Science.gov

Sample records for absolute spectrophotometric calibration

  1. Telescope Spectrophotometric and Absolute Flux Calibration, and National Security Applications, Using a Turntable Laser on a Satellite

    NASA Astrophysics Data System (ADS)

    Albert, J.; Burgett, W.; Rhodes, J.

    We propose a tunable laser-based satellite-mounted spectrophotometric and absolute flux calibration system, to be utilized by ground- and space-based telescopes. As uncertainties on the photometry, due to imperfect knowledge of both telescope optics and the atmosphere, will in the near future begin to dominate the uncertainties on fundamental cosmological parameters such as WL (Omega_Lambda) and w in measurements from SNIa, weak gravitational lensing, and baryon oscillations, a method for reducing such uncertainties is needed. We propose to improve spectrophotometric calibration, currently obtained using standard stars, by placing a tunable laser and a wide-angle light source on a satellite by early next decade (perhaps included in the upgrade to the GPS satellite network) to improve absolute flux calibration to 0.1% and relative spectrophotometric calibration to better than 0.001% across the visible and near-infrared spectrum. As well as fundamental astrophysical applications, the system proposed here potentially has broad utility for defense and national security applications such as ground target illumination and space communication. For further details please see http://www.arxiv.org/abs/astro-ph/0604339.

  2. The absolute spectrophotometric catalog by Anita Cochran

    NASA Astrophysics Data System (ADS)

    Burnashev, V. I.; Burnasheva, B. A.; Ruban, E. V.; Hagen-Torn, E. I.

    2014-06-01

    The absolute spectrophotometric catalog by Anita Cochran is presented in a machine-readable form. The catalog systematizes observations acquired at the McDonald Observatory in 1977-1978. The data are compared with other sources, in particular, the calculated broadband stellar magnitudes are compared with photometric observations by other authors, to show that the observational data given in the catalog are reliable and suitable for a variety of applications. Observations of variable stars of different types make Cochran's catalog especially valuable.

  3. Spectrophotometric Standards for Cross-Observatory Calibration

    NASA Astrophysics Data System (ADS)

    Diaz-Miller, Rosa

    2005-07-01

    This program will obtain NICMOS spectrophotometry of four main sequence A stars and four K giants, each selected from the Spitzer IRAC photometric calibration target and/or candidate calibration target lists {Reach et al 2005, PASP,117,978}. These observations will supplement existing HST observations of DA white dwarfs and solar analogs, and will provide a broad base of stellar types for spectrophotometric cross calibration of HST, Spitzer, and eventually JWST. The targets are chosen to be faint enough for unsaturated observations with JWST NIRSPEC, yet still bright enough for high signal to noise in relatively short observations with HST+NICMOS and with Spitzer+IRAC.ANALYSIS OF THE FIRST OBS OF 1812095 & KF06T2These data demonstated heavy saturation in the longer exposures. For example, 1812095 {A3V, V=11.8, Ks=11.6} shows a peak rate of 250DN/s in G096, while KF06T2 {K1.5III V=13.8, Ks=11.3} reaches 250DN/s in G206, including the 100DN/s of background. Thus, full saturation of some charge wells occurred after integrating for 100s. Adopting a 2x safety factor, the integration times should be limited to 50s. The brightest stars are Ks=11, or 32% brighter.

  4. Absolute calibration in vivo measurement systems

    SciTech Connect

    Kruchten, D.A.; Hickman, D.P.

    1991-02-01

    Lawrence Livermore National Laboratory (LLNL) is currently investigating a new method for obtaining absolute calibration factors for radiation measurement systems used to measure internally deposited radionuclides in vivo. Absolute calibration of in vivo measurement systems will eliminate the need to generate a series of human surrogate structures (i.e., phantoms) for calibrating in vivo measurement systems. The absolute calibration of in vivo measurement systems utilizes magnetic resonance imaging (MRI) to define physiological structure, size, and composition. The MRI image provides a digitized representation of the physiological structure, which allows for any mathematical distribution of radionuclides within the body. Using Monte Carlo transport codes, the emission spectrum from the body is predicted. The in vivo measurement equipment is calibrated using the Monte Carlo code and adjusting for the intrinsic properties of the detection system. The calibration factors are verified using measurements of existing phantoms and previously obtained measurements of human volunteers. 8 refs.

  5. Absolute calibration of optical flats

    DOEpatents

    Sommargren, Gary E.

    2005-04-05

    The invention uses the phase shifting diffraction interferometer (PSDI) to provide a true point-by-point measurement of absolute flatness over the surface of optical flats. Beams exiting the fiber optics in a PSDI have perfect spherical wavefronts. The measurement beam is reflected from the optical flat and passed through an auxiliary optic to then be combined with the reference beam on a CCD. The combined beams include phase errors due to both the optic under test and the auxiliary optic. Standard phase extraction algorithms are used to calculate this combined phase error. The optical flat is then removed from the system and the measurement fiber is moved to recombine the two beams. The newly combined beams include only the phase errors due to the auxiliary optic. When the second phase measurement is subtracted from the first phase measurement, the absolute phase error of the optical flat is obtained.

  6. Absolute calibration of remote sensing instruments

    NASA Astrophysics Data System (ADS)

    Biggar, S. F.; Bruegge, C. J.; Capron, B. A.; Castle, K. R.; Dinguirard, M. C.; Holm, R. G.; Lingg, L. J.; Mao, Y.; Palmer, J. M.; Phillips, A. L.

    1985-12-01

    Source-based and detector-based methods for the absolute radiometric calibration of a broadband field radiometer are described. Using such a radiometer, calibrated by both methods, the calibration of the integrating sphere used in the preflight calibration of the Thematic Mapper was redetermined. The results are presented. The in-flight calibration of space remote sensing instruments is discussed. A method which uses the results of ground-based reflectance and atmospheric measurements as input to a radiative transfer code to predict the radiance at the instrument is described. A calibrated, helicopter-mounted radiometer is used to determine the radiance levels at intermediate altitudes to check the code predictions. Results of such measurements for the calibration of the Thematic Mapper on Landsat 5 and an analysis that shows the value of such measurements are described.

  7. Absolute calibration of the Auger fluorescence detectors

    SciTech Connect

    Bauleo, P.; Brack, J.; Garrard, L.; Harton, J.; Knapik, R.; Meyhandan, R.; Rovero, A.C.; Tamashiro, A.; Warner, D.

    2005-07-01

    Absolute calibration of the Pierre Auger Observatory fluorescence detectors uses a light source at the telescope aperture. The technique accounts for the combined effects of all detector components in a single measurement. The calibrated 2.5 m diameter light source fills the aperture, providing uniform illumination to each pixel. The known flux from the light source and the response of the acquisition system give the required calibration for each pixel. In the lab, light source uniformity is studied using CCD images and the intensity is measured relative to NIST-calibrated photodiodes. Overall uncertainties are presently 12%, and are dominated by systematics.

  8. Pleiades Absolute Calibration : Inflight Calibration Sites and Methodology

    NASA Astrophysics Data System (ADS)

    Lachérade, S.; Fourest, S.; Gamet, P.; Lebègue, L.

    2012-07-01

    In-flight calibration of space sensors once in orbit is a decisive step to be able to fulfil the mission objectives. This article presents the methods of the in-flight absolute calibration processed during the commissioning phase. Four In-flight calibration methods are used: absolute calibration, cross-calibration with reference sensors such as PARASOL or MERIS, multi-temporal monitoring and inter-bands calibration. These algorithms are based on acquisitions over natural targets such as African deserts, Antarctic sites, La Crau (Automatic calibration station) and Oceans (Calibration over molecular scattering) or also new extra-terrestrial sites such as the Moon and selected stars. After an overview of the instrument and a description of the calibration sites, it is pointed out how each method is able to address one or several aspects of the calibration. We focus on how these methods complete each other in their operational use, and how they help building a coherent set of information that addresses all aspects of in-orbit calibration. Finally, we present the perspectives that the high level of agility of PLEIADES offers for the improvement of its calibration and a better characterization of the calibration sites.

  9. Absolute Radiometric Calibration Of The Thematic Mapper

    NASA Astrophysics Data System (ADS)

    Slater, P. N.; Biggar, S. F.; Holm, R. G.; Jackson, R. D.; Mao, Y.; Moran, M. S.; Palmer, J. M.; Yuan, B.

    1986-11-01

    The results are presented of five in-flight absolute radiometric calibrations, made in the period July 1984 to November 1985, at White Sands, New Mexico, of the solar reflective bands of the Landsat-5 Thematic Mapper (TM) . The 23 bandcalibrations made on the five dates show a ± 2.8% RMS variation from the mean as a percentage of the mean.

  10. Absolute Radiometric Calibration of EUNIS-06

    NASA Technical Reports Server (NTRS)

    Thomas, R. J.; Rabin, D. M.; Kent, B. J.; Paustian, W.

    2007-01-01

    The Extreme-Ultraviolet Normal-Incidence Spectrometer (EUNIS) is a soundingrocket payload that obtains imaged high-resolution spectra of individual solar features, providing information about the Sun's corona and upper transition region. Shortly after its successful initial flight last year, a complete end-to-end calibration was carried out to determine the instrument's absolute radiometric response over its Longwave bandpass of 300 - 370A. The measurements were done at the Rutherford-Appleton Laboratory (RAL) in England, using the same vacuum facility and EUV radiation source used in the pre-flight calibrations of both SOHO/CDS and Hinode/EIS, as well as in three post-flight calibrations of our SERTS sounding rocket payload, the precursor to EUNIS. The unique radiation source provided by the Physikalisch-Technische Bundesanstalt (PTB) had been calibrated to an absolute accuracy of 7% (l-sigma) at 12 wavelengths covering our bandpass directly against the Berlin electron storage ring BESSY, which is itself a primary radiometric source standard. Scans of the EUNIS aperture were made to determine the instrument's absolute spectral sensitivity to +- 25%, considering all sources of error, and demonstrate that EUNIS-06 was the most sensitive solar E W spectrometer yet flown. The results will be matched against prior calibrations which relied on combining measurements of individual optical components, and on comparisons with theoretically predicted 'insensitive' line ratios. Coordinated observations were made during the EUNIS-06 flight by SOHO/CDS and EIT that will allow re-calibrations of those instruments as well. In addition, future EUNIS flights will provide similar calibration updates for TRACE, Hinode/EIS, and STEREO/SECCHI/EUVI.

  11. The Carina Project: Absolute and Relative Calibrations

    NASA Astrophysics Data System (ADS)

    Corsi, C. E.; Bono, G.; Walker, A. R.; Brocato, E.; Buonanno, R.; Caputo, F.; Castellani, M.; Castellani, V.; Dall'Ora, M.; Marconi, M.; Monelli, M.; Nonino, M.; Pulone, L.; Ripepi, V.; Smith, H. A.

    We discuss the reduction strategy adopted to perform the relative and the absolute calibration of the Wide Field Imager (WFI) available at the 2.2m ESO/MPI telescope and of the Mosaic Camera (MC) available at the 4m CTIO Blanco telescope. To properly constrain the occurrence of deceptive systematic errors in the relative calibration we observed with each chip the same set of stars. Current photometry seems to suggest that the WFI shows a positional effect when moving from the top to the bottom of individual chips. Preliminary results based on an independent data set collected with the MC suggest that this camera is only marginally affected by the same problem. To perform the absolute calibration we observed with each chip the same set of standard stars. The sample covers a wide color range and the accuracy both in the B and in the V-band appears to be of the order of a few hundredths of magnitude. Finally, we briefly outline the observing strategy to improve both relative and absolute calibrations of mosaic CCD cameras.

  12. The Absolute Radiometric Calibration of Space - Sensors.

    NASA Astrophysics Data System (ADS)

    Holm, Ronald Gene

    1987-09-01

    The need for absolute radiometric calibration of space-based sensors will continue to increase as new generations of space sensors are developed. A reflectance -based in-flight calibration procedure is used to determine the radiance reaching the entrance pupil of the sensor. This procedure uses ground-based measurements coupled with a radiative transfer code to characterize the effects the atmosphere has on the signal reaching the sensor. The computed radiance is compared to the digital count output of the sensor associated with the image of a test site. This provides an update to the preflight calibration of the system and a check on the on-board internal calibrator. This calibration procedure was used to perform a series of five calibrations of the Landsat-5 Thematic Mapper (TM). For the 12 measurements made in TM bands 1-3, the RMS variation from the mean as a percentage of the mean is (+OR-) 1.9%, and for measurements in the IR, TM bands 4,5, and 7, the value is (+OR-) 3.4%. The RMS variation for all 23 measurements is (+OR-) 2.8%. The absolute calibration techniques were put to another test with a series of three calibration of the SPOT-1 High Resolution Visible, (HRV), sensors. The ratio, HRV-2/HRV-1, of absolute calibration coefficients compared very well with ratios of histogrammed data obtained when the cameras simultaneously imaged the same ground site. Bands PA, B1 and B3 agreed to within 3%, while band B2 showed a 7% difference. The procedure for performing a satellite calibration was then used to demonstrate how a calibrated satellite sensor can be used to quantitatively evaluate surface reflectance over a wide range of surface features. Predicted reflectance factors were compared to values obtained from aircraft -based radiometer data. This procedure was applied on four dates with two different surface conditions per date. A strong correlation, R('2) = .996, was shown between reflectance values determined from satellite imagery and low-flying aircraft

  13. Sentinel-2/MSI absolute calibration: first results

    NASA Astrophysics Data System (ADS)

    Lonjou, V.; Lachérade, S.; Fougnie, B.; Gamet, P.; Marcq, S.; Raynaud, J.-L.; Tremas, T.

    2015-10-01

    Sentinel-2 is an optical imaging mission devoted to the operational monitoring of land and coastal areas. It is developed in partnership between the European Commission and the European Space Agency. The Sentinel-2 mission is based on a satellites constellation deployed in polar sun-synchronous orbit. It will offer a unique combination of global coverage with a wide field of view (290km), a high revisit (5 days with two satellites), a high resolution (10m, 20m and 60m) and multi-spectral imagery (13 spectral bands in visible and shortwave infra-red domains). CNES is involved in the instrument commissioning in collaboration with ESA. This paper reviews all the techniques that will be used to insure an absolute calibration of the 13 spectral bands better than 5% (target 3%), and will present the first results if available. First, the nominal calibration technique, based on an on-board sun diffuser, is detailed. Then, we show how vicarious calibration methods based on acquisitions over natural targets (oceans, deserts, and Antarctica during winter) will be used to check and improve the accuracy of the absolute calibration coefficients. Finally, the verification scheme, exploiting photometer in-situ measurements over Lacrau plain, is described. A synthesis, including spectral coherence, inter-methods agreement and temporal evolution, will conclude the paper.

  14. Absolute radiometric calibration of the CCRS SAR

    NASA Astrophysics Data System (ADS)

    Ulander, Lars M. H.; Hawkins, Robert K.; Livingstone, Charles E.; Lukowski, Tom I.

    1991-11-01

    Determining the radar scattering coefficients from SAR (synthetic aperture radar) image data requires absolute radiometric calibration of the SAR system. The authors describe an internal calibration methodology for the airborne Canada Centre for Remote Sensing (CCRS) SAR system, based on radar theory, a detailed model of the radar system, and measurements of system parameters. The methodology is verified by analyzing external calibration data acquired over a 6-month period in 1988 by the C-band radar using HH polarization. The results indicate that the overall error is +/- 0.8 dB (1-sigma) for incidence angles +/- 20 deg from antenna boresight. The dominant error contributions are due to the antenna radome and uncertainties in the elevation angle relative to the antenna boresight.

  15. Absolute radiometric calibration of the Thematic Mapper

    NASA Technical Reports Server (NTRS)

    Slater, P. N.; Biggar, S. F.; Holm, R. G.; Jackson, R. D.; Mao, Y.

    1986-01-01

    Calibration data for the solar reflective bands of the Landsat-5 TM obtained from five in-flight absolute radiometric calibrations from July 1984-November 1985 at White Sands, New Mexico are presented and analyzed. Ground reflectance and atmospheric data were utilized to predict the spectral radiance at the entrance pupil of the TM and the average number of digital counts in each TM band. The calibration of each of the TM solar reflective bands was calculated in terms of average digital counts/unit spectral radiance for each band. It is observed that for the 12 reflectance-based measurements the rms variation from the means as a percentage of the mean is + or - 1.9 percent; for the 11 measurements in the IR bands, it is + or - 3.4 percent; and the rms variation for all 23 measurements is + or - 2.8 percent.

  16. Precision Spectrophotometric Calibration System for Dark Energy Instruments

    SciTech Connect

    Schubnell, Michael S.

    2015-06-30

    For this research we build a precision calibration system and carried out measurements to demonstrate the precision that can be achieved with a high precision spectrometric calibration system. It was shown that the system is capable of providing a complete spectrophotometric calibration at the sub-pixel level. The calibration system uses a fast, high precision monochromator that can quickly and efficiently scan over an instrument’s entire spectral range with a spectral line width of less than 0.01 nm corresponding to a fraction of a pixel on the CCD. The system was extensively evaluated in the laboratory. Our research showed that a complete spectrophotometric calibration standard for spectroscopic survey instruments such as DESI is possible. The monochromator precision and repeatability to a small fraction of the DESI spectrograph LSF was demonstrated with re-initialization on every scan and thermal drift compensation by locking to multiple external line sources. A projector system that mimics telescope aperture for point source at infinity was demonstrated.

  17. Absolute Radiometric Calibration of KOMPSAT-3A

    NASA Astrophysics Data System (ADS)

    Ahn, H. Y.; Shin, D. Y.; Kim, J. S.; Seo, D. C.; Choi, C. U.

    2016-06-01

    This paper presents a vicarious radiometric calibration of the Korea Multi-Purpose Satellite-3A (KOMPSAT-3A) performed by the Korea Aerospace Research Institute (KARI) and the Pukyong National University Remote Sensing Group (PKNU RSG) in 2015.The primary stages of this study are summarized as follows: (1) A field campaign to determine radiometric calibrated target fields was undertaken in Mongolia and South Korea. Surface reflectance data obtained in the campaign were input to a radiative transfer code that predicted at-sensor radiance. Through this process, equations and parameters were derived for the KOMPSAT-3A sensor to enable the conversion of calibrated DN to physical units, such as at-sensor radiance or TOA reflectance. (2) To validate the absolute calibration coefficients for the KOMPSAT-3A sensor, we performed a radiometric validation with a comparison of KOMPSAT-3A and Landsat-8 TOA reflectance using one of the six PICS (Libya 4). Correlations between top-of-atmosphere (TOA) radiances and the spectral band responses of the KOMPSAT-3A sensors at the Zuunmod, Mongolia and Goheung, South Korea sites were significant for multispectral bands. The average difference in TOA reflectance between KOMPSAT-3A and Landsat-8 image over the Libya 4, Libya site in the red-green-blue (RGB) region was under 3%, whereas in the NIR band, the TOA reflectance of KOMPSAT-3A was lower than the that of Landsat-8 due to the difference in the band passes of two sensors. The KOMPSAT-3Aensor includes a band pass near 940 nm that can be strongly absorbed by water vapor and therefore displayed low reflectance. Toovercome this, we need to undertake a detailed analysis using rescale methods, such as the spectral bandwidth adjustment factor.

  18. Absolute calibration of ultraviolet filter photometry

    NASA Technical Reports Server (NTRS)

    Bless, R. C.; Fairchild, T.; Code, A. D.

    1972-01-01

    The essential features of the calibration procedure can be divided into three parts. First, the shape of the bandpass of each photometer was determined by measuring the transmissions of the individual optical components and also by measuring the response of the photometer as a whole. Secondly, each photometer was placed in the essentially-collimated synchrotron radiation bundle maintained at a constant intensity level, and the output signal was determined from about 100 points on the objective. Finally, two or three points on the objective were illuminated by synchrotron radiation at several different intensity levels covering the dynamic range of the photometers. The output signals were placed on an absolute basis by the electron counting technique described earlier.

  19. Issues in Absolute Spectral Radiometric Calibration: Intercomparison of Eight Sources

    NASA Technical Reports Server (NTRS)

    Goetz, Alexander F. H.; Kindel, Bruce; Pilewskie, Peter

    1998-01-01

    The application of atmospheric models to AVIRIS and other spectral imaging data to derive surface reflectance requires that the sensor output be calibrated to absolute radiance. Uncertainties in absolute calibration are to be expected, and claims of 92% accuracy have been published. Measurements of accurate surface albedos and cloud absorption to be used in radiative balance calculations depend critically on knowing the absolute spectral-radiometric response of the sensor. The Earth Observing System project is implementing a rigorous program of absolute radiometric calibration for all optical sensors. Since a number of imaging instruments that provide output in terms of absolute radiance are calibrated at different sites, it is important to determine the errors that can be expected among calibration sites. Another question exists about the errors in the absolute knowledge of the exoatmospheric spectral solar irradiance.

  20. Absolute radiometric calibration of advanced remote sensing systems

    NASA Technical Reports Server (NTRS)

    Slater, P. N.

    1982-01-01

    The distinction between the uses of relative and absolute spectroradiometric calibration of remote sensing systems is discussed. The advantages of detector-based absolute calibration are described, and the categories of relative and absolute system calibrations are listed. The limitations and problems associated with three common methods used for the absolute calibration of remote sensing systems are addressed. Two methods are proposed for the in-flight absolute calibration of advanced multispectral linear array systems. One makes use of a sun-illuminated panel in front of the sensor, the radiance of which is monitored by a spectrally flat pyroelectric radiometer. The other uses a large, uniform, high-radiance reference ground surface. The ground and atmospheric measurements required as input to a radiative transfer program to predict the radiance level at the entrance pupil of the orbital sensor are discussed, and the ground instrumentation is described.

  1. Absolute calibration of sniffer probes on Wendelstein 7-X

    NASA Astrophysics Data System (ADS)

    Moseev, D.; Laqua, H. P.; Marsen, S.; Stange, T.; Braune, H.; Erckmann, V.; Gellert, F.; Oosterbeek, J. W.

    2016-08-01

    Here we report the first measurements of the power levels of stray radiation in the vacuum vessel of Wendelstein 7-X using absolutely calibrated sniffer probes. The absolute calibration is achieved by using calibrated sources of stray radiation and the implicit measurement of the quality factor of the Wendelstein 7-X empty vacuum vessel. Normalized absolute calibration coefficients agree with the cross-calibration coefficients that are obtained by the direct measurements, indicating that the measured absolute calibration coefficients and stray radiation levels in the vessel are valid. Close to the launcher, the stray radiation in the empty vessel reaches power levels up to 340 kW/m2 per MW injected beam power. Furthest away from the launcher, i.e., half a toroidal turn, still 90 kW/m2 per MW injected beam power is measured.

  2. Absolute calibration of sniffer probes on Wendelstein 7-X.

    PubMed

    Moseev, D; Laqua, H P; Marsen, S; Stange, T; Braune, H; Erckmann, V; Gellert, F; Oosterbeek, J W

    2016-08-01

    Here we report the first measurements of the power levels of stray radiation in the vacuum vessel of Wendelstein 7-X using absolutely calibrated sniffer probes. The absolute calibration is achieved by using calibrated sources of stray radiation and the implicit measurement of the quality factor of the Wendelstein 7-X empty vacuum vessel. Normalized absolute calibration coefficients agree with the cross-calibration coefficients that are obtained by the direct measurements, indicating that the measured absolute calibration coefficients and stray radiation levels in the vessel are valid. Close to the launcher, the stray radiation in the empty vessel reaches power levels up to 340 kW/m(2) per MW injected beam power. Furthest away from the launcher, i.e., half a toroidal turn, still 90 kW/m(2) per MW injected beam power is measured. PMID:27587121

  3. A practical method for sensor absolute calibration.

    PubMed

    Meisenholder, G W

    1966-04-01

    This paper describes a method of performing sensor calibrations using an NBS standard of spectral irradiance. The method shown, among others, was used for calibration of the Mariner IV Canopus sensor. Agreement of inflight response to preflight calibrations performed by this technique has been found to be well within 10%. PMID:20048890

  4. Absolute Antenna Calibration at the US National Geodetic Survey

    NASA Astrophysics Data System (ADS)

    Mader, G. L.; Bilich, A. L.

    2012-12-01

    Geodetic GNSS applications routinely demand millimeter precision and extremely high levels of accuracy. To achieve these accuracies, measurement and instrument biases at the centimeter to millimeter level must be understood. One of these biases is the antenna phase center, the apparent point of signal reception for a GNSS antenna. It has been well established that phase center patterns differ between antenna models and manufacturers; additional research suggests that the addition of a radome or the choice of antenna mount can significantly alter those a priori phase center patterns. For the more demanding GNSS positioning applications and especially in cases of mixed-antenna networks, it is all the more important to know antenna phase center variations as a function of both elevation and azimuth in the antenna reference frame and incorporate these models into analysis software. Determination of antenna phase center behavior is known as "antenna calibration". Since 1994, NGS has computed relative antenna calibrations for more than 350 antennas. In recent years, the geodetic community has moved to absolute calibrations - the IGS adopted absolute antenna phase center calibrations in 2006 for use in their orbit and clock products, and NGS's CORS group began using absolute antenna calibration upon the release of the new CORS coordinates in IGS08 epoch 2005.00 and NAD 83(2011,MA11,PA11) epoch 2010.00. Although NGS relative calibrations can be and have been converted to absolute, it is considered best practice to independently measure phase center characteristics in an absolute sense. Consequently, NGS has developed and operates an absolute calibration system. These absolute antenna calibrations accommodate the demand for greater accuracy and for 2-dimensional (elevation and azimuth) parameterization. NGS will continue to provide calibration values via the NGS web site www.ngs.noaa.gov/ANTCAL, and will publish calibrations in the ANTEX format as well as the legacy ANTINFO

  5. System and method for calibrating a rotary absolute position sensor

    NASA Technical Reports Server (NTRS)

    Davis, Donald R. (Inventor); Permenter, Frank Noble (Inventor); Radford, Nicolaus A (Inventor)

    2012-01-01

    A system includes a rotary device, a rotary absolute position (RAP) sensor generating encoded pairs of voltage signals describing positional data of the rotary device, a host machine, and an algorithm. The algorithm calculates calibration parameters usable to determine an absolute position of the rotary device using the encoded pairs, and is adapted for linearly-mapping an ellipse defined by the encoded pairs to thereby calculate the calibration parameters. A method of calibrating the RAP sensor includes measuring the rotary position as encoded pairs of voltage signals, linearly-mapping an ellipse defined by the encoded pairs to thereby calculate the calibration parameters, and calculating an absolute position of the rotary device using the calibration parameters. The calibration parameters include a positive definite matrix (A) and a center point (q) of the ellipse. The voltage signals may include an encoded sine and cosine of a rotary angle of the rotary device.

  6. Absolute flux density calibrations: Receiver saturation effects

    NASA Technical Reports Server (NTRS)

    Freiley, A. J.; Ohlson, J. E.; Seidel, B. L.

    1978-01-01

    The effect of receiver saturation was examined for a total power radiometer which uses an ambient load for calibration. Extension to other calibration schemes is indicated. The analysis shows that a monotonic receiver saturation characteristic could cause either positive or negative measurement errors, with polarity depending upon operating conditions. A realistic model of the receiver was made by using a linear-cubic voltage transfer characteristic. The evaluation of measurement error for this model provided a means for correcting radio source measurements.

  7. Absolute calibration technique for broadband ultrasonic transducers

    NASA Technical Reports Server (NTRS)

    Yost, William T. (Inventor); Cantrell, John H. (Inventor)

    1994-01-01

    Calibrating an ultrasonic transducer can be performed with a reduced number of calculations and testing. A wide-band pulser is connected to an ultrasonic transducer under test to generate ultrasonic waves in a liquid. A single frequency is transmitted to the electrostatic acoustic transducer (ESAT) and the voltage change produced is monitored. Then a broadband ultrasonic pulse is generated by the ultrasonic transducer and received by the ESAT. The output of the ESAT is amplified and input to a digitized oscilloscope for fast Fourier transform. The resulting plot is normalized with the monitored signal from the single frequency pulse. The plot is then corrected for characteristics of the membrane and diffraction effects. The transfer function of the final plot is determined. The transfer function gives the final sensitivity of the ultrasonic transducer as a function of frequency. The advantage of the system is the speed of calibrating the transducer by a reduced number of measurements and removal of the membrane and diffraction effects.

  8. SDSS-IV/MaNGA: Spectrophotometric Calibration Technique

    NASA Astrophysics Data System (ADS)

    Yan, Renbin; Tremonti, Christy; Bershady, Matthew A.; Law, David R.; Schlegel, David J.; Bundy, Kevin; Drory, Niv; MacDonald, Nicholas; Bizyaev, Dmitry; Blanc, Guillermo A.; Blanton, Michael R.; Cherinka, Brian; Eigenbrot, Arthur; Gunn, James E.; Harding, Paul; Hogg, David W.; Sánchez-Gallego, José R.; Sánchez, Sebastian F.; Wake, David A.; Weijmans, Anne-Marie; Xiao, Ting; Zhang, Kai

    2016-01-01

    Mapping Nearby Galaxies at Apache Point Observatory (MaNGA), one of three core programs in the Sloan Digital Sky Survey-IV, is an integral-field spectroscopic survey of roughly 10,000 nearby galaxies. It employs dithered observations using 17 hexagonal bundles of 2″ fibers to obtain resolved spectroscopy over a wide wavelength range of 3600-10300 Å. To map the internal variations within each galaxy, we need to perform accurate spectral surface photometry, which is to calibrate the specific intensity at every spatial location sampled by each individual aperture element of the integral field unit. The calibration must correct only for the flux loss due to atmospheric throughput and the instrument response, but not for losses due to the finite geometry of the fiber aperture. This requires the use of standard star measurements to strictly separate these two flux loss factors (throughput versus geometry), a difficult challenge with standard single-fiber spectroscopy techniques due to various practical limitations. Therefore, we developed a technique for spectral surface photometry using multiple small fiber-bundles targeting standard stars simultaneously with galaxy observations. We discuss the principles of our approach and how they compare to previous efforts, and we demonstrate the precision and accuracy achieved. MaNGA's relative calibration between the wavelengths of Hα and Hβ has an rms of 1.7%, while that between [N ii] λ6583 and [O ii] λ3727 has an rms of 4.7%. Using extinction-corrected star formation rates and gas-phase metallicities as an illustration, this level of precision guarantees that flux calibration errors will be sub-dominant when estimating these quantities. The absolute calibration is better than 5% for more than 89% of MaNGA's wavelength range.

  9. GNSS Absolute Antenna Calibration at the National Geodetic Survey

    NASA Astrophysics Data System (ADS)

    Mader, G. L.; Bilich, A. L.; Geoghegan, C.

    2011-12-01

    Geodetic GNSS applications routinely demand millimeter precision and extremely high levels of accuracy. To achieve these accuracies, measurement and instrument biases at the centimeter to millimeter level must be understood. One of these biases is the antenna phase center, the apparent point of signal reception for a GNSS antenna. It has been well established that phase center patterns differ between antenna models and manufacturers; additional research suggests that the addition of a radome or the choice of antenna mount can significantly alter those a priori phase center patterns. For the more demanding GNSS positioning applications and especially in cases of mixed-antenna networks, it is all the more important to know antenna phase center variations as a function of both elevation and azimuth in the antenna reference frame and incorporate these models into analysis software. To help meet the needs of the high-precision GNSS community, the National Geodetic Survey (NGS) now operates an absolute antenna calibration facility. Located in Corbin, Virginia, this facility uses field measurements and actual GNSS satellite signals to quantitatively determine the carrier phase advance/delay introduced by the antenna element. The NGS facility was built to serve traditional NGS constituents such as the surveying and geodesy communities, however calibration services are open and available to all GNSS users as the calibration schedule permits. All phase center patterns computed by this facility will be publicly available and disseminated in both the ANTEX and NGS formats. We describe the NGS calibration facility, and discuss the observation models and strategy currently used to generate NGS absolute calibrations. We demonstrate that NGS absolute phase center variation (PCV) patterns are consistent with published values determined by other absolute antenna calibration facilities, and compare absolute calibrations to the traditional NGS relative calibrations.

  10. Prelaunch absolute radiometric calibration of LANDSAT-4 protoflight Thematic Mapper

    NASA Technical Reports Server (NTRS)

    Barker, J. L.; Ball, D. L.; Leung, K. C.; Walker, J. A.

    1984-01-01

    Results are summarized and analyzed from several prelaunch tests with a 122 cm integrating sphere used as part of the absolute radiometric calibration experiments for the protoflight TM sensor carried on the LANDSAT-4 satellite. The calibration procedure is presented and the radiometric sensitivity of the TM is assessed. The internal calibrator and dynamic range after calibration are considered. Tables show dynamic range after ground processing, spectral radiance to digital number and digital number to spectral radiance values for TM bands 1, 2, 3, 4, 5, 7 and for channel 4 of band 6.

  11. In-flight absolute radiometric calibration of the thematic mapper

    NASA Technical Reports Server (NTRS)

    Castle, K. R.; Holm, R. G.; Kastner, C. J.; Palmer, J. M.; Slater, P. N.; Dinguirard, M.; Ezra, C. E.; Jackson, R. D.; Savage, R. K.

    1983-01-01

    The TM multispectral scanner system was calibrated in an absolute manner before launch. To determine the temporal changes of the absolute radiometric calibration of the entire system, spectroradiometric measurements of the ground and the atmosphere were made simultaneously with TM collections over White Sands, New Mexico. By entering the measured values in an atmospheric radiative transfer program, the radiance levels of the in four of the spectral bands of the TM were determined. Tables show values for the reflectance of snow at White Sands measured by a modular 8 channel radiometer, and values for exoatmospheric irradiance within the TM passbands, calculated for the Earth-Sun distance using a solar radiometer.

  12. Landsat-5 TM reflective-band absolute radiometric calibration

    USGS Publications Warehouse

    Chander, G.; Helder, D.L.; Markham, B.L.; Dewald, J.D.; Kaita, E.; Thome, K.J.; Micijevic, E.; Ruggles, T.A.

    2004-01-01

    The Landsat-5 Thematic Mapper (TM) sensor provides the longest running continuous dataset of moderate spatial resolution remote sensing imagery, dating back to its launch in March 1984. Historically, the radiometric calibration procedure for this imagery used the instrument's response to the Internal Calibrator (IC) on a scene-by-scene basis to determine the gain and offset of each detector. Due to observed degradations in the IC, a new procedure was implemented for U.S.-processed data in May 2003. This new calibration procedure is based on a lifetime radiometric calibration model for the instrument's reflective bands (1-5 and 7) and is derived, in part, from the IC response without the related degradation effects and is tied to the cross calibration with the Landsat-7 Enhanced Thematic Mapper Plus. Reflective-band absolute radiometric accuracy of the instrument tends to be on the order of 7% to 10%, based on a variety of calibration methods.

  13. Absolute calibration and beam background of the Squid Polarimeter

    SciTech Connect

    Blaskiewicz, M.M.; Cameron, P.R.; Shea, T.J.

    1996-12-31

    The problem of beam background in Squid Polarimetry is not without residual benefits. The authors may deliberately generate beam background by gently kicking the beam at the spin tune frequency. This signal may be used to accomplish a simple and accurate absolute calibration of the polarimeter. The authors present details of beam background calculations and their application to polarimeter calibration, and suggest a simple proof-of-principle accelerator experiment.

  14. Absolute irradiance of the Moon for on-orbit calibration

    USGS Publications Warehouse

    Stone, T.C.; Kieffer, H.H.; ,

    2002-01-01

    The recognized need for on-orbit calibration of remote sensing imaging instruments drives the ROLO project effort to characterize the Moon for use as an absolute radiance source. For over 5 years the ground-based ROLO telescopes have acquired spatially-resolved lunar images in 23 VNIR (Moon diameter ???500 pixels) and 9 SWIR (???250 pixels) passbands at phase angles within ??90 degrees. A numerical model for lunar irradiance has been developed which fits hundreds of ROLO images in each band, corrected for atmospheric extinction and calibrated to absolute radiance, then integrated to irradiance. The band-coupled extinction algorithm uses absorption spectra of several gases and aerosols derived from MODTRAN to fit time-dependent component abundances to nightly observations of standard stars. The absolute radiance scale is based upon independent telescopic measurements of the star Vega. The fitting process yields uncertainties in lunar relative irradiance over small ranges of phase angle and the full range of lunar libration well under 0.5%. A larger source of uncertainty enters in the absolute solar spectral irradiance, especially in the SWIR, where solar models disagree by up to 6%. Results of ROLO model direct comparisons to spacecraft observations demonstrate the ability of the technique to track sensor responsivity drifts to sub-percent precision. Intercomparisons among instruments provide key insights into both calibration issues and the absolute scale for lunar irradiance.

  15. Lyman alpha SMM/UVSP absolute calibration and geocoronal correction

    NASA Technical Reports Server (NTRS)

    Fontenla, Juan M.; Reichmann, Edwin J.

    1987-01-01

    Lyman alpha observations from the Ultraviolet Spectrometer Polarimeter (UVSP) instrument of the Solar Maximum Mission (SMM) spacecraft were analyzed and provide instrumental calibration details. Specific values of the instrument quantum efficiency, Lyman alpha absolute intensity, and correction for geocoronal absorption are presented.

  16. Absolute calibration of Landsat instruments using the moon.

    USGS Publications Warehouse

    Kieffer, H.H.; Wildey, R.L.

    1985-01-01

    A lunar observation by Landsat could provide improved radiometric and geometric calibration of both the Thematic Mapper and the Multispectral Scanner in terms of absolute radiometry, determination of the modulation transfer function, and sensitivity to scattered light. A pitch of the spacecraft would be required. -Authors

  17. In-flight Absolute Radiometric Calibration of the Thematic Mapper

    NASA Technical Reports Server (NTRS)

    Castle, K. R.; Holm, R. G.; Kastner, C. J.; Palmer, J. M.; Slater, P. N.; Dinguirard, M.; Ezra, C. E.; Jackson, D.; Savage, R. K.

    1984-01-01

    The Thematic Mapper (TM) multispectral scanner system was placed into Earth orbit on July 16, 1982, as part of NASA's LANDSAT 4 payload. To determine temporal changes of the absolute radiometric calibration of the entire system in flight, spectroradiometric measurements of the ground and the atmosphere are made simultaneously with TM image acquisitions over the White Sands, New Mexico area. By entering the measured values into an atmospheric radiative transfer program, the radiance levels at the entrance pupil of the TM in four of the TM spectral bands are determined. These levels are compared to the output digital counts from the detectors that sampled the radiometrically measured ground area, thus providing an absolute radiometric calibration of the entire TM system utilizing those detectors. By reference to an adjacent, larger uniform area, the calibration is extended to all 16 detectors in each of the three bands.

  18. Absolute GNSS Antenna Calibration at the National Geodetic Survey

    NASA Astrophysics Data System (ADS)

    Mader, G.; Bilich, A.; Geoghegan, C.

    2012-04-01

    Geodetic GNSS applications routinely demand millimeter precision and extremely high levels of accuracy. To achieve these accuracies, measurement and instrument biases at the centimeter to millimeter level must be understood. One of these biases is the antenna phase center, the apparent point of signal reception for a GNSS antenna. It has been well established that phase center patterns differ between antenna models and manufacturers; additional research suggests that the addition of a radome or the choice of antenna mount can significantly alter those a priori phase center patterns. For the more demanding GNSS positioning applications and especially in cases of mixed-antenna networks, it is all the more important to know antenna phase center variations as a function of both elevation and azimuth in the antenna reference frame and incorporate these models into analysis software. To help meet the needs of the high-precision GNSS community, the National Geodetic Survey (NGS) now operates an absolute antenna calibration facility. Located in Corbin, Virginia, this facility uses field measurements and actual GNSS satellite signals to quantitatively determine the carrier phase advance/delay introduced by the antenna element. The NGS facility was built to serve traditional NGS constituents such as the surveying and geodesy communities, however calibration services are open and available to all GNSS users as the calibration schedule permits. All phase center patterns computed by this facility will be publicly available and disseminated in both the ANTEX and NGS formats. We describe the NGS calibration facility, and discuss the observation models and strategy currently used to generate NGS absolute calibrations. We demonstrate that NGS absolute phase center variation (PCV) patterns are consistent with published values determined by other absolute antenna calibration facilities, and outline future planned refinements to the system.

  19. The absolute radiometric calibration of space-based sensors

    NASA Astrophysics Data System (ADS)

    Holm, Ronald Gene

    A reflectance based inflight calibration procedure is used to determine the radiance reaching the entrance pupil of a sensor. This procedure uses ground based measurements coupled with a radiative transfer code to characterize the effects the atmosphere has on the signal reaching the sensor. The computed radiance is compared to the digital count output of the sensor associated with the image of a test site. This provides an update to the preflight calibration of the system and a check on the on-board internal calibrator. This calibration procedure was used to perform a series of 5 calibrations of the LANDSAT-5 Thematic Mapper. The absolute calibration techniques were put to another test with a series of 3 calibration of the SPOT-1 High Resolution Visible sensors. The procedure for performing a satellite calibration was then used to demonstrate how a calibrated satellite sensor can be used to quantitatively evaluate surface reflectance over a wide range of surface features. Predicted reflectance factors were compared to values obtained from aircraft based radiometer data. A strong correlation was shown between reflectance values determined from satellite imagery and low flying aircraft data.

  20. In-flight absolute radiometric calibration of the thematic mapper

    NASA Technical Reports Server (NTRS)

    Castle, K. R.; Holm, R. G.; Kastner, C. J.; Palmer, J. M.; Slater, P. N.; Dinguirard, M.; Ezra, C. E.; Jackson, R. D.; Savage, R. K.

    1984-01-01

    In order to determine temporal changes of the absolute radiometric calibration of the entire TM system in flight spectroradiometric measurements of the ground and the atmosphere were made simultaneously with TM image collections over the White Sands, New Mexico area. By entering the measured values in an atmospheric radiative transfer program, the radiance levels in four of the spectral bands of the TM were determined, band 1:0.45 to 0.52 micrometers, band 2:0.53 to 0.61 micrometers band 3:0.62 to 0.70 micrometers and 4:0.78 to 0.91 micrometers. These levels were compared to the output digital counts from the detectors that sampled the radiometrically measured ground area, thus providing an absolute radiometric calibration of the entire TM system utilizing those detectors.

  1. In-flight absolute radiometric calibration of the Thematic Mapper

    NASA Technical Reports Server (NTRS)

    Castle, K. R.; Holm, R. G.; Kastner, C. J.; Palmer, J. M.; Slater, P. N.; Dinguirard, M.; Ezra, C. E.; Jackson, R. D.; Savage, R. K.

    1984-01-01

    In order to determine temporal changes of the absolute radiometric calibration of the entire TM system in flight spectroradiometric measurements of the ground and the atmosphere were made simultaneously with TM image collections over the White Sands, NM area. By entering the measured values in an atmospheric radiative transfer program, the radiance levels in four of the spectral bands of the TM were determined, band 1: 0.45 to 0.52 micrometers, band 2: 0.53 to 0.61 micrometers, band 3: 0.62 to 0.70 micrometers, and 4: 0.78 to 0.91 micrometers. These levels were compared to the output digital counts from the detectors that sampled the radiometrically measured ground area, thus providing an absolute radiometric calibration of the entire TM system utilizing those detectors. Previously announced in STAR as N84-15633

  2. Landsat-7 ETM+ radiometric stability and absolute calibration

    USGS Publications Warehouse

    Markham, B.L.; Barker, J.L.; Barsi, J.A.; Kaita, E.; Thome, K.J.; Helder, D.L.; Palluconi, Frank Don; Schott, J.R.; Scaramuzza, P.; ,

    2002-01-01

    Launched in April 1999, the Landsat-7 ETM+ instrument is in its fourth year of operation. The quality of the acquired calibrated imagery continues to be high, especially with respect to its three most important radiometric performance parameters: reflective band instrument stability to better than ??1%, reflective band absolute calibration to better than ??5%, and thermal band absolute calibration to better than ??0.6 K. The ETM+ instrument has been the most stable of any of the Landsat instruments, in both the reflective and thermal channels. To date, the best on-board calibration source for the reflective bands has been the Full Aperture Solar Calibrator, which has indicated changes of at most -1.8% to -2.0% (95% C.I.) change per year in the ETM+ gain (band 4). However, this change is believed to be caused by changes in the solar diffuser panel, as opposed to a change in the instrument's gain. This belief is based partially on ground observations, which bound the changes in gain in band 4 at -0.7% to +1.5%. Also, ETM+ stability is indicated by the monitoring of desert targets. These image-based results for four Saharan and Arabian sites, for a collection of 35 scenes over the three years since launch, bound the gain change at -0.7% to +0.5% in band 4. Thermal calibration from ground observations revealed an offset error of +0.31 W/m 2 sr um soon after launch. This offset was corrected within the U. S. ground processing system at EROS Data Center on 21-Dec-00, and since then, the band 6 on-board calibration has indicated changes of at most +0.02% to +0.04% (95% C.I.) per year. The latest ground observations have detected no remaining offset error with an RMS error of ??0.6 K. The stability and absolute calibration of the Landsat-7 ETM+ sensor make it an ideal candidate to be used as a reference source for radiometric cross-calibrating to other land remote sensing satellite systems.

  3. Landsat-7 ETM+ radiometric stability and absolute calibration

    NASA Astrophysics Data System (ADS)

    Markham, Brian L.; Barker, John L.; Barsi, Julia A.; Kaita, Ed; Thome, Kurtis J.; Helder, Dennis L.; Palluconi, Frank D.; Schott, John R.; Scaramuzza, Pat

    2003-04-01

    Launched in April 1999, the Landsat-7 ETM+ instrument is in its fourth year of operation. The quality of the acquired calibrated imagery continues to be high, especially with respect to its three most important radiometric performance parameters: reflective band instrument stability to better than +/-1%, reflective band absolute calibration to better than +/-5%, and thermal band absolute calibration to better than +/- 0.6 K. The ETM+ instrument has been the most stable of any of the Landsat instruments, in both the reflective and thermal channels. To date, the best on-board calibration source for the reflective bands has been the Full Aperture Solar Calibrator, which has indicated changes of at most -1.8% to -2.0% (95% C.I.) change per year in the ETM+ gain (band 4). However, this change is believed to be caused by changes in the solar diffuser panel, as opposed to a change in the instrument's gain. This belief is based partially on ground observations, which bound the changes in gain in band 4 at -0.7% to +1.5%. Also, ETM+ stability is indicated by the monitoring of desert targets. These image-based results for four Saharan and Arabian sites, for a collection of 35 scenes over the three years since launch, bound the gain change at -0.7% to +0.5% in band 4. Thermal calibration from ground observations revealed an offset error of +0.31 W/m2 sr um soon after launch. This offset was corrected within the U. S. ground processing system at EROS Data Center on 21-Dec-00, and since then, the band 6 on-board calibration has indicated changes of at most +0.02% to +0.04% (95% C.I.) per year. The latest ground observations have detected no remaining offset error with an RMS error of +/- 0.6 K. The stability and absolute calibration of the Landsat-7 ETM+ sensor make it an ideal candidate to be used as a reference source for radiometric cross-calibrating to other land remote sensing satellite systems.

  4. Absolute calibration in the 1750 - 3350 A region

    NASA Technical Reports Server (NTRS)

    Strongylis, G. J.; Bohlin, R. C.

    1977-01-01

    The absolute flux measurements in the rocket ultraviolet made by Bohlin, Frimout, and Lillie (BFL) are revised using a more correct treatment of the air extinction that enters the air calibration of their instrument. The absorption by molecular oxygen and ozone, Rayleigh scattering, and extinction by aerosols is tabulated for general use in ultraviolet calibrations performed in air. The revised absolute flux of eta UMa and final fluxes for alpha Lyr and zeta Oph are presented in the 1750-3350 A region. The absolute flux of the star eta UMa is compared to four other independent determinations in the 1200-3400 A region and a maximum difference of 35% is found near 1500 A between the OAO-2 and Apollo 17 fluxes. The rocket measurements of BFL, the ANS and TD-1 satellite data, and the Apollo 17 data are compared to the ultraviolet fluxes from the OAO-2, demonstrating a photometric reproducibility of about + or - 3 percent. Therefore, all four sets of spectrophotometry can be reduced to a common absolute scale.

  5. Updated Absolute Flux Calibration of the COS FUV Modes

    NASA Astrophysics Data System (ADS)

    Massa, D.; Ely, J.; Osten, R.; Penton, S.; Aloisi, A.; Bostroem, A.; Roman-Duval, J.; Proffitt, C.

    2014-03-01

    We present newly derived point source absolute flux calibrations for the COS FUV modes at both the original and second lifetime positions. The analysis includes observa- tions through the Primary Science Aperture (PSA) of the standard stars WD0308-565, GD71, WD1057+729 and WD0947+857 obtained as part of two calibration programs. Data were were obtained for all of the gratings at all of the original CENWAVE settings at both the original and second lifetime positions and for the G130M CENWAVE = 1222 at the second lifetime position. Data were also obtained with the FUVB segment for the G130M CENWAVE = 1055 and 1096 setting at the second lifetime position. We also present the derivation of L-flats that were used in processing the data and show that the internal consistency of the primary standards is 1%. The accuracy of the absolute flux calibrations over the UV are estimated to be 1-2% for the medium resolution gratings, and 2-3% over most of the wavelength range of the G140L grating, although the uncertainty can be as large as 5% or more at some G140L wavelengths. We note that these errors are all relative to the optical flux near the V band and small additional errors may be present due to inaccuracies in the V band calibration. In addition, these error estimates are for the time at which the flux calibration data were obtained; the accuracy of the flux calibration at other times can be affected by errors in the time dependent sensitivity (TDS) correction.

  6. On the Error Sources in Absolute Individual Antenna Calibrations

    NASA Astrophysics Data System (ADS)

    Aerts, Wim; Baire, Quentin; Bilich, Andria; Bruyninx, Carine; Legrand, Juliette

    2013-04-01

    field) multi path errors, both during calibration and later on at the station, absolute sub-millimeter positioning with GPS is not (yet) possible. References [1] G. Wübbena, M. Schmitz, G. Boettcher, C. Schumann, "Absolute GNSS Antenna Calibration with a Robot: Repeatability of Phase Variations, Calibration of GLONASS and Determination of Carrier-to-Noise Pattern", International GNSS Service: Analysis Center workshop, 8-12 May 2006, Darmstadt, Germany. [2] P. Zeimetz, H. Kuhlmann, "On the Accuracy of Absolute GNSS Antenna Calibration and the Conception of a New Anechoic Chamber", FIG Working Week 2008, 14-19 June 2008, Stockholm, Sweden. [3] P. Zeimetz, H. Kuhlmann, L. Wanninger, V. Frevert, S. Schön and K. Strauch, "Ringversuch 2009", 7th GNSS-Antennen-Workshop, 19-20 March 2009, Dresden, Germany.

  7. Absolute calibration for complex-geometry biomedical diffuse optical spectroscopy

    NASA Astrophysics Data System (ADS)

    Mastanduno, Michael A.; Jiang, Shudong; El-Ghussein, Fadi; diFlorio-Alexander, Roberta; Pogue, Brian W.; Paulsen, Keith D.

    2013-03-01

    We have presented methodology to calibrate data in NIRS/MRI imaging versus an absolute reference phantom and results in both phantoms and healthy volunteers. This method directly calibrates data to a diffusion-based model, takes advantage of patient specific geometry from MRI prior information, and generates an initial guess without the need for a large data set. This method of calibration allows for more accurate quantification of total hemoglobin, oxygen saturation, water content, scattering, and lipid concentration as compared with other, slope-based methods. We found the main source of error in the method to be derived from incorrect assignment of reference phantom optical properties rather than initial guess in reconstruction. We also present examples of phantom and breast images from a combined frequency domain and continuous wave MRI-coupled NIRS system. We were able to recover phantom data within 10% of expected contrast and within 10% of the actual value using this method and compare these results with slope-based calibration methods. Finally, we were able to use this technique to calibrate and reconstruct images from healthy volunteers. Representative images are shown and discussion is provided for comparison with existing literature. These methods work towards fully combining the synergistic attributes of MRI and NIRS for in-vivo imaging of breast cancer. Complete software and hardware integration in dual modality instruments is especially important due to the complexity of the technology and success will contribute to complex anatomical and molecular prognostic information that can be readily obtained in clinical use.

  8. Flow rate calibration for absolute cell counting rationale and design.

    PubMed

    Walker, Clare; Barnett, David

    2006-05-01

    There is a need for absolute leukocyte enumeration in the clinical setting, and accurate, reliable (and affordable) technology to determine absolute leukocyte counts has been developed. Such technology includes single platform and dual platform approaches. Derivations of these counts commonly incorporate the addition of a known number of latex microsphere beads to a blood sample, although it has been suggested that the addition of beads to a sample may only be required to act as an internal quality control procedure for assessing the pipetting error. This unit provides the technical details for undertaking flow rate calibration that obviates the need to add reference beads to each sample. It is envisaged that this report will provide the basis for subsequent clinical evaluations of this novel approach. PMID:18770842

  9. Absolute magnitude calibration using trigonometric parallax - Incomplete, spectroscopic samples

    NASA Technical Reports Server (NTRS)

    Ratnatunga, Kavan U.; Casertano, Stefano

    1991-01-01

    A new numerical algorithm is used to calibrate the absolute magnitude of spectroscopically selected stars from their observed trigonometric parallax. This procedure, based on maximum-likelihood estimation, can retrieve unbiased estimates of the intrinsic absolute magnitude and its dispersion even from incomplete samples suffering from selection biases in apparent magnitude and color. It can also make full use of low accuracy and negative parallaxes and incorporate censorship on reported parallax values. Accurate error estimates are derived for each of the fitted parameters. The algorithm allows an a posteriori check of whether the fitted model gives a good representation of the observations. The procedure is described in general and applied to both real and simulated data.

  10. Absolute radiometric calibration of Landsat using a pseudo invariant calibration site

    USGS Publications Warehouse

    Helder, D.; Thome, K.J.; Mishra, N.; Chander, G.; Xiong, Xiaoxiong; Angal, A.; Choi, Tae-young

    2013-01-01

    Pseudo invariant calibration sites (PICS) have been used for on-orbit radiometric trending of optical satellite systems for more than 15 years. This approach to vicarious calibration has demonstrated a high degree of reliability and repeatability at the level of 1-3% depending on the site, spectral channel, and imaging geometries. A variety of sensors have used this approach for trending because it is broadly applicable and easy to implement. Models to describe the surface reflectance properties, as well as the intervening atmosphere have also been developed to improve the precision of the method. However, one limiting factor of using PICS is that an absolute calibration capability has not yet been fully developed. Because of this, PICS are primarily limited to providing only long term trending information for individual sensors or cross-calibration opportunities between two sensors. This paper builds an argument that PICS can be used more extensively for absolute calibration. To illustrate this, a simple empirical model is developed for the well-known Libya 4 PICS based on observations by Terra MODIS and EO-1 Hyperion. The model is validated by comparing model predicted top-of-atmosphere reflectance values to actual measurements made by the Landsat ETM+ sensor reflective bands. Following this, an outline is presented to develop a more comprehensive and accurate PICS absolute calibration model that can be Système international d'unités (SI) traceable. These initial concepts suggest that absolute calibration using PICS is possible on a broad scale and can lead to improved on-orbit calibration capabilities for optical satellite sensors.

  11. Absolute calibration of a laser system for atmospheric probing.

    PubMed

    Hall, F F; Ageno, H Y

    1970-08-01

    In order to obtain quantitative data on the backscatter function from laser irradiance backscattered from the atmosphere, the ratio of power transmitted to power received must be accurately known. No absolute measurements of power, optical system transmittance, detector quantum efficiency, or electronic gain are necessarily required. The technique of measuring the power ratio by irradiating a smoked or painted target of known diffuse reflectance at a fixed range is used to calibrate a complete lidar system. The relative area of the output power pulse is monitored by a fast response photodiode, and the relative area of the returned pulse is also recorded after passing through a filter of known high optical density. It is essential to control the temperatures of the laser rod and receiver interference prefilter to ensure proper spectral matching. Field experience gained using this technique is described, and examples of calibration measurements and backscatter functions for smog and cirrus clouds are presented.

  12. Active radiometric calorimeter for absolute calibration of radioactive sources

    SciTech Connect

    Stump, K.E.; DeWerd, L.A.; Rudman, D.A.; Schima, S.A.

    2005-03-01

    This report describes the design and initial noise floor measurements of a radiometric calorimeter designed to measure therapeutic medical radioactive sources. The instrument demonstrates a noise floor of approximately 2 nW. This low noise floor is achieved by using high temperature superconducting (HTS) transition edge sensor (TES) thermometers in a temperature-control feedback loop. This feedback loop will be used to provide absolute source calibrations based upon the electrical substitution method. Other unique features of the calorimeter are (a) its ability to change sources for calibration without disrupting the vacuum of the instrument, and (b) the ability to measure the emitted power of a source in addition to the total contained source power.

  13. Monochromator-Based Absolute Calibration of a Standard Radiation Thermometer

    NASA Astrophysics Data System (ADS)

    Mantilla, J. M.; Hernanz, M. L.; Campos, J.; Martín, M. J.; Pons, A.; del Campo, D.

    2014-04-01

    Centro Español de Metrología (CEM) is disseminating the International Temperature Scale (ITS-90), at high temperatures, by using the fixed points of Ag and Cu and a standard radiation thermometer. However, the future mise-en-pratique for the definition of the kelvin ( MeP-K) will include the dissemination of the kelvin by primary methods and by indirect approximations capable of exceptionally low uncertainties or increased reliability. Primary radiometry is, at present, able to achieve uncertainties competitive with the ITS-90 above the silver point with one of the possible techniques the calibration for radiance responsivity of an imaging radiometer (radiance method). In order to carry out this calibration, IO-CSIC (Spanish Designated Institute for luminous intensity and luminous flux) has collaborated with CEM, allowing traceability to its cryogenic radiometer. A monochromator integrating sphere-based spectral comparator facility has been used to calibrate one of the CEM standard radiation thermometers. The absolute calibrated standard radiation thermometer has been used to determine the temperatures of the fixed points of Cu, Co-C, Pt-C, and Re-C. The results obtained are 1357.80 K, 1597.10 K, 2011.66 K, and 2747.64 K, respectively, with uncertainties ranging from 0.4 K to 1.1 K.

