Langmuir probe measurements and mass spectrometry of plasma plumes generated by laser ablation of La0.4Ca0.6MnO3

NASA Astrophysics Data System (ADS)

Chen, Jikun; Lunney, James G.; Lippert, Thomas; Ojeda-G-P, Alejandro; Stender, Dieter; Schneider, Christof W.; Wokaun, Alexander

2014-08-01

The plasma formed in vacuum by UV nanosecond laser ablation of La0.4Ca0.6MnO3 in the fluence range of 0.8 to 1.9 J cm-2 using both Langmuir probe analysis and energy-resolved mass spectrometry has been studied. Mass spectrometry shows that the main positive ion species are Ca+, Mn+, La+, and LaO+. The Ca+ and Mn+ energy distributions are quite broad and lie in the 0-100 eV region, with the average energies increasing with laser fluence. In contrast, the La+ and LaO+ distributions are strongly peaked around 10 eV. The net time-of-arrival signal derived from the measured positive ion energy distributions is broadly consistent with the positive ion signal measured by the Langmuir probe. We also detected a significant number of O- ions with energies in the range of 0 to 10 eV. The Langmuir probe was also used to measure the temporal variation of the electron density and temperature at 6 cm from the ablation target. In the period when O- ions are found at this position, the plasma conditions are consistent with those required for significant negative oxygen ion formation, as revealed by studies on radio frequency excited oxygen plasma.

Laser ablated copper plasmas in liquid and gas ambient

NASA Astrophysics Data System (ADS)

Kumar, Bhupesh; Thareja, Raj K.

2013-05-01

The dynamics of copper ablated plasma plumes generated using laser ablation of copper targets in both liquid (de-ionized water) and gas (air) ambients is reported. Using time and space resolved visible emission spectroscopy (450-650 nm), the plasma plumes parameters are investigated. The electron density (ne) determined using Stark broadening of the Cu I (3d104d1 2D3/2-3d104p1 2P3/2 at 521.8 nm) line is estimated and compared for both plasma plumes. The electron temperature (Te) was estimated using the relative line emission intensities of the neutral copper transitions. Field emission scanning electron microscopy and energy dispersive x-ray spectral analysis of the ablated copper surface indicated abundance of spherical nanoparticles in liquid while those in air are amalgamates of irregular shapes. The nanoparticles suspended in the confining liquid form aggregates and exhibit a surface plasmon resonance at ˜590 nm.

Plasma plume MHD power generator and method

DOEpatents

Hammer, J.H.

1993-08-10

A method is described of generating power at a situs exposed to the solar wind which comprises creating at separate sources at the situs discrete plasma plumes extending in opposed directions, providing electrical communication between the plumes at their source and interposing a desired electrical load in the said electrical communication between the plumes.

Plasma plume expansion dynamics in nanosecond Nd:YAG laserosteotome

NASA Astrophysics Data System (ADS)

Abbasi, Hamed; Rauter, Georg; Guzman, Raphael; Cattin, Philippe C.; Zam, Azhar

2018-02-01

In minimal invasive laser osteotomy precise information about the ablation process can be obtained with LIBS in order to avoid carbonization, or cutting of wrong types of tissue. Therefore, the collecting fiber for LIBS needs to be optimally placed in narrow cavities in the endoscope. To determine this optimal placement, the plasma plume expansion dynamics in ablation of bone tissue by the second harmonic of a nanosecond Nd:YAG laser at 532 nm has been studied. The laserinduced plasma plume was monitored in different time delays, from one nanosecond up to one hundred microseconds. Measurements were performed using high-speed gated illumination imaging. The expansion features were studied using illumination of the overall visible emission by using a gated intensified charged coupled device (ICCD). The camera was capable of having a minimum gate width (Optical FWHM) of 3 ns and the timing resolution (minimum temporal shift of the gate) of 10 ps. The imaging data were used to generate position-time data of the luminous plasma-front. Moreover, the velocity of the plasma plume expansion was studied based on the time-resolved intensity data. By knowing the plasma plume profile over time, the optimum position (axial distance from the laser spot) of the collecting fiber and optimal time delay (to have the best signal to noise ratio) in spatial-resolved and time-resolved laser-induced breakdown spectroscopy (LIBS) can be determined. Additionally, the function of plasma plume expansion could be used to study the shock wave of the plasma plume.

Time resolved optical diagnostics of ZnO plasma plumes in air

SciTech Connect

Gupta, Shyam L.; Singh, Ravi Pratap; Thareja, Raj K.

2013-10-15

We report dynamical evolution of laser ablated ZnO plasma plumes using interferometry and shadowgraphy; 2-D fast imaging and optical emission spectroscopy in air ambient at atmospheric pressure. Recorded interferograms using Nomarski interferometer and shadowgram images at various time delays show the presence of electrons and neutrals in the ablated plumes. The inference drawn from sign change of fringe shifts is consistent with two dimensional images of the plume and optical emission spectra at varying time delays with respect to ablating pulse. Zinc oxide plasma plumes are created by focusing 1.06 μm radiation on to ZnO target in air and 532more » nm is used as probe beam.« less

Plume dynamics from UV pulsed ablation of Al and Ti

NASA Astrophysics Data System (ADS)

Bauer, William; Perram, Glen; Haugan, Timothy

2016-12-01

Pulsed laser ablation of Al and Ti with a < 3.3 J/cm2 KrF laser and Ar background pressure of up to 1 Torr was performed to study the ablated plume. Mass loss experiments revealed the number of ablated atoms per pulse increases by 30% for Ti and 20% for Al as pressure decreases from 1 Torr to vacuum. Optical emission imaging performed using a gated ICCD revealed a strong dependence of shock front parameters, defined by the Sedov-Taylor blast and classical drag models, on background pressure. Spatially resolved optical emission spectroscopy from Al I, Al II, Ti I, and Ti II revealed ion temperatures of 104 K that decreased away from the target surface along the surface normal and neutral temperatures of 103 K independent of target distance. Comparison between kinetic energy in the shock and internal excitation energy reveals that nearly 100% of the energy is partitioned into shock front kinetic energy and 1% into internal excitation.

Kinetic electron model for plasma thruster plumes

NASA Astrophysics Data System (ADS)

Merino, Mario; Mauriño, Javier; Ahedo, Eduardo

2018-03-01

A paraxial model of an unmagnetized, collisionless plasma plume expanding into vacuum is presented. Electrons are treated kinetically, relying on the adiabatic invariance of their radial action integral for the integration of Vlasov's equation, whereas ions are treated as a cold species. The quasi-2D plasma density, self-consistent electric potential, and electron pressure, temperature, and heat fluxes are analyzed. In particular, the model yields the collisionless cooling of electrons, which differs from the Boltzmann relation and the simple polytropic laws usually employed in fluid and hybrid PIC/fluid plume codes.

Stationary Plasma Thruster Plume Emissions

NASA Technical Reports Server (NTRS)

Manzella, David H.

1994-01-01

The emission spectrum from a xenon plasma produced by a Stationary Plasma Thruster provided by the Ballistic Missile Defense Organization (BMDO) was measured. Approximately 270 individual Xe I, Xe II, and XE III transitions were identified. A total of 250 mW of radiated optical emission was estimated from measurements taken at the thruster exit plane. There was no evidence of erosion products in the emission signature. Ingestion and ionization of background gas at elevated background pressure was detected. The distribution of excited states could be described by temperatures ranging from fractions of 1 eV to 4 eV with a high degree of uncertainty due to the nonequilibrium nature of this plasma. The plasma was over 95 percent ionized at the thruster exit plane. Between 10 and 20 percent of the ions were doubly charged. Two modes of operation were identified. The intensity of plasma emission increased by a factor of two during operation in an oscillatory mode. The transfer between the two modes of operation was likely related to unidentified phenomena occurring on a time scale of minutes.

High Current Hollow Cathode Plasma Plume Measurements

NASA Technical Reports Server (NTRS)

Thomas, Robert E.; Kamhawi, Hani; Williams, George J., Jr.

2014-01-01

Plasma plume measurements are reported for a hollow cathode assembly (HCA) operated at discharge currents of 50, 70, and 100 A at xenon flow rates between 19 - 46 standard cubic centimeter per minute. The HCA was centrally mounted in the NASA-300MS Hall Thruster and was operated in the "spot" and "plume" modes with additional data taken with an applied magnetic field. Langmuir probes, retarding potential analyzers, and optical emission spectroscopy were employed to measure plasma properties near the orifice of the HCA and to assess the charge state of the near-field plasma. Electron temperatures (2-6 electron volt) and plasma potentials are consistent with probe-measured values in previous investigations. Operation with an applied-field yields higher discharge voltages, increased Xe III production, and increased signals from the 833.5 nm C I line. While operating in plume mode and with an applied field, ion energy distribution measurements yield ions with energies significantly exceeding the applied discharge voltage. These findings are correlated with high-frequency oscillations associated with each mode.

Ablation plume structure and dynamics in ambient gas observed by laser-induced fluorescence imaging spectroscopy

NASA Astrophysics Data System (ADS)

Miyabe, M.; Oba, M.; Iimura, H.; Akaoka, K.; Khumaeni, A.; Kato, M.; Wakaida, I.

2015-08-01

The dynamic behavior of an ablation plume in ambient gas has been investigated by laser-induced fluorescence imaging spectroscopy. The second harmonic beam from an Nd:YAG laser (0.5-6 J/cm2) was focused on a sintered oxide pellet or a metal chip of gadolinium. The produced plume was subsequently intersected with a sheet-shaped UV beam from a dye laser so that time-resolved fluorescence images were acquired with an intensified CCD camera at various delay times. The obtained cross-sectional images of the plume indicate that the ablated ground state atoms and ions of gadolinium accumulate in a hemispherical contact layer between the plume and the ambient gas, and a cavity containing a smaller density of ablated species is formed near the center of the plume. At earlier expansion stage, another luminous component also expands in the cavity so that it coalesces into the hemispherical layer. The splitting and coalescence for atomic plume occur later than those for ionic plume. Furthermore, the hemispherical layer of neutral atoms appears later than that of ions; however, the locations of the layers are nearly identical. This coincidence of the appearance locations of the layers strongly suggests that the neutral atoms in the hemispherical layer are produced as a consequence of three-body recombination of ions through collisions with gas atoms. The obtained knowledge regarding plume expansion dynamics and detailed plume structure is useful for optimizing the experimental conditions for ablation-based spectroscopic analysis.

Higher Order Chemistry Models in the CFD Simulation of Laser-Ablated Carbon Plumes

NASA Technical Reports Server (NTRS)

Greendyke, R. B.; Creel, J. R.; Payne, B. T.; Scott, C. D.

2005-01-01

Production of single-walled carbon nanotubes (SWNT) has taken place for a number of years and by a variety of methods such as laser ablation, chemical vapor deposition, and arc-jet ablation. Yet, little is actually understood about the exact chemical kinetics and processes that occur in SWNT formation. In recent time, NASA Johnson Space Center has devoted a considerable effort to the experimental evaluation of the laser ablation production process for SWNT originally developed at Rice University. To fully understand the nature of the laser ablation process it is necessary to understand the development of the carbon plume dynamics within the laser ablation oven. The present work is a continuation of previous studies into the efforts to model plume dynamics using computational fluid dynamics (CFD). The ultimate goal of the work is to improve understanding of the laser ablation process, and through that improved understanding, refine the laser ablation production of SWNT.

Comparison of plume dynamics for laser ablated metals: Al and Ti

NASA Astrophysics Data System (ADS)

Bauer, William; Perram, Glen P.; Haugan, Timothy

2018-03-01

Emissive plumes from pulsed laser ablation of bulk Ti and Al from KrF laser irradiation at laser fluence up to 3.5 J/cm2 and argon background pressures of 0-1 Torr have been observed using gated intensified charged-coupled device imagery. Mass loss for Ti increases from 0.1 to 0.8 μg/pulse as pulse energy increase from 174 to 282 mJ/pulse (35-170 photons/atom) and decreases by ˜30% as pressure increases from vacuum to 1 Torr. Early plume energies are described by the free expansion velocities of 1.57 ± 0.02 and of 1.81 ± 0.07 cm/μs for Ti and Al, respectively, and up to 90% of the incoming laser energy can be attributed to the Al shock front in the mid-field. The ablation thresholds of 90 ± 27 mJ (1.12 ± 0.34 J/cm2) for Ti and 126 ± 13 mJ (1.58 ± 0.16 J/cm2) for Al also represent 30%-70% of the incident laser energy. The decrease in mass loss at higher pressures is attributed to plasma shielding of the target surface.

High Current Hollow Cathode Plasma Plume Measurements

NASA Technical Reports Server (NTRS)

Thomas, Robert E.; Kamhawi, Hani; Williams, George J., Jr.

2013-01-01

Plasma plume measurements are reported for a hollow cathode assembly (HCA) oper-ated at discharge currents of 50, 70, and 100 A at xenon ow rates between 19 - 46 sccm.The HCA was centrally mounted in the annulus of the NASA-300MS Hall Thruster andwas operated in the spot and plume modes with additional data taken with an appliedmagnetic eld. Langmuir probes, retarding potential analyzers, and optical emission spec-troscopy were employed to measure plasma properties near the orice of the HCA and toassess the charge state of the near-eld plasma. Electron temperatures (2-6 eV) and plasmapotentials are consistent with probe-measured values in previous investigations. Operationwith an applied-eld yields higher discharge voltages, increased Xe III production, andincreased signals from the 833.5 nm C I line. While operating in plume mode and with anapplied eld, ion energy distribution measurements yield ions with energies signicantlyexceeding the applied discharge voltage. These ndings are correlated with high-frequencyoscillations associated with each mode.

Effect of defocusing on laser ablation plume observed by laser-induced fluorescence imaging spectroscopy

NASA Astrophysics Data System (ADS)

Oba, Masaki; Miyabe, Masabumi; Akaoka, Katsuaki; Wakaida, Ikuo

2016-02-01

We used laser-induced fluorescence imaging with a varying beam focal point to observe ablation plumes from metal and oxide samples of gadolinium. The plumes expand vertically when the focal point is far from the sample surface. In contrast, the plume becomes hemispherical when the focal point is on the sample surface. In addition, the internal plume structure and the composition of the ablated atomic and ionic particles also vary significantly. The fluorescence intensity of a plume from a metal sample is greater than that from an oxide sample, which suggests that the number of monatomic species produced in each plume differs. For both the metal and oxide samples, the most intense fluorescence from atomic (ionic) species is observed with the beam focal point at 3-4 mm (2 mm) from the sample surface.

Laser Ablation Molecular Isotopic Spectrometry for Molecules Formation Chemistry in Femtosecond-Laser Ablated Plasmas.

PubMed

Hou, Huaming; Mao, Xianglei; Zorba, Vassilia; Russo, Richard E

2017-07-18

Recently, laser ablated molecular isotopic spectrometry (LAMIS) has expanded its capability to explore molecules formation mechanism in laser-induced plasma in addition to isotope analysis. LAMIS is a powerful tool for tracking the origination of atoms that is involved in formation of investigated molecules by labeling atoms with their isotopic substitution. The evolutionary formation pathways of organic molecules, especially of C 2 dimers and CN radicals, were frequently reported. However, very little is known about the formation pathways for metallic radicals and heterodimers in laser ablated plasma. This research focuses on elucidating the formation pathways of AlO radicals in femtosecond laser ablated plasma from 18 O-labeled Al 2 O 3 pellet. Plasmas expanding with strong forward bias in the direction normal to the sample surface were generated in the wake of a weakly ionized channel created by a femtosecond laser. The formation mechanism of AlO and influence of air were investigated with multiple plasma diagnostic methods such as monochromatic fast gating imaging, spatiotemporal resolved optical emission spectroscopy, and LAMIS. An advanced LAMIS fitting procedure was used to deduce the spatiotemporal distributions of Al 18 O and Al 16 O number densities and also their ratios. We found that the Al 16 O/Al 18 O number density ratio is higher for plasma portion closer to the sample surface, which suggests that chemical reactions between the plasma plume and ambient air are more intense at the tail of the plasma. The results also reveals that direct association of free Al and O atoms is the main mechanism for the formation of AlO at the early stage of the plasma. To the contrast, chemical reactions between plasma materials and ambient oxygen molecules and the isotope exchange effect are the dominant mechanisms of the formation of AlO and evolution of Al 16 O/Al 18 O number density ratio at the late stage of the plasma.

Tracing the plasma interactions for pulsed reactive crossed-beam laser ablation

NASA Astrophysics Data System (ADS)

Chen, Jikun; Stender, Dieter; Pichler, Markus; Döbeli, Max; Pergolesi, Daniele; Schneider, Christof W.; Wokaun, Alexander; Lippert, Thomas

2015-10-01

Pulsed reactive crossed-beam laser ablation is an effective technique to govern the chemical activity of plasma species and background molecules during pulsed laser deposition. Instead of using a constant background pressure, a gas pulse with a reactive gas, synchronized with the laser beam, is injected into vacuum or a low background pressure near the ablated area of the target. It intercepts the initially generated plasma plume, thereby enhancing the physicochemical interactions between the gaseous environment and the plasma species. For this study, kinetic energy resolved mass-spectrometry and time-resolved plasma imaging were used to study the physicochemical processes occurring during the reactive crossed beam laser ablation of a partially 18O substituted La0.6Sr0.4MnO3 target using oxygen as gas pulse. The characteristics of the ablated plasma are compared with those observed during pulsed laser deposition in different oxygen background pressures.

Influence of the ablation plume on the removal process during ArF-excimer laser photoablation

NASA Astrophysics Data System (ADS)

Doerbecker, Christina; Lubatschowski, Holger; Lohmann, Stefan; Ruff, Christine; Kermani, Omid; Ertmer, Wolfgang

1996-01-01

Correction of myopia with the ArF-excimer laser (PRK) sometimes leads to a so called 'central island' formation on the anterior corneal surface. The attenuation of the laser beam by the ablation plume might be one reason for this phenomenon. The attenuation properties of the ablation plume were investigated by a probe beam parallel to the surface of the tissue probe. By varying the laser parameters (fluence, repetition rate, spot size) and the target tissue (cornea, PMMA) the attenuation of the probe beam was measured time and spatial resolved. As a result of this study, a significant influence of the removal process due to scattering and absorption within the ablation plume can be assumed as a function of repetition rate, spot size and air flow on the tissue surface.

Spectroscopic measurements of plasma plume induced during the laser deposition of the hydroxyapatite

NASA Astrophysics Data System (ADS)

Jedyński, M.; Szymański, Z.; Mróz, W.; Prokopiuk, A.; Jelinek, M.; Kocourek, T.

2004-03-01

Plasma plume induced by ArF exeimer laser ablation of a Ca10(PO4)6(OH)2 hydroxyapatite target during deposition process has been studied in different ambient conditions, i.e. in air or water vapour. ArF laser operated at the wavelength of 193 nm with the pulse energy of 300 mJ and 20 ns pulse duration. Spectroscopic measurements of the emission spectra of plasma plume have been made with the use of a fast gate, lens coupled micro-channel plate (MCP) image intensifier placed between a spectrograph and a 1254 silicon intensified target (SIT) detector connected to an optical multichannel analyser. The electron densities of 1022 ÷ 1023m-3 have been determined from the Stark broadening of Ca I lines as a function of the distance from the target. The expansion of the plasma plume has been studied using the time of flight method. The time-dependent radiation of the 422.673 nm Ca I and 393.366 nm Ca II lines has been, registered with the use of a monochromator and photomultiplier at various distances from the target. Velocities between 104 ÷ 103 m/s have been found. The velocity in air is several times higher than in the case with water vapour. The plasma plume dynamics is also different in both cases. In the presence of water vapour the spliting of the plasma plume appears.

Two-dimensional fluorescence spectroscopy of uranium isotopes in femtosecond laser ablation plumes

DOE PAGES

Phillips, Mark C.; Brumfield, Brian E.; LaHaye, Nicole; ...

2017-06-19

Here, we demonstrate measurement of uranium isotopes in femtosecond laser ablation plumes using two-dimensional fluorescence spectroscopy (2DFS). The high-resolution, tunable CW-laser spectroscopy technique clearly distinguishes atomic absorption from 235U and 238U in natural and highly enriched uranium metal samples. We present analysis of spectral resolution and analytical performance of 2DFS as a function of ambient pressure. Simultaneous measurement using time-resolved absorption spectroscopy provides information on temporal dynamics of the laser ablation plume and saturation behavior of fluorescence signals. The rapid, non-contact measurement is promising for in-field, standoff measurements of uranium enrichment for nuclear safety and security.

Two-dimensional fluorescence spectroscopy of uranium isotopes in femtosecond laser ablation plumes

SciTech Connect

Phillips, Mark C.; Brumfield, Brian E.; LaHaye, Nicole

Here, we demonstrate measurement of uranium isotopes in femtosecond laser ablation plumes using two-dimensional fluorescence spectroscopy (2DFS). The high-resolution, tunable CW-laser spectroscopy technique clearly distinguishes atomic absorption from 235U and 238U in natural and highly enriched uranium metal samples. We present analysis of spectral resolution and analytical performance of 2DFS as a function of ambient pressure. Simultaneous measurement using time-resolved absorption spectroscopy provides information on temporal dynamics of the laser ablation plume and saturation behavior of fluorescence signals. The rapid, non-contact measurement is promising for in-field, standoff measurements of uranium enrichment for nuclear safety and security.

Two-dimensional fluorescence spectroscopy of uranium isotopes in femtosecond laser ablation plumes

SciTech Connect

Phillips, Mark C.; Brumfield, Brian E.; LaHaye, Nicole L.

We demonstrate measurement of uranium isotopes in femtosecond laser ablation plumes using two-dimensional fluorescence spectroscopy (2DFS). The high-resolution, tunable CW-laser spectroscopy technique clearly distinguishes atomic absorption from 235U and 238U in natural and highly enriched uranium metal samples. We present analysis of spectral resolution and analytical performance of 2DFS as a function of ambient pressure. Simultaneous measurement using time-resolved absorption spectroscopy provides information on temporal dynamics of the laser ablation plume and saturation behavior of fluorescence signals. The rapid, non-contact measurement is promising for in-field, standoff measurements of uranium enrichment for nuclear safety and security applications.

A tandem mirror plasma source for hybrid plume plasma studies

NASA Technical Reports Server (NTRS)

Yang, T. F.; Chang, F. R.; Miller, R. H.; Wenzel, K. W.; Krueger, W. A.

1985-01-01

A tandem mirror device to be considered as a hot plasma source for the hybrid plume rocket concept is discussed. The hot plamsa from this device is injected into an exhaust duct, which will interact with an annular hypersonic layer of neutral gas. The device can be used to study the dynamics of the hybrid plume, and to verify the numerical predictions obtained with computer codes. The basic system design is also geared towards low weight and compactness, and high power density at the exhaust. The basic structure of the device consists of four major subsystems: (1) an electric power supply; (2) a low temperature, high density plasma gun, such as a stream gun, an MPD source or gas cell; (3) a power booster in the form of a tandem mirror machine; and (4) an exhaust nozzle arrangement. The configuration of the tandem mirror section is shown.

Impact of oxygen chemistry on the emission and fluorescence spectroscopy of laser ablation plumes

NASA Astrophysics Data System (ADS)

Hartig, K. C.; Brumfield, B. E.; Phillips, M. C.; Harilal, S. S.

2017-09-01

Oxygen present in the ambient gas medium may affect both laser-induced breakdown spectroscopy (LIBS) and laser-induced fluorescence (LIF) emission through a reduction of emission intensity and persistence. In this study, an evaluation is made on the role of oxygen in the ambient environment under atmospheric pressure conditions in LIBS and laser ablation (LA)-LIF emission. To generate plasmas, 1064 nm, 10 ns pulses were focused on an aluminum alloy sample. LIF was performed by frequency scanning a CW laser over the 396.15 nm (3s24s 2S1/2 → 3s23p 2P°3/2) Al I transition. Time-resolved emission and fluorescence signals were recorded to evaluate the variation in emission intensity caused by the presence of oxygen. The oxygen partial pressure (po) in the atmospheric pressure environment using N2 as the makeup gas was varied from 0 to 400 Torr O2. 2D-fluorescence spectroscopy images were obtained for various oxygen concentrations for simultaneous evaluation of the emission and excitation spectral features. Results showed that the presence of oxygen in the ambient environment reduces the persistence of the LIBS and LIF emission through an oxidation process that depletes the density of atomic species within the resulting laser-produced plasma (LPP) plume.

Waves generated in the plasma plume of helicon magnetic nozzle

SciTech Connect

Singh, Nagendra; Rao, Sathyanarayan; Ranganath, Praveen

2013-03-15

Experimental measurements have shown that the plasma plume created in a helicon plasma device contains a conical structure in the plasma density and a U-shaped double layer (US-DL) tightly confined near the throat where plasma begins to expand from the source. Recently reported two-dimensional particle-in-cell simulations verified these density and US-DL features of the plasma plume. Simulations also showed that the plasma in the plume develops non-thermal feature consisting of radial ion beams with large densities near the conical surface of the density structure. The plasma waves that are generated by the radial ion beams affecting the structure of themore » plasma plume are studied here. We find that most intense waves persist in the high-density regions of the conical density structure, where the transversely accelerated ions in the radial electric fields in the plume are reflected setting up counter-streaming. The waves generated are primarily ion Bernstein modes. The nonlinear evolution of the waves leads to magnetic field-aligned striations in the fields and the plasma near the conical surface of the density structure.« less

Toward single-cell analysis by plume collimation in laser ablation electrospray ionization mass spectrometry.

PubMed

Stolee, Jessica A; Vertes, Akos

2013-04-02

Ambient ionization methods for mass spectrometry have enabled the in situ and in vivo analysis of biological tissues and cells. When an etched optical fiber is used to deliver laser energy to a sample in laser ablation electrospray ionization (LAESI) mass spectrometry, the analysis of large single cells becomes possible. However, because in this arrangement the ablation plume expands in three dimensions, only a small portion of it is ionized by the electrospray. Here we show that sample ablation within a capillary helps to confine the radial expansion of the plume. Plume collimation, due to the altered expansion dynamics, leads to greater interaction with the electrospray plume resulting in increased ionization efficiency, reduced limit of detection (by a factor of ~13, reaching 600 amol for verapamil), and extended dynamic range (6 orders of magnitude) compared to conventional LAESI. This enhanced sensitivity enables the analysis of a range of metabolites from small cell populations and single cells in the ambient environment. This technique has the potential to be integrated with flow cytometry for high-throughput metabolite analysis of sorted cells.

Laser beam-plasma plume interaction during laser welding

NASA Astrophysics Data System (ADS)

Hoffman, Jacek; Moscicki, Tomasz; Szymanski, Zygmunt

2003-10-01

Laser welding process is unstable because the keyhole wall performs oscillations which results in the oscillations of plasma plume over the keyhole mouth. The characteristic frequencies are equal to 0.5-4 kHz. Since plasma plume absorbs and refracts laser radiation, plasma oscillations modulate the laser beam before it reaches the workpiece. In this work temporary electron densities and temperatures are determined in the peaks of plasma bursts during welding with a continuous wave CO2 laser. It has been found that during strong bursts the plasma plume over the keyhole consists of metal vapour only, being not diluted by the shielding gas. As expected the values of electron density are about two times higher in peaks than their time-averaged values. Since the plasma absorption coefficient scales as ~N2e/T3/2 (for CO2 laser radiation) the results show that the power of the laser beam reaching the metal surface is modulated by the plasma plume oscillations. The attenuation factor equals 4-6% of the laser power but it is expected that it is doubled by the refraction effect. The results, together with the analysis of the colour pictures from streak camera, allow also interpretation of the dynamics of the plasma plume.

Higher Order Chemistry Models in the CFD Simulation of Laser-Ablated Carbon Plumes

NASA Technical Reports Server (NTRS)

Scott, C. D.; Greendyke, R. B.; Creel, J. R.; Payne, B. T.

2005-01-01

Production of single-walled carbon nanotubes (SWNT) has taken place for a number of years and by a variety of methods such-as laser ablation, chemical vapor deposition, and arc-jet ablation. Yet, little is actually understood about the exact chemical kinetics and processes that occur in SWNT formation. In recent time, NASA Johnson Space Center has devoted a considerable effort to the experimental evaluation of the laser ablation production process for SWNT originally developed at Rice University. To fully understand the nature of the laser ablation process it is necessary to understand the development of the carbon plume dynamics within the laser ablation oven. The present work is a continuation of previous studies into the efforts to model plume dynamics using computational fluid dynamics (CFD). The ultimate goal of the work is to improve understanding of the laser ablation process, and through that improved understanding, refine the laser ablation production of SWNT. Fig. 1 shows a basic schematic of the laser-ablation oven at NASA-JSC. Construction of the facility is simple in concept. Two concentric quartz tubes of 1.5 mm thickness form the inner and outer tubes with inside diameters of 2.2 and 5.08 cm respectively. At one end of the inner tube are located two 60 Hz pulsed lasers operating at 1064 nm and 532 nm wavelength with beam diameters of 5 mm aligned coaxially with the longitudinal axis of the inner quartz tube. For standard nanotube production runs, a 10 ns 532 nm pulse is followed 50 ns later by a 10 ns 1064 nm pulse. Each pulse is of 300 mJ energy. A target of carbon graphite with approximately 1% nickel and cobalt catalysts is located at the other end of the inner quartz tube. In the ordinary processing of SWNT, a base flow of 100 sccm of argon is maintained from the laser location and exits past the carbon target at a pressure of 66.7 kPa. These conditions yield a baseline mass flow through the chamber of 2.723x10(exp -6)kg/s of argon. The whole

Experimental measurement of ablation effects in plasma armature railguns

SciTech Connect

Parker, J.V.; Parsons, W.M.

1986-01-01

Experimental evidence supporting the importance of ablation in plasma armature railguns is presented. Experiments conducted using the HYVAX and MIDI-2 railguns are described. Several indirect effects of ablation are identified from the experimental results. An improved ablation model of plasma armature dynamics is proposed which incorporates the restrike process.

Experimental measurement of ablation effects in plasma armature railguns

SciTech Connect

Parker, J.V.; Parsons, W.M.

1986-11-01

Experimental evidence supporting the importance of ablation in plasma armature railguns is presented. Experiments conducted using the HYVAX and MIDI-2 railguns are described. Several indirect effects of ablation are identified from the experimental results. An improved ablation model of plasma armature dynamics is proposed which incorporates the restrike process.

Modeling of Heat Transfer and Ablation of Refractory Material Due to Rocket Plume Impingement

NASA Technical Reports Server (NTRS)

Harris, Michael F.; Vu, Bruce T.

2012-01-01

CR Tech's Thermal Desktop-SINDA/FLUINT software was used in the thermal analysis of a flame deflector design for Launch Complex 39B at Kennedy Space Center, Florida. The analysis of the flame deflector takes into account heat transfer due to plume impingement from expected vehicles to be launched at KSC. The heat flux from the plume was computed using computational fluid dynamics provided by Ames Research Center in Moffet Field, California. The results from the CFD solutions were mapped onto a 3-D Thermal Desktop model of the flame deflector using the boundary condition mapping capabilities in Thermal Desktop. The ablation subroutine in SINDA/FLUINT was then used to model the ablation of the refractory material.

Rail gun performance and plasma characteristics due to wall ablation

NASA Technical Reports Server (NTRS)

Ray, P. K.

1986-01-01

The experiment of Bauer, et al. (1982) is analyzed by considering wall ablation and viscous drag in the plasma. Plasma characteristics are evaluated through a simple fluid-mechanical analysis considering only wall ablation. By equating the energy dissipated in the plasma with the radiation heat loss, the average properties of the plasma are determined as a function of time.

Dynamics of Molecular Emission Features from Nanosecond, Femtosecond Laser and Filament Ablation Plasmas

SciTech Connect

Harilal, Sivanandan S.; Yeak, J.; Brumfield, Brian E.

2016-06-15

The evolutionary paths of molecular species and nanoparticles in laser ablation plumes are not well understood due to the complexity of numerous physical processes that occur simultaneously in a transient laser-plasma system. It is well known that the emission features of ions, atoms, molecules and nanoparticles in a laser ablation plume strongly depend on the laser irradiation conditions. In this letter we report the temporal emission features of AlO molecules in plasmas generated using a nanosecond laser, a femtosecond laser and filaments generated from a femtosecond laser. Our results show that, at a fixed laser energy, the persistence of AlOmore » is found to be highest and lowest in ns and filament laser plasmas respectively while molecular species are formed at early times for both ultrashort pulse (fs and filament) generated plasmas. Analysis of the AlO emission band features show that the vibrational temperature of AlO decays rapidly in filament assisted laser ablation plumes.« less

EM Modelling of RF Propagation Through Plasma Plumes

NASA Astrophysics Data System (ADS)

Pandolfo, L.; Bandinelli, M.; Araque Quijano, J. L.; Vecchi, G.; Pawlak, H.; Marliani, F.

2012-05-01

Electric propulsion is a commercially attractive solution for attitude and position control of geostationary satellites. Hall-effect ion thrusters generate a localized plasma flow in the surrounding of the satellite, whose impact on the communication system needs to be qualitatively and quantitatively assessed. An electromagnetic modelling tool has been developed and integrated into the Antenna Design Framework- ElectroMagnetic Satellite (ADF-EMS). The system is able to guide the user from the plume definition phases through plume installation and simulation. A validation activity has been carried out and the system has been applied to the plume modulation analysis of SGEO/Hispasat mission.

Imaging spectroscopy of polymer ablation plasmas for laser propulsion applications

NASA Astrophysics Data System (ADS)

Jiao, Long; Truscott, Benjamin S.; Liu, Hao; Ashfold, Michael N. R.; Ma, Honghao

2017-01-01

A number of polymers have been proposed for use as propellants in space launch and thruster applications based on laser ablation, although few prior studies have either evaluated their performance at background pressures representative of the upper atmosphere or investigated interactions with ambient gases other than air. Here, we use spatially and temporally resolved optical emission spectroscopy to compare three polymers, poly(ethylene), poly(oxymethylene), and glycidyl azide polymer, ablated using a 532 nm, nanosecond pulsed laser under Ar and O2 at pressures below 1 Torr. Emission lines from neutrally and positively charged atoms are observed in each case, along with the recombination radiation at the interaction front between the plasma plume and the background gas. C2 radicals arise either as a direct fragmentation product or by a three-body recombination of C atoms, depending on the structure of the polymer backbone, and exhibit a rotational temperature of ≈5000 K. The Sedov-Taylor point blast model is used to infer the energy release relative to the incident laser energy, which for all polymers is greater in the presence of O2, as to be expected based on their negative oxygen balance. Under Ar, plume confinement is seen to enhance the self-reactivity of the ejecta from poly(oxymethylene) and glycidyl azide polymer, with maximum exothermicity close to 0.5 Torr. However, little advantage of the latter, widely considered one of the most promising energetic polymers, is apparent under the present conditions over the former, a common engineering plastic.

An ablative pulsed plasma thruster with a segmented anode

NASA Astrophysics Data System (ADS)

Zhang, Zhe; Ren, Junxue; Tang, Haibin; Ling, William Yeong Liang; York, Thomas M.

2018-01-01

An ablative pulsed plasma thruster (APPT) design with a ‘segmented anode’ is proposed in this paper. We aim to examine the effect that this asymmetric electrode configuration (a normal cathode and a segmented anode) has on the performance of an APPT. The magnetic field of the discharge arc, plasma density in the exit plume, impulse bit, and thrust efficiency were studied using a magnetic probe, Langmuir probe, thrust stand, and mass bit measurements, respectively. When compared with conventional symmetric parallel electrodes, the segmented anode APPT shows an improvement in the impulse bit of up to 28%. The thrust efficiency is also improved by 49% (from 5.3% to 7.9% for conventional and segmented designs, respectively). Long-exposure broadband emission images of the discharge morphology show that compared with a normal anode, a segmented anode results in clear differences in the luminous discharge morphology and better collimation of the plasma. The magnetic probe data indicate that the segmented anode APPT exhibits a higher current density in the discharge arc. Furthermore, Langmuir probe data collected from the central exit plane show that the peak electron density is 75% higher than with conventional parallel electrodes. These results are believed to be fundamental to the physical mechanisms behind the increased impulse bit of an APPT with a segmented electrode.

Modeling and Simulation of Ablation-Controlled Plasmas

NASA Astrophysics Data System (ADS)

Kundrapu, Madhusudhan N.

Ablation and plasma formation in high energy laser target interactions and arc discharges are studied numerically. Each of the two processes is modeled separately due to the type of energy source and the resulting flow eld. Ablation of the target material and plasma formation are coupled to obtain evaporation rate, temperature distribution, velocity eld, and species concentration self-consistently. Laser ablation is studied in the perspective of directed energy applications, where beam size varies from few centimeters to tens of centimeters with energies extending up to 10 kW/cm2. Because of this high energy deposition, the evaporated material expands to supersonic speeds into the free space. Due to the large spot sizes and associated supersonic flow, one dimensional Euler equations are considered to be sufficient for modeling the plume. Instead, more emphasis was given to evaporation model, by introducing Knudsen layer kinetics at the plume target interface, and plasma shielding. The evaporation rate is validated with results from the experiments and simulations are carried out to nd the in fluence of laser beam frequency on evaporation rates. The evaporation model used in this work is found to be more accurate than the widely used model based on sonic speed assumption. The optimum beam wavelength for Al surfaces is found to be 850 nm. Attenuation of telemetry data by plasma is a concern for the testing of directed energy systems. Electrostatic approach for the mitigation of communication attenuation is analyzed to obtain the fluency limits up to which the approach can be implemented. It is found from sheath calculations that uninterrupted telemetry can be achieved through Al plasma for fluences below 4 J/cm2 at a background pressure of 1 atm, using a maximum bias voltage of 10 kV . Arc discharge ablation is modeled for the synthesis of nanoparticles. The electric arc generated between the electrodes, placed inside a Helium chamber, evaporates the catalyst

Magnetic Field Effects on Plasma Plumes

NASA Technical Reports Server (NTRS)

Ebersohn, F.; Shebalin, J.; Girimaji, S.; Staack, D.

2012-01-01

Here, we will discuss our numerical studies of plasma jets and loops, of basic interest for plasma propulsion and plasma astrophysics. Space plasma propulsion systems require strong guiding magnetic fields known as magnetic nozzles to control plasma flow and produce thrust. Propulsion methods currently being developed that require magnetic nozzles include the VAriable Specific Impulse Magnetoplasma Rocket (VASIMR) [1] and magnetoplasmadynamic thrusters. Magnetic nozzles are functionally similar to de Laval nozzles, but are inherently more complex due to electromagnetic field interactions. The two crucial physical phenomenon are thrust production and plasma detachment. Thrust production encompasses the energy conversion within the nozzle and momentum transfer to a spacecraft. Plasma detachment through magnetic reconnection addresses the problem of the fluid separating efficiently from the magnetic field lines to produce maximum thrust. Plasma jets similar to those of VASIMR will be studied with particular interest in dual jet configurations, which begin as a plasma loops between two nozzles. This research strives to fulfill a need for computational study of these systems and should culminate with a greater understanding of the crucial physics of magnetic nozzles with dual jet plasma thrusters, as well as astrophysics problems such as magnetic reconnection and dynamics of coronal loops.[2] To study this problem a novel, hybrid kinetic theory and single fluid magnetohydrodynamic (MHD) solver known as the Magneto-Gas Kinetic Method is used.[3] The solver is comprised of a "hydrodynamic" portion based on the Gas Kinetic Method and a "magnetic" portion that accounts for the electromagnetic behaviour of the fluid through source terms based on the resistive MHD equations. This method is being further developed to include additional physics such as the Hall effect. Here, we will discuss the current level of code development, as well as numerical simulation results

Diagnostics of Carbon Nanotube Formation in a Laser Produced Plume: An Investigation of the Metal Catalyst by Laser Ablation Atomic Fluorescence Spectroscopy

NASA Technical Reports Server (NTRS)

deBoer, Gary; Scott, Carl

2003-01-01

Carbon nanotubes, elongated molecular tubes with diameters of nanometers and lengths in microns, hold great promise for material science. Hopes for super strong light-weight material to be used in spacecraft design is the driving force behind nanotube work at JSC. The molecular nature of these materials requires the appropriate tools for investigation of their structure, properties, and formation. The mechanism of nanotube formation is of particular interest because it may hold keys to controlling the formation of different types of nanotubes and allow them to be produced in much greater quantities at less cost than is currently available. This summer's work involved the interpretation of data taken last summer and analyzed over the academic year. The work involved diagnostic studies of carbon nanotube formation processes occurring in a laser-produced plume. Laser ablation of metal doped graphite to produce a plasma plume in which carbon nanotubes self assemble is one method of making carbon nanotube. The laser ablation method is amenable to applying the techniques of laser spectroscopy, a powerful tool for probing the energies and dynamics of atomic and molecular species. The experimental work performed last summer involved probing one of the metal catalysts, nickel, by laser induced fluorescence. The nickel atom was studied as a function of oven temperature, probe laser wavelength, time after ablation, and position in the laser produced plume. This data along with previously obtained data on carbon was analyzed over the academic year. Interpretations of the data were developed this summer along with discussions of future work. The temperature of the oven in which the target is ablated greatly influences the amount of material ablated and the propagation of the plume. The ablation conditions and the time scale of atomic and molecular lifetimes suggest that initial ablation of the metal doped carbon target results in atomic and small molecular species. The metal

Investigation of plume dynamics during picosecond laser ablation of H13 steel using high-speed digital holography

NASA Astrophysics Data System (ADS)

Pangovski, Krste; Otanocha, Omonigho B.; Zhong, Shan; Sparkes, Martin; Liu, Zhu; O'Neill, William; Li, Lin

2017-02-01

Ablation of H13 tool steel using pulse packets with repetition rates of 400 and 1000 kHz and pulse energies of 75 and 44 μ {J}, respectively, is investigated. A drop in ablation efficiency (defined here as the depth per pulse or μ {m}{/}μ {J}) is shown to occur when using pulse energies of E_{{pulse}} > 44 μ {J}, accompanied by a marked difference in crater morphology. A pulsed digital holographic system is applied to image the resulting plumes, showing a persistent plume in both cases. Holographic data are used to calculate the plume absorption and subsequently the fraction of pulse energy arriving at the surface after traversing the plume for different pulse arrival times. A significant proportion of the pulse energy is shown to be absorbed in the plume for E_{{pulse}} > 44 μ {J} for pulse arrival times corresponding to {>}1 MHz pulse repetition rate, shifting the interaction to a vapour-dominated ablation regime, an energetically costlier ablation mechanism.

Evaluation of pressure in a plasma produced by laser ablation of steel

NASA Astrophysics Data System (ADS)

Hermann, Jörg; Axente, Emanuel; Craciun, Valentin; Taleb, Aya; Pelascini, Frédéric

2018-05-01

We investigated the time evolution of pressure in the plume generated by laser ablation with ultraviolet nanosecond laser pulses in a near-atmospheric argon atmosphere. These conditions were previously identified to produce a plasma of properties that facilitate accurate spectroscopic diagnostics. Using steel as sample material, the present investigations benefit from the large number of reliable spectroscopic data available for iron. Recording time-resolved emission spectra with an echelle spectrometer, we were able to perform accurate measurements of electron density and temperature over a time interval from 200 ns to 12 μs. Assuming local thermodynamic equilibrium, we computed the plasma composition within the ablated vapor material and the corresponding kinetic pressure. The time evolution of plume pressure is shown to reach a minimum value below the pressure of the background gas. This indicates that the process of vapor-gas interdiffusion has a negligible influence on the plume expansion dynamics in the considered timescale. Moreover, the results promote the plasma pressure as a control parameter in calibration-free laser-induced breakdown spectroscopy.

Discharge reliability in ablative pulsed plasma thrusters

NASA Astrophysics Data System (ADS)

Wu, Zhiwen; Sun, Guorui; Yuan, Shiyue; Huang, Tiankun; Liu, Xiangyang; Xie, Kan; Wang, Ningfei

2017-08-01

Discharge reliability is typically neglected in low-ignition-cycle ablative pulsed plasma thrusters (APPTs). In this study, the discharge reliability of an APPT is assessed analytically and experimentally. The goals of this study are to better understand the ignition characteristics and to assess the accuracy of the analytical method. For each of six sets of operating conditions, 500 tests of a parallel-plate APPT with a coaxial semiconductor spark plug are conducted. The discharge voltage and current are measured with a high-voltage probe and a Rogowski coil, respectively, to determine whether the discharge is successful. Generally, the discharge success rate increases as the discharge voltage increases, and it decreases as the electrode gap and the number of ignitions increases. The theoretical analysis and the experimental results are reasonably consistent. This approach provides a reference for designing APPTs and improving their stability.

Global Modeling of Uranium Molecular Species Formation Using Laser-Ablated Plasmas

NASA Astrophysics Data System (ADS)

Curreli, Davide; Finko, Mikhail; Azer, Magdi; Armstrong, Mike; Crowhurst, Jonathan; Radousky, Harry; Rose, Timothy; Stavrou, Elissaios; Weisz, David; Zaug, Joseph

2016-10-01

Uranium is chemically fractionated from other refractory elements in post-detonation nuclear debris but the mechanism is poorly understood. Fractionation alters the chemistry of the nuclear debris so that it no longer reflects the chemistry of the source weapon. The conditions of a condensing fireball can be simulated by a low-temperature plasma formed by vaporizing a uranium sample via laser heating. We have developed a global plasma kinetic model in order to model the chemical evolution of U/UOx species within an ablated plasma plume. The model allows to track the time evolution of the density and energy of an uranium plasma plume moving through an oxygen atmosphere of given fugacity, as well as other relevant quantities such as average electron and gas temperature. Comparison of model predictions with absorption spectroscopy of uranium-ablated plasmas provide preliminary insights on the key chemical species and evolution pathways involved during the fractionation process. This project was sponsored by the DoD, Defense Threat Reduction Agency, Grant HDTRA1-16-1-0020. This work was performed in part under the auspices of the U.S. DoE by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344.

Long-lived plasmaspheric drainage plumes: Where does the plasma come from?

NASA Astrophysics Data System (ADS)

Borovsky, Joseph E.; Welling, Daniel T.; Thomsen, Michelle F.; Denton, Michael H.

2014-08-01

Long-lived (weeks) plasmaspheric drainage plumes are explored. The long-lived plumes occur during long-lived high-speed-stream-driven storms. Spacecraft in geosynchronous orbit see the plumes as dense plasmaspheric plasma advecting sunward toward the dayside magnetopause. The older plumes have the same densities and local time widths as younger plumes, and like younger plumes they are lumpy in density and they reside in a spatial gap in the electron plasma sheet (in sort of a drainage corridor). Magnetospheric-convection simulations indicate that drainage from a filled outer plasmasphere can only supply a plume for 1.5-2 days. The question arises for long-lived plumes (and for any plume older than about 2 days): Where is the plasma coming from? Three candidate sources appear promising: (1) substorm disruption of the nightside plasmasphere which may transport plasmaspheric plasma outward onto open drift orbits, (2) radial transport of plasmaspheric plasma in velocity-shear-driven instabilities near the duskside plasmapause, and (3) an anomalously high upflux of cold ionospheric protons from the tongue of ionization in the dayside ionosphere, which may directly supply ionospheric plasma into the plume. In the first two cases the plume is drainage of plasma from the magnetosphere; in the third case it is not. Where the plasma in long-lived plumes is coming from is a quandary: to fix this dilemma, further work and probably full-scale simulations are needed.

A tandem mirror hybrid plume plasma propulsion facility

NASA Technical Reports Server (NTRS)

Chang-Diaz, F. R.; Yang, T. F.; Krueger, W. A.; Peng, S.; Urbahn, J.; Yao, X.; Griffin, D.

1988-01-01

A concept in electrodeless plasma propulsion, which is also capable of delivering a variable Isp, is presented. The concept involves a three-stage system of plasma injection, heating, and subsequent ejection through a magnetic nozzle. The nozzle produces the hybrid plume by the coaxial injection of hypersonic neutral gas. The gas layer, thus formed, protects the material walls from the hot plasma and, through increased collisions, helps detach it from the diverging magnetic field. The physics of this concept is evaluated numerically through full spatial and temporal simulations; these explore the operating characteristics of such a device over a wide region of parameter space. An experimental facility to study the plasma dynamics in the hybrid plume was built. The device consists of a tandem mirror operating in an asymmetric mode. A later upgrade of this system will incorporate a cold plasma injector at one end of the machine. Initial experiments involve the full characterization of the operating envelope, as well as extensive measurements of plasma properties at the exhaust. The results of the numerical simulations are described.

A tandem mirror hybrid plume plasma propulsion facility

NASA Technical Reports Server (NTRS)

Yang, T. F.; Krueger, W. A.; Peng, S.; Urbahn, J.; Chang-Diaz, F. R.

1988-01-01

This paper discusses a novel concept in electrodeless plasma propulsion, in which the materials problems are ameliorated by an electrodeless magnetic confinement scheme borrowed from the tandem mirror approach to controlled thermonuclear fusion. The concept also features a two-stage magnetic nozzle with an annular hypersonic coaxial gas injector near the throat. The nozzle produces hybrid plume by the coaxial injection of hypersonic neutral gas, and the gas layer thus formed protects the material walls from the hot plasma and, through increased collisions, helps detach it from the diverging magnetic field. The tandem mirror plasma propulsion facility is capable of delivering a variable I(sp). The results of numerical simulation of this concept are presented together with those from an experimental tandem-mirror plasma propulsion device.

Measurement of magnetic field fluctuations and diamagnetic currents within a laser ablation plasma interacting with an axial magnetic field

SciTech Connect

Ikeda, S.; Horioka, K.; Okamura, M.

Here, the guiding of laser ablation plasmas with axial magnetic fields has been used for many applications, since its effectiveness has been proven empirically. For more sophisticated and complicated manipulations of the plasma flow, the behavior of the magnetic field during the interaction and the induced diamagnetic current in the plasma plume needs to be clearly understood. To achieve the first milestone for establishing magnetic plasma manipulation, we measured the spatial and temporal fluctuations of the magnetic field caused by the diamagnetic current. We showed that the small fluctuations of the magnetic field can be detected by using a simplemore » magnetic probe. We observed that the field penetrates to the core of the plasma plume. The diamagnetic current estimated from the magnetic field had temporal and spatial distributions which were confirmed to be correlated with the transformation of the plasma plume. Our results show that the measurement by the magnetic probe is an effective method to observe the temporal and spatial distributions of the magnetic field and diamagnetic current. The systematic measurement of the magnetic field variations is a valuable method to establish the magnetic field manipulation of the laser ablation plasma.« less

Measurement of magnetic field fluctuations and diamagnetic currents within a laser ablation plasma interacting with an axial magnetic field

DOE PAGES

Ikeda, S.; Horioka, K.; Okamura, M.

2017-10-10

Here, the guiding of laser ablation plasmas with axial magnetic fields has been used for many applications, since its effectiveness has been proven empirically. For more sophisticated and complicated manipulations of the plasma flow, the behavior of the magnetic field during the interaction and the induced diamagnetic current in the plasma plume needs to be clearly understood. To achieve the first milestone for establishing magnetic plasma manipulation, we measured the spatial and temporal fluctuations of the magnetic field caused by the diamagnetic current. We showed that the small fluctuations of the magnetic field can be detected by using a simplemore » magnetic probe. We observed that the field penetrates to the core of the plasma plume. The diamagnetic current estimated from the magnetic field had temporal and spatial distributions which were confirmed to be correlated with the transformation of the plasma plume. Our results show that the measurement by the magnetic probe is an effective method to observe the temporal and spatial distributions of the magnetic field and diamagnetic current. The systematic measurement of the magnetic field variations is a valuable method to establish the magnetic field manipulation of the laser ablation plasma.« less

An 11 cm long atmospheric pressure cold plasma plume for applications of plasma medicine

SciTech Connect

Lu Xinpei; Jiang Zhonghe; Xiong Qing

2008-02-25

In this letter, a room temperature atmospheric pressure plasma jet device is reported. The high voltage electrode of the device is covered by a quartz tube with one end closed. The device, which is driven by a kilohertz ac power supply, is capable of generating a plasma plume up to 11 cm long in the surrounding room air. The rotational and vibrational temperatures of the plasma plume are 300 and 2300 K, respectively. A simple electrical model shows that, when the plasma plume is contacted with a human, the voltage drop on the human is less than 66 V formore » applied voltage of 5 kV (rms)« less

Effects of Plume Hydrodynamics and Oxidation on the Composition of a Condensing Laser-Induced Plasma

DOE PAGES

Weisz, David G.; Crowhurst, Jonathan C.; Finko, Mikhail S.; ...

2018-02-01

High-temperature chemistry in laser ablation plumes leads to vapor-phase speciation, which can induce chemical fractionation during condensation. In this work, using emission spectroscopy acquired after ablation of a SrZrO 3 target, we have experimentally observed the formation of multiple molecular species (ZrO and SrO) as a function of time as the laser ablation plume evolves. Although the stable oxides SrO and ZrO 2 are both refractory, we observed emission from the ZrO intermediate at earlier times than SrO. We deduced the time-scale of oxygen entrainment into the laser ablation plume using an 18O 2 environment by observing the in-growth ofmore » Zr 18O in the emission spectra relative to Zr 16O, which was formed by reaction of Zr with 16O from the target itself. Using temporally resolved plume-imaging, we determined that ZrO formed more readily at early times, volumetrically in the plume, while SrO formed later in time, around the periphery. Lastly, using a simple temperature-dependent reaction model, we have illustrated that the formation sequence of these oxides subsequent to ablation is predictable to first order.« less

Plasma Plume Characterization of the HERMeS During a 1722-hr Wear Test Campaign

NASA Technical Reports Server (NTRS)

Huang, Wensheng; Williams, George J.; Peterson, Peter Y.; Kamhawi, Hani; Gilland, James H.; Herman, Daniel A.

2017-01-01

A 1722-hr wear test campaign of NASA's 12.5-kW Hall Effect Rocket with Magnetic Shielding was completed. This wear test campaign, completed in 2016, was divided into four segments including an electrical configuration characterization test, two short duration tests, and one long wear test. During the electrical configuration characterization test, the plasma plume was examined to provide data to support the down select of the electrical configuration for further testing. During the long wear tests, the plasma plume was periodically examined for indications of changes in thruster behavior. Examination of the plasma plume data from the electrical configuration characterization test revealed a correlation between the plume properties and the presence of a conduction path through the front poles. Examination of the long wear test plasma plume data revealed that the plume characteristics remained unchanged during testing to within the measurement uncertainty.

Plasma Plume Characterization of the HERMeS during a 1722-hr Wear Test Campaign

NASA Technical Reports Server (NTRS)

Huang, Wensheng; Williams, George J.; Peterson, Peter Y.; Kamhawi, Hani; Gilland, James H.; Herman, Daniel A.

2017-01-01

A 1722-hour wear test campaign of NASAs 12.5 kilowatt Hall Effect Rocket with Magnetic Shielding was completed. This wear test campaign, completed in 2016, was divided into four segments including an electrical configuration characterization test, two short duration tests, and one long wear test. During the electrical configuration characterization test, the plasma plume was examined to provide data to support the down select of the electrical configuration for further testing. During the long wear tests, the plasma plume was periodically examined for indications of changes in thruster behavior. Examination of the plasma plume data from the electrical configuration characterization test revealed a correlation between the plume properties and the presence of a conduction path through the front poles. Examination of the long wear test plasma plume data revealed that the plume characteristics remained unchanged during testing to within the measurement uncertainty.

Confluence or independence of microwave plasma bullets in atmospheric argon plasma jet plumes

NASA Astrophysics Data System (ADS)

Li, Ping; Chen, Zhaoquan; Mu, Haibao; Xu, Guimin; Yao, Congwei; Sun, Anbang; Zhou, Yuming; Zhang, Guanjun

2018-03-01

Plasma bullet is the formation and propagation of a guided ionization wave (streamer), normally generated in atmospheric pressure plasma jet (APPJ). In most cases, only an ionization front produces in a dielectric tube. The present study shows that two or three ionization fronts can be generated in a single quartz tube by using a microwave coaxial resonator. The argon APPJ plumes with a maximum length of 170 mm can be driven by continuous microwaves or microwave pulses. When the input power is higher than 90 W, two or three ionization fronts propagate independently at first; thereafter, they confluence to form a central plasma jet plume. On the other hand, the plasma bullets move independently as the lower input power is applied. For pulsed microwave discharges, the discharge images captured by a fast camera show the ionization process in detail. Another interesting finding is that the strongest lightening plasma jet plumes always appear at the shrinking phase. Both the discharge images and electromagnetic simulations suggest that the confluence or independent propagation of plasma bullets is resonantly excited by the local enhanced electric fields, in terms of wave modes of traveling surface plasmon polaritons.

Monitoring of KrF excimer laser ablation for burn scars: a comparative study of transient reflection measurement and time-resolved photography of ablation plume

NASA Astrophysics Data System (ADS)

Nakajima, Akio; Arai, Tsunenori; Kikuchi, Makoto; Iwaya, Akimi; Arai, Katsuyuki; Inazaki, Satoshi; Takaoka, Takatsugu; Kato, Masayoshi

1995-05-01

A simple laser ablation monitoring during burn scar removal by KrF laser irradiation was studied to control laser fluence in real-time. Because, to obtain suitable surface for auto skin-graft, the laser fluence should be precisely controlled at each laser shot. We employed simple probe transmission method which could detect ejected material/phenomena from irradiated surface. The time-course of measured probe intensity contained a couple of attenuated peaks, which might corresponded to a shock wave front and debris plume. The delay time from laser irradiation to the debris plume peak appearance varied with the ablation fluence. The delay time of 1 J/cm2 (near ablation threshold) case prolonged 25% from 8 J/cm2 (far above threshold) case. Therefore, we think the delay time measurement by means of the simple probe transmission method may be available to attain the laser fluence control for nonuniform burn scar removal. The time-resolved photography and probe reflection method were also studied to understand the measured time-course of the transmitted probe intensity.

Analysis of plasma-mediated ablation in aqueous tissue

NASA Astrophysics Data System (ADS)

Jiao, Jian; Guo, Zhixiong

2012-06-01

Plasma-mediated ablation using ultrafast lasers in transparent media such as aqueous tissues is studied. It is postulated that a critical seed free electron density exists due to the multiphoton ionization in order to trigger the avalanche ionization which causes ablation and during the avalanche ionization process the contribution of laser-induced photon ionization is negligible. Based on this assumption, the ablation process can be treated as two separate processes - the multiphoton and avalanche ionizations - at different time stages; so that an analytical solution to the evolution of plasma formation is obtained for the first time. The analysis is applied to plasma-mediated ablation in corneal epithelium and validated via comparison with experimental data available in the literature. The critical seed free-electron density and the time to initiate the avalanche ionization for sub-picosecond laser pulses are analyzed. It is found that the critical seed free-electron density decreases as the pulse width increases, obeying a tp-5.65 rule. This model is further extended to the estimation of crater size in the ablation of tissue-mimic polydimethylsiloxane (PDMS). The results match well with the available experimental measurements.

Single laser based pump-probe technique to study plasma shielding during nanosecond laser ablation of copper thin films

NASA Astrophysics Data System (ADS)

Nammi, Srinagalakshmi; Vasa, Nilesh J.; Gurusamy, Balaganesan; Mathur, Anil C.

2017-09-01

A plasma shielding phenomenon and its influence on micromachining is studied experimentally and theoretically for laser wavelengths of 355 nm, 532 nm and 1064 nm. A time resolved pump-probe technique is proposed and demonstrated by splitting a single nanosecond Nd3+:YAG laser into an ablation laser (pump laser) and a probe laser to understand the influence of plasma shielding on laser ablation of copper (Cu) clad on polyimide thin films. The proposed nanosecond pump-probe technique allows simultaneous measurement of the absorption characteristics of plasma produced during Cu film ablation by the pump laser. Experimental measurements of the probe intensity distinctly show that the absorption by the ablated plume increases with increase in the pump intensity, as a result of plasma shielding. Theoretical estimation of the intensity of the transmitted pump beam based on the thermo-temporal modeling is in qualitative agreement with the pump-probe based experimental measurements. The theoretical estimate of the depth attained for a single pulse with high pump intensity value on a Cu thin film is limited by the plasma shielding of the incident laser beam, similar to that observed experimentally. Further, the depth of micro-channels produced shows a similar trend for all three wavelengths, however, the channel depth achieved is lesser at the wavelength of 1064 nm.

