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Sample records for absolute absorption cross-section

  1. Absolute UV absorption cross sections of dimethyl substituted Criegee intermediate (CH3)2COO

    NASA Astrophysics Data System (ADS)

    Chang, Yuan-Pin; Chang, Chun-Hung; Takahashi, Kaito; Lin, Jim-Min, Jr.

    2016-06-01

    The absolute absorption cross sections of (CH3)2COO under a jet-cooled condition were measured via laser depletion to be (1.32 ± 0.10) × 10-17 cm2 molecule-1 at 308 nm and (9.6 ± 0.8) × 10-18 cm2 molecule-1 at 352 nm. The peak UV cross section is estimated to be (1.75 ± 0.14) × 10-17 cm2 molecule-1 at 330 nm, according to the UV spectrum of (CH3)2COO (Huang et al., 2015) scaled to the absolute cross section at 308 nm.

  2. Absolute absorption cross sections of ozone in the 185- to 350-nm wavelength range

    NASA Technical Reports Server (NTRS)

    Molina, L. T.; Molina, M. J.

    1986-01-01

    The absorption cross sections of ozone have been measured in the wavelength range 185-350 nm and in the temperature range 225-298 K. The absolute ozone concentrations were established by measuring the pressure of pure gaseous samples in the 0.08to 300-torr range, and the UV spectra were recorded under conditions where less than 1 percent of the sample decomposed. The temperature dependence is significant for wavelengths longer than about 280 nm. The absorption cross-section values around 210 nm were found to be about 10 percent larger than the previously accepted values.

  3. Measurements of absolute absorption cross sections of ozone in the 185- to 254-nm wavelength region and the temperature dependence

    NASA Technical Reports Server (NTRS)

    Yoshino, K.; Esmond, J. R.; Freeman, D. E.; Parkinson, W. H.

    1993-01-01

    Laboratory measurements of the relative absorption cross sections of ozone at temperatures 195, 228, and 295 K have been made throughout the 185 to 254 nm wavelength region. The absolute absorption cross sections at the same temperatures have been measured at several discrete wavelengths in the 185 to 250 nm region. The absolute cross sections of ozone have been used to put the relative cross sections on a firm absolute basis throughout the 185 to 255 nm region. These recalibrated cross sections are slightly lower than those of Molina and Molina (1986), but the differences are within a few percent and would not be significant in atmospheric applications.

  4. Systematic determination of absolute absorption cross-section of individual carbon nanotubes

    PubMed Central

    Liu, Kaihui; Hong, Xiaoping; Choi, Sangkook; Jin, Chenhao; Capaz, Rodrigo B.; Kim, Jihoon; Wang, Wenlong; Bai, Xuedong; Louie, Steven G.; Wang, Enge; Wang, Feng

    2014-01-01

    Optical absorption is the most fundamental optical property characterizing light–matter interactions in materials and can be most readily compared with theoretical predictions. However, determination of optical absorption cross-section of individual nanostructures is experimentally challenging due to the small extinction signal using conventional transmission measurements. Recently, dramatic increase of optical contrast from individual carbon nanotubes has been successfully achieved with a polarization-based homodyne microscope, where the scattered light wave from the nanostructure interferes with the optimized reference signal (the reflected/transmitted light). Here we demonstrate high-sensitivity absorption spectroscopy for individual single-walled carbon nanotubes by combining the polarization-based homodyne technique with broadband supercontinuum excitation in transmission configuration. To our knowledge, this is the first time that high-throughput and quantitative determination of nanotube absorption cross-section over broad spectral range at the single-tube level was performed for more than 50 individual chirality-defined single-walled nanotubes. Our data reveal chirality-dependent behaviors of exciton resonances in carbon nanotubes, where the exciton oscillator strength exhibits a universal scaling law with the nanotube diameter and the transition order. The exciton linewidth (characterizing the exciton lifetime) varies strongly in different nanotubes, and on average it increases linearly with the transition energy. In addition, we establish an empirical formula by extrapolating our data to predict the absorption cross-section spectrum for any given nanotube. The quantitative information of absorption cross-section in a broad spectral range and all nanotube species not only provides new insight into the unique photophysics in one-dimensional carbon nanotubes, but also enables absolute determination of optical quantum efficiencies in important

  5. Systematic determination of absolute absorption cross-section of individual carbon nanotubes.

    PubMed

    Liu, Kaihui; Hong, Xiaoping; Choi, Sangkook; Jin, Chenhao; Capaz, Rodrigo B; Kim, Jihoon; Wang, Wenlong; Bai, Xuedong; Louie, Steven G; Wang, Enge; Wang, Feng

    2014-05-27

    Optical absorption is the most fundamental optical property characterizing light-matter interactions in materials and can be most readily compared with theoretical predictions. However, determination of optical absorption cross-section of individual nanostructures is experimentally challenging due to the small extinction signal using conventional transmission measurements. Recently, dramatic increase of optical contrast from individual carbon nanotubes has been successfully achieved with a polarization-based homodyne microscope, where the scattered light wave from the nanostructure interferes with the optimized reference signal (the reflected/transmitted light). Here we demonstrate high-sensitivity absorption spectroscopy for individual single-walled carbon nanotubes by combining the polarization-based homodyne technique with broadband supercontinuum excitation in transmission configuration. To our knowledge, this is the first time that high-throughput and quantitative determination of nanotube absorption cross-section over broad spectral range at the single-tube level was performed for more than 50 individual chirality-defined single-walled nanotubes. Our data reveal chirality-dependent behaviors of exciton resonances in carbon nanotubes, where the exciton oscillator strength exhibits a universal scaling law with the nanotube diameter and the transition order. The exciton linewidth (characterizing the exciton lifetime) varies strongly in different nanotubes, and on average it increases linearly with the transition energy. In addition, we establish an empirical formula by extrapolating our data to predict the absorption cross-section spectrum for any given nanotube. The quantitative information of absorption cross-section in a broad spectral range and all nanotube species not only provides new insight into the unique photophysics in one-dimensional carbon nanotubes, but also enables absolute determination of optical quantum efficiencies in important

  6. Absolute absorption cross-section measurements of ozone in the wavelength region 238-335 nm and the temperature dependence

    NASA Technical Reports Server (NTRS)

    Yoshino, K.; Freeman, D. E.; Esmond, J. R.; Parkinson, W. H.

    1988-01-01

    The absolute absorption cross-section of ozone has been experimentally determined at the temperatures 195, 228, and 295 K at several discrete wavelengths in the 238-335-nm region. The present results for ozone at 295 K are found to be in agreement with those of Hearn (1961). Absolute cross-section measurements of ozone at 195 K have confirmed previous (Freeman et al., 1984) relative cross-section measurements throughout the 240-335-nm region.

  7. Absolute absorption cross sections of ozone at 300 K, 228 K and 195 K in the wavelength region 185-240 nm

    NASA Technical Reports Server (NTRS)

    Yoshino, K.; Parkinson, W. H.; Freeman, D. E.

    1992-01-01

    An account is given of progress of work on absorption cross section measurements of ozone at 300 K, 228 K and 195 K in the wavelength region 185-240 nm. In this wavelength region, the penetration of solar radiation into the Earth's atmosphere is controlled by O2 and O3. The transmitted radiation is available to dissociate trace species such as halocarbons and nitrous oxide. We have recently measured absolute absorption cross sections of O3 in the wavelength region 240-350 nm (Freeman et al., 1985; Yoshino et al., 1988). We apply these proven techniques to the determination of the absorption cross section of O3 at 300 K, 228 K and 195 K throughout the wavelength region 185-240 nm. A paper titled 'Absolute Absorption Cross Section Measurements of Ozone in the Wavelength Region 185-254 nm and the Temperature Dependence' has been submitted for publication in the Journal of Geophysical Research.

  8. Absorption and scattering of light by Pt, Pd, Ag, and Au nanodisks: absolute cross sections and branching ratios.

    PubMed

    Langhammer, Christoph; Kasemo, Bengt; Zorić, Igor

    2007-05-21

    Localized surface plasmons (LSPs) of metallic nanoparticles decay either radiatively or via an electron-hole pair cascade. In this work, the authors have experimentally and theoretically explored the branching ratio of the radiative and nonradiative LSP decay channels for nanodisks of Ag, Au, Pt, and Pd, with diameters D ranging from 38 to 530 nm and height h=20 nm, supported on a fused silica substrate. The branching ratio for the two plasmon decay channels was obtained by measuring the absorption and scattering cross sections as a function of photon energy. The former was obtained from measured extinction and scattering coefficients, using an integrating sphere detector combined with particle density measurements obtained from scanning electron microscopy images of the nanoparticles. Partly angle-resolved measurements of the scattered light allowed the authors to clearly identify contributions from dipolar and higher plasmonic modes to the extinction, scattering, and absorption cross sections. Based on these experiments they find that absorption dominates the total scattering cross section in all the examined cases for small metallic nanodisks (D<100 nm). For D>100 nm absorption still dominates for Pt and Pd nanodisks, while scattering dominates for Au and Ag. A theoretical approach, where the metal disks are approximated as oblate spheroids, is used to account for the trends in the measured cross sections. The field problem is solved in the electrostatic limit. The spheroid is treated as an induced dipole for which the dipolar polarizability is calculated based on spheroid geometry and the (bulk) dielectric response function of the metal the spheroid consists of and the dielectric medium surrounding it. One might expect this model to be inappropriate for disks with D>100 nm since effects due to the retardation of the incoming field across the metallic nanodisk and contributions from higher plasmonic modes are neglected. However, this model describes quite well

  9. Absolute partial photoionization cross sections of ozone.

    SciTech Connect

    Berkowitz, J.; Chemistry

    2008-04-01

    Despite the current concerns about ozone, absolute partial photoionization cross sections for this molecule in the vacuum ultraviolet (valence) region have been unavailable. By eclectic re-evaluation of old/new data and plausible assumptions, such cross sections have been assembled to fill this void.

  10. Absolute photoionization cross sections of atomic oxygen

    NASA Technical Reports Server (NTRS)

    Samson, J. A. R.; Pareek, P. N.

    1985-01-01

    The absolute values of photoionization cross sections of atomic oxygen were measured from the ionization threshold to 120 A. An auto-ionizing resonance belonging to the 2S2P4(4P)3P(3Do, 3So) transition was observed at 479.43 A and another line at 389.97 A. The experimental data is in excellent agreement with rigorous close-coupling calculations that include electron correlations in both the initial and final states.

  11. Absolute photoionization cross sections of atomic oxygen

    NASA Technical Reports Server (NTRS)

    Samson, J. A. R.; Pareek, P. N.

    1982-01-01

    The absolute values of photoionization cross sections of atomic oxygen were measured from the ionization threshold to 120 A. An auto-ionizing resonance belonging to the 2S2P4(4P)3P(3Do, 3So) transition was observed at 479.43 A and another line at 389.97 A. The experimental data is in excellent agreement with rigorous close-coupling calculations that include electron correlations in both the initial and final states.

  12. High resolution absolute absorption cross sections of the B ̃(1)A'-X ̃(1)A' transition of the CH2OO biradical.

    PubMed

    Foreman, Elizabeth S; Kapnas, Kara M; Jou, YiTien; Kalinowski, Jarosław; Feng, David; Gerber, R Benny; Murray, Craig

    2015-12-28

    Carbonyl oxides, or Criegee intermediates, are formed from the gas phase ozonolysis of alkenes and play a pivotal role in night-time and urban area atmospheric chemistry. Significant discrepancies exist among measurements of the strong B ̃(1)A'-X ̃(1)A' electronic transition of the simplest Criegee intermediate, CH2OO in the visible/near-UV. We report room temperature spectra of the B ̃(1)A'-X ̃(1)A' electronic absorption band of CH2OO acquired at higher resolution using both single-pass broadband absorption and cavity ring-down spectroscopy. The new absorption spectra confirm the vibrational structure on the red edge of the band that is absent from ionization depletion measurements. The absolute absorption cross sections over the 362-470 nm range are in good agreement with those reported by Ting et al. Broadband absorption spectra recorded over the temperature range of 276-357 K were identical within their mutual uncertainties, confirming that the vibrational structure is not due to hot bands.

  13. Theoretical antideuteron-nucleus absorptive cross sections

    NASA Technical Reports Server (NTRS)

    Buck, W. W.; Norbury, J. W.; Townsend, L. W.; Wilson, J. W.

    1993-01-01

    Antideuteron-nucleus absorptive cross sections for intermediate to high energies are calculated using an ion-ion optical model. Good agreement with experiment (within 15 percent) is obtained in this same model for (bar p)-nucleus cross sections at laboratory energies up to 15 GeV. We describe a technique for estimating antinucleus-nucleus cross sections from NN data and suggest that further cosmic ray studies to search for antideuterons and other antinuclei be undertaken.

  14. Absorption cross section of canonical acoustic holes

    SciTech Connect

    Crispino, Luis C. B.; Oliveira, Ednilton S.; Matsas, George E. A.

    2007-11-15

    We compute numerically the absorption cross section of a canonical acoustic hole for sound waves with arbitrary frequencies. Our outputs are in full agreement with the expected low- and high-frequency limits.

  15. Ultraviolet absorption cross sections of hydrogen peroxide

    NASA Technical Reports Server (NTRS)

    Lin, C. L.; Rohatgi, N. K.; Demore, W. B.

    1978-01-01

    Absorption cross-sections of hydrogen peroxide vapor and of neutral aqueous solutions of hydrogen peroxide were measured in the wavelength range from 195 to 350 nm at 296 K. The spectrophotometric procedure is described, and the reported cross-sections are compared with values obtained by other researchers. Photodissociation coefficients of atmospheric H2O2 were calculated for direct absorption of unscattered solar radiation, and the vertical distributions of these coefficients are shown for various solar zenith angles.

  16. Temperature-dependent absorption cross sections for hydrogen peroxide vapor

    NASA Technical Reports Server (NTRS)

    Nicovich, J. M.; Wine, P. H.

    1988-01-01

    Relative absorption cross sections for hydrogen peroxide vapor were measured over the temperature ranges 285-381 K for lambda = 230 nm-295 nm and 300-381 K for lambda = 193 nm-350 nm. The well established 298 K cross sections at 202.6 and 228.8 nm were used as an absolute calibration. A significant temperature dependence was observed at the important tropospheric photolysis wavelengths lambda over 300 nm. Measured cross sections were extrapolated to lower temperatures, using a simple model which attributes the observed temperature dependence to enhanced absorption by molecules possessing one quantum of O-O stretch vibrational excitation. Upper tropospheric photodissociation rates calculated using the extrapolated cross sections are about 25 percent lower than those calculated using currently recommended 298 K cross sections.

  17. Absolute photoionization cross sections of the ions Ca+ Ni+

    NASA Astrophysics Data System (ADS)

    Hansen, J. E.; Kjeldsen, H.; Folkmann, F.; Martins, M.; West, J. B.

    2007-01-01

    Absolute measurements of the photoionization cross sections of the singly charged ions in the sequence Ca to Ni are presented, focussing on the 3p → 3d resonance region. Major differences are found in both spectral structure and cross section as the 3d shell is filled progressively. The behaviour of the total oscillator strength is studied as well as its relation to the collapse of the 3d orbital. The 3p53d 1P term is found to have an influence on the spectra even when further 3d electrons are added and this dependence combined with the effect of Hund's rule leads to a considerable simplification in the structure of the absorption spectra before the half-filled 3d shell, while from the half-filled 3d shell Hund's rule is the main simplifying effect.

  18. Absolute photoneutron cross sections of Sm isotopes

    SciTech Connect

    Gheorghe, I.; Glodariu, T.; Utsunomiya, H.; Filipescu, D.; Nyhus, H.-T.; Renstrom, T.; Tesileanu, O.; Shima, T.; Takahisa, K.; Miyamoto, S.

    2015-02-24

    Photoneutron cross sections for seven samarium isotopes, {sup 144}Sm, {sup 147}Sm, {sup 148}Sm, {sup 149}Sm, {sup 150}Sm, {sup 152}Sm and {sup 154}Sm, have been investigated near neutron emission threshold using quasimonochromatic laser-Compton scattering γ-rays produced at the synchrotron radiation facility NewSUBARU. The results are important for nuclear astrophysics calculations and also for probing γ-ray strength functions in the vicinity of neutron threshold. Here we describe the neutron detection system and we discuss the related data analysis and the necessary method improvements for adapting the current experimental method to the working parameters of the future Gamma Beam System of Extreme Light Infrastructure - Nuclear Physics facility.

  19. Infrared absorption cross sections of alternative CFCs

    NASA Technical Reports Server (NTRS)

    Clerbaux, Cathy; Colin, Reginald; Simon, Paul C.

    1994-01-01

    Absorption cross sections have obtained in the infrared atmospheric window, between 600 and 1500 cm(exp -1), for 10 alternative hydrohalocarbons: HCFC-22, HCFC-123, HCFC-124, HCFC-141b, HCFC-142b, HCFC-225ca, HCFC-225cb, HFC-125, HFC-134a, and HFC-152a. The measurements were made at three temperatures (287K, 270K and 253K) with a Fourier transform spectrometer operating at 0.03 cm(exp -1) apodized resolution. Integrated cross sections are also derived for use in radiative models to calculate the global warming potentials.

  20. Rotational averaging of multiphoton absorption cross sections

    SciTech Connect

    Friese, Daniel H. Beerepoot, Maarten T. P.; Ruud, Kenneth

    2014-11-28

    Rotational averaging of tensors is a crucial step in the calculation of molecular properties in isotropic media. We present a scheme for the rotational averaging of multiphoton absorption cross sections. We extend existing literature on rotational averaging to even-rank tensors of arbitrary order and derive equations that require only the number of photons as input. In particular, we derive the first explicit expressions for the rotational average of five-, six-, and seven-photon absorption cross sections. This work is one of the required steps in making the calculation of these higher-order absorption properties possible. The results can be applied to any even-rank tensor provided linearly polarized light is used.

  1. Infrared absorption cross sections for trifluoromethane

    NASA Astrophysics Data System (ADS)

    Harrison, Jeremy J.

    2013-11-01

    High-resolution infrared absorption cross sections for trifluoromethane have been determined over the range 950-1500 cm-1 from spectra recorded using a high-resolution FTIR spectrometer (Bruker IFS 125HR) and a 26-cm-pathlength cell. Spectra of trifluoromethane/dry synthetic air mixtures were recorded at 0.015 cm-1 resolution (calculated as 0.9/MOPD) at a number of temperatures and pressures (23-762 Torr and 188-294 K) appropriate for atmospheric conditions. Intensities were calibrated using composite trifluoromethane spectra taken from the Pacific Northwest National Laboratory (PNNL) IR database.

  2. Absolute photoionization cross-section of the propargyl radical

    SciTech Connect

    Savee, John D.; Welz, Oliver; Taatjes, Craig A.; Osborn, David L.; Soorkia, Satchin; Selby, Talitha M.

    2012-04-07

    Using synchrotron-generated vacuum-ultraviolet radiation and multiplexed time-resolved photoionization mass spectrometry we have measured the absolute photoionization cross-section for the propargyl (C{sub 3}H{sub 3}) radical, {sigma}{sub propargyl}{sup ion}(E), relative to the known absolute cross-section of the methyl (CH{sub 3}) radical. We generated a stoichiometric 1:1 ratio of C{sub 3}H{sub 3} : CH{sub 3} from 193 nm photolysis of two different C{sub 4}H{sub 6} isomers (1-butyne and 1,3-butadiene). Photolysis of 1-butyne yielded values of {sigma}{sub propargyl}{sup ion}(10.213 eV)=(26.1{+-}4.2) Mb and {sigma}{sub propargyl}{sup ion}(10.413 eV)=(23.4{+-}3.2) Mb, whereas photolysis of 1,3-butadiene yielded values of {sigma}{sub propargyl}{sup ion}(10.213 eV)=(23.6{+-}3.6) Mb and {sigma}{sub propargyl}{sup ion}(10.413 eV)=(25.1{+-}3.5) Mb. These measurements place our relative photoionization cross-section spectrum for propargyl on an absolute scale between 8.6 and 10.5 eV. The cross-section derived from our results is approximately a factor of three larger than previous determinations.

  3. Absolute photoionization cross-section of the methyl radical.

    SciTech Connect

    Taatjes, C. A.; Osborn, D. L.; Selby, T.; Meloni, G.; Fan, H.; Pratt, S. T.; Chemical Sciences and Engineering Division; SNL

    2008-01-01

    The absolute photoionization cross-section of the methyl radical has been measured using two completely independent methods. The CH{sub 3} photoionization cross-section was determined relative to that of acetone and methyl vinyl ketone at photon energies of 10.2 and 11.0 eV by using a pulsed laser-photolysis/time-resolved synchrotron photoionization mass spectrometry method. The time-resolved depletion of the acetone or methyl vinyl ketone precursor and the production of methyl radicals following 193 nm photolysis are monitored simultaneously by using time-resolved synchrotron photoionization mass spectrometry. Comparison of the initial methyl signal with the decrease in precursor signal, in combination with previously measured absolute photoionization cross-sections of the precursors, yields the absolute photoionization cross-section of the methyl radical; {sigma}{sub CH}(10.2 eV) = (5.7 {+-} 0.9) x 10{sup -18} cm{sup 2} and {sigma}{sub CH{sub 3}}(11.0 eV) = (6.0 {+-} 2.0) x 10{sup -18} cm{sup 2}. The photoionization cross-section for vinyl radical determined by photolysis of methyl vinyl ketone is in good agreement with previous measurements. The methyl radical photoionization cross-section was also independently measured relative to that of the iodine atom by comparison of ionization signals from CH{sub 3} and I fragments following 266 nm photolysis of methyl iodide in a molecular-beam ion-imaging apparatus. These measurements gave a cross-section of (5.4 {+-} 2.0) x 10{sup -18} cm{sup 2} at 10.460 eV, (5.5 {+-} 2.0) x 10{sup -18} cm{sup 2} at 10.466 eV, and (4.9 {+-} 2.0) x 10{sup -18} cm{sup 2} at 10.471 eV. The measurements allow relative photoionization efficiency spectra of methyl radical to be placed on an absolute scale and will facilitate quantitative measurements of methyl concentrations by photoionization mass spectrometry.

  4. Absolute doubly differential bremsstrahlung cross sections from rare gas atoms

    NASA Astrophysics Data System (ADS)

    Portillo, Salvador

    The absolute doubly differential bremsstrahlung cross section has been measured for 28 and 50 keV electrons incident on the rare gases Xe, Kr, Ar and Ne. The cross sections are differential with respect to energy and photon emission. A SiLi solid state detector measured data at 90° with respect to the beam line. A thorough analysis of the experimental systematic error yielded a high degree of confidence in the experimental data. The absolute bremsstrahlung doubly differential cross sections provided for a rigorous test of the normal bremsstrahlung theory, tabulated by Kissel, Quarles and Pratt1 (KQP) and of the SA theory2 that includes the contribution from polarization bremsstrahlung. To test the theories a comparison of the overall magnitude of the cross section as well as comparison of the photon energy dependence was carried out. The KQP theoretical values underestimated the magnitude of the cross section for all targets and for both energies. The SA values were in excellent agreement with the 28 keV data. For the 50keV data the fit was also very good. However, there were energy regions where there was a small discrepancy between the theory and the data. This suggests that the Polarization Bremsstrahlung (PB) mechanism does contribute to the overall spectrum and is detectable in this parameter space. 1Kissel, L., Quarles, C. A., Pratt, R. H., Atom. Data Nucl. Data Tables 28, 381 (1983). 2Avdonina N. B., Pratt, R. H., J. Phys. B: At. Mol. Opt. Phys. 32 4261 (1999).

  5. Chirality Dependence of the Absorption Cross Section of Carbon Nanotubes

    NASA Astrophysics Data System (ADS)

    Vialla, Fabien; Roquelet, Cyrielle; Langlois, Benjamin; Delport, Géraud; Santos, Silvia Morim; Deleporte, Emmanuelle; Roussignol, Philippe; Delalande, Claude; Voisin, Christophe; Lauret, Jean-Sébastien

    2013-09-01

    The variation of the optical absorption of carbon nanotubes with their geometry has been a long-standing question at the heart of both metrological and applicative issues, in particular because optical spectroscopy is one of the primary tools for the assessment of the chiral species abundance of samples. Here, we tackle the chirality dependence of the optical absorption with an original method involving ultraefficient energy transfer in porphyrin-nanotube compounds that allows uniform photoexcitation of all chiral species. We measure the absolute absorption cross section of a wide range of semiconducting nanotubes at their S22 transition and show that it varies by up to a factor of 2.2 with the chiral angle, with type I nanotubes showing a larger absorption. In contrast, the luminescence quantum yield remains almost constant.

  6. Absolute np and pp Cross Section Determinations Aimed At Improving The Standard For Cross Section Measurements

    SciTech Connect

    Laptev, A. B.; Haight, R. C.; Tovesson, F.; Arndt, R. A.; Briscoe, W. J.; Paris, M. W.; Strakovsky, I. I.; Workman, R. L.

    2011-06-01

    Purpose of present research is a keeping improvement of the standard for cross section measurements of neutron-induced reactions. The cross sections for np and pp scattering below 1 GeV are determined based on partial-wave analyses (PWAs) of nucleon-nucleon scattering data. These cross sections are compared with the most recent ENDF/B-VII.0 and JENDL-4.0 data files, and the Nijmegen PWA. Also a comparison of evaluated data with recent experimental data was made to check a quality of evaluation. Excellent agreement was found between the new experimental data and our PWA predictions.

  7. Absolute np and pp cross section determinations aimed at improving the standard for cross section measurements

    SciTech Connect

    Laptev, Alexander B; Haight, Robert C; Tovesson, Fredrik; Arndt, Richard A; Briscoe, William J; Paris, Mark W; Strakovsky, Igor I; Workman, Ron L

    2010-01-01

    Purpose of present research is a keeping improvement of the standard for cross section measurements of neutron-induced reactions. The cross sections for np and pp scattering below 1000 MeV are determined based on partial-wave analyses (PW As) of nucleon-nucleon scattering data. These cross sections are compared with the most recent ENDF/B-V11.0 and JENDL-4.0 data files, and the Nijmegen PWA. Also a comparison of evaluated data with recent experimental data was made to check a quality of evaluation. Excellent agreement was found between the new experimental data and our PWA predictions.

  8. Temperature-dependent high resolution absorption cross sections of propane

    NASA Astrophysics Data System (ADS)

    Beale, Christopher A.; Hargreaves, Robert J.; Bernath, Peter F.

    2016-10-01

    High resolution (0.005 cm-1) absorption cross sections have been measured for pure propane (C3H8). These cross sections cover the 2550-3500 cm-1 region at five temperatures (from 296 to 700 K) and were measured using a Fourier transform spectrometer and a quartz cell heated by a tube furnace. Calibrations were made by comparison to the integrated cross sections of propane from the Pacific Northwest National Laboratory. These are the first high resolution absorption cross sections of propane for the 3 μm region at elevated temperatures. The cross sections provided may be used to monitor propane in combustion environments and in astronomical sources such as the auroral regions of Jupiter, brown dwarfs and exoplanets.

  9. Saturation Dynamics Measures Absolute Cross Section and Generates Contrast within a Neuron.

    PubMed

    Kumar, Suraj; Singh, Aditya; Singh, Vijay R; George, Jude B; Balaji, J

    2016-09-20

    The intensity required to optically saturate a chromophore is a molecular property that is determined by its absorption cross section (σ) and the excited state lifetime. We present an analytical description of such a system and show that fluorescence around the onset of saturation is characterized by product of absorption cross section and lifetime. Using this approach we formulate a generalized method for measuring the multiphoton cross section of fluorophores and use it to obtain the absolute three-photon cross-section spectra of tryptophan. We find that the tryptophan three-photon cross section ranges from 0.28 S.I. units (m(6)s(2)photon(-2)) at 870 nm to 20 S.I. units at 740 nm. Further, we show that the product of molecular rate of excitation and de-excitation, denoted as β, serves as a vital contrasting agent for imaging local environment. Our contrast parameter, β, is related to fraction of the population present in the excited state and is independent of the fluorophore concentration. We show that β-imaging can be carried out in a regular two-photon microscope setup through a series of intensity scans. Using enhanced green fluorescent protein (EGFP) fluorescence from the brain slices of Thy-1 EGFP transgenic mice, we show that there is an inherent, concentration independent, variation in contrast across the soma and the dendrite.

  10. Saturation Dynamics Measures Absolute Cross Section and Generates Contrast within a Neuron.

    PubMed

    Kumar, Suraj; Singh, Aditya; Singh, Vijay R; George, Jude B; Balaji, J

    2016-09-20

    The intensity required to optically saturate a chromophore is a molecular property that is determined by its absorption cross section (σ) and the excited state lifetime. We present an analytical description of such a system and show that fluorescence around the onset of saturation is characterized by product of absorption cross section and lifetime. Using this approach we formulate a generalized method for measuring the multiphoton cross section of fluorophores and use it to obtain the absolute three-photon cross-section spectra of tryptophan. We find that the tryptophan three-photon cross section ranges from 0.28 S.I. units (m(6)s(2)photon(-2)) at 870 nm to 20 S.I. units at 740 nm. Further, we show that the product of molecular rate of excitation and de-excitation, denoted as β, serves as a vital contrasting agent for imaging local environment. Our contrast parameter, β, is related to fraction of the population present in the excited state and is independent of the fluorophore concentration. We show that β-imaging can be carried out in a regular two-photon microscope setup through a series of intensity scans. Using enhanced green fluorescent protein (EGFP) fluorescence from the brain slices of Thy-1 EGFP transgenic mice, we show that there is an inherent, concentration independent, variation in contrast across the soma and the dendrite. PMID:27653491

  11. Nonadiabatic calculations of ultraviolet absorption cross section of sulfur monoxide: Isotopic effects on the photodissociation reaction

    SciTech Connect

    Danielache, Sebastian O.; Tomoya, Suzuki; Nanbu, Shinkoh; Kondorsky, Alexey; Tokue, Ikuo

    2014-01-28

    Ultraviolet absorption cross sections of the main and substituted sulfur monoxide (SO) isotopologues were calculated using R-Matrix expansion technique. Energies, transition dipole moments, and nonadiabatic coupling matrix elements were calculated at MRCI/AV6Z level. The calculated absorption cross section of {sup 32}S{sup 16}O was compared with experimental spectrum; the spectral feature and the absolute value of photoabsorption cross sections are in good agreement. Our calculation predicts a long lived photoexcited SO* species which causes large non-mass dependent isotopic effects depending on the excitation energy in the ultraviolet region.

  12. Absorption cross sections of the ClO dimer

    NASA Technical Reports Server (NTRS)

    Huder, K. J.; DeMore, W. B.

    1995-01-01

    The absorption cross sections of the ClO dimer, ClOOCl, are important to the photochemistry of ozone depletion in the Antarctic. In this work, new measurements were made of the dimer cross sections at 195 K. the results yield somewhat lower values in the long wavelength region, compared to those currently recommended in the NASA data evaluation (JPL 94-26). The corresponding solar photodissociation rates in the Antarctic are reduced by about 40%.

  13. Updated ozone absorption cross section will reduce air quality compliance

    NASA Astrophysics Data System (ADS)

    Sofen, E. D.; Evans, M. J.; Lewis, A. C.

    2015-12-01

    Photometric ozone measurements rely upon an accurate value of the ozone absorption cross section at 253.65 nm. This has recently been re-evaluated by Viallon et al. (2015) as 1.8 % smaller than the accepted value (Hearn, 1961) used for the preceding 50 years. Thus, ozone measurements that applied the older cross section systematically underestimate the amount of ozone in air. We correct the reported historical surface data from North America and Europe and find that this modest change in cross section has a significant impact on the number of locations that are out of compliance with air quality regulations if the air quality standards remain the same. We find 18, 23, and 20 % increases in the number of sites that are out of compliance with current US, Canadian, and European ozone air quality health standards for the year 2012. Should the new cross-section value be applied, it would impact attainment of air quality standards and compliance with relevant clean air acts, unless the air quality target values themselves were also changed proportionately. We draw attention to how a small change in gas metrology has a global impact on attainment and compliance with legal air quality standards. We suggest that further laboratory work to evaluate the new cross section is needed and suggest three possible technical and policy responses should the new cross section be adopted.

  14. Updated ozone absorption cross section will reduce air quality compliance

    NASA Astrophysics Data System (ADS)

    Sofen, E. D.; Evans, M. J.; Lewis, A. C.

    2015-07-01

    Photometric ozone measurements rely upon an accurate value of the ozone absorption cross section at 253.65 nm. This has recently been reevaluated by Viallon et al. (2015) as 1.8 % smaller than the accepted value (Hearn, 1961) used for the preceding fifty years. Thus, ozone measurements that applied the older cross section systematically underestimate the amount of ozone in air. We correct the reported historical surface data from North America and Europe and find that this modest change in cross section has a significant impact on the number of locations that are out of compliance with air quality regulations if the air quality standards remain the same. We find 18, 23, and 20 % increases in the number of sites that are out of compliance with current US, Canadian, and European ozone air quality health standards for the year 2012. Should the new cross section value be applied, it would impact attainment of air quality standards and compliance with relevant clean air acts, unless the air quality target values themselves were also changed proportionately. We draw attention to how a small change in gas metrology has a global impact on attainment and compliance with legal air quality standards. We suggest that further laboratory work to evaluate the new cross section is needed and suggest three possible technical and policy responses should the new cross section be adopted.

  15. Hadronic absorption cross sections of B{sub c}

    SciTech Connect

    Lodhi, M. A. K.; Akram, Faisal; Irfan, Shaheen

    2011-09-15

    The cross sections of B{sub c} absorption by {pi} mesons are calculated using a hadronic Lagrangian based on the SU(5) flavor symmetry. Calculated cross sections are found to be in the ranges 2-7 mb and 0.2-2 mb for the processes B{sub c}{sup +}{pi}{yields}DB and B{sub c}{sup +}{pi}{yields}D*B*, respectively, when the monopole form factor is included. These results could be useful in calculating the production rate of B{sub c} mesons in relativistic heavy ion collisions.

  16. Absolute vacuum ultraviolet photoabsorption cross section studies of atomic and molecular species: Techniques and observational data

    NASA Technical Reports Server (NTRS)

    Judge, D. L.; Wu, C. Y. R.

    1990-01-01

    Absorption of a high energy photon (greater than 6 eV) by an isolated molecule results in the formation of highly excited quasi-discrete or continuum states which evolve through a wide range of direct and indirect photochemical processes. These are: photoionization and autoionization, photodissociation and predissociation, and fluorescence. The ultimate goal is to understand the dynamics of the excitation and decay processes and to quantitatively measure the absolute partial cross sections for all processes which occur in photoabsorption. Typical experimental techniques and the status of observational results of particular interest to solar system observations are presented.

  17. Absolute electron-impact total ionization cross sections of chlorofluoromethanes

    NASA Astrophysics Data System (ADS)

    Martínez, Roberto; Sierra, Borja; Redondo, Carolina; Rayo, María N. Sánchez; Castaño, Fernando

    2004-12-01

    An experimental study is reported on the electron-impact total ionization cross sections (TICSs) of CCl4, CCl3F, CCl2F2, and CClF3 molecules. The kinetic energy of the colliding electrons was in the 10-85 eV range. TICSs were obtained as the sum of the partial ionization cross sections of all fragment ions, measured and identified in a linear double focusing time-of-flight mass spectrometer. The resulting TICS profiles—as a function of the electron-impact energy—have been compared both with those computed by ab initio and (semi)empirical methods and with the available experimental data. The computational methods used include the binary-encounter-Bethe (BEB) modified to include atoms with principal quantum numbers n⩾3, the Deutsch and Märk (DM) formalism, and the modified additivity rule (MAR). It is concluded that both modified BEB and DM methods fit the experimental TICS for (CF4), CClF3, CCl2F2, CCl3F, and CCl4 to a high accuracy, in contrast with the poor accord of the MAR method. A discussion on the factors influencing the discrepancies of the fittings is presented.

  18. Principles and procedures for determining absolute differential electron-molecule (atom) scattering cross sections

    NASA Technical Reports Server (NTRS)

    Nickel, J. C.; Zetner, P. W.; Shen, G.; Trajmar, S.

    1989-01-01

    Procedures and calibration techniques for measuring the absolute elastic and inelastic differential cross sections (DCS) for electron impact on molecular (atomic) species are described and illustrated by examples. The elastic DCS for the molecule under study is first determined by calibration against helium using the relative flow technique. The second step involves the production of energy-loss spectra for the instrument response function, the unfolding of overlapping inelastic structures and the normalization of inelastic intensities to the elastic cross sections. It is concluded that this method of determining absolute differential electron-molecule (atom) scattering cross sections is generally applicable and provides reliable results.

  19. Beam Elements with Trapezoidal Cross Section Deformation Modes Based on the Absolute Nodal Coordinate Formulation

    NASA Astrophysics Data System (ADS)

    Matikainen, Marko K.; Dmitrochenko, Oleg; Mikkola, Aki

    2010-09-01

    In this study, higher order beam elements are developed based on the absolute nodal coordinate formulation. The absolute nodal coordinate formulation is a finite element procedure that was recently proposed for flexible multibody applications. Many different elements based on the absolute nodal coordinate formulation are introduced, but still the beam elements are not able to describe the trapezoidal cross section mode. This leads to the locking phenomena, and therefore, the beam elements based on the absolute nodal coordinate formulation with three dimensional elasticity converge to an inexact solution. In order to avoid the locking phenomena, the trapezoidal cross section deformation mode is included in the beam elements based on the absolute nodal coordinate with additional degrees of freedom. The proper description for the trapezoidal cross section deformation is important for the continuum beam elements based on three-dimensional elasticity where the material model is often based on general continuum mechanics.

  20. Cross section for absorption of partly shielded dielectric sphere

    NASA Astrophysics Data System (ADS)

    Vinogradov, S. S.; Sulima, A. V.

    1984-05-01

    The effect of an ideally conducting spherical metal cup, as a shield, on the microwave absorption characteristics of a dielectric sphere is evaluated on the basis of the known solution to the diffraction problem for a plane electromagnetic wave propagating along the axis of cup and sphere. The Debye electric and magnetic potentials are calculated for the shielded segment of the sphere and for the unshielded remainder of the dielectric sphere, the cup lying either on the front surface or the back surface of the sphere. The problem reduces to two coupled systems of linear algebraic equations of the second kind. The cross section for absorption, equal to the difference between total incident energy flux and scattered energy flux in accordance with power balance or conservation of diffraction energy, has been calculated as a function of kb (k- wave number in free space, b- radius of cup base circle). Numerical results indicate that within the resonance range (b- wavelength of incident radiation) correction must be made to include quasi-natural modes of the shield. A narrow shield behind the sphere increases the overall absorption level in the latter, while a narrow shield before the sphere has almost no effect on the absorption.

  1. Absolute differential cross sections for electron capture and loss by kilo-electron-volt hydrogen atoms

    NASA Technical Reports Server (NTRS)

    Smith, G. J.; Johnson, L. K.; Gao, R. S.; Smith, K. A.; Stebbings, R. F.

    1991-01-01

    This paper reports measurements of absolute differential cross sections for electron capture and loss for fast hydrogen atoms incident on H2, N2, O2, Ar, and He. Cross sections have been determined in the 2.0- to 5.0-keV energy range over the laboratory angular range 0.02-2 deg, with an angular, resolution of 0.02 deg. The high angular resolution allows observation of the structure at small angles in some of the cross sections. Comparison of the present results with those of other authors generally shows very good agreement.

  2. Near-UV absorption cross sections and trans/cis equilibrium of nitrous acid

    SciTech Connect

    Bongartz, A.; Kames, J.; Welter, F.; Schurath, U. )

    1991-02-07

    The A {sup 1}A{double prime} {l arrow} X {sup 1}A{prime} absorption spectrum of gaseous nitrous acid has been measured in the 300-400-nm range. Absolute cross sections were determined by a combination of gas-phase and wet chemical analysis. The cross sections of prominent bands are 25% larger than the recommended values of Stockwell and Calvert. The influence of spectral resolution on absolute and differential absorption cross sections was also investigated. The integrated band area of the n{pi}* transition yields an oscillator strength f = (8.90 {plus minus} 0.36) {times} 10{sup {minus}4}, less than the reported liquid phase value of 2 {times} 10{sup {minus}3}. The equilibrium constant K = p{sub trans}/p{sub cis}, based on the assumption that the oscillator strength of the n{pi}* transition is the same for both rotamers, was found to be 3.25 {plus minus} 0.30 at 277 K. This yields an energy difference {Delta}E between trans- and cis-HONO of -2,700 J mol{sup {minus}1} in the electronic ground state, and -6,000 J mol{sup {minus}1} in the excited state.

  3. Absolute cross section for photoionization of Mn+ in the 3p region

    NASA Astrophysics Data System (ADS)

    Kjeldsen, H.; Folkmann, F.; Kristensen, B.; West, J. B.; Hansen, J. E.

    2004-03-01

    The absolute cross section for photoionization of Mn+ has been measured using the merged-beam technique, focusing on the region of the 'giant' 3p rarr 3d resonance. The main discrepancy between theory and earlier experiments has been removed. However, more extensive relativistic calculations are required for a rigorous comparison with theory.

  4. Quantitative infrared absorption cross sections of isoprene for atmospheric measurements

    DOE PAGES

    Brauer, C. S.; Blake, T. A.; Guenther, A. B.; Sharpe, S. W.; Sams, R. L.; Johnson, T. J.

    2014-11-19

    Isoprene (C5H8, 2-methyl-1,3-butadiene) is a volatile organic compound (VOC) and is one of the primary contributors to annual global VOC emissions. Isoprene is produced primarily by vegetation as well as anthropogenic sources, and its OH- and O3-initiated oxidations are a major source of atmospheric oxygenated organics. Few quantitative infrared studies have been reported for isoprene, limiting the ability to quantify isoprene emissions via remote or in situ infrared detection. We thus report absorption cross sections and integrated band intensities for isoprene in the 600–6500 cm-1 region. The pressure-broadened (1 atmosphere N2) spectra were recorded at 278, 298, and 323 Kmore » in a 19.94 cm path-length cell at 0.112 cm-1 resolution, using a Bruker IFS 66v/S Fourier transform infrared (FTIR) spectrometer. Composite spectra are derived from a minimum of seven isoprene sample pressures, each at one of three temperatures, and the number densities are normalized to 296 K and 1 atm.« less

  5. Absolute measurement of the 242Pu neutron-capture cross section

    NASA Astrophysics Data System (ADS)

    Buckner, M. Q.; Wu, C. Y.; Henderson, R. A.; Bucher, B.; Chyzh, A.; Bredeweg, T. A.; Baramsai, B.; Couture, A.; Jandel, M.; Mosby, S.; O'Donnell, J. M.; Ullmann, J. L.; Dance Collaboration

    2016-04-01

    The absolute neutron-capture cross section of 242Pu was measured at the Los Alamos Neutron Science Center using the Detector for Advanced Neutron-Capture Experiments array along with a compact parallel-plate avalanche counter for fission-fragment detection. The first direct measurement of the 242Pu(n ,γ ) cross section was made over the incident neutron energy range from thermal to ≈6 keV, and the absolute scale of the (n ,γ ) cross section was set according to the known 239Pu(n ,f ) resonance at En ,R=7.83 eV. This was accomplished by adding a small quantity of 239Pu to the 242Pu sample. The relative scale of the cross section, with a range of four orders of magnitude, was determined for incident neutron energies from thermal to ≈40 keV. Our data, in general, are in agreement with previous measurements and those reported in ENDF/B-VII.1; the 242Pu(n ,γ ) cross section at the En ,R=2.68 eV resonance is within 2.4 % of the evaluated value. However, discrepancies exist at higher energies; our data are ≈30 % lower than the evaluated data at En≈1 keV and are approximately 2 σ away from the previous measurement at En≈20 keV.

  6. Absolute cross sections for molecular photoabsorption, partial photoionization, and ionic photofragmentation process

    SciTech Connect

    Gallagher, J.W.; Brion, C.E.; Samson, J.A.R.; Langhoff, P.W.

    1988-01-01

    A compilation is provided of absolute total photoabsorption and partial-channel photoionization cross sections for the valence shells of selected molecules, including diatomics (H2, N2, O2, CO, NO) and triatomics (CO2, N2O), simple hydrides (H2O, NH3, CH4), hydrogen halides (HF, HCl, HBr, HI), sulfur compounds (H2S, CS2, OCS, SO2, SF6),and chlorine compounds (Cl2, CCl4). The partial-channel cross sections presented refer to production of the individual electronic states of molecular ions and also to production of parent and specific fragment ions, as functions of incident photon energy, typically from approximately 20 to 100 eV. Photoelectron anisotropy factors, which together with electronic partial cross sections provide cross sections differential in photon energy and in ejection angle, are also reported. There is generally good agreement between cross sections measured by the physically distinct optical and dipole electron-impact methods. The cross sections and anisotropy factors also compare favorably with selection ab initio and model potential (X-alpha) calculations which provide a basis for interpretation of the measurements.

  7. Absolute X-ray emission cross section measurements of Fe K transitions

    NASA Astrophysics Data System (ADS)

    Hell, Natalie; Brown, Gregory V.; Beiersdorfer, Peter; Boyce, Kevin R.; Grinberg, Victoria; Kelley, Richard L.; Kilbourne, Caroline; Leutenegger, Maurice A.; Porter, Frederick Scott; Wilms, Jörn

    2016-06-01

    We have measured the absolute X-ray emission cross sections of K-shell transitions in highly charged L- and K-shell Fe ions using the LLNL EBIT-I electron beam ion trap and the NASA GSFC EBIT Calorimeter Spectrometer (ECS). The cross sections are determined by using the ECS to simultaneously record the spectrum of the bound-bound K-shell transitions and the emission from radiative recombination from trapped Fe ions. The measured spectrum is then brought to an absolute scale by normalizing the measured flux in the radiative recombination features to their theoretical cross sections, which are well known. Once the spectrum is brought to an absolute scale, the cross sections of the K-shell transitions are determined. These measurements are made possible by the ECS, which consists of a 32 channel array, with 14 channels optimized for detecting high energy photons (hν > 10 keV) and 18 channels optimized for detecting low energy photons (hν < 10 keV). The ECS has a large collection area, relatively high energy resolution, and a large bandpass; all properties necessary for this measurement technique to be successful. These data will be used to benchmark cross sections in the atomic reference data bases underlying the plasma modeling codes used to analyze astrophysical spectra, especially those measured by the Soft X-ray Spectrometer calorimeter instrument recently launched on the Hitomi X-ray Observatory.This work was performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344, and supported by NASA grants to LLNL and NASA/GSFC and by ESA under contract No. 4000114313/15/NL/CB.

  8. Absolute measurement of the 242Pu neutron-capture cross section

    DOE PAGES

    Buckner, M. Q.; Wu, C. Y.; Henderson, R. A.; Bucher, B.; Chyzh, A.; Bredeweg, T. A.; Baramsai, B.; Couture, A.; Jandel, M.; Mosby, S.; et al

    2016-04-21

    Here, the absolute neutron-capture cross section of 242Pu was measured at the Los Alamos Neutron Science Center using the Detector for Advanced Neutron-Capture Experiments array along with a compact parallel-plate avalanche counter for fission-fragment detection. The first direct measurement of the 242Pu(n,γ) cross section was made over the incident neutron energy range from thermal to ≈ 6 keV, and the absolute scale of the (n,γ) cross section was set according to the known 239Pu(n,f) resonance at En,R = 7.83 eV. This was accomplished by adding a small quantity of 239Pu to the 242Pu sample. The relative scale of the crossmore » section, with a range of four orders of magnitude, was determined for incident neutron energies from thermal to ≈ 40 keV. Our data, in general, are in agreement with previous measurements and those reported in ENDF/B-VII.1; the 242Pu(n,γ) cross section at the En,R = 2.68 eV resonance is within 2.4% of the evaluated value. However, discrepancies exist at higher energies; our data are ≈30% lower than the evaluated data at En ≈ 1 keV and are approximately 2σ away from the previous measurement at En ≈ 20 keV.« less

  9. Measurement of the absolute differential cross section for np elastic scattering at 194 MeV

    SciTech Connect

    Sarsour, M.; Peterson, T.; Planinic, M.; Vigdor, S. E.; Allgower, C.; Hossbach, T.; Jacobs, W. W.; Klyachko, A. V.; Rinckel, T.; Stephenson, E. J.; Wissink, S. W.; Zhou, Y.; Bergenwall, B.; Blomgren, J.; Johansson, C.; Klug, J.; Nadel-Turonski, P.; Nilsson, L.; Olsson, N.; Pomp, S.

    2006-10-15

    A tagged medium-energy neutron beam was used in a precise measurement of the absolute differential cross section for np backscattering. The results resolve significant discrepancies within the np database concerning the angular dependence in this regime. The experiment has determined the absolute normalization with {+-}1.5% uncertainty, suitable to verify constraints of supposedly comparable precision that arise from the rest of the database in partial wave analyses. The analysis procedures, especially those associated with the evaluation of systematic errors in the experiment, are described in detail so that systematic uncertainties may be included in a reasonable way in subsequent partial wave analysis fits incorporating the present results.

  10. Microscopic optical model calculations of 4He, 12C-nucleus absorption cross sections

    NASA Technical Reports Server (NTRS)

    Dubey, R. R.; Khandelwal, G. S.; Cucinotta, F. A.; Wilson, J. W.

    1996-01-01

    Calculations of absorption cross sections using a microscopic first-order optical potential for heavy-ion scattering are compared with experiments. In-medium nucleon-nucleon (NN) cross sections were used to calculate the two-body scattering amplitude. A medium-modified first-order optical potential was obtained for heavy-ion scattering using the in-medium two-body scattering amplitude. A partial wave expansion of the Lippmann-Schwinger equation in momentum space was used to calculate the absorption cross sections for various systems. The results are presented for the absorption cross sections for 4He-nucleus and 12C-nucleus scattering systems and are compared with the experimental values in the energy range 18-83A MeV. The use of the in-medium NN cross sections is found to result in significant reduction of the free space absorption cross sections in agreement with experiment.

  11. Scattered light and accuracy of the cross-section measurements of weak absorptions: Gas and liquid phase UV absorption cross sections of CH3CFCl2

    NASA Technical Reports Server (NTRS)

    Fahr, A.; Braun, W.; Kurylo, M. J.

    1993-01-01

    Ultraviolet absorption cross sections of CH3CFCl2(HCFC-141b) were determined in the gas phase (190-260 nm) and liquid phase (230-260 mm) at 298 K. The liquid phase absorption cross sections were then converted into accurate gas phase values using a previously described procedure. It has been demonstrated that scattered light from the shorter-wavelength region (as little as several parts per thousand) can seriously compromise the absorption cross-section measurement, particularly at longer wavelengths where cross sections are low, and can be a source of discrepancies in the cross sections of weakly absorbing halocarbons reported in the literature. A modeling procedure was developed to assess the effect of scattered light on the measured absorption cross section in our experiments, thereby permitting appropriate corrections to be made on the experimental values. Modeled and experimental results were found to be in good agreement. Experimental results from this study were compared with other available determinations and provide accurate input for calculating the atmospheric lifetime of HCFC-141b.

  12. Nucleon-nucleus interaction data base: Total nuclear and absorption cross sections

    NASA Technical Reports Server (NTRS)

    Wilson, J. W.; Townsend, L. W.; Buck, W. W.; Chun, S. Y.; Hong, B. S.; Lamkin, S. L.

    1988-01-01

    Neutron total cross sections are represented for Li to Pu targets at energies above 0.1 MeV and less than 100 MeV using a modified nuclear Ramsauer formalism. The formalism is derived for energies above 100 MeV by fitting theoretical cross sections. Neutron absorption cross sections are represented by analytic expressions of similar form, but shape resonance phenomena of the Ramsauer effect is not present. Elastic differential cross sections are given as a renormalized impulse approximation. These cross section data bases are useful for nucleon transport applications.

  13. Absolute photoionization cross sections of furanic fuels: 2-ethylfuran, 2-acetylfuran and furfural.

    PubMed

    Smith, Audrey R; Meloni, Giovanni

    2015-11-01

    Absolute photoionization cross sections of the molecules 2-ethylfuran, 2-acetylfuran and furfural, including partial ionization cross sections for the dissociative ionized fragments, are measured for the first time. These measurements are important because they allow fuel quantification via photoionization mass spectrometry and the development of quantitative kinetic modeling for the complex combustion of potential fuels. The experiments are carried out using synchrotron photoionization mass spectrometry with an orthogonal time-of-flight spectrometer used for mass analysis at the Advanced Light Source of Lawrence Berkeley National Laboratory. The CBS-QB3 calculations of adiabatic ionization energies and appearance energies agree well with the experimental results. Several bond dissociation energies are also derived and presented.

  14. ^241Am(n,γ) absolute cross sections measured with DANCE

    NASA Astrophysics Data System (ADS)

    Jandel, M.; Bredeweg, T. A.; Fowler, M. M.; Bond, E. M.; Chadwick, M. B.; Clement, R. R.; Couture, A.; O'Donnell, J. M.; Reifarth, R.; Rundberg, R. S.; Ullmann, J. L.; Vieira, D. J.; Wilhelmy, J. B.; Wouters, J. M.; Agvaanluvsan, U.; Macri, R. A.; Sheets, S. A.; Wu, C. Y.; Becker, J. A.

    2007-10-01

    ^241Am is present in plutonium due to the beta decay of ^241Pu (t1/2=14.38 years). As such ^241Am can be used as a detector for nuclear forensics. A precise measurement of ^241Am(n,γ) cross section is thus needed for this application. The measurement is also of interest for advanced reactor design as part of the Global Nuclear Energy Partnership (GNEP). The Detector for Advanced Neutron Capture Experiments (DANCE) at Los Alamos National Laboratory (LANL) was used for neutron capture cross section measurement on ^241Am. The high granularity of DANCE (160 BaF2 detectors in a 4π geometry) enables the efficient detection of prompt gamma-rays following a neutron capture. DANCE is located on the 20.26 m neutron flight path 14(FP14) at the Manuel Lujan Jr. Neutron Scattering Center at the Los Alamos Neutron Science Center (LANSCE). The absolute ^241Am(n,γ) cross sections were obtained in the range of neutron energies from 0.02 eV to 320 keV. The results will be compared to existing evaluations in detail.

  15. Absolute partial and total cross sections for electron-impact ionization of argon from threshold to 1000 eV

    NASA Astrophysics Data System (ADS)

    Straub, H. C.; Renault, P.; Lindsay, B. G.; Smith, K. A.; Stebbings, R. F.

    1995-08-01

    Absolute partial cross sections from threshold to 1000 eV are reported for the production of Arn+ (n=1-4) by electron-impact ionization of argon. The total cross sections, obtained from an appropriately weighted sum of the partial cross sections, are also reported. These results are obtained with an apparatus incorporating a time-of-flight mass spectrometer with position-sensitive detection of the product ions. The simple apparatus design embodies recent developments in pressure measurement and particle detection and is believed to yield more reliable results than those previously reported. For singly charged ions, the overall uncertainty in the absolute cross section values reported here is +/-3.5%. Previous measurements of absolute partial and total cross sections are reviewed and compared with the present results.

  16. Photodissociation of acetaldehyde and the absolute photoionization cross section of HCO.

    SciTech Connect

    Shubert, V. A.; Pratt, S. T.

    2010-01-01

    Photodissociation of acetaldehyde (CH{sub 3}CHO) at 266 nm produced CH{sub 3} and HCO radicals, and single-photon vacuum ultraviolet ionization was used to record velocity map ion images of both CH{sub 3}{sup +} and HCO{sup +}. Comparison of the translational energy distributions from both species indicates that secondary fragmentation of HCO is negligible for 266 nm photodissociation. Thus, the relative photoion signals for CH{sub 3}{sup +} and HCO{sup +} in the mass spectrometer, combined with the recently measured absolute photoionization cross section of CH{sub 3}, allowed the determination of the absolute photoionization cross section of HCO ({sigma}(HCO) = 4.8 {+-} {sub 1.5}{sup 2.0}, 5.9 {+-} {sub 1.6}{sup 2.2}, and 3.7 {+-} {sub 1.2}{sup 1.6} Mb at 10.257, 10.304, and 10.379 eV, respectively). The observed values are quite small but consistent with the similarly small value at threshold for the isoelectronic species NO. This behavior is discussed in terms of the character of the HOMO in both molecules.

  17. Accurate measurements of ozone absorption cross-sections in the Hartley band

    NASA Astrophysics Data System (ADS)

    Viallon, J.; Lee, S.; Moussay, P.; Tworek, K.; Petersen, M.; Wielgosz, R. I.

    2015-03-01

    Ozone plays a crucial role in tropospheric chemistry, is the third largest contributor to greenhouse radiative forcing after carbon dioxide and methane and also a toxic air pollutant affecting human health and agriculture. Long-term measurements of tropospheric ozone have been performed globally for more than 30 years with UV photometers, all relying on the absorption of ozone at the 253.65 nm line of mercury. We have re-determined this cross-section and report a value of 11.27 x 10-18 cm2 molecule-1 with an expanded relative uncertainty of 0.86% (coverage factor k= 2). This is lower than the conventional value currently in use and measured by Hearn (1961) with a relative difference of 1.8%, with the consequence that historically reported ozone concentrations should be increased by 1.8%. In order to perform the new measurements of cross-sections with reduced uncertainties, a system was set up to generate pure ozone in the gas phase together with an optical system based on a UV laser with lines in the Hartley band, including accurate path length measurement of the absorption cell and a careful evaluation of possible impurities in the ozone sample by mass spectrometry and Fourier transform infrared spectroscopy. This resulted in new measurements of absolute values of ozone absorption cross-sections of 9.48 x 10-18, 10.44 x 10-18 and 11.07 x 10-18 cm2 molecule-1, with relative expanded uncertainties better than 0.7%, for the wavelengths (in vacuum) of 244.06, 248.32, and 257.34 nm respectively. The cross-section at the 253.65 nm line of mercury was determined by comparisons using a Standard Reference Photometer equipped with a mercury lamp as the light source. The newly reported value should be used in the future to obtain the most accurate measurements of ozone concentration, which are in closer agreement with non-UV-photometry based methods such as the gas phase titration of ozone with nitrogen monoxide.

  18. Accurate laser measurements of ozone absorption cross-sections in the Hartley band

    NASA Astrophysics Data System (ADS)

    Viallon, J.; Lee, S.; Moussay, P.; Tworek, K.; Petersen, M.; Wielgosz, R. I.

    2014-08-01

    Ozone plays a crucial role in tropospheric chemistry, is the third largest contributor to greenhouse radiative forcing after carbon dioxide and methane and also a toxic air pollutant affecting human health and agriculture. Long-term measurements of tropospheric ozone have been performed globally for more than 30 years with UV photometers, all relying on the absorption of ozone at the 253.65 nm line of mercury. We have re-determined this cross-section and report a value of 11.27 × 10-18 cm2 molecule-1 with an expanded relative uncertainty of 0.84 %. This is lower than the conventional value currently in use and measured by Hearn in 1961 with a relative difference of 1.8%, with the consequence that historically reported ozone concentrations should be increased by 1.8%. In order to perform the new measurements of cross sections with reduced uncertainties, a system to generate pure ozone in the gas phase together with an optical system based on a UV laser with lines in the Hartley band, including accurate path length measurement of the absorption cell and a careful evaluation of possible impurities in the ozone sample by mass spectrometry and Fourier Transform Infrared spectroscopy was setup. This resulted in new measurements of absolute values of ozone absorption cross sections of 9.48 × 10-18, 10.44 × 10-18, and 11.07 × 10-18 cm2 molecule-1, with relative expanded uncertainties better than 0.6%, for the wavelengths (in vacuum) of 244.062, 248.32, and 257.34 nm respectively. The cross-section at the 253.65 nm line of mercury was determined by comparisons using a Standard Reference Photometer equipped with a mercury lamp as the light source. The newly reported value should be used in the future to obtain the most accurate measurements of ozone concentration, which are in closer agreement with non UV photometry based methods such as the gas phase titration of ozone with nitrogen monoxide.

  19. Absolute photoabsorption cross sections of Sr I from the 5s ionization threshold to the 5p threshold

    NASA Astrophysics Data System (ADS)

    Chu, C. C.; Fung, H. S.; Wu, H. H.; Yih, T. S.

    1998-09-01

    We have measured the absolute photoabsorption cross sections of Sr I from its 5s ionization threshold up to the 0953-4075/31/17/010/img1 thresholds. The spectrum includes the Sr I 0953-4075/31/17/010/img2, 0953-4075/31/17/010/img3, 0953-4075/31/17/010/img4 and 0953-4075/31/17/010/img5 doubly excited series which converge to the 0953-4075/31/17/010/img6 or 0953-4075/31/17/010/img1 series limits. Synchrotron radiation, from the 1 m Seya-Namioka beam line of the Synchrotron Radiation Research Center at Hsin-Chu, Taiwan, was used as the background continuum. The absolute column density was determined by measuring simultaneously the temperature distribution profiles and the total pressure in a heatpipe. Absolute cross sections were obtained using the Beer-Lambert law. The measured absolute cross section for the 5s ionization threshold was 0953-4075/31/17/010/img8. At the most significant autoionizing resonance, 0953-4075/31/17/010/img9 around 0953-4075/31/17/010/img10, the absolute cross section was measured as 0953-4075/31/17/010/img11. The absolute cross sections presented here are larger than those based on saturated vapour-pressure data, and less than those based on the f-value measurements. All the absolute cross sections in this work are compared with both recent experiments and

  20. Measurement of the absolute and differential cross sections for 7Li(γ, n0)6Li

    SciTech Connect

    W.A. Wurtz, R.E. Pywell, B.E. Norum, S. Kucuker, B.D. Sawatzky, H.R. Weller, M.W. Ahmed, S. Stave

    2011-10-01

    We have measured the cross section of the photoneutron reaction channel {sup 7}Li+{gamma}{yields}{sup 6}Li(g.s.)+n where the progeny nucleus is the ground state of {sup 6}Li. We obtained the absolute cross section at photon energies 10, 11, 12, 13, 15, 20, 25, 30, and 35 MeV and also the dependence of the cross section on polar angle for all but the highest photon energy. For the energies 10 to 15 MeV we were able to use linearly polarized photons to obtain the dependence of the cross section on the photon polarization.

  1. Absolute angle-differential vibrational excitation cross sections for electron collisions with diacetylene

    SciTech Connect

    Allan, M.; May, O.; Fedor, J.; Ibanescu, B. C.; Andric, L.

    2011-05-15

    Absolute vibrational excitation cross sections were measured for diacetylene (1,3-butadiyne). The selectivity of vibrational excitation reveals detailed information about the shape resonances. Excitation of the C{identical_to}C stretch and of double quanta of the C-H bend vibrations reveals a {sup 2}{Pi}{sub u} resonance at 1 eV (autodetachment width {approx}30 meV) and a {sup 2}{Pi}{sub g} resonance at 6.2 eV (autodetachment width 1-2 eV). There is a strong preference for excitation of even quanta of the bending vibration. Excitation of the C-H stretch vibration reveals {sigma}* resonances at 4.3, 6.8, and 9.8 eV, with autodetachment widths of {approx}2 eV. Detailed information about resonances permits conclusions about the mechanism of the dissociative electron attachment.

  2. Quantitative infrared absorption cross sections of isoprene for atmospheric measurements

    SciTech Connect

    Brauer, Carolyn S.; Blake, Thomas A.; Guenther, Alex B.; Sharpe, Steven W.; Sams, Robert L.; Johnson, Timothy J.

    2014-11-19

    The OH- and O3- initiated oxidations of isoprene, which is one of the primary volatile organic compounds produced by vegetation, are a major source of atmospheric formaldehyde and other oxygenated organics, yet little quantitative IR data exists for isoprene. We thus report absorption coefficients and integrated band intensities for isoprene in the 600 - 6500 cm-1 region. The pressure-broadened (1 atmosphere N2) spectra were recorded at 278, 298 and 323 K in a 19.96 cm path length cell at 0.112 cm-1 resolution, using a Bruker 66V FTIR. Composite spectra are derived from a minimum of seven pressures at each temperature.

  3. Measurements of the mass absorption cross section of atmospheric soot particles using Raman spectroscopy

    NASA Astrophysics Data System (ADS)

    Nordmann, S.; Birmili, W.; Weinhold, K.; Müller, K.; Spindler, G.; Wiedensohler, A.

    2013-11-01

    Soot particles are a major absorber of shortwave radiation in the atmosphere. The mass absorption cross section is an essential quantity to describe this light absorption process. This work presents new experimental data on the mass absorption cross section of soot particles in the troposphere over Central Europe. Mass absorption cross sections were derived as the ratio between the light absorption coefficient determined by multiangle absorption photometry (MAAP) and the soot mass concentration determined by Raman spectroscopy. The Raman method is sensitive to graphitic structures present in the particle samples and was calibrated in the laboratory using Printex®90 model particles. Mass absorption cross sections were determined for a number of seven observation sites, ranging between 3.9 and 7.4 m2 g-1depending on measurement site and observational period. The highest values were found in a continentally aged air mass in winter, where soot particles were assumed to be mainly internally mixed. Our values are in the lower range of previously reported values, possibly due to instrumental differences to the former photometer and mass measurements. Overall, a value of 5.3m2 g-1from orthogonal regression over all samples is considered to be representative for the soot mass absorption cross section in the troposphere over Central Europe.

  4. Gas-phase absorption cross sections of 24 monocyclic aromatic hydrocarbons in the UV and IR spectral ranges

    NASA Astrophysics Data System (ADS)

    Etzkorn, Thomas; Klotz, Björn; Sørensen, Søren; Patroescu, Iulia V.; Barnes, Ian; Becker, Karl H.; Platt, Ulrich

    Absorption cross sections of 24 volatile and non-volatile derivatives of benzene in the ultraviolet (UV) and the infrared (IR) regions of the electromagnetic spectrum have been determined using a 1080 l quartz cell. For the UV a 0.5 m Czerny-Turner spectrometer coupled with a photodiode array detector (spectral resolution 0.15 nm) was used. IR spectra were recorded with an FT-IR spectrometer (Bruker IFS-88, spectral resolution 1 cm -1). Absolute absorption cross sections and the instrument function are given for the UV, while for the IR, absorption cross sections and integrated band intensities are reported. The study focused primarily on the atmospherically relevant methylated benzenes (benzene, toluene, o-xylene, m-xylene, p-xylene, 1,2,4-trimethylbenzene, 1,3,5-trimethylbenzene, ethylbenzene, styrene) and their ring retaining oxidation products (benzaldehyde, o-tolualdehyde, m-tolualdehyde, p-tolualdehyde, phenol, o-cresol, m-cresol, p-cresol, 2,3-dimethylphenol, 2,4-dimethylphenol, 2,5-dimethylphenol, 2,6-dimethylphenol, 3,4-dimethylphenol, 3,5-dimethylphenol, 2,4,6-trimethylphenol and ( E,Z)- and ( E,E)-2,4-hexadienedial). The UV absorption cross sections reported here can be used for the evaluation of DOAS spectra (Differential Optical Absorption Spectroscopy) for measurements of the above compounds in the atmosphere and in reaction chambers, while the IR absorption cross sections will primarily be useful in laboratory studies on atmospheric chemistry, where FT-IR spectrometry is an important tool.

  5. Orthogonal spectra and cross sections: Application to optimization of multi-spectral absorption and fluorescence lidar

    SciTech Connect

    Shokair, I.R.

    1997-09-01

    This report addresses the problem of selection of lidar parameters, namely wavelengths for absorption lidar and excitation fluorescence pairs for fluorescence lidar, for optimal detection of species. Orthogonal spectra and cross sections are used as mathematical representations which provide a quantitative measure of species distinguishability in mixtures. Using these quantities, a simple expression for the absolute error in calculated species concentration is derived and optimization is accomplished by variation of lidar parameters to minimize this error. It is shown that the optimum number of wavelengths for detection of a species using absorption lidar (excitation fluorescence pairs for fluorescence lidar) is the same as the number of species in the mixture. Each species present in the mixture has its own set of optimum wavelengths. There is usually some overlap in these sets. The optimization method is applied to two examples, one using absorption and the other using fluorescence lidar, for analyzing mixtures of four organic compounds. The effect of atmospheric attenuation is included in the optimization process. Although the number of optimum wavelengths might be small, it is essential to do large numbers of measurements at these wavelengths in order to maximize canceling of statistical errors.

  6. Absolute Raman cross-sections of some explosives: Trend to UV

    NASA Astrophysics Data System (ADS)

    Nagli, L.; Gaft, M.; Fleger, Y.; Rosenbluh, M.

    2008-07-01

    The Raman cross-section dependence on excitation energy in spectral range 620-248 nm have been investigated for UN, TATP, RDX, TNT, and PETN explosives. For all investigated explosive materials, significant pre-resonance enhancement in the UV spectral range has been revealed. Normalized Raman scattering signals are 100-200 times stronger with UV excitation at 248 nm compared to visible excitation at 532 nm. Thus the gated Raman technique with UV excitation has significant advantages compared to IR-VIS excitation for the remote detection of explosives. Certain of the observed Raman lines exhibit deviations from classical λ-4 dependence of Raman cross-section and may totally disappear with UV excitation. The possible explanation for this may be that numerous electronic transitions contribute to the molecular polarizability. These contributions could be of opposite sign and lead to partial cancellation of certain transitions. Another possible reason could be that this is a result of the stronger UV absorption that reduces the sampling volume and therefore the number of scatterers that produce the Raman signal.

  7. Experimental determination of single CdSe nanowire absorption cross sections through photothermal imaging.

    PubMed

    Giblin, Jay; Syed, Muhammad; Banning, Michael T; Kuno, Masaru; Hartland, Greg

    2010-01-26

    Absorption cross sections ((sigma)abs) of single branched CdSe nanowires (NWs) have been measured by photothermal heterodyne imaging (PHI). Specifically, PHI signals from isolated gold nanoparticles (NPs) with known cross sections were compared to those of individual CdSe NWs excited at 532 nm. This allowed us to determine average NW absorption cross sections at 532 nm of (sigma)abs = (3.17 +/- 0.44) x 10(-11) cm2/microm (standard error reported). This agrees well with a theoretical value obtained using a classical electromagnetic analysis ((sigma)abs = 5.00 x 10(-11) cm2/microm) and also with prior ensemble estimates. Furthermore, NWs exhibit significant absorption polarization sensitivities consistent with prior NW excitation polarization anisotropy measurements. This has enabled additional estimates of the absorption cross section parallel ((sigma)abs) and perpendicular ((sigma)abs(perpendicular) to the NW growth axis, as well as the corresponding NW absorption anisotropy ((rho)abs). Resulting values of (sigma)abs = (5.6 +/- 1.1) x 10(-11) cm2/microm, (sigma)abs(perpendicular) = (1.26 +/- 0.21) x 10(-11) cm2/microm, and (rho)abs = 0.63+/- 0.04 (standard errors reported) are again in good agreement with theoretical predictions. These measurements all indicate sizable NW absorption cross sections and ultimately suggest the possibility of future direct single NW absorption studies.

