastern part of Vasyugan Mire. The investigations were made on the territory of scientific-research ground (56˚ 03´ and 56˚ 57´ NL, 82˚ 22´ and 82˚ 42´ EL). It is situated between two rivers Bakchar and Iksa (in outskirts of the village Polynyanka, Bakchar region, Tomsk oblast). Evolution of investigated mire massif began with the domination of eutrophic phytocenosis - Filicinae, then sedge. Later transfer into oligotrophic phase was accompanied by formation of meter high-moor peat deposit. The age of three-meter peat deposit reaches four thousand years. Biochemical processes of carbon cycle cover the whole peat deposit, but the process activity and its direction in different layers are defined by genesis and duration of peat formation. So, the number of cellulose-fermenting aerobes in researched peat deposits ranges from 16.8 to 75.5 million CFU/g, and anaerobic bacteria from 9.6 to 48.6 million CFU/g. The high number of aerobes is characteristic for high water levels, organizing by raised bog peats. Their number decreases along the profile in 1.7 - 2 times. The number of microflora in peat deposit is defined by the position in the landscape profile (different geneses), by the depth, by hydrothermic conditions of years and individual months. But microflora activity shows along all depth of peat deposit. We found the same in the process of studying of micromycete complex structure. There was revealed either active component micromycete complex - mycelium, or inert one - spores in a meter layer of peat deposit. If mushrooms

  1. Comparison of heavy metal immobilization in contaminated soils amended with peat moss and peat moss-derived biochar.

    PubMed

    Park, Jin Hee; Lee, Seul-Ji; Lee, Myoung-Eun; Chung, Jae Woo

    2016-04-01

    There have been contradictory viewpoints whether soil amendments immobilize or mobilize heavy metals. Therefore, this study evaluated the mobility and bioavailability of Pb, Cu, and Cd in contaminated soil (1218 mg Pb per kg, 63.2 mg Cu per kg, 2.8 mg Cd per kg) amended with peat moss (0.22, 0.43, and 1.29% carbon ratio) and peat moss-derived biochar (0.38, 0.75, and 2.26% carbon ratio) at 0.5, 1, 3% levels. The more peat moss added, the stronger both mobility and bioavailability of Pb, Cu, and Cd would be. In contrast, the addition of peat moss-derived biochar significantly reduced both mobility and bioavailability of heavy metals through the coordination of metal electrons to C[double bond, length as m-dash]C (π-electron) bonds and increased pH. Maximum immobilization was observed in 3% peat moss-derived biochar treatment after 10 days of incubation, which was measured at 97.8%, 100%, and 77.2% for Pb, Cu, and Cd, respectively. Since peat moss and peat moss-derived biochar showed conflicting effectiveness in mobility and bioavailability of heavy metals, soil amendments should be carefully applied to soils for remediation purposes.

  2. Subsidence control over abandoned mines

    SciTech Connect

    Nazimko, V.V.

    1996-12-01

    Long term stability of the pillars that have been remained after R&P extraction causes postponed subsidence. To prevent unforeseen subsidence and to diminish postponed subsidence 25-50% new method for its control has been developed by the author. It supposes to use drilling and blasting technology and other original approaches. New method has been fulfilled through the holes being drilled from the surface or from the active underground openings. Explosives had been charged into the holes and were blasted. This had increased bulking factor dramatically and prevented natural caving of the strata. Physical scale modeling corroborated efficiency of the new approach. The bulking factor has grown from 0.0623 to 0.1185 and surface subsidence has been diminished from 1.1 m to 0.2 m or 5.5 times.

  3. 32 CFR 636.31 - Abandoned vehicles.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... § 636.31 Abandoned vehicles. (a) Any MP or DOD police officer who finds or has knowledge of a motor... MP or DOD police officer who, under the provisions of this section, causes any motor vehicle to be... motor vehicle by any MP or DOD police officer should not be within the scope of either that...

  4. Towards Understanding Methane Emissions from Abandoned Wells

    EPA Science Inventory

    Reconciliation of large-scale top-down methane measurements and bottom-up inventories requires complete accounting of source types. Methane emissions from abandoned oil and gas wells is an area of uncertainty. This presentation reviews progress to characterize the potential inv...

  5. 18 CFR 157.216 - Abandonment.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... Interstate Pipeline Blanket Certificates and Authorization Under Section 7 of the Natural Gas Act for Certain... abandon: (1) Any receipt or delivery point if all of the existing customers of the pipeline served through...) showing the location of the proposed facilities and a concise analysis discussing the relevant...

  6. 18 CFR 157.216 - Abandonment.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... Interstate Pipeline Blanket Certificates and Authorization Under Section 7 of the Natural Gas Act for Certain... abandon: (1) Any receipt or delivery point if all of the existing customers of the pipeline served through...) showing the location of the proposed facilities and a concise analysis discussing the relevant...

  7. 18 CFR 157.216 - Abandonment.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... Interstate Pipeline Blanket Certificates and Authorization Under Section 7 of the Natural Gas Act for Certain... abandon: (1) Any receipt or delivery point if all of the existing customers of the pipeline served through...) showing the location of the proposed facilities and a concise analysis discussing the relevant...

  8. 32 CFR 636.31 - Abandoned vehicles.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 32 National Defense 4 2010-07-01 2010-07-01 true Abandoned vehicles. 636.31 Section 636.31 National Defense Department of Defense (Continued) DEPARTMENT OF THE ARMY (CONTINUED) LAW ENFORCEMENT AND CRIMINAL INVESTIGATIONS MOTOR VEHICLE TRAFFIC SUPERVISION (SPECIFIC INSTALLATIONS) Fort Stewart,...

  9. Alfred P. Dachnowski and the scientific study of peats

    USGS Publications Warehouse

    Landa, E.R.; Cohen, K.M.

    2011-01-01

    Botanist Alfred Paul Dachnowski (1875–1949) was a major contributor to efforts at mapping organic soils in the United States during the early 20th century. He began his career at The Ohio State University, and spent most of his professional life at the U.S. Department of Agriculture in Washington, DC. His work spanned a diversity of topics, including bog ecology and the ecosystem services provided by wetlands, the mapping and chemical characterization of peat, and the commercial applications of peat. We present a biography and overview of his work. Dachnowski is best known today for the peat sampler that bears his name. The details of its operation are described here, and its place in modern peat studies is discussed.

  10. 4. INTERIOR OF ABANDONED SANTA ANA CANAL TUNNEL, SHOWING CEMENT ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    4. INTERIOR OF ABANDONED SANTA ANA CANAL TUNNEL, SHOWING CEMENT TROUGH FLOOR AND UNFINISHED GRANITE ROOF. VIEW TO SOUTHWEST. - Santa Ana River Hydroelectric System, Abandoned Tunnel, Redlands, San Bernardino County, CA

  11. Effect of Peat on Physicomechanical Properties of Cemented Brick

    PubMed Central

    Hashim, Roslan; Kurnia, Ryan

    2014-01-01

    The popularity of low cost, lightweight, and environmentally affable masonry unit in building industry carries the need to investigate more flexible and adaptable brick component as well as to retain the requirements confirmed in building standards. In this study, potential use of local materials used as lightweight building materials in solving the economic problems of housing has been investigated. Experimental studies on peat added bricks have been carried out. It demonstrates the physicomechanical properties of bricks and investigates the influence of peat, sand, and cement solid bricks to the role of various types of constructional applications. The achieved compressive strength, spitting strength, flexural strength, unit weight, and ultrasonic pulse velocity are significantly reduced and the water absorption is increased with percentage wise replacement of peat as aggregate in the samples. The maximum 20% of (% mass) peat content meets the requirements of relevant well-known international standards. The experimental values illustrate that, the 44% volumetric replacement with peat did not exhibit any sudden brittle fracture even beyond the ultimate loads and a comparatively smooth surface is found. The application of peat as efficient brick substance shows a potential to be used for wall and a viable solution in the economic buildings design. PMID:24982941

  12. Effect of peat on physicomechanical properties of cemented brick.

    PubMed

    Islam, Syed Mofachirul; Hashim, Roslan; Islam, A B M Saiful; Kurnia, Ryan

    2014-01-01

    The popularity of low cost, lightweight, and environmentally affable masonry unit in building industry carries the need to investigate more flexible and adaptable brick component as well as to retain the requirements confirmed in building standards. In this study, potential use of local materials used as lightweight building materials in solving the economic problems of housing has been investigated. Experimental studies on peat added bricks have been carried out. It demonstrates the physicomechanical properties of bricks and investigates the influence of peat, sand, and cement solid bricks to the role of various types of constructional applications. The achieved compressive strength, spitting strength, flexural strength, unit weight, and ultrasonic pulse velocity are significantly reduced and the water absorption is increased with percentage wise replacement of peat as aggregate in the samples. The maximum 20% of (% mass) peat content meets the requirements of relevant well-known international standards. The experimental values illustrate that, the 44% volumetric replacement with peat did not exhibit any sudden brittle fracture even beyond the ultimate loads and a comparatively smooth surface is found. The application of peat as efficient brick substance shows a potential to be used for wall and a viable solution in the economic buildings design.

  13. Volatile and semivolatile organic compounds in laboratory peat fire emissions

    NASA Astrophysics Data System (ADS)

    George, Ingrid J.; Black, Robert R.; Geron, Chris D.; Aurell, Johanna; Hays, Michael D.; Preston, William T.; Gullett, Brian K.

    2016-05-01

    In this study, volatile and semi-volatile organic compound (VOCs and SVOCs) mass emission factors were determined from laboratory peat fire experiments. The peat samples originated from two National Wildlife Refuges on the coastal plain of North Carolina, U.S.A. Gas- and particle-phase organic compounds were quantified by gas chromatography-mass spectrometry and by high pressure liquid chromatography. Hazardous air pollutants (HAPs) accounted for a large fraction (∼60%) of the speciated VOC emissions from peat burning, including large contributions of acetaldehyde, formaldehyde, benzene, toluene, and chloromethane. In the fine particle mass (PM2.5), the following organic compound classes were dominant: organic acids, levoglucosan, n-alkanes, and n-alkenes. Emission factors for the organic acids in PM2.5 including n-alkanoic acids, n-alkenoic acids, n-alkanedioic acids, and aromatic acids were reported for the first time for peat burning, representing the largest fraction of organic carbon (OC) mass (11-12%) of all speciated compound classes measured in this work. Levoglucosan contributed to 2-3% of the OC mass, while methoxyphenols represented 0.2-0.3% of the OC mass on a carbon mass basis. Retene was the most abundant particulate phase polycyclic aromatic hydrocarbon (PAH). Total HAP VOC and particulate PAH emissions from a 2008 peat wildfire in North Carolina were estimated, suggesting that peat fires can contribute a large fraction of state-wide HAP emissions.

  14. Influence of Biodegradation on the Organic Compounds Composition of Peat.

    NASA Astrophysics Data System (ADS)

    Serebrennikova, Olga; Svarovskaya, Lidiya; Duchko, Maria; Strelnikova, Evgeniya; Russkikh, Irina

    2016-06-01

    Largest wetland systems are situated on the territory of the Tomsk region. They are characterized by the high content of organic matter (OM), which undergoes transformation as a result of physical, chemical and biological processes. The composition of peat OM is determined by the nature of initial peat-forming plants, their transformation products and bacteria. An experiment in stimulated microbial impact was carried out for estimating the influence of biodegradation on the composition of peat lipids. The composition of the functional groups in the bacterial biomass, initial peat and peat after biodegradation was determined by IR-spectroscopy using the spectrometer NICOLET 5700. The IR spectra of peat and bacteria organic matter are characterized by the presence of absorption bands in ranges: 3400-3200 cm-1, which refers to the stretching vibrations of OH-group of carboxylic acids and various types of hydrogen bonds; 1738-1671 cm-1 - characteristic stretching vibrations of the C = O group of carboxylic acids and ketones; 1262 cm-1 - stretching vibrations of C-O of carboxylic acids. Group and individual composition of organic compounds in studied samples was determined by gas chromatography-mass-spectrometry.

  15. Evaluation of the VIIRS Land Algorithms at Land PEATE

    NASA Technical Reports Server (NTRS)

    Wolfe, Robert E.; Devadiga, Sadashiva; Ye, Gang; Masuoka, Edward J.; Schweiss, Robert J.

    2010-01-01

    The Land Product Evaluation and Algorithm Testing Element (Land PEATE), a component of the Science Data Segment of the National Polar-orbiting Operational Environmental Satellite System (NPOESS) Preparatory Project (NPP), is being developed at the NASA Goddard Space Flight Center (GSFC). The primary task of the Land PEATE is to assess the quality of the Visible Infrared Imaging Radiometer Suite (VIIRS) Land data products made by the Interface Data Processing System (IDPS) using the Operational (OPS) Code during the NPP era and to recommend improvements to the algorithms in the IDPS OPS code. The Land PEATE uses a version of the MODIS Adaptive Processing System (MODAPS), NPPDAPS, that has been modified to produce products from the IDPS OPS code and software provided by the VIIRS Science Team, and uses the MODIS Land Data Operational Product Evaluation (LDOPE) team for evaluation of the data records generated by the NPPDAPS. Land PEATE evaluates the algorithms by comparing data products generated using different versions of the algorithm and also by comparing to heritage products generated from different instrument such as MODIS using various quality assessment tools developed at LDOPE. This paper describes the Land PEATE system and some of the approaches used by the Land PEATE for evaluating the VIIRS Land algorithms during the pre-launch period of the NPP mission and the proposed plan for long term monitoring of the quality of the VIIRS Land products post-launch.

  16. 30 CFR 256.56 - Lease-specific abandonment accounts.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 2 2010-07-01 2010-07-01 false Lease-specific abandonment accounts. 256.56... OF SULPHUR OR OIL AND GAS IN THE OUTER CONTINENTAL SHELF Bonding § 256.56 Lease-specific abandonment accounts. (a) The Regional Director may authorize you to establish a lease-specific abandonment account...

  17. Non-Abandonment as a Foundation for Inclusive School Practice

    ERIC Educational Resources Information Center

    Razer, Michal; Friedman, Victor J.

    2013-01-01

    The authors of this article describe an essential feature of inclusive educational practice: "non-abandonment". When students' needs and difficult behavior are overwhelming, teachers may abandon them emotionally as a defensive reaction to their own experience of emotional distress and helplessness. Non-abandonment represents a…

  18. 25 CFR 214.29 - Prospecting; abandonment of mines.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... RESERVATION LANDS, OKLAHOMA, FOR MINING, EXCEPT OIL AND GAS § 214.29 Prospecting; abandonment of mines. All prospecting or mining operations or the abandonment of a well or mine shall be subject to the approval of the... 25 Indians 1 2010-04-01 2010-04-01 false Prospecting; abandonment of mines. 214.29 Section...

  19. 19 CFR 18.44 - Abandonment of exportation.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... Control Exported Under Cover of A Tir Carnet § 18.44 Abandonment of exportation. In the event that exportation is abandoned at any time after merchandise has been placed under cover of a TIR carnet, the... 19 Customs Duties 1 2010-04-01 2010-04-01 false Abandonment of exportation. 18.44 Section...

  20. 30 CFR 900.14 - Abandoned mine land programs.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 3 2013-07-01 2013-07-01 false Abandoned mine land programs. 900.14 Section 900.14 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND ENFORCEMENT, DEPARTMENT OF THE... Abandoned mine land programs. Programs for reclamation of abandoned mine lands are codified under...

  1. 30 CFR 900.14 - Abandoned mine land programs.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 30 Mineral Resources 3 2014-07-01 2014-07-01 false Abandoned mine land programs. 900.14 Section 900.14 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND ENFORCEMENT, DEPARTMENT OF THE... Abandoned mine land programs. Programs for reclamation of abandoned mine lands are codified under...

  2. 30 CFR 900.14 - Abandoned mine land programs.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 3 2012-07-01 2012-07-01 false Abandoned mine land programs. 900.14 Section 900.14 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND ENFORCEMENT, DEPARTMENT OF THE... Abandoned mine land programs. Programs for reclamation of abandoned mine lands are codified under...

  3. 30 CFR 900.14 - Abandoned mine land programs.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 3 2010-07-01 2010-07-01 false Abandoned mine land programs. 900.14 Section 900.14 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND ENFORCEMENT, DEPARTMENT OF THE... Abandoned mine land programs. Programs for reclamation of abandoned mine lands are codified under...

  4. 30 CFR 57.4011 - Abandoned electric circuits.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Abandoned electric circuits. 57.4011 Section 57.4011 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL... and Control § 57.4011 Abandoned electric circuits. Abandoned electric circuits shall be...

  5. 30 CFR 57.4011 - Abandoned electric circuits.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Abandoned electric circuits. 57.4011 Section 57.4011 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL... and Control § 57.4011 Abandoned electric circuits. Abandoned electric circuits shall be...

  6. 30 CFR 57.4011 - Abandoned electric circuits.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Abandoned electric circuits. 57.4011 Section 57.4011 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL... and Control § 57.4011 Abandoned electric circuits. Abandoned electric circuits shall be...

  7. 30 CFR 56.4011 - Abandoned electric circuits.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Abandoned electric circuits. 56.4011 Section 56.4011 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL... Control § 56.4011 Abandoned electric circuits. Abandoned electric circuits shall be deenergized...

  8. 30 CFR 56.4011 - Abandoned electric circuits.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Abandoned electric circuits. 56.4011 Section 56.4011 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL... Control § 56.4011 Abandoned electric circuits. Abandoned electric circuits shall be deenergized...

  9. 30 CFR 56.4011 - Abandoned electric circuits.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Abandoned electric circuits. 56.4011 Section 56.4011 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL... Control § 56.4011 Abandoned electric circuits. Abandoned electric circuits shall be deenergized...

  10. 30 CFR 57.4011 - Abandoned electric circuits.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 1 2013-07-01 2013-07-01 false Abandoned electric circuits. 57.4011 Section 57.4011 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL... and Control § 57.4011 Abandoned electric circuits. Abandoned electric circuits shall be...

  11. 30 CFR 57.4011 - Abandoned electric circuits.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Abandoned electric circuits. 57.4011 Section 57.4011 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL... and Control § 57.4011 Abandoned electric circuits. Abandoned electric circuits shall be...

  12. 30 CFR 56.4011 - Abandoned electric circuits.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Abandoned electric circuits. 56.4011 Section 56.4011 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL... Control § 56.4011 Abandoned electric circuits. Abandoned electric circuits shall be deenergized...

  13. 30 CFR 56.4011 - Abandoned electric circuits.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 1 2013-07-01 2013-07-01 false Abandoned electric circuits. 56.4011 Section 56.4011 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL... Control § 56.4011 Abandoned electric circuits. Abandoned electric circuits shall be deenergized...

  14. 15-ky Peat Paleo-Monsoon Reconstructions from Lipid Biomarker Contents of Three Bogs in China

    NASA Astrophysics Data System (ADS)

    Zhou, W.; Zheng, Y.; Meyers, P. A.; Xie, S.

    2007-12-01

    Paleoclimate reconstructions based on lipid biomarkers from peat bogs are relatively uncommon, although this approach has been widely applied to lake sediments where it yields important histories of climate-related changes in types of vegetation and organic matter preservation. We describe stratigraphic patterns in peat lipid biomarker distributions extracted from three well-dated peat cores. One core is from the Dingnan bog on the border of Guangdong and Jiangxi Provinces of southeastern China. A second core is from the Zoige-Hongyuan bog, which is on the Qinghai-Xizang Plateau of west China on the northeast edge of the Tibetan Plateau. The third peat core is from a shallow lake that is the source of the Hani River in Jiling Province of northeastern China. The combination of the three locations provides a broad regional history of the evolution of monsoon-influenced climate in China from the late-glacial through the Holocene. The start of peat accumulation in these locations at about 15 ka indicates the onset of wetter post-glacial climate. A period of warmer climate corresponding to the Holocene Optimum between 9 ka to 5 ka is evident in greater alterations of n-alkanoic acids and n-alkanols and in the appearance of biomarkers diagnostic of greater microbial activity. Changes in local precipitation that raised the water level of the Zoige-Hongyuan bog are indicated by increases in the proportions of C23 and C25 n- alkanes that are mainly derived from submerged/floating plants and by conversion of the Dingnan bog to a lake. Alternations in submergent and emergent plant n-alkane proxies reveal millennial scale rises and falls of the water level in these bogs, thereby reflecting variations in East Asian and Indian Ocean monsoon precipitation during the Holocene. These events correlate well with cold-dry events recorded in same regions by other climatic proxies. Our results reflect Holocene instability in the Asian monsoon system and indicate that millennial

  15. Impact of catchment degree on peat properties in peat deposits of eutrophic bog

    NASA Astrophysics Data System (ADS)

    Inisheva, L. I.; Golubina, O. A.; Rodikova, A. V.; Shinkeeva, N. A.; Bubina, A. B.

    2010-05-01

    Fundamental works of many investigators show that according to the biophysical properties peat deposit (PD) is divided into 2 layers: active and inert. It is interesting to analyze the supposed changes in PD of eutrophic bog according to different data (physical, chemical and biological). The researches were carried out at two plots of one bog (points 1 and 2, positions 56° 21' NL, 84° 47' EL, Russia, Siberia). Agricultural afforestation (pine planting) was made at one of them (point 2) 60 years ago. Now this plot is absolutely identical in ground cover to 1 point, but other conditions are significantly changed. In spring bog water level is at the depth of 20cm at 2 point (at 1 point it is near water face), it lows up to 53 cm during summer time (at 1 point - up to 37 cm). According to redox conditions zone of anoxic-oxic conditions reaches meter depth at 2 points. PDs don't significantly differ in activity of ammonifiers but in activity of cellulose-lytic aerobic microflora it follows that it is more active at 2 point in PD active layer. In spite of good aeration, more favorable conditions were created also for anaerobic cellulose-fermenting microflora in PD of 2 point in comparison with 1 one. Activity analysis of denitrifying agents and microflora of other physiological groups also showed high activity of biota at the plot with afforestation amelioration. This fact was confirmed by high coefficient of mineralization. Time of drainage effect created by afforestation amelioration influenced group composition of peat organic matter which builds up PD of examined plots. According to fractional and group composition data fracture of hard-to-hydrolyze organic matters decreased during the process of microflora activating at the plot with afforestation amelioration but FA content increased. Fractional composition of nitrogen showed that content of mineral nitrogen compounds definitely increased. Thus, 60 years of surface drainage influenced composition change of peat

  16. Oxidation of organosulfur-coordinated arsenic and realgar in peat: implications for the fate of arsenic.

    PubMed

    Langner, Peggy; Mikutta, Christian; Kretzschmar, Ruben

    2014-02-18

    Organosulfur-coordinated As(III) and realgar (α-As4S4) have been identified as the dominant As species in the naturally As-enriched minerotrophic peatland Gola di Lago, Switzerland. In this study, we explored their oxidation kinetics in peat exposed to atmospheric O2 for up to 180 days under sterile and nonsterile conditions (25 °C, ∼ 100% relative humidity). Anoxic peat samples were collected from a near-surface (0-38 cm) and a deep peat layer (200-250 cm) and studied by bulk As, Fe, and S K-edge X-ray absorption spectroscopy as well as selective extractions as a function of time. Over 180 days, only up to 33% of organosulfur-coordinated As(III) and 44% of realgar were oxidized, corresponding to half-life times, t1/2, of 312 and 215 days, respectively. The oxidation of both As species was mainly controlled by abiotic processes. Realgar was oxidized orders of magnitude slower than predicted from published mixed-flow reactor experiments, indicating that mass-transfer processes were rate-limiting. Most of the As released (>97%) was sequestered by Fe(III)-(hydr)oxides. However, water-extractable As reached concentrations of 0.7-19 μmol As L(-1), exceeding the WHO drinking water limit by up to 145 times. Only a fraction (20-36%) of reduced S(-II to I) was sensitive to oxidation and was oxidized faster (t1/2 = 50-173 days) than organosulfur-coordinated As(III) and realgar, suggesting a rapid loss of reactive As-sequestering S species following a drop in the water table. Our results imply that wetlands like Gola di Lago can serve as long-term sources for As under prolonged oxidizing conditions. The maintenance of reducing conditions is thus regarded as the primary strategy in the management of this and other As-rich peatlands.

  17. 76 FR 31008 - CSX Transportation, Inc.-Abandonment Exemption-in Erie County, NY

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-05-27

    ... Abandonments to abandon an approximately 0.56-mile rail line on its Northern Region, Albany Division, Buffalo... abandonment shall be protected under Oregon Short Line Railroad--Abandonment Portion Goshen Branch...

  18. Re-vegetation processes in cutaway peat production fields in Estonia in relation to peat quality and water regime.

    PubMed

    Orru, Mall; Ots, Katri; Orru, Hans

    2016-12-01

    Eighty-one cutaway peat production fields with a total area of about 9000 ha exist and were studied in Estonia in 2005-2015. Only a very small number of the fields (seven) have been restored-either afforested or used for growing berries. The re-vegetation of Estonian cutaway peat production fields is mainly the result of natural processes, which are generally very slow due to an unfavourable water regime or a too thin remaining peat layer. The fields are mostly covered by cotton grass and birches. Often sparse vegetation covers 15-20% of a peat field, but some fields have turned into heaths or grasslands with plant coverage up to 60%. However, due to changes in environmental (mainly hydrological) conditions and peat characteristics (mainly peat type), these areas can also be new niches for several species. A number of moss species new to or rare in Estonia, e.g. Pohlia elongata, Ephemerum serratum, Campylopus introflexus and Bryum oblongum, were recorded.

  19. Biomarkers in a peat deposit in Northern Spain (Huelga de Bayas, Asturias) as proxy for climate variation.

    PubMed

    López-Días, V; Borrego, A G; Blanco, C G; Arboleya, M; López-Sáez, J A; López-Merino, L

    2010-05-21

    Peatlands are peculiar ecosystems in which well-adapted communities grow and develop, recording the variation in climate and hydrological conditions inland. In addition necromass is well preserved and therefore peatlands can be used as palaeo-archives for environmental variation. In this work a peat core of depth 60 cm dated at the bottom of the peat deposit as ca. 250cal AD from Huelga de Bayas (Asturias, Northern Spain) was studied to a resolution of 2-4 cm to investigate the evolution of the environmental conditions in the area. Samples were extracted with a dichloromethane/methanol ratio of 3:1 and studied by means of gas chromatography (GC) and mass spectrometry (GC-MS) in order to identify possible biomarkers of climatic variation during the period of peat formation. Lipid biomarker study allows the identification of periods in which Sphagnum or higher plants preferentially contributed to the peat profile. The absolute dating of the profile combined with the n-alkane record displayed five episodes of wetter conditions around ca. 250 cal AD (Roman Warm Period), 1080 and 1270 cal AD (Medieval Warm Period), 1460 cal AD (Little Ice Age) and 1920 cal AD (Recent warming), which are consistent with climate evolution in the region. Pentacyclic triterpenoids with hopane skeleton derived from microorganisms and with oleanane skeleton derived from higher plants were identified. The presence of their ketone and acetyl-derivatives, along with the presence of unstable hopane configurations indicates a low maturity of the peat profile. A tendency for the functionalised triterpenoids to decrease with depth was observed in the profile.

  20. Paenibacillus alba nov., isolated from peat soil.

    PubMed

    Kim, Hyun-Sook; Srinivasan, Sathiyaraj; Lee, Sang-Seob

    2015-06-01

    A white-colored bacterial strain designated J20-6(T) was isolated from peat soil collected in Russia. Based on the 16S rRNA gene sequence similarities, the strain J20-6(T) belonged to the genus Paenibacillus, and the closest relatives were Paenibacillus frigoriresistens YIM 016(T) (98.2 %), Paenibacillus alginolyticus DSM 5050T(T) (97.9 %), Paenibacillus chondroitinus DSM 5051(T) (97.4 %), Paenibacillus pocheonensis Gsoil 1138(T) (96.9 %), and Paenibacillus pectinilyticus RCB-08(T) (96.6 %). Cells are gram-positive, motile, facultative aerobic, endospore forming, and rod shaped. The cell wall contains MK-7 as the predominant menaquinone and meso-diaminopimelic acid as the diagnostic diamino acid. The major fatty acid is anteiso-C15:0, and the major polar lipids are diphosphatidylglycerol and phosphatidyl-ethanolamine. The DNA G+C content of the strain J20-6(T) was 49.9 mol %. The phenotypic, chemotaxonomic, and phylogenetic data clearly suggest that the strain J20-6(T) belongs to the novel member of the genus Paenibacillus, for which the name Paenibacillus alba sp. nov., is proposed. The type strain is J20-6(T) (=KEMC 7302-005(T) = JCM 18165(T)).

  1. Understanding Peat Bubbles: Biogeochemical-Hydrological Linkages

    NASA Astrophysics Data System (ADS)

    Strack, M.

    2009-05-01

    Decomposition of organic matter in peatland ecosystems produces gaseous end-products that can accumulate at depth and result in the build up of free-phase gas below the water table. This free-phase gas, or bubbles, reduces hydraulic conductivity, alters hydrologic and chemical gradients, and affects productivity surface vegetation through its role in peat buoyancy. In terms of greenhouse gas dynamics, these bubbles are likely the dominant subsurface stock of methane (CH4) and release of this CH4 to the atmosphere via ebullition may account for a significant portion of total efflux. Despite the importance of entrapped bubbles for peatland ecohydrological function there is still little known about how the quantity of bubbles varies between peatland types and at smaller scales within a peatland. Profiles of bubbles collected from several locations within four peatlands reveal that bubble volume varies significant among peatlands, between microforms and with depth. Previous studies also suggest that ebullition is spatially and temporally variable. This spatial variability may have important impacts on system ecohydrology and should be incorporated in models of peatland hydrology and development. This requires the difficult task of mapping bubble volume in three dimensions and over large areas. The potential for geophysical methods and the use of surface features to address this task will be discussed.

  2. Isotope evidence for N2-fixation in Sphagnum peat bogs

    NASA Astrophysics Data System (ADS)

    Novak, Martin; Jackova, Ivana; Buzek, Frantisek; Stepanova, Marketa; Veselovsky, Frantisek; Curik, Jan; Prechova, Eva

    2016-04-01

    Waterlogged organic soils store as much as 30 % of the world's soil carbon (C), and 15 % of the world's soil nitrogen (N). In the era of climate change, wetlands are vulnerable to increasing temperatures and prolonged periods of low rainfall. Higher rates of microbial processes and/or changing availability of oxygen may lead to peat thinning and elevated emissions of greenhouse gases (mostly CO2, but also CH4 and N2O). Biogeochemical cycling of C and N in peat bogs is coupled. Under low levels of pollution by reactive nitrogen (NO3-, NH4+), increasing N inputs may positively affect C storage in peat. Recent studies in North America and Scandinavia have suggested that pristine bogs are characterized by significant rates of microbial N2 fixation that augments C storage in the peat substrate. We present a nitrogen isotope study aimed at corroborating these findings. We conducted an isotope inventory of N fluxes and pools at two Sphagnum-dominated ombrotrophic peat bogs in the Czech Republic (Central Europe). For the first time, we present a time-series of del15N values of atmospheric input at the same locations as del15N values of living Sphagnum and peat. The mean del15N values systematically increased in the order: input NH4+ (-10.0 ‰) < input NO3- (-7.9 ‰) < peat porewater (-5.6 ‰) < Sphagnum (-5.0 ‰) < shallow peat (-4.2 ‰) < deep peat (-2.2 ‰) < runoff (-1.4 ‰) < porewater N2O (1.4 ‰). Importantly, N of Sphagnum was isotopically heavier than N of the atmospheric input (p < 0.001). If partial incorporation of reactive N from the atmosphere into Sphagnum was isotopically selective, the residual N would have to be isotopically extremely light. Such N, however, was not identified anywhere in the ecosystem. Alternatively, Sphagnum may have contained an admixture of isotopically heavier N from atmospheric N2 (del15N N2 = 0 ‰). We conlude that the N isotope systematics at the two Czech sites is consistent with the concept of significant N2 fixation

  3. A Study on the Thermal Characteristics of Space Abandoned Satellites

    NASA Astrophysics Data System (ADS)

    Shaohua, Zhang

    Abstract: Influenced by the limited space resources and the increased space debris, it is very exigent to clean the orbital abandoned satellite. The thermal characteristic of the abandoned satellite is a key parameter for the infrared radiation study, and it is also an important gist to estimate whether or not the satellite can be worked correctly. And this paper researched on the thermal analysis of the LEO and GEO abandoned satellite, and has been acquired the temperature variety law for the the space abandoned target, which is very significant for apperceiving the space situation and cleaning the space abandoned satellites and other debris initiatively.    

  4. Explosives remain preferred methods for platform abandonment

    SciTech Connect

    Pulsipher, A.; Daniel, W. IV; Kiesler, J.E.; Mackey, V. III

    1996-05-06

    Economics and safety concerns indicate that methods involving explosives remain the most practical and cost-effective means for abandoning oil and gas structures in the Gulf of Mexico. A decade has passed since 51 dead sea turtles, many endangered Kemp`s Ridleys, washed ashore on the Texas coast shortly after explosives helped remove several offshore platforms. Although no relationship between the explosions and the dead turtles was ever established, in response to widespread public concern, the US Minerals Management Service (MMS) and National Marine Fisheries Service (NMFS) implemented regulations limiting the size and timing of explosive charges. Also, more importantly, they required that operators pay for observers to survey waters surrounding platforms scheduled for removal for 48 hr before any detonations. If observers spot sea turtles or marine mammals within the danger zone, the platform abandonment is delayed until the turtles leave or are removed. However, concern about the effects of explosives on marine life remains.

  5. Abandoned metal mine stability risk evaluation.

    PubMed

    Bétournay, Marc C

    2009-10-01

    The abandoned mine legacy is critical in many countries around the world, where mine cave-ins and surface subsidence disruptions are perpetual risks that can affect the population, infrastructure, historical legacies, land use, and the environment. This article establishes abandoned metal mine failure risk evaluation approaches and quantification techniques based on the Canadian mining experience. These utilize clear geomechanics considerations such as failure mechanisms, which are dependent on well-defined rock mass parameters. Quantified risk is computed using probability of failure (probabilistics using limit-equilibrium factors of safety or applicable numerical modeling factor of safety quantifications) times a consequence impact value. Semi-quantified risk can be based on failure-case-study-based empirical data used in calculating probability of failure, and personal experience can provide qualified hazard and impact consequence assessments. The article provides outlines for land use and selection of remediation measures based on risk.

  6. Why are pharmaceutical companies gradually abandoning vaccines?

    PubMed

    Offit, Paul A

    2005-01-01

    During the past fifty years, the number of pharmaceutical companies making vaccines has decreased dramatically, and those that still make vaccines have reduced resources to make new ones. Pharmaceutical companies are gradually abandoning vaccines because the research, development, testing, and manufacture of vaccines are expensive and because the market to sell vaccines is much smaller than the market for other drug products. Congressional action could assure both a steady supply of existing vaccines and the promise of vaccines for the future.

