Science.gov

Sample records for above-cloud precipitable water

  1. Above-Cloud Precipitable Water Retrievals using the MODIS 0.94 micron Band with Applications for Multi-Layer Cloud Detection

    NASA Technical Reports Server (NTRS)

    Platnick, S.; Wind, G.

    2004-01-01

    In order to perform satellite retrievals of cloud properties, it is important to account for the effect of the above-cloud atmosphere on the observations. The solar bands used in the operational MODIS Terra and Aqua cloud optical and microphysical algorithms (visible, NIR, and SWIR spectral windows) are primarily affected by water vapor, and to a lesser extent by well-mixed gases. For water vapor, the above-cloud column amount, or precipitable water, provides adequate information for an atmospheric correction; details of the vertical vapor distribution are not typically necessary for the level of correction required. Cloud-top pressure has a secondary effect due to pressure broadening influences. For well- mixed gases, cloud-top pressure is also required for estimates of above-cloud abundances. We present a method for obtaining above-cloud precipitable water over dark Ocean surfaces using the MODIS 0.94 pm vapor absorption band. The retrieval includes an iterative procedure for establishing cloud-top temperature and pressure, and is useful for both single layer water and ice clouds. Knowledge of cloud thermodynamic phase is fundamental in retrieving cloud optical and microphysical properties. However, in cases of optically thin cirrus overlapping lower water clouds, the concept of a single unique phase is ill- defined and depends, at least, on the spectral region of interest. We will present a method for multi-layer and multi-phase cloud detection which uses above-cloud precipitable water retrievals along with several existing MODIS operational cloud products (cloud-top pressure derived from a C02 slicing algorithm, IR and SWIR phase retrievals). Results are catagorized by whether the radiative signature in the MODIS solar bands is primarily that of a water cloud with ice cloud contamination, or visa-versa. Examples in polar and mid-latitude regions will be shown.

  2. Global Analysis of Aerosol Properties Above Clouds

    NASA Technical Reports Server (NTRS)

    Waquet, F.; Peers, F.; Ducos, F.; Goloub, P.; Platnick, S. E.; Riedi, J.; Tanre, D.; Thieuleux, F.

    2013-01-01

    The seasonal and spatial varability of Aerosol Above Cloud (AAC) properties are derived from passive satellite data for the year 2008. A significant amount of aerosols are transported above liquid water clouds on the global scale. For particles in the fine mode (i.e., radius smaller than 0.3 m), including both clear sky and AAC retrievals increases the global mean aerosol optical thickness by 25(+/- 6%). The two main regions with man-made AAC are the tropical Southeast Atlantic, for biomass burning aerosols, and the North Pacific, mainly for pollutants. Man-made AAC are also detected over the Arctic during the spring. Mineral dust particles are detected above clouds within the so-called dust belt region (5-40 N). AAC may cause a warming effect and bias the retrieval of the cloud properties. This study will then help to better quantify the impacts of aerosols on clouds and climate.

  3. Global estimation of above-cloud aerosols using spaceborne LIDAR

    NASA Astrophysics Data System (ADS)

    Chand, D.; Wood, R.; Anderson, T. L.; Satheesh, S. K.; Leahy, L.

    2008-12-01

    Estimates of global mean direct climate forcing by absorbing aerosols located above boundary layer clouds are large, uncertain, and almost entirely unconstrained by observations. Spaceborne lidar offers a new opportunity of estimating the aerosols at global scale. Here we use two recently available techniques quantifying the above-cloud aerosols using liquid water clouds as lidar targets from Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations (CALIPSO) [Chand et al., 2008]. Both methods can quantify aerosols above clouds and are based on their self-calibrating techniques. We used one year of global data between 70N-70S to show that day time calibration constants are different than night time calibrations constants. A clear latitudinal dependence is observed in the calibrations constants in CALIPSO observations. Using these 'self-calibration' constants, aerosol optical depth (AOD) and angstrom exponent (AE) of 'above- cloud' aerosols are quantified. Biomass burning is a major source of fine mode aerosols in different regions of world. For example, it is observed that June is the onset of the biomass burning fires in Southern Africa, peaking in August and September and then slowly decreasing until November, with a corresponding signature in aerosol optical depth. Layers with aerosol optical depth greater than 0.3 are commonly observed up to several thousand kilometers away from Africa over the Atlantic Ocean. The 'above-cloud' AOD as high as 1.5 is observed in the peak months. Despite of large variations is AOD, mean AE of these aerosols is about 1.6, without any systematic variability away from the source region. The results estimating the aerosols above clouds, including other regions at global scale, will be presented in the AGU meeting. Chand, D., T. L. Anderson, R. Wood, R. J. Charlson, Y. Hu, Z. Liu, and M. Vaughan (2008), Quantifying above-cloud aerosol using spaceborne lidar for improved understanding of cloudy-sky direct climate forcing, J

  4. On the source of organic acid aerosol layers above clouds.

    PubMed

    Sorooshian, Armin; Lu, Miao-Ling; Brechtel, Fred J; Jonsson, Haflidi; Feingold, Graham; Flagan, Richard C; Seinfeld, John H

    2007-07-01

    During the July 2005 Marine Stratus/Stratocumulus Experiment (MASE) and the August-September 2006 Gulf of Mexico Atmospheric Composition and Climate Study (GoMACCS), the Center for Interdisciplinary Remotely-Piloted Aircraft Studies (CIRPAS) Twin Otter probed aerosols and cumulus clouds in the eastern Pacific Ocean off the coast of northern California and in southeastern Texas, respectively. An on-board particle-into-liquid sampler (PILS) quantified inorganic and organic acid species with < or = 5-min time resolution. Ubiquitous organic aerosol layers above cloud with enhanced organic acid levels were observed in both locations. The data suggest that aqueous-phase reactions to produce organic acids, mainly oxalic acid, followed by droplet evaporation is a source of elevated organic acid aerosol levels above cloud. Oxalic acid is observed to be produced more efficiently relative to sulfate as the cloud liquid water content increases, corresponding to larger and less acidic droplets. As derived from large eddy simulations of stratocumulus underthe conditions of MASE, both Lagrangian trajectory analysis and diurnal cloudtop evolution provide evidence that a significant fraction of the aerosol mass concentration above cloud can be accounted for by evaporated droplet residual particles. Methanesulfonate data suggest that entrainment of free tropospheric aerosol can also be a source of organic acids above boundary layer clouds.

  5. Total Precipitable Water

    SciTech Connect

    2012-01-01

    The simulation was performed on 64K cores of Intrepid, running at 0.25 simulated-years-per-day and taking 25 million core-hours. This is the first simulation using both the CAM5 physics and the highly scalable spectral element dynamical core. The animation of Total Precipitable Water clearly shows hurricanes developing in the Atlantic and Pacific.

  6. WEATHER_Layered-Precipitable-Water

    Atmospheric Science Data Center

    2016-06-23

    ... TOVS (HIRS) clear sky radiances Radiosonde GPS (after 1995) AIRS Level 2 TPW and Layered PW Spatial ... Parameters:  Precipitable Water Order Data:  Earthdata Search:  Earthdata Search SCAR-B ...

  7. WEATHER_Total-Precipitable-Water

    Atmospheric Science Data Center

    2016-06-23

    ... TOVS (HIRS) clear sky radiances Radiosonde GPS (after 1995) AIRS Level 2 TPW and Layered PW Spatial ... Parameters:  Precipitable Water Order Data:  Earthdata Search:  Earthdata Search SCAR-B ...

  8. Quantifying Above-Cloud Aerosols through Integrating Multi-Sensor Measurements from A-Train Satellites

    NASA Technical Reports Server (NTRS)

    Zhang, Yan

    2012-01-01

    Quantifying above-cloud aerosols can help improve the assessment of aerosol intercontinental transport and climate impacts. Large-scale measurements of aerosol above low-level clouds had been generally unexplored until very recently when CALIPSO lidar started to acquire aerosol and cloud profiles in June 2006. Despite CALIPSO s unique capability of measuring above-cloud aerosol optical depth (AOD), such observations are substantially limited in spatial coverage because of the lidar s near-zero swath. We developed an approach that integrates measurements from A-Train satellite sensors (including CALIPSO lidar, OMI, and MODIS) to extend CALIPSO above-cloud AOD observations to substantially larger areas. We first examine relationships between collocated CALIPSO above-cloud AOD and OMI absorbing aerosol index (AI, a qualitative measure of AOD for elevated dust and smoke aerosol) as a function of MODIS cloud optical depth (COD) by using 8-month data in the Saharan dust outflow and southwest African smoke outflow regions. The analysis shows that for a given cloud albedo, above-cloud AOD correlates positively with AI in a linear manner. We then apply the derived relationships with MODIS COD and OMI AI measurements to derive above-cloud AOD over the whole outflow regions. In this talk, we will present spatial and day-to-day variations of the above-cloud AOD and the estimated direct radiative forcing by the above-cloud aerosols.

  9. Layer Precipitable Water (LPW) Briefing

    NASA Technical Reports Server (NTRS)

    Forsythe, John; Kidder, Stan; Fuell, Kevin; LeRoy, Anita

    2013-01-01

    Microwave Integrated Retrieval System (MIRS) provides soundings of specific humidity from a variety of instruments and is combined with AIRS infrared soundings to create a Layered Precipitable Water (LPW) composite product. The LPW provides vertical moisture information in the column instead of just upper levels via WV imagery, or a single column value via TPW products. LPW is created every 3 hours using the last 12 hours worth of data and has a delivery latency of 40 minutes. Weaknesses include discontinuities in the composite. Strengths include seeing through clouds, over land usage, and greater spatial coverage of vertical moisture profiles. Applications of LPW include analysis of horizontal and vertical moisture gradients, verification of NWP moisture, and analysis of atmospheric rivers and other moisture advection. Operational testbed is ongoing to determine viability of wider distribution.

  10. Measurement-based estimates of direct radiative effects of absorbing aerosols above clouds

    NASA Astrophysics Data System (ADS)

    Feng, Nan; Christopher, Sundar A.

    2015-07-01

    The elevated layers of absorbing smoke aerosols from western African (e.g., Gabon and Congo) biomass burning activities have been frequently observed above low-level stratocumulus clouds off the African coast, which presents an excellent natural laboratory for studying the effects of aerosols above clouds (AAC) on regional energy balance in tropical and subtropical environments. Using spatially and temporally collocated Moderate Resolution Imaging Spectroradiometer, Ozone Monitoring Instrument (OMI), and Clouds and the Earth's Radiant Energy System data sets, the top-of-atmosphere shortwave aerosol direct shortwave radiative effects (ARE) of absorbing aerosols above low-level water clouds in the southeast Atlantic Ocean was examined in this study. The regional averaged instantaneous ARE has been estimated to be 36.7 ± 20.5 Wm-2 (regional mean ± standard deviation) along with a mean positive OMI Aerosol Index at 1.3 in August 2006 based on multisensors measurements. The highest magnitude of instantaneous ARE can even reach 138.2 Wm-2. We assess that the 660 nm cloud optical depth (COD) values of 8-12 is the critical value above (below) which aerosol absorption (scattering) effect dominates and further produces positive (negative) ARE values. The results further show that ARE values are more sensitive to aerosols above lower COD values than cases for higher COD values. This is among the first studies to provide quantitative estimates of shortwave ARE due to AAC events from an observational perspective.

  11. Using OMI Observations to Measure Aerosol Absorption of Biomass Burning Aerosols Above Clouds

    NASA Technical Reports Server (NTRS)

    Torres, Omar; Bhartia, P. K.; Jethva, Hiren

    2011-01-01

    The presence of absorbing aerosol layers above clouds is unambiguously detected by the TOMS/OMI UV Aerosol Index (AI) that uses satellite observations at two near-UV channels. A sensitivity study using radiative transfer calculations shows that the AI signal of resulting from the presence of aerosols above clouds is mainly driven by the aerosol absorption optical depth and the optical depth of the underlying cloud. Based on these results, an inversion algorithm has been developed to retrieve the aerosol optical depth (AOD) of aerosol layers above clouds. In this presentation we will discuss the sensitivity analysis, describe the retrieval approach, and present results of applications of the retrieval method to OMI observations over the South Atlantic Ocean. Preliminary error analyses, to be discussed, indicate that the AOD can be underestimated (up to -30%) or overestimated (up to 60%) depending on algorithmic assumptions.

  12. New Directions: Emerging Satellite Observations of Above-cloud Aerosols and Direct Radiative Forcing

    NASA Technical Reports Server (NTRS)

    Yu, Hongbin; Zhang, Zhibo

    2013-01-01

    Spaceborne lidar and passive sensors with multi-wavelength and polarization capabilities onboard the A-Train provide unprecedented opportunities of observing above-cloud aerosols and direct radiative forcing. Significant progress has been made in recent years in exploring these new aerosol remote sensing capabilities and generating unique datasets. The emerging observations will advance the understanding of aerosol climate forcing.

  13. Retrieval of Aerosol Optical Depth Above Clouds from OMI Observations: Sensitivity Analysis, Case Studies

    NASA Technical Reports Server (NTRS)

    Torres, O.; Jethva, H.; Bhartia, P. K.

    2012-01-01

    A large fraction of the atmospheric aerosol load reaching the free troposphere is frequently located above low clouds. Most commonly observed aerosols above clouds are carbonaceous particles generally associated with biomass burning and boreal forest fires, and mineral aerosols originated in arid and semi-arid regions and transported across large distances, often above clouds. Because these aerosols absorb solar radiation, their role in the radiative transfer balance of the earth atmosphere system is especially important. The generally negative (cooling) top of the atmosphere direct effect of absorbing aerosols, may turn into warming when the light-absorbing particles are located above clouds. The actual effect depends on the aerosol load and the single scattering albedo, and on the geometric cloud fraction. In spite of its potential significance, the role of aerosols above clouds is not adequately accounted for in the assessment of aerosol radiative forcing effects due to the lack of measurements. In this paper we discuss the basis of a simple technique that uses near-UV observations to simultaneously derive the optical depth of both the aerosol layer and the underlying cloud for overcast conditions. The two-parameter retrieval method described here makes use of the UV aerosol index and reflectance measurements at 388 nm. A detailed sensitivity analysis indicates that the measured radiances depend mainly on the aerosol absorption exponent and aerosol-cloud separation. The technique was applied to above-cloud aerosol events over the Southern Atlantic Ocean yielding realistic results as indicated by indirect evaluation methods. An error analysis indicates that for typical overcast cloudy conditions and aerosol loads, the aerosol optical depth can be retrieved with an accuracy of approximately 54% whereas the cloud optical depth can be derived within 17% of the true value.

  14. Solubilization of phenanthrene above cloud point of Brij 30: a new application in biodegradation.

    PubMed

    Pantsyrnaya, T; Delaunay, S; Goergen, J L; Guseva, E; Boudrant, J

    2013-06-01

    In the present study a new application of solubilization of phenanthrene above cloud point of Brij 30 in biodegradation was developed. It was shown that a temporal solubilization of phenanthrene above cloud point of Brij 30 (5wt%) permitted to obtain a stable increase of the solubility of phenanthrene even when the temperature was decreased to culture conditions of used microorganism Pseudomonas putida (28°C). A higher initial concentration of soluble phenanthrene was obtained after the cloud point treatment: 200 against 120μM without treatment. All soluble phenanthrene was metabolized and a higher final concentration of its major metabolite - 1-hydroxy-2-naphthoic acid - (160 against 85μM) was measured in the culture medium in the case of a preliminary cloud point treatment. Therefore a temporary solubilization at cloud point might have a perspective application in the enhancement of biodegradation of polycyclic aromatic hydrocarbons.

  15. CALCULATION: PRECIPITATION CHARACTERISITICS FOR STORM WATER MANAGEMENT

    SciTech Connect

    D. Ambos

    2000-08-14

    This Calculation is intended to satisfy engineering requirements for maximum 60-minute precipitation amounts for 50 and 100-year return periods at and near Yucca Mountain. This data requirement is documented in the ''Interface Control Document for Support Operations to Surface Facilities Operations Functional and Organizational Interfaces'' (CRWMS M&O 1998a). These developed data will supplement the information on 0.1 hour to 6-hour (in 0.1-hour increments) probable maximum precipitation (PMP) presented in the report, ''Precipitation Design Criteria for Storm Water Management'' (CRWMS M&O 1998b). The Reference Information Base (RIB) item, Precipitation ''Characteristics for Storm Water Management'' (M09902RIB00045 .OOO), was developed based on CRWMS M&O (1998b) and will be supplemented (via revision) with the information developed in this Calculation. The ''Development Plan for the Calculation: Precipitation Characteristics for Storm Water Management'' (CRWMS M&O 2000) was prepared in accordance with AP-2.l3Q, ''Technical Product Development Planning''. This calculation was developed in accordance with AP-3.12Q, Rev. O/ICN 2.

  16. Mars water-ice clouds and precipitation.

    PubMed

    Whiteway, J A; Komguem, L; Dickinson, C; Cook, C; Illnicki, M; Seabrook, J; Popovici, V; Duck, T J; Davy, R; Taylor, P A; Pathak, J; Fisher, D; Carswell, A I; Daly, M; Hipkin, V; Zent, A P; Hecht, M H; Wood, S E; Tamppari, L K; Renno, N; Moores, J E; Lemmon, M T; Daerden, F; Smith, P H

    2009-07-03

    The light detection and ranging instrument on the Phoenix mission observed water-ice clouds in the atmosphere of Mars that were similar to cirrus clouds on Earth. Fall streaks in the cloud structure traced the precipitation of ice crystals toward the ground. Measurements of atmospheric dust indicated that the planetary boundary layer (PBL) on Mars was well mixed, up to heights of around 4 kilometers, by the summer daytime turbulence and convection. The water-ice clouds were detected at the top of the PBL and near the ground each night in late summer after the air temperature started decreasing. The interpretation is that water vapor mixed upward by daytime turbulence and convection forms ice crystal clouds at night that precipitate back toward the surface.

  17. Extending 'Deep Blue' aerosol retrieval coverage to cases of absorbing aerosols above clouds: sensitivity analysis and first case studies

    SciTech Connect

    Sayer, Andrew M.; Hsu, C.; Bettenhausen, Corey; Lee, Jae N.; Redemann, Jens; Schmid, Beat; Shinozuka, Yohei

    2016-05-07

    Cases of absorbing aerosols above clouds (AAC), such as smoke or mineral dust, are omitted from most routinely-processed space-based aerosol optical depth (AOD) data products, including those from the Moderate Resolution Imaging Spectroradiometer (MODIS). This study presents a sensitivity analysis and preliminary algorithm to retrieve above-cloud AOD and liquid cloud optical depth (COD) for AAC cases from MODIS or similar

  18. Extending MODIS Deep Blue Aerosol Retrieval Coverage to Cases of Absorbing Aerosols Above Clouds: First Results

    NASA Technical Reports Server (NTRS)

    Sayer, A. M.; Hsu, N. C.; Bettenhausen, C.; Lee, J.; Redemann, J.; Shinozuka, Y.; Schmid, B.

    2015-01-01

    Absorbing smoke or mineral dust aerosols above clouds (AAC) are a frequent occurrence in certain regions and seasons. Operational aerosol retrievals from sensors like MODIS omit AAC because they are designed to work only over cloud-free scenes. However, AAC can in principle be quantified by these sensors in some situations (e.g. Jethva et al., 2013; Meyer et al., 2013). We present a summary of some analyses of the potential of MODIS-like instruments for this purpose, along with two case studies using airborne observations from the Ames Airborne Tracking Sunphotometer (AATS; http://geo.arc.nasa.gov/sgg/AATS-website/) as a validation data source for a preliminary AAC algorithm applied to MODIS measurements. AAC retrievals will eventually be added to the MODIS Deep Blue (Hsu et al., 2013) processing chain.

  19. Precipitation Recycling and the Vertical Distribution of Local and Remote Sources of Water for Precipitation

    NASA Technical Reports Server (NTRS)

    Bosilovich, Michael G.; Atlas, Robert (Technical Monitor)

    2002-01-01

    Precipitation recycling is defined as the amount of water that evaporates from a region that precipitates within the same region. This is also interpreted as the local source of water for precipitation. In this study, the local and remote sources of water for precipitation have been diagnosed through the use of passive constituent tracers that represent regional evaporative sources along with their transport and precipitation. We will discuss the differences between this method and the simpler bulk diagnostic approach to precipitation recycling. A summer seasonal simulation has been analyzed for the regional sources of the United States Great Plains precipitation. While the tropical Atlantic Ocean (including the Gulf of Mexico) and the local continental sources of precipitation are most dominant, the vertically integrated column of water contains substantial water content originating from the Northern Pacific Ocean, which is not precipitated. The vertical profiles of regional water sources indicate that local Great Plains source of water dominates the lower troposphere, predominantly in the PBL. However, the Pacific Ocean source is dominant over a large portion of the middle to upper troposphere. The influence of the tropical Atlantic Ocean is reasonably uniform throughout the column. While the results are not unexpected given the formulation of the model's convective parameterization, the analysis provides a quantitative assessment of the impact of local evaporation on the occurrence of convective precipitation in the GCM. Further, these results suggest that local source of water is not well mixed throughout the vertical column.

  20. Precipitation Nonstationarity Effects on Water Infrastructure and Risk Management

    EPA Science Inventory

    The non-stationary precipitation regime, as increasingly recognized, affects the engineering basis and service functions of drinking water, wastewater, and stormwater infrastructures in urban centers. Small, yet significant rates of temporal precipitation change and diverse spat...

  1. Comparison of aerosol optical properties above clouds between POLDER and AeroCom models over the South East Atlantic Ocean during the fire season: POLDER/AeroCom Comparison Above Clouds

    SciTech Connect

    Peers, F.; Bellouin, N.; Waquet, F.; Ducos, F.; Goloub, P.; Mollard, J.; Myhre, G.; Skeie, R. B.; Takemura, T.; Tanré, D.; Thieuleux, F.; Zhang, K.

    2016-04-21

    Aerosol properties above clouds have been retrieved over the South East Atlantic Ocean during the fire season 2006 using satellite observations from POLDER (Polarization and Directionality of Earth Reflectances). From June to October, POLDER has observed a mean Above-Cloud Aerosol Optical Thickness (ACAOT) of 0.28 and a mean Above-Clouds Single Scattering Albedo (ACSSA) of 0.87 at 550nm. These results have been used to evaluate the simulation of aerosols above clouds in 5 AeroCom (Aerosol Comparisons between Observations and Models) models (GOCART, HadGEM3, ECHAM5-HAM2, OsloCTM2 and SPRINTARS). Most models do not reproduce the observed large aerosol load episodes. The comparison highlights the importance of the injection height and the vertical transport parameterizations to simulate the large ACAOT observed by POLDER. Furthermore, some models overestimate the ACSSA. In accordance with recent recommendations of the black carbon refractive index, a higher prescription of the imaginary part allows a better comparison with POLDER’s ACSSA.

  2. Stochastic Models for Precipitable Water in Convection

    NASA Astrophysics Data System (ADS)

    Leung, Kimberly

    Atmospheric precipitable water vapor (PWV) is the amount of water vapor in the atmosphere within a vertical column of unit cross-sectional area and is a critically important parameter of precipitation processes. However, accurate high-frequency and long-term observations of PWV in the sky were impossible until the availability of modern instruments such as radar. The United States Department of Energy (DOE)'s Atmospheric Radiation Measurement (ARM) Program facility made the first systematic and high-resolution observations of PWV at Darwin, Australia since 2002. At a resolution of 20 seconds, this time series allowed us to examine the volatility of PWV, including fractal behavior with dimension equal to 1.9, higher than the Brownian motion dimension of 1.5. Such strong fractal behavior calls for stochastic differential equation modeling in an attempt to address some of the difficulties of convective parameterization in various kinds of climate models, ranging from general circulation models (GCM) to weather research forecasting (WRF) models. This important observed data at high resolution can capture the fractal behavior of PWV and enables stochastic exploration into the next generation of climate models which considers scales from micrometers to thousands of kilometers. As a first step, this thesis explores a simple stochastic differential equation model of water mass balance for PWV and assesses accuracy, robustness, and sensitivity of the stochastic model. A 1000-day simulation allows for the determination of the best-fitting 25-day period as compared to data from the TWP-ICE field campaign conducted out of Darwin, Australia in early 2006. The observed data and this portion of the simulation had a correlation coefficient of 0.6513 and followed similar statistics and low-resolution temporal trends. Building on the point model foundation, a similar algorithm was applied to the National Center for Atmospheric Research (NCAR)'s existing single-column model as a test

  3. Stochastic Models for Precipitable Water in Convection

    NASA Astrophysics Data System (ADS)

    Leung, Kimberly

    Atmospheric precipitable water vapor (PWV) is the amount of water vapor in the atmosphere within a vertical column of unit cross-sectional area and is a critically important parameter of precipitation processes. However, accurate high-frequency and long-term observations of PWV in the sky were impossible until the availability of modern instruments such as radar. The United States Department of Energy (DOE)'s Atmospheric Radiation Measurement (ARM) Program facility made the first systematic and high-resolution observations of PWV at Darwin, Australia since 2002. At a resolution of 20 seconds, this time series allowed us to examine the volatility of PWV, including fractal behavior with dimension equal to 1.9, higher than the Brownian motion dimension of 1.5. Such strong fractal behavior calls for stochastic differential equation modeling in an attempt to address some of the difficulties of convective parameterization in various kinds of climate models, ranging from general circulation models (GCM) to weather research forecasting (WRF) models. This important observed data at high resolution can capture the fractal behavior of PWV and enables stochastic exploration into the next generation of climate models which considers scales from micrometers to thousands of kilometers. As a first step, this thesis explores a simple stochastic differential equation model of water mass balance for PWV and assesses accuracy, robustness, and sensitivity of the stochastic model. A 1000-day simulation allows for the determination of the best-fitting 25-day period as compared to data from the TWP-ICE field campaign conducted out of Darwin, Australia in early 2006. The observed data and this portion of the simulation had a correlation coefficient of 0.6513 and followed similar statistics and low-resolution temporal trends. Building on the point model foundation, a similar algorithm was applied to the National Center for Atmospheric Research (NCAR)'s existing single-column model as a test

  4. A ten-year global record of absorbing aerosols above clouds from OMI's near-UV observations

    NASA Astrophysics Data System (ADS)

    Jethva, Hiren; Torrres, Omar; Ahn, Changwoo

    2016-05-01

    Aerosol-cloud interaction continues to be one of the leading uncertain components of climate models, primarily due to the lack of an adequate knowledge of the complex microphysical and radiative processes associated with the aerosolcloud system. The situations when aerosols and clouds are found in the same atmospheric column, for instance, when light-absorbing aerosols such as biomass burning generated carbonaceous particles or wind-blown dust overlay low-level cloud decks, are commonly found over several regional of the world. Contrary to the cloud-free scenario over dark surface, for which aerosols are known to produce a net cooling effect (negative radiative forcing) on climate, the overlapping situation of absorbing aerosols over cloud can potentially exert a significant level of atmospheric absorption and produces a positive radiative forcing at top-of-atmosphere. The magnitude of direct radiative effects of aerosols above cloud depends directly on the aerosol loading, microphysical-optical properties of the aerosol layer and the underlying cloud deck, and geometric cloud fraction. We help in addressing this problem by introducing a novel product of optical depth of absorbing aerosols above clouds retrieved from near-UV observations made by the Ozone Monitoring Instrument (OMI) on board NASA's Aura platform. The presence of absorbing aerosols above cloud reduces the upwelling radiation reflected by cloud and produces a strong `color ratio' effect in the near-UV region, which can be unambiguously detected in the OMI measurements. Physically based on this effect, the OMACA algorithm retrieves the optical depths of aerosols and clouds simultaneously under a prescribed state of atmosphere. The algorithm architecture and results from a ten-year global record including global climatology of frequency of occurrence and above-cloud aerosol optical depth, and a discussion on related future field campaigns are presented.

  5. Using total precipitable water anomaly as a forecast aid for heavy precipitation events

    NASA Astrophysics Data System (ADS)

    VandenBoogart, Lance M.

    Heavy precipitation events are of interest to weather forecasters, local government officials, and the Department of Defense. These events can cause flooding which endangers lives and property. Military concerns include decreased trafficability for military vehicles, which hinders both war- and peace-time missions. Even in data-rich areas such as the United States, it is difficult to determine when and where a heavy precipitation event will occur. The challenges are compounded in data-denied regions. The hypothesis that total precipitable water anomaly (TPWA) will be positive and increasing preceding heavy precipitation events is tested in order to establish an understanding of TPWA evolution. Results are then used to create a precipitation forecast aid. The operational, 16 km-gridded, 6-hourly TPWA product developed at the Cooperative Institute for Research in the Atmosphere (CIRA) compares a blended TPW product with a TPW climatology to give a percent of normal TPWA value. TPWA evolution is examined for 84 heavy precipitation events which occurred between August 2010 and November 2011. An algorithm which uses various TPWA thresholds derived from the 84 events is then developed and tested using dichotomous contingency table verification statistics to determine the extent to which satellite-based TPWA might be used to aid in forecasting precipitation over mesoscale domains. The hypothesis of positive and increasing TPWA preceding heavy precipitation events is supported by the analysis. Event-average TPWA rises for 36 hours and peaks at 154% of normal at the event time. The average precipitation event detected by the forecast algorithm is not of sufficient magnitude to be termed a "heavy" precipitation event; however, the algorithm adds skill to a climatological precipitation forecast. Probability of detection is low and false alarm ratios are large, thus qualifying the algorithm's current use as an aid rather than a deterministic forecast tool. The algorithm

  6. A New Method for Near Real Time Precipitation Estimates Using a Derived Statistical Relationship between Precipitable Water Vapor and Precipitation

    NASA Astrophysics Data System (ADS)

    Roman, J.

    2015-12-01

    The IPCC 5th Assessment found that the predicted warming of 1oC would increase the risk of extreme events such as heat waves, droughts, and floods. Weather extremes, like floods, have shown the vulnerability and susceptibility society has to these extreme weather events, through impacts such as disruption of food production, water supply, health, and damage of infrastructure. This paper examines a new way of near-real time forecasting of precipitation. A 10-year statistical climatological relationship was derived between precipitable water vapor (PWV) and precipitation by using the NASA Atmospheric Infrared Sounder daily gridded PWV product and the NASA Tropical Rainfall Measuring Mission daily gridded precipitation total. Forecasting precipitation estimates in real time is dire for flood monitoring and disaster management. Near real time PWV observations from AIRS on Aqua are available through the Goddard Earth Sciences Data and Information Service Center. In addition, PWV observations are available through direct broadcast from the NASA Suomi-NPP ATMS/CrIS instrument, the operational follow on to AIRS. The derived climatological relationship can be applied to create precipitation estimates in near real time by utilizing the direct broadcasting capabilities currently available in the CONUS region. The application of this relationship will be characterized through case-studies by using near real-time NASA AIRS Science Team v6 PWV products and ground-based SuomiNet GPS to estimate the current precipitation potential; the max amount of precipitation that can occur based on the moisture availability. Furthermore, the potential contribution of using the direct broadcasting of the NUCAPS ATMS/CrIS PWV products will be demonstrated. The analysis will highlight the advantages of applying this relationship in near-real time for flash flood monitoring and risk management. Relevance to the NWS River Forecast Centers will be discussed.

  7. University of Oregon: GPS-based Precipitable Water Vapor (PWV)

    DOE Data Explorer

    Vignola, F.; Andreas, A.

    2013-08-22

    A partnership with the University of Oregon and U.S. Department of Energy's National Renewable Energy Laboratory (NREL) to collect Precipitable Water Vapor (PWV) data to compliment existing resource assessment data collection by the university.

  8. Evaluating cloud precipitation efficiency with satellite retrievals of water isotopologues

    NASA Astrophysics Data System (ADS)

    Bailey, A.; Noone, D. C.; Wood, R.

    2015-12-01

    The efficiency with which clouds precipitate is believed to influence climate by modifying cloud lifetime and, ultimately, cloud amount. Aerosols can influence this linkage by reducing the effective radii of cloud droplets and suppressing precipitation. This relationship, however, is not unidirectional. Cloud precipitation efficiency can also regulate particle concentrations, since precipitation effectively scavenges aerosols from the atmosphere. One challenge in studying how aerosols, clouds, and precipitation processes interrelate is that observational constraints are difficult to attain. This work evaluates the ability of isotope ratios in water vapor to quantify cloud precipitation efficiency across the tropical and subtropical oceans. Theory suggests isotope ratios will record the precipitation efficiency of a convective plume, since heavier isotopologues precipitate preferentially; and a recent analysis of in situ measurements from the Mauna Loa Observatory (MLO, Hawaii, USA) verifies this to be the case. The challenge now lies in understanding whether satellite retrievals of isotope ratios in water vapor are sensitive enough to track precipitation efficiency globally. To answer this question, vertical profiles of the D/H ratio derived from NASA's Tropospheric Emission Spectrometer (TES) are first compared with the MLO in situ measurements. A qualitative match indicates the satellite retrievals can distinguish high from low precipitation efficiency convection. To expand the analysis geographically, TES profiles between 40°S and 40°N are compared with estimates of precipitation efficiency derived from the Tropical Rainfall Measuring Mission (TRMM) and ECMWF's ERA-Interim. Retrievals are binned by lower-tropospheric humidity and by vertical velocity in order to minimize large-scale thermodynamical influences. Co-located cloud retrievals provide the context necessary to evaluate the utility of these new estimates in elucidating cloud feedbacks on climate.

  9. Measurement of atmospheric precipitable water using a solar radiometer. [water vapor absorption effects

    NASA Technical Reports Server (NTRS)

    Pitts, D. E.; Dillinger, A. E.; Mcallum, W. E.

    1974-01-01

    A technique is described and tested that allows the determination of atmospheric precipitable water from two measurements of solar intensity: one in a water-vapor absorption band and another in a nearby spectral region unaffected by water vapor.

  10. Original isotopic composition of water in precipitation by different methods

    NASA Astrophysics Data System (ADS)

    Singh, B. P.

    2016-11-01

    Stable isotopes of 2H and 18O in precipitation are different globally and carry all information about water molecules movement in hydrosphere cycles. Isotopic composition is a function of temperature, relative humidity, and speed of evaporation at different latitudes, longitudes, and altitudes. On the basis of this, we observe local meteoric water line measurements in the plot of δ2H versus δ18O. It will be interesting to know the original isotopic composition (without any modification) in a transition from cloud down to earth in different environmental conditions. This had been done by plotting of slope versus intercept of Local Meteoric Water Line (LMWL) at different altitudes in different years of observations. Intercept of LMWL with Global Meteoric Water Line (GMWL) data taken from the hydrology frame work of Corsica was plotted and it was found that the isotopic composition of water in precipitation by all these methods is same.

  11. Effect of antiscalants on precipitation of an RO concentrate: metals precipitated and particle characteristics for several water compositions.

    PubMed

    Greenlee, Lauren F; Testa, Fabrice; Lawler, Desmond F; Freeman, Benny D; Moulin, Philippe

    2010-04-01

    Inland brackish water reverse osmosis (RO) is economically and technically limited by the large volume of salty waste (concentrate) produced. The use of a controlled precipitation step, followed by solid/liquid separation (filtration), has emerged as a promising side-stream treatment process to treat reverse osmosis concentrate and increase overall system recovery. The addition of antiscalants to the RO feed prevents precipitation within the membrane system but might have a deleterious effect on a concentrate treatment process that uses precipitation to remove problematic precipitates. The effects of antiscalant type and concentration on salt precipitation and precipitate particle morphology were evaluated for several water compositions. The primary precipitate for the synthetic brackish waters tested was calcium carbonate; the presence of magnesium, sulfate, minor ions, and antiscalant compounds affected the amount of calcium precipitated, as well as the phases of calcium carbonate formed during precipitation. Addition of antiscalant decreased calcium precipitation but increased incorporation of magnesium and sulfate into precipitating calcium carbonate. Antiscalants prevented the growth of nucleated precipitates, resulting in the formation of small (100-200 nm diameter) particles, as well as larger (6-10 microm) particles. Elemental analysis revealed changes in composition and calcium carbonate polymorph with antiscalant addition and antiscalant type. Results indicate that the presence of antiscalants does reduce the extent of calcium precipitation and can worsen subsequent filtration performance.

  12. Process Control for Precipitation Prevention in Space Water Recovery Systems

    NASA Technical Reports Server (NTRS)

    Sargusingh, Miriam; Callahan, Michael R.; Muirhead, Dean

    2015-01-01

    The ability to recover and purify water through physiochemical processes is crucial for realizing long-term human space missions, including both planetary habitation and space travel. Because of their robust nature, rotary distillation systems have been actively pursued by NASA as one of the technologies for water recovery from wastewater primarily comprised of human urine. A specific area of interest is the prevention of the formation of solids that could clog fluid lines and damage rotating equipment. To mitigate the formation of solids, operational constraints are in place that limits such that the concentration of key precipitating ions in the wastewater brine are below the theoretical threshold. This control in effected by limiting the amount of water recovered such that the risk of reaching the precipitation threshold is within acceptable limits. The water recovery limit is based on an empirically derived worst case wastewater composition. During the batch process, water recovery is estimated by monitoring the throughput of the system. NASA Johnson Space Center is working on means of enhancing the process controls to increase water recovery. Options include more precise prediction of the precipitation threshold. To this end, JSC is developing a means of more accurately measuring the constituent of the brine and/or wastewater. Another means would be to more accurately monitor the throughput of the system. In spring of 2015, testing will be performed to test strategies for optimizing water recovery without increasing the risk of solids formation in the brine.

  13. Distribution of tritium in precipitation and surface water in California

    NASA Astrophysics Data System (ADS)

    Harms, Patrick A.; Visser, Ate; Moran, Jean E.; Esser, Brad K.

    2016-03-01

    The tritium concentration in the surface hydrosphere throughout California was characterized to examine the reasons for spatial variability and to enhance the applicability of tritium in hydrological investigations. Eighteen precipitation samples were analyzed and 148 samples were collected from surface waters across California in the Summer and Fall of 2013, with repeat samples from some locations collected in Winter and Spring of 2014 to examine seasonal variation. The concentration of tritium in present day precipitation varied from 4.0 pCi/L near the California coast to 17.8 pCi/L in the Sierra Nevada Mountains. Concentrations in precipitation increase in spring due to the 'Spring Leak' phenomenon. The average coastal concentration (6.3 ± 1.2 pCi/L) in precipitation matches estimated pre-nuclear levels. Surface water samples show a trend of increasing tritium with inland distance. Superimposed on that trend, elevated tritium concentrations are found in the San Francisco Bay area compared to other coastal areas, resulting from municipal water imported from inland mountain sources and local anthropogenic sources. Tritium concentrations in most surface waters decreased between Summer/Fall 2013 and Winter/Spring 2014 likely due to an increased groundwater signal as a result of drought conditions in 2014. A relationship between tritium and electrical conductivity in surface water was found to be indicative of water provenance and anthropogenic influences such as agricultural runoff. Despite low initial concentrations in precipitation, tritium continues to be a valuable tracer in a post nuclear bomb pulse world.

  14. A multi-satellite analysis of the direct radiative effects of absorbing aerosols above clouds

    NASA Astrophysics Data System (ADS)

    Chang, Y. Y.; Christopher, S. A.

    2015-12-01

    Radiative effects of absorbing aerosols above liquid water clouds in the southeast Atlantic as a function of fire sources are investigated using A-Train data coupled with the Visible Infrared Imaging Radiometer Suite (VIIRS) onboard Suomi National Polar-orbiting Partnership (Suomi NPP). Both the VIIRS Active Fire product and the Aqua Moderate Resolution Imaging Spectroradiometer (MODIS) Thermal Anomalies product (MYD14) are used to identify the biomass burning fire origin in southern Africa. The Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP) are used to assess the aerosol type, aerosol altitude, and cloud altitude. We use back trajectory information, wind data, and the Fire Locating and Modeling of Burning Emissions (FLAMBE) product to infer the transportation of aerosols from the fire source to the CALIOP swath in the southeast Atlantic during austral winter.

  15. Extending "Deep Blue" Aerosol Retrieval Coverage to Cases of Absorbing Aerosols Above Clouds: Sensitivity Analysis and First Case Studies

    NASA Technical Reports Server (NTRS)

    Sayer, A. M.; Hsu, N. C.; Bettenhausen, C.; Lee, J.; Redemann, J.; Schmid, B.; Shinozuka, Y.

    2016-01-01

    Cases of absorbing aerosols above clouds (AACs), such as smoke or mineral dust, are omitted from most routinely processed space-based aerosol optical depth (AOD) data products, including those from the Moderate Resolution Imaging Spectroradiometer (MODIS). This study presents a sensitivity analysis and preliminary algorithm to retrieve above-cloud AOD and liquid cloud optical depth (COD) for AAC cases from MODIS or similar sensors, for incorporation into a future version of the "Deep Blue" AOD data product. Detailed retrieval simulations suggest that these sensors should be able to determine AAC AOD with a typical level of uncertainty approximately 25-50 percent (with lower uncertainties for more strongly absorbing aerosol types) and COD with an uncertainty approximately10-20 percent, if an appropriate aerosol optical model is known beforehand. Errors are larger, particularly if the aerosols are only weakly absorbing, if the aerosol optical properties are not known, and the appropriate model to use must also be retrieved. Actual retrieval errors are also compared to uncertainty envelopes obtained through the optimal estimation (OE) technique; OE-based uncertainties are found to be generally reasonable for COD but larger than actual retrieval errors for AOD, due in part to difficulties in quantifying the degree of spectral correlation of forward model error. The algorithm is also applied to two MODIS scenes (one smoke and one dust) for which near-coincident NASA Ames Airborne Tracking Sun photometer (AATS) data were available to use as a ground truth AOD data source, and found to be in good agreement, demonstrating the validity of the technique with real observations.

  16. Comparison Between Water Level and Precipitation in Rio Negro Basin

    NASA Astrophysics Data System (ADS)

    Figliuolo, G. C.; Santos Da Silva, J.; Calmant, S.; Seyler, F.; Correia, F.; Oliveira, R. J.

    2013-12-01

    The Amazon Basin holds a lot of difficulties for providing data that enable regional researching works, because of its large extension and for having areas, whose access is very difficult. Remote sensing data presents an excellent way for monitoring the Amazon Basin and collecting data for researches. This current study aims matching radar altimetry data from the JASON-2, with the rainfall data from the TRMM satellite in order to analyze the relation between the water level and the precipitation in two different points along the Rio Negro Basin. After data analysis, it was possible noting a difference on the responding process for both regions. Whilst at the NEGRO_089_03 station (located in the city of São Gabriel da Cachoeira) the graphic of precipitation and water level were very similar, in NEGRO_063 station (located in the city of Manaus) the graphic showed a two month discrepancy due to the difference of the river's bottom size in both regions, at NEGRO_089_03's area for having a smaller river and the water level rises faster, whereas in NEGRO_063 the water level takes about two months to respond to precipitation.

  17. Study of de-watering from the gelatinous precipitate formed during co-precipitation of Nd-YAG powder

    NASA Astrophysics Data System (ADS)

    Karmakar, Sanjib; Sharma, Rachna; Pathak, S. K.; Gupta, S. M.; Gupta, P. K.

    2013-02-01

    Neodymium doped Yttrium Aluminium Garnet (Nd:YAG) ceramics have been synthesised using coprecipitation technique and high temperature vacuum sintering. Gelatinous like precipitates were obtained when precursors of Nd, Al and Yb-nitrate solutions are co-precipitated using ammonia co-precipitant. De-watering from the gelatinous like precipitates is a big challenge and it possesses difficulty in filtration. Evaporation of water by heating resulted in strong agglomerated powder. Different agents were used to ease the filtration process, which is correlated with the phase in the calcined powder.

  18. Study of de-watering from the gelatinous precipitate formed during co-precipitation of Nd-YAG powder

    SciTech Connect

    Karmakar, Sanjib; Sharma, Rachna; Pathak, S. K.; Gupta, S. M.; Gupta, P. K.

    2013-02-05

    Neodymium doped Yttrium Aluminium Garnet (Nd:YAG) ceramics have been synthesised using coprecipitation technique and high temperature vacuum sintering. Gelatinous like precipitates were obtained when precursors of Nd, Al and Yb-nitrate solutions are co-precipitated using ammonia co-precipitant. De-watering from the gelatinous like precipitates is a big challenge and it possesses difficulty in filtration. Evaporation of water by heating resulted in strong agglomerated powder. Different agents were used to ease the filtration process, which is correlated with the phase in the calcined powder.

  19. A Novel Method for Estimating Shortwave Direct Radiative Effect of Above-Cloud Aerosols Using CALIOP and MODIS Data

    NASA Technical Reports Server (NTRS)

    Zhang, Zhibo; Meyer, Kerry G.; Platnick, Steven; Oreopoulos, Lazaros; Lee, Dongmin; Yu, Hongbin

    2014-01-01

    This paper describes an efficient and unique method for computing the shortwave direct radiative effect (DRE) of aerosol residing above low-level liquid-phase clouds using CALIOP and MODIS data. It addresses the overlap of aerosol and cloud rigorously by utilizing the joint histogram of cloud optical depth and cloud top pressure while also accounting for subgrid-scale variations of aerosols. The method is computationally efficient because of its use of grid-level cloud and aerosol statistics, instead of pixel-level products, and a pre-computed look-up table based on radiative transfer calculations. We verify that for smoke over the southeast Atlantic Ocean the method yields a seasonal mean instantaneous (approximately 1:30PM local time) shortwave DRE of above cloud aerosol (ACA) that generally agrees with more rigorous pixel-level computation within 4 percent. We also estimate the impact of potential CALIOP aerosol optical depth (AOD) retrieval bias of ACA on DRE. We find that the regional and seasonal mean instantaneous DRE of ACA over southeast Atlantic Ocean would increase, from the original value of 6.4 W m(-2) based on operational CALIOP AOD to 9.6 W m(-2) if CALIOP AOD retrieval are biased low by a factor of 1.5 (Meyer et al., 2013) and further to 30.9 W m(-2) if CALIOP AOD retrieval are biased low by a factor of 5 as suggested in (Jethva et al., 2014). In contrast, the instantaneous ACA radiative forcing efficiency (RFE) remains relatively invariant in all cases at about 53 W m(-2) AOD(-1), suggesting a near linear relation between the instantaneous RFE and AOD. We also compute the annual mean instantaneous shortwave DRE of light-absorbing aerosols (i.e., smoke and polluted dust) over global oceans based on 4 years of CALIOP and MODIS data. We find that the variability of the annual mean shortwave DRE of above-cloud light-absorbing aerosol is mainly driven by the optical depth of the underlying clouds. While we demonstrate our method using CALIOP and MODIS

  20. Retrieval of Atmospheric CO2 Concentration above Clouds and Cloud Top Pressure from Airborne Lidar Measurements during ASCENDS Science Campaigns

    NASA Astrophysics Data System (ADS)

    Mao, J.; Ramanathan, A. K.; Rodriguez, M.; Allan, G. R.; Hasselbrack, W. E.; Abshire, J. B.; Riris, H.; Kawa, S. R.

    2014-12-01

    NASA Goddard is developing an integrated-path, differential absorption (IPDA) lidar approach to measure atmospheric CO2 concentrations from space as a candidate for NASA's ASCENDS (Active Sensing of CO2 Emissions over Nights, Days, and Seasons) mission. The approach uses pulsed lasers to measure both CO2 and O2 absorption simultaneously in the vertical path to the surface at a number of wavelengths across a CO2 line at 1572.335 nm and an O2 line doublet near 764.7 nm. Measurements of time-resolved laser backscatter profiles from the atmosphere allow the technique to estimate column CO2 and O2 number density and range to cloud tops in addition to those to the ground. This allows retrievals of CO2 column above clouds and cloud top pressure, and all-sky measurement capability from space. This additional information can be used to evaluate atmospheric transport processes and other remote sensing carbon data in the free atmosphere, improve carbon data assimilation in models and help global and regional carbon flux estimates. We show some preliminary results of this capability using airborne lidar measurements from the summers of 2011 and 2014 ASCENDS science campaigns. These show simultaneous retrievals of CO2 and O2 column densities for laser returns from low-level marine stratus clouds in the west coast of California. This demonstrates the supplemental capability of the future space carbon mission to measure CO2 above clouds, which is valuable particularly for the areas with persistent cloud covers, e.g, tropical ITCZ, west coasts of continents with marine layered clouds and southern ocean with highest occurrence of low-level clouds, where underneath carbon cycles are active but passive remote sensing techniques using the reflected short wave sunlight are unable to measure accurately due to cloud scattering effect. We exercise cloud top pressure retrieval from O2 absorption measurements during the flights over the low-level marine stratus cloud decks, which is one of

  1. Retrieval, Inter-Comparison, and Validation of Above-Cloud Aerosol Optical Depth from A-train Sensors

    NASA Technical Reports Server (NTRS)

    Jethva, Hiren; Torres, Omar; Bhartia, Pawan K.; Remer, Lorraine; Redemann, Jens; Dunagan, Stephen E.; Livingston, John; Shinozuka, Yohei; Kacenelenbogen, Meloe; Segal-Rosenbeimer, Michal; Spurr, Rob

    2014-01-01

    Absorbing aerosols produced from biomass burning and dust outbreaks are often found to overlay lower level cloud decks and pose greater potentials of exerting positive radiative effects (warming) whose magnitude directly depends on the aerosol loading above cloud, optical properties of clouds and aerosols, and cloud fraction. Recent development of a 'color ratio' (CR) algorithm applied to observations made by the Aura/OMI and Aqua/MODIS constitutes a major breakthrough and has provided unprecedented maps of above-cloud aerosol optical depth (ACAOD). The CR technique employs reflectance measurements at TOA in two channels (354 and 388 nm for OMI; 470 and 860 nm for MODIS) to retrieve ACAOD in near-UV and visible regions and aerosol-corrected cloud optical depth, simultaneously. An inter-satellite comparison of ACAOD retrieved from NASA's A-train sensors reveals a good level of agreement between the passive sensors over the homogeneous cloud fields. Direct measurements of ACA such as carried out by the NASA Ames Airborne Tracking Sunphotometer (AATS) and Spectrometer for Sky-Scanning, Sun-Tracking Atmospheric Research (4STAR) can be of immense help in validating ACA retrievals. We validate the ACA optical depth retrieved using the CR method applied to the MODIS cloudy-sky reflectance against the airborne AATS and 4STAR measurements. A thorough search of the historic AATS-4STAR database collected during different field campaigns revealed five events where biomass burning, dust, and wildfire-emitted aerosols were found to overlay lower level cloud decks observed during SAFARI-2000, ACE-ASIA 2001, and SEAC4RS- 2013, respectively. The co-located satellite-airborne measurements revealed a good agreement (RMSE less than 0.1 for AOD at 500 nm) with most matchups falling within the estimated uncertainties in the MODIS retrievals. An extensive validation of satellite-based ACA retrievals requires equivalent field measurements particularly over the regions where ACA are often

  2. Syndepositional shallow-water precipitation of glauconitic minerals

    NASA Astrophysics Data System (ADS)

    Chafetz, H. S.; Reid, A.

    2000-10-01

    Numerous studies have demonstrated that glauconitic minerals predominantly form in water depths of mid-shelf to upper slope in modern oceans. These areas tend to have slow sedimentation rates, another commonly cited requisite for glauconitic mineral precipitation. Cambro-Ordovician strata from the southwestern US are rich in glauconitic minerals. Stratigraphic, sedimentological, and petrographic constraints indicate that the glauconitic minerals are autochthonous. In marked contrast to the modern environments of deposition, these Cambro-Ordovician strata formed under very shallow-water to tidal-flat conditions. The trough cross-stratified deposits of the most glauconitic mineral-rich accumulations (glaucarenites) indicate a high energy environment and probably a normal to high rate of sedimentation. The presence of fibroradiated rims of glauconitic minerals on glauconitic mineral pellets, echinoderm fragments, and quartz grains demonstrates that the Cambro-Ordovician glauconitic minerals precipitated on or in close proximity to the sea floor and prior to calcite precipitation. Consequently, glauconitic minerals must have formed under markedly different conditions in the lower Paleozoic than they do today. Thus, the occurrence of glauconitic minerals in the rock record cannot be used a priori as an environmental indicator of either mid-shelf and deeper water and/or a slow rate of sedimentation.

  3. A Novel Method for Estimating Shortwave Direct Radiative Effect of Above-Cloud Aerosols Using CALIOP and MODIS Data

    NASA Technical Reports Server (NTRS)

    Zhang, Z.; Meyer, K.; Platnick, S.; Oreopoulos, L.; Lee, D.; Yu, H.

    2014-01-01

    This paper describes an efficient and unique method for computing the shortwave direct radiative effect (DRE) of aerosol residing above low-level liquid-phase clouds using CALIOP and MODIS data. It accounts for the overlapping of aerosol and cloud rigorously by utilizing the joint histogram of cloud optical depth and cloud top pressure. Effects of sub-grid scale cloud and aerosol variations on DRE are accounted for. It is computationally efficient through using grid-level cloud and aerosol statistics, instead of pixel-level products, and a pre-computed look-up table in radiative transfer calculations. We verified that for smoke over the southeast Atlantic Ocean the method yields a seasonal mean instantaneous shortwave DRE that generally agrees with more rigorous pixel-level computation within 4. We have also computed the annual mean instantaneous shortwave DRE of light-absorbing aerosols (i.e., smoke and polluted dust) over global ocean based on 4 yr of CALIOP and MODIS data. We found that the variability of the annual mean shortwave DRE of above-cloud light-absorbing aerosol is mainly driven by the optical depth of the underlying clouds.

  4. Precipitable water as a predictor of LCL height

    NASA Astrophysics Data System (ADS)

    Murugavel, P.; Malap, N.; Balaji, B.; Mehajan, R. K.; Prabha, T. V.

    2016-08-01

    Based on the precipitable water observations easily available from in situ and remote sensing sensors, a simple approach to define the lifting condensation level (LCL) is proposed in this study. High-resolution radiosonde and microwave radiometer observations over peninsular Indian region during the Cloud Aerosol Interaction and Precipitation Enhancement Experiment Integrated Ground Observational Campaign (CAIPEEX-IGOC) during the monsoon season of 2011 are used to illustrate the unique relationship. The inferences illustrate a linear relationship between the precipitable water (PW) and the LCL temperature. This relationship is especially valuable because PW is easily available as a derived parameter from various remote sensing and ground-based observations. Thus, it could be used to estimate the LCL height and perhaps also the boundary layer height. LCL height and PW correlations are established from historical radiosonde data (1984-2012). This finding could be used to illustrate the boundary layer-cloud interactions during the monsoon and is important for parameterization of boundary layer clouds in numerical models. The relationships are illustrated to be robust and seem promising to get reasonable estimates of the LCL height over other locations as well using satellite observations of PW.

  5. Getting water right: A case study in water yield modelling based on precipitation data.

    PubMed

    Pessacg, Natalia; Flaherty, Silvia; Brandizi, Laura; Solman, Silvina; Pascual, Miguel

    2015-12-15

    Water yield is a key ecosystem service in river basins and especially in dry regions around the World. In this study we carry out a modelling analysis of water yields in the Chubut River basin, located in one of the driest districts of Patagonia, Argentina. We focus on the uncertainty around precipitation data, a driver of paramount importance for water yield. The objectives of this study are to: i) explore the spatial and numeric differences among six widely used global precipitation datasets for this region, ii) test them against data from independent ground stations, and iii) explore the effects of precipitation data uncertainty on simulations of water yield. The simulations were performed using the ecosystem services model InVEST (Integrated Valuation of Ecosystem Services and Tradeoffs) with each of the six different precipitation datasets as input. Our results show marked differences among datasets for the Chubut watershed region, both in the magnitude of precipitations and their spatial arrangement. Five of the precipitation databases overestimate the precipitation over the basin by 50% or more, particularly over the more humid western range. Meanwhile, the remaining dataset (Tropical Rainfall Measuring Mission - TRMM), based on satellite measurements, adjusts well to the observed rainfall in different stations throughout the watershed and provides a better representation of the precipitation gradient characteristic of the rain shadow of the Andes. The observed differences among datasets in the representation of the rainfall gradient translate into large differences in water yield simulations. Errors in precipitation of +30% (-30%) amplify to water yield errors ranging from 50 to 150% (-45 to -60%) in some sub-basins. These results highlight the importance of assessing uncertainties in main input data when quantifying and mapping ecosystem services with biophysical models and cautions about the undisputed use of global environmental datasets.

  6. An evaluation of CALIOP/CALIPSO's aerosol-above-cloud detection and retrieval capability over North America

    NASA Astrophysics Data System (ADS)

    Kacenelenbogen, M.; Redemann, J.; Vaughan, M. A.; Omar, A. H.; Russell, P. B.; Burton, S.; Rogers, R. R.; Ferrare, R. A.; Hostetler, C. A.

    2014-01-01

    Assessing the accuracy of the aerosol-above-cloud (AAC) properties derived by CALIOP (the Cloud-Aerosol Lidar with Orthogonal Polarization) is challenged by the shortage of accurate global validation measurements. We have used measurements of aerosol vertical profiles from the NASA Langley airborne High Spectral Resolution Lidar (HSRL-1) in 86 CALIOP-coincident flights to evaluate CALIOP AAC detection, classification, and retrieval. Our study shows that CALIOP detects ~23% of the HSRL-detected AAC. According to our CALIOP-HSRL data set, the majority of AAC aerosol optical depth (AOD) values are < 0.1 at 532 nm over North America. Our analyses show that the standard CALIOP retrieval algorithm substantially underestimates the occurrence frequency of AAC when optical depths are less than ~0.02. Those aerosols with low AOD values can still have a consequent radiative forcing effect depending on the underlying cloud cover and overlying aerosol absorption properties. We find essentially no correlation between CALIOP and HSRL AAC AOD (R2 = 0.27 and N = 151). We show that the CALIOP underestimation of AAC is mostly due to tenuous aerosol layers with backscatter less than the CALIOP detection threshold. The application of an alternate CALIOP AAC retrieval method (depolarization ratio) to our data set yields very few coincident cases. We stress the need for more extensive suborbital CALIOP validation campaigns to acquire a process-level understanding of AAC implications and further evaluate CALIOP's AAC detection and retrieval capability, especially over the ocean and in different parts of the world where AAC are more frequently observed and show higher values of AOD.

  7. Improving Reanalyses Using TRMM and SSM/I-Derived Precipitation and Total Precipitable Water Observations

    NASA Technical Reports Server (NTRS)

    Hou, Arthur Y.; Zhang, Sara Q.; daSilva, Arlindo M.

    1999-01-01

    Global reanalyses currently contain significant errors in the primary fields of the hydrological cycle such as precipitation, evaporation, moisture, and the related cloud fields, especially in the tropics. The Data Assimilation Office (DAO) at the NASA Goddard Space Flight Center has been exploring the use of rainfall and total precipitable water (TPW) observations from the Tropical Rainfall Measuring Mission (TRMM) Microwave Imager (TMI) and the Special Sensor Microwave/ Imager (SSM/I) instruments to improve these fields in reanalyses. The DAO has developed a "1+1"D procedure to assimilate 6-hr averaged rainfall and TPW into the Goddard Earth Observing System (GEOS) Data Assimilation System (DAS). The algorithm is based on a 6-hr time integration of a column version of the GEOS DAS. The "1+1" designation refers to one spatial dimension plus one temporal dimension. The scheme minimizes the least-square differences between the satellite-retrieved rain rates and those produced by the column model over the 6-hr analysis window. The control variables are analysis increments of moisture within the Incremental Analysis Update (IAU) framework of the GEOS DAS. This 1+1D scheme, in its generalization to four dimensions, is related to the standard 4D variational assimilation but differs in its choice of the control variable. Instead of estimating the initial condition at the beginning of the assimilation cycle, it estimates the constant IAU forcing applied over a 6-hr assimilation cycle. In doing so, it imposes the forecast model as a weak constraint in a manner similar to the variational continuous assimilation techniques. We present results from an experiment in which the observed rain rate and TPW are assumed to be "perfect". They show that assimilating the TMI and SSM/I-derived surface precipitation and TPW observations improves not only the precipitation and moisture fields but also key climate parameters directly linked to convective activities such as clouds, the

  8. GPS Estimates of Integrated Precipitable Water Aid Weather Forecasters

    NASA Technical Reports Server (NTRS)

    Moore, Angelyn W.; Gutman, Seth I.; Holub, Kirk; Bock, Yehuda; Danielson, David; Laber, Jayme; Small, Ivory

    2013-01-01

    Global Positioning System (GPS) meteorology provides enhanced density, low-latency (30-min resolution), integrated precipitable water (IPW) estimates to NOAA NWS (National Oceanic and Atmospheric Adminis tration Nat ional Weather Service) Weather Forecast Offices (WFOs) to provide improved model and satellite data verification capability and more accurate forecasts of extreme weather such as flooding. An early activity of this project was to increase the number of stations contributing to the NOAA Earth System Research Laboratory (ESRL) GPS meteorology observing network in Southern California by about 27 stations. Following this, the Los Angeles/Oxnard and San Diego WFOs began using the enhanced GPS-based IPW measurements provided by ESRL in the 2012 and 2013 monsoon seasons. Forecasters found GPS IPW to be an effective tool in evaluating model performance, and in monitoring monsoon development between weather model runs for improved flood forecasting. GPS stations are multi-purpose, and routine processing for position solutions also yields estimates of tropospheric zenith delays, which can be converted into mm-accuracy PWV (precipitable water vapor) using in situ pressure and temperature measurements, the basis for GPS meteorology. NOAA ESRL has implemented this concept with a nationwide distribution of more than 300 "GPSMet" stations providing IPW estimates at sub-hourly resolution currently used in operational weather models in the U.S.

  9. Shortwave direct radiative effects of above cloud aerosols over global oceans derived from eight years of CALIOP and MODIS observations

    NASA Astrophysics Data System (ADS)

    Zhang, Z.; Meyer, K.; Yu, H.; Platnick, S.; Colarco, P.; Liu, Z.; Oreopoulos, L.

    2015-09-01

    In this paper, we studied the frequency of occurrence and shortwave direct radiative effects (DRE) of above-cloud aerosols (ACAs) over global oceans using eight years of collocated CALIOP and MODIS observations. Similar to previous work, we found high ACA occurrence in four regions: Southeast (SE) Atlantic region where ACAs are mostly light-absorbing aerosols, i.e., smoke and polluted dust according to CALIOP classification, originating from biomass burning over African Savanna; Tropical Northeast Atlantic and Arabian Sea where ACAs are predominantly windblown dust from the Sahara and Arabian desert, respectively; and Northwest Pacific where ACAs are mostly transported smoke and polluted dusts from Asian. From radiative transfer simulations based on CALIOP-MODIS observations and a set of the preselected aerosol optical models, we found the DREs of ACAs at the top of atmosphere (TOA) to be positive (i.e., warming) in the SE Atlantic and NW Pacific regions, but negative (i.e., cooling) in TNE Atlantic and Arabian Sea. The cancellation of positive and negative regional DREs results in a global ocean annual mean diurnally averaged cloudy-sky DRE of 0.015 W m-2 (range of -0.03 to 0.06 W m-2) at TOA. The DREs at surface and within atmosphere are -0.15 W m-2 (range of -0.09 to -0.21 W m-2), and 0.17 W m-2 (range of 0.11 to 0.24 W m-2), respectively. The regional and seasonal mean DREs are much stronger. For example, in the SE Atlantic region the JJA (July ~ August) seasonal mean cloudy-sky DRE is about 0.7 W m-2 (range of 0.2 to 1.2 W m-2) at TOA. The uncertainty in our DRE computations is mainly cause by the uncertainties in the aerosol optical properties, in particular aerosol absorption, and uncertainties in the CALIOP operational aerosol optical thickness retrieval. In situ and remotely sensed measurements of ACA from future field campaigns and satellite missions, and improved lidar retrieval algorithm, in particular vertical feature masking, would help reduce the

  10. Natural chlorine and fluorine in the atmosphere, water and precipitation

    NASA Technical Reports Server (NTRS)

    Friend, James P.

    1990-01-01

    The geochemical cycles of chlorine and fluorine are surveyed and summarized as framework for the understanding of the global natural abundances of these species in the atmosphere, water, and precipitation. In the cycles the fluxes into and out of the atmosphere can be balanced within the limits of our knowledge of the natural sources and sinks. Sea salt from the ocean surfaces represent the predominant portion of the source of chlorine. It is also an important source of atmospheric fluorine, but volcanoes are likely to be more important fluorine sources. Dry deposition of sea salt returns about 85 percent of the salt released there. Precipitation removes the remainder. Most of the sea salt materials are considered to be cyclic, moving through sea spray over the oceans and either directly back to the oceans or deposited dry and in precipitation on land, whence it runs off into rivers and streams and returns to the oceans. Most of the natural chlorine in the atmosphere is in the form of particulate chloride ion with lesser amounts as gaseous inorganic chloride and methyl chloride vapor. Fluorine is emitted from volcanoes primarily as HF. It is possible that HF may be released directly form the ocean surface but this has not been confirmed by observation. HCl and most likely HF gases are released into the atmosphere by sea salt aerosols. The mechanism for the release is likely to be the provision of protons from the so-called excess sulfate and HNO3. Sea salt aerosol contains fluorine as F(-), MgF(+), CaF(+), and NaF. The concentrations of the various species of chlorine and fluorine that characterize primarily natural, unpolluted atmospheres are summarized in tables and are discussed in relation to their fluxes through the geochemical cycle.

  11. Relation of bulk precipitation and evapotranspiration to water quality and water resources, St. Thomas, Virgin Islands

    USGS Publications Warehouse

    Jordan, Donald George; Fisher, Donald W.

    1977-01-01

    St. Thomas, Virgin Islands, lies in what can be considered a true maritime regime, being 600 miles (1000 kilometers) from the nearest continental landmass. The island is composed almost entirely of volcanic rocks mantled by a thin soil seldom more than 2 feet (60 centimeters) thick. Rainfall, averaging about 40 inches (1020 millimeters) annually, has an orographic distribution related to the central ridge of the island, altitude 600 to 1500 feet (180 to 405 meters), and the easterly to northeasterly trade winds. The mineral content of bulk precipitation falling on the island is derived principally from the sea although soil dust contributes much of the calcium, sodium, and bicarbonate. Two-thirds of the sulfate in the precipitation is provided by sea salts; the remainder is derived from other sources. The concentration of the constituents of bulk precipitation fluctuates widely month to month, but the load of the constituents shows little monthly variation. Bulk precipitation is concentrated on the land surface and in the soil zone. From there it is carried into the ground water during recharge or is removed by storm-water runoff. It is the principal source of minerals in the waters of the island. Soil-moisture demand and evaporation limits recharge to 1 to 2 inches (25 to 50 millimeters) annually for the greater part of the island. Evapotranspiration also occurs directly from the aquifer. The salts left further increase the mineralization of the ground water. Water loss from the aquifer by evapotranspiration ranges from 40 to 80 percent of the recharge. Recharge to the aquifers and evapotranspiration of ground water determined by ratios of chloride concentrations in bulk precipitation, surface water, and subsurface water agree favorably with recharge and groundwater loss computed by other means.

  12. Estimation of precipitable water vapor at GPS sites in Morocco

    NASA Astrophysics Data System (ADS)

    Koulali Idrissi, A.; Ouazar, D.; Bock, O.; Fadil, A.

    2009-12-01

    Knowledge of the distribution of water vapor in both time and space is essential for understanding weather and global climate change. This study presents the results of precipitable water vapor (PWV) estimates from GPS data for three continuously operating GPS stations in Morocco (Rabat, Tetouan, and Ifrane) for the period 2001 to 2007. The conversion of atmospheric delays to integrated water vapor was carried out using interpolated surface meteorological parameters derived from the global numerical weather model analysis from the National Centers for Environmental Prediction (NCEP). The surface pressure extracted from the NCEP model was compared with observations provided from the synoptic network of the Moroccan Meteorological Agency (DMN). Good agreement was found between the two data sets with a bias of less than 1hPa. We compared the GPS derived PWV with the nearest radiosondes at the Rabat and Tetouan stations. The results show overall good agreement between the two data sets (mean difference < 2.5Kg/m2). The NCEP PWV compared well with GPS observations with a mean difference of less than 2.5 Kg/m2 and a standard deviation of less than 3.5 Kg/m2, confirming the potential of ground based GPS to provide an accurate and continuous description of water vapor field variations. The study showed by means of GPS, radiosondes and both NCEP model, a clear seasonal cycle of PWV with the highest values recorded during June, July, August, and September, peaking at 29 Kg/m2. The highest seasonal modulations seen at the 3 GPS stations were linked to large-scale atmospheric circulation.

  13. Aerosol concentration and size distribution measured below, in, and above cloud from the DOE G-1 during VOCALS-REx

    SciTech Connect

    Kleinman, L.I.; Daum, P. H.; Lee, Y.-N.; Lewis, E. R.; Sedlacek III, A. J.; Senum, G. I.; Springston, S. R.; Wang, J.; Hubbe, J.; Jayne, J.; Min, Q.; Yum, S. S.; Allen, G.

    2011-06-21

    During the VOCALS Regional Experiment, the DOE G-1 aircraft was used to sample a varying aerosol environment pertinent to properties of stratocumulus clouds over a longitude band extending 800 km west from the Chilean coast at Arica. Trace gas and aerosol measurements are presented as a function of longitude, altitude, and dew point in this study. Spatial distributions are consistent with an upper atmospheric source for O{sub 3} and South American coastal sources for marine boundary layer (MBL) CO and aerosol, most of which is acidic sulfate in agreement with the dominant pollution source being SO{sub 2} from Cu smelters and power plants. Pollutant layers in the free troposphere (FT) can be a result of emissions to the north in Peru or long range transport from the west. At a given altitude in the FT (up to 3 km), dew point varies by 40 C with dry air descending from the upper atmospheric and moist air having a BL contribution. Ascent of BL air to a cold high altitude results in the condensation and precipitation removal of all but a few percent of BL water along with aerosol that served as CCN. Thus, aerosol volume decreases with dew point in the FT. Aerosol size spectra have a bimodal structure in the MBL and an intermediate diameter unimodal distribution in the FT. Comparing cloud droplet number concentration (CDNC) and pre-cloud aerosol (Dp > 100 nm) gives a linear relation up to a number concentration of {approx}150 cm{sup -3}, followed by a less than proportional increase in CDNC at higher aerosol number concentration. A number balance between below cloud aerosol and cloud droplets indicates that {approx}25% of aerosol in the PCASP size range are interstitial (not activated). One hundred and two constant altitude cloud transects were identified and used to determine properties of interstitial aerosol. One transect is examined in detail as a case study. Approximately 25 to 50% of aerosol with D{sub p} > 110 nm were not activated, the difference between the two

  14. Aerosol concentration and size distribution measured below, in, and above cloud from the DOE G-1 during VOCALS-REx

    NASA Astrophysics Data System (ADS)

    Kleinman, L. I.; Daum, P. H.; Lee, Y.-N.; Lewis, E. R.; Sedlacek, A. J., III; Senum, G. I.; Springston, S. R.; Wang, J.; Hubbe, J.; Jayne, J.; Min, Q.; Yum, S. S.; Allen, G.

    2011-06-01

    During the VOCALS Regional Experiment, the DOE G-1 aircraft was used to sample a varying aerosol environment pertinent to properties of stratocumulus clouds over a longitude band extending 800 km west from the Chilean coast at Arica. Trace gas and aerosol measurements are presented as a function of longitude, altitude, and dew point in this study. Spatial distributions are consistent with an upper atmospheric source for O3 and South American coastal sources for marine boundary layer (MBL) CO and aerosol, most of which is acidic sulfate in agreement with the dominant pollution source being SO2 from Cu smelters and power plants. Pollutant layers in the free troposphere (FT) can be a result of emissions to the north in Peru or long range transport from the west. At a given altitude in the FT (up to 3 km), dew point varies by 40 °C with dry air descending from the upper atmospheric and moist air having a BL contribution. Ascent of BL air to a cold high altitude results in the condensation and precipitation removal of all but a few percent of BL water along with aerosol that served as CCN. Thus, aerosol volume decreases with dew point in the FT. Aerosol size spectra have a bimodal structure in the MBL and an intermediate diameter unimodal distribution in the FT. Comparing cloud droplet number concentration (CDNC) and pre-cloud aerosol (Dp > 100 nm) gives a linear relation up to a number concentration of ~150 cm-3, followed by a less than proportional increase in CDNC at higher aerosol number concentration. A number balance between below cloud aerosol and cloud droplets indicates that ~25 % of aerosol in the PCASP size range are interstitial (not activated). One hundred and two constant altitude cloud transects were identified and used to determine properties of interstitial aerosol. One transect is examined in detail as a case study. Approximately 25 to 50 % of aerosol with Dp > 110 nm were not activated, the difference between the two approaches possibly representing

  15. Aerosol concentration and size distribution measured below, in, and above cloud from the DOE G-1 during VOCALS-REx

    SciTech Connect

    Kleinman L. I.; Daum, P. H.; Lee, Y.-N.; Lewis, E. R.; Sedlacek III, A. J.; Senum, G. I.; Springston, S. R.; Wang, J.; Hubbe, J.; Jayne, J.; Min, Q.; Yum, S. S.; Allen, G.

    2012-01-04

    During the VOCALS Regional Experiment, the DOE G-1 aircraft was used to sample a varying aerosol environment pertinent to properties of stratocumulus clouds over a longitude band extending 800 km west from the Chilean coast at Arica. Trace gas and aerosol measurements are presented as a function of longitude, altitude, and dew point in this study. Spatial distributions are consistent with an upper atmospheric source for O{sub 3} and South American coastal sources for marine boundary layer (MBL) CO and aerosol, most of which is acidic sulfate. Pollutant layers in the free troposphere (FT) can be a result of emissions to the north in Peru or long range transport from the west. At a given altitude in the FT (up to 3 km), dew point varies by 40 C with dry air descending from the upper atmospheric and moist air having a boundary layer (BL) contribution. Ascent of BL air to a cold high altitude results in the condensation and precipitation removal of all but a few percent of BL water along with aerosol that served as CCN. Thus, aerosol volume decreases with dew point in the FT. Aerosol size spectra have a bimodal structure in the MBL and an intermediate diameter unimodal distribution in the FT. Comparing cloud droplet number concentration (CDNC) and pre-cloud aerosol (D{sub p} > 100 nm) gives a linear relation up to a number concentration of {approx}150 cm{sup -3}, followed by a less than proportional increase in CDNC at higher aerosol number concentration. A number balance between below cloud aerosol and cloud droplets indicates that {approx}25 % of aerosol with D{sub p} > 100 nm are interstitial (not activated). A direct comparison of pre-cloud and in-cloud aerosol yields a higher estimate. Artifacts in the measurement of interstitial aerosol due to droplet shatter and evaporation are discussed. Within each of 102 constant altitude cloud transects, CDNC and interstitial aerosol were anti-correlated. An examination of one cloud as a case study shows that the

  16. The impact of extreme precipitation on plant growth and water relations

    NASA Astrophysics Data System (ADS)

    Zeppel, M.; Lehmann, C.; Lewis, J. D.; Medlyn, B. E.