  8. OH reaction rate constants and UV absorption cross-sections of unsaturated esters

    NASA Astrophysics Data System (ADS)

    Teruel, M. A.; Lane, S. I.; Mellouki, A.; Solignac, G.; Le Bras, G.

    Absolute rate coefficients have been determined for the gas-phase reactions of hydroxyl radicals with methyl acrylate ( k1), methyl methacrylate ( k2) and ethyl acrylate ( k3). Experiments were performed using two different techniques, the relative rate method and the pulsed laser photolysis-laser induced fluorescence technique. The kinetic data obtained were used to derive the following Arrhenius expressions in the temperature range 253-374 K (in units of cm 3 molecule -1 s -1): k1=(2.0±0.8)×10exp[(553±51)/T], k2=(2.5±0.8)×10exp[(821±55)/T], k3=(2.3±0.8)×10exp[(580±65)/T]. At 298 K, the reaction rate constants obtained by the two methods were in good agreement. In addition, the UV absorption spectra for the three unsaturated esters have been determined at (298±2) K and the absorption cross-sections in the wavelength region 215-298 nm were reported. The results are presented, discussed and used to estimate the atmospheric lifetimes for the studied esters.

  9. Total absorption and photoionization cross sections of water vapor between 100 and 1000 A

    NASA Technical Reports Server (NTRS)

    Haddad, G. N.; Samson, J. A. R.

    1986-01-01

    Absolute photoabsorption and photoionization cross sections of water vapor are reported at a large number of discrete wavelengths between 100 and 1000 A with an estimate error of + or - 3 percent in regions free from any discrete structure. The double ionization chamber technique utilized is described. Recent calculations are shown to be in reasonable agreement with the present data.

  10. Absorption cross-sections of sodium diatomic molecules. M.S. Thesis

    NASA Technical Reports Server (NTRS)

    Fong, Zeng-Shevan

    1985-01-01

    The absorption cross sections of sodium dimers were studied using a heat pipe over operating in the non-heat-pipe mode. Three wavelength regions were observed. They are in the red, the green-blue, and the near ultraviolet regions. The absorption cross section depends on the wavelength of the incident light. Representative peak values for the v"=0 progression in the red and green-blue regions are 2.59 A sup 2 (average value) and 11.77 A sup 2 (T sub ave=624 K). The value for the C greater than X transitions is several tenths A sup 2. The cross sections were measured from absorption spectra taken as a function of temperature.

  11. Absolute triple-differential cross sections for ionization-excitation of helium

    SciTech Connect

    Bartschat, K.; Bray, I.; Fursa, D. V.; Stelbovics, A. T.

    2007-08-15

    Triple-differential cross sections (TDCSs) for electron-impact ionization of He(1s{sup 2}){sup 1}S leading to He{sup +}(1s) are calculated using the highly accurate convergent close-coupling (CCC) method for incident projectile energies of 268.6 and 112.6 eV, with at least one of the outgoing electrons having an energy of 44 eV. These results are used to obtain absolute TDCSs from the recent experimental data [Bellm et al., Phys. Rev. A 75, 042704 (2007)] for TDCS ratios of ionization with no excitation to ionization with excitation resulting in He{sup +}(n=2,3,4). The TDCSs can be used as comparison benchmarks in future studies, and already allow us to test the accuracy of the TDCSs obtained from the hybrid distorted-wave+R-matrix (close-coupling) model, which was fairly successful in predicting the ratios, using CCC for n=1 and experimental results for n=2,3,4.

  12. Absolute cross sections for dissociative electron attachment to HCN and DCN

    SciTech Connect

    May, O.; Kubala, D.; Allan, M.

    2010-07-15

    Absolute partial cross sections for the formation of CN{sup -} in dissociative electron attachment to HCN and DCN have been measured using a time-of-flight ion spectrometer combined with a trochoidal electron monochromator to be 940pm{sup 2} for CN{sup -}/HCN and 340pm{sup 2} for CN{sup -}/DCN at peaks of the bands due to the {sup 2{Pi}}-shape resonance. The dissociative electron attachment bands were then recorded under higher resolution, 60 meV, with a trochoidal monochromator plus quadrupole mass filter combination and found to have a nearly vertical onset at the threshold energy and to peak at 1.85 eV. Broad structure was observed on the bands, assigned to formation of vibrationally excited CN{sup -}, from which the branching ratios could be determined to be 1,0.49, and 0.22 for the formation of CN{sup -} in the v=0,1, and 2 states, respectively. The results are compared to the recent multidimensional ab initio calculations of Chourou and Orel [Phys. Rev. A 80, 032709 (2009)].

  13. Absorption cross sections of some atmospheric molecules for resonantly scattered O I 1304-A radiation

    NASA Technical Reports Server (NTRS)

    Starr, W. L.

    1976-01-01

    Absorption cross sections for O2, N2, CO2, CH4, N2O, and CO have been measured at each of the lines of the atomic oxygen triplet at 1302, 1305, and 1306 A. Radiation resonantly scattered from oxygen atoms at a temperature of about 300 K was used for the line source. Absorber temperatures were also near 300 K. Direct application of the Lambert-Beer absorption equation yielded pressure-dependent cross sections for carbon monoxide at each line of the O I triplet. Reasons for this apparent dependence are presented and discussed.

  14. Relative high-resolution absorption cross sections of C2H6 at low temperatures

    NASA Astrophysics Data System (ADS)

    Hargreaves, R. J.; Bernath, P. F.; Appadoo, D. R. T.

    2015-09-01

    Synchrotron radiation has been used to record absorption cross sections of ethane, C2H6, in the far-infrared with very high spectral resolution (up to 0.00096 cm-1). C2H6 is present in the atmospheres of the Gas Giant planets and Titan but the vapor pressure at relevant atmospheric temperatures (i.e., between 70 and 200 K) is low. This makes laboratory measurements difficult. We demonstrate the effectiveness of a unique "enclosive flow" cold cell, located at the Australian Synchrotron, that enables high-resolution absorption cross sections of gaseous C2H6 to be recorded at 90 K.

  15. High-resolution absorption cross sections of C2H6 at elevated temperatures

    NASA Astrophysics Data System (ADS)

    Hargreaves, Robert J.; Buzan, Eric; Dulick, Michael; Bernath, Peter F.

    2015-11-01

    Infrared absorption cross sections near 3.3 μm have been obtained for ethane, C2H6. These were acquired at elevated temperatures (up to 773 K) using a Fourier transform infrared spectrometer and tube furnace with a resolution of 0.005 cm-1. The integrated absorption was calibrated using composite infrared spectra taken from the Pacific Northwest National Laboratory (PNNL). These new measurements are the first high-resolution infrared C2H6 cross sections at elevated temperatures.

  16. Temperature- and pressure-dependent absorption cross sections of gaseous hydrocarbons at 3.39 µm

    NASA Astrophysics Data System (ADS)

    Klingbeil, A. E.; Jeffries, J. B.; Hanson, R. K.

    2006-07-01

    The pressure- and temperature-dependent absorption cross sections of several neat hydrocarbons and multi-component fuels are measured using a 3.39 µm helium-neon laser. Absorption cross section measurements are reported for methane, ethylene, propane, n-heptane, iso-octane, n-decane, n-dodecane, JP-10, gasoline and jet-A with an estimated uncertainty of less than 3.5%. The experimental conditions range from 298 to 673 K and from 500 to 2000 Torr with nitrogen as the bath gas. An apparatus is designed to facilitate these measurements, and specific care is taken to ensure the compositional accuracy of the hydrocarbon/N2 mixtures. The absorption cross sections of the smallest hydrocarbons, methane and ethylene, vary with temperature and pressure. The cross sections of larger hydrocarbons show negligible dependence on pressure and only a weak dependence on temperature. The reported data increase the range of conditions and the number of hydrocarbons for which cross section measurements are available at the HeNe laser wavelength.

  17. Absolute Rb one-color two-photon ionization cross-section measurement near a quantum interference

    SciTech Connect

    Takekoshi, T.; Brooke, G.M.; Patterson, B.M.; Knize, R.J.

    2004-05-01

    We observe destructive interference in the ground-state Rb two-photon ionization cross section when the single photon energy is tuned between the 5S{yields}5P and 5S{yields}6P transition energies. The minimum cross section is 5.9(1.5)x10{sup -52} cm{sup 4} s and it occurs at a wavelength of 441.0(3) nm (in vacuo). Relative measurements of these cross sections are made at various wavelengths by counting ions produced when magneto-optically trapped Rb atoms are exposed to light from a tunable pulsed laser. This relative curve is calibrated to an absolute cross-section measurement at 532 nm using the trap loss method. A simple calculation agrees reasonably with our results.

  18. Absolute elastic differential electron scattering cross sections in the intermediate energy region. IV - CO

    NASA Technical Reports Server (NTRS)

    Tanaka, H.; Srivastava, S. K.; Chutjian, A.

    1978-01-01

    Using a crossed electron beam-molecular beam scattering geometry and a relative-flow technique, ratios of elastic differential cross sections of CO to those of He have been measured at electron impact energies of 3, 5, 7.5, 9.9, 15, 20, 30, 50, 75, and 100 eV. At each energy, an angular range of 15 to 130 deg has been covered. These ratios have been multiplied by previously known He elastic differential cross sections to obtain elastic differential cross sections for CO. Since pure rotational excitations were not resolved, the elastic differential cross sections are a sum of elastic and pure rotational excitations at room temperature. From a knowledge of differential cross sections (DCS), integral and momentum transfer cross sections have been calculated. Both the DCS and integral cross sections are compared at 50, 75, and 100 eV to a recent two-potential theory of e-molecule scattering. Present results show that the isoelectronic molecules CO and N2 have very similar magnitudes and shapes of their differential cross sections.

  19. Effect of pressure broadening on molecular absorption cross sections in exoplanetary atmospheres

    NASA Astrophysics Data System (ADS)

    Hedges, Christina; Madhusudhan, Nikku

    2016-05-01

    Spectroscopic observations of exoplanets are leading to unprecedented constraints on their atmospheric compositions. However, molecular abundances derived from spectra are degenerate with the absorption cross-sections which form critical input data in atmospheric models. Therefore, it is important to quantify the uncertainties in molecular cross-sections to reliably estimate the uncertainties in derived molecular abundances. However, converting line lists into cross-sections via line broadening involves a series of prescriptions for which the uncertainties are not well understood. We investigate and quantify the effects of various factors involved in line broadening in exoplanetary atmospheres - the profile evaluation width, pressure versus thermal broadening, broadening agent, spectral resolution and completeness of broadening parameters - on molecular absorption cross-sections. We use H2O as a case study as it has the most complete absorption line data. For low-resolution spectra (R ≲ 100) for representative temperatures and pressures (T ˜ 500-3000 K, P ≲ 1 atm) of H2-rich exoplanetary atmospheres, we find the median difference in cross-sections (δ) introduced by various aspects of pressure broadening to be ≲1 per cent. For medium resolutions (R ≲ 5000), including those attainable with James Webb Space Telescope, we find that δ can be up to 40 per cent. For high resolutions (R ˜ 105), δ can be ≳100 per cent, reaching ≳1000 per cent for low temperatures (T ≲ 500 K) and high pressures (P ≳ 1 atm). The effect is higher still for self-broadening. We generate a homogeneous data base of absorption cross-sections of molecules of relevance to exoplanetary atmospheres for which high-temperature line lists are available, particularly H2O, CO, CH4, CO2, HCN, and NH3.

  20. Absolute Rayleigh scattering cross sections of gases and freons of stratospheric interest in the visible and ultraviolet regions

    NASA Technical Reports Server (NTRS)

    SHARDANAND; Rao, A. D. P.

    1977-01-01

    The laboratory measurements of absolute Rayleigh scattering cross sections as a function wavelength are reported for gas molecules He, Ne, Ar, N2, H2, O2, CO2, CH4 and for vapors of most commonly used freons CCl2F2, CBrF3, CF4, and CHClf2. These cross sections are determined from the measurements of photon scattering at an angle of 54 deg 44 min which yield the absolute values independent of the value of normal depolarization ratios. The present results show that in the spectral range 6943-3638A deg, the values of the Rayleigh scattering cross section can be extrapolated from one wavelength to the other using 1/lambda (4) law without knowing the values of the polarizabilities. However, such an extrapolation can not be done in the region of shorter wavelengths.

  1. Absolute elastic differential electron scattering cross sections for He - A proposed calibration standard from 5 to 200 eV

    NASA Technical Reports Server (NTRS)

    Register, D. F.; Trajmar, S.; Srivastava, S. K.

    1980-01-01

    Absolute differential, integral, and momentum-transfer cross sections for electrons elastically scattered from helium are reported for the impact energy range of 5 to 200 eV. Angular distributions for elastically scattered electrons are measured in a crossed-beam geometry using a collimated, differentially pumped atomic-beam source which requires no effective-path-length correction. Below the first inelastic threshold the angular distributions were placed on an absolute scale by use of a phase-shift analysis. Above this threshold, the angular distributions from 10 to 140 deg were fitted using the phase-shift technique, and the resulting integral cross sections were normalized to a semiempirically derived integral elastic cross section. Depending on the impact energy, the data are estimated to be accurate to within 5 to 9%.

  2. Measurement of the absolute Raman cross section of the optical phonon in silicon

    NASA Astrophysics Data System (ADS)

    Aggarwal, R. L.; Farrar, L. W.; Saikin, S. K.; Aspuru-Guzik, A.; Stopa, M.; Polla, D. L.

    2011-04-01

    The absolute Raman cross section σ of the first-order 519 cm -1 optical phonon in silicon was measured using a small temperature-controlled blackbody for the signal calibration of the Raman system. Measurements were made with a 25-mil thick (001) silicon sample located in the focal plane of a 20-mm effective focal length (EFL) lens using 785-, 1064-, and 1535-nm CW pump lasers for the excitation of Raman scattering. The pump beam was polarized along the [100] axis of the silicon sample. Values of 1.0±0.2×10 -27, 3.6±0.7×10 -28, and 1.1±0.2×10 -29 cm 2 were determined for σ for 785-, 1064-, and 1535-nm excitation, respectively. The corresponding values of the Raman scattering efficiency S are 4.0±0.8×10 -6, 1.4±0.3×10 -6, and 4.4±0.8×10 -8 cm -1 sr -1.The values of the Raman polarizability |d| for 785-, 1064-, and 1535-nm excitation are 4.4±0.4×10 -15, 5.1±0.5×10 -15, and 1.9±0.2×10 -15 cm 2, respectively. The values of 4.4±0.4×10 -15 and 5.1±0.5×10 -15 cm 2 for |d| for 785- and 1064-nm excitation, respectively, are 1.3 and 2.0 times larger than the values of 3.5×10 -15 and 2.5×10 -15 cm 2 calculated by Wendel. The Raman polarizability |d| computed using the density functional theory in the long-wavelength limit is consistent with the general trend of the measured data and Wendel's model.

  3. Energy-absorption capability and scalability of square cross section composite tube specimens

    NASA Technical Reports Server (NTRS)

    Farley, Gary L.

    1987-01-01

    Static crushing tests were conducted on graphite/epoxy and Kevlar/epoxy square cross section tubes to study the influence of specimen geometry on the energy-absorption capability and scalability of composite materials. The tube inside width-to-wall thickness (W/t) ratio was determined to significantly affect the energy-absorption capability of composite materials. As W/t ratio decreases, the energy-absorption capability increases nonlinearly. The energy-absorption capability of Kevlar epoxy tubes was found to be geometrically scalable, but the energy-absorption capability of graphite/epoxy tubes was not geometrically scalable.

  4. Cross section calculations of astrophysical interest. [for theories of absorption and emission lines

    NASA Technical Reports Server (NTRS)

    Gerjuoy, E.

    1974-01-01

    Cross sections are discussed for rotational excitation associated with theories of absorption and emission lines from molecules in space with emphasis on H2CO, CO, and OH by collisions with neutral particles such H, H2, and He. The sensitivity of the Thaddeus equation for the H2CO calculation is examined.

  5. Measurement of Two-Photon Absorption Cross Section of Metal Ions by a Mass Sedimentation Approach

    PubMed Central

    Ma, Zhuo-Chen; Chen, Qi-Dai; Han, Bing; Liu, Xue-Qing; Song, Jun-Feng; Sun, Hong-Bo

    2015-01-01

    The photo-reduction of metal ions in solution induced by femtosecond laser is an important and novel method for fabricating three-dimensional metal microstructures. However, the nonlinear absorption cross section of metal ions remains unknown because its measurement is difficult. In the present study, a method based on Two-Photon Excited Sedimentation (TPES) is proposed to measure the two-photon absorption cross section (TPACS) of metal ions in solution. The power-squared dependence of the amount of sediment on the excitation intensity was confirmed, revealing that 800 nm femtosecond laser induced reduction of metal ions was a two photon absorption process. We believe that the proposed method may be applied to measure the TPACS of several metal ions, thereby opening a new avenue towards future analysis of two-photon absorption materials. PMID:26657990

  6. Derivation of water vapour absorption cross-sections in the red region

    NASA Technical Reports Server (NTRS)

    Lal, M.; Chakrabarty, D. K.

    1994-01-01

    Absorption spectrum in 436 to 448 nm wavelength region gives NO2 and O3 column densities. This spectrum can also give H2O column density. The spectrum in the range of 655 to 667 nm contains absorption due to NO3 and H2O. Combining the absorption spectra in the wavelength ranges of 436 to 448 and 655 to 667 nm, water vapor absorption cross-sections in this range comes out to be of the order of 2.0 x 10(exp -24) cm(exp -2).

  7. Absolute Photoionization Cross Sections for Br2+ in the 4 p --> 4d and 3d --> 4p Energy Regions

    NASA Astrophysics Data System (ADS)

    Aguilar, A.; Juarez, A. M.; Bilodeau, R. C.; Esteves, D. A.; Hardy, D. A.; Red, E. C.

    2011-05-01

    Absolute single photoionization cross-section measurements are reported for Br2+ in the 31 eV to 46 eV and 64 eV to 72 eV photon energy ranges. The first energy range includes the low-lying 2P3 / 2 , 1 / 2 and 2D5 / 2 , 3 / 2 metastable state thresholds and extends for 10 eV above the 4S3 / 2 ground state threshold. Strong photoexcitation-autoionization resonances due to 4p --> nd transitions are seen in the cross-section spectrum and identified based on a quantum-defect analysis of the series. The systematic behavior of the quantum defect parameter of some of the Rydberg series observed in the Br2+ spectrum as well as in previously measured Se+ spectrum, are analyzed as a function of the nuclear charge. The 64 eV to 72 eV energy range contains discrete structure that arises from 3d --> np excitations. The R-matrix photoionization cross section calculations of Cummings and O'Sullivan, PRA, 54 (1996) are compared to our absolute cross section measurements in this energy range. Absolute single photoionization cross-section measurements are reported for Br2+ in the 31 eV to 46 eV and 64 eV to 72 eV photon energy ranges. The first energy range includes the low-lying 2P3 / 2 , 1 / 2 and 2D5 / 2 , 3 / 2 metastable state thresholds and extends for 10 eV above the 4S3 / 2 ground state threshold. Strong photoexcitation-autoionization resonances due to 4p --> nd transitions are seen in the cross-section spectrum and identified based on a quantum-defect analysis of the series. The systematic behavior of the quantum defect parameter of some of the Rydberg series observed in the Br2+ spectrum as well as in previously measured Se+ spectrum, are analyzed as a function of the nuclear charge. The 64 eV to 72 eV energy range contains discrete structure that arises from 3d --> np excitations. The R-matrix photoionization cross section calculations of Cummings and O'Sullivan, PRA, 54 (1996) are compared to our absolute cross section measurements in this energy range. This work is

  8. Modeling of gas absorption cross sections by use of principal-component-analysis model parameters.

    PubMed

    Bak, Jimmy

    2002-05-20

    Monitoring the amount of gaseous species in the atmosphere and exhaust gases by remote infrared spectroscopic methods calls for the use of a compilation of spectral data, which can be used to match spectra measured in a practical application. Model spectra are based on time-consuming line-by-line calculations of absorption cross sections in databases by use of temperature as input combined with path length and partial and total pressure. It is demonstrated that principal component analysis (PCA) can be used to compress the spectrum of absorption cross sections, which depend strongly on temperature, into a reduced representation of score values and loading vectors. The temperature range from 300 to 1000 K is studied. This range is divided into two subranges (300-650 K and 650-1000K), and separate PCA models are constructed for each. The relationship between the scores and the temperature values is highly nonlinear. It is shown, however, that because the score-temperature relationships are smooth and continuous, they can be modeled by polynomials of varying degrees. The accuracy of the data compression method is validated with line-by-line-calculated absorption data of carbon monoxide and water vapor. Relative deviations between the absorption cross sections reconstructed from the PCA model parameters and the line-by-line-calculated values are found to be smaller than 0.15% for cross sections exceeding 1.27 x 10(-21) cm(-1) atm(-1) (CO) and 0.20% for cross sections exceeding 4.03 x 10(-21) cm(-1) atm(-1) (H2O). The computing time is reduced by a factor of 10(4). PMID:12027171

  9. Uncertainty budgets of major ozone absorption cross sections used in UV remote sensing applications

    NASA Astrophysics Data System (ADS)

    Weber, Mark; Gorshelev, Victor; Serdyuchenko, Anna

    2016-09-01

    Detailed uncertainty budgets of three major ultraviolet (UV) ozone absorption cross-section datasets that are used in remote sensing application are provided and discussed. The datasets are Bass-Paur (BP), Brion-Daumont-Malicet (BDM), and the more recent Serdyuchenko-Gorshelev (SG). For most remote sensing application the temperature dependence of the Huggins ozone band is described by a quadratic polynomial in temperature (Bass-Paur parameterization) by applying a regression to the cross-section data measured at selected atmospherically relevant temperatures. For traceability of atmospheric ozone measurements, uncertainties from the laboratory measurements as well as from the temperature parameterization of the ozone cross-section data are needed as input for detailed uncertainty calculation of atmospheric ozone measurements. In this paper the uncertainty budgets of the three major ozone cross-section datasets are summarized from the original literature. The quadratic temperature dependence of the cross-section datasets is investigated. Combined uncertainty budgets is provided for all datasets based upon Monte Carlo simulation that includes uncertainties from the laboratory measurements as well as uncertainties from the temperature parameterization. Between 300 and 330 nm both BDM and SG have an overall uncertainty of 1.5 %, while BP has a somewhat larger uncertainty of 2.1 %. At temperatures below about 215 K, uncertainties in the BDM data increase more strongly than the others due to the lack of very low temperature laboratory measurements (lowest temperature of BDM available is 218 K).

  10. Universality of high-energy absorption cross sections for black holes

    SciTech Connect

    Decanini, Yves; Esposito-Farese, Gilles; Folacci, Antoine

    2011-02-15

    We consider the absorption problem for a massless scalar field propagating in static and spherically symmetric black holes of arbitrary dimension endowed with a photon sphere. For this wide class of black holes, we show that the fluctuations of the high-energy absorption cross section are totally and very simply described from the properties (dispersion relation and damping) of the waves trapped near the photon sphere and therefore, in the eikonal regime, from the characteristics (orbital period and Lyapunov exponent) of the null unstable geodesics lying on the photon sphere. This is achieved by using Regge pole techniques. They permit us to make an elegant and powerful resummation of the absorption cross section and to extract then all the physical information encoded in the sum over the partial wave contributions. Our analysis induces moreover some consequences concerning Hawking radiation which we briefly report.

  11. Absolute elastic differential electron scattering cross sections in the intermediate energy region. III - SF6 and UF6

    NASA Technical Reports Server (NTRS)

    Srivastava, S. K.; Trajmar, S.; Chutjian, A.; Williams, W.

    1976-01-01

    A recently developed technique has been used to measure the ratios of elastic differential electron scattering cross sections (DCS) for SF6 and UF6 to those of He at electron impact energies of 5, 10, 15, 20, 30, 40, 50, 60, and 75 eV and at scattering angles of 20 to 135 deg. In order to obtain the absolute values of DCS from these ratios, He DCS of McConkey and Preston have been employed in the 20 to 90 deg range. At angles in the 90 to 135 deg range the recently determined cross sections of Srivastava and Trajmar have been utilized. From these DCS, elastic integral and momentum transfer cross sections have been obtained.

  12. The recent absolute total np and pp cross section determinations: quality of data description and prediction of experimental observables

    SciTech Connect

    Laptev, Alexander B; Haight, Robert C; Arndt, Richard A; Briscoe, William J; Paris, Mark W; Strakovsky, Igor I; Workman, Ron L

    2010-01-01

    The absolute total cross sections for np and pp scattering below 1000 MeV are determined based on partial-wave analyses (PWAs) of nucleon-nucleon scattering data. These cross sections are compared with the most recent ENDF/B-VII.0 and JENDL-3.3 data files, and the Nijmegen PWA. Systematic deviations from the ENDF/B-VII.0 and JENDL-3.3 evaluations are found to exist in the low-energy region. Comparison of the np evaluation with the result of most recent np total and differential cross section measurements will be discussed. Results of those measurements were not used in the evaluation database. A comparison was done to check a quality of evaluation and its capabilities to predict experimental observables. Excellent agreement was found between the new experimental data and our PWA predictions.

  13. Thermal neutron absorption cross sections for igneous rocks: Newberry Caldera, Oregon

    SciTech Connect

    Lysne, P.

    1990-01-01

    The thermal neutron absorption cross sections of geologic materials are of first-order importance to the interpretation of pulsed neutron porosity logs and of second-order importance to the interpretation of steady-state porosity logs using dual detectors. Even in the latter case, uncertainties in log response can be excessive whenever formations are encountered that possess absorption properties appreciably greater than the limestones used in most tool calibrations. These effects are of importance to logging operations directed at geothermal applications where formation vary from igneous to sedimentary and which may contain solution-deposited minerals with very large cross-section values. Most measurements of cross-section values for geologic materials have been made for hydrocarbon production applications. Hence, the specimen materials are sedimentary and clean in the sense that they are not altered by geothermal fluids. This investigation was undertaken to measure cross-section values from a sequence of igneous materials obtained from a single hole drilled in an active hydrothermal system. 3 refs., 1 fig.

  14. Exceptionally large two- and three-photon absorption cross-sections by OPV organometalation.

    PubMed

    Gao, Beibei; Mazur, Leszek M; Morshedi, Mahbod; Barlow, Adam; Wang, Huan; Quintana, Cristóbal; Zhang, Chi; Samoc, Marek; Cifuentes, Marie P; Humphrey, Mark G

    2016-07-01

    Oligo(p-phenylenevinylene)s (OPVs) containing up to 8 PV units and end-functionalized by ruthenium alkynyl groups have been prepared and their nonlinear absorption properties assessed using the Z-scan technique and employing low repetition rate femtosecond pulses. Exceptionally large two-photon absorption (ca. 12 500 GM at 725 nm) and three-photon absorption cross sections (ca. 1.6 × 10(-76) cm(6) s(2) at 1100 nm) are found for the 8PV-containing example, highlighting the potential of an "organometalation" approach to NLO-efficient organic materials. PMID:27297290

  15. Absolute cross sections for the dissociation of hydrogen cluster ions in high-energy collisions with helium atoms

    SciTech Connect

    Eden, S.; Tabet, J.; Samraoui, K.; Louc, S.; Farizon, B.; Farizon, M.; Ouaskit, S.; Maerk, T. D.

    2006-02-15

    Absolute dissociation cross sections are reported for H{sub n}{sup +} clusters of varied mass (n=3,5,...,35) following collisions with He atoms at 60 keV/amu. Initial results have been published previously for a smaller range of cluster sizes [Ouaskit et al., Phys. Rev. A 49, 1484 (1994)]. The present extended study includes further experimental results, reducing the statistical errors associated with the absolute cross sections. The previously suggested quasilinear dependence of the H{sub n}{sup +} dissociation cross sections upon n is developed with reference to expected series of geometrical shells of H{sub 2} molecules surrounding a H{sub 3}{sup +} core. Recent calculations identify n=9 as corresponding to the first closed H{sub 2} shell [e.g., Stich et al., J. Chem. Phys. 107, 9482 (1997)]. Recurrence of the distinct characteristics observed in the dissociation-cross-section dependence upon cluster size around n=9 provides the basis for the presently proposed subsequent closed shells at n=15, 21, 27, and 33, in agreement with the calculations of Nagashima et al. [J. Phys. Chem. 96, 4294 (1992)].

  16. Temperature dependent measurement of absorption and emission cross sections for various Yb3+ doped laser materials

    NASA Astrophysics Data System (ADS)

    Körner, J.; Hein, J.; Kahle, M.; Liebetrau, H.; Lenski, M.; Kaluza, M.; Loeser, M.; Siebold, M.

    2011-06-01

    For laser performance simulations, optical properties of applied active materials have to be exactly known. Here we report on temperature dependent emission and absorption cross section measurements for Yb:YAG, Yb:CaF2 and Yb:FP15-glass. The temperature of the samples was aligned in steps of 20 K between 100 K and room temperature with a liquid nitrogen driven cryostat. Absorption spectra were obtained with a fiber coupled white light source and fluorescence spectra by excitation with a fiber coupled 10W laser diode at 970 nm. All spectral measurements were performed with a scanning spectrum analyzer, providing a spectral resolution down to 0.05 nm. By applying the McCumber relation in combination with the Fuchtbauer-Ladenburg method, we were able to obtain a valid emission cross section over the whole range of interest from the measured data.

  17. Absorption cross-section and decay rate of rotating linear dilaton black holes

    NASA Astrophysics Data System (ADS)

    Sakalli, I.; Aslan, O. A.

    2016-02-01

    We analytically study the scalar perturbation of non-asymptotically flat (NAF) rotating linear dilaton black holes (RLDBHs) in 4-dimensions. We show that both radial and angular wave equations can be solved in terms of the hypergeometric functions. The exact greybody factor (GF), the absorption cross-section (ACS), and the decay rate (DR) for the massless scalar waves are computed for these black holes (BHs). The results obtained for ACS and DR are discussed through graphs.

  18. Absolute cross sections for vibrational excitations of cytosine by low energy electron impact

    NASA Astrophysics Data System (ADS)

    Michaud, M.; Bazin, M.; Sanche, L.

    2012-09-01

    The absolute cross sections (CSs) for vibrational excitations of cytosine by electron impact between 0.5 and 18 eV were measured by electron-energy loss (EEL) spectroscopy of the molecule deposited at monolayer coverage on an inert Ar substrate. The vibrational energies compare to those that have been reported from IR spectroscopy of cytosine isolated in Ar matrix, IR and Raman spectra of polycrystalline cytosine, and ab initio calculation. The CSs for the various H bending modes at 142 and 160 meV are both rising from their energy threshold up to 1.7 and 2.1 × 10-17 cm2 at about 4 eV, respectively, and then decrease moderately while maintaining some intensity at 18 eV. The latter trend is displayed as well for the CS assigned to the NH2 scissor along with bending of all H at 179 meV. This overall behavior in electron-molecule collision is attributed to direct processes such as the dipole, quadrupole, and polarization contributions, etc. of the interaction of the incident electron with a molecule. The CSs for the ring deformation at 61 meV, the ring deformation with N-H symmetric wag at 77 meV, and the ring deformations with symmetric bending of all H at 119 meV exhibit common enhancement maxima at 1.5, 3.5, and 5.5 eV followed by a broad hump at about 12 eV, which are superimposed on the contribution due to the direct processes. At 3.5 eV, the CS values for the 61-, 77-, and 119-meV modes reach 4.0, 3.0, and 4.5 × 10-17 cm2, respectively. The CS for the C-C and C-O stretches at 202 meV, which dominates in the intermediate EEL region, rises sharply until 1.5 eV, reaches its maximum of 5.7 × 10-17 cm2 at 3.5 eV and then decreases toward 18 eV. The present vibrational enhancements, correspond to the features found around 1.5 and 4.5 eV in electron transmission spectroscopy (ETS) and those lying within 1.5-2.1 eV, 5.2-6.8 eV, and 9.5-10.9 eV range in dissociative electron attachment (DEA) experiments with cytosine in gas phase. While the ETS features are ascribed

  19. Absolute cross sections for vibrational excitations of cytosine by low energy electron impact.

    PubMed

    Michaud, M; Bazin, M; Sanche, L

    2012-09-21

    The absolute cross sections (CSs) for vibrational excitations of cytosine by electron impact between 0.5 and 18 eV were measured by electron-energy loss (EEL) spectroscopy of the molecule deposited at monolayer coverage on an inert Ar substrate. The vibrational energies compare to those that have been reported from IR spectroscopy of cytosine isolated in Ar matrix, IR and Raman spectra of polycrystalline cytosine, and ab initio calculation. The CSs for the various H bending modes at 142 and 160 meV are both rising from their energy threshold up to 1.7 and 2.1 × 10(-17) cm(2) at about 4 eV, respectively, and then decrease moderately while maintaining some intensity at 18 eV. The latter trend is displayed as well for the CS assigned to the NH(2) scissor along with bending of all H at 179 meV. This overall behavior in electron-molecule collision is attributed to direct processes such as the dipole, quadrupole, and polarization contributions, etc. of the interaction of the incident electron with a molecule. The CSs for the ring deformation at 61 meV, the ring deformation with N-H symmetric wag at 77 meV, and the ring deformations with symmetric bending of all H at 119 meV exhibit common enhancement maxima at 1.5, 3.5, and 5.5 eV followed by a broad hump at about 12 eV, which are superimposed on the contribution due to the direct processes. At 3.5 eV, the CS values for the 61-, 77-, and 119-meV modes reach 4.0, 3.0, and 4.5 × 10(-17) cm(2), respectively. The CS for the C-C and C-O stretches at 202 meV, which dominates in the intermediate EEL region, rises sharply until 1.5 eV, reaches its maximum of 5.7 × 10(-17) cm(2) at 3.5 eV and then decreases toward 18 eV. The present vibrational enhancements, correspond to the features found around 1.5 and 4.5 eV in electron transmission spectroscopy (ETS) and those lying within 1.5-2.1 eV, 5.2-6.8 eV, and 9.5-10.9 eV range in dissociative electron attachment (DEA) experiments with cytosine in gas phase. While the ETS features

  20. Effect of light state transitions on the apparent absorption cross section of Photosystem II in Chlorella

    SciTech Connect

    Falkowski, P.G.; Fujita, Yoshihiko

    1986-01-01

    The distribution of excitation energy between photosystems may profoundly affect the quantum yield of photosynthetic oxygen evolution. Excitation energy absorbed by pigment molecules is transferred to reaction centers, where it may potentially drive a photochemical event. To balance the photochemical events in PSII with those in PSI, excitation energy may be transferred between PSII and PSI. This type of energy transfer has been inferred primarily in the steady state quantum yield of oxygen evolution and/or fluorescence with changes in excitation wavelength. These so called ''state transitions'' have been attributed to changes in either the absorption cross section of PSII or ''spillover'' of excitation energy between the two photosystems. We report here on measurements of relative absorption cross sections of PSII under state I and state II light conditions. We simultaneously followed the yields of O/sub 2/ and the change in fluorescence yields, ..delta.. phi, as a function of flash energy using single turnover xenon flashes. Our data suggest that the effective absorption cross section of PSII does not change within +- 10% under physiological conditions in unpoisoned Chlorella pyrenoidosa. 13 refs., 3 figs.

  1. Quantitative comparisons of absorption cross-section spectra and integrated intensities of HFC-143a

    NASA Astrophysics Data System (ADS)

    Le Bris, Karine; Graham, Laura

    2015-01-01

    The integrated absorption cross-sections of HFC-143a (CH3CF3) differ substantially in the literature. This leads to an important uncertainty on the value of the radiative efficiency of this molecule. The ambiguity on the absorption cross-sections of HFC-143a is highlighted by the existence of two significantly different datasets in the HITRAN database. To solve the issue, we performed high-resolution Fourier transform infrared laboratory measurements of HFC-13a and compared the spectra with the two HITRAN datasets and with the data from the Pacific Northwest National Laboratory (PNNL). The experimental methods and data analysis techniques are examined and typical sources of errors are discussed. The integrated intensities of the main bands are compared to other literature values. It was found that the integrated absorption cross-section values in the highest range - around 13.8 ×10-17 cm .molecule-1 in the 570-1500 cm-1 spectral band - show the most consistency between authors.

  2. Supplementary absolute differential cross sections for the excitation of atomic hydrogen's n=3 and 4 levels by electron impact

    SciTech Connect

    Sweeney, Christopher J.; Shyn, Tong W.; Grafe, Alan

    2004-05-01

    We have conducted measurements of absolute differential cross sections for the excitation of hydrogen atoms to their n=3(3S+3P+3D) and 4(4S+4P+4D+4F) levels. A modulated, crossed-beam method was employed, and the impact energies were 40 and 60 eV. Comparison of our results with those of others is quite favorable.

  3. Measurement of the absolute differential cross section of proton–proton elastic scattering at small angles

    DOE PAGES

    Mchedlishvili, D.; Chiladze, D.; Dymov, S.; Bagdasarian, Z.; Barsov, S.; Gebel, R.; Gou, B.; Hartmann, M.; Kacharava, A.; Keshelashvili, I.; et al

    2016-02-03

    The differential cross section for proton-proton elastic scattering has been measured at a beam kinetic energy of 1.0 GeV and in 200 MeV steps from 1.6 to 2.8 GeV for centre-of-mass angles in the range from 12°-16° to 25°-30°, depending on the energy. A precision in the overall normalisation of typically 3% was achieved by studying the energy losses of the circulating beam of the COSY storage ring as it passed repeatedly through the windowless hydrogen target of the ANKE magnetic spectrometer. It is shown that the data have a significant impact upon the results of a partial wave analysis.more » Furthermore, after extrapolating the differential cross sections to the forward direction, the results are broadly compatible with the predictions of forward dispersion relations.« less

  4. Measurements of the infrared absorption cross-sections of HCFC-141b (CH3CFCl2)

    NASA Astrophysics Data System (ADS)

    Le Bris, Karine; McDowell, James; Strong, Kimberly

    2012-10-01

    Detection of atmospheric trace gases by optical remote sensing techniques relies on the availability of molecular absorption spectra over a range of relevant temperatures. Absorption cross-sections of a pure vapour of the hydrochlorofluorocarbon HCFC-141b are reported at a resolution of 0.02 cm-1 for a range of temperatures between 223 and 283 K and a spectral range of 570-3100 cm-1. The integrated intensities of the nine main harmonic bands compare well with the data available from previous experimental studies and with theoretical calculations by ab initio and density functional theories.

  5. Total cross section for photon absorption by two protons in [sup 3]He

    SciTech Connect

    Emura, T.; Endo, S.; Huber, G.M.; Itoh, H.; Kato, S.; Koike, M.; Konno, O.; Lasiuk, B.; Lolos, G.J.; Maeda, K.; Maki, T.; Maruyama, K.; Miyamoto, H.; Naridomi, R.; Niki, K.; Ogata, T.; Rangacharyulu, C.; Sasaki, A.; Suda, T.; Sumi, Y.; Wada, Y.; Yamazaki, H. Department of Physics, Hiroshima University, Higashi-Hiroshima 724 Department of Physics, University of Regina, Regina, SK, S4S0A2 Department of Physics, Saga University, Saga 840 Institute for Nuclear Study, University of Tokyo, Tanashi, Tokyo 188 Laboratory of Nuclear Science, Tohoku University, Sendai 982 Department of Physics, University of Saskatchewan, Saskatoon, SK, S7N0W0 Department of Physics, Tohoku University, Sendai 980 University of Occupational and Environmental Health, Kitakyushi 807 College of General Education, Akita University, Akita, 010

    1994-07-18

    The [sup 3]He([gamma],[ital pp])[ital n] reaction was investigated in the photon energy range 200--500 MeV using the spectrometer TAGX, which has a solid angle for protons of [pi] sr. Two types of photon absorption, one by two protons and the other by three nucleons, were observed by looking at the undetected neutron momentum distributions. The total cross section for photon absorption by two protons shows that this process is consistent with the [ital E]2 transition.

  6. Absorption Cross Sections of Hot Hydrocarbons in the 3 μm Region

    NASA Astrophysics Data System (ADS)

    Beale, Christopher A.; Hargreaves, Robert J.; Buzan, Eric M.; Bernath, Peter F.

    2016-06-01

    The 3 μm region of ethane, propane and propene contains a number of vibrational modes dominated by various C-H stretches. Transmission spectra for these hydrocarbons have been obtained at high resolution (0.005 wn) and at elevated temperatures (up to 773 K). The integrated absorption cross sections over the isolated 3 μm region are calibrated to those from the Pacific Northwest National Laboratory (PNNL) in order to obtain an effective pressure for the sample. With the Jovian Infrared Auroral Mapper (JIRAM on Juno) due to arrive at Jupiter in July 2016, these cross sections will find use in the study of hot emission from hydrocarbons in the auroral regions of Jupiter. They are also appropriate for modeling atmospheres of hot Jupiter exoplanets and brown dwarfs.

  7. Infrared absorption cross sections for 1,1,1,2-tetrafluoroethane

    NASA Astrophysics Data System (ADS)

    Harrison, Jeremy J.

    2015-01-01

    High-resolution infrared absorption cross sections for 1,1,1,2-tetrafluoroethane have been determined over the spectral range 750-1600 cm-1 from spectra recorded using a high-resolution FTIR spectrometer (Bruker IFS 125HR) and a 26-cm-pathlength cell. Spectra of 1,1,1,2-tetrafluoroethane/dry synthetic air mixtures were recorded at 0.015 cm-1 resolution (calculated as 0.9/MOPD) at a number of temperatures and pressures (22-761 Torr and 191-296 K) appropriate for atmospheric conditions. Intensities were calibrated using composite 1,1,1,2-tetrafluoroethane spectra taken from the Pacific Northwest National Laboratory (PNNL) IR database. This cross section dataset is intended to replace what is currently available in the HITRAN/GEISA databases.

  8. A new method for measuring absolute total electron-impact cross sections with forward scattering corrections

    SciTech Connect

    Ma, C.; Liescheski, P.B.; Bonham, R.A. )

    1989-12-01

    In this article we describe an experimental technique to measure the total electron-impact cross section by measurement of the attenuation of an electron beam passing through a gas at constant pressure with the unwanted forward scattering contribution removed. The technique is based on the different spatial propagation properties of scattered and unscattered electrons. The correction is accomplished by measuring the electron beam attenuation dependence on both the target gas pressure (number density) and transmission length. Two extended forms of the Beer--Lambert law which approximately include the contributions for forward scattering and for forward scattering plus multiple scattering from the gas outside the electron beam were developed. It is argued that the dependence of the forward scattering on the path length through the gas is approximately independent of the model used to describe it. The proposed methods were used to determine the total cross section and forward scattering contribution from argon (Ar) with 300-eV electrons. Our results are compared with those in the literature and the predictions of theory and experiment for the forward scattering and multiple scattering contributions. In addition, Monte Carlo simulations were performed as a further test of the method.

  9. Absolute Charge Transfer and Fragmentation Cross Sections in He{sup 2+}-C{sub 60} Collisions

    SciTech Connect

    Rentenier, A.; Moretto-Capelle, P.; Bordenave-Montesquieu, D.; Bordenave-Montesquieu, A.; Ruiz, L. F.; Diaz-Tendero, S.; Alcami, M.; Martin, F.; Zarour, B.; Hanssen, J.; Hervieux, P.-A.; Politis, M. F.

    2008-05-09

    We have determined absolute charge transfer and fragmentation cross sections in He{sup 2+}+C{sub 60} collisions in the impact-energy range 0.1-250 keV by using a combined experimental and theoretical approach. We have found that the cross sections for the formation of He{sup +} and He{sup 0} are comparable in magnitude, which cannot be explained by the sole contribution of pure single and double electron capture but also by contribution of transfer-ionization processes that are important even at low impact energies. The results show that multifragmentation is important only at impact energies larger than 40 keV; at lower energies, sequential C{sub 2} evaporation is the dominant process.

  10. Absorption cross-sections of ozone in the ultraviolet and visible spectral regions: Status report 2015

    NASA Astrophysics Data System (ADS)

    Orphal, Johannes; Staehelin, Johannes; Tamminen, Johanna; Braathen, Geir; De Backer, Marie-Renée; Bais, Alkiviadis; Balis, Dimitris; Barbe, Alain; Bhartia, Pawan K.; Birk, Manfred; Burkholder, James B.; Chance, Kelly; von Clarmann, Thomas; Cox, Anthony; Degenstein, Doug; Evans, Robert; Flaud, Jean-Marie; Flittner, David; Godin-Beekmann, Sophie; Gorshelev, Viktor; Gratien, Aline; Hare, Edward; Janssen, Christof; Kyrölä, Erkki; McElroy, Thomas; McPeters, Richard; Pastel, Maud; Petersen, Michael; Petropavlovskikh, Irina; Picquet-Varrault, Benedicte; Pitts, Michael; Labow, Gordon; Rotger-Languereau, Maud; Leblanc, Thierry; Lerot, Christophe; Liu, Xiong; Moussay, Philippe; Redondas, Alberto; Van Roozendael, Michel; Sander, Stanley P.; Schneider, Matthias; Serdyuchenko, Anna; Veefkind, Pepijn; Viallon, Joële; Viatte, Camille; Wagner, Georg; Weber, Mark; Wielgosz, Robert I.; Zehner, Claus

    2016-09-01

    The activity "Absorption Cross-Sections of Ozone" (ACSO) started in 2008 as a joint initiative of the International Ozone Commission (IO3C), the World Meteorological Organization (WMO) and the IGACO ("Integrated Global Atmospheric Chemistry Observations") O3/UV subgroup to study, evaluate, and recommend the most suitable ozone absorption cross-section laboratory data to be used in atmospheric ozone measurements. The evaluation was basically restricted to ozone absorption cross-sections in the UV range with particular focus on the Huggins band. Up until now, the data of Bass and Paur published in 1985 (BP, 1985) are still officially recommended for such measurements. During the last decade it became obvious that BP (1985) cross-section data have deficits for use in advanced space-borne ozone measurements. At the same time, it was recognized that the origin of systematic differences in ground-based measurements of ozone required further investigation, in particular whether the BP (1985) cross-section data might contribute to these differences. In ACSO, different sets of laboratory ozone absorption cross-section data (including their dependence on temperature) of the group of Reims (France) (Brion et al., 1993, 1998, 1992, 1995, abbreviated as BDM, 1995) and those of Serdyuchenko et al. (2014), and Gorshelev et al. (2014), (abbreviated as SER, 2014) were examined for use in atmospheric ozone measurements in the Huggins band. In conclusion, ACSO recommends: The spectroscopic data of BP (1985) should no longer be used for retrieval of atmospheric ozone measurements. For retrieval of ground-based instruments of total ozone and ozone profile measurements by the Umkehr method performed by Brewer and Dobson instruments data of SER (2014) are recommended to be used. When SER (2014) is used, the difference between total ozone measurements of Brewer and Dobson instruments are very small and the difference between Dobson measurements at AD and CD wavelength pairs are diminished

  11. Effective absorption cross sections and photolysis rates of anthropogenic and biogenic secondary organic aerosols

    NASA Astrophysics Data System (ADS)

    Romonosky, Dian E.; Ali, Nujhat N.; Saiduddin, Mariyah N.; Wu, Michael; Lee, Hyun Ji (Julie); Aiona, Paige K.; Nizkorodov, Sergey A.

    2016-04-01

    Mass absorption coefficient (MAC) values were measured for secondary organic aerosol (SOA) samples produced by flow tube ozonolysis and smog chamber photooxidation of a wide range of volatile organic compounds (VOC), specifically: α-pinene, β-pinene, β-myrcene, d-limonene, farnesene, guaiacol, imidazole, isoprene, linalool, ocimene, p-xylene, 1-methylpyrrole, and 2-methylpyrrole. Both low-NOx and high-NOx conditions were employed during the chamber photooxidation experiments. MAC values were converted into effective molecular absorption cross sections assuming an average molecular weight of 300 g/mol for SOA compounds. The upper limits for the effective photolysis rates of SOA compounds were calculated by assuming unity photolysis quantum yields and convoluting the absorption cross sections with a time-dependent solar spectral flux. A more realistic estimate for the photolysis rates relying on the quantum yield of acetone was also obtained. The results show that condensed-phase photolysis of SOA compounds can potentially occur with effective lifetimes ranging from minutes to days, suggesting that photolysis is an efficient and largely overlooked mechanism of SOA aging.

  12. Absorption cross section for the 5νOH stretch of acetic acid and peracetic acid

    NASA Astrophysics Data System (ADS)

    Begashaw, I. G.; Collingwood, M.; Bililign, S.

    2009-12-01

    We report measurements of the absorption cross sections for the vibrational O-H stretch (5νOH) overtone transitions in glacial acetic acid and peracetic acid. The photochemistry that results from overtone excitation has been shown to lead to OH radical production in molecules containing O-H (HNO3, H2O2). In addition the overtone excitation has been observed to result in light initiated chemical reaction. A Cavity ring-down spectroscopy (CRDS) instrument comprising of an Nd:YAG pumped dye laser and 620nm high reflectivity mirrors (R=99.995%) was used to measure the cross sections. The dye laser wavelength was calibrated using water vapor spectrum and the HITRAN 2008 database. The instrument’s minimum detectable absorption is αmin =4.5 *10-9cm-1 Hz-1/2 at 2σ noise level near the peak of the absorption feature. This measurement is the first for acetic acid at this excitation level. Preliminary results for acetic acid show the peak occurs near 615nm. Procedures for separating the monomer and dimer contribution will be presented. We would like to acknowledge support from NSF award #0803016 and NOAA-EPP award #NA06OAR4810187.

  13. Effective Absorption Cross-Sections in Porphyridium cruentum: Implications for Energy Transfer between Phycobilisomes and Photosystem II Reaction Centers.

    PubMed

    Ley, A C

    1984-02-01

    Effective absorption cross-sections for O(2) production by Porphyridium cruentum were measured at 546 and 596 nanometers. Although all photosystem II reaction centers are energetically coupled to phycobilisomes, any single phycobilisome acts as antenna for several photosystem II reaction centers. The cross-section measured in state I was 50% larger than that measured in state II.

  14. UV absorption cross sections between 290 and 380 nm of a series of furanaldehydes: Estimation of their photolysis lifetimes

    NASA Astrophysics Data System (ADS)

    Colmenar, Inmaculada; González, Sergio; Jiménez, Elena; Martín, Pilar; Salgado, Sagrario; Cabañas, Beatriz; Albaladejo, José

    2015-02-01

    Furanaldehydes, such as 2-furanaldehyde (also known as furfural), 3-furanaldehyde and 5-methyl-2-furanaldehyde, are aromatic aldehydes which can be present in the atmosphere as primary and secondary pollutants. The atmospheric removal initiated by sunlight for these species is not well-known in the solar actinic region (at λ > 290 nm), mainly due to the absence of data concerning the UV absorption cross sections (σλ) and photolysis frequencies (Ji(z,θ)). In this work σλ for the mentioned furanaldehydes have been determined between 290 and 380 nm at room temperature for the first time. Experiments were performed in an absorption jacketed Pyrex cell, employing a deuterium lamp as irradiation source and a CCD detector. The obtained absorption spectra exhibit absorption maxima around 320 nm with absolute absorption cross sections of 1.13, 0.75 and 1.14 × 10-19 cm2 molecule-1 for 2-furanaldehyde, 3-furanaldehyde and 5-methyl-2-furanaldehyde, respectively. The reported UV absorption cross sections were used to provide estimates of Ji(z,θ) and, therefore, estimates of the lifetime (τhν) due to this atmospheric removal process, under different solar radiation situations. Estimated τhν have been compared with the lifetimes due to the homogeneous reaction with the main diurnal tropospheric oxidants. The results obtained suggest that photolysis in the actinic region can be the main degradation pathway for these furanaldehydes when assuming a quantum yield (Φλ) of unity and the maximum solar actinic flux, while photolysis can compete with the reaction of OH radicals when assuming Φλ = 0.1. On the contrary, the removal of all three furanaldehydes by the reactions with OH radicals becomes more important than the UV photolysis under low solar actinic flux conditions independently of Φλ. If the emission source of these furanaldehydes also occurs during the nighttime NO3 radicals will dominate the elimination process of these species.

  15. Optical Absorption Cross Section of Individual Multi-Walled Carbon Nanotubes in the Visible Region.

    PubMed

    Shahzad, Muhammad Imran; Shahzad, Nadia; Tagliaferro, Alberto

    2016-01-01

    The aim of the present work is to determine the optical absorption cross section for visible radiation of various types of multiwall carbon nanotubes (MWCNTs) having different dimensions through macroscopic optical measurements. This is achieved by dispersing MWCNTs in polydimethylsiloxane (PDMS) and preparing composite films. Different percentages (0.0% to 1.5%) of each MWCNTs type were mixed into the PDMS matrix using high speed mechanical stirring (~1000 rpm) and ultrasonication (~37 kHz) to reach optimal dispersion. By using doctor blading technique, 100 µm thick uniform films were produced on glass. They were then thermally cured and detached from the glass to get flexible and self-standing films. Field-Emission Scanning Electron Microscope (FESEM) analysis of cryo-fractured composite samples was used to check the dispersion of MWCNTs in PDMS, while Raman spectroscopy and FTIR were employed to rule out possible structural changes of the polymer in the composite that would have altered its optical properties. Total and specular reflection and transmission spectra were measured for all films. The absorption coefficient, which represents the fractional absorption per unit length and is proportional to the concentration of absorbing sites (i.e., MWCNTs at photon energies upon which PDMS is non-absorbing), was extracted. For each MWCNTs type, the absorption cross section of an individual MWCNT was obtained from the slope of absorption coefficient versus MWCNTs number density curve. It was found to be related with MWCNT volume. This method can be applied to all other nanoparticles as far as they can be dispersed in a host transparent matrix. PMID:27398474

  16. Method and apparatus for determination of temperature, neutron absorption cross section and neutron moderating power

    DOEpatents

    Vagelatos, Nicholas; Steinman, Donald K.; John, Joseph; Young, Jack C.

    1981-01-01

    A nuclear method and apparatus determines the temperature of a medium by injecting fast neutrons into the medium and detecting returning slow neutrons in three first energy ranges by producing three respective detection signals. The detection signals are combined to produce three derived indicia each systematically related to the population of slow neutrons returning from the medium in a respective one of three second energy ranges, specifically exclusively epithermal neutrons, exclusively substantially all thermal neutrons and exclusively a portion of the thermal neutron spectrum. The derived indicia are compared with calibration indicia similarly systematically related to the population of slow neutrons in the same three second energy ranges returning from similarly irradiated calibration media for which the relationships temperature, neutron absorption cross section and neutron moderating power to such calibration indicia are known. The comparison indicates the temperature at which the calibration indicia correspond to the derived indicia and consequently the temperature of the medium. The neutron absorption cross section and moderating power of the medium can be identified at the same time.

  17. Measurement of the absolute vμ-CCQE cross section at the SciBooNE experiment

    SciTech Connect

    Aunion, Jose Luis Alcaraz

    2010-07-01

    This thesis presents the measurement of the charged current quasi-elastic (CCQE) neutrino-nucleon cross section at neutrino energies around 1 GeV. This measurement has two main physical motivations. On one hand, the neutrino-nucleon interactions at few GeV is a region where existing old data are sparse and with low statistics. The current measurement populates low energy regions with higher statistics and precision than previous experiments. On the other hand, the CCQE interaction is the most useful interaction in neutrino oscillation experiments. The CCQE channel is used to measure the initial and final neutrino fluxes in order to determine the neutrino fraction that disappeared. The neutrino oscillation experiments work at low neutrino energies, so precise measurement of CCQE interactions are essential for flux measurements. The main goal of this thesis is to measure the CCQE absolute neutrino cross section from the SciBooNE data. The SciBar Booster Neutrino Experiment (SciBooNE) is a neutrino and anti-neutrino scattering off experiment. The neutrino energy spectrum works at energies around 1 GeV. SciBooNE was running from June 8th 2007 to August 18th 2008. In that period, the experiment collected a total of 2.65 x 1020 protons on target (POT). This thesis has used full data collection in neutrino mode 0.99 x 1020 POT. A CCQE selection cut has been performed, achieving around 70% pure CCQE sample. A fit method has been exclusively developed to determine the absolute CCQE cross section, presenting results in a neutrino energy range from 0.2 to 2 GeV. The results are compatible with the NEUT predictions. The SciBooNE measurement has been compared with both Carbon (MiniBoonE) and deuterium (ANL and BNL) target experiments, showing a good agreement in both cases.

  18. Measurement of the absolute cross section for multiphoton ionization of atomic hydrogen at 248 nm

    SciTech Connect

    Kyrala, G.A.; Nichols, T.D.

    1990-01-01

    We present measurements of the absolute rates for multiphoton ionization of the ground state from atomic hydrogen by a linearly polarized, subpicosecond KrF laser pulse at a wavelength of 248 nm. A laser crossed atomic beam technique is used. The irradiance was varied from 3{times}10{sup 12} w/cm{sup 2} to 2{times}10{sup 14} w/cm{sup 2} and three above threshold ionization peaks were observed. The measured rate for total electron production is less than predicted by the numerical and perturbation calculations, but significantly higher than calculated by the Reiss and Keldysh methods. 21 refs., 7 figs.

  19. Two-photon absorption cross section measurement in the gamma band system of nitric oxide

    SciTech Connect

    Burris, J.F. Jr.

    1982-01-01

    A dye laser with a single longitudinal mode and very stable spatial mode structure has been constructed. With this laser system a four-wave mixing experiment was done in the gamma bands of nitric oxide using two photon resonance. Another four-wave mixing experiment was done in nitrogen using coherent anti-Stokes Raman scattering (CARS) and the two signals ratioed. Using accurately known values of the Raman scattering cross section, the third order susceptibility in NO was determined without needing to know the spatial and temporal properties of the dye lasers. From this susceptibility, the two photon absorption cross section was calculated with the explicit dependence of sigma/sup (2)/ upon X/sup (3)/ shown. For the R/sub 22/ + S/sub 12/(J'' = 9 1/2) (A/sup 2/..sigma..+(v' = 0) -- X/sup 2/..pi..(v'' = 0)) line, sigma/sup (2)/ = (1.0 +/- 0.6) x 10/sup -38/cm/sup 4/g(2/sub 1/-Vertical Barsub f/ is the normalized lineshape. Branching ratios for the A/sup 2/..sigma..+(v' = n) ..-->.. X/sup 2/..omega..(v'' = n)(n = o,...9) transitions of NO were also measured, Franck-Condon factors calculated and the lifetime of the A state determined.

  20. New and improved infrared absorption cross sections for chlorodifluoromethane (HCFC-22)

    NASA Astrophysics Data System (ADS)

    Harrison, Jeremy J.

    2016-06-01

    The most widely used hydrochlorofluorocarbon (HCFC) commercially since the 1930s has been chloro-difluoromethane, or HCFC-22, which has the undesirable effect of depleting stratospheric ozone. As this molecule is currently being phased out under the Montreal Protocol, monitoring its concentration profiles using infrared sounders crucially requires accurate laboratory spectroscopic data. This work describes new high-resolution infrared absorption cross sections of chlorodifluoromethane over the spectral range 730-1380 cm-1, determined from spectra recorded using a high-resolution Fourier transform spectrometer (Bruker IFS 125HR) and a 26 cm pathlength cell. Spectra of chlorodifluoromethane/dry synthetic air mixtures were recorded at resolutions between 0.01 and 0.03 cm-1 (calculated as 0.9/MOPD; MOPD denotes the maximum optical path difference) over a range of temperatures and pressures (7.5-762 Torr and 191-295 K) appropriate for atmospheric conditions. This new cross-section dataset improves upon the one currently available in the HITRAN (HIgh-resolution TRANsmission) and GEISA (Gestion et Etude des Informations Spectroscopiques Atmosphériques) databases; in particular it provides coverage over a wider range of pressures and temperatures, has more accurate wavenumber scales, more consistent integrated band intensities, improved signal-to-noise, is free of channel fringing, and additionally covers the ν2 and ν7 bands.

  1. New and improved infrared absorption cross sections for dichlorodifluoromethane (CFC-12)

    NASA Astrophysics Data System (ADS)

    Harrison, J. J.

    2015-03-01

    Despite its widespread commercial use throughout the twentieth century, primarily in the refrigeration industry, dichlorodifluoromethane (CFC-12) is now known to have the undesirable effect of depleting stratospheric ozone. As this long-lived molecule slowly degrades in the atmosphere, monitoring its vertical concentration profile using infrared sounders on satellite platforms crucially requires accurate laboratory spectroscopic data. This work describes new high-resolution infrared absorption cross sections of dichlorodifluoromethane over the spectral range 800-1270 cm-1, determined from spectra recorded using a high-resolution Fourier transform spectrometer (Bruker IFS 125HR) and a 26 cm-pathlength cell. Spectra of dichlorodifluoromethane/dry synthetic air mixtures were recorded at resolutions between 0.01 and 0.03 cm-1 (calculated as 0.9/MOPD; MOPD = maximum optical path difference) over a range of temperatures and pressures (7.5-761 Torr and 190-294 K) appropriate for atmospheric conditions. This new cross-section dataset improves upon the one currently available in the HITRAN and GEISA databases.

  2. New and improved infrared absorption cross sections for dichlorodifluoromethane (CFC-12)

    NASA Astrophysics Data System (ADS)

    Harrison, J. J.

    2015-08-01

    Despite its widespread commercial use throughout the twentieth century, primarily in the refrigeration industry, dichlorodifluoromethane (CFC-12) is now known to have the undesirable effect of depleting stratospheric ozone. As this long-lived molecule slowly degrades in the atmosphere, monitoring its vertical concentration profile using infrared sounders on satellite platforms crucially requires accurate laboratory spectroscopic data. This work describes new high-resolution infrared absorption cross sections of dichlorodifluoromethane over the spectral range 800-1270 cm-1, determined from spectra recorded using a high-resolution Fourier transform spectrometer (Bruker IFS 125HR) and a 26 cm pathlength cell. Spectra of dichlorodifluoromethane/dry synthetic air mixtures were recorded at resolutions between 0.01 and 0.03 cm-1 (calculated as 0.9/MOPD; MOPD = maximum optical path difference) over a range of temperatures and pressures (7.5-761 Torr and 190-294 K) appropriate for atmospheric conditions. This new cross-section dataset improves upon the one currently available in the HITRAN and GEISA databases.

  3. SO_2 Absorption Cross Sections and N_2 VUV Oscillator Strengths for Planetary Atmosphere Studies

    NASA Astrophysics Data System (ADS)

    Smith, Peter L.; Stark, G.; Rufus, J.; Pickering, J. C.; Cox, G.; Huber, K. P.

    1998-09-01

    The determination of the chemical composition of the atmosphere of Io from Hubble Space Telescope observations in the 190-220 nm wavelength region requires knowledge of the photoabsorption cross sections of SO_2 at temperatures ranging from about 110 K to 300 K. We are engaged in a laboratory program to measure SO_2 absorption cross sections with very high resolving power (lambda /delta lambda =~ 450,000) and at a range of temperatures appropriate to the Io atmosphere. Previous photoabsorption measurements, with lambda /delta lambda =~ 100,000, have been unable to resolve the very congested SO_2 spectrum, and, thus, to elucidate the temperature dependence of the cross sections. Our measurements are being performed at Imperial College, London, using an ultraviolet Fourier transform spectrometer. We will present our recently completed room temperature measurements of SO_2 cross sections in the 190-220 nm region and plans for extending these to ~ 195 K. Analyses of Voyager VUV occultation measurements of the N_2-rich atmospheres of Titan and Triton have been hampered by the lack of fundamental spectroscopic data for N_2, in particular, by the lack of reliable f-values and line widths for electronic bands of N_2 in the 80-100 nm wavelength region. We are continuing our program of measurements of band oscillator strengths for the many (approximately 100) N_2 bands between 80 and 100 nm. We report new f-values, derived from data obtained at the Photon Factory (Tsukuba, Japan) synchrotron radiation facility with lambda /delta lambda =~ 130,000, of 37 bands in the 80-86 nm region and 21 bands in the 90-95 nm region. We have also begun the compilation of a searchable archive of N_2 data on the World Wide Web; see http://cfa-www.harvard. edu/amp/data/n2/n2home.html. The archive, covering the spectroscopy of N_2 between 80 and 100 nm, will include published and unpublished (14) N_2, (14) N(15) N, and (15) N_2 line lists and spectroscopic identifications, excited state energy

  4. Scattered light and accuracy of the cross-section measurements of weak absorptions: Gas and liquid phase UV absorption cross sections of CH{sub 3}CFCl{sub 2}

    SciTech Connect

    Fahr, A.; Braun, W.; Kurylo, M.J.

    1993-11-20

    Ultraviolet absorption cross sections of CH{sub 3}CFCl{sub 2} (HCFC-141b) were determined in the gas phase (190-260 nm) and liquid phase (230-260 mm) at 298 K. The liquid phase absorption cross sections were then converted into accurate gas phase values using a previously described procedure. It has been demonstrated that scattered light from the shorter-wavelength region (as little as several parts per thousand) can seriously compromise the absorption cross-section measurement, particularly at longer wavelengths where cross sections are low, and can be a source of discrepancies in the cross sections of weakly absorbing halocarbons reported in the literature. A modeling procedure was developed to assess the effect of scattered light on the measured absorption cross section in these experiments, thereby permitting appropriate corrections to be made on the experimental values. Modeled and experimental results were found to be in good agreement. Experimental results from this study were compared with other available determinations and provide accurate input for calculating the atmospheric lifetime of HCFC-141b. 8 refs., 3 figs., 1 tab.

  5. Absorption and scattering cross-section extinction values of silver nanoparticles

    NASA Astrophysics Data System (ADS)

    Hlaing, May; Gebear-Eigzabher, Bellsabel; Roa, Azael; Marcano, Aristides; Radu, Daniela; Lai, Cheng-Yu

    2016-08-01

    We determine the extinction values of silver nanoparticles as a function of their diameter for three different wavelengths (405 nm, 532 nm, and 671 nm) from the values of absorbance and their photothermal lens response. We show that for particles of small diameters (<50 nm) the extinction grows as the cube of the diameter for all three wavelengths. For larger particles the extinction determined from absorbance exhibits a sixth order dependence on the diameters for 532 nm and 671 nm. This kind of behavior is typical of scattering processes that should dominate for large particles. For 405 nm the plasmonic resonant absorption dominates over scattering making difficult the observation of the sixth order dependence even for particles larger than 50 nm. The absorption cross-section measured by the photothermal method does not show the sixth order dependence. It depends on the cube of the particle's diameter for all nanoparticles confirming the scattering free character of this absorption technique and validating the results of the absorbance experiment.

  6. Absolute total electron scattering cross sections for N/sub 2/ between 0. 5 and 50 eV

    SciTech Connect

    Kennerly, R.E.

    1980-06-01

    Absolute total electron scattering cross sections for N/sub 2/ from 0.5 to 50 eV have been measured with an estimated uncertainty of +- 3% using a transmission time-of-flight method previously described. The results are compared to previous experimental results and to recent calculations. The positions of the /sup 2/Pi/sub g/ resonance peaks were determined with much greater accuracy ( +- 15 meV) than in previous transmission measurements. The structure reported by Golden (1966) below the /sup 2/Pi/sub g/ resonance was clearly not present, indicating that, if real, these features are not a property of the N/sub 2/ ground vibronic state. The shape resonance predicted at 11 eV by Dill and Dehmer (1977) was not seen, perhaps because it was too weakly manifested in the total cross section. A weak broad band centered at 25 eV may be interpreted as being due to a sigma/sub u/ shape resonance as predicted by Dehmer, Siegel, Welch, and Dill.

  7. Using DNA origami nanostructures to determine absolute cross sections for UV photon-induced DNA strand breakage.

    PubMed

    Vogel, Stefanie; Rackwitz, Jenny; Schürman, Robin; Prinz, Julia; Milosavljević, Aleksandar R; Réfrégiers, Matthieu; Giuliani, Alexandre; Bald, Ilko

    2015-11-19

    We have characterized ultraviolet (UV) photon-induced DNA strand break processes by determination of absolute cross sections for photoabsorption and for sequence-specific DNA single strand breakage induced by photons in an energy range from 6.50 to 8.94 eV. These represent the lowest-energy photons able to induce DNA strand breaks. Oligonucleotide targets are immobilized on a UV transparent substrate in controlled quantities through attachment to DNA origami templates. Photon-induced dissociation of single DNA strands is visualized and quantified using atomic force microscopy. The obtained quantum yields for strand breakage vary between 0.06 and 0.5, indicating highly efficient DNA strand breakage by UV photons, which is clearly dependent on the photon energy. Above the ionization threshold strand breakage becomes clearly the dominant form of DNA radiation damage, which is then also dependent on the nucleotide sequence.

  8. Absolute vibrational cross sections for 1-19 eV electron scattering from condensed tetrahydrofuran (THF)

    NASA Astrophysics Data System (ADS)

    Lemelin, V.; Bass, A. D.; Cloutier, P.; Sanche, L.

    2016-02-01

    Absolute cross sections (CSs) for vibrational excitation by 1-19 eV electrons impacting on condensed tetrahydrofuran (THF) were measured with a high-resolution electron energy loss spectrometer. Experiments were performed under ultra-high vacuum (3 × 10-11 Torr) at a temperature of about 20 K. The magnitudes of the vibrational CSs lie within the 10-17 cm2 range. Features observed near 4.5, 9.5, and 12.5 eV in the incident energy dependence of the CSs were compared to the results of theoretical calculations and other experiments on gas and solid-phase THF. These three resonances are attributed to the formation of shape or core-excited shape resonances. Another maximum observed around 2.5 eV is not found in the calculations but has been observed in gas-phase studies; it is attributed to the formation of a shape resonance.

  9. Studies on mass energy-absorption coefficients and effective atomic energy-absorption cross sections for carbohydrates

    NASA Astrophysics Data System (ADS)

    Ladhaf, Bibifatima M.; Pawar, Pravina P.

    2015-04-01

    We measured here the mass attenuation coefficients (μ/ρ) of carbohydrates, Esculine (C15H16O9), Sucrose (C12H22O11), Sorbitol (C6H14O6), D-Galactose (C6H12O6), Inositol (C6H12O6), D-Xylose (C5H10O5) covering the energy range from 122 keV up to 1330 keV photon energies by using gamma ray transmission method in a narrow beam good geometry set-up. The gamma-rays were detected using NaI(Tl) scintillation detection system with a resolution of 8.2% at 662 keV. The attenuation coefficient data were then used to obtain the total attenuation cross-section (σtot), molar extinction coefficients (ε), mass-energy absorption coefficients (μen/ρ) and effective (average) atomic energy-absorption cross section (σa,en) of the compounds. These values are found to be in good agreement with the theoretical values calculated based on XCOM data.

