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Sample records for absolute photoabsorption cross

  1. Absolute vacuum ultraviolet photoabsorption cross section studies of atomic and molecular species: Techniques and observational data

    NASA Technical Reports Server (NTRS)

    Judge, D. L.; Wu, C. Y. R.

    1990-01-01

    Absorption of a high energy photon (greater than 6 eV) by an isolated molecule results in the formation of highly excited quasi-discrete or continuum states which evolve through a wide range of direct and indirect photochemical processes. These are: photoionization and autoionization, photodissociation and predissociation, and fluorescence. The ultimate goal is to understand the dynamics of the excitation and decay processes and to quantitatively measure the absolute partial cross sections for all processes which occur in photoabsorption. Typical experimental techniques and the status of observational results of particular interest to solar system observations are presented.

  2. Bibliography of photoabsorption cross-section data

    NASA Technical Reports Server (NTRS)

    Hudson, R. D.; Kieffer, L. J.

    1970-01-01

    This bibliography contains only references which report a measured or calculated photoabsorption cross section (relative or normalized) in regions of continuous absorption. The bibliography is current as of January 1, 1970.

  3. Photoabsorption cross section of OD at 115-180 nm

    NASA Technical Reports Server (NTRS)

    Nee, J. B.; Lee, L. C.

    1984-01-01

    The photoabsorption cross sections of OD in the 115-180 nm region were measured. The OD radicals were produced from a pulsed discharge in a mixture containing a trace of D2O in a few Torr of argon. Results are compared with the photoabsorption of OH previously measured.

  4. Photoabsorption cross section of acetylene in the EUV region

    NASA Technical Reports Server (NTRS)

    Wu, C. Y. R.; Judge, D. L.

    1985-01-01

    The measurement of the absolute photoabsorption cross sections of C2H2 in the 175-740 A region by means of a double ionization chamber is reported. The continuum background source is the synchrotron radiation emitted by the Wisconsin 240 MeV electron storage ring. It is found that the cross sections range from 2 to a maximum of 36 Mb. Two new Rydberg series are identified and the cross section data are applied in the analysis of various sum rules. From the rules, it is shown that the data of C2H2 in the 580-1088 A range may be too low, while the measured ionization transition moment may be too high.

  5. A program to obtain reliable photoabsorption cross sections

    SciTech Connect

    Del Grande, N.K.; Tirsell, K.G.

    1988-01-01

    A program to obtain reliable photoabsorption cross sections for a broad range of elements has been initiated at Lawrence Livermore National Laboratory. Using well-characterized samples, absolute measurements have been made with overall uncertainties of /+-/10% or less over energy ranges from about 50 eV to several keV, at several synchrotron radiation facilities. More than a dozen elements have been investigated and other measurements are being planned for elements beryllium (Z-4) through uranium (Z-92). Among the interesting phenomena observed are the resonances/enhancements which seem to accompany virtually every inner shell threshold. Specific examples discussed in this paper include carbon, nickel and uranium. Comparison with theory and existing data compilations/data bases indicate the need for substantial theoretical and compilation improvements. 24 refs., 6 figs.

  6. Considerations for the use of synchrotron radiation sources to measure sub-keV x-ray photoabsorption cross sections in transmission

    SciTech Connect

    Tirsell, K.G.; Del Grande, N.K.

    1988-02-01

    Sub-keV x-ray photoabsorption cross section measurements in transmission have been made using synchrotron radiation beam lines on the VUV storage ring at the National Synchrotron Light Source (NSLS) and on the SPEAR storage ring at Stanford. The experimental considerations associated with making absolute measurements are reviewed, along with techniques for resolving difficulties. Suggestions for future measurements are included.

  7. Absolute oscillator strengths for the valence and inner (P 2p,2s) shell photoabsorption, photoionization, and ionic photofragmentation of PF 3

    NASA Astrophysics Data System (ADS)

    Au, Jennifer W.; Brion, C. E.

    1997-08-01

    Absolute oscillator strengths (cross-sections) for the photoabsorption of phosphorus pentafluoride (PF 5) have been measured for the first time in the valence and phosphorus 2p discrete regions using high-resolution (0.0-0.1 eV fwhm), dipole ( e, e) spectroscopy. Long-range data (10-300 eV) have also been obtained at lower resolution (1 eV fwhm), from which the absolute oscillator strength scale has been determined using the valence-shell Thomas-Reiche-Kuhn sum-rule. The accuracy of the present measurement has been tested using the S(-2) sum rule normalization. Evaluation of the S(-2) sum using the presently reported absolute photoabsorption oscillator strength data gives a dipole polarizabilit for PF 5 in good agreement with the experimental value. The photoionization efficiencies, photoion branching ratios, and absolute partial oscillator strengths for molecular and dissociative photoionization have also been determined for PF 5 by dipole ( e, e+ion) coincidence spectroscopy from the first ionization threshold up to and above the phosphorus 2p edge.

  8. Photoionization and photoabsorption cross sections for the aluminum iso-nuclear sequence

    SciTech Connect

    Witthoeft, M.C.; García, J.; Kallman, T.R.; Palmeri, P.; Quinet, P.

    2013-01-15

    K-shell photoionization and photoabsorption cross sections are presented for Li-like to Na-like Al. The calculations are performed using the Breit–Pauli R-matrix method where the effects of radiation and Auger dampings are included. We provide electronic data files for the raw cross sections as well as those convolved with a Gaussian of width ΔE/E=10{sup −4}. In addition to total cross sections for photoabsorption and photoionization, partial cross sections are available for photoionization.

  9. Photofission and total photoabsorption cross sections in the energy range of shadowing effects

    SciTech Connect

    Deppman, A.; Silva, G.; Anefalos, S.; Hisamoto, F.H.; Duarte, S.B.; Tavares, O.A.P.

    2006-06-15

    The energy dependence of photofission cross section for heavy nuclei has recently been well described in terms of a Monte Carlo calculation at energies from the pion photoproduction threshold up to 1 GeV [see, for instance, A. Deppman et al., Phys. Rev. Lett. 87 (2001) 182701]. Recent experimental data from CLAS (CEBAF Large Angle Spectrometer) collaboration have extended the measured photofission cross section up to 3.5 GeV for actinide and preactinide nuclei. In this work we address the calculation of photoabsorption and photofission cross sections for actinide and preactinide nuclei above 1 GeV, a region where the shadowing effect plays an important role in the nuclear photoabsorption process.

  10. HIGH PRECISION K-SHELL PHOTOABSORPTION CROSS SECTIONS FOR ATOMIC OXYGEN: EXPERIMENT AND THEORY

    SciTech Connect

    McLaughlin, B. M.; Ballance, C. P.; Bowen, K. P.; Gardenghi, D. J.; Stolte, W. C. E-mail: ballance@physics.auburn.edu E-mail: dgardenghi@gmail.com

    2013-07-01

    Photoabsorption of atomic oxygen in the energy region below the 1s {sup -1} threshold in X-ray spectroscopy from Chandra and XMM-Newton is observed in a variety of X-ray binary spectra. Photoabsorption cross sections determined from an R-matrix method with pseudo-states and new, high precision measurements from the Advanced Light Source (ALS) are presented. High-resolution spectroscopy with E/{Delta}E Almost-Equal-To 4250 {+-} 400 was obtained for photon energies from 520 eV to 555 eV at an energy resolution of 124 {+-} 12 meV FWHM. K-shell photoabsorption cross section measurements were made with a re-analysis of previous experimental data on atomic oxygen at the ALS. Natural line widths {Gamma} are extracted for the 1s {sup -1}2s {sup 2}2p {sup 4}({sup 4} P)np {sup 3} P Degree-Sign and 1s {sup -1}2s {sup 2}2p {sup 4}({sup 2} P)np {sup 3} P Degree-Sign Rydberg resonances series and compared with theoretical predictions. Accurate cross sections and line widths are obtained for applications in X-ray astronomy. Excellent agreement between theory and the ALS measurements is shown which will have profound implications for the modeling of X-ray spectra and spectral diagnostics.

  11. K-Shell Photoabsorption Cross Sections for the Magnesium Isonuclear Sequence

    NASA Astrophysics Data System (ADS)

    Abdel-Naby, Shahin; Hasoglu, Fatih; Gorczyca, Thomas

    2011-05-01

    With the improved spectral resolution of launched X-ray telescopes, there is a demand for highly-accurate K-shell photoabsorption cross sections. Such data are needed for modeling astrophysical plasmas, interpreting the observed spectra from distant cosmic emitters, and determining the elemental abundances of the interstellar medium (ISM). Here we present new calculations for photoabsorption of the entire Mg isonuclear sequence using state-of-the-art R-matrix methods, including important spectator Auger broadening and inner-shell relaxation effects. Unlike our earlier work on carbon, oxygen, and neon ions, and the present work on multiply-ionized magnesium, the calculations for neutral Mg and singly-ionized Mg+ are complicated by additional M-shell occupancy, which leads to a larger R-matrix box and difficulties in implementing the quantum defect theoretical spectator Auger decay method for low-lying resonances. With the improved spectral resolution of launched X-ray telescopes, there is a demand for highly-accurate K-shell photoabsorption cross sections. Such data are needed for modeling astrophysical plasmas, interpreting the observed spectra from distant cosmic emitters, and determining the elemental abundances of the interstellar medium (ISM). Here we present new calculations for photoabsorption of the entire Mg isonuclear sequence using state-of-the-art R-matrix methods, including important spectator Auger broadening and inner-shell relaxation effects. Unlike our earlier work on carbon, oxygen, and neon ions, and the present work on multiply-ionized magnesium, the calculations for neutral Mg and singly-ionized Mg+ are complicated by additional M-shell occupancy, which leads to a larger R-matrix box and difficulties in implementing the quantum defect theoretical spectator Auger decay method for low-lying resonances. This work was funded in part by NASA's Astronomy Physics Research and Analysis (APRA) program.

  12. Photoabsorption cross sections of OH at 115-183 nm

    NASA Technical Reports Server (NTRS)

    Nee, J. B.; Lee, L. C.

    1984-01-01

    The absorption spectrum for OH was obtained in the 115-183 nm region. The OH radicals were produced by a pulse discharge of trace H2O in few torr of Ar. Absorption cross sections were obtained by calibration with absorption of the OH (X 2 Pi to A 2 Sigma +) transition. The features in the absorption spectrum are correlated with the excited states 1 2 Sigma -, D 2 Sigma -, 1 2 Delta, B 2 Sigma + and possibly others calculated by van Dishoeck, Langhoff, and Dalgarno. The measured cross sections are comparable with the calculated values.

  13. High-resolution, VUV (147-201 nm) photoabsorption cross sections for C2H2 at 195 and 295 K

    NASA Technical Reports Server (NTRS)

    Smith, Peter L.; Yoshino, Kouichi; Parkinson, W. H.; Ito, Kenji; Stark, Glenn

    1991-01-01

    Results of measurements of photoabsorption cross sections of acetylene at 195 and 295 K in the wavelength range of 147-201 nm are reported. Short-wavelength data are obtained at 0.002 nm intervals, but no structure was observed on that scale. Emission and absorption lines from contaminant species in xenon and hydrogen discharges are used to determine the correct wavelength scale for the data. The uncertainty in the relative wavelengths is estimated to be about 0.004 nm, whereas the absolute wavelength values are accurate to + or - 0.043 nm. No significant photodestruction of C2H2 was found during the measurements. Cross-section values determined at the beginning portions of the measurements are indistinguishable from the values determined at the ends, thus demonstrating that there was no loss of absorbers.

  14. Biexciton cascade emission reveals absolute absorption cross section of single semiconductor nanocrystals

    NASA Astrophysics Data System (ADS)

    Ihara, Toshiyuki

    2016-06-01

    The sequential two-photon emission process known as biexciton cascade emission is a characteristic phenomenon that occurs in photoexcited semiconductor nanocrystals (NCs). This process occurs when a biexciton state is created in the NCs; thus, the occurrence of the process is related to the photoabsorption properties of the NCs. This paper presents a simple equation that connects the photoabsorption of single NCs and the biexciton cascade emission. The equation is found to be independent of the quantum yields of photoluminescence (PL). With this equation and using an analysis of second-order photon correlation, the absolute absorption cross section σ of the single NCs can be evaluated, obtaining values on the order of 10-14c m2 . This analysis shows that ionization during PL blinking does not affect the validity of the relation, indicating that the evaluation of σ , based on the equation, is applicable for various NCs with unique structures.

  15. Absolute partial photoionization cross sections of ozone.

    SciTech Connect

    Berkowitz, J.; Chemistry

    2008-04-01

    Despite the current concerns about ozone, absolute partial photoionization cross sections for this molecule in the vacuum ultraviolet (valence) region have been unavailable. By eclectic re-evaluation of old/new data and plausible assumptions, such cross sections have been assembled to fill this void.

  16. Vacuum ultraviolet photoabsorption study of SO

    NASA Technical Reports Server (NTRS)

    Nee, J. B.; Lee, L. C.

    1986-01-01

    The photoabsorption of SO was investigated by producing the radicals from a pulsed discharge of a trace of SO2 in Ar. The photoabsorption cross section of SO in the 115-135 nm region was measured. A repulsive potential curve is constructed from the observed photoabsorption spectrum.

  17. UV photoabsorption cross sections of CO, N2, and SO2 for studies of the ISM and planetary atmospheres

    NASA Technical Reports Server (NTRS)

    Smith, Peter L.; Rufus, J.; Yoshino, K.; Parkinson, W. H.; Stark, Glenn; Pickering, Juliet C.; Thorne, A. P.

    2002-01-01

    We report high-resolution laboratory measurements of photoabsorption cross sections of CO, N2, and SO2 in the wavelength range 80 to 320 nm. The motivation is to provide the quantitative data that are needed to analyze observations of absorption by, and to model photochemical processes in, the interstellar medium and a number of planetary atmospheres. Because of the high resolution of the spectrometers used, we can minimize distortion of the spectrum that occurs when instrument widths are greater than the widths of spectral features being measured. In many cases, we can determine oscillator strengths of individual rotational lines - a unique feature of our work.

  18. Absolute photoionization cross sections of atomic oxygen

    NASA Technical Reports Server (NTRS)

    Samson, J. A. R.; Pareek, P. N.

    1985-01-01

    The absolute values of photoionization cross sections of atomic oxygen were measured from the ionization threshold to 120 A. An auto-ionizing resonance belonging to the 2S2P4(4P)3P(3Do, 3So) transition was observed at 479.43 A and another line at 389.97 A. The experimental data is in excellent agreement with rigorous close-coupling calculations that include electron correlations in both the initial and final states.

  19. Absolute photoionization cross sections of atomic oxygen

    NASA Technical Reports Server (NTRS)

    Samson, J. A. R.; Pareek, P. N.

    1982-01-01

    The absolute values of photoionization cross sections of atomic oxygen were measured from the ionization threshold to 120 A. An auto-ionizing resonance belonging to the 2S2P4(4P)3P(3Do, 3So) transition was observed at 479.43 A and another line at 389.97 A. The experimental data is in excellent agreement with rigorous close-coupling calculations that include electron correlations in both the initial and final states.

  20. K-edge photoabsorption cross section in metal oxides: Effect of vacancies in TiOx and VOx

    NASA Astrophysics Data System (ADS)

    Kutzler, F. W.; Ellis, D. E.

    1984-06-01

    The x-ray K-edge photoabsorption cross sections for TiO and VO have been calculated, with the use of the self-consistent one-electron local-density theory. Energy levels, charge distribution, and cross sections were obtained from a 27-atom "microcrystal," with a molecular-cluster approach in the discrete-variational method. A detailed comparison is made with experimental spectra for VOx; features of theory and experiment are in good agreement if one assumes a relaxation of the nearest-neighbor oxygen atoms for the O-vacancy cluster. Bound-to-bound transitions are found to contribute significantly to the near-edge structure for the defect crystal.

  1. Laboratory Measurements and Modeling of Molecular Photoabsorption Cross Sections in the Ultraviolet: Diatomic Sulfur (S2) and Sulfur Monoxide (SO)

    NASA Astrophysics Data System (ADS)

    Stark, Glenn; Lyons, James; Herde, Hannah; Nave, Gillian; de Oliveira, Nelson

    2015-11-01

    Our research program comprises the measurement and modeling of ultraviolet molecular photoabsorption cross sections with the highest practical resolution. It supports efforts to interpret and model observations of planetary atmospheres. Measurement and modeling efforts on diatomic sulfur (S2) and sulfur monoxide (SO) are in progress.S2: Interpretations of atmospheric (Io, Jupiter, cometary comae) S2 absorption features are hindered by a complete lack of laboratory cross section data in the ultraviolet. We are working to quantify the photoabsorption spectrum of S2 from 240 to 300 nm based on laboratory measurements and theoretical calculations. We have constructed an experimental apparatus to produce a stable column of S2 vapor at a temperature of 800 K. High-resolution measurements of the absorption spectrum of the strong B - X system of S2 were completed using the NIST VUV-FTS at Gaithersburg, MD. These measurements are being incorporated into a coupled-channel model of the absorption spectrum of S2 to quantify the contributions from individual bands and to establish the mechanisms responsible for the strong predissociation signature of the B - X system. A successful coupled channels model can then be used to calculate the B - X absorption spectrum at any temperature.SO: There has been a long-standing need for high-resolution cross sections of SO radicals in the UV and VUV regions, where the molecule strongly predissociates, for modeling the atmospheres of Io and Venus, and for understanding sulfur isotope effects in the ancient (pre-O2) atmosphere of Earth. We have produced a measurable column of SO in a continuous-flow DC discharge cell, using SO2 as a parent molecule. Photoabsorption measurements were recently recorded with the high-resolution VUV-FTS on the DESIRS beamline of the SOLEIL synchrotron. A number of strong, predissociated SO bands were measured in the 140 to 200 nm region. Weaker features associated with the SO B - X system were simultaneously

  2. Resonances in near-threshold x-ray photoabsorption of inner shells

    SciTech Connect

    Del Grande, N.K.; Tirsell, K.G.; Schneider, M.B.; Garrett, R.F.; Kneedler, E.M.; Manson, S.T.

    1987-08-24

    Synchrotron radiation measurements of near-threshold and broad-range (20 eV - 3 keV) absolute photoabsorption cross sections were made at the Brookhaven National Laboratory (NSLS) and at Stanford (SSRL). Transmission data for well-characterized multilayer foils provided absolute cross sections with 10% overall uncertainties and better than 0.2% energy resolution. Several examples of our results are presented.

  3. The Effect of N2 Photoabsorption Cross Section Resolution on C2H6 Production in Titan’s Ionosphere

    NASA Astrophysics Data System (ADS)

    Luspay-Kuti, Adrienn; Mandt, Kathleen E.; Plessis, Sylvain; Greathouse, Thomas K.

    2014-11-01

    Titan’s rich organic chemistry begins with the photochemistry of only two molecules: N2 and CH4. The details on how higher-order hydrocarbons and nitriles are formed from these molecules have key implications for both the structure and evolution of Titan’s atmosphere, and for its surface-atmosphere interactions. Of high importance is the production of C2H6, which is a sink for CH4, and a main component in the polar lakes. Results of photochemical models, though, may be sensitive to the choice of input parameters, such as the N2 photoabsorption cross section resolution, as previously shown for nitrogen (Liang et al. (2007) ApJL 664, 115-118), and CH4 (Lavvas et al. (2011) Icarus 213, 233-251). Here we investigate the possibility of the same effect on the production rates of C2H6. We modeled production and loss rates, as well as mixing ratio and density profiles between an altitude of 600 and 1600 km for low and high resolution N2 cross sections via a coupled ion-neutral-thermal model (De La Haye et al. (2008) Icarus 197, 110-136; Mandt et al. (2012) JGR 117, E10006). Our results show a clear impact of photoabsorption cross section resolution used on all neutral and ion species contributing to C2H6 production. The magnitude of the influence varies amongst species. Ethane production profiles exhibit a significant increase with better resolution; a factor of 1.2 between 750 and 950 km, and a factor of 1.1 in the total column-integrated production rate. These values are lower limits, as additional reactions involving C2H5 not included in the model may also contribute to the production rates. The clear effect on C2H6 (which is not a parent molecule, nor does it bear nitrogen) may have important implications for other molecules in Titan’s atmosphere as well. The possible non-negligible impact of an isotope of nitrogen may argue for the inclusion of isotopes in photochemical models. For future analysis, development of a more efficient and streamlined model called

  4. Photoabsorption cross sections of methane and ethane, 1380-1600 A, at T equals 295 K and T equals 200 K. [in Jupiter atmosphere

    NASA Technical Reports Server (NTRS)

    Mount, G. H.; Moos, H. W.

    1978-01-01

    Photoabsorption cross sections of methane and ethane have been determined in the wavelength range from 1380 to 1600 A at room (295 K) and dry-ice (200 K) temperatures. It is found that the room-temperature ethane data are in excellent agreement with the older measurements of Okabe and Becker (1963) rather than with more recent determinations and that a small systematic blueshift occurs at the foot of the molecular absorption edges of both gases as the gases are cooled from room temperature to 200 K, a value close to the actual temperature of the Jovian atmosphere. It is concluded that methane photoabsorption will dominate until its cross section is about 0.01 that of ethane, which occurs at about 1440 A, and that ethane should be the dominant photoabsorber in the Jovian atmosphere in the region from above 1440 A to not farther than 1575 A.

  5. Absolute measurement of the photoionization cross section of atomic hydrogen with a shock tube for the extreme ultraviolet. [for astrophysical applications

    NASA Technical Reports Server (NTRS)

    Palenius, H. P.; Kohl, J. L.; Parkinson, W. H.

    1976-01-01

    The paper reports an experiment which is part of a program to measure the absolute values of the atomic photoionization cross sections of astrophysically abundant elements, particularly in stars and planetary atmospheres. An aerodynamic pressure-driven shock tube constructed from stainless steel with a quadratic cross section was used to measure the photoionization cross section of H I at 19 wavelength points from 910 to 609 A with experimental uncertainties between 7 and 20%. The shock tube was used to produce fully dissociated hydrogen and neon mixtures for the photoabsorption measurements.

  6. UV, VUV and soft X-ray photoabsorption of dimethyl ether by dipole (e,e) spectroscopies

    NASA Astrophysics Data System (ADS)

    Feng, Renfei; Cooper, Glyn; Brion, C. E.

    2000-10-01

    Absolute UV and VUV photoabsorption oscillator strengths (cross-sections) for the valence shell discrete and continuum regions of dimethyl ether (CH 3OCH 3, DME) have been measured from 5 to 32 eV using high resolution (HR) (˜0.05 eV f.w.h.m.) dipole (e,e) spectroscopy. A wide-range spectrum, spanning the UV, VUV and soft X-ray regions, from 5 to 200 eV has also been obtained at low resolution (LR) (˜1 eV f.w.h.m.), and this has been used to determine the absolute oscillator strength scale by employing valence shell Thomas-Reiche-Kuhn (i.e., S(0)) sum-rule normalization. The presently reported HR and LR absolute photoabsorption oscillator strengths are compared with previously published data from direct photoabsorption measurements in those limited energy regions where such data are available. Evaluation of the S(-2) sum using the presently reported absolute differential photoabsorption oscillator strength data gives a static dipole polarizability for dimethyl ether in excellent agreement (within 0.5%) with previously reported polarizability values. Other dipole sums S( u), ( u=-1,-3,-4,-5,-6,-8,-10), and logarithmic dipole sums L( u), ( u=-1 to -6), are also determined from the presently reported absolute differential photoabsorption oscillator strength data using dipole sum rules.

  7. Absolute photoneutron cross sections of Sm isotopes

    SciTech Connect

    Gheorghe, I.; Glodariu, T.; Utsunomiya, H.; Filipescu, D.; Nyhus, H.-T.; Renstrom, T.; Tesileanu, O.; Shima, T.; Takahisa, K.; Miyamoto, S.

    2015-02-24

    Photoneutron cross sections for seven samarium isotopes, {sup 144}Sm, {sup 147}Sm, {sup 148}Sm, {sup 149}Sm, {sup 150}Sm, {sup 152}Sm and {sup 154}Sm, have been investigated near neutron emission threshold using quasimonochromatic laser-Compton scattering γ-rays produced at the synchrotron radiation facility NewSUBARU. The results are important for nuclear astrophysics calculations and also for probing γ-ray strength functions in the vicinity of neutron threshold. Here we describe the neutron detection system and we discuss the related data analysis and the necessary method improvements for adapting the current experimental method to the working parameters of the future Gamma Beam System of Extreme Light Infrastructure - Nuclear Physics facility.

  8. Measurement of the total photoabsorption cross section on a proton in the energy range 600-1500 MeV at the GRAAL

    SciTech Connect

    Bartalini, O.; Bellini, V.; Bocquet, J. P.; Calvat, P.; D'Angelo, A.; Didelez, J.-P.; Di Salvo, R.; Fantini, A.; Ghio, F.; Girolami, B.; Guidal, M.; Giusa, A.; Hourany, E.; Ignatov, A. S.; Kunne, R.; Lapik, A. M.; Sandri, P. Levi; Lleres, A.; Moricciani, D.; Mushkarenkov, A. N.; and others

    2008-01-15

    The total photoabsorption cross section on a free proton was measured at the GRAAL facility in the energy range E{sub {gamma}} = 600-1500 MeV. The large-aperture LAGRAN{gamma}E detector and a liquid hydrogen target were used in the experiment performed with a back-scattered Compton gamma beam. To improve the accuracy, two alternative methods were employed. First, a subtraction method of using empty-target measurements allowed the cross section {sigma}{sub tot} to be evaluated directly because of a low level of the electromagnetic background. Second, an algorithm for evaluating {sigma}{sub tot} on the basis of summing the dominating partial cross sections was developed. Experimental results obtained for {sigma}{sub tot} by the two methods are compared with existing data.

  9. Absolute photoionization cross-section of the propargyl radical

    SciTech Connect

    Savee, John D.; Welz, Oliver; Taatjes, Craig A.; Osborn, David L.; Soorkia, Satchin; Selby, Talitha M.

    2012-04-07

    Using synchrotron-generated vacuum-ultraviolet radiation and multiplexed time-resolved photoionization mass spectrometry we have measured the absolute photoionization cross-section for the propargyl (C{sub 3}H{sub 3}) radical, {sigma}{sub propargyl}{sup ion}(E), relative to the known absolute cross-section of the methyl (CH{sub 3}) radical. We generated a stoichiometric 1:1 ratio of C{sub 3}H{sub 3} : CH{sub 3} from 193 nm photolysis of two different C{sub 4}H{sub 6} isomers (1-butyne and 1,3-butadiene). Photolysis of 1-butyne yielded values of {sigma}{sub propargyl}{sup ion}(10.213 eV)=(26.1{+-}4.2) Mb and {sigma}{sub propargyl}{sup ion}(10.413 eV)=(23.4{+-}3.2) Mb, whereas photolysis of 1,3-butadiene yielded values of {sigma}{sub propargyl}{sup ion}(10.213 eV)=(23.6{+-}3.6) Mb and {sigma}{sub propargyl}{sup ion}(10.413 eV)=(25.1{+-}3.5) Mb. These measurements place our relative photoionization cross-section spectrum for propargyl on an absolute scale between 8.6 and 10.5 eV. The cross-section derived from our results is approximately a factor of three larger than previous determinations.

  10. Absolute cross section for recoil detection of deuterium

    NASA Astrophysics Data System (ADS)

    Besenbacher, F.; Stensgaard, I.; Vase, P.

    1986-04-01

    The D( 4He, D) 4He cross section used for recoil detection of deuterium (D) has been calibrated on an absolute scale against the cross section of the D( 3He, α)p nuclear reaction which is often used for D profiling. For 4He energies ranging from 0.8 to ~1.8 MeV. the D( 4He, D) 4He cross section varies only slightly with incident energy and recoil angle θ (for 0° ⩽ 8 ⩽ 35°) and has a value of ~ 500 mb/sr which is significantly higher than the ~ 65 mb/sr c.m.s. cross section of the D( 3He, α)p nuclear reaction. For 4He energies ranging from ~ 1.9 to ~ 2.3 MeV, the D( 4He,D) 4He cross section exhibits a fairly narrow resonance peak (fwhm ~ 70 keV), with a maximum value (for θ = 0°) of ~ 8.5 b/sr, corresponding to a 4He energy of ~ 2130 keV. The large values of the cross section in connection with the described energy dependence makes the use of forward-recoil detection of D attractive for many purposes, e.g., D Jepth profiling (with an extreme gain in sensitivity), absolute concentration or coverage measurements, and lattice-location experiments by transmission channeling.

  11. High-resolution vacuum-ultraviolet photoabsorption spectra of 1-butyne and 2-butyne

    SciTech Connect

    Jacovella, U.; Holland, D. M. P.; Boyé-Péronne, S.; Gans, B.; Oliveira, N. de; Joyeux, D.; Archer, L. E.; Lucchese, R. R.; Xu, H.; Pratt, S. T.

    2015-07-21

    The absolute photoabsorption cross sections of 1- and 2-butyne have been recorded at high resolution by using the vacuum-ultraviolet Fourier-Transform spectrometer at the SOLEIL Synchrotron. Both spectra show more resolved structure than previously observed, especially in the case of 2-butyne. In this work, we assess the potential importance of Rydberg states with higher values of orbital angular momentum, l, than are typically observed in photoabsorption experiments from ground state molecules. We show how the character of the highest occupied molecular orbitals in 1- and 2-butyne suggests the potential importance of transitions to such high-l (l = 3 and 4) Rydberg states. Furthermore, we use theoretical calculations of the partial wave composition of the absorption cross section just above the ionization threshold and the principle of continuity of oscillator strength through an ionization threshold to support this conclusion. The new absolute photoabsorption cross sections are discussed in light of these arguments, and the results are consistent with the expectations. This type of argument should be valuable for assessing the potential importance of different Rydberg series when sufficiently accurate direct quantum chemical calculations are difficult, for example, in the n ≥ 5 manifolds of excited states of larger molecules.

  12. Absolute photoionization cross-section of the methyl radical.

    SciTech Connect

    Taatjes, C. A.; Osborn, D. L.; Selby, T.; Meloni, G.; Fan, H.; Pratt, S. T.; Chemical Sciences and Engineering Division; SNL

    2008-01-01

    The absolute photoionization cross-section of the methyl radical has been measured using two completely independent methods. The CH{sub 3} photoionization cross-section was determined relative to that of acetone and methyl vinyl ketone at photon energies of 10.2 and 11.0 eV by using a pulsed laser-photolysis/time-resolved synchrotron photoionization mass spectrometry method. The time-resolved depletion of the acetone or methyl vinyl ketone precursor and the production of methyl radicals following 193 nm photolysis are monitored simultaneously by using time-resolved synchrotron photoionization mass spectrometry. Comparison of the initial methyl signal with the decrease in precursor signal, in combination with previously measured absolute photoionization cross-sections of the precursors, yields the absolute photoionization cross-section of the methyl radical; {sigma}{sub CH}(10.2 eV) = (5.7 {+-} 0.9) x 10{sup -18} cm{sup 2} and {sigma}{sub CH{sub 3}}(11.0 eV) = (6.0 {+-} 2.0) x 10{sup -18} cm{sup 2}. The photoionization cross-section for vinyl radical determined by photolysis of methyl vinyl ketone is in good agreement with previous measurements. The methyl radical photoionization cross-section was also independently measured relative to that of the iodine atom by comparison of ionization signals from CH{sub 3} and I fragments following 266 nm photolysis of methyl iodide in a molecular-beam ion-imaging apparatus. These measurements gave a cross-section of (5.4 {+-} 2.0) x 10{sup -18} cm{sup 2} at 10.460 eV, (5.5 {+-} 2.0) x 10{sup -18} cm{sup 2} at 10.466 eV, and (4.9 {+-} 2.0) x 10{sup -18} cm{sup 2} at 10.471 eV. The measurements allow relative photoionization efficiency spectra of methyl radical to be placed on an absolute scale and will facilitate quantitative measurements of methyl concentrations by photoionization mass spectrometry.

  13. High-resolution photoabsorption spectrum of jet-cooled propyne

    SciTech Connect

    Jacovella, U.; Holland, D. M. P.; Boyé-Péronne, S.; Joyeux, D.; Archer, L. E.; Oliveira, N. de; Nahon, L.; Lucchese, R. R.; Xu, Hong; Pratt, S. T.

    2014-09-21

    The absolute photoabsorption cross section of propyne was recorded between 62 000 and 88 000 cm{sup −1} by using the vacuum-ultraviolet, Fourier-transform spectrometer at the Synchrotron Soleil. This cross section spans the region including the lowest Rydberg bands and extends above the Franck-Condon envelope for ionization to the ground electronic state of the propyne cation, X{sup ~+}. Room-temperature spectra were recorded in a flowing cell at 0.9 cm{sup −1} resolution, and jet-cooled spectra were recorded at 1.8 cm{sup −1} resolution and a rotational temperature of ∼100 K. The reduced widths of the rotational band envelopes in the latter spectra reveal new structure and simplify a number of assignments. Although nf Rydberg series have not been assigned previously in the photoabsorption spectrum of propyne, arguments are presented for their potential importance, and the assignment of one nf series is proposed. As expected from previous photoelectron spectra, Rydberg series are also observed above the adiabatic ionization threshold that converge to the v{sub 3}{sup +} = 1 and 2 levels of the C≡C stretching vibration.

  14. Quantitative studies for photoabsorption and fluorescence of HCl

    NASA Technical Reports Server (NTRS)

    Nee, J. B.; Suto, M.; Lee, L. C.

    1984-01-01

    Photoabsorption and fluorescence cross sections of HCl are investigated in the wavelength region between 105 to 220 nm. The oscillator strengths of discrete structures at wavelengths shorter than 130 nm are measured.

  15. VUV and mid-UV photoabsorption cross sections of thin films of guanine and uracil: application on their photochemistry in the solar system.

    PubMed

    Saïagh, Kafila; Cottin, Hervé; Aleian, Aicha; Fray, Nicolas

    2015-04-01

    We present a photostability study of two nucleobases, guanine and uracil. For the first time, the photoabsorption cross-section spectra of these molecules in the solid phase were measured in the VUV and mid-UV domain (115≤λ≤300 nm). They show a quite similar absorption level throughout this wavelength range, highlighting the importance of considering the whole VUV and UV domain during photolysis experiments in the laboratory. Their photolysis constant (J) can be estimated from those measurements as follows: 2.2×10(-2) s(-1)±11% for guanine and 5.3×10(-2) s(-1)±14% for uracil. This work shows that (i) measuring kinetic constants from a direct and "traditional" photolysis of a thin sample in the laboratory suffers strong limitations and (ii) achieving this measurement requires comprehensive modeling of the radiative transfer that occurs in any sample not optically thin (i.e.,≤2 nm). Moreover, this work has provided other data of interest: the refractive index of solid guanine and of uracil at 650 nm are 1.52 (±0.01) and 1.39 (±0.02), respectively, and the integrated IR band strengths (A) of solid guanine between 3700 and 2120 cm(-1) (3.4×10(-16) cm·molecule(-1)±13%) and of solid uracil between 3400 and 1890 cm(-1) (2.1×10(-16) cm·molecule(-1)±21%). PMID:25836367

  16. NITROGEN K-SHELL PHOTOABSORPTION

    SciTech Connect

    GarcIa, J.; Kallman, T. R.; Witthoeft, M.; Behar, E.; Mendoza, C.; Palmeri, P.; Quinet, P.; Bautista, M.A.; Klapisch, M. E-mail: michael.c.witthoeft@nasa.gov E-mail: behar@milkyway.gsfc.nasa.gov E-mail: palmeri@umons.ac.be E-mail: bautista@vt.edu

    2009-12-01

    Reliable atomic data have been computed for the spectral modeling of the nitrogen K lines, which may lead to useful astrophysical diagnostics. Data sets comprise valence and K-vacancy level energies, wavelengths, Einstein A-coefficients, radiative and Auger widths, and K-edge photoionization cross sections. An important issue is the lack of measurements that are usually employed to fine-tune calculations so as to attain spectroscopic accuracy. In order to estimate data quality, several atomic structure codes are used and extensive comparisons with previous theoretical data have been carried out. In the calculation of K photoabsorption with the Breit-Pauli R-matrix method, both radiation and Auger dampings, which cause the smearing of the K edge, are taken into account. This work is part of a wider project to compute atomic data in the X-ray regime to be included in the database of the popular XSTAR modeling code.

  17. High resolution, low temperature photoabsorption cross-section of C2H2 with application to Saturn's atmosphere

    NASA Technical Reports Server (NTRS)

    Caldwell, John; Wu, C. Y. R.; Xia, T. J.; Judge, D. L.; Wagener, R.

    1990-01-01

    New laboratory observations of the VUV absorption cross-section of C2H2, obtained under physical conditions approximating stratospheres of the giant planets, were combined with IUE observations of the albedo of Saturn, for which improved data reduction techniques have been used, to produce new models for that atmosphere. When the effects of C2H2 absorption are accounted for, additional absorption by other molecules is required. The best-fitting model also includes absorption by PH3, H2O, C2H6 and CH4. A small residual disagreement near 1600 A suggests that an additional trace species may be required to complete the model.

  18. Precision measurements of photoabsorption cross sections of Ar, Kr, Xe, and selected molecules at 58.4, 73.6, and 74.4 nm

    NASA Technical Reports Server (NTRS)

    Samson, James A. R.; Yin, Lifeng

    1989-01-01

    Absolute absorption cross sections have been measured for the rare gases at 58.43, 73.59, and 74.37 nm with an accuracy of + or - 0.8 percent. For the molecules H2, N2, O2, CO, N2O, CO2, and CH4, precision measurements were made at 58.43 nm with an accuracy of + or - 0.8 percent. Molecular absorption cross sections are also reported at 73.59 and 74.37 nm. However, in the vicinity of these wavelengths most molecules exhibit considerable structure, and cross sections measured at these wavelengths may depend on the widths and the amounts of self-reversal of these resonance lines. A detailed discussion is given of the systematic errors encountered with the double-ion chamber used in the cross-sectional measurements. Details are also given of precision pressure measurements.

  19. Workshop report on new directions in soft x-ray photoabsorption

    SciTech Connect

    Bartlett, R.; Del Grande, N.K.; Lindau, I.; Manson, S.; Merts, A.L.; Pratt, R.

    1984-09-17

    The Workshop Report integrates what was said at the Workshop on New Directions in Soft X-Ray Photoabsorption, which focused on the region from 100 eV to 10 keV. The report clarifies the current state of theory and experiment and identifies the opportunities which new theoretical methods and experimental facilities could be expected to provide. The understanding of photoabsorption (which requires experimental photoabsorption cross section data) is a key to understanding the properties and behavior of atoms, molecules and solids. The Workshop participants were forty-three physicists and quantum chemists, from twenty-four institutions in four countries, all interested in photoabsorption from different perspectives.

  20. Photoabsorption and photodissociation of molecules important in the interstellar medium

    NASA Technical Reports Server (NTRS)

    Lee, L. C.

    1986-01-01

    In the period from May 15, 1985 to May 14, 1986, the photoabsorption and photodissociation cross sections of the interstellar radical of SO and the interstellar molecules of HCl, H2CO, and CH3CN were measured and the results were reported in scientific papers. In the meantime, a windowless apparatus is used to measure the photoabsorption and photodissociation cross sections of CO in the 90-105 nm region. The optical data obtained in this research program are needed for the determination of the formation and destruction rates of molecules and radicals in the interstellar medium. Accomplishments in this research period are summarized below.

  1. Quantitative photoabsorption and fluorescence spectroscopy of benzene, naphthalene, and some derivatives at 106-295 nm

    NASA Technical Reports Server (NTRS)

    Suto, Masako; Wang, Xiuyan; Shan, Jun; Lee, L. C.

    1992-01-01

    Photoabsorption and fluorescence cross sections of benzene, (o-, m-, p-) xylenes, naphthalene, 1-methylnaphthalene, and 2-ethylnaphthalene in the gas phase are measured at 106-295 nm using synchrotron radiation as a light source. Fluorescences are observed from the photoexcitation of benzene and xylenes at 230-280 nm and from naphthalene and its derivatives at 190-295 nm. The absolute fluorescence cross section is determined by calibration with respect to the emission intensity of the NO(A-X) system, for which the fluorescence quantum yield is equal to 1. To cross-check the current calibration method, the quantum yield of the SO2(C-X) system at 220-230 nm was measured since it is about equal to 1. The current quantum-yield data are compared with previously published values measured by different methods.

  2. Photoabsorption and photoionization of HD

    SciTech Connect

    Dehmer, Patricia M.; Chupka, William A.

    1983-01-01

    Relative photoabsorption and photoionization cross sections have been measured for HD at a temperature of 78 K in the wavelength region from 735 to 805 Â. The present wavelength resolution of 0.016 Â represents an improvement of more than two orders of magnitude over that of previous photoionization studies of this molecule. Bands of the 3pπ D ¹Πu←X ¹Σg⁺ system are observed to v'=17, and ionization efficiencies are reported for a number of Rydberg states of low principal quantum number. As in the case of H2, the ionization efficiency is close to unity for Rydberg states that can autoionize with Δv= -1, but drops to zero for states that can autoionize only with a large change in vibrational quantum number and that are significantly predissociated (such as the 3pπ D ¹Πu state). The breakdown of (g,u) symmetry in HD and the resulting effects on the absorption spectrum and on the decay paths of the Rydberg states are discussed.

  3. Principles and procedures for determining absolute differential electron-molecule (atom) scattering cross sections

    NASA Technical Reports Server (NTRS)

    Nickel, J. C.; Zetner, P. W.; Shen, G.; Trajmar, S.

    1989-01-01

    Procedures and calibration techniques for measuring the absolute elastic and inelastic differential cross sections (DCS) for electron impact on molecular (atomic) species are described and illustrated by examples. The elastic DCS for the molecule under study is first determined by calibration against helium using the relative flow technique. The second step involves the production of energy-loss spectra for the instrument response function, the unfolding of overlapping inelastic structures and the normalization of inelastic intensities to the elastic cross sections. It is concluded that this method of determining absolute differential electron-molecule (atom) scattering cross sections is generally applicable and provides reliable results.

  4. Absolute electron-impact total ionization cross sections of chlorofluoromethanes

    NASA Astrophysics Data System (ADS)

    Martínez, Roberto; Sierra, Borja; Redondo, Carolina; Rayo, María N. Sánchez; Castaño, Fernando

    2004-12-01

    An experimental study is reported on the electron-impact total ionization cross sections (TICSs) of CCl4, CCl3F, CCl2F2, and CClF3 molecules. The kinetic energy of the colliding electrons was in the 10-85 eV range. TICSs were obtained as the sum of the partial ionization cross sections of all fragment ions, measured and identified in a linear double focusing time-of-flight mass spectrometer. The resulting TICS profiles—as a function of the electron-impact energy—have been compared both with those computed by ab initio and (semi)empirical methods and with the available experimental data. The computational methods used include the binary-encounter-Bethe (BEB) modified to include atoms with principal quantum numbers n⩾3, the Deutsch and Märk (DM) formalism, and the modified additivity rule (MAR). It is concluded that both modified BEB and DM methods fit the experimental TICS for (CF4), CClF3, CCl2F2, CCl3F, and CCl4 to a high accuracy, in contrast with the poor accord of the MAR method. A discussion on the factors influencing the discrepancies of the fittings is presented.

  5. Photoabsorption and phototdissociation of molecules important in the interstellar medium

    NASA Technical Reports Server (NTRS)

    Lee, Long C.; Sutom, Masako

    1988-01-01

    The photoabsorption and photodissociation cross sections of interstellar molecules and radicals were measured in the 90 to 200 nm region using synchrotron radiation, F sub 2 laser, excimer lasers, and discharge lamps as light sources. These data are currently needed for determining the formation and destruction rates of molecules and radicals by the interstellar radiation field.

  6. Photoabsorption spectra of potassium and rubidium near the K-edge

    SciTech Connect

    Azuma, Y.; Berry, H.G.; Cowan, P.L.

    1995-08-01

    We have used a high-temperature circulating heat-pipe absorption cell together with monochromatized X-ray beams at the X24A and X23A2 beam lines at the NSLS to obtain photoabsorption spectra of potassium and rubidium at their K- and KM-edges. The photon-energy ranges lay near 3600 eV and 15200 eV, respectively. We have also obtained first measurements of the LII and LIII edges in cesium. Although the K-edge photoabsorptions of the rare gases have been studied, there is little previous work on other atomic vapors. Most of the edges and resonance peaks that we observed have now been identified using Dirac Hartree-Fock calculations. As a check, we have compared these results with those obtained previously in closed-shell rare-gas absorption spectra. The absolute energies were obtained through a calibration of the X24A systems using measurements of several metal L-edges in the 3200-5000 eV energy range. We found that the 4p resonance in potassium is significantly enhanced compared with the corresponding situation in argon. Likewise, the 5p resonance in krypton is unresolved from the background ionization cross section, whereas it is well resolved in rubidium. As suggested by Amusia, these enhancements may be due to the enhanced potential seen in the excited state of the alkali systems as a result of the presence of an s-electron which reduces the nuclear shielding.

  7. Quantitative photoabsorption and fluorescence study of HCl in vacuum ultraviolet

    NASA Technical Reports Server (NTRS)

    Nee, J. B.; Suto, M.; Lee, L. C.

    1986-01-01

    The photoabsorption and fluorescence cross sections of HCl were measured in the 106-185 nm region. Sharp absorption bands appear at wavelengths shorter than 135 nm, and fluorescence occurs at several excited states. The fluorescence cross sections are generally quite small, indicating that the excited states are strongly predissociative. The molecular processes for producing the VUV and UV fluorescences are investigated, and the Rydberg characteristics of the strong absorption bands are discussed.

  8. Absolute total and partial dissociative cross sections of pyrimidine at electron and proton intermediate impact velocities

    SciTech Connect

    Wolff, Wania Luna, Hugo; Sigaud, Lucas; Montenegro, Eduardo C.; Tavares, Andre C.

    2014-02-14

    Absolute total non-dissociative and partial dissociative cross sections of pyrimidine were measured for electron impact energies ranging from 70 to 400 eV and for proton impact energies from 125 up to 2500 keV. MOs ionization induced by coulomb interaction were studied by measuring both ionization and partial dissociative cross sections through time of flight mass spectrometry and by obtaining the branching ratios for fragment formation via a model calculation based on the Born approximation. The partial yields and the absolute cross sections measured as a function of the energy combined with the model calculation proved to be a useful tool to determine the vacancy population of the valence MOs from which several sets of fragment ions are produced. It was also a key point to distinguish the dissociation regimes induced by both particles. A comparison with previous experimental results is also presented.

  9. Absolute Absorption Cross Sections from Photon Recoil in a Matter-Wave Interferometer

    NASA Astrophysics Data System (ADS)

    Eibenberger, Sandra; Cheng, Xiaxi; Cotter, J. P.; Arndt, Markus

    2014-06-01

    We measure the absolute absorption cross section of molecules using a matter-wave interferometer. A nanostructured density distribution is imprinted onto a dilute molecular beam through quantum interference. As the beam crosses the light field of a probe laser some molecules will absorb a single photon. These absorption events impart a momentum recoil which shifts the position of the molecule relative to the unperturbed beam. Averaging over the shifted and unshifted components within the beam leads to a reduction of the fringe visibility, enabling the absolute absorption cross section to be extracted with high accuracy. This technique is independent of the molecular density, it is minimally invasive and successfully eliminates many problems related to photon cycling, state mixing, photobleaching, photoinduced heating, fragmentation, and ionization. It can therefore be extended to a wide variety of neutral molecules, clusters, and nanoparticles.

  10. Absolute differential cross sections for electron capture and loss by kilo-electron-volt hydrogen atoms

    NASA Technical Reports Server (NTRS)

    Smith, G. J.; Johnson, L. K.; Gao, R. S.; Smith, K. A.; Stebbings, R. F.

    1991-01-01

    This paper reports measurements of absolute differential cross sections for electron capture and loss for fast hydrogen atoms incident on H2, N2, O2, Ar, and He. Cross sections have been determined in the 2.0- to 5.0-keV energy range over the laboratory angular range 0.02-2 deg, with an angular, resolution of 0.02 deg. The high angular resolution allows observation of the structure at small angles in some of the cross sections. Comparison of the present results with those of other authors generally shows very good agreement.

  11. K-SHELL PHOTOABSORPTION STUDIES OF THE CARBON ISONUCLEAR SEQUENCE

    SciTech Connect

    Hasoglu, M. F.; Abdel-Naby, Sh. A.; Gorczyca, T. W.; Drake, J. J.; McLaughlin, B. M.

    2010-12-01

    K-shell photoabsorption cross sections for the isonuclear C I-C IV ions have been computed using the R-matrix method. Above the K-shell threshold, the present results are in good agreement with the independent-particle results of Reilman and Manson. Below threshold, we also compute the strong 1s {yields} np absorption resonances with the inclusion of important spectator Auger broadening effects. For the lowest 1s {yields} 2p, 3p resonances, comparisons to available C II, C III, and C IV experimental results show good agreement in general for the resonance strengths and positions. Our results also provide detailed information on the C I K-shell photoabsorption cross section including the strong resonance features, since very limited laboratory experimental data exist. The resultant R-matrix cross sections are then used to model the Chandra X-ray absorption spectrum of the blazar Mkn 421.

  12. Measurements of absolute absorption cross sections of ozone in the 185- to 254-nm wavelength region and the temperature dependence

    NASA Technical Reports Server (NTRS)

    Yoshino, K.; Esmond, J. R.; Freeman, D. E.; Parkinson, W. H.

    1993-01-01

    Laboratory measurements of the relative absorption cross sections of ozone at temperatures 195, 228, and 295 K have been made throughout the 185 to 254 nm wavelength region. The absolute absorption cross sections at the same temperatures have been measured at several discrete wavelengths in the 185 to 250 nm region. The absolute cross sections of ozone have been used to put the relative cross sections on a firm absolute basis throughout the 185 to 255 nm region. These recalibrated cross sections are slightly lower than those of Molina and Molina (1986), but the differences are within a few percent and would not be significant in atmospheric applications.

  13. Total photoabsorption in nuclei

    SciTech Connect

    Bianchi, N.

    1992-06-01

    The Frascati-Genova collaboration proposes to measure the total photonuclear cross section on a wide range of nuclei between 500 MeV and 2 GeV, to obtain informations on the interaction of baryon resonances with nucleons and on the onset of the shadowing effect. The experiment could be performed in the Hall B as soon as the tagging facility will be ready and before the end of the installation of the CLAS spectrometer. The requirements for the photon beam, like maximum energy, intensity and beam definition, are not so strong so that the experiment would also be a good first test of the tagged photon facility.

  14. Absolute absorption cross sections of ozone in the 185- to 350-nm wavelength range

    NASA Technical Reports Server (NTRS)

    Molina, L. T.; Molina, M. J.

    1986-01-01

    The absorption cross sections of ozone have been measured in the wavelength range 185-350 nm and in the temperature range 225-298 K. The absolute ozone concentrations were established by measuring the pressure of pure gaseous samples in the 0.08to 300-torr range, and the UV spectra were recorded under conditions where less than 1 percent of the sample decomposed. The temperature dependence is significant for wavelengths longer than about 280 nm. The absorption cross-section values around 210 nm were found to be about 10 percent larger than the previously accepted values.

  15. Photoabsorption in formaldehyde

    NASA Technical Reports Server (NTRS)

    Langhoff, P. W.; Langhoff, S. R.; Corcoran, C. T.

    1977-01-01

    Theoretical studies of the vertical electronic dipole excitation and ionization spectra in molecular formaldehyde are reported. The investigations relied on configuration-interaction calculations and moment-theory techniques. A double-zeta basis of contracted Gaussian-lobe functions supplemented with appropriate polarization and bond functions was used to construct Fock spectra in C(2 nu) symmetry for certain states near the ground state equilibrium geometry. The ionization energies, discrete vertical transition frequencies, and oscillator strengths for occupied and vertical Fock orbitals are in general accord with experimental determinations and other theoretical calculations. Stieltjes and Chebyshev vertical electronic photoionization profiles were calculated and found to be in good agreement with appropriately averaged photoionization-mass spectrometric measurements of the cross section for parent H2CO(+) ion production.

  16. Absolute measurement of the 242Pu neutron-capture cross section

    NASA Astrophysics Data System (ADS)

    Buckner, M. Q.; Wu, C. Y.; Henderson, R. A.; Bucher, B.; Chyzh, A.; Bredeweg, T. A.; Baramsai, B.; Couture, A.; Jandel, M.; Mosby, S.; O'Donnell, J. M.; Ullmann, J. L.; Dance Collaboration

    2016-04-01

    The absolute neutron-capture cross section of 242Pu was measured at the Los Alamos Neutron Science Center using the Detector for Advanced Neutron-Capture Experiments array along with a compact parallel-plate avalanche counter for fission-fragment detection. The first direct measurement of the 242Pu(n ,γ ) cross section was made over the incident neutron energy range from thermal to ≈6 keV, and the absolute scale of the (n ,γ ) cross section was set according to the known 239Pu(n ,f ) resonance at En ,R=7.83 eV. This was accomplished by adding a small quantity of 239Pu to the 242Pu sample. The relative scale of the cross section, with a range of four orders of magnitude, was determined for incident neutron energies from thermal to ≈40 keV. Our data, in general, are in agreement with previous measurements and those reported in ENDF/B-VII.1; the 242Pu(n ,γ ) cross section at the En ,R=2.68 eV resonance is within 2.4 % of the evaluated value. However, discrepancies exist at higher energies; our data are ≈30 % lower than the evaluated data at En≈1 keV and are approximately 2 σ away from the previous measurement at En≈20 keV.

  17. Absolute X-ray emission cross section measurements of Fe K transitions

    NASA Astrophysics Data System (ADS)

    Hell, Natalie; Brown, Gregory V.; Beiersdorfer, Peter; Boyce, Kevin R.; Grinberg, Victoria; Kelley, Richard L.; Kilbourne, Caroline; Leutenegger, Maurice A.; Porter, Frederick Scott; Wilms, Jörn

    2016-06-01

    We have measured the absolute X-ray emission cross sections of K-shell transitions in highly charged L- and K-shell Fe ions using the LLNL EBIT-I electron beam ion trap and the NASA GSFC EBIT Calorimeter Spectrometer (ECS). The cross sections are determined by using the ECS to simultaneously record the spectrum of the bound-bound K-shell transitions and the emission from radiative recombination from trapped Fe ions. The measured spectrum is then brought to an absolute scale by normalizing the measured flux in the radiative recombination features to their theoretical cross sections, which are well known. Once the spectrum is brought to an absolute scale, the cross sections of the K-shell transitions are determined. These measurements are made possible by the ECS, which consists of a 32 channel array, with 14 channels optimized for detecting high energy photons (hν > 10 keV) and 18 channels optimized for detecting low energy photons (hν < 10 keV). The ECS has a large collection area, relatively high energy resolution, and a large bandpass; all properties necessary for this measurement technique to be successful. These data will be used to benchmark cross sections in the atomic reference data bases underlying the plasma modeling codes used to analyze astrophysical spectra, especially those measured by the Soft X-ray Spectrometer calorimeter instrument recently launched on the Hitomi X-ray Observatory.This work was performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344, and supported by NASA grants to LLNL and NASA/GSFC and by ESA under contract No. 4000114313/15/NL/CB.

  18. Atmospheric Oxygen Photoabsorption

    NASA Technical Reports Server (NTRS)

    Slanger, Tom G.

    1996-01-01

    The work conducted on this grant was devoted to various aspects of the photophysics and photochemistry of the oxygen molecule. Predissociation linewidths were measured for several vibrational levels in the O2(B3 Sigma(sub u)(sup -)) state, providing good agreement with other groups working on this important problem. Extensive measurements were made on the loss kinetics of vibrationally excited oxygen, where levels between v = 5 and v = 22 were investigated. Cavity ring-down spectroscopy was used to measure oscillator strengths in the oxygen Herzberg bands. The great sensitivity of this technique made it possible to extend the known absorption bands to the dissociation limit as well as providing many new absorption lines that seem to be associated with new O2 transitions. The literature concerning the Herzberg band strengths was evaluated in light of our new measurements, and we made recommendations for the appropriate Herzberg continuum cross sections to be used in stratospheric chemistry. The transition probabilities for all three Herzberg band systems were re-evaluated, and we are recommending a new set of values.

  19. Absolute absorption cross-section measurements of ozone in the wavelength region 238-335 nm and the temperature dependence

    NASA Technical Reports Server (NTRS)

    Yoshino, K.; Freeman, D. E.; Esmond, J. R.; Parkinson, W. H.

    1988-01-01

    The absolute absorption cross-section of ozone has been experimentally determined at the temperatures 195, 228, and 295 K at several discrete wavelengths in the 238-335-nm region. The present results for ozone at 295 K are found to be in agreement with those of Hearn (1961). Absolute cross-section measurements of ozone at 195 K have confirmed previous (Freeman et al., 1984) relative cross-section measurements throughout the 240-335-nm region.

  20. K-SHELL PHOTOABSORPTION OF MAGNESIUM IONS

    SciTech Connect

    Hasoğlu, M. F.; Abdel-Naby, Sh. A.; Gatuzz, E.; Mendoza, C.; García, J.; Kallman, T. R.; Gorczyca, T. W.

    2014-09-01

    X-ray photoabsorption cross sections have been computed for all magnesium ions with three or more electrons using the R-matrix method. A comparison with other available data for Mg II-Mg X shows good qualitative agreement in the resultant resonance shapes. However, for the lower ionization stages, and for singly ionized Mg II in particular, the previous R-matrix results overestimate the K-edge position due to the neglect of important orbital relaxation effects, and a global shift downward in photon energy of those cross sections is therefore warranted. We have found that the cross sections for Mg I and Mg II are further complicated by the M-shell (n = 3) occupancy. As a result, the treatment of spectator Auger decay of 1s → np resonances using a method based on multichannel quantum defect theory and an optical potential becomes problematic, making it necessary to implement an alternative, approximate treatment of Auger decay for neutral Mg I. The new cross sections are used to fit the Mg K edge in XMM-Newton spectra of the low-mass X-ray binary GS 1826-238, where most of the interstellar Mg is found to be in ionized form.

  1. On the absolute photoionization cross section and dissociative photoionization of cyclopropenylidene.

    PubMed

    Holzmeier, Fabian; Fischer, Ingo; Kiendl, Benjamin; Krueger, Anke; Bodi, Andras; Hemberger, Patrick

    2016-04-01

    We report the determination of the absolute photoionization cross section of cyclopropenylidene, c-C3H2, and the heat of formation of the C3H radical and ion derived by the dissociative ionization of the carbene. Vacuum ultraviolet (VUV) synchrotron radiation as provided by the Swiss Light Source and imaging photoelectron photoion coincidence (iPEPICO) were employed. Cyclopropenylidene was generated by pyrolysis of a quadricyclane precursor in a 1 : 1 ratio with benzene, which enabled us to derive the carbene's near threshold absolute photoionization cross section from the photoionization yield of the two pyrolysis products and the known cross section of benzene. The cross section at 9.5 eV, for example, was determined to be 4.5 ± 1.4 Mb. Upon dissociative ionization the carbene decomposes by hydrogen atom loss to the linear isomer of C3H(+). The appearance energy for this process was determined to be AE(0K)(c-C3H2; l-C3H(+)) = 13.67 ± 0.10 eV. The heat of formation of neutral and cationic C3H was derived from this value via a thermochemical cycle as Δ(f)H(0K)(C3H) = 725 ± 25 kJ mol(-1) and Δ(f)H(0K)(C3H(+)) = 1604 ± 19 kJ mol(-1), using a previously reported ionization energy of C3H. PMID:26975696

  2. Absolute single-photoionization cross sections of Se2 +: Experiment and theory

    NASA Astrophysics Data System (ADS)

    Macaluso, D. A.; Aguilar, A.; Kilcoyne, A. L. D.; Red, E. C.; Bilodeau, R. C.; Phaneuf, R. A.; Sterling, N. C.; McLaughlin, B. M.

    2015-12-01

    Absolute single-photoionization cross-section measurements for Se2 + ions were performed at the Advanced Light Source at Lawrence Berkeley National Laboratory using the merged-beams photo-ion technique. Measurements were made at a photon energy resolution of 24 ±3 meV in the photon energy range 23.5-42.5 eV, spanning the ground state and low-lying metastable state ionization thresholds. To clearly resolve the resonant structure near the ground-state threshold, high-resolution measurements were made from 30.0 to 31.9 eV at a photon energy resolution of 6.7 ±0.7 meV. Numerous resonance features observed in the experimental spectra are assigned and their energies and quantum defects tabulated. The high-resolution cross-section measurements are compared with large-scale, state-of-the-art theoretical cross-section calculations obtained from the Dirac Coulomb R -matrix method. Suitable agreement is obtained over the entire photon energy range investigated. These results are an experimental determination of the absolute photoionization cross section of doubly ionized selenium and include a detailed analysis of the photoionization resonance spectrum of this ion.

  3. Absolute measurement of the 242Pu neutron-capture cross section

    DOE PAGESBeta

    Buckner, M. Q.; Wu, C. Y.; Henderson, R. A.; Bucher, B.; Chyzh, A.; Bredeweg, T. A.; Baramsai, B.; Couture, A.; Jandel, M.; Mosby, S.; et al

    2016-04-21

    Here, the absolute neutron-capture cross section of 242Pu was measured at the Los Alamos Neutron Science Center using the Detector for Advanced Neutron-Capture Experiments array along with a compact parallel-plate avalanche counter for fission-fragment detection. The first direct measurement of the 242Pu(n,γ) cross section was made over the incident neutron energy range from thermal to ≈ 6 keV, and the absolute scale of the (n,γ) cross section was set according to the known 239Pu(n,f) resonance at En,R = 7.83 eV. This was accomplished by adding a small quantity of 239Pu to the 242Pu sample. The relative scale of the crossmore » section, with a range of four orders of magnitude, was determined for incident neutron energies from thermal to ≈ 40 keV. Our data, in general, are in agreement with previous measurements and those reported in ENDF/B-VII.1; the 242Pu(n,γ) cross section at the En,R = 2.68 eV resonance is within 2.4% of the evaluated value. However, discrepancies exist at higher energies; our data are ≈30% lower than the evaluated data at En ≈ 1 keV and are approximately 2σ away from the previous measurement at En ≈ 20 keV.« less

  4. Absolute np and pp cross section determinations aimed at improving the standard for cross section measurements

    SciTech Connect

    Laptev, Alexander B; Haight, Robert C; Tovesson, Fredrik; Arndt, Richard A; Briscoe, William J; Paris, Mark W; Strakovsky, Igor I; Workman, Ron L

    2010-01-01

    Purpose of present research is a keeping improvement of the standard for cross section measurements of neutron-induced reactions. The cross sections for np and pp scattering below 1000 MeV are determined based on partial-wave analyses (PW As) of nucleon-nucleon scattering data. These cross sections are compared with the most recent ENDF/B-V11.0 and JENDL-4.0 data files, and the Nijmegen PWA. Also a comparison of evaluated data with recent experimental data was made to check a quality of evaluation. Excellent agreement was found between the new experimental data and our PWA predictions.

  5. Absolute np and pp Cross Section Determinations Aimed At Improving The Standard For Cross Section Measurements

    SciTech Connect

    Laptev, A. B.; Haight, R. C.; Tovesson, F.; Arndt, R. A.; Briscoe, W. J.; Paris, M. W.; Strakovsky, I. I.; Workman, R. L.