  7. Detecting abandoned objects using interacting multiple models

    NASA Astrophysics Data System (ADS)

    Becker, Stefan; Münch, David; Kieritz, Hilke; Hübner, Wolfgang; Arens, Michael

    2015-10-01

    In recent years, the wide use of video surveillance systems has caused an enormous increase in the amount of data that has to be stored, monitored, and processed. As a consequence, it is crucial to support human operators with automated surveillance applications. Towards this end an intelligent video analysis module for real-time alerting in case of abandoned objects in public spaces is proposed. The overall processing pipeline consists of two major parts. First, person motion is modeled using an Interacting Multiple Model (IMM) filter. The IMM filter estimates the state of a person according to a finite-state, discrete-time Markov chain. Second, the location of persons that stay at a fixed position defines a region of interest, in which a nonparametric background model with dynamic per-pixel state variables identifies abandoned objects. In case of a detected abandoned object, an alarm event is triggered. The effectiveness of the proposed system is evaluated on the PETS 2006 dataset and the i-Lids dataset, both reflecting prototypical surveillance scenarios.

  8. Environmental monitoring in peat bog areas by change detection methods

    NASA Astrophysics Data System (ADS)

    Michel, Ulrich; Mildes, Wiebke

    2016-10-01

    Remote sensing image analysis systems and geographic information systems (GIS) show great promise for the integration of a wide variety of spatial information supporting tasks such as urban and regional planning, natural resource management, agricultural studies and topographic or thematic mapping. Current and future remote sensing programs are based on a variety of sensors that will provide timely and repetitive multisensor earth observation on a global scale. GIS offer efficient tools for handling, manipulating, analyzing and presenting spatial data that are required for sensible decision making in various areas. The Environmental Monitoring project may serve as a convincing example of the operational use of integrated GIS/remote sensing technologies. The overall goal of the project is to assess the capabilities of satellite remote sensing for the analysis of land use changes, especially in moor areas. These areas are recognized as areas crucial to the mission of the Department of Environment and, therefore, to be placed under an extended level of protection. It is of critical importance, however, to have accurate and current information about the ecological and economic state of these sensitive areas. In selected pasture and moor areas, methods for multisensor data fusion have being developed and tested. The results of this testing show which techniques are useful for pasture and moor monitoring at an operational level. A hierarchical method is used for extracting bog land classes with respect to the environmental protection goals. A highly accurate classification of the following classes was accomplished: deciduous- and mixed forest, coniferous forest, water, very wet areas, meadowland/farmland with vegetation, meadowland/farmland with partly vegetation, meadowland/ farmland without vegetation, peat quarrying with maximum of 50% vegetation, de- and regeneration stages. In addition, a change detection analysis is performed in comparison with the existing

  9. RETENTION TIME EFFECT ON METAL REMOVAL BY PEAT COLUMNS

    SciTech Connect

    Nelson, E

    2007-02-28

    The potential use of a peat bed to treat the H-12 Outfall discharge to bring it to new compliance limits was previously investigated and reported utilizing a 7 hour retention time. The influence of retention time (contact time) of water with peat moss on the removal of copper from the water was investigated under laboratory conditions using vertical flow peat moss columns. Reduction of the necessary retention time has a large influence on the design sizing of any peat bed that would be constructed to treat the H-12 discharge on a full scale basis. Retention times of 5 hours, 3 hours and 1 hour were tested to determine the copper removal by the peat columns using vertical flow. Water samples were collected after 4, 8, 12, and 16 water volumes had passed through the columns and analyzed for a suite of metals, with quantitative emphasis on copper. Laboratory results indicated that copper removal was very high at each of the 3 retention times tested, ranging from 99.6 % removal at 5 and 3 hours to 98.8% removal at 1 hour. All these values are much lower that the new compliance limit for the outfall. The results also indicated that most divalent metals were removed to their normal reporting detection limit for the analytical methods used, including zinc. Lead levels in the H-12 discharge used in this study were below PQL in all samples analyzed. While each of the retention times studied removed copper very well, there were indications that 1 hour is probably too short for an operational, long-term facility. At that retention time, there was about 6% compaction of the peat in the column due to the water velocity, and this may affect long term hydraulic conductivity of the peat bed. At that retention time, copper concentration in the effluent was higher than the other times tested, although still very low. Because of the potential compacting and somewhat reduced removal efficiency at a 1 hour retention time, it would be prudent to design to at least a 3 hour retention

  10. Community heterogeneity of Early Pennsylvanian peat mires

    USGS Publications Warehouse

    Gastaldo, R.A.; Stevanovic-Walls, I. M.; Ware, W.N.; Greb, S.F.

    2004-01-01

    Reconstructions of Pennsylvanian coal swamps are some of the most common images of late Paleozoic terrestrial ecosystems. All reconstructions to date are based on data from either time-averaged permineralized peats or single-site collections. An erect, in situ Early Pennsylvanian forest preserved above the Blue Creek Coal, Black Warrior Basin, Alabama, was sampled in 17 localities over an area of >0.5 km2, resulting in the first temporally and spatially constrained Pennsylvanian mire data set. This three-tiered forest was heterogeneous. Lycopsid and calamitean trees composed the canopy, and lepidodendrids, Lepidophloios, and sigillarians grew together at most sites. More juvenile than mature lycopsid biomass occurs in the forest-floor litter, indicating a mixed-age, multicohort canopy. Pteridophytes (tree fern) and pteridosperms (seed fern) dominated as understory shrubs, whereas sphenophyllaleans, pteridophytes, and pteridosperms composed the ground-cover and liana tier. The proportion of canopy, understory, and ground-cover biomass varied across the forest. Low proportions of ground-cover and liana taxa existed where canopy fossils accounted for >60% of the litter. There is a distinct spatial clustering of sites with more or less understory (or ground cover) where canopy contribution was <60%. Where canopy biomass was low (<50%), understory shrubs contributed more biomass, indicative of light interception and/or competition strategies. Sphenopteris pottsvillea, a ubiquitous ground-cover plant, is abundant in all sites except one, where pteridosperm creepers and lianas dominate the litter, interpreted to indicate total suppression of other ground-cover growth. Ecological wet-dry gradients identified in other Pennsylvanian swamps do not exist in the Blue Creek mire, with the interpreted wettest (Lepidophloios), driest (Sigillaria), and intermediate (Lepidodendron sensu latu) taxa coexisting in most assemblages. ?? 2004 Geological Society of America.

  11. Magnitude and timing of peat-to-coal compaction

    SciTech Connect

    Nadon, G.C.

    1998-08-01

    The peat-to-coal transition is commonly assumed to be accompanied by compaction that decreases the thickness of the organic deposit to values of 10% or less of the original peat thickness. Decompaction modeling using such values for coal seams in contact with penecontemporaneous channel sandstones leads to impossible depositional geometries for the sandstones, which have a final thickness that is 90% of their original thickness. Similarly, decompaction modeling of the fragments of organic material within channel lags using the assumed large peat compaction value results in the destruction of the associated sedimentary structures, such as trough cross-beds. Dinosaur tracks in the roofs of coal mines show a shallow depth of penetration and a preservation of foot morphology that is not possible unless the peat the animals walked upon was very firm. These data confirm the macroscopic observations from coal balls that the compaction associated with the peat-to-coal transformation is minimal. Equally important, the data also show that most of the compaction occurs essentially at the surface and not at the depths where coalification takes place.

  12. Afobazole protects rats exposed to peat smoke in utero.

    PubMed

    Gorbatova, D M; Litvinova, S A; Durnev, A D; Seredenin, S B

    2015-03-01

    Female outbred albino rats were daily subjected to forced inhalations of peat smoke (4 cores packed with a mixture of peat (70%) and wood pulp (30%); 0.46 g, pH at least 5.5, core burning time 6 min,; total exposure 44 min) per se and in combination with oral afobazole (anxiolytic) in doses of 1 and 10 mg/kg on days 1-20 of pregnancy. Some groups of females received oral afobazole (200 mg/kg) after delivery, due to which their newborn rats received the drug in doses of 1-10 mg/kg with maternal milk on days 1-20 of life. Exposure to peat smoke inhibited body weight gain in the progeny on days 5-60 of life. Afobazole treatment during the pre- and postnatal periods prevented this effect. Open field testing showed that exposure to peat smoke prolonged the motor activity in the progeny and impaired the loss of orientation and exploratory behavior during repeated testing. Oral afobazole (1 and 10 mg/kg) during the prenatal and/or postnatal period (with maternal milk) prevented the effects of peat smoke.

  13. High nitrogen availability reduces polyphenol content in Sphagnum peat.

    PubMed

    Bragazza, Luca; Freeman, Chris

    2007-05-15

    Peat mosses of the genus Sphagnum constitute the bulk of living and dead biomass in bogs. These plants contain peculiar polyphenols which hamper litter peat decomposition through their inhibitory activity on microbial breakdown. In the light of the increasing availability of biologically active nitrogen in natural ecosystems, litter derived from Sphagnum mosses is an ideal substrate to test the potential effects of increased atmospheric nitrogen deposition on polyphenol content in litter peat. To this aim, we measured total nitrogen and soluble polyphenol concentration in Sphagnum litter peat collected in 11 European bogs under a chronic gradient of atmospheric nitrogen deposition. Our results demonstrate that increasing nitrogen concentration in Sphagnum litter, as a consequence of increased exogenous nitrogen availability, is accompanied by a decreasing concentration of polyphenols. This inverse relationship is consistent with reports that in Sphagnum mosses, polyphenol and protein biosynthesis compete for the same precursor. Our observation of modified Sphagnum litter chemistry under chronic nitrogen eutrophication has implications in the context of the global carbon balance, because a lower content of decay-inhibiting polyphenols would accelerate litter peat decomposition.

  14. Analyzing peat pyrolysis by in-situ FTIR

    SciTech Connect

    Fen, J.; Li, W.Y.; Li, F.; Xie, K.C.

    1997-12-31

    Coal pyrolysis is complex process that includes many small reactions. Being complicated, it is difficult to study the pyrolysis mechanism with high rank coal directly. Peat is a rudimentary coal which has the most simple structure with lower polymerization. Some researchers think that the key to understanding coal structure is in an appreciation of the molecular components of the original peat swamp and how these might be modified. It is generally agreed that the chemical diversity of various coals will affect rate of coal combustion through the devolatilization process. Upon heating, some of the chemical bonds in coal undergo cracking and result in the release of light gases and the production of tar. Through analysis of peat which is best model compound of coal, some basic step reactions of coal can be understood. The objective of this study is to analyze peat pyrolysis using a in-situ pyrolysis-FTIR and to establish the pyrolysis model. The results show that during rapid peat pyrolysis, all the functional groups produced have almost the same activity energy; the difference among them is the degree of reaction.

  15. Models of the geomorphology, hydrology, and development of domed peat bodies

    SciTech Connect

    Winston, R.B.

    1994-12-01

    Because peat accumulates only beneath the water table, the shape of a peat body should reflect the shape of its water table and thus the hydrology of the peat body. Three different models successfully reproduce the observed peat dome morphology, including a central bog plain. In the first model, the bog plain develops because peat accumulation is limited by anaerobic decay of peat beneath the water table. With certain simplifying assumptions, an analytic solution for this model can be obtained. The other two models are more easily investigated numerically. In the first model, the initial peat accumulation rate is limited only by plant growth and decay and is the maximum rate observed during peat dome development. As a peat dome expands laterally, peat accumulation slows because the water table ceases to rise fast enough to preserve all the available plant material. Eventually, anaerobic decay beneath the water table matches the rate of peat addition to the top of the peat body, and net peat accumulation ceases. 17 refs., 2 tabs.

  16. Applications of peat-based sorbents for removal of metals from water

    SciTech Connect

    Cohen, A.D.; Stack, E.M.; Eltayeb, S.; Durig, J.B

    1995-12-31

    The results reported in this paper are derived from one part of an ongoing investigation of peat sorption properties, in particular, the capacities of acid-treated peats to adsorb chromium, nickel, zinc, copper, and cadmium from water. Acid treatment was done to remove as much previously adsorbed metal as possible before testing. Four peat types were selected for study, two highly decomposed types (a woody, Taxodium-dominated peat from the Okefenokee Swamp of Georgia and a sedge-dominated, charcoal-rich peat from the Tamiami Trail region of Florida) and two less decomposed ones (a Sphagnum moss-dominated peat from Maine and a Nymphaea-dominated peat from the Okefenokee Swamp of Georgia). Single metal and mixed metal solutions were tested in slurry experiments with each peat type. Solutions were analyzed using a Perkin-Elmer model 305B Flame Atomic Absorption Spectrophotometer. In single metal tests, chromium and copper tended to be adsorbed to a greater extent than the other metals. Three of the peats were found to be capable of adsorbine more copper ions than zince ions, while a fourth type adsorbed approximately the same amounts of each. Degree of decomposition of the peats tended to affect sorption properties for certain metals. The results of batch studies revealed that chromium was always preferentially adsorbed regardless of the peat type tested. The results of these studies further confirm that remediation of metal-contaminated waters using peats will require selection of specific peats to match the contaminants.

  17. Water-soluble organic acids in cryomorphic peat soils of the southeastern Bol'shezemel'skaya tundra

    NASA Astrophysics Data System (ADS)

    Shamrikova, E. V.; Kaverin, D. A.; Pastukhov, A. V.; Lapteva, E. M.; Kubik, O. S.; Punegov, V. V.

    2015-03-01

    The composition of the water extracts, the pH, and the weight concentrations of the total organic carbon and low-molecular-weight organic acids in seasonally thawed and perennially frozen horizons of cryomorphic peat soils have been determined. The quantitative analysis of the acids converted to trimethylsilyl derivatives has been performed by gas chromatography and chromato-mass spectroscopy. Hydroxypropanoic, propanoic, and hydroxyethanoic acids are the prevailing acids (30-50, 10-20, and 10% of the total acids, respectively). Malic, glyceric, hexadionic, trihydroxybutanoic, ribonic, and other acids have also been detected. It has been shown that the differences in the genesis of the peat deposits significantly affect the composition and content of water-soluble organic compounds in soils on the soil-profile and landscape levels.

  18. The impact of 90 years of drainage works on some chemical properties of raised peat bog organic soils - case study from valley of the Upper San river in Polish Bieszczady Mts. (Eastern Carpathians).

    NASA Astrophysics Data System (ADS)

    Stolarczyk, Mateusz

    2016-04-01

    Wetland ecosystems, including raised peat bogs are characterized by a specific water conditions and unique vegetation, which makes peatland highly important habitats due to protection of biodiversity. Transformation of peat bog areas is particularly related to changes in the environment e.g. according to reclamation works. Drainage of peatlands is directly associated to the decrease of groundwater levels and lead to a number of changes in the chemical and physical properties of peat material, included contents of exchangeable cations in the surface layers of peat soils in the decession phase of peat development and release above compounds from the soil to ground or surface waters. The aim of the research was to determine the impact of extended drainage works on chemical composition of sorption complex of raised peat bog organic soils and identification the potential environmental effects of alkaline cations leaching to the surface waters. Research was carried out on the peat bogs located in the Upper San valley in Polish Bieszczady Mts. (Eastern Carpathians). Soil samples used in this study were collected from 3 soil profiles in 10 or 20 cm intervals to the approximately 130 cm depth. Laboratory analyses included determination of basic properties of organic material such as the degree of peat decomposition, ash content, soil pH and carbon, hydrogen, nitrogen concentrations. Additionally the amount of alkaline cations, exchangeable and extractable acidity was determined. Furthermore, the degree of saturation of the sorption complex with alkaline cations (V) and cation exchange capacity (CEC) are calculated. In order to evaluate the impact of the examined peat bog to the environment, also water samples were collected and ions composition was measured. The obtained results show that studied organic soils are oligotrophic and strongly acidic. In the case of organic material related to decession phase of peat development, as a result of the lengthy drainage works

  19. Suggested protocol for collecting, handling and preparing peat cores and peat samples for physical, chemical, mineralogical and isotopic analyses.

    PubMed

    Givelet, Nicolas; Le Roux, Gaël; Cheburkin, Andriy; Chen, Bin; Frank, Jutta; Goodsite, Michael E; Kempter, Heike; Krachler, Michael; Noernberg, Tommy; Rausch, Nicole; Rheinberger, Stefan; Roos-Barraclough, Fiona; Sapkota, Atindra; Scholz, Christian; Shotyk, William

    2004-05-01

    For detailed reconstructions of atmospheric metal deposition using peat cores from bogs, a comprehensive protocol for working with peat cores is proposed. The first step is to locate and determine suitable sampling sites in accordance with the principal goal of the study, the period of time of interest and the precision required. Using the state of the art procedures and field equipment, peat cores are collected in such a way as to provide high quality records for paleoenvironmental study. Pertinent field observations gathered during the fieldwork are recorded in a field report. Cores are kept frozen at -18 degree C until they can be prepared in the laboratory. Frozen peat cores are precisely cut into 1 cm slices using a stainless steel band saw with stainless steel blades. The outside edges of each slice are removed using a titanium knife to avoid any possible contamination which might have occurred during the sampling and handling stage. Each slice is split, with one-half kept frozen for future studies (archived), and the other half further subdivided for physical, chemical, and mineralogical analyses. Physical parameters such as ash and water contents, the bulk density and the degree of decomposition of the peat are determined using established methods. A subsample is dried overnight at 105 degree C in a drying oven and milled in a centrifugal mill with titanium sieve. Prior to any expensive and time consuming chemical procedures and analyses, the resulting powdered samples, after manual homogenisation, are measured for more than twenty-two major and trace elements using non-destructive X-Ray fluorescence (XRF) methods. This approach provides lots of valuable geochemical data which documents the natural geochemical processes which occur in the peat profiles and their possible effect on the trace metal profiles. The development, evaluation and use of peat cores from bogs as archives of high-resolution records of atmospheric deposition of mineral dust and trace

  20. Bacterial populations and environmental factors controlling cellulose degradation in an acidic Sphagnum peat.

    PubMed

    Pankratov, Timofey A; Ivanova, Anastasia O; Dedysh, Svetlana N; Liesack, Werner

    2011-07-01

    Northern peatlands represent a major global carbon store harbouring approximately one-third of the global reserves of soil organic carbon. A large proportion of these peatlands consists of acidic Sphagnum-dominated ombrotrophic bogs, which are characterized by extremely low rates of plant debris decomposition. The degradation of cellulose, the major component of Sphagnum-derived litter, was monitored in long-term incubation experiments with acidic (pH 4.0) peat extracts. This process was almost undetectable at 10°C and occurred at low rates at 20°C, while it was significantly accelerated at both temperature regimes by the addition of available nitrogen. Cellulose breakdown was only partially inhibited in the presence of cycloheximide, suggesting that bacteria participated in this process. We aimed to identify these bacteria by a combination of molecular and cultivation approaches and to determine the factors that limit their activity in situ. The indigenous bacterial community in peat was dominated by Alphaproteobacteria and Acidobacteria. The addition of cellulose induced a clear shift in the community structure towards an increase in the relative abundance of the Bacteroidetes. Increasing temperature and nitrogen availability resulted in a selective development of bacteria phylogenetically related to Cytophaga hutchinsonii (94-95% 16S rRNA gene sequence similarity), which densely colonized microfibrils of cellulose. Among isolates obtained from this community only some subdivision 1 Acidobacteria were capable of degrading cellulose, albeit at a very slow rate. These Acidobacteria represent indigenous cellulolytic members of the microbial community in acidic peat and are easily out-competed by Cytophaga-like bacteria under conditions of increased nitrogen availability. Members of the phylum Firmicutes, known to be key players in cellulose degradation in neutral habitats, were not detected in the cellulolytic community enriched at low pH.

  1. An ecologic study of peat landforms in Canada and Alaska

    NASA Technical Reports Server (NTRS)

    Glaser, P. H.

    1986-01-01

    The role of groundwater and surface runoff in controlling the water chemistry and development of peat landforms in northern Minnesota are described. The LANDSAT imagery taken duing spring break-up are particularly valuable in identifying potential zones of groundwater discharge. The vascular floras of raised bogs in eastern North Americas demonstrating the remarkabe uniformity of the ombrotrophic flora over broad geographic regions are described. The evolution of peat landforms in the major boreal peatlands of eastern America is examined. The LANDSAT imagery is used to determine the area of patterned to featureless peatlands, the area of ombrotrophic bog relative to minerotrophic fen, and the relative size and degree of streamlining of island landforms entirely composed of peat. Such measurements can be used to assess the role of climate, time, and hydrology in controlling the formation of peatland patterns across broad geographic regions.

  2. Processes in the pore waters of peat deposits

    SciTech Connect

    Levshenko, T.V.; Efremova, A.G.; Galkina, Z.M.; Surkova, T.E.; Tolstov, K.A.

    1983-01-01

    The composition of the waters of modern peat bogs that have developed in the intracontinental regions under the conditions of bogs of the high-moor, mixed, and lowmoor types have been investigated for the case of a number of peat deposits of the Smolensk, Volgorad, and Pskov provinces. During the work the pH of the deposits and the C1-, Alk, SO/sup 2/-, Ca/sup 2 +/, Mg/sup 2 +/, K- contents of the pore water of modern peat beds were studied. The thickness of the deposits studied amounted to 5-7 m. Samples were taken every 0.5 m in depth. The water was separated from the deposits by pressing out.

  3. Persistent high temperature and low precipitation reduce peat carbon accumulation.

    PubMed

    Bragazza, Luca; Buttler, Alexandre; Robroek, Bjorn J M; Albrecht, Remy; Zaccone, Claudio; Jassey, Vincent E J; Signarbieux, Constant

    2016-12-01

    Extreme climate events are predicted to become more frequent and intense. Their ecological impacts, particularly on carbon cycling, can differ in relation to ecosystem sensitivity. Peatlands, being characterized by peat accumulation under waterlogged conditions, can be particularly sensitive to climate extremes if the climate event increases soil oxygenation. However, a mechanistic understanding of peatland responses to persistent climate extremes is still lacking, particularly in terms of aboveground-belowground feedback. Here, we present the results of a transplantation experiment of peat mesocosms from high to low altitude in order to simulate, during 3 years, a mean annual temperature c. 5 °C higher and a mean annual precipitation c. 60% lower. Specifically, we aim at understanding the intensity of changes for a set of biogeochemical processes and their feedback on carbon accumulation. In the transplanted mesocosms, plant productivity showed a species-specific response depending on plant growth forms, with a significant decrease (c. 60%) in peat moss productivity. Soil respiration almost doubled and Q10 halved in the transplanted mesocosms in combination with an increase in activity of soil enzymes. Spectroscopic characterization of peat chemistry in the transplanted mesocosms confirmed the deepening of soil oxygenation which, in turn, stimulated microbial decomposition. After 3 years, soil carbon stock increased only in the control mesocosms whereas a reduction in mean annual carbon accumulation of c. 30% was observed in the transplanted mesocosms. Based on the above information, a structural equation model was built to provide a mechanistic understanding of the causal connections between peat moisture, vegetation response, soil respiration and carbon accumulation. This study identifies, in the feedback between plant and microbial responses, the primary pathways explaining the reduction in carbon accumulation in response to recurring climate extremes in

  4. Evaluation of reclaimed abandoned bentonite mine lands

    SciTech Connect

    Edinger, K.D.; Schuman, G.E.; Vance, G.F.

    1999-07-01

    In 1985, the Abandoned Mined Land Division of the Wyoming Department of Environmental Quality began reclamation of 4,148 ha of abandoned bentonite mined lands. Calcium amendments and sawmill wood wastes were applied to the regraded spoils to enhance water infiltration, displacement of Na on the clay spoil, and leaching of the displaced Na and other soluble salts. Revegetation of these lands was generally successful, but after several years small areas (0.1--0.2 ha) began to show signs of vegetation die-back and to prescribe corrective treatment options. A randomized block design was imposed on study areas near Upton, Colony, and Greybull, Wyoming to characterize spoil chemical properties of good, moderate, and dead vegetation zones, which were subjectively delineated by visual vegetation cover and density differences. Spoil analyses indicated exchangeable-sodium (Na) concentrations were high and the dead vegetation zones exhibited exchangeable-sodium-percentages (ESP) above 50%, while surrounding good vegetation zones exhibited ESP values <10%. This coupled with low soluble-Na concentrations (<2 cmol/kg) suggests insufficient calcium (Ca) amendments were initially applied to ameliorate the sodic conditions of the spoil. The sampling design used to determine Ca amendment rates, which consisted of a composite of 5 spoil cores taken from each 0.8 ha area, was apparently insufficient to account for the highly heterogeneous spoil material that occurred throughout these abandoned bentonite reclamation sites. To revegetate these small degraded sites, additional Ca amendment would be necessary and reseeding would be required. However, the authors recommend further monitoring of the affected sites to determine if unfavorable conditions continue to degrade the reclaimed landscape before any attempt is made to rehabilitate the affected sites. If the degraded sites are stable, further Remediation efforts are not warranted because small areas of little or no vegetation are

  5. Sketch maps, sections and laboratory analyses of peat resources in deposits of southern and western Maine

    USGS Publications Warehouse

    Cameron, Cornelia Clermont; Mullen, Michael K.

    1983-01-01

    Peat deposits in southern and western Maine were investigated for their estimated potential as peat resources suitable for energy, horticultural, and agricultural uses. Fifty-six sketch maps illustrate the areal extent, thickness, and amount of commercial-quality peat. The total yield is estimated at 27,736,400 short tons air-dried peat. Ash content is generally less than 11 percent and BTU ranges from 8,063 to 10,076.

  6. Investigation of occupational radiation exposures to NORM at an Irish peat-fired power station and potential use of peat fly ash by the construction industry.

    PubMed

    Organo, C; Lee, E M; Menezes, G; Finch, E C

    2005-12-01

    Annually, approximately 15% of Ireland's electricity requirement is provided through the combustion of 3 x 10(6) tonnes of peat. While the literature on coal-fired power generation is quite abundant, studies on the peat-fired power generation industry from a radiological point of view are scarce. A study of the largest Irish peat-fired power plant was initiated to review the potential occupational radiation exposures arising from the occurrence of naturally occurring radioactive material (NORM) at different stages of the industrial process and to investigate any radiological health consequences that may arise should peat fly ash be used as a component of building materials. Ambient gamma dose rate measurements, radon measurements, quantification of the occupational exposure from inhalation of airborne particles (personal air sampling) and gamma spectrometry analysis of peat, peat ash and effluent samples from the ash ponds were undertaken. The results indicate that the radiation dose received by any worker involved in the processing of the peat and the handling of the ash resulting from peat combustion does not exceed 150 microSv per annum. Regulatory control of the peat-fired power generation is therefore unnecessary according to the Irish legislation with regards to NORM. The potential use of peat fly ash as a by-product in the building industry was also found to have a negligible radiological impact for construction workers and for members of the public.

  7. Using peat for energy: Potential environmental restraints. Overview

    NASA Astrophysics Data System (ADS)

    Reed, R. M.; Voorhees, L. D.; Mulholland, P. J.

    Serious consideration is being given to using peat as an energy resource in Minnesota, North Carolina, Florida, and some New England States. Potential environmental constraints for using peat as an energy resource are associated with disruption of important regional wetland ecosystems. Mining peatlands may significantly modify ground and surface water hydrology, degrade water quality in downstream receiving systems, contribute to the deterioration of local air quality, disrupt or eliminate plant and animal populations having specialized requirements and limited distributions, and destroy unique wetland ecosystems representing important scientific and educational resources. Careful selection of peatlands to be developed and application of appropriate mitigation and monitoring programs will be necessary to offset these impacts.

  8. Application of microwave digestion to the analysis of peat

    USGS Publications Warehouse

    Papp, C.S.E.; Fischer, L.B.

    1987-01-01

    A microwave digestion technique for the dissolution of peat is described and compared with a dry ashing method and a nitric - perchloric - hydrofluoric acid wet digestion. Peat samples with different organic matter contents were used and Ca, Mg, Fe, AI, Na, K, Mn, Zn, Cu and Li were determined by atomic absoprtion spectrometry. The results obtained using the three dissolution techniques were in good agreement. The microwave method has the advantage of digesting the samples in less than 2 h and uses less acid than the conventional wet digestion method. Keeping the volume of the acid mixture as small as possible minimises contamination and leads to lower blank values.

  9. Complete Genome Sequence of Phytopathogenic Pectobacterium atrosepticum Bacteriophage Peat1

    PubMed Central

    Kalischuk, Melanie; Hachey, John

    2015-01-01

    Pectobacterium atrosepticum is a common phytopathogen causing significant economic losses worldwide. To develop a biocontrol strategy for this blackleg pathogen of solanaceous plants, P. atrosepticum bacteriophage Peat1 was isolated and its genome completely sequenced. Interestingly, morphological and sequence analyses of the 45,633-bp genome revealed that phage Peat1 is a member of the family Podoviridae and most closely resembles the Klebsiella pneumoniae bacteriophage KP34. This is the first published complete genome sequence of a phytopathogenic P. atrosepticum bacteriophage, and details provide important information for the development of biocontrol by advancing our understanding of phage-phytopathogen interactions. PMID:26272557

  10. Complete Genome Sequence of Phytopathogenic Pectobacterium atrosepticum Bacteriophage Peat1.

    PubMed

    Kalischuk, Melanie; Hachey, John; Kawchuk, Lawrence

    2015-08-13

    Pectobacterium atrosepticum is a common phytopathogen causing significant economic losses worldwide. To develop a biocontrol strategy for this blackleg pathogen of solanaceous plants, P. atrosepticum bacteriophage Peat1 was isolated and its genome completely sequenced. Interestingly, morphological and sequence analyses of the 45,633-bp genome revealed that phage Peat1 is a member of the family Podoviridae and most closely resembles the Klebsiella pneumoniae bacteriophage KP34. This is the first published complete genome sequence of a phytopathogenic P. atrosepticum bacteriophage, and details provide important information for the development of biocontrol by advancing our understanding of phage-phytopathogen interactions.

  11. Genesis of peat-bog soils in the northern taiga spruce forests of the Kola Peninsula

    SciTech Connect

    Nikonov, V.V.

    1981-01-01

    The characteristics of soil formation processes in the Peat-Bog soils of waterlogged spruce phytocenoses on the Kola Peninsula are investigated. It is found that the ash composition of the peat layer is determined primarily by the composition of the buried plant residues. The effect of the chemical composition of water feeding the peat bogs is determined. (Refs. 7).

  12. Abandoned Rayrock uranium mill tailings in the Northwest Territories: environmental conditions and radiological impact.

    PubMed

    Veska, E; Eaton, R S

    1991-03-01

    Field and laboratory investigations were undertaken of the environment surrounding abandoned U mill tailings at Rayrock, Northwest Territories, Canada, to examine the extent of 226Ra and U contamination. Samples of ground water, surface water, and unconsolidated geological material from the Rayrock area were collected for chemical and radiochemical analyses. Results indicated that the surface waters contained levels of 226Ra as high as 20 Bq L-1, 210Pb as high as 1.1 Bq L-1, and ground water U as high as 2800 micrograms L-1. Lower levels of 226Ra, 210Pb, and U, 3.6 Bq L-1, 0.5 Bq L-1, and 4 micrograms L-1, respectively, were found in a small lake adjacent to the tailings area. Analysis of tailings and soil in the immediate vicinity indicates that the radionuclides and U are mobilized and can move within the tailings. Some of the mobilized radionuclides will be bound by the surrounding peat. The remainder may move to Lake Alpha in ground water. Surface water flow also transports some contaminants both in the water of Alpha Creek and by washing tailings into Lake Alpha. The potential annual external and internal dose equivalents to a hypothetical resident were calculated based on exposure from the abandoned U mill tailings, drinking water, and fish caught in the lakes in the vicinity of the tailings. While Alpha Creek and Lake Alpha water showed evidence of contamination, the rest of the water system and the fish were at natural background levels of radioactivity.

  13. Cardiopulmonary toxicity of peat wildfire particulate matter and the predictive utility of precision cut lung slices

    PubMed Central

    2014-01-01

    Background Emissions from a large peat fire in North Carolina in 2008 were associated with increased hospital admissions for asthma and the rate of heart failure in the exposed population. Peat fires often produce larger amounts of smoke and last longer than forest fires, however few studies have reported on their toxicity. Moreover, reliable alternatives to traditional animal toxicity testing are needed to reduce the number of animals required for hazard identification and risk assessments. Methods Size-fractionated particulate matter (PM; ultrafine, fine, and coarse) were obtained from the peat fire while smoldering (ENCF-1) or when nearly extinguished (ENCF-4). Extracted samples were analyzed for chemical constituents and endotoxin content. Female CD-1 mice were exposed via oropharyngeal aspiration to 100 μg/mouse, and assessed for relative changes in lung and systemic markers of injury and inflammation. At 24 h post-exposure, hearts were removed for ex vivo functional assessments and ischemic challenge. Lastly, 8 mm diameter lung slices from CD-1 mice were exposed (11 μg) ± co-treatment of PM with polymyxin B (PMB), an endotoxin-binding compound. Results On an equi-mass basis, coarse ENCF-1 PM had the highest endotoxin content and elicited the greatest pro-inflammatory responses in the mice including: increases in bronchoalveolar lavage fluid protein, cytokines (IL-6, TNF-α, and MIP-2), neutrophils and intracellular reactive oxygen species (ROS) production. Exposure to fine or ultrafine particles from either period failed to elicit significant lung or systemic effects. In contrast, mice exposed to ENCF-1 ultrafine PM developed significantly decreased cardiac function and greater post-ischemia-associated myocardial infarction. Finally, similar exposures to mouse lung slices induced comparable patterns of cytokine production; and these responses were significantly attenuated by PMB. Conclusions The findings suggest that exposure to coarse PM

  14. Mycotrophy of crops in rotation and soil amendment with peat influence the abundance and effectiveness of indigenous arbuscular mycorrhizal fungi in field soil.