  10. On the photochemistry of IONO2: absorption cross section (240-370 nm) and photolysis product yields at 248 nm.

    PubMed

    Joseph, D M; Ashworth, S H; Plane, J M C

    2007-11-01

    The absolute absorption cross section of IONO(2) was measured by the pulsed photolysis at 193 nm of a NO(2)/CF(3)I mixture, followed by time-resolved Fourier transform spectroscopy in the near-UV. The resulting cross section at a temperature of 296 K over the wavelength range from 240 to 370 nm is given by log(10)(sigma(IONO(2))/cm(2) molecule(-1)) = 170.4 - 3.773 lambda + 2.965 x 10(-2)lambda(2)- 1.139 x 10(-4)lambda(3) + 2.144 x 10(-7)lambda(4)- 1.587 x 10(-10)lambda(5), where lambda is in nm; the cross section, with 2sigma uncertainty, ranges from (6.5 +/- 1.9) x 10(-18) cm(2) at 240 nm to (5 +/- 3) x 10(-19) cm(2) at 350 nm, and is significantly lower than a previous measurement [J. C. Mössinger, D. M. Rowley and R. A. Cox, Atmos. Chem. Phys., 2002, 2, 227]. The photolysis quantum yields for IO and NO(3) production at 248 nm were measured using laser induced fluorescence of IO at 445 nm, and cavity ring-down spectroscopy of NO(3) at 662 nm, yielding phi(IO)

  11. Absolute measurement of the photoionization cross section of atomic hydrogen with a shock tube for the extreme ultraviolet. [for astrophysical applications

    NASA Technical Reports Server (NTRS)

    Palenius, H. P.; Kohl, J. L.; Parkinson, W. H.

    1976-01-01

    The paper reports an experiment which is part of a program to measure the absolute values of the atomic photoionization cross sections of astrophysically abundant elements, particularly in stars and planetary atmospheres. An aerodynamic pressure-driven shock tube constructed from stainless steel with a quadratic cross section was used to measure the photoionization cross section of H I at 19 wavelength points from 910 to 609 A with experimental uncertainties between 7 and 20%. The shock tube was used to produce fully dissociated hydrogen and neon mixtures for the photoabsorption measurements.

  12. UV absorption cross-sections of phenol and naphthalene at temperatures up to 500 °C

    NASA Astrophysics Data System (ADS)

    Grosch, H.; Sárossy, Z.; Egsgaard, H.; Fateev, A.

    2015-05-01

    Absorption cross-sections and their temperature dependency, especially in the UV spectral range, of organic compounds such as phenol and naphthalene are of great interest in atmospheric research and high temperature processes. Due to the challenges of producing premixed gases of known concentration, it is difficult to determine absorption cross-sections in experiments, especially at higher temperatures. In this paper, a gas flow of nitrogen with a stable but unknown concentration of phenol or naphthalene is produced, and their UV absorption spectra between 195 and 350 nm have been measured at higher resolution than before (0.019 nm) in a hot gas flow cell at temperatures of up to 500 °C/773 K. A Petersen column is used to sample the organic compounds in the gas mixture to determine their concentration by GC-MS. The absorption cross-sections are calculated with the use of the Lambert-Beer law. Consequently, the absorption cross-sections for phenol and naphthalene at room temperature, 423 K, 573 K and 773 K in the range of 195-360 nm are presented in this study.

  13. Measurement of Absolute Excitation Cross Sections in Highly-Charged Ions Using Electron Energy Loss and Merged Beams

    NASA Technical Reports Server (NTRS)

    Chutjian, A.; Smith, Steven J.; Lozano, J.

    2002-01-01

    There is increasing emphasis during this decade on understanding energy balance and phenomena observed in high electron temperature plasmas. The UV spectral return from FUSE, the X-ray spectral return from the HETG on Chandra and the LETGS 011 XMM-Newton are just beginning. Line emissions are almost entirely from highly-charged ions (HCIs) of C, N, 0, Ne, Mg, S, Si, Ca, and Fe. The Constellation-X mission will provide X-ray spectroscopy up to photon energies of 0.12 nm (10 keV) where primary line emitters will be HCIs. A variety of atomic parameters are required to model the stellar and solar plasma. These include cross sections for excitation, ionization, charge-exchange, X-ray emission, direct and indirect recombination, lifetimes and branching ratios, and dependences on l, m mixing by external E and B fields. In almost all cases the atomic quantities are calculated, and few comparisons to experiment have been carried out. Collision strengths and Einstein A-values are required to convert the observed spectral intensities to electron temperatures and densities in the stellar plasma. The JPL electron energy-loss and merged beam approach has been used to measure absolute collision strengths in a number of ions, with critical comparison made to the best available theories.

  14. Absolute cross section for low-energy-electron damage to condensed macromolecules: A case study of DNA

    NASA Astrophysics Data System (ADS)

    Rezaee, Mohammad; Cloutier, Pierre; Bass, Andrew D.; Michaud, Marc; Hunting, Darel J.; Sanche, Léon

    2012-09-01

    Cross sections (CSs) for the interaction of low-energy electrons (LEE) with condensed macromolecules are essential parameters for accurate modeling of radiation-induced molecular decomposition and chemical synthesis. Electron irradiation of dry nanometer-scale macromolecular solid films has often been employed to measure CSs and other quantitative parameters for LEE interactions. Since such films have thicknesses comparable with electron thermalization distances, energy deposition varies throughout the film. Moreover, charge accumulation occurring inside the films shields a proportion of the macromolecules from electron irradiation. Such effects complicate the quantitative comparison of the CSs obtained in films of different thicknesses and limit the applicability of such measurements. Here, we develop a simple mathematical model, termed the molecular survival model, that employs a CS for a particular damage process together with an attenuation length related to the total CS, to investigate how a measured CS might be expected to vary with experimental conditions. As a case study, we measure the absolute CS for the formation of DNA strand breaks (SBs) by electron irradiation at 10 and 100 eV of lyophilized plasmid DNA films with thicknesses between 10 and 30 nm. The measurements are shown to depend strongly on the thickness and charging condition of the nanometer-scale films. Such behaviors are in accord with the model and support its validity. Via this analysis, the CS obtained for SB damage is nearly independent of film thickness and charging effects. In principle, this model can be adapted to provide absolute CSs for electron-induced damage or reactions occurring in other molecular solids across a wider range of experimental conditions.

  15. Measuring the Optical Absorption Cross-sections of Au-Ag Nanocages and Au Nanorods by Photoacoustic Imaging

    PubMed Central

    Cho, Eun Chul; Kim, Chulhong; Zhou, Fei; Cobley, Claire M.; Song, Kwang Hyun; Chen, Jingyi; Li, Zhi-Yuhan; Wang, Lihong V.; Xia, Younan

    2009-01-01

    This paper presents a method for measuring the optical absorption cross-sections (σa) of Au-Ag nanocages and Au nanorods. The method is based on photoacoustic (PA) imaging, where the detected signal is directly proportional to the absorption coefficient (μa) of the nanostructure. For each type of nanostructure, we firstly obtained μa from the PA signal by benchmarking against a linear calibration curve (PA signal vs. μa) derived from a set of methylene blue solutions with different concentrations. We then calculated σa by dividing the μa by the corresponding concentration of the Au nanostructure. Additonally, we obtained the extinction cross-section (σe, sum of absorption and scattering) from the extinction spectrum recorded using a conventional UV-vis-NIR spectrometer. From the measurements of σa and σe, we were able to easily derive both the absorption and scattering cross-sections for each type of gold nanostructure. The ratios of absorption to extinction obtained from experimental and theoretical approaches agreed well, demonstrating the potential use of this method in determining the optical absorption and scattering properties of gold nanostructures and other types of nanomaterials. PMID:19680423

  16. ABSORPTION CROSS SECTION OF GASEOUS ACETYLENE AT 85 K IN THE WAVELENGTH RANGE 110-155 nm

    SciTech Connect

    Cheng, Bing-Ming; Chen, Hui-Fen; Lu, Hsiao-Chi; Chen, Hong-Kai; Alam, M. S.; Chou, Sheng-Lung; Lin, Meng-Yeh

    2011-09-01

    Absorption spectra and absorption cross sections of gaseous acetylene, C{sub 2}H{sub 2}, at 298 and 85 K were measured in the wavelength range 110-155 nm with a slit-jet system coupled to a synchrotron as a source of vacuum ultraviolet light. Using published spectral parameters of C{sub 2}H{sub 2}, we simulated the absorption profile for the Rydberg transition to state 4R{sub 0} in the range 124.6-125.1 nm, according to which the temperature of the jet-expanded sample at stagnation pressure 200 Torr is 85 {+-} 5 K. Our cross sections of C{sub 2}H{sub 2} are applicable for determining properties sensitive to temperature for diagnostic work on Saturn and Titan.

  17. High-temperature measurements of VUV-absorption cross sections of CO2 and their application to exoplanets

    NASA Astrophysics Data System (ADS)

    Venot, O.; Fray, N.; Bénilan, Y.; Gazeau, M.-C.; Hébrard, E.; Larcher, G.; Schwell, M.; Dobrijevic, M.; Selsis, F.

    2013-03-01

    Context. Ultraviolet (UV) absorption cross sections are an essential ingredient of photochemical atmosphere models. Exoplanet searches have unveiled a large population of short-period objects with hot atmospheres, very different from what we find in our solar system. Transiting exoplanets whose atmospheres can now be studied by transit spectroscopy receive extremely strong UV fluxes and have typical temperatures ranging from 400 to 2500 K. At these temperatures, UV photolysis cross section data are severely lacking. Aims: Our goal is to provide high-temperature absorption cross sections and their temperature dependency for important atmospheric compounds. This study is dedicated to CO2, which is observed and photodissociated in exoplanet atmospheres. We also investigate the influence of these new data on the photochemistry of some exoplanets. Methods: We performed these measurements with synchrotron radiation as a tunable VUV light source for the 115-200 nm range at 300, 410, 480, and 550 K. In the 195-230 nm range, we used a deuterium lamp and a 1.5 m Jobin-Yvon spectrometer and we worked at seven temperatures between 465 and 800 K. We implemented the measured cross section into a 1D photochemical model. Results: For λ > 170 nm, the wavelength dependence of ln(σCO2(λ,T) × 1/(Qv(T))) can be parametrized with a linear law. Thus, we can interpolate σCO2(λ,T) at any temperature between 300 and 800 K. Within the studied range of temperature, the CO2 cross section can vary by more than two orders of magnitude. This, in particular, makes the absorption of CO2 significant up to wavelengths as high as 230 nm, while it is negligible above 200 nm at 300 K. Conclusions: The absorption cross section of CO2 is very sensitive to temperature, especially above 160 nm. The model predicts that accounting for this temperature dependency of CO2 cross section can affect the computed abundances of NH3, CO2, and CO by one order of magnitude in the atmospheres of hot Jupiter and hot

  18. Absolute partial electron impact ionization cross sections of Xe from threshold up to 180 eV

    SciTech Connect

    Stephan, K.; Maerk, T.D.

    1984-10-01

    Partial electron ionization cross section ratios and functions of Xe were determined in the low energy regime (< or =180 eV) using a refined mass spectrometric technique. The experimental results are compared with previous measurements and calculations.

  19. Absolute cascade-free cross-sections for the 2S to 2P transition in Zn(+) using electron-energy-loss and merged-beams methods

    NASA Technical Reports Server (NTRS)

    Smith, Steven J.; Man, K.-F.; Chutjian, A.; Mawhorter, R. J.; Williams, I. D.

    1991-01-01

    Absolute cascade-free excitation cross-sections in an ion have been measured for the resonance 2S to 2P transition in Zn(+) using electron-energy-loss and merged electron-ion beams methods. Measurements were carried out at electron energies of below threshold to 6 times threshold. Comparisons are made with 2-, 5-, and 15-state close-coupling and distorted-wave theories. There is good agreement between experiment and the 15-state close-coupling cross-sections over the energy range of the calculations.

  20. New High-Resolution Absorption Cross-Section Measurements of HCFC-142B in the Mid-Ir

    NASA Astrophysics Data System (ADS)

    Le Bris, Karine; Strong, Kimberly; Melo, Stella

    2009-06-01

    HCFC-142b (1-chloro-1,1-difluoroethane) is a temporary substitute for ozone-depleting chlorofluorocarbons (CFCs). However, due to its high absorption cross-sections in the mid-IR, HCFC-142b is also a highly potent greenhouse gas, now detectable from space by satellite missions. So far, the accuracy of the retrieval has been limited by the lack of reference data in a range of temperatures compatible with atmospheric observations. We present new absorption cross section measurements of HCFC-142b at high-resolution (0.02 cm^{-1}) from 223 K to 283 K in the 600 cm^{-1}- 4000 cm^{-1} spectral window. The composite spectra are calculated for each temperature from a set of acquisitions at different pressures by Fourier transform spectroscopy.

  1. High resolution absorption cross sections for the A2Pi-X2Pi system of ClO

    NASA Technical Reports Server (NTRS)

    Wine, P. H.; Ravishankara, A. R.; Philen, D. L.; Davis, D. D.; Watson, R. T.

    1977-01-01

    High-resolution ultraviolet absorption cross-sections for the ClO molecule are obtained, with the aim of facilitating studies of ozone depletion resulting from the injection of chlorofluorocarbons into the atmosphere. The spectroscopic analysis, which involves a frequency-doubled tunable dye laser with a bandwidth of 0.015 A, is described. Studies of the rotational lines of the ClO A 2Pi 3/2-X2Pi 3/2 9-10 band were conducted. Peak cross-sections for the P and R lines of the 9-0 band are found to be 10.0, 9.6, 8.6, 10.6, 10.3, and 9.2 times ten to the negative seventeenth power cm squared, with estimated accuracy of plus or minus 25%. Problems in distinguishing between Cl-35 and Cl-37 absorption are also considered.

  2. Absolute Photoionization Cross Section with an Ultra-high Energy Resolution for Ne in the Region of 1s Rydberg States

    SciTech Connect

    Kato, M.; Morishita, Y.; Suzuki, I. H.; Saito, N.; Oura, M.; Yamaoka, H.; Okada, K.; Matsudo, T.; Gejo, T.

    2007-01-19

    The high-resolution absolute photoabsorption cross section with an absolute photon energy scale for Ne in the energy region of 864-872 eV (1s-1np Rydberg states) has been measured using a multi-electrode ionization chamber and monochromatized synchrotron radiation. The natural lifetime width of Ne 1s-13p resonance state has been obtained to be 252 {+-} 5 meV. The Ne+ (1s-1) ionization potential is determined to be 870.16 {+-} 0.04 eV by using the Rydberg formula. These absolute values are supposed to be more reliable than those previously reported.

  3. Absolute vibrational excitation cross sections for slow-electron (1-18 eV) scattering in solid H2O

    NASA Astrophysics Data System (ADS)

    Michaud, M.; Sanche, L.

    1987-11-01

    High-resolution vibrational electron-energy-loss spectra of amorphous ice films condensed at 14 K are reported for the incident-energy range 1-18 eV. Absolute electron scattering cross sections for elastic collisions, individual vibrational excitations, and the sum of electronic transitions are obtained by performing a two-stream multiple-scattering analysis of the spectra. The various features found in the energy-dependent cross sections are discussed, whenever possible, by comparison with data and mechanisms (e.g., transient anion formation) well established in the gas phase. Quantum-interference effects introduced implicitly in the cross sections by the classical analysis are discussed within the first Born approximation for electron-multiple-site scattering.

  4. Reengineering the optical absorption cross-section of photosynthetic reaction centers.

    PubMed

    Dutta, Palash K; Lin, Su; Loskutov, Andrey; Levenberg, Symon; Jun, Daniel; Saer, Rafael; Beatty, J Thomas; Liu, Yan; Yan, Hao; Woodbury, Neal W

    2014-03-26

    Engineered cysteine residues near the primary electron donor (P) of the reaction center from the purple photosynthetic bacterium Rhodobacter sphaeroides were covalently conjugated to each of several dye molecules in order to explore the geometric design and spectral requirements for energy transfer between an artificial antenna system and the reaction center. An average of 2.5 fluorescent dye molecules were attached at specific locations near P. The enhanced absorbance cross-section afforded by conjugation of Alexa Fluor 660 dyes resulted in a 2.2-fold increase in the formation of reaction center charge-separated state upon intensity-limited excitation at 650 nm. The effective increase in absorbance cross-section resulting from the conjugation of two other dyes, Alexa Fluor 647 and Alexa Fluor 750, was also investigated. The key parameters that dictate the efficiency of dye-to-reaction center energy transfer and subsequent charge separation were examined using both steady-state and time-resolved fluorescence spectroscopy as well as transient absorbance spectroscopy techniques. An understanding of these parameters is an important first step toward developing more complex model light-harvesting systems integrated with reaction centers. PMID:24568563

  5. Measured Absolute Cross Section of Charge Transfer in H + H2+ at Low Energy: Signature of vi = 2 and Trajectory Effects

    NASA Astrophysics Data System (ADS)

    Strom, R. A.; Bacani, K. G.; Chi, R. M.; Heczko, S. L.; Singh, B. N.; Tobar, J. A.; Vassantachart, A. K.; Andrianarijaona, V. M.; Seely, D. G.; Havener, C. C.

    2015-04-01

    Measurements of absolute cross sections of charge transfer (CT) in H + H2+--> H+ + H2 were conducted at the merged-beam apparatus at Oak Ridge National Laboratory (ORNL) in Oak Ridge, Tennessee, which can reliably create and access collision energies as low as 0.1 eV/u. The measured absolute cross section shows evidence of trajectory effects at low energy. Also, the comparison to state-to-state calculations (PRA 67 022708 (2003) suggests a strong contribution from vi = 2 of the H2+that are produced by the electron cyclotron resonance ion source. The data analysis will be presented here. Research supported by the NASA Solar & Heliospheric Physics Program NNH07ZDA001N, the Office of Fusion Energy Sciences and the Division of Chemical Sciences, Geosciences, and Biosciences, Office of Basic Energy Sciences of the U.S. Department of Energy, the National Science Foundation through Grant No. PHY-1068877.

  6. High resolution absorption cross sections in the transmission window region of the Schumann-Runge bands and Herzberg continuum of O2

    NASA Technical Reports Server (NTRS)

    Yoshino, K.; Esmond, J. R.; Cheung, A. S.-C.; Freeman, D. E.; Parkinson, W. H.

    1992-01-01

    Results are presented on measurements, conducted in the wavelength region 180-195 nm, and at different pressures of oxygen (between 2.5-760 torr) in order to separate the pressure-dependent absorption from the main cross sections, of the absorption cross sections of the Schumann-Runge bands in the window region between the rotational lines of S-R bands of O2. The present cross sections supersede the earlier published cross sections (Yoshino et al., 1983). The combined cross sections are presented graphically; they are available at wavenumber intervals of about 0.1/cm from the National Space Science Data Center. The Herzberg continuum cross sections are derived after subtracting calculated contributions from the Schumann-Runge bands. These are significantly smaller than any previous measurements.

  7. Measurements of the absorption cross section of (13)CHO(13)CHO at visible wavelengths and application to DOAS retrievals.

    PubMed

    Goss, Natasha R; Waxman, Eleanor M; Coburn, Sean C; Koenig, Theodore K; Thalman, Ryan; Dommen, Josef; Hannigan, James W; Tyndall, Geoffrey S; Volkamer, Rainer

    2015-05-14

    The trace gas glyoxal (CHOCHO) forms from the atmospheric oxidation of hydrocarbons and is a precursor to secondary organic aerosol. We have measured the absorption cross section of disubstituted (13)CHO(13)CHO ((13)C glyoxal) at moderately high (1 cm(-1)) optical resolution between 21 280 and 23 260 cm(-1) (430-470 nm). The isotopic shifts in the position of absorption features were found to be largest near 455 nm (Δν = 14 cm(-1); Δλ = 0.29 nm), whereas no significant shifts were observed near 440 nm (Δν < 0.5 cm(-1); Δλ < 0.01 nm). These shifts are used to investigate the selective detection of (12)C glyoxal (natural isotope abundance) and (13)C glyoxal by in situ cavity enhanced differential optical absorption spectroscopy (CE-DOAS) in a series of sensitivity tests using synthetic spectra, and laboratory measurements of mixtures containing (12)C and (13)C glyoxal, nitrogen dioxide, and other interfering absorbers. We find the changes in apparent spectral band shapes remain significant at the moderately high optical resolution typical of CE-DOAS (0.55 nm fwhm). CE-DOAS allows for the selective online detection of both isotopes with detection limits of ∼200 pptv (1 pptv = 10(-12) volume mixing ratio), and sensitivity toward total glyoxal of few pptv. The (13)C absorption cross section is available for download from the Supporting Information. PMID:25551419

  8. Non-mass dependent photodissociation rates of ozone isotopologues from ab-initio absorption cross sections and experimental actinic flux

    NASA Astrophysics Data System (ADS)

    Ndengué, Steve; Jost, Rémy; Gatti, Fabien; Schinke, Reinhard; Madronich, Sasha

    2010-05-01

    The absorption cross sections (XSs) of eighteen isotopologues of the ozone molecule have been calculated in the range of the Chappuis-Huggins-Hartley bands: 15000-55000 cm-1 with special emphasis to those of atmospheric interest: symmetric 16O3, 16O17O16O, and 16O18O16O and asymmetric 17O16O2 and 18O16O2. We have used the MCTDH code which is based on the time propagation of the X(0,0,0) ground state initial wavepacket on the excited state PESs. The XSs have been obtained as the Fourier transform of the autocorrelation function of this wavepacket. The calculations have been performed only for zero total angular momentum and the rotational structure has been modeled numerically. The isotopologue dependence of the overall XSs has been characterized differently in each of the three bands: in the Chappuis band (15000-27000 cm-1) and in the Hartley band (33000-55000 cm-1), the XSs are weakly structured and the isotopologue dependence is globally weak. In contrast, in the Huggins band (27000 to 33000 cm-1) the different XSs are highly structured and their peaks are significantly shifted from those of the 16O3 absolute XS which has been chosen as reference. The Hartley band of each isotopologue can be approximated by a bell shape envelop modeled by a modified Gaussian depending on only four parameters: amplitude, centre, width and asymmetry. The isotopologue dependence of the Hartley band resumes only into tiny differences between these parameters. The dependence of the Chappuis band is also weak. The isotopologue shifts of peaks in the Huggins bands induce a significant dependence of the photodissociation rates because these rates are the integral of the product of the XS by the actinic flux. Below 30 km, the actinic flux displays a tremendous attenuation in the range of the Hartley band because the solar flux is strongly absorbed by the stratospheric ozone, almost exclusively by the 16O3 isotopologue. This implies two consequences: a) the actinic flux reproduces

  9. Off-Resonant Two-Photon Absorption Cross-Section Enhancement of an Organic Chromophore on Gold Nanorods

    PubMed Central

    Sivapalan, Sean T.; Vella, Jarrett H.; Yang, Timothy K.; Dalton, Matthew J.; Haley, Joy E.; Cooper, Thomas M.; Urbas, Augustine M.; Tan, Loon-Seng; Murphy, Catherine J.

    2013-01-01

    Surface-plasmon-initiated interference effects of polyelectrolyte-coated gold nanorods on the two-photon absorption of an organic chromophore were investigated. With polyelectrolyte bearing gold nanorods of 2,4,6 and 8 layers, the role of the plasmonic fields as function of distance on such effects was examined. An unusual distance dependence was found: enhancements in the two-photon cross-section were at a minimum at an intermediate distance, then rose again at a further distance. The observed values of enhancement were compared to theoretical predictions using finite element analysis and showed good agreementdue to constructive and destructive interference effects. PMID:23687561

  10. EMPIRICAL LINE LISTS AND ABSORPTION CROSS SECTIONS FOR METHANE AT HIGH TEMPERATURES

    SciTech Connect

    Hargreaves, R. J.; Bernath, P. F.; Dulick, M.; Bailey, J.

    2015-11-01

    Hot methane is found in many “cool” sub-stellar astronomical sources including brown dwarfs and exoplanets, as well as in combustion environments on Earth. We report on the first high-resolution laboratory absorption spectra of hot methane at temperatures up to 1200 K. Our observations are compared to the latest theoretical spectral predictions and recent brown dwarf spectra. The expectation that millions of weak absorption lines combine to form a continuum, not seen at room temperature, is confirmed. Our high-resolution transmittance spectra account for both the emission and absorption of methane at elevated temperatures. From these spectra, we obtain an empirical line list and continuum that is able to account for the absorption of methane in high temperature environments at both high and low resolution. Great advances have recently been made in the theoretical prediction of hot methane, and our experimental measurements highlight the progress made and the problems that still remain.

  11. Tracing multiple scattering patterns in absolute (e,2e) cross sections for H{sub 2} and He over a 4{pi} solid angle

    SciTech Connect

    Ren, X.; Senftleben, A.; Pflueger, T.; Dorn, A.; Ullrich, J.; Colgan, J.; Pindzola, M. S.; Al-Hagan, O.; Madison, D. H.; Bray, I.; Fursa, D. V.

    2010-09-15

    Absolutely normalized (e,2e) measurements for H{sub 2} and He covering the full solid angle of one ejected electron are presented for 16 eV sum energy of both final state continuum electrons. For both targets rich cross-section structures in addition to the binary and recoil lobes are identified and studied as a function of the fixed electron's emission angle and the energy sharing among both electrons. For H{sub 2} their behavior is consistent with multiple scattering of the projectile as discussed before [Al-Hagan et al., Nature Phys. 5, 59 (2009)]. For He the binary and recoil lobes are significantly larger than for H{sub 2} and partly cover the multiple scattering structures. To highlight these patterns we propose a alternative representation of the triply differential cross section. Nonperturbative calculations are in good agreement with the He results and show discrepancies for H{sub 2} in the recoil peak region. For H{sub 2} a perturbative approach reasonably reproduces the cross-section shape but deviates in absolute magnitude.

  12. Benchmark experiment for electron-impact ionization of argon: Absolute triple-differential cross sections via three-dimensional electron emission images

    SciTech Connect

    Ren Xueguang; Senftleben, Arne; Pflueger, Thomas; Dorn, Alexander; Ullrich, Joachim; Bartschat, Klaus

    2011-05-15

    Single ionization of argon by 195-eV electron impact is studied in an experiment, where the absolute triple-differential cross sections are presented as three-dimensional electron emission images for a series of kinematic conditions. Thereby a comprehensive set of experimental data for electron-impact ionization of a many-electron system is produced to provide a benchmark for comparison with theoretical predictions. Theoretical models using a hybrid first-order and second-order distorted-wave Born plus R-matrix approach are employed to compare their predictions with the experimental data. While the relative shape of the calculated cross section is generally in reasonable agreement with experiment, the magnitude appears to be the most significant problem with the theoretical treatment for the conditions studied in the present work. This suggests that the most significant challenge in the further development of theory for this process may lie in the reproduction of the absolute scale rather than the angular dependence of the cross section.

  13. Investigation of the formaldehyde differential absorption cross section at high and low spectral resolution in the simulation chamber SAPHIR

    NASA Astrophysics Data System (ADS)

    Brauers, T.; Bossmeyer, J.; Dorn, H.-P.; Schlosser, E.; Tillmann, R.; Wegener, R.; Wahner, A.

    2007-07-01

    The results from a simulation chamber study on the formaldehyde (HCHO) absorption cross section in the UV spectral region are presented. We performed 4 experiments at ambient HCHO concentrations with simultaneous measurements of two DOAS instruments in the atmosphere simulation chamber SAPHIR in Jülich. The two instruments differ in their spectral resolution, one working at 0.2 nm (broad-band, BB-DOAS), the other at 2.7 pm (high-resolution, HR-DOAS). Both instruments use dedicated multi reflection cells to achieve long light path lengths of 960 m and 2240 m, respectively, inside the chamber. During two experiments HCHO was injected into the clean chamber by thermolysis of well defined amounts of para-formaldehyde reaching mixing rations of 30 ppbV at maximum. The HCHO concentration calculated from the injection and the chamber volume agrees with the BB-DOAS measured value when the absorption cross section of Meller and Moortgat (2000) and the temperature coefficient of Cantrell (1990) were used for data evaluation. In two further experiments we produced HCHO in-situ from the ozone + ethene reaction which was intended to provide an independent way of HCHO calibration through the measurements of ozone and ethene. However, we found an unexpected deviation from the current understanding of the ozone + ethene reaction when CO was added to suppress possible oxidation of ethene by OH radicals. The reaction of the Criegee intermediate with CO could be 240 times slower than currently assumed. Based on the BB-DOAS measurements we could deduce a high-resolution cross section for HCHO which was not measured directly so far.

  14. Absolute fragmentation cross sections in atom-molecule collisions: Scaling laws for non-statistical fragmentation of polycyclic aromatic hydrocarbon molecules

    SciTech Connect

    Chen, T.; Gatchell, M.; Stockett, M. H.; Alexander, J. D.; Schmidt, H. T.; Cederquist, H.; Zettergren, H.; Zhang, Y.; Rousseau, P.; Maclot, S.; Delaunay, R.; Adoui, L.; Domaracka, A.; Huber, B. A.

    2014-06-14

    We present scaling laws for absolute cross sections for non-statistical fragmentation in collisions between Polycyclic Aromatic Hydrocarbons (PAH/PAH{sup +}) and hydrogen or helium atoms with kinetic energies ranging from 50 eV to 10 keV. Further, we calculate the total fragmentation cross sections (including statistical fragmentation) for 110 eV PAH/PAH{sup +} + He collisions, and show that they compare well with experimental results. We demonstrate that non-statistical fragmentation becomes dominant for large PAHs and that it yields highly reactive fragments forming strong covalent bonds with atoms (H and N) and molecules (C{sub 6}H{sub 5}). Thus nonstatistical fragmentation may be an effective initial step in the formation of, e.g., Polycyclic Aromatic Nitrogen Heterocycles (PANHs). This relates to recent discussions on the evolution of PAHNs in space and the reactivities of defect graphene structures.

  15. Computation of the ultraviolet absorption and electron inelastic scattering cross section of multishell fullerenes

    NASA Astrophysics Data System (ADS)

    Lucas, A. A.; Henrard, L.; Lambin, Ph.

    1994-01-01

    We develop a model in which the ultraviolet dielectric tensor of planar graphite is transported to the spherical geometry of a nanoscale multishell fullerene with a central cavity. This is accomplished by assigning to every point of the multishell fullerene a local dielectric tensor identical to that of graphite with its c axis aligned along the local radial direction. The dynamic, multipolar polarizabilities of the model fullerene are obtained from the exact solutions of the nonretarded Maxwell equations. The ultraviolet absorption spectrum of the hollow fullerene is calculated as a function of the ratio of the inner and outer radii. Comparisons of the theoretical absorption spectra with the 2175-Å interstellar extinction hump and with recent absorption measurements for synthetic multishell fullerenes indicate that the dielectric properties of graphite are qualitatively adequate for understanding the optical data. However, difficulties persist with both the astrophysical and laboratory absorption peaks which lead us to consider the possible role of multishell fullerene aggregation into small or large clusters. It is found that the effect of clustering is important and reduces but does not remove completely the quantitative difficulties of the graphitic multishell model. Finally theoretical electron-energy-loss spectra (EELS) of these structures with an empty or filled cavity are calculated from the multipolar polarizabilities of the model. The results indicate that spatially resolved EELS measurements should be ideally suited to study the dielectric properties of individual multishell fullerenes and to ascertain to what extent they differ from those of planar graphite.

  16. Absorption enhancement by matching the cross-section of plasmonic nanowires to the field structure of tightly focused beams.

    PubMed

    Normatov, Alexander; Spektor, Boris; Leviatan, Yehuda; Shamir, Joseph

    2011-04-25

    Nanostructured materials, designed for enhanced light absorption, are receiving increased scientific and technological interest. In this paper we propose a physical criterion for designing the cross-sectional shape of plasmonic nanowires for improved absorption of a given tightly focused illumination. The idea is to design a shape which increases the matching between the nanowire plasmon resonance field and the incident field. As examples, we design nanowire shapes for two illumination cases: a tightly focused plane wave and a tightly focused beam containing a line singularity. We show that properly shaped and positioned silver nanowires that occupy a relatively small portion of the beam-waist area can absorb up to 65% of the total power of the incident beam. PMID:21643100

  17. Absolute state-selected and state-to-state total cross sections for the Ar sup + ( sup 2 P sub 3/2,1/2 )+CO reactions

    SciTech Connect

    Flesch, G.D.; Nourbakhsh, S.; Ng, C.Y. . Ames Laboratory Iowa State University, Ames, Iowa . Department of Chemistry)

    1991-09-01

    Absolute spin--orbit state-selected total cross sections for the reactions, Ar{sup +}({sup 2}{ital P}{sub 3/2,1/2})+CO{r arrow}CO{sup +}+Ar (reaction (1)), C{sup +}+O+Ar (reaction (2)), O{sup +}+C+Ar (reaction (3)), and ArC{sup +}+O (reaction (4)), have been measured in the center-of-mass collision energy ({ital E}{sub c.m.}) range of 0.04--123.5 eV. Absolute spin--orbit state transition total cross sections for the Ar{sup +}({sup 2}{ital P}{sub 3/2,1/2})+CO reactions at {ital E}{sub c.m.} have also been obtained. The appearance energies (AE) for C{sup +}({ital E}{sub c.m.}=6.6{plus minus}0.4 eV) and O{sup +}({ital E}{sub c.m.}=8.6{plus minus}0.4 eV) are in agreement with the thermochemical thresholds for reactions (2) and (3), respectively. The observed AE for reaction (4) yields a lower bound of 0.5 eV for the ArC{sup +} bond dissociation energy. The kinetic energy dependence of the absolute cross sections and the retarding potential analysis of the product ions support that ArC{sup +}, C{sup +}, and O{sup +} are formed via a charge transfer predissociation mechanism, similar to that proposed to be responsible for the formation of O{sup +} (N{sup +}) and ArO{sup +} (ArN{sup +}) in the collisions of Ar{sup +}({sup 2}{ital P}{sub 3/2,1/2})+O{sub 2}(N{sub 2}).

  18. Quantitative infrared absorption cross-sections of isoprene for atmospheric measurements

    DOE PAGES

    Brauer, C. S.; Blake, T. A.; Guenther, A. B.; Sams, R. L.; Johnson, T. J.

    2014-04-25

    Isoprene (C5H8, 2-methyl-1,3-butadiene) is a volatile organic compound (VOC) that is one of the primary contributors to annual global VOC emissions. Produced by vegetation as well as anthropogenic sources, the OH- and O3-initiated oxidations of isoprene are a major source of atmospheric oxygenated organics. Few quantitative infrared studies have been reported for isoprene, however, limiting the ability to quantify isoprene emissions via stand-off infrared or in situ detection. We thus report absorption coefficients and integrated band intensities for isoprene in the 600–6500 cm−1 region. The pressure-broadened (1 atmosphere N2) spectra were recorded at 278, 298 and 323 K in amore » 19.94 cm path length cell at 0.112 cm−1 resolution, using a Bruker 66v FTIR. Composite spectra are derived from a minimum of seven isoprene sample pressures at each temperature and the number densities are normalized to 296 K and 1 atmosphere.« less

  19. PSI-LHCI of Chlamydomonas reinhardtii: Increasing the absorption cross section without losing efficiency.

    PubMed

    Le Quiniou, Clotilde; Tian, Lijin; Drop, Bartlomiej; Wientjes, Emilie; van Stokkum, Ivo H M; van Oort, Bart; Croce, Roberta

    2015-01-01

    Photosystem I (PSI) is an essential component of photosynthetic membranes. Despite the high sequence and structural homologies, its absorption properties differ substantially in algae, plants and cyanobacteria. In particular it is characterized by the presence of low-energy chlorophylls (red forms), the number and the energy of which vary in different organisms. The PSI-LHCI (PSI-light harvesting complex I) complex of the green alga Chlamydomonas reinhardtii (C.r.) is significantly larger than that of plants, containing five additional light-harvesting complexes (together binding≈65 chlorophylls), and contains red forms with higher energy than plants. To understand how these differences influence excitation energy transfer and trapping in the system, we studied two PSI-LHCI C.r. particles, differing in antenna size and red-form content, using time-resolved fluorescence and compared them to plant PSI-LHCI. The excited state kinetics in C.r. shows the same average lifetime (50 ps) as in plants suggesting that the effect of antenna enlargement is compensated by higher energy red forms. The system equilibrates very fast, indicating that all Lhcas are well-connected, despite their long distance to the core. The differences between C.r. PSI-LHCI with and without Lhca2 and Lhca9 show that these Lhcas bind red forms, although not the red-most. The red-most forms are in (or functionally close to) other Lhcas and slow down the trapping, but hardly affect the quantum efficiency, which remains as high as 97% even in a complex that contains 235 chlorophylls. PMID:25681242

  20. PSI-LHCI of Chlamydomonas reinhardtii: Increasing the absorption cross section without losing efficiency.

    PubMed

    Le Quiniou, Clotilde; Tian, Lijin; Drop, Bartlomiej; Wientjes, Emilie; van Stokkum, Ivo H M; van Oort, Bart; Croce, Roberta

    2015-01-01

    Photosystem I (PSI) is an essential component of photosynthetic membranes. Despite the high sequence and structural homologies, its absorption properties differ substantially in algae, plants and cyanobacteria. In particular it is characterized by the presence of low-energy chlorophylls (red forms), the number and the energy of which vary in different organisms. The PSI-LHCI (PSI-light harvesting complex I) complex of the green alga Chlamydomonas reinhardtii (C.r.) is significantly larger than that of plants, containing five additional light-harvesting complexes (together binding≈65 chlorophylls), and contains red forms with higher energy than plants. To understand how these differences influence excitation energy transfer and trapping in the system, we studied two PSI-LHCI C.r. particles, differing in antenna size and red-form content, using time-resolved fluorescence and compared them to plant PSI-LHCI. The excited state kinetics in C.r. shows the same average lifetime (50 ps) as in plants suggesting that the effect of antenna enlargement is compensated by higher energy red forms. The system equilibrates very fast, indicating that all Lhcas are well-connected, despite their long distance to the core. The differences between C.r. PSI-LHCI with and without Lhca2 and Lhca9 show that these Lhcas bind red forms, although not the red-most. The red-most forms are in (or functionally close to) other Lhcas and slow down the trapping, but hardly affect the quantum efficiency, which remains as high as 97% even in a complex that contains 235 chlorophylls.

  1. Apparent PS II absorption cross-section and estimation of mean PAR in optically thin and dense suspensions of Chlorella.

    PubMed

    Klughammer, Christof; Schreiber, Ulrich

    2015-01-01

    Theoretical prediction of effective mean PAR in optically dense samples is complicated by various optical effects, including light scattering and reflections. Direct information on the mean rate of photon absorption by PS II is provided by the kinetics of the fluorescence rise induced upon onset of strong actinic illumination (O-I1 rise). A recently introduced kinetic multi-color PAM fluorometer was applied to study the relationship between initial slope and cell density in the relatively simple model system of suspensions of Chlorella. Use of a curve fitting routine was made which was originally developed for assessment of the wavelength-dependent absorption cross-section of PS II, σ II(λ), in dilute suspensions. The model underlying analysis of the O-I1 rise kinetics is outlined and data on the relationship between fitted values of σ II(λ) and PAR in dilute samples are presented. With increasing cell density, lowering of apparent cross-section, <σ>(λ), with respect to σ II(λ), relates to a decrease of effective mean PAR, (λ), relative to incident PAR(λ). When ML and AL are applied in the same direction, the decline of <σ>(λ)/σ II(λ) with increasing optical density is less steep than that of the theoretically predicted (λ)/PAR(λ). It approaches a value of 0.5 when the same colors of ML and AL are used, in agreement with theory. These observations open the way for estimating mean PAR in optically dense samples via measurements of <σ>(λ)/σ II(λ)).

  2. The application of reduced absorption cross section on the identification of the compounds with similar function-groups

    NASA Astrophysics Data System (ADS)

    Yu, Fei; Zuo, Jian; Mu, Kai-jun; Zhang, Zhen-wei; Zhang, Liang-liang; Zhang, Lei-wei; Zhang, Cun-lin

    2013-08-01

    Terahertz spectroscopy is a powerful tool for materials investigation. The low frequency vibrations were usually investigated by means of absorption coefficient regardless of the refractive index. It leads to the disregard of some inherent low-frequency vibrational information of the chemical compounds. Moreover, due to the scattering inside the sample, there are some distortions of the absorption features, so that the absorption dependent material identification is not valid enough. Here, a statistical parameter named reduced absorption cross section (RACS) is introduced. This can not only help us investigate the molecular dynamics but also distinguish one chemical compound with another which has similar function-groups. Experiments are carried out on L-Tyrosine and L-Phenylalanine and the different mass ratios of their mixtures as an example of the application of RACS. The results come out that the RACS spectrum of L-Tyrosine and L-Phenylalanine reserve the spectral fingerprint information of absorption spectrum. The log plot of RACSs of the two amino acids show power-law behavior σR(~ν) ~ (ν~α), and there is a linear relation between the wavenumber and the RACS in the double logarithmic plot. The exponents α, at the same time, are the slopes of the RACS curves in the double logarithmic plot. The big differences of the exponents α between the two amino acids and their mixtures can be seen visually from the slopes of the RACS curves. So we can use RACS analytical method to distinguish some complex compounds with similar function-groups and mixtures from another which has similar absorption peaks in THz region.

  3. Temperature dependence of the gas and liquid phase ultraviolet absorption cross sections of HCFC-123 (CF3CHCl2) and HCFC-142b (CH3CF2Cl)

    NASA Astrophysics Data System (ADS)

    Nayak, Akshaya K.; Buckley, Thomas J.; Kurylo, Michael J.; Fahr, Askar

    1996-04-01

    The absorption cross sections for HCFC-123 (CF3CHCl2) and HCFC-142b (CH3CF2Cl) have been measured in the gas and liquid phases over the temperature range of about 220-330 K. The liquid phase results were converted into effective gas phase cross sections using a wavelength shift procedure, thereby extending the gas phase cross sections to longer wavelengths. The results are compared with other available data and lend increased confidence in atmospheric lifetime calculations for these important industrial alternatives to the fully halogenated chlorofluorocarbons.

  4. A novel double-focusing time-of-flight mass spectrometer for absolute recoil ion cross sections measurements.

    PubMed

    Sigaud, L; de Jesus, V L B; Ferreira, Natalia; Montenegro, E C

    2016-08-01

    In this work, the inclusion of an Einzel-like lens inside the time-of-flight drift tube of a standard mass spectrometer coupled to a gas cell-to study ionization of atoms and molecules by electron impact-is described. Both this lens and a conical collimator are responsible for further focalization of the ions and charged molecular fragments inside the spectrometer, allowing a much better resolution at the time-of-flight spectra, leading to a separation of a single mass-to-charge unit up to 100 a.m.u. The procedure to obtain the overall absolute efficiency of the spectrometer and micro-channel plate detector is also discussed. PMID:27587105

  5. A novel double-focusing time-of-flight mass spectrometer for absolute recoil ion cross sections measurements.

    PubMed

    Sigaud, L; de Jesus, V L B; Ferreira, Natalia; Montenegro, E C

    2016-08-01

    In this work, the inclusion of an Einzel-like lens inside the time-of-flight drift tube of a standard mass spectrometer coupled to a gas cell-to study ionization of atoms and molecules by electron impact-is described. Both this lens and a conical collimator are responsible for further focalization of the ions and charged molecular fragments inside the spectrometer, allowing a much better resolution at the time-of-flight spectra, leading to a separation of a single mass-to-charge unit up to 100 a.m.u. The procedure to obtain the overall absolute efficiency of the spectrometer and micro-channel plate detector is also discussed.

  6. A novel double-focusing time-of-flight mass spectrometer for absolute recoil ion cross sections measurements

    NASA Astrophysics Data System (ADS)

    Sigaud, L.; de Jesus, V. L. B.; Ferreira, Natalia; Montenegro, E. C.

    2016-08-01

    In this work, the inclusion of an Einzel-like lens inside the time-of-flight drift tube of a standard mass spectrometer coupled to a gas cell—to study ionization of atoms and molecules by electron impact—is described. Both this lens and a conical collimator are responsible for further focalization of the ions and charged molecular fragments inside the spectrometer, allowing a much better resolution at the time-of-flight spectra, leading to a separation of a single mass-to-charge unit up to 100 a.m.u. The procedure to obtain the overall absolute efficiency of the spectrometer and micro-channel plate detector is also discussed.

  7. Photonuclear absorption cross sections

    NASA Technical Reports Server (NTRS)

    Norbury, John W.

    1989-01-01

    Neutron multiplicity in photonuclear reactions; invariance of classical electromagnetism; momentum transfer models in ion collisions; cosmic ray electromagnetic interactions; quadrupole excitations in nucleus-nucleus collisons and Y-89 interactions with relativistic nuclei; and the Weizsacker-Williams theory for nucleon emission via electromagnetic excitations in nucleus-nucleus collisions are discussed.

  8. Comparison of x-ray absorption spectra between water and ice: new ice data with low pre-edge absorption cross-section.

    PubMed

    Sellberg, Jonas A; Kaya, Sarp; Segtnan, Vegard H; Chen, Chen; Tyliszczak, Tolek; Ogasawara, Hirohito; Nordlund, Dennis; Pettersson, Lars G M; Nilsson, Anders

    2014-07-21

    The effect of crystal growth conditions on the O K-edge x-ray absorption spectra of ice is investigated through detailed analysis of the spectral features. The amount of ice defects is found to be minimized on hydrophobic surfaces, such as BaF2(111), with low concentration of nucleation centers. This is manifested through a reduction of the absorption cross-section at 535 eV, which is associated with distorted hydrogen bonds. Furthermore, a connection is made between the observed increase in spectral intensity between 544 and 548 eV and high-symmetry points in the electronic band structure, suggesting a more extended hydrogen-bond network as compared to ices prepared differently. The spectral differences for various ice preparations are compared to the temperature dependence of spectra of liquid water upon supercooling. A double-peak feature in the absorption cross-section between 540 and 543 eV is identified as a characteristic of the crystalline phase. The connection to the interpretation of the liquid phase O K-edge x-ray absorption spectrum is extensively discussed.

  9. Comparison of x-ray absorption spectra between water and ice: New ice data with low pre-edge absorption cross-section

    SciTech Connect

    Sellberg, Jonas A.; Nilsson, Anders; Kaya, Sarp; Segtnan, Vegard H.; Chen, Chen; Tyliszczak, Tolek; Ogasawara, Hirohito; Nordlund, Dennis; Pettersson, Lars G. M.

    2014-07-21

    The effect of crystal growth conditions on the O K-edge x-ray absorption spectra of ice is investigated through detailed analysis of the spectral features. The amount of ice defects is found to be minimized on hydrophobic surfaces, such as BaF{sub 2}(111), with low concentration of nucleation centers. This is manifested through a reduction of the absorption cross-section at 535 eV, which is associated with distorted hydrogen bonds. Furthermore, a connection is made between the observed increase in spectral intensity between 544 and 548 eV and high-symmetry points in the electronic band structure, suggesting a more extended hydrogen-bond network as compared to ices prepared differently. The spectral differences for various ice preparations are compared to the temperature dependence of spectra of liquid water upon supercooling. A double-peak feature in the absorption cross-section between 540 and 543 eV is identified as a characteristic of the crystalline phase. The connection to the interpretation of the liquid phase O K-edge x-ray absorption spectrum is extensively discussed.

  10. Measurement of Absolute Excitation Cross Sections in Highly-Charged Ions Using Electron Energy Loss and Merged Beams

    NASA Astrophysics Data System (ADS)

    Chutjian, A.; Smith, Steven J.; Lozano, J. A.

    2002-11-01

    There is increasing emphasis within this decade on understanding energy balance and new phenomena observed in high electron temperature plasmas. The UV spectral return from FUSE, and the X-ray spectral return from the HETG on Chandra and the LETGS on XMM-Newton are just beginning. The line emissions are almost entirely from highly-charged ions (HCIs) of C, N, O, Ne, Mg, S, Si, Ca, and Fe. In addition, the Constellation-X mission, currently in the planning stages, will provide high-throughput X-ray spectroscopy up to photon energies of 0.12 nm (10 keV), where the primary line emitters will again be the HCIs. This array of space instruments is providing an overwhelming return of HCI spectral data from a variety of astrophysical objects. Collision strengths and Einstein A-values are required to convert the observed spectral intensities to electron temperatures and densities in the stellar plasma [1]. The JPL electron energy-loss and merged-beams approach [2] has been used to measure absolute collision strengths in a number of ions, with critical comparisons to the best available theories. Experimental methods will be reviewed, and results presented on experimental comparisons to R-Matrix and Breit-Pauli theoretical results in C3+[3], O2+[4], O5+[5], S2+[6], and Fe9+ [7]. Work is planned for comparisons in Mgq+, and higher charge states Fe(10-15)+. J. Lozano thanks the National Research Council for a fellowship though the NASA- NRC program. This work was carried out at the Jet Propulsion Laboratory, California Institute of Technology, and was supported under contract with the National Aeronautics and Space Administration.

  11. Absolute cross sections and branching ratios for the radiative decay of doubly excited helium determined by photon-induced fluorescence spectroscopy

    NASA Astrophysics Data System (ADS)

    Mickat, S.; Schartner, K.-H.; Kammer, Sv; Schill, R.; Werner, L.; Klumpp, S.; Ehresmann, A.; Schmoranzer, H.; Sukhorukov, V. L.

    2005-08-01

    The decay of doubly excited helium states below the N = 2 threshold, cascading radiatively over three steps, were investigated using the photon-induced fluorescence spectroscopy (PIFS) at BESSY II. Absolute cross sections as the product of the resonance excitation cross section of the doubly excited states and their fluorescence rate to decay into the singly excited 1sms(1S) and 1smd(1D) states were measured. The experiments showed that the (sp,2n+)(1P) states decay predominantly into the 1sns(1S) states, whereas the (pd,2n)(1P) states prefer to decay into the 1snd(1D) states. For the (sp,2n-)(1P) states with n = 4, 5 and 6 we observed a broad and complex decay pattern. In addition the angular distribution of the fluorescence radiation was measured. The results are in good agreement with theoretical predictions. Furthermore, the weakening of the LS coupling scheme and the mixing between singlet and triplet states in helium was confirmed by observation of the 1s6d(3D0,1,2) → 1s2p(3P0,1,2) transition on a doubly excited singlet state.

  12. QSO ABSORPTION SYSTEMS DETECTED IN Ne VIII: HIGH-METALLICITY CLOUDS WITH A LARGE EFFECTIVE CROSS SECTION

    SciTech Connect

    Meiring, J. D.; Tripp, T. M.; Werk, J. K.; Prochaska, J. X.; Howk, J. C.; Jenkins, E. B.; Lehner, N.; Sembach, K. R.

    2013-04-10

    Using high-resolution, high signal-to-noise ultraviolet spectra of the z{sub em} = 0.9754 quasar PG1148+549 obtained with the Cosmic Origins Spectrograph (COS) on the Hubble Space Telescope, we study the physical conditions and abundances of Ne VIII+O VI absorption line systems at z{sub abs} = 0.68381, 0.70152, 0.72478. In addition to Ne VIII and O VI, absorption lines from multiple ionization stages of oxygen (O II, O III, O IV) are detected and are well aligned with the more highly ionized species. We show that these absorbers are multiphase systems including hot gas (T Almost-Equal-To 10{sup 5.7} K) that produces Ne VIII and O VI, and the gas metallicity of the cool phase ranges from Z = 0.3 Z{sub Sun} to supersolar. The cool ( Almost-Equal-To 10{sup 4} K) phases have densities n{sub H} Almost-Equal-To 10{sup -4} cm{sup -3} and small sizes (<4 kpc); these cool clouds are likely to expand and dissipate, and the Ne VIII may be within a transition layer between the cool gas and a surrounding, much hotter medium. The Ne VIII redshift density, dN/dz{approx}7{sup +7}{sub -3}, requires a large number of these clouds for every L > 0.1 L* galaxy and a large effective absorption cross section ({approx}> 100 kpc), and indeed, we find a star-forming {approx}L {sup *} galaxy at the redshift of the z{sub abs} = 0.72478 system, at an impact parameter of 217 kpc. Multiphase absorbers like these Ne VIII systems are likely to be an important reservoir of baryons and metals in the circumgalactic media of galaxies.

  13. Absolute cross sections for near-threshold electron-impact excitation of the 2s 2S-->2p 2P transition in C3+

    NASA Astrophysics Data System (ADS)

    Bannister, M. E.; Chung, Y.-S.; Djurić, N.; Wallbank, B.; Woitke, O.; Zhou, S.; Dunn, G. H.; Smith, A. C.

    1998-01-01

    Absolute total cross sections for electron-impact excitation of the 2s 2S-->2p 2P transition in C3+ were measured from 7.35 eV to 8.45 eV using the merged electron-ion-beams energy-loss technique. The results settle the discrepancy between two previous experiments using the crossed-beams fluorescence method, being in very good agreement with the older results [P. O. Taylor, D. Gregory, G. H. Dunn, R. A. Phaneuf, and D. H. Crandall, Phys. Rev. Lett. 39, 1256 (1977)] but less so with the more recent ones [D. W. Savin, L. D. Gardner, D. B. Reisenfeld, A. R. Young, and J. L. Kohl, Phys. Rev. A 51, 2162 (1995)]. The present measurements are also in good agreement with unitarized Coulomb-Born and close-coupling calculations.

  14. Planetary gamma-ray spectroscopy: the effects of hydrogen absorption cross-section of the gamma-ray spectrum

    SciTech Connect

    Lapides, J.R.

    1981-01-01

    The gamma-ray spectroscopy of planet surfaces is one of several possible methods that are useful in determining the elemental composition of planet surfaces from orbiting spacecraft. This has been demonstrated on the Apollos 15 and 16 missions as well as the Soviet Mars-5 mission. Planetary gamma-ray emission is primarily the result of natural radioactive decay and cosmic-ray and solar-flare-induced nuclear reactions. Secondary neutron reactions play a large role in the more intense gamma-ray emission. The technique provides information on the elemental composition of the top few tens of centimeters of the planet surface. Varying concentrations of hydrogen and compositional variations that alter the macroscopic thermal-neutron absorption cross section have a significant effect on the neutron flux in the planet surface and therefore also on the gamma-ray emission from the surface. These effects have been systematically studied for a wide range of possible planetary compositions that include Mercury, the moon, Mars, the comets, and the asteroids. The problem of the Martian atmosphere was also investigated. The results of these calculations, in which both surface neutron fluxes and gamma-ray emission fluxes were determined, were used to develop general procedures for obtaining planet compositions from the gamma-ray spectrum. Several changes have been suggested for reanalyzing the Apollos 15 and 16 gamma-ray results. In addition, procedures have been suggested that can be applied to neutron-gamma techniques in mineral and oil exploration.

  15. Absorption cross sections of surface-adsorbed H2O in the 295-370 nm region and heterogeneous nucleation of H2O on fused silica surfaces.

    PubMed

    Du, Juan; Huang, Li; Zhu, Lei

    2013-09-12

    We have determined absorption cross sections of a monolayer of H2O adsorbed on the fused silica surfaces in the 295-370 nm region at 293 ± 1 K by using Brewster angle cavity ring-down spectroscopy. Absorption cross sections of surface-adsorbed H2O vary between (4.66 ± 0.83) × 10(-20) and (1.73 ± 0.52) × 10(-21) cm(2)/molecule over this wavelength range, where errors quoted represent experimental scatter (1σ). Our experimental study provides direct evidence that surface-adsorbed H2O is an absorber of the near UV solar radiation. We also varied the H2O pressure in the surface study cell over the 0.01-17 Torr range and obtained probe laser absorptions at 295, 340, and 350 nm by multilayer of adsorbed H2O molecules until the heterogeneous nucleation of water occurred on fused silica surfaces. The average absorption cross sections of multilayer adsorbed H2O are (2.17 ± 0.53) × 10(-20), (2.48 ± 0.67) × 10(-21), and (2.34 ± 0.59) × 10(-21) cm(2)/molecule at 295, 340, and 350 nm. The average absorption cross sections of transitional H2O layer are (6.06 ± 2.73) × 10(-20), (6.48 ± 3.85) × 10(-21), and (8.04 ± 4.92) × 10(-21) cm(2)/molecule at 295, 340, and 350 nm. The average thin water film absorption cross sections are (2.39 ± 0.50) × 10(-19), (3.21 ± 0.81) × 10(-20), and (3.37 ± 0.94) × 10(-20) cm(2)/molecule at 295 nm, 340 nm, and 350 nm. Atmospheric implications of the results are discussed.

  16. Classical Calculations of Scattering Signatures from a Gravitational Singularity or the Scattering and Absorption Cross-Sections of a Black Hole

    NASA Astrophysics Data System (ADS)

    Difilippo, Felix C.

    2012-09-01

    Within the context of general relativity theory we calculate, analytically, scattering signatures around a gravitational singularity: angular and time distributions of scattered massive objects and photons and the time and space modulation of Doppler effects. Additionally, the scattering and absorption cross sections for the gravitational interactions are calculated. The results of numerical simulations of the trajectories are compared with the analytical results.

  17. Temperature dependent absorption cross-sections of O2-O2 collision pairs between 340 and 630 nm and at atmospherically relevant pressure.

    PubMed

    Thalman, Ryan; Volkamer, Rainer

    2013-10-01

    The collisions between two oxygen molecules give rise to O4 absorption in the Earth atmosphere. O4 absorption is relevant to atmospheric transmission and Earth's radiation budget. O4 is further used as a reference gas in Differential Optical Absorption Spectroscopy (DOAS) applications to infer properties of clouds and aerosols. The O4 absorption cross section spectrum of bands centered at 343, 360, 380, 446, 477, 532, 577 and 630 nm is investigated in dry air and oxygen as a function of temperature (203-295 K), and at 820 mbar pressure. We characterize the temperature dependent O4 line shape and provide high precision O4 absorption cross section reference spectra that are suitable for atmospheric O4 measurements. The peak absorption cross-section is found to increase at lower temperatures due to a corresponding narrowing of the spectral band width, while the integrated cross-section remains constant (within <3%, the uncertainty of our measurements). The enthalpy of formation is determined to be ΔH(250) = -0.12 ± 0.12 kJ mol(-1), which is essentially zero, and supports previous assignments of O4 as collision induced absorption (CIA). At 203 K, van der Waals complexes (O(2-dimer)) contribute less than 0.14% to the O4 absorption in air. We conclude that O(2-dimer) is not observable in the Earth atmosphere, and as a consequence the atmospheric O4 distribution is for all practical means and purposes independent of temperature, and can be predicted with an accuracy of better than 10(-3) from knowledge of the oxygen concentration profile.

  18. Temperature dependent absorption cross-sections of O2-O2 collision pairs between 340 and 630 nm and at atmospherically relevant pressure.

    PubMed

    Thalman, Ryan; Volkamer, Rainer

    2013-10-01

    The collisions between two oxygen molecules give rise to O4 absorption in the Earth atmosphere. O4 absorption is relevant to atmospheric transmission and Earth's radiation budget. O4 is further used as a reference gas in Differential Optical Absorption Spectroscopy (DOAS) applications to infer properties of clouds and aerosols. The O4 absorption cross section spectrum of bands centered at 343, 360, 380, 446, 477, 532, 577 and 630 nm is investigated in dry air and oxygen as a function of temperature (203-295 K), and at 820 mbar pressure. We characterize the temperature dependent O4 line shape and provide high precision O4 absorption cross section reference spectra that are suitable for atmospheric O4 measurements. The peak absorption cross-section is found to increase at lower temperatures due to a corresponding narrowing of the spectral band width, while the integrated cross-section remains constant (within <3%, the uncertainty of our measurements). The enthalpy of formation is determined to be ΔH(250) = -0.12 ± 0.12 kJ mol(-1), which is essentially zero, and supports previous assignments of O4 as collision induced absorption (CIA). At 203 K, van der Waals complexes (O(2-dimer)) contribute less than 0.14% to the O4 absorption in air. We conclude that O(2-dimer) is not observable in the Earth atmosphere, and as a consequence the atmospheric O4 distribution is for all practical means and purposes independent of temperature, and can be predicted with an accuracy of better than 10(-3) from knowledge of the oxygen concentration profile. PMID:23928555

  19. Electron photoemission from charged films: absolute cross section for trapping 0-5 eV electrons in condensed CO2.

    PubMed

    Michaud, M; Hébert, E M; Cloutier, P; Sanche, L

    2007-01-14

    The electron trapping or attachment cross section of carbon dioxide (CO2) condensed as thin films on a spacer of Ar is obtained using a simple model for electron trapping in a molecular film and then charge releasing from the same film by photon absorption. The measurements are presented for different electron exposures and impact energies, film thicknesses, and probing photon energies. The cross section for trapping an electron of incident energy between 0 and 5 eV reveals three different attachment processes characterized by a maximum at about 0.75 eV, a structured feature around 2.25 eV, and a shoulder around 3.75 eV. From the measurement of their dependence with the probing photon energy, the two lowest processes produce traps having a vertical electron binding energy of approximately 3.5 eV, whereas the highest one yields a slightly higher value of approximately 3.7 eV. The 0.75 eV maximum corresponds to the formation of vibrational Feshbach resonances in (CO2)n- anion clusters. The 2.25 eV feature is attributed to the formation of a vibrationally excited 2Piu anion in (CO2)n- clusters, followed by fast decay into its vibrational ground state without undergoing autodetachment. Finally, 3.75 eV shoulder is assigned to the well-known dissociative electron attachment process from 2Piu anion state producing the O- anion in the gas phase and the (CO2)nO- anions in clusters.

  20. o-nitrobenzyl photolabile protecting groups with red-shifted absorption: syntheses and uncaging cross-sections for one- and two-photon excitation.

    PubMed

    Aujard, Isabelle; Benbrahim, Chouaha; Gouget, Marine; Ruel, Odile; Baudin, Jean-Bernard; Neveu, Pierre; Jullien, Ludovic

    2006-09-01

    We evaluated the o-nitrobenzyl platform for designing photolabile protecting groups with red-shifted absorption that could be photolyzed upon one- and two-photon excitation. Several synthetic pathways to build different conjugated o-nitrobenzyl backbones, as well as to vary the benzylic position, are reported. Relative to the reference 4,5-dimethoxy-2-nitrobenzyl group, several o-nitrobenzyl derivatives exhibit a large and red-shifted one-photon absorption within the near-UV range. Uncaging after one-photon excitation was studied by measuring UV-visible absorption and steady-state fluorescence emission on model caged ethers and esters. In the whole series investigated, the caged substrates were released cleanly upon photolysis. Quantum yields of uncaging after one-photon absorption lie within the 0.1-1 % range. We observed that these drop as the maximum wavelength absorption of the o-nitrobenzyl protecting group is increased. A new method based on fluorescence correlation spectroscopy (FCS) after two-photon excitation was used to measure the action uncaging cross section for two-photon excitation. The series of o-nitrobenzyl caged fluorescent coumarins investigated exhibit values within the 0.1-0.01 Goeppert-Mayer (GM) range. Such results are in line with the low quantum yields of uncaging associated with cross-sections of 1-50 GM for two-photon absorption. Although the cross-sections for one- and two-photon absorption of o-nitrobenzyl photolabile protecting groups can be readily improved, we emphasize the difficulty in enlarging the corresponding action uncaging cross-sections in view of the observed trend of their quantum yield of uncaging.

  1. o-nitrobenzyl photolabile protecting groups with red-shifted absorption: syntheses and uncaging cross-sections for one- and two-photon excitation.

    PubMed

    Aujard, Isabelle; Benbrahim, Chouaha; Gouget, Marine; Ruel, Odile; Baudin, Jean-Bernard; Neveu, Pierre; Jullien, Ludovic

    2006-09-01

    We evaluated the o-nitrobenzyl platform for designing photolabile protecting groups with red-shifted absorption that could be photolyzed upon one- and two-photon excitation. Several synthetic pathways to build different conjugated o-nitrobenzyl backbones, as well as to vary the benzylic position, are reported. Relative to the reference 4,5-dimethoxy-2-nitrobenzyl group, several o-nitrobenzyl derivatives exhibit a large and red-shifted one-photon absorption within the near-UV range. Uncaging after one-photon excitation was studied by measuring UV-visible absorption and steady-state fluorescence emission on model caged ethers and esters. In the whole series investigated, the caged substrates were released cleanly upon photolysis. Quantum yields of uncaging after one-photon absorption lie within the 0.1-1 % range. We observed that these drop as the maximum wavelength absorption of the o-nitrobenzyl protecting group is increased. A new method based on fluorescence correlation spectroscopy (FCS) after two-photon excitation was used to measure the action uncaging cross section for two-photon excitation. The series of o-nitrobenzyl caged fluorescent coumarins investigated exhibit values within the 0.1-0.01 Goeppert-Mayer (GM) range. Such results are in line with the low quantum yields of uncaging associated with cross-sections of 1-50 GM for two-photon absorption. Although the cross-sections for one- and two-photon absorption of o-nitrobenzyl photolabile protecting groups can be readily improved, we emphasize the difficulty in enlarging the corresponding action uncaging cross-sections in view of the observed trend of their quantum yield of uncaging. PMID:16763952

  2. XCOM: Photon Cross Sections Database

    National Institute of Standards and Technology Data Gateway

    SRD 8 XCOM: Photon Cross Sections Database (Web, free access)   A web database is provided which can be used to calculate photon cross sections for scattering, photoelectric absorption and pair production, as well as total attenuation coefficients, for any element, compound or mixture (Z <= 100) at energies from 1 keV to 100 GeV.

  3. Assessment of experimental d-PIGE γ-ray production cross sections for 12C, 14N and 16O and comparison with absolute thick target yields

    NASA Astrophysics Data System (ADS)

    Csedreki, L.; Halász, Z.; Kiss, Á. Z.

    2016-08-01

    Measured differential cross sections for deuteron induced γ-ray emission from the reactions 12C(d,pγ)13C, (Eγ = 3089 keV), 14N(d,pγ)15N (Eγ = 8310 keV) and 16O(d,pγ)17O (Eγ = 871 keV) available in the literature were assessed. In order to cross check the assessed γ-ray production cross section data, thick target γ-yields calculated from the differential cross sections were compared with available measured thick target yields. Recommended differential cross section data for each reaction were deduced for particle induced γ-ray emission (PIGE) applications.

  4. Reduced mass absorption cross section of black carbon under an extremely polluted condition in southern suburb of Beijing, China

    NASA Astrophysics Data System (ADS)

    Wang, J.; Wang, S.; Hua, Y.; Jiang, J.; Zhao, B.; Xing, J.; Jiang, S.; Cai, R.; Hao, J.

    2015-12-01

    Black carbon (BC), as one of the most important climate-warming agent, has been the focus of extensive studies in recent years. Mass absorption cross section (MAC) is a key parameter to assess the radiative forcing by linking the mass concentration with the radiation effect. In this study, we conducted a two-month field campaign in Beijing, the capital city of China, in a October and November, a period that severe PM2.5 pollution occurred. PM2.5 offline samples were collected daily onto quartz fiber filters by a Partisol 2300 Speciation Sampler. Size-segregated aerosol samples of the size ranged from 0.056 - 10 µm with 11 bins were collected onto quartz fiber filters by a cascade impactor developed by National Chiao Tung University (NCTU). A DRI Model 2001 thermal/optical carbon analyzer were used to analyze the samples. The MAC of BC is measured by a thermal-optical carbon analyzer. In contrast to previous studies, we found that after "shadow effect" has been corrected, the MAC is reduced from 14 m2/g to 5 m2/g with the increase of BC concentrations. There was no significant correlation between MAC with secondary inorganic aerosols. Such unexpected reduction in MAC of BC is possibly associated with the microphysical property of BC modulated under serious pollution condition. The study of size-segregated species concentrations shows that the size distribution of BC is unimodal, with the peak around 0.56-1.8 µm. The results also show the proportion of BC larger than 0.56 µm is significant increased. Additionally, "soot superaggregate", as distinct from conventional sub-micron aggregates, was found in the bins of BC with size ranged from 1 to1.8 µm. Such high carbon aerosol proportion and large BC size distribution suggests that emissions from residential biomass burning is dominant during this episode. This study suggests that the optical property for BC from different emission sectors should be considered in the estimation of radiative forcing.

  5. Determination of Two-Photon Absorption Cross-Section of Noble Gases for Calibration of Laser Spectroscopic Techniques

    SciTech Connect

    Rosa, M. I. de la; Perez, C.; Gruetzmacher, K.; Fuentes, L. M.

    2008-10-22

    The objective of our work is to apply two-photon polarization spectroscopy as a new calibration method for the determination of two-photon excitation cross-sections of noble gases, like Xe and Kr, which are commonly used for calibrations of MP-LIF techniques in other laboratories.

  6. UV Absorption Cross Sections of Nitrous Oxide (N2O) and Carbon Tetrachloride (CCl4) Between 210 and 350 K and the Atmospheric Implications

    NASA Technical Reports Server (NTRS)

    Carlon, Nabilah Rontu; Papanastasiou, Dimitrios K.; Fleming, Eric L.; Jackman, Charles H.; Newman, Paul A.; Burkholder, James B.

    2010-01-01

    Absorption cross sections of nitrous oxide (N2O) and carbon tetrachloride (CCl4) are reported at five atomic UV lines (184.95, 202.548, 206.200, 213.857, and 228.8 nm) at 27 temperatures in the range 210-350 K. In addition, UV absorption spectra of CCl4 are reported between 200-235 nm as a function of temperature (225-350 K). The results from this work are critically compared with results from earlier studies. For N2O, the present results are in good agreement with the current JPL recommendation enabling a reduction in the estimated uncertainty in the N2O atmospheric photolysis rate. For CCl4, the present cross section results are systematically greater than the current recommendation at the reduced temperatures most relevant to stratospheric photolysis. The new cross sections result in a 5-7% increase in the modeled CCl4 photolysis loss, and a slight decrease in the stratospheric lifetime, from 51 to 50 years, for present day conditions. The corresponding changes in modeled inorganic chlorine and ozone in the stratosphere are quite small. A CCl4 cross section parameterization for use in 37 atmospheric model calculations is presented.

  7. Absolute cross sections for one electron capture into excited projectile states in collisions between He 2+ (15-150 keV) and Li atoms

    NASA Astrophysics Data System (ADS)

    Kadota, K.; Dijkkamp, D.; Van Der Woude, R.; Yan, Pan Guang; De Heer, F. J.

    1982-03-01

    We have studied the He 2+-Li collision system at laboratory energies between 15 and 150 keV using optical methods. From the measured emission cross sections we derive state-selective capture cross sections for n = 2,3,4 and n ⩾ 5 states of the He + ions. Our data are consistent with theoretical predictions of Bransden and Ermolaev. The total capture cross sections as evaluated from our emission cross section data, agree very well with the results of McCullough et al. obtained from projectile charge detection measurements. Near 15 keV our emission cross sections for 30.4 nm and 25.6 nm are much larger than those measured previously by Barrett and Leventhal at slightly lower energies.