    2012-12-01

    Background The global hydrological cycle is predicted to become more intense, or extreme in future climates, with both larger precipitation events and longer times between events. The resulting wide fluctuations in soil water content (long droughts followed by flooding) may dramatically affect terrestrial ecosystems. Although effects of drought are well studied, tree responses to changed timing of precipitation are mostly unknown. Further, in future extreme precipitation is likely to occur in conjunction with elevated atmospheric CO2 concentrations [CO2]. We tested the impact of extreme precipitation and elevated [CO2] on plant growth and water relations. Methods/results Ten Acacia auriculiformis and Eucalyptus tetradonta saplings were grown in glasshouses, with ambient (380 p.p.m.) and elevated (600 p.p.m.) [CO2] and subject to ambient (1L weekly) and extreme (2L fortnightly) watering conditions (four treatments). We tested whether: (1) plants would show differential water stress and growth under extreme precipitation compared with ambient water treatments; and (2) plants would show differential water stress and growth responses under elevated compared with ambient [CO2] treatments. We found that the extreme precipitation, compared to ambient precipitation, lead to more water stressed plants, with more negative leaf water potential and lower stomatal conductance in both species. Further, plants experiencing extreme precipitation had a higher proportion of root volume at depth within the Eucalyptus. In contrast, the root depth of Acacia was similar across all treatments. Leaf area was smaller in extreme precipitation compared with ambient for Acacias, whereas leaf area was comparable across watering treatments in Eucalypts. Elevated CO2 had no impact on leaf water potential, stomatal conductance during the day or proportion of root depth. The Acacia, from tropical dry forest ecosystems, showed more signs of water stress (more negative leaf water potential and lower

  17. Validation of MODIS Total Precipitable Water Using Surface GPS Technology

    NASA Astrophysics Data System (ADS)

    Serra, Y. L.; Fears, A. J.; Moker, J.

    2014-12-01

    In this research we validate estimates of atmospheric total precipitable water (TPW) from the MODIS (Moderate Resolution Imaging Spectroradiometer) instruments onboard the Terra and Aqua satellites using surface Global Positioning System (GPS) derived TPW collected at ten stations across northwest Mexico during the 2013 North American monsoon (NAM) season. The MODIS Level 2 products provide TPW estimated from both the infrared (IR) and near-infrared (NIR) spectral bands and are available over the NAM region approximately twice per day. Our comparisons indicate that the correlations of Terra and Aqua IR TPW with the GPS observations are all significant at the 95% confidence level, while the NIR correlations show little or no significance. The analysis also finds that Terra and Aqua have significant seasonal biases with respect to the GPS for both the IR and NIR estimates at several locations, with the IR estimates showing better agreement than the NIR estimates. The dependence of the errors on elevation and time of overpass will be discussed to help identify contributing factors to the observed errors.

  18. Enhanced precipitation variability effects on water losses and ecosystem

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Climate change will result in increased precipitation variability with more extreme events reflected in more frequent droughts as well as more frequent extremely wet conditions. The increase in precipitation variability will occur at different temporal scales from intra to inter-annual and even long...

  19. Trends in precipitation and stream-water chemistry in the northeastern United States, water years 1984-96

    USGS Publications Warehouse

    Clow, D.W.; Mast, M. Alisa

    1999-01-01

    Trends in precipitation and stream-water chemistry during water years 1984-96 were examined at eight precipitation monitoring sites and five nearby streams operated by the U.S. Geological Survey in the northeastern United States. The statistical analyses indicate the following: 1)Stream-water sulfate (SO4) concentrations decreased at seven of eight precipitation monitoring sites and in each of five streams. 2)Calcium plus magnesium (Ca + Mg) concentrations decreased at seven of eight precipitation monitoring sites and in three of five streams. 3)Precipitation acidity decreased at five of eight precipitation monitoring sites, but alkalinity increased in only one stream. These results indicate that decreases in atmospheric deposition of SO4 have resulted in decreased precipitation acidity. The chemical response of stream water to changes in precipitation chemistry was complex. Decreases in stream-water SO4 concentrations generally matched decreases of precipitation SO4. In stream water, increases in alkalinity were uncommon because decreases in SO4 concentrations often were accompanied by decreases in Ca + Mg concentrations. The decreases in Ca + Mg concentrations might be related to depletion of base cations from soil caused by long-term exposure to acidic deposition. Increases in streamwater alkalinity might not occur until rates of acidic deposition are reduced to substantially less than the rate of cation resupply by weathering and atmospheric deposition. In areas where forests are aggrading, recovery of stream-water alkalinity will be delayed further because of the acidifying effect of biomass accumulation.

  20. Validating Above-cloud Aerosol Optical Depth Retrieved from MODIS using NASA Ames Airborne Sun-Tracking Photometric and Spectrometric (AATS and 4STAR) Measurements

    NASA Astrophysics Data System (ADS)

    Jethva, H. T.; Torres, O.; Remer, L. A.; Redemann, J.; Dunagan, S. E.; Livingston, J. M.; Shinozuka, Y.; Kacenelenbogen, M. S.; Segal-Rosenhaimer, M.

    2014-12-01

    Absorbing aerosols produced from biomass burning and dust outbreaks are often found to overlay the lower level cloud decks as evident in the satellite images. In contrast to the cloud-free atmosphere, in which aerosols generally tend to cool the atmosphere, the presence of absorbing aerosols above cloud poses greater potential of exerting positive radiative effects (warming) whose magnitude directly depends on the aerosol loading above cloud, optical properties of clouds and aerosols, and cloud fraction. In recent years, development of algorithms that exploit satellite-based passive measurements of ultraviolet (UV), visible, and polarized light as well as lidar-based active measurements constitute a major breakthrough in the field of remote sensing of aerosols. While the unprecedented quantitative information on aerosol loading above cloud is now available from NASA's A-train sensors, a greater question remains ahead: How to validate the satellite retrievals of above-cloud aerosols (ACA)? Direct measurements of ACA such as carried out by the NASA Ames Airborne Tracking Sunphotometer (AATS) and Spectrometer for Sky-Scanning, Sun-Tracking Atmospheric Research (4STAR) can be of immense help in validating ACA retrievals. In this study, we validate the ACA optical depth retrieved using the 'color ratio' (CR) method applied to the MODIS cloudy-sky reflectance by using the airborne AATS and 4STAR measurements. A thorough search of the historic AATS-4STAR database collected during different field campaigns revealed five events where biomass burning, dust, and wildfire-emitted aerosols were found to overlay lower level cloud decks observed during SAFARI-2000, ACE-ASIA 2001, and SEAC4RS-2013, respectively. The co-located satellite-airborne measurements revealed a good agreement (root-mean-square-error<0.1 for Aerosol Optical Depth (AOD) at 500 nm) with most matchups falling within the estimated uncertainties in the MODIS retrievals (-10% to +50%). An extensive validation of

  1. DIURNAL CYCLE OF PRECIPITABLE WATER VAPOR OVER SPAIN

    SciTech Connect

    Ortiz de Galisteo, J. P.; Cachorro, V. E.; Toledano, C.; Torres, B.; Laulainen, Nels S.; Bennouna, Yasmine; de Frutos, A. M.

    2011-05-20

    Despite the importance of the diurnal cycle of precipitable water vapor (PWV), its knowledge is very limited due to the lack of data with sufficient temporal resolution. Currently, from GPS receivers, PWV can be obtained with high temporal resolution in all weather conditions for all hours of the day. In this study we have calculated the diurnal cycle of PWV for ten GPS stations over Spain. The minimum value is reached approximately at the same time at all the stations, ~0400-0500 UTC, whereas the maximum is reached in the second half of the day, but with a larger dispersion of its occurrence between stations. The amplitude of the cycle ranges between 0.72 mm and 1.78 mm. The highest values are recorded at the stations on the Mediterranean coast, with a doubling of the values of the stations on the Atlantic coast or inland. The amplitude of the PWV cycle, relative to the annual mean value, ranges between 8.8 % on the Mediterranean coast and 3.6 % on the Atlantic coast. Two distinctly different seasonal diurnal cycles have been identified, one in winter and other in summer, with spring and autumn being only transition states. The winter cycle is quite similar at all locations, whereas in summer, local effects are felt strongly, making the diurnal cycle quite different between stations. The amplitude of the summer cycle is 1.69 mm, it is almost double the winter one (0.93 mm). Analogous to the annual cycles, the seasonal cycles of the different stations are more similar during the night and early morning hours than during the afternoon. The observed features of the PWV diurnal cycle are explained in a qualitative way on the basis of the air temperature, the transport of moisture by local winds, and the turbulent vertical mixing.

  2. On the Vertical Distribution of Local and Remote Sources of Water for Precipitation

    NASA Technical Reports Server (NTRS)

    Bosilovich, Michael G.

    2001-01-01

    The vertical distribution of local and remote sources of water for precipitation and total column water over the United States are evaluated in a general circulation model simulation. The Goddard Earth Observing System (GEOS) general circulation model (GCM) includes passive constituent tracers to determine the geographical sources of the water in the column. Results show that the local percentage of precipitable water and local percentage of precipitation can be very different. The transport of water vapor from remote oceanic sources at mid and upper levels is important to the total water in the column over the central United States, while the access of locally evaporated water in convective precipitation processes is important to the local precipitation ratio. This result resembles the conceptual formulation of the convective parameterization. However, the formulations of simple models of precipitation recycling include the assumption that the ratio of the local water in the column is equal to the ratio of the local precipitation. The present results demonstrate the uncertainty in that assumption, as locally evaporated water is more concentrated near the surface.

  3. Validating MODIS above-cloud aerosol optical depth retrieved from "color ratio" algorithm using direct measurements made by NASA's airborne AATS and 4STAR sensors

    NASA Astrophysics Data System (ADS)

    Jethva, Hiren; Torres, Omar; Remer, Lorraine; Redemann, Jens; Livingston, John; Dunagan, Stephen; Shinozuka, Yohei; Kacenelenbogen, Meloe; Segal Rosenheimer, Michal; Spurr, Rob

    2016-10-01

    We present the validation analysis of above-cloud aerosol optical depth (ACAOD) retrieved from the "color ratio" method applied to MODIS cloudy-sky reflectance measurements using the limited direct measurements made by NASA's airborne Ames Airborne Tracking Sunphotometer (AATS) and Spectrometer for Sky-Scanning, Sun-Tracking Atmospheric Research (4STAR) sensors. A thorough search of the airborne database collection revealed a total of five significant events in which an airborne sun photometer, coincident with the MODIS overpass, observed partially absorbing aerosols emitted from agricultural biomass burning, dust, and wildfires over a low-level cloud deck during SAFARI-2000, ACE-ASIA 2001, and SEAC4RS 2013 campaigns, respectively. The co-located satellite-airborne matchups revealed a good agreement (root-mean-square difference < 0.1), with most matchups falling within the estimated uncertainties associated the MODIS retrievals (about -10 to +50 %). The co-retrieved cloud optical depth was comparable to that of the MODIS operational cloud product for ACE-ASIA and SEAC4RS, however, higher by 30-50 % for the SAFARI-2000 case study. The reason for this discrepancy could be attributed to the distinct aerosol optical properties encountered during respective campaigns. A brief discussion on the sources of uncertainty in the satellite-based ACAOD retrieval and co-location procedure is presented. Field experiments dedicated to making direct measurements of aerosols above cloud are needed for the extensive validation of satellite-based retrievals.

  4. How Do A-train Sensors Intercompare in the Retrieval of Above-cloud Aerosol Optical Depth? A Case Study-based Assessment

    NASA Technical Reports Server (NTRS)

    Jethva, Hiren; Torres, Omar; Waquet, Fabien; Chand, Duli; Hu, Yongxiang

    2014-01-01

    We intercompare the above-cloud aerosol optical depth (ACAOD) of biomass burning plumes retrieved from A-train sensors, i.e., Moderate Resolution Imaging Spectroradiometer (MODIS), Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP), Polarization and Directionality of Earth Reflectances (POLDER), and Ozone Monitoring Instrument (OMI). These sensors have shown independent capabilities to retrieve aerosol loading above marine boundary layer clouds-a kind of situation often found over the southeast Atlantic Ocean during dry burning season. A systematic comparison reveals that all passive sensors and CALIOP-based research methods derive comparable ACAOD with differences mostly within 0.2 over homogeneous cloud fields. The 532 nm ACAOD retrieved by CALIOP operational algorithm is underestimated. The retrieved 1064 nm AOD however shows closer agreement with passive sensors. Given the different types of measurements processed with different algorithms, the reported close agreement between them is encouraging. Due to unavailability of direct measurements above cloud, the validation of satellite-based ACAOD remains an open challenge. The intersatellite comparison however can be useful for the relative evaluation and consistency check

  5. How do A-train Sensors Inter-Compare in the Retrieval of Above-Cloud Aerosol Optical Depth? A Case Study based Assessment

    NASA Astrophysics Data System (ADS)

    Jethva, H. T.; Torres, O.; Waquet, F.; Chand, D.

    2013-12-01

    Atmospheric aerosols are known to produce a net cooling effect in the cloud-free conditions. However, when present over the reflective cloud decks, absorbing aerosols such as biomass burning generated smoke and wind-blown dust can potentially exert a large positive forcing through enhanced atmospheric heating resulting from cloud-aerosol radiative interactions. The interest on this aspect of aerosol science has grown significantly in the recent years. Particularly, development of the satellite-based retrieval techniques and unprecedented knowledge on the above-cloud aerosol optical depth (ACAOD) is of great relevance. A direct validation of satellite ACAOD is a difficult task primarily due to lack of ample in situ and/or remote sensing measurements of aerosols above cloud. In these circumstances, a comparative analysis on the inter-satellite ACAOD retrievals can be performed for the sack of consistency check. Here, we inter-compare the ACAOD of biomass burning plumes observed from different A-train sensors, i.e., MODIS [Jethva et al., 2013], CALIOP [Chand et al., 2008], POLDER [Waquet et al., 2009], and OMI [Torres et al., 2012]. These sensors have been shown to acquire sensitivity and independent capabilities to detect and retrieve aerosol loading above marine stratocumulus clouds--a kind of situation often found over the southeastern Atlantic Ocean during dry burning season. A systematic one-to-one comparison reveals that, in general, all passive sensors and CALIOP-based research methods retrieve comparable ACAOD over homogeneous cloud fields. The high-resolution sensors (MODIS and CALIOP) are able to retrieve aerosols over thin clouds but with larger discrepancies. Given the different types of sensor measurements processed with different algorithms, a reasonable agreement between them is encouraging. A direct validation of satellite-based ACAOD remains an open challenge for which dedicated field measurements over the region of frequent aerosol/cloud overlap are

  6. [Hydrogen and Oxygen Isotopic Compositions of Precipitation and Its Water Vapor Sources in Eastern Qaidam Basin].

    PubMed

    Zhu, Jian-jia; Chen, Hui; Gong, Guo-li

    2015-08-01

    Stable hydrogen and oxygen isotopes can be used as a tracer to analyze water vapor sources of atmospheric precipitation. We choose Golmud and Delingha as our study areas, Golmud locates in the south of Qaidam basin, and Delingha locates in the northeast. Based on the analysis of monthly change of hydrogen and oxygen isotopic compositions of precipitation during June to September of 2010, and the relationship between deltaD and delta18O in precipitation, we investigated the water vapor sources of precipitation in eastern Qaidam basin. The results show that: (1) meteoric water line between June to September in Golmud is: deltaD = 7.840 delta18O - 4.566 (R2 = 0.918, P < 0.001), and in Delingha is: deltaD = 7.833 delta18O + 8.606 (R2 = 0.986, P < 0.001). The slopes and intercepts of meteoric water line between June to September in both Golmud and Delingha are lower than the global average, and the intercept in Golmud is only -4.566, which indicates the extremely arid climate condition. (2) the delta18O content of precipitation is much higher in Golmud in early July, it shows the enrichment of some heavier isotopes. However, the delta18O content of precipitation becomes lower from late July to early September, especially for the late September. The 8180 content of precipitation in Delingha is higher in June to August than that in late September. (3) the water vapor sources of precipitation in Golmud and Delingha are different, Golmud area is the northern border of Qinghai-Tibet Plateau where the southwest monsoon can reach, and the southwest monsoon brings water vapors of precipitation, but the water vapors of precipitation in Delingha are mainly from local evaporation.

  7. Solvation agent for disulfide precipitates from inhibited glycol-water solutions

    NASA Technical Reports Server (NTRS)

    Taylor, M. F.

    1971-01-01

    Small additions /0.01 percent or less/ of triethanoloamine sodium sulfite adduct to mercapto benzothiazole inhibited glycol water heat transfer solutions containing disulfide precipitate produce marked reduction in amount of precipitate. Adduct is useful as additive in glycol base antifreezes and coolants.

  8. Trends in the chemistry of precipitation and surface water in a national network of small watersheds

    USGS Publications Warehouse

    Aulenbach, Brent T.; Hooper, R.P.; Bricker, O.P.

    1996-01-01

    Trends in precipitation and surface water chemistry at a network of 15 small watersheds ( < 10 km2) in the USA were evaluated using a statistical test for monotonic trends (the seasonal Kendall test) and a graphical smoothing technique for the visual identification of trends. Composite precipitation samples were collected weekly and surface water samples were collected at least monthly. Concentrations were adjusted before trend analysis, by volume for precipitation samples and by flow for surface water samples. A relation between precipitation and surface water trends was not evident either for individual inorganic solutes or for solute combinations, such as ionic strength, at most sites. The only exception was chloride, for which there was a similar trend at 60% of the sites. The smoothing technique indicated that short-term patterns in precipitation chemistry were not reflected in surface waters. The magnitude of the short-term variations in surface water concentration was generally larger than the overall long-term trend, possibly because flow adjustment did not adequately correct for climatic variability. Detecting the relation between precipitation and surface water chemistry trends may be improved by using a more powerful sampling strategy and by developing better methods of concentration adjustment to remove the effects of natural variation in surface waters.

  9. Importance of Dry-Season Precipitation to the Water Resources of Monteverde, Costa Rica

    NASA Astrophysics Data System (ADS)

    Guswa, A. J.; Rhodes, A. L.

    2005-12-01

    Monteverde, Costa Rica harbors montane forests that exemplify the delicate balances among climate, hydrology, habitat, and development. Most of the annual precipitation to this region arrives during the wet season, but the importance of orographic precipitation during the dry and transitional seasons should not be underestimated. Changes in regional land-cover and global climate may lead to reduced precipitation and cloud cover and a subsequent decline in endemic species, and a boom in ecotourism has put stress on water resources. A recent attempt to withdraw water from a local stream led to a standoff between conservationists and business developers, and there is a clear need for hydrologic data and understanding in support of policy. Through signals observed in the stable isotopic composition of precipitation and streamflow, we seek to understand how precipitation from the drier seasons propagates through the hydrologic cycle. In precipitation, δ18O and δ2H are heaviest during the dry and transitional seasons and light during the rainy season, consistent with the condensation mechanisms and degree of rainout typical of these periods. The signal in d-excess indicates a contribution of recycled water to precipitation in Monteverde from late in the rainy season through the dry season. Attenuated versions of these seasonal signals propagate through to the stream samples and provide a means of determining the importance of dry-season precipitation to water resources for the region. Results from six catchments on the leeward slope indicate that the Brillante Gap in the continental divide exerts strong control on the input of orographic precipitation to the region. Disparities in the temporal signals of precipitation and streamflow isotopes indicate non-linear behavior in the hydrologic processes that move water through these catchments.

  10. Exploring geophysical processes influencing U.S. West Coast precipitation and water supply

    USGS Publications Warehouse

    Ralph, F.M.; Prather, K.; Cayan, D.

    2011-01-01

    CalWater Science Workshop; La Jolla, California, 8-10 June 2011 CalWater is a multiyear, multiagency research project with two primary research themes: the effects of changing climate on atmospheric rivers (ARs) and associated extreme events, and the potential role of aerosols in modulating cloud properties and precipitation, especially regarding orographic precipitation and water supply. Advances made in CalWater have implications for both water supply and flood control in California and other West Coast areas, both in the near term and in a changing climate.

  11. Exploring geophysical processes influencing U.S. West Coast precipitation and water supply

    NASA Astrophysics Data System (ADS)

    Ralph, F. Martin; Prather, Kim; Cayan, Dan

    2011-10-01

    CalWater Science Workshop; La Jolla, California, 8-10 June 2011 CalWater is a multiyear, multiagency research project with two primary research themes: the effects of changing climate on atmospheric rivers (ARs) and associated extreme events, and the potential role of aerosols in modulating cloud properties and precipitation, especially regarding orographic precipitation and water supply. Advances made in CalWater have implications for both water supply and flood control in California and other West Coast areas, both in the near term and in a changing climate.

  12. The removal of sulphate from mine water by precipitation as ettringite and the utilisation of the precipitate as a sorbent for arsenate removal.

    PubMed

    Tolonen, Emma-Tuulia; Hu, Tao; Rämö, Jaakko; Lassi, Ulla

    2016-10-01

    The aim of this research was to investigate sulphate removal from mine water by precipitation as ettringite (Ca6Al2(SO4)3(OH)12·26H2O) and the utilisation of the precipitate as a sorbent for arsenate removal. The mine water sulphate concentration was reduced by 85-90% from the initial 1400 mg/L during ettringite precipitation depending on the treatment method. The precipitation conditions were also simulated with MINEQL + software, and the computational results were compared with the experimental results. The precipitated solids were characterised with X-ray diffraction and a scanning electron microscope. The precipitated solids were tested as sorbents for arsenate removal from the model solution. The arsenic(V) model solution concentration reduced 86-96% from the initial 1.5 mg/L with a 1 g/L sorbent dosage. The effect of initial arsenate concentration on the sorption of arsenate on the precipitate was studied and Langmuir, Freundlich, and Langmuir-Freundlich sorption isotherm models were fitted to the experimental data. The maximum arsenate sorption capacity (qm = 11.2 ± 4.7 mg/g) of the precipitate was obtained from the Langmuir-Freundlich isotherm. The results indicate that the precipitate produced during sulphate removal from mine water by precipitation as ettringite could be further used as a sorbent for arsenate removal.

  13. Global aerosol typing from a combination of A-Train satellite observations in clear-sky and above clouds

    NASA Astrophysics Data System (ADS)

    Kacenelenbogen, M. S.; Russell, P. B.; Vaughan, M.; Redemann, J.; Shinozuka, Y.; Livingston, J. M.; Zhang, Q.

    2014-12-01

    According to the 5th Assessment Report of the Intergovernmental Panel on Climate Change (IPCC), the model estimates of Radiative Forcing due to aerosol-radiation interactions (RFari) for individual aerosol types are less certain than the total RFari [Boucher et al., 2013]. For example, the RFari specific to Black Carbon (BC) is uncertain due to an underestimation of its mass concentration near source regions [Koch et al., 2009]. Several recent studies have evaluated chemical transport model (CTM) predictions using observations of aerosol optical properties such as Aerosol Optical Depth (AOD) or Single Scattering Albedo (SSA) from satellite or ground-based instruments (e.g., Huneeus et al., [2010]). However, most passive remote sensing instruments fail to provide a comprehensive assessment of the particle type without further analysis and combination of measurements. To improve the predictions of aerosol composition in CTMs, we have developed an aerosol classification algorithm (called Specified Clustering and Mahalanobis Classification, SCMC) that assigns an aerosol type to multi-parameter retrievals by spaceborne, airborne or ground based passive remote sensing instruments [Russell et al., 2014]. The aerosol types identified by our scheme are pure dust, polluted dust, urban-industrial/developed economy, urban-industrial/developing economy, dark biomass smoke, light biomass smoke and pure marine. First, we apply the SCMC method to five years of clear-sky space-borne POLDER observations over Greece. We then use the aerosol extinction and SSA spectra retrieved from a combination of MODIS, OMI and CALIOP clear-sky observations to infer the aerosol type over the globe in 2007. Finally, we will extend the spaceborne aerosol classification from clear-sky to above low opaque water clouds using a combination of CALIOP AOD and backscatter observations and OMI absorption AOD values from near-by clear-sky pixels.

  14. Distribution of tritium in water vapour and precipitation around Wolsung nuclear power plant.

    PubMed

    Chae, Jung-Seok; Lee, Sang-Kuk; Kim, Yongjae; Lee, Jung-Min; Cho, Heung-Joon; Cho, Yong-Woo; Yun, Ju-Yong

    2011-07-01

    The distribution of tritium in water vapour and precipitation with discharge of tritiated water vapour and meteorological factors was studied around the Wolsung nuclear power plant (NPP) site during the period 2004-2008. The tritium concentrations in atmospheric water vapour and precipitation had a temporal variation with relatively high values in the early summer. Spatial distribution of tritium concentrations was affected by various factors such as distance from the NPP site, wind direction, tritium discharge into the atmosphere and atmospheric dispersion factor. The annual mean concentrations of atmospheric HTO and precipitation were correlated with the amount of gaseous tritium released from the Wolsung NPP. The tritium concentrations in precipitation decrease exponentially with an increase of the distance from the Wolsung NPP site.

  15. Tritium and Stable Isotopes of Precipitation and Surface Water in California

    NASA Astrophysics Data System (ADS)

    Harms, P.; Moran, J. E.; Visser, A.; Esser, B. K.

    2014-12-01

    Tritium (3H) and stable isotopes (2H and 18O) are effective natural tracers of water molecules through the hydrologic system. The strong topographic gradient in California results in distinct isotopic signatures that are particularly effective in watershed studies. Past studies of meteoric tritium distribution within the United States have focused on large-scale trends, at low spatial resolution. Globally, tritium in precipitation is monitored by the International Atomic Energy Agency contributing to the Global Network of Isotopes in Precipitation (GNIP) database. The two tritium monitoring stations in California contributing to the GNIP database were discontinued in 1976 (Santa Maria) and 1993 (Menlo Park). Surface water studies have focused on time series in major rivers nationwide or localized studies. Our study focuses on high spatial resolution water isotope data collection in California. Over 140 tritium and stable water isotope samples were collected from surface water and direct precipitation during the 2013 Summer/Fall and 2014 Winter/Spring flow regimes and analyzed by helium accumulation and noble gas mass spectrometry. Surface water samples are collected as a proxy for precipitation and to investigate trends related to water residence times. Tritium concentrations in precipitation show strong spatial trends, with higher concentrations at inland high elevation locations. Surface water tritium trends with spatial location (latitude and longitude) and elevation (reflecting the precipitation signal) and distance downstream (reflecting water residence times). A local meteoric water line (MWL) for California is developed from stable isotope data and analyzed in comparison to the global MWL. Results have implications for tritium tracer and water provenance studies.

  16. Warming combined with more extreme precipitation regimes modifies the water sources used by trees.

    PubMed

    Grossiord, Charlotte; Sevanto, Sanna; Dawson, Todd E; Adams, Henry D; Collins, Adam D; Dickman, Lee T; Newman, Brent D; Stockton, Elizabeth A; McDowell, Nate G

    2017-01-01

    The persistence of vegetation under climate change will depend on a plant's capacity to exploit water resources. We analyzed water source dynamics in piñon pine and juniper trees subjected to precipitation reduction, atmospheric warming, and to both simultaneously. Piñon and juniper exhibited different and opposite shifts in water uptake depth in response to experimental stress and background climate over 3 yr. During a dry summer, juniper responded to warming with a shift to shallow water sources, whereas piñon pine responded to precipitation reduction with a shift to deeper sources in autumn. In normal and wet summers, both species responded to precipitation reduction, but juniper increased deep water uptake and piñon increased shallow water uptake. Shifts in the utilization of water sources were associated with reduced stomatal conductance and photosynthesis, suggesting that belowground compensation in response to warming and water reduction did not alleviate stress impacts for gas exchange. We have demonstrated that predicted climate change could modify water sources of trees. Warming impairs juniper uptake of deep sources during extended dry periods. Precipitation reduction alters the uptake of shallow sources following extended droughts for piñon. Shifts in water sources may not compensate for climate change impacts on tree physiology.

  17. Importance of orographic precipitation to the water resources of Monteverde, Costa Rica

    NASA Astrophysics Data System (ADS)

    Guswa, Andrew J.; Rhodes, Amy L.; Newell, Silvia E.

    2007-10-01

    Monteverde, Costa Rica harbors montane forests that exemplify the delicate balances among climate, hydrology, habitat, and development. Most of the annual precipitation to this region arrives during the wet season, but the importance of orographic precipitation during the dry and transitional seasons should not be underestimated. Development associated with ecotourism has put significant stress on water resources, and recent work has shown evidence that changes in regional land-cover and global climate may lead to reduced precipitation and cloud cover and a subsequent decline in endemic species. Precipitation samples collected from 2003 to 2005 reveal a seasonal signal in stable isotope composition, as measured by δ 18O and δ 2H, that is heaviest during the dry and transitional seasons. Attenuated versions of this signal propagate through to stream samples and provide a means of determining the importance of precipitation delivered by the trade winds during the dry and transitional seasons to water resources for the region. Results from six catchments on the leeward slope indicate that topography exerts a strong control on the importance of orographic precipitation to stream baseflow. The contributions are greatest in those catchments that are close to the Brillante Gap in the Continental Divide. Differences in the temporal variation of precipitation and streamflow isotope compositions provide insight to the hydrologic pathways that move water to the streams.

  18. Precipitation patterns and moisture fluxes in a sandy, tropical environment with a shallow water table

    NASA Astrophysics Data System (ADS)

    Minihane, M. R.; Freyberg, D. L.

    2011-08-01

    Identifying the dominant mechanisms controlling recharge in shallow sandy soils in tropical climates has received relatively little attention. Given the expansion of coastal fill using marine sands and the growth of coastal populations throughout the tropics, there is a need to better understand the nature of water balances in these settings. We use time series of field observations at a coastal landfill in Singapore coupled with numerical modeling using the Richards' equation to examine the impact of precipitation patterns on soil moisture dynamics, including percolation past the root zone and recharge, in such an environment. A threshold in total precipitation event depth, much more so than peak precipitation intensity, is the strongest event control on recharge. However, shallow antecedent moisture, and therefore the timing between events along with the seasonal depth to water table, also play significant roles in determining recharge amounts. For example, at our field site, precipitation events of less than 3 mm per event yield little to no direct recharge, but for larger events, moisture content changes below the root zone are linearly correlated to the product of the average antecedent moisture content and the total event precipitation. Therefore, water resources planners need to consider identifying threshold precipitation volumes, along with the multiple time scales that capture variability in event antecedent conditions and storm frequency in assessing the role of recharge in coastal water balances in tropical settings.

  19. Remote sensing of precipitable water over the oceans from Nimbus-7 microwave measurements

    NASA Technical Reports Server (NTRS)

    Prabhakara, C.; Change, H. D.; Chang, A. T. C.

    1981-01-01

    Global maps of precipitable water over derived from scanning multichannel microwave radiometer (SMMR) data reveal salient features associated with ocean currents and the large scale general circulation in the atmosphere. Nimbus-7 SMMR brightness temperature measurements in the 21 and 18 GHz channels are used to sense the precipitable water in the atmospheric over oceans. The difference in the brightness temperature (T sub 21 -T sub 18), both in the horizontal and vertical polarization, is found to be essentially a function of the precipitable water in the atmosphere. An equation, based on the physical consideration of the radiative transfer in the microwave region, is developed to relate the precipitable water to (T sub 21 - T sub 18). It shows that the signal (T sub 21- T sub 18) does not suffer severely from the noise introduced by variations in the sea surface temperature, surface winds, and liquid water content in non rain clouds. The rms deviation between the estimated precipitable water from SMMR data and that given by the closely coincident ship radiosondes is about 0.25 g/ sq cm

  20. Prediction of Water-level Changes and Water Use in the High Plains Aquifer from Radar Precipitation

    NASA Astrophysics Data System (ADS)

    Whittemore, D. O.; Butler, J. J., Jr.; Wilson, B. B.

    2015-12-01

    Meteorological conditions are the primary driver of variations in the annual volume of groundwater pumped for irrigation from the High Plains aquifer (HPA), one of the largest aquifers of the world. Correlations between climatic indices (such as the Standardized Precipitation Index [SPI]) and mean annual water-level changes and water use have been shown to be valuable tools for assessing the aquifer's response to various climatic scenarios in the semi-arid Kansas HPA (Whittemore et al., 2015). The correlations are generally better for a relatively large area (region) of the aquifer (such as that encompassed by a climatic division) because of the number of weather stations from which the climatic indices are computed. Correlations can be poor for county-sized and smaller areas (less than a few to several hundred km2) because of the low density of weather stations. Since 2005, radar precipitation data have been served online by the National Weather Service. The radar data are adjusted based on ground observations and are available at a spatial resolution of ~4x4 km. Correlations between radar precipitation and mean annual water-level changes and water use are comparable to those using SPI for the same region. Correlations using radar precipitation data are generally higher than with SPI computed for smaller areas, such as for counties and areas around individual monitoring wells. The optimum correlations for radar precipitation are determined using sums of different spans of monthly mean precipitation that include the irrigation season for the area of interest. Coefficients of determination, R2, for radar precipitation versus annual water-level change and water use can exceed 0.8 for counties and monitoring well areas in the Kansas HPA. These correlations are being used to assess the impact of drought and water-use management on HPA sustainability. These correlations can also be used to assess the quality of the reported water-use data.

  1. Selective recovery of copper and zinc from mine dump waters of mining enterprises in precipitates

    NASA Astrophysics Data System (ADS)

    Orekhova, N. N.; Tarybaeva, G. A.; Muravev, D. S.

    2017-01-01

    The acid mine dump waters at mining companies that mining the copper and copperzinc sulphide ore have the high concentrates of metals and classified in our view as the raw materials for selective recovery of metals in precipitates comparable in quality with concentrates of ores enrichment and suitable for further metallurgical processing. Authors have implemented three two-stage schemes for sequential extraction of copper and zinc: cementation-sulphide precipitation, galvanocoagulation-sulphide precipitation, precipitation-precipitation. Moreover, parameters of processes and quality of the obtained precipitates have described. The achieved copper recovery is 89% and 94% respectively with the application of cementation and galvanocoagulation, in sulphide precipitate exceeded 75%. Furthermore, the copper recovery from decoppering in precipitates amounted to more than 65%. Zinc-containing precipitates because of coprecipitation of iron, magnesium and calcium contain zinc from 14% to 28%, in two to three times less than the quality of conditioned zinc concentrates. The content of precipitates allows to apply them for additional charging to concentrates of enrichment or for the production of metals in metallurgical treatment. As a result of the studying the effect of reduced total salinity (S) on mass fraction of zinc in precipitate (β) with the constant concentration of zinc (SZn), the changes in concentration with constant salinity and reduction in total salinity (S) with constant ratio S/CZn, the following dependencies have obtained: ≤ft( {{S}} \\right):{≤ft( {{{\\partial β } \\over {\\partial {cZn}}}} \\right)_S} > 0,{≤ft( {{{\\partial β } \\over {\\partial S}}} \\right){C_{Zn}}} < 0, in the range of an index S from 4.5 to 90.0 g/L {≤ft( {{{\\partial β } \\over {\\partial S}}} \\right){{{C_{Zn}} \\over S}}} < 0, where {≤ft( {{{\\partial x} \\over {\\partial y}}} \\right)_Z} is a partial derivative of x to y, whereas the value z is fixed.

  2. Real-time QEXAFS spectroscopy measures rapid precipitate formation at the mineral-water interface.

    PubMed

    Siebecker, Matthew; Li, Wei; Khalid, Syed; Sparks, Donald

    2014-09-19

    Reactions at the mineral-water interface are central to numerous geochemical processes and have consequences at local, regional and global scales. They are also important in materials science research. Kinetics greatly influences mineral-water interface reactions; however, there are few kinetic data in real-time and at the molecular scale. Here we report real-time data illustrating the rapid formation of nickel aluminium-layered double hydroxide precipitates at the mineral-water interface in a flow environment in as little as 31-40 min. Layered double hydroxides have a variety of applications in environmental remediation and materials science. The real-time data shown here enhance our fundamental understanding of the kinetics of mineral-water interface processes, such as adsorption, dissolution and precipitation, by illustrating their rapid and simultaneous occurrence in a dynamic environment. Both precipitation and adsorption can occur on the same rapid timescale.

  3. Warming combined with more extreme precipitation regimes modifies the water sources used by trees

    SciTech Connect

    Grossiord, Charlotte; Sevanto, Sanna; Dawson, Todd E.; Adams, Henry D.; Collins, Adam D.; Dickman, Lee T.; Newman, Brent D.; Stockton, Elizabeth A.; McDowell, Nate G.

    2016-09-09

    The persistence of vegetation under climate change will depend on a plant's capacity to exploit water resources. In addition, we analyzed water source dynamics in piñon pine and juniper trees subjected to precipitation reduction, atmospheric warming, and to both simultaneously.

  4. CalWater 2 - Precipitation, Aerosols, and Pacific Atmospheric Rivers Experiment

    NASA Astrophysics Data System (ADS)

    Spackman, J. R.; Ralph, F. M.; Prather, K. A.; Cayan, D. R.; DeMott, P. J.; Dettinger, M. D.; Fairall, C. W.; Leung, L. R.; Rosenfeld, D.; Rutledge, S. A.; Waliser, D. E.; White, A. B.

    2014-12-01

    Emerging research has identified two phenomena that play key roles in the variability of the water supply and the incidence of extreme precipitation events along the West Coast of the United States. These phenomena include the role of (1) atmospheric rivers (ARs) in delivering much of the precipitation associated with major storms along the U.S. West Coast, and (2) aerosols—from local sources as well as those transported from remote continents—and their modulating effects on western U.S. precipitation. A better understanding of these processes is needed to reduce uncertainties in weather predictions and climate projections of extreme precipitation and its effects, including the provision of beneficial water supply. This presentation summarizes the science objectives and strategies to address gaps associated with (1) the evolution and structure of ARs including cloud and precipitation processes and air-sea interaction, and (2) aerosol interaction with ARs and the impact on precipitation, including locally-generated aerosol effects on orographic precipitation along the U.S. West Coast. Observations are proposed for multiple winter seasons as part of a 5-year broad interagency vision referred to as CalWater 2 to address these science gaps (http://esrl.noaa.gov/psd/calwater). In January-February 2015, a field campaign has been planned consisting of a targeted set of aircraft and ship-based measurements and associated evaluation of data in near-shore regions of California and in the eastern Pacific. In close coordination with NOAA, DOE's Atmospheric Radiation Measurement (ARM) program is also contributing air and shipborne facilities for ACAPEX (ARM Cloud Aerosol and Precipitation Experiment), a DOE-sponsored study complementing CalWater 2. Ground-based measurements from NOAA's HydroMeteorological Testbed (HMT) network in California and aerosol chemical instrumentation at Bodega Bay, California have been designed to add important near surface-level context for the

  5. Seasonal transfer of oxygen isotopes from precipitation and soil to the tree ring: source water versus needle water enrichment.

    PubMed

    Treydte, Kerstin; Boda, Sonja; Graf Pannatier, Elisabeth; Fonti, Patrick; Frank, David; Ullrich, Bastian; Saurer, Matthias; Siegwolf, Rolf; Battipaglia, Giovanna; Werner, Willy; Gessler, Arthur

    2014-05-01

    For accurate interpretation of oxygen isotopes in tree rings (δ(18) O), it is necessary to disentangle the mechanisms underlying the variations in the tree's internal water cycle and to understand the transfer of source versus leaf water δ(18) O to phloem sugars and stem wood. We studied the seasonal transfer of oxygen isotopes from precipitation and soil water through the xylem, needles and phloem to the tree rings of Larix decidua at two alpine sites in the Lötschental (Switzerland). Weekly resolved δ(18) O records of precipitation, soil water, xylem and needle water, phloem organic matter and tree rings were developed. Week-to-week variations in needle-water (18) O enrichment were strongly controlled by weather conditions during the growing season. These short-term variations were, however, not significantly fingerprinted in tree-ring δ(18) O. Instead, seasonal trends in tree-ring δ(18) O predominantly mirrored trends in the source water, including recent precipitation and soil water pools. Modelling results support these findings: seasonal tree-ring δ(18) O variations are captured best when the week-to-week variations of the leaf water signal are suppressed. Our results suggest that climate signals in tree-ring δ(18) O variations should be strongest at temperate sites with humid conditions and precipitation maxima during the growing season.

  6. Evaporation tagging and atmospheric water budget analysis with WRF: A regional precipitation recycling study for West

    NASA Astrophysics Data System (ADS)

    Arnault, Joel; Knoche, Richard; Wei, Jianhui; Kunstmann, Harald

    2016-04-01

    Regional precipitation recycling is the measure of the contribution of local evaporation E to local precipitation. This study provides a set of two methods developed in the Weather Research and Forecasting WRF model system for investigating regional precipitation recycling mechanisms: (1) tracking of tagged atmospheric water species originating from evaporation in a source region, ie E-tagging, and (2) three-dimensional budgets of total and tagged atmospheric water species. These methods are used to quantify the effect of return flow and non-well vertical mixing neglected in the computation of the bulk precipitation recycling ratio. The developed algorithms are applied to a WRF simulation of the West African Monsoon 2003. The simulated region is characterized by vertical wind shear condition, i.e. southwesterlies in the low levels and easterlies in the mid-levels, which favours return flow and non-well vertical mixing. Regional precipitation recycling is investigated in 100x100 and 1000x1000 km2 areas. A prerequisite condition for evaporated water to contribute to the precipitation process in both areas is that it is lifted to the mid-levels where hydrometeors are produced. In the 100x100 (1000x1000) km2 area the bulk precipitation recycling ratio is 0.9 (7.3) %. Our budget analysis reveals that return flow and non-well vertically mixed outflow increase this value by about +0.2 (2.9) and +0.2 (1.6) %, respectively, thus strengthening the well-known scale-dependency of regional precipitation recycling.

  7. A Novel Method for Estimating Shortwave Direct Radiative Effect of Above-cloud Aerosols over Ocean Using CALIOP and MODIS Data

    NASA Technical Reports Server (NTRS)

    Zhang, Z.; Meyer, K.; Platnick, S.; Oreopoulos, L.; Lee, D.; Yu, H.

    2013-01-01

    This paper describes an efficient and unique method for computing the shortwave direct radiative effect (DRE) of aerosol residing above low-level liquid-phase clouds using CALIOP and MODIS data. It accounts for the overlapping of aerosol and cloud rigorously by utilizing the joint histogram of cloud optical depth and cloud top pressure. Effects of sub-grid scale cloud and aerosol variations on DRE are accounted for. It is computationally efficient through using grid-level cloud and aerosol statistics, instead of pixel-level products, and a pre-computed look-up table in radiative transfer calculations. We verified that for smoke over the southeast Atlantic Ocean the method yields a seasonal mean instantaneous shortwave DRE that generally agrees with more rigorous pixel-level computation within 4%. We have also computed the annual mean instantaneous shortwave DRE of light-absorbing aerosols (i.e., smoke and polluted dust) over global ocean based on 4 yr of CALIOP and MODIS data. We found that the variability of the annual mean shortwave DRE of above-cloud light-absorbing aerosol is mainly driven by the optical depth of the underlying clouds.

  8. CCN and IN Effects on Cloud Properties and Precipitation - Case Studies from CalWater 2011

    NASA Astrophysics Data System (ADS)

    Fan, J.; Leung, L.; Comstock, J. M.; Tomlinson, J. M.

    2011-12-01

    Aerosols in the atmosphere can serve as cloud condensation nuclei (CCN) and ice nuclei (IN) to modify cloud microphysical processes, which could potentially change the location, intensity, and type of precipitation. Dust aerosols are often observed over California in the Sierra Nevada Mountains in winter/spring, associated with long-range transport from Asia. Although anthropogenic pollution has been postulated to contribute to reduction of precipitation in the Sierra Nevada Mountains, the effects of dust aerosols on the winter clouds and precipitation has not been examined in detail particularly with model simulations. We incorporate recent progress in ice nucleation parameterizations to link dust with ice crystal formation in a spectral-bin cloud microphysical model coupled with WRF, to exclusively look into how dust can possibly affect cloud properties and precipitation type and intensity. Simulations are carried out for two cases under different environmental conditions with atmospheric river (AR) and Sierra barrier jet (SBJ) from the CalWater 2011 field campaign. It is shown that increasing IN concentrations or adding a dust layer at 4-6 km as IN enhances surface rain and snow due to enhanced production of ice and snow in clouds. However, increasing CCN suppresses surface rain and snow, and significantly redistributes surface precipitation upwind and downwind of the mountains, with important implication to improving our understanding of the impacts of aerosols on orographic precipitation and water supply in the region.

  9. Precipitation recycling in West Africa - regional modeling, evaporation tagging and atmospheric water budget analysis

    NASA Astrophysics Data System (ADS)

    Arnault, Joel; Kunstmann, Harald; Knoche, Hans-Richard

    2015-04-01

    Many numerical studies have shown that the West African monsoon is highly sensitive to the state of the land surface. It is however questionable to which extend a local change of land surface properties would affect the local climate, especially with respect to precipitation. This issue is traditionally addressed with the concept of precipitation recycling, defined as the contribution of local surface evaporation to local precipitation. For this study the West African monsoon has been simulated with the Weather Research and Forecasting (WRF) model using explicit convection, for the domain (1°S-21°N, 18°W-14°E) at a spatial resolution of 10 km, for the period January-October 2013, and using ERA-Interim reanalyses as driving data. This WRF configuration has been selected for its ability to simulate monthly precipitation amounts and daily histograms close to TRMM (Tropical Rainfall Measuring Mission) data. In order to investigate precipitation recycling in this WRF simulation, surface evaporation tagging has been implemented in the WRF source code as well as the budget of total and tagged atmospheric water. Surface evaporation tagging consists in duplicating all water species and the respective prognostic equations in the source code. Then, tagged water species are set to zero at the lateral boundaries of the simulated domain (no inflow of tagged water vapor), and tagged surface evaporation is considered only in a specified region. All the source terms of the prognostic equations of total and tagged water species are finally saved in the outputs for the budget analysis. This allows quantifying the respective contribution of total and tagged atmospheric water to atmospheric precipitation processes. The WRF simulation with surface evaporation tagging and budgets has been conducted two times, first with a 100 km2 tagged region (11-12°N, 1-2°W), and second with a 1000 km2 tagged region (7-16°N, 6°W -3°E). In this presentation we will investigate hydro

  10. Controls on the stable isotopes in precipitation and surface waters across the southeastern Tibetan Plateau

    NASA Astrophysics Data System (ADS)

    Ren, Wei; Yao, Tandong; Xie, Shiyou; He, You

    2017-02-01

    Constraining temporal and spatial variability in water stable isotopes (δ18O and δD) is requested for interpreting proxy records of paleoclimate/paleoaltimetry. The southeastern Tibetan Plateau (TP) receives large amounts of precipitation in both summer (JJAS) and spring (MAM) and this makes it different from most other parts of the TP where annual precipitation concentrates only in summer. However, our knowledge of controls on precipitation and surface runoff generation in this region is still far from sufficient. In this study, the δ18O and δD of precipitation and stream waters across the southeastern TP were analyzed to investigate moisture sources and empirical isotope-elevation relationships. Herein, seasonal precipitation patterns, moisture trajectories and precipitation isotopes suggest this region is seasonally dominated by the monsoon in summer and the southerlies (from the Bay of Bengal) or a mix of southerlies and westerlies in spring. Spatially, vertical variations in precipitation seasonality exert profound influences on isotopic variability for stream waters. Larger contributions of spring precipitation (with higher δ18O and d-excess (d-excess = δD-8δ18O) compared to summer precipitation) vs. summer precipitation in the surface runoff generation at lower elevations account for the uncommon altitudinal decrease in streamwater d-excess. Such a cause also contributes to the slightly greater vertical lapse rates of streamwater δ18O (-0.28 to -0.48‰/100 m) relative to the Himalayan front. In addition, although a robust δ18O-elevation relationship is demonstrated based upon our measured and other published data on a broad spatial scale (over a 5200 m elevation range), this relationship is found to deviate from the empirical/theoretical pattern in the Himalayan front, which is also caused by the substantial spring precipitation in the southeastern TP. It is suggested that long-term changes in δ18O or δD of paleowater in this region actually

  11. Q Conversion Factor Models for Estimating Precipitable Water Vapor for Turkey

    NASA Astrophysics Data System (ADS)

    Deniz, Ilke; Mekik, Cetin; Gurbuz, Gokhan

    2015-04-01

    Global Navigation Satellite Systems (GNSS) have recently proved to be one of the crucial tools for determining continuous and precise precipitable water vapor (GNSS-MET networks). GNSS, especially CORS networks such as CORS-TR (the Turkish Network-RTK), provide high temporal and spatial accuracy for the wet tropospheric zenith delays which are then converted to the precipitable water vapor due to the fact that they can operate in all weather conditions continuously and economically. The accuracy of wet tropospheric zenith delay highly depends on the accuracy of precipitable water vapor content in the troposphere. Therefore, the precipitable water vapor is an important element of the tropospheric zenith delay. A number of studies can be found in the literature on the determination of the precipitable water vapor from the tropospheric zenith delay. Studies of Hogg showed that when the precipitable water vapor is known, the tropospheric zenith delay can be computed. Askne and Nodius have developed fundamental equations between the wet tropospheric zenith delay and the precipitable water vapor from the equation of the index of refraction in the troposphere. Furthermore, Bevis have developed a linear regression model to determine the weighted mean temperature (Tm) depending on the surface temperature (Ts) in Askne and Nodius studies. For this reason, nearly 9000 radiosonde profiles in USA were analyzed and the coefficients calculated. Similarly, there are other studies on the calculation of those coefficients for different regions: Solbrig for Germany, Liou for Taiwan, Jihyun for South Korea, Dongseob for North Korea, Suresh Raju for India, Boutiouta and Lahcene for Algeria, Bokoye for Canada, Baltink for Netherlands and Baltic, Bock for Africa. It is stated that the weighted mean temperature can be found with a root mean square error of ±2-5 K. In addition, there are studies on the calculation of the coefficients globally. Another model for the determination of

  12. The CalWater 2 - ARM Cloud Aerosol Precipitation Experiment (ACAPEX)

    NASA Astrophysics Data System (ADS)

    Leung, L. Y.; Prather, K. A.; Ralph, F. M.; Rosenfeld, D.; Spackman, J. R.; Fairall, C. W.; DeMott, P. J.; Fan, J.; Zhao, C.

    2014-12-01

    The western U.S. receives precipitation predominantly during the cold season when storms approach from the Pacific Ocean. The snowpack that accumulates during winter storms provides about 70-90% of water supply for the region. Two elements of significant importance in predicting precipitation variability in the western U.S. are atmospheric rivers and aerosols. Atmospheric rivers (ARs) are narrow bands of enhanced water vapor associated with the warm sector of extratropical cyclones over the Pacific and Atlantic oceans. While ARs are responsible for a large fraction of heavy precipitation in the western U.S. during winter, much of the rest of the orographic precipitation occurs in post-frontal clouds, which are typically quite shallow, with tops just high enough to pass the mountain barrier. Such clouds are inherently quite susceptible to aerosol effects on both warm rain and ice precipitation-forming processes. In January - March 2015, the ARM Cloud Aerosol Precipitation Experiment (ACAPEX) field campaign will take place in northern California. Joined with CalWater 2, the field campaign aims to improve understanding and modeling of large-scale dynamics and cloud and precipitation processes associated with ARs and aerosol-cloud interactions that influence precipitation variability and extremes in the western U.S. We will implement an observational strategy consisting of the use of land and offshore assets to monitor (1) the evolution and structure of ARs from near their regions of development, (2) long range transport of aerosols in eastern North Pacific and potential interactions with ARs, and (3) how aerosols from long-range transport and local sources influence cloud and precipitation in the U.S. West Coast where ARs make landfall and post-frontal clouds are frequent. This presentation will provide an overview of the science questions and hypotheses to be addressed by CalWater 2/ACAPEX, review key results from prior studies, and discuss recent findings from

  13. Next-Generation Satellite Precipitation Products for Understanding Global and Regional Water Variability

    NASA Technical Reports Server (NTRS)

    Hou, Arthur Y.

    2011-01-01

    A major challenge in understanding the space-time variability of continental water fluxes is the lack of accurate precipitation estimates over complex terrains. While satellite precipitation observations can be used to complement ground-based data to obtain improved estimates, space-based and ground-based estimates come with their own sets of uncertainties, which must be understood and characterized. Quantitative estimation of uncertainties in these products also provides a necessary foundation for merging satellite and ground-based precipitation measurements within a rigorous statistical framework. Global Precipitation Measurement (GPM) is an international satellite mission that will provide next-generation global precipitation data products for research and applications. It consists of a constellation of microwave sensors provided by NASA, JAXA, CNES, ISRO, EUMETSAT, DOD, NOAA, NPP, and JPSS. At the heart of the mission is the GPM Core Observatory provided by NASA and JAXA to be launched in 2013. The GPM Core, which will carry the first space-borne dual-frequency radar and a state-of-the-art multi-frequency radiometer, is designed to set new reference standards for precipitation measurements from space, which can then be used to unify and refine precipitation retrievals from all constellation sensors. The next-generation constellation-based satellite precipitation estimates will be characterized by intercalibrated radiometric measurements and physical-based retrievals using a common observation-derived hydrometeor database. For pre-launch algorithm development and post-launch product evaluation, NASA supports an extensive ground validation (GV) program in cooperation with domestic and international partners to improve (1) physics of remote-sensing algorithms through a series of focused field campaigns, (2) characterization of uncertainties in satellite and ground-based precipitation products over selected GV testbeds, and (3) modeling of atmospheric processes and

  14. Natural acidity of waters in podzolized soils and potential impacts from acid precipitation

    SciTech Connect

    Stednick, J.D.; Johnson, D.W.

    1982-01-01

    Nutrient movements through sites in southeast Alaska and Washington were documented to determine net changes in chemical composition of precipitation water as it passed through a forest soil and became stream flow. These sites were not subject to acid precipitation (rainfall pH 5.8 to 7.2), yet soil water was acidified to 4.2 by natural organic acid forming processes in the podzol soils. Organic acids precipitated in the subsoils, allowing a pH increase. Stream water pH ranged from 6.5 to 7.2 indicating a natural buffering capacity that may exceed any additional acid input from acid rain. Precipitation composition was dominated by magnesium, sodium, and chloride due to the proximity of the ocean at the southeast Alaska site. Anionic constituents of the precipitation were dominated by bicarbonate at the Washington site. Soil podzolization processes concurrently increased solution color and iron concentrations in the litter and surface horizons leachates. The anion flux through the soil profile was dominated by chloride and sulfate at the southwast Alaska site, whereas at the Washington site anion flux appeared to be dominated by organic acids. Electroneutrality calculations indicated a cation deficit for the southeast Alaska site. 10 references, 2 tables.

  15. ASSESSING MINE DRAINAGE WATER QUALITY FROM THE COLOR AND SPECTRAL REFLECTANCE OF CHEMICAL PRECIPITATES

    EPA Science Inventory


    The pH and dissolved sulfate concentrations of mine impacted waters were estimated on the basis of the spectral reflectance of resident sediments composed mostly of chemical precipitates. Mine drainage sediments were collected from sites in the Anthracite Region of eastern Pe...

  16. Annual precipitation and effects of runoff-nutrient from agricultural watersheds on water quality

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Declining surface water quality from agricultural nonpoint sources is of great concern across the Platte river basin in Nebraska. Recent changes in the earth climate create abrupt changes in domestic weather (i.e., precipitation, temperature, etc.) which can alter the impact of these nonpoint source...

  17. Hydrologic response of catchments to precipitation: Quantification of mechanical carriers and origins of water

    NASA Astrophysics Data System (ADS)

    Park, Y.-J.; Sudicky, E. A.; Brookfield, A. E.; Jones, J. P.

    2011-12-01

    Precipitation-induced overland and groundwater flow and mixing processes are quantified to analyze the temporal (event and pre-event water) and spatial (groundwater discharge and overland runoff) origins of water entering a stream. Using a distributed-parameter control volume finite-element simulator that can simultaneously solve the fully coupled partial differential equations describing 2-D Manning and 3-D Darcian flow and advective-dispersive transport, mechanical flow (driven by hydraulic potential) and tracer-based hydrograph separation (driven by dispersive mixing as well as mechanical flow) are simulated in response to precipitation events in two cross sections oriented parallel and perpendicular to a stream. The results indicate that as precipitation becomes more intense, the subsurface mechanical flow contributions tend to become less significant relative to the total pre-event stream discharge. Hydrodynamic mixing can play an important role in enhancing pre-event tracer signals in the stream. This implies that temporally tagged chemical signals introduced into surface-subsurface flow systems from precipitation may not be strong enough to detect the changes in the subsurface flow system. It is concluded that diffusive/dispersive mixing, capillary fringe groundwater ridging, and macropore flow can influence the temporal sources of water in the stream, but any sole mechanism may not fully explain the strong pre-event water discharge. Further investigations of the influence of heterogeneity, residence time, geomorphology, and root zone processes are required to confirm the conclusions of this study.

  18. Hydrologic response of catchments to precipitation: Quantification of mechanical carriers and origins of water

    USGS Publications Warehouse

    Park, Y.-J.; Sudicky, E.A.; Brookfield, A.E.; Jones, J.P.

    2011-01-01

    Precipitation-induced overland and groundwater flow and mixing processes are quantified to analyze the temporal (event and pre-event water) and spatial (groundwater discharge and overland runoff) origins of water entering a stream. Using a distributed-parameter control volume finite-element simulator that can simultaneously solve the fully coupled partial differential equations describing 2-D Manning and 3-D Darcian flow and advective-dispersive transport, mechanical flow (driven by hydraulic potential) and tracer-based hydrograph separation (driven by dispersive mixing as well as mechanical flow) are simulated in response to precipitation events in two cross sections oriented parallel and perpendicular to a stream. The results indicate that as precipitation becomes more intense, the subsurface mechanical flow contributions tend to become less significant relative to the total pre-event stream discharge. Hydrodynamic mixing can play an important role in enhancing pre-event tracer signals in the stream. This implies that temporally tagged chemical signals introduced into surface-subsurface flow systems from precipitation may not be strong enough to detect the changes in the subsurface flow system. It is concluded that diffusive/dispersive mixing, capillary fringe groundwater ridging, and macropore flow can influence the temporal sources of water in the stream, but any sole mechanism may not fully explain the strong pre-event water discharge. Further investigations of the influence of heterogeneity, residence time, geomorphology, and root zone processes are required to confirm the conclusions of this study. Copyright 2011 by the American Geophysical Union.

  19. Intercomparison of CMIP5 simulations of summer precipitation, evaporation, and water vapor transport over Yellow and Yangtze River basins

    NASA Astrophysics Data System (ADS)

    Bao, Jiawei; Feng, Jinming

    2016-02-01

    Precipitation and other hydrologic variables play important roles in river basins. In this study, summer precipitation, evaporation, and water vapor transport from 16 models that have participated in Coupled Model Intercomparison Project Phase 5 (CMIP5) for the Yellow River basin (a water-limited basin) and the Yangtze River basin (an energy-limited basin) over the period 1986-2005 are analyzed and evaluated. The results suggest that most models tend to overestimate precipitation in the Yellow River basin, whereas precipitation in the Yangtze River basin is generally well simulated. Models that overestimate precipitation in the Yellow River basin also simulate evaporation with large positive biases. For water vapor transport, models and reanalysis data concur that both basins are moisture sinks in summer. In addition, models that strongly overestimate precipitation in the Yellow River basin tend to produce strong water vapor convergence in that region, which is likely to be related to the situation that the western Pacific subtropical high (WPSH) simulated by these models strengthens and advances further westward and northward, resulting in stronger water vapor convergence in the Yellow River basin. Moreover, convective precipitation biases simulated by the models are also partially responsible for their total precipitation biases. Finally, summer precipitation and evaporation are negatively correlated in the Yangtze River basin, whereas the relation between these variables is weak in the Yellow River basin. In both basins, precipitation and water vapor convergence are positively correlated, which is well simulated by all models.

  20. Estimating the Risk of Domestic Water Source Contamination Following Precipitation Events.

    PubMed

    Eisenhauer, Ian F; Hoover, Christopher M; Remais, Justin V; Monaghan, Andrew; Celada, Marco; Carlton, Elizabeth J

    2016-06-01

    Climate change is expected to increase precipitation extremes, threatening water quality. In low resource settings, it is unclear which water sources are most vulnerable to contamination following rainfall events. We evaluated the relationship between rainfall and drinking water quality in southwest Guatemala where heavy rainfall is frequent and access to safe water is limited. We surveyed 59 shallow household wells, measured precipitation, and calculated simple hydrological variables. We compared Escherichia coli concentration at wells where recent rainfall had occurred versus had not occurred, and evaluated variability in the association between rainfall and E. coli concentration under different conditions using interaction models. Rainfall in the past 24 hours was associated with greater E. coli concentrations, with the strongest association between rainfall and fecal contamination at wells where pigs were nearby. Because of the small sample size, these findings should be considered preliminary, but provide a model to evaluate vulnerability to climate change.

  1. The new portfolio of global precipitation data products of the Global Precipitation Climatology Centre suitable to assess and quantify the global water cycle and resources

    NASA Astrophysics Data System (ADS)

    Schneider, Udo; Ziese, Markus; Meyer-Christoffer, Anja; Finger, Peter; Rustemeier, Elke; Becker, Andreas

    2016-10-01

    Precipitation plays an important role in the global energy and water cycle. Accurate knowledge of precipitation amounts reaching the land surface is of special importance for fresh water assessment and management related to land use, agriculture and hydrology, incl. risk reduction of flood and drought. High interest in long-term precipitation analyses arises from the needs to assess climate change and its impacts on all spatial scales. In this framework, the Global Precipitation Climatology Centre (GPCC) has been established in 1989 on request of the World Meteorological Organization (WMO). It is operated by Deutscher Wetterdienst (DWD, National Meteorological Service of Germany) as a German contribution to the World Climate Research Programme (WCRP). This paper provides information on the most recent update of GPCC's gridded data product portfolio including example use cases.

  2. Short-range precipitation forecasts using assimilation of simulated satellite water vapor profiles and column cloud liquid water amounts

    NASA Technical Reports Server (NTRS)

    Wu, Xiaohua; Diak, George R.; Hayden, Cristopher M.; Young, John A.

    1995-01-01

    These observing system simulation experiments investigate the assimilation of satellite-observed water vapor and cloud liquid water data in the initialization of a limited-area primitive equations model with the goal of improving short-range precipitation forecasts. The assimilation procedure presented includes two aspects: specification of an initial cloud liquid water vertical distribution and diabatic initialization. The satellite data is simulated for the next generation of polar-orbiting satellite instruments, the Advanced Microwave Sounding Unit (AMSU) and the High-Resolution Infrared Sounder (HIRS), which are scheduled to be launched on the NOAA-K satellite in the mid-1990s. Based on cloud-top height and total column cloud liquid water amounts simulated for satellite data a diagnostic method is used to specify an initial cloud water vertical distribution and to modify the initial moisture distribution in cloudy areas. Using a diabatic initialization procedure, the associated latent heating profiles are directly assimilated into the numerical model. The initial heating is estimated by time averaging the latent heat release from convective and large-scale condensation during the early forecast stage after insertion of satellite-observed temperature, water vapor, and cloud water formation. The assimilation of satellite-observed moisture and cloud water, together withy three-mode diabatic initialization, significantly alleviates the model precipitation spinup problem, especially in the first 3 h of the forecast. Experimental forecasts indicate that the impact of satellite-observed temperature and water vapor profiles and cloud water alone in the initialization procedure shortens the spinup time for precipitation rates by 1-2 h and for regeneration of the areal coverage by 3 h. The diabatic initialization further reduces the precipitation spinup time (compared to adiabatic initialization) by 1 h.

  3. Numerical simulation of the geographical sources of water for Continental Scale Experiments (CSEs) Precipitation

    NASA Technical Reports Server (NTRS)

    Bosilovich, Michael G.; Sud, Yogesh; Schubert, Siegfried D.; Walker, Gregory K.

    2003-01-01

    There are several important research questions that the Global Energy and Water Cycle Experiment (GEWEX) is actively pursuing, namely: What is the intensity of the water cycle and how does it change? And what is the sustainability of water resources? Much of the research to address these questions is directed at understanding the atmospheric water cycle. In this paper, we have used a new diagnostic tool, called Water Vapor Tracers (WVTs), to quantify the how much precipitation originated as continental or oceanic evaporation. This shows how long water can remain in the atmosphere and how far it can travel. The model-simulated data are analyzed over regions of interest to the GEWEX community, specifically, their Continental Scale Experiments (CSEs) that are in place in the United States, Europe, Asia, Brazil, Africa and Canada. The paper presents quantitative data on how much each continent and ocean on Earth supplies water for each CSE. Furthermore, the analysis also shows the seasonal variation of the water sources. For example, in the United States, summertime precipitation is dominated by continental (land surface) sources of water, while wintertime precipitation is dominated by the Pacific Ocean sources of water. We also analyze the residence time of water in the atmosphere. The new diagnostic shows a longer residence time for water (9.2 days) than more traditional estimates (7.5 days). We emphasize that the results are based on model simulations and they depend on the model s veracity. However, there are many potential uses for the new diagnostic tool in understanding weather processes and large and small scales.

  4. Cloud and Aerosol Properties, Precipitable Water, and Profiles of Temperature and Water Vapor from MODIS

    NASA Technical Reports Server (NTRS)

    King, Michael D.; Menzel, W. Paul; Kaufman, Yoram J.; Tanre, Didier; Gao, Bo-Cai; Platnick, Steven; Ackerman, Steven A.; Remer, Lorraine A.; Pincus, Robert; Hubanks, Paul A.

    2003-01-01

    The Moderate Resolution Imaging Spectroradiometer (MODIS) is an earth-viewing sensor that flies on the Earth Observing System (EOS) Terra and Aqua satellites, launched in 1999 and 2002, respectively. MODIS scans a swath width of 2330 km that is sufficiently wide to provide nearly complete global coverage every two days from a polar-orbiting, sun-synchronous, platform at an altitude of 705 km. MODIS provides images in 36 spectral bands between 0.415 and 14.235 pm with spatial resolutions of 250 m (2 bands), 500 m (5 bands) and 1000 m (29 bands). These bands have been carefully selected to en- able advanced studies of land, ocean, and atmospheric properties. Twenty-six bands are used to derive atmospheric properties such as cloud mask, atmospheric profiles, aerosol properties, total precipitable water, and cloud properties. In this paper we describe each of these atmospheric data products, including characteristics of each of these products such as file size, spatial resolution used in producing the product, and data availability.

  5. CalWater 2015 — Atmospheric Rivers and Aerosol Impacts on Precipitation

    NASA Astrophysics Data System (ADS)

    Spackman, J. R.; Ralph, F. M.; Prather, K. A.; Cayan, D.; DeMott, P. J.; Dettinger, M. D.; Doyle, J. D.; Fairall, C. W.; Leung, L. R.; Rosenfeld, D.; Rutledge, S. A.; Waliser, D. E.; White, A. B.

    2015-12-01

    The CalWater 2015 field experiment was conducted between January and March and consisted of more than fifty science flights, a major research cruise, and continuous ground-based observations coordinated to study phenomena driving the incidence of extreme precipitation events and the variability of water supply along the West Coast of the United States. CalWater 2015 examined key processes linked to (1) atmospheric rivers (ARs) in delivering much of the precipitation associated with major winter storms, and (2) aerosols, originating from local sources as well as from remote continents, within and between storms and their modulating effects on precipitation on the U.S. West Coast. As part of a large interagency field effort including NOAA, DOE, NASA, NSF, and the Naval Research Laboratory, four research aircraft from three government agencies were deployed in coordination with the oceangoing NOAA Ronald H. Brown and were equipped with meteorological and chemical observing systems in near-shore regions of California and the eastern Pacific. At the same time, ground-based measurements from NOAA's HydroMeteorological Testbed (HMT) network on the U.S. West Coast and a major NSF-supported observing site for aerosols and microphysics at Bodega Bay, California provided continuous near surface-level meteorological and chemical observations, respectively, during CalWater 2015. The DOE-sponsored ARM Cloud Aerosol and Precipitation Experiment (ACAPEX) was executed in close coordination with NOAA and NASA facilities and deployed airborne and ship-based observing systems. This presentation summarizes the objectives, implementation strategy, data acquisitions, and some preliminary results from CalWater 2015 addressing science gaps associated with (1) the evolution and structure of ARs including cloud and precipitation processes and air-sea interaction, and (2) aerosol interaction with ARs and the impact on precipitation, including locally-generated aerosol effects on orographic

  6. CalWater 2 - Precipitation, Aerosols, and Pacific Atmospheric Rivers Experiment

    NASA Astrophysics Data System (ADS)

    Spackman, Ryan; Ralph, Marty; Prather, Kim; Cayan, Dan; DeMott, Paul; Dettinger, Mike; Fairall, Chris; Leung, Ruby; Rosenfeld, Daniel; Rutledge, Steven; Waliser, Duane; White, Allen

    2014-05-01

    Emerging research has identified two phenomena that play key roles in the variability of the water supply and the incidence of extreme precipitation events along the West Coast of the United States. These phenomena include the role of (1) atmospheric rivers (ARs) in delivering much of the precipitation associated with major storms along the U.S. West Coast, and (2) aerosols—from local sources as well as those transported from remote continents—and their modulating effects on western U.S. precipitation. A better understanding of these processes is needed to reduce uncertainties in weather predictions and climate projections of extreme precipitation and its effects, including the provision of beneficial water supply. This presentation summarizes science gaps associated with (1) the evolution and structure of ARs including cloud and precipitation processes and air-sea interaction, and (2) aerosol interaction with ARs and the impact on precipitation, including locally-generated aerosol effects on orographic precipitation along the U.S. West Coast. Observations are proposed for multiple winter seasons as part of a 5-year broad interagency vision referred to as CalWater 2 to address these science gaps (http://esrl.noaa.gov/psd/calwater). In the near term, a science investigation is being planned including a targeted set of aircraft and ship-based measurements and associated evaluation of data in near-shore regions of California and in the eastern Pacific for an intensive observing period between January 2015 and March 2015. DOE's Atmospheric Radiation Measurement (ARM) program and NOAA are coordinating on deployment of airborne and ship-borne facilities for this period in a DOE-sponsored study called ACAPEX (ARM Cloud Aerosol and Precipitation Experiment) to complement CalWater 2. The motivation for this major study is based on findings that have emerged in the last few years from airborne and ground-based studies including CalWater and NOAA's HydroMeterology Testbed

  7. Natural acidity of waters in podzolized soils and potential impacts from acid precipitation

    SciTech Connect

    Stednick, J.D.; Johnson, D.W.

    1982-01-01

    Nutrient movements through sites in southeast Alaska and Washington were documented to determine net changes in chemical composition of precipitation water as it passed through a forest soil and became stream-flow. These sites were not subject to acid precipitation (rainfall pH 5.8 to 7.2), yet soil water was acidified to 4.2 by natural organic acid-forming processes in the podzol soils. Organic acids precipitated in the subsoils, allowing a pH increase. Streamwater pH ranged from 6.5 to 7.2 indicating a natural buffering capacity that may exceed any additional acid input from acid rain. Precipitation composition was dominated by calcium, magnesium, sodium, and chloride due to the proximity of the ocean at the southeast Alaska site. Anionic constituents of the precipitation were dominated by bicarbonate at the Washington site. Soil podzolization processes concurrently increased solution color and iron concentrations in the litter and surface horizons leachates. The anion flux through the soil profile was dominated by chloride and sulfate at the southeast Alaska site, whereas at the Washington site anion flux appeared to be dominated by organic acids. Electroneutrality calculations indicated a cation deficit for the southeast Alaska site.

  8. Seasonal predictions of precipitation in the Aksu-Tarim River basin for improved water resources management

    NASA Astrophysics Data System (ADS)

    Hartmann, Heike; Snow, Julie A.; Su, Buda; Jiang, Tong

    2016-12-01

    Since the 1950s, the population in the arid to hyperarid Tarim River basin has grown rapidly concurrent with an expansion of irrigated agriculture. This threatens the Tarim River basin's natural ecosystems and causes water shortages, even though increased discharges in the headwaters have been observed more recently. These increases have mainly been attributed to receding glaciers and are projected to cease when the glaciers are unable to provide sufficient amounts of meltwater. Under these circumstances water management will face a serious challenge in adapting its strategies to changes in river discharge, which to a greater extent will depend on changes in precipitation. In this paper, we aim to develop accurate seasonal predictions of precipitation to improve water resources management. Possible predictors of precipitation for the Tarim River basin were either downloaded directly or calculated using NCEP/NCAR Reanalysis 1 and NOAA Extended Reconstructed Sea Surface Temperature (SST) V3b data in monthly resolution. To evaluate the significance of the predictors, they were then correlated with the monthly precipitation dataset GPCCv6 extracted for the Tarim River basin for the period 1961 to 2010. Prior to the Spearman rank correlation analyses, the precipitation data were averaged over the subbasins of the Tarim River. The strongest correlations were mainly detected with lead times of four and five months. Finally, an artificial neural network model, namely a multilayer perceptron (MLP), and a multiple linear regression (LR) model were developed each in two different configurations for the Aksu River subbasin, predicting precipitation five months in advance. Overall, the MLP using all predictors shows the best performance. The performance of both models drops only slightly when restricting the model input to the SST of the Black Sea and the Siberian High Intensity (SHI) pointing towards their importance as predictors.

  9. Impact of AIRS Thermodynamic Profiles on Precipitation Forecasts for Atmospheric River Cases Affecting the Western United States

    NASA Technical Reports Server (NTRS)

    Zavodsky, Bradley T.; Jedlovec, Gary J.; Blakenship, Clay B.; Wick, Gary A.; Neiman, Paul J.

    2013-01-01

    This project is a collaborative activity between the NASA Short-term Prediction Research and Transition (SPoRT) Center and the NOAA Hydrometeorology Testbed (HMT) to evaluate a SPoRT Advanced Infrared Sounding Radiometer (AIRS: Aumann et al. 2003) enhanced moisture analysis product. We test the impact of assimilating AIRS temperature and humidity profiles above clouds and in partly cloudy regions, using the three-dimensional variational Gridpoint Statistical Interpolation (GSI) data assimilation (DA) system (Developmental Testbed Center 2012) to produce a new analysis. Forecasts of the Weather Research and Forecasting (WRF) model initialized from the new analysis are compared to control forecasts without the additional AIRS data. We focus on some cases where atmospheric rivers caused heavy precipitation on the US West Coast. We verify the forecasts by comparison with dropsondes and the Cooperative Institute for Research in the Atmosphere (CIRA) Blended Total Precipitable Water product.

  10. An approach to improve precipitation estimation to model the water budget in Alpine catchments

    NASA Astrophysics Data System (ADS)

    Mair, E.; Bertoldi, G.; Della Chiesa, S.; Niedrist, G.; Egarter Vigl, L.; Tappeiner, U.