    2011-06-01

    Purpose of present research is a keeping improvement of the standard for cross section measurements of neutron-induced reactions. The cross sections for np and pp scattering below 1 GeV are determined based on partial-wave analyses (PWAs) of nucleon-nucleon scattering data. These cross sections are compared with the most recent ENDF/B-VII.0 and JENDL-4.0 data files, and the Nijmegen PWA. Also a comparison of evaluated data with recent experimental data was made to check a quality of evaluation. Excellent agreement was found between the new experimental data and our PWA predictions.

  6. Absolute state-selected total cross sections for the O(+)(4S) + CO2 reactions

    NASA Astrophysics Data System (ADS)

    Flesch, G. D.; Ng, C. Y.

    1991-12-01

    Results are presented on measurements of absolute state-selected total cross sections for O2(+), CO2(+), CO(+), and C(+) produced in the reaction between O(+)(4S) and CO2, which were conducted in the center-of-mass collision energy (Ecm) range of 0.2-150 eV. It was found that, with increasing collisional energy, the cross section of O2(+) dropped off rapidly and became essentially zero at Ecm above 3 eV. The dependence of O2(+) cross section on the Ecm is consistent with a collision complex mechanism for the reaction between O(+)(4S) and CO2 yielding CO2(+) + O. The values for O2(+) obtained in this experiment were significantly higher than those reported by Rutherford and Vroom (1976).

  7. Effect of Wall Suction on Cross-Flow Absolute Instability of a Rotating Disk Boundary Layer

    NASA Astrophysics Data System (ADS)

    Ho, Joanna; Corke, Thomas; Matlis, Eric

    2014-11-01

    The effect of uniform suction on the absolute instability of Type I cross-flow modes on a rotating disk is examined. Specifically it investigates if wall suction transforms the absolute instability into a global mode as postulated in the numerical simulations of Davies and Carpenter (2003). The experiment is designed so that a suction parameter of a =W0 /(νω) 1 / 2 = 0 . 2 locates the absolute instability critical Reynolds number, Rca = 650 , on the disk. Uniform wall suction is applied from R = 317 to 696. The design for wall suction follows that of Gregory and Walker (1950), where an array of holes through the disk communicate between the measurement side of the disk and the underside of the disk in an enclosure that is maintained at a slight vacuum. The measurement surface is covered by a 20 micron pore size Polyethylene sheet. Temporal disturbances are introduced using the method of Othman and Corke (2006), and the evolution of the resulting wave packets are documented. The present results indicate a rapid transition to turbulence near Rca.

  8. Absolute effective cross sections of ionization of adenine and guanine molecules by electron impact

    NASA Astrophysics Data System (ADS)

    Shafranyosh, I. I.; Svida, Yu. Yu.; Sukhoviya, M. I.; Shafranyosh, M. I.; Minaev, B. F.; Baryshnikov, G. V.; Minaeva, V. A.

    2015-10-01

    Effective cross sections of the formation of positive ions of nitrous nucleic acids of adenine and guanine are determined by the crossed electron and molecular beam method in the energy interval from the threshold to 200 eV. It is found that the maximal value of the total cross section of adenine ionization is attained at an energy of 90 eV and is equal to (2.8 ± 0.6) × 10-15 cm2. The maximal value of the total cross section of guanine ionization is equal to (3.2 ± 0.7) × 10-15 cm2 and is observed at an energy of 88 eV. The energy ionization thresholds are determined, which amount to (8.8 ± 0.2) eV for adenine and to (8.3 ± 0.2) eV for guanine. The adenine and guanine mass spectra are measured. The absolute values of partial ionization cross sections of adenine and guanine molecules are determined.

  9. Relative vs. absolute physiological measures as predictors of mountain bike cross-country race performance.

    PubMed

    Gregory, John; Johns, David P; Walls, Justin T

    2007-02-01

    The aims of this study were to document the effect terrain has on the physiological responses and work demands (power output) of riding a typical mountain bike cross-country course under race conditions. We were particularly interested in determining whether physiological measures relative to mass were better predictors of race performance than absolute measures. Eleven A-grade male cross-country mountain bike riders (VO2max 67.1 +/- 3.6 ml x kg(-1) x min(-1)) performed 2 tests: a laboratory-based maximum progressive exercise test, and a 15.5-km (six 2.58-km laps) mountain bike cross-country time trial. There were significant differences among the speed, cadence, and power output measured in each of 8 different terrain types found in the cross-country time trial course. The highest average speed was measured during the 10-15% downhill section (22.7 +/- 2.6 km x h(-1)), whereas the cadence was highest in the posttechnical flat sections (74.3 +/- 5.6 rpm) and lowest on the 15-20% downhill sections (6.4 +/- 12.1 rpm). The highest mean heart rate (HR) was obtained during the steepest (15-20% incline) section of the course (179 +/- 8 b x min(-1)), when the power output was greatest (419.8 +/- 39.7 W). However, HR remained elevated relative to power output in the downhill sections of the course. Physiological measures relative to total rider mass correlated more strongly to average course speed than did absolute measures (peak power relative to mass r = 0.93, p < 0.01, vs. peak power r = 0.64, p < 0.05; relative VO2max r = 0.80, p < 0.05, vs. VO2max r = 0.66, p < 0.05; power at anaerobic threshold relative to mass r = 0.78, p < 0.05, vs. power at anaerobic threshold r = 0.5, p < 0.05). This suggests that mountain bike cross-country training programs should focus upon improving relative physiological values rather than focusing upon maximizing absolute values to improve performance. PMID:17313256

  10. Photodissociation of acetaldehyde and the absolute photoionization cross section of HCO.

    SciTech Connect

    Shubert, V. A.; Pratt, S. T.

    2010-01-01

    Photodissociation of acetaldehyde (CH{sub 3}CHO) at 266 nm produced CH{sub 3} and HCO radicals, and single-photon vacuum ultraviolet ionization was used to record velocity map ion images of both CH{sub 3}{sup +} and HCO{sup +}. Comparison of the translational energy distributions from both species indicates that secondary fragmentation of HCO is negligible for 266 nm photodissociation. Thus, the relative photoion signals for CH{sub 3}{sup +} and HCO{sup +} in the mass spectrometer, combined with the recently measured absolute photoionization cross section of CH{sub 3}, allowed the determination of the absolute photoionization cross section of HCO ({sigma}(HCO) = 4.8 {+-} {sub 1.5}{sup 2.0}, 5.9 {+-} {sub 1.6}{sup 2.2}, and 3.7 {+-} {sub 1.2}{sup 1.6} Mb at 10.257, 10.304, and 10.379 eV, respectively). The observed values are quite small but consistent with the similarly small value at threshold for the isoelectronic species NO. This behavior is discussed in terms of the character of the HOMO in both molecules.

  11. Photoabsorption and photodissociation of molecules important in the interstellar medium

    NASA Technical Reports Server (NTRS)

    Lee, Long C.; Suto, Masako

    1991-01-01

    The photoabsorption, photodissociation, and fluorescence cross sections of interstellar molecules are measured at 90 to 250 nm. These quantitative optical data are needed for the understanding of the formation and destruction processes of molecules under the intense interstellar UV radiation field. Research covering the following topics is presented: (1) fluorescences from photoexcitation of CH4, CH3OH, and CH3SH; (2) NO gamma emission from photoexcitation of NO; (3) photoexcitation cross sections of aromatic molecules; (4) IR emission from UV excitation of HONO2; (5) IR emission from UV excitation of benzene and methyl-derivitives; and (6) IR emission from UV excitation of polycyclic aromatic hydrocarbon molecules.

  12. Absolute angle-differential vibrational excitation cross sections for electron collisions with diacetylene

    SciTech Connect

    Allan, M.; May, O.; Fedor, J.; Ibanescu, B. C.; Andric, L.

    2011-05-15

    Absolute vibrational excitation cross sections were measured for diacetylene (1,3-butadiyne). The selectivity of vibrational excitation reveals detailed information about the shape resonances. Excitation of the C{identical_to}C stretch and of double quanta of the C-H bend vibrations reveals a {sup 2}{Pi}{sub u} resonance at 1 eV (autodetachment width {approx}30 meV) and a {sup 2}{Pi}{sub g} resonance at 6.2 eV (autodetachment width 1-2 eV). There is a strong preference for excitation of even quanta of the bending vibration. Excitation of the C-H stretch vibration reveals {sigma}* resonances at 4.3, 6.8, and 9.8 eV, with autodetachment widths of {approx}2 eV. Detailed information about resonances permits conclusions about the mechanism of the dissociative electron attachment.

  13. Absolute photofission cross section of sup 197 Au, @Pb, sup 209 Bi, sup 232 Th, sup 238 U, and sup 235 U nuclei by 69-MeV monochromatic and polarized photons

    SciTech Connect

    Martins, J.B.; Moreira, E.L.; Tavares, O.A.P.; Vieira, J.L. Centro Brasileiro de Pesquisas Fisicas-CBPF, Rua Dr. Xavier Sigaud 150, 22290 Rio de Janeiro-RJ, ); Casano, L.; D'Angelo, A.; Schaerf, C. Istituto Nazionale di Fisica Nucleare-INFN, Sezione di Roma 2, Roma, ); Terranova, M.L. Istituto Nazionale di Fisica Nucleare-INFN, Sezione di Roma 2, Roma, Italy); Babusci, D. ); Girolami, B. Istituto Nazionale di Fisica Nuclea

    1991-07-01

    Absolute cross-section measurements for the photofission reactions of {sup 197}Au, {sup nat}Pb, {sup 209}Bi, {sup 232}Th, {sup 238}U, and {sup 235}U nuclei have been performed at an incident photon energy of 69 MeV using monochromatic and polarized photon beams and dielectric fission-track detectors. Nuclear fissility values have been obtained and results are in agreement with those from other laboratories, although in some cases discrepancies are observed between one other. For nuclei in the region of the actinides the fissility result is {approx gt}0.4, while for Au, Pb, and Bi nuclei it only is {similar to}10{sup {minus}3}--10{sup {minus}2}. Results have been interpreted in terms of the primary Levinger's quasideuteron nuclear photoabsorption followed by a mechanism of evaporation-fission competition for the excited nuclei. Shell effects have been taken into account, and they are clearly manifested when fissility is evaluated. The influence of photon polarization on photofission of {sup 238}U also has been investigated, and results have shown isotropy in the fragment azimuthal distribution.

  14. Systematic determination of absolute absorption cross-section of individual carbon nanotubes

    PubMed Central

    Liu, Kaihui; Hong, Xiaoping; Choi, Sangkook; Jin, Chenhao; Capaz, Rodrigo B.; Kim, Jihoon; Wang, Wenlong; Bai, Xuedong; Louie, Steven G.; Wang, Enge; Wang, Feng

    2014-01-01

    Optical absorption is the most fundamental optical property characterizing light–matter interactions in materials and can be most readily compared with theoretical predictions. However, determination of optical absorption cross-section of individual nanostructures is experimentally challenging due to the small extinction signal using conventional transmission measurements. Recently, dramatic increase of optical contrast from individual carbon nanotubes has been successfully achieved with a polarization-based homodyne microscope, where the scattered light wave from the nanostructure interferes with the optimized reference signal (the reflected/transmitted light). Here we demonstrate high-sensitivity absorption spectroscopy for individual single-walled carbon nanotubes by combining the polarization-based homodyne technique with broadband supercontinuum excitation in transmission configuration. To our knowledge, this is the first time that high-throughput and quantitative determination of nanotube absorption cross-section over broad spectral range at the single-tube level was performed for more than 50 individual chirality-defined single-walled nanotubes. Our data reveal chirality-dependent behaviors of exciton resonances in carbon nanotubes, where the exciton oscillator strength exhibits a universal scaling law with the nanotube diameter and the transition order. The exciton linewidth (characterizing the exciton lifetime) varies strongly in different nanotubes, and on average it increases linearly with the transition energy. In addition, we establish an empirical formula by extrapolating our data to predict the absorption cross-section spectrum for any given nanotube. The quantitative information of absorption cross-section in a broad spectral range and all nanotube species not only provides new insight into the unique photophysics in one-dimensional carbon nanotubes, but also enables absolute determination of optical quantum efficiencies in important

  15. Electronic excitation of carbonyl sulphide (COS) by high-resolution vacuum ultraviolet photoabsorption and electron-impact spectroscopy in the energy region from 4 to 11 eV

    SciTech Connect

    Limão-Vieira, P.; Ferreira da Silva, F.; Almeida, D.; Hoshino, M.; Tanaka, H.; Mogi, D.; Tanioka, T.; Mason, N. J.; Hoffmann, S. V.; Hubin-Franskin, M.-J.; Delwiche, J.

    2015-02-14

    The electronic state spectroscopy of carbonyl sulphide, COS, has been investigated using high resolution vacuum ultraviolet photoabsorption spectroscopy and electron energy loss spectroscopy in the energy range of 4.0–10.8 eV. The spectrum reveals several new features not previously reported in the literature. Vibronic structure has been observed, notably in the low energy absorption dipole forbidden band assigned to the (4π←3π) ({sup 1}Δ←{sup 1}Σ{sup +}) transition, with a new weak transition assigned to ({sup 1}Σ{sup −}←{sup 1}Σ{sup +}) reported here for the first time. The absolute optical oscillator strengths are determined for ground state to {sup 1}Σ{sup +} and {sup 1}Π transitions. Based on our recent measurements of differential cross sections for the optically allowed ({sup 1}Σ{sup +} and {sup 1}Π) transitions of COS by electron impact, the optical oscillator strength f{sub 0} value and integral cross sections (ICSs) are derived by applying a generalized oscillator strength analysis. Subsequently, ICSs predicted by the scaling are confirmed down to 60 eV in the intermediate energy region. The measured absolute photoabsorption cross sections have been used to calculate the photolysis lifetime of carbonyl sulphide in the upper stratosphere (20–50 km)

  16. Electronic excitation of carbonyl sulphide (COS) by high-resolution vacuum ultraviolet photoabsorption and electron-impact spectroscopy in the energy region from 4 to 11 eV.

    PubMed

    Limão-Vieira, P; Ferreira da Silva, F; Almeida, D; Hoshino, M; Tanaka, H; Mogi, D; Tanioka, T; Mason, N J; Hoffmann, S V; Hubin-Franskin, M-J; Delwiche, J

    2015-02-14

    The electronic state spectroscopy of carbonyl sulphide, COS, has been investigated using high resolution vacuum ultraviolet photoabsorption spectroscopy and electron energy loss spectroscopy in the energy range of 4.0-10.8 eV. The spectrum reveals several new features not previously reported in the literature. Vibronic structure has been observed, notably in the low energy absorption dipole forbidden band assigned to the (4π←3π) ((1)Δ←(1)Σ(+)) transition, with a new weak transition assigned to ((1)Σ(-)←(1)Σ(+)) reported here for the first time. The absolute optical oscillator strengths are determined for ground state to (1)Σ(+) and (1)Π transitions. Based on our recent measurements of differential cross sections for the optically allowed ((1)Σ(+) and (1)Π) transitions of COS by electron impact, the optical oscillator strength f0 value and integral cross sections (ICSs) are derived by applying a generalized oscillator strength analysis. Subsequently, ICSs predicted by the scaling are confirmed down to 60 eV in the intermediate energy region. The measured absolute photoabsorption cross sections have been used to calculate the photolysis lifetime of carbonyl sulphide in the upper stratosphere (20-50 km). PMID:25681902

  17. Theoretical photoabsorption spectra of Ar n+ clusters

    NASA Astrophysics Data System (ADS)

    Doltsinis, Nikos L.; Knowles, Peter J.

    2000-08-01

    The photoabsorption spectra of selected Ar n+ clusters ( n=7, 8, 17, 19, 23) have been investigated theoretically using an extended Diatomics-in-Molecules approach including induced dipole - induced dipole and spin-orbit coupling interaction effects. Our calculations at 0 K confirm the experimentally observed spectral red-shift of the visible photoabsorption peak in the region 15< n<20 [Levinger et al., J. Chem. Phys. 89 (1988) 5654]. Furthermore, we have been able to reproduce the additional red-shift measured for 7⩽ n⩽9 [Haberland et al., Phys. Rev. Lett. 67 (1991) 3290] by carrying out finite temperature Monte Carlo simulations.

  18. Absolute triple-differential cross sections for ionization-excitation of helium

    SciTech Connect

    Bartschat, K.; Bray, I.; Fursa, D. V.; Stelbovics, A. T.

    2007-08-15

    Triple-differential cross sections (TDCSs) for electron-impact ionization of He(1s{sup 2}){sup 1}S leading to He{sup +}(1s) are calculated using the highly accurate convergent close-coupling (CCC) method for incident projectile energies of 268.6 and 112.6 eV, with at least one of the outgoing electrons having an energy of 44 eV. These results are used to obtain absolute TDCSs from the recent experimental data [Bellm et al., Phys. Rev. A 75, 042704 (2007)] for TDCS ratios of ionization with no excitation to ionization with excitation resulting in He{sup +}(n=2,3,4). The TDCSs can be used as comparison benchmarks in future studies, and already allow us to test the accuracy of the TDCSs obtained from the hybrid distorted-wave+R-matrix (close-coupling) model, which was fairly successful in predicting the ratios, using CCC for n=1 and experimental results for n=2,3,4.

  19. Absolute cross sections for dissociative electron attachment to HCN and DCN

    SciTech Connect

    May, O.; Kubala, D.; Allan, M.

    2010-07-15

    Absolute partial cross sections for the formation of CN{sup -} in dissociative electron attachment to HCN and DCN have been measured using a time-of-flight ion spectrometer combined with a trochoidal electron monochromator to be 940pm{sup 2} for CN{sup -}/HCN and 340pm{sup 2} for CN{sup -}/DCN at peaks of the bands due to the {sup 2{Pi}}-shape resonance. The dissociative electron attachment bands were then recorded under higher resolution, 60 meV, with a trochoidal monochromator plus quadrupole mass filter combination and found to have a nearly vertical onset at the threshold energy and to peak at 1.85 eV. Broad structure was observed on the bands, assigned to formation of vibrationally excited CN{sup -}, from which the branching ratios could be determined to be 1,0.49, and 0.22 for the formation of CN{sup -} in the v=0,1, and 2 states, respectively. The results are compared to the recent multidimensional ab initio calculations of Chourou and Orel [Phys. Rev. A 80, 032709 (2009)].

  20. Supplementary absolute differential cross sections for the excitation of atomic hydrogen's n=3 and 4 levels by electron impact

    SciTech Connect

    Sweeney, Christopher J.; Shyn, Tong W.; Grafe, Alan

    2004-05-01

    We have conducted measurements of absolute differential cross sections for the excitation of hydrogen atoms to their n=3(3S+3P+3D) and 4(4S+4P+4D+4F) levels. A modulated, crossed-beam method was employed, and the impact energies were 40 and 60 eV. Comparison of our results with those of others is quite favorable.

  1. Absolute total cross-sections for the scattering of 2-18-eV electrons by cesium atoms

    NASA Astrophysics Data System (ADS)

    Jaduszliwer, B.; Chan, Y. C.

    1992-01-01

    An atomic-recoil technique in a scattering-out mode is used to measure absolute total cross sections for the scattering of electrons by cesium atoms between 2 and 18 eV. A comparison of the results with those obtained by Visconti, Slevin, and Rubin (1971) indicate that the close-coupling calculations have yielded total cross sections which are consistently high over the covered energy range.

  2. Absolute total cross sections for the scattering of 2-18-eV electrons by cesium atoms

    NASA Astrophysics Data System (ADS)

    Jaduszliwer, B.; Chan, Y. C.

    1992-01-01

    Absolute total cross sections for the scattering of electrons by cesium atoms between 2 and 18 eV have been measured using the atomic-recoil technique in the scattering-out mode. Our results are somewhat lower than those of Visconti, Slevin, and Rubin [Phys. Rev. A 3, 1310 (1971)] above 2 eV.

  3. Measurements of absolute K-shell ionization cross sections and L-shell x-ray production cross sections of Ge by electron impact

    SciTech Connect

    Merlet, C.; Llovet, X.; Salvat, F.

    2004-03-01

    Results from measurements of absolute K-shell ionization cross sections and L{alpha} x-ray production cross sections of Ge by impact of electrons with kinetic energies ranging from the ionization threshold up to 40 keV are presented. The cross sections were obtained by measuring K{alpha} and L{alpha} x-ray intensities emitted from ultrathin Ge films deposited onto self-supporting carbon backing films. Recorded x-ray intensities were converted to absolute cross sections by using estimated values of the sample thicknesses, the number of incident electrons, and the detector efficiency. Experimental data are compared with the results of widely used simple analytical formulas, with calculated cross sections obtained from the plane-wave and distorted-wave Born approximations and with experimental data from the literature.

  4. ScaRaB: first results of absolute and cross calibration

    NASA Astrophysics Data System (ADS)

    Trémas, Thierry L.; Aznay, Ouahid; Chomette, Olivier

    2015-10-01

    ScaRaB (SCAnner for RAdiation Budget) is the name of three radiometers whose two first flight models have been launched in 1994 and 1997. The instruments were mounted on-board Russian satellites, METEOR and RESURS. On October 12th 2011, a last model has been launched from the Indian site of Sriharikota. ScaRaB is a passenger of MEGHA-TROPIQUES, an Indo-French joint Satellite Mission for studying the water cycle and energy exchanges in the tropics. ScaRaB is composed of four parallel and independent channels. Channel-2 and channel-3 are considered as the main ones. Channel-1 is dedicated to measure solar radiance (0.5 to 0.7 μm) while channel-4 (10 to 13 μm) is an infrared window. The absolute calibration of ScaRab is assured by internal calibration sources (black bodies and a lamp for channel-1). However, during the commissioning phase, the lamp used for the absolute calibration of channel-1 revealed to be inaccurate. We propose here an alternative calibration method based on terrestrial targets. Due to the spectral range of channel-1, only calibration over desert sites (temporal monitoring) and clouds (cross band) is suitable. Desert sites have been widely used for sensor calibration since they have a stable spectral response over time. Because of their high reflectances, the atmospheric effect on the upward radiance is relatively minimal. In addition, they are spatially uniform. Their temporal instability without atmospheric correction has been determined to be less than 1-2% over a year. Very-high-altitude (10 km) bright clouds are good validation targets in the visible and near-infrared spectra because of their high spectrally consistent reflectance. If the clouds are very high, there is no need to correct aerosol scattering and water vapor absorption as both aerosol and water vapor are distributed near the surface. Only Rayleigh scattering and ozone absorption need to be considered. This method has been found to give a 4% uncertainty. Radiometric cross

  5. Absolute Rayleigh scattering cross sections of gases and freons of stratospheric interest in the visible and ultraviolet regions

    NASA Technical Reports Server (NTRS)

    SHARDANAND; Rao, A. D. P.

    1977-01-01

    The laboratory measurements of absolute Rayleigh scattering cross sections as a function wavelength are reported for gas molecules He, Ne, Ar, N2, H2, O2, CO2, CH4 and for vapors of most commonly used freons CCl2F2, CBrF3, CF4, and CHClf2. These cross sections are determined from the measurements of photon scattering at an angle of 54 deg 44 min which yield the absolute values independent of the value of normal depolarization ratios. The present results show that in the spectral range 6943-3638A deg, the values of the Rayleigh scattering cross section can be extrapolated from one wavelength to the other using 1/lambda (4) law without knowing the values of the polarizabilities. However, such an extrapolation can not be done in the region of shorter wavelengths.

  6. Absolute differential and total cross sections for neutral fragments from dissociative collisions of triatomic hydrogen like ions on He

    NASA Astrophysics Data System (ADS)

    Yousif, F. B.; Fuentes, B. E.; Martínez, H.

    2010-12-01

    Neutral fragment products from dissociative collisions of triatomic hydrogen like ions incident on He atoms were studied. Absolute differential and total cross sections are reported here in the energy range of 1.00-5.00 keV and scattering angles between -5.0° and 5.0°. The differential cross sections show decreasing behaviour with a slight structure around 2.0°. The total cross sections for all triatomic molecular ions studied in this work are found to be comparable for the same velocity (E/M). The measured cross sections are between 0.7 × 10-17 cm2 and 0.9 × 10-16 cm2. The present results for the neutral total cross section correlate very well with previously measured total ions cross section for H+3, D+3 and HD+2 on He.

  7. Absolute cross sections for projectile electron loss accompanied by target multiple ionization in collisions of He+ with noble gases

    NASA Astrophysics Data System (ADS)

    Santos, A. C. F.; Sigaud, G. M.; Melo, W. S.; Sant'Anna, M. M.; Montenegro, E. C.

    2011-02-01

    Absolute cross sections for projectile electron loss accompanied by target multiple ionization in collisions between He+ ions and noble gases have been measured for energies between 1.0 and 3.5 MeV. The data have been compared with other absolute cross sections that exist in the literature for the same projectile, and with calculations for the screening mode (nucleus-electron interaction) using both perturbative (plane-wave Born approximation (PWBA)) and non-perturbative (extended classical-impulse free-collision model, sudden approximation and coupled-channel method) approaches, and for the antiscreening mode (electron-electron interaction) within the PWBA. The energy dependence of the average number of active electrons for the antiscreening has been described by means of a simple function, which is 'universal' for noble gases but projectile dependent. A previously developed method has been employed to obtain the number of active electrons for each target subshell in the high-velocity regime.

  8. Absolute cross sections for electronic excitations of cytosine by low energy electron impact

    PubMed Central

    Bazin, M.; Michaud, M.; Sanche, L.

    2013-01-01

    The absolute cross sections (CS) for electronic excitations of cytosine by electron impact between 5 and 18 eV were measured by electron-energy loss (EEL) spectroscopy of the molecule deposited at low coverage on an inert Ar substrate. The lowest EEL features found at 3.55 and 4.02 eV are ascribed to transitions from the ground state to the two lowest triplet 1 3A′(π→π*) and 2 3A′(π→π*) valence states of the molecule. Their energy dependent CS exhibit essentially a common maximum at about 6 eV with a value of 1.84 × 10−17 cm2 for the former and 4.94 × 10−17 cm2 for the latter. In contrast, the CS for the next EEL feature at 4.65 eV, which is ascribed to the optically allowed transition to the 2 1A′(π→π*) valence state, shows only a steep rise to about 1.04 × 10−16 cm2 followed by a monotonous decrease with the incident electron energy. The higher EEL features at 5.39, 6.18, 6.83, and 7.55 eV are assigned to the excitations of the 3 3, 1A′(π→π*), 4 1A′(π→π*), 5 1A′(π→π*), and 6 1A′(π→π*) valence states, respectively. The CS for the 3 3, 1A′ and 4 1A′ states exhibit a common enhancement at about 10 eV superimposed on a more or less a steep rise, reaching respectively a maximum of 1.27 and 1.79 × 10−16 cm2, followed by a monotonous decrease. This latter enhancement and the maximum seen at about 6 eV in the lowest triplet states correspond to the core-excited electron resonances that have been found by dissociative electron attachment experiments with cytosine in the gas phase. The weak EEL feature found at 5.01 eV with a maximum CS of 3.8 × 10−18 cm2 near its excitation threshold is attributed to transitions from the ground state to the 1 3, 1A″(n→π*) states. The monotonous rise of the EEL signal above 8 eV is attributed to the ionization of the molecule. It is partitioned into four excitation energy regions at about 8.55, 9.21, 9.83, and 11.53 eV, which correspond closely to the ionization energies of

  9. Absolute cross sections for vibrational excitations of cytosine by low energy electron impact

    PubMed Central

    Michaud, M.; Bazin, M.; Sanche, L.

    2013-01-01

    The absolute cross sections (CSs) for vibrational excitations of cytosine by electron impact between 0.5 and 18 eV were measured by electron-energy loss (EEL) spectroscopy of the molecule deposited at monolayer coverage on an inert Ar substrate. The vibrational energies compare to those that have been reported from IR spectroscopy of cytosine isolated in Ar matrix, IR and Raman spectra of poly-crystalline cytosine, and ab initio calculation. The CSs for the various H bending modes at 142 and 160 meV are both rising from their energy threshold up to 1.7 and 2.1 × 10−17 cm2 at about 4 eV, respectively, and then decrease moderately while maintaining some intensity at 18 eV. The latter trend is displayed as well for the CS assigned to the NH2 scissor along with bending of all H at 179 meV. This overall behavior in electron-molecule collision is attributed to direct processes such as the dipole, quadrupole, and polarization contributions, etc. of the interaction of the incident electron with a molecule. The CSs for the ring deformation at 61 meV, the ring deformation with N-H symmetric wag at 77 meV, and the ring deformations with symmetric bending of all H at 119 meV exhibit common enhancement maxima at 1.5, 3.5, and 5.5 eV followed by a broad hump at about 12 eV, which are superimposed on the contribution due to the direct processes. At 3.5 eV, the CS values for the 61-, 77-, and 119-meV modes reach 4.0, 3.0, and 4.5 × 10−17 cm2, respectively. The CS for the C-C and C-O stretches at 202 meV, which dominates in the intermediate EEL region, rises sharply until 1.5 eV, reaches its maximum of 5.7 × 10−17 cm2 at 3.5 eV and then decreases toward 18 eV. The present vibrational enhancements, correspond to the features found around 1.5 and 4.5 eV in electron transmission spectroscopy (ETS) and those lying within 1.5–2.1 eV, 5.2–6.8 eV, and 9.5–10.9 eV range in dissociative electron attachment (DEA) experiments with cytosine in gas phase. While the ETS features

  10. Absolute cross sections for the dissociation of hydrogen cluster ions in high-energy collisions with helium atoms

    SciTech Connect

    Eden, S.; Tabet, J.; Samraoui, K.; Louc, S.; Farizon, B.; Farizon, M.; Ouaskit, S.; Maerk, T. D.

    2006-02-15

    Absolute dissociation cross sections are reported for H{sub n}{sup +} clusters of varied mass (n=3,5,...,35) following collisions with He atoms at 60 keV/amu. Initial results have been published previously for a smaller range of cluster sizes [Ouaskit et al., Phys. Rev. A 49, 1484 (1994)]. The present extended study includes further experimental results, reducing the statistical errors associated with the absolute cross sections. The previously suggested quasilinear dependence of the H{sub n}{sup +} dissociation cross sections upon n is developed with reference to expected series of geometrical shells of H{sub 2} molecules surrounding a H{sub 3}{sup +} core. Recent calculations identify n=9 as corresponding to the first closed H{sub 2} shell [e.g., Stich et al., J. Chem. Phys. 107, 9482 (1997)]. Recurrence of the distinct characteristics observed in the dissociation-cross-section dependence upon cluster size around n=9 provides the basis for the presently proposed subsequent closed shells at n=15, 21, 27, and 33, in agreement with the calculations of Nagashima et al. [J. Phys. Chem. 96, 4294 (1992)].

  11. Absolute elastic differential electron scattering cross sections in the intermediate energy region. III - SF6 and UF6

    NASA Technical Reports Server (NTRS)

    Srivastava, S. K.; Trajmar, S.; Chutjian, A.; Williams, W.

    1976-01-01

    A recently developed technique has been used to measure the ratios of elastic differential electron scattering cross sections (DCS) for SF6 and UF6 to those of He at electron impact energies of 5, 10, 15, 20, 30, 40, 50, 60, and 75 eV and at scattering angles of 20 to 135 deg. In order to obtain the absolute values of DCS from these ratios, He DCS of McConkey and Preston have been employed in the 20 to 90 deg range. At angles in the 90 to 135 deg range the recently determined cross sections of Srivastava and Trajmar have been utilized. From these DCS, elastic integral and momentum transfer cross sections have been obtained.

  12. Absolute angle-differential elastic cross sections for electron collisions with diacetylene

    SciTech Connect

    Allan, M.; Winstead, C.; McKoy, V.

    2011-06-15

    We report measured and calculated differential elastic cross sections for collisions of low-energy electrons with diacetylene (1,3-butadiyne). A generally satisfactory agreement between theory and experiment has been found. The calculated cross sections provide interesting insight into the underlying resonant structure.

  13. A Preliminary Report on X-Ray Photoabsorption Coefficients andAtomic Scattering Factors for 92 Elements in the 10-10,000 eVRegion

    SciTech Connect

    Henke, B.L.; Davis, J.C.; Gullikson, E.M.; Perera, R.C.C.

    1988-11-01

    Based on currently available photoabsorption measurements and recent theoretical calculations by Doolen and Liberman (Physica Scripta 36, 77 (1987)), a revised (from ADNDT 27, 1 (1982)) best-fit determination of the photoabsorption cross sections is presented here for the elements Z=1 to Z=92 in the 10-10,000 eV range. The photoabsorption data used include those described in the Lockheed and DOE listings of research abstracts for the past ten years and those which have been recently added to the comprehensive NBS Measured Data Base (NBSIR 86-3461, Hubbell et al.). The best-fit curves are compared with both the compilation of measurements and the calculations by Doolen and Liberman. Using the photoabsorption curves, the atomic scattering factors have been calculated for the energy range 50-10,000 eV and are also presented in this report.

  14. Absolute cross sections for electronic excitation of pyrimidine by electron impact.

    PubMed

    Regeta, Khrystyna; Allan, Michael; Mašín, Zdeněk; Gorfinkiel, Jimena D

    2016-01-14

    We measured differential cross sections for electron-impact electronic excitation of pyrimidine, both as a function of electron energy up to 18 eV, and of scattering angle up to 180°. The emphasis of the present work is on recording detailed excitation functions revealing resonances in the excitation process. The differential cross sections were summed to obtain integral cross sections. These are compared to results of R-matrix calculations, which successfully reproduce both the magnitude of the cross section and the major resonant features. Comparison of the experiment to the calculated contributions of different symmetries to the integral cross section permitted assignment of several features to specific core-excited resonances. Comparison of the resonant structure of pyrimidine with that of benzene revealed pronounced similarities and thus a dominant role of π-π(∗) excited states and resonances. Electron energy loss spectra were measured as a preparation for the cross section measurements and vibrational structure was observed for some of the triplet states. A detailed analysis of the electronic excited states of pyrimidine is also presented. PMID:26772566

  15. Absolute Charge Transfer and Fragmentation Cross Sections in He{sup 2+}-C{sub 60} Collisions

    SciTech Connect

    Rentenier, A.; Moretto-Capelle, P.; Bordenave-Montesquieu, D.; Bordenave-Montesquieu, A.; Ruiz, L. F.; Diaz-Tendero, S.; Alcami, M.; Martin, F.; Zarour, B.; Hanssen, J.; Hervieux, P.-A.; Politis, M. F.

    2008-05-09

    We have determined absolute charge transfer and fragmentation cross sections in He{sup 2+}+C{sub 60} collisions in the impact-energy range 0.1-250 keV by using a combined experimental and theoretical approach. We have found that the cross sections for the formation of He{sup +} and He{sup 0} are comparable in magnitude, which cannot be explained by the sole contribution of pure single and double electron capture but also by contribution of transfer-ionization processes that are important even at low impact energies. The results show that multifragmentation is important only at impact energies larger than 40 keV; at lower energies, sequential C{sub 2} evaporation is the dominant process.

  16. Absolute cross sections for electron loss, electron capture, and multiple ionization in collisions of Li2+ with argon

    NASA Astrophysics Data System (ADS)

    Losqui, A. L. C.; Zappa, F.; Sigaud, G. M.; Wolff, W.; Sant'Anna, M. M.; Santos, A. C. F.; Luna, H.; Melo, W. S.

    2014-02-01

    Exclusive absolute cross sections for the electron loss and capture processes, accompanied by target multiple ionization and pure target multiple ionization, as well as total electron loss and capture cross sections, in collisions of Li2+ with Ar have been measured in the 0.5-3.5 MeV energy range. The experimental data of the total electron loss cross section are compared with theoretical results based on the plane-wave Born approximation and the free-collision model, and with the available experimental data. Some discrepancies are observed when comparing the experimental data with the theoretical models, which can be attributed to the competitive mechanisms that lead to electron loss. The dependences of the single-capture and transfer-ionization processes on the projectile charge state are similar to those observed for collisions between other low-charged light ions and noble-gas targets. The same behaviour is observed when one compares the present data for the single- and double-ionization cross sections with those for He2+ projectiles on Ar. These facts indicate that the dynamics of the collision does not seem to depend on the projectile species, so that few-electron projectiles may act as structureless point charges in the intermediate- to high-velocity regime.

  17. Measurement of the absolute vμ-CCQE cross section at the SciBooNE experiment

    SciTech Connect

    Aunion, Jose Luis Alcaraz

    2010-07-01

    This thesis presents the measurement of the charged current quasi-elastic (CCQE) neutrino-nucleon cross section at neutrino energies around 1 GeV. This measurement has two main physical motivations. On one hand, the neutrino-nucleon interactions at few GeV is a region where existing old data are sparse and with low statistics. The current measurement populates low energy regions with higher statistics and precision than previous experiments. On the other hand, the CCQE interaction is the most useful interaction in neutrino oscillation experiments. The CCQE channel is used to measure the initial and final neutrino fluxes in order to determine the neutrino fraction that disappeared. The neutrino oscillation experiments work at low neutrino energies, so precise measurement of CCQE interactions are essential for flux measurements. The main goal of this thesis is to measure the CCQE absolute neutrino cross section from the SciBooNE data. The SciBar Booster Neutrino Experiment (SciBooNE) is a neutrino and anti-neutrino scattering off experiment. The neutrino energy spectrum works at energies around 1 GeV. SciBooNE was running from June 8th 2007 to August 18th 2008. In that period, the experiment collected a total of 2.65 x 1020 protons on target (POT). This thesis has used full data collection in neutrino mode 0.99 x 1020 POT. A CCQE selection cut has been performed, achieving around 70% pure CCQE sample. A fit method has been exclusively developed to determine the absolute CCQE cross section, presenting results in a neutrino energy range from 0.2 to 2 GeV. The results are compatible with the NEUT predictions. The SciBooNE measurement has been compared with both Carbon (MiniBoonE) and deuterium (ANL and BNL) target experiments, showing a good agreement in both cases.

  18. Absolute Cross sections of Fe XVII x-ray transitions measured with the spare Astro-E microcalorimeter Array

    NASA Astrophysics Data System (ADS)

    Brown, G.; Boyce, K. R.; Kelley, R. L.; Porter, F. S.; Stahle, C. K.; Beiersdorfer, P.; Chen, H.; May, M.; Scofield, J.; Kahn, S. M.

    2002-04-01

    We have used the NASA/GSFC engineering model Astro-E microcalorimeter 6x6 array with the LLNL electron beam ion trap uc(ebit-i) to measure absolute excitation cross sections of Fe uc(xvii) L-shell x-ray transitions by normalizing to radiative recombination (RR). In the past, normalizing Fe uc(xvii) L-shell transitions to RR has not been possible because it is approximately 1000 times weaker than direct excitation, its emission often blends with emission from other charge states, and it is separated from direct excitation by greater than 500 eV. However, because of its large effective area, high resolution, large bandwidth, and long-time gain stability, the spare Astro-E microcalorimeter coupled with uc(ebit-i) has made measurement of absolute cross sections of Fe uc(xvii) L-shell transitons possible. We present the measured cross sections of two of the strongest lines observed in a plethora of astrophysical sources, the Fe uc(xvii) resonance and intercombination lines, located at 15.01 Å and 15.26 Årespectively. Our results provide stringent tests for atomic data present in spectral modeling packages and can be used to interpret high-resolution spectra provided by the Chandra X-Ray Observatory, XMM-Newton, and, in the near future, Astro-E2. Work by the UC-LLNL was performed under auspices of DOE under contract No. W-7405-Eng-48 and supported by NASA SARA grants to LLNL, GSFC, and Columbia University.

  19. Measurement of the absolute differential cross section of proton-proton elastic scattering at small angles

    NASA Astrophysics Data System (ADS)

    Mchedlishvili, D.; Chiladze, D.; Dymov, S.; Bagdasarian, Z.; Barsov, S.; Gebel, R.; Gou, B.; Hartmann, M.; Kacharava, A.; Keshelashvili, I.; Khoukaz, A.; Kulessa, P.; Kulikov, A.; Lehrach, A.; Lomidze, N.; Lorentz, B.; Maier, R.; Macharashvili, G.; Merzliakov, S.; Mikirtychyants, S.; Nioradze, M.; Ohm, H.; Prasuhn, D.; Rathmann, F.; Serdyuk, V.; Schroer, D.; Shmakova, V.; Stassen, R.; Stein, H. J.; Stockhorst, H.; Strakovsky, I. I.; Ströher, H.; Tabidze, M.; Täschner, A.; Trusov, S.; Tsirkov, D.; Uzikov, Yu.; Valdau, Yu.; Wilkin, C.; Workman, R. L.; Wüstner, P.

    2016-04-01

    The differential cross section for proton-proton elastic scattering has been measured at a beam kinetic energy of 1.0 GeV and in 200 MeV steps from 1.6 to 2.8 GeV for centre-of-mass angles in the range from 12°-16° to 25°-30°, depending on the energy. A precision in the overall normalisation of typically 3% was achieved by studying the energy losses of the circulating beam of the COSY storage ring as it passed repeatedly through the windowless hydrogen target of the ANKE magnetic spectrometer. It is shown that the data have a significant impact upon the results of a partial wave analysis. After extrapolating the differential cross sections to the forward direction, the results are broadly compatible with the predictions of forward dispersion relations.

  20. Measurement of the absolute differential cross section of proton–proton elastic scattering at small angles

    DOE PAGESBeta

    Mchedlishvili, D.; Chiladze, D.; Dymov, S.; Bagdasarian, Z.; Barsov, S.; Gebel, R.; Gou, B.; Hartmann, M.; Kacharava, A.; Keshelashvili, I.; et al

    2016-02-03

    The differential cross section for proton-proton elastic scattering has been measured at a beam kinetic energy of 1.0 GeV and in 200 MeV steps from 1.6 to 2.8 GeV for centre-of-mass angles in the range from 12°-16° to 25°-30°, depending on the energy. A precision in the overall normalisation of typically 3% was achieved by studying the energy losses of the circulating beam of the COSY storage ring as it passed repeatedly through the windowless hydrogen target of the ANKE magnetic spectrometer. It is shown that the data have a significant impact upon the results of a partial wave analysis.more » Furthermore, after extrapolating the differential cross sections to the forward direction, the results are broadly compatible with the predictions of forward dispersion relations.« less

  1. The realization of the dipole (γ, γ) method and its application to determine the absolute optical oscillator strengths of helium

    PubMed Central

    Xu, Long-Quan; Liu, Ya-Wei; Kang, Xu; Ni, Dong-Dong; Yang, Ke; Hiraoka, Nozomu; Tsuei, Ku-Ding; Zhu, Lin-Fan

    2015-01-01

    The dipole (γ, γ) method, which is the inelastic x-ray scattering operated at a negligibly small momentum transfer, is proposed and realized to determine the absolute optical oscillator strengths of the vanlence-shell excitations of atoms and molecules. Compared with the conventionally used photoabsorption method, this new method is free from the line saturation effect, which can seriously limit the accuracies of the measured photoabsorption cross sections for discrete transitions with narrow natural linewidths. Furthermore, the Bethe-Born conversion factor of the dipole (γ, γ) method varies much more slowly with the excitation energy than does that of the dipole (e, e) method. Absolute optical oscillator strengths for the excitations of 1s2 → 1 snp(n = 3 − 7) of atomic helium have been determined using the high-resolution dipole (γ, γ) method, and the excellent agreement of the present measurements with both those measured by the dipole (e, e) method and the previous theoretical calculations indicates that the dipole (γ, γ) method is a powerful tool to measure the absolute optical oscillator strengths of the valence-shell excitations of atoms and molecules. PMID:26678298

  2. A new method for measuring absolute total electron-impact cross sections with forward scattering corrections

    SciTech Connect

    Ma, C.; Liescheski, P.B.; Bonham, R.A. )

    1989-12-01

    In this article we describe an experimental technique to measure the total electron-impact cross section by measurement of the attenuation of an electron beam passing through a gas at constant pressure with the unwanted forward scattering contribution removed. The technique is based on the different spatial propagation properties of scattered and unscattered electrons. The correction is accomplished by measuring the electron beam attenuation dependence on both the target gas pressure (number density) and transmission length. Two extended forms of the Beer--Lambert law which approximately include the contributions for forward scattering and for forward scattering plus multiple scattering from the gas outside the electron beam were developed. It is argued that the dependence of the forward scattering on the path length through the gas is approximately independent of the model used to describe it. The proposed methods were used to determine the total cross section and forward scattering contribution from argon (Ar) with 300-eV electrons. Our results are compared with those in the literature and the predictions of theory and experiment for the forward scattering and multiple scattering contributions. In addition, Monte Carlo simulations were performed as a further test of the method.

  3. Photoabsorption and photoionization of chlorine dioxide

    SciTech Connect

    Flesch, R.; Ruehl, E.; Hottmann, K.; Baumgaertel, H. )

    1993-01-28

    Photoprocesses of chlorine dioxide in the near-UV have become highly important for stratospheric photoprocesses at high latitudes, especially in Antarctica. Chlorine dioxide has been identified among other absorbers because of its specific absorption cross section in the near-UV. Possible contributions of chlorine dioxide photochemistry to polar ozone depletion have been discussed recently. The high-resolution He I photoelectron spectrum and the absolute (vacuum-UV) absorption cross section (6-25 eV) as well as the ionic fragmentation of chlorine dioxide (OCIO) are reported. The photoelectron spectrum is interpreted in terms of exchange splitting effects of the various singlet and triplet cation states as well as by comparison to chemically related molecules. The vacuum-UV absorption spectrum shows different Rydberg series converging to the cation states. These Rydberg series and their vibrational progressions are assigned by term value arguments, dipole selection rules, and comparison with the photoelectron spectrum. Photoionization mass spectrometry is used for measurements of the ionization and fragmentation threshold of OCIO. The major fragment is ClO[sup +] which occurs above 13.4 eV. Thermomechanical data such as heats of formation and bond dissociation energies are derived. No evidence for isomerization of OClO[sup +] is found, as observed for the electronically excited neutral molecule. 54 refs., 6 figs., 7 tabs.

  4. Absolute vibrational cross sections for 1-19 eV electron scattering from condensed tetrahydrofuran (THF)

    NASA Astrophysics Data System (ADS)

    Lemelin, V.; Bass, A. D.; Cloutier, P.; Sanche, L.

    2016-02-01

    Absolute cross sections (CSs) for vibrational excitation by 1-19 eV electrons impacting on condensed tetrahydrofuran (THF) were measured with a high-resolution electron energy loss spectrometer. Experiments were performed under ultra-high vacuum (3 × 10-11 Torr) at a temperature of about 20 K. The magnitudes of the vibrational CSs lie within the 10-17 cm2 range. Features observed near 4.5, 9.5, and 12.5 eV in the incident energy dependence of the CSs were compared to the results of theoretical calculations and other experiments on gas and solid-phase THF. These three resonances are attributed to the formation of shape or core-excited shape resonances. Another maximum observed around 2.5 eV is not found in the calculations but has been observed in gas-phase studies; it is attributed to the formation of a shape resonance.

  5. Enhanced photoabsorption efficiency of incomplete nanoshells.

    PubMed

    Venkatapathi, Murugesan; Dastidar, Sudipta G; Bharath, P; Roy, Arindam; Ghosh, Anupam

    2013-09-01

    The rather low scattering or extinction efficiency of small nanoparticles, metallic and otherwise, is significantly enhanced when they are adsorbed on a larger core particle. But the photoabsorption by particles with varying surface area fractions on a larger core particle is found to be limited by saturation. It is found that the core-shell particle can have a lower absorption efficiency than a dielectric core with its surface partially nucleated with absorbing particles-an "incomplete nanoshell" particle. We have both numerically and experimentally studied the optical efficiencies of titania (TiO2) nucleated in various degrees on silica (SiO2) nanospheres. We show that optimal surface nucleation over cores of appropriate sizes and optical properties will have a direct impact on the applications exploiting the absorption and scattering properties of such composite particles. PMID:23988933

  6. State densities with linear momentum and their application to preequilibrium and photoabsorption reactions

    SciTech Connect

    Chadwick, M.B. ); Oblozinsky, P. . Fyzikalny Ustav)

    1991-01-01

    We discuss the concept of state densities with linear momentum and describe their application to preequilibrium reaction theory as well as nuclear photoabsorption via the quasideuteron mechanism. An exciton model is presented for particle emission in nucleon-induced reactions in which linear momentum conversion is included. The nucleon emission contributions from the first two preequilibrium stages are calculated by determining exact particle-hole state densities with a specific energy and linear momentum in a Fermi-gas model of the nucleus. Angular distributions arise naturally from our treatment and do not have to be added in an ad hoc way. The angular distributions that we obtain from the first two preequilibrium stages are identical to those found using the Kikuchi-Kawai quasifree scattering kernel. Since many preequilibrium analyses are based upon an equidistant single-particle model of the nucleus, we also determine the state densities wit linear momentum (and hence angular distributions) in such a model. A no-parameter quasideuteron model of photoabsorption is presented in which the Levinger parameter and Pauli-blocking function are determined theoretically, using state densities with linear momentum. Comparisons with data are shown, and the temperature dependence of the photoabsorption cross section is calculated. 45 refs., 6 figs.

  7. Measurement of the Absolute Elastic and Inelastic Differential Neutron Cross Sections for 23Na Between 2 and 4 MeV

    NASA Astrophysics Data System (ADS)

    Kumar, A.; Chakraborty, A.; Crider, B. P.; McEllistrem, M. T.; Peters, E. E.; Prados-Estévez, F. M.; Yates, S. W.; Hicks, S. F.; Kersting, L. J.; Luke, C. J.; McDonough, P. J.; Sigillito, A. J.; Vanhoy, J. R.

    2013-03-01

    Elastic and inelastic neutron scattering angular distributions have been measured from 23Na for incident neutron energies between 2 and 4 MeV at the University of Kentucky using neutron time-of-flight techniques. The cross sections obtained are important for applications in nuclear reactor development and other areas, and they are an energy region in which existing data are very sparse. Absolute cross sections were obtained by normalizing Na angular distributions to the well-known np cross sections.

  8. Absolute total electron scattering cross sections for N/sub 2/ between 0. 5 and 50 eV

    SciTech Connect

    Kennerly, R.E.

    1980-06-01

    Absolute total electron scattering cross sections for N/sub 2/ from 0.5 to 50 eV have been measured with an estimated uncertainty of +- 3% using a transmission time-of-flight method previously described. The results are compared to previous experimental results and to recent calculations. The positions of the /sup 2/Pi/sub g/ resonance peaks were determined with much greater accuracy ( +- 15 meV) than in previous transmission measurements. The structure reported by Golden (1966) below the /sup 2/Pi/sub g/ resonance was clearly not present, indicating that, if real, these features are not a property of the N/sub 2/ ground vibronic state. The shape resonance predicted at 11 eV by Dill and Dehmer (1977) was not seen, perhaps because it was too weakly manifested in the total cross section. A weak broad band centered at 25 eV may be interpreted as being due to a sigma/sub u/ shape resonance as predicted by Dehmer, Siegel, Welch, and Dill.

  9. Absolute Total Cross Section Measurements for Electron Scattering on GeH4 and SiH4 Molecules

    NASA Astrophysics Data System (ADS)

    Zejko, Pawel. Mo.; Kasperski, Grzegorz; Szmytkowski, Czeslaw

    1996-10-01

    We have measured absolute grand total electron--scattering cross section for GeH4 and SiH4 molecules in the energy range of 0.75--250 eV and 0.6--250 eV, respectively, using the linear transmission experimental setup(A.M. Krzysztofowicz and Cz. Szmytkowski 1995 J. Phys. B 28) 1593. The general character of both obtained total cross section (TCS) functions is similar. For germane TCS dramatically increases from 12× 10-20 m^2 at 0.8 eV up to nearly 59× 10-20 m^2 at the 3.8 eV maximum. For silane the maximum (57× 10-20 m^2) is localized near 2.9 eV. These structures are partly attributable to the existence of short-lived negative-ion resonant states. From 10 eV to the highest applied energy TCS' decrease monotonically with increasing impact energy E, and above 50 eV the total cross sections change like E-0.5. None low-energy e^--GeH4 experiment is available for comparison. Above 75 eV our results are in good agreement with the recent intermediate-energy TCS measurements of Karwasz(G.P. Karwasz 1995 J. Phys. B 28) 1301 and with calculations of Baluja et al(K.L. Baluja et al) 1992 Europhys. Lett. 17 139. There is also reasonably agreement of present e^--SiH4 data with available experimental results.

  10. Easy Absolute Values? Absolutely

    ERIC Educational Resources Information Center

    Taylor, Sharon E.; Mittag, Kathleen Cage

    2015-01-01

    The authors teach a problem-solving course for preservice middle-grades education majors that includes concepts dealing with absolute-value computations, equations, and inequalities. Many of these students like mathematics and plan to teach it, so they are adept at symbolic manipulations. Getting them to think differently about a concept that they…

  11. Absolute absorption cross sections of ozone at 300 K, 228 K and 195 K in the wavelength region 185-240 nm

    NASA Technical Reports Server (NTRS)

    Yoshino, K.; Parkinson, W. H.; Freeman, D. E.

    1992-01-01

    An account is given of progress of work on absorption cross section measurements of ozone at 300 K, 228 K and 195 K in the wavelength region 185-240 nm. In this wavelength region, the penetration of solar radiation into the Earth's atmosphere is controlled by O2 and O3. The transmitted radiation is available to dissociate trace species such as halocarbons and nitrous oxide. We have recently measured absolute absorption cross sections of O3 in the wavelength region 240-350 nm (Freeman et al., 1985; Yoshino et al., 1988). We apply these proven techniques to the determination of the absorption cross section of O3 at 300 K, 228 K and 195 K throughout the wavelength region 185-240 nm. A paper titled 'Absolute Absorption Cross Section Measurements of Ozone in the Wavelength Region 185-254 nm and the Temperature Dependence' has been submitted for publication in the Journal of Geophysical Research.

  12. Measurement of Absolute Excitation Cross Sections in Highly-Charged Ions Using Electron Energy Loss and Merged Beams

    NASA Technical Reports Server (NTRS)

    Chutjian, A.; Smith, Steven J.; Lozano, J.

    2002-01-01

    There is increasing emphasis during this decade on understanding energy balance and phenomena observed in high electron temperature plasmas. The UV spectral return from FUSE, the X-ray spectral return from the HETG on Chandra and the LETGS 011 XMM-Newton are just beginning. Line emissions are almost entirely from highly-charged ions (HCIs) of C, N, 0, Ne, Mg, S, Si, Ca, and Fe. The Constellation-X mission will provide X-ray spectroscopy up to photon energies of 0.12 nm (10 keV) where primary line emitters will be HCIs. A variety of atomic parameters are required to model the stellar and solar plasma. These include cross sections for excitation, ionization, charge-exchange, X-ray emission, direct and indirect recombination, lifetimes and branching ratios, and dependences on l, m mixing by external E and B fields. In almost all cases the atomic quantities are calculated, and few comparisons to experiment have been carried out. Collision strengths and Einstein A-values are required to convert the observed spectral intensities to electron temperatures and densities in the stellar plasma. The JPL electron energy-loss and merged beam approach has been used to measure absolute collision strengths in a number of ions, with critical comparison made to the best available theories.

  13. Determination of relative and absolute photoionization cross-sections in multiply-charged Ba^n+ Ions

    NASA Astrophysics Data System (ADS)

    Bizau, J.-M.; Cubaynes, D.; Esteva, J. M.; Wuilleumier, F. J.; Marmoret, R.; Petrault, L.; Remond, C.; Couillaud, C.; Compant La Fontaine, A.; Blancard, C.; Hitz, D.; Ludwig, P.; Deshmukh, P. C.; Zhou, H.-L.; Manson, S. T.

    2001-05-01

    Following our first photoionization measurements for the multiply-charged Xe^n+ [1] and Ba^2+ [2] ions, we introduced several modifications in the experimental set-up to allow us to measure absolute cross sections for multiply-charged ions. Photoionization studies of barium ions up to Ba^6+ were performed using synchrotron radiation emitted by an undulator of the Super ACO storage ring in Orsay and an ECR ion source. Collapse of the 4f (ɛ f) orbitals has been observed to occur faster than for Xe^n+: the relative intensity of transitions to continuum states is negligible already for Ba^3+ ions, discrete transitions to 4d^95s^25p^mnf states then dominating the measured spectra. The experimental results are in good agreement with the results of MCDF calculations for the discrete transitions and, in Ba^2+, with RRPA calculations for transitions to continuum states. 1. J.-M. Bizau et al., Phys. Rev. Lett. 84, 435 (2000). 2. J.-M. Bizau et al., Bull. Am. Phys. Soc. 45, 61 (2000).

  14. Absolute photofission cross sections for /sup 235,238/U in the energy range 11. 5--30 MeV

    SciTech Connect

    Ries, H.; Mank, G.; Drexler, J.; Heil, R.; Huber, K.; Kneissl, U.; Ratzek, R.; Stroeher, H.; Weber, T.; Wilke, W.

    1984-06-01

    Absolute photofission cross sections of /sup 235/U and /sup 238/U have been measured with quasimonoenergetic photons from e/sup +/ annihilation and direct fragment detection between 11.5 and 30 MeV. The results obtained in the energy range of the giant dipole resonance (up to 18 MeV) are compared with those from previous experiments.

  15. Electronic state spectroscopy by high-resolution vacuum ultraviolet photoabsorption, He(I) photoelectron spectroscopy and ab initio calculations of ethyl acetate

    NASA Astrophysics Data System (ADS)

    Śmialek, Malgorzata A.; Łabuda, Marta; Guthmuller, Julien; Hubin-Franskin, Marie-Jeanne; Delwiche, Jacques; Hoffmann, Søren Vrønning; Jones, Nykola C.; Mason, Nigel J.; Limão-Vieira, Paulo

    2016-06-01

    The high-resolution vacuum ultraviolet photoabsorption spectrum of ethyl acetate, C4H8O2, is presented over the energy range 4.5-10.7 eV (275.5-116.0 nm). Valence and Rydberg transitions and their associated vibronic series observed in the photoabsorption spectrum, have been assigned in accordance with new ab initio calculations of the vertical excitation energies and oscillator strengths. Also, the photoabsorption cross sections have been used to calculate the photolysis lifetime of this ester in the upper stratosphere (20-50 km). Calculations have also been carried out to determine the ionisation energies and fine structure of the lowest ionic state of ethyl acetate and are compared with a newly recorded photoelectron spectrum (from 9.5 to 16.7 eV). Vibrational structure is observed in the first photoelectron band of this molecule for the first time.

  16. Absolute cross sections for binary-encounter electron ejection by 95-MeV/u {sup 36}Ar{sup 18+} penetrating carbon foils

    SciTech Connect

    De Filippo, E.; Lanzano, G.; Aiello, S.; Arena, N.; Geraci, M.; Pagano, A.; Rothard, H.; Volant, C.; Anzalone, A.; Giustolisi, F.

    2003-08-01

    Doubly differential electron velocity spectra induced by 95-MeV/u {sup 36}Ar{sup 18+} from thin carbon foils were measured at GANIL (Caen, France) by means of the ARGOS multidetector and the time-of-flight technique. The spectra allow us to determine absolute singly differential cross sections as a function of the emission angle. Absolute doubly differential cross sections for binary encounter electron ejection from C targets are compared to a transport theory, which is based on the relativistic electron impact approximation for electron production and which accounts for angular deflection, energy loss, and also energy straggling of the transmitted electrons. For the thinnest targets, the measured peak width is in good agreement with experimental data obtained with a different detection technique. The theory underestimates the peak width but provides (within a factor of 2) the correct peak intensity. For the thickest target, even the peak shape is well reproduced by theory.

  17. Measured Absolute Cross Section of Charge Transfer in H + H2+ at Low Energy: Signature of vi = 2 and Trajectory Effects

    NASA Astrophysics Data System (ADS)

    Strom, R. A.; Bacani, K. G.; Chi, R. M.; Heczko, S. L.; Singh, B. N.; Tobar, J. A.; Vassantachart, A. K.; Andrianarijaona, V. M.; Seely, D. G.; Havener, C. C.

    2015-04-01

    Measurements of absolute cross sections of charge transfer (CT) in H + H2+--> H+ + H2 were conducted at the merged-beam apparatus at Oak Ridge National Laboratory (ORNL) in Oak Ridge, Tennessee, which can reliably create and access collision energies as low as 0.1 eV/u. The measured absolute cross section shows evidence of trajectory effects at low energy. Also, the comparison to state-to-state calculations (PRA 67 022708 (2003) suggests a strong contribution from vi = 2 of the H2+that are produced by the electron cyclotron resonance ion source. The data analysis will be presented here. Research supported by the NASA Solar & Heliospheric Physics Program NNH07ZDA001N, the Office of Fusion Energy Sciences and the Division of Chemical Sciences, Geosciences, and Biosciences, Office of Basic Energy Sciences of the U.S. Department of Energy, the National Science Foundation through Grant No. PHY-1068877.

  18. Measurement and Calculation of Absolute Single- and Multiple-Charge-Exchange Cross Sections for Feq+ Ions Impacting CO and CO2

    SciTech Connect

    Simcic, J.; Mawhorter, R. J.; Cadez, I.; Greenwood, J. B.; Chutjian, A.; Smith, S. J.

    2010-01-01

    Absolute cross sections are reported for single, double, and triple charge exchange of Feq+ (q=5- 13) ions with CO and CO2. The highly-charged Fe ions are generated in an electron cyclotron resonance ion source. Absolute data are derived from knowledge of the target gas pressure, target path length, and incident and charge-exchanged ion currents. Experimental results are compared with new calculations of these cross sections in the n-electron classical trajectory Monte-Carlo approximation, in which the ensuing radiative and non-radiative cascades are approximated with scaled hydrogenic transition probabilities and scaled Auger rates. The present data are needed in astrophysical applications of solar- and stellar-wind charge-exchange with comets, planetary atmospheres, and circumstellar clouds.

  19. Absolute K-shell ionization cross sections and L{alpha} and L{beta}{sub 1} x-ray production cross sections of Ga and As by 1.5-39-keV electrons

    SciTech Connect

    Merlet, C.; Llovet, X.; Fernandez-Varea, J. M.

    2006-06-15

    Absolute K-shell ionization and L{alpha} and L{beta}{sub 1} x-ray production cross sections for Ga and As have been measured for incident electrons in the energy range from 1.5 to 39 keV. The cross sections were deduced from K{alpha}, L{alpha}, and L{beta}{sub 1} x-ray intensities emitted from ultrathin GaAs samples deposited onto self-supporting carbon films. The x-ray intensities were measured on an electron microprobe equipped with several wavelength-dispersive spectrometers and were converted into absolute cross sections by using estimated values of the target thickness, spectrometer efficiency, and number of incident electrons. Experimental results are compared with cross sections calculated from the plane-wave and distorted-wave Born approximations, the relativistic binary-encounter-Bethe model, the results of two widely used simple analytical formulas, and, whenever possible, experimental data from the literature.

  20. Absolute cascade-free cross-sections for the 2S to 2P transition in Zn(+) using electron-energy-loss and merged-beams methods

    NASA Technical Reports Server (NTRS)

    Smith, Steven J.; Man, K.-F.; Chutjian, A.; Mawhorter, R. J.; Williams, I. D.