  8. Theoretical X-ray production cross sections at incident photon energies across Li (i=1-3) absorption edges of Br

    NASA Astrophysics Data System (ADS)

    Puri, Sanjiv

    2015-08-01

    The X-ray production (XRP) cross sections, σLk (k = l, η, α, β6, β1, β3, β4, β9,10, γ1,5, γ2,3) have been evaluated at incident photon energies across the Li(i=1-3) absorption edge energies of 35Br using theoretical data sets of different physical parameters, namely, the Li(i=1-3) sub-shell the X-ray emission rates based on the Dirac-Fock (DF) model, the fluorescence and Coster Kronig yields based on the Dirac-Hartree-Slater (DHS) model, and two sets of the photoionisation cross sections based on the relativistic Hartree-Fock-Slater (RHFS) model and the Dirac-Fock (DF) model, in order to highlight the importance of electron exchange effects at photon energies in vicinity of absorption edge energies.

  9. High-resolution absorption cross sections of carbon monoxide bands at 295 K between 91.7 and 100.4 nanometers

    NASA Technical Reports Server (NTRS)

    Stark, G.; Yoshino, K.; Smith, Peter L.; Ito, K.; Parkinson, W. H.

    1991-01-01

    Theoretical descriptions of the abundance and excitation of carbon monoxide in interstellar clouds require accurate data on the vacuum-ultraviolet absorption spectrum of the molecule. The 6.65 m spectrometer at the Photon Factory synchrotron light source was used to measure photoabsorption cross sections of CO features between 91.2 and 100.4 nm. These data were recorded at a resolving power of 170,000, more than 20 times greater than that used in previous work.

  10. Two-photon excitation and excited-state absorption cross sections for H2 E,F 1Sigma sub g (v=6) - Measurement and calculations

    NASA Astrophysics Data System (ADS)

    Buck, Jesse D.; Robie, Daniel C.; Hickman, A. P.; Bamford, Douglas J.; Bischel, William K.

    1989-04-01

    Observations of the E,F 1Sigma sub g (+) (v-prime=6)-to-B 1Sigma sub u (+) (v-double-prime=0) fluorescence transition at about 750 nm have been conducted to determine the absolute two-photon excitation cross section for the H2 E,F 1Sigma sub g (v-prime=6)-from-X 1Sigma sub g (v-double-prime=0) Q(1) transition at 193 nm. The 2.0 + or - 0.9 x 10 to the -36th cm exp 4 integrated two-photon excitation cross-section obtained is in good agreement with Huo and Jaffe's (1983) theoretical calculation result of 2.8 x 10 to the -36th cm exp 4.

  11. The 4He Total Photo-Absorption Cross Section With Two- Plus Three-Nucleon Interactions From Chiral Effective Field Theory

    SciTech Connect

    Quaglioni, S; Navratil, P

    2007-03-09

    The total photo-absorption cross section of {sup 4}He is evaluated microscopically using two- (NN) and three-nucleon (NNN) interactions based upon chiral effective field theory ({chi}EFT). The calculation is performed using the Lorentz integral transform method along with the ab initio no-core shell model approach. An important feature of the present study is the consistency of the NN and NNN interactions and also, through the Siegert theorem, of the two- and three-body current operators. This is due to the application of the {chi}EFT framework. The inclusion of the NNN interaction produces a suppression of the peak height and enhancement of the tail of the cross section. We compare to calculations obtained using other interactions and to representative experiments. The rather confused experimental situation in the giant resonance region prevents discrimination among different interaction models.

  12. Size-dependent optical absorption modulation of Si/Ge and Ge/Si core/shell nanowires with different cross-sectional geometries.

    PubMed

    Luo, S; Yu, W B; He, Y; Ouyang, G

    2015-02-27

    We present an atomic-level and quantitative study of the absorption properties in Si/Ge and Ge/Si core/shell nanowires (CSNWs) along [110] direction with different cross-sectional geometries using the atomic bond relaxation method. We find that the strain existing in self-equilibrium state of CSNWs and associated with elastic energy originating from interface mismatch and surface relaxation affect the band shift and absorption properties. Compared to the CSNWs with tetragonal, hexagonal and circular shapes, the triangular CSNWs have the largest band gap shift at a fixed strain and the smallest absorption coefficient at a determinate incident light wavelength. The tunable absorption property, realized by controlling the size and geometry structure, could be helpful for nanoelectronic applications. PMID:25649268

  13. Toward Improving Atmospheric Models and Ozone Projections: Laboratory UV Absorption Cross Sections and Equilibrium Constant of ClOOCl

    NASA Astrophysics Data System (ADS)

    Wilmouth, D. M.; Klobas, J. E.; Anderson, J. G.

    2015-12-01

    Thirty years have now passed since the discovery of the Antarctic ozone hole, and despite comprehensive international agreements being in place to phase out CFCs and halons, polar ozone losses generally remain severe. The relevant halogen compounds have very long atmospheric lifetimes, which ensures that seasonal polar ozone depletion will likely continue for decades to come. Changes in the climate system can further impact stratospheric ozone abundance through changes in the temperature and water vapor structure of the atmosphere and through the potential initiation of solar radiation management efforts. In many ways, the rate at which climate is changing must now be considered fast relative to the slow removal of halogens from the atmosphere. Photochemical models of Earth's atmosphere play a critical role in understanding and projecting ozone levels, but in order for these models to be accurate, they must be built on a foundation of accurate laboratory data. ClOOCl is the centerpiece of the catalytic cycle that accounts for more than 50% of the chlorine-catalyzed ozone loss in the Arctic and Antarctic stratosphere every spring, and so uncertainties in the ultraviolet cross sections of ClOOCl are particularly important. Additionally, the equilibrium constant of the dimerization reaction of ClO merits further study, as there are important discrepancies between in situ measurements and lab-based models, and the JPL-11 recommended equilibrium constant includes high error bars at atmospherically relevant temperatures (~75% at 200 K). Here we analyze available data for the ClOOCl ultraviolet cross sections and equilibrium constant and present new laboratory spectroscopic results.

  14. Temperature dependent emission and absorption cross section of Yb3+ doped yttrium lanthanum oxide (YLO) ceramic and its application in diode pumped amplifier.

    PubMed

    Banerjee, Saumyabrata; Koerner, Joerg; Siebold, Mathias; Yang, Qiuhong; Ertel, Klaus; Mason, Paul D; Phillips, P Jonathan; Loeser, Markus; Zhang, Haojia; Lu, Shenzhou; Hein, Joachim; Schramm, Ulrich; Kaluza, Malte C; Collier, John L

    2013-07-01

    Temperature dependent absorption and emission cross-sections of 5 at% Yb(3+) doped yttrium lanthanum oxide (Yb:YLO) ceramic between 80K and 300 K are presented. In addition, we report on the first demonstration of ns pulse amplification in Yb:YLO ceramic. A pulse energy of 102 mJ was extracted from a multi-pass amplifier setup. The amplification bandwidth at room temperature confirms the potential of Yb:YLO ceramic for broad bandwidth amplification at cryogenic temperatures.

  15. Quantification of Brown Carbon Mass Absorption Cross Section from Sources through the Application of Physical and Mathematical Segregation of Black Carbon

    NASA Astrophysics Data System (ADS)

    Olson, M.; Van Rooy, P.; Dietenberger, M.; Short, K.; Zhan, Y.; Schauer, J. J.

    2015-12-01

    Quantification of the black carbon (BC) and brown carbon (BrC) components of source emissions is critical to understanding the impact combustion aerosols have on atmospheric light absorption. Multiple-wavelength absorption of particulate matter emissions was measured from combustion of wood, agricultural biomass, coals, leaf litter, and petroleum distillates in controlled combustion settings. Aethalometer corrected BC absorption was segregated mathematically from the total light extinction to estimate the BrC absorption from individual sources. Results were compared to elemental carbon (EC)/organic carbon (OC) concentrations to determine composition's impact on light absorption. The bulk carbonaceous aerosol and BrC Mass absorption cross section (MAC) were variable across source types and light wavelengths. Sources such as incense and peat emissions showed ultraviolet wavelength (370nm) BrC absorption over 175 and 80 times (respectively) the BC absorption but only 21 and 11 times (respectively) at 520nm wavelength. The bulk EC MACEC, λ (average at 520nm=9.0±3.7 m2 g-1; with OC fraction <0.85 = ~7.5 m2 g-1) and the BrC OC mass absorption cross sections (MACBrC,OC,λ) were calculated; at 370 nm ultraviolet wavelengths; the MACBrC,OC,λ ranged from 0.8 m2 g-1 to 2.29 m2 g-1 (lowest peat, highest kerosene), while at 520nm wavelength MACBrC,OC,λ ranged from 0.07 m2 g-1 to 0.37 m2 g-1 (lowest peat, highest kerosene/incense mixture). Samples from the same combustions sources were water and organic solvent extracted, filtered to physically remove BC, and the extracts were re-aerosolized in a controlled suspension chamber. The MACBrC,OC,λ derived from the re-suspended OC were compared to the mathematically derived MACBrC,OC,λ and were shown to have similar absorption spectra, however variability between the methods were observed, likely due to variations in particle size distributions, particle mixing state, and uncertainty associated with the OC quantification. The

  16. In vivo estimation of pigment composition and optical absorption cross-section by spectroradiometry in four aquatic photosynthetic micro-organisms.

    PubMed

    Méléder, Vona; Laviale, Martin; Jesus, Bruno; Mouget, Jean Luc; Lavaud, Johann; Kazemipour, Farzaneh; Launeau, Patrick; Barillé, Laurent

    2013-12-01

    The objective of the present study was to estimate in vivo pigment composition and to retrieve absorption cross-section values, a(∗), of photosynthetic micro-organisms using a non-invasive technique of reflectance spectrometry. To test the methodology, organisms from different taxonomical groups and different pigment composition were used (Spirulina platensis a Cyanophyta, Porphyridium cruentum a Rhodophyta, Dunaliella tertiolecta a Chlorophyta and Entomoneis paludosa a Bacillariophyta) and photoacclimated to two different irradiance levels: 25 μmol photonm(-2)s(-1) (Low Light, LL) and 500 μmol photonm(-2)s(-1) (High Light, HL). Second derivative spectra from reflectance were used to identify pigment in vivo absorption bands that were linked to specific pigments detected by high performance liquid chromatography. Whereas some absorption bands such as those induced by Chlorophyll (Chl) a (416, 440, 625 and around 675 nm) were ubiquous, others were taxonomically specific (e.g. 636 nm for Chl c in E. paludosa) and/or photo-physiological dependent (e.g. 489 nm for zeaxanthin in the HL-acclimated S. platensis). The optical absorption cross-section, a(∗), was retrieved from reflectance data using a radiative transfer model previously developed for microphytobenthos. Despite the cellular Chl a decrease observed from LL to HL (up to 88% for S. platensis), the a(∗) increased, except for P. cruentum. This was attributed to a 'package effect' and to a greater absorption by photoprotective carotenoids that did not contribute to the energy transfer to the core Chl a.

  17. In vivo estimation of pigment composition and optical absorption cross-section by spectroradiometry in four aquatic photosynthetic micro-organisms.

    PubMed

    Méléder, Vona; Laviale, Martin; Jesus, Bruno; Mouget, Jean Luc; Lavaud, Johann; Kazemipour, Farzaneh; Launeau, Patrick; Barillé, Laurent

    2013-12-01

    The objective of the present study was to estimate in vivo pigment composition and to retrieve absorption cross-section values, a(∗), of photosynthetic micro-organisms using a non-invasive technique of reflectance spectrometry. To test the methodology, organisms from different taxonomical groups and different pigment composition were used (Spirulina platensis a Cyanophyta, Porphyridium cruentum a Rhodophyta, Dunaliella tertiolecta a Chlorophyta and Entomoneis paludosa a Bacillariophyta) and photoacclimated to two different irradiance levels: 25 μmol photonm(-2)s(-1) (Low Light, LL) and 500 μmol photonm(-2)s(-1) (High Light, HL). Second derivative spectra from reflectance were used to identify pigment in vivo absorption bands that were linked to specific pigments detected by high performance liquid chromatography. Whereas some absorption bands such as those induced by Chlorophyll (Chl) a (416, 440, 625 and around 675 nm) were ubiquous, others were taxonomically specific (e.g. 636 nm for Chl c in E. paludosa) and/or photo-physiological dependent (e.g. 489 nm for zeaxanthin in the HL-acclimated S. platensis). The optical absorption cross-section, a(∗), was retrieved from reflectance data using a radiative transfer model previously developed for microphytobenthos. Despite the cellular Chl a decrease observed from LL to HL (up to 88% for S. platensis), the a(∗) increased, except for P. cruentum. This was attributed to a 'package effect' and to a greater absorption by photoprotective carotenoids that did not contribute to the energy transfer to the core Chl a. PMID:24211563

  18. Theoretical X-ray production cross sections at incident photon energies across L{sub i} (i=1-3) absorption edges of Br

    SciTech Connect

    Puri, Sanjiv

    2015-08-28

    The X-ray production (XRP) cross sections, σ{sub Lk} (k = l, η, α, β{sub 6}, β{sub 1}, β{sub 3}, β{sub 4}, β{sub 9,10}, γ{sub 1,5}, γ{sub 2,3}) have been evaluated at incident photon energies across the L{sub i}(i=1-3) absorption edge energies of {sub 35}Br using theoretical data sets of different physical parameters, namely, the L{sub i}(i=1-3) sub-shell the X-ray emission rates based on the Dirac-Fock (DF) model, the fluorescence and Coster Kronig yields based on the Dirac-Hartree-Slater (DHS) model, and two sets of the photoionisation cross sections based on the relativistic Hartree-Fock-Slater (RHFS) model and the Dirac-Fock (DF) model, in order to highlight the importance of electron exchange effects at photon energies in vicinity of absorption edge energies.

  19. Black carbon over Mexico: The effect of atmospheric transport on mixing state, mass absorption cross-section, and BC/CO ratios

    SciTech Connect

    Subramanian, R.; Kok, G. L.; Baumgardner, Darrel; Clarke, A. D.; Shinozuka, Y.; Campos, Teresa; Heizer, CG; Stephens, Britton; de Foy, B.; Voss, Paul B.; Zaveri, Rahul A.

    2010-01-13

    A single particle soot photometer (SP2) was operated on the NCAR C-130 during the MIRAGE campaign (part of MILAGRO), sampling black carbon (BC) over Mexico. The highest BC concentrations were measured over Mexico City (sometimes as much as 2 Fg/m34 ) and over hill fires to the south of the city. The age of plumes outside of Mexico City was determined using a combination of HYSPLIT trajectories, WRF-FLEXPART modeling and CMET balloon tracks. As expected, older, diluted air masses had lower BC concentrations. A comparison of carbon monoxide (CO) and BC suggests a CO background of around 65 ppbv, and a backgroundcorrected BC/COnet ratio of 2.89±0.89 (ng/m39 -STP)/ppbv (average ± standard deviation). This ratio is similar for fresh emissions over Mexico City, as well as for aged airmasses. Comparison of light absorption measured with a particle soot absorption photometer (PSAP) and the SP2 BC suggests a BC mass-normalized absorption cross-section (MAC) of 10.9±2.1 m212 /g at 660 nm (or 13.1 m213 /g @ 550 nm, assuming MAC is inversely dependent on wavelength). This appears independent of aging and similar to the expected absorption cross-section for aged BC, but values, particularly in fresh emissions, could be biased high due to instrument artifacts. SP2-derived BC coating indicators show a prominent thinly-coated BC mode over the Mexico City Metropolitan Area (MCMA), while older air masses show both thinly-coated and thickly-coated BC. Some 2-day-old plumes do not show a prominent thickly-coated BC mode, possibly due to preferential wet scavenging of the likely-hydrophilic thickly-coated BC.

  20. Evolution of wavelength-dependent mass absorption cross sections of carbonaceous aerosols during the 2010 DOE CARES campaign

    NASA Astrophysics Data System (ADS)

    Flowers, B. A.; Dubey, M. K.; Subramanian, R.; Sedlacek, A. J.; Kelley, P.; Luke, W. T.; Jobson, B. T.; Zaveri, R. A.

    2011-12-01

    Predictions of aerosol radiative forcing require process level optical property models that are built on precise and accurate field observations. Evolution of aerosol optical properties for urban influenced carbonaceous aerosol undergoing transport and mixing with rural air masses was a focal point of the DOE Carbonaceous Aerosol and Radiative Effects (CARES) campaign near Sacramento, CA in summer 2010. Urban aerosol was transported from Sacramento, CA (T0) to the foothills of the Sierra Nevada Mountains to a rural site located near Cool, CA (T1). Aerosol absorption and scattering coefficients were measured at the T0 and T1 sites using integrated photoacoustic acoustic/nephelometer instruments (PASS-3 and PASS-UV) at 781, 532, 405, and 375 nm. Single particle soot photometry (SP2) instrumentation was used to monitor black carbon (BC) mass at both sites. Combining data from these sensors allows estimate of the wavelength-dependent mass absorption coefficient (MAC(λ)) and partitioning of MAC(λ) into contributions from the BC core and from enhancements from coating of BC cores. MAC(λ) measured in this way is free of artifacts associated with filter-based aerosol absorption measurements and takes advantage of the single particle sensitivity of the SP2 instrument, allowing observation of MAC(λ) on 10 minute and faster time scales. Coating was observed to enhance MAC(λ) by 20 - 30 % and different wavelength dependence for MAC(λ) was observed for urban and biomass burning aerosol. Further, T0 - T1 evolution of MAC(λ) was correlated with separately measured NO/NOy ratios and CO/CO2 ratios to understand the effects of aging & transport on MAC(λ) and the implications of aerosol processing that links air quality to radiative forcing on a regional scale. Aircraft observations made from the Gulfstream-1 during CARES are also analyzed to enhance process level understanding of the optical properties of fresh and aged carbonaceous aerosol in the urban-rural interface.

  1. Measurement of absolute total cross sections for the scattering of electrons by He, H/sub 2/, CH/sub 4/ and CCl/sub n/F/sub m/

    SciTech Connect

    Jones, R.K.

    1985-01-01

    Absolute total electron scattering sections (elastic plus inelastic, integrated over all angles) were measured for helium, molecular hydrogen, methane, tetrachloromethane, trichlorofluoromethane, dichlorodifluoromethane, chlorotrifluoromethane and tetrafluoromethane for incident electron energies from below 1 eV to 50 eV. The electron transmission spectrometer employed consisted of a broad spectrum pulsed electron source in line with a gas sample cell and electron detector. The electron energy was derived from the measured electron time of flight from the source to the detector. The total cross section was determined, using Beer's law, from the attenuation of the electron beam as it passed through a sample cell. Thorough theoretical studies have been reported for helium and the simpler molecules. For these systems, comparisons are made between the above results and reported absolute cross section measurements and calculations with careful consideration given to possible causes of the differences observed between recent measurements. For the more complicated molecules there are few reported calculations or measurements of the total cross sections. In these cases the low energy resonances associated with electron capture processes are not adequately described by available theoretical studies, so molecular orbital calculations and complementary experimental results are employed to explain the observed structure.

  2. Broadband transient absorption spectroscopy with 1- and 2-photon excitations: Relaxation paths and cross sections of a triphenylamine dye in solution

    SciTech Connect

    Moreno, J.; Dobryakov, A. L.; Hecht, S. E-mail: skovale@chemie.hu-berlin.de; Kovalenko, S. A. E-mail: skovale@chemie.hu-berlin.de; Ioffe, I. N.; Granovsky, A. A.

    2015-07-14

    1-photon (382 nm) and 2-photon (752 nm) excitations to the S{sub 1} state are applied to record and compare transient absorption spectra of a push-pull triphenylamine (TrP) dye in solution. After 1-photon excitation, ultrafast vibrational and structural molecular relaxations are detected on a 0.1 ps time scale in nonpolar hexane, while in polar acetonitrile, the spectral evolution is dominated by dipolar solvation. Upon 2-photon excitation, transient spectra in hexane reveal an unexpected growth of stimulated emission (SE) and excited-state absorption (ESA) bands. The behavior is explained by strong population transfer S{sub 1} → S{sub n} due to resonant absorption of a third pump photon. Subsequent S{sub n} → S{sub 1} internal conversion (with τ{sub 1} = 1 ps) prepares a very hot S{sub 1} state which cools down with τ{sub 2} = 13 ps. The pump pulse energy dependence proves the 2-photon origin of the bleach signal. At the same time, SE and ESA are strongly affected by higher-order pump absorptions that should be taken into account in nonlinear fluorescence applications. The 2-photon excitation cross sections σ{sup (2)} = 32 ⋅ 10{sup −50} cm{sup 4} s at 752 nm are evaluated from the bleach signal.

  3. Measurement of absolute cross sections for excitation of the 2s(2) S-1 -> 2s2p P-1 degrees transition in O+4

    NASA Technical Reports Server (NTRS)

    Smith, S. J.; Djuric, N.; Lozano, J. A.; Berrington, K. A.; Chutjian, A.

    2005-01-01

    Experimental cross sections are reported for the 1s(2)2s(2) S-1 -> 1s(2)2s2p P-1(o) transition in O+4 located at 19.689 eV. Use is made of the electron energy-loss method, using a merged electron-ion beam geometry. The center-of-mass interaction energies for the measurements in the S-1 -> P-1(o) transition are in the range 18 eV ( below the threshold) to 30 eV. Data are compared with other previous electron energy-loss measurements and with results of a 26 term R-matrix calculation that includes fine structure explicitly via the Breit-Pauli Hamiltonian. Clear resonance enhancement is observed in all experimental and theoretical results near the threshold for this S-1 -> P-1(o) transition.

  4. Accurate Cross Sections for Microanalysis

    PubMed Central

    Rez, Peter

    2002-01-01

    To calculate the intensity of x-ray emission in electron beam microanalysis requires a knowledge of the energy distribution of the electrons in the solid, the energy variation of the ionization cross section of the relevant subshell, the fraction of ionizations events producing x rays of interest and the absorption coefficient of the x rays on the path to the detector. The theoretical predictions and experimental data available for ionization cross sections are limited mainly to K shells of a few elements. Results of systematic plane wave Born approximation calculations with exchange for K, L, and M shell ionization cross sections over the range of electron energies used in microanalysis are presented. Comparisons are made with experimental measurement for selected K shells and it is shown that the plane wave theory is not appropriate for overvoltages less than 2.5 V. PMID:27446747

  5. Absolute measurements of nonlinear absorption near LIDT at 193 nm

    NASA Astrophysics Data System (ADS)

    Blaschke, Holger; Ristau, Detlev; Welsch, Eberhard; Apel, Oliver

    2001-04-01

    Previous investigations indicate that oxide coatings exhibit non-linear absorption phenomena below 200 nm. Hereby, absorption data of Al2O3 thin film coatings has been determined absolutely by laser calorimetry (LCA) at 193 nm in the low fluence regime. As an alternative, on the basis of the pulsed surface thermal lens technique (STL), photothermal measurements allow to determine the absorption relatively at fluence levels both in the subdamage fluence range far from the damage onset and close to the LIDT. By combining the two measurement techniques, the absolute determination of linear as well as multiphoton absorption can be achieved also in the vicinity of the laser damage fluences. This is of crucial interest because the initiation of damage onset can be observed immediately. Absolute absorption data of Al2O3 coatings at different laser fluences stating of some mJoule/cm2 will be presented for the wavelength 193 nm. Thus, the correlation between the increase of absorption and the onset of breakdown can be illustrated impressively. The evaluation and discussion of the experimental results are focused on the degree of non-linearity of the investigated absorption behavior of oxide single layers initiating the optical breakdown of UV oxide coatings.

  6. Measurement of Absolute Cross Sections for Excitation of the 2s^2 ^1S - 2s2p ^1P^o Transition in O^4+

    NASA Astrophysics Data System (ADS)

    Smith, Steven J.; Berrington, K. A.

    2005-05-01

    Experimental electron excitation cross sections are reported for the 2s^2 1S - 2s2p^ 1P^o transitions in O^4+ located at 19.689 eV. The JPL electron-cyclotron resonance ion source is utilized [1], along with the electron energy loss method, in a merged electron-ion beams geometry[2]. The center-of-mass interaction energies for the measurements are in the range 18 eV (below threshold) to 30 eV. Data are compared with results of a 26-term R-matrix calculation that includes fine structure explicitly via the Breit-Pauli Hamiltonian [3]. There is good agreement with theoretical results and with previous electron energy-loss measurements [3]. Clear resonance enhancement is observed in both experiment and theoretical results near threshold for this ^1S - ^1P^o transition. J. Lozano and N. Djuric acknowledge support through the NASA-NRC program. This work was carried out at JPL/Caltech and was supported by NASA. [1] J. B. Greenwood, S. J. Smith, A.Chutjian, and E. Pollack, Phys. Rev. A 59 1348, (1999). [2] A. Chutjian, Physica Scripta T110, 203 (2004). [3] M. Bannister et al., Int.J. Mass Spectrometry 192, 39 (1999).

  7. Novel 2,1,3-benzothiadiazole-based red-fluorescent dyes with enhanced two-photon absorption cross-sections.

    PubMed

    Kato, Shin-ichiro; Matsumoto, Taisuke; Shigeiwa, Motoyuki; Gorohmaru, Hideki; Maeda, Shuuichi; Ishi-i, Tsutomu; Mataka, Shuntaro

    2006-03-01

    This paper reports the two-photon absorbing and orange-red fluorescence emitting properties of a series of new 2,1,3-benzothiadiazole (BTD)-based D-pi-A-pi-D-type and star-burst-type fluorescent dyes. In the D-pi-A-pi-D-type dyes 1-6, a central BTD core was connected with two terminal N,N-disubstituted amino groups via various pi-conjugated spacers. The star-burst-type dyes 8 and 10 have a three-branched structure composed of a central core (benzene core in 8 and triphenylamine core in 10) and three triphenylamine-containing BTD branches. All the BTD-based dyes displayed intense orange-red color fluorescence in a region of 550-689 nm, which was obtained by single-photon excitation with good fluorescent quantum yield up to 0.98 as well as by two-photon excitation. Large two-photon absorption (TPA) cross-sections (110-800 GM) of these BTD dyes were evaluated by open aperture Z-scan technique with a femtosecond Ti/sapphire laser. The TPA cross-sections of D-pi-A-pi-D-type dyes 2-6 with a benzene, thiophene, ethene, ethyne, and styrene moiety, respectively, as an additional pi-conjugated spacer are about 1.5-2.5 times larger than that of 1c with only a benzene spacer. The TPA cross-sections significantly increased in three-branched star-burst-type BTDs 8 (780 GM) with a benzene core and 10 (800 GM) with a triphenylamine core, which are about 3-5 times larger than those of the corresponding one-dimensional sub-units 9 (170 GM) and 11 (230 GM), respectively. The ratios of sigma/e(pi) between three-branched and one-dimensional dyes were 6.5:3.8 (for 8 and 9) and 6.0:4.0 (for 10 and 11), which are larger than those predicted simply on the basis of the chromophore number density (1:1), according to a cooperative enhancement of the two-photon absorbing nature in the three-branched system.

  8. A Novel Algorithm Applied to Common Thermal-Optical Transmission Data for Determining Mass Absorption Cross Sections of Atmospheric Black Carbon: Applications to the Indian Outflow

    NASA Astrophysics Data System (ADS)

    Andersson, A.; Sheesley, R. J.; Kirillova, E.; Gustafsson, O.

    2010-12-01

    High wintertime concentrations of black carbon aerosols (BCA) over South Asia and the Northern Indian Ocean are thought to have a large impact on the regional climate. Direct absorption of sunlight by BCAs causes heating of the atmosphere and cooling at the surface. To quantify such effects it is important to characterize a number of different properties of the aerosols. Here we present a novel application of the thermal-optical (OCEC) instrument in which the laser beam is used to obtain optical information about the aerosols. In particular, the novel algorithm accounts for non-carbon contributions to the light extinction. Combining these light extinction coefficients with the simultaneously constrained Elemental Carbon (EC) concentrations, the Mass Absorption Cross Section (MAC) is computed. Samples were collected during a continuous 14-month campaign Dec 2008 - Mar 2009 at Sinaghad in Western India and on Hanimaadhoo, the Northernmost Island in the Maldives. This data set suggests that the MAC of the BCAs are variable, sometimes by a factor of 3 compared to the mean. This observation adds to the complexity of calculating the radiative forcing for BCAs, reinforcing previous observations that parameters such as aerosol mixing state and sources need to be taken into account.

  9. Large Femtosecond Two-Photon Absorption Cross-Sections of Fullerosome Vesicle Nanostructures Derived from Highly Photoresponsive Amphiphilic C60-Light-Harvesting Fluorene Dyad

    PubMed Central

    Wang, Min; Nalla, Venkatram; Jeon, Seaho; Mamidala, Venkatesh; Ji, Wei; Tan, Loon-Seng; Cooper, Thomas; Chiang, Long Y.

    2011-01-01

    We demonstrated ultrafast femtosecond nonlinear optical (NLO) absorption characteristics of bilayered fullerosome vesicle nanostructures derived from molecular self-assembly of amphiphilic oligo(ethylene glycolated) C60-(light-harvesting diphenylaminofluorene antenna). Fullerene conjugates were designed to enhance photoresponse in a femtosecond time scale by applying an isomerizable periconjugation linker between the C60 cage and diphenylaminofluorene antenna subunit in an intramolecular contact distance of only < 3.0 Å. Morphology of C60(>DPAF-EG12C1)-based fullerosome nanovesicles in H2O was characterized to consist of a bilayered shell with a sphere diameter of 20–70 nm and a chromophore shell-width of 9.0–10 nm, fitting well with a head-to-head packing configuration of the molecular length. At the estimated effective nanovesicle concentration as low as 5.5 × 10−8 MV (molecular molar concentration of 5.0 × 10−4 M) in H2O, two-photon absorption (2PA) phenomena were found to be the dominating photophysical events showing a large molar concentration-insensitive 2PA cross-section value equivalent to 8500 GM in a form of nanovesicles, on average. The observed NLO characteristics led to a sharp trend of efficient light-transmittance intensity reduction at the input laser intensity above 100 GW/cm2. PMID:22022620

  10. Determination of band oscillator strengths of atmospheric molecules from high resolution vacuum ultraviolet cross section measurements

    NASA Technical Reports Server (NTRS)

    Parkinson, W. H.

    1986-01-01

    An account is given of progress in work on (1) the determination of band oscillator strengths of the Schumann-Runge absorption bands of (16)O2 and (18)O2 from cross section measurements conducted at 79 K; (2) the determination of the absolute absorption cross section of the Schumann-Runge bands of (16)O(18)O from optical depth measurements performed on mixtures of (16)O2, (18)O2 and (16)O(18)O at 79K; and (3) the influence of Schumann-Runge linewing contributions on the determination of the Herzberg continuum absorption cross section of (16)O2 in the wavelength region 194 to 204 nm. The experimental investigations are effected at high resolution with a 6.65 m scanning spectrometer which is, by virtue of its small instrumental width (EWHM = 0.0013 nm), uniquely suitable for cross section measurements of molecular bands with discrete rotational structure. Absolute cross sections, which are independent of the instrumental function and from which band oscillator strengths are directly determined, are measured for the absorption bands that are most predissociated. Such measurements are needed for (1) accurate calculations of the stratospheric production of atomic oxygen and heavy ozone formed following the photopredissociation of (18)O(16)O by solar radiation penetrating between the absorption lines of (16)O2; (2) elucidation of the mechanism of predissociation of the upper state of the Schumann-Runge bands; and (3) determination of the true shape of the Herzberg continuum cross section.

  11. Measurement and calculation of absolute single- and double-charge-exchange cross sections for O6 + ions at 1.17 and 2.33 keV/u impacting He and H2

    NASA Astrophysics Data System (ADS)

    Machacek, J. R.; Mahapatra, D. P.; Schultz, D. R.; Ralchenko, Yu.; Chutjian, A.; Simcic, J.; Mawhorter, R. J.

    2014-11-01

    Absolute single- and double-charge-exchange cross sections for the astrophysically prominent O6 + ion with the atomic and molecular targets He and H2 are reported. These collisions give rise to x-ray emissions in the interplanetary medium, planetary atmospheres, and comets as they approach the sun. Measurements have been carried out using the Caltech Jet Propulsion Laboratory electron cyclotron resonance ion source with O6 + at energies of 1.17 and 2.33 keV/u characteristic of the slow and fast components of the solar wind. Absolute charge-exchange (CE) data are derived from knowledge of the target gas pressure, target path length, incident ion current, and charge-exchanged ion currents. These data are compared with results obtained using the n -electron classical trajectory Monte Carlo method. The radiative and Auger evolution of ion populations following one- and two-electron transfers is calculated with the time-dependent collisional-radiative code nomad using atomic data from the flexible atomic code. Calculated CE emission spectra for 100 Å <λ <1400 Å are reported as well and compared with experimental sublevel spectra and cross sections.

  12. Optical transitions, absorption intensities, and intermanifold emission cross sections of Pr3+(4f2) in Ca5(PO4)3F crystal host

    NASA Astrophysics Data System (ADS)

    Sardar, Dhiraj K.; Russell, Charles C.

    2004-05-01

    A spectroscopic Judd-Ofelt investigation has been performed on Pr3+ ions doped in calcium fluorapatite, Ca5(PO4)3F, belonging to the apatite structure family. The standard Judd-Ofelt analysis was applied to the room temperature absorption intensities of Pr3+ transitions to determine the phenomenological intensity parameters: Ω2, Ω4, and Ω6. Values of the intensity parameters were subsequently used to determine the decay rates (emission probabilities), radiative lifetimes, and branching ratios of the principal intermanifold transitions of Pr3+ from the 3P2, 1D2, and 3P0 manifold states to the lower-lying manifolds. In addition, the room temperature fluorescence lifetimes and emission cross sections of the 3P2→3H5, 1D2→3H4, and 3P0→3F2 transitions were measured; these values were compared with those of Nd3+:yttritium-aluminum-garnet and Pr3+:Sr5(PO4)3 (known as S-FAP).

  13. Climatology of aerosol optical properties and black carbon mass absorption cross section at a remote high-altitude site in the western Mediterranean Basin

    NASA Astrophysics Data System (ADS)

    Pandolfi, M.; Ripoll, A.; Querol, X.; Alastuey, A.

    2014-06-01

    Aerosol light scattering (σsp), backscattering (σbsp) and absorption (σap) were measured at Montsec (MSC; 42°3' N, 0°44' E, 1570 m a.s.l.), a remote high-altitude site in the western Mediterranean Basin. Mean (±SD) σsp, σbsp and σap were 18.9 ± 20.8, 2.6 ± 2.8 and 1.5 ± 1.4 Mm-1, respectively at 635 nm during the period under study (June 2011-June 2013). Mean values of single-scattering albedo (SSA, 635 nm), the scattering Ångström exponent (SAE, 450-635 nm), backscatter-to-scatter ratio (B / S, 635 nm), asymmetry parameter (g, 635 nm), black carbon mass absorption cross section (MAC, 637 nm) and PM2.5 mass scattering cross section (MSCS, 635 nm) were 0.92 ± 0.03, 1.56 ± 0.88, 0.16 ± 0.09, 0.53 ± 0.16, 10.9 ± 3.5 m2 g-1 and 2.5 ± 1.3 m2 g-1, respectively. The scattering measurements performed at MSC were in the medium/upper range of values reported by Andrews et al. (2011) for other mountaintop sites in Europe due to the frequent regional recirculation scenarios (SREG) and Saharan dust episodes (NAF) occurring mostly in spring/summer and causing the presence of polluted layers at the MSC altitude. However, the development of upslope winds and the possible presence of planetary boundary layer air at MSC altitude in summer may also have contributed to the high scattering observed. Under these summer conditions no clear diurnal cycles were observed for the measured extensive aerosol optical properties (σsp, σbsp and σap). Conversely, low σsp and σap at MSC were measured during Atlantic advections (AA) and winter regional anticyclonic episodes (WREG) typically observed during the cold season in the western Mediterranean. Therefore, a season-dependent decrease in the magnitude of aerosol extensive properties was observed when MSC was in the free troposphere, with the highest free-troposphere vs. all-data difference observed in winter and the lowest in spring/summer. The location of MSC station allowed for a reliable characterization of aerosols

  14. Filter-based measurements of UV-vis mass absorption cross sections of organic carbon aerosol from residential biomass combustion: Preliminary findings and sources of uncertainty

    NASA Astrophysics Data System (ADS)

    Pandey, Apoorva; Pervez, Shamsh; Chakrabarty, Rajan K.

    2016-10-01

    Combustion of solid biomass fuels is a major source of household energy in developing nations. Black (BC) and organic carbon (OC) aerosols are the major PM2.5 (particulate matter with aerodynamic diameter smaller than 2.5 μm) pollutants co-emitted during burning of these fuels. While the optical nature of BC is well characterized, very little is known about the properties of light-absorbing OC (LAOC). Here, we report our preliminary findings on the mass-based optical properties of LAOC emitted from the combustion of four commonly used solid biomass fuels - fuel-wood, agricultural residue, dung-cake, and mixed - in traditional Indian cookstoves. As part of a pilot field study conducted in central India, PM2.5 samples were collected on Teflon filters and analyzed for their absorbance spectra in the 300-900 nm wavelengths at 1 nm resolution using a UV-Visible spectrophotometer equipped with an integrating sphere. The mean mass absorption cross-sections (MAC) of the emitted PM2.5 and OC, at 550 nm, were 0.8 and 0.2 m2 g-1, respectively, each with a factor of ~2.3 uncertainty. The mean absorption Ångström exponent (AǺE) values for PM2.5 were 3±1 between 350 and 550 nm, and 1.2±0.1 between 550 and 880 nm. In the 350-550 nm range, OC had an AǺE of 6.3±1.8. The emitted OC mass, which was on average 25 times of the BC mass, contributed over 50% of the aerosol absorbance at wavelengths smaller than 450 nm. The overall OC contribution to visible solar light (300-900 nm) absorption by the emitted particles was 26-45%. Our results highlight the need to comprehensively and accurately address: (i) the climatic impacts of light absorption by OC from cookstove emissions, and (ii) the uncertainties and biases associated with variability in biomass fuel types and combustion conditions, and filter-based measurement artifacts during determination of MAC values.

  15. Bibliography of photoabsorption cross-section data

    NASA Technical Reports Server (NTRS)

    Hudson, R. D.; Kieffer, L. J.

    1970-01-01

    This bibliography contains only references which report a measured or calculated photoabsorption cross section (relative or normalized) in regions of continuous absorption. The bibliography is current as of January 1, 1970.

  16. Dissociative recombination of CH{sub 5}{sup +} and CD{sub 5}{sup +}: Measurement of the product branching fractions and the absolute cross sections, and the breakup dynamics in the CH{sub 3}+H+H product channel

    SciTech Connect

    Kaminska, Magdalena; Zhaunerchyk, Vitali; Vigren, Erik; Danielsson, Mathias; Hamberg, Mathias; Geppert, Wolf D.; Larsson, Mats; Rosen, Stefan; Thomas, Richard D.; Semaniak, Jacek

    2010-06-15

    The dissociative recombination (DR) of CH{sub 5}{sup +} and CD{sub 5}{sup +} has been studied at the heavy-ion storage ring CRYRING. The fragmentation dynamics of the dominant reaction channel CH{sub 3}+H+H has been investigated using an imaging detector. The results indicate that a two-step process via the production of a CH{sub 4} intermediate, which has sufficient energy to fragment further to CH{sub 3}+H, may play an important role. Discrepancies between the present and earlier results obtained from storage ring measurements with those from flowing afterglow experiments are addressed. Newly measured branching fractions in the DR of CD{sub 5}{sup +} show an excellent agreement with branching fractions previously measured for CH{sub 5}{sup +}, and the absolute DR cross sections have been also measured over an interaction energy range between {approx}0 and 0.1 eV for both isotopologs.

  17. Absolute cross section for loss of supercoiled topology induced by 10 eV electrons in highly uniform /DNA/1,3-diaminopropane films deposited on highly ordered pyrolitic graphite

    NASA Astrophysics Data System (ADS)

    Boulanouar, Omar; Fromm, Michel; Bass, Andrew D.; Cloutier, Pierre; Sanche, Léon

    2013-08-01

    It was recently shown that the affinity of doubly charged, 1-3 diaminopropane (Dap2+) for DNA permits the growth on highly ordered pyrolitic graphite (HOPG) substrates, of plasmid DNA films, of known uniform thickness [O. Boulanouar, A. Khatyr, G. Herlem, F. Palmino, L. Sanche, and M. Fromm, J. Phys. Chem. C 115, 21291-21298 (2011)]. Post-irradiation analysis by electrophoresis of such targets confirms that electron impact at 10 eV produces a maximum in the yield of single strand breaks that can be associated with the formation of a DNA- transient anion. Using a well-adapted deterministic survival model for the variation of electron damage with fluence and film thickness, we have determined an absolute cross section for strand-break damage by 10 eV electrons and inelastic scattering attenuation length in DNA-Dap complex films.

  18. Absolute cross sections for near-threshold electron-impact excitation of the 2s{sup 2}S{r_arrow}2p{sup 2}P transition in C{sup 3+}

    SciTech Connect

    Bannister, M.E.; Chung, Y.; Djuric, N.; Wallbank, B.; Woitke, O.; Zhou, S.; Dunn, G.H.; Smith, A.C.

    1998-01-01

    Absolute total cross sections for electron-impact excitation of the 2s{sup 2}S{r_arrow}2p{sup 2}P transition in C{sup 3+} were measured from 7.35 eV to 8.45 eV using the merged electron-ion-beams energy-loss technique. The results settle the discrepancy between two previous experiments using the crossed-beams fluorescence method, being in very good agreement with the older results [P. O. Taylor, D. Gregory, G. H. Dunn, R. A. Phaneuf, and D. H. Crandall, Phys. Rev. Lett. {bold 39}, 1256 (1977)] but less so with the more recent ones [D. W. Savin, L. D. Gardner, D. B. Reisenfeld, A. R. Young, and J. L. Kohl, Phys. Rev. A {bold 51}, 2162 (1995)]. The present measurements are also in good agreement with unitarized Coulomb-Born and close-coupling calculations. {copyright} {ital 1998} {ital The American Physical Society}

  19. Absolute cross section for loss of supercoiled topology induced by 10 eV electrons in highly uniform /DNA/1,3-diaminopropane films deposited on highly ordered pyrolitic graphite

    SciTech Connect

    Boulanouar, Omar; Fromm, Michel; Bass, Andrew D.; Cloutier, Pierre; Sanche, Léon

    2013-08-07

    It was recently shown that the affinity of doubly charged, 1-3 diaminopropane (Dap{sup 2+}) for DNA permits the growth on highly ordered pyrolitic graphite (HOPG) substrates, of plasmid DNA films, of known uniform thickness [O. Boulanouar, A. Khatyr, G. Herlem, F. Palmino, L. Sanche, and M. Fromm, J. Phys. Chem. C 115, 21291–21298 (2011)]. Post-irradiation analysis by electrophoresis of such targets confirms that electron impact at 10 eV produces a maximum in the yield of single strand breaks that can be associated with the formation of a DNA{sup −} transient anion. Using a well-adapted deterministic survival model for the variation of electron damage with fluence and film thickness, we have determined an absolute cross section for strand-break damage by 10 eV electrons and inelastic scattering attenuation length in DNA-Dap complex films.

  20. Average absorption cross-section of the human body measured at 1-12 GHz in a reverberant chamber: results of a human volunteer study

    NASA Astrophysics Data System (ADS)

    Flintoft, I. D.; Robinson, M. P.; Melia, G. C. R.; Marvin, A. C.; Dawson, J. F.

    2014-07-01

    The electromagnetic absorption cross-section (ACS) averaged over polarization and angle-of-incidence of 60 ungrounded adult subjects was measured at microwave frequencies of 1-12 GHz in a reverberation chamber. Average ACS is important in non-ionizing dosimetry and exposure studies, and is closely related to the whole-body averaged specific absorption rate (WBSAR). The average ACS was measured with a statistical uncertainty of less than 3% and high frequency resolution for individuals with a range of body shapes and sizes allowing the statistical distribution of WBSAR over a real population with individual internal and external morphologies to be determined. The average ACS of all subjects was found to vary from 0.15 to 0.4 m2 for an individual subject it falls with frequency over 1-6 GHz, and then rises slowly over the 6-12 GHz range in which few other studies have been conducted. Average ACS and WBSAR are then used as a surrogate for worst-case ACS/WBSAR, in order to study their variability across a real population compared to literature results from simulations using numerical phantoms with a limited range of anatomies. Correlations with body morphological parameters such as height, mass and waist circumference have been investigated: the strongest correlation is with body surface area (BSA) at all frequencies above 1 GHz, however direct proportionality to BSA is not established until above 5 GHz. When the average ACS is normalized to the BSA, the resulting absorption efficiency shows a negative correlation with the estimated thickness of subcutaneous body fat. Surrogate models and statistical analysis of the measurement data are presented and compared to similar models from the literature. The overall dispersion of measured average WBSAR of the sample of the UK population studied is consistent with the dispersion of simulated worst-case WBSAR across multiple numerical phantom families. The statistical results obtained allow the calibration of human exposure

  1. Constraining the N2O5 UV absorption cross-section from spectroscopic trace gas measurements in the tropical mid-stratosphere

    NASA Astrophysics Data System (ADS)

    Kritten, L.; Butz, A.; Chipperfield, M. P.; Dorf, M.; Dhomse, S.; Hossaini, R.; Oelhaf, H.; Prados-Roman, C.; Wetzel, G.; Pfeilsticker, K.

    2014-02-01

    The absorption cross-section of N2O5, σN2O5(λ, T), which is known from laboratory measurements with the uncertainty of a factor of 2 (Table 4-2 in JPL-2011, Sander et al., 2011), was investigated by balloon-borne observations of the relevant trace gases in the tropical mid-stratosphere. The method relies on the observation of the diurnal variation of NO2 supported by detailed photochemical modelling of NOy (NOx(= NO + NO2) + NO3 + 2N2O5 + ClONO2 + HO2NO2 +BrONO2 + HNO3) photochemistry. Simulations are initialised with O3 measured by direct sun observations, the NOy partitioning from MIPAS-B (Michelson Interferometer for Passive Atmospheric Sounding-Balloon) observations in similar air masses at nighttime, and all other relevant species from simulations of the SLIMCAT chemical transport model (CTM). Best agreement between the simulated and observed diurnal increase of NO2 is found if the σN2O5(λ, T) is scaled by a factor of 1.6 ± 0.8 in the UV-C (200-260 nm) and by a factor of 0.9 ± 0.26 in the UV-B/A (260-350 nm), compared to current recommendations. In consequence, at 30 km altitude, the N2O5 lifetime against photolysis becomes a factor of 0.77 shorter at solar zenith angle (SZA) of 30° than using the recommended σN2O5 (λ, T), and stays more or less constant at SZAs of 60°. Our scaled N2O5 photolysis frequency slightly reduces the lifetime (0.2-0.6%) of ozone in the tropical mid- and upper stratosphere, but not to an extent to be important for global ozone.

  2. Constraining the N2O5 UV absorption cross section from spectroscopic trace gas measurements in the tropical mid-stratosphere

    NASA Astrophysics Data System (ADS)

    Kritten, L.; Butz, A.; Chipperfield, M. P.; Dorf, M.; Dhomse, S.; Hossaini, R.; Oelhaf, H.; Prados-Roman, C.; Wetzel, G.; Pfeilsticker, K.

    2014-09-01

    The absorption cross section of N2O5, σN2O5(λ, T), which is known from laboratory measurements with the uncertainty of a factor of 2 (Table 4-2 in (Jet Propulsion Laboratory) JPL-2011; the spread in laboratory data, however, points to an uncertainty in the range of 25 to 30%, Sander et al., 2011), was investigated by balloon-borne observations of the relevant trace gases in the tropical mid-stratosphere. The method relies on the observation of the diurnal variation of NO2 by limb scanning DOAS (differential optical absorption spectroscopy) measurements (Weidner et al., 2005; Kritten et al., 2010), supported by detailed photochemical modelling of NOy (NOx(= NO + NO2) + NO3 + 2N2O5 + ClONO2 + HO2NO2 + BrONO2 + HNO3) photochemistry and a non-linear least square fitting of the model result to the NO2 observations. Simulations are initialised with O3 measured by direct sun observations, the NOy partitioning from MIPAS-B (Michelson Interferometer for Passive Atmospheric Sounding - Balloon-borne version) observations in similar air masses at night-time, and all other relevant species from simulations of the SLIMCAT (Single Layer Isentropic Model of Chemistry And Transport) chemical transport model (CTM). Best agreement between the simulated and observed diurnal increase of NO2 is found if the σN2O5(λ, T) is scaled by a factor of 1.6 ± 0.8 in the UV-C (200-260 nm) and by a factor of 0.9 ± 0.26 in the UV-B/A (260-350 nm), compared to current recommendations. As a consequence, at 30 km altitude, the N2O5 lifetime against photolysis becomes a factor of 0.77 shorter at solar zenith angle (SZA) of 30° than using the recommended σN2O5(λ, T), and stays more or less constant at SZAs of 60°. Our scaled N2O5 photolysis frequency slightly reduces the lifetime (0.2-0.6%) of ozone in the tropical mid- and upper stratosphere, but not to an extent to be important for global ozone.

  3. Mass energy-absorption coefficients and average atomic energy-absorption cross-sections for amino acids in the energy range 0.122-1.330 MeV

    NASA Astrophysics Data System (ADS)

    More, Chaitali V.; Lokhande, Rajkumar M.; Pawar, Pravina. P.

    2016-05-01

    Mass attenuation coefficients of amino acids such as n-acetyl-l-tryptophan, n-acetyl-l-tyrosine and d-tryptophan were measured in the energy range 0.122-1.330 MeV. NaI (Tl) scintillation detection system was used to detect gamma rays with a resolution of 8.2% at 0.662 MeV. The measured attenuation coefficient values were then used to determine the mass energy-absorption coefficients (σa,en) and average atomic energy-absorption cross sections (μen/ρ) of the amino acids. Theoretical values were calculated based on XCOM data. Theoretical and experimental values are found to be in good agreement.

  4. Effective light absorption and absolute electron transport rates in the coral Pocillopora damicornis.

    PubMed

    Szabó, Milán; Wangpraseurt, Daniel; Tamburic, Bojan; Larkum, Anthony W D; Schreiber, Ulrich; Suggett, David J; Kühl, Michael; Ralph, Peter J

    2014-10-01

    Pulse Amplitude Modulation (PAM) fluorometry has been widely used to estimate the relative photosynthetic efficiency of corals. However, both the optical properties of intact corals as well as past technical constrains to PAM fluorometers have prevented calculations of the electron turnover rate of PSII. We used a new Multi-colour PAM (MC-PAM) in parallel with light microsensors to determine for the first time the wavelength-specific effective absorption cross-section of PSII photochemistry, σII(λ), and thus PAM-based absolute electron transport rates of the coral photosymbiont Symbiodinium both in culture and in hospite in the coral Pocillopora damicornis. In both cases, σII of Symbiodinium was highest in the blue spectral region and showed a progressive decrease towards red wavelengths. Absolute values for σII at 440 nm were up to 1.5-times higher in culture than in hospite. Scalar irradiance within the living coral tissue was reduced by 20% in the blue when compared to the incident downwelling irradiance. Absolute electron transport rates of P. damicornis at 440 nm revealed a maximum PSII turnover rate of ca. 250 electrons PSII(-1) s(-1), consistent with one PSII turnover for every 4 photons absorbed by PSII; this likely reflects the limiting steps in electron transfer between PSII and PSI. Our results show that optical properties of the coral host strongly affect light use efficiency of Symbiodinium. Therefore, relative electron transport rates do not reflect the productivity rates (or indeed how the photosynthesis-light response is parameterised). Here we provide a non-invasive approach to estimate absolute electron transport rates in corals.

  5. The use of NO2 absorption cross section temperature sensitivity to derive NO2 profile temperature and stratospheric/tropospheric column partitioning from visible direct sun DOAS measurements

    NASA Astrophysics Data System (ADS)

    Spinei, E.; Cede, A.; Swartz, W. H.; Herman, J.; Mount, G. H.

    2014-06-01

    This paper presents a TEmperature SEnsitivity Method (TESEM) to accurately calculate total vertical NO2 column, atmospheric slant NO2 profile-weighted temperature (T), and to separate stratospheric and tropospheric columns from direct-sun (DS) ground-based measurements using the retrieved T. TESEM is based on Differential Optical Absorption Spectroscopy (DOAS) fitting of the linear temperature-dependent NO2 absorption cross section, σ (T), regression model (Vandaele et al., 2003). The direct result of the DOAS spectral fitting retrieval is NO2 differential slant column density (Δ SCD) at the actual atmospheric NO2 T. Atmospheric NO2 T is determined from the DOAS fitting results after SCD in the reference spectrum is estimated using the Minimum Langley Extrapolation method (MLE). Since NO2 is mostly distributed between the lower troposphere and middle stratosphere and direct sun measurements have almost equal sensitivity to stratospheric and tropospheric absorption at solar zenith angles < 75° with a well known photon path, we assume that the retrieved total column NO2 T can be represented as a sum of the NO2 stratospheric and tropospheric Ts multiplied by the corresponding stratospheric and tropospheric fractions of the total SCDNO2. We use Global Modeling Initiative (GMI) chemistry-transport model (CTM) simulations to evaluate diurnal and seasonal variability of stratospheric and tropospheric NO2 T over two northern middle latitude sites in 2011. GMI simulations reveal that stratospheric NO2 T over northern middle latitudes can be estimated with an error of less than 3 K by the simulated temperature at 27 km from April to October. During November-March months the error can reach as high as 10 K. The tropospheric NO2 T can be approximated by the surface temperature within 3-5 K according to GMI simulations. Traditionally, either σ (NO2) is fitted at a single estimated NO2 T, or two predetermined (stratospheric and tropospheric) temperatures. Use of a single T

  6. Photoionization cross sections and oscillator strengths of neutral cesium

    NASA Astrophysics Data System (ADS)

    Haq, S. U.; Nadeem, Ali; Nawaz, M.

    2012-11-01

    The absolute photoionization cross sections from the 6p 2P1/2 excited state of cesium at threshold and above the threshold region have been measured using the saturation absorption technique. The photoionization cross section at the ionization threshold is determined as 22.6±3.6 Mb, whereas in the region above threshold its value ranges from 22 to 20 Mb for photoelectron energies up to 0.1 eV. A comparison of the photoionization cross sections with earlier reported theoretical and experimental data have been presented and are in good agreement within the uncertainty. In addition, the oscillator strengths of the 6p 2P1/2→n d 2D3/2 (21≤n≤60) Rydberg transitions of cesium have been calibrated using the threshold value of the photoionization cross section. A complete picture of the oscillator strengths from the present work and previously reported data from n=5-60 is presented.

  7. Photoionization research on atomic beams. 2: The photoionization cross section of atomic oxygen

    NASA Technical Reports Server (NTRS)

    Comes, F. J.; Speier, F.; Elzer, A.

    1982-01-01

    An experiment to determine the absolute value of the photo-ionization cross section of atomic oxygen is described. The atoms are produced in an electrical discharge in oxygen gas with 1% hydrogen added. In order to prevent recombination a crossed beam technique is employed. The ions formed are detected by a time-of-flight mass spectrometer. The concentration of oxygen atoms in the beam is 57%. The measured photoionization cross section of atomic oxygen is compared with theoretical data. The results show the participation of autoionization processes in ionization. The cross section at the autoionizing levels detected is considerably higher than the absorption due to the unperturbed continuum. Except for wavelengths where autoionization occurs, the measured ionization cross section is in fair agreement with theory. This holds up to 550 A whereas for shorter wavelengths the theoretical values are much higher.

  8. Absolute cross sections with polarization effects in Ne{sup {asterisk}}(2p{sup 5}3p)+He collisions: A detailed comparison between theory and experiment

    SciTech Connect

    Bahrim, C. |; Kucal, H.; Masnou-Seeuws, F.

    1997-08-01

    Quantal calculations are presented for intramultiplet mixing collisions of Ne{sup {asterisk}}(2p{sup 5}3p) with He({sup 1}S{sub 0}) in the 60{endash}1250 meV collision energy range. The coupled equations are solved in a diabatic representation where the coupling terms are obtained using the model potential calculations of Hennecart and Masnou-Seeuws [J. Phys. B {bold 18}, 657 (1985)] for the interaction of the Ne{sup {asterisk}} outer electron with the two cores and values fitted on the spectroscopic data of Dabrowski and Herzberg [Mol. Spectrosc. {bold 73}, 183 (1978)] for the core-core interaction. An extensive comparison with the experimental data of the Eindhoven group is presented for absolute polarized cross sections and anisotropy parameters. Very good agreement is obtained with thermal energy data of Manders {ital et al.} [Phys. Rev. A {bold 39}, 4467 (1989)], while the systematic 30{endash}40{percent} discrepancy with superthermal data of Boom {ital et al.} [Phys. Rev. A {bold 49}, 4660 (1994)] might be attributed to a calibration problem in the experiment rather than to an inaccuracy in the long-range potentials. {copyright} {ital 1997} {ital The American Physical Society}

  9. Two-photon absorption cross sections within equation-of-motion coupled-cluster formalism using resolution-of-the-identity and Cholesky decomposition representations: Theory, implementation, and benchmarks

    NASA Astrophysics Data System (ADS)

    Nanda, Kaushik D.; Krylov, Anna I.

    2015-02-01

    The equation-of-motion coupled-cluster (EOM-CC) methods provide a robust description of electronically excited states and their properties. Here, we present a formalism for two-photon absorption (2PA) cross sections for the equation-of-motion for excitation energies CC with single and double substitutions (EOM-CC for electronically excited states with single and double substitutions) wave functions. Rather than the response theory formulation, we employ the expectation-value approach which is commonly used within EOM-CC, configuration interaction, and algebraic diagrammatic construction frameworks. In addition to canonical implementation, we also exploit resolution-of-the-identity (RI) and Cholesky decomposition (CD) for the electron-repulsion integrals to reduce memory requirements and to increase parallel efficiency. The new methods are benchmarked against the CCSD and CC3 response theories for several small molecules. We found that the expectation-value 2PA cross sections are within 5% from the quadratic response CCSD values. The RI and CD approximations lead to small errors relative to the canonical implementation (less than 4%) while affording computational savings. RI/CD successfully address the well-known issue of large basis set requirements for 2PA cross sections calculations. The capabilities of the new code are illustrated by calculations of the 2PA cross sections for model chromophores of the photoactive yellow and green fluorescent proteins.

  10. Two-photon absorption cross sections within equation-of-motion coupled-cluster formalism using resolution-of-the-identity and Cholesky decomposition representations: Theory, implementation, and benchmarks

    SciTech Connect

    Nanda, Kaushik D.; Krylov, Anna I.

    2015-02-14

    The equation-of-motion coupled-cluster (EOM-CC) methods provide a robust description of electronically excited states and their properties. Here, we present a formalism for two-photon absorption (2PA) cross sections for the equation-of-motion for excitation energies CC with single and double substitutions (EOM-CC for electronically excited states with single and double substitutions) wave functions. Rather than the response theory formulation, we employ the expectation-value approach which is commonly used within EOM-CC, configuration interaction, and algebraic diagrammatic construction frameworks. In addition to canonical implementation, we also exploit resolution-of-the-identity (RI) and Cholesky decomposition (CD) for the electron-repulsion integrals to reduce memory requirements and to increase parallel efficiency. The new methods are benchmarked against the CCSD and CC3 response theories for several small molecules. We found that the expectation-value 2PA cross sections are within 5% from the quadratic response CCSD values. The RI and CD approximations lead to small errors relative to the canonical implementation (less than 4%) while affording computational savings. RI/CD successfully address the well-known issue of large basis set requirements for 2PA cross sections calculations. The capabilities of the new code are illustrated by calculations of the 2PA cross sections for model chromophores of the photoactive yellow and green fluorescent proteins.

  11. International Evaluation of Neutron Cross Section Standards

    NASA Astrophysics Data System (ADS)

    Carlson, A. D.; Pronyaev, V. G.; Smith, D. L.; Larson, N. M.; Chen, Zhenpeng; Hale, G. M.; Hambsch, F.-J.; Gai, E. V.; Oh, Soo-Youl; Badikov, S. A.; Kawano, T.; Hofmann, H. M.; Vonach, H.; Tagesen, S.

    2009-12-01

    Neutron cross section standards are the basis for the determination of most neutron cross sections. They are used for both measurements and evaluations of neutron cross sections. Not many cross sections can be obtained absolutely - most cross sections are measured relative to the cross section standards and converted using evaluations of the standards. The previous complete evaluation of the neutron cross section standards was finished in 1987 and disseminated as the NEANDC/INDC and ENDF/B-VI standards. R-matrix model fits for the light elements and non-model least-squares fits for all the cross sections in the evaluation were the basis of the combined fits for all of the data. Some important reactions and constants are not standards, but they assist greatly in the determination of the standard cross sections and reduce their uncertainties - these data were also included in the combined fits. The largest experimental database used in the evaluation was prepared by Poenitz and included about 400 sets of experimental data with covariance matrices of uncertainties that account for all cross-energy, cross-reaction and cross-material correlations. For the evaluation GMA, a least-squares code developed by Poenitz, was used to fit all types of cross sections (absolute and shape), their ratios, spectrum-averaged cross sections and thermal constants in one full analysis. But, the uncertainties derived in this manner, and especially those obtained in the R-matrix model fits, have been judged to be too low and unrealistic. These uncertainties were substantially increased prior to their release in the recommended data files of 1987. Modified percentage uncertainties were reassigned by the United States Cross Section Evaluation Working Group's Standards Subcommittee for a wide range of energies, and no covariance (or correlation) matrices were supplied at that time. The need to re-evaluate the cross section standards is based on the appearance of a significant amount of precise

  12. Photodisintegration Cross Section of 241Am

    NASA Astrophysics Data System (ADS)

    Tonchev, A. P.; Hammond, S.; Howell, C. R.; Huibregtse, C.; Hutcheson, A.; Karwowski, H. J.; Kelley, J. H.; Kwan, E.; Rusev, G.; Tornow, W.; Vieira, D. J.; Wilhelmy, J. B.

    2009-03-01

    The photodisintegration cross section of radioactive 241Am has been obtained for the first time using monoenergetic γ-ray beams from the HIγS facility. The induced activity of 240Am produced via the 241Am(γ,n) reaction in the γ-ray energy range from 9.5 to 16 MeV was measured by the activation technique utilizing high resolution HPGe detectors. The 241Am(γ,n) cross section was determined both by measuring the absolute γ-ray flux and by comparison to the 197Au(γ,n) and 58Ni(γ,n) cross section standards. The experimental data for the 241Am(γ,n) reaction in the giant dipole resonance energy region is compared with statistical nuclear-model calculations.

  13. Radar cross section of insects

    NASA Astrophysics Data System (ADS)

    Riley, J. R.

    1985-02-01

    X-band measurements of radar cross section as a function of the angle between insect body axis and the plane of polarization are presented. A finding of particular interest is that in larger insects, maximum cross section occurs when the E-vector is perpendicular to the body axis. A new range of measurements on small insects (aphids, and planthoppers) is also described, and a comprehensive summary of insect cross-section data at X-band is given.

  14. Total quadruple photoionization cross section of beryllium

    SciTech Connect

    Emmanouilidou, Agapi

    2007-11-15

    In a quasiclassical framework, we formulate the quadruple ionization by single-photon absorption of the Coulomb five-body problem. We present the quadruple photoionization total cross section of the ground state of beryllium for energies up to 620 eV. Our results for energies close to threshold are in agreement with the Wannier threshold law for four-electron escape. In addition, the agreement of our results with a shape formula provides support for the overall shape of our total quadruple cross section. Finally, we find that the photon energy where the maximum of the total photoionization cross section occurs for single, double, triple, and quadruple photoionization of H, He, Li, and Be, respectively, seems to follow a linear relation with the threshold energy for complete breakup of the respective element.

  15. Cross Section and Analyzing Power Measurements for Neutron Scattering from Aluminum and Cobalt and Spin - Cross Section Calculations

    NASA Astrophysics Data System (ADS)

    Nagadi, Mahmoud Mohamud

    Differential cross sections and analyzing power data have been measured for ^{27} Al and ^{59}Co at 15.5 MeV. Cross section data was also measured for ^{59}Co at 10, 12, 14, 17, and 19 MeV using standard time-of-flight techniques at the Triangle Universities Nuclear Laboratory (TUNL). Absolute normalization of the sigma(theta) data was performed using n-p scattering measurements. Both sigma(theta) and rm A_{y}(theta) were corrected for finite geometry, attenuation, relative efficiency, and multiple scattering effects using Monte Carlo techniques. A large data base was formed from our data and the existing data on ^{27}Al and ^{59}Co. This data base was used to develop a Dispersive Optical Model (DOM) and a Coupled Channels Model (CCM). The DOM model describes the data quite well above 8 MeV for ^{27 }Al and ^{59}Co. However, for data below 8 MeV the model is not as satisfactory, perhaps because of angular momentum l-dependencies in the absorptive potential. The CCM improved the description of the data over the DOM, but still does not describe the data well at low energies. The DOM and CCM for ^{27} Al and ^{59}Co were used to describe the spin-spin cross section data for ^{27}Al and ^{59}Co. We obtained a good fit for the spin-spin cross section with both the DOM and CCM with the spin-spin real surface parameters of V _{rm ss} = 0.80 MeV, r _{rm ss} = 1.00 fm and a _{rm ss} = 0.654 for both ^{27}Al and ^{59}Co. A surprising relation between the spin-spin cross section and the derivative of the total cross section with respect to energy, was discovered: sigma_{ss } = c {dsigma_{T} over dE} where c is a constant related to the slope of the real central potential and spin-spin potential strength. This observation is not yet understood.

  16. Cross sections relevant to gamma ray astronomy

    NASA Technical Reports Server (NTRS)

    Dyer, P.; Bodansky, D.; Maxson, D. R.

    1978-01-01

    Gamma-ray production cross sections were measured for protons and alpha particles incident on targets consisting of nuclei of high cosmic abundance: C-12, N-14, O-16, Ne-20, Mg-24, Si-28 and Fe-56. Solid or gaseous targets were bombarded by monoenergetic beams of protons and alpha particles, and gamma rays were detected by two Ge(Li) detectors. The proton energy for each target was varied from threshold to about 24 MeV (lab); for alphas the range was from threshold to about 27 MeV. For most transitions, it was possible to measure the total cross section by placing the detectors at 30.5 deg and 109.9 deg where the fourth-order Legendre polynomial is zero. For the case of the 16O (E sub gamma = 6.13 MeV, multipolarity E3) cross sections, yields were measured at four angles. Absolute cross sections were obtained by integrating the beam current and by measuring target thicknesses and detector efficiencies. The Ge(Li) detector resolution was a few keV (although the peak widths were greater, due to Doppler broadening).

  17. Maternal post-absorptive leucine kinetics during late pregnancy in US women with HIV taking antiretroviral therapy: a cross-sectional pilot study

    PubMed Central

    Cade, W. Todd; Singh, Gautam K.; Holland, Mark R.; Reeds, Dominic N.; Overton, E. Turner; Cibulka, Nancy; Bahow, Karen; Presti, Rachel; Stephens, Andrea; Cahill, Alison G.

    2015-01-01

    Background Despite the success of combination antiretroviral therapy (cART) for the prevention of mother to child transmission of HIV, infants exposed to cART in utero frequently are born smaller and have mild cardiac abnormalities. The mechanisms responsible for lower birth weight and cardiac abnormalities in children exposed to cART are unclear but could be related to dysregulation of maternal amino acid metabolism during pregnancy. Previous data in HIV(−) women have shown a relationship between abnormal maternal protein metabolism during pregnancy and low infant birth weight and animal data demonstrate a relationship between altered maternal protein metabolism and increased risk for offspring cardiovascular abnormalities. Objective The objectives of this study were to: characterize post-absorptive maternal leucine kinetics during late pregnancy and examine the relationships between maternal leucine kinetics and offspring birth weight and cardiac function. Design Post-absorptive maternal leucine kinetics (evaluated by using stable isotope tracer methodology) in 16 HIV(+) women receiving cART and 14 HIV(−) US women during the 3rd trimester of pregnancy were compared. Relationships between post-absorptive maternal leucine kinetics, cardiac function (echocardiography) and birth weight were statistically examined. Results Maternal plasma leucine concentration (HIV(−): 82.8 ± 10.7 vs. HIV(+): 72.3 ± 13.5 μM, p=0.06) and leucine oxidation rate (HIV(−): 6.1 ± 1.6 vs. HIV(+): 4.9 ± 1.8 μmol/kgBW/min, p=0.03) were lower in HIV+ women compared to controls. Total leucine turnover rate, non-oxidative leucine disposal rate and post-absorptive maternal glucose and palmitate kinetics did not differ between groups. Left ventricular fractional shortening tended to be lower in children born to HIV(+) compared to controls (HIV(−): 42 ± 1 vs. HIV+: 36 ± 5 %, p=0.08) and associated with lower maternal plasma leucine concentration (r= 0.43, p=0.08). Conclusions

  18. Temperature dependence of the NO3 absorption cross-section above 298 K and determination of the equilibrium constant for NO3 + NO2 <--> N2O5 at atmospherically relevant conditions.

    PubMed

    Osthoff, Hans D; Pilling, Michael J; Ravishankara, A R; Brown, Steven S

    2007-11-21

    The reaction NO3 + NO2 <--> N2O5 was studied over the 278-323 K temperature range. Concentrations of NO3, N2O5, and NO2 were measured simultaneously in a 3-channel cavity ring-down spectrometer. Equilibrium constants were determined over atmospherically relevant concentration ranges of the three species in both synthetic samples in the laboratory and ambient air samples in the field. A fit to the laboratory data yielded Keq = (5.1 +/- 0.8) x 10(-27) x e((10871 +/- 46)/7) cm3 molecule(-1). The temperature dependence of the NO3 absorption cross-section at 662 nm was investigated over the 298-388 K temperature range. The line width was found to be independent of temperature, in agreement with previous results. New data for the peak cross section (662.2 nm, vacuum wavelength) were combined with previous measurements in the 200 K-298 K region. A least-squares fit to the combined data gave sigma = [(4.582 +/- 0.096) - (0.00796 +/- 0.00031) x T] x 10(-17) cm2 molecule(-1).

  19. The measurement of absolute absorption of millimeter radiation in gases - The absorption of CO and O2

    NASA Technical Reports Server (NTRS)

    Read, William G.; Cohen, Edward A.; Pickett, Herbert M.; Hillig, Kurt W., II

    1988-01-01

    An apparatus is described that will measure absolute absorption of millimeter radiation in gases. The method measures the change in the quality factor of a Fabry-Perot resonator with and without gas present. The magnitude of the change is interpreted in terms of the absorption of the lossy medium inside the resonator. Experiments have been performed on the 115-GHz CO line and the 119-GHz O2 line at two different temperatures to determine the linewidth parameter and the peak absorption value. These numbers can be combined to give the integrated intensity which can be accurately calculated from results of spectroscopy measurements. The CO results are within 2 percent percent of theoretically predicted valves. Measurements on O2 have shown that absorption can be measured as accurately as 0.5 dB/km with this technique. Results have been obtained for oxygen absolute absorption in the 60-80-GHz region.