Third harmonic generation in air ambient and laser ablated carbon plasma

SciTech Connect

Singh, Ravi Pratap, E-mail: ravips@iitk.ac.in; Gupta, Shyam L.; Thareja, Raj K.

2015-12-15

We report the third harmonic generation of a nanosecond laser pulse (1.06 μm) in air ambient and in the presence of nanoparticles from laser ablated carbon plasma. Significant decrease in the threshold of third harmonic generation and multi-fold increment in the intensity of generated third harmonic is observed in presence of carbon plasma. The third harmonic in air is due to the quasi-resonant four photon process involving vibrationally excited states of molecular ion of nitrogen due to electron impact ionization and laser pulse. Following optical emission spectroscopic observations we conclude that the presence of C{sub 2} and CN in the ablatedmore » plume play a vital role in the observed third harmonic signals.« less

[Research on cells ablation characters by laser plasma].

PubMed

Han, Jing-hua; Zhang, Xin-gang; Cai, Xiao-tang; Duan, Tao; Feng, Guo-ying; Yang, Li-ming; Zhang, Ya-jun; Wang, Shao-peng; Li, Shi-wen

2012-08-01

The study on the mechanism of laser ablated cells is of importance to laser surgery and killing harmful cells. Three radiation modes were researched on the ablation characteristics of onion epidermal cells under: laser direct irradiation, focused irradiation and the laser plasma radiation. Based on the thermodynamic properties of the laser irradiation, the cell temperature rise and phase change have been analyzed. The experiments show that the cells damage under direct irradiation is not obvious at all, but the focused irradiation can cause cells to split and moisture removal. The removal shape is circular with larger area and rough fracture edges. The theoretical analysis found out that the laser plasma effects play a key role in the laser ablation. The thermal effects, radiation ionization and shock waves can increase the deposition of laser pulses energy and impact peeling of the cells, which will greatly increase the scope and efficiency of cell killing and is suitable for the cell destruction.

Experimental Investigation of Molecular Species Formation in Metal Plasmas During Laser Ablation

NASA Astrophysics Data System (ADS)

Radousky, H.; Crowhurst, J.; Rose, T.; Armstrong, M.; Stavrou, E.; Zaug, J.; Weisz, D.; Azer, M.; Finko, M.; Curreli, D.

2016-10-01

Atomic and molecular spectra on metal plasmas generated by laser ablation have been measured using single, nominally 6-7 ns pulses at 1064 nm, and with energies less than 50 mJ. The primary goal for these studies is to constrain the physical and chemical mechanisms that control the distribution of radionuclides in fallout after a nuclear detonation. In this work, laser emission spectroscopy was used to obtain in situdata for vapor phase molecular species as they form in a controlled oxygen atmosphere for a variety of metals such as Fe, Al, as well as preliminary results for U. In particular, the ablation plumes created from these metals have been imaged with a resolution of 10 ns, and it is possible to observe the expansion of the plume out to 0.5 us. These data serve as one set of inputs for a semi-empirical model to describe the chemical fractionation of uranium during fallout formation. Prepared by LLNL under Contract DE-AC52-07NA27344. This project was sponsored by the Department of the Defense, Defense Threat Reduction Agency, under Grant Number HDTRA1-16-1-0020.

Laser ablation and deposition of wide bandgap semiconductors: plasma and nanostructure of deposits diagnosis

NASA Astrophysics Data System (ADS)

Sanz, M.; López-Arias, M.; Rebollar, E.; de Nalda, R.; Castillejo, M.

2011-12-01

Nanostructured CdS and ZnS films on Si (100) substrates were obtained by nanosecond pulsed laser deposition at the wavelengths of 266 and 532 nm. The effect of laser irradiation wavelength on the surface structure and crystallinity of deposits was characterized, together with the composition, expansion dynamics and thermodynamic parameters of the ablation plume. Deposits were analyzed by environmental scanning electron microscopy, atomic force microscopy and X-ray diffraction, while in situ monitoring of the plume was carried out with spectral, temporal and spatial resolution by optical emission spectroscopy. The deposits consist of 25-50 nm nanoparticle assembled films but ablation in the visible results in larger aggregates (150 nm) over imposed on the film surface. The aggregate free films grown at 266 nm on heated substrates are thicker than those grown at room temperature and in the former case they reveal a crystalline structure congruent with that of the initial target material. The observed trends are discussed in reference to the light absorption step, the plasma composition and the nucleation processes occurring on the substrate.

Characteristics of chiral plasma plumes generated in the absence of external magnetic field

NASA Astrophysics Data System (ADS)

Nie, LanLan; Liu, FengWu; Zhou, XinCai; Lu, XinPei; Xian, YuBin

2018-05-01

A chiral plasma plume has recently been generated inside a dielectric tube without the use of an external magnetic field. In this paper, we seek to further study the key properties of such a chiral plume to improve our understanding of how this interesting structure is generated and controlled. The chiral plume is generated by externally mounting a stainless steel helical coil or a ring onto the dielectric tube. By changing the pitch of the helical coil, the pitch of the plasma plume can be controlled, with the shape of the plume following the shape of the helical coil. The addition of the helical coil significantly expands the range of parameters under which the chiral plasma plume appears. When the frequency of the applied voltage increases, additional stable discharge channels appear between the adjacent helices. The addition of two helical coils results in the formation of two chiral plasma plumes, which follow the shape of the helical coils. When a metal ring is placed on the outside of the tube, there is no chiral plasma plume between the high voltage electrode and the ring; however, a chiral plasma plume appears on the right side of the ring if the distance between the ring and the high voltage electrode is small. These findings suggest that the chiral plasma can be effectively modulated and guided using an externally mounted helical coil, which acts as the floating/actual ground to reduce the impedance of the discharge and as such contributes to the emergence of the chiral plasma plume behavior.

Near field interaction of microwave signals with a bounded plasma plume

NASA Technical Reports Server (NTRS)

Ling, Hao; Hallock, Gary A.; Kim, Hyeongdong; Birkner, Bjorn

1991-01-01

The objective was to study the effect of the arcjet thruster plume on the performance of an onboard satellite reflector antenna. A project summary is presented along with sections on plasma and electromagnetic modeling. The plasma modeling section includes the following topics: wave propagation; plasma analysis; plume electron density model; and the proposed experimental program. The section on electromagnetic modeling includes new developments in ray modeling and the validation of three dimensional ray results.

Significance of ambient conditions in uranium absorption and emission features of laser ablation plasmas

SciTech Connect

Skrodzki, P. J.; Shah, N. P.; Taylor, N.

2016-11-01

This study employs laser ablation (LA) to investigate mechanisms for U optical signal variation under various environmental conditions during laser absorption spectroscopy (LAS) and optical emission spectroscopy (OES). Potential explored mechanisms for signal quenching related to ambient conditions include plasma chemistry (e.g., uranium oxide formation), ambient gas confinement effects, and other collisional interactions between plasma constituents and the ambient gas. LA-LAS studies show that the persistence of the U ground state population is significantly reduced in the presence of air ambient compared to nitrogen. LA-OES results yield congested spectra from which the U I 356.18 nm transition is prominent andmore » serves as the basis for signal tracking. LA-OES signal and persistence vary negligibly between the test gases (air and N2), unlike the LA-LAS results. The plume hydrodynamic features and plume fundamental properties showed similar results in both air and nitrogen ambient. Investigation of U oxide formation in the laser-produced plasma suggests that low U concentration in a sample hinders consistent detection of UO molecular spectra.« less

Significance of ambient conditions in uranium absorption and emission features of laser ablation plasmas

SciTech Connect

Skrodzki, P. J.; Shah, N. P.; Taylor, N.

2016-10-02

This study employs laser ablation (LA) to investigate mechanisms for U optical signal variation under various environmental conditions during laser absorption spectroscopy (LAS) and optical emission spectroscopy (OES). Potential mechanisms explored for signal quenching related to ambient conditions include plasma chemistry (e.g., uranium oxide formation), ambient gas confinement effects, and other collisional interactions between plas-ma constituents and the ambient gas. LA-LAS studies show that the persistence of the U ground state population is significantly reduced in the presence of air ambient compared to nitrogen. LA-OES yields congested spectra from which the U I 356.18 nm transition is prominent and servesmore » as the basis for signal tracking. LA-OES signal and per-sistence vary negligibly between the test gases (air and N 2), unlike the LA-LAS results. The plume hydrodynamic features and plume fundamental properties showed similar results in both air and nitrogen ambient. In conclusion, investigation of U oxide formation in the laser-produced plasma suggests that low U concentration in a sample hinders consistent detection of UO molecular spectra.« less

A tandem mirror plasma source for a hybrid plume plasma propulsion concept

NASA Technical Reports Server (NTRS)

Yang, T. F.; Miller, R. H.; Wenzel, K. W.; Krueger, W. A.; Chang, F. R.

1985-01-01

This paper describes a tandem mirror magnetic plasma confinement device to be considered as a hot plasma source for the hybrid plume rocket concept. The hot plasma from this device is injected into an exhaust duct, which will interact with an annular layer of hypersonic neutral gas. Such a device can be used to study the dynamics of the hybrid plume and to experimentally verify the numerical predictions obtained with computer codes. The basic system design is also geared toward being lightweight and compact, as well as having high power density (i.e., several kW/sq cm) at the exhaust. This feature is aimed toward the feasibility of 'space testing'. The plasma is heated by microwaves. A 50 percent heating efficiency can be obtained by using two half-circle antennas. The preliminary Monte Carlo modeling of test particles result reported here indicates that interaction does take place in the exhaust duct. Neutrals gain energy from the ion, which confirms the hybrid plume concept.

Unsteady motion of laser ablation plume by vortex induced by the expansion of curved shock wave

NASA Astrophysics Data System (ADS)

Tran, D. T.; Mori, K.

2017-02-01

There are a number of industrial applications of laser ablation in a gas atmosphere. When an intense pulsed laser beam is irradiated on a solid surface in the gas atmosphere, the surface material is ablated and expands into the atmosphere. At the same time, a spherical shock wave is launched by the ablation jet to induce the unsteady flow around the target surface. The ablated materials, luminously working as tracer, exhibit strange unsteady motions depending on the experimental conditions. By using a high-speed video camera (HPV-X2), unsteady motion ablated materials are visualized at the frame rate more than 106 fps, and qualitatively characterized.

Plume splitting and rebounding in a high-intensity CO{sub 2} laser induced air plasma

SciTech Connect

Chen Anmin; Jiang Yuanfei; Liu Hang

2012-07-15

The dynamics of plasma plume formed by high-intensity CO{sub 2} laser induced breakdown of air at atmospheric pressure is investigated. The laser wavelength is 10.6 {mu}m. Measurements were made using 3 ns gated fast photography as well as space and time resolved optical emission spectroscopy. The behavior of the plasma plume was studied with a laser energy of 3 J and 10 J. The results show that the evolution of the plasma plume is very complicated. The splitting and rebounding of the plasma plume is observed to occur early in the plumes history.

A model of early formation of uranium molecular oxides in laser-ablated plasmas

NASA Astrophysics Data System (ADS)

Finko, Mikhail S.; Curreli, Davide; Weisz, David G.; Crowhurst, Jonathan C.; Rose, Timothy P.; Koroglu, Batikan; Radousky, Harry B.; Armstrong, Michael R.

2017-12-01

In this work, we present a newly constructed U x O y reaction mechanism that consists of 30 reaction channels (21 of which are reversible channels) for 11 uranium molecular species (including ions). Both the selection of reaction channels and calculation of corresponding rate coefficients is accomplished via a comprehensive literature review and application of basic reaction rate theory. The reaction mechanism is supplemented by a detailed description of oxygen plasma chemistry (19 species and 142 reaction channels) and is used to model an atmospheric laser ablated uranium plume via a 0D (global) model. The global model is used to analyze the evolution of key uranium molecular species predicted by the reaction mechanism, and the initial stage of formation of uranium oxide species.

A model of early formation of uranium molecular oxides in laser-ablated plasmas

DOE PAGES

Finko, Mikhail S.; Curreli, Davide; Weisz, David G.; ...

2017-10-12

Here, in this work, we present a newly constructed U xO y reaction mechanism that consists of 30 reaction channels (21 of which are reversible channels) for 11 uranium molecular species (including ions). Both the selection of reaction channels and calculation of corresponding rate coefficients is accomplished via a comprehensive literature review and application of basic reaction rate theory. The reaction mechanism is supplemented by a detailed description of oxygen plasma chemistry (19 species and 142 reaction channels) and is used to model an atmospheric laser ablated uranium plume via a 0D (global) model. Finally, the global model is usedmore » to analyze the evolution of key uranium molecular species predicted by the reaction mechanism, and the initial stage of formation of uranium oxide species.« less

A model of early formation of uranium molecular oxides in laser-ablated plasmas

SciTech Connect

Finko, Mikhail S.; Curreli, Davide; Weisz, David G.

Here, in this work, we present a newly constructed U xO y reaction mechanism that consists of 30 reaction channels (21 of which are reversible channels) for 11 uranium molecular species (including ions). Both the selection of reaction channels and calculation of corresponding rate coefficients is accomplished via a comprehensive literature review and application of basic reaction rate theory. The reaction mechanism is supplemented by a detailed description of oxygen plasma chemistry (19 species and 142 reaction channels) and is used to model an atmospheric laser ablated uranium plume via a 0D (global) model. Finally, the global model is usedmore » to analyze the evolution of key uranium molecular species predicted by the reaction mechanism, and the initial stage of formation of uranium oxide species.« less

Effects of Cr2O3 Activating Flux on the Plasma Plume in Pulsed Laser Welding

NASA Astrophysics Data System (ADS)

Yi, Luo; Yunfei, Du; Xiaojian, Xie; Rui, Wan; Liang, Zhu; Jingtao, Han

2016-11-01

The effects of Cr2O3 activating flux on pulsed YAG laser welding of stainless steel and, particularly, on the behavior of the plasma plume in the welding process were investigated. According to the acoustic emission (AE) signals detected in the welding process, the possible mechanism for the improvement in penetration depth was discussed. The results indicated that the AE signals detected in the welding process reflected the behavior of the plasma plume as pulsed laser energy affecting the molten pool. The root-mean-square (RMS) waveform, AE count, and power spectrum of AE signals were three effective means to characterize the behavior of the plasma plume, which indicated the characteristics of energy released by the plasma plume. The activating flux affected by the laser beam helped to increase the duration and intensity of energy released by the plasma plume, which improved the recoil force and thermal effect transferred from the plasma plume to the molten pool. These results were the main mechanism for Cr2O3 activating flux addition improving the penetration depth in pulsed YAG laser welding.

Simulation of laser interaction with ablative plasma and hydrodynamic behavior of laser supported plasma

SciTech Connect

Tong Huifeng; Yuan Hong; Tang Zhiping

When an intense laser beam irradiates on a solid target, ambient air ionizes and becomes plasma, while part of the target rises in temperature, melts, vaporizes, ionizes, and yet becomes plasma. A general Godunov finite difference scheme WENO (Weighted Essentially Non-Oscillatory Scheme) with fifth-order accuracy is used to simulate 2-dimensional axis symmetrical laser-supported plasma flow field in the process of laser ablation. The model of the calculation of ionization degree of plasma and the interaction between laser beam and plasma are considered in the simulation. The numerical simulations obtain the profiles of temperature, density, and velocity at different times whichmore » show the evolvement of the ablative plasma. The simulated results show that the laser energy is strongly absorbed by plasma on target surface and that the velocity of laser supported detonation (LSD) wave is half of the ideal LSD value derived from Chapman-Jouguet detonation theory.« less

Angular distributions of plasma edge velocity and integrated intensity: Update on specific impulse for Ablative Laser Propulsion

NASA Astrophysics Data System (ADS)

Lin, Jun; Pakhomov, Andrew V.

2005-04-01

This work concludes our discussion of the image processing technique developed earlier for determination of specific impulse (Isp) for Ablative Laser Propulsion (ALP). The plasma plumes are recorded with a time-resolved intensified charge-coupled device (ICCD) camera. The plasma was formed in vacuum (˜ 3×10-3 Torr) by focusing output pulses of a laser system (100-ps pulsewidth at 532 nm wavelength and ˜35 mJ energy) on surfaces of C (graphite), Al, Si, Fe, Cu, Zn, Sn, and Pb elements. Angular profiles for integrated intensity and plasma expansion velocity were determined for the tested elements. Such profiles were used further for assessment of specific impulse. Specific impulses derived from angular distributions of plasma expansion velocity and integral intensity appeared in excellent agreement with the data derived earlier from force measurements.

Laser plasma interaction at an early stage of laser ablation

NASA Astrophysics Data System (ADS)

Lu, Y. F.; Hong, M. H.; Low, T. S.

1999-03-01

Laser scattering and its interaction with plasma during KrF excimer laser ablation of silicon are investigated by ultrafast phototube detection. There are two peaks in an optical signal with the first peak attributed to laser scattering and the second one to plasma generation. For laser fluence above 5.8 J/cm2, the second peak rises earlier to overlap with the first one. The optical signal is fitted by a pulse distribution for the scattered laser light and a drifted Maxwell-Boltzmann distribution with a center-of-mass velocity for the plasma. Peak amplitude and its arrival time, full width at half maximum (FWHM), starting time, and termination time of the profiles are studied for different laser fluences and detection angles. Laser pulse is scattered from both the substrate and the plasma with the latter part as a dominant factor during the laser ablation. Peak amplitude of the scattered laser signal increases but its FWHM decreases with the laser fluence. Angular distribution of the peak amplitude can be fitted with cosn θ(n=4) while the detection angle has no obvious influence on the FWHM. In addition, FWHM and peak amplitude of plasma signal increase with the laser fluence. However, starting time and peak arrival time of plasma signal reduce with the laser fluence. The time interval between plasma starting and scattered laser pulse termination is proposed as a quantitative parameter to characterize laser plasma interaction. Threshold fluence for the interaction is estimated to be 3.5 J/cm2. For laser fluence above 12.6 J/cm2, the plasma and scattered laser pulse distributions tend to saturate.

Infrared laser ablation of polymeric nanocomposites: A study of surface structure and plume formation

NASA Astrophysics Data System (ADS)

Bartolucci, S. F.; Miller, M. J.; Warrender, J. M.

2016-12-01

The behavior of carbon nanotube composites subjected to laser pulse heating with a 1070 nm variable pulse duration laser has been studied. Previous work has shown that carbon nanotube composites form a protective network on the surface of a composite, which reduces heat input to the underlying polymer and slows mass loss. In this work, we have studied the interaction between the incident laser and the plume formed above the composite. We have correlated these interactions with features observed in the time-resolved mass loss data and confirmed them with observations using high-speed video of the laser irradiations. Beam interactions were studied as a function of laser irradiance and nanotube content. It is shown that beam-plume interactions occur for the carbon nanotube composites and that the interactions occur at shorter pulse durations for increased nanotube content and laser irradiance. When we eliminate beam-plume interaction through alteration of the sample orientation relative to the incident beam, we are able to elucidate the individual contributions of the carbon nanotube surface network and the plume to the observed decrease in mass loss after laser irradiation. We examine the plume content using microscopy and Raman spectroscopy and show that greater beam absorption occurs when there is a higher graphitic content in the plume.

Investigation of the vapour-plasma plume in the welding of titanium by high-power ytterbium fibre laser radiation

NASA Astrophysics Data System (ADS)

Bykovskiy, D. P.; Petrovskii, V. N.; Uspenskiy, S. A.

2015-03-01

The vapour-plasma plume produced in the welding of 6-mm thick VT-23 titanium alloy plates by ytterbium fibre laser radiation of up to 10 kW power is studied in the protective Ar gas medium. High-speed video filming of the vapour-plasma plume is used to visualise the processes occurring during laser welding. The coefficient of inverse bremsstrahlung by the welding plasma plume is calculated from the data of the spectrometric study.

Plasma Observations During the Mars Atmospheric Plume Event of March-April 2012

NASA Technical Reports Server (NTRS)

Andrews, D. J.; Barabash, S.; Edberg, N. J. T.; Gurnett, D. A.; Hall, B. E. S.; Holmstrom, M.; Lester, M.; Morgan, D. D.; Opgenoorth, H. J.; Ramstad, R.;

Evidence of Plume on Europa from Galileo Magnetic and Plasma Density Signatures

NASA Astrophysics Data System (ADS)

Jia, X.; Kivelson, M.; Khurana, K. K.; Kurth, W. S.

2017-12-01

The icy surface of Jupiter's moon, Europa, is thought to lie on top of a global ocean [Khurana et al., 1998; Kivelson et al., 2000]. Water plumes rising 200 kilometers above the disk of the solid body in some Hubble Space Telescope images have been identified through emission spectra of hydrogen and oxygen [Roth et al., 2016] and through absorption in the far ultraviolet of sunlight reflected off of Jupiter [Sparks et al., 2016, 2017]. Plume activity appears to be intermittent, although Sparks et al. [2017] identified a plume at a location where one had been detected in an earlier study. While the detections appear to be valid within statistical uncertainty, they are all close to the limit of detection, making it desirable to find other evidence of the presence of localized vapor above Europa's surface. In this presentation, we examine magnetometer and electromagnetic wave data acquired by the Galileo spacecraft on a close encounter with Europa on December 16, 1997. We identify distinct features in the data that have the characteristics expected if the spacecraft went through magnetic flux tubes that pass around a plume, close to the location proposed for one of the plumes observed by Sparks et al. [2016]. 3D magnetohydrodynamic simulations have been conducted to model the interaction of plume with Europa's plasma and magnetic environment. Our simulations confirm that the magnetic and plasma signatures identified in the Galileo data are consistent with perturbations associated with a localized plume source.

The search for active Europa plumes in Galileo plasma particle detector data: the E12 flyby

NASA Astrophysics Data System (ADS)

Huybrighs, H.; Roussos, E.; Krupp, N.; Fraenz, M.; Futaana, Y.; Barabash, S. V.; Glassmeier, K. H.

2017-12-01

Hubble Space Telescope observations of Europa's auroral emissions and transits in front of Jupiter suggest that recurring water vapour plumes originating from Europa's surface might exist. If conclusively proven, the discovery of these plumes would be significant, because Europa's potentially habitable ocean could be studied remotely by taking in-situ samples of these plumes from a flyby mission. The first opportunity to collect in-situ evidence of the plumes will not arise before the early 2030's when ESA's JUICE mission or NASA's Europa Clipper are set to arrive. However, it may be possible that NASA's Galileo mission has already encountered the plumes when it was active in the Jupiter system from 1995 to 2003. It has been suggested that the high plasma densities and anomalous magnetic fields measured during one of the Galileo flybys of Europa (flyby E12) could be connected to plume activity. In the context of the search for Europa plume signatures in Galileo particle data we present an overview of the in-situ plasma particle data obtained by the Galileo spacecraft during the E12 flyby. Focus is in particular on the data obtained with the plasma particle instruments PLS (low energy ions and electrons) and EPD (high energy ions and electrons). We search for signs of an extended exosphere/ionosphere that could be consistent with ongoing plume activity. The PLS data obtained during the E12 flyby show an extended interaction region between Europa and the plasma from Jupiter's magnetosphere, hinting at the existence of an extended ionosphere and exosphere. Furthermore we show how the EPD data are analyzed and modelled in order to evaluate whether a series of energetic ion depletions can be attributed to losses on the moon's surface or its neutral exosphere.

Evidence of a plume on Europa from Galileo magnetic and plasma wave signatures

NASA Astrophysics Data System (ADS)

Jia, Xianzhe; Kivelson, Margaret G.; Khurana, Krishan K.; Kurth, William S.

2018-05-01

The icy surface of Jupiter's moon, Europa, is thought to lie on top of a global ocean1-4. Signatures in some Hubble Space Telescope images have been associated with putative water plumes rising above Europa's surface5,6, providing support for the ocean theory. However, all telescopic detections reported were made at the limit of sensitivity of the data5-7, thereby calling for a search for plume signatures in in-situ measurements. Here, we report in-situ evidence of a plume on Europa from the magnetic field and plasma wave observations acquired on Galileo's closest encounter with the moon. During this flyby, which dropped below 400 km altitude, the magnetometer8 recorded an approximately 1,000-kilometre-scale field rotation and a decrease of over 200 nT in field magnitude, and the Plasma Wave Spectrometer9 registered intense localized wave emissions indicative of a brief but substantial increase in plasma density. We show that the location, duration and variations of the magnetic field and plasma wave measurements are consistent with the interaction of Jupiter's corotating plasma with Europa if a plume with characteristics inferred from Hubble images were erupting from the region of Europa's thermal anomalies. These results provide strong independent evidence of the presence of plumes at Europa.

Evidence of a plume on Europa from Galileo magnetic and plasma wave signatures

NASA Astrophysics Data System (ADS)

Jia, Xianzhe; Kivelson, Margaret G.; Khurana, Krishan K.; Kurth, William S.

2018-06-01

The icy surface of Jupiter's moon, Europa, is thought to lie on top of a global ocean1-4. Signatures in some Hubble Space Telescope images have been associated with putative water plumes rising above Europa's surface5,6, providing support for the ocean theory. However, all telescopic detections reported were made at the limit of sensitivity of the data5-7, thereby calling for a search for plume signatures in in-situ measurements. Here, we report in-situ evidence of a plume on Europa from the magnetic field and plasma wave observations acquired on Galileo's closest encounter with the moon. During this flyby, which dropped below 400 km altitude, the magnetometer8 recorded an approximately 1,000-kilometre-scale field rotation and a decrease of over 200 nT in field magnitude, and the Plasma Wave Spectrometer9 registered intense localized wave emissions indicative of a brief but substantial increase in plasma density. We show that the location, duration and variations of the magnetic field and plasma wave measurements are consistent with the interaction of Jupiter's corotating plasma with Europa if a plume with characteristics inferred from Hubble images were erupting from the region of Europa's thermal anomalies. These results provide strong independent evidence of the presence of plumes at Europa.

Numerical studies of wall–plasma interactions and ionization phenomena in an ablative pulsed plasma thruster

SciTech Connect

Yang, Lei; School of Astronautics, Beihang University, Beijing 100191; Zeng, Guangshang

2016-07-15

Wall–plasma interactions excited by ablation controlled arcs are very critical physical processes in pulsed plasma thrusters (PPTs). Their effects on the ionization processes of ablated vapor into discharge plasma directly determine PPT performances. To reveal the physics governing the ionization phenomena in PPT discharge, a modified model taking into account the pyrolysis effect of heated polytetrafluoroethylene propellant on the wall–plasma interactions was developed. The feasibility of the modified model was analyzed by creating a one-dimensional simulation of a rectangular ablative PPT. The wall–plasma interaction results based on this modified model were found to be more realistic than for the unmodifiedmore » model; this reflects the dynamic changes of the inflow parameters during discharge in our model. Furthermore, the temporal and spatial variations of the different plasma species in the discharge chamber were numerically studied. The numerical studies showed that polytetrafluoroethylene plasma was mainly composed of monovalent ions; carbon and fluorine ions were concentrated in the upstream and downstream discharge chamber, respectively. The results based on this modified model were in good agreement with the experimental formation times of the various plasma species. A large number of short-lived and highly ionized carbon and fluorine species (divalent and trivalent ions) were created during initial discharge. These highly ionized species reached their peak density earlier than the singly ionized species.« less

Fields in laser-ablated plasmas generalized to degenerate electrons and to Fermi energy in nuclei with change to quark-gluon plasma

NASA Astrophysics Data System (ADS)

Hora, Heinrich; Miley, George H.; Osman, Frederick; Hammerling, Peter X.

2004-09-01

The studies of laser ablation have lead to a new theory of nuclei, endothermic nuclei generation and quark-gluon plasmas. The surface of ablated plasma expanding into vacuum after high power laser irradiation of targets, contains an electric double layer having the thickness of the Debye length. This led to the discovery of surface tension of plasmas and to the internal dynamic electric fields in all inhomogeneous plasmas. The surface causes stabilization by short length surface waves smoothing the expanding plasma plume. Generalizing this to the degenerate electrons in a metal with the Fermi energy instead of the temperature, resulted in the surface tension of metals in agreement with measurements. Taking then the Fermi energy in the Debye length for nucleons results in a theory of nuclei with stable confinement of protons and neutrons just at the well known nuclear density, and in the Debye length equal to Hofstadter's decay of the nuclear surface. Increasing the nuclear density by a factor of 6 leads to the change of the Fermi energy into its relativistic branch where no surface energy is possible and the particle mass is not defined, permitting the quark-gluon plasma. Expansion of this higher density at the big band or in a supernova results in nucleation and element generation. The Boltzmann equilibrium permits the synthesis of nuclei even in the endothermic range limited to about uranium.

Plasma Properties in the Plume of a Hall Thruster Cluster

DTIC Science & Technology

2003-06-04

The Hall thruster cluster is an attractive propulsion approach for spacecraft requiring very high-power electric propulsion systems. This article...probes in the plume of a low-power, four-engine Hall thruster cluster. Simple analytical formulas are introduced that allow these quantities to be

Numerical and experimental investigation of plasma plume deflection with MHD flow control

NASA Astrophysics Data System (ADS)

Kai, ZHAO; Feng, LI; Baigang, SUN; Hongyu, YANG; Tao, ZHOU; Ruizhi, SUN

2018-04-01

This paper presents a composite magneto hydrodynamics (MHD) method to control the low-temperature micro-ionized plasma flow generated by injecting alkali salt into the combustion gas to realize the thrust vector of an aeroengine. The principle of plasma flow with MHD control is analyzed. The feasibility of plasma jet deflection is investigated using numerical simulation with MHD control by loading the User-Defined Function model. A test rig with plasma flow controlled by MHD is established. An alkali salt compound with a low ionization energy is injected into combustion gas to obtain the low-temperature plasma flow. Finally, plasma plume deflection is obtained in different working conditions. The results demonstrate that plasma plume deflection with MHD control can be realized via numerical simulation. A low-temperature plasma flow can be obtained by injecting an alkali metal salt compound with low ionization energy into a combustion gas at 1800–2500 K. The vector angle of plasma plume deflection increases with the increase of gas temperature and the magnetic field intensity. It is feasible to realize the aim of the thrust vector of aeroengine by using MHD to control plasma flow deflection.

Collective behavior of silver plasma during pulsed laser ablation

NASA Astrophysics Data System (ADS)

Dildar, I. M.; Rehman, S.; Khaleeq-ur-Rahman, M.; Bhatti, K. A.; Shuaib, A.

2015-07-01

The present work reports an electrical investigation of silver plasma using a self-fabricated Langmuir probe in air and under a low vacuum (~10-3 torr). A silver target was irradiated with a Q-switched Nd:YAG laser with the wavelength 1.064 µm, energy 10 mJ, pulse duration 9-14 ns and power 1.1 MW. The collective behavior of a silver plasma plume is studied using a Langmuir probe as an electrical diagnostic technique. By applying different positive and negative voltages to the probe, the respective signals are collected on a four channels digital storage oscilloscope having a frequency of 500 MHz. An I-V curve helps to measure electron temperature and electron density directly and plasma frequency, response time, Debye length and number of particles in ‘Debye’s sphere’ indirectly using the theory of Langmuir probe and mathematical formulas. The floating potential is measured as negative for laser induced silver plasma in air and vacuum, following the theory of plasma.

Improving Hall Thruster Plume Simulation through Refined Characterization of Near-field Plasma Properties

NASA Astrophysics Data System (ADS)

Huismann, Tyler D.

Due to the rapidly expanding role of electric propulsion (EP) devices, it is important to evaluate their integration with other spacecraft systems. Specifically, EP device plumes can play a major role in spacecraft integration, and as such, accurate characterization of plume structure bears on mission success. This dissertation addresses issues related to accurate prediction of plume structure in a particular type of EP device, a Hall thruster. This is done in two ways: first, by coupling current plume simulation models with current models that simulate a Hall thruster's internal plasma behavior; second, by improving plume simulation models and thereby increasing physical fidelity. These methods are assessed by comparing simulated results to experimental measurements. Assessment indicates the two methods improve plume modeling capabilities significantly: using far-field ion current density as a metric, these approaches used in conjunction improve agreement with measurements by a factor of 2.5, as compared to previous methods. Based on comparison to experimental measurements, recent computational work on discharge chamber modeling has been largely successful in predicting properties of internal thruster plasmas. This model can provide detailed information on plasma properties at a variety of locations. Frequently, experimental data is not available at many locations that are of interest regarding computational models. Excepting the presence of experimental data, there are limited alternatives for scientifically determining plasma properties that are necessary as inputs into plume simulations. Therefore, this dissertation focuses on coupling current models that simulate internal thruster plasma behavior with plume simulation models. Further, recent experimental work on atom-ion interactions has provided a better understanding of particle collisions within plasmas. This experimental work is used to update collision models in a current plume simulation code. Previous

Comparative study of the expansion dynamics of laser-driven plasma and shock wave in in-air and underwater ablation regimes

NASA Astrophysics Data System (ADS)

Nguyen, Thao T. P.; Tanabe, Rie; Ito, Yoshiro

2018-03-01

We compared the expansion characteristics of the plasma plumes and shock waves generated in laser-induced shock process between the two ablation regimes: in air and under water. The observation was made from the initial moment when the laser pulse hit the target until 1.5 μs. The shock processes were driven by focusing a single laser pulse (1064 nm, FWHM = 13 ns) onto the surface of epoxy-resin blocks using a 40-mm focal length lens. The estimated laser intensity at the target plane is approximate to 9 ×109Wcm-2 . We used the fast-imaging technique to observe the expansion of the plasma plume and a custom-designed time-resolved photoelasticity imaging technique to observe the propagation of shock waves with the time resolution of nanoseconds. We found that at the same intensity of the laser beam, the plasma expansion during the laser pulse follows different mechanisms: the plasma plume that grows in air follows a radiation-wave model while a detonation-wave model can explain the expansion of the plasma plume induced in water. The ideal blast wave theory can be used to predict the decay of the shock wave in air but is not appropriate to describe the decay of the shock wave induced under water.

Cold Atmospheric Plasma for Selectively Ablating Metastatic Breast Cancer Cells

PubMed Central

Wang, Mian; Holmes, Benjamin; Cheng, Xiaoqian; Zhu, Wei; Keidar, Michael; Zhang, Lijie Grace

2013-01-01

Traditional breast cancer treatments such as surgery and radiotherapy contain many inherent limitations with regards to incomplete and nonselective tumor ablation. Cold atomospheric plasma (CAP) is an ionized gas where the ion temperature is close to room temperature. It contains electrons, charged particles, radicals, various excited molecules, UV photons and transient electric fields. These various compositional elements have the potential to either enhance and promote cellular activity, or disrupt and destroy them. In particular, based on this unique composition, CAP could offer a minimally-invasive surgical approach allowing for specific cancer cell or tumor tissue removal without influencing healthy cells. Thus, the objective of this research is to investigate a novel CAP-based therapy for selectively bone metastatic breast cancer treatment. For this purpose, human metastatic breast cancer (BrCa) cells and bone marrow derived human mesenchymal stem cells (MSCs) were separately treated with CAP, and behavioral changes were evaluated after 1, 3, and 5 days of culture. With different treatment times, different BrCa and MSC cell responses were observed. Our results showed that BrCa cells were more sensitive to these CAP treatments than MSCs under plasma dose conditions tested. It demonstrated that CAP can selectively ablate metastatic BrCa cells in vitro without damaging healthy MSCs at the metastatic bone site. In addition, our study showed that CAP treatment can significantly inhibit the migration and invasion of BrCa cells. The results suggest the great potential of CAP for breast cancer therapy. PMID:24040051

Long-lived plasmaspheric plumes: What is the source of the plasma?

NASA Astrophysics Data System (ADS)

Denton, M.; Borovsky, J.; Thomsen, M. F.; Welling, D. T.

2015-12-01

Magnetospheric Plasma Analyzer (MPA) instruments on-board Los Alamos National Laboratory (LANL) satellites regularly measures cold ions in the plasmasphere, and in plasmaspheric plumes. Following periods of calm geomagnetic conditions, the plasmasphere fills to ion number densities in excess of 100 cm-3 - these ions corotate with the Earth. During enhanced convection the outer plasmasphere is eroded - these ions are convected to the dayside magnetopause. LANL/MPA instruments regularly measure plumes which last for many days. On occasion, plumes can last more than two weeks. Such observations raise questions as to the production mechanisms that can continually supply high-number-density material to geosynchronous orbit, and onwards to the magnetopause. We will discuss the plume observations by LANL/MPA, improvements in theoretical modeling of the refilling process, and the need for in-situ observations (from TEC, satellites, etc.) required to address this problem.

Low- and high-order harmonic generation in the extended plasmas produced by laser ablation of zinc and manganese targets

SciTech Connect

Ganeev, R. A., E-mail: rashid-ganeev@mail.ru; Physical Department, Voronezh State University, Voronezh 394006; Baba, M.

The systematic studies of the harmonic generation of ultrashort laser pulses in the 5-mm-long Zn and Mn plasmas (i.e., application of nanosecond, picosecond, and femtosecond pulses for ablation, comparison of harmonic generation from atomic, ionic, and cluster-contained species of plasma, variation of plasma length, two-color pump of plasmas, etc.) are presented. The conversion efficiency of the 11th–19th harmonics generated in the Zn plasma was ∼5 × 10{sup −5}. The role of the ionic resonances of Zn near the 9th and 10th harmonics on the enhancement of harmonics is discussed. The enhancement of harmonics was also analyzed using the two-color pump of extendedmore » plasmas, which showed similar intensities of the odd and even harmonics along the whole range of generation. The harmonics up to the 107th order were demonstrated in the case of manganese plasma. The comparison of harmonic generation in the 5-mm-long and commonly used short (≤0.5 mm) plasma plumes showed the advanced properties of extended media.« less

Thruster Plume Plasma Diagnostics: A Ground Chamber Experiment for a 2-Kilowatt Arcjet

NASA Technical Reports Server (NTRS)

Galofaro, Joel T.; Vayner, Boris V.; Hillard, G. Barry; Chornak, Michael T.

2005-01-01

Although detailed near field (0 to 3 cm) information regarding the exhaust plume of a two kilowatt arc jet is available (refs. 1 to 6), there is virtually little or no information (outside of theoretical extrapolations) available concerning the far field (2.6 to 6.1 m). Furthermore real information about the plasma at distances between (3 to 6 m) is of critical importance to high technology satellite companies in understanding the effect of arc jet plume exhausts on space based power systems. It is therefore of utmost importance that one understands the exact nature of the interaction between the arc jet plume, the spacecraft power system and the surrounding electrical plasma environment. A good first step in understanding the nature of the interactions lies in making the needed plume parameter measurements in the far field. All diagnostic measurements are performed inside a large vacuum system (12 m diameter by 18 m high) with a full scale arc jet and solar array panel in the required flight configuration geometry. Thus, necessary information regarding the plume plasma parameters in the far field is obtained. Measurements of the floating potential, the plasma potential, the electron temperature, number density, density distribution, debye length, and plasma frequency are obtained at various locations about the array (at vertical distances from the arc jet nozzle: 2.6, 2.7, 2.8, 3.2, 3.6, 4.0, 4.9, 5.0, 5.4, 5.75, and 6.14 m). Plasma diagnostic parameters are measured for both the floating and grounded configurations of the arc jet anode and array. Spectroscopic optical measurements are then acquired in close proximity to the nozzle, and contamination measurements are made in the vicinity of the array utilizing a mass spectrometer and two Quartz Crystal Microbalances (QCM's).

Plasma observations during the Mars atmospheric "plume" event of March-April 2012.

PubMed

Andrews, D J; Barabash, S; Edberg, N J T; Gurnett, D A; Hall, B E S; Holmström, M; Lester, M; Morgan, D D; Opgenoorth, H J; Ramstad, R; Sanchez-Cano, B; Way, M; Witasse, O

2016-04-01

We present initial analysis and conclusions from plasma observations made during the reported "Mars plume event" of March - April 2012. During this period, multiple independent amateur observers detected a localized, high-altitude "plume" over the Martian dawn terminator [Sanchez-Lavega et al., Nature, 2015, doi:10.1038/nature14162], the cause of which remains to be explained. The estimated brightness of the plume exceeds that expected for auroral emissions, and its projected altitude greatly exceeds that at which clouds are expected to form. We report on in-situ measurements of ionospheric plasma density and solar wind parameters throughout this interval made by Mars Express, obtained over the same surface region, but at the opposing terminator. Measurements in the ionosphere at the corresponding location frequently show a disturbed structure, though this is not atypical for such regions with intense crustal magnetic fields. We tentatively conclude that the formation and/or transport of this plume to the altitudes where it was observed could be due in part to the result of a large interplanetary coronal mass ejection (ICME) encountering the Martian system. Interestingly, we note that the only similar plume detection in May 1997 may also have been associated with a large ICME impact at Mars.

Fully kinetic simulations of collisionless, mesothermal plasma emission: Macroscopic plume structure and microscopic electron characteristics

NASA Astrophysics Data System (ADS)

Hu, Yuan; Wang, Joseph

2017-03-01

This paper presents a fully kinetic particle particle-in-cell simulation study on the emission of a collisionless plasma plume consisting of cold beam ions and thermal electrons. Results are presented for both the two-dimensional macroscopic plume structure and the microscopic electron kinetic characteristics. We find that the macroscopic plume structure exhibits several distinctive regions, including an undisturbed core region, an electron cooling expansion region, and an electron isothermal expansion region. The properties of each region are determined by microscopic electron kinetic characteristics. The division between the undisturbed region and the cooling expansion region approximately matches the Mach line generated at the edge of the emission surface, and that between the cooling expansion region and the isothermal expansion region approximately matches the potential well established in the beam. The interactions between electrons and the potential well lead to a new, near-equilibrium state different from the initial distribution for the electrons in the isothermal expansion region. The electron kinetic characteristics in the plume are also very anisotropic. As the electron expansion process is mostly non-equilibrium and anisotropic, the commonly used assumption that the electrons in a collisionless, mesothermal plasma plume may be treated as a single equilibrium fluid in general is not valid.

Plume and Discharge Plasma Measurements of an NSTAR-type Ion Thruster

NASA Technical Reports Server (NTRS)

Foster, John E.; Soulas, George C.; Patterson, Michael J.

2000-01-01

The success of the NASA Deep Space 1 spacecraft has demonstrated that ion propulsion is a viable option for deep space science missions. More aggressive missions such as Comet Nuclear Sample Return and Europa lander will require higher power, higher propellant throughput and longer thruster lifetime than the NASA Solar Electric Propulsion Technology Application Readiness (NSTAR) engine. Presented here are thruster plume and discharge plasma measurements of an NSTAR-type thruster operated from 0.5 kW to 5 kW. From Faraday plume sweeps, beam divergence was determined. From Langmuir probe plume measurements on centerline, low energy ion production on axis due to charge-exchange and direct ionization was assessed. Additionally, plume plasma potential measurements made on axis were used to determine the upper energy limits at which ions created on centerline could be radially accelerated. Wall probes flush-mounted to the thruster discharge chamber anode were used to assess plasma conditions. Langmuir probe measurements at the wall indicated significant differences in the electron temperature in the cylindrical and conical sections of the discharge chamber.

Plume and Discharge Plasma Measurements of an NSTAR-type Ion Thruster

NASA Technical Reports Server (NTRS)

Foster, John E; Soulas, George C.; Patterson, Michael J.

2000-01-01

The success of the NASA Deep Space I spacecraft has demonstrated that ion propulsion is a viable option for deep space science missions. More aggressive missions such as Comet Nuclear Sample Return and Europa lander will require higher power, higher propellant throughput and longer thruster lifetime than the NASA Solar Electric Propulsion Technology Application Readiness (NSTAR) engine. Presented here are thruster plume and discharge plasma measurements of an NSTAR-type thruster operated from 0.5 kW to 5 kW. From Faraday plume sweeps, beam divergence was determined. From Langmuir probe plume measurements on centerline, low energy ion production on axis due to charge-exchange and direct ionization was assessed. Additionally, plume plasma potential measurements made on axis were used to determine the upper energy limits at which ions created on centerline could be radially accelerated. Wall probes flush-mounted to the thruster discharge chamber anode were used to assess plasma conditions. Langmuir probe measurements at the wall indicated significant differences in the electron temperature in the cylindrical and conical sections of the discharge chamber.

Space-dependent characterization of laser-induced plasma plume during fiber laser welding

NASA Astrophysics Data System (ADS)

Xiao, Xianfeng; Song, Lijun; Xiao, Wenjia; Liu, Xingbo

2016-12-01

The role of a plasma plume in high power fiber laser welding is of considerable interest due to its influence on the energy transfer mechanism. In this study, the space-dependent plasma characteristics including spectrum intensity, plasma temperature and electron density were investigated using optical emission spectroscopy technique. The plasma temperature was calculated using the Boltzmann plot of atomic iron lines, whereas the electron density was determined from the Stark broadening of the Fe I line at 381.584 nm. Quantitative analysis of plasma characteristics with respect to the laser radiation was performed. The results show that the plasma radiation increases as the laser power increases during the partial penetration mode, and then decreases sharply after the initiation of full penetration. Both the plasma temperature and electron density increase with the increase of laser power until they reach steady state values after full penetration. Moreover, the hottest core of the plasma shifts toward the surface of the workpiece as the penetration depth increases, whereas the electron density is more evenly distributed above the surface of the workpiece. The results also indicate that the absorption and scattering of nanoparticles in the plasma plume is the main mechanism for laser power attenuation.

Time-dependent spectroscopy of plasma plume under laser welding conditions

NASA Astrophysics Data System (ADS)

Hoffman, Jacek; Szymanski, Zygmunt

2004-07-01

Momentary emission spectra of iron and argon lines were measured in a plasma plume induced during welding with a continuous wave CO2 laser. Time-dependent spectra were registered using a fast gate, lens coupled microchannel plate image intensifier placed between a spectrograph and a 1254 silicon intensified target detector connected to an optical multichannel analyser. The results, together with the analysis of the colour images from a fast camera, show that in the case when argon is the shielding gas, two plasmas exist: the argon plasma and the iron plasma. It has been found that during strong bursts the plasma plume over the keyhole consists mainly of metal vapour, not being diluted by the shielding gas. No apparent mixing of the metal vapour and the shielding gas has been observed. The space-averaged electron densities determined from the Stark broadening of the 7503.87, 7514.65 Å Ar I lines amounts to (0.75-1.05) × 1023 m-3 depending on the distance from the surface. Assuming that argon is not mixed with the metal vapour and is in local thermodynamic equilibrium these electron densities correspond to the temperatures of 12-13 kK. At the peaks of strong vapour bursts the space-averaged electron densities determined from the Stark broadening of the 5383.37 Å Fe I line are (0.6-1) × 1023 m-3. Numerical simulations showed that the maximum densities in the plasma centre are considerably higher and amount to ~1.8 × 1023 m-3 and ~2.45 × 1023 m-3 in the case of the argon and metal plasma, respectively. Consequently the absorption of the laser beam in the plasma plume amounts to ~5% of the beam power in the case of argon and 10% in the case of metal plasma.

Plume Characterization of a One-Millipound Solid Teflon Pulsed Plasma Thruster, Phase 2

NASA Technical Reports Server (NTRS)

Rudolph, L. K.; Harstad, K. G.; Pless, L. C.; Jones, R. M.

1979-01-01

Measurements of the pulsed plasma thruster (PPT) plume upstream mass flux were made in the Molecular Sink (MOLSINK) vacuum facility in order to minimize the plume-tank wall reflected mass flux. Using specially designed collimators on 4 rows of Quartz Crystal Microbalanced (QCMs) mounted on a support extending radially away from the plume axis, measurements were made of the mass flux originating in a thin slice of the PPT primary plume at an arbitrary dip angle with respect to the thruster axis. The measured and analytically corrected mass flux from particles reflected from the MOLSINK walls was substracted from the collimated QCM measurements to improve their accuracy. These data were then analytically summed over dip angle to estimate the total plume backflow upstream of the thruster nozzle. The results indicate that the PPT backflow is of order 10 to the minus 10th power g/square cm/pulse in the region from 38 to 86 cm from the PPT axis in the nozzle exit plane. This flux drops with the square of the radial distance from the PPT axis and is comparable to the backflow of an 8 cm ion thruster, which has performance characteristics similar to those of the PPT.

Experimental studies of the effect target geometry on the evolution of laser produced plasma plumes

NASA Astrophysics Data System (ADS)

Beatty, Cuyler; Anderson, Austin; Iratcabal, Jeremy; Dutra, Eric; Covington, Aaron

2016-10-01

The expansion of the laser plumes was shown to be dependent on the initial target geometry. A 16 channel framing camera was used to record the plume shape and propagation speeds were determined from analysis of the images. Plastic targets were manufactured using different methods including 3D printing, CNC machining and vacuum casting. Preliminary target designs were made using a 3D printer and ABS plastic material. These targets were then tested using a 3 J laser with a 5 ns duration pulse. Targets with a deep conical depression were shown to produce highly collimated plumes when compared to flat top targets. Preliminary results of these experiments will be discussed along with planned future experiments that will use the indented targets with a 30 J laser with a 0.8 ns duration pulse in preparation for pinched laser plume experiments at the Nevada Terawatt Facility. Other polymers that are readily available in a deuterated form will also be explored as part of an effort to develop a cost effective plasma plume target for follow on neutron production experiments. Dr. Austin Anderson.

Investigation of the vapour-plasma plume in the welding of titanium by high-power ytterbium fibre laser radiation

SciTech Connect

Bykovskiy, D P; Petrovskii, V N; Uspenskiy, S A

2015-03-31

The vapour-plasma plume produced in the welding of 6-mm thick VT-23 titanium alloy plates by ytterbium fibre laser radiation of up to 10 kW power is studied in the protective Ar gas medium. High-speed video filming of the vapour-plasma plume is used to visualise the processes occurring during laser welding. The coefficient of inverse bremsstrahlung by the welding plasma plume is calculated from the data of the spectrometric study. (interaction of laser radiation with matter)

Spectral diagnostics of a vapor-plasma plume produced during welding titanium with a high-power ytterbium fiber laser

NASA Astrophysics Data System (ADS)

Uspenskiy, S. A.; Petrovskiy, V. N.; Bykovskiy, D. P.; Mironov, V. D.; Prokopova, N. M.; Tret'yakov, E. V.

2015-03-01

This work is devoted to the research of welding plume during high power ytterbium fiber laser welding of a titanium alloy in the Ar shielding gas environment. High speed video observation of a vapor-plasma plume for visualization of processes occurring at laser welding was carried out. The coefficient of the inverse Bremsstrahlung absorption of laser radiation is calculated for a plasma welding plume by results of spectrometer researches. The conclusion deals with the impact of plasma on a high-power fiber laser radiation.

Spectroscopic investigations of beam-plasma interactions in an ion plume

NASA Technical Reports Server (NTRS)

Ruyten, W. M.; Friedly, V. J.; Peng, X.; Celenza, J. A.; Keefer, D.

1993-01-01

We report the results of spectroscopic investigations of beam-plasma interactions in the plume from a 3 cm ion source operated on argon. Ion-electron, ion-neutral, and electron-neutral scattering are identified by studying the dependence of neutral and ion emission intensities on chamber pressure and mass flow rate, and by analyzing the emission lineshapes at a non-orthogonal angle to the plume axis. Through the Doppler shift, we are able to separate contributions from fast beam ions and fast charge-exchange neutrals on the one hand, and of slow neutrals and slow ions on the other. We discuss the application of this new technique to the characterization of beam plasma interactions in the downstream region of ion thruster engines, and its potential for identifying the processes which lead to grid erosion.

Local Neutral Density and Plasma Parameter Measurements in a Hollow Cathode Plume

NASA Technical Reports Server (NTRS)

Jameson, Kristina K.; Goebel, Dan M.; MiKellides, Joannis; Watkins, Ron M.

2006-01-01

In order to understand the cathode and keeper wear observed during the Extended Life Test (ELT) of the DS1 flight spare NSTAR thruster and provide benchmarking data for a 2D cathode/cathode-plume model, a basic understanding of the plasma and neutral gas parameters in the cathode orifice and keeper region of the cathode plume must be obtained. The JPL cathode facility is instrumented with an array of Langmuir probe diagnostics along with an optical diagnostic to measure line intensity of xenon neutrals. In order to make direct comparisons with the present model, a flat plate anode arrangement was installed for these tests. Neutral density is deduced from the scanning probe data of the plasma parameters and the measured xenon line intensity in the optical regime. The Langmuir probes are scanned both axially, out to 7.0 cm downstream of the keeper, and radially to obtain 2D profile of the plasma parameters. The optical fiber is housed in a collimating stainless steel tube, and is scanned to view across the cathode plume along cuts in front of the keeper with a resolution of 1.5 mm. The radial intensities are unfolded using the Abel inversion technique that produces radial profiles of local neutral density. In this paper, detailed measurements of the plasma parameters and the local neutral densities will be presented in the cathode/keeper plume region for a 1.5 cm diameter NEXIS cathode at 25A of discharge current at several different strengths of applied magnetic field.

Iodine Plasma Species Measurements in a Hall Effect Thruster Plume

DTIC Science & Technology

2013-05-01

with an ExB probe , an electrostatic analyzer (ESA), and a combined ESA/ExB probe . The distribution of xenon ions was also measured. Multiply charge...of iodine ions was measured with an ExB probe , an electrostatic analyzer (ESA), and a combined ESA/ExB probe . • Results: – Multiply charged species...Test Hardware – Vacuum test facility (6’ diameter) – Faraday probe (MIT) – ESA, ExB, ESA/ExB Probes (Plasma Controls) – Rotary probe arm (about

A uniform laminar air plasma plume with large volume excited by an alternating current voltage

NASA Astrophysics Data System (ADS)

Li, Xuechen; Bao, Wenting; Chu, Jingdi; Zhang, Panpan; Jia, Pengying

2015-12-01

Using a plasma jet composed of two needle electrodes, a laminar plasma plume with large volume is generated in air through an alternating current voltage excitation. Based on high-speed photography, a train of filaments is observed to propagate periodically away from their birth place along the gas flow. The laminar plume is in fact a temporal superposition of the arched filament train. The filament consists of a negative glow near the real time cathode, a positive column near the real time anode, and a Faraday dark space between them. It has been found that the propagation velocity of the filament increases with increasing the gas flow rate. Furthermore, the filament lifetime tends to follow a normal distribution (Gaussian distribution). The most probable lifetime decreases with increasing the gas flow rate or decreasing the averaged peak voltage. Results also indicate that the real time peak current decreases and the real time peak voltage increases with the propagation of the filament along the gas flow. The voltage-current curve indicates that, in every discharge cycle, the filament evolves from a Townsend discharge to a glow one and then the discharge quenches. Characteristic regions including a negative glow, a Faraday dark space, and a positive column can be discerned from the discharge filament. Furthermore, the plasma parameters such as the electron density, the vibrational temperature and the gas temperature are investigated based on the optical spectrum emitted from the laminar plume.

Steady and oscillatory plasma properties in the near-field plume of a hollow cathode

NASA Astrophysics Data System (ADS)

Zun, ZHANG; Kan, XIE; Jiting, OUYANG; Ning, GUO; Yu, QIN; Qimeng, XIA; Song, BAI; Xianming, WU; Zengjie, GU

2018-02-01

Hollow cathodes serve as electron sources in Hall thrusters, ion thrusters and other electric propulsion systems. One of the vital problems in their application is the cathode erosion. However, the basic erosion mechanism and the source of high-energy ions cause of erosion are not fully understood. In this paper, both potential measurements and simulation analyses were performed to explain the formation of high-energy ions. A high-speed camera, a single Langmuir probe and a floating emissive probe were used to determine the steady and oscillatory plasma properties in the near-field plume of a hollow cathode. The temporal structure, electron temperature, electron density, and both static and oscillation of plasma potentials of the plume have been obtained by the diagnostics mentioned above. The experimental results show that there exists a potential hill (about 30 V) and also severe potential oscillations in the near-plume region. Moreover, a simple 2D particle-in-cell model was used to analyze the energy transition between the potential hill and/or its oscillations and the ions. The simulation results show that the energy of ions gained from the static potential background is about 20 eV, but it could reach to 60 eV when the plasma oscillates.

Physical Simulation of a Prolonged Plasma-Plume Exposure of a Space Debris Object

NASA Astrophysics Data System (ADS)

Shuvalov, V. A.; Gorev, N. B.; Tokmak, N. A.; Kochubei, G. S.

2018-05-01

A methodology has been developed for the physical (laboratory) simulation of the prolonged exposure of a space debris object to high-energy ions of a plasma plume for removing the object into low-Earth orbit with its subsequent burning in the Earth's atmosphere. The methodology is based on the equivalence criteria of two modes of exposure (in the Earth's ionosphere and in the setup) and the procedure for accelerated resource tests in terms of the sputtering of the space debris material and its deceleration by a plasma jet in the Earth's ionosphere.

Electrostatic measurement of plasma plume characteristics in pulsed laser evaporated carbon

NASA Astrophysics Data System (ADS)

Mayo, R. M.; Newman, J. W.; Sharma, A.; Yamagata, Y.; Narayan, J.

1999-09-01

A triple Langmuir probe measurement has been implemented to investigate plasma plume character in low fluence (˜3.0 J/cm2) pulsed laser evaporation (PLE) discharges and has been found to be an extremely valuable tool. Absolute plasma plume density estimates are found to reside in the range 1.0×1013-2.0×1014cm-3 for vacuum pulses. A simple heavy particle streaming model for vacuum pulses allows estimates of the plume ionization fraction of ˜10%. This is consistent with typical deposition inventory suggesting that high kinetic energy ions may play an important role in diamond-like carbon (DLC) film deposition. Electron temperature inferred from the electrostatic probe is found to consistently reside in the range 0.5-3.0 eV, and appears to be uninfluenced by operating conditions and large variations in Ar and N2 fill gas pressure. Consistent with strong plume ion and neutral particle coupling to the background fill, constancy of Te suggests expulsion of background gas by the energetic plume. The leading edge ion plume speed is measured via temporal displacement of spatially separated probe signals on consecutive PLE pulses. Flow speeds as high as 5.0×104m/s are observed, corresponding to ˜156 eV in C+. The ion flow speed is found to be a strongly decreasing function of fill pressure from an average high of ˜126 eV in vacuum to ˜0.24 eV at 600 mTorr N2. Raman scattering spectroscopy indicates DLC film quality also degrades with fill pressure suggesting the importance of high ion kinetic energy in producing good quality films, consistent with earlier work demonstrating the importance of energetic particles. Optical emission indicates an increase in C2 molecular light intensity with fill gas pressure implying a reduced, if any, role of these species in DLC production. Ion current signal anomalies are often seen during high pressure pulses. It is suggested that this may indicate the formation of high mass carbon clusters during plume evolution in the presence of

Characterization of a 50kW Inductively Coupled Plasma Torch for Testing of Ablative Thermal Protection Materials

NASA Technical Reports Server (NTRS)

Greene, Benton R.; Clemens, Noel T.; Varghese, Philip L.; Bouslog, Stanley A.; Del Papa, Steven V.

2017-01-01

With the development of new manned spaceflight capabilities including NASA's Orion capsule and the Space-X Dragon capsule, there is a renewed importance of understanding the dynamics of ablative thermal protection systems. To this end, a new inductively coupled plasma torch facility is being developed at UT-Austin. The torch operates on argon and/or air at plasma powers up to 50 kW. In the present configuration the flow issues from a low-speed subsonic nozzle and the hot plume is characterized using slug calorimetry and emission spectroscopy. Preliminary measurements using emission spectroscopy have indicated that the torch is capable of producing an air plasma with a temperature between 6,000 K and 8,000 K depending on the power and flow settings and an argon plasma with a temperature of approximately 12,000 K. The operation envelope was measured, and heat flux measured for every point within the envelope using both a slug calorimeter and a Gardon gauge heat flux sensor. The torch was found to induce a stagnation point heat flux of between 90 and 225 W/sq cm.