    PubMed

    Vestberg, M; Saari, K; Kukkonen, S; Hurme, T

    2005-09-01

    Mycotrophy of previous crops has been shown to have an impact on arbuscular mycorrhizal fungi (AMF), and the growth and productivity of succeeding crops. We studied the impact of 3 years of cultivation of eight crops with different degrees of mycotrophy, including mycorrhizal (strawberry, rye, timothy, onion, caraway) and non-mycorrhizal (turnip rape, buckwheat, fiddleneck) hosts, as well as the impact of peat amendment, on the effectiveness, amount and diversity of indigenous AMF. A field experiment having a split-plot design with peat amendment as the main plot, crop cultivation as a sub-plot and three replications, was carried out on silt clay mineral soil in 1999-2001. A well-humified dark peat was applied immediately before establishment of the field experiment. Each year, the relative mycorrhizal effectiveness of soil collected in September, in terms of shoot dry weight (RME(DW)), was determined in a bioassay. In the 3rd year of the experiment, AMF spores were also extracted and identified from the field soil. Expressed as the mean of 3 years of cropping in unamended soil, the mycorrhizal crops strawberry and caraway maintained RME(DW) most effectively, while the values were lower in the non-host crops buckwheat, turnip rape and fiddleneck. In addition, the numbers of AM spores detected in soil were considerably greater during 3 years of strawberry cultivation. In soil under caraway, there were high numbers of AM spores compared to the other crops. In soil amended with peat, the situation was in some cases opposite of that of unamended soil; RME(DW) was highest in rye and onion and lowest in strawberry and caraway. The reasons behind the negative impact of peat on mycorrhizal effectiveness in strawberry soil may be due to the microbiological properties of peat. The importance of including mycotrophic species in crop rotations for maintaining high soil quality and for increasing yields of subsequent crops is discussed.

  15. Crimes and misdemeanours: the case of child abandonment

    PubMed Central

    Giordano, S

    2007-01-01

    In 2002, a child was abandoned in a Burger King restaurant in Amsterdam by a Chinese woman, who hoped that the baby would be picked up by someone able to give the child a better life. She was convicted for child abandonment and imprisoned. Whereas some forms of child abandonment are criminalised, others are socially accepted and not even on the ethics agenda. This paper is an invitation to reflect on the inconsistency in the ways in which we prosecute, punish or try to correct some forms of child abandonment and yet make allowances for others. PMID:17209107

  16. Ecological study of peat landforms in Canada and Alaska

    NASA Technical Reports Server (NTRS)

    Glaser, Paul H.

    1989-01-01

    Over 20 percent of the land surface of Canada and Alaska is covered by peatlands, which may be defined as any waterlogged ecosystem with a minimum thickness of 20 cm of organic matter in the soil. Past investigations have demonstrated the value of aerial photographs in identifying the major vegetation types and analyzing the biotic and hydrogeologic processes that control the development of these peatlands. In the present study, LANDSAT TM imagery was used in conjunction with field studies to determine the utility of this satellite sensor for detecting these important processes. Although the vegetation landforms within these major peat basins are visible on aerial photographs, LANDSAT TM imagery provides essential new evidence for their analysis. Spectral data from the LANDSAT TM system provides: (1) synoptic views of the patterns across large portions of these peat basins, indicating important physiographic controls on peatland development, (2) more sensitive detection of the major vegetation types, allowing rapid quantitative estimates to be made of their distribution and aerial extent, (3) discrimination of bog areas with potentially rapid or slow rates of peat accumulation, (4) identification of discharge zones for groundwater, which apparently represents the most important source of alkalinity in these peat basins, and (5) detection of flow patterns in water tracks that appear nearly uniform on standard aerial photographs.

  17. Health burden from peat wildfire in North Carolina

    EPA Science Inventory

    In June 2008, a wildfire smoldering through rich peat deposits in the Pocosin Lakes National Wildlife Refuge produced massive amounts of smoke and exposed a largely rural North Carolina area to air pollution in access of the National Ambient Air Quality Standards. In this talk, w...

  18. Experimental evidence for mobility/immobility of metals in peat.

    PubMed

    Novak, Martin; Zemanova, Leona; Voldrichova, Petra; Stepanova, Marketa; Adamova, Marie; Pacherova, Petra; Komarek, Arnost; Krachler, Michael; Prechova, Eva

    2011-09-01

    The biogeochemical cycles of most toxic metals have been significantly altered by anthropogenic activities. Anaerobic, rain-fed organic soils are believed to record historical changes in atmospheric pollution. Suspected postdepositional mobility of trace elements, however, hinders the usefulness of peat bogs as pollution archives. To lower this uncertainty, we quantified the mobility of six trace metals in peat during an 18-month field manipulation. A replicated, reciprocal peat transplant experiment was conducted between a heavily polluted and a relatively unpolluted peatland, located 200 km apart in the Czech Republic (Central Europe). Both peatlands were Sphagnum-derived, lawn-dominated, and had water table close to the surface. A strikingly different behavior was observed for two groups of elements. Elements of group I, Fe and Mn, adjusted their abundances and vertical patterns to the host site, showing an extremely high degree of mobility. In contrast, elements of group II, Pb, Cu, Zn, and Ti, preserved their original vertical patterns at the host site, showing a high degree of immobility. Our experimental results suggest that not just lead, but also copper and zinc concentration profiles in peat are a reliable archive of temporal pollution changes within a wide pH range (2.5-5.8).

  19. Bacteriohopanepolyol signatures as markers for methanotrophic bacteria in peat moss

    NASA Astrophysics Data System (ADS)

    van Winden, Julia F.; Talbot, Helen M.; Kip, Nardy; Reichart, Gert-Jan; Pol, Arjan; McNamara, Niall P.; Jetten, Mike S. M.; Op den Camp, Huub J. M.; Sinninghe Damsté, Jaap S.

    2012-01-01

    Bacteriohopanepolyols (BHPs) are bacterial biomarkers with a likely potential to identify present and past methanotrophic communities. To unravel the methanotrophic community in peat bogs, we report the BHP signatures of type I and type II methanotrophs isolated from Sphagnum mosses and of an extreme acidophilic verrucomicrobial methanotroph. A type I Methylovulum-like strain (M200) contains a remarkable combination of BHPs, including a complete suite of mono-unsaturated aminobacteriohopanepentol, -tetrol and -triol. The Methylomonas-like strain (M5) mainly produces aminobacteriohopanepentol, characteristic for type I methanotrophs, and the Methylosinus-like strain (29) contains both aminobacteriohopanetetrol and aminobacteriohopanetriol, typical for a type II methanotroph. The type II methanotroph Methylocella palustris and the verrucomicrobial Methylacidiphilum fumariolicum strain SolV primarily produce aminotriol, which is also produced by many other bacteria. In Sphagnum mosses and underlying peat from a peat bog from Moorhouse, UK, the only detectable BHPs indicative of methanotrophs are aminobacteriohopanepentol (aminopentol) and aminobacteriohopanetetrol (aminotetrol), although both are relatively low in abundance compared to other BHPs. Aminopentol serves as a marker for type I methanotrophs, while aminotetrol may reflect the presence of both type I and type II methanotrophs. The similar quantities of aminotetrol and aminopentol indicate that the methanotrophic community in Sphagnum peat probably consist of a combination of both type I and type II methanotrophs, which is in line with previously published pmoA-based micro-array results.

  20. Classifying and mapping wetlands and peat resources using digital cartography

    USGS Publications Warehouse

    Cameron, Cornelia C.; Emery, David A.

    1992-01-01

    Digital cartography allows the portrayal of spatial associations among diverse data types and is ideally suited for land use and resource analysis. We have developed methodology that uses digital cartography for the classification of wetlands and their associated peat resources and applied it to a 1:24 000 scale map area in New Hampshire. Classifying and mapping wetlands involves integrating the spatial distribution of wetlands types with depth variations in associated peat quality and character. A hierarchically structured classification that integrates the spatial distribution of variations in (1) vegetation, (2) soil type, (3) hydrology, (4) geologic aspects, and (5) peat characteristics has been developed and can be used to build digital cartographic files for resource and land use analysis. The first three parameters are the bases used by the National Wetlands Inventory to classify wetlands and deepwater habitats of the United States. The fourth parameter, geological aspects, includes slope, relief, depth of wetland (from surface to underlying rock or substrate), wetland stratigraphy, and the type and structure of solid and unconsolidated rock surrounding and underlying the wetland. The fifth parameter, peat characteristics, includes the subsurface variation in ash, acidity, moisture, heating value (Btu), sulfur content, and other chemical properties as shown in specimens obtained from core holes. These parameters can be shown as a series of map data overlays with tables that can be integrated for resource or land use analysis.

  1. The effects of salinization on aerobic and anaerobic decomposition and mineralization in peat meadows: the roles of peat type and land use.

    PubMed

    Brouns, Karlijn; Verhoeven, Jos T A; Hefting, Mariet M

    2014-10-01

    Peat soils comprise a large part of the western and northern Netherlands. Drainage for agriculture has caused increased soil aeration which has stimulated decomposition and, hence, soil subsidence, currently amounting to 1-2 cm/yr. River water is supplied to these peat areas in summer to prevent drying out of the peat soils. Saltwater intrusion and evaporation make this surface water slightly brackish during drought periods. In addition, brackish seepage can surface more easily during such dry periods. We performed an incubation experiment in which the effects of salinization on aerobic decomposition and mineralization of shallow peat samples and anaerobic decomposition and mineralization of deep peat samples were studied. We considered four different types of peat samples: peat sampled in agricultural peat meadows and in nature reserves, originally formed under either eutrophic or oligotrophic conditions. The aerobic decomposition was approximately reduced by 50% after salinization, whereas the anaerobic decomposition rates remained unchanged. Remarkably, the response to salinization did not differ between the peat types and land uses. Ammonium concentrations increased while nitrate concentrations decreased after salinization, probably as a result of reduced nitrification. Especially in the oligotrophic peat, ammonium concentrations increased substantially. Phosphate concentrations increased, possibly caused by changes in desorption and adsorption processes due to higher ion concentrations. DOC concentrations decreased in the brackish samples due to precipitation. Furthermore, the eutrophic peat samples showed increasing sulfate concentrations, both in oxic and anoxic incubations, which was attributed to pyrite oxidation. Independently of salinization, nitrification rates were higher in the agricultural, fertilized, peat soils. In conclusion, while salinization might reduce subsidence rates, it will have adverse effects on water quality.

  2. Emission Factor from Small Scale Tropical Peat Combustion

    NASA Astrophysics Data System (ADS)

    Setyawati, W.; Damanhuri, E.; Lestari, P.; Dewi, K.

    2017-03-01

    Peatfire in Indonesia recently had become an important issue regarding its global warming impact of green house gases emitted. Emission factor is one of important variables to determine total emission of carbon released by peatfire. But currently there were only a few studies about Indonesian peat fire emission factors. The previous studies of Indonesian peat fire emission factor reported the results from a very limited number of samples and during smoldering combustion stages only. Therefore this study attempts to quantify carbon dioxide (CO2) and methane (CH4) emission factors from laboratory peat combustion based on higher number of samples and taken both of combustion stages (flaming and smoldering) into consideration. Peats were sampled from five different districts in Pontianak, West Kalimantan. Ultimate analysis showed that pure peat composed of relatively high carbon content (52.85 – 59.43% dry basis). Laboratory experiments were carried out by burning small amout of peats in a mini furnace and measuring their CO2 and CH4 emission concentration during flaming and smoldering. CO2, CO and CH4 average emission factors and their related average MCE for flaming were found to be 2,088 ± 21 g/kg (n = 17), 3.104 ± 7.173 g/kg (n = 17), 0.143 ± 0.132 g/kg (n = 17) and 0.998 ± 0.005 (n = 17), respectively, while for smoldering were 1,831 ± 131 g/kg (n = 17), 138 ± 72 g/kg (n = 17), 17 ± 12 g/kg (n = 17) and 0.894 ± 0.055 g/kg (n = 17), respectively. This emission factors based on the laboratory combustion experiment can be conveniently used to estimate CO2 and CH4 emission from Indonesian peat fire. Equation models to correlate between MCE and emission factors for both flaming and smoldering were developed. MCE and CO2 emission factor during flaming was relatively higher than smoldering. On the contrary, CO and CH4 emission factors were relatively smaller during flaming than smoldering.

  3. Untangling climatic and autogenic signals in peat records

    NASA Astrophysics Data System (ADS)

    Morris, Paul J.; Baird, Andrew J.; Young, Dylan M.; Swindles, Graeme T.

    2016-04-01

    Raised bogs contain potentially valuable information about Holocene climate change. However, autogenic processes may disconnect peatland hydrological behaviour from climate, and overwrite and degrade climatic signals in peat records. How can genuine climate signals be separated from autogenic changes? What level of detail of climatic information should we expect to be able to recover from peat-based reconstructions? We used an updated version of the DigiBog model to simulate peatland development and response to reconstructed Holocene rainfall and temperature reconstructions. The model represents key processes that are influential in peatland development and climate signal preservation, and includes a network of feedbacks between peat accumulation, decomposition, hydraulic structure and hydrological processes. It also incorporates the effects of temperature upon evapotranspiration, plant (litter) productivity and peat decomposition. Negative feedbacks in the model cause simulated water-table depths and peat humification records to exhibit homeostatic recovery from prescribed changes in rainfall, chiefly through changes in drainage. However, the simulated bogs show less resilience to changes in temperature, which cause lasting alterations to peatland structure and function and may therefore be more readily detectable in peat records. The network of feedbacks represented in DigiBog also provide both high- and low-pass filters for climatic information, meaning that the fidelity with which climate signals are preserved in simulated peatlands is determined by both the magnitude and the rate of climate change. Large-magnitude climatic events of an intermediate frequency (i.e., multi-decadal to centennial) are best preserved in the simulated bogs. We found that simulated humification records are further degraded by a phenomenon known as secondary decomposition. Decomposition signals are consistently offset from the climatic events that generate them, and decomposition

  4. Biological activity and biodegradation of organic matter in sandy peat soils

    SciTech Connect

    Zimenko, T.G.; Bambalov, N.N.; Belkovskii, V.I.; Gavrilkina, N V.

    1986-11-01

    Various techniques for sandy reclaimed peat soils act differently on the microbiochemical processes responsible for peat biodegradation. Mixing the upper layer of peat with sand increases its biogenicity and intensifies biodegradation. These processes are greatly inhibited by creating a mineral screen (sand without mixing) on the surface of the peat soil. Deep reclamational tilling of thin peatbogs, which produces from the underlying mineral substrate a thicker (20-25 cm) organic-mineral plowed layer, ensures a high biological activity and fertility of the new soil. Mixing the peat layer into the soil profile by tilling promotes its preservation from rapid biodegradation.

  5. Peat bogs offer a reliable, local source of fuel in several states

    SciTech Connect

    Punwani, D.V.

    1981-10-01

    With total estimated US peat resources equivalent to the energy content of 240-billion bbl of oil, peat could be a significant energy resource even if only a fraction of it can be recovered. Resource estimates include only those areas (mostly in eight states) with at least 80 acres/sq mi of peat, where the deposits are at least 4 ft deep. Peat fuel properties, new equipment for peat harvesting and dewatering, and modern combustion technology are described. Conversion to synthetic fuels looks promising.

  6. Preferential degradation of polyphenols from Sphagnum - 4-Isopropenylphenol as a proxy for past hydrological conditions in Sphagnum-dominated peat

    NASA Astrophysics Data System (ADS)

    Schellekens, Judith; Bindler, Richard; Martínez-Cortizas, Antonio; McClymont, Erin L.; Abbott, Geoffrey D.; Biester, Harald; Pontevedra-Pombal, Xabier; Buurman, Peter

    2015-02-01

    The net accumulation of remains of Sphagnum spp. is fundamental to the development of many peatlands. The effect of polyphenols from Sphagnum on decomposition processes is frequently cited but has barely been studied. The central area of the Rödmossamyran peatland (Sweden) is an open lawn that consists mostly of Sphagnum spp. with a very low contribution from vascular plants. In order to determine the effects of decay on sphagnum phenols, 53 samples of a 2.7 m deep core from this lawn were analysed with pyrolysis gas chromatography-mass spectrometry (pyrolysis-GC-MS) and compared with more traditional decomposition proxies such as C/N ratio, UV light transmission of alkaline peat extracts, and bulk density. Factor analysis of 72 quantified pyrolysis products suggested that the variation in 4-isopropenylphenol was largely determined by aerobic decomposition instead of Sphagnum abundance. In order to evaluate the effects of aerobic decay in Sphagnum peat, down-core records from different climatic regions were compared using molecular markers for plant biopolymers and C/N ratio. These included markers for lignin from vascular plants ((di)methoxyphenols), polyphenols from Sphagnum spp. (4-isopropenylphenol), and cellulose (levoglucosan). Our results indicate that polyphenols from Sphagnum are preferentially degraded over polysaccharides; consequently the variability of the marker for sphagnum acid, 4-isopropenylphenol, was found indicative of decomposition instead of reflecting the abundance of Sphagnum remains. The fact that 4-isopropenylphenol is aerobically degraded in combination with its specificity for Sphagnum spp. makes it a consistent indicator of past hydrological conditions in Sphagnum-dominated peat. In contrast, the variability of C/N records in Sphagnum-dominated peat was influenced by both vegetation shifts and decomposition, and the dominant effect differed between the studied peatlands. Our results provide direction for modelling studies that try to

  7. Advancement of peat hydrogasification. Final report, July 1983

    SciTech Connect

    Garey, M.P.; Rosemary, J.K.

    1983-07-01

    This final technical report summarizes the results of a preliminary conceptual commercial-scale peat hydrogasification plant study performed for the US Department of Energy by the Energy Systems Group of Rockwell International and its subcontractor, the C.E. Lummus Company. The plant design is based on the Rockwell single-stage, entrained flow, short-residence-time hydrogasifier in which peat and hot hydrogen are reacted to produce SNG and a high-value co-product liquid, predominantly chemical-grade benzene. The overall design objective was to integrate the Rockwell hydrogasifier with a combination of unit operations and plant subsystems to yield an effective and economic plant for producing 250 billion Btu per stream day of pipeline quality SNG from peat. The report is divided into two parts. Part I contains a summary of the work performed by Rockwell in support of the Lummus plant design effort. Rockwell provided to Lummus correlations of reactor performance data, cost and design information pertaining to the reactor train, specifications of equipment requirements for the peat drying and pulverization system, and preliminary material balances for an alternate plant design based upon the use of a partial oxidation gasifier system for hydrogen generation. Lummus performed the major part of this study. Their final report to Rockwell is presented in its entirety as Part II of this document. Included are the design and economic bases for the commercial-scale plant concept, detailed descriptions of the selected process configurations, and preliminary order of magnitude estimates for the capital requirements, the net annual operating costs, and an average cost of gas for the proposed plant design. The Lummus section and a review article on peat have been entered separately. (LTN)

  8. The role of peat double porosity on groundwater-surface water interaction in a drained fen

    NASA Astrophysics Data System (ADS)

    Rossi, P. M.; Ala-aho, P.; Ronkanen, A.-K.

    2012-04-01

    Groundwater discharge from an esker aquifer to a fen was studied to understand relevant hydrological processes for surface-groundwater interaction in an esker-peatland hillslope. Piezometric levels of the peat layer and esker sand layer were continuously monitored and compared to climate data. Groundwater exfiltration points were spatially mapped and related to peat depth. The study showed a clear interaction between fen surface water and sand esker groundwater although the hydraulic conductivity of peat was low and the peat depth thick. In the artesian aquifer beneath the fen, the piezometric head showed a clear response to precipitation and evapotranspiration. Wetting of the peat is rapidly seen as pressure increase in the confined aquifer. This provides new information on hydraulics of wetlands found in aquifer discharge areas. Groundwater exfiltrated through thick peat layers in vertical preferential point discharges demonstrating how double porosity provides flow through the peat layer with low hydraulic conductivity in the peat matrix. The "pipe flow" channels were found in the deep peat area in the transition zones from deep peat to shallow peat. Diffuse seepage through the ditch bottom was found where ditches cut into the sand layer. Increased discharge through the ditch bed reduced the flow resistance at the aquifer boundary which can lower the groundwater level in the esker. The results show new processes in the groundwater discharge zone that are useful for groundwater modeling and policy development for future groundwater protection.

  9. Comparison of Shear Strength Properties for Undisturbed and Reconstituted Parit Nipah Peat, Johor

    NASA Astrophysics Data System (ADS)

    Azhar, A. T. S.; Norhaliza, W.; Ismail, B.; Abdullah, M. E.; Zakaria, M. N.

    2016-11-01

    Shear strength of soil is required to determine the soil stability and design the foundations. Peat is known as a soil with complex natural formations which also contributes problems to the researchers, developers, engineers and contractors in constructions and infrastructures. Most researchers conducted experiment and investigation of shear strength on peat using shear box test and simple shear test, but only a few had discovered the behavior of peat using triaxial consolidated undrained test. The aim of this paper is to determine the undrained shear strength properties of reconstituted peat and undisturbed peat of Parit Nipah, Johor for comparison purposes. All the reconstituted peat samples were formed with the size that passed opening sieve 3.35 mm and preconsolidation pressure at 100 kPa. The result of undrained shear strength of reconstituted peat was 21kPa for cohesion with the angle of friction, 41° compare to the undisturbed peat with cohesion 10 kPa and angle of friction, 16°. The undrained shear strength properties result obtained shows that the reconstituted peat has higher strength than undisturbed peat. For relationship deviator stress-strain, σd max and excess pore pressure, Δu, it shows that both of undisturbed and reconstituted gradually increased when σ’ increased, but at the end of the test, the values are slightly dropped. The physical properties of undisturbed and reconstituted peat were also investigated to correlate with the undrained shear strength results.

  10. Sketch maps showing areal extent, thickness and amount of commercial-quality peat in deposits of southern and western Maine

    USGS Publications Warehouse

    Cameron, C.C.; Mullen, M.K.

    1982-01-01

    Peat deposits in southern and western Maine were investigated for their estimated potential as peat resources suitable for energy, horticultural, and agricultural uses. Fifty-six sketch maps illustrate the areal extent, thickness, and amount of commercial-quality peat. The total yield is estimated at 27,736,400 short tons air-dried peat.

  11. A new soil mechanics approach to quantify and predict land subsidence by peat compression

    NASA Astrophysics Data System (ADS)

    Koster, Kay; Erkens, Gilles; Zwanenburg, Cor

    2016-10-01

    Land subsidence threatens many coastal areas. Quantifying current and predicting future subsidence are essential to sustain the viability of these areas with respect to rising sea levels. Despite its scale and severity, methods to quantify subsidence are scarce. In peat-rich subsidence hot spots, subsidence is often caused by peat compression. We introduce the standard Cone Penetration Test (CPT) as a technique to quantify subsidence due to compression of peat. In a test in the Holland coastal plain, the Netherlands, we found a strong relationship between thickness reduction of peat and cone resistance, due to an increase in peat stiffness after compression. We use these results to quantify subsidence of peat in subsiding areas of Sacramento-San Joaquin delta and Kalimantan, and found values corresponding with previously made observations. These results open the door for CPT as a new method to document past and predict future subsidence due to peat compression over large areas.

  12. Louisiana peat resources. Final technical report, 1 April 1981-15 April 1983

    SciTech Connect

    Kosters, E.C.; Bailey, A.

    1983-08-01

    Five peat prospect areas - Gueydan, Avery Island, Sale-Cypremort, Barataria, and Lake Pontchartrain - are representative of different types of South Louisiana peat deposits. Together, the prospects are estimated to contain about 20 x 10/sup 6/ metric tons of peat. Because these areas occupy only a small portion of the deltaic and chenier plains, there is potentially much more peat present in South Louisiana. Approximately 2000 samples, taken from about 200 auger holes and vibracores, were analyzed. Average values of Louisiana peat are 90% moisture, 80% organic matter (20% ash), a bulk density of 0.12 g/cm/sup 3/, and a Btu of 8515. The relationships between percent moisture and organic matter and between bulk density and depth indicate that compaction during the first few thousand years was minimal. Freshwater peats contain primarily kaolinite and quartz, whereas marine-influenced peats contain kaolinite, quartz, and water-soluble salts.

  13. Peat resource estimation in South Carolina. Second quarterly report (year 2)

    SciTech Connect

    Cohen, Dr., A. D.; Tisdale, M.; Andrejko, M.; Corvinus, D.; Knight, Richard A.; Olsen, N. K.; Vigerstad, Dr., T. J.

    1981-04-01

    The objectives of this program are to assess the magnitude of the resources and locate areas of highest potential for peat deposits in South Carolina. The energy potential of these peat resources is also being evaluated. This report presents the results of progress made during the last quarter in: assessing data and prioritizing peat areas to be surveyed; procurement of equipment and supplies; and preliminary peat resource assessment. A summary of the results of all new field surveys conducted during the quarter is included. Approximate locations of potential major peat deposits have been identified. Preliminary sampling studies indicate that Pigeon Bay may have the thickest and best quality peat in Berkeley County. Probes indicate peats up to 12 feet thick are located near the Black River in Georgetown County. Samples from areas designated as organic soils by the USDA were analyzed for moisture, organic, and ash content. (DMC)

  14. What controls the oxidative ratio of UK peats? A multi-site study of elemental CHNO concentrations in peat cores

    NASA Astrophysics Data System (ADS)

    Clay, Gareth; Worrall, Fred; Masiello, Carrie

    2013-04-01

    The oxidative ratio (OR) is the amount of CO2 sequestered in the terrestrial biosphere for each mol of O2 produced. The OR governs the effectiveness of a terrestrial biome to mitigate the impact of anthropogenic CO2 emissions and it has been used to calculate the balance of terrestrial and oceanic carbon sinks across the globe. However, few studies have investigated the controls of the variability in OR. What factors affect OR - climate? Soil type? Vegetation type? N deposition? Land use? Land use change? Small shifts in OR could have important implications in the global partitioning of CO2 between the atmosphere, biosphere, and oceans. This study looks at peat soils from a series of sites representing a climatic transect across the UK. Duplicate peat cores were taken, along with samples of above-ground vegetation and litter, from sites in northern Scotland (Forsinard), southern Scotland (Auchencorth), northern England (Moor House; Thorne Moor) through the Welsh borders (Whixhall Moss) and Somerset levels (Westhay Moor) to Dartmoor and Bodmin Moor in the south west of England. Sub-samples of the cores were analysed for their CHNO concentrations using a Costech ECS 4010 Elemental combustion system. Using the method of Masiello et al. (2008), OR values could be calculated from these elemental concentrations. Results show that OR values of UK peats varied between 0.82 and 1.27 with a median value of 1.08 which is within the range of world soils. There were significant differences in OR of the peat between sites with the data falling into two broad groupings - Group 1: Forsinard, Auchencorth, Dartmoor and Bodmin Moor; Group 2: Moor House, Thorne Moor, Westhay Moor, Whixhall Moss. Whilst there were significant changes (p < 0.05) in elemental ratios with increasing peat depth (increasing C:N ratio and decreasing O:C ratio) there was no significant difference overall in OR with depth. This paper will explore some of the possible controlling factors on these ratios. Local

  15. The Band Must Not Be Abandoned.

    PubMed

    Brown, Wendy A; O'Brien, Paul E

    2017-03-06

    The use of laparoscopic adjustable gastric banding (LAGB) is on the decline around the world despite the evidence base suggesting that it is a safe, effective and durable short-stay procedure which can be safely revised and is well tolerated by patients when they are appropriately supported. Currently, less than 1% of eligible obese persons are choosing to undergo bariatric surgery. If we are to improve uptake of bariatric surgery we need a raft of therapeutic options, including the LAGB, which sit between the relative impotence of medical therapies and the aggression of stapling procedures. This brief communication discusses what some of the drivers may be that are leading surgeons to abandon the band.

  16. 17 CFR 230.155 - Integration of abandoned offerings.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 17 Commodity and Securities Exchanges 2 2012-04-01 2012-04-01 false Integration of abandoned... GENERAL RULES AND REGULATIONS, SECURITIES ACT OF 1933 General § 230.155 Integration of abandoned offerings... from integration of private and registered offerings. Because of the objectives of Rule 155 and...

  17. 17 CFR 230.155 - Integration of abandoned offerings.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 17 Commodity and Securities Exchanges 2 2011-04-01 2011-04-01 false Integration of abandoned... GENERAL RULES AND REGULATIONS, SECURITIES ACT OF 1933 General § 230.155 Integration of abandoned offerings... from integration of private and registered offerings. Because of the objectives of Rule 155 and...

  18. 17 CFR 230.155 - Integration of abandoned offerings.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 17 Commodity and Securities Exchanges 2 2013-04-01 2013-04-01 false Integration of abandoned... GENERAL RULES AND REGULATIONS, SECURITIES ACT OF 1933 General § 230.155 Integration of abandoned offerings... from integration of private and registered offerings. Because of the objectives of Rule 155 and...

  19. 17 CFR 230.155 - Integration of abandoned offerings.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 17 Commodity and Securities Exchanges 2 2010-04-01 2010-04-01 false Integration of abandoned... GENERAL RULES AND REGULATIONS, SECURITIES ACT OF 1933 General § 230.155 Integration of abandoned offerings... from integration of private and registered offerings. Because of the objectives of Rule 155 and...

  20. 37 CFR 2.68 - Express abandonment (withdrawal) of application.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 37 Patents, Trademarks, and Copyrights 1 2010-07-01 2010-07-01 false Express abandonment (withdrawal) of application. 2.68 Section 2.68 Patents, Trademarks, and Copyrights UNITED STATES PATENT AND... Action by Applicants § 2.68 Express abandonment (withdrawal) of application. (a) Written...

  1. 32 CFR 644.494 - Donation, abandonment or destruction.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 32 National Defense 4 2010-07-01 2010-07-01 true Donation, abandonment or destruction. 644.494 Section 644.494 National Defense Department of Defense (Continued) DEPARTMENT OF THE ARMY (CONTINUED) REAL... Land) § 644.494 Donation, abandonment or destruction. (a) General. Improvements may be...

  2. 15 CFR 904.508 - Voluntary forfeiture by abandonment.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 15 Commerce and Foreign Trade 3 2011-01-01 2011-01-01 false Voluntary forfeiture by abandonment. 904.508 Section 904.508 Commerce and Foreign Trade Regulations Relating to Commerce and Foreign Trade... PROCEDURES Seizure and Forfeiture Procedures § 904.508 Voluntary forfeiture by abandonment. (a) The owner...

  3. 15 CFR 904.508 - Voluntary forfeiture by abandonment.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 15 Commerce and Foreign Trade 3 2014-01-01 2014-01-01 false Voluntary forfeiture by abandonment. 904.508 Section 904.508 Commerce and Foreign Trade Regulations Relating to Commerce and Foreign Trade... PROCEDURES Seizure and Forfeiture Procedures § 904.508 Voluntary forfeiture by abandonment. (a) The owner...

  4. 40 CFR 147.3102 - Plugging and abandonment plans.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 22 2010-07-01 2010-07-01 false Plugging and abandonment plans. 147... PROGRAMS (CONTINUED) STATE, TRIBAL, AND EPA-ADMINISTERED UNDERGROUND INJECTION CONTROL PROGRAMS Lands of Certain Oklahoma Indian Tribes § 147.3102 Plugging and abandonment plans. In lieu of the requirements...

  5. 40 CFR 147.3104 - Notice of abandonment.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 22 2010-07-01 2010-07-01 false Notice of abandonment. 147.3104... (CONTINUED) STATE, TRIBAL, AND EPA-ADMINISTERED UNDERGROUND INJECTION CONTROL PROGRAMS Lands of Certain Oklahoma Indian Tribes § 147.3104 Notice of abandonment. (a) In addition to the notice required by §...

  6. 40 CFR 147.3105 - Plugging and abandonment report.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 22 2010-07-01 2010-07-01 false Plugging and abandonment report. 147... PROGRAMS (CONTINUED) STATE, TRIBAL, AND EPA-ADMINISTERED UNDERGROUND INJECTION CONTROL PROGRAMS Lands of Certain Oklahoma Indian Tribes § 147.3105 Plugging and abandonment report. (a) In lieu of the time...

  7. Book review: old fields: dynamics and restoration of abandoned farmland

    Technology Transfer Automated Retrieval System (TEKTRAN)

    The 2007 volume, “Old Fields: Dynamics and Restoration of Abandoned Farmland”, edited by VA Cramer and RJ Hobbs and published by the Society for Ecological Restoration International (Island Press), is a valuable attempt to synthesize a dozen case studies on agricultural abandonment from all of the ...

  8. 28 CFR 104.35 - Claims deemed abandoned by claimants.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 28 Judicial Administration 2 2010-07-01 2010-07-01 false Claims deemed abandoned by claimants. 104.35 Section 104.35 Judicial Administration DEPARTMENT OF JUSTICE (CONTINUED) SEPTEMBER 11TH VICTIM COMPENSATION FUND OF 2001 Claim Intake, Assistance, and Review Procedures § 104.35 Claims deemed abandoned...

  9. 28 CFR 104.35 - Claims deemed abandoned by claimants.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 28 Judicial Administration 2 2011-07-01 2011-07-01 false Claims deemed abandoned by claimants. 104.35 Section 104.35 Judicial Administration DEPARTMENT OF JUSTICE (CONTINUED) SEPTEMBER 11TH VICTIM COMPENSATION FUND OF 2001 Claim Intake, Assistance, and Review Procedures § 104.35 Claims deemed abandoned...

  10. 43 CFR 3162.3-4 - Well abandonment.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 43 Public Lands: Interior 2 2011-10-01 2011-10-01 false Well abandonment. 3162.3-4 Section 3162.3... Operating Rights Owners and Operators § 3162.3-4 Well abandonment. (a) The operator shall promptly plug and... newly completed or recompleted well in which oil or gas is not encountered in paying quantities or...

  11. 43 CFR 3162.3-4 - Well abandonment.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 43 Public Lands: Interior 2 2014-10-01 2014-10-01 false Well abandonment. 3162.3-4 Section 3162.3... Operating Rights Owners and Operators § 3162.3-4 Well abandonment. (a) The operator shall promptly plug and... newly completed or recompleted well in which oil or gas is not encountered in paying quantities or...

  12. 43 CFR 3162.3-4 - Well abandonment.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 43 Public Lands: Interior 2 2012-10-01 2012-10-01 false Well abandonment. 3162.3-4 Section 3162.3... Operating Rights Owners and Operators § 3162.3-4 Well abandonment. (a) The operator shall promptly plug and... newly completed or recompleted well in which oil or gas is not encountered in paying quantities or...

  13. 43 CFR 3162.3-4 - Well abandonment.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 43 Public Lands: Interior 2 2013-10-01 2013-10-01 false Well abandonment. 3162.3-4 Section 3162.3... Operating Rights Owners and Operators § 3162.3-4 Well abandonment. (a) The operator shall promptly plug and... newly completed or recompleted well in which oil or gas is not encountered in paying quantities or...

  14. 21 CFR 1315.27 - Abandonment of quota.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 21 Food and Drugs 9 2012-04-01 2012-04-01 false Abandonment of quota. 1315.27 Section 1315.27 Food and Drugs DRUG ENFORCEMENT ADMINISTRATION, DEPARTMENT OF JUSTICE IMPORTATION AND PRODUCTION QUOTAS FOR EPHEDRINE, PSEUDOEPHEDRINE, AND PHENYLPROPANOLAMINE Individual Manufacturing Quotas § 1315.27 Abandonment...