  20. UV-Vis Ratiometric Resonance Synchronous Spectroscopy for Determination of Nanoparticle and Molecular Optical Cross Sections.

    PubMed

    Nettles, Charles B; Zhou, Yadong; Zou, Shengli; Zhang, Dongmao

    2016-03-01

    Demonstrated herein is a UV-vis Ratiometric Resonance Synchronous Spectroscopic (R2S2, pronounced as "R-two-S-two" for simplicity) technique where the R2S2 spectrum is obtained by dividing the resonance synchronous spectrum of a NP-containing solution by the solvent resonance synchronous spectrum. Combined with conventional UV-vis measurements, this R2S2 method enables experimental quantification of the absolute optical cross sections for a wide range of molecular and nanoparticle (NP) materials that range optically from pure photon absorbers or scatterers to simultaneous photon absorbers and scatterers, simultaneous photon absorbers and emitters, and all the way to simultaneous photon absorbers, scatterers, and emitters in the UV-vis wavelength region. Example applications of this R2S2 method were demonstrated for quantifying the Rayleigh scattering cross sections of solvents including water and toluene, absorption and resonance light scattering cross sections for plasmonic gold nanoparticles, and absorption, scattering, and on-resonance fluorescence cross sections for semiconductor quantum dots (Qdots). On-resonance fluorescence quantum yields were quantified for the model molecular fluorophore Eosin Y and fluorescent Qdots CdSe and CdSe/ZnS. The insights and methodology presented in this work should be of broad significance in physical and biological science research that involves photon/matter interactions.

  1. Neutrino cross-sections: Experiments

    SciTech Connect

    Sánchez, F.

    2015-07-15

    Neutrino-nucleus cross-sections are as of today the main source of systematic errors for oscillation experiments together with neutrino flux uncertainties. Despite recent experimental and theoretical developments, future experiments require even higher precisions in their search of CP violation. We will review the experimental status and explore possible future developments required by next generation of experiments.

  2. Precision measurements of photoabsorption cross sections of Ar, Kr, Xe, and selected molecules at 58.4, 73.6, and 74.4 nm

    NASA Technical Reports Server (NTRS)

    Samson, James A. R.; Yin, Lifeng

    1989-01-01

    Absolute absorption cross sections have been measured for the rare gases at 58.43, 73.59, and 74.37 nm with an accuracy of + or - 0.8 percent. For the molecules H2, N2, O2, CO, N2O, CO2, and CH4, precision measurements were made at 58.43 nm with an accuracy of + or - 0.8 percent. Molecular absorption cross sections are also reported at 73.59 and 74.37 nm. However, in the vicinity of these wavelengths most molecules exhibit considerable structure, and cross sections measured at these wavelengths may depend on the widths and the amounts of self-reversal of these resonance lines. A detailed discussion is given of the systematic errors encountered with the double-ion chamber used in the cross-sectional measurements. Details are also given of precision pressure measurements.

  3. Hydroxyl radical reaction rate coefficients as a function of temperature and IR absorption cross sections for CF3CH=CH2 (HFO-1243zf), potential replacement of CF3CH2F (HFC-134a).

    PubMed

    González, Sergio; Jiménez, Elena; Ballesteros, Bernabé; Martínez, Ernesto; Albaladejo, José

    2015-04-01

    CF3CH=CH2 (hydrofluoroolefin, HFO-1243zf) is a potential replacement of high global-warming potential (GWP) hydrofluorocarbon (HFC-134a, CF3CFH2). Both the atmospheric lifetime and the radiative efficiency of HFO-1243zf are parameters needed for estimating the GWP of this species. Therefore, the aim of this work is (i) to estimate the atmospheric lifetime of HFO-1243zf from the reported OH rate coefficients, k OH, determined under tropospheric conditions and (ii) to calculate its radiative efficiency from the reported IR absorption cross sections. The OH rate coefficient at 298 K also allows the estimation of the photochemical ozone creation potential (ε(POCP)). The pulsed laser photolysis coupled to a laser-induced fluorescence technique was used to determine k OH for the reaction of OH radicals with HFO-1243zf as a function of pressure (50-650 Torr of He) and temperature (263-358 K). Gas-phase IR spectra of HFO-1243zf were recorded at room temperature using a Fourier transform IR spectrometer between 500 and 4,000 cm(-1). At all temperatures, k OH did not depend on bath gas concentration (i.e., on the total pressure between 50 and 650 Torr of He). A slight but noticeable T dependence of k OH was observed in the temperature range investigated. The observed behavior is well described by the following Arrhenius expression: k OH(T) = (7.65 ± 0.26) × 10(-13) exp [(165 ± 10) / T] cm(3) molecule(-1) s(-1). Negligible IR absorption of HFO-1243zf was observed at wavenumbers greater than 1,700 cm(-1). Therefore, IR absorption cross sections, [Formula: see text], were determined in the 500-1,700 cm(-1) range. Integrated [Formula: see text] were determined between 650 and 1,800 cm(-1) for comparison purposes. The main diurnal removal pathway for HFO-1243zf is the reaction with OH radicals, which accounts for 64% of the overall loss by homogeneous reactions at 298 K. Globally, the lifetime due to OH reaction (τ OH) was estimated to be 8.7 days under

  4. Hydroxyl radical reaction rate coefficients as a function of temperature and IR absorption cross sections for CF3CH=CH2 (HFO-1243zf), potential replacement of CF3CH2F (HFC-134a).

    PubMed

    González, Sergio; Jiménez, Elena; Ballesteros, Bernabé; Martínez, Ernesto; Albaladejo, José

    2015-04-01

    CF3CH=CH2 (hydrofluoroolefin, HFO-1243zf) is a potential replacement of high global-warming potential (GWP) hydrofluorocarbon (HFC-134a, CF3CFH2). Both the atmospheric lifetime and the radiative efficiency of HFO-1243zf are parameters needed for estimating the GWP of this species. Therefore, the aim of this work is (i) to estimate the atmospheric lifetime of HFO-1243zf from the reported OH rate coefficients, k OH, determined under tropospheric conditions and (ii) to calculate its radiative efficiency from the reported IR absorption cross sections. The OH rate coefficient at 298 K also allows the estimation of the photochemical ozone creation potential (ε(POCP)). The pulsed laser photolysis coupled to a laser-induced fluorescence technique was used to determine k OH for the reaction of OH radicals with HFO-1243zf as a function of pressure (50-650 Torr of He) and temperature (263-358 K). Gas-phase IR spectra of HFO-1243zf were recorded at room temperature using a Fourier transform IR spectrometer between 500 and 4,000 cm(-1). At all temperatures, k OH did not depend on bath gas concentration (i.e., on the total pressure between 50 and 650 Torr of He). A slight but noticeable T dependence of k OH was observed in the temperature range investigated. The observed behavior is well described by the following Arrhenius expression: k OH(T) = (7.65 ± 0.26) × 10(-13) exp [(165 ± 10) / T] cm(3) molecule(-1) s(-1). Negligible IR absorption of HFO-1243zf was observed at wavenumbers greater than 1,700 cm(-1). Therefore, IR absorption cross sections, [Formula: see text], were determined in the 500-1,700 cm(-1) range. Integrated [Formula: see text] were determined between 650 and 1,800 cm(-1) for comparison purposes. The main diurnal removal pathway for HFO-1243zf is the reaction with OH radicals, which accounts for 64% of the overall loss by homogeneous reactions at 298 K. Globally, the lifetime due to OH reaction (τ OH) was estimated to be 8.7 days under

  5. Absorption by ground-state lead atoms of the 283. 3-nm resonant line from a lead hollow cathode lamp. An absolute number density calibration

    SciTech Connect

    Simons, J.W. ); Oldenborg, R.C.; Baughcum, S.L. )

    1989-10-19

    An accurate absolute number density calibration curve for absorption by gaseous lead atoms of the 283.3-nm resonant line from a typical lead hollow cathode lamp is reported. This calibration shows the usual curvature in the Beer-Lambert plot for atomic absorption at moderate to high absorbances that is commonly attributed to self-absorption leading to line reversal in the source and/or preferential absorption at the line center when the absorber temperature is not much greater than the source Doppler temperature. A theoretical calculation utilizing a Doppler-limited Fourier transform spectrum of the 283.3-nm emission from the lamp and a tabulated value of the absorption cross section and accounting for the isotopic and nuclear hyperfine components in both the emission and absorption due to naturally occurring lead quantitatively reproduces the experimental calibration curve without any parameter adjustments. It is found that the curvature in the Beer-Lambert plot has more to do with the fact that the absorbing and emitting atoms are a mixture of isotopes giving several isotopic and nuclear hyperfine transitions at slightly different frequencies than it does with preferential absorption at line centers.

  6. Analytical approximations for x-ray cross sections III

    SciTech Connect

    Biggs, F; Lighthill, R

    1988-08-01

    This report updates our previous work that provided analytical approximations to cross sections for both photoelectric absorption of photons by atoms and incoherent scattering of photons by atoms. This representation is convenient for use in programmable calculators and in computer programs to evaluate these cross sections numerically. The results apply to atoms of atomic numbers between 1 and 100 and for photon energiesgreater than or equal to10 eV. The photoelectric cross sections are again approximated by four-term polynomials in reciprocal powers of the photon energy. There are now more fitting intervals, however, than were used previously. The incoherent-scattering cross sections are based on the Klein-Nishina relation, but use simpler approximate equations for efficient computer evaluation. We describe the averaging scheme for applying these atomic results to any composite material. The fitting coefficients are included in tables, and the cross sections are shown graphically. 100 graphs, 1 tab.

  7. On the cyclo-synchrotron cross-section

    NASA Astrophysics Data System (ADS)

    Gliozzi, M.; Bodo, G.; Ghisellini, G.; Trussoni, E.

    1996-06-01

    The study of the synchrotron and cyclotron absorption processes and their relative cross-sections, recently analysed by Ghisellini & Svensson, is extended to the case of photons propagating along the direction of the magnetic field. In the relativistic regime we follow a quantum approach, which requires first the derivation of the particle emissivity for the assumed configuration. The expression for the cross-section coincides with that obtained through a classical treatment of the problem in the non-relativistic regime. In the frequency range where absorption is important, the cross-section is larger than the Thomson cross-section by several orders of magnitude, implying a strong coupling between radiation and magnetized plasma. The possible atrophysical implications of this process are briefly discussed; in particular, in a magnetized plasma the Eddington luminosity for synchrotron interaction can be much lower than the standard value.

  8. Excited state cross sections for Er-doped glasses

    NASA Astrophysics Data System (ADS)

    Zemon, Stanley A.; Lambert, Gary M.; Miniscalco, William J.; Davies, Richard W.; Hall, Bruce T.; Folweiler, Robert C.; Wei, Ta-Sheng; Andrews, Leonard J.; Singh, Mahendra P.

    1991-01-01

    Excited-state-absorption (ESA) cross sections were determined for the region between 760 and 900 nm for Er-doped fluorophosphate phosphate and silicate glasses. Measurements were performed on multimode fibers pumping at 647 nm with powers 1 . 5 Wto invert the population into the saturation regime. Over much of the 800-nm band ground-state-absorption (GSA) cross sections are equal to or greater than ESA cross sections. For comparison ESA was also measured for singlemode Al/P-doped silica fiber. The cross sections were incorporated into an amplifier model and the phosphate and fluorophosphate glasses were found to provide higher gain than silica for pumping in the 800-nm band. Photoexcited fluorozirconates were found to have substantial populations in the first four excited states and ESA transitions originating from these states are identified.

  9. Partial (gamma)-Ray Cross Sections for the Reaction 239Pu(n,2n(gamma)i) and the 239Pu(n,2n) Cross Section

    SciTech Connect

    Beacker, J.A.; Bernstein, L.A.; Younes, W.; McNabb, D.P.; Garrett, P.E.; Archer, D.; McGrath, C.A.; Stoyer, M.A.; Chen, H.; Ormand, W.E.; Nelson, R.O.; Chadwick, M.B.; Johns, G.D.; Drake, D.; Young, P.G.; Devlin, M.; Fotiades, N.; Wilburn, W.S.

    2001-09-14

    Absolute partial {gamma}-ray cross sections for production of discrete {gamma} rays in the {sup 239}Pu(n,2n{gamma}i){sup 238}Pu reaction have been measured. The experiments were performed at LANSCE/WNR on the 60R flight line. Reaction {gamma}-rays were measured using the large-scale Compton-suppressed array of Ge detectors, GEANIE. The motivation for this experiment, an overview of the partial {gamma}-ray cross-section measurement, and an introduction to the main experimental issues will be presented. The energy resolution of the Ge detectors allowed identification of reaction {gamma} rays above the background of sample radioactivity and fission {gamma} rays. The use of planar Ge detectors with their reduced sensitivity to neutron interactions and improved line shape was also important to the success of this experiment. Absolute partial {gamma}-ray cross sections are presented for the 6{sub 1}{sup +} {yields} 4{sub 1}{sup +} member of the ground state rotational band in {sup 238}Pu, together with miscellaneous other {gamma}-ray partial cross sections. The n,2n reaction cross section shape and magnitude as a function of neutron energy was extracted from these partial cross sections using nuclear modeling (enhanced Hauser-Feshbach) to relate partial {gamma}-ray cross sections to the n,2n cross section. The critical nuclear modeling issue is the ratio of a partial cross section to the reaction channel cross section, and not the prediction of the absolute magnitude.

  10. The use of NO2 absorption cross section temperature sensitivity to derive NO2 profile temperature and stratospheric-tropospheric column partitioning from visible direct-sun DOAS measurements

    NASA Astrophysics Data System (ADS)

    Spinei, E.; Cede, A.; Swartz, W. H.; Herman, J.; Mount, G. H.

    2014-12-01

    This paper presents a temperature sensitivity method (TESEM) to accurately calculate total vertical NO2 column, atmospheric slant NO2 profile-weighted temperature (T), and to separate stratospheric and tropospheric columns from direct-sun (DS), ground-based measurements using the retrieved T. TESEM is based on differential optical absorption spectroscopy (DOAS) fitting of the linear temperature-dependent NO2 absorption cross section, σ (T), regression model (Vandaele et al., 2003). Separation between stratospheric and tropospheric columns is based on the primarily bimodal vertical distribution of NO2 and an assumption that stratospheric effective temperature can be represented by temperature at 27 km ± 3 K, and tropospheric effective temperature is equal to surface temperature within 3-5 K. These assumptions were derived from the Global Modeling Initiative (GMI) chemistry-transport model (CTM) simulations over two northern midlatitude sites in 2011. TESEM was applied to the Washington State University Multi-Function DOAS instrument (MFDOAS) measurements at four midlatitude locations with low and moderate NO2 anthropogenic emissions: (1) the Jet Propulsion Laboratory's Table Mountain Facility (JPL-TMF), CA, USA (34.38° N/117.68° W); (2) Pullman, WA, USA (46.73° N/117.17° W); (3) Greenbelt, MD, USA (38.99° N/76.84° W); and (4) Cabauw, the Netherlands (51.97° N/4.93° E) during July 2007, June-July 2009, July-August and October 2011, November 2012-May 2013, respectively. NO2 T and total, stratospheric, and tropospheric NO2 vertical columns were determined over each site.

  11. Recommended Dosimetry Cross Section Compendium.

    1994-07-11

    Version 00 The data is recommended for spectrum determination applications and for the prediction of neutron activation of typical radiation sensor materials. The library has been tested for consistency of the cross sections in a wide variety of neutron environments. The results and cautions from this testing have been documented. The data has been interfaced with radiation transport codes, such as TWODANT-SYS (CCC-547) and MCNP (CCC-200), in order to compare calculated and measured activities formore » benchmark reactor experiments.« less

  12. Simultaneous evaluation of interrelated cross sections by generalized least-squares and related data file requirements

    SciTech Connect

    Poenitz, W.P.

    1984-10-25

    Though several cross sections have been designated as standards, they are not basic units and are interrelated by ratio measurements. Moreover, as such interactions as /sup 6/Li + n and /sup 10/B + n involve only two and three cross sections respectively, total cross section data become useful for the evaluation process. The problem can be resolved by a simultaneous evaluation of the available absolute and shape data for cross sections, ratios, sums, and average cross sections by generalized least-squares. A data file is required for such evaluation which contains the originally measured quantities and their uncertainty components. Establishing such a file is a substantial task because data were frequently reported as absolute cross sections where ratios were measured without sufficient information on which reference cross section and which normalization were utilized. Reporting of uncertainties is often missing or incomplete. The requirements for data reporting will be discussed.

  13. Time-resolved postdischarge absolute silicon monoxide density measurement by resonant absorption spectroscopy in a nonthermal atmospheric plasma

    SciTech Connect

    Motret, Olivier; Coursimault, Fabien; Pouvesle, Jean-Michel

    2006-11-01

    In this study we present the technique of resonant absorption spectroscopy diagnostic developed to estimate the density of silicon monoxide (SiO) molecules during the postdischarge of an atmospheric dielectric barrier discharge plasma. The ultraviolet (0,0) rovibrational band of the SiO(A {sup 1}{pi}-X {sup 1}{sigma}{sup +}) electronic transition was investigated. Effective values of absorption coefficient and absorption cross section for the rotational transitions under consideration were calculated. The SiO concentration was estimated by comparison between experimental and computed spectra. The self-absorption in the probe reactor was taken into account in the computed spectra.

  14. Electron-Impact Ionization Cross Section Database

    National Institute of Standards and Technology Data Gateway

    SRD 107 Electron-Impact Ionization Cross Section Database (Web, free access)   This is a database primarily of total ionization cross sections of molecules by electron impact. The database also includes cross sections for a small number of atoms and energy distributions of ejected electrons for H, He, and H2. The cross sections were calculated using the Binary-Encounter-Bethe (BEB) model, which combines the Mott cross section with the high-incident energy behavior of the Bethe cross section. Selected experimental data are included.

  15. Terahertz radar cross section measurements.

    PubMed

    Iwaszczuk, Krzysztof; Heiselberg, Henning; Jepsen, Peter Uhd

    2010-12-01

    We perform angle- and frequency-resolved radar cross section (RCS) measurements on objects at terahertz frequencies. Our RCS measurements are performed on a scale model aircraft of size 5-10 cm in polar and azimuthal configurations, and correspond closely to RCS measurements with conventional radar on full-size objects. The measurements are performed in a terahertz time-domain system with freely propagating terahertz pulses generated by tilted pulse front excitation of lithium niobate crystals and measured with sub-picosecond time resolution. The application of a time domain system provides ranging information and also allows for identification of scattering points such as weaponry attached to the aircraft. The shapes of the models and positions of reflecting parts are retrieved by the filtered back projection algorithm.

  16. Measurement of the 242Pu neutron capture cross section

    NASA Astrophysics Data System (ADS)

    Buckner, M. Q.; Wu, C. Y.; Henderson, R. A.; Bucher, B.; Bredeweg, T. A.; Baramsai, B.; Couture, A.; Jandel, M.; Mosby, S.; O'Donnell, J. M.; Ullmann, J. L.; Chyzh, A.; Dance Collaboration

    2015-10-01

    Precision (n,f) and (n, γ) cross sections are important for the network calculations of the radiochemical diagnostic chain for the U.S. DOE's Stockpile Stewardship Program. 242Pu(n, γ) cross section is relevant to the network calculations of Pu and Am. Additionally, new reactor concepts have catalyzed considerable interest in the measurement of improved cross sections for neutron-induced reactions on key actinides. To date, little or no experimental data has been reported on 242Pu(n, γ) for incident neutron energy below 50 keV. A new measurement of the 242Pu(n, γ) reaction was performed with the DANCE together with an improved PPAC for fission-fragment detection at LANSCE during FY14. The relative scale of the 242Pu(n, γ) cross section spans four orders of magnitude for incident neutron energies from thermal to ~ 30 keV. The absolute scale of the 242Pu(n, γ) cross section is set according to the measured 239Pu(n,f) resonance at 7.8 eV; the target was spiked with 239Pu for this measurement. The absolute 242Pu(n, γ) neutron capture cross section is ~ 30% higher than the cross section reported in ENDF for the 2.7 eV resonance. Latest results to be reported. Funded by U.S. DOE Contract No. DE-AC52-07NA27344 (LLNL) and DE-AC52-06NA25396 (LANL). U.S. DOE/NNSA Office of Defense Nuclear Nonproliferation Research and Development. Isotopes (ORNL).

  17. Absolute Integral Cross Sections for the State-selected Ion-Molecule Reaction N2+(X2Σg+ v+ = 0-2) + C2H2 in the Collision Energy Range of 0.03-10.00 eV

    NASA Astrophysics Data System (ADS)

    Xu, Yuntao; Xiong, Bo; Chung Chang, Yih; Ng, C. Y.

    2016-08-01

    Using the vacuum ultraviolet laser pulsed field ionization-photoion source, together with the double-quadrupole-double-octopole mass spectrometer developed in our laboratory, we have investigated the state-selected ion-molecule reaction {{{{N}}}2}+({X}2{{{{Σ }}}{{g}}}+; v + = 0-2, N+ = 0-9) + C2H2, achieving high internal-state selectivity and high kinetic energy resolution for reactant {{{{N}}}2}+ ions. The charge transfer (CT) and hydrogen-atom transfer (HT) channels, which lead to the respective formation of product {{{C}}}2{{{{H}}}2}+ and N2H+ ions, are observed. The vibrationally selected absolute integral cross sections for the CT [σ CT(v +)] and HT [[σ HT(v +)] channels obtained in the center-of-mass collision energy (E cm) range of 0.03-10.00 eV reveal opposite E cm dependences. The σ CT(v +) is found to increase as E cm is decreased, and is consistent with the long-range exothermic CT mechanism, whereas the E cm enhancement observed for the σ HT(v +) suggests effective coupling of kinetic energy to internal energy, enhancing the formation of N2H+. The σ HT(v +) curve exhibits a step at E cm = 0.70-1.00 eV, suggesting the involvement of the excited {{{C}}}2{{{{H}}}2}+({A}2{{{{Σ }}}{{g}}}+) state in the HT reaction. Contrary to the strong E cm dependences for σ CT(v +) and σ HT(v +), the effect of vibrational excitation of {{{{N}}}2}+ on both the CT and HT channels is marginal. The branching ratios and cross sections for the CT and HT channels determined in the present study are useful for modeling the atmospheric compositions of Saturn's largest moon, Titan. These cross sections and branching ratios are also valuable for benchmarking theoretical calculations on chemical dynamics of the titled reaction.

  18. Absolute Integral Cross Sections for the State-selected Ion–Molecule Reaction N2+(X2Σg+ v+ = 0–2) + C2H2 in the Collision Energy Range of 0.03–10.00 eV

    NASA Astrophysics Data System (ADS)

    Xu, Yuntao; Xiong, Bo; Chung Chang, Yih; Ng, C. Y.

    2016-08-01

    Using the vacuum ultraviolet laser pulsed field ionization-photoion source, together with the double-quadrupole–double-octopole mass spectrometer developed in our laboratory, we have investigated the state-selected ion–molecule reaction {{{{N}}}2}+({X}2{{{{Σ }}}{{g}}}+; v + = 0–2, N+ = 0–9) + C2H2, achieving high internal-state selectivity and high kinetic energy resolution for reactant {{{{N}}}2}+ ions. The charge transfer (CT) and hydrogen-atom transfer (HT) channels, which lead to the respective formation of product {{{C}}}2{{{{H}}}2}+ and N2H+ ions, are observed. The vibrationally selected absolute integral cross sections for the CT [σ CT(v +)] and HT [[σ HT(v +)] channels obtained in the center-of-mass collision energy (E cm) range of 0.03–10.00 eV reveal opposite E cm dependences. The σ CT(v +) is found to increase as E cm is decreased, and is consistent with the long-range exothermic CT mechanism, whereas the E cm enhancement observed for the σ HT(v +) suggests effective coupling of kinetic energy to internal energy, enhancing the formation of N2H+. The σ HT(v +) curve exhibits a step at E cm = 0.70–1.00 eV, suggesting the involvement of the excited {{{C}}}2{{{{H}}}2}+({A}2{{{{Σ }}}{{g}}}+) state in the HT reaction. Contrary to the strong E cm dependences for σ CT(v +) and σ HT(v +), the effect of vibrational excitation of {{{{N}}}2}+ on both the CT and HT channels is marginal. The branching ratios and cross sections for the CT and HT channels determined in the present study are useful for modeling the atmospheric compositions of Saturn's largest moon, Titan. These cross sections and branching ratios are also valuable for benchmarking theoretical calculations on chemical dynamics of the titled reaction.

  19. Ionisation cross sections of rare-gas atoms by electron impact

    NASA Technical Reports Server (NTRS)

    Krishnakumar, E.; Srivastava, S. K.

    1988-01-01

    A pulsed electron beam and ion extraction method is used to measure normalized values of partial ionization cross sections for rare gases from threshold to 1000 eV. Cross sections obtained for singly ionized species are used to calibrate the mass transmission efficiency of the ion extraction/analyzer/detection system by the relative flow technique, and this mass transmission curve is then used to determine the absolute cross sections of the multiply ionized species. Total ion cross sections are found by summation of the individual partial cross sections with proper weighting for charge.

  20. Review of Current and Future Neutrino Cross-Section Experiments

    SciTech Connect

    Schmitz, D.; /Fermilab

    2009-07-01

    There has been a surge of progress and published results in neutrino cross-section physics in recent years. In many cases, absolute differential cross-sections are being measured for the first time and can be compared to interaction models first developed decades ago. These measurements are important input for the next generation of accelerator-based neutrino oscillation experiments where precise understanding of both signal and background channels will be critical to the observation of sub-dominant oscillation effects. This paper discusses recent results from several experiments and describes new experiments currently under construction dedicated to making these measurements with unprecedented precision.

  1. Review of Current and Future Neutrino Cross-Section Experiments

    SciTech Connect

    Schmitz, D.

    2010-03-30

    There has been a surge of progress and published results in neutrino cross-section physics in recent years. In many cases, absolute differential cross-sections are being measured for the first time and can be compared to interaction models first developed decades ago. These measurements are important input for the next generation of accelerator-based neutrino oscillation experiments where precise understanding of both signal and background channels will be critical to the observation of sub-dominant oscillation effects. This paper discusses recent results from several experiments and describes new experiments currently under construction dedicated to making these measurements with unprecedented precision.

  2. Electron Photon Interaction Cross Sections

    2014-11-01

    Version 00 The Electron Photon Interaction Cross Sections, EPICS, provides the atomic data needed to perform coupled Electron-Photon transport calculations, to produce accurate macroscopic results, such as energy deposit and dose. Atomic data is provided for elements, Z = 1 to 100, over the energy range 10 eV to 100 GeV; note that nuclear data, such as photo-nuclear, and data for compounds, are not included. All data is in a simple computer independent text formatmore » that is standard and presented to a high precision that can be easily read by computer codes written in any computer language, e.g., C, C++, and FORTRAN. EPICS includes four separate data bases that are designed to be used in combination, these include, • The Evaluated Electron Data Library (EEDL), to describe the interaction of electrons with matter. • The Evaluated Photon Data Library (EPDL), to describe the interaction of photons with matter. • The Evaluated Atomic Data Library (EADL), to describe the emission of electrons and photons back to neutrality following an ionizing event, caused by either electron or photon interactions. • The Evaluated Excitation Data Library (EXDL), to describe the excitation of atoms due to photon interaction. All of these are available in the Extended ENDL format (ENDLX) in which the evaluations were originally performed. The first three are also available in the ENDF format; as yet ENDF does not include formats to handle excitation data (EXDL).« less

  3. Electron Photon Interaction Cross Sections

    SciTech Connect

    Cullen, D. E.

    2014-11-01

    Version 00 The Electron Photon Interaction Cross Sections, EPICS, provides the atomic data needed to perform coupled Electron-Photon transport calculations, to produce accurate macroscopic results, such as energy deposit and dose. Atomic data is provided for elements, Z = 1 to 100, over the energy range 10 eV to 100 GeV; note that nuclear data, such as photo-nuclear, and data for compounds, are not included. All data is in a simple computer independent text format that is standard and presented to a high precision that can be easily read by computer codes written in any computer language, e.g., C, C++, and FORTRAN. EPICS includes four separate data bases that are designed to be used in combination, these include, • The Evaluated Electron Data Library (EEDL), to describe the interaction of electrons with matter. • The Evaluated Photon Data Library (EPDL), to describe the interaction of photons with matter. • The Evaluated Atomic Data Library (EADL), to describe the emission of electrons and photons back to neutrality following an ionizing event, caused by either electron or photon interactions. • The Evaluated Excitation Data Library (EXDL), to describe the excitation of atoms due to photon interaction. All of these are available in the Extended ENDL format (ENDLX) in which the evaluations were originally performed. The first three are also available in the ENDF format; as yet ENDF does not include formats to handle excitation data (EXDL).

  4. [Fast neutron cross section measurements

    SciTech Connect

    Knoll, G.F.

    1992-10-26

    From its inception, the Nuclear Data Project at the University of Michigan has concentrated on two major objectives: (1) to carry out carefully controlled nuclear measurements of the highest possible reliability in support of the national nuclear data program, and (2) to provide an educational opportunity for students with interests in experimental nuclear science. The project has undergone a successful transition from a primary dependence on our photoneutron laboratory to one in which our current research is entirely based on a unique pulsed 14 MeV fast neutron facility. The new experimental facility is unique in its ability to provide nanosecond bursts of 14 MeV neutrons under conditions that are clean'' and as scatter-free as possible, and is the only one of its type currently in operation in the United States. It has been designed and put into operation primarily by graduate students, and has met or exceeded all of its important initial performance goals. We have reached the point of its routine operation, and most of the data are now in hand that will serve as the basis for the first two doctoral dissertations to be written by participating graduate students. Our initial results on double differential neutron cross sections will be presented at the May 1993 Fusion Reactor Technology Workshop. We are pleased to report that, after investing several years in equipment assembly and optimization, the project has now entered its data production'' phase.

  5. Recent fission cross section standards measurements

    SciTech Connect

    Wasson, O.A.

    1985-01-01

    The /sup 235/U(n,f) reaction is the standard by which most neutron induced fission cross sections are determined. Most of these cross sections are derived from relatively easy ratio measurements to /sup 235/U. However, the more difficult /sup 235/U(n,f) cross section measurements require the use of advanced neutron detectors for the determination of the incident neutron fluence. Examples of recent standard cross section measurements are discussed, various neutron detectors are described, and the status of the /sup 235/U(n,f) cross section standard is assessed. 23 refs., 8 figs., 4 tabs.

  6. pi+- p differential cross sections at low energies

    SciTech Connect

    H. Denz; P. Amaudruz; J.T. Brack; J. Breitschopf; P. Camerini; J.L. Clark; H. Clement; L. Felawka; E. Fragiacomo; E.F. Gibson; N. Grion; G.J. Hofman; B. Jamieson; E.L. Mathie; R. Meier; G. Moloney; D. Ottewell; O. Patarakin; J.D. Patterson; M.M. Pavan; S. Piano; K. Raywood; R.A. Ristinen; R. Rui; M.E. Sevior; G.R. Smith; J. Stahov; R. Tacik; G.J. Wagner; F. von Wrochem; D.M. Yeomans

    2005-12-03

    Differential cross sections for pi- p and pi+ p elastic scattering were measured at five energies between 19.9 and 43.3 MeV. The use of the CHAOS magnetic spectrometer at TRIUMF, supplemented by a range telescope for muon background suppression, provided simultaneous coverage of a large part of the full angular range, thus allowing very precise relative cross section measurements. The absolute normalization was determined with a typical accuracy of 5 %. This was verified in a simultaneous measurement of muon proton elastic scattering. The measured cross sections show some deviations from phase shift analysis predictions, in particular at large angles and low energies. From the new data we determine the real part of the isospin forward scattering amplitude.

  7. Photoabsorption cross section of acetylene in the EUV region

    NASA Technical Reports Server (NTRS)

    Wu, C. Y. R.; Judge, D. L.

    1985-01-01

    The measurement of the absolute photoabsorption cross sections of C2H2 in the 175-740 A region by means of a double ionization chamber is reported. The continuum background source is the synchrotron radiation emitted by the Wisconsin 240 MeV electron storage ring. It is found that the cross sections range from 2 to a maximum of 36 Mb. Two new Rydberg series are identified and the cross section data are applied in the analysis of various sum rules. From the rules, it is shown that the data of C2H2 in the 580-1088 A range may be too low, while the measured ionization transition moment may be too high.

  8. Electron Impact Ionization Cross Sections in Rb and Cs.

    NASA Astrophysics Data System (ADS)

    Reddish, T. J.; Lukomski, M.; Sutton, S.; Kedzierski, W.; McConkey, J. W.; Bartschat, K.; Bartlett, P. L.; Stelbovics, A. T.; Bray, I.

    2006-05-01

    We present a new atom trapping technique for determining absolute, total ionisation cross sections (TICS) out of an excited atom. The novel feature of this method is in utilizing Doppler cooling of neutral atoms to determine ionisation cross sections. This fluorescence-monitoring experiment, which is a variant of the `trap loss' technique, has enabled us to obtain the experimental electron impact ionisation cross sections out of the Cs 6^2P3/2 excited state between 7 - 400 eV. New CCC, R-Matrix with Pseudo-States (RMPS), and Born approximation single ionisation cross sections (SICS) are also presented for both the ground and excited states of Cs and Rb, and compared with the available experimental data. The comparison of the results reveals the importance of the autoionisation and multiple ionisation contributions to the TICS. The autoionisation contribution appears to be substantial for ionisation out of the Cs 6^2P and Rb 5^2P excited states; ˜ 3-4 larger than the direct ionisation contribution predicted by CCC at ˜ 30-50 eV. This surprising result shows the importance of multi-electron processes in determining the ionisation cross sections of heavy alkali atoms.

  9. Measurement of proton inelastic scattering cross sections on fluorine

    NASA Astrophysics Data System (ADS)

    Chiari, M.; Caciolli, A.; Calzolai, G.; Climent-Font, A.; Lucarelli, F.; Nava, S.

    2016-10-01

    Differential cross-sections for proton inelastic scattering on fluorine, 19F(p,p')19F, from the first five excited levels of 19F at 110, 197, 1346, 1459 and 1554 keV were measured for beam energies from 3 to 7 MeV at a scattering angle of 150° using a LiF thin target (50 μg/cm2) evaporated on a self-supporting C thin film (30 μg/cm2). Absolute differential cross-sections were calculated with a method not dependent on the absolute values of collected beam charge and detector solid angle. The validity of the measured inelastic scattering cross sections was then tested by successfully reproducing EBS spectra collected from a thick Teflon (CF2) target. As a practical application of these measured inelastic scattering cross sections in elastic backscattering spectroscopy (EBS), the feasibility of quantitative light element (C, N and O) analysis in aerosol particulate matter samples collected on Teflon by EBS measurements and spectra simulation is demonstrated.

  10. Vertically stabilized elongated cross-section tokamak

    DOEpatents

    Sheffield, George V.

    1977-01-01

    This invention provides a vertically stabilized, non-circular (minor) cross-section, toroidal plasma column characterized by an external separatrix. To this end, a specific poloidal coil means is added outside a toroidal plasma column containing an endless plasma current in a tokamak to produce a rectangular cross-section plasma column along the equilibrium axis of the plasma column. By elongating the spacing between the poloidal coil means the plasma cross-section is vertically elongated, while maintaining vertical stability, efficiently to increase the poloidal flux in linear proportion to the plasma cross-section height to achieve a much greater plasma volume than could be achieved with the heretofore known round cross-section plasma columns. Also, vertical stability is enhanced over an elliptical cross-section plasma column, and poloidal magnetic divertors are achieved.

  11. Annular-Cross-Section CFE Chamber

    NASA Technical Reports Server (NTRS)

    Sharnez, Rizwan; Sammons, David W.

    1994-01-01

    Proposed continuous-flow-electrophoresis (CFE) chamber of annular cross section offers advantages over conventional CFE chamber, and wedge-cross-section chamber described in "Increasing Sensitivity in Continuous-Flow Electrophoresis" (MFS-26176). In comparison with wedge-shaped chamber, chamber of annular cross section virtually eliminates such wall effects as electro-osmosis and transverse gradients of velocity. Sensitivity enhanced by incorporating gradient maker and radial (collateral) flow.

  12. Cross Sections for Electron Collisions with Methane

    SciTech Connect

    Song, Mi-Young Yoon, Jung-Sik; Cho, Hyuck; Itikawa, Yukikazu; Karwasz, Grzegorz P.; Kokoouline, Viatcheslav; Nakamura, Yoshiharu; Tennyson, Jonathan

    2015-06-15

    Cross section data are compiled from the literature for electron collisions with methane (CH{sub 4}) molecules. Cross sections are collected and reviewed for total scattering, elastic scattering, momentum transfer, excitations of rotational and vibrational states, dissociation, ionization, and dissociative attachment. The data derived from swarm experiments are also considered. For each of these processes, the recommended values of the cross sections are presented. The literature has been surveyed through early 2014.

  13. Neutron capture cross section standards for BNL 325, Fourth Edition

    SciTech Connect

    Holden, N.E.

    1981-01-01

    This report evaluates the experimental data and recommends values for the thermal neutron cross sections and resonance integrals for the neutron capture reactions: /sup 55/Mn(n,..gamma..), /sup 59/Co(n,..gamma..) and /sup 197/Au(n,..gamma..). The failure of lithium and boron as standards due to the natural variation of the absorption cross sections of these elements is discussed. The Westcott convention, which describes the neutron spectrum as a thermal Maxwellian distribution with an epithermal component, is also discussed.

  14. Measurement of a metastability-exchange cross section in krypton

    SciTech Connect

    Brechignac, C.; Vetter, R.

    1980-08-01

    The metastability-exchange cross section between (/sup 3/P/sub 2/)Kr atoms and (/sup 1/S/sub 0/)Kr atoms is measured by means of a two-laser saturated-absorption experiment performed on the lambda=557-nm transition. A study of velocity changes occurring in pure /sup 86/Kr and in (/sup 86/Kr--/sup 78/Kr) discharges leads to a value for the cross section Q75=(plus-or-minus10) A/sup 2/.

  15. Froissart bound on inelastic cross section without unknown constants

    NASA Astrophysics Data System (ADS)

    Martin, André; Roy, S. M.

    2015-04-01

    Assuming that axiomatic local field theory results hold for hadron scattering, André Martin and S. M. Roy recently obtained absolute bounds on the D wave below threshold for pion-pion scattering and thereby determined the scale of the logarithm in the Froissart bound on total cross sections in terms of pion mass only. Previously, Martin proved a rigorous upper bound on the inelastic cross-section σinel which is one-fourth of the corresponding upper bound on σtot, and Wu, Martin, Roy and Singh improved the bound by adding the constraint of a given σtot. Here we use unitarity and analyticity to determine, without any high-energy approximation, upper bounds on energy-averaged inelastic cross sections in terms of low-energy data in the crossed channel. These are Froissart-type bounds without any unknown coefficient or unknown scale factors and can be tested experimentally. Alternatively, their asymptotic forms, together with the Martin-Roy absolute bounds on pion-pion D waves below threshold, yield absolute bounds on energy-averaged inelastic cross sections. For example, for π0π0 scattering, defining σinel=σtot-(σπ0π0→π0π0+σπ0π0→π+π-) , we show that for c.m. energy √{s }→∞, σ¯ inel(s ,∞)≡s ∫s∞d s'σinel(s')/s'2≤(π /4 )(mπ)-2[ln (s /s1)+(1 /2 )ln ln (s /s1)+1 ]2 where 1 /s1=34 π √{2 π }mπ-2 . This bound is asymptotically one-fourth of the corresponding Martin-Roy bound on the total cross section, and the scale factor s1 is one-fourth of the scale factor in the total cross section bound. The average over the interval (s,2s) of the inelastic π0π0 cross section has a bound of the same form with 1 /s1 replaced by 1 /s2=2 /s1.

  16. Photoabsorption cross-section measurements of 32S, 33S, 34S, and 36S sulfur dioxide from 190 to 220 nm

    NASA Astrophysics Data System (ADS)

    Endo, Yoshiaki; Danielache, Sebastian O.; Ueno, Yuichiro; Hattori, Shohei; Johnson, Matthew S.; Yoshida, Naohiro; Kjaergaard, Henrik G.

    2015-03-01

    The ultraviolet absorption cross sections of the SO2 isotopologues are essential to understanding the photochemical fractionation of sulfur isotopes in planetary atmospheres. We present measurements of the absorption cross sections of 32SO2, 33SO2, 34SO2, and 36SO2, recorded from 190 to 220 nm at room temperature with a resolution of 0.1 nm (~25 cm-1) made using a dual-beam photospectrometer. The measured absorption cross sections show an apparent pressure dependence and a newly developed analytical model shows that this is caused by underresolved fine structure. The model made possible the calculation of absorption cross sections at the zero-pressure limit that can be used to calculate photolysis rates for atmospheric scenarios. The 32SO2, 33SO2, and 34SO2 cross sections improve upon previously published spectra including fine structure and peak widths. This is the first report of absolute absorption cross sections of the 36SO2 isotopologue for the C1B2-X1A2 band where the amplitude of the vibrational structure is smaller than the other isotopologues throughout the spectrum. Based on the new results, solar UV photodissociation of SO2 produces 34ɛ, 33Ε, and 36Ε isotopic fractionations of +4.6 ± 11.6‰, +8.8 ± 9.0‰, and -8.8 ± 19.6‰, respectively. From these spectra isotopic effects during photolysis in the Archean atmosphere can be calculated and compared to the Archean sedimentary record. Our results suggest that broadband solar UV photolysis is capable of producing the mass-independent fractionation observed in the Archean sedimentary record without involving shielding by specific gaseous compounds in the atmosphere including SO2 itself. The estimated magnitude of 33Ε, for example, is close to the maximum Δ33S observed in the geological record.

  17. Infrared cross-sections and integrated band intensities of propylene: Temperature-dependent studies

    NASA Astrophysics Data System (ADS)

    Es-sebbar, Et-touhami; Alrefae, Majed; Farooq, Aamir

    2014-01-01

    Propylene, a by-product of biomass burning, thermal cracking of hydrocarbons and incomplete combustion of fossil fuels, is a ubiquitous molecule found in the environment and atmosphere. Accurate infrared (IR) cross-sections and integrated band intensities of propylene are essential for quantitative measurements and atmospheric modeling. We measured absolute IR cross-sections of propylene using Fourier Transform Infrared (FTIR) Spectroscopy over the wavenumber range of 400-6500 cm-1 and at gas temperatures between 296 and 460 K. We recorded these spectra at spectral resolutions ranging from 0.08 to 0.5 cm-1 and measured the integrated band intensities for a number of vibrational bands in certain spectral regions. We then compared the integrated band intensities measured at room temperature with values derived from the National Institute of Standards and Technology (NIST) and the Pacific Northwest National Laboratory (PNNL) databases. Our results agreed well with the results reported in the two databases with a maximum deviation of about 4%. The peak cross-sections for the primary bands decreased by about 20-54% when the temperature increased from 296 to 460 K. Moreover, we determined the integrated band intensities as a function of temperature for certain features in various spectral regions; we found no significant temperature dependence over the range of temperatures considered here. We also studied the effect of temperature on absorption cross-section using a Difference Frequency Generation (DFG) laser system. We compared the DFG results with those obtained from the FTIR study at certain wavenumbers over the 2850-2975 cm-1 range and found a reasonable agreement with less than 10% discrepancy.

  18. Giant raman scattering cross section for an adsorbed dye at ag colloids associated with low EM field enhancement

    NASA Astrophysics Data System (ADS)

    Pettinger, B.; Krischer, K.; Ertl, G.

    1988-10-01

    Surface-enhanced resonance Raman scattering (SERRS) of rhodamine 6G molecules adsorbed at aggregated Ag colloids shows an absolute cross section of σ SERRStotal = 2.3 × 10 -16 cm 2, the highest value observed so far, which is nearly equal to the absorption cross section of the same dye in solution. Its magnitude as well as the weak decrease of colloidal Rayleigh scattering, but significant drop of SERRS with increasing dye coverage (0.001 < θ < 0.1), can be explained within the framework of a recently developed quantum-mechanical model of SERRS, which relates the surface enhancement, FSERRS, with the EM field enhancement, g: FSERRS≈ g6, where g is estimated to be about 10.

  19. Elastic photonuclear cross sections for bremsstrahlung from relativistic ions

    NASA Astrophysics Data System (ADS)

    Mikkelsen, Rune E.; Sørensen, Allan H.; Uggerhøj, Ulrik I.

    2016-04-01

    In this paper, we provide a procedure to calculate the bremsstrahlung spectrum for virtually any relativistic bare ion with charge 6e or beyond, Z ⩾ 6 , in ultraperipheral collisions with target nuclei. We apply the Weizsäcker-Williams method of virtual quanta to model the effect of the distribution of nuclear constituents on the interaction of the ion with the radiation target. This leads to a bremsstrahlung spectrum peaking at 2 γ times the energy of the giant dipole resonance (γ is the projectile energy in units of its rest energy). A central ingredient in the calculation is the cross section for elastic scattering of photons on the ion. This is only available in the literature for a few selected nuclei and, usually, only in a rather restricted parameter range. Hence we develop a procedure applicable for all Z ⩾ 6 to estimate the elastic scattering. The elastic cross section is obtained at low to moderate photon energies, somewhat beyond the giant dipole resonance, by means of the optical theorem, a dispersion relation, and data on the total absorption cross section. The cross section is continued at higher energies by invoking depletion due to loss of coherence in the scattering. Our procedure is intended for any ion where absorption data is available and for moderate to high energies, γ ≳ 10 .

  20. Photon scattering cross sections of H2 and He measured with synchrotron radiation

    NASA Technical Reports Server (NTRS)

    Ice, G. E.

    1977-01-01

    Total (elastic + inelastic) differential photon scattering cross sections have been measured for H2 gas and He, using an X-ray beam. Absolute measured cross sections agree with theory within the probable errors. Relative cross sections (normalized to theory at large S) agree to better than one percent with theoretical values calculated from wave functions that include the effect of electron-electron Coulomb correlation, but the data deviate significantly from theoretical independent-particle (e.g., Hartree-Fock) results. The ratios of measured absolute He cross sections to those of H2, at any given S, also agree to better than one percent with theoretical He-to-H2 cross-section ratios computed from correlated wave functions. It appears that photon scattering constitutes a very promising tool for probing electron correlation in light atoms and molecules.

  1. Energy and angle differential cross sections for the electron-impact double ionization of helium

    SciTech Connect

    Colgan, James P; Pindzola, M S; Robicheaux, F

    2008-01-01

    Energy and angle differential cross sections for the electron-impact double ionization of helium are calculated using a non-perturbative time-dependent close-coupling method. Collision probabilities are found by projection of a time evolved nine dimensional coordinate space wave function onto fully antisymmetric products of spatial and spin functions representing three outgoing Coulomb waves. At an incident energy of 106 eV, we present double energy differential cross sections and pentuple energy and angle differential cross sections. The pentuple energy and angle differential cross sections are found to be in relative agreement with the shapes observed in recent (e,3e) reaction microscope experiments. Integration of the differential cross sections over all energies and angles yields a total ionization cross section that is also in reasonable agreement with absolute crossed-beams experiments.

  2. Spectrally resolved fluorescence cross sections of BG and BT with a 266-nm pump wavelength

    NASA Astrophysics Data System (ADS)

    Atkins, Joshua; Thomas, Michael E.; Joseph, Richard I.

    2007-04-01

    The spectrally resolved absolute fluorescence cross sections of Bacillus globigii (BG) and Bacillus thuringiensis (BT) were measured with a 266nm Nd:YAG laser source. The aerosol samples were prepared in dilute aqueous suspensions for measurement and the absolute cross section was found by use of the Raman scattering line from water. Integrated cross sections for BT and BG were found to be 1.1864 × 10 -12 cm2(spore sr) and 3.251 × 10 -13 cm2/ (spore sr) respectively.

  3. Highly charged ion impact on uracil: Cross sections measurements and scaling

    NASA Astrophysics Data System (ADS)

    Agnihotri, A. N.; Kasthurirangan, S.; Champion, C.; Rivarola, R. D.; Tribedi, L. C.

    2014-04-01

    Absolute total ionization cross sections (TCS) of uracil in collisions with highly charge C, O and F ions are measured. The scaling properties of cross sections are obtained as a function of projectile charge state and energy. The measurements are compared with the CDW-EIS, CB1 and CTMC calculations. The absolute double differential cross sections (DDCS) of secondary electron emission from uracil in collisions with bare MeV energy C and O ions are also measured. Large enhancement in forward emission is observed.

  4. Excitation and Charge Exchange Phenomena in Astronomical Objects: Measurement of Cross Sections and Lifetimes

    NASA Technical Reports Server (NTRS)

    Chutjian, Ara; Smith, S.; Lozano, J.; Cadez, I.; Greewnood, J.; Mawhovter, R.; Williams, I.; Niimura, M.

    2003-01-01

    This document addresses extreme ultraviolet radiation and X-ray emissions from comets, planets and heliospheric gases focusing on the measurement of charge-exchange cross sections and radiative lifetimes. Highly-charged heavy ions present in the solar wind, and their abundance relative to the total oxygen-ion abundance are detailed. The plan for the Jet Propulsion Laboratory high-charge ion facility is outlined detailing its ability to measure absolute collisional excitation cross sections, absolute charge-exchange cross sections, lifetimes of metastable ion levels, and X-ray emission spectra following charge changes.

  5. Silicon Detector System for Cross Section Measurements

    NASA Technical Reports Server (NTRS)

    2003-01-01

    In order to estimate the radiation shielding effectiveness of materials it is necessary to know cosmic ray particles are broken up as they pass though these materials. The breakup of cosmic ray particles is characterized by the nuclear fragmentation cross sections, i.e. an effective geometrical cross section assigned to each target nucleus that represents its apparent size for fragmenting the incident particle. The values of these cross sections depend on the details of nuclear physics and cannot be calculated from first principles owing to the many-body nature of the interactions. The only way to determine them is to measure them. Once a sufficient number of cross sections have been measured, the systematic nature of the interactions allows other cross-sections to be estimated. The number of cross sections that contribute to the estimation of shielding effectiveness is very large 10,000. Fortunately most make minor contributions. These can be estimated from nuclear systematics. Only those who's uncertainties make significant contributions to the error in the shielding effectiveness estimations need to be measured. In the past it has proven difficult to measure light fragment production cross sections from the interactions of heavy cosmic rays owing to the size of the detectors used. We have developed a highly pixilated silicon (Si) detector system that can individually identify these light fragments while making efficient use of costly accelerator time. This system is an outgrowth of detector technology developed under a CDDF and a Code S sponsored cosmic ray experiment.

  6. Cross Section Evaluations for Arsenic Isotopes

    SciTech Connect

    Pruet, J; McNabb, D P; Ormand, W E

    2005-03-10

    The authors present an evaluation of cross sections describing reactions with neutrons incident on the arsenic isotopes with mass numbers 75 and 74. Particular attention is paid to (n,2n) reactions. The evaluation for {sup 75}As, the only stable As isotope, is guided largely by experimental data. Evaluation for {sup 74}As is made through calculations with the EMPIRE statistical-model reaction code. Cross sections describing the production and destruction of the 26.8 ns isomer in {sup 74}As are explicitly considered. Uncertainties and covariances in some evaluated cross sections are also estimated.

  7. Differential cross-sections with hard targets

    NASA Astrophysics Data System (ADS)

    Brun, J. L.; Pacheco, A. F.

    2005-09-01

    When the concept of scattering differential cross-section is introduced in classical mechanics textbooks, usually it is first supposed that the target is a fixed, hard sphere. In this paper we calculate the scattering differential cross-section in the case of the hard target being a fixed figure of revolution of any shape. When the target is a paraboloid of revolution, we find the well-known formula corresponding to Rutherford's scattering. In addition, we analyse the inverse problem, i.e. given a differential cross-section, what is the profile of the corresponding hard target?

  8. Reconstruction of absolute absorption spectrum of reduced heme a in cytochrome C oxidase from bovine heart.

    PubMed

    Dyuba, A V; Vygodina, T V; Konstantinov, A A

    2013-12-01

    This paper presents a new experimental approach for determining the individual optical characteristics of reduced heme a in bovine heart cytochrome c oxidase starting from a small selective shift of the heme a absorption spectrum induced by calcium ions. The difference spectrum induced by Ca2+ corresponds actually to a first derivative (differential) of the heme a(2+) absolute absorption spectrum. Such an absolute spectrum was obtained for the mixed-valence cyanide complex of cytochrome oxidase (a(2+)a3(3+)-CN) and was subsequently used as a basis spectrum for further procession and modeling. The individual absorption spectrum of the reduced heme a in the Soret region was reconstructed as the integral of the difference spectrum induced by addition of Ca2+. The spectrum of heme a(2+) in the Soret region obtained in this way is characterized by a peak with a maximum at 447 nm and half-width of 17 nm and can be decomposed into two Gaussians with maxima at 442 and 451 nm and half-widths of ~10 nm (589 cm(-1)) corresponding to the perpendicularly oriented electronic π→π* transitions B0x and B0y in the porphyrin ring. The reconstructed spectrum in the Soret band differs significantly from the "classical" absorption spectrum of heme a(2+) originally described by Vanneste (Vanneste, W. H. (1966) Biochemistry, 65, 838-848). The differences indicate that the overall γ-band of heme a(2+) in cytochrome oxidase contains in addition to the B0x and B0y transitions extra components that are not sensitive to calcium ions, or, alternatively, that the Vanneste's spectrum of heme a(2+) contains significant contribution from heme a3(2+). The reconstructed absorption band of heme a(2+) in the α-band with maximum at 605 nm and half-width of 18 nm (850 cm(-1)) corresponds most likely to the individual Q0y transition of heme a, whereas the Q0x transition contributes only weakly to the spectrum.

  9. MODELING AND FISSION CROSS SECTIONS FOR AMERICIUM.

    SciTech Connect

    ROCHMAN, D.; HERMAN, M.; OBLOZINSKY, P.

    2005-05-01

    This is the final report of the work performed under the LANL contract on the modeling and fission cross section for americium isotopes (May 2004-June 2005). The purpose of the contract was to provide fission cross sections for americium isotopes with the nuclear reaction model code EMPIRE 2.19. The following work was performed: (1) Fission calculations capability suitable for americium was implemented to the EMPIRE-2.19 code. (2) Calculations of neutron-induced fission cross sections for {sup 239}Am to {sup 244g}Am were performed with EMPIRE-2.19 for energies up to 20 MeV. For the neutron-induced reaction of {sup 240}Am, fission cross sections were predicted and uncertainties were assessed. (3) Set of fission barrier heights for each americium isotopes was chosen so that the new calculations fit the experimental data and follow the systematics found in the literature.

  10. The radar cross section of dielectric disks

    NASA Technical Reports Server (NTRS)

    Levine, D. M.

    1982-01-01

    A solution is presented for the backscatter (nonstatic) radar cross section of dielectric disks of arbitrary shape, thickness and dielectric constant. The result is obtained by employing a Kirchhoff type approximation to obtain the fields inside the disk. The internal fields induce polarization and conduction currents from which the scattered fields and the radar cross section can be computed. The solution for the radar cross section obtained in this manner is shown to agree with known results in the special cases of normal incidence, thin disks and perfect conductivity. The solution can also be written as a product of the reflection coefficient of an identically oriented slab times the physical optics solution for the backscatter cross section of a perfectly conducting disk of the same shape. This result follows directly from the Kirchhoff type approximation without additional assumptions.

  11. A nuclear cross section data handbook

    SciTech Connect

    Fisher, H.O.M.

    1989-12-01

    Isotopic information, reaction data, data availability, heating numbers, and evaluation information are given for 129 neutron cross-section evaluations, which are the source of the default cross sections for the Monte Carlo code MCNP. Additionally, pie diagrams for each nuclide displaying the percent contribution of a given reaction to the total cross section are given at 14 MeV, 1 MeV, and thermal energy. Other information about the evaluations and their availability in continuous-energy, discrete-reaction, and multigroup forms is provided. The evaluations come from ENDF/B-V, ENDL85, and the Los Alamos Applied Nuclear Science Group T-2. Graphs of all neutron and photon production cross-section reactions for these nuclides have been categorized and plotted. 21 refs., 5 tabs.

  12. QuickSite Cross Section Processing

    2003-05-27

    This AGEM-developed system produces cross sections by inputting data in both standard and custom file formats and outputting a graphic file that can be printed or further modified in a commercial graphic program. The system has evolved over several years in order to combine and visualize a changing set of field data more rapidly than was possible with commercially available cross section software packages. It uses some commercial packages to produce the input and tomore » modify the output files. Flexibility is provided by a dynamic set of programs that are customized to accept varying input and accomodate varying output requirements. There are two basic types of routines: conversion routines and cross section generation routines. The conversion routines convery various data files to logger file format which is compatible with a standard file format for LogPlot 98, a commonly used commercial log plotting program. The cross section routines generate cross sections and apply topography to these cross sections. All of the generation routines produce a standard graphic DXF file, which is the format used in AutoCAD and can then be modified in a number of available graphics programs.« less

  13. Absolute 1* quantum yields for the ICN A state by diode laser gain versus absorption spectroscopy

    NASA Technical Reports Server (NTRS)

    Hess, Wayne P.; Leone, Stephen R.

    1987-01-01

    Absolute I* quantum yields were measured as a function of wavelength for room temperature photodissociation of the ICN A state continuum. The temperature yields are obtained by the technique of time-resolved diode laser gain-versus-absorption spectroscopy. Quantum yields are evaluated at seven wavelengths from 248 to 284 nm. The yield at 266 nm is 66.0 +/- 2% and it falls off to 53.4 +/- 2% and 44.0 +/- 4% at 284 and 248 respectively. The latter values are significantly higher than those obtained by previous workers using infrared fluorescence. Estimates of I* quantum yields obtained from analysis of CN photofragment rotational distributions, as discussed by other workers, are in good agreement with the I* yields. The results are considered in conjunction with recent theoretical and experimental work on the CN rotational distributions and with previous I* yield results.

  14. SU-E-I-43: Photoelectric Cross Section Revisited

    SciTech Connect

    Haga, A; Nakagawa, K; Kotoku, J; Horikawa, Y

    2015-06-15

    Purpose: The importance of the precision in photoelectric cross-section value increases for recent developed technology such as dual energy computed tomography, in which some reconstruction algorithms require the energy dependence of the photo-absorption in each material composition of human being. In this study, we revisited the photoelectric cross-section calculation by self-consistent relativistic Hartree-Fock (HF) atomic model and compared with that widely distributed as “XCOM database” in National Institute of Standards and Technology, which was evaluated with localdensity approximation for electron-exchange (Fock)z potential. Methods: The photoelectric cross section can be calculated with the electron wave functions in initial atomic state (bound electron) and final continuum state (photoelectron). These electron states were constructed based on the selfconsistent HF calculation, where the repulsive Coulomb potential from the electron charge distribution (Hartree term) and the electron exchange potential with full electromagnetic interaction (Fock term) were included for the electron-electron interaction. The photoelectric cross sections were evaluated for He (Z=2), Be (Z=4), C (Z=6), O (Z=8), and Ne (Z=10) in energy range of 10keV to 1MeV. The Result was compared with XCOM database. Results: The difference of the photoelectric cross section between the present calculation and XCOM database was 8% at a maximum (in 10keV for Be). The agreement tends to be better as the atomic number increases. The contribution from each atomic shell has a considerable discrepancy with XCOM database except for K-shell. However, because the photoelectric cross section arising from K-shell is dominant, the net photoelectric cross section was almost insensitive to the different handling in Fock potential. Conclusion: The photoelectric cross-section program has been developed based on the fully self-consistent relativistic HF atomic model. Due to small effect on the Fock

  15. Single and Triple Differential Cross Sections for DoublePhotoionization of H-

    SciTech Connect

    Yip, Frank L.; Horner, Daniel A.; McCurdy, C. William; Rescigno,Thomas N.

    2007-02-15

    The hydride anion H- would not be bound in the absence ofelectron correlation. Electron correlation drives the doublephotoionization process and, thus should impact double photoionizationresults most strongly for H-. We present fully differential crosssections for the three-body breakup of H- by single photon absorption.The absolute triple-differential and single-differential cross sectionswere yielded by ab initio calculations making use of exterior complexscaling within a discrete variable representation partialwave basis.Results calculated at photon energies of 18eV and 30eV are compared withreported cross sections for helium calculated at 20eV above the doubleionization threshold. These comparisons show a clear signature of initialstate correlation that differentiate the He and H- cases.

  16. Actinide cross section program at ORELA

    SciTech Connect

    Dabbs, J. W.T.

    1980-01-01

    The actinide cross section program at ORELA, the Oak Ridge Electron Linear Accelerator, is aimed at obtaining accurate neutron cross sections (primarily fission, capture, and total) for actinide nuclides which occur in fission reactors. Such cross sections, measured as a function of neutron energy over as wide a range of energies as feasible, comprise a data base that permits calculated predictions of the formation and removal of these nuclides in reactors. The present program is funded by the Division of Basic Energy Sciences of DOE, and has components in several divisions at ORNL. For intensively ..cap alpha..-active nuclides, many of the existing fission cross section data have been provided by underground explosions. New measurement techniques, developed at ORELA, now permit linac measurements on fissionable nuclides with alpha half-lives as short as 28 years. Capture and capture-plus-fission measurements utilize scintillation detectors (of capture ..gamma.. rays and fission neutrons) in which pulse shape discrimination plays an important role. Total cross sections can be measured at ORELA on samples of only a few milligrams. A simultaneous program of chemical and isotopic analyses of samples irradiated in EBR-II is in progress to provide benchmarks for the existing differential measurements. These analyses are being studied with updated versions of ORIGEN and with sensitivity determinations. Calculations of the sensitivity to cross section changes of various aspects of the nuclear fuel cycle are also being made. Even in this relatively mature field, many cross sections still require improvements to provide an adequate data base. Examples of recent techniques and measurements are presented. 12 figures, 3 tables.

  17. Top differential cross section measurements (Tevatron)

    SciTech Connect

    Jung, Andreas W.

    2012-01-01

    Differential cross sections in the top quark sector measured at the Fermilab Tevatron collider are presented. CDF used 2.7 fb{sup -1} of data and measured the differential cross section as a function of the invariant mass of the t{bar t} system. The measurement shows good agreement with the standard model and furthermore is used to derive limits on the ratio {kappa}/M{sub Pl} for gravitons which decay to top quarks in the Randall-Sundrum model. D0 used 1.0 fb{sup -1} of data to measure the differential cross section as a function of the transverse momentum of the top-quark. The measurement shows a good agreement to the next-to-leading order perturbative QCD prediction and various other standard model predictions.

  18. Algorithmic analysis of quantum radar cross sections

    NASA Astrophysics Data System (ADS)

    Lanzagorta, Marco; Venegas-Andraca, Salvador

    2015-05-01

    Sidelobe structures on classical radar cross section graphs are a consequence of discontinuities in the surface currents. In contrast, quantum radar theory states that sidelobe structures on quantum radar cross section graphs are due to quantum interference. Moreover, it is conjectured that quantum sidelobe structures may be used to detect targets oriented off the specular direction. Because of the high data bandwidth expected from quantum radar, it may be necessary to use sophisticated quantum signal analysis algorithms to determine the presence of stealth targets through the sidelobe structures. In this paper we introduce three potential quantum algorithmic techniques to compute classical and quantum radar cross sections. It is our purpose to develop a computer science-oriented tool for further physical analysis of quantum radar models as well as applications of quantum radar technology in various fields.

  19. The cross section for double Compton scattering

    NASA Technical Reports Server (NTRS)

    Gould, R. J.

    1984-01-01

    Employing elementary methods in nonrelativistic quantum electrodynamics, the cross section for gamma sub 0 + e yields e + gamma + gamma is computed for arbitrary energy in the spectrum of the outgoing photons. The final result is given, differential in the energy of one of these photons, for the case where the incident photon is unpolarized and has energy E sub 0 much less than mc-squared, a polarization sum and angular integration being performed for the final-state photons. The cross section has a simple algebraic form resulting from contributions from the sum of squared direct and exchange amplitudes; interference terms from these amplitudes do not contribute to the angular-integrated cross section.

  20. Neutron capture cross section of 136 Xe

    NASA Astrophysics Data System (ADS)

    Daugherty, Sean; Albert, Joshua; Johnson, Tessa; O'Conner, Thomasina; Kaufman, Lisa

    2015-04-01

    136 Xe is an important 0 νββ candidate, studied in experiments such as EXO-200 and, in the future, nEXO. These experiments require a precise study of neutron capture for their background models. The neutron capture cross section of 136 Xe has been measured at the Detector for Advanced Capture Experiments (DANCE) at the Los Alamos Neutron Science Center. A neutron beam ranging from thermal energy to 100 keV was incident on a gas cell filled with isotopically pure 136 Xe . We will discuss the measurement of partial neutron capture cross sections at thermal and first neutron resonance energies along with corresponding capture gamma cascades.

  1. Covariance Evaluation Methodology for Neutron Cross Sections

    SciTech Connect

    Herman,M.; Arcilla, R.; Mattoon, C.M.; Mughabghab, S.F.; Oblozinsky, P.; Pigni, M.; Pritychenko, b.; Songzoni, A.A.

    2008-09-01

    We present the NNDC-BNL methodology for estimating neutron cross section covariances in thermal, resolved resonance, unresolved resonance and fast neutron regions. The three key elements of the methodology are Atlas of Neutron Resonances, nuclear reaction code EMPIRE, and the Bayesian code implementing Kalman filter concept. The covariance data processing, visualization and distribution capabilities are integral components of the NNDC methodology. We illustrate its application on examples including relatively detailed evaluation of covariances for two individual nuclei and massive production of simple covariance estimates for 307 materials. Certain peculiarities regarding evaluation of covariances for resolved resonances and the consistency between resonance parameter uncertainties and thermal cross section uncertainties are also discussed.

  2. Study of the cross section determination with the PRISMA spectrometer: The 40Ar + 208Pb case

    NASA Astrophysics Data System (ADS)

    Mijatović, T.; Szilner, S.; Corradi, L.; Montanari, D.; Pollarolo, G.; Fioretto, E.; Gadea, A.; Goasduff, A.; Jelavić Malenica, D.; Mărginean, N.; Montagnoli, G.; Scarlassara, F.; Soić, N.; Stefanini, A. M.; Ur, C. A.; Valiente-Dobón, J. J.

    2016-04-01

    The PRISMA spectrometer's response function was successfully applied to match three angular and magnetic settings over a wide angular range for measurements of quasi-elastic reactions in 40Ar + 208Pb . The absolute scale of cross sections has been obtained by using the Rutherford cross section at the forward angles and the information from the energy distributions measured with the spectrometer without and with coincidences with the CLARA γ-array. The semi-classical model GRAZING has been used to test the unfolding procedure and for comparison with the corrected cross sections.

  3. Testing (Validating?) Cross Sections with ICSBEP Benchmarks

    SciTech Connect

    Kahler, Albert C. III

    2012-06-28

    We discuss how to use critical benchmarks from the International Handbook of Evaluated Criticality Safety Benchmark Experiments to determine the applicability of specific cross sections to the end-user's problem of interest. Particular attention is paid to making sure the selected suite of benchmarks includes the user's range of applicability (ROA).

  4. Neutron capture cross section of Am241

    NASA Astrophysics Data System (ADS)

    Jandel, M.; Bredeweg, T. A.; Bond, E. M.; Chadwick, M. B.; Clement, R. R.; Couture, A.; O'Donnell, J. M.; Haight, R. C.; Kawano, T.; Reifarth, R.; Rundberg, R. S.; Ullmann, J. L.; Vieira, D. J.; Wilhelmy, J. B.; Wouters, J. M.; Agvaanluvsan, U.; Parker, W. E.; Wu, C. Y.; Becker, J. A.

    2008-09-01

    The neutron capture cross section of Am241 for incident neutrons from 0.02 eV to 320 keV has been measured with the detector for advanced neutron capture experiments (DANCE) at the Los Alamos Neutron Science Center. The thermal neutron capture cross section was determined to be 665±33 b. Our result is in good agreement with other recent measurements. Resonance parameters for En<12 eV were obtained using an R-matrix fit to the measured cross section. The results are compared with values from the ENDF/B-VII.0, Mughabghab, JENDL-3.3, and JEFF-3.1 evaluations. Γn neutron widths for the first three resonances are systematically larger by 5-15% than the ENDF/B-VII.0 values. The resonance integral above 0.5 eV was determined to be 1553±7 b. Cross sections in the resolved and unresolved energy regions above 12 eV were calculated using the Hauser-Feshbach theory incorporating the width-fluctuation correction of Moldauer. The calculated results agree well with the measured data, and the extracted averaged resonance parameters in the unresolved resonance region are consistent with those for the resolved resonances.

  5. Cross Sections From Scalar Field Theory

    NASA Technical Reports Server (NTRS)

    Norbury, John W.; Dick, Frank; Norman, Ryan B.; Nasto, Rachel

    2008-01-01

    A one pion exchange scalar model is used to calculate differential and total cross sections for pion production through nucleon- nucleon collisions. The collisions involve intermediate delta particle production and decay to nucleons and a pion. The model provides the basic theoretical framework for scalar field theory and can be applied to particle production processes where the effects of spin can be neglected.

  6. Neutron Capture Cross Sections for Radioactive Nuclei

    NASA Astrophysics Data System (ADS)

    Tonchev, Anton; Bedrossian, Peter; Escher, Jutta; Scielzo, Nicholas

    2015-10-01

    Accurate neutron-capture cross sections for radioactive nuclei near or far away from the line of beta stability are crucial for understanding the nucleosynthesis of heavy elements. However, neutron-capture cross sections for short-lived radionuclides are difficult to measure due to the fact that the measurements require both highly radioactive samples and intense neutron sources. Essential ingredients for describing the γ decays following neutron capture are the γ-ray strength function and level densities. We will compare different indirect approaches for obtaining observables that can constrain Hauser-Feshbach statistical model calculations of capture cross sections. Specifically, we will consider photon scattering, transfer reactions, and beta-delayed neutron emission. Challenges that exist on the path to obtaining neutron-capture cross sections for reactions on isotopes far from stability will be discussed. This work was performed under the auspices of US DOE by LLNL under contract DE-AC52-07NA27344. Funding was provided via the LDRD-ERD-069 project.

  7. [Study for differential cross section of ring effect].