A linear-field plasma jet for generating a brush-shaped laminar plume at atmospheric pressure

SciTech Connect

Li, Xuechen; Jia, Pengying, E-mail: plasmalab@126.com; Key Laboratory of Photo-Electronics Information Materials of Hebei Province, Baoding 071002

2016-06-15

A linear-field plasma jet composed of line-to-plate electrodes is used to generate a large-scale brush-shaped plasma plume with flowing argon used as working gas. Through electrical measurement and fast photography, it is found that the plasma plume bridges the two electrodes for the discharge in the positive voltage half-cycle, which behaves like fast moving plasma bullets directed from the anode to the cathode. Compared with the positive discharge, the negative discharge only develops inside the nozzle and propagates much slower. Results also indicate that the gas temperature of the plume is close to room temperature, which is promising for biomedicalmore » application.« less

Hybrid 3D model for the interaction of plasma thruster plumes with nearby objects

NASA Astrophysics Data System (ADS)

Cichocki, Filippo; Domínguez-Vázquez, Adrián; Merino, Mario; Ahedo, Eduardo

2017-12-01

This paper presents a hybrid particle-in-cell (PIC) fluid approach to model the interaction of a plasma plume with a spacecraft and/or any nearby object. Ions and neutrals are modeled with a PIC approach, while electrons are treated as a fluid. After a first iteration of the code, the domain is split into quasineutral and non-neutral regions, based on non-neutrality criteria, such as the relative charge density and the Debye length-to-cell size ratio. At the material boundaries of the former quasineutral region, a dedicated algorithm ensures that the Bohm condition is met. In the latter non-neutral regions, the electron density and electric potential are obtained by solving the coupled electron momentum balance and Poisson equations. Boundary conditions for both the electric current and potential are finally obtained with a plasma sheath sub-code and an equivalent circuit model. The hybrid code is validated by applying it to a typical plasma plume-spacecraft interaction scenario, and the physics and capabilities of the model are finally discussed.

Simulation of ablation and plume dynamics under femtosecond double-pulse laser irradiation of aluminum: Comparison of atomistic and continual approaches

NASA Astrophysics Data System (ADS)

Fokin, Vladimir B.; Povarnitsyn, Mikhail E.; Levashov, Pavel R.

2017-02-01

We elaborated two numerical methods, two-temperature hydrodynamics and hybrid two-temperature molecular dynamics, which take into account basic mechanisms of a metal target response to ultrashort laser irradiation. The model used for the description of the electronic subsystem is identical for both approaches, while the ionic part is defined by an equation of state in hydrodynamics and by an interatomic potential in molecular dynamics. Since the phase diagram of the equation of state and corresponding potential match reasonably well, the dynamics of laser ablation obtained by both methods is quite similar. This correspondence can be considered as a first step towards the development of a self-consistent combined model. Two important processes are highlighted in simulations of double-pulse ablation: (1) the crater depth decrease as a result of recoil flux formation in the nascent plume when the delay between the pulses increases; (2) the plume reheating by the second pulse that gives rise to two- three-fold growth of the electron temperature with the delay varying from 0 to 200 ps.

Modification of modulated plasma plumes for the quasi-phase-matching of high-order harmonics in different spectral ranges

SciTech Connect

Ganeev, R. A., E-mail: rashid-ganeev@mail.ru; Ophthalmology and Advanced Laser Medical Center, Saitama Medical University, Saitama 350-0495; Boltaev, G. S.

We demonstrate the technique allowing the fine tuning of the distance between the laser-produced plasma plumes on the surfaces of different materials, as well as the variation of the sizes of these plumes. The modification of plasma formations is based on the tilting of the multi-slit mask placed between the heating laser beam and target surface, as well as the positioning of this mask in the telescope placed on the path of heating radiation. The modulated plasma plumes with the sizes of single plume ranging between 0.1 and 1 mm were produced on the manganese and silver targets. Modification of themore » geometrical parameters of plasma plumes proved to be useful for the fine tuning of the quasi-phase-matched high-order harmonics generated in such structures during propagation of the ultrashort laser pulses. We show the enhancement of some groups of harmonics along the plateau range and the tuning of maximally enhanced harmonic by variable modulation of the plasma.« less

Optical radiative properties of ablating polymers exposed to high-power arc plasmas

NASA Astrophysics Data System (ADS)

Becerra, Marley; Pettersson, Jonas

2018-03-01

The radiative properties of polymers exposed to high-intensity radiation are of importance for the numerical simulation of arc-induced ablation. The paper investigates the optical properties of polymethylmethacrylate PMMA and polyamide PA6 films exposed to high-power arc plasmas, which can cause ablation of the material. A four-flux radiative approximation is first used to estimate absorption and scattering coefficients of the tested materials in the ultraviolet (UV) and in the visible (VIS) ranges from spectrophotometric measurements. The temperature-induced variation of the collimated transmissivity of the polymers is also measured from room temperature to the glass temperature of PMMA and the melting temperature of PA6. Furthermore, band-averaged absorption and scattering coefficients of non-ablating and ablating polymers are estimated from the UV to the short-wavelength infrared (SWIR), covering the range of interest for the simulation of arc-induced ablation. These estimates are obtained from collimated transmissivities measured with an additional in situ photometric system that uses a high-power, transient arc plasma to both illuminate the samples and to induce ablation. It is shown that the increase in the bulk temperature of PA6 leads to a strong reversible increase in collimated transmissivity, significantly reducing the absorption and scattering coefficients of the material. A weaker but opposite effect of temperature on the optical properties is found in PMMA. As a consequence, it is suggested that the absorption coefficient of polymers used for arc-induced ablation estimates should not be taken directly from direct collimated transmissivity measurements at room temperature. The band-averaged radiation measurements also show that the layer of products released by ablation of PMMA produces scattering radiation losses mainly in the VIS-SWIR ranges, which are only a small fraction of the total incident arc radiation. In a similar manner, the ablation layer

Spectroscopy Measurements on Ablation Testing in High Enthalpy Plasma Flows

DTIC Science & Technology

2010-11-01

sample as well as the recession rate. Further, the chemical composition of the free- stream and the surrounding gas layer in front of the sample...of the samples due to ablation (mass loss & surface recession ), different temperature measurements (surface & inside) and spectroscopic results...25 5 MEASUREMENT RESULTS AND DISCUSSIONS ................................................................ 26 5.1 MASS LOSS AND RECESSION

Optical emission spectroscopic study of plasma plumes generated by IR CO2 pulsed laser on carbon targets

NASA Astrophysics Data System (ADS)

Camacho, J. J.; Díaz, L.; Santos, M.; Reyman, D.; Poyato, J. M. L.

2008-05-01

Optical emission spectroscopy studies, in the spectral range ultraviolet-visible-near infrared (UV-Vis-NIR), were performed to investigate thermal and dynamical properties of a plume produced by laser ablation of a graphite target. Ablation is carried out using a high-power IR CO2 pulsed laser at λ = 9.621 µm, power density ranging from 0.22 to 5.36 GW cm-2 and air pressures around 4 Pa. The strong emission observed in the plasma region is mainly due to electronic relaxation of excited C, ionic fragments C+, C2+ and C3+ and molecular features of C2(d 3Πg-a 3Πu Swan band system). The medium-weak emission is mainly due to excited atomic N, H, O, ionic fragment C4+ and molecular features of C2( E\\,^1\\Sigma _g^+\\--A\\,^{1}\\Pi _u ; Freymark system), C2( D\\,^1\\Sigma _u^+\\--X\\,^1\\Sigma _g^+ ; Mulliken system), CN(D 2Π-A 2Π), C2(e 3Πg-a 3Πu Fox-Herzberg system), C2(C 1Πg-A 1Πu Deslandres-d'Azambuja system), OH(A 2Σ+-X 2Π), CH(C 2Σ+-X 2Π), NH(A 3Π-X 3Σ-), CN(B 2Σ+-X 2Σ+ violet system), CH(B 2Σ+-X 2Π), CH(A 2Δ-X 2Π), C2( A\\,^{1}\\Pi_u\\--X\\,^{1}\\Sigma ^{+}_g ; Phillips system) and CN(A 2Π-X 2Σ+ red system). An excitation temperature Texc = 23 000 ± 1900 K and electron densities in the range (0.6-5.6) × 1016 cm-3 were estimated by means of C+ ionic lines. The characteristics of the spectral emission intensities from different species have been investigated as functions of the ambient pressure and laser irradiance. Estimates of vibrational temperatures of C2 and CN electronically excited species under various laser irradiance conditions are made.

Wall ablation of heated compound-materials into non-equilibrium discharge plasmas

NASA Astrophysics Data System (ADS)

Wang, Weizong; Kong, Linghan; Geng, Jinyue; Wei, Fuzhi; Xia, Guangqing

2017-02-01

The discharge properties of the plasma bulk flow near the surface of heated compound-materials strongly affects the kinetic layer parameters modeled and manifested in the Knudsen layer. This paper extends the widely used two-layer kinetic ablation model to the ablation controlled non-equilibrium discharge due to the fact that the local thermodynamic equilibrium (LTE) approximation is often violated as a result of the interaction between the plasma and solid walls. Modifications to the governing set of equations, to account for this effect, are derived and presented by assuming that the temperature of the electrons deviates from that of the heavy particles. The ablation characteristics of one typical material, polytetrafluoroethylene (PTFE) are calculated with this improved model. The internal degrees of freedom as well as the average particle mass and specific heat ratio of the polyatomic vapor, which strongly depends on the temperature, pressure and plasma non-equilibrium degree and plays a crucial role in the accurate determination of the ablation behavior by this model, are also taken into account. Our assessment showed the significance of including such modifications related to the non-equilibrium effect in the study of vaporization of heated compound materials in ablation controlled arcs. Additionally, a two-temperature magneto-hydrodynamic (MHD) model accounting for the thermal non-equilibrium occurring near the wall surface is developed and applied into an ablation-dominated discharge for an electro-thermal chemical launch device. Special attention is paid to the interaction between the non-equilibrium plasma and the solid propellant surface. Both the mass exchange process caused by the wall ablation and plasma species deposition as well as the associated momentum and energy exchange processes are taken into account. A detailed comparison of the results of the non-equilibrium model with those of an equilibrium model is presented. The non-equilibrium results

Long-wave plasma radiofrequency ablation for treatment of xanthelasma palpebrarum.

PubMed

Baroni, Adone

2018-03-01

Xanthelasma palpebrarum is the most common type of xanthoma affecting the eyelids. It is characterized by asymptomatic soft yellowish macules, papules, or plaques over the upper and lower eyelids. Many treatments are available for management of xanthelasma palpebrarum, the most commonly used include surgical excision, ablative CO 2 or erbium lasers, nonablative Q-switched Nd:YAG laser, trichloroacetic acid peeling, and radiofrequency ablation. This study aims to evaluate the effectiveness of RF ablation in the treatment of xanthelasma palpebrarum, with D.A.S. Medical portable device (Technolux, Italia), a radiofrequency tool working with long-wave plasma energy and without anesthesia. Twenty patients, 15 female and 5 male, affected by xanthelasma palpebrarum, were enrolled for long-wave plasma radiofrequency ablation treatment. The treatment consisted of 3/4 sessions that were carried out at intervals of 30 days. Treatments were well tolerated by all patients with no adverse effects and optimal aesthetic results. The procedure is very fast and can be performed without anesthesia because of the low and tolerable pain stimulation. Long-wave plasma radiofrequency ablation is an effective option for treatment of xanthelasma palpebrarum and adds an additional tool to the increasing list of medical devices for aesthetic treatments. © 2018 Wiley Periodicals, Inc.

Plasma plume diagnostics of low power stationary plasma thruster (SPT-20M8) with collisional radiative model

NASA Astrophysics Data System (ADS)

Uttamsing Rajput, Rajendrasing; Alona, Khaustova; Loyan, Andriy V.

2017-03-01

Electric propulsion offers higher specific impulse compared to the chemical propulsion systems. It reduces the overall propellant mass and enables high operational lifetimes. Scientific Technological Center of Space Power and Energy (STC SPE), KhAI is involved in designing, manufacturing and testing of stationary plasma thrusters (SPT). Efforts are made to perform plasma diagnostics with corona and collisional radiative models (C-R model), as expected corona model falls short below 4 eV because of the heavy particle collisions elimination, whereas the C-R model's applicability is confirmed. Several tests are performed to analyze the electron temperature at various operational parameters of thruster like discharge voltage and mass flow rate. SPT-20M8 far and near-field plumes diagnostics are performed. Feasibility of C-R model by comparing its result to optical emission spectroscopy (OES) to investigate the electron temperature is validated with the probe measurements within the 10% of discrepancy.

[Voice acoustic study of plasma radiofrequency ablation for the treatment of laryngeal premalignant lesions].

PubMed

Zang, Y Z; Wan, B L; Jia, X D; Wang, G K

2016-11-01

Objective: To study the voice function effect of low temperature plasma radiofrequency ablation in the treatment of patients with laryngeal premalignant lesions. Method: Fifty cases of laryngeal premalignant lesions were treated with low temperature plasma radiofrequency ablation. All of the patients were examined by electronic laryngoscopy and acoustic analysis(F0，Jitter，Shimmer，NNE，HNR) in 2 weeks,1 month,3 months after surgery. Voice acoustic results were compared with a control group of 50 normal adults for the further analysis. Result: Fifty patients with laryngeal premalignant lesions were treated by low temperature plasma radiofrequency ablation.The result showed that 47 patients(94%)were successfully decannulated without serious complications, such as dyspnea, aphonia and anterior glottic stenosis. Acoustic analysis showed that F0,Jitter,Shimmer and NNE were significantly different from normal 2 weeks after surgery（ P <0.01）.Voice function recovered weakly 1 month after operation（ P <0.05）.There were no significant differences in the vocal parameters between plasma radiofrequency ablation group and control group 3 months after surgery( P >0.05). Conclusion: Radiofrequency coblation was a safe,minimally invasive and effective surgical method and can be widely used to treat laryngeal premalignant lesions．. Copyright© by the Editorial Department of Journal of Clinical Otorhinolaryngology Head and Neck Surgery.

Low pressure laser ablation coupled to inductively coupled plasma mass spectrometry

NASA Astrophysics Data System (ADS)

Fliegel, Daniel; Günther, Detlef

2006-07-01

The particle size distribution in laser ablation inductively coupled plasma mass spectrometry is known to be a critical parameter for complete vaporization of particles. Any strategy to reduce the particle size distribution of laser generated aerosols has the potential to increase the ion signal intensity and to reduce fractionation effects. Due to the fact that vapor generation, nucleation, condensation, and agglomeration take place within an extremely short period of time, ablation under atmospheric pressure might not allow influencing these processes while under reduced pressure condition the cooling of the aerosol and therefore the condensation is expected to be slower. In this study, a low pressure laser ablation cell for the generation of laser aerosols was coupled to an ICP-MS. In contrast to the previously developed trapped ablation mode, the newly designed cell allows the adjustment of the pressure in the ablation cell between 20 and 1400 mbar prior to the ablation. Ablation experiments carried out using this configuration showed a dependence of the aerosol properties (size distribution and particle structure) on the ablation cell pressure. The intensity ratio U/Th measured as a figure of merit for complete vaporization within the ICP indicated a change in the aerosol structure at approximately 500 mbar toward smaller particle size. A significant difference between low pressure and at ambient pressure ablated aerosol was observed. The intensity ratios (U/Th) of the ablated sample moves closer to the bulk composition at lower pressures at the expense of sensitivity. Therefore the decrease in the ICP-MS signal intensity in the low pressure cell can be attributed to vapor deposition within the ablation cell walls. Moreover, scanning electron microscope images of aerosols collected on filters after the low pressure ablation cell suggest the possibility of a slower cooling velocity of the aerosol, which was observed in the condensed material on the surface of

Pulsed Plasma Thruster Plume Study: Symmetry and Impact on Spacecraft Surfaces

NASA Technical Reports Server (NTRS)

Arrington, Lynn A.; Marrese, Colleen M.; Blandino, John J.

2000-01-01

Twenty-four witness plates were positioned on perpendicular arrays near a breadboard Pulsed Plasma Thruster (PPT) to collect plume constituents for analysis. Over one million shots were fired during the experiment at 43 J using fluorocarbon polymer propellant. The asymmetry of the film deposition on the witness plates was investigated with mass and thickness measurements and correlated with off-axis thrust vector measurements. The composition of the films was determined. The transmittance and reflectance of the films were measured and the absorption coefficients were calculated in the wavelength range from 350 to 1200 mn. These data were applied to calculate the loss in signal intensity through the films, which will impact the visibility of spaceborne interferometer systems positioned by these thrusters.

Design, Fabrication, and Testing of Emissive Probes to Determine the Plasma Potential of the Plumes of Various Electric Thrusters

NASA Technical Reports Server (NTRS)

Chen, Erinna M.

2005-01-01

A significant problem in the use of electric thrusters in spacecraft is the formation of low-energy ions in the thruster plume. Low-energy ions are formed in the plume via random collisions between high-velocity ions ejected from the thruster and slow-moving neutral atoms of propellant effusing from the engine. The sputtering of spacecraft materials due to interactions with low-energy ions may result in erosion or contamination of the spacecraft. The trajectory of these ions is determined primarily by the plasma potential of the plume. Thus, accurate characterization of the plasma potential is essential to predicting low-energy ion contamination. Emissive probes were utilized to determine the plasma potential. When the ion and electron currents to the probe are balanced, the potential of such probes float to the plasma potential. Two emissive probes were fabricated; one utilizing a DC power supply, another utilizing a rectified AC power source. Labview programs were written to coordinate and automate probe motion in the thruster plume. Employing handshaking interaction, these motion programs were synchronized to various data acquisition programs to ensure precision and accuracy of the measurements. Comparing these experimental values to values from theoretical models will allow for a more accurate prediction of low-energy ion interaction.

Infrared nanosecond laser-metal ablation in atmosphere: Initial plasma during laser pulse and further expansion

SciTech Connect

Wu, Jian; Wei, Wenfu; Li, Xingwen

2013-04-22

We have investigated the dynamics of the nanosecond laser ablated plasma within and after the laser pulse irradiation using fast photography. A 1064 nm, 15 ns laser beam was focused onto a target made from various materials with an energy density in the order of J/mm{sup 2} in atmosphere. The plasma dynamics during the nanosecond laser pulse were observed, which could be divided into three stages: fast expansion, division into the primary plasma and the front plasma, and stagnation. After the laser terminated, a critical moment when the primary plasma expansion transited from the shock model to the drag modelmore » was resolved, and this phenomenon could be understood in terms of interactions between the primary and the front plasmas.« less

Investigation on the Characteristics of Pellet Ablation in a Toroidal Plasma

NASA Astrophysics Data System (ADS)

Sato, K. N.; Sakakita, H.; Fujita, H.

2003-06-01

Characteristics of a cloud ablated from an ice pellet has been investigated in detail in the JIPP T-IIU tokamak plasma by utilizing a new scheme of pellet injection system, "the injection-angle controllable system". A long "helical tail" of ablation light has been observed using CCD cameras and a high speed framing photograph in the case of on-axis and off-axis injection with the injection angle smaller than a certain value. The direction of the helical tail is found to be independent to that of the total magnetic field lines of the torus. From the experiments with the combination of two toroildal filed directions and two plasma current directions, it is considered that the tail seems to rotate, in most cases, to the electron diamagnetic direction poloidally, and to the opposite to the plasma current direction toroidally. Consideration on various cross sections including charge exchange, ionization and elastic collisions leads us to the conclusion that the tail-shaped phenomena may come from the situation of charge exchange equilibrium of hydrogen ions and neutrals at extremely high density regime in the cloud. The relation of ablation behavior with plasma potential and rotation has also been studied. Potential measurements of pellet-injected plasmas using heavy ion beam probe (HIBP) method were carried out for the first time. In the case of an injection angle to be anti-parallel to the electron diamagnetic direction in the poloidal plane, the result shows that the direction of potential change is negative, and consequently the potential after the injection should be negative because it has been measured to be negative in usual ohmic plasmas without pellet injection. Thus, the direction of the "tail" structure seems to be consistent to that of the plasma potential measured, if it is considered that tail structure may be caused by the effect of the plasma potential and the rotation.

Numerical-experimental analysis of a carbon-phenolic composite via plasma jet ablation test

NASA Astrophysics Data System (ADS)

Guilherme Silva Pesci, Pedro; Araújo Machado, Humberto; Silva, Homero de Paula e.; Cley Paterniani Rita, Cristian; Petraconi Filho, Gilberto; Cocchieri Botelho, Edson

2018-06-01

Materials used in space vehicles components are subjected to thermally aggressive environments when exposed to atmospheric reentry. In order to protect the payload and the vehicle itself, ablative composites are employed as TPS (Thermal Protection System). The development of TPS materials generally go through phases of obtaining, atmospheric reentry tests and comparison with a mathematical model. The state of the art presents some reentry tests in a subsonic or supersonic arc-jet facility, and a complex type of mathematical model, which normally requires large computational cost. This work presents a reliable method for estimate the performance of ablative composites, combining empirical and experimental data. Tests of composite materials used in thermal protection systems through exposure to a plasma jet are performed, where the heat fluxes emulate those present in atmospheric reentry of space vehicles components. The carbon/phenolic material samples have been performed in the hypersonic plasma tunnel of Plasma and Process Laboratory, available in Aeronautics Institute of Technology (ITA), by a plasma torch with a 50 kW DC power source. The plasma tunnel parameters were optimized to reproduce the conditions close to the critical re-entry point of the space vehicles payloads developed by the Aeronautics and Space Institute (IAE). The specimens in study were developed and manufactured in Brazil. Mass loss and specific mass loss rates of the samples and the back surface temperatures, as a function of the exposure time to the thermal flow, were determined. A computational simulation based in a two-front ablation model was performed, in order to compare the tests and the simulation results. The results allowed to estimate the ablative behavior of the tested material and to validate the theoretical model used in the computational simulation for its use in geometries close to the thermal protection systems used in the Brazilian space and suborbital vehicles.

A feasibility study and mission analysis for the Hybrid Plume Plasma Rocket

NASA Technical Reports Server (NTRS)

Sullivan, Daniel J.; Micci, Michael M.

1990-01-01

The Hybrid Plume Plasma Rocket (HPPR) is a high power electric propulsion concept which is being developed at the MIT Plasma Fusion Center. This paper presents a theoretical overview of the concept as well as the results and conclusions of an independent study which has been conducted to identify and categorize those technologies which require significant development before the HPPR can be considered a viable electric propulsion device. It has been determined that the technologies which require the most development are high power radio-frequency and microwave generation for space applications and the associated power processing units, low mass superconducting magnets, a reliable, long duration, multi-megawatt space nuclear power source, and long term storage of liquid hydrogen propellant. In addition to this, a mission analysis of a one-way transfer from low earth orbit (LEO) to Mars indicates that a constant acceleration thrust profile, which can be obtained using the HPPR, results in faster trip times and greater payload capacities than those afforded by more conventional constant thrust profiles.

Mass ablation and magnetic flux losses through a magnetized plasma-liner wall interface

NASA Astrophysics Data System (ADS)

García-Rubio, F.; Sanz, J.

2017-07-01

The understanding of energy and magnetic flux losses in a magnetized plasma medium confined by a cold wall is of great interest in the success of magnetized liner inertial fusion (MagLIF). In a MagLIF scheme, the fuel is magnetized and subsonically compressed by a cylindrical liner. Magnetic flux conservation is degraded by the presence of gradient-driven transport processes such as thermoelectric effects (Nernst) and magnetic field diffusion. In previous publications [Velikovich et al., Phys. Plasmas 22, 042702 (2015)], the evolution of a hot magnetized plasma in contact with a cold solid wall (liner) was studied using the classical collisional Braginskii's plasma transport equations in one dimension. The Nernst term degraded the magnetic flux conservation, while both thermal energy and magnetic flux losses were reduced with the electron Hall parameter ωeτe with a power-law asymptotic scaling (ωeτe)-1/2. In the analysis made in the present paper, we consider a similar situation, but with the liner being treated differently. Instead of a cold solid wall acting as a heat sink, we model the liner as a cold dense plasma with low thermal conduction (that could represent the cryogenic fuel layer added on the inner surface of the liner in a high-gain MagLIF configuration). Mass ablation comes into play, which adds notably differences to the previous analysis. The direction of the plasma motion is inverted, but the Nernst term still convects the magnetic field towards the liner. Magnetization suppresses the Nernst velocity and improves the magnetic flux conservation. Thermal energy in the hot plasma is lost in heating the ablated material. When the electron Hall parameter is large, mass ablation scales as (ωeτe)-3/10, while both the energy and magnetic flux losses are reduced with a power-law asymptotic scaling (ωeτe)-7/10.

Laser ablation inductively coupled plasma mass spectrometry measurement of isotope ratios in depleted uranium contaminated soils.

PubMed

Seltzer, Michael D

2003-09-01

Laser ablation of pressed soil pellets was examined as a means of direct sample introduction to enable inductively coupled plasma mass spectrometry (ICP-MS) screening of soils for residual depleted uranium (DU) contamination. Differentiation between depleted uranium, an anthropogenic contaminant, and naturally occurring uranium was accomplished on the basis of measured 235U/238U isotope ratios. The amount of sample preparation required for laser ablation is considerably less than that typically required for aqueous sample introduction. The amount of hazardous laboratory waste generated is diminished accordingly. During the present investigation, 235U/238U isotope ratios measured for field samples were in good agreement with those derived from gamma spectrometry measurements. However, substantial compensation was required to mitigate the effects of impaired pulse counting attributed to sample inhomogeneity and sporadic introduction of uranium analyte into the plasma.

Distinctive plume formation in atmospheric Ar and He plasmas in microwave frequency band and suitability for biomedical applications

SciTech Connect

Lee, H. Wk.; Kang, S. K.; Won, I. H.

Distinctive discharge formation in atmospheric Ar and He plasmas was observed in the microwave frequency band using coaxial transmission line resonators. Ar plasmas formed a plasma plume whereas He formed only confined plasmas. As the frequency increased from 0.9 GHz to 2.45 GHz, the Ar plasma exhibited contraction and filamentation, and the He plasmas were constricted. Various powers and gas flow rates were applied to identify the effect of the electric field and gas flow rate on plasma plume formation. The He plasmas were more strongly affected by the electric field than the Ar plasmas. The breakdown and sustain powersmore » yielded opposite results from those for low-frequency plasmas (∼kHz). The phenomena could be explained by a change in the dominant ionization process with increasing frequency. Penning ionization and the contribution of secondary electrons in sheath region reduced as the frequency increased, leading to less efficient ionization of He because its ionization and excitation energies are higher than those of Ar. The emission spectra showed an increase in the NO and N{sub 2} second positive band in both the Ar and He plasmas with increasing frequency whereas the hydroxyl radical and atomic O peaks did not increase with increasing frequency but were highest at particular frequencies. Further, the frequency effect of properties such as the plasma impedance, electron density, and device efficiency were presented. The study is expected to be helpful for determining the optimal conditions of plasma systems for biomedical applications.« less

Experimental scaling law for mass ablation rate from a Sn plasma generated by a 1064 nm laser

NASA Astrophysics Data System (ADS)

Burdt, Russell A.; Yuspeh, Sam; Sequoia, Kevin L.; Tao, Yezheng; Tillack, Mark S.; Najmabadi, Farrokh

2009-08-01

The ablation depth in planar Sn targets irradiated with a pulsed 1064 nm laser was investigated over laser intensities from 3×1011 to 2×1012 W/cm2. The ablation depth was measured by irradiating a thin layer of Sn evaporated onto a Si wafer, and looking for signatures of Si ions in the expanding plasma with spectroscopic and particle diagnostics. It was found that ablation depth scales with laser intensity to the (5/9)th power, which is consistent with analytical models of steady-state laser ablation, as well as empirical formulae from previous studies of mass ablation rate in overlapping parameter space. In addition, the scaling of mass ablation rate with atomic number of the target as given by empirical formulae in previous studies using targets such as C and Al, are shown to remain valid for the higher atomic number of the target (Z =50) used in these experiments.

Filamentation due to the Weibel instability in two counterstreaming laser ablated plasmas

DOE PAGES

Dong, Quan -Li; Yuan, Dawei; Gao, Lan; ...

2016-05-01

Weibel-type filamentation instability was observed in the interaction of two counter streaming laser ablated plasma flows, which were supersonic, collisionless, and closely relevant to astrophysical conditions. The plasma flows were created by irradiating a pair of oppositely standing plastic (CH) foils with 1ns-pulsed laser beams of total energy of 1.7 kJ in two laser spots. Finally, with characteristics diagnosed in experiments, the calculated features of Weibel-type filaments are in good agreement with measurements.

Ambient infrared laser ablation mass spectrometry (AIRLAB-MS) with plume capture by continuous flow solvent probe

DOEpatents

O'Brien, Jeremy T.; Williams, Evan R.; Holman, Hoi-Ying N.

2017-10-31

A new experimental setup for spatially resolved ambient infrared laser ablation mass spectrometry (AIRLAB-MS) that uses an infrared microscope with an infinity-corrected reflective objective and a continuous flow solvent probe coupled to a Fourier transform ion cyclotron resonance mass spectrometer is described. The efficiency of material transfer from the sample to the electrospray ionization emitter was determined using glycerol/methanol droplets containing 1 mM nicotine and is .about.50%. This transfer efficiency is significantly higher than values reported for similar techniques.

Investigation of effect of solenoid magnet on emittances of ion beam from laser ablation plasma

NASA Astrophysics Data System (ADS)

Ikeda, Shunsuke; Romanelli, Mark; Cinquegrani, David; Sekine, Megumi; Kumaki, Masafumi; Fuwa, Yasuhiro; Kanesue, Takeshi; Okamura, Masahiro; Horioka, Kazuhiko

2014-02-01

A magnetic field can increase an ion current of a laser ablation plasma and is expected to control the change of the plasma ion current. However, the magnetic field can also make some fluctuations of the plasma and the effect on the beam emittance and the emission surface is not clear. To investigate the effect of a magnetic field, we extracted the ion beams under three conditions where without magnetic field, with magnetic field, and without magnetic field with higher laser energy to measure the beam distribution in phase space. Then we compared the relations between the plasma ion current density into the extraction gap and the Twiss parameters with each condition. We observed the effect of the magnetic field on the emission surface.

Investigation of effect of solenoid magnet on emittances of ion beam from laser ablation plasma.

PubMed

Ikeda, Shunsuke; Romanelli, Mark; Cinquegrani, David; Sekine, Megumi; Kumaki, Masafumi; Fuwa, Yasuhiro; Kanesue, Takeshi; Okamura, Masahiro; Horioka, Kazuhiko

2014-02-01

A magnetic field can increase an ion current of a laser ablation plasma and is expected to control the change of the plasma ion current. However, the magnetic field can also make some fluctuations of the plasma and the effect on the beam emittance and the emission surface is not clear. To investigate the effect of a magnetic field, we extracted the ion beams under three conditions where without magnetic field, with magnetic field, and without magnetic field with higher laser energy to measure the beam distribution in phase space. Then we compared the relations between the plasma ion current density into the extraction gap and the Twiss parameters with each condition. We observed the effect of the magnetic field on the emission surface.

Emission spectroscopy analysis during Nopal cladodes dethorning by laser ablation

NASA Astrophysics Data System (ADS)

Peña-Díaz, M.; Ponce, L.; Arronte, M.; Flores, T.

2007-04-01

Optical emission spectroscopy of the pulsed laser ablation of spines and glochids from Opuntia (Nopal) cladodes was performed. Nopal cladodes were irradiated with Nd:YAG free-running laser pulses on their body, glochids and spines. Emission spectroscopy analyses in the 350-1000 nm region of the laser induced plasma were made. Plasma plume evolution characterization, theoretical calculations of plasma plume temperature and experiments varying the processing atmosphere showed that the process is dominated by a thermally activated combustion reaction which increases the dethorning process efficiency. Therefore, appropriate laser pulse energy for minimal damage of cladodes body and in the area beneath glochids and spines can be obtained.

Investigating the Response and Expansion of Plasma Plumes in a Mesosonic Plasma Using the Situational Awareness Sensor Suite for the ISS (SASSI)

NASA Technical Reports Server (NTRS)

Gilchrist, Brian E.; Hoegy, W. R.; Krause, L. Habash; Minow, J. I.; Coffey, V. N.

2014-01-01

To study the complex interactions between the space environment surrounding the International Space Station (ISS) and the ISS space vehicle, we are exploring a specialized suite of plasma sensors, manipulated by the Space Station Remote Manipulator System (SSRMS) to probe the near-ISS mesosonic plasma ionosphere moving past the ISS. It is proposed that SASSI consists of the NASA Marshall Space Flight Center's (MSFC's) Thermal Ion Capped Hemispherical Spectrometer (TICHS), Thermal Electron Capped Hemispherical Spectrometer (TECHS), Charge Analyzer Responsive to Local Oscillations (CARLO), the Collimated PhotoElectron Gun (CPEG), and the University of Michigan Advanced Langmuir Probe (ALP). There are multiple expected applications for SASSI. Here, we will discuss the study of fundamental plasma physics questions associated with how an emitted plasma plume (such as from the ISS Plasma Contactor Unit (PCU)) responds and expands in a mesosonic magnetoplasma as well as emit and collect current. The ISS PCU Xe plasma plume drifts through the ionosphere and across the Earth's magnetic field, resulting in complex dynamics. This is of practical and theoretical interest pertaining to contamination concerns (e.g. energetic ion scattering) and the ability to collect and emit current between the spacecraft and the ambient plasma ionosphere. This impacts, for example, predictions of electrodynamic tether current performance using plasma contactors as well as decisions about placing high-energy electric propulsion thrusters on ISS. We will discuss the required measurements and connection to proposed instruments for this study.

Surface modification of biomaterials by pulsed laser ablation deposition and plasma/gamma polymerization

NASA Astrophysics Data System (ADS)

Rau, Kaustubh R.

Surface modification of stainless-steel was carried out by two different methods: pulsed laser ablation deposition (PLAD) and a combined plasma/gamma process. A potential application was the surface modification of endovascular stents, to enhance biocompatibility. The pulsed laser ablation deposition process, had not been previously reported for modifying stents and represented a unique and potentially important method for surface modification of biomaterials. Polydimethylsiloxane (PDMS) elatomer was studied using the PLAD technique. Cross- linked PDMS was deemed important because of its general use for biomedical implants and devices as well as in other fields. Furthermore, PDMS deposition using PLAD had not been previously studied and any information gained on its ablation characteristics could be important scientifically and technologically. The studies reported here showed that the deposited silicone film properties had a dependence on the laser energy density incident on the target. Smooth, hydrophobic, silicone-like films were deposited at low energy densities (100-150 mJ/cm2). At high energy densities (>200 mJ/cm2), the films had an higher oxygen content than PDMS, were hydrophilic and tended to show a more particulate morphology. It was also determined that (1)the deposited films were stable and extremely adherent to the substrate, (2)silicone deposition exhibited an `incubation effect' which led to the film properties changing with laser pulse number and (3)films deposited under high vacuum were similar to films deposited at low vacuum levels. The mechanical properties of the PLAD films were determined by nanomechanical measurements which are based on the Atomic Force Microscope (AFM). From these measurements, it was possible to determine the modulus of the films and also study their scratch resistance. Such measurement techniques represent a significant advance over current state-of-the-art thin film characterization methods. An empirical model for

A model of early formation of uranium molecular oxides in laser-ablated plasmas

NASA Astrophysics Data System (ADS)

Finko, Mikhail; Curreli, Davide; Azer, Magdi; Weisz, David; Crowhurst, Jonathan; Rose, Timothy; Koroglu, Batikan; Radousky, Harry; Zaug, Joseph; Armstrong, Mike

2017-10-01

An important problem within the field of nuclear forensics is fractionation: the formation of post-detonation nuclear debris whose composition does not reflect that of the source weapon. We are investigating uranium fractionation in rapidly cooling plasma using a combined experimental and modeling approach. In particular, we use laser ablation of uranium metal samples to produce a low-temperature plasma with physical conditions similar to a condensing nuclear fireball. Here we present a first plasma-chemistry model of uranium molecular species formation during the early stage of laser ablated plasma evolution in atmospheric oxygen. The system is simulated using a global kinetic model with rate coefficients calculated according to literature data and the application of reaction rate theory. The model allows for a detailed analysis of the evolution of key uranium molecular species and represents the first step in producing a uranium fireball model that is kinetically validated against spatially and temporally resolved spectroscopy measurements. This project was sponsored by the DoD, Defense Threat Reduction Agency, Grant HDTRA1-16- 1-0020. This work was performed in part under the auspices of the U.S. DoE by Lawrence Livermore National Laboratory under Contract DE-AC52- 07NA27344.

Analysis of Indium Tin Oxide Film Using Argon Fluroide (ArF) Laser-Excited Atomic Fluorescence of Ablated Plumes.

PubMed

Ho, Sut Kam; Garcia, Dario Machado

2017-04-01

A two-pulse laser-excited atomic fluorescence (LEAF) technique at 193 nm wavelength was applied to the analysis of indium tin oxide (ITO) layer on polyethylene terephthalate (PET) film. Fluorescence emissions from analytes were induced from plumes generated by first laser pulse. Using this approach, non-selective LEAF can be accomplished for simultaneous multi-element analysis and it overcomes the handicap of strict requirement for laser excitation wavelength. In this study, experimental conditions including laser fluences, times for gating and time delay between pulses were optimized to reveal high sensitivity with minimal sample destruction and penetration. With weak laser fluences of 100 and 125 mJ/cm 2 for 355 and 193 nm pulses, detection limits were estimated to be 0.10% and 0.43% for Sn and In, respectively. In addition, the relation between fluorescence emissions and number of laser shots was investigated; reproducible results were obtained for Sn and In. It shows the feasibility of depth profiling by this technique. Morphologies of samples were characterized at various laser fluences and number of shots to examine the accurate penetration. Images of craters were also investigated using scanning electron microscopy (SEM). The results demonstrate the imperceptible destructiveness of film after laser shot. With such weak laser fluences and minimal destructiveness, this LEAF technique is suitable for thin-film analysis.

Study of the phosphine plasma decomposition and its formation by ablation of red phosphorus in hydrogen plasma

NASA Astrophysics Data System (ADS)

Bruno, G.; Losurdo, M.; Capezzuto, P.

1995-03-01

Mass spectrometry and optical emission spectroscopy have been used to study the chemistry of PH(sub 3) plasma decomposition as well as its formation by ablation of red phosphorus in hydrogen plasma. It has been shown that PH(sub 3) decomposition easily equilibrates at low levels of PH(sub 3) depletion (15%-30%), this depending mainly on the rf power. The ablation of red phosphorus in H(sub 2) plasma produces phosphine in significant amount, depending mainly on the total pressure but also on the rf power. It has also been found that H(sup *) and PH(sup *) emitting species originate not only by the dissociative excitation of H(sub 2) and PH(sub 3), respectively, but also by the direct excitation of the same species in the ground state. Considerations are developed on how to derive the H-atom and PH radical densities by actinometry, under specific experimental conditions. Besides, the linear dependence of PH(sub 3) formation rate, r(sub PH(3)), on H-atom density, (left bracket) H (right bracket), leads to the definition of the kinetic equation r(sub PH(3)) = k (left bracket) H (right bracket), and to the hypothesis that the formation of PH radical on the surface or its desorption is the dominant mechanism for PH(sub 3) production.

An electrothermal plasma model considering polyethylene and copper ablation based on ignition experiment

NASA Astrophysics Data System (ADS)

Zhang, Jiangbo; Li, Xingwen; Hang, Yuhua; Yang, Weihong

2018-06-01

In order to study the characteristics of electrothermal plasma interaction with energetic materials, especially the ignition ability, a novel model considering polyethylene and copper ablation is developed, and an ignition experiment system is set up. The parameters of the plasma and the surface conditions of the energetic materials are measured in the testing. The results show the measured first peak pressure to be ~2.2 MPa, the second peak pressure to be ~3.9 MPa, and the visible flame velocity to be ~2000 m s‑1. Circular pits of the order of microns and nanometers in size are observed on the surface of the energetic materials. Further, the parameters of the plasma, including static pressure, total pressure, density, temperature, velocity, copper concentration and PE concentration, are calculated and analyzed by the established model, under discharge currents of 9 kA. The simulation is similar to those of experimental results. A shock wave is observed in the experiment and is presented in the calculations; it plays an important role in the performance of the plasma in the nozzle region, where the parameters of the plasma variation trends are very complex. With the aim of obtaining the overall performance of the plasma, the coupling characteristics of multiple parameters must be taken into account, in accordance with the developed electrothermal plasma model.

Laser ablation in an ambient gas: Modelling and experiment

NASA Astrophysics Data System (ADS)

Moscicki, Tomasz; Hoffman, Jacek; Szymanski, Zygmunt

2018-02-01

The laser ablation of graphite in ambient argon is studied both experimentally and theoretically in conditions corresponding to the initial conditions of carbon nanotube synthesis by the laser vaporization method. The results of the experiment show that the maximum plasma temperature of 24 000 K is reached 25 ns after the beginning of the laser pulse and decreases to about 4000-4500 K after 10 μs. The maximum electron density of 8 × 1025 m-3 is reached 15 ns from the beginning of the laser pulse. The hydrodynamic model applied shows comparable plasma temperatures and electron densities. The model also replicates well a shock wave and plume confinement—intrinsic features of supersonic flow of the ablated plume in an ambient gas. The results show that the theoretical model can be used to simulate nanosecond laser ablation in an ambient gas from the beginning of the process up to several microseconds.

Plasma-mediated ablation for the management of obstructive sleep apnea

NASA Astrophysics Data System (ADS)

Puchalski, Robert; Shah, Udayan K.

2000-05-01

Plasma-mediated ablation (PMA) removes tissue by developing an electrically induced plasma layer between the instrument and target tissue. Charged particles within the plasma field then accelerate toward the tissue, breaking the molecular bonds within the top layer of tissue. Thermal damage to collateral tissue is minimal, resulting in the moniker, 'cold' ablation, for this method. Recently, instrumentation has been developed to permit application for soft tissue resection in Otolaryngology. Presentation of the theory, as well as the benefits and disadvantages associated with CoblationTM technology will be followed by examples of its use. A brief videotape will demonstrate the application of PMA for UPPP, tonsillectomy and nasal turbinate reduction. Preliminary experience from our institution, including eighteen children treated with tonsillectomy and followed for at least one month post-operatively, has provided an initial cohort for comparing the risks and benefits of the approach. The advantage of CoblationTM technology identified thus far, that of less thermal damage, is balanced against a decreased level of hemostasis (compared to MES) and an increased cost.

Effect of magnetic field configuration on the multiply charged ion and plume characteristics in Hall thruster plasmas

SciTech Connect

Kim, Holak; Lim, Youbong; Choe, Wonho, E-mail: wchoe@kaist.ac.kr

2015-04-13

Multiply charged ions and plume characteristics in Hall thruster plasmas are investigated with regard to magnetic field configuration. Differences in the plume shape and the fraction of ions with different charge states are demonstrated by the counter-current and co-current magnetic field configurations, respectively. The significantly larger number of multiply charged and higher charge state ions including Xe{sup 4+} are observed in the co-current configuration than in the counter-current configuration. The large fraction of multiply charged ions and high ion currents in this experiment may be related to the strong electron confinement, which is due to the strong magnetic mirror effectmore » in the co-current magnetic field configuration.« less

Patterning of graphene on silicon-on-insulator waveguides through laser ablation and plasma etching

NASA Astrophysics Data System (ADS)

Van Erps, Jürgen; Ciuk, Tymoteusz; Pasternak, Iwona; Krajewska, Aleksandra; Strupinski, Wlodek; Van Put, Steven; Van Steenberge, Geert; Baert, Kitty; Terryn, Herman; Thienpont, Hugo; Vermeulen, Nathalie

2016-05-01

We present the use of femtosecond laser ablation for the removal of monolayer graphene from silicon-on-insulator (SOI) waveguides, and the use of oxygen plasma etching through a metal mask to peel off graphene from the grating couplers attached to the waveguides. Through Raman spectroscopy and atomic force microscopy, we show that the removal of graphene is successful with minimal damage to the underlying SOI waveguides. Finally, we employ both removal techniques to measure the contribution of graphene to the loss of grating-coupled graphene-covered SOI waveguides using the cut-back method. This loss contribution is measured to be 0.132 dB/μm.

Performance of an ablator for Space Shuttle inorbit repair in an arc-plasma airstream

NASA Technical Reports Server (NTRS)

Stewart, D. A.; Cuellar, M.; Flowers, O.

1983-01-01

An ablator patch material performed well in an arc plasma environment simulating nominal Earth entry conditions for the Space Shuttle. Ablation tests using vacuum molded cones provided data to optimize the formulation of a two part polymer system for application under space conditions. The blunt cones were made using a Teflon mold and a state of the art caulking gun. Char stability of formulations with various amounts of catalyst and diluent were investigated. The char was found to be unstable in formulations with low amounts of catalyst and high amounts of diluent. The best polymer system determined by these tests was evaluated using a half tile patch in a multiple High Temperature Reusable surface Insulation tile model. It was demonstrated that this ablator could be applied in a space environment using a state of the art caulking gun, would maintain the outer mold line of the thermal protection system during entry, and would keep the bond line temperature at the aluminum tile interface below the design limit.

Time resolved interferometric study of the plasma plume induced shock wave in confined geometry: Two-dimensional mapping of the ambient and plasma density

SciTech Connect

Choudhury, Kaushik; Singh, R. K.; Kumar, Ajai, E-mail: ajai@ipr.res.in

2016-04-15

An experimental investigation of the laser produced plasma induced shock wave in the presence of confining walls placed along the axial as well as the lateral direction has been performed. A time resolved Mach Zehnder interferometer is set up to track the primary as well as the reflected shock waves and its effect on the evolving plasma plume has been studied. An attempt has been made to discriminate the electronic and medium density contributions towards the changes in the refractive index of the medium. Two dimensional spatial distributions for both ambient medium density and plasma density (electron density) have beenmore » obtained by employing customised inversion technique and algorithm on the recorded interferograms. The observed density pattern of the surrounding medium in the presence of confining walls is correlated with the reflected shock wave propagation in the medium. Further, the shock wave plasma interaction and the subsequent changes in the shape and density of the plasma plume in confined geometry are briefly described.« less

Minimally-invasive Laser Ablation Inductively Coupled Plasma Mass Spectrometry analysis of model ancient copper alloys

NASA Astrophysics Data System (ADS)

Walaszek, Damian; Senn, Marianne; Wichser, Adrian; Faller, Markus; Wagner, Barbara; Bulska, Ewa; Ulrich, Andrea

2014-09-01

This work describes an evaluation of a strategy for multi-elemental analysis of typical ancient bronzes (copper, lead bronze and tin bronze) by means of laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS).The samples originating from archeological experiments on ancient metal smelting processes using direct reduction in a ‘bloomery’ furnace as well as historical casting techniques were investigated with the use of the previously proposed analytical procedure, including metallurgical observation and preliminary visual estimation of the homogeneity of the samples. The results of LA-ICPMS analysis were compared to the results of bulk composition obtained by X-ray fluorescence spectrometry (XRF) and by inductively coupled plasma mass spectrometry (ICPMS) after acid digestion. These results were coherent for most of the elements confirming the usefulness of the proposed analytical procedure, however the reliability of the quantitative information about the content of the most heterogeneously distributed elements was also discussed in more detail.

Analysis of the correlation between plasma plume and keyhole behavior in laser metal welding for the modeling of the keyhole geometry

NASA Astrophysics Data System (ADS)

Tenner, F.; Brock, C.; Klämpfl, F.; Schmidt, M.

2015-01-01

The process of laser metal welding is widely used in industry. Nevertheless, there is still a lack of complete process understanding and control. For analyzing the process we used two high-speed cameras. Therefore, we could image the plasma plume (which is directly accessible by a camera) and the keyhole (where most of the process instabilities occur) during laser welding isochronously. Applying different image processing steps we were able to find a correlation between those two process characteristics. Additionally we imaged the plasma plume from two directions and were able to calculate a volume with respect to the vaporized material the plasma plume carries. Due to these correlations we are able to conclude the keyhole stability from imaging the plasma plume and vice versa. We used the found correlation between the keyhole behavior and the plasma plume to explain the effect of changing laser power and feed rate on the keyhole geometry. Furthermore, we tried to outline the phenomena which have the biggest effect on the keyhole geometry during changes of feed rate and laser power.

Comparison of pulsating DC and DC power air-water plasma jet: A method to decrease plume temperature and increase ROS

NASA Astrophysics Data System (ADS)

Liu, K.; Hu, H.; Lei, J.; Hu, Y.; Zheng, Z.

2016-12-01

Most air-water plasma jets are rich in hydroxyl radicals (•OH), but the plasma has higher temperatures, compared to that of pure gas, especially when using air as working gas. In this paper, pulsating direct current (PDC) power was used to excite the air-water plasma jet to reduce plume temperature. In addition to the temperature, other differences between PDC and DC plasma jets are not yet clear. Thus, comparative studies of those plasmas are performed to evaluate characteristics, such as breakdown voltage, temperature, and reactive oxygen species. The results show that the plume temperature of PDC plasma is roughly 5-10 °C lower than that of DC plasma in the same conditions. The •OH content of PDC is lower than that of DC plasma, whereas the O content of PDC plasma is higher. The addition of water leads in an increase in the plume temperature and in the production of •OH with two types of power supplies. The production of O inversely shows a declining tendency with higher water ratio. The most important finding is that the PDC plasma with 100% water ratio achieves lower temperature and more abundant production of •OH and O, compared with DC plasma with 0% water ratio.

Thermodynamic properties and transport coefficients of a two-temperature polytetrafluoroethylene vapor plasma for ablation-controlled discharge applications

NASA Astrophysics Data System (ADS)

Wang, Haiyan; Wang, Weizong; Yan, Joseph D.; Qi, Haiyang; Geng, Jinyue; Wu, Yaowu

2017-10-01

Ablation-controlled plasmas have been used in a range of technical applications where local thermodynamic equilibrium (LTE) is often violated near the wall due to the strong cooling effect caused by the ablation of wall materials. The thermodynamic and transport properties of ablated polytetrafluoroethylene (PTFE) vapor, which determine the flowing plasma behavior in such applications, are calculated based on a two-temperature model at atmospheric pressure. To our knowledge, no data for PTFE have been reported in the literature. The species composition and thermodynamic properties are numerically determined using the two-temperature Saha equation and the Guldberg-Waage equation according to van de Sanden et al’s derivation. The transport coefficients, including viscosity, thermal conductivity and electrical conductivity, are calculated with the most recent collision interaction potentials using Devoto’s electron and heavy-particle decoupling approach but expanded to the third-order approximation (second-order for viscosity) in the frame of the Chapman-Enskog method. Results are computed for different degrees of thermal non-equilibrium, i.e. the ratio of electron to heavy-particle temperatures, from 1 to 10, with electron temperature ranging from 300 to 40 000 K. Plasma transport properties in the LTE state obtained from the present work are compared with existing published results and the causes for the discrepancy analyzed. The two-temperature plasma properties calculated in the present work enable the modeling of wall ablation-controlled plasma processes.

Modeling of plasma distortions by laser-induced ablation spectroscopy (LIAS) and implications for the interpretation of LIAS measurements

NASA Astrophysics Data System (ADS)

Tokar, M. Z.; Gierse, N.; Philipps, V.; Samm, U.

2015-09-01

For the interpretation of the line radiation observed from laser induced ablation spectroscopy (LIAS) such parameters as the density and temperature of electrons within very compact clouds of atoms and singly charged ions of ablated material have to be known. Compared to the local plasma conditions prior to the laser pulse, these can be strongly changed during LIAS since new electrons are generated by the ionisation of particles ejected from the irradiated target. Because of their transience and spatial inhomogeneity it is technically difficult to measure disturbances induced in the plasma by LIAS. To overcome this uncertainty a numerical model has been elaborated, providing a self-consistent description for the spreading of ablated particles and accompanying modifications in the plasma. The results of calculations for LIAS performed on carbon-containing targets in Ohmic and additionally heated discharges in the tokamak TEXTOR are presented. Due to the increase in the electron density the ‘ionisation per photon’ ratio, S/XB factor, is significantly enhanced compared to unperturbed plasma conditions. The impact of the amount of material ablated and of the plasma conditions before LIAS on the level of the S/XB-enhancement is investigated.

Impact of cross-field motion on ablation of high-Z dust in fusion edge plasmas

DOE PAGES

Smirnov, R. D.; Krasheninnikov, S. I.

2017-07-05

The impact of cross-field motion of high-Z dust grains on their shielding by ablation cloud in edge plasmas of tokamaks is analyzed. The modification of the existing high-Z dust shielding theory is developed, which takes the dust motion effects into account. We show that the cross-field motion can lead to a large factor increase of the dust ablation rate, as compared to the previous model. It is also shown that the motion effects take place when the dust cross-field velocity exceeds a threshold value. We also obtain the dependencies of the dust ablation flux on the dust velocity and ofmore » the threshold velocity on the dust size and the ambient plasma temperature.« less

Plasma-mediated radiofrequency ablation followed by percutaneous cementoplasty under fluoro-CT guidance: a case report

PubMed Central

Laganà, Domenico; Ianniello, Andrea; Fontana, Federico; Mangini, Monica; Mocciardini, Lucia; Spanò, Emanuela; Piacentino, Filippo; Cuffari, Salvatore; Fugazzola, Carlo

2009-01-01

We report a case of a 81-year-old Caucasian man with colorectal carcinoma, treated by surgery in 1998, referred for palliative treatment of a refractory painful caused by osteolytic metastases of 2.5 cm in back-upper ilium spine. Plasma-mediated radiofrequency ablation was performed under conscious sedation, using Fluoroscopic Computer Tomography guidance. After completing the ablation phase of the procedure, a mixture of bone cement and Biotrace sterile barium sulfate was injected into the ablated cavity. Patient was evaluated by using the Brief Pain Inventory and considering pain interference with daily living at day 1 and 3 and week 1, 2, 3, 4 by means of a telephone interview. A post-procedure Computer Tomography scan was performed to examine the distribution of cement deposition few minutes after the procedure. The plasma mediated RFA and cementoplasty were well tolerated by the patient who did not develop any complication. PMID:19918385

Plasma-mediated radiofrequency ablation followed by percutaneous cementoplasty under fluoro-CT guidance: a case report.

PubMed

Carrafiello, Gianpaolo; Laganà, Domenico; Ianniello, Andrea; Fontana, Federico; Mangini, Monica; Mocciardini, Lucia; Spanò, Emanuela; Piacentino, Filippo; Cuffari, Salvatore; Fugazzola, Carlo

2009-08-17

We report a case of a 81-year-old Caucasian man with colorectal carcinoma, treated by surgery in 1998, referred for palliative treatment of a refractory painful caused by osteolytic metastases of 2.5 cm in back-upper ilium spine. Plasma-mediated radiofrequency ablation was performed under conscious sedation, using Fluoroscopic Computer Tomography guidance. After completing the ablation phase of the procedure, a mixture of bone cement and Biotrace sterile barium sulfate was injected into the ablated cavity.Patient was evaluated by using the Brief Pain Inventory and considering pain interference with daily living at day 1 and 3 and week 1, 2, 3, 4 by means of a telephone interview. A post-procedure Computer Tomography scan was performed to examine the distribution of cement deposition few minutes after the procedure. The plasma mediated RFA and cementoplasty were well tolerated by the patient who did not develop any complication.

Impact of cross-field motion on ablation of high-Z dust in fusion edge plasmas

SciTech Connect

Smirnov, R. D.; Krasheninnikov, S. I.

The impact of cross-field motion of high-Z dust grains on their shielding by ablation cloud in edge plasmas of tokamaks is analyzed. The modification of the existing high-Z dust shielding theory is developed, which takes the dust motion effects into account. We show that the cross-field motion can lead to a large factor increase of the dust ablation rate, as compared to the previous model. It is also shown that the motion effects take place when the dust cross-field velocity exceeds a threshold value. We also obtain the dependencies of the dust ablation flux on the dust velocity and ofmore » the threshold velocity on the dust size and the ambient plasma temperature.« less

Profiling of patterned metal layers by laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS)

NASA Astrophysics Data System (ADS)

Bi, Melody; Ruiz, Antonio M.; Gornushkin, Igor; Smith, Ben W.; Winefordner, James D.

2000-02-01

Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) was used for profiling patterned thin metal layers on a polymer/silicon substrate. The parameters of the laser and ICP-MS operating conditions have been studied and optimized for this purpose. A new laser ablation chamber was designed and built to achieve the best spatial resolution. The results of the profiling by LA-ICP-MS were compared to those obtained from a laser ablation optical emission spectrometry (LA-OES) instrument, which measured the emission of the plasma at the sample surface, and thus, eliminated the time delay caused by the sample transport into the ICP-MS system. Emission spectra gave better spatial resolution than mass spectra. However, LA-ICP-MS provided much better sensitivity and was able to profile thin metal layers (on the order of a few nanometers) on the silicon surface. A lateral spatial resolution of 45 μm was achieved.

Plasma Potential and Langmuir Probe Measurements in the Near-field Plume of the NASA 300M Hall Thruster

NASA Technical Reports Server (NTRS)

Herman, Daniel A; Shastry, Rohit; Huang, Wensheng; Soulas, George C.; KamHawi, Hani

2012-01-01

In order to aid in the design of high-power Hall thrusters and provide experimental validation for existing modeling efforts, plasma potential and Langmuir probe measurements were performed in the near-field plume of the NASA 300M Hall thruster. A probe array consisting of a Faraday probe, Langmuir probe, and emissive probe was used to interrogate the plume from approximately 0.1 - 2.0 DT,m downstream of the thruster exit plane at four operating conditions: 300 V, 400 V, and 500 V at 20 kW as well as 300 V at 10 kW. Results show that the acceleration zone and high-temperature region were contained within 0.3 DT,m from the exit plane at all operating conditions. Isothermal lines were shown to strongly follow magnetic field lines in the nearfield, with maximum temperatures ranging from 19 - 27 eV. The electron temperature spatial distribution created large drops in measured floating potentials in front of the magnetic pole surfaces where the plasma density was small, which suggests strong sheaths at these surfaces. The data taken have provided valuable information for future design and modeling validation, and complements ongoing internal measurement efforts on the NASA 300 M.

Experimental Simulation of Meteorite Ablation during Earth Entry using a Plasma Wind Tunnel

NASA Astrophysics Data System (ADS)

Loehle, Stefan; Zander, Fabian; Hermann, Tobias; Eberhart, Martin; Meindl, Arne; Oefele, Rainer; Vaubaillon, Jeremie; Colas, Francois; Vernazza, Pierre; Drouard, Alexis; Gattacceca, Jerome

2017-03-01

Three different types of rocks were tested in a high enthalpy air plasma flow. Two terrestrial rocks, basalt and argillite, and an ordinary chondrite, with a 10 mm diameter cylindrical shape were tested in order to observe decomposition, potential fragmentation, and spectral signature. The goal was to simulate meteoroid ablation to interpret meteor observation and compare these observations with ground based measurements. The test flow with a local mass-specific enthalpy of 70 MJ kg-1 results in a surface heat flux at the meteorite fragment surface of approximately 16 MW m-2. The stagnation pressure is 24 hPa, which corresponds to a flight condition in the upper atmosphere around 80 km assuming an entry velocity of 10 km s-1. Five different diagnostic methods were applied simultaneously to characterize the meteorite fragmentation and destruction in the ground test: short exposure photography, regular video, high-speed imaging with 10 kHz frame rate, thermography, and Echelle emission spectroscopy. This is the first time that comprehensive testing of various meteorite fragments under the same flow condition was conducted. The data sets indeed show typical meteorite ablation behavior. The cylindrically shaped fragments melt and evaporate within about 4 s. The spectral data allow the identification of the material from the spectra which is of particular importance for future spectroscopic meteor observations. For the tested ordinary chondrite sample a comparison to an observed meteor spectra shows good agreement. The present data show that this testing methodology reproduces the ablation phenomena of meteoritic material alongside the corresponding spectral signatures.