  15. 21 CFR 1315.27 - Abandonment of quota.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 21 Food and Drugs 9 2010-04-01 2010-04-01 false Abandonment of quota. 1315.27 Section 1315.27 Food and Drugs DRUG ENFORCEMENT ADMINISTRATION, DEPARTMENT OF JUSTICE IMPORTATION AND PRODUCTION QUOTAS FOR EPHEDRINE, PSEUDOEPHEDRINE, AND PHENYLPROPANOLAMINE Individual Manufacturing Quotas § 1315.27 Abandonment...

  16. 21 CFR 1315.27 - Abandonment of quota.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 21 Food and Drugs 9 2011-04-01 2011-04-01 false Abandonment of quota. 1315.27 Section 1315.27 Food and Drugs DRUG ENFORCEMENT ADMINISTRATION, DEPARTMENT OF JUSTICE IMPORTATION AND PRODUCTION QUOTAS FOR EPHEDRINE, PSEUDOEPHEDRINE, AND PHENYLPROPANOLAMINE Individual Manufacturing Quotas § 1315.27 Abandonment...

  17. 21 CFR 1315.27 - Abandonment of quota.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 21 Food and Drugs 9 2013-04-01 2013-04-01 false Abandonment of quota. 1315.27 Section 1315.27 Food and Drugs DRUG ENFORCEMENT ADMINISTRATION, DEPARTMENT OF JUSTICE IMPORTATION AND PRODUCTION QUOTAS FOR EPHEDRINE, PSEUDOEPHEDRINE, AND PHENYLPROPANOLAMINE Individual Manufacturing Quotas § 1315.27 Abandonment...

  18. 21 CFR 1315.27 - Abandonment of quota.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 21 Food and Drugs 9 2014-04-01 2014-04-01 false Abandonment of quota. 1315.27 Section 1315.27 Food and Drugs DRUG ENFORCEMENT ADMINISTRATION, DEPARTMENT OF JUSTICE IMPORTATION AND PRODUCTION QUOTAS FOR EPHEDRINE, PSEUDOEPHEDRINE, AND PHENYLPROPANOLAMINE Individual Manufacturing Quotas § 1315.27 Abandonment...

  19. 25 CFR 214.29 - Prospecting; abandonment of mines.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 25 Indians 1 2014-04-01 2014-04-01 false Prospecting; abandonment of mines. 214.29 Section 214.29 Indians BUREAU OF INDIAN AFFAIRS, DEPARTMENT OF THE INTERIOR ENERGY AND MINERALS LEASING OF OSAGE... prospecting or mining operations or the abandonment of a well or mine shall be subject to the approval of...

  20. Abandoning pipelines working group regulatory issues

    SciTech Connect

    1997-03-01

    The history of hydrocarbon development in Louisiana and off its coast is one of the interdependence of technological innovation, entrepreneurial risk-taking, resource management, judicial decisions, legislation, marketing, employee good will, infrastructure and support services, coupled with favorable geologic structures that made early exploration and development relatively easy. Mariners sailing off the coast of Louisiana and Texas in the 1600`s recorded one of the earliest known natural oil seeps. They shrugged it off as unimportant, as there was no market for the substance they witnessed. The seepage, however, provided a tiny clue to the vast storehouse of hydrocarbons trapped in the earth`s crust extending from the uplands, through Louisiana`s swamps and marshes, and into the subaqueous habitats of the Gulf of Mexico-the world`s ninth largest body of water. In all cases, each move into a new geographic province required considerable change in operation philosophy and in the science supporting the exploration and development activity. As technology changed, or was developed to meet the industry`s needs, new frontiers were explored. However, with time-as is the case with any nonrenewable resource-fields and wells lost their productive life. They had to be abandoned. In fact, the Minerals Management Service suggests that within the next 10 years the offshore industry will remove 150 platforms per year, or nearly half of the current number of production units. The industry will be asked to dispose of nearly one unit every 2.4 days. If this is the case, abandonment issues are going to continue to surface.

  1. Effects of spatial heterogeneity in moisture content on the horizontal spread of peat fires.

    PubMed

    Prat-Guitart, Nuria; Rein, Guillermo; Hadden, Rory M; Belcher, Claire M; Yearsley, Jon M

    2016-12-01

    The gravimetric moisture content of peat is the main factor limiting the ignition and spread propagation of smouldering fires. Our aim is to use controlled laboratory experiments to better understand how the spread of smouldering fires is influenced in natural landscape conditions where the moisture content of the top peat layer is not homogeneous. In this paper, we study for the first time the spread of peat fires across a spatial matrix of two moisture contents (dry/wet) in the laboratory. The experiments were undertaken using an open-top insulated box (22×18×6cm) filled with milled peat. The peat was ignited at one side of the box initiating smouldering and horizontal spread. Measurements of the peak temperature inside the peat, fire duration and longwave thermal radiation from the burning samples revealed important local changes of the smouldering behaviour in response to sharp gradients in moisture content. Both, peak temperatures and radiation in wetter peat (after the moisture gradient) were sensitive to the drier moisture condition (preceding the moisture gradient). Drier peat conditions before the moisture gradient led to higher temperatures and higher radiation flux from the fire during the first 6cm of horizontal spread into a wet peat patch. The total spread distance into a wet peat patch was affected by the moisture content gradient. We predicted that in most peat moisture gradients of relevance to natural ecosystems the fire self-extinguishes within the first 10cm of horizontal spread into a wet peat patch. Spread distances of more than 10cm are limited to wet peat patches below 160% moisture content (mass of water per mass of dry peat). We found that spatial gradients of moisture content have important local effects on the horizontal spread and should be considered in field and modelling studies.

  2. Age models for peat deposits on the basis of coupled lead-210 and radiocarbon data.

    NASA Astrophysics Data System (ADS)

    Piotrowska, Natalia; de Vleeschouwer, François; Sikorski, Jarosław; Sensuła, Barbara; Michczyński, Adam; Fiałkiewicz-Kozieł, Barbara; Palowski, Bernard

    2010-05-01

    The study presents three examples of age-model construction based on the results of 210Pb and 14C dating methods applied to peat deposits. The three sites are ombrotrophic peat bogs: the Misten (Belgium), Slowinskie Bloto (N Poland) and Puscizna Mala (S Poland). All sites have been subjected to multiproxy studies aimed at reconstructing paleoenvironment and human activity, covering the last 1500, 1300 and 1800 years, respectively (De Vleeschouwer et al. 2009A, 2009B, in prep., Fialkiewicz-Koziel, ongoing PhD). A detailed comparison between 210Pb and post-bomb 14C results in the Misten bog has also been carried out by Piotrowska et al. (2009). In all cores, the 210Pb activity was calculated using 210Po and 208Po activities after acid-extraction from bulk samples, subsequent deposition on silver discs and measurements by alpha spectrometry. Unsupported 210Pb was detected until 35cm in Slowinskie Bloto, 15cm in the Misten and 19cm in Puscizna Mala. Constant Rate of Supply (CRS) model was then applied to compute ages of each 1-cm core interval. For the Misten and Slowinskie Bloto, radiocarbon measurements were performed on selected aboveground plant macrofossils, mainly Sphagnum spp. or Calluna vulgaris, Erica tetralix, and Andromeda polyfolia. Radiocarbon ages were determined using accelerator mass spectrometry (AMS) after acid-alkali-acid wash, combustion, purification of carbon dioxide and graphitisation. For Puscizna Mala bulk samples were dated after chemical preparation of benzene for liquid scintillation counting (LSC) or CO2 for gas proportional counting (GPC). Radiocarbon calibration was undertaken using the Intcal04 calibration curve and OxCal 4 software. As a priori information the 210Pb-derived ages were used in a P_Sequence model (Bronk Ramsey, 2008). A number of dates characterized by low agreement with stratigraphical order had to be considered as outliers and rejected from the final age model. For building a continuous age models a non-linear approach

  3. South Florida wetlands ecosystem; biogeochemical processes in peat

    USGS Publications Warehouse

    Orem, William; ,

    1996-01-01

    The South Florida wetlands ecosystem is an environment of great size and ecological diversity (figs. 1 and 2). The landscape diversity and subtropical setting of this ecosystem provide a habitat for an abundance of plants and wildlife, some of which are unique to South Florida. South Florida wetlands are currently in crisis, however, due to the combined effects of agriculture, urbanization, and nearly 100 years of water management. Serious problems facing this ecosystem include (1) phosphorus contamination producing nutrient enrichment, which is causing changes in the native vegetation, (2) methylmercury contamination of fish and other wildlife, which poses a potential threat to human health, (3) changes in the natural flow of water in the region, resulting in more frequent drying of wetlands, loss of organic soils, and a reduction in freshwater flow to Florida Bay, (4) hypersalinity, massive algal blooms, and seagrass loss in parts of Florida Bay, and (5) a decrease in wildlife populations, especially those of wading birds. This U.S. Geological Survey (USGS) project focuses on the role of organic-rich sediments (peat) of South Florida wetlands in regulating the concentrations and impact of important chemical species in the environment. The cycling of carbon, nitrogen, phosphorus, and sulfur in peat is an important factor in the regulation of water quality in the South Florida wetlands ecosystem. These elements are central to many of the contamination issues facing South Florida wetlands, such as nutrient enrichment, mercury toxicity, and loss of peat. Many important chemical and biological reactions occur in peat and control the fate of chemical species in wetlands. Wetland scientists often refer to these reactions as biogeochemical processes, because they are chemical reactions usually mediated by microorganisms in a geological environment. An understanding of the biogeochemical processes in peat of South Florida wetlands will provide a basis for evaluating the

  4. Regional Haze Evolved from Peat Fires - an Overview

    NASA Astrophysics Data System (ADS)

    Hu, Yuqi; Rein, Guillermo

    2016-04-01

    This work provides an overview of haze episodes, their cause, emissions and health effects found in the scientific literature. Peatlands, the terrestrial ecosystems resulting from the accumulation of partially decayed vegetation, become susceptible to smouldering fires because of natural droughts or anthropogenic-induced drainages. Once ignited, smouldering peat fires persistently consume large amounts of soil carbon in a flameless form. It is estimated that the average annual carbon gas emissions (mainly CO2 and CO) from peat fires are equivalent to 15% of manmade emissions, representing influential perturbation of global carbon circle. In addition to carbon emissions, smouldering peat fires emit substantial quantities of heterogeneous smoke, which is responsible for haze phenomena, has not yet been fully studied. Peat-fire-derived smoke is characterized by high concentration of particulate matter (PM), ranging from nano-scale ultrafine fraction (PM1, particle diameter < 1 μm) to micro-scale fine (PM2.5, particle diameter < 2.5 μm) and coarse fraction (PM10, particle diameter < 10 μm). The dispersal of the smoke could be blocked due to the stagnant weather condition, and then low buoyant smoke plume could accumulate and migrate long distances, leading to regional haze. Apart from air quality deterioration, haze leads to severe reduction in visibility, which strongly affects local transportation, construction, tourism and agriculture-based industries. For example, an unprecedented peatland mega-fire burst on the Indonesian islands Kalimantan and Sumatra during the 1997 El-Niño event, resulting in transboundary smoke-haze disaster. Severe haze events continue to appear in Southeast Asia every few years due to periodical peat fires in this region. In addition, smouldering peat fires have been frequently reported in tropical, temperate and boreal regions (Botswana in 2000, North America in 2004, Scotland in 2006 and Central Russia in 2010 et al.), peat

  5. Identification of organic matter from peat, leonardite and lignite fertilisers using humification parameters and electrofocusing.

    PubMed

    Cavani, L; Ciavatta, C; Gessa, C

    2003-01-01

    The organic matter extracted from peats (P), leonardites (Le) and lignites (Li) was characterised by humification parameters and electrofocusing (EF). The degree of humification and the humification index might be used to distinguish P from Le and Li, but not Le from Li because they showed overlapped values, while the humification rate could be used only for the identification of Le and EF profiles of P, Le and Li fertilisers revealed different band patterns: P samples did not show bands in the region with isoelectric point, pI > 4.4; Le samples showed very intense bands in the region with pI > 4.4; Li samples showed a very different band pattern with poorly resolved bands in the region with pI > 3.8. P, Le and Li samples can be distinguished by combining humification parameters and EF.

  6. Use of humic acids derived from peat and lignite as phenanthrene sorbents

    NASA Astrophysics Data System (ADS)

    Sofikitis, Elias; Giannouli, Andriana; Kalaitzidis, Stavros; Christanis, Kimon; Karapanagioti, Hrissi K.; Papanicolaou, Cassiani

    2015-04-01

    A broad range of materials is being applied for environmental remediation of water, among them sorbents such as humic acids. Being natural substances, the extraction and purification of humic acids might be cheaper than the production of synthetic sorbents. Having higher absorbing capacity than most of the sorbents used to date, humic acids have a competitive advantage against commonly used sorbents such as active charcoals and biochar. Humic acids are "complex colloidal super-mixtures" that are characterized by their functional groups. Therefore, composition and molecular formula can vary depending on the properties of the parent material. The aim of this project was (a) to study the sorption capacity of humic acids derived from peat and lignite samples picked up from deposits spread throughout Greece and (b) to compare the results with these of the parent materials. This comparison provides an insight to which matrix samples are suitable for further chemical treatment for the isolation of humic acids to be used as sorbents. The selected model pollutant was phenanthrene, which is a PAH that consists of three fused benzene rings. Humic acids were extracted according to the methodology proposed by the IHSS, slightly modified, in order to fit better to the properties of organic sediments. Sorption experiments were conducted by mixing 0.004 g of the sorbent (peat or lignite or humic acid) with aqueous solutions of phenanthrene at different concentrations of 30, 50, 100, 300, and 500 μg/L. The results show that phenanthrene sorption is higher for the humic acid than for the original lignite and peat samples. The original samples display higher sorption at the lower phenanthere solutions (30 μg/L; Kd ranges from 15,000 to 47,000 L/kg) than at the higher one (500 μg/L; Kd ranges from 4,100 to 13,000 L/Kg) suggesting non-linear sorption. The humic acids display mainly linear isotherms with Kd ranges from 6,600 to 120,000 L/kg. Concerning the suitability of the studied

  7. Tracing of ca 800 yr old mining activity in peat bog using Pb elemental concentrations and isotope compositions.

    NASA Astrophysics Data System (ADS)

    Baron, S.; Carignan, J.; Ploquin, A.

    2003-04-01

    Sixty sites of slags have been documented on the Mont-Lozère in southern France. The petrographic analysis shows that slags are metallurgical wastes (800 to 850 yr BP) which certainly result from smelting activity for lead and silver extraction (Ploquin et al., 2001). The aims of this study are: 1) to trace the source of Pb ores which supplied the smelting sites, by using the Pb isotopic composition of several surrounding Pb deposits, 2) to evaluate the actual pollution caused by these slags, by using elemental and isotopic compositions of soils, water and vegetation, and 3) to document the pollution history of the region, by using elemental and isotopic compositions of peat bog cores collected in the neighbourhood of the historical smelting sites. The lead isotopic composition of galena collected in most surrounding ores is very similar to that of different slag samples. On the other hand, the high precision of the results allowed us to select the mineralised areas which were probably the ore sources. The Pb isotopic composition of slags is even more homogeneous: 208/206 Pb: 2.092±0.002; 206/207 Pb: 1.179±0.001; 208/204 Pb: 38.663±0.025; 207/204 Pb: 15.665±0.006; 206/204 Pb: 18.476±0.023, and will allow source tracing in the environment. The "Narses Mortes" peat bog, around which two smelting sites have been reported, is strongly minerotrophic and contains 8 to 60% ash. A 1.40 m core have been retrieved and divided into 58 individual samples. Minerotrophic peat bog records both atmospheric deposition, soils leaching and the grounwater influence. The measured metal concentrations are normalised to Al contents of peat bog samples and the metal/Al ratios are compared to that of the Mont-Lozère granite: relative excess in metal concentrations are found in peat bog samples. An increasing excess of most metals (Pb, Zn, Cd...) was measured for surface samples, from 55 cm depth to the top of the core (23 cm depth). This profil might be attributed to atmospheric

  8. Strong Wavelength Dependence of Aerosol Light Absorption from Peat Combustion

    NASA Astrophysics Data System (ADS)

    Gyawali, M. S.; Chakrabarty, R. K.; Yatavelli, R. L. N.; Chen, L. W. A. A.; Knue, J.; Samburova, V.; Watts, A.; Moosmüller, H.; Arnott, W. P.; Wang, X.; Zielinska, B.; Chow, J. C.; Watson, J. G.; Tsibart, A.

    2014-12-01

    Globally, organic soils and peats may store as much as 600 Gt of terrestrial carbon, representing 20 - 30% of the planet's terrestrial organic carbon mass. This is approximately the same carbon mass as that contained in Earth's atmosphere, despite peatlands occupying only 3% of its surface. Effects of fires in these ecosystems are of global concern due to their potential for enormous carbon release into the atmosphere. The implications for contributions of peat fires to the global carbon cycle and radiative forcing scenarios are significant. Combustion of peat mostly takes place in the low temperature, smoldering phase of a fire. It consumes carbon that may have accumulated over a period of hundreds to thousands of years. In comparison, combustion of aboveground biomass fuels releases carbon that has accumulated much more recently, generally over a period of years or decades. Here, we report our findings on characterization of emissions from laboratory combustion of peat soils from three locations representing the biomes in which these soils occur. Peat samples from Alaska and Florida (USA) and Siberia (Russia) were burned at two different fuel moisture levels. Burns were conducted in an 8-m3 volume combustion chamber located at the Desert Research Institute, Reno, NV, USA. We report significant brown carbon production from combustion of all three peat soils. We used a multispectral (405, 532, 781 nm) photoacoustic instrument equipped with integrating nephelometer to measure the wavelength-dependent aerosol light absorption and scattering. Absorption Ångström exponents (between 405 and 532 nm) as high as ten were observed, revealing strongly enhanced aerosol light absorption in the violet and blue wavelengths. Single scattering albedos (SSA) of 0.94 and 0.99 were observed at 405 and 532 nm, respectively, for the same sample. Variability of these optical parameters will be discussed as a function of fuel and combustion conditions. Other real-time measurements

  9. Reduction of trichloroethylene and nitrate by zero-valent iron with peat.

    PubMed

    Min, Jee-Eun; Kim, Meejeong; Pardue, John H; Park, Jae-Woo

    2008-02-01

    The feasibility of using zero-valent iron (ZVI) and peat mixture as in situ barriers for contaminated sediments and groundwater was investigated. Trichloroethylene (TCE) and nitrate (NO(3)(-)), redox sensitive contaminants were reduced by ZVI and peat soil mixture under anaerobic condition. Peat was used to support the sorption of TCE, microbial activity for biodegradation of TCE and denitrification while TCE and nitrate were reduced by ZVI. Decreases in TCE concentrations were mainly due to ZVI, while peat supported denitrifying microbes and further affected the sorption of TCE. Due to the competition of electrons, nitrate reduction was inhibited by TCE, while TCE reduction was not affected by nitrate. From the results of peat and sterilized peat, it can be concluded that peat was involved in both dechlorination and denitrification but biological reduction of TCE was negligible compared to that of nitrate. The results from hydrogen and methane gas analyses confirmed that hydrogen utilization by microbes and methanogenic process had occurred in the ZVI-peat system. Even though effect of the peat on TCE reduction were quantitatively small, ZVI and peat contributed to the removal of TCE and nitrate independently. The 16S rRNA analysis revealed that viable bacterial diversity was narrow and the most frequently observed genera were Bacillus and Staphylococcus spp.

  10. Annual sulfate budgets for Dutch lowland peat polders: The soil is a major sulfate source through peat and pyrite oxidation

    NASA Astrophysics Data System (ADS)

    Vermaat, Jan E.; Harmsen, Joop; Hellmann, Fritz A.; van der Geest, Harm G.; de Klein, Jeroen J. M.; Kosten, Sarian; Smolders, Alfons J. P.; Verhoeven, Jos T. A.; Mes, Ron G.; Ouboter, Maarten

    2016-02-01

    Annual sulfate mass balances have been constructed for four low-lying peat polders in the Netherlands, to resolve the origin of high sulfate concentrations in surface water, which is considered a water quality problem, as indicated amongst others by the absence of sensitive water plant species. Potential limitation of these plants to areas with low sulfate was analyzed with a spatial match-up of two large databases. The peat polders are generally used for dairy farming or nature conservation, and have considerable areas of shallow surface water (mean 16%, range 6-43%). As a consequence of continuous drainage, the peat in these polders mineralizes causing subsidence rates generally ranging between 2 and 10 mm y-1. Together with pyrite oxidation, this peat mineralization the most important internal source of sulfate, providing an estimated 96 kg SO4 ha-1 mm-1 subsidence y-1. External sources are precipitation and water supplied during summer to compensate for water shortage, but these were found to be minor compared to internal release. The most important output flux is discharge of excess surface water during autumn and winter. If only external fluxes in and out of a polder are evaluated, inputs average 37 ± 9 and exports 169 ± 17 kg S ha-1 y-1. During summer, when evapotranspiration exceeds rainfall, sulfate accumulates in the unsaturated zone, to be flushed away and drained off during the wet autumn and winter. In some polders, upward seepage from early Holocene, brackish sediments can be a source of sulfate. Peat polders export sulfate to the regional water system and the sea during winter drainage. The available sulfate probably only plays a minor role in the oxidation of peat: we estimate that this is less than 10% whereas aerobic mineralization is the most important. Most surface waters in these polders have high sulfate concentrations, which generally decline during the growing season when aquatic sediments are a sink. In the sediment, this sulfur is

  11. Peat Formation on Minjerribah (North Stradbroke Island), subtropical eastern Australia

    NASA Astrophysics Data System (ADS)

    Moss, Patrick; Tibby, John; Barr, Cameron; Weerensena, Chagi; Gontz, Allen; Petherick, Lynda

    2016-04-01

    Minjerribah (North Stradbroke Island) is the second largest sand island in the world and contains extensive peat dominated wetlands, comprising ~20% of the total area of the island. These wetland systems include large areas of estuarine swamps [mainly mangrove forest (~16% of the island's wetland area)], freshwater swamps [both herb (~58% of the island's wetland area) and tree dominated (~20% of the island's wetland area)] and numerous lake systems [both perched and window lakes (~2% of the island's wetland area)]. This presentation will examine peat formation processes at four wetland sites: a late Holocene prograding beach system (Flinders Beach); a 150,000 year lacustrine system (Welsby Lagoon 1), as well as a late Holocene lacustrine/palustrine system (Welsby Lagoon 2); and a late Quaternary lacustrine/palustrine system (Tortoise Lagoon), as well as discussing broader environmental characteristics of Minjerribah's nationally and internationally important wetland systems.

  12. The sorption of Zectran on bottom sediments and peat moss

    SciTech Connect

    Matthews, E.W.; Faust, S.D.

    1981-01-01

    A modified analytical method employed to determine the insecticide Zectran in natural waters frequently has resulted in erroneous data. The errors have been attributed to interferences from particulate matter in these waters. In order to evaluate analytical interferences due to sorption of Zectran on particulates, a series of experiments was performed using bottom sediments and a peat moss in contact with aqueous solutions of zectran at a pH values of 6.0 and 20 degrees C. Isotherm studies confirmed that Zectran sorption occurs in a direct relation to the amount of chemically oxidizable carbon present in the bottom sediments or peat moss. However, the extent of sorption was limited, which suggested that particulates may not be the primary interference in the modified analytical method.

  13. Phenol oxidase activity in secondary transformed peat-moorsh soils

    NASA Astrophysics Data System (ADS)

    Styła, K.; Szajdak, L.

    2009-04-01

    The chemical composition of peat depends on the geobotanical conditions of its formation and on the depth of sampling. The evolution of hydrogenic peat soils is closely related to the genesis of peat and to the changes in water conditions. Due to a number of factors including oscillation of ground water level, different redox potential, changes of aerobic conditions, different plant communities, and root exudes, and products of the degradation of plant remains, peat-moorsh soils may undergo a process of secondary transformation conditions (Sokolowska et al. 2005; Szajdak et al. 2007). Phenol oxidase is one of the few enzymes able to degrade recalcitrant phenolic materials as lignin (Freeman et al. 2004). Phenol oxidase enzymes catalyze polyphenol oxidation in the presence of oxygen (O2) by removing phenolic hydrogen or hydrogenes to from radicals or quinines. These products undergo nucleophilic addition reactions in the presence or absence of free - NH2 group with the eventual production of humic acid-like polymers. The presence of phenol oxidase in soil environments is important in the formation of humic substances a desirable process because the carbon is stored in a stable form (Matocha et al. 2004). The investigations were carried out on the transect of peatland 4.5 km long, located in the Agroecological Landscape Park host D. Chlapowski in Turew (40 km South-West of Poznań, West Polish Lowland). The sites of investigation were located along Wyskoć ditch. The following material was taken from four chosen sites marked as Zbechy, Bridge, Shelterbelt and Hirudo in two layers: cartel (0-50cm) and cattle (50-100cm). The object of this study was to characterize the biochemical properties by the determination of the phenol oxidize activity in two layers of the four different peat-moors soils used as meadow. The phenol oxidase activity was determined spectrophotometrically by measuring quinone formation at λmax=525 nm with catechol as substrate by method of Perucci

  14. Petrified peat from a permian coal bed in Antarctica

    USGS Publications Warehouse

    Schopf, J.M.

    1970-01-01

    Petrified plant remains that composed a Permian peat deposit occur at a coal horizon in a local area of Mount Augusta near the Beardmore Glacier in Antarctica. This discovery is the first in the entire Gondwana area that yields plant materials as exquisitely preserved as the materials of the well-known coal-ball localities of the Northern Hemisphere. A sampling of anatomical details is illustrated.

  15. Modelling uncertainty of carbon stocks changes in peats.

    NASA Astrophysics Data System (ADS)

    Poggio, Laura; Gimona, Alessandro; Aalders, Inge; Morrice, Jane; Hough, Rupert

    2015-04-01

    Global warming might change the hydrology of upland blanket peats in Scotland with increased risk of release of the stored carbon. It is therefore important to model the loss of carbon in peat areas with estimation of the damage potential. The presented approach has the potential to provide important information for the assessment of carbon stocks over large areas, but also in case of changes of land use, such as construction of wind farms. The provided spatial uncertainty is important for including the results in further environmental and climate-change models and for decision making in order to provide alternatives and prioritisation. In this study, main peat properties (i.e. depth, water content, bulk density and carbon content) were modelled using a hybrid GAM-geostatistical 3D approach that allows full uncertainty propagation. The approach used involves 1) modelling the trend with full 3D spatial correlation, i.e., exploiting the values of the neighbouring pixels in 3D-space, and 2) 3D kriging as spatial component. The uncertainty of the approach is assessed with iterations in both steps of the process. We studied the difference between local estimates obtained with the present method and local estimates obtained assuming the global average value across the test area for Carbon content and bulk density. To this end, virtual pits with a surface area of 30x30 m were excavated for the whole peat depth at randomly selected locations. Calculated uncertainty was used to estimate credible intervals of C loss. In this case the estimates obtained with the proposed approach are higher that what would be obtained by assuming spatial homogeneity and using just average values across the area. This has implications for environmental decision making and planning as, in this case, it is likely that more carbon would be lost than estimated using traditional approaches.

  16. Hydrological modeling in swelling/shrinking peat soils

    NASA Astrophysics Data System (ADS)

    Camporese, M.; Ferraris, S.; Putti, M.; Salandin, P.; Teatini, P.

    2006-06-01

    Peatlands respond to natural hydrologic cycles of precipitation and evapotranspiration with reversible deformations due to variations of water content in both the unsaturated and saturated zone. This phenomenon results in short-term vertical displacements of the soil surface that superimpose to the irreversible long-term subsidence naturally occurring in drained cropped peatlands because of bio-oxidation of the organic matter. These processes cause changes in the peat structure, in particular, soil density and void ratio. The consequential changes in the hydrological parameters need to be incorporated in water flow dynamical models. In this paper, we present a new constitutive relationship for the soil shrinkage characteristic (SSC) in peats by describing the variation of porosity with moisture content. This model, based on simple physical considerations, is valid for both anisotropic and isotropic three-dimensional peat deformations. The capability of the proposed SSC to accurately describe the deformation dynamics has been assessed by comparison against a set of laboratory experimental results recently published. The constitutive relationship has been implemented into a Richards' equation-based numerical code and applied for the simulation of the peat soil dynamics as observed in a peatland south of the Venice Lagoon, Italy, in an ad hoc field experiment where the relevant parameters are continuously measured. The modeling results match well a large set of field data encompassing a period of more than 50 days and demonstrate that the proposed approach allows for a reliable reproduction of the soil vertical displacement dynamics as well as the hydrological behavior in terms of, for example, water flow, moisture content, and suction.

  17. Carbon and Water Cycles in a New Zealand Peat Bog

    NASA Astrophysics Data System (ADS)

    Campbell, D.; Smith, J.

    2001-12-01

    Peat soils represent globally significant stores of carbon and an understanding of carbon exchange processes between peat wetland ecosystems and the atmosphere is important for understanding the effects of, and impacts upon, global climate change. Eddy covariance measurements of CO2, water vapour and energy fluxes were made during 1999 and 2000 at a remnant oligotrophic raised peat bog in North Island, New Zealand. The bog's hydrology has been modified by drainage of surrounding agricultural land, so that the water table is relatively deep compared to that of unmodified bogs in the region. Vegetation is dominated by two indigenous species of rush-like vascular plants belonging to the Southern hemisphere family Restionaceae. Maximum daytime CO2 fluxes were commonly -9 {μ }mol m-2 s-1 and averaged -1.3 {μ }mol m-2 s-1 over the 24-hour period in summertime. The ecosystem was a sink of atmospheric carbon for most of the year, with wintertime characterised by 12--15 weeks of carbon neutrality or slight carbon loss. Average carbon uptake by the ecosystem was 196 gC m-2 yr-1 for the two-year period. Modelling suggests that the key factor determining inter-annual variability of the carbon budget is seasonal soil temperature, whereas ecosystem respiration is relatively insensitive to the position of the lowered water table. The bog vegetation acts as a major control over water vapour loss and energy partitioning favors sensible heat production with mean summertime Bowen ratios of approximately 2.0. Water use efficiency was highest in the morning, indicating that the vegetation maximizes CO2 assimilation while the saturation vapour pressure deficit and transpiration rates are low. The dense canopy structure also restricts penetration of solar radiation to the peat surface, which minimizes evaporation and soil respiration.

  18. Old carbon efflux from tropical peat swamp drainage waters

    NASA Astrophysics Data System (ADS)

    Vihermaa, Leena; Waldron, Susan; Evers, Stephanie; Garnett, Mark; Newton, Jason

    2014-05-01

    Tropical peatlands constitute ~12% of the global peatland carbon pool, and of this 10% is in Malaysia1. Due to rising demand for food and biofuels, large areas of peat swamp forest ecosystems have been converted to plantation in Southeast Asia and are being subjected to degradation, drainage and fire, changing their carbon fluxes eg.2,3. Dissolved organic carbon (DOC) lost from disturbed tropical peat can be derived from deep within the peat column and be aged from centuries to millennia4 contributing to aquatic release and cycling of old carbon. Here we present the results of a field campaign to the Raja Musa Peat Swamp Forest Reserve in N. Selangor Malaysia, which has been selectively logged for 80 years before being granted timber reserve status. We measured CO2 and CH4efflux rates from drainage systems with different treatment history, and radiocarbon dated the evasion CO2 and associated [DOC]. We also collected water chemistry and stable isotope data from the sites. During our sampling in the dry season CO2 efflux rates ranged from 0.8 - 13.6 μmol m-2 s-1. Sediments in the channel bottom contained CH4 that appeared to be primarily lost by ebullition, leading to sporadic CH4 efflux. However, dissolved CH4 was also observed in water samples collected from these systems. The CO2 efflux was aged up to 582±37 years BP (0 BP = AD 1950) with the associated DOC aged 495±35 years BP. Both DOC and evasion CO2 were most 14C-enriched (i.e. younger) at the least disturbed site, and implied a substantial component of recently fixed carbon. In contrast, CO2 and DOC from the other sites had older 14C ages, indicating disturbance as the trigger for the loss of old carbon. 1Page et al., 2010 2Hooijer et al., 2010 3Kimberly et al., 2012 4Moore et al., 2013

  19. Vertical variation of δ13C of sphagnum in the four peat cores collected from both the hemispheres

    NASA Astrophysics Data System (ADS)

    Ooki, S.; Akagi, T.; Franzen, L.; McCulloch, R.; Skrzypek, G. D.

    2009-12-01

    The carbon isotope profiles of the organic burials in several peat lands have been reported and have been discussed in terms of some local climatic and/or environmental conditions such as moistness, local CO2 supply from fossil carbon combustion, etc. In order to discuss the influence of some global environmental factors on the carbon isotope composition of sphagnum, we have sampled four peat cores from the world: two high latitudinal location in the Northern hemisphere (Fallahogy, Northern Ireland and Suche Bagno, Poland), one medium latitudinal site in the Northern hemisphere (Oze, Japan), and one high latitudinal site in the Southern hemisphere (Harbarton, Argentina). Here we report the vertical profiles of δ13C of sphagnum in the four peat cores. The peat core samples were divided to 2-5cm and dried. After drying we separated only sphagnum tissues with tweezers. The waxes and oils in the collected sphagnum material were removed with a mixture solvent of benzene and ethanol by soxhlet extraction and then lignin and cellulose components were isolated from the treated samples and the recovered components were weighed. The δ13C of the three components (the treated sample, lignin and cellulose components) were measured with EA-IRMS. The 14C ages were also measured using some of the treated samples. The δ13C variations of the cores showed a similar general tend to become greater with time and it is very interesting that the range of the δ13C changes were equally 2.5-3‰. Although the possibility of the diagensis of organic materials cannot be ruled out as the cause of the changes at the moment, a global factor, such as gradual increase in atmospheric carbon dioxide concentration during the last ten millennia years, may be one of the candidates for the cause. Besides some simultaneous changes, some minor local changes are also noticeable. It has been reported that the δ13C of sphagnum varies with several factors: species, tissue, lignin/cellulose ratio, water

  20. Investigating Environmental Influences on the Morphology and Stable Isotope Changes in a Holocene Peat Deposit from Congaree National Park

    NASA Astrophysics Data System (ADS)

    Wesselschmidt, N.; Werts, S. P.