    PubMed

    Han, Dong; Chen, Liang-fu; Su, Lin; Tao, Jin-hua; Li, Shen-shen; Yu, Chao; Wang, Zi-feng

    2010-08-01

    The Ring effect is a significant limitation to the accuracy of the retrieval of trace gas constituents in atmosphere, while using satellite data with differential optical absorption spectroscopy technique. The Ring effect refers to the filling in of Fraunhofer lines, known as solar absorption lines, caused almost entirely by rotational Raman scattering. The inelastic component of the molecular scattering results in a net increase in radiance in the line because more radiation is shifted to the wavelength of an absorption line than shifted from this wavelength to other wavelengths. The rotational Raman scattering by N2 and Oz in the atmosphere is the main factor that leads to Ring effect. Basically, the Ring effect is considered as a pseudo-absorption process in retrieval of trace gas constituents in atmosphere. The solar spectrum measured by OMI/AURA is convolved with rotational Raman cross sections of N2 and O2, divided by the original solar spectrum, with a cubic polynomial subtracted off, to create differential Ring spectrum. This method has been suggested in order to obtain an effective differential Ring cross-section for the DOAS fitting process. The differential Ring spectrum could be used to improve the accuracy of the retrieval of the trace gases concentration. The results in this paper have been in basic agreement with the corresponding results calculated with RTM, and the R2 Statistic is 0. 966 3. PMID:20939324

  8. Inclusive jet cross section at the Tevatron

    SciTech Connect

    1998-01-01

    The authors report preliminary measurements of the central inclusive jet cross section at 1.8 TeV by the D0 and the CDF collaborations at the p{anti p} Fermilab collider. They are based on an integrated luminosity of 92 and 87 pb-1, respectively. The cross sections are measured as a function of jet transverse energy in the pseudorapidity interval 0.1 < 1,711 < 0.7 (CDF), and the two pseudorapidity ranges 1,711 < 0.5 and 0.1 < Inj < 0.7 (D0). D0 reports good agreement with the Next-to-Leading Order QCD predictions currently available. CDF observes an excess above 200 GeV, which can be accommodated with a modification in the gluon distribution function at high x.

  9. Cross sections required for FMIT dosimetry

    SciTech Connect

    Gold, R.; McElroy, W.N.; Lippincott, E.P.; Mann, F.M.; Oberg, D.L.; Roberts, J.H.; Ruddy, F.H.

    1980-05-02

    The Fusion Materials Irradiation Test (FMIT) facility, currently under construction, is designed to produce a high flux of high energy neutrons for irradiation effects experiments on fusion reactor materials. Characterization of the flux-fluence-spectrum in this rapidly varying neutron field requires adaptation and extension of currently available dosimetry techniques. This characterization will be carried out by a combination of active, passive, and calculational dosimetry. The goal is to provide the experimenter with accurate neutron flux-fluence-spectra at all positions in the test cell. Plans have been completed for a number of experimental dosimetry stations and provision for these facilities has been incorporated into the FMIT design. Overall needs of the FMIT irradiation damage program delineate goal accuracies for dosimetry that, in turn, create new requirements for high energy neutron cross section data. Recommendations based on these needs have been derived for required cross section data and accuracies.

  10. Proton Pair Production Cross Sections at BESIII

    NASA Astrophysics Data System (ADS)

    Zhou, Xiaorong

    Using data samples collected with the BESIII detector at the BEPCII collider, the Born cross section of e + e - to pbar{p} at 12 center-of-mass energies from 2232.4 to 3671.0 MeV is provided. The corresponding effective electromagnetic form factor of the proton is deduced under the assumption that the electric and magnetic form factors are equal. In addition, the ratio of electric to magnetic form factors are extracted for the data samples with larger statistics. The measured cross sections are in agreement with recent results from BaBar, improving the overall uncertainty by about 30%. The |GE/GM| ratios are close to unity and consistent with BaBar results in the same q2 region.

  11. Inclusive jet cross section measurement at CDF

    SciTech Connect

    Pagliarone, C.

    1996-08-01

    The CDF Collaboration has measured the inclusive jet cross section using 1992-93 collider data at 1.8 TeV. The CDF measurement is in very good agreement with NLO QCD predictions for transverse energies (E{sub T}) below 200 GeV. However, it is systematically higher than NLO QCD predictions for E{sub T} above 200 GeV.

  12. {sup 231}Pa photofission cross section

    SciTech Connect

    Soldatov, A.S.; Rudnikov, V.E.; Smirenkin, G.N.

    1995-12-01

    The measurements of the {sup 231}Pa yield and cross section photofission in the energy range 7-9 MeV are presented. These measurements are a continuation of similar measurements performed for the {gamma}-ray energy range 4.8-7 MeV. The entire collection of experimental data which combine the results obtained in the present work and in Ref. 1 was analyzed.

  13. Fusion cross sections measurements with MUSIC

    NASA Astrophysics Data System (ADS)

    Carnelli, P. F. F.; Fernández Niello, J. O.; Almaraz-Calderon, S.; Rehm, K. E.; Albers, M.; Digiovine, B.; Esbensen, H.; Henderson, D.; Jiang, C. L.; Nusair, O.; Palchan-Hazan, T.; Pardo, R. C.; Ugalde, C.; Paul, M.; Alcorta, M.; Bertone, P. F.; Lai, J.; Marley, S. T.

    2014-09-01

    The interaction between exotic nuclei plays an important role for understanding the reaction mechanism of the fusion processes as well as for the energy production in stars. With the advent of radioactive beams new frontiers for fusion reaction studies have become accessible. We have performed the first measurements of the total fusion cross sections in the systems 10 , 14 , 15C + 12C using a newly developed active target-detector system (MUSIC). Comparison of the obtained cross sections with theoretical predictions show a good agreement in the energy region accessible with existing radioactive beams. This type of comparison allows us to calibrate the calculations for cases that cannot be studied in the laboratory with the current experimental capabilities. The high efficiency of this active detector system will allow future measurements with even more neutron-rich isotopes. The interaction between exotic nuclei plays an important role for understanding the reaction mechanism of the fusion processes as well as for the energy production in stars. With the advent of radioactive beams new frontiers for fusion reaction studies have become accessible. We have performed the first measurements of the total fusion cross sections in the systems 10 , 14 , 15C + 12C using a newly developed active target-detector system (MUSIC). Comparison of the obtained cross sections with theoretical predictions show a good agreement in the energy region accessible with existing radioactive beams. This type of comparison allows us to calibrate the calculations for cases that cannot be studied in the laboratory with the current experimental capabilities. The high efficiency of this active detector system will allow future measurements with even more neutron-rich isotopes. This work is supported by the U.S. DOE Office of Nuclear Physics under Contract No. DE-AC02-06CH11357 and the Universidad Nacional de San Martin, Argentina, Grant SJ10/39.

  14. How to Calculate Colourful Cross Sections Efficiently

    SciTech Connect

    Gleisberg, Tanju; Hoeche, Stefan; Krauss, Frank

    2008-09-03

    Different methods for the calculation of cross sections with many QCD particles are compared. To this end, CSW vertex rules, Berends-Giele recursion and Feynman-diagram based techniques are implemented as well as various methods for the treatment of colours and phase space integration. We find that typically there is only a small window of jet multiplicities, where the CSW technique has efficiencies comparable or better than both of the other two methods.

  15. Nonperturbative corrections in resummed cross sections

    NASA Astrophysics Data System (ADS)

    Korchemsky, Gregory P.; Sterman, George

    1995-02-01

    We show that the resummation of large perturbative corrections in QCD leads to ambiguities in high energy cross sections that are suppressed by powers of large momentum scales. These ambiguities are caused by infrared renormalons, which are a general feature of resummed hardscattering functions in perturbative QCD, even though these functions are infrared safe order-by-order in perturbation theory. As in the case of the operator product expansion, the contributions of infrared renormalons to coefficient functions may be absorbed into the definition of higher-dimensional operators, which induce nonperturbative corrections that are power-suppressed at high energies. The strength of the suppression is determined by the location of the dominant infrared renormalon, which may be identified explicitly in the resummed series. In contrast to the operator product expansion, however, the relevant operators in factorized hadron-hadron scattering and jet cross sections are generally nonlocal in QCD, although they may be expressed as local operators in an effective theory for eikonalized quarks. In this context, we verify and interpret the presence of 1 / Q corrections to the inclusive Drell-Yan cross section with Q the pair mass. In a similar manner, we find exp (- b2 In Q) corrections in the impact parameter space of the transverse momentum distributions of the Drell-Yan process and e +6 - annihilation. We also show that the dominant nonperturbative corrections to cone-based jet cross sections behave as 1 /( Qδ), with δ the opening angle of the jet and Q the center of mass energy.

  16. KLOE results on hadronic cross section

    NASA Astrophysics Data System (ADS)

    Mandaglio, Giuseppe; Ambrosino, F.; Antonelli, A.; Antonelli, M.; Archilli, F.; Balwierz, I.; Bencivenni, G.; Bini, C.; Bloise, C; . Bocchetta, S.; Bossi, F.; Branchini, P.; Capon, G.; Capussela, T.; Ceradini, F.; Ciambrone, P.; Czerwiński, E.; De Lucia, E.; De Santis, A.; De Simone, P.; De Zorzi, G.; Denig, A.; Di Domenico, A.; Di Donato, C.; Di Micco, B.; Dreucci, M.; Felici, G.; Fiore, S.; Franzini, P.; Gatti, C.; Gauzzi, P.; Giovannella, S.; Graziani, E.; Jacewicz, M.; Kluge, W.; Lee-Franzini, J.; Lukin, P.; Martemianov, M.; Martini, M.; Massarotti, P.; Meola, S.; Miscetti, S.; Morello, G.; Moulson, M.; Müller, S; . Napolitano, M.; Nguyen, F.; Palutan, M.; Passeri, A.; Patera, V.; Prado Longhi, I.; Santangelo, P.; Sciascia, B.; Silarski, M.; Spadaro, T.; Taccini, C.; Tortora, L.; Venanzoni, G.; Versaci, R.; Xu, G.; Zdebik, J.; Babusci, D.; Badoni, D.; Bocci, V.; Budano, A.; Bulychjev, S. A; .; Caldeira Balkeståhl, L.; Campana, P.; Dané, E.; De Robertis, G.; Domenici, D.; Erriquez, O.; Fanizzi, G.; Giardina, G.; Gonnella, F.; Happacher, F.; Höistad, B.; Iafolla, L.; Iarocci, E.; Johansson, T.; Kowalewska, A.; Kulikov, V.; Kupsc, A.; Loddo, F.; Mandaglio, G.; Mascolo, M.; Matsyuk, M.; Messi, R.; Moricciani, D.; Ranieri, A.; Redmer, C. F.; Sarra, I.; Schioppa, M.; Sciubba, A.; Wiślicki, W.; Wolke, M.; KLOE/KLOE-2 Collaborations

    2012-03-01

    The KLOE experiment at the phi - factory DAΦNE is the first to have exploited Initial State Radiation (ISR) to precisely determine the e+e- → π+π-(γ) cross section below 1 GeV, representing the 70% of the leading order contribution to the muon anomaly. The leading order contribution ahloμ is presently the main source of uncertainty in the theoretical evaluation of the muon anomaly, and it can be evaluated by dispersion integral using the experimental measurement of hadronic cross section. A persistent discrepancy of about 3 σ between standard model (SM) prediction and experimental measurements of the muon anomalous magnetic moment has been up to now observed. The KLOE collaboration published two measurements of the π+π- cross section with the photon in the initial state emitted at small polar angle in Phys. Lett. B vol. 606 pg. 12 and vol. 670 pg. 285, and an independent measurement with the photon emitted at large polar angle in Phys. Lett. B vol. 700 pg. 102. These measurements were normalized to the DAΦNE luminosity. Recently, a new analysis deriving the pion form factor directly from measuring the bin-by-bin π+πγ and μ+μγ final states ratio has been performed. In this paper, the preliminary results of this new measurement and the comparison to the previous published ones, the impact on the evaluation of the hadronic contribution to the muon anomaly, the preliminary μ+μγ cross section measurement and the comparison with the PHOKHARA-MC prediction are presented.

  17. Quality Quantification of Evaluated Cross Section Covariances

    SciTech Connect

    Varet, S.; Dossantos-Uzarralde, P.

    2015-01-15

    Presently, several methods are used to estimate the covariance matrix of evaluated nuclear cross sections. Because the resulting covariance matrices can be different according to the method used and according to the assumptions of the method, we propose a general and objective approach to quantify the quality of the covariance estimation for evaluated cross sections. The first step consists in defining an objective criterion. The second step is computation of the criterion. In this paper the Kullback-Leibler distance is proposed for the quality quantification of a covariance matrix estimation and its inverse. It is based on the distance to the true covariance matrix. A method based on the bootstrap is presented for the estimation of this criterion, which can be applied with most methods for covariance matrix estimation and without the knowledge of the true covariance matrix. The full approach is illustrated on the {sup 85}Rb nucleus evaluations and the results are then used for a discussion on scoring and Monte Carlo approaches for covariance matrix estimation of the cross section evaluations.

  18. Higher order representation of the beam cross section deformation in large displacement finite element analysis

    NASA Astrophysics Data System (ADS)

    Li, Pengfei; Gantoi, Florentina M.; Shabana, Ahmed A.

    2011-12-01

    Most existing beam formulations assume that the cross section of the beam remains rigid regardless of the amplitude of the displacement. The absolute nodal coordinate formulation (ANCF); however, allows for the deformation of the cross section and leads to a more general beam models that capture the coupling between different modes of displacement. This paper examines the effect of the order of interpolation on the modes of deformation of the beam cross section using ANCF finite elements. To this end, a new two-dimensional shear deformable ANCF beam element is developed. The new finite element employs a higher order of interpolation, and allows for new cross section deformation modes that cannot be captured using previously developed shear deformable ANCF beam elements. The element developed in this study relaxes the assumption of planar cross section; thereby allowing for including the effect of warping as well as for different stretch values at different points on the element cross section. The displacement field of the new element is assumed to be cubic in the axial direction and quadratic in the transverse direction. Using this displacement field, more expressions for the element extension, shear and the cross section stretch can be systematically defined. The change in the cross section area is measured using Nanson's formula. Measures of the shear angle, extension, and cross section stretch can also be systematically defined using coordinate systems defined at the element material points. Using these local coordinate systems, expressions for a nominal shear angle are obtained. The differences between the cross section deformation modes obtained using the new higher order element and those obtained using the previously developed lower order elements are highlighted. Numerical examples are presented in order to compare the results obtained using the new finite element and the results obtained using previously developed ANCF finite elements.

  19. Propionaldehyde infrared cross-sections and band strengths

    NASA Astrophysics Data System (ADS)

    Köroğlu, Batikan; Loparo, Zachary; Nath, Janardan; Peale, Robert E.; Vasu, Subith S.

    2015-02-01

    The use of oxygenated biofuels reduces the greenhouse gas emissions; however, they also result in increased toxic aldehyde by-products, mainly formaldehyde, acetaldehyde, acrolein, and propionaldehyde. These aldehydes are carcinogenic and/or toxic and therefore it is important to understand their formation and destruction pathways in combustion and atmospheric systems. Accurate information about their infrared cross-sections and integrated strengths are crucially needed for development of quantitative detection schemes and modeling tools. Critical to the development of such diagnostics are accurate characterization of the absorption features of these species. In this study, the gas phase infrared spectra of propionaldehyde (also called propanal, CH3-CH2-CHO), a saturated three carbon aldehyde found in the exhaust emissions of biodiesel or diesel fuels, was studied using high resolution Fourier Transform Infrared (FTIR) spectroscopy over the wavenumber range of 750-3300 cm-1 and at room temperature 295 K. The absorption cross sections of propionaldehyde were recorded at resolutions of 0.08 and 0.096 cm-1 and at seven different pressures (4-33 Torr). The calculated band-strengths were reported and the integrated band intensity results were compared with values taken from the Pacific Northwest National Laboratory (PNNL) database (showing less than 2% discrepancy). The peak positions of the 19 different vibrational bands of propionaldehyde were also compared with previous studies taken at a lower resolution of 1 cm-1. To the best of our knowledge, the current FTIR measurements provide the first highest resolution infrared cross section data for propionaldehyde.

  20. Two-photon excitation cross-section in light and intermediate atoms

    NASA Technical Reports Server (NTRS)

    Omidvar, K.

    1980-01-01

    The method of explicit summation over the intermediate states is used along with LS coupling to derive an expression for two-photon absorption cross section in light and intermediate atoms in terms of integrals over radial wave functions. Two selection rules, one exact and one approximate, are also derived. In evaluating the radial integrals, for low-lying levels, the Hartree-Fock wave functions, and for high-lying levels, hydrogenic wave functions obtained by the quantum defect method are used. A relationship between the cross section and the oscillator strengths is derived. Cross sections due to selected transitions in nitrogen, oxygen, and chlorine are given. The expression for the cross section is useful in calculating the two-photon absorption in light and intermediate atoms.

  1. Capture cross section measurement analysis in the Californium-252 spectrum with the Monte Carlo method.

    PubMed

    Manojlovič, Stanko; Trkov, Andrej; Žerovnik, Gašper; Snoj, Luka

    2015-07-01

    Absolute average capture cross sections of gold, thorium, tantalum, molybdenum, copper and strontium in (252)Cf spontaneous fission neutron spectrum were simulated for two types of experiment setups preformed by Z. Dezso and J. Csikai and by L. Green. The experiments were simulated with MCNP5 using cross section data from the ENDF/B-VII.0 library. The determination of neutron backscattering was calculated with the use of neutron flagging. Correction factors to experimentally measured values were determined to obtain average cross sections in a pure (252)Cf spontaneous fission spectrum. Influence of concrete wall thickness, air moisture and room size on the average cross section was analyzed. Correction factors amounted to about 30%. Corrected values corresponding to average cross sections in a pure (252)Cf spectrum were calculated for (197)Au, (232)Th, (181)Ta, (98)Mo, (65)Cu and (84)Sr. Average cross sections were also calculated with the RR_UNC software using IRDFF-v.1.05 and ENDF/B-VII.0 libraries. The revised average radiative capture cross sections are 75.5±0.1 mb for (197)Au, 87.0±1.6 mb for (232)Th , 98.0±4.5 mb for (181)Ta, 21.2±0.5 mb for (98)Mo, 10.3±0.3 mb for (63)Cu, and 34.9±6.5 mb for (84)Sr.

  2. K-shell ionization cross section for Ti, Fe, Cu, Zr, and Ag

    SciTech Connect

    Benka, O.; Geretschlager, M.

    1981-04-01

    Absolute K-shell ionisation cross sections have been measured for thin targets of Ti, Fe, Cu, Zr and Ag for protons in the energy range 85-790 keV and for thin targets of Ti, Fe and Cu for He ions in the energy range 190-750 keV. In addition the relative variation of the cross sections with energy has been determined with high accuracy. The experimental values are compared to the perturbed stationary state approximation (CPSSR) and the semiclassical approximation (SCA). The CPSSR theory provides the best overall agreement with experimental cross sections. For higher scaled energies the CPSSR theory predicts the energy dependence of the cross sections very well but in the lower energy range it overpredicts the cross sections by as much as a factor of two and this overprediction seems to increase with Z/sub 2/ at a fixed scaled energy y. The SCA theory predicts slightly too large ionisation cross sections except for the lowest pounds values. The relative variation of the cross sections with energy is not well described in either energy range.

  3. High-resolution, VUV (147-201 nm) photoabsorption cross sections for C2H2 at 195 and 295 K

    NASA Technical Reports Server (NTRS)

    Smith, Peter L.; Yoshino, Kouichi; Parkinson, W. H.; Ito, Kenji; Stark, Glenn

    1991-01-01

    Results of measurements of photoabsorption cross sections of acetylene at 195 and 295 K in the wavelength range of 147-201 nm are reported. Short-wavelength data are obtained at 0.002 nm intervals, but no structure was observed on that scale. Emission and absorption lines from contaminant species in xenon and hydrogen discharges are used to determine the correct wavelength scale for the data. The uncertainty in the relative wavelengths is estimated to be about 0.004 nm, whereas the absolute wavelength values are accurate to + or - 0.043 nm. No significant photodestruction of C2H2 was found during the measurements. Cross-section values determined at the beginning portions of the measurements are indistinguishable from the values determined at the ends, thus demonstrating that there was no loss of absorbers.

  4. Detailed photonuclear cross-section calculations and astrophysical applications

    SciTech Connect

    Gardner, D.G.; Gardner, M.A.; Hoff, R.W.

    1989-06-15

    We have investigated the role of an isomeric state and its coupling to the ground state (g.s.) via photons and neutron inelastic scattering in a stellar environment by making detailed photonuclear and neutron cross-section calculations for /sup 176/Lu and /sup 210/Bi. In the case of /sup 176/Lu, the g.s. would function as an excellent galactic slow- (s-) process chronometer were it not for the 3.7-h isomer at 123 keV. Our calculations predicted much larger photon cross sections for production of the isomer, as well as a lower threshold, than had been assumed based on earlier measurements. These two factors combine to indicate that an enormous correction, a factor of 10/sup 7/, must be applied to shorten the current estimate of the half-life against photoexcitation of /sup 176/Lu as a function of temperature. This severely limits the use of /sup 176/Lu as a stellar chronometer and indicates a significantly lower temperature at which the two states reach thermal equilibrium. For /sup 210/Bi, our preliminary calculations of the production and destruction of the 3 /times/ 10/sup 6/ y isomeric state by neutrons and photons suggest that the /sup 210/Bi isomer may not be destroyed by photons as rapidly as assumed in certain stellar environments. This leads to an alternate production path of /sup 207/Pb and significantly affects presently interpreted lead isotopic abundances. We have been able to make such detailed nuclear cross-section calculations using: modern statistical-model codes of the Hauser-Feshbach type, with complete conservation of angular momentum and parity; reliable systematics of the input parameters required by these codes, including knowledge of the absolute gamma-ray strength-functions for E1, M1, and E2 transitions; and codes developed to compute large, discrete, nuclear level sets, their associated gamma-ray branchings, and the presence and location of isomeric states. 7 refs., 2 figs.

  5. Cross sections of high-energy hadron interactions in LLA QCD

    NASA Astrophysics Data System (ADS)

    Ryskin, M. G.; Shabelski, Yu. M.

    1992-06-01

    Total, total elastic and diffraction dissociation cross sections ofpp(bar pp) interactions are calculated in the leading logarithmic approximation of QCD in the energy regionsqrt s = 0.05 - 200TeV accounting for absorption effects at the quark level. Our calculations with very large intercept of bare pomeron (Δ>1/2) are in qualitative agreement with the data; however, we predict comparatively large cross section of double-diffraction dissociation.

  6. Averaging cross section data so we can fit it

    SciTech Connect

    Brown, D.

    2014-10-23

    The 56Fe cross section we are interested in have a lot of fluctuations. We would like to fit the average of the cross section with cross sections calculated within EMPIRE. EMPIRE is a Hauser-Feshbach theory based nuclear reaction code, requires cross sections to be smoothed using a Lorentzian profile. The plan is to fit EMPIRE to these cross sections in the fast region (say above 500 keV).

  7. Multicollinearity in cross-sectional regressions

    NASA Astrophysics Data System (ADS)

    Lauridsen, Jørgen; Mur, Jesùs

    2006-10-01

    The paper examines robustness of results from cross-sectional regression paying attention to the impact of multicollinearity. It is well known that the reliability of estimators (least-squares or maximum-likelihood) gets worse as the linear relationships between the regressors become more acute. We resolve the discussion in a spatial context, looking closely into the behaviour shown, under several unfavourable conditions, by the most outstanding misspecification tests when collinear variables are added to the regression. A Monte Carlo simulation is performed. The conclusions point to the fact that these statistics react in different ways to the problems posed.

  8. The calculation of radar cross sections

    NASA Astrophysics Data System (ADS)

    Pizer, R.

    1980-04-01

    The FORTRAN program CHAOS, used for calculating cross sections is described including the physical approximations used to simplify Maxwell's equations. The scattering bodies are extended to both open and closed surfaces. The numerical methods used are supplied. The problems of wire junctions, of finite conductivity and the attaching of lumped loads to the structure are considered. Techniques for dealing with bodies having rotational or left-right symmetries are examined as well as the sparse matrix approximation and the complex frequency version of CHAOS. The formula used to calculate the impedance matrix elements, and the conventions adopted concerning coordinate systems and polarization are included.

  9. CCKT Calculation of e-H Total Cross Sections

    NASA Technical Reports Server (NTRS)

    Bhatia, Aaron K.; Schneider, B. I.; Temkin, A.; Fisher, Richard R. (Technical Monitor)

    2002-01-01

    We are in the process of carrying out calculations of e-H total cross sections using the 'complex-correlation Kohn-T' (CCKT) method. In a later paper, we described the methodology more completely, but confined calculations to the elastic scattering region, with definitive, precision results for S-wave phase shifts. Here we extend the calculations to the (low) continuum (1 much less than k(exp 2) much less than 3) using a Green's function formulation. This avoids having to solve integro-differential equations; rather we evaluate indefinite integrals involving appropriate Green's functions and the (complex) optical potential to find the scattering function u(r). From the asymptotic form of u(r) we extract a T(sub L) which is a complex number. From T(sub L), elastic sigma(sub L)(elastic) = 4pi(2L+1)((absolute value of T(sub L))(exp 2)), and total sigma (sub L)(total) = 4pi/k(2L+1)Im(T(sub L)) cross sections follow.

  10. Temperature dependence of the cross section for the fragmentation of thymine via dissociative electron attachment

    NASA Astrophysics Data System (ADS)

    Kopyra, Janina; Abdoul-Carime, Hassan

    2015-05-01

    Providing experimental values for absolute Dissociative Electron Attachment (DEA) cross sections for nucleobases at realistic biological conditions is a considerable challenge. In this work, we provide the temperature dependence of the cross section, σ, of the dehydrogenated thymine anion (T - H)- produced via DEA. Within the 393-443 K temperature range, it is observed that σ varies by one order of magnitude. By extrapolating to a temperature of 313 K, the relative DEA cross section for the production of the dehydrogenated thymine anion at an incident energy of 1 eV decreases by 2 orders of magnitude and the absolute value reaches approximately 6 × 10-19 cm2. These quantitative measurements provide a benchmark for theoretical prediction and also a contribution to a more accurate description of the effects of ionizing radiation on molecular medium.

  11. Temperature dependence of the cross section for the fragmentation of thymine via dissociative electron attachment

    SciTech Connect

    Kopyra, Janina; Abdoul-Carime, Hassan

    2015-05-07

    Providing experimental values for absolute Dissociative Electron Attachment (DEA) cross sections for nucleobases at realistic biological conditions is a considerable challenge. In this work, we provide the temperature dependence of the cross section, σ, of the dehydrogenated thymine anion (T − H){sup −} produced via DEA. Within the 393-443 K temperature range, it is observed that σ varies by one order of magnitude. By extrapolating to a temperature of 313 K, the relative DEA cross section for the production of the dehydrogenated thymine anion at an incident energy of 1 eV decreases by 2 orders of magnitude and the absolute value reaches approximately 6 × 10{sup −19} cm{sup 2}. These quantitative measurements provide a benchmark for theoretical prediction and also a contribution to a more accurate description of the effects of ionizing radiation on molecular medium.

  12. Windowed multipole for cross section Doppler broadening

    NASA Astrophysics Data System (ADS)

    Josey, C.; Ducru, P.; Forget, B.; Smith, K.

    2016-02-01

    This paper presents an in-depth analysis on the accuracy and performance of the windowed multipole Doppler broadening method. The basic theory behind cross section data is described, along with the basic multipole formalism followed by the approximations leading to windowed multipole method and the algorithm used to efficiently evaluate Doppler broadened cross sections. The method is tested by simulating the BEAVRS benchmark with a windowed multipole library composed of 70 nuclides. Accuracy of the method is demonstrated on a single assembly case where total neutron production rates and 238U capture rates compare within 0.1% to ACE format files at the same temperature. With regards to performance, clock cycle counts and cache misses were measured for single temperature ACE table lookup and for windowed multipole. The windowed multipole method was found to require 39.6% more clock cycles to evaluate, translating to a 7.9% performance loss overall. However, the algorithm has significantly better last-level cache performance, with 3 fewer misses per evaluation, or a 65% reduction in last-level misses. This is due to the small memory footprint of the windowed multipole method and better memory access pattern of the algorithm.

  13. Actinide Targets for Neutron Cross Section Measurements

    SciTech Connect

    John D. Baker; Christopher A. McGrath

    2006-10-01

    The Advanced Fuel Cycle Initiative (AFCI) and the Generation IV Reactor Initiative have demonstrated a lack of detailed neutron cross-sections for certain "minor" actinides, those other than the most common (235U, 238U, and 239Pu). For some closed-fuel-cycle reactor designs more than 50% of reactivity will, at some point, be derived from "minor" actinides that currently have poorly known or in some cases not measured (n,?) and (n,f) cross sections. A program of measurements under AFCI has begun to correct this. One of the initial hurdles has been to produce well-characterized, highly isotopically enriched, and chemically pure actinide targets on thin backings. Using a combination of resurrected techniques and new developments, we have made a series of targets including highly enriched 239Pu, 240Pu, and 242Pu. Thus far, we have electrodeposited these actinide targets. In the future, we plan to study reductive distillation to achieve homogeneous, adherent targets on thin metal foils and polymer backings. As we move forward, separated isotopes become scarcer, and safety concerns become greater. The chemical purification and electodeposition techniques will be described.

  14. Resonance analysis and evaluation of the sup 235 U neutron induced cross sections

    SciTech Connect

    Leal, L.C.

    1990-06-01

    Neutron cross sections of fissile nuclei are of considerable interest for the understanding of parameters such as resonance absorption, resonance escape probability, resonance self-shielding,and the dependence of the reactivity on temperature. In the present study, new techniques for the evaluation of the {sup 235}U neutron cross sections are described. The Reich-Moore formalism of the Bayesian computer code SAMMY was used to perform consistent R-matrix multilevel analyses of the selected neutron cross-section data. The {Delta}{sub 3}-statistics of Dyson and Mehta, along with high-resolution data and the spin-separated fission cross-section data, have provided the possibility of developing a new methodology for the analysis and evaluation of neutron-nucleus cross sections. The results of the analysis consists of a set of resonance parameters which describe the {sup 235}U neutron cross sections up to 500 eV. The set of resonance parameters obtained through a R-matrix analysis are expected to satisfy statistical properties which lead to information on the nuclear structure. The resonance parameters were tested and showed good agreement with the theory. It is expected that the parametrization of the {sub 235}U neutron cross sections obtained in this dissertation represents the current state of art in data as well as in theory and, therefore, can be of direct use in reactor calculations. 44 refs., 21 figs., 8 tabs.

  15. Lunar Radar Cross Section at Low Frequency

    NASA Technical Reports Server (NTRS)

    Rodriguez, P.; Kennedy, E. J.; Kossey, P.; McCarrick, M.; Kaiser, M. L.; Bougeret, J.-L.; Tokarev, Y. V.

    2002-01-01

    Recent bistatic measurements of the lunar radar cross-section have extended the spectrum to long radio wavelength. We have utilized the HF Active Auroral Research Program (HAARP) radar facility near Gakona, Alaska to transmit high power pulses at 8.075 MHz to the Moon; the echo pulses were received onboard the NASA/WIND spacecraft by the WAVES HF receiver. This lunar radar experiment follows our previous use of earth-based HF radar with satellites to conduct space experiments. The spacecraft was approaching the Moon for a scheduled orbit perturbation when our experiment of 13 September 2001 was conducted. During the two-hour experiment, the radial distance of the satellite from the Moon varied from 28 to 24 Rm, where Rm is in lunar radii.

  16. Correlation cross sections along the international border

    SciTech Connect

    Martiniuk, C.D. ); Le Fever, J.A.; Anderson, S.B. )

    1991-06-01

    The Manitoba-North Dakota (Canada-US) stratigraphic correlation project is a joint study between the Petroleum Branch of Manitoba Energy and Mines and the North Dakota Geological Survey. It is an attempt to correlate the differing stratigraphic terminologies established in the two jurisdictions by providing a reference cross section across the international boundary. The study involves the subsurface correlation of logs of the Paleozoic and Mesozoic sequences in the Manitoba and North Dakota portions of the Williston basin. The Paleozoic and Mesozoic sequences are subdivided for presentation into the following stratigraphic intervals: (a) Cambrian-Ordovician-Silurian, (b) Devonian, (c) Mississippian, (d) Jurassic, and (e) Cretaceous. Wireline logs show the actual stratigraphic correlations. A nomenclature chart is also presented from each sequence. In addition, the sections include a generalized description of lithologies, thicknesses, environments of deposition, and petroleum potential for each geographic area.

  17. Collision cross sections for structural proteomics.

    PubMed

    Marklund, Erik G; Degiacomi, Matteo T; Robinson, Carol V; Baldwin, Andrew J; Benesch, Justin L P

    2015-04-01

    Ion mobility mass spectrometry (IM-MS) allows the structural interrogation of biomolecules by reporting their collision cross sections (CCSs). The major bottleneck for exploiting IM-MS in structural proteomics lies in the lack of speed at which structures and models can be related to experimental data. Here we present IMPACT (Ion Mobility Projection Approximation Calculation Tool), which overcomes these twin challenges, providing accurate CCSs up to 10(6) times faster than alternative methods. This allows us to assess the CCS space presented by the entire structural proteome, interrogate ensembles of protein conformers, and monitor molecular dynamics trajectories. Our data demonstrate that the CCS is a highly informative parameter and that IM-MS is of considerable practical value to structural biologists. PMID:25800554

  18. Preliminary cross section of Englebright Lake sediments

    USGS Publications Warehouse

    Snyder, Noah P.; Hampton, Margaret A.

    2003-01-01

    Overview -- The Upper Yuba River Studies Program is a CALFED-funded, multidisciplinary investigation of the feasibility of introducing anadromous fish species to the Yuba River system upstream of Englebright Dam. Englebright Lake (Figure 1 on poster) is a narrow, 14-km-long reservoir located in the northern Sierra Nevada, northeast of Marysville, CA. The dam was completed in 1941 for the primary purpose of trapping sediment derived from mining operations in the Yuba River watershed. Possible management scenarios include lowering or removing Englebright Dam, which could cause the release of stored sediments and associated contaminants, such as mercury used extensively in 19th-century hydraulic gold mining. Transport of released sediment to downstream areas could increase existing problems including flooding and mercury bioaccumulation in sport fish. To characterize the extent, grain size, and chemistry of this sediment, a coring campaign was done in Englebright Lake in May and June 2002. More than twenty holes were drilled at 7 different locations along the longitudinal axis of the reservoir (Figure 4 on poster), recovering 6 complete sequences of post-reservoir deposition and progradation. Here, a longitudinal cross section of Englebright Lake is presented (Figure 5 on poster), including pre-dam and present-day topographic profiles, and sedimentologic sections for each coring site. This figure shows the deltaic form of the reservoir deposit, with a thick upper section consisting of sand and gravel overlying silt, a steep front, and a thinner lower section dominated by silt. The methodologies used to create the reservoir cross section are discussed in the lower part of this poster.

  19. Status update on the NIFFTE high precision fission cross section measurement program

    SciTech Connect

    Laptev, Alexander B; Tovesson, Fredrik; Burgett, Eric; Greife, Uwe; Grimes, Steven; Heffner, Michael D; Hertel, Nolan E; Hill, Tony; Isenhower, Donald; Klay, Jennifer L; Kornilov, Nickolay; Kudo, Ryuho; Loveland, Walter; Massey, Thomas; Mc Grath, Chris; Pickle, Nathan; Qu, Hai; Sharma, Sarvagya; Snyder, Lucas; Thornton, Tyler; Towell, Rusty S; Watson, Shon

    2010-01-01

    The Neutron Induced Fission Fragment Tracking Experiment (NIFFTE) program has been underway for nearly two years. The program's mission is to measure fission cross sections of the primary fissionable and fissile materials ({sup 235}U, {sup 239}Pu, {sup 238}U) as well as the minor actinides across energies from approximately 50 keV up to 20 MeV with an absolute uncertainty of less than one percent while investigating energy ranges from below an eV to 600 MeV. This basic nuclear physics data is being reinvestigated to support the next generation power plants and a fast burner reactor program. Uncertainties in the fast, resolved and unresolved resonance regions in plutonium and other transuranics are extremely large, dominating safety margins in the next generation nuclear power plants and power plants of today. This basic nuclear data can be used to support all aspects of the nuciear renaissance. The measurement campaign is utilizing a Time Projection Chamber or TPC as the tool to measure these cross sections to these unprecedented levels. Unlike traditional fission cross section measurements using time-of-flight and a multiple fission foil configurations in which fission cross sections in relation to that of {sup 235}U are performed, the TPC project uses time-of-flight and hydrogen as the benchmark cross section. Using the switch to hydrogen, a simple, smooth cross section that can be used which removes the uncertainties associated with the resolved and unresolved resonances in {sup 235}U.

  20. Determination of differential cross sections for electron-impact excitation of electronic states of molecular oxygen

    SciTech Connect

    Campbell, L.; Green, M. A.; Brunger, M. J.; Teubner, P. J. O.; Cartwright, D. C.

    2000-02-01

    The development and initial results of a method for the determination of differential cross sections for electron scattering by molecular oxygen are described. The method has been incorporated into an existing package of computer programs which, given spectroscopic factors, dissociation energies and an energy-loss spectrum for electron-impact excitation, determine the differential cross sections for each electronic state relative to that of the elastic peak. Enhancements of the original code were made to deal with particular aspects of electron scattering from O{sub 2}, such as the overlap of vibrational levels of the ground state with transitions to excited states, and transitions to levels close to and above the dissocation energy in the Herzberg and Schumann-Runge continua. The utility of the code is specifically demonstrated for the ''6-eV states'' of O{sub 2}, where we report absolute differential cross sections for their excitation by 15-eV electrons. In addition an integral cross section, derived from the differential cross section measurements, is also reported for this excitation process and compared against available theoretical results. The present differential and integral cross sections for excitation of the ''6-eV states'' of O{sub 2} are the first to be reported in the literature for electron-impact energies below 20 eV. (c) 2000 The American Physical Society.

  1. Measurements of the Ultraviolet Fluorescence Cross Sections and Spectra of Bacillus Anthracis Simulants

    SciTech Connect

    Stephens, J.R.

    1998-09-01

    Measurements of the ultraviolet autofluorescence spectra and absolute cross sections of the Bacillus anthracis (Ba) simulants Bacillus globigii (Bg), Bacillus megaterium (Bm), Bacillus subtilis (Bs), and Bacillus cereus (Bc) were measured. Fluorescence spectra and cross sections of pine pollen (Pina echinata) were measured for comparison. Both dried vegetative cells and spores separated from the sporulated vegetative material were studied. The spectra were obtained by suspending a small number (<10) of particles in air in our Single Particle Spectroscopy Apparatus (SPSA), illuminating the particles with light from a spectrally filtered arc lamp, and measuring the fluorescence spectra of the particles. The illumination was 280 nm (20 nm FWHM) and the fluorescence spectra was measured between 300 and 450 nm. The fluorescence cross section of vegetative Bg peaks at 320 nm with a maximum cross section of 5 X 10{sup -14} cm{sup 2}/sr-nm-particle while the Bg spore fluorescence peaks at 310 nm with peak fluorescence of 8 X 10{sup -15} cm{sup 2}/sr-nm-particle. Pine pollen particles showed a higher fluorescence peaking at 355 nm with a cross section of 1.7 X 10{sup -13} cm{sup 2}/sr-nm-particle. Integrated cross sections ranged from 3.0 X 10{sup -13} for the Bg spores through 2.25 X 10{sup -12} (cm{sup 2}/sr-particle) for the vegetative cells.

  2. Experiments on Antiprotons: Antiproton-Nucleon Cross Sections

    DOE R&D Accomplishments Database

    Chamberlain, Owen; Keller, Donald V.; Mermond, Ronald; Segre, Emilio; Steiner, Herbert M.; Ypsilantis, Tom

    1957-07-22

    In this paper experiments are reported on annihilation and scattering of antiprotons in H{sub 2}O , D{sub 2}O, and O{sub 2}. From the data measured it is possible to obtain an antiproton-proton and an antiproton-deuteron cross section at 457 Mev (lab). Further analysis gives the p-p and p-n cross sections as 104 mb for the p-p reaction cross section and 113 mb for the p-n reaction cross section. The respective annihilation cross sections are 89 and 74 mb. The Glauber correction necessary in order to pass from the p-d to the p-n cross section by subtraction of the p-p cross section is unfortunately large and somewhat uncertain. The data are compared with the p-p and p-n cross sections and with other results on p-p collisions.

  3. Single-level resonance parameters fit nuclear cross-sections

    NASA Technical Reports Server (NTRS)

    Drawbaugh, D. W.; Gibson, G.; Miller, M.; Page, S. L.

    1970-01-01

    Least squares analyses of experimental differential cross-section data for the U-235 nucleus have yielded single level Breit-Wigner resonance parameters that fit, simultaneously, three nuclear cross sections of capture, fission, and total.

  4. Electron Elastic-Scattering Cross-Section Database

    National Institute of Standards and Technology Data Gateway

    SRD 64 NIST Electron Elastic-Scattering Cross-Section Database (PC database, no charge)   This database provides values of differential elastic-scattering cross sections, corresponding total elastic-scattering cross sections, phase shifts, and transport cross sections for elements with atomic numbers from 1 to 96 and for electron energies between 50 eV and 20,000 eV (in steps of 1 eV).

  5. Collision Cross Sections for 20 Protonated Amino Acids: Fourier Transform Ion Cyclotron Resonance and Ion Mobility Results

    NASA Astrophysics Data System (ADS)

    Anupriya; Jones, Chad A.; Dearden, David V.

    2016-08-01

    We report relative dephasing cross sections for the 20 biogenic protonated amino acids measured using the cross sectional areas by Fourier transform ion cyclotron resonance (CRAFTI) technique at 1.9 keV in the laboratory reference frame, as well as momentum transfer cross sections for the same ions computed from Boltzmann-weighted structures determined using molecular mechanics. Cross sections generally increase with increasing molecular weight. Cross sections for aliphatic and aromatic protonated amino acids are larger than the average trend, suggesting these side chains do not fold efficiently. Sulfur-containing protonated amino acids have smaller than average cross sections, reflecting the mass of the S atom. Protonated amino acids that can internally hydrogen-bond have smaller than average cross sections, reflecting more extensive folding. The CRAFTI measurements correlate well with results from drift ion mobility (IMS) and traveling wave ion mobility (TWIMS) spectrometric measurements; CRAFTI results correlate with IMS values approximately as well as IMS and TWIMS values from independent measurements correlate with each other. Both CRAFTI and IMS results correlate well with the computed momentum transfer cross sections, suggesting both techniques provide accurate molecular structural information. Absolute values obtained using the various methods differ significantly; in the case of CRAFTI, this may be due to errors in measurements of collision gas pressure, measurement of excitation voltage, and/or dependence of cross sections on kinetic energy.

  6. Collision Cross Sections for 20 Protonated Amino Acids: Fourier Transform Ion Cyclotron Resonance and Ion Mobility Results.

    PubMed

    Anupriya; Jones, Chad A; Dearden, David V

    2016-08-01

    We report relative dephasing cross sections for the 20 biogenic protonated amino acids measured using the cross sectional areas by Fourier transform ion cyclotron resonance (CRAFTI) technique at 1.9 keV in the laboratory reference frame, as well as momentum transfer cross sections for the same ions computed from Boltzmann-weighted structures determined using molecular mechanics. Cross sections generally increase with increasing molecular weight. Cross sections for aliphatic and aromatic protonated amino acids are larger than the average trend, suggesting these side chains do not fold efficiently. Sulfur-containing protonated amino acids have smaller than average cross sections, reflecting the mass of the S atom. Protonated amino acids that can internally hydrogen-bond have smaller than average cross sections, reflecting more extensive folding. The CRAFTI measurements correlate well with results from drift ion mobility (IMS) and traveling wave ion mobility (TWIMS) spectrometric measurements; CRAFTI results correlate with IMS values approximately as well as IMS and TWIMS values from independent measurements correlate with each other. Both CRAFTI and IMS results correlate well with the computed momentum transfer cross sections, suggesting both techniques provide accurate molecular structural information. Absolute values obtained using the various methods differ significantly; in the case of CRAFTI, this may be due to errors in measurements of collision gas pressure, measurement of excitation voltage, and/or dependence of cross sections on kinetic energy. Graphical Abstract ᅟ. PMID:27220844

  7. Viscous Flow through Pipes of Various Cross-Sections

    ERIC Educational Resources Information Center

    Lekner, John

    2007-01-01

    An interesting variety of pipe cross-sectional shapes can be generated, for which the Navier-Stokes equations can be solved exactly. The simplest cases include the known solutions for elliptical and equilateral triangle cross-sections. Students can find pipe cross-sections from solutions of Laplace's equation in two dimensions, and then plot the…

  8. Mental Visualization of Objects from Cross-Sectional Images

    ERIC Educational Resources Information Center

    Wu, Bing; Klatzky, Roberta L.; Stetten, George D.

    2012-01-01

    We extended the classic anorthoscopic viewing procedure to test a model of visualization of 3D structures from 2D cross-sections. Four experiments were conducted to examine key processes described in the model, localizing cross-sections within a common frame of reference and spatiotemporal integration of cross sections into a hierarchical object…

  9. Measurements of ultra-low-energy electron scattering cross sections of atoms and molecules

    SciTech Connect

    Kitajima, M.; Shigemura, K.; Kurokawa, M.; Odagiri, T.; Kato, H.; Hoshino, M.; Tanaka, H.; Ito, K.

    2014-03-05

    A new experimental technique for the total cross section measurements of ultra-low energy electron collisions with atoms and molecules utilizing the synchrotron radiation is presented. The technique employs a combination of the penetrating field technique and the threshold photoionization of rare gas atoms using the synchrotron radiation as an electron source in order to produce a high resolution electron beam at very low energy. Absolute total cross sections for electron scattering from He, Ne, Ar, Kr, and Xe in the energy region from extremely low electron energy to 20 eV are presented.

  10. Cross Section of OH Radical Overtone Transition near 7028 cm(-1) and Measurement of the Rate Constant of the Reaction of OH with HO2 Radicals.

    PubMed

    Assaf, Emmanuel; Fittschen, Christa

    2016-09-15

    The absorption cross section of an overtone transition of OH radicals at 7028.831 cm(-1) has been measured using an improved experimental setup coupling laser photolysis to three individual time-resolved detection techniques. Time-resolved relative OH radical profiles were measured by laser-induced fluorescence (LIF), and their absolute profiles have been obtained by cw-cavity ring-down spectroscopy (cw-CRDS). HO2 radicals were quantified simultaneously at the well-characterized absorption line at 6638.21 cm(-1) by a second cw-CRDS absorption path. Initial OH concentrations and thus their absorption cross sections have been deduced from experiments of 248 nm photolysis of H2O2: OH and HO2 profiles have been fitted to a simple kinetic model using well-known rate constants. The rate constant of the reaction between OH and HO2 radicals turned out to be sensitive to the deduction of the initial OH concentration and has been revisited in this work: OH decays have been observed in the presence of varying excess HO2 concentrations. A rate constant of (1.02 ± 0.06) × 10(-10) cm(3) s(-1) has been obtained, in good agreement with previous measurements and recent recommendations. An absorption cross section of σOH = (1.54 ± 0.1) × 10(-19) cm(2) at a total pressure of 50 Torr helium has been obtained from consistent fitting of OH and HO2 profiles in a large range of concentrations.

  11. Cross Section of OH Radical Overtone Transition near 7028 cm(-1) and Measurement of the Rate Constant of the Reaction of OH with HO2 Radicals.

    PubMed

    Assaf, Emmanuel; Fittschen, Christa

    2016-09-15

    The absorption cross section of an overtone transition of OH radicals at 7028.831 cm(-1) has been measured using an improved experimental setup coupling laser photolysis to three individual time-resolved detection techniques. Time-resolved relative OH radical profiles were measured by laser-induced fluorescence (LIF), and their absolute profiles have been obtained by cw-cavity ring-down spectroscopy (cw-CRDS). HO2 radicals were quantified simultaneously at the well-characterized absorption line at 6638.21 cm(-1) by a second cw-CRDS absorption path. Initial OH concentrations and thus their absorption cross sections have been deduced from experiments of 248 nm photolysis of H2O2: OH and HO2 profiles have been fitted to a simple kinetic model using well-known rate constants. The rate constant of the reaction between OH and HO2 radicals turned out to be sensitive to the deduction of the initial OH concentration and has been revisited in this work: OH decays have been observed in the presence of varying excess HO2 concentrations. A rate constant of (1.02 ± 0.06) × 10(-10) cm(3) s(-1) has been obtained, in good agreement with previous measurements and recent recommendations. An absorption cross section of σOH = (1.54 ± 0.1) × 10(-19) cm(2) at a total pressure of 50 Torr helium has been obtained from consistent fitting of OH and HO2 profiles in a large range of concentrations. PMID:27556141

  12. Abdominal sarcoidosis: cross-sectional imaging findings

    PubMed Central

    Gezer, Naciye Sinem; Başara, Işıl; Altay, Canan; Harman, Mustafa; Rocher, Laurence; Karabulut, Nevzat; Seçil, Mustafa

    2015-01-01

    Sarcoidosis is a multisystem inflammatory disease of unknown etiology. The lungs and the lymphoid system are the most commonly involved organs. Extrapulmonary involvement is reported in 30% of patients, and the abdomen is the most common extrapulmonary site with a frequency of 50%–70%. Although intra-abdominal sarcoidosis is usually asymptomatic, its presence may affect the prognosis and treatment options. The lesions are less characteristic and may mimick neoplastic or infectious diseases such as lymphoma, diffuse metastasis, and granulomatous inflammation. The liver and spleen are the most common abdominal sites of involvement. Sarcoidosis of the gastrointestinal system, pancreas, and kidneys are extremely rare. Adenopathy which is most commonly found in the porta hepatis, exudative ascites, and multiple granulomatous nodules studding the peritoneum are the reported manifestations of abdominal sarcoidosis. Since abdominal sarcoidosis is less common and long-standing, unrecognized disease can result in significant morbidity and mortality. Imaging contributes to diagnosis and management of intra-abdominal sarcoidosis. In this report we reviewed the cross-sectional imaging findings of hepatobiliary, gastrointestinal, and genitourinary sarcoidosis. PMID:25512071

  13. The hadronic cross section measurement at KLOE

    NASA Astrophysics Data System (ADS)

    Valeriani, B.; KLOE Collaboration

    2004-04-01

    KLOE uses the radiative return to measure the hadronic cross section e+e- → π +- at DANE. Theemission of one or more hard photons in the initial state ( ISR) reduces the collision energy, otherwise fixed at 1020 MeV, and allows to perform an effective scan of the two pions invariant mass squared, sπ, in the whole sπ, region from threshold to mφ2. An extremely accurate knowledge of experimental systematics, background, luminosity and, on the theoretical side, a precise description of initial state radiation are needed to perform a competitive measurement. We present here the status of the analysis of 140 pb -1 collected in 2001. A preliminary evaluation of the hadronic contribution to aμ in the sπ range between 0.37 GeV 2 and 0.93 GeV 2 yields aμ = 378.4 ± 0.8 stat ± 4.5 syst ± 3.0 theo ± 3.8 FSR, consistent with the CMD-2 result and confirming the present discrepancy between e+e - and τ data.

  14. APPARATUS FOR MEASURING TOTAL NEUTRON CROSS SECTIONS

    DOEpatents

    Cranberg, L.

    1959-10-13

    An apparatus is described for measuring high-resolution total neutron cross sections at high counting rate in the range above 50-kev neutron energy. The pulsed-beam time-of-flight technique is used to identify the neutrons of interest which are produced in the target of an electrostatic accelerator. Energy modulation of the accelerator . makes it possible to make observations at 100 energy points simultaneously. 761O An apparatus is described for monitoring the proton resonance of a liquid which is particulariy useful in the continuous purity analysis of heavy water. A hollow shell with parallel sides defines a meander chamber positioned within a uniform magnetic fieid. The liquid passes through an inlet at the outer edge of the chamber and through a spiral channel to the central region of the chamber where an outlet tube extends into the chamber perpendicular to the magnetic field. The radiofrequency energy for the monitor is coupled to a coil positioned coaxially with the outlet tube at its entrance point within the chamber. The improvement lies in the compact mechanical arrangement of the monitor unit whereby the liquid under analysis is subjected to the same magnetic field in the storage and sensing areas, and the entire unit is shielded from external electrostatic influences.

  15. [Fast neutron cross section measurements]. Progress report

    SciTech Connect

    Knoll, G.F.

    1992-10-26

    From its inception, the Nuclear Data Project at the University of Michigan has concentrated on two major objectives: (1) to carry out carefully controlled nuclear measurements of the highest possible reliability in support of the national nuclear data program, and (2) to provide an educational opportunity for students with interests in experimental nuclear science. The project has undergone a successful transition from a primary dependence on our photoneutron laboratory to one in which our current research is entirely based on a unique pulsed 14 MeV fast neutron facility. The new experimental facility is unique in its ability to provide nanosecond bursts of 14 MeV neutrons under conditions that are ``clean`` and as scatter-free as possible, and is the only one of its type currently in operation in the United States. It has been designed and put into operation primarily by graduate students, and has met or exceeded all of its important initial performance goals. We have reached the point of its routine operation, and most of the data are now in hand that will serve as the basis for the first two doctoral dissertations to be written by participating graduate students. Our initial results on double differential neutron cross sections will be presented at the May 1993 Fusion Reactor Technology Workshop. We are pleased to report that, after investing several years in equipment assembly and optimization, the project has now entered its ``data production`` phase.

  16. Electron-impact-ionization cross section for the hydrogen atom

    NASA Astrophysics Data System (ADS)

    Hu, W.; Fang, D.; Wang, Y.; Yang, F.

    1994-02-01

    A distorted-wave Born exchange approximation was used to calculate the cross section for electron-impact ionization of the hydrogen atoms. Both the integral and energy-differential cross section were calculated. The results were compared with the latest experimental data and other theoretical calculations. Comparison shows that the calculations agree with differential cross-section measurements in general. For integral cross sections the calculation shows a better agreement with an earlier measurement [M.B. Shah, D. S. Elliott, and H. B. Gilbody, J. Phys. B 20, 3501 (1987)] in which the cross sections are normalized to the first Born approximation.

  17. Graphs of the cross sections in the recommended Monte Carlo cross-section library at the Los Alamos Scientific Laboratory

    SciTech Connect

    Soran, P.D.; Seamon, R.E.

    1980-05-01

    Graphs of all neutron cross sections and photon production cross sections on the Recommended Monte Carlo Cross Section (RMCCS) library have been plotted along with local neutron heating numbers. Values for anti ..nu.., the average number of neutrons per fission, are also given.

  18. Employee engagement within the NHS: a cross-sectional study

    PubMed Central

    Jeve, Yadava Bapurao; Oppenheimer, Christina; Konje, Justin

    2015-01-01

    Background: Employee engagement is the emotional commitment of the employee towards the organisation. We aimed to analyse baseline work engagement using Utrecht Work Engagement Scale (UWES) at a teaching hospital. Methods: We have conducted a cross-sectional study within the National Health Service (NHS) Teaching Hospital in the UK. All participants were working age population from both genders directly employed by the hospital. UWES has three constituting dimensions of work engagement as vigor, dedication, and absorption. We conducted the study using UWES-9 tool. Outcome measures were mean score for each dimension of work engagement (vigor, dedication, absorption) and total score compared with control score from test manual. Results: We found that the score for vigor and dedication is significantly lower than comparison group (P< 0.0001 for both). The score for absorption was significantly higher than comparison group (P< 0.0001). However, total score is not significantly different. Conclusion: The study shows that work engagement level is below average within the NHS employees. Vigor and dedication are significantly lower, these are characterised by energy, mental resilience, the willingness to invest one’s effort, and persistence as well as a sense of significance, enthusiasm, inspiration, pride, and challenge. The NHS employees are immersed in work. Urgent need to explore strategies to improve work engagement as it is vital for improving productivity, safety and patient experience PMID:25674571

  19. Thermal neutron radiative cross sections for Li,76,9Be,B,1110,C,1312, and N,1514

    NASA Astrophysics Data System (ADS)

    Firestone, R. B.; Revay, Zs.

    2016-05-01

    Total thermal radiative neutron cross sections have been measured on natural and enriched isotopic targets containing Li,76,9Be,B,1110,C,1312, and N,1514 with neutron beams from the Budapest Reactor. Complete neutron capture γ -ray decay schemes were measured for each isotope. Absolute transition probabilities have been determined by a least-squares fit of the transition intensities, corrected for internal conversion, to the (n ,γ ) decay schemes. The γ -ray cross sections were standardized using stoichiometric compounds containing both the isotope of interest and another element whose γ -ray cross sections are well known. Total cross sections σ0 were then determined for each isotope from the γ -ray cross sections and transition probabilities. For the 11B(n ,γ )12B reaction decay transition probabilities were determined for the γ rays from 12B (t1 /2=20.20 ms) β- decay.

  20. Validation of Cross Sections for Monte Carlo Simulation of the Photoelectric Effect

    NASA Astrophysics Data System (ADS)

    Han, Min Cheol; Kim, Han Sung; Pia, Maria Grazia; Basaglia, Tullio; Batic, Matej; Hoff, Gabriela; Kim, Chan Hyeong; Saracco, Paolo

    2016-04-01

    Several total and partial photoionization cross section calculations, based on both theoretical and empirical approaches, are quantitatively evaluated with statistical analyses using a large collection of experimental data retrieved from the literature to identify the state of the art for modeling the photoelectric effect in Monte Carlo particle transport. Some of the examined cross section models are available in general purpose Monte Carlo systems, while others have been implemented and subjected to validation tests for the first time to estimate whether they could improve the accuracy of particle transport codes. The validation process identifies Scofield's 1973 non-relativistic calculations, tabulated in the Evaluated Photon Data Library(EPDL), as the one best reproducing experimental measurements of total cross sections. Specialized total cross section models, some of which derive from more recent calculations, do not provide significant improvements. Scofield's non-relativistic calculations are not surpassed regarding the compatibility with experiment of K and L shell photoionization cross sections either, although in a few test cases Ebel's parameterization produces more accurate results close to absorption edges. Modifications to Biggs and Lighthill's parameterization implemented in Geant4 significantly reduce the accuracy of total cross sections at low energies with respect to its original formulation. The scarcity of suitable experimental data hinders a similar extensive analysis for the simulation of the photoelectron angular distribution, which is limited to a qualitative appraisal.

  1. Excitation cross sections for krypton by electrons in the 15-100-eV impact-energy range

    NASA Technical Reports Server (NTRS)

    Trajmar, S.; Srivastava, S. K.; Tanaka, H.; Nishimura, H.; Cartwright, D. C.

    1981-01-01

    Differential, integral, and momentum-transfer cross sections have been determined for the excitation of the 24 lowest electronic states of Kr (some of the transitions are unresolved). The inelastic-scattering cross sections were normalized to the absolute scale with the help of the elastic-scattering differential cross sections (DCS's) which in turn were normalized with respect to absolute He DCS's. The impact energies were 15, 20, 30, 50, and 100 eV and the DCS's were obtained over the range of 5-135 deg scattering angles. The error limits associated with the differential, integral, and momentum-transfer cross sections have been estimated at 25%, 38%, and 46%, respectively.

  2. Precision Cross Section Measurement for the ^241Am(γ,n) Reaction at HIγS

    NASA Astrophysics Data System (ADS)

    Tonchev, A.; Hutcheson, A.; Howell, C. R.; Kwan, E.; Rusev, G.; Tornow, W.; Hammond, S.; Karwowski, H. J.; Huibregtse, C.; Kelley, J. H.; Vieira, D. L.; Wilhelmy, J. B.; Stoyer, M. A.

    2008-10-01

    The photodisintegration cross section on radioactive ^241Am target has been measured for the first time using monoenergetic γ-ray beams from the HIγS facility. Induced activity from ^240Am produced via the (γ,n) reaction was measured by the activation technique using high resolution HPGe detectors. The (γ,n) cross section was determined both by measuring the absolute γ-flux and by comparison to the ^197Au(γ,n) cross section used as a standard. In the following, we report new data for the excitation function of the ^241Am(γ,n ) reaction from near threshold to 16 MeV incident γ-ray energy and we compare the data with statistical nuclear-model calculations performed with the GNASH, EMPIRE, and TALYS codes.

  3. First Measurement of the Muon Neutrino Charged Current Quasielastic Double Differential Cross Section

    SciTech Connect

    Aguilar-Arevalo, A.A.; Anderson, C.E.; Bazarko, A.O.; Brice, S.J.; Brown, B.C.; Bugel, L.; Cao, J.; Coney, L.; Conrad, J.M.; Cox, D.C.; Curioni, A.; /Yale U. /Columbia U.

    2010-02-01

    A high-statistics sample of charged-current muon neutrino scattering events collected with the MiniBooNE experiment is analyzed to extract the first measurement of the double differential cross section (d{sup 2}{sigma}/dT{sub {mu}}d cos {theta}{sub {mu}}) for charged-current quasielastic (CCQE) scattering on carbon. This result features minimal model dependence and provides the most complete information on this process to date. With the assumption of CCQE scattering, the absolute cross section as a function of neutrino energy ({sigma}[E{sub {nu}}]) and the single differential cross section (d{sigma}/dQ{sup 2}) are extracted to facilitate comparison with previous measurements. These quantities may be used to characterize an effective axial-vector form factor of the nucleon and to improve the modeling of low-energy neutrino interactions on nuclear targets. The results are relevant for experiments searching for neutrino oscillations.

  4. Vibrational-excitation cross sections of water molecules by electron impact

    NASA Technical Reports Server (NTRS)

    Shyn, T. W.; Cho, S. Y.; Cravens, T. E.

    1988-01-01

    A crossed-beam technique was used to measure absolute differential cross sections for the vibrational excitation of water-vapor molecules. The energy and angular range were from 2.2 to 20 eV and from 30 to 150 deg. Vibrational-excitation cross sections were determined for the bending (010) and stretching (100 and 001) modes of the electronic ground state. It is shown that the integral cross sections are generally larger than those of Seng and Linder (1976) by 10-20 percent for both the bending and stretching modes. It is noted that the results obtained are of interest in connection with the theoretical modeling of cometary ionospheres.

  5. First Measurement of Muon Neutrino Charged Current Quasielastic (CCQE) Double Differential Cross Section

    SciTech Connect

    Katori, Teppei; /MIT, LNS

    2009-09-01

    Using a high statistics sample of muon neutrino charged current quasielastic (CCQE) events, we report the first measurement of the double differential cross section (d{sup 2}{sigma}/dT{sub {mu}}d cos {theta}{sub {mu}}) for this process. The result features reduced model dependence and supplies the most complete information on neutrino CCQE scattering to date. Measurements of the absolute cross section as a function of neutrino energy ({sigma}[E{sub v}{sup QE,RFG}]) and the single differential cross section (d{sigma}/dQ{sub QE}{sup 2}) are also provided, largely to facilitate comparison with prior measurements. This data is of particular use for understanding the axial-vector form factor of the nucleon as well as improving the simulation of low energy neutrino interactions on nuclear targets, which is of particular relevance for experiments searching for neutrino oscillations.

  6. First measurement of the muon neutrino charged current quasielastic double differential cross section

    SciTech Connect

    Aguilar-Arevalo, A. A.; Anderson, C. E.; Curioni, A.; Fleming, B. T.; Linden, S. K.; Soderberg, M.; Spitz, J.; Bazarko, A. O.; Laird, E. M.; Meyers, P. D.; Patterson, R. B.; Shoemaker, F. C.; Tanaka, H. A.; Brice, S. J.; Brown, B. C.; Finley, D. A.; Ford, R.; Garcia, F. G.; Kasper, P.; Kobilarcik, T.

    2010-05-01

    A high-statistics sample of charged-current muon neutrino scattering events collected with the MiniBooNE experiment is analyzed to extract the first measurement of the double differential cross section ((d{sup 2{sigma}}/dT{sub {mu}d}cos{theta}{sub {mu}})) for charged-current quasielastic (CCQE) scattering on carbon. This result features minimal model dependence and provides the most complete information on this process to date. With the assumption of CCQE scattering, the absolute cross section as a function of neutrino energy ({sigma}[E{sub {nu}}]) and the single differential cross section ((d{sigma}/dQ{sup 2})) are extracted to facilitate comparison with previous measurements. These quantities may be used to characterize an effective axial-vector form factor of the nucleon and to improve the modeling of low-energy neutrino interactions on nuclear targets. The results are relevant for experiments searching for neutrino oscillations.

  7. Cross sections for elastic electron scattering by tetramethylsilane in the intermediate-energy range

    SciTech Connect

    Sugohara, R. T.; Lee, M.-T.; Iga, I.; Souza, G. L. C. de; Homem, M. G. P.

    2011-12-15

    Organosilicon compounds are of current interest due to the numerous applications of these species in industries. Some of these applications require the knowledge of electron collision cross sections, which are scarce for such compounds. In this work, we report absolute values of differential, integral, and momentum-transfer cross sections for elastic electron scattering by tetramethylsilane (TMS) measured in the 100-1000 eV energy range. The relative-flow technique is used to normalize our data. In addition, the independent-atom-model (IAM) and the additivity rule (AR), widely used to model electron collisions with light hydrocarbons, are also applied for e{sup -}-TMS interaction. The comparison of our measured results of cross sections and the calculated data shows good agreement, particularly near the higher-end of incident energies.

  8. Electron-impact ionization cross sections out of the ground and excited states of cesium

    SciTech Connect

    Lukomski, M.; Sutton, S.; Kedzierski, W.; Reddish, T. J.; Bartschat, K.; Bartlett, P. L.; Bray, I.; Stelbovics, A. T.; McConkey, J. W.

    2006-09-15

    An atom trapping technique for determining absolute, total ionization cross sections (TICS) out of an excited atom is presented. The unique feature of our method is in utilizing Doppler cooling of neutral atoms to determine ionization cross sections. This fluorescence-monitoring experiment, which is a variant of the 'trap loss' technique, has enabled us to obtain the experimental electron impact ionization cross sections out of the Cs state between 7 eV and 400 eV. CCC, RMPS, and Born theoretical results are also presented for both the ground and excited states of cesium and rubidium. In the low energy region (<11 eV) where best agreement between these excited state measurements and theory might be expected, a discrepancy of approximately a factor of five is observed. Above this energy there are significant contributions to the TICS from both autoionization and multiple ionization.

  9. Cross sections for electron scattering from furan molecules: Measurements and calculations

    SciTech Connect

    Szmytkowski, Czeslaw; Mozejko, Pawel; Ptasinska-Denga, Elzbieta; Sabisz, Agnieszka

    2010-09-15

    Electron-scattering cross sections have been determined for the furan (C{sub 4}H{sub 4}O) molecule, both experimentally and theoretically. An absolute total cross section (TCS) has been measured over energies from 0.6 to 400 eV using a linear electron-transmission method. The TCS energy function is dominated with a very broad enhancement, between 1.2 and 9 eV; on the low-energy side, some resonant structures are visible. Integral elastic (ECS) and ionization (ICS) cross sections have been also calculated up to 4 keV in the additivity rule approximation and the binary-encounter-Bethe approach, respectively. Their sum, ECS+ICS, is in a very good agreement with the measured TCS above 70 eV.

  10. Ab initio calculation of the cross sections for electron impact vibrational excitation of CO via the (2)Π shape resonance.

    PubMed

    Falcetta, Michael F; Fair, Mark C; Tharnish, Emily M; Williams, Lorna M; Hayes, Nathan J; Jordan, Kenneth D

    2016-03-14

    The stabilization method is used to calculate the complex potential energy curve of the (2)Π state of CO(-) as a function of bond length, with the refinement that separate potentials are determined for p-wave and d-wave attachment and detachment of the excess electron. Using the resulting complex potentials, absolute vibrational excitation cross sections are calculated as a function of electron energy and scattering angle. The calculated cross sections agree well with experiment.

  11. Studies of the dependence of the microwave radar cross section on ocean surface variables during the FASINEX experiment

    NASA Technical Reports Server (NTRS)

    Weissman, D. A.; Li, Fuk

    1988-01-01

    The ability of theoretical radar cross section (RCS) models to predict the absolute magnitude of the ocean radar cross section under a wide variety of sea and atmospheric conditions was studied using experimental data from the FASINEX Experiment. This consists of RCS data from a Ku-band scatterometer mounted on an aircraft (10 separate flights were conducted), a wide variety of atmospheric measurements (including stress) and sea conditions. Theoretical models are tested. Where discrepancies are observed, revisions are hypothesized and evaluated.

  12. Measurement of K Shell Photoelectric Cross Sections at a K Edge--A Laboratory Experiment

    ERIC Educational Resources Information Center

    Nayak, S. V.; Badiger, N. M.

    2007-01-01

    We describe in this paper a new method for measuring the K shell photoelectric cross sections of high-Z elemental targets at a K absorption edge. In this method the external bremsstrahlung (EB) photons produced in the Ni target foil by beta particles from a weak[superscript 90]Sr-[superscript 90]Y beta source are passed through an elemental target…

  13. Optical properties and cross-sections of biological aerosols

    NASA Astrophysics Data System (ADS)

    Thrush, E.; Brown, D. M.; Salciccioli, N.; Gomes, J.; Brown, A.; Siegrist, K.; Thomas, M. E.; Boggs, N. T.; Carter, C. C.

    2010-04-01

    There is an urgent need to develop standoff sensing of biological agents in aerosolized clouds. In support of the Joint Biological Standoff Detection System (JBSDS) program, lidar systems have been a dominant technology and have shown significant capability in field tests conducted in the Joint Ambient Breeze Tunnel (JABT) at Dugway Proving Ground (DPG). The release of biological agents in the open air is forbidden. Therefore, indirect methods must be developed to determine agent cross-sections in order to validate sensor against biological agents. A method has been developed that begins with laboratory measurements of thin films and liquid suspensions of biological material to obtain the complex index of refraction from the ultraviolet (UV) to the long wave infrared (LWIR). Using that result and the aerosols' particle size distribution as inputs to Mie calculations yields the backscatter and extinction cross-sections as a function of wavelength. Recent efforts to model field measurements from the UV to the IR have been successful. Measurements with aerodynamic and geometric particle sizers show evidence of particle clustering. Backscatter simulations of these aerosols show these clustered particles dominate the aerosol backscatter and depolarization signals. In addition, these large particles create spectral signatures in the backscatter signal due to material absorption. Spectral signatures from the UV to the IR have been observed in simulations of field releases. This method has been demonstrated for a variety of biological simulant materials such as Ovalbumin (OV), Erwinia (EH), Bacillus atrophaeus (BG) and male specific bacteriophage (MS2). These spectral signatures may offer new methods for biological discrimination for both stand-off sensing and point detection systems.

  14. Integral elastic, electronic-state, ionization, and total cross sections for electron scattering with furfural

    NASA Astrophysics Data System (ADS)

    Jones, D. B.; da Costa, R. F.; Varella, M. T. do N.; Bettega, M. H. F.; Lima, M. A. P.; Blanco, F.; García, G.; Brunger, M. J.