Laser ablation inductively coupled plasma mass spectrometry for direct isotope ratio measurements on solid samples

NASA Astrophysics Data System (ADS)

Pickhardt, Carola; Dietze, Hans-Joachim; Becker, J. Sabine

2005-04-01

Isotope ratio measurements have been increasingly used in quite different application fields, e.g., for the investigation of isotope variation in nature, in geoscience (geochemistry and geochronology), in cosmochemistry and planetary science, in environmental science, e.g., in environmental monitoring, or by the application of the isotope dilution technique for quantification purposes using stable or radioactive high-enriched isotope tracers. Due to its high sensitivity, laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) is today a challenging mass spectrometric technique for the direct determination of precise and accurate isotope ratios in solid samples. In comparison to laser ablation quadrupole ICP-MS (LA-ICP-QMS), laser ablation coupled to a double-focusing sector field ICP-MS (LA-ICP-SFMS) with single ion detection offers a significant improvement of sensitivity at low mass resolution, whereby isotope ratios can be measured with a precision to 0.1% relative standard deviation (R.S.D.). In LA-ICP-SFMS, many disturbing isobaric interferences of analyte and molecular ions can be separated at the required mass resolution (e.g., 40Ar16O+ and 56Fe+ for iron isotope ratio measurements). The precision on isotope ratio measurements was improved by one order of magnitude via the simultaneous detection of mass-separated ion currents of isotopes using multiple ion collectors in LA-ICP-MS (LA-MC-ICP-MS). The paper discusses the state of the art, the challenges and limits in isotope ratio measurements by LA-ICP-MS using different instrumentations at the trace and ultratrace level in different fields of application as in environmental and biological research, geochemistry and geochronology with respect to their precision and accuracy.

Spark ablation-inductively coupled plasma spectrometry for analysis of geologic materials

USGS Publications Warehouse

Golightly, D.W.; Montaser, A.; Smith, B.L.; Dorrzapf, A.F.

1989-01-01

Spark ablation-inductively coupled plasma (SA-ICP) spectrometry is applied to the measurement of hafnium-zirconium ratios in zircons and to the determination of cerium, cobalt, iron, lead, nickel and phosphorus in ferromanganese nodules. Six operating parameters used for the high-voltage spark and argon-ICP combination are established by sequential simplex optimization of both signal-to-background ratio and signal-to-noise ratio. The time-dependences of the atomic emission signals of analytes and matrix elements ablated from a finely pulverized sample embedded in a pressed disk of copper demonstrate selective sampling by the spark. Concentration ratios of hafnium to zirconium in zircons are measured with a precision of 4% (relative standard deviation, RSD). For ferromanganese nodules, spectral measurements based on intensity ratios of analyte line to the Mn(II) 257.610 nm line provide precisions of analysis in the range from 7 to 14% RSD. The accuracy of analysis depends on use of standard additions of the reference material USGS Nod P-1, and an independent measurement of the Mn concentration. ?? 1989.

Demonstration and Analysis of Materials Processing by Ablation Plasma Ion Implantation (APII)

NASA Astrophysics Data System (ADS)

Qi, B.; Gilgenbach, R. M.; Lau, Y. Y.; Jones, M. C.; Lian, J.; Wang, L. M.; Doll, G. L.; Lazarides, A.

2001-10-01

Experiments have demonstrated laser-ablated Fe ion implantation into Si substrates. Baseline laser deposited films (0 kV) showed an amorphous Fe-Si film overlying the Si substrate with a top layer of nanocrystalline Fe. APII films exhibited an additional Fe ion-induced damage layer, extending 7.6 nm below the Si surface. The overlying Fe-Si layer and Fe top layer were amorphized by fast ions. Results were confirmed by XPS vs Ar ion etching time for depth profile of the deposited films. XPS showed primarily Fe (top layer), transitioning to roughly equal Fe/Si , then mostly Si with lower Fe (implanted region). These data clearly prove Fe ion implantation into Si, verifying the feasibility of APII as an ion acceleration and implantation process [1]. SRIM simulations predict about 20 percent deeper Fe ion penetration than data, due to:(a) Subsequent ions must pass through the Fe film deposited by earlier ions, and (b) the bias voltage has a slow rise and fall time. Theoretical research has developed the scaling laws for APII [2]. Recently, a model has successfully explained the shortening of the decay time in the high voltage pulse with the laser ablation plasma. This reduces the theoretical RC time constant, which agrees with the experimental data. * Research supported by National Science Foundation Grant CTS-9907106 [1] Appl. Phys. Lett. 78, 3785 (2001) [2] Appl. Phys. Lett. 78, 706 (2001)),

Determination of elemental content off rocks by laser ablation inductively coupled plasma mass spectrometry

USGS Publications Warehouse

Lichte, F.E.

1995-01-01

A new method of analysis for rocks and soils is presented using laser ablation inductively coupled plasma mass spectrometry. It is based on a lithium borate fusion and the free-running mode of a Nd/YAG laser. An Ar/N2 sample gas improves sensitivity 7 ?? for most elements. Sixty-three elements are characterized for the fusion, and 49 elements can be quantified. Internal standards and isotopic spikes ensure accurate results. Limits of detection are 0.01 ??g/g for many trace elements. Accuracy approaches 5% for all elements. A new quality assurance procedure is presented that uses fundamental parameters to test relative response factors for the calibration.

Power-law scaling of plasma pressure on laser-ablated tin microdroplets

NASA Astrophysics Data System (ADS)

Kurilovich, Dmitry; Basko, Mikhail M.; Kim, Dmitrii A.; Torretti, Francesco; Schupp, Ruben; Visschers, Jim C.; Scheers, Joris; Hoekstra, Ronnie; Ubachs, Wim; Versolato, Oscar O.

2018-01-01

The measurement of the propulsion of metallic microdroplets exposed to nanosecond laser pulses provides an elegant method for probing the ablation pressure in a dense laser-produced plasma. We present the measurements of the propulsion velocity over three decades in the driving Nd:YAG laser pulse energy and observe a near-perfect power law dependence. Simulations performed with the RALEF-2D radiation-hydrodynamic code are shown to be in good agreement with the power law above a specific threshold energy. The simulations highlight the importance of radiative losses which significantly modify the power of the pressure scaling. Having found a good agreement between the experiment and the simulations, we investigate the analytic origins of the obtained power law and conclude that none of the available analytic theories is directly applicable for explaining our power exponent.

Characteristics of a non-volatile liquid propellant in liquid-fed ablative pulsed plasma thrusters

NASA Astrophysics Data System (ADS)

Ling, William Yeong Liang; Schönherr, Tony; Koizumi, Hiroyuki

2017-02-01

In the past several decades, the use of electric propulsion in spacecraft has experienced tremendous growth. With the increasing adoption of small satellites in the kilogram range, suitable propulsion systems will be necessary in the near future. Pulsed plasma thrusters (PPTs) were the first form of electric propulsion to be deployed in orbit, and are highly suitable for small satellites due to their inherent simplicity. However, their lifetime is limited by disadvantages such as carbon deposition leading to thruster failure, and complicated feeding systems required due to the conventional use of solid propellants (usually polytetrafluoroethylene (PTFE)). A promising alternative to solid propellants has recently emerged in the form of non-volatile liquids that are stable in vacuum. This study presents a broad comparison of the non-volatile liquid perfluoropolyether (PFPE) and solid PTFE as propellants on a PPT with a common design base. We show that liquid PFPE can be successfully used as a propellant, and exhibits similar plasma discharge properties to conventional solid PTFE, but with a mass bit that is an order of magnitude higher for an identical ablation area. We also demonstrate that the liquid PFPE propellant has exceptional resistance to carbon deposition, completely negating one of the major causes of thruster failure, while solid PTFE exhibited considerable carbon build-up. Energy dispersive X-ray spectroscopy was used to examine the elemental compositions of the surface deposition on the electrodes and the ablation area of the propellant (or PFPE encapsulator). The results show that based on its physical characteristics and behavior, non-volatile liquid PFPE is an extremely promising propellant for use in PPTs, with an extensive scope available for future research and development.

A Mass Spectrometry Study of Isotope Separation in the Laser Plume

NASA Astrophysics Data System (ADS)

Suen, Timothy Wu

Accurate quantification of isotope ratios is critical for both preventing the development of illicit weapons programs in nuclear safeguards and identifying the source of smuggled material in nuclear forensics. While isotope analysis has traditionally been performed by mass spectrometry, the need for in situ measurements has prompted the development of optical techniques, such as laser-induced breakdown spectroscopy (LIBS) and laser ablation molecular isotopic spectrometry (LAMIS). These optical measurements rely on laser ablation for direct solid sampling, but several past studies have suggested that the distribution of isotopes in the ablation plume is not uniform. This study seeks to characterize isotope separation in the laser plume through the use of orthogonal-acceleration time-of-flight mass spectrometry. A silver foil was ablated with a Nd:YAG at 355 nm at an energy of 50 muJ with a spot size of 71 mum, for a fluence of 1.3 J/cm2 and an irradiance of 250 MW/cm2. Flat-plate repellers were used to sample the plume, and a temporal profile of the ions was obtained by varying the time delay on the high-voltage pulse. A spatial profile along the axis of the plume was generated by changing the position of the sample, which yielded snapshots of the isotopic composition with time. In addition, the reflectron time-of-flight system was used as an energy filter in conjunction with the repellers to sample slices of the laser plasma orthogonal to the plume axis. Mass spectrometry of the plume revealed a fast ion distribution and a slow ion distribution. Measurements taken across the entire plume showed the fast 109Ag ions slightly ahead in both space and time, causing the 107Ag fraction to drop to 0.34 at 3 mus, 4 mm from the sample surface. Although measurements centered on the near side of the plume did not show isotope separation, the slow ions on the far side of the plume included much more 109Ag than 107Ag. In addition to examining the isotope content of the ablation

Electromagnetic Effects in the Near Field Plume Exhaust of a Micro-Pulsed Plasma Thruster

DTIC Science & Technology

2002-06-12

plasma focus is developed at a few millimeters from the thruster exit plane at the axis. This plasma focus exists during the entire pulse, but the plasma density in the focus decreases from about 2x10(exp 22)/cu m at the beginning of the pulse down to 0.3x10(exp 22)/cu m at 5 microsec.

Simultaneous observation of nascent plasma and bubble induced by laser ablation in water with various pulse durations

SciTech Connect

Tamura, Ayaka, E-mail: atamura@hiroshima-u.ac.jp; Matsumoto, Ayumu; Nishi, Naoya

2015-05-07

We investigate the effects of pulse duration on the dynamics of the nascent plasma and bubble induced by laser ablation in water. To examine the relationship between the nascent plasma and the bubble without disturbed by shot-to-shot fluctuation, we observe the images of the plasma and the bubble simultaneously by using two intensified charge coupled device detectors. We successfully observe the images of the plasma and bubble during the pulsed-irradiation, when the bubble size is as small as 20 μm. The light-emitting region of the plasma during the laser irradiation seems to exceed the bubble boundary in the case of themore » short-pulse (30-ns pulse) irradiation, while the size of the plasma is significantly smaller than that of the bubble in the case of the long-pulse (100-ns pulse) irradiation. The results suggest that the extent of the plasma quenching in the initial stage significantly depends on the pulse duration. Also, we investigate how the plasma-bubble relationship in the very early stage affects the shape of the atomic spectral lines observed at the later delay time of 600 ns. The present work gives important information to obtain high quality spectra in the application of underwater laser-induced breakdown spectroscopy, as well as to clarify the mechanism of liquid-phase laser ablation.« less

Measurement of plasma gentamicin concentrations postchemical ciliary body ablation in dogs with chronic glaucoma.

PubMed

Rankin, Amy J; Lanuza, Rick; KuKanich, Butch; Crumley, William C; Pucket, Jonathan D; Allbaugh, Rachel A; Meekins, Jessica M

2016-01-01

To investigate the absorption of gentamicin into the plasma after an intravitreal injection in dogs and to report the success rate of this procedure in lowering the intraocular pressure. Twenty-four client-owned dogs with chronic, end-stage glaucoma. Dogs received a unilateral (22) or bilateral (2) intravitreal injection of 25-40 mg of gentamicin (mean ± SD dose 2.57 ± 1.65 mg/kg and range 0.61-7.50 mg/kg) and 1 mg of dexamethasone per eye. Blood samples were collected at various time points following the intravitreal injection. Plasma concentrations of gentamicin were determined by liquid chromatography and mass spectrometry. The total plasma concentration of gentamicin ranged from 0.21 to 9.71 μg/mL (mean ± SD 2.15 ± 2.03). The mean gentamicin CMAX was 2.29 μg/mL at 2.54 h with a terminal half-life of 9.8 h. The success rate of the chemical ablation procedure was 86.4% (19/22 eyes) in dogs that had at least 1 month of follow-up. Intravitreal injection of gentamicin in eyes with chronic glaucoma resulted in detectable plasma levels in dogs and was successful in lowering the intraocular pressure in 86.4% of the eyes after the first procedure. © 2015 American College of Veterinary Ophthalmologists.

Influence of the distance between target surface and focal point on the expansion dynamics of a laser-induced silicon plasma with spatial confinement

NASA Astrophysics Data System (ADS)

Zhang, Dan; Chen, Anmin; Wang, Xiaowei; Wang, Ying; Sui, Laizhi; Ke, Da; Li, Suyu; Jiang, Yuanfei; Jin, Mingxing

2018-05-01

Expansion dynamics of a laser-induced plasma plume, with spatial confinement, for various distances between the target surface and focal point were studied by the fast photography technique. A silicon wafer was ablated to induce the plasma with a Nd:YAG laser in an atmospheric environment. The expansion dynamics of the plasma plume depended on the distance between the target surface and focal point. In addition, spatially confined time-resolved images showed the different structures of the plasma plumes at different distances between the target surface and focal point. By analyzing the plume images, the optimal distance for emission enhancement was found to be approximately 6 mm away from the geometrical focus using a 10 cm focal length lens. This optimized distance resulted in the strongest compression ratio of the plasma plume by the reflected shock wave. Furthermore, the duration of the interaction between the reflected shock wave and the plasma plume was also prolonged.

Diurnal and Seasonal Statistical Characteristics of Well-formed Plasma Depletion and Enhancement Plumes under Quiet Solar Conditions

NASA Astrophysics Data System (ADS)

Haaser, R. A.

2011-12-01

The Ion Velocity Meter (IVM), a part of the Coupled Ion Neutral Dynamics Investigation (CINDI) aboard the Communication/ Navigation Outage Forecasting System (C/NOFS) satellite, is used to measure in situ ion densities and drifts at altitudes between 400 and 550 km during the nighttime hours from 2100 to 300 local time. A new approach to detecting and classifying well-formed ionospheric plasma depletion and enhancement plumes (bubbles and blobs) of scale sizes between 50 and 500 km is used to develop geophysical statistics for the summer, winter and equinox seasons of the quiet solar conditions during 2009 and 2010. Some diurnal and seasonal geomagnetic distribution characteristics confirm previous work on irregularities and scintillations, while others reveal new behaviors that require additional observations and modeling to promote full understanding.

Prognostic Impact of Indocyanine Green Plasma Disappearance Rate in Hepatocellular Carcinoma Patients after Radiofrequency Ablation: A Prognostic Nomogram Study

PubMed Central

Azumi, Motoi; Suda, Takeshi; Terai, Shuji; Akazawa, Kouhei

2017-01-01

Objective Radiofrequency ablation has been used widely for the local ablation of hepatocellular carcinoma, particularly in its early stages. The study aim was to identify significant prognostic factors and develop a predictive nomogram for patients with hepatocellular carcinoma who have undergone radiofrequency ablation. We also developed the formula to predict the probability of 3- and 5-year overall survival based on clinical variables. Methods We retrospectively studied 96 consecutive patients with hepatocellular carcinoma who had undergone radiofrequency ablation as a first-line treatment. Independent and significant factors affecting the overall survival were selected using a Cox proportional hazards model, and a prognostic nomogram was developed based on these factors. The predictive accuracy of the nomogram was determined by Harrell's concordance index and compared with the Cancer of the Liver Italian Program score and Japan Integrated Staging score. Results A multivariate analysis revealed that age, indocyanine green plasma disappearance rate, and log(des-gamma-carboxy prothrombin) level were independent and significant factors influencing the overall survival. The nomogram was based on these three factors. The mean concordance index of the nomogram was 0.74±0.08, which was significantly better than that of conventional staging systems using the Cancer of the Liver Italian Program score (0.54±0.03) and Japan Integrated Staging score (0.59±0.07). Conclusion This study suggested that the indocyanine green plasma disappearance rate and age at radiofrequency ablation (RFA) and des-gamma-carboxy-prothrombin (DCP) are good predictors of the prognosis in hepatocellular carcinoma patients after radiofrequency ablation. We successfully developed a nomogram using obtainable variables before treatment. PMID:28458303

Prognostic Impact of Indocyanine Green Plasma Disappearance Rate in Hepatocellular Carcinoma Patients after Radiofrequency Ablation: A Prognostic Nomogram Study.

PubMed

Azumi, Motoi; Suda, Takeshi; Terai, Shuji; Akazawa, Kouhei

2017-01-01

Objective Radiofrequency ablation has been used widely for the local ablation of hepatocellular carcinoma, particularly in its early stages. The study aim was to identify significant prognostic factors and develop a predictive nomogram for patients with hepatocellular carcinoma who have undergone radiofrequency ablation. We also developed the formula to predict the probability of 3- and 5-year overall survival based on clinical variables. Methods We retrospectively studied 96 consecutive patients with hepatocellular carcinoma who had undergone radiofrequency ablation as a first-line treatment. Independent and significant factors affecting the overall survival were selected using a Cox proportional hazards model, and a prognostic nomogram was developed based on these factors. The predictive accuracy of the nomogram was determined by Harrell's concordance index and compared with the Cancer of the Liver Italian Program score and Japan Integrated Staging score. Results A multivariate analysis revealed that age, indocyanine green plasma disappearance rate, and log (des-gamma-carboxy prothrombin) level were independent and significant factors influencing the overall survival. The nomogram was based on these three factors. The mean concordance index of the nomogram was 0.74±0.08, which was significantly better than that of conventional staging systems using the Cancer of the Liver Italian Program score (0.54±0.03) and Japan Integrated Staging score (0.59±0.07). Conclusion This study suggested that the indocyanine green plasma disappearance rate and age at radiofrequency ablation (RFA) and des-gamma-carboxy-prothrombin (DCP) are good predictors of the prognosis in hepatocellular carcinoma patients after radiofrequency ablation. We successfully developed a nomogram using obtainable variables before treatment.

The effect of ultrafast laser wavelength on ablation properties and implications on sample introduction in inductively coupled plasma mass spectrometry

PubMed Central

LaHaye, N. L.; Harilal, S. S.; Diwakar, P. K.; Hassanein, A.; Kulkarni, P.

2015-01-01

We investigated the role of femtosecond (fs) laser wavelength on laser ablation (LA) and its relation to laser generated aerosol counts and particle distribution, inductively coupled plasma-mass spectrometry (ICP-MS) signal intensity, detection limits, and elemental fractionation. Four different NIST standard reference materials (610, 613, 615, and 616) were ablated using 400 nm and 800 nm fs laser pulses to study the effect of wavelength on laser ablation rate, accuracy, precision, and fractionation. Our results show that the detection limits are lower for 400 nm laser excitation than 800 nm laser excitation at lower laser energies but approximately equal at higher energies. Ablation threshold was also found to be lower for 400 nm than 800 nm laser excitation. Particle size distributions are very similar for 400 nm and 800 nm wavelengths; however, they differ significantly in counts at similar laser fluence levels. This study concludes that 400 nm LA is more beneficial for sample introduction in ICP-MS, particularly when lower laser energies are to be used for ablation. PMID:26640294

Thermal Shock and Ablation Behavior of Tungsten Nozzle Produced by Plasma Spray Forming and Hot Isostatic Pressing

NASA Astrophysics Data System (ADS)

Wang, Y. M.; Xiong, X.; Zhao, Z. W.; Xie, L.; Min, X. B.; Yan, J. H.; Xia, G. M.; Zheng, F.

2015-08-01

Tungsten nozzle was produced by plasma spray forming (PSF, relative density of 86 ± 2%) followed by hot isostatic pressing (HIPing, 97 ± 2%) at 2000 °C and 180 MPa for 180 min. Scanning electron microscope, x-ray diffractometer, Archimedes method, Vickers hardness, and tensile tests have been employed to study microstructure, phase composition, density, micro-hardness, and mechanical properties of the parts. Resistance of thermal shock and ablation behavior of W nozzle were investigated by hot-firing test on solid rocket motor (SRM). Comparing with PSF nozzle, less damage was observed for HIPed sample after SRM test. Linear ablation rate of nozzle made by PSF was (0.120 ± 0.048) mm/s, while that after HIPing reduced to (0.0075 ± 0.0025) mm/s. Three types of ablation mechanisms including mechanical erosion, thermophysical erosion, and thermochemical ablation took place during hot-firing test. The order of degree of ablation was nozzle throat > convergence > dilation inside W nozzle.

Comparison of laser ablation and dried solution aerosol as sampling systems in inductively coupled plasma mass spectrometry.

PubMed

Coedo, A G; Padilla, I; Dorado, M T

2004-12-01

This paper describes a study designed to determine the possibility of using a dried aerosol solution for calibration in laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS). The relative sensitivities of tested materials mobilized by laser ablation and by aqueous nebulization were established, and the experimentally determined relative sensitivity factors (RSFs) were used in conjunction with aqueous calibration for the analysis of solid steel samples. To such a purpose a set of CRM carbon steel samples (SS-451/1 to SS-460/1) were sampled into an ICP-MS instrument by solution nebulization using a microconcentric nebulizer with membrane desolvating (D-MCN) and by laser ablation (LA). Both systems were applied with the same ICP-MS operating parameters and the analyte signals were compared. The RSF (desolvated aerosol response/ablated solid response) values were close to 1 for the analytes Cr, Ni, Co, V, and W, about 1.3 for Mo, and 1.7 for As, P, and Mn. Complementary tests were carried out using CRM SS-455/1 as a solid standard for one-point calibration, applying LAMTRACE software for data reduction and quantification. The analytical results are in good agreement with the certified values in all cases, showing that the applicability of dried aerosol solutions is a good alternative calibration system for laser ablation sampling.

Secondary plasma formation after single pulse laser ablation underwater and its advantages for laser induced breakdown spectroscopy (LIBS).

PubMed

Gavrilović, M R; Cvejić, M; Lazic, V; Jovićević, S

2016-06-07

In this work we present studies of spatial and temporal plasma evolution after single pulse ablation of an aluminium target in water. The laser ablation was performed using 20 ns long pulses emitted at 1064 nm. The plasma characterization was performed by fast photography, the Schlieren technique, shadowgraphy and optical emission spectroscopy. The experimental results indicate the existence of two distinct plasma stages: the first stage has a duration of approximately 500 ns from the laser pulse, and is followed by a new plasma growth starting from the crater center. The secondary plasma slowly evolves inside the growing vapor bubble, and its optical emission lasts over several tens of microseconds. Later, the hot glowing particles, trapped inside the vapor cavity, were detected during the whole cycle of the bubble, where the first collapse occurs after 475 μs from the laser pulse. Differences in the plasma properties during the two evolution phases are discussed, with an accent on the optical emission since its detection is of primary importance for LIBS. Here we demonstrate that the LIBS signal quality in single pulse excitation underwater can be greatly enhanced by detecting only the secondary plasma emission, and also by applying long acquisition gates (in the order of 10-100 μs). The presented results are of great importance for LIBS measurements inside a liquid environment, since they prove that a good analytical signal can be obtained by using nanosecond pulses from a single commercial laser source and by employing cost effective, not gated detectors.

Postoperative recurrence and fertility after endometrioma ablation using plasma energy: retrospective assessment of a 3-year experience.

PubMed

Roman, Horace; Auber, Mathieu; Bourdel, Nicolas; Martin, Cécile; Marpeau, Loïc; Puscasiu, Lucian

2013-01-01

To assess recurrence and pregnancy rates in women with ovarian endometrioma treated via ablation using plasma energy. Retrospective non-comparative pilot study including 55 patients treated during 28 months, with prospective recording of data (Canadian Task Force classification II-2). Tertiary referral center. Fifty-five consecutive women with pelvic endometriosis in whom ovarian endometriomas were managed solely via ablation using plasma energy. The minimum follow-up was 1 year. Endometrioma ablation using plasma energy. Information was obtained from the database of the North-West Inter Regional Female Cohort for Patients with Endometriosis, based on self-questionnaires completed before surgery, surgical and histologic data, and systematic recording of recurrences, pregnancy, and symptoms. Recurrences were assessed using pelvic ultrasound examination. Mean (SD) follow-up was 20.6 (7.2) months (range, 12-39 months). In 75% of patients, deep infiltrating endometriosis was treated, and 40% had colorectal involvement. Preoperative infertility was recorded in 42% of patients. The rate of postoperative recurrence was 10.9% for the entire series. Of 33 women who wished to conceive, 67% became pregnant, spontaneously in 59%. Time from surgery to the first pregnancy was 7.6 (4.3) months. After discontinuation of postoperative hormone therapy, the probability of not conceiving at 12 months was 0.36 (95% confidence interval, 0.19-0.53), and at 24 months was 0.27 (95% confidence interval, 0.12-0.44). Recurrence and pregnancy rates are encouraging in that they seem comparable to the best reported results after endometrioma cystectomy. Plasma energy may have an important role in the management of ovarian endometrioma in women seeking to conceive. Patients most in need of surgical procedures that can spare ovarian parenchyma, such as those with bilateral endometriomas or a history of ovarian surgery, may particularly benefit from ablation using plasma energy. Copyright © 2013

Subcellular analysis by laser ablation electrospray ionization mass spectrometry

DOEpatents

Vertes, Akos; Stolee, Jessica A; Shrestha, Bindesh

2014-12-02

In various embodiments, a method of laser ablation electrospray ionization mass spectrometry (LAESI-MS) may generally comprise micro-dissecting a cell comprising at least one of a cell wall and a cell membrane to expose at least one subcellular component therein, ablating the at least one subcellular component by an infrared laser pulse to form an ablation plume, intercepting the ablation plume by an electrospray plume to form ions, and detecting the ions by mass spectrometry.

Quasi-phase-matching of high-order harmonics in plasma plumes: theory and experiment.

PubMed

Strelkov, V V; Ganeev, R A

2017-09-04

We theoretically analyze the phase-matching of high-order harmonic generation (HHG) in multi-jet plasmas and find the harmonic orders for which the quasi-phase-matching (QPM) is achieved depending on the parameters of the plasma and the generating beam. HHG by single- and two-color generating fields is analyzed. The QMP is studied experimentally for silver, indium and manganese plasmas using near IR and mid-IR laser fields. The theory is validated by comparison with our experimental observations, as well as published experimental data. In particular, the plasma densities and the harmonic phase coefficients reconstructed from the observed harmonic spectra using our theory agree with the corresponding parameters found using other methods. Our theory allows defining the plasma jet and the generating field properties, which can maximize the HHG efficiency due to QPM.

Involvement of small carbon clusters in the enhancement of high-order harmonic generation of ultrashort pulses in the plasmas produced during ablation of carbon-contained nanoparticles

NASA Astrophysics Data System (ADS)

Ganeev, R. A.

2017-09-01

Various carbon-based nanoparticles ablated at the conditions suitable for efficient harmonic generation during propagation of ultrashort pulses through the laser-produced plasmas were studied. The transmission electron microscopy of ablated debris and the time-of-flight mass-spectroscopy studies of plasmas are presented. The conditions of laser ablation of the carbon-contained nanoparticles (fullerenes, graphene, carbon nanotubes, carbon nanofibers, and diamond nanoparticles) were varied to define the impeding processes restricting the harmonic yield from such laser-produced plasmas. These studies show that the enhancement of harmonics during ablation of nanoparticle targets was related with the appearance of small carbon clusters at the moment of propagation of the ultrashort laser pulses though such plasmas.

Strong Field-Induced Frequency Conversion of Laser Radiation in Plasma Plumes: Recent Achievements

PubMed Central

Ganeev, R. A.

2013-01-01

New findings in plasma harmonics studies using strong laser fields are reviewed. We discuss recent achievements in the growth of the efficiency of coherent extreme ultraviolet (XUV) radiation sources based on frequency conversion of the ultrashort pulses in the laser-produced plasmas, which allowed for the spectral and structural studies of matter through the high-order harmonic generation (HHG) spectroscopy. These studies showed that plasma HHG can open new opportunities in many unexpected areas of laser-matter interaction. Besides being considered as an alternative method for generation of coherent XUV radiation, it can be used as a powerful tool for various spectroscopic and analytical applications. PMID:23864818

Characterizing the Exhaust Plume of the Three-Electrode Micro Pulsed Plasma Thrusters

DTIC Science & Technology

2009-03-01

Plasma Thruster “, J Prop Power 1998;14:716-35 3 W. Andrew Hoskins, Christopher Rayburn, and Charles Sarmiento ” Pulsed Plasma Thruster...plasma thrusters are based on the previous PPT-4 and PPT-7 thruster designs. These thrusters used energy levels between 40 and 80 J generating several...PPT Programs 3 Program Year Energy Voltage Program Year Energy Voltage Zond-2 1964 50 J 1000 V TIP-III 1976 20 J 1630 V LES-6 1968 1.85 J 1360 V NOVA

Deposition and composition-control of Mn-doped ZnO thin films by combinatorial pulsed laser deposition using two delayed plasma plumes

SciTech Connect

Sanchez-Ake, C.; Camacho, R.; Moreno, L.

2012-08-15

Thin films of ZnO doped with manganese were deposited by double-beam, combinatorial pulsed laser deposition. The laser-induced plasmas were studied by means of fast photography and using a Langmuir probe, whereas the films were analyzed by x-ray-diffraction and energy-dispersive x-ray spectroscopy. The effect of the relative delay between plasma plumes on the characteristics of the films was analyzed. It was found that using this parameter, it is possible to control the dopant content keeping the oriented wurtzite structure of the films. The minimum content of Mn was found for plume delays between 0 and 10 {mu}s as the interaction betweenmore » plasmas scatters the dopant species away from the substrate, thus reducing the incorporation of Mn into the films. Results suggest that for delays shorter than {approx}100 {mu}s, the expansion of the second plume through the region behind the first plume affects the composition of the film.« less

INTERACTION OF LASER RADIATION WITH MATTER. LASER PLASMA: Spectroscopic investigation of thermodynamic parameters of a plasma plume formed by the action of cw CO2 laser radiation on a metal substrate

NASA Astrophysics Data System (ADS)

Vasil'chenko, Zh V.; Azharonok, V. V.; Filatova, I. I.; Shimanovich, V. D.; Golubev, V. S.; Zabelin, A. M.

1996-09-01

Emission spectroscopy methods were used in an investigation of thermodynamic parameters of a surface plasma formed by the action of cw CO2 laser radiation of (2-5)×106 W cm-2 intensity on stainless steel in a protective He or Ar atmosphere. The spatiotemporal structure and pulsation characteristics of the plasma plume were used to determine the fields of the plasma electron density and temperature.

Development of a fluid model for DC arc plasma torches and its integration with downstream models of atmospheric plasma spray particle plumes

NASA Astrophysics Data System (ADS)

Cannamela, Michael J., III

The plasma spray process uses plasma flames to melt micron sized particles of e.g. ceramic and propel the droplets to impinge upon and freeze to the target workpiece, forming a functional coating. Variations in the process arise from many sources, and because sensing of the process is imperfect one is motivated to pursue a modeling approach. This dissertation models the major elements of the process; the torch that produces the plasma flame, the jet of hot plasma issuing from the torch, and the plume of particles conveyed and heated by the jet. The plasma in the torch is modeled by a one-fluid magnetohydrodynamic (MHD) approach and it is found that the MHD equations can accurately predict the power dissipated in the bulk of the plasma, while special treatment is required in regions near the electrodes. Treatment of the cathode region is eased since it can be de-coupled from the bulk flow. Treatment of the anode region aims to extract the correct amount of power from the plasma. With MHD in the bulk and these special conditions at the electrode boundaries, the net power into the plasma can be matched with experiment. For one simulation of an SG-100 torch operating at 500A, the measured net power was 7.0kW while the computed net power was 7.1kW. Using outlet information from the torch, the impact of plasma arc oscillations on the free jet and on the in-flight particle states is predicted. The model of the plasma jet is validated against the existing LAVA code, and is able to predict the fraction of entrained air in the jet to within 20% of the experimental value. The variations in particle states due to the arc fluctuations are found to be similar in size to variations due to changes in particle injection velocity, and so cannot be neglected when considering particle state distributions. The end result of this work is to make available a complete chain of models for the plasma spray process, from torch input conditions to in-flight particle state.

Current-driven ion-acoustic and potential-relaxation instabilities excited in plasma plume during electron beam welding

SciTech Connect

Trushnikov, D. N., E-mail: trdimitr@yandex.ru; Mladenov, G. M., E-mail: gmmladenov@abv.bg; Koleva, E. G., E-mail: eligeorg@abv.bg

Many papers have sought correlations between the parameters of secondary particles generated above the beam/work piece interaction zone, dynamics of processes in the keyhole, and technological processes. Low- and high-frequency oscillations of the current, collected by plasma have been observed above the welding zone during electron beam welding. Low-frequency oscillations of secondary signals are related to capillary instabilities of the keyhole, however; the physical mechanisms responsible for the high-frequency oscillations (>10 kHz) of the collected current are not fully understood. This paper shows that peak frequencies in the spectra of the collected high-frequency signal are dependent on the reciprocal distancemore » between the welding zone and collector electrode. From the relationship between current harmonics frequency and distance of the collector/welding zone, it can be estimated that the draft velocity of electrons or phase velocity of excited waves is about 1600 m/s. The dispersion relation with the properties of ion-acoustic waves is related to electron temperature 10 000 K, ion temperature 2 400 K and plasma density 10{sup 16} m{sup −3}, which is analogues to the parameters of potential-relaxation instabilities, observed in similar conditions. The estimated critical density of the transported current for creating the anomalous resistance state of plasma is of the order of 3 A·m{sup −2}, i.e. 8 mA for a 3–10 cm{sup 2} collector electrode. Thus, it is assumed that the observed high-frequency oscillations of the current collected by the positive collector electrode are caused by relaxation processes in the plasma plume above the welding zone, and not a direct demonstration of oscillations in the keyhole.« less

Current-driven ion-acoustic and potential-relaxation instabilities excited in plasma plume during electron beam welding

NASA Astrophysics Data System (ADS)

Trushnikov, D. N.; Mladenov, G. M.; Belenkiy, V. Ya.; Koleva, E. G.; Varushkin, S. V.

2014-04-01

Many papers have sought correlations between the parameters of secondary particles generated above the beam/work piece interaction zone, dynamics of processes in the keyhole, and technological processes. Low- and high-frequency oscillations of the current, collected by plasma have been observed above the welding zone during electron beam welding. Low-frequency oscillations of secondary signals are related to capillary instabilities of the keyhole, however; the physical mechanisms responsible for the high-frequency oscillations (>10 kHz) of the collected current are not fully understood. This paper shows that peak frequencies in the spectra of the collected high-frequency signal are dependent on the reciprocal distance between the welding zone and collector electrode. From the relationship between current harmonics frequency and distance of the collector/welding zone, it can be estimated that the draft velocity of electrons or phase velocity of excited waves is about 1600 m/s. The dispersion relation with the properties of ion-acoustic waves is related to electron temperature 10 000 K, ion temperature 2 400 K and plasma density 1016 m-3, which is analogues to the parameters of potential-relaxation instabilities, observed in similar conditions. The estimated critical density of the transported current for creating the anomalous resistance state of plasma is of the order of 3 A.m-2, i.e. 8 mA for a 3-10 cm2 collector electrode. Thus, it is assumed that the observed high-frequency oscillations of the current collected by the positive collector electrode are caused by relaxation processes in the plasma plume above the welding zone, and not a direct demonstration of oscillations in the keyhole.

Femtosecond ablation applied to deep-drilling of hard metals

NASA Astrophysics Data System (ADS)

Bruneau, Sebastien; Hermann, Joerg; Dumitru, Gabriel; Sentis, Marc L.

2004-09-01

Mechanisms responsible for the limitation of the aspect ratio obtained by deep drilling of hard metals are investigated in the present work. Cemented carbide targets have been irradiated with laser pulses of 100 fs duration and 100 μJ maximum energy delivered by a Ti:sapphire laser system. The experiments are carried out in different gas environments (vacuum, air, helium up to atmospheric pressure) with incident laser fluences ranging from 1 to 20 Jcm-2. During deep drilling, the laser-induced ablation plume is characterized by means of in-situ plasma diagnostics. Fast imaging is used to observe the expansion behavior of the plasma plume whereas time- and space-resolved emission spectroscopy is employed to analyze the plasma composition. After irradiation, the laser-produced craters were examined by optical microscopy. A correlation between the ablation plume characteristics and the morphological changes of the mciro-holes is established. The results indicate that nanoclusters, that present a significant part of the ablated material, are responsbile for the alteration of the crater shape in the high laser fluence regime.

Plasma Potential and Langmuir Probe Measurements in the Near-field Plume of the NASA-457Mv2 Hall Thruster

NASA Technical Reports Server (NTRS)

Shastry, Rohit; Huang, Wensheng; Herman, Daniel A.; Soulas, George C.; Kamhawi, Hani

2012-01-01

In order to further the design of future high-power Hall thrusters and provide experimental validation for ongoing modeling efforts, plasma potential and Langmuir probe measurements were performed on the 50-kW NASA-457Mv2. An electrostatic probe array comprised of a near-field Faraday probe, single Langmuir probe, and emissive probe was used to interrogate the near-field plume from approximately 0.1 - 2.0 mean thruster diameters downstream of the thruster exit plane at the following operating conditions: 300 V, 400 V and 500 V at 30 kW and 500 V at 50 kW. Results have shown that the acceleration zone is limited to within 0.4 mean thruster diameters of the exit plane while the high-temperature region is limited to 0.25 mean thruster diameters from the exit plane at all four operating conditions. Maximum plasma potentials in the near-field at 300 and 400 V were approximately 50 V with respect to cathode potential, while maximum electron temperatures varied from 24 - 32 eV, depending on operating condition. Isothermal lines at all operating conditions were found to strongly resemble the magnetic field topology in the high-temperature regions. This distribution was found to create regions of high temperature and low density near the magnetic poles, indicating strong, thick sheath formation along these surfaces. The data taken from this study are considered valuable for future design as well as modeling validation.

Comparison of femtosecond and nanosecond laser ablation inductively coupled plasma mass spectrometry for uranium isotopic measurements

SciTech Connect

Havrilla, George Joseph; McIntosh, Kathryn Gallagher; Judge, Elizabeth

2016-10-20

Feasibility tests were conducted using femtosecond and nanosecond laser ablation inductively coupled plasma mass spectrometry for rapid uranium isotopic measurements. The samples used in this study consisted of a range of pg quantities of known 235/238 U solutions as dried spot residues of 300 pL drops on silicon substrates. The samples spanned the following enrichments of 235U: 0.5, 1.5, 2, 3, and 15.1%. In this direct comparison using these particular samples both pulse durations demonstrated near equivalent data can be produced on either system with respect to accuracy and precision. There is no question that either LA-ICP-MS method offers themore » potential for rapid, accurate and precise isotopic measurements of U10Mo materials whether DU, LEU or HEU. The LA-ICP-MS equipment used for this work is commercially available. The program is in the process of validating this work for large samples using center samples strips from Y-12 MP-1 LEU-Mo Casting #1.« less

Laser ablation inductively coupled plasma mass spectrometry imaging of metals in experimental and clinical Wilson's disease

PubMed Central

Boaru, Sorina Georgiana; Merle, Uta; Uerlings, Ricarda; Zimmermann, Astrid; Flechtenmacher, Christa; Willheim, Claudia; Eder, Elisabeth; Ferenci, Peter; Stremmel, Wolfgang; Weiskirchen, Ralf

2015-01-01

Wilson's disease is an autosomal recessive disorder in which the liver does not properly release copper into bile, resulting in prominent copper accumulation in various tissues. Affected patients suffer from hepatic disorders and severe neurological defects. Experimental studies in mutant mice in which the copper-transporting ATPase gene (Atp7b) is disrupted revealed a drastic, time-dependent accumulation of hepatic copper that is accompanied by formation of regenerative nodes resembling cirrhosis. Therefore, these mice represent an excellent exploratory model for Wilson's disease. However, the precise time course in hepatic copper accumulation and its impact on other trace metals within the liver is yet poorly understood. We have recently established novel laser ablation inductively coupled plasma mass spectrometry protocols allowing quantitative metal imaging in human and murine liver tissue with high sensitivity, spatial resolution, specificity and quantification ability. By use of these techniques, we here aimed to comparatively analyse hepatic metal content in wild-type and Atp7b deficient mice during ageing. We demonstrate that the age-dependent accumulation of hepatic copper is strictly associated with a simultaneous increase in iron and zinc, while the intrahepatic concentration and distribution of other metals or metalloids is not affected. The same findings were obtained in well-defined human liver samples that were obtained from patients suffering from Wilson's disease. We conclude that in Wilson's disease the imbalances of hepatic copper during ageing are closely correlated with alterations in intrahepatic iron and zinc content. PMID:25704483

Inductively coupled plasma mass spectrometer with laser ablation metal ions release detection in the human mouth

NASA Astrophysics Data System (ADS)

Kueerova, Hana; Dostalova, Tatjana; Prochazkova, J.

2002-06-01

Presence of more dental alloys in oral cavity often causes pathological symptoms. Due to various and multi-faced symptomatology, they tend to be a source of significant problems not only for the patient but also for the dentist. Metal ions released from alloys can cause subjective and objective symptoms in mouth. The aim of this study was detection of metal elements presence in saliva. There were 4 groups of examined persons: with intact teeth (15 individuals) with metallic restorations, pathological currents 5-30 (mu) A, multi-faced subjective symptomatology and uncharacteristic objective diagnosis (32 patients), with metallic restorations and no subjective symptoms (14 persons) and with metallic restorations, without pathological currents and with problems related to galvanism (13 patients). Presence of 14 metal elements was checked by inductively coupled plasma mass spectrometer with laser ablation. Nd:YAG laser detector was used. There were significant differences in content of silver, gold and mercury between persons with intact teeth and other three groups. There were no differences found between subjects with and without galvanic currents, and presence of subjective and objective symptoms.

Computational fluid dynamics and frequency-dependent finite-difference time-domain method coupling for the interaction between microwaves and plasma in rocket plumes

NASA Astrophysics Data System (ADS)

Kinefuchi, K.; Funaki, I.; Shimada, T.; Abe, T.

2012-10-01

Under certain conditions during rocket flights, ionized exhaust plumes from solid rocket motors may interfere with radio frequency transmissions. To understand the relevant physical processes involved in this phenomenon and establish a prediction process for in-flight attenuation levels, we attempted to measure microwave attenuation caused by rocket exhaust plumes in a sea-level static firing test for a full-scale solid propellant rocket motor. The microwave attenuation level was calculated by a coupling simulation of the inviscid-frozen-flow computational fluid dynamics of an exhaust plume and detailed analysis of microwave transmissions by applying a frequency-dependent finite-difference time-domain method with the Drude dispersion model. The calculated microwave attenuation level agreed well with the experimental results, except in the case of interference downstream the Mach disk in the exhaust plume. It was concluded that the coupling estimation method based on the physics of the frozen plasma flow with Drude dispersion would be suitable for actual flight conditions, although the mixing and afterburning in the plume should be considered depending on the flow condition.

Computational fluid dynamics and frequency-dependent finite-difference time-domain method coupling for the interaction between microwaves and plasma in rocket plumes

SciTech Connect

Kinefuchi, K.; Funaki, I.; Shimada, T.

Under certain conditions during rocket flights, ionized exhaust plumes from solid rocket motors may interfere with radio frequency transmissions. To understand the relevant physical processes involved in this phenomenon and establish a prediction process for in-flight attenuation levels, we attempted to measure microwave attenuation caused by rocket exhaust plumes in a sea-level static firing test for a full-scale solid propellant rocket motor. The microwave attenuation level was calculated by a coupling simulation of the inviscid-frozen-flow computational fluid dynamics of an exhaust plume and detailed analysis of microwave transmissions by applying a frequency-dependent finite-difference time-domain method with the Drude dispersion model.more » The calculated microwave attenuation level agreed well with the experimental results, except in the case of interference downstream the Mach disk in the exhaust plume. It was concluded that the coupling estimation method based on the physics of the frozen plasma flow with Drude dispersion would be suitable for actual flight conditions, although the mixing and afterburning in the plume should be considered depending on the flow condition.« less

Effects of a static inhomogeneous magnetic field acting on a laser-produced carbon plasma plume

NASA Astrophysics Data System (ADS)

Favre, M.; Ruiz, H. M.; Bendixsen, L. S. Caballero; Reyes, S.; Veloso, F.; Wyndham, E.; Bhuyan, H.

2017-08-01

We present time- and space-resolved observations of the dynamics of a laser-produced carbon plasma, propagating in a sub-Tesla inhomogeneous magnetic field, with both, axial and radial field gradients. An Nd:YAG laser pulse, 340 mJ, 3.5 ns, at 1.06 μ m, with a fluence of 7 J/cm2, is used to generate the plasma from a solid graphite target, in vacuum. The magnetic field is produced using two coaxial sets of two NeFeB ring magnets, parallel to the laser target surface. The diagnostics include plasma imaging with 50 ns time resolution, spatially resolved optical emission spectroscopy and Faraday cup. Based on our observations, evidence of radial and axial plasma confinement due to magnetic field gradients is presented. Formation of C2 molecules, previously observed in the presence of a low pressure neutral gas background, and enhanced on-axis ion flux, are ascribed to finite Larmor radius effects and reduced radial transport due to the presence of the magnetic field.

Considerations on data acquisition in laser ablation-inductively coupled plasma-mass spectrometry with low-dispersion interfaces

NASA Astrophysics Data System (ADS)

Van Malderen, Stijn J. M.; van Elteren, Johannes T.; Šelih, Vid S.; Vanhaecke, Frank

2018-02-01

This work describes the aliasing effects induced by undersampling the high-frequency signal patterns generated by a laser ablation-inductively coupled plasma-mass spectrometer equipped with a low-dispersion ablation cell and sequential mass analyzer. By characterizing the width of the signal peak generated from a single shot on the sample, critical experimental parameters, such as the laser repetition rate and detector cycle timings for the individual nuclides can be matched so as to avoid these imaging artifacts (spectral skew) induced by an insufficient sampling rate. By increasing the laser repetition rate by a factor 2-3, masses at the end of the mass scan can be sampled at higher sensitivity. Furthermore, the dwell times can be redistributed over the nuclides of interest based on the signal-to-noise ratio to increase the image contrast.

In-situ small-angle x-ray scattering study of nanoparticles in the plasma plume induced by pulsed laser irradiation of metallic targets

SciTech Connect

Lavisse, L.; Jouvard, J.-M.; Girault, M.

2012-04-16

Small angle x-ray scattering was used to probe in-situ the formation of nanoparticles in the plasma plume generated by pulsed laser irradiation of a titanium metal surface under atmospheric conditions. The size and morphology of the nanoparticles were characterized as function of laser irradiance. Two families of nanoparticles were identified with sizes on the order of 10 and 70 nm, respectively. These results were confirmed by ex-situ transmission electron microscopy experiments.

Plasma plume oscillations monitoring during laser welding of stainless steel by discrete wavelet transform application.

PubMed

Sibillano, Teresa; Ancona, Antonio; Rizzi, Domenico; Lupo, Valentina; Tricarico, Luigi; Lugarà, Pietro Mario

2010-01-01

The plasma optical radiation emitted during CO2 laser welding of stainless steel samples has been detected with a Si-PIN photodiode and analyzed under different process conditions. The discrete wavelet transform (DWT) has been used to decompose the optical signal into various discrete series of sequences over different frequency bands. The results show that changes of the process settings may yield different signal features in the range of frequencies between 200 Hz and 30 kHz. Potential applications of this method to monitor in real time the laser welding processes are also discussed.

Reduction of time-averaged irradiation speckle nonuniformity in laser-driven plasmas due to target ablation

SciTech Connect

Epstein, R.

1997-09-01

In inertial confinement fusion (ICF) experiments, irradiation uniformity is improved by passing laser beams through distributed phase plates (DPPs), which produce focused intensity profiles with well-controlled, reproducible envelopes modulated by fine random speckle. [C. B. Burckhardt, Appl. Opt. {bold 9}, 695 (1970); Y. Kato and K. Mima, Appl. Phys. B {bold 29}, 186 (1982); Y. Kato {ital et al.}, Phys. Rev. Lett. {bold 53}, 1057 (1984); Laboratory for Laser Energetics LLE Review 33, NTIS Document No. DOE/DP/40200-65, 1987 (unpublished), p. 1; Laboratory for Laser Energetics LLE Review 63, NTIS Document No. DOE/SF/19460-91, 1995 (unpublished), p. 1.] A uniformly ablating plasmamore » atmosphere acts to reduce the contribution of the speckle to the time-averaged irradiation nonuniformity by causing the intensity distribution to move relative to the absorption layer of the plasma. This occurs most directly as the absorption layer in the plasma moves with the ablation-driven flow, but it is shown that the effect of the accumulating ablated plasma on the phase of the laser light also makes a quantitatively significant contribution. Analytical results are obtained using the paraxial approximation applied to the beam propagation, and a simple statistical model is assumed for the properties of DPPs. The reduction in the time-averaged spatial spectrum of the speckle due to these effects is shown to be quantitatively significant within time intervals characteristic of atmospheric hydrodynamics under typical ICF irradiation intensities. {copyright} {ital 1997 American Institute of Physics.}« less

Applications of inductively coupled plasma mass spectrometry and laser ablation inductively coupled plasma mass spectrometry in materials science

NASA Astrophysics Data System (ADS)

Becker, Johanna Sabine

2002-12-01

Inductively coupled plasma mass spectrometry (ICP-MS) and laser ablation ICP-MS (LA-ICP-MS) have been applied as the most important inorganic mass spectrometric techniques having multielemental capability for the characterization of solid samples in materials science. ICP-MS is used for the sensitive determination of trace and ultratrace elements in digested solutions of solid samples or of process chemicals (ultrapure water, acids and organic solutions) for the semiconductor industry with detection limits down to sub-picogram per liter levels. Whereas ICP-MS on solid samples (e.g. high-purity ceramics) sometimes requires time-consuming sample preparation for its application in materials science, and the risk of contamination is a serious drawback, a fast, direct determination of trace elements in solid materials without any sample preparation by LA-ICP-MS is possible. The detection limits for the direct analysis of solid samples by LA-ICP-MS have been determined for many elements down to the nanogram per gram range. A deterioration of detection limits was observed for elements where interferences with polyatomic ions occur. The inherent interference problem can often be solved by applying a double-focusing sector field mass spectrometer at higher mass resolution or by collision-induced reactions of polyatomic ions with a collision gas using an ICP-MS fitted with collision cell. The main problem of LA-ICP-MS is quantification if no suitable standard reference materials with a similar matrix composition are available. The calibration problem in LA-ICP-MS can be solved using on-line solution-based calibration, and different procedures, such as external calibration and standard addition, have been discussed with respect to their application in materials science. The application of isotope dilution in solution-based calibration for trace metal determination in small amounts of noble metals has been developed as a new calibration strategy. This review discusses new

Effect of mass and density of ambient gas on the interaction of laser-blow-off plasma plumes propagating in close proximity

SciTech Connect

Kumar, Bhupesh; Singh, R. K.; Kumar, Ajai, E-mail: ajai@ipr.res.in

2016-04-15

The effects of mass and pressure of ambient gas on the propagation dynamics of two laser-blow-off plasma plumes created in close proximity are investigated. A time gated fast imaging technique is used for recording the images of the laterally colliding plumes under different experimental conditions. Pressure is varied from 0.1 to 3 mbar in three ambient, i.e., helium, neon, and argon. Emphasis is given on the nature of shock-shock interaction under different ambient conditions. It has been observed that the shock-velocity, shape, strength, and their interactions are strongly dependent on the mass and density of the ambient gases. The rolemore » of the interacting shocks and their subsequent reflections on the formation and geometrical shape of the interaction region in different ambient conditions is briefly described.« less

Ambient infrared laser ablation mass spectrometry (AIRLAB-MS) of live plant tissue with plume capture by continuous flow solvent probe.

PubMed

O'Brien, Jeremy T; Williams, Evan R; Holman, Hoi-Ying N

2015-03-03

A new experimental setup for spatially resolved ambient infrared laser ablation-mass spectrometry (AIRLAB-MS) that uses an infrared microscope with an infinity-corrected reflective objective and a continuous flow solvent probe coupled to a Fourier transform ion cyclotron resonance mass spectrometer is described. The efficiency of material transfer from the sample to the electrospray ionization emitter was determined using glycerol/methanol droplets containing 1 mM nicotine and is ∼50%. This transfer efficiency is significantly higher than values reported for similar techniques. Laser desorption does not induce fragmentation of biomolecules in droplets containing bradykinin, leucine enkephalin and myoglobin, but loss of the heme group from myoglobin occurs as a result of the denaturing solution used. An application of AIRLAB-MS to biological materials is demonstrated for tobacco leaves. Chemical components are identified from the spatially resolved mass spectra of the ablated plant material, including nicotine and uridine. The reproducibility of measurements made using AIRLAB-MS on plant material was demonstrated by the ablation of six closely spaced areas (within 2 × 2 mm) on a young tobacco leaf, and the results indicate a standard deviation of <10% in the uridine signal obtained for each area. The spatial distribution of nicotine was measured for selected leaf areas and variation in the relative nicotine levels (15-100%) was observed. Comparative analysis of the nicotine distribution was demonstrated for two tobacco plant varieties, a genetically modified plant and its corresponding wild-type, indicating generally higher nicotine levels in the mutant.

Multielemental analysis of prehistoric animal teeth by laser-induced breakdown spectroscopy and laser ablation inductively coupled plasma mass spectrometry

SciTech Connect

Galiova, Michaela; Kaiser, Jozef; Fortes, Francisco J.

2010-05-01

Laser-induced breakdown spectroscopy (LIBS) and laser ablation (LA) inductively coupled plasma (ICP) mass spectrometry (MS) were utilized for microspatial analyses of a prehistoric bear (Ursus arctos) tooth dentine. The distribution of selected trace elements (Sr, Ba, Fe) was measured on a 26 mmx15 mm large and 3 mm thick transverse cross section of a canine tooth. The Na and Mg content together with the distribution of matrix elements (Ca, P) was also monitored within this area. The depth of the LIBS craters was measured with an optical profilometer. As shown, both LIBS and LA-ICP-MS can be successfully used for themore » fast, spatially resolved analysis of prehistoric teeth samples. In addition to microchemical analysis, the sample hardness was calculated using LIBS plasma ionic-to-atomic line intensity ratios of Mg (or Ca). To validate the sample hardness calculations, the hardness was also measured with a Vickers microhardness tester.« less

Electron temperature measurements inside the ablating plasma of gas-filled hohlraums at the National Ignition Facility

NASA Astrophysics Data System (ADS)

Barrios, M. A.; Liedahl, D. A.; Schneider, M. B.; Jones, O.; Brown, G. V.; Regan, S. P.; Fournier, K. B.; Moore, A. S.; Ross, J. S.; Landen, O.; Kauffman, R. L.; Nikroo, A.; Kroll, J.; Jaquez, J.; Huang, H.; Hansen, S. B.; Callahan, D. A.; Hinkel, D. E.; Bradley, D.; Moody, J. D.

2016-05-01

The first measurement of the electron temperature (Te) inside a National Ignition Facility hohlraum is obtained using temporally resolved K-shell X-ray spectroscopy of a mid-Z tracer dot. Both isoelectronic- and interstage-line ratios are used to calculate the local Te via the collisional-radiative atomic physics code SCRAM [Hansen et al., High Energy Density Phys 3, 109 (2007)]. The trajectory of the mid-Z dot as it is ablated from the capsule surface and moves toward the laser entrance hole (LEH) is measured using side-on x-ray imaging, characterizing the plasma flow of the ablating capsule. Data show that the measured dot location is farther away from the LEH in comparison to the radiation-hydrodynamics simulation prediction using HYDRA [Marinak et al., Phys. Plasmas 3, 2070 (1996)]. To account for this discrepancy, the predicted simulation Te is evaluated at the measured dot trajectory. The peak Te, measured to be 4.2 keV ± 0.2 keV, is ˜0.5 keV hotter than the simulation prediction.

Electron temperature measurements inside the ablating plasma of gas-filled hohlraums at the National Ignition Facility

SciTech Connect

Barrios, M. A.; Liedahl, D. A.; Schneider, M. B.

The first measurement of the electron temperature (T{sub e}) inside a National Ignition Facility hohlraum is obtained using temporally resolved K-shell X-ray spectroscopy of a mid-Z tracer dot. Both isoelectronic- and interstage-line ratios are used to calculate the local T{sub e} via the collisional–radiative atomic physics code SCRAM [Hansen et al., High Energy Density Phys 3, 109 (2007)]. The trajectory of the mid-Z dot as it is ablated from the capsule surface and moves toward the laser entrance hole (LEH) is measured using side-on x-ray imaging, characterizing the plasma flow of the ablating capsule. Data show that the measured dotmore » location is farther away from the LEH in comparison to the radiation-hydrodynamics simulation prediction using HYDRA [Marinak et al., Phys. Plasmas 3, 2070 (1996)]. To account for this discrepancy, the predicted simulation T{sub e} is evaluated at the measured dot trajectory. The peak T{sub e}, measured to be 4.2 keV ± 0.2 keV, is ∼0.5 keV hotter than the simulation prediction.« less

Dust ablation laboratory experiments to measure the plasma and light production of meteoroids in the atmosphere

NASA Astrophysics Data System (ADS)

Sternovsky, Z.; DeLuca, M.; Janches, D.; Marshall, R. A.; Munsat, T.; Plane, J. M. C.; Horanyi, M.

2017-12-01

Radars play an important role in characterizing the distribution of meteoroids entering Earth's atmosphere, and they are sensitive to the size range where most of the mass input occurs. The interpretation of meteor radar measurements, however, is handicapped by the incomplete understanding of the microphysical processes relevant to meteoric ablation. A facility has been developed to simulate the ablation of small dust particles in laboratory conditions and to determine the most critical parameters. An electrostatic dust accelerator is used to generate iron, aluminum and meteoric analog particles with velocities of 1-70 km/s. The particles are then introduced into a cell filled with nitrogen, air, oxygen, or carbon dioxide gas with pressures adjustable in the 0.02 - 0.5 Torr range, where partial or complete ablation occurs over a short distance. An array of biased electrodes is used to collect the ionized products with spatial resolution along the ablating particles' path. An optical observation setup using a 64 channel PMT system allows direct observation of the particle and estimating the light output. A new addition to the facility, using pickup tube detectors and precise timing, allows measurement of the drag coefficient of the particle's slowdown, which we find to be significantly higher than commonly used in existing models. Measurements also indicated that the ionization efficiency of iron and aluminum at low velocities is larger than previously expected.