    1991-01-01

    Absolute cascade-free excitation cross-sections in an ion have been measured for the resonance 2S to 2P transition in Zn(+) using electron-energy-loss and merged electron-ion beams methods. Measurements were carried out at electron energies of below threshold to 6 times threshold. Comparisons are made with 2-, 5-, and 15-state close-coupling and distorted-wave theories. There is good agreement between experiment and the 15-state close-coupling cross-sections over the energy range of the calculations.

  1. Measurement of the Absolute Elastic and Inelastic Differential Neutron Cross Sections for 23Na between 2 and 4 MeV

    NASA Astrophysics Data System (ADS)

    Kumar, Ajay; McEllistrem, M. T.; Crider, B. P.; Peters, E. E.; Prados-Estevez, F. M.; Chakraborty, A.; Yates, S. W.; Sigillito, A.; McDonough, P. J.; Kersting, L. J.; Luke, C. J.; Hicks, S. F.; Vanhoy, J. R.

    2011-10-01

    Elastic and inelastic neutron scattering angular distributions for 23Na sample were measured at the University of Kentucky using the time-of-flight (ToF) technique, between 2 and 4 MeV incident neutron energies.Normalization of yields into scattering cross sections was accomplished by comparison of Na yields to the yields obtained from hydrogen in polyethylene samples via the well-known n-p scattering cross sections.The 3H(p,n) differential cross sections are used to determine the energy-dependent efficiency of the main detector. Because the efficiency of this detector appears as a ratio in the comparison of scattered yields from different samples, the absolute values of the 3H(p,n) cross sections are not critical, but their energy dependence is. This work is supported by the U.S. DOE contract no. DE-AC07-051D14517.

  2. Absolute (γ,p0) and (γ,p1) cross sections and angular distributions for the light, deformed nucleus 19F

    NASA Astrophysics Data System (ADS)

    Kerkhove, E.; Ferdinande, H.; van de Vyver, R.; Berkvens, P.; van Otten, P.; van Camp, E.; Ryckbosch, D.

    1984-06-01

    Absolute (γ,p0) and (γ,p1) differential cross sections for 19F have been measured at seven angles in the energy interval between 13.4 and 25.8 MeV. A sum of Legendre polynomials was fitted to the angular distributions to deduce the angular distribution coefficients. The (γ,p0) and (γ,p1) cross sections have a similar magnitude and represent a minor fraction of the total photoproton channel. The global difference between the two cross sections is attributed to configurational splitting effects. From the (γ,p0) angular distribution coefficients, an E2 cross section was estimated, contributing about 37% to the total E2 energy-weighted sum rule.

  3. Absolute single and multiple charge exchange cross sections for highly charged C, O, and Ne ions on H{sub 2}O, CO, and CO{sub 2}

    SciTech Connect

    Mawhorter, R. J.; Chutjian, A.; Djuric, N.; Hossain, S.; MacAskill, J. A.; Smith, S. J.; Simcic, J.; Cravens, T. E.; Lisse, C. M.; Williams, I. D.

    2007-03-15

    Reported herein are measured absolute single, double, and triple charge exchange (CE) cross sections for the highly charged ions (HCIs) C{sup q+} (q=5,6), O{sup q+} (q=6,7,8), and Ne{sup q+} (q=7,8) colliding with the molecular species H{sub 2}O, CO, and CO{sub 2}. Present data can be applied to interpreting observations of x-ray emissions from comets as they interact with the solar wind. As such, the ion impact energies of 7.0q keV (1.62-3.06 keV/amu) are representative of the fast solar wind, and data at 1.5q keV for O{sup 6+} (0.56 keV/amu) on CO and CO{sub 2} and 3.5q keV for O{sup 5+} (1.09 keV/amu) on CO provide checks of the energy dependence of the cross sections at intermediate and typical slow solar wind velocities. The HCIs are generated within a 14 GHz electron cyclotron resonance ion source. Absolute CE measurements are made using a retarding potential energy analyzer, with measurement of the target gas cell pressure and incident and final ion currents. Trends in the cross sections are discussed in light of the classical overbarrier model (OBM), extended OBM, and with recent results of the classical trajectory Monte Carlo theory.

  4. Tracing multiple scattering patterns in absolute (e,2e) cross sections for H{sub 2} and He over a 4{pi} solid angle

    SciTech Connect

    Ren, X.; Senftleben, A.; Pflueger, T.; Dorn, A.; Ullrich, J.; Colgan, J.; Pindzola, M. S.; Al-Hagan, O.; Madison, D. H.; Bray, I.; Fursa, D. V.

    2010-09-15

    Absolutely normalized (e,2e) measurements for H{sub 2} and He covering the full solid angle of one ejected electron are presented for 16 eV sum energy of both final state continuum electrons. For both targets rich cross-section structures in addition to the binary and recoil lobes are identified and studied as a function of the fixed electron's emission angle and the energy sharing among both electrons. For H{sub 2} their behavior is consistent with multiple scattering of the projectile as discussed before [Al-Hagan et al., Nature Phys. 5, 59 (2009)]. For He the binary and recoil lobes are significantly larger than for H{sub 2} and partly cover the multiple scattering structures. To highlight these patterns we propose a alternative representation of the triply differential cross section. Nonperturbative calculations are in good agreement with the He results and show discrepancies for H{sub 2} in the recoil peak region. For H{sub 2} a perturbative approach reasonably reproduces the cross-section shape but deviates in absolute magnitude.

  5. K-shell photoabsorption coefficients of O2, CO2, CO, and N2O

    NASA Technical Reports Server (NTRS)

    Barrus, D. M.; Blake, R. L.; Burek, A. J.; Chambers, K. C.; Pregenzer, A. L.

    1979-01-01

    The total photoabsorption coefficient has been measured from 500 to 600 eV around the K edge of oxygen in gases O2, CO2, CO, and N2O by means of a gold continuum source and crystal spectrometer with better than 1-eV resolution. The cross sections are dominated by discrete molecular-orbital transitions below the K-edge energy. A few Rydberg transitions were barely detectable. Broad shape resonances appear at or above the K edge. Additional broad, weak features above the K edge possibly arise from shake up. Quantitative results are given that have about 10% accuracy except on the very strong peaks. All the measured features are discussed in relation to other related measurements and theory.

  6. K-SHELL PHOTOIONIZATION AND PHOTOABSORPTION OF Ne, Mg, Si, S, Ar, AND Ca

    SciTech Connect

    Witthoeft, M. C.; Kallman, T. R.; Bautista, M. A.; Mendoza, C.; Palmeri, P.; Quinet, P.

    2009-05-15

    We present extensive computations of photoabsorption and photoionization cross sections across the K-edge of Ne, Mg, Si, S, Ar, and Ca ions with less than 11 electrons. The calculations are performed using the Breit-Pauli R-matrix method and include the effects of radiative and Auger damping by means of an optical potential. The wave functions are constructed from single-electron orbital bases obtained using a Thomas-Fermi-Dirac statistical model potential. Configuration interaction is considered among all fine-structure levels within the n = 2 complex. The damping processes affect the resonances converging to the K thresholds causing them to display symmetric profiles of constant width that smear the otherwise sharp edge at the photoionization thresholds.

  7. Absolute fragmentation cross sections in atom-molecule collisions: Scaling laws for non-statistical fragmentation of polycyclic aromatic hydrocarbon molecules

    SciTech Connect

    Chen, T.; Gatchell, M.; Stockett, M. H.; Alexander, J. D.; Schmidt, H. T.; Cederquist, H.; Zettergren, H.; Zhang, Y.; Rousseau, P.; Maclot, S.; Delaunay, R.; Adoui, L.; Domaracka, A.; Huber, B. A.

    2014-06-14

    We present scaling laws for absolute cross sections for non-statistical fragmentation in collisions between Polycyclic Aromatic Hydrocarbons (PAH/PAH{sup +}) and hydrogen or helium atoms with kinetic energies ranging from 50 eV to 10 keV. Further, we calculate the total fragmentation cross sections (including statistical fragmentation) for 110 eV PAH/PAH{sup +} + He collisions, and show that they compare well with experimental results. We demonstrate that non-statistical fragmentation becomes dominant for large PAHs and that it yields highly reactive fragments forming strong covalent bonds with atoms (H and N) and molecules (C{sub 6}H{sub 5}). Thus nonstatistical fragmentation may be an effective initial step in the formation of, e.g., Polycyclic Aromatic Nitrogen Heterocycles (PANHs). This relates to recent discussions on the evolution of PAHNs in space and the reactivities of defect graphene structures.

  8. Fast-electron ejection from C, Ni, Ag and Au foils by 36 Ar 18 + (95 MeV/u): Measurements of absolute cross-sections

    NASA Astrophysics Data System (ADS)

    de Filippo, E.; Lanzanó, G.; Rothard, H.; Volant, C.; Aiello, S.; Anzalone, A.; Arena, N.; Geraci, M.; Giustolisi, F.; Pagano, A.

    2004-07-01

    Doubly differential electron velocity spectra induced by 36Ar18 + (95 MeV/ u) from thin target foils (C, Ni, Ag, Au) were measured at GANIL (Caen, France) by means of the ARGOS multidetector and the time-of-flight technique. The main features observed in the forward spectra are convoy electrons, binary-encounter electrons, and (for the Au target only) a high-velocity tail which we attribute to a “Fermi shuttle” acceleration mechanism. Backward spectra do not show distinct structures. The spectra allow us to determine absolute singly differential cross-sections as a function of the target material and the emission angle. The convoy electron yield increases with the target atomic number, but for C their yield is so small that our experiment is not able to detect them. Absolute doubly differential cross-sections for binary-encounter electron ejection from C targets are well described by a transport theory which is based on the relativistic electron impact approximation (EIA) for electron production and which accounts for angular deflection, energy loss and energy straggling of the transmitted electrons.

  9. A novel double-focusing time-of-flight mass spectrometer for absolute recoil ion cross sections measurements.

    PubMed

    Sigaud, L; de Jesus, V L B; Ferreira, Natalia; Montenegro, E C

    2016-08-01

    In this work, the inclusion of an Einzel-like lens inside the time-of-flight drift tube of a standard mass spectrometer coupled to a gas cell-to study ionization of atoms and molecules by electron impact-is described. Both this lens and a conical collimator are responsible for further focalization of the ions and charged molecular fragments inside the spectrometer, allowing a much better resolution at the time-of-flight spectra, leading to a separation of a single mass-to-charge unit up to 100 a.m.u. The procedure to obtain the overall absolute efficiency of the spectrometer and micro-channel plate detector is also discussed. PMID:27587105

  10. A Near-Threshold Shape Resonance in the Valence-Shell Photoabsorption of Linear Alkynes.

    PubMed

    Jacovella, U; Holland, D M P; Boyé-Péronne, S; Gans, Bérenger; de Oliveira, N; Ito, K; Joyeux, D; Archer, L E; Lucchese, R R; Xu, Hong; Pratt, S T

    2015-12-17

    The room-temperature photoabsorption spectra of a number of linear alkynes with internal triple bonds (e.g., 2-butyne, 2-pentyne, and 2- and 3-hexyne) show similar resonances just above the lowest ionization threshold of the neutral molecules. These features result in a substantial enhancement of the photoabsorption cross sections relative to the cross sections of alkynes with terminal triple bonds (e.g., propyne, 1-butyne, 1-pentyne, ...). Based on earlier work on 2-butyne [ Xu et al., J. Chem. Phys. 2012, 136, 154303 ], these features are assigned to excitation from the neutral highest occupied molecular orbital (HOMO) to a shape resonance with g (l = 4) character and approximate π symmetry. This generic behavior results from the similarity of the HOMOs in all internal alkynes, as well as the similarity of the corresponding gπ virtual orbital in the continuum. Theoretical calculations of the absorption spectrum above the ionization threshold for the 2- and 3-alkynes show the presence of a shape resonance when the coupling between the two degenerate or nearly degenerate π channels is included, with a dominant contribution from l = 4. These calculations thus confirm the qualitative arguments for the importance of the l = 4 continuum near threshold for internal alkynes, which should also apply to other linear internal alkynes and alkynyl radicals. The 1-alkynes do not have such high partial waves present in the shape resonance. The lower l partial waves in these systems are consistent with the broader features observed in the corresponding spectra. PMID:26469080

  11. Valence and ionic lowest-lying electronic states of ethyl formate as studied by high-resolution vacuum ultraviolet photoabsorption, He(I) photoelectron spectroscopy, and ab initio calculations

    SciTech Connect

    Śmiałek, M. A.; Duflot, D.; Mason, N. J.; Hoffmann, S. V.; Jones, N. C.; Limão-Vieira, P.

    2014-09-14

    The highest resolution vacuum ultraviolet photoabsorption spectrum of ethyl formate, C{sub 2}H{sub 5}OCHO, yet reported is presented over the wavelength range 115.0–275.5 nm (10.75–4.5 eV) revealing several new spectral features. Valence and Rydberg transitions and their associated vibronic series, observed in the photoabsorption spectrum, have been assigned in accordance with new ab initio calculations of the vertical excitation energies and oscillator strengths. Calculations have also been carried out to determine the ionization energies and fine structure of the lowest ionic state of ethyl formate and are compared with a newly recorded He(I) photoelectron spectrum (from 10.1 to 16.1 eV). New vibrational structure is observed in the first photoelectron band. The photoabsorption cross sections have been used to calculate the photolysis lifetime of ethyl formate in the upper stratosphere (20–50 km)

  12. Valence and ionic lowest-lying electronic states of ethyl formate as studied by high-resolution vacuum ultraviolet photoabsorption, He(I) photoelectron spectroscopy, and ab initio calculations.

    PubMed

    Śmiałek, M A; Łabuda, M; Guthmuller, J; Hubin-Franskin, M-J; Delwiche, J; Duflot, D; Mason, N J; Hoffmann, S V; Jones, N C; Limão-Vieira, P

    2014-09-14

    The highest resolution vacuum ultraviolet photoabsorption spectrum of ethyl formate, C2H5OCHO, yet reported is presented over the wavelength range 115.0-275.5 nm (10.75-4.5 eV) revealing several new spectral features. Valence and Rydberg transitions and their associated vibronic series, observed in the photoabsorption spectrum, have been assigned in accordance with new ab initio calculations of the vertical excitation energies and oscillator strengths. Calculations have also been carried out to determine the ionization energies and fine structure of the lowest ionic state of ethyl formate and are compared with a newly recorded He(I) photoelectron spectrum (from 10.1 to 16.1 eV). New vibrational structure is observed in the first photoelectron band. The photoabsorption cross sections have been used to calculate the photolysis lifetime of ethyl formate in the upper stratosphere (20-50 km). PMID:25217920

  13. Rydberg states of chloroform studied by VUV photoabsorption spectroscopy

    NASA Astrophysics Data System (ADS)

    Singh, Param Jeet; Shastri, Aparna; D'Souza, R.; Jagatap, B. N.

    2013-11-01

    The VUV photoabsorption spectra of CHCl3 and CDCl3 in the energy region 6.2-11.8 eV (50,000-95,000 cm-1) have been investigated using synchrotron radiation from the Indus-1 source. Rydberg series converging to the first four ionization limits at 11.48, 11.91, 12.01 and 12.85 eV corresponding to excitation from the 1a2, 4a1, 4e, 3e, orbitals of CHCl3 respectively are identified and analyzed. Quantum defect values are observed to be consistent with excitation from the chlorine lone pair orbitals. Vibrational progressions observed in the region of 72,500-76,500 cm-1 have been reassigned to ν3 and combination modes of ν3+ν6 belonging to the 1a2→4p transition in contrast to earlier studies where they were assigned to a ν3 progression superimposed on the 3e→4p Rydberg transition. The assignments are further confirmed based on isotopic substitution studies on CDCl3 whose VUV photoabsorption spectrum is reported here for the first time. The frequencies of the ν3 and ν6 modes in the 4p Rydberg state of CHCl3 (CDCl3) are proposed to be ~454 (409) cm-1 and~130 (129) cm-1 respectively based on the vibronic analysis. DFT calculations of neutral and ionic ground state vibrational frequencies support the vibronic analysis. Experimental spectrum is found to be in good agreement with that predicted by TDDFT calculations. This work presents a consolidated analysis of the VUV photoabsorption spectrum of chloroform.

  14. Angular distribution of molecular K-shell Auger electrons: Spectroscopy of photoabsorption anisotropy

    SciTech Connect

    Dill, D.; Swanson, J.R.; Wallace, S.; Dehmer, J.L.

    1980-10-27

    The angular distribution of Auger electrons emitted in the decay of molecular K-shell vacancies created by photoabsorption is predicted to be a direct probe of the anisotropy of molecular photoabsorption. The sigma..--> pi.. discrete absorption of the sigma..-->..sigma f-wave shape resonance in N/sub 2/ and CO are given as examples.

  15. Formation of magnetoconvection by photoabsorptive methods in ferrofluid layers

    NASA Astrophysics Data System (ADS)

    Zablotsky, Dmitry; Mezulis, Ansis; Blums, Elmars

    2013-04-01

    A periodic concentration grating was induced in a layer of ferrofluid by photoabsorption and thermophoresis under the action of the applied uniform magnetic field. The application of the external field causes the appearance of an internal demagnetizing field within the layer and of magnetic forces due to the non-uniform distribution of concentration. The induced magnetic forces cause the appearance of parasitic microconvection within the layer. The experimental observations of the formation stage of the grating are interpreted to explain magnetoconvection, making use of numerical simulations.

  16. Absolute optical oscillator strengths for the electronic excitation of atoms at high resolution: Experimental methods and measurements for helium

    SciTech Connect

    Chan, W.F.; Cooper, G.; Brion, C.E. )

    1991-07-01

    An alternative method is described for the measurement of absolute optical oscillator strengths (cross sections) for electronic excitation of free atoms and molecules throughout the discrete region of the valence-shell spectrum at high energy resolution (full width at half maximum of 0.048 eV). The technique, utilizing the virtual-photon field of a fast electron inelastically scattered at negligible momentum transfer, avoids many of the difficulties associated with the various direct optical techniques that have traditionally been used for absolute optical oscillator strength measurements. The method is also free of the bandwidth (line saturation) effects that can seriously limit the accuracy of photoabsorption cross-section measurements for discrete transitions of narrow linewidth obtained using the Beer-Lambert law ({ital I}{sub 0}/{ital I}=exp({ital nl}{sigma}{sub {ital p}})). Since the line-saturation effects are not widely appreciated and are only usually considered in the context of peak heights, a detailed analysis of this problem is presented, with consideration of the integrated cross section (oscillator strength) over the profile of each discrete peak.

  17. Absolute Doubly Differential Cross Sections for Ejection of Electrons in - and Five-Body Collisions of 20 TO 114-KEV Protons on Atomic and Molecular Hydrogen.

    NASA Astrophysics Data System (ADS)

    Kerby, George W., III

    A crossed-beam experiment was performed to detect ejected electrons from ground-state atomic and molecular hydrogen after collisions with 20- to 114-keV protons. Because a pure atomic hydrogen target is not readily attainable, a method has been devised which yields atomic to molecular hydrogen doubly differential cross section (DDCS) ratios. Since the molecular hydrogen DDCS's were independently measured, the atomic cross sections could be directly calculated. Absolute cross sections differential in electron energy and angle were measured for electron energies ranging from 1.5 to 400 eV and scattering angles from 15^circ to 165^circ with respect to the fast beam. Electrons and ions were energy analyzed by an electrostatic hemispherical analyzer, which has an energy resolution of 5% and is rotatable in the scattering plane about the collision center. Atomic hydrogen is produced by a radio-frequency discharge of the type devised by J. Slevin. Hydrogen gas effuses from a 1 mm diameter nozzle in a nearly cos theta distribution. The projectile beam intersects the thermal gas targets 4 mm below the tip of the nozzle. Dissociation fractions of 74% and atomic hydrogen densities of 7 times 10 ^{11} cm^ {-3} were typical. The fraction of dissociated hydrogen was measured by detecting the reduced 9-eV ion signal from the molecular target when the RF is on. This characteristic ion signal originates from the coulomb breakup of the molecule and dissociative channels of excited H _sp{2}{+}. An auxiliary experiment was performed to determine the target densities with the aid of a low-resolution magnetic mass spectrometer after the slow recoil ions were extracted from the collision volume by a weak electric field. Comparisons of the atomic cross sections are made with theories such as the classical-trajectory Monte Carlo (CTMC) method, the plane-wave Born approximation (PWBA) and the continuum-distorted-wave eikonal-initial-state (CDW-EIS) approximation.

  18. Photoabsorption spectrum of helium trimer cation—Theoretical modeling

    NASA Astrophysics Data System (ADS)

    Kalus, René; Karlický, František; Lepetit, Bruno; Paidarová, Ivana; Gadea, Florent Xavier

    2013-11-01

    The photoabsorption spectrum of He_3^+ is calculated for two semiempirical models of intracluster interactions and compared with available experimental data reported in the middle UV range [H. Haberland and B. von Issendorff, J. Chem. Phys. 102, 8773 (1995)]. Nuclear delocalization effects are investigated via several approaches comprising quantum samplings using either exact or approximate (harmonic) nuclear wavefunctions, as well as classical samplings based on the Monte Carlo methodology. Good agreement with the experiment is achieved for the model by Knowles et al., [Mol. Phys. 85, 243 (1995); Knowles et al., Mol. Phys. 87, 827 (1996)] whereas the model by Calvo et al., [J. Chem. Phys. 135, 124308 (2011)] exhibits non-negligible deviations from the experiment. Predictions of far UV absorption spectrum of He_3^+, for which no experimental data are presently available, are reported for both models and compared to each other as well as to the photoabsorption spectrum of He_2^+. A simple semiempirical point-charge approximation for calculating transition probabilities is shown to perform well for He_3^+.

  19. Photoabsorption spectrum of helium trimer cation--theoretical modeling.

    PubMed

    Kalus, René; Karlický, František; Lepetit, Bruno; Paidarová, Ivana; Gadea, Florent Xavier

    2013-11-28

    The photoabsorption spectrum of He3(+) is calculated for two semiempirical models of intracluster interactions and compared with available experimental data reported in the middle UV range [H. Haberland and B. von Issendorff, J. Chem. Phys. 102, 8773 (1995)]. Nuclear delocalization effects are investigated via several approaches comprising quantum samplings using either exact or approximate (harmonic) nuclear wavefunctions, as well as classical samplings based on the Monte Carlo methodology. Good agreement with the experiment is achieved for the model by Knowles et al., [Mol. Phys. 85, 243 (1995); Mol. Phys. 87, 827 (1996)] whereas the model by Calvo et al., [J. Chem. Phys. 135, 124308 (2011)] exhibits non-negligible deviations from the experiment. Predictions of far UV absorption spectrum of He3(+), for which no experimental data are presently available, are reported for both models and compared to each other as well as to the photoabsorption spectrum of He2(+). A simple semiempirical point-charge approximation for calculating transition probabilities is shown to perform well for He3(+). PMID:24289357

  20. Photoabsorption spectrum of helium trimer cation—Theoretical modeling

    SciTech Connect

    Kalus, René; Karlický, František; Lepetit, Bruno; Paidarová, Ivana; Gadea, Florent Xavier

    2013-11-28

    The photoabsorption spectrum of He{sub 3}{sup +} is calculated for two semiempirical models of intracluster interactions and compared with available experimental data reported in the middle UV range [H. Haberland and B. von Issendorff, J. Chem. Phys. 102, 8773 (1995)]. Nuclear delocalization effects are investigated via several approaches comprising quantum samplings using either exact or approximate (harmonic) nuclear wavefunctions, as well as classical samplings based on the Monte Carlo methodology. Good agreement with the experiment is achieved for the model by Knowles et al., [Mol. Phys. 85, 243 (1995); Mol. Phys. 87, 827 (1996)] whereas the model by Calvo et al., [J. Chem. Phys. 135, 124308 (2011)] exhibits non-negligible deviations from the experiment. Predictions of far UV absorption spectrum of He{sub 3}{sup +}, for which no experimental data are presently available, are reported for both models and compared to each other as well as to the photoabsorption spectrum of He{sub 2}{sup +}. A simple semiempirical point-charge approximation for calculating transition probabilities is shown to perform well for He{sub 3}{sup +}.

  1. Absolute Zero

    NASA Astrophysics Data System (ADS)

    Donnelly, Russell J.; Sheibley, D.; Belloni, M.; Stamper-Kurn, D.; Vinen, W. F.

    2006-12-01

    Absolute Zero is a two hour PBS special attempting to bring to the general public some of the advances made in 400 years of thermodynamics. It is based on the book “Absolute Zero and the Conquest of Cold” by Tom Shachtman. Absolute Zero will call long-overdue attention to the remarkable strides that have been made in low-temperature physics, a field that has produced 27 Nobel Prizes. It will explore the ongoing interplay between science and technology through historical examples including refrigerators, ice machines, frozen foods, liquid oxygen and nitrogen as well as much colder fluids such as liquid hydrogen and liquid helium. A website has been established to promote the series: www.absolutezerocampaign.org. It contains information on the series, aimed primarily at students at the middle school level. There is a wealth of material here and we hope interested teachers will draw their student’s attention to this website and its substantial contents, which have been carefully vetted for accuracy.

  2. Compton scattering from nuclei and photo-absorption sum rules

    NASA Astrophysics Data System (ADS)

    Gorchtein, Mikhail; Hobbs, Timothy; Londergan, J. Timothy; Szczepaniak, Adam P.

    2011-12-01

    We revisit the photo-absorption sum rule for real Compton scattering from the proton and from nuclear targets. In analogy with the Thomas-Reiche-Kuhn sum rule appropriate at low energies, we propose a new “constituent quark model” sum rule that relates the integrated strength of hadronic resonances to the scattering amplitude on constituent quarks. We study the constituent quark model sum rule for several nuclear targets. In addition, we extract the α=0 pole contribution for both proton and nuclei. Using the modern high-energy proton data, we find that the α=0 pole contribution differs significantly from the Thomson term, in contrast with the original findings by Damashek and Gilman.

  3. Model for analytical calculation of nuclear photoabsorption at intermediate energies

    NASA Astrophysics Data System (ADS)

    Hütt, M.-Th.; Milstein, A. I.; Schumacher, M.

    1997-02-01

    The universal curve {σ}/{A} of nuclear photoabsorption is investigated within a Fermi gas model of nuclear matter. An energy range from pion threshold up to 400 MeV is considered. The interactions between nucleon, pion, Δ-isobar and photon are considered in the non-relativistic approximation with corrections of the order {1}/{M} taken into account with respect to proton mass. Analytical expressions are obtained, in which the influence of nuclear correlations and two-nucleon contributions is studied explicitly. The contributions of real and virtual pions are found to be sufficient to obtain agreement with experimental data in this energy range. An extension of the model calculation to nucleon knock-out reactions is discussed.

  4. Absolute Summ

    NASA Astrophysics Data System (ADS)

    Phillips, Alfred, Jr.

    Summ means the entirety of the multiverse. It seems clear, from the inflation theories of A. Guth and others, that the creation of many universes is plausible. We argue that Absolute cosmological ideas, not unlike those of I. Newton, may be consistent with dynamic multiverse creations. As suggested in W. Heisenberg's uncertainty principle, and with the Anthropic Principle defended by S. Hawking, et al., human consciousness, buttressed by findings of neuroscience, may have to be considered in our models. Predictability, as A. Einstein realized with Invariants and General Relativity, may be required for new ideas to be part of physics. We present here a two postulate model geared to an Absolute Summ. The seedbed of this work is part of Akhnaton's philosophy (see S. Freud, Moses and Monotheism). Most important, however, is that the structure of human consciousness, manifest in Kenya's Rift Valley 200,000 years ago as Homo sapiens, who were the culmination of the six million year co-creation process of Hominins and Nature in Africa, allows us to do the physics that we do. .

  5. Valence and Ionic Lowest-Lying Electronic States of Isobutyl Formate Studied by High-Resolution Vacuum Ultraviolet Photoabsorption, Photoelectron Spectroscopy, and Ab Initio Calculations.

    PubMed

    Śmiałek, M A; Łabuda, M; Guthmuller, J; Hoffmann, S V; Jones, N C; MacDonald, M A; Zuin, L; Mason, N J; Limão-Vieira, P

    2015-08-13

    The highest resolution vacuum ultraviolet photoabsorption spectrum of isobutyl formate, C5H10O2, yet reported is presented over the energy range 4.5-10.7 eV (275.5-118.0 nm) revealing several new spectral features. Valence and Rydberg transitions and their associated vibronic series observed in the photoabsorption spectrum have been assigned in accordance with new ab initio calculations of the vertical excitation energies and oscillator strengths. Calculations have also been carried out to determine the ionization energies and fine structure of the lowest ionic state of isobutyl formate and are compared with a newly recorded photoelectron spectrum (from 9.0 to 27.0 eV). The value of the first ionization energy was determined to be 10.508 eV (adiabatic) and 10.837 eV (vertical). New vibrational structure is observed in the first photoelectron band, predominantly resulting from C-O and C═O stretches of the molecule. The photoabsorption cross sections have been used to calculate the photolysis lifetime of isobutyl formate in the upper stratosphere (20-50 km), indicating that the hydroxyl radical processes will be the main loss process for isobutyl formate. PMID:26176891

  6. High resolution absolute absorption cross sections of the B ̃(1)A'-X ̃(1)A' transition of the CH2OO biradical.

    PubMed

    Foreman, Elizabeth S; Kapnas, Kara M; Jou, YiTien; Kalinowski, Jarosław; Feng, David; Gerber, R Benny; Murray, Craig

    2015-12-28

    Carbonyl oxides, or Criegee intermediates, are formed from the gas phase ozonolysis of alkenes and play a pivotal role in night-time and urban area atmospheric chemistry. Significant discrepancies exist among measurements of the strong B ̃(1)A'-X ̃(1)A' electronic transition of the simplest Criegee intermediate, CH2OO in the visible/near-UV. We report room temperature spectra of the B ̃(1)A'-X ̃(1)A' electronic absorption band of CH2OO acquired at higher resolution using both single-pass broadband absorption and cavity ring-down spectroscopy. The new absorption spectra confirm the vibrational structure on the red edge of the band that is absent from ionization depletion measurements. The absolute absorption cross sections over the 362-470 nm range are in good agreement with those reported by Ting et al. Broadband absorption spectra recorded over the temperature range of 276-357 K were identical within their mutual uncertainties, confirming that the vibrational structure is not due to hot bands. PMID:26595457

  7. Laboratory measurements and modeling of molecular photoabsorption in the ultraviolet for planetary atmospheres applications: diatomic sulfur and sulfur monoxide

    NASA Astrophysics Data System (ADS)

    Stark, Glenn

    2016-07-01

    Our research program comprises the measurement and modeling of ultraviolet molecular photoabsorption cross sections with the highest practical resolution. It supports efforts to interpret and model observations of planetary atmospheres. Measurement and modeling efforts on diatomic sulfur (S _{2}) and sulfur monoxide (SO) are in progress. S _{2}: Interpretations of atmospheric (Io, Jupiter, cometary comae) S _{2} absorption features are hindered by a complete lack of laboratory cross section data in the ultraviolet. We are working to quantify the photoabsorption spectrum of S _{2} from 240 to 300 nm based on laboratory measurements and theoretical calculations. We have constructed an experimental apparatus to produce a stable column of S _{2} vapor at a temperature of 800 K. High-resolution measurements of the absorption spectrum of the strong B - X system of S _{2} were completed using the NIST VUV-FTS at Gaithersburg, Maryland. These measurements are currently being incorporated into a coupled-channel model of the absorption spectrum of S _{2} to quantify the contributions from individual band features and to establish the mechanisms responsible for the strong predissociation signature of the B - X system. A successful coupled channels model can then be used to calculate the B - X absorption spectrum at any temperature. SO: There has been a long-standing need for high-resolution cross sections of sulfur monoxide radicals in the ultraviolet and vacuum ultraviolet regions, where the molecule strongly predissociates, for modeling the atmospheres of Io and Venus, and most recently for understanding sulfur isotope effects in the ancient (pre-O _{2}) atmosphere of Earth. We have produced a measurable column of SO in a continuous-flow DC discharge cell, using SO _{2} as a parent molecule. Photoabsorption measurements were recently recorded on the DESIRS beamline of the SOLEIL synchrotron, taking advantage of the high-resolution VUV-FTS on that beamline. A number of

  8. Theoretical Calculations of Photoabsorption of Several Alicyclic Molecules in the Vacuum Ultraviolet Region

    SciTech Connect

    Matsuzawa, Nobuyuki; Ishitani, Akihiko; Dixon, David A.; Uda, Tsuyoshi

    2001-06-13

    In order to aid in the design of transparent materials for use as photoresists for F2 lithography (157 nm), we have performed time-dependent density functional theory (TD-DFT) calculations of the photoabsorption of molecules in the vacuum ultraviolet region. The application of this TD-DFT method to the prediction of photoabsorption was benchmarked using model molecules such as formaldehyde, and an empirical equation for correcting the calculated transition energy was obtained. The TD-DFT method with the empirical correction equation provides dramatically more accurate results than those obtained with the CIS (single-excitation configuration interaction) method, which we employed in previous studies. We used it to predict the photoabsorption of various molecules such as methanol, t-butylalcohol, acetic acid, methyl acetate, cycloalkane, norbonane, tricyclodecane, tetrahydropyrane, adamantane, maleic anhydride and their fluorinated derivatives.

  9. Large photocurrents in GaN porous structures with a redshift of the photoabsorption edge

    NASA Astrophysics Data System (ADS)

    Sato, Taketomo; Kumazaki, Yusuke; Kida, Hirofumi; Watanabe, Akio; Yatabe, Zenji; Matsuda, Soichiro

    2016-01-01

    Photoresponse and photoabsorption properties of GaN porous structures were investigated by measuring photocurrent and spectroscopic photoabsorption under monochromatic light with various wavelengths. The measured photocurrents on the porous GaN electrodes were larger than those on the planar electrodes due to the unique features of the former electrode, such as large surface area and low photoreflectance properties. Moreover, the photocurrents were observed even under illumination with wavelength of 380 nm, corresponding to photon energy of 3.26 eV, which is 130 meV lower than the bandgap energy of bulk GaN. A potential simulation revealed that a high-electric field was induced at the pore tips due to modification of the potential in the porous structures. The observed redshift of the photoabsorption edge can be qualitatively explained by the Franz-Keldysh effect.

  10. Detecting the formation of single-walled carbon nanotube rings by photoabsorption spectroscopy

    NASA Astrophysics Data System (ADS)

    Hida, Akira; Suzuki, Takayuki; Ishibashi, Koji

    2016-08-01

    Photoabsorption spectroscopy was conducted on single-walled carbon nanotubes (SWNTs) during the formation of ring structures. The absorption bands observed before starting the formation gradually shifted while broadening in the middle. When they finally disappeared, it was found, via atomic force microscopy observations, that almost all SWNTs were transformed into rings. The spectral changes were assumed to be due to the changes in the electronic states of SWNTs. This idea was supported by the results of an investigation using a scanning tunneling microscope. It could be said that photoabsorption spectroscopy is useful for detecting ring formation in situ.

  11. Assessment of experimental d-PIGE γ-ray production cross sections for 12C, 14N and 16O and comparison with absolute thick target yields

    NASA Astrophysics Data System (ADS)

    Csedreki, L.; Halász, Z.; Kiss, Á. Z.

    2016-08-01

    Measured differential cross sections for deuteron induced γ-ray emission from the reactions 12C(d,pγ)13C, (Eγ = 3089 keV), 14N(d,pγ)15N (Eγ = 8310 keV) and 16O(d,pγ)17O (Eγ = 871 keV) available in the literature were assessed. In order to cross check the assessed γ-ray production cross section data, thick target γ-yields calculated from the differential cross sections were compared with available measured thick target yields. Recommended differential cross section data for each reaction were deduced for particle induced γ-ray emission (PIGE) applications.

  12. Teaching Absolute Value Meaningfully

    ERIC Educational Resources Information Center

    Wade, Angela

    2012-01-01

    What is the meaning of absolute value? And why do teachers teach students how to solve absolute value equations? Absolute value is a concept introduced in first-year algebra and then reinforced in later courses. Various authors have suggested instructional methods for teaching absolute value to high school students (Wei 2005; Stallings-Roberts…

  13. Communication: Rovibrationally selected absolute total cross sections for the reaction H2O+(X2B1; v1+v2+v3+ = 000; N+Ka+Kc+) + D2: Observation of the rotational enhancement effect

    NASA Astrophysics Data System (ADS)

    Xu, Yuntao; Xiong, Bo; Chang, Yih Chung; Ng, C. Y.

    2012-12-01

    By employing the newly established vacuum ultraviolet laser pulsed field ionization-photoion (PFI-PI) double quadrupole-double octopole ion guide apparatus, we have measured the rovibrationally selected absolute total cross sections of the ion-molecule reaction H2O+(X2B1; v1+v2+v3+ = 000; N+Ka+Kc+) + D2 → H2DO+ + D in the center-of-mass collision energy (Ecm) range of 0.05-10.00 eV. The pulsing scheme used for the generation of PFI-PIs has made possible the preparation of reactant H2O+(X2B1; v1+v2+v3+ = 000) ions in single N+Ka+Kc+ rotational levels with high kinetic energy resolutions. The absolute total cross sections observed in different N+Ka+Kc+ levels with rotational energies in the range of 0-200 cm-1 were found to exhibit a significant rotational enhancement on the reactivity for the titled reaction. In contrast, the measured cross sections reveal a decreasing trend with increasing Ecm, indicating that the rotational enhancement observed is not a total energy effect, but a dynamical effect. Furthermore, the rotational enhancement is found to be more pronounced as Ecm is decreased. This experiment provided evidence that the coupling of the core rotational angular momentum with the orbital angular momentum could play a role in chemical reactivity, particularly at low Ecm.

  14. The efficacy of safety barriers for children: absolute efficacy, time to cross and action modes in children between 19 and 75 months.

    PubMed

    Cordovil, R; Barreiros, J; Vieira, F; Neto, C

    2009-09-01

    We examined the efficacy of safety barriers by testing their capabilities to prevent or delay crossing. Children between 19 and 75 months tried to climb different barriers selected for their age group, which represented the most common types of panel and horizontal bars barriers available on the market. Success or failure in crossing, time to cross and crossing techniques were analysed. Barrier characteristics' influenced its restraining efficacy. Children's success rate varied between 10% and 95.3%. None of the barriers assured a considerable protective delay. Three major action modes were identified: head over waist (HOW), head and waist (HAW) and head under waist (HUW). Generally, children adopted the safer action mode, HOW, to cross most barriers. Younger children often adopted unstable action mode in barriers with crossable gaps. Although some standards might need to be re-evaluated, there are no childproof barriers. Barriers are time-delaying devices that cannot substitute supervision and education. PMID:19941212

  15. Vacuum ultraviolet electron impact excitation of the styrene molecule: cross sections and oscillator strengths

    NASA Astrophysics Data System (ADS)

    Boechat-Roberty, H. M.; Lucas, C. A.; Lopes, M. C. A.; Rocco, M. L. M.; de Souza, G. G. B.

    2009-05-01

    The vacuum ultraviolet electronic excitation of the styrene molecule has been studied in the 0-50 eV energy range, using angle-resolved electron-energy-loss spectroscopy at an incident energy of 1 keV. Intense new features have been observed at 10.3, 11.8, 13.7 and 17.1 eV. They were tentatively assigned to high-energy transitions originating from σ electrons or to double excitations involving π electrons. The absolute generalized oscillator strengths and absolute inelastic differential cross sections have been determined for the band centred at 5.3 eV, associated with the 2,3 1A'<--1 1A' transitions. The absolute elastic differential cross section has also been determined over an angular range of 2.5°-22.0°. The valence photoabsorption spectrum of styrene, derived from the electron-energy-loss spectrum, is compared to a previously measured benzene spectrum in the 3-45 eV energy range.

  16. Absolute cross sections for near-threshold electron-impact excitation of the 2s{sup 2}S{r_arrow}2p{sup 2}P transition in C{sup 3+}

    SciTech Connect

    Bannister, M.E.; Chung, Y.; Djuric, N.; Wallbank, B.; Woitke, O.; Zhou, S.; Dunn, G.H.; Smith, A.C.

    1998-01-01

    Absolute total cross sections for electron-impact excitation of the 2s{sup 2}S{r_arrow}2p{sup 2}P transition in C{sup 3+} were measured from 7.35 eV to 8.45 eV using the merged electron-ion-beams energy-loss technique. The results settle the discrepancy between two previous experiments using the crossed-beams fluorescence method, being in very good agreement with the older results [P. O. Taylor, D. Gregory, G. H. Dunn, R. A. Phaneuf, and D. H. Crandall, Phys. Rev. Lett. {bold 39}, 1256 (1977)] but less so with the more recent ones [D. W. Savin, L. D. Gardner, D. B. Reisenfeld, A. R. Young, and J. L. Kohl, Phys. Rev. A {bold 51}, 2162 (1995)]. The present measurements are also in good agreement with unitarized Coulomb-Born and close-coupling calculations. {copyright} {ital 1998} {ital The American Physical Society}

  17. K-shell photoabsorption and photoionisation of trace elements. I. Isoelectronic sequences with electron number 3 ≤N ≤ 11

    NASA Astrophysics Data System (ADS)

    Palmeri, P.; Quinet, P.; Mendoza, C.; Bautista, M. A.; Witthoeft, M. C.; Kallman, T. R.

    2016-05-01

    Context. With the recent launching of the Hitomi X-ray space observatory, K lines and edges of chemical elements with low cosmic abundances, namely F, Na, P, Cl, K, Sc, Ti, V, Cr, Mn, Co, Cu and Zn, can be resolved and used to determine important properties of supernova remnants, galaxy clusters and accreting black holes and neutron stars. Aims: The second stage of the present ongoing project involves the computation of the accurate photoabsorption and photoionisation cross sections required to interpret the X-ray spectra of such trace elements. Methods: Depending on target complexity and computer tractability, ground-state cross sections are computed either with the close-coupling Breit-Pauli R-matrix method or with the autostructure atomic structure code in the isolated-resonance approximation. The intermediate-coupling scheme is used whenever possible. In order to determine a realistic K-edge behaviour for each species, both radiative and Auger dampings are taken into account, the latter being included in the R-matrix formalism by means of an optical potential. Results: Photoabsorption and total and partial photoionisation cross sections are reported for isoelectronic sequences with electron numbers 3 ≤ N ≤ 11. The Na sequence (N = 11) is used to estimate the contributions from configurations with a 2s hole (i.e. [2s]μ) and those containing 3d orbitals, which will be crucial when considering sequences with N > 11. Conclusions: It is found that the [2s]μ configurations must be included in the target representations of species with N ≥ 11 as they contribute significantly to the monotonic background of the cross section between the L and K edges. Configurations with 3d orbitals are important in rendering an accurate L edge, but they can be practically neglected in the K-edge region.

  18. Eosinophil count - absolute

    MedlinePlus

    Eosinophils; Absolute eosinophil count ... the white blood cell count to give the absolute eosinophil count. ... than 500 cells per microliter (cells/mcL). Normal value ranges may vary slightly among different laboratories. Talk ...

  19. Photoabsorption and photoemission of magnesium diboride at the Mg K edge

    NASA Astrophysics Data System (ADS)

    Prince, K. C.; Feyer, V.; Tadich, A.; Thomsen, L.; Cowie, B. C. C.

    2009-10-01

    The Mg K edge photoabsorption spectrum and the B 1s, Mg 1s, Mg 2p and valence band photoemission spectra of polycrystalline magnesium diboride have been measured. The photoabsorption spectra of the diboride and the oxide, which is present as an impurity, were separated by measuring the Auger electron partial yield at electron energies characteristic of each phase. The spectra are consistent with published calculations of the density of unoccupied p symmetry states. Better agreement is obtained with calculations for the ground state of the system than with ones for the excited state. Valence band photoemission spectra were measured at photon energies corresponding to core resonances, but, within the signal to noise level of the spectra, no resonant enhancement was observed. This is consistent with the delocalized nature of the valence band.

  20. Semi-empirical calculations on the photoabsorption spectra of Xe +n

    NASA Astrophysics Data System (ADS)

    Doltsinis, Nikos L.

    The semi-empirical Diatomics-in-Molecules method has been employed to calculate the photoabsorption spectra of selected Xe+n (n = 3,4,13,19) clusters making use of diatomic potential energy curves derived from purely experimental data. This model is demonstrated to reproduce the photoabsorption spectra in the visible spectral region measured by Haberland and co-workers [1991, Phys. Rev. Lett., 67, 3290] while revealing additional absorption bands in the ultraviolet spectral region for all cluster sizes. In the case of Xe3 + a further, weak maximum in the infrared is observed. Moreover, it has been proven that the lowest energy peak in the visible for cluster sizes n > 5 is due to a trimeric and not as previously believed due to a tetrameric ion core.

  1. Stereoselective and Regiodivergent Allylic Suzuki-Miyaura Cross-Coupling of 2-Ethoxydihydropyranyl Boronates: Synthesis and Confirmation of Absolute Stereochemistry of Diospongin B.

    PubMed

    Rybak, Taras; Hall, Dennis G

    2015-09-01

    Oxygen-containing heterocycles such as pyrans are a common substructure present in a variety of natural products and pharmaceutical drugs. Highly functionalized 4- and 6-aryl/heteroaryl dihydropyran derivatives are assembled by a highly stereoselective, ligand-controlled regiodivergent sp(3)-sp(2) Suzuki-Miyaura cross-coupling of a 2-ethoxy dihydropyranyl boronate derived from a catalytic enantioselective inverse-electron-demand oxa[4 + 2] cycloaddition. The scope and selectivity of this method were assessed along with an application to a concise total synthesis of the diarylheptanoid natural product diospongin B. PMID:26291472

  2. Absolute cross section for loss of supercoiled topology induced by 10 eV electrons in highly uniform /DNA/1,3-diaminopropane films deposited on highly ordered pyrolitic graphite

    NASA Astrophysics Data System (ADS)

    Boulanouar, Omar; Fromm, Michel; Bass, Andrew D.; Cloutier, Pierre; Sanche, Léon

    2013-08-01

    It was recently shown that the affinity of doubly charged, 1-3 diaminopropane (Dap2+) for DNA permits the growth on highly ordered pyrolitic graphite (HOPG) substrates, of plasmid DNA films, of known uniform thickness [O. Boulanouar, A. Khatyr, G. Herlem, F. Palmino, L. Sanche, and M. Fromm, J. Phys. Chem. C 115, 21291-21298 (2011)]. Post-irradiation analysis by electrophoresis of such targets confirms that electron impact at 10 eV produces a maximum in the yield of single strand breaks that can be associated with the formation of a DNA- transient anion. Using a well-adapted deterministic survival model for the variation of electron damage with fluence and film thickness, we have determined an absolute cross section for strand-break damage by 10 eV electrons and inelastic scattering attenuation length in DNA-Dap complex films.

  3. Absolute cross section for loss of supercoiled topology induced by 10 eV electrons in highly uniform /DNA/1,3-diaminopropane films deposited on highly ordered pyrolitic graphite

    PubMed Central

    Boulanouar, Omar; Fromm, Michel; Bass, Andrew D.; Cloutier, Pierre; Sanche, Léon

    2013-01-01

    It was recently shown that the affinity of doubly charged, 1–3 diaminopropane (Dap2+) for DNA permits the growth on highly ordered pyrolitic graphite (HOPG) substrates, of plasmid DNA films, of known uniform thickness [O. Boulanouar, A. Khatyr, G. Herlem, F. Palmino, L. Sanche, and M. Fromm, J. Phys. Chem. C 115, 21291–21298 (2011)]. Post-irradiation analysis by electrophoresis of such targets confirms that electron impact at 10 eV produces a maximum in the yield of single strand breaks that can be associated with the formation of a DNA− transient anion. Using a well-adapted deterministic survival model for the variation of electron damage with fluence and film thickness, we have determined an absolute cross section for strand-break damage by 10 eV electrons and inelastic scattering attenuation length in DNA-Dap complex films. PMID:23927289

  4. Absolute cross section for loss of supercoiled topology induced by 10 eV electrons in highly uniform /DNA/1,3-diaminopropane films deposited on highly ordered pyrolitic graphite

    SciTech Connect

    Boulanouar, Omar; Fromm, Michel; Bass, Andrew D.; Cloutier, Pierre; Sanche, Léon

    2013-08-07

    It was recently shown that the affinity of doubly charged, 1-3 diaminopropane (Dap{sup 2+}) for DNA permits the growth on highly ordered pyrolitic graphite (HOPG) substrates, of plasmid DNA films, of known uniform thickness [O. Boulanouar, A. Khatyr, G. Herlem, F. Palmino, L. Sanche, and M. Fromm, J. Phys. Chem. C 115, 21291–21298 (2011)]. Post-irradiation analysis by electrophoresis of such targets confirms that electron impact at 10 eV produces a maximum in the yield of single strand breaks that can be associated with the formation of a DNA{sup −} transient anion. Using a well-adapted deterministic survival model for the variation of electron damage with fluence and film thickness, we have determined an absolute cross section for strand-break damage by 10 eV electrons and inelastic scattering attenuation length in DNA-Dap complex films.

  5. Absolute nuclear material assay

    DOEpatents

    Prasad, Manoj K.; Snyderman, Neal J.; Rowland, Mark S.

    2012-05-15

    A method of absolute nuclear material assay of an unknown source comprising counting neutrons from the unknown source and providing an absolute nuclear material assay utilizing a model to optimally compare to the measured count distributions. In one embodiment, the step of providing an absolute nuclear material assay comprises utilizing a random sampling of analytically computed fission chain distributions to generate a continuous time-evolving sequence of event-counts by spreading the fission chain distribution in time.

  6. Absolute nuclear material assay

    DOEpatents

    Prasad, Manoj K.; Snyderman, Neal J.; Rowland, Mark S.

    2010-07-13

    A method of absolute nuclear material assay of an unknown source comprising counting neutrons from the unknown source and providing an absolute nuclear material assay utilizing a model to optimally compare to the measured count distributions. In one embodiment, the step of providing an absolute nuclear material assay comprises utilizing a random sampling of analytically computed fission chain distributions to generate a continuous time-evolving sequence of event-counts by spreading the fission chain distribution in time.

  7. Measurement of absolute cross sections for excitation of the 2s(2) S-1 -> 2s2p P-1 degrees transition in O+4

    NASA Technical Reports Server (NTRS)

    Smith, S. J.; Djuric, N.; Lozano, J. A.; Berrington, K. A.; Chutjian, A.

    2005-01-01

    Experimental cross sections are reported for the 1s(2)2s(2) S-1 -> 1s(2)2s2p P-1(o) transition in O+4 located at 19.689 eV. Use is made of the electron energy-loss method, using a merged electron-ion beam geometry. The center-of-mass interaction energies for the measurements in the S-1 -> P-1(o) transition are in the range 18 eV ( below the threshold) to 30 eV. Data are compared with other previous electron energy-loss measurements and with results of a 26 term R-matrix calculation that includes fine structure explicitly via the Breit-Pauli Hamiltonian. Clear resonance enhancement is observed in all experimental and theoretical results near the threshold for this S-1 -> P-1(o) transition.

  8. The Color Dipole Picture and the Ratio of the Longitudinal to the Transverse Photoabsorption Cross Section

    SciTech Connect

    Schildknecht, Dieter

    2009-03-23

    The transverse size of qq-bar fluctuations of a longitudinally polarized photon is reduced relative to the transverse size of qq-bar fluctuations of a transversely polarized photon. This implies a model-independent prediction of the ratio R(W{sup 2},Q{sup 2}){identical_to}{sigma}{sub L}/{sigma}{sub T} = 0.375, or, equivalently, F{sub L}/F{sub 2} = 0.27, for x congruent with Q{sup 2}/W{sup 2}<<1 and Q{sup 2} sufficiently large, while R(W{sup 2},Q{sup 2}) 0.50, if this effect is ignored. Experimental data from HERA confirm the transverse-size reduction.

  9. Enhanced anomalous photo-absorption from TiO{sub 2} nanostructures

    SciTech Connect

    Solanki, Vanaraj; Majumder, Subrata; Mishra, Indrani; Varma, Shikha; Dash, P.; Singh, C.; Kanjilal, D.

    2014-03-28

    Two dimensional nanostructures have been created on the rutile TiO{sub 2} (110) surfaces via ion irradiation technique. Enhanced anomalous photo- absorption response is displayed, where nanostructures of 15 nm diameter with 0.5 nm height, and not the smaller nanostructures with larger surface area, delineate highest absorbance. Comprehensive investigations of oxygen vacancy states, on ion- irradiated surfaces, display a remarkable result that the number of vacancies saturates for higher fluences. A competition between the number of vacancy sites on the nanostructure in conjunction with its size is responsible for the observed anomalous photo-absorption.

  10. Information-theoretic analysis of x-ray photoabsorption based threat detection system for check-point

    NASA Astrophysics Data System (ADS)

    Lin, Yuzhang; Allouche, Genevieve G.; Huang, James; Ashok, Amit; Gong, Qian; Coccarelli, David; Stoian, Razvan-Ionut; Gehm, Michael E.

    2016-05-01

    In this work we present an information-theoretic framework for a systematic study of checkpoint x-ray systems using photoabsorption measurements. Conventional system performance analysis of threat detection systems confounds the effect of the system architecture choice with the performance of a threat detection algorithm. However, our system analysis approach enables a direct comparison of the fundamental performance limits of disparate hardware architectures, independent of the choice of a specific detection algorithm. We compare photoabsorptive measurements from different system architectures to understand the affect of system geometry (angular views) and spectral resolution on the fundamental limits of the system performance.

  11. Absolute biological needs.

    PubMed

    McLeod, Stephen

    2014-07-01

    Absolute needs (as against instrumental needs) are independent of the ends, goals and purposes of personal agents. Against the view that the only needs are instrumental needs, David Wiggins and Garrett Thomson have defended absolute needs on the grounds that the verb 'need' has instrumental and absolute senses. While remaining neutral about it, this article does not adopt that approach. Instead, it suggests that there are absolute biological needs. The absolute nature of these needs is defended by appeal to: their objectivity (as against mind-dependence); the universality of the phenomenon of needing across the plant and animal kingdoms; the impossibility that biological needs depend wholly upon the exercise of the abilities characteristic of personal agency; the contention that the possession of biological needs is prior to the possession of the abilities characteristic of personal agency. Finally, three philosophical usages of 'normative' are distinguished. On two of these, to describe a phenomenon or claim as 'normative' is to describe it as value-dependent. A description of a phenomenon or claim as 'normative' in the third sense does not entail such value-dependency, though it leaves open the possibility that value depends upon the phenomenon or upon the truth of the claim. It is argued that while survival needs (or claims about them) may well be normative in this third sense, they are normative in neither of the first two. Thus, the idea of absolute need is not inherently normative in either of the first two senses. PMID:23586876

  12. Enhanced photoabsorption in front-tapered single-nanowire solar cells.

    PubMed

    Zhan, Yaohui; Li, Xiaofeng; Wu, Shaolong; Li, Ke; Yang, Zhenhai; Shang, Aixue

    2014-10-01

    Vertically aligned single-nanowire is verified to be a unique building block to realize the high-efficiency solar cell beyond Schockley-Queisser limit. We proposed a front-tapered vertically aligned single-nanowire solar cell (V-SNSC) and investigated numerically the possibility of this configuration to improve the photoabsorption efficiency compared to the conventional designs, by using 2.5D full-wave finite-element method. The influences of the feature sizes of aspect ratio, bottom radius, and nanowire length on the light-trapping properties were explored; the detailed field distribution and carrier generation rate were revealed as well based on the theory of dielectric resonant antenna, in order to elucidate the underlying physical mechanism. Results showed that, compared with the cylindrical counterparts, the absorption capability of V-SNSCs could be greatly enhanced by using a front-tapered configuration with less material utilized, and that such a positive effect can be further strengthened by increasing the nanowire length. The proposed configuration provides a promising approach to engineer the photoabsorption in the photovoltaic and other optoelectronic devices. PMID:25360977

  13. K-shell photoabsorption edge of strongly coupled matter driven by laser-converted radiation.

    PubMed

    Zhao, Yang; Yang, Jiamin; Zhang, Jiyan; Yang, Guohong; Wei, Minxi; Xiong, Gang; Song, Tianming; Zhang, Zhiyu; Bao, Lihua; Deng, Bo; Li, Yukun; He, Xiaoan; Li, Chaoguang; Mei, Yu; Yu, Ruizhen; Jiang, Shaoen; Liu, Shenye; Ding, Yongkun; Zhang, Baohan

    2013-10-11

    The first observation of the K-shell photoabsorption edge of strongly coupled matter with an ion-ion coupling parameter of about 65 generated by intense x-ray radiation-driven shocks is reported. The soft x-ray radiation generated by laser interaction with a "dog bone" high-Z hohlraum is used to ablate two thick CH layers, which cover a KCl sample, to create symmetrical inward shocks. While the two shocks impact at the central KCl sample, a highly compressed KCl is obtained with a density of 3-5 times solid density and a temperature of about 2-4 eV. The photoabsorption spectra of chlorine near the K-shell edge are measured with a crystal spectrometer using a short x-ray backlighter. The redshift of the K edge up to 11.7 eV and broadening of 15.2 eV are obtained for the maximum compression. A comparison of the measured redshifts and broadenings with dense plasma calculations are made, and it indicates potential improvements in the theoretical description. PMID:24160607

  14. Photoabsorption of attosecond XUV light pulses by two strongly laser-coupled autoionizing states

    NASA Astrophysics Data System (ADS)

    Chu, Wei-Chun; Lin, C. D.

    2012-01-01

    We study theoretically the photoabsorption spectra of an attosecond extreme ultraviolet (XUV) pulse by a laser-dressed atomic system. A weak XUV excites an autoionizing state which is strongly coupled to another autoionizing state by a laser. The theory was applied to explain two recent experiments [Loh, Greene, and Leone, Chem. Phys.CMPHC20301-010410.1016/j.chemphys.2007.11.005 350, 7 (2008); Wang, Chini, Chen, Zhang, Cheng, He, Cheng, Wu, Thumm, and Chang, Phys. Rev. Lett.PRLTAO0031-900710.1103/PhysRevLett.105.143002 105, 143002 (2010)] where the absorption spectra of the XUV lights were measured against the time delay between the laser and the XUV. In another example, we study an attosecond pulse exciting the 2s2p(1P) resonance of helium which is resonantly coupled to the 2s2(1S) resonance by a moderately intense 540-nm laser. The relation between the photoabsorption spectra and the photoelectron spectra and the modification of the transmitted lights in such an experiment are analyzed. The role of Rabi flopping between the two autoionizing states within their lifetimes is investigated with respect to the laser intensity and detuning.

  15. The absolute path command

    2012-05-11

    The ap command traveres all symlinks in a given file, directory, or executable name to identify the final absolute path. It can print just the final path, each intermediate link along with the symlink chan, and the permissions and ownership of each directory component in the final path. It has functionality similar to "which", except that it shows the final path instead of the first path. It is also similar to "pwd", but it canmore » provide the absolute path to a relative directory from the current working directory.« less

  16. The absolute path command

    SciTech Connect

    Moody, A.

    2012-05-11

    The ap command traveres all symlinks in a given file, directory, or executable name to identify the final absolute path. It can print just the final path, each intermediate link along with the symlink chan, and the permissions and ownership of each directory component in the final path. It has functionality similar to "which", except that it shows the final path instead of the first path. It is also similar to "pwd", but it can provide the absolute path to a relative directory from the current working directory.

  17. Photocurrent and photoabsorption transients in amorphous solids in the presence of optical bias

    NASA Astrophysics Data System (ADS)

    Grygiel, P.; Tomaszewicz, W.

    1997-11-01

    An approximate treatment of the transient response of an illuminated (`optically biased') amorphous semiconductor to a short light pulse is presented. The problem is formulated in terms of Rose's multiple-trapping model and is studied in two specific cases, corresponding to strongly non-equilibrium and quasi-equilibrium trapped-carrier distributions. In both approximations, the formulae describing the photocurrent and photoabsorption transients in some characteristic time intervals are derived. The accuracy of the formulae is verified by numerical calculations, performed for the exponential distribution of traps. The above results are consistent with those obtained previously by other authors, particularly by Pandya and Schiff. The given formulae make it possible to determine the trap distribution in the energy gap as well as some trap parameters from experimental data without making any model assumptions.

  18. Theoretical investigation of the lithium 2p←2s photoabsorption spectra perturbed by atomic hydrogen

    NASA Astrophysics Data System (ADS)

    Lamoudi, N.; Bouledroua, M.; Alioua, K.; Allouche, A.-R.; Aubert-Frécon, M.

    2013-05-01

    This work proposes a theoretical study of the Li(2p←2s) photoabsorption spectra perturbed by ground hydrogen atoms. The temperature effect on the far-wing spectra is examined in the temperature range 4000-20000K. For this purpose, the ground and excited LiH potential curves and the transition dipole moments that connect them are constructed from ab initio data. The investigation shows that the profile spectra are dominated at all temperatures by the singlet A←X transitions and exhibit in the red wing a satellite structure near the wavelength 1000nm. The spectra revealed also the appearance beyond 14000K of a second satellite structure in the blue wing close to the wavelength 510nm originating from the triplet c←a transitions.

  19. Characterization of combustion chamber products by core-level photoabsorption spectroscopy

    SciTech Connect

    Kellar, S. A.; Huff, W. R.A.; Moler, E J; Yeah, S.; Hussain, Z.

    1997-04-01

    The lubricating performance of motor oil is adversely affected by the carbon soot contamination that is a natural by-product of the combustion process. Particularly in diesel engines, {open_quote}blow-by{close_quote} is a problem that greatly decreases the longevity of the engine-lubricating oil. Motor oil manufacturers spend considerable resources developing new oil formulations that counteract the adverse affects of this combustion soot. At present, the only effective way to test new formulations is in a working engine. This process is obviously expensive and not especially efficient. In this ongoing work in collaboration with Chevron Research and Technology, the authors goal is to find a form of carbon that chemically resembles the soot created by the {open_quote}blow-by{close_quote} in a diesel engine. The chemically correct soot substitute can be used in bench tests to replace the expensive full motor testing for new formulations. The final testing would still be done in the test motors but only with promising candidates. To these ends, Near Edge X-ray Adsorption spectroscopy Extended Fine Structure (NEXAFS) is an attractive technique in that it has chemical specificity through the core-level binding energy and because it probes the chemically important unoccupied molecular orbitals of the material. Core-level photoabsorption has been used to characterize the empty electronic states of a wide variety of materials. Specifically, the near-edge region of the photoabsorption process has been used to determine the relative quantity of sp{sup 2} and sp{sup 3}bonding in carbon films. The samples were fine grained powders pressed into pellets. The C(1s) absorption spectra were collected from each sample by measuring the total electron yield from the sample as a function of photon energy. The absorption intensity was normalized to the incoming photon flux by measuring the photoyield from a fine gold mesh.

  20. Wavelengths, f-Values, and Cross Sections in the UV Spectra of Astrophysical Atoms, Ions, and Molecules

    NASA Technical Reports Server (NTRS)

    Crane, Phil (Technical Monitor); Raymond, John C.; Parkinson, W. H.

    2004-01-01

    Contents include the following: Improved UV wavelengths, energy levels, and f-values for iron group ions. Update of Kurucz database of wavelengths and f-values. Publication of improved UV photodissociation cross sections for H2O. UV photoabsorption cross sections for CO bands. Service Activities and Data Outreach.