    2012-04-01

    Accurate quantification of precipitation is still one of the major sources of uncertainty in quantifying the water budget of Alpine catchments. In fact, besides increasing data availability, usually most of the stations are located in the bottom of the valleys, while, at high elevations, rain gauge accuracy is limited by snow and wind, with strong underestimation of the total precipitation. Similar problems exist for snow measurement devices. In this contribution we present a novel empirical approach to improve precipitation estimation using rain gauge data, snow height and standard meteorological observations, and we evaluate the improvements in estimating the water budget of the Mazia Valley (100 km2 - Central Alps - South Tyrol, Italy). In fact, due to the screening effect of the surrounding mountains (mostly glaciated, maximum elevation: 3750 m a.s.l.) this valley has a relatively dry cold continental climate with strong precipitation gradients. In the framework of the projects "Klimawandel" and "HydroAlp", 17 monitoring stations were installed to measure standard micrometeorological variables, vegetation properties and soil moisture. For a correct climate analysis, a distinction between snow and rainfall is necessary. Due to energy limitations in remote alpine areas no heated rain gauges were installed. However, four stations are equipped with snow height sensors, from which snow data can be retrieved. For other stations the calculation of the snow water equivalent was more complicated because of the lack of snow height sensors. In the empirical approach, for every registered precipitation data record snow height change was reviewed and compared to air temperature and relative humidity, as well as to the calculated wet bulb temperature, in order to distinguish between rainfall and snowfall events. Also the global solar radiation was controlled to identify melt water production coming from accumulated snow on the top of the unheated rain gauges. With a formula

  11. Enrichment of 88Sr in continental waters due to calcium carbonate precipitation

    NASA Astrophysics Data System (ADS)

    Shalev, Netta; Gavrieli, Ittai; Halicz, Ludwik; Sandler, Amir; Stein, Mordechai; Lazar, Boaz

    2017-02-01

    δ88/86Sr data published over the last few years suggest that continental waters are enriched with 88Sr as compared to the rocks in their drainage basins. In an attempt to understand this phenomenon, this study established the fractionation in the 88Sr/86Sr ratio during precipitation of continental carbonates (i.e., carbonates precipitated on land from surface, pedogenic, or ground waters), and evaluated the contribution of this process to the 88Sr-enrichment in rivers. For this, stable and radiogenic Sr isotopes (88Sr, 87Sr and 86Sr) were measured in calcite samples and their precipitating waters collected in various continental environments, such as soil, cave, streams and groundwater. The results indicate that continental carbonates are 88Sr-depleted relative to their precipitating waters, placing them as one of the most 88Sr-depleted reservoirs on earth. The average difference in δ88/86Sr values between waters and solid CaCO3 (tufas or speleothems) that they precipitate is Δcarb-water = - 0.218 ± 0.014 ‰ (1SD). An even larger fractionation (εcarb-water = - 0.285 ± 0.02 ‰) was measured in groundwater with particularly high carbonate-alkalinity and high carbonate precipitation rate that depleted ∼65% of the Sr in the groundwater, resulting in substantial 88Sr-enrichment in the residual dissolved Sr (δ88/86Sr = 0.656 ‰). Results also suggest that pedogenic carbonate precipitation in soil profile removes 50-85% of the Sr from the recharging soil-water, thereby increasing the δ88/86Sr value of the soil-water from ∼ 0.18 ‰ to 0.3 ‰- 0.6 ‰. Similar 88Sr-enrichment was observed in drip water from a karst cave. A maximum removal flux of Sr into continental carbonates of about 20 Gmol(Sr)ṡy-1 is required to yield the reported 88Sr-enrichment in global rivers (δ88/86Sr = 0.32 ‰) relative to their rock sources when using the fractionation factor derived in this study, Δcarb-water = - 0.218 ‰, and the published δ88/86Sr composition of marine

  12. Silicon isotope fractionation during silica precipitation from hot-spring waters

    NASA Astrophysics Data System (ADS)

    Geilert, Sonja; Vroon, Pieter; Keller, Nicole; Gudbrnadsson, Snorri; Stefánsson, Andri; van Bergen, Manfred

    2014-05-01

    Hot-spring systems in the Geysir geothermal area, Iceland, have been studied to explore silicon isotope fractionation in a natural setting where sinter deposits are actively formed over a temperature interval between 20° and 100° C. The SiO2(aq)concentrations in spring and stream waters range between 290 and 560ppm and stay relatively constant along downstream trajectories, irrespective of significant cooling gradients. The waters are predominantly oversaturated in amorphous silica at the temperatures measured in the field. Correlations between the saturation indices, temperature and amounts of evaporative water loss suggest that cooling and evaporation are the main causes of subaqueous silica precipitation. The δ30Si values of dissolved silica in spring water and outflowing streams average around +1o probably due to the small quantities of instantaneously precipitating silica relative to the dissolved amount. Siliceous sinters, in contrast, range between -0.1o to -4.0o consistent with a preferred incorporation of the light silicon isotope and with values for precipitated silica becoming more negative with downstream decreasing temperatures. Larger fractionation magnitudes are inversely correlated with the precipitation rate, which itself is dependent on temperature, saturation state and the extent of a system. The resulting magnitudes of solid-fluid isotopic fractionation generally decline from -3.5o at 10° C to -2.0o at 90° C. These values confirm a similar relationship between fractionation magnitude and temperature that we found in laboratory-controlled silica-precipitation experiments. However, a relatively constant offset of ca. -2.9o between field and experimental fractionation values indicates that temperature alone cannot be responsible for the observed shifts. We infer that precipitation kinetics are a prominent control of silicon isotope fractionation in aqueous environments, whereby the influence of the extent of the system on the precipitation

  13. Predicting the Effect of Changing Precipitation Extremes and Land Cover Change on Urban Water Quality

    NASA Astrophysics Data System (ADS)

    SUN, N.; Yearsley, J. R.; Lettenmaier, D. P.

    2013-12-01

    Recent research shows that precipitation extremes in many of the largest U.S. urban areas have increased over the last 60 years. These changes have important implications for stormwater runoff and water quality, which in urban areas are dominated by the most extreme precipitation events. We assess the potential implications of changes in extreme precipitation and changing land cover in urban and urbanizing watersheds at the regional scale using a combination of hydrology and water quality models. Specifically, we describe the integration of a spatially distributed hydrological model - the Distributed Hydrology Soil Vegetation Model (DHSVM), the urban water quality model in EPA's Storm Water Management Model (SWMM), the semi-Lagrangian stream temperature model RBM10, and dynamical and statistical downscaling methods applied to global climate predictions. Key output water quality parameters include total suspended solids (TSS), toal nitrogen, total phosphorous, fecal coliform bacteria and stream temperature. We have evaluated the performance of the modeling system in the highly urbanized Mercer Creek watershed in the rapidly growing Bellevue urban area in WA, USA. The results suggest that the model is able to (1) produce reasonable streamflow predictions at fine temporal and spatial scales; (2) provide spatially distributed water temperature predictions that mostly agree with observations throughout a complex stream network, and characterize impacts of climate, landscape, near-stream vegetation change on stream temperature at local and regional scales; and (3) capture plausibly the response of water quality constituents to varying magnitude of precipitation events in urban environments. Next we will extend the scope of the study from the Mercer Creek watershed to include the entire Puget Sound Basin, WA, USA.

  14. [Effects of ground cover and water-retaining agent on winter wheat growth and precipitation utilization].

    PubMed

    Wu, Ji-Cheng; Guan, Xiu-Juan; Yang, Yong-Hui

    2011-01-01

    An investigation was made at a hilly upland in western Henan Province to understand the effects of water-retaining agent (0, 45, and 60 kg x hm(-2)), straw mulching (3000 and 6000 kg x hm(-2)), and plastic mulching (thickness < 0.005 mm) on winter wheat growth, soil moisture and nutrition conditions, and precipitation use. All the three measures promoted winter wheat growth, enhanced grain yield and precipitation use efficiency, and improved soil moisture and nutritional regimes. These positive effects were more obvious when the straw- or plastic mulching was combined with the use of water-retaining agent. Comparing with the control, all the measures increased the soil moisture content at different growth stages by 0.1%-6.5%. Plastic film mulching had the best water-retention effect before jointing stage, whereas water-retaining agent showed its best effect after jointing stage. Soil moisture content was the lowest at flowering and grain-filling stages. Land cover increased the grain yield by 2.6%-20.1%. The yield increment was the greatest (14.2%-20.1%) by the combined use of straw mulching and water-retaining agent, followed by plastic mulching combined with water-retaining agent (11.9% on average). Land cover also improved the precipitation use efficiency (0.4-3.2 kg x mm(-1) x hm(-2)) in a similar trend as the grain yield. This study showed that land cover and water-retaining agent improved soil moisture and nutrition conditions and precipitation utilization, which in turn, promoted the tillering of winter wheat, and increased the grain number per ear and the 1000-grain mass.

  15. Estimation of precipitable water over the Amazon Basin using GOES imagery

    NASA Astrophysics Data System (ADS)

    Callahan, John Andrew

    The Amazon Rainforest is the largest continuous rainforest on Earth. It holds a rich abundance of life containing approximately one-half of all existing plant and animal species and 20% of the world's fresh water. Climatologically, the Amazon Rainforest is a massive storehouse of carbon dioxide and water vapor and hosts hydrologic and energy cycles that influence regional and global patterns. However, this region has gone through vast land cover changes during the past several decades. Lack of conventional, in situ data sources prohibits detailed measurements to assess the climatological impact these changes may cause. This thesis applies a satellite-based, thermal infrared remote sensing algorithm to determine precipitable water in the Amazon Basin to test its applicability in the region and to measure the diurnal changes in water vapor. Imagery from the GOES geostationary satellite and estimated atmospheric conditions and radiance values derived from the NCEP/NCAR Reanalysis project were used as inputs to the Physical Split Window (PSW) technique. Retrievals of precipitable water were made every 3 hours throughout each day from 12Z to 24Z for the months of June and October, 1988 and 1995. These months correspond to when the atmosphere is not dominated by clouds during the rainy (wet) season or smoke and haze during the burning (dry) season. Monthly, daily, and diurnal aggregates of precipitable water Fields were analyzed spatially through seven zones located uniformly throughout the region. Monthly average precipitable water values were found to be 20mm to 25mm in the southeast and 45mm to 50mm in the northwest zones. Central and northwest zones showed little variation throughout the day with most areas peaking between 15Z and 21Z, representing early to late afternoon local time. Comparisons were made to nearby, coincident radiosonde observations with r ranging from 0.7 to 0.9 and MAE from 6mm to 12 mm.

  16. Tracer water transport and subgrid precipitation variation within atmospheric general circulation models

    NASA Technical Reports Server (NTRS)

    Koster, Randal D.; Eagleson, Peter S.; Broecker, Wallace S.

    1988-01-01

    A capability is developed for monitoring tracer water movement in the three-dimensional Goddard Institute for Space Science Atmospheric General Circulation Model (GCM). A typical experiment with the tracer water model follows water evaporating from selected grid squares and determines where this water first returns to the Earth's surface as precipitation or condensate, thereby providing information on the lateral scales of hydrological transport in the GCM. Through a comparison of model results with observations in nature, inferences can be drawn concerning real world water transport. Tests of the tracer water model include a comparison of simulated and observed vertically-integrated vapor flux fields and simulations of atomic tritium transport from the stratosphere to the oceans. The inter-annual variability of the tracer water model results is also examined.

  17. Ikaite precipitation by mixing of shoreline springs and lake water, Mono Lake, California, USA

    USGS Publications Warehouse

    Bischoff, J.L.; Stine, S.; Rosenbauer, R.J.; Fitzpatrick, J.A.; Stafford, Thomas W.

    1993-01-01

    Metastable ikaite (CaCO3??6H2O) forms abundantly during winter months along the south shoreline of Mono Lake where shoreline springs mix with lake water. Ikaite precipitates because of its decreased solubility at low temperature and because of orthophosphate-ion inhibition of calcite and aragonite. During the spring some of the ikaite is transformed to anhydrous CaCO3 and is incorporated into tufa, but most is dispersed by wave action into the lake where it reacts to form gaylussite (Na2Ca(CO3)2?? 5H2O). Spring waters have low pH values, are dominantly Ca-Na-HCO3, have low radiocarbon activities, and are mixtures of deep-seated geothermal and cold groundwaters. Chemical modeling reveals that precipitation of CaCO3 can occur over a broad range of mixtures of spring and lake water with a maximum production occurring at 96% spring water and 4% lake water. Under these conditions all the Ca and a significant fraction of the CO3 of the precipitate is spring supplied. A radiocarbon age of 19,580 years obtained on a natural ikaite sample supports this conclusion. With the springs supplying a large and probably variable portion of the carbonate, and with apparent 14C age of the carbonate varying from spring to spring, tufa of similar actual antiquity may yield significantly different 14C dates, making tufa at this location unsuitable for absolute age dating by the radiocarbon method. ?? 1993.

  18. Evaluation of Technologies to Prevent Precipitation During Water Recovery from Urine

    NASA Technical Reports Server (NTRS)

    Broyan, James L., Jr.; Pickering, Karen D.; Adam, Niklas M.; Mitchell, Julie L.; Anderson, Molly S.; Carter, Layne; Muirhead, Dean; Gazda, Daniel B.

    2011-01-01

    The International Space Station (ISS) Urine Processor Assembly (UPA) experienced a hardware failure in the Distillation Assembly (DA) in October 2010. Initially the UPA was operated to recover 85% of the water from urine through distillation, concentrating the contaminants in the remaining urine. The DA failed due to precipitation of calcium sulfate (gypsum) which caused a loss of UPA function. The ISS UPA operations have been modified to only recover 70% of the water minimizing gypsum precipitation risk but substantially increasing water resupply needs. This paper describes the feasibility assessment of several technologies (ion exchange, chelating agents, threshold inhibitors, and Lorentz devices) to prevent gypsum precipitation. The feasibility assessment includes the development of assessment methods, chemical modeling, bench top testing, and validation testing in a flight-like ground UPA unit. Ion exchange technology has been successfully demonstrated and has been recommended for further development. The incorporation of the selected technology will enable water recovery to be increased from 70% back to the original 85% and improve the ISS water balance.

  19. Precipitation variability and future projections for water resources management in Tunisia Northern Coastal basins

    NASA Astrophysics Data System (ADS)

    Bargaoui, Z.; Tramblay, Y.; Lawin, E.; Servat, E.

    2012-04-01

    Northern Tunisia is the rainiest part of the country. This is the reason why the surface water resources management scheme of Tunisia is principally focused on that area. The strategic situation of the study area, with respect to surface water resources, encourages the investigation of the climate change impacts as projected by climate models. The goal of this study is first to compare the observed precipitation with climate model outputs, and then to evaluate the future changes projected by the models. The study area is subdivided into three regions: the transboundary Medjerda basin, the northern coastal basins (Zouara, Sidi El Barrack, Lake Ichkeul basins) and the eastern coastal basins (Cap-Bon region and wadi Meliane basins). Rainfall data are collected in this area since the late 19th century. A data base provided by the Tunisian hydrological service (DGRE) is including 388 stations with monthly precipitation data over the period 1961-2000. Recent advances in downscaling have provided regional climate model (RCM) simulations at a coarser resolution than Global climate models (GCM). However there is a need to validate RCM outputs with respect to observed precipitation data before using them to make future projections. For that purpose, an ensemble of RCM simulations provided by the European Union-funded project ENSEMBLES (www. ensembles-eu.org) are used. Six RCM models runs (CNR_ARPEGE, DMI_ARPEGE, DMI_BCM, ICT_ECHAM, SMH_BCM, SMH_ECHAM) are tested for a control period (1961-2000) and two projection periods (2011-2050 and 2051-2090).The models efficiency in reproducing seasonal precipitation amounts and variability over the study domain is evaluated. A 1-km monthly precipitation grid is first obtained through the interpolation of rainfall observations during the period 1961-2000 with kriging techniques. Monthly precipitation series averaged over the three great regions are built for comparison for the control period. The RCM outputs are evaluated with respect

  20. Physicochemical characteristics of drip waters: Influence on mineralogy of recent cave carbonate precipitates

    NASA Astrophysics Data System (ADS)

    Riechelmann, Sylvia; Schröder-Ritzrau, Andrea; Wassenburg, Jasper A.; Richter, Detlev K.; Riechelmann, Dana FC; Terente, Mihai; Constantin, Silviu; Immenhauser, Adrian

    2015-04-01

    Speleothems are one of the most intensively explored archives of palaeoclimate variability in continental settings. Considerable advances with respect to climatic and cave forcing of drip characteristics and related speleothem proxy data have been made during the last decades. The parameters, however, that control speleothem mineralogy and its changes with time and space are still poorly understood. In order to shed light on processes influencing speleothem mineralogy, precipitation experiments of recent carbonate crystals on watch glasses and glass plates were performed in seven selected caves. These include three caves in Germany as well as Morocco and one cave in Romania, which are situated in both limestone and dolostone. Drip water sites of these caves were analysed for their fluid Mg/Ca molar ratio, pH, degree of saturation for calcite and aragonite and drip rates. Corresponding precipitates were analysed with respect to their mineralogy using a high resolution scanning electron microscope (SEM). The following results are found: High fluid Mg/Ca ratios are observed only for caves situated in dolostone, hence the hostrock lithology indirectly controls the carbonate mineralogy of speleothems. The precipitation of aragonite in place of calcite occurred only in dolostone caves and is bound to very specific conditions, which are: high fluid Mg/Ca ratios (≥ 0.5), high fluid pH (> 8.2) and low fluid saturation indices for calcite (< 0.8). These specific conditions are induced by slow drip rates of < 0.2 ml/min (often under more arid conditions), causing the precipitation of calcite / aragonite prior to reaching the stalagmite top. Due to this, fluid chemistry is altered, which in turn leads to changes in carbonate mineralogy and geochemistry on the stalagmite top. Interestingly, all of the above mentioned factors must act in a concerted manner. If this is not the case, calcite is the dominant phase. The threshold, where only aragonite precipitates is at fluid Mg

  1. Tropical convective onset statistics and establishing causality in the water vapor-precipitation relation

    NASA Astrophysics Data System (ADS)

    Neelin, J. D.; Kuo, Y. H.; Schiro, K. A.; Langenbrunner, B.; Mechoso, C. R.; Sahany, S.; Bernstein, D. N.

    2015-12-01

    Previous work by various authors has pointed to the role of humidity in the lower free troposphere in affecting the onset of deep convection in the tropics. Empirical relations between column water vapor and the onset of precipitation have been inferred to be related to this. Evidence includes deep-convective conditional instability calculations for entraining plumes, in which the lower free-tropospheric environment affects the onset of deep convection due to the impact on buoyancy of turbulent entrainment of dry versus moist air. Tropical Western Pacific in situ observations, and tropical ocean basin satellite retrievals in comparison to climate model diagnostics each indicate that substantial entrainment is required to explain the observed relationship. In situ observations from the GoAmazon field campaign confirm that the basic relationship holds over tropical land much as it does over tropical ocean (although with greater additional sensitivity to boundary layer variations and to freezing processes). The relationship between deep convection and water vapor is, however, a two-way street, with convection moistening the free troposphere. One might thus argue that there has not yet been a smoking gun in terms of establishing the causality of the precipitation-water vapor relationship. Parameter perturbation experiments in the coupled Community Earth System Model show that when the deep convective scheme has low values of entrainment, the set of statistics associated with the transition to deep convection are radically altered, and the observed pickup of precipitation with column water vapor is no longer seen. In addition to cementing the dominant direction of causality in the fast timescale precipitation-column water vapor relationship, the results point to impacts of this mechanism on the climatology. Because at low entrainment the convection can fire before the lower troposphere is moistened, the climatology of water vapor remains lower than observed. These

  2. Study on the vertical distribution of precipitation amount within the water clouds

    NASA Astrophysics Data System (ADS)

    Kawamoto, K.; Suzuki, K.

    2015-12-01

    This work studied the behavior of radar reflectivity (Ze) of Cloud Profiling Radar on board CloudSat with variation in the properties of low-level water clouds, such as the effective droplet radius (re), geometrical thickness (Dcld), and liquid water path (LWP), over the northwest Pacific and China. The changes in the distribution of maxZe (the largest Ze within a cloud layer) were examined in terms of variation in the cloud parameters such as small, mid and large categories, while maxZe had monomodal distributions regarding variation in re and Dcld, that appeared bimodal in the small category of LWP. It was confirmed that the small category of LWP contained both non-precipitating clouds in the incipient stage and raining clouds in the dissipating stage. Next, optically measured particle size was combined with LWP derived from the microwave measurement to classify the precipitation type. Applying maxZe and Dcld to the analysis of classified precipitation types corroborated the importance of Dcld for examining the occurrence of precipitation. Finally, the position of maxZe relative to the cloud top was investigated using a measure of the probability of precipitation (POP) according to variation in re in order to get better understanding of the vertical distribution of precipitation amount. The results showed that the Pacific and China had 'bow' and 'funnel' shapes, respectively. The emergence of these shapes according to the variation in re was interpreted as the enhancement of Ze due to droplet collisional growth and the attenuation of Ze by the presence of large particles. Furthermore, a detailed analysis of smaller particles (nearly10 μm in radius) reinforced the idea of rapid, efficient particle growth in the lower part of the cloud. Detailed results will be given in the presentation.

  3. Liquid water content and precipitation characteristics of stratiform clouds as inferred from satellite microwave measurements

    SciTech Connect

    Curry, J.A. ); Ardell, C.D. ); Tian, Lin )

    1990-09-20

    In this paper the authors present an analysis of the integrated liquid water content and precipitation characteristics of stratiform clouds using data from the Nimbus 7 Scanning Multichannel Microwave Radiometer (SMMR) for January 1979, over the North Atlantic Ocean (40{degree}-60{degree}N). Concurrent analysis of the SMMR data with the US Air Force 3-Dimensional Nephanalysis (3DNEPH) allows the interpretation of the SMMR-derived liquid water paths and precipitation characteristics in terms of cloud type, cloud fraction, and cloud height. Combining the initialized analyses from the European Center for Medium-Range Weather Forecasting with the 3DNEPH enables vertical temperature and humidity profiles to be incorporated into the retrievals. The interpretation and presentation of results are guided by their implications for the parameterization of liquid water content of layer clouds in large-scale atmospheric models. The average liquid water paths for middle and low clouds were determined to be 115 and 102 g m{sup {minus}2}, respectively, with a maximum value of 1,070 g m{sup {minus}2}. Analysis of the liquid water path as a function of temperature showed that clouds with average temperature below 246 K had little liquid water and were inferred to be predominantly crystalline. Liquid water paths of 350 g m{sup {minus}2} and 500 g m{sup {minus}2} for middle and low clouds, respectively, were determined to be average thresholds for the onset of precipitation. Maximum rain rates for these clouds were determined to be 7 mm h{sup {minus}1}. The autoconversion of cloud water to rain water was determined to occur at a rate of 0.001 s{sup {minus}1}.

  4. Advances in Global Water Cycle Science Made Possible by Global Precipitation Mission (GPM)

    NASA Technical Reports Server (NTRS)

    Smith, Eric A.; Starr, David OC. (Technical Monitor)

    2001-01-01

    Within this decade the internationally sponsored Global Precipitation Mission (GPM) will take an important step in creating a global precipitation observing system from space. One perspective for understanding the nature of GPM is that it will be a hierarchical system of datastreams from very high caliber combined dual frequency radar/passive microwave (PMW) rain-radiometer retrievals, to high caliber PMW rain-radiometer only retrievals, and on to blends of the former datastreams with other less-high caliber PMW-based and IR-based rain retrievals. Within the context of NASA's role in global water cycle science and its own Global Water & Energy Cycle (GWEC) program, GPM is the centerpiece mission for improving our understanding of the global water cycle from a space-based measurement perspective. One of the salient problems within our current understanding of the global water and energy cycle is determining whether a change in the rate of the water cycle is accompanying changes in global temperature. As there are a number of ways in which to define a rate-change of the global water cycle, it is not entirely clear as to what constitutes such a determination, This paper presents an overview of the Global Precipitation Mission and how its datasets can be used in a set of quantitative tests within the framework of the oceanic and continental water budget equations to determine comprehensively whether substantive rate changes do accompany perturbations in global temperatures and how such rate changes manifest themselves in both water storage and water flux transport processes.

  5. Advances in Understanding Global Water Cycle with Advent of Global Precipitation Measurement (GPM) Mission

    NASA Technical Reports Server (NTRS)

    Smith, Eric A.; Starr, David (Technical Monitor)

    2002-01-01

    Within this decade the internationally organized Global Precipitation Measurement (GPM) Mission will take an important step in creating a global precipitation observing system from space. One perspective for understanding the nature of GPM is that it will be a hierarchical system of datastreams beginning with very high caliber combined dual frequency radar/passive microwave (PMW) rain-radiometer retrievals, to high caliber PMW rain-radiometer only retrievals, and then on to blends of the former datastreams with additional lower-caliber PMW-based and IR-based rain retrievals. Within the context of the now emerging global water & energy cycle (GWEC) programs of a number of research agencies throughout the world, GPM serves as a centerpiece space mission for improving our understanding of the global water cycle from a global measurement perspective. One of the salient problems within our current understanding of the global water and energy cycle is determining whether a change in the rate of the water cycle is accompanying changes in climate, e.g., climate warming. As there are a number of ways in which to define a rate-change of the global water cycle, it is not entirely clear as to what constitutes such a determination. This paper presents an overview of the GPM Mission and how its observations can be used within the framework of the oceanic and continental water budget equations to determine whether a given perturbation in precipitation is indicative of an actual rate change in the global water cycle, consistent with required responses in water storage and/or water flux transport processes, or whether it is the natural variability of a fixed rate cycle.

  6. Assessing surface water consumption using remotely-sensed groundwater, evapotranspiration, and precipitation

    NASA Astrophysics Data System (ADS)

    Anderson, Ray G.; Lo, Min-Hui; Famiglietti, James S.

    2012-08-01

    Estimates of consumptive use of surface water by agriculture are vital for assessing food security, managing water rights, and evaluating anthropogenic impacts on regional hydrology. However, reliable, current, and public data on consumptive use can be difficult to obtain, particularly in international and less developed basins. We combine remotely-sensed precipitation and satellite observations of evapotranspiration and groundwater depletion to estimate surface water consumption by irrigated agriculture in California's Central Valley for the 2004-09 water years. We validated our technique against measured consumption data determined from streamflow observations and water export data in the Central Valley. Mean satellite-derived surface water consumption was 291.0 ± 32.4 mm/year while measured surface water consumption was 308.1 ± 6.5 mm/year. The results show the potential for remotely-sensed hydrologic data to independently observe irrigated agriculture's surface water consumption in contested or unmonitored basins. Improvements in the precision and spatial resolution of satellite precipitation, evapotranspiration and gravimetric groundwater observations are needed to reduce the uncertainty in this method and to allow its use on smaller basins and at shorter time scales.

  7. Shortwave direct radiative effects of above-cloud aerosols over global oceans derived from 8 years of CALIOP and MODIS observations

    NASA Astrophysics Data System (ADS)

    Zhang, Zhibo; Meyer, Kerry; Yu, Hongbin; Platnick, Steven; Colarco, Peter; Liu, Zhaoyan; Oreopoulos, Lazaros

    2016-03-01

    In this paper, we studied the frequency of occurrence and shortwave direct radiative effects (DREs) of above-cloud aerosols (ACAs) over global oceans using 8 years (2007-2014) of collocated CALIOP and MODIS observations. Similar to previous work, we found high ACA occurrence in four regions: southeastern (SE) Atlantic region, where ACAs are mostly light-absorbing aerosols, i.e., smoke and polluted dust according to CALIOP classification, originating from biomass burning over the African Savanna; tropical northeastern (TNE) Atlantic and the Arabian Sea, where ACAs are predominantly windblown dust from the Sahara and Arabian deserts, respectively; and the northwestern (NW) Pacific, where ACAs are mostly transported smoke and polluted dusts from Asian. From radiative transfer simulations based on CALIOP-MODIS observations and a set of the preselected aerosol optical models, we found the DREs of ACAs at the top of atmosphere (TOA) to be positive (i.e., warming) in the SE Atlantic and NW Pacific regions, but negative (i.e., cooling) in the TNE Atlantic Ocean and the Arabian Sea. The cancellation of positive and negative regional DREs results in a global ocean annual mean diurnally averaged cloudy-sky DRE of 0.015 W m-2 (range of -0.03 to 0.06 W m-2) at TOA. The DREs at surface and within the atmosphere are -0.15 W m-2 (range of -0.09 to -0.21 W m-2), and 0.17 W m-2 (range of 0.11 to 0.24 W m-2), respectively. The regional and seasonal mean DREs are much stronger. For example, in the SE Atlantic region, the JJA (July-August) seasonal mean cloudy-sky DRE is about 0.7 W m-2 (range of 0.2 to 1.2 W m-2) at TOA. All our DRE computations are publicly available1. The uncertainty in our DRE computations is mainly caused by the uncertainties in the aerosol optical properties, in particular aerosol absorption, the uncertainties in the CALIOP operational aerosol optical thickness retrieval, and the ignorance of cloud and potential aerosol diurnal cycle. In situ and remotely sensed

  8. Water Isotopes in Precipitation: Data/Model Comparison for Present-Day and Past Climates

    NASA Technical Reports Server (NTRS)

    Jouzel, J.; Hoffmann, G.; Masson, V.

    1998-01-01

    Variations of HDO and H2O-18 concentrations are observed in precipitation both on a geographical and on a temporal basis. These variations, resulting from successive isotopic fractionation processes at each phase change of water during its atmospheric cycle, are well documented through the IAEA/WMO network and other sources. Isotope concentrations are, in middle and high latitudes, linearly related to the annual mean temperature at the precipitation site. Paleoclimatologists have used this relationship to infer paleotemperatures from isotope paleodata extractable from ice cores, deep groundwater and other such sources. For this application to be valid, however, the spatial relationship must also hold in time at a given location as the location undergoes a series of climatic changes. Progress in water isotope modeling aimed at examining and evaluating this assumption has been recently reviewed with a focus on polar regions and, more specifically, on Greenland. This article was largely based on the results obtained using the isotopic version of the NASA/GISS Atmospheric General Circulation Model (AGCM) fitted with isotope tracer diagnostics. We extend this review in comparing the results of two different isotopic AGCMs (NASA/GISS and ECHAM) and in examining, with a more global perspective, the validity of the above assumption, i.e. the equivalence of the spatial and temporal isotope-temperature relationship. We also examine recent progress made in modeling the relationship between the conditions prevailing in moisture source regions for precipitation and the deuterium-excess of that precipitation.

  9. Anticipated Improvements in Precipitation Physics and Understanding of Water Cycle from GPM Mission

    NASA Technical Reports Server (NTRS)

    Smith, Eric A.

    2003-01-01

    The GPM mission is currently planned for start in the late-2007 to early-2008 time frame. Its main scientific goal is to help answer pressing scientific problems arising within the context of global and regional water cycles. These problems cut across a hierarchy of scales and include climate-water cycle interactions, techniques for improving weather and climate predictions, and better methods for combining observed precipitation with hydrometeorological prediction models for applications to hazardous flood-producing storms, seasonal flood/draught conditions, and fresh water resource assessments. The GPM mission will expand the scope of precipitation measurement through the use of a constellation of some 9 satellites, one of which will be an advanced TRMM-like core satellite carrying a dual-frequency Ku-Ka band precipitation radar and an advanced, multifrequency passive microwave radiometer with vertical-horizontal polarization discrimination. The other constellation members will include new dedicated satellites and co-existing operational/research satellites carrying similar (but not identical) passive microwave radiometers. The goal of the constellation is to achieve approximately 3-hour sampling at any spot on the globe -- continuously. The constellation s orbit architecture will consist of a mix of sun-synchronous and non-sun-synchronous satellites with the core satellite providing measurements of cloud-precipitation microphysical processes plus calibration-quality rainrate retrievals to be used with the other retrieval information to ensure bias-free constellation coverage. GPM is organized internationally, involving existing, pending, projected, and under-study partnerships which will link NASA and NOAA in the US, NASDA in Japan, ESA in Europe, ISRO in India, CNES in France, and possibly AS1 in Italy, KARI in South Korea, CSA in Canada, and AEB in Brazil. Additionally, the program is actively pursuing agreements with other international collaborators and

  10. Specific lignin precipitation for oligosaccharides recovery from hot water wood extract.

    PubMed

    Chen, Xiaoqian; Wang, Zhaojiang; Fu, Yingjuan; Li, Zongquan; Qin, Menghua

    2014-01-01

    Hot water extraction is an important strategy of wood fractionation, by which the hemicelluloses can be separated for value-added products, while the residual solid can still be processed into traditional wood products. In this study, a combined process consisting of specific lignin precipitation and dialysis was proposed to recover hemicellulosic oligosaccharides (OS) from hot water extract (HWE). The results showed that polyaluminium chloride (PAC) precipitation was highly specific to large molecular lignin, leading to 25.1% lignin removal with negligible OS loss through charge neutralization mechanism. The separation was further enhanced by dialysis, reaching 37.6% OS recovery from HWE with remarkable purity of 94.1%. By the proposed process, 56.36 g OS, mainly xylooligosaccharides with two fractions of 5.2 and 0.51 kDa was recovered from one kg dried wood. This process can be envisaged as a great contribution to wood biorefinery.

  11. Latitudinal change in precipitation and water vapor isotopes over Southern ocean

    NASA Astrophysics Data System (ADS)

    Rahul, P.

    2015-12-01

    The evaporation process over ocean is primary source of water vapor in the hydrological cycle. The Global Network of Isotopes in Precipitation (GNIP) dataset of rainwater and water vapor isotopes are predominantly based on continental observations, with very limited observation available from the oceanic area. Stable isotope ratios in precipitation provide valuable means to understand the process of evaporation and transport of water vapor. This is further extended in the study of past changes in climate from the isotopic composition of ice core. In this study we present latitudinal variability of water vapor and rainwater isotopic composition and compared it with factors like physical condition of sea surface water from near equator (1°S) to the polar front (56°S) during the summer time expedition of the year 2013. The water vapor and rainwater isotopes showed a sharp depletion in isotopes while progressively move southward from the tropical regions (i.e. >30°S), which follows the pattern recorded in the surface ocean water isotopic composition. From the tropics to the southern latitudes, the water vapor d18O varied between -11.8‰ to -14.7‰ while dD variation ranges between -77.7‰ to -122.2‰. Using the data we estimated the expected water vapor isotopic composition under kinetic as well as equilibrium process. Our observation suggests that the water vapor isotopic compositions are in equilibrium with the sea water in majority of cases. At one point of observation, where trajectory of air parcel originated from the continental region, we observed a large deviation from the existing trend of latitudinal variability. The deduced rainwater composition adopting equilibrium model showed a consistent pattern with observed values at the tropical region, while role of kinetic process become dominant on progressive shift towards the southern latitudes. We will draw comparison of our observation with other data available in the literature together with isotope

  12. Precipitation water stable isotope measurements and analyses in Middle and Polar Ural

    NASA Astrophysics Data System (ADS)

    Stukova, Olga; Gribanov, Konstantin; Zakharov, Vyacheslav; Cattani, Olivier; Jouzel, Jean

    2015-11-01

    In this paper, we present results of precipitation (rain, snow) water stable isotope measurements, which were collected on two places. Measuring was made on laser spectroscopy analyzer PICARRO L2130-i equipped with liquid auto sampler. We describe method of sample collecting, preparing, measuring and continuing analysis of experimental data. Stored data include results of 177 samples measuring from Kourovka collected from November 2012 to March 2014 and 73 samples from Labytnangi collected from March 2013 to December 2013.

  13. Solute contributions from precipitation to the compositions of soil waters in a marine terrace chronosequence

    NASA Astrophysics Data System (ADS)

    Vivit, D. V.; White, A. F.; Bullen, T. D.; Fitzpatrick, J.

    2010-12-01

    Solute loading of soil waters by rainfall together with evapo-transpiration can increase the concentrations of various dissolved constituents. This process complicates the modeling of saturation states for the different mineral phases in the soil profile that are products of the weathering of primary minerals found in the original granitic source material. The estimation of true rates of regolith weathering due to CO2 drawdown at temperate hydrogeological sites requires having soil pore water solute concentration data which have been corrected for solute inputs from precipitation before proceeding with chemical weathering calculations. As part of a chemical weathering study of a coastal marine terrace chronosequence located in the vicinity of Wilder Ranch State Park, Santa Cruz County, CA, bulk samplers and automatic precipitation-event samplers installed at a range of sites enabled us to determine elemental concentrations and isotopic compositions of rainfall solutes which influence the overall compositions of the pore waters. Variations in rain sample chemistry (mole-ratio data using Na, Mg, Ca, Cl and SO4) correlated with precipitation intensity result from solute inputs contributed by marine and terrestrial aerosols. Higher strontium-isotope ratios (87Sr/86Sr), which point to radiogenic dust sources, occur in rain water collected in the fall at the beginning of the rainy season while lower ratio values indicating marine aerosol sources appear in winter and spring samples. Use of the NOAA HYSPLIT particle-tracking program for computing the chronological progression of storm tracks during precipitation events could show the development of solute levels in rain. Subsequently, the installation of wind sensors along with the automatic rain collectors afforded the capability of correlating high resolution wind-speed and wind-direction data with changing compositions of rain samples collected at fixed-time intervals during storm events. Wind data show that wind

  14. Tropical intercontinental optical measurement network of aerosol, precipitable water and total column ozone

    NASA Technical Reports Server (NTRS)

    Holben, B. N.; Tanre, D.; Reagan, J. A.; Eck, T. F.; Setzer, A.; Kaufman, Y. A.; Vermote, E.; Vassiliou, G. D.; Lavenu, F.

    1992-01-01

    A new generation of automatic sunphotometers is used to systematically monitor clear sky total column aerosol concentration and optical properties, precipitable water and total column ozone diurnally and annually in West Africa and South America. The instruments are designed to measure direct beam sun, solar aureole and sky radiances in nine narrow spectral bands from the UV to the near infrared on an hourly basis. The instrumentation and the algorithms required to reduce the data for subsequent analysis are described.

  15. Stable isotope compositions of waters in the Great Basin, United States 2. Modern precipitation

    USGS Publications Warehouse

    Friedman, I.; Smith, G.I.; Johnson, C.A.; Moscati, R.J.

    2002-01-01

    Precipitation was collected between 1991 and 1997 at 41 locations within and adjacent to parts of the Great Basin lying in California, Oregon, Nevada, and Utah. These samples were analyzed for their deuterium (??D) and oxygen-18 (??18O) contents. Separate collections were made of summer and winter season precipitation at stations ranging in elevation from -65 m to 3246 m. The ??D per mil values of stations that were closely spaced but at different elevations showed an average ??D decrease of approximately 10???/km rise in elevation. Data for all samples representing winter precipitation, when plotted on a ??D versus ??18O plot, fall close to the Meteoric Water Line (??D = 8 ??18O + 10); samples representing summer precipitation define a line of slightly lower slope due to evaporation of the raindrops during their passage from cloud to ground. Comparison of our 1991-1997 ??D data with those from the same three stations reported by an earlier study in the southeastern California shows seasonal differences ranging from 0 per mil to 19??? (average: 15) and annual differences ranging from 0 to 13 per mil (average: 2), illustrating the degree of annual and seasonal variability in this region. When contoured, the ??D values display gradients indicating a north to northwest decrease in deuterium, with values ranging from -60 to -125??? in winter precipitation and from -40 to -110??? in summer precipitation. These gradient trends can be explained by the predominance of air mass trajectories originating in the tropical Pacific, the Gulf of California, and (in summer) the Gulf of Mexico.

  16. Water And Carbon Fluxes Along An Elevation/Precipitation Gradient In A Sagebrush Steppe Environment

    NASA Astrophysics Data System (ADS)

    Flerchinger, G. N.; Fellows, A.; Seyfried, M. S.

    2015-12-01

    Environmental gradients exert controls on water, carbon and energy fluxes across montane landscapes, impacting the magnitude and timing of evapotranspiration, carbon uptake, water stress, and water use efficiency. Four eddy covariance systems were situated along an elevation gradient in Idaho's Owyhee Mountains. The sites are part of the Reynolds Creek Critical Zone Observatory and contribute to an ongoing long-term environmental monitoring network in the USDA's Reynold's Creek Experimental Watershed. The sites include a Wyoming big sagebrush site, a low sagebrush site, a post-fire mountain big sagebrush site, and a mountain big sagebrush site located at elevations of 1425, 1680, 1808 and 2111 m. Variations in climate follow the montane elevation gradient; mean annual precipitation at the sites is 290, 337, 425, and 795 mm, respectively, and mean annual temperature is 8.9, 8.4, 6.1, 5.4°C. Transpiration peaked about a month earlier at the lower elevation sites, but with limited precipitation the vegetation also encountered water stress much earlier. The two higher elevation sites experienced relatively little water stress and transpired at near potential for most of the growing season. Implications on water use efficiency were investigated.

  17. Modeling Aerosol Effects on Clouds and Precipitation: Insights from CalWater 2015

    NASA Astrophysics Data System (ADS)

    Leung, L. R.; Lim, K. S. S.; Fan, J.; Prather, K. A.; DeMott, P. J.; Spackman, J. R.; Ralph, F. M.

    2015-12-01

    The CalWater 2015 field campaign took place in northern California from mid January through early March of 2015. The field campaign, including collaborations between CalWater 2 and ACAPEX, aims to improve understanding and modeling of large-scale dynamics and cloud and precipitation processes associated with atmospheric rivers (ARs) and aerosol-cloud interactions that influence precipitation variability and extremes in the western U.S. An observational strategy was employed using land and offshore assets to monitor (1) the evolution and structure of ARs from near their regions of development, (2) long range transport of aerosols in eastern North Pacific and potential interactions with ARs, and (3) how aerosols from long-range transport and local sources influence cloud and precipitation in the U.S. During the field campaign, an AR developed in the Northeast Pacific Ocean in early February and made landfall in northern California. In-situ aerosol and cloud measurements from the G-1 aircraft; remote sensing data of clouds and aerosols; and meteorological measurements from aircraft, ship, and ground-based instruments collected from February 5 - 8, 2015 are analyzed to characterize the large-scale environment and cloud and precipitation forming processes. Modeling experiments are designed using a regional model for simulations with a cloud resolving limited area domain and quasi-global coarser resolution domain to evaluate the impacts of aerosols on clouds and precipitation, and to explore the relative contributions of long-range transported and regional aerosols that interacted with the clouds before, during, and after AR landfall. Preliminary results will be discussed in the context of the field data as well as a multi-year simulation of the climatological contributions of long-range transported dust during AR landfall in California.

  18. Alterations in 'water yield' associated with land use changes under different precipitation regime

    NASA Astrophysics Data System (ADS)

    Rohatyn, Shani; Ramati, Efrat; Tatarinov, Fyodor; Rotenberg, Eyal; Tas, Eran; Yakir, Dan

    2016-04-01

    Changes in rainfall regimes and land cover results in complex alterations in plant water use and in ecosystem water balance, which are not well quantified. This results in poor estimates of the 'water yield' (WY; the difference between precipitation, P, input and evapotranspiration, ET, losses), which provides the water available for runoff and re-charge, and ultimately also for human consumption. The objective of this study was to examine the interactions between the effects of land use change (from sparse shrubland to pine forest) on ecosystem WY, and changes in the precipitation regime (from humid Mediterranean to semi-arid conditions). We hypothesized that the forestation increased ET and reduced WY, but this impact diminishes with decreasing precipitation. We used a new approach centered on a custom-built mobile laboratory of eddy co-variance measurements deployed on a campaign basis (about two weeks per site repeated along the seasonal cycle), that allowed us to measure ecosystem-scale ET together with carbon and energy fluxes and meteorological parameters. Measurements were carried out between the years of 2012-2015 in three paired sites of Pinus halepensis forests and adjacent non-forest ecosystems along the rainfall gradient in Israel, from 755 to 290 mm in annual precipitation. Annual ET was estimated from the campaigns results based on multiple regression analyses with meteorological parameters (relative humidity, RH, temperature, T, and global radiation, Rg) from local meteorological stations that provided continuous data records. The results indicated that decrease in annual precipitation by a factor of ~2.5, resulted in decrease in ET by a factor of 2.4 from 685 mm, with WY=210 mm, in the humid forest, to 290 mm, with WY= 0 mm, in the dry forest. In the non-forest ecosystems ET showed relatively small decrease (by a factor of 1.3) from 285 mm, with WY=460 mm, to 220 mm, with WY=95 mm. The differences 'Forest-shrubland' in ET decreased from 400 mm to

  19. Retrieving moisture profiles from precipitable water measurements using a variational data assimilation approach

    SciTech Connect

    Guo, Y.R.; Zou, X.; Kuo, Y.H.

    1996-04-01

    Atmospheric moisture distribution is directly related to the formation of clouds and precipitation and affects the atmospheric radiation and climate. Currently, several remote sensing systems can measure precipitable water (PW) with fairly high accuracy. As part of the development of an Integrated Data Assimilation and Sounding System in support of the Atmospheric Radiation Measurement Program, retrieving the 3-D water vapor fields from PW measurements is an important problem. A new four dimensional variational (4DVAR) data assimilation system based on the Penn State/National Center for Atmospheric Research (NCAR) mesoscale model (MM5) has been developed by Zou et al. (1995) with the adjoint technique. In this study, we used this 4DVAR system to retrieve the moisture profiles. Because we do not have a set of real observed PW measurements now, the special soundings collected during the Severe Environmental Storm and Mesoscale Experiment (SESAME) in 1979 were used to simulate a set of PW measurements, which were then assimilated into the 4DVAR system. The accuracy of the derived water vapor fields was assessed by direct comparison with the detailed specific humidity soundings. The impact of PW assimilation on precipitation forecast was examined by conducting a series of model forecast experiments started from the different initial conditions with or without data assimilation.

  20. Geochemical mass-balance relationships for selected ions in precipitation and stream water, Catoctin Mountains, Maryland.

    USGS Publications Warehouse

    Katz, B.G.; Bricker, O.P.; Kennedy, M.M.

    1985-01-01

    Results of a study of input/output mass balances for major ions based on the chemical composition of precipitation and stream-water, geochemical reactions with different loading rates of hydrogen ion, and watershed processes influencing the chemical character of stream-waters in two small watershed areas are reported with a view to predicting the effect of additions of acidic rain to the watershed systems. Geochemical weathering processes account for the observed changes in the chemistry of stream flow. Although present in bedrock in extremely small quantities, calcite plays an important role in neutralization of the total hydrogen-ion input.-M.S.

  1. Water quality data for precipitation and storm runoff in Pennypack Creek Basin, Philadelphia, Pennsylvania

    USGS Publications Warehouse

    Speight, D.W.

    1989-01-01

    This report presents data on the chemistry of precipitation and storm runoff that were collected during 29 storms from July 1979 through November 1980, in an urban environment in the Pennypack Creek basin, Philadelphia, Pennsylvania. Daily mean and instantaneous stream discharge data were collected at two U.S. Geological Survey gaging stations. Water-quality data collected from these sites and from one storm-sewer sampling site included nutrients, chemical and biochemical oxygen demands, solids, metals, major anions, other constituents, and pH. Instantaneous loads of selected constituents were computed. Chemical oxygen demand, biochemical oxygen demand, sulfate, alkalinity, chloride, and dissolved solids generally were low in precipitation and runoff. During the November 5, 1980 storm at Pine Road, dissolved nitrate concentrations equaled or exceeded 10 milligrams per liter in 17 percent of the samples analyzed and dissolved ammonia nitrogen concentrations exceeded 2.5 milligrams per liter. Generally, a comparison of median concentration of copper, lead, or zinc in precipitation and runoff at the Tustin Street storm-sewer site showed that median concentrations in precipitation were greater than those in runoff.

  2. Instrumental and Reconstructed Water Year Precipitation for the Western United States: A 440-Year Perspective

    NASA Astrophysics Data System (ADS)

    Diaz, H. F.; Wahl, E. R.

    2014-12-01

    We use a suite of reconstructed water year (WY; October through September) streamflow for 12 river basins in the western United States to reconstruct gridded water year precipitation over a similar western US domain. The streamflow values were reconstructed based on moisture sensitive tree ring records and we used values published in the peer-reviewed literature. A set of Principal Components (PC) of the streamflow reconstructions were calibrated against a complementary PC set from an ~120-year long instrumental record of WY precipitation west of ~90˚W to yield a 407 year reconstruction at each gridpoint. We were motivated to assess the rarity of the current extreme 3-year drought in the Southwest US—particularly in California. Hence, our analysis focuses largely on the moisture side of the water balance, although of course, streamflow is an integrator of both evapotranspiration and precipitation. Nevertheless, the strong calibration and validation statistics obtained in our study (and notably for California and Nevada) suggest that WY streamflow in much of the West is mainly driven by precipitation variability. The current WY drought (2013-14) and three year (2012-2014) extended drought is ranked in the instrumental record for California itself as the driest such period since 1895. In our longer reconstructed record of California and adjacent western Nevada, the current dry episode—exceeding one year's mean total in three years—is similar to only three other such occurrences over the past 440 years, centered on 1654, 1795, and 1930. Analyses of anomalous mid-tropospheric (700 hPa) circulation features over the instrumental period (since 1895) show the presence of persistent anticyclonic flow over, near, and to the west of the US Pacific coast during the driest WYs. Some differences in the location and spatial structure of the anomalous Northeast Pacific ridge are evident and these are discussed in the context of low-frequency climate variability and change.

  3. Solute contributions from precipitation to the compositions of soil waters in a marine terrace chronosequence

    NASA Astrophysics Data System (ADS)

    Vivit, D. V.; White, A. F.; Bullen, T. D.; Fitzpatrick, J.

    2009-12-01

    Solute loading of soil waters by rainfall together with evapo-transpiration can increase the concentrations of various dissolved constituents. This process complicates the modeling of saturation states for the different mineral phases in the soil profile that are products of the weathering of primary minerals in the original granitic source material. The estimation of true rates of regolith weathering due to CO2 drawdown at temperate hydrogeological sites requires having soil pore water solute concentration data which have been corrected for solute inputs from precipitation before proceeding with chemical weathering calculations. As part of a chemical weathering study of a coastal marine terrace chronosequence located in the vicinity of Wilder Ranch State Park, Santa Cruz County, CA, bulk samplers and automatic precipitation-event samplers were used at a range of sites to determine elemental concentrations as well as isotopic compositions of rainfall solutes which influence the overall compositions of the pore waters. Variations in rain sample chemistry correlated with precipitation intensity (see Fig. 1) are a result of solute inputs from aerosols of marine and terrestrial origins. Higher isotope ratios (87Sr/86Sr), which point to radiogenic dust sources, were found in rain collected in the fall at the beginning of the rainy season while lower ratio values indicating marine aerosol effects were seen in winter and spring samples. To further understand the development of solute levels in rain, the NOAA HYSPLIT particle-tracking program was used to follow the chronological progression of storm tracks during precipitation events. Subsequently, wind sensors along with the automatic rain collectors were installed in an effort to correlate high resolution wind-speed and wind-direction data with changing compositions of rain samples collected at fixed-time intervals during storm events. Wind data show that wind directions during periods of rainfall generally deviate from

  4. Melting of the precipitated ice IV in LiCl aqueous solution and polyamorphism of water.

    PubMed

    Mishima, Osamu

    2011-12-08

    Melting of the precipitated ice IV in supercooled LiCl-H(2)O solution was studied in the range of 0-0.6 MPa and 160-270 K. Emulsified solution was used to detect this metastable transition. Ice IV was precipitated from the aqueous solution of 2.0 mol % LiCl (or 4.8 mol % LiCl) in each emulsion particle at low-temperature and high-pressure conditions, and the emulsion was decompressed at different temperatures. The melting of ice IV was detected from the temperature change of the emulsified sample during the decompression. There was an apparently sudden change in the slope of the ice IV melting curve (liquidus) in the pressure-temperature diagram. At the high-pressure and high-temperature side of the change, the solute-induced freezing point depression was observed. At the low-pressure and low-temperature side, ice IV transformed into ice Ih on the decompression, and the transition was almost unrelated to the concentration of LiCl. These experimental results were roughly explained by the presumed existence of two kinds of liquid water (low-density liquid water and high-density liquid water), or polyamorphism in water, and by the simple assumption that LiCl dissolved maily in high-density liquid water.

  5. Precipitation Trends and Water Consumption Related to Population in the Southwestern United States: A Reassessment

    NASA Astrophysics Data System (ADS)

    Diaz, Henry F.; Anderson, Craig A.

    1995-03-01

    Water consumption figures for the southwest United States are compared for the last four decades. Past trends in consumption are evaluated in the context of precipitation variability in the region and with regard to Colorado River streamflow changes. The study represents a follow-up look at a previous assessment of water consumption, regional precipitation, and demographic trends in Arizona, California, Colorado, Nevada, New Mexico, and Utah, which account for much of the annual depletions of Colorado River water. The previous study was completed during a wet spell in the West, and trends in all major categories of water consumption were consistently upward. This study indicates that a decline or reversal has taken place in water use in many of the western states. The greater water efficiency (reduced per capita water use) is particularly noteworthy in California, which alone accounts for the lion's share of water depletions from the Colorado River Basin. The years since the mid-1980's have been predominantly dry in much of the West. At the same time, population in the six-state region has ncreased at about the same pace it had grown during prior decades. A shift from irrigation-related uses to civil consumption is evident in the 1980's. Taking into consideration a situation where multiyear dry spells are a normal part of the climate of the region, it appears that irrigation depletions may have peaked in the West. In the future, allocations for civil supply, recreation, and other in-stream uses as well as for hydropower generation may heighten the competition for available water supplies, put pressure on existing pricing policies, and force users toward greater conservation efforts and improved efficiencies.

  6. Trace Perchlorate in Background Ground Water and Local Precipitation, Northern Rio Grande Basin, New Mexico

    NASA Astrophysics Data System (ADS)

    Dale, M.; Longmire, P.; Granzow, K. P.; Englert, D.; Yanicak, S.; Larson, T.; Rearick, M.; Heikoop, J.; Perkins, G.

    2007-12-01

    Perchlorate occurs at detectable concentrations of 0.07 to 0.45 parts per billion (ppb) in ground water of background quality within the northern Rio Grande basin, New Mexico. Ground-water samples were collected from 47 wells and springs near Los Alamos, Santa Fe, and Taos, New Mexico. Analytical methods consisted of liquid and ion chromatography-mass spectrometry mass spectrometry (LC/MS/MS and IC/MS/MS). An upper tolerance limit (mean plus two standard deviations) of 0.40 ppb was calculated from 184 analytical results for the background samples. Six distinguishable ground-water zones were sampled based on location, age, and hydrochemistry. In the Los Alamos area, ground water within the mountain-front and mountain-block region is mostly young or modern (less than 50 years). The regional aquifer including the White Rock Canyon springs are of sub-modern age (greater than 50 years). Tritium data from springs north of Taos indicate ground water of modern and sub-modern ages. Background perchlorate concentrations within the Los Alamos area were consistently higher than those measured in the Taos area. Ground water from the Taos area contains less perchlorate and has lower δ18O and δ2H values than ground water from the Los Alamos area. The elevation at which precipitation occurs with respect to recharge and/or the amount of evapotranspiration may play a role in perchlorate concentration in ground water. Natural variability, hydrogeology, and atmospheric inputs may also affect perchlorate concentration in ground water. A linear regression through perchlorate and chloride concentrations for all stations resulted in an r2 = 0. However, the r2 value of the Los Alamos regional aquifer for perchlorate versus chloride was 0.66. Thirteen precipitation samples were collected in the Los Alamos area. Results from eleven of these samples showed no perchlorate greater than 0.05 and 0.009 ppb, the method detection limit (MDL). Two precipitation samples analyzed using the IC

  7. Soil water and vegetation responses to precipitation and changes in depth to ground water in Owens Valley, California

    USGS Publications Warehouse

    Sorenson, Stephen K.; Dileanis, Peter D.; Branson, Farrel A.

    1991-01-01

    Vegetation on the floor of Owens Valley, California, is composed predominantly of phreatophytic desert communities that are adapted to small quantities of precipitation and alkaline soils. These plant communities are believed to be dependent on the continuing presence of a shallow water table. Maintaining existing plant communities is important to preserve the environmental quality of the valley. Proposals to pump additional quantities of ground water from the valley for export to the city of Los Angeles caused concern about the effect of pumping on the existing vegetation and how the plants would adapt to short- or long-term declines of the shallow water table. To test the ability of selected major shrub species to adapt to water-table decline, four sites were selected, pump-equipped wells were installed, and water-table drawdown was monitored. Soil samples were collected with a hand auger and analyzed by using the filter-paper method to monitor changes in soil water content and soil matric potential at test sites. Plant reactions were determined by measurements of plant cover, shoot growth, and xylem pressure potential. Results of 3 years of monitoring show that growth and cover repetition of the shrubs studied are affected greatly by the quantity of annual precipitation, especially at sites with coarse-textured soils. Plants were not affected by drying soil in the root zone until the maximum matric potential exceeded 4.3 pF (-1,950 kilopascal) at depths greater than 0.5 meter. Rabbit-brush was most sensitive to dry soil and was the only shrub species that died as the result of water stress from water-table drawdown. The change in cover repetition correlated positively with the magnitude of water-table drawdown at one site and negatively at another site. Measurements of xylem pressure potential taken before dawn correlated well with water content in the upper 1.5 meters of soil. The magnitude of water-table drawdown achieved by the pump-equipped wells was less

  8. Precipitation Recycling

    NASA Technical Reports Server (NTRS)

    Eltahir, Elfatih A. B.; Bras, Rafael L.

    1996-01-01

    The water cycle regulates and reflects natural variability in climate at the regional and global scales. Large-scale human activities that involve changes in land cover, such as tropical deforestation, are likely to modify climate through changes in the water cycle. In order to understand, and hopefully be able to predict, the extent of these potential global and regional changes, we need first to understand how the water cycle works. In the past, most of the research in hydrology focused on the land branch of the water cycle, with little attention given to the atmospheric branch. The study of precipitation recycling which is defined as the contribution of local evaporation to local precipitation, aims at understanding hydrologic processes in the atmospheric branch of the water cycle. Simply stated, any study on precipitation recycling is about how the atmospheric branch of the water cycle works, namely, what happens to water vapor molecules after they evaporate from the surface, and where will they precipitate?

  9. The effect of antiscalant addition on calcium carbonate precipitation for a simplified synthetic brackish water reverse osmosis concentrate.

    PubMed

    Greenlee, Lauren F; Testa, Fabrice; Lawler, Desmond F; Freeman, Benny D; Moulin, Philippe

    2010-05-01

    The primary limitations to inland brackish water reverse osmosis (RO) desalination are the cost and technical feasibility of concentrate disposal. To decrease concentrate volume, a side-stream process can be used to precipitate problematic scaling salts and remove the precipitate with a solid/liquid separation step. The treated concentrate can then be purified through a secondary reverse osmosis stage to increase overall recovery and decrease the volume of waste requiring disposal. Antiscalants are used in an RO system to prevent salt precipitation but might affect side-stream concentrate treatment. Precipitation experiments were performed on a synthetic RO concentrate with and without antiscalant; of particular interest was the precipitation of calcium carbonate. Particle size distributions, calcium precipitation, microfiltration flux, and scanning electron microscopy were used to evaluate the effects of antiscalant type, antiscalant concentration, and precipitation pH on calcium carbonate precipitation and filtration. Results show that antiscalants can decrease precipitate particle size and change the shape of the particles; smaller particles can cause an increase in microfiltration flux decline during the solid/liquid separation step. The presence of antiscalant during precipitation can also decrease the mass of precipitated calcium carbonate.

  10. Short-Term Effects of Changing Precipitation Patterns on Shrub-Steppe Grasslands: Seasonal Watering Is More Important than Frequency of Watering Events

    PubMed Central

    Densmore-McCulloch, Justine A.; Thompson, Donald L.; Fraser, Lauchlan H.

    2016-01-01

    Climate change is expected to alter precipitation patterns. Droughts may become longer and more frequent, and the timing and intensity of precipitation may change. We tested how shifting precipitation patterns, both seasonally and by frequency of events, affects soil nitrogen availability, plant biomass and diversity in a shrub-steppe temperate grassland along a natural productivity gradient in Lac du Bois Grasslands Protected Area near Kamloops, British Columbia, Canada. We manipulated seasonal watering patterns by either exclusively watering in the spring or the fall. To simulate spring precipitation we restricted precipitation inputs in the fall, then added 50% more water than the long term average in the spring, and vice-versa for the fall precipitation treatment. Overall, the amount of precipitation remained roughly the same. We manipulated the frequency of rainfall events by either applying water weekly (frequent) or monthly (intensive). After 2 years, changes in the seasonality of watering had greater effects on plant biomass and diversity than changes in the frequency of watering. Fall watering reduced biomass and increased species diversity, while spring watering had little effect. The reduction in biomass in fall watered treatments was due to a decline in grasses, but not forbs. Plant available N, measured by Plant Root Simulator (PRS)-probes, increased from spring to summer to fall, and was higher in fall watered treatments compared to spring watered treatments when measured in the fall. The only effect observed due to frequency of watering events was greater extractable soil N in monthly applied treatments compared to weekly watering treatments. Understanding the effects of changing precipitation patterns on grasslands will allow improved grassland conservation and management in the face of global climatic change, and here we show that if precipitation is more abundant in the fall, compared to the spring, grassland primary productivity will likely be

  11. Short-Term Effects of Changing Precipitation Patterns on Shrub-Steppe Grasslands: Seasonal Watering Is More Important than Frequency of Watering Events.

    PubMed

    Densmore-McCulloch, Justine A; Thompson, Donald L; Fraser, Lauchlan H

    2016-01-01

    Climate change is expected to alter precipitation patterns. Droughts may become longer and more frequent, and the timing and intensity of precipitation may change. We tested how shifting precipitation patterns, both seasonally and by frequency of events, affects soil nitrogen availability, plant biomass and diversity in a shrub-steppe temperate grassland along a natural productivity gradient in Lac du Bois Grasslands Protected Area near Kamloops, British Columbia, Canada. We manipulated seasonal watering patterns by either exclusively watering in the spring or the fall. To simulate spring precipitation we restricted precipitation inputs in the fall, then added 50% more water than the long term average in the spring, and vice-versa for the fall precipitation treatment. Overall, the amount of precipitation remained roughly the same. We manipulated the frequency of rainfall events by either applying water weekly (frequent) or monthly (intensive). After 2 years, changes in the seasonality of watering had greater effects on plant biomass and diversity than changes in the frequency of watering. Fall watering reduced biomass and increased species diversity, while spring watering had little effect. The reduction in biomass in fall watered treatments was due to a decline in grasses, but not forbs. Plant available N, measured by Plant Root Simulator (PRS)-probes, increased from spring to summer to fall, and was higher in fall watered treatments compared to spring watered treatments when measured in the fall. The only effect observed due to frequency of watering events was greater extractable soil N in monthly applied treatments compared to weekly watering treatments. Understanding the effects of changing precipitation patterns on grasslands will allow improved grassland conservation and management in the face of global climatic change, and here we show that if precipitation is more abundant in the fall, compared to the spring, grassland primary productivity will likely be

  12. Comparison of precipitable water over Ghana using GPS signals and reanalysis products

    NASA Astrophysics Data System (ADS)

    Acheampong, A. A.; Fosu, C.; Amekudzi, L. K.; Kaas, E.

    2015-11-01

    Signals from Global Navigational Satellite Systems (GNSS) when integrated with surface meteorological parameters can be used to sense atmospheric water vapour. Using gLAB software and employing precise point positioning techniques, zenith troposphere delays (ZTD) for a GPS base station at KNUST, Kumasi have been computed and used to retrieve Precipitable Water (PW). The PW values obtained were compared with products from ERA-Interim and NCEP reanalysis data. The correlation coefficients, r, determined from these comparisons were 0.839 and 0.729 for ERA-interim and NCEP respectively. This study has demonstrated that water vapour can be retrieved with high precision from GNSS signal. Furthermore, a location map have been produced to serve as a guide in adopting and installing GNSS base stations in Ghana to achieve a country wide coverage of GNSS based water vapour monitoring.

  13. Impacts of precipitation variability on plant species and community water stress in a temperate deciduous forest in the central US

    SciTech Connect

    Gu, Lianhong; Pallardy, Stephen G.; Hosman, Kevin P.; Sun, Ying

    2015-12-11

    Variations in precipitation regimes can shift ecosystem structure and function by altering frequency, severity and timing of plant water stress. There is a need for predictively understanding impacts of precipitation regimes on plant water stress in relation to species water use strategies. Here we first formulated two complementary, physiologically-linked measures of precipitation variability (PV) - Precipitation Variability Index (PVI) and Average Recurrence Interval of Effective Precipitation (ARIEP). We then used nine-year continuous measurements of Predawn Leaf Water Potential Integral (PLWPI) in a central US forest to relate PVI and ARIEP to actual plant water availability and comparative water stress responses of six species with different capacities to regulate their internal water status. We found that PVI and ARIEP explained nearly all inter-annual variations in PLWPI for all species as well as for the community scaled from species measurements. The six species investigated showed differential sensitivities to variations in precipitation regimes. Their sensitivities were reflected more in the responses to PVI and ARIEP than to the mean precipitation rate. Further, they exhibited tradeoffs between responses to low and high PV. Finally, PVI and ARIEP were closely correlated with temporal integrals of positive temperature anomalies and vapor pressure deficit. We suggest that the comparative responses of plant species to PV are part of species-specific water use strategies in a plant community facing the uncertainty of fluctuating precipitation regimes. In conclusion, PVI and ARIEP should be adopted as key indices to quantify physiological drought and the ecological impacts of precipitation regimes in a changing climate.

  14. Impacts of precipitation variability on plant species and community water stress in a temperate deciduous forest in the central US

    DOE PAGES

    Gu, Lianhong; Pallardy, Stephen G.; Hosman, Kevin P.; ...

    2015-12-11

    Variations in precipitation regimes can shift ecosystem structure and function by altering frequency, severity and timing of plant water stress. There is a need for predictively understanding impacts of precipitation regimes on plant water stress in relation to species water use strategies. Here we first formulated two complementary, physiologically-linked measures of precipitation variability (PV) - Precipitation Variability Index (PVI) and Average Recurrence Interval of Effective Precipitation (ARIEP). We then used nine-year continuous measurements of Predawn Leaf Water Potential Integral (PLWPI) in a central US forest to relate PVI and ARIEP to actual plant water availability and comparative water stress responsesmore » of six species with different capacities to regulate their internal water status. We found that PVI and ARIEP explained nearly all inter-annual variations in PLWPI for all species as well as for the community scaled from species measurements. The six species investigated showed differential sensitivities to variations in precipitation regimes. Their sensitivities were reflected more in the responses to PVI and ARIEP than to the mean precipitation rate. Further, they exhibited tradeoffs between responses to low and high PV. Finally, PVI and ARIEP were closely correlated with temporal integrals of positive temperature anomalies and vapor pressure deficit. We suggest that the comparative responses of plant species to PV are part of species-specific water use strategies in a plant community facing the uncertainty of fluctuating precipitation regimes. In conclusion, PVI and ARIEP should be adopted as key indices to quantify physiological drought and the ecological impacts of precipitation regimes in a changing climate.« less

  15. Long-term trends in stream water and precipitation chemistry at five headwater basins in the northeastern United States

    USGS Publications Warehouse

    Clow, David W.; Mast, M. Alisa

    1999-01-01

    Stream water data from five headwater basins in the northeastern United States covering water years 1968-1996 and precipitation data from eight nearby precipitation monitoring sites covering water years 1984-1996 were analyzed for temporal trends in chemistry using the nonparametric seasonal Kendall test. Concentrations of SO4 declined at three of five streams during 1968,1996 (p < 0.1), and all of the streams exhibited downward trends in SO4 over the second half of the period (1984-1996). Concentrations of SO4 in precipitation declined at seven of eight sites from 1984 to 1996, and the magnitudes of the declines (-0.7 to -2.0 ??eq L-1 yr-1) generally were similar to those of stream water SO4. These results indicate that changes in precipitation SO4 were of sufficient magnitude to account for changes in stream water SO4. Concentrations of Ca + Mg declined at three of five streams and five of eight precipitation sites from 1984 to 1996. Precipitation acidity decreased at five of eight sites during the same period, but alkalinity increased in only one stream. In most cases the decreases in stream water SO4 were similar in magnitude to declines in stream water Ca + Mg, which is consistent with the theory of leaching by mobile acid anions in soils. In precipitation the magnitudes of SO4 declines were similar to those of hydrogen, and declines in Ca + Mg were much smaller. This indicates that recent decreases in SO4 deposition are now being reflected in reduced precipitation acidity. The lack of widespread increases in stream water alkalinity, despite the prevalence of downward trends in Stream water SO4, suggests that at most sites, increases in stream water pH and acid-neutralizing capacity may be delayed until higher soil base-saturation levels are achieved.

  16. The Potential of Water Vapor & Precipitation Estimation with a Differential-frequency Radar

    NASA Technical Reports Server (NTRS)

    Meneghini, Robert; Liao, Liang; Tian, Lin

    2006-01-01

    In the presence of rain, the radar return powers from a three-frequency radar, with center frequency at 22.235 GHz and upper and lower frequencies chosen with equal water vapor absorption coefficients, can be used to estimate water vapor density and parameters of the precipitation. A linear combination of differential measurements between the center and lower frequencies on one hand and the upper and lower frequencies on the other provide an estimate of differential water vapor absorption. Conversely, the difference in radar reflectivity factors (in dB) between the upper and lower frequencies is independent of water vapor absorption and can be used to estimate the median mass diameter of the hydrometeors. For a down-looking radar, path-integrated estimates of water vapor absorption may be possible under rain-free as well as raining conditions by using the surface returns at the three frequencies. Cross-talk or interference between the precipitation and water vapor estimates depends on the frequency separation of the channels as well as on the phase state and the median mass diameter of the hydrometeors. Simulations of the retrieval of water vapor absorption show that the largest source of variability arises from the variance in the measured radar return powers while the largest biases occur in the mixed-phase region. Use of high pulse repetition frequencies and signal whitening methods may be needed to obtain the large number of independent samples required. Measurements over a fractional bandwidth, defined as the ratio of the difference between the upper and lower frequencies to the center frequency, up to about 0.2 should be passible in a differential frequency mode, where a single transceiver and antenna are used. Difficulties in frequency allocation may require alternative choices of frequency where the water vapor absorptions at the low and high frequencies are unequal. We consider the degradation in the retrieval accuracy when the frequencies are not optimum.

  17. Refining hot-water extracted silk sericin by ethanol-induced precipitation.

    PubMed

    Oh, Hanjin; Lee, Ji Young; Kim, Moo Kon; Um, In Chul; Lee, Ki Hoon

    2011-01-01

    In order to improve some inherent disadvantages in the mechanical properties of silk sericin (SS), we prepared ethanol-precipitated sericin (EpSS) by adding ethanol into hot-water extracted sericin (HS) solution. EpSS had higher viscosity compared to HS and it was due to the differences in their molecular weight distribution (MWD). The different MWD of EpSS was due to the different solubility of sericin molecules at various concentrations of ethanol, and the amino acid composition of EpSS showed that the more hydrophobic sericin is precipitated more readily in the presence of ethanol. The secondary structure of sericin is also changed from a random coil to β-sheet structure when the amount of ethanol added is high enough. The DSC analysis also revealed that EpSSs has a more compact structure. Finally, when beads were prepared from EpSS, they had enhanced compressive strength compared to those from HS.

  18. Aragonite precipitation induced by anaerobic oxidation of methane in shallow-water seeps, Tyrrhenian Sea, Italy

    NASA Astrophysics Data System (ADS)

    Wiedling, Johanna; Kuhfuß, Hanna; Lott, Christian; Böttcher, Michael E.; Lichtschlag, Anna; Wegener, Gunter; Deusner, Christian; Bach, Wolfgang; Weber, Miriam

    2014-05-01

    In the shallow-water organic-poor silicate sands off the West coast of Elba, Italy, we found aragonite precipitates within a radius of 10 cm to methane seeps in 20 - 40 cm sediment depth. The shallow seep site was mapped by SCUBA diving and in an area of 100 m2 nine gas emission spots were observed. The gas emission, containing 73 Vol. % methane, was measured to be 0.72 L m-2 d-1. Findings of anaerobic methane oxidizing archea (ANME 1, 2, 2a, 2b) and sulphate reducing bacteria (SRB) as well as in vitro rate measurements of anaerobic oxidation of methane (AOM) with a maximum of 67 ± 7 nmol CH4 cm-3 d-1 led to the hypothesis that carbonate precipitation is coupled to these microbial processes. Porewater analysis showed elevated concentrations of dissolved inorganic carbon (DIC) (up to 15.5 mmol L-1) and hydrogen sulfide (up to 6.6 mmol L-1). The presence of bicarbonate and the ambient temperature (14 - 25 ° C) facilitate the precipitation of needle-shaped aragonite. Oxygen isotope compositions of the mineral are consistent with the ambient temperatures and may indicate a recent diagenetic formation of this mineral. Although precipitation should not be preserved in these sandy permeable sediments, influenced by seasonality, wave action, and fluid flow, we found up to 10-50 cm3 irregular pieces of cemented sand grains, very often encrusting dead seagrass rhizomes. Commonly known carbonate structures, especially from the deep sea, are chimneys, mounds, hardgrounds and nodules. These structures are well known from seep and vent sites, usually showing the same range of stable carbon isotope fractionation as the escaping methane. The permeable sediment at the Elba site possibly allows the gas to frequently change its pathway to the sediment surface and thus precipitation can occure at several spots and more irregular than in the reported sites. Preservation of precipitates, however, requires sufficient authigenic aragonite to be formed before fluid dynamics changed the

  19. Climate Change Impacts on US Precipitation Extremes and Consequences for Hydraulic Infrastructures and Water Resources

    NASA Astrophysics Data System (ADS)

    Pal, S.; Kumar, D.; Mishra, V.; Ganguly, A. R.

    2013-12-01

    Precipitation extremes in the conterminous United States are expected to intensify and grow more frequent with climate change. However, translating this climate insight to metrics relevant for hydraulic infrastructures or water resources remains a challenge. The primary issue is one of scale, which in turn may ultimately stem from the space-time variability in, and our lack of understanding of, fine-scale precipitation processes. Here we examine the hypothesis that credible metrics for civil engineers and hydrologists can be obtained through extreme value analysis of regional climate model simulations. Specifically, we develop intensity-duration-frequency (IDF) curves from the North American Regional Climate Change Assessment Program (NARCCAP) simulations, and characterize uncertainties by comparing with observations. We attempt to understand the nature of the insights, if any, that can be extracted despite the uncertainties.

  20. Simulating the effects of ground-water withdrawals on streamflow in a precipitation-runoff model

    USGS Publications Warehouse

    Zarriello, P.J.; Barlow, P.M.; Duda, P.B.