  14. The Absolute Calibration of the HiRes Detectors

    NASA Astrophysics Data System (ADS)

    Matthews, J. N.; Thomas, S. B.; HiRes Collaboration

    2003-07-01

    The HiRes experiment studies ultra high energy cosmic rays using the air fluorescence technique. The experiment uses large mirrors that collect the fluorescence light and fo cus it onto arrays of photomultiplier tubes (PMTs). The PMTs measure the intensity and time of arrival of the collected light. Our primary system for in situ calibration of the PMTs uses a high stability (<1%) portable light source. This source is transferred from the lab to the field where it is employed as a standard candle to calibrate the 64 detectors (>16,000 PMTs). To determine the absolute response it is necessary to understand the absolute light output of this source. We have measured the source irradiance using a hybrid photo dio de system, two NIST calibrated photo-dio des, and by observing the photo electron statistics of the PMTs. 2. Introduction The goal of the High Resolution Fly's Eye (HiRes) project is to study cosmic rays at the highest energies. An ultra high energy cosmic ray entering the earth's atmosphere collides with atmospheric nuclei triggering the development of an Extensive Air Shower (EAS). The EAS emits fluorescence light as it develops. HiRes uses the air fluorescence signal to measure properties of the primary cosmic ray particle. The fundamental detector elements in HiRes are photomultiplier tubes (PMTs). The light from an EAS is collected by large mirrors and fo cused into cameras each consisting of 256 PMTs [1]. Routine monitoring and calibration of the PMTs and associated electronics are crucial to the proper interpretation of the data. The primary system for in situ calibration of the PMTs involves the use of a high stability portable xenon flash lamp. The Roving Xenon Flasher (RXF) offers several advantages. The pulse-to-pulse variation in intensity is very small ˜0.3% and the stability over a night is better than 2%. The emission spectrum of the RXF is sufficiently broad to allow calibration over a wide range of wavelengths. It is also readily transported

  15. On the absolute calibration of SO2 cameras

    NASA Astrophysics Data System (ADS)

    Lübcke, P.; Bobrowski, N.; Illing, S.; Kern, C.; Alvarez Nieves, J. M.; Vogel, L.; Zielcke, J.; Delgado Granados, H.; Platt, U.

    2012-09-01

    Sulphur dioxide emission flux measurements are an important tool for volcanic monitoring and eruption risk assessment. The SO2 camera technique remotely measures volcanic emissions by analysing the ultraviolet absorption of SO2 in a narrow spectral window between 305 nm and 320 nm using solar radiation scattered in the atmosphere. The SO2 absorption is selectively detected by mounting band-pass interference filters in front of a two-dimensional, UV-sensitive CCD detector. While this approach is simple and delivers valuable insights into the two-dimensional SO2 distribution, absolute calibration has proven to be difficult. An accurate calibration of the SO2 camera (i.e., conversion from optical density to SO2 column density, CD) is crucial to obtain correct SO2 CDs and flux measurements that are comparable to other measurement techniques and can be used for volcanological applications. The most common approach for calibrating SO2 camera measurements is based on inserting quartz cells (cuvettes) containing known amounts of SO2 into the light path. It has been found, however, that reflections from the windows of the calibration cell can considerably affect the signal measured by the camera. Another possibility for calibration relies on performing simultaneous measurements in a small area of the camera's field-of-view (FOV) by a narrow-field-of-view Differential Optical Absorption Spectroscopy (NFOV-DOAS) system. This procedure combines the very good spatial and temporal resolution of the SO2 camera technique with the more accurate column densities obtainable from DOAS measurements. This work investigates the uncertainty of results gained through the two commonly used, but quite different calibration methods (DOAS and calibration cells). Measurements with three different instruments, an SO2 camera, a NFOV-DOAS system and an Imaging DOAS (IDOAS), are presented. We compare the calibration-cell approach with the calibration from the NFOV-DOAS system. The respective

  16. Absolute calorimetric calibration of low energy brachytherapy sources

    NASA Astrophysics Data System (ADS)

    Stump, Kurt E.

    In the past decade there has been a dramatic increase in the use of permanent radioactive source implants in the treatment of prostate cancer. A small radioactive source encapsulated in a titanium shell is used in this type of treatment. The radioisotopes used are generally 125I or 103Pd. Both of these isotopes have relatively short half-lives, 59.4 days and 16.99 days, respectively, and have low-energy emissions and a low dose rate. These factors make these sources well suited for this application, but the calibration of these sources poses significant metrological challenges. The current standard calibration technique involves the measurement of ionization in air to determine the source air-kerma strength. While this has proved to be an improvement over previous techniques, the method has been shown to be metrologically impure and may not be the ideal means of calbrating these sources. Calorimetric methods have long been viewed to be the most fundamental means of determining source strength for a radiation source. This is because calorimetry provides a direct measurement of source energy. However, due to the low energy and low power of the sources described above, current calorimetric methods are inadequate. This thesis presents work oriented toward developing novel methods to provide direct and absolute measurements of source power for low-energy low dose rate brachytherapy sources. The method is the first use of an actively temperature-controlled radiation absorber using the electrical substitution method to determine total contained source power of these sources. The instrument described operates at cryogenic temperatures. The method employed provides a direct measurement of source power. The work presented here is focused upon building a metrological foundation upon which to establish power-based calibrations of clinical-strength sources. To that end instrument performance has been assessed for these source strengths. The intent is to establish the limits of

  17. THE ABSOLUTE CALIBRATION OF THE EUV IMAGING SPECTROMETER ON HINODE

    SciTech Connect

    Warren, Harry P.; Ugarte-Urra, Ignacio; Landi, Enrico

    2014-07-01

    We investigate the absolute calibration of the EUV Imaging Spectrometer (EIS) on Hinode by comparing EIS full-disk mosaics with irradiance observations from the EUV Variability Experiment on the Solar Dynamics Observatory. We also use extended observations of the quiet corona above the limb combined with a simple differential emission measure model to establish new effective area curves that incorporate information from the most recent atomic physics calculations. We find that changes to the EIS instrument sensitivity are a complex function of both time and wavelength. We find that the sensitivity is decaying exponentially with time and that the decay constants vary with wavelength. The EIS short wavelength channel shows significantly longer decay times than the long wavelength channel.

  18. Absolute Calibration of Optical Satellite Sensors Using Libya 4 Pseudo Invariant Calibration Site

    NASA Technical Reports Server (NTRS)

    Mishra, Nischal; Helder, Dennis; Angal, Amit; Choi, Jason; Xiong, Xiaoxiong

    2014-01-01

    The objective of this paper is to report the improvements in an empirical absolute calibration model developed at South Dakota State University using Libya 4 (+28.55 deg, +23.39 deg) pseudo invariant calibration site (PICS). The approach was based on use of the Terra MODIS as the radiometer to develop an absolute calibration model for the spectral channels covered by this instrument from visible to shortwave infrared. Earth Observing One (EO-1) Hyperion, with a spectral resolution of 10 nm, was used to extend the model to cover visible and near-infrared regions. A simple Bidirectional Reflectance Distribution function (BRDF) model was generated using Terra Moderate Resolution Imaging Spectroradiometer (MODIS) observations over Libya 4 and the resulting model was validated with nadir data acquired from satellite sensors such as Aqua MODIS and Landsat 7 (L7) Enhanced Thematic Mapper (ETM+). The improvements in the absolute calibration model to account for the BRDF due to off-nadir measurements and annual variations in the atmosphere are summarized. BRDF models due to off-nadir viewing angles have been derived using the measurements from EO-1 Hyperion. In addition to L7 ETM+, measurements from other sensors such as Aqua MODIS, UK-2 Disaster Monitoring Constellation (DMC), ENVISAT Medium Resolution Imaging Spectrometer (MERIS) and Operational Land Imager (OLI) onboard Landsat 8 (L8), which was launched in February 2013, were employed to validate the model. These satellite sensors differ in terms of the width of their spectral bandpasses, overpass time, off-nadir-viewing capabilities, spatial resolution and temporal revisit time, etc. The results demonstrate that the proposed empirical calibration model has accuracy of the order of 3% with an uncertainty of about 2% for the sensors used in the study.

  19. Alignment and absolute wavelength calibration of imaging Bragg spectrometers

    NASA Astrophysics Data System (ADS)

    Bertschinger, G.; Marchuk, O.; Barnsley, R.

    2016-11-01

    In the present and the next generation of fusion devices, imaging Bragg spectrometers are key diagnostics to measure plasma parameters in the hot core, especially ion temperature and plasma rotation. The latter quantities are routinely obtained using the Doppler-width and -shift of the emitted spectral lines, respectively. Line shift measurements require absolute accuracies Δλ/λ of about 10 ppm, where λ-is the observed wavelength. For ITER and the present fusion devices, spectral lines of He-and H-like argon, iron, and krypton as well as Ne-like tungsten are foreseen for the measurements. For these lines, Kα lines can be found, some in higher order, which fit into the narrow energy window of the spectrometers. For arbitrary wavelength settings, Kα lines are also used to measure the miscut of the spherical crystals; afterwards the spectrometers can be set according to the geometrical imaging properties using coordinate measurement machines. For the spectrometers measuring Lyα lines of H-like ions, fluorescence targets can provide in situ localized calibration lines on the spectra. The fluorescence targets are used best in transmission and are excited by the thermal x-ray radiation of the plasma. An analytic theory of fluorescence is worked out.

  20. Relative vs Absolute Antenna Calibrations: How, when, and why do they differ? A Comparison of Antenna Calibration Catalogs

    NASA Astrophysics Data System (ADS)

    Mader, G. L.; Bilich, A. L.

    2013-12-01

    Since 1994, NGS has computed relative antenna calibrations for more than 350 antenna models used by NGS customers and geodetic networks worldwide. In a 'relative' calibration, the antenna under test is calibrated relative to a standard reference antenna, the AOA D/M_T chokering. The majority of NGS calibrations have been made publicly available at the web site www.ngs.noaa.gov/ANTCAL as well as via the NGS master calibrations file ant_info.003. In the mid-2000's, institutions in Germany began distributing 'absolute' antenna calibrations, where the antenna under test is calibrated independent of any reference antenna. These calibration methods also overcame some limitations of relative calibrations by going to lower elevation angles and capturing azimuthal variations. Soon thereafter (2008), the International GNSS Service (IGS) initiated a geodetic community movement away from relative calibrations and toward absolute calibrations as the defacto standard. The IGS now distributes a catalog of absolute calibrations taken from several institutions, distributed as the IGS master calibrations file igs08.atx. The competing methods and files have raised many questions about when it is or is not valid to process a geodetic network using a combination of relative and absolute calibrations, and if/when it is valid to combine the NGS and IGS catalogs. Therefore, in this study, we compare the NGS catalog of relative calibrations against the IGS catalog of absolute calibrations. As of the writing of this abstract, there are 77 antenna+radome combinations which are common to both the NGS relative and IGS absolute catalogs, spanning 16 years of testing (1997 to present). 50 different antenna models and 8 manufacturers are represented in the study sample. We apply the widely-accepted standard method for converting relative to absolute, then difference the calibrations. Various statistics describe the observed differences between phase center offset (PCO), phase center variation

  1. Methods to calibrate the absolute receive sensitivity of single-element, focused transducers.

    PubMed

    Rich, Kyle T; Mast, T Douglas

    2015-09-01

    Absolute pressure measurements of acoustic emissions by single-element, focused passive cavitation detectors would be facilitated by improved wideband receive calibration techniques. Here, calibration methods were developed to characterize the absolute, frequency-dependent receive sensitivity of a spherically focused, single-element transducer using pulse-echo and pitch-catch techniques. Validation of these calibration methods on a focused receiver were made by generating a pulse from a small diameter source at the focus of the transducer and comparing the absolute pressure measured by a calibrated hydrophone to that of the focused transducer using the receive sensitivities determined here. PMID:26428812

  2. Methods to calibrate the absolute receive sensitivity of single-element, focused transducers

    PubMed Central

    Rich, Kyle T.; Mast, T. Douglas

    2015-01-01

    Absolute pressure measurements of acoustic emissions by single-element, focused passive cavitation detectors would be facilitated by improved wideband receive calibration techniques. Here, calibration methods were developed to characterize the absolute, frequency-dependent receive sensitivity of a spherically focused, single-element transducer using pulse-echo and pitch-catch techniques. Validation of these calibration methods on a focused receiver were made by generating a pulse from a small diameter source at the focus of the transducer and comparing the absolute pressure measured by a calibrated hydrophone to that of the focused transducer using the receive sensitivities determined here. PMID:26428812

  3. [Study on the absolute spectral irradiation calibration method for far ultraviolet spectrometer in remote sensing].

    PubMed

    Yu, Lei; Lin, Guan-Yu; Chen, Bin

    2013-01-01

    The present paper studied spectral irradiation responsivities calibration method which can be applied to the far ultraviolet spectrometer for upper atmosphere remote sensing. It is difficult to realize the calibration for far ultraviolet spectrometer for many reasons. Standard instruments for far ultraviolet waveband calibration are few, the degree of the vacuum experiment system is required to be high, the stabilities of the experiment are hardly maintained, and the limitation of the far ultraviolet waveband makes traditional diffuser and the integrating sphere radiance calibration method difficult to be used. To solve these problems, a new absolute spectral irradiance calibration method was studied, which can be applied to the far ultraviolet calibration. We build a corresponding special vacuum experiment system to verify the calibration method. The light source system consists of a calibrated deuterium lamp, a vacuum ultraviolet monochromater and a collimating system. We used the calibrated detector to obtain the irradiance responsivities of it. The three instruments compose the calibration irradiance source. We used the "calibration irradiance source" to illuminate the spectrometer prototype and obtained the spectral irradiance responsivities. It realized the absolute spectral irradiance calibration for the far ultraviolet spectrometer utilizing the calibrated detector. The absolute uncertainty of the calibration is 7.7%. The method is significant for the ground irradiation calibration of the far ultraviolet spectrometer in upper atmosphere remote sensing.

  4. [In-flight absolute radiometric calibration of UAV multispectral sensor].

    PubMed

    Chen, Wei; Yan, Lei; Gou, Zhi-Yang; Zhao, Hong-Ying; Liu, Da-Ping; Duan, Yi-Ni

    2012-12-01

    Based on the data of the scientific experiment in Urad Front Banner for UAV Remote Sensing Load Calibration Field project, with the help of 6 hyperspectral radiometric targets with good Lambertian property, the wide-view multispectral camera in UAV was calibrated adopting reflectance-based method. The result reveals that for green, red and infrared channel, whose images were successfully captured, the linear correlation coefficients between the DN and radiance are all larger than 99%. In final analysis, the comprehensive error is no more than 6%. The calibration results demonstrate that the hyperspectral targets equipped by the calibration field are well suitable for air-borne multispectral load in-flight calibration. The calibration result is reliable and could be used in the retrieval of geophysical parameters.

  5. Absolute calibration of space-resolving soft X-ray spectrograph for plasma diagnostics

    NASA Astrophysics Data System (ADS)

    Yoshikawa, M.; Okamoto, Y.; Kawamori, E.; Watanabe, Y.; Watabe, C.; Yamaguchi, N.; Tamano, T.

    2001-07-01

    A grazing incidence flat-field soft X-ray (20-350 Å) spectrograph was constructed and applied for impurity diagnostics in the GAMMA 10 fusion plasma. The spectrograph consisted of a limited height entrance slit, an aberration-corrected concave grating, a microchannel-plate intensified detector and an instant camera/a high speed solid state camera. An absolute calibration experiment for the SX spectrograph was performed at the Photon Factory in the High Energy Accelerator Research Organization with monitoring the incident synchrotron beam intensity by using an absolutely calibrated XUV silicon photodiode. From the results of absolute calibration of the spectrograph, the radiation loss from the plasma was obtained.

  6. On the absolute calibration of SO2 cameras

    USGS Publications Warehouse

    Lübcke, Peter; Bobrowski, Nicole; Illing, Sebastian; Kern, Christoph; Alvarez Nieves, Jose Manuel; Vogel, Leif; Zielcke, Johannes; Delgados Granados, Hugo; Platt, Ulrich

    2013-01-01

    This work investigates the uncertainty of results gained through the two commonly used, but quite different, calibration methods (DOAS and calibration cells). Measurements with three different instruments, an SO2 camera, a NFOVDOAS system and an Imaging DOAS (I-DOAS), are presented. We compare the calibration-cell approach with the calibration from the NFOV-DOAS system. The respective results are compared with measurements from an I-DOAS to verify the calibration curve over the spatial extent of the image. The results show that calibration cells, while working fine in some cases, can lead to an overestimation of the SO2 CD by up to 60% compared with CDs from the DOAS measurements. Besides these errors of calibration, radiative transfer effects (e.g. light dilution, multiple scattering) can significantly influence the results of both instrument types. The measurements presented in this work were taken at Popocatepetl, Mexico, between 1 March 2011 and 4 March 2011. Average SO2 emission rates between 4.00 and 14.34 kg s−1 were observed.

  7. Spectrophotometric multicomponent resolution of a veterinary formulation containing oxfendazole and oxyclozanide by multivariate calibration-prediction techniques.

    PubMed

    Dinç, Erdal; Kanbur, Murat

    2002-05-15

    Four multivariate calibration-prediction techniques, classical least-squares, inverse least-squares, principal component regression and partial least-squares regression were applied to the spectrophotometric multicomponent analysis of a veterinary formulation containing oxfendazole (OXF) and oxyclozanide (OXC) without any separation step. The multivariate calibrations were constructed by measuring the absorbance values at 14 points in the 285-350 nm wavelength range and by using the training set of standard mixtures containing OXF and OXC in the different compositions. The validity of building multivariate calibrations was checked by using the synthetic mixtures of both drugs. The multivariate calibration models were successfully applied to the spectrophotometric determination of OXF and OXC in laboratory prepared mixtures and a veterinary formulation. The results obtained were statistically compared with each other.

  8. Quantum Efficient Detectors for Use in Absolute Calibration

    NASA Technical Reports Server (NTRS)

    Faust, Jessica; Eastwood, Michael; Pavri, Betina; Raney, James

    1998-01-01

    The trap or quantum efficient detector has a quantum efficiency of greater than 0.98 for the region from 450 to 900 nm. The region of flattest response is from 600 to 900 nm. The QED consists of three windowless Hamamatsu silicon detectors. The QED was mounted below AVIRIS to monitor the Spectralon panel for changes in radiance during radiometric calibration. The next step is to permanently mount the detector to AVIRIS and monitor the overall radiance of scenes along with calibration.

  9. Confidence-Accuracy Calibration in Absolute and Relative Face Recognition Judgments

    ERIC Educational Resources Information Center

    Weber, Nathan; Brewer, Neil

    2004-01-01

    Confidence-accuracy (CA) calibration was examined for absolute and relative face recognition judgments as well as for recognition judgments from groups of stimuli presented simultaneously or sequentially (i.e., simultaneous or sequential mini-lineups). When the effect of difficulty was controlled, absolute and relative judgments produced…

  10. On the absolute calibration of SO2 cameras

    NASA Astrophysics Data System (ADS)

    Lübcke, P.; Bobrowski, N.; Illing, S.; Kern, C.; Alvarez Nieves, J. M.; Vogel, L.; Zielcke, J.; Delgado Granados, H.; Platt, U.

    2013-03-01

    Sulphur dioxide emission rate measurements are an important tool for volcanic monitoring and eruption risk assessment. The SO2 camera technique remotely measures volcanic emissions by analysing the ultraviolet absorption of SO2 in a narrow spectral window between 300 and 320 nm using solar radiation scattered in the atmosphere. The SO2 absorption is selectively detected by mounting band-pass interference filters in front of a two-dimensional, UV-sensitive CCD detector. One important step for correct SO2 emission rate measurements that can be compared with other measurement techniques is a correct calibration. This requires conversion from the measured optical density to the desired SO2 column density (CD). The conversion factor is most commonly determined by inserting quartz cells (cuvettes) with known amounts of SO2 into the light path. Another calibration method uses an additional narrow field-of-view Differential Optical Absorption Spectroscopy system (NFOV-DOAS), which measures the column density simultaneously in a small area of the camera's field-of-view. This procedure combines the very good spatial and temporal resolution of the SO2 camera technique with the more accurate column densities obtainable from DOAS measurements. This work investigates the uncertainty of results gained through the two commonly used, but quite different, calibration methods (DOAS and calibration cells). Measurements with three different instruments, an SO2 camera, a NFOV-DOAS system and an Imaging DOAS (I-DOAS), are presented. We compare the calibration-cell approach with the calibration from the NFOV-DOAS system. The respective results are compared with measurements from an I-DOAS to verify the calibration curve over the spatial extent of the image. The results show that calibration cells, while working fine in some cases, can lead to an overestimation of the SO2 CD by up to 60% compared with CDs from the DOAS measurements. Besides these errors of calibration, radiative transfer

  11. Absolute calibration of the RADSCAT scatterometer using precision spheres

    NASA Technical Reports Server (NTRS)

    Grantham, W. L.; Schroeder, L. C.; Mitchell, J. L.

    1976-01-01

    Tests using precision sphere targets suspended from balloons were conducted to calibrate the received-power/transmitted-power tatio of the RADSCAT scatterometer. Comparisons were made of these measured results with theoretical return from spheres. The RADSCAT scatterometer measurements at 13.9 GHz should be corrected by -2.4 dB, and those at 9.3 GHz, by -4.3 dB. The techniques described should be generally applicable to calibration of scatterometers where measurement precision is of prime importance. Inferred from the magnitude of these RADSCAT corrections was the present state of technology in building precision scatterometers.

  12. High accuracy absolute laser powermeter calibrated over the whole range

    SciTech Connect

    Miron, N.; Korony, G.; Velculescu, V.G.

    1994-12-31

    The main contribution to this laser powermeter is the capability of its detector to be electrically calibrated over the whole measuring range (0 ... 100W), with an accuracy better than 1%. This allows an improved accuracy in determining the second-order polynomial coefficients describing thermocouple electric response.

  13. First Absolutely Calibrated Localized Measurements of Ion Velocity in the MST in Locked and Rotating Plasmas

    NASA Astrophysics Data System (ADS)

    Baltzer, M.; Craig, D.; den Hartog, D. J.; Nornberg, M. D.; Munaretto, S.

    2015-11-01

    An Ion Doppler Spectrometer (IDS) is used on MST for high time-resolution passive and active measurements of impurity ion emission. Absolutely calibrated measurements of flow are difficult because the spectrometer records data within 0.3 nm of the C+5 line of interest, and commercial calibration lamps do not produce lines in this narrow range . A novel optical system was designed to absolutely calibrate the IDS. The device uses an UV LED to produce a broad emission curve in the desired region. A Fabry-Perot etalon filters this light, cutting transmittance peaks into the pattern of the LED emission. An optical train of fused silica lenses focuses the light into the IDS with f/4. A holographic diffuser blurs the light cone to increase homogeneity. Using this light source, the absolute Doppler shift of ion emissions can be measured in MST plasmas. In combination with charge exchange recombination spectroscopy, localized ion velocities can now be measured. Previously, a time-averaged measurement along the chord bisecting the poloidal plane was used to calibrate the IDS; the quality of these central chord calibrations can be characterized with our absolute calibration. Calibration errors may also be quantified and minimized by optimizing the curve-fitting process. Preliminary measurements of toroidal velocity in locked and rotating plasmas will be shown. This work has been supported by the US DOE.

  14. Prelaunch absolute radiometric calibration of the reflective bands on the LANDSAT-4 protoflight Thematic Mapper

    NASA Technical Reports Server (NTRS)

    Barker, J. L.; Ball, D. L.; Leung, K. C.; Walker, J. A.

    1984-01-01

    The results of the absolute radiometric calibration of the LANDSAT 4 thematic mapper, as determined during pre-launch tests with a 122 cm integrating sphere, are presented. Detailed results for the best calibration of the protoflight TM are given, as well as summaries of other tests performed on the sensor. The dynamic range of the TM is within a few per cent of that required in all bands, except bands 1 and 3. Three detectors failed to pass the minimum SNR specified for their respective bands: band 5, channel 3 (dead), band 2, and channels 2 and 4 (noisy or slow response). Estimates of the absolute calibration accuracy for the TM show that the detectors are typically calibrated to 5% absolute error for the reflective bands; 10% full-scale accuracy was specified. Ten tests performed to transfer the detector absolute calibration to the internal calibrator show a 5% range at full scale in the transfer calibration; however, in two cases band 5 showed a 10% and a 7% difference.

  15. Strategies for absolute calibration of near infrared tomographic tissue imaging.

    PubMed

    McBride, Troy O; Pogue, Brian W; Osterberg, Ulf L; Paulsen, Keith D

    2003-01-01

    Quantitative near infrared (NIR) imaging of tissue requires the use of a diffusion model-based reconstruction algorithm, which solves for the absorption and scattering coefficients of a tissue volume by matching transmission measurements of light to the predictive diffusion equation solution. Calibration problems as well as other practical considerations arise for an imaging system when using a model-based method for a real system. For example, systematic noise in the data acquisition hardware and source/detector fibers must be removed to prevent spurious results in the reconstructed image. Practical considerations for a NIR diffuse tomographic imaging system include: (1) calibration with a homogeneous phantom, (2) use of a homogenous fitting algorithm to arrive at an initial optical property estimate for image reconstruction of a heterogeneous medium, and (3) correction for fluctuations in source strength and initial phase offset during data acquisition. These practical considerations, which rely on an accurate homogeneous fitting algorithm are described. They have allowed demonstration of a prototype imaging system that has the ability to quantitatively reconstruct heterogeneous images of hemoglobin concentrations within a highly scattering medium with no a priori information.

  16. Absolutely calibrated soft-x-ray streak camera for laser-fusion applications

    SciTech Connect

    Kauffman, R.L.; Medecki, H.; Stradling, G.

    1982-01-01

    The intensity output of a soft-x-ray streak camera was calibrated (SXRSC) in order to make absolute flux measurements of x rays emitted from laser-produced plasmas. The SXRSC developed at LLNL is used to time-resolve x-ray pulses to better than 20 ps. The SXRSC uses a Au photocathode on a thin carbon substrate which is sensitive to x rays from 100 eV to greater than 10 keV. Calibrations are done in the dynamic mode using a small laser-produced x-ray source. The SXRSC is calibrated by comparing its integrated signal to the output of calibrated x-ray diodes monitoring the source strength. The measured SXRSC response is linear over greater than two orders of magnitude. Using these calibrations, absolute intensities can be measured to an accuracy of +-30%.

  17. A Laser Frequency Comb System for Absolute Calibration of the VTT Echelle Spectrograph

    NASA Astrophysics Data System (ADS)

    Doerr, H.-P.; Steinmetz, T.; Holzwarth, R.; Kentischer, T.; Schmidt, W.

    2012-10-01

    A wavelength calibration system based on a laser frequency comb (LFC) was developed in a co-operation between the Kiepenheuer-Institut für Sonnenphysik, Freiburg, Germany and the Max-Planck-Institut für Quantenoptik, Garching, Germany for permanent installation at the German Vacuum Tower Telescope (VTT) on Tenerife, Canary Islands. The system was installed successfully in October 2011. By simultaneously recording the spectra from the Sun and the LFC, for each exposure a calibration curve can be derived from the known frequencies of the comb modes that is suitable for absolute calibration at the meters per second level. We briefly summarize some topics in solar physics that benefit from absolute spectroscopy and point out the advantages of LFC compared to traditional calibration techniques. We also sketch the basic setup of the VTT calibration system and its integration with the existing echelle spectrograph.

  18. Calibration of the Reflected Solar Instrument for the Climate Absolute Radiance and Refractivity Observatory

    NASA Technical Reports Server (NTRS)

    Thome, Kurtis; Barnes, Robert; Baize, Rosemary; O'Connell, Joseph; Hair, Jason

    2010-01-01

    The Climate Absolute Radiance and Refractivity Observatory (CLARREO) plans to observe climate change trends over decadal time scales to determine the accuracy of climate projections. The project relies on spaceborne earth observations of SI-traceable variables sensitive to key decadal change parameters. The mission includes a reflected solar instrument retrieving at-sensor reflectance over the 320 to 2300 nm spectral range with 500-m spatial resolution and 100-km swath. Reflectance is obtained from the ratio of measurements of the earth s surface to those while viewing the sun relying on a calibration approach that retrieves reflectance with uncertainties less than 0.3%. The calibration is predicated on heritage hardware, reduction of sensor complexity, adherence to detector-based calibration standards, and an ability to simulate in the laboratory on-orbit sources in both size and brightness to provide the basis of a transfer to orbit of the laboratory calibration including a link to absolute solar irradiance measurements.

  19. Artifact correction and absolute radiometric calibration techniques employed in the Landsat 7 image assessment system

    USGS Publications Warehouse

    Boncyk, Wayne C.; Markham, Brian L.; Barker, John L.; Helder, Dennis

    1996-01-01

    The Landsat-7 Image Assessment System (IAS), part of the Landsat-7 Ground System, will calibrate and evaluate the radiometric and geometric performance of the Enhanced Thematic Mapper Plus (ETM +) instrument. The IAS incorporates new instrument radiometric artifact correction and absolute radiometric calibration techniques which overcome some limitations to calibration accuracy inherent in historical calibration methods. Knowledge of ETM + instrument characteristics gleaned from analysis of archival Thematic Mapper in-flight data and from ETM + prelaunch tests allow the determination and quantification of the sources of instrument artifacts. This a priori knowledge will be utilized in IAS algorithms designed to minimize the effects of the noise sources before calibration, in both ETM + image and calibration data.

  20. Absolute intensity calibration of the 32-channel heterodyne radiometer on experimental advanced superconducting tokamak

    SciTech Connect

    Liu, X.; Zhao, H. L.; Liu, Y. Li, E. Z.; Han, X.; Ti, A.; Hu, L. Q.; Zhang, X. D.; Domier, C. W.; Luhmann, N. C.

    2014-09-15

    This paper presents the results of the in situ absolute intensity calibration for the 32-channel heterodyne radiometer on the experimental advanced superconducting tokamak. The hot/cold load method is adopted, and the coherent averaging technique is employed to improve the signal to noise ratio. Measured spectra and electron temperature profiles are compared with those from an independent calibrated Michelson interferometer, and there is a relatively good agreement between the results from the two different systems.

  1. Pre-Launch Absolute Calibration of CCD/CBERS-2B Sensor

    PubMed Central

    Ponzoni, Flávio Jorge; Albuquerque, Bráulio Fonseca Carneiro

    2008-01-01

    Pre-launch absolute calibration coefficients for the CCD/CBERS-2B sensor have been calculated from radiometric measurements performed in a satellite integration and test hall in the Chinese Academy of Space Technology (CAST) headquarters, located in Beijing, China. An illuminated integrating sphere was positioned in the test hall facilities to allow the CCD/CBERS-2B imagery of the entire sphere aperture. Calibration images were recorded and a relative calibration procedure adopted exclusively in Brazil was applied to equalize the detectors responses. Averages of digital numbers (DN) from these images were determined and correlated to their respective radiance levels in order to calculate the absolute calibration coefficients. It has been the first time these pre-launch absolute calibration coefficients have been calculated considering the Brazilian image processing criteria. Now it will be possible to compare them to those that will be calculated from vicarious calibration campaigns. This comparison will permit the CCD/CBERS-2B monitoring and the frequently data updating to the user community.

  2. Glassy carbon as an absolute intensity calibration standard for small-angle scattering.

    SciTech Connect

    Zhang, F.; Ilavsky, J.; Long, G.; Allen, A.; Quintana, J.; Jemian, P.; NIST

    2010-05-01

    Absolute calibration of small-angle scattering (SAS) intensity data (measured in terms of the differential scattering cross section per unit sample volume per unit solid angle) is essential for many important aspects of quantitative SAS analysis, such as obtaining the number density, volume fraction, and specific surface area of the scatterers. It also enables scattering data from different instruments (light, X-ray, or neutron scattering) to be combined, and it can even be useful to detect the existence of artifacts in the experimental data. Different primary or secondary calibration methods are available. In the latter case, absolute intensity calibration requires a stable artifact with the necessary scattering profile. Glassy carbon has sometimes been selected as this intensity calibration standard. Here we review the spatial homogeneity and temporal stability of one type of commercially available glassy carbon that is being used as an intensity calibration standard at a number of SAS facilities. We demonstrate that glassy carbon is sufficiently homogeneous and stable during routine use to be relied upon as a suitable standard for absolute intensity calibration of SAS data.

  3. Variations in in-flight absolute radiometric calibration. [satellite remote sensors

    NASA Technical Reports Server (NTRS)

    Slater, Philip N.

    1986-01-01

    Variations in the in-flight absolute radiometric calibration of the Coastal Zone Color Scanner and the Thematic Mapper (TM) are reviewed. At short wavelengths, the sensors show a gradual reduction in response, while in the mid-IR the TM shows oscillatory variations. One set of measurements made at White Sands, New Mexico shows anomalous results in TM bands 2 and 4. The results of a reflectance-based and a radiance-based calibration method at White Sands are described. An analysis of the radiance-based method shows the value of such measurements from helicopter altitudes for calibration.

  4. Image plate characterization and absolute calibration to low kilo-electron-volt electrons

    SciTech Connect

    Busold, S.; Philipp, K.; Otten, A.; Roth, M.

    2014-11-15

    We report on the characterization of an image plate and its absolute calibration to electrons in the low keV energy range (1–30 keV). In our case, an Agfa MD4.0 without protection layer was used in combination with a Fuji FLA7000 scanner. The calibration data are compared to other published data and a consistent picture of the sensitivity of image plates to electrons is obtained, which suggests a validity of the obtained calibration up to 100 keV.

  5. Absolute flux calibration for the Mg II observations near 2800 angstroms

    NASA Technical Reports Server (NTRS)

    Kondo, Y.; Duval, J. E.; Modisette, J. L.; Morgan, T. H.

    1976-01-01

    Observations of the Mg II features near 2800 A, obtained with a balloon-borne ultraviolet stellar spectrometer for five stars, have been calibrated against the absolute flux measures from OAO-2 spectrometer results. Equivalent widths of the Mg II resonance doublet and their respective subordinate lines, as well as the emission intensities, were evaluated where applicable.

  6. [Research on absolute calibration of sun channel of sun photometer using laser raster scanning method].

    PubMed

    Xu, Wen-Bin; Li, Jian-Jun; Zheng, Xiao-Bing

    2013-01-01

    In the present paper, a new calibration method of absolute spectral irradiance responsivity of sun channel of sun photometer was developed. A tunable laser was used as source and a standard tranfer detector, calibrated against cryogenic absolute radiometer, was used to measure laser beam power. By raster scanning of a single collimated laser beam to generate the uniform irradiance field at the plane of effective aperture stop of sun photometer, the absolute irradiance responsivity of center wavelength of the 870 nm unpolarized sun channels of sun photometer was obtained accurately. The relative spectral irradiance responsivity of corresponding channel was obtained by using lamp-monochromator system and then used to acquire the absolute spectral irradiance responsivity in the laboratory. On the basis of the above results, the top-of-the-atmosphere responsive constant V0 was obtained by integration with extraterrestrial solar spectral irradiance data. Comparing the calibration result with that from GSFC, NASA in 2009, the difference is only 3.75%. In the last, the uncertainties of calibration were evaluated and reached to 2.06%. The principle feasibility of the new method was validated.

  7. Possibility of absolute calibration of analog detectors by using parametric downconversion: a systematic study

    SciTech Connect

    Brida, Giorgio; Genovese, Marco; Ruo-Berchera, Ivano; Chekhova, Maria; Penin, Alexander

    2006-10-15

    Prompted by the need for various studies ranging from quantum information to foundations of quantum mechanics, we systematically study the possibility of the absolute calibration of analog photodetectors based on the properties of parametric amplifiers. Our results show that such a method can be effectively developed with interesting possible applications in metrology.

  8. Absolute wavelength calibration of a Doppler spectrometer with a custom Fabry-Perot optical system

    NASA Astrophysics Data System (ADS)

    Baltzer, M. M.; Craig, D.; Den Hartog, D. J.; Nishizawa, T.; Nornberg, M. D.

    2016-11-01

    An Ion Doppler Spectrometer (IDS) is used for fast measurements of C VI line emission (343.4 nm) in the Madison Symmetric Torus. Absolutely calibrated flow measurements are difficult because the IDS records data within 0.25 nm of the line. Commercial calibration lamps do not produce lines in this narrow range. A light source using an ultraviolet LED and etalon was designed to provide a fiducial marker 0.08 nm wide. The light is coupled into the IDS at f/4, and a holographic diffuser increases homogeneity of the final image. Random and systematic errors in data analysis were assessed. The calibration is accurate to 0.003 nm, allowing for flow measurements accurate to 3 km/s. This calibration is superior to the previous method which used a time-averaged measurement along a chord believed to have zero net Doppler shift.

  9. Absolute calibration of neutron detectors on the C-2U advanced beam-driven FRC

    NASA Astrophysics Data System (ADS)

    Magee, R. M.; Clary, R.; Korepanov, S.; Jauregui, F.; Allfrey, I.; Garate, E.; Valentine, T.; Smirnov, A.

    2016-11-01

    In the C-2U fusion energy experiment, high power neutral beam injection creates a large fast ion population that sustains a field-reversed configuration (FRC) plasma. The diagnosis of the fast ion pressure in these high-performance plasmas is therefore critical, and the measurement of the flux of neutrons from the deuterium-deuterium (D-D) fusion reaction is well suited to the task. Here we describe the absolute, in situ calibration of scintillation neutron detectors via two independent methods: firing deuterium beams into a high density gas target and calibration with a 2 × 107 n/s AmBe source. The practical issues of each method are discussed and the resulting calibration factors are shown to be in good agreement. Finally, the calibration factor is applied to C-2U experimental data where the measured neutron rate is found to exceed the classical expectation.

  10. Reflectance- and radiance-based methods for the in-flight absolute calibration of multispectral sensors

    NASA Technical Reports Server (NTRS)

    Slater, P. N.; Biggar, S. F.; Holm, R. G.; Jackson, R. D.; Mao, Y.

    1987-01-01

    Variations reported in the in-flight absolute radiometric calibration of the Coastal Zone Color Scanner (CZCS) and the Thematic Mapper (TM) on Landsat 4 are reviewed. At short wavelengths these sensors exhibited a gradual reduction in response, while in the midinfrared the TM showed oscillatory variations, according to the results of TM internal calibration. The methodology and results are presented for five reflectance-based calibrations of the Landsat 5 TM at White Sands, NM, in the period July 1984 to November 1985. These show a + or - 2.8 percent standard deviation for the six solar-reflective bands. Analysis and preliminary results of a second, independent calibration method, based on radiance measurements from a helicopter at White Sands, indicate that this is potentially an accurate method for corroborating the results from the reflectance-based method.

  11. Reflectance- and radiance-based methods for the in-flight absolute calibration of multispectral sensors

    NASA Astrophysics Data System (ADS)

    Slater, P. N.; Biggar, S. F.; Holm, R. G.; Jackson, R. D.; Mao, Y.

    1987-06-01

    Variations reported in the in-flight absolute radiometric calibration of the Coastal Zone Color Scanner (CZCS) and the Thematic Mapper (TM) on Landsat 4 are reviewed. At short wavelengths these sensors exhibited a gradual reduction in response, while in the midinfrared the TM showed oscillatory variations, according to the results of TM internal calibration. The methodology and results are presented for five reflectance-based calibrations of the Landsat 5 TM at White Sands, NM, in the period July 1984 to November 1985. These show a + or - 2.8 percent standard deviation for the six solar-reflective bands. Analysis and preliminary results of a second, independent calibration method, based on radiance measurements from a helicopter at White Sands, indicate that this is potentially an accurate method for corroborating the results from the reflectance-based method.

  12. Relative and absolute intensity calibrations of a modern broadband echelle spectrometer

    NASA Astrophysics Data System (ADS)

    Bibinov, N.; Halfmann, H.; Awakowicz, P.; Wiesemann, K.

    2007-05-01

    We report on relative and absolute intensity calibrations of a modern broadband echelle spectrometer (type ESA 3000® trademark of LLA Instruments GmbH, Berlin) for use in the diagnostics of low-temperature plasma. This type of device measures simultaneously complete emission spectra in the spectral range from 200 to 800 nm with a spectral resolution of several picometres by using more than 90 spectral orders, causing a strongly structured efficiency function. The assumptions and approximations entering the calibration procedure under these conditions are discussed in section 3. For coping with the strongly structured efficiency function a continuum light source is needed, which covers the entire spectral range. Furthermore, the variation of its intensity must be low enough to ensure that neither statistical errors perturb the calibration in regions with low photon flux and/or low efficiency, nor local memory overflow in regions with high photon flux or high efficiency. In our case this requires that during calibration over the whole spectral range of the spectrometer the counts per pixel in one measurement vary at highest by a factor 10 to 12. Usual broadband light sources do not meet this latter requirement. We, therefore, use an uncalibrated 'composite' source, an adjustable combination of a standard tungsten strip lamp and a deuterium lamp, and calibrate the spectrometer in a two-step process against the tungsten strip lamp and well-known rovibrational intensity distributions in the emission spectra of NO and N2. We adjust the composite source in a way to produce a perturbation-free first approximation of an (uncalibrated) efficiency function, which is then corrected and thus calibrated by comparison with the (secondary) standards mentioned above. For absolute calibration we use the tungsten strip lamp. The uncertainty attained in this way for the relative calibration depends on the wavelength and varies between 5% and 10%. For the absolute calibration we

  13. Rapid, absolute calibration of x-ray filters employed by laser-produced plasma diagnostics.

    PubMed

    Brown, G V; Beiersdorfer, P; Emig, J; Frankel, M; Gu, M F; Heeter, R F; Magee, E; Thorn, D B; Widmann, K; Kelley, R L; Kilbourne, C A; Porter, F S

    2008-10-01

    The Electron Beam Ion Trap (EBIT) facility at the Lawrence Livermore National Laboratory is being used to absolutely calibrate the transmission efficiency of x-ray filters employed by diodes and spectrometers used to diagnose laser-produced plasmas. EBIT emits strong, discrete monoenergetic lines at appropriately chosen x-ray energies. X rays are detected using the high resolution EBIT Calorimeter Spectrometer (ECS), developed for LLNL at the NASA/Goddard Space Flight Center. X-ray filter transmission efficiency is determined by dividing the x-ray counts detected when the filter is in the line of sight by those detected when out of the line of sight. Verification of filter thickness can be completed in only a few hours, and absolute efficiencies can be calibrated in a single day over a broad range from about 0.1 to 15 keV. The EBIT calibration lab has been used to field diagnostics (e.g., the OZSPEC instrument) with fully calibrated x-ray filters at the OMEGA laser. Extensions to use the capability for calibrating filter transmission for the DANTE instrument on the National Ignition Facility are discussed. PMID:19044471

  14. Rapid, absolute calibration of x-ray filters employed by laser-produced plasma diagnostics

    SciTech Connect

    Brown, G. V.; Beiersdorfer, P.; Emig, J.; Frankel, M.; Gu, M. F.; Heeter, R. F.; Magee, E.; Thorn, D. B.; Widmann, K.; Kelley, R. L.; Kilbourne, C. A.; Porter, F. S.

    2008-10-15

    The Electron Beam Ion Trap (EBIT) facility at the Lawrence Livermore National Laboratory is being used to absolutely calibrate the transmission efficiency of x-ray filters employed by diodes and spectrometers used to diagnose laser-produced plasmas. EBIT emits strong, discrete monoenergetic lines at appropriately chosen x-ray energies. X rays are detected using the high resolution EBIT Calorimeter Spectrometer (ECS), developed for LLNL at the NASA/Goddard Space Flight Center. X-ray filter transmission efficiency is determined by dividing the x-ray counts detected when the filter is in the line of sight by those detected when out of the line of sight. Verification of filter thickness can be completed in only a few hours, and absolute efficiencies can be calibrated in a single day over a broad range from about 0.1 to 15 keV. The EBIT calibration lab has been used to field diagnostics (e.g., the OZSPEC instrument) with fully calibrated x-ray filters at the OMEGA laser. Extensions to use the capability for calibrating filter transmission for the DANTE instrument on the National Ignition Facility are discussed.

  15. Rapid, Absolute Calibration of X-ray Filters Employed By Laser-Produced Plasma Diagnostics

    SciTech Connect

    Brown, G V; Beiersdorfer, P; Emig, J; Frankel, M; Gu, M F; Heeter, R F; Magee, E; Thorn, D B; Widmann, K; . Kelley, R L; Kilbourne, C A; Porter, F S

    2008-05-11

    The electron beam ion trap (EBIT) facility at the Lawrence Livermore National Laboratory is being used to absolutely calibrate the transmission efficiency of X-ray filters employed by diodes and spectrometers used to diagnose laser-produced plasmas. EBIT emits strong, discrete monoenergetic lines at appropriately chosen X-ray energies. X-rays are detected using the high-resolution EBIT calorimeter spectrometer (ECS), developed for LLNL at the NASA/Goddard Space Flight Center. X-ray filter transmission efficiency is determined by dividing the X-ray counts detected when the filter is in the line of sight by those detected when out of the line of sight. Verification of filter thickness can be completed in only a few hours, and absolute efficiencies can be calibrated in a single day over a broad range from about 0.1 to 15 keV. The EBIT calibration lab has been used to field diagnostics (e.g., the OZSPEC instrument) with fully calibrated X-ray filters at the OMEGA laser. Extensions to use the capability for calibrating filter transmission for the DANTE instrument on the National Ignition Facility are discussed.

  16. Calibration-free absolute frequency response measurement of directly modulated lasers based on additional modulation.

    PubMed

    Zhang, Shangjian; Zou, Xinhai; Wang, Heng; Zhang, Yali; Lu, Rongguo; Liu, Yong

    2015-10-15

    A calibration-free electrical method is proposed for measuring the absolute frequency response of directly modulated semiconductor lasers based on additional modulation. The method achieves the electrical domain measurement of the modulation index of directly modulated lasers without the need for correcting the responsivity fluctuation in the photodetection. Moreover, it doubles measuring frequency range by setting a specific frequency relationship between the direct and additional modulation. Both the absolute and relative frequency response of semiconductor lasers are experimentally measured from the electrical spectrum of the twice-modulated optical signal, and the measured results are compared to those obtained with conventional methods to check the consistency. The proposed method provides calibration-free and accurate measurement for high-speed semiconductor lasers with high-resolution electrical spectrum analysis.

  17. A Liquid-Helium-Cooled Absolute Reference Cold Load forLong-Wavelength Radiometric Calibration

    SciTech Connect

    Bensadoun, M.; Witebsky, C.; Smoot, George F.; De Amici,Giovanni; Kogut, A.; Levin, S.

    1990-05-01

    We describe a large (78-cm) diameter liquid-helium-cooled black-body absolute reference cold load for the calibration of microwave radiometers. The load provides an absolute calibration near the liquid helium (LHe) boiling point, accurate to better than 30 mK for wavelengths from 2.5 to 25 cm (12-1.2 GHz). The emission (from non-LHe temperature parts of the cold load) and reflection are small and well determined. Total corrections to the LHe boiling point temperature are {le} 50 mK over the operating range. This cold load has been used at several wavelengths at the South Pole and at the White Mountain Research Station. In operation, the average LHe loss rate was {le} 4.4 l/hr. Design considerations, radiometric and thermal performance and operational aspects are discussed. A comparison with other LHe-cooled reference loads including the predecessor of this cold load is given.

  18. Absolute calibration of photon-number-resolving detectors with an analog output using twin beams

    SciTech Connect

    Peřina, Jan; Haderka, Ondřej; Allevi, Alessia; Bondani, Maria

    2014-01-27

    A method for absolute calibration of a photon-number resolving detector producing analog signals as the output is developed using a twin beam. The method gives both analog-to-digital conversion parameters and quantum detection efficiency for the photon fields. Characteristics of the used twin beam are also obtained. A simplified variant of the method applicable to fields with high signal to noise ratios and suitable for more intense twin beams is suggested.

  19. Absolute calibration of a charge-coupled device camera with twin beams

    SciTech Connect

    Meda, A.; Ruo-Berchera, I. Degiovanni, I. P.; Brida, G.; Rastello, M. L.; Genovese, M.

    2014-09-08

    We report on the absolute calibration of a Charge-Coupled Device (CCD) camera by exploiting quantum correlation. This method exploits a certain number of spatial pairwise quantum correlated modes produced by spontaneous parametric-down-conversion. We develop a measurement model accounting for all the uncertainty contributions, and we reach the relative uncertainty of 0.3% in low photon flux regime. This represents a significant step forward for the characterization of (scientific) CCDs used in mesoscopic light regime.

  20. Absolute calibration in the 1750 A-3350 A region. [revisions for air extinction

    NASA Technical Reports Server (NTRS)

    Strongylis, G. J.; Bohlin, R. C.

    1979-01-01

    The absolute flux measurements in the rocket ultraviolet made by Bohlin, Frimout, and Lillie (BFL) are revised using a more correct treatment of the air extinction that enters the air calibration of their instrument. The absorption by molecular oxygen and ozone, Rayleigh scattering, and extinction by aerosols is tabulated for general use in ultraviolet calibrations performed in air. The revised absolute flux of Eta UMa and final fluxes for Alpha Lyr and Zeta Oph are presented in the 1750 A-3350 A region. The absolute flux of the star Eta UMa (B3 V) is compared to four other independent determinations in the 1200 A-3400 A region and a maximum difference of 35% is found near 1500 A between the OAO-2 and Apollo 17 fluxes. Longward of 1700 A the typical scatter in the different determinations is only plus or minus 5%. The rocket measurements of BFL, the ANS and TD-1 satellite data, and the Apollo 17 data are compared to the ultraviolet fluxes from the OAO-2, demonstrating a photometric reproducibility of about plus or minus 3%. Therefore, all four sets of spectrophotometry can be reduced to a common absolute scale.

  1. Absolute calibration of a hydrogen discharge lamp in the vacuum ultraviolet

    NASA Technical Reports Server (NTRS)

    Nealy, J. E.

    1975-01-01

    A low-pressure hydrogen discharge lamp was calibrated for radiant intensity in the vacuum ultraviolet spectral region on an absolute basis and was employed as a laboratory standard source in spectrograph calibrations. This calibration was accomplished through the use of a standard photodiode detector obtained from the National Bureau of Standards together with onsite measurements of spectral properties of optical components used. The stability of the light source for use in the calibration of vacuum ultraviolet spectrographs and optical systems was investigated and found to be amenable to laboratory applications. The lamp was studied for a range of operating parameters; the results indicate that with appropriate peripheral instrumentation, the light source can be used as a secondary laboratory standard source when operated under preset controlled conditions. Absolute intensity measurements were recorded for the wavelengths 127.7, 158.0, 177.5, and 195.0 nm for a time period of over 1 month, and the measurements were found to be repeatable to within 11 percent.

  2. Calibration of Fourier domain short coherence interferometer for absolute distance measurements.

    PubMed

    Montonen, R; Kassamakov, I; Hæggström, E; Österberg, K

    2015-05-20

    We calibrated and determined the measurement uncertainty of a custom-made Fourier domain short coherence interferometer operated in laboratory conditions. We compared the optical thickness of two thickness standards and three coverslips determined with our interferometer to the geometric thickness determined by SEM. Using this calibration data, we derived a calibration function with a 95% confidence level system uncertainty of (5.9×10(-3)r+2.3)  μm, where r is the optical distance in μm, across the 240 μm optical measurement range. The confidence limit includes contributions from uncertainties in the optical thickness, geometric thickness, and refractive index measurements as well as uncertainties arising from cosine errors and thermal expansion. The results show feasibility for noncontacting absolute distance characterization with micrometer-level accuracy. This instrument is intended for verifying the alignment of the discs of an accelerating structure in the possible future compact linear collider.

  3. A new method for the absolute radiance calibration for UV-vis measurements of scattered sunlight

    NASA Astrophysics Data System (ADS)

    Wagner, T.; Beirle, S.; Dörner, S.; Penning de Vries, M.; Remmers, J.; Rozanov, A.; Shaiganfar, R.

    2015-10-01

    Absolute radiometric calibrations are important for measurements of the atmospheric spectral radiance. Such measurements can be used to determine actinic fluxes, the properties of aerosols and clouds, and the shortwave energy budget. Conventional calibration methods in the laboratory are based on calibrated light sources and reflectors and are expensive, time consuming and subject to relatively large uncertainties. Also, the calibrated instruments might change during transport from the laboratory to the measurement sites. Here we present a new calibration method for UV-vis instruments that measure the spectrally resolved sky radiance, for example zenith sky differential optical absorption spectroscopy (DOAS) instruments or multi-axis (MAX)-DOAS instruments. Our method is based on the comparison of the solar zenith angle dependence of the measured zenith sky radiance with radiative transfer simulations. For the application of our method, clear-sky measurements during periods with almost constant aerosol optical depth are needed. The radiative transfer simulations have to take polarisation into account. We show that the calibration results are almost independent from the knowledge of the aerosol optical properties and surface albedo, which causes a rather small uncertainty of about < 7 %. For wavelengths below about 330 nm it is essential that the ozone column density during the measurements be constant and known.

  4. Simultaneous spectrophotometric-multivariate calibration determination of several components of ophthalmic solutions: phenylephrine, chloramphenicol, antipyrine, methylparaben and thimerosal.

    PubMed

    Collado, M S; Mantovani, V E; Goicoechea, H C; Olivieri, A C

    2000-08-16

    The use of multivariate spectrophotometric calibration for the simultaneous determination of several active components and excipients in ophthalmic solutions is presented. The resolution of five-component mixtures of phenylephrine, chloramphenicol, antipyrine, methylparaben and thimerosal has been accomplished by using partial least-squares (PLS-1) and a variant of the so-called hybrid linear analysis (HLA). Notwithstanding the presence of a large number of components and their high degree of spectral overlap, they have been determined simultaneously with high accuracy and precision, with no interference, rapidly and without resorting to extraction procedures using non aqueous solvents. A simple and fast method for wavelength selection in the calibration step is presented, based on the minimisation of the predicted error sum of squares (PRESS) calculated as a function of a moving spectral window.

  5. Multispectral Photometry of the Moon and Absolute Calibration of the Clementine UV/Vis Camera

    NASA Astrophysics Data System (ADS)

    Hillier, John K.; Buratti, Bonnie J.; Hill, Kathryn

    1999-10-01

    We present a multispectral photometric study of the Moon between solar phase angles of 0 and 85°. Using Clementine images obtained between 0.4 and 1.0 μm, we produce a comprehensive study of the lunar surface containing the following results: (1) empirical photometric functions for the spectral range and viewing and illumination geometries mentioned, (2) photometric modeling that derives the physical properties of the upper regolith and includes a detailed study of the causes for the lunar opposition surge, (3) an absolute calibration of the Clementine UV/Vis camera. The calibration procedure given on the Clementine calibration web site produces reflectances relative to a halon standard and further appear significantly higher than those seen in groundbased observations. By comparing Clementine observations with prior groundbased observations of 15 sites on the Moon we have determined a good absolute calibration of the Clementine UV/Vis camera. A correction factor of 0.532 has been determined to convert the web site (www.planetary.brown.edu/clementine/calibration.html) reflectances to absolute values. From the calibrated data, we calculate empirical phase functions useful for performing photometric corrections to observations of the Moon between solar phase angles of 0 and 85° and in the spectral range 0.4 to 1.0μm. Finally, the calibrated data is used to fit a version of Hapke's photometric model modified to incorporate a new formulation, developed in this paper, of the lunar opposition surge which includes coherent backscatter. Recent studies of the lunar opposition effect have yielded contradictory results as to the mechanism responsible: shadow hiding, coherent backscatter, or both. We find that most of the surge can be explained by shadow hiding with a halfwidth of ˜8°. However, for the brightest regions (the highlands at 0.75-1.0μm) a small additional narrow component (halfwidth of <2°) of total amplitude ˜1/6 to 1/4 that of the shadow hiding surge is

  6. PREMOS Absolute Radiometer Calibration and Implications to on-orbit Measurements of the Total Solar Irradiance

    NASA Astrophysics Data System (ADS)

    Fehlmann, A.; Kopp, G.; Schmutz, W. K.; Winkler, R.; Finsterle, W.; Fox, N.

    2011-12-01

    On orbit measurements starting in the late 1970's, have revealed the 11 year cycle of the Total Solar Irradiance (TSI). However, the absolute results from individual experiments differ although all instrument teams claim to measure an absolute value. Especially the data from the TIM/SORCE experiment confused the community as it measures 0.3 % lower than the other instruments, e.g. VIRGO/SOHO by PMOD/WRC, which clearly exceeds the uncertainty stated for the absolute characterization of the experiments. The PREMOS package on the PICARD platform launched in June 2010 is the latest space experiment by PMOD/WRC measuring the TSI. We have put great effort in the calibration and characterization of this instrument in order to resolve the inter-instrument differences. We performed calibrations at the National Physical Laboratory (NPL) in London and the Laboratory for Atmospheric and Space Physics (LASP) in Boulder against national SI standards for radiant power using a laser beam with a diameter being smaller than the aperture of the instrument. These measurements together with the World Radiometric Reference (WRR) calibration in Davos allowed to compare the WRR and the SI radiant power scale. We found that the WRR lies 0.18 % above the SI radiant power scale which explains a part of the VIRGO-TIM difference. The Total solar irradiance Radiometer Facility (TRF) at the LASP allows to generate a beam that over fills the apertures of our instruments, giving the presently best available representation of solar irradiance in a laboratory. These irradiance calibrations revealed a stray light contribution between 0.09 and 0.3 % to the measurements which had been underestimated in the characterization of our instruments. Using the irradiance calibrations, we found that the WRR lies 0.32 % above the TRF scale which in turn explains the full VIRGO-TIM difference. The first light PREMOS measurements in space confirmed our findings. If we use the WRR calibration, PREMOS yields a TSI

  7. Absolute Calibration of Si iRMs used for Si Paleo-nutrient proxies

    NASA Astrophysics Data System (ADS)

    Vocke, Robert; Rabb, Savelas

    2016-04-01

    The Avogadro Project is an ongoing international effort, coordinated by the International Bureau of Weights and Measures (BIPM) and the International Avogadro Coordination (IAC) to redefine the SI unit mole in terms of the Avogadro constant and the SI unit kg in terms of the Planck constant. One of the outgrowths of this effort has been the development of a novel, precise and highly accurate method to measure calibrated (absolute) isotopic ratios that are traceable to the SI (Vocke et al., 2014 Metrologia 51, 361, Azuma et al., 2015 Metrologia 52 360). This approach has also been able to produce absolute Si isotope ratio data with lower levels of uncertainty when compared to the traditional "Atomic Weights" method of absolute isotope ratio measurement. Silicon isotope variations (reported as delta(Si30)and delta(Si29)) in silicic acid dissolved in ocean waters, in biogenic silica and in diatoms are extremely informative paleo-nutrient proxies. The utility and comparability of such measurements however depends on calibration with artifact isotopic Reference Materials (iRMs). We will be reporting new measurements on the iRMs NBS-28 (RM 8546 - Silica Sand), Diatomite, Big Batch and SRM 990 using the Avogadro measurement approach, comparing them with prior assessments of these iRMs.