  1. Combined Use of Absolute and Differential Seismic Arrival Time Data to Improve Absolute Event Location

    NASA Astrophysics Data System (ADS)

    Myers, S.; Johannesson, G.

    2012-12-01

    Arrival time measurements based on waveform cross correlation are becoming more common as advanced signal processing methods are applied to seismic data archives and real-time data streams. Waveform correlation can precisely measure the time difference between the arrival of two phases, and differential time data can be used to constrain relative location of events. Absolute locations are needed for many applications, which generally requires the use of absolute time data. Current methods for measuring absolute time data are approximately two orders of magnitude less precise than differential time measurements. To exploit the strengths of both absolute and differential time data, we extend our multiple-event location method Bayesloc, which previously used absolute time data only, to include the use of differential time measurements that are based on waveform cross correlation. Fundamentally, Bayesloc is a formulation of the joint probability over all parameters comprising the multiple event location system. The Markov-Chain Monte Carlo method is used to sample from the joint probability distribution given arrival data sets. The differential time component of Bayesloc includes scaling a stochastic estimate of differential time measurement precision based the waveform correlation coefficient for each datum. For a regional-distance synthetic data set with absolute and differential time measurement error of 0.25 seconds and 0.01 second, respectively, epicenter location accuracy is improved from and average of 1.05 km when solely absolute time data are used to 0.28 km when absolute and differential time data are used jointly (73% improvement). The improvement in absolute location accuracy is the result of conditionally limiting absolute location probability regions based on the precise relative position with respect to neighboring events. Bayesloc estimates of data precision are found to be accurate for the synthetic test, with absolute and differential time measurement

  2. Electronic Absolute Cartesian Autocollimator

    NASA Technical Reports Server (NTRS)

    Leviton, Douglas B.

    2006-01-01

    An electronic absolute Cartesian autocollimator performs the same basic optical function as does a conventional all-optical or a conventional electronic autocollimator but differs in the nature of its optical target and the manner in which the position of the image of the target is measured. The term absolute in the name of this apparatus reflects the nature of the position measurement, which, unlike in a conventional electronic autocollimator, is based absolutely on the position of the image rather than on an assumed proportionality between the position and the levels of processed analog electronic signals. The term Cartesian in the name of this apparatus reflects the nature of its optical target. Figure 1 depicts the electronic functional blocks of an electronic absolute Cartesian autocollimator along with its basic optical layout, which is the same as that of a conventional autocollimator. Referring first to the optical layout and functions only, this or any autocollimator is used to measure the compound angular deviation of a flat datum mirror with respect to the optical axis of the autocollimator itself. The optical components include an illuminated target, a beam splitter, an objective or collimating lens, and a viewer or detector (described in more detail below) at a viewing plane. The target and the viewing planes are focal planes of the lens. Target light reflected by the datum mirror is imaged on the viewing plane at unit magnification by the collimating lens. If the normal to the datum mirror is parallel to the optical axis of the autocollimator, then the target image is centered on the viewing plane. Any angular deviation of the normal from the optical axis manifests itself as a lateral displacement of the target image from the center. The magnitude of the displacement is proportional to the focal length and to the magnitude (assumed to be small) of the angular deviation. The direction of the displacement is perpendicular to the axis about which the

  3. ABSOLUTE POLARIMETRY AT RHIC.

    SciTech Connect

    OKADA; BRAVAR, A.; BUNCE, G.; GILL, R.; HUANG, H.; MAKDISI, Y.; NASS, A.; WOOD, J.; ZELENSKI, Z.; ET AL.

    2007-09-10

    Precise and absolute beam polarization measurements are critical for the RHIC spin physics program. Because all experimental spin-dependent results are normalized by beam polarization, the normalization uncertainty contributes directly to final physics uncertainties. We aimed to perform the beam polarization measurement to an accuracy Of {Delta}P{sub beam}/P{sub beam} < 5%. The absolute polarimeter consists of Polarized Atomic Hydrogen Gas Jet Target and left-right pairs of silicon strip detectors and was installed in the RHIC-ring in 2004. This system features proton-proton elastic scattering in the Coulomb nuclear interference (CNI) region. Precise measurements of the analyzing power A{sub N} of this process has allowed us to achieve {Delta}P{sub beam}/P{sub beam} = 4.2% in 2005 for the first long spin-physics run. In this report, we describe the entire set up and performance of the system. The procedure of beam polarization measurement and analysis results from 2004-2005 are described. Physics topics of AN in the CNI region (four-momentum transfer squared 0.001 < -t < 0.032 (GeV/c){sup 2}) are also discussed. We point out the current issues and expected optimum accuracy in 2006 and the future.

  4. Testing the quasi-absolute method in photon activation analysis

    SciTech Connect

    Sun, Z. J.; Wells, D.; Starovoitova, V.; Segebade, C.

    2013-04-19

    In photon activation analysis (PAA), relative methods are widely used because of their accuracy and precision. Absolute methods, which are conducted without any assistance from calibration materials, are seldom applied for the difficulty in obtaining photon flux in measurements. This research is an attempt to perform a new absolute approach in PAA - quasi-absolute method - by retrieving photon flux in the sample through Monte Carlo simulation. With simulated photon flux and database of experimental cross sections, it is possible to calculate the concentration of target elements in the sample directly. The QA/QC procedures to solidify the research are discussed in detail. Our results show that the accuracy of the method for certain elements is close to a useful level in practice. Furthermore, the future results from the quasi-absolute method can also serve as a validation technique for experimental data on cross sections. The quasi-absolute method looks promising.

  5. Implants as absolute anchorage.

    PubMed

    Rungcharassaeng, Kitichai; Kan, Joseph Y K; Caruso, Joseph M

    2005-11-01

    Anchorage control is essential for successful orthodontic treatment. Each tooth has its own anchorage potential as well as propensity to move when force is applied. When teeth are used as anchorage, the untoward movements of the anchoring units may result in the prolonged treatment time, and unpredictable or less-than-ideal outcome. To maximize tooth-related anchorage, techniques such as differential torque, placing roots into the cortex of the bone, the use of various intraoral devices and/or extraoral appliances have been implemented. Implants, as they are in direct contact with bone, do not possess a periodontal ligament. As a result, they do not move when orthodontic/orthopedic force is applied, and therefore can be used as "absolute anchorage." This article describes different types of implants that have been used as orthodontic anchorage. Their clinical applications and limitations are also discussed. PMID:16463910

  6. Absolute Equilibrium Entropy

    NASA Technical Reports Server (NTRS)

    Shebalin, John V.

    1997-01-01

    The entropy associated with absolute equilibrium ensemble theories of ideal, homogeneous, fluid and magneto-fluid turbulence is discussed and the three-dimensional fluid case is examined in detail. A sigma-function is defined, whose minimum value with respect to global parameters is the entropy. A comparison is made between the use of global functions sigma and phase functions H (associated with the development of various H-theorems of ideal turbulence). It is shown that the two approaches are complimentary though conceptually different: H-theorems show that an isolated system tends to equilibrium while sigma-functions allow the demonstration that entropy never decreases when two previously isolated systems are combined. This provides a more complete picture of entropy in the statistical mechanics of ideal fluids.

  7. Electron yield soft X-ray photoabsorption spectroscopy under normal ambient-pressure conditions

    PubMed Central

    Tamenori, Yusuke

    2013-01-01

    Ambient-pressure soft X-ray photoabsorption spectroscopy (XAS) was demonstrated to be applicable to the chemical analysis of hydrated transition-metal compounds. For this purpose, even under ambient-pressure conditions, electron yield detection XAS (EY-XAS), based on a simple drain-current set-up, was used to overcome a weakness in fluorescence yield detection XAS (FY-XAS), which does not give a pure soft XAS. The feasibility of EY-XAS was investigated and it was clarified that the EY-XAS under ambient-pressure conditions corresponds to the mixed data of the total EY and conversion EY spectra. Normal ambient-pressure EY-XAS analysis was applied to anhydrous (CoCl2) and to hydrated (CoCl2·6H2O) cobalt chloride at the Co L 23-edge. The present measurements demonstrated the ability to unambiguously distinguish the different chemical states of cobalt ions, relying upon spectral differences that indicate octahedral/quasi-octahedral structural changes as a result of hydration/dehydration reactions. PMID:23592620

  8. Ultraviolet photochemistry of buta-1,3- and buta-1,2-dienes: Laser spectroscopic absolute hydrogen atom quantum yield and translational energy distribution measurements

    SciTech Connect

    Hanf, A.; Volpp, H.-R.; Sharma, P.; Mittal, J. P.; Vatsa, R. K.

    2010-07-14

    Using pulsed H-atom Lyman-{alpha} laser-induced fluorescence spectroscopy along with a photolytic calibration approach, absolute H-atom product quantum yields of {phi}{sub H-b13d}=(0.32{+-}0.04) and {phi}{sub H-b12d}=(0.36{+-}0.04) were measured under collision-free conditions for the 193 nm gas-phase laser flash photolysis of buta-1,3- and buta-1,2-diene at room temperature, which demonstrate that nascent H-atom formation is of comparable importance for both parent molecules. Comparison of the available energy fraction, f{sub T-b13d}=(0.22{+-}0.03) and f{sub T-b12d}=(0.13{+-}0.01), released as H+C{sub 4}H{sub 5} product translational energy with results of impulsive and statistical energy partitioning modeling calculations indicates that for both, buta-1,3- and buta-1,2-diene, H-atom formation is preceded by internal conversion to the respective electronic ground state (S{sub 0}) potential energy surfaces. In addition, values of {sigma}{sub b-1,3-d-L{alpha}=}(3.5{+-}0.2)x10{sup -17} cm{sup 2} and {sigma}{sub b-1,2-d-L{alpha}=}(4.4{+-}0.2)x10{sup -17} cm{sup 2} for the previously unknown Lyman-{alpha} (121.6 nm) radiation photoabsorption cross sections of buta-1,3- and buta-1,2-diene in the gas-phase were determined.

  9. Absolute neutrino mass measurements

    NASA Astrophysics Data System (ADS)

    Wolf, Joachim

    2011-10-01

    The neutrino mass plays an important role in particle physics, astrophysics and cosmology. In recent years the detection of neutrino flavour oscillations proved that neutrinos carry mass. However, oscillation experiments are only sensitive to the mass-squared difference of the mass eigenvalues. In contrast to cosmological observations and neutrino-less double beta decay (0v2β) searches, single β-decay experiments provide a direct, model-independent way to determine the absolute neutrino mass by measuring the energy spectrum of decay electrons at the endpoint region with high accuracy. Currently the best kinematic upper limits on the neutrino mass of 2.2eV have been set by two experiments in Mainz and Troitsk, using tritium as beta emitter. The next generation tritium β-experiment KATRIN is currently under construction in Karlsruhe/Germany by an international collaboration. KATRIN intends to improve the sensitivity by one order of magnitude to 0.2eV. The investigation of a second isotope (137Rh) is being pursued by the international MARE collaboration using micro-calorimeters to measure the beta spectrum. The technology needed to reach 0.2eV sensitivity is still in the R&D phase. This paper reviews the present status of neutrino-mass measurements with cosmological data, 0v2β decay and single β-decay.

  10. Absolute neutrino mass measurements

    SciTech Connect

    Wolf, Joachim

    2011-10-06

    The neutrino mass plays an important role in particle physics, astrophysics and cosmology. In recent years the detection of neutrino flavour oscillations proved that neutrinos carry mass. However, oscillation experiments are only sensitive to the mass-squared difference of the mass eigenvalues. In contrast to cosmological observations and neutrino-less double beta decay (0v2{beta}) searches, single {beta}-decay experiments provide a direct, model-independent way to determine the absolute neutrino mass by measuring the energy spectrum of decay electrons at the endpoint region with high accuracy.Currently the best kinematic upper limits on the neutrino mass of 2.2eV have been set by two experiments in Mainz and Troitsk, using tritium as beta emitter. The next generation tritium {beta}-experiment KATRIN is currently under construction in Karlsruhe/Germany by an international collaboration. KATRIN intends to improve the sensitivity by one order of magnitude to 0.2eV. The investigation of a second isotope ({sup 137}Rh) is being pursued by the international MARE collaboration using micro-calorimeters to measure the beta spectrum. The technology needed to reach 0.2eV sensitivity is still in the R and D phase. This paper reviews the present status of neutrino-mass measurements with cosmological data, 0v2{beta} decay and single {beta}-decay.

  11. Differential cross sections for ionization of helium, neon, and argon by fast electrons

    SciTech Connect

    Miller, J.H.; Manson, S.T.

    1984-05-01

    Ionization cross sections, differential in the energy of secondary electrons, are presented for high-energy electrons incident on helium, neon, and argon. The results are based on Bethe's theory for inelastic scattering of fast charged particles using photoabsorption data and proton-impact differential ionization cross sections to determine the coefficients of this asymptotic expansion of the first Born approximation. The model cross sections are compared with experimental data for primary-electron energies between 100 and 5000 eV.

  12. Absolute cross sections for near-threshold electron-impact excitation of the dipole-allowed transitions 3s2 1S-->3s3p 1P in Cl5+ and 3s 2S-->3p 2P in Cl6+

    NASA Astrophysics Data System (ADS)

    Djurić, N.; Bannister, M. E.; Derkatch, A. M.; Griffin, D. C.; Krause, H. F.; Popović, D. B.; Smith, A. C.; Wallbank, B.; Dunn, G. H.

    2002-05-01

    Experimental and theoretical cross sections for electron-impact excitation of the dipole-allowed transitions 3s2 1S-->3s3p 1P in Cl5+ and 3s 2S-->3p 2P in Cl6+ near the excitation thresholds are reported. Absolute cross sections are measured using the merged electron-ion beams energy-loss technique. The intermediate-coupling frame-transformation R-matrix method is used to obtain theoretical cross sections. The total cross sections, for the transitions studied in both ions, exhibit resonance structures near threshold. There is excellent agreement between theory and experiment with respect to both the shape and the magnitude of the cross section for the 3s 2S-->3p 2P transition in Cl6+. For Cl5+, structures and trends in both the present R-matrix calculation and the previous calculation of Baluja and Mohan [J. Phys. B 20, 831 (1987)] agree well with the experimental results. However, the magnitudes of the theoretical cross sections for Cl5+ are significantly smaller than the measured cross section, which has been corrected for metastable contamination.

  13. Absolute Identification by Relative Judgment

    ERIC Educational Resources Information Center

    Stewart, Neil; Brown, Gordon D. A.; Chater, Nick

    2005-01-01

    In unidimensional absolute identification tasks, participants identify stimuli that vary along a single dimension. Performance is surprisingly poor compared with discrimination of the same stimuli. Existing models assume that identification is achieved using long-term representations of absolute magnitudes. The authors propose an alternative…

  14. Be Resolute about Absolute Value

    ERIC Educational Resources Information Center

    Kidd, Margaret L.

    2007-01-01

    This article explores how conceptualization of absolute value can start long before it is introduced. The manner in which absolute value is introduced to students in middle school has far-reaching consequences for their future mathematical understanding. It begins to lay the foundation for students' understanding of algebra, which can change…

  15. Vacuum ultraviolet photoabsorption of pure solid ozone and its implication on the identification of ozone on Moon

    NASA Astrophysics Data System (ADS)

    Sivaraman, B.; Nair, B. G.; Raja Sekhar, B. N.; Lo, J.-I.; Sridharan, R.; Cheng, B.-M.; Mason, N. J.

    2014-05-01

    In this Letter we present, for the first time, VUV (109-220 nm) photoabsorption spectra of high density amorphous and crystalline forms of O3 relevant to both planetary/satellite and InterStellar Medium (ISM) conditions. Absorption in the Hartley region was observed to be very weak or absent when pure O3 ice was formed in the crystalline phase. Our results suggest that pure solid O3 effectively absorbs in the Hartley band but only at temperatures <70 K. Such results suggest the need for in-situ techniques to detect the presence of O3, which otherwise is a minor constituent in the lunar exosphere.

  16. Redetermining CEBAF's Absolute Energy

    NASA Astrophysics Data System (ADS)

    Su, Tong; Jlab Marathon Collaboration

    2015-04-01

    With the upgrade of the Jefferson Lab accelerator (CEBAF) from 6 GeV max energy to 12 GeV, all the dipole magnets in the machine were refurbished. Most of them were switched from open c-shaped to closed h-shaped by adding extra iron. With these upgraded magnets, the energy calibration of the accelerator needed to be redetermined. We will show how an extra external dipole, which is run in series with those in the machine, helps us cross check the current in the magnets as well as precisely map out the integral field for any machine setting. Using knowledge of the relative performance of the dipoles as well as the bend angle into the Hall, has allowed us to already determine a 4th pass 7 GeV beam to better than 7 MeV. In the future, we will use g-2 spin precession as a second independent energy determination. This work is supported by Kent State University, NSF Grant PHY-1405814, and DOE Contract DE-AC05-06OR23177 (JLab).

  17. Photoabsorption and resonance energy transfer phenomenon in CdTe-protein bioconjugates: an insight into QD-biomolecular interactions.

    PubMed

    Vinayaka, Aaydha C; Thakur, Munna S

    2011-05-18

    Luminescent quantum dots (QDs) possess unique photophysical properties, which are advantageous in the development of new generation robust fluorescent probes based on Forster resonance energy transfer (FRET) phenomena. Bioconjugation of these QDs with biomolecules create hybrid materials having unique photophysical properties along with biological activity. The present study is aimed at characterizing QD bioconjugates in terms of optical behavior. Colloidal CdTe QDs capped with 3-mercaptopropionic acid (MPA) were conjugated to different proteins by the carbodiimide protocol using N-(3-dimethylaminopropyl)-N-ethylcarbodiimide hydrochloride (EDC) and a coupling reagent like N-hydroxysuccinimide (NHS). The photoabsorption of these QD-protein bioconjugates demonstrated an effective coupling of electronic orbitals of constituents. A linear variation in absorbance of bioconjugates at 330 nm proportionate to conjugation suggests a covalent attachment as confirmed by gel electrophoresis. A red shift in the fluorescence of bovine serum albumin (BSA) due to conjugation inferred a decrease in Stokes shift and solvent polarization effects on protein. A proportionate quenching in BSA fluorescence followed by an enhancement of QD fluorescence point toward nonradiative dipolar interactions. Further, reduction in photobleaching of BSA suggests QD-biomolecular interactions. Bioconjugation has significantly influenced the photoabsorption spectrum of QD bioconjugates suggesting the formation of a possible protein shell on the surface of QD. The experimental result suggests that these bioconjugates can be considered nanoparticle (NP) superstructures for the development of a new generation of robust nanoprobes. PMID:21452896

  18. Dynamic linear response of atoms in plasmas and photo-absorption cross-section in the dipole approximation

    NASA Astrophysics Data System (ADS)

    Caizergues, C.; Blenski, T.; Piron, R.

    2016-03-01

    We report results on the self-consistent linear response theory of quantum average-atoms in plasmas. The approach is based on the two first orders of the cluster expansion of the plasma susceptibility. A change of variable is applied, which allows us to handle the diverging free-free transitions contribution in the self-consistent induced electron density and potential. The method is first tested on the case of rare gas isolated neutral atoms. A test of the Ehrenfest-type sum rule is then performed in a case of an actual average-atom in a plasma. At frequencies much higher than the plasma frequency, the sum rule seems to be fulfilled within the accuracy of the numerical methods. Close to the plasma frequency, the method seems not to account for the cold-plasma dielectric function renormalization in the sum rule, which was correctly reproduced in the case of the Thomas-Fermi-Bloch self-consistent linear response. This suggests the need for a better accounting for the outgoing waves in the asymptotic boundary conditions.

  19. Absolute calibration of sniffer probes on Wendelstein 7-X.

    PubMed

    Moseev, D; Laqua, H P; Marsen, S; Stange, T; Braune, H; Erckmann, V; Gellert, F; Oosterbeek, J W

    2016-08-01

    Here we report the first measurements of the power levels of stray radiation in the vacuum vessel of Wendelstein 7-X using absolutely calibrated sniffer probes. The absolute calibration is achieved by using calibrated sources of stray radiation and the implicit measurement of the quality factor of the Wendelstein 7-X empty vacuum vessel. Normalized absolute calibration coefficients agree with the cross-calibration coefficients that are obtained by the direct measurements, indicating that the measured absolute calibration coefficients and stray radiation levels in the vessel are valid. Close to the launcher, the stray radiation in the empty vessel reaches power levels up to 340 kW/m(2) per MW injected beam power. Furthest away from the launcher, i.e., half a toroidal turn, still 90 kW/m(2) per MW injected beam power is measured. PMID:27587121

  20. Absolute calibration of sniffer probes on Wendelstein 7-X

    NASA Astrophysics Data System (ADS)

    Moseev, D.; Laqua, H. P.; Marsen, S.; Stange, T.; Braune, H.; Erckmann, V.; Gellert, F.; Oosterbeek, J. W.

    2016-08-01

    Here we report the first measurements of the power levels of stray radiation in the vacuum vessel of Wendelstein 7-X using absolutely calibrated sniffer probes. The absolute calibration is achieved by using calibrated sources of stray radiation and the implicit measurement of the quality factor of the Wendelstein 7-X empty vacuum vessel. Normalized absolute calibration coefficients agree with the cross-calibration coefficients that are obtained by the direct measurements, indicating that the measured absolute calibration coefficients and stray radiation levels in the vessel are valid. Close to the launcher, the stray radiation in the empty vessel reaches power levels up to 340 kW/m2 per MW injected beam power. Furthest away from the launcher, i.e., half a toroidal turn, still 90 kW/m2 per MW injected beam power is measured.

  1. Characterization of SiC fibers by soft x-ray photoelectron and photoabsorption spectroscopies and scanning Auger microscopy

    SciTech Connect

    Ma, Qing; McDowell, M.W.; Rosenberg, R.A.

    1996-08-01

    Synchrotron radiation soft x-ray photoelectron and photoabsorption spectroscopy was used to characterize commercially obtained SiC fibers produced by CVD on a W core and followed by a C passivating layer. Depth profiling of the fiber through the C/SiC interface was done by making Si 2p and C 1s core level PES and PAS, as well as scanning Auger microscopy, measurements following Ar{sup +} sputtering. No significant changes in either photoemission or absorption or Auger line shapes were observed versus depth, indicating no significant interfacial reaction. The line shapes of the carbonaceous coatings are predominantely graphite-like and those of the CVD SiC coatings are microcrystalline, with disorder present to some extent in both cases.

  2. Excited states of aniline by photoabsorption spectroscopy in the 30,000-90,000 cm(-1) region using synchrotron radiation.

    PubMed

    Rajasekhar, B N; Veeraiah, A; Sunanda, K; Jagatap, B N

    2013-08-14

    The photoabsorption spectrum of aniline (C6H5NH2) in gas phase in the 30,000-90,000 cm(-1) (3.7-11.2 eV) region is recorded at resolution limit of 0.008 eV using synchrotron radiation source for the first time to comprehend the nature of the excited valence and Rydberg states. The first half of the energy interval constitutes the richly structured valence transitions from the ground to excited states up to the first ionization potential (IP) at 8.02 eV. The spectrum in the second half consists of vibrational features up to second IP (9.12 eV) and structureless broad continuum up to the third IP (10.78 eV). The electronic states are assigned mainly to the singlets belonging to π → π* transitions. A few weak initial members of Rydberg states arising from π → 4s, np or nd transitions are also identified. Observed vibrational features are assigned to transitions from the ground state A' to the excited states 1A", 3A', 5A", 6A', and 10A" in C(s) symmetry. Time dependent density functional theory (TDDFT) calculations at B3LYP level of theory are employed to obtain the vertical excitation energies and the symmetries of the excited states in equilibrium configuration. The computed values of the transition energies agree fairly well with the experimental data. Further the calculated oscillator strengths are used to substantiate the assignments of the bands. The work provides a comprehensive picture of the vacuum ultraviolet photoabsorption spectrum of aniline up to its third ionization limit. PMID:23947851

  3. Absolute transition probabilities of phosphorus.

    NASA Technical Reports Server (NTRS)

    Miller, M. H.; Roig, R. A.; Bengtson, R. D.

    1971-01-01

    Use of a gas-driven shock tube to measure the absolute strengths of 21 P I lines and 126 P II lines (from 3300 to 6900 A). Accuracy for prominent, isolated neutral and ionic lines is estimated to be 28 to 40% and 18 to 30%, respectively. The data and the corresponding theoretical predictions are examined for conformity with the sum rules.-

  4. Optomechanics for absolute rotation detection

    NASA Astrophysics Data System (ADS)

    Davuluri, Sankar

    2016-07-01

    In this article, we present an application of optomechanical cavity for the absolute rotation detection. The optomechanical cavity is arranged in a Michelson interferometer in such a way that the classical centrifugal force due to rotation changes the length of the optomechanical cavity. The change in the cavity length induces a shift in the frequency of the cavity mode. The phase shift corresponding to the frequency shift in the cavity mode is measured at the interferometer output to estimate the angular velocity of absolute rotation. We derived an analytic expression to estimate the minimum detectable rotation rate in our scheme for a given optomechanical cavity. Temperature dependence of the rotation detection sensitivity is studied.

  5. The Absolute Spectrum Polarimeter (ASP)

    NASA Technical Reports Server (NTRS)

    Kogut, A. J.

    2010-01-01

    The Absolute Spectrum Polarimeter (ASP) is an Explorer-class mission to map the absolute intensity and linear polarization of the cosmic microwave background and diffuse astrophysical foregrounds over the full sky from 30 GHz to 5 THz. The principal science goal is the detection and characterization of linear polarization from an inflationary epoch in the early universe, with tensor-to-scalar ratio r much greater than 1O(raised to the power of { -3}) and Compton distortion y < 10 (raised to the power of{-6}). We describe the ASP instrument and mission architecture needed to detect the signature of an inflationary epoch in the early universe using only 4 semiconductor bolometers.

  6. Absolute calibration of optical flats

    DOEpatents

    Sommargren, Gary E.

    2005-04-05

    The invention uses the phase shifting diffraction interferometer (PSDI) to provide a true point-by-point measurement of absolute flatness over the surface of optical flats. Beams exiting the fiber optics in a PSDI have perfect spherical wavefronts. The measurement beam is reflected from the optical flat and passed through an auxiliary optic to then be combined with the reference beam on a CCD. The combined beams include phase errors due to both the optic under test and the auxiliary optic. Standard phase extraction algorithms are used to calculate this combined phase error. The optical flat is then removed from the system and the measurement fiber is moved to recombine the two beams. The newly combined beams include only the phase errors due to the auxiliary optic. When the second phase measurement is subtracted from the first phase measurement, the absolute phase error of the optical flat is obtained.

  7. Photoabsorption and photodissociation studies of dimethyl sulphoxide (DMSO) in the 35,000-80,000 cm-1 region using synchrotron radiation

    NASA Astrophysics Data System (ADS)

    Mandal, Anuvab; Singh, Param Jeet; Shastri, Aparna; Sunanda, K.; Jagatap, B. N.

    2015-05-01

    Photoabsorption and photodissociation studies of dimethyl sulphoxide and its deuterated isotopologue (DMSO-h6 and DMSO-d6) are performed using synchrotron radiation in the 35,000-80,000 cm-1 region. In the photoabsorption spectrum, Rydberg series converging to the first three ionization potentials of DMSO at 9.1, 10.1 and 12.3 eV corresponding to removal of an electron from the highest three occupied molecular orbitals (14a‧, 7a″ and 13a‧) are observed. Based on a quantum defect analysis, Rydberg series assignments are extended to higher members as compared to earlier works and a few ambiguities in earlier assignments are clarified. Analysis is aided by quantum chemical calculations using the DFT and TDDFT methodologies. Vibronic structures observed in the spectrum of DMSO-h6 in the regions 7.7-8.1 eV and 8.1-8.8 eV are attributed to the transitions 7a″→4p at 7.862 eV and 14a‧→6s/4d at 8.182 eV, respectively. Photoabsorption spectra of DMSO-h6 and -d6 recorded using a broad band incident radiation show prominent peaks, which are identified and assigned to electronic and vibronic transitions of the SO radical. This provides a direct confirmation of the fact that DMSO preferentially dissociates into CH3 and SO upon UV-VUV excitation, as proposed in earlier photodissociation studies. An extended vibronic band system associated with the e1Π-X3Σ- transition of the SO radical is identified and assigned. The complete VUV photoabsorption spectrum of DMSO-d6 is also reported here for the first time.

  8. Differential cross sections for ionization of methane, ammonia, and water vapor by high velocity ions

    SciTech Connect

    Wilson, W.E.; Miller, J.H.; Toburen, L.H.; Manson, S.T.

    1984-06-01

    Cross sections, differential in the energy of secondary electrons, for ionization of methane, ammonia, and water vapor by high energy protons are presented. The results are based on a model that uses photoabsorption and ion impact ionization data to evaluate the coefficients in Bethe's asymptotic cross section for inelastic scattering of high velocity ions. Model cross sections are compared with previously published data and new data on ionization of methane and water vapor by 3.0 and 4.2 MeV protons. The simple, analytic model should be very useful in transport calculations where differential ionization cross sections over a broad range of primary and secondary energies are needed.

  9. Strong light scattering and broadband (UV to IR) photoabsorption in stretchable 3D hybrid architectures based on Aerographite decorated by ZnO nanocrystallites.

    PubMed

    Tiginyanu, Ion; Ghimpu, Lidia; Gröttrup, Jorit; Postolache, Vitalie; Mecklenburg, Matthias; Stevens-Kalceff, Marion A; Ursaki, Veaceslav; Payami, Nader; Feidenhansl, Robert; Schulte, Karl; Adelung, Rainer; Mishra, Yogendra Kumar

    2016-01-01

    In present work, the nano- and microscale tetrapods from zinc oxide were integrated on the surface of Aerographite material (as backbone) in carbon-metal oxide hybrid hierarchical network via a simple and single step magnetron sputtering process. The fabricated hybrid networks are characterized for morphology, microstructural and optical properties. The cathodoluminescence investigations revealed interesting luminescence features related to carbon impurities and inherent host defects in zinc oxide. Because of the wide bandgap of zinc oxide and its intrinsic defects, the hybrid network absorbs light in the UV and visible regions, however, this broadband photoabsorption behavior extends to the infrared (IR) region due to the dependence of the optical properties of ZnO architectures upon size and shape of constituent nanostructures and their doping by carbon impurities. Such a phenomenon of broadband photoabsorption ranging from UV to IR for zinc oxide based hybrid materials is novel. Additionally, the fabricated network exhibits strong visible light scattering behavior. The developed Aerographite/nanocrystalline ZnO hybrid network materials, equipped with broadband photoabsorption and strong light scattering, are very promising candidates for optoelectronic technologies. PMID:27616632

  10. Absolute Integral Cross Sections for the State-selected Ion–Molecule Reaction N2+(X2Σg+ v+ = 0–2) + C2H2 in the Collision Energy Range of 0.03–10.00 eV

    NASA Astrophysics Data System (ADS)

    Xu, Yuntao; Xiong, Bo; Chung Chang, Yih; Ng, C. Y.

    2016-08-01

    Using the vacuum ultraviolet laser pulsed field ionization-photoion source, together with the double-quadrupole–double-octopole mass spectrometer developed in our laboratory, we have investigated the state-selected ion–molecule reaction {{{{N}}}2}+({X}2{{{{Σ }}}{{g}}}+; v + = 0–2, N+ = 0–9) + C2H2, achieving high internal-state selectivity and high kinetic energy resolution for reactant {{{{N}}}2}+ ions. The charge transfer (CT) and hydrogen-atom transfer (HT) channels, which lead to the respective formation of product {{{C}}}2{{{{H}}}2}+ and N2H+ ions, are observed. The vibrationally selected absolute integral cross sections for the CT [σ CT(v +)] and HT [[σ HT(v +)] channels obtained in the center-of-mass collision energy (E cm) range of 0.03–10.00 eV reveal opposite E cm dependences. The σ CT(v +) is found to increase as E cm is decreased, and is consistent with the long-range exothermic CT mechanism, whereas the E cm enhancement observed for the σ HT(v +) suggests effective coupling of kinetic energy to internal energy, enhancing the formation of N2H+. The σ HT(v +) curve exhibits a step at E cm = 0.70–1.00 eV, suggesting the involvement of the excited {{{C}}}2{{{{H}}}2}+({A}2{{{{Σ }}}{{g}}}+) state in the HT reaction. Contrary to the strong E cm dependences for σ CT(v +) and σ HT(v +), the effect of vibrational excitation of {{{{N}}}2}+ on both the CT and HT channels is marginal. The branching ratios and cross sections for the CT and HT channels determined in the present study are useful for modeling the atmospheric compositions of Saturn's largest moon, Titan. These cross sections and branching ratios are also valuable for benchmarking theoretical calculations on chemical dynamics of the titled reaction.

  11. The AFGL absolute gravity program

    NASA Technical Reports Server (NTRS)

    Hammond, J. A.; Iliff, R. L.

    1978-01-01

    A brief discussion of the AFGL's (Air Force Geophysics Laboratory) program in absolute gravity is presented. Support of outside work and in-house studies relating to gravity instrumentation are discussed. A description of the current transportable system is included and the latest results are presented. These results show good agreement with measurements at the AFGL site by an Italian system. The accuracy obtained by the transportable apparatus is better than 0.1 microns sq sec 10 microgal and agreement with previous measurements is within the combined uncertainties of the measurements.

  12. Absolute luminosity measurements with the LHCb detector at the LHC

    NASA Astrophysics Data System (ADS)

    LHCb Collaboration

    2012-01-01

    Absolute luminosity measurements are of general interest for colliding-beam experiments at storage rings. These measurements are necessary to determine the absolute cross-sections of reaction processes and are valuable to quantify the performance of the accelerator. Using data taken in 2010, LHCb has applied two methods to determine the absolute scale of its luminosity measurements for proton-proton collisions at the LHC with a centre-of-mass energy of 7 TeV. In addition to the classic ``van der Meer scan'' method a novel technique has been developed which makes use of direct imaging of the individual beams using beam-gas and beam-beam interactions. This beam imaging method is made possible by the high resolution of the LHCb vertex detector and the close proximity of the detector to the beams, and allows beam parameters such as positions, angles and widths to be determined. The results of the two methods have comparable precision and are in good agreement. Combining the two methods, an overal precision of 3.5% in the absolute luminosity determination is reached. The techniques used to transport the absolute luminosity calibration to the full 2010 data-taking period are presented.

  13. Measurements of Photoabsorpton Cross Sections and their Temperature Dependence for CO2 in the 170nm to 200nm Region

    NASA Astrophysics Data System (ADS)

    Parkinson, W. H.; Yoshino, K.

    2001-11-01

    All the photochemical models for the predominately CO2 Martian atmosphere ar e very sensitive to the amount of CO2 and to the values and spectral details of the absorpton cross sections of CO2 in the region 170nm-200nm. Earlier we had measured and published absolute cross sections of CO2 in the region 118.0 nm-175.5 nm at 295K and 195K. We have recently extended these measurements from 170 nm to 200 nm at 300K and 1 95K. The new measurements have been carried out at high resolution with our 6.65 -m normal incidence , photoelectric spectrometer. To measure the weak photoabsorption of the CO2 bands in the wavelength region 170 --200 nm, we required a high column density of the gas. We obtained this by using a multi pass technique, a White cell. The White cell was designed to have a distance of 1.50 m between two main mirrors, and was set for four, double pas ses making a path length of 12.0 m. CO2 gas was frozen in a stainless cylinder immersed in liquid nitrogen, and t he frozen product (dryice) was pumped by the diffusion pump for purification. The CO2 was warmed up slowly and kept in the cylinder at high pressure. The CO2 pressure used in the White cell was varied from 1 to 1000 Torr depend ing on the wavelength region, and was measured with a a capacitance manometer (M KS Baratron, 10 Torr and 1000 Torr). We divided the spectral region into twenty sections of about 1.5 nm extent. At each scan range, another scan was obtained from the emission spectrum of the fourth positive bands of CO for wavelength calibration. We acknowledge funding from NASA, grant NAGS-7859 to Harvard College Observatory.

  14. Direct potential and temperature effects on the MgHe line-core and far-wing photoabsorption profiles

    SciTech Connect

    Reggami, L.; Bouledroua, M.

    2011-03-15

    The present study deals with the collisional broadening of monatomic magnesium, evolving in a helium buffer gas, in the wavelength and temperature ranges 260-310 nm and 100-3000 K, respectively. The computed emission and absorption spectral profiles are based on the most recent potential-energy curves and transition dipole moments. The required interatomic Mg(3s{sup 2})+He(1s{sup 2}) and Mg(3s3p)+He(1s{sup 2}) potentials are constructed from two different sets. The purpose of this treatment is twofold. First, using the quantum-mechanical Baranger impact approximation, the width and shift of the line-core spectra are determined and their variation law with temperature is examined. Then, the satellite structures in the blue and red wings are analyzed quantum mechanically. The calculations show especially that the free-free transitions contribute most to the MgHe photoabsorption spectra and that a satellite structure is observable beyond the temperature 1800 K around the wavelengths 272 or 276 nm, depending on the used potential set. Weak satellites have also been investigated and, for all cases, the obtained results showed good agreement with those already published.

  15. Decomposition Process of Alane and Gallane Compounds in Metal-Organic Chemical Vapor Deposition Studied by Surface Photo-Absorption

    NASA Astrophysics Data System (ADS)

    Yamauchi, Yoshiharu; Kobayashi, Naoki

    1992-09-01

    We used surface photo-absorption (SPA) to study trimethylamine alane (TMAA) and dimethylamine gallane (DMAG) decomposition processes on a substrate surface in metal-organic chemical vapor deposition. The decomposition onset temperatures of these group III hydride sources correspond to the substrate temperature at which the SPA reflectivity starts to increase during the supply of the group III source onto a group V stabilized surface. It was found that TMAA and DMAG start to decompose at about 150°C on an As-stabilized surface, which is much lower than the decomposition onsets of trialkyl Al and Ga compounds. Low temperature photoluminescence spectra exhibit dominant excitionic emissions for GaAs layers grown by DMAG at substrate temperatures above 400°C, indicating that carbon incorporation and the crystal quality deterioration due to incomplete decomposition on surface is much suppressed by using DMAG. A comparison of AlGaAs photoluminescence between layers by TMAA/triethylgallium and triethylaluminum/triethylgallium shows that the band-to-carbon acceptor transition is greatly reduced by using TMAA. TMAA and DMAG were verified to be promising group III sources for low-temperature and high-purity growth with low-carbon incorporation.

  16. Cosmology with negative absolute temperatures

    NASA Astrophysics Data System (ADS)

    Vieira, J. P. P.; Byrnes, Christian T.; Lewis, Antony

    2016-08-01

    Negative absolute temperatures (NAT) are an exotic thermodynamical consequence of quantum physics which has been known since the 1950's (having been achieved in the lab on a number of occasions). Recently, the work of Braun et al. [1] has rekindled interest in negative temperatures and hinted at a possibility of using NAT systems in the lab as dark energy analogues. This paper goes one step further, looking into the cosmological consequences of the existence of a NAT component in the Universe. NAT-dominated expanding Universes experience a borderline phantom expansion (w < ‑1) with no Big Rip, and their contracting counterparts are forced to bounce after the energy density becomes sufficiently large. Both scenarios might be used to solve horizon and flatness problems analogously to standard inflation and bouncing cosmologies. We discuss the difficulties in obtaining and ending a NAT-dominated epoch, and possible ways of obtaining density perturbations with an acceptable spectrum.

  17. Neutron activation analysis of certified samples by the absolute method

    NASA Astrophysics Data System (ADS)

    Kadem, F.; Belouadah, N.; Idiri, Z.

    2015-07-01

    The nuclear reactions analysis technique is mainly based on the relative method or the use of activation cross sections. In order to validate nuclear data for the calculated cross section evaluated from systematic studies, we used the neutron activation analysis technique (NAA) to determine the various constituent concentrations of certified samples for animal blood, milk and hay. In this analysis, the absolute method is used. The neutron activation technique involves irradiating the sample and subsequently performing a measurement of the activity of the sample. The fundamental equation of the activation connects several physical parameters including the cross section that is essential for the quantitative determination of the different elements composing the sample without resorting to the use of standard sample. Called the absolute method, it allows a measurement as accurate as the relative method. The results obtained by the absolute method showed that the values are as precise as the relative method requiring the use of standard sample for each element to be quantified.

  18. Cross sections and reaction rates of relevance to aeronomy

    SciTech Connect

    Fox, J.L. )

    1991-01-01

    Experimental and theoretical data relevant to models and measurements of the chemical and thermal structures and luminosity of the thermospheres of the earth and planets published during the last four years are surveyed. Among chemical processes, attention is given to ion-molecule reactions, dissociative recombination of molecular ions, and reactions between neutral species. Both reactions between ground state species and species in excited states are considered, including energy transfer and quenching. Measured and calculated cross sections for interactions of solar radiation with atmospheric species, such as photoabsorption, photoionization, and photodissociation and related processes are surveyed.

  19. Improving HST Pointing & Absolute Astrometry

    NASA Astrophysics Data System (ADS)

    Lallo, Matthew; Nelan, E.; Kimmer, E.; Cox, C.; Casertano, S.

    2007-05-01

    Accurate absolute astrometry is becoming increasingly important in an era of multi-mission archives and virtual observatories. Hubble Space Telescope's (HST's) Guidestar Catalog II (GSC2) has reduced coordinate error to around 0.25 arcsecond, a factor 2 or more compared with GSC1. With this reduced catalog error, special attention must be given to calibrate and maintain the Fine Guidance Sensors (FGSs) and Science Instruments (SIs) alignments in HST to a level well below this in order to ensure that the accuracy of science product's astrometry keywords and target positioning are limited only by the catalog errors. After HST Servicing Mission 4, such calibrations' improvement in "blind" pointing accuracy will allow for more efficient COS acquisitions. Multiple SIs and FGSs each have their own footprints in the spatially shared HST focal plane. It is the small changes over time in primarily the whole-body positions & orientations of these instruments & guiders relative to one another that is addressed by this work. We describe the HST Cycle 15 program CAL/OTA 11021 which, along with future variants of it, determines and maintains positions and orientations of the SIs and FGSs to better than 50 milli- arcseconds and 0.04 to 0.004 degrees of roll, putting errors associated with the alignment sufficiently below GSC2 errors. We present recent alignment results and assess their errors, illustrate trends, and describe where and how the observer sees benefit from these calibrations when using HST.

  20. Absolute oral bioavailability of ciprofloxacin.

    PubMed

    Drusano, G L; Standiford, H C; Plaisance, K; Forrest, A; Leslie, J; Caldwell, J

    1986-09-01

    We evaluated the absolute bioavailability of ciprofloxacin, a new quinoline carboxylic acid, in 12 healthy male volunteers. Doses of 200 mg were given to each of the volunteers in a randomized, crossover manner 1 week apart orally and as a 10-min intravenous infusion. Half-lives (mean +/- standard deviation) for the intravenous and oral administration arms were 4.2 +/- 0.77 and 4.11 +/- 0.74 h, respectively. The serum clearance rate averaged 28.5 +/- 4.7 liters/h per 1.73 m2 for the intravenous administration arm. The renal clearance rate accounted for approximately 60% of the corresponding serum clearance rate and was 16.9 +/- 3.0 liters/h per 1.73 m2 for the intravenous arm and 17.0 +/- 2.86 liters/h per 1.73 m2 for the oral administration arm. Absorption was rapid, with peak concentrations in serum occurring at 0.71 +/- 0.15 h. Bioavailability, defined as the ratio of the area under the curve from 0 h to infinity for the oral to the intravenous dose, was 69 +/- 7%. We conclude that ciprofloxacin is rapidly absorbed and reliably bioavailable in these healthy volunteers. Further studies with ciprofloxacin should be undertaken in target patient populations under actual clinical circumstances. PMID:3777908

  1. Absolute Instability in Coupled-Cavity TWTs

    NASA Astrophysics Data System (ADS)

    Hung, D. M. H.; Rittersdorf, I. M.; Zhang, Peng; Lau, Y. Y.; Simon, D. H.; Gilgenbach, R. M.; Chernin, D.; Antonsen, T. M., Jr.

    2014-10-01

    This paper will present results of our analysis of absolute instability in a coupled-cavity traveling wave tube (TWT). The structure mode at the lower and upper band edges are respectively approximated by a hyperbola in the (omega, k) plane. When the Briggs-Bers criterion is applied, a threshold current for onset of absolute instability is observed at the upper band edge, but not the lower band edge. The nonexistence of absolute instability at the lower band edge is mathematically similar to the nonexistence of absolute instability that we recently demonstrated for a dielectric TWT. The existence of absolute instability at the upper band edge is mathematically similar to the existence of absolute instability in a gyroton traveling wave amplifier. These interesting observations will be discussed, and the practical implications will be explored. This work was supported by AFOSR, ONR, and L-3 Communications Electron Devices.

  2. Modélisation des effets de la photoabsorption K sur l'ADN

    NASA Astrophysics Data System (ADS)

    Vrigneaud, J. M.; Terrissol, M.

    1999-01-01

    Monte Carlo codes were used to simulate the transport of photons and their secondary electrons produced on a linear and hydrated DNA model. Between 150 and 550eV, the variation of photon cross section upon the K-ionisation threshold in C, N, O atoms of DNA is responsible for an increase of the biological effectiveness. We showed that, with the same number of absorbed photons, the distribution of breaks as a function of energy reaches a maximum around 450eV. Nous avons simulé le transport des photons et de leurs électrons secondaires mis en mouvement dans un modèle d'ADN linéaire hydraté, en utilisant la méthode de Monte Carlo. Entre 150 et 550 eV, la variation de section efficace photonique au- dessus du seuil d'ionisation K des atomes C, N, O de l'ADN est responsable d'un accroissement de l'efficacité biologique. Nous avons montré que, pour un même nombre de photons absorbés, la distribution des cassures en fonction de l'énergie passe par un maximum autour de 450 eV.

  3. Absolute negative mobility of interacting Brownian particles

    NASA Astrophysics Data System (ADS)

    Ou, Ya-li; Hu, Cai-tian; Wu, Jian-chun; Ai, Bao-quan

    2015-12-01

    Transport of interacting Brownian particles in a periodic potential is investigated in the presence of an ac force and a dc force. From Brownian dynamic simulations, we find that both the interaction between particles and the thermal fluctuations play key roles in the absolute negative mobility (the particle noisily moves backwards against a small constant bias). When no the interaction acts, there is only one region where the absolute negative mobility occurs. In the presence of the interaction, the absolute negative mobility may appear in multiple regions. The weak interaction can be helpful for the absolute negative mobility, while the strong interaction has a destructive impact on it.

  4. Absolute instability from linear conversion of counter-propagating positive and negative energy waves

    SciTech Connect

    Kaufman, A.N.; Brizard, A.J.; Morehead, J.J.; Tracy, E.R.

    1997-12-31

    The resonant interaction of a negative-energy wave with a positive-energy wave gives rise to a linear instability. Whereas a single crossing of rays in a nonuniform medium leads to a convectively saturated instability, we show that a double crossing can yield an absolute instability.

  5. Inequalities, Absolute Value, and Logical Connectives.

    ERIC Educational Resources Information Center

    Parish, Charles R.

    1992-01-01

    Presents an approach to the concept of absolute value that alleviates students' problems with the traditional definition and the use of logical connectives in solving related problems. Uses a model that maps numbers from a horizontal number line to a vertical ray originating from the origin. Provides examples solving absolute value equations and…

  6. Absolute optical metrology : nanometers to kilometers

    NASA Technical Reports Server (NTRS)

    Dubovitsky, Serge; Lay, O. P.; Peters, R. D.; Liebe, C. C.

    2005-01-01

    We provide and overview of the developments in the field of high-accuracy absolute optical metrology with emphasis on space-based applications. Specific work on the Modulation Sideband Technology for Absolute Ranging (MSTAR) sensor is described along with novel applications of the sensor.

  7. Monolithically integrated absolute frequency comb laser system

    DOEpatents

    Wanke, Michael C.

    2016-07-12

    Rather than down-convert optical frequencies, a QCL laser system directly generates a THz frequency comb in a compact monolithically integrated chip that can be locked to an absolute frequency without the need of a frequency-comb synthesizer. The monolithic, absolute frequency comb can provide a THz frequency reference and tool for high-resolution broad band spectroscopy.

  8. Introducing the Mean Absolute Deviation "Effect" Size

    ERIC Educational Resources Information Center

    Gorard, Stephen

    2015-01-01

    This paper revisits the use of effect sizes in the analysis of experimental and similar results, and reminds readers of the relative advantages of the mean absolute deviation as a measure of variation, as opposed to the more complex standard deviation. The mean absolute deviation is easier to use and understand, and more tolerant of extreme…

  9. Investigating Absolute Value: A Real World Application

    ERIC Educational Resources Information Center

    Kidd, Margaret; Pagni, David

    2009-01-01

    Making connections between various representations is important in mathematics. In this article, the authors discuss the numeric, algebraic, and graphical representations of sums of absolute values of linear functions. The initial explanations are accessible to all students who have experience graphing and who understand that absolute value simply…

  10. Absolute Income, Relative Income, and Happiness

    ERIC Educational Resources Information Center

    Ball, Richard; Chernova, Kateryna

    2008-01-01

    This paper uses data from the World Values Survey to investigate how an individual's self-reported happiness is related to (i) the level of her income in absolute terms, and (ii) the level of her income relative to other people in her country. The main findings are that (i) both absolute and relative income are positively and significantly…

  11. Absolute instability of the Gaussian wake profile

    NASA Technical Reports Server (NTRS)

    Hultgren, Lennart S.; Aggarwal, Arun K.

    1987-01-01

    Linear parallel-flow stability theory has been used to investigate the effect of viscosity on the local absolute instability of a family of wake profiles with a Gaussian velocity distribution. The type of local instability, i.e., convective or absolute, is determined by the location of a branch-point singularity with zero group velocity of the complex dispersion relation for the instability waves. The effects of viscosity were found to be weak for values of the wake Reynolds number, based on the center-line velocity defect and the wake half-width, larger than about 400. Absolute instability occurs only for sufficiently large values of the center-line wake defect. The critical value of this parameter increases with decreasing wake Reynolds number, thereby indicating a shrinking region of absolute instability with decreasing wake Reynolds number. If backflow is not allowed, absolute instability does not occur for wake Reynolds numbers smaller than about 38.

  12. Au photofission cross section by quasimonochromatic photons in the intermediate energy region

    SciTech Connect

    Lucherini, V.; Guaraldo, C.; De Sanctis, E.; Sandri, P.L.; Polli, E.; Reolon, A.R.; Iljinov, A.S.; Lo Nigro, S.; Aiello, S.; Bellini, V.; and others

    1989-03-01

    The photofission cross section of Au was determined in the energy range 100--300 MeV by means of a quasimonochromatic photon beam. The nuclear fissility P/sub f/ was calculated using the recently measured total photoabsorption cross sections. The nuclear excitation energy E/sup */, charge and mass of compound nucleus were obtained by means of an intranuclear cascade Monte Carlo calculation. The fissility values determined for Au, Bi, and U were compared with the predictions of the cascade-evaporation model and remarkably fitted by the calculation.

  13. High-resolution absorption cross sections of carbon monoxide bands at 295 K between 91.7 and 100.4 nanometers

    NASA Technical Reports Server (NTRS)

    Stark, G.; Yoshino, K.; Smith, Peter L.; Ito, K.; Parkinson, W. H.

    1991-01-01

    Theoretical descriptions of the abundance and excitation of carbon monoxide in interstellar clouds require accurate data on the vacuum-ultraviolet absorption spectrum of the molecule. The 6.65 m spectrometer at the Photon Factory synchrotron light source was used to measure photoabsorption cross sections of CO features between 91.2 and 100.4 nm. These data were recorded at a resolving power of 170,000, more than 20 times greater than that used in previous work.

  14. Absolute optical instruments without spherical symmetry

    NASA Astrophysics Data System (ADS)

    Tyc, Tomáš; Dao, H. L.; Danner, Aaron J.

    2015-11-01

    Until now, the known set of absolute optical instruments has been limited to those containing high levels of symmetry. Here, we demonstrate a method of mathematically constructing refractive index profiles that result in asymmetric absolute optical instruments. The method is based on the analogy between geometrical optics and classical mechanics and employs Lagrangians that separate in Cartesian coordinates. In addition, our method can be used to construct the index profiles of most previously known absolute optical instruments, as well as infinitely many different ones.

  15. Strategy for the absolute neutron emission measurement on ITER

    SciTech Connect

    Sasao, M.; Bertalot, L.; Ishikawa, M.; Popovichev, S.

    2010-10-15

    Accuracy of 10% is demanded to the absolute fusion measurement on ITER. To achieve this accuracy, a functional combination of several types of neutron measurement subsystem, cross calibration among them, and in situ calibration are needed. Neutron transport calculation shows the suitable calibration source is a DT/DD neutron generator of source strength higher than 10{sup 10} n/s (neutron/second) for DT and 10{sup 8} n/s for DD. It will take eight weeks at the minimum with this source to calibrate flux monitors, profile monitors, and the activation system.

  16. Son preference in Indian families: absolute versus relative wealth effects.

    PubMed

    Gaudin, Sylvestre

    2011-02-01

    The desire for male children is prevalent in India, where son preference has been shown to affect fertility behavior and intrahousehold allocation of resources. Economic theory predicts less gender discrimination in wealthier households, but demographers and sociologists have argued that wealth can exacerbate bias in the Indian context. I argue that these apparently conflicting theories can be reconciled and simultaneously tested if one considers that they are based on two different notions of wealth: one related to resource constraints (absolute wealth), and the other to notions of local status (relative wealth). Using cross-sectional data from the 1998-1999 and 2005-2006 National Family and Health Surveys, I construct measures of absolute and relative wealth by using principal components analysis. A series of statistical models of son preference is estimated by using multilevel methods. Results consistently show that higher absolute wealth is strongly associated with lower son preference, and the effect is 20%-40% stronger when the household's community-specific wealth score is included in the regression. Coefficients on relative wealth are positive and significant although lower in magnitude. Results are robust to using different samples, alternative groupings of households in local areas, different estimation methods, and alternative dependent variables. PMID:21302027

  17. Absolute magnitudes of trans-neptunian objects

    NASA Astrophysics Data System (ADS)

    Duffard, R.; Alvarez-candal, A.; Pinilla-Alonso, N.; Ortiz, J. L.; Morales, N.; Santos-Sanz, P.; Thirouin, A.

    2015-10-01

    Accurate measurements of diameters of trans- Neptunian objects are extremely complicated to obtain. Radiomatric techniques applied to thermal measurements can provide good results, but precise absolute magnitudes are needed to constrain diameters and albedos. Our objective is to measure accurate absolute magnitudes for a sample of trans- Neptunian objects, many of which have been observed, and modelled, by the "TNOs are cool" team, one of Herschel Space Observatory key projects grantes with ~ 400 hours of observing time. We observed 56 objects in filters V and R, if possible. These data, along with data available in the literature, was used to obtain phase curves and to measure absolute magnitudes by assuming a linear trend of the phase curves and considering magnitude variability due to rotational light-curve. In total we obtained 234 new magnitudes for the 56 objects, 6 of them with no reported previous measurements. Including the data from the literature we report a total of 109 absolute magnitudes.

  18. A New Gimmick for Assigning Absolute Configuration.

    ERIC Educational Resources Information Center

    Ayorinde, F. O.

    1983-01-01

    A five-step procedure is provided to help students in making the assignment absolute configuration less bothersome. Examples for both single (2-butanol) and multi-chiral carbon (3-chloro-2-butanol) molecules are included. (JN)

  19. Karst Water System Investigated by Absolute Gravimetry

    NASA Astrophysics Data System (ADS)

    Quinif, Y.; Meus, P.; van Camp, M.; Kaufmann, O.; van Ruymbeke, M.; Vandiepenbeeck, M.; Camelbeeck, T.

    2006-12-01

    The highly anisotropic and heterogeneous hydrogeological characteristics of karst aquifers are difficult to characterize and present challenges for modeling of storage capacities. Little is known about the surface and groundwater interconnection, about the connection between the porous formations and the draining cave and conduits, and about the variability of groundwater volume within the system. Usually, an aquifer is considered as a black box, where water fluxes are monitored as input and output. However, water inflow and outflow are highly variable and cannot be measured directly. A recent project, begun in 2006 sought to constrain the water budget in a Belgian karst aquifer and to assess the porosity and water dynamics, combining absolute gravity (AG) measurements and piezometric levels around the Rochefort cave. The advantage of gravity measurements is that they integrate all the subsystems in the karst system. This is not the case with traditional geophysical tools like boring or monitoring wells, which are soundings affected by their near environment and its heterogeneity. The investigated cave results from the meander cutoff system of the Lomme River. The main inputs are swallow holes of the river crossing the limestone massif. The river is canalized and the karst system is partly disconnected from the hydraulic system. In February and March 2006, when the river spilled over its dyke and sank into the most important swallow hole, this resulted in dramatic and nearly instantaneous increases in the piezometric levels in the cave, reaching up to 13 meters. Meanwhile, gravity increased by 50 and 90 nms-2 in February and March, respectively. A first conclusion is that during these sudden floods, the pores and fine fissures were poorly connected with the enlarged fractures, cave, and conduits. With a rise of 13 meters in the water level and a 5% porosity, a gravity change of 250 nms-2 should have been expected. This moderate gravity variation suggests either a

  20. Jasminum flexile flower absolute from India--a detailed comparison with three other jasmine absolutes.

    PubMed

    Braun, Norbert A; Kohlenberg, Birgit; Sim, Sherina; Meier, Manfred; Hammerschmidt, Franz-Josef

    2009-09-01

    Jasminum flexile flower absolute from the south of India and the corresponding vacuum headspace (VHS) sample of the absolute were analyzed using GC and GC-MS. Three other commercially available Indian jasmine absolutes from the species: J. sambac, J. officinale subsp. grandiflorum, and J. auriculatum and the respective VHS samples were used for comparison purposes. One hundred and twenty-one compounds were characterized in J. flexile flower absolute, with methyl linolate, benzyl salicylate, benzyl benzoate, (2E,6E)-farnesol, and benzyl acetate as the main constituents. A detailed olfactory evaluation was also performed. PMID:19831037

  1. Measurement and calculation of absolute cross sections for excitation of the 3s{sup 2}3p {sup 2}P{sub 1} at {sub {approx}}{sub sol{approx}} at {sub 2}{sup o}-3s{sup 2}3p {sup 2}P{sub 3} at {sub {approx}} {sub sol{approx}} at {sub 2}{sup o} fine-structure transition in Fe{sup 13+}

    SciTech Connect

    Hossain, S.; Smith, S. J.; Chutjian, A.; Tayal, S. S.; Raymond, J. C.

    2007-02-15

    Experimental cross sections are reported for the Fe{sup 13+} coronal green line transition 3s{sup 2}3p {sup 2}P{sub 1} at {sub {approx}}{sub sol{approx}} at {sub 2}{sup o}-3s{sup 2}3p {sup 2}P{sub 3} at {sub {approx}}{sub sol{approx}} at {sub 2}{sup o} at {lambda}5303 A ring (2.338 eV). The center-of-mass interaction energies are in the range 1.7 eV (below threshold) through threshold, to 6.6 eV (2.9xthreshold). Data are compared with results of a 135-level Breit-Pauli R-matrix theory. Present experiment detects a strong maximum in the excitation cross section of magnitude 15x10{sup -16} cm{sup 2} at 2.6 eV. Smaller structures are observed between 3 eV and 6.6 eV, with a maximum cross section never exceeding about 1.2x10{sup -16} cm{sup 2}. All features are due to enhancement of the direct excitation via a multitude of narrow, closely-spaced resonances calculated by the theory, the effects of which are convoluted by the 125 meV energy resolution of the present experiment. Iron is present in practically every astrophysical object, as well as being an impurity in fusion plasmas. Present results are the highest charge state in any ion for which an absolute excitation cross section has been measured.

  2. Universal Cosmic Absolute and Modern Science

    NASA Astrophysics Data System (ADS)

    Kostro, Ludwik

    The official Sciences, especially all natural sciences, respect in their researches the principle of methodic naturalism i.e. they consider all phenomena as entirely natural and therefore in their scientific explanations they do never adduce or cite supernatural entities and forces. The purpose of this paper is to show that Modern Science has its own self-existent, self-acting, and self-sufficient Natural All-in Being or Omni-Being i.e. the entire Nature as a Whole that justifies the scientific methodic naturalism. Since this Natural All-in Being is one and only It should be considered as the own scientifically justified Natural Absolute of Science and should be called, in my opinion, the Universal Cosmic Absolute of Modern Science. It will be also shown that the Universal Cosmic Absolute is ontologically enormously stratified and is in its ultimate i.e. in its most fundamental stratum trans-reistic and trans-personal. It means that in its basic stratum. It is neither a Thing or a Person although It contains in Itself all things and persons with all other sentient and conscious individuals as well, On the turn of the 20th century the Science has begun to look for a theory of everything, for a final theory, for a master theory. In my opinion the natural Universal Cosmic Absolute will constitute in such a theory the radical all penetrating Ultimate Basic Reality and will substitute step by step the traditional supernatural personal Absolute.

  3. Absolute isotopic abundances of TI in meteorites

    NASA Astrophysics Data System (ADS)

    Niederer, F. R.; Papanastassiou, D. A.; Wasserburg, G. J.

    1985-03-01

    The absolute isotope abundance of Ti has been determined in Ca-Al-rich inclusions from the Allende and Leoville meteorites and in samples of whole meteorites. The absolute Ti isotope abundances differ by a significant mass dependent isotope fractionation transformation from the previously reported abundances, which were normalized for fractionation using 46Ti/48Ti. Therefore, the absolute compositions define distinct nucleosynthetic components from those previously identified or reflect the existence of significant mass dependent isotope fractionation in nature. The authors provide a general formalism for determining the possible isotope compositions of the exotic Ti from the measured composition, for different values of isotope fractionation in nature and for different mixing ratios of the exotic and normal components.

  4. Molecular iodine absolute frequencies. Final report

    SciTech Connect

    Sansonetti, C.J.

    1990-06-25

    Fifty specified lines of {sup 127}I{sub 2} were studied by Doppler-free frequency modulation spectroscopy. For each line the classification of the molecular transition was determined, hyperfine components were identified, and one well-resolved component was selected for precise determination of its absolute frequency. In 3 cases, a nearby alternate line was selected for measurement because no well-resolved component was found for the specified line. Absolute frequency determinations were made with an estimated uncertainty of 1.1 MHz by locking a dye laser to the selected hyperfine component and measuring its wave number with a high-precision Fabry-Perot wavemeter. For each line results of the absolute measurement, the line classification, and a Doppler-free spectrum are given.

  5. Stimulus probability effects in absolute identification.

    PubMed

    Kent, Christopher; Lamberts, Koen

    2016-05-01

    This study investigated the effect of stimulus presentation probability on accuracy and response times in an absolute identification task. Three schedules of presentation were used to investigate the interaction between presentation probability and stimulus position within the set. Data from individual participants indicated strong effects of presentation probability on both proportion correct and response times. The effects were moderated by the ubiquitous stimulus position effect. The accuracy and response time data were predicted by an exemplar-based model of perceptual cognition (Kent & Lamberts, 2005). The bow in discriminability was also attenuated when presentation probability for middle items was relatively high, an effect that will constrain future model development. The study provides evidence for item-specific learning in absolute identification. Implications for other theories of absolute identification are discussed. (PsycINFO Database Record PMID:26478959

  6. Absolute calibration in vivo measurement systems

    SciTech Connect

    Kruchten, D.A.; Hickman, D.P.