    2004-01-01

    Precipitation-runoff models are used to assess the effects of water use and management alternatives on streamflow. Often, ground-water withdrawals are a major water-use component that affect streamflow, but the ability of surface-water models to simulate ground-water withdrawals is limited. As part of a Hydrologic Simulation Program-FORTRAN (HSPF) precipitation-runoff model developed to analyze the effect of ground-water and surface-water withdrawals on streamflow in the Ipswich River in northeastern Massachusetts, an analytical technique (STRMDEPL) was developed for calculating the effects of pumped wells on streamflow. STRMDEPL is a FORTRAN program based on two analytical solutions that solve equations for ground-water flow to a well completed in a semi-infinite, homogeneous, and isotropic aquifer in direct hydraulic connection to a fully penetrating stream. One analytical method calculates unimpeded flow at the stream-aquifer boundary and the other method calculates the resistance to flow caused by semipervious streambed and streambank material. The principle of superposition is used with these analytical equations to calculate time-varying streamflow depletions due to daily pumping. The HSPF model can readily incorporate streamflow depletions caused by a well or surface-water withdrawal, or by multiple wells or surface-water withdrawals, or both, as a combined time-varying outflow demand from affected channel reaches. These demands are stored as a time series in the Watershed Data Management (WDM) file. This time-series data is read into the model as an external source used to specify flow from the first outflow gate in the reach where these withdrawals are located. Although the STRMDEPL program can be run independently of the HSPF model, an extension was developed to run this program within GenScn, a scenario generator and graphical user interface developed for use with the HSPF model. This extension requires that actual pumping rates for each well be stored

  1. Predictability of horizontal water vapor transport relative to precipitation: Enhancing situational awareness for forecasting western U.S. extreme precipitation and flooding

    USGS Publications Warehouse

    Lavers, David A.; Waliser, Duane E.; Ralph, F. Martin; Dettinger, Michael

    2016-01-01

    The western United States is vulnerable to socioeconomic disruption due to extreme winter precipitation and floods. Traditionally, forecasts of precipitation and river discharge provide the basis for preparations. Herein we show that earlier event awareness may be possible through use of horizontal water vapor transport (integrated vapor transport (IVT)) forecasts. Applying the potential predictability concept to the National Centers for Environmental Prediction global ensemble reforecasts, across 31 winters, IVT is found to be more predictable than precipitation. IVT ensemble forecasts with the smallest spreads (least forecast uncertainty) are associated with initiation states with anomalously high geopotential heights south of Alaska, a setup conducive for anticyclonic conditions and weak IVT into the western United States. IVT ensemble forecasts with the greatest spreads (most forecast uncertainty) have initiation states with anomalously low geopotential heights south of Alaska and correspond to atmospheric rivers. The greater IVT predictability could provide warnings of impending storminess with additional lead times for hydrometeorological applications.

  2. Determination of trifluoroacetic acid in 1996--1997 precipitation and surface waters in California and Nevada

    SciTech Connect

    Wujcik, C.E.; Cahill, T.M.; Seiber, J.N.

    1999-05-15

    The atmospheric degradation of three chlorofluorocarbon (CFC) replacement compounds, namely HFC-134a, HCFC-123, and HCFC-124, results in the formation of trifluoroacetic acid (TFA). Concentrations of TFA were determined in precipitation and surface water samples collected in California and Nevada during 1996--1997. Terminal lake systems were found to have concentrations 4--13 times higher than their calculated yearly inputs, providing evidence for accumulation. The results support dry deposition as the primary contributor of TFA to surface waters in arid and semiarid environments. Precipitation samples obtained from three different locations contained 20.7--1530 ng/L with significantly higher concentrations in fogwater over rainwater. Elevated levels of TFA were observed for rainwater collected in Nevada over those collected in California, indicating continual uptake and concentration as clouds move from a semiarid to arid climate. Thus several mechanisms exist, including evaporative concentration, vapor-liquid phase partitioning, lowered washout volumes of atmospheric deposition water, and dry deposition, which may lead to elevated concentrations of TFA in atmospheric and surface waters above levels expected from usual rainfall washout.

  3. Annual precipitation regulates spatial and temporal drivers of lake water clarity.

    PubMed

    Rose, Kevin C; Greb, Steven R; Diebel, Matthew; Turner, Monica G

    2017-03-01

    Understanding how and why lakes vary and respond to different drivers through time and space is needed to understand, predict, and manage freshwater quality in an era of rapidly changing land use and climate. Water clarity regulates many characteristics of aquatic ecosystems and is responsive to watershed features, making it a sentinel of environmental change. However, whether precipitation alters the relative importance of features that influence lake water clarity or the spatial scales at which they operate is unknown. We used a data set of thousands of northern temperate lakes and asked (1) How does water clarity differ between a very wet vs. dry year? (2) Does the relative importance of different watershed features, or the spatial extent at which they are measured, vary between wet and dry years? (3) What lake and watershed characteristics regulate long-term water clarity trends? Among lakes, water clarity was reduced and less variable in the wet year than in the dry year; furthermore, water clarity was reduced much more in high-clarity lakes during the wet year than in low-clarity lakes. Climate, land use/land cover, and lake morphometry explained most variance in clarity among lakes in both years, but the spatial scales at which some features were important differed between the dry and wet years. Watershed percent agriculture was most important in the dry year, whereas riparian zone percent agriculture (around each lake and upstream features) was most important in the wet year. Between 1991 and 2012, water clarity declined in 23% of lakes and increased in only 6% of lakes. Conductance influenced the direction of temporal trend (clarity declined in lakes with low conductance), whereas the proportion of watershed wetlands, catchment-to-lake-area ratio, and lake maximum depth interacted with antecedent precipitation. Many predictors of water clarity, such as lake depth and landscape position, are features that cannot be readily managed. Given trends of

  4. Soil Water Balance and Water Use Efficiency of Dryland Wheat in Different Precipitation Years in Response to Green Manure Approach

    NASA Astrophysics Data System (ADS)

    Zhang, Dabin; Yao, Pengwei; Na, Zhao; Cao, Weidong; Zhang, Suiqi; Li, Yangyang; Gao, Yajun

    2016-05-01

    Winter wheat (Triticum aestivum L.) monoculture is conventionally cultivated followed by two to three months of summer fallow in the Loess Plateau. To develop a sustainable cropping system, we conducted a six-year field experiment to investigate the effect of leguminous green manure (LGM) instead of bare fallow on the yield and water use efficiency (WUE) of winter wheat and the soil water balance (SWB) in different precipitation years in a semi-arid region of northwest China. Results confirmed that planting LGM crop consumes soil water in the fallow season can bring varied effects to the subsequent wheat. The effect is positive or neutral when the annual precipitation is adequate, so that there is no significant reduction in the soil water supplied to wheat. If this is not the case, the effect is negative. On average, the LGM crop increased wheat yield and WUE by 13% and 28%, respectively, and had considerable potential for maintaining the SWB (0–200 cm) compared with fallow management. In conclusion, cultivation of the LGM crop is a better option than fallow to improve the productivity and WUE of the next crop and maintain the soil water balance in the normal and wet years in the Loess Plateau.

  5. Soil Water Balance and Water Use Efficiency of Dryland Wheat in Different Precipitation Years in Response to Green Manure Approach

    PubMed Central

    Zhang, Dabin; Yao, Pengwei; Na, Zhao; Cao, Weidong; Zhang, Suiqi; Li, Yangyang; Gao, Yajun

    2016-01-01

    Winter wheat (Triticum aestivum L.) monoculture is conventionally cultivated followed by two to three months of summer fallow in the Loess Plateau. To develop a sustainable cropping system, we conducted a six-year field experiment to investigate the effect of leguminous green manure (LGM) instead of bare fallow on the yield and water use efficiency (WUE) of winter wheat and the soil water balance (SWB) in different precipitation years in a semi-arid region of northwest China. Results confirmed that planting LGM crop consumes soil water in the fallow season can bring varied effects to the subsequent wheat. The effect is positive or neutral when the annual precipitation is adequate, so that there is no significant reduction in the soil water supplied to wheat. If this is not the case, the effect is negative. On average, the LGM crop increased wheat yield and WUE by 13% and 28%, respectively, and had considerable potential for maintaining the SWB (0–200 cm) compared with fallow management. In conclusion, cultivation of the LGM crop is a better option than fallow to improve the productivity and WUE of the next crop and maintain the soil water balance in the normal and wet years in the Loess Plateau. PMID:27225842

  6. Precipitation and river water chemistry of the Piracicaba River basin, southeast Brazil.

    PubMed

    Williams, M R; Filoso, S; Martinelli, L A; Lara, L B; Camargo, P B

    2001-01-01

    Annual precipitation and river water volumes and chemistry were measured from 1995 to 1998 in a mesoscale agricultural area of southeast Brazil. Precipitation was mildly acidic and solute concentrations were higher in the west than in the east of the basin. Combustion products from biomass burning, automobile exhaust, and industry typically accumulate in the atmosphere from March until October and are responsible for seasonal differences observed in precipitation chemistry. In river waters, the volume-weighted mean (VWM) concentrations of major solutes at 10 sites across the basin were generally lower at upriver than at downriver sampling sites for most solutes. Mass balances for major solutes indicate that, as a regional entity, the Piracicaba River basin was a net sink of H+, PO4(3-), and NH4+, and a net source of other solutes. The main stem of the Piracicaba River had a general increase in solute concentrations from upriver to downriver sampling sites. In contrast, NO3- and NH4+ concentrations increased in the mid-reach sampling sites and decreased due to immobilization or utilization in the mid-reach reservoir, and there was denitrification immediately downriver of this reservoir. Compared with tributaries of the Chesapeake Bay estuary, the Piracicaba River is affected more by point-source inputs of raw sewage and industrial wastes than nonpoint agricultural runoff high in N and P. Inputs of N and C are responsible for a degradation of water quality at downriver sampling sites of the Piracicaba River drainage, and water quality could be considerably improved by augmenting sewage treatment.

  7. Contrasting precipitation seasonality influences evapotranspiration dynamics in water-limited shrublands

    NASA Astrophysics Data System (ADS)

    Villarreal, Samuel; Vargas, Rodrigo; Yepez, Enrico A.; Acosta, Jose S.; Castro, Angel; Escoto-Rodriguez, Martin; Lopez, Eulogio; Martínez-Osuna, Juan; Rodriguez, Julio C.; Smith, Stephen V.; Vivoni, Enrique R.; Watts, Christopher J.

    2016-02-01

    Water-limited ecosystems occupy nearly 30% of the Earth, but arguably, the controls on their ecosystem processes remain largely uncertain. We analyzed six site years of eddy covariance measurements of evapotranspiration (ET) from 2008 to 2010 at two water-limited shrublands: one dominated by winter precipitation (WP site) and another dominated by summer precipitation (SP site), but with similar solar radiation patterns in the Northern Hemisphere. We determined how physical forcing factors (i.e., net radiation (Rn), soil water content (SWC), air temperature (Ta), and vapor pressure deficit (VPD)) influence annual and seasonal variability of ET. Mean annual ET at SP site was 455 ± 91 mm yr-1, was mainly influenced by SWC during the dry season, by Rn during the wet season, and was highly sensitive to changes in annual precipitation (P). Mean annual ET at WP site was 363 ± 52 mm yr-1, had less interannual variability, but multiple variables (i.e., SWC, Ta, VPD, and Rn) were needed to explain ET among years and seasons. Wavelet coherence analysis showed that ET at SP site has a consistent temporal coherency with Ta and P, but this was not the case for ET at WP site. Our results support the paradigm that SWC is the main control of ET in water-limited ecosystems when radiation and temperature are not the limiting factors. In contrast, when P and SWC are decoupled from available energy (i.e., radiation and temperature), then ET is controlled by an interaction of multiple variables. Our results bring attention to the need for better understanding how climate and soil dynamics influence ET across these globally distributed ecosystems.

  8. Evaporation tagging and atmospheric water budget analysis with WRF: A regional precipitation recycling study for West Africa

    NASA Astrophysics Data System (ADS)

    Arnault, Joel; Knoche, Richard; Wei, Jianhui; Kunstmann, Harald

    2016-03-01

    Regional precipitation recycling is the measure of the contribution of local evaporation E to local precipitation. This study provides a set of two methods developed in the Weather Research and Forecasting WRF model system for investigating regional precipitation recycling mechanisms: (1) tracking of tagged atmospheric water species originating from evaporation in a source region, ie E-tagging, and (2) three-dimensional budgets of total and tagged atmospheric water species. These methods are used to quantify the effect of return flow and nonwell vertical mixing neglected in the computation of the bulk precipitation recycling ratio. The developed algorithms are applied to a WRF simulation of the West African Monsoon 2003. The simulated region is characterized by vertical wind shear condition, i.e., southwesterlies in the low levels and easterlies in the mid-levels, which favors return flow and nonwell vertical mixing. Regional precipitation recycling is investigated in 100 × 100 and 1000 × 1000 km2 areas. A prerequisite condition for evaporated water to contribute to the precipitation process in both areas is that it is lifted to the mid-levels where hydrometeors are produced. In the 100 × 100 (1000 × 1000) km2 area the bulk precipitation recycling ratio is 0.9 (7.3) %. Our budget analysis reveals that return flow and nonwell vertically mixed outflow increase this value by about +0.2 (2.9) and +0.2 (1.6) %, respectively, thus strengthening the well-known scale-dependency of regional precipitation recycling.

  9. Estimating Ground-Water Recharge from Precipitation on Whidbey and Camano Islands, Island County, Washington, Water Years 1998 and 1999

    USGS Publications Warehouse

    Sumioka, S.S.; Bauer, H.H.

    2003-01-01

    Ground-water recharge from precipitation to unconsolidated deposits on Whidbey and Camano Islands, Washington, was estimated for water years 1998-99 using a near-surface water-balance method and a chloride mass-balance method. A daily near-surface water-balance method, the Deep Percolation Model (DPM), was used to simulate water budgets for October 1, 1997 through September 30, 1999 (water years 1998-99) for six small drainage basins?four on Whidbey Island and two on Camano Island. Adjusted parameters from the DPM for each small basin were then used in island-wide DPM simulations. A spatial distribution of annual recharge was simulated for each island, with island averages of 5.71 inches per year for Whidbey Island and 5.98 inches per year for Camano Island. The spatial distribution of simulated annual recharge for each island reflects variations in precipitation amounts and the distribution of surficial materials. DPM results indicate that recharge generally is higher in areas underlain by coarse-grained deposits (outwash) than in areas underlain by fine-grained deposits (till). A chloride mass-balance method was used to estimate combined recharge to unconsolidated deposits on Whidbey and Camano Islands. The average combined recharge for Whidbey and Camano Islands estimated by this method was 2.00 inches per year. The range of chloride concentrations in ground-water samples from selected wells indicates that the average recharge to unconsolidated deposits ranges from 0.78 to 7.81 inches per year. Sources of chloride in ground water other than from the atmosphere would cause recharge estimated by the chloride mass-balance method to be less than the actual recharge, therefore, these estimates may represent lower limits.

  10. Precipitation and Topography as Drivers of Tree Water Use and Productivity at Multiple Scales

    NASA Astrophysics Data System (ADS)

    Martin, J. T.; Hu, J.; Looker, N. T.; Jencso, K. G.

    2014-12-01

    Water is commonly the primary limiting factor for tree growth in semi-arid regions of the Western U.S. and tree productivity can vary drastically across landscapes as a function of water availability. The role of topography as a first order control on soil and ground water has been well studied; however, the strategies trees use to cope with water limitation in different landscape positions and across time remain unclear. As growing seasons progress, the availability of water changes temporally, as water inputs transition from snowmelt to rainfall, and spatially, as divergent positions dry more than convergent ones. We seek to understand how the interaction of these processes dictate where trees access water and which strategies most successfully avert water limitation of growth. We take advantage of clear differences in the isotopic signatures of snow and summer rain to track water utilized by Douglas fir, Ponderosa pine, Subalpine fir, Engelmann spruce, and Western larch in both convergent and divergent landscape positions and across time. We couple these data with evidence of growth limitation inferred from reductions in lateral growth rates observed by continuous dendrometer measurements to link tree water use and productivity. Xylem waters reflect both the precipitation type and soil profile distribution of water used by trees for growth and dendrometer measurements reflect the effects of water limitation through changes in the lateral growth curve as soil moistures decline. Isotope signatures from rain, snow and stream water fell predictably along the local meteoric water line with values from xylem samples falling between those of rain and snow. Trees on southern aspects exhibit more growth limitation in divergent than convergent positions while this effect appears muted or non-existent on northern aspects. Trees in convergent hollow positions rely more on snow water while trees on slopes utilize more rain water. Surprisingly, trees at lower elevation rely

  11. Precipitation of ikaite crystals in Antarctic marine sediments: implications from pore water geochemistry

    NASA Astrophysics Data System (ADS)

    Lu, Z.; Kennedy, H.; Rickaby, R. E.; Georg, B.; Shaw, S.; Lennie, A.; Pancost, R. D.

    2008-12-01

    Ikaite is a calcium carbonate hexahydrate (CaCO3•6H20) considered to be stable only at low temperatures. It has been found in form of tufa tower at locations where alkaline water mixes with water masses enriched in calcium (e.g. Ikka Fjord, Mono Lake). Large euhedral single crystals of ikaite were also recovered in marine sediments, associated with organic matter degradation, anaerobic oxidation of methane (AOM) and sulfate reduction. The hydration water in the ikaite crystals were demonstrated to record the oxygen isotope composition of the water from which they precipitated. Such a characteristic may allow using ikaite to reconstruct the ice volume in the past. For this purpose, the controls on its precipitation in the sediment column need to be investigated which is the main goal of this study. U.S. Antarctica Program cruise NBP0703 collected two cores with ikaite crystals at Antarctica Peninsula (Bransfield Strait and Firth of Tay). We determined major cation/anion concentrations, dissolved inorganic carbon (DIC) and δ13C composition of DIC in the pore waters in these two cores. Strong organic matter degradation or AOM in both cores results in quick consumption of sulfate in shallow part of the cores (SMT at around 3m).Rapid build-up of DIC is accompanied by the sharp decrease of dissolved calcium in the top 5m. Large variations were observed in δ13CDIC values (-20‰ to +13‰). The δ13C of ikaite in two cores were distinctive from each other (-19‰ and +4‰) corresponding to the DIC pools at different depths. The down core saturation state of the ikaite was modeled in PHREEQC based on the pore water chemistry, and the results are consistent with carbon isotope data, suggesting that these large crystals very likely formed within a narrow depth interval and a short time period (given high sedimentation rates of 0.5-1 cm/yr in this area).

  12. Are the earthquakes of Central Virginia influenced by underground water fed by precipitation?

    NASA Astrophysics Data System (ADS)

    Muco, B.

    2012-12-01

    Even though Central Virginia is far from the nearest plate boundaries, the zone is well-known for frequent small-to-moderate shocks that have occurred since at least 18th century. People in central Virginia have felt small earthquakes and suffered damage from infrequent larger ones. The largest damaging earthquake (magnitude 5.8) in this seismic zone occurred in August 2011. Smaller earthquakes that cause little or no damage are felt each year or two. It is difficult to link the earthquakes of this zone to known small faults which are numerous, deeply buried and which don't show up at the surface. The mean earthquake depth since 1960 is 6.7 km. On the other hand, Central Virginia is a big collector and transporter of the precipitation water which run for the Atlantic Ocean through James River and its tributaries. There are about 2,000 abandoned mine lands sites in Virginia which with their underground opening can facilitate the interception and conveying of surface water. Looking for a correlation between earthquake time series for Central Virginia and monthly precipitation series for some hydrometeorological stations of the zone, we got that the best cross-correlation is obtained for a time log of three months. This time period approximately three months, has been observed also in the case of some historical earthquakes which have occurred preceded by large amount of precipitation. A good cross-correlations results also matching earthquake time series with levels of James River and Rivanna River. These results support the hydroseismicity hypothesis which suggests the role of water in the generation of intraplate seismicity

  13. Application of pulsed spark discharge for calcium carbonate precipitation in hard water.

    PubMed

    Yang, Yong; Kim, Hyoungsup; Starikovskiy, Andrey; Fridman, Alexander; Cho, Young I

    2010-06-01

    The effect of underwater pulsed spark discharge on the precipitation of dissolved calcium ions was investigated in the present study. Water samples with different calcium hardness were prepared by continuous evaporation of tap water using a laboratory cooling tower. It was shown that the concentration of calcium ions dropped by 20-26% after 10-min plasma treatment, comparing with no drop for untreated cases. A laser particle counting method demonstrated that the total number of solid particles suspended in water increased by over 100% after the plasma treatment. The morphology and the crystal form of the particles were identified by both scanning electron microscopy and X-ray diffraction. Calcite with rhombohedron morphology was observed for plasma treated cases, comparing with the round structure observed for no-treatment cases. It was hypothesized that the main mechanisms for the plasma-assisted calcium carbonate precipitation might include electrolysis, local heating in the vicinity of plasma channel and a high electric field at the tip of plasma streamers, inducing structural changes in the electric double layer of hydrated ions.

  14. Atmospheric water vapor transport: Estimation of continental precipitation recycling and parameterization of a simple climate model. M.S. Thesis

    NASA Technical Reports Server (NTRS)

    Brubaker, Kaye L.; Entekhabi, Dara; Eagleson, Peter S.

    1991-01-01

    The advective transport of atmospheric water vapor and its role in global hydrology and the water balance of continental regions are discussed and explored. The data set consists of ten years of global wind and humidity observations interpolated onto a regular grid by objective analysis. Atmospheric water vapor fluxes across the boundaries of selected continental regions are displayed graphically. The water vapor flux data are used to investigate the sources of continental precipitation. The total amount of water that precipitates on large continental regions is supplied by two mechanisms: (1) advection from surrounding areas external to the region; and (2) evaporation and transpiration from the land surface recycling of precipitation over the continental area. The degree to which regional precipitation is supplied by recycled moisture is a potentially significant climate feedback mechanism and land surface-atmosphere interaction, which may contribute to the persistence and intensification of droughts. A simplified model of the atmospheric moisture over continents and simultaneous estimates of regional precipitation are employed to estimate, for several large continental regions, the fraction of precipitation that is locally derived. In a separate, but related, study estimates of ocean to land water vapor transport are used to parameterize an existing simple climate model, containing both land and ocean surfaces, that is intended to mimic the dynamics of continental climates.

  15. The Alaska Water Isotope Network (AKWIN): Precipitation, lake, river and stream dynamics

    NASA Astrophysics Data System (ADS)

    Rogers, M.; Welker, J. M.; Toohey, R.

    2011-12-01

    The hydrologic cycle is central to the structure and function of northern landscapes. The movement of water creates interactions between terrestrial, aquatic, marine and atmospheric processes. Understanding the processes and the spatial patterns that govern the isotopic (δ18O & δD) characteristics of the hydrologic cycle is especially important today as: a) modern climate/weather-isotope relations allow for more accurate interpretation of climate proxies and the calibration of atmospheric models, b) water isotopes facilitate understanding the role of storm tracks in regulating precipitation isotopic variability, c) water isotopes allow for estimates of glacial melt water inputs into aquatic systems, d) water isotopes allow for quantification of surface and groundwater interactions, e) water isotopes allow for quantification of permafrost meltwater use by plant communities, f) water isotopes aid in migratory bird forensics, g) water isotopes are critical to estimating field metabolic rates, h) water isotopes allow for crop and diet forensics and i) water isotopes can provide insight into evaporation and transpiration processes. As part of a new NSF MRI project at the Environment and Natural Resources Institute (ENRI) at the University of Alaska Anchorage and as an extension of the US Network for Isotopes in Precipitation (USNIP); we are forming AKWIN. The network will utilize long-term weekly sampling at Denali National Park and Caribou Poker Creek Watershed (USNIP sites-1989 to present), regular sampling across Alaska involving land management agencies (USGS, NPS, USFWS, EPA), educators, volunteers and citizen scientists, UA extended campuses, individual research projects, opportunistic sampling and published data to construct isoscapes and time series databases and information packages. We will be using a suite of spatial and temporal analysis methods to characterize water isotopes across Alaska and will provide web portals for data products. Our network is

  16. Fine-Scale Spatial Variability of Precipitation, Soil, and Plant Water Isotopes

    NASA Astrophysics Data System (ADS)

    Goldsmith, G. R.; Braun, S.; Romero, C.; Engbersen, N.; Gessler, A.; Siegwolf, R. T.; Schmid, L.

    2015-12-01

    Introduction: The measurement of stable isotope ratios of water has become fundamental in advancing our understanding of environmental patterns and processes, particularly with respect to understanding the movement of water within the soil-plant-atmosphere continuum. While considerable research has explored the temporal variation in stable isotope ratios of water in the environment, our understanding of the spatial variability of these isotopes remains poorly understood. Methods: We collected spatially explicit samples of throughfall and soil water (n=150 locations) from a 1 ha plot delineated in a mixed deciduous forest in the northern Alps of Switzerland. We complemented this with fully sunlit branch and leaf samples (n = 60 individuals) collected from Picea abies and Fagus sylvatica between 14:00 and 16:00 on the same day by means of a helicopter. Soil and plant waters were extracted using cryogenic vacuum distillation and all samples were analyzed for δ18O using an isotope ratio mass spectrometer. Results: The mean δ18O of throughfall (-3.3 ± 0.8‰) indicated some evaporative enrichment associated with passage through the canopy, but this did not significantly differ from the precipitation collected in nearby open sites (-4.05‰). However, soil was depleted (-7.0 ± 1.8‰) compared to throughfall and there was no significant relationship between the two, suggesting that the sampling for precipitation inputs did not capture all the sources (e.g. stream water, which was -11.5‰) contributing to soil water δ18O ratios. Evaporative enrichment of δ18O was higher in leaves of Fagus (14.8 ± 1.8‰) than in leaves of Picea (11.8 ± 1.7‰). Sampling within crowns of each species (n = 5 branches each from 5 individuals) indicated that variability in a single individual is similar to that among individuals. Discussion: Stable isotopes of water are frequently engaged for studies of ecohydrology, plant ecophysiology, and paleoclimatology. Our results help

  17. Precipitable water vapor budget associated with MJO represented in newly-released JRA-55 reanalysis data

    NASA Astrophysics Data System (ADS)

    Yokoi, S.

    2013-12-01

    The Japan Meteorological Agency (JMA) recently released a new reanalysis dataset JRA-55 with the use of a JMA operational prediction model and 4D-VAR data assimilation. To evaluate merit in utilizing the JRA-55 dataset to investigate dynamics of the tropical intraseasonal variability (ISV) including the Madden-Julian Oscillation (MJO), this study examines ISV-scale precipitable water vapor (PWV) budget over the period 1989-2012. The ISV-scale PWV anomaly related to the boreal-winter MJO propagates eastward along with precipitation, consistent with the SSM/I PWV product. Decomposition of the PWV tendency into that simulated by the model and the analysis increment estimated by the data assimilation reveals that the model makes the PWV anomaly move eastward. On the other hand, the analysis increment exhibits positive values over the area where the PWV anomaly is positive, indicating that the model tends to damp the MJO signal. Note that the analysis increment over the Maritime Continent has comparable magnitude to the model tendency. The positive analysis increment may mainly be caused by an excess of precipitation anomaly with respect to the magnitude of PWV anomaly. In addition to the boreal-winter MJO, this study also examines the PWV budget associated with northward-propagating ISV during the boreal summer and find similar relationship between the PWV anomaly and analysis increment.

  18. Precipitation projections under GCMs perspective and Turkish Water Foundation (TWF) statistical downscaling model procedures

    NASA Astrophysics Data System (ADS)

    Dabanlı, İsmail; Şen, Zekai

    2017-02-01

    The statistical climate downscaling model by the Turkish Water Foundation (TWF) is further developed and applied to a set of monthly precipitation records. The model is structured by two phases as spatial (regional) and temporal downscaling of global circulation model (GCM) scenarios. The TWF model takes into consideration the regional dependence function (RDF) for spatial structure and Markov whitening process (MWP) for temporal characteristics of the records to set projections. The impact of climate change on monthly precipitations is studied by downscaling Intergovernmental Panel on Climate Change-Special Report on Emission Scenarios (IPCC-SRES) A2 and B2 emission scenarios from Max Plank Institute (EH40PYC) and Hadley Center (HadCM3). The main purposes are to explain the TWF statistical climate downscaling model procedures and to expose the validation tests, which are rewarded in same specifications as "very good" for all stations except one (Suhut) station in the Akarcay basin that is in the west central part of Turkey. Eventhough, the validation score is just a bit lower at the Suhut station, the results are "satisfactory." It is, therefore, possible to say that the TWF model has reasonably acceptable skill for highly accurate estimation regarding standard deviation ratio (SDR), Nash-Sutcliffe efficiency (NSE), and percent bias (PBIAS) criteria. Based on the validated model, precipitation predictions are generated from 2011 to 2100 by using 30-year reference observation period (1981-2010). Precipitation arithmetic average and standard deviation have less than 5% error for EH40PYC and HadCM3 SRES (A2 and B2) scenarios.

  19. Inter-comparison of precipitable water among reanalyses and its effect on downscaling in the tropics

    NASA Astrophysics Data System (ADS)

    Takahashi, H. G.; Fujita, M.; Hara, M.

    2012-12-01

    This paper compared precipitable water (PW) among four major reanalyses. In addition, we also investigated the effect of the boundary conditions on downscaling in the tropics, using a regional climate model. The spatial pattern of PW in the reanalyses agreed closely with observations. However, the absolute amounts of PW in some reanalyses were very small compared to observations. The discrepancies of the 12-year mean PW in July over the Southeast Asian monsoon region exceeded the inter-annual standard deviation of the PW. There was also a discrepancy in tropical PWs throughout the year, an indication that the problem is not regional, but global. The downscaling experiments were conducted, which were forced by the different four reanalyses. The atmospheric circulation, including monsoon westerlies and various disturbances, was very small among the reanalyses. However, simulated precipitation was only 60 % of observed precipitation, although the dry bias in the boundary conditions was only 6 %. This result indicates that dry bias has large effects on precipitation in downscaling over the tropics. This suggests that a simulated regional climate downscaled from ensemble-mean boundary conditions is quite different from an ensemble-mean regional climate averaged over the several regional ones downscaled from boundary conditions of the ensemble members in the tropics. Downscaled models can provide realistic simulations of regional tropical climates only if the boundary conditions include realistic absolute amounts of PW. Use of boundary conditions that include realistic absolute amounts of PW in downscaling in the tropics is imperative at the present time. This work was partly supported by the Global Environment Research Fund (RFa-1101) of the Ministry of the Environment, Japan.

  20. Polyfluorinated telomers in precipitation and surface water in an urban area of Japan.

    PubMed

    Mahmoud, Manal A M; Kärrman, Anna; Oono, Sayoko; Harada, Kouji H; Koizumi, Akio

    2009-01-01

    Although fluorotelomer alcohols (FTOHs) have been detected in various environmental matrices worldwide, no studies have been conducted to evaluate their concentrations in surface water or precipitation. Therefore, we developed a sensitive and reliable method to analyze various environmental aqueous samples for the presence of trace levels of 6:2 FTOH, 8:2 FTOH, 10:2 FTOH, 8:2 FTOAcr and 8:2 FTOMethacr FTOlefin using gas-chromatography/mass-spectrometry. The recoveries obtained using this method ranged from 57.8% to 78.2% and the detection limits were 0.5, 0.2, 0.2, 0.05 and 0.1 ng L(-1) for 6:2 FTOH, 8:2 FTOH, 10:2 FTOH, 8:2 FTOAcr and 8:2 FTOMethacr, respectively. Liquid and suspended phases of the examined samples were analyzed. The analysis revealed presence of telomer alcohols from the liquid phase only. Of the FTOHs evaluated, 6:2 FTOH and 8:2 FTOMethacr FTOlefin were not found in any of the environmental samples. The average concentrations of 8:2 FTOH, 10:2 FTOH and 8:2 FTOAcr of the precipitation samples were 1.97, 0.82 and 0.21 ng L(-1), respectively. In surface water samples, the highest concentrations of 8:2 FTOH, 10:2 FTOH and 8:2 FTOAcr were 3.38, 4.06 and 0.16 ng L(-1), which were observed in samples from the Daini-Neyagawa, Yamato and Kanzaki rivers, respectively. The total concentration of FTOHs in wastewater treatment plant effluents (23.2 ng L(-1)) was much higher than that of surface water (10.8 ng L(-1)). Taken together, the results of this study indicate that FTOHs released into the air contaminate rain and that those released from water disposal sites contaminate surface water.

  1. Inter-annual precipitation fluctuations alter the responses of above- and belowground biomass to water and N enrichment

    NASA Astrophysics Data System (ADS)

    Kong, D. L.; Lü, X. T.; Jiang, L. L.; Wu, H. F.; Miao, Y.; Kardol, P.

    2013-08-01

    Water availability has profound effects on plant growth and productivity in temperate and semi-arid grasslands. However, it remains unclear how variation of inter-annual precipitation by extreme rainfall events will alter the aboveground and belowground responses of plants, and how these responses may be contingent on N availability. In this study, we examined the interactive effects of inter-annual precipitation variation and N addition on aboveground and live fine root biomass of a semi-arid grassland in northern China for two consecutive years (2007 and 2008). Inter-annual variation in precipitation resulting mainly from the occurrence of extreme rainfall events in 2008 significantly affected above- and belowground plant biomass responses to water addition. In addition, variation of inter-annual precipitation by this extreme rainfall event suppressed plant responses to nitrogen addition and reduced the interaction effects between water and nitrogen addition. These effects of inter-annual precipitation fluctuation could be attributed to the negative influence of the extreme rainfall event on soil N and water availability, ultimately reducing plant rainfall use efficiency and nitrogen use efficiency. In conclusion, our results suggest ecosystem responses to water and N enrichment could be altered by inter-annual variation of precipitation regime caused by the naturally occurring extreme rainfall events.

  2. The Precipitation Behavior of Poorly Water-Soluble Drugs with an Emphasis on the Digestion of Lipid Based Formulations.

    PubMed

    Khan, Jamal; Rades, Thomas; Boyd, Ben

    2016-03-01

    An increasing number of newly discovered drugs are poorly water-soluble and the use of natural and synthetic lipids to improve the oral bioavailability of these drugs by utilizing the digestion pathway in-vivo has proved an effective formulation strategy. The mechanisms responsible for lipid digestion and drug solubilisation during gastrointestinal transit have been explored in detail, but the implications of drug precipitation beyond the potential adverse effect on bioavailability have received attention only in recent years. Specifically, these implications are that different solid forms of drug on precipitation may affect the total amount of drug absorbed in-vivo through their different physico-chemical properties, and the possibility that the dynamic environment of the small intestine may afford re-dissolution of precipitated drug if present in a high-energy form. This review describes the events that lead to drug precipitation during the dispersion and digestion of lipid based formulations, common methods used to inhibit precipitation, as well as conventional and newly emerging characterization techniques for studying the solid state form of the precipitated drug. Moreover, selected case studies are discussed where drug precipitation has ensued from the digestion of lipid based formulations, as well as the apparent link between drug ionisability and altered solid forms on precipitation, culminating in a discussion about the importance of the solid form on precipitation with relevance to the total drug absorbed.

  3. Simulation of Water Sources and Precipitation Recycling for the MacKenzie, Mississippi and Amazon River Basins

    NASA Technical Reports Server (NTRS)

    Bosilovich, Michael G.; Chern, Jiun-Dar

    2005-01-01

    An atmospheric general circulation model simulation for 1948-1997 of the water budgets for the MacKenzie, Mississippi and Amazon River basins is presented. In addition to the water budget, we include passive tracers to identify the geographic sources of water for the basins, and the analysis focuses on the mechanisms contributing to precipitation recycling in each basin. While each basin s precipitation recycling has a strong dependency on evaporation during the mean annual cycle, the interannual variability of the recycling shows important relationships with the atmospheric circulation. The MacKenzie River basin has only a weak interannual dependency on evaporation, where the variations in zonal moisture transport from the Pacific Ocean can affect the basin water cycle. On the other hand, the Mississippi River basin has strong interannual dependencies on evaporation. While the precipitation recycling weakens with increased low level jet intensity, the evaporation variations exert stronger influence in providing water vapor for convective precipitation at the convective cloud base. High precipitation recycling is also found to be partly connected to warm SSTs in the tropical Pacific Ocean. The Amazon River basin evaporation exhibits small interannual variations, so that the interannual variations of precipitation recycling are related to atmospheric moisture transport from the tropical south Atlantic Ocean. Increasing SSTs over the 50-year period are causing increased easterly transport across the basin. As moisture transport increases, the Amazon precipitation recycling decreases (without real time varying vegetation changes). In addition, precipitation recycling from a bulk diagnostic method is compared to the passive tracer method used in the analysis. While the mean values are different, the interannual variations are comparable between each method. The methods also exhibit similar relationships to the terms of the basin scale water budgets.

  4. The role of precipitation type, intensity, and spatial distribution in source water quality after wildfire

    NASA Astrophysics Data System (ADS)

    Murphy, Sheila F.; Writer, Jeffrey H.; Blaine McCleskey, R.; Martin, Deborah A.

    2015-08-01

    Storms following wildfires are known to impair drinking water supplies in the southwestern United States, yet our understanding of the role of precipitation in post-wildfire water quality is far from complete. We quantitatively assessed water-quality impacts of different hydrologic events in the Colorado Front Range and found that for a three-year period, substantial hydrologic and geochemical responses downstream of a burned area were primarily driven by convective storms with a 30 min rainfall intensity >10 mm h-1. These storms, which typically occur several times each year in July-September, are often small in area, short-lived, and highly variable in intensity and geographic distribution. Thus, a rain gage network with high temporal resolution and spatial density, together with high-resolution stream sampling, are required to adequately characterize post-wildfire responses. We measured total suspended sediment, dissolved organic carbon (DOC), nitrate, and manganese concentrations that were 10-156 times higher downstream of a burned area compared to upstream during relatively common (50% annual exceedance probability) rainstorms, and water quality was sufficiently impaired to pose water-treatment concerns. Short-term water-quality impairment was driven primarily by increased surface runoff during higher intensity convective storms that caused erosion in the burned area and transport of sediment and chemical constituents to streams. Annual sediment yields downstream of the burned area were controlled by storm events and subsequent remobilization, whereas DOC yields were closely linked to annual runoff and thus were more dependent on interannual variation in spring runoff. Nitrate yields were highest in the third year post-wildfire. Results from this study quantitatively demonstrate that water quality can be altered for several years after wildfire. Because the southwestern US is prone to wildfires and high-intensity rain storms, the role of storms in post

  5. The role of precipitation type, intensity, and spatial distribution in source water quality after wildfire

    USGS Publications Warehouse

    Murphy, Sheila F.; Writer, Jeffrey H.; McCleskey, R. Blaine; Martin, Deborah A.

    2015-01-01

    Storms following wildfires are known to impair drinking water supplies in the southwestern United States, yet our understanding of the role of precipitation in post-wildfire water quality is far from complete. We quantitatively assessed water-quality impacts of different hydrologic events in the Colorado Front Range and found that for a three-year period, substantial hydrologic and geochemical responses downstream of a burned area were primarily driven by convective storms with a 30 min rainfall intensity >10 mm h−1. These storms, which typically occur several times each year in July–September, are often small in area, short-lived, and highly variable in intensity and geographic distribution. Thus, a rain gage network with high temporal resolution and spatial density, together with high-resolution stream sampling, are required to adequately characterize post-wildfire responses. We measured total suspended sediment, dissolved organic carbon (DOC), nitrate, and manganese concentrations that were 10–156 times higher downstream of a burned area compared to upstream during relatively common (50% annual exceedance probability) rainstorms, and water quality was sufficiently impaired to pose water-treatment concerns. Short-term water-quality impairment was driven primarily by increased surface runoff during higher intensity convective storms that caused erosion in the burned area and transport of sediment and chemical constituents to streams. Annual sediment yields downstream of the burned area were controlled by storm events and subsequent remobilization, whereas DOC yields were closely linked to annual runoff and thus were more dependent on interannual variation in spring runoff. Nitrate yields were highest in the third year post-wildfire. Results from this study quantitatively demonstrate that water quality can be altered for several years after wildfire. Because the southwestern US is prone to wildfires and high-intensity rain storms, the role of storms in post

  6. Precipitable water: Its linear retrieval using leaps and bounds procedure and its global distribution from SEASAT SMMR data

    NASA Technical Reports Server (NTRS)

    Pandey, P. C.

    1982-01-01

    Eight subsets using two to five frequencies of the SEASAT scanning multichannel microwave radiometer are examined to determine their potential in the retrieval of atmospheric water vapor content. Analysis indicates that the information concerning the 18 and 21 GHz channels are optimum for water vapor retrieval. A comparison with radiosonde observations gave an rms accuracy of approximately 0.40 g sq cm. The rms accuracy of precipitable water using different subsets was within 10 percent. Global maps of precipitable water over oceans using two and five channel retrieval (average of two and five channel retrieval) are given. Study of these maps reveals the possibility of global moisture distribution associated with oceanic currents and large scale general circulation in the atmosphere. A stable feature of the large scale circulation is noticed. The precipitable water is maximum over the Bay of Bengal and in the North Pacific over the Kuroshio current and shows a general latitudinal pattern.

  7. Statistical relation between monthly mean precipitable water and surface-level humidity over global oceans

    NASA Technical Reports Server (NTRS)

    Liu, W. T.

    1986-01-01

    Monthly summaries of atmospheric soundings taken over 17 years from 49 midocean stations at small islands and weather ships distributed over major oceans are examined. Over tropical oceans, precipitable water is found to be a better predictor of surface-level humidity than surface-level air temperature. A statistical relation in the form of a polynomial is derived; from this relation, the monthly-mean, surface-level mixing ratio can be computed from monthly-mean precipitable water. The root-mean-square differences between the measured and derived values were found to be less than 8 x 10 to the -4th over most ocean areas. Such a relation is useful in deriving large-scale evaporation and latent heat flux data from the ocean, using spaceborne observations. The temporal and spatial variabilities of data deviations from this relation are examined. This relation is found to be applicable to all major ocean basins and can be used to monitor interannual variability. Boundary-layer thermodynamics of different air masses are suggested as an explanation of some characteristics of this relation.

  8. Attribution of the United States "warming hole": aerosol indirect effect and precipitable water vapor.

    PubMed

    Yu, Shaocai; Alapaty, Kiran; Mathur, Rohit; Pleim, Jonathan; Zhang, Yuanhang; Nolte, Chris; Eder, Brian; Foley, Kristen; Nagashima, Tatsuya

    2014-11-06

    Aerosols can influence the climate indirectly by acting as cloud condensation nuclei and/or ice nuclei, thereby modifying cloud optical properties. In contrast to the widespread global warming, the central and south central United States display a noteworthy overall cooling trend during the 20(th) century, with an especially striking cooling trend in summertime daily maximum temperature (Tmax) (termed the U.S. "warming hole"). Here we used observations of temperature, shortwave cloud forcing (SWCF), longwave cloud forcing (LWCF), aerosol optical depth and precipitable water vapor as well as global coupled climate models to explore the attribution of the "warming hole". We find that the observed cooling trend in summer Tmax can be attributed mainly to SWCF due to aerosols with offset from the greenhouse effect of precipitable water vapor. A global coupled climate model reveals that the observed "warming hole" can be produced only when the aerosol fields are simulated with a reasonable degree of accuracy as this is necessary for accurate simulation of SWCF over the region. These results provide compelling evidence of the role of the aerosol indirect effect in cooling regional climate on the Earth. Our results reaffirm that LWCF can warm both winter Tmax and Tmin.

  9. Attribution of the United States “warming hole”: Aerosol indirect effect and precipitable water vapor

    PubMed Central

    Yu, Shaocai; Alapaty, Kiran; Mathur, Rohit; Pleim, Jonathan; Zhang, Yuanhang; Nolte, Chris; Eder, Brian; Foley, Kristen; Nagashima, Tatsuya

    2014-01-01

    Aerosols can influence the climate indirectly by acting as cloud condensation nuclei and/or ice nuclei, thereby modifying cloud optical properties. In contrast to the widespread global warming, the central and south central United States display a noteworthy overall cooling trend during the 20th century, with an especially striking cooling trend in summertime daily maximum temperature (Tmax) (termed the U.S. “warming hole”). Here we used observations of temperature, shortwave cloud forcing (SWCF), longwave cloud forcing (LWCF), aerosol optical depth and precipitable water vapor as well as global coupled climate models to explore the attribution of the “warming hole”. We find that the observed cooling trend in summer Tmax can be attributed mainly to SWCF due to aerosols with offset from the greenhouse effect of precipitable water vapor. A global coupled climate model reveals that the observed “warming hole” can be produced only when the aerosol fields are simulated with a reasonable degree of accuracy as this is necessary for accurate simulation of SWCF over the region. These results provide compelling evidence of the role of the aerosol indirect effect in cooling regional climate on the Earth. Our results reaffirm that LWCF can warm both winter Tmax and Tmin. PMID:25373416

  10. Evaluation of AERONET precipitable water vapor versus microwave radiometry, GPS, and radiosondes at ARM sites

    NASA Astrophysics Data System (ADS)

    Pérez-Ramírez, Daniel; Whiteman, David N.; Smirnov, Alexander; Lyamani, Hassan; Holben, Brent N.; Pinker, Rachel; Andrade, Marcos; Alados-Arboledas, Lucas

    2014-08-01

    In this paper we present comparisons of Aerosol Robotic Network (AERONET) precipitable water vapor (W) retrievals from Sun photometers versus radiosonde observations and other ground-based retrieval techniques such as microwave radiometry (MWR) and GPS. The comparisons make use of the extensive measurements made within the U.S. Department of Energy Atmospheric Radiation Measurement Program (ARM), mainly at their permanent sites located at the Southern Great Plains (Oklahoma, U.S.), Nauru Islands, and Barrow (Alaska, U.S.). These places experience different types of weather which allows the comparison of W under different conditions. Radiosonde and microwave radiometry data were provided by the ARM program while the GPS data were obtained from the SOUMINET network. In general, W obtained by AERONET is lower than those obtained by MWR and GPS by ~6.0-9.0% and ~6.0-8.0%, respectively. The AERONET values are also lower by approximately 5% than those obtained from the numerous balloon-borne radiosondes launched at the Southern Great Plains. These results point toward a consistent dry bias in the retrievals of W by AERONET of approximately 5-6% and a total estimated uncertainty of 12-15%. Differences with respect to MWR retrievals are a function of solar zenith angle pointing toward a possible bias in the MWR retrievals. Finally, the ability of AERONET precipitable water vapor retrievals to provide long-term records of W in diverse climate regimes is demonstrated.

  11. Physicochemical characteristics of drip waters: Influence on mineralogy and crystal morphology of recent cave carbonate precipitates

    NASA Astrophysics Data System (ADS)

    Riechelmann, Sylvia; Schröder-Ritzrau, Andrea; Wassenburg, Jasper A.; Schreuer, Jürgen; Richter, Detlev K.; Riechelmann, Dana F. C.; Terente, Mihai; Constantin, Silviu; Mangini, Augusto; Immenhauser, Adrian

    2014-11-01

    Speleothems are one of the most intensively explored continental archives for palaeoclimate variability. The parameters, however, that control speleothem petrography and its changes with time and space, specifically calcite crystal morphology and carbonate mineralogy, are still poorly understood. In order to shed light on processes and their products, precipitation experiments of recent carbonate crystals on watch glasses and glass plates were performed in seven selected caves. Drip water sites were analysed for their fluid Mg/Ca molar ratio, pH, degree of saturation for calcite and aragonite and drip rates. Corresponding precipitates were analysed with respect to their mineralogy, calcite crystal morphology and Mg/Ca molar ratio of calcite. The following results are found: High fluid Mg/Ca ratios are found only for caves situated in dolostone, thus the hostrock lithology indirectly controls the carbonate mineralogy and calcite crystal morphology of speleothems. The precipitation of aragonite in place of calcite occurred only in dolostone caves and is bound to very specific conditions. These are: high fluid Mg/Ca ratios (⩾0.5), high fluid pH (>8.2) and low fluid saturation indices for calcite (<0.8). These specific conditions are induced by slow drip rates of <0.2 ml/min as often under more arid conditions, causing the precipitation of calcite/aragonite prior to reaching the stalagmite top. Due to this, fluid chemistry is altered, which in turn leads to changes in carbonate mineralogy and geochemistry on the stalagmite top. Calcite growth is inhibited at high fluid Mg/Ca ratios and hence, aragonite precipitation is kinetically stabilised. An increase of the drip water Mg/Ca ratio leads to an increased incorporation of Mg2+ into the calcite crystal lattice and thus, to a change in calcite crystal morphology. Four distinctive changes occur with increasing Mg2+ incorporation: (i) development of new forms (steeper rhombohedra and base pinacoid) at the edges and

  12. The Synthesis of Calcium Salt from Brine Water by Partial Evaporation and Chemical Precipitation

    NASA Astrophysics Data System (ADS)

    Lalasari, L. H.; Widowati, M. K.; Natasha, N. C.; Sulistiyono, E.; Prasetyo, A. B.

    2017-02-01

    In this study would be investigated the effects of partial evaporation and chemical precipitation in the formation of calcium salt from brine water resources. The chemical reagents used in the study was oxalate acid (C2H2O4), ammonium carbonate (NH4)2CO3) and ammonium hydroxide (NH4OH) with reagent concentration of 2 N, respectively. The procedure was 10 liters brine water evaporated until 20% volume and continued with filtration process to separate brine water filtrate from residue (salt). Salt resulted from evaporation process was characterized by Scanning Electron Microscopy (SEM), X-Ray Fluorescence (XRF) and X-Ray Diffraction (XRD) techniques. Filtrate then was reacted with C2H2O4, (NH4)2CO3 and NH4OH reagents to get salt products in atmospheric condition and variation ratio volume brine water/chemicals (v/v) [10/1; 10/5; 10/10; 10/20; 10/30; 10:50; 20/1; 20/5; 20/10; 20/20; 20/30; 20:50]. The salt product than were filtered, dried, measured weights and finally characterized by SEM/EDS and XRD techniques. The result of experiment showed the chemical composition of brine water from Tirta Sanita, Bogor was 28.87% Na, 9.17% Mg, 2.94% Ca, 22.33% O, 0.71% Sr, 30.02% Cl, 1.51% Si, 1.23% K, 0.55% S, 1.31% Al. The chemical composition of salt resulted by partial evaporation was 53.02% Ca, 28.93%O, 9.50% Na, 2.10% Mg, 1.53% Sr, 1.20% Cl, 1.10% Si, 0.63% K, 0.40% S, 0.39% Al. The salt resulted by total evaporation was indicated namely as NaCl. Whereas salt resulted by partial evaporation was CaCO3 with a purity of 90 % from High Score Plus analysis. In the experiment by chemical precipitation was reported that the reagents of ammonium carbonate were more reactive for synthesizing calcium salt from brine water compared to reagents of oxalate acid and ammonium hydroxide. The salts precipitated by NH4OH, (NH4)2CO3, and H2C2O4 reagents were indicated as NaCl, CaCO3 and CaC2O4.H2O, respectively. The techniques of partial evaporation until 20% volume sample of brine water and

  13. Desalination of brackish ground waters and produced waters using in-situ precipitation.

    SciTech Connect

    Krumhansl, James Lee; Pless, Jason; Nenoff, Tina Maria; Voigt, James A.; Phillips, Mark L. F.; Axness, Marlene; Moore, Diana Lynn; Sattler, Allan Richard

    2004-08-01

    The need for fresh water has increased exponentially during the last several decades due to the continuous growth of human population and industrial and agricultural activities. Yet existing resources are limited often because of their high salinity. This unfavorable situation requires the development of new, long-term strategies and alternative technologies for desalination of saline waters presently not being used to supply the population growth occurring in arid regions. We have developed a novel environmentally friendly method for desalinating inland brackish waters. This process can be applied to either brackish ground water or produced waters (i.e., coal-bed methane or oil and gas produced waters). Using a set of ion exchange and sorption materials, our process effectively removes anions and cations in separate steps. The ion exchange materials were chosen because of their specific selectivity for ions of interest, and for their ability to work in the temperature and pH regions necessary for cost and energy effectiveness. For anion exchange, we have focused on hydrotalcite (HTC), a layered hydroxide similar to clay in structure. For cation exchange, we have developed an amorphous silica material that has enhanced cation (in particular Na{sup +}) selectivity. In the case of produced waters with high concentrations of Ca{sup 2+}, a lime softening step is included.

  14. Application of the Precipitation Runoff Modeling System to evaluate water budgets after forest fuel management

    NASA Astrophysics Data System (ADS)

    Anderson, A. M.; Micheletty, P. D.; Kinoshita, A. M.; Hogue, T. S.

    2014-12-01

    The Sagehen Experimental Forest is being used as a prototype for forest fuel management to mitigate severe wildfires and improve ecosystem function and habitat. Sagehen is located at the headwaters of Sagehen Creek and contributes to the Truckee River, which is the main water supply for Reno, Nevada. Sagehen is a snow-dominated basin that receives an average annual rainfall of 892 mm and streamflow of 392 mm. A standardized precipitation index (SPI) indicates eight wet years and three dry years occurred since 1978. The Precipitation Runoff Modeling System (PRMS) is utilized to run scenarios of fuel treatments and to analyze corresponding water budget changes in Sagehen. PRMS is calibrated to observed streamflow using the systematic multi-objective, step-wise calibration software Let Us Calibrate (LUCA). The basin is divided into 128 hydrologic response units (HRUs) based on similar hydrologic and physical characteristics. Fuel management will include multiple thinning and burning treatments based on topography and ecosystem characteristics and coincides with approximately 41 percent of the defined HRUs. Three treatment scenarios were run for relevant HRUs for water years 1981-2000. Scenarios reflect a 25, 50, and 75 percent vegetation reduction by altering sensitive parameters such as summer and winter cover density, summer and winter rain-interception storage capacity, and snow-interception storage capacity. Preliminary analysis shows changes in the water budget exemplified by simulated streamflow compared to baseline simulations. Ongoing work includes investigating PRMS outputs such as evapotranspiration, snow, and recharge to fully understand the scope of proposed fuel management in Sagehen. Individual assessment of impacted HRUs will also provide insight on specific treatment types and ultimately provide insight for future regional treatments in the Sierra Nevada.

  15. Trend Analysis of GPS Precipitable Water Vapor Above South Korea Over the Last 10 Years

    NASA Astrophysics Data System (ADS)

    Sohn, Dong-Hyo; Cho, Jungho

    2010-09-01

    We analyzed global positioning system (GPS)-derived precipitable water vapor (PWV) trends of the Korea Astronomy and Space Science Institute 5 stations (Seoul, Daejeon, Mokpo, Milyang, Sokcho) where Korea Meteorological Administration meteorological data can be obtained at the same place. In the least squares analysis, the GPS PWV time series showed consistent positive trends (0.11 mm/year) over South Korea from 2000 to 2009. The annual increase of GPS PWV was comparable with the 0.17 mm/year and 0.02 mm/year from the National Center for Atmospheric Research Earth Observing Laboratory and Atmospheric InfraRed Sounder, respectively. For seasonal analysis, the increasing tendency was found by 0.05 mm/year, 0.16 mm/year, 0.04 mm/year in spring (March-May), summer (June-August) and winter (December-February), respectively. However, a negative trend (-0.14 mm/year) was seen in autumn (September-November). We examined the relationship between GPS PWV and temperature which is the one of the climatic elements. Two elements trends increased during the same period and the correlation coefficient was about 0.8. Also, we found the temperature rise has increased more GPS PWV and observed a stronger positive trend in summer than in winter. This is characterized by hot humid summer and cold dry winter of Korea climate and depending on the amount of water vapor the air contains at a certain temperature. In addition, it is assumed that GPS PWV positive trend is caused by increasing amount of saturated water vapor due to temperature rise in the Korean Peninsula. In the future, we plan to verify GPS PWV effectiveness as a tool to monitor changes in precipitable water through cause analysis of seasonal trends and indepth/ long-term comparative analysis between GPS PWV and other climatic elements.

  16. Enhancements to the Precipitation-Runoff Modeling System for simulating in-stream water temperature

    NASA Astrophysics Data System (ADS)

    Markstrom, S. L.; Hay, L.

    2010-12-01

    A stream temperature module has been developed for the U.S. Geological Survey Precipitation-Runoff Modeling System (PRMS) for simulating maximum- and mean-daily stream temperature. This module provides additional simulation capabilities by coupling PRMS with the U.S. Geological Survey Stream Network Temperature (SNTEMP) model. PRMS is a modular, deterministic, distributed-parameter, physical-process watershed model that simulates watershed response to various combinations of climate and land use. Normal and extreme rainfall and snowmelt can be simulated to evaluate changes in water-balance relations, streamflow regimes, soil-water relations, and ground-water recharge. SNTEMP was developed to help aquatic biologists and engineers predict the effects of flow regime changes on water temperatures. This coupling of PRMS with SNTEMP will allow scientists and watershed managers to evaluate the effects of historical climate and projected climate change, landscape evolution, and resource management scenarios on watershed hydrology and in-stream water temperature. The prototype of this coupled model was developed for the U.S. Geological Survey Southeast Regional Assessment Project (SERAP) and tested in the Apalachicola-Chattahoochee-Flint River Basin in the southeastern United States. Preliminary results from the prototype are presented.

  17. ECMWF Extreme Forecast Index for water vapor transport: A forecast tool for atmospheric rivers and extreme precipitation

    NASA Astrophysics Data System (ADS)

    Lavers, David A.; Pappenberger, Florian; Richardson, David S.; Zsoter, Ervin

    2016-11-01

    In winter, heavy precipitation and floods along the west coasts of midlatitude continents are largely caused by intense water vapor transport (integrated vapor transport (IVT)) within the atmospheric river of extratropical cyclones. This study builds on previous findings that showed that forecasts of IVT have higher predictability than precipitation, by applying and evaluating the European Centre for Medium-Range Weather Forecasts Extreme Forecast Index (EFI) for IVT in ensemble forecasts during three winters across Europe. We show that the IVT EFI is more able (than the precipitation EFI) to capture extreme precipitation in forecast week 2 during forecasts initialized in a positive North Atlantic Oscillation (NAO) phase; conversely, the precipitation EFI is better during the negative NAO phase and at shorter leads. An IVT EFI example for storm Desmond in December 2015 highlights its potential to identify upcoming hydrometeorological extremes, which may prove useful to the user and forecasting communities.

  18. Precipitation variability in High Mountain Asia from multiple datasets and implication for water balance analysis in large lake basins

    NASA Astrophysics Data System (ADS)

    Song, Chunqiao; Huang, Bo; Ke, Linghong; Ye, Qinghua

    2016-10-01

    For the period 1979-2011, eight gridded monthly precipitation datasets, including GPCP, CMAP-1/2, TRMM, PREC/L, APHRODITE, NCEP-2 and ERA-Interim, are inter-compared with each other and station observations over High Mountain Asia (HMA). The precipitation variability from the first six gauge-based or merged analysis datasets agree better with each other than with the two reanalysis data. The long-term trend analysis of GPCP, CMAP-1, PREC/L and APHRODITE precipitation datasets consistently reveals moderate increases in the inner and northeastern Tibetan Plateau (TP) and northwest Xinjiang, and obvious decreases in the southeast TP. However, in the Himalayas and Karakorum, there are large discrepancies among different datasets, where GPCP and APHRODITE precipitation datasets show significant decreases along the Himalayas while other datasets show strong spatial heterogeneity or slight variations. The larger uncertainties in the rugged area may be largely attributed to scarce station observations, as well as the stronger snow-induced scattering by microwave measurement. To assess which precipitation datasets tend to be more suitable for hydrologic analysis in HMA, we further investigate the accuracy of precipitation estimates at basin scale by comparing with gauge-based observations, and examine the coherences of annual lake water budgets and precipitation variability over four large closed lake catchments. The results indicate that two reanalysis precipitation datasets show evidently weaker correlations with station observations; the other six datasets perform better in indicating inter-annual variations of lake water budgets. It suggests that these merged analysis precipitation datasets, especially for GPCP, CMAP-1/2 and PREC/L, have the potential in examining regional water balances of the inner basins in HMA.

  19. Global analyses of water vapor, cloud and precipitation derived from a diagnostic assimilation of SSM/I geophysical retrievals

    NASA Technical Reports Server (NTRS)

    Robertson, Franklin R.; Cohen, Charles

    1990-01-01

    An analytical approach is described for diagnostically assimilating moisture data from Special Sensor Microwave Imager (SSM/I) into a global analysis of water vapor, cloud content, and precipitation. In this method, 3D fields of wind and temperature values taken from ECMWF gridded analysis are used to drive moisture conservation equations with parameterized microphysical treatment of vapor, liquid, and ice; the evolving field of water vapor is periodically updated or constrained by SSM/I retrievals of precipitable water. Initial results indicate that this diagnostic model can produce realistic large-scale fields of cloud and precipitation. The resulting water vapor analyses agree well with SSM/I and have an additional advantage of being synoptic.

  20. [Impact of precipitation and underground water level in the edge of oases on growth and decline of Nitraria tangugtorum community].

    PubMed

    Yang, Z; Gao, Z

    2000-12-01

    Based on the data from underground water monitoring, meterological measuring and fixed sample square investigating in successive years at the edge of the oasis in Minqin, Gansu, the impact of precipitation and underground water on the growth and decline of Nitraria tangutorum community was studied. The result showed that the desiccated environment in oases driven by the decline of underground water level was favorable for the growth and develoment of N. tangutorum community, and made this species more xerophilous. This declining underground water level was not a limiting factor for N. tangutorum growth in late years. These N. tangutorum-dominated communities were predicted to survive comparatively longer, and to function as sand fixer and wind breaker at oasis edge in Minqin. When average annual precipitation was about 110 mm, N. tangutorum would maintain its normal growth, but the community couldn't spread freely. Only when the annual precipitation was up 140 mm in two years running, could its growth be improved.

  1. GPS sensing of precipitable water vapour during the March 2010 Melbourne storm

    NASA Astrophysics Data System (ADS)

    Choy, S.; Wang, C.; Zhang, K.; Kuleshov, Y.

    2013-11-01

    The March 2010 Melbourne storm is used as a case study to examine the potential of using Global Positioning System (GPS) observations for studying the precipitable water vapour (PWV) field. The Victorian statewide GPS infrastructure network, i.e. GPSnet, was used in this study. GPSnet is currently the only statewide and densest GPS infrastructure network in Australia, which provides an excellent opportunity to examine the distribution of water vapour as the severe weather system passed over the state. Data from 15 GPSnet stations were processed over a one-week period, i.e. a few days prior to and after the storm passage, during which the course of the storm extended from the west to the southeast corner of the state. In addition, data from two radiosonde sites of the Australian Bureau of Meteorology Upper Air Network were used to compare and validate the GPS derived PWV measurements. The findings demonstrate that there is strong spatial and temporal correlation between variations of the ground-based GPS-PWV estimates and the passage of the storm over the state. This is encouraging as the ground-based GPS water vapour sensing technique can be considered as a supplemental meteorological sensor in studying severe weather events. The advantage of using ground-based GPS-PWV technique is that it is capable of providing continuous observation of the storm passage with high temporal resolution. The spatial resolution of the distribution of water vapour is dependent on the geographical location and density of the GPS stations.

  2. Comparison of precipitable water observations in the near tropics by GPS, microwave radiometer and radiosondes.

    SciTech Connect

    Liou, Y. A.; Teng, Y. T.; VanHove, T.; Liljegren, J. C.; Environmental Research; National Central Univ.; UCAR

    2001-01-01

    The sensing of precipitable water (PW) using the Global Positioning System (GPS) in the near Tropics is investigated. GPS data acquired from the Central Weather Bureau's Taipei weather station in Banchao (Taipei), Taiwan, and each of nine International GPS Service (IGS) stations were utilized to determine independently the PW at the Taipei site from 18 to 24 March 1998. Baselines between Taipei and the other nine stations range from 676 to 3009 km. The PW determined from GPS observations for the nine baseline cases are compared with measurements by a dual-channel water vapor radiometer (WVR) and radiosondes at the Taipei site. Although previous results from other locations show that the variability in the rms difference between GPS- and WVR-observed PW ranges from 1 to 2 mm, a variability of 2.2 mm is found. The increase is consistent with scaling of the variability with the total water vapor burden (PW). In addition, accurate absolute PW estimates from GPS data for baseline lengths between 1500 and 3000 km were obtained. Previously, 500 and 2000 km have been recommended in the literature as the minimum baseline length needed for accurate absolute PW estimation. An exception occurs when GPS data acquired in Guam, one of the nine IGS stations, were utilized. This result is a possible further indication that the rms difference between GPS- and WVR-measured PW is dependent on the total water vapor burden, because both Taipei and Guam are located in more humid regions than the other stations.

  3. Seasonal change in precipitation, snowpack, snowmelt, soil water and streamwater chemistry, northern Michigan

    USGS Publications Warehouse

    Stottlemyer, R.; Toczydlowski, D.

    1999-01-01

    We have studied weekly precipitation, snowpack, snowmelt, soil water and streamwater chemistry throughout winter for over a decade in a small (176 ha) northern Michigan watershed with high snowfall and vegetated by 60 to 80 year-old northern hardwoods. In this paper, we examine physical, chemical, and biological processes responsible for observed seasonal change in streamwater chemistry based upon intensive study during winter 1996-1997. The objective was to define the contributions made to winter and spring streamwater chemical concentration and flux by processes as snowmelt, over-winter forest floor and surface soil mineralization, immobilization, and exchange, and subsurface flowpath. The forest floor and soil were unfrozen beneath the snowpack which permitted most snowmelt to enter. Over-winter soil mineralization and other biological processes maintain shallow subsurface ion and dissolved organic carbon (DOC) reservoirs. Small, but steady, snowmelt throughout winter removed readily mobilized soil NO3- which resulted in high over-winter streamwater concentrations but little flux. Winter soil water levels and flowpaths were generally deep which increased soil water and streamwater base cation (C(B)), HCO3-, and Si concentrations. Spring snowmelt increased soil water levels and removal of ions and DOC from the biologically active forest floor and shallow soils. The snowpack solute content was a minor component in determining streamwater ion concentration or flux during and following peak snowmelt. Exchangeable ions, weakly adsorbed anions, and DOC in the forest floor and surface soils dominated the chemical concentration and flux in soil water and streamwater. Following peak snowmelt, soil microbial immobilization and rapidly increased plant uptake of limiting nutrients removed nearly all available nitrogen from soil water and streamwater. During the growing season high evapotranspiration increased subsurface flowpath depth which in turn removed weathering

  4. Precipitation; ground-water age; ground-water nitrate concentrations, 1995-2002; and ground-water levels, 2002-03 in Eastern Bernalillo County, New Mexico

    USGS Publications Warehouse

    Blanchard, Paul J.

    2004-01-01

    The eastern Bernalillo County study area consists of about 150 square miles and includes all of Bernalillo County east of the crests of the Sandia and Manzanita Mountains. Soil and unconsolidated alluvial deposits overlie fractured and solution-channeled limestone in most of the study area. North of Interstate Highway 40 and east of New Mexico Highway 14, the uppermost consolidated geologic units are fractured sandstones and shales. Average annual precipitation at three long-term National Oceanic and Atmospheric Administration precipitation and snowfall data-collection sites was 14.94 inches at approximately 6,300 feet (Sandia Ranger Station), 19.06 inches at about 7,020 feet (Sandia Park), and 23.07 inches at approximately 10,680 feet (Sandia Crest). The periods of record at these sites are 1933-74, 1939-2001, and 1953-79, respectively. Average annual snowfall during these same periods of record was 27.7 inches at Sandia Ranger Station, 60.8 inches at Sandia Park, and 115.5 inches at Sandia Crest. Seven precipitation data-collection sites were established during December 2000-March 2001. Precipitation during 2001-03 at three U.S. Geological Survey sites ranged from 66 to 94 percent of period-of-record average annual precipitation at corresponding National Oceanic and Atmospheric Administration long-term sites in 2001, from 51 to 75 percent in 2002, and from 34 to 81 percent during January through September 2003. Missing precipitation records for one site resulted in the 34-percent value in 2003. Analyses of concentrations of chlorofluorocarbons CFC-11, CFC-12, and CFC-113 in ground-water samples from nine wells and one spring were used to estimate when the sampled water entered the ground-water system. Apparent ages of ground water ranged from as young as about 10 to 16 years to as old as about 20 to 26 years. Concentrations of dissolved nitrates in samples collected from 24 wells during 2001-02 were similar to concentrations in samples collected from the same

  5. Measurement of Low Amounts of Precipitable Water Vapor Using Ground-Based Millimeterwave Radiometry

    NASA Technical Reports Server (NTRS)

    Racette, Paul E.; Westwater, Ed R.; Han, Yong; Gasiewski, Albin J.; Klein, Marian; Cimini, Domenico; Jones, David C.; Manning, WIll; Kim, Edward J.; Wang, James R.

    2003-01-01

    Extremely dry conditions characterized by amounts of precipitable water vapor (PWV) as as 1-2 mm commonly occur in high-latitude regions during the winter months. While such atmospheres carry only a few percent of the latent heat energy compared to tropical atmospheres, the effects of low vapor amounts on the polar radiation budget - both directly through modulation of longwave radiation and indirectly through the formation of clouds - are considerable. Accurate measurements of precipitable water vapor (PWV) during such dry conditions are needed to improve polar radiation models for use in understanding and predicting change in the climatically sensitive polar regions. To this end, the strong water vapor absorption at 183.310 GHz provides a unique means of measuring low amounts of PWV. Weighting function analysis, forward model calculations based upon a 7-year radiosonde dataset, and retrieval simulations consistently predict that radiometric measurements made using several millimeter-wavelength (MMW) channels near the 183 GHz line, together with established microwave (MW) measurements at the 22.235 GHz water vapor line and -3 1 GHz atmospheric absorption window can be used to determine within 5% uncertainty the full range of PWV expected in the Arctic. This unique collective capability stands in spite of accuracy limitations stemming from uncertainties due to the sensitivity of the vertical distribution of temperature and water vapor at MMW channels. In this study the potential of MMW radiometry using the 183 GHz line for measuring low amounts of PWV is demonstrated both theoretically and experimentally. The study uses data obtained during March 1999 as part of an experiment conducted at the Department of Energy s Cloud and Radiation Testbed (CART) near Barrow, Alaska. Several radiometers from both NOAA and NASA were deployed during the experiment to provide the first combined MMW and MW ground-based data set during dry arctic conditions. Single-channel retrievals

  6. Isotopic (18O) characteristics of weekly precipitation collected across the USA: an initial analysis with application to water source studies

    NASA Astrophysics Data System (ADS)

    Welker, J. M.

    2000-06-01

    A portion of the precipitation samples collected and stored by the National Atmospheric Deposition Program (NADP) are shown to be useful for analysis of isotopes in precipitation. The potential problems with evaporation are small based on deuterium excess analyses and comparisons with the Global Meteroic Water Line. Presented here are the 18O values of precipitation collected from nine NADP sites during 1989, 1990 and 1991. The trends in the isotopic (18O) characteristics of recent precipitation are in agreement with findings from previous International Atomic Energy Agency (IAEA) sites in the USA. The findings are also in agreement with several major isotope-environment relationships, further supporting the use of these samples for a modern global data base on the isotopes in precipitation being developed by IAEA, called GNIP (Global Network for Isotopes in Precipitation) and for use by research groups in the hydrological modelling, palaeoclimate and ecological communities.As expected, the average 18O values of precipitation that is derived from the Gulf of Mexico (-3) and from the Pacific North-west are isotopically distinct (-7). In addition, using the NADP network, isotopic depletion in the 18O values of precipitation in the range of 8 was observed from coastal to inland locations either in the Pacific North-west or along the east side of the Rocky Mountains, from Texas to Eastern Montana. In central USA, especially at high elevation, there is a strong seasonal variation in the 18O values of precipitation, differing by almost 25 between January and August, whereas at coastal locations the seasonal variation in the 18O values of precipitation was minimal. Comparisons between the average 18precipitation from several NADP sites and those of the IAEA collected in the 1960s and 1970s are exceptionally comparable, differing in some cases by only 01, further substantiating the quality and utility of precipitation from this network. The

  7. Comparison of Daily Total Precipitable Water From Satellite and Model Reanalysis Fields

    NASA Technical Reports Server (NTRS)

    Jedlovec, Gary J.; Suggs, R. J.; Haines, S. L.

    2000-01-01

    Previous studies have shown that there is fairly good agreement between the monthly values of total precipitable water (TPW) from the NVAP data set, a multi satellite and radiosonde merged data product, and the NCEP reanalysis TPW data. However, there are regions and time periods where significant differences between the data sets are found in the monthly mean TPW time series and period of record trends. To better understand these differences seen in the monthly data values, the daily mean TPW data are examined. Possible contributions to the TPW differences such as data quality of the individual NVAP data set components associated with missing or irregular daily values are addressed. Also, effects associated with the weighting of the individual NVAP data set components to form a merged product are considered. The daily variations in TPW exhibited by each data set are also quantified and compared between the data sets.

  8. Analysis of the distribution of precipitable water vapor in the Chajnantor area

    NASA Astrophysics Data System (ADS)

    Cortés, Fernando; Reeves, Rodrigo; Bustos, Ricardo

    2016-07-01

    In this work, we present results from a long-term precipitable water vapor (PWV) study in the Chajnantor area, in northern Chile. Data from several instruments located at relevant sites for submillimeter and midinfrared astronomy were processed to obtain relations between the atmospheric conditions among the sites. The data used for this study can be considered the richest data set to date, because of the geographical sampling of the region, including sites at different altitudes, a time span from 2005 to 2014, and the different techniques and instruments used for the measurements. We validate a method to convert atmospheric opacity from 350 μm tipper radiometers to PWV. An average of 0.68 PWV ratio between Cerro Chajnantor and Llano of Chajnantor was found.

  9. Simultaneous measurements of stable water isotopes in near-surface vapor and precipitation to constrain below-cloud processes

    NASA Astrophysics Data System (ADS)

    Graf, Pascal; Sodemann, Harald; Pfahl, Stephan; Schneebeli, Marc; Ventura, Jordi Figueras i.; Leuenberger, Andreas; Grazioli, Jacopo; Raupach, Tim; Berne, Alexis; Wernli, Heini

    2016-04-01

    Present-day observations of stable water isotopes (SWI) in precipitation on monthly time scales are abundant and the processes governing the variation of SWI on these time scales have been investigated by many studies. However, also on much shorter time scales of hours mesoscale meteorological processes lead to significant variations of SWIs, which are important to understand. There are only few studies investigating the variations of SWI on this short time scale, for which, e.g., frontal dynamics, convection and cloud microphysics play an essential role. In particular, the isotopic composition of both near-surface vapor and precipitation is significantly influenced by below-cloud processes that include precipitation evaporation and isotopic exchange between falling precipitation and surrounding vapor. In this study, simultaneous measurements of SWI in near-surface vapor and precipitation with high (sub-hourly) temporal resolution in combination with observational data from radars, disdrometers, radiosondes and standard meteorological instruments are used for a detailed analysis of the relative importance of below-cloud and in-cloud (i.e., precipitation formation) processes during the course of three rain events in Switzerland in spring 2014. Periods are identified when the isotopic composition of near-surface vapor and equilibrium vapor above liquid rain drops agree and when they differ due to either evaporation of precipitation or incomplete equilibration of precipitation with surrounding vapor. These findings are verified by the supporting observational data. In addition, calculations with a simple rain-shaft model fed with observational data are compared to the actual isotopic composition of precipitation. This combination of isotope measurements and model calculations allows us to test the sensitivity of the precipitation isotope signal to rain intensity, drop-size distribution and temperature and humidity profiles.