    2011-12-01

    Congaree National Park, near Columbia, South Carolina, is a floodplain forest that contains the United States' largest contiguous track of old-growth bottomland forest as well as one of the highest natural canopies that remains on Earth. A portion of the park contains a groundwater fed muckswamp and is in the footprint of several ancient meanders of the Congaree River. Within one ancient meander lies an extensive peat deposit assembled over thousands of years from the formation of an oxbow lake. The aim of this study is to investigate the environmental influences affecting the development of this peat deposit and implications on paleoclimate investigation of the southeastern US since the last ice age. From this deposit, a 3.5 meter long core was extracted with a basal date of 21,000 years before present (kyr). We have sampled this core for δ13C and δ15N values in both the bulk peat and in monocot macrofossils which were present through most sections of the entire core. The bulk peat was sampled at key changes in morphology and the monocot samples were taken at 8 cm intervals. This data reveals a sawtooth pattern of variation of about 1% throughout the lower two meters (-28.5 to -29.5%) before a much more negative excursion down to -30% in the last half a meter. We have also obtained several radiocarbon dates indicating that the initial oxbow lake filled within approximately 1000 years followed by a depositional hiatus or erosional surface occurring between 10,000 and 20,000 kyr. This was followed by a period of slow peat accumulation through 3500 kyr. In more recent years (<160 yrs), an inorganic lens has developed within the upper 10 cm of the core. Further investigation into this section of the core suggest the possibility of vertical leaching and subsequent removal of organic material from this section. Results from this study have implications in further investigations into carbon cycling and storage within Congaree National Park.

  1. The fate of lead at abandoned and active shooting ranges in a boreal pine forest.

    PubMed

    Selonen, Salla; Liiri, Mira; Strömmer, Rauni; Setälä, Heikki

    2012-12-01

    Changes in leaching, availability, bioaccumulation, and vertical distribution of lead (Pb) in soil 20 years after the cessation of shooting activity were studied by comparing three pine forest sites in southern Finland: an active shooting range, an abandoned shooting range, and a noncontaminated control site. At both shooting ranges, shooting activity had lasted for 20 years, but it had taken place 20 years earlier at the abandoned range. Up to 4 kg m(-2) of Pb pellets had accumulated in the soil at both shooting ranges, and extremely high Pb concentrations, reaching 50,000 mg kg(-1) , were detected in the organic soil layer. Elevated Pb concentrations were also found in leachate waters and in the biota. Concentrations of Pb in the top organic soil layer and in some of the biota were lower at the abandoned shooting range, which can be taken as a sign of starting recovery of the forest ecosystem. However, the concentration of water-extractable Pb had not decreased in the topsoil, possibly indicating the release of Pb from decaying litter. Deeper in the organic soil layer, weathering of Pb pellets enhanced Pb availability and leaching, indicating an increased risk of groundwater contamination over time at shooting sites located above aquifers.

  2. State of New York peat-resource inventory. Volume II

    SciTech Connect

    Not Available

    1982-07-01

    A comprehensive peat resource inventory of New York State has been prepared based on airphoto interpretation supported by field reconnaissance and detailed surveys of certain selected peatlands. The entire state, with the exception of the Adirondack Park and a number of other protected areas, was included in the study. A total of 872 peatlands were identified, of which 235 individual deposits were judged usable for peat mining, based on criteria presented within the text, and then mapped using airphotos. The study shows that the state has over 145,910 acres of peatland containing an estimated 336 million tons of peat (at 50% moisture content) located in deposits which may be technically mineable. However, various other factors, such as ownership, location in park or wildlife management holdings, and existing uses, may exclude some of the otherwise potential deposits from possible use. Section 1 of Volume 2 contains all the bore hole logs compiled in the field during the detailed and reconnaissance surveys. This data was not included in the main report due to bulkiness and the fact that the data can be regarded as semi-raw field information which has been used as a partial basis for the resource calculations, included in Volume 1. The details on the information codes contained in the bore hole logs are explained in Section 3, Volume 1, pages 3-6.

  3. Peat resource estimation in Minnesota. Third quarter report, FY1985

    SciTech Connect

    Not Available

    1985-01-01

    The Minnesota Department of Natural Resources has been surveying organic soil deposits to determine the location of fuel-grade peat since October 1, 1979, when the US Department of Energy and the Gas Research Institute awarded Minnesota a grant for peat resource estimation. The survey determines the type, quantity, and energy potential of peatlands by field mapping and laboratory characterization. The focus of the project is an eight-county study area (Aitkin, Beltrami, Carlton, Cass, Itasca, Koochiching, Lake of the Woods, and St. Louis counties) that contain over half of Minnesota's six or seven million acres of peatland. Approximately one million acres of the state's total peatland acreage are currently available for state lease. The Koochiching County survey (1,147,560 acres of peatland), the Aitkin County survey (420,560 acres of peatland), and the survey of an area of Beltrami and Lake of the Woods counties (775,400 acres of peatland) have been completed, and the reports have been published. A reconnaissance-level peatland survey of southwest St. Louis County was completed, and a report was published with state funding. Our staff is continuing the redrafting of the Carlton County Peat Resource Map to correct registration errors. We expect the redrafted version of map to be completed in the fourth quarter. The computerized version of the map will be started when the redrafting is complete.

  4. Contribution of peat fires to the 2015 Indonesian fires

    NASA Astrophysics Data System (ADS)

    Kaiser, Johannes W.; Heil, Angelika; Wooster, Martin J.; van der Werf, Guido R.

    2016-04-01

    Indonesia experienced widespread fires and severe air quality degradation due to smoke during September and October 2015. The fires are thought to have originated from the combination of El-Niño-induced drought and human activities. Fires ignited for land clearing escaped into drained peatlands and burned until the onset of the monsoonal rain. In addition to the health impact, these fires are thought to have emitted large amounts of greenhouse gases, e.g. more than Japan over the entire year. The Copernicus Atmosphere Monitoring Service (CAMS) has detected and quantified the fires with the Global Fire Assimilation System (GFAS) and the smoke dispersion with the Chemistry-Integrated Forecasting System (C-IFS) in near real time. GFAS and C-IFS are constrained by satellite-based observations of fire and smoke constituents, respectively. The distinction between peat and above-ground fires is a crucial and difficult step in fire emission estimation as it introduces errors of up to one order of magnitude. Here, we quantify the contribution of peat fires to the total emission flux of the 2015 Indonesian fires by (1) using an improved peat map in GFAS and (2) analysing the observed diurnal cycle of the fire activity as represented in a new development for GFAS. Furthermore, we link the fires occurrence to economic activity by analysing the coincidence with concessions for palm oil plantations and other industrial forest uses.

  5. Biofiltration of isopentane in peat and compost packed beds

    SciTech Connect

    Wang, Z.; Govind, R.

    1997-05-01

    Commercially available biofiltration systems have used natural bioactive materials in packed beds due to low media cost and easy availability. Detailed understanding and modeling of biofiltration systems are lacking in existing literature. Experimental studies on the isopentane treatment in air using peat- and compost-packed beds were conducted with inlet isopentane concentrations of 360 to 960 ppmv, and empty-bed gas-phase residence times of 2 to 10 min. High removal efficiencies (>90%) were achieved at low contaminant concentrations (<500 ppmv) and large empty-bed gas-phase residence times (>8 min). For both peat and compost biofilters, there was an optimal water content that gave the highest removal efficiency. For higher water content, mass transfer of isopentane through the liquid phase controlled the biofiltration removal efficiency. At low water content, irreversible changes in the bioactivity of peat and compost occurred, resulting in an irrecoverable loss of removal efficiency. Increases in biofilter bed temperature from 25 to 40 C improved the removal efficiency. A mathematical model incorporating the effect of water content and temperature was developed to describe the packed-bed biofilter performance. Model predictions agreed closely with experimental data.

  6. Is it clean or contaminated soil? Using petrogenic versus biogenic GC-FID chromatogram patterns to mathematically resolve false petroleum hydrocarbon detections in clean organic soils: a crude oil-spiked peat microcosm experiment.

    PubMed

    Kelly-Hooper, Francine; Farwell, Andrea J; Pike, Glenna; Kennedy, Jocelyn; Wang, Zhendi; Grunsky, Eric C; Dixon, D George

    2013-10-01

    The Canadian Council of Ministers of the Environment (CCME) reference method for the Canada-wide standard (CWS) for petroleum hydrocarbon (PHC) in soil provides chemistry analysis standards and guidelines for the management of contaminated sites. However, these methods can coextract natural biogenic organic compounds (BOCs) from organic soils, causing false exceedences of toxicity guidelines. The present 300-d microcosm experiment used CWS PHC tier 1 soil extraction and gas chromatography-flame ionization detector (GC-FID) analysis to develop a new tier 2 mathematical approach to resolving this problem. Carbon fractions F2 (C10-C16), F3 (C16-C34), and F4 (>C34) as well as subfractions F3a (C16-C22) and F3b (C22-C34) were studied in peat and sand spiked once with Federated crude oil. These carbon ranges were also studied in 14 light to heavy crude oils. The F3 range in the clean peat was dominated by F3b, whereas the crude oils had approximately equal F3a and F3b distributions. The F2 was nondetectable in the clean peat but was a significant component in crude oil. The crude oil–spiked peat had elevated F2 and F3a distributions. The BOC-adjusted PHC F3 calculation estimated the true PHC concentrations in the spiked peat. The F2:F3b ratio of less than 0.10 indicated PHC absence in the clean peat, and the ratio of greater than or equal to 0.10 indicated PHC presence in the spiked peat and sand. Validation studies are required to confirm whether this new tier 2 approach is applicable to real-case scenarios. Potential adoption of this approach could minimize unnecessary ecological disruptions of thousands of peatlands throughout Canada while also saving millions of dollars in management costs.

  7. Isolation and identification of methanogen-specific DNA from blanket bog peat by PCR amplification and sequence analysis.

    PubMed

    Hales, B A; Edwards, C; Ritchie, D A; Hall, G; Pickup, R W; Saunders, J R

    1996-02-01

    The presence of methanogenic bacteria was assessed in peat and soil cores taken from upland moors. The sampling area was largely covered by blanket bog peat together with small areas of red-brown limestone and peaty gley. A 30-cm-deep core of each soil type was taken, and DNA was extracted from 5-cm transverse sections. Purified DNA was subjected to PCR amplification with primers IAf and 1100Ar, which specifically amplify 1.1 kb of the archaeal 16S rRNA gene, and ME1 and ME2, which were designed to amplify a 0.75-kb region of the alpha-subunit gene for methyl coenzyme M reductase (MCR). Amplification with both primer pairs was obtained only with DNA extracted from the two deepest sections of the blanket bog peat core. This is consistent with the notion that anaerobiosis is required for activity and survival of the methanogen population. PCR products from both amplifications were cloned, and the resulting transformants were screened with specific oligonucleotide probes internal to the MCR or archaeal 16S rRNA PCR product. Plasmid DNA was extracted from probe-positive clones of both types and the insert was sequenced. The DNA sequences of 8 MCR clones were identical, as were those of 16 of the 17 16S rRNA clones. One clone showed marked variation from the remainder in specific regions of the sequence. From a comparison of these two different 16S rRNA sequences, an oligonucleotide was synthesized that was 100% homologous to a sequence region of the first 16 clones but had six mismatches with the variant. This probe was used to screen primary populations of PCR clones, and all of those that were probe negative were checked for the presence of inserts, which were then sequenced. By using this strategy, further novel methanogen 16S rRNA variants were identified and analyzed. The sequences recovered from the peat formed two clusters on the end of long branches within the methanogen radiation that are distinct from each other. These cannot be placed directly with sequences

  8. Characterization of peat structure using X-ray computed tomography and its control on the ebullition of biogenic gas bubbles

    NASA Astrophysics Data System (ADS)

    Kettridge, Nicholas; Binley, Andrew

    2011-03-01

    The structural arrangement of peat constituents controls the hydrological and thermal properties of peat. However, the importance of these structural characteristics on other physical processes within a peatland has not been fully assessed. Here, we evaluate the importance of peat structure on its ability to entrain biogenic gas bubbles and control ebullition, an important transport mechanism for methane. X-ray computed tomography (CT) was applied to characterize the structure of a range of peats at varying levels of decomposition. The structural properties of the peat were quantified from a vector representation of the CT images, and the potential of each sample to entrain biogenic gas bubbles was quantified using a rule-based Monte Carlo model that calculates the tortuosity of bubbles pathways through the peat. Sixty-six percent of the variability in the trapping potential of the peat results from porosity variations and 34% from structural variations between samples. A metric that represents this structural control was not identified for all peat types because of difficulties adequately representing some peats as a vector network. However, for S. magellanicum peat we were able to establish that the influence of peat structure on the entrainment of gas bubbles is characterized by ?v, the average vector length of the stems and branches. Peat characterized by longer structural components (larger ?v) enhances the entrainment of gas bubbles. Our findings demonstrate the need to incorporate some representation of the peat structure in numerical models of biogenic gas transport in peat.

  9. Peat: a natural repository for low-level radioactive waste

    SciTech Connect

    Thomas, E.D.

    1985-12-01

    A study has been initiated to evaluate the possibility of using peat as a natural repository for the disposal of low-level radioactive waste. One aspect of this study was to determine the retentive properties of the peat through measurements of the distribution coefficients (K/sub d/) for Am-241, Ru-106, Cs-137, Co-57, and Sr-85 in two layers of mountain top peat bogs from Lefgren's, NY, and Spruce Flats, PA. These K/sub d/ values were then compared to literature values of various sediment/water systems at similar environmental conditions. Am-241, Ru-106, Co-57, and Sr-85 attained distribution coefficients in the organic rich layers of the bogs two orders of magnitude greater than those obtained previously at pH 4.0. Although, the Cs-137 sorbed strongly to the inorganic rich layer of the Spruce Flats, PA, bog, the K/sub d/ values obtained for this isotope were, again, comparable or higher than those reported previously at pH 4.0, indicating the greater retentive properties of the peat. A chromatographic ''theoretical plate'' model was used to describe the field migration of Cs-137. The advection and diffusion coefficients were higher in the Lefgren's Bog, NY, than those obtained for the Spruce Flats Bog, PA. These field data were substantiated by the lower Cs-137 K/sub d/ values determined in the laboratory for the Lefgren's Bog, NY, compared to the Spruce Flats Bog. Although this model gave a good indication of the field migration, it neglected the process of sorption as defined by the sorption isotherm. Based on the time series data on distribution ratio measurements, a Cameron-Klute type of sorption isotherm was indicated, with rapid equilibrium initially superimposed onto a slower first order linear reversible equilibrium. This sorption isotherm can then be used in the final form of a model to describe the migration of radionuclides in a peat bog. 19 refs., 15 figs., 10 tabs.

  10. Carbohydrates and phenols as quantitative molecular vegetation proxies in peats

    NASA Astrophysics Data System (ADS)

    Kaiser, K.; Benner, R. H.

    2012-12-01

    Vegetation in peatlands is intricately linked to local environmental conditions and climate. Here we use chemical analyses of carbohydrates and phenols to reconstruct paleovegetation in peat cores collected from 56.8°N (SIB04), 58.4°N (SIB06), 63.8°N (G137) and 66.5°N (E113) in the Western Siberian Lowland. Lignin phenols (vanillyl and syringyl phenols) were sensitive biomarkers for vascular plant contributions and provided additional information on the relative contributions of angiosperm and gymnosperm plants. Specific neutral sugar compositions allowed identification of sphagnum mosses, sedges (Cyperaceae) and lichens. Hydroxyphenols released by CuO oxidation were useful tracers of sphagnum moss contributions. The three independent molecular proxies were calibrated with a diverse group of peat-forming plants to yield quantitative estimates (%C) of vascular plant, sphagnum moss and lichen contributions in peat core samples. Correlation analysis indicated the three molecular proxies produced fairly similar results for paleovegetation compositions, generally within the error interval of each approach (≤26%). The lignin-based method generally lead to higher estimates of vascular plant vegetation. Several significant deviations were also observed due to different reactivities of carbohydrate and phenolic polymers during peat decomposition. Rapid vegetation changes on timescales of 50-200 years were observed in the southern cores SIB04 and SIB06 over the last 2000 years. Vanillyl and syringyl phenol ratios indicated these vegetation changes were largely due to varying inputs of angiosperm and gymnosperm plants. The northern permafrost cores G137 and E113 showed a more stable development. Lichens briefly replaced sphagnum mosses and vascular plants in both of these cores. Shifts in vegetation did not correlate well with Northern hemisphere climate variability over the last 2000 years. This suggested that direct climate forcing of peatland dynamics was overridden

  11. Peat resource estimation in South Carolina. First quarterly report (year 2)

    SciTech Connect

    Cohen, Dr., A. D.; Tisdale, M.; Holmes, M.; Corvinus, D.; Andrejko, M.; Olson, N. K.; Vigerstad, Dr., T. J.

    1981-01-01

    The objectives of this program are to assess the magnitude of the resources and areas of highest potential for peat deposits in South Carolina and evaluate the energy potential of these peat resources. This report presents the results of progress made in: data analysis of areas to be surveyed; sampling procedures and strategy; procurement of equipment and supplies; and preliminary peat resource assessment stuies. (DMC)

  12. Substrate quality and nutrient availability influence CO2 production from tropical peat decomposition

    NASA Astrophysics Data System (ADS)

    Swails, E.; Jaye, D.; Verchot, L. V.; Hergoualc'h, K.; Wahyuni, N. S.; Borchard, N.; Lawrence, D.

    2015-12-01

    In Indonesia, peatlands are a major and growing source of greenhouse gas emissions due to increasing pressure from oil palm and pulp wood plantations. We are using a combination of field measures, laboratory experiments, and remote sensing to investigate relationships among land use, climatic factors and biogeochemical controls, and their influence on trace gas fluxes from tropical peat soils. Analysis of soils collected from peat sites on two major islands indicated substantial variation in peat substrate quality and nutrient content among land uses and geographic location. We conducted laboratory incubations to test the influence of substrate quality and nutrient availability on CO2 production from peat decomposition. Differences in peat characteristics attributable to land use change were tested by comparison of forest and oil palm peat samples collected from the same peat dome in Kalimantan. Regional differences in peat characteristics were tested by comparison of samples from Sumatra with samples from Kalimantan. We conducted additional experiments to test the influence of N and P availability and labile carbon on CO2 production. Under moisture conditions typical of oil palm plantations, CO2 production was higher from peat forest samples than from oil palm samples. CO2 production from Sumatra and Kalimantan oil palm samples was not different, despite apparent differences in nutrient content of these soils. N and P treatments representative of fertilizer application rates raised CO2 production from forest samples but not oil palm samples. Labile carbon treatments raised CO2 production in all samples. Our results suggest that decomposition of peat forest soils is nutrient limited, while substrate quality controls decomposition of oil palm soils post-conversion. Though fertilizer application could accelerate peat decomposition initially, fertilizer application may not influence long-term CO2 emissions from oil palm on peat.

  13. Peat soil composition as indicator of plants growth environment

    NASA Astrophysics Data System (ADS)

    Noormets, M.; Tonutare, T.; Kauer, K.; Szajdak, L.; Kolli, R.

    2009-04-01

    Exhausted milled peat areas have been left behind as a result of decades-lasting intensive peat production in Estonia and Europe. According to different data there in Estonia is 10 000 - 15 000 ha of exhausted milled peat areas that should be vegetated. Restoration using Sphagnum species is most advantageous, as it creates ecological conditions closest to the natural succession towards a natural bog area. It is also thought that the large scale translocation of vegetation from intact bogs, as used in some Canadian restoration trials, is not applicable in most of European sites due to limited availability of suitable donor areas. Another possibility to reduce the CO2 emission in these areas is their use for cultivation of species that requires minimum agrotechnical measures exploitation. It is found by experiments that it is possible to establish on Vaccinium species for revegetation of exhausted milled peat areas. Several physiological activity of the plant is regulated by the number of phytohormones. These substances in low quantities move within the plant from a site of production to a site of action. Phytohormone, indole-3-acetic acid (IAA) is formed in soils from tryptophane by enzymatic conversion. This compound seems to play an important function in nature as result to its influence in regulation of plant growth and development. A principal feature of IAA is its ability to affect growth, development and health of plants. This compound activates root morphology and metabolic changes in the host plant. The physiological impact of this substance is involved in cell elongation, apical dominance, root initiation, parthenocarpy, abscission, callus formation and the respiration. The investigation areas are located in the county of Tartu (58˚ 22' N, 26˚ 43' E), in the southern part of Estonia. The soil of the experimental fields belongs according to the WRB soil classification, to the soils subgroups of Fibri-Dystric Histosols. The investigation areas were

  14. Thermal properties of degraded lowland peat-moorsh soils

    NASA Astrophysics Data System (ADS)

    Gnatowski, Tomasz

    2016-04-01

    Soil thermal properties, i.e.: specific heat capacity (c), thermal conductivity (K), volumetric heat capacity (C) govern the thermal environment and heat transport through the soil. Hence the precise knowledge and accurate predictions of these properties for peaty soils with high amount of organic matter are especially important for the proper forecasting of soil temperature and thus it may lead to a better assessment of the greenhouse gas emissions created by microbiological activity of the peatlands. The objective of the study was to develop the predictive models of the selected thermal parameters of peat-moorsh soils in terms of their potential applicability for forecasting changes of soil temperature in degraded ecosystems of the Middle Biebrza River Valley area. Evaluation of the soil thermal properties was conducted for the parameters: specific heat capacity (c), volumetric heat capacities of the dry and saturated soil (Cdry, Csat) and thermal conductivities of the dry and saturated soil (Kdry, Ksat). The thermal parameters were measured using the dual-needle probe (KD2-Pro) on soil samples collected from seven peaty soils, representing total 24 horizons. The surface layers were characterized by different degrees of advancement of soil degradation dependent on intensiveness of the cultivation practises (peaty and humic moorsh). The underlying soil layers contain peat deposits of different botanical composition (peat-moss, sedge-reed, reed and alder) and varying degrees of decomposition of the organic matter, from H1 to H7 (von Post scale). Based on the research results it has been shown that the specific heat capacity of the soils differs depending on the type of soil (type of moorsh and type of peat). The range of changes varied from 1276 J.kg-1.K-1 in the humic moorsh soil to 1944 J.kg-1.K-1 in the low decomposed sedge-moss peat. It has also been stated that in degraded peat soils with the increasing of the ash content in the soil the value of specific heat

  15. View of abandoned Yosemite Valley Railroad track grade and trestle ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    View of abandoned Yosemite Valley Railroad track grade and trestle remain. Seen from same camera location as HAER CA-150-39. Looking northwest - All Year Highway, Between Arch Rock & Yosemite Valley, El Portal, Mariposa County, CA

  16. 6. ANGLE VIEW OF ABANDONED INCINERATOR, INTERIOR OF BUILDING, 499 ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    6. ANGLE VIEW OF ABANDONED INCINERATOR, INTERIOR OF BUILDING, 499 FACING NORTHWEST. - U.S. Naval Base, Pearl Harbor, Fleet Accounting & Dispersing Center, 178 Main Street, Pearl City, Honolulu County, HI

  17. 77 FR 5740 - Tennessee Abandoned Mine Land Program

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-02-06

    ... 1992: This bill revised the AML program in areas of coal remining, and abandoned coal refuse sites, as... Disposal; Reclamation on Private Land; Rights of Entry; Public Participation Policies; Organization... include landslide hazards, highwalls, flooding, erosion, sedimentation, acid drainage, coal...

  18. Community Involvement Plan: Western Abandoned Uranium Mine Region

    EPA Pesticide Factsheets

    Factsheets related to the Western Abandoned Uranium Mine Region, generally located along the Little Colorado River and Highway 89, and are in the Cameron, Coalmine Canyon, Bodaway/Gap, and Leupp Chapters.

  19. Working with Communities on Cleaning Up Abandoned Uranium Mines

    EPA Pesticide Factsheets

    This site provides information about the EPA's work to inform and include communities in the cleanup of abandoned mines, including health impacts, major enforcement and removal milestones, and community actions.

  20. BOILING HOUSE, GROUND FLOOR, ABANDONED SUGAR BIN IN CENTER. IN ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    BOILING HOUSE, GROUND FLOOR, ABANDONED SUGAR BIN IN CENTER. IN BACKGROUND, THE ELEVATOR AND STAIRS GOING UP. VIEW FROM SOUTHWEST - Lihue Plantation Company, Sugar Mill Building, Haleko Road, Lihue, Kauai County, HI

  1. 67. View of old, abandoned vehicular bridge near entrance to ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    67. View of old, abandoned vehicular bridge near entrance to Lake Trapps. Photo by Brian C. Morris, Puget Power, 1989. - Puget Sound Power & Light Company, White River Hydroelectric Project, 600 North River Avenue, Dieringer, Pierce County, WA

  2. 11. Remains of Douglasfir cordwood abandoned when kilns ceased operation, ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    11. Remains of Douglas-fir cordwood abandoned when kilns ceased operation, looking northeast. - Warren King Charcoal Kilns, 5 miles west of Idaho Highway 28, Targhee National Forest, Leadore, Lemhi County, ID

  3. 5. GENERAL VIEW OF NORTH WINGWALL LOOKING SOUTHWEST TOWARD ABANDONED ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    5. GENERAL VIEW OF NORTH WINGWALL LOOKING SOUTHWEST TOWARD ABANDONED WATERPUMP FACILITY FOR A SUGAR PROCESSING PLANT SOUTH OF THE BRIDGE. - Winnebago River Bridge, Spanning Winnebago River at U.S. Highway 65, Mason City, Cerro Gordo County, IA

  4. Substitution of peat for municipal solid waste- and sewage sludge-based composts in nursery growing media: effects on growth and nutrition of the native shrub Pistacia lentiscus L.

    PubMed

    Ostos, J C; López-Garrido, R; Murillo, J M; López, R

    2008-04-01

    In this study, the effect of a partial substitution of peat for compost on the growth and nutrition of a native shrub (Pistacia lentiscus L.) was tested. Composts were prepared from pruning and municipal solid wastes or pruning waste and sewage sludge. For preparing growing media each compost was added at a rate of 40%, fresh pine bark at 20% or 40% and peat at 20%, 40% or 60%. Aqueous extracts from the substrates did not impair germination of cress (germination bioassay). In relation to plants growing in peat-based substrate (used as a control), plants of the compost-based substrates reached better growth and nutrition, especially when using the sewage sludge-based compost, and the P uptake was notably enhanced. The concentrations of trace elements were far lower than the ranges considered phytotoxic for vascular plants. Detrimental effect derived from using fresh pine bark was not observed.

  5. Inventory of peat resources: an area of Beltrami and Lake of the Woods counties, Minnesota

    SciTech Connect

    Not Available

    1984-01-01

    This report presents the findings of the Minnesota Peat Inventory Project's (MPIP) reconnaissance-level survey of an area of Beltrami and Lake of the Woods counties. Peatlands cover about 314,000 hectares (775,000 acres) of this area and constitute about 12 percent of the state's total peat resource. The survey identifies the location and amount of fuel-grade and horticultural peat in the two county area. The report provides a general discussion of peatlands and describes the field and laboratory procedures of this peatland survey and presents a map of the peat resources in the surveyed area. 28 references, 12 figures, 12 tables.

  6. Peat deposits in Panama: Their potential for use in energy applications

    SciTech Connect

    Ramirez, A.; Thayer, G.; Cohen, A.D.; Allen, A.

    1986-12-01

    A major peak bog has been discovered in the Changuinola area of Panama. The bog averages 8-m deep, is thought to be 82 km/sup 2/, in area and the peat has an ash content of about 4%. It is estimated that this size peat bog could support a 30-MW power plant for 360 years. Preliminary cost estimates for using the peat in an electrical power plant give an estimated cost of electricity of 0.09$US/kWh if wet mining is used and 0.079$US/kWh if milled peat is used. 2 refs., 4 figs.

  7. Prenatal effects of peat combustion products and afobazole correction thereof in the rat progeny.

    PubMed

    Gorbatova, D M; Nemova, E P; Solomina, A S; Durnev, A D; Seredenin, S B

    2015-03-01

    Female outbred albino rats were daily subjected to forced inhalations of peat smoke (4 cores packed with a mixture of peat (70%) and wood pulp (30%); 0.46 g, pH ≥ 5.5) per se and in combination with oral afobazole (anxiolytic) on days 1-20 of pregnancy. Exposure to peat smoke inhibited body weight gain in pregnant rats, caused an increase of postimplantation deaths, reduction of fetal weights, and an increase in the number of hematomas and hemorrhages in fetuses. Afobazole in doses of 1 and 10 mg/kg reduced significantly the untoward effects of peat smoke on fetal development.

  8. Feedstock characteristics and preparation for peat gasification. Annual report, January-December 1980

    SciTech Connect

    Punwani, D.V.; Aspinall, F.; Loftons, S.M.

    1981-08-01

    The report describes the work conducted to prepare updated peat resource maps and to conduct quantitative economic and environmental assessments of a few selected peat harvesting, dewatering, and beneficiation alternatives. In the task on peat resources, maps of seven states (Florida, Illinois, Maine, Michigan, North Carolina, Ohio, and Wisconsin) have been completed. A number of peat harvesting system designs have been ranked according to their technical merits. A preliminary economic comparison of four peat dewatering systems has been made. A description of a beneficiation (wet-carbonization) process and a preliminary economic estimate for producing beneficiated peat is presented. Recent developments in both thermal and biological conversion of peat to substitute natural gas (SNG) are described. The major air and water pollution emission rates from a peat gasification plant producing 250 billion Btu/day of SNG have been estimated. Detailed environmental scenarios have been prepared for three peat bogs typical of those in the Upper Midwest, Northeast, and Southeast United States. Preliminary cost estimates for harvested peatland reclamation options have been made.

  9. Copper and zinc adsorption onto poorly humified Sphagnum and Carex peat.

    PubMed

    Ringqvist, L; Oborn, I

    2002-05-01

    Peat generally has a high adsorption capacity and has been suggested as an adsorbent for metals in polluted waters. However, the adsorption potential of peat can be expected to be strongly dependent on the chemical properties of the water. In this study, the effect of pH, ionic strength (CaCl2 and NaCl concentrations), and metal concentration on Cu and Zn adsorption onto poorly humified Sphagnum and Carex peat was investigated in batch experiments using a fractional factorial experimental design. The pH value was varied between 4 and 8, the CaCl2 and NaCl concentrations between 1.2-6.2 and 0.4-43 mM, respectively, and the Cu and Zn concentrations between 0.05 and 0.5 mM. The amount of Zn adsorbed increased more with increasing pH than the amount of Cu adsorbed. The effect of NaCl/CaCl2 concentration was minor. It was found that Zn adsorption in particular, but also Cu adsorption, increased more with pH onto Carex peat than onto Sphagnum peat. In the pH interval 4-8, the removal of Zn from the solution increased from 0% to 80% using Carex peat and from 10% to 65% using Sphagnum peat as the adsorbent. The Carex peat sample decreased the Cu concentration by 80% at pH 4 and by 95% at pH 8 and for Sphagnum peat a decrease of 85% was maintained in the pH range investigated. The differences between Sphagnum and Carex peat were attributed to the habitat conditions at the time of peat formation. Carex peat has higher ash, nitrogen and sulphur concentrations, while Sphagnum peat contains a higher amount of uronic acid. In treating polluted waters with peat, a higher degree of metal removal can be expected at high pH values than at low. The removal of Cu, which has a high affinity to the peat surface, was less dependent on pH than Zn removal. Poorly humified Carex peat should be chosen in treating wastewaters high in pH.

  10. Experimental Investigation of the Deepening of the Combustion Front into Peat Layers Different in Botanical Composition

    NASA Astrophysics Data System (ADS)

    Kasymov, D. P.

    2017-01-01

    The deepening of the center of combustion into peat layers of different botanical compositions (pine-cotton grass and grass-sphagnum peats), typical for the Tomsk region, was investigated experimentally. Peats were ignited from a model ground forest fire initiated by firing of a needle-litter layer. As a result of laboratory investigations, the change in the temperature in the bulk of peat samples with time was determined and analyzed, and the rates of their combustion in the horizontal and vertical directions were estimated. It was established that a fire penetrates deep into a layer of grass-sphagnum peat, containing more than 70% of combustion conductors in its composition, more rapidly as compared to that of pine-cotton grass peat. The rates of combustion of grass-sphagnum peat in the vertical and horizontal directions are larger by 20 and 22%, respectively, than those of pine-cotton grass peat, which is evidently due to the botanical composition of grass-sphagnum peat and the random arrangement of components in its layers.

  11. The morphology of peat bog surfaces on Hermansenøya, NW Svalbard

    NASA Astrophysics Data System (ADS)

    Jaworski, Tomasz

    2017-03-01

    This article analyses the surface morphology of the arctic peat bogs occurring on Hermansenøya, a small island in the Forlandsundet, NW Svalbard. Six small, shallow peat bogs on the island show different microrelief features formed by ice-segregation as well as thermokarst and thermo-erosion processes. On the peat bogs the following forms have been identified: aggradational, associated with the growth of different types of ground ice (frost peat mounds, peat plateaus, polygonal peat plateaus, networks of ice-wedge polygons); and degradational, associated with thermokarst (symmetrically developed residual peat mounds and the furrows in between) and thermo-erosion (channels of niveo-fluvial streams). Some importance can also be attributed to aeolian processes, i.e. snow drifting from the tops of convex relief features for aggradational forms. Lack of insulating snow cover significantly increases frost penetration depth, promoting cryosuction and/or ice growth at the base of a frozen core. The oldest preserved forms and structures, frost peat mounds with an ice-peat core and ice-wedge polygons, developed during climatic cooling at the turn of the Subboreal and Subatlantic (c. 3.0-2.5 ka BP). Thermokarst mounds are younger, associated with warmer periods after the Little Ice Age (the warmer 1920s). Channels of niveo-fluvial streams are being shaped today.

  12. Emissions of volatile organic compounds and particulate matter from small-scale peat fires

    NASA Astrophysics Data System (ADS)

    George, I. J.; Black, R.; Walker, J. T.; Hays, M. D.; Tabor, D.; Gullett, B.

    2013-12-01

    Air pollution emitted from peat fires can negatively impact regional air quality, visibility, climate, and human health. Peat fires can smolder over long periods of time and, therefore, can release significantly greater amounts of carbon into the atmosphere per unit area compared to burning of other types of biomass. However, few studies have characterized the gas and particulate emissions from peat burning. To assess the atmospheric impact of peat fires, particulate matter (PM) and volatile organic compounds (VOCs) were quantified from controlled small-scale peat fire experiments. Major carbon emissions (i.e. CO2, CO, methane and total hydrocarbons) were measured during the peat burn experiments. Speciated PM mass was also determined from the peat burns from filter and polyurethane foam samples. Whole air samples were taken in SUMMA canisters and analyzed by gas chromatography-mass spectrometry to measure 82 trace VOCs. Additional gaseous carbonyl species were measured by sampling with dinitrophenylhydrazine-coated cartridges and analyzed with high performance liquid chromatography. VOCs with highest observed concentrations measured from the peat burns were propylene, benzene, chloromethane and toluene. Gas-phase carbonyls with highest observed concentrations included acetaldehyde, formaldehyde and acetone. Emission factors of major pollutants will be compared with recommended values for peat and other biomass burning.