    1991-02-01

    Lawrence Livermore National Laboratory (LLNL) is currently investigating a new method for obtaining absolute calibration factors for radiation measurement systems used to measure internally deposited radionuclides in vivo. Absolute calibration of in vivo measurement systems will eliminate the need to generate a series of human surrogate structures (i.e., phantoms) for calibrating in vivo measurement systems. The absolute calibration of in vivo measurement systems utilizes magnetic resonance imaging (MRI) to define physiological structure, size, and composition. The MRI image provides a digitized representation of the physiological structure, which allows for any mathematical distribution of radionuclides within the body. Using Monte Carlo transport codes, the emission spectrum from the body is predicted. The in vivo measurement equipment is calibrated using the Monte Carlo code and adjusting for the intrinsic properties of the detection system. The calibration factors are verified using measurements of existing phantoms and previously obtained measurements of human volunteers. 8 refs.

  7. Precise Measurement of the Absolute Fluorescence Yield

    NASA Astrophysics Data System (ADS)

    Ave, M.; Bohacova, M.; Daumiller, K.; Di Carlo, P.; di Giulio, C.; San Luis, P. Facal; Gonzales, D.; Hojvat, C.; Hörandel, J. R.; Hrabovsky, M.; Iarlori, M.; Keilhauer, B.; Klages, H.; Kleifges, M.; Kuehn, F.; Monasor, M.; Nozka, L.; Palatka, M.; Petrera, S.; Privitera, P.; Ridky, J.; Rizi, V.; D'Orfeuil, B. Rouille; Salamida, F.; Schovanek, P.; Smida, R.; Spinka, H.; Ulrich, A.; Verzi, V.; Williams, C.

    2011-09-01

    We present preliminary results of the absolute yield of fluorescence emission in atmospheric gases. Measurements were performed at the Fermilab Test Beam Facility with a variety of beam particles and gases. Absolute calibration of the fluorescence yield to 5% level was achieved by comparison with two known light sources--the Cherenkov light emitted by the beam particles, and a calibrated nitrogen laser. The uncertainty of the energy scale of current Ultra-High Energy Cosmic Rays experiments will be significantly improved by the AIRFLY measurement.

  8. Absolutely relative or relatively absolute: violations of value invariance in human decision making.

    PubMed

    Teodorescu, Andrei R; Moran, Rani; Usher, Marius

    2016-02-01

    Making decisions based on relative rather than absolute information processing is tied to choice optimality via the accumulation of evidence differences and to canonical neural processing via accumulation of evidence ratios. These theoretical frameworks predict invariance of decision latencies to absolute intensities that maintain differences and ratios, respectively. While information about the absolute values of the choice alternatives is not necessary for choosing the best alternative, it may nevertheless hold valuable information about the context of the decision. To test the sensitivity of human decision making to absolute values, we manipulated the intensities of brightness stimuli pairs while preserving either their differences or their ratios. Although asked to choose the brighter alternative relative to the other, participants responded faster to higher absolute values. Thus, our results provide empirical evidence for human sensitivity to task irrelevant absolute values indicating a hard-wired mechanism that precedes executive control. Computational investigations of several modelling architectures reveal two alternative accounts for this phenomenon, which combine absolute and relative processing. One account involves accumulation of differences with activation dependent processing noise and the other emerges from accumulation of absolute values subject to the temporal dynamics of lateral inhibition. The potential adaptive role of such choice mechanisms is discussed. PMID:26022836

  9. Resonant and Near-Threshold Photoionization Cross Sections of Fe{sup 14+}

    SciTech Connect

    Simon, M. C.; Crespo Lopez-Urrutia, J. R.; Beilmann, C.; Schwarz, M.; Epp, S. W.; Schmitt, B. L.; Baumann, T. M.; Bernitt, S.; Ginzel, R.; Keitel, C. H.; Klawitter, R.; Kubicek, K.; Maeckel, V.; Mokler, P. H.; Ullrich, J.; Harman, Z.; Behar, E.; Follath, R.; Reichardt, G.; Schwarzkopf, O.

    2010-10-29

    Photoionization (PI) of Fe{sup 14+} in the range from 450 to 1100 eV was measured at the BESSY II storage ring using an electron beam ion trap achieving high target-ion area densities of 10{sup 10} cm{sup -2}. Photoabsorption by this ion is observed in astrophysical spectra and plasmas, but until now cross sections and resonance energies could only be provided by calculations. We reach a resolving power E/{Delta}E of at least 6500, outstanding in the present energy range, which enables benchmarking and improving the most advanced theories for PI of ions in high charge states.

  10. Cross section measurement on 139La (γ,γ') below neutron separation energy

    NASA Astrophysics Data System (ADS)

    Makinaga, A.; Rusev, G.; Schwengner, R.; Dönau, F.; Beyer, R.; Bemmerer, D.; Crespo, P.; Erhard, M.; Junghans, A. R.; Klug, J.; Nair, C.; Schilling, K. D.; Wagner, A.

    2010-06-01

    The γ-ray strength function is an important input quantity for the determination of the photoreaction rate and the neutron capture rate for astrophysics as well as for nuclear technologies. Recent studies show that extra γ-ray strength near the neutron separation energy Sn (pygmy resonance) affects the stellar reaction rate strongly. In this work, the photoabsorption cross section for 139La below Sn was measured using bremsstrahlung produced at the electron accelerator ELBE of Eorschungszentrum Dresden-Rossendorf with an electron beam of 11.5 MeV kinetic energy. Experimental result of 139La is presented.

  11. Solving Absolute Value Equations Algebraically and Geometrically

    ERIC Educational Resources Information Center

    Shiyuan, Wei

    2005-01-01

    The way in which students can improve their comprehension by understanding the geometrical meaning of algebraic equations or solving algebraic equation geometrically is described. Students can experiment with the conditions of the absolute value equation presented, for an interesting way to form an overall understanding of the concept.

  12. Teaching Absolute Value Inequalities to Mature Students

    ERIC Educational Resources Information Center

    Sierpinska, Anna; Bobos, Georgeana; Pruncut, Andreea

    2011-01-01

    This paper gives an account of a teaching experiment on absolute value inequalities, whose aim was to identify characteristics of an approach that would realize the potential of the topic to develop theoretical thinking in students enrolled in prerequisite mathematics courses at a large, urban North American university. The potential is…

  13. Increasing Capacity: Practice Effects in Absolute Identification

    ERIC Educational Resources Information Center

    Dodds, Pennie; Donkin, Christopher; Brown, Scott D.; Heathcote, Andrew

    2011-01-01

    In most of the long history of the study of absolute identification--since Miller's (1956) seminal article--a severe limit on performance has been observed, and this limit has resisted improvement even by extensive practice. In a startling result, Rouder, Morey, Cowan, and Pfaltz (2004) found substantially improved performance with practice in the…

  14. On Relative and Absolute Conviction in Mathematics

    ERIC Educational Resources Information Center

    Weber, Keith; Mejia-Ramos, Juan Pablo

    2015-01-01

    Conviction is a central construct in mathematics education research on justification and proof. In this paper, we claim that it is important to distinguish between absolute conviction and relative conviction. We argue that researchers in mathematics education frequently have not done so and this has lead to researchers making unwarranted claims…

  15. Absolute Points for Multiple Assignment Problems

    ERIC Educational Resources Information Center

    Adlakha, V.; Kowalski, K.

    2006-01-01

    An algorithm is presented to solve multiple assignment problems in which a cost is incurred only when an assignment is made at a given cell. The proposed method recursively searches for single/group absolute points to identify cells that must be loaded in any optimal solution. Unlike other methods, the first solution is the optimal solution. The…

  16. Nonequilibrium equalities in absolutely irreversible processes

    NASA Astrophysics Data System (ADS)

    Murashita, Yuto; Funo, Ken; Ueda, Masahito

    2015-03-01

    Nonequilibrium equalities have attracted considerable attention in the context of statistical mechanics and information thermodynamics. Integral nonequilibrium equalities reveal an ensemble property of the entropy production σ as = 1 . Although nonequilibrium equalities apply to rather general nonequilibrium situations, they break down in absolutely irreversible processes, where the forward-path probability vanishes and the entropy production diverges. We identify the mathematical origins of this inapplicability as the singularity of probability measure. As a result, we generalize conventional integral nonequilibrium equalities to absolutely irreversible processes as = 1 -λS , where λS is the probability of the singular part defined based on Lebesgue's decomposition theorem. The acquired equality contains two physical quantities related to irreversibility: σ characterizing ordinary irreversibility and λS describing absolute irreversibility. An inequality derived from the obtained equality demonstrates the absolute irreversibility leads to the fundamental lower bound on the entropy production. We demonstrate the validity of the obtained equality for a simple model.

  17. Stimulus Probability Effects in Absolute Identification

    ERIC Educational Resources Information Center

    Kent, Christopher; Lamberts, Koen

    2016-01-01

    This study investigated the effect of stimulus presentation probability on accuracy and response times in an absolute identification task. Three schedules of presentation were used to investigate the interaction between presentation probability and stimulus position within the set. Data from individual participants indicated strong effects of…

  18. Precision absolute positional measurement of laser beams.

    PubMed

    Fitzsimons, Ewan D; Bogenstahl, Johanna; Hough, James; Killow, Christian J; Perreur-Lloyd, Michael; Robertson, David I; Ward, Henry

    2013-04-20

    We describe an instrument which, coupled with a suitable coordinate measuring machine, facilitates the absolute measurement within the machine frame of the propagation direction of a millimeter-scale laser beam to an accuracy of around ±4 μm in position and ±20 μrad in angle. PMID:23669658

  19. A three-axis SQUID-based absolute vector magnetometer

    NASA Astrophysics Data System (ADS)

    Schönau, T.; Zakosarenko, V.; Schmelz, M.; Stolz, R.; Anders, S.; Linzen, S.; Meyer, M.; Meyer, H.-G.

    2015-10-01

    We report on the development of a three-axis absolute vector magnetometer suited for mobile operation in the Earth's magnetic field. It is based on low critical temperature dc superconducting quantum interference devices (LTS dc SQUIDs) with sub-micrometer sized cross-type Josephson junctions and exhibits a white noise level of about 10 fT/Hz1/2. The width of superconducting strip lines is restricted to less than 6 μm in order to avoid flux trapping during cool-down in magnetically unshielded environment. The long-term stability of the flux-to-voltage transfer coefficients of the SQUID electronics is investigated in detail and a method is presented to significantly increase their reproducibility. We further demonstrate the long-term operation of the setup in a magnetic field varying by about 200 μT amplitude without the need for recalibration.

  20. Landsat-5 TM reflective-band absolute radiometric calibration

    USGS Publications Warehouse

    Chander, G.; Helder, D.L.; Markham, B.L.; Dewald, J.D.; Kaita, E.; Thome, K.J.; Micijevic, E.; Ruggles, T.A.

    2004-01-01

    The Landsat-5 Thematic Mapper (TM) sensor provides the longest running continuous dataset of moderate spatial resolution remote sensing imagery, dating back to its launch in March 1984. Historically, the radiometric calibration procedure for this imagery used the instrument's response to the Internal Calibrator (IC) on a scene-by-scene basis to determine the gain and offset of each detector. Due to observed degradations in the IC, a new procedure was implemented for U.S.-processed data in May 2003. This new calibration procedure is based on a lifetime radiometric calibration model for the instrument's reflective bands (1-5 and 7) and is derived, in part, from the IC response without the related degradation effects and is tied to the cross calibration with the Landsat-7 Enhanced Thematic Mapper Plus. Reflective-band absolute radiometric accuracy of the instrument tends to be on the order of 7% to 10%, based on a variety of calibration methods.

  1. Upgrade of absolute extreme ultraviolet diagnostic on J-TEXT.

    PubMed

    Zhang, X L; Cheng, Z F; Hou, S Y; Zhuang, G; Luo, J

    2014-11-01

    The absolute extreme ultraviolet (AXUV) diagnostic system is used for radiation observation on J-TEXT tokamak [J. Zhang, G. Zhuang, Z. J. Wang, Y. H. Ding, X. Q. Zhang, and Y. J. Tang, Rev. Sci. Instrum. 81, 073509 (2010)]. The upgrade of the AXUV system is aimed to improve the spatial resolution and provide a three-dimensional image on J-TEXT. The new system consists of 12 AXUV arrays (4 AXUV16ELG arrays, 8 AXUV20ELG arrays). The spatial resolution in the cross-section is 21 mm for the AXUV16ELG arrays and 17 mm for the AXUV20ELG arrays. The pre-amplifier is also upgraded for a higher signal to noise ratio. By upgrading the AXUV imaging system, a more accurate observation on the radiation information is obtained. PMID:25430327

  2. Upgrade of absolute extreme ultraviolet diagnostic on J-TEXT

    SciTech Connect

    Zhang, X. L.; Cheng, Z. F. Hou, S. Y.; Zhuang, G.; Luo, J.

    2014-11-15

    The absolute extreme ultraviolet (AXUV) diagnostic system is used for radiation observation on J-TEXT tokamak [J. Zhang, G. Zhuang, Z. J. Wang, Y. H. Ding, X. Q. Zhang, and Y. J. Tang, Rev. Sci. Instrum. 81, 073509 (2010)]. The upgrade of the AXUV system is aimed to improve the spatial resolution and provide a three-dimensional image on J-TEXT. The new system consists of 12 AXUV arrays (4 AXUV16ELG arrays, 8 AXUV20ELG arrays). The spatial resolution in the cross-section is 21 mm for the AXUV16ELG arrays and 17 mm for the AXUV20ELG arrays. The pre-amplifier is also upgraded for a higher signal to noise ratio. By upgrading the AXUV imaging system, a more accurate observation on the radiation information is obtained.

  3. A three-axis SQUID-based absolute vector magnetometer

    SciTech Connect

    Schönau, T.; Schmelz, M.; Stolz, R.; Anders, S.; Linzen, S.; Meyer, H.-G.; Zakosarenko, V.; Meyer, M.

    2015-10-15

    We report on the development of a three-axis absolute vector magnetometer suited for mobile operation in the Earth’s magnetic field. It is based on low critical temperature dc superconducting quantum interference devices (LTS dc SQUIDs) with sub-micrometer sized cross-type Josephson junctions and exhibits a white noise level of about 10 fT/Hz{sup 1/2}. The width of superconducting strip lines is restricted to less than 6 μm in order to avoid flux trapping during cool-down in magnetically unshielded environment. The long-term stability of the flux-to-voltage transfer coefficients of the SQUID electronics is investigated in detail and a method is presented to significantly increase their reproducibility. We further demonstrate the long-term operation of the setup in a magnetic field varying by about 200 μT amplitude without the need for recalibration.

  4. Absolute and relative dosimetry for ELIMED

    SciTech Connect

    Cirrone, G. A. P.; Schillaci, F.; Scuderi, V.; Cuttone, G.; Candiano, G.; Musumarra, A.; Pisciotta, P.; Romano, F.; Carpinelli, M.; Presti, D. Lo; Raffaele, L.; Tramontana, A.; Cirio, R.; Sacchi, R.; Monaco, V.; Marchetto, F.; Giordanengo, S.

    2013-07-26

    The definition of detectors, methods and procedures for the absolute and relative dosimetry of laser-driven proton beams is a crucial step toward the clinical use of this new kind of beams. Hence, one of the ELIMED task, will be the definition of procedures aiming to obtain an absolute dose measure at the end of the transport beamline with an accuracy as close as possible to the one required for clinical applications (i.e. of the order of 5% or less). Relative dosimetry procedures must be established, as well: they are necessary in order to determine and verify the beam dose distributions and to monitor the beam fluence and the energetic spectra during irradiations. Radiochromic films, CR39, Faraday Cup, Secondary Emission Monitor (SEM) and transmission ionization chamber will be considered, designed and studied in order to perform a fully dosimetric characterization of the ELIMED proton beam.

  5. Probing absolute spin polarization at the nanoscale.

    PubMed

    Eltschka, Matthias; Jäck, Berthold; Assig, Maximilian; Kondrashov, Oleg V; Skvortsov, Mikhail A; Etzkorn, Markus; Ast, Christian R; Kern, Klaus

    2014-12-10

    Probing absolute values of spin polarization at the nanoscale offers insight into the fundamental mechanisms of spin-dependent transport. Employing the Zeeman splitting in superconducting tips (Meservey-Tedrow-Fulde effect), we introduce a novel spin-polarized scanning tunneling microscopy that combines the probing capability of the absolute values of spin polarization with precise control at the atomic scale. We utilize our novel approach to measure the locally resolved spin polarization of magnetic Co nanoislands on Cu(111). We find that the spin polarization is enhanced by 65% when increasing the width of the tunnel barrier by only 2.3 Å due to the different decay of the electron orbitals into vacuum. PMID:25423049

  6. Absolute-magnitude distributions of supernovae

    SciTech Connect

    Richardson, Dean; Wright, John; Jenkins III, Robert L.; Maddox, Larry

    2014-05-01

    The absolute-magnitude distributions of seven supernova (SN) types are presented. The data used here were primarily taken from the Asiago Supernova Catalogue, but were supplemented with additional data. We accounted for both foreground and host-galaxy extinction. A bootstrap method is used to correct the samples for Malmquist bias. Separately, we generate volume-limited samples, restricted to events within 100 Mpc. We find that the superluminous events (M{sub B} < –21) make up only about 0.1% of all SNe in the bias-corrected sample. The subluminous events (M{sub B} > –15) make up about 3%. The normal Ia distribution was the brightest with a mean absolute blue magnitude of –19.25. The IIP distribution was the dimmest at –16.75.

  7. Absolute radiometry and the solar constant

    NASA Technical Reports Server (NTRS)

    Willson, R. C.

    1974-01-01

    A series of active cavity radiometers (ACRs) are described which have been developed as standard detectors for the accurate measurement of irradiance in absolute units. It is noted that the ACR is an electrical substitution calorimeter, is designed for automatic remote operation in any environment, and can make irradiance measurements in the range from low-level IR fluxes up to 30 solar constants with small absolute uncertainty. The instrument operates in a differential mode by chopping the radiant flux to be measured at a slow rate, and irradiance is determined from two electrical power measurements together with the instrumental constant. Results are reported for measurements of the solar constant with two types of ACRs. The more accurate measurement yielded a value of 136.6 plus or minus 0.7 mW/sq cm (1.958 plus or minus 0.010 cal/sq cm per min).

  8. Asteroid absolute magnitudes and slope parameters

    NASA Technical Reports Server (NTRS)

    Tedesco, Edward F.

    1991-01-01

    A new listing of absolute magnitudes (H) and slope parameters (G) has been created and published in the Minor Planet Circulars; this same listing will appear in the 1992 Ephemerides of Minor Planets. Unlike previous listings, the values of the current list were derived from fits of data at the V band. All observations were reduced in the same fashion using, where appropriate, a single basis default value of 0.15 for the slope parameter. Distances and phase angles were computed for each observation. The data for 113 asteroids was of sufficiently high quality to permit derivation of their H and G. These improved absolute magnitudes and slope parameters will be used to deduce the most reliable bias-corrected asteroid size-frequency distribution yet made.

  9. Absolute calibration of TFTR helium proportional counters

    SciTech Connect

    Strachan, J.D.; Diesso, M.; Jassby, D.; Johnson, L.; McCauley, S.; Munsat, T.; Roquemore, A.L.; Barnes, C.W. |; Loughlin, M. |

    1995-06-01

    The TFTR helium proportional counters are located in the central five (5) channels of the TFTR multichannel neutron collimator. These detectors were absolutely calibrated using a 14 MeV neutron generator positioned at the horizontal midplane of the TFTR vacuum vessel. The neutron generator position was scanned in centimeter steps to determine the collimator aperture width to 14 MeV neutrons and the absolute sensitivity of each channel. Neutron profiles were measured for TFTR plasmas with time resolution between 5 msec and 50 msec depending upon count rates. The He detectors were used to measure the burnup of 1 MeV tritons in deuterium plasmas, the transport of tritium in trace tritium experiments, and the residual tritium levels in plasmas following 50:50 DT experiments.

  10. Absolute enantioselective separation: optical activity ex machina.

    PubMed

    Bielski, Roman; Tencer, Michal

    2005-11-01

    The paper describes methodology of using three independent macroscopic factors affecting molecular orientation to accomplish separation of a racemic mixture without the presence of any other chiral compounds, i. e., absolute enantioselective separation (AES) which is an extension of a concept of applying these factors to absolute asymmetric synthesis. The three factors may be applied simultaneously or, if their effects can be retained, consecutively. The resulting three mutually orthogonal or near orthogonal directors constitute a true chiral influence and their scalar triple product is the measure of the chirality of the system. AES can be executed in a chromatography-like microfluidic process in the presence of an electric field. It may be carried out on a chemically modified flat surface, a monolithic polymer column made of a mesoporous material, each having imparted directional properties. Separation parameters were estimated for these media and possible implications for the natural homochirality are discussed. PMID:16342798

  11. An absolute measure for a key currency

    NASA Astrophysics Data System (ADS)

    Oya, Shunsuke; Aihara, Kazuyuki; Hirata, Yoshito

    It is generally considered that the US dollar and the euro are the key currencies in the world and in Europe, respectively. However, there is no absolute general measure for a key currency. Here, we investigate the 24-hour periodicity of foreign exchange markets using a recurrence plot, and define an absolute measure for a key currency based on the strength of the periodicity. Moreover, we analyze the time evolution of this measure. The results show that the credibility of the US dollar has not decreased significantly since the Lehman shock, when the Lehman Brothers bankrupted and influenced the economic markets, and has increased even relatively better than that of the euro and that of the Japanese yen.

  12. From Hubble's NGSL to Absolute Fluxes

    NASA Technical Reports Server (NTRS)

    Heap, Sara R.; Lindler, Don

    2012-01-01

    Hubble's Next Generation Spectral Library (NGSL) consists of R-l000 spectra of 374 stars of assorted temperature, gravity, and metallicity. Each spectrum covers the wavelength range, 0.18-1.00 microns. The library can be viewed and/or downloaded from the website, http://archive.stsci.edu/prepds/stisngsll. Stars in the NGSL are now being used as absolute flux standards at ground-based observatories. However, the uncertainty in the absolute flux is about 2%, which does not meet the requirements of dark-energy surveys. We are therefore developing an observing procedure that should yield fluxes with uncertainties less than 1 % and will take part in an HST proposal to observe up to 15 stars using this new procedure.

  13. Metallic Magnetic Calorimeters for Absolute Activity Measurement

    NASA Astrophysics Data System (ADS)

    Loidl, M.; Leblanc, E.; Rodrigues, M.; Bouchard, J.; Censier, B.; Branger, T.; Lacour, D.

    2008-05-01

    We present a prototype of metallic magnetic calorimeters that we are developing for absolute activity measurements of low energy emitting radionuclides. We give a detailed description of the realization of the prototype, containing an 55Fe source inside the detector absorber. We present the analysis of first data taken with this detector and compare the result of activity measurement with liquid scintillation counting. We also propose some ways for reducing the uncertainty on the activity determination with this new technique.

  14. Silicon Absolute X-Ray Detectors

    SciTech Connect

    Seely, John F.; Korde, Raj; Sprunck, Jacob; Medjoubi, Kadda; Hustache, Stephanie

    2010-06-23

    The responsivity of silicon photodiodes having no loss in the entrance window, measured using synchrotron radiation in the 1.75 to 60 keV range, was compared to the responsivity calculated using the silicon thickness measured using near-infrared light. The measured and calculated responsivities agree with an average difference of 1.3%. This enables their use as absolute x-ray detectors.

  15. Blood pressure targets and absolute cardiovascular risk.

    PubMed

    Odutayo, Ayodele; Rahimi, Kazem; Hsiao, Allan J; Emdin, Connor A

    2015-08-01

    In the Eighth Joint National Committee guideline on hypertension, the threshold for the initiation of blood pressure-lowering treatment for elderly adults (≥60 years) without chronic kidney disease or diabetes mellitus was raised from 140/90 mm Hg to 150/90 mm Hg. However, the committee was not unanimous in this decision, particularly because a large proportion of adults ≥60 years may be at high cardiovascular risk. On the basis of Eighth Joint National Committee guideline, we sought to determine the absolute 10-year risk of cardiovascular disease among these adults through analyzing the National Health and Nutrition Examination Survey (2005-2012). The primary outcome measure was the proportion of adults who were at ≥20% predicted absolute cardiovascular risk and above goals for the Seventh Joint National Committee guideline but reclassified as at target under the Eighth Joint National Committee guideline (reclassified). The Framingham General Cardiovascular Disease Risk Score was used. From 2005 to 2012, the surveys included 12 963 adults aged 30 to 74 years with blood pressure measurements, of which 914 were reclassified based on the guideline. Among individuals reclassified as not in need of additional treatment, the proportion of adults 60 to 74 years without chronic kidney disease or diabetes mellitus at ≥20% absolute risk was 44.8%. This corresponds to 0.8 million adults. The proportion at high cardiovascular risk remained sizable among adults who were not receiving blood pressure-lowering treatment. Taken together, a sizable proportion of reclassified adults 60 to 74 years without chronic kidney disease or diabetes mellitus was at ≥20% absolute cardiovascular risk. PMID:26056340

  16. Relative errors can cue absolute visuomotor mappings.

    PubMed

    van Dam, Loes C J; Ernst, Marc O

    2015-12-01

    When repeatedly switching between two visuomotor mappings, e.g. in a reaching or pointing task, adaptation tends to speed up over time. That is, when the error in the feedback corresponds to a mapping switch, fast adaptation occurs. Yet, what is learned, the relative error or the absolute mappings? When switching between mappings, errors with a size corresponding to the relative difference between the mappings will occur more often than other large errors. Thus, we could learn to correct more for errors with this familiar size (Error Learning). On the other hand, it has been shown that the human visuomotor system can store several absolute visuomotor mappings (Mapping Learning) and can use associated contextual cues to retrieve them. Thus, when contextual information is present, no error feedback is needed to switch between mappings. Using a rapid pointing task, we investigated how these two types of learning may each contribute when repeatedly switching between mappings in the absence of task-irrelevant contextual cues. After training, we examined how participants changed their behaviour when a single error probe indicated either the often-experienced error (Error Learning) or one of the previously experienced absolute mappings (Mapping Learning). Results were consistent with Mapping Learning despite the relative nature of the error information in the feedback. This shows that errors in the feedback can have a double role in visuomotor behaviour: they drive the general adaptation process by making corrections possible on subsequent movements, as well as serve as contextual cues that can signal a learned absolute mapping. PMID:26280315

  17. Absolute distance measurements by variable wavelength interferometry

    NASA Astrophysics Data System (ADS)

    Bien, F.; Camac, M.; Caulfield, H. J.; Ezekiel, S.

    1981-02-01

    This paper describes a laser interferometer which provides absolute distance measurements using tunable lasers. An active feedback loop system, in which the laser frequency is locked to the optical path length difference of the interferometer, is used to tune the laser wavelengths. If the two wavelengths are very close, electronic frequency counters can be used to measure the beat frequency between the two laser frequencies and thus to determine the optical path difference between the two legs of the interferometer.

  18. Absolute dosimetry for extreme-ultraviolet lithography

    NASA Astrophysics Data System (ADS)

    Berger, Kurt W.; Campiotti, Richard H.

    2000-06-01

    The accurate measurement of an exposure dose reaching the wafer on an extreme ultraviolet (EUV) lithographic system has been a technical challenge directly applicable to the evaluation of candidate EUV resist materials and calculating lithography system throughputs. We have developed a dose monitoring sensor system that can directly measure EUV intensities at the wafer plane of a prototype EUV lithographic system. This sensor system, located on the wafer stage adjacent to the electrostatic chuck used to grip wafers, operates by translating the sensor into the aerial image, typically illuminating an 'open' (unpatterned) area on the reticle. The absolute signal strength can be related to energy density at the wafer, and thus used to determine resist sensitivity, and the signal as a function of position can be used to determine illumination uniformity at the wafer plane. Spectral filtering to enhance the detection of 13.4 nm radiation was incorporated into the sensor. Other critical design parameters include the packaging and amplification technologies required to place this device into the space and vacuum constraints of a EUV lithography environment. We describe two approaches used to determine the absolute calibration of this sensor. The first conventional approach requires separate characterization of each element of the sensor. A second novel approach uses x-ray emission from a mildly radioactive iron source to calibrate the absolute response of the entire sensor system (detector and electronics) in a single measurement.

  19. Hybrid theory of P-wave electron-Li2+ elastic scattering and photoabsorption in two-electron systems

    NASA Astrophysics Data System (ADS)

    Bhatia, A. K.

    2013-04-01

    In previous papers [Bhatia, Phys. Rev. APLRAAN1050-294710.1103/PhysRevA.85.052708 85, 052708 (2012); Bhatia, Phys. Rev. A10.1103/PhysRevA.86.032709 86, 032709 (2012)] electron-hydrogen and electron-He+ P-wave scattering phase shifts were calculated using the hybrid theory. This method is extended to the singlet and triplet electron-Li2+ P-wave scattering in the elastic region, where the correlation functions are of Hylleraas type. The short-range and long-range correlations are included in the Schrödinger equation at the same time, by using a combination of a modified method of polarized orbitals and the optical potential formalism. Phase shifts are compared to those obtained by other methods. The present calculation requires very few correlation functions to obtain accurate results which are rigorous lower bounds to the exact phase shifts. The continuum functions obtained in this method are used to calculate photodetachment and photoionization cross sections of two-electron systems H-, He, and Li+. Cross sections of the metastable 1,3S states of He, and Li+ are also calculated. These cross sections are calculated in the elastic region and compared with previous calculations. Using these cross sections, the Maxwellian-averaged radiative-recombination rates at various electron temperatures are also calculated.

  20. Absolute bioavailability and regional absorption of ticagrelor in healthy volunteers

    PubMed Central

    Teng, Renli; Maya, Juan

    2014-01-01

    Objective Ticagrelor is a direct-acting, reversibly-binding, oral P2Y12 receptor antagonist. It demonstrates predictable, linear pharmacokinetics. Two studies were undertaken to further elucidate the absolute bioavailability of ticagrelor and its regional absorption in the gastrointestinal (GI) tract. Design and methods In two open-label, randomized, cross-over studies, 12 volunteers received a single dose of ticagrelor: oral 90 mg and 15 mg IV (Study 1); or 100 mg oral suspension vs 100 mg immediate release (IR) tablet (Study 2). After the initial cross-over period in Study 2, patients received 100 mg suspension delivered to specific sites in the GI tract using an Enterion capsule. In both studies, plasma concentrations of ticagrelor and AR-C124910XX were measured following administration of each formulation. Results The mean absolute bioavailability of ticagrelor was 36% (95% confidence interval = 30–42%). Metabolite:parent ratios were higher after oral administration, compared with IV administration (maximum plasma concentration [Cmax] = 0.356 and 0.037; area under the plasma concentration-time curves [AUC] = 0.530 and 0.173, respectively). Following oral administration of the 100 mg IR tablet, the AUC and Cmax of ticagrelor were 78% and 58%, respectively, of those following oral administration of the 100 mg suspension. Exposure to ticagrelor decreased the further down the GI tract it was released: mean Cmax for ticagrelor was 91%, 68%, and 13% that for the oral suspension when released in the proximal small bowel, distal small bowel and ascending colon, respectively; mean AUCs were 89%, 73%, and 32%, respectively. Conclusion The mean absolute bioavailability of ticagrelor was 36% and the proportion of ticagrelor absorbed decreased the further down the GI tract it was released: the mean AUC for ticagrelor was 89% (proximal small bowel), 73% (distal small bowel), and 32% (ascending colon) that of the mean AUC for the orally

  1. Photoabsorption of the ground state of Ne and of Ne-like Na+, Mg2+, Al3+, Si4+, P5+, S6+, and Cl7+ ions

    NASA Astrophysics Data System (ADS)

    Sakho, I.

    2016-03-01

    Photoabsorption of the 1s2 2s2 2p6 (1S0) ground state of Ne-like ions is presented in this paper. Resonance energies and width of the 2 s 2p6 n p1P1 series of Ne and Ne-like Na+, Mg2+, Al3+, Si4+, P5+, S6+, and Cl7+ ions are reported. Wavelengths of the 2s2 2p6 (1S0) → 2s2 2p5(2P 3 / 2 , 1 / 2) n d transitions in neon-like Na+ ion and of the 2s2 2p6(1S0) → 2 s 2p6 n p1P1 transitions in Ne and in Ne-like Na+, Mg2+, Al3+, Si4+, P5+, S6+, and Cl7+ ions are tabulated. Analysis of the resonances investigated is done in the framework of the LS, jj and JK coupling schemes. All the calculations are made using the Screening constant by unit nuclear charge (SCUNC) formalism. Very good agreement is found between the SCUNC results and various experimental and theoretical literature values and new data for the Ne-like Si4+, P5+, S6+, and Cl7+ ions are listed.

  2. Clock time is absolute and universal

    NASA Astrophysics Data System (ADS)

    Shen, Xinhang

    2015-09-01

    A critical error is found in the Special Theory of Relativity (STR): mixing up the concepts of the STR abstract time of a reference frame and the displayed time of a physical clock, which leads to use the properties of the abstract time to predict time dilation on physical clocks and all other physical processes. Actually, a clock can never directly measure the abstract time, but can only record the result of a physical process during a period of the abstract time such as the number of cycles of oscillation which is the multiplication of the abstract time and the frequency of oscillation. After Lorentz Transformation, the abstract time of a reference frame expands by a factor gamma, but the frequency of a clock decreases by the same factor gamma, and the resulting multiplication i.e. the displayed time of a moving clock remains unchanged. That is, the displayed time of any physical clock is an invariant of Lorentz Transformation. The Lorentz invariance of the displayed times of clocks can further prove within the framework of STR our earth based standard physical time is absolute, universal and independent of inertial reference frames as confirmed by both the physical fact of the universal synchronization of clocks on the GPS satellites and clocks on the earth, and the theoretical existence of the absolute and universal Galilean time in STR which has proved that time dilation and space contraction are pure illusions of STR. The existence of the absolute and universal time in STR has directly denied that the reference frame dependent abstract time of STR is the physical time, and therefore, STR is wrong and all its predictions can never happen in the physical world.

  3. Achieving Climate Change Absolute Accuracy in Orbit

    NASA Technical Reports Server (NTRS)

    Wielicki, Bruce A.; Young, D. F.; Mlynczak, M. G.; Thome, K. J; Leroy, S.; Corliss, J.; Anderson, J. G.; Ao, C. O.; Bantges, R.; Best, F.; Bowman, K.; Brindley, H.; Butler, J. J.; Collins, W.; Dykema, J. A.; Doelling, D. R.; Feldman, D. R.; Fox, N.; Huang, X.; Holz, R.; Huang, Y.; Jennings, D.; Jin, Z.; Johnson, D. G.; Jucks, K.; Kato, S.; Kratz, D. P.; Liu, X.; Lukashin, C.; Mannucci, A. J.; Phojanamongkolkij, N.; Roithmayr, C. M.; Sandford, S.; Taylor, P. C.; Xiong, X.

    2013-01-01

    The Climate Absolute Radiance and Refractivity Observatory (CLARREO) mission will provide a calibration laboratory in orbit for the purpose of accurately measuring and attributing climate change. CLARREO measurements establish new climate change benchmarks with high absolute radiometric accuracy and high statistical confidence across a wide range of essential climate variables. CLARREO's inherently high absolute accuracy will be verified and traceable on orbit to Système Internationale (SI) units. The benchmarks established by CLARREO will be critical for assessing changes in the Earth system and climate model predictive capabilities for decades into the future as society works to meet the challenge of optimizing strategies for mitigating and adapting to climate change. The CLARREO benchmarks are derived from measurements of the Earth's thermal infrared spectrum (5-50 micron), the spectrum of solar radiation reflected by the Earth and its atmosphere (320-2300 nm), and radio occultation refractivity from which accurate temperature profiles are derived. The mission has the ability to provide new spectral fingerprints of climate change, as well as to provide the first orbiting radiometer with accuracy sufficient to serve as the reference transfer standard for other space sensors, in essence serving as a "NIST [National Institute of Standards and Technology] in orbit." CLARREO will greatly improve the accuracy and relevance of a wide range of space-borne instruments for decadal climate change. Finally, CLARREO has developed new metrics and methods for determining the accuracy requirements of climate observations for a wide range of climate variables and uncertainty sources. These methods should be useful for improving our understanding of observing requirements for most climate change observations.

  4. The National Geodetic Survey absolute gravity program

    NASA Astrophysics Data System (ADS)

    Peter, George; Moose, Robert E.; Wessells, Claude W.

    1989-03-01

    The National Geodetic Survey absolute gravity program will utilize the high precision afforded by the JILAG-4 instrument to support geodetic and geophysical research, which involves studies of vertical motions, identification and modeling of other temporal variations, and establishment of reference values. The scientific rationale of these objectives is given, the procedures used to collect gravity and environmental data in the field are defined, and the steps necessary to correct and remove unwanted environmental effects are stated. In addition, site selection criteria, methods of concomitant environmental data collection and relative gravity observations, and schedule and logistics are discussed.

  5. An absolute radius scale for Saturn's rings

    NASA Technical Reports Server (NTRS)

    Nicholson, Philip D.; Cooke, Maren L.; Pelton, Emily

    1990-01-01

    Radio and stellar occultation observations of Saturn's rings made by the Voyager spacecraft are discussed. The data reveal systematic discrepancies of almost 10 km in some parts of the rings, limiting some of the investigations. A revised solution for Saturn's rotation pole has been proposed which removes the discrepancies between the stellar and radio occultation profiles. Corrections to previously published radii vary from -2 to -10 km for the radio occultation, and +5 to -6 km for the stellar occultation. An examination of spiral density waves in the outer A Ring supports that the revised absolute radii are in error by no more than 2 km.

  6. Characterization of the DARA solar absolute radiometer

    NASA Astrophysics Data System (ADS)

    Finsterle, W.; Suter, M.; Fehlmann, A.; Kopp, G.

    2011-12-01

    The Davos Absolute Radiometer (DARA) prototype is an Electrical Substitution Radiometer (ESR) which has been developed as a successor of the PMO6 type on future space missions and ground based TSI measurements. The DARA implements an improved thermal design of the cavity detector and heat sink assembly to minimize air-vacuum differences and to maximize thermal symmetry of measuring and compensating cavity. The DARA also employs an inverted viewing geometry to reduce internal stray light. We will report on the characterization and calibration experiments which were carried out at PMOD/WRC and LASP (TRF).

  7. Absolute calibration of the Auger fluorescence detectors

    SciTech Connect

    Bauleo, P.; Brack, J.; Garrard, L.; Harton, J.; Knapik, R.; Meyhandan, R.; Rovero, A.C.; Tamashiro, A.; Warner, D.

    2005-07-01

    Absolute calibration of the Pierre Auger Observatory fluorescence detectors uses a light source at the telescope aperture. The technique accounts for the combined effects of all detector components in a single measurement. The calibrated 2.5 m diameter light source fills the aperture, providing uniform illumination to each pixel. The known flux from the light source and the response of the acquisition system give the required calibration for each pixel. In the lab, light source uniformity is studied using CCD images and the intensity is measured relative to NIST-calibrated photodiodes. Overall uncertainties are presently 12%, and are dominated by systematics.

  8. Absolute angular positioning in ultrahigh vacuum

    SciTech Connect

    Schief, H.; Marsico, V.; Kern, K.

    1996-05-01

    Commercially available angular resolvers, which are routinely used in machine tools and robotics, are modified and adapted to be used under ultrahigh-vacuum (UHV) conditions. They provide straightforward and reliable measurements of angular positions for any kind of UHV sample manipulators. The corresponding absolute reproducibility is on the order of 0.005{degree}, whereas the relative resolution is better than 0.001{degree}, as demonstrated by high-resolution helium-reflectivity measurements. The mechanical setup and possible applications are discussed. {copyright} {ital 1996 American Institute of Physics.}

  9. Absolute method of measuring magnetic susceptibility

    USGS Publications Warehouse

    Thorpe, A.; Senftle, F.E.

    1959-01-01

    An absolute method of standardization and measurement of the magnetic susceptibility of small samples is presented which can be applied to most techniques based on the Faraday method. The fact that the susceptibility is a function of the area under the curve of sample displacement versus distance of the magnet from the sample, offers a simple method of measuring the susceptibility without recourse to a standard sample. Typical results on a few substances are compared with reported values, and an error of less than 2% can be achieved. ?? 1959 The American Institute of Physics.

  10. Absolute Priority for a Vehicle in VANET

    NASA Astrophysics Data System (ADS)

    Shirani, Rostam; Hendessi, Faramarz; Montazeri, Mohammad Ali; Sheikh Zefreh, Mohammad

    In today's world, traffic jams waste hundreds of hours of our life. This causes many researchers try to resolve the problem with the idea of Intelligent Transportation System. For some applications like a travelling ambulance, it is important to reduce delay even for a second. In this paper, we propose a completely infrastructure-less approach for finding shortest path and controlling traffic light to provide absolute priority for an emergency vehicle. We use the idea of vehicular ad-hoc networking to reduce the imposed travelling time. Then, we simulate our proposed protocol and compare it with a centrally controlled traffic light system.

  11. Determination of the absolute contours of optical flats

    NASA Technical Reports Server (NTRS)

    Primak, W.

    1969-01-01

    Emersons procedure is used to determine true absolute contours of optical flats. Absolute contours of standard flats are determined and a comparison is then made between standard and unknown flats. Contour differences are determined by deviation of Fizeau fringe.

  12. Standardization of the cumulative absolute velocity

    SciTech Connect

    O'Hara, T.F.; Jacobson, J.P. )

    1991-12-01

    EPRI NP-5930, A Criterion for Determining Exceedance of the Operating Basis Earthquake,'' was published in July 1988. As defined in that report, the Operating Basis Earthquake (OBE) is exceeded when both a response spectrum parameter and a second damage parameter, referred to as the Cumulative Absolute Velocity (CAV), are exceeded. In the review process of the above report, it was noted that the calculation of CAV could be confounded by time history records of long duration containing low (nondamaging) acceleration. Therefore, it is necessary to standardize the method of calculating CAV to account for record length. This standardized methodology allows consistent comparisons between future CAV calculations and the adjusted CAV threshold value based upon applying the standardized methodology to the data set presented in EPRI NP-5930. The recommended method to standardize the CAV calculation is to window its calculation on a second-by-second basis for a given time history. If the absolute acceleration exceeds 0.025g at any time during each one second interval, the earthquake records used in EPRI NP-5930 have been reanalyzed and the adjusted threshold of damage for CAV was found to be 0.16g-set.

  13. Absolute rates of hole transfer in DNA.

    PubMed

    Senthilkumar, Kittusamy; Grozema, Ferdinand C; Guerra, Célia Fonseca; Bickelhaupt, F Matthias; Lewis, Frederick D; Berlin, Yuri A; Ratner, Mark A; Siebbeles, Laurens D A

    2005-10-26

    Absolute rates of hole transfer between guanine nucleobases separated by one or two A:T base pairs in stilbenedicarboxamide-linked DNA hairpins were obtained by improved kinetic analysis of experimental data. The charge-transfer rates in four different DNA sequences were calculated using a density-functional-based tight-binding model and a semiclassical superexchange model. Site energies and charge-transfer integrals were calculated directly as the diagonal and off-diagonal matrix elements of the Kohn-Sham Hamiltonian, respectively, for all possible combinations of nucleobases. Taking into account the Coulomb interaction between the negative charge on the stilbenedicarboxamide linker and the hole on the DNA strand as well as effects of base pair twisting, the relative order of the experimental rates for hole transfer in different hairpins could be reproduced by tight-binding calculations. To reproduce quantitatively the absolute values of the measured rate constants, the effect of the reorganization energy was taken into account within the semiclassical superexchange model for charge transfer. The experimental rates could be reproduced with reorganization energies near 1 eV. The quantum chemical data obtained were used to discuss charge carrier mobility and hole-transport equilibria in DNA. PMID:16231945

  14. Transient absolute robustness in stochastic biochemical networks.

    PubMed

    Enciso, German A

    2016-08-01

    Absolute robustness allows biochemical networks to sustain a consistent steady-state output in the face of protein concentration variability from cell to cell. This property is structural and can be determined from the topology of the network alone regardless of rate parameters. An important question regarding these systems is the effect of discrete biochemical noise in the dynamical behaviour. In this paper, a variable freezing technique is developed to show that under mild hypotheses the corresponding stochastic system has a transiently robust behaviour. Specifically, after finite time the distribution of the output approximates a Poisson distribution, centred around the deterministic mean. The approximation becomes increasingly accurate, and it holds for increasingly long finite times, as the total protein concentrations grow to infinity. In particular, the stochastic system retains a transient, absolutely robust behaviour corresponding to the deterministic case. This result contrasts with the long-term dynamics of the stochastic system, which eventually must undergo an extinction event that eliminates robustness and is completely different from the deterministic dynamics. The transiently robust behaviour may be sufficient to carry out many forms of robust signal transduction and cellular decision-making in cellular organisms. PMID:27581485

  15. Absolute Electron Extraction Efficiency of Liquid Xenon

    NASA Astrophysics Data System (ADS)

    Kamdin, Katayun; Mizrachi, Eli; Morad, James; Sorensen, Peter

    2016-03-01

    Dual phase liquid/gas xenon time projection chambers (TPCs) currently set the world's most sensitive limits on weakly interacting massive particles (WIMPs), a favored dark matter candidate. These detectors rely on extracting electrons from liquid xenon into gaseous xenon, where they produce proportional scintillation. The proportional scintillation from the extracted electrons serves to internally amplify the WIMP signal; even a single extracted electron is detectable. Credible dark matter searches can proceed with electron extraction efficiency (EEE) lower than 100%. However, electrons systematically left at the liquid/gas boundary are a concern. Possible effects include spontaneous single or multi-electron proportional scintillation signals in the gas, or charging of the liquid/gas interface or detector materials. Understanding EEE is consequently a serious concern for this class of rare event search detectors. Previous EEE measurements have mostly been relative, not absolute, assuming efficiency plateaus at 100%. I will present an absolute EEE measurement with a small liquid/gas xenon TPC test bed located at Lawrence Berkeley National Laboratory.

  16. Sentinel-2/MSI absolute calibration: first results

    NASA Astrophysics Data System (ADS)

    Lonjou, V.; Lachérade, S.; Fougnie, B.; Gamet, P.; Marcq, S.; Raynaud, J.-L.; Tremas, T.

    2015-10-01

    Sentinel-2 is an optical imaging mission devoted to the operational monitoring of land and coastal areas. It is developed in partnership between the European Commission and the European Space Agency. The Sentinel-2 mission is based on a satellites constellation deployed in polar sun-synchronous orbit. It will offer a unique combination of global coverage with a wide field of view (290km), a high revisit (5 days with two satellites), a high resolution (10m, 20m and 60m) and multi-spectral imagery (13 spectral bands in visible and shortwave infra-red domains). CNES is involved in the instrument commissioning in collaboration with ESA. This paper reviews all the techniques that will be used to insure an absolute calibration of the 13 spectral bands better than 5% (target 3%), and will present the first results if available. First, the nominal calibration technique, based on an on-board sun diffuser, is detailed. Then, we show how vicarious calibration methods based on acquisitions over natural targets (oceans, deserts, and Antarctica during winter) will be used to check and improve the accuracy of the absolute calibration coefficients. Finally, the verification scheme, exploiting photometer in-situ measurements over Lacrau plain, is described. A synthesis, including spectral coherence, inter-methods agreement and temporal evolution, will conclude the paper.

  17. Absolute Spectrophotometry of 237 Open Cluster Stars

    NASA Astrophysics Data System (ADS)

    Clampitt, L.; Burstein, D.

    1994-12-01

    We present absolute spectrophotometry of 237 stars in 7 nearby open clusters: Hyades, Pleiades, Alpha Persei, Praesepe, Coma Berenices, IC 4665, and M 39. The observations were taken using the Wampler single-channel scanner (Wampler 1966) on the Crossley 0.9m telescope at Lick Observatory from July 1973 through December 1974. 21 bandpasses spanning the spectral range 3500 Angstroms to 7780 Angstroms were observed for each star, with bandwiths ranging from 32Angstroms to 64 Angstroms. Data are standardized to the Hayes--Latham (1975) system. Our measurements are compared to filter colors on the Johnson BV, Stromgren ubvy, and Geneva U V B_1 B_2 V_1 G systems, as well as to spectrophotometry of a few stars published by Gunn, Stryker & Tinsley and in the Spectrophotometric Standards Catalog (Adelman; as distributed by the NSSDC). Both internal and external comparisons to the filter systems indicate a formal statistical accuracy per bandpass of 0.01 to 0.02 mag, with apparent larger ( ~ 0.03 mag) differences in absolute calibration between this data set and existing spectrophotometry. These data will comprise part of the spectrophotometry that will be used to calibrate the Beijing-Arizona-Taipei-Connecticut Color Survey of the Sky (see separate paper by Burstein et al. at this meeting).

  18. A Conceptual Approach to Absolute Value Equations and Inequalities

    ERIC Educational Resources Information Center

    Ellis, Mark W.; Bryson, Janet L.

    2011-01-01

    The absolute value learning objective in high school mathematics requires students to solve far more complex absolute value equations and inequalities. When absolute value problems become more complex, students often do not have sufficient conceptual understanding to make any sense of what is happening mathematically. The authors suggest that the…

  19. Using, Seeing, Feeling, and Doing Absolute Value for Deeper Understanding

    ERIC Educational Resources Information Center

    Ponce, Gregorio A.

    2008-01-01

    Using sticky notes and number lines, a hands-on activity is shared that anchors initial student thinking about absolute value. The initial point of reference should help students successfully evaluate numeric problems involving absolute value. They should also be able to solve absolute value equations and inequalities that are typically found in…

  20. 20 CFR 404.1205 - Absolute coverage groups.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 20 Employees' Benefits 2 2010-04-01 2010-04-01 false Absolute coverage groups. 404.1205 Section... INSURANCE (1950- ) Coverage of Employees of State and Local Governments What Groups of Employees May Be Covered § 404.1205 Absolute coverage groups. (a) General. An absolute coverage group is a...

  1. Landsat-7 ETM+ radiometric stability and absolute calibration

    USGS Publications Warehouse

    Markham, B.L.; Barker, J.L.; Barsi, J.A.; Kaita, E.; Thome, K.J.; Helder, D.L.; Palluconi, Frank Don; Schott, J.R.; Scaramuzza, P.

    2002-01-01

    Launched in April 1999, the Landsat-7 ETM+ instrument is in its fourth year of operation. The quality of the acquired calibrated imagery continues to be high, especially with respect to its three most important radiometric performance parameters: reflective band instrument stability to better than ??1%, reflective band absolute calibration to better than ??5%, and thermal band absolute calibration to better than ??0.6 K. The ETM+ instrument has been the most stable of any of the Landsat instruments, in both the reflective and thermal channels. To date, the best on-board calibration source for the reflective bands has been the Full Aperture Solar Calibrator, which has indicated changes of at most -1.8% to -2.0% (95% C.I.) change per year in the ETM+ gain (band 4). However, this change is believed to be caused by changes in the solar diffuser panel, as opposed to a change in the instrument's gain. This belief is based partially on ground observations, which bound the changes in gain in band 4 at -0.7% to +1.5%. Also, ETM+ stability is indicated by the monitoring of desert targets. These image-based results for four Saharan and Arabian sites, for a collection of 35 scenes over the three years since launch, bound the gain change at -0.7% to +0.5% in band 4. Thermal calibration from ground observations revealed an offset error of +0.31 W/m 2 sr um soon after launch. This offset was corrected within the U. S. ground processing system at EROS Data Center on 21-Dec-00, and since then, the band 6 on-board calibration has indicated changes of at most +0.02% to +0.04% (95% C.I.) per year. The latest ground observations have detected no remaining offset error with an RMS error of ??0.6 K. The stability and absolute calibration of the Landsat-7 ETM+ sensor make it an ideal candidate to be used as a reference source for radiometric cross-calibrating to other land remote sensing satellite systems.

  2. Integrated cross sections for excitation of nuclear isomers by inelastic photon scattering at giant resonance

    NASA Astrophysics Data System (ADS)

    Sáfár, József; Lakosi, László

    2014-02-01

    In the view of the evidences arising from our experimental and theoretical studies, the long-standing picture of a two-humped excitation function for photoexcitation of isomers cannot be confirmed. Whereas the first maximum (at the photoneutron threshold) of the cross section of nuclear photon scattering can be attributed to inelastic (compound) scattering, the second large peak at about giant dipole resonance is mostly due to the elastic (direct) process. A second large peak or increase reported to appear in isomer production has been shown to be practically vanishing. On realizing such a situation, calculated estimates have been given for saturated integral cross section values for isomer activation, based on photoabsorption cross sections taken from the usual Lorentzian parametrization up to the photoneutron threshold. Results compare reasonably well to available experimental data acquired by gamma-ray spectrometry in a large set of stable nuclides having long-lived isomeric states.

  3. Total absorption cross sections of several gases of aeronomic interest at 584 A.

    NASA Technical Reports Server (NTRS)

    Starr, W. L.; Loewenstein, M.

    1972-01-01

    Total photoabsorption cross sections have been measured at 584.3 A for N2, O2, Ar, CO2, CO, NO, N2O, NH3, CH4, H2, and H2S. A monochromator was used to isolate the He I 584 line produced in a helium resonance lamp, and thin aluminum filters were used as absorption cell windows, thereby eliminating possible errors associated with the use of undispersed radiation or windowless cells. Sources of error are examined, and limits of uncertainty are given. Previous relevant cross-sectional measurements and possible error sources are reviewed. Wall adsorption as a source of error in cross-sectional measurements has not previously been considered and is discussed briefly.

  4. Precise Measurement of the Absolute Yield of Fluorescence Photons in Atmospheric Gases

    SciTech Connect

    Ave, M.; Bohacova, M.; Daumiller, K.; Di Carlo, P.; Di Giulio, C.; Luis, P.Facal San; Gonzales, D.; Hojvat, C.; Horandel, J.R.; Hrabovsky, M.; Iarlori, M.; /INFN, Aquila /Karlsruhe, Inst. Technol.

    2011-01-01

    We have performed a measurement of the absolute yield of fluorescence photons at the Fermilab Test Beam. A systematic uncertainty at 5% level was achieved by the use of Cherenkov radiation as a reference calibration light source. A cross-check was performed by an independent calibration using a laser light source. A significant improvement on the energy scale uncertainty of Ultra-High Energy Cosmic Rays is expected.

  5. Use of Absolute and Comparative Performance Feedback in Absolute and Comparative Judgments and Decisions

    ERIC Educational Resources Information Center

    Moore, Don A.; Klein, William M. P.

    2008-01-01

    Which matters more--beliefs about absolute ability or ability relative to others? This study set out to compare the effects of such beliefs on satisfaction with performance, self-evaluations, and bets on future performance. In Experiment 1, undergraduate participants were told they had answered 20% correct, 80% correct, or were not given their…

  6. Inverse bremsstrahlung cross section estimated within evolving plasmas using effective ion potentials

    NASA Astrophysics Data System (ADS)

    Wang, F.; Weckert, E.; Ziaja, B.

    2009-06-01

    We estimate the total cross sections for field-stimulated photoemissions and photoabsorptions by quasi-free electrons within a non-equilibrium plasma evolving from the strong coupling to the weak coupling regime. Such a transition may occur within laser-created plasmas, when the initially created plasma is cold but the heating of the plasma by the laser field is efficient. In particular, such a transition may occur within plasmas created by intense vacuum ultraviolet (VUV) radiation from a free-electron laser (FEL) as indicated by the results of the first experiments performed by Wabnitz at the FLASH facility at DESY. In order to estimate the inverse bremsstrahlung cross sections, we use point-like and effective atomic potentials. For ions modelled as point-like charges, the total cross sections are strongly affected by the changing plasma environment. The maximal change of the cross sections may be of the order of 75 at the change of the plasma parameters: inverse Debye length, κ, in the range κ = 0 - 3 Å-1 and the electron density, ρe, in the range ρe = 0.01 - 1 Å-3. These ranges correspond to the physical conditions within the plasmas created during the first cluster experiments performed at the FLASH facility at DESY. In contrast, for the effective atomic potentials the total cross sections for photoemission and photoabsorption change only by a factor of seven at most in the same plasma parameter range. Our results show that the inverse bremsstrahlung cross section estimated with the effective atomic potentials is not affected much by the plasma environment. This observation validates the estimations of the enhanced heating effect obtained by Walters, Santra and Greene. This is important as this effect may be responsible for the high-energy absorption within clusters irradiated with VUV radiation.

  7. Absolute calibration of ultraviolet filter photometry

    NASA Technical Reports Server (NTRS)

    Bless, R. C.; Fairchild, T.; Code, A. D.

    1972-01-01

    The essential features of the calibration procedure can be divided into three parts. First, the shape of the bandpass of each photometer was determined by measuring the transmissions of the individual optical components and also by measuring the response of the photometer as a whole. Secondly, each photometer was placed in the essentially-collimated synchrotron radiation bundle maintained at a constant intensity level, and the output signal was determined from about 100 points on the objective. Finally, two or three points on the objective were illuminated by synchrotron radiation at several different intensity levels covering the dynamic range of the photometers. The output signals were placed on an absolute basis by the electron counting technique described earlier.

  8. MAGSAT: Vector magnetometer absolute sensor alignment determination

    NASA Technical Reports Server (NTRS)

    Acuna, M. H.

    1981-01-01

    A procedure is described for accurately determining the absolute alignment of the magnetic axes of a triaxial magnetometer sensor with respect to an external, fixed, reference coordinate system. The method does not require that the magnetic field vector orientation, as generated by a triaxial calibration coil system, be known to better than a few degrees from its true position, and minimizes the number of positions through which a sensor assembly must be rotated to obtain a solution. Computer simulations show that accuracies of better than 0.4 seconds of arc can be achieved under typical test conditions associated with existing magnetic test facilities. The basic approach is similar in nature to that presented by McPherron and Snare (1978) except that only three sensor positions are required and the system of equations to be solved is considerably simplified. Applications of the method to the case of the MAGSAT Vector Magnetometer are presented and the problems encountered discussed.

  9. Absolute geostrophic currents in global tropical oceans

    NASA Astrophysics Data System (ADS)

    Yang, Lina; Yuan, Dongliang

    2016-03-01

    A set of absolute geostrophic current (AGC) data for the period January 2004 to December 2012 are calculated using the P-vector method based on monthly gridded Argo profiles in the world tropical oceans. The AGCs agree well with altimeter geostrophic currents, Ocean Surface Current Analysis-Real time currents, and moored current-meter measurements at 10-m depth, based on which the classical Sverdrup circulation theory is evaluated. Calculations have shown that errors of wind stress calculation, AGC transport, and depth ranges of vertical integration cannot explain non-Sverdrup transport, which is mainly in the subtropical western ocean basins and equatorial currents near the Equator in each ocean basin (except the North Indian Ocean, where the circulation is dominated by monsoons). The identified non-Sverdrup transport is thereby robust and attributed to the joint effect of baroclinicity and relief of the bottom (JEBAR) and mesoscale eddy nonlinearity.

  10. Absolute Measurement of Electron Cloud Density

    SciTech Connect

    Covo, M K; Molvik, A W; Cohen, R H; Friedman, A; Seidl, P A; Logan, G; Bieniosek, F; Baca, D; Vay, J; Orlando, E; Vujic, J L

    2007-06-21

    Beam interaction with background gas and walls produces ubiquitous clouds of stray electrons that frequently limit the performance of particle accelerator and storage rings. Counterintuitively we obtained the electron cloud accumulation by measuring the expelled ions that are originated from the beam-background gas interaction, rather than by measuring electrons that reach the walls. The kinetic ion energy measured with a retarding field analyzer (RFA) maps the depressed beam space-charge potential and provides the dynamic electron cloud density. Clearing electrode current measurements give the static electron cloud background that complements and corroborates with the RFA measurements, providing an absolute measurement of electron cloud density during a 5 {micro}s duration beam pulse in a drift region of the magnetic transport section of the High-Current Experiment (HCX) at LBNL.

  11. Absolute instability of a viscous hollow jet

    NASA Astrophysics Data System (ADS)

    Gañán-Calvo, Alfonso M.

    2007-02-01

    An investigation of the spatiotemporal stability of hollow jets in unbounded coflowing liquids, using a general dispersion relation previously derived, shows them to be absolutely unstable for all physical values of the Reynolds and Weber numbers. The roots of the symmetry breakdown with respect to the liquid jet case, and the validity of asymptotic models are here studied in detail. Asymptotic analyses for low and high Reynolds numbers are provided, showing that old and well-established limiting dispersion relations [J. W. S. Rayleigh, The Theory of Sound (Dover, New York, 1945); S. Chandrasekhar, Hydrodynamic and Hydromagnetic Stability (Dover, New York, 1961)] should be used with caution. In the creeping flow limit, the analysis shows that, if the hollow jet is filled with any finite density and viscosity fluid, a steady jet could be made arbitrarily small (compatible with the continuum hypothesis) if the coflowing liquid moves faster than a critical velocity.

  12. Stitching interferometry: recent results and absolute calibration

    NASA Astrophysics Data System (ADS)

    Bray, Michael

    2004-02-01

    Stitching Interferometry is a method of analysing large optical components using a standard "small" interferometer. This result is obtained by taking multiple overlapping images of the large component, and numerically "stitching" these sub-apertures together. We have already reported the industrial use our Stitching Interferometry systems (Previous SPIE symposia), but experimental results had been lacking because this technique is still new, and users needed to get accustomed to it before producing reliable measurements. We now have more results. We will report user comments and show new, unpublished results. We will discuss sources of error, and show how some of these can be reduced to arbitrarily small values. These will be discussed in some detail. We conclude with a few graphical examples of absolute measurements performed by us.

  13. Swarm's Absolute Scalar Magnetometer metrological performances

    NASA Astrophysics Data System (ADS)

    Leger, J.; Fratter, I.; Bertrand, F.; Jager, T.; Morales, S.

    2012-12-01

    The Absolute Scalar Magnetometer (ASM) has been developed for the ESA Earth Observation Swarm mission, planned for launch in November 2012. As its Overhauser magnetometers forerunners flown on Oersted and Champ satellites, it will deliver high resolution scalar measurements for the in-flight calibration of the Vector Field Magnetometer manufactured by the Danish Technical University. Latest results of the ground tests carried out to fully characterize all parameters that may affect its accuracy, both at instrument and satellite level, will be presented. In addition to its baseline function, the ASM can be operated either at a much higher sampling rate (burst mode at 250 Hz) or in a dual mode where it also delivers vector field measurements as a by-product. The calibration procedure and the relevant vector performances will be discussed.

  14. Absolute nonlocality via distributed computing without communication

    NASA Astrophysics Data System (ADS)

    Czekaj, Ł.; Pawłowski, M.; Vértesi, T.; Grudka, A.; Horodecki, M.; Horodecki, R.