  8. Precision evaluation of calibration factor of a superconducting gravimeter using an absolute gravimeter

    NASA Astrophysics Data System (ADS)

    Feng, Jin-yang; Wu, Shu-qing; Li, Chun-jian; Su, Duo-wu; Xu, Jin-yi; Yu, Mei

    2016-01-01

    The precision of the calibration factor of a superconducting gravimeter (SG) using an absolute gravimeter (AG) is analyzed based on linear least square fitting and error propagation theory and factors affecting the accuracy are discussed. It can improve the accuracy to choose the observation period of solid tide as a significant change or increase the calibration time. Simulation is carried out based on synthetic gravity tides calculated with T-soft at observed site from Aug. 14th to Sept. 2nd in 2014. The result indicates that the highest precision using half a day's observation data is below 0.28% and the precision exponentially increases with the increase of peak-to-peak gravity change. The comparison of results obtained from the same observation time indicated that using properly selected observation data has more beneficial on the improvement of precision. Finally, the calibration experiment of the SG iGrav-012 is introduced and the calibration factor is determined for the first time using AG FG5X-249. With 2.5 days' data properly selected from solid tide period with large tidal amplitude, the determined calibration factor of iGrav-012 is (-92.54423+/-0.13616) μGal/V (1μGal=10-8m/s2), with the relative accuracy of about 0.15%.

  9. Absolute intensity calibration of two-channel prototype ITER vacuum ultraviolet spectrometer with a collimating mirror.

    NASA Astrophysics Data System (ADS)

    Seon, Changrae; Hong, Joohwan; Cheon, Munseong; Pak, Sunil; Lee, Hyeongon; Biel, Wolfgang; Barnsley, Robin

    2012-10-01

    To optimize the design of ITER vacuum ultraviolet (VUV) spectrometer, a two-channel prototype spectrometer was implemented with No. 3 (14.4 nm -- 31.8 nm) and No. 4 (29.0 nm -- 60.0 nm) among the five channels. The prototype is composed of a toroidal mirror, and two toroidal diffraction gratings and two different detectors of the back-illuminated CCD and the micro-channel plate (MCP). To verify each optical component, the absolute intensity calibration was performed using the calibrated hollow cathode lamp. Inverse sensitivities of each spectrometer were derived by dividing the incident photon numbers with the measured detector counts. The measured sensitivity values were consistent with the sensitivities calculated from the grating and the detector efficiencies. Consequently the calibration curves of the two-channel VUV spectrometer were provided, and the mirror reflectivity and the detector efficiency could be confirmed experimentally. For the application of the calibrated spectrometer, measurements of impurity lines in KSTAR plasmas were performed, and the line integrated emissivity was derived from the calibration curve during impurity injection experiments.

  10. Absolute range calibration for JASON-1 and ENVISAT using a dedicated transponder

    NASA Astrophysics Data System (ADS)

    Cristea, E.; Pesec, P.

    2003-04-01

    Altimeter waveforms are used to study absolute range calibration for the altimeters on board of JASON-1 and ENVISAT. As a uniquely defined terrestrial reflection surface, a transponder is deployed within the footprint of the altimeter. The waveforms corresponding to the transponder distinguish themselves from the other waveforms resulting from natural targets in power and shape. When a satellite-borne altimeter passes over a ground-based active transponder, it makes within 3 to 4 seconds, 3000 - 4000 measurements of the satellite to transponder separation. That distance (range) varies in a parabolic fashion so that, when a parabolic curve is fitted to the measurements, the range at the point of the closest approach, that is the vertex of this parabola, can be determined with a resolution < 1mm. The accuracy of a single measurement of this sort is limited to about 2 - 3 cm by the ability to model the propagation delay in the atmosphere. The technique of using a dedicated transponder eliminates error sources such as tides and sea state bias and resolves the unknown altimeter calibration constant. Best results are obtained when the range window of the radar altimeter is preset to a fixed value during the transponder overpass, and this has been successfully used on RA-2 on board of ENVISAT. The poster presents the concept of absolute range calibration using a transponder and will show numerical results if relevant data are available.

  11. Absolute energy calibration of the Telescope Array fluorescence detector with an electron linear accelerator

    NASA Astrophysics Data System (ADS)

    Shibata, T.; Beitollahi, M.; Fukushima, M.; Ikeda, D.; Langely, K.; Matthews, J. N.; Sagawa, H.; Shin, B. K.; Thomas, S. B.; Thomson, G. B.

    2013-06-01

    The Electron Light Source(ELS) is a new light source for the absolute energy calibration of cosmic ray Fluorescence Detector(FD) telescopes. The ELS is a compact electron linear accelerator with a typical output of 109 electrons per pulse at 40 MeV. We fire the electron beam vertically into the air 100 m in front of the telescope. The electron beam excites the gases of the atmosphere in the same way as the charged particles of the cosmic ray induced extensive air shower. The gases give off the same light with the same wavelength dependence. The light passes through a small amount of atmosphere and is collected by the same mirror and camera with their wavelength dependence. In this way we can use the electron beam from ELS to make an end-to-end calibration of the telescope. In September 2010, we began operation of the ELS and the FD telescopes observed the fluorescence photons from the air shower which was generated by the electron beam. In this article, we will reort the status of analysis of the absolute energy calibration with data which was taken in September 2010, and beam monitor study in November 2011.

  12. In-Flight Absolute Radiometric Calibration of the Landsat Thematic Mapper

    NASA Astrophysics Data System (ADS)

    Kastner, Carol Jane

    The in-flight absolute radiometric calibration of the Thematic Mapper (TM) is being conducted using the results of field measurements at White Sands, New Mexico. These measurements are made to characterize the ground and atmosphere at the time the TM is acquiring an image of White Sands. The data are used as input to a radiative transfer code that computes the radiance at the entrance pupil of the TM. The calibration is obtained by comparing the digital counts associated with the TM image of the measured ground site with the radiative transfer code result. The calibrations discussed here are for the first four visible and near -infrared bands of the TM. In this dissertation the data reduction for the first calibration attempts on January 3, 1983, and July 8, 1984, is discussed. Included are a review of radiative transfer theory and a discussion of model atmospheric parameters as defined for the White Sands area. These model parameters are used to assess the errors associated with the calibration procedure. Each input parameter to the radiative transfer code is varied from its model value in proportion to the uncertainty with which it can be determined. The effects of these uncertainties on the predicted radiances are determined. It is thought that the optical depth components (tau)(,Ray), (tau)(,Mie), (tau)(,oz), and (tau)(,H(,2)O) can be measured to within 10%, 2%, 10%, and 30%, respectively. For the white gypsum sand, surface reflectance uniformity is on the order of 1.5%, and the overall uncertainty in measured reflectance is about 2%. This is due to an uncertainty in the reflectance factor of the calibration plates. The greatest uncertainty in calibration is attributed to our uncertainty in the aerosol parameters, in particular the imaginary component of refractive index. The cumulative effect of these uncertainties is thought to produce an uncertainty in computed radiance of about 5%.

  13. In-flight absolute calibration of the CBERS-2 CCD sensor data.

    PubMed

    Ponzoni, Flávio J; Zullo Junior, Jurandir; Lamparelli, Rubens A C

    2008-06-01

    Since the first images of the sensors on board of CBERS-2 (China-Brazil Earth Resources Satellite) satellite were made available by the National Institute for Space Research (INPE), users have asked information about the conversion of image digital numbers to physical data (radiance or reflectance). This paper describes the main steps that were carried out to calculate the in-flight absolute calibration coefficients for CBERS-2 CCD level 2 (radiometric and geometric correction) images considering the reflectance-based method. Remarks about the preliminary evaluation of these coefficients application are also presented.

  14. In-progress absolute radiometric inflight calibration of the LANDSAT-4 sensors

    NASA Technical Reports Server (NTRS)

    Castle, K.; Dinguirard, M.; Ezra, C. E.; Holm, R. G.; Jackson, R. J.; Kastner, C. J.; Palmer, J. M.; Savage, R.; Slater, P. N.

    1983-01-01

    An approach is described for providing periodic inflight absolute radiometric calibrations of the LANDSAT-4 sensors by reference to selected, instrumented ground areas. Results of some early ground measurements and computer simulations are presented. Selection of a suitable ground reference site, accurate measurement of the spectral reflectance of the selected area, determination of atmospheric characteristics during the morning of the sensor overpass, reduction of the measured data and their use in an appropriate atmospheric radiative transfer program, and comparison of the radiance level data with the digital counts of for the images of the selected areas are discussed. Preliminary measurements of gypsum are being made as an aid in defining the characteristics of field equipment to be constructed and calibrated for use over the White Sands Missile Range.

  15. Landsat-7 ETM+ on-orbit reflective-band radiometric stability and absolute calibration

    USGS Publications Warehouse

    Markham, B.L.; Thome, K.J.; Barsi, J.A.; Kaita, E.; Helder, Dennis L.; Barker, J. L.; Scaramuzza, Pat

    2004-01-01

    Launched in April 1999, the Landsat-7 Enhanced Thematic Mapper Plus (ETM+) instrument is in its sixth year of operation. The ETM+ instrument has been the most stable of any of the Landsat instruments. To date, the best onboard calibration source for the reflective bands has been the Full Aperture Solar Calibrator, a solar-diffuser-based system, which has indicated changes of between 1% to 2% per year in the ETM+ gain for bands 1-4 and 8 and less than 0.5%/year for bands 5 and 7. However, most of this change is believed to be caused by changes in the solar diffuser panel, as opposed to a change in the instrument's gain. This belief is based partially on vicarious calibrations and observations of "invariant sites", hyperarid sites of the Sahara and Arabia. Weighted average slopes determined from these datasets suggest changes of 0.0% to 0.4% per year for bands 1-4 and 8 and 0.4% to 0.5% per year for bands 5 and 7. Absolute calibration of the reflective bands of the ETM+ is consistent with vicarious observations and other sensors generally at the 5% level, though there appear to be some systematic differences.

  16. [In-flight absolute radiometric calibration of UAV hyperspectral camera and its validation analysis].

    PubMed

    Gou, Zhi-yang; Yan, Lei; Chen, Wei; Jing, Xin; Yin, Zhong-yi; Duan, Yi-ni

    2012-02-01

    With the data in Urad Front Banner, Inner Mongolia on November 14th, 2010, hyper-spectral camera on UAV was calibrated adopting reflectance-based method. During the in-flight absolute radiometric calibration, 6 hyper-spectral radiometric gray-scale targets were arranged in the validation field. These targets' reflectances are 4.5%, 20%, 30%, 40%, 50% and 60% separately. To validate the calibration result, four extra hyper-spectral targets with sharp-edge spectrum were arranged to simulate the reflection and absorption peaks in natural objectives. With these peaks, the apparent radiance calculated by radiation transfer model and that calculated through calibration coefficients are much different. The result shows that in the first 15 bands (blue bands), errors are somewhat huge due to the noises of equipment. In the rest bands with quite even spectrum, the errors are small, most of which are less than 10%. For those bands with sharp changes in spectral curves, the errors are quite considerable, varying from 10% to 25%.

  17. The absolute radiometric calibration of the advanced very high resolution radiometer

    NASA Technical Reports Server (NTRS)

    Slater, P. N.; Teillet, P. M.; Mao, Y.

    1987-01-01

    The early results of an absolute radiometric calibration of the NOAA-9 AVHRR sensor indicate significant degradations in the response of bands 1 and 2 compared to prelaunch values. The results are currently in the process of being verified and it may be that refinements of the methodology will be in order as additional data sets are analyzed. The LANDSAT TM calibration used in this approach is known to be very precise and the Herman radiative transfer code, supplemented by the 5-S code for gaseous transmission, is reliable as well. The extent to which other steps in the analysis procedure give rise to uncertainties in the results is currently under investigation. Particular attention is being given to the geometric matching of the AVHRR and TM imagery, as well as to the spectral redistribution procedure. By taking advantage of a reasonably precise calibration of TM imagery acquired on the same day as the AVHRR data at White Sands, a promising approach to the in-orbit calibration of AVHRR sensors is being developed. Current efforts involve primarily the examination of additional test cases and the investigation of possible simplifications in the procedure through judicious use of atmospheric models.

  18. The absolute radiometric calibration of the advanced very high resolution radiometer

    NASA Astrophysics Data System (ADS)

    Slater, P. N.; Teillet, P. M.; Mao, Y.

    1987-09-01

    The early results of an absolute radiometric calibration of the NOAA-9 AVHRR sensor indicate significant degradations in the response of bands 1 and 2 compared to prelaunch values. The results are currently in the process of being verified and it may be that refinements of the methodology will be in order as additional data sets are analyzed. The LANDSAT TM calibration used in this approach is known to be very precise and the Herman radiative transfer code, supplemented by the 5-S code for gaseous transmission, is reliable as well. The extent to which other steps in the analysis procedure give rise to uncertainties in the results is currently under investigation. Particular attention is being given to the geometric matching of the AVHRR and TM imagery, as well as to the spectral redistribution procedure. By taking advantage of a reasonably precise calibration of TM imagery acquired on the same day as the AVHRR data at White Sands, a promising approach to the in-orbit calibration of AVHRR sensors is being developed. Current efforts involve primarily the examination of additional test cases and the investigation of possible simplifications in the procedure through judicious use of atmospheric models.

  19. First Results of Field Absolute Calibration of the GPS Receiver Antenna at Wuhan University.

    PubMed

    Hu, Zhigang; Zhao, Qile; Chen, Guo; Wang, Guangxing; Dai, Zhiqiang; Li, Tao

    2015-11-13

    GNSS receiver antenna phase center variations (PCVs), which arise from the non-spherical phase response of GNSS signals have to be well corrected for high-precision GNSS applications. Without using a precise antenna phase center correction (PCC) model, the estimated position of a station monument will lead to a bias of up to several centimeters. The Chinese large-scale research project "Crustal Movement Observation Network of China" (CMONOC), which requires high-precision positions in a comprehensive GPS observational network motived establishment of a set of absolute field calibrations of the GPS receiver antenna located at Wuhan University. In this paper the calibration facilities are firstly introduced and then the multipath elimination and PCV estimation strategies currently used are elaborated. The validation of estimated PCV values of test antenna are finally conducted, compared with the International GNSS Service (IGS) type values. Examples of TRM57971.00 NONE antenna calibrations from our calibration facility demonstrate that the derived PCVs and IGS type mean values agree at the 1 mm level.

  20. First Results of Field Absolute Calibration of the GPS Receiver Antenna at Wuhan University

    PubMed Central

    Hu, Zhigang; Zhao, Qile; Chen, Guo; Wang, Guangxing; Dai, Zhiqiang; Li, Tao

    2015-01-01

    GNSS receiver antenna phase center variations (PCVs), which arise from the non-spherical phase response of GNSS signals have to be well corrected for high-precision GNSS applications. Without using a precise antenna phase center correction (PCC) model, the estimated position of a station monument will lead to a bias of up to several centimeters. The Chinese large-scale research project “Crustal Movement Observation Network of China” (CMONOC), which requires high-precision positions in a comprehensive GPS observational network motived establishment of a set of absolute field calibrations of the GPS receiver antenna located at Wuhan University. In this paper the calibration facilities are firstly introduced and then the multipath elimination and PCV estimation strategies currently used are elaborated. The validation of estimated PCV values of test antenna are finally conducted, compared with the International GNSS Service (IGS) type values. Examples of TRM57971.00 NONE antenna calibrations from our calibration facility demonstrate that the derived PCVs and IGS type mean values agree at the 1 mm level. PMID:26580616

  1. Absolute calibration method for nanosecond-resolved, time-streaked, fiber optic light collection, spectroscopy systems

    NASA Astrophysics Data System (ADS)

    Johnston, Mark D.; Oliver, Bryan V.; Droemer, Darryl W.; Frogget, Brent; Crain, Marlon D.; Maron, Yitzhak

    2012-08-01

    This paper describes a convenient and accurate method to calibrate fast (<1 ns resolution) streaked, fiber optic light collection, spectroscopy systems. Such systems are inherently difficult to calibrate due to the lack of sufficiently intense, calibrated light sources. Such a system is used to collect spectral data on plasmas generated in electron beam diodes fielded on the RITS-6 accelerator (8-12MV, 140-200kA) at Sandia National Laboratories. On RITS, plasma light is collected through a small diameter (200 μm) optical fiber and recorded on a fast streak camera at the output of a 1 meter Czerny-Turner monochromator. For this paper, a 300 W xenon short arc lamp (Oriel Model 6258) was used as the calibration source. Since the radiance of the xenon arc varies from cathode to anode, just the area around the tip of the cathode ("hotspot") was imaged onto the fiber, to produce the highest intensity output. To compensate for chromatic aberrations, the signal was optimized at each wavelength measured. Output power was measured using 10 nm bandpass interference filters and a calibrated photodetector. These measurements give power at discrete wavelengths across the spectrum, and when linearly interpolated, provide a calibration curve for the lamp. The shape of the spectrum is determined by the collective response of the optics, monochromator, and streak tube across the spectral region of interest. The ratio of the spectral curve to the measured bandpass filter curve at each wavelength produces a correction factor (Q) curve. This curve is then applied to the experimental data and the resultant spectra are given in absolute intensity units (photons/sec/cm2/steradian/nm). Error analysis shows this method to be accurate to within +/- 20%, which represents a high level of accuracy for this type of measurement.

  2. Absolute calibration method for nanosecond-resolved, time-streaked, fiber optic light collection, spectroscopy systems.

    PubMed

    Johnston, Mark D; Oliver, Bryan V; Droemer, Darryl W; Frogget, Brent; Crain, Marlon D; Maron, Yitzhak

    2012-08-01

    This paper describes a convenient and accurate method to calibrate fast (<1 ns resolution) streaked, fiber optic light collection, spectroscopy systems. Such systems are inherently difficult to calibrate due to the lack of sufficiently intense, calibrated light sources. Such a system is used to collect spectral data on plasmas generated in electron beam diodes fielded on the RITS-6 accelerator (8-12MV, 140-200kA) at Sandia National Laboratories. On RITS, plasma light is collected through a small diameter (200 μm) optical fiber and recorded on a fast streak camera at the output of a 1 meter Czerny-Turner monochromator. For this paper, a 300 W xenon short arc lamp (Oriel Model 6258) was used as the calibration source. Since the radiance of the xenon arc varies from cathode to anode, just the area around the tip of the cathode ("hotspot") was imaged onto the fiber, to produce the highest intensity output. To compensate for chromatic aberrations, the signal was optimized at each wavelength measured. Output power was measured using 10 nm bandpass interference filters and a calibrated photodetector. These measurements give power at discrete wavelengths across the spectrum, and when linearly interpolated, provide a calibration curve for the lamp. The shape of the spectrum is determined by the collective response of the optics, monochromator, and streak tube across the spectral region of interest. The ratio of the spectral curve to the measured bandpass filter curve at each wavelength produces a correction factor (Q) curve. This curve is then applied to the experimental data and the resultant spectra are given in absolute intensity units (photons/sec/cm(2)/steradian/nm). Error analysis shows this method to be accurate to within +∕- 20%, which represents a high level of accuracy for this type of measurement. PMID:22938275

  3. Absolute Calibration of the Radio Astronomy Flux Density Scale at 22 to 43 GHz Using Planck

    NASA Astrophysics Data System (ADS)

    Partridge, B.; López-Caniego, M.; Perley, R. A.; Stevens, J.; Butler, B. J.; Rocha, G.; Walter, B.; Zacchei, A.

    2016-04-01

    The Planck mission detected thousands of extragalactic radio sources at frequencies from 28 to 857 GHz. Planck's calibration is absolute (in the sense that it is based on the satellite’s annual motion around the Sun and the temperature of the cosmic microwave background), and its beams are well characterized at sub-percent levels. Thus, Planck's flux density measurements of compact sources are absolute in the same sense. We have made coordinated Very Large Array (VLA) and Australia Telescope Compact Array (ATCA) observations of 65 strong, unresolved Planck sources in order to transfer Planck's calibration to ground-based instruments at 22, 28, and 43 GHz. The results are compared to microwave flux density scales currently based on planetary observations. Despite the scatter introduced by the variability of many of the sources, the flux density scales are determined to 1%-2% accuracy. At 28 GHz, the flux density scale used by the VLA runs 2%-3% ± 1.0% below Planck values with an uncertainty of +/- 1.0%; at 43 GHz, the discrepancy increases to 5%-6% ± 1.4% for both ATCA and the VLA.

  4. Pantomime-Grasping: Advance Knowledge of Haptic Feedback Availability Supports an Absolute Visuo-Haptic Calibration.

    PubMed

    Davarpanah Jazi, Shirin; Heath, Matthew

    2016-01-01

    An emerging issue in movement neurosciences is whether haptic feedback influences the nature of the information supporting a simulated grasping response (i.e., pantomime-grasping). In particular, recent work by our group contrasted pantomime-grasping responses performed with (i.e., PH+ trials) and without (i.e., PH- trials) terminal haptic feedback in separate blocks of trials. Results showed that PH- trials were mediated via relative visual information. In contrast, PH+ trials showed evidence of an absolute visuo-haptic calibration-a finding attributed to an error signal derived from a comparison between expected and actual haptic feedback (i.e., an internal forward model). The present study examined whether advanced knowledge of haptic feedback availability influences the aforementioned calibration process. To that end, PH- and PH+ trials were completed in separate blocks (i.e., the feedback schedule used in our group's previous study) and a block wherein PH- and PH+ trials were randomly interleaved on a trial-by-trial basis (i.e., random feedback schedule). In other words, the random feedback schedule precluded participants from predicting whether haptic feedback would be available at the movement goal location. We computed just-noticeable-difference (JND) values to determine whether responses adhered to, or violated, the relative psychophysical principles of Weber's law. Results for the blocked feedback schedule replicated our group's previous work, whereas in the random feedback schedule PH- and PH+ trials were supported via relative visual information. Accordingly, we propose that a priori knowledge of haptic feedback is necessary to support an absolute visuo-haptic calibration. Moreover, our results demonstrate that the presence and expectancy of haptic feedback is an important consideration in contrasting the behavioral and neural properties of natural and simulated grasping. PMID:27199718

  5. Absolute calibration method for laser megajoule neutron yield measurement by activation diagnostics

    NASA Astrophysics Data System (ADS)

    Landoas, Olivier; Yu Glebov, Vladimir; Rossé, Bertrand; Briat, Michelle; Disdier, Laurent; Sangster, Thomas C.; Duffy, Tim; Marmouget, Jean Gabriel; Varignon, Cyril; Ledoux, Xavier; Caillaud, Tony; Thfoin, Isabelle; Bourgade, Jean-Luc

    2011-07-01

    The laser megajoule (LMJ) and the National Ignition Facility (NIF) plan to demonstrate thermonuclear ignition using inertial confinement fusion (ICF). The neutron yield is one of the most important parameters to characterize ICF experiment performance. For decades, the activation diagnostic was chosen as a reference at ICF facilities and is now planned to be the first nuclear diagnostic on LMJ, measuring both 2.45 MeV and 14.1 MeV neutron yields. Challenges for the activation diagnostic development are absolute calibration, accuracy, range requirement, and harsh environment. At this time, copper and zirconium material are identified for 14.1 MeV neutron yield measurement and indium material for 2.45 MeV neutrons. A series of calibrations were performed at Commissariat à l'Energie Atomique (CEA) on a Van de Graff facility to determine activation diagnostics efficiencies and to compare them with results from calculations. The CEA copper activation diagnostic was tested on the OMEGA facility during DT implosion. Experiments showed that CEA and Laboratory for Laser Energetics (LLE) diagnostics agree to better than 1% on the neutron yield measurement, with an independent calibration for each system. Also, experimental sensitivities are in good agreement with simulations and allow us to scale activation diagnostics for the LMJ measurement range.

  6. ScaRaB: first results of absolute and cross calibration

    NASA Astrophysics Data System (ADS)

    Trémas, Thierry L.; Aznay, Ouahid; Chomette, Olivier

    2015-10-01

    ScaRaB (SCAnner for RAdiation Budget) is the name of three radiometers whose two first flight models have been launched in 1994 and 1997. The instruments were mounted on-board Russian satellites, METEOR and RESURS. On October 12th 2011, a last model has been launched from the Indian site of Sriharikota. ScaRaB is a passenger of MEGHA-TROPIQUES, an Indo-French joint Satellite Mission for studying the water cycle and energy exchanges in the tropics. ScaRaB is composed of four parallel and independent channels. Channel-2 and channel-3 are considered as the main ones. Channel-1 is dedicated to measure solar radiance (0.5 to 0.7 μm) while channel-4 (10 to 13 μm) is an infrared window. The absolute calibration of ScaRab is assured by internal calibration sources (black bodies and a lamp for channel-1). However, during the commissioning phase, the lamp used for the absolute calibration of channel-1 revealed to be inaccurate. We propose here an alternative calibration method based on terrestrial targets. Due to the spectral range of channel-1, only calibration over desert sites (temporal monitoring) and clouds (cross band) is suitable. Desert sites have been widely used for sensor calibration since they have a stable spectral response over time. Because of their high reflectances, the atmospheric effect on the upward radiance is relatively minimal. In addition, they are spatially uniform. Their temporal instability without atmospheric correction has been determined to be less than 1-2% over a year. Very-high-altitude (10 km) bright clouds are good validation targets in the visible and near-infrared spectra because of their high spectrally consistent reflectance. If the clouds are very high, there is no need to correct aerosol scattering and water vapor absorption as both aerosol and water vapor are distributed near the surface. Only Rayleigh scattering and ozone absorption need to be considered. This method has been found to give a 4% uncertainty. Radiometric cross

  7. Absolute Density Calibration Cell for Laser Induced Fluorescence Erosion Rate Measurements

    NASA Technical Reports Server (NTRS)

    Domonkos, Matthew T.; Stevens, Richard E.

    2001-01-01

    Flight qualification of ion thrusters typically requires testing on the order of 10,000 hours. Extensive knowledge of wear mechanisms and rates is necessary to establish design confidence prior to long duration tests. Consequently, real-time erosion rate measurements offer the potential both to reduce development costs and to enhance knowledge of the dependency of component wear on operating conditions. Several previous studies have used laser-induced fluorescence (LIF) to measure real-time, in situ erosion rates of ion thruster accelerator grids. Those studies provided only relative measurements of the erosion rate. In the present investigation, a molybdenum tube was resistively heated such that the evaporation rate yielded densities within the tube on the order of those expected from accelerator grid erosion. This work examines the suitability of the density cell as an absolute calibration source for LIF measurements, and the intrinsic error was evaluated.

  8. An Investigation of Mars NIR Spectral Features using Absolutely Calibrated Images

    NASA Astrophysics Data System (ADS)

    Klassen, D. R.; Bell, J. F., III

    1998-09-01

    We used the NSFCAM 256x256 InSb array camera at the NASA Infrared Telescope Facility to gather near-infrared (NIR) spectral image sets of Mars through the 1995 opposition. In previous studies with these data [1-6] we noted several interesting spectral features, some of which are diagnostic volatile absorption bands that allow the discrimination between CO_2 or H_2O ices. Band depth maps of these regions show polar and morning and evening limb ices composed of water and some indication of polar CO_2 ices. Other features, near 3.33 and 3.4\\micron, appear to be confined to particular geographic regions; specifically Syrtis Major. However, the images used in these previous studies were calibrated to either the disk average or only to a rough scaled reflectance by simple division by solar-type star data gathered at the same time as the images. This only allowed determinations of spectral features either relative to some global average of the feature, or to some unit not directly comparable to other published data. For at least three of our observation nights the conditions and data are sufficient to absolutely calibrate the images to radiance factors. For this work we reinvestigate the spectra and band depth mapping results using these absolutely calibrated images. In general we find that bright regions have peak radiance factors of 0.5 to 0.6 at 2.25\\micron\\ and 0.3 to 0.4 at 3.5\\micron; dark regions have radiance factors of 0.2 to 0.25 at 2.25\\micron\\ and 0.1 to 0.15 at 3.5\\micron. Overall, precision errors are about 0.025 in radiance factor and absolute errors are at the 10-15% level. These results are consistent with previous studies that found radiance factors of 0.35 in Tharsis, 0.47 in Elysium, and 0.26 in dark regions at 2.25\\micron\\ [7,8] and 0.3 in bright regions and 0.1 in dark regions at 3.5\\micron\\ [8]. These absolute flux values will allow direct comparison of these results to radiative transfer models of the behavior of the surface and

  9. Comb-calibrated frequency-modulated continuous-wave ladar for absolute distance measurements.

    PubMed

    Baumann, Esther; Giorgetta, Fabrizio R; Coddington, Ian; Sinclair, Laura C; Knabe, Kevin; Swann, William C; Newbury, Nathan R

    2013-06-15

    We demonstrate a comb-calibrated frequency-modulated continuous-wave laser detection and ranging (FMCW ladar) system for absolute distance measurements. The FMCW ladar uses a compact external cavity laser that is swept quasi-sinusoidally over 1 THz at a 1 kHz rate. The system simultaneously records the heterodyne FMCW ladar signal and the instantaneous laser frequency at sweep rates up to 3400 THz/s, as measured against a free-running frequency comb (femtosecond fiber laser). Demodulation of the ladar signal against the instantaneous laser frequency yields the range to the target with 1 ms update rates, bandwidth-limited 130 μm resolution and a ~100 nm accuracy that is directly linked to the counted repetition rate of the comb. The precision is <100 nm at the 1 ms update rate and reaches ~6 nm for a 100 ms average. PMID:23938965

  10. Pantomime-Grasping: Advance Knowledge of Haptic Feedback Availability Supports an Absolute Visuo-Haptic Calibration

    PubMed Central

    Davarpanah Jazi, Shirin; Heath, Matthew

    2016-01-01

    An emerging issue in movement neurosciences is whether haptic feedback influences the nature of the information supporting a simulated grasping response (i.e., pantomime-grasping). In particular, recent work by our group contrasted pantomime-grasping responses performed with (i.e., PH+ trials) and without (i.e., PH− trials) terminal haptic feedback in separate blocks of trials. Results showed that PH− trials were mediated via relative visual information. In contrast, PH+ trials showed evidence of an absolute visuo-haptic calibration—a finding attributed to an error signal derived from a comparison between expected and actual haptic feedback (i.e., an internal forward model). The present study examined whether advanced knowledge of haptic feedback availability influences the aforementioned calibration process. To that end, PH− and PH+ trials were completed in separate blocks (i.e., the feedback schedule used in our group’s previous study) and a block wherein PH− and PH+ trials were randomly interleaved on a trial-by-trial basis (i.e., random feedback schedule). In other words, the random feedback schedule precluded participants from predicting whether haptic feedback would be available at the movement goal location. We computed just-noticeable-difference (JND) values to determine whether responses adhered to, or violated, the relative psychophysical principles of Weber’s law. Results for the blocked feedback schedule replicated our group’s previous work, whereas in the random feedback schedule PH− and PH+ trials were supported via relative visual information. Accordingly, we propose that a priori knowledge of haptic feedback is necessary to support an absolute visuo-haptic calibration. Moreover, our results demonstrate that the presence and expectancy of haptic feedback is an important consideration in contrasting the behavioral and neural properties of natural and simulated grasping. PMID:27199718

  11. Absolute calibration accuracy of L4 TM and L5 TM sensor image pairs

    USGS Publications Warehouse

    Chander, G.; Micijevic, E.

    2006-01-01

    The Landsat suite of satellites has collected the longest continuous archive of multispectral data of any land-observing space program. From the Landsat program's inception in 1972 to the present, the Earth science user community has benefited from a historical record of remotely sensed data. However, little attention has been paid to ensuring that the data are calibrated and comparable from mission to mission, Launched in 1982 and 1984 respectively, the Landsat 4 (L4) and Landsat 5 (L5) Thematic Mappers (TM) are the backbone of an extensive archive of moderate resolution Earth imagery. To evaluate the "current" absolute accuracy of these two sensors, image pairs from the L5 TM and L4 TM sensors were compared. The approach involves comparing image statistics derived from large common areas observed eight days apart by the two sensors. The average percent differences in reflectance estimates obtained from the L4 TM agree with those from the L5 TM to within 15 percent. Additional work to characterize the absolute differences between the two sensors over the entire mission is in progress.

  12. A dedicated pistonphone for absolute calibration of infrasound sensors at very low frequencies

    NASA Astrophysics Data System (ADS)

    He, Wen; He, Longbiao; Zhang, Fan; Rong, Zuochao; Jia, Shushi

    2016-02-01

    Aimed at the absolute calibration of infrasound sensors at very low frequencies, an upgraded and improved infrasonic pistonphone has been developed. The pistonphone was designed such that a very narrow clearance between the piston and its guide was realized based on an automatically-centered clearance-sealing structure, and a large volume rigid-walled chamber was also adopted, which improved the leakage time-constant of the chamber. A composite feedback control system was applied to the electromagnetic vibrator to control the precise motion of the piston. Performance tests and uncertainty analysis show that the leakage time-constant is so large, and the distortion of the sound pressure is so small, that the pistonphone can be used as a standard infrasound source in the frequency range from 0.001 Hz to 20 Hz. The low frequency property of the pistonphone has been verified through calibrating low frequency microphones. Comparison tests with the reciprocity method have shown that the pressure sensitivities from the pistonphone are not only reliable at common frequencies but also have smaller uncertainties at low frequencies.

  13. Absolute energy calibration for relativistic electron beams with pointing instability from a laser-plasma accelerator

    SciTech Connect

    Cha, H. J.; Choi, I. W.; Kim, H. T.; Kim, I J.; Nam, K. H.; Jeong, T. M.; Lee, J.

    2012-06-15

    The pointing instability of energetic electron beams generated from a laser-driven accelerator can cause a serious error in measuring the electron spectrum with a magnetic spectrometer. In order to determine a correct electron spectrum, the pointing angle of an electron beam incident on the spectrometer should be exactly defined. Here, we present a method for absolutely calibrating the electron spectrum by monitoring the pointing angle using a scintillating screen installed in front of a permanent dipole magnet. The ambiguous electron energy due to the pointing instability is corrected by the numerical and analytical calculations based on the relativistic equation of electron motion. It is also possible to estimate the energy spread of the electron beam and determine the energy resolution of the spectrometer using the beam divergence angle that is simultaneously measured on the screen. The calibration method with direct measurement of the spatial profile of an incident electron beam has a simple experimental layout and presents the full range of spatial and spectral information of the electron beams with energies of multi-hundred MeV level, despite the limited energy resolution of the simple electron spectrometer.

  14. ABSOLUTE RADIOMETRIC CALIBRATION OF THE EUNIS-06 170-205 A CHANNEL AND CALIBRATION UPDATE FOR CORONAL DIAGNOSTIC SPECTROMETER/NORMAL-INCIDENCE SPECTROMETER

    SciTech Connect

    Wang Tongjiang; Brosius, Jeffrey W.; Thomas, Roger J.; Rabin, Douglas M.; Davila, Joseph M.

    2010-02-01

    The Extreme-Ultraviolet Normal-Incidence Spectrograph sounding-rocket payload was flown on 2006 April 12 (EUNIS-06), carrying two independent imaging spectrographs covering wavebands of 300-370 A in first order and 170-205 A in second order, respectively. The absolute radiometric response of the EUNIS-06 long-wavelength (LW) channel was directly measured in the same facility used to calibrate Coronal Diagnostic Spectrometer (CDS) prior to the Solar and Heliospheric Observatory (SOHO) launch. Because the absolute calibration of the short-wavelength (SW) channel could not be obtained from the same lab configuration, we here present a technique to derive it using a combination of solar LW spectra and density- and temperature-insensitive line intensity ratios. The first step in this procedure is to use the coordinated, cospatial EUNIS and SOHO/CDS spectra to carry out an intensity calibration update for the CDS NIS-1 waveband, which shows that its efficiency has decreased by a factor about 1.7 compared to that of the previously implemented calibration. Then, theoretical insensitive line ratios obtained from CHIANTI allow us to determine absolute intensities of emission lines within the EUNIS SW bandpass from those of cospatial CDS/NIS-1 spectra after the EUNIS LW calibration correction. A total of 12 ratios derived from intensities of 5 CDS and 12 SW emission lines from Fe X to Fe XIII yield an instrumental response curve for the EUNIS-06 SW channel that matches well to a relative calibration which relied on combining measurements of individual optical components. Taking into account all potential sources of error, we estimate that the EUNIS-06 SW absolute calibration is accurate to {+-}20%.

  15. A new solar irradiance calibration from 3295 A to 8500 A derived from absolute spectrophotometry of Vega

    NASA Technical Reports Server (NTRS)

    Lockwood, G. W.; Tueg, H.; White, N. M.

    1992-01-01

    By imaging sunlight diffracted by 20- and 30-micron diameter pinholes onto the entrance aperture of a photoelectric grating scanner, the solar spectral irradiance was determined relative to the spectrophotometric standard star Vega, observed at night with the same instrument. Solar irradiances are tabulated at 4 A increments from 3295 A to 8500 A. Over most of the visible spectrum, the internal error of measurement is less than 2 percent. This calibration is compared with earlier irradiance measurements by Neckel and Labs (1984) and by Arvesen et al. (1969) and with the high-resolution solar atlas by Kurucz et al. The three calibrations agree well in visible light but differ by as much as 10 percent in the ultraviolet.

  16. A BAYESIAN METHOD FOR CALCULATING REAL-TIME QUANTITATIVE PCR CALIBRATION CURVES USING ABSOLUTE PLASMID DNA STANDARDS

    EPA Science Inventory

    In real-time quantitative PCR studies using absolute plasmid DNA standards, a calibration curve is developed to estimate an unknown DNA concentration. However, potential differences in the amplification performance of plasmid DNA compared to genomic DNA standards are often ignore...

  17. Test Plan for a Calibration Demonstration System for the Reflected Solar Instrument for the Climate Absolute Radiance and Refractivity Observatory

    NASA Technical Reports Server (NTRS)

    Thome, Kurtis; McCorkel, Joel; Hair, Jason; McAndrew, Brendan; Daw, Adrian; Jennings, Donald; Rabin, Douglas

    2012-01-01

    The Climate Absolute Radiance and Refractivity Observatory (CLARREO) mission addresses the need to observe high-accuracy, long-term climate change trends and to use decadal change observations as the most critical method to determine the accuracy of climate change. One of the major objectives of CLARREO is to advance the accuracy of SI traceable absolute calibration at infrared and reflected solar wavelengths. This advance is required to reach the on-orbit absolute accuracy required to allow climate change observations to survive data gaps while remaining sufficiently accurate to observe climate change to within the uncertainty of the limit of natural variability. While these capabilities exist at NIST in the laboratory, there is a need to demonstrate that it can move successfully from NIST to NASA and/or instrument vendor capabilities for future spaceborne instruments. The current work describes the test plan for the Solar, Lunar for Absolute Reflectance Imaging Spectroradiometer (SOLARIS) which is the calibration demonstration system (CDS) for the reflected solar portion of CLARREO. The goal of the CDS is to allow the testing and evaluation of calibration approaches , alternate design and/or implementation approaches and components for the CLARREO mission. SOLARIS also provides a test-bed for detector technologies, non-linearity determination and uncertainties, and application of future technology developments and suggested spacecraft instrument design modifications. The end result of efforts with the SOLARIS CDS will be an SI-traceable error budget for reflectance retrieval using solar irradiance as a reference and methods for laboratory-based, absolute calibration suitable for climate-quality data collections. The CLARREO mission addresses the need to observe high-accuracy, long-term climate change trends and advance the accuracy of SI traceable absolute calibration. The current work describes the test plan for the SOLARIS which is the calibration demonstration

  18. A comparison of absolute calibrations of a radiation thermometer based on a monochromator and a tunable source

    SciTech Connect

    Keawprasert, T.; Anhalt, K.; Taubert, D. R.; Sperling, A.; Schuster, M.; Nevas, S.

    2013-09-11

    An LP3 radiation thermometer was absolutely calibrated at a newly developed monochromator-based set-up and the TUneable Lasers in Photometry (TULIP) facility of PTB in the wavelength range from 400 nm to 1100 nm. At both facilities, the spectral radiation of the respective sources irradiates an integrating sphere, thus generating uniform radiance across its precision aperture. The spectral irradiance of the integrating sphere is determined via an effective area of a precision aperture and a Si trap detector, traceable to the primary cryogenic radiometer of PTB. Due to the limited output power from the monochromator, the absolute calibration was performed with the measurement uncertainty of 0.17 % (k= 1), while the respective uncertainty at the TULIP facility is 0.14 %. Calibration results obtained by the two facilities were compared in terms of spectral radiance responsivity, effective wavelength and integral responsivity. It was found that the measurement results in integral responsivity at the both facilities are in agreement within the expanded uncertainty (k= 2). To verify the calibration accuracy, the absolutely calibrated radiation thermometer was used to measure the thermodynamic freezing temperatures of the PTB gold fixed-point blackbody.

  19. A comparison of absolute calibrations of a radiation thermometer based on a monochromator and a tunable source

    NASA Astrophysics Data System (ADS)

    Keawprasert, T.; Anhalt, K.; Taubert, D. R.; Sperling, A.; Schuster, M.; Nevas, S.

    2013-09-01

    An LP3 radiation thermometer was absolutely calibrated at a newly developed monochromator-based set-up and the TUneable Lasers in Photometry (TULIP) facility of PTB in the wavelength range from 400 nm to 1100 nm. At both facilities, the spectral radiation of the respective sources irradiates an integrating sphere, thus generating uniform radiance across its precision aperture. The spectral irradiance of the integrating sphere is determined via an effective area of a precision aperture and a Si trap detector, traceable to the primary cryogenic radiometer of PTB. Due to the limited output power from the monochromator, the absolute calibration was performed with the measurement uncertainty of 0.17 % (k = 1), while the respective uncertainty at the TULIP facility is 0.14 %. Calibration results obtained by the two facilities were compared in terms of spectral radiance responsivity, effective wavelength and integral responsivity. It was found that the measurement results in integral responsivity at the both facilities are in agreement within the expanded uncertainty (k = 2). To verify the calibration accuracy, the absolutely calibrated radiation thermometer was used to measure the thermodynamic freezing temperatures of the PTB gold fixed-point blackbody.

  20. Error Budget for a Calibration Demonstration System for the Reflected Solar Instrument for the Climate Absolute Radiance and Refractivity Observatory

    NASA Technical Reports Server (NTRS)

    Thome, Kurtis; McCorkel, Joel; McAndrew, Brendan

    2013-01-01

    A goal of the Climate Absolute Radiance and Refractivity Observatory (CLARREO) mission is to observe highaccuracy, long-term climate change trends over decadal time scales. The key to such a goal is to improving the accuracy of SI traceable absolute calibration across infrared and reflected solar wavelengths allowing climate change to be separated from the limit of natural variability. The advances required to reach on-orbit absolute accuracy to allow climate change observations to survive data gaps exist at NIST in the laboratory, but still need demonstration that the advances can move successfully from to NASA and/or instrument vendor capabilities for spaceborne instruments. The current work describes the radiometric calibration error budget for the Solar, Lunar for Absolute Reflectance Imaging Spectroradiometer (SOLARIS) which is the calibration demonstration system (CDS) for the reflected solar portion of CLARREO. The goal of the CDS is to allow the testing and evaluation of calibration approaches, alternate design and/or implementation approaches and components for the CLARREO mission. SOLARIS also provides a test-bed for detector technologies, non-linearity determination and uncertainties, and application of future technology developments and suggested spacecraft instrument design modifications. The resulting SI-traceable error budget for reflectance retrieval using solar irradiance as a reference and methods for laboratory-based, absolute calibration suitable for climatequality data collections is given. Key components in the error budget are geometry differences between the solar and earth views, knowledge of attenuator behavior when viewing the sun, and sensor behavior such as detector linearity and noise behavior. Methods for demonstrating this error budget are also presented.

  1. Improved Strategies and Optimization of Calibration Models for Real-time PCR Absolute Quantification

    EPA Science Inventory

    Real-time PCR absolute quantification applications rely on the use of standard curves to make estimates of DNA target concentrations in unknown samples. Traditional absolute quantification approaches dictate that a standard curve must accompany each experimental run. However, t...

  2. Absolute Dating of Desert Varnish Using Portable X-Ray Fluorescence: Calibration and Testing

    NASA Astrophysics Data System (ADS)

    Pingitore, N. E.; Lytle, F. W.; Rowley, P. D.; Ferris, D. E.

    2004-12-01

    Desert varnish, also called rock varnish, is a thin biogenic layer of Mn-oxides, Fe-oxides, and clays that coats rock surfaces in arid and semi-arid regions. The mass of these metals in the varnish registers cumulative biologic activity over time and presents a possible dating mechanism, subject to appropriate assumptions and restrictions. We have used a portable x-ray fluorescence (PXRF) unit to measure Mn and Fe in numerous desert varnishes, both in the field and laboratory; the anticipated relationship between age and mass emerges from these data. Our attempts to refine the PXRF technique for absolute dating of desert varnish are confounded by the limited number of "dated" varnishes available to calibrate and test the method. Although there is no current method to directly ascertain the age of desert varnish, our search for "dated" varnishes has yielded three suitable types of test materials: (1) The ages of young basalt flows dated by various K/Ar radiometric techniques represent the maximum age of varnish developed on those surfaces. Such rocks are useful in the time range of perhaps 250,000 to 10,000 years; surface spalling with loss of varnish presents an upper time limit and difficulty in dating Holocene basalts presents a lower limit. Basalt flows typically provide horizontal surfaces that are ideal for PXRF measurements because, as a biogenic process, varnish development even at a single site varies with solar orientation. (2) Petroglyphs are the rock art that native peoples produced by pecking away varnish to expose fresh rock. This process restarts varnish development and the pecked surface gradually repatinates over time. At some locales, certain figures, symbols, and stylistic elements can be associated with an archaeological culture of known antiquity and duration, thus providing an age range for such glyphs. In the desert Southwest and Great Basin of the United States, appropriate glyphs are known from the present to at least 7000 years BP. Many of

  3. Absolute radiometric calibration of Als intensity data: effects on accuracy and target classification.

    PubMed

    Kaasalainen, Sanna; Pyysalo, Ulla; Krooks, Anssi; Vain, Ants; Kukko, Antero; Hyyppä, Juha; Kaasalainen, Mikko

    2011-01-01

    Radiometric calibration of airborne laser scanning (ALS) intensity data aims at retrieving a value related to the target scattering properties, which is independent on the instrument or flight parameters. The aim of a calibration procedure is also to be able to compare results from different flights and instruments, but practical applications are sparsely available, and the performance of calibration methods for this purpose needs to be further assessed. We have studied the radiometric calibration with data from three separate flights and two different instruments using external calibration targets. We find that the intensity data from different flights and instruments can be compared to each other only after a radiometric calibration process using separate calibration targets carefully selected for each flight. The calibration is also necessary for target classification purposes, such as separating vegetation from sand using intensity data from different flights. The classification results are meaningful only for calibrated intensity data.

  4. Absolute radiometric calibration of Als intensity data: effects on accuracy and target classification.

    PubMed

    Kaasalainen, Sanna; Pyysalo, Ulla; Krooks, Anssi; Vain, Ants; Kukko, Antero; Hyyppä, Juha; Kaasalainen, Mikko

    2011-01-01

    Radiometric calibration of airborne laser scanning (ALS) intensity data aims at retrieving a value related to the target scattering properties, which is independent on the instrument or flight parameters. The aim of a calibration procedure is also to be able to compare results from different flights and instruments, but practical applications are sparsely available, and the performance of calibration methods for this purpose needs to be further assessed. We have studied the radiometric calibration with data from three separate flights and two different instruments using external calibration targets. We find that the intensity data from different flights and instruments can be compared to each other only after a radiometric calibration process using separate calibration targets carefully selected for each flight. The calibration is also necessary for target classification purposes, such as separating vegetation from sand using intensity data from different flights. The classification results are meaningful only for calibrated intensity data. PMID:22346660

  5. Exploring a Black Body Source as an Absolute Radiometric Calibration Standard and Comparison with a NIST Traced Lamp Standard

    NASA Technical Reports Server (NTRS)

    Green, Robert O.; Chrien, Thomas; Sarture, Chuck

    2001-01-01

    Radiometric calibration of the Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) is required for the scientific research and application objectives pursued with the spectroscopic measurements. Specifically calibration is required for: inter-comparison of AVIRIS data measured at different locations and at different times; analysis of AVIRIS data with data measured by other instruments; and analysis of AVIRIS data in conjunction with computer models. The primary effect of radiometric calibration is conversion of AVIRIS instrument response values (digitized numbers, or DN) to units of absolute radiance. For example, a figure shows the instrument response spectrum measured by AVIRIS over a portion of Rogers Dry Lake, California, and another figure shows the same spectrum calibrated to radiance. Only the calibrated spectrum may be quantitatively analyzed for science research and application objectives. Since the initial development of the AVIRIS instrument-radiometric calibration has been based upon a 1000-W irradiance lamp with a calibration traced to the National Institute of Standards and Technology (NIST). There are several advantages to this irradiance-lamp calibration approach. First, the considerable effort of NIST backs up the calibration. Second, by changing the distance to the lamp, the output can closely span the radiance levels measured by AVIRIS. Third, this type of standard is widely used. Fourth, these calibrated lamps are comparatively inexpensive. Conversely, there are several disadvantages to this approach as well. First, the lamp is not a primary standard. Second, the lamp output characteristics may change in an unknown manner through time. Third, it is difficult to assess, constrain, or improve the calibration uncertainty delivered with the lamp. In an attempt to explore the effect and potentially address some of these disadvantages a set of analyses and measurements comparing an irradiance lamp with a black-body source have been completed

  6. Absolute Calibration of Image Plate for electrons at energy between 100 keV and 4 MeV

    SciTech Connect

    Chen, H; Back, N L; Eder, D C; Ping, Y; Song, P M; Throop, A

    2007-12-10

    The authors measured the absolute response of image plate (Fuji BAS SR2040) for electrons at energies between 100 keV to 4 MeV using an electron spectrometer. The electron source was produced from a short pulse laser irradiated on the solid density targets. This paper presents the calibration results of image plate Photon Stimulated Luminescence PSL per electrons at this energy range. The Monte Carlo radiation transport code MCNPX results are also presented for three representative incident angles onto the image plates and corresponding electron energies depositions at these angles. These provide a complete set of tools that allows extraction of the absolute calibration to other spectrometer setting at this electron energy range.

  7. Spectrophotometric catalogs and databases

    NASA Astrophysics Data System (ADS)

    Burnashev, V. I.; Burnasheva, B. A.

    2014-06-01

    An overview is given of different spectrophotometric catalogs, including a brief description of the applications of absolute spectrophotometry in evolutionary population synthesis. Observational data for different stars are given. A list of catalogs is presented, including those containing intrinsic energy distributions for stars of different temperatures and luminosities, spectrophotometric standards, extragalactic sources, and theoretically calculated spectra. A number of useful links and Internet resources are provided.

  8. Absolute Radiometric Calibration of Narrow-Swath Imaging Sensors with Reference to Non-Coincident Wide-Swath Sensors

    NASA Technical Reports Server (NTRS)

    McCorkel, Joel; Thome, Kurtis; Lockwood, Ronald

    2012-01-01

    An inter-calibration method is developed to provide absolute radiometric calibration of narrow-swath imaging sensors with reference to non-coincident wide-swath sensors. The method predicts at-sensor radiance using non-coincident imagery from the reference sensor and knowledge of spectral reflectance of the test site. The imagery of the reference sensor is restricted to acquisitions that provide similar view and solar illumination geometry to reduce uncertainties due to directional reflectance effects. Spectral reflectance of the test site is found with a simple iterative radiative transfer method using radiance values of a well-understood wide-swath sensor and spectral shape information based on historical ground-based measurements. At-sensor radiance is calculated for the narrow-swath sensor using this spectral reflectance and atmospheric parameters that are also based on historical in situ measurements. Results of the inter-calibration method show agreement on the 2 5 percent level in most spectral regions with the vicarious calibration technique relying on coincident ground-based measurements referred to as the reflectance-based approach. While the variability of the inter-calibration method based on non-coincident image pairs is significantly larger, results are consistent with techniques relying on in situ measurements. The method is also insensitive to spectral differences between the sensors by transferring to surface spectral reflectance prior to prediction of at-sensor radiance. The utility of this inter-calibration method is made clear by its flexibility to utilize image pairings with acquisition dates differing in excess of 30 days allowing frequent absolute calibration comparisons between wide- and narrow-swath sensors.

  9. Absolute calibration of optical power for PDT: report of AAPM TG140.

    PubMed

    Zhu, Timothy C; Bonnerup, Chris; Colussi, Valdir C; Dowell, Marla L; Finlay, Jarod C; Lilge, Lothar; Slowey, Thomas W; Sibata, Claudio

    2013-08-01

    This report is primarily concerned with methods for optical calibration of laser power for continuous wave (CW) light sources, predominantly used in photodynamic therapy (PDT). Light power calibration is very important for PDT, however, no clear standard has been established for the calibration procedure nor the requirements of power meters suitable for optical power calibration. The purposes of the report are to provide guidance for establishing calibration procedures for thermopile type power meters and establish calibration uncertainties for most commercially available detectors and readout assemblies. The authors have also provided a review of the use of various power meters for CW and pulsed optical sources, and provided recommended temporal frequencies for optical power meter calibrations and guidance for routine quality assurance procedure.

  10. Determining the importance of model calibration for forecasting absolute/relative changes in streamflow from LULC and climate changes

    USGS Publications Warehouse

    Niraula, Rewati; Meixner, Thomas; Norman, Laura M.

    2015-01-01

    Land use/land cover (LULC) and climate changes are important drivers of change in streamflow. Assessing the impact of LULC and climate changes on streamflow is typically done with a calibrated and validated watershed model. However, there is a debate on the degree of calibration required. The objective of this study was to quantify the variation in estimated relative and absolute changes in streamflow associated with LULC and climate changes with different calibration approaches. The Soil and Water Assessment Tool (SWAT) was applied in an uncalibrated (UC), single outlet calibrated (OC), and spatially-calibrated (SC) mode to compare the relative and absolute changes in streamflow at 14 gaging stations within the Santa Cruz River Watershed in southern Arizona, USA. For this purpose, the effect of 3 LULC, 3 precipitation (P), and 3 temperature (T) scenarios were tested individually. For the validation period, Percent Bias (PBIAS) values were >100% with the UC model for all gages, the values were between 0% and 100% with the OC model and within 20% with the SC model. Changes in streamflow predicted with the UC and OC models were compared with those of the SC model. This approach implicitly assumes that the SC model is “ideal”. Results indicated that the magnitude of both absolute and relative changes in streamflow due to LULC predicted with the UC and OC results were different than those of the SC model. The magnitude of absolute changes predicted with the UC and SC models due to climate change (both P and T) were also significantly different, but were not different for OC and SC models. Results clearly indicated that relative changes due to climate change predicted with the UC and OC were not significantly different than that predicted with the SC models. This result suggests that it is important to calibrate the model spatially to analyze the effect of LULC change but not as important for analyzing the relative change in streamflow due to climate change. This

  11. The absolute radiometric calibration of the Landsat 8 Operational Land Imager using the reflectance-based approach and the Radiometric Calibration Test Site (RadCaTS)

    NASA Astrophysics Data System (ADS)

    Czapla-Myers, Jeffrey; Anderson, Nikolaus; Thome, Kurtis; Biggar, Stuart

    2014-10-01

    Landsat 8 was launched on 11 February 2013 as the newest platform in the Landsat program. It contains two Earthobserving instruments, one of which is the Operational Land Imager (OLI). OLI includes an onboard radiometric calibration system that is used to monitor changes in its responsivity throughout the mission lifetime, and it consists of Spectralon solar diffuser panels as well as tungsten lamp assemblies. External techniques are used to monitor both OLI and its calibration system, and they include lunar views, side slither maneuvers of the satellite, and ground-based vicarious calibration. This work presents the absolute radiometric calibration results for Landsat 8 OLI that were obtained using two ground-based measurement techniques. The first is the reflectance-based approach, where measurements of atmospheric and surface properties are made during a Landsat 8 overpass, and it requires personnel to be on site during the time of measurement. The second uses the Radiometric Calibration Test Site (RadCaTS), which was developed by the Remote Sensing Group in the College of Optical Sciences at the University of Arizona so that radiometric calibration data can be collected without the requirement of on-site personnel. It allows more data to be collected annually, which increases the temporal sampling of trending results.

  12. The absolute amplitude calibration of the SEASAT synthetic aperture radar - An intercomparison with other L-band radar systems

    NASA Technical Reports Server (NTRS)

    Held, D.; Werner, C.; Wall, S.

    1983-01-01

    The absolute amplitude calibration of the spaceborne Seasat SAR data set is presented based on previous relative calibration studies. A scale factor making it possible to express the perceived radar brightness of a scene in units of sigma-zero is established. The system components are analyzed for error contribution, and the calibration techniques are introduced for each stage. These include: A/D converter saturation tests; prevention of clipping in the processing step; and converting the digital image into the units of received power. Experimental verification was performed by screening and processing the data of the lava flow surrounding the Pisgah Crater in Southern California, for which previous C-130 airborne scatterometer data were available. The average backscatter difference between the two data sets is estimated to be 2 dB in the brighter, and 4 dB in the dimmer regions. For the SAR a calculated uncertainty of 3 dB is expected.