  13. Soil quality assessment for peat-mineral mix cover soil used in oil sands reclamation.

    PubMed

    Ojekanmi, A A; Chang, S X

    2014-09-01

    A soil quality (SQ) assessment and rating framework that is quantitative, iterative, and adaptable, with justifiable weighting for quality scores, is required for evaluating site-specific SQ at land reclamation sites. Such a framework needs to identify the minimum dataset that reflects the current knowledge regarding relationships between SQ indicators and relevant measures of ecosystem performance. Our objective was to develop nonlinear scoring functions for assessing the impact on SQ of peat-mineral mix (PMM) used as a cover soil at land reclamation sites. Soil functional indicators affected by PMM were extracted from existing databases and correlated with soil organic carbon (SOC). Based on defined objectives for SQ assessment, indicators with significant correlation ( < 0.05) to SOC were selected, normalized, and fitted to sigmoid functions using nonlinear regression procedure to establish SQ functions (SQFs) that can analyze changes in field capacity, permanent wilting point, soil nitrogen, and cation exchange capacity of PMM using SOC as input parameter. Application of the SQFs to an independent dataset produced ratings with mean differences similar to the treatment effects of mixing three levels of peat and mineral soil. These results show that derived ratings and weighing factors using SOC reflect the relationship between PMM treatment and other SQ indicators. Applying the developed SQFs to a long-term soil monitoring dataset shows that an increase or decrease in SOC from 10 to 20 g kg causes a significant change in SQ. This identifies the need for further nutrient and moisture management of PMM to support long-term SQ development in land reclamation.

  14. Degradation of hydrogen sulfide by Xanthomonas sp. strain DY44 isolated from peat

    SciTech Connect

    Cho, Kyeoungsuk; Hirai, Mitsuyo; Shoda, Makoto )

    1992-04-01

    Xanthomonas sp. strain DY44, capable of degrading H{sub 2}S, was isolated from dimethyl disulfide-acclimated peat. This bacterium removed H{sub 2}S either as a single gas or in the presence of the sulfur-containing compounds methanethiol, dimethyl sulfide, and dimethyl disulfide. The maximum specific H{sub 2}S removal rate, obtained in the late stationary phase, was 3.92 mmol g of dry cells{sup {minus}1}h{sup {minus}1} (6.7 {times} 10{sup {minus}16} mol cell{sup {minus}1}h{sup {minus}1}) at pH 7 and 30C through a batch experiment in a basal mineral medium. Since Xanthomonas sp. Strain DY44 exhibited no autotrophic growth with H{sub 2}S, the H{sub 2}S removal was judged not to be a consequence of chemolithotrophic activity. By using x-ray photoelectron spectroscopy, the metabolic product of H{sub 2}S oxidation was determined to be polysulfide, which has properties very similar to those of elemental sulfur. Autoclaved cells (120C, 20 min) did not show H{sub 2}S degradation, but cells killed by {gamma}-irradiation and cell extracts both oxidized H{sub 2}S, suggesting the existence of a heat-labile intracellular enzymatic system for H{sub 2}S oxidation. When Xanthomonas sp. strain DY44 was inoculated into fibrous peat, this strain degraded H{sub 2}S without lag time, suggesting that it will be a good candidate for maintaining high H{sub 2}S removability in the treatment of exhaust gases.

  15. Brent spar experience haunts N. Sea platform abandonments

    SciTech Connect

    Knott, D.

    1996-06-03

    This paper reviews the environmental conflicts that oil and gas industry officials have recently encountered in their attempts to abandon offshore platforms. It reviews the various governmental policies which are in effect in the North Sea area and the effect these policies have had on removal or deepsea disposal of these facilities. It provides a prospectus of soon to be abandoned facilities in the North Sea countries and a summary of removal operations in recent history.

  16. Abandoned floodplain plant communities along a regulated dryland river

    USGS Publications Warehouse

    Reynolds, L. V.; Shafroth, Patrick B.; House, P. K.

    2014-01-01

    Rivers and their floodplains worldwide have changed dramatically over the last century because of regulation by dams, flow diversions and channel stabilization. Floodplains no longer inundated by river flows following dam-induced flood reduction comprise large areas of bottomland habitat, but the effects of abandonment on plant communities are not well understood. Using a hydraulic flow model, geomorphic mapping and field surveys, we addressed the following questions along the Bill Williams River, Arizona: (i) What per cent of the bottomland do abandoned floodplains comprise? and (ii) Are abandoned floodplains quantitatively different from adjacent xeric and riparian surfaces in terms of vegetation composition and surface sediment? We found that nearly 70% of active channel and floodplain area was abandoned following dam installation. Abandoned floodplains along the Bill Williams River tend to be similar to each other yet distinct from neighbouring habitats: they have been altered physically from their historic state, leading to distinct combinations of surface sediments, hydrology and plant communities. Abandoned floodplains may transition to xeric communities over time but are likely to retain some riparian qualities as long as there is access to relatively shallow ground water. With expected increases in water demand and drying climatic conditions in many regions, these surfaces and associated vegetation will continue to be extensive in riparian landscapes worldwide

  17. History and environmental impact of mining activity in Celtic Aeduan territory recorded in a peat bog (Morvan, France).

    PubMed

    Monna, F; Petit, C; Guillaumet, J P; Jouffroy-Bapicot, I; Blanchot, C; Dominik, J; Losno, R; Richard, H; Lévêque, J; Chateau, C

    2004-02-01

    The present study aims to document historical mining and smelting activities by means of geochemical and pollen analyses performed in a peat bog core collected around the Bibracte oppidum (Morvan, France), the largest settlement of the great Aeduan Celtic tribe (ca. 180 B.C. to 25 A.D.). The anthropogenic Pb profile indicates local mining operations starting from the Late Bronze Age, ca. cal. 1300 B.C. Lead inputs peaked at the height of Aeduan civilization and then decreased after the Roman conquest of Gaul, when the site was abandoned. Other phases of mining are recognized from the 11th century to modern times. They have all led to modifications in plant cover, probably related in part to forest clearances necessary to supply energy for mining and smelting. Zn, Sb, Cd, and Cu distributions may result from diffusional and biological processes or from the influence of groundwater and underlying mineral soil, precluding their interpretation for historical reconstruction. The abundance of mineral resources, in addition to the strategic location, might explain why early settlers founded the city of Bibracte at that particular place. About 20% of the anthropogenic lead record was accumulated before our era and about 50% before the 18th century, which constitutes a troublesome heritage. Any attempts to develop control strategies in accumulating environments should take into account past human activities in order to not overestimate the impact of contemporary pollution.

  18. Peat humic substances enriched with nutrients for agricultural applications: competition between nutrients and non-essential metals present in tropical soils.

    PubMed

    Botero, Wander Gustavo; de Oliveira, Luciana Camargo; Rocha, Julio Cesar; Rosa, Andre Henrique; Dos Santos, Ademir

    2010-05-15

    Improved agricultural productivity, and reduction of environmental impacts, require studies of the interactions between different soil components. Fertilizers marketed as "organic" or "natural", such as peats or humic substances (HS) extracted from peats, are enriched with macro and micronutrients that, according to the manufacturers, are released to the plant in accordance with its needs. This work investigates the complexation capacity of HS for macro and micronutrient metal species, considering the competition, for HS complexation sites, between non-essential metals (aluminium and lead), present in the soil, and the nutrients. Humic substances were found to possess strong affinities for Pb(II) and Al(III), forming stable complexes, with concomitant release of complexed nutrients. Although HS are already used commercially as organic fertilizers, further studies of methods of HS enrichment, aimed at avoiding losses, are highly desirable from environmental and economic perspectives.

  19. Adsorption/desorption of arsenic by tropical peat: influence of organic matter, iron and aluminium.

    PubMed

    de Oliveira, Lílian Karla; Melo, Camila Almeida; Goveia, Danielle; Lobo, Fabiana Aparecida; Armienta Hernández, Maria Aurora; Fraceto, Leonardo Fernandes; Rosa, André Henrique

    2015-01-01

    The objective of this work was to investigate the interaction of arsenic species (As(III) and As(V)) with tropical peat. Peat samples collected in Brazil were characterized using elemental analysis and 13C NMR. Adsorption experiments were performed using different concentrations of As with peat in natura and enriched with Fe or Al, at three different pH levels. Peat samples, in natura or enriched with metals, were analysed before and after adsorption processes using Fourier transform infrared spectroscopy (FTIR) spectroscopy. The adsorption kinetics was evaluated, and the data were fitted using the Langmuir and Freundlich models. The results showed that interaction between As and peat was dependent on the levels of organic matter (OM) and the metals (Fe and Al). As(III) was not adsorbed by in natura peat or Al-enriched peat, although small amounts of As(III) were adsorbed by Fe-enriched peat. Adsorption of As(V) by the different peat samples ranged from 21.3 to 52.7 μg g(-1). The best fit to the results was obtained using the pseudo-second-order kinetic model, and the adsorption of As(V) could be described by the Freundlich isotherm model. The results showed that Fe-enriched peat was most effective in immobilizing As(V). FTIR analysis revealed the formation of ternary complexes involving As(V) and peat enriched with metals, suggesting that As(V) was associated with Al or Fe-OM complexes by metal bridging.

  20. Properties and structure of peat humic acids depending on humification and precursor biota in bogs

    NASA Astrophysics Data System (ADS)

    Klavins, Maris; Purmalis, Oskars

    2013-04-01

    Humic substances form most of the organic component of soil, peat and natural waters, but their structure and properties very much differs depending on their source. The aim of this study is to characterize humic acids from raised bog peat profiles to evaluate the homogeneity of humic acids isolated from the bog bodies and study peat humification impact on properties of humic acids. A major impact on the structure of peat humic acids have raised bog biota (dominantly represented by bryophytes of different origin) void of lignin. For characterization of peat humic acids their elemental (CHNOS), functional (-COOH, phenolic OH) analysis, spectroscopic characterization (UV, fluorescence, FTIR, 1H NMR, CP/MAS 13C NMR, ESR) and degradation studies (Py-GC/MS) were done. Peat humic acids (HA) have an intermediate position between the living organic matter and coal organic matter and their structure is formed in a process in which more labile structures (carbohydrates, amino acids, etc.) are destroyed, but thermodynamically more stable aromatic and polyaromatic structures emerge. Comparatively, the studied peat HAs are at the start of the transformation process of living organic matter. Concentrations of carboxyl and phenolic hydroxyl groups changes depending on the depth of peat from which HAs have been isolated: and carboxylic acidity is increasing with depth of peat location and the humification degree. The ability to influence the surface tension of peat humic acids isolated from a well-characterized bog profile demonstrates dependence on age and humification degree. With increase of the humification degree and age of humic acids, their molecular complexity and ability to influence surface tension decreases; even so, the impact of the biological precursor (peat-forming bryophytes and plants) can be identified.

  1. Impact of prescribed burning on blanket peat hydrology

    NASA Astrophysics Data System (ADS)

    Holden, Joseph; Palmer, Sheila M.; Johnston, Kerrylyn; Wearing, Catherine; Irvine, Brian; Brown, Lee E.

    2015-08-01

    Fire is known to impact soil properties and hydrological flow paths. However, the impact of prescribed vegetation burning on blanket peatland hydrology is poorly understood. We studied 10 blanket peat headwater catchments. Five were subject to prescribed burning, while five were unburnt controls. Within the burnt catchments, we studied plots where the last burn occurred ˜2 (B2), 4 (B4), 7 (B7), or greater than 10 years (B10+) prior to the start of measurements. These were compared with plots at similar topographic wetness index locations in the control catchments. Plots subject to prescribed vegetation burning had significantly deeper water tables (difference in means = 5.3 cm) and greater water table variability than unburnt plots. Water table depths were significantly different between burn age classes (B2 > B4 > B7 > B10+) while B10+ water tables were not significantly different to the unburnt controls. Overland flow was less common on burnt peat than on unburnt peat, recorded in 9% and 17% of all runoff trap visits, respectively. Storm lag times and hydrograph recession limb periods were significantly greater (by ˜1 and 13 h on average, respectively) in the burnt catchments overall, but for the largest 20% of storms sampled, there was no significant difference in storm lag times between burnt and unburnt catchments. For the largest 20% of storms, the hydrograph intensity of burnt catchments was significantly greater than those of unburnt catchments (means of 4.2 × 10-5 and 3.4 × 10-5 s-1, respectively), thereby indicating a nonlinear streamflow response to prescribed burning. Together, these results from plots to whole river catchments indicate that prescribed vegetation burning has important effects on blanket peatland hydrology at a range of spatial scales.

  2. The adsorption of lead and copper from aqueous solution on modified peat-resin particles.

    PubMed

    Sun, Q Y; Lu, P; Yang, L Z

    2004-01-01

    Raw peat was modified with sulfuric acid, then mixed modified with resin to prepare the modified peat-resin particles. Using the batch experimental systems, the removal of heavy metals (copper and lead) on the modified peat-resin particles was investigated. The data of the adsorption isotherm could be fitted by the Langmuir equation well. The adsorption rate of heavy metals on modified peat-resin particles was very swift. The removal processes of heavy metals on modified peat-resin particles could be well described by pseudo-second order model. The adsorption rate of lead was affected by the initial heavy metal concentration, initial pH, particle size, agitation speed and particle mass. In the adsorption of heavy metals (lead and copper) on the modified peat-resin particles, ion exchange was the major reaction mechanism. Desorption data showed that the lead adsorbed by modified peat-resin particle could be desorbed by 0.5 N or 1.0 N HNO3. The desorption rate was swift. The experiments indicated that the modified peat-resin particles have great potential for the removal of heavy metals from wastewater.

  3. Cardiopulmonary toxicity of peat wildfire particulate matter and the predictive utility of precision cut lung slices

    EPA Science Inventory

    Background: Emissions from a large peat fire in North Carolina were associated with increased hospital admissions for asthma and the rate of heart failure in the exposed population. Peat fires often produce larger amounts of smoke and last longer than forest fires, however few st...

  4. Peat-assisted phytoremediation of waste foundry sands: plant growth, metal accumulation and fertility aspects.

    PubMed

    Moreno, Fábio N; Sígolo, Joel B; Figueira, Antonio V

    2012-03-01

    We investigated the potential of peat additions to improve plant growth and fertility and to reduce plant metal uptake in waste foundry sands (WFS) landfills. The WFS contains 78211 mg kg(-1) and 371 mg kg(-1) concentrations of Cr and Ni, respectively, and varied metal concentrations. The experiment investigated the growth of Brassica juncea plants on fertilized WFS mixed with peat at concentrations of 0, 2.5, 5, and 10% (w/w). The highest peat treatment allowed substantial plant growth and increased Ni mass in shoots, which was positively correlated to shoot biomass increments. On a concentration basis, peat additions did not increase shoot Ni values, thus suggesting that plants grown on peat-treated WFS may not increase risks to human and ecological receptors. Chromium was below detection levels in shoots for all peat treatments. Peat-treated substrates also promoted increased CEC values and higher water holding capacity, therefore improving the WFS agronomical properties. These results indicate that peat can be used as an amendment to assist in the phytoremediation of WFS landfill areas. However, there was evidence for increased mobilization of Cr and Ni in the substrate solution which can pose a threat to local groundwater.

  5. Extensive turnover of plant nitrogen in peats from the West Siberian Lowland

    NASA Astrophysics Data System (ADS)

    Philben, M. J.; Kaiser, K.; Benner, R. H.

    2012-12-01

    Nitrogen cycling in peatlands is of great interest because N is scarce in peatlands and may limit both primary production and microbial decomposition. The amino acid hydroxyproline (Hyp) was used to determine the proportion of peat N derived from plants in two peat cores collected from the West Siberian Lowland, Russia. Hyp is an effective tracer of plant N because plants are its only significant source in peats. In addition, its reactivity is similar to that of bulk plant N, so its yield in peat can be used to quantitatively estimate plant N. The C:N ratio of the peat was very high (>70) throughout both cores. As N is assumed to be conserved while C is removed with decomposition, high C:N ratios are often interpreted as indicating relatively unaltered peat. However, Hyp yields indicate extensive turnover of plant N. Peat N was mostly plant-derived in the upper 50 cm of both cores, but declined to 30-60% in the catotelm. These results suggest that N from plant litter is rapidly utilized by microbes and incorporated into new forms. Thus despite high C:N ratios, these peats have undergone substantial alteration and decomposition. This demonstrates the organic N pool in peatlands is intensely recycled and is more dynamic than can be inferred by considering the C:N ratio alone.

  6. Emissions of volatile organic compounds and particulate matter from small-scale peat fires

    EPA Science Inventory

    Air pollution emitted from peat fires can negatively impact regional air quality, visibility, climate, and human health. Peat fires can smolder over long periods of time and, therefore, can release significantly greater amounts of carbon into the atmosphere per unit area compared...

  7. Emissions of volatile organic compounds and particulate matter from small-scale peat fire

    EPA Science Inventory

    Air pollution emitted from peat fires can negatively impact regional air quality, visibility, climate, and human health. Peat fires can smolder over long periods of time and, therefore, can release significantly greater amounts of carbon into the atmosphere per unit area compared...

  8. Characterisation of VOC, SVOC, and PM emissions from peat burnt in laboratory simulations

    EPA Science Inventory

    Peat, or organic soil, is a vast store of organic carbon, widely distributed from polar temperate to equatorial regions. Drainage for agriculture and drought are drying vast areas of peat, exposing it to increasing fire risk, which may be exacerbated by climate change. This has ...

  9. Preliminary investigation of mineralogy and chemistry of peats from the Kietrz site, southern Poland

    NASA Astrophysics Data System (ADS)

    Skreczko, Sylwia; Nadłonek, Weronika; Szopa, Krzysztof

    2015-10-01

    Peat bog deposits provide a very important record of past environmental conditions, preserving biotic and abiotic processes that occurred in the vicinity of the bog. In this study, we examined three peat bog profiles from Kietrz, located in the micro-region of the Głubczycki Plateau, southern Poland. The objective of this study was to determine the type of peat occurring in this area, through examination of its mineral composition, and evaluation of the total carbon and total sulphur content. In addition, we measured peat reaction (pH) and identified floral and faunal components occurring within the peat deposits. The peat comprises primarily of fragments of fossilized plant and mollusk remains, as well as minerals (calcium sulphates, calcium carbonates, and pyrites). Additionally, an assemblage of iron oxides/hydroxides, Kfeldspar, apatite, zircon, and quartz grains was identified. A neutral and/or light alkalinity was recorded for the peat deposits, but an increase in acidity (pH) with increasing depth through each peat profile was also recorded. We observed a positive correlation between the pH and chemical composition of deposits, where a significant presence of calcite is associated with higher reaction (higher pH), whilst a lower pH is characteristic for sediments where carbonates are rare. The recognized species of mollusks are typical of shallow, fresh-water stagnant reservoirs with a high fluctuation of water level.

  10. In situ fluidization for peat bed rupture, and preliminary economic analysis.

    PubMed

    Niven, R K; Khalili, N

    2002-11-01

    This study concerns in situ fluidization (ISF), a new remediation method with potential application to the remediation of NAPL and heavy metal contaminants, by their release from the fluidized zone generated by a water jet. The present study examines the effect of ISF on layers of peat, of significance owing to its role as an important NAPL and metal contaminant trap. Once trapped, such contaminants are not readily accessible by most remedial methods, due to the low permeability and diffusivity of the peat. A simple tank experiment is used to demonstrate rupture of a peat layer by ISF, with removal of the peat as elutriated fines and segregated peat chunks. The application of ISF in the field is then examined by three field trials in uncontaminated sands, in both saturated and unsaturated conditions. Fluidized depths of up to 1.9 m in the saturated zone (with refusal on a peat layer) and 2.5 m in the unsaturated zone (no refusal) were attained, using a 1.9-m-long, 50 mm diameter jet operated at 5-13 1 s(-1). Pulses of dark turbidity and shell fragments in the effluent indicated the rupture of peat and shelly layers. The experiments demonstrate the hydraulic viability of ISF in the field, and its ability to remove peat-based contaminants. The issues of appropriate jet design and water generation during ISF are discussed, followed by a preliminary economic analysis of ISF relative to existing remediation methods.

  11. PeaT1-induced systemic acquired resistance in tobacco follows salicylic acid-dependent pathway.

    PubMed

    Zhang, Wei; Yang, Xiufen; Qiu, Dewen; Guo, Lihua; Zeng, Hongmei; Mao, Jianjun; Gao, Qiufeng

    2011-04-01

    Systemic acquired resistance (SAR) is an inducible defense mechanism which plays a central role in protecting plants from pathogen attack. A new elicitor, PeaT1 from Alternaria tenuissima, was expressed in Escherichia coil and characterized with systemic acquired resistance to tobacco mosaic virus (TMV). PeaT1-treated plants exhibited enhanced systemic resistance with a significant reduction in number and size of TMV lesions on wild tobacco leaves as compared with control. The quantitative analysis of TMV CP gene expression with real-time quantitative PCR showed there was reduction in TMV virus concentration after PeaT1 treatment. Similarly, peroxidase (POD) activity and lignin increased significantly after PeaT1 treatment. The real-time quantitative PCR revealed that PeaT1 also induced the systemic accumulation of pathogenesis-related gene, PR-1a and PR-1b which are the markers of systemic acquired resistance (SAR), NPR1 gene for salicylic acid (SA) signal transduction pathway and PAL gene for SA synthesis. The accumulation of SA and the failure in development of similar level of resistance as in wild type tobacco plants in PeaT1 treated nahG transgenic tobacco plants indicated that PeaT1-induced resistance depended on SA accumulation. The present work suggested that the molecular mechanism of PeaT1 inducing disease resistance in tobacco was likely through the systemic acquired resistance pathway mediated by salicylic acid and the NPR1 gene.

  12. Who Says There Is No Life after Abandonment? A Grounded Theory on the Coping of Abandoned Filipino Elderly in Nursing Homes

    ERIC Educational Resources Information Center

    de Guzman, Allan B.; Lacorte, Jeremy C.; Lacsamana, Andrea Keith G.; Lagac, Mark Lawrence M.; Laguador, Jobel M.; Lapid, Jazminn Jessica R.; Lee, Lyndcie Miriele C.

    2012-01-01

    Cases of abandoned elderly are increasing worldwide. By and large, this group struggles with the sudden change in living arrangement as well as abandonment by their families. Consequently, many elderly are forced into living in nursing homes for the remainder of their lives. Abandonment among these elderly negatively affects how they view…

  13. Dynamics of peat accumulation and marl flat formation in a calcareous fen, midwestern United States

    USGS Publications Warehouse

    Miner, J.J.; Ketterling, D.B.

    2003-01-01

    The age and sequence of peat accumulation were investigated at a calcareous fen in northeastern Illinois, USA. The purpose of this study was to identify the processes that form and sustain marl flats, which are areas of marl or tufa substrate within the fen that contain numerous rare plant species. Geomorphic, stratigraphic, and radiocarbon evidence was used to establish the processes and chronology of peat accumulation and erosion adjacent to each marl flat. The age of the base of the peat deposit varies greatly throughout the fen, ranging from 14,679 calibrated years before present (cal. years BP) to nearly modern, indicating that colonization of the sand and gravel substrate by peat occurred throughout the period from the Late Pleistocene to present. Adjacent to one marl flat, trends in basal peat age and thickness show that peat accumulation has progressed laterally inward from both sides, suggesting that the marl flat has been infilling with peat progressively by accumulation at the margins since at least 5,370 cal. years BP or longer. A second marl flat in the fen is surrounded by older, thick peat of differing ages on either edge and is bounded by fresh scarps, indicating that the marl flat currently is expanding laterally by erosion into the preexisting peat blanket. These two examples suggest a continuously repeating process, where erosion of the accumulated peat blanket forms a marl flat, which is later covered by peat accumulation. Trends in basal peat age elsewhere in the fen suggest that other marl flats may have existed in the past that have been completely infilled with peat. This study suggests that marl flat formation is a natural process that has been occurring for millennia, continuously creating habitat for the rare plant species that occupy marl flats. There is no evidence that the marl flats at this site are indicative of anthropogenic disturbance, so that management options for these areas are limited to maintaining the quality and quantity

  14. Abandoned pastoral settlements provide concentrations of resources for savanna birds

    NASA Astrophysics Data System (ADS)

    Söderström, Bo; Reid, Robin S.

    2010-03-01

    Knowledge is poor of how fertilization affects birds in grasslands. We investigated the impact on birds of abandoned pastoral settlements that historically received very high levels of livestock dung. A total of 28 abandoned settlements and 74 landscape controls - in Koyake Group Ranch and Maasai Mara National Reserve in Kenya - were surveyed for birds during the wet and/or dry season. Our results showed that bird species richness and total abundance increased within 200 m of abandoned pastoral settlements, particularly during the dry season when foraging resources on the savanna are limited. The high concentrations of nutrients inside abandoned settlements favoured the abundance of Diptera and Coleoptera, as shown by invertebrate surveys performed during the dry season on a subset of 32 sites. Both total numbers and dry biomass of these two invertebrate orders were higher on abandoned settlements in comparison with the surrounding landscape. We conclude that higher fertilization levels cause a temporal and spatial redistribution of birds on the savanna. Livestock fertilization and bird abundance are probably linked through an increase in abundance of invertebrate food upon which birds feed in an opportunistic fashion.

  15. Seasonal energy storage using bioenergy production from abandoned croplands

    NASA Astrophysics Data System (ADS)

    Campbell, J. Elliott; Lobell, David B.; Genova, Robert C.; Zumkehr, Andrew; Field, Christopher B.

    2013-09-01

    Bioenergy has the unique potential to provide a dispatchable and carbon-negative component to renewable energy portfolios. However, the sustainability, spatial distribution, and capacity for bioenergy are critically dependent on highly uncertain land-use impacts of biomass agriculture. Biomass cultivation on abandoned agriculture lands is thought to reduce land-use impacts relative to biomass production on currently used croplands. While coarse global estimates of abandoned agriculture lands have been used for large-scale bioenergy assessments, more practical technological and policy applications will require regional, high-resolution information on land availability. Here, we present US county-level estimates of the magnitude and distribution of abandoned cropland and potential bioenergy production on this land using remote sensing data, agriculture inventories, and land-use modeling. These abandoned land estimates are 61% larger than previous estimates for the US, mainly due to the coarse resolution of data applied in previous studies. We apply the land availability results to consider the capacity of biomass electricity to meet the seasonal energy storage requirement in a national energy system that is dominated by wind and solar electricity production. Bioenergy from abandoned croplands can supply most of the seasonal storage needs for a range of energy production scenarios, regions, and biomass yield estimates. These data provide the basis for further down-scaling using models of spatially gridded land-use areas as well as a range of applications for the exploration of bioenergy sustainability.

  16. [Adsorption of acid orange II from aqueous solution onto modified peat-resin particles].

    PubMed

    Sun, Qing-Ye; Yang, Lin-Zhang

    2007-06-01

    The adsorption of acid orange II onto modified peat-resin particles was examined in aqueous solution in a batch system. The Langmuir and Freundlich adsorption models were applied to describe the equilibrium isotherms. The pseudo-first-order, pseudo-second-order kinetic and the intraparticle diffusion models were used to describe the kinetic data. The results showed that both Langmuir and Freundlich adsorption models could be used to describe the adsorption of acid orange II onto modified peat-resin particles. The maximum adsorption capacity was 71.43 mg x g(-1). The data analysis indicated that the intraparticle diffusion model could fit the results of kinetic experiment well. The adsorption rate of acid orange II onto modified peat-resin particles is affected by the initial dye concentrations, sizes and doses of modified peat-resin particles and agitation rates. The surface of modified peat-resin particle is the major adsorption area.

  17. Uncertainties in peat volume and soil carbon estimated using ground penetrating radar and probing

    SciTech Connect

    Parsekian, Andrew D.; Slater, Lee; Ntarlagiannis, Dimitrios; Nolan, James; Sebestyen, Stephen D; Kolka, Randall K; Hanson, Paul J

    2012-01-01

    We evaluate the uncertainty in calculations of peat basin volume using high-resolution data . to resolve the three-dimensional structure of a peat basin using both direct (push probes) and indirect geophysical (ground penetrating radar) measurements. We compared volumetric estimates from both approaches with values from literature. We identified subsurface features that can introduce uncertainties into direct peat thickness measurements including the presence of woody peat and soft clay or gyttja. We demonstrate that a simple geophysical technique that is easily scalable to larger peatlands can be used to rapidly and cost effectively obtain more accurate and less uncertain estimates of peat basin volumes critical to improving understanding of the total terrestrial carbon pool in peatlands.

  18. Actinomycetal complexes in drained peat soils of the taiga zone upon pyrogenic succession

    NASA Astrophysics Data System (ADS)

    Zenova, G. M.; Glushkova, N. A.; Bannikov, M. V.; Shvarov, A. P.; Pozdnyakov, A. I.; Zvyagintsev, D. G.

    2008-04-01

    The number and diversity of actinomycetes in peat soils vary in dependence on the stage of pyrogenic succession. In the cultivated peat soil, the number of actinomycetes after fires decreases by three-four times, mainly at the expense of acidophilic and neutrophilic groups. An increase in the number of mycelial prokaryotes (at the expense of alkaliphilic forms) is seen on the fifth year of functioning of the pyrogenic peat soil. The species diversity of streptomycetes in peat soils also decreases after fires. An increase in the range of streptomycetal species at the expense of neutrophilic and alkaliphilic forms takes place on the fifth year of the pyrogenic succession. Parameters of the actinomycetal complex—the population density, species composition, and ecological features—are the criteria whose changes allow us to judge the state of peat soils in the course of their pyrogenic succession.

  19. Adsorption of dyes using peat: equilibrium and kinetic studies.

    PubMed

    Sepúlveda, L; Fernández, K; Contreras, E; Palma, C

    2004-09-01

    In recent years, adsorption has been accepted as one of the most appropriate processes for decolorization of wastewaters. This paper presents experimental results on application of peat for removal of structurally diverse dyes (azo, oxazine, triphenylmethane, thiazine and others) with emphasis on relevant factors such as the adsorbate-adsorbent chemical properties and chemical interaction as well as adsorption conditions. The equilibrium experimental results were fitted to Langmuir and Freundlich isotherms to obtain the characteristic parameters of each model. According to the evaluation using the Langmuir equation, the maximum sorption capacity of basic dyes at 22 degrees C was 667 (mg g(-1)) for Basic Blue 24, 526 (mg g(-1)) for Basic Green 4 and 714 (mg g(-1)) for Basic Violet 4. On the other hand for Acid Black 1 it was only 25 (mg g(-1)). Batch kinetics studies were undertaken and the data evaluated in compliance with chemical sorption mechanisms. For all of the systems studied the pseudo-second order model provided the best correlation of the kinetic experimental data. A film-pore double resistance diffusion model for mass transfer has also been used in this study to determine the effective diffusivity, Deff, for the adsorption of basic dyes in to peat.

  20. Electrocoagulation treatment of peat bog drainage water containing humic substances.

    PubMed

    Kuokkanen, V; Kuokkanen, T; Rämö, J; Lassi, U

    2015-08-01

    Electrocoagulation (EC) treatment of 100 mg/L synthetic wastewater (SWW) containing humic acids was optimized (achieving 90% CODMn and 80% DOC removal efficiencies), after which real peat bog drainage waters (PBDWs) from three northern Finnish peat bogs were also treated. High pollutant removal efficiencies were achieved: Ptot, TS, and color could be removed completely, while Ntot, CODMn, and DOC/TOC removal efficiencies were in the range of 33-41%, 75-90%, and 62-75%, respectively. Al and Fe performed similarly as the anode material. Large scale experiments (1 m(3)) using cold (T = 10-11 °C) PBDWs were also conducted successfully, with optimal treatment times of 60-120 min (applying current densities of 60-75 A/m(2)). Residual values of Al and Fe (complete removal) were lower than their initial values in the EC-treated PBDWs. Electricity consumption and operational costs in optimum conditions were found to be low and similar for all the waters studied: 0.94 kWh/m(3) and 0.15 €/m(3) for SWW and 0.35-0.70 kWh/m(3) and 0.06-0.12 €/m(3) for the PBDWs (large-scale). Thus, e.g. solar cells could be considered as a power source for this EC application. In conclusion, EC treatment of PBDW containing humic substances was shown to be feasible.

  1. Additives for cement compositions based on modified peat

    SciTech Connect

    Kopanitsa, Natalya Sarkisov, Yurij Gorshkova, Aleksandra Demyanenko, Olga

    2016-01-15

    High quality competitive dry building mixes require modifying additives for various purposes to be included in their composition. There is insufficient amount of quality additives having stable properties for controlling the properties of cement compositions produced in Russia. Using of foreign modifying additives leads to significant increasing of the final cost of the product. The cost of imported modifiers in the composition of the dry building mixes can be up to 90% of the material cost, depending on the composition complexity. Thus, the problem of import substitution becomes relevant, especially in recent years, due to difficult economic situation. The article discusses the possibility of using local raw materials as a basis for obtaining dry building mixtures components. The properties of organo-mineral additives for cement compositions based on thermally modified peat raw materials are studied. Studies of the structure and composition of the additives are carried out by physicochemical research methods: electron microscopy and X-ray analysis. Results of experimental research showed that the peat additives contribute to improving of cement-sand mortar strength and hydrophysical properties.

  2. Hydrology of peat-forming wetlands in Scotland.

    PubMed

    Bragg, O M

    2002-07-22

    Peatlands cover approximately 14% of Scotland, although only part of this area is active (peat-forming) mire. Mires are important for the biodiversity of the specialist plant and animal communities they support. Study of mire ecosystems has revealed intimate relationships between their organic components and water, which mean that it is impossible to understand their ecology without considering hydrology. Whilst ecohydrological studies have concentrated on the internal functioning of mires, the insights gained are relevant to runoff generation in peat-covered river catchments. This paper reviews our knowledge of processes occurring in mires and relates these to wider catchment hydrology, on the basis of published information and recent research in Scotland. The influence of different types of land management is considered, and it emerges that mire is most effective in delaying storm run-off, in preventing soil erosion and in retaining inorganic nutrients when it is undrained; although there can be adverse effects on water quality under certain conditions. In the context of global warming, mire ecosystems are sensitive but at the same time robust to climate change, and thus contain archives of climatic data for the Holocene. Moreover, peatlands store significant quantities of carbon, and influence directly the concentrations of greenhouse gases in the atmosphere. Various issues related to conservation and restoration of peatland biodiversity have been addressed constructively in recent decades, although approaches and objectives are not always consistent between sites. These are reviewed, and some outstanding issues and research needs are identified.