    2015-09-01

    Understanding the role that quantum entanglement plays as a resource in various information processing tasks is one of the crucial goals of quantum information theory. Here we propose an alternative perspective for studying quantum entanglement: distributed computation of functions without communication between nodes. To formalize this approach, we propose identity games. Surprisingly, despite no signaling, we obtain that nonlocal quantum strategies beat classical ones in terms of winning probability for identity games originating from certain bipartite and multipartite functions. Moreover we show that, for a majority of functions, access to general nonsignaling resources boosts success probability two times in comparison to classical ones for a number of large enough outputs. Because there are no constraints on the inputs and no processing of the outputs in the identity games, they detect very strong types of correlations: absolute nonlocality.

  15. Absolute Neutron Fluence Measurements at the NIST Center for Neutron Research

    NASA Astrophysics Data System (ADS)

    Yue, A.; Dewey, M.; Gilliam, D.; Nico, J.; Anderson, E.; Snow, M.; Greene, G.; Laptev, A.

    2015-10-01

    Precise, absolute fluence measurements of cold and thermal neutron beams are of primary importance to beam-type determinations of the neutron lifetime, measurements of standard neutron cross sections, and the development of standards for neutron dosimetry. At the National Institute of Standards and Technology (NIST), a totally absorbing neutron detector based on absolute counting of the 10B(n,α1)7Li reaction 478 keV gamma ray has been used to perform fluence measurements with a precision of 0.06%. This detector has been used to improve the neutron fluence determination in the 2000 NIST beam neutron lifetime by a factor of five, significantly reducing the uncertainty in the lifetime result. Ongoing and possible future uses of the Alpha-Gamma device include 1) Calibration of the neutron fluence monitors that will be used in the upcoming NIST beam neutron lifetime measurement BL2; 2) The first direct, absolute measurement of the 6Li(n,t)4He neutron cross section at sub-thermal neutron energy; 3) Measurements of the 10B(n, γ)11B and 235U(n,f) neutron cross sections; 4) A re-calibration of the national neutron standard NBS-1. The apparatus, measurement technique, and applications will be discussed.

  16. Convective-to-absolute instability transition in a viscoelastic capillary jet subject to unrelaxed axial elastic tension.

    PubMed

    Mohamed, A Said; Herrada, M A; Gañán-Calvo, A M; Montanero, J M

    2015-08-01

    The convective-to-absolute instability transition in an Oldroyd-B capillary jet subject to unrelaxed axial stress is examined theoretically. There is a critical Weber number below which the jet is absolutely unstable under axisymmetric perturbations. We analyze the dependence of this critical parameter with respect to the Reynolds and Deborah numbers, as well as the unrelaxed axial stress. For small Deborah numbers, the unrelaxed stress destabilizes the viscoelastic jet, increasing the critical Weber number for which the convective-to-absolute instability transition takes place. If the Deborah number takes higher values, then the transitional Weber number decreases as the unrelaxed stress increases until two solution branches cross each other. The dominant branch for large axial stress leads to a threshold of this quantity above which the viscoelastic jet becomes absolutely unstable independently of the Weber number. The threshold depends on neither the Reynolds nor the Deborah number for sufficiently large values of these parameters. PMID:26382502

  17. Convective-to-absolute instability transition in a viscoelastic capillary jet subject to unrelaxed axial elastic tension

    NASA Astrophysics Data System (ADS)

    Mohamed, A. Said; Herrada, M. A.; Gañán-Calvo, A. M.; Montanero, J. M.

    2015-08-01

    The convective-to-absolute instability transition in an Oldroyd-B capillary jet subject to unrelaxed axial stress is examined theoretically. There is a critical Weber number below which the jet is absolutely unstable under axisymmetric perturbations. We analyze the dependence of this critical parameter with respect to the Reynolds and Deborah numbers, as well as the unrelaxed axial stress. For small Deborah numbers, the unrelaxed stress destabilizes the viscoelastic jet, increasing the critical Weber number for which the convective-to-absolute instability transition takes place. If the Deborah number takes higher values, then the transitional Weber number decreases as the unrelaxed stress increases until two solution branches cross each other. The dominant branch for large axial stress leads to a threshold of this quantity above which the viscoelastic jet becomes absolutely unstable independently of the Weber number. The threshold depends on neither the Reynolds nor the Deborah number for sufficiently large values of these parameters.

  18. A Method for Selecting between Fisher's Linear Classification Functions and Least Absolute Deviation in Predictive Discriminant Analysis.

    ERIC Educational Resources Information Center

    Meshbane, Alice; Morris, John D.

    A method for comparing the cross-validated classification accuracy of Fisher's linear classification functions (FLCFs) and the least absolute deviation is presented under varying data conditions for the two-group classification problem. With this method, separate-group as well as total-sample proportions of current classifications can be compared…

  19. Gyrokinetic Statistical Absolute Equilibrium and Turbulence

    SciTech Connect

    Jian-Zhou Zhu and Gregory W. Hammett

    2011-01-10

    A paradigm based on the absolute equilibrium of Galerkin-truncated inviscid systems to aid in understanding turbulence [T.-D. Lee, "On some statistical properties of hydrodynamical and magnetohydrodynamical fields," Q. Appl. Math. 10, 69 (1952)] is taken to study gyrokinetic plasma turbulence: A finite set of Fourier modes of the collisionless gyrokinetic equations are kept and the statistical equilibria are calculated; possible implications for plasma turbulence in various situations are discussed. For the case of two spatial and one velocity dimension, in the calculation with discretization also of velocity v with N grid points (where N + 1 quantities are conserved, corresponding to an energy invariant and N entropy-related invariants), the negative temperature states, corresponding to the condensation of the generalized energy into the lowest modes, are found. This indicates a generic feature of inverse energy cascade. Comparisons are made with some classical results, such as those of Charney-Hasegawa-Mima in the cold-ion limit. There is a universal shape for statistical equilibrium of gyrokinetics in three spatial and two velocity dimensions with just one conserved quantity. Possible physical relevance to turbulence, such as ITG zonal flows, and to a critical balance hypothesis are also discussed.

  20. Absolute surface energy for zincblende semiconductors

    NASA Astrophysics Data System (ADS)

    Zhang, S. B.; Wei, Su-Huai

    2003-03-01

    Recent advance in nanosciences requires the determination of surface (or facet) energy of semiconductors, which is often difficult due to the polar nature of some of the most important surfaces such as the (111)A/(111)B surfaces. Several approaches have been developed in the past [1-3] to deal with the problem but an unambiguous division of the polar surface energies is yet to come [2]. Here we show that an accurate division is indeed possible for the zincblende semiconductors and will present the results for GaAs, ZnSe, and CuInSe2 [4], respectively. A general trend emerges, relating the absolute surface energy to the ionicity of the bulk materials. [1] N. Chetty and R. M. Martin, Phys. Rev. B 45, 6074 (1992). [2] N. Moll, et al., Phys. Rev. B 54, 8844 (1996). [3] S. Mankefors, Phys. Rev. B 59, 13151 (1999). [4] S. B. Zhang and S.-H. Wei, Phys. Rev. B 65, 081402 (2002).

  1. Climate Absolute Radiance and Refractivity Observatory (CLARREO)

    NASA Technical Reports Server (NTRS)

    Leckey, John P.

    2015-01-01

    The Climate Absolute Radiance and Refractivity Observatory (CLARREO) is a mission, led and developed by NASA, that will measure a variety of climate variables with an unprecedented accuracy to quantify and attribute climate change. CLARREO consists of three separate instruments: an infrared (IR) spectrometer, a reflected solar (RS) spectrometer, and a radio occultation (RO) instrument. The mission will contain orbiting radiometers with sufficient accuracy, including on orbit verification, to calibrate other space-based instrumentation, increasing their respective accuracy by as much as an order of magnitude. The IR spectrometer is a Fourier Transform spectrometer (FTS) working in the 5 to 50 microns wavelength region with a goal of 0.1 K (k = 3) accuracy. The FTS will achieve this accuracy using phase change cells to verify thermistor accuracy and heated halos to verify blackbody emissivity, both on orbit. The RS spectrometer will measure the reflectance of the atmosphere in the 0.32 to 2.3 microns wavelength region with an accuracy of 0.3% (k = 2). The status of the instrumentation packages and potential mission options will be presented.

  2. Absolute decay width measurements in 16O

    NASA Astrophysics Data System (ADS)

    Wheldon, C.; Ashwood, N. I.; Barr, M.; Curtis, N.; Freer, M.; Kokalova, Tz; Malcolm, J. D.; Spencer, S. J.; Ziman, V. A.; Faestermann, Th; Krücken, R.; Wirth, H.-F.; Hertenberger, R.; Lutter, R.; Bergmaier, A.

    2012-09-01

    The reaction 126C(63Li, d)168O* at a 6Li bombarding energy of 42 MeV has been used to populate excited states in 16O. The deuteron ejectiles were measured using the high-resolution Munich Q3D spectrograph. A large-acceptance silicon-strip detector array was used to register the recoil and break-up products. This complete kinematic set-up has enabled absolute α-decay widths to be measured with high-resolution in the 13.9 to 15.9 MeV excitation energy regime in 16O; many for the first time. This energy region spans the 14.4 MeV four-α breakup threshold. Monte-Carlo simulations of the detector geometry and break-up processes yield detection efficiencies for the two dominant decay modes of 40% and 37% for the α+12C(g.s.) and a+12C(2+1) break-up channels respectively.

  3. Absolute calibration of forces in optical tweezers

    NASA Astrophysics Data System (ADS)

    Dutra, R. S.; Viana, N. B.; Maia Neto, P. A.; Nussenzveig, H. M.

    2014-07-01

    Optical tweezers are highly versatile laser traps for neutral microparticles, with fundamental applications in physics and in single molecule cell biology. Force measurements are performed by converting the stiffness response to displacement of trapped transparent microspheres, employed as force transducers. Usually, calibration is indirect, by comparison with fluid drag forces. This can lead to discrepancies by sizable factors. Progress achieved in a program aiming at absolute calibration, conducted over the past 15 years, is briefly reviewed. Here we overcome its last major obstacle, a theoretical overestimation of the peak stiffness, within the most employed range for applications, and we perform experimental validation. The discrepancy is traced to the effect of primary aberrations of the optical system, which are now included in the theory. All required experimental parameters are readily accessible. Astigmatism, the dominant effect, is measured by analyzing reflected images of the focused laser spot, adapting frequently employed video microscopy techniques. Combined with interface spherical aberration, it reveals a previously unknown window of instability for trapping. Comparison with experimental data leads to an overall agreement within error bars, with no fitting, for a broad range of microsphere radii, from the Rayleigh regime to the ray optics one, for different polarizations and trapping heights, including all commonly employed parameter domains. Besides signaling full first-principles theoretical understanding of optical tweezers operation, the results may lead to improved instrument design and control over experiments, as well as to an extended domain of applicability, allowing reliable force measurements, in principle, from femtonewtons to nanonewtons.

  4. Absolute spectrophotometry of northern compact planetary nebulae

    NASA Astrophysics Data System (ADS)

    Wright, S. A.; Corradi, R. L. M.; Perinotto, M.

    2005-06-01

    We present medium-dispersion spectra and narrowband images of six northern compact planetary nebulae (PNe): BoBn 1, DdDm 1, IC 5117, M 1-5, M 1-71, and NGC 6833. From broad-slit spectra, total absolute fluxes and equivalent widths were measured for all observable emission lines. High signal-to-noise emission line fluxes of Hα, Hβ, [Oiii], [Nii], and HeI may serve as emission line flux standards for northern hemisphere observers. From narrow-slit spectra, we derive systemic radial velocities. For four PNe, available emission line fluxes were measured with sufficient signal-to-noise to probe the physical properties of their electron densities, temperatures, and chemical abundances. BoBn 1 and DdDm 1, both type IV PNe, have an Hβ flux over three sigma away from previous measurements. We report the first abundance measurements of M 1-71. NGC 6833 measured radial velocity and galactic coordinates suggest that it is associated with the outer arm or possibly the galactic halo, and its low abundance ([O/H]=1.3× 10-4) may be indicative of low metallicity within that region.

  5. Absolute nuclear material assay using count distribution (LAMBDA) space

    DOEpatents

    Prasad, Mano K.; Snyderman, Neal J.; Rowland, Mark S.

    2015-12-01

    A method of absolute nuclear material assay of an unknown source comprising counting neutrons from the unknown source and providing an absolute nuclear material assay utilizing a model to optimally compare to the measured count distributions. In one embodiment, the step of providing an absolute nuclear material assay comprises utilizing a random sampling of analytically computed fission chain distributions to generate a continuous time-evolving sequence of event-counts by spreading the fission chain distribution in time.

  6. Absolute nuclear material assay using count distribution (LAMBDA) space

    DOEpatents

    Prasad, Manoj K.; Snyderman, Neal J.; Rowland, Mark S.

    2012-06-05

    A method of absolute nuclear material assay of an unknown source comprising counting neutrons from the unknown source and providing an absolute nuclear material assay utilizing a model to optimally compare to the measured count distributions. In one embodiment, the step of providing an absolute nuclear material assay comprises utilizing a random sampling of analytically computed fission chain distributions to generate a continuous time-evolving sequence of event-counts by spreading the fission chain distribution in time.

  7. The absolute disparity anomaly and the mechanism of relative disparities.

    PubMed

    Chopin, Adrien; Levi, Dennis; Knill, David; Bavelier, Daphne

    2016-06-01

    There has been a long-standing debate about the mechanisms underlying the perception of stereoscopic depth and the computation of the relative disparities that it relies on. Relative disparities between visual objects could be computed in two ways: (a) using the difference in the object's absolute disparities (Hypothesis 1) or (b) using relative disparities based on the differences in the monocular separations between objects (Hypothesis 2). To differentiate between these hypotheses, we measured stereoscopic discrimination thresholds for lines with different absolute and relative disparities. Participants were asked to judge the depth of two lines presented at the same distance from the fixation plane (absolute disparity) or the depth between two lines presented at different distances (relative disparity). We used a single stimulus method involving a unique memory component for both conditions, and no extraneous references were available. We also measured vergence noise using Nonius lines. Stereo thresholds were substantially worse for absolute disparities than for relative disparities, and the difference could not be explained by vergence noise. We attribute this difference to an absence of conscious readout of absolute disparities, termed the absolute disparity anomaly. We further show that the pattern of correlations between vergence noise and absolute and relative disparity acuities can be explained jointly by the existence of the absolute disparity anomaly and by the assumption that relative disparity information is computed from absolute disparities (Hypothesis 1). PMID:27248566

  8. The absolute disparity anomaly and the mechanism of relative disparities

    PubMed Central

    Chopin, Adrien; Levi, Dennis; Knill, David; Bavelier, Daphne

    2016-01-01

    There has been a long-standing debate about the mechanisms underlying the perception of stereoscopic depth and the computation of the relative disparities that it relies on. Relative disparities between visual objects could be computed in two ways: (a) using the difference in the object's absolute disparities (Hypothesis 1) or (b) using relative disparities based on the differences in the monocular separations between objects (Hypothesis 2). To differentiate between these hypotheses, we measured stereoscopic discrimination thresholds for lines with different absolute and relative disparities. Participants were asked to judge the depth of two lines presented at the same distance from the fixation plane (absolute disparity) or the depth between two lines presented at different distances (relative disparity). We used a single stimulus method involving a unique memory component for both conditions, and no extraneous references were available. We also measured vergence noise using Nonius lines. Stereo thresholds were substantially worse for absolute disparities than for relative disparities, and the difference could not be explained by vergence noise. We attribute this difference to an absence of conscious readout of absolute disparities, termed the absolute disparity anomaly. We further show that the pattern of correlations between vergence noise and absolute and relative disparity acuities can be explained jointly by the existence of the absolute disparity anomaly and by the assumption that relative disparity information is computed from absolute disparities (Hypothesis 1). PMID:27248566

  9. Differential cross sections for ionization of water vapor by high-velocity bare ions and electrons

    SciTech Connect

    Miller, J.H.; Wilson, W.E.; Manson, S.T.; Rudd, M.E.

    1987-01-01

    A semiempirical model of single differential cross sections (SDCS) for ionization of water vapor by fast electrons and bare ions is presented. At low secondary-electron energy, the model is based on an asymptotic expansion of the first Born approximation with coefficients, that are independent of projectile properties, evaluated from experimental photoabsorption and proton-impact ionization data. As the secondary-electron energy increases, the model converges to a binary-encounter approximation. Comparisons with measured differential, total, and dissociative cross sections for ionization of water by fast electrons are used to test the model. For primary electrons with energy greater than about 500 eV, agreement with these data is generally within experimental uncertainty; however, some discrepancies of uncertain origin exist.

  10. Orion Absolute Navigation System Progress and Challenge

    NASA Technical Reports Server (NTRS)

    Holt, Greg N.; D'Souza, Christopher

    2012-01-01

    The absolute navigation design of NASA's Orion vehicle is described. It has undergone several iterations and modifications since its inception, and continues as a work-in-progress. This paper seeks to benchmark the current state of the design and some of the rationale and analysis behind it. There are specific challenges to address when preparing a timely and effective design for the Exploration Flight Test (EFT-1), while still looking ahead and providing software extensibility for future exploration missions. The primary onboard measurements in a Near-Earth or Mid-Earth environment consist of GPS pseudo-range and delta-range, but for future explorations missions the use of star-tracker and optical navigation sources need to be considered. Discussions are presented for state size and composition, processing techniques, and consider states. A presentation is given for the processing technique using the computationally stable and robust UDU formulation with an Agee-Turner Rank-One update. This allows for computational savings when dealing with many parameters which are modeled as slowly varying Gauss-Markov processes. Preliminary analysis shows up to a 50% reduction in computation versus a more traditional formulation. Several state elements are discussed and evaluated, including position, velocity, attitude, clock bias/drift, and GPS measurement biases in addition to bias, scale factor, misalignment, and non-orthogonalities of the accelerometers and gyroscopes. Another consideration is the initialization of the EKF in various scenarios. Scenarios such as single-event upset, ground command, and cold start are discussed as are strategies for whole and partial state updates as well as covariance considerations. Strategies are given for dealing with latent measurements and high-rate propagation using multi-rate architecture. The details of the rate groups and the data ow between the elements is discussed and evaluated.

  11. Evaluation of the Absolute Regional Temperature Potential

    NASA Technical Reports Server (NTRS)

    Shindell, D. T.

    2012-01-01

    The Absolute Regional Temperature Potential (ARTP) is one of the few climate metrics that provides estimates of impacts at a sub-global scale. The ARTP presented here gives the time-dependent temperature response in four latitude bands (90-28degS, 28degS-28degN, 28-60degN and 60-90degN) as a function of emissions based on the forcing in those bands caused by the emissions. It is based on a large set of simulations performed with a single atmosphere-ocean climate model to derive regional forcing/response relationships. Here I evaluate the robustness of those relationships using the forcing/response portion of the ARTP to estimate regional temperature responses to the historic aerosol forcing in three independent climate models. These ARTP results are in good accord with the actual responses in those models. Nearly all ARTP estimates fall within +/-20%of the actual responses, though there are some exceptions for 90-28degS and the Arctic, and in the latter the ARTP may vary with forcing agent. However, for the tropics and the Northern Hemisphere mid-latitudes in particular, the +/-20% range appears to be roughly consistent with the 95% confidence interval. Land areas within these two bands respond 39-45% and 9-39% more than the latitude band as a whole. The ARTP, presented here in a slightly revised form, thus appears to provide a relatively robust estimate for the responses of large-scale latitude bands and land areas within those bands to inhomogeneous radiative forcing and thus potentially to emissions as well. Hence this metric could allow rapid evaluation of the effects of emissions policies at a finer scale than global metrics without requiring use of a full climate model.

  12. Absolute optical surface measurement with deflectometry

    NASA Astrophysics Data System (ADS)

    Li, Wansong; Sandner, Marc; Gesierich, Achim; Burke, Jan

    Deflectometry utilises the deformation and displacement of a sample pattern after reflection from a test surface to infer the surface slopes. Differentiation of the measurement data leads to a curvature map, which is very useful for surface quality checks with sensitivity down to the nanometre range. Integration of the data allows reconstruction of the absolute surface shape, but the procedure is very error-prone because systematic errors may add up to large shape deviations. In addition, there are infinitely many combinations for slope and object distance that satisfy a given observation. One solution for this ambiguity is to include information on the object's distance. It must be known very accurately. Two laser pointers can be used for positioning the object, and we also show how a confocal chromatic distance sensor can be used to define a reference point on a smooth surface from which the integration can be started. The used integration algorithm works without symmetry constraints and is therefore suitable for free-form surfaces as well. Unlike null testing, deflectometry also determines radius of curvature (ROC) or focal lengths as a direct result of the 3D surface reconstruction. This is shown by the example of a 200 mm diameter telescope mirror, whose ROC measurements by coordinate measurement machine and deflectometry coincide to within 0.27 mm (or a sag error of 1.3μm). By the example of a diamond-turned off-axis parabolic mirror, we demonstrate that the figure measurement uncertainty comes close to a well-calibrated Fizeau interferometer.

  13. Absolute determination of local tropospheric OH concentrations

    NASA Technical Reports Server (NTRS)

    Armerding, Wolfgang; Comes, Franz-Josef

    1994-01-01

    Long path absorption (LPA) according to Lambert Beer's law is a method to determine absolute concentrations of trace gases such as tropospheric OH. We have developed a LPA instrument which is based on a rapid tuning of the light source which is a frequency doubled dye laser. The laser is tuned across two or three OH absorption features around 308 nm with a scanning speed of 0.07 cm(exp -1)/microsecond and a repetition rate of 1.3 kHz. This high scanning speed greatly reduces the fluctuation of the light intensity caused by the atmosphere. To obtain the required high sensitivity the laser output power is additionally made constant and stabilized by an electro-optical modulator. The present sensitivity is of the order of a few times 10(exp 5) OH per cm(exp 3) for an acquisition time of a minute and an absorption path length of only 1200 meters so that a folding of the optical path in a multireflection cell was possible leading to a lateral dimension of the cell of a few meters. This allows local measurements to be made. Tropospheric measurements have been carried out in 1991 resulting in the determination of OH diurnal variation at specific days in late summer. Comparison with model calculations have been made. Interferences are mainly due to SO2 absorption. The problem of OH self generation in the multireflection cell is of minor extent. This could be shown by using different experimental methods. The minimum-maximum signal to noise ratio is about 8 x 10(exp -4) for a single scan. Due to the small size of the absorption cell the realization of an open air laboratory is possible in which by use of an additional UV light source or by additional fluxes of trace gases the chemistry can be changed under controlled conditions allowing kinetic studies of tropospheric photochemistry to be made in open air.

  14. Absolute Radiometric Calibration of KOMPSAT-3A

    NASA Astrophysics Data System (ADS)

    Ahn, H. Y.; Shin, D. Y.; Kim, J. S.; Seo, D. C.; Choi, C. U.

    2016-06-01

    This paper presents a vicarious radiometric calibration of the Korea Multi-Purpose Satellite-3A (KOMPSAT-3A) performed by the Korea Aerospace Research Institute (KARI) and the Pukyong National University Remote Sensing Group (PKNU RSG) in 2015.The primary stages of this study are summarized as follows: (1) A field campaign to determine radiometric calibrated target fields was undertaken in Mongolia and South Korea. Surface reflectance data obtained in the campaign were input to a radiative transfer code that predicted at-sensor radiance. Through this process, equations and parameters were derived for the KOMPSAT-3A sensor to enable the conversion of calibrated DN to physical units, such as at-sensor radiance or TOA reflectance. (2) To validate the absolute calibration coefficients for the KOMPSAT-3A sensor, we performed a radiometric validation with a comparison of KOMPSAT-3A and Landsat-8 TOA reflectance using one of the six PICS (Libya 4). Correlations between top-of-atmosphere (TOA) radiances and the spectral band responses of the KOMPSAT-3A sensors at the Zuunmod, Mongolia and Goheung, South Korea sites were significant for multispectral bands. The average difference in TOA reflectance between KOMPSAT-3A and Landsat-8 image over the Libya 4, Libya site in the red-green-blue (RGB) region was under 3%, whereas in the NIR band, the TOA reflectance of KOMPSAT-3A was lower than the that of Landsat-8 due to the difference in the band passes of two sensors. The KOMPSAT-3Aensor includes a band pass near 940 nm that can be strongly absorbed by water vapor and therefore displayed low reflectance. Toovercome this, we need to undertake a detailed analysis using rescale methods, such as the spectral bandwidth adjustment factor.

  15. Absolute Ligand Discrimination by Dimeric Signaling Receptors.

    PubMed

    Fathi, Sepehr; Nayak, Chitra R; Feld, Jordan J; Zilman, Anton G

    2016-09-01

    Many signaling pathways act through shared components, where different ligand molecules bind the same receptors or activate overlapping sets of response regulators downstream. Nevertheless, different ligands acting through cross-wired pathways often lead to different outcomes in terms of the target cell behavior and function. Although a number of mechanisms have been proposed, it still largely remains unclear how cells can reliably discriminate different molecular ligands under such circumstances. Here we show that signaling via ligand-induced receptor dimerization-a very common motif in cellular signaling-naturally incorporates a mechanism for the discrimination of ligands acting through the same receptor. PMID:27602720

  16. Mid-infrared absolute spectral responsivity scale based on an absolute cryogenic radiometer and an optical parametric oscillator laser

    NASA Astrophysics Data System (ADS)

    Zhao, Kun; Shi, Xueshun; Chen, Haidong; Liu, Yulong; Liu, Changming; Chen, Kunfeng; Li, Ligong; Gan, Haiyong; Ma, Chong

    2016-06-01

    We are reporting on a laser-based absolute spectral responsivity scale in the mid-infrared spectral range. By using a mid-infrared tunable optical parametric oscillator as the laser source, the absolute responsivity scale has been established by calibrating thin-film thermopile detectors against an absolute cryogenic radiometer. The thin-film thermopile detectors can be then used as transfer standard detectors. The extended uncertainty of the absolute spectral responsivity measurement has been analyzed to be 0.58%–0.68% (k  =  2).

  17. Radial velocity studies and absolute parameters of contact binaries. I - AB Andromedae

    NASA Technical Reports Server (NTRS)

    Hrivnak, Bruce J.

    1988-01-01

    New radial velocity curves have been obtained for the contact binary AB And, using the cross-correlation technique. A mass ratio of 0.479 is determined, which is revised to 0.491 when the velocities are corrected for proximity effects using a light curve model. These values differ by less than ten percent from the photometric mass ratio. An analysis of the symmetric B and V light curves reported by Rigterink in 1973 using the spectroscopic mass ratio yields a consistent set of light and velocity curve elements. These also produce a reasonably good fit to the infrared J and K light curves reported by Jameson and Akinci in 1979. Absolute elements are determined, and these indicate that both components have a main-sequence internal structure. These absolute parameters, together with the Galactic kinematics, suggest an age for the system similar to or greater than that of the Sun.

  18. Measuring the absolute DT neutron yield using the Magnetic Recoil Spectrometer at OMEGA and the NIF

    SciTech Connect

    Mackinnon, A; Casey, D; Frenje, J A; Johnson, M G; Seguin, F H; Li, C K; Petrasso, R D; Glebov, V Y; Katz, J; Knauer, J; Meyerhofer, D; Sangster, T; Bionta, R; Bleuel, D; Hachett, S P; Hartouni, E; Lepape, S; Mckernan, M; Moran, M; Yeamans, C

    2012-05-03

    A Magnetic Recoil Spectrometer (MRS) has been installed and extensively used on OMEGA and the National Ignition Facility (NIF) for measurements of the absolute neutron spectrum from inertial confinement fusion (ICF) implosions. From the neutron spectrum measured with the MRS, many critical implosion parameters are determined including the primary DT neutron yield, the ion temperature, and the down-scattered neutron yield. As the MRS detection efficiency is determined from first principles, the absolute DT neutron yield is obtained without cross-calibration to other techniques. The MRS primary DT neutron measurements at OMEGA and the NIF are shown to be in excellent agreement with previously established yield diagnostics on OMEGA, and with the newly commissioned nuclear activation diagnostics on the NIF.

  19. Supplementary and Enrichment Series: Absolute Value. Teachers' Commentary. SP-25.

    ERIC Educational Resources Information Center

    Bridgess, M. Philbrick, Ed.

    This is one in a series of manuals for teachers using SMSG high school supplementary materials. The pamphlet includes commentaries on the sections of the student's booklet, answers to the exercises, and sample test questions. Topics covered include addition and multiplication in terms of absolute value, graphs of absolute value in the Cartesian…

  20. Supplementary and Enrichment Series: Absolute Value. SP-24.

    ERIC Educational Resources Information Center

    Bridgess, M. Philbrick, Ed.

    This is one in a series of SMSG supplementary and enrichment pamphlets for high school students. This series is designed to make material for the study of topics of special interest to students readily accessible in classroom quantity. Topics covered include absolute value, addition and multiplication in terms of absolute value, graphs of absolute…

  1. Novalis' Poetic Uncertainty: A "Bildung" with the Absolute

    ERIC Educational Resources Information Center

    Mika, Carl

    2016-01-01

    Novalis, the Early German Romantic poet and philosopher, had at the core of his work a mysterious depiction of the "absolute." The absolute is Novalis' name for a substance that defies precise knowledge yet calls for a tentative and sensitive speculation. How one asserts a truth, represents an object, and sets about encountering things…

  2. Absolute Humidity and the Seasonality of Influenza (Invited)

    NASA Astrophysics Data System (ADS)

    Shaman, J. L.; Pitzer, V.; Viboud, C.; Grenfell, B.; Goldstein, E.; Lipsitch, M.

    2010-12-01

    Much of the observed wintertime increase of mortality in temperate regions is attributed to seasonal influenza. A recent re-analysis of laboratory experiments indicates that absolute humidity strongly modulates the airborne survival and transmission of the influenza virus. Here we show that the onset of increased wintertime influenza-related mortality in the United States is associated with anomalously low absolute humidity levels during the prior weeks. We then use an epidemiological model, in which observed absolute humidity conditions temper influenza transmission rates, to successfully simulate the seasonal cycle of observed influenza-related mortality. The model results indicate that direct modulation of influenza transmissibility by absolute humidity alone is sufficient to produce this observed seasonality. These findings provide epidemiological support for the hypothesis that absolute humidity drives seasonal variations of influenza transmission in temperate regions. In addition, we show that variations of the basic and effective reproductive numbers for influenza, caused by seasonal changes in absolute humidity, are consistent with the general timing of pandemic influenza outbreaks observed for 2009 A/H1N1 in temperate regions. Indeed, absolute humidity conditions correctly identify the region of the United States vulnerable to a third, wintertime wave of pandemic influenza. These findings suggest that the timing of pandemic influenza outbreaks is controlled by a combination of absolute humidity conditions, levels of susceptibility and changes in population mixing and contact rates.

  3. Absolute radiometric calibration of advanced remote sensing systems

    NASA Technical Reports Server (NTRS)

    Slater, P. N.

    1982-01-01

    The distinction between the uses of relative and absolute spectroradiometric calibration of remote sensing systems is discussed. The advantages of detector-based absolute calibration are described, and the categories of relative and absolute system calibrations are listed. The limitations and problems associated with three common methods used for the absolute calibration of remote sensing systems are addressed. Two methods are proposed for the in-flight absolute calibration of advanced multispectral linear array systems. One makes use of a sun-illuminated panel in front of the sensor, the radiance of which is monitored by a spectrally flat pyroelectric radiometer. The other uses a large, uniform, high-radiance reference ground surface. The ground and atmospheric measurements required as input to a radiative transfer program to predict the radiance level at the entrance pupil of the orbital sensor are discussed, and the ground instrumentation is described.

  4. Learning in the temporal bisection task: Relative or absolute?

    PubMed

    de Carvalho, Marilia Pinheiro; Machado, Armando; Tonneau, François

    2016-01-01

    We examined whether temporal learning in a bisection task is absolute or relational. Eight pigeons learned to choose a red key after a t-seconds sample and a green key after a 3t-seconds sample. To determine whether they had learned a relative mapping (short→Red, long→Green) or an absolute mapping (t-seconds→Red, 3t-seconds→Green), the pigeons then learned a series of new discriminations in which either the relative or the absolute mapping was maintained. Results showed that the generalization gradient obtained at the end of a discrimination predicted the pattern of choices made during the first session of a new discrimination. Moreover, most acquisition curves and generalization gradients were consistent with the predictions of the learning-to-time model, a Spencean model that instantiates absolute learning with temporal generalization. In the bisection task, the basis of temporal discrimination seems to be absolute, not relational. PMID:26752233

  5. Mini-implants and miniplates generate sub-absolute and absolute anchorage

    PubMed Central

    Consolaro, Alberto

    2014-01-01

    The functional demand imposed on bone promotes changes in the spatial properties of osteocytes as well as in their extensions uniformly distributed throughout the mineralized surface. Once spatial deformation is established, osteocytes create the need for structural adaptations that result in bone formation and resorption that happen to meet the functional demands. The endosteum and the periosteum are the effectors responsible for stimulating adaptive osteocytes in the inner and outer surfaces.Changes in shape, volume and position of the jaws as a result of skeletal correction of the maxilla and mandible require anchorage to allow bone remodeling to redefine morphology, esthetics and function as a result of spatial deformation conducted by orthodontic appliances. Examining the degree of changes in shape, volume and structural relationship of areas where mini-implants and miniplates are placed allows us to classify mini-implants as devices of subabsolute anchorage and miniplates as devices of absolute anchorage. PMID:25162561

  6. Absolute brightness temperature measurements at 2.1-mm wavelength

    NASA Technical Reports Server (NTRS)

    Ulich, B. L.

    1974-01-01

    Absolute measurements of the brightness temperatures of the Sun, new Moon, Venus, Mars, Jupiter, Saturn, and Uranus, and of the flux density of DR21 at 2.1-mm wavelength are reported. Relative measurements at 3.5-mm wavelength are also preented which resolve the absolute calibration discrepancy between The University of Texas 16-ft radio telescope and the Aerospace Corporation 15-ft antenna. The use of the bright planets and DR21 as absolute calibration sources at millimeter wavelengths is discussed in the light of recent observations.

  7. Absolute Antenna Calibration at the US National Geodetic Survey

    NASA Astrophysics Data System (ADS)

    Mader, G. L.; Bilich, A. L.

    2012-12-01

    Geodetic GNSS applications routinely demand millimeter precision and extremely high levels of accuracy. To achieve these accuracies, measurement and instrument biases at the centimeter to millimeter level must be understood. One of these biases is the antenna phase center, the apparent point of signal reception for a GNSS antenna. It has been well established that phase center patterns differ between antenna models and manufacturers; additional research suggests that the addition of a radome or the choice of antenna mount can significantly alter those a priori phase center patterns. For the more demanding GNSS positioning applications and especially in cases of mixed-antenna networks, it is all the more important to know antenna phase center variations as a function of both elevation and azimuth in the antenna reference frame and incorporate these models into analysis software. Determination of antenna phase center behavior is known as "antenna calibration". Since 1994, NGS has computed relative antenna calibrations for more than 350 antennas. In recent years, the geodetic community has moved to absolute calibrations - the IGS adopted absolute antenna phase center calibrations in 2006 for use in their orbit and clock products, and NGS's CORS group began using absolute antenna calibration upon the release of the new CORS coordinates in IGS08 epoch 2005.00 and NAD 83(2011,MA11,PA11) epoch 2010.00. Although NGS relative calibrations can be and have been converted to absolute, it is considered best practice to independently measure phase center characteristics in an absolute sense. Consequently, NGS has developed and operates an absolute calibration system. These absolute antenna calibrations accommodate the demand for greater accuracy and for 2-dimensional (elevation and azimuth) parameterization. NGS will continue to provide calibration values via the NGS web site www.ngs.noaa.gov/ANTCAL, and will publish calibrations in the ANTEX format as well as the legacy ANTINFO

  8. Direct comparisons between absolute and relative geomagnetic paleointensities: Absolute calibration of a relative paleointensity stack

    NASA Astrophysics Data System (ADS)

    Mochizuki, N.; Yamamoto, Y.; Hatakeyama, T.; Shibuya, H.

    2013-12-01

    Absolute geomagnetic paleointensities (APIs) have been estimated from igneous rocks, while relative paleomagnetic intensities (RPIs) have been reported from sediment cores. These two datasets have been treated separately, as correlations between APIs and RPIs are difficult on account of age uncertainties. High-resolution RPI stacks have been constructed from globally distributed sediment cores with high sedimentation rates. Previous studies often assumed that the RPI stacks have a linear relationship with geomagnetic axial dipole moments, and calibrated the RPI values to API values. However, the assumption of a linear relationship between APIs and RPIs has not been evaluated. Also, a quantitative calibration method for the RPI is lacking. We present a procedure for directly comparing API and RPI stacks, thus allowing reliable calibrations of RPIs. Direct comparisons between APIs and RPIs were conducted with virtually no associated age errors using both tephrochronologic correlations and RPI minima. Using the stratigraphic positions of tephra layers in oxygen isotope stratigraphic records, we directly compared the RPIs and APIs reported from welded tuffs contemporaneously extruded with the tephra layers. In addition, RPI minima during geomagnetic reversals and excursions were compared with APIs corresponding to the reversals and excursions. The comparison of APIs and RPIs at these exact points allowed a reliable calibration of the RPI values. We applied this direct comparison procedure to the global RPI stack PISO-1500. For six independent calibration points, virtual axial dipole moments (VADMs) from the corresponding APIs and RPIs of the PISO-1500 stack showed a near-linear relationship. On the basis of the linear relationship, RPIs of the stack were successfully calibrated to the VADMs. The direct comparison procedure provides an absolute calibration method that will contribute to the recovery of temporal variations and distributions of geomagnetic axial dipole

  9. OCT angiography by absolute intensity difference applied to normal and diseased human retinas

    PubMed Central

    Ruminski, Daniel; Sikorski, Bartosz L.; Bukowska, Danuta; Szkulmowski, Maciej; Krawiec, Krzysztof; Malukiewicz, Grazyna; Bieganowski, Lech; Wojtkowski, Maciej

    2015-01-01

    We compare four optical coherence tomography techniques for noninvasive visualization of microcapillary network in the human retina and murine cortex. We perform phantom studies to investigate contrast-to-noise ratio for angiographic images obtained with each of the algorithm. We show that the computationally simplest absolute intensity difference angiographic OCT algorithm that bases only on two cross-sectional intensity images may be successfully used in clinical study of healthy eyes and eyes with diabetic maculopathy and branch retinal vein occlusion. PMID:26309740

  10. Absolute velocity measurement using three-beam spectral-domain Doppler optical coherence tomography

    NASA Astrophysics Data System (ADS)

    Sharma, P.; Verma, Y.; Kumar, S.; Gupta, P. K.

    2015-09-01

    We report the development of a three-beam spectral-domain Doppler optical coherence tomography setup that allows single interferometer-based measurement of absolute flow velocity. The setup makes use of galvo-based phase shifting to remove complex conjugate mirror artifact and a beam displacer in the sample arm to avoid cross talk image. The results show that the developed approach allows efficient utilization of the imaging range of the spectral-domain optical coherence tomography setup for three-beam-based velocity measurement.

  11. Glassy Carbon as an Absolute Intensity Calibration Standard for Small-Angle Scattering

    NASA Astrophysics Data System (ADS)

    Zhang, Fan; Ilavsky, Jan; Long, Gabrielle G.; Quintana, John P. G.; Allen, Andrew J.; Jemian, Pete R.

    2010-05-01

    Absolute calibration of small-angle scattering (SAS) intensity data (measured in terms of the differential scattering cross section per unit sample volume per unit solid angle) is essential for many important aspects of quantitative SAS analysis, such as obtaining the number density, volume fraction, and specific surface area of the scatterers. It also enables scattering data from different instruments (light, X-ray, or neutron scattering) to be combined, and it can even be useful to detect the existence of artifacts in the experimental data. Different primary or secondary calibration methods are available. In the latter case, absolute intensity calibration requires a stable artifact with the necessary scattering profile. Glassy carbon has sometimes been selected as this intensity calibration standard. Here we review the spatial homogeneity and temporal stability of one type of commercially available glassy carbon that is being used as an intensity calibration standard at a number of SAS facilities. We demonstrate that glassy carbon is sufficiently homogeneous and stable during routine use to be relied upon as a suitable standard for absolute intensity calibration of SAS data.

  12. Glassy carbon as an absolute intensity calibration standard for small-angle scattering.

    SciTech Connect

    Zhang, F.; Ilavsky, J.; Long, G.; Allen, A.; Quintana, J.; Jemian, P.; NIST

    2010-05-01

    Absolute calibration of small-angle scattering (SAS) intensity data (measured in terms of the differential scattering cross section per unit sample volume per unit solid angle) is essential for many important aspects of quantitative SAS analysis, such as obtaining the number density, volume fraction, and specific surface area of the scatterers. It also enables scattering data from different instruments (light, X-ray, or neutron scattering) to be combined, and it can even be useful to detect the existence of artifacts in the experimental data. Different primary or secondary calibration methods are available. In the latter case, absolute intensity calibration requires a stable artifact with the necessary scattering profile. Glassy carbon has sometimes been selected as this intensity calibration standard. Here we review the spatial homogeneity and temporal stability of one type of commercially available glassy carbon that is being used as an intensity calibration standard at a number of SAS facilities. We demonstrate that glassy carbon is sufficiently homogeneous and stable during routine use to be relied upon as a suitable standard for absolute intensity calibration of SAS data.

  13. Absolute Value Boundedness, Operator Decomposition, and Stochastic Media and Equations

    NASA Technical Reports Server (NTRS)

    Adomian, G.; Miao, C. C.

    1973-01-01

    The research accomplished during this period is reported. Published abstracts and technical reports are listed. Articles presented include: boundedness of absolute values of generalized Fourier coefficients, propagation in stochastic media, and stationary conditions for stochastic differential equations.

  14. The conditions of absolute summability of multiple trigonometric series

    NASA Astrophysics Data System (ADS)

    Bitimkhan, Samat; Akishev, Gabdolla

    2015-09-01

    In this work necessary and sufficient conditions of absolute summability of multiple trigonometric Fourier series of functions from anisotropic spaces of Lebesque are found in terms of its best approximation, the module of smoothness and the mixed smoothness module.

  15. Absolute and Convective Instability of a Liquid Jet in Microgravity

    NASA Technical Reports Server (NTRS)

    Lin, Sung P.; Vihinen, I.; Honohan, A.; Hudman, Michael D.

    1996-01-01

    The transition from convective to absolute instability is observed in the 2.2 second drop tower of the NASA Lewis Research Center. In convective instability the disturbance grows spatially as it is convected downstream. In absolute instability the disturbance propagates both downstream and upstream, and manifests itself as an expanding sphere. The transition Reynolds numbers are determined for two different Weber numbers by use of Glycerin and a Silicone oil. Preliminary comparisons with theory are made.

  16. Absolute biphoton meter of the quantum efficiency of photomultipliers

    NASA Astrophysics Data System (ADS)

    Ginzburg, V. M.; Keratishvili, N. G.; Korzhenevich, E. L.; Lunev, G. V.; Sapritskii, V. I.

    1992-07-01

    An biphoton absolute meter of photomultiplier quantum efficiency is presented which is based on spontaneous parametric down-conversion. Calculation and experiment results were obtained which made it possible to choose the parameters of the setup that guarantee a linear dependence of wavelength on the Z coordinate (along the axicon axis). Results of a series of absolute measurements of the quantum efficiency of a specific photomultiplier (FEU-136) are presented.

  17. Absolute/convective instability of planar viscoelastic jets

    NASA Astrophysics Data System (ADS)

    Ray, Prasun K.; Zaki, Tamer A.

    2015-01-01

    Spatiotemporal linear stability analysis is used to investigate the onset of local absolute instability in planar viscoelastic jets. The influence of viscoelasticity in dilute polymer solutions is modeled with the FENE-P constitutive equation which requires the specification of a non-dimensional polymer relaxation time (the Weissenberg number, We), the maximum polymer extensibility, L, and the ratio of solvent and solution viscosities, β. A two-parameter family of velocity profiles is used as the base state with the parameter, S, controlling the amount of co- or counter-flow while N-1 sets the thickness of the jet shear layer. We examine how the variation of these fluid and flow parameters affects the minimum value of S at which the flow becomes locally absolutely unstable. Initially setting the Reynolds number to Re = 500, we find that the first varicose jet-column mode dictates the presence of absolute instability, and increasing the Weissenberg number produces important changes in the nature of the instability. The region of absolute instability shifts towards thin shear layers, and the amount of back-flow needed for absolute instability decreases (i.e., the influence of viscoelasticity is destabilizing). Additionally, when We is sufficiently large and N-1 is sufficiently small, single-stream jets become absolutely unstable. Numerical experiments with approximate equations show that both the polymer and solvent contributions to the stress become destabilizing when the scaled shear rate, η = /W e dU¯1/dx 2L ( /d U ¯ 1 d x 2 is the base-state velocity gradient), is sufficiently large. These qualitative trends are largely unchanged when the Reynolds number is reduced; however, the relative importance of the destabilizing stresses increases tangibly. Consequently, absolute instability is substantially enhanced, and single-stream jets become absolutely unstable over a sizable portion of the parameter space.

  18. Heat capacity and absolute entropy of iron phosphides

    SciTech Connect

    Dobrokhotova, Z.V.; Zaitsev, A.I.; Litvina, A.D.

    1994-09-01

    There is little or no data on the thermodynamic properties of iron phosphides despite their importance for several areas of science and technology. The information available is of a qualitative character and is based on assessments of the heat capacity and absolute entropy. In the present work, we measured the heat capacity over the temperature range of 113-873 K using a differential scanning calorimeter (DSC) and calculated the absolute entropy.

  19. Medium and high resolution vacuum UV photoabsorption spectroscopy of methyl iodide (CH 3I) and its deuterated isotopomers CD 3I and CH 2DI. A Rydberg series analysis

    NASA Astrophysics Data System (ADS)

    Locht, R.; Leyh, B.; Jochims, H. W.; Baumgärtel, H.

    2009-11-01

    The vacuum UV photoabsorption spectrum of CH 3I has been investigated between 5 eV and 20 eV. Numerous vibronic transitions are observed. In the high 10-20 eV photon energy range weak to very weak diffuse bands are observed and ascribed to electronic transitions from 3a 1, 1e and 2a 1 to Rydberg orbitals. In the 6-10.5 eV photon energy range more than 200 sharp and strong to weak lines have been observed. Several photon energy ranges were explored under high resolution conditions allowing us to observe many series up to high values of the principal quantum number n. They are assigned to vibrationless Rydberg transitions and classified into two groups converging to the two components of the spin-orbit split XE state of CH 3I +. These two groups consist of six different Rydberg series, i.e., nsa 1, npa 1, npe, nda 1, nde and nf. A very close correlation has been established between the term values of the Rydberg states in CH 3I and in Xe for ns, np, nd and nf Rydberg transitions. For the first time, the same measurements have been performed and the interpretation has been proposed for the photoabsorption spectrum of CH 2DI and CD 3I in the 6-10.5 eV photon energy range. For these two species, ionization energies are deduced: for the XE 3/2 and XE 1/2 states of CH 2DI, these are IE ad = 9.544 eV and IE ad = 10.168 eV, respectively, and the corresponding energies are 9.552 eV and 10.173 eV in CD 3I.

  20. Global absolut gravity reference system as replacement of IGSN 71

    NASA Astrophysics Data System (ADS)

    Wilmes, Herbert; Wziontek, Hartmut; Falk, Reinhard

    2015-04-01

    The determination of precise gravity field parameters is of great importance in a period in which earth sciences are achieving the necessary accuracy to monitor and document global change processes. This is the reason why experts from geodesy and metrology joined in a successful cooperation to make absolute gravity observations traceable to SI quantities, to improve the metrological kilogram definition and to monitor mass movements and smallest height changes for geodetic and geophysical applications. The international gravity datum is still defined by the International Gravity Standardization Net adopted in 1971 (IGSN 71). The network is based upon pendulum and spring gravimeter observations taken in the 1950s and 60s supported by the early free fall absolute gravimeters. Its gravity values agreed in every case to better than 0.1 mGal. Today, more than 100 absolute gravimeters are in use worldwide. The series of repeated international comparisons confirms the traceability of absolute gravity measurements to SI quantities and confirm the degree of equivalence of the gravimeters in the order of a few µGal. For applications in geosciences where e.g. gravity changes over time need to be analyzed, the temporal stability of an absolute gravimeter is most important. Therefore, the proposition is made to replace the IGSN 71 by an up-to-date gravity reference system which is based upon repeated absolute gravimeter comparisons and a global network of well controlled gravity reference stations.

  1. Revisiting absolute and relative judgments in the WITNESS model.

    PubMed

    Fife, Dustin; Perry, Colton; Gronlund, Scott D

    2014-04-01

    The WITNESS model (Clark in Applied Cognitive Psychology 17:629-654, 2003) provides a theoretical framework with which to investigate the factors that contribute to eyewitness identification decisions. One key factor involves the contributions of absolute versus relative judgments. An absolute contribution is determined by the degree of match between an individual lineup member and memory for the perpetrator; a relative contribution involves the degree to which the best-matching lineup member is a better match to memory than the remaining lineup members. In WITNESS, the proportional contributions of relative versus absolute judgments are governed by the values of the decision weight parameters. We conducted an exploration of the WITNESS model's parameter space to determine the identifiability of these relative/absolute decision weight parameters, and compared the results to a restricted version of the model that does not vary the decision weight parameters. This exploration revealed that the decision weights in WITNESS are difficult to identify: Data often can be fit equally well by setting the decision weights to nearly any value and compensating with a criterion adjustment. Clark, Erickson, and Breneman (Law and Human Behavior 35:364-380, 2011) claimed to demonstrate a theoretical basis for the superiority of lineup decisions that are based on absolute contributions, but the relationship between the decision weights and the criterion weakens this claim. These findings necessitate reconsidering the role of the relative/absolute judgment distinction in eyewitness decision making. PMID:23943556

  2. Experimental study of the 15O(2p, γ)17Ne cross section by Coulomb Dissociation for the rp process

    NASA Astrophysics Data System (ADS)

    Marganiec, J.; Warners, F.; Aksouh, F.; Aksyutina, Y.; Alvarez Pol, H.; Aumann, T.; Beceiro, S.; Bertulani, C.; Boretzky, K.; Borge, M. J.; Chartier, M.; Chatillon, A.; Chulkov, L.; Cortina-Gil, D.; Egorova, I.; Emling, H.; Ershova, O.; Forssén, C.; Fraile, L. M.; Fynbo, H.; Galaviz, D.; Geissel, H.; Grigorenko, L.; Heil, M.; Hoffmann, D. H. H.; Hoffmann, J.; Johansson, H.; Jonson, B.; Karakoç, M.; Karagiannis, C.; Kiselev, O.; Kratz, J. V.; Kulessa, R.; Kurz, N.; Langer, C.; Lantz, M.; Larsson, K.; Le Bleis, T.; Lemmon, R.; Litvinov, Yu A.; Mahata, K.; Müntz, C.; Nilsson, T.; Nociforo, C.; Nyman, G.; Ott, W.; Panin, V.; Parfenova, Yu; Paschalis, S.; Perea, A.; Plag, R.; Reifarth, R.; Richter, A.; Riisager, K.; Rodríguez Tajes, C.; Rossi, D.; Schrieder, G.; Shulgina, N.; Simon, H.; Stroth, J.; Sümmerer, K.; Taylor, J.; Tengblad, O.; Tengborn, E.; Weick, H.; Wiescher, M.; Wimmer, C.; Zhukov, M.

    2016-01-01

    The time-reversed reaction 15O(2p, γ)17Ne has been studied by the Coulomb dissociation technique. Secondary 17Ne ion beams at 500 AMeV have been produced by fragmentation reactions of 20Ne in a beryllium production target and dissociated on a secondary Pb target. The incoming beam and the reaction products have been identified with the kinematically complete LAND-R3B experimental setup at GSI. The excitation energy prior to decay has been reconstructed by using the invariant-mass method. The preliminary differential and integral Coulomb Dissociation cross sections (σCoul) have been calculated, which provide a photoabsorption (σphoto) and a radiative capture cross section (σcap). Additionally, important information about the nuclear structure of the 17Ne nucleus will be obtained. The analysis is in progress.

  3. Photoexcitation mechanisms and photofission cross section for Bi by 100--300 MeV quasi-monochromatic photons

    SciTech Connect

    Guaraldo, C.; Lucherini, V.; De Sanctis, E.; Levi Sandri, P.; Polli, E.; Reolon, A.R.; Lo Nigro, S.; Aiello, S.; Bellini, V.; Emma, V.; and others

    1987-09-01

    The photofission cross section of natural Bi was measured in the energy range 100--300 MeV by means of a quasi-monochromatic photon beam. The nuclear fissility P/sub f/ was calculated using the recently measured total photoabsorption cross sections. A discussion on the dependence of fissility from the excitation energy E/sub x/ shows that a linear dependence of lnP/sub f/ vs E/sub x//sup -1/2/ can hardly be assumed over all the considered energy range. The analysis of the data confirms this consideration and shows an evident saturation effect at high excitation energy. As a consequence, in disagreement with recent interpretations, inferring that the modified quasi-deuteron model is the only efficient mechanism in inducing fission of Bi is less compelling, and also the pion photoproduction excitation mechanism plays a role.

  4. Theoretical study of the photodissociation cross sections and the photodissociation dynamics of HOCl

    SciTech Connect

    Nanbu, Shinkoh; Iwata, Suehiro

    1992-03-05

    Potential energy surfaces for electronic ground and excited states of HOCl, which are related to the experimentally observed photoabsorption between 400 and 200 nm, were calculated with the ab initio molecular orbital (MO) configuration interaction (CI) method. The transition dipole moment surfaces between these states were also calculated. Two types of model calculations were carried out for evaluation of the theoretical photodissociation cross section. Theoretical spectra exhibit two peaks at about 335 and 245 nm. They are in better agreement with the experimental results than those in the previous study. The present calculation supports the assumption that the HOCl molecule in the stratosphere may contribute to ozone depletion. The rotational state distributions of the product OH({sup 2}II) were explored with classical trajectory calculations. The rotational state distributions are dependent on the excited state. 36 refs., 14 figs., 3 tabs.

  5. Effective light absorption and absolute electron transport rates in the coral Pocillopora damicornis.

    PubMed

    Szabó, Milán; Wangpraseurt, Daniel; Tamburic, Bojan; Larkum, Anthony W D; Schreiber, Ulrich; Suggett, David J; Kühl, Michael; Ralph, Peter J

    2014-10-01

    Pulse Amplitude Modulation (PAM) fluorometry has been widely used to estimate the relative photosynthetic efficiency of corals. However, both the optical properties of intact corals as well as past technical constrains to PAM fluorometers have prevented calculations of the electron turnover rate of PSII. We used a new Multi-colour PAM (MC-PAM) in parallel with light microsensors to determine for the first time the wavelength-specific effective absorption cross-section of PSII photochemistry, σII(λ), and thus PAM-based absolute electron transport rates of the coral photosymbiont Symbiodinium both in culture and in hospite in the coral Pocillopora damicornis. In both cases, σII of Symbiodinium was highest in the blue spectral region and showed a progressive decrease towards red wavelengths. Absolute values for σII at 440 nm were up to 1.5-times higher in culture than in hospite. Scalar irradiance within the living coral tissue was reduced by 20% in the blue when compared to the incident downwelling irradiance. Absolute electron transport rates of P. damicornis at 440 nm revealed a maximum PSII turnover rate of ca. 250 electrons PSII(-1) s(-1), consistent with one PSII turnover for every 4 photons absorbed by PSII; this likely reflects the limiting steps in electron transfer between PSII and PSI. Our results show that optical properties of the coral host strongly affect light use efficiency of Symbiodinium. Therefore, relative electron transport rates do not reflect the productivity rates (or indeed how the photosynthesis-light response is parameterised). Here we provide a non-invasive approach to estimate absolute electron transport rates in corals. PMID:25146689

  6. Absolute radiometric calibration of Landsat using a pseudo invariant calibration site

    USGS Publications Warehouse

    Helder, D.; Thome, K.J.; Mishra, N.; Chander, G.; Xiong, Xiaoxiong; Angal, A.; Choi, Tae-young

    2013-01-01

    Pseudo invariant calibration sites (PICS) have been used for on-orbit radiometric trending of optical satellite systems for more than 15 years. This approach to vicarious calibration has demonstrated a high degree of reliability and repeatability at the level of 1-3% depending on the site, spectral channel, and imaging geometries. A variety of sensors have used this approach for trending because it is broadly applicable and easy to implement. Models to describe the surface reflectance properties, as well as the intervening atmosphere have also been developed to improve the precision of the method. However, one limiting factor of using PICS is that an absolute calibration capability has not yet been fully developed. Because of this, PICS are primarily limited to providing only long term trending information for individual sensors or cross-calibration opportunities between two sensors. This paper builds an argument that PICS can be used more extensively for absolute calibration. To illustrate this, a simple empirical model is developed for the well-known Libya 4 PICS based on observations by Terra MODIS and EO-1 Hyperion. The model is validated by comparing model predicted top-of-atmosphere reflectance values to actual measurements made by the Landsat ETM+ sensor reflective bands. Following this, an outline is presented to develop a more comprehensive and accurate PICS absolute calibration model that can be Système international d'unités (SI) traceable. These initial concepts suggest that absolute calibration using PICS is possible on a broad scale and can lead to improved on-orbit calibration capabilities for optical satellite sensors.

  7. Intensity evaluation using a femtosecond pulse laser for absolute distance measurement.

    PubMed

    Wu, Hanzhong; Zhang, Fumin; Li, Jianshuang; Cao, Shiying; Meng, Xiangsong; Qu, Xinghua

    2015-06-10

    In this paper, we propose a method of intensity evaluation based on different pulse models using a femtosecond pulse laser, which enables long-range absolute distance measurement with nanometer precision and large non-ambiguity range. The pulse cross-correlation is analyzed based on different pulse models, including Gaussian, Sech(2), and Lorenz. The DC intensity and the amplitude of the cross-correlation patterns are also demonstrated theoretically. In the experiments, we develop a new combined system and perform the distance measurements on an underground granite rail system. The DC intensity and amplitude of the interference fringes are measured and show a good agreement with the theory, and the distance to be determined can be up to 25 m using intensity evaluation, within 64 nm deviation compared with a He-Ne incremental interferometer, and corresponds to a relative precision of 2.7×10(-9). PMID:26192864

  8. High-resolution absorption cross section measurements of supersonic jet-cooled carbon monoxide between 92.5 and 97.4 nanometers

    NASA Technical Reports Server (NTRS)

    Yoshino, K.; Stark, G.; Esmond, J. R.; Smith, P. L.; Ito, K.; Matsui, T.

    1995-01-01

    High-resolution photoabsorption cross sections for eight CO bands, at wavelengths between 92.5 nm and 97.4 nm, have been measured in a supersonic jet-cooled source (approximately equals 20 K) at the Photon Factory synchrotron radiation facility. New integrated cross sections are reported for four bands between 92.5 nm and 94.2 nm. A low-temperature spectrum of the W(1)-X(0) band (95.6 nm), which was used to determine the absorbing CO column densities, is also presented. Additional jet-cooled cross section measurements were made on the L(0)-X(0), K(0)-X(0), and W(0)-X(0) bands (96.7-97.4 nm) which verify previously published results. A self-consistent set of band oscillator strengths is presented for the eight bands studied.

  9. Estimation of absolute protein quantities of unlabeled samples by selected reaction monitoring mass spectrometry.

    PubMed

    Ludwig, Christina; Claassen, Manfred; Schmidt, Alexander; Aebersold, Ruedi

    2012-03-01

    For many research questions in modern molecular and systems biology, information about absolute protein quantities is imperative. This information includes, for example, kinetic modeling of processes, protein turnover determinations, stoichiometric investigations of protein complexes, or quantitative comparisons of different proteins within one sample or across samples. To date, the vast majority of proteomic studies are limited to providing relative quantitative comparisons of protein levels between limited numbers of samples. Here we describe and demonstrate the utility of a targeting MS technique for the estimation of absolute protein abundance in unlabeled and nonfractionated cell lysates. The method is based on selected reaction monitoring (SRM) mass spectrometry and the "best flyer" hypothesis, which assumes that the specific MS signal intensity of the most intense tryptic peptides per protein is approximately constant throughout a whole proteome. SRM-targeted best flyer peptides were selected for each protein from the peptide precursor ion signal intensities from directed MS data. The most intense transitions per peptide were selected from full MS/MS scans of crude synthetic analogs. We used Monte Carlo cross-validation to systematically investigate the accuracy of the technique as a function of the number of measured best flyer peptides and the number of SRM transitions per peptide. We found that a linear model based on the two most intense transitions of the three best flying peptides per proteins (TopPep3/TopTra2) generated optimal results with a cross-correlated mean fold error of 1.8 and a squared Pearson coefficient R(2) of 0.88. Applying the optimized model to lysates of the microbe Leptospira interrogans, we detected significant protein abundance changes of 39 target proteins upon antibiotic treatment, which correlate well with literature values. The described method is generally applicable and exploits the inherent performance advantages of SRM

  10. Absolute intensity and polarization of rotational Raman scattering from N2, O2, and CO2

    NASA Technical Reports Server (NTRS)

    Penney, C. M.; St.peters, R. L.; Lapp, M.

    1973-01-01

    An experimental examination of the absolute intensity, polarization, and relative line intensities of rotational Raman scattering (RRS) from N2, O2, and CO2 is reported. The absolute scattering intensity for N2 is characterized by its differential cross section for backscattering of incident light at 647.1 nm, which is calculated from basic measured values. The ratio of the corresponding cross section for O2 to that for N2 is 2.50 plus or minus 5 percent. The intensity recent for N2, O2, and CO2 are shown to compare favorably to values calculated from recent measurements of the depolarization of Rayleigh scattering plus RRS. Measured depolarizations of various RRS lines agree to within a few percent with the theoretical value of 3/4. Detailed error analyses are presented for intensity and depolarization measurements. Finally, extensive RRS spectra at nominal gas temperatures of 23 C, 75 C, and 125 C are presented and shown to compare favorably to theoretical predictions.