  10. Monitoring the variability of precipitable water vapor over the Klang Valley, Malaysia during flash flood

    NASA Astrophysics Data System (ADS)

    Suparta, W.; Rahman, R.; Singh, M. S. J.

    2014-06-01

    Klang Valley is a focal area of Malaysian economic and business activities where the local weather condition is very important to maintain its reputation. Heavy rainfalls for more than an hour were reported up to 40 mm in September 2013 and 35 mm in October 2013. Both events are monitored as the first and second cases of flash flood, respectively. Based on these cases, we investigate the water vapor, rainfall, surface meteorological data (surface pressure, relative humidity, and temperature) and river water level. The precipitable water vapor (PWV) derived from Global Positioning System (GPS) is used to indicate the impact of flash flood on the rainfall. We found that PWV was dropped 4 mm in 2 hours before rainfall reached to 40 mm and dropped 3 mm in 3 hours before 35 mm of rainfall in respective cases. Variation of PWV was higher in September case compared to October case of about 2 mm. We suggest the rainfall phenomena can disturb the GPS propagation and therefore, the impact of PWV before, during and after the flash flood event at three selected GPS stations in Klang Valley is investigated for possible mitigation in the future.

  11. Determination of the sources and impacts of aerosols on clouds and orographic precipitation during CalWater

    NASA Astrophysics Data System (ADS)

    Prather, K. A.; Suski, K.; Cazorla, A.; Cahill, J. F.; Creamean, J.; Collins, D. B.; Ralph, F. M.; Cayan, D. R.; Rosenfeld, D.; DeMott, P. J.; Sullivan, R. C.; Comstock, J. M.; Leung, L.; Tomlinson, J. M.; Roberts, G. C.; Nenes, A.; Lin, J. J.

    2011-12-01

    Climate projections for the remainder of this century for the U.S. Southwest, including parts of California, suggest a drying trend (reductions ~ 10 -15 %). Thus, understanding factors which could potentially influence the amount and type of precipitation is critical to future water resources in California. Previous studies suggest aerosols transported from the Central Valley into the mountains may be reducing the amount of orographic precipitation in the Sierra Nevada mountain range, the key region for water storage in the snowpack. CalWater, which commenced in the Winter of 2009, is an ongoing multi-year, multi-agency field campaign to investigate the primary sources of aerosols influencing clouds and precipitation in this region. Single particle measurements, used in both ground as well as PNNL G1 aircraft measurements, in the recent campaign provide insight into the sources of aerosols impacting the clouds and precipitation. Biomass burning, Central Valley pollution, long range transported Asian dust and pollution, locally generated newly formed particles, and marine aerosols all show strong impacts on the cloud microphysical properties. This presentation will provide a brief overview of the objective and key findings from CalWater measurements of aerosols, precipitation, clouds, and meteorology conducted from 2009-2011 in this region.

  12. A CloudSat Perspective of the Atmospheric Water Cycle and Precipitation: Recent Progress and Grand Challenges

    NASA Technical Reports Server (NTRS)

    Stephens, Graeme L.; Im, Eastwood; Vane, Deborah

    2012-01-01

    Summary Global - mean precipitation - is controlled by Earth's energy balance and is a quantifiable consequence of the water vapor feedback. Predictability rests on the degree to which the water vapor feedback is predictable. Regional scale - to a significant extent, changes are shaped by atmospheric circulation changes but we do not know the extent to which regional scale changes are predictable. The impacts of changes to atmospheric circulation on regional scale water cycle changes can be dramatic. Process - scale - significant biases to the CHARACTER of precipitation (frequency and intensity) is related to how the precipitation process is parameterized in models. Aerosol - We still do not know the extent to which the water cycle is influenced by aerosol but anecdotal evidence is building. The character of precipitation is affected by the way aerosol influence clouds and thus affects the forcing of the climate system through the albedo effect. Observations - we still have a way to go and need to approach the problem in a more integrated way (tie clouds, aerosol and precipitation together and then link to soil moisture, etc). Globally our capabilities seriously lag behind the science and model development.

  13. NASA-modified precipitation products to improve USEPA nonpoint source water quality modeling for the Chesapeake Bay.

    PubMed

    Nigro, Joseph; Toll, David; Partington, Ed; Ni-Meister, Wenge; Lee, Shihyan; Gutierrez-Magness, Angelica; Engman, Ted; Arsenault, Kristi

    2010-01-01

    The USEPA has estimated that over 20,000 water bodies within the United States do not meet water quality standards. One of the regulations in the Clean Water Act of 1972 requires states to monitor the total maximum daily load, or the amount of pollution that can be carried by a water body before it is determined to be "polluted," for any watershed in the United States (Copeland, 2005). In response to this mandate, the USEPA developed Better Assessment Science Integrating Nonpoint Sources (BASINS) as a decision support tool for assessing pollution and to guide the decision-making process for improving water quality. One of the models in BASINS, the Hydrological Simulation Program-Fortran (HSPF), computes continuous streamflow rates and pollutant concentration at each basin outlet. By design, precipitation and other meteorological data from weather stations serve as standard model input. In practice, these stations may be unable to capture the spatial heterogeneity of precipitation events, especially if they are few and far between. An attempt was made to resolve this issue by substituting station data with NASA-modified/NOAA precipitation data. Using these data within HSPF, streamflow was calculated for seven watersheds in the Chesapeake Bay Basin during low flow periods, convective storm periods, and annual flows. In almost every case, the modeling performance of HSPF increased when using the NASA-modified precipitation data, resulting in better streamflow statistics and, potentially, in improved water quality assessment.

  14. Precipitation efficiency derived from isotope ratios in water vapor distinguishes dynamical and microphysical influences on subtropical atmospheric constituents

    NASA Astrophysics Data System (ADS)

    Bailey, A.; Nusbaumer, J.; Noone, D.

    2015-09-01

    With water vapor and clouds expected to effect significant feedbacks on climate, moisture transport through convective processes has important implications for future temperature change. The precipitation efficiency—the ratio of the rates at which precipitation and condensation form (e = P/C)—is useful for characterizing how much boundary layer moisture recycles through precipitation versus mixes into the free troposphere through cloud detrainment. Yet it is a difficult metric to constrain with traditional observational techniques. This analysis characterizes the precipitation efficiency of convection near the Big Island of Hawaii, USA, using a novel tracer: isotope ratios in water vapor. The synoptic circulation patterns associated with high and low precipitation efficiency are identified, and the importance of large-scale dynamics and local convective processes in regulating vertical distributions of atmospheric constituents important for climate is evaluated. The results suggest that high e days are correlated with plume-like transport originating from the relatively clean tropics, while low e days are associated with westerly transport, generated by a branching of the jet stream. Differences in transport pathway clearly modify background concentrations of water vapor and other trace gases measured at Mauna Loa Observatory; however, local convective processes appear to regulate aerosols there. Indeed, differences between observed and simulated diurnal cycles of particle number concentration indicate that precipitation scavenges aerosols and possibly facilitates new particle formation when e is high. As measurements of isotope ratios in water vapor expand across the subtropics, the techniques presented here can further our understanding of how synoptic weather, precipitation processes, and climate feedbacks interrelate.

  15. Association between Precipitation Upstream of a Drinking Water Utility and Nurse Advice Calls Relating to Acute Gastrointestinal Illnesses

    PubMed Central

    Tornevi, Andreas; Axelsson, Gösta; Forsberg, Bertil

    2013-01-01

    Background The River Göta Älv is a source of fresh-water for the City of Gothenburg (Sweden). We recently identified a clear association between upstream precipitation and indicator bacteria concentrations in the river water outside the intake to the drinking water utility. This study aimed to determine if variation in the incidence of acute gastrointestinal illnesses is associated with upstream precipitation. Methods We acquired data, covering 1494 days, on the daily number of telephone calls to the nurse advice line from citizens in Gothenburg living in areas with Göta Älv as a fresh-water supply. We separated calls relating to gastrointestinal illnesses from other medical concerns, and analyzed their association with precipitation using a distributed lag non-linear Poisson regression model, adjusting for seasonal patterns and covariates. We used a 0–21-day lag period for precipitation to account for drinking water delivery times and incubation periods of waterborne pathogens. Results The study period contained 25,659 nurse advice calls relating to gastrointestinal illnesses. Heavy rainfall was associated with increased calls the same day and around 5–6 days later. Consecutive days of wet weather were also found to be associated with an increase in the daily number of gastrointestinal concerns. No associations were identified between precipitation and nurse advice calls relating to other medical concerns. Conclusion An increase in nurse advice calls relating to gastrointestinal illnesses around 5–6 days after heavy rainfall is consistent with a hypothesis that the cause could be related to drinking water due to insufficient barriers in the drinking water production, suggesting the need for improved drinking water treatment. PMID:23875009

  16. Changing Precipitation Patterns or Waning Glaciers? Identifying Water Supply Vulnerabilities to Climate Change in the Bolivian Andes

    NASA Astrophysics Data System (ADS)

    Guido, Z. S.; McIntosh, J. C.; Papuga, S. A.

    2010-12-01

    The Bolivian Andes have become an iconic example for the impacts of climate change. Glaciers are rapidly melting and some have already completely disappeared. More than 75 percent of the water consumed by 2 million people living on the flanks of the Bolivian Andes comes from mountains and it is often cited that the dwindling ice threatens the water supply of the expanding and destitute population living in the twin cities of La Paz and El Alto. However, the wet and the warm seasons and the cold and dry seasons coincide, causing high precipitation and ice melt—and therefore high streamflows—to occur only in the austral summer (October-March); during the austral winter, cold conditions limit glacier melt. This suggests that reductions in the water supply could be influenced more by changing precipitation amounts than continued glacial mass-wasting. We hypothesize that precipitation is the principal component of groundwater recharge for the aquifers at the base of the central Cordillera Real. Oxygen and hydrogen isotopes from rivers partially fed by glaciers, groundwater, and glacial melt water can help determine the relative contribution of precipitation and glacial melt to important water supplies. During the dry season in August 2010, we sampled 23 sites that follow the flow path of water in the Condiriri watershed, beginning in the glacial headwaters and ending several kilometers upriver from Lake Titicaca. We collected five samples at the toe of the Pequeño Alpamayo glacier and four samples from three tributary rivers that drain glaciated headwaters, which include meltwater from the Pequeño Alpamayo glacier. W also collected 14 water samples from shallow and deep wells in rural communities within 40 kilometers of the glaciers. If the isotopic values of groundwater are similar to rain values, as we suspect, precipitation is likely the largest contributor to groundwater resources in the region and will suggest that changing precipitation patterns present the

  17. Precipitation Matters

    ERIC Educational Resources Information Center

    McDuffie, Thomas

    2007-01-01

    Although weather, including its role in the water cycle, is included in most elementary science programs, any further examination of raindrops and snowflakes is rare. Together rain and snow make up most of the precipitation that replenishes Earth's life-sustaining fresh water supply. When viewed individually, raindrops and snowflakes are quite…

  18. The Use of Water Vapor for Detecting Environments that Lead to Convectively Produced Heavy Precipitation and Flash Floods

    NASA Technical Reports Server (NTRS)

    Scofield, Rod; Vicente, Gilberto; Hodges, Mike

    2000-01-01

    This Tech Report summarizes years of study and experiences on using GOES Water vapor (6.7 micron and precipitable water) and Special Sensor Microwave Imager (SSM/1) from the Defense Meteorological Satellite Program (DMSP) derived Precipitable Water (PNAI) for detecting environments favorable for convectively produced flash floods. An emphasis is on the moisture. upper air flow, and equivalent potential temperature (Theta(sub e)) patterns that lead to devastating flood events. The 15 minute 6.7 micron water vapor imagery is essential for tracking middle to upper tropospheric disturbances that produce upward vertical motion and initiate flash flood producing systems. Water vapor imagery at 6.7 micron is also used to detect surges of upper level moisture (called tropical water vapor plumes) that have been associated with extremely heavy rainfall. Since the water vapor readily depicts lifting mechanisms and upper level moisture, water vapor imagery is often an excellent source of data for recognizing patterns of heavy precipitation and flash floods. In order to analyze the depth of the moisture, the PW aspects of the troposphere must be measured. The collocation (or nearby location) of high values ofP\\V and instability are antecedent conditions prior to the flash flood or heavy rainfall events. Knowledge of PW magnitudes have been used as thresholds for impending flash flood events, PW trends are essential in flash flood prediction. Conceptual models and water vapor products are used to study some of the characteristics of convective systems that occurred over the United States of America (USA) during the summer of 1997 and the 1997-1998 El Nino. P\\V plumes were associated with most of the \\vest coast heavy precipitation events examined during the winter season of 1997 - 1998, In another study, conducted during the summer season of 1997. results showed that the collocation of water vapor (6.7 micron) and P\\N' plumes possessed higher correlations with predicted

  19. Methodology to assess water presence on speleothems during periods of low precipitation, with implications for recharge sources - Kartchner Caverns, Arizona

    USGS Publications Warehouse

    Blasch, Kyle W.

    2011-01-01

    Beginning in January 2005, recharge processes and the presence of water on speleothems were monitored in Kartchner Caverns during a 44-month period when annual rainfall rates were 6 to 18 percent below the long-term mean. Electrical-resistance sensors designed to detect the presence of water were used to identify ephemeral streamflow in the channels overlying the cave as well as the movement of water within the cave system. Direct infiltration of precipitation through overhead rocks provided consistent inflow to the cave, but precipitation rates and subsequent infiltration rates were reduced during the comparatively dry years. Ephemeral stream-channel recharge through autogenic and allogenic processes, the predominant recharge mechanism during wetter periods, was limited to two low-volume events. From visual observations, it appeared that recharge from channel infiltration was equal to or less than recharge from overhead infiltration. Electrical-resistance sensors were able to detect thin films of water on speleothems, including stalactites, ribbons, and stalagmites. These films of water were directly attributed to overhead infiltration of precipitation. Periods of low precipitation resulted in decreased speleothem wetness.

  20. Influence of the vertical structure of the atmosphere on the seasonal variation of precipitable water and greenhouse effect

    SciTech Connect

    Bony, S.; Duvel, J.P.

    1994-06-01

    By using satellite observations and European Centre for Medium Range Weather Forecasts (ECMWF) analyses, we study the seasonal variations of the precipitable water and the greenhouse effect, defined as the normalized difference between the longwave flux emitted at the surface and that emergent at the top of the atmosphere. Results show a strong systematic influence of the vertical structure of the atmosphere on geographical and seasonal variations of both precipitable water and greenhouse effect. Over ocean, in middle and high latitudes, the seasonal variation of the mean temperature lapse rate in the troposphere leads to large seasonal phase lags between greenhouse effect and precipitable water. By contrast, the seasonal variation of the clear-sky greenhouse effect over tropical oceans is mainly driven by the total atmospheric transmittance and thus by precipitable water variations. Over land, the seasonal variations of the tropospheric lapse rate acts to amplify the radiative impact of water vapor changes, giving a strong seasonal variation of the greenhouse effect. Over tropical land regions, monsoon activity generates a seasonal phase lag between surface temperature and relative humidity variations that gives a seasonal lag of about 2 months between the surface temperature and the clear-sky greenhouse effect. Generally, the cloudiness amplifies clear-sky tendencies. Finally, as an illustration, obtained results are used to evaluate the general circulation model of the Laboratoire de Meteorologie Dynamique.

  1. The comparison of IR and MW ground-based measurements of total precipitable water

    NASA Astrophysics Data System (ADS)

    Berezin, I. A.; Virolainen, Ya. A.; Timofeyev, Yu. M.; Poberovskii, A. V.

    2016-05-01

    Water vapor is one of the basic climate gases playing a key role in various processes at different altitudes of the Earth's atmosphere. An intercomparison and validation of different total precipitable water (TPW) measurement methods are important for determining the true accuracy of these methods, the shared use of data from multiple sources, the creation of data archives of different measurements, etc. In this paper, the TPW values obtained from measurements of solar IR spectral radiation (~8-9 μm absorption band) and thermal MW radiation of the atmosphere (1.35 cm absorption line) for 138 days of observation are compared. Measurements have been carried out from March 2013 to June 2014 at Peterhof station of the St. Petersburg State University in (59.88° N, 29.82° E). It is shown that MW measurements usually give higher TPW values than IR measurements. The bias between the two methods varies from 1 to 8% for small and large TPW values, respectively. With increasing TPW values, the bias reduces and for TPW > 1 cm it is ~1%. Standard deviation (SD) between the two methods reaches 7% for TPW < 0.4 cm and 3-5% for TPW > 1 cm. These data show the high quality of both remote sensing methods. Moreover, the IR measurements have a higher accuracy than MW measurements for small TPW values.

  2. Assessment of spill flow emissions on the basis of measured precipitation and waste water data

    NASA Astrophysics Data System (ADS)

    Hochedlinger, Martin; Gruber, Günter; Kainz, Harald

    2005-09-01

    Combined sewer overflows (CSOs) are substantial contributors to the total emissions into surface water bodies. The emitted pollution results from dry-weather waste water loads, surface runoff pollution and from the remobilisation of sewer deposits and sewer slime during storm events. One possibility to estimate overflow loads is a calculation with load quantification models. Input data for these models are pollution concentrations, e.g. Total Chemical Oxygen Demand (COD tot), Total Suspended Solids (TSS) or Soluble Chemical Oxygen Demand (COD sol), rainfall series and flow measurements for model calibration and validation. It is important for the result of overflow loads to model with reliable input data, otherwise this inevitably leads to bad results. In this paper the correction of precipitation measurements and the sewer online-measurements are presented to satisfy the load quantification model requirements already described. The main focus is on tipping bucket gauge measurements and their corrections. The results evidence the importance of their corrections due the effects on load quantification modelling and show the difference between corrected and not corrected data of storm events with high rain intensities.

  3. A comparison of total precipitable water measurements from radiosonde and sunphotometers

    NASA Astrophysics Data System (ADS)

    Campmany, Elies; Bech, Joan; Rodríguez-Marcos, Javier; Sola, Yolanda; Lorente, Jerónimo

    2010-08-01

    Atmospheric water vapour is an essential component of the terrestrial atmosphere and must be known precisely in a wide range of applications such as radiative transfer modelling or weather forecasting to mention just a few examples. Vertically integrated measurements, or total precipitable water (TPW) equivalent amounts traditionally derived from radiosonde measurements, are needed in many of these applications and can also be obtained from other methodologies such as sunphotometers or GPS-based techniques. This paper presents a study comparing different measurements of TPW from radiosonde and sunphotometer data recorded from 2001 to 2004 in Barcelona, Spain. Three collocated instruments were employed in this study: RS-80A Vaisala sondes and two types of commonly used sunphotometers (Cimel 318N-VBS7 and Microtops II). A cloud screening filter was applied to photometer data based on the quality control procedure of the AERONET database. A systematic comparison among the measurements indicates that bivariate correlations between different instruments were high, with correlation factors ( r2) above 0.8 in all cases. Measurements covered all seasons allowing examining intra-annual variability, which generally did not exhibit statistically significant differences. Examination of 57 concurrent measurements of the three instruments indicated that radiosonde TPW measurements were the highest (15 mm on average) and Cimel and Microtops presented similar values (12 mm and 11 mm respectively).

  4. MM-Wave Radiometric Measurements of Low Amounts of Precipitable Water Vapor

    NASA Technical Reports Server (NTRS)

    Racette, P.; Westwater, Ed; Han, Yong; Manning, Will; Jones, David; Gasiewski, Al

    2000-01-01

    An experiment was conducted during March, 1999 to study ways in which to improve techniques for measuring low amounts of total-column precipitable water vapor (PWV). The experiment was conducted at the DOE's ARM program's North Slope of Alaska/Adjacent Arctic Ocean Cloud and Radiation Testbed site (DoE ARM NSA/AAO CaRT) located just outside Barrow, Alaska. NASA and NOAA deployed a suite of radiometers covering 25 channels in the frequency range of 20 GHz up to 340 GHz including 8 channels around the 183 GHz water vapor absorption line. In addition to the usual CaRT site instrumentation the NOAA Depolarization and Backscatter Unattended Lidar (DABUL), the SUNY Rotating Shadowband Spectroradiometer (RSS) and other surface based meteorological instrumentation were deployed during the intensive observation period. Vaisala RS80 radiosondes were launched daily as well as nearby National Weather Service VIZ sondes. Atmospheric conditions ranged from clear calm skies to blowing snow and heavy multi-layer cloud coverage. Measurements made by the radiosondes indicate the PWV varied from approx. 1 to approx. 5 mm during the experiment. The near-surface temperature varied between about -40 C to - 15 C. In this presentation, an overview of the experiment with examples of data collected will be presented. Application of the data for assessing the potential and limitations of millimeter-wave radiometry for retrieving very low amounts of PWV will be discussed.

  5. The Impact of Urbanization on the Precipitation Component of the Water Cycle: A New Perspective

    NASA Technical Reports Server (NTRS)

    Shephard, J. Marshal

    2002-01-01

    It is estimated that by the year 2025, 60% of the world s population will live in cities (UNFP, 1999). As cities continue to grow, urban sprawl (e.g., the expansion of urban surfaces outward into rural surroundings) creates unique problems related to land use, transportation, agriculture, housing, pollution, and development. Urban expansion also has measurable impacts on environmental processes. Urban areas modify boundary layer processes through the creation of an urban heat island (UHI). The literature indicates that the signature of the urban heat island effect may be resolvable in rainfall patterns over and downwind of metropolitan areas. However, a recent U.S. Weather Research Program panel concluded that more observational and modeling research is needed in this area (Dabberdt et al. 2000). NASA and other agencies initiated programs such as the Atlanta Land-use Analysis: Temperature and Air Quality Project (ATLANTA) (Quattrochi et al. 1998) which aimed to identify and understand how urban heat islands impact the environment. However, a comprehensive assessment of the role of urban-induced rainfall in the global water and energy cycle (GWEC) and cycling of freshwater was not a primary focus of these efforts. NASA's Earth Science Enterprise (ESE) seeks to develop a scientific understanding of the Earth system and its response to natural or human-induced changes to enable improved prediction capability for climate, weather, and natural hazards (NASA, 2000). Within this mission, the ESE has three basic thrusts: science research to increase Earth system knowledge; an applications program to transfer science knowledge to practical use in society; and a technology program to enable new, better, and cheaper capabilities for observing the earth. Within this framework, a research program is underway to further address the co-relationship between land cover use and change (e.g. urban development) and its impact on key components of the GWEC (e.g., precipitation). This

  6. Precipitation, Ground-water Hydrology, and Recharge Along the Eastern Slopes of the Sandia Mountains, Bernalillo County, New Mexico

    USGS Publications Warehouse

    McCoy, Kurt J.; Blanchard, Paul J.

    2008-01-01

    The spatial and temporal distribution of recharge to carbonate and clastic aquifers along the eastern slopes of the Sandia Mountains was investigated by using precipitation, water-level, dissolved chloride, and specific-conductance data. The U.S. Geological Survey (USGS), in cooperation with the Bernalillo County Public Works Division, conducted a study to assess ground-water conditions and provide technical data that could be used as a basis for management and future planning of eastern Bernalillo County water resources. The intent of the investigation was to improve the current understanding of subsurface mechanisms controlling recharge dynamics in a geologically complex aquifer system. In the Sandia Mountains, precipitation events are generally limited to snowfalls in winter months and monsoon rainfall in late summer. Monthly meteorological data from weather stations in the study area indicate that monsoon rainfall during July and August constitutes close to one-third of annual precipitation totals. Following precipitation and snowmelt events, daily ground-water level data show low-amplitude, long-duration peaks in hydrographs of wells north and west of the Tijeras Fault. Hydrographs of monthly and biannual water-level data from across the study area show seasonal variation and water-level fluctuations in excess of 30 ft during a period of below-average precipitation. Water level observations in 67 percent of wells showing drought-induced water-level declines rebounded to at or near predrought conditions within 6 months of return to normal climate conditions. Cross-correlation of annual hydrologic data shows aquifer response to periods of monsoon recharge to persist from 1 to 6 months following events. The lag time between precipitation input and response of water levels or solute concentrations was largest near the Tijeras and Gutierrez Faults. These results indicate regional faults hydrologically isolate the Tijeras Graben from groundwater recharge originating

  7. Preparation of nanoparticles of poorly water-soluble antioxidant curcumin by antisolvent precipitation methods

    NASA Astrophysics Data System (ADS)

    Kakran, Mitali; Sahoo, Nanda Gopal; Tan, I.-Lin; Li, Lin

    2012-03-01

    The objective of this study was to enhance the solubility and dissolution rate of a poorly water-soluble antioxidant, curcumin, by fabricating its nanoparticles with two methods: antisolvent precipitation with a syringe pump (APSP) and evaporative precipitation of nanosuspension (EPN). For APSP, process parameters like flow rate, stirring speed, solvent to antisolvent (SAS) ratio, and drug concentration were investigated to obtain the smallest particle size. For EPN, factors like drug concentration and the SAS ratio were examined. The effects of these process parameters on the supersaturation, nucleation, and growth rate were studied and optimized to obtain the smallest particle size of curcumin by both the methods. The average particle size of the original drug was about 10-12 μm and it was decreased to a mean diameter of 330 nm for the APSP method and to 150 nm for the EPN method. Overall, decreasing the drug concentration or increasing the flow rate, stirring rate, and antisolvent amount resulted in smaller particle sizes. Differential scanning calorimetry studies suggested lower crystallinity of curcumin particles fabricated. The solubility and dissolution rates of the prepared curcumin particles were significantly higher than those the original curcumin. The antioxidant activity, studied by the DPPH free radical-scavenging assay, was greater for the curcumin nanoparticles than the original curcumin. This study demonstrated that both the methods can successfully prepare curcumin into submicro to nanoparticles. However, drug particles prepared by EPN were smaller than those by APSP and hence, showed the slightly better solubility, dissolution rate, and antioxidant activity than the latter.

  8. Simulation of the Diurnal Cycle of Integrated Precipitable Water in the North American Monsoon Region

    NASA Astrophysics Data System (ADS)

    Ochoa, C. A.; Quintanar, A.; Adams, D. K.; Martinez-lopez, B.

    2015-12-01

    Organized deep convection over the North American monsoon region (NAM) is a salient climatic feature that has been the subject of several experimental campaigns and modeling efforts. Recently, however, in Mexico and the Caribbean, there has been mounting interest towards implementing low-cost, low-maintenance GPS-meteorological networks (TLALOCNet and COCOnet) that provide near real-time Integrated Precipitable Water data (IPW) into the assimilation cycle of regional models. A wealth of interesting new observational results concerning the link between the diurnal cycle of deep convection and the processes that could alter it at the surface and aloft has open up opportunities of model verification and improvements to the physics that are specific to subtropical deep convection. In this work, the diurnal cycle of IPW is studied using observational data collected during the North American Monsoon GPS Transect Experiment 2013 experiment and numerical simulations with the Weather Research and Forecasting model (WRF). WRF was run in climate mode to generate a simulation for the entire experiment using ECMWF ERA-Interim analysis data for initial and boundary conditions and spectral nudging. We classified the days during the experiment, according to type of mesoscale phenomena present each day and averaged days with same weather types in both data sets (observed and simulated). Preliminary results show that the simulated diurnal cycle of IPW is very sensitive to Land Use/Land Cover data and to initial and the boundary conditions. Preliminary results show that the simulated amplitude and phase of the diurnal cycle of IPW is well represented only when a more up-to-date LULC is used (MODIS v.s. 99 USGS LULC) and the Thompson mycrophysics scheme is used. In agreement with the previous results, modeled precipitation time series agree better with observed GPS-meterological station reports during the NAM 2013 experiment.

  9. Biases in Total Precipitable Water Vapor Climatologies from Atmospheric Infrared Sounder and Advanced Microwave Scanning Radiometer

    NASA Technical Reports Server (NTRS)

    Fetzer, Eric J.; Lambrigtsen, Bjorn H.; Eldering, Annmarie; Aumann, Hartmut H.; Chahine, Moustafa T.

    2006-01-01

    We examine differences in total precipitable water vapor (PWV) from the Atmospheric Infrared Sounder (AIRS) and the Advanced Microwave Scanning Radiometer (AMSR-E) experiments sharing the Aqua spacecraft platform. Both systems provide estimates of PWV over water surfaces. We compare AIRS and AMSR-E PWV to constrain AIRS retrieval uncertainties as functions of AIRS retrieved infrared cloud fraction. PWV differences between the two instruments vary only weakly with infrared cloud fraction up to about 70%. Maps of AIRS-AMSR-E PWV differences vary with location and season. Observational biases, when both instruments observe identical scenes, are generally less than 5%. Exceptions are in cold air outbreaks where AIRS is biased moist by 10-20% or 10-60% (depending on retrieval processing) and at high latitudes in winter where AIRS is dry by 5-10%. Sampling biases, from different sampling characteristics of AIRS and AMSR-E, vary in sign and magnitude. AIRS sampling is dry by up to 30% in most high-latitude regions but moist by 5-15% in subtropical stratus cloud belts. Over the northwest Pacific, AIRS samples conditions more moist than AMSR-E by a much as 60%. We hypothesize that both wet and dry sampling biases are due to the effects of clouds on the AIRS retrieval methodology. The sign and magnitude of these biases depend upon the types of cloud present and on the relationship between clouds and PWV. These results for PWV imply that climatologies of height-resolved water vapor from AIRS must take into consideration local meteorological processes affecting AIRS sampling.

  10. Global Positioning System (GPS) Precipitable Water in Forecasting Lightning at Spaceport Canaveral

    NASA Technical Reports Server (NTRS)

    Kehrer, Kristen C.; Graf, Brian; Roeder, William

    2006-01-01

    This paper evaluates the use of precipitable water (PW) from Global Positioning System (GPS) in lightning prediction. Additional independent verification of an earlier model is performed. This earlier model used binary logistic regression with the following four predictor variables optimally selected from a candidate list of 23 candidate predictors: the current precipitable water value for a given time of the day, the change in GPS-PW over the past 9 hours, the KIndex, and the electric field mill value. This earlier model was not optimized for any specific forecast interval, but showed promise for 6 hour and 1.5 hour forecasts. Two new models were developed and verified. These new models were optimized for two operationally significant forecast intervals. The first model was optimized for the 0.5 hour lightning advisories issued by the 45th Weather Squadron. An additional 1.5 hours was allowed for sensor dwell, communication, calculation, analysis, and advisory decision by the forecaster. Therefore the 0.5 hour advisory model became a 2 hour forecast model for lightning within the 45th Weather Squadron advisory areas. The second model was optimized for major ground processing operations supported by the 45th Weather Squadron, which can require lightning forecasts with a lead-time of up to 7.5 hours. Using the same 1.5 lag as in the other new model, this became a 9 hour forecast model for lightning within 37 km (20 NM)) of the 45th Weather Squadron advisory areas. The two new models were built using binary logistic regression from a list of 26 candidate predictor variables: the current GPS-PW value, the change of GPS-PW over 0.5 hour increments from 0.5 to 12 hours, and the K-index. The new 2 hour model found the following for predictors to be statistically significant, listed in decreasing order of contribution to the forecast: the 0.5 hour change in GPS-PW, the 7.5 hour change in GPS-PW, the current GPS-PW value, and the KIndex. The new 9 hour forecast model found

  11. Global Positioning System (GPS) Precipitable Water in Forecasting Lightning at Spaceport Canaveral

    NASA Technical Reports Server (NTRS)

    Kehrer, Kristen; Graf, Brian G.; Roeder, William

    2005-01-01

    Using meteorology data, focusing on precipitable water (PW), obtained during the 2000-2003 thunderstorm seasons in Central Florida, this paper will, one, assess the skill and accuracy measurements of the current Mazany forecasting tool and, two, provide additional forecasting tools that can be used in predicting lightning. Kennedy Space Center (KSC) and Cape Canaveral Air Force Station (CCAFS) are located in east Central Florida. KSC and CCAFS process and launch manned (NASA Space Shuttle) and unmanned (NASA and Air Force Expendable Launch Vehicles) space vehicles. One of the biggest cost impacts is unplanned launch scrubs due to inclement weather conditions such as thunderstorms. Each launch delay/scrub costs over a quarter million dollars, and the need to land the Shuttle at another landing site and return to KSC costs approximately $ 1M. Given the amount of time lost and costs incurred, the ability to accurately forecast (predict) when lightning will occur can result in significant cost and time savings. All lightning prediction models were developed using binary logistic regression. Lightning is the dependent variable and is binary. The independent variables are the Precipitable Water (PW) value for a given time of the day, the change in PW up to 12 hours, the electric field mill value, and the K-index value. In comparing the Mazany model results for the 1999 period B against actual observations for the 2000-2003 thunderstorm seasons, differences were found in the False Alarm Rate (FAR), Probability of Detection (POD) and Hit Rate (H). On average, the False Alarm Rate (FAR) increased by 58%, the Probability of Detection (POD) decreased by 31% and the Hit Rate decreased by 20%. In comparing the performance of the 6 hour forecast period to the performance of the 1.5 hour forecast period for the Mazany model, the FAR was lower by 15% and the Hit Rate was higher by 7%. However, the POD for the 6 hour forecast period was lower by 16% as compared to the POD of the 1

  12. Where Does the Irrigation Water Go? An Estimate of the Contribution of Irrigation to Precipitation Using MERRA

    NASA Technical Reports Server (NTRS)

    Wei, Jiangfeng; Dirmeyer, Paul A.; Wisser, Dominik; Bosilovich, Michael G.; Mocko, David M.

    2013-01-01

    Irrigation is an important human activity that may impact local and regional climate, but current climate model simulations and data assimilation systems generally do not explicitly include it. The European Centre for Medium-Range Weather Forecasts (ECMWF) Interim Re-Analysis (ERA-Interim) shows more irrigation signal in surface evapotranspiration (ET) than the Modern-Era Retrospective Analysis for Research and Applications (MERRA) because ERA-Interim adjusts soil moisture according to the observed surface temperature and humidity while MERRA has no explicit consideration of irrigation at the surface. But, when compared with the results from a hydrological model with detailed considerations of agriculture, the ET from both reanalyses show large deficiencies in capturing the impact of irrigation. Here, a back-trajectory method is used to estimate the contribution of irrigation to precipitation over local and surrounding regions, using MERRA with observation-based corrections and added irrigation-caused ET increase from the hydrological model. Results show substantial contributions of irrigation to precipitation over heavily irrigated regions in Asia, but the precipitation increase is much less than the ET increase over most areas, indicating that irrigation could lead to water deficits over these regions. For the same increase in ET, precipitation increases are larger over wetter areas where convection is more easily triggered, but the percentage increase in precipitation is similar for different areas. There are substantial regional differences in the patterns of irrigation impact, but, for all the studied regions, the highest percentage contribution to precipitation is over local land.

  13. A continuous and highly effective static mixing process for antisolvent precipitation of nanoparticles of poorly water-soluble drugs.

    PubMed

    Dong, Yuancai; Ng, Wai Kiong; Hu, Jun; Shen, Shoucang; Tan, Reginald B H

    2010-02-15

    Rapid and homogeneous mixing of the solvent and antisolvent is critical to achieve submicron drug particles by antisolvent precipitation technique. This work aims to develop a continuous and highly effective static mixing process for antisolvent precipitation of nanoparticles of poorly water-soluble drugs with spironolactone as a model drug. Continuous antisolvent production of drug nanoparticles was carried out with a SMV DN25 static mixer comprising 6-18 mixing elements. The total flow rate ranged from 1.0 to 3.0 L/min while the flow rate ratio of solvent to antisolvent was maintained at 1:9. It is found that only 6 mixing elements were sufficient to precipitate the particles in the submicron range. Increasing the number of elements would further reduce the precipitated particle size. Increasing flow rate from 1.0 to 3.0 L/min did not further reduce the particle size, while higher drug concentrations led to particle size increase. XRD and SEM results demonstrated that the freshly precipitated drug nanoparticles are in the amorphous state, which would, in presence of the mixture of solvent and antisolvent, change to crystalline form in short time. The lyophilized spironolactone nanoparticles with lactose as lyoprotectant possessed good redispersibility and showed 6.6 and 3.3 times faster dissolution rate than that of lyophilized raw drug formulation in 5 and 10 min, respectively. The developed static mixing process exhibits high potential for continuous and large-scale antisolvent precipitation of submicron drug particles.

  14. Relations Between Grace-Derived Water Storage Change with Precipitation and Temperature Over Kaidu River Basin, China

    NASA Astrophysics Data System (ADS)

    Huang, J.; Zhou, Q.

    2016-06-01

    Water is essential for human survival and well-being, and important to virtually all sectors of the economy. In the aridzone of China's west, water resource is the controlling factor on the distribution of human settlements. Water cycle variation is sensitive to temperature and precipitation, which are influenced by human activity and climate change. Satellite observations of Earth's time-variable gravity field from the Gravity Recovery and Climate Experiment (GRACE) mission, which enable direct measurement of changes of total terrestrial water storage, could be useful to aid this modelling. In this pilot study, TWS change from 2002 to 2013 obtained from GRACE satellite mission over the Kaidu River Basin in Xinjiang, China is presented. Precipitation and temperature data from in-situ station and National Satellite Meteorological Centre of China (NSMC) are analysed to examine whether there is a statistically significant correlation between them.

  15. Estimation of total precipitable water and snow cover in Alaska using radiometric measurements near 90 and 183 GHz

    NASA Technical Reports Server (NTRS)

    Wang, J. R.; Chang, A. T. C.; Sharma, A. K.

    1991-01-01

    Radiometric measurements at 90 GHz and three sideband frequencies near the peak water-vapor absorption line of 183.3 GHz were made with the Advanced Microwave Moisture Sounder (AMMS) aboard the NASA DC-8 aircraft over Alaska on November 28, 1989. These measurements show that when the atmosphere is relatively dry the total precipitable water and snow cover could be estimated with high sensitivity. The estimated total precipitable water correlates positively with the aircraft radar altitude. This positive correlation is expected because aircraft radar altitude provides a measure of atmospheric burden above the surface. The surface reflectivities at both 90 and 183 GHz are also estimated which can be used to estimate snow water equivalent.

  16. Precipitation and temperature variations affecting glacierised Himalayan headwaters and water resources in the upper Indus and Sutlej basins

    NASA Astrophysics Data System (ADS)

    Collins, D. N.; Eaton, D.; Entwistle, N. S.

    2013-12-01

    Both the main stem upper Indus and Sutlej rivers feed major reservoirs for hydropower plants and supply water for irrigated agriculture in the Punjab plains. Flows in both rivers have shown significant decreases since the mid-20th century. Monsoon precipitation, which dominates flow in lower Himalayan section of the Sutlej as the upper basin on the Tibetan plateau is fairly dry, has declined by about 30% since the 1950s maximum. Air temperatures decreased from the 1960s to 1980s before recovering in the early 2000s to previous levels. Any enhanced glacier melt in the late twentieth century failed to offset declining precipitation and river flow continued to fall. In the upper Indus basin, precipitation derived in winter from the westerlies was enhanced but temperatures remained flat at stations in valleys at which measurements were undertaken. Runoff from tributary basins of the Indus, which have variable percentages of ice-cover, appears to be subdued as precipitation gently increased. Temperature was more stable than in mountain basins farther east. Valley bottoms in the Karakoram are arid, so that precipitation on glaciers reduces flow but there is little seasonal slow to melt to contribute to runoff in the ice-free areas. Changes in glacierised area seem to have limited impact on flow in these two significant rivers. Precipitation in Himalayan sub-catchments dominates flow, but has contrasting effects on runoff downstream. Temporal variations in both winter and summer precipitation along the Himalayan arc therefore have strong influences on the sustainability of water resources in the adjacent plains.

  17. Analytical studies assessing the association between extreme precipitation or temperature and drinking water-related waterborne infections: a review.

    PubMed

    Guzman Herrador, Bernardo R; de Blasio, Birgitte Freiesleben; MacDonald, Emily; Nichols, Gordon; Sudre, Bertrand; Vold, Line; Semenza, Jan C; Nygård, Karin

    2015-03-27

    Determining the role of weather in waterborne infections is a priority public health research issue as climate change is predicted to increase the frequency of extreme precipitation and temperature events. To document the current knowledge on this topic, we performed a literature review of analytical research studies that have combined epidemiological and meteorological data in order to analyze associations between extreme precipitation or temperature and waterborne disease.A search of the databases Ovid MEDLINE, EMBASE, SCOPUS and Web of Science was conducted, using search terms related to waterborne infections and precipitation or temperature. Results were limited to studies published in English between January 2001 and December 2013.Twenty-four articles were included in this review, predominantly from Asia and North-America. Four articles used waterborne outbreaks as study units, while the remaining articles used number of cases of waterborne infections. Results presented in the different articles were heterogeneous. Although most of the studies identified a positive association between increased precipitation or temperature and infection, there were several in which this association was not evidenced. A number of articles also identified an association between decreased precipitation and infections. This highlights the complex relationship between precipitation or temperature driven transmission and waterborne disease. We encourage researchers to conduct studies examining potential effect modifiers, such as the specific type of microorganism, geographical region, season, type of water supply, water source or water treatment, in order to assess how they modulate the relationship between heavy rain events or temperature and waterborne disease. Addressing these gaps is of primary importance in order to identify the areas where action is needed to minimize negative impact of climate change on health in the future.

  18. The effects of precipitation, river discharge, land use and coastal circulation on water quality in coastal Maine

    PubMed Central

    Tilburg, Charles E.; Jordan, Linda M.; Carlson, Amy E.; Zeeman, Stephan I.; Yund, Philip O.

    2015-01-01

    Faecal pollution in stormwater, wastewater and direct run-off can carry zoonotic pathogens to streams, rivers and the ocean, reduce water quality, and affect both recreational and commercial fishing areas of the coastal ocean. Typically, the closure of beaches and commercial fishing areas is governed by the testing for the presence of faecal bacteria, which requires an 18–24 h period for sample incubation. As water quality can change during this testing period, the need for accurate and timely predictions of coastal water quality has become acute. In this study, we: (i) examine the relationship between water quality, precipitation and river discharge at several locations within the Gulf of Maine, and (ii) use multiple linear regression models based on readily obtainable hydrometeorological measurements to predict water quality events at five coastal locations. Analysis of a 12 year dataset revealed that high river discharge and/or precipitation events can lead to reduced water quality; however, the use of only these two parameters to predict water quality can result in a number of errors. Analysis of a higher frequency, 2 year study using multiple linear regression models revealed that precipitation, salinity, river discharge, winds, seasonality and coastal circulation correlate with variations in water quality. Although there has been extensive development of regression models for freshwater, this is one of the first attempts to create a mechanistic model to predict water quality in coastal marine waters. Model performance is similar to that of efforts in other regions, which have incorporated models into water resource managers' decisions, indicating that the use of a mechanistic model in coastal Maine is feasible. PMID:26587258

  19. The effects of precipitation, river discharge, land use and coastal circulation on water quality in coastal Maine.

    PubMed

    Tilburg, Charles E; Jordan, Linda M; Carlson, Amy E; Zeeman, Stephan I; Yund, Philip O

    2015-07-01

    Faecal pollution in stormwater, wastewater and direct run-off can carry zoonotic pathogens to streams, rivers and the ocean, reduce water quality, and affect both recreational and commercial fishing areas of the coastal ocean. Typically, the closure of beaches and commercial fishing areas is governed by the testing for the presence of faecal bacteria, which requires an 18-24 h period for sample incubation. As water quality can change during this testing period, the need for accurate and timely predictions of coastal water quality has become acute. In this study, we: (i) examine the relationship between water quality, precipitation and river discharge at several locations within the Gulf of Maine, and (ii) use multiple linear regression models based on readily obtainable hydrometeorological measurements to predict water quality events at five coastal locations. Analysis of a 12 year dataset revealed that high river discharge and/or precipitation events can lead to reduced water quality; however, the use of only these two parameters to predict water quality can result in a number of errors. Analysis of a higher frequency, 2 year study using multiple linear regression models revealed that precipitation, salinity, river discharge, winds, seasonality and coastal circulation correlate with variations in water quality. Although there has been extensive development of regression models for freshwater, this is one of the first attempts to create a mechanistic model to predict water quality in coastal marine waters. Model performance is similar to that of efforts in other regions, which have incorporated models into water resource managers' decisions, indicating that the use of a mechanistic model in coastal Maine is feasible.

  20. Monitoring and Prediction of Precipitable Water Vapor using GPS data in Turkey

    NASA Astrophysics Data System (ADS)

    Ansari, Kutubuddin; Althuwaynee, Omar F.; Corumluoglu, Ozsen

    2016-12-01

    Although Global Positioning System (GPS) primarily provide accurate estimates of position, velocity and time of the receiver, as the signals pass through the atmoshphere carrying its signatures, thus offers opportunities for atmoshpheric applications. Precipitable water vapor (PWV) is a vital component of the atmosphere and significantly influences atmospheric processes like rainfall and atmospheric temperature. The developing networks of continuously operating GPS can be used to efficiently estimate PWV. The Turkish Permanent GPS Network (TPGN) is employed to monitor PWV information in Turkey. This work primarily aims to derive long-term data of PWV by using atmospheric path delays observed through continuously operating TPGN from November 2014 to October 2015. A least square mathematical approach was then applied to establish the relation of the observed PWV to rainfall and temperature. The modeled PWV was correlated with PWV estimated from GPS data, with an average correlation of 67.10 %-88.60 %. The estimated root mean square error (RMSE) varied from 2.840 to 6.380, with an average of 4.697. Finally, data of TPGN, rainfall, and temperature were obtained for less than 2 months (November 2015 to December 2015) and assessed to validate the mathematical model. This study provides a basis for determining PWV by using rainfall and temperature data.

  1. Comparison of Precipitable Water Vapor Observations by GPS, Radiosonde and NWP Simulation

    NASA Astrophysics Data System (ADS)

    Park, Chang-Geun; Baek, Jeongho; Cho, Jungho

    2009-12-01

    Precipitable water vapor (PWV) derived from a numerical weather prediction (NWP) model were compared to observations derived from ground-based Global Positioning System (GPS) receivers. The model data compared were from the Weather Research and Forecasting (WRF) model short-range forecasts on nested grids. The numerical experiments were performed by selecting the cloud microphysics schemes and for the comparisons, the Changma period of 2008 was selected. The observational data were derived from GPS measurements at 9-sites in South Korea over a 1-month period, in the middle of June-July 2008. In general, the WRF model demonstrated considerable skill in reproducing the temporal and spatial evolution of the PWV as depicted by the GPS estimations. The correlation between forecasts and GPS estimates of PWV depreciated slowly with increasing forecast times. Comparing simulations with a resolution of 18 km and 6 km showed no obvious PWV dependence on resolution. Besides, GPS and the model PWV data were found to be in quite good agreement with data derived from radiosondes. These results indicated that the GPS-derived PWV data, with high temporal and spatial resolution, are very useful for meteorological applications.

  2. Long Series of GNSS Integrated Precipitable Water as a Climate Change Indicator

    NASA Astrophysics Data System (ADS)

    Kruczyk, Michał

    2015-12-01

    This paper investigates information potential contained in tropospheric delay product for selected International GNSS Service (IGS) stations in climatologic research. Long time series of daily averaged Integrated Precipitable Water (IPW) can serve as climate indicator. The seasonal model of IPW change has been adjusted to the multi-year series (by the least square method). Author applied two modes: sinusoidal and composite (two or more oscillations). Even simple sinusoidal seasonal model (of daily IPW values series) clearly represents diversity of world climates. Residuals in periods from 10 up to 17 years are searched for some long-term IPW trend - self-evident climate change indicator. Results are ambiguous: for some stations or periods IPW trends are quite clear, the following years (or the other station) not visible. Method of fitting linear trend to IPW series does not influence considerably the value of linear trend. The results are mostly influenced by series length, completeness and data (e.g. meteorological) quality. The longer and more homogenous IPW series, the better chance to estimate the magnitude of climatologic IPW changes.

  3. Real-time retrieval of precipitable water vapor from GPS and BeiDou observations

    NASA Astrophysics Data System (ADS)

    Lu, Cuixian; Li, Xingxing; Nilsson, Tobias; Ning, Tong; Heinkelmann, Robert; Ge, Maorong; Glaser, Susanne; Schuh, Harald

    2015-09-01

    The rapid development of the Chinese BeiDou Navigation Satellite System (BDS) brings a promising prospect for the real-time retrieval of zenith tropospheric delays (ZTD) and precipitable water vapor (PWV), which is of great benefit for supporting the time-critical meteorological applications such as nowcasting or severe weather event monitoring. In this study, we develop a real-time ZTD/PWV processing method based on Global Positioning System (GPS) and BDS observations. The performance of ZTD and PWV derived from BDS observations using real-time precise point positioning (PPP) technique is carefully investigated. The contribution of combining BDS and GPS for ZTD/PWV retrieving is evaluated as well. GPS and BDS observations of a half-year period for 40 globally distributed stations from the International GNSS Service Multi-GNSS Experiment and BeiDou Experiment Tracking Network are processed. The results show that the real-time BDS-only ZTD series agree well with the GPS-only ZTD series in general: the RMS values are about 11-16 mm (about 2-3 mm in PWV). Furthermore, the real-time ZTD derived from GPS-only, BDS-only, and GPS/BDS combined solutions are compared with those derived from the Very Long Baseline Interferometry. The comparisons show that the BDS can contribute to real-time meteorological applications, slightly less accurately than GPS. More accurate and reliable water vapor estimates, about 1.3-1.8 mm in PWV, can be obtained if the BDS observations are combined with the GPS observations in the real-time PPP data processing. The PWV comparisons with radiosondes further confirm the performance of BDS-derived real-time PWV and the benefit of adding BDS to standard GPS processing.

  4. GPS-derived Precipitable Water Vapour in Antarctica and validation with radiosoundings

    NASA Astrophysics Data System (ADS)

    Negusini, M.; Sarti, P.; Tomasi, C.; Petkov, B.

    2012-12-01

    The capability of the GPS in retrieving the precipitable water vapour (PWV) content at low- and mid-latitudes has been amply investigated by several studies. In Polar Regions, beyond the classical positioning application, the use of GPS observations for sensing the atmosphere is of particular interest due to its easy and unmanned operability. It is well known that, in those areas, the atmospheric water vapour content is approximately one third or less than that present at mid latitudes and that on the Antarctic Plateau the PWV drops down to less than a few mm. As a consequence, the use of GPS data in sensing the atmosphere can be reliably applied only on coastal areas, were the PWV is large enough to exceed the sensitivity of the method. Radio-soundings are periodically performed at several coastal Antarctic stations, where permanent GPS equipments are also installed. The co-location of GPS and radio-soundings allows a validation of the PWV derived from the geodetic data. In this investigation we present the results of the analysis of continuous long time series of GPS data acquired at Mawson (MAW1), Casey (CAS1), Davis (DAV1), McMurdo (MCM4) and Mario Zucchelli (TNB1) stations during twelve years spanning 1999-2010. Particularly, at each site, the PWV is determined with GPS data and the same parameter derived from the analysis of the radio-sounding is used for validation. The GPS analysis is optimized for Antarctic data, using specific atmospheric models (e.g. the Vienna Mapping Function) and particular care in the data screening and elimination. The sites to be analyzed were selected according to the radiosonde equipment: the Vaisala sensors' readings were corrected specifically with ad hoc models.

  5. Measurement of Low Amounts of Precipitable Water Vapor Using Ground-Based Millimeterwave Radiometry

    NASA Astrophysics Data System (ADS)

    Racette, Paul E.; Westwater, Ed R.; Han, Yong; Gasiewski, Albin J.; Klein, Marian; Cimini, Domenico; Jones, David C.; Manning, Will; Kim, Edward J.; Wang, James R.; Leuski, Vladimir; Kiedron, Peter

    2005-04-01

    Extremely dry conditions characterized by amounts of precipitable water vapor (PWV) as low as 1-2 mm commonly occur in high-latitude regions during the winter months. While such dry atmospheres carry only a few percent of the latent heat energy compared to tropical atmospheres, the effects of low vapor amounts on the polar radiation budget - both directly through modulation of longwave radiation and indirectly through the formation of clouds - are considerable. Accurate measurements of PWV during such dry conditions are needed to improve polar radiation models for use in understanding and predicting change in the climatically sensitive polar regions. To this end, the strong water-vapor absorption line at 183.310 GHz provides a unique means of measuring low amounts of PWV. Weighting function analysis, forward model calculations based upon a 7-yr radiosonde dataset, and retrieval simulations consistently predict that radiometric measurements made using several millimeter-wavelength (MMW) channels near the 183-GHz line, together with established microwave (MW) measurements near the 22.235-GHz water-vapor line and ∼31-GHz atmospheric absorption window can be used to determine within 5% uncertainty the full range of PWV expected in the Arctic. This combined capability stands in spite of accuracy limitations stemming from uncertainties due to the sensitivity of the vertical distribution of temperature and water vapor at MMW channels. In this study the potential of MMW radiometry using the 183-GHz line for measuring low amounts of PWV is demonstrated both theoretically and experimentally. The study uses data obtained during March 1999 as part of an experiment conducted at the Department of Energy's Cloud and Radiation Testbed (CART) site near Barrow, Alaska. Several radiometers from both NOAA and NASA were deployed during the experiment to provide the first combined MMW and MW ground-based dataset during dry Arctic conditions. Single-channel retrievals of PWV were

  6. Instrumenting Wildlife Water Developments to Measure Precipitation and Estimate Runoff in Remote Catchments

    Technology Transfer Automated Retrieval System (TEKTRAN)

    In Nevada, available data on precipitation and runoff in remote catchments are extremely limited. The National Weather Service’s Cooperative Observer Network (COOP) includes 178 weather stations, most of which collect precipitation data and qualitative weather observations. Most of these stations ar...

  7. Using Wildlife Water Developments to Measure Precipitation and Estimate Runoff in Remote Catchments

    Technology Transfer Automated Retrieval System (TEKTRAN)

    In Nevada, available data on precipitation and runoff in remote catchments is extremely limited. The National Weather Service’s Cooperative Observer Network (COOP) includes 178 weather stations, most of which collect precipitation data and qualitative weather observations. Most of these stations a...

  8. Water and sediment yield response to multi-year precipitation variations in a central Oklahoma watershed

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Persistent, multi-year departures of annual precipitation from long term mean have been observed in various parts of the United States. The Dust Bowl years in the central plains and the recent drought in the West are examples of such persistent departures. Departures in annual precipitation that las...

  9. Calculation of Precipitable Water for Stratospheric Observatory for Infrared Astronomy Aircraft (SOFIA): Airplane in the Night Sky

    NASA Technical Reports Server (NTRS)

    Wen, Pey Chun; Busby, Christopher M.

    2011-01-01

    Stratospheric Observatory for Infrared Astronomy, or SOFIA, is the new generation airborne observatory station based at NASA s Dryden Aircraft Operations Facility, Palmdale, CA, to study the universe. Since the observatory detects infrared energy, water vapor is a concern in the atmosphere due to its known capacity to absorb infrared energy emitted by astronomical objects. Although SOFIA is hoping to fly above 99% of water vapor in the atmosphere it is still possible to affect astronomical observation. Water vapor is one of the toughest parameter to measure in the atmosphere, several atmosphere modeling are used to calculate water vapor loading. The water vapor loading, or Precipitable water, is being calculated by Matlab along the planned flight path. Over time, these results will help SOFIA to plan flights to regions of lower water vapor loading and hopefully improve the imagery collection of these astronomical features.

  10. Summary and statistical analysis of precipitation and groundwater data for Brunswick County, North Carolina, Water Year 2008

    USGS Publications Warehouse

    McSwain, Kristen Bukowski; Strickland, A.G.

    2010-01-01

    Groundwater conditions in Brunswick County, North Carolina, have been monitored continuously since 2000 through the operation and maintenance of groundwater-level observation wells in the surficial, Castle Hayne, and Peedee aquifers of the North Atlantic Coastal Plain aquifer system. Groundwater-resource conditions for the Brunswick County area were evaluated by relating the normal range (25th to 75th percentile) monthly mean groundwater-level and precipitation data for water years 2001 to 2008 to median monthly mean groundwater levels and monthly sum of daily precipitation for water year 2008. Summaries of precipitation and groundwater conditions for the Brunswick County area and hydrographs and statistics of continuous groundwater levels collected during the 2008 water year are presented in this report. Groundwater levels varied by aquifer and geographic location within Brunswick County, but were influenced by drought conditions and groundwater withdrawals. Water levels were normal in two of the eight observation wells and below normal in the remaining six wells. Seasonal Kendall trend analysis performed on more than 9 years of monthly mean groundwater-level data collected in an observation well located within the Brunswick County well field indicated there is a strong downward trend, with water levels declining at a rate of about 2.2 feet per year.

  11. Multilayer Cloud Detection with the MODIS Near-Infrared Water Vapor Absorption Band

    NASA Technical Reports Server (NTRS)

    Wind, Galina; Platnick, Steven; King, Michael D.; Hubanks, Paul A,; Pavolonis, Michael J.; Heidinger, Andrew K.; Yang, Ping; Baum, Bryan A.

    2009-01-01

    Data Collection 5 processing for the Moderate Resolution Imaging Spectroradiometer (MODIS) onboard the NASA Earth Observing System EOS Terra and Aqua spacecraft includes an algorithm for detecting multilayered clouds in daytime. The main objective of this algorithm is to detect multilayered cloud scenes, specifically optically thin ice cloud overlying a lower-level water cloud, that presents difficulties for retrieving cloud effective radius using single layer plane-parallel cloud models. The algorithm uses the MODIS 0.94 micron water vapor band along with CO2 bands to obtain two above-cloud precipitable water retrievals, the difference of which, in conjunction with additional tests, provides a map of where multilayered clouds might potentially exist. The presence of a multilayered cloud results in a large difference in retrievals of above-cloud properties between the CO2 and the 0.94 micron methods. In this paper the MODIS multilayered cloud algorithm is described, results of using the algorithm over example scenes are shown, and global statistics for multilayered clouds as observed by MODIS are discussed. A theoretical study of the algorithm behavior for simulated multilayered clouds is also given. Results are compared to two other comparable passive imager methods. A set of standard cloudy atmospheric profiles developed during the course of this investigation is also presented. The results lead to the conclusion that the MODIS multilayer cloud detection algorithm has some skill in identifying multilayered clouds with different thermodynamic phases

  12. Effect of precipitation change on water balance and WUE of the winter wheat-summer maize rotation in the North China Plain

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Limited precipitation restricts crops yield in the North China Plain, where high levels of production depend largely on irrigation. Establishing the optimal irrigation scheduling according to the crop water requirements (CWR) and precipitation is the key factor to achieve rational water use. Precipi...

  13. NASA-Modified Precipitation Products to Improve EPA Nonpoint Source Water Quality Modeling for the Chesapeake Bay

    NASA Technical Reports Server (NTRS)

    Nigro, Joseph; Toll, David; Partington, Ed; Ni-Meister, Wenge; Lee, Shihyan; Gutierrez-Magness, Angelica; Engman, Ted; Arsenault, Kristi

    2010-01-01

    The Environmental Protection Agency (EPA) has estimated that over 20,000 water bodies within the United States do not meet water quality standards. Ninety percent of the impairments are typically caused by nonpoint sources. One of the regulations in the Clean Water Act of 1972 requires States to monitor the Total Maximum Daily Load (TMDL), or the amount of pollution that can be carried by a water body before it is determined to be "polluted", for any watershed in the U.S.. In response to this mandate, the EPA developed Better Assessment Science Integrating Nonpoint Sources (BASINS) as a Decision Support Tool (DST) for assessing pollution and to guide the decision making process for improving water quality. One of the models in BASINS, the Hydrological Simulation Program -- Fortran (HSPF), computes daily stream flow rates and pollutant concentration at each basin outlet. By design, precipitation and other meteorological data from weather stations serve as standard model input. In practice, these stations may be unable to capture the spatial heterogeneity of precipitation events especially if they are few and far between. An attempt was made to resolve this issue by substituting station data with NASA modified/NOAA precipitation data. Using these data within HSPF, stream flow was calculated for seven watersheds in the Chesapeake Bay Basin during low flow periods, convective storm periods, and annual flows. In almost every case, the modeling performance of HSPF increased when using the NASA-modified precipitation data, resulting in better stream flow statistics and, ultimately, in improved water quality assessment.

  14. Infiltration/ground water linkage in the southwest: Response of shallow ground water to interannual variations of precipitation, Jemez Mountains, New Mexico

    SciTech Connect

    Groffman, A. R.

    2002-01-01

    Hydraulic gradients, residence times and the hydrochemistry of shallow ground water are linked to the episodic precipitation and recharge events characteristic of the arid southwest. In this region, the amount of precipitation, and corresponding biomass, is dependant upon altitude with greater frequency and duration in the montane highlands and less in the desert lowlands. Results from a four-year study at the Rio Calaveras research site in the Jemez Mountains of northern New Mexico show a strong correlation between the physical and hydrochemical properties of shallow ground water and variations of seasonal precipitation and infiltration. For example, the water table shows a dramatic response to snowmelt infiltration during years of abundant snow pack (El Nifio) and diminished response during years of reduced snow pack (La Niiia). The chemical structure of shallow ground water is also affected by the precipitation regime, primarily by variations in the flux of reductants (organic carbon) and oxidants (dissolved oxygen) from the vadose zone to the water table. Generally, oxic conditions persist during spring snowmelt infiltration shifting to anoxic conditions as biotic and abiotic processes transform dissolved oxygen. Other redox-sensitive constituents (ferrous iron, manganese, sulfate, nitrate, and nitrite) show increasing and decreasing concentrations as redox fluctuates seasonally and year-to-year. The cycling of these redox sensitive solutes in the subsurface depends upon the character of the aquifer materials, the biomass at the surface, moisture and temperature regime of the vadose zone, and frequency of infiltration events.

  15. Analyses of extreme precipitation and runoff events including uncertainties and reliability in design and management of urban water infrastructure

    NASA Astrophysics Data System (ADS)

    Hailegeorgis, Teklu T.; Alfredsen, Knut

    2017-01-01

    There is a need for assessment of uncertainties and hence effects on reliability of design and management of stormwater pipes due to the prevalence of urban floods trigged by modification of land cover and high precipitation intensities respectively due to increasing urbanization and changing climate. Observed annual maximum series (AMS) of extreme precipitation intensities of 17 durations (1-min to 1440-min) and runoff records of 27 years from a 21.255 ha (23% impervious, 35% built-up and 41% open areas) Risvollan catchment in Trondheim City were used. Using a balanced bootstrap resampling (BBRS) with frequency analysis, we quantified considerable uncertainty in precipitation and runoff quantiles due to the sampling variability of systematic observations (e.g., -43% to +49% relative differences from the quantile estimates for the original sample). These differences are higher than suggested increase in design rainfall and floods by many countries for climate change adjustment. The uncertainties in IDF curves and derived design storm hyetographs are found to have large effects on the reliability of sizing of stormwater pipes. The study also indicated low validity of the assumptions on extreme precipitation and runoff relationships in the return period-based method for the partially paved urban catchment: (i) maximum of only 46% of the AMS of extreme precipitation and runoff events occurred concurrently and (ii) T-year return period extreme precipitation events do not necessarily result in T-year flood events. These indicate that there are effects of snowmelt seasonality, and probably catchment moisture states and interactions between the flows in subsurface media and pipes. The results substantiate the need for better understanding of relationships between precipitation and runoff extremes and urban runoff generation process, and importance of uncertainty assessment and application of reliability-based methods for design and management of water infrastructure.

  16. Investigation of the Potential for 90Sr Immobilization in INTEC Perched Water via Microbially Facilitated Calcite Precipitation

    SciTech Connect

    Yoshiko Fujita; Karen E. Wright; William A. Smith

    2006-10-01

    The goal of this work is to evaluate the applicability of a biogeochemical sequestration approach for remediation of 90Sr contamination in perched water zones underlying the Idaho Nuclear Technology and Engineering Center (INTEC). The approach is based on the accelerated co-precipitation of the contaminant in calcite, where the acceleration is catalyzed by the microbial urea hydrolysis. We have previously demonstrated the potential for this remediation mechanism to immobilize strontium. Urea hydrolysis promotes calcite precipitation (and trace metal co-precipitation) by increasing groundwater pH and alkalinity. Ureolysis is catalyzed by the urease enzyme, which is produced by many environmental microorganisms. In the Snake River Plain Aquifer, which is saturated with respect to calcite, any co-precipitated 90Sr should be effectively sequestered over the long-term, even after return to pre-manipulation conditions. Another advantage of the ureolysis approach is that the NH4+ ions produced by the reaction can exchange with cations sorbed to subsurface minerals, thereby enhancing the availability of the radionuclides for re-capture via a more stable mechanism (co-precipitation rather than adsorption).

  17. Isotopic equilibrium between precipitation and water vapor: evidence from continental rains in central Kenya

    NASA Astrophysics Data System (ADS)

    Soderberg, K.; Gerlein, C.; Kemeny, P. C.; Caylor, K. K.

    2013-12-01

    An accurate understanding of the relationships between the isotopic composition of liquid water and that of water vapor in the environment can help describe hydrologic processes across many scales. One such relationship is the isotopic equilibrium between falling raindrops and the surrounding vapor. The degree of equilibration is used to model the isotopic composition of precipitation in isotope-enable general circulation models and land-atmosphere exchange models. Although this equilibrium has been a topic of isotope hydrology research for more than four decades, few studies have included vapor measurements to validate modeling efforts. Recent advances in laser technology have allowed for in situ vapor measurements at high temporal resolution (e.g., >1 Hz). Here we present concomitant rain and vapor measurements for a series of 17 rain events during the 'Continental' rainy season (June through August) at Mpala Research Center in central Kenya. Rain samples (n=218) were collected at intervals of 2 to 35 minutes (median of 3 minutes) depending on the rain rate (0.4 to 10.5 mm/hr). The volume-weighted mean rain values for δ18O, δ2H and D-excess (δ2H - 8* δ18O) were 0.1 ‰, 10.7 ‰, and 10.1 ‰. These values are more enriched than the annual weighted means reported for the area (-2.2 ‰, -7.6 ‰, and 11.0 ‰, respectively). Vapor was measured continuously at ~2Hz (DLT-100, Los Gatos Research), with an inverted funnel intake 4m above the ground surface. The mean vapor isotopic composition during the rain events was -10.0 +/- 1.2 ‰ (1 σ) for δ18O and -73.9 +/- 7.0 ‰ for δ2H. The difference between the rain sample isotopic composition and that of liquid in isotopic equilibrium with the corresponding vapor at the ambient temperature was 0.8 +/- 2.2 ‰ for δ18O and 6.2 +/- 7.0 ‰ for δ2H. This disequilibrium was found to correlate with the natural log of rain rate (R2 of 0.26 for δ18O and 0.46 for δ2H), with lower rain rates having larger

  18. GPS-derived Precipitable Water Vapour in Antarctica and validation with radiosoundings

    NASA Astrophysics Data System (ADS)

    Negusini, Monia; Sarti, Pierguido; Tomasi, Claudio; Petkov, Boyan; Capra, Alessandro

    2013-04-01

    In Polar regions, the atmospheric precipitable water vapour (PWV) content is approximately one third or less than that present at mid latitudes. On the Antarctic Plateau, it drops down to less than a few mm. As a consequence, the use of GPS data in sensing the atmosphere can be reliably applied only on coastal areas, were the PWV is large enough to exceed the sensitivity of the method. Radio-soundings (RS) are periodically performed at several coastal Antarctic stations, where permanent GPS equipments are also installed. The sites to be analyzed were selected according to the radiosonde equipment: the Vaisala sensors' readings were corrected specifically with ad hoc models. The co-location of GPS and radio-soundings allows us to validate the PWV content with totally independent techniques. In this investigation we present the results of the analysis of continuous long time series of GPS data acquired at Mawson (MAW1), Casey (CAS1), Davis (DAV1), McMurdo (MCM4) and Mario Zucchelli (TNB1) stations over twelve years (1999-2010). Particularly, at each site, the PWV is determined with GPS data and the same parameter derived from the analysis of the radio-sounding is used for validation. The GPS analysis is optimized for Antarctic data, using specific atmospheric models (e.g. the Vienna Mapping Function) and particular care in the data screening and elimination. The ZHD values are extracted from a grid model provided by the TU Wien (http://ggosatm.hg.tuwien.ac.at/DELAY/GRID) and bilienarly interpolated at the site location. At MZS, surface met parameters are available and used to compute the ZHD which is compared with the corresponding grid-derived ZHD series. We find discrepancies and a seasonal signal that straightforwardly impact the PW time series.

  19. Stable isotope compositions of waters in the Great Basin, United States 3. Comparison of groundwaters with modern precipitation

    USGS Publications Warehouse

    Smith, G.I.; Friedman, I.; Veronda, G.; Johnson, C.A.

    2002-01-01

    Groundwater samples from wells and springs, scattered over most of the Great Basin province, were collected and analyzed for their isotopic makeup. They were augmented by previously published isotopic data on groundwaters from southeast California and by several hundred unpublished isotopic analyses. The ratio of 2H (deuterium, D) to 1H, in water samples from valleys in parts of California, Idaho, Nevada, Oregon, and Utah, are here compared with the winter, summer, and annual isotopic compositions of precipitation falling in or near the sampled areas. The main goal of this study was to identify basins where the groundwaters have isotopic compositions that are "lighter" (depleted in the heavier isotope, D) relative to modern winter precipitation. Where these basins do not adjoin substantially higher terrain, we consider those light groundwaters to be of Pleistocene age and thus more than 10,000 years old. Where the groundwater is 10 to 19??? lighter than local winter precipitation, we consider it to be possibly an indication of Pleistocene water; where the ??D makeup is >20??? lighter, we consider it to be probably Pleistocene water. More than 80 sites underlain by waters of possible or probable Pleistocene age were identified.

  20. Concentration of infectious hematopoietic necrosis virus from water samples by tangential flow filtration and polyethylene glycol precipitation

    USGS Publications Warehouse

    Batts, W.N.; Winton, J.R.

    1989-01-01

    Infectious hematopoietic necrosis virus (IHNV) was concentrated from water samples by polyethylene glycol (PEG) precipitation, tangential flow filtration (TFF), and by a combination of TFF followed by PEG precipitation of the retentate. Used alone, PEG increased virus titers more than 200-fold, and the efficiency of recovery was as great as 100%. Used alone, TFF concentrated IHNV more than 20-fold, and average recovery was 70%. When the two techniques were combined, 10-L water samples were reduced to about 300 mL by TFF and the virus was precipitated with PEG into a 1 to 2 g pellet; total recovery was as great as 100%. The combined techniques were used to isolate IHNV from water samples taken from a river containing adult sockeye salmon (Oncorhynchus nerka) and from a hatchery pond containing adult spring chinook salmon (O. tshawytscha). The combination of these methods was effective in concentrating and detecting IHNV from water containing only three infectious particles per 10-L sample.

  1. Precipitation isotopes link regional climate patterns to water supply in a tropical mountain forest, eastern Puerto Rico

    USGS Publications Warehouse

    Scholl, Martha A.; Murphy, Sheila F.

    2014-01-01

    Like many mountainous areas in the tropics, watersheds in the Luquillo Mountains of eastern Puerto Rico have abundant rainfall and stream discharge and provide much of the water supply for the densely populated metropolitan areas nearby. Projected changes in regional temperature and atmospheric dynamics as a result of global warming suggest that water availability will be affected by changes in rainfall patterns. It is essential to understand the relative importance of different weather systems to water supply to determine how changes in rainfall patterns, interacting with geology and vegetation, will affect the water balance. To help determine the links between climate and water availability, stable isotope signatures of precipitation from different weather systems were established to identify those that are most important in maintaining streamflow and groundwater recharge. Precipitation stable isotope values in the Luquillo Mountains had a large range, from fog/cloud water with δ2H, δ18O values as high as +12 ‰, −0.73 ‰ to tropical storm rain with values as low as −127 ‰, −16.8 ‰. Temporal isotope values exhibit a reverse seasonality from those observed in higher latitude continental watersheds, with higher isotopic values in the winter and lower values in the summer. Despite the higher volume of convective and low-pressure system rainfall, stable isotope analyses indicated that under the current rainfall regime, frequent trade -wind orographic showers contribute much of the groundwater recharge and stream base flow. Analysis of rain events using 20 years of 15 -minute resolution data at a mountain station (643 m) showed an increasing trend in rainfall amount, in agreement with increased precipitable water in the atmosphere, but differing from climate model projections of drying in the region. The mean intensity of rain events also showed an increasing trend. The determination of recharge sources from stable isotope tracers indicates that water

  2. A Feasibility Study for Simultaneous Measurements of Water Vapor and Precipitation Parameters using a Three-frequency Radar

    NASA Technical Reports Server (NTRS)

    Meneghini, R.; Liao, L.; Tian, L.

    2005-01-01

    The radar return powers from a three-frequency radar, with center frequency at 22.235 GHz and upper and lower frequencies chosen with equal water vapor absorption coefficients, can be used to estimate water vapor density and parameters of the precipitation. A linear combination of differential measurements between the center and lower frequencies on one hand and the upper and lower frequencies on the other provide an estimate of differential water vapor absorption. The coupling between the precipitation and water vapor estimates is generally weak but increases with bandwidth and the amount of non-Rayleigh scattering of the hydrometeors. The coupling leads to biases in the estimates of water vapor absorption that are related primarily to the phase state and the median mass diameter of the hydrometeors. For a down-looking radar, path-averaged estimates of water vapor absorption are possible under rain-free as well as raining conditions by using the surface returns at the three frequencies. Simulations of the water vapor attenuation retrieval show that the largest source of error typically arises from the variance in the measured radar return powers. Although the error can be mitigated by a combination of a high pulse repetition frequency, pulse compression, and averaging in range and time, the radar receiver must be stable over the averaging period. For fractional bandwidths of 20% or less, the potential exists for simultaneous measurements at the three frequencies with a single antenna and transceiver, thereby significantly reducing the cost and mass of the system.

  3. Chemistry and isotopic composition of precipitation and surface waters in Khumbu valley (Nepal Himalaya): N dynamics of high elevation basins.