[INVITED] Control of femtosecond pulsed laser ablation and deposition by temporal pulse shaping

NASA Astrophysics Data System (ADS)

Garrelie, Florence; Bourquard, Florent; Loir, Anne--Sophie; Donnet, Christophe; Colombier, Jean-Philippe

2016-04-01

This study explores the effects of temporal laser pulse shaping on femtosecond pulsed laser deposition (PLD). The potential of laser pulses temporally tailored on ultrafast time scales is used to control the expansion and the excitation degree of ablation products including atomic species and nanoparticles. The ablation plume generated by temporally shaped femtosecond pulsed laser ablation of aluminum and graphite targets is studied by in situ optical diagnostic methods. Taking advantage of automated pulse shaping techniques, an adaptive procedure based on spectroscopic feedback regulates the irradiance for the enhancement of typical plasma features. Thin films elaborated by unshaped femtosecond laser pulses and by optimized sequence indicate that the nanoparticles generation efficiency is strongly influenced by the temporal shaping of the laser irradiation. The ablation processes leading either to the generation of the nanoparticles either to the formation of plasma can be favored by using a temporal shaping of the laser pulse. Insights are given on the possibility to control the quantity of the nanoparticles. The temporal laser pulse shaping is shown also to strongly modify the laser-induced plasma contents and kinetics for graphite ablation. Temporal pulse shaping proves its capability to reduce the number of slow radicals while increasing the proportion of monomers, with the addition of ionized species in front of the plume. This modification of the composition and kinetics of plumes in graphite ablation using temporal laser pulse shaping is discussed in terms of modification of the structural properties of deposited Diamond-Like Carbon films (DLC). This gives rise to a better understanding of the growth processes involved in femtosecond-PLD and picosecond-PLD of DLC suggesting the importance of neutral C atoms, which are responsible for the subplantation process.

Plume radiation

NASA Astrophysics Data System (ADS)

Dirscherl, R.

1993-06-01

The electromagnetic radiation originating from the exhaust plume of tactical missile motors is of outstanding importance for military system designers. Both missile- and countermeasure engineer rely on the knowledge of plume radiation properties, be it for guidance/interference control or for passive detection of adversary missiles. To allow access to plume radiation properties, they are characterized with respect to the radiation producing mechanisms like afterburning, its chemical constituents, and reactions as well as particle radiation. A classification of plume spectral emissivity regions is given due to the constraints imposed by available sensor technology and atmospheric propagation windows. Additionally assessment methods are presented that allow a common and general grouping of rocket motor properties into various categories. These methods describe state of the art experimental evaluation techniques as well as calculation codes that are most commonly used by developers of NATO countries. Dominant aspects influencing plume radiation are discussed and a standardized test technique is proposed for the assessment of plume radiation properties that include prediction procedures. These recommendations on terminology and assessment methods should be common to all employers of plume radiation. Special emphasis is put on the omnipresent need for self-protection by the passive detection of plume radiation in the ultraviolet (UV) and infrared (IR) spectral band.

Eiffel Tower Plume

NASA Image and Video Library

2015-08-19

This still image from an animation from NASA GSFC Solar Dynamics Observatory shows a single plume of plasma, many times taller than the diameter of Earth, spewing streams of particles for over two days Aug. 17-19, 2015 before breaking apart. At times, its shape resembled the Eiffel Tower. Other lesser plumes and streams of particles can be seen dancing above the solar surface as well. The action was observed in a wavelength of extreme ultraviolet light. http://photojournal.jpl.nasa.gov/catalog/PIA19875

Green and Fast Laser Fusion Technique for Bulk Silicate Rock Analysis by Laser Ablation-Inductively Coupled Plasma Mass Spectrometry.

PubMed

Zhang, Chenxi; Hu, Zhaochu; Zhang, Wen; Liu, Yongsheng; Zong, Keqing; Li, Ming; Chen, Haihong; Hu, Shenghong

2016-10-18

Sample preparation of whole-rock powders is the major limitation for their accurate and precise elemental analysis by laser ablation inductively-coupled plasma mass spectrometry (ICPMS). In this study, a green, efficient, and simplified fusion technique using a high energy infrared laser was developed for major and trace elemental analysis. Fusion takes only tens of milliseconds for each sample. Compared to the pressed pellet sample preparation, the analytical precision of the developed laser fusion technique is higher by an order of magnitude for most elements in granodiorite GSP-2. Analytical results obtained for five USGS reference materials (ranging from mafic to intermediate to felsic) using the laser fusion technique generally agree with recommended values with discrepancies of less than 10% for most elements. However, high losses (20-70%) of highly volatile elements (Zn and Pb) and the transition metal Cu are observed. The achieved precision is within 5% for major elements and within 15% for most trace elements. Direct laser fusion of rock powders is a green and notably simple method to obtain homogeneous samples, which will significantly accelerate the application of laser ablation ICPMS for whole-rock sample analysis.

Determination of tin isotope ratios in cassiterite by femtosecond laser ablation multicollector inductively coupled plasma mass spectrometry

NASA Astrophysics Data System (ADS)

Schulze, Marie; Ziegerick, Marco; Horn, Ingo; Weyer, Stefan; Vogt, Carla

2017-04-01

In comparison to isotope analysis of dissolved samples femtosecond laser ablation multicollector inductively coupled plasma mass spectrometry (fs-LA-MC-ICP-MS) enables precise isotope ratio analyses consuming much less sample material and with a minimum effort in sample preparation. This is especially important for the investigation of valuable historical objects for which visual traces of sampling are unwanted. The present study provides a basis for tin isotope ratio measurements using LA-MC-ICP-MS technique. For this, in house isotope standards had to be defined. Investigations on interferences and matrix effects illustrate that beside Sb only high Te contents (with values above those to be expected in cassiterite) result in a significant shift of the measured tin isotope ratios. This effect can partly be corrected for using natural isotope abundances. However, a natural isotope fractionation of Te cannot be excluded. Tin beads reduced from cassiterite were analysed by laser ablation and after dissolution. It was shown that tin isotope ratios can be determined accurately by using fs-LA-MC-ICP-MS. Furthermore the homogeneity of tin isotope ratios in cassiterite was proven.

Unambiguous characterization of gunshot residue particles using scanning laser ablation and inductively coupled plasma-mass spectrometry.

PubMed

Abrego, Zuriñe; Ugarte, Ana; Unceta, Nora; Fernández-Isla, Alberto; Goicolea, M Aranzazu; Barrio, Ramón J

2012-03-06

A new method based on scanning laser ablation and inductively coupled plasma-mass spectrometry (LA-ICPMS) for the detection and identification of gunshot residue (GSR) particles from firearms discharges has been developed. Tape lifts were used to collect inorganic residues from skin surfaces. The laser ablation pattern and ICPMS conditions were optimized for the detection of metals present in GSR, such as (121)Sb, (137)Ba, and (208)Pb. Other isotopes ((27)Al, (29)Si, (31)P, (33)S, (35)Cl, (39)K, (44)Ca, (57)Fe, (60)Ni, (63)Cu, (66)Zn, and (118)Sn) were monitored during the ICPMS analyses to obtain additional information to possibly classify the GSR particles as either characteristic of GSR or consistent with GSR. In experiments with real samples, different firearms, calibers, and ammunitions were used. The performed method evaluation confirms that the developed methodology can be used as an alternative to the standard scanning electron microscopy-energy dispersive spectroscopy (SEM-EDS) technique, with the significant advantage of drastically reducing the analysis time to less than 66 min.

Ablation Behavior of Plasma-Sprayed La1-xSrxTiO3+δ Coating Irradiated by High-Intensity Continuous Laser.

PubMed

Zhu, Jinpeng; Ma, Zhuang; Gao, Yinjun; Gao, Lihong; Pervak, Vladimir; Wang, Lijun; Wei, Chenghua; Wang, Fuchi

2017-10-11

Laser protection for optical components, particularly those in high-power laser systems, has been a major concern. La 1-x Sr x TiO 3+δ with its good optical and thermal properties can be potentially applied as a high-temperature optical protective coating or high-reflectivity material for optical components. However, the high-power laser ablation behavior of plasma-sprayed La 1-x Sr x TiO 3+δ (x = 0.1) coatings has rarely been investigated. Thus, in this study, laser irradiation experiments were performed to study the effect of high-intensity continuous laser on the ablation behavior of the La 1-x Sr x TiO 3+δ coating. The results show that the La 1-x Sr x TiO 3+δ coating undergoes three ablation stages during laser irradiation: coating oxidation, formation and growth of new structures (columnar and dendritic crystals), and mechanical failure. A finite-element simulation was also conducted to explore the mechanism of the ablation damage to the La 1-x Sr x TiO 3+δ coating and provided a good understanding of the ablation behavior. The apparent ablation characteristics are attributed to the different temperature gradients determined by the reflectivity and thermal diffusivity of the La 1-x Sr x TiO 3+δ coating material, which are critical factors for improving the antilaser ablation property. Now, the stainless steel substrate deposited by it can effectively work as a protective shield layer against ablation by laser irradiation.

Elemental analysis of glass by laser ablation inductively coupled plasma optical emission spectrometry (LA-ICP-OES).

PubMed

Schenk, Emily R; Almirall, José R

2012-04-10

The elemental analysis of glass evidence has been established as a powerful discrimination tool for forensic analysts. Laser ablation inductively coupled plasma optical emission spectrometry (LA-ICP-OES) has been compared to laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) and energy dispersive micro X-ray fluorescence spectroscopy (μXRF/EDS) as competing instrumentation for the elemental analysis of glass. The development of a method for the forensic analysis of glass coupling laser ablation to ICP-OES is presented for the first time. LA-ICP-OES has demonstrated comparable analytical performance to LA-ICP-MS based on the use of the element menu, Al (Al I 396.15 nm), Ba (Ba II 455.40 nm), Ca (Ca II 315.88 nm), Fe (Fe II 238.20 nm), Li (Li I 670.78 nm), Mg (Mg I 285.21 nm), Sr (Sr II 407.77 nm), Ti (Ti II 368.51 nm), and Zr (Zr II 343.82 nm). The relevant figures of merit, such as precision, accuracy and sensitivity, are presented and compared to LA-ICP-MS. A set of 41 glass samples was used to assess the discrimination power of the LA-ICP-OES method in comparison to other elemental analysis techniques. This sample set consisted of several vehicle glass samples that originated from the same source (inside and outside windshield panes) and several glass samples that originated from different vehicles. Different match criteria were used and compared to determine the potential for Type I and Type II errors. It was determined that broader match criteria is more applicable to the forensic comparison of glass analysis because it can reduce the affect that micro-heterogeneity inherent in the glass fragments and a less than ideal sampling strategy can have on the interpretation of the results. Based on the test set reported here, a plus or minus four standard deviation (± 4s) match criterion yielded the lowest possibility of Type I and Type II errors. The developed LA-ICP-OES method has been shown to perform similarly to LA-ICP-MS in the

A fibre based triature interferometer for measuring rapidly evolving, ablatively driven plasma densities

NASA Astrophysics Data System (ADS)

Macdonald, J.; Bland, S. N.; Threadgold, J.

2015-08-01

We report on the first use of a fibre interferometer incorporating triature analysis for measuring rapidly evolving plasma densities of ne ˜ 1013/cm3 and above, such as those produced by simple coaxial plasma guns. The resultant system is extremely portable, easy to field in experiments, relatively cheap to produce, and—with the exception of a small open area in which the plasma is sampled—safe in operation as all laser light is enclosed.

Mapping of lead, magnesium and copper accumulation in plant tissues by laser-induced breakdown spectroscopy and laser-ablation inductively coupled plasma mass spectrometry

NASA Astrophysics Data System (ADS)

Kaiser, J.; Galiová, M.; Novotný, K.; Červenka, R.; Reale, L.; Novotný, J.; Liška, M.; Samek, O.; Kanický, V.; Hrdlička, A.; Stejskal, K.; Adam, V.; Kizek, R.

2009-01-01

Laser-Induced Breakdown Spectroscopy (LIBS) and Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS) were utilized for mapping the accumulation of Pb, Mg and Cu with a resolution up to 200 μm in a up to cm × cm area of sunflower ( Helianthus annuus L.) leaves. The results obtained by LIBS and LA-ICP-MS are compared with the outcomes from Atomic Absorption Spectrometry (AAS) and Thin-Layer Chromatography (TLC). It is shown that laser-ablation based analytical methods can substitute or supplement these techniques mainly in the cases when a fast multi-elemental mapping of a large sample area is needed.

Myocardium tissue ablation with high-peak-power nanosecond 1,064- and 532-nm pulsed lasers: influence of laser-induced plasma.

PubMed

Ogura, Makoto; Sato, Shunichi; Ishihara, Miya; Kawauchi, Satoko; Arai, Tunenori; Matsui, Takemi; Kurita, Akira; Kikuchi, Makoto; Ashida, Hiroshi; Obara, Minoru

2002-01-01

We investigated the mechanism and characteristics of porcine myocardium tissue ablation in vitro with nanosecond 1,064- and 532-nm pulsed lasers at laser intensities up to approximately 5.0 GW/cm(2). Particular attention was paid to study the influence of the laser-induced plasma on the ablation characteristics. The applicability of these two lasers to transmyocardial laser revascularization (TMLR) was discussed. Porcine myocardium tissue samples were irradiated with 1,064- and 532-nm, Q-switched Nd:YAG laser pulses, and the ablation depths were measured. The temporal profiles of the laser-induced optical emissions were measured with a biplanar phototube. For the ablated tissue samples, histological analysis was performed with an optical microscope and a polarization microscope. The ablation efficiency at 1,064 nm was higher than that at 532 nm. The ablation threshold at 1,064 nm (approximately 0.8 GW/cm(2)) was lower than that at 532 nm (approximately 1.6 GW/cm(2)), in spite of the lower absorption coefficient being expected at 1,064 nm. For the 1,064-nm laser-ablated tissues, thermal damage was very limited, while damage presumably caused by the mechanical effect was observed in most of the cases. For the 1,064-nm laser ablation, the ablation threshold was equal to the threshold of the laser-induced optical emission (approximately 0.8 GW/cm(2)), while for the 532-nm laser ablation, the optical emission threshold ( approximately 2.4 GW/cm(2)) was higher than the ablation threshold. We considered that for the 1,064-nm laser ablation, the tissue removal was achieved through a photodisruption process at laser intensities of > approximately 0.8 GW/cm(2). At laser intensities of > 3.0 GW/cm(2), however, the ablation efficiency decreased; this can be attributed to the absorption of incoming laser pulses by the plasma. For the 532-nm laser ablation, the tissue removal was achieved through a photothermal process at laser intensities of > approximately 1.6 GW/cm(2). At

Direct measurements of sample heating by a laser-induced air plasma in pre-ablation spark dual-pulse laser-induced breakdown spectroscopy (LIBS).

PubMed

Register, Janna; Scaffidi, Jonathan; Angel, S Michael

2012-08-01

Direct measurements of temperature changes were made using small thermocouples (TC), placed near a laser-induced air plasma. Temperature changes up to ~500 °C were observed. From the measured temperature changes, estimates were made of the amount of heat absorbed per unit area. This allowed calculations to be made of the surface temperature, as a function of time, of a sample heated by the air plasma that is generated during orthogonal pre-ablation spark dual-pulse (DP) LIBS measurements. In separate experiments, single-pulse (SP) LIBS emission and sample ablation rate measurements were performed on nickel at sample temperatures ranging from room temperature to the maximum surface temperature that was calculated using the TC measurement results (500 °C). A small, but real sample temperature-dependent increase in both SP LIBS emission and the rate of sample ablation was found for nickel samples heated up to 500 °C. Comparison of DP LIBS emission enhancement values for bulk nickel samples at room temperature versus the enhanced SP LIBS emission and sample ablation rates observed as a function of increasing sample temperature suggests that sample heating by the laser-induced air plasma plays only a minor role in DP LIBS emission enhancement.

Tribological characterization of TiCN coatings deposited by two crossed laser ablation plasma beams

NASA Astrophysics Data System (ADS)

Camps, Enrique; Escobar-Alarcón, L.; Camps, Iván; Muhl, Stephen; Flores, Martín

2013-03-01

The simultaneous laser ablation of two targets (graphite and titanium) in an Ar-N2 gas mixture was carried out to deposit thin films of the ternary compound TiCN at room temperature. The base conditions used to produce the TiN without carbon were taken from our previous studies. The experimental conditions for the ablation of the carbon target were varied so that the carbon content in the films could be changed depending on the carbon ion energy. The control of the experimental conditions was carried out using a Langmuir planar probe which permitted the determination of the mean kinetic ion energy. The maximum hardness value of 35 GPa, was obtained with a carbon ion energy of about 250 eV, which corresponds to a film with 5 at% carbon content. In order to perform tribological and scratch tests, two types of substrate were used: nitrided AISI 316 stainless steel and AISI 316 stainless steel previously coated with a thin titanium layer (˜50 nm). Values of the wear rate in the range of 1.39×10-6 to 7.45×10-5 mm3 N-1 m-1, friction coefficient from 0.21 to 0.28 and adhesion from scratch test measurements up to 80 N for final critical load, were obtained.

Dual beam optical system for pulsed laser ablation film deposition

DOEpatents

Mashburn, D.N.

1996-09-24

A laser ablation apparatus having a laser source outputting a laser ablation beam includes an ablation chamber having a sidewall, a beam divider for dividing the laser ablation beam into two substantially equal halves, and a pair of mirrors for converging the two halves on a surface of the target from complementary angles relative to the target surface normal, thereby generating a plume of ablated material emanating from the target. 3 figs.

Dual beam optical system for pulsed laser ablation film deposition

DOEpatents

Mashburn, Douglas N.

1996-01-01

A laser ablation apparatus having a laser source outputting a laser ablation beam includes an ablation chamber having a sidewall, a beam divider for dividing the laser ablation beam into two substantially equal halves, and a pair of mirrors for converging the two halves on a surface of the target from complementary angles relative to the target surface normal, thereby generating a plume of ablated material emanating from the target.

Quasi ?non-destructive? laser ablation-inductively coupled plasma-mass spectrometry fingerprinting of sapphires

NASA Astrophysics Data System (ADS)

Guillong, M.; Günther, D.

2001-07-01

A homogenized 193 nm excimer laser with a flat-top beam profile was used to study the capabilities of LA-ICP-MS for 'quasi' non-destructive fingerprinting and sourcing of sapphires from different locations. Sapphires contain 97-99% of Al 2O 3 (corundum), with the remainder composed of several trace elements, which can be used to distinguish the origin of these gemstones. The ablation behavior of sapphires, as well as the minimum quantity of sample removal that is required to determine these trace elements, was investigated. The optimum ablation conditions were a fluency of 6 J cm -2, a crater diameter of 120 μm, and a laser repetition rate of 10 Hz. The optimum time for the ablation was determined to be 2 s, equivalent to 20 laser pulses. The mean sample removal was 60 nm per pulse (approx. 3 ng per pulse). This allowed satisfactory trace element determination, and was found to cause the minimum amount of damage, while allowing for the fingerprinting of sapphires. More than 40 isotopes were measured using different spatial resolutions (20-120 μm) and eight elements were reproducibly detected in 25 sapphire samples from five different locations. The reproducibility of the trace element distribution is limited by the heterogeneity of the sample. The mean of five or more replicate analyses per sample was used. Calibration was carried out using NIST 612 glass reference material as external standard. The linear dynamic range of the ICP-MS (nine orders of magnitude) allowed the use of Al, the major element in sapphire, as an internal standard. The limits of detection for most of the light elements were in the μg g -1 range and were better for heavier elements (mass >85), being in the 0.1 μg g -1 range. The accuracy of the determinations was demonstrated by comparison with XRF analyses of the same set of samples. Using the quantitative analyses obtained using LA-ICP-MS, natural sapphires from five different origins were statistically classified using ternary plots and

The effects of electron thermal radiation on laser ablative shock waves from aluminum plasma into ambient air

SciTech Connect

Sai Shiva, S.; Leela, Ch.; Prem Kiran, P., E-mail: premkiranuoh@gmail.com, E-mail: prem@uohyd.ac.in

2016-05-15

The effect of electron thermal radiation on 7 ns laser ablative shock waves from aluminum (Al) plasma into an ambient atmospheric air has been numerically investigated using a one-dimensional, three-temperature (electron, ion, and radiation) radiation hydrodynamic code MULTI. The governing equations in Lagrangian form are solved using an implicit scheme for planar, cylindrical, and spherical geometries. The shockwave velocities (V{sub sw}) obtained numerically are compared with our experimental values obtained over the intensity range of 2.0 × 10{sup 10} to 1.4 × 10{sup 11 }W/cm{sup 2}. It is observed that the numerically obtained V{sub sw} is significantly influenced by the thermal radiation effects which are foundmore » to be dominant in the initial stage up to 2 μs depending on the input laser energy. Also, the results are found to be sensitive to the co-ordinate geometry used in the simulation (planar, cylindrical, and spherical). Moreover, it is revealed that shock wave undergoes geometrical transitions from planar to cylindrical nature and from cylindrical to spherical nature with time during its propagation into an ambient atmospheric air. It is also observed that the spatio-temporal evolution of plasma electron and ion parameters such as temperature, specific energy, pressure, electron number density, and mass density were found to be modified significantly due to the effects of electron thermal radiation.« less

Determinations of rare earth element abundance and U-Pb age of zircons using multispot laser ablation-inductively coupled plasma mass spectrometry.

PubMed

Yokoyama, Takaomi D; Suzuki, Toshihiro; Kon, Yoshiaki; Hirata, Takafumi

2011-12-01

We have developed a new calibration technique for multielement determination and U-Pb dating of zircon samples using laser ablation-inductively coupled plasma mass spectrometry (ICPMS) coupled with galvanometric optics. With the galvanometric optics, laser ablation of two or more sample materials could be achieved in very short time intervals (~10 ms). The resulting sample aerosols released from different ablation pits or different solid samples were mixed and homogenized within the sample cell and then transported into the ICP ion source. Multiple spot laser ablation enables spiking of analytes or internal standard elements directly into the solid samples, and therefore the standard addition calibration method can be applied for the determination of trace elements in solid samples. In this study, we have measured the rare earth element (REE) abundances of two zircon samples (Nancy 91500 and Prešovice) based on the standard addition technique, using a direct spiking of analytes through a multispot laser ablation of the glass standard material (NIST SRM612). The resulting REE abundance data show good agreement with previously reported values within analytical uncertainties achieved in this study (10% for most elements). Our experiments demonstrated that nonspectroscopic interferences on 14 REEs could be significantly reduced by the standard addition technique employed here. Another advantage of galvanometric devices is the accumulation of sample aerosol released from multiple spots. In this study we have measured the U-Pb age of a zircon sample (LMR) using an accumulation of sample aerosols released from 10 separate ablation pits of low diameters (~8 μm). The resulting (238)U-(206)Pb age data for the LMR zircons was 369 ± 64 Ma, which is in good agreement with previously reported age data (367.6 ± 1.5 Ma). (1) The data obtained here clearly demonstrate that the multiple spot laser ablation-ICPMS technique can become a powerful approach for elemental and isotopic

Inductively coupled plasma mass spectrometry with a twin quadrupole instrument using laser ablation sample introduction and monodisperse dried microparticulate injection

SciTech Connect

Allen, Lloyd A.

1996-10-17

The focus of this dissertation is the use of a twin quadrupole inductively coupled plasma mass spectrometer (ICP-MS) for the simultaneous detection of two m/z values. The twin quadrupole ICP-MS is used with laser ablation sample introduction in both the steady state (10 Hz) and single pulse modes. Steady state signals are highly correlated and the majority of flicker noise cancels when the ratio is calculated. Using a copper sample, the isotope ratio 63Cu +/ 65Cu + is measured with a relative standard deviation (RSD) of 0.26%. Transient signals for single laser pulses are also obtained. Copper isotope ratio measurementsmore » for several laser pulses are measured with an RSD of 0.85%. Laser ablation (LA) is used with steel samples to assess the ability of the twin quadrupole ICP-MS to eliminate flicker noise of minor components of steel samples. Isotopic and internal standard ratios are measured in the first part of this work. The isotope ratio 52Cr +/ 53Cr + (Cr present at 1.31 %) can be measured with an RSD of 0.06 % to 0.1 %. For internal standard elements, RSDs improve from 1.9 % in the Cr + signal to 0.12% for the ratio of 51V + to 52Cr +. In the second part of this work, one mass spectrometer is scanned while the second channel measures an individual m/z value. When the ratio of these two signals is calculated, the peak shapes in the mass spectrum are improved significantly. Pulses of analyte and matrix ions from individual drops are measured simultaneously using the twin quadrupole ICP-MS with monodisperse dried microparticulate injection (MDMI). At modest Pb concentrations (500 ppm), a shoulder on the leading edge of the Li + signal becomes apparent. Space charge effects are consistent with the disturbances seen.« less

Trace element analysis of synthetic mono- and poly-crystalline CaF 2 by ultraviolet laser ablation inductively coupled plasma mass spectrometry at 266 and 193 nm

NASA Astrophysics Data System (ADS)

Koch, J.; Feldmann, I.; Hattendorf, B.; Günther, D.; Engel, U.; Jakubowski, N.; Bolshov, M.; Niemax, K.; Hergenröder, R.

2002-06-01

The analytical figures of merit for ultraviolet laser ablation-inductively coupled plasma mass spectrometry (UV-LA-ICP-MS) at 266 nm with respect to the trace element analysis of high-purity, UV-transmitting alkaline earth halides are investigated and discussed. Ablation threshold energy density values and ablation rates for mono- and poly-crystalline CaF 2 samples were determined. Furthermore, Pb-, Rb-, Sr-, Ba- and Yb-specific analysis was performed. For these purposes, a pulsed Nd:YAG laser operated at the fourth harmonic of the fundamental wavelength (λ=266 nm) and a double-focusing sector field ICP-MS detector were employed. Depending on the background noise and isotope-specific sensitivity, the detection limits typically varied from 0.7 ng/g for Sr to 7 ng/g in the case of Pb. The concentrations were determined using a glass standard reference material (SRM NIST612). In order to demonstrate the sensitivity of the arrangement described, comparative measurements by means of a commercial ablation system consisting of an ArF excimer laser (λ=193 nm) and a quadrupole-type ICP-MS (ICP-QMS) instrument were carried out. The accuracy of both analyses was in good agreement, whereas ablation at 266 nm and detection using sector-field ICP-MS led to a sensitivity that was one order of magnitude above that obtained at 193 nm with ICP-QMS.

Tvashtar's Plume

NASA Technical Reports Server (NTRS)

2007-01-01

This dramatic image of Io was taken by the Long Range Reconnaissance Imager (LORRI) on New Horizons at 11:04 Universal Time on February 28, 2007, just about 5 hours after the spacecraft's closest approach to Jupiter. The distance to Io was 2.5 million kilometers (1.5 million miles) and the image is centered at 85 degrees west longitude. At this distance, one LORRI pixel subtends 12 kilometers (7.4 miles) on Io.

This processed image provides the best view yet of the enormous 290-kilometer (180-mile) high plume from the volcano Tvashtar, in the 11 o'clock direction near Io's north pole. The plume was first seen by the Hubble Space Telescope two weeks ago and then by New Horizons on February 26; this image is clearer than the February 26 image because Io was closer to the spacecraft, the plume was more backlit by the Sun, and a longer exposure time (75 milliseconds versus 20 milliseconds) was used. Io's dayside was deliberately overexposed in this picture to image the faint plumes, and the long exposure also provided an excellent view of Io's night side, illuminated by Jupiter. The remarkable filamentary structure in the Tvashtar plume is similar to details glimpsed faintly in 1979 Voyager images of a similar plume produced by Io's volcano Pele. However, no previous image by any spacecraft has shown these mysterious structures so clearly.

The image also shows the much smaller symmetrical fountain of the plume, about 60 kilometers (or 40 miles) high, from the Prometheus volcano in the 9 o'clock direction. The top of a third volcanic plume, from the volcano Masubi, erupts high enough to catch the setting Sun on the night side near the bottom of the image, appearing as an irregular bright patch against Io's Jupiter-lit surface. Several Everest-sized mountains are highlighted by the setting Sun along the terminator, the line between day and night.

This is the last of a handful of LORRI images that New Horizons is sending 'home' during its busy close

Impact of the cavitation bubble on a plasma emission following laser ablation in liquid

NASA Astrophysics Data System (ADS)

Gavrilović, Marijana R.

2017-12-01

In this work, the impact of the cavitation bubble on a plasma emission produced after the interaction of the strong focused laser radiation with the target in the liquid was studied. Several experimental techniques were applied to assess different aspects of the complex phenomena of the laser induced breakdown in the liquid media. The results of the fast photography, Schlieren and shadowgraphy techniques were compared with the results of simpler probe beam techniques, transmission and scattering. In addition, emission from the plasma was analysed using optical emission spectroscopy, with aim to relate the quality of the recorded spectral lines to the bubble properties. Bubble had proved to be more convenient surrounding than the liquid for the long lasting plasma emission, due to the high temperature and pressure state inside of it and significantly lower density, which causes less confined plasma. Changes in refractive index of the bubble were also monitored, although in the limited time interval, when the bubble was sufficiently expanded and the refractive index difference between the bubble and the water was large enough to produce glory rings and the bright spot in the bubble's centre. Reshaping of the plasma emission due to the optical properties of the bubble was detected and the need for careful optimization of the optical system was stressed. Contribution to the "Topical Issue: Physics of Ionized Gases (SPIG 2016)", edited by Goran Poparic, Bratislav Obradovic, Dragana Maric and Aleksandar Milosavljevic.

Temporally and Spatially Resolved Plasma Spectroscopy in Pulsed Laser Deposition of Ultra-Thin Boron Nitride Films (Postprint)

DTIC Science & Technology

2015-04-24

AFRL-RX-WP-JA-2016-0196 TEMPORALLY AND SPATIALLY RESOLVED PLASMA SPECTROSCOPY IN PULSED LASER DEPOSITION OF ULTRA-THIN BORON NITRIDE...AND SPATIALLY RESOLVED PLASMA SPECTROSCOPY IN PULSED LASER DEPOSITION OF ULTRA-THIN BORON NITRIDE FILMS (POSTPRINT) 5a. CONTRACT NUMBER FA8650...distributions within a PVD plasma plume ablated from a boron nitride (BN) target by a KrF laser at different pressures of nitrogen gas were investigated

Determination of refractive and volatile elements in sediment using laser ablation inductively coupled plasma mass spectrometry.

PubMed

Duodu, Godfred Odame; Goonetilleke, Ashantha; Allen, Charlotte; Ayoko, Godwin A

2015-10-22

Wet-milling protocol was employed to produce pressed powder tablets with excellent cohesion and homogeneity suitable for laser ablation (LA) analysis of volatile and refractive elements in sediment. The influence of sample preparation on analytical performance was also investigated, including sample homogeneity, accuracy and limit of detection. Milling in volatile solvent for 40 min ensured sample is well mixed and could reasonably recover both volatile (Hg) and refractive (Zr) elements. With the exception of Cr (-52%) and Nb (+26%) major, minor and trace elements in STSD-1 and MESS-3 could be analysed within ±20% of the certified values. Comparison of the method with total digestion method using HF was tested by analysing 10 different sediment samples. The laser method recovers significantly higher amounts of analytes such as Ag, Cd, Sn and Sn than the total digestion method making it a more robust method for elements across the periodic table. LA-ICP-MS also eliminates the interferences from chemical reagents as well as the health and safety risks associated with digestion processes. Therefore, it can be considered as an enhanced method for the analysis of heterogeneous matrices such as river sediments. Copyright © 2015 Elsevier B.V. All rights reserved.

Visualizing fossilization using laser ablation-inductively coupled plasma-mass spectrometry maps of trace elements in Late Cretaceous bones

USGS Publications Warehouse

Koenig, A.E.; Rogers, R.R.; Trueman, C.N.

2009-01-01

Elemental maps generated by laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) provide a previously unavailable high-resolution visualization of the complex physicochemical conditions operating within individual bones during the early stages of diagenesis and fossilization. A selection of LA-ICP-MS maps of bones collected from the Late Cretaceous of Montana (United States) and Madagascar graphically illustrate diverse paths to recrystallization, and reveal unique insights into geochemical aspects of taphonomic history. Some bones show distinct gradients in concentrations of rare earth elements and uranium, with highest concentrations at external bone margins. Others exhibit more intricate patterns of trace element uptake related to bone histology and its control on the flow paths of pore waters. Patterns of element uptake as revealed by LA-ICP-MS maps can be used to guide sampling strategies, and call into question previous studies that hinge upon localized bulk samples of fossilized bone tissue. LA-ICP-MS maps also allow for comparison of recrystallization rates among fossil bones, and afford a novel approach to identifying bones or regions of bones potentially suitable for extracting intact biogeochemical signals. ?? 2009 Geological Society of America.

Role of laser ablation-inductively coupled plasma-mass spectrometry in cultural heritage research: a review.

PubMed

Giussani, Barbara; Monticelli, Damiano; Rampazzi, Laura

2009-03-02

Cultural heritage represents a bridge between the contemporary society and the past populations, and a strong collaboration between archaeologists, art historians and analysts may lead to the decryption of the information hidden in an ancient object. Quantitative elemental compositional data play a key role in solving questions concerning dating, provenance, technology, use and the relationship of ancient cultures with the environment. Nevertheless, the scientific investigation of an artifact should be carried out complying with some important constraints: above all the analyses should be as little destructive as possible and performed directly on the object to preserve its integrity. Laser ablation sampling coupled to inductively coupled plasma-mass spectrometry (LA-ICP-MS) fulfils these requirements exhibiting comparably strong analytical performance in trace element determination. This review intends to show through the applications found in the literature how valuable is the contribution of LA-ICP-MS in the investigation of ancient materials such as obsidian, glass, pottery, human remains, written heritage, metal objects and miscellaneous stone materials. The main issues related to cultural heritage investigation are introduced, followed by a brief description of the features of this technique. An overview of the exploitation of LA-ICP-MS is then presented. Finally, advantages and drawbacks of this technique are critically discussed: the fit for purpose and prospects of the use of LA-ICP-MS are presented.

On-line double isotope dilution laser ablation inductively coupled plasma mass spectrometry for the quantitative analysis of solid materials.

PubMed

Fernández, Beatriz; Rodríguez-González, Pablo; García Alonso, J Ignacio; Malherbe, Julien; García-Fonseca, Sergio; Pereiro, Rosario; Sanz-Medel, Alfredo

2014-12-03

We report on the determination of trace elements in solid samples by the combination of on-line double isotope dilution and laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS). The proposed method requires the sequential analysis of the sample and a certified natural abundance standard by on-line IDMS using the same isotopically-enriched spike solution. In this way, the mass fraction of the analyte in the sample can be directly referred to the certified standard so the previous characterization of the spike solution is not required. To validate the procedure, Sr, Rb and Pb were determined in certified reference materials with different matrices, including silicate glasses (SRM 610, 612 and 614) and powdered samples (PACS-2, SRM 2710a, SRM 1944, SRM 2702 and SRM 2780). The analysis of powdered samples was carried out both by the preparation of pressed pellets and by lithium borate fusion. Experimental results for the analysis of powdered samples were in agreement with the certified values for all materials. Relative standard deviations in the range of 6-21% for pressed pellets and 3-21% for fused solids were obtained from n=3 independent measurements. Minimal sample preparation, data treatment and consumption of the isotopically-enriched isotopes are the main advantages of the method over previously reported approaches. Copyright © 2014 Elsevier B.V. All rights reserved.

Imaging Metals in Brain Tissue by Laser Ablation - Inductively Coupled Plasma - Mass Spectrometry (LA-ICP-MS)

PubMed Central

Hare, Dominic J.; Kysenius, Kai; Paul, Bence; Knauer, Beate; Hutchinson, Robert W.; O'Connor, Ciaran; Fryer, Fred; Hennessey, Tom P.; Bush, Ashley I.; Crouch, Peter J.; Doble, Philip A.

2017-01-01

Metals are found ubiquitously throughout an organism, with their biological role dictated by both their chemical reactivity and abundance within a specific anatomical region. Within the brain, metals have a highly compartmentalized distribution, depending on the primary function they play within the central nervous system. Imaging the spatial distribution of metals has provided unique insight into the biochemical architecture of the brain, allowing direct correlation between neuroanatomical regions and their known function with regard to metal-dependent processes. In addition, several age-related neurological disorders feature disrupted metal homeostasis, which is often confined to small regions of the brain that are otherwise difficult to analyze. Here, we describe a comprehensive method for quantitatively imaging metals in the mouse brain, using laser ablation - inductively coupled plasma - mass spectrometry (LA-ICP-MS) and specially designed image processing software. Focusing on iron, copper and zinc, which are three of the most abundant and disease-relevant metals within the brain, we describe the essential steps in sample preparation, analysis, quantitative measurements and image processing to produce maps of metal distribution within the low micrometer resolution range. This technique, applicable to any cut tissue section, is capable of demonstrating the highly variable distribution of metals within an organ or system, and can be used to identify changes in metal homeostasis and absolute levels within fine anatomical structures. PMID:28190025

Bioimaging of metals in brain tissue by laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) and metallomics.

PubMed

Becker, J Sabine; Matusch, Andreas; Palm, Christoph; Salber, Dagmar; Morton, Kathryn A; Becker, J Susanne

2010-02-01

Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) has been developed and established as an emerging technique in the generation of quantitative images of metal distributions in thin tissue sections of brain samples (such as human, rat and mouse brain), with applications in research related to neurodegenerative disorders. A new analytical protocol is described which includes sample preparation by cryo-cutting of thin tissue sections and matrix-matched laboratory standards, mass spectrometric measurements, data acquisition, and quantitative analysis. Specific examples of the bioimaging of metal distributions in normal rodent brains are provided. Differences to the normal were assessed in a Parkinson's disease and a stroke brain model. Furthermore, changes during normal aging were studied. Powerful analytical techniques are also required for the determination and characterization of metal-containing proteins within a large pool of proteins, e.g., after denaturing or non-denaturing electrophoretic separation of proteins in one-dimensional and two-dimensional gels. LA-ICP-MS can be employed to detect metalloproteins in protein bands or spots separated after gel electrophoresis. MALDI-MS can then be used to identify specific metal-containing proteins in these bands or spots. The combination of these techniques is described in the second section.

Quantitative analysis of gold nanoparticles in single cells by laser ablation inductively coupled plasma-mass spectrometry.

PubMed

Wang, Meng; Zheng, Ling-Na; Wang, Bing; Chen, Han-Qing; Zhao, Yu-Liang; Chai, Zhi-Fang; Reid, Helen J; Sharp, Barry L; Feng, Wei-Yue

2014-10-21

Single cell analysis has become an important field of research in recent years reflecting the heterogeneity of cellular responses in biological systems. Here, we demonstrate a new method, based on laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS), which can quantify in situ gold nanoparticles (Au NPs) in single cells. Dried residues of picoliter droplets ejected by a commercial inkjet printer were used to simulate matrix-matched calibration standards. The gold mass in single cells exposed to 100 nM NIST Au NPs (Reference material 8012, 30 nm) for 4 h showed a log-normal distribution, ranging from 1.7 to 72 fg Au per cell, which approximately corresponds to 9 to 370 Au NPs per cell. The average result from 70 single cells (15 ± 13 fg Au per cell) was in good agreement with the result from an aqua regia digest solution of 1.2 × 10(6) cells (18 ± 1 fg Au per cell). The limit of quantification was 1.7 fg Au. This paper demonstrates the great potential of LA-ICPMS for single cell analysis and the beneficial study of biological responses to metal drugs or NPs at the single cell level.

Laser ablation-inductively coupled plasma mass spectrometry: an emerging technology for detecting rare cells in tissue sections.

PubMed

Managh, Amy J; Hutchinson, Robert W; Riquelme, Paloma; Broichhausen, Christiane; Wege, Anja K; Ritter, Uwe; Ahrens, Norbert; Koehl, Gudrun E; Walter, Lisa; Florian, Christian; Schlitt, Hans J; Reid, Helen J; Geissler, Edward K; Sharp, Barry L; Hutchinson, James A

2014-09-01

Administering immunoregulatory cells to patients as medicinal agents is a potentially revolutionary approach to the treatment of immunologically mediated diseases. Presently, there are no satisfactory, clinically applicable methods of tracking human cells in patients with adequate spatial resolution and target cell specificity over a sufficient period of time. Laser ablation-inductively coupled plasma mass spectrometry (LA-ICP-MS) represents a potential solution to the problem of detecting very rare cells in tissues. In this article, this exquisitely sensitive technique is applied to the tracking of gold-labeled human regulatory macrophages (Mregs) in immunodeficient mice. Optimal conditions for labeling Mregs with 50-nm gold particles were investigated by exposing Mregs in culture to variable concentrations of label: Mregs incubated with 3.5 × 10(9) particles/ml for 1 h incorporated an average of 3.39 × 10(8) Au atoms/cell without loss of cell viability. Analysis of single, gold-labeled Mregs by LA-ICP-MS registered an average of 1.9 × 10(5) counts/cell. Under these conditions, 100% labeling efficiency was achieved, and label was retained by Mregs for ≥36 h. Gold-labeled Mregs adhered to glass surfaces; after 24 h of culture, it was possible to colabel these cells with human-specific (154)Sm-tagged anti-HLA-DR or (174)Yb-tagged anti-CD45 mAbs. Following injection into immunodeficient mice, signals from gold-labeled human Mregs could be detected in mouse lung, liver, and spleen for at least 7 d by solution-based inductively coupled plasma mass spectrometry and LA-ICP-MS. These promising results indicate that LA-ICP-MS tissue imaging has great potential as an analytical technique in immunology. Copyright © 2014 by The American Association of Immunologists, Inc.

Solution-based calibration strategy for laser ablation-inductively coupled plasma-mass spectrometry using desolvating nebulizer system

NASA Astrophysics Data System (ADS)

Zhang, Guoxia; Li, Qing; Zhu, Yan; Wang, Zheng

2018-07-01

An additional quantification strategy using a desolvating nebulizer system (DNS) for solution-based calibration was developed. For quantitative analysis, laser ablation (LA) and DNS-generated aerosols were coupled using a "Y" connector and introduced into the inductively coupled plasma (ICP). These aerosols were also observed by scanning electron microscopy following collection on a silicon chip. Internal standards (108Ag, 64Cu, 89Y) were used to correct for the different aerosol transport efficiencies between the DNS and LA. The correlation coefficients of the calibration curves for all elements ranged from 0.9986 to 0.9999. Standard reference materials (NIST 610-616 and GBW08407-08411) were used to demonstrate the accuracy and precision of the method. The results were in good agreement with certified values, and the relative standard deviation (RSD) of most elements was <3%. The limits of detection (LODs) for 50Cr, 55Mn, 59Co, 60Ni, 66Zn, 89Y, 110Cd, 139La, 140Ce, 146Nd, 147Sm, 157Gd, 163Dy, 166Er, and 208Pb were 23, 3, 3, 19, 31, 4, 12, 0.4, 0.9, 0.1, 0.2, 2, 0.3, 0.4, and 21 ng/g, respectively, which were significantly better than those obtained by other methods. Further, this approach was applied for the analysis of multiple elements in biological tissues, and the results were in good agreement with those obtained using solution-based inductively coupled plasma-mass spectrometry (ICP-MS).

Strontium isotope ratios (87Sr/86Sr) of tooth enamel: a comparison of solution and laser ablation multicollector inductively coupled plasma mass spectrometry methods.

PubMed

Copeland, Sandi R; Sponheimer, Matt; le Roux, Petrus J; Grimes, Vaughan; Lee-Thorp, Julia A; de Ruiter, Darryl J; Richards, Michael P

2008-10-01

Strontium isotope ratios (87Sr/86Sr) in tooth enamel provide a means to investigate migration and landscape use in humans and other animals. Established methods for measuring (87)Sr/(86)Sr in teeth use bulk sampling (5-20 mg) and labor-intensive elemental purification procedures before analysis by either thermal ionization mass spectrometry (TIMS) or multicollector inductively coupled plasma mass spectrometry (MC-ICP-MS). Another method for measuring 87Sr/86Sr is laser ablation MC-ICP-MS, but concerns have been expressed about its accuracy for measuring tooth enamel. In this study we test the precision and accuracy of the technique by analyzing 30 modern rodent teeth from the Sterkfontein Valley, South Africa by laser ablation MC-ICP-MS and solution MC-ICP-MS. The results show a mean difference in 87Sr/86Sr measured by laser ablation and by solution of 0.0003 +/- 0.0002. This degree of precision is well within the margin necessary for investigating the potential geographic origins of humans or animals in many areas of the world. Because laser ablation is faster, less expensive, and less destructive than bulk sampling solution methods, it opens the possibility for conducting 87Sr/86Sr analyses of intra-tooth samples and small and/or rare specimens such as micromammal and fossil teeth.

Eiffel Tower Plume

NASA Image and Video Library

2015-08-31

A single plume of plasma, many times taller than the diameter of Earth, rose up from the Sun, twisted and spun around, all the while spewing streams of particles for over two days (Aug. 17-19, 2015) before breaking apart. At times, its shape resembled the Eiffel Tower. Other lesser plumes and streams of particles can be seen dancing above the solar surface as well. The action was observed in a wavelength of extreme ultraviolet light. Credit: NASA/Goddard/SDO NASA image use policy. NASA Goddard Space Flight Center enables NASA’s mission through four scientific endeavors: Earth Science, Heliophysics, Solar System Exploration, and Astrophysics. Goddard plays a leading role in NASA’s accomplishments by contributing compelling scientific knowledge to advance the Agency’s mission. Follow us on Twitter Like us on Facebook Find us on Instagram

Modeling of Interactions of Ablated Plumes

DTIC Science & Technology

2008-02-01

code was tested and verified using the Sedov-Taylor explosion problem 24. The grid 300 x 300 is used so as the single code run takes 30 minutes in a...still air and b) temperature contours along with the vector field for 20 km at t-10ps. 9 Final report AFOSR FA9550-07-1-0457 February 2008 0960014 09 C ow...ia Figue9FrainoIeodr shok wves a-)pesr otus0 )~22,bt4F,adetJ n d) het trnsferat te TPSw9PS 00 As 10 04 J. ’ Figure 9:Formation of secondary shock

Experimental assessment of the performance of ablative heat shield materials from plasma wind tunnel testing

NASA Astrophysics Data System (ADS)

Löhle, S.; Hermann, T.; Zander, F.

2018-06-01

A method for assessing the performance of typical heat shield materials is presented in this paper. Three different material samples, the DLR material Zuram, the Airbus material Asterm and the carbon preform Calcarb were tested in the IRS plasma wind tunnel PWK1 at the same nominal condition. State of the art diagnostic tools, i.e., surface temperature with pyrometry and thermography and boundary layer optical emission spectroscopy were completed by photogrammetric surface recession measurements. These data allow the assessment of the net heat flux for each material. The analysis shows that the three materials each have a different effect on heat flux mitigation with ASTERM showing the largest reduction in surface heat flux. The effect of pyrolysis and blowing is clearly observed and the heat flux reduction can be determined from an energy balance.

Experimental assessment of the performance of ablative heat shield materials from plasma wind tunnel testing

NASA Astrophysics Data System (ADS)

Löhle, S.; Hermann, T.; Zander, F.

2017-12-01

A method for assessing the performance of typical heat shield materials is presented in this paper. Three different material samples, the DLR material uc(Zuram), the Airbus material uc(Asterm) and the carbon preform uc(Calcarb) were tested in the IRS plasma wind tunnel PWK1 at the same nominal condition. State of the art diagnostic tools, i.e., surface temperature with pyrometry and thermography and boundary layer optical emission spectroscopy were completed by photogrammetric surface recession measurements. These data allow the assessment of the net heat flux for each material. The analysis shows that the three materials each have a different effect on heat flux mitigation with ASTERM showing the largest reduction in surface heat flux. The effect of pyrolysis and blowing is clearly observed and the heat flux reduction can be determined from an energy balance.

2D elemental mapping of sections of human kidney stones using laser ablation inductively-coupled plasma-mass spectrometry: Possibilities and limitations

NASA Astrophysics Data System (ADS)

Vašinová Galiová, Michaela; Čopjaková, Renata; Škoda, Radek; Štěpánková, Kateřina; Vaňková, Michaela; Kuta, Jan; Prokeš, Lubomír; Kynický, Jindřich; Kanický, Viktor

2014-10-01

A 213 nm Nd:YAG-based laser ablation (LA) system coupled to quadrupole-based inductively coupled plasma-mass spectrometer and an ArF* excimer-based LA-system coupled to a double-focusing sector field inductively coupled plasma-mass spectrometer were employed to study the spatial distribution of various elements in kidney stones (uroliths). Sections of the surfaces of uroliths were ablated according to line patterns to investigate the elemental profiles for the different urolith growth zones. This exploratory study was mainly focused on the distinguishing of the main constituents of urinary calculus fragments by means of LA-ICP-mass spectrometry. Changes in the ablation rate for oxalate and phosphate phases related to matrix density and hardness are discussed. Elemental association was investigated on the basis of 2D mapping. The possibility of using NIST SRM 1486 Bone Meal as an external standard for calibration was tested. It is shown that LA-ICP-MS is helpful for determination of the mineralogical composition and size of all phases within the analyzed surface area, for tracing down elemental associations and for documenting the elemental content of urinary stones. LA-ICP-MS results (elemental contents and maps) are compared to those obtained with electron microprobe analysis and solution analysis ICP-MS.

Optical spectroscopy of laser-produced plasmas for standoff isotopic analysis

SciTech Connect

Harilal, S. S.; Brumfield, B. E.; LaHaye, N. L.

This review article covers the present status of isotope detection through emission, absorption, and fluorescence spectroscopy of atoms and molecules in a laser-produced plasma formed from a solid sample. A description of the physics behind isotope shifts in atoms and molecules is presented, followed by the physics behind solid sampling of laser ablation plumes, optical methods for isotope measurements, the suitable physical conditions of laser-produced plasma plumes for isotopic analysis, and the current status. Lastly, concluding remarks will be made on the existing gaps between previous works in the literature and suggestions for future work.

Optical spectroscopy of laser-produced plasmas for standoff isotopic analysis

DOE PAGES

Harilal, S. S.; Brumfield, B. E.; LaHaye, N. L.; ...

2018-06-01

This review article covers the present status of isotope detection through emission, absorption, and fluorescence spectroscopy of atoms and molecules in a laser-produced plasma formed from a solid sample. A description of the physics behind isotope shifts in atoms and molecules is presented, followed by the physics behind solid sampling of laser ablation plumes, optical methods for isotope measurements, the suitable physical conditions of laser-produced plasma plumes for isotopic analysis, and the current status. Finally, concluding remarks will be made on the existing gaps between previous works in the literature and suggestions for future work.

Optical spectroscopy of laser-produced plasmas for standoff isotopic analysis

DOE PAGES

Harilal, S. S.; Brumfield, B. E.; LaHaye, N. L.; ...

2018-04-20

This review article covers the present status of isotope detection through emission, absorption, and fluorescence spectroscopy of atoms and molecules in a laser-produced plasma formed from a solid sample. A description of the physics behind isotope shifts in atoms and molecules is presented, followed by the physics behind solid sampling of laser ablation plumes, optical methods for isotope measurements, the suitable physical conditions of laser-produced plasma plumes for isotopic analysis, and the current status. Lastly, concluding remarks will be made on the existing gaps between previous works in the literature and suggestions for future work.

Optical spectroscopy of laser-produced plasmas for standoff isotopic analysis

SciTech Connect

Harilal, Sivanandan S.; Brumfield, Brian E.; LaHaye, Nicole L.

2018-04-20

This review article covers the present status of isotope detection through emission, absorption, and fluorescence spectroscopy of atoms and molecules in a laser-produced plasma formed from a solid sample. A description of the physics behind isotope shifts in atoms and molecules is presented, followed by the physics behind solid sampling of laser ablation plumes, optical methods for isotope measurements, the suitable physical conditions of laser-produced plasma plumes for isotopic analysis, and the current status. Finally, concluding remarks will be made on the existing gaps between previous works in the literature and suggestions for future work.

Optical spectroscopy of laser-produced plasmas for standoff isotopic analysis

SciTech Connect

Harilal, S. S.; Brumfield, B. E.; LaHaye, N. L.

This review article covers the present status of isotope detection through emission, absorption, and fluorescence spectroscopy of atoms and molecules in a laser-produced plasma formed from a solid sample. A description of the physics behind isotope shifts in atoms and molecules is presented, followed by the physics behind solid sampling of laser ablation plumes, optical methods for isotope measurements, the suitable physical conditions of laser-produced plasma plumes for isotopic analysis, and the current status. Finally, concluding remarks will be made on the existing gaps between previous works in the literature and suggestions for future work.

A randomised controlled trial of ablation of Barrett's oesophagus with multipolar electrocoagulation versus argon plasma coagulation in combination with acid suppression: long term results

PubMed Central

Sharma, P; Wani, S; Weston, A P; Bansal, A; Hall, M; Mathur, S; Prasad, A; Sampliner, R E

2006-01-01

Background Many modalities have been used to ablate Barrett's oesophagus (BO). However, long term results and comparative effectiveness are unknown. Aims Our aim was to compare the long term efficacy of achieving complete reversal (endoscopic and histological) between multipolar electrocoagulation (MPEC) and argon plasma coagulation (APC) in BO patients and assess factors influencing successful ablation. Methods Patients with BO, 2–6 cm long, underwent 24 hour pH testing on proton pump inhibitor (PPI) therapy. Patients were then randomised by BO length to undergo ablation with MPEC or APC every 4–8 weeks until endoscopic reversal or maximal of six treatment sessions. Results Thirty five BO patients have been followed for at least two years following endoscopic ablation, 16 treated with MPEC and 19 with APC. There was complete reversal of BO in 24 patients (69%); 75% with MPEC and 63% with APC (p = 0.49). There was no difference in the number of sessions required in the two groups. There was no difference in age, pH results, BO length, PPI dose, or hiatal hernia size between patients with and without complete reversal. One patient developed an oesophageal stricture but there were no major complications such as bleeding or perforation. Conclusions In BO patients treated with MPEC or APC in combination with acid suppression, at long term follow up, complete reversal of BO can be maintained in approximately 70% of patients, irrespective of the technique. There are no predictors associated with achieving complete reversal of BO. Continued surveillance is still indicated in the post ablative setting. As yet, these techniques are not ready for clinical application (other than for high grade dysplasia or early oesophageal adenocarcinoma) and cannot be offered outside the research arena. PMID:16905695

Discrimination of side-window glass of Korean autos by laser ablation inductively coupled plasma mass spectrometry.

PubMed

Lee, Sin-Woo; Ryu, Jong-Sik; Min, Ji-Sook; Choi, Man-Yong; Lee, Kwang-Sik; Shin, Woo-Jin

2016-07-15

Fragments of glass from cars are often found at crime scenes and can be crucial evidence for solving the crime. The glass fragments are important as trace evidence at crime scenes related to car accidents and burgled homes. By identifying the origin of glass fragments, it is possible to infer the identity of a suspect. Our results represent a promising approach to a thorough forensic investigation of car glass. Thirty-five samples from the side windows of cars produced and used in South Korea were collected from the official agencies of five car manufacturers and from two glassmakers. In addition, 120 samples from side mirrors were collected from the same suppliers as well as from small businesses. Their chemical compositions (including Pb isotopes) were analyzed using laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) and linear discriminant analysis (LDA) was performed. The percentages of major elements (Si, Ca, and Fe) in side-window glass varied within narrow ranges (30.0 ± 2.36%, 5.93 ± 0.52%, and 0.33 ± 0.05%, respectively), while the differences among Pb isotope ratios were not significant. In contrast, light rare earth elements (LREEs) were different from each glassmaker. From the LDA, the types of side-window glass were successfully discriminated according to car manufacturer, glassmaker, and even glass thickness. However, glass from side mirrors cannot be used for good forensic identifiers. Discrimination techniques for side-window glass, although not for side mirrors, using chemical compositions combined with multivariate statistical analyses provide evidence for forensic investigations. Copyright © 2016 John Wiley & Sons, Ltd. Copyright © 2016 John Wiley & Sons, Ltd.

Laser ablation-inductively coupled plasma mass spectrometry for the characterization of pigments in prehistoric rock art.

PubMed

Resano, Martin; García-Ruiz, Esperanza; Alloza, Ramiro; Marzo, Maria P; Vandenabeele, Peter; Vanhaecke, Frank

2007-12-01

In this work, several red-colored paintings of post-Paleolithic schematic style found in 10 different shelters in the vicinity of the Vero River (Huesca) were sampled and subjected to analysis by means of scanning electron microscopy-energy-dispersive X-ray spectrometry (SEM-EDX), Raman spectroscopy, and laser ablation-inductively coupled plasma mass spectrometry (LA-ICPMS). The goal of this research was to obtain meaningful information on the samples composition, in order to establish differences or similarities among them. The combined use of these techniques proved beneficial, as Raman data permitted structural information on the compounds present (hematite was identified as the main pigment, whereas calcite and gypsum are the main components of the substrate layer, as well as of the accretions that covered the pigments) to be obtained, while the quantitative values obtained by SEM were suitable for the use of Ca as internal reference during LA-ICPMS analysis. However, it was this latter technique that provided the most relevant data for fingerprinting purposes. The potential of this technique for obtaining spatially resolved information allowed the multielement quantitative analysis of the pigment layer, in spite of the presence of superficial accretions. The sensitivity of the technique permitted the determination of more than 40 elements present in a wide concentration range (from microgram per gram to 10% level) with minimum sample consumption (approximately 900 ng for each sample, corresponding to five replicates). Finally, in order to establish significant differences, only those elements showing a high correlation with Fe (As, Co, Mo, Sb, Tl, and Zr, in this case) were selected, as it is expected that these were truly present in the original pigment, while others could have migrated into the pigment layer throughout time. By using this information, it seems feasible to discriminate between various paint pots, as demonstrated for the samples under

Visualizing trace element distribution in quartz using cathodoluminescence, electron microprobe, and laser ablation-inductively coupled plasma-mass spectrometry

USGS Publications Warehouse

Rusk, Brian; Koenig, Alan; Lowers, Heather

2011-01-01

Cathodoluminescent (CL) textures in quartz reveal successive histories of the physical and chemical fluctuations that accompany crystal growth. Such CL textures reflect trace element concentration variations that can be mapped by electron microprobe or laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS). Trace element maps in hydrothermal quartz from four different ore deposit types (Carlin-type Au, epithermal Ag, porphyry-Cu, and MVT Pb-Zn) reveal correlations among trace elements and between trace element concentrations and CL textures. The distributions of trace elements reflect variations in the physical and chemical conditions of quartz precipitation. These maps show that Al is the most abundant trace element in hydrothermal quartz. In crystals grown at temperatures below 300 °C, Al concentrations may vary by up to two orders of magnitude between adjacent growth zones, with no evidence for diffusion. The monovalent cations Li, Na, and K, where detectable, always correlate with Al, with Li being the most abundant of the three. In most samples, Al is more abundant than the combined total of the monovalent cations; however, in the MVT sample, molar Al/Li ratios are ~0.8. Antimony is present in concentrations up to ~120 ppm in epithermal quartz (~200–300 °C), but is not detectable in MVT, Carlin, or porphyry-Cu quartz. Concentrations of Sb do not correlate consistently with those of other trace elements or with CL textures. Titanium is only abundant enough to be mapped in quartz from porphyry-type ore deposits that precipitate at temperatures above ~400 °C. In such quartz, Ti concentration correlates positively with CL intensity, suggesting a causative relationship. In contrast, in quartz from other deposit types, there is no consistent correlation between concentrations of any trace element and CL intensity fluctuations.

Debris Albedo from Laser Ablation in Low and High Vacuum: Comparisons to Hypervelocity Impact

NASA Astrophysics Data System (ADS)

Radhakrishnan, G.; Adams, P. M.; Alaan, D. R.; Panetta, C. J.