  13. A new method for the absolute radiance calibration for UV/vis measurements of scattered sun light

    NASA Astrophysics Data System (ADS)

    Wagner, T.; Beirle, S.; Dörner, S.; Penning de Vries, M.; Remmers, J.; Rozanov, A.; Shaiganfar, R.

    2015-05-01

    Absolute radiometric calibrations are important for measurements of the atmospheric spectral radiance. Such measurements can be used to determine actinic fluxes, the properties of aerosols and clouds and the short wave energy budget. Conventional calibration methods in the laboratory are based on calibrated light sources and reflectors and are expensive, time consuming and subject to relatively large uncertainties. Also, the calibrated instruments might change during transport from the laboratory to the measurement sites. Here we present a new calibration method for UV/vis instruments that measure the spectrally resolved sky radiance, like for example zenith sky Differential Optical Absorption Spectroscopy (DOAS-) instruments or Multi-AXis (MAX-) DOAS instruments. Our method is based on the comparison of the solar zenith angle dependence of the measured zenith sky radiance with radiative transfer simulations. For the application of our method clear sky measurements during periods with almost constant aerosol optical depth are needed. The radiative transfer simulations have to take polarisation into account. We show that the calibration results are almost independent from the knowledge of the aerosol optical properties and surface albedo, which causes a rather small uncertainty of about <7%. For wavelengths below about 330 nm it is essential that the ozone column density during the measurements is constant and known.

  14. Absolute calibration of photostimulable image plate detectors used as (0.5-20 MeV) high-energy proton detectors.

    PubMed

    Mancić, A; Fuchs, J; Antici, P; Gaillard, S A; Audebert, P

    2008-07-01

    In this paper, the absolute calibration of photostimulable image plates (IPs) used as proton detectors is presented. The calibration is performed in a wide range of proton energies (0.5-20 MeV) by exposing simultaneously the IP and calibrated detectors (radiochromic films and solid state detector CR39) to a source of broadband laser-accelerated protons, which are spectrally resolved. The final result is a calibration curve that enables retrieving the proton number from the IP signal. PMID:18681694

  15. Absolutely calibrated, time-resolved measurements of soft x rays using transmission grating spectrometers at the Nike Laser Facility

    NASA Astrophysics Data System (ADS)

    Weaver, J. L.; Feldman, U.; Seely, J. F.; Holland, G.; Serlin, V.; Klapisch, M.; Columbant, D.; Mostovych, A.

    2001-12-01

    Accurate simulation of pellet implosions for direct drive inertial confinement fusion requires benchmarking the codes with experimental data. The Naval Research Laboratory (NRL) has begun to measure the absolute intensity of radiation from laser irradiated targets to provide critical information for the radiatively preheated pellet designs developed by the Nike laser group. Two main diagnostics for this effort are two spectrometers incorporating three detection systems. While both spectrometers use 2500 lines/mm transmission gratings, one instrument is coupled to a soft x-ray streak camera and the other is coupled to both an absolutely calibrated Si photodiode array and a charge coupled device (CCD) camera. Absolute calibration of spectrometer components has been undertaken at the National Synchrotron Light Source at Brookhaven National Laboratories. Currently, the system has been used to measure the spatially integrated soft x-ray flux as a function of target material, laser power, and laser spot size. A comparison between measured and calculated flux for Au and CH targets shows reasonable agreement to one-dimensional modeling for two laser power densities.

  16. Comparison of absolute gain photometric calibration between Planck/HFI and Herschel/SPIRE at 545 and 857 GHz

    NASA Astrophysics Data System (ADS)

    Bertincourt, B.; Lagache, G.; Martin, P. G.; Schulz, B.; Conversi, L.; Dassas, K.; Maurin, L.; Abergel, A.; Beelen, A.; Bernard, J.-P.; Crill, B. P.; Dole, H.; Eales, S.; Gudmundsson, J. E.; Lellouch, E.; Moreno, R.; Perdereau, O.

    2016-04-01

    We compare the absolute gain photometric calibration of the Planck/HFI and Herschel/SPIRE instruments on diffuse emission. The absolute calibration of HFI and SPIRE each relies on planet flux measurements and comparison with theoretical far-infrared emission models of planetary atmospheres. We measure the photometric cross calibration between the instruments at two overlapping bands, 545 GHz/500 μm and 857 GHz/350 μm. The SPIRE maps used have been processed in the Herschel Interactive Processing Environment (Version 12) and the HFI data are from the 2015 Public Data Release 2. For our study we used 15 large fields observed with SPIRE, which cover a total of about 120 deg2. We have selected these fields carefully to provide high signal-to-noise ratio, avoid residual systematics in the SPIRE maps, and span a wide range of surface brightness. The HFI maps are bandpass-corrected to match the emission observed by the SPIRE bandpasses. The SPIRE maps are convolved to match the HFI beam and put on a common pixel grid. We measure the cross-calibration relative gain between the instruments using two methods in each field, pixel-to-pixel correlation and angular power spectrum measurements. The SPIRE/HFI relative gains are 1.047 (±0.0069) and 1.003 (±0.0080) at 545 and 857 GHz, respectively, indicating very good agreement between the instruments. These relative gains deviate from unity by much less than the uncertainty of the absolute extended emission calibration, which is about 6.4% and 9.5% for HFI and SPIRE, respectively, but the deviations are comparable to the values 1.4% and 5.5% for HFI and SPIRE if the uncertainty from models of the common calibrator can be discounted. Of the 5.5% uncertainty for SPIRE, 4% arises from the uncertainty of the effective beam solid angle, which impacts the adopted SPIRE point source to extended source unit conversion factor, highlighting that as a focus for refinement.

  17. Landsat-7 ETM+ On-Orbit Reflective-Band Radiometric Stability and Absolute Calibration

    NASA Technical Reports Server (NTRS)

    Markham, Brian L.; Thome, Kurtis J.; Barsi, Julia A.; Kaita, Ed; Helder, Dennis L.; Barker, John L.

    2003-01-01

    The Landsat-7 spacecraft carries the Enhanced Thematic Mapper Plus (ETM+) instrument. This instrument images the Earth land surface in eight parts of the electromagnetic spectrum, termed spectral bands. These spectral images are used to monitor changes in the land surface, so a consistent relationship, i.e., calibration, between the image data and the Earth surface brightness, is required. The ETM+ has several on- board calibration devices that are used to monitor this calibration. The best on-board calibration source employs a flat white painted reference panel and has indicated changes of between 0.5% to 2% per year in the ETM+ response, depending on the spectral band. However, most of these changes are believed to be caused by changes in the reference panel, as opposed to changes in the instrument's sensitivity. This belief is based partially on on-orbit calibrations using instrumented ground sites and observations of "invariant sites", hyper-arid sites of the Sahara and Arabia. Changes determined from these data sets indicate are 0.1% - 0.6% per year. Tests and comparisons to other sensors also indicate that the uncertainty of the calibration is at the 5% level.

  18. Absolute calibration of OH density in a nanosecond pulsed plasma filament in atmospheric pressure He-H2O: comparison of independent calibration methods

    NASA Astrophysics Data System (ADS)

    Verreycken, T.; van der Horst, R. M.; Sadeghi, N.; Bruggeman, P. J.

    2013-11-01

    The absolute density of OH radicals generated in a nanosecond pulsed filamentary discharge in atmospheric pressure He +0.84% H2O is measured independently by UV absorption and laser induced fluorescence (LIF) calibrated with Rayleigh scattering. For the calibration of LIF with Rayleigh scattering, two LIF models, with six levels and four levels, are studied to investigate the influence of the rotational and vibrational energy transfers. In addition, a chemical model is used to deduce the OH density in the afterglow from the relative LIF intensity as function of time. The different models show good correspondence and by comparing these different methods, the accuracy and the effect of assumptions on the obtained OH density are discussed in detail. This analysis includes an analysis of the sensitivity to parameters used in the LIF models.

  19. The absolute radiometric calibration of the advanced very high resolution radiometer

    NASA Technical Reports Server (NTRS)

    Slater, P. N.; Teillet, P. M.; Ding, Y.

    1989-01-01

    The measurement conditions are described for an intensive field campaign at White Sands Missile Range for the calibration of the AVHRRs on NOAA-9, NOAA-10 and NOAA-11, LANDSAT-4 TM and SPOT. Three different methods for calibration of AVHRRs by reference to a ground surface site are reported, and results from these methods are compared. Significant degradations in NOAA-9 and NOAA-10 AVHRR responsivities occurred since prelaunch calibrations were completed. As of February 1988, degradations in NOAA-9 AVHRR responsivities were on the order of 37 percent in channel and 41 percent in channel 2, and for the NOAA-10 AVHRR these degradations were 42 and 59 percent in channels 1 and 2, respectively.

  20. Absolute calibration of the Gamma Knife{sup ®} Perfexion™ and delivered dose verification using EPR/alanine dosimetry

    SciTech Connect

    Hornbeck, Amaury E-mail: tristan.garcia@cea.fr; Garcia, Tristan E-mail: tristan.garcia@cea.fr; Cuttat, Marguerite; Jenny, Catherine

    2014-06-15

    Purpose: Elekta Leksell Gamma Knife{sup ®} (LGK) is a radiotherapy beam machine whose features are not compliant with the international calibration protocols for radiotherapy. In this scope, the Laboratoire National Henri Becquerel and the Pitié-Salpêtrière Hospital decided to conceive a new LKG dose calibration method and to compare it with the currently used one. Furthermore, the accuracy of the dose delivered by the LGK machine was checked using an “end-to-end” test. This study also aims to compare doses delivered by the two latest software versions of the Gammaplan treatment planning system (TPS). Methods: The dosimetric method chosen is the electron paramagnetic resonance (EPR) of alanine. Dose rate (calibration) verification was done without TPS using a spherical phantom. Absolute calibration was done with factors calculated by Monte Carlo simulation (MCNP-X). For “end-to-end” test, irradiations in an anthropomorphic head phantom, close to real treatment conditions, are done using the TPS in order to verify the delivered dose. Results: The comparison of the currently used calibration method with the new one revealed a deviation of +0.8% between the dose rates measured by ion chamber and EPR/alanine. For simple fields configuration (less than 16 mm diameter), the “end-to-end” tests showed out average deviations of −1.7% and −0.9% between the measured dose and the calculated dose by Gammaplan v9 and v10, respectively. Conclusions: This paper shows there is a good agreement between the new calibration method and the currently used one. There is also a good agreement between the calculated and delivered doses especially for Gammaplan v10.

  1. Sustained prediction ability of net analyte preprocessing methods using reduced calibration sets. Theoretical and experimental study involving the spectrophotometric analysis of multicomponent mixtures.

    PubMed

    Goicoechea, H C; Olivieri, A C

    2001-07-01

    A newly developed multivariate method involving net analyte preprocessing (NAP) was tested using central composite calibration designs of progressively decreasing size regarding the multivariate simultaneous spectrophotometric determination of three active components (phenylephrine, diphenhydramine and naphazoline) and one excipient (methylparaben) in nasal solutions. Its performance was evaluated and compared with that of partial least-squares (PLS-1). Minimisation of the calibration predicted error sum of squares (PRESS) as a function of a moving spectral window helped to select appropriate working spectral ranges for both methods. The comparison of NAP and PLS results was carried out using two tests: (1) the elliptical joint confidence region for the slope and intercept of a predicted versus actual concentrations plot for a large validation set of samples and (2) the D-optimality criterion concerning the information content of the calibration data matrix. Extensive simulations and experimental validation showed that, unlike PLS, the NAP method is able to furnish highly satisfactory results when the calibration set is reduced from a full four-component central composite to a fractional central composite, as expected from the modelling requirements of net analyte based methods.

  2. Calibration of a Solar Absolute Cavity Radiometer with Traceability to the World Radiometric Reference

    SciTech Connect

    Reda, I.

    1996-01-01

    This report describes the present method of establishing traceability of absolute cavity radiometers to the World Radiometric Reference (WRR) through the process employed in the International Pyrheliometer Comparisons (IPC). This method derives the WRR reduction factor for each of the participating cavity radiometers. An alternative method is proposed, described, and evaluated as a way to reduce the uncertainty in the comparison process. The two methods are compared using a sample of data from the recent IPC-VIII conducted from September 25th to October 13th, 1995 at the World Radiation Center in Davos, Switzerland. A description of absolute cavity radiometers is also included, using a PMO-6 as an example of active cavity radiometers, and a HF as an example of passive cavity radiometers.

  3. Absolute gauge block calibration using ultra-precise optical frequency synthesizer locked to a femtosecond comb.

    PubMed

    Hussein, Hatem; Farid, Niveen; Terra, Osama

    2015-02-01

    In this paper, we report a gauge block (GB) calibration that is traceable to the SI unit of time, the second. Four ultra-stable optical telecommunication wavelengths near 1556 nm are obtained by locking a narrow-tuning-range fiber laser to a fiber-based femtosecond frequency comb. Since the GB calibration system does not operate at this region of spectrum, the superior frequency stability of the laser is transferred to the 778 nm region by using a waveguide periodically poled lithium niobate crystal. After applying the locking scheme, the stability and accuracy of the laser become better than 8×10(-12). The frequency-doubled light is sent through 30 m optical fiber to a GB interferometer, which is installed at a different laboratory in the same building. Using this calibration scheme, a GB with a nominal length of 100 mm is calibrated with an uncertainty of ±52  nm. This uncertainty value is still comparable to or even better than other metrology laboratories for a similar block length.

  4. The Importance of Post-Launch, On-Orbit Absolute Radiometric Calibration for Remote Sensing Applications

    NASA Astrophysics Data System (ADS)

    Kuester, M. A.

    2015-12-01

    Remote sensing is a powerful tool for monitoring changes on the surface of the Earth at a local or global scale. The use of data sets from different sensors across many platforms, or even a single sensor over time, can bring a wealth of information when exploring anthropogenic changes to the environment. For example, variations in crop yield and health for a specific region can be detected by observing changes in the spectral signature of the particular species under study. However, changes in the atmosphere, sun illumination and viewing geometries during image capture can result in inconsistent image data, hindering automated information extraction. Additionally, an incorrect spectral radiometric calibration will lead to false or misleading results. It is therefore critical that the data being used are normalized and calibrated on a regular basis to ensure that physically derived variables are as close to truth as is possible. Although most earth observing sensors are well-calibrated in a laboratory prior to launch, a change in the radiometric response of the system is inevitable due to thermal, mechanical or electrical effects caused during the rigors of launch or by the space environment itself. Outgassing and exposure to ultra-violet radiation will also have an effect on the sensor's filter responses. Pre-launch lamps and other laboratory calibration systems can also fall short in representing the actual output of the Sun. A presentation of the differences in the results of some example cases (e.g. geology, agriculture) derived for science variables using pre- and post-launch calibration will be presented using DigitalGlobe's WorldView-3 super spectral sensor, with bands in the visible and near infrared, as well as in the shortwave infrared. Important defects caused by an incomplete (i.e. pre-launch only) calibration will be discussed using validation data where available. In addition, the benefits of using a well-validated surface reflectance product will be

  5. Absolute calibration method for fast-streaked, fiber optic light collection, spectroscopy systems.

    SciTech Connect

    Johnston, Mark D.; Frogget, Brent; Oliver, Bryan Velten; Maron, Yitzhak; Droemer, Darryl W.; Crain, Marlon D.

    2010-04-01

    This report outlines a convenient method to calibrate fast (<1ns resolution) streaked, fiber optic light collection, spectroscopy systems. Such a system is used to collect spectral data on plasmas generated in the A-K gap of electron beam diodes fielded on the RITS-6 accelerator (8-12MV, 140-200kA). On RITS, light is collected through a small diameter (200 micron) optical fiber and recorded on a fast streak camera at the output of 1 meter Czerny-Turner monochromator (F/7 optics). To calibrate such a system, it is necessary to efficiently couple light from a spectral lamp into a 200 micron diameter fiber, split it into its spectral components, with 10 Angstroms or less resolution, and record it on a streak camera with 1ns or less temporal resolution.

  6. Absolute energy calibration of FD by an electron linear accelerator for Telescope Array

    SciTech Connect

    Shibata, T.; Fukushima, M.; Ikeda, D.; Enomoto, A.; Fukuda, S.; Furukawa, K.; Ikeda, M.; Iwase, H.; Kakihara, K.; Kamitani, T.; Kondo, Y.; Ohsawa, S.; Sagawa, H.; Sanami, T.; Satoh, M.; Shidara, T.; Sugimura, T.; Yoshida, M.; Matthews, J. N.; Ogio, S.

    2011-09-22

    The primary energy of the ultra-high energy cosmic rays(UHECR) are measured with the number of fluorescence photons which are detected with fluorescence detectors(FD) in the Telescope Array experiment(TA). Howevery since there is large uncertinty as 19% in the measurement of the energy scale, the most important theme is improvement of the energy calibration. The electron light source(ELS) is a small electron linear accelerator for new energy calibration. The ELS is located 100 m far from the FD station, and injects electron beam which is accelerated to 40 MeV energy into the sky. We can calibrate the FD energy scale by detection the air shower directly which is generated by the electron beam. The ELS was developed in KEK Japan, and moved to the TA site in March 2009. We started the beam operation in September 2010, in consequence we detected the air shower which was generated by electron beam in the air. The output kinetic energy of the electron beam was 41.1 MeV, we adjusted the output charge from 40 to 140 pC/pulse. We expect that we can improve the uncertinty of the energy scale to about 10% with the ELS, futhermore ELS will be a very useful apparatus for R and D of future UHECR observation.

  7. First preliminary results for the absolute calibration of the Chinese HY-2 altimetric mission using the CRS1 calibration facilities in West Crete, Greece

    NASA Astrophysics Data System (ADS)

    Mertikas, Stelios P.; Zhou, Xinghua; Qiao, Fangli; Daskalakis, Antonis; Lin, Mingsen; Peng, Hailong; Tziavos, Ilias N.; Vergos, George; Tripolitsiotis, Achilleas; Frantzis, Xenophon

    2016-01-01

    In this work, absolute calibration of the Chinese HY-2 satellite altimetry mission is carried out, employing Pass No. 280 and the calibration facility, CRS1, located in the Southwest end of the island of Crete, Greece. Satellite Pass No. 280 is descending and follows a ground track almost parallel to the west coast of Crete. It comes close to the coast, at a distance of about 9 km from the CRS1 calibration site, and finally goes away south of Crete. The HY-2 sensor geophysical data records (S-GDR) have been incorporated into the calibration procedures and processing has taken place for cycles No. 54-62, at 20 Hz data rate. Some peculiarities in the HY-2 satellite altimeter data, as delivered and depicted in the I-GDR and S-GDR data, have also been noticed. All calibration results have been determined using a regional, precise and detailed geoid, along with a good knowledge of local ocean circulation and site characteristics and a well-defined sea-surface calibration methodology. The first preliminary results for the HY-2 altimeter calibration have shown that the initial cycles, up to No. 51, display an erratic behavior. After those cycles, the altimeter range bias values seem to be stable and reach a value of B = -45.6 cm ± 4.4 cm, when applying the net instrument corrections as provided in the GDR. If the relativistic effects of the satellite clocks are properly applied for the net instrument corrections, then the altimeter range bias goes down to B = -27 cm ± 3 cm. Also, preliminary cross-over analysis with the SARAL/AliKa and Jason-2 satellites show a bias of B = -23 cm, and B = -28.5 cm, respectively. The performance of the HY-2 on-board radiometer has also been examined in terms of the wet troposphere corrections and shows a mean difference of -1 cm ± 0.1 cm with respect to in-situ GNSS-derived corrections. Finally, the ionosphere path corrections of the HY-2 satellite show a difference of +1 cm ± 1.1 cm, when compared against the GNSS-derived ionosphere

  8. Absolutely calibrated CCD images of Saturn at methane band and continuum wavelengths during its 1991 opposition

    NASA Astrophysics Data System (ADS)

    Ortiz, J. L.; Moreno, F.; Molina, A.

    1993-02-01

    Ground-based charge-coupled device images of Saturn were obtained at the Cassegrain focus of the 1.52-m telescope at the Calar Alto Observatory (Andalucia, Spain) during the 1991 opposition. The images were obtained in and out of the absorption methane bands at 6190, 7250, and 8900A under very good seeing conditions. A Bayesian deconvolution technique was employed in the restoration procedure. The derived absolute reflectivities and band depths at some locations of the disk are provided in tables appropriate for analysis in terms of scattering models. Possible temporal variations between the reflectivities found here and those reported by West et al. (1982) are discussed. No longitudinal variations in reflectivity larger than a 4 percent level were found. Some images showed bright spot activity at the equatorial region.

  9. Validation of short-pulse-laser-based measurement setup for absolute spectral irradiance responsivity calibration.

    PubMed

    Schuster, Michaela; Nevas, Saulius; Sperling, Armin

    2014-05-01

    This paper describes the validation process of mode-locked lasers in the "tunable lasers in photometry" (TULIP) setup at Physikalisch-Technische Bundesanstalt (PTB) regarding spectral irradiance responsivity calibrations. Validation has been carried out in the visible spectral range, 400-700 nm, with two different photometer heads and in the long wavelength range, 690-780 nm, with a filtered radiometer. A comparison of the results against those from two different validated measurement setups has been carried out for validation. For the visible spectral range, the comparison is conducted against the data obtained from a lamp-based monochromator setup for spectral irradiance responsivity calibrations and against the photometric values (integral quantity) measured at the photometric bench setup of PTB. For the long wavelength range, comparisons against results from two different lamp-based monochromator measurement setups were made. Additionally, the effect of different radiation bandwidths on interference oscillations has been determined for a filter radiometer without a diffuser. A procedure for the determination of the optimum bandwidth of the setup for the respective measurement device is presented. PMID:24921865

  10. Improvement in absolute calibration accuracy of Landsat-5 TM with Landsat-7 ETM+ data

    NASA Astrophysics Data System (ADS)

    Chander, Gyanesh; Markham, Brian L.; Micijevic, Esad; Teillet, Philippe M.; Helder, Dennis L.

    2005-08-01

    The ability to detect and quantify changes in the Earth's environment depends on satellites sensors that can provide calibrated, consistent measurements of Earth's surface features through time. A critical step in this process is to put image data from subsequent generations of sensors onto a common radiometric scale. To evaluate Landsat-5 (L5) Thematic Mapper's (TM) utility in this role, image pairs from the L5 TM and Landsat-7 (L7) Enhanced Thematic Mapper Plus (ETM+) sensors were compared. This approach involves comparison of surface observations based on image statistics from large common areas observed eight days apart by the two sensors. The results indicate a significant improvement in the consistency of L5 TM data with respect to L7 ETM+ data, achieved using a revised Look-Up-Table (LUT) procedure as opposed to the historical Internal Calibrator (IC) procedure previously used in the L5 TM product generation system. The average percent difference in reflectance estimates obtained from the L5 TM agree with those from the L7 ETM+ in the Visible and Near Infrared (VNIR) bands to within four percent and in the Short Wave Infrared (SWIR) bands to within six percent.

  11. Improvement in absolute calibration accuracy of Landsat-5 TM with Landsat-7 ETM+ data

    USGS Publications Warehouse

    Chander, G.; Markham, B.L.; Micijevic, E.; Teillet, P.M.; Helder, D.L.; ,

    2005-01-01

    The ability to detect and quantify changes in the Earth's environment depends on satellites sensors that can provide calibrated, consistent measurements of Earth's surface features through time. A critical step in this process is to put image data from subsequent generations of sensors onto a common radiometric scale. To evaluate Landsat-5 (L5) Thematic Mapper's (TM) utility in this role, image pairs from the L5 TM and Landsat-7 (L7) Enhanced Thematic Mapper Plus (ETM+) sensors were compared. This approach involves comparison of surface observations based on image statistics from large common areas observed eight days apart by the two sensors. The results indicate a significant improvement in the consistency of L5 TM data with respect to L7 ETM+ data, achieved using a revised Look-Up-Table (LUT) procedure as opposed to the historical Internal Calibrator (IC) procedure previously used in the L5 TM product generation system. The average percent difference in reflectance estimates obtained from the L5 TM agree with those from the L7 ETM+ in the Visible and Near Infrared (VNIR) bands to within four percent and in the Short Wave Infrared (SWIR) bands to within six percent.

  12. SU-E-J-85: Leave-One-Out Perturbation (LOOP) Fitting Algorithm for Absolute Dose Film Calibration

    SciTech Connect

    Chu, A; Ahmad, M; Chen, Z; Nath, R

    2014-06-01

    Purpose: To introduce an outliers-recognition fitting routine for film dosimetry. It cannot only be flexible with any linear and non-linear regression but also can provide information for the minimal number of sampling points, critical sampling distributions and evaluating analytical functions for absolute film-dose calibration. Methods: The technique, leave-one-out (LOO) cross validation, is often used for statistical analyses on model performance. We used LOO analyses with perturbed bootstrap fitting called leave-one-out perturbation (LOOP) for film-dose calibration . Given a threshold, the LOO process detects unfit points (“outliers”) compared to other cohorts, and a bootstrap fitting process follows to seek any possibilities of using perturbations for further improvement. After that outliers were reconfirmed by a traditional t-test statistics and eliminated, then another LOOP feedback resulted in the final. An over-sampled film-dose- calibration dataset was collected as a reference (dose range: 0-800cGy), and various simulated conditions for outliers and sampling distributions were derived from the reference. Comparisons over the various conditions were made, and the performance of fitting functions, polynomial and rational functions, were evaluated. Results: (1) LOOP can prove its sensitive outlier-recognition by its statistical correlation to an exceptional better goodness-of-fit as outliers being left-out. (2) With sufficient statistical information, the LOOP can correct outliers under some low-sampling conditions that other “robust fits”, e.g. Least Absolute Residuals, cannot. (3) Complete cross-validated analyses of LOOP indicate that the function of rational type demonstrates a much superior performance compared to the polynomial. Even with 5 data points including one outlier, using LOOP with rational function can restore more than a 95% value back to its reference values, while the polynomial fitting completely failed under the same conditions

  13. Improved entrance optics design for ground-based solar spectral ultraviolet irradiance measurements and system absolute calibration

    NASA Astrophysics Data System (ADS)

    Dai, Caihong; Yu, Jialin; Huang, Bo; Tian, Yan

    2009-07-01

    The angular response of entrance optics is an important parameter for solar spectral UV measurements, and ideal cosine entrance optics is required to measure ground-based global solar spectral UV irradiance including direct and diffuse radiation over a solid angle of 2π sr. Early international comparisons have shown that deviations from the ideal cosine response lead to uncertainties in solar measurements of more than 10%. A special spectroradiometer used for solar spectral UV measurements was developed at National Institute of Metrology (NIM). Based on Polytetrafluoroethylene (PTFE) integrating sphere, seven kinds of cosine-entrance system were designed and compared. A special cosine measurement apparatus was developed to measure the angular response of the entrance optics. Experimental results show that, the integral cosine error is 1.41% for a novel combination entrance optics, which is composed by a PTFE integrating sphere, a spherical ground quartz diffuser and a special correction ring, and the cosine error is 0.08% for an incidence angle of θ=+/-30°, 0.84% at θ=+/-45°, -0.47% at θ=+/-60°, -0.74% at θ=+/-70°, and 5.47% at θ=+/-80°. With the new non-plane entrance optics, the angular response of the solar UV spectroradiometer is improved evidently, but on the other side, the system's absolute calibration becomes more difficult owing to the curved geometry of the new diffuser. The calibration source is a 1000W tungsten halogen lamp, but the measurement object is the global radiation of the solar, so a small error of the calibration distance will lead to an enormous measurement error of solar spectral UV irradiance. When the calibration distance is 500mm, for an actual diffuser with spherical radius 32.5mm and spherical height 20mm, the calibration error will be up to 3%~10% on the assumption that the starting point was calculated just from the acme or the bottom of the half-spherical diffuser. It was investigated that which point inside the

  14. Calibration and absolute normalization procedure of a new Deep Inelastic Neutron Scattering spectrometer

    NASA Astrophysics Data System (ADS)

    Rodríguez Palomino, L. A.; Blostein, J. J.; Dawidowski, J.

    2011-08-01

    We describe the calibration process of a new Deep Inelastic Neutron Scattering (DINS) spectrometer, recently implemented at the Bariloche Electron LINAC (Argentina), consisting in the determination of the incident neutron spectrum, dead-time and electronic delay of the data acquisition line, and detector bank efficiency. For this purpose, samples of lead, polyethylene and graphite of different sizes were employed. Their measured spectra were corrected by multiple scattering, attenuation and detector efficiency effects, by means of an ad hoc Monte Carlo code. We show that the corrected spectra are correctly scaled with respect to the scattering power of the tested materials within a 2% of experimental error, thus allowing us to define an experimental constant that links the arbitrary experimental scale (number of recorded counts per monitor counts) with the involved cross-sections. The present work also serves to analyze the existence of possible sources of systematic errors.

  15. New method to remove the electronic noise for absolutely calibrating low gain photomultiplier tubes with a higher precision

    NASA Astrophysics Data System (ADS)

    Zhang, Xiaodong; Hayward, Jason P.; Laubach, Mitchell A.

    2014-08-01

    A new method to remove the electronic noise in order to absolutely calibrate low gain photomultiplier tubes with a higher precision is proposed and validated with experiments using a digitizer-based data acquisition system. This method utilizes the fall time difference between the electronic noise (about 0.5 ns) and the real PMT signal (about 2.4 ns for Hamamatsu H10570 PMT assembly). Using this technique along with a convolution algorithm, the electronic noise and the real signals are separated very well, even including the very small signals heavily influenced by the electronic noise. One application that this method allows is for us to explore the energy relationship for gamma sensing in Cherenkov radiators while maintaining the fastest possible timing performance and high dynamic range.

  16. In-flight calibration of the experimental Absolute Scalar Magnetometer vector mode on board the Swarm satellites

    NASA Astrophysics Data System (ADS)

    Leger, J. M.; Jager, T.; Bertrand, F.; Cattin, V.; Fratter, I.; Brocco, L.; Vigneron, P.; Lalanne, X.; Hulot, G.

    2014-12-01

    While the role of the ASM is to provide absolute measurements of the magnetic field's strength for the in-flight calibration of the Vector Fluxgate Magnetometer, it can also deliver simultaneously vector measurements with no impact on its scalar performance. Since these scalar and vector measurements are both perfectly synchronous and spatially coherent, their comparison can be directly used to assess the ASM performances at instrument level with no need to correct for the various magnetic perturbations generated by the satellites. This presentation will detail the ASM vector calibration process, with an emphasis on its susceptibility to the ASM operational conditions (primarily the sensor temperature and attitude, but also sun exposition parameters). The evolution of the instrument's performances during the first year of the Swarm mission will then be discussed, with a particular interest in the long term scalar residuals behaviour. These results will be analyzed to demonstrate both the noise performances of the ASM scalar and vector measurements and their excellent long term stability.

  17. Determining the Absolute Concentration of Nanoparticles without Calibration Factor by Visualizing the Dynamic Processes of Interfacial Adsorption.

    PubMed

    Wo, Xiang; Li, Zhimin; Jiang, Yingyan; Li, Minghe; Su, Yu-Wen; Wang, Wei; Tao, Nongjian

    2016-02-16

    Previous approaches of determining the molar concentration of nanoparticles often relied on the calibration factors extracted from standard samples or required prior knowledge regarding the geometry, optical, or chemical properties. In the present work, we proposed an absolute quantification method that determined the molar concentration of nano-objects without any calibration factor or prior knowledge. It was realized by monitoring the dynamic adsorption processes of individual nanoparticles with a high-speed surface plasmon resonance microscopy. In this case, diffusing nano-objects stochastically collided onto an adsorption interface and stayed there ("hit-n-stay" scenario), resulting in a semi-infinite diffusion system. The dynamic processes were analyzed with a theoretical model consisting of Fick's laws of diffusion and random-walk assumption. The quantification of molar concentration was achieved on the basis of an analytical expression, which involved only physical constants and experimental parameters. By using spherical polystyrene nanoparticles as a model, the present approach provided a molar concentration with excellent accuracy. PMID:26781326

  18. A method for in situ absolute DD yield calibration of neutron time-of-flight detectors on OMEGA using CR-39-based proton detectors.

    PubMed

    Waugh, C J; Rosenberg, M J; Zylstra, A B; Frenje, J A; Séguin, F H; Petrasso, R D; Glebov, V Yu; Sangster, T C; Stoeckl, C

    2015-05-01

    Neutron time of flight (nTOF) detectors are used routinely to measure the absolute DD neutron yield at OMEGA. To check the DD yield calibration of these detectors, originally calibrated using indium activation systems, which in turn were cross-calibrated to NOVA nTOF detectors in the early 1990s, a direct in situ calibration method using CR-39 range filter proton detectors has been successfully developed. By measuring DD neutron and proton yields from a series of exploding pusher implosions at OMEGA, a yield calibration coefficient of 1.09 ± 0.02 (relative to the previous coefficient) was determined for the 3m nTOF detector. In addition, comparison of these and other shots indicates that significant reduction in charged particle flux anisotropies is achieved when bang time occurs significantly (on the order of 500 ps) after the trailing edge of the laser pulse. This is an important observation as the main source of the yield calibration error is due to particle anisotropies caused by field effects. The results indicate that the CR-39-nTOF in situ calibration method can serve as a valuable technique for calibrating and reducing the uncertainty in the DD absolute yield calibration of nTOF detector systems on OMEGA, the National Ignition Facility, and laser megajoule. PMID:26026524

  19. A method for in situ absolute DD yield calibration of neutron time-of-flight detectors on OMEGA using CR-39-based proton detectors

    SciTech Connect

    Waugh, C. J. Zylstra, A. B.; Frenje, J. A.; Séguin, F. H.; Petrasso, R. D.; Rosenberg, M. J.; Glebov, V. Yu.; Sangster, T. C.; Stoeckl, C.

    2015-05-15

    Neutron time of flight (nTOF) detectors are used routinely to measure the absolute DD neutron yield at OMEGA. To check the DD yield calibration of these detectors, originally calibrated using indium activation systems, which in turn were cross-calibrated to NOVA nTOF detectors in the early 1990s, a direct in situ calibration method using CR-39 range filter proton detectors has been successfully developed. By measuring DD neutron and proton yields from a series of exploding pusher implosions at OMEGA, a yield calibration coefficient of 1.09 ± 0.02 (relative to the previous coefficient) was determined for the 3m nTOF detector. In addition, comparison of these and other shots indicates that significant reduction in charged particle flux anisotropies is achieved when bang time occurs significantly (on the order of 500 ps) after the trailing edge of the laser pulse. This is an important observation as the main source of the yield calibration error is due to particle anisotropies caused by field effects. The results indicate that the CR-39-nTOF in situ calibration method can serve as a valuable technique for calibrating and reducing the uncertainty in the DD absolute yield calibration of nTOF detector systems on OMEGA, the National Ignition Facility, and laser megajoule.

  20. A method for in situ absolute DD yield calibration of neutron time-of-flight detectors on OMEGA using CR-39-based proton detectors

    DOE PAGES

    Waugh, C. J.; Rosenberg, M. J.; Zylstra, A. B.; Frenje, J. A.; Seguin, F. H.; Petrasso, R. D.; Glebov, V. Yu.; Sangster, T. C.; Stoeckl, C.

    2015-05-27

    Neutron time of flight (nTOF) detectors are used routinely to measure the absolute DD neutron yield at OMEGA. To check the DD yield calibration of these detectors, originally calibrated using indium activation systems, which in turn were cross-calibrated to NOVA nTOF detectors in the early 1990s, a direct in situ calibration method using CR-39 range filter proton detectors has been successfully developed. By measuring DD neutron and proton yields from a series of exploding pusher implosions at OMEGA, a yield calibration coefficient of 1.09 ± 0.02 (relative to the previous coefficient) was determined for the 3m nTOF detector. In addition,more » comparison of these and other shots indicates that significant reduction in charged particle flux anisotropies is achieved when bang time occurs significantly (on the order of 500 ps) after the trailing edge of the laser pulse. This is an important observation as the main source of the yield calibration error is due to particle anisotropies caused by field effects. The results indicate that the CR-39-nTOF in situ calibration method can serve as a valuable technique for calibrating and reducing the uncertainty in the DD absolute yield calibration of nTOF detector systems on OMEGA, the National Ignition Facility, and laser megajoule.« less

  1. A method for in situ absolute DD yield calibration of neutron time-of-flight detectors on OMEGA using CR-39-based proton detectors

    SciTech Connect

    Waugh, C. J.; Rosenberg, M. J.; Zylstra, A. B.; Frenje, J. A.; Seguin, F. H.; Petrasso, R. D.; Glebov, V. Yu.; Sangster, T. C.; Stoeckl, C.

    2015-05-27

    Neutron time of flight (nTOF) detectors are used routinely to measure the absolute DD neutron yield at OMEGA. To check the DD yield calibration of these detectors, originally calibrated using indium activation systems, which in turn were cross-calibrated to NOVA nTOF detectors in the early 1990s, a direct in situ calibration method using CR-39 range filter proton detectors has been successfully developed. By measuring DD neutron and proton yields from a series of exploding pusher implosions at OMEGA, a yield calibration coefficient of 1.09 ± 0.02 (relative to the previous coefficient) was determined for the 3m nTOF detector. In addition, comparison of these and other shots indicates that significant reduction in charged particle flux anisotropies is achieved when bang time occurs significantly (on the order of 500 ps) after the trailing edge of the laser pulse. This is an important observation as the main source of the yield calibration error is due to particle anisotropies caused by field effects. The results indicate that the CR-39-nTOF in situ calibration method can serve as a valuable technique for calibrating and reducing the uncertainty in the DD absolute yield calibration of nTOF detector systems on OMEGA, the National Ignition Facility, and laser megajoule.

  2. Absolute sensitivity calibration of vacuum and extreme ultraviolet spectrometer systems and Z{sub eff} measurement based on bremsstrahlung continuum in HL-2A tokamak

    SciTech Connect

    Zhou Hangyu; Cui Zhengying; Fu Bingzhong; Sun Ping; Gao Yadong; Xu Yuan; Lu Ping; Yang Qingwei; Duan Xuru; Morita, Shigeru; Goto, Motoshi; Dong Chunfeng

    2012-10-15

    A grazing-incidence flat-field extreme ultraviolet (EUV) spectrometer has been newly developed in HL-2A tokamak. Typical spectral lines are observed from intrinsic impurities of carbon, oxygen, iron, and extrinsic impurity of helium in the wavelength range of 20 A-500 A. Bremsstrahlung continuum is measured at different electron densities of HL-2A discharges to calibrate absolute sensitivity of the EUV spectrometer system and to measure effective ionic charge, Z{sub eff}. The sensitivity of a vacuum ultraviolet (VUV) spectrometer system is also absolutely calibrated in overlapped wavelength range of 300 A-500 A by comparing the intensity between VUV and EUV line emissions.

  3. High-resolution imaging spectrometer for recording absolutely calibrated far ultraviolet spectra from laser-produced plasmas

    SciTech Connect

    Brown, Charles M.; Seely, John F.; Feldman, Uri; Holland, Glenn E.; Weaver, James L.; Obenschain, Steven P.; Kjornrattanawanich, Benjawan; Fielding, Drew

    2008-10-15

    An imaging spectrometer was designed and fabricated for recording far ultraviolet spectra from laser-produced plasmas with wavelengths as short as 155 nm. The spectrometer implements a Cassegrain telescope and two gratings in a tandem Wadsworth optical configuration that provides diffraction limited resolution. Spectral images were recorded from plasmas produced by the irradiation of various target materials by intense KrF laser radiation with 248 nm wavelength. Two pairs of high-resolution gratings can be selected for the coverage of two wavebands, one grating pair with 1800 grooves/mm and covering approximately 155-175 nm and another grating pair with 1200 grooves/mm covering 230-260 nm. The latter waveband includes the 248 nm KrF laser wavelength, and the former waveband includes the wavelength of the two-plasmon decay instability at (2/3) the KrF laser wavelength (165 nm). The detection media consist of a complementary metal oxide semiconductor imager, photostimulable phosphor image plates, and a linear array of 1 mm{sup 2} square silicon photodiodes with 0.4 ns rise time. The telescope mirrors, spectrometer gratings, and 1 mm{sup 2} photodiode were calibrated using synchrotron radiation, and this enables the measurement of the absolute emission from the laser-produced plasmas with temporal, spatial, and spectral resolutions. The spectrometer is capable of measuring absolute spectral emissions at 165 nm wavelength as small as 5x10{sup -7} J/nm from a plasma source area of 0.37 mm{sup 2} and with 0.4 ns time resolution.

  4. High-resolution imaging spectrometer for recording absolutely calibrated far ultraviolet spectra from laser-produced plasmas.

    PubMed

    Brown, Charles M; Seely, John F; Feldman, Uri; Holland, Glenn E; Weaver, James L; Obenschain, Steven P; Kjornrattanawanich, Benjawan; Fielding, Drew

    2008-10-01

    An imaging spectrometer was designed and fabricated for recording far ultraviolet spectra from laser-produced plasmas with wavelengths as short as 155 nm. The spectrometer implements a Cassegrain telescope and two gratings in a tandem Wadsworth optical configuration that provides diffraction limited resolution. Spectral images were recorded from plasmas produced by the irradiation of various target materials by intense KrF laser radiation with 248 nm wavelength. Two pairs of high-resolution gratings can be selected for the coverage of two wavebands, one grating pair with 1800 grooves/mm and covering approximately 155-175 nm and another grating pair with 1200 grooves/mm covering 230-260 nm. The latter waveband includes the 248 nm KrF laser wavelength, and the former waveband includes the wavelength of the two-plasmon decay instability at 23 the KrF laser wavelength (165 nm). The detection media consist of a complementary metal oxide semiconductor imager, photostimulable phosphor image plates, and a linear array of 1 mm(2) square silicon photodiodes with 0.4 ns rise time. The telescope mirrors, spectrometer gratings, and 1 mm(2) photodiode were calibrated using synchrotron radiation, and this enables the measurement of the absolute emission from the laser-produced plasmas with temporal, spatial, and spectral resolutions. The spectrometer is capable of measuring absolute spectral emissions at 165 nm wavelength as small as 5x10(-7) J/nm from a plasma source area of 0.37 mm(2) and with 0.4 ns time resolution.

  5. (18)F primary standard at ENEA-INMRI by three absolute techniques and calibration of a well-type IG11 ionization chamber.

    PubMed

    Capogni, Marco; Carconi, Pierluigi; De Felice, Pierino; Fazio, Aldo

    2016-03-01

    A new (18)F primary standardization carried out at ENEA-INMRI by three different absolute techniques, i.e. 4πγNaI(Tl)γ high-efficiency counting, TDCR and 4πβ(LS)-γ[NaI(Tl)] coincidence counting method, allowed the calibration of a fixed well-reentrant IG11 ionization chamber (IC), with an uncertainty lower than 1%, and to check the calibration factor of a portable well-type IC NPL-CRC model, previously calibrated. By the new standard the ENEA-INMRI was linked to the BIPM International Reference System (SIR) through the BIPM SIR Transfer Instrument (SIRTI).

  6. (18)F primary standard at ENEA-INMRI by three absolute techniques and calibration of a well-type IG11 ionization chamber.

    PubMed

    Capogni, Marco; Carconi, Pierluigi; De Felice, Pierino; Fazio, Aldo

    2016-03-01

    A new (18)F primary standardization carried out at ENEA-INMRI by three different absolute techniques, i.e. 4πγNaI(Tl)γ high-efficiency counting, TDCR and 4πβ(LS)-γ[NaI(Tl)] coincidence counting method, allowed the calibration of a fixed well-reentrant IG11 ionization chamber (IC), with an uncertainty lower than 1%, and to check the calibration factor of a portable well-type IC NPL-CRC model, previously calibrated. By the new standard the ENEA-INMRI was linked to the BIPM International Reference System (SIR) through the BIPM SIR Transfer Instrument (SIRTI). PMID:26774395

  7. Continuous absolute g monitoring of the mobile LNE-SYRTE Cold Atom Gravimeter - a new tool to calibrate superconducting gravimeters -

    NASA Astrophysics Data System (ADS)

    Merlet, Sébastien; Gillot, Pierre; Cheng, Bing; Pereira Dos Santos, Franck

    2016-04-01

    Atom interferometry allows for the realization of a new generation of instruments for inertial sensing based on laser cooled atoms. We have developed an absolute gravimeter (CAG) based on this technic, which can perform continuous gravity measurements at a high cycling rate. This instrument, operating since summer 2009, is the new metrological french standard for gravimetry. The CAG has been designed to be movable, so as to participate to international comparisons and on field measurements. It took part to several comparisons since ICAG'09 and operated in both urban environments and low noise underground facilities. The atom gravimeter operates with a high cycling rate of 3 Hz. Its sensitivity is predominantly limited by ground vibration noise which is rejected thanks to isolation platforms and correlation with other sensors, such as broadband accelerometers or sismometers. These developments allow us to perform continuous gravity measurements, no matter what the sismic conditions are and even in the worst cases such as during earthquakes. At best, a sensitivity of 5.6 μGal at 1 s measurement time has been demonstrated. The long term stability averages down to 0.1 μGal for long term measurements. Presently, the measurement accuracy is 4 μGal, which we plan to reduce to 1 μGal or below. I will present the instrument, the principle of the gravity acceleration measurement and its performances. I will focus on continuous gravity measurements performed over several years and compared with our superconducting gravimeter iGrav signal. This comparison allows us to calibrate the iGrav scale factor and follow its evolution. Especially, we demonstrate that, thanks to the CAG very high cycling rate, a single day gravity measurement allows to calibrate the iGrav scaling factor with a relative uncertainty as good as 4.10-4.

  8. Progress in obtaining an absolute calibration of a total deuterium-tritium neutron yield diagnostic based on copper activationa)

    NASA Astrophysics Data System (ADS)

    Ruiz, C. L.; Chandler, G. A.; Cooper, G. W.; Fehl, D. L.; Hahn, K. D.; Leeper, R. J.; McWatters, B. R.; Nelson, A. J.; Smelser, R. M.; Snow, C. S.; Torres, J. A.

    2012-10-01

    The 350-keV Cockroft-Walton accelerator at Sandia National laboratory's Ion Beam facility is being used to calibrate absolutely a total DT neutron yield diagnostic based on the 63Cu(n,2n)62Cu(β+) reaction. These investigations have led to first-order uncertainties approaching 5% or better. The experiments employ the associated-particle technique. Deuterons at 175 keV impinge a 2.6 μm thick erbium tritide target producing 14.1 MeV neutrons from the T(d,n)4He reaction. The alpha particles emitted are measured at two angles relative to the beam direction and used to infer the neutron flux on a copper sample. The induced 62Cu activity is then measured and related to the neutron flux. This method is known as the F-factor technique. Description of the associated-particle method, copper sample geometries employed, and the present estimates of the uncertainties to the F-factor obtained are given.

  9. DAQ Software Contributions, Absolute Scale Energy Calibration and Background Evaluation for the NOvA Experiment at Fermilab

    SciTech Connect

    Flumerfelt, Eric Lewis

    2015-08-01

    The NOvA (NuMI Off-axis ve [nu_e] Appearance) Experiment is a long-baseline accelerator neutrino experiment currently in its second year of operations. NOvA uses the Neutrinos from the Main Injector (NuMI) beam at Fermilab, and there are two main off-axis detectors: a Near Detector at Fermilab and a Far Detector 810 km away at Ash River, MN. The work reported herein is in support of the NOvA Experiment, through contributions to the development of data acquisition software, providing an accurate, absolute-scale energy calibration for electromagnetic showers in NOvA detector elements, crucial to the primary electron neutrino search, and through an initial evaluation of the cosmic background rate in the NOvA Far Detector, which is situated on the surface without significant overburden. Additional support work for the NOvA Experiment is also detailed, including DAQ Server Administration duties and a study of NOvA’s sensitivity to neutrino oscillations into a “sterile” state.

  10. Absolutely calibrated radio polarimetry of the inner Galaxy at 2.3 and 4.8 GHz

    NASA Astrophysics Data System (ADS)

    Sun, X. H.; Gaensler, B. M.; Carretti, E.; Purcell, C. R.; Staveley-Smith, L.; Bernardi, G.; Haverkorn, M.

    2014-01-01

    We present high-sensitivity and absolutely calibrated images of diffuse radio polarization at a resolution of about 10 arcmin covering the range 10° < l < 34° and |b| < 5° at 2.3 GHz from the S-band Polarization All Sky Survey and at 4.8 GHz from the Sino-German λ6 cm polarization survey of the Galactic plane. Strong depolarization near the Galactic plane is seen at 2.3 GHz, which correlates with strong Hα emission. We ascribe the depolarization to spatial Faraday rotation measure fluctuations of about 65 rad m-2 on scales smaller than 6-9 pc. We argue that most (about 90 per cent) of the polarized emission seen at 4.8 GHz originates from a distance of 3-4 kpc in the Scutum arm and that the random magnetic field dominates the regular field there. A branch extending from the North Polar Spur towards lower latitudes can be identified from the polarization image at 4.8 GHz but only partly from the polarization image at 2.3 GHz, implying that the branch is at a distance larger than 2-3 kpc. We show that comparison of structure functions of complex polarized intensity with those of polarized intensity can indicate whether the observed polarized structures are intrinsic or caused by Faraday screens. The probability distribution function of gradients from the polarization images at 2.3 GHz indicates that the turbulence in the warm ionized medium is transonic.

  11. Determination of tartrazine in beverage samples by stopped-flow analysis and three-way multivariate calibration of non-linear kinetic-spectrophotometric data.

    PubMed

    Schenone, Agustina V; Culzoni, María J; Marsili, Nilda R; Goicoechea, Héctor C

    2013-06-01

    The performance of MCR-ALS was studied in the modeling of non-linear kinetic-spectrophotometric data acquired by a stopped-flow system for the quantitation of tartrazine in the presence of brilliant blue and sunset yellow FCF as possible interferents. In the present work, MCR-ALS and U-PCA/RBL were firstly applied to remove the contribution of unexpected components not included in the calibration set. Secondly, a polynomial function was used to model the non-linear data obtained by the implementation of the algorithms. MCR-ALS was the only strategy that allowed the determination of tartrazine in test samples accurately. Therefore, it was applied for the analysis of tartrazine in beverage samples with minimum sample preparation and short analysis time. The proposed method was validated by comparison with a chromatographic procedure published in the literature. Mean recovery values between 98% and 100% and relative errors of prediction values between 4% and 9% were indicative of the good performance of the method.

  12. Comparative study for determination of some polycyclic aromatic hydrocarbons 'PAHs' by a new spectrophotometric method and multivariate calibration coupled with dispersive liquid-liquid extraction.

    PubMed

    Abdel-Aziz, Omar; El Kosasy, A M; El-Sayed Okeil, S M

    2014-12-10

    A modified dispersive liquid-liquid extraction (DLLE) procedure coupled with spectrophotometric techniques was adopted for simultaneous determination of naphthalene, anthracene, benzo(a)pyrene, alpha-naphthol and beta-naphthol in water samples. Two different methods were used, partial least-squares (PLS) method and a new derivative ratio method, namely extended derivative ratio (EDR). A PLS-2 model was established for simultaneous determination of the studied pollutants in methanol, by using twenty mixtures as calibration set and five mixtures as validation set. Also, in methanol a novel (EDR) method was developed for determination of the studied pollutants, where each component in the mixture of the five PAHs was determined by using a mixture of the other four components as divisor. Chemometric and EDR methods could be also adopted for determination of the studied PAH in water samples after transferring them from aqueous medium to the organic one by utilizing dispersive liquid-liquid extraction technique, where different parameters were investigated using a full factorial design. Both methods were compared and the proposed method was validated according to ICH guidelines and successfully applied to determine these PAHs simultaneously in spiked water samples, where satisfactory results were obtained. All the results obtained agreed with those of published methods, where no significant difference was observed. PMID:24934969

  13. Consistency of L4 TM absolute calibration with respect to the L5 TM sensor based on near-simultaneous image acquisition

    USGS Publications Warehouse

    Chander, G.; Helder, D.L.; Malla, R.; Micijevic, E.; Mettler, C.J.

    2007-01-01

    The Landsat archive provides more than 35 years of uninterrupted multispectral remotely sensed data of Earth observations. Since 1972, Landsat missions have carried different types of sensors, from the Return Beam Vidicon (RBV) camera to the Enhanced Thematic Mapper Plus (ETM+). However, the Thematic Mapper (TM) sensors on Landsat 4 (L4) and Landsat 5 (L5), launched in 1982 and 1984 respectively, are the backbone of an extensive archive. Effective April 2, 2007, the radiometric calibration of L5 TM data processed and distributed by the U.S. Geological Survey (USGS) Center for Earth Resources Observation and Science (EROS) was updated to use an improved lifetime gain model, based on the instrument's detector response to pseudo-invariant desert site data and cross-calibration with the L7 ETM+. However, no modifications were ever made to the radiometric calibration procedure of the Landsat 4 (L4) TM data. The L4 TM radiometric calibration procedure has continued to use the Internal Calibrator (IC) based calibration algorithms and the post calibration dynamic ranges, as previously defined. To evaluate the "current" absolute accuracy of these two sensors, image pairs from the L5 TM and L4 TM sensors were compared. The number of coincident image pairs in the USGS EROS archive is limited, so the scene selection for the cross-calibration studies proved to be a challenge. Additionally, because of the lack of near-simultaneous images available over well-characterized and traditionally used calibration sites, alternate sites that have high reflectance, large dynamic range, high spatial uniformity, high sun elevation, and minimal cloud cover were investigated. The alternate sites were identified in Yuma, Iraq, Egypt, Libya, and Algeria. The cross-calibration approach involved comparing image statistics derived from large common areas observed eight days apart by the two sensors. This paper summarizes the average percent differences in reflectance estimates obtained between the

  14. Consistency of L4 TM absolute calibration with respect to the L5 TM sensor based on near-simultaneous image acquisition

    NASA Astrophysics Data System (ADS)

    Chander, Gyanesh; Helder, Dennis L.; Malla, Rimy; Micijevic, Esad; Mettler, Cory J.

    2007-09-01

    The Landsat archive provides more than 35 years of uninterrupted multispectral remotely sensed data of Earth observations. Since 1972, Landsat missions have carried different types of sensors, from the Return Beam Vidicon (RBV) camera to the Enhanced Thematic Mapper Plus (ETM+). However, the Thematic Mapper (TM) sensors on Landsat 4 (L4) and Landsat 5 (L5), launched in 1982 and 1984 respectively, are the backbone of an extensive archive. Effective April 2, 2007, the radiometric calibration of L5 TM data processed and distributed by the U.S. Geological Survey (USGS) Center for Earth Resources Observation and Science (EROS) was updated to use an improved lifetime gain model, based on the instrument's detector response to pseudo-invariant desert site data and cross-calibration with the L7 ETM+. However, no modifications were ever made to the radiometric calibration procedure of the Landsat 4 (L4) TM data. The L4 TM radiometric calibration procedure has continued to use the Internal Calibrator (IC) based calibration algorithms and the post calibration dynamic ranges, as previously defined. To evaluate the "current" absolute accuracy of these two sensors, image pairs from the L5 TM and L4 TM sensors were compared. The number of coincident image pairs in the USGS EROS archive is limited, so the scene selection for the cross-calibration studies proved to be a challenge. Additionally, because of the lack of near-simultaneous images available over well-characterized and traditionally used calibration sites, alternate sites that have high reflectance, large dynamic range, high spatial uniformity, high sun elevation, and minimal cloud cover were investigated. The alternate sites were identified in Yuma, Iraq, Egypt, Libya, and Algeria. The cross-calibration approach involved comparing image statistics derived from large common areas observed eight days apart by the two sensors. This paper summarizes the average percent differences in reflectance estimates obtained between the

  15. Fine structure of the age-chromospheric activity relation in solar-type stars. I. The Ca II infrared triplet: Absolute flux calibration

    NASA Astrophysics Data System (ADS)

    Lorenzo-Oliveira, D.; Porto de Mello, G. F.; Dutra-Ferreira, L.; Ribas, I.

    2016-10-01

    Context. Strong spectral lines are useful indicators of stellar chromospheric activity. They are physically linked to the convection efficiency, differential rotation, and angular momentum evolution and are a potential indicator of age. However, for ages > 2 Gyr, the age-activity relationship remains poorly constrained thus hampering its full application. Aims: The Ca II infrared triplet (IRT lines, λλ 8498, 8542, and 8662) has been poorly studied compared to classical chromospheric indicators. We report in this paper absolute chromospheric fluxes in the three Ca II IRT lines, based on a new calibration tied to up-to-date model atmospheres. Methods: We obtain the Ca II IRT absolute fluxes for 113 FGK stars from high signal-to-noise ratio (S/N) and high-resolution spectra covering an extensive domain of chromospheric activity levels. We perform an absolute continuum flux calibration for the Ca II IRT lines anchored in atmospheric models calculated as an explicit function of effective temperatures (Teff), metallicity ([Fe/H]), and gravities (log g) avoiding the degeneracy usually present in photometric continuum calibrations based solely on color indices. Results: The internal uncertainties achieved for continuum absolute flux calculations are ≈2% of the solar chromospheric flux, one order of magnitude lower than for photometric calibrations. Using Monte Carlo simulations, we gauge the impact of observational errors on the final chromospheric fluxes due to the absolute continuum flux calibration and find that Teffuncertainties are properly mitigated by the photospheric correction leaving [Fe/H] as the dominating factor in the chromospheric flux uncertainty. Conclusions: Across the FGK spectral types, the Ca II IRT lines are sensitive to chromospheric activity. The reduced internal uncertainties reported here enable us to build a new chromospheric absolute flux scale and explore the age-activity relation from the active regime down to very low activity levels and

  16. Absolute Radiometric Calibration of the GÖKTÜRK-2 Satellite Sensor Using Tuz GÖLÜ (landnet Site) from Ndvi Perspective

    NASA Astrophysics Data System (ADS)

    Sakarya, Ufuk; Hakkı Demirhan, İsmail; Seda Deveci, Hüsne; Teke, Mustafa; Demirkesen, Can; Küpçü, Ramazan; Feray Öztoprak, A.; Efendioğlu, Mehmet; Fehmi Şimşek, F.; Berke, Erdinç; Zübeyde Gürbüz, Sevgi

    2016-06-01

    TÜBİTAK UZAY has conducted a research study on the use of space-based satellite resources for several aspects of agriculture. Especially, there are two precision agriculture related projects: HASSAS (Widespread application of sustainable precision agriculture practices in Southeastern Anatolia Project Region (GAP) Project) and AKTAR (Smart Agriculture Feasibility Project). The HASSAS project aims to study development of precision agriculture practice in GAP region. Multi-spectral satellite imagery and aerial hyperspectral data along with ground measurements was collected to analyze data in an information system. AKTAR aims to develop models for irrigation, fertilization and spectral signatures of crops in Inner Anatolia. By the end of the project precision agriculture practices to control irrigation, fertilization, pesticide and estimation of crop yield will be developed. Analyzing the phenology of crops using NDVI is critical for the projects. For this reason, absolute radiometric calibration of the Red and NIR bands in space-based satellite sensors is an important issue. The Göktürk-2 satellite is an earth observation satellite which was designed and built in Turkey and was launched in 2012. The Göktürk-2 satellite sensor has a resolution 2.5 meters in panchromatic and 5 meters in R/G/B/NIR bands. The absolute radiometric calibration of the Göktürk-2 satellite sensor was performed via the ground-based measurements - spectra-radiometer, sun photometer, and meteorological station- in Tuz Gölü cal/val site in 2015. In this paper, the first ground-based absolute radiometric calibration results of the Göktürk-2 satellite sensor using Tuz Gölü is demonstrated. The absolute radiometric calibration results of this paper are compared with the published cross-calibration results of the Göktürk-2 satellite sensor utilizing Landsat 8 imagery. According to the experimental comparison results, the Göktürk-2 satellite sensor coefficients for red and NIR bands

  17. Contributed Review: Absolute spectral radiance calibration of fiber-optic shock-temperature pyrometers using a coiled-coil irradiance standard lamp.