    PubMed

    Balestrini, Raffaella; Polesello, Stefano; Sacchi, Elisa

    2014-07-01

    We monitored the chemical and isotopic compositions of wet depositions, at the Pyramid International Laboratory (5050 ma.s.l.), and surrounding surface waters, in the Khumbu basin, to understand precipitation chemistry and to obtain insights regarding ecosystem responses to atmospheric inputs. The major cations in the precipitation were NH4(+) and Ca(2+), whereas the main anion was HCO3(-), which constituted approximately 69% of the anions, followed by NO3(-), SO4(2-) and Cl(-). Data analysis suggested that Na(+), Cl(-) and K(+) were derived from the long-range transport of marine aerosols. Ca(2+), Mg(2+) and HCO3(-) were related to rock and soil dust contributions and the NO3(-) and SO4(2-) concentrations were derived from anthropogenic sources. Furthermore, NH4(+) was derived from gaseous NH3 scavenging. The isotopic composition of weekly precipitation ranged from -1.9 to -23.2‰ in δ(18)O, and from -0.8 to -174‰ in δ(2)H, with depleted values characterizing the central part of the monsoon period. The chemical composition of the stream water was dominated by calcite and/or gypsum dissolution. However, the isotopic composition of the stream water did not fully reflect the composition of the monsoon precipitation, which suggested that other water sources contributed to the stream flow. Precipitation contents for all ions were the lowest ones among those measured in high elevation sites around the world. During the monsoon periods the depositions were not substantially influenced by anthropogenic inputs, while in pre- and post-monsoon seasons the Himalayas could not represent an effective barrier for airborne pollution. In the late monsoon phase, the increase of ionic contents in precipitation could also be due to a change in the moisture source. The calculated atmospheric N load (0.30 kg ha(-1) y(-1)) was considerably lower than the levels that were measured in other high-altitude environments. Nevertheless, the NO3(-) concentrations in the surface waters

  4. The annual and interannual variabilities of precipitable water, surface wind speed, and sea surface temperature over the tropical Pacific

    NASA Technical Reports Server (NTRS)

    Liu, W. Timothy

    1989-01-01

    The Nimbus-7 Scanning Multichannel Microwave Radiometer (SSMR) provided simultaneous measurements of three geophysical parameters, each of which describing a certain aspect of the evolution of the 1982-1983 ENSO: the sea-surface temperature (T), precipitable water (W), and surface-wind speed (U). In this paper, values derived from the SSMR were compared with in situ measurements from ships, research buoys, and operational island stations in the tropical Pacific between January 1980 and October 1983, demonstrating the temporal and spatial coherence of the SSMR measurements. The results show that the variabilities of the surface convergence, sea surface temperature, and precipitable water are related. It was found that W anomalies were not always colocated with T anomalies, and that W anomalies were often associated with negative U anomalies, interpreted as surface convergence.

  5. Streamflow and selected precipitation data for Yucca Mountain and vicinity, Nye County, Nevada, water years 1983-85

    USGS Publications Warehouse

    Pabst, M.E.; Beck, D.A.; Glancy, P.A.; Johnson, J.A.

    1993-01-01

    Streamflow and precipitation data collected at and near Yucca Mountain, Nevada, during water years 1983-85, are presented. The data were collected and compiled as part of the studies the U.S. Geological Survey is making, in cooperation with the U.S. Department of Energy, to characterize surface water hydrology in the Yucca Mountain area. Streamflow data include daily mean discharges and peak discharges at 4 complete-record gaging stations and peak discharges at 10 crest-stage, partial-record stations and 12 miscellaneous sites. Precipitation data include cumulative totals at 12 stations maintained by the U.S. Geological Survey and daily totals at 17 stations maintained by the Weather Service Nuclear Support Office, National Oceanic and Atmospheric Administration.

  6. Streamflow and Selected Precipitation Data for Yucca Mountain Region, Southern Nevada and Eastern California, Water Years 1986-90

    USGS Publications Warehouse

    Kane, Thomas G.; Bauer, David J.; Martinez, Clair M.

    1994-01-01

    Streamflow and precipitation data collected at and near Yucca Mountain, Nevada, during water years 1986-90 are presented in this report. The data were collected and compiled as part of the studies by the U.S. Geological Survey, in cooperation with the U.S. Department of Energy, to characterize surface-water hydrology in the Yucca Mountain area. Streamflow data include daily-mean discharges and peak discharges at 5 continuous-record gaging stations, and peak discharges at 10 crest-stage, partial-record stations and 2 miscellaneous sites. Precipitation data include cumulative totals at 20 stations maintained by the U.S. Geological Survey and daily totals at 15 stations maintained by the Weather Service Nuclear Support Office, National Oceanic and Atmospheric Administration.

  7. Acid precipitation and drinking water quality in the eastern United States. Final report, November 1981-January 1984

    SciTech Connect

    Taylor, F.; Taylor, J.A.; Symons, G.E.; Collins, J.J.; Schock, M.R.

    1984-01-01

    Research was conducted to provide accurate modern and historical data on drinking water quality and the possible effect of acid precipitation on water samples. Samples of source raw and finished water were collected from more than 300 surface and groundwater supplies in the New England States, New York, New Jersey, Pennsylvania, West Virginia, Virginia, and North Carolina. The samples were analyzed at EPA laboratories. Historical records were obtained dating back to 1886. Acid rain may dissolve harmful elements from soils and from water supply distribution systems. Because soils can alter the character of acid rain through buffering, causal relationships are difficult to identify. A helpful approach to this problem is the use of indices of water supply sensitiviy and corrosiveness. With these indices, drinking water standards, and reliable chemical data, an assessment of water supply characteristics has been accomplished. Though solution products of acid rain in the water supply sources studied do not exceed EPA Primary Drinking Water Regulations, a large number of tests for aluminum showed levels that could be of concern to kidney dialysis patients. Because of the present water quality conditions (low alkalinity and pH) at numerous water sources, future acid deposition could be expected to have a detrimental effect on water quality. 42 references, 15 figures, 42 tables.

  8. An assessment of two automated snow water equivalent instruments during the WMO Solid Precipitation Intercomparison Experiment

    NASA Astrophysics Data System (ADS)

    Smith, Craig D.; Kontu, Anna; Laffin, Richard; Pomeroy, John W.

    2017-01-01

    During the World Meteorological Organization (WMO) Solid Precipitation Intercomparison Experiment (SPICE), automated measurements of snow water equivalent (SWE) were made at the Sodankylä (Finland), Weissfluhjoch (Switzerland) and Caribou Creek (Canada) SPICE sites during the northern hemispheric winters of 2013/14 and 2014/15. Supplementary intercomparison measurements were made at Fortress Mountain (Kananaskis, Canada) during the 2013/14 winter. The objectives of this analysis are to compare automated SWE measurements with a reference, comment on their performance and, where possible, to make recommendations on how to best use the instruments and interpret their measurements. Sodankylä, Caribou Creek and Fortress Mountain hosted a Campbell Scientific CS725 passive gamma radiation SWE sensor. Sodankylä and Weissfluhjoch hosted a Sommer Messtechnik SSG1000 snow scale. The CS725 operating principle is based on measuring the attenuation of soil emitted gamma radiation by the snowpack and relating the attenuation to SWE. The SSG1000 measures the mass of the overlying snowpack directly by using a weighing platform and load cell. Manual SWE measurements were obtained at the intercomparison sites on a bi-weekly basis over the accumulation-ablation periods using bulk density samplers. These manual measurements are considered to be the reference for the intercomparison. Results from Sodankylä and Caribou Creek showed that the CS725 generally overestimates SWE as compared to manual measurements by roughly 30-35 % with correlations (r2) as high as 0.99 for Sodankylä and 0.90 for Caribou Creek. The RMSE varied from 30 to 43 mm water equivalent (mm w.e.) and from 18 to 25 mm w.e. at Sodankylä and Caribou Creek, which had respective SWE maximums of approximately 200 and 120 mm w.e. The correlation at Fortress Mountain was 0.94 (RMSE of 48 mm w.e. with a maximum SWE of approximately 650 mm w.e.) with no systematic overestimation. The SSG1000 snow scale, having a different

  9. Exploring the influence of precipitation extremes and human water use on total water storage (TWS) changes in the Ganges-Brahmaputra-Meghna River Basin

    NASA Astrophysics Data System (ADS)

    Khandu; Forootan, Ehsan; Schumacher, Maike; Awange, Joseph L.; Müller Schmied, Hannes

    2016-03-01

    Climate extremes such as droughts and intense rainfall events are expected to strongly influence global/regional water resources in addition to the growing demands for freshwater. This study examines the impacts of precipitation extremes and human water usage on total water storage (TWS) over the Ganges-Brahmaputra-Meghna (GBM) River Basin in South Asia. Monthly TWS changes derived from the Gravity Recovery And Climate Experiment (GRACE) (2002-2014) and soil moisture from three reanalyses (1979-2014) are used to estimate new extreme indices. These indices are applied in conjunction with standardized precipitation indices (SPI) to explore the impacts of precipitation extremes on TWS in the region. The results indicate that although long-term precipitation do not indicate any significant trends over the two subbasins (Ganges and Brahmaputra-Meghna), there is significant decline in rainfall (9.0 ± 4.0 mm/decade) over the Brahmaputra-Meghna River Basin from 1998 to 2014. Both river basins exhibit a rapid decline of TWS from 2002 to 2014 (Ganges: 12.2 ± 3.4 km3/yr and Brahmaputra-Meghna: 9.1 ± 2.7 km3/yr). While the Ganges River Basin has been regaining TWS (5.4 ± 2.2 km3/yr) from 2010 onward, the Brahmaputra-Meghna River Basin exhibits a further decline (13.0 ± 3.2 km3/yr) in TWS from 2011 onward. The impact of human water consumption on TWS appears to be considerably higher in Ganges compared to Brahmaputra-Meghna, where it is mainly concentrated over Bangladesh. The interannual water storage dynamics are found to be strongly associated with meteorological forcing data such as precipitation. In particular, extreme drought conditions, such as those of 2006 and 2009, had profound negative impacts on the TWS, where groundwater resources are already being unsustainably exploited.

  10. Stable isotopes in monsoon precipitation and water vapour in Nagqu, Tibet, and their implications for monsoon moisture

    NASA Astrophysics Data System (ADS)

    He, Siyuan; Richards, Keith

    2016-09-01

    Understanding climate variations over the Qinghai-Tibetan plateau has become essential because the high plateau sustains various ecosystems and water sources, and impacts on the Asian monsoon system. This paper provides new information from isotopic signals in meteoric water and atmospheric water vapour on the Qinghai-Tibetan Plateau using high frequency observation data over a relatively short period. The aim is to explore temporal moisture changes and annual variations at the onset and during the summer monsoon season at a transitional site with respect to the monsoon influence. Data show that high frequency and short period observations can reveal typical moisture changes from the pre-monsoon to the monsoon seasons (2010), and the large variation in isotopic signals in different years with respect to active/inactive periods during a mature phase of the monsoon (2011), especially inferring from the temporal changes in the d-excess of precipitation and its relationship with δ18O values, when higher d-excess is found in the pre-monsoon precipitation. In this transition zone on a daily basis, δ18O values in precipitation are controlled mainly by the amount of rainfall during the monsoon season, while temperature seems more important before the onset of monsoon. Furthermore, the ;amount effect; is significant for night-time rain events. From comparison of signals in both the precipitation and water vapour, an inconsistent relationship between d-excess values suggests various moisture fluxes are active in a short period. The temporal pattern of isotopic signal change from the onset of the monsoon to the mature monsoon phase provides information about the larger circulation dynamics of the Asian monsoon.

  11. Precipitation-runoff processes in the Feather River basin, northeastern California, and streamflow predictability, water years 1971-97

    USGS Publications Warehouse

    Koczot, Kathryn M.; Jeton, Anne E.; McGurk, Bruce; Dettinger, Michael D.

    2005-01-01

    Precipitation-runoff processes in the Feather River Basin of northern California determine short- and long-term streamflow variations that are of considerable local, State, and Federal concern. The river is an important source of water and power for the region. The basin forms the headwaters of the California State Water Project. Lake Oroville, at the outlet of the basin, plays an important role in flood management, water quality, and the health of fisheries as far downstream as the Sacramento-San Joaquin Delta. Existing models of the river simulate streamflow in hourly, daily, weekly, and seasonal time steps, but cannot adequately describe responses to climate and land-use variations in the basin. New spatially detailed precipitation-runoff models of the basin have been developed to simulate responses to climate and land-use variations at a higher spatial resolution than was available previously. This report characterizes daily rainfall, snowpack evolution, runoff, water and energy balances, and streamflow variations from, and within, the basin above Lake Oroville. The new model's ability to predict streamflow is assessed. The Feather River Basin sits astride geologic, topographic, and climatic divides that establish a hydrologic character that is relatively unusual among the basins of the Sierra Nevada. It straddles a north-south geologic transition in the Sierra Nevada between the granitic bedrock that underlies and forms most of the central and southern Sierra Nevada and volcanic bedrock that underlies the northernmost parts of the range (and basin). Because volcanic bedrock generally is more permeable than granitic, the northern, volcanic parts of the basin contribute larger fractions of ground-water flow to streams than do the southern, granitic parts of the basin. The Sierra Nevada topographic divide forms a high altitude ridgeline running northwest to southeast through the middle of the basin. The topography east of this ridgeline is more like the rain

  12. Effect of some organic solvent-water mixtures composition on precipitated calcium carbonate in carbonation process

    NASA Astrophysics Data System (ADS)

    Konopacka-Łyskawa, Donata; Kościelska, Barbara; Karczewski, Jakub

    2015-05-01

    Precipitated calcium carbonate particles were obtained during carbonation of calcium hydroxide slurry with carbon dioxide. Aqueous solutions of isopropyl alcohol, n-butanol and glycerol were used as solvents. Concentration of organic additives in the reactive mixture was from 0% to 20% (vol). Precipitation process were performed in a stirred tank reactor equipped with gas distributor. Multimodal courses of particles size distribution were determined for produced CaCO3 particles. Calcium carbonate as calcite was precipitated in all experiments. The mean Sauter diameter of CaCO3 particles decreased when the concentration of all used organic additives increased. The amount of small particle fraction in the product increased with the increasing concentration of organic solvents. Similar physical properties of used liquid phase resulted in the similar characteristics of obtained particles.

  13. Temporal trends in the acidity of precipitation and surface waters of New York

    USGS Publications Warehouse

    Peters, Norman E.; Schroeder, Roy A.; Troutman, David E.

    1982-01-01

    Statistical analyses of precipitation data from a nine-station monitoring network indicate little change in pH from 1965-78 within New York State as a whole but suggest that pH of bulk precipitation has decreased in the western part of the State by approximately 0.2 pH units since 1965 and increased in the eastern part by a similar amount. This trend is equivalent to an annual change in hydrogen-ion concentration of 0.2 microequivalents per liter. An average annual increase in precipitation quantity of 2 to 3 percent since 1965 has resulted in an increased acid load in the western and central parts of the State. During 1965-78, sulfate concentration in precipitation decreased an average of 1-4 percent annually. In general, no trend in nitrate was detected. Calculated trends in hydrogen-ion concentration do not correlate with measured trends of sulfate and nitrate, which suggests variable neutralization of hydrogen ion, possibly by particles from dry deposition. Neutralization has produced an increase of about 0.3 pH units in nonurban areas and 0.7 pH units in urban areas. Statistical analyses of chemical data from several streams throughout New York suggest that sulfate concentrations decreased an average of 1 to 4 percent per year. This decrease is comparable to the sulfate decrease in precipitation during the same period. In most areas of the State, chemical contributions from urbanization and farming, as well as the neutralizing effect of carbonate soils, conceal whatever effects acid precipitation may have on pH of streams.

  14. Effects of landuse and precipitation on pesticides and water quality in playa lakes of the southern high plains.

    PubMed

    Anderson, Todd A; Salice, Christopher J; Erickson, Richard A; McMurry, Scott T; Cox, Stephen B; Smith, Loren M

    2013-06-01

    The 25000 playa wetlands within the Southern High Plains (SHP) of the United States of America (USA) are the dominant hydrogeomorphic feature in the region, providing habitat for numerous plants and wildlife. The SHP are among the most intensively cultivated regions; there are concerns over the degradation and/or loss of playa wetland habitat. We examined water quality in playa wetlands surrounded by both grassland and agriculture and measured water concentrations of pesticides used on cotton (acephate, trifluralin, malathion, pendimethalin, tribufos, bifenthrin, λ-cyhalothrin, acetamiprid, and thiamethoxam), the dominant crop in the SHP. Pesticides used on cotton were detected in water samples collected from all playas. Precipitation events and the amount of cultivation were related to pesticide concentrations in sediment and water. Our results show that pesticide concentrations were related in some circumstances to time, precipitation, and tilled-index for some but not all pesticides. We further compared measured pesticide concentrations in playas to toxicity benchmarks used by the US EPA in pesticide ecological risk assessments to obtain some insight into the potential for ecological effects. For all pesticides in water, the maximum measured concentrations exceeded at least one toxicity benchmark, while median concentrations did not exceed any benchmarks. This analysis indicates that there is a potential for adverse effects of pesticides to aquatic organisms.

  15. Water chemistry impacts on arsenic mobilization from arsenopyrite dissolution and secondary mineral precipitation: implications for managed aquifer recharge.

    PubMed

    Neil, Chelsea W; Yang, Y Jeffrey; Schupp, Don; Jun, Young-Shin

    2014-04-15

    Managed aquifer recharge (MAR) is a water reuse technique with the potential to meet growing water demands. However, MAR sites have encountered arsenic mobilization resulting from recharge operations. To combat this challenge, it is imperative to identify the mechanisms of arsenic mobilization during MAR. In this bench-scale study, arsenic mobilization from arsenopyrite (FeAsS) was characterized for conditions relevant to MAR operations. Experimentally determined activation energies for arsenic mobilization from FeAsS under aerobic conditions were 36.9 ± 2.3 kJ/mol for 10 mM sodium chloride, 40.8 ± 3.5 kJ/mol for 10 mM sodium nitrate, and 43.6 ± 5.0 kJ/mol for secondary effluent from a wastewater treatment plant. Interestingly, the sodium chloride system showed higher arsenic mobilization under aerobic conditions. In addition, secondary mineral precipitation varied among systems and further affected arsenic mobilization. For example, the wastewater system inhibited precipitation, while in the sodium chloride system, faster phase transformation of iron(III) (hydr)oxide precipitates was observed, resulting in hematite formation after 7 days. The phase transformation to hematite will result in less available surface area for arsenic attenuation. These new observations and activation energies can be useful to develop improved reactive transport models for the fate of arsenic during MAR, and develop strategies to minimize arsenic release.

  16. Intraspecific variation in precipitation responses of a widespread C4 grass depends on site water limitation

    Technology Transfer Automated Retrieval System (TEKTRAN)

    1. Changes in precipitation expected with climate change have important implications for plant growth and fitness, as well as species genetic diversity and ecological distributions. Intraspecific variation in phenotypic plasticity – the ability of a genotype to alter its phenotype in response to e...

  17. Characterization of iron and manganese precipitates from an in situ ground water treatment plant.

    PubMed

    Mettler, S; Abdelmoula, M; Hoehn, E; Schoenenberger, R; Weidler, P; von Gunten, U

    2001-01-01

    Aquifer samples from the precipitation zone of an in situ iron and manganese removal plant that was operated for 10 years were analyzed for iron and manganese minerals. Measurements were performed by various chemical extraction techniques (5 M HCI, 0.008 M Ti(III)-EDTA, 0.114 M ascorbic acid), X-ray diffraction and Mössbauer spectroscopy. Chemical extractions showed that iron was precipitated as ferric oxides, whereas manganese was not oxidized but deposited as Mn(II) probably within carbonates. The ferric oxides in particular accumulate preferentially in the smaller grain- size fractions. This tendency was observed to a lesser extent for manganese. X-ray diffraction and Mössbauer spectroscopy showed that the ferric oxides were mainly crystalline (goethite, 50% to 100% of the iron). Ferrihydrite was found as well, but only as a minor fraction (< or = 12%). Pure manganese minerals were not found by X-ray diffraction. The precipitated amounts of iron (5 to 27 micromol/g Fe as ferric oxide) and manganese (1 to 4 micromol/g Mn) during 10 years operation of the treatment plant agree with values that were estimated from operational parameters (9 to 31 micromol/g Fe and 3 to 6 micromol/g Mn). Considering the small amounts of precipitated iron and manganese, no long-term risks of clogging of the aquifer are expected.

  18. Influence of the North Atlantic Oscillation on water resources in central Iberia: Precipitation, streamflow anomalies, and reservoir management strategies

    NASA Astrophysics Data System (ADS)

    López-Moreno, Juan I.; BegueríA, Santiago; Vicente-Serrano, Sergio M.; GarcíA-Ruiz, José M.

    2007-09-01

    This paper analyzes the influence of the extreme phases of the winter North Atlantic Oscillation (NAO) on water resources in the Spanish region of the Tagus River basin. By analyzing a winter NAO index based on station sea level pressure, the years between 1957 and 2003 were classified as normal, positive, and negative NAO years. A statistical test was then applied to monthly data series of precipitation, river discharge, reservoir storage, and reservoir release to analyze the variations in these variables. For all four variables, significant differences were found between positive and negative NAO years, the former resulting in reduced water availability (negative anomalies) and the latter resulting in increased water availability (positive anomalies). The influence of extreme NAO winters was found to act with different time lags on different variables: The effect of extreme NAO winters on precipitation was found to be quite immediate (and significant for December to March), but this effect was observed later in the year and lasted longer for river discharge, reservoir storage, and water release. Positive and negative NAO years were also found to have different effects on these variables, in that the effects of positive years were more sustained and those of negative years were more rapid and less prolonged. In spite of the high variability of the availability of water resources, the strategies for management of the reservoir system of the basin were found in most cases to provide a regular supply that meets water demands. However, our results also indicate that these water management practices are not adequate for the expected scenarios of climate change and increasing water demand.

  19. Flow patterns of precipitation and soil water beneath forest canopies: An experimental approach to assessing water flow heterogeneity with high resolution measurements.

    NASA Astrophysics Data System (ADS)

    Metzger, Johanna Clara; Dalla Valle, Nicolas; Wutzler, Thomas; Filipzik, Janett; Grauer, Christoph; Schelhorn, Danny; Weckmüller, Josef; Hildebrandt, Anke

    2015-04-01

    Due to the mechanisms of interception, stemflow and canopy throughfall, precipitation reaches a forest soil surface in an altered temporal and spatial distribution. It is characterized by a strong heterogeneity. The retention of water by canopies is contrasted by the formation of dynamic hotspots, which channel rain water down to the soil: canopy dripping points and stemflow. This poster introduces a new experimental site established within the collaborative research center of AquaDiva, where we aim to investigate the flow paths of water from the top of the canopy through the soil below the main rooting zone in an intensive field study. The study site, sized one hectare, is located in Thuringia in an unmanaged Central European beech forest on limestone, and complemented by measurements in an adjacent grassland site. A soil moisture sensor network (SoilNet) has been established for monitoring soil water content at high temporal (3 min interval) and spatial (420 sensors per ha) resolution. During field campaigns in spring and early summer, the spatial distribution of net precipitation is measured. Vegetation properties and soil physical and scientific characteristics have been surveyed. Using this setup, we plan to determine, whether and during which conditions spatial patterns of net precipitation persist in soil moisture and fluxes. Using the high-resolution soil water content data we aim to discover flow dynamics and thus identify preferential flow paths in the soil. Geostatistical analysis will yield information about spatial distribution and the relationship of above- and subsurface flow patterns and impact factors. In this poster we will present first results of net precipitation composition and statistical characteristics of throughfall and soil moisture data.

  20. Controls on oxygen isotope variability in precipitation and drip water at eight caves in the monsoon regions of China

    NASA Astrophysics Data System (ADS)

    Duan, Wuhui; Ruan, Jiaoyang; Luo, Weijun; Li, Tingyong; Tian, Lijun; Zeng, Guangneng; Zhang, Dezhong; Bai, Yijun; Li, Jilong; Tao, Tao; Zhang, Pingzhong; Tan, Ming

    2015-04-01

    Cave monitoring is important to fully understand the climatic significance of stalagmite δ18O records. Most previous studies focus on one cave, or several caves in one area. A large regional-scale investigation on the isotopic composition of precipitation and drip water is scarce. To investigate the regional-scale climate forcing on the oxygen isotopic composition of precipitation in the monsoon regions of China (MRC) and how the isotopic signals are transmitted to various drip sites, a three-year-long (2011-2014) on-site rainfall and drip water monitoring program has been carried out with approximately monthly sampling at 37 drip sites in eight caves in the MRC. Neither rainfall amount nor air temperature are the predominant controls on the oxygen isotopic composition of monthly precipitation. The rain in the wet season (May to October), with relatively low δ18O values, is sourced from tropical air masses, whereas the rainfall in the dry season (November to April), with relatively high δ18O values, is mostly sourced from continental air masses. Additionally, the weighted summer rainwater δ18O values decrease from coastal southwest China to inland northeast China, which suggests that the moisture of monsoon rainfall in China originates mainly from Indian Ocean, and transports to the north along the southwest-northeast path. 28 of the 37 drip sites are constant drips with little discernable variation in drip water δ18O through the whole study period. For most of the constant drips, the mean value of each drip water δ18O is nearly identical to or slightly higher than the three-year weighted mean value of the corresponding local rainwater δ18O, indicating these drips may be mainly recharged by none-evaporated or slightly evaporated, well-mixed older water stored in the vadose zone. 7 of all the 37 drip sites are seasonal drips, for which, although the amplitude of drip water δ18O is narrower than that of rainfall, the monthly response of drip water δ18O to

  1. Time series study of concentrations of SO4(2-) and H+ in precipitation and soil waters in Norway.

    PubMed

    Kvaalen, H; Solberg, S; Clarke, N; Torp, T; Aamlid, D

    2002-01-01

    Along with a steady reduction of acid inputs during 14 years of intensive forest monitoring in Norway, the influence of acid deposition upon soil water acidity is gradually reduced in favour of other and internal sources of H+ and sulphate, in particular from processes in the upper soil layer. We used statistical analyses in two steps for precipitation, throughfall and soil water at 5, 15 and 40 cm depths. Firstly, we employed time series analyses to model the temporal variation as a long-term linear trend and a monthly variation, and by this filtered out residual, weekly variation. Secondly, we used the parameter estimates and the residuals from this to show that the long term, the monthly and the weekly variation in one layer were correlated to similar temporal variation in the above, adjacent layer. This was strongly evident for throughfall correlated to precipitation, but much weaker for soil water. Continued acidification in soil water on many plots suggests that the combined effects of anthropogenic and natural acid inputs exceed in places the buffering capacity of the soil.

  2. Runoff water quality from broiler litter-amended tall fescue in response to natural precipitation in the Ozark Highlands.

    PubMed

    Menjoulet, B C; Brye, K R; Pirani, A L; Haggard, B E; Gbur, E E

    2009-01-01

    The Arkansas poultry industry produced more than 1.2 billion broiler chickens (Gallus gallus domesticus) and generated approximately 1.3 million Mg of broiler litter in 2002. High transportation costs of relocating broiler litter have led to annual land applications near poultry houses, increasing concern for potential surface water contamination from runoff. The objective of this study was to evaluate the effect of broiler litter application rate on runoff water quality in response to natural precipitation. Six plots (1.5 by 6.0 m), located on a Captina silt loam (finesilty, siliceous, active, mesic Typic Fragiudult), were amended with fresh broiler litter at 0, 5.6, and 11.2 Mg ha(-1) (control, low, and high litter treatments, respectively) once annually for 4 yr (May 2003 through April 2007). Runoff collected after each runoff-producing event was analyzed for soluble nutrients and metals. Cumulative runoff did not differ among litter treatments over the 4-yr study. At times, flow-weighted mean (FWM) concentrations of As from all litter treatments exceeded the maximum contaminant level for drinking water (0.01 mg As L(-1)). Four-year FWM Fe concentrations and runoff losses were greater (P < 0.05) from the high than from the low litter treatment and unamended control, and the 4-yr FWM P concentration from the low litter treatment (3.0 mg L(-1)) was greater than that from the unamended control (1.8 mg L(-1)). Since precipitation is temporally variable, evaluating runoff water quality in response to natural precipitation over several years is key to ascertaining the long-term impacts of surface-applied soil amendments like broiler litter.

  3. Precipitation Climate Data Records

    NASA Astrophysics Data System (ADS)

    Nelson, B. R.; Prat, O.; Vasquez, L.

    2015-12-01

    Five precipitation CDRs are now or soon will be transitioned to NOAA's CDR program. These include the PERSIANN data set, which is a 30-year record of daily adjusted global precipitation based on retrievals from satellite microwave data using artificial neural networks. The AMSU-A/B/Hydrobundle is an 11-year record of precipitable water, cloud water, ice water, and other variables. CMORPH (the NOAA Climate Prediction Center Morphing Technique) is a 17-year record of daily and sub-daily adjusted global precipitation measured from passive microwave and infrared data at high spatial and temporal resolution. GPCP (the Global Precipitation Climatology Project) is an approximately 30-year record of monthly and pentad adjusted global precipitation and a 17-year record of daily adjusted global precipitation. The NEXRAD Reanalysis is a 10-year record of high resolution NEXRAD radar based adjusted CONUS-wide hourly and daily precipitation. This study provides an assessment of the existing and transitioned long term precipitation CDRs and includes the verification of the five precipitation CDRs using various methods including comparison with in-situ data sets and trend analysis. As all of the precipitation related CDRs are transitioned, long term analyses can be performed. Comparisons at varying scales (hourly, daily and longer) of the precipitation CDRs with in-situ data sets are provided as well as a first look at what could be an ensemble long term precipitation data record.

  4. An assessment of the isotopic (2H/18O) integrity of water samples collected and stored by unattended precipitation totalizers

    NASA Astrophysics Data System (ADS)

    Terzer, Stefan; Wassenaar, Leonard I.; Douence, Cedric; Araguas-Araguas, Luis

    2016-04-01

    The IAEA-WMO Global Network of Isotopes in Precipitation (GNIP) provides worldwide δ18O and δ2H data for numerous hydrological and climatological studies. The traditional GNIP sample collection method relies on weather station operators to accumulate precipitation obtained from manual rain gauges. Over the past decades, widespread weather station automatization resulted in the increased use of unattended precipitation totalizers that accumulate and store the rainwater in the field for up to one month. Several low-tech measures were adopted to prevent in situ secondary evaporative isotopic enrichment (SEE) of totalized water samples (i.e. disequilibrium isotopic fractionation after precipitation is stored in the collection device). These include: (a) adding a 0.5-1 cm floating layer of paraffin oil to the totalizer bottle, (b) using an intake tube leading from the collection funnel and submerged to the bottom of the totalizer bottle, or (c) placing a table tennis ball in the funnel aiming to reduce evaporation of the collected water from the receiving bottle to the atmosphere. We assessed the isotopic integrity of stored rainwater samples for three totalizers under controlled settings: each aforementioned totalizer was filled with a 100 or 500 mL of isotopically known water and installed in the field with the intake funnels sheltered to prevent rainwater collection. Potential evapotranspiration (PET) was obtained from on-site meteorological recordings. Stored evaporative loss from each totalizer was evaluated on a monthly basis; gravimetrically and by analysing δ18O and δ2H of the stored water, for a period of 6 months and a cumulative PET of ˜500 mm. The gravimetric and isotope results revealed that for smaller water volumes (100 ml, corresponding to ca. 5 mm of monthly precipitation), negligible isotope enrichment (δ18O) was observed in the paraffin-oil based totalizer, whereas unacceptable evaporative isotope effects were observed for the ball

  5. Stable isotope study of precipitation and cave drip water in Florida (USA): implications for speleothem-based paleoclimate studies.

    PubMed

    Onac, Bogdan P; Pace-Graczyk, Kali; Atudirei, Viorel

    2008-06-01

    Stable isotopes of hydrogen and oxygen were used to examine how the isotopic signal of meteoric water is modified as it travels through soil and epikarst into two caves in Florida. Surface and cave water samples were collected every week from February 2006 until March 2007. The isotopic composition of precipitation at the investigated sites is highly variable and shows little seasonal control. The delta18O vs. delta2H plot shows a mixing line having a slope of 5.63, suggesting evaporation effects dominate the isotopic composition of most rainfall events of less than 8 cm/day, as indicated by their low d-excess values. The delta18O values of the drip water show little variability (<0.6 per thousand), which is loosely tied to local variations in the seasonal amount of precipitation. This is only seen during wintertime at the Florida Caverns site. The lag time of over two months and the lack of any relationship between rainfall amount and the increase in drip rate indicate a dominance of matrix flow relative to fracture/conduit flow at each site. The long residence time of the vadose seepage waters allows for an effective isotopic homogenisation of individual and seasonal rainfall events. We find no correlation between rainfall and drip water delta18O at any site. The isotopic composition of drip water in both caves consistently tends to resemble the amount-weighted monthly mean rainfall input. This implies that the delta18O of speleothems from these two caves in Florida cannot record seasonal cycle in rainfall delta18O, but are suitable for paleoclimate reconstructions at inter-annual time scales.dagger.

  6. MWRRET Value-Added Product: The Retrieval of Liquid Water Path and Precipitable Water Vapor from Microwave Radiometer (MWR) Data Sets (Revision 2)

    SciTech Connect

    Gaustad, KL; Turner, DD; McFarlane, SA

    2011-07-25

    This report provides a short description of the Atmospheric Radiation Measurement (ARM) Climate Research Facility microwave radiometer (MWR) Retrieval (MWRRET) value-added product (VAP) algorithm. This algorithm utilizes a complementary physical retrieval method and applies brightness temperature offsets to reduce spurious liquid water path (LWP) bias in clear skies resulting in significantly improved precipitable water vapor (PWV) and LWP retrievals. We present a general overview of the technique, input parameters, output products, and describe data quality checks. A more complete discussion of the theory and results is given in Turner et al. (2007b).

  7. Effects of nitrate and water on the oxygen isotopic analysis of barium sulfate precipitated from solution

    USGS Publications Warehouse

    Hannon, Janet E.; Bohlke, Johnkarl F.; Mroczkowski, Stanley J.

    2008-01-01

    BaSO4 precipitated from mixed salt solutions by common techniques for SO isotopic analysis may contain quantities of H2O and NOthat introduce errors in O isotope measurements. Experiments with synthetic solutions indicate that δ18O values of CO produced by decomposition of precipitated BaSO4 in a carbon reactor may be either too low or too high, depending on the relative concentrations of SO and NO and the δ18O values of the H2O, NO, and SO. Typical δ18O errors are of the order of 0.5 to 1‰ in many sample types, and can be larger in samples containing atmospheric NO, which can cause similar errors in δ17O and Δ17O. These errors can be reduced by (1) ion chromatographic separation of SO from NO, (2) increasing the salinity of the solutions before precipitating BaSO4 to minimize incorporation of H2O, (3) heating BaSO4 under vacuum to remove H2O, (4) preparing isotopic reference materials as aqueous samples to mimic the conditions of the samples, and (5) adjusting measured δ18O values based on amounts and isotopic compositions of coexisting H2O and NO. These procedures are demonstrated for SO isotopic reference materials, synthetic solutions with isotopically known reagents, atmospheric deposition from Shenandoah National Park, Virginia, USA, and sulfate salt deposits from the Atacama Desert, Chile, and Mojave Desert, California, USA. These results have implications for the calibration and use of O isotope data in studies of SOsources and reaction mechanisms.

  8. Origin and Migration of the Pollutants in Precipitation and Surface Water in Seoul, Korea

    NASA Astrophysics Data System (ADS)

    Lee, I.; Lim, C.; Yu, J.

    2002-12-01

    Variations in abundance of stable isotopes of sulfur, hydrogen, and oxygen are studied on snow and rainwater samples from Seoul area. Their suitability as a tool for characterizing the seasonality and source of regions near Korea, which contribute to the pollution in Seoul Area was investigated. Also stable isotopic and chemical evidence has been used to trace the sources of sulfate in precipitation at study area and to distinguish sulfate between natural and anthropogenic origins. The contribution of different sources to a specific receptor site depends on emission patterns and meteorological conditions. Measured isotope ratios reflect the actual superposition of the distinct source types based on the assumption that no major isotope fractionation occurs during the transportation process between source region and sampling site. The sulfur isotopic composition of sulfate (δ34S) in precipitation decreased during spring and summer. The δ34S values ranged from +4.4 to +6.5› (mean +5.9›) in winter and from +3.7 to 4.8› (mean +4.3›) in summer. Furthermore, the isotope ratios of hydrogen and oxygen in the snow and rainwater samples were used to support the meteorological information. The δ34S value of the sulfate in precipitation shows characteristic patterns of seasonal variation in the present research. Seasonal variations of the δ34S values and their relation to chemical composition of the atmospheric pollutants are discussed taking into account the δ34S values of sulfur originating from sea salt, oil and coal combustion, and biogenic activity. Also, the δ34S values of sulfate in the atmospheric pollutants show a remarkable seasonal variation depending on the wind directions. The relationship between wind direction and seasonal variation can be explained by contribution of sulfur from coal combustion in northern China and southern China.

  9. The effects of acid precipitation runoff episodes on reservoir and tapwater quality in an Appalachian Mountain water supply.

    PubMed Central

    Sharpe, W E; DeWalle, D R

    1990-01-01

    The aluminum concentration and Ryznar Index increased and the pH decreased in a small Appalachian water supply reservoir following acid precipitation runoff episodes. Concomitant increases in tapwater aluminum and decreases in tapwater pH were also observed at two homes in the water distribution system. Lead concentrations in the tapwater of one home frequently exceeded recommended levels, although spatial and temporal variation in tapwater copper and lead concentrations was considerable. Since source water and reservoir water copper and lead concentrations were much lower, the increased copper and lead concentrations in tapwater were attributed to corrosion of household plumbing. Tapwater copper concentration correlated well with tapwater pH and tapwater temperature. Asbestos fibers were not detected in tapwater. The asbestos-cement pipe in the water distribution system was protected by a spontaneous metallic coating that inhibited fiber release from the pipe. Several simultaneous reactions were hypothesized to be taking place in the distribution system that involved corrosion of metallic components and coating of asbestos-cement pipe components in part with corrosion products and in part by cations of watershed origin. Greater water quality changes might be expected in areas of higher atmospheric deposition. Images FIGURE 5. FIGURE 6. PMID:2088742

  10. A Rapid Protoyping Approach for the Evaluation of Potential GPM-Era Precipitation Products for Water Resources Management Applications

    NASA Astrophysics Data System (ADS)

    Anantharaj, V. G.; Houser, P. R.; Turk, F. J.; Peterson, C. A.; Hossain, F.; Moorhead, R. J.; Toll, D. L.; Mostovoy, G.

    2009-04-01

    societal benefits related to human health (soil moisture, climate and disease outbreak), homeland security (removal of chemical/biological/nuclear agents), flooding potential and warning, water availability, water quality, and agriculture and food security. In 2006, the NASA ASP sponsored two RPC experiments to evaluate potential GPM-era high resolution satellite precipitation products for water management applications. One of the current uncertainties involved in the GPM missions is the nature of the exact configuration of the constellations of satellites and hence the potential for the dynamic error characteristics over time of the precipitation estimates. For the RPC evaluations, we needed a satellite precipitation product that would be analogous to the GPM-era products. Our solution was to develop a suite of high resolution precipitation products, based on the NRL-Blend algorithm. We created a set of 10 different satellite precipitation estimates (hereafter referred to as the "GPM-proxy data"), using the currently available IR and microwave sensors. However, in each product we systematically left out sets of observations and/or sensors, such as AM orbits. The geographical focus of our study was the operational domain of the Arkansas Basin River Forecast Center (ABRFC) of the U.S. National Weather Service. We have evaluated the GPM-proxy data against the operational product (radar and gauge based) used by ABRFC. Further, we also performed a set of soil water content (SWC) sensitivity experiments using the Noah and Mosaic Land Surface Models (LSM) to quantify the impacts on water management applications involving land surface hydrology. Both the LSMs were forced with the same set of GPM-proxy data. Though the overall spatial patterns for both the models were similar, there were subtle differences in the respective model sensitivities to the different precipitation forcings. These experimental results illustrate the need for comprehensive pre-evaluations of applications

  11. Chemical Data for Rock, Sediment, Biological, Precipitate, and Water Samples from Abandoned Copper Mines in Prince William Sound, Alaska

    USGS Publications Warehouse

    Koski, Randolph A.; Munk, LeeAnn

    2007-01-01

    In the early 20th century, approximately 6 million metric tons of copper ore were mined from numerous deposits located along the shorelines of fjords and islands in Prince William Sound, Alaska. At the Beatson, Ellamar, and Threeman mine sites (fig. 1), rocks containing Fe, Cu, Zn, and Pb sulfide minerals are exposed to chemical weathering in abandoned mine workings and remnant waste piles that extend into the littoral zone. Field investigations in 2003 and 2005 as well as analytical data for rock, sediment, precipitate, water, and biological samples reveal that the oxidation of sulfides at these sites is resulting in the generation of acid mine drainage and the transport of metals into the marine environment (Koski and others, 2008; Stillings and others, 2008). At the Ellamar and Threeman sites, plumes of acidic and metal-enriched water are flowing through beach gravels into the shallow offshore environment. Interstitial water samples collected from beach sediment at Ellamar have low pH levels (to ~3) and high concentrations of metals including iron, copper, zinc, cobalt, lead, and mercury. The abundant precipitation of the iron sulfate mineral jarosite in the Ellamar gravels also signifies a low-pH environment. At the Beatson mine site (the largest copper mine in the region) seeps containing iron-rich microbial precipitates drain into the intertidal zone below mine dumps (Foster and others, 2008). A stream flowing down to the shoreline from underground mine workings at Beatson has near-neutral pH, but elevated levels of zinc, copper, and lead (Stillings and others, 2008). Offshore sediment samples at Beatson are enriched in these metals. Preliminary chemical data for tissue from marine mussels collected near the Ellamar, Threeman, and Beatson sites reveal elevated levels of copper, zinc, and lead compared to tissue in mussels from other locations in Prince William Sound (Koski and others, 2008). Three papers presenting results of this ongoing investigation of

  12. Chemical Data for Rock, Sediment, Biological, Precipitate, and Water Samples from Abandoned Copper Mines in Prince William Sound, Alaska

    USGS Publications Warehouse

    Koski, Randolph A.; Munk, LeeAnn

    2007-01-01

    Introduction In the early 20th century, approximately 6 million metric tons of copper ore were mined from numerous deposits located along the shorelines of fjords and islands in Prince William Sound, Alaska. At the Beatson, Ellamar, and Threeman mine sites (fig. 1), rocks containing Fe, Cu, Zn, and Pb sulfide minerals are exposed to chemical weathering in abandoned mine workings and remnant waste piles that extend into the littoral zone. Field investigations in 2003 and 2005 as well as analytical data for rock, sediment, precipitate, water, and biological samples reveal that the oxidation of sulfides at these sites is resulting in the generation of acid mine drainage and the transport of metals into the marine environment (Koski and others, 2008; Stillings and others, 2008). At the Ellamar and Threeman sites, plumes of acidic and metal-enriched water are flowing through beach gravels into the shallow offshore environment. Interstitial water samples collected from beach sediment at Ellamar have low pH levels (to ~3) and high concentrations of metals including iron, copper, zinc, cobalt, lead, and mercury. The abundant precipitation of the iron sulfate mineral jarosite in the Ellamar gravels also signifies a low-pH environment. At the Beatson mine site (the largest copper mine in the region) seeps containing iron-rich microbial precipitates drain into the intertidal zone below mine dumps (Foster and others, 2008). A stream flowing down to the shoreline from underground mine workings at Beatson has near-neutral pH, but elevated levels of zinc, copper, and lead (Stillings and others, 2008). Offshore sediment samples at Beatson are enriched in these metals. Preliminary chemical data for tissue from marine mussels collected near the Ellamar, Threeman, and Beatson sites reveal elevated levels of copper, zinc, and lead compared to tissue in mussels from other locations in Prince William Sound (Koski and others, 2008). Three papers presenting results of this ongoing

  13. Effects of water addition on soil arthropods and soil characteristics in a precipitation-limited environment

    NASA Astrophysics Data System (ADS)

    Chikoski, Jennifer M.; Ferguson, Steven H.; Meyer, Lense

    2006-09-01

    We investigated the effect of water addition and season on soil arthropod abundance and soil characteristics (%C, %N, C:N, moisture, pH). The experimental design consisted of 24 groups of five boxes distributed within a small aspen stand in Saskatchewan, Canada. The boxes depressed the soil to create a habitat with suitable microclimate for soil arthropods, and by overturning boxes we counted soil arthropods during weekly surveys from April to September 1999. Soil samples were collected at two-month intervals and water was added once per week to half of the plots. Of the eleven recognizable taxonomic units identified, only mites (Acari) and springtails (Collembola) responded to water addition by increasing abundance, whereas ants decreased in abundance with water addition. During summer, springtail numbers increased with water addition, whereas pH was a stronger determinant of mite abundance. In autumn, springtails were positively correlated with water and negatively correlated with mites, whereas mite abundance was negatively correlated with increasing C:N ratio, positively correlated to water addition, and negatively correlated with springtail abundance. Although both mite and springtail numbers decreased in autumn with a decrease in soil moisture, mites became more abundant than springtails suggesting a predator-prey (mite-springtail) relationship. Water had a significant effect on both springtails and mites in summer and autumn supporting the assertion that prairie soil communities are water limited.

  14. Silicon isotope fractionation during silica precipitation from hot-spring waters: Evidence from the Geysir geothermal field, Iceland

    NASA Astrophysics Data System (ADS)

    Geilert, Sonja; Vroon, Pieter Z.; Keller, Nicole S.; Gudbrandsson, Snorri; Stefánsson, Andri; van Bergen, Manfred J.

    2015-09-01

    This study aims to explore the extent and controls of silicon isotope fractionation in hot spring systems of the Geysir geothermal area (Iceland), a setting where sinter deposits are actively formed. The δ30Si values of dissolved silica measured in the spring water and sampling sites along outflowing streams, covering a temperature range between 20 and 100 °C, were relatively constant around +0.2‰, whereas the δ30Si signatures of associated opaline sinters from the streambeds were between -0.1‰ and -4.0‰, becoming progressively more negative in the downstream parts of the aprons. Here, the deposited sinters represent some of the most 30Si depleted abiotically produced terrestrial materials documented to date. Compared to the data reported for Icelandic basalts, considered to be the source of the silicon, the δ30Si values of the fluids and sinter deposits are higher and lower, respectively. The resulting values for apparent solid-water isotope fractionation (Δ30Sisolid-water) decreased with decreasing temperature from ca. -0.7‰ at ∼80 °C to -3.7‰ at ∼20 °C, locally down to -4.4‰. This temperature relationship was reproducible in each of the investigated hot spring systems and is qualitatively consistent with recent findings in laboratory experiments on kinetic fractionation for a flowing fluid. However, the apparent fractionation magnitudes observed in the field are ca. -2‰ more negative and thus significantly larger. We infer that solid-water silicon isotope fractionation during deposition of amorphous silica from a flowing fluid correlates inversely with temperature, but is essentially a function of the precipitation rate, such that the fractionation factor decreases with increasing rate. As an important corollary, the effective fractionation behavior during precipitation of silica from saturated solutions is a system-dependent feature, which should be taken into account when using silicon isotopes for paleo-environmental reconstructions.

  15. High-spatial-resolution mapping of precipitable water vapour using SAR interferograms, GPS observations and ERA-Interim reanalysis

    NASA Astrophysics Data System (ADS)

    Tang, Wei; Liao, Mingsheng; Zhang, Lu; Li, Wei; Yu, Weimin

    2016-09-01

    A high spatial and temporal resolution of the precipitable water vapour (PWV) in the atmosphere is a key requirement for the short-scale weather forecasting and climate research. The aim of this work is to derive temporally differenced maps of the spatial distribution of PWV by analysing the tropospheric delay "noise" in interferometric synthetic aperture radar (InSAR). Time series maps of differential PWV were obtained by processing a set of ENVISAT ASAR (Advanced Synthetic Aperture Radar) images covering the area of southern California, USA from 6 October 2007 to 29 November 2008. To get a more accurate PWV, the component of hydrostatic delay was calculated and subtracted by using ERA-Interim reanalysis products. In addition, the ERA-Interim was used to compute the conversion factors required to convert the zenith wet delay to water vapour. The InSAR-derived differential PWV maps were calibrated by means of the GPS PWV measurements over the study area. We validated our results against the measurements of PWV derived from the Medium Resolution Imaging Spectrometer (MERIS) which was located together with the ASAR sensor on board the ENVISAT satellite. Our comparative results show strong spatial correlations between the two data sets. The difference maps have Gaussian distributions with mean values close to zero and standard deviations below 2 mm. The advantage of the InSAR technique is that it provides water vapour distribution with a spatial resolution as fine as 20 m and an accuracy of ˜ 2 mm. Such high-spatial-resolution maps of PWV could lead to much greater accuracy in meteorological understanding and quantitative precipitation forecasts. With the launch of Sentinel-1A and Sentinel-1B satellites, every few days (6 days) new SAR images can be acquired with a wide swath up to 250 km, enabling a unique operational service for InSAR-based water vapour maps with unprecedented spatial and temporal resolution.

  16. Electrostatic precipitation of particulate emissions from the combustion of coal-oil-water and coal-water-slurry in an industrial packaged boiler. Final report

    SciTech Connect

    Noll, C.G.; Dooher, J.R.

    1984-12-01

    The report discusses the results of a research project designed to determine electrostatic-precipitation performance in collecting particulate emissions from coal-oil-water or coal-water slurry fuels. Measurements made on a mobile electrostatic precipitator (ESP) showed that New Source Performance Standards (NSPS) could be met by appropriate design and operation. Coal-oil-water fuels required a specific collection area (SCA) of 340 sq ft/1,000 ACFM flue gas, while coal-water slurry fuel needed 500 sq ft/ACFM flue gas to comply with NSPS. Specific electrode power densities were 200 watts/1,000 ACFM flue gas. The mobile ESP accepted flue gas from a packaged fire-tube boiler converted to coal-slurry firing. The fully instrumented boiler produced a fly-ash high-in carbon content, especially when burning CWS fuel. The high carbon content influenced fly-ash resistivity vs. temperature curves and must be taken into account in designing an ESP for this kind of service.

  17. Effects of nitrate and water on the oxygen isotopic analysis of barium sulfate precipitated from water samples.

    PubMed

    Hannon, Janet E; Böhlke, John Karl; Mroczkowski, Stanley J

    2008-12-01

    BaSO(4) precipitated from mixed salt solutions by common techniques for SO(4) (2-) isotopic analysis may contain quantities of H(2)O and NO(3) (-) that introduce errors in O isotope measurements. Experiments with synthetic solutions indicate that delta(18)O values of CO produced by decomposition of precipitated BaSO(4) in a carbon reactor may be either too low or too high, depending on the relative concentrations of SO(4) (2-) and NO(3) (-) and the delta(18)O values of the H(2)O, NO(3) (-), and SO(4) (2-). Typical delta(18)O errors are of the order of 0.5 to 1 per thousand in many sample types, and can be larger in samples containing atmospheric NO(3) (-), which can cause similar errors in delta(17)O and Delta(17)O. These errors can be reduced by (1) ion chromatographic separation of SO(4) (2-) from NO(3) (-), (2) increasing the salinity of the solutions before precipitating BaSO(4) to minimize incorporation of H(2)O, (3) heating BaSO(4) under vacuum to remove H(2)O, (4) preparing isotopic reference materials as aqueous samples to mimic the conditions of the samples, and (5) adjusting measured delta(18)O values based on amounts and isotopic compositions of coexisting H(2)O and NO(3) (-). These procedures are demonstrated for SO(4) (2-) isotopic reference materials, synthetic solutions with isotopically known reagents, atmospheric deposition from Shenandoah National Park, Virginia, USA, and sulfate salt deposits from the Atacama Desert, Chile, and Mojave Desert, California, USA. These results have implications for the calibration and use of O isotope data in studies of SO(4) (2-) sources and reaction mechanisms.

  18. Effects of nitrate and water on the oxygen isotopic analysis of barium sulfate precipitated from water samples

    USGS Publications Warehouse

    Hannon, J.E.; Böhlke, J.K.; Mroczkowski, S.J.

    2008-01-01

    BaSO4 precipitated from mixed salt solutions by common techniques for SO42- isotopic analysis may contain quantities of H2O and NO3- that introduce errors in O isotope measurements. Experiments with synthetic solutions indicate that ??18O values of CO produced by decomposition of precipitated BaSO4 in a carbon reactor may be either too low or too high, depending on the relative concentrations of SO42- and NO3- and the ??18O values of the H2O, NO3-, and SO42-. Typical ??18O errors are of the order of 0.5 to 1??? in many sample types, and can be larger in samples containing atmospheric NO 3-, which can cause similar errors in ?? 17O and ??17O. These errors can be reduced by (1) ion chromatographic separation of SO42- from NO 3-, (2) increasing the salinity of the solutions before precipitating BaSO4 to minimize incorporation of H2O, (3) heating BaSO4 under vacuum to remove H2O, (4) preparing isotopic reference materials as aqueous samples to mimic the conditions of the samples, and (5) adjusting measured ??18O values based on amounts and isotopic compositions of coexisting H2O and NO 3-. These procedures are demonstrated for SO 42- isotopic reference materials, synthetic solutions with isotopically known reagents, atmospheric deposition from Shenandoah National Park, Virginia, USA, and sulfate salt deposits from the Atacama Desert, Chile, and Mojave Desert, California, USA. These results have implications for the calibration and use of O isotope data in studies of SO42- sources and reaction mechanisms.

  19. Controls on the isotopic composition of surface water and precipitation in the Northern Andes, Colombian Eastern Cordillera

    NASA Astrophysics Data System (ADS)

    Saylor, Joel E.; Mora, Andrés; Horton, Brian K.; Nie, Junsheng

    2009-12-01

    Empirical datasets provide the constraints on the variability and causes of variability in stable isotope compositions (δD or δ 18O) of surface water and precipitation that are essential not only for models of modern and past climate but also for investigations of paleoelevation. This study presents stable isotope data for 76 samples from four elevation transects and three IAEA GNIP stations in the Eastern Cordillera of Colombia and the northern Andean foreland. These data are largely consistent with theories of stable isotope variability developed based on a global dataset. On a monthly basis, the precipitation-amount effect exerts the dominant control on δD p and δ 18O p values at the IAEA GNIP stations. At the Bogotá station (2547 m), the δD p and δ 18O p values vary seasonally, with isotopic minima correlating with maxima in precipitation-amount. Although surface water samples from Eastern Cordilleran streams and rivers fall on the Global Meteoric Water Line, samples from three of four lakes (2842-3459 m) have evaporatively elevated δD sw and δ 18O sw values. The IAEA GNIP station data averaged over multiple years, combined with stream and river water data, define vertical lapse rates of -1.8‰ km -1 for Δδ 18O and -14.6‰ km -1 for ΔδD, and are a close fit to a common thermodynamically based Rayleigh distillation model. Elevation uncertainties for these relationships are also evaluated. Comparison of this Colombian dataset with the elevation uncertainties generated by the thermodynamically based model shows that the model underestimates uncertainty at high Δδ 18O and ΔδD values while overestimating it for low Δδ 18O and ΔδD values. This study presents an independent, empirical assessment of stable isotope-based elevation uncertainties for the northern Andes based on a dataset of sufficient size to ensure statistical integrity. These vertical lapse rates and associated uncertainties form the basis for stable isotope paleoelevation studies

  20. Evaluation of the effects of precipitation on ground-water levels from wells in selected alluvial aquifers in Utah and Arizona, 1936-2005

    USGS Publications Warehouse

    Gardner, Philip M.; Heilweil, Victor M.

    2009-01-01

    Increased withdrawals from alluvial aquifers of the southwestern United States during the last half-century have intensified the effects of drought on ground-water levels in valleys where withdrawal for irrigation is greatest. Furthermore, during wet periods, reduced withdrawals coupled with increased natural recharge cause rising ground-water levels. In order to manage water resources more effectively, analysis of ground-water levels under the influence of natural and anthropogenic stresses is useful. This report evaluates the effects of precipitation patterns on ground-water levels in areas of Utah and Arizona that have experienced different amounts of ground-water withdrawal. This includes a comparison of water-level records from basins that are hydrogeologically and climatologically similar but have contrasting levels of ground-water development. Hydrologic data, including records of ground-water levels, basin-wide annual ground-water withdrawals, and precipitation were examined from two basins in Utah (Milford and central Sevier) and three in Arizona (Aravaipa Canyon, Willcox, and Douglas). Most water-level records examined in this study from basins experiencing substantial ground-water development (Milford, Douglas, and Willcox) showed strong trends of declining water levels. Other water-level records, generally from the less-developed basins (central Sevier and Aravaipa Canyon) exhibited trends of increasing water levels. These trends are likely the result of accumulating infiltration of unconsumed irrigation water. Water-level records that had significant trends were detrended by subtraction of a low-order polynomial in an attempt to eliminate the variation in the water-level records that resulted from ground-water withdrawal or the application of water for irrigation. After detrending, water-level residuals were correlated with 2- to 10-year moving averages of annual precipitation from representative stations for the individual basins. The water

  1. Relative humidity patterns and fog water precipitation in the Atacama Desert and biological implications

    NASA Astrophysics Data System (ADS)

    CáCeres, Luis; Gómez-Silva, Benito; Garró, Ximena; RodríGuez, Violeta; Monardes, Vinka; McKay, Christopher P.

    2007-12-01

    Fog is the most important source of water for native plants and biological soil crusts in the Atacama Desert. Since fog depends upon available moisture, an understanding of climatic patterns is essential to interpret its present-day occurrence and distribution. In this work, temperature and humidity of ambient air and collected fog water in selected sites were studied across a transect from the coast to inland of the Atacama Desert, by using automated outdoor sensors for temperature and relative humidity, and also fog collectors equipped with automated rain gauges to measure collected fog water flow rates. Field measurements were organized to determine fog and collected fog water patterns at three selected sites, namely, Coloso, Inacesa and Yungay in addition to the relative humidity and temperature variation with altitude at Coloso Mountain located within Coloso site. The results show a decreasing trend in the collected fog water flow rates from the coast toward inland locations. Daily thermal oscillations at each site are closely related to fog water collection. At Coloso Mountain, an adiabatic cooling-like effect of the wind ascending its slope was observed preferentially during nighttime. At daytime, occasional distortions observed in the temperature profiles are probably produced by a thermal driven-air convection process along the Coloso Mountain slope heated by solar radiation. The reduction in available water from fog from the coast to the inland site is consistent with the reduction in colonization rate for hypolithic cyanobacteria along this same transect.

  2. Unit operation optimization for the manufacturing of botanical injections using a design space approach: a case study of water precipitation.

    PubMed

    Gong, Xingchu; Chen, Huali; Chen, Teng; Qu, Haibin

    2014-01-01

    Quality by design (QbD) concept is a paradigm for the improvement of botanical injection quality control. In this work, water precipitation process for the manufacturing of Xueshuantong injection, a botanical injection made from Notoginseng Radix et Rhizoma, was optimized using a design space approach as a sample. Saponin recovery and total saponin purity (TSP) in supernatant were identified as the critical quality attributes (CQAs) of water precipitation using a risk assessment for all the processes of Xueshuantong injection. An Ishikawa diagram and experiments of fractional factorial design were applied to determine critical process parameters (CPPs). Dry matter content of concentrated extract (DMCC), amount of water added (AWA), and stirring speed (SS) were identified as CPPs. Box-Behnken designed experiments were carried out to develop models between CPPs and process CQAs. Determination coefficients were higher than 0.86 for all the models. High TSP in supernatant can be obtained when DMCC is low and SS is high. Saponin recoveries decreased as DMCC increased. Incomplete collection of supernatant was the main reason for the loss of saponins. Design space was calculated using a Monte-Carlo simulation method with acceptable probability of 0.90. Recommended normal operation region are located in DMCC of 0.38-0.41 g/g, AWA of 3.7-4.9 g/g, and SS of 280-350 rpm, with a probability more than 0.919 to attain CQA criteria. Verification experiment results showed that operating DMCC, SS, and AWA within design space can attain CQA criteria with high probability.

  3. Unit Operation Optimization for the Manufacturing of Botanical Injections Using a Design Space Approach: A Case Study of Water Precipitation

    PubMed Central

    Gong, Xingchu; Chen, Huali; Chen, Teng; Qu, Haibin

    2014-01-01

    Quality by design (QbD) concept is a paradigm for the improvement of botanical injection quality control. In this work, water precipitation process for the manufacturing of Xueshuantong injection, a botanical injection made from Notoginseng Radix et Rhizoma, was optimized using a design space approach as a sample. Saponin recovery and total saponin purity (TSP) in supernatant were identified as the critical quality attributes (CQAs) of water precipitation using a risk assessment for all the processes of Xueshuantong injection. An Ishikawa diagram and experiments of fractional factorial design were applied to determine critical process parameters (CPPs). Dry matter content of concentrated extract (DMCC), amount of water added (AWA), and stirring speed (SS) were identified as CPPs. Box-Behnken designed experiments were carried out to develop models between CPPs and process CQAs. Determination coefficients were higher than 0.86 for all the models. High TSP in supernatant can be obtained when DMCC is low and SS is high. Saponin recoveries decreased as DMCC increased. Incomplete collection of supernatant was the main reason for the loss of saponins. Design space was calculated using a Monte-Carlo simulation method with acceptable probability of 0.90. Recommended normal operation region are located in DMCC of 0.38–0.41 g/g, AWA of 3.7–4.9 g/g, and SS of 280–350 rpm, with a probability more than 0.919 to attain CQA criteria. Verification experiment results showed that operating DMCC, SS, and AWA within design space can attain CQA criteria with high probability. PMID:25101624

  4. Synthesis by precipitation polymerization of molecularly imprinted polymer for the selective extraction of diclofenac from water samples.

    PubMed

    Dai, Chao-meng; Zhou, Xue-fei; Zhang, Ya-lei; Liu, Shu-guang; Zhang, Juan

    2011-12-30

    A molecularly imprinted polymer (MIP) was synthesized by precipitation polymerization using diclofenac (DFC) as a template, 2-vinylpyridine (2-VP) as functional monomer, ethylene glycol dimethacrylate (EGDMA) as cross-linker, and toluene as porogen. The MIP showed outstanding affinity toward DFC in aqueous solution with a binding site capacity (Q(max)) of 324.8 mg/g (1.09 mmol/g) and was used as solid-phase extraction (SPE) material for the quantitative enrichment of DFC in environmental water samples and off-line coupled to a reversed-phase HPLC/DAD. Various parameters including washing solvent, elution solvent and breakthrough volume affecting the extraction efficiency of the polymers have been evaluated to achieve the selective preconcentration of DFC from water samples and to reduce non-specific interactions. Recoveries of DFC extracted from tap water, river water and wastewater samples were higher than 95%, and no significant DFC recovery difference was obtained among the different water matrix. The stability of MIP was tested by consecutive percolation of water sample, and it was shown that the performance of the MIP did not vary even after 30 adsorption and desorption cycles. Furthermore, the MISPE was used for the analysis of DFC in river water and wastewater samples and revealed DFC concentrations of 0.69±0.002 μg/L (n=3) and 0.31±0.004μg/L (n=3), respectively. The results were in good agreement with corresponding LC-MS/MS data.

  5. [Seasonal characteristics of δD and δ18O in precipitation and its water vapor sources in the Xiaolangdi Reservoir area of Yellow River, China].

    PubMed

    Tian, Chao; Meng, Ping; Zhang, Jin-song; Sun, Shou-jia; He, Chun-xia; Jia, Chang-rong; Li, Jian-zhong

    2015-12-01

    The seasonal characteristics of δD and δ¹⁸O in precipitation and the influence factors were studied in the Xiaolangdi Reservoir area at the eastern monsoon region of China. The precipitation samples and the corresponding meteorological data were collected between April and October from the year 2011 to 2014. The local meteoric water lines (LMWL) of different seasons were established, and the water vapor sources in different seasons were investigated. The results showed that the δD and δ¹⁸O in precipitation exhibited an extremely wide range and a distinct seasonal variation, and they were enriched in the spring, and depleted in the fall. The δD and δ¹⁸O values showed negative correlations with the amount of precipitation from April to October and the fall, respectively. The δD values and the mean air temperature showed a negative correlation from April to October, but showed no correlation in seasonal precipitation. Both the slopes of LMWL and excess deuterium (d values) of precipitation were the smallest in the summer, and the largest in the fall. The results of air mass back trajectories of seasonal precipitation using the HYSPLIT model indicated a dominant effect of southeast and southwest maritime monsoon air masses in the summer and the co-influence of continental and oceanic monsoons air masses in the spring and fall in the study area.

  6. Impact of extreme precipitation and water table change on N2O fluxes in a bio-energy poplar plantation

    NASA Astrophysics Data System (ADS)

    Zona, D.; Janssens, I. A.; Verlinden, M. S.; Broeckx, L. S.; Cools, J.; Gioli, B.; Zaldei, A.; Ceulemans, R.

    2011-03-01

    A large fraction of the West European landscape is used for intensive agriculture. Several of these countries have very high nitrous oxide (N2O) emissions, because of substantial use of fertilizers and high rates of atmospheric nitrogen deposition. N2O production in soils is controlled by water-filled pore space (WFPS) and substrate availability (NO3). Here we show that extreme precipitation (80 mm rainfall in 48 h) after a long dry period, led to a week-long peak in N2O emissions (up to about 2200 μg N2O-N m-2 h-1). In the first four of these peak emission days, N2O fluxes showed a pronounced diurnal pattern correlated to daytime increase in temperature and wind speed. It is possible that N2O was transported through the transpiration stream of the poplar trees and emitted through the stomates. However, during the following three high emission days, N2O emission was fairly stable with no pronounced diurnal trend, and was correlated with wind speed and WFPS (at 20 and 40 cm depth) but no longer with soil temperature. We hypothesized that wind speed facilitated N2O emission from the soil to the atmosphere through a significant pressure-pumping. Successive rainfall events and similar WFPS after this first intense precipitation did not lead to N2O emissions of the same magnitude. These findings suggest that climate change-induced modification in precipitation patterns may lead to high N2O emission pulses from soil, such that sparser and more extreme rainfall events after longer dry periods could lead to peak N2O emissions. The cumulative effects of more variable climate on annual N2O emission are still largely uncertain and need further investigation.

  7. Modeled Interactive Effects of Precipitation, temperature, and [CO2] on Ecosystem Carbon and Water Dynamics in Different Climatic Zones

    SciTech Connect

    Luo, Yiqi; Gerten, Dieter; Le Maire, Guerric; Parton, William; Weng, Ensheng; Zhou, Xuhuui; Keough, Cindy; Beier, Claus; Ciais, Philippe; Cramer, Wolfgang; Dukes, Jeff; Emmett, Bridget; Hanson, Paul J; Knapp, Alan; Linder, Sune; Nepstad, Daniel; Rustad, Lindsey

    2008-01-01

    Interactive effects of multiple global change factors on ecosystem processes are complex. It is relatively expensive to explore those interactions in manipulative experiments. We conducted a modeling analysis to identify potentially important interactions and to stimulate hypothesis formulation for experimental research. Four models were used to quantify interactive effects of climate warming (T), altered precipitation amounts [doubled (DP) and halved (HP)] and seasonality (SP, moving precipitation in July and August to January and February to create summer drought), and elevated [CO2] (C) on net primary production (NPP), heterotrophic respiration (Rh), net ecosystem production (NEP), transpiration, and runoff.We examined those responses in seven ecosystems, including forests, grasslands, and heathlands in different climate zones. The modeling analysis showed that none of the threeway interactions among T, C, and altered precipitation was substantial for either carbon or water processes, nor consistent among the seven ecosystems. However, two-way interactive effects on NPP, Rh, and NEP were generally positive (i.e. amplification of one factor s effect by the other factor) between T and C or between T and DP. A negative interaction (i.e. depression of one factor s effect by the other factor) occurred for simulated NPP between T and HP. The interactive effects on runoff were positive between T and HP. Four pairs of two-way interactive effects on plant transpiration were positive and two pairs negative. In addition, wet sites generally had smaller relative changes in NPP, Rh, runoff, and transpiration but larger absolute changes in NEP than dry sites in response to the treatments. The modeling results suggest new hypotheses to be tested in multifactor global change experiments. Likewise, more experimental evidence is needed for the further improvement of ecosystem models in order to adequately simulate complex interactive processes.

  8. A universal salt model based on under-ground precipitation of solid salts due to supercritical water `out-salting'

    NASA Astrophysics Data System (ADS)

    Rueslåtten, H.; Hovland, M. T.

    2010-12-01

    One of the common characteristics of planets Earth and Mars is that both host water (H2O) and large accumulations of salt. Whereas Earth’s surface-environment can be regarded as ‘water-friendly’ and ‘salt hostile’, the reverse can be said for the surface of Mars. This is because liquid water is stable on Earth, and the atmosphere transports humidity around the globe, whereas on planet Mars, liquid water is unstable, rendering the atmosphere dry and, therefore, ‘salt-friendly’. The riddle as to how the salt accumulated in various locations on those two planets, is one of long-lasting and great debate. The salt accumulations on Earth are traditionally termed ‘evaporites’, meaning that they formed as a consequence of the evaporation of large masses of seawater. How the accumulations on Mars formed is much harder to explain, as an ocean only existed briefly. Although water molecules and OH-groups may exist in abundance in bound form (crystal water, adsorbed water, etc.), the only place where free water is expected to be stable on Mars is within underground faults, fractures, and crevices. Here it likely occurs as brine or in the form of ice. Based on these conditions, a key to understanding the accumulation of large deposits of salt on both planets is linked to how brines behave in the subsurface when pressurized and heated beyond their supercritical point. At depths greater than about 3 km (P>300 bars) water will no longer boil in a steam phase. Rather, it becomes supercritical and will attain the phase of supercritical water vapor (SCRIW) with a specific gravity of typically 0.3 g/cm3. An important characteristic of SCRIW is its inability to dissolve the common sea salts. The salt dissolved in the brines will therefore precipitate as solid particles when brines (seawater on the Earth) move into the supercritical P&T-domain (T>400°C, P>300 bars). Numerical modeling of a hydrothermal system in the Atlantis II Deep of the Red Sea indicates that a

  9. Precipitate deposition around CMC and vesicle-to-micelle transition of monopotassium monododecyl phosphate in water.

    PubMed

    Sakai, Takaya; Miyaki, Masahiro; Tajima, Hitoshi; Shimizu, Masaki

    2012-09-13

    Monoalkyl phosphate (MAP) salts are a kind of bivalent anionic surfactants. The difference of properties between half-neutralized monosalt and completely neutralized disalt is very interesting. In this study, the aggregation behavior of monopotassium monododecyl phosphate (MAP-12K) in aqueous solution with an increase in concentration was investigated by surface tension (γ), elemental analysis, gas chromatography, differential scanning calorimetry, steady-state fluorescence, and negative strained transmission electron microscopy techniques. MAP-12K aqueous solution showed some characteristics: (I) Vesicle aggregates were formed at very dilute concentration (1.2 mM). (II) The precipitate of a highly hydrophobic dimer of MAP, which was quaternary neutralized by potassium, was generated only in a certain dilute concentration region (2.7-200 mM) around the critical micelle concentration (cmc = 20 mM). (III) Vesicles spontaneously translate into micelles at the cmc. (IV) In the higher concentration above 200 mM, the solution becomes homogeneous micellar solution. All of these uncommon characteristics are thought to be caused by the generation of the dimer, which is much more hydrophobic than dissolved MAP derivatives, in the complicated chemical equilibria based on the weakly acidic character of MAP. MAP-12K aqueous solution behaves as if it is a binary mixed surfactant solution of hydrophobic dialkyl surfactant and hydrophilic monoalkyl surfactant in spite of a single component solution.

  10. Annual Variations in Water Storage and Precipitation in the Amazon Basin: Bounding Sink Terms in the Terrestrial Hydrological Balance using GRACE Satellite Gravity Data

    NASA Technical Reports Server (NTRS)

    Crowley, John W.; Mitrovica, Jerry X.; Bailey, Richard C.; Tamisiea, Mark E.; Davis, James L.

    2007-01-01

    We combine satellite gravity data from the Gravity Recovery and Climate Experiment (GRACE) and precipitation measurements from the National Oceanic and Atmospheric Administration (NOAA) Climate Prediction Center's (CPC) Merged Analysis of Precipitation (CMAP) and the Tropical Rainfall Measuring Mission (TRMM), over the period from mid-2002 to mid-2006, to investigate the relative importance of sink (runoff and evaporation) and source (precipitation) terms in the hydrological balance of the Amazon Basin. When linear and quadratic terms are removed, the time series of land water storage variations estimated from GRACE exhibits a dominant annual signal of 250 mm peak-to-peak, which is equivalent to a water volume change of approximately 1800 cubic kilometers. A comparison of this trend with accumulated (i.e., integrated) precipitation shows excellent agreement and no evidence of basin saturation. The agreement indicates that the net runoff and evaporation contributes significantly less than precipitation to the annual hydrological mass balance. Indeed, raw residuals between the detrended water storage and precipitation anomalies range from plus or minus 40 mm. This range is consistent with streamflow measurements from the region, although the latter are characterized by a stronger annual signal than ow residuals, suggesting that runoff and evaporation may act to partially cancel each other.

  11. Measurements of total column ozone, precipitable water content and aerosol optical depth at Sofia

    NASA Astrophysics Data System (ADS)

    Kaleyna, P.; Kolev, N.; Savov, P.; Evgenieva, Ts.; Danchovski, V.; Muhtarov, P.

    2016-03-01

    This article reports the results of a study related to variations in total ozone content, aerosol optical depth, water vapor content and Ångström coefficients from summer campaign carried out in June-July 2014, at two sites in the city of Sofia (Astronomical Observatory in the Borisova Gradina Park and National Institute of Geophysics, Geodesy and Geography (NIGGG)). The results of data analysis indicate the following: Spectral dependence of aerosol optical depth (AOD); Greater AOD values due to greater portion of aerosols; Inverse relationship between the time variations of AOD or water vapor and ozone.

  12. Application of quantitative XRD on the precipitation of struvite from Brine Water

    NASA Astrophysics Data System (ADS)

    Heraldy, E.; Rahmawati, F.; Heryanto; Putra, D. P.

    2017-02-01

    The present studies have been conducted to quantify the varied phases in struvite formation from brine water as the magnesium source. The quantitative X-ray Diffraction (QXRD) method was performed to quantitatively determine the crystal phases and amorphous content of struvite samples. Substantial phase samples were employed quantitative analysis to calibrate against known phase composition information by Rietveld refinement on powder XRD data. The results showed that brine water could be considered as magnesium source the formation of struvite products. The study demonstrated that in general, the high N:P molar ratio (both pH 9 and 10) might lead to the significant formation of struvite.

  13. Use of NADP archive samples to determine the isotope composition of precipitation: characterizing the meteoric input function for use in ground water studies.

    PubMed

    Harvey, F E

    2001-01-01

    Stable oxygen and hydrogen isotopes have been used in ground water studies to investigate recharge, mixing, ground water/surface water interaction, advective-diffusive transport, paleohydrogeologic interactions and to estimate ground water ages. Such studies require that the isotopic composition of precipitation be known, as precipitation is a major input to ground water and surface water systems. As oxygen-18 and deuterium data for precipitation are lacking across much of the United States, there is need to establish additional local meteoric water lines as isotope input functions across the region, as well as to develop better understanding of the isotopic climate linkages that control oxygen and hydrogen isotope ratios in precipitation. In the absence of long-term monitoring stations, one possible solution to this problem is to determine the delta 18O and delta 2H values of precipitation using archive samples collected at monitoring stations managed by the National Atmospheric Deposition Program (NADP). This study describes and interprets the seasonal delta 18O and delta 2H composition of archived precipitation samples collected in eastern Nebraska near the town of Mead during the years 1992-1994. Values for delta 18O range from -23.6 to -0.7@1000. Values for delta 2H range from -172 to 0@1000. Yearly arithmetic mean delta 18O and delta 2H values for the Mead station are -8.1@1000 and -53@1000, respectively. Weighted yearly means for delta 18O and delta 2H were -7.4@1000 and -48@1000, respectively. Mead values show a strong isotopic enrichment between winter and summer precipitation, and a strong delta 18O-T correlation (r2 = 0.91) for mean monthly values of about 0.5@1000 per degree Celsius. The local meteoric water line for the Mead site is delta 2H = 7.40 delta 18O + 7.32. Deuterium excess values suggest that most of the moisture across the region is derived primarily from a Gulf of Mexico source. The results of this study demonstrate that in the absence of

  14. Factors Affecting P Loads to Surface Waters: Comparing the Roles of Precipitation and Land Management Practices

    NASA Astrophysics Data System (ADS)

    Motew, M.; Booth, E.; Carpenter, S. R.; Kucharik, C. J.