  3. Peat Bogs as Hotspots for Organoarsenical Formation and Persistence.

    PubMed

    Mikutta, Christian; Rothwell, James J

    2016-04-19

    Peatlands have received significant atmospheric inputs of As and S since the onset of the Industrial Revolution, but the effect of S deposition on the fate of As is largely unknown. It may encompass the formation of As sulfides and organosulfur-bound As, or the indirect stimulation of As biotransformation processes, which are presently not considered as important As immobilization pathways in wetlands. To investigate the immobilization mechanisms of anthropogenically derived As in peatlands subjected to long-term atmospheric pollution, we explored the solid-phase speciation of As, Fe, and S in English peat bogs by X-ray absorption spectroscopy. Additionally, we analyzed the speciation of As in pore- and streamwaters. Linear combination fits of extended X-ray absorption fine structure (EXAFS) data imply that 62-100% (average: 82%) of solid-phase As (Astot: 9-92 mg/kg) was present as organic As(V) and As(III). In agreement with appreciable concentrations of organoarsenicals in surface waters (pH: 4.0-4.4, Eh: 165-190 mV, average Astot: 1.5-129 μg/L), our findings reveal extensive biotransformation of atmospheric As and the enrichment of organoarsenicals in the peat, suggesting that the importance of organometal(loid)s in wetlands subjected to prolonged air pollution is higher than previously assumed.

  4. Additives for cement compositions based on modified peat

    NASA Astrophysics Data System (ADS)

    Kopanitsa, Natalya; Sarkisov, Yurij; Gorshkova, Aleksandra; Demyanenko, Olga

    2016-01-01

    High quality competitive dry building mixes require modifying additives for various purposes to be included in their composition. There is insufficient amount of quality additives having stable properties for controlling the properties of cement compositions produced in Russia. Using of foreign modifying additives leads to significant increasing of the final cost of the product. The cost of imported modifiers in the composition of the dry building mixes can be up to 90% of the material cost, depending on the composition complexity. Thus, the problem of import substitution becomes relevant, especially in recent years, due to difficult economic situation. The article discusses the possibility of using local raw materials as a basis for obtaining dry building mixtures components. The properties of organo-mineral additives for cement compositions based on thermally modified peat raw materials are studied. Studies of the structure and composition of the additives are carried out by physicochemical research methods: electron microscopy and X-ray analysis. Results of experimental research showed that the peat additives contribute to improving of cement-sand mortar strength and hydrophysical properties.

  5. Geophysical methods for locating abandoned wells

    USGS Publications Warehouse

    Frischknecht, Frank C.; Muth, L.; Grette, R.; Buckley, T.; Kornegay, B.

    1983-01-01

    A preliminary study of the feasibility of using geophysical exploration methods to locate abandoned wells containing steel casing indicated that magnetic methods promise to be effective and that some electrical techniques might be useful as auxiliary methods. Ground magnetic measurements made in the vicinity of several known cased wells yielded total field anomalies with peak values ranging from about 1,500 to 6,000 gammas. The anomalies measured on the ground are very narrow and, considering noise due to other cultural and geologic sources, a line spacing on the order of 50 feet (15.2 m) would be necessary to locate all casings in the test area. The mathematical model used to represent a casing was a set of magnetic pole pairs. By use of a non-linear least squares curve fitting (inversion) program, model parameters which characterize each test casing were determined. The position and strength of the uppermost pole was usually well resolved. The parameters of lower poles were not as well resolved but it appears that the results are adequate for predicting the anomalies which would be observed at aircraft altitudes. Modeling based on the parameters determined from the ground data indicates that all of the test casings could be detected by airborne measurements made at heights of 150 to 200 feet (45.7-61.0 m) above the ground, provided lines spaced as closely as 330 feet (100 m) were used and provided noise due to other cultural and geologic sources is not very large. Given the noise levels of currently available equipment and assuming very low magnetic gradients due to geologic sources, the detection range for total field measurements is greater than that for measurements of the horizontal or vertical gradient of the total intensity. Electrical self-potential anomalies were found to be associated with most of the casings where measurements were made. However, the anomalies tend to be very narrow and, in several cases, they are comparable in magnitude to other small

  6. Soil carbon dioxide emissions from a rubber plantation on tropical peat.

    PubMed

    Wakhid, Nur; Hirano, Takashi; Okimoto, Yosuke; Nurzakiah, Siti; Nursyamsi, Dedi

    2017-03-01

    Land-use change in tropical peatland potentially results in a large amount of carbon dioxide (CO2) emissions owing to drainage, which lowers groundwater level (GWL) and consequently enhances oxidative peat decomposition. However, field information on carbon balance is lacking for rubber plantations, which are expanding into Indonesia's peatlands. To assess soil CO2 emissions from an eight-year-old rubber plantation established on peat after compaction, soil CO2 efflux was measured monthly using a closed chamber system from December 2014 to December 2015, in which a strong El Niño event occurred, and consequently GWL lowered deeply. Total soil respiration (SR) and oxidative peat decomposition (PD) were separately quantified by trenching. In addition, peat surface elevation was measured to determine annual subsidence along with GWL. With GWL, SR showed a negative logarithmic relationship (p<0.01), whereas PD showed a strong negative linearity (p<0.001). Using the significant relationships, annual SR and PD were calculated from hourly GWL data to be 3293±1039 and 1408±214gCm(-2)yr(-1) (mean±1 standard deviation), respectively. PD accounted for 43% of SR on an annual basis. SR showed no significant difference between near and far positions from rubber trees (p>0.05). Peat surface elevation varied seasonally in almost parallel with GWL. After correcting for GWL difference, annual total subsidence was determined at 5.64±3.20 and 5.96±0.43cmyr(-1) outside and inside the trenching, respectively. Annual subsidence only through peat oxidation that was calculated from the annual PD, peat bulk density and peat carbon content was 1.50cmyr(-1). As a result, oxidative peat decomposition accounted for 25% of total subsidence (5.96cmyr(-1)) on average on an annual basis. The contribution of peat oxidation was lower than those of previous studies probably because of compaction through land preparation.

  7. Phosphorus mobilization in rewetted fens: the effect of altered peat properties and implications for their restoration.

    PubMed

    Zak, Dominik; Wagner, Carola; Payer, Brian; Augustin, Jürgen; Gelbrecht, Jörg

    2010-07-01

    Rewetting of drained fens is necessary to stop further soil degradation and to reestablish important ecological functions. However, substantial changes of peat characteristics in the upper soil layers, due to drainage and land use, could counteract their recovery as nutrient-poor systems for an unknown period. We assessed the importance of altered peat properties, such as the degree of peat decomposition and the amount of redox-sensitive phosphorus (P) compounds, for P mobilization in different degraded fens. An experimental design involving 63 intact peat cores from fens with varying drainage and land-use histories was developed to quantify the mobilization of P, as well as that of iron (Fe), ammonium, carbon dioxide, and methane, all indicators of organic-matter decomposition and/or P-releasing processes. We found that net P release rates in peat cores with highly decomposed peat (range: 0.1-52.3 mg P x m(-2) x d(-1)) were significantly correlated to the amount of P bound to redox-sensitive compounds and the molar Fe:P as well as Al:P ratios of peat. We conclude that the following general rules apply for P mobilization in rewetted fens: (1) elevated levels of P release rates and P concentrations in pore water up to three orders of magnitude larger than under natural reference conditions can only be expected for rewetted fens whose surface soil layers consist of highly decomposed peat; (2) peat characteristics, such as the amount of P bound to redox-sensitive Fe(III) compounds (positive correlation) and molar ratios of Fe:P or Al:P (negative correlations), explain the high range of P release rates; and (3) a critical P export to adjacent lakes or rivers can only be expected if molar Fe:P ratios of highly decomposed peat are less than 10.

  8. How suitable are peat cores to study historical deposition of PAHs?

    PubMed

    Thuens, Sabine; Blodau, Christian; Radke, Michael

    2013-04-15

    Ombrotrophic peat bogs are natural archives of atmospheric pollution, their depth profiles can be used to study the deposition chronology of harmful contaminants. Prerequisites for deriving historical deposition rates from the peat archive are that contaminants are persistent and immobile in the peat and that the applied dating technique is accurate. To examine these requirements and the accuracy of peat archives for polycyclic aromatic hydrocarbons (PAHs) 12 peat profiles were sampled in 4 bogs in Ontario, Canada, as well as surface peat in one bog. Additionally we carried out laboratory incubations; no degradation occurred over a 3-year period in these experiments. The standard deviations of PAH concentrations in surface samples and of PAH inventories in whole cores was approximately 30%, and concentrations in surface peat were on average 50% higher in hollows than in hummocks. No indications for mobility of PAHs were observed in peat. Temporal deposition trends inferred from peat cores were generally in agreement with trends derived from a sediment core sampled close by but deposition rates to the sediment were substantially higher. A major source of uncertainty was the rather coarse vertical sampling resolution of 5 cm which introduced substantial uncertainty in the dating of the individual segments. This caused variations of the deposition rates up to 70% per PAH between three replicate cores, and it also impedes the identification of deposition peaks. Overall, we conclude that peat cores are suitable archives for inferring atmospheric deposition trends, but due to their relatively low temporal resolution short-term events may not be identified and the development of sampling methods that allow a higher vertical resolution would greatly improve the performance of the method. The analysis of more than one core per site is suggested to provide a realistic estimate of the historic deposition and total inventories.

  9. Reduced bed agglomeration by co-combustion biomass with peat fuels in a fluidized bed

    SciTech Connect

    Karin Lundholm; Anders Nordin; Marcus Oehman; Dan Bostroem

    2005-12-01

    Fluidized bed combustion is an energy conversion technology that is very suitable for biomass combustion because of its fuel flexibility and low process temperatures. However, agglomeration of bed material may cause severe operating problems. To prevent or at least reduce this, peat has been suggested as an additive to the main fuels. Nevertheless, the characteristics of peat fuels vary and there is limited information of the effect of different peat fuels and of the mechanisms behind the agglomeration prevention. The objectives of the present work were therefore to: (I) quantify the potential positive effect by co-combustion peat with forest fuels in terms of initial agglomeration temperatures; (ii) determine the amount of peat fuel that is needed to significantly reduce the agglomeration tendencies; and, if possible, (iii) elucidate the governing mechanisms. The results showed that all peat fuels prevented agglomeration in the studied interval of 760-1020{sup o}C and even as little as 5% peat fuel was found to have significant effects. The results also indicated that the mechanism of the agglomeration prevention varies between different peat fuels. Possible mechanisms are the minerals in the peat fuel retain alkali, which then is either elutriated up from the bed or captured in the bed; calcium and other refractory elements increase the melting temperature and thereby counteract the melting of alkali; and sulfur reacts with alkali metals and the alkali sulfates is either elutriated up from the bed or prevents agglomeration by increased melting temperature and lowered viscosity. Results from elemental analysis of the coating on bed particles showed that all mixtures with peat fuel resulted in a decreased or unchanged fraction of potassium and an increased fraction of aluminum in the coatings. The results also indicated a complex relationship between the fuel inorganic contents and the agglomeration process. 21 refs., 6 figs., 5 tabs.

  10. Age Determination of the Remaining Peat in the Sacramento-San Joaquin Delta, California, USA

    USGS Publications Warehouse

    Drexler, Judith Z.; de Fontaine, Christian S.; Knifong, Donna L.

    2007-01-01

    Introduction The Sacramento-San Joaquin Delta of California was once a 1,400 square kilometer (km2) tidal marsh, which contained a vast layer of peat ranging up to 15 meters (m) thick (Atwater and Belknap, 1980). Because of its favorable climate and highly fertile peat soils, the majority of the Delta was drained and reclaimed for agriculture during the late 1800s and early 1900s. Drainage of the peat soils changed the conditions in the surface layers of peat from anaerobic (having no free oxygen present) to aerobic (exposed to the atmosphere). This change in conditions greatly increased the decomposition rate of the peat, which consists largely of organic (plant) matter. Thus began the process of land-surface subsidence, which initially was a result of peat shrinkage and compaction, and later largely was a result of oxidation by which organic carbon in the peat essentially vaporized to carbon dioxide (Deverel and others, 1998; Ingebritsen and Ikehara, 1999). Because of subsidence, the land-surface elevation on farmed islands in the Delta has decreased from a few meters to as much as 8 m below local mean sea level (California Department of Water Resources, 1995; Steve Deverel, Hydrofocus, Inc., written commun., 2007). The USGS, in collaboration with the University of California at Davis, and Hydrofocus Inc. of Davis, California, has been studying the formation of the Delta and the impact of wetland reclamation on the peat column as part of a project called Rates and Evolution of Peat Accretion through Time (REPEAT). The purpose of this report is to provide results on the age of the remaining peat soils on four farmed islands in the Delta.

  11. Changes in Flow and Transport Patterns in Fen Peat as a Result of Soil Degradation

    NASA Astrophysics Data System (ADS)

    Liu, Haojie; Janssen, Manon; Lennartz, Bernd

    2016-04-01

    The preferential movement of water and transport of substances play an important role in soils and are not yet fully understood especially in degraded peat soils. In this study, we aimed at deducing changes in flow and transport patterns in the course of soil degradation as resulting from peat drainage, using titanium dioxide (TiO2) as a dye tracer. The dye tracer experiments were conducted on columns of eight types of differently degraded peat soils from three sites taken both in vertical and horizontal directions. The titanium dioxide suspension (average particle size of 0.3 μm; 10 g l-1) was applied in a pulse of 40 mm to each soil core. Twenty-four hours after the application of the tracer, cross sections of the soil cores were prepared for photo documentation. In addition, the saturated hydraulic conductivity (Ks) was determined. Preferential flow occurred in all investigated peat types. From the stained soil structural elements, we concluded that undecomposed plant remains are the major preferential flow pathways in less degraded peat. For more strongly degraded peat, bio-pores, such as root and earthworm channels, operated as the major transport domain. Results show that Ks and the effective pore network in less degraded peat soils are anisotropic. With increasing peat degradation, the Ks and cross section of effective pore network decreased. The results also indicate a strong positive relationship between Ks and number of macropores as well as pore continuity. Hence, we conclude that changes in flow and transport pathways as well as Ks with an increasing peat degradation are due to the disintegration of the peat forming plant material and decrement of number and continuity of macropores after drainage.

  12. An analytical protocol for the determination of total mercury concentrations in solid peat samples.

    PubMed

    Roos-Barraclough, F; Givelet, N; Martinez-Cortizas, A; Goodsite, M E; Biester, H; Shotyk, W

    2002-06-20

    Traditional peat sample preparation methods such as drying at high temperatures and milling may be unsuitable for Hg concentration determination in peats due to the possible presence of volatile Hg species, which could be lost during drying. Here, the effects of sample preparation and natural variation on measured Hg concentrations are investigated. Slight increases in mercury concentrations were observed in samples dried at room temperature and at 30 degrees C (6.7 and 2.48 ng kg(-1) h(-1), respectively), and slight decreases were observed in samples dried at 60, 90 and 105 degrees C (2.36, 3.12 and 8.52 ng kg(-1) h(-1), respectively). Fertilising the peat slightly increased Hg loss (3.08 ng kg(-1) h(-1) in NPK-fertilised peat compared to 0.28 ng kg(-1) h(-1) in unfertilised peat, when averaged over all temperatures used). Homogenising samples by grinding in a machine also caused a loss of Hg. A comparison of two Hg profiles from an Arctic peat core, measured in frozen samples and in air-dried samples, revealed that no Hg losses occurred upon air-drying. A comparison of Hg concentrations in several plant species that make up peat, showed that some species (Pinus mugo, Sphagnum recurvum and Pseudevernia furfuracea) are particularly efficient Hg retainers. The disproportionally high Hg concentrations in these species can cause considerable variation in Hg concentrations within a peat slice. The variation of water content (1.6% throughout 17-cm core, 0.97% in a 10 x 10 cm slice), bulk density (40% throughout 17-cm core, 15.6% in a 10 x 10 cm slice) and Hg concentration (20% in a 10 x 10 cm slice) in ombrotrophic peat were quantified in order to determine their relative importance as sources of analytical error. Experiments were carried out to determine a suitable peat analysis program using the Leco AMA 254, capable of determining mercury concentrations in solid samples. Finally, an analytical protocol for the determination of Hg concentrations in solid peat samples

  13. Atmospheric lead and heavy metal pollution records from a Belgian peat bog spanning the last two millenia: human impact on a regional to global scale.

    PubMed

    De Vleeschouwer, François; Gérard, Laëtitia; Goormaghtigh, Catherine; Mattielli, Nadine; Le Roux, Gaël; Fagel, Nathalie

    2007-05-15

    Europe has been continuously polluted throughout the last two millennia. During the Roman Empire, these pollutions were mainly from ore extraction and smelting across Europe. Then, during the Middle Ages and the Early times of Industrial revolution (i.e. 1750), these pollutions extended to coal burning and combustion engine. Belgian ombrotrophic peat bogs have proved an effective archive of these pollutants and provide the opportunity to reconstruct the history of atmospheric deposition in NW Europe. The results of recent and past trace metal accumulation and Pb isotopes from a one-meter peat core (in the Misten peat bog) have been derived using XRF and Nu-plasma MC-ICP-MS. Combined with (14)C and (210)Pb dates these data have enabled us to trace fluxes in anthropogenic pollution back to original Roman times. Several periods of well-known Pb pollution events are clearly recorded including the Early and Late Roman Empire, the Middle Ages and the second industrial revolution. Also recorded is the introduction of leaded gasoline, and more recently the introduction of unleaded gasoline. Lead isotopes in this site have also enabled us to fingerprint several regional and global sources of anthropogenic particles.

  14. Peat form and distribution – acrotelm hydrology and topographic wetness index

    NASA Astrophysics Data System (ADS)

    Kirkby, Mike; Irvine, Brian

    2015-04-01

    Away from the divide in a peat mire, steadily increasing volumes of rainwater flowing through and over the peat can only be transported by increasing surface and water table gradient, forcing development of a domed form for a raised bog. Simple models assume either a groundwater mound in which the peat surface is defined by the water table, or a surface limited by the balance between growth and decomposition. Recognised complications to the hydrology include the observations of substantial flow both close to the bog surface and through pipes within the peat mass and the near-random heterogeneity of hydraulic conductivity values in the peat. In addition the assumptions of these end member models interact, since increases in peat depth allow more water to flow through the catotelm, thereby increasing seasonal drying near the surface and raising decomposition rates. These competing factors have been built into a model which combines TOPmodel near-surface with Darcian flow at depth, creating a dynamic oxic layer within which rates of decomposition are highest. This enriched mire model, distinguishes bogs, and regions within bogs, dominated by surface or internal flow and those that are limited by growth and decomposition. The model also helps to clarify the important role of seasonality in bog growth, provides some guidance on where peat can become established, on the basis of climate and local topography, and how this may evolve as global temperatures rise.

  15. Net ecosystem CO2 exchange of a primary tropical peat swamp forest in Sarawak, Malaysia

    NASA Astrophysics Data System (ADS)

    Tang Che Ing, A.; Stoy, P. C.; Melling, L.

    2014-12-01

    Tropical peat swamp forests are widely recognized as one of the world's most efficient ecosystems for the sequestration and storage of carbon through both their aboveground biomass and underlying thick deposits of peat. As the peat characteristics exhibit high spatial and temporal variability as well as the structural and functional complexity of forests, tropical peat ecosystems can act naturally as both carbon sinks and sources over their life cycles. Nonetheless, few reports of studies on the ecosystem-scale CO2 exchange of tropical peat swamp forests are available to-date and their present roles in the global carbon cycle remain uncertain. To quantify CO2 exchange and unravel the prevailing factors and potential underlying mechanism regulating net CO2 fluxes, an eddy covariance tower was erected in a tropical peat swamp forest in Sarawak, Malaysia. We observed that the diurnal and seasonal patterns of net ecosystem CO2 exchange (NEE) and its components (gross primary productivity (GPP) and ecosystem respiration (RE)) varied between seasons and years. Rates of NEE declined in the wet season relative to the dry season. Conversely, both the gross primary productivity (GPP) and ecosystem respiration (RE) were found to be higher during the wet season than the dry season, in which GPP was strongly negatively correlated with NEE. The average annual NEE was 385 ± 74 g C m-2 yr-1, indicating the primary peat swamp forest functioned as net source of CO2 to the atmosphere over the observation period.

  16. Peat decomposition - shaping factors, significance in environmental studies and methods of determination; a literature review

    NASA Astrophysics Data System (ADS)

    Drzymulska, Danuta

    2016-03-01

    A review of literature data on the degree of peat decomposition - an important parameter that yields data on environmental conditions during the peat-forming process, i.e., humidity of the mire surface, is presented. A decrease in the rate of peat decomposition indicates a rise of the ground water table. In the case of bogs, which receive exclusively atmospheric (meteoric) water, data on changes in the wetness of past mire surfaces could even be treated as data on past climates. Different factors shaping the process of peat decomposition are also discussed, such as humidity of the substratum and climatic conditions, as well as the chemical composition of peat-forming plants. Methods for the determination of the degree of peat decomposition are also outlined, maintaining the division into field and laboratory analyses. Among the latter are methods based on physical and chemical features of peat and microscopic methods. Comparisons of results obtained by different methods can occasionally be difficult, which may be ascribed to different experience of researchers or the chemically undefined nature of many analyses of humification.

  17. On the retention of uranyl and thorium ions from radioactive solution on peat moss.

    PubMed

    Humelnicu, Doina; Bulgariu, Laura; Macoveanu, Matei

    2010-02-15

    The efficiency of the radioactive uranyl and thorium ions on the peat moss from aqueous solutions has been investigated under different experimental conditions. The sorption and desorption of uranyl and thorium ions on three types (unmodified peat moss, peat moss treated with HNO(3) and peat moss treated with NaOH) of peat moss were studied by the static method. Peat moss was selected as it is available in nature, in any amount, as a cheap and accessible sorbent. Study on desorption of such ions led to the conclusion that the most favourable desorptive reagent for the uranyl ions is Na(2)CO(3) 1M while, for the thorium ions is HCl 1M. The results obtained show that the parameters here under investigation exercise a significant effect on the sorption process of the two ions. Also, the investigations performed recommend the peat moss treated with a base as a potential sorbent for the uranyl and thorium ions from a radioactive aqueous solution.

  18. The legacy of wetland drainage on the remaining peat in the Sacramento San Joaquin Delta, California, USA

    USGS Publications Warehouse

    Drexler, J.Z.; De Fontaine, C. S.; Deverel, S.J.

    2009-01-01

    Throughout the world, many extensive wetlands, such as the Sacramento-San Joaquin Delta of California (hereafter, the Delta), have been drained for agriculture, resulting in land-surface subsidence of peat soils. The purpose of this project was to study the in situ effects of wetland drainage on the remaining peat in the Delta. Peat cores were retrieved from four drained, farmed islands and four relatively undisturbed, marsh islands. Core samples were analyzed for bulk density and percent organic carbon. Macrofossils in the peat were dated using radiocarbon age determination. The peat from the farmed islands is highly distinct from marsh island peat. Bulk density of peat from the farmed islands is generally greater than that of the marsh islands at a given organic carbon content. On the farmed islands, increased bulk density, which is an indication of compaction, decreases with depth within the unoxidized peat zone, whereas, on the marsh islands, bulk density is generally constant with depth except near the surface. Approximately 5580 of the original peat layer on the farmed islands has been lost due to land-surface subsidence. For the center regions of the farmed islands, this translates into an estimated loss of between 29005700 metric tons of organic carbon/hectare. Most of the intact peat just below the currently farmed soil layer is over 4000 years old. Peat loss will continue as long as the artificial water table on the farmed islands is held below the land surface. ?? 2009 The Society of Wetland Scientists.

  19. The legacy of wetland drainage on the remaining peat in the Sacramento-San Joaquin Delta, California, USA

    USGS Publications Warehouse

    Drexler, Judith Z.; Christian S. de Fontaine,; Steven J. Deverel,

    2009-01-01

    Throughout the world, many extensive wetlands, such as the Sacramento-San Joaquin Delta of California (hereafter, the Delta), have been drained for agriculture, resulting in land-surface subsidence of peat soils. The purpose of this project was to study the in situ effects of wetland drainage on the remaining peat in the Delta. Peat cores were retrieved from four drained, farmed islands and four relatively undisturbed, marsh islands. Core samples were analyzed for bulk density and percent organic carbon. Macrofossils in the peat were dated using radiocarbon age determination. The peat from the farmed islands is highly distinct from marsh island peat. Bulk density of peat from the farmed islands is generally greater than that of the marsh islands at a given organic carbon content. On the farmed islands, increased bulk density, which is an indication of compaction, decreases with depth within the unoxidized peat zone, whereas, on the marsh islands, bulk density is generally constant with depth except near the surface. Approximately 55–80% of the original peat layer on the farmed islands has been lost due to landsurface subsidence. For the center regions of the farmed islands, this translates into an estimated loss of between 2900-5700 metric tons of organic carbon/hectare. Most of the intact peat just below the currently farmed soil layer is over 4000 years old. Peat loss will continue as long as the artificial water table on the farmed islands is held below the land surface.

  20. The impact of drought and air pollution on metal profiles in peat cores.

    PubMed

    Souter, Laura; Watmough, Shaun A

    2016-01-15

    Peat cores have long been used to reconstruct atmospheric metal deposition; however, debate remains regarding how well historical depositional patterns are preserved in peat. This study examined peat cores sampled from 14 peatlands in the Sudbury region of Ontario, Canada, which has a well-documented history of acid and metal deposition. Copper (Cu) and lead (Pb) concentrations within individual peat cores were strongly correlated and were elevated in the upper 10 cm, especially in the sites closest to the main Copper Cliff smelter. In contrast, nickel (Ni) and cobalt (Co) concentrations were often elevated at depths greater than 10 cm, indicating much greater post-depositional movement of these metals compared with Cu and Pb. Post-depositional movement of metals is supported by the observation that Ni and Co concentrations in peat pore water increased by approximately 530 and 960% for Ni and Co, respectively between spring and summer due to drought-induced acidification, but there was much less change in Cu concentration. Sphagnum cover and (210)Pb activity measured at 10 cm at the 14 sites significantly increased with distance from Copper Cliff, and the surface peat von Post score decreased with distance from Copper Cliff, indicating the rate of peat formation increases with distance from Sudbury presumably as a result of improved Sphagnum survival. This study shows that the ability of peat to preserve deposition histories of some metals is strongly affected by drought-induced post-depositional movement and that loss of Sphagnum due to air pollution impairs the rate of peat formation, further affecting metal profiles in peatlands.

  1. Improving conceptual models of water and carbon transfer through peat

    USGS Publications Warehouse

    McKenzie, Jeffery M.; Siegel, Donald I.; Rosenberry, Donald O.; Baird, Andrew J.; Belyea, Lisa R.; Comas, Xavier; Reeve, A.S.; Slater, Lee D.

    2009-01-01

    Northern peatlands store 500 × 1015 g of organic carbon and are very sensitive to climate change. There is a strong conceptual model of sources, sinks, and pathways of carbon within peatlands, but challenges remain both in understanding the hydrogeology and the linkages between carbon cycling and peat pore water flow. In this chapter, research findings from the glacial Lake Agassiz peatlands are used to develop a conceptual framework for peatland hydrogeology and identify four challenges related to northern peatlands yet to be addressed: (1) develop a better understanding of the extent and net impact of climate-driven groundwater flushing in peatlands; (2) quantify the complexities of heterogeneity on pore water flow and, in particular, reconcile contradictions between peatland hydrogeologic interpretations and isotopic data; (3) understand the hydrogeologic implications of free-phase methane production, entrapment, and release in peatlands; and (4) quantify the impact of arctic and subarctic warming on peatland hydrogeology and its linkage to carbon cycling.

  2. 7. ALIGNMENT OF ABANDONED COULTERVILLE ROAD IN FORESTA AT FALLEN ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    7. ALIGNMENT OF ABANDONED COULTERVILLE ROAD IN FORESTA AT FALLEN TREE IN CENTER REAR. FOREGROUND MARKS TURN OF NEW ROAD FROM FORESTA TO HIGHWAY 120. LOOKING E. GIS: N-37 42 16.6 / W-119 44 00.3 - Coulterville Road, Between Foresta & All-Weather Highway, Yosemite Village, Mariposa County, CA

  3. 90. View of east facade of powerhouse, and abandoned lightning ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    90. View of east facade of powerhouse, and abandoned lightning arrester houses on hillside above powerhouse; looking west. Photo by Jet Lowe, HAER, 1989. - Puget Sound Power & Light Company, White River Hydroelectric Project, 600 North River Avenue, Dieringer, Pierce County, WA

  4. 36 CFR 13.45 - Unattended or abandoned property.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... INTERIOR NATIONAL PARK SYSTEM UNITS IN ALASKA General Provisions § 13.45 Unattended or abandoned property... access the contents. Storing property in a manner that wildlife can access contents is prohibited. (4..., or both. (d) In the event unattended property interferes with the safe and orderly management of...

  5. 36 CFR 13.45 - Unattended or abandoned property.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... INTERIOR NATIONAL PARK SYSTEM UNITS IN ALASKA General Provisions § 13.45 Unattended or abandoned property... access the contents. Storing property in a manner that wildlife can access contents is prohibited. (4..., or both. (d) In the event unattended property interferes with the safe and orderly management of...

  6. 37 CFR 2.66 - Revival of abandoned applications.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... applications. 2.66 Section 2.66 Patents, Trademarks, and Copyrights UNITED STATES PATENT AND TRADEMARK OFFICE... date of issuance of the notice of abandonment; or (2) Within two months of actual knowledge of the... with firsthand knowledge of the facts, that the delay in filing the response on or before the due...

  7. Predicting Abandonment of School-Wide Behavior Support Interventions

    ERIC Educational Resources Information Center

    Nese, Rhonda N. T.; McIntosh, Kent; Nese, Joseph F. T.; Ghemraoui, Adam; Bloom, Jerry; Johnson, Nanci W.; Phillips, Danielle; Richter, Mary F.; Hoselton, Robert

    2016-01-01

    This study examines predictors of abandonment of evidence-based practices through descriptive analyses of extant state-level training data, fidelity of implementation data, and nationally reported school demographic data across 915 schools in 3 states implementing school-wide positive behavioral interventions and supports (SWPBIS). Schools…

  8. 49 CFR 195.59 - Abandonment or deactivation of facilities.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... System (NPMS) in accordance with the NPMS “Standards for Pipeline and Liquefied Natural Gas Operator... in accordance with applicable laws. Refer to the NPMS Standards for details in preparing your data... abandoned in accordance with all applicable laws. (b) [Reserved] [Amdt. 195-69, 65 FR 54444, Sept. 8,...

  9. 1. ABANDONED TURNOUT (CALLED CAPTAIN WHEEL) TO SAN TAN INDIAN ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    1. ABANDONED TURN-OUT (CALLED CAPTAIN WHEEL) TO SAN TAN INDIAN CANAL OFF OF SAN TAN FLOOD-WATER CANAL, T4S, R6E, S11/12. VIEW LOOKING SOUTHWEST. - San Carlos Irrigation Project, San Tan Indian Canal, North of Gila River, Coolidge, Pinal County, AZ

  10. 2. UPSTREAM SIDE OF DAM AND BRIDGE WITH ABANDONED SAN ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    2. UPSTREAM SIDE OF DAM AND BRIDGE WITH ABANDONED SAN TAN FLOOD-WATER HEADGATE IN FOREGROUND. TAKEN FROM NORTH END OF DAM - San Carlos Irrigation Project, Sacaton Dam & Bridge, Gila River, T4S R6E S12/13, Coolidge, Pinal County, AZ

  11. Deradicalization or Disengagement : A Framework for Encouraging Jihad Abandonment

    DTIC Science & Technology

    2016-06-10

    included law enforcement, the military, and intelligence services. Only recently have soft power elements been brought to bear to encourage jihad...intelligence services. Only recently have soft power elements been brought to bear to encourage jihad abandonment. Several nations implement a variety of de

  12. The Bureau of Refugees, Freedmen, and Abandoned Lands

    ERIC Educational Resources Information Center

    Chism, Kahlil

    2006-01-01

    This article discusses the Bureau of Refugees, Freedmen, and Abandoned Lands (Freedmen's Bureau), which was established by the Congress on March 3, 1865, to assist former slaves in acquiring land, securing employment, legalizing marriages, and pursuing education. After the bureau's abolition through an act of Congress approved on June 10, 1872,…

  13. 78 FR 9803 - Tennessee Abandoned Mine Land Program

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-02-12

    ... bill revised the AML program in areas of coal re-mining, abandoned coal refuse sites, as well as... Selection; Coordination with Other Programs; Land Acquisition, Management and Disposal; Reclamation on... of OSM, Tennessee revised its proposed amendment to read, ``Land Acquisition, Management and...

  14. 36 CFR 331.22 - Abandonment of personal property.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 36 Parks, Forests, and Public Property 3 2011-07-01 2011-07-01 false Abandonment of personal property. 331.22 Section 331.22 Parks, Forests, and Public Property CORPS OF ENGINEERS, DEPARTMENT OF THE ARMY REGULATIONS GOVERNING THE PROTECTION, USE AND MANAGEMENT OF THE FALLS OF THE OHIO...

  15. PARTIAL VIEW OF NORTH SIDE, SHOWING ENCLOSED CONVEYOR AND ABANDONED ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    PARTIAL VIEW OF NORTH SIDE, SHOWING ENCLOSED CONVEYOR AND ABANDONED PEDESTRIAN BRIDGE TO THE FORMER THIRD FLOOR. VIEW FACING SOUTH-SOUTHEAST. - U.S. Naval Base, Pearl Harbor, Aviation Storehouse, Vincennes Avenue at Simms Street, Pearl City, Honolulu County, HI

  16. 30 CFR 556.56 - Lease-specific abandonment accounts.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 2 2012-07-01 2012-07-01 false Lease-specific abandonment accounts. 556.56 Section 556.56 Mineral Resources BUREAU OF OCEAN ENERGY MANAGEMENT, DEPARTMENT OF THE INTERIOR OFFSHORE... the current Treasury Circular No. 154 from the Surety Bond Branch, Financial Management...

  17. 30 CFR 556.56 - Lease-specific abandonment accounts.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 30 Mineral Resources 2 2014-07-01 2014-07-01 false Lease-specific abandonment accounts. 556.56 Section 556.56 Mineral Resources BUREAU OF OCEAN ENERGY MANAGEMENT, DEPARTMENT OF THE INTERIOR OFFSHORE... the current Treasury Circular No. 154 from the Surety Bond Branch, Financial Management...