The albedo of orbital debris fragments in space is a critical parameter used in the derivation of their physical sizes from optical measurements. The change in albedo results from scattering due to micron and sub-micron particles on the surface. There are however no known hypervelocity collision ground tests that simulate the high-vacuum conditions on-orbit. While hypervelocity impact experiments at a gun range can offer a realistic representation of the energy of impact and fragmentation, and can aid the understanding of albedo, they are conducted in low-pressure air that is not representative of the very high vacuum of 10-8 Torr or less that exists in the Low Earth Orbit environment. Laboratory simulation using laser ablation with a high power laser, on the same target materials as used in current satellite structures, is appealing because it allows for well-controlled investigations that can be coupled to optical albedo (reflectance) measurements of the resultant debris. This relatively low-cost laboratory approach can complement the significantly more elaborate and expensive field-testing of single-shot hypervelocity impact on representative satellite structures. Debris generated is optically characterized with UV-VIS-NIR reflectance, and particle size distributions can be measured. In-situ spectroscopic diagnostics (nanosecond time frame) provide an identification of atoms and ions in the plume, and plasma temperatures, allowing a correlation of the energetics of the ablated plume with resulting albedo and particle size distributions of ablated debris. Our laboratory experiments offer both a high-vacuum environment, and selection of any gaseous ambient, at any controlled pressure, thus allowing for comparison to the hypervelocity impact experiments in low-pressure air. Initial results from plume analysis, and size distribution and microstructure of debris collected on witness plates show that laser ablations in low-pressure air offer many similarities to the

Space Shuttle Plume and Plume Impingement Study

NASA Technical Reports Server (NTRS)

Tevepaugh, J. A.; Penny, M. M.

1977-01-01

The extent of the influence of the propulsion system exhaust plumes on the vehicle performance and control characteristics is a complex function of vehicle geometry, propulsion system geometry, engine operating conditions and vehicle flight trajectory were investigated. Analytical support of the plume technology test program was directed at the two latter problem areas: (1) definition of the full-scale exhaust plume characteristics, (2) application of appropriate similarity parameters; and (3) analysis of wind tunnel test data. Verification of the two-phase plume and plume impingement models was directed toward the definition of the full-scale exhaust plume characteristics and the separation motor impingement problem.

Imaging of Selenium by Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS) in 2-D Electrophoresis Gels and Biological Tissues.

PubMed

Cruz, Elisa Castañeda Santa; Susanne Becker, J; Sabine Becker, J; Sussulini, Alessandra

2018-01-01

Selenium and selenoproteins are important components of living organisms that play a role in different biological processes. Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) is a powerful analytical technique that has been employed to obtain distribution maps of selenium in biological tissues in a direct manner, as well as in selenoproteins, previously separated by their molecular masses and isoelectric points using two-dimensional polyacrylamide gel electrophoresis (2-D PAGE). In this chapter, we present the protocols to perform LA-ICP-MS imaging experiments, allowing the distribution visualization and determination of selenium and/or selenoproteins in biological systems.

Experimental Investigation of the Properties of an Acoustic Wave Induced by Laser Ablation of a Solid Target in Water-Confined Plasma Propulsion

NASA Astrophysics Data System (ADS)

Zheng, Zhiyuan; Gao, Hua; Gao, Lu; Xing, Jie

2014-11-01

Acoustic waves generated in nanosecond pulsed-laser ablation of a solid target in both air and water-confined environments were measured experimentally. It was found that the amplitude of the acoustic wave tended to decrease with an increase in water thickness. The waves were analyzed by means of fast Fourier transform. It was shown that there are several frequency components in the acoustic waves with the dominant frequency shifting from high frequency to low frequency as the thickness of the water layer increases. Furthermore, strong acoustic pressure led to enhancement of the coupling of the laser energy to the target in laser plasma propulsion.

Analysis of atmospheric pollutant metals by laser ablation inductively coupled plasma mass spectrometry with a radial line-scan dried-droplet approach

NASA Astrophysics Data System (ADS)

Tang, Xiaoxing; Qian, Yuan; Guo, Yanchuan; Wei, Nannan; Li, Yulan; Yao, Jian; Wang, Guanghua; Ma, Jifei; Liu, Wei

2017-12-01

A novel method has been improved for analyzing atmospheric pollutant metals (Be, Mn, Fe, Co, Ni, Cu, Zn, Se, Sr, Cd, and Pb) by laser ablation inductively coupled plasma mass spectrometry. In this method, solid standards are prepared by depositing droplets of aqueous standard solutions on the surface of a membrane filter, which is the same type as used for collecting atmospheric pollutant metals. Laser parameters were optimized, and ablation behaviors of the filter discs were studied. The mode of radial line scans across the filter disc was a representative ablation strategy and can avoid error from the inhomogeneous filter standards and marginal effect of the filter disc. Pt, as the internal standard, greatly improved the correlation coefficient of the calibration curve. The developed method provides low detection limits, from 0.01 ng m- 3 for Be and Co to 1.92 ng m- 3 for Fe. It was successfully applied for the determination of atmospheric pollutant metals collected in Lhasa, China. The analytical results showed good agreement with those obtained by conventional liquid analysis. In contrast to the conventional acid digestion procedure, the novel method not only greatly reduces sample preparation and shortens the analysis time but also provides a possible means for studying the spatial distribution of atmospheric filter samples.

Matrix and energy effects during in-situ determination of Cu isotope ratios by ultraviolet-femtosecond laser ablation multicollector inductively coupled plasma mass spectrometry

NASA Astrophysics Data System (ADS)

Lazarov, Marina; Horn, Ingo

2015-09-01

Copper isotope compositions in Cu-bearing metals and minerals have been measured by deep (194 nm) ultraviolet femtosecond laser ablation multi-collector inductively coupled plasma mass spectrometry (UV-fsLA-MC-ICP-MS). Pure Cu-metal, brass, and several Cu-rich minerals (chalcopyrite, enargite, covellite, malachite and cuprite) have been investigated. A long-term reproducibility of better than 0.08‰ at the 95% confidence limit on the NIST SRM 976 (National Institute of Standards and Technology) Cu-metal standard has been achieved with this technique. The δ65Cu values for all samples have been calculated by standard-sample-standard bracketing with NIST SRM 976. All analyses have been carried out using Ni as a mass discrimination monitor added by nebulization prior to entering the plasma torch. For further verification samples have been analysed by conventional solution nebulization MC-ICP-MS and the results obtained have been compared with those from UV-fsLA-MC-ICP-MS. Several potential matrix-induced molecular interferences on the mineral copper isotope ratio, such as (32S33S)+ and (32S-16O17O)+ do not affect the Cu isotope measurements on sulfides, while hydrides, such as Zn-H or doubly-charged Sn2 + that interfere Ni isotopes can be either neglected or stripped by calculation. Matrix independent Cu-isotope measurements are sensitive to the energy density (fluence) applied onto the sample and can produce artificial shifts in the obtained δ65Cu values which are on the order of 3‰ for Cu-metal, 0.5‰ for brass and 0.3‰ for malachite when using energy density of up to 2 J/cm2 for ablation. A positive correlation between applied energy density and the magnitude of the isotope ratio shift has been found in the energy density range from 0.2 to 1.3 J/cm2 which is below the ablation threshold for ns-laser ablation. The results demonstrate that by using appropriate low fluence it is possible to measure Cu isotopic ratios in native copper and Cu-bearing sulfides

Laser ablation inductively coupled plasma dynamic reaction cell mass spectrometry for the multi-element analysis of polymers

NASA Astrophysics Data System (ADS)

Resano, M.; García-Ruiz, E.; Vanhaecke, F.

2005-11-01

In this work, the potential of laser ablation-inductively coupled plasma-mass spectrometry for the fast analysis of polymers has been explored. Different real-life samples (polyethylene shopping bags, an acrylonitrile butadiene styrene material and various plastic bricks) as well as several reference materials (VDA 001 to 004, Cd in polyethylene) have been selected for the study. Two polyethylene reference materials (ERM-EC 680 and 681), for which a reference or indicative value for the most relevant metals is available, have proved their suitability as standards for calibration. Special attention has been paid to the difficulties expected for the determination of Cr at the μg g - 1 level in this kind of materials, due to the interference of ArC + ions on the most abundant isotopes of Cr. The use of ammonia as a reaction gas in a dynamic reaction cell is shown to alleviate this problem, resulting in a limit of detection of 0.15 μg g - 1 for this element, while limiting only modestly the possibilities of the technique for simultaneous multi-element analysis. In this regard, As is the analyte most seriously affected by the use of ammonia, and its determination has to be carried out in vented mode, at the expense of measuring time. In all cases studied, accurate results could be obtained for elements ranging in content from the sub-μg g - 1 level to tens of thousands of μg g - 1 . However, the use of an element of known concentration as internal standard may be needed for materials with a matrix significantly different from that of the standard (polyethylene in this work). Precision ranged between 5% and 10% RSD for elements found at the 10 μg g - 1 level or higher, while this value could deteriorate to 20% for analytes found at the sub-μg g - 1 level. Overall, the technique evaluated presents many advantages for the fast and accurate multi-element analysis of these materials, avoiding laborious digestion procedures and minimizing the risk of analyte losses due

Endometrial Ablation

MedlinePlus

... or lighter levels. If ablation does not control heavy bleeding, further treatment or surgery may be needed. ... ablation is used to treat many causes of heavy bleeding. In most cases, women with heavy bleeding ...

The influence of ns- and fs-LA plume local conditions on the performance of a combined LIBS/LA-ICP-MS sensor

SciTech Connect

LaHaye, Nicole L.; Phillips, Mark C.; Duffin, Andrew M.

2016-01-01

Both laser-induced breakdown spectroscopy (LIBS) and laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) are well-established analytical techniques with their own unique advantages and disadvantages. The combination of the two analytical methods is a very promising way to overcome the challenges faced by each method individually. We made a comprehensive comparison of local plasma conditions between nanosecond (ns) and femtosecond (fs) laser ablation (LA) sources in a combined LIBS and LA-ICP-MS system. The optical emission spectra and ICP-MS signal were recorded simultaneously for both ns- and fs-LA and figures of merit of the system were analyzed. Characterization of the plasma was conductedmore » by evaluating temperature and density of the plume under various irradiation conditions using optical emission spectroscopy, and correlations to ns- and fs-LIBS and LA-ICP-MS signal were made. The present study is very useful for providing conditions for a multimodal system as well as giving insight into how laser ablation plume parameters are related to LA-ICP-MS and LIBS results for both ns- and fs-LA.« less

Formation and dynamics of plasma bullets in a non-thermal plasma jet: influence of the high-voltage parameters on the plume characteristics

NASA Astrophysics Data System (ADS)

Jarrige, Julien; Laroussi, Mounir; Karakas, Erdinc

2010-12-01

Non-thermal plasma jets in open air are composed of ionization waves commonly known as 'plasma bullets' propagating at high velocities. We present in this paper an experimental study of plasma bullets produced in a dielectric barrier discharge linear-field reactor fed with helium and driven by microsecond high-voltage pulses. Two discharges were produced between electrodes for every pulse (at the rising and falling edge), but only one bullet was generated. Fast intensified charge coupled device camera imaging showed that bullet velocity and diameter increase with applied voltage. Spatially resolved optical emission spectroscopy measurements provided evidence of the hollow structure of the jet and its contraction. It was shown that the pulse amplitude significantly enhances electron energy and production of active species. The plasma bullet appeared to behave like a surface discharge in the tube, and like a positive streamer in air. A kinetics mechanism based on electron impact, Penning effect and charge transfer reactions is proposed to explain the propagation of the ionization front and temporal behavior of the radiative species.

Laser ablation based fuel ignition

DOEpatents

Early, J.W.; Lester, C.S.

1998-06-23

There is provided a method of fuel/oxidizer ignition comprising: (a) application of laser light to a material surface which is absorptive to the laser radiation; (b) heating of the material surface with the laser light to produce a high temperature ablation plume which emanates from the heated surface as an intensely hot cloud of vaporized surface material; and (c) contacting the fuel/oxidizer mixture with the hot ablation cloud at or near the surface of the material in order to heat the fuel to a temperature sufficient to initiate fuel ignition. 3 figs.

Laser ablation based fuel ignition

DOEpatents

Early, James W.; Lester, Charles S.

1998-01-01

There is provided a method of fuel/oxidizer ignition comprising: (a) application of laser light to a material surface which is absorptive to the laser radiation; (b) heating of the material surface with the laser light to produce a high temperature ablation plume which emanates from the heated surface as an intensely hot cloud of vaporized surface material; and (c) contacting the fuel/oxidizer mixture with the hot ablation cloud at or near the surface of the material in order to heat the fuel to a temperature sufficient to initiate fuel ignition.

Europa Scene: Plume, Galileo, Magnetic Field (Artist's Concept)

NASA Image and Video Library

2018-05-14

Artist's illustration of Jupiter and Europa (in the foreground) with the Galileo spacecraft after its pass through a plume erupting from Europa's surface. A new computer simulation gives us an idea of how the magnetic field interacted with a plume. The magnetic field lines (depicted in blue) show how the plume interacts with the ambient flow of Jovian plasma. The red colors on the lines show more dense areas of plasma. https://photojournal.jpl.nasa.gov/catalog/PIA21922

Subduction disfigured mantle plumes: Plumes that are not plumes?

NASA Astrophysics Data System (ADS)

Druken, K. A.; Stegman, D. R.; Kincaid, C. R.; Griffiths, R. W.

2012-12-01

"Hotspot" volcanism is generally attributed to upwelling of anomalously warm mantle plumes, the intra-plate Hawaiian island chain and its simple age progression serving as an archetypal example. However, interactions of such plumes with plate margins, and in particular with subduction zones, is likely to have been a common occurrence and leads to more complicated geological records. Here we present results from a series of complementary, three-dimensional numerical and laboratory experiments that examine the dynamic interaction between negatively buoyant subducting slabs and positively buoyant mantle plumes. Slab-driven flow is shown to significantly influence the evolution and morphology of nearby plumes, which leads to a range of deformation regimes of the plume head and conduit. The success or failure of an ascending plume head to reach the lithosphere depends on the combination of plume buoyancy and position within the subduction system, where the mantle flow owing to downdip and rollback components of slab motion entrain plume material both vertically and laterally. Plumes rising within the sub-slab region tend to be suppressed by the surrounding flow field, while wedge-side plumes experience a slight enhancement before ultimately being entrained by subduction. Hotspot motion is more complex than that expected at intraplate settings and is primarily controlled by position alone. Regimes include severely deflected conduits as well as retrograde (corkscrew) motion from rollback-driven flow, often with weak and variable age-progression. The interaction styles and surface manifestations of plumes can be predicted from these models, and the results have important implications for potential hotspot evolution near convergent margins.

Plasma plume effects on the conductivity of amorphous-LaAlO{sub 3}/SrTiO{sub 3} interfaces grown by pulsed laser deposition in O{sub 2} and Ar

SciTech Connect

Sambri, A.; Amoruso, S.; Bruzzese, R.

2012-06-04

Amorphous-LaAlO{sub 3}/SrTiO{sub 3} interfaces exhibit metallic conductivity similar to those found for the extensively studied crystalline-LaAlO{sub 3}/SrTiO{sub 3} interfaces. Here, we investigate the conductivity of the amorphous-LaAlO{sub 3}/SrTiO{sub 3} interfaces grown in different pressures of O{sub 2} and Ar background gases. During the deposition, the LaAlO{sub 3} ablation plume is also studied, in situ, by fast photography and space-resolved optical emission spectroscopy. An interesting correlation between interfacial conductivity and kinetic energy of the Al atoms in the plume is observed: to assure conducting interfaces of amorphous-LaAlO{sub 3}/SrTiO{sub 3}, the kinetic energy of Al should be higher than 1 eV. Ourmore » findings add further insights on mechanisms leading to interfacial conductivity in SrTiO{sub 3}-based oxide heterostructures.« less

Formation of carbon allotrope aerosol by colliding plasmas in an inertial fusion reactor

NASA Astrophysics Data System (ADS)

Hirooka, Y.; Sato, H.; Ishihara, K.; Yabuuchi, T.; Tanaka, K. A.

2014-02-01

Along with repeated implosions, the interior of an inertial fusion target chamber is exposed to short pulses of high-energy x-ray, unburned DT-fuel particles, He-ash and pellet debris. As a result, chamber wall materials are subjected to ablation, emitting particles in the plasma state. Ablated particles will either be re-deposited elsewhere or collide with each other, perhaps in the centre-of-symmetry region of the chamber volume. Colliding ablation plasma particles can lead to the formation of clusters to grow into aerosol, possibly floating thereafter, which can deteriorate the subsequent implosion performance via laser scattering, etc. In a laboratory-scale YAG laser setup, the formation of nano-scale aerosol has been demonstrated in vacuum at irradiation power densities of the orders of 108-10 W cm-2 at 10 Hz, each 6 ns long, simulating the high-repetition rate inertial fusion reactor situation. Interestingly, carbon aerosol formation has been observed in the form of fullerene onion, nano- and micro-tubes when laser-ablated plasma plumes of carbon collide with each other. In contrast, colliding plasma plumes of metals tend to generate aerosol in the form of droplets under identical laser irradiation conditions. An atomic and molecular reaction model is proposed to interpret the process of carbon allotrope aerosol formation.

Analysis of rare earth elements in coal fly ash using laser ablation inductively coupled plasma mass spectrometry and scanning electron microscopy

NASA Astrophysics Data System (ADS)

Thompson, Robert L.; Bank, Tracy; Montross, Scott; Roth, Elliot; Howard, Bret; Verba, Circe; Granite, Evan

2018-05-01

Reference standard NIST SRM 1633b and FA 345, a fly ash sample from an eastern U.S. coal power plant, were analyzed to determine and quantify the mineralogical association of rare earth elements (REE). These analyses were completed using laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) and a scanning electron microscope, equipped with an energy-dispersive X-ray spectrometer (SEM-EDS). Internal standardization was avoided by quantifying elemental concentrations by normalizing to 100% oxides. Mineral grains containing elevated REE concentrations were found in diverse chemical environments, but were most commonly found in regions where Al and Si were predominant. Dividing the spot analyses into time segments yielded plots that showed the REE content changing over time as individual mineral grains were being ablated. SEM-EDS images of FA 345 confirmed the trends that were found in the LA-ICP-MS results. Small grains of apatite, monazite, or zircon were frequently observed as free mineral grains or embedded in amorphous aluminosilicate glass and were not associated with ferrous particles. This finding is consistent with previous reports that magnetic enrichment may be an effective way of concentrating non-magnetic REE phases. Furthermore, aggressive mechanical and chemical-based separation schemes will be required to separate and recover REE from aluminosilicate glass.

Multivariate classification of edible salts: Simultaneous Laser-Induced Breakdown Spectroscopy and Laser-Ablation Inductively Coupled Plasma Mass Spectrometry Analysis

NASA Astrophysics Data System (ADS)

Lee, Yonghoon; Nam, Sang-Ho; Ham, Kyung-Sik; Gonzalez, Jhanis; Oropeza, Dayana; Quarles, Derrick; Yoo, Jonghyun; Russo, Richard E.

2016-04-01

Laser-Induced Breakdown Spectroscopy (LIBS) and Laser-Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS), both based on laser ablation sampling, can be employed simultaneously to obtain different chemical fingerprints from a sample. We demonstrated that this analysis approach can provide complementary information for improved classification of edible salts. LIBS could detect several of the minor metallic elements along with Na and Cl, while LA-ICP-MS spectra were used to measure non-metallic and trace heavy metal elements. Principal component analysis using LIBS and LA-ICP-MS spectra showed that their major spectral variations classified the sample salts in different ways. Three classification models were developed by using partial least squares-discriminant analysis based on the LIBS, LA-ICP-MS, and their fused data. From the cross-validation performances and confusion matrices of these models, the minor metallic elements (Mg, Ca, and K) detected by LIBS and the non-metallic (I) and trace heavy metal (Ba, W, and Pb) elements detected by LA-ICP-MS provided complementary chemical information to distinguish particular salt samples.

Inductively coupled plasma mass spectrometry (ICP-MS) and laser ablation ICP-MS for isotope analysis of long-lived radionuclides

NASA Astrophysics Data System (ADS)

Becker, J. Sabine

2005-04-01

For a few years now inductively coupled plasma mass spectrometry has been increasingly used for precise and accurate determination of isotope ratios of long-lived radionuclides at the trace and ultratrace level due to its excellent sensitivity, good precision and accuracy. At present, ICP-MS and also laser ablation ICP-MS are applied as powerful analytical techniques in different fields such as the characterization of nuclear materials, recycled and by-products (e.g., spent nuclear fuel or depleted uranium ammunitions), radioactive waste control, in environmental monitoring and in bioassay measurements, in health control, in geochemistry and geochronology. Especially double-focusing sector field ICP mass spectrometers with single ion detector or with multiple ion collector device have been used for the precise determination of long-lived radionuclides isotope ratios at very low concentration levels. Progress has been achieved by the combination of ultrasensitive mass spectrometric techniques with effective separation and enrichment procedures in order to improve detection limits or by the introduction of the collision cell in ICP-MS for reducing disturbing interfering ions (e.g., of 129Xe+ for the determination of 129I). This review describes the state of the art and the progress of ICP-MS and laser ablation ICP-MS for isotope ratio measurements of long-lived radionuclides in different sample types, especially in the main application fields of characterization of nuclear and radioactive waste material, environmental research and health controls.

Development of laser ablation multi-collector inductively coupled plasma mass spectrometry for boron isotopic measurement in marine biocarbonates: new improvements and application to a modern Porites coral.

PubMed

Thil, François; Blamart, Dominique; Assailly, Caroline; Lazareth, Claire E; Leblanc, Thierry; Butsher, John; Douville, Eric

2016-02-15

Laser Ablation coupled to Multi-Collector Inductively Coupled Plasma Mass Spectrometry (LA-MC-ICPMS) is a powerful tool for the high-precision measurement of the isotopic ratios of many elements in geological samples, with the isotope ratio ((11) B/(10) B) of boron being used as an indicator of the pH of oceanic waters. Most geological samples or standards are polished and ablation occurs on flat surfaces. However, the shape and the irregularities of marine biocarbonates (e.g., corals, foraminifera) can make precise isotopic measurements of boron difficult. Even after polishing, the porosity properties and the presence of holes or micro-fractures affect the signal and the isotopic ratio when ablating the material, especially in raster mode. The effect of porosity and of the crater itself on the (11) B signal and the isotopic ratio acquired by LA-MC-ICPMS in both raster and spot mode was studied. Characterization of the craters was then performed with an optical profilometer to determine their shapes and depths. Surface state effects were examined by analyzing the isotopic fractionation of boron in silicate (NIST-SRM 612 and 610 standards) and in carbonate (corals). Surface irregularities led to a considerable loss of signal when the crater depth exceeded 20 µm. The stability and precision were degraded when ablation occurred in a deep cavity. The effect of laser focusing and of blank correction was also highlighted and our observations indicate that the accuracy of the boron isotopic ratio does not depend on the shape of the surface. After validation of the analytical protocol for boron isotopes, a raster application on a Porites coral, which grew for 18 months in an aquarium after field sampling, was carried out. This original LA-MC-ICPMS study revealed a well-marked boron isotope ratio temporal variability, probably related to growth rate and density changes, irrespective of the pH of the surrounding seawater. Copyright © 2015 John Wiley & Sons, Ltd. Copyright

Tissue ablation after 120W greenlight laser vaporization and bipolar plasma vaporization of the prostate: a comparison using transrectal three-dimensional ultrasound volumetry

NASA Astrophysics Data System (ADS)

Kranzbühler, Benedikt; Gross, Oliver; Fankhauser, Christian D.; Hefermehl, Lukas J.; Poyet, Cédric; Largo, Remo; Müntener, Michael; Seifert, Hans-Helge; Zimmermann, Matthias; Sulser, Tullio; Müller, Alexander; Hermanns, Thomas

2012-02-01

Introduction and objectives: Greenlight laser vaporization (LV) of the prostate is characterized by simultaneous vaporization and coagulation of prostatic tissue resulting in tissue ablation together with excellent hemostasis during the procedure. It has been reported that bipolar plasma vaporization (BPV) of the prostate might be an alternative for LV. So far, it has not been shown that BPV is as effective as LV in terms of tissue ablation or hemostasis. We performed transrectal three-dimensional ultrasound investigations to compare the efficiency of tissue ablation between LV and BPV. Methods: Between 11.2009 and 5.2011, 50 patients underwent pure BPV in our institution. These patients were matched with regard to the pre-operative prostate volume to 50 LV patients from our existing 3D-volumetry-database. Transrectal 3D ultrasound and planimetric volumetry of the prostate were performed pre-operatively, after catheter removal, 6 weeks and 6 months. Results: Median pre-operative prostate volume was not significantly different between the two groups (45.3ml vs. 45.4ml; p=1.0). After catheter removal, median absolute volume reduction (BPV 12.4ml, LV 6.55ml) as well as relative volume reduction (27.8% vs. 16.4%) were significantly higher in the BPV group (p<0.001). After six weeks (42.9% vs. 33.3%) and six months (47.2% vs. 39.7%), relative volume reduction remained significantly higher in the BPV group (p<0.001). Absolute volume reduction was non-significantly higher in the BPV group after six weeks (18.4ml, 13.8ml; p=0.051) and six months (20.8ml, 18ml; p=0.3). Clinical outcome parameters improved significantly in both groups without relevant differences between the groups. Conclusions: Both vaporization techniques result in efficient tissue ablation with initial prostatic swelling. BPV seems to be superior due to a higher relative volume reduction. This difference had no clinical impact after a follow-up of 6M.

Investigation of heavy-metal accumulation in selected plant samples using laser induced breakdown spectroscopy and laser ablation inductively coupled plasma mass spectrometry

NASA Astrophysics Data System (ADS)

Galiová, M.; Kaiser, J.; Novotný, K.; Novotný, J.; Vaculovič, T.; Liška, M.; Malina, R.; Stejskal, K.; Adam, V.; Kizek, R.

2008-12-01

Single-pulse Laser-Induced Breakdown Spectroscopy (LIBS) and Laser-Ablation Inductively Coupled Plasma Mass-Spectrometry (LA-ICP-MS) were applied for mapping the silver and copper distribution in Helianthus Annuus L. samples treated with contaminant in controlled conditions. For Ag and Cu detection the 328.07 nm Ag(I) and 324.75 nm Cu(I) lines were used, respectively. The LIBS experimental conditions (mainly the laser energy and the observation window) were optimized in order to avoid self-absorption effect in the measured spectra. In the LA-ICP-MS analysis the Ag 107 and Cu 63 isotopes were detected. The capability of these two analytical techniques for high-resolution mapping of selected trace chemical elements was demonstrated.

Experimental and Numerical Examination of a Hall Thruster Plume (Preprint)

DTIC Science & Technology

2007-07-31

Hall thruster has been characterized through measurements from various plasma electrostatic probes. Ion current flux, plasma potential, plasma density, and electron temperatures were measured from the near-field plume to 60 cm downstream of the exit plane. These experimentally derived measurements were compared to numerical simulations run with the plasma plume code DRACO. A major goal of this study was to determine the fidelity of the DRACO numerical simulation. The effect of background pressure on the thruster plume was also examined using ion current flux measurements

Modeling a Hall Thruster from Anode to Plume Far Field

DTIC Science & Technology

2005-01-01

Hall thruster simulation capability that begins with propellant injection at the thruster anode, and ends in the plume far field. The development of a comprehensive simulation capability is critical for a number of reasons. The main motivation stems from the need to directly couple simulation of the plasma discharge processes inside the thruster and the transport of the plasma to the plume far field. The simulation strategy will employ two existing codes, one for the Hall thruster device and one for the plume. The coupling will take place in the plume

Toward a comprehensive UV laser ablation modeling of multicomponent materials—A non-equilibrium investigation on titanium carbide

NASA Astrophysics Data System (ADS)

Ait Oumeziane, Amina; Parisse, Jean-Denis

2018-05-01

Titanium carbide (TiC) coatings of great quality can be produced using nanosecond pulsed laser deposition (PLD). Because the deposition rate and the transfer of the target stoichiometry depend strongly on the laser-target/laser-plasma interaction as well as the composition of the laser induced plume, investigating the ruling fundamental mechanisms behind the material ablation and the plasma evolution in the background environment under PLD conditions is essential. This work, which extends previous investigations dedicated to the study of nanosecond laser ablation of pure target materials, is a first step toward a comprehensive non-equilibrium model of multicomponent ones. A laser-material interaction model coupled to a laser-plasma interaction one is presented. A UV 20 ns KrF (248 nm) laser pulse is considered. Ablation depths, plasma ignition thresholds, and shielding rates have been calculated for a wide range of laser beam fluences. A comparison of TiC behavior with pure titanium material under the same conditions is made. Plasma characteristics such as temperature and composition have been investigated. An overall correlation between the various results is presented.

Tandem Laser Induced Breakdown Spectroscopy (LIBS), Laser Ablation Inductively Coupled Plasma Mass Spectroscopy (LA-ICP-MS) and/or Laser Ablation Inductively Coupled Plasma Optical Emission Spectroscopy (LA-ICP-OES) for the analysis of samples of geological interest

NASA Astrophysics Data System (ADS)

Oropeza, D.

2016-12-01

A highly innovative laser ablation sampling instrument (J200 Tandem LA - LIBS) that combines the capabilities and analytical benefits of LIBS, LA-ICP-MS and LA-ICP-OES was used for micrometer-scale, spatially-resolved, elemental analysis of a wide variety of samples of geological interest. Data collected using ablation systems consisted of nanosecond (Nd:YAG operated 266nm) and femtosecond lasers (1030 and 343nm). An ICCD LIBS detector and Quadrupole based mass spectrometer were selected for LIBS and ICP-MS detection, respectively. This tandem instrument allows simultaneous determination of major and minor elements (for example, Si, Ca, Na, and Al, and trace elements such as Li, Ce, Cr, Sr, Y, Zn, Zr among others). The research also focused on elemental mapping and calibration strategies, specifically the use of emission and mass spectra for multivariate data analysis. Partial Least Square Regression (PLSR) is shown to minimize and compensate for matrix effects in the emission and mass spectra improving quantitative analysis by LIBS and LA-ICP-MS, respectively. The study provides a benchmark to evaluate analytical results for more complex geological sample matrices.

High-speed photography of plasma during excimer laser-tissue interaction.

PubMed

Murray, Andrea K; Dickinson, Mark R

2004-08-07

During high fluence laser-tissue interaction, ablation of tissue occurs, debris is removed from the ablation site and is then ejected at high velocity. This debris may be observed as a combination of luminous plasma and non-luminous plume, both of which have the potential to shield the ablation site. This study examined the role of ablation debris in shielding the tissue and determined its effects on the ablation rate over a range of laser pulse energies, pulse repetition rates and pulse numbers for dentine; the velocity differences between hard and soft tissues were also examined. High-speed photography was carried out at up to 1 x 10(8) frames per second. A maximum velocity of 2.58 +/- 0.52 x 10(4) m s(-1) was recorded for dentine debris within the first 10 ns following ejection. The maximum duration of tissue shielding due to a single pulse, determined by attenuation of a probe beam, was found to be approximately 7 ms, approximately 80 micros of which was due to luminous plasma and the remainder due to the non-luminous plume.

Galileo observations of volcanic plumes on Io

USGS Publications Warehouse

Geissler, P.E.; McMillan, M.T.

2008-01-01

Io's volcanic plumes erupt in a dazzling variety of sizes, shapes, colors and opacities. In general, the plumes fall into two classes, representing distinct source gas temperatures. Most of the Galileo imaging observations were of the smaller, more numerous Prometheus-type plumes that are produced when hot flows of silicate lava impinge on volatile surface ices of SO2. Few detections were made of the giant, Pele-type plumes that vent high temperature, sulfur-rich gases from the interior of Io; this was partly because of the insensitivity of Galileo's camera to ultraviolet wavelengths. Both gas and dust spout from plumes of each class. Favorably located gas plumes were detected during eclipse, when Io was in Jupiter's shadow. Dense dust columns were imaged in daylight above several Prometheus-type eruptions, reaching heights typically less than 100 km. Comparisons between eclipse observations, sunlit images, and the record of surface changes show that these optically thick dust columns are much smaller in stature than the corresponding gas plumes but are adequate to produce the observed surface deposits. Mie scattering calculations suggest that these conspicuous dust plumes are made up of coarse grained “ash” particles with radii on the order of 100 nm, and total masses on the order of 106 kg per plume. Long exposure images of Thor in sunlight show a faint outer envelope apparently populated by particles small enough to be carried along with the gas flow, perhaps formed by condensation of sulfurous “snowflakes” as suggested by the plasma instrumentation aboard Galileo as it flew through Thor's plume [Frank, L.A., Paterson, W.R., 2002. J. Geophys. Res. (Space Phys.) 107, doi:10.1029/2002JA009240. 31-1]. If so, the total mass of these fine, nearly invisible particles may be comparable to the mass of the gas, and could account for much of Io's rapid resurfacing.

Modeling Europa's dust plumes

NASA Astrophysics Data System (ADS)

Southworth, B. S.; Kempf, S.; Schmidt, J.

2015-12-01

The discovery of Jupiter's moon Europa maintaining a probably sporadic water vapor plume constitutes a huge scientific opportunity for NASA's upcoming mission to this Galilean moon. Measuring properties of material emerging from interior sources offers a unique chance to understand conditions at Europa's subsurface ocean. Exploiting results obtained for the Enceladus plume, we simulate possible Europa plume configurations, analyze particle number density and surface deposition results, and estimate the expected flux of ice grains on a spacecraft. Due to Europa's high escape speed, observing an active plume will require low-altitude flybys, preferably at altitudes of 5-100 km. At higher altitudes a plume may escape detection. Our simulations provide an extensive library documenting the possible structure of Europa dust plumes, which can be quickly refined as more data on Europa dust plumes are collected.

In situ location and U-Pb dating of small zircon grains in igneous rocks using laser ablation-inductively coupled plasma-quadrupole mass spectrometry

NASA Astrophysics Data System (ADS)

Sack, Patrick J.; Berry, Ron F.; Meffre, Sebastien; Falloon, Trevor J.; Gemmell, J. Bruce; Friedman, Richard M.

2011-05-01

A new U-Pb zircon dating protocol for small (10-50 μm) zircons has been developed using an automated searching method to locate zircon grains in a polished rock mount. The scanning electron microscope-energy-dispersive X ray spectrum-based automated searching method can routinely find in situ zircon grains larger than 5 μm across. A selection of these grains was ablated using a 10 μm laser spot and analyzed in an inductively coupled plasma-quadrupole mass spectrometer (ICP-QMS). The technique has lower precision (˜6% uncertainty at 95% confidence on individual spot analyses) than typical laser ablation ICP-MS (˜2%), secondary ion mass spectrometry (<1%), and isotope dilution-thermal ionization mass spectrometry (˜0.4%) methods. However, it is accurate and has been used successfully on fine-grained lithologies, including mafic rocks from island arcs, ocean basins, and ophiolites, which have traditionally been considered devoid of dateable zircons. This technique is particularly well suited for medium- to fine-grained mafic volcanic rocks where zircon separation is challenging and can also be used to date rocks where only small amounts of sample are available (clasts, xenoliths, dredge rocks). The most significant problem with dating small in situ zircon grains is Pb loss. In our study, many of the small zircons analyzed have high U contents, and the isotopic compositions of these grains are consistent with Pb loss resulting from internal α radiation damage. This problem is not significant in very young rocks and can be minimized in older rocks by avoiding high-U zircon grains.

Analysis and comparison of glass fragments by laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) and ICP-MS.

PubMed

Trejos, Tatiana; Montero, Shirly; Almirall, José R

2003-08-01

The discrimination potential of Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS) is compared with previously reported solution ICP-MS methods using external calibration (EC) with internal standardization and a newly reported solution isotope dilution (ID) method for the analysis of two different glass populations. A total of 91 different glass samples were used for the comparison study; refractive index and elemental composition were measured by the techniques mentioned above. One set consisted of 45 headlamps taken from a variety of automobiles that represents a range of 20 years of manufacturing dates. A second set consisted of 46 automotive glasses (side windows, rear windows, and windshields) representing casework glass from different vehicle manufacturers over several years. The element menu for the LA-ICP-MS and EC-ICP-MS methods include Mg, Al, Ca, Mn, Ce, Ti, Zr, Sb, Ga, Ba, Rb, Sm, Sr, Hf, La, and Pb. The ID method was limited to the analysis of two isotopes each of Mg, Sr, Zr, Sb, Ba, Sm, Hf, and Pb. Laser ablation analyses were performed with a Q switched Nd:YAG, 266 nm, 6 mJ output energy laser. The laser was used in depth profile mode while sampling using a 50 microm spot size for 50 sec at 10 Hz (500 shots). The typical bias for the analysis of NIST 612 by LA-ICP-MS was less than 5% in all cases and typically better than 5% for most isotopes. The precision for the vast majority of the element menu was determined generally less than 10% for all the methods when NIST 612 was measured (40 microg x g(-1)). Method detection limits (MDL) for the EC and LA-ICP-MS methods were similar and generally reported as less than 1 microg x g(-1) for the analysis of NIST 612. While the solution sample introduction methods using EC and ID presented excellent sensitivity and precision, these methods have the disadvantages of destroying the sample, and also involve complex sample preparation. The laser ablation method was simpler, faster, and

Ablation article and method

NASA Technical Reports Server (NTRS)

Erickson, W. D.; Sullivan, E. M. (Inventor)

1973-01-01

An ablation article, such as a conical heat shield, having an ablating surface is provided with at least one discrete area of at least one seed material, such as aluminum. When subjected to ablation conditions, the seed material is ablated. Radiation emanating from the ablated seed material is detected to analyze ablation effects without disturbing the ablation surface. By providing different seed materials having different radiation characteristics, the ablating effects on various areas of the ablating surface can be analyzed under any prevailing ablation conditions. The ablating article can be provided with means for detecting the radiation characteristics of the ablated seed material to provide a self-contained analysis unit.

Simultaneous measurement of sulfur and lead isotopes in sulfides using nanosecond laser ablation coupled with two multi-collector inductively coupled plasma mass spectrometers

NASA Astrophysics Data System (ADS)

Yuan, Honglin; Liu, Xu; Chen, Lu; Bao, Zhian; Chen, Kaiyun; Zong, Chunlei; Li, Xiao-Chun; Qiu, Johnson Wenhong

2018-04-01

We herein report the coupling of a nanosecond laser ablation system with a large-scale multi-collector inductively coupled plasma mass spectrometer (Nu1700 MC-ICPMS, NP-1700) and a conventional Nu Plasma II MC-ICPMS (NP-II) for the simultaneous laser ablation and determination of in situ S and Pb isotopic compositions of sulfide minerals. We found that the required aerosol distribution between the two spectrometers depended on the Pb content of the sample. For example, for a sulfide containing 100-3000 ppm Pb, the aerosol was distributed between the NP-1700 and the NP-II spectrometers in a 1:1 ratio, while for lead contents >3000 and <100 ppm, these ratios were 5:1 and 1:3, respectively. In addition, S isotopic analysis showed a pronounced matrix effect, so a matrix-matched external standard was used for standard-sample bracketing correction. The NIST NBS 977 (NBS, National Bureau of Standards; NIST, National Institute of Standards & Technology) Tl (thallium) dry aerosol internal standard and the NIST SRM 610 (SRM, standard reference material) external standard were employed to obtain accurate results for the analysis of Pb isotopes. In tandem experiments where airflow conditions were similar to those employed during stand-alone analyses, small changes in the aerosol carrier gas flow did not significantly influence the accurate determination of S and Pb isotope ratios. In addition, careful optimization of the flow ratio of the aerosol carrier (He) and makeup (Ar) gases to match stand-alone analytical conditions allowed comparable S and Pb isotope ratios to be obtained within an error of 2 s analytical uncertainties. Furthermore, the results of tandem analyses obtained using our method were consistent with those of previously reported stand-alone techniques for the S and Pb isotopes of chalcopyrite, pyrite, galena, and sphalerite, thus indicating that this method is suitable for the simultaneous analysis of S and Pb isotopes of natural sulfide minerals, and provides

Development of routines for simultaneous in situ chemical composition and stable Si isotope ratio analysis by femtosecond laser ablation inductively coupled plasma mass spectrometry.

PubMed

Frick, Daniel A; Schuessler, Jan A; von Blanckenburg, Friedhelm

2016-09-28

Stable metal (e.g. Li, Mg, Ca, Fe, Cu, Zn, and Mo) and metalloid (B, Si, Ge) isotope ratio systems have emerged as geochemical tracers to fingerprint distinct physicochemical reactions. These systems are relevant to many Earth Science questions. The benefit of in situ microscale analysis using laser ablation (LA) over bulk sample analysis is to use the spatial context of different phases in the solid sample to disclose the processes that govern their chemical and isotopic compositions. However, there is a lack of in situ analytical routines to obtain a samples' stable isotope ratio together with its chemical composition. Here, we evaluate two novel analytical routines for the simultaneous determination of the chemical and Si stable isotope composition (δ(30)Si) on the micrometre scale in geological samples. In both routines, multicollector inductively coupled plasma mass spectrometry (MC-ICP-MS) is combined with femtosecond-LA, where stable isotope ratios are corrected for mass bias using standard-sample-bracketing with matrix-independent calibration. The first method is based on laser ablation split stream (LASS), where the laser aerosol is split and introduced simultaneously into both the MC-ICP-MS and a quadrupole ICP-MS. The second method is based on optical emission spectroscopy using direct observation of the MC-ICP-MS plasma (LA-MC-ICP-MS|OES). Both methods are evaluated using international geological reference materials. Accurate and precise Si isotope ratios were obtained with an uncertainty typically better than 0.23‰, 2SD, δ(30)Si. With both methods major element concentrations (e.g., Na, Al, Si, Mg, Ca) can be simultaneously determined. However, LASS-ICP-MS is superior over LA-MC-ICP-MS|OES, which is limited by its lower sensitivity. Moreover, LASS-ICP-MS offers trace element analysis down to the μg g(-1)-range for more than 28 elements due to lower limits of detection, and with typical uncertainties better than 15%. For in situ simultaneous

A novel method for fabrication of size-controlled metallic nanoparticles by laser ablation

NASA Astrophysics Data System (ADS)

Choudhury, Kaushik; Singh, R. K.; Ranjan, Mukesh; Kumar, Ajai; Srivastava, Atul

2017-12-01

Time resolved experimental investigation of laser produced plasma-induced shockwaves has been carried out in the presence of confining walls placed along the lateral directions using a Mach Zehnder interferometer in air ambient. Copper was used as target material. The primary and the reflected shock waves and their effects on the evolution of medium density and the plasma density have been studied. The reflected shock wave has been seen to be affecting the shape and density of the plasma plume in the confined geometry. The same experiments were performed with water and isopropyl alcohol as the ambient liquids and the produced nanoparticles were characterised for size and size distribution. Significant differences in the size and size distribution are seen in case of the nanoparticles produced from the ablation of the targets with and without confining boundary. The observed trend has been attributed to the presence of confining boundary and the way it affects the thermalisation time of the plasma plume. The experiments also show the effect of medium density on the mean size of the copper nanoparticles produced.

Monitoring the formation of inorganic fullerene-like MoS2 nanostructures by laser ablation in liquid environments

NASA Astrophysics Data System (ADS)

Compagnini, Giuseppe; Sinatra, Marco G.; Messina, Gabriele C.; Patanè, Giacomo; Scalese, Silvia; Puglisi, Orazio

2012-05-01

Laser ablation of solid targets in liquid media is emerging as a simple, clean and reproducible way to generate a large number of intriguing nanometric structures with peculiar properties. In this work we present some results on the formation of MoS2 fullerene-like nanoparticles (10-15 nm diameter) obtained by the ablation of crystalline targets in water. Such a top-down approach can be considered greener than standard sulphidization reactions and represents an intriguing single step procedure. The generation of the MoS2 nanostructures is in competition with that of oxide clusters and strongly depends on the oxidative environment created by the plasma plume. The size, shape and crystalline phase of the obtained nanoparticles are studied by microscopy while X-Ray Photoelectron Spectroscopy is used to investigate the chemical state of produced nanostructures and to propose mechanisms for their growth.

Population inversions in ablation plasmas generated by intense electron beams. Final report, 1 November 1985-31 October 1988

SciTech Connect

Gilgenbach, R.M.; Kammash, T.; Brake, M.L.

1988-11-01

Experiments during the past three years have concerned the generation and spectroscopic study of electron beam-driven carbon plasmas in order to explore the production of optical and ultraviolet radiation from nonequilibrium populations. The output of MELBA (Michigan Electron Long Beam Accelerator), has been connected to an electron-beam diode consisting of an aluminum (or brass) cathode stalk and a carbon anode. Magnetic-field coils were designed, procured, and utilized to focus the electron beam. A side viewing port permitted spectroscopic diagnostics to view across the surface of the anode. Spectroscopic diagnosis was performed using a 1-m spectrograph capable of operation from themore » vacuum-ultraviolet through the visible. This spectrograph is coupled to a 1024-channel optical multichannel analyzer. Spectra taken during the initial 400-ns period of the e-beam pulse showed a low effective-charge plasma with primarily molecular components (C/sub 2/, CH) as well as atomic hydrogen and singly ionized carbon (CII). When the generator pulse was crowbarred after the first 400 ns, the spectra revealed a continuation of the low-charge-state plasma. At times greater than 400 ns in non-crowbarred shots, the spectra revealed a highly ionized plasma with a very large intensity line at 2530 Angstroms due to CIV (5g-4f), and lower-intensity lines due to CIII and CII. This CIV line emission increased with time, peaking sharply between 750 and 900 ns, and decayed rapidly in less than 100 ns. Emission from these high ionization states may be due to electron beam-plasma instabilities, as this emission was accompanied by high levels of radio frequency and microwave emission.« less

Ion dynamics of a laser produced aluminium plasma at different ambient pressures

NASA Astrophysics Data System (ADS)

Sankar, Pranitha; Shashikala, H. D.; Philip, Reji

2018-01-01

Plasma is generated by pulsed laser ablation of an Aluminium target using 1064 nm, 7 ns Nd:YAG laser pulses. The spatial and temporal evolution of the whole plasma plume, as well as that of the ionic (Al2+) component present in the plume, are investigated using spectrally resolved time-gated imaging. The influence of ambient gas pressure on the expansion dynamics of Al2+ is studied in particular. In vacuum (10-5 Torr, 10-2 Torr) the whole plume expands adiabatically and diffuses into the ambient. For higher pressures in the range of 1-10 Torr plume expansion is in accordance with the shock wave model, while at 760 Torr the expansion follows the drag model. On the other hand, the expansion dynamics of the Al2+ component, measured by introducing a band pass optical filter in the detection system, fits to the shock wave model for the entire pressure range of 10-2 Torr to 760 Torr. The expansion velocities of the whole plume and the Al2+ component have been measured in vacuum. These dynamics studies are of potential importance for applications such as laser-driven plasma accelerators, ion acceleration, pulsed laser deposition, micromachining, laser-assisted mass spectrometry, ion implantation, and light source generation.

RELATIVE ABUNDANCE MEASUREMENTS IN PLUMES AND INTERPLUMES

SciTech Connect

Guennou, C.; Hahn, M.; Savin, D. W., E-mail: cguennou@iac.es

2015-07-10

We present measurements of relative elemental abundances in plumes and interplumes. Plumes are bright, narrow structures in coronal holes that extend along open magnetic field lines far out into the corona. Previous work has found that in some coronal structures the abundances of elements with a low first ionization potential (FIP) <10 eV are enhanced relative to their photospheric abundances. This coronal-to-photospheric abundance ratio, commonly called the FIP bias, is typically 1 for elements with a high-FIP (>10 eV). We have used Extreme Ultraviolet Imaging Spectrometer observations made on 2007 March 13 and 14 over a ≈24 hr period tomore » characterize abundance variations in plumes and interplumes. To assess their elemental composition, we used a differential emission measure analysis, which accounts for the thermal structure of the observed plasma. We used lines from ions of iron, silicon, and sulfur. From these we estimated the ratio of the iron and silicon FIP bias relative to that for sulfur. From the results, we have created FIP-bias-ratio maps. We find that the FIP-bias ratio is sometimes higher in plumes than in interplumes and that this enhancement can be time dependent. These results may help to identify whether plumes or interplumes contribute to the fast solar wind observed in situ and may also provide constraints on the formation and heating mechanisms of plumes.« less

Forensic analysis of printing inks using tandem Laser Induced Breakdown Spectroscopy and Laser Ablation Inductively Coupled Plasma Mass Spectrometry

NASA Astrophysics Data System (ADS)

Subedi, Kiran; Trejos, Tatiana; Almirall, José

2015-01-01

Elemental analysis, using either LA-ICP-MS or LIBS, can be used for the chemical characterization of materials of forensic interest to discriminate between source materials originating from different sources and also for the association of materials known to originate from the same source. In this study, a tandem LIBS/LA-ICP-MS system that combines the benefits of both LIBS and LA-ICP-MS was evaluated for the characterization of samples of printing inks (toners, inkjets, intaglio and offset.). The performance of both laser sampling methods is presented. A subset of 9 black laser toners, 10 colored (CMYK) inkjet samples, 12 colored (CMYK) offset samples and 12 intaglio inks originating from different manufacturing sources were analyzed to evaluate the discrimination capability of the tandem method. These samples were selected because they presented a very similar elemental profile by LA-ICP-MS. Although typical discrimination between different ink sources is found to be > 99% for a variety of inks when only LA-ICP-MS was used for the analysis, additional discrimination was achieved by combining the elemental results from the LIBS analysis to the LA-ICP-MS analysis in the tandem technique, enhancing the overall discrimination capability of the individual laser ablation methods. The LIBS measurements of the Ca, Fe, K and Si signals, in particular, improved the discrimination for this specific set of different ink samples previously shown to exhibit very similar LA-ICP-MS elemental profiles. The combination of these two techniques in a single setup resulted in better discrimination of the printing inks with two distinct fingerprint spectra, providing information from atomic/ionic emissions and isotopic composition (m/z) for each ink sample.

Three Dimensional Hybrid Simulations of Super-Alfvénic Laser Ablation Experiments in the Large Plasma Device

NASA Astrophysics Data System (ADS)

Clark, Stephen; Winske, Dan; Schaeffer, Derek; Everson, Erik; Bondarenko, Anton; Constantin, Carmen; Niemann, Christoph

2014-10-01

We present 3D hybrid simulations of laser produced expanding debris clouds propagating though a magnetized ambient plasma in the context of magnetized collisionless shocks. New results from the 3D code are compared to previously obtained simulation results using a 2D hybrid code. The 3D code is an extension of a previously developed 2D code developed at Los Alamos National Laboratory. It has been parallelized and ported to execute on a cluster environment. The new simulations are used to verify scaling relationships, such as shock onset time and coupling parameter (Rm /ρd), developed via 2D simulations. Previous 2D results focus primarily on laboratory shock formation relevant to experiments being performed on the Large Plasma Device, where the shock propagates across the magnetic field. The new 3D simulations show wave structure and dynamics oblique to the magnetic field that introduce new physics to be considered in future experiments.

Application and Analysis of the Isoelectronic Line Ratio Temperature Diagnostic in a Planar Ablating-Plasma Experiment at the National Ignition Facility

NASA Astrophysics Data System (ADS)

Epstein, R.; Rosenberg, M. J.; Solodov, A. A.; Myatt, J. F.; Regan, S. P.; Seka, W.; Hohenberger, M.; Barrios, M. A.; Moody, J. D.

2015-11-01

The Mn/Co isoelectronic emission-line ratio from a microdot source in planar CH foil targets was measured to infer the electron temperature (Te) in the ablating plasma during two-plasmon-decay experiments at the National Ignition Facility (NIF). We examine the systematic uncertainty in the Te estimate based on the temperature and density sensitivities of the line ratio in conjunction with plausible density constraints, and its contribution to the total Te estimate uncertainty. The potential advantages of alternative microdot elements (e.g., Ti/Cr and Sc/V) are considered. The microdot mass was selected to provide ample line strength while minimizing the effect of self-absorption on the line emission, which is of particular concern, given the narrow linewidths of mid- Z emitters at subcritical electron densities. Atomic line-formation theory and detailed atomic-radiative simulations show that the straight forward interpretation of the isoelectronic ratio solely in terms of its temperature independence remains valid with lines of moderate optical thickness (up to ~ 10) at line center. This material is based upon work supported by the Department of Energy National Nuclear Security Administration under Award Number DE-NA0001944.

Determination of Os by isotope dilution-inductively coupled plasma-mass spectrometry with the combination of laser ablation to introduce chemically separated geological samples

NASA Astrophysics Data System (ADS)

Sun, Yali; Ren, Minghao; Xia, Xiaoping; Li, Congying; Sun, Weidong

2015-11-01

A method was developed for the determination of trace Os in geological samples by laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) with the combination of chemical separation and preconcentration. Samples are digested using aqua regia in Carius tubes, and the Os analyte is converted into volatile OsO4, which is distilled and absorbed with HBr. The HBr solution is concentrated for further Os purification using the microdistillation technique. The purified Os is dissolved in 10 μl of 0.02% sucrose-0.005% H3PO4 solution and then evaporated on pieces of perfluoroalkoxy (PFA) film, resulting in the formation of a tiny object (< 3 × 104 μm2 superficial area). Using LA-ICP-MS measurements, the object can give Os signals at least 100 times higher than those provided by routine solution-ICP-MS while successfully avoiding the memory effect. The procedural blank and detection limit in the developed technique are 3.0 pg and 1.8 pg for Os, respectively when 1 g of samples is taken. Reference materials (RM) are analyzed, and their Os concentrations obtained by isotope dilution are comparable to reference or literature values. Based on the individual RM results, the precision is estimated within the range of 0.6 to 9.4% relative standard deviation (RSD), revealing that this method is applicable to the determination of trace Os in geological samples.

Analytical procedure for characterization of medieval wall-paintings by X-ray fluorescence spectrometry, laser ablation inductively coupled plasma mass spectrometry and Raman spectroscopy

NASA Astrophysics Data System (ADS)

Syta, Olga; Rozum, Karol; Choińska, Marta; Zielińska, Dobrochna; Żukowska, Grażyna Zofia; Kijowska, Agnieszka; Wagner, Barbara

2014-11-01

Analytical procedure for the comprehensive chemical characterization of samples from medieval Nubian wall-paintings by means of portable X-ray fluorescence (pXRF), laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS) and Raman spectroscopy (RS) was proposed in this work. The procedure was used for elemental and molecular investigations of samples from archeological excavations in Nubia (modern southern Egypt and northern Sudan). Numerous remains of churches with painted decorations dated back to the 7th-14th century were excavated in the region of medieval kingdoms of Nubia but many aspects of this art and its technology are still unknown. Samples from the selected archeological sites (Faras, Old Dongola and Banganarti) were analyzed in the form of transfers (n = 26), small fragments collected during the excavations (n = 35) and cross sections (n = 15). XRF was used to collect data about elemental composition, LA-ICPMS allowed mapping of selected elements, while RS was used to get the molecular information about the samples. The preliminary results indicated the usefulness of the proposed analytical procedure for distinguishing the substances, from both the surface and sub-surface domains of the wall-paintings. The possibility to identify raw materials from the wall-paintings will be used in the further systematic, archeometric studies devoted to the detailed comparison of various historic Nubian centers.

Validation of the determination of the B isotopic composition in Roman glasses with laser ablation multi-collector inductively coupled plasma-mass spectrometry

NASA Astrophysics Data System (ADS)

Devulder, Veerle; Gerdes, Axel; Vanhaecke, Frank; Degryse, Patrick

2015-03-01

The applicability of laser ablation multi-collector inductively coupled plasma-mass spectrometry (LA-MC-ICP-MS) for the determination of the B isotopic composition in Roman glasses was investigated. The δ11B values thus obtained provide information on the natron flux used during the glass-making process. The glass samples used for this purpose were previously characterized using pneumatic nebulization (PN) MC-ICP-MS. Unfortunately, this method is time-consuming and labor-intensive and consumes some 100 mg of sample, which is a rather high amount for ancient materials. Therefore, the use of the less invasive and faster LA-MC-ICP-MS approach was explored. In this work, the results for 29 Roman glasses and 4 home-made glasses obtained using both techniques were compared to assess the suitability of LA-MC-ICP-MS in this context. The results are in excellent agreement within experimental uncertainty. No difference in overall mass discrimination was observed between the Roman glasses, NIST SRM 610 reference glass and B6 obsidian. The expanded uncertainty of the LA-MC-ICP-MS approach was estimated to be < 2‰, which is similar to that obtained upon sample digestion and PN-MC-ICP-MS measurement.

Direct trace-elemental analysis of urine samples by laser ablation-inductively coupled plasma mass spectrometry after sample deposition on clinical filter papers.

PubMed

Aramendía, Maite; Rello, Luis; Vanhaecke, Frank; Resano, Martín

2012-10-16

Collection of biological fluids on clinical filter papers shows important advantages from a logistic point of view, although analysis of these specimens is far from straightforward. Concerning urine analysis, and particularly when direct trace elemental analysis by laser ablation-inductively coupled plasma mass spectrometry (LA-ICPMS) is aimed at, several problems arise, such as lack of sensitivity or different distribution of the analytes on the filter paper, rendering obtaining reliable quantitative results quite difficult. In this paper, a novel approach for urine collection is proposed, which circumvents many of these problems. This methodology consists on the use of precut filter paper discs where large amounts of sample can be retained upon a single deposition. This provides higher amounts of the target analytes and, thus, sufficient sensitivity, and allows addition of an adequate internal standard at the clinical lab prior to analysis, therefore making it suitable for a strategy based on unsupervised sample collection and ulterior analysis at referral centers. On the basis of this sampling methodology, an analytical method was developed for the direct determination of several elements in urine (Be, Bi, Cd, Co, Cu, Ni, Sb, Sn, Tl, Pb, and V) at the low μg L(-1) level by means of LA-ICPMS. The method developed provides good results in terms of accuracy and LODs (≤1 μg L(-1) for most of the analytes tested), with a precision in the range of 15%, fit-for-purpose for clinical control analysis.

Determination of changes in the concentration and distribution of elements within olive drupes (cv. Leccino) from Se biofortified plants, using laser ablation inductively coupled plasma mass spectrometry.

PubMed

D'Amato, Roberto; Petrelli, Maurizio; Proietti, Primo; Onofri, Andrea; Regni, Luca; Perugini, Diego; Businelli, Daniela

2018-03-25

Biofortification of food crops has been used to increase the intake of Se in the human diet, even though this may change the concentration of other elements and modify the nutritional properties of the enriched food. Selenium biofortification programs should include routine assessment of the overall mineral composition of enriched plants. Laser ablation inductively coupled plasma mass spectrometry (LA ICP-MS) was used for the assessment of mineral composition of table olives. Olive trees were fertilized with sodium selenate before flowering. At harvest, the edible parts of drupes proved to be significantly enriched in Se, delivering 6.1 μg g -1 (39% of the RDA for five olives). Such enrichment was followed by significant changes in the concentrations of B, Mg, K, Cr, Mn, Fe and Cu in edible parts, which are discussed for their impact on food quality. The biofortification of olive plants has allowed the enrichment of fruits with selenium. Enrichment with selenium has caused an increase in the concentration of other elements, which can change the nutritional quality of the drupes. The analytical technique used well as a valuable tool for routinely determining the chemical composition of all fruit parts. © 2018 Society of Chemical Industry. © 2018 Society of Chemical Industry.