    PubMed

    Fat'yanov, O V; Asimow, P D

    2015-10-01

    We describe an accurate and precise calibration procedure for multichannel optical pyrometers such as the 6-channel, 3-ns temporal resolution instrument used in the Caltech experimental geophysics laboratory. We begin with a review of calibration sources for shock temperatures in the 3000-30,000 K range. High-power, coiled tungsten halogen standards of spectral irradiance appear to be the only practical alternative to NIST-traceable tungsten ribbon lamps, which are no longer available with large enough calibrated area. However, non-uniform radiance complicates the use of such coiled lamps for reliable and reproducible calibration of pyrometers that employ imaging or relay optics. Careful analysis of documented methods of shock pyrometer calibration to coiled irradiance standard lamps shows that only one technique, not directly applicable in our case, is free of major radiometric errors. We provide a detailed description of the modified Caltech pyrometer instrument and a procedure for its absolute spectral radiance calibration, accurate to ±5%. We employ a designated central area of a 0.7× demagnified image of a coiled-coil tungsten halogen lamp filament, cross-calibrated against a NIST-traceable tungsten ribbon lamp. We give the results of the cross-calibration along with descriptions of the optical arrangement, data acquisition, and processing. We describe a procedure to characterize the difference between the static and dynamic response of amplified photodetectors, allowing time-dependent photodiode correction factors for spectral radiance histories from shock experiments. We validate correct operation of the modified Caltech pyrometer with actual shock temperature experiments on single-crystal NaCl and MgO and obtain very good agreement with the literature data for these substances. We conclude with a summary of the most essential requirements for error-free calibration of a fiber-optic shock-temperature pyrometer using a high-power coiled tungsten halogen

  18. Contributed Review: Absolute spectral radiance calibration of fiber-optic shock-temperature pyrometers using a coiled-coil irradiance standard lamp

    SciTech Connect

    Fat’yanov, O. V. Asimow, P. D.

    2015-10-15

    We describe an accurate and precise calibration procedure for multichannel optical pyrometers such as the 6-channel, 3-ns temporal resolution instrument used in the Caltech experimental geophysics laboratory. We begin with a review of calibration sources for shock temperatures in the 3000-30 000 K range. High-power, coiled tungsten halogen standards of spectral irradiance appear to be the only practical alternative to NIST-traceable tungsten ribbon lamps, which are no longer available with large enough calibrated area. However, non-uniform radiance complicates the use of such coiled lamps for reliable and reproducible calibration of pyrometers that employ imaging or relay optics. Careful analysis of documented methods of shock pyrometer calibration to coiled irradiance standard lamps shows that only one technique, not directly applicable in our case, is free of major radiometric errors. We provide a detailed description of the modified Caltech pyrometer instrument and a procedure for its absolute spectral radiance calibration, accurate to ±5%. We employ a designated central area of a 0.7× demagnified image of a coiled-coil tungsten halogen lamp filament, cross-calibrated against a NIST-traceable tungsten ribbon lamp. We give the results of the cross-calibration along with descriptions of the optical arrangement, data acquisition, and processing. We describe a procedure to characterize the difference between the static and dynamic response of amplified photodetectors, allowing time-dependent photodiode correction factors for spectral radiance histories from shock experiments. We validate correct operation of the modified Caltech pyrometer with actual shock temperature experiments on single-crystal NaCl and MgO and obtain very good agreement with the literature data for these substances. We conclude with a summary of the most essential requirements for error-free calibration of a fiber-optic shock-temperature pyrometer using a high-power coiled tungsten halogen

  19. Contributed Review: Absolute spectral radiance calibration of fiber-optic shock-temperature pyrometers using a coiled-coil irradiance standard lamp.

    PubMed

    Fat'yanov, O V; Asimow, P D

    2015-10-01

    We describe an accurate and precise calibration procedure for multichannel optical pyrometers such as the 6-channel, 3-ns temporal resolution instrument used in the Caltech experimental geophysics laboratory. We begin with a review of calibration sources for shock temperatures in the 3000-30,000 K range. High-power, coiled tungsten halogen standards of spectral irradiance appear to be the only practical alternative to NIST-traceable tungsten ribbon lamps, which are no longer available with large enough calibrated area. However, non-uniform radiance complicates the use of such coiled lamps for reliable and reproducible calibration of pyrometers that employ imaging or relay optics. Careful analysis of documented methods of shock pyrometer calibration to coiled irradiance standard lamps shows that only one technique, not directly applicable in our case, is free of major radiometric errors. We provide a detailed description of the modified Caltech pyrometer instrument and a procedure for its absolute spectral radiance calibration, accurate to ±5%. We employ a designated central area of a 0.7× demagnified image of a coiled-coil tungsten halogen lamp filament, cross-calibrated against a NIST-traceable tungsten ribbon lamp. We give the results of the cross-calibration along with descriptions of the optical arrangement, data acquisition, and processing. We describe a procedure to characterize the difference between the static and dynamic response of amplified photodetectors, allowing time-dependent photodiode correction factors for spectral radiance histories from shock experiments. We validate correct operation of the modified Caltech pyrometer with actual shock temperature experiments on single-crystal NaCl and MgO and obtain very good agreement with the literature data for these substances. We conclude with a summary of the most essential requirements for error-free calibration of a fiber-optic shock-temperature pyrometer using a high-power coiled tungsten halogen

  20. Contributed Review: Absolute spectral radiance calibration of fiber-optic shock-temperature pyrometers using a coiled-coil irradiance standard lamp

    NASA Astrophysics Data System (ADS)

    Fat'yanov, O. V.; Asimow, P. D.

    2015-10-01

    We describe an accurate and precise calibration procedure for multichannel optical pyrometers such as the 6-channel, 3-ns temporal resolution instrument used in the Caltech experimental geophysics laboratory. We begin with a review of calibration sources for shock temperatures in the 3000-30 000 K range. High-power, coiled tungsten halogen standards of spectral irradiance appear to be the only practical alternative to NIST-traceable tungsten ribbon lamps, which are no longer available with large enough calibrated area. However, non-uniform radiance complicates the use of such coiled lamps for reliable and reproducible calibration of pyrometers that employ imaging or relay optics. Careful analysis of documented methods of shock pyrometer calibration to coiled irradiance standard lamps shows that only one technique, not directly applicable in our case, is free of major radiometric errors. We provide a detailed description of the modified Caltech pyrometer instrument and a procedure for its absolute spectral radiance calibration, accurate to ±5%. We employ a designated central area of a 0.7× demagnified image of a coiled-coil tungsten halogen lamp filament, cross-calibrated against a NIST-traceable tungsten ribbon lamp. We give the results of the cross-calibration along with descriptions of the optical arrangement, data acquisition, and processing. We describe a procedure to characterize the difference between the static and dynamic response of amplified photodetectors, allowing time-dependent photodiode correction factors for spectral radiance histories from shock experiments. We validate correct operation of the modified Caltech pyrometer with actual shock temperature experiments on single-crystal NaCl and MgO and obtain very good agreement with the literature data for these substances. We conclude with a summary of the most essential requirements for error-free calibration of a fiber-optic shock-temperature pyrometer using a high-power coiled tungsten halogen

  1. STANDARDIZING TYPE Ia SUPERNOVA ABSOLUTE MAGNITUDES USING GAUSSIAN PROCESS DATA REGRESSION

    SciTech Connect

    Kim, A. G.; Aldering, G.; Aragon, C.; Bailey, S.; Childress, M.; Fakhouri, H. K.; Nordin, J.; Thomas, R. C.; Antilogus, P.; Bongard, S.; Canto, A.; Cellier-Holzem, F.; Guy, J.; Baltay, C.; Buton, C.; Kerschhaggl, M.; Kowalski, M.; Chotard, N.; Copin, Y.; Gangler, E.; and others

    2013-04-01

    We present a novel class of models for Type Ia supernova time-evolving spectral energy distributions (SEDs) and absolute magnitudes: they are each modeled as stochastic functions described by Gaussian processes. The values of the SED and absolute magnitudes are defined through well-defined regression prescriptions, so that data directly inform the models. As a proof of concept, we implement a model for synthetic photometry built from the spectrophotometric time series from the Nearby Supernova Factory. Absolute magnitudes at peak B brightness are calibrated to 0.13 mag in the g band and to as low as 0.09 mag in the z = 0.25 blueshifted i band, where the dispersion includes contributions from measurement uncertainties and peculiar velocities. The methodology can be applied to spectrophotometric time series of supernovae that span a range of redshifts to simultaneously standardize supernovae together with fitting cosmological parameters.

  2. Calibration Monitor for Dark Energy Experiments

    SciTech Connect

    Kaiser, M. E.

    2009-11-23

    The goal of this program was to design, build, test, and characterize a flight qualified calibration source and monitor for a Dark Energy related experiment: ACCESS - 'Absolute Color Calibration Experiment for Standard Stars'. This calibration source, the On-board Calibration Monitor (OCM), is a key component of our ACCESS spectrophotometric calibration program. The OCM will be flown as part of the ACCESS sub-orbital rocket payload in addition to monitoring instrument sensitivity on the ground. The objective of the OCM is to minimize systematic errors associated with any potential changes in the ACCESS instrument sensitivity. Importantly, the OCM will be used to monitor instrument sensitivity immediately after astronomical observations while the instrument payload is parachuting to the ground. Through monitoring, we can detect, track, characterize, and thus correct for any changes in instrument senstivity over the proposed 5-year duration of the assembled and calibrated instrument.

  3. Piston manometer as an absolute standard for vacuum-gage calibration in the range 2 to 500 millitorr

    NASA Technical Reports Server (NTRS)

    Warshawsky, I.

    1972-01-01

    A thin disk is suspended, with very small annular clearance, in a cylindrical opening in the base plate of a calibration chamber. A continuous flow of calibration gas passes through the chamber and annular opening to a downstream high vacuum pump. The ratio of pressures on the two faces of the disk is very large, so that the upstream pressure is substantially equal to net force on the disk divided by disk area. This force is measured with a dynamometer that is calibrated in place with dead weights. A probable error of + or - (0.2 millitorr plus 0.2 percent) is attainable when downstream pressure is known to 10 percent.

  4. Systematic Uncertainties in the Spectroscopic Measurements of Neutron-star Masses and Radii from Thermonuclear X-Ray Bursts. III. Absolute Flux Calibration

    NASA Astrophysics Data System (ADS)

    Güver, Tolga; Özel, Feryal; Marshall, Herman; Psaltis, Dimitrios; Guainazzi, Matteo; Díaz-Trigo, Maria

    2016-09-01

    Many techniques for measuring neutron star radii rely on absolute flux measurements in the X-rays. As a result, one of the fundamental uncertainties in these spectroscopic measurements arises from the absolute flux calibrations of the detectors being used. Using the stable X-ray burster, GS 1826-238, and its simultaneous observations by Chandra HETG/ACIS-S and RXTE/PCA as well as by XMM-Newton EPIC-pn and RXTE/PCA, we quantify the degree of uncertainty in the flux calibration by assessing the differences between the measured fluxes during bursts. We find that the RXTE/PCA and the Chandra gratings measurements agree with each other within their formal uncertainties, increasing our confidence in these flux measurements. In contrast, XMM-Newton EPIC-pn measures 14.0 ± 0.3% less flux than the RXTE/PCA. This is consistent with the previously reported discrepancy with the flux measurements of EPIC-pn, compared with EPIC MOS1, MOS2, and ACIS-S detectors. We also show that any intrinsic time-dependent systematic uncertainty that may exist in the calibration of the satellites has already been implicity taken into account in the neutron star radius measurements.

  5. Performance Demonstration of Miniature Phase Transition Cells in Microgravity as a Validation for their use in the Absolute Calibration of Temperature Sensors On-Orbit

    NASA Astrophysics Data System (ADS)

    Pettersen, C.; Best, F. A.; Adler, D. P.; Aguilar, D. M.; Perepezko, J. H.

    2012-12-01

    The next generation of infrared remote sensing missions, including the climate benchmark missions, will require better absolute measurement accuracy than now available, and will most certainly rely on the emerging capability to fly SI traceable standards that provide irrefutable absolute measurement accuracy. As an example, instrumentation designed to measure spectrally resolved infrared radiances with an absolute brightness temperature error of better than 0.1 K will require high-emissivity (>0.999) calibration blackbodies requiring absolute temperature uncertainties of better than 0.045K (k=3). Key elements of an On-Orbit Absolute Radiance Standard (OARS) meeting these stringent requirements have been demonstrated in the laboratory at the University of Wisconsin and were further refined under the NASA Instrument Incubator Program (IIP). In particular, the OARS has imbedded thermistors that can be periodically calibrated on-orbit using the melt signatures of small quantities (<0.5g) of three reference materials - mercury, water, and gallium, providing calibration from 233K to 303K. One of the many tests to determine the readiness of this technology for on-orbit application is a demonstration of performance in microgravity to be conducted on the International Space Station (ISS). This demonstration will make use of an Experiment Support Package developed by Utah State Space Dynamics Laboratory to continuously run melt cycles on miniature phase change cells containing gallium, a gallium-tin eutectic, and water. The phase change cells will be mounted in a small aluminum block along with a thermistor temperature sensor. A thermoelectric cooler will be used to change the temperature of the block. The demonstration will use the configuration of the phase transition cells developed under our NASA IIP that has been tested extensively in the laboratory under simulated mission life cycle scenarios - these included vibration, thermal soaks, and deep cycling. Melt signatures

  6. Update to the Cosmic Origins Spectrograph FUV Calibration: Improved Characterization Below 1150 Angstroms and Improved Absolute Flux Calibration at all Wavelengths

    NASA Astrophysics Data System (ADS)

    Sonnentrucker, Paule; Bostroem, K. A.; Ely, J.; Debes, J. H.; DiFelice, A.; Hernandez, S.; Hodge, P. E.; Lindsay, K.; Lockwood, S. A.; Massa, D.; Oliveira, C. M.; Roman-Duval, J.; Penton, S. V.; Proffitt, C. R.; Taylor, J. M.

    2014-01-01

    As of Cycle 20, the three COS/FUV "Blue Mode" wavelength settings at G130M/1055, 1096 and 1222, have become available as regular observing modes. We provide updates on the wavelength and flux calibration of these new Blue Mode settings, which allow medium-resolution spectroscopy down to 900A with effective areas comparable to those of FUSE. We discuss also recent improvements to the COS/FUV flux and flat-field calibrations and present the most recent time-dependent sensitivity trends of the FUV and NUV channels.

  7. Spectrophotometric determination of carminic acid in human plasma and fruit juices by second order calibration of the absorbance spectra-pH data matrices coupled with standard addition method.

    PubMed

    Samari, Fayezeh; Hemmateenejad, Bahram; Shamsipur, Mojtaba

    2010-05-14

    A simple analytical method based on the second-order calibration of the pH gradient spectrophotometric data was developed for assay of carminic acid (CA) in human plasma and orange juice over the concentration range of 1.5-14.0microM. The multi-way data analysis method was coupled with standard addition to encounter the significant effects of plasma and juices matrices on the acid-base behavior and UV-vis. absorbance spectra of CA. Thus, the standard addition three-way calibration data of plasma or fruit juices samples were analyzed by parallel factor analysis (PARAFAC) and the concentration related scores were used to derive a standard addition plot such as one obtained in univariate standard addition method. The number of PARAFAC components was obtained utilizing different criteria such as core consistency and residual errors through pf-test implementation. The applicability of the proposed method was evaluated by analysis of human plasma and fruit juices spiked with different levels of standard CA solutions. The results confirmed the success of the proposed method in the analysis of pH gradient spectrophotometric data for determination of CA. The recoveries were between 86.7 and 106.7. PMID:20441865

  8. Absolute elastic differential electron scattering cross sections for He - A proposed calibration standard from 5 to 200 eV

    NASA Technical Reports Server (NTRS)

    Register, D. F.; Trajmar, S.; Srivastava, S. K.

    1980-01-01

    Absolute differential, integral, and momentum-transfer cross sections for electrons elastically scattered from helium are reported for the impact energy range of 5 to 200 eV. Angular distributions for elastically scattered electrons are measured in a crossed-beam geometry using a collimated, differentially pumped atomic-beam source which requires no effective-path-length correction. Below the first inelastic threshold the angular distributions were placed on an absolute scale by use of a phase-shift analysis. Above this threshold, the angular distributions from 10 to 140 deg were fitted using the phase-shift technique, and the resulting integral cross sections were normalized to a semiempirically derived integral elastic cross section. Depending on the impact energy, the data are estimated to be accurate to within 5 to 9%.

  9. Absolute calibration of Kodak Biomax-MS film response to x rays in the 1.5- to 8-keV energy range

    NASA Astrophysics Data System (ADS)

    Marshall, F. J.; Knauer, J. P.; Anderson, D.; Schmitt, B. L.

    2006-10-01

    The absolute response of Kodak Biomax-MS film to x rays in the range from 1.5- to 8-keV has been measured using a laboratory electron-beam generated x-ray source. The measurements were taken at specific line energies by using Bragg diffraction to produce monochromatic beams of x rays. Multiple exposures were taken on Biomax MS film up to levels exceeding optical densities of 2 as measured by a microdensitometer. The absolute beam intensity for each exposure was measured with a Si (Li) detector. Additional response measurements were taken with Kodak direct exposure film (DEF) so as to compare the results of this technique to previously published calibrations. The Biomax-MS results have been fitted to a semiempirical mathematical model (Knauer et al., these proceedings). Users of the model can infer absolute fluences from observed exposure levels at either interpolated or extrapolated energies. To summarize the results: Biomax MS has comparable sensitivity to DEF film below 3keV but has reduced sensitivity above 3keV (˜50%). The lower exposure results from thinner emulsion layers, designed for use with phosphor screens. The ease with which Biomax-MS can be used in place of DEF (same format film, same developing process, and comparable sensitivity) makes it a good replacement.

  10. An absolute calibration method of an ethyl alcohol biosensor based on wavelength-modulated differential photothermal radiometry.

    PubMed

    Liu, Yi Jun; Mandelis, Andreas; Guo, Xinxin

    2015-11-01

    In this work, laser-based wavelength-modulated differential photothermal radiometry (WM-DPTR) is applied to develop a non-invasive in-vehicle alcohol biosensor. WM-DPTR features unprecedented ethanol-specificity and sensitivity by suppressing baseline variations through a differential measurement near the peak and baseline of the mid-infrared ethanol absorption spectrum. Biosensor signal calibration curves are obtained from WM-DPTR theory and from measurements in human blood serum and ethanol solutions diffused from skin. The results demonstrate that the WM-DPTR-based calibrated alcohol biosensor can achieve high precision and accuracy for the ethanol concentration range of 0-100 mg/dl. The high-performance alcohol biosensor can be incorporated into ignition interlocks that could be fitted as a universal accessory in vehicles in an effort to reduce incidents of drinking and driving.

  11. An absolute calibration method of an ethyl alcohol biosensor based on wavelength-modulated differential photothermal radiometry.

    PubMed

    Liu, Yi Jun; Mandelis, Andreas; Guo, Xinxin

    2015-11-01

    In this work, laser-based wavelength-modulated differential photothermal radiometry (WM-DPTR) is applied to develop a non-invasive in-vehicle alcohol biosensor. WM-DPTR features unprecedented ethanol-specificity and sensitivity by suppressing baseline variations through a differential measurement near the peak and baseline of the mid-infrared ethanol absorption spectrum. Biosensor signal calibration curves are obtained from WM-DPTR theory and from measurements in human blood serum and ethanol solutions diffused from skin. The results demonstrate that the WM-DPTR-based calibrated alcohol biosensor can achieve high precision and accuracy for the ethanol concentration range of 0-100 mg/dl. The high-performance alcohol biosensor can be incorporated into ignition interlocks that could be fitted as a universal accessory in vehicles in an effort to reduce incidents of drinking and driving. PMID:26628164

  12. An absolute calibration method of an ethyl alcohol biosensor based on wavelength-modulated differential photothermal radiometry

    SciTech Connect

    Liu, Yi Jun; Mandelis, Andreas; Guo, Xinxin

    2015-11-15

    In this work, laser-based wavelength-modulated differential photothermal radiometry (WM-DPTR) is applied to develop a non-invasive in-vehicle alcohol biosensor. WM-DPTR features unprecedented ethanol-specificity and sensitivity by suppressing baseline variations through a differential measurement near the peak and baseline of the mid-infrared ethanol absorption spectrum. Biosensor signal calibration curves are obtained from WM-DPTR theory and from measurements in human blood serum and ethanol solutions diffused from skin. The results demonstrate that the WM-DPTR-based calibrated alcohol biosensor can achieve high precision and accuracy for the ethanol concentration range of 0-100 mg/dl. The high-performance alcohol biosensor can be incorporated into ignition interlocks that could be fitted as a universal accessory in vehicles in an effort to reduce incidents of drinking and driving.

  13. Absorption by ground-state lead atoms of the 283. 3-nm resonant line from a lead hollow cathode lamp. An absolute number density calibration

    SciTech Connect

    Simons, J.W. ); Oldenborg, R.C.; Baughcum, S.L. )

    1989-10-19

    An accurate absolute number density calibration curve for absorption by gaseous lead atoms of the 283.3-nm resonant line from a typical lead hollow cathode lamp is reported. This calibration shows the usual curvature in the Beer-Lambert plot for atomic absorption at moderate to high absorbances that is commonly attributed to self-absorption leading to line reversal in the source and/or preferential absorption at the line center when the absorber temperature is not much greater than the source Doppler temperature. A theoretical calculation utilizing a Doppler-limited Fourier transform spectrum of the 283.3-nm emission from the lamp and a tabulated value of the absorption cross section and accounting for the isotopic and nuclear hyperfine components in both the emission and absorption due to naturally occurring lead quantitatively reproduces the experimental calibration curve without any parameter adjustments. It is found that the curvature in the Beer-Lambert plot has more to do with the fact that the absorbing and emitting atoms are a mixture of isotopes giving several isotopic and nuclear hyperfine transitions at slightly different frequencies than it does with preferential absorption at line centers.

  14. Spectrophotometric probe

    DOEpatents

    Prather, William S.; O'Rourke, Patrick E.

    1994-01-01

    A support structure bearing at least one probe for making spectrophotometric measurements of a fluid using a source of light and a spectrophotometer. The probe includes a housing with two optical fibers and a planoconvex lens. A sleeve bearing a mirror surrounds the housing. The lens is separated from the mirror by a fixed distance, defining an interior space for receiving a volume of the fluid sample. A plurality of throughholes extending through the sleeve communicate between the sample volume and the exterior of the probe, all but one hole bearing a screen. A protective jacket surrounds the probe. A hollow conduit bearing a tube is formed in the wall of the probe for venting any air in the interior space when fluid enters. The probe is held at an acute angle so the optic fibers carrying the light to and from the probe are not bent severely on emergence from the probe.

  15. Spectrophotometric probe

    DOEpatents

    Prather, W.S.; O'Rourke, P.E.

    1994-08-02

    A support structure is described bearing at least one probe for making spectrophotometric measurements of a fluid using a source of light and a spectrophotometer. The probe includes a housing with two optical fibers and a planoconvex lens. A sleeve bearing a mirror surrounds the housing. The lens is separated from the mirror by a fixed distance, defining an interior space for receiving a volume of the fluid sample. A plurality of throughholes extending through the sleeve communicate between the sample volume and the exterior of the probe, all but one hole bearing a screen. A protective jacket surrounds the probe. A hollow conduit bearing a tube is formed in the wall of the probe for venting any air in the interior space when fluid enters. The probe is held at an acute angle so the optic fibers carrying the light to and from the probe are not bent severely on emergence from the probe. 3 figs.

  16. Sequential injection kinetic spectrophotometric determination of quaternary mixtures of carbamate pesticides in water and fruit samples using artificial neural networks for multivariate calibration

    NASA Astrophysics Data System (ADS)

    Chu, Ning; Fan, Shihua

    2009-12-01

    A new analytical method was developed for the simultaneous kinetic spectrophotometric determination of a quaternary carbamate pesticide mixture consisting of carbofuran, propoxur, metolcarb and fenobucarb using sequential injection analysis (SIA). The procedure was based upon the different kinetic properties between the analytes reacted with reagent in flow system in the non-stopped-flow mode, in which their hydrolysis products coupled with diazotized p-nitroaniline in an alkaline medium to form the corresponding colored complexes. The absorbance data from SIA peak time profile were recorded at 510 nm and resolved by the use of back-propagation-artificial neural network (BP-ANN) algorithms for multivariate quantitative analysis. The experimental variables and main network parameters were optimized and each of the pesticides could be determined in the concentration range of 0.5-10.0 μg mL -1, at a sampling frequency of 18 h -1. The proposed method was compared to other spectrophotometric methods for simultaneous determination of mixtures of carbamate pesticides, and it was proved to be adequately reliable and was successfully applied to the simultaneous determination of the four pesticide residues in water and fruit samples, obtaining the satisfactory results based on recovery studies (84.7-116.0%).

  17. CO{sub 2} laser light scattering by bare soils for emissivity measurements: Absolute calibration and correlation with backscattering and composition

    SciTech Connect

    Kologo, N.; Stoll, M.P.

    1996-07-01

    Measurements of the scattering cross section of a number of bare soils have been made with CO{sub 2} laser illumination at 10.59 {micro}m. The primary focus was on absolute calibration of the measurements. First, comparison of emissivity values resulting from the application of Kirchhoff`s relation after angular integration of the bidirectional measurements, with emissivity values obtained from the analysis of the emitted radiation show excellent agreement to within less than 0.3%. Second, it was found that a simple formula holds for a relationship between the emissivity and co- and cross-polarized backscattering cross section at an angle of 30{degree}. Third, a clear correlation was observed between emissivity and composition (in this case % Al + Fe oxides; % SiO{sub 2}) for a homogeneous series of samples from the same area in Niger. These results emphasize the importance of calibrated experimental data. The implications of the research give evidence of the advantage of obtaining emissivity from remote reflectivity measurements and possibly only backscattering measurements, and remotely estimating mineral composition.

  18. ACCESS: Design, Calibration Strategy, and Status

    NASA Astrophysics Data System (ADS)

    Kaiser, M. E.; Access Team

    2016-05-01

    ACCESS, Absolute Color Calibration Experiment for Standard Stars, is a series of rocket-borne sub-orbital missions and ground-based experiments designed to enable improvements in the precision of the astrophysical flux scale through the transfer of absolute laboratory detector standards from the National Institute of Standards and Technology (NIST) to a network of stellar standards with a calibration accuracy of 1% and a spectral resolving power of 500 across the 0.35–1.7μm bandpass. Establishing improved spectrophotometric standards is important for a broad range of missions and is relevant to many astrophysical problems. Systematic errors associated with problems such as dark energy now compete with the statistical errors and thus limit our ability to answer fundamental questions in astrophysics.

  19. ACCESS: Design, Calibration Strategy, and Status

    NASA Astrophysics Data System (ADS)

    Kaiser, M. E.; Access Team

    2016-05-01

    ACCESS, Absolute Color Calibration Experiment for Standard Stars, is a series of rocket-borne sub-orbital missions and ground-based experiments designed to enable improvements in the precision of the astrophysical flux scale through the transfer of absolute laboratory detector standards from the National Institute of Standards and Technology (NIST) to a network of stellar standards with a calibration accuracy of 1% and a spectral resolving power of 500 across the 0.35-1.7μm bandpass. Establishing improved spectrophotometric standards is important for a broad range of missions and is relevant to many astrophysical problems. Systematic errors associated with problems such as dark energy now compete with the statistical errors and thus limit our ability to answer fundamental questions in astrophysics.

  20. Easy Absolute Values? Absolutely

    ERIC Educational Resources Information Center

    Taylor, Sharon E.; Mittag, Kathleen Cage

    2015-01-01

    The authors teach a problem-solving course for preservice middle-grades education majors that includes concepts dealing with absolute-value computations, equations, and inequalities. Many of these students like mathematics and plan to teach it, so they are adept at symbolic manipulations. Getting them to think differently about a concept that they…

  1. SkyProbe: Real-Time Precision Monitoring in the Optical of the Absolute Atmospheric Absorption on the Telescope Science and Calibration Fields

    NASA Astrophysics Data System (ADS)

    Cuillandre, J.-C.; Magnier, E.; Sabin, D.; Mahoney, B.

    2016-05-01

    Mauna Kea is known for its pristine seeing conditions but sky transparency can be an issue for science operations since at least 25% of the observable (i.e. open dome) nights are not photometric, an effect mostly due to high-altitude cirrus. Since 2001, the original single channel SkyProbe mounted in parallel on the Canada-France-Hawaii Telescope (CFHT) has gathered one V-band exposure every minute during each observing night using a small CCD camera offering a very wide field of view (35 sq. deg.) encompassing the region pointed by the telescope for science operations, and exposures long enough (40 seconds) to capture at least 100 stars of Hipparcos' Tycho catalog at high galactic latitudes (and up to 600 stars at low galactic latitudes). The measurement of the true atmospheric absorption is achieved within 2%, a key advantage over all-sky direct thermal infrared imaging detection of clouds. The absolute measurement of the true atmospheric absorption by clouds and particulates affecting the data being gathered by the telescope's main science instrument has proven crucial for decision making in the CFHT queued service observing (QSO) representing today all of the telescope time. Also, science exposures taken in non-photometric conditions are automatically registered for a new observation at a later date at 1/10th of the original exposure time in photometric conditions to ensure a proper final absolute photometric calibration. Photometric standards are observed only when conditions are reported as being perfectly stable by SkyProbe. The more recent dual color system (simultaneous B & V bands) will offer a better characterization of the sky properties above Mauna Kea and should enable a better detection of the thinnest cirrus (absorption down to 0.01 mag., or 1%).

  2. Absolute intensity calibration of flat-field space-resolved extreme ultraviolet spectrometer using radial profiles of visible and extreme ultraviolet bremsstrahlung continuum emitted from high-density plasmas in Large Helical Device

    SciTech Connect

    Dong Chunfeng; Wang Erhui; Morita, Shigeru; Goto, Motoshi

    2011-11-15

    A precise absolute intensity calibration of a flat-field space-resolved extreme ultraviolet (EUV) spectrometer working in wavelength range of 60-400 A is carried out using a new calibration technique based on radial profile measurement of the bremsstrahlung continuum in Large Helical Device. A peaked vertical profile of the EUV bremsstrahlung continuum has been successfully observed in high-density plasmas (n{sub e}{>=} 10{sup 14} cm{sup -3}) with hydrogen ice pellet injection. The absolute calibration can be done by comparing the EUV bremsstrahlung profile with the visible bremsstrahlung profile of which the absolute value has been already calibrated using a standard lamp. The line-integrated profile of measured visible bremsstrahlung continuum is firstly converted into the local emissivity profile by considering a magnetic surface distortion due to the plasma pressure, and the local emissivity profile of EUV bremsstrahlung is secondly calculated by taking into account the electron temperature profile and free-free gaunt factor. The line-integrated profile of the EUV bremsstrahlung continuum is finally calculated from the local emissivity profile in order to compare with measured EUV bremsstrahlung profile. The absolute intensity calibration can be done by comparing measured and calculated EUV bremsstrahlung profiles. The calibration factor is thus obtained as a function of wavelength with excellent accuracy. It is also found in the profile analysis that the grating reflectivity of EUV emissions is constant along the direction perpendicular to the wavelength dispersion. Uncertainties on the calibration factor determined with the present method are discussed including charge-coupled device operation modes.

  3. Absolute number density calibration of the absorption by ground-state lead atoms of the 283. 3-nm resonance line from a high-intensity lead hollow cathode lamp and the calculated effect of argon pressures

    SciTech Connect

    Simons, J.W.; McClean, R.E. ); Oldenborg, R.C. )

    1991-03-21

    The absolute number density calibration for the absorption by ground-state lead atoms of the 283.3-nm resonance line from a high-intensity lead hollow cathode lamp (Photron superlamp) is determined and found to be the same as that of a standard hollow cathode lamp. Comparisons of the calibrations to theoretical calculations are found to be quite satisfactory. The effects of argon pressures in the absorption cell on the calibration are examined theoretically by using a simple Lorentzian broadening and shifting model. These calculations show the expected reduction in sensitivity and increasing linearity of Beer-Lambert plots with increasing argon pressure.

  4. Absolute calibration and atmospheric versus mineralogic origin of absorption features in 2.0 to 2.5 micron Mars spectra obtained during 1993

    NASA Technical Reports Server (NTRS)

    Bell, James F., III; Pollack, James B.; Geballe, Thomas R.; Cruikshank, Dale P.; Freedman, Richard

    1994-01-01

    We obtained new high resolution reflectance spectra of Mars during the 1993 opposition from Mauna Kea Observatory using the UKIRT CGS4 spectrometer. Fifty spectra of 1600-2000 km surface regions and a number of standard star spectra were obtained in the 2.04 to 2.44 micron wavelength region on 4 February 1993 UT. Near-simultaneous observations of bright standard stars were used to perform terrestrial atmospheric corrections and an absolute flux calibration. Using the known magnitude of the stars and assuming blackbody continuum behavior, the flux from Mars could be derived. A radiative transfer model and the HITRAN spectral line data base were used to compute atmospheric transmission spectra for Mars and the Earth in order to simulate the contributions of these atmospheres to our observed data. Also, we examined the ATMOS solar spectrum in the near-IR to try to identify absorption features in the spectrum of the Sun that could be misinterpreted as Mars features. Eleven absorption features were detected in our Mars spectra. Our data provide no conclusive identification of the mineralogy responsible for the absorption features we detected. However, examination of terrestrial spectral libraries and previous high spectral resolution mineral studies indicates that the most likely origin of these features is either CO3(sup 2-), HCO3(-), or HSO4(-) anions in framework silicates or possibly (Fe, Mg)-OH bonds in sheet silicates.

  5. Determination of Delta m(d) and absolute calibration of flavor taggers for the Delta m(s) analysis, in fully reconstructed decays at the CDF experiment

    SciTech Connect

    Gomez, Jonatan Piedra

    2005-04-21

    The new trigger processor, the Silicon Vertex Tracking (SVT), has dramatically improved the B physics capabilities of the upgraded CDF II Detector; for the first time in a hadron collider, the SVT has enabled the access to non-lepton-triggered B meson decays. Within the new available range of decay modes, the B$0\\atop{s}$ → D$-\\atop{s}$π+ signature is of paramount importance in the measurement of the Δms mixing frequency. The analysis reported here is a step towards the measurement of this frequency; two where our goals: carrying out the absolute calibration of the opposite side flavor taggers, used in the Δms measurement; and measuring the B$0\\atop{d}$ mixing frequency in a B → Dπ sample, establishing the feasibility of the mixing measurement in this sample whose decay-length is strongly biased by the selective SVT trigger. We analyze a total integrated luminosity of 355 pb-1 collected with the CDF II Detector. By triggering on muons, using the conventional di-muon trigger; or displaced tracks, using the SVT trigger, we gather a sample rich in bottom and charm mesons.

  6. Highly selective artificial gel antibodies for detection and quantification of biomarkers in clinical samples. I. Spectrophotometric approach to design the calibration curve for the quantification.

    PubMed

    Ghasemzadeh, Nasim; Nyberg, Fred; Hjertén, Stellan

    2008-12-01

    High selectivity of a biomarker is a basic requirement when it is used for diagnosis, prognosis and treatment of a disease. The artificial gel antibodies, which we synthesise by a molecular imprinting method, have this property not only for proteins, but also for bioparticles, such as viruses and bacteria. However, diagnosis of a disease requires not only that the biomarker can be "fished out" from a body fluid with high selectivity, but also that its concentration in the sample can rapidly be determined and preferably by a simple technique. This paper deals primarily with the development of a spectrophotometric method, which is so simple and fast that it can be used with advantage in a Doctor's Office. The development of this method was not straight-forward. However, by modifications of the performance of these measurements we can now design standard curves in the form of a straight line, when we plot the true (not the recorded "apparent" absorption) against known protein concentrations. In an additional publication (see the following paper in this issue of JSS) we show an application of such a plot: determination of the concentration of albumin in serum and cerebrospinal fluid from patients with neurological disorders to investigate whether albumin is a biomarker for these diseases.

  7. STARCaL: A Tunable Laser in Space for Telescope Calibration and Atmospheric Studies

    NASA Astrophysics Data System (ADS)

    Albert, Justin; Burgett, W.; Deustua, S.

    2006-12-01

    We propose a tunable laser-based satellite-mounted spectrophotometric and absolute flux calibration system, to be utilized by groundand space-based telescopes. As uncertainties on the photometry, due to imperfect knowledge of both telescope optics and the atmosphere, will in the near future begin to dominate the uncertainties on fundamental cosmological parameters such as ΩΛ (Omega_Lambda) and w in measurements from SNIa, weak gravitational lensing, and baryon oscillations, a method for reducing such uncertainties is needed. We propose to improve spectrophotometric calibration, currently obtained using standard stars, by placing a tunable laser and a wide-angle light source on a satellite by early next decade (perhaps included in the upgrade to the GPS satellite network) to improve absolute flux calibration to the 0.02% level and relative spectrophotometric calibration to better than 0.001% across the visible and near-infrared spectrum. As well as fundamental astrophysical applications, the system proposed here potentially has broad utility for atmospheric physics, as well as for defense and national security applications such as ground target illumination, space situational awareness, and space communication. For further details please see http://www.starcal.org/ and http://www.arxiv.org/abs/astro-ph/0604339.

  8. Selection of stars to calibrate Gaia

    NASA Astrophysics Data System (ADS)

    Carrasco, J. M.; Voss, H.; Jordi, C.; Fabricius, C.; Pancino, E.; Altavilla, G.

    2015-05-01

    Gaia is an all-sky survey satellite, launched by ESA on 19th December 2013, to obtain parallaxes and proper motions to microarcsecond level precision, radial velocities and astrophysical parameters for about one billion objects down to a limiting magnitude of 20. The chosen strategy to perform the photometric calibration is to split the process into two steps, internal and external calibration. The internal calibration will combine all different transits of a given source to a common reference internal system producing a 'mean' Gaia observation. This internal calibration accounts for the differential instrumental effects (in sensitivity, aperture, PSF, etc.). They depend on the colour and type of the source. For this reason, a selection of calibration sources ensuring a good representation of all kind of observed sources is needed. The entire magnitude and colour range of the sources have to be covered by these calibration stars and for all calibration intervals. It is a challenge to obtain a suitable colour distribution for the standards, especially for bright sources and the daily large scale calibration intervals. Once the mean Gaia observations are produced, a final step, the external calibration, transforms them to absolute fluxes and wavelengths. In principle, few calibration sources are needed (about 200 spectrophotometric standard stars, SPSS, are currently being considered). They need to have accurate determinations of their absolute fluxes and their non-variability need to be ensured below 1% precision. For this purpose, a big international observational effort is being done (using telescopes as 2.2m@CAHA, TNG@LaPalma, NTT@LaSilla, LaRuca@SPM, and others). During this observational effort some cases of non-expected variability of the SPSS candidates have been discovered.

  9. Electron cyclotron emission spectra in X- and O-mode polarisation at JET: Martin-Puplett interferometer, absolute calibration, revised uncertainties, inboard/outboard temperature profile, and wall properties

    NASA Astrophysics Data System (ADS)

    Schmuck, S.; Fessey, J.; Boom, J. E.; Meneses, L.; Abreu, P.; Belonohy, E.; Lupelli, I.

    2016-09-01

    At the tokamak Joint European Torus (JET), the electron cyclotron emission spectra in O-mode and X-mode polarisations are diagnosed simultaneous in absolute terms for several harmonics with two Martin-Puplett interferometers. From the second harmonic range in X-mode polarisation, the electron temperature profile can be deduced for the outboard side (low magnetic field strength) of JET but only for some parts of the inboard side (high magnetic field strength). This spatial restriction can be bypassed, if a cutoff is not present inside the plasma for O-mode waves in the first harmonic range. Then, from this spectral domain, the profile on the entire inboard side is accessible. The profile determination relies on the new absolute and independent calibration for both interferometers. During the calibration procedure, the antenna pattern was investigated as well, and, potentially, an increase in the diagnostic responsivity of about 5% was found for the domain 100-300 GHz. This increase and other uncertainty sources are taken into account in the thorough revision of the uncertainty for the diagnostic absolute calibration. The uncertainty deduced and the convolution inherent for Fourier spectroscopy diagnostics have implications for the temperature profile inferred. Having probed the electron cyclotron emission spectra in orthogonal polarisation directions for the first harmonic range, a condition is derived for the reflection and polarisation-scrambling coefficients of the first wall on the outboard side of JET.

  10. Simultaneous spectrophotometric determination of Fe(III) and Al(III) using orthogonal signal correction-partial least squares calibration method after solidified floating organic drop microextraction.

    PubMed

    Rohani Moghadam, Masoud; Haji Shabani, Ali Mohammad; Dadfarnia, Shayessteh

    2015-01-25

    A solidified floating organic drop microextraction (SFODME) procedure was developed for the simultaneous extraction and preconcentration of Fe(III) and Al(III) from water samples. The method was based on the formation of cationic complexes between Fe(III) and Al(III) and 3,5,7,2',4'-pentahydroxyflavone (morin) which were extracted into 1-undecanol as ion pairs with perchlorate ions. The absorbance of the extracted complexes was then measured in the wavelength range of 300-450 nm. Finally, the concentration of each metal ion was determined by the use of the orthogonal signal correction-partial least squares (OSC-PLS) calibration method. Several experimental parameters that may be affected on the extraction process such as the type and volume of extraction solvent, pH of the aqueous solution, morin and perchlorate concentration and extraction time were optimized. Under the optimum conditions, Fe(III) and Al(III) were determined in the ranges of 0.83-27.00 μg L(-1) (R(2)=0.9985) and 1.00-32.00 μg L(-1) (R(2)=0.9979) of Fe(III) and Al(III), respectively. The relative standard deviations (n=6) at 12.80 μg L(-1) of Fe(III) and 17.00 μg L(-)(1) of Al(III) were 3.2% and 3.5%, respectively. An enhancement factors of 102 and 96 were obtained for Fe(III) and Al(III) ions, respectively. The procedure was successfully applied to determination of iron and aluminum in steam and water samples of thermal power plant; and the accuracy was assessed through the recovery experiments and independent analysis by electrothermal atomic absorption spectroscopy (ETAAS). PMID:25168229

  11. Simultaneous spectrophotometric determination of Fe(III) and Al(III) using orthogonal signal correction-partial least squares calibration method after solidified floating organic drop microextraction

    NASA Astrophysics Data System (ADS)

    Rohani Moghadam, Masoud; Haji Shabani, Ali Mohammad; Dadfarnia, Shayessteh

    2015-01-01

    A solidified floating organic drop microextraction (SFODME) procedure was developed for the simultaneous extraction and preconcentration of Fe(III) and Al(III) from water samples. The method was based on the formation of cationic complexes between Fe(III) and Al(III) and 3,5,7,2‧,4‧-pentahydroxyflavone (morin) which were extracted into 1-undecanol as ion pairs with perchlorate ions. The absorbance of the extracted complexes was then measured in the wavelength range of 300-450 nm. Finally, the concentration of each metal ion was determined by the use of the orthogonal signal correction-partial least squares (OSC-PLS) calibration method. Several experimental parameters that may be affected on the extraction process such as the type and volume of extraction solvent, pH of the aqueous solution, morin and perchlorate concentration and extraction time were optimized. Under the optimum conditions, Fe(III) and Al(III) were determined in the ranges of 0.83-27.00 μg L-1 (R2 = 0.9985) and 1.00-32.00 μg L-1 (R2 = 0.9979) of Fe(III) and Al(III), respectively. The relative standard deviations (n = 6) at 12.80 μg L-1 of Fe(III) and 17.00 μg L-1 of Al(III) were 3.2% and 3.5%, respectively. An enhancement factors of 102 and 96 were obtained for Fe(III) and Al(III) ions, respectively. The procedure was successfully applied to determination of iron and aluminum in steam and water samples of thermal power plant; and the accuracy was assessed through the recovery experiments and independent analysis by electrothermal atomic absorption spectroscopy (ETAAS).

  12. Detection of 15 dB Squeezed States of Light and their Application for the Absolute Calibration of Photoelectric Quantum Efficiency.

    PubMed

    Vahlbruch, Henning; Mehmet, Moritz; Danzmann, Karsten; Schnabel, Roman

    2016-09-01

    Squeezed states of light belong to the most prominent nonclassical resources. They have compelling applications in metrology, which has been demonstrated by their routine exploitation for improving the sensitivity of a gravitational-wave detector since 2010. Here, we report on the direct measurement of 15 dB squeezed vacuum states of light and their application to calibrate the quantum efficiency of photoelectric detection. The object of calibration is a customized InGaAs positive intrinsic negative (p-i-n) photodiode optimized for high external quantum efficiency. The calibration yields a value of 99.5% with a 0.5% (k=2) uncertainty for a photon flux of the order 10^{17}  s^{-1} at a wavelength of 1064 nm. The calibration neither requires any standard nor knowledge of the incident light power and thus represents a valuable application of squeezed states of light in quantum metrology. PMID:27661673

  13. Detection of 15 dB Squeezed States of Light and their Application for the Absolute Calibration of Photoelectric Quantum Efficiency

    NASA Astrophysics Data System (ADS)

    Vahlbruch, Henning; Mehmet, Moritz; Danzmann, Karsten; Schnabel, Roman

    2016-09-01

    Squeezed states of light belong to the most prominent nonclassical resources. They have compelling applications in metrology, which has been demonstrated by their routine exploitation for improving the sensitivity of a gravitational-wave detector since 2010. Here, we report on the direct measurement of 15 dB squeezed vacuum states of light and their application to calibrate the quantum efficiency of photoelectric detection. The object of calibration is a customized InGaAs positive intrinsic negative (p-i-n) photodiode optimized for high external quantum efficiency. The calibration yields a value of 99.5% with a 0.5% (k =2 ) uncertainty for a photon flux of the order 1 017 s-1 at a wavelength of 1064 nm. The calibration neither requires any standard nor knowledge of the incident light power and thus represents a valuable application of squeezed states of light in quantum metrology.

  14. VizieR Online Data Catalog: Gaia spectrophotometric standard stars I. (Pancino+, 2012)

    NASA Astrophysics Data System (ADS)

    Pancino, E.; Altavilla, G.; Marinoni, S.; Cocozza, G.; Carrasco, J. M.; Bellazzini, M.; Bragaglia, A.; Federici, L.; Rossetti, E.; Cacciari, C.; Balaguer Nunez, L.; Castro, A.; Figueras, F.; Fusi Pecci, F.; Galleti, S.; Gebran, M.; Jordi, C.; Lardo, C.; Masana, E.; Monguio, M.; Montegriffo, P.; Ragaini, S.; Schuster, W.; Trager, S.; Vilardell, F.; Voss, H.

    2013-10-01

    We describe two ground-based observing campaigns aimed at building a grid of approximately 200 spectrophotometric standard stars (SPSS), with an internal =~1% precision and tied to Vega within =~3%, for the absolute flux calibration of data gathered by Gaia, the European Space Agency (ESA) astrometric mission. The criteria for the selection and a list of candidates are presented, together with a description of the survey strategy and the adopted data analysis methods. We also discuss a short list of notable rejected SPSS candidates and difficult cases, based on identification problems, literature discordant data, visual companions and variability. In fact, all candidates are also monitored for constancy (within +/-5mmag, approximately). In particular, we report on a CALSPEC standard, 1740346, that we found to be a δ Scuti variable during our short-term monitoring (1-2h) campaign. (5 data files).

  15. Absolute calibration of the colour index and O4 absorption derived from Multi AXis (MAX-)DOAS measurements and their application to a standardised cloud classification algorithm

    NASA Astrophysics Data System (ADS)

    Wagner, Thomas; Beirle, Steffen; Remmers, Julia; Shaiganfar, Reza; Wang, Yang

    2016-09-01

    A method is developed for the calibration of the colour index (CI) and the O4 absorption derived from differential optical absorption spectroscopy (DOAS) measurements of scattered sunlight. The method is based on the comparison of measurements and radiative transfer simulations for well-defined atmospheric conditions and viewing geometries. Calibrated measurements of the CI and the O4 absorption are important for the detection and classification of clouds from MAX-DOAS observations. Such information is needed for the identification and correction of the cloud influence on Multi AXis (MAX-)DOAS profile inversion results, but might be also be of interest on their own, e.g. for meteorological applications. The calibration algorithm was successfully applied to measurements at two locations: Cabauw in the Netherlands and Wuxi in China. We used CI and O4 observations calibrated by the new method as input for our recently developed cloud classification scheme and also adapted the corresponding threshold values accordingly. For the observations at Cabauw, good agreement is found with the results of the original algorithm. Together with the calibration procedure of the CI and O4 absorption, the cloud classification scheme, which has been tuned to specific locations/conditions so far, can now be applied consistently to MAX-DOAS measurements at different locations. In addition to the new threshold values, further improvements were introduced to the cloud classification algorithm, namely a better description of the SZA (solar zenith angle) dependence of the threshold values and a new set of wavelengths for the determination of the CI. We also indicate specific areas for future research to further improve the cloud classification scheme.

  16. Spectrophotometric Analysis of Caffeine

    PubMed Central

    Ahmad Bhawani, Showkat; Fong, Sim Siong; Mohamad Ibrahim, Mohamad Nasir

    2015-01-01

    The nature of caffeine reveals that it is a bitter white crystalline alkaloid. It is a common ingredient in a variety of drinks (soft and energy drinks) and is also used in combination with various medicines. In order to maintain the optimum level of caffeine, various spectrophotometric methods have been developed. The monitoring of caffeine is very important aspect because of its consumption in higher doses that can lead to various physiological disorders. This paper incorporates various spectrophotometric methods used in the analysis of caffeine in various environmental samples such as pharmaceuticals, soft and energy drinks, tea, and coffee. A range of spectrophotometric methodologies including chemometric techniques and derivatization of spectra have been used to analyse the caffeine. PMID:26604926

  17. Spectrophotometric Analysis of Caffeine.

    PubMed

    Ahmad Bhawani, Showkat; Fong, Sim Siong; Mohamad Ibrahim, Mohamad Nasir

    2015-01-01

    The nature of caffeine reveals that it is a bitter white crystalline alkaloid. It is a common ingredient in a variety of drinks (soft and energy drinks) and is also used in combination with various medicines. In order to maintain the optimum level of caffeine, various spectrophotometric methods have been developed. The monitoring of caffeine is very important aspect because of its consumption in higher doses that can lead to various physiological disorders. This paper incorporates various spectrophotometric methods used in the analysis of caffeine in various environmental samples such as pharmaceuticals, soft and energy drinks, tea, and coffee. A range of spectrophotometric methodologies including chemometric techniques and derivatization of spectra have been used to analyse the caffeine. PMID:26604926

  18. The Gaia spectrophotometric standard stars survey - I. Preliminary results

    NASA Astrophysics Data System (ADS)

    Pancino, E.; Altavilla, G.; Marinoni, S.; Cocozza, G.; Carrasco, J. M.; Bellazzini, M.; Bragaglia, A.; Federici, L.; Rossetti, E.; Cacciari, C.; Balaguer Núñez, L.; Castro, A.; Figueras, F.; Fusi Pecci, F.; Galleti, S.; Gebran, M.; Jordi, C.; Lardo, C.; Masana, E.; Monguió, M.; Montegriffo, P.; Ragaini, S.; Schuster, W.; Trager, S.; Vilardell, F.; Voss, H.

    2012-11-01

    We describe two ground-based observing campaigns aimed at building a grid of approximately 200 spectrophotometric standard stars (SPSS), with an internal ≃1 per cent precision and tied to Vega within ≃3 per cent, for the absolute flux calibration of data gathered by Gaia, the European Space Agency (ESA) astrometric mission. The criteria for the selection and a list of candidates are presented, together with a description of the survey strategy and the adopted data analysis methods. We also discuss a short list of notable rejected SPSS candidates and difficult cases, based on identification problems, literature discordant data, visual companions and variability. In fact, all candidates are also monitored for constancy (within ±5 mmag, approximately). In particular, we report on a CALSPEC standard, 1740346, that we found to be a δ Scuti variable during our short-term monitoring (1-2 h) campaign. Based on data obtained within the Gaia Data Processing and Analysis Consortium (DPAC) - and coordinated by the Ground-based Observations for Gaia (GBOG) working group - at various telescopes; see acknowledgments.

  19. Absolute and relative quantification and calibration for sectioning fluorescence microscopy using standardized uniform fluorescent layers and SIPchart-based correction procedures

    NASA Astrophysics Data System (ADS)

    Zwier, J. M.; Oomen, L.; Brocks, L.; Jalink, K.; Brakenhoff, G. J.

    2007-02-01

    The total or integrated fluorescence intensity of a through-focus series of a thin standardized uniform fluorescent or calibration layer is shown to be suitable for image intensity correction and calibration in sectioning microscopy. This integrated intensity can be derived from the earlier introduced SectionedImagingProperty or SIPcharts, derived from the 3D layer datasets. By correcting the 3D image of an object with the 3D image of the standardized uniform fluorescent layer obtained under identical conditions one is able to express the object fluorescence in units fluorescence of the calibration layer. With object fluorescence intensities in fluorescence layer unit's or FLU's the object image intensities becomes independent of microscope system and imaging conditions. A direct result is that the often-appreciable lateral intensity variations present in confocal microscopy are eliminated (shading correction). Of more general value is that images obtained with different objectives, magnifications or from different microscope systems can be quantitatively related to each other. The effectiveness of shading correction and relating images obtained under various microscope conditions is demonstrated on images of standard fluorocent beads. Expressing the object fluorescence in FLU units seems to be a promising approach for general quantification of sectioning imaging enabling cross-correlation of imaging results over time and between imaging systems.

  20. Absolute Energy Calibration with the Neutron-Activated Liquid-Source System at BaBar's CsI(Tl) Calorimeter

    SciTech Connect

    Bauer, J

    2004-01-05

    The electro-magnetic calorimeter at the BABAR detector, part of the asymmetric B Factory at SLAC, measures photons in the energy range from 20 MeV to 8 GeV with good resolution. The calorimeter is calibrated at the low energy end with 6.13 MeV photons obtained from a liquid source system. During the calibration, a fluorine-rich liquid is activated via a neutron generator and pumped past the front of the calorimeter's crystals. Decays that occur in front of the crystals emit photons of well-defined energy, which are detected in the crystals with the regular data acquisition system. The liquid source system adds only very little material in front of the calorimeter, needs nearly no maintenance, and allows operation at the switch of a key with minimal safety hazards. The report describes the system, presents calibration results obtained from its operation since 1999, shows the crystals' loss of light yield due to radiation damage, and shares experiences gained over the years.

  1. Absolute vicarious calibration of Landsat-8 OLI and Resourcesat-2 AWiFS sensors over Rann of Kutch site in Gujarat

    NASA Astrophysics Data System (ADS)

    Sharma, Shweta; Sridhar, V. N.; Prajapati, R. P.; Rao, K. M.; Mathur, A. K.

    2016-05-01

    In this work, vicarious calibration coefficients for all the four bands (green, red, NIR and SWIR) of Resourcesat-2 AWiFS sensor for four dates during Dec 2013-Nov 2014 and for seven bands (blue, green, red, NIR, SWIR1, SWIR2 and PAN) of OLI sensor onboard Landsat-8 for six dates during Dec 2013-Feb 2015 were estimated using field measured reflectance and measured atmospheric parameters during sensor image acquisition over Rann of Kutch site in Gujarat. The top of atmosphere (TOA) at-satellite radiances for all the bands were simulated using 6S radiative transfer code with field measured reflectance, synchronous atmospheric measurements and respective sensor's spectral response functions as an input. These predicted spectral radiances were compared with the radiances from the respective sensor's image in the respective band over the calibration site. Cross-calibration between the sensors AWiFS and OLI was also attempted using near-simultaneous same day image acquisition. Effect of spectral band adjustment factor was also studied with OLI sensor taken as reference sensor. Results show that the variation in average estimated radiance ratio for the AWiFS sensor was found to be within 10% for all the bands, whereas, for OLI sensor, the variation was found to be within 6% for all the bands except green and SWIR2 for which the variation was 8% and 11% respectively higher than the 5% uncertainty of the OLI sensor specification for TOA spectral radiance. At the 1σ level, red, NIR, SWIR1 and Panchromatic bands of OLI sensor showed close agreement between sensor-measured and vicarious TOA radiance resulting no change in calibration coefficient and hence indicating no sensor degradation. Two sets of near-simultaneous SBAFs were derived from respective ground measured target reflectance profiles and applied to the AWiFS and it was observed that overall, SBAF compensation provides a significant improvement in sensor agreement. The reduction in the difference between AWiFS and

  2. Absolute Energy Calibration of X-ray TESs with 0.04 eV Uncertainty at 6.4 keV in a Hadron-Beam Environment

    NASA Astrophysics Data System (ADS)

    Tatsuno, H.; Doriese, W. B.; Bennett, D. A.; Curceanu, C.; Fowler, J. W.; Gard, J.; Gustafsson, F. P.; Hashimoto, T.; Hayano, R. S.; Hays-Wehle, J. P.; Hilton, G. C.; Iliescu, M.; Ishimoto, S.; Itahashi, K.; Iwasaki, M.; Kuwabara, K.; Ma, Y.; Marton, J.; Noda, H.; O'Neil, G. C.; Okada, S.; Outa, H.; Reintsema, C. D.; Sato, M.; Schmidt, D. R.; Shi, H.; Suzuki, K.; Suzuki, T.; Uhlig, J.; Ullom, J. N.; Widmann, E.; Yamada, S.; Zmeskal, J.; Swetz, D. S.