  11. Near-Threshold Photodetachment Cross Section of (SF6)(n)(-) Cluster Anions: The Ion Core Structure.

    PubMed

    Luzon, Itamar; Nagler, Maoz; Chandrasekaran, Vijayanand; Heber, Oded; Strasser, Daniel

    2016-01-21

    Photodetachment cross sections as a function of photon energy are measured for cold (SF6)n(-) cluster anions stored in an electrostatic ion beam trap. Absolute photodetachment cross sections near the adiabatic limit are reported. The strong dependence of the SF6(-) absolute photodetachment cross section on the anion equilibrium bond length leads to the conclusion that the excess charge is localized on a SF6(-) ion core that is only subtly perturbed by the neighboring cluster units. PMID:26667587

  12. Nuclear depolarization and absolute sensitivity in magic-angle spinning cross effect dynamic nuclear polarization.

    PubMed

    Mentink-Vigier, Frédéric; Paul, Subhradip; Lee, Daniel; Feintuch, Akiva; Hediger, Sabine; Vega, Shimon; De Paëpe, Gaël

    2015-09-14

    Over the last two decades solid state Nuclear Magnetic Resonance has witnessed a breakthrough in increasing the nuclear polarization, and thus experimental sensitivity, with the advent of Magic Angle Spinning Dynamic Nuclear Polarization (MAS-DNP). To enhance the nuclear polarization of protons, exogenous nitroxide biradicals such as TOTAPOL or AMUPOL are routinely used. Their efficiency is usually assessed as the ratio between the NMR signal intensity in the presence and the absence of microwave irradiation εon/off. While TOTAPOL delivers an enhancement εon/off of about 60 on a model sample, the more recent AMUPOL is more efficient: >200 at 100 K. Such a comparison is valid as long as the signal measured in the absence of microwaves is merely the Boltzmann polarization and is not affected by the spinning of the sample. However, recent MAS-DNP studies at 25 K by Thurber and Tycko (2014) have demonstrated that the presence of nitroxide biradicals combined with sample spinning can lead to a depolarized nuclear state, below the Boltzmann polarization. In this work we demonstrate that TOTAPOL and AMUPOL both lead to observable depolarization at ≈110 K, and that the magnitude of this depolarization is radical dependent. Compared to the static sample, TOTAPOL and AMUPOL lead, respectively, to nuclear polarization losses of up to 20% and 60% at a 10 kHz MAS frequency, while Trityl OX63 does not depolarize at all. This experimental work is analyzed using a theoretical model that explains how the depolarization process works under MAS and gives new insights into the DNP mechanism and into the spin parameters, which are relevant for the efficiency of a biradical. In light of these results, the outstanding performance of AMUPOL must be revised and we propose a new method to assess the polarization gain for future radicals. PMID:26235749

  13. Absolute irradiance of the Moon for on-orbit calibration

    USGS Publications Warehouse

    Stone, T.C.; Kieffer, H.H.

    2002-01-01

    The recognized need for on-orbit calibration of remote sensing imaging instruments drives the ROLO project effort to characterize the Moon for use as an absolute radiance source. For over 5 years the ground-based ROLO telescopes have acquired spatially-resolved lunar images in 23 VNIR (Moon diameter ???500 pixels) and 9 SWIR (???250 pixels) passbands at phase angles within ??90 degrees. A numerical model for lunar irradiance has been developed which fits hundreds of ROLO images in each band, corrected for atmospheric extinction and calibrated to absolute radiance, then integrated to irradiance. The band-coupled extinction algorithm uses absorption spectra of several gases and aerosols derived from MODTRAN to fit time-dependent component abundances to nightly observations of standard stars. The absolute radiance scale is based upon independent telescopic measurements of the star Vega. The fitting process yields uncertainties in lunar relative irradiance over small ranges of phase angle and the full range of lunar libration well under 0.5%. A larger source of uncertainty enters in the absolute solar spectral irradiance, especially in the SWIR, where solar models disagree by up to 6%. Results of ROLO model direct comparisons to spacecraft observations demonstrate the ability of the technique to track sensor responsivity drifts to sub-percent precision. Intercomparisons among instruments provide key insights into both calibration issues and the absolute scale for lunar irradiance.

  14. System and method for calibrating a rotary absolute position sensor

    NASA Technical Reports Server (NTRS)

    Davis, Donald R. (Inventor); Permenter, Frank Noble (Inventor); Radford, Nicolaus A (Inventor)

    2012-01-01

    A system includes a rotary device, a rotary absolute position (RAP) sensor generating encoded pairs of voltage signals describing positional data of the rotary device, a host machine, and an algorithm. The algorithm calculates calibration parameters usable to determine an absolute position of the rotary device using the encoded pairs, and is adapted for linearly-mapping an ellipse defined by the encoded pairs to thereby calculate the calibration parameters. A method of calibrating the RAP sensor includes measuring the rotary position as encoded pairs of voltage signals, linearly-mapping an ellipse defined by the encoded pairs to thereby calculate the calibration parameters, and calculating an absolute position of the rotary device using the calibration parameters. The calibration parameters include a positive definite matrix (A) and a center point (q) of the ellipse. The voltage signals may include an encoded sine and cosine of a rotary angle of the rotary device.

  15. Method and apparatus for two-dimensional absolute optical encoding

    NASA Technical Reports Server (NTRS)

    Leviton, Douglas B. (Inventor)

    2004-01-01

    This invention presents a two-dimensional absolute optical encoder and a method for determining position of an object in accordance with information from the encoder. The encoder of the present invention comprises a scale having a pattern being predetermined to indicate an absolute location on the scale, means for illuminating the scale, means for forming an image of the pattern; and detector means for outputting signals derived from the portion of the image of the pattern which lies within a field of view of the detector means, the field of view defining an image reference coordinate system, and analyzing means, receiving the signals from the detector means, for determining the absolute location of the object. There are two types of scale patterns presented in this invention: grid type and starfield type.

  16. Absolute and Convective Instability in Fluid-Conveying Flexible Pipes

    NASA Astrophysics Data System (ADS)

    de Langre, E.; Ouvrard, A. E.

    1998-11-01

    The effect of internal plug flow on the lateral stability of fluid conveying flexible pipes is investigated by determining the absolute/convective nature of the instability from the analytically derived linear dispersion relation. The fluid-structure interaction is modeled following the work of Gregory and Paidoussis (1966). The different domains of stability, convective instability, and absolute instability are explicitly derived in parameter space. The effect of flow velocity, mass ratio between the fluid and the structure, stiffness of the elastic foundation and axial tension is considered. Absolute instability prevails over a wide range of parameters. Convective instability only takes place at very high mass ratio, small stiffness and small axial tension. Relation is made with previous work of Brazier-Smith & Scott (1984) and Crighton (1991), considered here as a short wave approximation.

  17. Absolute surface metrology by rotational averaging in oblique incidence interferometry.

    PubMed

    Lin, Weihao; He, Yumei; Song, Li; Luo, Hongxin; Wang, Jie

    2014-06-01

    A modified method for measuring the absolute figure of a large optical flat surface in synchrotron radiation by a small aperture interferometer is presented. The method consists of two procedures: the first step is oblique incidence measurement; the second is multiple rotating measurements. This simple method is described in terms of functions that are symmetric or antisymmetric with respect to reflections at the vertical axis. Absolute deviations of a large flat surface could be obtained when mirror antisymmetric errors are removed by N-position rotational averaging. Formulas are derived for measuring the absolute surface errors of a rectangle flat, and experiments on high-accuracy rectangle flats are performed to verify the method. Finally, uncertainty analysis is carried out in detail. PMID:24922410

  18. Field Measurement of Sand Dune Bidirectional Reflectance Characteristics for Absolute Radiometric Calibration of Optical Remote Sensing Data.

    NASA Astrophysics Data System (ADS)

    Coburn, C. A.; Logie, G.; Beaver, J.; Helder, D.

    2015-12-01

    The use of Pseudo Invariant Calibration Sites (PICS) for establishing the radiometric trending of optical remote sensing systems has a long history of successful implementation. Past studies have shown that the PICS method is useful for evaluating the trend of sensors over time or cross-calibration of sensors but was not considered until recently for deriving absolute calibration. Current interest in using this approach to establish absolute radiometric calibration stems from recent research that indicates that with empirically derived models of the surface properties and careful atmospheric characterisation Top of Atmosphere (TOA) reflectance values can be predicted and used for absolute sensor radiometric calibration. Critical to the continued development of this approach is the accurate characterization of the Bidirectional Reflectance Distribution Function (BRDF) of PICS sites. This paper presents the field data collected by a high-performance portable goniometer system in order to develop a BRDF model for the Algodones Dunes in California. These BRDF data are part of a larger study that is seeking to evaluate and quantify all aspects of this dune system (from regional effects to the micro scale optical properties of the sand) in order to provide an absolute radiometric calibration PICS. This paper presents the results of a dense temporal measurement sequence (several measurements per hour with high angular resolution), to yield detailed information on the nature of the surface reflectance properties. The BRDF data were collected covering typical view geometry of space borne sensors and will be used to close the loop on the calibration to create an absolute calibration target for optical satellite absolute radiometric calibration.

  19. Non-Invasive Method of Determining Absolute Intracranial Pressure

    NASA Technical Reports Server (NTRS)

    Yost, William T. (Inventor); Cantrell, John H., Jr. (Inventor); Hargens, Alan E. (Inventor)

    2004-01-01

    A method is presented for determining absolute intracranial pressure (ICP) in a patient. Skull expansion is monitored while changes in ICP are induced. The patient's blood pressure is measured when skull expansion is approximately zero. The measured blood pressure is indicative of a reference ICP value. Subsequently, the method causes a known change in ICP and measured the change in skull expansion associated therewith. The absolute ICP is a function of the reference ICP value, the known change in ICP and its associated change in skull expansion; and a measured change in skull expansion.

  20. Measurements of the reactor neutron power in absolute units

    NASA Astrophysics Data System (ADS)

    Lebedev, G. V.

    2015-12-01

    The neutron power of the reactor of the Yenisei space nuclear power plant is measured in absolute units using the modernized method of correlation analysis during the ground-based tests of the Yenisei prototypes. Results of the experiments are given. The desired result is obtained in a series of experiments carried out at the stage of the plant preparation for tests. The acceptability of experimental data is confirmed by the results of measuring the reactor neutron power in absolute units at the nominal level by the thermal balance during the life cycle tests of the ground prototypes.

  1. In-flight absolute radiometric calibration of the thematic mapper

    NASA Technical Reports Server (NTRS)

    Castle, K. R.; Holm, R. G.; Kastner, C. J.; Palmer, J. M.; Slater, P. N.; Dinguirard, M.; Ezra, C. E.; Jackson, R. D.; Savage, R. K.

    1983-01-01

    The TM multispectral scanner system was calibrated in an absolute manner before launch. To determine the temporal changes of the absolute radiometric calibration of the entire system, spectroradiometric measurements of the ground and the atmosphere were made simultaneously with TM collections over White Sands, New Mexico. By entering the measured values in an atmospheric radiative transfer program, the radiance levels of the in four of the spectral bands of the TM were determined. Tables show values for the reflectance of snow at White Sands measured by a modular 8 channel radiometer, and values for exoatmospheric irradiance within the TM passbands, calculated for the Earth-Sun distance using a solar radiometer.

  2. Absolute photon-flux measurements in the vacuum ultraviolet

    NASA Technical Reports Server (NTRS)

    Samson, J. A. R.; Haddad, G. N.

    1974-01-01

    Absolute photon-flux measurements in the vacuum ultraviolet have extended to short wavelengths by use of rare-gas ionization chambers. The technique involves the measurement of the ion current as a function of the gas pressure in the ion chamber. The true value of the ion current, and hence the absolute photon flux, is obtained by extrapolating the ion current to zero gas pressure. Examples are given at 162 and 266 A. The short-wavelength limit is determined only by the sensitivity of the current-measuring apparatus and by present knowledge of the photoionization processes that occur in the rate gases.

  3. Notes on Van der Meer scan for absolute luminosity measurement

    NASA Astrophysics Data System (ADS)

    Balagura, Vladislav

    2011-10-01

    The absolute luminosity can be measured in an accelerator by sweeping beams transversely across each other in the so-called van der Meer scan. We prove that the method can be applied in the general case of arbitrary beam directions and a separation scan plane. A simple method to develop an image of the beam in its transverse plane from spatial distributions of interaction vertexes is also proposed. From the beam images one can determine their overlap and the absolute luminosity. This provides an alternative way of the luminosity measurement during van der Meer scan.

  4. Measurements of the reactor neutron power in absolute units

    SciTech Connect

    Lebedev, G. V.

    2015-12-15

    The neutron power of the reactor of the Yenisei space nuclear power plant is measured in absolute units using the modernized method of correlation analysis during the ground-based tests of the Yenisei prototypes. Results of the experiments are given. The desired result is obtained in a series of experiments carried out at the stage of the plant preparation for tests. The acceptability of experimental data is confirmed by the results of measuring the reactor neutron power in absolute units at the nominal level by the thermal balance during the life cycle tests of the ground prototypes.

  5. Absolute Stability Analysis of a Phase Plane Controlled Spacecraft

    NASA Technical Reports Server (NTRS)

    Jang, Jiann-Woei; Plummer, Michael; Bedrossian, Nazareth; Hall, Charles; Jackson, Mark; Spanos, Pol

    2010-01-01

    Many aerospace attitude control systems utilize phase plane control schemes that include nonlinear elements such as dead zone and ideal relay. To evaluate phase plane control robustness, stability margin prediction methods must be developed. Absolute stability is extended to predict stability margins and to define an abort condition. A constrained optimization approach is also used to design flex filters for roll control. The design goal is to optimize vehicle tracking performance while maintaining adequate stability margins. Absolute stability is shown to provide satisfactory stability constraints for the optimization.

  6. A general relativistic model for free-fall absolute gravimeters

    NASA Astrophysics Data System (ADS)

    Tan, Yu-Jie; Shao, Cheng-Gang; Li, Jia; Hu, Zhong-Kun

    2016-04-01

    Although the relativistic manifestations of gravitational fields in gravimetry were first studied 40 years ago, the relativistic effects combined with free-fall absolute gravimeters have rarely been considered. In light of this, we present a general relativistic model for free-fall absolute gravimeters in a local-Fermi coordinates system, where we focus on effects related to the measuring devices: relativistic transverse Doppler effects, gravitational redshift effects and Earth’s rotation effects. Based on this model, a general relativistic expression of the measured gravity acceleration is obtained.

  7. False Cross

    NASA Astrophysics Data System (ADS)

    Murdin, P.

    2000-11-01

    The asterism formed by the four stars δ and κ Velorum, and ɛ and ι Carinae, all of the second magnitude, which make up a cross of about 10°×6°. It is so named because it is sometimes mistaken for the Southern Cross (Crux) by observers unfamiliar with the southern sky. There is a superficial resemblance, but Crux is more compact (about 7°×5°) and comprises rather brighter stars. The two crosses ca...

  8. Absolute determination of inelastic mean-free paths and surface excitation parameters by absolute reflection electron energy loss spectrum analysis

    NASA Astrophysics Data System (ADS)

    Nagatomi, T.; Goto, K.

    2005-11-01

    An analytical approach was proposed for simultaneously determining an inelastic mean-free path (IMFP) and a surface excitation parameter (SEP) with absolute units by the analysis of an absolute experimental reflection electron energy loss spectrum. The IMFPs and SEPs in Ni were deduced for electrons of 300 to 3000 eV. The obtained IMFPs were in good agreement with those calculated using the TPP-2M equation. The Chen-type empirical formula was proposed for determining the SEP. The results confirmed the applicability of the present approach for determining the IMFP and SEP for medium-energy electrons.

  9. Series that Converge Absolutely but Don't Converge

    ERIC Educational Resources Information Center

    Kantrowitz, Robert; Schramm, Michael

    2012-01-01

    If a series of real numbers converges absolutely, then it converges. The usual proof requires completeness in the form of the Cauchy criterion. Failing completeness, the result is false. We provide examples of rational series that illustrate this point. The Cantor set appears in connection with one of the examples.

  10. Population-based absolute risk estimation with survey data.

    PubMed

    Kovalchik, Stephanie A; Pfeiffer, Ruth M

    2014-04-01

    Absolute risk is the probability that a cause-specific event occurs in a given time interval in the presence of competing events. We present methods to estimate population-based absolute risk from a complex survey cohort that can accommodate multiple exposure-specific competing risks. The hazard function for each event type consists of an individualized relative risk multiplied by a baseline hazard function, which is modeled nonparametrically or parametrically with a piecewise exponential model. An influence method is used to derive a Taylor-linearized variance estimate for the absolute risk estimates. We introduce novel measures of the cause-specific influences that can guide modeling choices for the competing event components of the model. To illustrate our methodology, we build and validate cause-specific absolute risk models for cardiovascular and cancer deaths using data from the National Health and Nutrition Examination Survey. Our applications demonstrate the usefulness of survey-based risk prediction models for predicting health outcomes and quantifying the potential impact of disease prevention programs at the population level. PMID:23686614

  11. Invalid phase values removal method for absolute phase recovery.

    PubMed

    Lu, Jin; Mo, Rong; Sun, Huibin; Chang, Zhiyong; Zhao, Xiaxia

    2016-01-10

    A novel approach is presented for more effectively removing invalid phase values in absolute phase recovery. The approach is based on a detailed study involving the types and cases of invalid phase values. Meanwhile, some commonalities of the existing removal algorithms also are thoroughly analyzed. It is well known that rough absolute phase and fringe order maps can very easily be obtained by temporal phase unwrapping techniques. After carefully analyzing the components and fringe order distribution of the rough fringe order map, the proposed method chiefly adopts an entirely new strategy to refine a pure fringe order map. The strategy consists of three parts: (1) the square of an image gradient, (2) subregion areas of the binary image, and (3) image decomposition and composition. In combination with the pure fringe order map and a removal criterion, the invalid phase values can be identified and filtered out from the rough absolute phase map. This new strategy not only gets rid of the limitations of traditional removal methods but also has a two-fold function. The paper also offers different metrics from the experiment to evaluate the quality of the final absolute phase. In contrast with other removal methods, experimental results have verified the feasibility, effectiveness, and superiority of the proposed method. PMID:26835776

  12. Absolute Value Inequalities: High School Students' Solutions and Misconceptions

    ERIC Educational Resources Information Center

    Almog, Nava; Ilany, Bat-Sheva

    2012-01-01

    Inequalities are one of the foundational subjects in high school math curricula, but there is a lack of academic research into how students learn certain types of inequalities. This article fills part of the research gap by presenting the findings of a study that examined high school students' methods of approaching absolute value inequalities,…

  13. Lyman alpha SMM/UVSP absolute calibration and geocoronal correction

    NASA Technical Reports Server (NTRS)

    Fontenla, Juan M.; Reichmann, Edwin J.

    1987-01-01

    Lyman alpha observations from the Ultraviolet Spectrometer Polarimeter (UVSP) instrument of the Solar Maximum Mission (SMM) spacecraft were analyzed and provide instrumental calibration details. Specific values of the instrument quantum efficiency, Lyman alpha absolute intensity, and correction for geocoronal absorption are presented.

  14. An improved generalized Newton method for absolute value equations.

    PubMed

    Feng, Jingmei; Liu, Sanyang

    2016-01-01

    In this paper, we suggest and analyze an improved generalized Newton method for solving the NP-hard absolute value equations [Formula: see text] when the singular values of A exceed 1. We show that the global and local quadratic convergence of the proposed method. Numerical experiments show the efficiency of the method and the high accuracy of calculation. PMID:27462490

  15. Relative versus Absolute Stimulus Control in the Temporal Bisection Task

    ERIC Educational Resources Information Center

    de Carvalho, Marilia Pinhiero; Machado, Armando

    2012-01-01

    When subjects learn to associate two sample durations with two comparison keys, do they learn to associate the keys with the short and long samples (relational hypothesis), or with the specific sample durations (absolute hypothesis)? We exposed 16 pigeons to an ABA design in which phases A and B corresponded to tasks using samples of 1 s and 4 s,…

  16. Absolute calibration of Landsat instruments using the moon.

    USGS Publications Warehouse

    Kieffer, H.H.; Wildey, R.L.

    1985-01-01

    A lunar observation by Landsat could provide improved radiometric and geometric calibration of both the Thematic Mapper and the Multispectral Scanner in terms of absolute radiometry, determination of the modulation transfer function, and sensitivity to scattered light. A pitch of the spacecraft would be required. -Authors

  17. Absence of absolutely continuous spectrum for random scattering zippers

    NASA Astrophysics Data System (ADS)

    Boumaza, Hakim; Marin, Laurent

    2015-02-01

    A scattering zipper is a system obtained by concatenation of scattering events with equal even number of incoming and outgoing channels. The associated scattering zipper operator is the unitary analog of Jacobi matrices with matrix entries. For infinite identical events and independent and identically distributed random phases, Lyapunov exponents positivity is proved and yields absence of absolutely continuous spectrum by Kotani's theory.

  18. Individual Differences in Absolute and Relative Metacomprehension Accuracy

    ERIC Educational Resources Information Center

    Maki, Ruth H.; Shields, Micheal; Wheeler, Amanda Easton; Zacchilli, Tammy Lowery

    2005-01-01

    The authors investigated absolute and relative metacomprehension accuracy as a function of verbal ability in college students. Students read hard texts, revised texts, or a mixed set of texts. They then predicted their performance, took a multiple-choice test on the texts, and made posttest judgments about their performance. With hard texts,…

  19. Mathematical Model for Absolute Magnetic Measuring Systems in Industrial Applications

    NASA Astrophysics Data System (ADS)

    Fügenschuh, Armin; Fügenschuh, Marzena; Ludszuweit, Marina; Mojsic, Aleksandar; Sokół, Joanna

    2015-09-01

    Scales for measuring systems are either based on incremental or absolute measuring methods. Incremental scales need to initialize a measurement cycle at a reference point. From there, the position is computed by counting increments of a periodic graduation. Absolute methods do not need reference points, since the position can be read directly from the scale. The positions on the complete scales are encoded using two incremental tracks with different graduation. We present a new method for absolute measuring using only one track for position encoding up to micrometre range. Instead of the common perpendicular magnetic areas, we use a pattern of trapezoidal magnetic areas, to store more complex information. For positioning, we use the magnetic field where every position is characterized by a set of values measured by a hall sensor array. We implement a method for reconstruction of absolute positions from the set of unique measured values. We compare two patterns with respect to uniqueness, accuracy, stability and robustness of positioning. We discuss how stability and robustness are influenced by different errors during the measurement in real applications and how those errors can be compensated.

  20. Absolute Radiometer for Reproducing the Solar Irradiance Unit

    NASA Astrophysics Data System (ADS)

    Sapritskii, V. I.; Pavlovich, M. N.

    1989-01-01

    A high-precision absolute radiometer with a thermally stabilized cavity as receiving element has been designed for use in solar irradiance measurements. The State Special Standard of the Solar Irradiance Unit has been built on the basis of the developed absolute radiometer. The Standard also includes the sun tracking system and the system for automatic thermal stabilization and information processing, comprising a built-in microcalculator which calculates the irradiance according to the input program. During metrological certification of the Standard, main error sources have been analysed and the non-excluded systematic and accidental errors of the irradiance-unit realization have been determined. The total error of the Standard does not exceed 0.3%. Beginning in 1984 the Standard has been taking part in a comparison with the Å 212 pyrheliometer and other Soviet and foreign standards. In 1986 it took part in the international comparison of absolute radiometers and standard pyrheliometers of socialist countries. The results of the comparisons proved the high metrological quality of this Standard based on an absolute radiometer.

  1. Multifrequency continuous wave terahertz spectroscopy for absolute thickness determination

    SciTech Connect

    Scheller, Maik; Baaske, Kai; Koch, Martin

    2010-04-12

    We present a tunable multifrequency continuous wave terahertz spectrometer based on two laser diodes, photoconductive antennas, and a coherent detection scheme. The system is employed to determine the absolute thickness of samples utilizing a proposed synthetic difference frequency method to circumvent the 2pi uncertainty known from conventional photomixing systems while preserving a high spatial resolution.

  2. Ion chambers simplify absolute intensity measurements in the vacuum ultraviolet

    NASA Technical Reports Server (NTRS)

    Sampson, J. A. R.

    1966-01-01

    Single or double ion chamber technique measures absolute radiation intensities in the extreme vacuum ultraviolet region of the spectrum. The ion chambers use rare gases as the ion carrier. Photon absorbed by the gas creates one ion pair so a measure of these is a measure of the number of incident photons.

  3. Urey: to measure the absolute age of Mars

    NASA Technical Reports Server (NTRS)

    Randolph, J. E.; Plescia, J.; Bar-Cohen, Y.; Bartlett, P.; Bickler, D.; Carlson, R.; Carr, G.; Fong, M.; Gronroos, H.; Guske, P. J.; Herring, M.; Javadi, H.; Johnson, D. W.; Larson, T.; Malaviarachchi, K.; Sherrit, S.; Stride, S.; Trebi-Ollennu, A.; Warwick, R.

    2003-01-01

    UREY, a proposed NASA Mars Scout mission will, for the first time, measure the absolute age of an identified igneous rock formation on Mars. By extension to relatively older and younger rock formations dated by remote sensing, these results will enable a new and better understanding of Martian geologic history.

  4. Is There a Rule of Absolute Neutralization in Nupe?

    ERIC Educational Resources Information Center

    Krohn, Robert

    1975-01-01

    A previously prosed rule of absolute neutralization (merging underlying low vowels) is eliminated in an alternative analysis including instead a rule that "breaks" the feature matrix of certain low vowels and redistributes the features of each vowel as a sequence of vowel-like transition plus (a). (Author/RM)

  5. Assignment of absolute stereochemistry by computation of optical rotation angles

    NASA Astrophysics Data System (ADS)

    Kondru, Rama Krishna

    We have developed simple wire and molecular orbital models to qualitatively and quantitatively understand optical rotation angles of molecules. We reported the first ab initio theoretical approach to determine the absolute stereochemistry of a complex natural product by calculating molar rotation angles, [M]D. We applied this method for an unambiguous assignment of the absolute stereochemistry of the hennoxazole A. A protocol analogous to population analysis was devised to analyze atomic contributions to the rotation angles for oxiranes, orthoesters, and other organic compounds. The molar rotations for an indoline, an indonone, menthol and menthone were calculated using ab inito methods and compared with experimental values. We reported the first prediction of the absolute configuration of a natural product, i.e. an a priori assignment of the relative and absolute stereochemistry of pitiamide A. Furthermore, we described a strategy that may help to establish structure-function relations for rotation angles by visualizing the electric and magnetic-field perturbations to a molecule's molecular orbitals.

  6. Hitting the target: relatively easy, yet absolutely difficult.

    PubMed

    Mapp, Alistair P; Ono, Hiroshi; Khokhotva, Mykola

    2007-01-01

    It is generally agreed that absolute-direction judgments require information about eye position, whereas relative-direction judgments do not. The source of this eye-position information, particularly during monocular viewing, is a matter of debate. It may be either binocular eye position, or the position of the viewing-eye only, that is crucial. Using more ecologically valid stimulus situations than the traditional LED in the dark, we performed two experiments. In experiment 1, observers threw darts at targets that were fixated either monocularly or binocularly. In experiment 2, observers aimed a laser gun at targets while fixating either the rear or the front gunsight monocularly, or the target either monocularly or binocularly. We measured the accuracy and precision of the observers' absolute- and relative-direction judgments. We found that (a) relative-direction judgments were precise and independent of phoria, and (b) monocular absolute-direction judgments were inaccurate, and the magnitude of the inaccuracy was predictable from the magnitude of phoria. These results confirm that relative-direction judgments do not require information about eye position. Moreover, they show that binocular eye-position information is crucial when judging the absolute direction of both monocular and binocular targets. PMID:17972479

  7. Absolute Risk Aversion and the Returns to Education.

    ERIC Educational Resources Information Center

    Brunello, Giorgio

    2002-01-01

    Uses 1995 Italian household income and wealth survey to measure individual absolute risk aversion of 1,583 married Italian male household heads. Uses this measure as an instrument for attained education in a standard-log earnings equation. Finds that the IV estimate of the marginal return to schooling is much higher than the ordinary least squares…

  8. Improved cavity-type absolute total-radiation radiometer

    NASA Technical Reports Server (NTRS)

    Kendall, J. M., Sr.; Plamondon, J. A., Jr.

    1967-01-01

    Conical cavity-type absolute radiometer measures the intensity of radiant energy to an accuracy of one to two percent in a vacuum of ten to the minus fifth torr or lower. There is a uniform response over the ultraviolet, visible, and infrared range, and it requires no calibration or comparison with a radiation standard.

  9. Absolute Interrogative Intonation Patterns in Buenos Aires Spanish

    ERIC Educational Resources Information Center

    Lee, Su Ar

    2010-01-01

    In Spanish, each uttered phrase, depending on its use, has one of a variety of intonation patterns. For example, a phrase such as "Maria viene manana" "Mary is coming tomorrow" can be used as a declarative or as an absolute interrogative (a yes/no question) depending on the intonation pattern that a speaker produces. Patterns of usage also…

  10. Absolute configurations of zingiberenols isolated from ginger (Zingiber officinale) rhizomes

    Technology Transfer Automated Retrieval System (TEKTRAN)

    The sesquiterpene alcohol zingiberenol, or 1,10-bisaboladien-3-ol, was isolated some time ago from ginger, Zingiber officinale, rhizomes, but its absolute configuration had not been determined. With three chiral centers present in the molecule, zingiberenol can exist in eight stereoisomeric forms. ...

  11. Four Years of Absolute Gravity in the Taiwan Orogen (AGTO)

    NASA Astrophysics Data System (ADS)

    Mouyen, Maxime; Masson, Frédéric; Hwang, Cheinway; Cheng, Ching-Chung; Le Moigne, Nicolas; Lee, Chiung-Wu; Kao, Ricky; Hsieh, Nicky

    2010-05-01

    AGTO is a scientific project between Taiwanese and French institutes, which aim is to improve tectonic knowledge of Taiwan primarily using absolute gravity measurements and permanent GPS stations. Both tools are indeed useful to study vertical movements and mass transfers involved in mountain building, a major process in Taiwan located at the convergent margin between Philippine Sea plate and Eurasian plate. This convergence results in two subductions north and south of Taiwan (Ryukyu and Manilla trenches, respectively), while the center is experiencing collision. These processes make Taiwan very active tectonically, as illustrated by numerous large earthquakes and rapid uplift of the Central Range. High slopes of Taiwan mountains and heavy rains brought by typhoons together lead to high landslides and mudflows risks. Practically, absolute gravity measurements have been yearly repeated since 2006 along a transect across south Taiwan, from Penghu to Lutao islands, using FG5 absolute gravimeters. This transect contains ten sites for absolute measurements and has been densified in 2008 by incorporating 45 sites for relative gravity measurements with CG5 gravimeters. The last relative and absolute measurements have been performed in November 2009. Most of the absolute sites have been measured with a good accuracy, about 1 or 2 ?Gal. Only the site located in Tainan University has higher standard deviation, due to the city noise. We note that absolute gravity changes seem to follow a trend in every site. However, straightforward tectonic interpretation of these trends is not valuable as many non-tectonic effects are supposed to change g with time, like groundwater or erosion. Estimating and removing these effects leads to a tectonic gravity signal, which has theoretically two origins : deep mass transfers around the site and vertical movements of the station. The latter can be well constrained by permanent GPS stations located close to the measurement pillar. Deep mass

  12. Four Years of Absolute Gravity in the Taiwan Orogen (AGTO)

    NASA Astrophysics Data System (ADS)

    Mouyen, M.; Masson, F.; Hwang, C.; Cheng, C.; Le Moigne, N.; Lee, C.; Kao, R.; Hsieh, N.

    2009-12-01

    AGTO is a scientific project between Taiwanese and French institutes which aim is to improve tectonic knowledge of Taiwan primarily using absolute gravity measurements and permanent GPS stations. Both tools are indeed useful to study vertical movements and mass transfers involved in mountain building, a major process in Taiwan located at the convergent margin between Philippine Sea plate and Eurasian plate. This convergence results in two subductions north and south of Taiwan (Ryukyu and Manilla trenches, respectively), while the center is experiencing collision. These processes make Taiwan very active tectonically, as illustrated by numerous large earthquakes and rapid uplift of the Central Range. High slopes of Taiwan mountains and heavy rains brought by typhoons together lead to high landslides and mudflows risks. Practically, absolute gravity measurements have been yearly repeated since 2006 along a transect across south Taiwan, from Penghu to Lutao island, using FG5 absolute gravimeters. This transect contains ten sites for absolute measurements and has been densified in 2008 by incorporating 45 sites for relative gravity measurements with CG5 gravimeters. At the end of 2009, the relative gravity network will be densified again in its eastern part, i.e. in the Longitudinal Valley and the Central Range. A fourth set of absolute gravity measurements will also be performed at the same period. Most of the absolute sites have been measured with a good accuracy, about 1 or 2 μGal. Only the site located in Tainan University has higher standard deviation, due to the city noise. The stronger change in gravity reaches -7 μGal a -1 west of the Longitudinal Valley and might be explained by tectonic movement along a fault. A large decrease of -5 μGal a-1 is also measured in Tainan city and could be correlated with uplift of this region, also denoted by InSAR, leveling and GPS. Changes occurring in the Central Range are more difficult to interpret due to the small

  13. GNSS Absolute Antenna Calibration at the National Geodetic Survey

    NASA Astrophysics Data System (ADS)

    Mader, G. L.; Bilich, A. L.; Geoghegan, C.

    2011-12-01

    Geodetic GNSS applications routinely demand millimeter precision and extremely high levels of accuracy. To achieve these accuracies, measurement and instrument biases at the centimeter to millimeter level must be understood. One of these biases is the antenna phase center, the apparent point of signal reception for a GNSS antenna. It has been well established that phase center patterns differ between antenna models and manufacturers; additional research suggests that the addition of a radome or the choice of antenna mount can significantly alter those a priori phase center patterns. For the more demanding GNSS positioning applications and especially in cases of mixed-antenna networks, it is all the more important to know antenna phase center variations as a function of both elevation and azimuth in the antenna reference frame and incorporate these models into analysis software. To help meet the needs of the high-precision GNSS community, the National Geodetic Survey (NGS) now operates an absolute antenna calibration facility. Located in Corbin, Virginia, this facility uses field measurements and actual GNSS satellite signals to quantitatively determine the carrier phase advance/delay introduced by the antenna element. The NGS facility was built to serve traditional NGS constituents such as the surveying and geodesy communities, however calibration services are open and available to all GNSS users as the calibration schedule permits. All phase center patterns computed by this facility will be publicly available and disseminated in both the ANTEX and NGS formats. We describe the NGS calibration facility, and discuss the observation models and strategy currently used to generate NGS absolute calibrations. We demonstrate that NGS absolute phase center variation (PCV) patterns are consistent with published values determined by other absolute antenna calibration facilities, and compare absolute calibrations to the traditional NGS relative calibrations.

  14. Absolute Gravity Datum in the Age of Cold Atom Gravimeters

    NASA Astrophysics Data System (ADS)

    Childers, V. A.; Eckl, M. C.

    2014-12-01

    The international gravity datum is defined today by the International Gravity Standardization Net of 1971 (IGSN-71). The data supporting this network was measured in the 1950s and 60s using pendulum and spring-based gravimeter ties (plus some new ballistic absolute meters) to replace the prior protocol of referencing all gravity values to the earlier Potsdam value. Since this time, gravimeter technology has advanced significantly with the development and refinement of the FG-5 (the current standard of the industry) and again with the soon-to-be-available cold atom interferometric absolute gravimeters. This latest development is anticipated to provide improvement in the range of two orders of magnitude as compared to the measurement accuracy of technology utilized to develop ISGN-71. In this presentation, we will explore how the IGSN-71 might best be "modernized" given today's requirements and available instruments and resources. The National Geodetic Survey (NGS), along with other relevant US Government agencies, is concerned about establishing gravity control to establish and maintain high order geodetic networks as part of the nation's essential infrastructure. The need to modernize the nation's geodetic infrastructure was highlighted in "Precise Geodetic Infrastructure, National Requirements for a Shared Resource" National Academy of Science, 2010. The NGS mission, as dictated by Congress, is to establish and maintain the National Spatial Reference System, which includes gravity measurements. Absolute gravimeters measure the total gravity field directly and do not involve ties to other measurements. Periodic "intercomparisons" of multiple absolute gravimeters at reference gravity sites are used to constrain the behavior of the instruments to ensure that each would yield reasonably similar measurements of the same location (i.e. yield a sufficiently consistent datum when measured in disparate locales). New atomic interferometric gravimeters promise a significant

  15. Absolute magnitudes and phase coefficients of trans-Neptunian objects

    NASA Astrophysics Data System (ADS)

    Alvarez-Candal, A.; Pinilla-Alonso, N.; Ortiz, J. L.; Duffard, R.; Morales, N.; Santos-Sanz, P.; Thirouin, A.; Silva, J. S.

    2016-02-01

    Context. Accurate measurements of diameters of trans-Neptunian objects (TNOs) are extremely difficult to obtain. Thermal modeling can provide good results, but accurate absolute magnitudes are needed to constrain the thermal models and derive diameters and geometric albedos. The absolute magnitude, HV, is defined as the magnitude of the object reduced to unit helio- and geocentric distances and a zero solar phase angle and is determined using phase curves. Phase coefficients can also be obtained from phase curves. These are related to surface properties, but only few are known. Aims: Our objective is to measure accurate V-band absolute magnitudes and phase coefficients for a sample of TNOs, many of which have been observed and modeled within the program "TNOs are cool", which is one of the Herschel Space Observatory key projects. Methods: We observed 56 objects using the V and R filters. These data, along with those available in the literature, were used to obtain phase curves and measure V-band absolute magnitudes and phase coefficients by assuming a linear trend of the phase curves and considering a magnitude variability that is due to the rotational light-curve. Results: We obtained 237 new magnitudes for the 56 objects, six of which were without previously reported measurements. Including the data from the literature, we report a total of 110 absolute magnitudes with their respective phase coefficients. The average value of HV is 6.39, bracketed by a minimum of 14.60 and a maximum of -1.12. For the phase coefficients we report a median value of 0.10 mag per degree and a very large dispersion, ranging from -0.88 up to 1.35 mag per degree.

  16. Absolute determination of the neutron source yield using melamine as a neutron detector

    NASA Astrophysics Data System (ADS)

    Ciechanowski, M.; Bolewski, A., Jr.; Kreft, A.

    2015-01-01

    A new approach to absolute determination of the neutron source yield is presented. It bases on the application of melamine (C3H6N6) to neutron detection combined with Monte Carlo simulations of neutron transport. Melamine has the ability to detect neutrons via 14N(n, p)14C reaction and subsequent determination of 14C content. A cross section for this reaction is relatively high for thermal neutrons (1.827 b) and much lower for fast neutrons. A concentration of 14C nuclei created in the irradiated sample of melamine can be reliably measured with the aid of the accelerator mass spectrometry (AMS). The mass of melamine sufficient for this analysis is only 10 mg. Neutron detection is supported by Monte Carlo simulations of neutron transport carried out with the use of MCNP-4C code. These simulations are aimed at computing the probability of 14C creation in the melamine sample per the source neutron. The result of AMS measurements together with results of MCNP calculations enable us to determine the number of neutrons emitted from the source during the irradiation of melamine. The proposed method was applied for determining the neutron emission from a commercial 252Cf neutron source which was independently calibrated. The measured neutron emission agreed with the certified one within uncertainty limits. The relative expanded uncertainty (k=2) of the absolute neutron source yield determination was estimated at 2.6%. Apart from calibration of radionuclide neutron sources the proposed procedure could facilitate absolute yield measurements for more complex sources. Potential applications of this methodology as it is further developed include diagnostics of inertial confinement fusion and plasma-focus experiments, calibration of neutron measurement systems at tokamaks and accelerator-based neutron sources as well as characterization of neutron fields generated in large particle detectors during collisions of hadron beams.

  17. [Absolute bioavailability of a special sustained-release acetylsalicylic acid formulation].

    PubMed

    Lücker, P W; Swoboda, M; Wetzelsberger, N

    1989-03-01

    Absolute Bioavailability of a Special Acetylsalicylic Acid Sustained Release Formulation. The absolute bioavailability of an acetylsalicylic acid (ASA) sustained release formulation (Contrheuma retard), containing 300 mg ASA as initial dose and 350 mg in a retard formulation, was determined in comparison to a standard ASA solution for intravenous administration in a two-treatment, two-period cross-over trial with 6 healthy male volunteers by comparing the areas under the plasma-fluctuation-time curves of the primary metabolite. In addition, it was examined by comparison of the mean times after administration of both formulations, whether the test formulation meets the requirements of a sustained release formulation. The investigations led to the following results: The absolute bioavailability of the test formulation was 95%. The statistical comparison of the areas under the concentration-time courses allowed no decision (neither for equivalence nor difference). The maximal concentration of SA after intravenous administration of the standard formulation was reached after 0.4 h on an average and amounted to 62 micrograms/ml. After oral administration of the test formulation, a mean concentration maximum of 28 micrograms/ml was calculated, which had been reached after about 2 h. The differences are statistically significant. The mean time for SA was 6 h after the standard formulation, whereas after administration of the test compound, a mean of 11.5 h was calculated. 24 h following administration, the concentration of SA was 1.3 micrograms/ml after intravenous administration of the standard formulation and 5.5 micrograms/ml after administration of the test formulation. These differences, too, are statistically significant. From the comparison of the mean time for SA, a retard factor of 1.9 was calculated. PMID:2757664

  18. Absolute quantum cutting efficiency of Tb{sup 3+}-Yb{sup 3+} co-doped glass

    SciTech Connect

    Duan, Qianqian; Qin, Feng; Zhang, Zhiguo; Zhao, Hua; Cao, Wenwu

    2013-12-07

    The absolute quantum cutting efficiency of Tb{sup 3+}-Yb{sup 3+} co-doped glass was quantitatively measured by an integrating sphere detection system, which is independent of the excitation power. As the Yb{sup 3+} concentration increases, the near infrared quantum efficiency exhibited an exponential growth with an upper limit of 13.5%, but the visible light efficiency was reduced rapidly. As a result, the total quantum efficiency monotonically decreases rather than increases as theory predicted. In fact, the absolute quantum efficiency was far less than the theoretical value due to the low radiative efficiency of Tb{sup 3+} (<61%) and significant cross-relaxation nonradiative loss between Yb{sup 3+} ions.

  19. Normal incidence spectrophotometer using high density transmission grating technology and highly efficiency silicon photodiodes for absolute solar EUV irradiance measurements

    NASA Technical Reports Server (NTRS)

    Ogawa, H. S.; Mcmullin, D.; Judge, D. L.; Korde, R.

    1992-01-01

    New developments in transmission grating and photodiode technology now make it possible to realize spectrometers in the extreme ultraviolet (EUV) spectral region (wavelengths less than 1000 A) which are expected to be virtually constant in their diffraction and detector properties. Time dependent effects associated with reflection gratings are eliminated through the use of free standing transmission gratings. These gratings together with recently developed and highly stable EUV photodiodes have been utilized to construct a highly stable normal incidence spectrophotometer to monitor the variability and absolute intensity of the solar 304 A line. Owing to its low weight and compactness, such a spectrometer will be a valuable tool for providing absolute solar irradiance throughout the EUV. This novel instrument will also be useful for cross-calibrating other EUV flight instruments and will be flown on a series of Hitchhiker Shuttle Flights and on SOHO. A preliminary version of this instrument has been fabricated and characterized, and the results are described.

  20. Measuring the absolute deuterium-tritium neutron yield using the magnetic recoil spectrometer at OMEGA and the NIF.

    PubMed

    Casey, D T; Frenje, J A; Gatu Johnson, M; Séguin, F H; Li, C K; Petrasso, R D; Glebov, V Yu; Katz, J; Knauer, J P; Meyerhofer, D D; Sangster, T C; Bionta, R M; Bleuel, D L; Döppner, T; Glenzer, S; Hartouni, E; Hatchett, S P; Le Pape, S; Ma, T; MacKinnon, A; McKernan, M A; Moran, M; Moses, E; Park, H-S; Ralph, J; Remington, B A; Smalyuk, V; Yeamans, C B; Kline, J; Kyrala, G; Chandler, G A; Leeper, R J; Ruiz, C L; Cooper, G W; Nelson, A J; Fletcher, K; Kilkenny, J; Farrell, M; Jasion, D; Paguio, R

    2012-10-01

    A magnetic recoil spectrometer (MRS) has been installed and extensively used on OMEGA and the National Ignition Facility (NIF) for measurements of the absolute neutron spectrum from inertial confinement fusion implosions. From the neutron spectrum measured with the MRS, many critical implosion parameters are determined including the primary DT neutron yield, the ion temperature, and the down-scattered neutron yield. As the MRS detection efficiency is determined from first principles, the absolute DT neutron yield is obtained without cross-calibration to other techniques. The MRS primary DT neutron measurements at OMEGA and the NIF are shown to be in excellent agreement with previously established yield diagnostics on OMEGA, and with the newly commissioned nuclear activation diagnostics on the NIF. PMID:23126915

  1. Measuring the absolute deuterium-tritium neutron yield using the magnetic recoil spectrometer at OMEGA and the NIF

    SciTech Connect

    Casey, D. T.; Frenje, J. A.; Gatu Johnson, M.; Seguin, F. H.; Li, C. K.; Petrasso, R. D.; Glebov, V. Yu.; Katz, J.; Knauer, J. P.; Meyerhofer, D. D.; Sangster, T. C.; Bionta, R. M.; Bleuel, D. L.; Doeppner, T.; Glenzer, S.; Hartouni, E.; Hatchett, S. P.; Le Pape, S.; Ma, T.; MacKinnon, A.; and others

    2012-10-15

    A magnetic recoil spectrometer (MRS) has been installed and extensively used on OMEGA and the National Ignition Facility (NIF) for measurements of the absolute neutron spectrum from inertial confinement fusion implosions. From the neutron spectrum measured with the MRS, many critical implosion parameters are determined including the primary DT neutron yield, the ion temperature, and the down-scattered neutron yield. As the MRS detection efficiency is determined from first principles, the absolute DT neutron yield is obtained without cross-calibration to other techniques. The MRS primary DT neutron measurements at OMEGA and the NIF are shown to be in excellent agreement with previously established yield diagnostics on OMEGA, and with the newly commissioned nuclear activation diagnostics on the NIF.

  2. Absolute density measurement of SD radicals in a supersonic jet at the quantum-noise-limit.

    PubMed

    Mizouri, Arin; Deng, L Z; Eardley, Jack S; Nahler, N Hendrik; Wrede, Eckart; Carty, David

    2013-12-01

    The absolute density of SD radicals in a supersonic jet has been measured down to (1.1 ± 0.1) × 10(5) cm(-3) in a modestly specified apparatus that uses a cross-correlated combination of cavity ring-down and laser-induced fluorescence detection. Such a density corresponds to 215 ± 21 molecules in the probe volume at any given time. The minimum detectable absorption coefficient was quantum-noise-limited and measured to be (7.9 ± 0.6) × 10(-11) cm(-1), in 200 s of acquisition time, corresponding to a noise-equivalent absorption sensitivity for the apparatus of (1.6 ± 0.1) × 10(-9) cm(-1) Hz(-1/2). PMID:24145480

  3. Absolute diode laser-based in situ detection of HCl in gasification processes

    NASA Astrophysics Data System (ADS)

    Ortwein, P.; Woiwode, W.; Fleck, S.; Eberhard, M.; Kolb, T.; Wagner, S.; Gisi, M.; Ebert, V.

    2010-10-01

    The release of HCl is an important parameter for industrial combustion and gasification processes, which must be determined in the ppm range for active process control and optimization. Based on a low power vertical-cavity surface-emitting laser (VCSEL) at 1.74 μm, we developed a new tuneable diode laser absorption spectrometer for calibration-free, absolute in situ HCl detection using the H35Cl (2 ← 0) R(3) absorption line with minimized cross-sensitivity to CO2 and H2O. The spectrometer was applied to in situ measurements in a gasification process ( T = 1,130°C, P = 1 atm, L = 28 cm) and yielded an optical resolution of 2.3·10-4, i.e. a HCl sensitivity of 45 ppm (13 ppm·m).

  4. Minimum mean absolute error estimation over the class of generalized stack filters

    NASA Astrophysics Data System (ADS)

    Lin, Jean-Hsang; Coyle, Edward J.

    1990-04-01

    A class of sliding window operators called generalized stack filters is developed. This class of filters, which includes all rank order filters, stack filters, and digital morphological filters, is the set of all filters possessing the threshold decomposition architecture and a consistency property called the stacking property. Conditions under which these filters possess the weak superposition property known as threshold decomposition are determined. An algorithm is provided for determining a generalized stack filter which minimizes the mean absolute error (MAE) between the output of the filter and a desired input signal, given noisy observations of that signal. The algorithm is a linear program whose complexity depends on the window width of the filter and the number of threshold levels observed by each of the filters in the superposition architecture. The results show that choosing the generalized stack filter which minimizes the MAE is equivalent to massively parallel threshold-crossing decision making when the decisions are consistent with each other.

  5. SO_2 Absorption Cross Sections and N_2 VUV Oscillator Strengths for Planetary Atmosphere Studies

    NASA Astrophysics Data System (ADS)

    Smith, Peter L.; Stark, G.; Rufus, J.; Pickering, J. C.; Cox, G.; Huber, K. P.

    1998-09-01

    The determination of the chemical composition of the atmosphere of Io from Hubble Space Telescope observations in the 190-220 nm wavelength region requires knowledge of the photoabsorption cross sections of SO_2 at temperatures ranging from about 110 K to 300 K. We are engaged in a laboratory program to measure SO_2 absorption cross sections with very high resolving power (lambda /delta lambda =~ 450,000) and at a range of temperatures appropriate to the Io atmosphere. Previous photoabsorption measurements, with lambda /delta lambda =~ 100,000, have been unable to resolve the very congested SO_2 spectrum, and, thus, to elucidate the temperature dependence of the cross sections. Our measurements are being performed at Imperial College, London, using an ultraviolet Fourier transform spectrometer. We will present our recently completed room temperature measurements of SO_2 cross sections in the 190-220 nm region and plans for extending these to ~ 195 K. Analyses of Voyager VUV occultation measurements of the N_2-rich atmospheres of Titan and Triton have been hampered by the lack of fundamental spectroscopic data for N_2, in particular, by the lack of reliable f-values and line widths for electronic bands of N_2 in the 80-100 nm wavelength region. We are continuing our program of measurements of band oscillator strengths for the many (approximately 100) N_2 bands between 80 and 100 nm. We report new f-values, derived from data obtained at the Photon Factory (Tsukuba, Japan) synchrotron radiation facility with lambda /delta lambda =~ 130,000, of 37 bands in the 80-86 nm region and 21 bands in the 90-95 nm region. We have also begun the compilation of a searchable archive of N_2 data on the World Wide Web; see http://cfa-www.harvard. edu/amp/data/n2/n2home.html. The archive, covering the spectroscopy of N_2 between 80 and 100 nm, will include published and unpublished (14) N_2, (14) N(15) N, and (15) N_2 line lists and spectroscopic identifications, excited state energy

  6. On the role of spatial position of bridged oxygen atoms as surface passivants on the ground-state gap and photo-absorption spectrum of silicon nano-crystals

    SciTech Connect

    Nazemi, Sanaz; Soleimani, Ebrahim Asl; Pourfath, Mahdi E-mail: pourfath@iue.tuwien.ac.at

    2015-11-28

    Silicon nano-crystals (NCs) are potential candidates for enhancing and tuning optical properties of silicon for optoelectronic and photo-voltaic applications. Due to the high surface-to-volume ratio, however, optical properties of NC result from the interplay of quantum confinement and surface effects. In this work, we show that both the spatial position of surface terminants and their relative positions have strong effects on NC properties as well. This is accomplished by investigating the ground-state HOMO-LUMO band-gap, the photo-absorption spectra, and the localization and overlap of HOMO and LUMO orbital densities for prototype ∼1.2 nm Si{sub 32–x}H{sub 42–2x}O{sub x} hydrogenated silicon NC with bridged oxygen atoms as surface terminations. It is demonstrated that the surface passivation geometry significantly alters the localization center and thus the overlap of frontier molecular orbitals, which correspondingly modifies the electronic and optical properties of NC.

  7. Absolute charge calibration of scintillating screens for relativistic electron detection

    SciTech Connect

    Buck, A.; Popp, A.; Schmid, K.; Karsch, S.; Krausz, F.; Zeil, K.; Jochmann, A.; Kraft, S. D.; Sauerbrey, R.; Cowan, T.; Schramm, U.; Hidding, B.; Kudyakov, T.; Sears, C. M. S.; Veisz, L.; Pawelke, J.

    2010-03-15

    We report on new charge calibrations and linearity tests with high-dynamic range for eight different scintillating screens typically used for the detection of relativistic electrons from laser-plasma based acceleration schemes. The absolute charge calibration was done with picosecond electron bunches at the ELBE linear accelerator in Dresden. The lower detection limit in our setup for the most sensitive scintillating screen (KODAK Biomax MS) was 10 fC/mm{sup 2}. The screens showed a linear photon-to-charge dependency over several orders of magnitude. An onset of saturation effects starting around 10-100 pC/mm{sup 2} was found for some of the screens. Additionally, a constant light source was employed as a luminosity reference to simplify the transfer of a one-time absolute calibration to different experimental setups.

  8. Absolute calibration for a broad range single shot electron spectrometer

    SciTech Connect

    Glinec, Y.; Faure, J.; Guemnie-Tafo, A.; Malka, V.; Monard, H.; Larbre, J. P.; De Waele, V.; Marignier, J. L.; Mostafavi, M.

    2006-10-15

    This article gives a detailed description of a single shot electron spectrometer which was used to characterize electron beams produced by laser-plasma interaction. Contrary to conventional electron sources, electron beams from laser-plasma accelerators can produce a broad range of energies. Therefore, diagnosing these electron spectra requires specific attention and experimental development. Here, we provide an absolute calibration of the Lanex Kodak Fine screen on a laser-triggered radio frequency picosecond electron accelerator. The efficiency of scintillating screens irradiated by electron beams has never been investigated so far. This absolute calibration is then compared to charge measurements from an integrating current transformer for quasimonoenergetic electron spectra from laser-plasma interaction.

  9. Absolute charge calibration of scintillating screens for relativistic electron detection

    NASA Astrophysics Data System (ADS)

    Buck, A.; Zeil, K.; Popp, A.; Schmid, K.; Jochmann, A.; Kraft, S. D.; Hidding, B.; Kudyakov, T.; Sears, C. M. S.; Veisz, L.; Karsch, S.; Pawelke, J.; Sauerbrey, R.; Cowan, T.; Krausz, F.; Schramm, U.

    2010-03-01

    We report on new charge calibrations and linearity tests with high-dynamic range for eight different scintillating screens typically used for the detection of relativistic electrons from laser-plasma based acceleration schemes. The absolute charge calibration was done with picosecond electron bunches at the ELBE linear accelerator in Dresden. The lower detection limit in our setup for the most sensitive scintillating screen (KODAK Biomax MS) was 10 fC/mm2. The screens showed a linear photon-to-charge dependency over several orders of magnitude. An onset of saturation effects starting around 10-100 pC/mm2 was found for some of the screens. Additionally, a constant light source was employed as a luminosity reference to simplify the transfer of a one-time absolute calibration to different experimental setups.

  10. From Hubble's Next Generation Spectral Library (NGSL) to Absolute Fluxes

    NASA Astrophysics Data System (ADS)

    Heap, S. R.; Lindler, D.

    2016-05-01

    Hubble's Next Generation Spectral Library (NGSL) consists of R˜1000 spectra of 374 stars of assorted temperature, gravity, and metallicity. Each spectrum covers the wavelength range, 0.18–1.03 μ. The library can be viewed and/or downloaded from the website, http://archive.stsci.edu/prepds/stisngsl/. Stars in the NGSL are now being used as absolute flux standards at ground-based observatories. However, the uncertainty in the absolute flux is about 2%, which does not meet the requirements of dark-energy surveys. We have therefore developed an observing procedure, data-reduction procedure, and correction algorithms that should yield fluxes with uncertainties less than 1%.

  11. Determination of absolute internal conversion coefficients using the SAGE spectrometer

    NASA Astrophysics Data System (ADS)

    Sorri, J.; Greenlees, P. T.; Papadakis, P.; Konki, J.; Cox, D. M.; Auranen, K.; Partanen, J.; Sandzelius, M.; Pakarinen, J.; Rahkila, P.; Uusitalo, J.; Herzberg, R.-D.; Smallcombe, J.; Davies, P. J.; Barton, C. J.; Jenkins, D. G.

    2016-03-01

    A non-reference based method to determine internal conversion coefficients using the SAGE spectrometer is carried out for transitions in the nuclei of 154Sm, 152Sm and 166Yb. The Normalised-Peak-to-Gamma method is in general an efficient tool to extract internal conversion coefficients. However, in many cases the required well-known reference transitions are not available. The data analysis steps required to determine absolute internal conversion coefficients with the SAGE spectrometer are presented. In addition, several background suppression methods are introduced and an example of how ancillary detectors can be used to select specific reaction products is given. The results obtained for ground-state band E2 transitions show that the absolute internal conversion coefficients can be extracted using the methods described with a reasonable accuracy. In some cases of less intense transitions only an upper limit for the internal conversion coefficient could be given.

  12. Absolute magnitude calibration using trigonometric parallax - Incomplete, spectroscopic samples

    NASA Technical Reports Server (NTRS)

    Ratnatunga, Kavan U.; Casertano, Stefano

    1991-01-01

    A new numerical algorithm is used to calibrate the absolute magnitude of spectroscopically selected stars from their observed trigonometric parallax. This procedure, based on maximum-likelihood estimation, can retrieve unbiased estimates of the intrinsic absolute magnitude and its dispersion even from incomplete samples suffering from selection biases in apparent magnitude and color. It can also make full use of low accuracy and negative parallaxes and incorporate censorship on reported parallax values. Accurate error estimates are derived for each of the fitted parameters. The algorithm allows an a posteriori check of whether the fitted model gives a good representation of the observations. The procedure is described in general and applied to both real and simulated data.

  13. In-flight Absolute Radiometric Calibration of the Thematic Mapper

    NASA Technical Reports Server (NTRS)

    Castle, K. R.; Holm, R. G.; Kastner, C. J.; Palmer, J. M.; Slater, P. N.; Dinguirard, M.; Ezra, C. E.; Jackson, D.; Savage, R. K.

    1984-01-01

    The Thematic Mapper (TM) multispectral scanner system was placed into Earth orbit on July 16, 1982, as part of NASA's LANDSAT 4 payload. To determine temporal changes of the absolute radiometric calibration of the entire system in flight, spectroradiometric measurements of the ground and the atmosphere are made simultaneously with TM image acquisitions over the White Sands, New Mexico area. By entering the measured values into an atmospheric radiative transfer program, the radiance levels at the entrance pupil of the TM in four of the TM spectral bands are determined. These levels are compared to the output digital counts from the detectors that sampled the radiometrically measured ground area, thus providing an absolute radiometric calibration of the entire TM system utilizing those detectors. By reference to an adjacent, larger uniform area, the calibration is extended to all 16 detectors in each of the three bands.

  14. Absolute measurement of the extreme UV solar flux

    NASA Technical Reports Server (NTRS)

    Carlson, R. W.; Ogawa, H. S.; Judge, D. L.; Phillips, E.

    1984-01-01

    A windowless rare-gas ionization chamber has been developed to measure the absolute value of the solar extreme UV flux in the 50-575-A region. Successful results were obtained on a solar-pointing sounding rocket. The ionization chamber, operated in total absorption, is an inherently stable absolute detector of ionizing UV radiation and was designed to be independent of effects from secondary ionization and gas effusion. The net error of the measurement is + or - 7.3 percent, which is primarily due to residual outgassing in the instrument, other errors such as multiple ionization, photoelectron collection, and extrapolation to the zero atmospheric optical depth being small in comparison. For the day of the flight, Aug. 10, 1982, the solar irradiance (50-575 A), normalized to unit solar distance, was found to be 5.71 + or - 0.42 x 10 to the 10th photons per sq cm sec.

  15. In-flight absolute radiometric calibration of the thematic mapper

    NASA Technical Reports Server (NTRS)

    Castle, K. R.; Holm, R. G.; Kastner, C. J.; Palmer, J. M.; Slater, P. N.; Dinguirard, M.; Ezra, C. E.; Jackson, R. D.; Savage, R. K.

    1984-01-01

    In order to determine temporal changes of the absolute radiometric calibration of the entire TM system in flight spectroradiometric measurements of the ground and the atmosphere were made simultaneously with TM image collections over the White Sands, New Mexico area. By entering the measured values in an atmospheric radiative transfer program, the radiance levels in four of the spectral bands of the TM were determined, band 1:0.45 to 0.52 micrometers, band 2:0.53 to 0.61 micrometers band 3:0.62 to 0.70 micrometers and 4:0.78 to 0.91 micrometers. These levels were compared to the output digital counts from the detectors that sampled the radiometrically measured ground area, thus providing an absolute radiometric calibration of the entire TM system utilizing those detectors.

  16. In-flight absolute radiometric calibration of the Thematic Mapper

    NASA Technical Reports Server (NTRS)

    Castle, K. R.; Holm, R. G.; Kastner, C. J.; Palmer, J. M.; Slater, P. N.; Dinguirard, M.; Ezra, C. E.; Jackson, R. D.; Savage, R. K.

    1984-01-01

    In order to determine temporal changes of the absolute radiometric calibration of the entire TM system in flight spectroradiometric measurements of the ground and the atmosphere were made simultaneously with TM image collections over the White Sands, NM area. By entering the measured values in an atmospheric radiative transfer program, the radiance levels in four of the spectral bands of the TM were determined, band 1: 0.45 to 0.52 micrometers, band 2: 0.53 to 0.61 micrometers, band 3: 0.62 to 0.70 micrometers, and 4: 0.78 to 0.91 micrometers. These levels were compared to the output digital counts from the detectors that sampled the radiometrically measured ground area, thus providing an absolute radiometric calibration of the entire TM system utilizing those detectors. Previously announced in STAR as N84-15633

  17. Absolute calibration of vacuum ultraviolet spectrograph system for plasma diagnostics

    SciTech Connect

    Yoshikawa, M.; Kubota, Y.; Kobayashi, T.; Saito, M.; Numada, N.; Nakashima, Y.; Cho, T.; Koguchi, H.; Yagi, Y.; Yamaguchi, N.

    2004-10-01

    A space- and time-resolving vacuum ultraviolet (VUV) spectrograph system has been applied to diagnose impurity ions behavior in plasmas produced in the tandem mirror GAMMA 10 and the reversed field pinch TPE-RX. We have carried out ray tracing calculations for obtaining the characteristics of the VUV spectrograph and calibration experiments to measure the absolute sensitivities of the VUV spectrograph system for the wavelength range from 100 to 1100 A. By changing the incident angle, 50.6 deg. -51.4 deg., to the spectrograph whose nominal incident angle is 51 deg., we can change the observing spectral range of the VUV spectrograph. In this article, we show the ray tracing calculation results and absolute sensitivities when the angle of incidence into the VUV spectrograph is changed, and the results of VUV spectroscopic measurement in both GAMMA 10 and TPE-RX plasmas.

  18. Absolute Configurations of Zingiberenols Isolated from Ginger (Zingiber officinale) Rhizomes.

    PubMed

    Khrimian, Ashot; Shirali, Shyam; Guzman, Filadelfo

    2015-12-24

    Two stereoisomeric zingiberenols in ginger were identified as (3R,6R,7S)-1,10-bisaboladien-3-ol (2) and (3S,6R,7S)-1,10-bisaboladien-3-ol (5). Absolute configurations were assigned by utilizing 1,10-bisaboladien-3-ol stereoisomers and two gas-chromatography columns: a 25 m Hydrodex-β-6TBDM and 60 m DB-5MS. The C-6 and C-7 absolute configurations in both zingiberenols match those of zingiberene present abundantly in ginger rhizomes. Interestingly, zingiberenol 2 has recently been identified as a male-produced sex pheromone of the rice stink bug, Oebalus poecilus, thus indicating that ginger plants may be a potential source of the sex pheromone of this bug. PMID:26606508

  19. Absolute limit on rotation of gravitationally bound stars

    SciTech Connect

    Glendenning, N.K.