Demonstration of femtosecond laser ablation inductively coupled plasma mass spectrometry for uranium isotopic measurements in U-10Mo nuclear fuel foils

SciTech Connect

Havrilla, George Joseph; Gonzalez, Jhanis

2015-06-10

The use of femtosecond laser ablation inductively coupled plasma mass spectrometry was used to demonstrate the feasibility of measuring the isotopic ratio of uranium directly in U-10Mo fuel foils. The measurements were done on both the flat surface and cross sections of bare and Zr clad U-10Mo fuel foil samples. The results for the depleted uranium content measurements were less than 10% of the accepted U235/238 ratio of 0.0020. Sampling was demonstrated for line scans and elemental mapping over large areas. In addition to the U isotopic ratio measurement, the Zr thickness could be measured as well as trace elementalmore » composition if required. A number of interesting features were observed during the feasibility measurements which could provide the basis for further investigation using this methodology. The results demonstrate the feasibility of using fs-LA-ICP-MS for measuring the U isotopic ratio in U-10Mo fuel foils.« less

Study on quantitative analysis of Ti, Al and V in clinical soft tissues after placing the dental implants by laser ablation inductively coupled plasma mass spectrometry

NASA Astrophysics Data System (ADS)

Sajnóg, Adam; Hanć, Anetta; Makuch, Krzysztof; Koczorowski, Ryszard; Barałkiewicz, Danuta

2016-11-01

Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) was used for in-situ quantitative analysis of oral mucosa of patients before and after implantation with titanium implants and a closing screw based on Ti6Al4V alloy. Two calibration strategies were applied, both were based on matrix matched solid standards with analytes addition. A novel approach was the application of powdered egg white proteins as a matrix material which have a similar composition to the examined tissue. In the another approach, certified reference material Bovine Muscle ERM-BB184 was used. The isotope 34S was found to be the most appropriate as an internal standard since it is homogenously distributed in the examined tissues and resulted in lower relative standard deviation values of signal of analytes of interest. Other isotopes (13C, 26Mg, 43Ca) were also evaluated as potential internal standards. The analytical performance parameters and microwave digestion of solid standards followed by solution nebulization ICP-MS analysis proved that both calibration methods are fit for their intended purpose. The LA-ICP-MS analysis on the surface of tissues after the implantation process revealed an elevated content of elements in comparison to the control group. Analytes are distributed inhomogeneously and display local maximal content of Ti up to ca. 900 μg g- 1, Al up to ca. 760 μg g- 1 and for V up to 160 μg g- 1.

Rare earth elements profile in a cultivated and non-cultivated soil determined by laser ablation-inductively coupled plasma mass spectrometry.

PubMed

Neves, Vinicius M; Heidrich, Graciela M; Hanzel, Flavia B; Muller, Edson I; Dressler, Valderi L

2018-05-01

Rare earth elements (REEs) have several applications but the effects on environment are not well known. Therefore, the aim of this work is to establish a method for direct solid sample analysis by laser ablation-inductively coupled plasma mass spectrometry (LA-ICP-MS) to evaluate the concentration and distribution of REEs in cultivated and non-cultivated soil. Samples were collected in two areas to 40 cm of depth. The LA-ICP-MS method is easy to be implemented and the sample treatment is very fast comprising only its drying, grounding and pressing as a pellet. The accuracy of the method was evaluated by using a certified reference material (BCR 667 - Estuarine Sediment, Institute for Reference Materials and Measurements (IRMM)) where good agreement with the certified values was obtained. Analyte recovery at two levels of concentration (2.5 and 15.0 μg g -1 ) was also performed and recoveries in the range of 85%-120% were achieved, values that are acceptable for LA-ICP-MS analysis. In general, the concentration of the REEs is higher in the cultivated soil and increased from the surface to deeper layers, which can be a consequence of fertilizer application. Copyright © 2018 Elsevier Ltd. All rights reserved.

A preliminary characterization of applied-field MPD thruster plumes

NASA Technical Reports Server (NTRS)

Myers, Roger M.; Wehrle, David; Vernyi, Mark; Biaglow, James; Reese, Shawn

1991-01-01

Electric probes, quantitative imaging, and emission spectroscopy were used to study the plume characteristics of applied field magnetohydrodynamic thrusters. The measurements showed that the applied magnetic field plays the dominant role in establishing the plume structure, followed in importance by the cathode geometry and propellant. The anode radius had no measurable impact on the plume characteristics. For all cases studied the plume was highly ionized, though spectral lines of neutral species were always present. Centerline electron densities and temperatures ranged from 2 times 10 (exp 18) to 8 times 10 (exp 18) m(exp -3) and from 7500 to 20,000 K, respectively. The plume was strongly confined by the magnetic field, with radial density gradients increasing monotonically with applied field strength. Plasma potential measurements show a strong effect of the magnetic field on the electrical conductivity and indicate the presence of radial current conduction in the plume.

MISR Aoba Volcano Plume

Atmospheric Science Data Center

2018-06-07

... in ongoing eruptions using parallax. View the MISR Active Aerosol Plume-Height (AAP) Project paper to see peak altitude and settling ... R. Kahn/NASA GSFC Access Project Paper: MISR Active Aerosol Plume-Height (AAP) Project Access and Order MISR Data and ...

Pulsed laser ablation of complex oxides: The role of congruent ablation and preferential scattering for the film stoichiometry

SciTech Connect

Wicklein, S.; Koehl, A.; Dittmann, R.

2012-09-24

By combining structural and chemical thin film analysis with detailed plume diagnostics and modeling of the laser plume dynamics, we are able to elucidate the different physical mechanisms determining the stoichiometry of the complex oxides model material SrTiO{sub 3} during pulsed laser deposition. Deviations between thin film and target stoichiometry are basically a result of two effects, namely, incongruent ablation and preferential scattering of lighter ablated species during their motion towards the substrate in the O{sub 2} background gas. On the one hand, a progressive preferential ablation of the Ti species with increasing laser fluence leads to a regime ofmore » Ti-rich thin film growth at larger fluences. On the other hand, in the low laser fluence regime, a more effective scattering of the lighter Ti plume species results in Sr rich films.« less

Using laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) to characterize copper, zinc and mercury along grizzly bear hair providing estimate of diet.

PubMed

Noël, Marie; Christensen, Jennie R; Spence, Jody; Robbins, Charles T

2015-10-01

We enhanced an existing technique, laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS), to function as a non-lethal tool in the temporal characterization of trace element exposure in wild mammals. Mercury (Hg), copper (Cu), cadmium (Cd), lead (Pb), iron (Fe) and zinc (Zn) were analyzed along the hair of captive and wild grizzly bears (Ursus arctos horribilis). Laser parameters were optimized (consecutive 2000 μm line scans along the middle line of the hair at a speed of 50 μm/s; spot size=30 μm) for consistent ablation of the hair. A pressed pellet of reference material DOLT-2 and sulfur were used as external and internal standards, respectively. Our newly adapted method passed the quality control tests with strong correlations between trace element concentrations obtained using LA-ICP-MS and those obtained with regular solution-ICP-MS (r(2)=0.92, 0.98, 0.63, 0.57, 0.99 and 0.90 for Hg, Fe, Cu, Zn, Cd and Pb, respectively). Cross-correlation analyses revealed good reproducibility between trace element patterns obtained from hair collected from the same bear. One exception was Cd for which external contamination was observed resulting in poor reproducibility. In order to validate the method, we used LA-ICP-MS on the hair of five captive grizzly bears fed known and varying amounts of cutthroat trout over a period of 33 days. Trace element patterns along the hair revealed strong Hg, Cu and Zn signals coinciding with fish consumption. Accordingly, significant correlations between Hg, Cu, and Zn in the hair and Hg, Cu, and Zn intake were evident and we were able to develop accumulation models for each of these elements. While the use of LA-ICP-MS for the monitoring of trace elements in wildlife is in its infancy, this study highlights the robustness and applicability of this newly adapted method. Copyright © 2015 Elsevier B.V. All rights reserved.

Quantitative analysis of major and trace elements in NH4HF2-modified silicate rock powders by laser ablation - inductively coupled plasma mass spectrometry.

PubMed

Zhang, Wen; Hu, Zhaochu; Liu, Yongsheng; Yang, Wenwu; Chen, Haihong; Hu, Shenghong; Xiao, Hongyan

2017-08-29

In this paper, we described a NH 4 HF 2 digestion method as sample preparation for the rapid determination of major and trace elements in silicate rocks using laser ablation-inductively coupled plasma mass spectrometry (LA-ICP-MS). Sample powders digested by NH 4 HF 2 at 230 °C for 3 h form ultrafine powders with a typical grain size d 80  < 8.5 μm, and various silicate rocks have a consistent grain morphology and size, allowing us to produce pressed powder pellets that have excellent cohesion and homogeneity suitable for laser ablation micro-analysis without the addition of binder. The influences of the digestion parameters were investigated and optimized, including the evaporation stage of removing residual NH 4 HF 2 , sample homogenization, selection of the digestion vessel and calibration strategy of quantitative analysis. The optimized NH 4 HF 2 digestion method was applied to dissolve six silicate rock reference materials (BCR-2, BHVO-2, AGV-2, RGM-2, GSP-2, GSR-1) covering a wide range of rock types. Ten major elements and thirty-five trace elements were simultaneously analyzed by LA-ICP-MS. The analytical results of the six reference materials generally agreed with the recommended values, with discrepancies of less than 10% for most elements. The analytical precision is within 5% for most major elements and within 10% for most trace elements. Compared with previous methods of LA-ICP-MS bulk analysis, our method enables the complete dissolution of refractory minerals, such as zircon, in intermediate-acidic intrusive rocks and limits contamination as well as the loss of volatile elements. Moreover, there are many advantages for the new technique, including reducing matrix effects between reference materials and samples, spiking the internal standard simply and feasibly and sample batch processing. The applicability filed of the new technique in this study was focused on the whole-rock analysis of igneous rock samples, which are from basic rocks to acid

Segmented electrode hall thruster with reduced plume

DOEpatents

Fisch, Nathaniel J.; Raitses, Yevgeny

2004-08-17

An apparatus and method for thrusting plasma, utilizing a Hall thruster with segmented electrodes along the channel, which make the acceleration region as localized as possible. Also disclosed are methods of arranging the electrodes so as to minimize erosion and arcing. Also disclosed are methods of arranging the electrodes so as to produce a substantial reduction in plume divergence. The use of electrodes made of emissive material will reduce the radial potential drop within the channel, further decreasing the plume divergence. Also disclosed is a method of arranging and powering these electrodes so as to provide variable mode operation.

Prometheus: Io's wandering plume.

PubMed

Kieffer, S W; Lopes-Gautier, R; McEwen, A; Smythe, W; Keszthelyi, L; Carlson, R

2000-05-19

Unlike any volcanic behavior ever observed on Earth, the plume from Prometheus on Io has wandered 75 to 95 kilometers west over the last 20 years since it was first discovered by Voyager and more recently observed by Galileo. Despite the source motion, the geometric and optical properties of the plume have remained constant. We propose that this can be explained by vaporization of a sulfur dioxide and/or sulfur "snowfield" over which a lava flow is moving. Eruption of a boundary-layer slurry through a rootless conduit with sonic conditions at the intake of the melted snow can account for the constancy of plume properties.

Generation of nanoclusters by ultrafast laser ablation of Al: Molecular dynamics study

SciTech Connect

Miloshevsky, Alexander; Phillips, Mark C.; Harilal, Sivanandan S.

The laser ablation of materials induced by an ultrashort femtosecond pulse is a complex phenomenon, which depends on both the material properties and the properties of the laser pulse. The unique capability of a combination of molecular dynamics (MD) and Momentum Scaling Model (MSM) methods is developed and applied to a large atomic system for studying the process of ultrafast laser-material interactions, behavior of matter in a highly non-equilibrium state, material disintegration, and formation of nanoparticles (NPs). Laser pulses with several fluences in the range from 500 J/m2 to 5000 J/m2 interacting with a large system of aluminum atoms aremore » simulated. The response of Al material to the laser energy deposition is investigated within the finite-size laser spot. It is found that the shape of the plasma plume is dynamically changing during an expansion process. At several tens of picoseconds it can be characterized as a long hollow ellipsoid surrounded by atomized and nano-clustered particles. The time evolution of NP clusters in the plume is investigated. The collisions between the single Al atoms and generated NPs and fragmentation of large NPs determine the fractions of different-size NP clusters in the plume. The MD-MSM simulations show that laser fluence greatly affects the size distribution of NPs, their polar angles, magnitude and direction vectors of NP velocities. These results and predictions are supported by the experimental data and previous MD simulations.« less

CHLORINATED SOLVENT PLUME CONTROL

EPA Science Inventory

This lecture will cover recent success in controlling and assessing the treatment of shallow ground water plumes of chlorinated solvents, other halogenated organic compounds, and methyl tert-butyl ether (MTBE).

Thermodynamic properties and transport coefficients of air thermal plasmas mixed with ablated vapors of Cu and polytetrafluoroethylene

SciTech Connect

Zhang, JunMin, E-mail: jmzhang@buaa.edu.cn, E-mail: guanyg@tsinghua.edu.cn; Lu, ChunRong; Guan, YongGang, E-mail: jmzhang@buaa.edu.cn, E-mail: guanyg@tsinghua.edu.cn

2015-10-15

Because the fault arc in aircraft electrical system often causes a fire, it is particularly important to analyze its energy and transfer for aircraft safety. The calculation of arc energy requires the basic parameters of the arc. This paper is mainly devoted to the calculations of equilibrium composition, thermodynamic properties (density, molar weight, enthalpy, and specific heat at constant pressure) and transport coefficients (thermal conductivity, electrical conductivity, and viscosity) of plasmas produced by a mixture of air, Cu, and polytetrafluoroethylene under the condition of local thermodynamic equilibrium. The equilibrium composition is determined by solving a system of equations around themore » number densities of each species. The thermodynamic properties are obtained according to the standard thermodynamic relationships. The transport coefficients are calculated using the Chapman-Enskog approximations. Results are presented in the temperature range from 3000 to 30 000 K for pressures of 0.08 and 0.1 MPa, respectively. The results are more accurate and are reliable reference data for theoretical analysis and computational simulation of the behavior of fault arc.« less

The potential of using laser ablation inductively coupled plasma time of flight mass spectrometry (LA-ICP-TOF-MS) in the forensic analysis of micro debris.

PubMed

Scadding, Cameron J; Watling, R John; Thomas, Allen G

2005-08-15

The majority of crimes result in the generation of some form of physical evidence, which is available for collection by crime scene investigators or police. However, this debris is often limited in amount as modern criminals become more aware of its potential value to forensic scientists. The requirement to obtain robust evidence from increasingly smaller sized samples has required refinement and modification of old analytical techniques and the development of new ones. This paper describes a new method for the analysis of oxy-acetylene debris, left behind at a crime scene, and the establishment of its co-provenance with single particles of equivalent debris found on the clothing of persons of interest (POI). The ability to rapidly determine and match the elemental distribution patterns of debris collected from crime scenes to those recovered from persons of interest is essential in ensuring successful prosecution. Traditionally, relatively large amounts of sample (up to several milligrams) have been required to obtain a reliable elemental fingerprint of this type of material [R.J. Walting , B.F. Lynch, D. Herring, J. Anal. At. Spectrom. 12 (1997) 195]. However, this quantity of material is unlikely to be recovered from a POI. This paper describes the development and application of laser ablation inductively coupled plasma time of flight mass spectrometry (LA-ICP-TOF-MS), as an analytical protocol, which can be applied more appropriately to the analysis of micro-debris than conventional quadrupole based mass spectrometry. The resulting data, for debris as small as 70mum in diameter, was unambiguously matched between a single spherule recovered from a POI and a spherule recovered from the scene of crime, in an analytical procedure taking less than 5min.

TERMITE: An R script for fast reduction of laser ablation inductively coupled plasma mass spectrometry data and its application to trace element measurements.

PubMed

Mischel, Simon A; Mertz-Kraus, Regina; Jochum, Klaus Peter; Scholz, Denis

2017-07-15

High spatial resolution Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICPMS) determination of trace element concentrations is of great interest for geological and environmental studies. Data reduction is a very important aspect of LA-ICP-MS, and several commercial programs for handling LA-ICPMS trace element data are available. Each of these software packages has its specific advantages and disadvantages. Here we present TERMITE, an R script for the reduction of LA-ICPMS data, which can reduce both spot and line scan measurements. Several parameters can be adjusted by the user, who does not necessarily need prior knowledge in R. Currently, ten reference materials with different matrices for calibration of LA-ICPMS data are implemented, and additional reference materials can be added by the user. TERMITE also provides an optional outlier test, and the results are provided graphically (as a pdf file) as well as numerically (as a csv file). As an example, we apply TERMITE to a speleothem sample and compare the results with those obtained using the commercial software GLITTER. The two programs give similar results. TERMITE is particularly useful for samples that are homogeneous with respect to their major element composition (in particular for the element used as an internal standard) and when many measurements are performed using the same analytical parameters. In this case, data evaluation using TERMITE is much faster than with all other available software, and the concentrations of more than 100 single spot measurements can be calculated in less than a minute. TERMITE is an open-source software for the reduction of LA-ICPMS data, which is particularly useful for the fast, reproducible evaluation of large datasets of samples that are homogeneous with respect to their major element composition. Copyright © 2017 John Wiley & Sons, Ltd. Copyright © 2017 John Wiley & Sons, Ltd.

Novel Bioimaging Techniques of Metals by Laser Ablation Inductively Coupled Plasma Mass Spectrometry for Diagnosis Of Fibrotic and Cirrhotic Liver Disorders

PubMed Central

Gassler, Nikolaus; Bosserhoff, Anja K.; Becker, J. Sabine

2013-01-01

Background and Aims Hereditary disorders associated with metal overload or unwanted toxic accumulation of heavy metals can lead to morbidity and mortality. Patients with hereditary hemochromatosis or Wilson disease for example may develop severe hepatic pathology including fibrosis, cirrhosis or hepatocellular carcinoma. While relevant disease genes are identified and genetic testing is applicable, liver biopsy in combination with metal detecting techniques such as energy-dispersive X-ray spectroscopy (EDX) is still applied for accurate diagnosis of metals. Vice versa, several metals are needed in trace amounts for carrying out vital functions and their deficiency due to rapid growth, pregnancy, excessive blood loss, and insufficient nutritional or digestive uptake results in organic and systemic shortcomings. Established in situ techniques, such as EDX-ray spectroscopy, are not sensitive enough to analyze trace metal distribution and the quantification of metal images is difficult. Methods In this study, we developed a quantitative biometal imaging technique of human liver tissue by laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) in order to compare the distribution of selected metals in cryo-sections of healthy and fibrotic/cirrhotic livers. Results Most of the metals are homogeneous distributed within the normal tissue, while they are redirected within fibrotic livers resulting in significant metal deposits. Moreover, total iron and copper concentrations in diseased liver were found about 3-5 times higher than in normal liver samples. Conclusions Biometal imaging via LA-ICP-MS is a sensitive innovative diagnostic tool that will impact clinical practice in identification and evaluation of hepatic metal disorders and to detect subtle metal variations during ongoing hepatic fibrogenesis. PMID:23505552

Application of laser ablation multicollector inductively coupled plasma mass spectrometry for the measurement of calcium and lead isotope ratios in packaging for discriminatory purposes.

PubMed

Santamaria-Fernandez, Rebeca; Wolff, Jean-Claude

2010-07-30

The potential of high-precision calcium and lead isotope ratio measurements using laser ablation coupled to multicollector inductively coupled plasma mass spectrometry (LA-MC-ICP-MS) to aid distinction between four genuine and five counterfeit pharmaceutical packaging samples and further classification of counterfeit packaging samples has been evaluated. We highlight the lack of reference materials for LA-MC-ICP-MS isotope ratio measurements in solids. In this case the problem is minimised by using National Institute of Standards and Technology Standard Reference Material (NIST SRM) 915a calcium carbonate (as solid pellets) and NIST SRM610 glass disc for sample bracketing external standardisation. In addition, a new reference material, NIST SRM915b calcium carbonate, has been characterised in-house for Ca isotope ratios and is used as a reference sample. Significant differences have been found between genuine and counterfeit samples; the method allows detection of counterfeits and aids further classification of packaging samples. Typical expanded uncertainties for measured-corrected Ca isotope ratio values ((43)Ca/(44)Ca and (42)Ca/(44)Ca) were found to be below 0.06% (k = 2, 95% confidence) and below 0.2% for measured-corrected Pb isotope ratios ((207)Pb/(206)Pb and (208)Pb/(206)Pb). This is the first time that Ca isotope ratios have been measured in packaging materials using LA coupled to a multicollector (MC)-ICP-MS instrument. The use of LA-MC-ICP-MS for direct measurement of Ca and Pb isotopic variations in cardboard/ink in packaging has definitive potential to aid counterfeit detection and classification. Copyright 2010 John Wiley & Sons, Ltd.

Investigating the influence of standard staining procedures on the copper distribution and concentration in Wilson's disease liver samples by laser ablation-inductively coupled plasma-mass spectrometry.

PubMed

Hachmöller, Oliver; Aichler, Michaela; Schwamborn, Kristina; Lutz, Lisa; Werner, Martin; Sperling, Michael; Walch, Axel; Karst, Uwe

2017-12-01

The influence of rhodanine and haematoxylin and eosin (HE) staining on the copper distribution and concentration in liver needle biopsy samples originating from patients with Wilson's disease (WD), a rare autosomal recessive inherited disorder of the copper metabolism, is investigated. In contemporary diagnostic of WD, rhodanine staining is used for histopathology, since rhodanine and copper are forming a red to orange-red complex, which can be recognized in the liver tissue using a microscope. In this paper, a laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) method is applied for the analysis of eight different WD liver samples. Apart from a spatially resolved elemental detection as qualitative information, this LA-ICP-MS method offers also quantitative information by external calibration with matrix-matched gelatine standards. The sample set of this work included an unstained and a rhodanine stained section of each WD liver sample. While unstained sections of WD liver samples showed very distinct structures of the copper distribution with high copper concentrations, rhodanine stained sections revealed a blurred copper distribution with significant decreased concentrations in a range from 20 to more than 90%. This implies a copper removal from the liver tissue by complexation during the rhodanine staining. In contrast to this, a further HE stained sample of one WD liver sample did not show a significant decrease in the copper concentration and influence on the copper distribution in comparison to the unstained section. Therefore, HE staining can be combined with the analysis by means of LA-ICP-MS in two successive steps from one thin section of a biopsy specimen. This allows further information to be gained on the elemental distribution by LA-ICP-MS additional to results obtained by histological staining. Copyright © 2017 Elsevier GmbH. All rights reserved.

Fusion Bead Procedure for Nuclear Forensics Employing Synthetic Enstatite to Dissolve Uraniferous and Other Challenging Materials Prior to Laser Ablation Inductively Coupled Plasma Mass Spectrometry.

PubMed

Reading, David G; Croudace, Ian W; Warwick, Phillip E

2017-06-06

There is an increasing demand for rapid and effective analytical tools to support nuclear forensic investigations of seized or suspect materials. Some methods are simply adapted from other scientific disciplines and can effectively be used to rapidly prepare complex materials for subsequent analysis. A novel sample fusion method is developed, tested, and validated to produce homogeneous, flux-free glass beads of geochemical reference materials (GRMs), uranium ores, and uranium ore concentrates (UOC) prior to the analysis of 14 rare earth elements (REE) via laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS). The novelty of the procedure is the production of glass beads using 9 parts high purity synthetic enstatite (MgSiO 3 ) as the glass former with 1 part of sample (sample mass ∼1.5 mg). The beads are rapidly prepared (∼10 min overall time) by fusing the blended mixture on an iridium strip resistance heater in an argon-purged chamber. Many elements can be measured in the glass bead, but the rare earth group in particular is a valuable series in nuclear forensic studies and is well-determined using LA-ICP-MS. The REE data obtained from the GRMs, presented as chondrite normalized patterns, are in very good agreement with consensus patterns. The UOCs have comparable patterns to solution ICP-MS methods and published data. The attractions of the current development are its conservation of sample, speed of preparation, and suitability for microbeam analysis, all of which are favorable for nuclear forensics practitioners and geochemists requiring REE patterns from scarce or valuable samples.

Solid matrix transformation and tracer addition using molten ammonium bifluoride salt as a sample preparation method for laser ablation inductively coupled plasma mass spectrometry.

PubMed

Grate, Jay W; Gonzalez, Jhanis J; O'Hara, Matthew J; Kellogg, Cynthia M; Morrison, Samuel S; Koppenaal, David W; Chan, George C-Y; Mao, Xianglei; Zorba, Vassilia; Russo, Richard E

2017-09-08

Solid sampling and analysis methods, such as laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS), are challenged by matrix effects and calibration difficulties. Matrix-matched standards for external calibration are seldom available and it is difficult to distribute spikes evenly into a solid matrix as internal standards. While isotopic ratios of the same element can be measured to high precision, matrix-dependent effects in the sampling and analysis process frustrate accurate quantification and elemental ratio determinations. Here we introduce a potentially general solid matrix transformation approach entailing chemical reactions in molten ammonium bifluoride (ABF) salt that enables the introduction of spikes as tracers or internal standards. Proof of principle experiments show that the decomposition of uranium ore in sealed PFA fluoropolymer vials at 230 °C yields, after cooling, new solids suitable for direct solid sampling by LA. When spikes are included in the molten salt reaction, subsequent LA-ICP-MS sampling at several spots indicate that the spikes are evenly distributed, and that U-235 tracer dramatically improves reproducibility in U-238 analysis. Precisions improved from 17% relative standard deviation for U-238 signals to 0.1% for the ratio of sample U-238 to spiked U-235, a factor of over two orders of magnitude. These results introduce the concept of solid matrix transformation (SMT) using ABF, and provide proof of principle for a new method of incorporating internal standards into a solid for LA-ICP-MS. This new approach, SMT-LA-ICP-MS, provides opportunities to improve calibration and quantification in solids based analysis. Looking forward, tracer addition to transformed solids opens up LA-based methods to analytical methodologies such as standard addition, isotope dilution, preparation of matrix-matched solid standards, external calibration, and monitoring instrument drift against external calibration standards.

Sulfur plumes off Namibia

NASA Technical Reports Server (NTRS)

2002-01-01

Sulfur plumes rising up from the bottom of the ocean floor produce colorful swirls in the waters off the coast of Namibia in southern Africa. The plumes come from the breakdown of marine plant matter by anaerobic bacteria that do not need oxygen to live. This image was acquired by the Moderate Resolution Imaging Spectroradiometer (MODIS) on the Terra satellite on April 24, 2002 Credit: Jacques Descloitres, MODIS Land Rapid Response Team, NASA/GSFC

On the elemental analysis of different cigarette brands using laser induced breakdown spectroscopy and laser-ablation time of flight mass spectrometry

NASA Astrophysics Data System (ADS)

Ahmed, Nasar; Umar, Zeshan A.; Ahmed, Rizwan; Aslam Baig, M.

2017-10-01

We present qualitative and quantitative analysis of the trace elements present in different brands of tobacco available in Pakistan using laser induced breakdown spectroscopy (LIBS) and Laser ablation Time of Flight Mass Spectrometer (LA-TOFMS). The compositional analysis using the calibration free LIBS technique is based on the observed emission spectra of the laser produced plasma plume whereas the elemental composition analysis using LA-TOFMS is based on the mass spectra of the ions produced by laser ablation. The optical emission spectra of these samples contain spectral lines of calcium, magnesium, sodium, potassium, silicon, strontium, barium, lithium and aluminum with varying intensities. The corresponding mass spectra of the elements were detected in LA-TOF-MS with their composition concentration. The analysis of different brands of cigarettes demonstrates that LIBS coupled with a LA-TOF-MS is a powerful technique for the elemental analysis of the trace elements in any solid sample.

Dynamic absorption and scattering of water and hydrogel during high-repetition-rate (>100 MHz) burst-mode ultrafast-pulse laser ablation.

PubMed

Qian, Zuoming; Covarrubias, Andrés; Grindal, Alexander W; Akens, Margarete K; Lilge, Lothar; Marjoribanks, Robin S

2016-06-01

High-repetition-rate burst-mode ultrafast-laser ablation and disruption of biological tissues depends on interaction of each pulse with the sample, but under those particular conditions which persist from previous pulses. This work characterizes and compares the dynamics of absorption and scattering of a 133-MHz repetition-rate, burst-mode ultrafast-pulse laser, in agar hydrogel targets and distilled water. The differences in energy partition are quantified, pulse-by-pulse, using a time-resolving integrating-sphere-based device. These measurements reveal that high-repetition-rate burst-mode ultrafast-laser ablation is a highly dynamical process affected by the persistence of ionization, dissipation of plasma plume, neutral material flow, tissue tensile strength, and the hydrodynamic oscillation of cavitation bubbles.

Improved model for the angular dependence of excimer laser ablation rates in polymer materials

NASA Astrophysics Data System (ADS)

Pedder, J. E. A.; Holmes, A. S.; Dyer, P. E.

2009-10-01

Measurements of the angle-dependent ablation rates of polymers that have applications in microdevice fabrication are reported. A simple model based on Beer's law, including plume absorption, is shown to give good agreement with the experimental findings for polycarbonate and SU8, ablated using the 193 and 248 nm excimer lasers, respectively. The modeling forms a useful tool for designing masks needed to fabricate complex surface relief by ablation.

Efficacy of autologous platelet-rich plasma combined with fractional ablative carbon dioxide resurfacing laser in treatment of facial atrophic acne scars: A split-face randomized clinical trial.

PubMed

Faghihi, Gita; Keyvan, Shima; Asilian, Ali; Nouraei, Saeid; Behfar, Shadi; Nilforoushzadeh, Mohamad Ali

2016-01-01

Autologous platelet-rich plasma has recently attracted significant attention throughout the medical field for its wound-healing ability. This study was conducted to investigate the potential of platelet-rich plasma combined with fractional laser therapy in the treatment of acne scarring. Sixteen patients (12 women and 4 men) who underwent split-face therapy were analyzed in this study. They received ablative fractional carbon dioxide laser combined with intradermal platelet-rich plasma treatment on one half of their face and ablative fractional carbon dioxide laser with intradermal normal saline on the other half. The injections were administered immediately after laser therapy. The treatment sessions were repeated after an interval of one month. The clinical response was assessed based on patient satisfaction and the objective evaluation of serial photographs by two blinded dermatologists at baseline, 1 month after the first treatment session and 4 months after the second. The adverse effects including erythema and edema were scored by participants on days 0, 2, 4, 6, 8, 15 and 30 after each session. Overall clinical improvement of acne scars was higher on the platelet-rich plasma-fractional carbon dioxide laser treated side but the difference was not statistically significant either 1 month after the first treatment session (P = 0.15) or 4 months after the second (P = 0.23). In addition, adverse effects (erythema and edema) on the platelet-rich plasma-fractional carbon dioxide laser-treated side were more severe and of longer duration. Small sample size, absence of all skin phototypes within the study group and lack of objective methods for the evaluation of response to treatment and adverse effects were the limitations. This study demonstrated that adding platelet-rich plasma to fractional carbon dioxide laser treatment did not produce any statistically significant synergistic effects and also resulted in more severe side effects and longer downtime.

Self-mixing interferometry as a diagnostics tool for plasma characteristics in laser microdrilling

NASA Astrophysics Data System (ADS)

Colombo, Paolo; Demir, Ali Gökhan; Norgia, Michele; Previtali, Barbara

2017-05-01

In this work, self-mixing interferometry (SMI) was used to monitor the optical path difference induced by the ablation plasma and plume. The paper develops the analytical relationships to explain the fringe appearance in the SMI during laser microdrilling. The monitoring principle was tested under a large experimental campaign of laser microdrilling on TiAlN ceramic coating with a low-ns green fibre laser. Key process parameters namely pulse energy, number and repetition rate were varied. The effect of side gas on the SMI signal characteristic was analysed. Laser induced breakdown spectroscopy (LIBS) was used to identify the plasma temperature and electron number density. The SMI signals were correlated to the plume size and its evolution as a function of process parameters, as well as electron number density estimated by spectroscopy. In addition to proving the validity of the proposed new method, the results show insights to the micromachining of the ceramic material with low ns pulses.

A Brilliant Plume

NASA Technical Reports Server (NTRS)

2007-01-01

The Long Range Reconnaissance Imager (LORRI) on New Horizons captured another dramatic picture of Jupiter's moon Io and its volcanic plumes, 19 hours after the spacecraft's closest approach to Jupiter on Feb. 28, 2007. LORRI took this 75 millisecond exposure at 0035 Universal Time on March 1, 2007, when Io was 2.3 million kilometers (1.4 million miles) from the spacecraft.

Io's dayside is deliberately overexposed to bring out faint details in the plumes and on the moon's night side. The continuing eruption of the volcano Tvashtar, at the 1 o'clock position, produces an enormous plume roughly 330 kilometers (200 miles) high, which is illuminated both by sunlight and 'Jupiter light.'

The shadow of Io, cast by the Sun, slices across the plume. The plume is quite asymmetrical and has a complicated wispy texture, for reasons that are still mysterious. At the heart of the eruption incandescent lava, seen here as a brilliant point of light, is reminding scientists of the fire fountains spotted by the Galileo Jupiter orbiter at Tvashtar in 1999.

The sunlit plume faintly illuminates the surface underneath. 'New Horizons and Io continue to astonish us with these unprecedented views of the solar system's most geologically active body' says John Spencer, deputy leader of the New Horizons Jupiter Encounter Science Team and an Io expert from Southwest Research Institute.

Because this image shows the side of Io that faces away from Jupiter, the large planet does not illuminate the moon's night side except for an extremely thin crescent outlining the edge of the disk at lower right. Another plume, likely from the volcano Masubi, is illuminated by Jupiter just above this lower right edge. A third and much fainter plume, barely visible at the 2 o'clock position, could be the first plume seen from the volcano Zal Patera.

As in other New Horizons images of Io, mountains catch the setting Sun just beyond the terminator (the line dividing day and night

Ultra-micro analysis of liquids and suspensions based on laser-induced plasma emissions

NASA Astrophysics Data System (ADS)

Cheung, N. H.; Ng, C. W.; Ho, W. F.; Yeung, E. S.

1998-05-01

Spectrochemical analysis of liquids and suspensions using laser-induced plasma emissions was investigated. Nd:YAG pulsed-laser (532-nm) ablation of aqueous samples produced plasmas that were hot (few eV) and extensively ionized, with electron density in the 10 18 cm -3 range. Analyte line signals were initially masked by intense plasma continuum emissions, and would only emerge briefly above the background when the plume temperature dropped below 1 eV during the course of its very rapid cooling. In contrast, 193-nm laser ablation at similar fluence generated plasmas of much lower (<1 eV) temperature but comparable electron density. The plasma continuum emissions were relatively weak and the signal-to-background ratio was a thousand times better. This `cold' plasma was ideal for sampling trace amounts of biologically important elements such as sodium and potassium. By ablating hydrodynamically focused jets in a sheath-flow, and with acoustic normalization for improved precision, the single-shot detection limits of sodium and potassium were 8 and 50 fg, respectively. Using the sheath-flow arrangement, the amounts of sodium and potassium inside single human red blood cells were simultaneously determined for the first time. The intracellular contents for a given blood donor were found to vary significantly, with only very weak correlation between the amounts of sodium and potassium in individual cells.

Pulsed laser ablation of IC packages for device failure analyses

NASA Astrophysics Data System (ADS)

Hong, Ming Hui; Mai, ZhiHong; Chen, G. X.; Thiam, Thomas; Song, Wen D.; Lu, Yongfeng; Soh, Chye E.; Chong, Tow Chong

2002-06-01

Pulsed laser ablation of mold compounds for IC packaging in air and with steam assistance is investigated. It is applied to decap IC packages and expose computer CPU dies for the device failure analyses. Compared with chemical decapping, the laser ablation has advantages of being fast speed, non- contact and dry processing. Laser ablation with the steam assistance results in higher ablation rate and wider ablated crater with much smoother surface morphology. It implies that the steam assisted laser ablation can achieve a faster and better quality laser processing. Audible acoustic wave and plasma optical signal diagnostics are also carried out to have a better understanding of the mechanisms behind. Light wavelength and laser fluence applied in the decapping are two important parameters. The 532 nm Nd:YAG laser decapping at a low laser fluence can achieve a large decapping area with a fine ablation profile. IC packages decapped by the laser ablation show good quality for the device failure analyses.

Laser ablation of single-crystalline silicon by radiation of pulsed frequency-selective fiber laser

NASA Astrophysics Data System (ADS)

Veiko, V. P.; Skvortsov, A. M.; Huynh, C. T.; Petrov, A. A.

2015-07-01

We have studied the process of destruction of the surface of a single-crystalline silicon wafer scanned by the beam of a pulsed ytterbium-doped fiber laser radiation with a wavelength of λ = 1062 nm. It is established that the laser ablation can proceed without melting of silicon and the formation of a plasma plume. Under certain parameters of the process (radiation power, beam scan velocity, and beam overlap density), pronounced oxidation of silicon microparticles with the formation of a characteristic loose layer of fine powdered silicon dioxide has been observed for the first time. The range of lasing and beam scanning regimes in which the growth of SiO2 layer takes place is determined.

Modeling a Hall Thruster from Anode to Plume Far Field

DTIC Science & Technology

2008-12-31

Two dimensional ax symmetric simulations of xenon plasma plume flow fields from a D55 Anode layer Hall thruster is performed. A hybrid particle-fluid...method is used for the Simulations. The magnetic field surrounding the Hall thruster exit is included in the Calculation. The plasma properties

Advanced Hybrid Modeling of Hall Thruster Plumes

DTIC Science & Technology

2010-06-16

Hall thruster operated in the Large Vacuum Test Facility at the University of Michigan. The approach utilizes the direct simulation Monte Carlo method and the Particle-in-Cell method to simulate the collision and plasma dynamics of xenon neutrals and ions. The electrons are modeled as a fluid using conservation equations. A second code is employed to model discharge chamber behavior to provide improved input conditions at the thruster exit for the plume simulation. Simulation accuracy is assessed using experimental data previously

Cassini Radio Occultation by Enceladus Plume

NASA Astrophysics Data System (ADS)

Kliore, A.; Armstrong, J.; Flasar, F.; French, R.; Marouf, E.; Nagy, A.; Rappaport, N.; McGhee, C.; Schinder, P.; Anabtawi, A.; Asmar, S.; Barbinis, E.; Fleischman, D.; Goltz, G.; Aguilar, R.; Rochblatt, D.

2006-12-01

A fortuitous Cassini radio occultation by Enceladus plume occurs on September 15, 2006. The occultation track (the spacecraft trajectory in the plane of the sky as viewed from the Earth) has been designed to pass behind the plume (to pass above the south polar region of Enceladus) in a roughly symmetrical geometry centered on a minimum altitude above the surface of about 20 km. The minimum altitude was selected primarily to ensure probing much of the plume with good confidence given the uncertainty in the spacecraft trajectory. Three nearly-pure sinusoidal signals of 0.94, 3.6, and 13 cm-wavelength (Ka-, X-, and S-band, respectively) are simultaneously transmitted from Cassini and are monitored at two 34-m Earth receiving stations of the Deep Space Network (DSN) in Madrid, Spain (DSS-55 and DSS-65). The occultation of the visible plume is extremely fast, lasting less than about two minutes. The actual observation time extends over a much longer time interval, however, to provide a good reference baseline for potential detection of signal perturbations introduced by the tenuous neutral and ionized plume environment. Given the likely very small fraction of optical depth due to neutral particles of sizes larger than about 1 mm, detectable changes in signal intensity is perhaps unlikely. Detection of plume plasma along the radio path as perturbations in the signals frequency/phase is more likely and the magnitude will depend on the electron columnar density probed. The occultation time occurs not far from solar conjunction time (Sun-Earth-probe angle of about 33 degrees), causing phase scintillations due to the solar wind to be the primary limiting noise source. We estimate a delectability limit of about 1 to 3E16 electrons per square meter columnar density assuming about 100 seconds integration time. Potential measurement of the profile of electron columnar density along the occultation track is an exciting prospect at this time.

Advanced properties of extended plasmas for efficient high-order harmonic generation

SciTech Connect

Ganeev, R. A.; Physics Department, Voronezh State University, Voronezh 394006; Suzuki, M.

We demonstrate the advanced properties of extended plasma plumes (5 mm) for efficient harmonic generation of laser radiation compared with the short lengths of plasmas (∼0.3–0.5 mm) used in previous studies. The harmonic conversion efficiency quadratically increased with the growth of plasma length. The studies of this process along the whole extreme ultraviolet range using the long plasma jets produced on various metal surfaces, particularly including the resonance-enhanced laser frequency conversion and two-color pump, are presented. Such plasmas could be used for the quasi-phase matching experiments by proper modulation of the spatial characteristics of extended ablating area and formation of separated plasmamore » jets.« less

Artificial meteor ablation studies - Iron oxides.

NASA Technical Reports Server (NTRS)

Blanchard, M. B.

1972-01-01

Artificial meteor ablation was performed on natural minerals composed predominantly of magnetite and hematite by using an arc-heated plasma stream of air. Analysis indicates that most of the ablated debris was composed of two or more minerals. Wustite, a metastable mineral, was found to occur as a common product. The 'magnetite' sample, which was 80% magnetite, 14% hematite, 4% apatite, and 2% quartz, yielded ablated products consisting of more than 12 different minerals. Magnetite occurred in 91% of the specimens examined, hematite in 16%, and wustite in 30%. The 'hematite' sample, which was 96% hematite and 3% quartz, yielded ablated products consisting of more than 13 different minerals. Hematite occurred in 47% of the specimens examined, magnetite in 60%, and wustite in 28%. The more volatile elements (Si, P, and Cl) were depleted by about 50%. This study has shown that artificially created ablation products from iron oxides exhibit unique properties that can be used for identification.

Mt Agung (Bali) Eruption Plumes

Atmospheric Science Data Center

2018-05-23

article title:  Mt Agung (Bali) Eruption Plumes     View larger image ... 2017 (left) and calculated plume heights (right)   Volcanic eruptions can generate a significant amount of atmospheric aerosols ...

Active Volcanic Plumes on Io

NASA Image and Video Library

1998-03-26

This color image, acquired during NASA Galileo ninth orbit around Jupiter, shows two volcanic plumes on Io. One plume was captured on the bright limb or edge of the moon, erupting over a caldera volcanic depression named Pillan Patera.

Laser ablation for the synthesis of carbon nanotubes

NASA Technical Reports Server (NTRS)

Holloway, Brian C. (Inventor); Eklund, Peter C. (Inventor); Smith, Michael W. (Inventor); Jordan, Kevin C. (Inventor); Shinn, Michelle (Inventor)

2010-01-01

Single walled carbon nanotubes are produced in a novel apparatus by the laser-induced ablation of moving carbon target. The laser used is of high average power and ultra-fast pulsing. According to various preferred embodiments, the laser produces an output above about 50 watts/cm.sup.2 at a repetition rate above about 15 MHz and exhibits a pulse duration below about 10 picoseconds. The carbon, carbon/catalyst target and the laser beam are moved relative to one another and a focused flow of side pumped, preheated inert gas is introduced near the point of ablation to minimize or eliminate interference by the ablated plume by removal of the plume and introduction of new target area for incidence with the laser beam. When the target is moved relative to the laser beam, rotational or translational movement may be imparted thereto, but rotation of the target is preferred.

Laser ablation for the synthesis of carbon nanotubes

NASA Technical Reports Server (NTRS)

Holloway, Brian C. (Inventor); Eklund, Peter C. (Inventor); Smith, Michael W. (Inventor); Jordan, Kevin C. (Inventor); Shinn, Michelle (Inventor)

2012-01-01

Single walled carbon nanotubes are produced in a novel apparatus by the laser-induced ablation of moving carbon target. The laser used is of high average power and ultra-fast pulsing. According to various preferred embodiments, the laser produces and output above about 50 watts/cm.sup.2 at a repetition rate above about 15 MHz and exhibits a pulse duration below about 10 picoseconds. The carbon, carbon/catalyst target and the laser beam are moved relative to one another and a focused flow of "side pumped", preheated inert gas is introduced near the point of ablation to minimize or eliminate interference by the ablated plume by removal of the plume and introduction of new target area for incidence with the laser beam. When the target is moved relative to the laser beam, rotational or translational movement may be imparted thereto, but rotation of the target is preferred.

Laser ablation for the synthesis of carbon nanotubes

DOEpatents

Holloway, Brian C; Eklund, Peter C; Smith, Michael W; Jordan, Kevin C; Shinn, Michelle

2012-11-27

Single walled carbon nanotubes are produced in a novel apparatus by the laser-induced ablation of moving carbon target. The laser used is of high average power and ultra-fast pulsing. According to various preferred embodiments, the laser produces and output above about 50 watts/cm.sup.2 at a repetition rate above about 15 MHz and exhibits a pulse duration below about 10 picoseconds. The carbon, carbon/catalyst target and the laser beam are moved relative to one another and a focused flow of "side pumped", preheated inert gas is introduced near the point of ablation to minimize or eliminate interference by the ablated plume by removal of the plume and introduction of new target area for incidence with the laser beam. When the target is moved relative to the laser beam, rotational or translational movement may be imparted thereto, but rotation of the target is preferred.

Laser ablation for the synthesis of carbon nanotubes

DOEpatents

Holloway, Brian C.; Eklund, Peter C.; Smith, Michael W.; Jordan, Kevin C.; Shinn, Michelle

2010-04-06

Single walled carbon nanotubes are produced in a novel apparatus by the laser-induced ablation of moving carbon target. The laser used is of high average power and ultra-fast pulsing. According to various preferred embodiments, the laser produces an output above about 50 watts/cm.sup.2 at a repetition rate above about 15 MHz and exhibits a pulse duration below about 10 picoseconds. The carbon, carbon/catalyst target and the laser beam are moved relative to one another and a focused flow of "side pumped", preheated inert gas is introduced near the point of ablation to minimize or eliminate interference by the ablated plume by removal of the plume and introduction of new target area for incidence with the laser beam. When the target is moved relative to the laser beam, rotational or translational movement may be imparted thereto, but rotation of the target is preferred.

Enceladus' Water Vapour Plumes

NASA Technical Reports Server (NTRS)

Hansen, Candice J.; Esposito, L.; Colwell, J.; Hendrix, A.; Matson, Dennis; Parkinson, C.; Pryor, W.; Shemansky, D.; Stewart, I.; Tew, J.;

COLD WEATHER PLUME STUDY

EPA Science Inventory

While many studies of power plant plume transport and transformation have been performed during the summer, few studies of these processes during the winter have been carried out. Accordingly, the U.S. Environmental Protection Agency and the Electric Power Research Institute join...

Improving operational plume forecasts

NASA Astrophysics Data System (ADS)

Balcerak, Ernie

2012-04-01

Forecasting how plumes of particles, such as radioactive particles from a nuclear disaster, will be transported and dispersed in the atmosphere is an important but computationally challenging task. During the Fukushima nuclear disaster in Japan, operational plume forecasts were produced each day, but as the emissions continued, previous emissions were not included in the simulations used for forecasts because it became impractical to rerun the simulations each day from the beginning of the accident. Draxler and Rolph examine whether it is possible to improve plume simulation speed and flexibility as conditions and input data change. The authors use a method known as a transfer coefficient matrix approach that allows them to simulate many radionuclides using only a few generic species for the computation. Their simulations work faster by dividing the computation into separate independent segments in such a way that the most computationally time consuming pieces of the calculation need to be done only once. This makes it possible to provide real-time operational plume forecasts by continuously updating the previous simulations as new data become available. They tested their method using data from the Fukushima incident to show that it performed well. (Journal of Geophysical Research-Atmospheres, doi:10.1029/2011JD017205, 2012)

Evaluation of Visible Plumes.

ERIC Educational Resources Information Center

Brennan, Thomas

Developed for presentation at the 12th Conference on Methods in Air Pollution and Industrial Hygiene Studies, University of Southern California, April, 1971, this outline discusses plumes with contaminants that are visible to the naked eye. Information covers: (1) history of air pollution control regulations, (2) need for methods of evaluating…

PLUME and research sotware

NASA Astrophysics Data System (ADS)

Baudin, Veronique; Gomez-Diaz, Teresa

2013-04-01

The PLUME open platform (https://www.projet-plume.org) has as first goal to share competences and to value the knowledge of software experts within the French higher education and research communities. The project proposes in its platform the access to more than 380 index cards describing useful and economic software for this community, with open access to everybody. The second goal of PLUME focuses on to improve the visibility of software produced by research laboratories within the higher education and research communities. The "development-ESR" index cards briefly describe the main features of the software, including references to research publications associated to it. The platform counts more than 300 cards describing research software, where 89 cards have an English version. In this talk we describe the theme classification and the taxonomy of the index cards and the evolution with new themes added to the project. We will also focus on the organisation of PLUME as an open project and its interests in the promotion of free/open source software from and for research, contributing to the creation of a community of shared knowledge.

Enceladus Plume Movie

NASA Image and Video Library

2005-12-06

Jets of icy particles burst from Saturn’s moon Enceladus in this brief movie sequence of four images taken on Nov. 27, 2005. The sensational discovery of active eruptions on a third outer solar system body (Io and Triton are the others) is surely one of the great highlights of the Cassini mission. Imaging scientists, as reported in the journal Science on March 10, 2006, believe that the jets are geysers erupting from pressurized subsurface reservoirs of liquid water above 273 degrees Kelvin (0 degrees Celsius). Images taken in January 2005 appeared to show the plume emanating from the fractured south polar region of Enceladus, but the visible plume was only slightly brighter than the background noise in the image, because the lighting geometry was not suitable to reveal the true details of the feature. This potential sighting, in addition to the detection of the icy particles in the plume by other Cassini instruments, prompted imaging scientists to target Enceladus again with exposures designed to confirm the validity of the earlier plume sighting. The new views show individual jets, or plume sources, that contribute to the plume with much greater visibility than the earlier images. The full plume towers over the 505-kilometer-wide (314-mile) moon and is at least as tall as the moon's diameter. The four 10-second exposures were taken over the course of about 36 minutes at approximately 12 minute intervals. Enceladus rotates about 7.5 degrees in longitude over the course of the frames, and most of the observed changes in the appearances of the jets is likely attributable to changes in the viewing geometry. However, some of the changes may be due to actual variation in the flow from the jets on a time scale of tens of minutes. Additionally, the shift of the sources seen here should provide information about their location in front of and behind the visible limb (edge) of Enceladus. These images were obtained using the Cassini spacecraft narrow-angle camera at

Direct solid analysis of powdered tungsten carbide hardmetal precursors by laser-induced argon spark ablation with inductively coupled plasma atomic emission spectrometry.

PubMed

Holá, Markéta; Kanický, Viktor; Mermet, Jean-Michel; Otruba, Vítezslav

2003-12-01

The potential of the laser-induced argon spark atomizer (LINA-Spark atomizer) coupled with ICP-AES as a convenient device for direct analysis of WC/Co powdered precursors of sintered hardmetals was studied. The samples were presented for the ablation as pressed pellets prepared by mixing with powdered silver binder containing GeO2 as internal standard. The pellets were ablated with the aid of a Q-switched Nd:YAG laser (1064 nm) focused 16 mm behind the target surface with a resulting estimated power density of 5 GW cm(-2). Laser ablation ICP-AES signals were studied as a function of ablation time, and the duration of time prior to measurement (pre-ablation time) which was necessary to obtain reliable results was about 40 s. Linear calibration plots were obtained up to 10% (m/m) Ti, 9% Ta and 3.5% Nb both without internal standardization and by using germanium as an added internal standard or tungsten as a contained internal standard. The relative uncertainty at the centroid of the calibration line was in the range from +/- 6% to +/- 11% for Nb, Ta and Ti both with and without internal standardisation by Ge. A higher spread of points about the regression was observed for cobalt for which the relative uncertainty at the centroid was in the range from +/- 9% to +/- 14%. Repeatability of results was improved by the use of both Ge and W internal standards. The lowest determinable quantities calculated for calibration plots were 0.060% Co, 0.010% Nb, 0.16% Ta and 0.030% Ti with internal standardization by Ge. The LA-ICP-AES analyses of real samples led to good agreement with the results obtained by solution-based ICP determination with a relative bias not exceeding 10%. The elimination of the dissolution procedure of powdered tungsten (Nb, Ta, Ti) carbide is the principal advantage of the developed LA-ICP-AES method.

Thermal imaging of afterburning plumes

NASA Astrophysics Data System (ADS)

Ajdari, E.; Gutmark, E.; Parr, T. P.; Wilson, K. J.; Schadow, K. C.

1989-01-01

Afterburning and nonafterburning exhaust plumes were studied experimentally for underexpanded sonic and supersonic conical circular nozzles. The plume structure was visualized using thermal imaging camera and regular photography. IR emission by the plume is mainly dependent on the presence of afterburning. Temperature and reducing power of the exhaust gases, in addition to the nozzle configuration, determine the structure of the plume core, the location where the afterburning is initiated, its size and intensity. Comparison between single shot and average thermal images of the plume show that afterburning is a highly turbulent combustion process.

Simulation of Pellet Ablation

NASA Astrophysics Data System (ADS)

Parks, P. B.; Ishizaki, Ryuichi

2000-10-01

In order to clarify the structure of the ablation flow, 2D simulation is carried out with a fluid code solving temporal evolution of MHD equations. The code includes electrostatic sheath effect at the cloud interface.(P.B. Parks et al.), Plasma Phys. Contr. Fusion 38, 571 (1996). An Eulerian cylindrical coordinate system (r,z) is used with z in a spherical pellet. The code uses the Cubic-Interpolated Psudoparticle (CIP) method(H. Takewaki and T. Yabe, J. Comput. Phys. 70), 355 (1987). that divides the fluid equations into non-advection and advection phases. The most essential element of the CIP method is in calculation of the advection phase. In this phase, a cubic interpolated spatial profile is shifted in space according to the total derivative equations, similarly to a particle scheme. Since the profile is interpolated by using the value and the spatial derivative value at each grid point, there is no numerical oscillation in space, that often appears in conventional spline interpolation. A free boundary condition is used in the code. The possibility of a stationary shock will also be shown in the presentation because the supersonic ablation flow across the magnetic field is impeded.

Electron Scattering by Plasmaspheric Hiss in a Nightside Plume

NASA Astrophysics Data System (ADS)

Zhang, Wenxun; Fu, Song; Gu, Xudong; Ni, Binbin; Xiang, Zheng; Summers, Danny; Zou, Zhengyang; Cao, Xing; Lou, Yuequn; Hua, Man

2018-05-01

Plasmaspheric hiss is known to play an important role in radiation belt electron dynamics in high plasma density regions. We present observations of two crossings of a plasmaspheric plume by the Van Allen Probes on 26 December 2012, which occurred unusually at the post-midnight-to-dawn sector between L 4-6 during a geomagnetically quiet period. This plume exhibited pronounced electron densities higher than those of the average plume level. Moderate hiss emissions accompanied the two plume crossings with the peak power at about 100 Hz. Quantification of quasi-linear bounce-averaged electron scattering rates by hiss in the plume demonstrates that the waves are efficient to pitch angle scatter 10-100 keV electrons at rates up to 10-4 s-1 near the loss cone but become gradually insignificant to scatter the higher energy electron population. The resultant timescales of electron loss due to hiss in the nightside plume vary largely with electron kinetic energy over 3 orders of magnitude, that is, from several hours for tens of keV electrons to a few days for hundreds of keV electrons to well above 100 days for >1 MeV electrons. Changing slightly with L-shell and the multiquartile profile of hiss spectral intensity, these electron loss timescales suggest that hiss emissions in the nightside plume act as a viable candidate for the fast loss of the ≲100 keV electrons and the slow decay of higher energy electrons.

Laser ablation with applied magnetic field for electric propulsion

NASA Astrophysics Data System (ADS)

Batishcheva, Alla; Batishchev, Oleg; Cambier, Jean-Luc

2012-10-01

Using ultrafast lasers with tera-watt-level power allows efficient ablation and ionization of solid-density materials [1], creating dense and hot (˜100eV) plasma. We propose ablating small droplets in the magnetic nozzle configurations similar to mini-helicon plasma source [2]. Such approach may improve the momentum coupling compared to ablation of solid surfaces and facilitate plasma detachment. Results of 2D modeling of solid wire ablation in the applied magnetic field are presented and discussed. [4pt] [1] O. Batishchev et al, Ultrafast Laser Ablation for Space Propulsion, AIAA technical paper 2008-5294, -16p, 44th JPC, Hartford, 2008.[0pt] [2] O. Batishchev and J.L. Cambier, Experimental Study of the Mini-Helicon Thruster, Air Force Research Laboratory Report, AFRL-RZ-ED-TR-2009-0020, 2009.

Ablation enhancement of silicon by ultrashort double-pulse laser ablation

SciTech Connect

Zhao, Xin; Shin, Yung C.

In this study, the ultrashort double-pulse ablation of silicon is investigated. An atomistic simulation model is developed to analyze the underlying physics. It is revealed that the double-pulse ablation could significantly increase the ablation rate of silicon, compared with the single pulse ablation with the same total pulse energy, which is totally different from the case of metals. In the long pulse delay range (over 1 ps), the enhancement is caused by the metallic transition of melted silicon with the corresponding absorption efficiency. At ultrashort pulse delay (below 1 ps), the enhancement is due to the electron excitation by the first pulse.more » The enhancement only occurs at low and moderate laser fluence. The ablation is suppressed at high fluence due to the strong plasma shielding effect.« less

Mucosal ablation in Barrett's esophagus.

PubMed

Walker, S J; Selvasekar, C R; Birbeck, N

2002-01-01

Barrett's esophagus is a prevalent, premalignant condition affecting the gastroesophageal junction and distal esophagus. Ablation plus antireflux therapy has recently been advocated to prevent the development of adenocarcinoma or to treat those unfit or unwilling to undergo esophagectomy. The present article, based on a search of Medline/ISI databases and cross-referencing of relevant articles, reviews the literature on this subject. A number of techniques have been used to remove the affected mucosa, including laser, electrocoagulation, argon plasma coagulation and photodynamic therapy but, as yet, none has been shown to be superior. Depending on the method used, ablation results in complete removal of Barrett's esophagus in approximately one third of patients and a partial response in nearly two-thirds. The resultant squamous mucosa is apparently 'normal' but may regress. To promote and maintain regeneration, antireflux therapy must be sufficient to reduce repetitive injury to the esophageal mucosa. Whether ablation reduces the cancer risk or delays its occurrence is unknown, though recent data suggests benefit. Complications are infrequent and usually mild. Regular follow-up endoscopy and deep biopsies continue to be necessary. Careful data from much larger populations with long-term follow-up is required before ablation reaches the stage of broad clinical application.

A rapid and reliable method for Pb isotopic analysis of peat and lichens by laser ablation-quadrupole-inductively coupled plasma-mass spectrometry for biomonitoring and sample screening.

PubMed

Kylander, M E; Weiss, D J; Jeffries, T E; Kober, B; Dolgopolova, A; Garcia-Sanchez, R; Coles, B J

2007-01-16

An analytical protocol for rapid and reliable laser ablation-quadrupole (LA-Q)- and multi-collector (MC-) inductively coupled plasma-mass spectrometry (ICP-MS) analysis of Pb isotope ratios ((207)Pb/(206)Pb and (208)Pb/(206)Pb) in peats and lichens is developed. This technique is applicable to source tracing atmospheric Pb deposition in biomonitoring studies and sample screening. Reference materials and environmental samples were dry ashed and pressed into pellets for introduction by laser ablation. No binder was used to reduce contamination. LA-MC-ICP-MS internal and external precisions were <1.1% and <0.3%, respectively, on both (207)Pb/(206)Pb and (208)Pb/(206)Pb ratios. LA-Q-ICP-MS internal precisions on (207)Pb/(206)Pb and (208)Pb/(206)Pb ratios were lower with values for the different sample sets <14.3% while external precisions were <2.9%. The level of external precision acquired in this study is high enough to distinguish between most modern Pb sources. LA-MC-ICP-MS measurements differed from thermal ionisation mass spectrometry (TIMS) values by 1% or less while the accuracy obtained using LA-Q-ICP-MS compared to solution MC-ICP-MS was 3.1% or better using a run bracketing (RB) mass bias correction method. Sample heterogeneity and detector switching when measuring (208)Pb by Q-ICP-MS are identified as sources of reduced analytical performance.

Use of laser ablation-inductively coupled plasma-time of flight-mass spectrometry to identify the elemental composition of vanilla and determine the geographic origin by discriminant function analysis.