    2014-12-01

    Surface water quality is a major concern in the Yahara watershed (YW) of southern Wisconsin, home to a thriving dairy industry, the city of Madison, and five highly valued lakes that are eutrophic. Despite management interventions to mitigate runoff, there has been no significant trend in P loading to the lakes since 1975. Increases in manure production and heavy rainfall events over this time period may have offset any effects of management. We developed a comprehensive, integrated modeling framework that can simulate the effects of multiple drivers on ecosystem services, including surface water quality. The framework includes process-based representation of terrestrial ecosystems (Agro-IBIS) and groundwater flow (MODFLOW), hydrologic routing of water and nutrients across the landscape (THMB), and assessment of lake water quality (YWQM). Biogeochemical cycling and hydrologic transport of P have been added to the framework to enable detailed simulation of P dynamics within the watershed, including interactions with climate and management. The P module features in-soil cycling of organic, inorganic, and labile forms of P; manure application, decomposition, and subsequent loss of dissolved P in runoff; loss of particulate-bound P with erosion; and transport of dissolved and particulate P within waterways. Model results will compare the effects of increased heavy rainfall events, increased manure production, and implementation of best management practices on P loads to the Yahara lakes.

  15. The bovine immune response to Brucella abortus I. A water soluble antigen precipitated by sera of some naturally infected cattle.

    PubMed Central

    Stemshorn, B; Nielsen, K

    1977-01-01

    Selected sera from cattle naturally infected with Brucella abortus precipitate water soluble antigens extracted by sonication from B. abortus. One of these antigens resembles antigen E (Baughn and Freeman) as it is excluded from Sephadex G-200 gels, migrates anodally when electrophoresed at pH 8.6, resists heating at 100 degrees C for ten minutes and appears to be susceptible to papain digestion. Precipitins specific for this antigen remained in sera from which all detectable Brucella agglutinating antibody had been removed by adsorption with live or heat killed B. abortus. The antigen has been extracted from smooth and rough strains of B abortus. Precipitins specific for this antigen have been detected in antisera produced against Brucella canis. Images Fig. 1. Fig. 2. Fig. 3. Fig. 4. PMID:405088

  16. WetNet: Using SSM/I data interactively for global distribution of tropical rainfall and precipitable water

    NASA Technical Reports Server (NTRS)

    Zipser, Edward J.; Mcguirk, James P.

    1993-01-01

    The research objectives were the following: (1) to use SSM/I to categorize, measure, and parameterize effects of rainfall systems around the globe, especially mesoscale convective systems; (2) to use SSM/I to monitor key components of the global hydrologic cycle, including tropical rainfall and precipitable water, and links to increasing sea surface temperatures; and (3) to assist in the development of efficient methods of exchange of massive satellite data bases and of analysis techniques, especially their use at a university. Numerous tasks have been initiated. First and foremost has been the integration and startup of the WetNet computer system into the TAMU computer network. Scientific activity was infeasible before completion of this activity. Final hardware delivery was not completed until October 1991, after which followed a period of identification and solution of several hardware and software and software problems. Accomplishments representing approximately four months work with the WetNEt system are presented.

  17. Overland flow computations in urban and industrial catchments from direct precipitation data using a two-dimensional shallow water model.

    PubMed

    Cea, L; Garrido, M; Puertas, J; Jácome, A; Del Río, H; Suárez, J

    2010-01-01

    This paper presents the experimental validation and the application to a real industrial catchment of a two-dimensional depth-averaged shallow water model used for the computation of rainfall-runoff transformation from direct precipitation data. Instead of using the common approach in flood inundation modelling, which consists in computing the water depth and velocity fields given the water discharge, in this study the rainfall intensity is imposed directly in the model, the surface runoff being generated automatically. The model considers infiltration losses simultaneously with flow simulation. Gullies are also included in the model, although the coupling between the surface runoff and the sewer network is not considered. Experimental validation of the model is presented in several simplified laboratory configurations of urban catchments, in which the surface runoff has been measured for different hyetographs. The application to a real industrial catchment includes a sewer network flow component, which is solved with the SWMM model. The numerical predictions of the discharge hydrograph generated by a 12 hours storm event are compared with field measurements, providing encouraging results.

  18. Time distribution of the precipitable water vapor in central Saudi Arabia and its relationship to solar activity

    NASA Astrophysics Data System (ADS)

    Maghrabi, A. H.; Al Dajani, H. M.

    2014-04-01

    Water vapor is the most important greenhouse gas. It plays a major role in the dynamics of atmospheric circulation, radiation exchange within the atmosphere, and climate variability. Knowledge of the distribution of water vapor is important for understanding climate change and global warming. In this study, radiosonde data from 1985 to 2012 were used to examine the monthly, interannual, and annual variations and trends of precipitable water vapor (PWV) in central Saudi Arabia in the city of Riyadh (24° 43‧N; 46° 40‧E, 764 m a.s.l.). The results revealed a clear seasonal cycle of PWV with a maximum during the summer months (June-August) and a minimum during the winter (December-February). This variation follows the mean monthly variation of air temperature. The PWV displays considerable variability at the interannual scale. We could not attribute the variations to the air temperature because no relationship was found between the two variables when the interannual variations were examined. Study of the annual variations of the PWV showed cyclic variations with a period of approximately 10-11 years. The two maximums and minimums were in 1996 and 2007 and 1989 and 2000, respectively. The results showed that the annual PWV values are anticorrelated with solar activity, represented by sunspot number, during solar cycles 22 and 23. The physical mechanism underlying this relationship remains unclear. This finding is preliminary, and future investigations are recommended.

  19. Data Assimilation of AIRS Water Vapor Profiles: Impact on Precipitation Forecasts for Atmospheric River Cases Affecting the Western of the United States

    NASA Technical Reports Server (NTRS)

    Blankenship, Clay; Zavodsky, Bradley; Jedlovec, Gary; Wick, Gary; Neiman, Paul

    2013-01-01

    Atmospheric rivers are transient, narrow regions in the atmosphere responsible for the transport of large amounts of water vapor. These phenomena can have a large impact on precipitation. In particular, they can be responsible for intense rain events on the western coast of North America during the winter season. This paper focuses on attempts to improve forecasts of heavy precipitation events in the Western US due to atmospheric rivers. Profiles of water vapor derived from from Atmospheric Infrared Sounder (AIRS) observations are combined with GFS forecasts by a three-dimensional variational data assimilation in the Gridpoint Statistical Interpolation (GSI). Weather Research and Forecasting (WRF) forecasts initialized from the combined field are compared to forecasts initialized from the GFS forecast only for 3 test cases in the winter of 2011. Results will be presented showing the impact of the AIRS profile data on water vapor and temperature fields, and on the resultant precipitation forecasts.

  20. Precipitation chemistry - Atmospheric loadings to the surface waters of the Indian River lagoon basin by rainfall

    NASA Technical Reports Server (NTRS)

    Dreschel, Thomas W.; Madsen, Brooks C.; Maull, Lee A.; Hinkle, C. R.; Knott, William M., III

    1990-01-01

    Rain volume and chemistry monitoring as part of the Kennedy Space Center Long Term Environmental Monitoring Program included the years 1984-1987 as part of the National Atmospheric Deposition Program. Atmospheric deposition in rainfall consisted primarily of sea salt and hydrogen ion, sulfate, nitrate, and ammonium ions. The deposition of nitrogen (a principal plant nutrient) was on the order of 200-300 metric tons per year to the surface waters.

  1. Sustained Water Changes in California during Drought and Heavy Precipitation Inferred from GPS, InSAR, and GRACE

    NASA Astrophysics Data System (ADS)

    Argus, D. F.; Fu, Y.; Landerer, F. W.; Wiese, D. N.; Farr, T. G.; Liu, Z.; Thomas, B. F.; Famiglietti, J. S.

    2015-12-01

    About 1200 GPS sites in the westernmost United States are used to weigh changes in surface water as a function of location from 2006 to 2015. The effect of known changes in water in artificial reservoirs is removed, allowing changes in the total of snow, soil moisture, and mountain fracture groundwater to be inferred from GPS. In this study water changes inferred from GPS are placed into the context of complementary InSAR and GRACE data. The southern Central Valley (the San Joaquin Valley and Tulare Basin) is subsiding at spectacular rates of 0.01 m/yr to 0.2 m/yr in response to groundwater management. We construct an elastic model of groundwater change of the southern Central Valley, using GRACE as the basis of total groundwater loss and InSAR to infer the lateral distribution of that groundwater loss. This elastic model of Central Valley groundwater loss is removed from the GPS displacements. Because snow in California is insignificant in October, and because changes in soil moisture between successive autumns are small, we can infer changes in Sierra Nevada mountain fracture groundwater to be: -19 km3 during drought from 2006 to 2009, +35 km3 during heavy precipitation from 2009 to 2011, and -38 km3 during drought from 2011 to 2014 (start and end times are all in October). We infer changes in Sierra Nevada mountain groundwater to be playing an important role in modulating Central Valley groundwater loss. Total water in the Sierra Nevada recovered by 16 km3 from October 2014 to April 2015, but water is being lost again in summer 2015.

  2. Limitations of Snow-Water Equivalent and Precipitation Data in Seasonal Flow Forecasting in the Upper Klamath River Basin of Oregon and California

    NASA Astrophysics Data System (ADS)

    Risley, J. C.; Roehl, E. A.

    2005-12-01

    Water managers in the upper Klamath Basin, located in south-central Oregon and northeastern California, rely on accurate forecasts of spring and summer streamflow to optimally allocate increasingly limited water supplies for various demands that include irrigation for agriculture, habitat for endangered fishes, and hydropower production. Federal agencies make forecasts on the 1st of each month, from January through May, of the total volume of water expected to pass a stream gage or flow into a reservoir during an entire summer irrigation season. Often the forecasts are based on output from flow forecast models that use real-time snow-water equivalent (SWE) and precipitation data as input. Because the January and February forecasts are significantly less accurate than those made in the spring, we were interested in quantifying the limitations of real-time SWE and precipitation data in forecasting future flows. Using over 20 years of daily SWE, precipitation, and flow time-series from five sites in the upper Klamath Basin, we first decomposed the flow records into annual periodic, long-term climatic, and chaotic traces. Being the component of the original flow records with their seasonality and long-term trends removed, the chaotic traces were then lag correlated with SWE and precipitation records. After a 120 day lag (approximately 4 months), all of the correlation coefficients between the chaotic flow traces and the SWE and precipitation records were less than 0.4. From this, we could infer that SWE and precipitation data older than 120 days provide forecast models only with information regarding the annual seasonal and long-term climate patterns and do not provide information that is unique and specific for the upcoming irrigation season. These results also support the need to find new climate variables, such as mid-oceanic indicators, to improve forecast model accuracy rather than using just real-time SWE and precipitation conditions.

  3. A heat and water transfer model for seasonally frozen soils with application to a precipitation-runoff model

    USGS Publications Warehouse

    Emerson, Douglas G.

    1994-01-01

    A model that simulates heat and water transfer in soils during freezing and thawing periods was developed and incorporated into the U.S. Geological Survey's Precipitation-Runoff Modeling System. The model's transfer of heat is based on an equation developed from Fourier's equation for heat flux. The model's transfer of water within the soil profile is based on the concept of capillary forces. Field capacity and infiltration rate can vary throughout the freezing and thawing period, depending on soil conditions and rate and timing of snowmelt. The model can be used to determine the effects of seasonally frozen soils on ground-water recharge and surface-water runoff. Data collected for two winters, 1985-86 and 1986-87, on three runoff plots were used to calibrate and verify the model. The winter of 1985-86 was colder than normal, and snow cover was continuous throughout the winter. The winter of 1986-87 was warmer than normal, and snow accumulated for only short periods of several days. Runoff, snowmelt, and frost depths were used as the criteria for determining the degree of agreement between simulated and measured data. The model was calibrated using the 1985-86 data for plot 2. The calibration simulation agreed closely with the measured data. The verification simulations for plots 1 and 3 using the 1985-86 data and for plots 1 and 2 using the 1986-87 data agreed closely with the measured data. The verification simulation for plot 3 using the 1986-87 data did not agree closely. The recalibration simulations for plots 1 and 3 using the 1985-86 data indicated little improvement because the verification simulations for plots 1 and 3 already agreed closely with the measured data.

  4. Response of surface water chemistry to reduced levels of acid precipitation: Comparison of trends in two regions of New York, USA

    USGS Publications Warehouse

    Burns, Douglas A.; McHale, M.R.; Driscoll, C.T.; Roy, K.M.

    2006-01-01

    In light of recent reductions in sulphur (S) and nitrogen (N) emissions mandated by Title IV of the Clean Air Act Amendments of 1990, temporal trends and trend coherence in precipitation (1984-2001 and 1992-2001) and surface water chemistry (1992-2001) were determined in two of the most acid-sensitive regions of North America, i.e. the Catskill and Adirondack Mountains of New York. Precipitation chemistry data from six sites located near these regions showed decreasing sulphate (SO42-), nitrate (NO3-), and base cation (CB) concentrations and increasing pH during 1984-2001, but few significant trends during 1992-2001. Data from five Catskill streams and 12 Adirondack lakes showed decreasing trends in SO42- concentrations at all sites, and decreasing trends in NO3-, CB, and H+ concentrations and increasing trends in dissolved organic carbon at most sites. In contrast, acid-neutralizing capacity (ANC increased significantly at only about half the Adirondack lakes and in one of the Catskill streams. Flow correction prior to trend analysis did not change any trend directions and had little effect on SO42- trends, but it caused several significant non-flow-corrected trends in NO3- and ANC to become non-significant, suggesting that trend results for flow-sensitive constituents are affected by flow-related climate variation. SO42- concentrations showed high temporal coherence in precipitation, surface waters, and in precipitation-surface water comparisons, reflecting a strong link between S emissions, precipitation SO42- concentrations, and the processes that affect S cycling within these regions. NO3- and H+ concentrations and ANC generally showed weak coherence, especially in surface waters and in precipitation-surface water comparisons, indicating that variation in local-scale processes driven by factors such as climate are affecting trends in acid-base chemistry in these two regions. Copyright ?? 2005 John Wiley & Sons, Ltd.

  5. Jarosite Precipitation from Acidic Saline Waters in Kachchh, Gujarat, India: an Appropriate Martian Analogue?

    NASA Astrophysics Data System (ADS)

    Mitra, S.; Gupta, S.; Bhattacharya, S.; Banerjee, S.; Chauhan, P.; Parthasarathy, G.

    2014-12-01

    The origin of jarosite [KFe3(SO4)2(OH)6] on the Martian surface has been an intriguing problem since the Mars Exploration Rover 'Opportunity' first revealed its presence at the Meridiani Planum on Mars. To explain its origin, several terrestrial analogue sites have been studied in different geographical zones. Although several models have been suggested, there is a consensus that only the prevalence of acidic and oxidizing aqueous environmental conditions are conducive to form jarosite. In the Kachchh region of Gujarat, western India, jarosite has been recently discovered from gorges dissecting the Paleocene Matanumadh Formation sediments, that overlie basalts of the Deccan Volcanic Province. This formation comprises pebble conglomerates, carbonaceous shales and purple sandstones capped by a laterite on top. Jarosite, in association with gypsum and goethite, has been detected through FTIR and VNIR spectrometry in almost all litho-units of the succession, albeit in different modes and concentrations. The occurrence of jarosite within black shale in other parts of the world, has been attributed to the oxidation of pyrites within the shale layers. However, in shales of the Matanumadh Formation, jarosite is restricted to fractures that cut across the bedding, while the overlying purple sandstone unit only preserves jarosite in shale clasts within the sandstone. Since the sandstone overlies the black shale layer, downward percolation of sulfate-bearing water from the oxidation of pyrite within the shale layer cannot explain jarosite formation in this unit. In addition, no jarosite is observed below or within pyrite-rich lignite bearing sections in other parts of Kachchh. Alternative suggestions, that jarosite developed in the immediate aftermath of Deccan volcanism as surface waters were rendered acidic by interaction with the final phase of volcanic effusives, are also unlikely as on-going studies suggest that jarosite is not restricted to the Matanumadh Formation. The

  6. Precipitation driving of droplet concentration variability in marine low clouds

    NASA Astrophysics Data System (ADS)

    Wood, Robert; Leon, David; Lebsock, Matthew; Snider, Jefferson; Clarke, Antony D.

    2012-10-01

    The concentration Nd of cloud droplets in marine low clouds is a primary determinant of their ability to reflect sunlight and modulates their ability to precipitate. Previous studies have focused upon aerosol source variability as the key driver of variability in Nd. Here, we use a highly simplified aerosol budget model to examine the impact of precipitation on Nd. This model considers: precipitation (coalescence) scavenging, constrained using new satellite measurements of light precipitation; entrainment of aerosol from above cloud combined with constant aerosol concentration based on recent field observations of aerosol particles in the free troposphere; and sea-surface aerosol production estimated using a wind speed dependent source function. Despite the highly simplified nature of this model, it skillfully predicts the geographical variability ofNd in regions of extensive marine low clouds. Inclusion of precipitation results in reduction in Nd by factors of 2-3 over the remote oceans. Within 500 km of coastlines the reduction in Nd due to precipitation is weak but in these regions the model is not able to accurately predict Ndbecause of strong pollution sources. In general, neither free-tropospheric nor surface CCN sources alone are sufficient to maintainNd against precipitation losses. The results demonstrate that even the light precipitation rates typical of marine stratocumulus profoundly impact the radiative properties of marine low clouds.

  7. Aerosol Impacts on California Winter Clouds and Precipitation during CalWater 2011: Local Pollution versus Long-Range Transported Dust

    SciTech Connect

    Fan, Jiwen; Leung, Lai-Yung R.; DeMott, Paul J.; Comstock, Jennifer M.; Singh, Balwinder; Rosenfeld, Daniel; Tomlinson, Jason M.; White, Allen B.; Prather, Kimberly; Minnis, Patrick; Ayers, J. K.; Min, Qilong

    2014-01-03

    Mineral dust aerosols often observed over California in winter and spring, associated with long-range transport from Asia and Sahara, have been linked to enhanced precipitation based on observations. Local anthropogenic pollution, on the other hand, was shown in previous observational and modeling studies to reduce precipitation. Here we incorporate recent developments in ice nucleation parameterizations to link aerosols with ice crystal formation in a spectral-bin cloud microphysical model coupled with the Weather Research and Forecasting (WRF) model, to examine the relative and combined impacts of dust and local pollution particles on cloud properties and precipitation type and intensity. Simulations are carried out for two cloud cases with contrasting meteorology and cloud dynamics that occurred on February 16 (FEB16) and March 02 (MAR02) from the CalWater 2011 field campaign. In both cases, observations show the presence of dust and biological particles in a relative pristine environment. The simulated cloud microphysical properties and precipitation show reasonable agreement with aircraft and surface measurements. Model sensitivity experiments indicate that in the pristine environment, the dust and biological aerosol layers increase the accumulated precipitation by 10-20% from the Central Valley to the Sierra Nevada Mountains for both FEB16 and MAR02 due to a ~40% increase in snow formation, validating the observational hypothesis. Model results show that local pollution increases precipitation over the windward slope of the mountains by few percent due to increased snow formation when dust is present but reduces precipitation by 5-8% if dust is removed on FEB16. The effects of local pollution on cloud microphysics and precipitation strongly depend on meteorology including the strength of the Sierra Barrier Jet, and cloud dynamics. This study further underscores the importance of the interactions between local pollution, dust, and environmental conditions for

  8. Aerosol impacts on California winter clouds and precipitation during CalWater 2011: local pollution vs. long-range transported dust

    NASA Astrophysics Data System (ADS)

    Fan, J.; Leung, L. R.; DeMott, P. J.; Comstock, J. M.; Singh, B.; Rosenfeld, D.; Tomlinson, J. M.; White, A.; Prather, K. A.; Minnis, P.; Ayers, J. K.; Min, Q.

    2013-07-01

    Mineral dust aerosols often observed over California in winter/spring, associated with long-range transport from Asia and Sahara, have been linked to enhanced precipitation based on observations. Local anthropogenic pollution, on the other hand, was shown in previous observational and modeling studies to reduce precipitation. Here we incorporate recent developments in ice nucleation parameterizations to link aerosols with ice crystal formation in a spectral-bin cloud microphysical model coupled with the Weather Research and Forecasting (WRF) model, to examine the relative and combined impacts of dust and local pollution particles on cloud properties and precipitation type and intensity. Simulations are carried out for two cloud cases with contrasting meteorology and cloud dynamics that occurred on 16 February (FEB16) and 2 March (MAR02) from the CalWater 2011 field campaign. In both cases, observations show the presence of dust or dust/biological particles in a relative pristine environment. The simulated cloud microphysical properties and precipitation show reasonable agreement with aircraft and surface measurements. Model sensitivity experiments indicate that in the pristine environment, the dust/biological aerosol layers increase the accumulated precipitation by 10-20% from the Central Valley to the Sierra Nevada Mountains for both FEB16 and MAR02 due to a 40% increase in snow formation, validating the observational hypothesis. Model results show that local pollution increases precipitation over the windward slope of the mountains by few percent due to increased snow formation when dust is present but reduces precipitation by 5-8% if dust is removed on FEB16. The effects of local pollution on cloud microphysics and precipitation strongly depend on meteorology including the strength of the Sierra Barrier Jet, and cloud dynamics. This study further underscores the importance of the interactions between local pollution, dust, and environmental conditions for

  9. Aerosol impacts on California winter clouds and precipitation during CalWater 2011: local pollution versus long-range transported dust

    NASA Astrophysics Data System (ADS)

    Fan, J.; Leung, L. R.; DeMott, P. J.; Comstock, J. M.; Singh, B.; Rosenfeld, D.; Tomlinson, J. M.; White, A.; Prather, K. A.; Minnis, P.; Ayers, J. K.; Min, Q.

    2014-01-01

    Mineral dust aerosols often observed over California in winter and spring, associated with long-range transport from Asia and the Sahara, have been linked to enhanced precipitation based on observations. Local anthropogenic pollution, on the other hand, was shown in previous observational and modeling studies to reduce precipitation. Here we incorporate recent developments in ice nucleation parameterizations to link aerosols with ice crystal formation in a spectral-bin cloud microphysical model coupled with the Weather Research and Forecasting (WRF) model in order to examine the relative and combined impacts of dust and local pollution particles on cloud properties and precipitation type and intensity. Simulations are carried out for two cloud cases (from the CalWater 2011 field campaign) with contrasting meteorology and cloud dynamics that occurred on 16 February (FEB16) and 2 March (MAR02). In both cases, observations show the presence of dust and biological particles in a relative pristine environment. The simulated cloud microphysical properties and precipitation show reasonable agreement with aircraft and surface measurements. Model sensitivity experiments indicate that in the pristine environment, the dust and biological aerosol layers increase the accumulated precipitation by 10-20% from the Central Valley to the Sierra Nevada for both FEB16 and MAR02 due to a ~40% increase in snow formation, validating the observational hypothesis. Model results show that local pollution increases precipitation over the windward slope of the mountains by a few percent due to increased snow formation when dust is present, but reduces precipitation by 5-8% if dust is removed on FEB16. The effects of local pollution on cloud microphysics and precipitation strongly depend on meteorology, including cloud dynamics and the strength of the Sierra Barrier Jet. This study further underscores the importance of the interactions between local pollution, dust, and environmental

  10. Nanoparticles with photoinduced precipitation for the extraction of pollutants from water and soil

    PubMed Central

    Brandl, Ferdinand; Bertrand, Nicolas; Lima, Eliana Martins; Langer, Robert

    2015-01-01

    Nanotechnology may offer fast and effective solutions for environmental clean-up. Herein, amphiphilic diblock copolymers are used to develop a platform of photosensitive core-shell nanoparticles. Irradiation with ultraviolet light removes the protective layer responsible for colloidal stability; as a result, the nanoparticles are rapidly and irreversibly converted to macroscopic aggregates. The associated phase separation allows measuring the partitioning of small molecules between the aqueous phase and nanoparticles; data suggests that interactions are enhanced by decreasing the particle size. Adsorption onto nanoparticles can be exploited to efficiently remove hydrophobic pollutants from water and contaminated soil. Preliminary in vivo experiments suggest that treatment with photocleavable nanoparticles can significantly reduce the teratogenicity of bisphenol A, triclosan and 17α-ethinyl estradiol without generating obviously toxic byproducts. Small-scale pilot experiments on wastewater, thermal printing paper and contaminated soil demonstrate the applicability of the approach. PMID:26196119

  11. Nanoparticles with photoinduced precipitation for the extraction of pollutants from water and soil.

    PubMed

    Brandl, Ferdinand; Bertrand, Nicolas; Lima, Eliana Martins; Langer, Robert

    2015-07-21

    Nanotechnology may offer fast and effective solutions for environmental clean-up. Herein, amphiphilic diblock copolymers are used to develop a platform of photosensitive core-shell nanoparticles. Irradiation with ultraviolet light removes the protective layer responsible for colloidal stability; as a result, the nanoparticles are rapidly and irreversibly converted to macroscopic aggregates. The associated phase separation allows measuring the partitioning of small molecules between the aqueous phase and nanoparticles; data suggests that interactions are enhanced by decreasing the particle size. Adsorption onto nanoparticles can be exploited to efficiently remove hydrophobic pollutants from water and contaminated soil. Preliminary in vivo experiments suggest that treatment with photocleavable nanoparticles can significantly reduce the teratogenicity of bisphenol A, triclosan and 17α-ethinyl estradiol without generating obviously toxic byproducts. Small-scale pilot experiments on wastewater, thermal printing paper and contaminated soil demonstrate the applicability of the approach.

  12. Nanoparticles with photoinduced precipitation for the extraction of pollutants from water and soil

    NASA Astrophysics Data System (ADS)

    Brandl, Ferdinand; Bertrand, Nicolas; Lima, Eliana Martins; Langer, Robert

    2015-07-01

    Nanotechnology may offer fast and effective solutions for environmental clean-up. Herein, amphiphilic diblock copolymers are used to develop a platform of photosensitive core-shell nanoparticles. Irradiation with ultraviolet light removes the protective layer responsible for colloidal stability; as a result, the nanoparticles are rapidly and irreversibly converted to macroscopic aggregates. The associated phase separation allows measuring the partitioning of small molecules between the aqueous phase and nanoparticles; data suggests that interactions are enhanced by decreasing the particle size. Adsorption onto nanoparticles can be exploited to efficiently remove hydrophobic pollutants from water and contaminated soil. Preliminary in vivo experiments suggest that treatment with photocleavable nanoparticles can significantly reduce the teratogenicity of bisphenol A, triclosan and 17α-ethinyl estradiol without generating obviously toxic byproducts. Small-scale pilot experiments on wastewater, thermal printing paper and contaminated soil demonstrate the applicability of the approach.

  13. Detecting 1mm/Year Signals in Altimetric Global Sea Level: Effect of Atmospheric Water Vapor and Precipitation

    NASA Technical Reports Server (NTRS)

    Zlotnicki, Victor

    1999-01-01

    Several research efforts exist to use Topography Experiment (TOPEX)/ Projet d'Observatorie de Surveillance et d'Etudes Integrees de la Dynamique des Oceans (Poseidon) (T/P) to detect changes in global sea level possibly associated with climate change. This requires much better than 1 mm/yr accuracy, something that none of the instruments in T/P [or the European Remote Sensing (ERS-2) satellite, or the U.S. Navy's Geosat Follow-On (GFO) satellite] were designed for. This work focuses on the ability of the T/P microwave radiometer (TMR) to retrieve the path delay due to atmospheric water vapor along the altimeter's path with accuracy in the time changes below 1 mm/yr on global average. In collaboration with Stephen Keihm of JPL and Christopher Ruf of Pennsylvania State University, we compared TMR path delay (PD) estimates with atmospheric precipitable water (PW) from the Special Sensor Microwave Imager (SSMI) aboard the Defense Meteorological Satellite Program (DMSP) series of satellites for 1992-1998 to selected radiosondes, and we also looked at the brightness temperatures measured by TMR in the lowest 1% of the histogram. The conclusion is that TMR had a slow instrumental drift, associated with the 18-GHz channel, which causes an approximate underestimation of water vapor at a rate equivalent to 1.2 mm/yr in path delay between 1992 and 1996; this effect stopped and no drift is detected in 1997. The same study concluded that there is no detectable scale error (one which is proportional to measured vapor) in TMR. In related work, carried out with graduate student Damien Cailliau, we investigated the relative abilities of TMR, SSMI and the UP dual-frequency radar altimeter to detect rain, relative to a climatology of shipborne observations. Rain is a crucial but poorly measured variable in studies of the climate system, and a dedicated mission, Tropical Rainfall Measuring Mission (TRMM), was recently launched to measure it. However, the climatologies built over the

  14. Precipitation, streamflow and water quality data from selected sites in the City of Charlotte and Mecklenburg County, North Carolina, 1995-97

    USGS Publications Warehouse

    Robinson, J.B.; Hazell, W.F.; Garrett, R.G.

    1998-01-01

    Precipitation data were collected at 46 precipitation sites and 3 atmospheric deposition sites, and hydrologic data were collected at 9 stream sites in the vicinity of Charlotte and Mecklenburg County, North Carolina, from July 1995 through June 1997. Data were collected to identify the type, concentration, and amount of nonpoint-source stormwater runoff within the area. The data collected include measurements of precipitation; streamflow; physical characteristics, such as water temperature, pH, specific conductance, biochemical oxygen demand, oil and grease, and suspended sediment concentrations; and concentrations of nutrients, metals and minor constituents, and organic compounds. These data should provide valuable information needed for (1) planned watershed simulation models, (2) estimates of nonpoint-source constituent loadings to the Catawba River, and (3) characterization of water quality in relation to basin conditions. Streamflow and rainfall data have been used to provide early warning of possible flooding.

  15. Physical retrieval of precipitation water contents from Special Sensor Microwave/Imager (SSM/I) data. Part 2: Retrieval method and applications (report version)

    NASA Technical Reports Server (NTRS)

    Olson, William S.

    1990-01-01

    A physical retrieval method for estimating precipitating water distributions and other geophysical parameters based upon measurements from the DMSP-F8 SSM/I is developed. Three unique features of the retrieval method are (1) sensor antenna patterns are explicitly included to accommodate varying channel resolution; (2) precipitation-brightness temperature relationships are quantified using the cloud ensemble/radiative parameterization; and (3) spatial constraints are imposed for certain background parameters, such as humidity, which vary more slowly in the horizontal than the cloud and precipitation water contents. The general framework of the method will facilitate the incorporation of measurements from the SSMJT, SSM/T-2 and geostationary infrared measurements, as well as information from conventional sources (e.g., radiosondes) or numerical forecast model fields.

  16. Precipitation, atmospheric deposition, streamflow, and water-quality data from selected sites in the city of Charlotte and Mecklenburg County, North Carolina, 1997-98

    USGS Publications Warehouse

    Sarver, Kathleen M.; Hazell, W.F.; Robinson, J.B.

    1999-01-01

    Precipitation data were collected at 46 precipitation sites and 3 atmospheric deposition sites, and hydrologic data were collected at 6 stream sites in the vicinity of Charlotte and Mecklenburg County, North Carolina, from July 1997 through September 1998. Data were collected to identify the type, concentration, and amount of nonpoint- source stormwater runoff in the study area. The data collected include measurements of precipitation; streamflow; physical characteristics, such as water temperature, pH, specific conductance, biochemical oxygen demand, oil and grease, and suspended-sediment concentrations; and concentrations of nutrients, metals and minor constituents, and organic compounds. These data will provide information needed for (1) planned watershed simulation models, (2) estimates of nonpoint-source constituent loadings to the Catawba River, and (3) characterization of water quality in relation to basin conditions. Streamflow and rainfall data have been used to provide early warnings of possible flooding.

  17. Intercomparisons of Total Precipitable Water from Satellite and Other Long Term Data Sets

    NASA Technical Reports Server (NTRS)

    Chang, Fong-Chiau; Jedlovec, Gary J.; Suggs, Ronnie J.; Guillory, Anthony R.

    1998-01-01

    Global water vapor data sets from satellite (NVAP) and reanalysis (NCEP and DAO) are intercompared for a 5 year period (1988-1992). Global average indicates that the NCEP and DAO reanalyses are dryer than NVAP over much of the period. Spatial patterns of the NCEP/NVAP and DAO/NVAP differences show regional variations in the 60 month climatogical fields. For example, in the Eastern Pacific just south of the equator NVAP is much dryer than the NCEP and more moist than DAO. Rather large discrepancies exist in other regions as well. North Africa, Saudi Arabia, India, and Australia show that NVAP TPW values are more moist than the NCEP and DAO model analyses by 4-8 mm. In general, the NCEP and DAO exhibits a tendency to be dryer than NVAP over the tropical ocean region. Over the Americas little differences exist except over the west coast. The shapes of the differences fields over the Eastern Pacific region are significantly different between NCEP/NVAP and DAO/NVAP differences. Over South America and Central Africa, DAO TPW values are significantly higher than those of NVAP. These difference fields show monthly and seasonal variability as well. These results will be highlighted in the paper and on the poster.

  18. Enhanced bioavailability of a poorly water-soluble weakly basic compound using a combination approach of solubilization agents and precipitation inhibitors: a case study.

    PubMed

    Li, Shu; Pollock-Dove, Crystal; Dong, Liang C; Chen, Jing; Creasey, Abla A; Dai, Wei-Guo

    2012-05-07

    Poorly water-soluble weakly basic compounds which are solubilized in gastric fluid are likely to precipitate after the solution empties from the stomach into the small intestine, leading to a low oral bioavailability. In this study, we reported an approach of combining solubilization agents and precipitation inhibitors to produce a supersaturated drug concentration and to prolong such a drug concentration for an extended period of time for an optimal absorption, thereby improving oral bioavailability of poorly water-soluble drugs. A weakly basic compound from Johnson and Johnson Pharmaceutical Research and Development was used as a model compound. A parallel microscreening precipitation method using 96-well plates and a TECAN robot was used to assess the precipitation of the tested compound in the simulated gastric fluid (SGF) and the simulated intestinal fluid (SIF), respectively, for lead solubilizing agents and precipitation inhibitors. The precipitation screening results showed vitamin E TPGS was an effective solubilizing agent and Pluronic F127 was a potent precipitation inhibitor for the tested compound. Interestingly, the combination of Pluronic F127 with vitamin E TPGS resulted in a synergistic effect in prolonging compound concentration upon dilution in SIF. In addition, HPMC E5 and Eudragit L100-55 were found to be effective precipitation inhibitors for the tested compounds in SGF. Furthermore, optimization DOE study results suggested a formulation sweet spot comprising HPMC, Eudragit L 100-55, vitamin E TPGS, and Pluronic F127. The lead formulation maintained the tested compound concentration at 300 μg/mL upon dilution in SIF, and more than 70% of the compound remained solubilized compared with the compound alone at <1 μg/mL of its concentration. Dosing of the solid dosage form predissolved in SGF in dogs resulted in 52% of oral bioavailability compared to 26% for the suspension control, a statistically significant increase (p = 0.002). The enhanced

  19. Modifying the 'pulse-reserve' paradigm for deserts of North America: precipitation pulses, soil water, and plant responses.

    PubMed

    Reynolds, James F; Kemp, Paul R; Ogle, Kiona; Fernández, Roberto J

    2004-10-01

    The 'pulse-reserve' conceptual model--arguably one of the most-cited paradigms in aridland ecology--depicts a simple, direct relationship between rainfall, which triggers pulses of plant growth, and reserves of carbon and energy. While the heuristics of 'pulses', 'triggers' and 'reserves' are intuitive and thus appealing, the value of the paradigm is limited, both as a conceptual model of how pulsed water inputs are translated into primary production and as a framework for developing quantitative models. To overcome these limitations, we propose a revision of the pulse-reserve model that emphasizes the following: (1) what explicitly constitutes a biologically significant 'rainfall pulse', (2) how do rainfall pulses translate into usable 'soil moisture pulses', and (3) how are soil moisture pulses differentially utilized by various plant functional types (FTs) in terms of growth? We explore these questions using the patch arid lands simulation (PALS) model for sites in the Mojave, Sonoran, and Chihuahuan deserts of North America. Our analyses indicate that rainfall variability is best understood in terms of sequences of rainfall events that produce biologically-significant 'pulses' of soil moisture recharge, as opposed to individual rain events. In the desert regions investigated, biologically significant pulses of soil moisture occur in either winter (October-March) or summer (July-September), as determined by the period of activity of the plant FTs. Nevertheless, it is difficult to make generalizations regarding specific growth responses to moisture pulses, because of the strong effects of and interactions between precipitation, antecedent soil moisture, and plant FT responses, all of which vary among deserts and seasons. Our results further suggest that, in most soil types and in most seasons, there is little separation of soil water with depth. Thus, coexistence of plant FTs in a single patch as examined in this PALS study is likely to be fostered by factors

  20. My NASA Data Precipitation

    NASA Video Gallery

    This lesson has two activities that help students develop a basic understanding of the relationship between cloud type and the form of precipitation and the relationship between the amount of water...

  1. Impact of Atmospheric Infrared Sounder (AIRS) Thermodynamic Profiles on Regional Precipitation Forecasting

    NASA Technical Reports Server (NTRS)

    Chou, S.-H.; Zavodsky, B. T.; Jedloved, G. J.

    2010-01-01

    In data sparse regions, remotely-sensed observations can be used to improve analyses and lead to better forecasts. One such source comes from the Atmospheric Infrared Sounder (AIRS), which together with the Advanced Microwave Sounding Unit (AMSU), provides temperature and moisture profiles in clear and cloudy regions with accuracy which approaches that of radiosondes. The purpose of this paper is to describe an approach to assimilate AIRS thermodynamic profile data into a regional configuration of the Advanced Research WRF (ARW) model using WRF-Var. Quality indicators are used to select only the highest quality temperature and moisture profiles for assimilation in clear and partly cloudy regions, and uncontaminated portions of retrievals above clouds in overcast regions. Separate error characteristics for land and water profiles are also used in the assimilation process. Assimilation results indicate that AIRS profiles produce an analysis closer to in situ observations than the background field. Forecasts from a 37-day case study period in the winter of 2007 show that AIRS profile data can lead to improvements in 6-h cumulative precipitation forecasts resulting from improved thermodynamic fields. Additionally, in a convective heavy rainfall event from February 2007, assimilation of AIRS profiles produces a more unstable boundary layer resulting in enhanced updrafts in the model. These updrafts produce a squall line and precipitation totals that more closely reflect ground-based observations than a no AIRS control forecast. The location of available high-quality AIRS profiles ahead of approaching storm systems is found to be of paramount importance to the amount of impact the observations will have on the resulting forecasts.

  2. Dynamic interactions of dissolution, surface adsorption, and precipitation in an aging cobalt(II)-clay-water system

    NASA Astrophysics Data System (ADS)

    Thompson, Hillary A.; Parks, George A.; Brown, Gordon E.

    1999-06-01

    We have studied the dynamic interactions of mineral dissolution, cation surface adsorption, and precipitation in aqueous slurries initially containing kaolinite and millimolar quantities of cobalt(II) in 0.1 molar NaNO 3 solution. Batch slurries spent an initial 24 hours at pH 4.2, then NaOH was added to increase pH to 7.8, where pH was maintained for several months. Dissolved Co, Al, and Si concentrations were monitored by ICP-MS; solid-phase products were characterized using EXAFS and TEM. At low pH, kaolinite dissolved, releasing Al and Si to solution. Aluminum hydroxide and aluminosilicate phases precipitated rapidly as pH increased. Cobalt uptake from solution began as pH increased and continued throughout the remainder of the experiment. Rapid surface adsorption and precipitation accounted for early Co uptake; much slower precipitation caused continued Co uptake. Cobalt adsorbed on kaolinite in the form of hydroxy-bridged polymers or multimers and precipitated as a hydrotalcite-like solid that contained aluminum ions derived from kaolinite and aluminum hydroxide dissolution. The cobalt hydrotalcite precipitate had the approximate stoichiometry [Co 6Al 2(OH) 16(A n-) 2/n], with nitrate or silicate anions occupying A sites. Precipitate particles were several nanometers in diameter and some probably precipitated homogeneously. Some of the Co originally adsorbed was later incorporated into precipitate. Slow kaolinite dissolution near neutral pH limited the rate of Co uptake by precipitation, thereby accounting for the slow second stage of Co uptake. Continued changes in solution composition indicate that even this relatively simple system did not reach equilibrium under fixed solution conditions after several months. For this set of conditions, cobalt hydrotalcite appears to be the stable Co-containing phase, and its precipitation can reduce dissolved metal ion concentrations below levels achievable by simple adsorption on kaolinite.

  3. Dynamic interactions of dissolution, surface adsorption, and precipitation in an aging cobalt(II)-clay-water system

    SciTech Connect

    Thompson, H.A.; Parks, G.A.; Brown, G.E. Jr. |

    1999-06-01

    The authors have studied the dynamic interactions of mineral dissolution, cation surface adsorption, and precipitation in aqueous slurries initially containing kaolinite and millimolar quantities of cobalt(II) in 0.1 molar NaNO{sub 3} solution. Batch slurries spent an initial 24 hours at pH 4.2, then NaOH was added to increase pH to 7.8, where pH was maintained for several months. Dissolved Co, Al, and Si concentrations were monitored by ICP-MS; solid-phase products were characterized using EXAFS and TEM. At low pH, kaolinite dissolved, releasing Al and Si to solution. Aluminum hydroxide and aluminosilicate phases precipitated rapidly as pH increased. Cobalt uptake from solution began as pH increased and continued throughout the remainder of the experiment. Rapid surface adsorption and precipitation accounted for early Co uptake; much slower precipitation caused continued Co uptake. Cobalt adsorbed on kaolinite in the form of hydroxy-bridged polymers or multimers and precipitated as a hydrotalcite-like solid that contained aluminum ions derived from kaolinite and aluminum hydroxide dissolution. The cobalt hydrotalcite precipitate had the approximate stoichiometry [Co{sub 6}Al{sub 2}(OH){sub 16}(N{sup n{minus}}){sub 2/n}], with nitrate or silicate anions occupying A sites. Precipitate particles were several nanometers in diameter and some probably precipitated homogeneously. Some of the Co originally adsorbed was later incorporated into precipitate. Slow kaolinite dissolution near neutral pH limited the rate of Co uptake by precipitation, thereby accounting for the slow second stage of Co uptake. Continued changes in solution composition indicate that even this relatively simple system did not reach equilibrium under fixed solution conditions after several months. For this set of conditions, cobalt hydrotalcite appears to be the stable Co-containing phase, and its precipitation can reduce dissolved metal ion concentrations below levels achievable by simple

  4. Characterization and interaction of precipitation, river water and groundwater in the Vietnamese Mekong Delta - A case study in the Plain of Reeds

    NASA Astrophysics Data System (ADS)

    Duy Nguyen, Le; Heidbüchel, Ingo; Merz, Bruno; Apel, Heiko

    2016-04-01

    An understanding of the interactions between surface water and groundwater systems in the Vietnamese Mekong Delta (VMD) is important not only for water resources planning and management, but also for the livelihood of the majority of the population in the delta. Precipitation and ground water, but also river water is used as drinking water in the communes of the Delta. Particularly the ground water is increasingly exploited, but the important processes like river - aquifer interaction and ground water recharge rates are largely unknown. This study thus aims at the characterization of processes between the different water resources. For this the different water sources were sampled over longer time periods and analysed for isotopic composition (2H, 18O). Additionally surface and ground water levels were recorded, as well as the temperature profile at and under the river bed in order to identify the river-ground water interaction. First results indicate that the isotopic composition and the local meteoric water line of the precipitation is very similar to the GNIP data for Bangkok, indicating similar isotopic sequestration and origin of the rainfall in the region (near ocean areas of SE-Asia). The isotopic composition of precipitation and river water exhibits a strong seasonal signal indicating the monsoonal influence. During the monsoon season both precipitation and river water is depleted in stable isotopes, while the dry season shows an enriched composition. This also indicates the different composition of the river water over the seasons. During the rainy season the portion of rain water, i.e. surface runoff stemming from the Mekong basin but also direct rainfall contribution in the Mekong Delta is considerably larger, as expected. The enriched composition during the dry season indicates a larger ground water, i.e. base flow portion, but also a generally higher evaporation due to the lower atmospheric moisture. The isotopic composition of the ground water differs

  5. Total ozone column, aerosol optical depth and precipitable water effects on solar erythemal ultraviolet radiation recorded in Malta.

    NASA Astrophysics Data System (ADS)

    Bilbao, Julia; Román, Roberto; Yousif, Charles; Mateos, David; Miguel, Argimiro

    2013-04-01

    The Universities of Malta and Valladolid (Spain) developed a measurement campaign, which took place in the Institute for Energy Technology in Marsaxlokk (Southern Malta) between May and October 2012, and it was supported by the Spanish government through the Project titled "Measurement campaign about Solar Radiation, Ozone, and Aerosol in the Mediterranean area" (with reference CGL2010-12140-E). This campaign provided the first ground-based measurements in Malta of erythemal radiation and UV index, which indicate the effectiveness of the sun exposure to produce sunburn on human skin. A wide variety of instruments was involved in the campaign, providing a complete atmospheric characterization. Data of erythemal radiation and UV index (from UVB-1 pyranometer), total shortwave radiaton (global and diffuse components from CM-6B pyranometers), and total ozone column, aerosol optical thickness, and precitable water column (from a Microtops-II sunphotometer) were available in the campaign. Ground-based and satellite instruments were used in the analysis, and several intercomparisons were carried out to validate remote sensing data. OMI, GOME, GOME-2, and MODIS instruments, which provide data of ozone, aerosol load and optical properties, were used to this end. The effects on solar radiation, ultraviolet and total shortwave ranges, of total ozone column, aerosol optical thickness and precipitable water column were obtained using radiation measurements at different fixed solar zenith angles. The empirical results shown a determinant role of the solar position, a negligible effect of ozone on total shortwave radiation, and a stronger attenuation provided by aerosol particles in the erythemal radiation. A variety of aerosol types from different sources (desert dust, biomass burning, continental, and maritime) reach Malta, in this campaign several dust events from the Sahara desert occurred and were analyzed establishing the air mass back-trajectories ending at Malta at

  6. Study on the properties of the Integrated Precipitable Water (IPW) maps derived by GPS, SAR interferometry and numerical forecasting models

    NASA Astrophysics Data System (ADS)

    Mateus, Pedro; Nico, Giovanni; Tomé, Ricardo; Catalão, João.; Miranda, Pedro

    2010-05-01

    The knowledge of spatial distribution of relative changes in atmospheric Integrated Precipitable Water (IPW) density is important for climate studies and numerical weather forecasting. An increase (or decrease) of the IPW density affects the phase of electromagnetic waves. For this reason, this quantity can be measured by techniques such as GPS and space-borne SAR interferometry (InSAR). The aim of this work is to study the isotropic properties of the IPW maps obtained by GPS and SAR InSAR measurements and derived by a Numerical Weather Forecasting Model. The existence of a power law in their phase spectrum is verified. The relationship between the interferometric phase delay and the topographic height of the observed area is also investigated. The Lisbon region, Portugal, was chosen as a study area. This region is monitored by a network of GPS permanent stations covering an area of about squared kilometers. The network consists of 12 GPS stations of which 4 belonging to the Instituto Geográfico Português (IGP) and 8 to Instituto Geográfico do Exercito (IGEOE). All stations were installed between 1997 and the beginning of 2009. The GAMIT package was used to process GPS data and to estimate the total zenith delay with a temporal sampling of 15 minutes. A set of 25 SAR interferograms with a 35-day temporal baseline were processed using ASAR-ENVISAT data acquired over the Lisbon region during the period from 2003 to 2005 and from 2008 to 2009. These interferograms give an estimate of the variation of the global atmospheric delay. Terrain deformations related to known geological phenomena in the Lisbon area are negligible at this time scale of 35 days. Furthermore, two interferometric SAR images acquired by ERS-1/2 over the Lisbon region on 20/07/1995 and 21/07/1995, respectively, and so with a temporal baseline of just 1 day, were also processed. The Weather Research & Forecasting Model (WRF) was used to generate the three-dimensional fields of temperature

  7. Aerosol Impacts on California Winter Clouds and Precipitation during CalWater 2011: Local Pollution versus Long-Range Transported Dust

    NASA Astrophysics Data System (ADS)

    Fan, J.; Leung, L.; DeMott, P. J.; Comstock, J. M.; Singh, B.; Rosenfeld, D.; Tomlinson, J. M.; White, A. B.; Prather, K. A.; Minnis, P.

    2013-12-01

    Mineral dust aerosols often observed over California in winter/spring, associated with long-range transport from Asia and Sahara, have been linked to enhanced precipitation based on observations. Local anthropogenic pollution, on the other hand, was shown in previous observational and modeling studies to reduce precipitation. Here we incorporate recent developments in ice nucleation parameterizations to link aerosols with ice crystal formation in a spectral-bin cloud microphysical model coupled with the Weather Research and Forecasting (WRF) model, to examine the relative and combined impacts of dust and local pollution particles on cloud properties and precipitation type and intensity. Simulations are carried out for two cloud cases with contrasting meteorology and cloud dynamics that occurred on February 16 (FEB16) and March 02 (MAR02) from the CalWater 2011 field campaign. Simulations are carried out for two cloud cases with contrasting meteorology and cloud dynamics that occurred on February 16 (FEB16) and March 02 (MAR02) from the CalWater 2011 field campaign. In both cases, observations show the presence of dust or dust/biological particles in a relative pristine environment. The simulated cloud microphysical properties and precipitation show reasonable agreement with aircraft and surface measurements. Model sensitivity experiments indicate that in the pristine environment, the dust/biological aerosol layers increase the accumulated precipitation by 10-20% from the Central Valley to the Sierra Nevada Mountains for both FEB06 and MAR02 due to a ~40% increase in snow formation, validating the observational hypothesis. Model results show that local pollution increases precipitation over the windward slope of the mountains by few percent due to increased snow formation when dust is present but reduces precipitation by 5-8% if dust is removed on FEB16. The effects of local pollution on cloud microphysics and precipitation strongly depend on meteorology including

  8. Hydrological Modeling of Storm Water Drainage System due to Frequent and Intense Precipitation of Dhaka city using Storm Water Management Model (SWMM)

    NASA Astrophysics Data System (ADS)

    Hossain, S., Jr.

    2015-12-01

    Rainfall induced flooding during rainy season is a regular phenomenon in Dhaka City. Almost every year a significant part of the city suffers badly with drainage congestion. There are some highly dense areas with lower ground elevation which submerge under water even with an intense precipitation of few hours. The higher areas also suffer with the drainage problem due to inadequate maintenance of the system and encroachment or illegal filling up of the drainage canals and lakes. Most part of the city suffered from long term urban flooding during historical extreme rainfall events in September 2004, 2007 and July 2009. The situation is likely to worsen in the future due to Climate Change, which may lead to more frequent and intense precipitation. To assess the major and minor drainage systems and elements of the urban basins using the hydrodynamic modelling and, through this, identifying the flooding events and areas, taking into account the current situation and future flood or drainage scenarios. Stormwater modeling has a major role in preventing issues such as flash floods and urban water-quality problems. Stormwater models of a lowered spatial resolution would thus appear valuable if only their ability to provide realistic results could be proved. The present scenario of urban morphology of Dhaka city and existing drainage system is complex for hydrological and hydrodynamic modeling. Furthermore limitations of background data and uncertain future urban scenarios may confine the potential outputs of a model. Although several studies were carried out including modeling for drainage master planning, a detail model for whole DAP (Detaile Area Plan) of Dhaka city area is not available. The model developed under this study is covering the existing drainage system in the study area as well as natural flows in the fringe area. A good number of models are available for hydrological and hydraulic analysis of urban areas. These are MIKE 11, MOUSE, HEC-RAS, HEC HMS and EPA

  9. The Effect of Contrasting Wet and Dry Extreme Precipitation on Ecosystem Carbon Fluxes and Water Use Efficiency in the Southern Great Plains, United States

    NASA Astrophysics Data System (ADS)

    Zhang, J.; Felzer, B. S.

    2015-12-01

    Climate extremes, such as heat waves and heavy precipitation, are more likely to occur with increased warming and simultaneously have profound influences on ecosystem fluxes. Existing studies have already investigated how a single extreme event affects ecosystem dynamics. However, how ecosystems respond to consecutive climate extremes is rarely examined. More heat waves are expected to cause more droughts, while more heavy precipitation could cause more floods. Both may have a negative effect on vegetation growth, although wetter conditions may alternatively stimulate growth. In the southern Great Plains the hydrological year of 2006 was the second-driest year on record, with only 61% of long-term annual precipitation. In contrast, the summer of 2007 was the second-wettest summer, with 121% of the normal annual precipitation. This "pair" provides a unique example to study alternatively contrasting climate extremes and their impacts on ecosystem dynamics. In this study, we aim to assess whether or not this consecutive drought and flood has altered the sensitivity of ecosystem carbon fluxes and water use efficiency. To investigate this question, we parameterized a newly developed process-based terrestrial ecosystem model (TEM-Hydro daily version) and applied the Maurer's 1/8 degree daily climate datasets. The modeled results are compared against the MODIS datasets and Ameriflux Eddy Covariance observations to determine the mechanism responsible for understanding how extremes in precipitation affect ecosystem functions. The significance of the consecutive climate extremes on ecosystem structures and processes in the southern Great Plains will be discussed.

  10. Field Evaluation Of Arsenic Transport Across The Ground-Water/Surface Water Interface: Ground-Water Discharge And Iron Oxide Precipitation

    EPA Science Inventory

    A field investigation was conducted to examine the distribution of arsenic in ground water, surface water, and sediments at a Superfund Site in the northeastern United States (see companion presentation by K. G. Scheckel et al). Ground-water discharge into the study area was cha...

  11. A model for the spatial distribution of snow water equivalent parameterized from the spatial variability of precipitation

    NASA Astrophysics Data System (ADS)

    Skaugen, Thomas; Weltzien, Ingunn H.

    2016-09-01

    Snow is an important and complicated element in hydrological modelling. The traditional catchment hydrological model with its many free calibration parameters, also in snow sub-models, is not a well-suited tool for predicting conditions for which it has not been calibrated. Such conditions include prediction in ungauged basins and assessing hydrological effects of climate change. In this study, a new model for the spatial distribution of snow water equivalent (SWE), parameterized solely from observed spatial variability of precipitation, is compared with the current snow distribution model used in the operational flood forecasting models in Norway. The former model uses a dynamic gamma distribution and is called Snow Distribution_Gamma, (SD_G), whereas the latter model has a fixed, calibrated coefficient of variation, which parameterizes a log-normal model for snow distribution and is called Snow Distribution_Log-Normal (SD_LN). The two models are implemented in the parameter parsimonious rainfall-runoff model Distance Distribution Dynamics (DDD), and their capability for predicting runoff, SWE and snow-covered area (SCA) is tested and compared for 71 Norwegian catchments. The calibration period is 1985-2000 and validation period is 2000-2014. Results show that SDG better simulates SCA when compared with MODIS satellite-derived snow cover. In addition, SWE is simulated more realistically in that seasonal snow is melted out and the building up of "snow towers" and giving spurious positive trends in SWE, typical for SD_LN, is prevented. The precision of runoff simulations using SDG is slightly inferior, with a reduction in Nash-Sutcliffe and Kling-Gupta efficiency criterion of 0.01, but it is shown that the high precision in runoff prediction using SD_LN is accompanied with erroneous simulations of SWE.

  12. Estimation of precipitable water vapour using kinematic GNSS precise point positioning over an altitude range of 1 km

    NASA Astrophysics Data System (ADS)

    Webb, S. R.; Penna, N. T.; Clarke, P. J.; Webster, S.; Martin, I.

    2013-12-01

    The estimation of total precipitable water vapour (PWV) using kinematic GNSS has been investigated since around 2001, aiming to extend the use of static ground-based GNSS, from which PWV estimates are now operationally assimilated into numerical weather prediction models. To date, kinematic GNSS PWV studies suggest a PWV measurement agreement with radiosondes of 2-3 mm, almost commensurate with static GNSS measurement accuracy, but only shipborne experiments have so far been carried out. As a first step towards extending such sea level-based studies to platforms that operate at a range of altitudes, such as airplanes or land based vehicles, the kinematic GNSS estimation of PWV over an exactly repeated trajectory is considered. A data set was collected from a GNSS receiver and antenna mounted on a carriage of the Snowdon Mountain Railway, UK, which continually ascends and descends through 950 m of vertical relief. Static GNSS reference receivers were installed at the top and bottom of the altitude profile, and derived zenith wet delay (ZWD) was interpolated to the altitude of the train to provide reference values together with profile estimates from the 100 m resolution runs of the Met Office's Unified Model. We demonstrate similar GNSS accuracies as obtained from previous shipborne studies, namely a double difference relative kinematic GNSS ZWD accuracy within 14 mm, and a kinematic GNSS precise point positioning ZWD accuracy within 15 mm. The latter is a more typical airborne PWV estimation scenario i.e. without the reliance on ground-based GNSS reference stations. We show that the kinematic GPS-only precise point positioning ZWD estimation is enhanced by also incorporating GLONASS observations.

  13. Response of vegetation and carbon accumulation to changes in precipitation and water table depths in two bogs during the Holocene: a modelling exercise

    NASA Astrophysics Data System (ADS)

    Quillet, A.; Garneau, M.; van Bellen, S.; Frolking, S. E.; Tuittila, E.

    2013-12-01

    To assess the influence of hydrological changes on northern peatland ecosystems, we analysed the response of the Holocene Peat Model (HPM, Frolking et al. 2010), designed to simulate peatland development at millennial timescale, to two hydrological settings, based on precipitation and water table depths reconstructions. The studied sites are two open ombrotrophic peatlands located in the James Bay Lowlands in Northeastern Canada. For both sites, two simulations were realised: one based on a precipitation reconstruction from pollen data, used as input in the model, and a second using a water table depth reconstruction derived from testate amoebae to apply a water table forcing on the model. Simulated variations in carbon accumulation rates (CAR) and vegetation composition were analysed against the palaeoecological datasets. Results in CAR in both sites and hydrological settings showed periods of net carbon loss, which coincided with fluctuations in observed CAR, though they cannot be traced in palaeoecological datasets. The comparison between plant macrofossils records and simulated vegetation distributions highlighted differences between precipitation and water table depth driven simulations that can be used to distinguish the origin of vegetation shifts. The methodology used could thus be useful in paleoecological studies when two or more proxies are available.

  14. Agricultural intensification, hydrologic alteration, and increasing precipitation in the US Midwest: Implications for hydrology and water quality

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Agriculture in the US Midwest is experiencing changes in climate impacting crop production systems. Climatic shifts show increases in precipitation, and particularly increased frequency of high intensity events. Meanwhile, agricultural production systems are responding to the demand for biofuel prod...

  15. USGS48 Puerto Rico precipitation - A new isotopic reference material for δ2H and δ18O measurements of water

    USGS Publications Warehouse

    Qi, Haiping; Coplen, Tyler B.; Tarbox, Lauren V.; Lorenz, Jennifer M.; Scholl, Martha A.

    2014-01-01

    A new secondary isotopic reference material has been prepared from Puerto Rico precipitation, which was filtered, homogenised, loaded into glass ampoules, sealed with a torch, autoclaved to eliminate biological activity, and calibrated by dual-inlet isotope-ratio mass spectrometry. This isotopic reference material, designated as USGS48, is intended to be one of two isotopic reference waters for daily normalisation of stable hydrogen (δ2H) and stable oxygen (δ18O) isotopic analysis of water with a mass spectrometer or a laser absorption spectrometer. The δ2H and δ18O values of this reference water are−2.0±0.4 and−2.224±0.012 ‰, respectively, relative to Vienna Standard Mean Ocean Water on scales normalised such that the δ2H and δ18O values of Standard Light Antarctic Precipitation reference water are−428 and−55.5 ‰, respectively. Each uncertainty is an estimated expanded uncertainty (U=2uc) about the reference value that provides an interval that has about a 95 % probability of encompassing the true value. This isotopic reference water is available by the case of 144 glass ampoules containing 5 mL of water in each ampoule.

  16. The influence of dissolved Si on Ni precipitate formation at the kaolinite water interface: Kinetics, DRS and EXAFS analysis.

    PubMed

    Tan, Xiaoli; Liu, Ge; Mei, Huiyang; Fang, Ming; Ren, Xuemei; Chen, Changlun

    2017-04-01

    Unraveling the formation process of Ni precipitates at molecular scale is important for understanding the fate and mobility of Ni species in the real environment. Dissolved Si presents in the natural environment ubiquitously, which can alter Ni sorption as well as incorporation into neoformed precipitates. Batch experiments show that the dissolved Si leads to a rapid increase in the Ni sorption rate and interferes with the formation of Ni precipitates. The results of diffuse reflectance spectroscopy (DRS) and extended X-ray absorption fine structure (EXAFS) spectroscopy analyses suggest that the nucleation of a (Ni,Al) phyllosilicate phase involves a kaolinite-like local structure. Then, the substantial presence of Si affects the initial formation of Ni precipitate nucleation and the resulting crystal growth. Dioctahedral kaolinite may act as a nucleating surface for the heterogeneous formation of trioctahedral (Ni,Al) phyllosilicates under environmentally relevant conditions. This study provides experimental evidence on nucleation and epitaxial growth processes of Ni precipitate on kaolinite and provides insight on the relationship between substrates and precipitation, which is crucial for understanding the physicochemical behavior of Ni on mineral surfaces.

  17. Concrete-Water-Interaction and Ikaite (CaCO3.6H2O) Precipitation in a Man-Made River Bed

    NASA Astrophysics Data System (ADS)

    Boch, R.; Dietzel, M.; Reichl, P.; Leis, A.; Pölt, P.; Baldermann, A.

    2014-12-01

    Centimetre-thick, beige-colored and soft crusts were observed shortly after construction of a man-made river bed, i.e. a small natural river was bypassed flowing through a new bed lined with concrete and blocks. Hydrochemical investigations during wintertime - when water temperatures dropped down close to freezing - showed surprisingly high pH values up to 13.0 and elevated Ca2+ concentrations up to 200 mg/l. Both, the artifical and natural (downstream) section of the river bed were affected by the anomalous hydrochemistry and formation of prominent secondary precipitates. In order to better understand the particular and rapid water-rock-interaction, a hydrochemical monitoring program was launched and several of the delicate precipitates were recovered in refrigerator boxes in their original solution. The samples were analyzed in the laboratory within a few hours after sampling and stored at 1 °C. XRD and FT-IR patterns clearly revealed the predominant occurrence of "ikaite" in the crusts next to minor amounts of other carbonates (calcite, aragonite, vaterite) and detrital minerals. Ikaite - calcium carbonate hexahydrate - is a worldwide rarely documented carbonate mineral. This mineral is metastable and needs particular and narrow conditions in order to precipitate from solutions, i.e. a very limited water-temperature range between 0 and 4 °C (with ambient-pressure and low-salinity), highly alkaline pH conditions, high supersaturation values, and in many cases carbonate precipitation inhibitors (e.g. phosphates). Outside these conditions it disintegrates into calcite and water within minutes to hours. The few places of ikaite formation include Ikka Fjord in Greenland, Arctic- and Antarctic sea-ice and some sites of water mixing at Mono Lake, California. Combining detailed field monitoring results, solid-phase analyses and regional meteorological data (rainfall, water discharge, temperature) with hydrogeochemical modeling allows constraining the mechanisms of

  18. GSFLOW - Coupled Ground-Water and Surface-Water Flow Model Based on the Integration of the Precipitation-Runoff Modeling System (PRMS) and the Modular Ground-Water Flow Model (MODFLOW-2005)

    USGS Publications Warehouse

    Markstrom, Steven L.; Niswonger, Richard G.; Regan, R. Steven; Prudic, David E.; Barlow, Paul M.

    2008-01-01

    The need to assess the effects of variability in climate, biota, geology, and human activities on water availability and flow requires the development of models that couple two or more components of the hydrologic cycle. An integrated hydrologic model called GSFLOW (Ground-water and Surface-water FLOW) was developed to simulate coupled ground-water and surface-water resources. The new model is based on the integration of the U.S. Geological Survey Precipitation-Runoff Modeling System (PRMS) and the U.S. Geological Survey Modular Ground-Water Flow Model (MODFLOW). Additional model components were developed, and existing components were modified, to facilitate integration of the models. Methods were developed to route flow among the PRMS Hydrologic Response Units (HRUs) and between the HRUs and the MODFLOW finite-difference cells. This report describes the organization, concepts, design, and mathematical formulation of all GSFLOW model components. An important aspect of the integrated model design is its ability to conserve water mass and to provide comprehensive water budgets for a location of interest. This report includes descriptions of how water budgets are calculated for the integrated model and for individual model components. GSFLOW provides a robust modeling system for simulating flow through the hydrologic cycle, while allowing for future enhancements to incorporate other simulation techniques.

  19. Effects of emission reductions at the Hayden powerplant on precipitation, snowpack, and surface-water chemistry in the Mount Zirkel Wilderness Area, Colorado, 1995-2003

    USGS Publications Warehouse

    Mast, M. Alisa; Campbell, Donald H.; Ingersoll, George P.

    2005-01-01

    Precipitation, snowpack, and surface-water samples collected during 1995-2003 were analyzed to evaluate the effects of emission reductions at the Hayden powerplant on water chemistry in the Mount Zirkel Wilderness Area. The Hayden powerplant, one of two large coal-fired powerplants in the Yampa Valley, was retrofitted with control systems during late 1998 and 1999 to reduce emissions of sulfur dioxide and nitrogen oxide--the primary precursors of haze and acidic precipitation. The U.S. Geological Survey, in cooperation with the Colorado Department of Public Health and Environment, evaluated three water-chemistry data sets: wet-only precipitation chemistry from the National Atmospheric Deposition Program, snowpack chemistry from the Rocky Mountain snowpack network, and surface-water chemistry from a U.S. Geological Survey long-term lakes monitoring program. Concentrations and deposition rates of selected constituents were compared for the periods before and after emission reductions at the Hayden powerplant. Data collected during 1995-98 were used to represent the pre-control period, and data collected during 2000-2003 were used to represent the post-control period. Ten stations in the National Atmospheric Deposition Program were evaluated including two that were directly downwind from the Hayden powerplant (Dry Lake and Buffalo Pass) and eight that were upwind or more distant (more than 100 kilometers) from the powerplant. Precipitation amount at all 10 precipitation stations was lower in the post-control period than the pre-control period as a result of a regional drought that persisted during the post-control period. In contrast to precipitation amount, there was no consistent pattern of change in sulfate concentrations between periods, indicating that the drought did not have a concentrating effect on sulfate or that trends in regional sulfur dioxide emissions masked its influence. Sulfate concentrations increased at three stations between periods, remained the

  20. Near-Infrared Spectroscopy as an Analytical Process Technology for the On-Line Quantification of Water Precipitation Processes during Danhong Injection.

    PubMed

    Liu, Xuesong; Wu, Chunyan; Geng, Shu; Jin, Ye; Luan, Lianjun; Chen, Yong; Wu, Yongjiang

    2015-01-01

    This paper used near-infrared (NIR) spectroscopy for the on-line quantitative monitoring of water precipitation during Danhong injection. For these NIR measurements, two fiber optic probes designed to transmit NIR radiation through a 2 mm flow cell were used to collect spectra in real-time. Partial least squares regression (PLSR) was developed as the preferred chemometrics quantitative analysis of the critical intermediate qualities: the danshensu (DSS, (R)-3, 4-dihydroxyphenyllactic acid), protocatechuic aldehyde (PA), rosmarinic acid (RA), and salvianolic acid B (SAB) concentrations. Optimized PLSR models were successfully built and used for on-line detecting of the concentrations of DSS, PA, RA, and SAB of water precipitation during Danhong injection. Besides, the information of DSS, PA, RA, and SAB concentrations would be instantly fed back to site technical personnel for control and adjustment timely. The verification experiments determined that the predicted values agreed with the actual homologic value.

  1. Near-Infrared Spectroscopy as an Analytical Process Technology for the On-Line Quantification of Water Precipitation Processes during Danhong Injection

    PubMed Central

    Liu, Xuesong; Wu, Chunyan; Geng, Shu; Jin, Ye; Luan, Lianjun; Chen, Yong; Wu, Yongjiang

    2015-01-01

    This paper used near-infrared (NIR) spectroscopy for the on-line quantitative monitoring of water precipitation during Danhong injection. For these NIR measurements, two fiber optic probes designed to transmit NIR radiation through a 2 mm flow cell were used to collect spectra in real-time. Partial least squares regression (PLSR) was developed as the preferred chemometrics quantitative analysis of the critical intermediate qualities: the danshensu (DSS, (R)-3, 4-dihydroxyphenyllactic acid), protocatechuic aldehyde (PA), rosmarinic acid (RA), and salvianolic acid B (SAB) concentrations. Optimized PLSR models were successfully built and used for on-line detecting of the concentrations of DSS, PA, RA, and SAB of water precipitation during Danhong injection. Besides, the information of DSS, PA, RA, and SAB concentrations would be instantly fed back to site technical personnel for control and adjustment timely. The verification experiments determined that the predicted values agreed with the actual homologic value. PMID:26839549

  2. CalWater Field Studies Designed to Quantify the Roles of Atmospheric Rivers and Aerosols in Modulating U.S. West Coast Precipitation in a Changing Climate

    SciTech Connect

    Ralph, F. M.; Prather, K. A.; Cayan, D.; Spackman, J. R.; DeMott, P.; Dettinger, M.; Fairall, C.; Leung, R.; Rosenfeld, D.; Rutledge, S.; Waliser, D.; White, A. B.; Cordeira, J.; Martin, A.; Helly, J.; Intrieri, J.

    2016-07-01

    The variability of precipitation and water supply along the U.S. West Coast creates major challenges to the region’s economy and environment, as evidenced by the recent California drought. This variability is strongly influenced by atmospheric rivers (AR), which deliver much of the precipitation along the U.S. West Coast and can cause flooding, and by aerosols (from local sources and transported from remote continents and oceans) that modulate clouds and precipitation. A better understanding of these processes is needed to reduce uncertainties in weather predictions and climate projections of droughts and floods, both now and under changing climate conditions.To address these gaps a group of meteorologists, hydrologists, climate scientists, atmospheric chemists, and oceanographers have created an interdisciplinary research effort, with support from multiple agencies. From 2009-2011 a series of field campaigns (CalWater 1) collected atmospheric chemistry, cloud microphysics and meteorological measurements in California and associated modeling and diagnostic studies were carried out. Based on remaining gaps, a vision was developed to extend these studies offshore over the Eastern North Pacific and to enhance land based measurements from 2014-2018 (CalWater 2). The data set and selected results from CalWater 1 are summarized here. The goals of CalWater-2, and measurements to date, are then described. CalWater is producing new findings and exploring new technologies to evaluate and improve global climate models and their regional performance and to develop tools supporting water and hydropower management. These advances also have potential to enhance hazard mitigation by improving near-term weather prediction and subseasonal and seasonal outlooks.

  3. Fusing enhanced radar precipitation, in-situ hydrometeorological measurements and airborne LIDAR snowpack estimates in a hyper-resolution hydrologic model to improve seasonal water supply forecasts

    NASA Astrophysics Data System (ADS)

    Gochis, D. J.; Busto, J.; Howard, K.; Mickey, J.; Deems, J. S.; Painter, T. H.; Richardson, M.; Dugger, A. L.; Karsten, L. R.; Tang, L.

    2015-12-01

    Scarcity of spatially- and temporally-continuous observations of precipitation and snowpack conditions in remote mountain watersheds results in fundamental limitations in water supply forecasting. These limitationsin observational capabilities can result in strong biases in total snowmelt-driven runoff amount, the elevational distribution of runoff, river basin tributary contributions to total basin runoff and, equally important for water management, the timing of runoff. The Upper Rio Grande River basin in Colorado and New Mexico is one basin where observational deficiencies are hypothesized to have significant adverse impacts on estimates of snowpack melt-out rates and on water supply forecasts. We present findings from a coordinated observational-modeling study within Upper Rio Grande River basin whose aim was to quanitfy the impact enhanced precipitation, meteorological and snowpack measurements on the simulation and prediction of snowmelt driven streamflow. The Rio Grande SNOwpack and streamFLOW (RIO-SNO-FLOW) Prediction Project conducted enhanced observing activities during the 2014-2015 water year. Measurements from a gap-filling, polarimetric radar (NOXP) and in-situ meteorological and snowpack measurement stations were assimilated into the WRF-Hydro modeling framework to provide continuous analyses of snowpack and streamflow conditions. Airborne lidar estimates of snowpack conditions from the NASA Airborne Snow Observatory during mid-April and mid-May were used as additional independent validations against the various model simulations and forecasts of snowpack conditions during the melt-out season. Uncalibrated WRF-Hydro model performance from simulations and forecasts driven by enhanced observational analyses were compared against results driven by currently operational data inputs. Precipitation estimates from the NOXP research radar validate significantly better against independent in situ observations of precipitation and snow-pack increases

  4. Ionic Flash NanoPrecipitation (iFNP) for the facile, one-step synthesis of inorganic-organic hybrid nanoparticles in water.

    PubMed

    Pinkerton, N M; Behar, L; Hadri, K; Amouroux, B; Mingotaud, C; Talham, D R; Chassaing, S; Marty, J-D

    2017-01-26

    Ionic Flash NanoPrecipitation (iFNP) was evaluated as a novel method for the synthesis of inorganic-organic hybrid nanomaterials and proved to be remarkably effective, fast and practical. To prove the potential of iFNP, various nanostructured GdPO4-based materials of biomedical imaging relevance were easily prepared in a one-step, tunable and highly controlled manner using only water as solvent.

  5. Using MODIS snow cover and precipitation data to model water runoff for the Mokelumne River Basin in the Sierra Nevada, California (2000-2009)

    NASA Astrophysics Data System (ADS)

    Powell, Cynthia; Blesius, Leonhard; Davis, Jerry; Schuetzenmeister, Falk

    2011-05-01

    Climate change will affect snowpack and water supply systems in California, and methods for predicting daily stream flow help prepare for these changes. This research provides a daily model to predict stream flow based on snow cover and precipitation in the Mokelumne River Basin in the Sierra Nevada in California. The snow cover of the Mokelumne River Basin is monitored using Moderate Resolution Imaging Spectroradiometer (MODIS) satellite images. Using data from these images as well as precipitation data from 2000 to 2009, we produced a predictive statistical model. The final results show that with an R2 of 0.71, the true natural flow (TNF) of the Mokelumne River is based on the daily area of snow cover in each of seven equal area elevation zones according to the time lag of that zone as well as the accumulated precipitation functioning as a proxy for snow depth. The capability of this model to predict water supply suggests the potential for developing new spatial hydrologic informational products based on MODIS and the probability of improving the accuracy of the prediction of hydrologic processes for water resource managers.