    1994-03-01

    The authors seek an absolute limit on the rotational period for a neutron star as a function of its mass, based on the minimal constraints imposed by Einstein`s theory of relativity, Le Chatelier`s principle, causality and a low-density equation of state, uncertainties which can be evaluated as to their effect on the result. This establishes a limiting curve in the mass-period plane below which no pulsar that is a neutron star can lie. For example, the minimum possible Kepler period, which is an absolute limit on rotation below which mass-shedding would occur, is 0.33 ms for a M = 1.442 M{circle_dot} neutron star (the mass of PSR1913+16). If the limit were found to be broken by any pulsar, it would signal that the confined hadronic phase of ordinary nucleons and nuclei is only metastable, an extraordinary conclusion.

  20. Validation of GOCE by absolute and relative gravimetry

    NASA Astrophysics Data System (ADS)

    Pettersen, B. R.; Sprlak, M.; Lysaker, D. I.; Omang, O. C. D.; Sekowski, M.; Dykowski, P.

    2012-04-01

    Absolute gravimetry has been performed in 2011 by FG5 and A10 instruments in selected sites of the Norwegian first order gravity network. These observations are used as reference values to transform a large number of relative gravity values collected in 1968-1972. The outcome is a database at current epoch in a reference frame defined by the absolute gravity values. This constitutes our test field for validation of GOCE results. In the test fields, validation of GOCE-derived gravity anomalies was performed. The spectral enhancement method was applied to avoid the spectral inconsistency between the terrestrial and the satellite data. For this purpose, contributions of the EGM2008 model and a gravitational effect of a residual terrain model were calculated.

  1. Proposal for an absolute, atomic definition of mass

    NASA Astrophysics Data System (ADS)

    Wignall, J. W. G.

    1991-11-01

    It is proposed that the mass of a particle be defined absolutely as its de Broglie frequency, measured as the mean de Broglie wavelength of the particle when it has a mean speed (v) and Lorentz factor (gamma); the masses of systems too large to have a measurable de Broglie wavelength mean are then to be derived by specifying the usual inertial and additive properties of mass. This definition avoids the use of an arbitrary macroscopic standard such as the prototype kilogram, and, if present theory is correct, does not even require the choice of a specific particle as a mass standard. Suggestions are made as to how this absolute mass can be realized and measured at the macroscopic level and, finally, some comments are made on the effect of the new definition on the form of the equations of physics.

  2. Absolute phase effects on CPMG-type pulse sequences

    NASA Astrophysics Data System (ADS)

    Mandal, Soumyajit; Oh, Sangwon; Hürlimann, Martin D.

    2015-12-01

    We describe and analyze the effects of transients within radio-frequency (RF) pulses on multiple-pulse NMR measurements such as the well-known Carr-Purcell-Meiboom-Gill (CPMG) sequence. These transients are functions of the absolute RF phases at the beginning and end of the pulse, and are thus affected by the timing of the pulse sequence with respect to the period of the RF waveform. Changes in transients between refocusing pulses in CPMG-type sequences can result in signal decay, persistent oscillations, changes in echo shape, and other effects. We have explored such effects by performing experiments in two different low-frequency NMR systems. The first uses a conventional tuned-and-matched probe circuit, while the second uses an ultra-broadband un-tuned or non-resonant probe circuit. We show that there are distinct differences between the absolute phase effects in these two systems, and present simple models that explain these differences.

  3. Henry More and the development of absolute time.

    PubMed

    Thomas, Emily

    2015-12-01

    This paper explores the nature, development and influence of the first English account of absolute time, put forward in the mid-seventeenth century by the 'Cambridge Platonist' Henry More. Against claims in the literature that More does not have an account of time, this paper sets out More's evolving account and shows that it reveals the lasting influence of Plotinus. Further, this paper argues that More developed his views on time in response to his adoption of Descartes' vortex cosmology and cosmogony, providing new evidence of More's wider project to absorb Cartesian natural philosophy into his Platonic metaphysics. Finally, this paper argues that More should be added to the list of sources that later English thinkers - including Newton and Samuel Clarke - drew on in constructing their absolute accounts of time. PMID:26568082

  4. Improved Absolute Approximation Ratios for Two-Dimensional Packing Problems

    NASA Astrophysics Data System (ADS)

    Harren, Rolf; van Stee, Rob

    We consider the two-dimensional bin packing and strip packing problem, where a list of rectangles has to be packed into a minimal number of rectangular bins or a strip of minimal height, respectively. All packings have to be non-overlapping and orthogonal, i.e., axis-parallel. Our algorithm for strip packing has an absolute approximation ratio of 1.9396 and is the first algorithm to break the approximation ratio of 2 which was established more than a decade ago. Moreover, we present a polynomial time approximation scheme (mathcal{PTAS}) for strip packing where rotations by 90 degrees are permitted and an algorithm for two-dimensional bin packing with an absolute worst-case ratio of 2, which is optimal provided mathcal{P} not= mathcal{NP}.

  5. Flow rate calibration for absolute cell counting rationale and design.

    PubMed

    Walker, Clare; Barnett, David

    2006-05-01

    There is a need for absolute leukocyte enumeration in the clinical setting, and accurate, reliable (and affordable) technology to determine absolute leukocyte counts has been developed. Such technology includes single platform and dual platform approaches. Derivations of these counts commonly incorporate the addition of a known number of latex microsphere beads to a blood sample, although it has been suggested that the addition of beads to a sample may only be required to act as an internal quality control procedure for assessing the pipetting error. This unit provides the technical details for undertaking flow rate calibration that obviates the need to add reference beads to each sample. It is envisaged that this report will provide the basis for subsequent clinical evaluations of this novel approach. PMID:18770842

  6. Enumeration of absolute cell counts using immunophenotypic techniques.

    PubMed

    Mandy, F; Brando, B

    2001-05-01

    Absolute counting of cells or cell subsets has a number of significant clinical applications: monitoring the disease status of HIV-infected patients, enumerating residual white blood cells in leukoreduced blood products, and assessing immunodeficiency in a variety of situations. The single-platform method (flow cytometry alone) has emerged as the method of choice for absolute cell enumeration. This technology counts only the cells of interest in a precisely determined blood volume. Exact cell identification is accomplished by a logical electronic gating algorithm capable of identifying lineage-specific immunofluorescent markers. Exclusion of unwanted cells is automatic. This extensive and detailed unit presents protocols for both volumetric and flow-rate determination of residual white blood cells and of leukocyte subsets. PMID:18770719

  7. Absolute calibration for a broad range single shot electron spectrometer

    NASA Astrophysics Data System (ADS)

    Glinec, Y.; Faure, J.; Guemnie-Tafo, A.; Malka, V.; Monard, H.; Larbre, J. P.; De Waele, V.; Marignier, J. L.; Mostafavi, M.

    2006-10-01

    This article gives a detailed description of a single shot electron spectrometer which was used to characterize electron beams produced by laser-plasma interaction. Contrary to conventional electron sources, electron beams from laser-plasma accelerators can produce a broad range of energies. Therefore, diagnosing these electron spectra requires specific attention and experimental development. Here, we provide an absolute calibration of the Lanex Kodak Fine screen on a laser-triggered radio frequency picosecond electron accelerator. The efficiency of scintillating screens irradiated by electron beams has never been investigated so far. This absolute calibration is then compared to charge measurements from an integrating current transformer for quasimonoenergetic electron spectra from laser-plasma interaction.

  8. Absolute GNSS Antenna Calibration at the National Geodetic Survey

    NASA Astrophysics Data System (ADS)

    Mader, G.; Bilich, A.; Geoghegan, C.

    2012-04-01

    Geodetic GNSS applications routinely demand millimeter precision and extremely high levels of accuracy. To achieve these accuracies, measurement and instrument biases at the centimeter to millimeter level must be understood. One of these biases is the antenna phase center, the apparent point of signal reception for a GNSS antenna. It has been well established that phase center patterns differ between antenna models and manufacturers; additional research suggests that the addition of a radome or the choice of antenna mount can significantly alter those a priori phase center patterns. For the more demanding GNSS positioning applications and especially in cases of mixed-antenna networks, it is all the more important to know antenna phase center variations as a function of both elevation and azimuth in the antenna reference frame and incorporate these models into analysis software. To help meet the needs of the high-precision GNSS community, the National Geodetic Survey (NGS) now operates an absolute antenna calibration facility. Located in Corbin, Virginia, this facility uses field measurements and actual GNSS satellite signals to quantitatively determine the carrier phase advance/delay introduced by the antenna element. The NGS facility was built to serve traditional NGS constituents such as the surveying and geodesy communities, however calibration services are open and available to all GNSS users as the calibration schedule permits. All phase center patterns computed by this facility will be publicly available and disseminated in both the ANTEX and NGS formats. We describe the NGS calibration facility, and discuss the observation models and strategy currently used to generate NGS absolute calibrations. We demonstrate that NGS absolute phase center variation (PCV) patterns are consistent with published values determined by other absolute antenna calibration facilities, and outline future planned refinements to the system.

  9. Engine performance and the determination of absolute ceiling

    NASA Technical Reports Server (NTRS)

    Diehl, Walter S

    1924-01-01

    This report contains a brief study of the variation of engine power with temperature and pressure. The variation of propeller efficiency in standard atmosphere is obtained from the general efficiency curve which is developed in NACA report no. 168. The variation of both power available and power required are then determined and curves plotted, so that the absolute ceiling may be read directly from any known sea-level value of the ratio of power available to power required.

  10. On the Absolute Continuity of the Blackwell Measure

    NASA Astrophysics Data System (ADS)

    Bárány, Balázs; Kolossváry, István

    2015-04-01

    In 1957, Blackwell expressed the entropy of hidden Markov chains using a measure which can be characterised as an invariant measure for an iterated function system with place-dependent weights. This measure, called the Blackwell measure, plays a central role in understanding the entropy rate and other important characteristics of fundamental models in information theory. We show that for a suitable set of parameter values the Blackwell measure is absolutely continuous for almost every parameter in the case of binary symmetric channels.

  11. Electroweak absolute, meta-, and thermal stability in neutrino mass models

    NASA Astrophysics Data System (ADS)

    Lindner, Manfred; Patel, Hiren H.; Radovčić, Branimir

    2016-04-01

    We analyze the stability of the electroweak vacuum in neutrino mass models containing right-handed neutrinos or fermionic isotriplets. In addition to considering absolute stability, we place limits on the Yukawa couplings of new fermions based on metastability and thermal stability in the early Universe. Our results reveal that the upper limits on the neutrino Yukawa couplings can change significantly when the top quark mass is allowed to vary within the experimental range of uncertainty in its determination.

  12. Successful treatment of pyogenic granuloma with injection of absolute ethanol.

    PubMed

    Ichimiya, Makoto; Yoshikawa, Yoshiaki; Hamamoto, Yoshiaki; Muto, Masahiko

    2004-04-01

    Pyogenic granuloma (PG) is a small, almost always solitary, sessile or pedunculated, raspberry-like vegetation of exuberant granulation tissue. Conservative treatment by techniques such as cryosurgery, laser surgery, and electrodesiccation are usually adequate, whereas excisional treatment can often result in noticeable scars. We attempted a different approach using an injection of absolute ethanol in five patients with recurrence due to inadequate cryosurgery. This therapy is less invasive than surgical excision and appears to be an alternative therapy for PG. PMID:15187331

  13. Diagnostic Application of Absolute Neutron Activation Analysis in Hematology

    SciTech Connect

    Zamboni, C.B.; Oliveira, L.C.; Dalaqua, L. Jr.

    2004-10-03

    The Absolute Neutron Activation Analysis (ANAA) technique was used to determine element concentrations of Cl and Na in blood of healthy group (male and female blood donators), select from Blood Banks at Sao Paulo city, to provide information which can help in diagnosis of patients. This study permitted to perform a discussion about the advantages and limitations of using this nuclear methodology in hematological examinations.

  14. Absolute intensity of radiation emitted by uranium plasmas

    NASA Technical Reports Server (NTRS)

    Jalufka, N. W.; Lee, J. H.; Mcfarland, D. R.

    1975-01-01

    The absolute intensity of radiation emitted by fissioning and nonfissioning uranium plasmas in the spectral range from 350 nm to 1000 nm was measured. The plasma was produced in a plasma-focus apparatus and the plasma properties are simular to those anticipated for plasma-core nuclear reactors. The results are expected to contribute to the establishment of design criteria for the development of plasma-core reactors.

  15. THE ABSOLUTE MAGNITUDES OF TYPE Ia SUPERNOVAE IN THE ULTRAVIOLET

    SciTech Connect

    Brown, Peter J.; Roming, Peter W. A.; Ciardullo, Robin; Gronwall, Caryl; Hoversten, Erik A.; Pritchard, Tyler; Milne, Peter; Bufano, Filomena; Mazzali, Paolo; Elias-Rosa, Nancy; Filippenko, Alexei V.; Li Weidong; Foley, Ryan J.; Hicken, Malcolm; Kirshner, Robert P.; Gehrels, Neil; Holland, Stephen T.; Immler, Stefan; Phillips, Mark M.; Still, Martin

    2010-10-01

    We examine the absolute magnitudes and light-curve shapes of 14 nearby (redshift z = 0.004-0.027) Type Ia supernovae (SNe Ia) observed in the ultraviolet (UV) with the Swift Ultraviolet/Optical Telescope. Colors and absolute magnitudes are calculated using both a standard Milky Way extinction law and one for the Large Magellanic Cloud that has been modified by circumstellar scattering. We find very different behavior in the near-UV filters (uvw1{sub rc} covering {approx}2600-3300 A after removing optical light, and u {approx} 3000-4000 A) compared to a mid-UV filter (uvm2 {approx}2000-2400 A). The uvw1{sub rc} - b colors show a scatter of {approx}0.3 mag while uvm2-b scatters by nearly 0.9 mag. Similarly, while the scatter in colors between neighboring filters is small in the optical and somewhat larger in the near-UV, the large scatter in the uvm2 - uvw1 colors implies significantly larger spectral variability below 2600 A. We find that in the near-UV the absolute magnitudes at peak brightness of normal SNe Ia in our sample are correlated with the optical decay rate with a scatter of 0.4 mag, comparable to that found for the optical in our sample. However, in the mid-UV the scatter is larger, {approx}1 mag, possibly indicating differences in metallicity. We find no strong correlation between either the UV light-curve shapes or the UV colors and the UV absolute magnitudes. With larger samples, the UV luminosity might be useful as an additional constraint to help determine distance, extinction, and metallicity in order to improve the utility of SNe Ia as standardized candles.

  16. Absolute partial decay branching-ratios in 16O

    NASA Astrophysics Data System (ADS)

    Wheldon, C.; Ashwood, N. I.; Barr, M.; Curtis, N.; Freer, M.; Kokalova, Tz; Malcolm, J. D.; Spencer, S. J.; Ziman, V. A.; Faestermann, Th; Krücken, R.; Wirth, H.-F.; Hertenberger, R.; Lutter, R.; Bergmaier, A.

    2013-04-01

    The a-transfer reaction 126C(63Li, d)168O* has been performed at a 6Li bombarding energy of 42 MeV to populate excited states in 13C and 16O. Absolute branching ratios have been unambiguously determined for states in the excitation energy range 13.85 to 15.87 MeV and reduced widths are extracted.

  17. The Electromotive Series and Other Non-Absolute Scales

    NASA Astrophysics Data System (ADS)

    Peckham, Gavin D.

    1998-01-01

    This article describes an analogy which may be used to illustrate the principles that underlie the establishment of non-absolute scales of measurements that are evaluated relative to a chosen reference point. The analogy is interwoven with the establishment of the electromotive series, but may be extended to other parameters such as the Celsius and Fahrenheit temperature scales, potential energies, formation and reaction enthalpies, etc.

  18. On the Absolutely Continuous Spectrum of Stark Operators

    NASA Astrophysics Data System (ADS)

    Perelman, Galina

    The stability of the absolutely continuous spectrum of the one-dimensional Stark operator under perturbations of the potential is discussed. The focus is on proving this stability under minimal assumptions on smoothness of the perturbation. A general criterion is presented together with some applications. These include the case of periodic perturbations where we show that any perturbation vL1()∩H-1/2() preserves the a.c. spectrum.

  19. Horizontal Cross Bracing Detail, Vertical Cross Bracing Detail, Horizontal Cross ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    Horizontal Cross Bracing Detail, Vertical Cross Bracing Detail, Horizontal Cross Bracing Joint, Vertical Cross Bracing End Detail - Ceylon Covered Bridge, Limberlost Park, spanning Wabash River at County Road 900 South, Geneva, Adams County, IN

  20. Overspecification of color, pattern, and size: salience, absoluteness, and consistency

    PubMed Central

    Tarenskeen, Sammie; Broersma, Mirjam; Geurts, Bart

    2015-01-01

    The rates of overspecification of color, pattern, and size are compared, to investigate how salience and absoluteness contribute to the production of overspecification. Color and pattern are absolute and salient attributes, whereas size is relative and less salient. Additionally, a tendency toward consistent responses is assessed. Using a within-participants design, we find similar rates of color and pattern overspecification, which are both higher than the rate of size overspecification. Using a between-participants design, however, we find similar rates of pattern and size overspecification, which are both lower than the rate of color overspecification. This indicates that although many speakers are more likely to include color than pattern (probably because color is more salient), they may also treat pattern like color due to a tendency toward consistency. We find no increase in size overspecification when the salience of size is increased, suggesting that speakers are more likely to include absolute than relative attributes. However, we do find an increase in size overspecification when mentioning the attributes is triggered, which again shows that speakers tend to refer in a consistent manner, and that there are circumstances in which even size overspecification is frequently produced. PMID:26594190

  1. Measurement of Absolute Carbon Isotope Ratios: Mechanisms and Implications

    NASA Astrophysics Data System (ADS)

    Vogel, J. S.; Giacomo, J. A.; Dueker, S. R.

    2012-12-01

    An accelerator mass spectrometer (AMS) produced absolute isotope ratio measurements for 14C/13C as tested against >500 samples of NIST SRM-4990-C (OxII 14C standard) to an accuracy of 2.2±0.6‰ over a period of one year with measurements made to 1% counting statistics. The spectrometer is not maximized for 13C/12C, but measured ∂13C to 0.4±0.1‰ accuracy, with known methods for improvement. An AMS produces elemental anions from a sputter ion source and includes a charge-changing collision in a gas cell to isolate the rare 14C from the common isotopes and molecular isobars. Both these physical processes have been modeled to determine the parameters providing such absolute measures. Neutral resonant ionization in a cesium plasma produces mass-independent ionization, while velocity dependent charge-state distributions in gas collisions produce relative ion beam intensities that are linear in mass at specific collision energies. The mechanisms are not specific to carbon isotopes, but stand alone absolute IRMS (AIR-MS) instruments have not yet been made. Aside from the obvious applications in metrology, AIR-MS is particularly valuable in coupled separatory MS because no internal or external standards are required. Sample definition processes can be compared, even if no exact standard reference sample exists. Isotope dilution measurements do not require standards matching the dilution end-points and can be made over an extended, even extrapolated, range.

  2. Peripheral absolute threshold spectral sensitivity in retinitis pigmentosa.

    PubMed Central

    Massof, R W; Johnson, M A; Finkelstein, D

    1981-01-01

    Dark-adapted spectral sensitivities were measured in the peripheral retinas of 38 patients diagnosed as having typical retinitis pigmentosa (RP) and in 3 normal volunteers. The patients included those having autosomal dominant and autosomal recessive inheritance patterns. Results were analysed by comparisons with the CIE standard scotopic spectral visibility function and with Judd's modification of the photopic spectral visibility function, with consideration of contributions from changes in spectral transmission of preretinal media. The data show 3 general patterns. One group of patients had absolute threshold spectral sensitivities that were fit by Judd's photopic visibility curve. Absolute threshold spectral sensitivities for a second group of patients were fit by a normal scotopic spectral visibility curve. The third group of patients had absolute threshold spectral sensitivities that were fit by a combination of scotopic and photopic spectral visibility curves. The autosomal dominant and autosomal recessive modes of inheritance were represented in each group of patients. These data indicate that RP patients have normal rod and/or cone spectral sensitivities, and support the subclassification of patients described previously by Massof and Finkelstein. PMID:7459312

  3. Absolute orientations from EBSD measurements - as easy as it seems?

    NASA Astrophysics Data System (ADS)

    Kilian, Rüdiger; Bestmann, Michel; Heilbronner, Renée

    2016-04-01

    In structural geology, some problems can be addressed by inspecting the crystal orientation of grains in a rock. Deriving shear senses, kinematics of flow, information on deformation processes and recrystallization are some examples. Usually, oriented samples are taken in the field and, if inspected in an universal stage, the researcher has full control over the procedure and can make sure that the derived orientation is related to our geographic reference frame - that it is an absolute orientation. Nowadays, usage of electron backscatter diffraction (EBSD) has greatly improved the information in the derived data (fully crystal orientations, mappings, etc…), and the speed of data acquisition. However, this comes to the price of having to rely on the vendor supplied software and machine setup. Recent benchmarks and comparison of reference data revealed that for various EBSD setups around the world, the orientation data defaults to the wrong absolute orientation. The absolute orientation is not correctly derived - it commonly suffer a 180 degree rotation around the normal of the sample surface. In this contribution we will discuss the implications of such erroneous measurements and what kind of interpretations derived by orientation and texture data will be affected.

  4. Determination of absolute structure using Bayesian statistics on Bijvoet differences

    PubMed Central

    Hooft, Rob W. W.; Straver, Leo H.; Spek, Anthony L.

    2008-01-01

    A new probabilistic approach is introduced for the determination of the absolute structure of a compound which is known to be enantiopure based on Bijvoet-pair intensity differences. The new method provides relative probabilities for different models of the chiral composition of the structure. The outcome of this type of analysis can also be cast in the form of a new value, along with associated standard uncertainty, that resembles the value of the well known Flack x parameter. The standard uncertainty we obtain is often about half of the standard uncertainty in the value of the Flack x parameter. The proposed formalism is suited in particular to absolute configuration determination from diffraction data of biologically active (pharmaceutical) compounds where the strongest resonant scattering signal often comes from oxygen. It is shown that a reliable absolute configuration assignment in such cases can be made on the basis of Cu Kα data, and in some cases even with carefully measured Mo Kα data. PMID:19461838

  5. Absolute Performance of AUSGeoid09 in Mountainous Regions

    NASA Astrophysics Data System (ADS)

    Sussanna, Vittorio; Janssen, Volker; Gibbings, Peter

    2014-09-01

    The Australian Height Datum (AHD) is the current national vertical datum for Australia, and AUSGeoid09 is the latest quasigeoid model used to compute (normal-orthometric)AHDheights fromGlobalNavigation Satellite System (GNSS) derived ellipsoidal heights. While previous studies have evaluated the AUSGeoid09 model across Australia, such studies have not focused on mountainous regions in particular. This paper investigates the performance of AUSGeoid09 in an absolute sense in the Mid Hunter and Snowy Mountains regions of New South Wales. Absolute (i.e. single point) comparisons were undertaken between AUSGeoid09-derived heights and published AHD heights. The performance of AUSGeoid09 was evaluated relative to its predecessor AUSGeoid98. In both study areas, an overall improvement is evident when applying AUSGeoid09 to compute AHD heights in an absolute sense. In the MidHunter, AUSGeoid09 provided a substantial improvement over its predecessor, clearly demonstrating the benefits of its new geometric component on GNSS-derived AHD height determination. In the Snowy Mountains, moderate improvement over AUSGeoid98 was evident. However, a slope was detected for AUSGeoid09 residuals, and it appears that the geometric component may have overcompensated for sea surface topography in this area. While this appraisal of AUSGeoid09 performance in mountainous regions is encouraging, it has been shown that some discrepancies still remain between AUSGeoid09-derived heights and AHD. Eventually, a new vertical datum will be necessary to ensure homogeneity across Australia.

  6. Absolute length measurement using manually decided stereo correspondence for endoscopy

    NASA Astrophysics Data System (ADS)

    Sasaki, M.; Koishi, T.; Nakaguchi, T.; Tsumura, N.; Miyake, Y.

    2009-02-01

    In recent years, various kinds of endoscope have been developed and widely used to endoscopic biopsy, endoscopic operation and endoscopy. The size of the inflammatory part is important to determine a method of medical treatment. However, it is not easy to measure absolute size of inflammatory part such as ulcer, cancer and polyp from the endoscopic image. Therefore, it is required measuring the size of those part in endoscopy. In this paper, we propose a new method to measure the absolute length in a straight line between arbitrary two points based on the photogrammetry using endoscope with magnetic tracking sensor which gives camera position and angle. In this method, the stereo-corresponding points between two endoscopic images are determined by the endoscopist without any apparatus of projection and calculation to find the stereo correspondences, then the absolute length can be calculated on the basis of the photogrammetry. The evaluation experiment using a checkerboard showed that the errors of the measurements are less than 2% of the target length when the baseline is sufficiently-long.

  7. Absolute surface reconstruction by slope metrology and photogrammetry

    NASA Astrophysics Data System (ADS)

    Dong, Yue

    Developing the manufacture of aspheric and freeform optical elements requires an advanced metrology method which is capable of inspecting these elements with arbitrary freeform surfaces. In this dissertation, a new surface measurement scheme is investigated for such a purpose, which is to measure the absolute surface shape of an object under test through its surface slope information obtained by photogrammetric measurement. A laser beam propagating toward the object reflects on its surface while the vectors of the incident and reflected beams are evaluated from the four spots they leave on the two parallel transparent windows in front of the object. The spots' spatial coordinates are determined by photogrammetry. With the knowledge of the incident and reflected beam vectors, the local slope information of the object surface is obtained through vector calculus and finally yields the absolute object surface profile by a reconstruction algorithm. An experimental setup is designed and the proposed measuring principle is experimentally demonstrated by measuring the absolute surface shape of a spherical mirror. The measurement uncertainty is analyzed, and efforts for improvement are made accordingly. In particular, structured windows are designed and fabricated to generate uniform scattering spots left by the transmitted laser beams. Calibration of the fringe reflection instrument, another typical surface slope measurement method, is also reported in the dissertation. Finally, a method for uncertainty analysis of a photogrammetry measurement system by optical simulation is investigated.

  8. Bio-Inspired Stretchable Absolute Pressure Sensor Network

    PubMed Central

    Guo, Yue; Li, Yu-Hung; Guo, Zhiqiang; Kim, Kyunglok; Chang, Fu-Kuo; Wang, Shan X.

    2016-01-01

    A bio-inspired absolute pressure sensor network has been developed. Absolute pressure sensors, distributed on multiple silicon islands, are connected as a network by stretchable polyimide wires. This sensor network, made on a 4’’ wafer, has 77 nodes and can be mounted on various curved surfaces to cover an area up to 0.64 m × 0.64 m, which is 100 times larger than its original size. Due to Micro Electro-Mechanical system (MEMS) surface micromachining technology, ultrathin sensing nodes can be realized with thicknesses of less than 100 µm. Additionally, good linearity and high sensitivity (~14 mV/V/bar) have been achieved. Since the MEMS sensor process has also been well integrated with a flexible polymer substrate process, the entire sensor network can be fabricated in a time-efficient and cost-effective manner. Moreover, an accurate pressure contour can be obtained from the sensor network. Therefore, this absolute pressure sensor network holds significant promise for smart vehicle applications, especially for unmanned aerial vehicles. PMID:26729134

  9. Bio-Inspired Stretchable Absolute Pressure Sensor Network.

    PubMed

    Guo, Yue; Li, Yu-Hung; Guo, Zhiqiang; Kim, Kyunglok; Chang, Fu-Kuo; Wang, Shan X

    2016-01-01

    A bio-inspired absolute pressure sensor network has been developed. Absolute pressure sensors, distributed on multiple silicon islands, are connected as a network by stretchable polyimide wires. This sensor network, made on a 4'' wafer, has 77 nodes and can be mounted on various curved surfaces to cover an area up to 0.64 m × 0.64 m, which is 100 times larger than its original size. Due to Micro Electro-Mechanical system (MEMS) surface micromachining technology, ultrathin sensing nodes can be realized with thicknesses of less than 100 µm. Additionally, good linearity and high sensitivity (~14 mV/V/bar) have been achieved. Since the MEMS sensor process has also been well integrated with a flexible polymer substrate process, the entire sensor network can be fabricated in a time-efficient and cost-effective manner. Moreover, an accurate pressure contour can be obtained from the sensor network. Therefore, this absolute pressure sensor network holds significant promise for smart vehicle applications, especially for unmanned aerial vehicles. PMID:26729134

  10. Absolute Timing Calibration of the USA Experiment Using Pulsar Observations

    NASA Astrophysics Data System (ADS)

    Ray, P. S.; Wood, K. S.; Wolff, M. T.; Lovellette, M. N.; Sheikh, S.; Moon, D.-S.; Eikenberry, S. S.; Roberts, M.; Lyne, A.; Jordon, C.; Bloom, E. D.; Tournear, D.; Saz Parkinson, P.; Reilly, K.

    2003-03-01

    We update the status of the absolute time calibration of the USA Experiment as determined by observations of X-ray emitting rotation-powered pulsars. The brightest such source is the Crab Pulsar and we have obtained observations of the Crab at radio, IR, optical, and X-ray wavelengths. We directly compare arrival time determinations for 2--10 keV X-ray observations made contemporaneously with the PCA on the Rossi X-ray Timing Explorer and the USA Experiment on ARGOS. These two X-ray measurements employ very different means of measuring time and satellite position and thus have different systematic error budgets. The comparison with other wavelengths requires additional steps such as dispersion measure corrections and a precise definition of the ``peak'' of the light curve since the light curve shape varies with observing wavelength. We will describe each of these effects and quantify the magnitude of the systematic error that each may contribute. We will also include time comparison results for other pulsars, such as PSR B1509-58 and PSR B1821-24. Once the absolute time calibrations are well understood, comparing absolute arrival times at multiple energies can provide clues to the magnetospheric structure and emission region geometry. Basic research on X-ray Astronomy at NRL is funded by NRL/ONR.

  11. Trends in absolute socioeconomic inequalities in mortality in Sweden and New Zealand. A 20-year gender perspective

    PubMed Central

    Wamala, Sarah; Blakely, Tony; Atkinson, June

    2006-01-01

    Background Both trends in socioeconomic inequalities in mortality, and cross-country comparisons, may give more information about the causes of health inequalities. We analysed trends in socioeconomic differentials by mortality from early 1980s to late 1990s, comparing Sweden with New Zealand. Methods The New Zealand Census Mortality Study (NZCMS) consisting of over 2 million individuals and the Swedish Survey of Living Conditions (ULF) comprising over 100, 000 individuals were used for analyses. Education and household income were used as measures of socioeconomic position (SEP). The slope index of inequality (SII) was calculated to estimate absolute inequalities in mortality. Analyses were based on 3–5 year follow-up and limited to individuals aged 25–77 years. Age standardised mortality rates were calculated using the European population standard. Results Absolute inequalities in mortality on average over the 1980s and 1990s for both men and women by education were similar in Sweden and New Zealand, but by income were greater in Sweden. Comparing trends in absolute inequalities over the 1980s and 1990s, men's absolute inequalities by education decreased by 66% in Sweden and by 17% in New Zealand (p for trend <0.01 in both countries). Women's absolute inequalities by education decreased by 19% in Sweden (p = 0.03) and by 8% in New Zealand (p = 0.53). Men's absolute inequalities by income decreased by 51% in Sweden (p for trend = 0.06), but increased by 16% in New Zealand (p = 0.13). Women's absolute inequalities by income increased in both countries: 12% in Sweden (p = 0.03) and 21% in New Zealand (p = 0.04). Conclusion Trends in socioeconomic inequalities in mortality were clearly most favourable for men in Sweden. Trends also seemed to be more favourable for men than women in New Zealand. Assuming the trends in male inequalities in Sweden were not a statistical chance finding, it is not clear what the substantive reason(s) was for the pronounced decrease

  12. The new Absolute Quantum Gravimeter (AQG): first results and perspectives

    NASA Astrophysics Data System (ADS)

    Bonvalot, Sylvain; Le Moigne, Nicolas; Merlet, Sebastien; Desruelle, Bruno; Lautier-Gaud, Jean; Menoret, Vincent; Vermeulen, Pierre

    2016-04-01

    Cold atom gravimetry represents one of the most innovative evolution in gravity instrumentation since the last 20 years. The concept of measuring the gravitational acceleration by dropping atoms and the development of the first instrumental devices during this last decade quickly revealed the promising perspectives of this new generation of gravity meters enabling accurate and absolute measurements of the Earth's gravity field for a wide range of applications (geophysics, geodesy, metrology, etc.). The Absolute Quantum Gravimeter (AQG) gravity meter, developed by MUQUANS (Talence, France - http://www.muquans.com/) with the support of RESIF, the French Seismologic and Geodetic Network (http://www.resif.fr/) belongs to this new generation of instruments. It also represents the first commercial device based on the utilization of advanced matter-wave interferometry techniques, which allow to characterize precisely the vertical acceleration experienced by a cloud of cold atoms. Recently, the first operational unit (AQG01) has been achieved as a compact transportable gravimeter with the aim of satisfying absolute gravity measurements in laboratory conditions under the following specifications: measurements the μGal level at a few Hz cycling frequency, sensitivity of 50μGal/√Hz, immunity to ground vibrations, easy and quickness of operation, automated continuous data acquisition for several months, etc. In order to evaluate the current performances of the AQG01, several experiments are carried out in collaboration between RESIF user's teams and the MUQUANS manufacturer on different reference gravity sites and laboratories in France. These measurements performed in indoor conditions including simultaneous observations with classical reference gravity instruments (corner-cube absolute gravity meters, relative superconducting meters) as well with the Cold Atom Gravity meter (CAG) developed by LNE-SYRTE, lead to a first objective characterization of the performances of

  13. SU-E-I-43: Photoelectric Cross Section Revisited

    SciTech Connect

    Haga, A; Nakagawa, K; Kotoku, J; Horikawa, Y

    2015-06-15

    Purpose: The importance of the precision in photoelectric cross-section value increases for recent developed technology such as dual energy computed tomography, in which some reconstruction algorithms require the energy dependence of the photo-absorption in each material composition of human being. In this study, we revisited the photoelectric cross-section calculation by self-consistent relativistic Hartree-Fock (HF) atomic model and compared with that widely distributed as “XCOM database” in National Institute of Standards and Technology, which was evaluated with localdensity approximation for electron-exchange (Fock)z potential. Methods: The photoelectric cross section can be calculated with the electron wave functions in initial atomic state (bound electron) and final continuum state (photoelectron). These electron states were constructed based on the selfconsistent HF calculation, where the repulsive Coulomb potential from the electron charge distribution (Hartree term) and the electron exchange potential with full electromagnetic interaction (Fock term) were included for the electron-electron interaction. The photoelectric cross sections were evaluated for He (Z=2), Be (Z=4), C (Z=6), O (Z=8), and Ne (Z=10) in energy range of 10keV to 1MeV. The Result was compared with XCOM database. Results: The difference of the photoelectric cross section between the present calculation and XCOM database was 8% at a maximum (in 10keV for Be). The agreement tends to be better as the atomic number increases. The contribution from each atomic shell has a considerable discrepancy with XCOM database except for K-shell. However, because the photoelectric cross section arising from K-shell is dominant, the net photoelectric cross section was almost insensitive to the different handling in Fock potential. Conclusion: The photoelectric cross-section program has been developed based on the fully self-consistent relativistic HF atomic model. Due to small effect on the Fock

  14. First Measurement of the Double-Shake-Up Photoionization Cross-Section of Li

    NASA Astrophysics Data System (ADS)

    Wuilleumier, F. J.; Cubaynes, D.; Bizau, J.-M.; Diehl, S.; Kennedy, E. T.; Mosnier, J.-P.

    2000-06-01

    Using synchrotron radiation from the Super-ACO storage ring and an electron spectrometer with angle-integrated detection, we have measured the cross-section for 1s-photoionization of the neutral 1s^22s ^2S lithium atom with the residual positive ion being left in a doubly-excited (2l, 2l’) or (2l, 3l’)^1,3L over the 150-450 eV energy range, according to: 1s^22s ^2S Li + hν arrow (2lnl’^1,3L) Li^+ + ɛl, with n >= 2. The relative values of the measured cross sections were normalized to total photoabsorption data.[1] The relative cross-sections for the ^1,3S and ^1,3P Li^+ states are continuously increasing and decreasing with photon energy, respectively, illustrating the different mechanisms leading to their production. At low photon energies, the experimental data are in good agreement with the predictions of a R-matrix calculation.[2] 1. G. Mehlman et al., Phys. Rev. A 25, 2113 (1982). 2. L. VoKy, private communication.

  15. New benzene absorption cross sections in the VUV, relevance for Titan's upper atmosphere

    NASA Astrophysics Data System (ADS)

    Capalbo, Fernando J.; Bénilan, Yves; Fray, Nicolas; Schwell, Martin; Champion, Norbert; Es-sebbar, Et-touhami; Koskinen, Tommi T.; Lehocki, Ivan; Yelle, Roger V.

    2016-02-01

    Benzene is an important molecule in Titan's atmosphere because it is a potential link between the gas phase and the organic solid phase. We measured photoabsorption in the ultraviolet by benzene gas at temperatures covering the range from room temperature to 215 K. We derived benzene absorption cross sections and analyzed them in terms of the transitions observed. No significant variation with measurement temperature was observed. We discuss the implications of our measurements for the derivation of benzene abundance profiles in Titan's thermosphere, by the Cassini/Ultraviolet Imaging Spectrograph (UVIS). The use of absorption cross sections at low temperature is recommended to avoid small systematic uncertainties in the profiles. We used our measurements, together with absorption cross sections from other molecules, to analyze four stellar occultations by Titan, measured by UVIS during flybys T21, T41, T41_II, and T53. We derived and compared benzene abundance profiles in Titan's thermosphere between approximately 530 and 1000 km, for different dates and geographical locations. The comparisons of our benzene profiles with each other, and with profiles from models of the upper atmosphere, point to a complex behavior that is not explained by current photochemical models.

  16. GNSS Absolute Antenna Calibration at the National Geodetic Survey

    NASA Astrophysics Data System (ADS)

    Bilich, A. L.; Mader, G. L.

    2009-12-01

    GNSS applications now routinely demand measurement and instrument biases at the centimeter to millimeter level in order to achieve the high precision and accuracy required for geodetic position solutions. One of these biases is the antenna phase center, the point of signal reception for a GNSS antenna. It has been well established that phase center patterns differ between antenna models and manufacturers; additional research suggests that the addition of a radome or the choice of antenna mount can significantly alter those a priori phase center patterns. As baseline lengths increase, or with antenna mixing, phase center effects on carrier phase data become more pronounced. To meet the needs of the high-precision GNSS community, the National Geodetic Survey (NGS) has constructed an absolute antenna calibration facility which uses field measurements and actual GNSS satellite signals to determine antenna phase center patterns. A pan/tilt motor changes the orientation of the antenna under test; signals are received at a wide range of angles, allowing computation of a robust phase center pattern. Ultimately, this facility will be used to measure antenna phase center variations of commonly-used geodetic GNSS antennas, as well as antennas submitted by users. The phase center patterns will be publicly available and disseminated in both the ANTEX and NGS formats. We provide information on the observation models and strategy currently used to generate NGS absolute calibrations, and propose some future refinements. We discuss the multipath mitigation strategy currently in use, and provide examples of antenna calibrations from the NGS facility. These examples are compared to the NGS relative calibrations as well as absolute calibrations generated by other organizations.

  17. Morphology and Absolute Magnitudes of the SDSS DR7 QSOs

    NASA Astrophysics Data System (ADS)

    Coelho, B.; Andrei, A. H.; Antón, S.

    2014-10-01

    The ESA mission Gaia will furnish a complete census of the Milky Way, delivering astrometrics, dynamics, and astrophysics information for 1 billion stars. Operating in all-sky repeated survey mode, Gaia will also provide measurements of extra-galactic objects. Among the later there will be at least 500,000 QSOs that will be used to build the reference frame upon which the several independent observations will be combined and interpreted. Not all the QSOs are equally suited to fulfill this role of fundamental, fiducial grid-points. Brightness, morphology, and variability define the astrometric error budget for each object. We made use of 3 morphological parameters based on the PSF sharpness, circularity and gaussianity, which enable us to distinguish the "real point-like" QSOs. These parameters are being explored on the spectroscopically certified QSOs of the SDSS DR7, to compare the performance against other morphology classification schemes, as well as to derive properties of the host galaxy. We present a new method, based on the Gaia quasar database, to derive absolute magnitudes, on the SDSS filters domain. The method can be extrapolated all over the optical window, including the Gaia filters. We discuss colors derived from SDSS apparent magnitudes and colors based on absolute magnitudes that we obtained tanking into account corrections for dust extinction, either intergalactic or from the QSO host, and for the Lyman α forest. In the future we want to further discuss properties of the host galaxies, comparing for e.g. the obtained morphological classification with the color, the apparent and absolute magnitudes, and the redshift distributions.

  18. Absolute dose calculations for Monte Carlo simulations of radiotherapy beams.

    PubMed

    Popescu, I A; Shaw, C P; Zavgorodni, S F; Beckham, W A

    2005-07-21

    Monte Carlo (MC) simulations have traditionally been used for single field relative comparisons with experimental data or commercial treatment planning systems (TPS). However, clinical treatment plans commonly involve more than one field. Since the contribution of each field must be accurately quantified, multiple field MC simulations are only possible by employing absolute dosimetry. Therefore, we have developed a rigorous calibration method that allows the incorporation of monitor units (MU) in MC simulations. This absolute dosimetry formalism can be easily implemented by any BEAMnrc/DOSXYZnrc user, and applies to any configuration of open and blocked fields, including intensity-modulated radiation therapy (IMRT) plans. Our approach involves the relationship between the dose scored in the monitor ionization chamber of a radiotherapy linear accelerator (linac), the number of initial particles incident on the target, and the field size. We found that for a 10 x 10 cm2 field of a 6 MV photon beam, 1 MU corresponds, in our model, to 8.129 x 10(13) +/- 1.0% electrons incident on the target and a total dose of 20.87 cGy +/- 1.0% in the monitor chambers of the virtual linac. We present an extensive experimental verification of our MC results for open and intensity-modulated fields, including a dynamic 7-field IMRT plan simulated on the CT data sets of a cylindrical phantom and of a Rando anthropomorphic phantom, which were validated by measurements using ionization chambers and thermoluminescent dosimeters (TLD). Our simulation results are in excellent agreement with experiment, with percentage differences of less than 2%, in general, demonstrating the accuracy of our Monte Carlo absolute dose calculations. PMID:16177516

  19. Absolute versus relative ascertainment of pedophilia in men.

    PubMed

    Blanchard, Ray; Kuban, Michael E; Blak, Thomas; Cantor, James M; Klassen, Philip E; Dickey, Robert

    2009-12-01

    There are at least two different criteria for assessing pedophilia in men: absolute ascertainment (their sexual interest in children is intense) and relative ascertainment (their sexual interest in children is greater than their interest in adults). The American Psychiatric Association's Diagnostic and Statistical Manual of Mental Disorders, 3rd edition (DSM-III) used relative ascertainment in its diagnostic criteria for pedophilia; this was abandoned and replaced by absolute ascertainment in the DSM-III-R and all subsequent editions. The present study was conducted to demonstrate the continuing need for relative ascertainment, particularly in the laboratory assessment of pedophilia. A total of 402 heterosexual men were selected from a database of patients referred to a specialty clinic. These had undergone phallometric testing, a psychophysiological procedure in which their penile blood volume was monitored while they were presented with a standardized set of laboratory stimuli depicting male and female children, pubescents, and adults.The 130 men selected for the Teleiophilic Profile group responded substantially to prepubescent girls but even more to adult women; the 272 men selected for the Pedophilic Profile group responded weakly to prepubescent girls but even less to adult women. In terms of absolute magnitude, every patient in the Pedophilic Profile group had a lesser penile response to prepubescent girls than every patient in the Teleiophilic Profile group. Nevertheless, the Pedophilic Profile group had a significantly greater number of known sexual offenses against prepubescent girls, indicating that they contained a higher proportion of true pedophiles. These results dramatically demonstrate the utility-or perhaps necessity-of relative ascertainment in the laboratory assessment of erotic age-preference. PMID:19901237

  20. Absolute dose calculations for Monte Carlo simulations of radiotherapy beams

    NASA Astrophysics Data System (ADS)

    Popescu, I. A.; Shaw, C. P.; Zavgorodni, S. F.; Beckham, W. A.

    2005-07-01

    Monte Carlo (MC) simulations have traditionally been used for single field relative comparisons with experimental data or commercial treatment planning systems (TPS). However, clinical treatment plans commonly involve more than one field. Since the contribution of each field must be accurately quantified, multiple field MC simulations are only possible by employing absolute dosimetry. Therefore, we have developed a rigorous calibration method that allows the incorporation of monitor units (MU) in MC simulations. This absolute dosimetry formalism can be easily implemented by any BEAMnrc/DOSXYZnrc user, and applies to any configuration of open and blocked fields, including intensity-modulated radiation therapy (IMRT) plans. Our approach involves the relationship between the dose scored in the monitor ionization chamber of a radiotherapy linear accelerator (linac), the number of initial particles incident on the target, and the field size. We found that for a 10 × 10 cm2 field of a 6 MV photon beam, 1 MU corresponds, in our model, to 8.129 × 1013 ± 1.0% electrons incident on the target and a total dose of 20.87 cGy ± 1.0% in the monitor chambers of the virtual linac. We present an extensive experimental verification of our MC results for open and intensity-modulated fields, including a dynamic 7-field IMRT plan simulated on the CT data sets of a cylindrical phantom and of a Rando anthropomorphic phantom, which were validated by measurements using ionization chambers and thermoluminescent dosimeters (TLD). Our simulation results are in excellent agreement with experiment, with percentage differences of less than 2%, in general, demonstrating the accuracy of our Monte Carlo absolute dose calculations.

  1. Absolute Efficiency Calibration of a Beta-Gamma Detector

    SciTech Connect

    Cooper, Matthew W.; Ely, James H.; Haas, Derek A.; Hayes, James C.; McIntyre, Justin I.; Lidey, Lance S.; Schrom, Brian T.

    2013-04-10

    Abstract- Identification and quantification of nuclear events such as the Fukushima reactor failure and nuclear explosions rely heavily on the accurate measurement of radioxenon releases. One radioxenon detection method depends on detecting beta-gamma coincident events paired with a stable xenon measurement to determine the concentration of a plume. Like all measurements, the beta-gamma method relies on knowing the detection efficiency for each isotope measured. Several methods are commonly used to characterize the detection efficiency for a beta-gamma detector. The most common method is using a NIST certified sealed source to determine the efficiency. A second method determines the detection efficiencies relative to an already characterized detector. Finally, a potentially more accurate method is to use the expected sample to perform an absolute efficiency calibration; in the case of a beta-gamma detector, this relies on radioxenon gas samples. The complication of the first method is it focuses only on the gamma detectors and does not offer a solution for determining the beta efficiency. The second method listed is not similarly constrained, however it relies on another detector to have a well-known efficiency calibration. The final method using actual radioxenon samples to make an absolute efficiency determination is the most desirable, but until recently it was not possible to produce all four isotopically pure radioxenon. The production, by University of Texas (UT), of isotopically pure radioxenon has allowed the beta-gamma detectors to be calibrated using the absolute efficiency method. The first four radioxenon isotope calibration will be discussed is this paper.

  2. On the convective-absolute nature of river bedform instabilities

    NASA Astrophysics Data System (ADS)

    Vesipa, Riccardo; Camporeale, Carlo; Ridolfi, Luca; Chomaz, Jean Marc

    2014-12-01

    River dunes and antidunes are induced by the morphological instability of stream-sediment boundary. Such bedforms raise a number of subtle theoretical questions and are crucial for many engineering and environmental problems. Despite their importance, the absolute/convective nature of the instability has never been addressed. The present work fills this gap as we demonstrate, by the cusp map method, that dune instability is convective for all values of the physical control parameters, while the antidune instability exhibits both behaviors. These theoretical predictions explain some previous experimental and numerical observations and are important to correctly plan flume experiments, numerical simulations, paleo-hydraulic reconstructions, and river works.

  3. Absolute spectrophotometry of Neptune - 3390 to 7800 A

    NASA Astrophysics Data System (ADS)

    Bergstralh, J. T.; Neff, J. S.

    1983-07-01

    Absolute spectrophotometry of Neptune from 3390 to 7800 Å, with spectral resolution of 10 Å in the interval 3390 - 6055 and 20 Å in the interval 6055 - 7800 Å, is reported. The results are compared with filter photometry (Appleby, 1973; Wamsteker, 1973; Savage et al., 1980) and with synthetic spectra computed on the basis of a parameterization proposed by Podolak and Danielson (1977) for aerosol scattering and absorption. A CH4/H2 ratio is derived for the convectively mixed part of Neptune's atmosphere, and constrains optical properties of hypothetical aerosol layers.

  4. Prelaunch absolute radiometric calibration of LANDSAT-4 protoflight Thematic Mapper

    NASA Technical Reports Server (NTRS)

    Barker, J. L.; Ball, D. L.; Leung, K. C.; Walker, J. A.

    1984-01-01

    Results are summarized and analyzed from several prelaunch tests with a 122 cm integrating sphere used as part of the absolute radiometric calibration experiments for the protoflight TM sensor carried on the LANDSAT-4 satellite. The calibration procedure is presented and the radiometric sensitivity of the TM is assessed. The internal calibrator and dynamic range after calibration are considered. Tables show dynamic range after ground processing, spectral radiance to digital number and digital number to spectral radiance values for TM bands 1, 2, 3, 4, 5, 7 and for channel 4 of band 6.

  5. Method of differential-phase/absolute-amplitude QAM

    DOEpatents

    Dimsdle, Jeffrey William

    2007-07-03

    A method of quadrature amplitude modulation involving encoding phase differentially and amplitude absolutely, allowing for a high data rate and spectral efficiency in data transmission and other communication applications, and allowing for amplitude scaling to facilitate data recovery; amplitude scale tracking to track-out rapid and severe scale variations and facilitate successful demodulation and data retrieval; 2.sup.N power carrier recovery; incoherent demodulation where coherent carrier recovery is not possible or practical due to signal degradation; coherent demodulation; multipath equalization to equalize frequency dependent multipath; and demodulation filtering.

  6. Method of differential-phase/absolute-amplitude QAM

    DOEpatents

    Dimsdle, Jeffrey William

    2008-10-21

    A method of quadrature amplitude modulation involving encoding phase differentially and amplitude absolutely, allowing for a high data rate and spectral efficiency in data transmission and other communication applications, and allowing for amplitude scaling to facilitate data recovery; amplitude scale tracking to track-out rapid and severe scale variations and facilitate successful demodulation and data retrieval; 2.sup.N power carrier recovery; incoherent demodulation where coherent carrier recovery is not possible or practical due to signal degradation; coherent demodulation; multipath equalization to equalize frequency dependent multipath; and demodulation filtering.

  7. Method of differential-phase/absolute-amplitude QAM

    DOEpatents

    Dimsdle, Jeffrey William

    2007-07-17

    A method of quadrature amplitude modulation involving encoding phase differentially and amplitude absolutely, allowing for a high data rate and spectral efficiency in data transmission and other communication applications, and allowing for amplitude scaling to facilitate data recovery; amplitude scale tracking to track-out rapid and severe scale variations and facilitate successful demodulation and data retrieval; 2.sup.N power carrier recovery; incoherent demodulation where coherent carrier recovery is not possible or practical due to signal degradation; coherent demodulation; multipath equalization to equalize frequency dependent multipath; and demodulation filtering.

  8. Method of differential-phase/absolute-amplitude QAM

    DOEpatents

    Dimsdle, Jeffrey William

    2007-10-02

    A method of quadrature amplitude modulation involving encoding phase differentially and amplitude absolutely, allowing for a high data rate and spectral efficiency in data transmission and other communication applications, and allowing for amplitude scaling to facilitate data recovery; amplitude scale tracking to track-out rapid and severe scale variations and facilitate successful demodulation and data retrieval; 2.sup.N power carrier recovery; incoherent demodulation where coherent carrier recovery is not possible or practical due to signal degradation; coherent demodulation; multipath equalization to equalize frequency dependent multipath; and demodulation filtering.

  9. Method of differential-phase/absolute-amplitude QAM

    DOEpatents

    Dimsdle, Jeffrey William

    2009-09-01

    A method of quadrature amplitude modulation involving encoding phase differentially and amplitude absolutely, allowing for a high data rate and spectral efficiency in data transmission and other communication applications, and allowing for amplitude scaling to facilitate data recovery; amplitude scale tracking to track-out rapid and severe scale variations and facilitate successful demodulation and data retrieval; 2.sup.N power carrier recovery; incoherent demodulation where coherent carrier recovery is not possible or practical due to signal degradation; coherent demodulation; multipath equalization to equalize frequency dependent multipath; and demodulation filtering.

  10. Stability of array spectroradiometers and their suitability for absolute calibrations

    NASA Astrophysics Data System (ADS)

    Nevas, Saulius; Teuber, Annette; Sperling, Armin; Lindemann, Matthias

    2012-04-01

    An investigation of the short- and long-term stability of various low-end and high-end array spectroradiometers is presented. Potentially weak points of array spectroradiometers with respect to their suitability for absolute calibrations are pointed out. The influence of ambient conditions on relevant instrumental characteristics and their temporal stability is discussed. It is shown that the temporal stability of some instruments can be significantly affected by high ambient humidity. Most important ambient temperature effects on instrument properties are also discussed.

  11. Albendazole sulfoxide enantiomers: preparative chiral separation and absolute stereochemistry.

    PubMed

    Lourenço, Tiago C; Batista, João M; Furlan, Maysa; He, Yanan; Nafie, Laurence A; Santana, Cesar C; Cass, Quezia B

    2012-03-23

    The enantiomeric separation of albendazole sulfoxide was carried out by simulated moving bed chromatography with variable zones (VARICOL). An overall recovery of 97% was achieved and enantiomeric ratios of 99.5% for raffinate and 99.0% for extract were attained. A total of 880 mg of (+)-albendazol sulfoxide and 930 mg of its antipode were collected after 55 cycles or 11 h of process, resulting in a mass rate of 2 g/day. Furthermore the absolute configuration of the enantiopure compounds was determined for the first time by vibrational circular dichroism (VCD) with the aid of theoretical calculations as (-)-(S) and (+)-(R)-albendazole sulfoxide. PMID:22341660

  12. Absolute magnetic helicity and the cylindrical magnetic field

    NASA Astrophysics Data System (ADS)

    Low, B. C.

    2011-05-01

    The different magnetic helicities conserved under conditions of perfect electrical conductivity are expressions of the fundamental property that every evolving fluid surface conserves its net magnetic flux. This basic hydromagnetic point unifies the well known Eulerian helicities with the Lagrangian helicity defined by the conserved fluxes frozen into a prescribed set of disjoint toroidal tubes of fluid flowing as a permanent partition of the entire fluid [B. C. Low, Astrophys. J. 649, 1064 (2006)]. This unifying theory is constructed from first principles, beginning with an analysis of the Eulerian and Lagrangian descriptions of fluids, separating the ideas of fluid and magnetic-flux tubes and removing the complication of the magnetic vector potential's free gauge from the concept of helicity. The analysis prepares for the construction of a conserved Eulerian helicity, without that gauge complication, to describe a 3D anchored flux in an upright cylindrical domain, this helicity called absolute to distinguish it from the well known relative helicity. In a version of the Chandrasekhar-Kendall representation, the evolving field at any instant is a unique superposition of a writhed, untwisted axial flux with a circulating flux of field lines all closed and unlinked within the cylindrical domain. The absolute helicity is then a flux-weighted sum of the writhe of that axial flux and its mutual linkage with the circulating flux. The absolute helicity is also conserved if the frozen-in field and its domain are continuously deformed by changing the separation between the rigid cylinder-ends with no change of cylinder radius. This hitherto intractable cylindrical construction closes a crucial conceptual gap for the fundamentals to be complete at last. The concluding discussion shows the impact of this development on our understanding of helicity, covering (i) the helicities of wholly contained and anchored fields; (ii) the Eulerian and Lagrangian descriptions of field

  13. Testing and evaluation of thermal cameras for absolute temperature measurement

    NASA Astrophysics Data System (ADS)

    Chrzanowski, Krzysztof; Fischer, Joachim; Matyszkiel, Robert

    2000-09-01

    The accuracy of temperature measurement is the most important criterion for the evaluation of thermal cameras used in applications requiring absolute temperature measurement. All the main international metrological organizations currently propose a parameter called uncertainty as a measure of measurement accuracy. We propose a set of parameters for the characterization of thermal measurement cameras. It is shown that if these parameters are known, then it is possible to determine the uncertainty of temperature measurement due to only the internal errors of these cameras. Values of this uncertainty can be used as an objective criterion for comparisons of different thermal measurement cameras.

  14. Precision Absolute Beam Current Measurement of Low Power Electron Beam

    SciTech Connect

    Ali, M. M.; Bevins, M. E.; Degtiarenko, P.; Freyberger, A.; Krafft, G. A.

    2012-11-01

    Precise measurements of low power CW electron beam current for the Jefferson Lab Nuclear Physics program have been performed using a Tungsten calorimeter. This paper describes the rationale for the choice of the calorimeter technique, as well as the design and calibration of the device. The calorimeter is in use presently to provide a 1% absolute current measurement of CW electron beam with 50 to 500 nA of average beam current and 1-3 GeV beam energy. Results from these recent measurements will also be presented.

  15. Spatially resolved absolute spectrophotometry of Saturn - 3390 to 8080 A

    NASA Technical Reports Server (NTRS)

    Bergstralh, J. T.; Diner, D. J.; Baines, K. H.; Neff, J. S.; Allen, M. A.; Orton, G. S.

    1981-01-01

    A series of spatially resolved absolute spectrophotometric measurements of Saturn was conducted for the expressed purpose of calibrating the data obtained with the Imaging Photopolarimeter (IPP) on Pioneer 11 during its recent encounter with Saturn. All observations reported were made at the Mt. Wilson 1.5-m telescope, using a 1-m Ebert-Fastie scanning spectrometer. Spatial resolution was 1.92 arcsec. Photometric errors are considered, taking into account the fixed error, the variable error, and the composite error. The results are compared with earlier observations, as well as with synthetic spectra derived from preliminary physical models, giving attention to the equatorial region and the South Temperate Zone.

  16. Verification of Absolute Calibration of Quantum Efficiency for LSST CCDs

    NASA Astrophysics Data System (ADS)

    Coles, Rebecca; Chiang, James; Cinabro, David; Gilbertson, Woodrow; Haupt, justine; Kotov, Ivan; Neal, Homer; Nomerotski, Andrei; O'Connor, Paul; Stubbs, Christopher; Takacs, Peter

    2016-01-01

    We describe a system to measure the Quantum Efficiency in the wavelength range of 300nm to 1100nm of 40x40 mm n-channel CCD sensors for the construction of the 3.2 gigapixel LSST focal plane. The technique uses a series of instruments to create a very uniform flux of photons of controllable intensity in the wavelength range of interest across the face of the sensor. This allows the absolute Quantum Efficiency to be measured with an accuracy in the 1% range. This system will be part of a production facility at Brookhaven National Lab for the basic components of the LSST camera.

  17. Lens transmission measurement for an absolute radiation thermometer

    SciTech Connect

    Hao, X.; Yuan, Z.; Lu, X.

    2013-09-11

    The lens transmission for the National Institute of Metrology of China absolute radiation thermometer is measured by a hybrid method. The results of the lens transmission measurements are 99.002% and 86.792% for filter radiometers with center wavelengths 633 nm and 900 nm, respectively. These results, after correcting for diffraction factors and the size-of-source effect when the lens is incorporated within the radiometer, can be used for measurement of thermodynamic temperature. The expanded uncertainty of the lens transmission measurement system has been evaluated. It is 1.3×10{sup −3} at 633 nm and 900 nm, respectively.

  18. Evaluation of Absolute Dynamic Ocean Topography Profiles along the Brazilian Coast

    NASA Astrophysics Data System (ADS)

    Luz, R. T.; Bosch, W.; Freitas, S. R. C.; Heck, B.

    2009-04-01

    Based on a new approach, which consistently filters GRACE-based geoid undulations and altimetry-derived sea surface heights along the tracks of altimeter satellites, absolute dynamic ocean topography (DOT) profiles are estimated along the Brazilian coast. Such DOT profiles can be used to perform levelling over the sea. Connecting these profiles with Brazilian Geodetic Tide Gauge Network (RMPG) stations it would be possible to validate the current studies on the modernization of the Brazilian height system, extended over many thousand kilometers on land. The link with coastal reference sites would also allow to connect isolated height systems, e.g. north of the Amazonas River mouth. We perform long-term mean DOT-profiles of cross-calibrated altimeter satellites which operated for many years over repeated ground tracks (TOPEX, Jason-1, ERS-2). Moreover, we analyze the consistency among crossing profiles (single- and dual-satellite) in particular in areas with strong mesoscale currents. The extrapolation of DOT profiles towards selected RMPG stations is investigated. For this connection strategies are considered to overcome the degradation of coastal altimetry due to errors in ocean tide models and the land contamination of the radiometer observations.

  19. Inelastic mean-free paths and surface excitation parameters by absolute reflection electron-energy loss measurements

    NASA Astrophysics Data System (ADS)

    Nagatomi, T.; Goto, K.

    2007-06-01

    An analytical approach is proposed for simultaneously determining the inelastic mean-free path (IMFP), the surface excitation parameter (SEP), and the differential SEP (DSEP) in absolute units from an absolute reflection electron energy loss spectroscopy (REELS) spectrum under the assumption that the normalized differential inelastic mean-free path for bulk excitations and the elastic scattering cross section are known. This approach was applied to an analysis of REELS spectra for Ni, and the IMFP, SEP, and DSEP in Ni for 300-3000eV electrons were determined. The resulting IMFPs showed good agreement with those calculated using the TPP-2M predictive equations and with those calculated from optical data. The deduced DSEPs show a reasonable agreement with those theoretically predicted. The obtained SEPs were compared with those calculated using several predictive equations. The present SEP results agreed well with the Chen formula with a material parameter proposed for Ni. The present approach has high potential for the experimental determination of IMFPs, SEPs, and DSEPs in absolute units.

  20. A new absolute extreme ultraviolet image system designed for studying the radiated power of the Joint Texas Experimental Tokamak discharges.

    PubMed

    Zhang, J; Zhuang, G; Wang, Z J; Ding, Y H; Zhang, X Q; Tang, Y J

    2010-07-01

    A bolometer imaging system mounted on different toroidal and poloidal locations used for radiation observation has been developed in the Joint Texas Experimental Tokamak (J-TEXT tokamak). Three miniature pinhole AXUV16ELG (16 elements absolute extreme ultraviolet silicon photodiodes) array cameras, which are settled down in the same toroidal position but in three different poloidal places, can provide a broad viewing angle that covers the whole plasma cross-section, and hence can measure the total radiated power and provide the radiated emissive profile, while nine AXUV10EL (10 elements absolute extreme ultraviolet silicon photodiodes) array cameras are divided into three groups and will be mounted on different toroidal locations to observe the toroidal radiated power distribution. Among these detectors, one element of the AXUV16ELG array is absolutely calibrated by the synchrotron radiation source to verify the system reliability. Although there are some discrepancies between the typical responsivity given by IRD Co. and the calibrated results, it is confirmed that the discrepancies have no major effect on the final result after the simulation. The details of the system as well as observations are presented in the paper. PMID:20687724