    2016-04-01

    We report absolute experimental integral cross sections (ICSs) for electron impact excitation of bands of electronic-states in furfural, for incident electron energies in the range 20-250 eV. Wherever possible, those results are compared to corresponding excitation cross sections in the structurally similar species furan, as previously reported by da Costa et al. [Phys. Rev. A 85, 062706 (2012)] and Regeta and Allan [Phys. Rev. A 91, 012707 (2015)]. Generally, very good agreement is found. In addition, ICSs calculated with our independent atom model (IAM) with screening corrected additivity rule (SCAR) formalism, extended to account for interference (I) terms that arise due to the multi-centre nature of the scattering problem, are also reported. The sum of those ICSs gives the IAM-SCAR+I total cross section for electron-furfural scattering. Where possible, those calculated IAM-SCAR+I ICS results are compared against corresponding results from the present measurements with an acceptable level of accord being obtained. Similarly, but only for the band I and band II excited electronic states, we also present results from our Schwinger multichannel method with pseudopotentials calculations. Those results are found to be in good qualitative accord with the present experimental ICSs. Finally, with a view to assembling a complete cross section data base for furfural, some binary-encounter-Bethe-level total ionization cross sections for this collision system are presented.

  15. Total photoionization cross sections of atomic oxygen from threshold to 44.3A

    NASA Technical Reports Server (NTRS)

    Angel, G. C.; Samson, James A. R.

    1987-01-01

    The relative cross section of atomic oxygen for the production of singly charged ions has been remeasured in more detail and extended to cover the wavelength range 44.3 to 910.5 A by the use of synchrotron radiation. In addition, the contribution of multiple ionization to the cross sections has been measured allowing total photoionization cross sections to be obtained below 250 A. The results have been made absolute by normalization to previously measured data. The use of synchrotron radiation has enabled measurements of the continuum cross section to be made between the numerous autoionizing resonances that occur near the ionization thresholds. This in turn has allowed a more critical comparison of the various theoretical estimates of the cross section to be made. The series of autoionizing resonances leading to the 4-P state of the oxygen ion have been observed for the first time in an ionization type experiment and their positions compared with both theory and previous photographic recordings.

  16. Influence of screening length modification on the scattering cross section in LEIS

    NASA Astrophysics Data System (ADS)

    Primetzhofer, D.; Markin, S. N.; Efrosinin, D. V.; Steinbauer, E.; Andrzejewski, R.; Bauer, P.

    2011-06-01

    Scattering cross sections for He + ions in the energy range of 100 eV to 100 keV and for Al, Cu and Au target atoms were calculated. Employing the Thomas-Fermi-Molière model the potential strength was tuned by variation of the screening length. The resulting change in scattering cross section was analyzed and the absolute value is compared to cross sections obtained from potentials commonly employed in the medium-energy ion scattering (MEIS) regime. A large influence on the scattering cross section is observed for targets with large atomic number in the very low energy range. For instance, the scattering cross section for 100 eV He +-ions scattered from Au by 129° changes by a factor of 2.5 between different potential strengths claimed in the literature to be suitable for low-energy ion scattering (LEIS) energies. An experiment to determine electronic energy loss of very slow ions in metals is presented. It shows how uncertainties in the scattering potential strength can lead to systematically wrong results, although perfect agreement between experimental data and simulations is found. The impact of these results on quantitative surface structure and composition analysis is discussed.

  17. Theoretical Fully Differential Cross Sections for Four-Body Processes

    NASA Astrophysics Data System (ADS)

    Harris, A. L.; Peacher, J. L.; Schulz, M.; Madison, D. H.

    2008-04-01

    Atomic collisions present a valuable opportunity to study the few body problem. Advances on the theoretical side now allow for an essentially exact numerical calculation of one of the simplest the few-body problems - the three-body problem. However, study of the four-body problem is still in its infancy, and the agreement between experiment and theory for kinematically complete experiments is far from satisfactory. The simplest four-body problem is a charged particle collision with helium in which both atomic electrons change state. Two theoretical models will be discussed for several possible outcomes of this type of collision. The first Born approximation (FBA) treats the projectile as a plane wave, and ignores the post collision Coulomb interaction between the two final state continuum electrons. The more sophisticated four-body distorted wave (4DW) model treats all continuum particles as distorted waves and explicitly includes the post collision Coulomb interaction between the two outgoing electrons. Fully differential cross sections calculated using the FBA and 4DW models will be compared to absolute experimental results, as well as other theories.

  18. High E{sub T} jet cross sections at CDF

    SciTech Connect

    Flaugher, B.; CDF Collaboration

    1996-08-01

    The inclusive jet cross section for {ital p}{ital {anti p}} collisions at {radical}s = 1.8 TeV as measured by the CDF collaboration will be presented. Preliminary CDF measurements of the {Sigma} E{sub T} cross section at {radical}s = 1.8 TeV and the central inclusive jet cross section at {radical}s = 0.630 TeV will also be shown.

  19. Measured microwave scattering cross sections of three meteorite specimens

    NASA Technical Reports Server (NTRS)

    Hughes, W. E.

    1972-01-01

    Three meteorite specimens were used in a microwave scattering experiment to determine the scattering cross sections of stony meteorites and iron meteorites in the frequency range from 10 to 14 GHz. The results indicate that the stony meteorites have a microwave scattering cross section that is 30 to 50 percent of their projected optical cross section. Measurements of the iron meteorite scattering were inconclusive because of specimen surface irregularities.

  20. Projectile and Lab Frame Differential Cross Sections for Electromagnetic Dissociation

    NASA Technical Reports Server (NTRS)

    Norbury, John W.; Adamczyk, Anne; Dick, Frank

    2008-01-01

    Differential cross sections for electromagnetic dissociation in nuclear collisions are calculated for the first time. In order to be useful for three - dimensional transport codes, these cross sections have been calculated in both the projectile and lab frames. The formulas for these cross sections are such that they can be immediately used in space radiation transport codes. Only a limited amount of data exists, but the comparison between theory and experiment is good.

  1. Analytical formulation of the quantum electromagnetic cross section

    NASA Astrophysics Data System (ADS)

    Brandsema, Matthew J.; Narayanan, Ram M.; Lanzagorta, Marco

    2016-05-01

    It has been found that the quantum radar cross section (QRCS) equation can be written in terms of the Fourier transform of the surface atom distribution of the object. This paper uses this form to provide an analytical formulation of the quantum radar cross section by deriving closed form expressions for various geometries. These expressions are compared to the classical radar cross section (RCS) expressions and the quantum advantages are discerned from the differences in the equations. Multiphoton illumination is also briefly discussed.

  2. Photoionization cross sections of E levels in electron-irradiated n-type GaAs

    SciTech Connect

    Budnitskii, D.L.; Kirov, M.A.; Popova, E.A.

    1986-11-01

    The spectral change of the photoionization cross sections of E/sub 1/-E/sub 2/ levels and the low-energy part of the photoionization cross sections of E/sub 4/ and E/sub 5/ levels are determined. It has been shown that radiation defects with which these levels are associated are characterized be a strong lattice relaxation of magnitude approx. = 0.5 eV. The red absorption edge for these levels in p-type GaAs has been found to lie at photon energies greater than E/sub g/ (except, possibly, level E/sub 5/)

  3. Absolute I(asterisk) quantum yields for the ICN A state by diode laser gain-vs-absorption spectroscopy

    NASA Technical Reports Server (NTRS)

    Hess, Wayne P.; Leone, Stephen R.

    1987-01-01

    Absolute I(asterisk) quantum yields have been measured as a function of wavelength for room temperature photodissociation of the ICN A state continuum. The yields are obtained by the technique of time-resolved diode laser gain-vs-absorption spectroscopy. Quantum yields are evaluated at seven wavelengths from 248 to 284 nm. The yield at 266 nm is 66.0 + or - 2 percent and it falls off to 53.4 + or - 2 percent and 44.0 + or - 4 percent at 284 and 248 nm, respectively. The latter values are significantly higher than those obtained by previous workers using infrared fluorescence. Estimates of I(asterisk) quantum yields obtained from analysis of CN photofragment rotational distributions, as discussed by other workers, are in good agreement with the I(asterisk) yields reported here. The results are considered in conjunction with recent theoretical and experimental work on the CN rotational distributions and with previous I(asterisk) quantum yield results.

  4. Flow in tubes of non-circular cross-sections

    NASA Astrophysics Data System (ADS)

    Quadir, Raushan Ara

    Laminar, viscous, incompressible flow in tubes of noncircular cross sections is investigated. The specific aims of the investigation are (1) to look at the problems of both developing flow and fully developed flow, (2) to consider noncircular cross sections in a more systematic manner than has been done in the past, and (3) to develop a relatively simple finite element technique for producing accurate numerical solutions of flow in tubes of fairly arbitrary cross sections. Fully developed flow in tubes is governed by a Poisson type equation for the mainstream velocity. Both analytical and numerical solutions are considered. The cross sections studied include elliptic and rectangular cross sections of different aspect ratios, some triangular cross sections, and a series of crescent-shaped cross sections. The physical characteristics of the flow are examined in a systematic manner in order to determine how these characteristics are affected by certain geometrical features of the cross section. Solutions fall into three basic categories depending on the shape of the cross section. In the first category, which includes circular and elliptic cross sections, solutions are possible in closed form. In the second, including rectangular and some triangular cross sections, solutions are in the form of infinite series. In the third, including cross sections of more complicated or irregular shapes, only numerical solutions are possible. Results of calculations of velocity profiles, flow rate, pumping power, and friction factor are presented in a way which can be useful for engineering applications. In numerical studies of both developing and fully developed flow finite element techniques are used. Results are obtained for tubes of rectangular and elliptic cross sections of different aspect ratios, for tubes of crescent-shaped cross sections, and a tube whose cross section is an oval of Cassini. For fully developed flow, results are compared with the corresponding exact

  5. Flow in Tubes of Non-Circular Cross-Sections

    NASA Astrophysics Data System (ADS)

    Quadir, Raushan Ara

    In this thesis steady, laminar, viscous, incompressible flow in tubes of non-circular cross sections is investigated. The specific aims of the investigation are (a) to look at the problems of both developing flow and fully developed flow, (b) to consider non-circular cross sections in a more systematic manner than has been done in the past, and (c) to develop a relatively simple finite element technique for producing accurate numerical solutions of flow in tubes of fairly arbitrary cross sections. Fully developed flow in tubes is governed by a Poisson type equation for the mainstream velocity. Both analytical and numerical solutions are considered. The cross sections studied include elliptic and rectangular cross sections of different aspect ratios, some triangular cross sections, and a series of crescent-shaped cross sections. The physical characteristics of the flow are examined in a systematic manner in order to determine how these characteristics are affected by certain geometrical features of the cross section. Solutions fall into three basic categories depending on the shape of the cross section. In the first category, which includes circular and elliptic cross sections, solutions are possible in closed form. In the second, including rectangular and some triangular cross sections, solutions are in the form of infinite series. In the third, including cross sections of more complicated or irregular shapes, only numerical solutions are possible. Results of calculations of velocity profiles, flow rate, pumping power, and friction factor are presented in a way which can be useful for engineering applications. In numerical studies of both developing and fully developed flow finite element techniques are used. Results are obtained for tubes of rectangular and elliptic cross sections of different aspect ratios, for tubes of crescent -shaped cross sections and a tube whose cross section is an oval of Cassini. For fully developed flow, results are compared with the

  6. Documentation of Uncertainties in Experimental Cross Sections for EXFOR

    SciTech Connect

    Otuka, N.; Smith, D.L.

    2014-06-15

    Documentation of uncertainties and covariances in experimental nuclear reaction cross sections has been assessed. Following consideration of the importance of covariances for nuclear data in various nuclear applications, and presentation of a simple numerical example to demonstrate this point, the minimum basic concepts (mean, covariance, standard derivation, partial uncertainties, micro- and macro-correlation coefficients) are introduced. A deterministic approach to propagating the covariances in primary measured parameters (e.g., counts) to the derived cross sections is discussed, using a neutron-induced activation cross section measurement as an example. Finally, various approaches to documentation (publication, compilation) of experimental cross sections to facilitate their use in future evaluations are mentioned.

  7. Neutron-capture Cross Sections from Indirect Measurements

    SciTech Connect

    Escher, J E; Burke, J T; Dietrich, F S; Ressler, J J; Scielzo, N D; Thompson, I J

    2011-10-18

    Cross sections for compound-nuclear reactions play an important role in models of astrophysical environments and simulations of the nuclear fuel cycle. Providing reliable cross section data remains a formidable task, and direct measurements have to be complemented by theoretical predictions and indirect methods. The surrogate nuclear reactions method provides an indirect approach for determining cross sections for reactions on unstable isotopes, which are difficult or impossible to measure otherwise. Current implementations of the method provide useful cross sections for (n,f) reactions, but need to be improved upon for applications to capture reactions.

  8. Thermal Neutron Capture Cross Section of 22Ne

    NASA Astrophysics Data System (ADS)

    Belgya, T.; Uberseder, E.; Petrich, D.; Käppeler, F.

    2009-01-01

    The radiative thermal neutron capture cross section of the astrophysically important 22Ne nucleus has been measured at the guided cold neutron beam of the Budapest Research Reactor. High-pressure gas-bottles filled with mixtures of enriched 22Ne and CH4 were used. The cross section was determined by means of the comparator method, and an improved decay-scheme obtained in this work. The new value for the thermal neutron cross section is 52.7±0.7 mb, 18% larger than the accepted value. The influence of the new cross section on the astrophysical reaction rate is under investigation.

  9. Converged cross-section results for double photoionization of helium atoms in hyperspherical partial wave theory at 6 eV above threshold

    SciTech Connect

    Das, J.N.; Paul, S.; Chakrabarti, K.

    2004-04-01

    Here we report a set of converged cross-section results for double photoionization of helium atoms obtained in the hyperspherical partial wave theory for equal energy sharing kinematics at 6 eV energy above threshold. The calculated cross section results are generally in excellent agreement with the absolute measured results of Doerner et al. [Phys. Rev. 57, 1074 (1998)].

  10. Positron interactions with water-total elastic, total inelastic, and elastic differential cross section measurements.

    PubMed

    Tattersall, Wade; Chiari, Luca; Machacek, J R; Anderson, Emma; White, Ron D; Brunger, M J; Buckman, Stephen J; Garcia, Gustavo; Blanco, Francisco; Sullivan, James P

    2014-01-28

    Utilising a high-resolution, trap-based positron beam, we have measured both elastic and inelastic scattering of positrons from water vapour. The measurements comprise differential elastic, total elastic, and total inelastic (not including positronium formation) absolute cross sections. The energy range investigated is from 1 eV to 60 eV. Comparison with theory is made with both R-Matrix and distorted wave calculations, and with our own application of the Independent Atom Model for positron interactions.

  11. Research on temperature measurement technology for graphite-cone-absorption-cavity absolute calorimeter

    NASA Astrophysics Data System (ADS)

    Wei, Ji Feng; Lu, Fei; Sun, Li Qun; Zhang, Kai; Hu, Xiao Yang; Zhou, Shan; Xu, De

    2015-02-01

    The nonlinear effect of materials and sensors in high-energy laser calorimeters is especially obvious—due to the steep temperature gradients of their absorbers. Significant measurement errors occur when traditional integral temperature sensors and methods are utilized. In an effort to remedy this, a method is proposed in this paper in which an absorption cavity is divided into many parts and multiple discrete thermocouple sensors are used to measure the temperature rise of the absorbers. The temperature distribution in the absorbers is theoretically analyzed, numerically simulated, and verified through experimentation. Energy measurement results are compared according to the temperature distribution for different layouts of thermocouples. A high-accuracy calorimeter is developed by setting and optimizing thermocouple layout, as well as correcting various elements such as the specific heat of graphite and responsivity of thermocouples. The calorimeter employing this measurement method is calibrated against a standard energy meter, resulting in correction coefficient of 1.027 and relative standard deviation of the correction coefficient of only 0.8%. Theoretical analysis, numerical simulation, and experimental verification all prove that the proposed method successfully improves measurement accuracy.

  12. Research on temperature measurement technology for graphite-cone-absorption-cavity absolute calorimeter.

    PubMed

    Wei, Ji Feng; Lu, Fei; Sun, Li Qun; Zhang, Kai; Hu, Xiao Yang; Zhou, Shan; Xu, De

    2015-02-01

    The nonlinear effect of materials and sensors in high-energy laser calorimeters is especially obvious-due to the steep temperature gradients of their absorbers. Significant measurement errors occur when traditional integral temperature sensors and methods are utilized. In an effort to remedy this, a method is proposed in this paper in which an absorption cavity is divided into many parts and multiple discrete thermocouple sensors are used to measure the temperature rise of the absorbers. The temperature distribution in the absorbers is theoretically analyzed, numerically simulated, and verified through experimentation. Energy measurement results are compared according to the temperature distribution for different layouts of thermocouples. A high-accuracy calorimeter is developed by setting and optimizing thermocouple layout, as well as correcting various elements such as the specific heat of graphite and responsivity of thermocouples. The calorimeter employing this measurement method is calibrated against a standard energy meter, resulting in correction coefficient of 1.027 and relative standard deviation of the correction coefficient of only 0.8%. Theoretical analysis, numerical simulation, and experimental verification all prove that the proposed method successfully improves measurement accuracy. PMID:25725875

  13. Neutron Fission of 235,237,239U and 241,243Pu: Cross Sections, Integral Cross Sections and Cross Sections on Excited States

    SciTech Connect

    Younes, W; Britt, H C

    2003-07-10

    In a recent paper submitted to Phys. Rev. C they have presented estimates for (n,f) cross sections on a series of Thorium, Uranium and Plutonium isotopes over the range E{sub n} = 0.1-2.5 MeV. The (n,f) cross sections for many of these isotopes are difficult or impossible to measure in the laboratory. The cross sections were obtained from previous (t,pf) reaction data invoking a model which takes into account the differences between (t,pf) and (n,f) reaction processes, and which includes improved estimates for the neutron compound formation process. The purpose of this note is: (1) to compare the estimated cross sections to current data files in both ENDF and ENDL databases; (2) to estimate ratios of cross sections relatively to {sup 235}U integrated over the ''tamped flattop'' critical assembly spectrum that was used in the earlier {sup 237}U report; and (3) to show the effect on the integral cross sections when the neutron capturing state is an excited rotational state or an isomer. The isomer and excited state results are shown for {sup 235}U and {sup 237}U.

  14. Cross Sections for Inner-Shell Ionization by Electron Impact

    SciTech Connect

    Llovet, Xavier; Powell, Cedric J.; Salvat, Francesc; Jablonski, Aleksander

    2014-03-15

    An analysis is presented of measured and calculated cross sections for inner-shell ionization by electron impact. We describe the essentials of classical and semiclassical models and of quantum approximations for computing ionization cross sections. The emphasis is on the recent formulation of the distorted-wave Born approximation by Bote and Salvat [Phys. Rev. A 77, 042701 (2008)] that has been used to generate an extensive database of cross sections for the ionization of the K shell and the L and M subshells of all elements from hydrogen to einsteinium (Z = 1 to Z = 99) by electrons and positrons with kinetic energies up to 1 GeV. We describe a systematic method for evaluating cross sections for emission of x rays and Auger electrons based on atomic transition probabilities from the Evaluated Atomic Data Library of Perkins et al. [Lawrence Livermore National Laboratory, UCRL-ID-50400, 1991]. We made an extensive comparison of measured K-shell, L-subshell, and M-subshell ionization cross sections and of Lα x-ray production cross sections with the corresponding calculated cross sections. We identified elements for which there were at least three (for K shells) or two (for L and M subshells) mutually consistent sets of cross-section measurements and for which the cross sections varied with energy as expected by theory. The overall average root-mean-square deviation between the measured and calculated cross sections was 10.9% and the overall average deviation was −2.5%. This degree of agreement between measured and calculated ionization and x-ray production cross sections was considered to be very satisfactory given the difficulties of these measurements.

  15. Absolute Rovibrational Intensities of C-12O2-16 Absorption Bands in the 3090-3850/ CM Spectral Region

    NASA Technical Reports Server (NTRS)

    Devi, V. Malathy; Benner, D. Chris; Rinsland, Curtis P.; Smith, Mary Ann H.

    1998-01-01

    A multispectrum nonlinear least-squares fitting technique has been used to determine the absolute intensities for approximately 1500 spectral lines in 36 vibration - rotation bands Of C-12O2-16 between 3090 and 3850/ cm. A total of six absorption spectra of a high- purity (99.995% minimum) natural sample of carbon dioxide were used in the analysis. The spectral data (0.01/cm resolution) were recorded at room temperature and low pressure (1 to 10 Torr) using the McMath-Pierce Fourier transform spectrometer of the National Solar Observatory (NSO) on Kitt Peak. The absorption path lengths for these spectra varied between 24.86 and 385.76 m. The first experimental determination of the intensity of the theoretically predicted 2(nu)(sub 2, sup 2) + nu(sub 3) "forbidden" band has been made. The measured line intensities obtained for each band have been analyzed to determine the vibrational band intensity, S(sub nu), in /cm/( molecule/sq cm) at 296 K, square of the rotationless transition dipole moment |R|(exp 2) in Debye, as well as the nonrigid rotor coefficients. The results are compared to the values listed in the 1996 HITRAN database which are obtained using the direct numerical diagonalization (DND) technique as well as to other published values where available.

  16. Terahertz calorimetry: an absolute power meter for terahertz radiation and the absorptivity of the Herschel Space Observatory telescope mirror coating

    NASA Astrophysics Data System (ADS)

    Klaassen, Tjeerd O.; Hovenier, J. Niels; Fischer, Jacqueline; Jakob, Gerd; Poglitsch, Albrecht; Sternberg, Oren

    2004-04-01

    A new calorimetric absolute power meter has been developed for THz radiation. This broad band THz power meter measures average power at ambient temperature and pressure, does not use a window, and is insensitive to polarization and time structure of THz radiation. The operation of the power meter is based on the calorimetric method: in order to determine the power of a beam of THz radiation, the beam is used to illuminate a highly absorbing surface with known BRDF characteristics until a stable temperature is reached. The power in the incident beam can then be determined by measuring the electric power needed to cause the sample temperature rise. The new power meter was used with laser calorimetry to measure the absorptivity, and thus the emissivity, of aluminum-coated silicon carbide mirror samples produced during the coating qualification run of the Herschel Space Observatory telescope to be launched by the European Space Agency in 2007. The samples were measured at 77 Kelvin to simulate the operating temperature of the telescope in its planned orbit around the second Lagrangian point, L2, of the Earth-Sun system. The absorptivity of both clean and dust-contaminated samples was measured at 70, 118, 184 and 496 mm and found to be in the range 0.2 - 0.8%.

  17. Influence of cross sectional geometry on surface plasmon polariton propagation in gold nanowires.

    PubMed

    Nauert, Scott; Paul, Aniruddha; Zhen, Yu-Rong; Solis, David; Vigderman, Leonid; Chang, Wei-Shun; Zubarev, Eugene R; Nordlander, Peter; Link, Stephan

    2014-01-28

    We investigated the effects of cross sectional geometry on surface plasmon polariton propagation in gold nanowires (NWs) using bleach-imaged plasmon propagation and electromagnetic simulations. Chemically synthesized NWs have pentagonally twinned crystal structures, but recent advances in synthesis have made it possible to amplify this pentagonal shape to yield NWs with a five-pointed-star cross section and sharp end tips. We found experimentally that NWs with a five-pointed-star cross section, referred to as SNWs, had a shorter propagation length for surface plasmon polaritons at 785 nm, but a higher effective incoupling efficiency compared to smooth NWs with a pentagonal cross section, labeled as PNWs. Electromagnetic simulations revealed that the electric fields were localized at the sharp ridges of the SNWs, leading to higher absorptive losses and hence shorter propagation lengths compared to PNWs. On the other hand, scattering losses were found to be relatively uncorrelated with cross sectional geometry, but were strongly dependent on the plasmon mode excited. Our results provide insight into the shape-dependent waveguiding properties of chemically synthesized metal NWs and the mode-dependent loss mechanisms that govern surface plasmon polariton propagation. PMID:24308802

  18. Electron induced inelastic and ionization cross section for plasma modeling

    NASA Astrophysics Data System (ADS)

    Verma, Pankaj; Mahato, Dibyendu; Kaur, Jaspreet; Antony, Bobby

    2016-09-01

    The present paper reports electron impact total inelastic and ionization cross section for silicon, germanium, and tin tetrahalides at energies varying from ionization threshold of the target to 5000 eV. These cross section data over a wide energy domain are very essential to understand the physico-chemical processes involved in various environments such as plasma modeling, semiconductor etching, atmospheric sciences, biological sciences, and radiation physics. However, the cross section data on the above mentioned molecules are scarce. In the present article, we report the computation of total inelastic cross section using spherical complex optical potential formalism and the estimation of ionization cross section through a semi-empirical method. The present ionization cross section result obtained for SiCl4 shows excellent agreement with previous measurements, while other molecules have not yet been investigated experimentally. Present results show more consistent behaviour than previous theoretical estimates. Besides cross sections, we have also studied the correlation of maximum ionization cross section with the square root of the ratio of polarizability to ionization potential for the molecules with known polarizabilities. A linear relation is observed between these quantities. This correlation is used to obtain approximate polarizability volumes for SiBr4, SiI4, GeCl4, GeBr4, and GeI4 molecules.

  19. Electron impact on atmospheric gases. I - Updated cross sections

    NASA Technical Reports Server (NTRS)

    Jackman, C. H.; Garvey, R. H.; Green, A. E. S.

    1977-01-01

    The analytic characterizations of electron impact cross sections for important atmospheric gases (namely, O2, N2, O, CO, CO2, and He) are updated. With these cross sections it is simple to communicate massive quantities of experimental and theoretical results. In addition, these forms are convenient for applications in energy degradation calculations, including a new approach described in a companion paper.

  20. Cross Sections for Electron Collisions with Carbon Monoxide

    SciTech Connect

    Itikawa, Yukikazu

    2015-03-15

    Cross section data are collected and reviewed for electron collisions with carbon monoxide. Collision processes included are total scattering, elastic scattering, momentum transfer, excitations of rotational, vibrational and electronic states, ionization, and dissociation. For each process, recommended values of the cross sections are presented, when possible. The literature has been surveyed through to the end of 2013.

  1. Learning of Cross-Sectional Anatomy Using Clay Models

    ERIC Educational Resources Information Center

    Oh, Chang-Seok; Kim, Ji-Young; Choe, Yeon Hyeon

    2009-01-01

    We incorporated clay modeling into gross anatomy and neuro-anatomy courses to help students understand cross-sectional anatomy. By making clay models, cutting them and comparing cut surfaces to CT and MR images, students learned how cross-sectional two-dimensional images were created from three-dimensional structure of human organs. Most students…

  2. Cross sections for electron collisions with nitric oxide

    NASA Astrophysics Data System (ADS)

    Itikawa, Yukikazu

    2016-09-01

    Cross section data are reviewed for electron collisions with nitric oxide. Collision processes considered are total scattering, elastic scattering, momentum transfer, excitations of rotational, vibrational, and electronic states, ionization, and dissociative electron attachment. After a survey of the literature (up to the end of 2015), recommended values of the cross section are determined, as far as possible.

  3. Benchmark Calculations of Electron-Impact Differential Cross Sections

    SciTech Connect

    Bray, I.; Bostock, C. J.; Fursa, D. V.; Hines, C. W.; Kadyrov, A. S.; Stelbovics, A. T.

    2011-05-11

    The calculation of electron-atom excitation and ionization cross section is considered in both the non-relativistic and relativistic scattering theory. We consider electron collisions with H, He, Cs, and Hg. Differential cross sections for elastic scattering and ionization are presented.

  4. Analysis of cross sections using various nuclear potential

    SciTech Connect

    Aziz, Azni Abdul; Kassim, Hasan Abu; Yusof, Norhasliza; Muhammad Zamrun, F.

    2014-05-02

    The relevant astrophysical reaction rates which are derived from the reaction cross sections are necessary input to the reaction network. In this work, we analyse several theoretical models of the nuclear potential which give better prediction of the cross sections for some selected reactions.

  5. Measurement of the Drell--Yan differential cross section with the CMS detector at the LHC

    NASA Astrophysics Data System (ADS)

    Svyatkovskiy, Alexey

    This thesis describes precision measurements of electroweak interactions in a new energy regime and the application of these measurements to improve our understanding of the structure of the proton. The results are based on proton-proton collision data at √s = 7 and 8TeV recorded with the Compact Muon Solenoid detector at the CERN Large Hadron Collider during the first years of operation. Measurements of the differential Drell-Yan cross section in the dimuon and dielectron channels covering the dilepton mass range of 15 to 2000GeV and absolute dilepton rapidity from 0 to 2.4 are presented. The Drell-Yan cross section in proton-proton collisions depends on empirical quantities known as parton distribution functions (PDFs) which parameterize the structure of the proton. In addition to the differential cross sections, the measurements of ratios of the normalized differential cross sections (double ratios) at √s = 7 and 8TeV are performed in order to provide further constraints for PDFs, substantially reducing theoretical systematic uncertainties due to correlations. These measurements are compared to predictions of perturbative QCD at the next-to-next-to-leading order computed with various sets of PDFs. The measured differential cross section and double ratio in bins of absolute rapidity are sufficiently precise to constrain the proton parton distribution functions. The inclusion of Drell-Yan data in PDF fits provides substantial constraints for the strange quark and the light sea quark distribution functions in a region of phase space which has not been accessible at hadron colliders in the past.

  6. Thermal neutron capture cross sections for 16,171,18O and 2H

    NASA Astrophysics Data System (ADS)

    Firestone, R. B.; Revay, Zs.

    2016-04-01

    Thermal neutron capture γ -ray spectra for 16,17,18O and 2H have been measured with guided cold neutron beams from the Forschungs-Neutronenquelle Heinz Maier-Leibnitz (FRM II) reactor and the Budapest Research Reactor (BRR) on natural and O,1817 enriched D2O targets. Complete neutron capture γ -ray decay schemes for the 16,17,18O(n ,γ ) reactions were measured. Absolute transition probabilities were determined for each reaction by a least-squares fit of the γ -ray intensities to the decay schemes after accounting for the contribution from internal conversion. The transition probability for the 870.76-keV γ ray from 16O(n ,γ ) was measured as Pγ(871 )=96.6 ±0.5 % and the thermal neutron cross section for this γ ray was determined as 0.164 ±0.003 mb by internal standardization with multiple targets containing oxygen and stoichiometric quantities of hydrogen, nitrogen, and carbon whose γ -ray cross sections were previously standardized. The γ -ray cross sections for the O,1817(n ,γ ) and 2H(n ,γ ) reactions were then determined relative to the 870.76-keV γ -ray cross section after accounting for the isotopic abundances in the targets. We determined the following total radiative thermal neutron cross sections for each isotope from the γ -ray cross sections and transition probabilities; σ0(16O )=0.170 ±0.003 mb; σ0(17O )=0.67 ±0.07 mb; σ0(18O )=0.141 ±0.006 mb; and σ0(2H )=0.489 ±0.006 mb.

  7. Fission cross section measurements of actinides at LANSCE

    SciTech Connect

    Tovesson, Fredrik; Laptev, Alexander B; Hill, Tony S

    2010-01-01

    Fission cross sections of a range of actinides have been measured at the Los Alamos Neutron Science Center (LANSCE) in support of nuclear energy applications. By combining measurement at two LANSCE facilities, Lujan Center and the Weapons Neutron Research center (WNR), differential cross sections can be measured from sub-thermal energies up to 200 MeV. Incident neutron energies are determined using the time-of-flight method, and parallel-plate ionization chambers are used to measure fission cross sections relative to the {sup 235}U standard. Recent measurements include the {sup 233,238}U, {sup 239,242}Pu and {sup 243}Am neutron-induced fission cross sections. In this paper preliminary results for cross section data of {sup 243}Am and {sup 233}U will be presented.

  8. UV absorption spectrum of the C2 Criegee intermediate CH3CHOO.

    PubMed

    Smith, Mica C; Ting, Wei-Lun; Chang, Chun-Hung; Takahashi, Kaito; Boering, Kristie A; Lin, Jim Jr-Min

    2014-08-21

    The UV spectrum of CH3CHOO was measured by transient absorption in a flow cell at 295 K. The absolute absorption cross sections of CH3CHOO were measured by laser depletion in a molecular beam to be (1.06 ± 0.09) × 10(-17) cm(2) molecule(-1) at 308 nm and (9.7 ± 0.6) × 10(-18) cm(2) molecule(-1) at 352 nm. After scaling the UV spectrum of CH3CHOO to the absolute cross section at 308 nm, the peak UV cross section is (1.27 ± 0.11) × 10(-17) cm(2) molecule(-1) at 328 nm. Compared to the simplest Criegee intermediate CH2OO, the UV absorption band of CH3CHOO is similar in intensity but blue shifted by 14 nm, resulting in a 20% slower photolysis rate estimated for CH3CHOO in the atmosphere.

  9. Precision measurement of the 238Pu(n,γ) cross section

    NASA Astrophysics Data System (ADS)

    Chyzh, A.; Wu, C. Y.; Kwan, E.; Henderson, R. A.; Gostic, J. M.; Bredeweg, T. A.; Couture, A.; Haight, R. C.; Lee, H. Y.; O'Donnell, J. M.; Ullmann, J. L.

    2013-10-01

    The neutron-capture cross section for 238Pu was measured by using the detector for advanced neutron-capture experiments (DANCE) array, which is a highly segmented and highly efficient 4π γ-ray calorimeter. The neutron-capture events were recognized by the total γ-ray energy deposited in DANCE, which is equal to the reaction Q value plus the incident neutron energy. The absolute neutron-capture cross section was derived as a function of incident neutron energy from thermal to about 30 keV. The measured cross section for incident neutron energy below 18 eV was performed for the first time by using the direct method and does not support the most recently adopted changes in endf/b-vii.1 where the neutron-capture cross section was lowered by as much as a factor of ˜3 in the neighborhood of 0.3 eV from those evaluated in endf/b-vii.0.

  10. Scaled plane-wave Born cross sections for atoms and molecules

    NASA Astrophysics Data System (ADS)

    Tanaka, H.; Brunger, M. J.; Campbell, L.; Kato, H.; Hoshino, M.; Rau, A. R. P.

    2016-04-01

    Integral cross sections for optically allowed electronic-state excitations of atoms and molecules by electron impact, by applying scaled plane-wave Born models, are reviewed. Over 40 years ago, Inokuti presented an influential review of charged-particle scattering, based on the theory pioneered by Bethe forty years earlier, which emphasized the importance of reliable cross-section data from low eV energies to high keV energies that are needed in many areas of radiation science with applications to astronomy, plasmas, and medicine. Yet, with a couple of possible exceptions, most computational methods in electron-atom scattering do not, in general, overlap each other's validity range in the region from threshold up to 300 eV and, in particular, in the intermediate region from 30 to 300 eV. This is even more so for electron-molecule scattering. In fact this entire energy range is of great importance and, to bridge the gap between the two regions of low and high energy, scaled plane-wave Born models were developed to provide reliable, comprehensive, and absolute integral cross sections, first for ionization by Kim and Rudd and then extended to optically allowed electronic-state excitation by Kim. These and other scaling models in a broad, general application to electron scattering from atoms and molecules, their theoretical basis, and their results for cross sections along with comparison to experimental measurements are reviewed. Where possible, these data are also compared to results from other computational approaches.

  11. Cross Section Sensitivity and Propagated Errors in HZE Exposures

    NASA Technical Reports Server (NTRS)

    Heinbockel, John H.; Wilson, John W.; Blatnig, Steve R.; Qualls, Garry D.; Badavi, Francis F.; Cucinotta, Francis A.

    2005-01-01

    It has long been recognized that galactic cosmic rays are of such high energy that they tend to pass through available shielding materials resulting in exposure of astronauts and equipment within space vehicles and habitats. Any protection provided by shielding materials result not so much from stopping such particles but by changing their physical character in interaction with shielding material nuclei forming, hopefully, less dangerous species. Clearly, the fidelity of the nuclear cross-sections is essential to correct specification of shield design and sensitivity to cross-section error is important in guiding experimental validation of cross-section models and database. We examine the Boltzmann transport equation which is used to calculate dose equivalent during solar minimum, with units (cSv/yr), associated with various depths of shielding materials. The dose equivalent is a weighted sum of contributions from neutrons, protons, light ions, medium ions and heavy ions. We investigate the sensitivity of dose equivalent calculations due to errors in nuclear fragmentation cross-sections. We do this error analysis for all possible projectile-fragment combinations (14,365 such combinations) to estimate the sensitivity of the shielding calculations to errors in the nuclear fragmentation cross-sections. Numerical differentiation with respect to the cross-sections will be evaluated in a broad class of materials including polyethylene, aluminum and copper. We will identify the most important cross-sections for further experimental study and evaluate their impact on propagated errors in shielding estimates.

  12. Modeling elastic momentum transfer cross-sections from mobility data

    NASA Astrophysics Data System (ADS)

    Nikitović, Ž. D.; Stojanović, V. D.; Raspopović, Z. M.

    2016-04-01

    In this letter we present a new method to simply obtain the elastic momentum transfer cross-section which predicts a maximum of reduced mobility and its sensitivity to the temperature variation at low energies. We first determined the transport cross-section which resembles mobility data for similar closed-shell systems by using the Monte Carlo method. Second, we selected the most probable reactive processes and compiled cross-sections from experimental and theoretical data. At the end, an elastic momentum transfer cross-section is obtained by subtracting the compiled cross-sections from the momentum transfer cross-section, taking into account the effects of the angular scattering distributions. Finally, the cross-section set determined in such a way is used as an input in a final Monte Carlo code run, to calculate the flux and bulk reduced mobility for Ne+ + CF4 which were discussed as functions of the reduced electric field E/N (N is the gas density) for the temperature T = 300 K.

  13. Electron impact rotationally elastic total cross section for formamide

    NASA Astrophysics Data System (ADS)

    Vinodkumar, Minaxi; Limbachiya, Chetan; Desai, Hardik; Vinodkumar, P. C.

    2014-09-01

    This paper reports computational results of the total cross sections for electron impact on formamide (HCONH2) over a wide range of energies from 0.01 eV to 5 keV. Total cross sections over such a wide range are reported for the first time as the earlier reported data is up to maximum of 12 eV. Below ionization threshold of the target, we performed ab initio calculations using UK molecular R-Matrix code within static, exchange plus polarization (SEP), and close coupling approximations. Twenty eight target states are included in close coupling formalism. Total 350 channels and 2410 configuration state functions are included in the calculations. We observe a π* shape resonance at 3.41 eV and a σ* resonance at 15.3 eV as against similar resonances reported at 3.77 eV and 14.9 eV, respectively, by Goumans et al. [J. Chem. Theory Comput. 5, 217 (2009)] using SEP model. The cross sections at higher energies are evaluated using the spherical complex optical potential formalism. The two methods are found to be consistent with a smooth cross over at 18 eV. The vertical excitation energies, electronic excitation cross sections, differential cross sections, momentum transfer, and total cross sections are computed. In absence of experimental data, we compared our computed total cross sections with available other theoretical results.

  14. Electron impact rotationally elastic total cross section for formamide

    SciTech Connect

    Vinodkumar, Minaxi; Limbachiya, Chetan; Desai, Hardik Vinodkumar, P. C.

    2014-09-28

    This paper reports computational results of the total cross sections for electron impact on formamide (HCONH₂) over a wide range of energies from 0.01 eV to 5 keV. Total cross sections over such a wide range are reported for the first time as the earlier reported data is up to maximum of 12 eV. Below ionization threshold of the target, we performed ab initio calculations using UK molecular R-Matrix code within static, exchange plus polarization (SEP), and close coupling approximations. Twenty eight target states are included in close coupling formalism. Total 350 channels and 2410 configuration state functions are included in the calculations. We observe a π* shape resonance at 3.41 eV and a σ* resonance at 15.3 eV as against similar resonances reported at 3.77 eV and 14.9 eV, respectively, by Goumans et al. [J. Chem. Theory Comput. 5, 217 (2009)] using SEP model. The cross sections at higher energies are evaluated using the spherical complex optical potential formalism. The two methods are found to be consistent with a smooth cross over at 18 eV. The vertical excitation energies, electronic excitation cross sections, differential cross sections, momentum transfer, and total cross sections are computed. In absence of experimental data, we compared our computed total cross sections with available other theoretical results.

  15. Review of electron impact excitation cross sections for copper atom

    SciTech Connect

    Winter, N.W.; Hazi, A.U.

    1982-02-01

    Excitation of atomic copper by electron impact plays an important role in the copper vapor laser and accurate cross sections are needed for understanding and modeling laser performance. During the past seven years, there have been several attempts to normalize the relative elastic and inelastic cross sections measured by Trajmar and coworkers. However, each of these efforts have yielded different cross sections, and the uncertainty in the correct normalization of the data has been a source of confusion and concern for the kinetic modeling efforts. This difficulty has motivated us to review previous work on the electron impact excitation of copper atom and to perform new calculations of the inelastic cross sections using the impact parameter method. In this memorandum we review the previous attempts to normalize the experimental data and provide a critical assessment of the accuracy of the resulting cross sections. We also present new theoretical cross sections for the electron impact excitation of the /sup 2/S ..-->.. /sup 2/P/sup 0/ and /sup 2/S ..-->.. /sup 2/D transitions in copper. When the experimental cross sections are renormalized to the results of the impact parameter calculations, they are a factor of three smaller than those published in the latest paper of Trajmar et. al. At impact energies above 60 eV the excitation cross sections obtained with the impact parameter method agree well with the results of the very recent, unpublished, close-coupling calculations of Henry. This agreement suggests that the present normalization of the experimental cross sections is probably the most reliable one obtained to date.

  16. Electron impact ionization cross sections of beryllium-tungsten clusters*

    NASA Astrophysics Data System (ADS)

    Sukuba, Ivan; Kaiser, Alexander; Huber, Stefan E.; Urban, Jan; Probst, Michael

    2016-01-01

    We report calculated electron impact ionization cross sections (EICSs) of beryllium-tungsten clusters, BenW with n = 1,...,12, from the ionization threshold to 10 keV using the Deutsch-Märk (DM) and the binary-encounter-Bethe (BEB) formalisms. The positions of the maxima of DM and BEB cross sections are mostly close to each other. The DM cross sections are more sensitive with respect to the cluster size. For the clusters smaller than Be4W they yield smaller cross sections than BEB and vice versa larger cross sections than BEB for clusters larger than Be6W. The maximum cross section values for the singlet-spin groundstate clusters range from 7.0 × 10-16 cm2 at 28 eV (BeW) to 54.2 × 10-16 cm2 at 43 eV (Be12W) for the DM cross sections and from 13.5 × 10-16 cm2 at 43 eV (BeW) to 38.9 × 10-16 cm2 at 43 eV (Be12W) for the BEB cross sections. Differences of the EICSs in different isomers and between singlet and triplet states are also explored. Both the DM and BEB cross sections could be fitted perfectly to a simple expression used in modeling and simulation codes in the framework of nuclear fusion research. Contribution to the Topical Issue "Atomic Cluster Collisions (7th International Symposium)", edited by Gerardo Delgado Barrio, Andrey Solov'Yov, Pablo Villarreal, Rita Prosmiti.Supplementary material in the form of one pdf file available from the Journal web page at http://dx.doi.org/10.1140/epjd/e2015-60583-7

  17. Top quark pair production cross section at Tevatron

    SciTech Connect

    Shary, V.; /DAPNIA, Saclay

    2009-05-01

    An overview of the recent measurements of the top antitop quark pair production cross section in proton antiproton collisions at {radical}s = 1.96 TeV in lepton + jets and dilepton final states is presented. These measurements are based on 1-2.8 fb{sup -1} of data collected with the D0 and CDF experiments at the Fermilab Tevatron collider. The cross section is measured with a precision close to 8 % and found to be compatible with the standard model prediction. Interpretations of the cross-section measurements for charge higgs search and for top quark mass measurement are also discussed.

  18. Relative charge transfer cross section from Rb (4d)

    NASA Astrophysics Data System (ADS)

    Shah, M. H.; Camp, H. A.; Trachy, M. L.; Fléchard, X.; Gearba, M. A.; Nguyen, H.; Brédy, R.; Lundeen, S. R.; Depaola, B. D.

    2005-08-01

    Relative charge transfer cross section measurements for the excited state Rb(4d) with 7keV Na+ is reported. The specific channels reported are Na++Rb(4d5/2)→Na(nl)+Rb+ , where the dominant transfer cross sections channels were nl=3d and 4s . Using a combination of a magneto-optical trap and recoil ion momentum spectroscopy (MOTRIMS methodology), the cross sections were measured relative to the previously studied Na++Rb(5s,5p) systems at the same collision energy.

  19. Antinucleus-Nucleus Cross Sections Implemented in Geant4

    SciTech Connect

    Uzhinsky, V.; Apostolakis, J.; Galoyan, A.; Folger, G.; Grichine, V.M.; Ivanchenko, V.N.; Wright, D.H.; /SLAC

    2012-04-26

    Cross sections of antinucleus ({bar p}, {bar d}, {bar t}, {sup 3}{ovr He}, {sup 4}{ovr He}) interactions with nuclei in the energy range 100 MeV/c to 1000 GeV/c per antinucleon are calculated in the Glauber approximation which provides good description of all known {bar p}Across sections. The results were obtained using a new parameterization of the total and elastic {bar p}p cross sections. Simple parameterizations of the antinucleus-nucleus cross sections are proposed for use in estimating the efficiency of antinucleus detection and tracking in cosmic rays and accelerator experiments. These parameterizations are implemented in the Geant4 toolkit.

  20. Actinide neutron-induced fission cross section measurements at LANSCE

    SciTech Connect

    Tovesson, Fredrik K; Laptev, Alexander B; Hill, Tony S

    2010-01-01

    Fission cross sections of a range of actinides have been measured at the Los Alamos Neutron Science Center (LANSCE) in support of nuclear energy applications in a wide energy range from sub-thermal energies up to 200 MeV. A parallel-plate ionization chamber are used to measure fission cross sections ratios relative to the {sup 235}U standard while incident neutron energies are determined using the time-of-flight method. Recent measurements include the {sup 233,238}U, {sup 239-242}Pu and {sup 243}Am neutron-induced fission cross sections. Obtained data are presented in comparison with ex isting evaluations and previous data.

  1. Relative charge transfer cross section from Rb(4d)

    SciTech Connect

    Shah, M.H.; Camp, H.A.; Trachy, M.L.; De Paola, B.D.; Flechard, X.; Gearba, M.A.; Nguyen, H.; Bredy, R.; Lundeen, S.R.

    2005-08-15

    Relative charge transfer cross section measurements for the excited state Rb(4d) with 7 keV Na{sup +} is reported. The specific channels reported are Na{sup +}+Rb(4d{sub 5/2}){yields}Na(nl)+Rb{sup +}, where the dominant transfer cross sections channels were nl=3d and 4s. Using a combination of a magneto-optical trap and recoil ion momentum spectroscopy (MOTRIMS methodology), the cross sections were measured relative to the previously studied Na{sup +}+Rb(5s,5p) systems at the same collision energy.

  2. Inverse bremsstrahlung cross section estimated within evolving plasmas using effective ion potentials

    NASA Astrophysics Data System (ADS)

    Wang, F.; Weckert, E.; Ziaja, B.

    2009-06-01

    We estimate the total cross sections for field-stimulated photoemissions and photoabsorptions by quasi-free electrons within a non-equilibrium plasma evolving from the strong coupling to the weak coupling regime. Such a transition may occur within laser-created plasmas, when the initially created plasma is cold but the heating of the plasma by the laser field is efficient. In particular, such a transition may occur within plasmas created by intense vacuum ultraviolet (VUV) radiation from a free-electron laser (FEL) as indicated by the results of the first experiments performed by Wabnitz at the FLASH facility at DESY. In order to estimate the inverse bremsstrahlung cross sections, we use point-like and effective atomic potentials. For ions modelled as point-like charges, the total cross sections are strongly affected by the changing plasma environment. The maximal change of the cross sections may be of the order of 75 at the change of the plasma parameters: inverse Debye length, κ, in the range κ = 0 - 3 Å-1 and the electron density, ρe, in the range ρe = 0.01 - 1 Å-3. These ranges correspond to the physical conditions within the plasmas created during the first cluster experiments performed at the FLASH facility at DESY. In contrast, for the effective atomic potentials the total cross sections for photoemission and photoabsorption change only by a factor of seven at most in the same plasma parameter range. Our results show that the inverse bremsstrahlung cross section estimated with the effective atomic potentials is not affected much by the plasma environment. This observation validates the estimations of the enhanced heating effect obtained by Walters, Santra and Greene. This is important as this effect may be responsible for the high-energy absorption within clusters irradiated with VUV radiation.

  3. VUV photoionization cross sections of HO2, H2O2, and H2CO.

    PubMed

    Dodson, Leah G; Shen, Linhan; Savee, John D; Eddingsaas, Nathan C; Welz, Oliver; Taatjes, Craig A; Osborn, David L; Sander, Stanley P; Okumura, Mitchio

    2015-02-26

    The absolute vacuum ultraviolet (VUV) photoionization spectra of the hydroperoxyl radical (HO2), hydrogen peroxide (H2O2), and formaldehyde (H2CO) have been measured from their first ionization thresholds to 12.008 eV. HO2, H2O2, and H2CO were generated from the oxidation of methanol initiated by pulsed-laser-photolysis of Cl2 in a low-pressure slow flow reactor. Reactants, intermediates, and products were detected by time-resolved multiplexed synchrotron photoionization mass spectrometry. Absolute concentrations were obtained from the time-dependent photoion signals by modeling the kinetics of the methanol oxidation chemistry. Photoionization cross sections were determined at several photon energies relative to the cross section of methanol, which was in turn determined relative to that of propene. These measurements were used to place relative photoionization spectra of HO2, H2O2, and H2CO on an absolute scale, resulting in absolute photoionization spectra. PMID:25621533

  4. 8. VIEW OF CROSS SECTION OF THE EASTERNMOST WALL SEGMENT ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    8. VIEW OF CROSS SECTION OF THE EASTERNMOST WALL SEGMENT THAT SHOWS THE TRENCHING AND 1960 PIPELINE CORRIDOR BETWEEN THE WALL SEGMENTS, LOOKING WEST-NORTHWEST - Rock Wall, North side of Battle Creek Canyon, Shingletown, Shasta County, CA

  5. Radiative neutron capture cross sections on 176Lu at DANCE

    NASA Astrophysics Data System (ADS)

    Roig, O.; Jandel, M.; Méot, V.; Bond, E. M.; Bredeweg, T. A.; Couture, A. J.; Haight, R. C.; Keksis, A. L.; Rundberg, R. S.; Ullmann, J. L.; Vieira, D. J.

    2016-03-01

    The cross section of the neutron capture reaction 176Lu(n ,γ ) has been measured for a wide incident neutron energy range with the Detector for Advanced Neutron Capture Experiments at the Los Alamos Neutron Science Center. The thermal neutron capture cross section was determined to be (1912 ±132 ) b for one of the Lu natural isotopes, 176Lu. The resonance part was measured and compared to the Mughabghab's atlas using the R -matrix code, sammy. At higher neutron energies the measured cross sections are compared to ENDF/B-VII.1, JEFF-3.2, and BRC evaluated nuclear data. The Maxwellian averaged cross sections in a stellar plasma for thermal energies between 5 keV and 100 keV were extracted using these data.

  6. Fluctuations of cross sections seen in cosmic ray data

    SciTech Connect

    Wilk, G. ); Wlodarczyk, Z. )

    1994-08-01

    We argue that the unexpected nonexponential behavior of some cosmic ray data is just a manifestation of cross section fluctuations discussed recently in the literature and observed in nuclear collisions and in diffraction dissociation experiments on accelerators.

  7. Local Deplanation Of Double Reinforced Beam Cross Section Under Bending

    NASA Astrophysics Data System (ADS)

    Baltov, Anguel; Yanakieva, Ana

    2015-12-01

    Bending of beams, double reinforced by means of thin composite layers, is considered in the study. Approximate numerical solution is proposed, considering transitional boundary areas, where smooth quadratic transition of the elasticity modulus and deformations take place. Deplanation of the cross section is also accounted for in the areas. Their thickness is found equalizing the total stiffness of the cross section and the layer stiffness. Deplanation of the cross section of the transitional area is determined via the longitudinal deformation in the reinforcing layer, accounting for the equilibrium between the internal and the external moment, generated by the longitudinal stresses in the cross section. A numerical example is given as an illustration demonstrating model's plausibility. The model allows the design and the calculation of recycled concrete beams double reinforced by means of thin layers. The approach is in agreement with modern design of nearly zero energy buildings (NZEB).

  8. 36. CROSS SECTIONAL VIEW OF ORIGINAL HORSE MESA DAM POWER ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    36. CROSS SECTIONAL VIEW OF ORIGINAL HORSE MESA DAM POWER PLANT, LOOKING NORTH. ONLY TWO OF THE THREE UNITS ARE VISIBLE - Horse Mesa Dam, Salt River, 65 miles East of Phoenix, Phoenix, Maricopa County, AZ

  9. 20. CROSS SECTIONAL VIEW OF HORSE MESA, SHOWING RIGHT SPILLWAY ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    20. CROSS SECTIONAL VIEW OF HORSE MESA, SHOWING RIGHT SPILLWAY SUPERSTRUCTURE AND CONCRETE PLACEMENT LINES August 2, 1927 - Horse Mesa Dam, Salt River, 65 miles East of Phoenix, Phoenix, Maricopa County, AZ

  10. Photocopy of longitudinal, cross sections and roof plan of the ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    Photocopy of longitudinal, cross sections and roof plan of the C.B. & Q. R.R. roundhouse and locomotive shops. June 1980. - Chicago, Burlington & Quincy Railroad, Roundhouse & Shops, Broadway & Spring Streets, Aurora, Kane County, IL

  11. Cross Sections for K-Shell Ionization by Electron Impact

    NASA Astrophysics Data System (ADS)

    Santos, J. P.; Parente, F.; Kim, Yong-Ki

    2001-05-01

    The formula for the total ionization cross section by electron impact based on the Binary-Encounter-Bethe (BEB) model, which has been very successful in reproducing electron-impact total ionization cross sections for atoms(Y.-K. Kim and M.E. Rudd, Phys. Rev A 50), 3954 (1994), was extended to provides reliable inner-shell ionization cross sections from the threshold to relativistic incident electron energies with simple input data for the target inner shell: the binding energy, the orbital kinetic energy and the electron occupation number(Y.-K. Kim, J. P. Santos, and F. Parente, Phys. Rev. A, 62), 052710 (2000). A comparison between the nonrelativistic BEB and the relativistic BEB (RBEB) K-shell ionization cross sections by electron impact for the carbon, argon, nickel, niobium, and silver atoms and the available experimental and theoretical data will be presented at the conference.

  12. 4. DETAIL VIEW OF CROSS SECTION OF STRUCTURE, SHOWING EXTERIOR ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    4. DETAIL VIEW OF CROSS SECTION OF STRUCTURE, SHOWING EXTERIOR FACINGS LINED WITH RUBBLE BACKING AND EARTH INFILL, LOOKING EAST - Rock Wall, North side of Battle Creek Canyon, Shingletown, Shasta County, CA

  13. Modeling ionization cross sections: Two decades of dreams come true

    NASA Astrophysics Data System (ADS)

    Kim, Yong-Ki

    1996-03-01

    Modeling of differential and total ionization cross sections by electron impact is reviewed. A new theoretical model that does not depend on any empirical or arbitrary parameters is described. The prototype of this new model was proposed by Rudd and was originally based on the binary-encounter theory. The model has been improved by replacing a part of the binary-encounter theory with the dipole contribution as prescribed by the Bethe theory. The current model, henceforth referred to as the binary-encounter-dipole (BED) model, reproduces known singly differential and total ionization cross sections for small atoms and molecules accurately. The possibility of extending the BED theory to doubly differential cross sections as well as to proton-impact ionization cross sections is discussed.

  14. 15. Power plant elevations and cross sections, sheet 64 of ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    15. Power plant elevations and cross sections, sheet 64 of 130 - Naval Air Station Fallon, Power Plant, 800 Complex, off Carson Road near intersection of Pasture & Berney Roads, Fallon, Churchill County, NV

  15. Theoretical Studies on Photoionization Cross Sections of Solid Gold

    NASA Astrophysics Data System (ADS)

    Ma, Xiao-Guang; Sun, Wei-Guo; Cheng, Yan-Song

    2005-01-01

    Accurate expression for photoabsorption (photoionization) cross sections of high density system proposed recently is used to study the photoionization of solid gold. The results show that the present theoretical photoionization cross sections have good agreement both in structure and in magnitude with the experimental results of gold crystal. The studies also indicate that both the real part ε' and the imaginary part ε'' of the complex dielectric constant ε, and the dielectric influence function of a nonideal system have rich structures in low energy side with a range about 50 eV, and suggest that the influence of particle interactions of surrounding particles with the photoionized particle on the photoionization cross sections can be easily investigated using the dielectric influence function. The electron overlap effects are suggested to be implemented in the future studies to improve the accuracy of theoretical photoionization cross sections of a solid system.

  16. Electron-Impact Total Ionization Cross Sections of Hydrocarbon Ions

    PubMed Central

    Irikura, Karl K.; Kim, Yong-Ki; Ali, M. A.

    2002-01-01

    The Binary-Encounter-Bethe (BEB) model for electron-impact total ionization cross sections has been applied to CH2+, CH3+, CH4+, C2H2+, C2H4+, C2H6+ and H3O+. The cross sections for the hydrocarbon ions are needed for modeling cool plasmas in fusion devices. No experimental data are available for direct comparison. Molecular constants to generate total ionization cross sections at arbitrary incident electron energies using the BEB formula are presented. A recent experimental result on the ionization of H3O+ is found to be almost 1/20 of the present theory at the cross section peak. PMID:27446718

  17. 28. CROSS SECTION OF A RECTANGULAR COKE OVEN SHOWING THE ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    28. CROSS SECTION OF A RECTANGULAR COKE OVEN SHOWING THE INTERNAL STRUCTURE OF THE OVEN. - Tower Hill No. 2 Mine, Approximately 0.47 mile Southwest of intersection of Stone Church Road & Township Route 561, Hibbs, Fayette County, PA

  18. 12. CLOSEUP VIEW OF CROSS SECTION OF SPILLWAY FIFTY FEET ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    12. CLOSE-UP VIEW OF CROSS SECTION OF SPILLWAY FIFTY FEET FROM LAKESHORE, SHOWING REMAINS OF SPILLWAY TIMBERS, LOOKING WEST - Three Bears Lake & Dams, North of Marias Pass, East Glacier Park, Glacier County, MT

  19. Differential cross sections of positron–hydrogen collisions

    NASA Astrophysics Data System (ADS)

    Rong-Mei, Yu; Chun-Ying, Pu; Xiao-Yu, Huang; Fu-Rong, Yin; Xu-Yan, Liu; Li-Guang, Jiao; Ya-Jun, Zhou

    2016-07-01

    We make a detailed study on the angular differential cross sections of positron–hydrogen collisions by using the momentum-space coupled-channels optical (CCO) method for incident energies below the H ionization threshold. The target continuum and the positronium (Ps) formation channels are included in the coupled-channels calculations via a complex equivalent-local optical potential. The critical points, which show minima in the differential cross sections, as a function of the scattering angle and the incident energy are investigated. The resonances in the angular differential cross sections are reported for the first time in this energy range. The effects of the target continuum and the Ps formation channels on the different cross sections are discussed. Project supported by the Nanyang Normal University Science Foundation of China (Grant No. ZX2013017) and the National Natural Science Foundation of China (Grant Nos. 11174066, 61306007, and U1304114).

  20. Photocopy of "sheet 6 of 8" showing cross section of ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    Photocopy of "sheet 6 of 8" showing cross section of house, front elevation, fire finder stand, hip roof cap, and shiplap roof sheathing. - Badger Mountain Lookout, .125 mile northwest of Badger Mountain summit, East Wenatchee, Douglas County, WA

  1. Absolute bioavailability and effect of formulation change, food, or elevated pH with rabeprazole on cobimetinib absorption in healthy subjects.

    PubMed

    Musib, Luna; Choo, Edna; Deng, Yuzhong; Eppler, Steve; Rooney, Isabelle; Chan, Iris T; Dresser, Mark J

    2013-11-01

    Cobimetinib is a potent and highly selective inhibitor of MEK1/2. Since cobimetinib exhibited absorption variability in cancer patients, a series of single-dose studies in healthy subjects were conducted to determine absolute bioavailability and elucidate potential effects of formulation, food, and elevated gastric pH on cobimetinib bioavailability. Three crossover trials were performed with a 20 mg cobimetinib oral dose: absolute bioavailability using a 2 mg intravenous infusion (n = 13), relative bioavailability of tablets versus capsules and food effect (n = 20), and drug interaction with a proton pump inhibitor (20 mg of rabeprazole daily for 5 days prior to cobimetinib administration; n = 20). Absolute bioavailability of cobimetinib was 46.2% (24.2, CV %), likely due to metabolism rather than incomplete absorption. The mean systemic clearance of cobimetinib was low (11.7 L/h [28.2, CV %]). Administration of cobimetinib tablets with a high-fat meal delayed drug absorption (prolonged tmax) but had no statistically significant effect on cobimetinib exposure (Cmax and AUC0-∞). Tablet and capsule formulations of cobimetinib showed comparable exposures. Cobimetinib exhibited delayed absorption (tmax) in the presence of rabeprazole, with no statistically significant effects on drug exposure (Cmax and AUC0-∞) in the fasted state. In conclusion, cobimetinib oral absorption was not affected by change in formulation, food, or elevated gastric pH.

  2. Thermal neutron capture cross sections of tellurium isotopes

    SciTech Connect

    Tomandl, I.; Honzatko, J.; von Egidy, T.; Wirth, H.-F.; Belgya, T.; Lakatos, M.; Szentmiklosi, L.; Revay, Zs.; Molnar, G.L.; Firestone, R.B.; Bondarenko, V.

    2004-03-01

    New values for thermal neutron capture cross sections of the tellurium isotopes 122Te, 124Te, 125Te, 126Te, 128Te, and 130Te are reported. These values are based on a combination of newly determined partial g-ray cross sections obtained from experiments on targets contained natural Te and gamma intensities per capture of individual Te isotopes. Isomeric ratios for the thermal neutron capture on the even tellurium isotopes are also given.

  3. Modelling of reaction cross sections and prompt neutron emission

    NASA Astrophysics Data System (ADS)

    Hambsch, F.-J.; Tudora, A.; Oberstedt, S.

    2010-10-01

    Accurate nuclear data concerning reaction cross sections and the emission of prompt fission neutrons (i.e. multiplicity and spectra) as well as other fission fragment data are of great importance for reactor physics design, especially for the new Generation IV nuclear energy systems. During the past years for several actinides (238U(n, f) and 237Np(n, f)) both the reaction cross sections and prompt neutron multiplicities and spectra have been calculated within the frame of the EFNUDAT project.

  4. Top Quark Pair Production Cross Section at the Tevatron

    SciTech Connect

    Peters, Reinhild Yvonne

    2015-09-25

    The top quark, discovered in 1995 by the CDF and D0 collaborations at the Tevatron proton antiproton collider at Fermilab, has undergone intense studies in the last 20 years. Currently, CDF and D0 converge on their measurements of top-antitop quark production cross sections using the full Tevatron data sample. In these proceedings, the latest results on inclusive and differential measurements of top-antitop quark production cross sections at the Tevatron are reported.

  5. Measurement of the Raman scattering cross section of the breathing mode in KDP and DKDP crystals.

    PubMed

    Demos, Stavros G; Raman, Rajesh N; Yang, Steven T; Negres, Raluca A; Schaffers, Kathleen I; Henesian, Mark A

    2011-10-10

    The spontaneous Raman scattering cross sections of the main peaks (related to the A1 vibrational mode) in rapid and conventional grown potassium dihydrogen phosphate and deuterated crystals are measured at 532 nm, 355 nm, and 266 nm. The measurement involves the use of the Raman line of water centered at 3400 cm-1 as a reference to obtain relative values of the cross sections which are subsequently normalized against the known absolute value for water as a function of excitation wavelength. This measurement enables the estimation of the transverse stimulated Raman scattering gain of these nonlinear optical materials in various configurations suitable for frequency conversion and beam control in high-power, large-aperture laser systems.

  6. Rapid decrease of radar cross section of meteor head echo observed by the MU radar

    NASA Astrophysics Data System (ADS)

    Nakamura, T.; Nishio, M.; Sato, T.; Tsutsumi, S.; Tsuda, T.; Fushimi, K.

    The meteor head echo observation using the MU (Middle and Upper atmosphere) radar (46.5M Hz, 1MW), Shigaraki, Japan, was carried out simultaneously with a high sensitive ICCD (Image-intensified CCD) camera observation in November 2001. The time records were synchronized using GPS satellite signals, in order to compare instantaneous radar and optical meteor magnitudes. 26 faint meteors were successfully observed simultaneously by both equipments. Detailed comparison of the time variation of radar echo intensity and absolute optical magnitude showed that the radar scattering cross section is likely to decrease rapidly by 5 - 20 dB without no corresponding magnitude variation in the optical data. From a simple modeling, we concluded that such decrease of RCS (radar cross section ) is probably due to the transition from overdense head echo to underd ense head echo.

  7. Photoionization cross section measurements of the excited states of cobalt in the near-threshold region

    SciTech Connect

    Zheng, Xianfeng Zhou, Xiaoyu; Cheng, Zaiqi; Jia, Dandan; Qu, Zehua; Yao, Guanxin; Zhang, Xianyi; Cui, Zhifeng

    2014-10-15

    We present measurements of photoionization cross-sections of the excited states of cobalt using a two-color, two-step resonance ionization technique in conjunction with a molecular beam time of flight (TOF) mass spectrometer. The atoms were produced by the laser vaporization of a cobalt rod, coupled with a supersonic gas jet. The absolute photoionization cross-sections at threshold and near-threshold regions (0-1.2 eV) were measured, and the measured values ranged from 4.2±0.7 Mb to 10.5±1.8 Mb. The lifetimes of four odd parity energy levels are reported for the first time.

  8. Measurement of the thermal neutron capture cross section and the resonance integral of radioactive Hf182

    NASA Astrophysics Data System (ADS)

    Vockenhuber, C.; Bichler, M.; Wallner, A.; Kutschera, W.; Dillmann, I.; Käppeler, F.

    2008-04-01

    The neutron capture cross sections of the radioactive isotope Hf182 (t1/2=8.9×106 yr) in the thermal and epithermal energy regions have been measured by activation at the TRIGA Mark-II reactor of the Atomic Institute of the Austrian Universities in Vienna, Austria, and subsequent γ-ray spectroscopy of Hf183. High values for the thermal (kT=25 meV) cross section σ0=133±10 b and for the resonance integral I0=5850±660 b were found. Additionally, the absolute intensities of the main γ-ray transitions in the decay of Hf182 have been considerably improved.

  9. Krypton charge exchange cross sections for Hall effect thruster models

    SciTech Connect

    Hause, Michael L.; Prince, Benjamin D.; Bemish, Raymond J.

    2013-04-28

    Following discharge from a Hall effect thruster, charge exchange occurs between ions and un-ionized propellant atoms. The low-energy cations produced can disturb operation of onboard instrumentation or the thruster itself. Charge-exchange cross sections for both singly and doubly charged propellant atoms are required to model these interactions. While xenon is the most common propellant currently used in Hall effect thrusters, other propellants are being considered, in particular, krypton. We present here guided-ion beam measurements and comparisons to semiclassical calculations for Kr{sup +} + Kr and Kr{sup 2+} + Kr cross sections. The measurements of symmetric Kr{sup +} + Kr charge exchange are in good agreement with both the calculations including spin-orbit effects and previous measurements. For the symmetric Kr{sup 2+} + Kr reaction, we present cross section measurements for center-of-mass energies between 1 eV and 300 eV, which spans energies not previously examined experimentally. These cross section measurements compare well with a simple one-electron transfer model. Finally, cross sections for the asymmetric Kr{sup 2+} + Kr {yields} Kr{sup +} + Kr{sup +} reaction show an onset near 12 eV, reaching cross sections near constant value of 1.6 A{sup 2} with an exception near 70-80 eV.

  10. Topological Optimization of Beam Cross Section by Employing Extrusion Constraint

    NASA Astrophysics Data System (ADS)

    Zuberi, Rehan H.; Zhengxing, Zuo; Kai, Long

    2010-05-01

    Optimal cross-section design of beams plays a characteristic role which signifies the rigidity of the member in bending, shear and torsion load conditions. Practically modern overhead crane girders, railway bridge girders or rail tracks etc. require constant cross-section along the axial direction. Conventional topological optimization modeling procedures in such cases prove inadequate for the reason that these procedures generate non-uniform topologies along the axis of the bending member. To examine optimal topology of those structural bending members which commonly possess constant cross-section along the axis the topology optimization with extrusion constraint is more appropriate. The extrusion constraint method suggests a fresh approach to investigate optimal topologies of beam cross-section under the influence of realistic loading condition across the section at the beginning of design cycle. Presented study is focused upon the influence of various configuration and location of the load and boundary conditions on the topology of the of the beam cross-section which was not possible prior to the materialization of the extrusion or stamping constraint method. Several realistic loads and boundary conditions have been applied on the 3D beam model and optimal cross-section topologies obtained have uniform compliance history and convergent solutions. The lowest compliance criteria have been suggested to choose topologies as furthers shape and size optimization candidates during beam design process.

  11. Thermoelastic damping in microrings with circular cross-section

    NASA Astrophysics Data System (ADS)

    Li, Pu; Fang, Yuming; Zhang, Jianrun

    2016-01-01

    Predicting thermoelastic damping (TED) is crucial in the design of high Q micro-resonators. Microrings are often critical components in many micro-resonators. Some analytical models for TED in microrings have already been developed in the past. However, the previous works are limited to the microrings with rectangular cross-section. The temperature field in the rectangular cross-section is one-dimensional. This paper deals with TED in the microrings with circular cross-section. The temperature field in the circular cross-section is two-dimensional. This paper first presents a 2-D analytical model for TED in the microrings with circular cross-section. Only the two-dimensional heat conduction in the circular cross-section is considered. The heat conduction along the circumferential direction of the microring is neglected in the 2-D model. Then the 2-D model has been extended to cover the circumferential heat conduction, and a 3-D analytical model for TED has been developed. The analytical results from the present 2-D and 3-D models show good agreement with the numerical results of FEM model. The limitations of the present 2-D analytical model are assessed.