  6. A precipitation-runoff model for simulating natural streamflow conditions in the Smith River watershed, Montana, water years 1996-2008

    USGS Publications Warehouse

    Chase, Katherine J.; Caldwell, Rodney R.; Stanley, Andrea K.

    2014-01-01

    This report documents the construction of a precipitation-runoff model for simulating natural streamflow in the Smith River watershed, Montana. This Precipitation-Runoff Modeling System model, constructed in cooperation with the Meagher County Conservation District, can be used to examine the general hydrologic framework of the Smith River watershed, including quantification of precipitation, evapotranspiration, and streamflow; partitioning of streamflow between surface runoff and subsurface flow; and quantifying contributions to streamflow from several parts of the watershed. The model was constructed by using spatial datasets describing watershed topography, the streams, and the hydrologic characteristics of the basin soils and vegetation. Time-series data (daily total precipitation, and daily minimum and maximum temperature) were input to the model to simulate daily streamflow. The model was calibrated for water years 2002–2007 and evaluated for water years 1996–2001. Though water year 2008 was included in the study period to evaluate water-budget components, calibration and evaluation data were unavailable for that year. During the calibration and evaluation periods, simulated-natural flow values were compared to reconstructed-natural streamflow data. These reconstructed-natural streamflow data were calculated by adding Bureau of Reclamation’s depletions data to the observed streamflows. Reconstructed-natural streamflows represent estimates of streamflows for water years 1996–2007 assuming there was no agricultural water-resources development in the watershed. Additional calibration targets were basin mean monthly solar radiation and potential evapotranspiration. The model estimated the hydrologic processes in the Smith River watershed during the calibration and evaluation periods. Simulated-natural mean annual and mean monthly flows generally were the same or higher than the reconstructed-natural streamflow values during the calibration period, whereas

  7. Co-precipitation of radium with barium and strontium sulfate and its impact on the fate of radium during treatment of produced water from unconventional gas extraction.

    PubMed

    Zhang, Tieyuan; Gregory, Kelvin; Hammack, Richard W; Vidic, Radisav D

    2014-04-15

    Radium occurs in flowback and produced waters from hydraulic fracturing for unconventional gas extraction along with high concentrations of barium and strontium and elevated salinity. Radium is often removed from this wastewater by co-precipitation with barium or other alkaline earth metals. The distribution equation for Ra in the precipitate is derived from the equilibrium of the lattice replacement reaction (inclusion) between the Ra(2+) ion and the carrier ions (e.g., Ba(2+) and Sr(2+)) in aqueous and solid phases and is often applied to describe the fate of radium in these systems. Although the theoretical distribution coefficient for Ra-SrSO4 (Kd = 237) is much larger than that for Ra-BaSO4 (Kd = 1.54), previous studies have focused on Ra-BaSO4 equilibrium. This study evaluates the equilibria and kinetics of co-precipitation reactions in Ra-Ba-SO4 and Ra-Sr-SO4 binary systems and the Ra-Ba-Sr-SO4 ternary system under varying ionic strength (IS) conditions that are representative of brines generated during unconventional gas extraction. Results show that radium removal generally follows the theoretical distribution law in binary systems and is enhanced in the Ra-Ba-SO4 system and restrained in the Ra-Sr-SO4 system by high IS. However, the experimental distribution coefficient (Kd') varies widely and cannot be accurately described by the distribution equation, which depends on IS, kinetics of carrier precipitation and does not account for radium removal by adsorption. Radium removal in the ternary system is controlled by the co-precipitation of Ra-Ba-SO4, which is attributed to the rapid BaSO4 nucleation rate and closer ionic radii of Ra(2+) with Ba(2+) than with Sr(2+). Carrier (i.e., barite) recycling during water treatment was shown to be effective in enhancing radium removal even after co-precipitation was completed. Calculations based on experimental results show that Ra levels in the precipitate generated in centralized waste treatment facilities far

  8. Thermodynamic Simulation of Carbonate Cements-Water-Carbon Dioxide Equilibrium in Sandstone for Prediction of Precipitation/Dissolution of Carbonate Cements

    PubMed Central

    Zhong, Xinyan; Shang, Ruishu; Huang, Lihong

    2016-01-01

    and remains negative, indicating it is also a precipitation process at burial depth of 3.9 km where overpressure generated. The method used in this study can be applied in assessing burial precipitation-dissolution processes and predicting possible pores in reservoirs with carbonate cement-water-carbon dioxide. PMID:27907043

  9. Thermodynamic Simulation of Carbonate Cements-Water-Carbon Dioxide Equilibrium in Sandstone for Prediction of Precipitation/Dissolution of Carbonate Cements.

    PubMed

    Duan, Yiping; Feng, Mingshi; Zhong, Xinyan; Shang, Ruishu; Huang, Lihong

    2016-01-01

    -2.17 mmol·L-1 and remains negative, indicating it is also a precipitation process at burial depth of 3.9 km where overpressure generated. The method used in this study can be applied in assessing burial precipitation-dissolution processes and predicting possible pores in reservoirs with carbonate cement-water-carbon dioxide.

  10. Precipitation, streamflow and water quality data from selected sites in the City of Charlotte and Mecklenburg County, North Carolina, 1993-95

    USGS Publications Warehouse

    Robinson, J.B.; Hazell, W.F.; Garrett, R.G.

    1996-01-01

    Charlotte and Mecklenburg County from October 1993 through June 1995 to identify the type, concentration, and amount of nonpoint-source stormwater runoff within the area. The data collected include measurements of precipitation; streamflow; physical characteristics, such as water temperature, pH, specific conductance, biochemical oxygen demand, oil and grease, and suspended sediment concentrations; and concentrations of nutrients, metals and minor constituents, and organic compounds. These data should provide valuable information needed for (1) planned watershed simulation models, (2) early warning of possible flooding, (3) estimates of nonpoint-source constituent loadings to the Catawba River, and (4) characterization of water quality in relation to basin conditions.

  11. Chemical and isotopic data collected from groundwater, surface-water, and atmospheric precipitation sites in Upper Kittitas County, Washington, 2010-12

    USGS Publications Warehouse

    Hinkle, Stephen R.; Ely, D. Matthew

    2013-01-01

    As part of a multidisciplinary U.S. Geological Survey study of water resources in Upper Kittitas County, Washington, chemical and isotopic data were collected from groundwater, surface-water, and atmospheric precipitation sites from 2010 to 2012. These data are documented here so that interested parties can quickly and easily find those chemical and isotopic data related to this study. The locations of the samples are shown on an interactive map of the study area. This report is dynamic; additional data will be added to it as they become available.

  12. Assessment of precipitable water vapor derived from ground-based BeiDou observations with Precise Point Positioning approach

    NASA Astrophysics Data System (ADS)

    Li, Min; Li, Wenwen; Shi, Chuang; Zhao, Qile; Su, Xing; Qu, Lizhong; Liu, Zhizhao

    2015-01-01

    Precipitable water vapor (PWV) estimation from Global Positioning System (GPS) has been extensively studied and used for meteorological applications. However PWV estimation using the emerging BeiDou Navigation Satellite System (BDS) is very limited. In this paper the PWV estimation strategy and the evaluation of the results inferred from ground-based BDS observations using Precise Point Positioning (PPP) method are presented. BDS and GPS data from 10 stations distributed in the Asia-Pacific and West Indian Ocean regions during the year 2013 are processed using the PANDA (Position and Navigation Data Analyst) software package. The BDS-PWV and GPS-PWV are derived from the BDS-only and GPS-only observations, respectively. The PPP positioning differences between BDS-only and GPS-only show a standard deviation (STD) <1 cm in the east and north components and 1-3 cm in vertical component. The BDS-PWV and GPS-PWV at the HKTU station (Hong Kong, China) is compared with PWV derived from a radiosonde station (about 1 km distance) over a 6-month period. The GPS-PWV shows a good agreement with radiosonde-PWV with a bias of 0.002 mm and a STD of 2.49 mm while BDS-PWV has with a bias of -2.04 mm and STD 2.68 mm with respect to radiosonde-PWV. This indicates that the PWV estimated from the BDS can achieve similar precision as PWV from GPS. The BDS-PWV is compared to GPS-PWV at 10 stations. The mean bias and STD of their differences at 10 stations are 0.78 mm and 1.77 mm, respectively. The mean root mean square (RMS) value is 2.00 mm by considering the GPS-PWV as reference truth. This again confirms that the BDS-PWV has a good agreement with the GPS-PWV. It clearly indicates that the BDS is ready for the high precision meteorological applications in the Asia-Pacific and West Indian Ocean regions and that BDS alone can be used for PWV estimation with an accuracy comparable to GPS.

  13. Stable isotope (δ18O and δ2H) data for precipitation, stream water, and groundwater in Puerto Rico

    USGS Publications Warehouse

    Scholl, Martha A.; Torres-Sanchez, Angel; Rosario-Torres, Manuel

    2014-01-01

    Puerto Rico is located in the northeastern Caribbean Sea (18.2 °N, 66.3 °W), with the Atlantic Ocean on its northern coast. The U.S. Geological Survey’s Water, Energy, and Biogeochemical Budgets (WEBB) program study area in which most of these data were collected comprises the El Yunque National Forest and surrounding area of eastern Puerto Rico. Samples were collected in two forested watersheds, the Rio Mameyes and the Rio Icacos/Rio Blanco, on opposite sides of a ridge in the Luquillo Mountains on the eastern end of the island (fig. 1). Elevation in both watersheds ranges from sea level to approximately 1,000 meters (m). Near sea level, land use is mixed pasture, moist forest, and residential, grading to completely forested within the boundaries of El Yunque National Forest. Forest type changes with elevation from tabonuco to palo colorado to sierra palm to cloud forest above approximately 950 m (Murphy and others, 2012). The Rio Mameyes watershed is oriented north-northeast, and the basin is underlain by volcaniclastic bedrock (basaltic to andesitic volcanic sandstone/mudstone/conglomerate/breccia). The Rio Icacos/Rio Blanco watershed is oriented south-southeast. The Rio Icacos is one of the headwaters of the Rio Blanco and is underlain by quartz diorite. The lower Rio Blanco basin is underlain by andesitic volcaniclastic bedrock. This report also contains a long-term rain isotope dataset from the San Agustin site, in north-central Puerto Rico (fig. 1). Puerto Rico has a tropical climate dominated by easterly trade winds, and seasonal climate patterns affect the hydrology of the study area. The summer wet season is characterized by convective precipitation from tropical easterly waves, troughs, and cyclonic low-pressure systems, including tropical storms and hurricanes; in contrast, the drier winter season is characterized by trade-wind showers and frontal systems. The highest single-event rainfall totals tend to be associated with tropical storms

  14. Understanding the Global Water and Energy Cycle Through Assimilation of Precipitation-Related Observations: Lessons from TRMM and Prospects for GPM

    NASA Technical Reports Server (NTRS)

    Hou, Arthur; Zhang, Sara; daSilva, Arlindo; Li, Frank; Atlas, Robert (Technical Monitor)

    2002-01-01

    Understanding the Earth's climate and how it responds to climate perturbations relies on what we know about how atmospheric moisture, clouds, latent heating, and the large-scale circulation vary with changing climatic conditions. The physical process that links these key climate elements is precipitation. Improving the fidelity of precipitation-related fields in global analyses is essential for gaining a better understanding of the global water and energy cycle. In recent years, research and operational use of precipitation observations derived from microwave sensors such as the Tropical Rainfall Measuring Mission (TRMM) Microwave Imager and Special Sensor Microwave/Imager (SSM/I) have shown the tremendous potential of using these data to improve global modeling, data assimilation, and numerical weather prediction. We will give an overview of the benefits of assimilating TRMM and SSM/I rain rates and discuss developmental strategies for using space-based rainfall and rainfall-related observations to improve forecast models and climate datasets in preparation for the proposed multi-national Global Precipitation Mission (GPM).

  15. Evaluation of effects of changes in canal management and precipitation patterns on salinity in Biscayne Bay, Florida, using an integrated surface-water/groundwater model

    USGS Publications Warehouse

    Lohmann, Melinda A.; Swain, Eric D.; Wang, John D.; Dixon, Joann

    2012-01-01

    Biscayne National Park, located in Biscayne Bay in southeast Florida, is one of the largest marine parks in the country and sustains a large natural marine fishery where numerous threatened and endangered species reproduce. In recent years, the bay has experienced hypersaline conditions (salinity greater than 35 practical salinity units) of increasing magnitude and duration. Hypersalinity events were particularly pronounced during April to August 2004 in nearshore areas along the southern and middle parts of the bay. Prolonged hypersaline conditions can cause degradation of water quality and permanent damage to, or loss of, brackish nursery habitats for multiple species of fish and crustaceans as well as damage to certain types of seagrasses that are not tolerant of extreme changes in salinity. To evaluate the factors that contribute to hypersalinity events and to test the effects of possible changes in precipitation patterns and canal flows into Biscayne Bay on salinity in the bay, the U.S. Geological Survey constructed a coupled surface-water/groundwater numerical flow model. The model is designed to account for freshwater flows into Biscayne Bay through the canal system, leakage of salty bay water into the underlying Biscayne aquifer, discharge of fresh and salty groundwater from the Biscayne aquifer into the bay, direct effects of precipitation on bay salinity, indirect effects of precipitation on recharge to the Biscayne aquifer, direct effects of evapotranspiration (ET) on bay salinity, indirect effects of ET on recharge to the Biscayne aquifer, and maintenance of mass balance of both water and solute. The model was constructed using the Flow and Transport in a Linked Overland/Aquifer Density Dependent System (FTLOADDS) simulator, version 3.3, which couples the two-dimensional, surface-water flow and solute-transport simulator SWIFT2D with the density-dependent, groundwater flow an solute-transport simulator SEAWAT. The model was calibrated by a trial

  16. Water-Rock Interaction Simulations of Iron Oxide Mobilization and Precipitation: Implications of Cross-diffusion Reactions for Terrestrial and Mars 'Blueberry' Hematite Concretions

    NASA Astrophysics Data System (ADS)

    Park, A. J.; Chan, M. A.; Parry, W. T.

    2005-12-01

    Modeling of how terrestrial concretions form can provide valuable insights into understanding water-rock interactions that led to the formation of hematite concretions at Meridiani Planum, Mars. Numerical simulations of iron oxide concretions in the Jurassic Navajo Sandstone of southern Utah provide physical and chemical input parameters for emulating conditions that may have prevailed on Mars. In the terrestrial example, iron oxide coatings on eolian sand grains are reduced and mobilized by methane or petroleum. Precipitation of goethite or hematite occurs as Fe interacts with oxygen. Conditions that produced Navajo Sandstone concretions can range from a regional scale that is strongly affected by advection of large pore volumes of water, to small sub-meter scale features that are dominantly controlled by diffusive processes. Hematite concretions are results of a small-scale cross-diffusional process, where Fe and oxygen are supplied from two opposite sides from the 'middle' zone of mixing where concretions precipitate. This is an ideal natural system where Liesegang banding and other self-organized patterns can evolve. A complicating variable here is the sedimentologic (both mineralogic and textural) heterogeneity that, in reality, may be the key factor controlling the nucleation and precipitation habits (including possible competitive growth) of hematite concretions. Sym.8 water-rock interaction simulator program was used for the Navajo Sandstone concretions. Sym.8 is a water-rock simulator that accounts for advective and diffusive mass-transfer, and equilibrium and kinetic reactions. The program uses a dynamic composite media texture model to address changing sediment composition and texture to be consistent with the reaction progress. Initial one-dimensional simulation results indicate precipitation heterogeneity in the range of sub-meters, e.g., possible banding and distribution of iron oxide nodules may be centimeters apart for published diffusivities and

  17. Mineral Dissolution and Precipitation due to Carbon Dioxide-Water-Rock Interactions: The Significance of Accessory Minerals in Carbonate Reservoirs (Invited)

    NASA Astrophysics Data System (ADS)

    Kaszuba, J. P.; Marcon, V.; Chopping, C.

    2013-12-01

    Accessory minerals in carbonate reservoirs, and in the caprocks that seal these reservoirs, can provide insight into multiphase fluid (CO2 + H2O)-rock interactions and the behavior of CO2 that resides in these water-rock systems. Our program integrates field data, hydrothermal experiments, and geochemical modeling to evaluate CO2-water-rock reactions and processes in a variety of carbonate reservoirs in the Rocky Mountain region of the US. These studies provide insights into a wide range of geologic environments, including natural CO2 reservoirs, geologic carbon sequestration, engineered geothermal systems, enhanced oil and gas recovery, and unconventional hydrocarbon resources. One suite of experiments evaluates the Madison Limestone on the Moxa Arch, Southwest Wyoming, a sulfur-rich natural CO2 reservoir. Mineral textures and geochemical features developed in the experiments suggest that carbonate minerals which constitute the natural reservoir will initially dissolve in response to emplacement of CO2. Euhedral, bladed anhydrite concomitantly precipitates in response to injected CO2. Analogous anhydrite is observed in drill core, suggesting that secondary anhydrite in the natural reservoir may be related to emplacement of CO2 into the Madison Limestone. Carbonate minerals ultimately re-precipitate, and anhydrite dissolves, as the rock buffers the acidity and reasserts geochemical control. Another suite of experiments emulates injection of CO2 for enhanced oil recovery in the Desert Creek Limestone (Paradox Formation), Paradox Basin, Southeast Utah. Euhedral iron oxyhydroxides (hematite) precipitate at pH 4.5 to 5 and low Eh (approximately -0.1 V) as a consequence of water-rock reaction. Injection of CO2 decreases pH to approximately 3.5 and increases Eh by approximately 0.1 V, yielding secondary mineralization of euhedral pyrite instead of iron oxyhydroxides. Carbonate minerals also dissolve and ultimately re-precipitate, as determined by experiments in the

  18. Centrifugal precipitation chromatography.

    PubMed

    Ito, Yoichiro; Qi, Lin

    2010-01-15

    Centrifugal precipitation chromatography separates analytes according their solubility in ammonium sulfate (AS) solution and other precipitants. The separation column is made from a pair of long spiral channels partitioned with a semipermeable membrane. In a typical separation, concentrated ammonium sulfate is eluted through one channel while water is eluted through the other channel in the opposite direction. This countercurrent process forms an exponential AS concentration gradient through the water channel. Consequently, protein samples injected into the water channel is subjected to a steadily increasing AS concentration and at the critical AS concentration they are precipitated and deposited in the channel bed by the centrifugal force. Then the chromatographic separation is started by gradually reducing the AS concentration in the AS channel which lowers the AS gradient concentration in the water channel. This results in dissolution of deposited proteins which are again precipitated at an advanced critical point as they move through the channel. Consequently, proteins repeat precipitation and dissolution through a long channel and finally eluted out from the column in the order of their solubility in the AS solution. The present method has been successfully applied to a number of analytes including human serum proteins, recombinant ketosteroid isomerase, carotenoid cleavage enzymes, plasmid DNA, polysaccharide, polymerized pigments, PEG-protein conjugates, etc. The method is capable to single out the target species of proteins by affinity ligand or immunoaffinity separation.

  19. A new method for As(V) removal from waters by precipitation of mimetite Pb5(AsO4)3Cl on Pb-activated zeolite

    NASA Astrophysics Data System (ADS)

    Manecki, Maciej; Buszkiewicz, Urszula

    2016-04-01

    A new method for removal of arsenate AsO43- ions from aqueous solutions is proposed. The principle of the method stems from precipitation of very insoluble crystalline lead arsenate apatite (mimetite Pb5(AsO4)3Cl) induced by bringing in contact Pb-activated zeolite and As-contaminated water in the presence of Cl-. Zeolite is activated by sorption of Pb2+ followed by washing with water to remove the excess of Pb and to desorbe weakly adsorbed ions. Lead adsorbed on zeolite is bound strong enough to prevent desorption by water but weak enough to undergo desorption induced by heterogeneous precipitation of mimetite nanocrystals on the surface of zeolite. The experiment consisted of two steps. In the first step, aliquots of 0.5 g of natural clinoptilolite zeolite (from Zeocem a.s., Bystré, Slovak Republic) were reacted with 40 mL of solutions containing 20, 100, 500, and 2000 mg Pb/L (pH =4.5; reaction for 30 minutes followed by centrifugation). The amount of Pb sorbed was calculated from the drop of Pb concentration in solution. Centrifuged zeolite was washed three times by mixing with 10 mL of DDI water, followed by centrifugation. No Pb was detected in the water after second washing. Wet pulp resulting from this stage was exposed to solutions containing 70 mg/L Cl- and various concentrations of AsO43- (2 and 100 mg As/L; pH=4). Complete removal of As was observed for 2 mg As/L solutions mixed with zeolite-20 and zeolite-100. The precipitation of mimetite Pb5(AsO4)3Cl in the form of hexagonal crystals ca. 0.25 μm in size was observed using SEM/EDS. This work is partially funded by AGH research grant no 11.11.140.319.

  20. STRONTIUM PRECIPITATION

    DOEpatents

    McKenzie, T.R.

    1960-09-13

    A process is given for improving the precipitation of strontium from an aqueous phosphoric-acid-containing solution with nickel or cobalt ferrocyanide by simultaneously precipitating strontium or calcium phosphate. This is accomplished by adding to the ferrocyanide-containing solution calcium or strontium nitrate in a quantity to yield a concentration of from 0.004 to 0.03 and adjusting the pH of the solution to a value of above 8.

  1. Microbial community responses to 17 years of altered precipitation are seasonally dependent and coupled to co-varying effects of water content on vegetation and soil C

    USGS Publications Warehouse

    Sorensen, Patrick O.; Germino, Matthew J.; Feris, Kevin P.

    2013-01-01

    Precipitation amount and seasonal timing determine the duration and distribution of water available for plant and microbial activity in the cold desert sagebrush steppe. In this study, we sought to determine if a sustained shift in the amount and timing of precipitation would affect soil microbial diversity, community composition, and soil carbon (C) storage. Field plots were irrigated (+200 mm) during the dormant or growing-season for 17 years. Microbial community responses were assessed over the course of a year at two depths (15–20 cm, 95–100 cm) by terminal restriction fragment length polymorphism (T-RFLP), along with co-occurring changes in plant cover and edaphic properties. Bacterial richness, Shannon Weaver diversity, and composition in shallow soils (15–20 cm) as well as evenness in deep soils (95–100 cm) differed across irrigation treatments during July. Irrigation timing affected fungal community diversity and community composition during the dormant season and most strongly in deep soils (95–100 cm). Dormant-season irrigation increased the ratio of shrubs to forbs and reduced soil C in shallow soils by 16% relative to ambient conditions. It is unclear whether or not soil C will continue to decline with continued treatment application or if microbial adaptation could mitigate sustained soil C losses. Future changes in precipitation timing will affect soil microbes in a seasonally dependent manner and be coupled to co-varying effects of water content on vegetation and soil C.

  2. Variations in High-Intensity Precipitation under Climate Changes in the LMRB and Implications on Drinking Water Supply Security

    EPA Science Inventory

    A systematic temporal and spatial analysis is being conducted at the U.S. EPA on historical precipitation and stream flow over the continental U.S. and their relationships with Atlantic hurricanes and lower Mississippi river basin flooding. The objective is to decipher the perio...

  3. Variations in High-density Precipitation under Climate Changes in the LMRB and Implications on Drinking Water Supply Security - Paper

    EPA Science Inventory

    A systematic temporal and spatial analysis is being conducted at the U.S. EPA on historical precipitation and stream flow over the continental U.S. and their relationships with Atlantic hurricanes and lower Mississippi river basin flooding. The objective is to decipher the period...

  4. Relation of precipitation to annual ground-water recharge in the Edwards Aquifer, San Antonio area, Texas

    USGS Publications Warehouse

    Puente, Celso

    1975-01-01

    The report includes a brief review of the geology and hydrology of the Edwards aquifer, a discussion of the preparation and evaluation of the precipitation data used in the regression analyses, and a brief summary of the method previously used to estimate recharge.

  5. Evaluation of different interpolation schemes for precipitation and reference evapotranspiration and the impact on simulated large-scale water balance in Slovenia

    NASA Astrophysics Data System (ADS)

    He, Qianwen; Molkenthin, Frank; Wendland, Frank; Herrmann, Frank

    2016-04-01

    Precipitation and reference evapotranspiration (ET0) are two main climate input components for hydrological models, which are often recorded or calculated based on measuring stations. Interpolation schemes are implemented to regionalize data from measuring stations for distributed hydrological models. This study had been conducted for 5 months, with the aim of: (1) evaluating three interpolation schemes for precipitation and reference evapotranspiration (ET0); (2) assessing the impact of the interpolation schemes on actual evapotranspiration and total runoff simulated by a distributed large-scale water balance model - mGROWA. The study case was the Republic of Slovenia, including a high variability in topography and climatic conditions, with daily meteorological data measured in 20 stations for a period of 44 years. ET0 were computed by both FAO Penman-Monteith equation and Hargreaves equation. The former equation is recommended as the standard equation, while the ET0 calculated by the latter one for Slovenia had a certain deviation (+150 mm/a) from it. Ordinary Kriging, Regression Kriging and Linear Regression were selected to regionalize precipitation and ET0. Reliability of the three interpolation schemes had been assessed based on the residual obtained from cross-validation. Monthly regionalized precipitation and ET0 were subsequently used as climate input for mGROWA model simulation. Evaluation of the interpolation schemes showed that the application of Regression Kriging and Linear Regression led to an acceptable interpolation result for reference evapotranspiration, especially in case the FAO Penman-Monteith equation was used. On the other hand, Regression Kriging also provided a more convincing interpolated result for precipitation. Meanwhile, mGROWA simulation results were affected by climate input data sets generated by applying difference interpolation schemes. Therefore, it is essential to select an appropriate interpolation scheme, in order to generate

  6. Lipid-Based Formulations Can Enable the Model Poorly Water-Soluble Weakly Basic Drug Cinnarizine To Precipitate in an Amorphous-Salt Form During In Vitro Digestion.

    PubMed

    Khan, Jamal; Rades, Thomas; Boyd, Ben J

    2016-11-07

    The tendency for poorly water-soluble weakly basic drugs to precipitate in a noncrystalline form during the in vitro digestion of lipid-based formulations (LBFs) was linked to an ionic interaction between drug and fatty acid molecules produced upon lipid digestion. Cinnarizine was chosen as a model weakly basic drug and was dissolved in a medium-chain (MC) LBF, which was subject to in vitro lipolysis experiments at various pH levels above and below the reported pKa value of cinnarizine (7.47). The solid-state form of the precipitated drug was analyzed using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and crossed polarized light microscopy (CPLM). In addition, the phase distribution of cinnarizine upon lipolysis was analyzed using high-performance liquid chromatography (HPLC). Cinnarizine precipitated in a noncrystalline form during lipolysis experiments at pH 6.5, pH 5.5, and pH 4.0 but precipitated in a crystalline form at pH 8.0 according to XRD measurements on the pellets. Differences were also observed in the FTIR spectra of the pellet phases at pH 8.0 and pH 6.5, with the absorption bands in the C-N stretch region of the IR spectra supporting a shift from the starting free base crystalline material to the hydrochloride salt, thus supporting the case that ionic interactions between weak bases and fatty acid molecules during digestion are responsible for producing amorphous-salts upon precipitation. The conclusion has wide implications for understanding past in vitro and in vivo data for lipid-based formulations of basic drugs, as well as future formulation design and optimization.

  7. Water soluble organic carbon in aerosols (PM1, PM2.5, PM10) and various precipitation forms (rain, snow, mixed) over the southern Baltic Sea station.

    PubMed

    Witkowska, Agnieszka; Lewandowska, Anita U

    2016-12-15

    In the urbanized coastal zone of the Southern Baltic, complex measurements of water soluble organic carbon (WSOC) were conducted between 2012 and 2015, involving atmospheric precipitation in its various forms (rain, snow, mixed) and PM1, PM2.5 and PM10 aerosols. WSOC constituted about 60% of the organic carbon mass in aerosols of various sizes. The average concentration of WSOC was equal to 2.6μg∙m(-3) in PM1, 3.6μg∙m(-3) in PM2.5 and 4.4μg∙m(-3) in PM10. The lowest concentration of WSOC was noted in summer as a result of effective removal of this compound with rainfall. The highest WSOC concentrations in PM2.5 and PM10 aerosols were measured in spring, which should be associated with developing vegetation on land and in the sea. On the other hand, the highest WSOC concentrations in PM1 occurred in winter at low air temperatures and greatest atmospheric stability, when there were increased carbon emissions from fuel combustion in the communal-utility sector and from transportation. WSOC concentrations in precipitation were determined by its form. Mixed precipitation turned out to be the richest in soluble organic carbon (5.1mg·dm(-3)), while snow contained the least WSOC (1.7mg·dm(-3)). Snow and rain cleaned carbon compounds from the atmosphere more effectively when precipitation lasted longer than 24h, while in the case of mixed precipitation WSOC was removed most effectively within the first 24h.

  8. Characterization and relation of precipitation, streamflow, and water-quality data at the U.S. Army Garrison Fort Carson and Piñon Canyon Maneuver Site, Colorado, water years 2013–14

    USGS Publications Warehouse

    Holmberg, Michael J.; Stogner, Robert W.; Bruce, James F.

    2016-11-29

    To evaluate the influence of military training activities on streamflow and water quality, the U.S. Geological Survey, in cooperation with the U.S. Department of the Army, began a hydrologic data collection network on the U.S. Army Garrison Fort Carson in 1978 and on the Piñon Canyon Maneuver Site in 1983. This report is a summary and characterization of the precipitation, streamflow, and water-quality data collected at 43 sites between October 1, 2012, and September 30, 2014 (water years 2013 and 2014).Variations in the frequency of daily precipitation, seasonal distribution, and seasonal and annual precipitation at 5 stations at the U.S. Army Garrison Fort Carson and 18 stations at or near the Piñon Canyon Maneuver Site were evaluated. Isohyetal diagrams indicated a general pattern of increase in total annual precipitation from east to west at the U.S. Army Garrison Fort Carson and the Piñon Canyon Maneuver Site. Between about 54 and 79 percent of daily precipitation was 0.1 inch or less in magnitude. Precipitation events were larger and more frequent between July and September.Daily streamflow data from 16 sites were used to evaluate temporal and spatial variations in streamflow for the water years 2013 and 2014. At all sites, median daily mean streamflow for the 2-year period ranged from 0.0 to 9.60 cubic feet per second. Daily mean streamflow hydrographs are included in this report. Five sites on the Piñon Canyon Maneuver Site were monitored for peak stage using crest-stage gages.At the Piñon Canyon Maneuver Site, five sites had a stage recorder and precipitation gage, providing a paired streamflow-precipitation dataset. There was a statistically significant correlation between precipitation and streamflow based on Spearman’s rho correlation (rho values ranged from 0.17 to 0.35).Suspended-sediment samples were collected in April through October for water years 2013–14 at one site at the U.S. Army Garrison Fort Carson and five sites at the Pi

  9. Modeling precipitation and sorption of elements during mixing of river water and porewater in the Coeur d'Alene River basin

    USGS Publications Warehouse

    Balistrieri, L.S.; Box, S.E.; Tonkin, J.W.

    2003-01-01

    Reddish brown flocs form along the edge of the Coeur d'Alene River when porewater drains into river water during the annual lowering of water level in the basin. The precipitates are efficient scavengers of dissolved elements and have characteristics that may make metals associated with them bioavailable. This work characterizes the geochemistry of the porewater and models the formation and composition of the flocs. Porewater is slightly acidic, has suboxic to anoxic characteristics, tends to have higher alkalinity, and contains elevated concentrations of many constituents relative to river water. Laboratory mixing experiments involving porewater and river water were done to produce the precipitates. Thermodynamic predictions using PHREEQC indicate that predicted amounts of ferrihydrite and gibbsite agree with removal of Fe and Al. Predictions of element removal by adsorption onto ferrihydrite are consistent with observed removal using a combination of surface complexation constants for the generalized two-layer model (As and Se), alternative surface constants derived from experiments at high sorbate-to-sorbent ratios (Cd, Co, Cu, Ni, Pb, and Zn), and adjusted surface constants to fit experimental data (Cr, Mo, and Sb). This new set of surface complexation constants needs further testing in other contaminated systems.

  10. Acidification of soil-water in low base-saturated sand soils of the superior uplands under acid and normal precipitation.

    PubMed

    Harris, A R

    1989-04-01

    Lakes and streams are acidified by direct precipitation and water channeled through nearby soils, but water in low base-saturation soils can produce highly acidic percolate after prolonged contact and subsequent degassing in surface waters. Theories advanced by Reuss (1983), Reuss and Johnson (1985), and Seip and Rustad (1984) suggest that soils with less than 15% base saturation are susceptible to soil-water pH depression of up to 0.4 unit, which is sufficient to cause negative alkalinity in soil solutions. High concentrations of mobile anions (notably sulfate) are responsible for the negative alkalinity and these solutions on CO2 degassing in surface waters can retain acidities equivalent to a pH value of 5.0 or less. This mechanism purports to explain why some lakes acidify when they are surrounded by acid soils and cation leaching is not required.Ambient precipitation set to pH 5.4 and pH 4.2 was applied to columns of low base-saturated, sand, soils, starting in 1985. The columns (15 cm diameter and 150 cm long) were collected from soils with base saturations falling into one of three groups (0-10, 10-20, and 20-40%) from national forests in the Superior Uplands area (includes Boundary Waters Canoe Area, Rainbow Lakes, Sylvania, Moquah Barrens, and other Wilderness and Natural areas). The soils were Haplorthods and Udipsamments mainly from outwash plains.The soil columns were instrumented and reburied around a subterranean structure used to collect leachate water and to maintain natural temperature, air, and light conditions. Three humus treatments were applied to soil column (none, northern hardwood, and jack pine) to measure the effect of natural acidification compared to acidification by acid precipitation. The cores were treated with precipitation buffered to pH 5.4 to simulate natural rain and pH 4.2 to simulate acid rain.Columns were treated in 1985 and 1986 with approximately 200 cm of buffered precipitation each year over the frost-free season. Data is

  11. Precipitation and carbon-water coupling jointly control the interannual variability of global land gross primary production

    NASA Astrophysics Data System (ADS)

    Zhang, Yao; Xiao, Xiangming; Guanter, Luis; Zhou, Sha; Ciais, Philippe; Joiner, Joanna; Sitch, Stephen; Wu, Xiaocui; Nabel, Julia; Dong, Jinwei; Kato, Etsushi; Jain, Atul K.; Wiltshire, Andy; Stocker, Benjamin D.

    2016-12-01

    Carbon uptake by terrestrial ecosystems is increasing along with the rising of atmospheric CO2 concentration. Embedded in this trend, recent studies suggested that the interannual variability (IAV) of global carbon fluxes may be dominated by semi-arid ecosystems, but the underlying mechanisms of this high variability in these specific regions are not well known. Here we derive an ensemble of gross primary production (GPP) estimates using the average of three data-driven models and eleven process-based models. These models are weighted by their spatial representativeness of the satellite-based solar-induced chlorophyll fluorescence (SIF). We then use this weighted GPP ensemble to investigate the GPP variability for different aridity regimes. We show that semi-arid regions contribute to 57% of the detrended IAV of global GPP. Moreover, in regions with higher GPP variability, GPP fluctuations are mostly controlled by precipitation and strongly coupled with evapotranspiration (ET). This higher GPP IAV in semi-arid regions is co-limited by supply (precipitation)-induced ET variability and GPP-ET coupling strength. Our results demonstrate the importance of semi-arid regions to the global terrestrial carbon cycle and posit that there will be larger GPP and ET variations in the future with changes in precipitation patterns and dryland expansion.

  12. Precipitation and carbon-water coupling jointly control the interannual variability of global land gross primary production

    PubMed Central

    Zhang, Yao; Xiao, Xiangming; Guanter, Luis; Zhou, Sha; Ciais, Philippe; Joiner, Joanna; Sitch, Stephen; Wu, Xiaocui; Nabel, Julia; Dong, Jinwei; Kato, Etsushi; Jain, Atul K.; Wiltshire, Andy; Stocker, Benjamin D.

    2016-01-01

    Carbon uptake by terrestrial ecosystems is increasing along with the rising of atmospheric CO2 concentration. Embedded in this trend, recent studies suggested that the interannual variability (IAV) of global carbon fluxes may be dominated by semi-arid ecosystems, but the underlying mechanisms of this high variability in these specific regions are not well known. Here we derive an ensemble of gross primary production (GPP) estimates using the average of three data-driven models and eleven process-based models. These models are weighted by their spatial representativeness of the satellite-based solar-induced chlorophyll fluorescence (SIF). We then use this weighted GPP ensemble to investigate the GPP variability for different aridity regimes. We show that semi-arid regions contribute to 57% of the detrended IAV of global GPP. Moreover, in regions with higher GPP variability, GPP fluctuations are mostly controlled by precipitation and strongly coupled with evapotranspiration (ET). This higher GPP IAV in semi-arid regions is co-limited by supply (precipitation)-induced ET variability and GPP-ET coupling strength. Our results demonstrate the importance of semi-arid regions to the global terrestrial carbon cycle and posit that there will be larger GPP and ET variations in the future with changes in precipitation patterns and dryland expansion. PMID:28008960

  13. Precipitation and Carbon-Water Coupling Jointly Control the Interannual Variability of Global Land Gross Primary Production

    NASA Technical Reports Server (NTRS)

    Zhang, Yao; Xiao, Xiangming; Guanter, Luis; Zhou, Sha; Ciais, Philippe; Joiner, Joanna; Sitch, Stephen; Wu, Xiaocui; Nabel, Julian; Dong, Jinwei; Kato, Etsushi; Jain, Atul K.; Wiltshire, Andy; Stocker, Benjamin D.

    2016-01-01

    Carbon uptake by terrestrial ecosystems is increasing along with the rising of atmospheric CO2 concentration. Embedded in this trend, recent studies suggested that the interannual variability (IAV) of global carbon fluxes may be dominated by semi-arid ecosystems, but the underlying mechanisms of this high variability in these specific regions are not well known. Here we derive an ensemble of gross primary production (GPP) estimates using the average of three data-driven models and eleven process-based models. These models are weighted by their spatial representativeness of the satellite-based solar-induced chlorophyll fluorescence (SIF). We then use this weighted GPP ensemble to investigate the GPP variability for different aridity regimes. We show that semi-arid regions contribute to 57% of the detrended IAV of global GPP. Moreover, in regions with higher GPP variability, GPP fluctuations are mostly controlled by precipitation and strongly coupled with evapotranspiration (ET). This higher GPP IAV in semi-arid regions is co-limited by supply (precipitation)-induced ET variability and GPP-ET coupling strength. Our results demonstrate the importance of semi-arid regions to the global terrestrial carbon cycle and posit that there will be larger GPP and ET variations in the future with changes in precipitation patterns and dryland expansion.

  14. GPS monitoring of the tropospheric water vapor distribution and variation during the 9 September 2002 torrential precipitation episode in the Cévennes (southern France)

    NASA Astrophysics Data System (ADS)

    Champollion, C.; Masson, F.; van Baelen, J.; Walpersdorf, A.; ChéRy, J.; Doerflinger, E.

    2004-12-01

    On 8-9 September 2002, torrential rainfall and flooding hit the Gard region in southern France causing extensive damages and casualties. This is an exceptional example of a so-called Cévenol episode with 24 hour cumulative rainfall up to about 600 mm at some places and more than 200 mm over a large area (5500 km2). In this work we have used GPS data to determine integrated water vapor (IWV) as well as horizontal wet gradients and residuals. Using the IWV, we have monitored the evolution of the convective system associated with the rainfall from the water vapor accumulation stage through the stagnation of the convective cell and finally to the breakup of the system. Our interpretation of the GPS meteorological parameters is supported by synoptic maps, numerical weather analyses, and rain images from meteorological radars. We have evidenced from GPS data that this heavy precipitation is associated with ongoing accumulation of water vapor, even through the raining period, but that rain stopped as soon as the weather circulation pattern changed. The evolution of this event is typical in the context of the Cévenol meteorology. Furthermore, we have shown that the horizontal wet gradients help describe the heterogeneity of the water vapor field and holds information concerning the passage of the convective system. Finally, we have noticed that the residuals, which in theory should be proportional to water vapor heterogeneity, were also highly perturbed by the precipitation itself. In our conclusions we discuss the interest of a regional GPS network for monitoring and for future studies on water vapor tomography.

  15. Annual and average estimates of water-budget components based on hydrograph separation and PRISM precipitation for gaged basins in the Appalachian Plateaus Region, 1900-2011

    USGS Publications Warehouse

    Nelms, David L.; Messinger, Terence; McCoy, Kurt J.

    2015-07-14

    As part of the U.S. Geological Survey’s Groundwater Resources Program study of the Appalachian Plateaus aquifers, annual and average estimates of water-budget components based on hydrograph separation and precipitation data from parameter-elevation regressions on independent slopes model (PRISM) were determined at 849 continuous-record streamflow-gaging stations from Mississippi to New York and covered the period of 1900 to 2011. Only complete calendar years (January to December) of streamflow record at each gage were used to determine estimates of base flow, which is that part of streamflow attributed to groundwater discharge; such estimates can serve as a proxy for annual recharge. For each year, estimates of annual base flow, runoff, and base-flow index were determined using computer programs—PART, HYSEP, and BFI—that have automated the separation procedures. These streamflow-hydrograph analysis methods are provided with version 1.0 of the U.S. Geological Survey Groundwater Toolbox, which is a new program that provides graphing, mapping, and analysis capabilities in a Windows environment. Annual values of precipitation were estimated by calculating the average of cell values intercepted by basin boundaries where previously defined in the GAGES–II dataset. Estimates of annual evapotranspiration were then calculated from the difference between precipitation and streamflow.

  16. Precipitation-runoff relations and water-quality characteristics at edge-of-field stations, Discovery Farms and Pioneer Farm, Wisconsin, 2003-8

    USGS Publications Warehouse

    Stuntebeck, Todd D.; Komiskey, Matthew J.; Peppler, Marie C.; Owens, David W.; Frame, Dennis R.

    2011-01-01

    A cooperative study between the U.S. Geological Survey, the University of Wisconsin (UW)-Madison Discovery Farms program (Discovery Farms), and the UW-Platteville Pioneer Farm program (Pioneer Farm) was developed to identify typical ranges and magnitudes, temporal distributions, and principal factors affecting concentrations and yields of sediment, nutrients, and other selected constituents in runoff from agricultural fields. Hydrologic and water-quality data were collected year-round at 23 edge-of-field monitoring stations on 5 privately owned Discovery Farms and on Pioneer Farm during water years 2003-8. The studied farms represented landscapes, soils, and farming systems typical of livestock farms throughout southern Wisconsin. Each farm employed a variety of soil, nutrient, and water-conservation practices to help minimize sediment and nutrient losses from fields and to improve crop productivity. This report summarizes the precipitation-runoff relations and water-quality characteristics measured in edge-of-field runoff for 26 "farm years" (aggregate years of averaged station data from all 6 farms for varying monitoring periods). A relatively wide range of constituents typically found in agricultural runoff were measured: suspended sediment, phosphorus (total, particulate, dissolved reactive, and total dissolved), and nitrogen (total, nitrate plus nitrite, organic, ammonium, total Kjeldahl and total Kjeldahl-dissolved), chloride, total solids, total suspended solids, total volatile suspended solids, and total dissolved solids. Mean annual precipitation was 32.8 inches for the study period, about 3 percent less than the 30-year mean. Overall mean annual runoff was 2.55 inches per year (about 8 percent of precipitation) and the distribution was nearly equal between periods of frozen ground (54 percent) and unfrozen ground (46 percent). Mean monthly runoff was highest during two periods: February to March and May to June. Ninety percent of annual runoff occurred

  17. Acid precipitation: Effects on fresh water ecosystems. (Latest citations from the Life Sciences Collection database). Published Search

    SciTech Connect

    Not Available

    1993-05-01

    The bibliography contains citations concerning the effects of acidification on fresh water ecosystems. Algae and diatom distribution, survival and reproduction rates of specific fish species under acid lake conditions, and tolerance to stress caused by acidic conditions in fresh water ecosystems are studied. Effects of water pH on trace metal toxicity to fresh water organisms are briefly considered. Control and reduction of acidification are excluded from this bibliography. (Contains 250 citations and includes a subject term index and title list.)

  18. Use of a water-soluble fullerene derivative as precipitating reagent and matrix-assisted laser desorption/ionization matrix to selectively detect charged species in aqueous solutions.

    PubMed

    Shiea, Jentaie; Huang, Jen-Pan; Teng, Chia-Fong; Jeng, Jingyueh; Wang, Lee Y; Chiang, Long Y

    2003-07-15

    A starlike water-soluble fullerene derivative, hexa(sulfonbutyl)fullerene (C60[(CH2)4SO3-]6; HSBF), consisting of a C60 cage covalently bonded with six negatively charged sulfonate arms, was synthesized and used to selectively precipitate positively charged surfactants, amino acids, peptides, and proteins. The affinity of HSBF to the analytes depends on the charge, structure, and hydrophobic characteristics of the analytes. The ion pair precipitate was easily removed from the solution by centrifugation. After washing, the precipitate was redissolved in the solvent or buffer solution and the analyte was characterized by laser desorption ionization-time-of-flight mass spectrometry (LD-TOF). HSBF shows strong optical absorbance in the UV range, so no additional organic matrix was required to conduct LD-TOF analysis of small analytes. For the solution that contained five quaternary amines differing only in alkyl chain length, HSBF exhibits the highest affinity to the amine with the longest alkyl chain. Only the arginine signal was detected from the solution that contained 14 amino acids. The peptides with arginine as the end groups interacted most strongly with HSBF and could be selectively precipitated from a solution of a mixture of five peptides. The signals associated with a trace amount of charged peptides derived from the digestion of proteins by trypsin were greatly enhanced after concentration with HSBF. Among eight proteins in the sample solution, insulin had the strongest affinity to the HSBF and exhibited the strongest signal on the matrix-assisted laser desorption/ionization mass spectrum.

  19. pH-driven solubilization and isoelectric precipitation of proteins from the brown seaweed Saccharina latissima-effects of osmotic shock, water volume and temperature.

    PubMed

    Vilg, Jenny Veide; Undeland, Ingrid

    2017-01-01

    In the light of the global search for novel and sustainable protein sources, macroalgal proteins are becoming an attractive target. To date, mainly red and green macroalgae have been investigated in this respect, whereas the brown species are less studied, possibly because of the lower content of protein. In a biorefinery context, however, the protein content of brown macroalgae can still be economically interesting due to fast growth and the possibility to co-extract other compounds, such as alginates. The aim of this study was to develop a simple, scalable pH shift-based protein isolation technique applicable on wet Saccharina latissima biomass. Factors investigated were extraction volume, temperature, protein solubilization pH, osmoshock pretreatment and protein precipitation pH. Maximum protein solubility was obtained at pH 12, where 34 % of the total protein content could be extracted with 5.56 volumes of extraction solution (20 volumes on dry weight (dw) basis). Osmoshocking significantly increased the yield, and 20, 40 and 60 volumes of water (dw basis) gave 45.1, 46.8 and 59.5 % yield, respectively. The temperature during osmoshocking did not significantly affect the extraction yield, and extended time (16 vs. 1 or 2 h) reduced protein yield. Precipitation of solubilized proteins was possible below pH 4; the highest precipitation yield, 34.5 %, was obtained at pH 2. After combined alkaline extraction and acid precipitation, 16.01 % of the Saccharina proteins were recovered, which can be considered acceptable in comparison to other studies on algae but leaves some room for improvement when compared to protein extraction from, for instance, soy.

  20. Simulation of stable isotopic pools and fluxes by a land-surface scheme forced with observed isotopic ratios in precipitation and atmospheric water vapour.

    NASA Astrophysics Data System (ADS)

    Henderson-Sellers, A.; Griffith, D.; Irannejad, P.; Williams, A.; Stone, D.

    2004-12-01

    Stable isotopes provide independent tools for evaluating key components of the hydrological and carbon cycles as simulated by land-surface schemes (LSS). The Project for Intercomparison of Land-surface Parameterisation Schemes (PILPS http://www.pilps.mq.edu.au) is initiating a new type of experiment (IPILPS) to assess the ability of LSSs to reproduce isotopic components of water and mass (carbon) budgets. The project aims to intercompare LSS simulations of diurnal and annual cycles of isotopic pools and fluxes, and to evaluate the performance of isotope-enabled LSSs under varying environmental conditions. The need for evaluation data is driving a new experimental effort concentrating on the measurement of stable water isotopes (SWI), in precipitation, atmospheric and canopy water vapour, soil water and leaf/stem water, on annual and diurnal time scales at three sites in the GEWEX CSE Amazon, Murray-Darling and Baltic Sea basins. We present diurnal and annual cycles of stable isotopes in the ecosystem as simulated by an isotope enabled LSS (ISOLSM)1 over an agricultural pasture in Wagga Wagga (SE Australia). Climatological values of SWI in precipitation and water vapour, as well as continuous in situ D/H ratios of atmospheric water vapour obtained during a three-week field campaign, are used to force the LSS. The D/H ratio was measured using a fully automated and mobile Fourier Transform Infrared (FTIR)2 spectrometer. The sensitivity of simulated isotopes (in soil water, plants and canopy air space, as well as isotopic exchanges between the land surface and the atmosphere) to the atmospheric forcing is analysed. The results highlight the importance of intensive field campaigns for measuring SWI in the environment as both forcing and evaluation data for land surface simulations. 1. A. Henderson-Sellers et al., 2004, Using stable water isotopes to evaluate basin-scale simulations of surface water budgets, in press, J. Hydrometeorol. 2. D.W.T. Griffith et al., 2002

  1. Coupling of continuous in situ ecosystem water vapor, precipitation, plant and soil water isotope (δ2H, δ18O and d-excess) measurements in Arctic Alaska to understand a changing water cycle

    NASA Astrophysics Data System (ADS)

    Welker, J. M.; Klein, E. S.; Leffler, J.; Cherry, J. E.; Young, J. M.

    2013-12-01

    A changing Arctic water cycle is focusing our efforts on the patterns and processes governing the exchange of water between the land surface and the atmosphere. We initiated a NSF EAGER study of the changing Arctic water cycle with a cross-scale water isotope (ecosystem-landscape and region) study employing tower, aircraft and satellite measurements in N Alaska. At the land surface, we measured in situ, continuous ecosystem δ2H and δ18O in water vapor isotopes along a vertical profile (0.1 to 3 m) in late winter, spring, and summer of 2013 at the Toolik Lake Field Station in Arctic Alaska. The continuous water vapor measurements are being combined with soil, plant and precipitation water isotope measurements, and species-level transpiration rates. Diurnal patterns of δ2H values in water vapor vary systematically from the soil surface, through the plant canopy and in the near boundary layer ranging between -200 ‰ at the surface to -240 ‰ at 3 m. These vertical patterns were also observed in d-excess ranging from 5 ‰ near the soil surface to -15 ‰ at 3 m. These patterns disappeared at night indicating their link with evapotranspiration. These data will serve as the foundation for a Bayesian model to articulate the sources, species, and processes governing the exchange of H2O with the lower boundary layer; and will also help to calibrate ecosystem, landscape (aircraft) and regional (satellite) measurements of the water vapor isotopes above different vegetation types (tussock tundra, riparian tundra, and recently burned tundra) and regions (Northern Foothills of the Brooks Range and the Arctic Coastal Plain). Continuous water vapor isotope traits in Arctic Tundra from the soil surface (0.02 m) to 3 m above the tundra for a window of time during the 2013 growing season. The diurnal patterns depict the evidence for transpiration and evaporation as the values above the soil (0.02 m) and in the canopy (0.2m) are enriched during the day and become depleted during

  2. An investigation of the existence of a surface water layer on aircraft radomes during simulated flight in heavy precipitation

    NASA Technical Reports Server (NTRS)

    Branstetter, J. R.; Bailey, M. C.; Hearn, C. P.; Dunham, R. E., Jr.; Couch, R. H.; Verstynen, H. A.; Gentry, L., Jr.; Williams, J. B.

    1984-01-01

    An experiment to investigate the electromagnetic attenuation effects of an impacting water spray on an aircraft weather radome was conducted in Langley's 4 X 7 m. wind tunnel equipped with a water spray system. Results indicate no significant liquid water film formed at the stagnation point of the radome under the test conditions. However, a water sheath was observed standing away from the radome surface, which could possibly have significant attenuation properties of its own. Due to the lack of fidelity in modeling both the natural environment with the tunnel apparatus and the water sheath, it is recommended that further studies be undertaken to better define the water distribution in the vicinity of the radome and measure its effect on weather radar performance.

  3. Field and modelling investigations of fresh-water plume behaviour in response to infrequent high-precipitation events, Sydney Estuary, Australia

    NASA Astrophysics Data System (ADS)

    B., Serena; Lee | Gavin, F.; Birch | Charles, J.; Lemckert

    2011-05-01

    Runoff from the urban environment is a major contributor of non-point source contamination for many estuaries, yet the ultimate fate of this stormwater within the estuary is frequently unknown in detail. The relationship between catchment rainfall and estuarine response within the Sydney Estuary (Australia) was investigated in the present study. A verified hydrodynamic model (Environmental Fluid Dynamics Computer Code) was utilised in concert with measured salinity data and rainfall measurements to determine the relationship between rainfall and discharge to the estuary, with particular attention being paid to a significant high-precipitation event. A simplified rational method for calculating runoff based upon daily rainfall, subcatchment area and runoff coefficients was found to replicate discharge into the estuary associated with the monitored event. Determining fresh-water supply based upon estuary conditions is a novel technique which may assist those researching systems where field-measured runoff data are not available and where minor field-measured information on catchment characteristics are obtainable. The study concluded that since the monitored fresh-water plume broke down within the estuary, contaminants associated with stormwater runoff due to high-precipitation events (daily rainfall > 50 mm) were retained within the system for a longer period than was previously recognised.

  4. Leaching behavior of microtektite glass compositions in sea water and the effect of precipitation on glass leaching

    NASA Technical Reports Server (NTRS)

    1991-01-01

    The present study attempts to account for the slow corrosion rates of microtektite glass in nature by comparing the leach rates of synthetic microtektite glass samples in deionized water and in sea-water, respectively. In order to obtain systematic data about leachant composition effects, leach tests were also carried out with synthetic leachant compositions enriched with respect to silica or depleted with respect to certain major components of sea-water (Mg, Ca).

  5. Ground-water levels and precipitation data at the Maxey Flats low-level radioactive waste disposal site near Morehead, Kentucky, October 1988-September 2000

    USGS Publications Warehouse

    Zettwoch, Douglas D.

    2002-01-01

    The U.S. Geological Survey, in cooperation with the Kentucky Natural Resources and Environmental Protection Cabinet--Department for Environmental Protection--Division of Waste Management, has an ongoing program to monitor water levels at the Maxey Flats low-level radioactive waste disposal site near Morehead, Kentucky. Ground-water-level and precipitation data were collected from 112 wells and 1 rain gage at the Maxey Flats low-level radioactive waste disposal site during October 1988-September 2000. Data were collected on a semi-annual basis from 62 wells, continuously from 6 wells, and monthly or bimonthly from 44 wells (13 of which had continuous recorders installed for the period October 1998-September 2000). One tipping-bucket rain gage was used to collect data at the Maxey Flats site for the period October 1988-September 2000.

  6. Acidic precipitation

    SciTech Connect

    Martin, H.C.

    1987-01-01

    At the International Symposium on Acidic Precipitation, over 400 papers were presented, and nearly 200 of them are included here. They provide an overview of the present state of the art of acid rain research. The Conference focused on atmospheric science (monitoring, source-receptor relationships), aquatic effects (marine eutrophication, lake acidification, impacts on plant and fish populations), and terrestrial effects (forest decline, soil acidification, etc.).

  7. Water Chemistry Impacts on Arsenic Mobilization from Arsenopyrite Dissolution and Secondary Mineral Precipitation: Implications for Managed Aquifer Recharge

    EPA Science Inventory

    Managed Aquifer Recharge (MAR) is one water reuse technique with the potential to meet growing water demands. However, MAR sites have encountered arsenic remobilization resulting from recharge operations. To combat this challenge, it is important to identify the mechanism of arse...

  8. Cultivar by environment effects of perennial ryegrass cultivars selected for high water soluble carbohydrates managed under differing precipitation levels

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Historic results of perennial ryegrass (Lolium perenne L.) breeding include improved disease resistance, biomass, and nutritional quality. Yet, lack of tolerance to water stress limits its wise use. Recent efforts to increase water soluble carbohydrate (WSC) content in perennial ryegrass may incre...

  9. A simulation study of the recession coefficient for antecedent precipitation index. [soil moisture and water runoff estimation

    NASA Technical Reports Server (NTRS)

    Choudhury, B. J.; Blanchard, B. J.

    1981-01-01

    The antecedent precipitation index (API) is a useful indicator of soil moisture conditions for watershed runoff calculations and recent attempts to correlate this index with spaceborne microwave observations have been fairly successful. It is shown that the prognostic equation for soil moisture used in some of the atmospheric general circulation models together with Thornthwaite-Mather parameterization of actual evapotranspiration leads to API equations. The recession coefficient for API is found to depend on climatic factors through potential evapotranspiration and on soil texture through the field capacity and the permanent wilting point. Climatologial data for Wisconsin together with a recently developed model for global isolation are used to simulate the annual trend of the recession coefficient. Good quantitative agreement is shown with the observed trend at Fennimore and Colby watersheds in Wisconsin. It is suggested that API could be a unifying vocabulary for watershed and atmospheric general circulation modelars.

  10. Removal of H 2S via an iron catalytic cycle and iron sulfide precipitation in the water column of dead end tributaries

    NASA Astrophysics Data System (ADS)

    Ma, Shufen; Noble, Abigail; Butcher, Derek; Trouwborst, Robert E.; Luther, George W., III

    2006-11-01

    The oxidation and precipitation of H 2S were investigated in Torquay Canal and Bald Eagle Creek, two tributaries of northern Rehoboth Bay, one of the Delaware Inland Bays. These man-made dead end canals develop seasonal anoxia and have been the site of past fish kills and harmful algal blooms. The canals have multiple holes over 5.5 m deep compared to an average low tide depth of 2 m. In situ determination for dissolved O 2, H 2S and other Fe and S redox species were conducted with a solid-state Au/Hg microelectrode in 2003 and 2004. Laboratory analyses of discrete samples were also performed to measure dissolved and particulate Fe, Mn, and S 8 to follow the seasonal dynamics of O, S, Fe and Mn redox species. Our results indicate that the water in the holes becomes stratified with O 2 decreasing with depth and H 2S increasing with depth. Dissolved Fe was as high as 30 μM whereas dissolved Mn was only 0.2 μM in the water column, indicating that Fe is the dominant metal involved in S redox cycling and precipitation. In surface oxic waters, the dominant form of Fe was particulate Fe(III) (oxy)hydroxides. When seasonal anoxia developed, Fe(III) (oxy)hydroxides were reduced by H 2S to Fe(II) at the oxic-anoxic interface. The Fe(II) reduced from particulate Fe can be re-oxidized to Fe(III) by O 2 above and at the interface to form a catalytic cycle to oxidize H 2S. Elemental S is the predominant oxidation product and was as high as 30 μM level (as S 0) at the interface. When the system was stable, the Fe catalytic cycle prevented H 2S from being released into surface waters during seasonal anoxia. However, when storms came, the water column was overturned and H 2S was released to the surface water. The reaction rates for the Fe catalytic cycle are not fast enough and the concentration of Fe was not high enough to regulate the high concentration of H 2S in surface waters during storm and mixing events.

  11. Spatiotemporal variation of the surface water effect on the groundwater recharge in a low-precipitation region: Application of the multi-tracer approach to the Taihang Mountains, North China

    NASA Astrophysics Data System (ADS)

    Sakakibara, Koichi; Tsujimura, Maki; Song, Xianfang; Zhang, Jie

    2017-02-01

    Groundwater recharge variations in time and space are crucial for effective water management, especially in low-precipitation regions. To determine comprehensive groundwater recharge processes in a catchment with large seasonal hydrological variations, intensive field surveys were conducted in the Wangkuai Reservoir watershed located in the Taihang Mountains, North China, during three different times of the year: beginning of the rainy season (June 2011), mid-rainy season (August 2012), and dry season (November 2012). Oxygen and hydrogen isotope and chemical analyses were conducted on the groundwater, spring water, stream water, and reservoir water of the Wangkuai Reservoir watershed. The results were processed using endmember mixing analysis to determine the amount of contribution of the groundwater recharging processes. Similar isotopic and chemical signatures between the surface water and groundwater in the target area indicate that the surface water in the mountain-plain transitional area and the Wangkuai Reservoir are the principal groundwater recharge sources, which result from the highly permeable geological structure of the target area and perennial large-scale surface water, respectively. Additionally, the widespread and significant effect of the diffuse groundwater recharge on the Wangkuai Reservoir was confirmed with the deuterium (d) excess indicator and the high contribution throughout the year, calculated using endmember mixing analysis. Conversely, the contribution of the stream water to the groundwater recharge in the mountain-plain transitional area clearly decreases from the beginning of the rainy season to the mid-rainy season, whereas that of the precipitation increases. This suggests that the main groundwater recharge source shifts from stream water to episodic/continuous heavy precipitation in the mid-rainy season. In other words, the surface water and precipitation commonly affect the groundwater recharge in the rainy season, whereas the

  12. Speciation and precipitation of heavy metals in high-metal and high-acid mine waters from the Iberian Pyrite Belt (Portugal).

    PubMed

    Durães, Nuno; Bobos, Iuliu; da Silva, Eduardo Ferreira

    2017-02-01

    Acid mine waters (AMW) collected during high- and low-flow water conditions from the Lousal, Aljustrel, and São Domingos mining areas (Iberian Pyrite Belt) were physicochemically analyzed. Speciation calculation using PHREEQC code confirms the predominance of Me(n+) and Me-SO4 species in AMW samples. Higher concentration of sulfate species (Me-SO4) than free ion species (Me(n+), i.e., Al, Fe, and Pb) were found, whereas opposite behavior is verified for Mg, Cu, and Zn. A high mobility of Zn than Cu and Pb was identified. The sulfate species distribution shows that Fe(3+)-SO4(2-), SO4(2-), HSO4(-), Al-SO4, MgSO4(0), and CaSO4(0) are the dominant species, in agreement with the simple and mixed metal sulfates and oxy-hydroxysulphates precipitated from AMW. The saturation indices (SI) of melanterite and epsomite show a positive correlation with Cu and Zn concentrations in AMW, which are frequently retained in simple metal sulfates. Lead is well correlated with jarosite and alunite (at least in very acid conditions) than with simple metal sulfates. The Pb for K substitution in jarosite occurs as increasing Pb concentration in solution. Lead mobility is also controlled by anglesite precipitation (a fairly insoluble sulfate), where a positive correlation was ascertained when the SI approaches equilibrium. The zeta potential of AMW decreased as pH increased due to colloidal particles aggregation, where water species change from SO4(2-) to OH(-) species during acid to alkaline conditions, respectively. The AMW samples were supersaturated in schwertmannite and goethite, confirmed by the Me(n+)-SO4, Me(n+)-Fe-O-OH, or Me(n+)-S-O-Fe-O complexes identified by attenuated total reflectance infrared spectroscopy (ATR-IR). The ATR-IR spectrum of an AMW sample with pH 3.5 (sample L1) shows well-defined vibration plans attributed to SO4 tetrahedron bonded with Fe-(oxy)hydroxides and the Me(n+) sorbed by either SO4 or Fe-(oxy)hydroxides. For samples with lower pH values (pH ~ 2

  13. Elevated concentrations of arsenic, predominance of thioarsenates, and orpiment precipitation on the seafloor at the marine shallow-water hydrothermal system off Milos Island, Greece

    NASA Astrophysics Data System (ADS)

    Price, R. E.; Planer-Friedrich, B.; Savov, I. P.; Pichler, T.

    2009-12-01

    Marine shallow-water hydrothermal vents off Milos Island, Greece, are discharging a low pH, high temperature, highly sulfidic brine into the coastal ocean. We present here the discovery that hydrothermal fluids are extremely elevated in arsenic (maximum ~78 μM (5.9 mg/L)), or almost 3000 times sea water concentration). This is the highest concentration of arsenic reported for marine hydrothermal vents to date. Ion microprobe analysis confirmed that red hydrothermal precipitates on the seafloor are orpiment (As2S3). Two sites were investigated; Palaeochori Bay, where abundant gas discharge is surrounded by large white and red patches of hydrothermal precipitates in 3-5 meters water depth, and Spathi Bay, a deeper site (~18 meters) where large patches of white hydrothermal precipitates occur. Total arsenic was measured on the hydrothermal fluids, as well as on fluids from brown areas surrounding the white and red patches. These 4 areas contained total arsenic concentrations of 20 (brown), 640 (white), 2700 (red), and 5900 μg/L (Spathi). Arsenic speciation analysis of the hydrothermal fluids revealed arsenite, arsenate, and mono-, di-, and trithioarsenate as the major species present in hydrothermal fluids. Fluids from the red area at Palaeochori Bay contained predominantly arsenite (77 %) followed by arsenate (14 %), then monothioarsenate (7 %) and dithioarsenate (1%). The hydrothermal fluids from the Palaeochori Bay white area were dominantly arsenite (49 %) and dithioarsenate (29 %), followed by arsenate, monothioarsenate, and trithioarsenate (9, 9, and 2 %, respectively). The brown area in Palaeochori Bay contained a similar distribution of arsenic species compared to the white area, only at much lower concentrations. Finally, the Spathi Bay site, which contained overall higher H2S and lower pH, was dominated by trithioarsenate (50%), followed by arsenite (24%), dithioarsenate (22%), and low abundances of monothioarsenate (3%) and arsenate (1%). Each of the

  14. Estimates of ground-water recharge from precipitation to glacial-deposit and bedrock aquifers on Lopez, San Juan, Orcas, and Shaw islands, San Juan County, Washington

    USGS Publications Warehouse

    Orr, Laura A.; Bauer, Henry H.; Wayenberg, Judith A.

    2002-01-01

    An important source of fresh water on Lopez, San Juan, Orcas, and Shaw Islands in San Juan County off the northwestern coast of Washington is glacial-deposit and bedrock aquifers. Two methods were used to estimate recharge from precipitation to the water tables on the islands. A daily near-surface water-balance method, the Deep Percolation Model (DPM), was used to simulate water budgets for the period October 1, 1996, through September 30, 1998 (water years 1997-98) for six small drainage basins?three on Lopez Island and one each on San Juan, Orcas, and Shaw Islands. The calibrated soil and subsoil parameters from the DPM for each small basin were then used in island-wide applications of the DPM where the direct runoff component (which is not available on an island-wide basis) was simulated, rather than input, and calibration was not required. A spatial distribution of annual recharge was simulated for each island, with island averages of: Lopez Island, 2.49 inches per year; San Juan Island, 1.99 inches per year; Orcas Island, 1.46 inches per year; and Shaw Island, 1.44 inches per year.A chloride mass-balance method that requires measurements of atmospheric chloride deposition, precipitation, streamflow, and chloride concentrations in ground water was used to estimate recharge to the glacial-deposit aquifers of Lopez Island. Only average recharge could be estimated using this method rather than area-specific recharge. Average recharge for Lopez Island estimated by this method was only 0.63 inch per year. The range of chloride concentrations in ground-water samples from selected wells indicates that the average recharge in areas of glacial deposits is between 0.29 and 1.95 inches per year. Recharge simulated using the DPM for two drainage basins on Lopez Island overlain by glacial deposits are 2.76 and 2.64 inches per year. Sources of chloride in ground water other than from the atmosphere would cause the recharge estimated by the chloride mass-balance method to be

  15. Precipitation Measurements from Space: The Global Precipitation Measurement Mission

    NASA Technical Reports Server (NTRS)

    Hou, Arthur Y.

    2007-01-01

    Water is fundamental to the life on Earth and its phase transition between the gaseous, liquid, and solid states dominates the behavior of the weather/climate/ecological system. Precipitation, which converts atmospheric water vapor into rain and snow, is central to the global water cycle. It regulates the global energy balance through interactions with clouds and water vapor (the primary greenhouse gas), and also shapes global winds and dynamic transport through latent heat release. Surface precipitation affects soil moisture, ocean salinity, and land hydrology, thus linking fast atmospheric processes to the slower components of the climate system. Precipitation is also the primary source of freshwater in the world, which is facing an emerging freshwater crisis in many regions. Accurate and timely knowledge of global precipitation is essential for understanding the behavior of the global water cycle, improving freshwater management, and advancing predictive capabilities of high-impact weather events such as hurricanes, floods, droughts, and landslides. With limited rainfall networks on land and the impracticality of making extensive rainfall measurements over oceans, a comprehensive description of the space and time variability of global precipitation can only be achieved from the vantage point of space. This presentation will examine current capabilities in space-borne rainfall measurements, highlight scientific and practical benefits derived from these observations to date, and provide an overview of the multi-national Global Precipitation Measurement (GPM) Mission scheduled to bc launched in the early next decade.

  16. Effects of acidic precipitation on the water quality of streams in the Laurel Hill area, Somerset County, Pennsylvania, 1983-86

    USGS Publications Warehouse

    Barker, J.L.; Witt, E. C.

    1990-01-01

    Five headwater streams in the Laurel Hill area in southwestern Pennsylvania were investigated from September 1983 through February 1986 to determine possible effects of acidic precipitation on water quality. Precipitation in the Laurel Hill area is among the most acidic in the Nation, with a mean volume-weighted pH of 4.06. Sulfate is the dominant acid-forming anion, averaging 3.6 milligrams per liter or about 50 kilograms per hectare in wet deposition alone. Nitrate averages about 2 milligrams per liter or 7 kilograms per hectare in the study area. Stream chemistry in the five streams is quite variable and apparently is influenced to a large degree by the bedrock geology and by small amounts of alkaline material in watershed soils. Three of the five streams with no or little acid-neutralizing capacity presently are devoid of fish because of low pH and elevated aluminum concentrations. Aluminum concentrations increase in the other two streams during rainfall and snowmelt despite comparatively higher base flow and acid-neutralizing capacities. Comparison of the chemistry of streamflow during 14 storm events at South Fork Bens Creek and North Fork Bens Creek reveals similar chemical responses when discharge suddenly increases. Concentrations of dissolved metals and sulfate increased during stormflow and snowmelt runoff, whereas concentrations of base cations, silica, and chloride decreased. Nitrate concentrations were not affected by rainfall runoff by tended to increase with snowmelt runoff.

  17. Synthesis of nanostructured β-Ni(OH)2 by electrochemical dissolution-precipitation and its application as a water oxidation catalyst

    NASA Astrophysics Data System (ADS)

    Jung, Sang Cheol; Sim, Soong Leong; Woan Soon, Ying; Lim, Chee Ming; Hing, Peter; Jennings, James Robert

    2016-07-01

    A straightforward electrochemical dissolution-precipitation approach has been developed to synthesize nanostructured β-Ni(OH)2 powders (particle size 10-100 nm, specific surface area ˜100 m2 g-1) from Ni metal anodes. The approach differs from existing electrochemical synthesis methods in that it predominantly results in bulk precipitation of nanoparticles, without significant film growth on either of the electrodes. Heat treatment of the as-synthesized β-Ni(OH)2 afforded NiO with mostly preserved nanostructure and very high specific surface area (≤100 m2 g-1, depending on calcination temperature). The as-synthesized β-Ni(OH)2 was found to be an excellent catalyst for the oxygen evolution reaction (OER) in the technologically important water electrolysis process, apparently contradicting recent reports that the α polymorph is required for such high activity. With catalyst loadings <0.1 mg cm-2, OER current densities of 10 mA cm-2 were sustained at overpotentials as low as 340 mV, with Tafel slopes of only ˜38 mV/decade. The catalyst was highly stable in alkaline media over the course of electrolysis experiments lasting for several hours. This performance surpasses that of many previously reported earth-abundant OER catalysts and is comparable to that obtained with state-of-the-art RuO2 and IrO2 catalysts.

  18. Effect of solvents and precipitant on the properties of chitosan nanoparticles in a water-in-oil microemulsion and its lipase immobilization performance.

    PubMed

    Wu, Yue; Wang, Yujun; Luo, Guangsheng; Dai, Youyuan

    2010-02-01

    When chitosan nanoparticles were prepared in a water-in-oil (W/O) microemulsion by using 2% (wt) acetic acid (HAc) and 30% (wt) tri-n-octylamine (TOA) as solvent and precipitant, respectively, particle diameters of 7 nm were observed and the particles formed ovoid shaped aggregates. Using 0.05% HCl and 5.0M NaOH as solvent and precipitant produced nanoparticles 10nm in size that aggregated in the form of snowflakes. These two types of nanoparticles were used to immobilize lipase, the lipase adsorption capacity using nanoparticles 7 nm in size reached 156 mg/g and activity retention compared to free enzyme was as high as 66.7%, and the residual activity of the immobilized lipase was 91% after 5 runs of reaction. In additional, the activity retention of nanoparticles 10nm in size also could reach 62.8%. This indicated that the chitosan nanoparticles prepared in a W/O microemulsion were suitable for lipase immobilization.

  19. Temporal trends of bulk precipitation and stream water chemistry (1977-1997) in a small forested area, Krusne hory, northern Bohemia, Czech Republic

    USGS Publications Warehouse

    Peters, N.E.; Cerny, J.; Havel, M.; Krejci, R.

    1999-01-01

    The Krusne hory (Erzgebirge or Ore Mountains) has been heavily affected by high atmospheric pollutant deposition caused by fossil fuel combustion in an adjacent Tertiary coal basin. Long-term routine sampling of bulk precipitation (1977-1996) and stream water (1977-1998) in a forested area on the south-eastern slope of the mountains were used to evaluate trends and patterns in solute concentration and flux with respect to controlling processes. From 1977 to 1996, the annual volume-weighted Ca2+ and SO42- concentrations decreased in bulk precipitation. However, after 1989, when a pronounced and continuous decrease occurred in coal production, annual volume-weighted concentrations decreased for most solutes, except H+. The concentration decreases were marked, with 1996 levels at or below 50% of those in 1989. The lack of a trend in H+ is attributed to similar decreases in both acid anions and neutralizing base cations. Stream water concentrations of most solutes, i.e. H+, Ca2+, Mg2+, SO42- and NO3-, were highest at the onset of sampling in 1977, decreased markedly from 1977 to 1983 and decreased more gradually from 1983 to 1998. The spruce forest die-back and removal reduced dry deposition of these solutes by reducing the filtering action, which was provided by the forest canopy. A notable decrease in stream water Ca2+ concentrations occurred after 1995 and may be due to the depletion of Ca2+, which was provided by catchment liming in 1986, 1988 and 1989. Solute flux trends in bulk atmospheric deposition and stream water generally were not significant and the lack of trend is attributed to the large interannual variabilit