PubMed

Hondrogiannis, Ellen M; Ehrlinger, Erin; Poplaski, Alyssa; Lisle, Meredith

2013-11-27

A total of 11 elements found in 25 vanilla samples from Uganda, Madagascar, Indonesia, and Papua New Guinea were measured by laser ablation-inductively coupled plasma-time-of-flight-mass spectrometry (LA-ICP-TOF-MS) for the purpose of collecting data that could be used to discriminate among the origins. Pellets were prepared of the samples, and elemental concentrations were obtained on the basis of external calibration curves created using five National Institute of Standards and Technology (NIST) standards and one Chinese standard with (13)C internal standardization. These curves were validated using NIST 1573a (tomato leaves) as a check standard. Discriminant analysis was used to successfully classify the vanilla samples by their origin. Our method illustrates the feasibility of using LA-ICP-TOF-MS with an external calibration curve for high-throughput screening of spice screening analysis.

Seismic Imaging of Mantle Plumes

NASA Astrophysics Data System (ADS)

Nataf, Henri-Claude

The mantle plume hypothesis was proposed thirty years ago by Jason Morgan to explain hotspot volcanoes such as Hawaii. A thermal diapir (or plume) rises from the thermal boundary layer at the base of the mantle and produces a chain of volcanoes as a plate moves on top of it. The idea is very attractive, but direct evidence for actual plumes is weak, and many questions remain unanswered. With the great improvement of seismic imagery in the past ten years, new prospects have arisen. Mantle plumes are expected to be rather narrow, and their detection by seismic techniques requires specific developments as well as dedicated field experiments. Regional travel-time tomography has provided good evidence for plumes in the upper mantle beneath a few hotspots (Yellowstone, Massif Central, Iceland). Beneath Hawaii and Iceland, the plume can be detected in the transition zone because it deflects the seismic discontinuities at 410 and 660 km depths. In the lower mantle, plumes are very difficult to detect, so specific methods have been worked out for this purpose. There are hints of a plume beneath the weak Bowie hotspot, as well as intriguing observations for Hawaii. Beneath Iceland, high-resolution tomography has just revealed a wide and meandering plume-like structure extending from the core-mantle boundary up to the surface. Among the many phenomena that seem to take place in the lowermost mantle (or D''), there are also signs there of the presence of plumes. In this article I review the main results obtained so far from these studies and discuss their implications for plume dynamics. Seismic imaging of mantle plumes is still in its infancy but should soon become a turbulent teenager.

Low altitude plume impingement handbook

NASA Technical Reports Server (NTRS)

Smith, Sheldon D.

1991-01-01

Plume Impingement modeling is required whenever an object immersed in a rocket exhaust plume must survive or remain undamaged within specified limits, due to thermal and pressure environments induced by the plume. At high altitudes inviscid plume models, Monte Carlo techniques along with the Plume Impingement Program can be used to predict reasonably accurate environments since there are usually no strong flowfield/body interactions or atmospheric effects. However, at low altitudes there is plume-atmospheric mixing and potential large flowfield perturbations due to plume-structure interaction. If the impinged surface is large relative to the flowfield and the flowfield is supersonic, the shock near the surface can stand off the surface several exit radii. This results in an effective total pressure that is higher than that which exists in the free plume at the surface. Additionally, in two phase plumes, there can be strong particle-gas interaction in the flowfield immediately ahead of the surface. To date there have been three levels of sophistication that have been used for low altitude plume induced environment predictions. Level 1 calculations rely on empirical characterizations of the flowfield and relatively simple impingement modeling. An example of this technique is described by Piesik. A Level 2 approach consists of characterizing the viscous plume using the SPF/2 code or RAMP2/LAMP and using the Plume Impingement Program to predict the environments. A Level 3 analysis would consist of using a Navier-Stokes code such as the FDNS code to model the flowfield and structure during a single calculation. To date, Level 1 and Level 2 type analyses have been primarily used to perform environment calculations. The recent advances in CFD modeling and computer resources allow Level 2 type analysis to be used for final design studies. Following some background on low altitude impingement, Level 1, 2, and 3 type analysis will be described.

Laser ablation in analytical chemistry - A review

SciTech Connect

Russo, Richard E.; Mao, Xianglei; Liu, Haichen

Laser ablation is becoming a dominant technology for direct solid sampling in analytical chemistry. Laser ablation refers to the process in which an intense burst of energy delivered by a short laser pulse is used to sample (remove a portion of) a material. The advantages of laser ablation chemical analysis include direct characterization of solids, no chemical procedures for dissolution, reduced risk of contamination or sample loss, analysis of very small samples not separable for solution analysis, and determination of spatial distributions of elemental composition. This review describes recent research to understand and utilize laser ablation for direct solid sampling,more » with emphasis on sample introduction to an inductively coupled plasma (ICP). Current research related to contemporary experimental systems, calibration and optimization, and fractionation is discussed, with a summary of applications in several areas.« less

Inorganic fullerene-like molybdenum selenide with good biocompatibility synthesized by laser ablation in liquids

NASA Astrophysics Data System (ADS)

Wu, Xiaoju; Tian, Xiumei; Chen, Tongming; Zeng, Ao; Yang, Guowei

2018-07-01

The fabrication of inorganic fullerene-like nanoparticles (IFNPs) is an attractive idea due to their unique structures and various potential applications. To date, IFNPs have been made from numerous compounds with layered two-dimensional structures, based on various synthetic methods. Here we have demonstrated for the first time that inorganic fullerene-like molybdenum selenide nanoparticles (MoSe2 IFNPs) can be synthesized by laser ablating a molybdenum selenide target in 30 vol % ethanol/water mixture at ambient temperature and pressure. The formation mechanism was proposed to elucidate the production of MoSe2 IFNPs in the process of laser ablation in liquids (LAL). The appropriate solvent facilitates the condensation of the plasma plume created by LAL to planar MoSe2. Then, laser-induced high temperature and high pressure lead to the formation of a vacancy in the planar MoSe2, causing the generation of nucleation and growth of the MoSe2 IFNPs. In addition, a CCK-8 (cell counting kit-8) assay and a cell viability assay were performed to examine the cytotoxic behavior and the effect on cell viability of MoSe2 IFNPs. The results show that MoSe2 IFNPs are reasonably nontoxic and biocompatible with the given cells, showing they have significant potential in biomedical applications.

Inorganic fullerene-like molybdenum selenide with good biocompatibility synthesized by laser ablation in liquids.

PubMed

Wu, Xiaoju; Tian, Xiumei; Chen, Tongming; Zeng, Ao; Yang, Guowei

2018-07-20

The fabrication of inorganic fullerene-like nanoparticles (IFNPs) is an attractive idea due to their unique structures and various potential applications. To date, IFNPs have been made from numerous compounds with layered two-dimensional structures, based on various synthetic methods. Here we have demonstrated for the first time that inorganic fullerene-like molybdenum selenide nanoparticles (MoSe 2 IFNPs) can be synthesized by laser ablating a molybdenum selenide target in 30 vol % ethanol/water mixture at ambient temperature and pressure. The formation mechanism was proposed to elucidate the production of MoSe 2 IFNPs in the process of laser ablation in liquids (LAL). The appropriate solvent facilitates the condensation of the plasma plume created by LAL to planar MoSe 2 . Then, laser-induced high temperature and high pressure lead to the formation of a vacancy in the planar MoSe 2 , causing the generation of nucleation and growth of the MoSe 2 IFNPs. In addition, a CCK-8 (cell counting kit-8) assay and a cell viability assay were performed to examine the cytotoxic behavior and the effect on cell viability of MoSe 2 IFNPs. The results show that MoSe 2 IFNPs are reasonably nontoxic and biocompatible with the given cells, showing they have significant potential in biomedical applications.

Mantle plumes and continental tectonics.

PubMed

Hill, R I; Campbell, I H; Davies, G F; Griffiths, R W

1992-04-10

Mantle plumes and plate tectonics, the result of two distinct modes of convection within the Earth, operate largely independently. Although plumes are secondary in terms of heat transport, they have probably played an important role in continental geology. A new plume starts with a large spherical head that can cause uplift and flood basalt volcanism, and may be responsible for regional-scale metamorphism or crustal melting and varying amounts of crustal extension. Plume heads are followed by narrow tails that give rise to the familiar hot-spot tracks. The cumulative effect of processes associated with tail volcanism may also significantly affect continental crust.

Oxide or carbide nanoparticles synthesized by laser ablation of a bulk Hf target in liquids and their structural, optical, and dielectric properties

SciTech Connect

Semaltianos, N. G., E-mail: nsemaltianos@yahoo.com; Friedt, J.-M.; Blondeau-Patissier, V.

2016-05-28

Laser ablation of a bulk Hf target in deionized (DI) water, ethanol, or toluene was carried out for the production of nanoparticles' colloidal solutions. Due to the interaction of the ablation plasma plume species with the species which are produced by the liquid decomposition at the plume-liquid interface, hafnia (HfO{sub 2}) nanoparticles are synthesized in DI water, hafnium carbide (HfC) nanoparticles in toluene, and a mixture of these in ethanol. The hafnia nanoparticles are in the monoclinic low temperature phase and in the tetragonal and fcc high temperature phases. Their size distribution follows log-normal function with a median diameter inmore » the range of 4.3–5.3 nm. Nanoparticles synthesized in DI water have band gaps of 5.6 and 5.4 eV, in ethanol 5.72 and 5.65 eV (using low and high pulse energy), and in toluene 3 eV. The values for the relative permittivity in the range of 7.74–8.90 were measured for hafnia nanoparticles' thin films deposited on substrates by drop-casting (self-assembled layers) in parallel plate capacitor structures.« less

Study of Mn laser ablation in methane atmosphere

NASA Astrophysics Data System (ADS)

Krstulović, N.; Labazan, I.; Milošević, S.

2006-02-01

Laser ablation of Mn target in vacuum and in the presence of CH4 was studied under 308 nm laser irradiation. Time-resolved emission using gated detection and scanning monochromator and absorption using the cavity ring-down spectroscopy were used to study vaporized plume. In the CH4 atmosphere we observed transitions identified as C2 and MnH bands, while these spectral features were not detected in emission spectra. This is a clear evidence of importance in combining both spectroscopic techniques in laser vaporized plume study.

Why the SL9 Plumes Were All About the Same Height

NASA Technical Reports Server (NTRS)

Zahnle, K.; MacLow, M.-M.; Cuzzi, Jeffery N. (Technical Monitor)

1995-01-01

Several of the SL9 ejecta plumes were observed by the HST to reach approximately the same height, about 3000 km above the jovian cloud tops. The duration of the infrared events, which were produced by the plume falling back on the atmosphere, measures time aloft and hence provides a second, more sensitive measure of plume height; the light curves indicate that the largest impacts produced modestly higher plumes. Evidently these plumes were launched with about the same vertical velocity, roughly 10-13 kilometers per second. As the impactors themselves were not all the same, nor the impacts equally luminous, nor the plumes equally opaque, the similar plume heights has been seen as a puzzle needing explanation. A second, closely related matter that needs to addressed quantitatively is the popular contention that a big plume requires a big impact. This view is misleading at best, yet plume heights can be used to constrain impact parameters. Dimensional analysis indicates that plume height goes as z alpha v (sup 2) (sub ej) alpha E/pH (sup 2), where v (sub ej) is the ejection velocity, E the explosion energy, and p and H the ambient pressure and scale height at termination. Using a semi-analytic model for the deceleration, disintegration, and destruction of intruding bodies by an ever-vigilant atmosphere, we find that the ratio E/pH(sup 2) is roughly constant for fragments with diameters of order 100 m to 1000 m. Constancy of v(sub ej) is in part due to the greater role of radiative ablation on the flight of smaller objects. We conclude that similar plume heights is a direct consequence of smaller impactors exploding at higher altitudes, in such a way that the different explosions were geometrically similar.

Geochronology and geochemistry of basaltic rocks from the Sartuohai ophiolitic mélange, NW China: Implications for a Devonian mantle plume within the Junggar Ocean

NASA Astrophysics Data System (ADS)

Yang, Gaoxue; Li, Yongjun; Santosh, M.; Yang, Baokai; Yan, Jing; Zhang, Bing; Tong, Lili

2012-10-01

The West Junggar domain in NW China is a distinct tectonic unit of the Central Asian Orogenic Belt (CAOB). It is composed of Paleozoic ophiolitic mélanges, arcs and accretionary complexes. The Sartuohai ophiolitic mélange in the eastern West Junggar forms the northeastern part of the Darbut ophiolitic mélange, which contains serpentinized harzburgite, pyroxenite, dunite, cumulate, pillow lava, abyssal radiolarian chert and podiform chromite, overlain by the Early Carboniferous volcano-sedimentary rocks. In this paper we report new geochronological and geochemical data from basaltic and gabbroic blocks embedded within the Sartuohai ophiolitic mélange, to assess the possible presence of a Devonian mantle plume in the West Junggar, and evaluate the petrogenesis and implications for understanding of the Paleozoic continental accretion of CAOB. Zircon U-Pb analyses from the alkali basalt and gabbro by laser ablation inductively coupled plasma mass spectrometry yielded weighted mean ages of 375 ± 2 Ma and 368 ± 11 Ma. Geochemically, the Sartuohai ophiolitic mélange includes at least two distinct magmatic units: (1) a Late Devonian fragmented ophiolite, which were produced by ca. 2-10% spinel lherzolite partial melting in arc-related setting, and (2) contemporary alkali lavas, which were derived from 5% to 10% garnet + minor spinel lherzolite partial melting in an oceanic plateau or a seamount. Based on detailed zircon U-Pb dating and geochemical data for basalts and gabbros from the Sartuohai ophiolitic mélange, in combination with previous work, indicate a complex evolution by subduction-accretion processes from the Devonian to the Carboniferous. Furthermore, the alkali basalts from the Sartuohai ophiolitic mélange might be correlated to a Devonian mantle plume-related magmatism within the Junggar Ocean. If the plume model as proposed here is correct, it would suggest that mantle plume activity significantly contributed to the crustal growth in the CAOB.

Plasma Medicine

NASA Astrophysics Data System (ADS)

Laroussi, M.; Kong, M. G.; Morfill, G.; Stolz, W.

2012-05-01

Foreword R. Satava and R. J. Barker; Part I. Introduction to Non-equilibrium Plasma, Cell Biology, and Contamination: 1. Introduction M. Laroussi; 2. Fundamentals of non-equilibrium plasmas M. Kushner and M. Kong; 3. Non-equilibrium plasma sources M. Laroussi and M. Kong; 4. Basic cell biology L. Greene and G. Shama; 5. Contamination G. Shama and B. Ahlfeld; Part II. Plasma Biology and Plasma Medicine: 6. Common healthcare challenges G. Isbary and W. Stolz; 7. Plasma decontamination of surfaces M. Kong and M. Laroussi; 8. Plasma decontamination of gases and liquids A. Fridman; 9. Plasma-cell interaction: prokaryotes M. Laroussi and M. Kong; 10. Plasma-cell interaction: eukaryotes G. Isbary, G. Morfill and W. Stolz; 11. Plasma based wound healing G. Isbary, G. Morfill and W. Stolz; 12. Plasma ablation, surgery, and dental applications K. Stalder, J. Woloszko, S. Kalghatgi, G. McCombs, M. Darby and M. Laroussi; Index.

Artificial meteor ablation studies: Olivine

NASA Technical Reports Server (NTRS)

Blanchard, M. B.; Cunningham, G. G.

1973-01-01

Artificial meteor ablation was performed on a Mg-rich olivine sample using an arc-heated plasma of ionized air. Experimental conditions simulated a meteor traveling about 12 km/sec at an altitude of 70 km. The mineral content of the original olivine sample was 98% olivine (including traces of olivine alteration products) and 2% chromite. Forsterite content of the original olivine was Fo-89. After ablation, the forsterite content had increased to Fo-94 in the recrystallized olivine. In addition, lamella-like intergrowths of magnetite were prevalent constituents. Wherever magnetite occurred, there was an increase in Mg and a corresponding decrease in Fe for the recrystallized olivine. The Allende fusion crust consisted of a recrystallized olivine, which was more Mg-rich and Fe-deficient than the original meteorite's olivine, and abundant magnetite grains. Although troilite and pentlandite were the common opaque mineral constituents in this meteorite, magnetite was the principal opaque mineral found in the fusion crust.

HYDRA: Macroscopic 3D Approach of Light Weight Ablator

NASA Astrophysics Data System (ADS)

Pinaud, G.; Barcena, J.; Bouilly, J.-M.; Leroy, V.; Fischer, Wpp.; Massuti, T.

2014-06-01

The HYDRA project is an European funded program that aims at developing novel solution in term of TPS associated to a demonstration of Technology Readiness Level (TRL) 4. We describe modelling activities (radiation/ablation) compared to plasma test.

Confinement effect of cylindrical-separatrix-type magnetic field on the plume of magnetic focusing type Hall thruster

NASA Astrophysics Data System (ADS)

Yu, Daren; Meng, Tianhang; Ning, Zhongxi; Liu, Hui

2017-04-01

A magnetic focusing type Hall thruster was designed with a cylindrical magnetic seperatrix. During the process of a hollow cathode crossing the separatrix, the variance of plume parameter distribution was monitored. Results show that the ion flux on the large spatial angle is significantly lower when the hollow cathode is located in the inner magnetic field. This convergence effect is preserved even in a distant area. A mechanism was proposed for plume divergence from the perspective of cathode-to-plume potential difference, through which the confinement effect of cylindrical-separatrix-type magnetic field on thruster plume was confirmed and proposed as a means of plume protection for plasma propulsion devices.

Ash Plume from Shiveluch

NASA Image and Video Library

2012-10-09

When NASA’s Terra satellite passed over Russia’s Kamchatka Peninsula at noon local time (00:00 Universal Time) on October 6, 2012, Shilveluch Volcano was quiet. By the time NASA’s Aqua satellite passed over the area two hours later (bottom image), the volcano had erupted and sent a plume of ash over the Kamchatskiy Zaliv. The plume traveled about 90 kilometers (55 miles) toward the south-southeast, where a change in wind direction began pushing the plume toward the east. On October 6, 2012, the Kamchatka Volcanic Emergency Response Team (KVERT) reported that the ash plume from Shiveluch reached an altitude of 3 kilometers (9,800 feet) above sea level, and had traveled some 220 kilometers (140 miles) from the volcano summit. Shiveluch (also spelled Sheveluch) ranks among the biggest and most active volcanoes on the Kamchatka Peninsula. Rising to 3,283 meters (10,771 feet) above sea level, Shiveluch is a stratovolcano composed of alternating layers of hardened lava, compacted ash, and rocks ejected by previous eruptions. The beige-colored expanse of rock on the volcano’s southern slopes (visible in both images) is due to an explosive eruption that occurred in 1964. Part of Shiveluch’s southern flank collapsed, and the light-colored rock is avalanche debris left by that event. High-resolution imagery of Shiveluch shows very little vegetation within that avalanche zone. On October 6, 2012, KVERT cited observations from the Moderate Resolution Imaging Spectroradiometer (MODIS) instruments on Terra and Aqua in detecting the Shiveluch eruption. This was not the first time that MODIS observed a Shiveluch eruption shortly after it started. In 2007, MODIS captured an image within minutes of the eruption’s start, before winds could blow the ash away from the summit. When NASA’s Terra satellite passed over Russia’s Kamchatka Peninsula at noon local time (00:00 Universal Time) on October 6, 2012, Shilveluch Volcano was quiet (top image). By the time NASA�

Applications of Nanoparticle-Containing Plasmas for High-Order Harmonic Generation of Laser Radiation

NASA Astrophysics Data System (ADS)

Ganeev, Rashid A.

The use of nanoparticles for efficient conversion of the wavelength of ultrashort laser toward the deep UV spectral range through harmonic generation is an attractive application of cluster-containing plasmas. Note that earlier observations of HHG in nanoparticles were limited by using the exotic gas clusters formed during fast cooling of atomic flow from the gas jets 1-4. One can assume the difficulties in definition of the structure of such clusters and the ratio between nanoparticles and atoms/ions in the gas flow. The characterization of gas phase cluster production was currently improved using the sophisticated techniques (e.g., a control of nanoparticle mass and spatial distribution, see the review 5). In the meantime, the plasma nanoparticle HHG has demonstrated some advantages over gas cluster HHG 6. The application of commercially available nanopowders allowed for precisely defining the sizes and structure of these clusters in the plume. The laser ablation technique made possible the predictable manipulation of plasma characteristics, which led to the creation of laser plumes containing mainly nanoparticles with known spatial structure. The latter allows the application of such plumes in nonlinear optics, X-ray emission of clusters, deposition of nanoparticles with fixed parameters on the substrates for semiconductor industry, production of nanostructured and nanocomposite films, etc.

Global ablation techniques.

PubMed

Woods, Sarah; Taylor, Betsy

2013-12-01

Global endometrial ablation techniques are a relatively new surgical technology for the treatment of heavy menstrual bleeding that can now be used even in an outpatient clinic setting. A comparison of global ablation versus earlier ablation technologies notes no significant differences in success rates and some improvement in patient satisfaction. The advantages of the newer global endometrial ablation systems include less operative time, improved recovery time, and decreased anesthetic risk. Ablation procedures performed in an outpatient surgical or clinic setting provide advantages both of potential cost savings for patients and the health care system and improved patient convenience. Copyright © 2013. Published by Elsevier Inc.

In Situ Determination of Trace Elements in Fish Otoliths by Laser Ablation Double Focusing Sector Field Inductively Coupled Plasma Mass Spectrometry Using a Solution Standard Addition Calibration Method

NASA Astrophysics Data System (ADS)

Chen, Z.; Jones, C. M.

2002-05-01

Microchemistry of fish otoliths (fish ear bones) is a very useful tool for monitoring aquatic environments and fish migration. However, determination of the elemental composition in fish otolith by ICP-MS has been limited to either analysis of dissolved sample solution or measurement of limited number of trace elements by laser ablation (LA)- ICP-MS due to low sensitivity, lack of available calibration standards, and complexity of polyatomic molecular interference. In this study, a method was developed for in situ determination of trace elements in fish otoliths by laser ablation double focusing sector field ultra high sensitivity Finnigan Element 2 ICP-MS using a solution standard addition calibration method. Due to the lack of matrix-match solid calibration standards, sixteen trace elements (Na, Mg, P, Cr, Mn, Fe, Ni, Cu, Rb, Sr, Y, Cd, La, Ba, Pb and U) were determined using a solution standard calibration with Ca as an internal standard. Flexibility, easy preparation and stable signals are the advantages of using solution calibration standards. In order to resolve polyatomic molecular interferences, medium resolution (M/delta M > 4000) was used for some elements (Na, Mg, P, Cr, Mn, Fe, Ni, and Cu). Both external calibration and standard addition quantification strategies are compared and discussed. Precision, accuracy, and limits of detection are presented.

Hypervelocity Dust Injection for Plasma Diagnostic Applications

NASA Astrophysics Data System (ADS)

Ticos, Catalin

2005-10-01

Hypervelocity micron-size dust grain injection was proposed for high-temperature magnetized plasma diagnosis. Multiple dust grains are launched simultaneously into high temperature plasmas at several km/s or more. The hypervelocity dust grains are ablated by the electron and ion fluxes. Fast imaging of the resulting luminous plumes attached to each grain is expected to yield local magnetic field vectors. Combination of multiple local magnetic field vectors reproduces 2D or even 3D maps of the internal magnetic field topology. Key features of HDI are: (1) a high spatial resolution, due to a relatively small transverse size of the elongated tail, and (2) a small perturbation level, as the dust grains introduce negligible number of particles compared to the plasma particle inventory. The latter advantage, however, could be seriously compromised if the gas load from the accelerator has an unobstructed access to the diagnosed plasma. Construction of a HDI diagnostic for National Spherical Torus Experiment (NSTX), which includes a coaxial plasma gun for dust grain acceleration, is underway. Hydrogen and deuterium gas discharges inside accelerator are created by a ˜ 1 mF capacitor bank pre-charged up to 10 kV. The diagnostic apparatus also comprises a dust dispenser for pre-loading the accelerator with dust grains, and an imaging system that has a high spatial and temporal resolution.

Atmospheric chemistry in volcanic plumes.

PubMed

von Glasow, Roland

2010-04-13

Recent field observations have shown that the atmospheric plumes of quiescently degassing volcanoes are chemically very active, pointing to the role of chemical cycles involving halogen species and heterogeneous reactions on aerosol particles that have previously been unexplored for this type of volcanic plumes. Key features of these measurements can be reproduced by numerical models such as the one employed in this study. The model shows sustained high levels of reactive bromine in the plume, leading to extensive ozone destruction, that, depending on plume dispersal, can be maintained for several days. The very high concentrations of sulfur dioxide in the volcanic plume reduces the lifetime of the OH radical drastically, so that it is virtually absent in the volcanic plume. This would imply an increased lifetime of methane in volcanic plumes, unless reactive chlorine chemistry in the plume is strong enough to offset the lack of OH chemistry. A further effect of bromine chemistry in addition to ozone destruction shown by the model studies presented here, is the oxidation of mercury. This relates to mercury that has been coemitted with bromine from the volcano but also to background atmospheric mercury. The rapid oxidation of mercury implies a drastically reduced atmospheric lifetime of mercury so that the contribution of volcanic mercury to the atmospheric background might be less than previously thought. However, the implications, especially health and environmental effects due to deposition, might be substantial and warrant further studies, especially field measurements to test this hypothesis.

Swirling plumes and spinning tops

NASA Astrophysics Data System (ADS)

Frank, Daria; Landel, Julien; Dalziel, Stuart; Linden, Paul

2017-11-01

Motivated by potential effects of the Earth's rotation on the dynamics of the oil plume resulting from the Deepwater Horizon disaster in 2010, we conducted laboratory experiments on saltwater and bubble axisymmetric point plumes in a homogeneous rotating environment. The effect of rotation is conventionally characterized by a Rossby number, based on the source buoyancy flux, the rotation rate of the system and the total water depth and which ranged from 0.02 to 1.3 in our experiments. In the range of parameters studied, we report a striking new physical instability in the plume dynamics near the source. After approximately one rotation period, the plume axis tilts away laterally from the centreline and the plume starts to precess in the anticyclonic direction. We find that the mean precession frequency of the plume scales linearly with the rotation rate of the environment. Surprisingly, the precession frequency is found to be independent of the diameter of the plume nozzle, the source buoyancy flux, the water depth and the geometry of the domain. In this talk, we present our experimental results and develop simple theoretical toy models to explain the observed plume behaviour.

Computational Modeling of Ablation on an Irradiated Target

NASA Astrophysics Data System (ADS)

Mehmedagic, Igbal; Thangam, Siva

2017-11-01

Computational modeling of pulsed nanosecond laser interaction with an irradiated metallic target is presented. The model formulation involves ablation of the metallic target irradiated by pulsed high intensity laser at normal atmospheric conditions. Computational findings based on effective representation and prediction of the heat transfer, melting and vaporization of the targeting material as well as plume formation and expansion are presented along with its relevance for the development of protective shields. In this context, the available results for a representative irradiation from 1064 nm laser pulse is used to analyze various ablation mechanisms, variable thermo-physical and optical properties, plume expansion and surface geometry. Funded in part by U. S. Army ARDEC, Picatinny Arsenal, NJ.

Femtosecond laser lithotripsy: feasibility and ablation mechanism.

PubMed

Qiu, Jinze; Teichman, Joel M H; Wang, Tianyi; Neev, Joseph; Glickman, Randolph D; Chan, Kin Foong; Milner, Thomas E

2010-01-01

Light emitted from a femtosecond laser is capable of plasma-induced ablation of various materials. We tested the feasibility of utilizing femtosecond-pulsed laser radiation (lambda=800 nm, 140 fs, 0.9 mJ/pulse) for ablation of urinary calculi. Ablation craters were observed in human calculi of greater than 90% calcium oxalate monohydrate (COM), cystine (CYST), or magnesium ammonium phosphate hexahydrate (MAPH). Largest crater volumes were achieved on CYST stones, among the most difficult stones to fragment using Holmium:YAG (Ho:YAG) lithotripsy. Diameter of debris was characterized using optical microscopy and found to be less than 20 microm, substantially smaller than that produced by long-pulsed Ho:YAG ablation. Stone retropulsion, monitored by a high-speed camera system with a spatial resolution of 15 microm, was negligible for stones with mass as small as 0.06 g. Peak shock wave pressures were less than 2 bars, measured by a polyvinylidene fluoride (PVDF) needle hydrophone. Ablation dynamics were visualized and characterized with pump-probe imaging and fast flash photography and correlated to shock wave pressures. Because femtosecond-pulsed laser ablates urinary calculi of soft and hard compositions, with micron-sized debris, negligible stone retropulsion, and small shock wave pressures, we conclude that the approach is a promising candidate technique for lithotripsy.

Nonequilibrium Ablation of Phenolic Impregnated Carbon Ablator

NASA Technical Reports Server (NTRS)

Milos, Frank S.; Chen, Yih K.; Gokcen, Tahir

2012-01-01

In previous work, an equilibrium ablation and thermal response model for Phenolic Impregnated Carbon Ablator was developed. In general, over a wide range of test conditions, model predictions compared well with arcjet data for surface recession, surface temperature, in-depth temperature at multiple thermocouples, and char depth. In this work, additional arcjet tests were conducted at stagnation conditions down to 40 W/sq cm and 1.6 kPa. The new data suggest that nonequilibrium effects become important for ablation predictions at heat flux or pressure below about 80 W/sq cm or 10 kPa, respectively. Modifications to the ablation model to account for nonequilibrium effects are investigated. Predictions of the equilibrium and nonequilibrium models are compared with the arcjet data.

Sonic and Supersonic Jet Plumes

NASA Technical Reports Server (NTRS)

Venkatapathy, E.; Naughton, J. W.; Flethcher, D. G.; Edwards, Thomas A. (Technical Monitor)

1994-01-01

Study of sonic and supersonic jet plumes are relevant to understanding such phenomenon as jet-noise, plume signatures, and rocket base-heating and radiation. Jet plumes are simple to simulate and yet, have complex flow structures such as Mach disks, triple points, shear-layers, barrel shocks, shock- shear- layer interaction, etc. Experimental and computational simulation of sonic and supersonic jet plumes have been performed for under- and over-expanded, axisymmetric plume conditions. The computational simulation compare very well with the experimental observations of schlieren pictures. Experimental data such as temperature measurements with hot-wire probes are yet to be measured and will be compared with computed values. Extensive analysis of the computational simulations presents a clear picture of how the complex flow structure develops and the conditions under which self-similar flow structures evolve. From the computations, the plume structure can be further classified into many sub-groups. In the proposed paper, detail results from the experimental and computational simulations for single, axisymmetric, under- and over-expanded, sonic and supersonic plumes will be compared and the fluid dynamic aspects of flow structures will be discussed.

Orbital Maneuvering Vehicle (OMV) plume and plume effects study

NASA Technical Reports Server (NTRS)

Smith, Sheldon D.

1991-01-01

The objective was to characterize the Orbital Maneuvering Vehicle (OMV) propulsion and attitude control system engine exhaust plumes and predict the resultant plume impingement pressure, heat loads, forces, and moments. Detailed description is provided of the OMV gaseous nitrogen (GN2) thruster exhaust plume flow field characteristics calculated with the RAMP2 snd SFPGEN computer codes. Brief descriptions are included of the two models, GN2 thruster characteristics and RAMP2 input data files. The RAMP2 flow field could be recalculated by other organizations using the information presented. The GN2 flow field can be readily used by other organizations who are interested in GN2 plume induced environments which require local flow field properties which can be supplied using the SFPGEN GN2 model.

Transgenic Reproductive Cell Ablation.

PubMed

Lawit, Shai J; Chamberlin, Mark A

2017-01-01

Numerous cell ablation technologies are available and have been used in reproductive tissues, particularly for male tissues and cells. The importance of ablation of reproductive tissues is toward a fundamental understanding reproductive tissue development and fertilization, as well as, in developing sterility lines important to breeding strategies. Here, we describe techniques for developing ablation lines for both male and female reproductive cells. Also discussed are techniques for analysis, quality control, maintenance, and the lessening of pleiotropism in such lines.

The Saturn hydrogen plume

NASA Astrophysics Data System (ADS)

Shemansky, D. E.; Liu, X.; Melin, H.

2009-12-01

Images of the Saturn atmosphere and magnetosphere in H Lyα emission during the Cassini spacecraft pre and post Saturn orbit insertion (SOI) event obtained using the UVIS experiment FUV spectrograph have revealed definitive evidence for the escape of H I atoms from the top of the thermosphere. An image at 0.1×0.1 Saturn equatorial radii ( RS) pixel resolution with an edge-on-view of the rings shows a distinctive structure (plume) with full width at half maximum (FWHM) of 0.56RS at the exobase sub-solar limb at ˜-13.5∘ latitude as part of the distributed outflow of H I from the sunlit hemisphere, with a counterpart on the antisolar side peaking near the equator above the exobase limb. The structure of the image indicates that part of the outflowing population is sub-orbital and re-enters the thermosphere in an approximate 5 h time scale. An evident larger more broadly distributed component fills the magnetosphere to beyond 45RS in the orbital plane in an asymmetric distribution in local time, similar to an image obtained at Voyager 1 post encounter in a different observational geometry. It has been found that H2 singlet ungerade Rydberg EUV/FUV emission spectra collected with the H Lyα into the image mosaic show a distinctive resonance property correlated with the H Lyα plume. The inferred approximate globally averaged energy deposition at the top of the thermosphere from the production of the hot atomic hydrogen accounts for the measured atmospheric temperature. The only known process capable of producing the atoms at the required few eV/atom kinetic energy appears to be the direct electron excitation of non-LTE H2XΣg+1( v:J) into the repulsive H2bΣu+3, although details of the processes need to be examined under the constraints imposed by the observations to determine compatibility with the current knowledge of hydrogen rate processes.

COMPARING AND LINKING PLUMES ACROSS MODELING APPROACHES

EPA Science Inventory

River plumes carry many pollutants, including microorganisms, into lakes and the coastal ocean. The physical scales of many stream and river plumes often lie between the scales for mixing zone plume models, such as the EPA Visual Plumes model, and larger-sized grid scales for re...

Ablative Thermal Protection System Fundamentals

NASA Technical Reports Server (NTRS)

Beck, Robin A. S.

2013-01-01

This is the presentation for a short course on the fundamentals of ablative thermal protection systems. It covers the definition of ablation, description of ablative materials, how they work, how to analyze them and how to model them.

Smoke plumes: Emissions and effects

Treesearch

Susan O' Neill; Shawn Urbanski; Scott Goodrick; Sim Larkin

2017-01-01

Smoke can manifest itself as a towering plume rising against the clear blue sky-or as a vast swath of thick haze, with fingers that settle into valleys overnight. It comes in many forms and colors, from fluffy and white to thick and black. Smoke plumes can rise high into the atmosphere and travel great distances across oceans and continents. Or smoke can remain close...

Development of a multi-variate calibration approach for quantitative analysis of oxidation resistant Mo-Si-B coatings using laser ablation inductively coupled plasma mass spectrometry

NASA Astrophysics Data System (ADS)

Cakara, Anja; Bonta, Maximilian; Riedl, Helmut; Mayrhofer, Paul H.; Limbeck, Andreas

2016-06-01

Nowadays, for the production of oxidation protection coatings in ultrahigh temperature environments, alloys of Mo-Si-B are employed. The properties of the material, mainly the oxidation resistance, are strongly influenced by the Si to B ratio; thus reliable analytical methods are needed to assure exact determination of the material composition for the respective applications. For analysis of such coatings, laser ablation inductively coupled mass spectrometry (LA-ICP-MS) has been reported as a versatile method with no specific requirements on the nature of the sample. However, matrix effects represent the main limitation of laser-based solid sampling techniques and usually the use of matrix-matched standards for quantitative analysis is required. In this work, LA-ICP-MS analysis of samples with known composition and varying Mo, Si and B content was carried out. Between known analyte concentrations and derived LA-ICP-MS signal intensities no linear correlation could be found. In order to allow quantitative analysis independent of matrix effects, a multiple linear regression model was developed. Besides the three target analytes also the signals of possible argides (40Ar36Ar and 98Mo40Ar) as well as detected impurities of the Mo-Si-B coatings (108Pd) were considered. Applicability of the model to unknown samples was confirmed using external validation. Relative deviations from the values determined using conventional liquid analysis after sample digestion between 5 and 10% for the main components Mo and Si were observed.

Exhaust Plume Measurements of the VASIMR VX-200

NASA Astrophysics Data System (ADS)

Longmier, Benjamin; Bering, Edgar, III; Squire, Jared; Glover, Tim; Chang-Diaz, Franklin; Brukardt, Michael

2008-11-01

Recent progress is discussed in the development of an advanced RF electric propulsion concept: the Variable Specific Impulse Magnetoplasma Rocket (VASIMR) VX-200 engine, a 200 kW flight-technology prototype. Results from high power Helicon only and Helicon with ICRH experiments are performed on the VX-200 using argon plasma. Recent measurements of axial plasma density and potential profiles, magnetic field-line shaping, charge exchange, and force measurements taken in the plume of the VX-200 exhaust are made within a new 125 cubic meter cryo-pumped vacuum chamber and are presented in the context of RF plasma thruster physics.

Stellar Ablation of Planetary Atmospheres

NASA Technical Reports Server (NTRS)

Moore, Thomas E.; Horwitz, J. L.

2007-01-01

We review observations and theories of the solar ablation of planetary atmospheres, focusing on the terrestrial case where a large magnetosphere holds off the solar wind, so that there is little direct atmospheric impact, but also couples the solar wind electromagnetically to the auroral zones. We consider the photothermal escape flows known as the polar wind or refilling flows, the enhanced mass flux escape flows that result from localized solar wind energy dissipation in the auroral zones, and the resultant enhanced neutral atom escape flows. We term these latter two escape flows the "auroral wind." We review observations and theories of the heating and acceleration of auroral winds, including energy inputs from precipitating particles, electromagnetic energy flux at magnetohydrodynamic and plasma wave frequencies, and acceleration by parallel electric fields and by convection pickup processes also known as "centrifugal acceleration." We consider also the global circulation of ionospheric plasmas within the magnetosphere, their participation in magnetospheric disturbances as absorbers of momentum and energy, and their ultimate loss from the magnetosphere into the downstream solar wind, loading reconnection processes that occur at high altitudes near the magnetospheric boundaries. We consider the role of planetary magnetization and the accumulating evidence of stellar ablation of extrasolar planetary atmospheres. Finally, we suggest and discuss future needs for both the theory and observation of the planetary ionospheres and their role in solar wind interactions, to achieve the generality required for a predictive science of the coupling of stellar and planetary atmospheres over the full range of possible conditions.

Laser Plasma Microthruster Performance Evaluation

NASA Astrophysics Data System (ADS)

Luke, James R.; Phipps, Claude R.

2003-05-01

The micro laser plasma thruster (μLPT) is a sub-kilogram thruster that is capable of meeting the Air Force requirements for the Attitude Control System on a 100-kg class small satellite. The μLPT uses one or more 4W diode lasers to ablate a solid fuel, producing a jet of hot gas or plasma which creates thrust with a high thrust/power ratio. A pre-prototype continuous thrust experiment has been constructed and tested. The continuous thrust experiment uses a 505 mm long continuous loop fuel tape, which consists of a black laser-absorbing fuel material on a transparent plastic substrate. When the laser is operated continuously, the exhaust plume and thrust vector are steered in the direction of the tape motion. Thrust steering can be avoided by pulsing the laser. A torsion pendulum thrust stand has been constructed and calibrated. Many fuel materials and substrates have been tested. Best performance from a non-energetic fuel material was obtained with black polyvinyl chloride (PVC), which produced an average of 70 μN thrust and coupling coefficient (Cm) of 190 μN/W. A proprietary energetic material was also tested, in which the laser initiates a non-propagating detonation. This material produced 500 μN of thrust.

Nanosecond laser-metal ablation at different ambient conditions

NASA Astrophysics Data System (ADS)

Elsied, Ahmed M.; Dieffenbach, Payson C.; Diwakar, Prasoon K.; Hassanein, Ahmed

2018-05-01

Ablation of metals under different ambient conditions and laser fluences, was investigated through series of experiments. A 1064 nm, 6 ns Nd:YAG laser was used to ablate 1 mm thick metal targets with laser energy ranging from 2 mJ to 300 mJ. The experiments were designed to study the effect of material properties, laser fluence, ambient gas, and ambient pressure on laser-metal ablation. The first experiment was conducted under vacuum to study the effect of laser fluence and material properties on metal ablation, using a wide range of laser fluences (2 J/cm2 up to 300 J/cm2) and two different targets, Al and W. The second experiment was conducted at atmospheric pressure using two different ambient gases air and argon, to understand the effect of ambient gas on laser-metal ablation process. The third experiment was conducted at two different pressures (10 Torr and 760 Torr) using the same ambient gas to investigate the effect of ambient pressure on laser-metal ablation. To compare the different ablation processes, the amount of mass ablated, ablation depth, crater profile and melt formation were measured using White Light Profilometer (WLP). The experimental results show that at low laser fluence: the ablated mass, ablation depth, and height of molten layer follow a logarithmic function of the incident laser fluence. While, at high laser fluence they follow a linear function. This dependence on laser fluence was found to be independent on ambient conditions and irradiated material. The effect of ambient pressure was more pronounced than the effect of ambient gas type. Plasma shielding effect was found to be very pronounced in the presence of ambient gas and led to significant reduction in the total mass ablation.

Ion energy distributions and densities in the plume of Enceladus

NASA Astrophysics Data System (ADS)

Sakai, Shotaro; Cravens, Thomas E.; Omidi, Nojan; Perry, Mark E.; Waite, J. Hunter

2016-10-01

Enceladus has a dynamic plume that is emitting gas, including water vapor, and dust. The gas is ionized by solar EUV radiation, charge exchange, and electron impact and extends throughout the inner magnetosphere of Saturn. The charge exchange collisions alter the plasma composition. Ice grains (dust) escape from the vicinity of Enceladus and form the E ring, including a portion that is negatively charged by the local plasma. The inner magnetosphere within 10 RS (Saturn radii) contains a complex mixture of plasma, neutral gas, and dust that links back to Enceladus. In this paper we investigate the energy distributions, ion species and densities of water group ions in the plume of Enceladus using test particle and Monte Carlo methods that include collisional processes such as charge exchange and ion-neutral chemical reactions. Ion observations from the Cassini Ion and Neutral Mass Spectrometer (INMS) for E07 are presented for the first time. We use the modeling results to interpret observations made by the Cassini Plasma Spectrometer (CAPS) and the INMS. The low energy ions, as observed by CAPS, appear to be affected by a vertical electric field (EZ=-10 μV/m) in the plume. The EZ field may be associated with the charged dust and/or the pressure gradient of plasma. The model results, along with the results of earlier models, show that H3O+ ions created by chemistry are predominant in the plume, which agrees with INMS and CAPS data, but the INMS count rate in the plume for the model is several times greater than the data, which we do not fully understand. This composition and the total ion count found in the plume agree with INMS and CAPS data. On the other hand, the Cassini Langmuir Probe measured a maximum plume ion density more than 30,000 cm-3, which is far larger than the maximum ion density from our model, 900 cm-3. The model results also demonstrate that most of the ions in the plume are from the external magnetospheric flow and are not generated by local

Numerical Simulation of Laser Ablative Shock Waves From Aluminum in Presence of Helium Gas At Different Ambient Pressures

NASA Astrophysics Data System (ADS)

Paturi, Prem Kiran; Durvasula, P. S. L. Kameswari; S, Sai Shiva; Acrhem, University Of Hyderabad Team

2017-06-01

A two dimensional comparative study of Laser Ablative Shock Wave into the Aluminum target in the presence of Helium gas at different ambient pressures over a range of 690 - 105 Pa performed using FLASH hydrodynamic codes will be presented. The irradiation of Aluminum target (thickness 2 mm and radius 3 mm) with a 7 ns laser pulse of energy 175 mJ, spot size of 150 µm on the target surface at a wavelength of 532 nm at normal incidence is simulated. Helium gas enclosed in a chamber of height 3 mm and width 3 mm. The electron-ion inverse bremsstrahlung absorption coefficient is considered in the laser energy deposition process. The simulation was performed over a duration of 1 μs. It was observed that an ablative shock is launched into the Helium gas for the pressures of 0.5 atm and above. However, for pressure less than the 0.5 atm the plasma expanded into the He gas upto 12ns and after which due to pressure equilibration with the surroundings and plume splitting shock wave is launched in to Al. Authors acknowledge funding from DRDO, India.

Sprayable lightweight ablative coating

NASA Technical Reports Server (NTRS)

Simpson, William G. (Inventor); Sharpe, Max H. (Inventor); Hill, William E. (Inventor)

1991-01-01

An improved lightweight, ablative coating is disclosed that may be spray applied and cured without the development of appreciable shrinkage cracks. The ablative mixture consists essentially of phenolic microballoons, hollow glass spheres, glass fibers, ground cork, a flexibilized resin binder, and an activated colloidal clay.

Active Volcanic Plumes on Io

NASA Technical Reports Server (NTRS)

1997-01-01

This color image, acquired during Galileo's ninth orbit around Jupiter, shows two volcanic plumes on Io. One plume was captured on the bright limb or edge of the moon (see inset at upper right), erupting over a caldera (volcanic depression) named Pillan Patera after a South American god of thunder, fire and volcanoes. The plume seen by Galileo is 140 kilometers (86 miles) high and was also detected by the Hubble Space Telescope. The Galileo spacecraft will pass almost directly over Pillan Patera in 1999 at a range of only 600 kilometers (373 miles).

The second plume, seen near the terminator (boundary between day and night), is called Prometheus after the Greek fire god (see inset at lower right). The shadow of the 75-kilometer (45- mile) high airborne plume can be seen extending to the right of the eruption vent. The vent is near the center of the bright and dark rings. Plumes on Io have a blue color, so the plume shadow is reddish. The Prometheus plume can be seen in every Galileo image with the appropriate geometry, as well as every such Voyager image acquired in 1979. It is possible that this plume has been continuously active for more than 18 years. In contrast, a plume has never been seen at Pillan Patera prior to the recent Galileo and Hubble Space Telescope images.

North is toward the top of the picture. The resolution is about 6 kilometers (3.7 miles) per picture element. This composite uses images taken with the green, violet and near infrared filters of the solid state imaging (CCD) system on NASA's Galileo spacecraft. The images were obtained on June 28, 1997, at a range of more than 600,000 kilometers (372,000 miles).

The Jet Propulsion Laboratory, Pasadena, CA manages the Galileo mission for NASA's Office of Space Science, Washington, DC. JPL is an operating division of California Institute of Technology (Caltech).

This image and other images and data received from Galileo are posted on the World Wide Web, on the Galileo mission home page

Application of 1013 ohm Faraday cup current amplifiers for boron isotopic analyses by solution mode and laser ablation multicollector inductively coupled plasma mass spectrometry.

PubMed

Lloyd, Nicholas S; Sadekov, Aleksey Yu; Misra, Sambuddha

2018-01-15

Boron isotope ratios (δ 11 B values) are used as a proxy for seawater paleo-pH, amongst several other applications. The analytical precision can be limited by the detection of low intensity ion beams from limited sample amounts. High-gain amplifiers offer improvements in signal/noise ratio and can be used to increase measurement precision and reduce sample amounts. 10 13 ohm amplifier technology has previously been applied to several radiogenic systems, but has thus far not been applied to non-traditional stable isotopes. Here we apply 10 13 ohm amplifier technology for the measurement of boron isotope ratios using solution mode MC-ICP-MS and laser ablation mode (LA-)MC-ICP-MS techniques. Precision is shown for reference materials as well as for low-volume foraminifera samples. The baseline uncertainty for a 0.1 pA 10 B + ion beam is reduced to <0.1 ‰ for a typical measurement period. The external precision is better than 0.2 ‰ (2SD) for δ 11 B measurements for solution samples containing as little as 0.8 ng total boron. For in situ microanalyses with LA-MC-ICP-MS, the external precision of 11 B/ 10 B from an in-house calcite standard was 1 ‰ (2SD) for individual spot analyses, and 0.3 ‰ for the mean of ≥10 replicate spot analyses. 10 13 ohm amplifier technology is demonstrated to offer advantages for the determination of δ 11 B values by both MC-ICP-MS and LA-MC-ICP-MS for small samples of biogenic carbonates, such as foraminifera shells. 10 13 ohm amplifier technology will also be of benefit to other non-traditional stable isotope measurements. Copyright © 2017 John Wiley & Sons, Ltd.

Classical and Ablative Richtmyer-Meshkov Instability and Other ICF-Relevant Plasma Flows Diagnosed With Monochromatic X-Ray Imaging

DTIC Science & Technology

2007-08-01

5] Our experiments on the 3 kJ Nike KrF laser at NRL [6] seek detailed understanding of laser plasma interactions and the physical processes...Research Laboratory (NRL). It has been first used in our ICF-related hydrodynamic experiments on the NRL’s Nike KrF laser [17], and later implemented...as implemented on Nike . In Section 3 we present some results of our hydrodynamic experiments, which have been made possible by this diagnostics. In

Can the Plasmaspheric Plume Significantly Contribute to Magnetosheath Densities?

NASA Technical Reports Server (NTRS)

Gallagher, Dennis; Goldstein, Jerry; Sibeck, David

2010-01-01

Intervals of strong magnetospheric convection electric fields can result in the removal of large portions of the outer plasmasphere and its transport to the vicinity of the magnetopause. Of growing interest is the disposition of that plasma and its possible influence on the processes operating in the regions contributed to by this dense thermal plasma of ionospheric origin. Plasmaspheric plasma may recirculate within the outer magnetosphere through the flanks to become part of the plasmasheet, be entrained on reconnected magnetic field lines drawn anti-sunward over the polar cap, or be lost into the magnetosheath flow and into the solar wind. Of interest here is whether it is reasonable to anticipate that the plume material is sufficient to contribute substantially to magnetosheath densities at the magnetopause where it could influence reconnection between the interplanetary and terrestrial magnetic fields. We present the results of model simulations of plasmaspheric plume and magnetosheath plasmas in the context of several storm-time event periods. Plume and magnetosheath densities are compared as a function of location and storm phase. The short answer is, "yes", but not always and not at all locations. The full answer will be presented.

The growth and decay of equatorial backscatter plumes

NASA Astrophysics Data System (ADS)

Tsunoda, R. T.

1980-02-01

During the past three years, a series of rocket experiments from the Kwajalein Atoll, Marshall Islands, were conducted to investigate the character of intense, scintillation-producing irregularities that occur in the nighttime equatorial ionosphere. Because the source mechanism of equatorial irregularities, believed to be the Rayleigh-Taylor instability, is analogous to that which generates plasma-density striations in a nuclear-induced environment, there is considerable interest in the underlying physics that controls the characteristics of these irregularities. A primary objective of ALTAIR investigations of equatorial irregularities is to seek an understanding of the underlying physics by establishing the relationship between meter-scale irregularities (detected by ALTAIR), and the large-scale plasma-density depletions (or 'bubbles') that contain the kilometer-scale, scintillation-producing irregularities. We describe the time evolution of backscatter 'plumes' produced by one meter equatorial field-aligned irregularities. Using ALTAIR, a fully steerable backscatter radar, to repeatedly map selected plumes, we characterize the dynamic behavior of plumes in terms of growth and a decay phase. Most of the observed characteristics are found to be consistent with equatorial-irregularity generation predicted by current theories of Rayleigh-Taylor and gradient-drift instabilities. However, other characteristics have been found that suggest key roles played by the eastward neutral wind and by altitude-modulation of the bottomside F layer in establishing the initial conditions for plume growth.

Charge dependence of the plasma travel length in atmospheric-pressure plasma

SciTech Connect

Yambe, Kiyoyuki; Konda, Kohmei; Masuda, Seiya

Plasma plume is generated using a quartz tube, helium gas, and foil electrode by applying AC high voltage under the atmosphere. The plasma plume is released into the atmosphere from inside of the quartz tube and is seen as the continuous movement of the plasma bullet. The travel length of plasma bullet is defined from plasma energy and force due to electric field. The drift velocity of plasma bullet has the upper limit under atmospheric-pressure because the drift velocity is determined from the balance between electric field and resistive force due to collisions between plasma and air. The plasma plumemore » charge depends on the drift velocity. Consequently, in the laminar flow of helium gas flow state, the travel length of the plasma plume logarithmically depends on the plasma plume charge which changes with both the electric field and the resistive force.« less

A comparison of laser ablation-inductively coupled plasma-mass spectrometry and high-resolution continuum source graphite furnace molecular absorption spectrometry for the direct determination of bromine in polymers

NASA Astrophysics Data System (ADS)

de Gois, Jefferson S.; Van Malderen, Stijn J. M.; Cadorim, Heloisa R.; Welz, Bernhard; Vanhaecke, Frank

2017-06-01

This work describes the development and comparison of two methods for the direct determination of Br in polymer samples via solid sampling, one using laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) and the other using high-resolution continuum source graphite furnace molecular absorption spectrometry with direct solid sample analysis (HR-CS SS-GF MAS). The methods were optimized and their accuracy was evaluated by comparing the results obtained for 6 polymeric certified reference materials (CRMs) with the corresponding certified values. For Br determination with LA-ICP-MS, the 79Br+ signal could be monitored interference-free. For Br determination via HR-CS SS-GF MAS, the CaBr molecule was monitored at 625.315 nm with integration of the central pixel ± 1. Bromine quantification by LA-ICP-MS was performed via external calibration against a single CRM while using the 12C+ signal as an internal standard. With HR-CS SS-GF MAS, Br quantification could be accomplished using external calibration against aqueous standard solutions. Except for one LA-ICP-MS result, the concentrations obtained with both techniques were in agreement with the certified values within the experimental uncertainty as evidenced using a t-test (95% confidence level). The limit of quantification was determined to be 100 μg g- 1 Br for LA-ICP-MS and 10 μg g- 1 Br for HR-CS SS-GF MAS.

Analysis of metal-binding proteins separated by non-denaturating gel electrophoresis using matrix-assisted laser desorption/ionization mass spectrometry (MALDI-MS) and laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS).

PubMed

Becker, J Susanne; Mounicou, Sandra; Zoriy, Miroslav V; Becker, J Sabine; Lobinski, Ryszard

2008-09-15

Matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-TOF-MS) and laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) have become established as very efficient and sensitive biopolymer and elemental mass spectrometric techniques for studying metal-binding proteins (metalloproteins) in life sciences. Protein complexes present in rat tissues (liver and kidney) were separated in their native state in the first dimension by blue native gel electrophoresis (BN-PAGE). Essential and toxic metals, such as zinc, copper, iron, nickel, chromium, cadmium and lead, were detected by scanning the gel bands using quadrupole LA-ICP-MS with and without collision cell as a microanalytical technique. Several proteins were identified by using MALDI-TOF-MS together with a database search. For example, on one protein band cut from the BN-PAGE gel and digested with the enzyme trypsin, two different proteins - protein FAM44B and cathepsin B precursor - were identified. By combining biomolecular and elemental mass spectrometry, it was possible to characterize and identify selected metal-binding rat liver and kidney tissue proteins.

Fourier Transform Infrared (FT-IR) and Laser Ablation Inductively Coupled Plasma-Mass Spectrometry (LA-ICP-MS) Imaging of Cerebral Ischemia: Combined Analysis of Rat Brain Thin Cuts Toward Improved Tissue Classification.

PubMed

Balbekova, Anna; Lohninger, Hans; van Tilborg, Geralda A F; Dijkhuizen, Rick M; Bonta, Maximilian; Limbeck, Andreas; Lendl, Bernhard; Al-Saad, Khalid A; Ali, Mohamed; Celikic, Minja; Ofner, Johannes

2018-02-01

Microspectroscopic techniques are widely used to complement histological studies. Due to recent developments in the field of chemical imaging, combined chemical analysis has become attractive. This technique facilitates a deepened analysis compared to single techniques or side-by-side analysis. In this study, rat brains harvested one week after induction of photothrombotic stroke were investigated. Adjacent thin cuts from rats' brains were imaged using Fourier transform infrared (FT-IR) microspectroscopy and laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS). The LA-ICP-MS data were normalized using an internal standard (a thin gold layer). The acquired hyperspectral data cubes were fused and subjected to multivariate analysis. Brain regions affected by stroke as well as unaffected gray and white matter were identified and classified using a model based on either partial least squares discriminant analysis (PLS-DA) or random decision forest (RDF) algorithms. The RDF algorithm demonstrated the best results for classification. Improved classification was observed in the case of fused data in comparison to individual data sets (either FT-IR or LA-ICP-MS). Variable importance analysis demonstrated that both molecular and elemental content contribute to the improved RDF classification. Univariate spectral analysis identified biochemical properties of the assigned tissue types. Classification of multisensor hyperspectral data sets using an RDF algorithm allows access to a novel and in-depth understanding of biochemical processes and solid chemical allocation of different brain regions.

Mass Spectrometric Imaging Using Laser Ablation and Solvent Capture by Aspiration (LASCA)

NASA Astrophysics Data System (ADS)

Brauer, Jonathan I.; Beech, Iwona B.; Sunner, Jan

2015-09-01

A novel interface for ambient, laser ablation-based mass spectrometric imaging (MSI) referred to as laser ablation and solvent capture by aspiration (LASCA) is presented and its performance demonstrated using selected, unaltered biological materials. LASCA employs a pulsed 2.94 μm laser beam for specimen ablation. Ablated materials in the laser plumes are collected on a hanging solvent droplet with electric field-enhanced trapping, followed by aspiration of droplets and remaining plume material in the form of a coarse aerosol into a collection capillary. The gas and liquid phases are subsequently separated in a 10 μL-volume separatory funnel, and the solution is analyzed with electrospray ionization in a high mass resolution Q-ToF mass spectrometer. The LASCA system separates the sampling and ionization steps in MSI and combines high efficiencies of laser plume sampling and of electrospray ionization (ESI) with high mass resolution MS. Up to 2000 different compounds are detected from a single ablation spot (pixel). Using the LASCA platform, rapid (6 s per pixel), high sensitivity, high mass-resolution ambient imaging of "as-received" biological material is achieved routinely and reproducibly.

Morphology and characteristics of laser-induced aluminum plasma in argon and in air: A comparative study

NASA Astrophysics Data System (ADS)

Bai, Xueshi; Cao, Fan; Motto-Ros, Vincent; Ma, Qianli; Chen, Yanping; Yu, Jin

2015-11-01

In laser-induced breakdown spectroscopy (LIBS), ablation takes place in general in an ambient gas of the atmospheric pressure, often in air but also in noble gas such as argon or helium. The use of noble gas is known to significantly improve the performance of the technique. We investigate in this work the morphology and the characteristics of induced plasma in argon and in air. The purpose is to understand the mechanism of the analytical performance improvement by the use of argon ambient with respective to air ambient and the dependence on the other experimental parameters such as the laser fluence. The observation of plasma morphology in different ambient gases provides also information for better design of the detection system which optimizes the signal collection according to the used ambient gases. More specifically, the expansion of the plasma induced on an aluminum target with nanosecond infrared (1064 nm) laser pulse in two ambient gases, argon and the atmospheric air, has been studied with spectroscopic imaging at short delays and with emission spectroscopy at longer delays. With relatively low ablation laser fluence (65 J/cm2), similar morphologies have been observed in argon and in air over the early stage of plasma expansion, while diagnostics at longer delay shows stronger emission, higher electron density and temperature for plasma induced in argon. With higher ablation laser fluence (160 J/cm2) however, different expansion behaviors have been observed, with a stagnating aluminum vapor near the target surface in air while a propagating plume away from the target in argon. The craters left on the target surface show as well corresponding difference: in air, the crater is very shallow with a target surface chaotically affected by the laser pulse, indicating an effective re-deposition of the ablated material back to the crater; while in Ar a deeper crater is observed, indicating an efficient mass removal by laser ablation. At longer delays, a brighter

Double-pulse femtosecond laser peening of aluminum alloy AA5038: Effect of inter-pulse delay on transient optical plume emission and final surface micro-hardness