  12. General Constraints on Cross Sections Deduced from Surrogate Reactions

    SciTech Connect

    Younes, W

    2003-08-14

    Cross sections that cannot be measured in the laboratory, e.g. because the target lifetime is too short, can be inferred indirectly from a different reaction forming the same compound system, but with a more accessible beam/target combination (the ''surrogate-reaction'' technique). The reactions share the same compound system and a common decay mechanism, but they involve different formation processes. Therefore, an implicit constraint is imposed on the inferred cross section deduced from the measured surrogate-reaction data, through the common decay mechanism. In this paper, the mathematical consequences of this implicit constraint are investigated. General formulas are derived from upper and lower bounds on the inferred cross section, estimated from surrogate data in a procedure which does not require any modeling of the common decay process. As an example, the formulas developed here are applied to the case of the {sup 235}U(n,f) cross section, deduced from {sup 234}U(t,pf) surrogate data. The calculated bounds are not very tight in this particular case. However, by introducing a few qualitative assumptions about the physics of the fission process, meaningful bounds on the deduced cross section are obtained. Upper and lower limits for the cross-section ratio of the (n,f) reaction on the {sup 235}U isomer at E{sub x} = 77 eV relative to the (n,f) reaction on the ground state are also calculated. The generalization of this technique to other surrogate reactions is discussed.

  13. A genetic algorithm to reduce stream channel cross section data

    USGS Publications Warehouse

    Berenbrock, C.

    2006-01-01

    A genetic algorithm (GA) was used to reduce cross section data for a hypothetical example consisting of 41 data points and for 10 cross sections on the Kootenai River. The number of data points for the Kootenai River cross sections ranged from about 500 to more than 2,500. The GA was applied to reduce the number of data points to a manageable dataset because most models and other software require fewer than 100 data points for management, manipulation, and analysis. Results indicated that the program successfully reduced the data. Fitness values from the genetic algorithm were lower (better) than those in a previous study that used standard procedures of reducing the cross section data. On average, fitnesses were 29 percent lower, and several were about 50 percent lower. Results also showed that cross sections produced by the genetic algorithm were representative of the original section and that near-optimal results could be obtained in a single run, even for large problems. Other data also can be reduced in a method similar to that for cross section data.

  14. Design of the Cross Section Shape of AN Aluminum Crash Box for Crashworthiness Enhancement of a CAR

    NASA Astrophysics Data System (ADS)

    Kim, S. B.; Huh, H.; Lee, G. H.; Yoo, J. S.; Lee, M. Y.

    This paper deals with the crashworthiness of an aluminum crash box for an auto-body with the various shapes of cross section such as a rectangle, a hexagon and an octagon. First, crash boxes with various cross sections were tested with numerical simulation to obtain the energy absorption capacity and the mean load. In case of the simple axial crush, the octagon shape shows higher mean load and energy absorption than the other two shapes. Secondly, the crash boxes were assembled to a simplified auto-body model for the overall crashworthiness. The model consists of a bumper, crash boxes, front side members and a sub-frame representing the behavior of a full car at the low speed impact. The analysis result shows that the rectangular cross section shows the best performance as a crash box which deforms prior to the front side member. The hexagonal and octagonal cross sections undergo torsion and local buckling as the width of cross section decreases while the rectangular cross section does not. The simulation result of the rectangular crash box was verified with the experimental result. The simulation result shows close tendency in the deformed shape and the load-displacement curve to the experimental result.

  15. Calculation of the Coulomb Fission Cross Sections for Pb-Pb and Bi-Pb Interactions at 158 A GeV

    NASA Technical Reports Server (NTRS)

    Poyser, William J.; Ahern, Sean C.; Norbury, John W.; Tripathi, R. K.

    2002-01-01

    The Weizsacker-Williams (WW) method of virtual quanta is used to make approximate cross section calculations for peripheral relativistic heavy-ion collisions. We calculated the Coulomb fission cross sections for projectile ions of Pb-208 and Bi-209 with energies of 158 A GeV interacting with a Pb-208 target. We also calculated the electromagnetic absorption cross section for Pb-208 ion interacting as described. For comparison we use both the full WW method and a standard approximate WW method. The approximate WW method in larger cross sections compared to the more accurate full WW method.

  16. Photo-fragmentation cross-section of gaseous 2,4,6-trinitrotoluene at different ultraviolet wavelengths.

    PubMed

    Sharma, Ramesh C; Miller, Tracy S; Usachev, Alexander D; Singh, Jagdish P; Yueh, Fang-Yu; Monts, David L

    2009-04-01

    The photo-fragmentation cross-section of 2,4,6-trinitrotoluene (TNT) vapor at room temperature was determined at different ultraviolet wavelengths (254, 300, 340, and 400 nm) by measuring the concentration of NO molecule with cavity ring down spectroscopy and correcting for the photo-fragmentation cross-section of NO(2). Nitric oxide (NO) molecules are produced by the TNT photo-fragmentation processes via an intermediate production of NO(2). Our results reveal that the photo-fragmentation cross-section of TNT changes appreciably with change in wavelength with xenon arc lamp illumination, increasing with decreasing excitation wavelength. The maximum value of cross-section was observed at the shortest photo-fragmentation wavelength studied (254 nm), which is closest to the wavelength of an absorption peak of TNT near 220 nm.

  17. Cross section for inelastic neutron ''acceleration'' by {sup 178}Hf{sup m2}

    SciTech Connect

    Karamian, S. A.; Carroll, J. J.

    2011-02-15

    The scattering of thermal neutrons from isomeric nuclei may include events in which the outgoing neutrons have increased kinetic energy. This process has been called inelastic neutron acceleration, or INNA, and occurs when the final nucleus, after emission of the neutron, is left in a state with lower energy than that of the isomer. The result, therefore, is an induced depletion of the isomer to the ground state. A cascade of several {gamma}'s must accompany the neutron emission to release the high angular momentum of the initial isomeric state. INNA was previously observed in a few cases, and the measured cross sections were only in modest agreement with theoretical estimates. The most recent measurement of an INNA cross section was {sigma}{sub INNA}=258{+-}58 b for neutron scattering by {sup 177}Lu{sup m}. In the present work, an INNA cross section of {sigma}{sub INNA}=168 {+-} 33 b was deduced from measurements of the total burnup of the high-spin, four-quasiparticle isomer {sup 178}Hf{sup m2} during irradiation by thermal neutrons. Statistical estimates for the probability of different reaction channels past neutron absorption were used in the analysis, and the deduced {sigma}{sub INNA} was compared to the theoretically predicted cross section.

  18. Measurement of muon neutrino and antineutrino induced single neutral pion production cross sections

    SciTech Connect

    Anderson, Colin E.

    2011-05-01

    Elucidating the nature of neutrino oscillation continues to be a goal in the vanguard of the efforts of physics experiment. As neutrino oscillation searches seek an increasingly elusive signal, a thorough understanding of the possible backgrounds becomes ever more important. Measurements of neutrino-nucleus interaction cross sections are key to this understanding. Searches for νμ → νe oscillation - a channel that may yield insight into the vanishingly small mixing parameter θ13, CP violation, and the neutrino mass hierarchy - are particularly susceptible to contamination from neutral current single π0 (NC 1π0) production. Unfortunately, the available data concerning NC 1π0 production are limited in scope and statistics. Without satisfactory constraints, theoretical models of NC 1π0 production yield substantially differing predictions in the critical Eν ~ 1 GeV regime. Additional investigation of this interaction can ameliorate the current deficiencies. The Mini Booster Neutrino Experiment (MiniBooNE) is a short-baseline neutrino oscillation search operating at the Fermi National Accelerator Laboratory (Fermilab). While the oscillation search is the principal charge of the MiniBooNE collaboration, the extensive data (~ 106 neutrino events) offer a rich resource with which to conduct neutrino cross section measurements. This work concerns the measurement of both neutrino and antineutrino NC 1π0 production cross sections at MiniBooNE. The size of the event samples used in the analysis exceeds that of all other similar experiments combined by an order of magnitude. We present the first measurements of the absolute NC 1π0 cross section as well as the first differential cross sections in both neutrino and antineutrino mode. Specifically, we measure single differential cross sections with respect to pion momentum and pion angle. We find the

  19. A Multigroup Reaction Cross-Section Collapsing Code and Library of 154-Group Fission-Product Cross Sections.

    1983-03-23

    Version 01/02 The code reads multigroup cross sections from a compatible data file and collapses user-selected reaction cross sections to any few-group structure using one of a variety of user neutron flux spectrum options given below: Option Flux description 1 Built-in function including Maxwellian, fission, fusion and slowing-down regions and requiring user-specified parameters and energy-region boundaries. 2 Set of log-log flux-energy interpolation points read from input cross-section data file. 3 Set of log-log flux-energy interpolationmore » points read from user-supplied card input. 4 - 6 Histogram flux values read from user-supplied card input in arbitrary group structure in units of flux-per unit-energy, flux-per-unit lethargy, or integral group flux. LAFPX-E may be used to collapse any set of multigroup reaction cross sections furnished in the required format. However, the code was developed for, and is furnished with, a library of 154-group fission-product cross sections processed from ENDF/B-IV with a typical light water reactor (LWR) flux spectrum and temperature. Four-group radiative capture cross sections produced for LWR calculations are tabulated in the code documentation and are incorporated in the EPRI-CINDER data library, RSIC Code Package CCC-309.« less

  20. ACTIV87: Fast Neutron Activation Cross Section File

    1993-08-01

    4. HISTORICAL BACKGROUND AND INFORMATION ACTIV87 is a compilation of fast neutron induced activation reaction cross-sections. The compilation covers energies from threshold to 20 MeV and is based on evaluated data taken from other evaluated data libraries and individual evaluations. The majority of these evaluations were performed by using available experimental data. The aforementioned available experimental data were used in the selection of needed parameters for theoretical computations and for normalizing the results of suchmore » computations. Theoretical calculations were also used for interpolation and extrapolation of experimental cross-section data. All of the evaluated data curves were compared with experimental data that had been reported over the four year period preceding 1987. Only those cross-sections not in contradiction with experimental data that was current in 1987 were retained in the activation file, ACTIV87. In cases of several conflicting evaluations, that evaluation was chosen which best corresponded to the experimental data. A few evaluated curves were renormalized in accordance with the results of the latest precision measurements. 5. APPLICATION OF THE DATA 6. SOURCE AND SCOPE OF DATA The following libraries and individual files of evaluated neutron cross-section data were used for the selection of the activation cross-sections: the BOSPOR Library, the Activation File of the Evaluated Nuclear Data Library, the Evaluated Neutron Data File (ENDF/B-V) Activation File, the International Reactor Dosimetry File (IRDF-82), and individual evaluations carried out under various IAEA research contracts. The file of selected reactions contains 206 evaluated cross-section curves of the (n,2n), (n,p) and (n,a) reactions which lead to radioactive products and may be used in many practical applications of neutron activation analysis. Some competing activation reactions, usually with low cross-section values, are given for completeness.« less

  1. Temperature dependence of the NO3 absorption spectrum

    NASA Technical Reports Server (NTRS)

    Sander, Stanley P.

    1986-01-01

    The absorption spectrum of the gas-phase NO3 radical has been studied between 220 and 700 nm by using both flash photolysis and discharge flow reactors for the production of NO3. In the flash photolysis method, cross sections at the peak of the (0,0) band at 661.9 nm were measured relative to the cross section of ClONO2 at several different wavelengths. From the best current measurements of the ClONO2 spectrum, the NO3 cross section at 661.9 nm was determined to be (2.28 + or 0.34) x 10 to the -17th sq cm/molecule at 298 K. Measurements at 230 K indicated that the cross section increases by a factor of 1.18 at the peak of the (0,0) band. The discharge flow method was used both to obtain absolute cross sections at 661.9 nm and to obtain relative absorption spectra between 300 and 700 nm at 298 and 230 K. A value of (1.83 + or - 0.27) x 10 to the -17th sq cm/molecule was obtained for sigma NO3 at 661.9 nm at 298 K. Upper limits to the NO3 cross sections were also measured between 220 and 260 nm with the discharge flow method.

  2. Inclined Bodies of Various Cross Sections at Supersonic Speeds

    NASA Technical Reports Server (NTRS)

    Jorgensen, Leland H.

    1958-01-01

    To aid in assessing effects of cross-sectional shape on body aerodynamics, the forces and moments have been measured for bodies with circular, elliptic, square, and triangular cross sections at Mach numbers 1.98 and 3.88. Results for bodies with noncircular cross sections have been compared with results for bodies of revolution having the same axial distribution of cross-sectional area (and, thus, the same equivalent fineness ratio). Comparisons have been made for bodies of fineness ratios 6 and 10 at angles of attack from 0 deg to about 20 deg and for Reynolds numbers, based on body length, of 4.0 x 10(exp 6) and 6.7 x 10(exp 6). The results of this investigation show that distinct aerodynamic advantages can be obtained by using bodies with noncircular cross sections. At certain angles of bank, bodies with elliptic, square, and triangular cross sections develop considerably greater lift and lift-drag ratios than equivalent bodies of revolution. For bodies with elliptic cross sections, lift and pitching-moment coefficients can be correlated with corresponding coefficients for equivalent circular bodies. It has been found that the ratios of lift and pitching-moment coefficients for an elliptic body to those for an equivalent circular body are practically constant with change in both angle of attack and Mach number. These lift and moment ratios are given very accurately by slender-body theory. As a result of this agreement, the method of NACA Rep. 1048 for computing forces and moments for bodies of revolution has been simply extended to bodies with elliptic cross sections. For the cases considered (elliptic bodies of fineness ratios 6 and 10 having cross-sectional axis ratios of 1.5 and 2), agreement of theory with experiment is very good. As a supplement to the force and moment results, visual studies of the flow over bodies have been made by use of the vapor-screen, sublimation, and white-lead techniques. Photographs from these studies are included in the report.

  3. Resonant vibrational excitation of H{sub 2} by electron impact: Full-range differential cross sections

    SciTech Connect

    Poparic, G. B.; Belic, D. S.; Ristic, M. M.

    2010-07-15

    Electron-impact vibrational excitation of the hydrogen molecule has been revisited in the energy region from 1 to 5 eV. A crossed-beam double trochoidal electron spectrometer is used. Forward and backward scattered electrons from the v=0{yields}1 excitation channel are separated by electron-beam modulation and time-of-flight detection technique. Present results are normalized and absolute values of differential cross sections at critical border angles of 0 deg. and 180 deg. are determined. In this way the differential cross-section measurements are completed in the full angular range from 0 deg. to 180 deg.

  4. Measurement of the Inclusive Jet Cross Section in pp Collisions at √s=7 TeV

    DOE PAGES

    Chatrchyan, S.; Khachatryan, V.; Sirunyan, A. M.; Tumasyan, A.; Adam, W.; Bergauer, T.; Dragicevic, M.; Erö, J.; Fabjan, C.; Friedl, M.; et al

    2011-09-19

    The inclusive jet cross section is measured in pp collisions with a center-of-mass energy of 7 TeV at the Large Hadron Collider using the CMS experiment. The data sample corresponds to an integrated luminosity of 34 pb⁻¹. The measurement is made for jet transverse momenta in the range 18–1100 GeV and for absolute values of rapidity less than 3. The measured cross section extends to the highest values of jet pT ever observed and, within the experimental and theoretical uncertainties, is generally in agreement with next-to-leading-order perturbative QCD predictions.

  5. Measurement of the inclusive jet cross section in pp collisions at √s = 7 TeV.

    PubMed

    Chatrchyan, S; Khachatryan, V; Sirunyan, A M; Tumasyan, A; Adam, W; Bergauer, T; Dragicevic, M; Erö, J; Fabjan, C; Friedl, M; Frühwirth, R; Ghete, V M; Hammer, J; Hänsel, S; Hoch, M; Hörmann, N; Hrubec, J; Jeitler, M; Kiesenhofer, W; Krammer, M; Liko, D; Mikulec, I; Pernicka, M; Rohringer, H; Schöfbeck, R; Strauss, J; Taurok, A; Teischinger, F; Wagner, P; Waltenberger, W; Walzel, G; Widl, E; Wulz, C-E; Mossolov, V; Shumeiko, N; Gonzalez, J Suarez; Bansal, S; Benucci, L; De Wolf, E A; Janssen, X; Maes, J; Maes, T; Mucibello, L; Ochesanu, S; Roland, B; Rougny, R; Selvaggi, M; Van Haevermaet, H; Van Mechelen, P; Van Remortel, N; Blekman, F; Blyweert, S; D'Hondt, J; Devroede, O; Suarez, R Gonzalez; Kalogeropoulos, A; Maes, M; Van Doninck, W; Van Mulders, P; Van Onsem, G P; Villella, I; Charaf, O; Clerbaux, B; De Lentdecker, G; Dero, V; Gay, A P R; Hammad, G H; Hreus, T; Marage, P E; Thomas, L; Vander Velde, C; Vanlaer, P; Adler, V; Cimmino, A; Costantini, S; Grunewald, M; Klein, B; Lellouch, J; Marinov, A; Mccartin, J; Ryckbosch, D; Thyssen, F; Tytgat, M; Vanelderen, L; Verwilligen, P; Walsh, S; Zaganidis, N; Basegmez, S; Bruno, G; Caudron, J; Ceard, L; Gil, E Cortina; De Favereau De Jeneret, J; Delaere, C; Favart, D; Giammanco, A; Grégoire, G; Hollar, J; Lemaitre, V; Liao, J; Militaru, O; Ovyn, S; Pagano, D; Pin, A; Piotrzkowski, K; Schul, N; Beliy, N; Caebergs, T; Daubie, E; Alves, G A; De Jesus Damiao, D; Pol, M E; Souza, M H G; Carvalho, W; Da Costa, E M; De Oliveira Martins, C; Fonseca De Souza, S; Mundim, L; Nogima, H; Oguri, V; Prado Da Silva, W L; Santoro, A; Silva Do Amaral, S M; Sznajder, A; Bernardes, C A; Dias, F A; Tomei, T R Fernandez Perez; Gregores, E M; Lagana, C; Marinho, F; Mercadante, P G; Novaes, S F; Padula, Sandra S; Darmenov, N; Dimitrov, L; Genchev, V; Iaydjiev, P; Piperov, S; Rodozov, M; Stoykova, S; Sultanov, G; Tcholakov, V; Trayanov, R; Vankov, I; Dimitrov, A; Hadjiiska, R; Karadzhinova, A; Kozhuharov, V; Litov, L; Mateev, M; Pavlov, B; Petkov, P; 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Fabbro, B; Faure, J L; Ferri, F; Ganjour, S; Gentit, F X; Givernaud, A; Gras, P; Hamel de Monchenault, G; Jarry, P; Locci, E; Malcles, J; Marionneau, M; Millischer, L; Rander, J; Rosowsky, A; Shreyber, I; Titov, M; Verrecchia, P; Baffioni, S; Beaudette, F; Benhabib, L; Bianchini, L; Bluj, M; Broutin, C; Busson, P; Charlot, C; Dahms, T; Dobrzynski, L; Elgammal, S; Granier de Cassagnac, R; Haguenauer, M; Miné, P; Mironov, C; Ochando, C; Paganini, P; Sabes, D; Salerno, R; Sirois, Y; Thiebaux, C; Wyslouch, B; Zabi, A; Agram, J-L; Andrea, J; Bloch, D; Bodin, D; Brom, J-M; Cardaci, M; Chabert, E C; Collard, C; Conte, E; Drouhin, F; Ferro, C; Fontaine, J-C; Gelé, D; Goerlach, U; Greder, S; Juillot, P; Karim, M; Le Bihan, A-C; Mikami, Y; Van Hove, P; Fassi, F; Mercier, D; Baty, C; Beauceron, S; Beaupere, N; Bedjidian, M; Bondu, O; Boudoul, G; Boumediene, D; Brun, H; Chasserat, J; Chierici, R; Contardo, D; Depasse, P; El Mamouni, H; Fay, J; Gascon, S; Ille, B; Kurca, T; Le Grand, T; Lethuillier, M; 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Sharma, V; Simon, S; Tu, Y; Vartak, A; Wasserbaech, S; Würthwein, F; Yagil, A; Yoo, J; Barge, D; Bellan, R; Campagnari, C; D'Alfonso, M; Danielson, T; Flowers, K; Geffert, P; Incandela, J; Justus, C; Kalavase, P; Koay, S A; Kovalskyi, D; Krutelyov, V; Lowette, S; Mccoll, N; Pavlunin, V; Rebassoo, F; Ribnik, J; Richman, J; Rossin, R; Stuart, D; To, W; Vlimant, J R; Apresyan, A; Bornheim, A; Bunn, J; Chen, Y; Gataullin, M; Ma, Y; Mott, A; Newman, H B; Rogan, C; Shin, K; Timciuc, V; Traczyk, P; Veverka, J; Wilkinson, R; Yang, Y; Zhu, R Y; Akgun, B; Carroll, R; Ferguson, T; Iiyama, Y; Jang, D W; Jun, S Y; Liu, Y F; Paulini, M; Russ, J; Vogel, H; Vorobiev, I; Cumalat, J P; Dinardo, M E; Drell, B R; Edelmaier, C J; Ford, W T; Gaz, A; Heyburn, B; Lopez, E Luiggi; Nauenberg, U; Smith, J G; Stenson, K; Ulmer, K A; Wagner, S R; Zang, S L; Agostino, L; Alexander, J; Cassel, D; Chatterjee, A; Das, S; Eggert, N; Gibbons, L K; Heltsley, B; Hopkins, W; Khukhunaishvili, A; Kreis, B; Kaufman, G Nicolas; Patterson, J R; Puigh, D; Ryd, A; Salvati, E; Shi, X; Sun, W; Teo, W D; Thom, J; Thompson, J; Vaughan, J; Weng, Y; Winstrom, L; Wittich, P; Biselli, A; Cirino, G; Winn, D; Abdullin, S; Albrow, M; Anderson, J; Apollinari, G; Atac, M; Bakken, J A; Banerjee, S; Bauerdick, L A T; Beretvas, A; Berryhill, J; Bhat, P C; Bloch, I; Borcherding, F; Burkett, K; Butler, J N; Chetluru, V; Cheung, H W K; Chlebana, F; Cihangir, S; Cooper, W; Eartly, D P; Elvira, V D; Esen, S; Fisk, I; Freeman, J; Gao, Y; Gottschalk, E; Green, D; Gunthoti, K; Gutsche, O; Hanlon, J; Harris, R M; Hirschauer, J; Hooberman, B; Jensen, H; Johnson, M; Joshi, U; Khatiwada, R; Klima, B; Kousouris, K; Kunori, S; Kwan, S; Leonidopoulos, C; Limon, P; Lincoln, D; Lipton, R; Lykken, J; Maeshima, K; Marraffino, J M; Mason, D; McBride, P; Miao, T; Mishra, K; Mrenna, S; Musienko, Y; Newman-Holmes, C; O'Dell, V; Pordes, R; Prokofyev, O; Saoulidou, N; Sexton-Kennedy, E; Sharma, S; Spalding, W J; Spiegel, L; Tan, P; Taylor, L; Tkaczyk, S; Uplegger, L; Vaandering, E W; Vidal, R; Whitmore, J; Wu, W; Yang, F; Yumiceva, F; Yun, J C; Acosta, D; Avery, P; Bourilkov, D; Chen, M; De Gruttola, M; Di Giovanni, G P; Dobur, D; Drozdetskiy, A; Field, R D; Fisher, M; Fu, Y; Furic, I K; Gartner, J; Kim, B; Konigsberg, J; Korytov, A; Kropivnitskaya, A; Kypreos, T; Matchev, K; Mitselmakher, G; Muniz, L; Prescott, C; Remington, R; Schmitt, M; Scurlock, B; Sellers, P; Skhirtladze, N; Snowball, M; Wang, D; Yelton, J; Zakaria, M; Ceron, C; Gaultney, V; Kramer, L; Lebolo, L M; Linn, S; Markowitz, P; Martinez, G; Mesa, D; Rodriguez, J L; Adams, T; Askew, A; Bochenek, J; Chen, J; Diamond, B; Gleyzer, S V; Haas, J; Hagopian, S; Hagopian, V; Jenkins, M; Johnson, K F; Prosper, H; Quertenmont, L; Sekmen, S; Veeraraghavan, V; Baarmand, M M; Dorney, B; Guragain, S; Hohlmann, M; Kalakhety, H; Ralich, R; Vodopiyanov, I; Adams, M R; Anghel, I M; Apanasevich, L; Bai, Y; Bazterra, V E; Betts, R R; Callner, J; Cavanaugh, R; Dragoiu, C; Gauthier, L; Gerber, C E; Hamdan, S; Hofman, D J; Khalatyan, S; Kunde, G J; Lacroix, F; Malek, M; O'Brien, C; Silvestre, C; Smoron, A; Strom, D; Varelas, N; Akgun, U; Albayrak, E A; Bilki, B; Clarida, W; Duru, F; Lae, C K; McCliment, E; Merlo, J-P; Mermerkaya, H; Mestvirishvili, A; Moeller, A; Nachtman, J; Newsom, C R; Norbeck, E; Olson, J; Onel, Y; Ozok, F; Sen, S; Wetzel, J; Yetkin, T; Yi, K; Barnett, B A; Blumenfeld, B; Bonato, A; Eskew, C; Fehling, D; Giurgiu, G; Gritsan, A V; Guo, Z J; Hu, G; Maksimovic, P; Rappoccio, S; Swartz, M; Tran, N V; Whitbeck, A; Baringer, P; Bean, A; Benelli, G; Grachov, O; Kenny, R P; Murray, M; Noonan, D; Sanders, S; Wood, J S; Zhukova, V; Barfuss, A F; Bolton, T; Chakaberia, I; Ivanov, A; Khalil, S; Makouski, M; Maravin, Y; Shrestha, S; Svintradze, I; Wan, Z; Gronberg, J; Lange, D; Wright, D; Baden, A; Boutemeur, M; Eno, S C; Ferencek, D; Gomez, J A; Hadley, N J; Kellogg, R G; Kirn, M; Lu, Y; Mignerey, A C; Rossato, K; Rumerio, P; Santanastasio, F; Skuja, A; Temple, J; Tonjes, M B; Tonwar, S C; Twedt, E; Alver, B; Bauer, G; Bendavid, J; Busza, W; Butz, E; Cali, I A; Chan, M; Dutta, V; Everaerts, P; Ceballos, G Gomez; Goncharov, M; Hahn, K A; Harris, P; Kim, Y; Klute, M; Lee, Y-J; Li, W; Loizides, C; Luckey, P D; Ma, T; Nahn, S; Paus, C; Ralph, D; Roland, C; Roland, G; Rudolph, M; Stephans, G S F; Stöckli, F; Sumorok, K; Sung, K; Wenger, E A; Xie, S; Yang, M; Yilmaz, Y; Yoon, A S; Zanetti, M; Cooper, S I; Cushman, P; Dahmes, B; De Benedetti, A; Dudero, P R; Franzoni, G; Haupt, J; Klapoetke, K; Kubota, Y; Mans, J; Rekovic, V; Rusack, R; Sasseville, M; Singovsky, A; Cremaldi, L M; Godang, R; Kroeger, R; Perera, L; Rahmat, R; Sanders, D A; Summers, D; Bloom, K; Bose, S; Butt, J; Claes, D R; Dominguez, A; Eads, M; Keller, J; Kelly, T; Kravchenko, I; Lazo-Flores, J; Malbouisson, H; Malik, S; Snow, G R; Baur, U; Godshalk, A; Iashvili, I; Jain, S; Kharchilava, A; Kumar, A; Shipkowski, S P; Smith, K; Alverson, G; Barberis, E; Baumgartel, D; Boeriu, O; Chasco, M; Reucroft, S; Swain, J; Trocino, D; Wood, D; Zhang, J; Anastassov, A; Kubik, A; Odell, N; Ofierzynski, R A; Pollack, B; Pozdnyakov, A; Schmitt, M; Stoynev, S; Velasco, M; Won, S; Antonelli, L; Berry, D; Hildreth, M; Jessop, C; Karmgard, D J; Kolb, J; Kolberg, T; Lannon, K; Luo, W; Lynch, S; Marinelli, N; Morse, D M; Pearson, T; Ruchti, R; Slaunwhite, J; Valls, N; Wayne, M; Ziegler, J; Bylsma, B; Durkin, L S; Gu, J; Hill, C; Killewald, P; Kotov, K; Ling, T Y; Rodenburg, M; Williams, G; Adam, N; Berry, E; Elmer, P; Gerbaudo, D; Halyo, V; Hebda, P; Hunt, A; Jones, J; Laird, E; Pegna, D Lopes; Marlow, D; Medvedeva, T; Mooney, M; Olsen, J; Piroué, P; Quan, X; Saka, H; Stickland, D; Tully, C; Werner, J S; Zuranski, A; Acosta, J G; Huang, X T; Lopez, A; Mendez, H; Oliveros, S; Vargas, J E Ramirez; Zatserklyaniy, A; Alagoz, E; Barnes, V E; Bolla, G; Borrello, L; Bortoletto, D; Everett, A; Garfinkel, A F; Gutay, L; Hu, Z; Jones, M; Koybasi, O; Kress, M; Laasanen, A T; Leonardo, N; Liu, C; Maroussov, V; Merkel, P; Miller, D H; Neumeister, N; Shipsey, I; Silvers, D; Svyatkovskiy, A; Yoo, H D; Zablocki, J; Zheng, Y; Jindal, P; Parashar, N; Boulahouache, C; Cuplov, V; Ecklund, K M; Geurts, F J M; Padley, B P; Redjimi, R; Roberts, J; Zabel, J; Betchart, B; Bodek, A; Chung, Y S; Covarelli, R; de Barbaro, P; Demina, R; Eshaq, Y; Flacher, H; Garcia-Bellido, A; Goldenzweig, P; Gotra, Y; Han, J; Harel, A; Miner, D C; Orbaker, D; Petrillo, G; Vishnevskiy, D; Zielinski, M; Bhatti, A; Ciesielski, R; Demortier, L; Goulianos, K; Lungu, G; Malik, S; Mesropian, C; Yan, M; Atramentov, O; Barker, A; Duggan, D; Gershtein, Y; Gray, R; Halkiadakis, E; Hidas, D; Hits, D; Lath, A; Panwalkar, S; Patel, R; Richards, A; Rose, K; Schnetzer, S; Somalwar, S; Stone, R; Thomas, S; Cerizza, G; Hollingsworth, M; Spanier, S; Yang, Z C; York, A; Eusebi, R; Gilmore, J; Gurrola, A; Kamon, T; Khotilovich, V; Montalvo, R; Osipenkov, I; Pakhotin, Y; Pivarski, J; Safonov, A; Sengupta, S; Tatarinov, A; Toback, D; Weinberger, M; Akchurin, N; Bardak, C; Damgov, J; Jeong, C; Kovitanggoon, K; Lee, S W; Mane, P; Roh, Y; Sill, A; Volobouev, I; Wigmans, R; Yazgan, E; Appelt, E; Brownson, E; Engh, D; Florez, C; Gabella, W; Issah, M; Johns, W; Kurt, P; Maguire, C; Melo, A; Sheldon, P; Snook, B; Tuo, S; Velkovska, J; Arenton, M W; Balazs, M; Boutle, S; Cox, B; Francis, B; Hirosky, R; Ledovskoy, A; Lin, C; Neu, C; Yohay, R; Gollapinni, S; Harr, R; Karchin, P E; Lamichhane, P; Mattson, M; Milstène, C; Sakharov, A; Anderson, M; Bachtis, M; Bellinger, J N; Carlsmith, D; Dasu, S; Efron, J; Flood, K; Gray, L; Grogg, K S; Grothe, M; Hall-Wilton, R; Herndon, M; Klabbers, P; Klukas, J; Lanaro, A; Lazaridis, C; Leonard, J; Loveless, R; Mohapatra, A; Palmonari, F; Reeder, D; Ross, I; Savin, A; Smith, W H; Swanson, J; Weinberg, M

    2011-09-23

    The inclusive jet cross section is measured in pp collisions with a center-of-mass energy of 7 TeV at the Large Hadron Collider using the CMS experiment. The data sample corresponds to an integrated luminosity of 34 pb(-1). The measurement is made for jet transverse momenta in the range 18-1100 GeV and for absolute values of rapidity less than 3. The measured cross section extends to the highest values of jet p(T) ever observed and, within the experimental and theoretical uncertainties, is generally in agreement with next-to-leading-order perturbative QCD predictions.

  6. Measurement of the Inclusive Jet Cross Section in pp Collisions at sqrt[s]=7 TeV

    SciTech Connect

    Chatrchyan, Serguei; et al.

    2011-09-01

    The inclusive jet cross section is measured in pp collisions with a center-of-mass energy of 7 TeV at the LHC using the CMS experiment. The data sample corresponds to an integrated luminosity of 34 inverse picobarns. The measurement is made for jet transverse momenta in the range 18-1100 GeV and for absolute values of rapidity less than 3. The measured cross section extends to the highest values of jet pT ever observed and, within the experimental and theoretical uncertainties, is generally in agreement with next-to-leading-order perturbative QCD predictions.

  7. Measurement of the inclusive jet cross section in pp collisions at √s = 7 TeV.

    PubMed

    Chatrchyan, S; Khachatryan, V; Sirunyan, A M; Tumasyan, A; Adam, W; Bergauer, T; Dragicevic, M; Erö, J; Fabjan, C; Friedl, M; Frühwirth, R; Ghete, V M; Hammer, J; Hänsel, S; Hoch, M; Hörmann, N; Hrubec, J; Jeitler, M; Kiesenhofer, W; Krammer, M; Liko, D; Mikulec, I; Pernicka, M; Rohringer, H; Schöfbeck, R; Strauss, J; Taurok, A; Teischinger, F; Wagner, P; Waltenberger, W; Walzel, G; Widl, E; Wulz, C-E; Mossolov, V; Shumeiko, N; Gonzalez, J Suarez; Bansal, S; Benucci, L; De Wolf, E A; Janssen, X; Maes, J; Maes, T; Mucibello, L; Ochesanu, S; Roland, B; Rougny, R; Selvaggi, M; Van Haevermaet, H; Van Mechelen, P; Van Remortel, N; Blekman, F; Blyweert, S; D'Hondt, J; Devroede, O; Suarez, R Gonzalez; Kalogeropoulos, A; Maes, M; Van Doninck, W; Van Mulders, P; Van Onsem, G P; Villella, I; Charaf, O; Clerbaux, B; De Lentdecker, G; Dero, V; Gay, A P R; Hammad, G H; Hreus, T; Marage, P E; Thomas, L; Vander Velde, C; Vanlaer, P; Adler, V; Cimmino, A; Costantini, S; Grunewald, M; Klein, B; Lellouch, J; Marinov, A; Mccartin, J; Ryckbosch, D; Thyssen, F; Tytgat, M; Vanelderen, L; Verwilligen, P; Walsh, S; Zaganidis, N; Basegmez, S; Bruno, G; Caudron, J; Ceard, L; Gil, E Cortina; De Favereau De Jeneret, J; Delaere, C; Favart, D; Giammanco, A; Grégoire, G; Hollar, J; Lemaitre, V; Liao, J; Militaru, O; Ovyn, S; Pagano, D; Pin, A; Piotrzkowski, K; Schul, N; Beliy, N; Caebergs, T; Daubie, E; Alves, G A; De Jesus Damiao, D; Pol, M E; Souza, M H G; Carvalho, W; Da Costa, E M; De Oliveira Martins, C; Fonseca De Souza, S; Mundim, L; Nogima, H; Oguri, V; Prado Da Silva, W L; Santoro, A; Silva Do Amaral, S M; Sznajder, A; Bernardes, C A; Dias, F A; Tomei, T R Fernandez Perez; Gregores, E M; Lagana, C; Marinho, F; Mercadante, P G; Novaes, S F; Padula, Sandra S; Darmenov, N; Dimitrov, L; Genchev, V; Iaydjiev, P; Piperov, S; Rodozov, M; Stoykova, S; Sultanov, G; Tcholakov, V; Trayanov, R; Vankov, I; Dimitrov, A; Hadjiiska, R; Karadzhinova, A; Kozhuharov, V; Litov, L; Mateev, M; Pavlov, B; Petkov, P; Bian, J G; Chen, G M; Chen, H S; Jiang, C H; Liang, D; Liang, S; Meng, X; Tao, J; Wang, J; Wang, J; Wang, X; Wang, Z; Xiao, H; Xu, M; Zang, J; Zhang, Z; Ban, Y; Guo, S; Guo, Y; Li, W; Mao, Y; Qian, S J; Teng, H; Zhang, L; Zhu, B; Zou, W; Cabrera, A; Moreno, B Gomez; Rios, A A Ocampo; Oliveros, A F Osorio; Sanabria, J C; Godinovic, N; Lelas, D; Lelas, K; Plestina, R; Polic, D; Puljak, I; Antunovic, Z; Dzelalija, M; Brigljevic, V; Duric, S; Kadija, K; Morovic, S; Attikis, A; Galanti, M; Mousa, J; Nicolaou, C; Ptochos, F; Razis, P A; Finger, M; Finger, M; Assran, Y; Khalil, S; Mahmoud, M A; Hektor, A; Kadastik, M; Müntel, M; Raidal, M; Rebane, L; Azzolini, V; Eerola, P; Fedi, G; Czellar, S; Härkönen, J; Heikkinen, A; Karimäki, V; Kinnunen, R; Kortelainen, M J; Lampén, T; Lassila-Perini, K; Lehti, S; Lindén, T; Luukka, P; Mäenpää, T; Tuominen, E; Tuominiemi, J; Tuovinen, E; Ungaro, D; Wendland, L; Banzuzi, K; Korpela, A; Tuuva, T; Sillou, D; Besancon, M; Choudhury, S; Dejardin, M; Denegri, D; Fabbro, B; Faure, J L; Ferri, F; Ganjour, S; Gentit, F X; Givernaud, A; Gras, P; Hamel de Monchenault, G; Jarry, P; Locci, E; Malcles, J; Marionneau, M; Millischer, L; Rander, J; Rosowsky, A; Shreyber, I; Titov, M; Verrecchia, P; Baffioni, S; Beaudette, F; Benhabib, L; Bianchini, L; Bluj, M; Broutin, C; Busson, P; Charlot, C; Dahms, T; Dobrzynski, L; Elgammal, S; Granier de Cassagnac, R; Haguenauer, M; Miné, P; Mironov, C; Ochando, C; Paganini, P; Sabes, D; Salerno, R; Sirois, Y; Thiebaux, C; Wyslouch, B; Zabi, A; Agram, J-L; Andrea, J; Bloch, D; Bodin, D; Brom, J-M; Cardaci, M; Chabert, E C; Collard, C; Conte, E; Drouhin, F; Ferro, C; Fontaine, J-C; Gelé, D; Goerlach, U; Greder, S; Juillot, P; Karim, M; Le Bihan, A-C; Mikami, Y; Van Hove, P; Fassi, F; Mercier, D; Baty, C; Beauceron, S; Beaupere, N; Bedjidian, M; Bondu, O; Boudoul, G; Boumediene, D; Brun, H; Chasserat, J; Chierici, R; Contardo, D; Depasse, P; El Mamouni, H; Fay, J; Gascon, S; Ille, B; Kurca, T; Le Grand, T; Lethuillier, M; Mirabito, L; Perries, S; Sordini, V; Tosi, S; Tschudi, Y; Verdier, P; Lomidze, D; Anagnostou, G; Edelhoff, M; Feld, L; Heracleous, N; Hindrichs, O; Jussen, R; Klein, K; Merz, J; Mohr, N; Ostapchuk, A; Perieanu, A; Raupach, F; Sammet, J; Schael, S; Sprenger, D; Weber, H; Weber, M; Wittmer, B; Ata, M; Bender, W; Dietz-Laursonn, E; Erdmann, M; Frangenheim, J; Hebbeker, T; Hinzmann, A; Hoepfner, K; Klimkovich, T; Klingebiel, D; Kreuzer, P; Lanske, D; Magass, C; Merschmeyer, M; Meyer, A; Papacz, P; Pieta, H; Reithler, H; Schmitz, S A; Sonnenschein, L; Steggemann, J; Teyssier, D; Bontenackels, M; Davids, M; Duda, M; Flügge, G; Geenen, H; Giffels, M; Haj Ahmad, W; Heydhausen, D; Kress, T; Kuessel, Y; Linn, A; Nowack, A; Perchalla, L; Pooth, O; Rennefeld, J; Sauerland, P; Stahl, A; Thomas, M; Tornier, D; Zoeller, M H; Martin, M Aldaya

    2011-09-23

    The inclusive jet cross section is measured in pp collisions with a center-of-mass energy of 7 TeV at the Large Hadron Collider using the CMS experiment. The data sample corresponds to an integrated luminosity of 34 pb(-1). The measurement is made for jet transverse momenta in the range 18-1100 GeV and for absolute values of rapidity less than 3. The measured cross section extends to the highest values of jet p(T) ever observed and, within the experimental and theoretical uncertainties, is generally in agreement with next-to-leading-order perturbative QCD predictions. PMID:22026843

  8. Theoretical Formalism To Estimate the Positron Scattering Cross Section.

    PubMed

    Singh, Suvam; Dutta, Sangita; Naghma, Rahla; Antony, Bobby

    2016-07-21

    A theoretical formalism is introduced in this article to calculate the total cross sections for positron scattering. This method incorporates positron-target interaction in the spherical complex optical potential formalism. The study of positron collision has been quite subtle until now. However, recently, it has emerged as an interesting area due to its role in atomic and molecular structure physics, astrophysics, and medicine. With the present method, the total cross sections for simple atoms C, N, and O and their diatomic molecules C2, N2, and O2 are obtained and compared with existing data. The total cross section obtained in the present work gives a more consistent shape and magnitude than existing theories. The characteristic dip below 10 eV is identified due to the positronium formation. The deviation of the present cross section with measurements at energies below 10 eV is attributed to the neglect of forward angle-discrimination effects in experiments, the inefficiency of additivity rule for molecules, empirical treatment of positronium formation, and the neglect of annihilation reactions. In spite of these deficiencies, the present results show consistent behavior and reasonable agreement with previous data, wherever available. Besides, this is the first computational model to report positron scattering cross sections over the energy range from 1 to 5000 eV. PMID:27333337

  9. Simulation of multistatic and backscattering cross sections for airborne radar

    NASA Astrophysics Data System (ADS)

    Biggs, Albert W.

    1986-07-01

    In order to determine susceptibilities of airborne radar to electronic countermeasures and electronic counter-countermeasures simulations of multistatic and backscattering cross sections were developed as digital modules in the form of algorithms. Cross section algorithms are described for prolate (cigar shape) and oblate (disk shape) spheroids. Backscattering cross section algorithms are also described for different categories of terrain. Backscattering cross section computer programs were written for terrain categorized as vegetation, sea ice, glacial ice, geological (rocks, sand, hills, etc.), oceans, man-made structures, and water bodies. PROGRAM SIGTERRA is a file for backscattering cross section modules of terrain (TERRA) such as vegetation (AGCROP), oceans (OCEAN), Arctic sea ice (SEAICE), glacial snow (GLASNO), geological structures (GEOL), man-made structures (MAMMAD), or water bodies (WATER). AGCROP describes agricultural crops, trees or forests, prairies or grassland, and shrubs or bush cover. OCEAN has the SLAR or SAR looking downwind, upwind, and crosswind at the ocean surface. SEAICE looks at winter ice and old or polar ice. GLASNO is divided into a glacial ice and snow or snowfields. MANMAD includes buildings, houses, roads, railroad tracks, airfields and hangars, telephone and power lines, barges, trucks, trains, and automobiles. WATER has lakes, rivers, canals, and swamps. PROGRAM SIGAIR is a similar file for airborne targets such as prolate and oblate spheroids.

  10. Cross Sections and Transport Properties of BR- Ions in AR

    NASA Astrophysics Data System (ADS)

    Jovanovic, Jasmina; Stojanovic, Vladimir; Raspopovic, Zoran; Petrovic, Zoran

    2014-10-01

    We have used a combination of a simple semi-analytic theory - Momentum Transfer Theory (MTT) and exact Monte Carlo (MC) simulations to develop Br- in Ar momentum transfer cross section based on the available data for reduced mobility at the temperature T = 300 K over the range 10 Td <= E / N <= 300 Td. At very low energies, we have extrapolated obtained cross sections towards Langevin's cross section. Also, we have extrapolated data to somewhat higher energies based on behavior of similar ions in similar gases and by the addition of the total detachment cross section that was used from the threshold around 7.7 eV. Relatively complete set was derived which can be used in modeling of plasmas by both hybrid, particle in cell (PIC) and fluid codes. A good agreement between calculated and measured ion mobilities and longitudinal diffusion coefficients is an independent proof of the validity of the cross sections that were derived for the negative ion mobility data. In addition to transport coefficients we have also calculated the net rate coefficients of elastic scattering and detachment. Author acknowledge Ministry of Education, Science and Technology, Proj. Nos. 171037 and 410011.

  11. Electromagnetic Dissociation Cross Sections using Weisskopf-Ewing Theory

    NASA Technical Reports Server (NTRS)

    Adamczyk, Anne M.; Norbury, John W.

    2011-01-01

    It is important that accurate estimates of crew exposure to radiation are obtained for future long-term space missions. Presently, several space radiation transport codes exist to predict the radiation environment, all of which take as input particle interaction cross sections that describe the nuclear interactions between the particles and the shielding material. The space radiation transport code HZETRN uses the nuclear fragmentation model NUCFRG2 to calculate Electromagnetic Dissociation (EMD) cross sections. Currently, NUCFRG2 employs energy independent branching ratios to calculate these cross sections. Using Weisskopf-Ewing (WE) theory to calculate branching ratios, however, is more advantageous than the method currently employed in NUCFRG2. The WE theory can calculate not only neutron and proton emission, as in the energy independent branching ratio formalism used in NUCFRG2, but also deuteron, triton, helion, and alpha particle emission. These particles can contribute significantly to total exposure estimates. In this work, photonuclear cross sections are calculated using WE theory and the energy independent branching ratios used in NUCFRG2 and then compared to experimental data. It is found that the WE theory gives comparable, but mainly better agreement with data than the energy independent branching ratio. Furthermore, EMD cross sections for single neutron, proton, and alpha particle removal are calculated using WE theory and an energy independent branching ratio used in NUCFRG2 and compared to experimental data.

  12. Cross-section fluctuations in chaotic scattering systems

    NASA Astrophysics Data System (ADS)

    Ericson, Torleif E. O.; Dietz, Barbara; Richter, Achim

    2016-10-01

    Exact analytical expressions for the cross-section correlation functions of chaotic scattering systems have hitherto been derived only under special conditions. The objective of the present article is to provide expressions that are applicable beyond these restrictions. The derivation is based on a statistical model of Breit-Wigner type for chaotic scattering amplitudes which has been shown to describe the exact analytical results for the scattering (S )-matrix correlation functions accurately. Our results are given in the energy and in the time representations and apply in the whole range from isolated to overlapping resonances. The S -matrix contributions to the cross-section correlations are obtained in terms of explicit irreducible and reducible correlation functions. Consequently, the model can be used for a detailed exploration of the key features of the cross-section correlations and the underlying physical mechanisms. In the region of isolated resonances, the cross-section correlations contain a dominant contribution from the self-correlation term. For narrow states the self-correlations originate predominantly from widely spaced states with exceptionally large partial width. In the asymptotic region of well-overlapping resonances, the cross-section autocorrelation functions are given in terms of the S -matrix autocorrelation functions. For inelastic correlations, in particular, the Ericson fluctuations rapidly dominate in that region. Agreement with known analytical and experimental results is excellent.

  13. Electron-impact ionization cross section of rubidium

    NASA Astrophysics Data System (ADS)

    Kim, Yong-Ki; Migdałek, Jacek; Siegel, Wojciech; Bieroń, Jacek

    1998-01-01

    A theoretical model for electron-impact ionization cross section has been applied to Rb and the theoretical cross section (from the threshold to 1 keV in incident energy) is in good agreement with the recent experimental data obtained using Rb atoms trapped in a magneto-optical trap. The theoretical model, called the binary-encounter-dipole (BED) model, combines a modified Mott cross section with the high-energy behavior of Born cross sections. To obtain the continuum dipole oscillator strength df/dE of the 5s electron required in the BED model, we used Dirac-Fock continuum wave functions with a core polarization potential that reproduced the known position of the Cooper minimum in the photoionization cross section. For inner-shell ionization, we used a simpler version of df/dE, which retained the hydrogenic shape. The contributions of the 4p-->4d, 5s, and 5p autoionizing excitations were estimated using the plane-wave Born approximation. As a by-product, we also present the dipole oscillator strengths for the 5s-->np1/2 and 5s-->np3/2 transitions for high principal quantum numbers n near the ionization threshold obtained from the Dirac-Fock wave functions with the same core polarization potential as that used for the continuum wave functions.

  14. Experience With the SCALE Criticality Safety Cross Section Libraries

    SciTech Connect

    Bowman, S.M.

    2000-08-21

    This report provides detailed information on the SCALE criticality safety cross-section libraries. Areas covered include the origins of the libraries, the data on which they are based, how they were generated, past experience and validations, and performance comparisons with measured critical experiments and numerical benchmarks. The performance of the SCALE criticality safety cross-section libraries on various types of fissile systems are examined in detail. Most of the performance areas are demonstrated by examining the performance of the libraries vs critical experiments to show general trends and weaknesses. In areas where directly applicable critical experiments do not exist, performance is examined based on the general knowledge of the strengths and weaknesses of the cross sections. In this case, the experience in the use of the cross sections and comparisons with the results of other libraries on the same systems are relied on for establishing acceptability of application of a particular SCALE library to a particular fissile system. This report should aid in establishing when a SCALE cross-section library would be expected to perform acceptably and where there are known or suspected deficiencies that would cause the calculations to be less reliable. To determine the acceptability of a library for a particular application, the calculational bias of the library should be established by directly applicable critical experiments.

  15. Coincidence measurement of the fully differential cross section for atomic-field bremsstrahlung

    NASA Technical Reports Server (NTRS)

    Faulk, J. D.; Quarles, C. A.

    1974-01-01

    A coincidence measurement was made of the absolute cross section for electron-atomic-field bremsstrahlung, differential in photon energy, photon-emission angle, and electron scattering angle. The incident electron energy was 140 keV and the scattering materials were thin films of aluminum and gold. The data are compared to the theoretical calculations of Elwert and Haug and of Bethe and Heitler. Both theories give generally satisfactory agreement for aluminum. The Elwert-Haug theory is somewhat more accurate for gold.

  16. Lactiferous vessel detection from microscopic cross-sectional images

    NASA Astrophysics Data System (ADS)

    Jariyawatthananon, Jirapath; Cooharojananone, Nagul; Lipikorn, Rajalida

    2014-04-01

    This paper presents the methods to detect and segment lactiferous vessels or rubber latex vessels from gray scale microscopic cross-sectional images using polynomial curve-fitting with maximum and minimum stationary points. Polynomial curve-fitting is used to detect the location of lactiferous vessels from an image of a non-dyed cross-sectional slice which was taken by a digital camera through microscope lens. The lactiferous vessels are then segmented from an image using maximum and minimum stationary points with morphological closing operation. Two species of rubber trees of age between one to two years old are sampled namely, RRIM600 and RRIT251. Two data sets contain 30 microscopic cross-sectional images of one-year old rubber tree's stems from each species are used in the experiments and the results reveal that most of the lactiferous vessel areas can be segmented correctly.

  17. Inversion of rotationally inelastic differential cross sections under sudden conditions

    NASA Astrophysics Data System (ADS)

    Schinke, Reinhard

    1980-12-01

    An inversion method for rotationally inelastic atom-diatom differential cross sections based on the infinite-order-sudden (IOS) approximation is presented. It consists of two separate steps: (1) The scattering phase shift, which is a function of the partial wave parameter l and the orientation angle γ, is determined by least-squares fitting of the reference cross sections. (2) For fixed orientation γ the R dependence of the interaction potential in obtained from the l dependence of the phase shift using the Firsov technique. This method is applicable in the so-called strong coupling case when rotational rainbow features are dominant and yields information about the anisotropy of the potential surface in the repulsive region. Because of the centrifugal sudden condition, scattering systems with deep potential wells cannot be treated by the present method. Test calculations are performed using theoretical IOS cross sections obtained from a realistic He-Na2 surface as reference data.

  18. 63Ni (n ,γ ) cross sections measured with DANCE

    NASA Astrophysics Data System (ADS)

    Weigand, M.; Bredeweg, T. A.; Couture, A.; Göbel, K.; Heftrich, T.; Jandel, M.; Käppeler, F.; Lederer, C.; Kivel, N.; Korschinek, G.; Krtička, M.; O'Donnell, J. M.; Ostermöller, J.; Plag, R.; Reifarth, R.; Schumann, D.; Ullmann, J. L.; Wallner, A.

    2015-10-01

    The neutron capture cross section of the s -process branch nucleus 63Ni affects the abundances of other nuclei in its region, especially 63Cu and 64Zn. In order to determine the energy-dependent neutron capture cross section in the astrophysical energy region, an experiment at the Los Alamos National Laboratory has been performed using the calorimetric 4 π BaF2 array DANCE. The (n ,γ ) cross section of 63Ni has been determined relative to the well-known 197Au standard with uncertainties below 15%. Various 63Ni resonances have been identified based on the Q value. Furthermore, the s -process sensitivity of the new values was analyzed with the new network calculation tool NETZ.

  19. High Energy Measurement of the Deuteron Photodisintegration Differential Cross Section

    SciTech Connect

    Elaine Schulte

    2002-05-01

    New measurements of the high energy deuteron photodisintegration differential cross section were made at the Thomas Jefferson National Accelerator Facility in Newport News, Virginia. Two experiments were performed. Experiment E96-003 was performed in experimental Hall C. The measurements were designed to extend the highest energy differential cross section values to 5.5 GeV incident photon energy at forward angles. This builds upon previous high energy measurements in which scaling consistent with the pQCD constituent counting rules was observed at 90 degrees and 70 degrees in the center of mass. From the new measurements, a threshold for the onset of constituent counting rule scaling seems present at transverse momentum approximately 1.3 GeV/c. The second experiment, E99-008, was performed in experimental Hall A. The measurements were designed to explore the angular distribution of the differential cross section at constant energy. The measurements were made symmetric about 90 degrees

  20. Double-differential heavy-ion production cross sections.

    PubMed

    Miller, T M; Townsend, L W

    2004-01-01

    Current computational tools used for space or accelerator shielding studies transport energetic heavy ions either using a one-dimensional straight-ahead approximation or by dissociating the nuclei into protons and neutrons and then performing neutron and proton transport using Monte Carlo techniques. Although the heavy secondary particles generally travel close to the beam direction, a proper treatment of the light ions produced in these reactions requires that double-differential cross sections should be utilised. Unfortunately, no fundamental nuclear model capable of serving as an event generator to provide these cross sections for all ions and energies of interest exists currently. Herein, we present a model for producing double-differential heavy-ion production cross sections that uses heavy-ion fragmentation yields produced by the NUCFRG2 fragmentation code coupled with a model of energy degradation in nucleus-nucleus collisions and systematics of momentum distributions to provide energy and angular dependences of the heavy-ion production.

  1. Dosimetry and cross section measurements at RTNS II

    SciTech Connect

    Greenwood, L.R.; Kneff, D.W.

    1987-01-01

    Numerous measurements have been conducted at TRNS-II in order to map the neutron field for materials irradiations, to measure activation cross sections, and to measure helium production cross sections. Experiments of up to two weeks duration irradiated large numbers of activation dosimetry and helium samples both close to the source and throughout the target room. Many other samples have been irradiated in piggy-back positions over periods lasting many months. All of these experiments fall into four main classes, namely, fluence-mapping, activation dosimetry, the production of long-lived isotopes, and helium generation measurements. Radiometric dosimetry and activation cross section measurements were performed at Argonne National Laboratory; helium production was measured at Rockwell International Corporation. This paper briefly summarizes the principal results of our measurements at RTNS-II; references are given for more detailed publications. 14 refs., 4 figs.

  2. Cross section versus time delay and trapping probability

    NASA Astrophysics Data System (ADS)

    Luna-Acosta, G. A.; Fernández-Marín, A. A.; Méndez-Bermúdez, J. A.; Poli, Charles

    2016-07-01

    We study the behavior of the s-wave partial cross section σ (k), the Wigner-Smith time delay τ (k), and the trapping probability P (k) as function of the wave number k. The s-wave central square well is used for concreteness, simplicity, and to elucidate the controversy whether it shows true resonances. It is shown that, except for very sharp structures, the resonance part of the cross section, the trapping probability, and the time delay, reach their local maxima at different values of k. We show numerically that τ (k) > 0 at its local maxima, occurring just before the resonant part of the cross section reaches its local maxima. These results are discussed in the light of the standard definition of resonance.

  3. Inelastic cross sections for positron scattering from atomic hydrogen

    SciTech Connect

    Weber, M.; Hofmann, A.; Raith, W.; Sperber, W.; Jacobsen, F.; Lynn, K.G.

    1994-12-31

    Positronium formation (Ps) cross sections for positrons impinging on atomic hydrogen were measured in the impact energy range from 13eV to 255eV at the High Intensity Positron (HIP) beam at Brookhaven National Laboratory (BNL). The Ps-formation cross section was found to rise rapidly from the threshold at 6.8eV to a maximum value of (2.98 {plus_minus} 0.18) {times} 10{sup {minus}16} cm{sup 2} for {approx} 15eV positrons. By 75eV it drops below the detection limit of 0.17 {times} 10{sup {minus}16} cm{sup 2} which is the present level of statistical uncertainty. The experiment was modified to enable the measurement of doubly differential scattering cross sections.

  4. Cross-Sectional Transport Imaging in a Multijunction Solar Cell

    SciTech Connect

    Haegel, Nancy M.; Ke, Chi-Wen; Taha, Hesham; Guthrey, Harvey; Fetzer, C. M.; King, Richard

    2015-06-14

    Combining highly localized electron-beam excitation at a point with the spatial resolution capability of optical near-field imaging, we have imaged carrier transport in a cross-sectioned multijunction (GaInP/GaInAs/Ge) solar cell. We image energy transport associated with carrier diffusion throughout the full width of the middle (GaInAs) cell and luminescent coupling from point excitation in the top cell GaInP to the middle cell. Supporting cathodoluminescence and near-field photoluminescence measurements demonstrate excitation-dependent Fermi level splitting effects that influence cross-sectioned spectroscopy results as well as transport limitations on the spatial resolution of cross-sectional measurements.

  5. Pion Total Cross Section in Nucleon - Nucleon Collisions

    NASA Technical Reports Server (NTRS)

    Norbury, John W.

    2009-01-01

    Total cross section parameterizations for neutral and charged pion production in nucleon - nucleon collisions are compared to experimental data over the projectile momentum range from threshold to 300 GeV. Both proton - proton and proton - neutron reactions are considered. Overall excellent agreement between parameterizations and experiment is found, except for notable disagreements near threshold. In addition, the hypothesis that the neutral pion production cross section can be obtained from the average charged pion cross section is checked. The theoretical formulas presented in the paper obey this hypothesis for projectile momenta below 500 GeV. The results presented provide a test of engineering tools used to calculate the pion component of space radiation.

  6. Recent advances in modeling fission cross sections over intermediate structures

    SciTech Connect

    Bouland, Olivier; Lynn, J. Eric; Talou, Patrick

    2009-01-01

    More accurate fission cross section calculations in presence of underlying intermediate structure are strongly desired. This paper recalls the common approximations used below the fission threshold and quantifies their impact. In particular, an exact expanded R-matrix Monte Carlo calculation of the intermediate structure, deeply mixed with the fluctuations of the class-I and II decay amplitudes, is shown. This paper also insists on the microscopic structure of the level densities as a function of the nucleus deformation and show preliminary neutron induced fission cross section calculations for {sup 239}Pu and {sup 240}Pu using newly calculated combinatorial level densities. Comparisons with recent evaluated and measured fission cross sections are made.

  7. Oscillator strength of the peptide bond {pi}* resonances at all relevant x-ray absorption edges

    SciTech Connect

    Kummer, K.; Vyalikh, D. V.; Molodtsov, S. L.; Sivkov, V. N.; Nekipelov, S. V.; Maslyuk, V. V.; Mertig, I.; Blueher, A.; Mertig, M.; Bredow, T.

    2009-10-15

    Absolute x-ray absorption cross sections of a regular bacterial surface-layer protein deposited on a naturally oxidized silicon substrate were determined experimentally. Upon separation of the partial cross sections of the three relevant 1s absorption edges, the oscillator strengths of the 1s{yields}{pi}* excitations within the peptide-backbone unit were extracted. Comparison with results of first-principles calculations revealed their close correlation to the topology of {pi}{sub peptide}* orbitals of the peptide backbone.

  8. The UV absorption spectrum of the simplest Criegee intermediate CH2OO.

    PubMed

    Ting, Wei-Lun; Chen, Ying-Hsuan; Chao, Wen; Smith, Mica C; Lin, Jim Jr-Min

    2014-06-14

    SO2 scavenging and self-reaction of CH2OO were utilized for the decay of CH2OO to extract the absorption spectrum of CH2OO under bulk conditions. Absolute absorption cross sections of CH2OO at 308.4 and 351.8 nm were obtained from laser-depletion measurements in a jet-cooled molecular beam. The peak cross section is (1.23 ± 0.18) × 10(-17) cm(2) at 340 nm.

  9. Intermediate energy cross sections for electron-impact vibrational-excitation of pyrimidine

    SciTech Connect

    Jones, D. B.; Ellis-Gibbings, L.; García, G.; Nixon, K. L.; Lopes, M. C. A.; Brunger, M. J.

    2015-09-07

    We report differential cross sections (DCSs) and integral cross sections (ICSs) for electron-impact vibrational-excitation of pyrimidine, at incident electron energies in the range 15–50 eV. The scattered electron angular range for the DCS measurements was 15°–90°. The measurements at the DCS-level are the first to be reported for vibrational-excitation in pyrimidine via electron impact, while for the ICS we extend the results from the only previous condensed-phase study [P. L. Levesque, M. Michaud, and L. Sanche, J. Chem. Phys. 122, 094701 (2005)], for electron energies ⩽12 eV, to higher energies. Interestingly, the trend in the magnitude of the lower energy condensed-phase ICSs is much smaller when compared to the corresponding gas phase results. As there is no evidence for the existence of any shape-resonances, in the available pyrimidine total cross sections [Baek et al., Phys. Rev. A 88, 032702 (2013); Fuss et al., ibid. 88, 042702 (2013)], between 10 and 20 eV, this mismatch in absolute magnitude between the condensed-phase and gas-phase ICSs might be indicative for collective-behaviour effects in the condensed-phase results.

  10. Two-photon excitation cross section in light and intermediate atoms in frozen-core LS-coupling approximation

    NASA Technical Reports Server (NTRS)

    Omidvar, K.

    1980-01-01

    Using the method of explicit summation over the intermediate states two-photon absorption cross sections in light and intermediate atoms based on the simplistic frozen-core approximation and LS coupling have been formulated. Formulas for the cross section in terms of integrals over radial wave functions are given. Two selection rules, one exact and one approximate, valid within the stated approximations are derived. The formulas are applied to two-photon absorptions in nitrogen, oxygen, and chlorine. In evaluating the radial integrals, for low-lying levels, the Hartree-Fock wave functions, and for high-lying levels, hydrogenic wave functions obtained by the quantum-defect method have been used. A relationship between the cross section and the oscillator strengths is derived.

  11. Inclusive jet cross sections and jet shapes at CDF

    SciTech Connect

    Wainer, N.

    1991-09-01

    The inclusive jet cross section and jet shapes at {radical}s = 1.8 TeV have been measured by CDF at the Fermilab Tevatron Collider. results are compared to recent next-to-leading order QCD calculations, which predict variation of the cross section with cone size, as well as variation of the jet shape with energy. A lower limit on the parameter {Lambda}{sub c}, which characterize a contact interaction associated with quark sub-structure is determined to be 1400 GeV at the 95% confidence level. 3 refs., 4 figs.

  12. Light ray tracing through a leaf cross section

    NASA Technical Reports Server (NTRS)

    Kumar, R.; Silva, L. F.

    1973-01-01

    A light ray, incident at about 5 deg to the normal, is geometrically plotted through the drawing of the cross section of a soybean leaf using Fresnel's equations and Snell's law. The optical mediums of the leaf considered for ray tracing are: air, cell sap, chloroplast, and cell wall. The ray is also drawn through the same leaf cross section with cell wall and air as the only optical mediums. The values of the reflection and transmission found from the ray tracing tests agree closely with the experimental results obtained using a Beckman Dk-2A Spectroreflector.

  13. Light ray tracing through a leaf cross section

    NASA Technical Reports Server (NTRS)

    Kumar, R.; Silva, L.

    1973-01-01

    A light ray, incident at about 5 deg to the normal, is geometrically plotted through the drawing of the cross section of a soybean leaf using Fresnel's equations and Snell's law. The optical mediums of the leaf considered for ray tracing are air, cell sap, chloroplast, and cell wall. The above ray is also drawn through the same leaf cross section considering cell wall and air as the only optical mediums. The values of the reflection and transmission found from ray tracing agree closely with the experimental results obtained using a Beckman DK-2A spectroreflectometer.

  14. Uncertainty Quantification in Fission Cross Section Measurements at LANSCE

    SciTech Connect

    Tovesson, F.

    2015-01-15

    Neutron-induced fission cross sections have been measured for several isotopes of uranium and plutonium at the Los Alamos Neutron Science Center (LANSCE) over a wide range of incident neutron energies. The total uncertainties in these measurements are in the range 3–5% above 100 keV of incident neutron energy, which results from uncertainties in the target, neutron source, and detector system. The individual sources of uncertainties are assumed to be uncorrelated, however correlation in the cross section across neutron energy bins are considered. The quantification of the uncertainty contributions will be described here.

  15. Inclusive jet cross section measurement at D0

    SciTech Connect

    Voutilainen, M.; /Nebraska U. /Helsinki Inst. of Phys.

    2006-09-01

    We present a new preliminary measurement of the inclusive jet cross section in p{bar p} collisions based on a integrated luminosity of about 0.8 fb{sup -1}. The data were acquired using the D0 detector between 2002 and 2005. Jets are reconstructed using an iterative cone algorithm with radius R{sub cone} = 0.7. The inclusive jet cross section is presented as a function of transverse jet momentum and rapidity. Predictions from perturbative QCD in next-to-leading order, plus threshold corrections in 2-loop accuracy describe the shape in the transverse jet momentum.

  16. Improved Actinide Neutron Capture Cross Sections Using Accelerator Mass Spectrometry

    NASA Astrophysics Data System (ADS)

    Bauder, W.; Pardo, R. C.; Kondev, F. G.; Kondrashev, S.; Nair, C.; Nusair, O.; Palchan, T.; Scott, R.; Seweryniak, D.; Vondrasek, R.; Collon, P.; Paul, M.; Youinou, G.; Salvatores, M.; Palmotti, G.; Berg, J.; Maddock, T.; Imel, G.

    2014-09-01

    The MANTRA (Measurement of Actinide Neutron TRAnsmutations) project will improve energy-integrated neutron capture cross section data across the actinide region. These data are incorporated into nuclear reactor models and are an important piece in understanding Generation IV reactor designs. We will infer the capture cross sections by measuring isotopic ratios from actinide samples, irradiated in the Advanced Test Reactor at INL, with Accelerator Mass Spectrometry (AMS) at ATLAS (ANL). The superior sensitivity of AMS allows us to extract multiple cross sections from a single sample. In order to analyze the large number of samples needed for MANTRA and to meet the goal of extracting multiple cross sections per sample, we have made a number of modifications to the AMS setup at ATLAS. In particular, we are developing a technique to inject solid material into the ECR with laser ablation. With laser ablation, we can better control material injection and potentially increase efficiency in the ECR, thus creating less contamination in the source and reducing cross talk. I will present work on the laser ablation system and preliminary results from our AMS measurements. The MANTRA (Measurement of Actinide Neutron TRAnsmutations) project will improve energy-integrated neutron capture cross section data across the actinide region. These data are incorporated into nuclear reactor models and are an important piece in understanding Generation IV reactor designs. We will infer the capture cross sections by measuring isotopic ratios from actinide samples, irradiated in the Advanced Test Reactor at INL, with Accelerator Mass Spectrometry (AMS) at ATLAS (ANL). The superior sensitivity of AMS allows us to extract multiple cross sections from a single sample. In order to analyze the large number of samples needed for MANTRA and to meet the goal of extracting multiple cross sections per sample, we have made a number of modifications to the AMS setup at ATLAS. In particular, we are

  17. Uncertainty quantification in fission cross section measurements at LANSCE

    DOE PAGES

    Tovesson, F.

    2015-01-09

    Neutron-induced fission cross sections have been measured for several isotopes of uranium and plutonium at the Los Alamos Neutron Science Center (LANSCE) over a wide range of incident neutron energies. The total uncertainties in these measurements are in the range 3–5% above 100 keV of incident neutron energy, which results from uncertainties in the target, neutron source, and detector system. The individual sources of uncertainties are assumed to be uncorrelated, however correlation in the cross section across neutron energy bins are considered. The quantification of the uncertainty contributions will be described here.

  18. Inelastic cross sections from gamma-ray measurements

    SciTech Connect

    Nelson, Ronald Owen

    2010-12-06

    Measurements of gamma rays following neutron induced reactions have been studied with the Germanium Array for Neutron-induced Excitations (GEANIE) at the Los Alamos Neutron Science Center (LANSCE) for many years. Gamma-ray excitation functions and coincidence studies provide insight into nuclear reaction mechanisms as well as expanding our knowledge of energy levels and gamma-rays. Samples studied with Ge detectors at LANSCE range from Be to Pu. Fe, Cr and Ti have been considered for use as reference cross sections. An overview of the measurements and efforts to create a reliable neutron-induced gamma-ray reference cross section will be presented.

  19. Total cross section of electron scattering by fluorocarbon molecules

    NASA Astrophysics Data System (ADS)

    Yamada, T.; Ushiroda, S.; Kondo, Y.

    2008-12-01

    A compact linear electron transmission apparatus was used for the measurement of the total electron scattering cross section at 4-500 eV. Total cross sections of chlorofluorocarbon (CCl2F2), hydrochlorofluorocarbon (CHClF2), perfluoropropane (C3F8), perfluoro-n-pentane (C5F12), perfluoro-n-hexane (C6F14) and perfluoro-n-octane (C8F18) were obtained experimentally and compared with the values obtained from a theoretical calculation and semi-empirical model calculation.

  20. Evaluation of the /sup 238/U neutron total cross section

    SciTech Connect

    Smith, A.; Poenitz, W.P.; Howerton, R.J.

    1982-12-01

    Experimental energy-averaged neutron total cross sections of /sup 238/U were evaluated from 0.044 to 20.0 MeV using regorous numerical methods. The evaluated results are presented together with the associated uncertainties and correlation matrix. They indicate that this energy-averaged neutron total cross section is known to better than 1% over wide energy regions. There are somwewhat larger uncertainties at low energies (e.g., less than or equal to 0.2 MeV), near 8 MeV and above 15 MeV. The present evaluation is compard with values given in ENDF/B-V.