    2016-08-01

    A performance evaluation of superconducting transition-edge sensors (TESs) in the environment of a pion beam line at a particle accelerator is presented. Averaged across the 209 functioning sensors in the array, the achieved energy resolution is 5.2 eV FWHM at Co K_{α } (6.9 keV) when the pion beam is off and 7.3 eV at a beam rate of 1.45 MHz. Absolute energy uncertainty of ± 0.04 eV is demonstrated for Fe K_{α } (6.4 keV) with in-situ energy calibration obtained from other nearby known X-ray lines. To achieve this small uncertainty, it is essential to consider the non-Gaussian energy response of the TESs and thermal cross-talk pile-up effects due to charged particle hits in the silicon substrate of the TES array.

  3. Calibration of diffuse correlation spectroscopy with a time-resolved near-infrared technique to yield absolute cerebral blood flow measurements

    PubMed Central

    Diop, Mamadou; Verdecchia, Kyle; Lee, Ting-Yim; St Lawrence, Keith

    2011-01-01

    A primary focus of neurointensive care is the prevention of secondary brain injury, mainly caused by ischemia. A noninvasive bedside technique for continuous monitoring of cerebral blood flow (CBF) could improve patient management by detecting ischemia before brain injury occurs. A promising technique for this purpose is diffuse correlation spectroscopy (DCS) since it can continuously monitor relative perfusion changes in deep tissue. In this study, DCS was combined with a time-resolved near-infrared technique (TR-NIR) that can directly measure CBF using indocyanine green as a flow tracer. With this combination, the TR-NIR technique can be used to convert DCS data into absolute CBF measurements. The agreement between the two techniques was assessed by concurrent measurements of CBF changes in piglets. A strong correlation between CBF changes measured by TR-NIR and changes in the scaled diffusion coefficient measured by DCS was observed (R2 = 0.93) with a slope of 1.05 ± 0.06 and an intercept of 6.4 ± 4.3% (mean ± standard error). PMID:21750781

  4. Absolute Summ

    NASA Astrophysics Data System (ADS)

    Phillips, Alfred, Jr.

    Summ means the entirety of the multiverse. It seems clear, from the inflation theories of A. Guth and others, that the creation of many universes is plausible. We argue that Absolute cosmological ideas, not unlike those of I. Newton, may be consistent with dynamic multiverse creations. As suggested in W. Heisenberg's uncertainty principle, and with the Anthropic Principle defended by S. Hawking, et al., human consciousness, buttressed by findings of neuroscience, may have to be considered in our models. Predictability, as A. Einstein realized with Invariants and General Relativity, may be required for new ideas to be part of physics. We present here a two postulate model geared to an Absolute Summ. The seedbed of this work is part of Akhnaton's philosophy (see S. Freud, Moses and Monotheism). Most important, however, is that the structure of human consciousness, manifest in Kenya's Rift Valley 200,000 years ago as Homo sapiens, who were the culmination of the six million year co-creation process of Hominins and Nature in Africa, allows us to do the physics that we do. .

  5. Polymerization Evaluation by Spectrophotometric Measurements.

    ERIC Educational Resources Information Center

    Dunach, Jaume

    1985-01-01

    Discusses polymerization evaluation by spectrophotometric measurements by considering: (1) association degrees and molar absorptivities; (2) association degrees and equilibrium constants; and (3) absorbance and equilibrium constants. (JN)

  6. Satellite-mounted Light Source as Photometric Calibration Standards

    NASA Astrophysics Data System (ADS)

    Albert, J.; Burgett, W.; Rhodes, J.; Battat, J.

    At AMOS 2006 we proposed a tunable laser-based satellite-mounted spectrophotometric and absolute flux calibration system, to be utilized by ground- and space-based telescopes, for precision calibration of ground-based telescope photometry and flux. Since then, we have performed a campaign of observations of the 532 nm pulsed laser aboard the CALIPSO satellite (launched Apr. 2006), using a portable network of cameras and NIST-calibrated photodiodes, to test the precision of this method of measuring atmospheric extinction. This technique has astrophysical applications including reducing a major systematic uncertainty (absolute photometry) on cosmological parameter measurement using type Ia supernovae, as well as in upcoming photometric red shift surveys measuring growth of large scale structure in the Universe. In addition, upcoming systems potentially have broad utility for defense and national security applications such as ground target illumination and space communication. We will report on our measurements using our observations of the CALIPSO laser, and discuss future directions and applications. For further details please see http://www.arxiv.org/abs/astro-ph/0604339 and http://www8.nationalacademies.org/astro2010/DetailFileDisplay.aspx?id=546.

  7. Spectrophotometric discrimination of river dissolved organic matter

    NASA Astrophysics Data System (ADS)

    Baker, Andy

    2002-11-01

    There is a need to be able to differentiate the dissolved organic matter (DOM) fraction in river waters. Research in the 1970s and 1980s has attempted to utilize both absorbance and fluorescence to distinguish between DOM fractions in river waters, but both were limited by the available technology. Total organic carbon content has, therefore, been widely used as a standard method of measuring DOM concentration, although it has little power to differentiate DOM fractions. Recent advances in fluorescence spectrophotometry enable rapid and optically precise analysis of DOM. Here, we show how a combination of both fluorescence and absorbance can be used to discriminate statistically between spatial variations of DOM in tributaries in a small catchment of the Ouseburn, NE England. The results of the discriminant analysis suggest that about 70% of the samples can be correctly classified to its tributary. Discriminant function 1 explains 60·8% of the variance in the data and the fulvic-like fluorescence intensity has the largest absolute correlation within this function; discriminant function 2 explains a further 21·5% of the variance and the fulvic-like fluorescence emission wavelength has the largest absolute correlation within this function. The discriminant analysis does not correctly classify all tributaries every time, and successfully discriminates between the different tributaries 70% of the time. Occasions when the tributary waters are less well discriminated are due to either episodic pollution events (at two sites) or due to tributaries that have strong seasonal trends in spectrophotometric parameters, which allows the sites to be misclassified. Results suggest that spectrophotometric techniques have considerable potential in the discrimination of DOM in rivers.

  8. Spectrophotometric determination of the fungicide captan.

    PubMed

    Galeano, Teresa; Guiberteau, Agustina; Mora, Nielene M; Alvarez, Pedro R; Salinas, Francisco

    2002-11-01

    A spectrophotometric method for the determination of the fungicide captan has been developed based on its reaction with thiosemicarbazide. The absorbance was measured at 315 nm. The effects of the proportion of water, thiosemicarbazide concentration, pH and temperature on this reaction was studied to select the best chemical conditions. The calibration graph was obtained between 1.2 and 30 ppm and the detection limit is 0.5 ppm. The RSD (n = 10) was 1.34%. Possible interference of various pesticides was examined. The method was applied to the determination of captan in agrochemical formulations. Results agree well with the labelled values and also with results that were obtained by a polarographic method.

  9. Novel spectrophotometric determination of flumethasone pivalate and clioquinol in their binary mixture and pharmaceutical formulation.

    PubMed

    Abdel-Aleem, Eglal A; Hegazy, Maha A; Sayed, Nour W; Abdelkawy, M; Abdelfatah, Rehab M

    2015-02-01

    This work is concerned with development and validation of three simple, specific, accurate and precise spectrophotometric methods for determination of flumethasone pivalate (FP) and clioquinol (CL) in their binary mixture and ear drops. Method A is a ratio subtraction spectrophotometric one (RSM). Method B is a ratio difference spectrophotometric one (RDSM), while method C is a mean center spectrophotometric one (MCR). The calibration curves are linear over the concentration range of 3-45 μg/mL for FP, and 2-25 μg/mL for CL. The specificity of the developed methods was assessed by analyzing different laboratory prepared mixtures of the FP and CL. The three methods were validated as per ICH guidelines; accuracy, precision and repeatability are found to be within the acceptable limits.

  10. Teaching Absolute Value Meaningfully

    ERIC Educational Resources Information Center

    Wade, Angela

    2012-01-01

    What is the meaning of absolute value? And why do teachers teach students how to solve absolute value equations? Absolute value is a concept introduced in first-year algebra and then reinforced in later courses. Various authors have suggested instructional methods for teaching absolute value to high school students (Wei 2005; Stallings-Roberts…

  11. Improved dewpoint-probe calibration

    NASA Technical Reports Server (NTRS)

    Stephenson, J. G.; Theodore, E. A.

    1978-01-01

    Relatively-simple pressure-control apparatus calibrates dewpoint probes considerably faster than conventional methods, with no loss of accuracy. Technique requires only pressure measurement at each calibration point and single absolute-humidity measurement at beginning of run. Several probes can be calibrated simultaneously and points can be checked above room temperature.

  12. The Flux Calibration of Gaia

    NASA Astrophysics Data System (ADS)

    Pancino, E.

    2016-05-01

    The Gaia mission is described, along with its scientific potential and its updated science perfomances. Although it is often described as a self-calibrated mission, Gaia still needs to tie part of its measurements to external scales (or to convert them in physical units). A detailed decription of the Gaia spectro-photometric standard stars survey is provided, along with a short description of the Gaia calibration model. The model requires a grid of approximately 200 stars, calibrated to a few percent with respect to Vega, and covering different spectral types.

  13. How Much Cranberry Juice Is in Cranberry-Apple Juice? A General Chemistry Spectrophotometric Experiment

    ERIC Educational Resources Information Center

    Edionwe, Etinosa; Villarreal, John R.; Smith, K. Christopher

    2011-01-01

    A laboratory experiment that spectrophotometrically determines the percent of cranberry juice in cranberry-apple juice is described. The experiment involves recording an absorption spectrum of cranberry juice to determine the wavelength of maximum absorption, generating a calibration curve, and measuring the absorbance of cranberry-apple juice.…

  14. Eosinophil count - absolute

    MedlinePlus

    Eosinophils; Absolute eosinophil count ... the white blood cell count to give the absolute eosinophil count. ... than 500 cells per microliter (cells/mcL). Normal value ranges may vary slightly among different laboratories. Talk ...

  15. The Science of Calibration

    NASA Astrophysics Data System (ADS)

    Kent, S. M.

    2016-05-01

    This paper presents a broad overview of the many issues involved in calibrating astronomical data, covering the full electromagnetic spectrum from radio waves to gamma rays, and considering both ground-based and space-based missions. These issues include the science drivers for absolute and relative calibration, the physics behind calibration and the mechanisms used to transfer it from the laboratory to an astronomical source, the need for networks of calibrated astronomical standards, and some of the challenges faced by large surveys and missions.

  16. Enzymic method for the spectrophotometric determination of aspartame in beverages.

    PubMed

    Hamano, T; Mitsuhashi, Y; Aoki, N; Yamamoto, S; Tsuji, S; Ito, Y; Oji, Y

    1990-04-01

    A sensitive spectrophotometric method for the determination of aspartame in beverages is described. The method involves the enzymic conversion of aspartame into formaldehyde by the alpha-chymotrypsin-alcohol oxidase system, followed by the formation of a chromophore with 4-aminopent-3-en-2-one. The calibration graph was linear in the range 2.0-30.0 micrograms ml-1 of aspartame. Many common ingredients of beverages do not interfere with the proposed method. The method was applied to the determination of the aspartame content of various real samples, and the results obtained were compared with those given by high-performance liquid chromatography.

  17. Spectrophotometric analysis of irradiated spices.

    PubMed

    Josimović, L; Cudina, I

    1987-01-01

    Seven different spices (thyme, cinnamon, coriander, caraway, pimento, paprika, black pepper) were treated by gamma radiation at an absorbed dose of 10 kGy, and the effect on chemical quality was determined. The effects of this dose were assessed by spectrophotometric analysis of some water-soluble constituents of spices (carbohydrates; carbonyl compounds) and on the content of water-insoluble steam-volatile oils. The colour of paprika and the content of piperine in pepper held in different packaging materials were measured in unirradiated and irradiated samples as a function of storage time. In all cases irradiation does not bring about any distinct qualitative or quantitative chemical changes based on spectrophotometric analysis of spice extracts.

  18. Extractive spectrophotometric methods for determination of lercanidipine.

    PubMed

    Erk, Nevin

    2003-11-01

    Extractive spectrophotometric methods are described for the determination of lercanidipine (LER) either in pure form or in pharmaceutical formulations. The methods involve formation of coloured chloroform extractable ion-pair complexes with bromothymol blue (BTB) and bromocresol green (BCG) in acidic medium. The extracted complexes showed absorbance maxima at 417 and 416 nm for BTB and BCG, respectively. The optimization of the reaction conditions was investigated. Beer's law is obeyed in the concentration ranges 6.0-42.0 microg x ml(-1) or 7.1-43.8 microg x ml(-1) with BTB or BCG, respectively. The composition of the ion-pairs was found to be 1:1 by Job's method. The specific absorptivities, molar absorptivities, Sandell sensitivities, standard deviations and percent recoveries were evaluated. Also, LER was determined by measurement of its first derivative signals at 245 nm. Calibration graph was established for 4.2-58.0 microg x ml(-1) of LER. The methods have been applied to the determination of drug in commercial tablets. Results of analysis were validated. No interferences were observed from common pharmaceutical adjuvants.

  19. Absolute nuclear material assay

    DOEpatents

    Prasad, Manoj K.; Snyderman, Neal J.; Rowland, Mark S.

    2012-05-15

    A method of absolute nuclear material assay of an unknown source comprising counting neutrons from the unknown source and providing an absolute nuclear material assay utilizing a model to optimally compare to the measured count distributions. In one embodiment, the step of providing an absolute nuclear material assay comprises utilizing a random sampling of analytically computed fission chain distributions to generate a continuous time-evolving sequence of event-counts by spreading the fission chain distribution in time.

  20. Absolute nuclear material assay

    DOEpatents

    Prasad, Manoj K.; Snyderman, Neal J.; Rowland, Mark S.

    2010-07-13

    A method of absolute nuclear material assay of an unknown source comprising counting neutrons from the unknown source and providing an absolute nuclear material assay utilizing a model to optimally compare to the measured count distributions. In one embodiment, the step of providing an absolute nuclear material assay comprises utilizing a random sampling of analytically computed fission chain distributions to generate a continuous time-evolving sequence of event-counts by spreading the fission chain distribution in time.

  1. In situ spectrophotometric measurement of dissolved inorganic carbon in seawater

    USGS Publications Warehouse

    Liua, Xuewu; Byrne, Robert H.; Adornato, Lori; Yates, Kimberly K.; Kaltenbacher, Eric; Ding, Xiaoling; Yang, Bo

    2013-01-01

    Autonomous in situ sensors are needed to document the effects of today’s rapid ocean uptake of atmospheric carbon dioxide (e.g., ocean acidification). General environmental conditions (e.g., biofouling, turbidity) and carbon-specific conditions (e.g., wide diel variations) present significant challenges to acquiring long-term measurements of dissolved inorganic carbon (DIC) with satisfactory accuracy and resolution. SEAS-DIC is a new in situ instrument designed to provide calibrated, high-frequency, long-term measurements of DIC in marine and fresh waters. Sample water is first acidified to convert all DIC to carbon dioxide (CO2). The sample and a known reagent solution are then equilibrated across a gas-permeable membrane. Spectrophotometric measurement of reagent pH can thereby determine the sample DIC over a wide dynamic range, with inherent calibration provided by the pH indicator’s molecular characteristics. Field trials indicate that SEAS-DIC performs well in biofouling and turbid waters, with a DIC accuracy and precision of ∼2 μmol kg–1 and a measurement rate of approximately once per minute. The acidic reagent protects the sensor cell from biofouling, and the gas-permeable membrane excludes particulates from the optical path. This instrument, the first spectrophotometric system capable of automated in situ DIC measurements, positions DIC to become a key parameter for in situ CO2-system characterizations.

  2. In situ spectrophotometric measurement of dissolved inorganic carbon in seawater.

    PubMed

    Liu, Xuewu; Byrne, Robert H; Adornato, Lori; Yates, Kimberly K; Kaltenbacher, Eric; Ding, Xiaoling; Yang, Bo

    2013-10-01

    Autonomous in situ sensors are needed to document the effects of today's rapid ocean uptake of atmospheric carbon dioxide (e.g., ocean acidification). General environmental conditions (e.g., biofouling, turbidity) and carbon-specific conditions (e.g., wide diel variations) present significant challenges to acquiring long-term measurements of dissolved inorganic carbon (DIC) with satisfactory accuracy and resolution. SEAS-DIC is a new in situ instrument designed to provide calibrated, high-frequency, long-term measurements of DIC in marine and fresh waters. Sample water is first acidified to convert all DIC to carbon dioxide (CO2). The sample and a known reagent solution are then equilibrated across a gas-permeable membrane. Spectrophotometric measurement of reagent pH can thereby determine the sample DIC over a wide dynamic range, with inherent calibration provided by the pH indicator's molecular characteristics. Field trials indicate that SEAS-DIC performs well in biofouling and turbid waters, with a DIC accuracy and precision of ∼2 μmol kg(-1) and a measurement rate of approximately once per minute. The acidic reagent protects the sensor cell from biofouling, and the gas-permeable membrane excludes particulates from the optical path. This instrument, the first spectrophotometric system capable of automated in situ DIC measurements, positions DIC to become a key parameter for in situ CO2-system characterizations.

  3. Software For Calibration Of Polarimetric SAR Data

    NASA Technical Reports Server (NTRS)

    Van Zyl, Jakob; Zebker, Howard; Freeman, Anthony; Holt, John; Dubois, Pascale; Chapman, Bruce

    1994-01-01

    POLCAL (Polarimetric Radar Calibration) software tool intended to assist in calibration of synthetic-aperture radar (SAR) systems. In particular, calibrates Stokes-matrix-format data produced as standard product by NASA/Jet Propulsion Laboratory (JPL) airborne imaging synthetic aperture radar (AIRSAR). Version 4.0 of POLCAL is upgrade of version 2.0. New options include automatic absolute calibration of 89/90 data, distributed-target analysis, calibration of nearby scenes with corner reflectors, altitude or roll-angle corrections, and calibration of errors introduced by known topography. Reduces crosstalk and corrects phase calibration without use of ground calibration equipment. Written in FORTRAN 77.

  4. Absolute biological needs.

    PubMed

    McLeod, Stephen

    2014-07-01

    Absolute needs (as against instrumental needs) are independent of the ends, goals and purposes of personal agents. Against the view that the only needs are instrumental needs, David Wiggins and Garrett Thomson have defended absolute needs on the grounds that the verb 'need' has instrumental and absolute senses. While remaining neutral about it, this article does not adopt that approach. Instead, it suggests that there are absolute biological needs. The absolute nature of these needs is defended by appeal to: their objectivity (as against mind-dependence); the universality of the phenomenon of needing across the plant and animal kingdoms; the impossibility that biological needs depend wholly upon the exercise of the abilities characteristic of personal agency; the contention that the possession of biological needs is prior to the possession of the abilities characteristic of personal agency. Finally, three philosophical usages of 'normative' are distinguished. On two of these, to describe a phenomenon or claim as 'normative' is to describe it as value-dependent. A description of a phenomenon or claim as 'normative' in the third sense does not entail such value-dependency, though it leaves open the possibility that value depends upon the phenomenon or upon the truth of the claim. It is argued that while survival needs (or claims about them) may well be normative in this third sense, they are normative in neither of the first two. Thus, the idea of absolute need is not inherently normative in either of the first two senses. PMID:23586876

  5. Absolute biological needs.

    PubMed

    McLeod, Stephen

    2014-07-01

    Absolute needs (as against instrumental needs) are independent of the ends, goals and purposes of personal agents. Against the view that the only needs are instrumental needs, David Wiggins and Garrett Thomson have defended absolute needs on the grounds that the verb 'need' has instrumental and absolute senses. While remaining neutral about it, this article does not adopt that approach. Instead, it suggests that there are absolute biological needs. The absolute nature of these needs is defended by appeal to: their objectivity (as against mind-dependence); the universality of the phenomenon of needing across the plant and animal kingdoms; the impossibility that biological needs depend wholly upon the exercise of the abilities characteristic of personal agency; the contention that the possession of biological needs is prior to the possession of the abilities characteristic of personal agency. Finally, three philosophical usages of 'normative' are distinguished. On two of these, to describe a phenomenon or claim as 'normative' is to describe it as value-dependent. A description of a phenomenon or claim as 'normative' in the third sense does not entail such value-dependency, though it leaves open the possibility that value depends upon the phenomenon or upon the truth of the claim. It is argued that while survival needs (or claims about them) may well be normative in this third sense, they are normative in neither of the first two. Thus, the idea of absolute need is not inherently normative in either of the first two senses.

  6. Application of the bivariate spectrophotometric method for the determination of metronidazole, furazolidone and di-iodohydroxyquinoline in pharmaceutical formulations.

    PubMed

    López-de-Alba, P L; Wróbel, K; López-Martínez, L; Wróbel, K; Yepez-Murrieta, M L; Amador-Hernández, J

    1997-10-01

    The bivariate calibration algorithm was applied to the spectrophotometric determination of metronidazole, furazolidone and di-iodohydroxyquinoline in pharmaceutical dosage forms. The results obtained were compared with the results of derivative spectrophotometry. The statistical evaluation of method bias was carried out, and it was shown that the proposed procedure may be competitive with commonly used first-derivative spectrophotometry. The advantage of the bivariate calibration is its simplicity, and the fact that there is no need to use the derivatization procedures.

  7. Photometric calibration of the International Ultraviolet Explorer /IUE/ - Low dispersion

    NASA Technical Reports Server (NTRS)

    Bohlin, R. C.; Sparks, W. M.; Holm, A. V.; Savage, B. D.; Snijders, M. A. J.

    1980-01-01

    Absolute sensitivity curves for IUE low-resolution spectra are obtained by comparing IUE measurements of hot stars with the absolute energy distributions established for these objects by previous satellite and rocket experiments. The differences between these earlier experiments are discussed quantitatively, and a common absolute flux scale is proposed as the basis for the absolute calibration of IUE.

  8. Mid-infrared absolute spectral responsivity scale based on an absolute cryogenic radiometer and an optical parametric oscillator laser

    NASA Astrophysics Data System (ADS)

    Zhao, Kun; Shi, Xueshun; Chen, Haidong; Liu, Yulong; Liu, Changming; Chen, Kunfeng; Li, Ligong; Gan, Haiyong; Ma, Chong

    2016-06-01

    We are reporting on a laser-based absolute spectral responsivity scale in the mid-infrared spectral range. By using a mid-infrared tunable optical parametric oscillator as the laser source, the absolute responsivity scale has been established by calibrating thin-film thermopile detectors against an absolute cryogenic radiometer. The thin-film thermopile detectors can be then used as transfer standard detectors. The extended uncertainty of the absolute spectral responsivity measurement has been analyzed to be 0.58%–0.68% (k  =  2).

  9. Mid-infrared absolute spectral responsivity scale based on an absolute cryogenic radiometer and an optical parametric oscillator laser

    NASA Astrophysics Data System (ADS)

    Zhao, Kun; Shi, Xueshun; Chen, Haidong; Liu, Yulong; Liu, Changming; Chen, Kunfeng; Li, Ligong; Gan, Haiyong; Ma, Chong

    2016-06-01

    We are reporting on a laser-based absolute spectral responsivity scale in the mid-infrared spectral range. By using a mid-infrared tunable optical parametric oscillator as the laser source, the absolute responsivity scale has been established by calibrating thin-film thermopile detectors against an absolute cryogenic radiometer. The thin-film thermopile detectors can be then used as transfer standard detectors. The extended uncertainty of the absolute spectral responsivity measurement has been analyzed to be 0.58%-0.68% (k  =  2).

  10. A rapid spectrophotometric determination of persulfate anion in ISCO.

    PubMed

    Liang, Chenju; Huang, Chiu-Fen; Mohanty, Nihar; Kurakalva, Rama Mohan

    2008-11-01

    Due to a gradual increase in the use of persulfate as an in situ chemical oxidation (ISCO) oxidant, a simple measurement of persulfate concentration is desirable to analyze persulfate distribution at designated time intervals on/off a site. Such a distribution helps evaluate efficacy of ISCO treatment at a site. This work proposes a spectrophotometric determination of persulfate based on modification of the iodometric titration method. The analysis of absorption spectra of a yellow color solution resulting from the reaction of persulfate and iodide in the presence of sodium bicarbonate reveals an absorbance at 352 nm, without significant interferences from the reagent matrix. The calibration graph was linear in the range of persulfate solution concentration of 0-70 mM at 352 nm. The proposed method is validated by the iodometric titration method. The solution pH was at near neutral and the presence of iron activator does not interfere with the absorption measurement. Also, analysis of persulfate in a groundwater sample using the proposed method indicates a good agreement with measurements by the titration method. This proposed spectrophotometric quantification of persulfate provides a simple and rapid method for evaluation of ISCO effectiveness at a remediation site.

  11. The absolute path command

    2012-05-11

    The ap command traveres all symlinks in a given file, directory, or executable name to identify the final absolute path. It can print just the final path, each intermediate link along with the symlink chan, and the permissions and ownership of each directory component in the final path. It has functionality similar to "which", except that it shows the final path instead of the first path. It is also similar to "pwd", but it canmore » provide the absolute path to a relative directory from the current working directory.« less

  12. The absolute path command

    SciTech Connect

    Moody, A.

    2012-05-11

    The ap command traveres all symlinks in a given file, directory, or executable name to identify the final absolute path. It can print just the final path, each intermediate link along with the symlink chan, and the permissions and ownership of each directory component in the final path. It has functionality similar to "which", except that it shows the final path instead of the first path. It is also similar to "pwd", but it can provide the absolute path to a relative directory from the current working directory.

  13. Extension of the absolute flux density scale to 22.285 GHz. [radio astronomy

    NASA Technical Reports Server (NTRS)

    Janssen, M. A.; Golden, L. M.; Welch, W. J.

    1974-01-01

    Extending the absolute flux density scale at microwave wavelengths, the absolute flux densities at 22.285 GHz of several standard sources were determined using the absolute calibrations of the 6.1 meter antenna of the Hat Creek Observatory. Interpolation formulas for each nonthermal standard source have been derived by combining these data with those determined at lower frequencies. The suitability of employing the standard sources for calibrating other antennas is discussed.

  14. Spectrophotometric multicomponent analysis applied to trace metal determinations

    SciTech Connect

    Otto, M.; Wegscheider, W.

    1985-01-01

    Quantitative spectrometric analysis of mixture components is featured for systems with low spectral selectivity, namely, in the ultraviolet, visible, and infrared spectral range. Limitations imposed by data reduction schemes based on ordinary multiple regression are shown to be overcome by means of partial least-squares analysis in latent variables. The influences of variables such as noise, band separation band intensity ratios, number of wavelengths, number of components, number of calibration mixtures, time drift, or deviations from Beer's law on the analytical result has been evaluated under a wide range of conditions providing a basis to search for new systems applicable to spectrophotometric multicomponent analysis. The practical utility of the method is demonstrated for simultaneous analysis of copper, nickel, cobalt, iron, and palladium down to 2 X 10/sup -6/ M concentrations by use of their diethyldithiocarbamate chelate complexes with relative errors less than 6%. 26 references, 4 figures, 6 tables.

  15. Spectrophotometric observations of symbiotic stars and related objects

    NASA Technical Reports Server (NTRS)

    Blair, W. P.; Feibelman, W. A.; Michalitsianos, A. G.; Stencel, R. E.

    1983-01-01

    Calibrated optical spectrophotometric observations of 16 symbiotic and symbiotic-like objects are presented. The objects observed include Z And, T CrB, CH Cyg, CI Cyg, V1016 Cyg, V1329 Cyg, AG Dra, YY Her, RS Oph, XX Oph, AG Peg, AX Per, CL Sco, HM Sge, AS 289, and M1-2. Integrated emission-line intensities are tabulated for comparison with ultraviolet and infrared data, as well as with previous optical studies. The reddening to each of the objects is derived by assuming that Balmer lines are emitted in their case B recombination ratios. However, the values so derived are often systematically higher than reddening estimates from the ultraviolet 2200 A feature. Comparisons with the available data from other wavelength ranges are noted.

  16. Summary of OARE flight calibration measurements

    NASA Astrophysics Data System (ADS)

    Blanchard, Robert C.; Nicholson, John Y.

    1995-01-01

    To date, the Orbital Acceleration Research Experiment (OARE) has flown on the shuttle orbiter for five missions; namely, STS-40, STS-50, STS-58, STS-62, and STS-65. The OARE instrument system contains a three-axis accelerometer which can resolve accelerations to the nano-g (10(exp -9) g) level and a full calibration station to permit in situ bias and scale factor calibration measurements. This calibration capability eliminates the large uncertainty encountered with accelerometers flown in the past on the orbiter which use ground-based calibrations to provide absolute acceleration measurements. A detailed flight data report presentation is given for the OARE calibration measurements from all missions, along with an estimate of the calibration errors. The main aim is to collect, process, and present the calibration data in one archival report. These calibration data are the necessary key ingredient to produce the absolute acceleration levels from the OARE acceleration flight data.

  17. Variable path length spectrophotometric probe

    DOEpatents

    O'Rourke, Patrick E.; McCarty, Jerry E.; Haggard, Ricky A.

    1992-01-01

    A compact, variable pathlength, fiber optic probe for spectrophotometric measurements of fluids in situ. The probe comprises a probe body with a shaft having a polished end penetrating one side of the probe, a pair of optic fibers, parallel and coterminous, entering the probe opposite the reflecting shaft, and a collimating lens to direct light from one of the fibers to the reflecting surface of the shaft and to direct the reflected light to the second optic fiber. The probe body has an inlet and an outlet port to allow the liquid to enter the probe body and pass between the lens and the reflecting surface of the shaft. A linear stepper motor is connected to the shaft to cause the shaft to advance toward or away from the lens in increments so that absorption measurements can be made at each of the incremental steps. The shaft is sealed to the probe body by a bellows seal to allow freedom of movement of the shaft and yet avoid leakage from the interior of the probe.

  18. Strategy for the absolute neutron emission measurement on ITER.

    PubMed

    Sasao, M; Bertalot, L; Ishikawa, M; Popovichev, S

    2010-10-01

    Accuracy of 10% is demanded to the absolute fusion measurement on ITER. To achieve this accuracy, a functional combination of several types of neutron measurement subsystem, cross calibration among them, and in situ calibration are needed. Neutron transport calculation shows the suitable calibration source is a DT/DD neutron generator of source strength higher than 10(10) n/s (neutron/second) for DT and 10(8) n/s for DD. It will take eight weeks at the minimum with this source to calibrate flux monitors, profile monitors, and the activation system.

  19. Strategy for the absolute neutron emission measurement on ITER

    SciTech Connect

    Sasao, M.; Bertalot, L.; Ishikawa, M.; Popovichev, S.

    2010-10-15

    Accuracy of 10% is demanded to the absolute fusion measurement on ITER. To achieve this accuracy, a functional combination of several types of neutron measurement subsystem, cross calibration among them, and in situ calibration are needed. Neutron transport calculation shows the suitable calibration source is a DT/DD neutron generator of source strength higher than 10{sup 10} n/s (neutron/second) for DT and 10{sup 8} n/s for DD. It will take eight weeks at the minimum with this source to calibrate flux monitors, profile monitors, and the activation system.

  20. Another Technique For Calibration Of Polarimetric Radar

    NASA Technical Reports Server (NTRS)

    Van Zyl, Jakob J.

    1992-01-01

    Inexpensive technique involves four-stage procedure where different aspects of radar system calibrated at each stage. Provides calibration of relative phase, crosstalk, relative amplitude, and absolute amplitude. Only artificial target(s) required is at least one trihedral corner reflector. Advantage of four-step calibration procedure is that one does not have to perform entire procedure if one does not need full calibration.

  1. Enzymatic determination of vitamin A in pharmaceutical formulations with spectrophotometric detection

    NASA Astrophysics Data System (ADS)

    Rishi, Lubna; Asgher, Mohammad; Yaqoob, Mohammad; Waseem, Amir; Nabi, Abdul

    2009-06-01

    An enzymatic method for the determination vitamin A (retinol) is reported using soluble and immobilized alcohol dehydrogenase, isolated from rabbit liver. The reaction is based on the oxidation of retinol and simultaneous reduction of NAD + to NADH followed by spectrophotometric detection at 340 nm. The calibration graph was linear over the range of 2.0-10 μM with correlation coefficients of 0.9967 and 0.9992 ( n = 5) for soluble and immobilized alcohol dehydrogenase respectively, with relative standard deviations ( n = 3) in the range of 0.5-1.2%. The limit of detection was lower than 1.0 μM. The proposed method was applied to determine vitamin A in pharmaceuticals, and the results obtained were in reasonable agreement with the amount labeled. The results were compared using spectrophotometric reference method, and no significant difference was found between the results of the both methods.

  2. Spectrophotometric measurement of carboxyhaemoglobin: An evaluation of the method of Commins and Lawther

    PubMed Central

    Lily, R. E. C.; Cole, P. V.; Hawkins, L. H.

    1972-01-01

    Lily, R. E. C., Cole, P. V., and Hawkins, L. H. (1972).Brit. J. industr. Med.,29, 454-457. Spectrophotometric measurement of carboxyhaemoglobin. An evaluation of the method of Commins and Lawther. The spectrophotometric method of Commins and Lawther for the measurement of carboxyhaemoglobin (COHb) concentration was evaluated for both accuracy and sensitivity. The method was calibrated by equilibrating diluted blood samples with known concentrations of carbon monoxide (CO) in air and measuring the resultant COHb saturations. Over the range 0-40% COHb saturation the mean error was 0·67% COHb (SD 0·65). It is considered that the accuracy of the method is more than sufficient for measurement of both the high COHb levels found in clinical situations and the lower COHb saturation resulting from exposure to urban air and cigarette smoking. PMID:4636665

  3. Characterization of the DARA solar absolute radiometer

    NASA Astrophysics Data System (ADS)

    Finsterle, W.; Suter, M.; Fehlmann, A.; Kopp, G.

    2011-12-01

    The Davos Absolute Radiometer (DARA) prototype is an Electrical Substitution Radiometer (ESR) which has been developed as a successor of the PMO6 type on future space missions and ground based TSI measurements. The DARA implements an improved thermal design of the cavity detector and heat sink assembly to minimize air-vacuum differences and to maximize thermal symmetry of measuring and compensating cavity. The DARA also employs an inverted viewing geometry to reduce internal stray light. We will report on the characterization and calibration experiments which were carried out at PMOD/WRC and LASP (TRF).

  4. ABSOLUTE POLARIMETRY AT RHIC.

    SciTech Connect

    OKADA; BRAVAR, A.; BUNCE, G.; GILL, R.; HUANG, H.; MAKDISI, Y.; NASS, A.; WOOD, J.; ZELENSKI, Z.; ET AL.

    2007-09-10

    Precise and absolute beam polarization measurements are critical for the RHIC spin physics program. Because all experimental spin-dependent results are normalized by beam polarization, the normalization uncertainty contributes directly to final physics uncertainties. We aimed to perform the beam polarization measurement to an accuracy Of {Delta}P{sub beam}/P{sub beam} < 5%. The absolute polarimeter consists of Polarized Atomic Hydrogen Gas Jet Target and left-right pairs of silicon strip detectors and was installed in the RHIC-ring in 2004. This system features proton-proton elastic scattering in the Coulomb nuclear interference (CNI) region. Precise measurements of the analyzing power A{sub N} of this process has allowed us to achieve {Delta}P{sub beam}/P{sub beam} = 4.2% in 2005 for the first long spin-physics run. In this report, we describe the entire set up and performance of the system. The procedure of beam polarization measurement and analysis results from 2004-2005 are described. Physics topics of AN in the CNI region (four-momentum transfer squared 0.001 < -t < 0.032 (GeV/c){sup 2}) are also discussed. We point out the current issues and expected optimum accuracy in 2006 and the future.

  5. Radiance factor calibration of near-infrared spectral images of Mars

    NASA Astrophysics Data System (ADS)

    Klassen, David R.; Bell, James F.

    2003-05-01

    We present radiometrically calibrated spectrophotometric images of Mars taken at the NASA Infrared Telescope Facility (IRTF) near and during the 1995 and 1999 oppositions. Absolute intensity and radiance factor ( r F = I/F) values have been calculated for approximately 95% of the surface over all longitudes between -70° to 90° latitude in the 1.5- to 4.1-μm spectral region at a spectral resolution (Δλ/λ) of 1.5%. Values of radiance factor range from r F = 0.4 to 0.6 at 2.2 μm for the bright regions such as Moab and Arabia to r F = 0.12 to 0.3 at 2.2 μm around the dark regions Syrtis Major and Acidalia Planitia. Variations are seen due to seasonal dust and/or condensate cloud cover and viewing geometry. Our results are generally consistent with the few reported previous radiance factor determinations for Mars. These data are unique among ground-based data in their relatively high spatial resolution (≲200 km/pixel at the sub-Earth point) and coverage combined with their spectral resolution and coverage. These radiometrically calibrated observations can be used as input to studies focusing on spectral unmixing of surface and atmospheric components, radiative transfer modeling of disk and limb radiances, and photometric modeling of the martian phase function.

  6. Swarm's Absolute Scalar Magnetometer metrological performances

    NASA Astrophysics Data System (ADS)

    Leger, J.; Fratter, I.; Bertrand, F.; Jager, T.; Morales, S.

    2012-12-01

    The Absolute Scalar Magnetometer (ASM) has been developed for the ESA Earth Observation Swarm mission, planned for launch in November 2012. As its Overhauser magnetometers forerunners flown on Oersted and Champ satellites, it will deliver high resolution scalar measurements for the in-flight calibration of the Vector Field Magnetometer manufactured by the Danish Technical University. Latest results of the ground tests carried out to fully characterize all parameters that may affect its accuracy, both at instrument and satellite level, will be presented. In addition to its baseline function, the ASM can be operated either at a much higher sampling rate (burst mode at 250 Hz) or in a dual mode where it also delivers vector field measurements as a by-product. The calibration procedure and the relevant vector performances will be discussed.

  7. Absolute Equilibrium Entropy

    NASA Technical Reports Server (NTRS)

    Shebalin, John V.

    1997-01-01

    The entropy associated with absolute equilibrium ensemble theories of ideal, homogeneous, fluid and magneto-fluid turbulence is discussed and the three-dimensional fluid case is examined in detail. A sigma-function is defined, whose minimum value with respect to global parameters is the entropy. A comparison is made between the use of global functions sigma and phase functions H (associated with the development of various H-theorems of ideal turbulence). It is shown that the two approaches are complimentary though conceptually different: H-theorems show that an isolated system tends to equilibrium while sigma-functions allow the demonstration that entropy never decreases when two previously isolated systems are combined. This provides a more complete picture of entropy in the statistical mechanics of ideal fluids.

  8. Method for calibration of plutonium NDA

    SciTech Connect

    Lemming, J.F.; Campbell, A.R.; Rodenburg, W.W.

    1980-01-01

    Calibration materials characterized by calorimetric assay can be a practical alternative to synthetic standards for the calibration of plutonium nondestructive assay. Calorimetric assay is an effective measurement system for the characterization because: it can give an absolute assay from first principles when the isotopic composition is known, it is insensitive to most matrix effects, and its traceability to international measurement systems has been demonstrated.

  9. Calibrating X-ray Imaging Devices for Accurate Intensity Measurement

    SciTech Connect

    Haugh, M. J.

    2011-07-28

    The purpose of the project presented is to develop methods to accurately calibrate X-ray imaging devices. The approach was to develop X-ray source systems suitable for this endeavor and to develop methods to calibrate solid state detectors to measure source intensity. NSTec X-ray sources used for the absolute calibration of cameras are described, as well as the method of calibrating the source by calibrating the detectors. The work resulted in calibration measurements for several types of X-ray cameras. X-ray camera calibration measured efficiency and efficiency variation over the CCD. Camera types calibrated include: CCD, CID, back thinned (back illuminated), front illuminated.

  10. Absolute cavity pyrgeometer

    DOEpatents

    Reda, Ibrahim

    2013-10-29

    Implementations of the present disclosure involve an apparatus and method to measure the long-wave irradiance of the atmosphere or long-wave source. The apparatus may involve a thermopile, a concentrator and temperature controller. The incoming long-wave irradiance may be reflected from the concentrator to a thermopile receiver located at the bottom of the concentrator to receive the reflected long-wave irradiance. In addition, the thermopile may be thermally connected to a temperature controller to control the device temperature. Through use of the apparatus, the long-wave irradiance of the atmosphere may be calculated from several measurements provided by the apparatus. In addition, the apparatus may provide an international standard of pyrgeometers' calibration that is traceable back to the International System of Units (SI) rather than to a blackbody atmospheric simulator.

  11. Calibrations of the LHD Thomson scattering system

    NASA Astrophysics Data System (ADS)

    Yamada, I.; Funaba, H.; Yasuhara, R.; Hayashi, H.; Kenmochi, N.; Minami, T.; Yoshikawa, M.; Ohta, K.; Lee, J. H.; Lee, S. H.

    2016-11-01

    The Thomson scattering diagnostic systems are widely used for the measurements of absolute local electron temperatures and densities of fusion plasmas. In order to obtain accurate and reliable temperature and density data, careful calibrations of the system are required. We have tried several calibration methods since the second LHD experiment campaign in 1998. We summarize the current status of the calibration methods for the electron temperature and density measurements by the LHD Thomson scattering diagnostic system. Future plans are briefly discussed.

  12. 1987 calibration of the TFTR neutron spectrometers

    SciTech Connect

    Barnes, C.W.; Strachan, J.D.; Princeton Univ., NJ . Plasma Physics Lab.)

    1989-12-01

    The {sup 3}He neutron spectrometer used for measuring ion temperatures and the NE213 proton recoil spectrometer used for triton burnup measurements were absolutely calibrated with DT and DD neutron generators placed inside the TFTR vacuum vessel. The details of the detector response and calibration are presented. Comparisons are made to the neutron source strengths measured from other calibrated systems. 23 refs., 19 figs., 6 tabs.

  13. Spectro-photometric determinations of Mn, Fe and Cu in aluminum master alloys

    NASA Astrophysics Data System (ADS)

    Rehan; Naveed, A.; Shan, A.; Afzal, M.; Saleem, J.; Noshad, M. A.

    2016-08-01

    Highly reliable, fast and cost effective Spectro-photometric methods have been developed for the determination of Mn, Fe & Cu in aluminum master alloys, based on the development of calibration curves being prepared via laboratory standards. The calibration curves are designed so as to induce maximum sensitivity and minimum instrumental error (Mn 1mg/100ml-2mg/100ml, Fe 0.01mg/100ml-0.2mg/100ml and Cu 2mg/100ml-10mg/ 100ml). The developed Spectro-photometric methods produce accurate results while analyzing Mn, Fe and Cu in certified reference materials. Particularly, these methods are suitable for all types of Al-Mn, Al-Fe and Al-Cu master alloys (5%, 10%, 50% etc. master alloys).Moreover, the sampling practices suggested herein include a reasonable amount of analytical sample, which truly represent the whole lot of a particular master alloy. Successive dilution technique was utilized to meet the calibration curve range. Furthermore, the workout methods were also found suitable for the analysis of said elements in ordinary aluminum alloys. However, it was observed that Cush owed a considerable interference with Fe, the later one may not be accurately measured in the presence of Cu greater than 0.01 %.

  14. Absolute neutrino mass measurements

    SciTech Connect

    Wolf, Joachim

    2011-10-06

    The neutrino mass plays an important role in particle physics, astrophysics and cosmology. In recent years the detection of neutrino flavour oscillations proved that neutrinos carry mass. However, oscillation experiments are only sensitive to the mass-squared difference of the mass eigenvalues. In contrast to cosmological observations and neutrino-less double beta decay (0v2{beta}) searches, single {beta}-decay experiments provide a direct, model-independent way to determine the absolute neutrino mass by measuring the energy spectrum of decay electrons at the endpoint region with high accuracy.Currently the best kinematic upper limits on the neutrino mass of 2.2eV have been set by two experiments in Mainz and Troitsk, using tritium as beta emitter. The next generation tritium {beta}-experiment KATRIN is currently under construction in Karlsruhe/Germany by an international collaboration. KATRIN intends to improve the sensitivity by one order of magnitude to 0.2eV. The investigation of a second isotope ({sup 137}Rh) is being pursued by the international MARE collaboration using micro-calorimeters to measure the beta spectrum. The technology needed to reach 0.2eV sensitivity is still in the R and D phase. This paper reviews the present status of neutrino-mass measurements with cosmological data, 0v2{beta} decay and single {beta}-decay.

  15. Kinetic spectrophotometric determination of trace manganese (II) with dahlia violet in nonionic microemulsion medium.

    PubMed

    Wei, Qin; Yan, Liangguo; Chang, Guohua; Ou, Qingyu

    2003-02-01

    A new catalytic kinetic spectrophotometric method has been developed for the determination of trace amount of manganese (II) in nonionic microemulsion medium. The method is based on the catalytic effect of manganese (II) on the oxidation of dahlia violet by potassium periodate with nitrilotriacetic acid as an activitor in the presence of nonionic microemulsion. Under the optimum conditions, the calibration graph is linear in the range of 0.0004-0.0056 mug ml(-1) of manganese (II) at 580 nm. The detection limit achieved is 3.75x10(-5) mug ml(-1). Manganese (II) in foodstuff samples was determined with satisfactory results. PMID:18968906

  16. POLCAL - POLARIMETRIC RADAR CALIBRATION

    NASA Technical Reports Server (NTRS)

    Vanzyl, J.

    1994-01-01

    Calibration of polarimetric radar systems is a field of research in which great progress has been made over the last few years. POLCAL (Polarimetric Radar Calibration) is a software tool intended to assist in the calibration of Synthetic Aperture Radar (SAR) systems. In particular, POLCAL calibrates Stokes matrix format data produced as the standard product by the NASA/Jet Propulsion Laboratory (JPL) airborne imaging synthetic aperture radar (AIRSAR). POLCAL was designed to be used in conjunction with data collected by the NASA/JPL AIRSAR system. AIRSAR is a multifrequency (6 cm, 24 cm, and 68 cm wavelength), fully polarimetric SAR system which produces 12 x 12 km imagery at 10 m resolution. AIRSTAR was designed as a testbed for NASA's Spaceborne Imaging Radar program. While the images produced after 1991 are thought to be calibrated (phase calibrated, cross-talk removed, channel imbalance removed, and absolutely calibrated), POLCAL can and should still be used to check the accuracy of the calibration and to correct it if necessary. Version 4.0 of POLCAL is an upgrade of POLCAL version 2.0 released to AIRSAR investigators in June, 1990. New options in version 4.0 include automatic absolute calibration of 89/90 data, distributed target analysis, calibration of nearby scenes with calibration parameters from a scene with corner reflectors, altitude or roll angle corrections, and calibration of errors introduced by known topography. Many sources of error can lead to false conclusions about the nature of scatterers on the surface. Errors in the phase relationship between polarization channels result in incorrect synthesis of polarization states. Cross-talk, caused by imperfections in the radar antenna itself, can also lead to error. POLCAL reduces cross-talk and corrects phase calibration without the use of ground calibration equipment. Removing the antenna patterns during SAR processing also forms a very important part of the calibration of SAR data. Errors in the

  17. Spectrophotometric Attachment for the Vacuum Ultraviolet

    NASA Technical Reports Server (NTRS)

    Axelrod, Norman N.

    1961-01-01

    An absorption spectrophotometric attachment to a vacuum ultraviolet monochromator has been built and tested. With an empty sample chamber, the ratio of the radiant flux through the sample chamber to the radiant flux through the reference chamber was measured. By optimizing conditions at the entrance slit, the ratio was constant within experimental error over the region 1000-1600 A. The transmittance of thin celluloid films was measured with the attachment.

  18. Spectrophotometric determination of fluorine in silicate rocks

    USGS Publications Warehouse

    Peck, L.C.; Smith, V.C.

    1964-01-01

    The rock powder is sintered with a sodium carbonate flux containing zinc oxide and magnesium carbonate, the sinter-cake leached with water and the resulting solution filtered. Fluorine is separated from the acidified filtrate by steam distillation and determined spectrophotometrically by means of a zirconium-SPADNS reagent. If a multiple-unit distillation apparatus is used, 12 determinations can be completed per man-day. ?? 1964.

  19. [Spectrophotometric determination of methaqualone in biologic material].

    PubMed

    Kerde, C

    1975-03-01

    A rapid and simple spectrophotometric procedure for the determination of 2-methyl-3-o-tolyl-4(3H)-quinazolinone (methaqualone) in biological material is described. After extraction of the specimen with chloroform and washing with 0.5 N sodium hydroxide and 0.5 N sulfuric acid methaqualone is extracted with 5 ml 50% sulfuric acid and read in a spectrophotometer at 234 nm. The procedure is suitable to determine serum levels of methaqualone after a therapeutic dose.

  20. Calibration of X-Ray Observatories

    NASA Technical Reports Server (NTRS)

    Weisskopf, Martin C.; L'Dell, Stephen L.

    2011-01-01

    Accurate calibration of x-ray observatories has proved an elusive goal. Inaccuracies and inconsistencies amongst on-ground measurements, differences between on-ground and in-space performance, in-space performance changes, and the absence of cosmic calibration standards whose physics we truly understand have precluded absolute calibration better than several percent and relative spectral calibration better than a few percent. The philosophy "the model is the calibration" relies upon a complete high-fidelity model of performance and an accurate verification and calibration of this model. As high-resolution x-ray spectroscopy begins to play a more important role in astrophysics, additional issues in accurately calibrating at high spectral resolution become more evident. Here we review the challenges of accurately calibrating the absolute and relative response of x-ray observatories. On-ground x-ray testing by itself is unlikely to achieve a high-accuracy calibration of in-space performance, especially when the performance changes with time. Nonetheless, it remains an essential tool in verifying functionality and in characterizing and verifying the performance model. In the absence of verified cosmic calibration sources, we also discuss the notion of an artificial, in-space x-ray calibration standard. 6th

  1. Redetermining CEBAF's Absolute Energy

    NASA Astrophysics Data System (ADS)

    Su, Tong; Jlab Marathon Collaboration

    2015-04-01

    With the upgrade of the Jefferson Lab accelerator (CEBAF) from 6 GeV max energy to 12 GeV, all the dipole magnets in the machine were refurbished. Most of them were switched from open c-shaped to closed h-shaped by adding extra iron. With these upgraded magnets, the energy calibration of the accelerator needed to be redetermined. We will show how an extra external dipole, which is run in series with those in the machine, helps us cross check the current in the magnets as well as precisely map out the integral field for any machine setting. Using knowledge of the relative performance of the dipoles as well as the bend angle into the Hall, has allowed us to already determine a 4th pass 7 GeV beam to better than 7 MeV. In the future, we will use g-2 spin precession as a second independent energy determination. This work is supported by Kent State University, NSF Grant PHY-1405814, and DOE Contract DE-AC05-06OR23177 (JLab).

  2. Method to obtain absolute impurity density profiles combining charge exchange and beam emission spectroscopy without absolute intensity calibrationa)

    NASA Astrophysics Data System (ADS)

    Kappatou, A.; Jaspers, R. J. E.; Delabie, E.; Marchuk, O.; Biel, W.; Jakobs, M. A.

    2012-10-01

    Investigation of impurity transport properties in tokamak plasmas is essential and a diagnostic that can provide information on the impurity content is required. Combining charge exchange recombination spectroscopy (CXRS) and beam emission spectroscopy (BES), absolute radial profiles of impurity densities can be obtained from the CXRS and BES intensities, electron density and CXRS and BES emission rates, without requiring any absolute calibration of the spectra. The technique is demonstrated here with absolute impurity density radial profiles obtained in TEXTOR plasmas, using a high efficiency charge exchange spectrometer with high etendue, that measures the CXRS and BES spectra along the same lines-of-sight, offering an additional advantage for the determination of absolute impurity densities.

  3. Absolute Identification by Relative Judgment

    ERIC Educational Resources Information Center

    Stewart, Neil; Brown, Gordon D. A.; Chater, Nick

    2005-01-01

    In unidimensional absolute identification tasks, participants identify stimuli that vary along a single dimension. Performance is surprisingly poor compared with discrimination of the same stimuli. Existing models assume that identification is achieved using long-term representations of absolute magnitudes. The authors propose an alternative…

  4. Be Resolute about Absolute Value

    ERIC Educational Resources Information Center

    Kidd, Margaret L.

    2007-01-01

    This article explores how conceptualization of absolute value can start long before it is introduced. The manner in which absolute value is introduced to students in middle school has far-reaching consequences for their future mathematical understanding. It begins to lay the foundation for students' understanding of algebra, which can change…

  5. Simultaneous spectrophotometric and mechanical property characterization of skin

    NASA Astrophysics Data System (ADS)

    Bunegin, Leonid; Moore, Jeffery B.

    2006-02-01

    Both reflectance spectroscopy and the determination Young's Modulus of skin have shown promise for identifying skin pathology. At present, these determinations are carried out using separate methodologies. This study demonstrates a new technology combining digital UV/VIS reflectance spectroscopy and vacuum aspiration for simultaneously determining the reflectance spectrum and mechanical properties of human skin tissue. A small hand held prototype device incorporating fiber-optic light guides into a vacuum channel was calibrated using various elastic materials subjected to increments of stress by vacuum from 0 to 25 in Hg. The intensity of a UV/VIS light beam reflected from the material at each vacuum increment was compared to the resulting material strain. The reflected beam was also spectrophotometrically analyzed. Skin types were similarly evaluated comparing normal and scar tissue and skin of various ages and coloration. An exponential relationship between reflected beam intensity and the amount of strain resulting from vacuum increments was observed. Young's Modulus (calculated from Aoki et. al equation) and spectra from normal skin and scar tissue were in agreement with previously published observations. Age related decreases in skin elasticity were also demonstrated. In the reflectance spectra, oxy and deoxy-hemoglobin absorbance bands were detected, becoming significantly enhanced at increased levels of vacuum. Melanin absorbance was also easily detected and appeared to correlate with skin coloration. Since superficial skin pathologies have characteristic spectroscopic and mechanical properties, this technique may provide a promising new approach for rapid, non-invasive method for the evaluation of skin lesions.

  6. Spectrophotometric determination of ofloxacin in pharmaceuticals by redox reaction

    NASA Astrophysics Data System (ADS)

    Ramesh, P. J.; Basavaiah, K.; Rajendraprasad, N.; Devi, O. Zenita; Vinay, K. B.

    2011-07-01

    Two simple spectrophotometric methods have been developed to analyze ofloxacin (OFX) in pharmaceuticals. The methods are based on the oxidation of OFX by a measured excess of cerium(IV) sulfate in H2SO4 medium. This was followed by the determination of the unreacted oxidant by reacting it with either p-toluidine ( p-TD) and measuring the absorbance at 525 nm (method A) or o-dianisidine ( o-DA) and measuring the absorbance at 470 nm (method B). In both methods, the amount of cerium(IV) sulfate reacted corresponds to the amount of OFX. Calibration graphs were linear over the ranges of 0-120 and 0-4 g/ml OFX for methods A and B, respectively. The calculated molar absorptivity (2.34ṡ103 and 5.99ṡ104), Sandell sensitivity, and limit of quantification for the methods are reported. The intra-day precision (%RSD) and accuracy (%RE) were < 8.0 and ≤ 4.0%, respectively, and the inter-day RSD and RE values were within 5 and 4.0%, respectively. The applicability of the methods was demonstrated by determining OFX in tablets with an accuracy (%RE) of < 3% and precision (%RSD) of ≤2.65%. The accuracy of the methods was further ascertained by recovery experiments via a standard-addition procedure.

  7. Simple fibre optic spectrophotometric cell for pH determination.

    PubMed

    Besar, S S; Kelly, S W; Greenhalgh, P A

    1989-03-01

    A simple, inexpensive fibre optic spectrophotometric cell has been developed for clinical use. The system may employ one of two indicator reagents for the measurement: phenol red and BDH universal indicator. The spectrophotometer uses two ultrabright LED sources and a PIN diode photodetector. The fibre is of the plastic type with a core diameter of 1.0 mm. Two alternative analytical methods are available: electronic or computer processing. In the case of phenol red the measuring range using computer processing is between 6.0 and 8.0 pH units, with an accuracy of 0.015 pH units. The range for electronic circuit processing is from 6.8 to 8.0 pH units with an accuracy of 0.02 pH units. Using a BDH universal indicator, the range for computer processing is between 5.5 and 8.5 pH units with an accuracy of 0.05 pH units, while with electronic processing the range is between 6.0 and 8.0 pH units with an accuracy of 0.03 pH units. A description of the optoelectronics, an analysis of the indicator reagents and the calibration procedure are presented here, together with some example results. PMID:2704218

  8. Absolute measurements of fast neutrons using yttrium

    SciTech Connect

    Roshan, M. V.; Springham, S. V.; Rawat, R. S.; Lee, P.; Krishnan, M.

    2010-08-15

    Yttrium is presented as an absolute neutron detector for pulsed neutron sources. It has high sensitivity for detecting fast neutrons. Yttrium has the property of generating a monoenergetic secondary radiation in the form of a 909 keV gamma-ray caused by inelastic neutron interaction. It was calibrated numerically using MCNPX and does not need periodic recalibration. The total yttrium efficiency for detecting 2.45 MeV neutrons was determined to be f{sub n}{approx}4.1x10{sup -4} with an uncertainty of about 0.27%. The yttrium detector was employed in the NX2 plasma focus experiments and showed the neutron yield of the order of 10{sup 8} neutrons per discharge.