  18. 30 CFR 556.56 - Lease-specific abandonment accounts.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 2 2013-07-01 2013-07-01 false Lease-specific abandonment accounts. 556.56 Section 556.56 Mineral Resources BUREAU OF OCEAN ENERGY MANAGEMENT, DEPARTMENT OF THE INTERIOR OFFSHORE... the current Treasury Circular No. 154 from the Surety Bond Branch, Financial Management...

  19. Eastern Agency Navajo Abandoned Uranium Mine Open House

    EPA Pesticide Factsheets

    Learn about the Contaminated Structures Program in the greater Eastern Agency with representatives from EPA, DOE, and Navajo Abandoned Mine Lands Program with updates on activities at NE Church Rock, Kerr-McGee/Quivira, and United Nuclear Co. Mill site.

  20. 36 CFR 13.906 - Unattended or abandoned property.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 36 Parks, Forests, and Public Property 1 2011-07-01 2011-07-01 false Unattended or abandoned property. 13.906 Section 13.906 Parks, Forests, and Public Property NATIONAL PARK SERVICE, DEPARTMENT OF THE INTERIOR NATIONAL PARK SYSTEM UNITS IN ALASKA Special Regulations-Denali National Park...

  1. 36 CFR 13.906 - Unattended or abandoned property.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 36 Parks, Forests, and Public Property 1 2010-07-01 2010-07-01 false Unattended or abandoned property. 13.906 Section 13.906 Parks, Forests, and Public Property NATIONAL PARK SERVICE, DEPARTMENT OF THE INTERIOR NATIONAL PARK SYSTEM UNITS IN ALASKA Special Regulations-Denali National Park...

  2. Why We Should Abandon the Idea of the Learning Organization

    ERIC Educational Resources Information Center

    Grieves, Jim

    2008-01-01

    Purpose: The purpose of this paper is to propose that the idea of the learning organization should be abandoned on the grounds that it was an imaginative idea that has now run its course. The paper seeks to explore the roots of the definition and provoke debate about the wisdom of retaining the concept. The argument is a challenge to readers to…

  3. 36 CFR 331.22 - Abandonment of personal property.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 36 Parks, Forests, and Public Property 3 2010-07-01 2010-07-01 false Abandonment of personal property. 331.22 Section 331.22 Parks, Forests, and Public Property CORPS OF ENGINEERS, DEPARTMENT OF THE ARMY REGULATIONS GOVERNING THE PROTECTION, USE AND MANAGEMENT OF THE FALLS OF THE OHIO...

  4. 7. ABANDONED OLD HIGHWAY 101. NORTH OF LEGGETT. HUMBOLDT COUNTY, ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    7. ABANDONED OLD HIGHWAY 101. NORTH OF LEGGETT. HUMBOLDT COUNTY, CALIFORNIA. NOTE CANTILEVERED DECKING. SOUTH FORK OF EEL RIVER AT LEFT. LOOKING SW. - Redwood National & State Parks Roads, California coast from Crescent City to Trinidad, Crescent City, Del Norte County, CA

  5. Inventory of Tank Farm equipment stored or abandoned aboveground

    SciTech Connect

    Hines, S.C.; Lakes, M.E.

    1994-10-12

    This document provides an inventory of Tank Farm equipment stored or abandoned aboveground and potentially subject to regulation. This inventory was conducted in part to ensure that Westinghouse Hanford Company (WHC) does not violate dangerous waste laws concerning storage of potentially contaminated equipment/debris that has been in contact with dangerous waste. The report identifies areas inventoried and provides photographs of equipment.

  6. Artesian Well Abandonment at Launch Complex 39A

    NASA Technical Reports Server (NTRS)

    Morgan, Lindsay; Johansen, Deda

    2015-01-01

    The artesian well tasked for abandonment was located on the LOX side (northwest area) of the launch complex. The exact date of well installation is unknown. The well was no longer in use at the time of the abandonment request, but was previously utilized under St. Johns River Water Management District (SJRWMD) consumptive use permit (No. 50054) for the Floridian Aquifer. The exact construction details of the LOX artesian well were also unknown; however, a similar-type artesian well was previously located on the LH2 side of the site, which was abandoned in 2012. Based on discussions with the NASA RPM and review of the LH2 artesian well abandonment completion report, the LH2 artesian well was reported to be an 8-inch diameter, 330-foot deep well. The NASA RPM communicated that the LOX artesian well was likely to be an 8-inch diameter, 380-foot deep well. This information was used for scoping, and was subsequently confirmed to be substantially accurate. No additional information could be found for the LOX artesian well using the NASA Remediation Information System (RIS).

  7. 36 CFR 13.906 - Unattended or abandoned property.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 36 Parks, Forests, and Public Property 1 2012-07-01 2012-07-01 false Unattended or abandoned property. 13.906 Section 13.906 Parks, Forests, and Public Property NATIONAL PARK SERVICE, DEPARTMENT OF THE INTERIOR NATIONAL PARK SYSTEM UNITS IN ALASKA Special Regulations-Denali National Park...

  8. 36 CFR 13.906 - Unattended or abandoned property.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 36 Parks, Forests, and Public Property 1 2013-07-01 2013-07-01 false Unattended or abandoned property. 13.906 Section 13.906 Parks, Forests, and Public Property NATIONAL PARK SERVICE, DEPARTMENT OF THE INTERIOR NATIONAL PARK SYSTEM UNITS IN ALASKA Special Regulations-Denali National Park...

  9. 36 CFR 13.906 - Unattended or abandoned property.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 36 Parks, Forests, and Public Property 1 2014-07-01 2014-07-01 false Unattended or abandoned property. 13.906 Section 13.906 Parks, Forests, and Public Property NATIONAL PARK SERVICE, DEPARTMENT OF THE INTERIOR NATIONAL PARK SYSTEM UNITS IN ALASKA Special Regulations-Denali National Park...

  10. 11. An abandoned electrical system was found under the pressedsteel ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    11. An abandoned electrical system was found under the pressed-steel ceiling. For some undetermined reason the pattern of the ceiling panels has 'photographed' onto the cardboard substrate. Two different panel designs were utilized in a checkerboard pattern. One panel of each design remains in place. Credit GADA/MRM. - Stroud Building, 31-33 North Central Avenue, Phoenix, Maricopa County, AZ

  11. View of interior of abandoned section of rail mill where ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    View of interior of abandoned section of rail mill where the roof has been removed (note the steel frame structure that supported the traveling crane); looking south - Bethlehem Steel Corporation, South Bethlehem Works, Iron Foundry, Along Lehigh River, North of Fourth Street, West of Minsi Trail Bridge, Bethlehem, Northampton County, PA

  12. Field-tracing approach to determine flow velocity and hydraulic conductivity in saturated peat soils

    SciTech Connect

    Gafni, A.

    1986-01-01

    A tracing methodology based on the point dilution concept was developed to quantify groundwater velocities in saturated peat soils. Groundwater velocity was measured in four different peatlands. The steepest hydraulic gradient and the dominant direction of groundwater flow were determined for each peatland. The hydraulic conductivity (K) of selected peat layers was estimated from measured groundwater velocity and hydraulic gradient using Darcy's equation. The effective porosity of three peat layers was determined using the pressure plate technique. The estimated hydraulic parameters of one of the bags were further evaluated by analyzing a rainfall-runoff event that exhibited groundwater discharge.

  13. Polyphenols as enzyme inhibitors in different degraded peat soils: Implication for microbial metabolism in rewetted peatlands

    NASA Astrophysics Data System (ADS)

    Zak, Dominik; Roth, Cyril; Gelbrecht, Jörg; Fenner, Nathalie; Reuter, Hendrik

    2015-04-01

    Recently, more than 30,000 ha of drained minerotrophic peatlands (= fens) in NE Germany were rewetted to restore their ecological functions. Due to an extended drainage history, a re-establishment of their original state is not expected in the short-term. Elevated concentrations of dissolved organic carbon, ammonium and phosphate have been measured in the soil porewater of the upper degraded peat layers of rewetted fens at levels of one to three orders higher than the values in pristine systems; an indicator of increased microbial activity in the upper degraded soil layers. On the other hand there is evidence that the substrate availability within the degraded peat layer is lowered since the organic matter has formerly been subject to intense decomposition over the decades of drainage and intense agricultural use of the areas. Previously however, it was suggested that inhibition of hydrolytic enzymes by polyphenolic substances is suspended during aeration of peat soils mainly due to the decomposition of the inhibiting polyphenols by oxidising enzymes such as phenol oxidase. Accordingly we hypothesised a lack of enzyme inhibiting polyphenols in degraded peat soils of rewetted fens compared to less decomposed peat of more natural fens. We collected both peat samples at the soil surface (0-20 cm) and fresh roots of dominating vascular plants and mosses (as peat parent material) from five formerly drained rewetted sites and five more natural sites of NE Germany and NW Poland. Less decomposed peat and living roots were used to obtain an internal standard for polyphenol analysis and to run enzyme inhibition tests. For all samples we determined the total phenolic contents and in addition we distinguished between the contents of hydrolysable and condensed tannic substances. From a methodical perspective the advantage of internal standards compared to the commercially available standards cyanidin chloride and tannic acid became apparent. Quantification with cyanidin or

  14. Coal and peat in the sub-Saharan region of Africa: alternative energy options?

    USGS Publications Warehouse

    Weaver, J.N.; Landis, E.R.

    1990-01-01

    Coal and peat are essentially unused and in some cases unknown in sub-Saharan Africa. However, they might comprise valuable alternative energy sources in some or all of the developing nations of the region. The 11 countries considered in this appraisal reportedly contain coal and peat. On the basis of regional geology, another five countries might also contain coal-bearing rocks. If the resource potential is adequate, coal and peat might be utilized in a variety of ways including substituting for fuelwood, generating electricity, supplying process heat for local industry and increasing agricultural productivity. -from Author

  15. Mechanisms regulating bioavailability of phenanthrene sorbed on a peat soil-origin humic substance.

    PubMed

    Yang, Yu; Shu, Liang; Wang, Xilong; Xing, Baoshan; Tao, Shu

    2012-07-01

    The organic matter-mineral complex plays an important role in regulating the fate of hydrophobic organic compounds (HOCs) in the environment. In the present study, the authors investigated the microbial bioavailability of phenanthrene (PHE) sorbed on the original and demineralized humic acids (HAs) and humin (HM) that were sequentially extracted from a peat soil. Demineralization treatment dramatically decreased the 720-h mineralized percentage of HM-sorbed PHE from 42.5 ± 2.6% to 3.4 ± 1.3%, whereas the influence of this treatment on the biodegradability of HA-associated PHE was much lower. Degradation kinetics of HA- and HM-sorbed PHE showed that its initial degradation rate was negatively correlated with the aromatic carbon content of humic substances (p<0.05). This was attributed to the strong interactions between PHE and the aromatic components of humic substances, which hampered its release and subsequent biodegradation. The 720-h mineralized percentage of PHE was inversely correlated with the estimated thickness of the organic matter layer at the surfaces of HAs and HMs. Therefore, in a relatively long term, diffusion of PHE within the organic matter layer could be an important factor that may limit the bioavailability of PHE to bacteria. Results of the present study highlight the molecular-scaled mechanisms governing bioavailability of PHE sorbed on humic substances.

  16. Heavy metals uptake from contaminated soils as affected by peat, lime, and chelates

    SciTech Connect

    Albasel, N.; Cottenie, A.

    1985-01-01

    Heavy metal contamination of soils may reduce yields as well as the suitability for consumption of crop growth (Keeney et al., Leeper). In an effort to find possible ways to counter this danger, the effect of lime, chelating agents, and peat applied to Zn-, Cu- and Pb-contaminated soils on the uptake of metal ions were studied. Pot experiments with barley (Hordeum vulgare L.), perennial ryegrass (Lolium perenne) and Italian ryegrass (Lolium multiflorum) plants and soils, humic podzols (haplohumads) contaminated with Zn (3030 mg kg/sup -1/) and with Pb, Zn and Cu (110, 630, and 40 mg kg/sup -//sub 1/, respectively) were carried out. The concentration of the acid extracts of soils and plants were determined with the aid of the simultaneous direct reading spectrograph and atomic absorption. In all cases, raising the pH of the soil by liming appeared to be the most efficient method for reducing plant absorption of toxic micronutrients and heavy metals. However, the uptake of Fe and Mn was more markedly dependent on pH than that of Zn and Cu.

  17. Determinants of the exclusive breastfeeding abandonment: psychosocial factors.

    PubMed

    Machado, Mariana Campos Martins; Assis, Karine Franklin; Oliveira, Fabiana de Cássia Carvalho; Ribeiro, Andréia Queiroz; Araújo, Raquel Maria Amaral; Cury, Alexandre Faisal; Priore, Silvia Eloiza; Franceschini, Sylvia do Carmo Castro

    2014-12-01

    OBJECTIVE To assess the determinants of exclusive breastfeeding abandonment. METHODS Longitudinal study based on a birth cohort in Viçosa, MG, Southeastern Brazil. In 2011/2012, 168 new mothers accessing the public health network were followed. Three interviews, at 30, 60, and 120 days postpartum, with the new mothers were conducted. Exclusive breastfeeding abandonment was analyzed in the first, second, and fourth months after childbirth. The Edinburgh Postnatal Depression Scale was applied to identify depressive symptoms in the first and second meetings, with a score of ≥ 12 considered as the cutoff point. Socioeconomic, demographic, and obstetric variables were investigated, along with emotional conditions and the new mothers' social network during pregnancy and the postpartum period. RESULTS The prevalence of exclusive breastfeeding abandonment at 30, 60, and 120 days postpartum was 53.6% (n = 90), 47.6% (n = 80), and 69.6% (n = 117), respectively, and its incidence in the fourth month compared with the first was 48.7%. Depressive symptoms and traumatic delivery were associated with exclusive breastfeeding abandonment in the second month after childbirth. In the fourth month, the following variables were significant: lower maternal education levels, lack of homeownership, returning to work, not receiving guidance on breastfeeding in the postpartum period, mother's negative reaction to the news of pregnancy, and not receiving assistance from their partners for infant care. CONCLUSIONS Psychosocial and sociodemographic factors were strong predictors of early exclusive breastfeeding abandonment. Therefore, it is necessary to identify and provide early treatment to nursing mothers with depressive symptoms, decreasing the associated morbidity and promoting greater duration of exclusive breastfeeding. Support from health professionals, as well as that received at home and at work, can assist in this process.

  18. Determinants of the exclusive breastfeeding abandonment: psychosocial factors

    PubMed Central

    Machado, Mariana Campos Martins; Assis, Karine Franklin; Oliveira, Fabiana de Cássia Carvalho; Ribeiro, Andréia Queiroz; Araújo, Raquel Maria Amaral; Cury, Alexandre Faisal; Priore, Silvia Eloiza; Franceschini, Sylvia do Carmo Castro

    2014-01-01

    OBJECTIVE To assess the determinants of exclusive breastfeeding abandonment. METHODS Longitudinal study based on a birth cohort in Viçosa, MG, Southeastern Brazil. In 2011/2012, 168 new mothers accessing the public health network were followed. Three interviews, at 30, 60, and 120 days postpartum, with the new mothers were conducted. Exclusive breastfeeding abandonment was analyzed in the first, second, and fourth months after childbirth. The Edinburgh Postnatal Depression Scale was applied to identify depressive symptoms in the first and second meetings, with a score of ≥ 12 considered as the cutoff point. Socioeconomic, demographic, and obstetric variables were investigated, along with emotional conditions and the new mothers’ social network during pregnancy and the postpartum period. RESULTS The prevalence of exclusive breastfeeding abandonment at 30, 60, and 120 days postpartum was 53.6% (n = 90), 47.6% (n = 80), and 69.6% (n = 117), respectively, and its incidence in the fourth month compared with the first was 48.7%. Depressive symptoms and traumatic delivery were associated with exclusive breastfeeding abandonment in the second month after childbirth. In the fourth month, the following variables were significant: lower maternal education levels, lack of homeownership, returning to work, not receiving guidance on breastfeeding in the postpartum period, mother’s negative reaction to the news of pregnancy, and not receiving assistance from their partners for infant care. CONCLUSIONS Psychosocial and sociodemographic factors were strong predictors of early exclusive breastfeeding abandonment. Therefore, it is necessary to identify and provide early treatment to nursing mothers with depressive symptoms, decreasing the associated morbidity and promoting greater duration of exclusive breastfeeding. Support from health professionals, as well as that received at home and at work, can assist in this process. PMID:26039402

  19. 76 FR 51470 - CSX Transportation, Inc.-Abandonment Exemption-In Oswego County, NY

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-08-18

    ... Abandonments to abandon 2 formerly connected rail lines in CSXT's Northern Region, Albany Division, Fulton... Road 57, and the end of the track between Ontario and Erie Streets; and (2) 5,938 feet between...

  20. Changes in the physiological and agricultural characteristics of peat-based Bradyrhizobium japonicum inoculants after long-term storage.

    PubMed

    Revellin, C; Meunier, G; Giraud, J J; Sommer, G; Wadoux, P; Catroux, G

    2000-08-01

    Commercial soybean inoculants processed with sterilised peat and stored at 20 degrees C for 1-8 years were used as experimental materials to assess the changes in the physiological activity of Bradyrhizobium japonicum after storage. Viable counts decreased and physiological characteristics of the bacterium changed during storage, with an increase in the time taken for colony appearance on a medium without yeast extract, an increase in the lag time for nodule appearance on soybean grown in glass tubes and a decrease in survival on seeds. All the inoculants produced a significant increase in grain yield in a field experiment. The percentage of efficient cells in the field (relative to the plate counts) decreased as the length of storage increased. These results suggest that the physiological activity of B. japonicum cells changes after storage. Practical implications for inoculant quality control are discussed.

  1. Effects of Humic Acids Isolated from Peat of Various Origin on in Vitro Production of Nitric Oxide: a Screening Study.

    PubMed

    Trofimova, E S; Zykova, M V; Ligacheva, A A; Sherstoboev, E Yu; Zhdanov, V V; Belousov, M V; Yusubov, M S; Krivoshchekov, S V; Danilets, M G; Dygai, A M

    2016-09-01

    A screening study of biological activity of native humic acids isolated from peat was performed; several physical and chemical parameters of their structures were studied by UV- and infrared spectroscopy. Spectroscopy yielded similar shape of light absorption curves of humic acids of different origin, which can reflect similarity of general structural principles of these substances. Alkaline humic acids have more developed system of polyconjugation, while molecular structures of pyrophosphate humic acids were characterized by higher aromaticity and condensation indexes. Biological activity of the studied humic acids was assessed by NO-stimulating capacity during their culturing with murine peritoneal macrophages in a wide concentration range. It was shown that due to dose-dependent enhancement of NO production humic acids can change the functional state of macrophages towards development of pro-inflammatory properties. These changes were associated with high activity of humic acids isolated by pyrophosphate extraction, which allows considering effects of isolation method on biological activity.

  2. Fiscal year 1993 well plugging and abandonment program, Y-12 Plant, Oak Ridge, Tennessee

    SciTech Connect

    Not Available

    1993-09-01

    This report is a synopsis of the progress of the well plugging and abandonment program at the Y-12 Plant, Oak Ridge, Tennessee, from December 1992 through August 20, 1993. A total of 70 wells and borings were plugged and abandoned during the period of time covered in this report. All wells and borings were plugged and abandoned in accordance with the Monitoring Well Plugging and Abandonment Plan for the US Department of Energy, Y-12 Plant, Oak Ridge, Tennessee (HSW, Inc. 1991).

  3. Fiscal Year 1993 Well Plugging and Abandonment Program Summary Report Y-12 Plant, Oak Ridge, Tennessee

    SciTech Connect

    1994-09-01

    This report is a synopsis of the progress of the well plugging and abandonment program at the Y-12 Plant, Oak Ridge, Tennessee, from October 1993 through August 1994. A total of 57 wells and borings were plugged and abandoned during the period of time covered in this report. All wells and borings were plugged and abandoned in accordance with the Monitoring Well Plugging and Abandonment Plan for the U.S. Department of Energy, Y-12 Plant, Oak Ridge, Tennessee.

  4. Sketch maps, sections and laboratory analyses of peat resources in deposits in and near Piscataquis and Somerset counties and northeastern Aroostook County, Maine

    USGS Publications Warehouse

    Cameron, C.C.; Mullen, M.K.

    1982-01-01

    Peat deposits in and near Piscataquis and Somerset Counties and northeastern Aroostook County, Maine, were investigated for their estimated potential as peat resources suitable for energy, horticultural, and agricultural uses. Fifty sketch maps with sections and laboratory analyses illustrate the amount and quality of peat resources. The total yield of commercial quality peat is estimated at 23,670,000 short tons air-dried peat.

  5. 30 CFR 904.20 - Approval of Arkansas abandoned mine land reclamation plan.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 3 2010-07-01 2010-07-01 false Approval of Arkansas abandoned mine land... § 904.20 Approval of Arkansas abandoned mine land reclamation plan. The Secretary approved the Arkansas abandoned mine land reclamation plan, as submitted on July 7, 1982, effective May 2, 1983. Copies of...

  6. 30 CFR 904.25 - Approval of Arkansas abandoned mine land reclamation plan amendments.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 30 Mineral Resources 3 2014-07-01 2014-07-01 false Approval of Arkansas abandoned mine land... STATE ARKANSAS § 904.25 Approval of Arkansas abandoned mine land reclamation plan amendments. The...; Management accounting; and Abandoned mine land problem description. September 22, 1999 January 14,...

  7. 30 CFR 904.25 - Approval of Arkansas abandoned mine land reclamation plan amendments.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 3 2012-07-01 2012-07-01 false Approval of Arkansas abandoned mine land... STATE ARKANSAS § 904.25 Approval of Arkansas abandoned mine land reclamation plan amendments. The...; Management accounting; and Abandoned mine land problem description. September 22, 1999 January 14,...

  8. 30 CFR 904.20 - Approval of Arkansas abandoned mine land reclamation plan.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 30 Mineral Resources 3 2014-07-01 2014-07-01 false Approval of Arkansas abandoned mine land... § 904.20 Approval of Arkansas abandoned mine land reclamation plan. The Secretary approved the Arkansas abandoned mine land reclamation plan, as submitted on July 7, 1982, effective May 2, 1983. Copies of...

  9. 30 CFR 904.20 - Approval of Arkansas abandoned mine land reclamation plan.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 3 2013-07-01 2013-07-01 false Approval of Arkansas abandoned mine land... § 904.20 Approval of Arkansas abandoned mine land reclamation plan. The Secretary approved the Arkansas abandoned mine land reclamation plan, as submitted on July 7, 1982, effective May 2, 1983. Copies of...

  10. 30 CFR 904.25 - Approval of Arkansas abandoned mine land reclamation plan amendments.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 3 2010-07-01 2010-07-01 false Approval of Arkansas abandoned mine land... STATE ARKANSAS § 904.25 Approval of Arkansas abandoned mine land reclamation plan amendments. The...; Management accounting; and Abandoned mine land problem description. September 22, 1999 January 14,...

  11. 30 CFR 904.25 - Approval of Arkansas abandoned mine land reclamation plan amendments.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 3 2011-07-01 2011-07-01 false Approval of Arkansas abandoned mine land... STATE ARKANSAS § 904.25 Approval of Arkansas abandoned mine land reclamation plan amendments. The...; Management accounting; and Abandoned mine land problem description. September 22, 1999 January 14,...

  12. 30 CFR 904.20 - Approval of Arkansas abandoned mine land reclamation plan.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 3 2012-07-01 2012-07-01 false Approval of Arkansas abandoned mine land... § 904.20 Approval of Arkansas abandoned mine land reclamation plan. The Secretary approved the Arkansas abandoned mine land reclamation plan, as submitted on July 7, 1982, effective May 2, 1983. Copies of...

  13. 30 CFR 904.20 - Approval of Arkansas abandoned mine land reclamation plan.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 3 2011-07-01 2011-07-01 false Approval of Arkansas abandoned mine land... § 904.20 Approval of Arkansas abandoned mine land reclamation plan. The Secretary approved the Arkansas abandoned mine land reclamation plan, as submitted on July 7, 1982, effective May 2, 1983. Copies of...

  14. 30 CFR 904.25 - Approval of Arkansas abandoned mine land reclamation plan amendments.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 3 2013-07-01 2013-07-01 false Approval of Arkansas abandoned mine land... STATE ARKANSAS § 904.25 Approval of Arkansas abandoned mine land reclamation plan amendments. The...; Management accounting; and Abandoned mine land problem description. September 22, 1999 January 14,...

  15. 76 FR 12222 - Wisconsin Central, Ltd.-Abandonment Exemption-in Marathon County, WI

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-03-04

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF TRANSPORTATION Surface Transportation Board Wisconsin Central, Ltd.--Abandonment Exemption--in Marathon County, WI... ] Abandonments to abandon 1.14 miles of rail line between mileposts 17.50 and 18.64, in Weston, Marathon...

  16. 19 CFR 127.41 - Government title to unclaimed and abandoned merchandise.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 19 Customs Duties 1 2010-04-01 2010-04-01 false Government title to unclaimed and abandoned... and Abandoned Merchandise Vesting in Government § 127.41 Government title to unclaimed and abandoned merchandise. (a) Vesting of title in Government. At the end of the 6-month period noted in § 127.11 of...

  17. 46 CFR 185.520 - Abandon ship and man overboard drills and training.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 46 Shipping 7 2010-10-01 2010-10-01 false Abandon ship and man overboard drills and training. 185... overboard drills and training. (a) The master shall conduct sufficient drills and give sufficient... necessitate abandoning ship or the recovery of persons who have fallen overboard. (b) Each abandon ship...

  18. 30 CFR 931.20 - Approval of the New Mexico abandoned mine reclamation plan.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 3 2010-07-01 2010-07-01 false Approval of the New Mexico abandoned mine..., DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE NEW MEXICO § 931.20 Approval of the New Mexico abandoned mine reclamation plan. The New Mexico Abandoned...

  19. 30 CFR 935.20 - Approval of Ohio abandoned mine land reclamation plan.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 3 2011-07-01 2011-07-01 false Approval of Ohio abandoned mine land..., DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE OHIO § 935.20 Approval of Ohio abandoned mine land reclamation plan. The Ohio Abandoned Mine Land...

  20. 30 CFR 935.20 - Approval of Ohio abandoned mine land reclamation plan.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 3 2010-07-01 2010-07-01 false Approval of Ohio abandoned mine land..., DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE OHIO § 935.20 Approval of Ohio abandoned mine land reclamation plan. The Ohio Abandoned Mine Land...

  1. 46 CFR 131.530 - Abandon-ship training and drills.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 46 Shipping 4 2013-10-01 2013-10-01 false Abandon-ship training and drills. 131.530 Section 131... OPERATIONS Tests, Drills, and Inspections § 131.530 Abandon-ship training and drills. (a) Material for abandon-ship training must be aboard each vessel. The material must consist of a manual of one or...

  2. 46 CFR 131.530 - Abandon-ship training and drills.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 46 Shipping 4 2014-10-01 2014-10-01 false Abandon-ship training and drills. 131.530 Section 131... OPERATIONS Tests, Drills, and Inspections § 131.530 Abandon-ship training and drills. (a) Material for abandon-ship training must be aboard each vessel. The material must consist of a manual of one or...

  3. 46 CFR 131.530 - Abandon-ship training and drills.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 46 Shipping 4 2011-10-01 2011-10-01 false Abandon-ship training and drills. 131.530 Section 131... OPERATIONS Tests, Drills, and Inspections § 131.530 Abandon-ship training and drills. (a) Material for abandon-ship training must be aboard each vessel. The material must consist of a manual of one or...

  4. 46 CFR 131.530 - Abandon-ship training and drills.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 46 Shipping 4 2010-10-01 2010-10-01 false Abandon-ship training and drills. 131.530 Section 131... OPERATIONS Tests, Drills, and Inspections § 131.530 Abandon-ship training and drills. (a) Material for abandon-ship training must be aboard each vessel. The material must consist of a manual of one or...

  5. 46 CFR 131.530 - Abandon-ship training and drills.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 46 Shipping 4 2012-10-01 2012-10-01 false Abandon-ship training and drills. 131.530 Section 131... OPERATIONS Tests, Drills, and Inspections § 131.530 Abandon-ship training and drills. (a) Material for abandon-ship training must be aboard each vessel. The material must consist of a manual of one or...

  6. 19 CFR 158.42 - Abandonment by importer within 30 days after entry.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 19 Customs Duties 2 2012-04-01 2012-04-01 false Abandonment by importer within 30 days after entry... days after entry. Allowance in duties for merchandise abandoned to the Government in accordance with... which the merchandise being abandoned appears. (b) Application within 30 days. The importer shall...

  7. 19 CFR 158.42 - Abandonment by importer within 30 days after entry.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 19 Customs Duties 2 2010-04-01 2010-04-01 false Abandonment by importer within 30 days after entry... days after entry. Allowance in duties for merchandise abandoned to the Government in accordance with... which the merchandise being abandoned appears. (b) Application within 30 days. The importer shall...

  8. 19 CFR 158.42 - Abandonment by importer within 30 days after entry.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 19 Customs Duties 2 2014-04-01 2014-04-01 false Abandonment by importer within 30 days after entry... days after entry. Allowance in duties for merchandise abandoned to the Government in accordance with... which the merchandise being abandoned appears. (b) Application within 30 days. The importer shall...

  9. 25 CFR 226.28 - Shutdown, abandonment, and plugging of wells.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... OSAGE RESERVATION LANDS FOR OIL AND GAS MINING Cessation of Operations § 226.28 Shutdown, abandonment... 25 Indians 1 2010-04-01 2010-04-01 false Shutdown, abandonment, and plugging of wells. 226.28...) Prior to permanent abandonment of any well, the oil lessee or the gas lessee, as the case may be,...

  10. 30 CFR 931.20 - Approval of the New Mexico abandoned mine reclamation plan.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 30 Mineral Resources 3 2014-07-01 2014-07-01 false Approval of the New Mexico abandoned mine..., DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE NEW MEXICO § 931.20 Approval of the New Mexico abandoned mine reclamation plan. The New Mexico Abandoned...

  11. 30 CFR 931.20 - Approval of the New Mexico abandoned mine reclamation plan.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 3 2011-07-01 2011-07-01 false Approval of the New Mexico abandoned mine..., DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE NEW MEXICO § 931.20 Approval of the New Mexico abandoned mine reclamation plan. The New Mexico Abandoned...

  12. 30 CFR 931.20 - Approval of the New Mexico abandoned mine reclamation plan.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 3 2013-07-01 2013-07-01 false Approval of the New Mexico abandoned mine..., DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE NEW MEXICO § 931.20 Approval of the New Mexico abandoned mine reclamation plan. The New Mexico Abandoned...

  13. 30 CFR 931.20 - Approval of the New Mexico abandoned mine reclamation plan.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 3 2012-07-01 2012-07-01 false Approval of the New Mexico abandoned mine..., DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE NEW MEXICO § 931.20 Approval of the New Mexico abandoned mine reclamation plan. The New Mexico Abandoned...

  14. 30 CFR 924.20 - Approval of Mississippi abandoned mine land reclamation plans.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 3 2010-07-01 2010-07-01 false Approval of Mississippi abandoned mine land... STATE MISSISSIPPI § 924.20 Approval of Mississippi abandoned mine land reclamation plans. The Mississippi abandoned mine land reclamation plan as submitted on April 5, 2006, and June 11, 2007, and...

  15. 30 CFR 924.20 - Approval of Mississippi abandoned mine land reclamation plans.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 30 Mineral Resources 3 2014-07-01 2014-07-01 false Approval of Mississippi abandoned mine land... STATE MISSISSIPPI § 924.20 Approval of Mississippi abandoned mine land reclamation plans. The Mississippi abandoned mine land reclamation plan as submitted on April 5, 2006, and June 11, 2007, and...

  16. 30 CFR 924.20 - Approval of Mississippi abandoned mine land reclamation plans.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 3 2012-07-01 2012-07-01 false Approval of Mississippi abandoned mine land... STATE MISSISSIPPI § 924.20 Approval of Mississippi abandoned mine land reclamation plans. The Mississippi abandoned mine land reclamation plan as submitted on April 5, 2006, and June 11, 2007, and...

  17. 30 CFR 924.20 - Approval of Mississippi abandoned mine land reclamation plans.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 3 2013-07-01 2013-07-01 false Approval of Mississippi abandoned mine land... STATE MISSISSIPPI § 924.20 Approval of Mississippi abandoned mine land reclamation plans. The Mississippi abandoned mine land reclamation plan as submitted on April 5, 2006, and June 11, 2007, and...

  18. 30 CFR 924.20 - Approval of Mississippi abandoned mine land reclamation plans.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 3 2011-07-01 2011-07-01 false Approval of Mississippi abandoned mine land... STATE MISSISSIPPI § 924.20 Approval of Mississippi abandoned mine land reclamation plans. The Mississippi abandoned mine land reclamation plan as submitted on April 5, 2006, and June 11, 2007, and...

  19. Biodestructive processes occurring in the organic matter of lowland peat in the arctic zone

    NASA Astrophysics Data System (ADS)

    Svarovskaya, L. I.; Altunina, L. K.; Serebrennikova, O. V.

    2016-11-01

    A model experiment was carried on in laboratory conditions. The biodestruction of organic matter was studied using lowland peat samples collected in Kolguev Island in Barents Sea. Here the purpose was to obtain information about the species range and the activity of bacterial complex involved in the destruction processes of lowland peat organic matter from the natural environment by simulating the Arctic zone climate. The species range is found to include bacteria dominant species, i.e. Rhodococcus, Arthrobacter, Bacillus and Pseudomonas. In order to stimulate the biodestruction of organic matter, inoculate was added to the culture medium containing peat; its composition and dose were determined by the trial-and-error method. The catalytic activity of bacterial ferments was initiated in the presence of inoculate; hence, the desired effect was achieved. The composition of the organic matter of bacterial biomass and peat was analyzed by the method of gas chromatography-mass spectrometry.

  20. Peat soil organic matter composition depth profiles - is the diplotelmic model real?

    NASA Astrophysics Data System (ADS)

    Boothroyd, Ian; Clay, Gareth; Moody, Catherine; Archer, Elaine; Dixon, Simon; Worrall, Fred

    2016-04-01

    Measures of bulk density and organic matter composition provide important insights into peat formation, degradation and hydrology as well as carbon and nutrient cycles, and indeed underpin the diplotelmic model of peat formation. This study presents soil core data from 23 upland and lowland peat sites across the United Kingdom. A series of soil cores up to ~3m depth were analysed for bulk density, gross heat value (energy content) and carbon, hydrogen, nitrogen and oxygen composition. Atomic ratios of C/N, H/C and O/C were used as indicators of the origin and quality of soil organic matter. Results show no consistent soil depth profiles evident across multiple sites, this challenges whether historical interpretations of peat soil formation and structure are appropriate.