  9. MAGSAT: Vector magnetometer absolute sensor alignment determination

    NASA Technical Reports Server (NTRS)

    Acuna, M. H.

    1981-01-01

    A procedure is described for accurately determining the absolute alignment of the magnetic axes of a triaxial magnetometer sensor with respect to an external, fixed, reference coordinate system. The method does not require that the magnetic field vector orientation, as generated by a triaxial calibration coil system, be known to better than a few degrees from its true position, and minimizes the number of positions through which a sensor assembly must be rotated to obtain a solution. Computer simulations show that accuracies of better than 0.4 seconds of arc can be achieved under typical test conditions associated with existing magnetic test facilities. The basic approach is similar in nature to that presented by McPherron and Snare (1978) except that only three sensor positions are required and the system of equations to be solved is considerably simplified. Applications of the method to the case of the MAGSAT Vector Magnetometer are presented and the problems encountered discussed.

  10. Kinetic-spectrophotometric determination of ascorbic acid by inhibition of the hydrochloric acid-bromate reaction

    NASA Astrophysics Data System (ADS)

    Ensafi, Ali A.; Rezaei, B.; Movahedinia, H.

    2002-10-01

    A new analytical method was developed for the determination of ascorbic acid in fruit juice and pharmaceuticals. The method is based on its inhibition effect on the reaction between hydrochloric acid and bromate. The decolourisation of Methyl Orange by the reaction products was used to monitor the reaction spectrophotometrically at 510 nm. The linearity range of the calibration graph depends on bromate concentration. The variable affecting the rate of the reaction was investigated. The method is simple, rapid, relatively sensitive and precise. The limit of detection is 7.6×10 -6 M and calibration rang is 8×10 -6-1.2×10 -3 M ascorbic acid. The relative standard deviation of seven replication determinations of 8×10 -6 and 2×10 -5 M ascorbic acid was 2.8 and 1.7%, respectively. The influence of potential interfering substance was studied. The method was successfully applied for the determination of ascorbic acid in pharmaceuticals.

  11. Anemometer calibrator

    NASA Technical Reports Server (NTRS)

    Bate, T.; Calkins, D. E.; Price, P.; Veikins, O.

    1971-01-01

    Calibrator generates accurate flow velocities over wide range of gas pressure, temperature, and composition. Both pressure and flow velocity can be maintained within 0.25 percent. Instrument is essentially closed loop hydraulic system containing positive displacement drive.

  12. Development of normalized spectra manipulating spectrophotometric methods for simultaneous determination of Dimenhydrinate and Cinnarizine binary mixture.

    PubMed

    Lamie, Nesrine T; Yehia, Ali M

    2015-01-01

    Simultaneous determination of Dimenhydrinate (DIM) and Cinnarizine (CIN) binary mixture with simple procedures were applied. Three ratio manipulating spectrophotometric methods were proposed. Normalized spectrum was utilized as a divisor for simultaneous determination of both drugs with minimum manipulation steps. The proposed methods were simultaneous constant center (SCC), simultaneous derivative ratio spectrophotometry (S(1)DD) and ratio H-point standard addition method (RHPSAM). Peak amplitudes at isoabsorptive point in ratio spectra were measured for determination of total concentrations of DIM and CIN. For subsequent determination of DIM concentration, difference between peak amplitudes at 250 nm and 267 nm were used in SCC. While the peak amplitude at 275 nm of the first derivative ratio spectra were used in S(1)DD; then subtraction of DIM concentration from the total one provided the CIN concentration. The last RHPSAM was a dual wavelength method in which two calibrations were plotted at 220 nm and 230 nm. The coordinates of intersection point between the two calibration lines were corresponding to DIM and CIN concentrations. The proposed methods were successfully applied for combined dosage form analysis, Moreover statistical comparison between the proposed and reported spectrophotometric methods was applied. PMID:26037499

  13. Estimates of absolute flux and radiance factor of localized regions on Mars in the 2-4 micron wavelength region

    NASA Technical Reports Server (NTRS)

    Roush, Ted L.; Roush, Eileen A.; Singer, Robert B.; Lucey, Paul G.

    1992-01-01

    IRTF spectrophotometric observations of Mars obtained during the 1986 opposition are the bases for the present estimates of 2.0-4.15 micron absolute flux and radiance factor values. The bright/dark ratios obtained show a wavelength dependence similar to that observed by Bell and Crisp (1991) in 1990, but the spectral contrast for 1986 is lower than in those observations; this difference could be due to changes in the location, sample are size, and/or suspended atmospheric dust.

  14. Two new spectrophotometric reagents for copper.

    PubMed

    Stookey, L

    1970-07-01

    Two ferroin-type compounds are proposed as spectrophotometric reagents for copper(I): 6-methyl-2-pyridylhydrazidine, which forms a yellow complex with lambda(max) 426 nm and molar absorptivity 700 l.mole(-1).mm(-1), and 3-(6-methyl-2-pyridyl)-5,6-diphenyl-1,2,4-triazine, which forms a red-orange complex with (lambda)max 492 nm and molar absorptivity of 955 l.mole(-1).mm(-1). These reagents are specific for copper and the complexes can be extracted into isopentanol for increased sensitivity.

  15. Improved spectrophotometric cell for hydrothermal solutions

    USGS Publications Warehouse

    Susak, N.J.; Crerar, D.A.; Forseman, T.C.; Haas, J.L.

    1981-01-01

    A simple, inexpensive spectrophotometric cell was designed for use with aqueous solutions for which temperature is a maximum of 325??C and pressure, 28 MPa. The cell has an internal volume of 5 ml and a path length of 1.31 cm. Each furnace assembly is 120 mm in diameter ?? 150 mm high and will fit into most commercial spectrophotometers. Temperature is controlled by a standard set-point controller and a balancing circuit that is used to maintain the temperature of the sample and reference cell within 1??C of each other at any temperature.

  16. Spectrophotometric estimation of cobalt with ninhydrin.

    PubMed

    Mahmood, Karamat; Wattoo, Feroza Hamid; Wattoo, Muhammad Hamid Sarwar; Imran, Muhammad; Asad, Muhammad Javaid; Tirmizi, Syed Ahmed; Wadood, Abdul

    2012-04-01

    A violet coloured complex was developed when cobalt metal reacts with ninhydrin at pH 8.2, using sodium acetate buffer solution. Absorbance of the complex was measured at 395 nm. Various factors, such as volume of the ligand used, solution pH, stability of the complex with time and interference of other metals, which effect the complex formation have been studied in detail. Present developed method can be used for the spectrophotometric estimation of cobalt with ninhydrin complex. The method is simple, selective and cheap for the determination of cobalt in very less time.

  17. Singular perturbation of absolute stability.

    NASA Technical Reports Server (NTRS)

    Siljak, D. D.

    1972-01-01

    It was previously shown (author, 1969) that the regions of absolute stability in the parameter space can be determined when the parameters appear on the right-hand side of the system equations, i.e., the regular case. Here, the effect on absolute stability of a small parameter attached to higher derivatives in the equations (the singular case) is studied. The Lur'e-Postnikov class of nonlinear systems is considered.

  18. Evaluating calibrations of normal incident pyrheliometers

    NASA Astrophysics Data System (ADS)

    Vignola, Frank; Lin, Fuding

    2010-08-01

    When an Eppley Normal Incident Pyrheliometer is calibrated against an Eppley Hickey Frieden Absolute Cavity Radiometer, the instrument systematically deviates from the absolute cavity readings. The reason for this deviation is not understood. Comparisons are made between one pyrheliometer and an absolute cavity radiometer on selected clear days over a period of 8 months in Eugene, Oregon. The ratios of the readings from the two instruments are correlated against wind speed, pressure, temperature, relative humidity, beam intensity, and zenith angle to determine if any of these parameters statistically influence the calibration process. Wind speed, pressure, beam intensity, and air mass are shown to be statistically significant factors in determining the responsivity of the normal incident pyrheliometer. The results of these tests are evaluated and discussed. Use of air mass instead of zenith angle is proposed for calibration reports.

  19. Ultraviolet photometry from the Orbiting Astronomical Observatory. XXI - Absolute energy distribution of stars in the ultraviolet

    NASA Technical Reports Server (NTRS)

    Bless, R. C.; Code, A. D.; Fairchild, E. T.

    1976-01-01

    The absolute energy distribution in the ultraviolet is given for the stars alpha Vir, eta UMa, and alpha Leo. The calibration is based on absolute heterochromatic photometry between 2920 and 1370 A carried out with an Aerobee sounding rocket. The fundamental radiation standard is the synchrotron radiation from 240-MeV electrons in a certain synchrotron storage ring. On the basis of the sounding-rocket calibration, the preliminary OAO-2 spectrometer calibration has been revised; the fluxes for the three program stars are tabulated in energy per second per square centimeter per unit wavelength interval.

  20. Achieving Climate Change Absolute Accuracy in Orbit

    NASA Technical Reports Server (NTRS)

    Wielicki, Bruce A.; Young, D. F.; Mlynczak, M. G.; Thome, K. J; Leroy, S.; Corliss, J.; Anderson, J. G.; Ao, C. O.; Bantges, R.; Best, F.; Bowman, K.; Brindley, H.; Butler, J. J.; Collins, W.; Dykema, J. A.; Doelling, D. R.; Feldman, D. R.; Fox, N.; Huang, X.; Holz, R.; Huang, Y.; Jennings, D.; Jin, Z.; Johnson, D. G.; Jucks, K.; Kato, S.; Kratz, D. P.; Liu, X.; Lukashin, C.; Mannucci, A. J.; Phojanamongkolkij, N.; Roithmayr, C. M.; Sandford, S.; Taylor, P. C.; Xiong, X.

    2013-01-01

    The Climate Absolute Radiance and Refractivity Observatory (CLARREO) mission will provide a calibration laboratory in orbit for the purpose of accurately measuring and attributing climate change. CLARREO measurements establish new climate change benchmarks with high absolute radiometric accuracy and high statistical confidence across a wide range of essential climate variables. CLARREO's inherently high absolute accuracy will be verified and traceable on orbit to Système Internationale (SI) units. The benchmarks established by CLARREO will be critical for assessing changes in the Earth system and climate model predictive capabilities for decades into the future as society works to meet the challenge of optimizing strategies for mitigating and adapting to climate change. The CLARREO benchmarks are derived from measurements of the Earth's thermal infrared spectrum (5-50 micron), the spectrum of solar radiation reflected by the Earth and its atmosphere (320-2300 nm), and radio occultation refractivity from which accurate temperature profiles are derived. The mission has the ability to provide new spectral fingerprints of climate change, as well as to provide the first orbiting radiometer with accuracy sufficient to serve as the reference transfer standard for other space sensors, in essence serving as a "NIST [National Institute of Standards and Technology] in orbit." CLARREO will greatly improve the accuracy and relevance of a wide range of space-borne instruments for decadal climate change. Finally, CLARREO has developed new metrics and methods for determining the accuracy requirements of climate observations for a wide range of climate variables and uncertainty sources. These methods should be useful for improving our understanding of observing requirements for most climate change observations.

  1. An atlas of selected calibrated stellar spectra

    NASA Technical Reports Server (NTRS)

    Walker, Russell G.; Cohen, Martin

    1992-01-01

    Five hundred and fifty six stars in the IRAS PSC-2 that are suitable for stellar radiometric standards and are brighter than 1 Jy at 25 microns were identified. In addition, 123 stars that meet all of our criteria for calibration standards, but which lack a luminosity class were identified. An approach to absolute stellar calibration of broadband infrared filters based upon new models of Vega and Sirius due to Kurucz (1992) is presented. A general technique used to assemble continuous wide-band calibrated infrared spectra is described and an absolutely calibrated 1-35 micron spectrum of alpha(Tau) is constructed and the method using new and carefully designed observations is independently validated. The absolute calibration of the IRAS Low Resolution Spectrometer (LRS) database is investigated by comparing the observed spectrum of alpha(Tau) with that assumed in the original LRS calibration scheme. Neglect of the SiO fundamental band in alpha(Tau) has led to the presence of a specious 'emission' feature in all LRS spectra near 8.5 microns, and to an incorrect spectral slope between 8 and 12 microns. Finally, some of the properties of asteroids that effect their utility as calibration objects for the middle and far infrared region are examined. A technique to determine, from IRAS multiwaveband observations, the basic physical parameters needed by various asteroid thermal models that minimize the number of assumptions required is developed.

  2. Precision goniometer equipped with a 22-bit absolute rotary encoder.

    PubMed

    Xiaowei, Z; Ando, M; Jidong, W

    1998-05-01

    The calibration of a compact precision goniometer equipped with a 22-bit absolute rotary encoder is presented. The goniometer is a modified Huber 410 goniometer: the diffraction angles can be coarsely generated by a stepping-motor-driven worm gear and precisely interpolated by a piezoactuator-driven tangent arm. The angular accuracy of the precision rotary stage was evaluated with an autocollimator. It was shown that the deviation from circularity of the rolling bearing utilized in the precision rotary stage restricts the angular positioning accuracy of the goniometer, and results in an angular accuracy ten times larger than the angular resolution of 0.01 arcsec. The 22-bit encoder was calibrated by an incremental rotary encoder. It became evident that the accuracy of the absolute encoder is approximately 18 bit due to systematic errors.

  3. Highly sensitive catalytic spectrophotometric determination of ruthenium

    NASA Astrophysics Data System (ADS)

    Naik, Radhey M.; Srivastava, Abhishek; Prasad, Surendra

    2008-01-01

    A new and highly sensitive catalytic kinetic method (CKM) for the determination of ruthenium(III) has been established based on its catalytic effect on the oxidation of L-phenylalanine ( L-Pheala) by KMnO 4 in highly alkaline medium. The reaction has been followed spectrophotometrically by measuring the decrease in the absorbance at 526 nm. The proposed CKM is based on the fixed time procedure under optimum reaction conditions. It relies on the linear relationship where the change in the absorbance (Δ At) versus added Ru(III) amounts in the range of 0.101-2.526 ng ml -1 is plotted. Under the optimum conditions, the sensitivity of the proposed method, i.e. the limit of detection corresponding to 5 min is 0.08 ng ml -1, and decreases with increased time of analysis. The method is featured with good accuracy and reproducibility for ruthenium(III) determination. The ruthenium(III) has also been determined in presence of several interfering and non-interfering cations, anions and polyaminocarboxylates. No foreign ions interfered in the determination ruthenium(III) up to 20-fold higher concentration of foreign ions. In addition to standard solutions analysis, this method was successfully applied for the quantitative determination of ruthenium(III) in drinking water samples. The method is highly sensitive, selective and very stable. A review of recently published catalytic spectrophotometric methods for the determination of ruthenium(III) has also been presented for comparison.

  4. A New Technique for Quantitative Determination of Dexamethasone in Pharmaceutical and Biological Samples Using Kinetic Spectrophotometric Method

    PubMed Central

    Akhoundi-Khalafi, Ali Mohammad; Shishehbore, Masoud Reza

    2015-01-01

    Dexamethasone is a type of steroidal medications that is prescribed in many cases. In this study, a new reaction system using kinetic spectrophotometric method for quantitative determination of dexamethasone is proposed. The method is based on the catalytic effect of dexamethasone on the oxidation of Orange G by bromate in acidic media. The change in absorbance as a criterion of the oxidation reaction progress was followed spectrophotometrically. To obtain the maximum sensitivity, the effective reaction variables were optimized. Under optimized experimental conditions, calibration graph was linear over the range 0.2–54.0 mg L−1. The calculated detection limit (3sb/m) was 0.14 mg L−1 for six replicate determinations of blank signal. The interfering effect of various species was also investigated. The present method was successfully applied for the determination of dexamethasone in pharmaceutical and biological samples satisfactorily. PMID:25737724

  5. Image Calibration

    NASA Technical Reports Server (NTRS)

    Peay, Christopher S.; Palacios, David M.

    2011-01-01

    Calibrate_Image calibrates images obtained from focal plane arrays so that the output image more accurately represents the observed scene. The function takes as input a degraded image along with a flat field image and a dark frame image produced by the focal plane array and outputs a corrected image. The three most prominent sources of image degradation are corrected for: dark current accumulation, gain non-uniformity across the focal plane array, and hot and/or dead pixels in the array. In the corrected output image the dark current is subtracted, the gain variation is equalized, and values for hot and dead pixels are estimated, using bicubic interpolation techniques.

  6. Flow Calibration

    NASA Technical Reports Server (NTRS)

    1983-01-01

    Flow Technology Inc. worked with Lewis Research Center to develop a system for monitoring two different propellants being supplied to a spacecraft rocket thruster. They then commercialized the technology in the Microtrack, an extremely precise low-flow calibration system. Moog Inc., one of the device's primary users, measures the flow rate or the speed at which hydraulic oil flows through pin sized holes in disc shaped sapphires with the Microtrack. Using this data, two orifices with exactly the same flow rate can be matched as a pair and used as masters in servovalve production. The microtrack can also be used to calibrate other equipment.

  7. Biogeographic calibrations for the molecular clock

    PubMed Central

    Ho, Simon Y. W.; Tong, K. Jun; Foster, Charles S. P.; Ritchie, Andrew M.; Lo, Nathan; Crisp, Michael D.

    2015-01-01

    Molecular estimates of evolutionary timescales have an important role in a range of biological studies. Such estimates can be made using methods based on molecular clocks, including models that are able to account for rate variation across lineages. All clock models share a dependence on calibrations, which enable estimates to be given in absolute time units. There are many available methods for incorporating fossil calibrations, but geological and climatic data can also provide useful calibrations for molecular clocks. However, a number of strong assumptions need to be made when using these biogeographic calibrations, leading to wide variation in their reliability and precision. In this review, we describe the nature of biogeographic calibrations and the assumptions that they involve. We present an overview of the different geological and climatic events that can provide informative calibrations, and explain how such temporal information can be incorporated into dating analyses. PMID:26333662

  8. Biogeographic calibrations for the molecular clock.

    PubMed

    Ho, Simon Y W; Tong, K Jun; Foster, Charles S P; Ritchie, Andrew M; Lo, Nathan; Crisp, Michael D

    2015-09-01

    Molecular estimates of evolutionary timescales have an important role in a range of biological studies. Such estimates can be made using methods based on molecular clocks, including models that are able to account for rate variation across lineages. All clock models share a dependence on calibrations, which enable estimates to be given in absolute time units. There are many available methods for incorporating fossil calibrations, but geological and climatic data can also provide useful calibrations for molecular clocks. However, a number of strong assumptions need to be made when using these biogeographic calibrations, leading to wide variation in their reliability and precision. In this review, we describe the nature of biogeographic calibrations and the assumptions that they involve. We present an overview of the different geological and climatic events that can provide informative calibrations, and explain how such temporal information can be incorporated into dating analyses.

  9. VERITAS Distant Laser Calibration and Atmospheric Monitoring

    SciTech Connect

    Hui, C. M.

    2008-12-24

    As a calibrated laser pulse propagates through the atmosphere, the intensity of the Rayleigh scattered light arriving at the VERITAS telescopes can be calculated precisely. This allows for absolute calibration of imaging atmospheric Cherenkov telescopes (IACT) to be simple and straightforward. In these proceedings, we present the comparison between laser data and simulation to estimate the light collection efficiencies of the VERITAS telescopes, and the analysis of multiple laser data sets taken in different months for atmospheric monitoring purpose.

  10. Absolute flux scale for radioastronomy

    SciTech Connect

    Ivanov, V.P.; Stankevich, K.S.

    1986-07-01

    The authors propose and provide support for a new absolute flux scale for radio astronomy, which is not encumbered with the inadequacies of the previous scales. In constructing it the method of relative spectra was used (a powerful tool for choosing reference spectra). A review is given of previous flux scales. The authors compare the AIS scale with the scale they propose. Both scales are based on absolute measurements by the ''artificial moon'' method, and they are practically coincident in the range from 0.96 to 6 GHz. At frequencies above 6 GHz, 0.96 GHz, the AIS scale is overestimated because of incorrect extrapolation of the spectra of the primary and secondary standards. The major results which have emerged from this review of absolute scales in radio astronomy are summarized.

  11. Flight calibration assessment of HiRAP accelerometer data

    NASA Technical Reports Server (NTRS)

    Blanchard, Robert C.; Larman, Kevin T.; Moast, Christina D.

    1993-01-01

    A flight derived method of calibrating the High Resolution Accelerometer Package (HiRAP) flight data has been developed and is discussed for Shuttle Orbiter missions STS-35 and STS-40. These two mission data sets have been analyzed using ground calibration factors and flight derived calibration factors. This flight technique evolved early in the flight program when it was recognized that ground calibration factors are insufficient to determine absolute low-acceleration levels. The application of flight calibration factors to the data sets from these missions produced calibrated acceleration levels within an accuracy of less than +/- 1.5 microgravity of zero during a time in the flight when the acceleration level was known to be less than 1.0 microgravity. This analysis further confirms the theory that flight calibrations are required in order to obtain the absolute measurement of low-frequency, low-acceleration flight signals.

  12. Spectrophotometric Measurements of Phytochrome in vivo and Their Correlation with Photomorphogenic Responses of Phaseolus 12

    PubMed Central

    Klein, W. H.; Edwards, J. L.; Shropshire, W.

    1967-01-01

    Direct in vivo measurements of phytochrome have been made in Phaseolus vulgaris by 2-filter difference spectrophotometry (Ratiospect). All measurements were made at 730 versus 800 nm and it is assumed that the Δ (ΔOD) is directly proportional to the PFR concentration of phytochrome present. Dose response curves were determined for both physiological and spectrophotometric responses for red induction and far-red photoinactivation. For induction, saturation occurs at 100 mj/cm2 and for inactivation at 30 mj/cm2. The rate of hook opening and the physiological response measured 20 hours after induction are both shown to be directly proportional to the initial amount of PFR present spectrophotometrically. The sensitivity of the tissue correlates well with the absolute amount of phytochrome present, the inner portion of the hook having the maximum concentration of 0.042 Δ (ΔOD)/g fresh weight. If the total reversible phytochrome concentration is reduced by exposure to red light and allowing PFR to decay out of the system the remaining sensitivity of the tissue is shown to be directly correlated with the amount of PR remaining in the tissue. PFR disappears rapidly in the dark at 25°, and is not detectable after 6 hours. There is no indication that PFR reverts in the system to PR. At 4°, PFR does not disappear measurably up to 1 hour and is nearly totally reversible to PR. Images PMID:16656503

  13. Calibration strategies for the Cherenkov Telescope Array

    NASA Astrophysics Data System (ADS)

    Gaug, Markus; Berge, David; Daniel, Michael; Doro, Michele; Förster, Andreas; Hofmann, Werner; Maccarone, Maria C.; Parsons, Dan; de los Reyes Lopez, Raquel; van Eldik, Christopher

    2014-08-01

    The Central Calibration Facilities workpackage of the Cherenkov Telescope Array (CTA) observatory for very high energy gamma ray astronomy defines the overall calibration strategy of the array, develops dedicated hardware and software for the overall array calibration and coordinates the calibration efforts of the different telescopes. The latter include LED-based light pulsers, and various methods and instruments to achieve a calibration of the overall optical throughput. On the array level, methods for the inter-telescope calibration and the absolute calibration of the entire observatory are being developed. Additionally, the atmosphere above the telescopes, used as a calorimeter, will be monitored constantly with state-of-the-art instruments to obtain a full molecular and aerosol profile up to the stratosphere. The aim is to provide a maximal uncertainty of 10% on the reconstructed energy-scale, obtained through various independent methods. Different types of LIDAR in combination with all-sky-cameras will provide the observatory with an online, intelligent scheduling system, which, if the sky is partially covered by clouds, gives preference to sources observable under good atmospheric conditions. Wide-field optical telescopes and Raman Lidars will provide online information about the height-resolved atmospheric extinction, throughout the field-of-view of the cameras, allowing for the correction of the reconstructed energy of each gamma-ray event. The aim is to maximize the duty cycle of the observatory, in terms of usable data, while reducing the dead time introduced by calibration activities to an absolute minimum.

  14. Validation of spectrophotometric method for lactulose assay in syrup preparation

    NASA Astrophysics Data System (ADS)

    Mahardhika, Andhika Bintang; Novelynda, Yoshella; Damayanti, Sophi

    2015-09-01

    Lactulose is a synthetic disaccharide widely used in food and pharmaceutical fields. In the pharmaceutical field, lactulose is used as osmotic laxative in a syrup dosage form. This research was aimed to validate the spectrophotometric method to determine the levels of lactulose in syrup preparation and the commercial sample. Lactulose is hydrolyzed by hydrochloric acid to form fructose and galactose. The fructose was reacted with resorcinol reagent, forming compounds that give absorption peak at 485 nm. Analytical methods was validated, hereafter lactulose content in syrup preparation were determined. The calibration curve was linear in the range of 30-100 μg/mL with a correlation coefficient (r) of 0.9996, coefficient of variance (Vxo) of 1.1 %, limit of detection of 2.32 μg/mL, and limit of quantitation of 7.04 μg/mL. The result of accuracy test for the lactulose assay in the syrup preparation showed recoveries of 96.6 to 100.8 %. Repeatability test of lactulose assay in standard solution of lactulose and sample preparation syrup showed the coefficient of variation (CV) of 0.75 % and 0.7 %. Intermediate precision (interday) test resulted in coefficient of variation 1.06 % on the first day, the second day by 0.99 %, and 0.95 % for the third day. This research gave a valid analysis method and levels of lactulose in syrup preparations of samples A, B, C were 101.6, 100.5, and 100.6 %, respectively.

  15. Sensitive indirect spectrophotometric determination of isoniazid

    NASA Astrophysics Data System (ADS)

    Safavi, A.; Karimi, M. A.; Hormozi Nezhad, M. R.; Kamali, R.; Saghir, N.

    2004-03-01

    A simple, rapid, sensitive and accurate indirect spectrophotometric method for the microdetermination of isoniazid (INH) in pure form and pharmaceutical formulations is developed. The procedure is based on the reaction of copper(II) with isoniazid in the presence of neocuproine (NC). In the presence of neocuproine, copper(II) is reduced easily by isoniazid to a Cu(I)-neocuproine complex, which shows an absorption maximum at 454 nm. By measuring the absorbance of the complex at this wavelength, isoniazid can be determined in the range 0.3-3.5 μg ml -1. This method was applied to the determination of isoniazid in pharmaceutical formulation and enabled the determination of the isoniazid in microgram quantities (0.3-3.5 μg ml -1). The results obtained for the assay of pharmaceutical preparations compared well with those obtained by the official method and demonstrated good accuracy and precision.

  16. Sensitive indirect spectrophotometric determination of isoniazid.

    PubMed

    Safavi, A; Karimi, M A; Hormozi Nezhad, M R; Kamali, R; Saghir, N

    2004-03-01

    A simple, rapid, sensitive and accurate indirect spectrophotometric method for the microdetermination of isoniazid (INH) in pure form and pharmaceutical formulations is developed. The procedure is based on the reaction of copper(II) with isoniazid in the presence of neocuproine (NC). In the presence of neocuproine, copper(II) is reduced easily by isoniazid to a Cu(I)-neocuproine complex, which shows an absorption maximum at 454 nm. By measuring the absorbance of the complex at this wavelength, isoniazid can be determined in the range 0.3-3.5 microgml-1. This method was applied to the determination of isoniazid in pharmaceutical formulation and enabled the determination of the isoniazid in microgram quantities (0.3-3.5 microgml-1). The results obtained for the assay of pharmaceutical preparations compared well with those obtained by the official method and demonstrated good accuracy and precision.

  17. Spectrophotometric determination of rosuvastatin calcium in tablets.

    PubMed

    Uyar, B; Celebier, M; Altinoz, S

    2007-06-01

    Rosuvastatin calcium is a synthetic lipid lowering agent which is used in hypercholesterolemia. It is a selective and competitive inhibitor of HMG-CoA reductase. In this study a simple, rapid and reliable spectrophotometric method was developed for the determination of rosuvastatin calcium in pharmaceutical preparations. The solutions of standard and pharmaceutical samples were prepared in methanol. 243 nm was chosen for measuring absorbances of rosuvastatin calcium. The developed method was validated with respect to linearity range, limit of detection and quantitation, accuracy, precision, specificity and ruggudness. The linearity range of the method was 1.0-60.0 microg mL(-1). The limit of detection was 0.33 microg mL(-1). The developed and validated method was applied to the determination of rosuvastatin calcium in pharmaceutical preparations.

  18. Relativistic Absolutism in Moral Education.

    ERIC Educational Resources Information Center

    Vogt, W. Paul

    1982-01-01

    Discusses Emile Durkheim's "Moral Education: A Study in the Theory and Application of the Sociology of Education," which holds that morally healthy societies may vary in culture and organization but must possess absolute rules of moral behavior. Compares this moral theory with current theory and practice of American educators. (MJL)

  19. Absolute transition probabilities of phosphorus.

    NASA Technical Reports Server (NTRS)

    Miller, M. H.; Roig, R. A.; Bengtson, R. D.

    1971-01-01

    Use of a gas-driven shock tube to measure the absolute strengths of 21 P I lines and 126 P II lines (from 3300 to 6900 A). Accuracy for prominent, isolated neutral and ionic lines is estimated to be 28 to 40% and 18 to 30%, respectively. The data and the corresponding theoretical predictions are examined for conformity with the sum rules.-

  20. Successive spectrophotometric resolution as a novel technique for the analysis of ternary mixtures of pharmaceuticals

    NASA Astrophysics Data System (ADS)

    Lotfy, Hayam M.; Tawakkol, Shereen M.; Fahmy, Nesma M.; Shehata, Mostafa A.

    2014-03-01

    A novel spectrophotometric technique was developed for the simultaneous determination of ternary mixtures, without prior separation steps. This technique was called successive spectrophotometric resolution technique. The technique was based on either the successive ratio subtraction or successive derivative subtraction. The mathematical explanation of the procedure was illustrated. In order to evaluate the applicability of the methods a model data as well as an experimental data were tested. The results from experimental data related to the simultaneous spectrophotometric determination of lidocaine hydrochloride (LH), calcium dobesilate (CD) and dexamethasone acetate (DA); in the presence of hydroquinone (HQ), the degradation product of calcium dobesilate were discussed. The proposed drugs were determined at their maxima 202 nm, 305 nm, 239 nm and 225 nm for LH, CD, DA and HQ respectively; by successive ratio subtraction coupled with constant multiplication method to obtain the zero order absorption spectra, while by applying successive derivative subtraction they were determined at their first derivative spectra at 210 nm for LH, 320 nm or P292-320 for CD, 256 nm or P225-252 for DA and P220-233 for HQ respectively. The calibration curves were linear over the concentration range of 2-20 μg/mL for both LH and DA, 6-50 μg/mL for CD, and 3-40 μg/mL for HQ. The proposed methods were checked using laboratory-prepared mixtures and were successfully applied for the analysis of pharmaceutical formulation containing the cited drugs with no interference from other dosage form additives. The proposed methods were validated according to the ICH guidelines. The obtained results were statistically compared with those of the official BP methods for LH, DA, and CD, and with the official USP method for HQ; using student t-test, F-test, and one way ANOVA, showing no significant difference with respect to accuracy and precision.

  1. Successive spectrophotometric resolution as a novel technique for the analysis of ternary mixtures of pharmaceuticals.

    PubMed

    Lotfy, Hayam M; Tawakkol, Shereen M; Fahmy, Nesma M; Shehata, Mostafa A

    2014-01-01

    A novel spectrophotometric technique was developed for the simultaneous determination of ternary mixtures, without prior separation steps. This technique was called successive spectrophotometric resolution technique. The technique was based on either the successive ratio subtraction or successive derivative subtraction. The mathematical explanation of the procedure was illustrated. In order to evaluate the applicability of the methods a model data as well as an experimental data were tested. The results from experimental data related to the simultaneous spectrophotometric determination of lidocaine hydrochloride (LH), calcium dobesilate (CD) and dexamethasone acetate (DA); in the presence of hydroquinone (HQ), the degradation product of calcium dobesilate were discussed. The proposed drugs were determined at their maxima 202 nm, 305 nm, 239 nm and 225 nm for LH, CD, DA and HQ respectively; by successive ratio subtraction coupled with constant multiplication method to obtain the zero order absorption spectra, while by applying successive derivative subtraction they were determined at their first derivative spectra at 210 nm for LH, 320 nm or P(292-320) for CD, 256 nm or P(225-252) for DA and P(220-233) for HQ respectively. The calibration curves were linear over the concentration range of 2-20 μg/mL for both LH and DA, 6-50 μg/mL for CD, and 3-40 μg/mL for HQ. The proposed methods were checked using laboratory-prepared mixtures and were successfully applied for the analysis of pharmaceutical formulation containing the cited drugs with no interference from other dosage form additives. The proposed methods were validated according to the ICH guidelines. The obtained results were statistically compared with those of the official BP methods for LH, DA, and CD, and with the official USP method for HQ; using student t-test, F-test, and one way ANOVA, showing no significant difference with respect to accuracy and precision.

  2. [The field radiometric calibration and validation of ZY-3 multispectral sensor].

    PubMed

    Zhang, Xue-Wen; Fu, Qiao-Yan; Han, Qi-Jin; Pan, Zhi-Qiang; Yang, Lei

    2014-09-01

    A field calibration campaign of ZY-3 multispectral sensor (MUS) was performed by the China Center for Resources Satellite Data and Application at the Dunhuang site. The reflectance-based method with two-point sites was used to obtain MUS absolute calibration coefficients in 2013. Compared to the calibration results in 2012, the calibration coefficients in 2013 changed by about 1%-8.5% in different bands. The results were also validated by intercalibration method using the Landsat 8 Operational Land Imager (OLI) data. It shows largely good consistency between field calibration and intercalibration. It was concluded that the absolute calibration coefficients were highly reliable.

  3. A simple UV spectrophotometric method for theophylline serum level determination.

    PubMed

    Plavsić, F

    1978-09-15

    A brief, simple and unexpensive UV spectrophotometric method for theophylline serum level determination is described. Charcoal extraction was performed for theophylline isolation from biological fluids. Coefficients of variation and recovery are similar to other parallel methods.

  4. Cross-calibration of the Landsat-4 and Landsat-5 thematic mappers

    NASA Astrophysics Data System (ADS)

    Mettler, Cory; Helder, Dennis

    2005-08-01

    The Landsat Thematic Mappers have obtained imagery of the Earth's surface since 1982 with the launch of Landsat 4. However, the absolute calibration of this first instrument, as well as it's cross-calibration to the other two thematic mappers on Landsat 5 and 7, remains in question. The objective for this work was to provide an absolute radiometric calibration of the Landsat 4 instrument. Landsat 4's internal calibrator, while still useful, does not provide an absolute calibration; it does provide a relative calibration of the instrument's responsivity over the lifetime of the mission. The same is true for the Landsat 5 internal calibrator; however, Landsat 5 has been cross-calibrated to Landsat 7's Enhanced Thematic Mapper Plus, which is believed to be absolutely calibrated to within 5%. Therefore, by cross-calibrating Landsat 4 to Landsat 7 through Landsat 5, an absolute calibration for Landsat 4 can be determined. This study provides only the Landsat 4 and 5 cross-calibration models. To determine these models, Landsat 4/Landsat 5 scene pairs were studied. Within each pair, 8 400x400-pixel sub-regions were selected from the image. The exact geo-located sub-region was located from both instruments and an assumption was made that the ground and the atmosphere did not change between image dates. Therefore, any difference between the images may be attributed to the difference in the instruments. Results of this cross-calibration using multiple dates were consistent to within 2%. Once the cross-calibration points were determined, they were used to correct the relative lifetime-calibration model from the internal calibrator, hence producing an absolute lifetime-calibration model.

  5. Photometric calibrations for 21st century science

    SciTech Connect

    Kent, Stephen; Kaiser, Mary Elizabeth; Deustua, Susana E.; Smith, J.Allyn; Adelman, Saul; Allam, Sahar S.; Baptista, Brian; Bohlin, Ralph C.; Clem, James L.; Conley, Alex; Edelstein, Jerry; /UC, Berkeley, Space Sci. Dept. /NOAO, Tucson

    2009-02-01

    The answers to fundamental science questions in astrophysics, ranging from the history of the expansion of the universe to the sizes of nearby stars, hinge on our ability to make precise measurements of diverse astronomical objects. As our knowledge of the underlying physics of objects improves along with advances in detectors and instrumentation, the limits on our capability to extract science from measurements is set, not by our lack of understanding of the nature of these objects, but rather by the most mundane of all issues: the precision with which we can calibrate observations in physical units. In principle, photometric calibration is a solved problem - laboratory reference standards such as blackbody furnaces achieve precisions well in excess of those needed for astrophysics. In practice, however, transferring the calibration from these laboratory standards to astronomical objects of interest is far from trivial - the transfer must reach outside the atmosphere, extend over 4{pi} steradians of sky, cover a wide range of wavelengths, and span an enormous dynamic range in intensity. Virtually all spectrophotometric observations today are calibrated against one or more stellar reference sources, such as Vega, which are themselves tied back to laboratory standards in a variety of ways. This system's accuracy is not uniform. Selected regions of the electromagnetic spectrum are calibrated extremely well, but discontinuities of a few percent still exist, e.g., between the optical and infrared. Independently, model stellar atmospheres are used to calibrate the spectra of selected white dwarf stars, e.g. the HST system, but the ultimate accuracy of this system should be verified against laboratory sources. Our traditional standard star systems, while sufficient until now, need to be improved and extended in order to serve future astrophysics experiments. This white paper calls for a program to improve upon and expand the current networks of spectrophotometrically

  6. Spectrophotometric determination of metronidazole and secnidazole in pharmaceutical preparations.

    PubMed

    Saffaj, T; Charrouf, M; Abourriche, A; Abboud, Y; Bennamara, A; Berrada, M

    2004-10-01

    A rapid and sensitive spectrophotometric method is proposed for determination of metronidazole and secnidazole. The method depends on the reduction of metronidazole and secnidazole molecule with zinc dust and hydrochloric acid flowed by diazotization and coupling with 8-quinolinol to give red colored chromogens easily measured spectrophotometrically which has lambda(max) = 500 nm. The experimental conditions were optimized and Berr's law was obeyed over the applicable concentration ranges both techniques were applied successfully to a wide variety of pharmaceutical preparations. PMID:15474063

  7. The MISR Calibration Program

    NASA Technical Reports Server (NTRS)

    Bruegge, Carol J.; Diner, David J.; Duval, Valerie G.

    1996-01-01

    The Multiangle Imaging SpectroRadiometer (MISR) is currently under development for NASA's Earth Observing System. The instrument consists of nine pushbroom cameras, each with four spectral bands in the visible and near-infrared. The cameras point in different view directions to provide measurements from nadir to highly oblique view angles in the along-track plane. Multiple view-angle observations provide a unique resource for studies of clouds, aerosols, and the surface. MISR is built to challenging radiometric and geometric performance specifications. Radiometric accuracy, for example, must be within +/- 3%/ 1 sigma, and polarization insensitivity must be better than +/- 1 %. An onboard calibrator (OBC) provides monthly updates to the instrument gain coefficients. Spectralon diffuse panels are used within the OBC to provide a uniform target for the cameras to view. The absolute radiometric scale is established both preflight and in orbit through the use of detector standards. During the mission, ground data processing to accomplish radiometric calibration, geometric rectification and registration of the nine view-angle imagery, and geophysical retrievals will proceed in an automated fashion. A global dataset is produced every 9 days. This paper details the preflight characterization of the MISR instrument, the design of the OBC, and the radiance product processing.

  8. Indirect spectrophotometric determination of arbutin, whitening agent through oxidation by periodate and complexation with ferric chloride

    NASA Astrophysics Data System (ADS)

    Barsoom, B. N.; Abdelsamad, A. M. E.; Adib, N. M.

    2006-07-01

    A simple and accurate spectrophotometric method for the determination of arbutin (glycosylated hydroquinone) is described. It is based on the oxidation of arbutin by periodate in presence of iodate. Excess periodate causes liberation of iodine at pH 8.0. The unreacted periodate is determined by measurement of the liberated iodine spectrophotometrically in the wavelength range (300-500 nm). A calibration curve was constructed for more accurate results and the correlation coefficient of linear regression analysis was -0.9778. The precision of this method was better than 6.17% R.S.D. ( n = 3). Regression analysis of Bear-Lambert plot shows good correlation in the concentration range 25-125 ug/ml. The identification limit was determined to be 25 ug/ml a detailed study of the reaction conditions was carried out, including effect of changing pH, time, temperature and volume of periodate. Analyzing pure and authentic samples containing arbutin tested the validity of the proposed method which has an average percent recovery of 100.86%. An alternative method is also proposed which involves a complexation reaction between arbutin and ferric chloride solution. The produced complex which is yellowish-green in color was determined spectophotometrically.

  9. Indirect spectrophotometric determination of arbutin, whitening agent through oxidation by periodate and complexation with ferric chloride.

    PubMed

    Barsoom, B N; Abdelsamad, A M E; Adib, N M

    2006-07-01

    A simple and accurate spectrophotometric method for the determination of arbutin (glycosylated hydroquinone) is described. It is based on the oxidation of arbutin by periodate in presence of iodate. Excess periodate causes liberation of iodine at pH 8.0. The unreacted periodate is determined by measurement of the liberated iodine spectrophotometrically in the wavelength range (300-500 nm). A calibration curve was constructed for more accurate results and the correlation coefficient of linear regression analysis was -0.9778. The precision of this method was better than 6.17% R.S.D. (n=3). Regression analysis of Bear-Lambert plot shows good correlation in the concentration range 25-125 ug/ml. The identification limit was determined to be 25 ug/ml a detailed study of the reaction conditions was carried out, including effect of changing pH, time, temperature and volume of periodate. Analyzing pure and authentic samples containing arbutin tested the validity of the proposed method which has an average percent recovery of 100.86%. An alternative method is also proposed which involves a complexation reaction between arbutin and ferric chloride solution. The produced complex which is yellowish-green in color was determined spectophotometrically. PMID:16458577

  10. Spectrophotometric determination of magnesium in pharmaceutical preparations by cost-effective sequential injection analysis.

    PubMed

    Tesfaldet, Zeriet O; van Staden, Jacobus F; Stefan, Raluca I

    2004-11-15

    A simple and rapid, inexpensive spectrophotometric method was proposed for magnesium assay in pharmaceutical preparations by sequential injection analysis (SIA). The method is based on the reaction between o-cresolphthalein complexone (CPC) and Mg(II) in alkaline media, yielding a pink colored complex with absorption maximum at 570nm. Since the formation constant between Ca-CPC and Mg-CPC is similar, initially a sample/standard solution was aspirated into the holding coil followed by a mixture of masking-buffer solutions. This was done because masking of calcium should be accomplished before Mg-CPC complexation. Then the reagent was introduced into the reaction coil to produce a colored complex, which is measured spectrophotometrically at 570nm. In this way the interference of calcium was reduced. Furthermore, all the parameters that affect the reaction were evaluated. The calibration curve is linear over a range of 0-20mgl(-1) of Mg(II) with a detection limit of 0.24mgl(-1). A sample throughput of 80 samples per hour and relative standard deviation <2.0% were achieved. The proposed method was successfully applied for the assay of magnesium in three different compositions of pharmaceutical preparations (tablets). The results were found to be in good agreement with the manual flame atomic absorption spectrophotometry (FAAS) and UV-Vis spectrophotometry methods and with the claimed values by the manufactures. The t-test shows no significant difference at 95% confidence level.

  11. Derivative-ratio spectrophotometric method for the determination of ternary mixture of aspirin, paracetamol and salicylic acid.

    PubMed

    El-Yazbi, Fawzi A; Hammud, Hassan H; Assi, Sulaf A

    2007-10-01

    A derivative spectrophotometric method was developed for the assay of a ternary mixture of aspirin (ASP), paracetamol (PAR) and salicylic acid (SAL). The method is based on the use of the first and second derivatives of the ratio spectra and measurement at zero-crossing wavelengths. The ratio spectra were obtained by dividing the absorption spectrum of the mixture by that of one of the components. The concentration of the other components are then determined from their respective calibration curves treated similarly. The described method was applied for the determination of these combinations in synthetic mixtures and dosage forms. The results obtained were accurate and precise.

  12. Derivative-ratio spectrophotometric method for the determination of ternary mixture of aspirin, paracetamol and salicylic acid

    NASA Astrophysics Data System (ADS)

    El-Yazbi, Fawzi A.; Hammud, Hassan H.; Assi, Sulaf A.

    2007-10-01

    A derivative spectrophotometric method was developed for the assay of a ternary mixture of aspirin (ASP), paracetamol (PAR) and salicylic acid (SAL). The method is based on the use of the first and second derivatives of the ratio spectra and measurement at zero-crossing wavelengths. The ratio spectra were obtained by dividing the absorption spectrum of the mixture by that of one of the components. The concentration of the other components are then determined from their respective calibration curves treated similarly. The described method was applied for the determination of these combinations in synthetic mixtures and dosage forms. The results obtained were accurate and precise.

  13. Orbital Acceleration Research Experiment: Calibration Measurements

    NASA Technical Reports Server (NTRS)

    Blanchard, Robert C.; Nicholson, John Y.; Ritter, James R.; Larman, Kevin T.

    1995-01-01

    The Orbital Acceleration Research Experiment (OARE), which has flown on STS-40, STS-50, and STS-58, contains a three-axis accelerometer with a single, nonpendulous, electrostatically suspended proofmass, which can resolve accelerations to the 10(sub -9) g level. The experiment also contains a full calibration station to permit in situ bias and scale-factor calibration. This on-orbit calibration capability eliminates the large uncertainty of ground-based calibrations encountered with accelerometers flown in the past on the Orbiter, and thus provides absolute acceleration measurement accuracy heretofore unachievable. This is the first time accelerometer scale-factor measurements have been performed on orbit. A detailed analysis of the calibration process is given, along with results of the calibration factors from the on-orbit OARE flight measurements on STS-58. In addition, the analysis of OARE flight-maneuver data used to validate the scale-factor measurements in the sensor's most sensitive range are also presented. Estimates on calibration uncertainties are discussed. These uncertainty estimates provides bounds on the STS-58 absolute acceleration measurements for future applications.

  14. Comparative study of spectrophotometric methods manipulating ratio spectra: an application on pharmaceutical binary mixture of cinnarizine and dimenhydrinate.

    PubMed

    Lamie, Nesrine T

    2015-04-15

    Four simple, specific, accurate and precise spectrophotometric methods are developed and validated for simultaneous determination of cinnarizine (CIN) and dimenhydrinate (DIM) in a binary mixture with overlapping spectra, without preliminary separation. The first method is dual wavelength spectrophotometry (DW), the second is a ratio difference spectrophotometric one (RD) which measures the difference in amplitudes between 250 and 270 nm of ratio spectrum, the third one is novel constant center spectrophotometric method (CC) and the fourth method is mean centering of ratio spectra (MCR). The calibration curve is linear over the concentration range of 4-20 and 10-45 μg/ml for CIN and DIM, respectively. These methods are tested by analyzing synthetic mixtures of the above drugs and they are applied to commercial pharmaceutical preparation of the subjected drugs. The validity of results was assessed by applying standard addition technique. The results obtained were found to agree statistically with those obtained by a reported method, showing no significant difference with respect to accuracy and precision. PMID:25677532

  15. Comparative study of spectrophotometric methods manipulating ratio spectra: An application on pharmaceutical binary mixture of cinnarizine and dimenhydrinate

    NASA Astrophysics Data System (ADS)

    Lamie, Nesrine T.

    2015-04-01

    Four simple, specific, accurate and precise spectrophotometric methods are developed and validated for simultaneous determination of cinnarizine (CIN) and dimenhydrinate (DIM) in a binary mixture with overlapping spectra, without preliminary separation. The first method is dual wavelength spectrophotometry (DW), the second is a ratio difference spectrophotometric one (RD) which measures the difference in amplitudes between 250 and 270 nm of ratio spectrum, the third one is novel constant center spectrophotometric method (CC) and the fourth method is mean centering of ratio spectra (MCR). The calibration curve is linear over the concentration range of 4-20 and 10-45 μg/ml for CIN and DIM, respectively. These methods are tested by analyzing synthetic mixtures of the above drugs and they are applied to commercial pharmaceutical preparation of the subjected drugs. The validity of results was assessed by applying standard addition technique. The results obtained were found to agree statistically with those obtained by a reported method, showing no significant difference with respect to accuracy and precision.

  16. Optomechanics for absolute rotation detection

    NASA Astrophysics Data System (ADS)

    Davuluri, Sankar

    2016-07-01

    In this article, we present an application of optomechanical cavity for the absolute rotation detection. The optomechanical cavity is arranged in a Michelson interferometer in such a way that the classical centrifugal force due to rotation changes the length of the optomechanical cavity. The change in the cavity length induces a shift in the frequency of the cavity mode. The phase shift corresponding to the frequency shift in the cavity mode is measured at the interferometer output to estimate the angular velocity of absolute rotation. We derived an analytic expression to estimate the minimum detectable rotation rate in our scheme for a given optomechanical cavity. Temperature dependence of the rotation detection sensitivity is studied.

  17. Moral absolutism and ectopic pregnancy.

    PubMed

    Kaczor, C

    2001-02-01

    If one accepts a version of absolutism that excludes the intentional killing of any innocent human person from conception to natural death, ectopic pregnancy poses vexing difficulties. Given that the embryonic life almost certainly will die anyway, how can one retain one's moral principle and yet adequately respond to a situation that gravely threatens the life of the mother and her future fertility? The four options of treatment most often discussed in the literature are non-intervention, salpingectomy (removal of tube with embryo), salpingostomy (removal of embryo alone), and use of methotrexate (MXT). In this essay, I review these four options and introduce a fifth (the milking technique). In order to assess these options in terms of the absolutism mentioned, it will also be necessary to discuss various accounts of the intention/foresight distinction. I conclude that salpingectomy, salpingostomy, and the milking technique are compatible with absolutist presuppositions, but not the use of methotrexate.

  18. Moral absolutism and ectopic pregnancy.

    PubMed

    Kaczor, C

    2001-02-01

    If one accepts a version of absolutism that excludes the intentional killing of any innocent human person from conception to natural death, ectopic pregnancy poses vexing difficulties. Given that the embryonic life almost certainly will die anyway, how can one retain one's moral principle and yet adequately respond to a situation that gravely threatens the life of the mother and her future fertility? The four options of treatment most often discussed in the literature are non-intervention, salpingectomy (removal of tube with embryo), salpingostomy (removal of embryo alone), and use of methotrexate (MXT). In this essay, I review these four options and introduce a fifth (the milking technique). In order to assess these options in terms of the absolutism mentioned, it will also be necessary to discuss various accounts of the intention/foresight distinction. I conclude that salpingectomy, salpingostomy, and the milking technique are compatible with absolutist presuppositions, but not the use of methotrexate. PMID:11262641

  19. The Absolute Spectrum Polarimeter (ASP)

    NASA Technical Reports Server (NTRS)

    Kogut, A. J.

    2010-01-01

    The Absolute Spectrum Polarimeter (ASP) is an Explorer-class mission to map the absolute intensity and linear polarization of the cosmic microwave background and diffuse astrophysical foregrounds over the full sky from 30 GHz to 5 THz. The principal science goal is the detection and characterization of linear polarization from an inflationary epoch in the early universe, with tensor-to-scalar ratio r much greater than 1O(raised to the power of { -3}) and Compton distortion y < 10 (raised to the power of{-6}). We describe the ASP instrument and mission architecture needed to detect the signature of an inflationary epoch in the early universe using only 4 semiconductor bolometers.

  20. Classification images predict absolute efficiency.

    PubMed

    Murray, Richard F; Bennett, Patrick J; Sekuler, Allison B

    2005-02-24

    How well do classification images characterize human observers' strategies in perceptual tasks? We show mathematically that from the classification image of a noisy linear observer, it is possible to recover the observer's absolute efficiency. If we could similarly predict human observers' performance from their classification images, this would suggest that the linear model that underlies use of the classification image method is adequate over the small range of stimuli typically encountered in a classification image experiment, and that a classification image captures most important aspects of human observers' performance over this range. In a contrast discrimination task and in a shape discrimination task, we found that observers' absolute efficiencies were generally well predicted by their classification images, although consistently slightly (approximately 13%) higher than predicted. We consider whether a number of plausible nonlinearities can account for the slight under prediction, and of these we find that only a form of phase uncertainty can account for the discrepancy.

  1. Spectrophotometric and colorimetric evaluation of staining of the light cured composite after exposure with different intensities of light curing units

    PubMed Central

    Chandrasekhar, Veeramachaneni; Reddy, L Pramod; Prakash, T Jaya; Rao, G Anitha; Pradeep, M

    2011-01-01

    Aim/Objective: To understand the importance of intensity of light in polymerizing light cured composites and its relation to color stability. Materials and Methods: Forty specimens of composite disc with 3mm diameter and 1.5 mm thick were divided into two groups of 20 samples each. Group1: Twenty samples were cured with a light curing unit of380mw/cm2. Group2: Twenty samples cured with a light curing unit of 680mw/cm2. These polymerized samples were immersed in methylene blue dye for 24hoursand later washed and immersed in absolute alcohol for 24 hours. The amount of color released into absolute alcohol was assessed by spectrophotometric and colorimetric analysis. Results: Results were analyzed for spectrophotometric and colorimetric values by using the Mann-Whitney test. The group cured with low intensity light stained more compared to the group cured with a normal intensity of light. Conclusions: Intensity of light plays a crucial role in staining of the polymerized light cured composite. The intensity of the curing unit has to be maintained in acceptable limits to achieve good clinical results. PMID:22144810

  2. A derivative standard for polarimeter calibration

    SciTech Connect

    Mulhollan, G.; Clendenin, J.; Saez, P.

    1996-10-01

    A long-standing problem in polarized electron physics is the lack of a traceable standard for calibrating electron spin polarimeters. While several polarimeters are absolutely calibrated to better than 2%, the typical instrument has an inherent accuracy no better than 10%. This variability among polarimeters makes it difficult to compare advances in polarized electron sources between laboratories. The authors have undertaken an effort to establish 100 nm thick molecular beam epitaxy grown GaAs(110) as a material which may be used as a derivative standard for calibrating systems possessing a solid state polarized electron source. The near-bandgap spin polarization of photoelectrons emitted from this material has been characterized for a variety of conditions and several laboratories which possess well calibrated polarimeters have measured the photoelectron polarization of cathodes cut from a common wafer. Despite instrumentation differences, the spread in the measurements is sufficiently small that this material may be used as a derivative calibration standard.

  3. ALTEA calibration

    NASA Astrophysics Data System (ADS)

    Zaconte, V.; Altea Team

    The ALTEA project is aimed at studying the possible functional damages to the Central Nervous System (CNS) due to particle radiation in space environment. The project is an international and multi-disciplinary collaboration. The ALTEA facility is an helmet-shaped device that will study concurrently the passage of cosmic radiation through the brain, the functional status of the visual system and the electrophysiological dynamics of the cortical activity. The basic instrumentation is composed by six active particle telescopes, one ElectroEncephaloGraph (EEG), a visual stimulator and a pushbutton. The telescopes are able to detect the passage of each particle measuring its energy, trajectory and released energy into the brain and identifying nuclear species. The EEG and the Visual Stimulator are able to measure the functional status of the visual system, the cortical electrophysiological activity, and to look for a correlation between incident particles, brain activity and Light Flash perceptions. These basic instruments can be used separately or in any combination, permitting several different experiments. ALTEA is scheduled to fly in the International Space Station (ISS) in November, 15th 2004. In this paper the calibration of the Flight Model of the silicon telescopes (Silicon Detector Units - SDUs) will be shown. These measures have been taken at the GSI heavy ion accelerator in Darmstadt. First calibration has been taken out in November 2003 on the SDU-FM1 using C nuclei at different energies: 100, 150, 400 and 600 Mev/n. We performed a complete beam scan of the SDU-FM1 to check functionality and homogeneity of all strips of silicon detector planes, for each beam energy we collected data to achieve good statistics and finally we put two different thickness of Aluminium and Plexiglas in front of the detector in order to study fragmentations. This test has been carried out with a Test Equipment to simulate the Digital Acquisition Unit (DAU). We are scheduled to

  4. Comparison of Two Spectrophotometric Techniques for Nutrients Analyses in Water Samples

    NASA Astrophysics Data System (ADS)

    Bartošová, Alica; Michalíková, Anna; Sirotiak, Maroš; Soldán, Maroš

    2013-01-01

    The aim of this contribution is to compare two common techniques for determining the concentrations of nitrate, nitrite, ammonium and phosphates in surface water and groundwater. Excess of these nutrients in water can directly affect human health (e.g. methemoglobinaemia) or indirectly through the products of secondary pollution - eutrophication (e.g. cyanotoxins, emanation of hydrogen sulphide, mercaptanes, methane...). Negative impact of nutrients excess in surface water often causes the destruction of water ecosystems, and therefore, common substances of these elements must be monitored and managed. For these experiments two spectrophotometric techniques - ultraviolet spectrophotometry and nutrient photometry were used. These techniques are commonly used for quick and simple analyses of nutrients in waste water. There are calibration curves for each nutrient and for determination of their concentration.

  5. Kinetic spectrophotometric method for the determination of morphine in biological samples

    NASA Astrophysics Data System (ADS)

    Sheibani, A.; Shishehbore, M. Reza; Mirparizi, E.

    2010-10-01

    In this paper a simple, selective and inexpensive kinetic method was developed for the determination of morphine based on its inhibitory effect on the Janus green-bromate system in sulfuric acid media. The reaction was monitored spectrophotometrically at 618 nm by a fixed time method. The effect of different parameters such as concentration of reactants and temperature on the rate of reaction was investigated and optimum conditions were obtained. The calibration curve was linear in the concentration range 0.07-7.98 mg L -1 of morphine, and detection limit of the method was 3.0 × 10 -2 mg L -1. The relative standard deviation for five determinations of 3.74 mg L -1 of morphine was 0.57%. Finally, the proposed method was successfully applied to the determination of morphine in human urine and serum as real samples.

  6. Three different spectrophotometric methods manipulating ratio spectra for determination of binary mixture of Amlodipine and Atorvastatin.

    PubMed

    Darwish, Hany W; Hassan, Said A; Salem, Maissa Y; El-Zeiny, Badr A

    2011-12-01

    Three simple, specific, accurate and precise spectrophotometric methods manipulating ratio spectra are developed for the simultaneous determination of Amlodipine besylate (AM) and Atorvastatin calcium (AT) in tablet dosage forms. The first method is first derivative of the ratio spectra ((1)DD), the second is ratio subtraction and the third is the method of mean centering of ratio spectra. The calibration curve is linear over the concentration range of 3-40 and 8-32 μg/ml for AM and AT, respectively. These methods are tested by analyzing synthetic mixtures of the above drugs and they are applied to commercial pharmaceutical preparation of the subjected drugs. Standard deviation is <1.5 in the assay of raw materials and tablets. Methods are validated as per ICH guidelines and accuracy, precision, repeatability and robustness are found to be within the acceptable limit.

  7. Cloud point extraction, preconcentration and simultaneous spectrophotometric determination of nickel and cobalt in water samples

    NASA Astrophysics Data System (ADS)

    Safavi, A.; Abdollahi, H.; Hormozi Nezhad, M. R.; Kamali, R.

    2004-10-01

    Cloud point extraction has been used for the preconcentration and simultaneous spectrophotometric determination of nickel and cobalt after the formation of a complex with 2-amino-cyclopentene-1-dithiocarboxylic acid (ACDA), and latter analysis by spectrophotometer using Triton X-114 as surfactant. The parameters affecting the separation phase and detection process were optimized. Under the optimum experimental conditions (i.e. pH=5, 0.07 mM ACDA, Triton X-114 = 0.25% (w/v)), calibration graphs were linear in the range of 20-500 and 20-200 μg l -1 with detection limits of 10 and 7.5 μg l -1 for Ni and Co, respectively. The method was applied to the determination of Ni and Co in natural and waste water samples with satisfactory results.

  8. Spectrophotometric method for determination parts per million levels of cyclohexylamine in water.

    PubMed

    Kumbhar, A G; Narasimhan, S V; Mathur, P K

    1998-10-01

    UV-vis spectrophotometric method for the analysis of cyclohexylamine (CHA) in aqueous medium in the range of 0.3-20 ppm was developed by coupling CHA with sodium 1,2-naphthaquinone-4-sulphonate (NQS). At 470 nm a calibration slope of 0.028 OD ppm(-1) was observed. Minimum detection limit was 0.3 ppm with standard deviation of 0.1 ppm. Reagent concentration and solution pH for the analysis are optimised by studying its effect on absorbance at 470 nm. The method was applied to analyse CHA for evaluating the performance of ion exchange resin used in condensate purification plant (CPP) of power station where, CHA is used as all volatile treatment (AVT) reagent to inhibit steam generator (SG) corrosion. Structure of the adduct formed by coupling CHA with NQS is elucidated using NMR ((1)H and (13)C) and IR spectra, CHN analysis and mole ratio variation method. PMID:18967343

  9. Validated spectrophotometric methods for simultaneous determination of Omeprazole, Tinidazole and Doxycycline in their ternary mixture

    NASA Astrophysics Data System (ADS)

    Lotfy, Hayam M.; Hegazy, Maha A.; Mowaka, Shereen; Mohamed, Ekram Hany

    2016-01-01

    A comparative study of smart spectrophotometric techniques for the simultaneous determination of Omeprazole (OMP), Tinidazole (TIN) and Doxycycline (DOX) without prior separation steps is developed. These techniques consist of several consecutive steps utilizing zero/or ratio/or derivative spectra. The proposed techniques adopt nine simple different methods, namely direct spectrophotometry, dual wavelength, first derivative-zero crossing, amplitude factor, spectrum subtraction, ratio subtraction, derivative ratio-zero crossing, constant center, and successive derivative ratio method. The calibration graphs are linear over the concentration range of 1-20 μg/mL, 5-40 μg/mL and 2-30 μg/mL for OMP, TIN and DOX, respectively. These methods are tested by analyzing synthetic mixtures of the above drugs and successfully applied to commercial pharmaceutical preparation. The methods that are validated according to the ICH guidelines, accuracy, precision, and repeatability, were found to be within the acceptable limits.

  10. Three different spectrophotometric methods manipulating ratio spectra for determination of binary mixture of Amlodipine and Atorvastatin

    NASA Astrophysics Data System (ADS)

    Darwish, Hany W.; Hassan, Said A.; Salem, Maissa Y.; El-Zeiny, Badr A.

    2011-12-01

    Three simple, specific, accurate and precise spectrophotometric methods manipulating ratio spectra are developed for the simultaneous determination of Amlodipine besylate (AM) and Atorvastatin calcium (AT) in tablet dosage forms. The first method is first derivative of the ratio spectra ( 1DD), the second is ratio subtraction and the third is the method of mean centering of ratio spectra. The calibration curve is linear over the concentration range of 3-40 and 8-32 μg/ml for AM and AT, respectively. These methods are tested by analyzing synthetic mixtures of the above drugs and they are applied to commercial pharmaceutical preparation of the subjected drugs. Standard deviation is <1.5 in the assay of raw materials and tablets. Methods are validated as per ICH guidelines and accuracy, precision, repeatability and robustness are found to be within the acceptable limit.

  11. The Gaia spectrophotometric standard stars survey - III. Short-term variability monitoring

    NASA Astrophysics Data System (ADS)

    Marinoni, S.; Pancino, E.; Altavilla, G.; Bellazzini, M.; Galleti, S.; Tessicini, G.; Valentini, G.; Cocozza, G.; Ragaini, S.; Braga, V.; Bragaglia, A.; Federici, L.; Schuster, W. J.; Carrasco, J. M.; Castro, A.; Figueras, F.; Jordi, C.

    2016-11-01

    We present the results of the short-term constancy monitoring of candidate Gaia Spectrophotometric Standard Stars (SPSS). We obtained time series of typically 1.24 h - with sampling periods from 1-3 min to a few hours, depending on the case - to monitor the constancy of our candidate SPSS down to 10 mmag, as required for the calibration of Gaia photometric data. We monitored 162 out of a total of 212 SPSS candidates. The observing campaign started in 2006 and finished in 2015, using 143 observing nights on nine different instruments covering both hemispheres. Using differential photometry techniques, we built light curves with a typical precision of 4 mmag, depending on the data quality. As a result of our constancy assessment, 150 SPSS candidates were validated against short-term variability, and only 12 were rejected because of variability including some widely used flux standards such as BD+174708, SA 105-448, 1740346, and HD 37725.

  12. Validated spectrophotometric methods for simultaneous determination of Omeprazole, Tinidazole and Doxycycline in their ternary mixture.

    PubMed

    Lotfy, Hayam M; Hegazy, Maha A; Mowaka, Shereen; Mohamed, Ekram Hany

    2016-01-15

    A comparative study of smart spectrophotometric techniques for the simultaneous determination of Omeprazole (OMP), Tinidazole (TIN) and Doxycycline (DOX) without prior separation steps is developed. These techniques consist of several consecutive steps utilizing zero/or ratio/or derivative spectra. The proposed techniques adopt nine simple different methods, namely direct spectrophotometry, dual wavelength, first derivative-zero crossing, amplitude factor, spectrum subtraction, ratio subtraction, derivative ratio-zero crossing, constant center, and successive derivative ratio method. The calibration graphs are linear over the concentration range of 1-20 μg/mL, 5-40 μg/mL and 2-30 μg/mL for OMP, TIN and DOX, respectively. These methods are tested by analyzing synthetic mixtures of the above drugs and successfully applied to commercial pharmaceutical preparation. The methods that are validated according to the ICH guidelines, accuracy, precision, and repeatability, were found to be within the acceptable limits. PMID:26322842

  13. Another look at volume self-calibration: calibration and self-calibration within a pinhole model of Scheimpflug cameras

    NASA Astrophysics Data System (ADS)

    Cornic, Philippe; Illoul, Cédric; Cheminet, Adam; Le Besnerais, Guy; Champagnat, Frédéric; Le Sant, Yves; Leclaire, Benjamin

    2016-09-01

    We address calibration and self-calibration of tomographic PIV experiments within a pinhole model of cameras. A complete and explicit pinhole model of a camera equipped with a 2-tilt angles Scheimpflug adapter is presented. It is then used in a calibration procedure based on a freely moving calibration plate. While the resulting calibrations are accurate enough for Tomo-PIV, we confirm, through a simple experiment, that they are not stable in time, and illustrate how the pinhole framework can be used to provide a quantitative evaluation of geometrical drifts in the setup. We propose an original self-calibration method based on global optimization of the extrinsic parameters of the pinhole model. These methods are successfully applied to the tomographic PIV of an air jet experiment. An unexpected by-product of our work is to show that volume self-calibration induces a change in the world frame coordinates. Provided the calibration drift is small, as generally observed in PIV, the bias on the estimated velocity field is negligible but the absolute location cannot be accurately recovered using standard calibration data.

  14. Prospects for the Moon as an SI-Traceable Absolute Spectroradiometric Standard for Satellite Remote Sensing

    NASA Astrophysics Data System (ADS)

    Cramer, C. E.; Stone, T. C.; Lykke, K.; Woodward, J. T.

    2015-12-01

    The Earth's Moon has many physical properties that make it suitable for use as a reference light source for radiometric calibration of remote sensing satellite instruments. Lunar calibration has been successfully applied to many imagers in orbit, including both MODIS instruments and NPP-VIIRS, using the USGS ROLO model to predict the reference exoatmospheric lunar irradiance. Sensor response trending was developed for SeaWIFS with a relative accuracy better than 0.1 % per year with lunar calibration techniques. However, the Moon rarely is used as an absolute reference for on-orbit calibration, primarily due to uncertainties in the ROLO model absolute scale of 5%-10%. But this limitation lies only with the models - the Moon itself is radiometrically stable, and development of a high-accuracy absolute lunar reference is inherently feasible. A program has been undertaken by NIST to collect absolute measurements of the lunar spectral irradiance with absolute accuracy <1 % (k=2), traceable to SI radiometric units. Initial Moon observations were acquired from the Whipple Observatory on Mt. Hopkins, Arizona, elevation 2367 meters, with continuous spectral coverage from 380 nm to 1040 nm at ~3 nm resolution. The lunar spectrometer acquired calibration measurements several times each observing night by pointing to a calibrated integrating sphere source. The lunar spectral irradiance at the top of the atmosphere was derived from a time series of ground-based measurements by a Langley analysis that incorporated measured atmospheric conditions and ROLO model predictions for the change in irradiance resulting from the changing Sun-Moon-Observer geometry throughout each night. Two nights were selected for further study. An extensive error analysis, which includes instrument calibration and atmospheric correction terms, shows a combined standard uncertainty under 1 % over most of the spectral range. Comparison of these two nights' spectral irradiance measurements with predictions

  15. Metrological activity determination of 133Ba by sum-peak absolute method

    NASA Astrophysics Data System (ADS)

    da Silva, R. L.; de Almeida, M. C. M.; Delgado, J. U.; Poledna, R.; Santos, A.; de Veras, E. V.; Rangel, J.; Trindade, O. L.

    2016-07-01

    The National Laboratory for Metrology of Ionizing Radiation provides gamma sources of radionuclide and standardized in activity with reduced uncertainties. Relative methods require standards to determine the sample activity while the absolute methods, as sum-peak, not. The activity is obtained directly with good accuracy and low uncertainties. 133Ba is used in research laboratories and on calibration of detectors for analysis in different work areas. Classical absolute methods don't calibrate 133Ba due to its complex decay scheme. The sum-peak method using gamma spectrometry with germanium detector standardizes 133Ba samples. Uncertainties lower than 1% to activity results were obtained.

  16. Cryogenic absolute radiometers as laboratory irradiance standards, remote sensing detectors, and pyroheliometers

    NASA Technical Reports Server (NTRS)

    Foukal, Peter V.; Hoyt, C.; Kochling, H.; Miller, P.

    1990-01-01

    The dramatic improvement in heat diffusivity of pure Cu at liquid-He temperatures makes possible very important advances in the absolute accuracy, reproducibility, sensitivity, and time constant of cryogenic electrical substitution radiometers (ESRs), relative to conventional ESRs. The design and characterization of a table-top cryogenic ESR now available for detector calibration work to the 0.01-percent level of absolute accuracy under laser illumination is discussed. A sensitive cryogenic ESR recently delivered to the NIST for radiometric calibrations of black bodies is also described, along with the design and testing of a very fast cryogenic ESR developed for NASA remote-sensing studies of the earth's radiation budget.

  17. Principles and procedures for determining absolute differential electron-molecule (atom) scattering cross sections

    NASA Technical Reports Server (NTRS)

    Nickel, J. C.; Zetner, P. W.; Shen, G.; Trajmar, S.

    1989-01-01

    Procedures and calibration techniques for measuring the absolute elastic and inelastic differential cross sections (DCS) for electron impact on molecular (atomic) species are described and illustrated by examples. The elastic DCS for the molecule under study is first determined by calibration against helium using the relative flow technique. The second step involves the production of energy-loss spectra for the instrument response function, the unfolding of overlapping inelastic structures and the normalization of inelastic intensities to the elastic cross sections. It is concluded that this method of determining absolute differential electron-molecule (atom) scattering cross sections is generally applicable and provides reliable results.

  18. Spectralon diffuser calibration for MERIS

    NASA Astrophysics Data System (ADS)

    Olij, Carina; Schaarsberg, Jos G.; Werij, Henri G.; Zoutman, Erik; Baudin, Gilles; Chommeloux, Beatrice; Bezy, Jean-Loup; Gourmelon, Georges

    1997-12-01

    One of the key payload instruments of ESA's ENVISAT polar platform is the medium resolution imaging spectrometer (MERIS), aiming at improved knowledge of our planet in the fields of bio-optical oceanography, and atmospheric and land surface processes. MERIS, which is built under responsibility of Aerospatiale, will monitor the solar irradiation scattered by the Earth by employing five cameras which simultaneously record data in 15 visible and near-infrared programmable spectral bands with very low degree of polarization sensitivity. The combined field-of-view of the five cameras spans a range of 68.5 degrees. Crucial for obtaining the desired high accuracy during a four-years lifetime, is the on- board calibration unit. This calibration unit contains a set of Spectralon diffusers, which were manufactured having in mind excellent in-flight stability as well as spectral and spatial uniformity. Preflight calibration of the Spectralon diffusers was carried out at TNO-TPD. This calibration includes the measurement of the bidirectional reflectance distribution function (BRDF) for applicable angles and wavelengths, i.e., while varying angle of incidence, angle of observation, observation area on the elongated diffusers, wavelength and polarization. The diffuser calibration was performed in a class 100 cleanroom. For these measurements the TPD calibration facility, which is described in detail, has been adapted, so that it now has five geometrical degrees of freedom. Detectors have been optimized to minimize stray light. Due to extensive commissioning of the calibration setup the absolute error (1 sigma) of these measurements amounts to less than 0.5%; relative errors are in the 0.3 - 0.4% range.

  19. Climate Absolute Radiance and Refractivity Observatory (CLARREO)

    NASA Technical Reports Server (NTRS)

    Leckey, John P.

    2015-01-01

    The Climate Absolute Radiance and Refractivity Observatory (CLARREO) is a mission, led and developed by NASA, that will measure a variety of climate variables with an unprecedented accuracy to quantify and attribute climate change. CLARREO consists of three separate instruments: an infrared (IR) spectrometer, a reflected solar (RS) spectrometer, and a radio occultation (RO) instrument. The mission will contain orbiting radiometers with sufficient accuracy, including on orbit verification, to calibrate other space-based instrumentation, increasing their respective accuracy by as much as an order of magnitude. The IR spectrometer is a Fourier Transform spectrometer (FTS) working in the 5 to 50 microns wavelength region with a goal of 0.1 K (k = 3) accuracy. The FTS will achieve this accuracy using phase change cells to verify thermistor accuracy and heated halos to verify blackbody emissivity, both on orbit. The RS spectrometer will measure the reflectance of the atmosphere in the 0.32 to 2.3 microns wavelength region with an accuracy of 0.3% (k = 2). The status of the instrumentation packages and potential mission options will be presented.

  20. Spectrophotometric determination of zirconium with xylenol orange

    SciTech Connect

    Antepenko, R J

    1982-05-14

    High purity hydride forming metal films are used as hydrogen isotope occluders and function as electrodes in neutron generator tubes. This use of zirconium occluder films requires reliable analytical methods for routine determination of the zirconium film weight in a production environment. In this study, a spectrophotometric method was evaluated for the determination of zirconium films. The method is based upon the formation of a highly colored zirconium complex with xylenol orange in a dilute perchloric acid medium. Dilute hydrofluoric acid is used in this procedure to selectively dissolve the zirconium film off the substrate. A perchloric acid fuming step is used to remove hydrofluoric acid from the solution. The zirconium solutions are depolymerized before complex formation by heating in 2 N perchloric acid. The zirconium complex exhibits a maximum absorbance in 0.2 to 0.3 M perchloric acid at a wavelength of 531 nanometers. Beer's law is obeyed for zirconium concentrations through 2.1 parts per million. Molybdenum, at concentrations equal to zirconium, does not interfere with the xylenol orange method.

  1. 67P/Churyumov-Gerasimenko Spectrophotometric Properties

    NASA Astrophysics Data System (ADS)

    Besse, S.; Fornasier, S.; Sierks, H.; Barucci, M. A.; Leyrat, C.; Hviid, S. F.; Jorda, L.; Keller, H. U.; Küppers, M.; Magrin, S.; Massironi, M.; Oklay, N.; Pajola, M.; Thomas, N.; Tubiana, C.; Snodgrass, C.; Vincent, J. B.

    2014-12-01

    On August 6th 2014, the Rosetta spacecraft entered orbit around the nucleus of comet 67P/Churyumov-Gerasimenko. During its approach, the Optical Spectroscopic and Infrared Remote Imaging System (OSIRIS) observed the nucleus with various illumination conditions and filters to characterize the surface. Observations with resolution of the order of 1m/pixel are scheduled before the end of the year 2014; they will provide incredible detail of the cometary nucleus's surface. The mineralogical and photometric properties of the surface are very important scientific topics to understand the properties of the nucleus, the formation and evolution of its surface, and its relationship with the activity of the comet Here we will present the results of the spectrophotometry obtained with 11 filters covering the 250-1000 nm range (obtained through the Narrow Angle Camera NAC), and of the photometric analysis of the surface of the cometary nucleus taken between July and November 2014. Images span various phase angles (including opposition) and various resolutions, and cover the entire surface of the nucleus. These observations will allow the first global and detailed spectrophotometric characterization of a comet nucleus. Of particular interest is the identification of ices on the surface or not, the mineralogical differences between the two lobes of the nucleus if any, and the global photometric properties.

  2. Ultraviolet spectrophotometric determination of tantalum with pyrogallol

    USGS Publications Warehouse

    Dinnin, J.I.

    1953-01-01

    In a search for a more rapid method for the determination of tantalum in rocks and minerals, an intensive study was made of the tantalum-pyrogallol reaction recommended by Platanov and Krivoshlikov, and a better modified spectrophotometric procedure is given. The improved method consists in measuring the absorbancy of the tantalum-pyrogallol complex at 325 m?? in 4N hydrochloric acid and a fixed concentration (0.0175M) of ammonium oxalate. Beer's law is followed for the concentration range up to 40 ?? per ml. Sensitivity in terms of molar absorbancy index is 4775. Most interferences are additive in character and readily correctable. Separations or major corrections are required in the presence of significant amounts of molybdenum, tungsten, antimony, and uranium. The method has been successfully applied to three ores previously analyzed by gravimetric techniques. The method affords greater speed, sensitivity, and reproducibility in the determination of tantalum in rocks and minerals. A more reliable technique for preparing standard solutions of tantalum has been developed.

  3. Demonstrating the Error Budget for the Climate Absolute Radiance and Refractivity Observatory Through Solar Irradiance Measurements

    NASA Technical Reports Server (NTRS)

    Thome, Kurtis; McCorkel, Joel; McAndrew, Brendan

    2016-01-01

    The Climate Absolute Radiance and Refractivity Observatory (CLARREO) mission addresses the need to observe highaccuracy, long-term climate change trends and to use decadal change observations as a method to determine the accuracy of climate change. A CLARREO objective is to improve the accuracy of SI-traceable, absolute calibration at infrared and reflected solar wavelengths to reach on-orbit accuracies required to allow climate change observations to survive data gaps and observe climate change at the limit of natural variability. Such an effort will also demonstrate National Institute of Standards and Technology (NIST) approaches for use in future spaceborne instruments. The current work describes the results of laboratory and field measurements with the Solar, Lunar for Absolute Reflectance Imaging Spectroradiometer (SOLARIS) which is the calibration demonstration system (CDS) for the reflected solar portion of CLARREO. SOLARIS allows testing and evaluation of calibration approaches, alternate design and/or implementation approaches and components for the CLARREO mission. SOLARIS also provides a test-bed for detector technologies, non-linearity determination and uncertainties, and application of future technology developments and suggested spacecraft instrument design modifications. Results of laboratory calibration measurements are provided to demonstrate key assumptions about instrument behavior that are needed to achieve CLARREO's climate measurement requirements. Absolute radiometric response is determined using laser-based calibration sources and applied to direct solar views for comparison with accepted solar irradiance models to demonstrate accuracy values giving confidence in the error budget for the CLARREO reflectance retrieval.

  4. Demonstrating the error budget for the Climate Absolute Radiance and Refractivity Observatory through solar irradiance measurements

    NASA Astrophysics Data System (ADS)

    Thome, Kurtis; McCorkel, Joel; McAndrew, Brendan

    2015-09-01

    The Climate Absolute Radiance and Refractivity Observatory (CLARREO) mission addresses the need to observe highaccuracy, long-term climate change trends and to use decadal change observations as a method to determine the accuracy of climate change. A CLARREO objective is to improve the accuracy of SI-traceable, absolute calibration at infrared and reflected solar wavelengths to reach on-orbit accuracies required to allow climate change observations to survive data gaps and observe climate change at the limit of natural variability. Such an effort will also demonstrate National Institute of Standards and Technology (NIST) approaches for use in future spaceborne instruments. The current work describes the results of laboratory and field measurements with the Solar, Lunar for Absolute Reflectance Imaging Spectroradiometer (SOLARIS) which is the calibration demonstration system (CDS) for the reflected solar portion of CLARREO. SOLARIS allows testing and evaluation of calibration approaches, alternate design and/or implementation approaches and components for the CLARREO mission. SOLARIS also provides a testbed for detector technologies, non-linearity determination and uncertainties, and application of future technology developments and suggested spacecraft instrument design modifications. Results of laboratory calibration measurements are provided to demonstrate key assumptions about instrument behavior that are needed to achieve CLARREO's climate measurement requirements. Absolute radiometric response is determined using laser-based calibration sources and applied to direct solar views for comparison with accepted solar irradiance models to demonstrate accuracy values giving confidence in the error budget for the CLARREO reflectance retrieval.

  5. Pixel-wise absolute phase unwrapping using geometric constraints of structured light system.

    PubMed

    An, Yatong; Hyun, Jae-Sang; Zhang, Song

    2016-08-01

    This paper presents a method to unwrap phase pixel by pixel by solely using geometric constraints of the structured light system without requiring additional image acquisition or another camera. Specifically, an artificial absolute phase map, Φmin, at a given virtual depth plane z = zmin, is created from geometric constraints of the calibrated structured light system; the wrapped phase is pixel-by-pixel unwrapped by referring to Φmin. Since Φmin is defined in the projector space, the unwrapped phase obtained from this method is absolute for each pixel. Experimental results demonstrate the success of this proposed novel absolute phase unwrapping method. PMID:27505808

  6. Accurate determination of absolute carrier-envelope phase dependence using photo-ionization.

    PubMed

    Sayler, A M; Arbeiter, M; Fasold, S; Adolph, D; Möller, M; Hoff, D; Rathje, T; Fetić, B; Milošević, D B; Fennel, T; Paulus, G G

    2015-07-01

    The carrier-envelope phase (CEP) dependence of few-cycle above-threshold ionization (ATI) of Xe is calibrated for use as a reference measurement for determining and controlling the absolute CEP in other interactions. This is achieved by referencing the CEP-dependent ATI measurements of Xe to measurements of atomic H, which are in turn referenced to ab initio calculations for atomic H. This allows for the accurate determination of the absolute CEP dependence of Xe ATI, which enables relatively easy determination of the offset between the relative CEP measured and/or controlled by typical devices and the absolute CEP in the interaction. PMID:26125386

  7. Absolute concentration measurements inside a jet plume using video digitization

    NASA Astrophysics Data System (ADS)

    Vauquelin, O.

    An experimental system based on digitized video image analysis is used to measure the local value of the concentration inside a plume. Experiments are carried out in a wind-tunnel for a smoke-seeded turbulent jet plume illuminated with a laser beam. Each test is filmed, subsequently video images are digitized and analysed in order to determine the smoke absolute concentration corresponding to each pixel gray level. This non-intrusive measurement technique is first calibrated and different laws connecting gray level to concentration are established. As a first application, concentration measurements are made inside a turbulent jet plume and compared with measurements conducted using a classic gas analysis method. We finally present and discuss the possibilities offered for the measurements of absolute concentration fluctuations.

  8. Precise Measurement of the Absolute Yield of Fluorescence Photons in Atmospheric Gases

    SciTech Connect

    Ave, M.; Bohacova, M.; Daumiller, K.; Di Carlo, P.; Di Giulio, C.; Luis, P.Facal San; Gonzales, D.; Hojvat, C.; Horandel, J.R.; Hrabovsky, M.; Iarlori, M.; /INFN, Aquila /Karlsruhe, Inst. Technol.

    2011-01-01

    We have performed a measurement of the absolute yield of fluorescence photons at the Fermilab Test Beam. A systematic uncertainty at 5% level was achieved by the use of Cherenkov radiation as a reference calibration light source. A cross-check was performed by an independent calibration using a laser light source. A significant improvement on the energy scale uncertainty of Ultra-High Energy Cosmic Rays is expected.

  9. Approaches on calibration of bolometer and establishment of bolometer calibration device

    NASA Astrophysics Data System (ADS)

    Xia, Ming; Gao, Jianqiang; Ye, Jun'an; Xia, Junwen; Yin, Dejin; Li, Tiecheng; Zhang, Dong

    2015-10-01

    Bolometer is mainly used for measuring thermal radiation in the field of public places, labor hygiene, heating and ventilation and building energy conservation. The working principle of bolometer is under the exposure of thermal radiation, temperature of black absorbing layer of detector rise after absorption of thermal radiation, which makes the electromotive force produced by thermoelectric. The white light reflective layer of detector does not absorb thermal radiation, so the electromotive force produced by thermoelectric is almost zero. A comparison of electromotive force produced by thermoelectric of black absorbing layer and white reflective layer can eliminate the influence of electric potential produced by the basal background temperature change. After the electromotive force which produced by thermal radiation is processed by the signal processing unit, the indication displays through the indication display unit. The measurement unit of thermal radiation intensity is usually W/m2 or kW/m2. Its accurate and reliable value has important significance for high temperature operation, labor safety and hygiene grading management. Bolometer calibration device is mainly composed of absolute radiometer, the reference light source, electric measuring instrument. Absolute radiometer is a self-calibration type radiometer. Its working principle is using the electric power which can be accurately measured replaces radiation power to absolutely measure the radiation power. Absolute radiometer is the standard apparatus of laser low power standard device, the measurement traceability is guaranteed. Using the calibration method of comparison, the absolute radiometer and bolometer measure the reference light source in the same position alternately which can get correction factor of irradiance indication. This paper is mainly about the design and calibration method of the bolometer calibration device. The uncertainty of the calibration result is also evaluated.

  10. The AFGL absolute gravity program

    NASA Technical Reports Server (NTRS)

    Hammond, J. A.; Iliff, R. L.

    1978-01-01

    A brief discussion of the AFGL's (Air Force Geophysics Laboratory) program in absolute gravity is presented. Support of outside work and in-house studies relating to gravity instrumentation are discussed. A description of the current transportable system is included and the latest results are presented. These results show good agreement with measurements at the AFGL site by an Italian system. The accuracy obtained by the transportable apparatus is better than 0.1 microns sq sec 10 microgal and agreement with previous measurements is within the combined uncertainties of the measurements.

  11. Familial Aggregation of Absolute Pitch

    PubMed Central

    Baharloo, Siamak; Service, Susan K.; Risch, Neil; Gitschier, Jane; Freimer, Nelson B.

    2000-01-01

    Absolute pitch (AP) is a behavioral trait that is defined as the ability to identify the pitch of tones in the absence of a reference pitch. AP is an ideal phenotype for investigation of gene and environment interactions in the development of complex human behaviors. Individuals who score exceptionally well on formalized auditory tests of pitch perception are designated as “AP-1.” As described in this report, auditory testing of siblings of AP-1 probands and of a control sample indicates that AP-1 aggregates in families. The implications of this finding for the mapping of loci for AP-1 predisposition are discussed. PMID:10924408

  12. Precision Absolute Beam Current Measurement of Low Power Electron Beam

    SciTech Connect

    Ali, M. M.; Bevins, M. E.; Degtiarenko, P.; Freyberger, A.; Krafft, G. A.

    2012-11-01

    Precise measurements of low power CW electron beam current for the Jefferson Lab Nuclear Physics program have been performed using a Tungsten calorimeter. This paper describes the rationale for the choice of the calorimeter technique, as well as the design and calibration of the device. The calorimeter is in use presently to provide a 1% absolute current measurement of CW electron beam with 50 to 500 nA of average beam current and 1-3 GeV beam energy. Results from these recent measurements will also be presented.

  13. SHARDS: AN OPTICAL SPECTRO-PHOTOMETRIC SURVEY OF DISTANT GALAXIES

    SciTech Connect

    Perez-Gonzalez, Pablo G.; Cava, Antonio; Barro, Guillermo; Villar, Victor; Cardiel, Nicolas; Espino, Nestor; Gallego, Jesus; Ferreras, Ignacio; Rodriguez-Espinosa, Jose Miguel; Balcells, Marc; Cepa, Jordi; Alonso-Herrero, Almudena; Cenarro, Javier; Charlot, Stephane; Cimatti, Andrea; Conselice, Christopher J.; Daddi, Emmanuele; Elbaz, David; Gobat, R. [Laboratoire AIM-Paris-Saclay, CEA and others

    2013-01-01

    We present the Survey for High-z Absorption Red and Dead Sources (SHARDS), an ESO/GTC Large Program carried out using the OSIRIS instrument on the 10.4 m Gran Telescopio Canarias (GTC). SHARDS is an ultra-deep optical spectro-photometric survey of the GOODS-N field covering 130 arcmin{sup 2} at wavelengths between 500 and 950 nm with 24 contiguous medium-band filters (providing a spectral resolution R {approx} 50). The data reach an AB magnitude of 26.5 (at least at a 3{sigma} level) with sub-arcsec seeing in all bands. SHARDS' main goal is to obtain accurate physical properties of intermediate- and high-z galaxies using well-sampled optical spectral energy distributions (SEDs) with sufficient spectral resolution to measure absorption and emission features, whose analysis will provide reliable stellar population and active galactic nucleus (AGN) parameters. Among the different populations of high-z galaxies, SHARDS' principal targets are massive quiescent galaxies at z > 1, whose existence is one of the major challenges facing current hierarchical models of galaxy formation. In this paper, we outline the observational strategy and include a detailed discussion of the special reduction and calibration procedures which should be applied to the GTC/OSIRIS data. An assessment of the SHARDS data quality is also performed. We present science demonstration results on the detection and study of emission-line galaxies (star-forming objects and AGNs) at z = 0-5. We also analyze the SEDs for a sample of 27 quiescent massive galaxies with spectroscopic redshifts in the range 1.0 < z {approx}< 1.4. We discuss the improvements introduced by the SHARDS data set in the analysis of their star formation history and stellar properties. We discuss the systematics arising from the use of different stellar population libraries, typical in this kind of study. Averaging the results from the different libraries, we find that the UV-to-MIR SEDs of the massive quiescent galaxies at z = 1

  14. Lunar eclipse photometry: absolute luminance measurements and modeling.

    PubMed

    Hernitschek, Nina; Schmidt, Elmar; Vollmer, Michael

    2008-12-01

    The Moon's time-dependent luminance was determined during the 9 February 1990 and 3 March 2007 total lunar eclipses by using calibrated, industry standard photometers. After the results were corrected to unit air mass and to standard distances for both Moon and Sun, an absolute calibration was accomplished by using the Sun's known luminance and a pre-eclipse lunar albedo of approximately 13.5%. The measured minimum level of brightness in the total phase of both eclipses was relatively high, namely -3.32 m(vis) and -1.7 m(vis), which hints at the absence of pronounced stratospheric aerosol. The light curves were modeled in such a way as to let the Moon move through an artificial Earth shadow composed of a multitude of disk and ring zones, containing a relative luminance data set from an atmospheric radiative transfer calculation. PMID:19037352

  15. Lunar eclipse photometry: absolute luminance measurements and modeling.

    PubMed

    Hernitschek, Nina; Schmidt, Elmar; Vollmer, Michael

    2008-12-01

    The Moon's time-dependent luminance was determined during the 9 February 1990 and 3 March 2007 total lunar eclipses by using calibrated, industry standard photometers. After the results were corrected to unit air mass and to standard distances for both Moon and Sun, an absolute calibration was accomplished by using the Sun's known luminance and a pre-eclipse lunar albedo of approximately 13.5%. The measured minimum level of brightness in the total phase of both eclipses was relatively high, namely -3.32 m(vis) and -1.7 m(vis), which hints at the absence of pronounced stratospheric aerosol. The light curves were modeled in such a way as to let the Moon move through an artificial Earth shadow composed of a multitude of disk and ring zones, containing a relative luminance data set from an atmospheric radiative transfer calculation.

  16. Absolute stellar photometry on moderate-resolution FPA images

    USGS Publications Warehouse

    Stone, T.C.

    2009-01-01

    An extensive database of star (and Moon) images has been collected by the ground-based RObotic Lunar Observatory (ROLO) as part of the US Geological Survey program for lunar calibration. The stellar data are used to derive nightly atmospheric corrections for the observations from extinction measurements, and absolute calibration of the ROLO sensors is based on observations of Vega and published reference flux and spectrum data. The ROLO telescopes were designed for imaging the Moon at moderate resolution, thus imposing some limitations for the stellar photometry. Attaining accurate stellar photometry with the ROLO image data has required development of specialized processing techniques. A key consideration is consistency in discriminating the star core signal from the off-axis point spread function. The analysis and processing methods applied to the ROLO stellar image database are described. ?? 2009 BIPM and IOP Publishing Ltd.

  17. Technique for calibrating angular measurement devices when calibration standards are unavailable

    NASA Technical Reports Server (NTRS)

    Finley, Tom D.

    1991-01-01

    A calibration technique is proposed that will allow the calibration of certain angular measurement devices without requiring the use of absolute standard. The technique assumes that the device to be calibrated has deterministic bias errors. A comparison device must be available that meets the same requirements. The two devices are compared; one device is then rotated with respect to the other, and a second comparison is performed. If the data are reduced using the described technique, the individual errors of the two devices can be determined.

  18. Revised Landsat-5 TM Radiometrie Calibration Procedures and Postcalibration Dynamic Ranges

    USGS Publications Warehouse

    Chander, G.; Markham, B.

    2003-01-01

    Effective May 5, 2003, Landsat-5 (L5) Thematic Mapper (TM) data processed and distributed by the U.S. Geological Survey (USGS) Earth Resources Observation System (EROS) Data Center (EDC) will be radiometrically calibrated using a new procedure and revised calibration parameters. This change will improve absolute calibration accuracy, consistency over time, and consistency with Landsat-7 (L7) Enhanced Thematic Mapper Plus (ETM+) data. Users will need to use new parameters to convert the calibrated data products to radiance. The new procedure for the reflective bands (1-5,7) is based on a lifetime radiometric calibration curve for the instrument derived from the instrument's internal calibrator, cross-calibration with the ETM+, and vicarious measurements. The thermal band will continue to be calibrated using the internal calibrator. Further updates to improve the relative detector-to-detector calibration and thermal band calibration are being investigated, as is the calibration of the Landsat-4 (L4) TM.

  19. Spectrophotometric Investigations of Macrolide Antibiotics: A Brief Review

    PubMed Central

    Keskar, Mrudul R; Jugade, Ravin M

    2015-01-01

    Macrolides, one of the most commonly used class of antibiotics, are a group of drugs produced by Streptomyces species. They belong to the polyketide class of natural products. Their activity is due to the presence of a large macrolide lactone ring with deoxy sugar moieties. They are protein synthesis inhibitors and broad-spectrum antibiotics, active against both gram-positive and gram-negative bacteria. Different analytical techniques have been reported for the determination of macrolides such as chromatographic methods, flow injection methods, spectrofluorometric methods, spectrophotometric methods, and capillary electrophoresis methods. Among these methods, spectrophotometric methods are sensitive and cost effective for the analysis of various antibiotics in pharmaceutical formulations as well as biological samples. This article reviews different spectrophotometric methods for the determination of macrolide antibiotics. PMID:26609215

  20. Cross-calibration between airborne SAR sensors

    NASA Technical Reports Server (NTRS)

    Zink, Manfred; Olivier, Philippe; Freeman, Anthony

    1993-01-01

    As Synthetic Aperture Radar (SAR) system performance and experience in SAR signature evaluation increase, quantitative analysis becomes more and more important. Such analyses require an absolute radiometric calibration of the complete SAR system. To keep the expenditure on calibration of future multichannel and multisensor remote sensing systems (e.g., X-SAR/SIR-C) within a tolerable level, data from different tracks and different sensors (channels) must be cross calibrated. The 1989 joint E-SAR/DC-8 SAR calibration campaign gave a first opportunity for such an experiment, including cross sensor and cross track calibration. A basic requirement for successful cross calibration is the stability of the SAR systems. The calibration parameters derived from different tracks and the polarimetric properties of the uncalibrated data are used to describe this stability. Quality criteria for a successful cross calibration are the agreement of alpha degree values and the consistency of radar cross sections of equally sized corner reflectors. Channel imbalance and cross talk provide additional quality in case of the polarimetric DC-8 SAR.

  1. COBE differential microwave radiometers - Calibration techniques

    NASA Technical Reports Server (NTRS)

    Bennett, C. L.; Smoot, G. F.; Janssen, M.; Gulkis, S.; Kogut, A.; Hinshaw, G.; Backus, C.; Hauser, M. G.; Mather, J. C.; Rokke, L.

    1992-01-01

    The COBE spacecraft was launched November 18, 1989 UT carrying three scientific instruments into earth orbit for studies of cosmology. One of these instruments, the Differential Microwave Radiometer (DMR), is designed to measure the large-angular-scale temperature anisotropy of the cosmic microwave background radiation at three frequencies (31.5, 53, and 90 GHz). This paper presents three methods used to calibrate the DMR. First, the signal difference between beam-filling hot and cold targets observed on the ground provides a primary calibration that is transferred to space by noise sources internal to the instrument. Second, the moon is used in flight as an external calibration source. Third, the signal arising from the Doppler effect due to the earth's motion around the barycenter of the solar system is used as an external calibration source. Preliminary analysis of the external source calibration techniques confirms the accuracy of the currently more precise ground-based calibration. Assuming the noise source behavior did not change from the ground-based calibration to flight, a 0.1-0.4 percent relative and 0.7-2.5 percent absolute calibration uncertainty is derived, depending on radiometer channel.

  2. Cosmology with negative absolute temperatures

    NASA Astrophysics Data System (ADS)

    Vieira, J. P. P.; Byrnes, Christian T.; Lewis, Antony

    2016-08-01

    Negative absolute temperatures (NAT) are an exotic thermodynamical consequence of quantum physics which has been known since the 1950's (having been achieved in the lab on a number of occasions). Recently, the work of Braun et al. [1] has rekindled interest in negative temperatures and hinted at a possibility of using NAT systems in the lab as dark energy analogues. This paper goes one step further, looking into the cosmological consequences of the existence of a NAT component in the Universe. NAT-dominated expanding Universes experience a borderline phantom expansion (w < ‑1) with no Big Rip, and their contracting counterparts are forced to bounce after the energy density becomes sufficiently large. Both scenarios might be used to solve horizon and flatness problems analogously to standard inflation and bouncing cosmologies. We discuss the difficulties in obtaining and ending a NAT-dominated epoch, and possible ways of obtaining density perturbations with an acceptable spectrum.

  3. Apparatus for absolute pressure measurement

    NASA Technical Reports Server (NTRS)

    Hecht, R. (Inventor)

    1969-01-01

    An absolute pressure sensor (e.g., the diaphragm of a capacitance manometer) was subjected to a superimposed potential to effectively reduce the mechanical stiffness of the sensor. This substantially increases the sensitivity of the sensor and is particularly useful in vacuum gauges. An oscillating component of the superimposed potential induced vibrations of the sensor. The phase of these vibrations with respect to that of the oscillating component was monitored, and served to initiate an automatic adjustment of the static component of the superimposed potential, so as to bring the sensor into resonance at the frequency of the oscillating component. This establishes a selected sensitivity for the sensor, since a definite relationship exists between resonant frequency and sensitivity.

  4. Cosmology with negative absolute temperatures

    NASA Astrophysics Data System (ADS)

    Vieira, J. P. P.; Byrnes, Christian T.; Lewis, Antony

    2016-08-01

    Negative absolute temperatures (NAT) are an exotic thermodynamical consequence of quantum physics which has been known since the 1950's (having been achieved in the lab on a number of occasions). Recently, the work of Braun et al. [1] has rekindled interest in negative temperatures and hinted at a possibility of using NAT systems in the lab as dark energy analogues. This paper goes one step further, looking into the cosmological consequences of the existence of a NAT component in the Universe. NAT-dominated expanding Universes experience a borderline phantom expansion (w < -1) with no Big Rip, and their contracting counterparts are forced to bounce after the energy density becomes sufficiently large. Both scenarios might be used to solve horizon and flatness problems analogously to standard inflation and bouncing cosmologies. We discuss the difficulties in obtaining and ending a NAT-dominated epoch, and possible ways of obtaining density perturbations with an acceptable spectrum.

  5. Spectrophotometric Procedure for Fast Reactor Advanced Coolant Manufacture Control

    NASA Astrophysics Data System (ADS)

    Andrienko, O. S.; Egorov, N. B.; Zherin, I. I.; Indyk, D. V.

    2016-01-01

    The paper describes a spectrophotometric procedure for fast reactor advanced coolant manufacture control. The molar absorption coefficient of dimethyllead dibromide with dithizone was defined as equal to 68864 ± 795 l·mole-1·cm-1, limit of detection as equal to 0.583 · 10-6 g/ml. The spectrophotometric procedure application range was found to be equal to 37.88 - 196.3 g. of dimethyllead dibromide in the sample. The procedure was used within the framework of the development of the method of synthesis of the advanced coolant for fast reactors.

  6. Interference by Gastrografin with a spectrophotometric trypsin assay

    PubMed Central

    Cowen, A. E.; McGeary, Heather M.; Campbell, C. B.

    1972-01-01

    Small quantities of Gastrografin remaining in the intestinal tract some hours after introduction have been shown to cause falsely low trypsin values as determined by a spectrophotometric assay system. This interference is due first to the high absorbance of Gastrografin at 254 nm resulting in a falsely high background optical density. Secondly, Gastrografin inhibits esterase activity towards the synthetic substrate used in this assay. Gastrografin did not interfere with gelatin proteolysis by trypsin and did not affect amylase or lipase determination. Thus the instillation of Gastrografin into the duodenum before pancreatic function tests should be avoided when the trypsin content is to be determined spectrophotometrically. PMID:5036096

  7. The formation of galaxy bulges: Spectrophotometric constraints

    NASA Astrophysics Data System (ADS)

    Prugniel, Ph.; Maubon, G.; Simien, F.

    2001-01-01

    We have measured Mg2, Fe 5270 and Fe 5335 spectrophotometric indices (LICK system) in the bulge of 89 galaxies, mostly spirals from the Héraudeau (\\cite{her96}) sample. The indices are reduced to a null velocity dispersion and normalized to an aperture of 0.2 h-1 kpc. The mean errors are 0.009 mag on Mg2, and 0.3 Å on the iron indices. These measurements almost double the amount of similar data already available on spiral galaxies. Our data confirm the existence of the relation between Mg2, and sigma0, the central stellar velocity dispersion; we find an even tighter relation between Mg2, and Vmrot, the maximum rotational velocity of the galaxy, deduced from HI observations. For the most massive bulges, these correlations may be interpreted as a mass-metallicity relation. However, the presence of young stellar populations, traced by the detection of [OIII] lambda 5007 Å, emission, provides clear evidence that age effects do play a role. Since the contribution of the young population is anti-correlated to the mass of the galaxy, it continues the Mg2, vs. sigma0 , relation toward the low-sigma0, region and globally increases its slope. We also present evidence for a new positive correlation between Fe indices and sigma0, and for a significant correlation between the line-strength indices and the total or disk luminosity. We propose to model the whole sequence of bulges within the folowing framework: bulges are composed of a primary population formed prior to the disk, during the initial collapse, and of a secondary population formed during its evolution. The whole family of bulges can be classified into three classes: (A) the bulges dominated by young populations are generally small, have ionized gas, low velocity dispersion and low line strengths; (B) the bulges dominated by the primary population lie along the mass-metallicity sequence defined for elliptical galaxies; and (C) the bulges where the secondary population is significant are less Mg-over-abundant than

  8. Simultaneous spectrophotometric determination of trace amount of polycyclic aromatic hydrocarbons in water samples after magnetic solid-phase extraction by using projection pursuit regression.

    PubMed

    Ghasemi, Jahan B; Zolfonoun, E

    2013-03-01

    Magnetic solid-phase extraction based on coated nano-magnets Fe(3)O(4) was applied for the preconcentration of four polycyclic aromatic hydrocarbons (PAHs; anthracene, phenanthrene, fluorine, and pyrene) in environmental water samples prior to simultaneous spectrophotometric determination using multivariate calibration method. Magnetic nanoparticles, carrying target metals, were easily separated from the aqueous solution by applying an external magnetic field so, no filtration or centrifugation was necessary. After elution of the adsorbed PAHs, the concentration of PAHs was determined spectrophotometrically with the aid of a new and efficient multivariate spectral analysis base on principal component analysis-projection pursuit regression, without separation of analytes. The obtained results revealed that using projection pursuit regression as a flexible modeling approach improves the predictive quality of the developed models compared with partial least squares and least squares support vector machine methods. The method was used to determine four PAHs in environmental water samples.

  9. Calibration of sound calibrators: an overview

    NASA Astrophysics Data System (ADS)

    Milhomem, T. A. B.; Soares, Z. M. D.

    2016-07-01

    This paper presents an overview of calibration of sound calibrators. Initially, traditional calibration methods are presented. Following, the international standard IEC 60942 is discussed emphasizing parameters, target measurement uncertainty and criteria for conformance to the requirements of the standard. Last, Regional Metrology Organizations comparisons are summarized.

  10. Aquarius L-Band Radiometers Calibration Using Cold Sky Observations

    NASA Technical Reports Server (NTRS)

    Dinnat, Emmanuel P.; Le Vine, David M.; Piepmeier, Jeffrey R.; Brown, Shannon T.; Hong, Liang

    2015-01-01

    An important element in the calibration plan for the Aquarius radiometers is to look at the cold sky. This involves rotating the satellite 180 degrees from its nominal Earth viewing configuration to point the main beams at the celestial sky. At L-band, the cold sky provides a stable, well-characterized scene to be used as a calibration reference. This paper describes the cold sky calibration for Aquarius and how it is used as part of the absolute calibration. Cold sky observations helped establish the radiometer bias, by correcting for an error in the spillover lobe of the antenna pattern, and monitor the long-term radiometer drift.

  11. SI-Traceable Calibrations of Celestial Objects

    NASA Astrophysics Data System (ADS)

    Cramer, C. E.; Lykke, K. R.; Woodward, J. T.

    2016-05-01

    Photometric calibration is currently the leading source of systematic uncertainty in supernova surveys that aim to determine the nature of dark energy. The bulk of this uncertainty is due to imperfect knowledge of the spectral energy distribution of stars used as primary standards. We review the challenges associated with establishing an absolute calibration of stellar spectra and describe how it is possible to do better by using recent advances in optical metrology, paying particular attention to the measurement chain establishing SI-traceability and reporting of measurement uncertainties.

  12. Continued Monitoring of Landsat Reflective Band Calibration Using Pseudo-Invariant Calibration Sites

    NASA Technical Reports Server (NTRS)

    Barsi, Julia A.; Markham, Brian L.; Helder, Dennis L.

    2012-01-01

    Though both of the current Landsat instruments, Landsat-7 Enhanced Thematic Mapper+ (ETM+) and Landsat-5 Thematic Mapper (TM), include on-board calibration systems, since 2001, pseudo-invariant calibration sites (PICS) have been added to the suite of metrics to assess the instruments calibration. These sites do not provide absolute calibration data since there are no ground measurements of the sites, but in monitoring these PICS over time, the relative calibration can be tracked. The sites used by the Landsat instruments are primarily in the Saharan Desert. To date, the trending from the PICS sites has confirmed that most of the degradation seen in the ETM+ on-board calibration systems is likely not degradation of the instrument, but rather degradation of the calibration systems themselves. However, the PICS data show statistically significant degradation (at 2-sigma) in all the reflective spectral bands of up to -0.22%/year since July 2003. For the TM, the PICS were instrumental in updating the calibration in 2007 and now suggest two bands may require another update. The data show a statistically significant degradation (at 2-sigma) in Bands 1 and 3 of -0.27 and -0.15%/year, respectively, since March 1999. The data filtering and processing methods are currently being reviewed but these PICS results may lead to an update in the reflective band calibration of both Landsat-7 and Landsat-5.

  13. Improving the Generic Camera Calibration Technique by an Extended Model of Calibration Display

    NASA Astrophysics Data System (ADS)

    Reh, T.; Li, W.; Burke, J.; Bergmann, R. B.

    2014-10-01

    Generic camera calibration is a method to characterize vision sensors by describing a line of sight for every single pixel. This procedure frees the calibration process from the restriction to pinhole-like optics that arises in the common photogrammetric camera models. Generic camera calibration also enables the calibration of high-frequency distortions, which is beneficial for high-precision measurement systems. The calibration process is as follows: To collect sufficient data for calculating a line of sight for each pixel, active grids are used as calibration reference rather than static markers such as corners of chessboard patterns. A common implementation of active grids are sinusoidal fringes presented on a flat TFT display. So far, the displays have always been treated as ideally flat. In this work we propose new and more sophisticated models to account for additional properties of the active grid display: The refraction of light in the glass cover is taken into account as well as a possible deviation of the top surface from absolute flatness. To examine the effectiveness of the new models, an example fringe projection measurement system is characterized with the resulting calibration methods and with the original generic camera calibration. Evaluating measurements using the different calibration methods shows that the extended display model substantially improves the uncertainty of the measurement system.

  14. The Gaia spectrophotometric standard stars survey: II. Instrumental effects of six ground-based observing campaigns

    NASA Astrophysics Data System (ADS)

    Altavilla, G.; Marinoni, S.; Pancino, E.; Galleti, S.; Ragaini, S.; Bellazzini, M.; Cocozza, G.; Bragaglia, A.; Carrasco, J. M.; Castro, A.; Di Fabrizio, L.; Federici, L.; Figueras, F.; Gebran, M.; Jordi, C.; Masana, E.; Schuster, W.; Valentini, G.; Voss, H.

    2015-08-01

    The Gaia SpectroPhotometric Standard Stars (SPSS) survey started in 2006, was awarded almost 450 observing nights and accumulated almost 100 000 raw data frames with both photometric and spectroscopic observations. Such large observational effort requires careful, homogeneous, and automatic data reduction and quality control procedures. In this paper, we quantitatively evaluate instrumental effects that might have a significant (i.e., ≥ 1 %) impact on the Gaia SPSS flux calibration. The measurements involve six different instruments, monitored over the eight years of observations dedicated to the Gaia flux standards campaigns: DOLORES@TNG in La Palma, EFOSC2@NTT and ROSS@REM in La Silla, CAFOS@2.2 m in Calar Alto, BFOSC@Cassini in Loiano, and LaRuca@1.5 m in San Pedro Mártir. We examine and quantitatively evaluate the following effects: CCD linearity and shutter times, calibration frames stability, lamp flexures, second order contamination, light polarization, and fringing. We present methods to correct for the relevant effects which can be applied to a wide range of observational projects at similar instruments. Based on data obtained with BFOSC@Cassini in Loiano, Italy; EFOSC2@NTT in La Silla, Chile; DOLORES@TNG in La Palma, Spain; CAFOS@2.2 m in Calar Alto, Spain; LaRuca@1.5 m in San Pedro Mártir, Mexico (see acknowledgements for more details).

  15. Spectrophotometric Properties of Gaspra’s Surface

    NASA Astrophysics Data System (ADS)

    Domingue, Deborah L.; Vilas, Faith; Stockstill-Cahill, Karen; Cahill, Joshua; Hendrix, Amanda

    2015-11-01

    Using the shape-model derived for Gaspra [1] we calculate the local incidence, emission, and phase angles on a pixel-by-pixel basis for the color image sets (164 m/px spatial resolution) acquired by the Galileo Solid State Imager (SSI) [2]. Using these geometric values, we derive a disk-resolved photometric correction for application to the to the spectral data set for more accurate regional examination of mineralogy and weathering across the surface. We use regional variations in color ratios of Gaspra’s surface to examine the degree of space weathering incurred upon the surface, and find subtle variations across its surface. Using mixing modeling methods that account for submicroscopic components, we examine evidence for space weathering variations correlated to composition and grain size. We note evidence of a young surface, with only moderate modification by space weathering processes. SSI radiometrically-calibrated data combined with shape-model derived incidence, emission, and phase angle backplanes have been archived in the Planetary Data System for broader use by the community [3, 4].[1] P. Thomas et al. 1994, Icarus 107, 23 - 36. [2] M. Belton et al. 1992, Science 257, 1647 - 1652. [3] D. Domingue 2015, Galileo SSI/Gaspra Radiometrically Calibrated Images V1.0. NASA PDS. [4] D. Domingue 2015, Galileo SSI/Gaspra Color and Geometry Image Cubes V1.0. NASA PDS, submitted.

  16. Preparation and Spectrophotometric Analysis of Hexaamminenickel(II) Chloride.

    ERIC Educational Resources Information Center

    Wieder, Grace M.

    1986-01-01

    Describes an experiment developed at Brooklyn College (New York) in which the preparation and ammonia analysis of an amminenickel(II) chloride is extended to include a spectrophotometric analysis for nickel. Discusses the materials needed and the procedure for the experiment which takes nine hours of laboratory work. (TW)

  17. Spectrophotometric Titration of a Mixture of Calcium and Magnesium.

    ERIC Educational Resources Information Center

    Fulton, Robert; And Others

    1986-01-01

    Describes a spectrophotometric titration experiment which uses a manual titration spectrophotometer and manually operated buret, rather than special instrumentation. Identifies the equipment, materials, and procedures needed for the completion of the experiment. Recommends the use of this experiment in introductory quantitative analysis…

  18. Absolute surface reconstruction by slope metrology and photogrammetry

    NASA Astrophysics Data System (ADS)

    Dong, Yue

    Developing the manufacture of aspheric and freeform optical elements requires an advanced metrology method which is capable of inspecting these elements with arbitrary freeform surfaces. In this dissertation, a new surface measurement scheme is investigated for such a purpose, which is to measure the absolute surface shape of an object under test through its surface slope information obtained by photogrammetric measurement. A laser beam propagating toward the object reflects on its surface while the vectors of the incident and reflected beams are evaluated from the four spots they leave on the two parallel transparent windows in front of the object. The spots' spatial coordinates are determined by photogrammetry. With the knowledge of the incident and reflected beam vectors, the local slope information of the object surface is obtained through vector calculus and finally yields the absolute object surface profile by a reconstruction algorithm. An experimental setup is designed and the proposed measuring principle is experimentally demonstrated by measuring the absolute surface shape of a spherical mirror. The measurement uncertainty is analyzed, and efforts for improvement are made accordingly. In particular, structured windows are designed and fabricated to generate uniform scattering spots left by the transmitted laser beams. Calibration of the fringe reflection instrument, another typical surface slope measurement method, is also reported in the dissertation. Finally, a method for uncertainty analysis of a photogrammetry measurement system by optical simulation is investigated.

  19. An Absolute Measurement of Resonance-Resolved Electron Impact Excitation

    NASA Astrophysics Data System (ADS)

    Reisenfeld, Daniel Brett

    1998-11-01

    An experiment to measure electron-impact excitation (EIE) of multiply-charged ions is described. An absolute measurement has been carried out of the cross section for EIE of Si2+(3s2/ 1S/to3s3p/ 1P) from energies below threshold to 11 eV above. A beams modulation technique with inclined electron and ion beams was used. Radiation at 120.7 nm from the excited ions was detected using an absolutely calibrated optical system. The analysis of the experimental data requires a determination of the population fraction of the Si2+ (3s3p/ 3Po) metastable state in the incident ion beam, which was measured to be 0.210 ± 0.018. The data have been corrected for contributions to the signal from radiative decay following excitation from the metastable state to 3s3p1P and 3p2/ 3P, and excitation of the ground state to levels above 3s3p/ 1P. The experimental 0.56 ± 0.08 eV energy spread has allowed us to resolve complex resonance structure throughout the studied energy range. At the reported ±14% uncertainty level (90% confidence limit), the measured structure and absolute scale of the cross section are in good agreement with 12-state close-coupling R-matrix calculations.

  20. Absolute brightness temperature measurements at 3.5-mm wavelength. [of sun, Venus, Jupiter and Saturn

    NASA Technical Reports Server (NTRS)

    Ulich, B. L.; Rhodes, P. J.; Davis, J. H.; Hollis, J. M.

    1980-01-01

    Careful observations have been made at 86.1 GHz to derive the absolute brightness temperatures of the sun (7914 + or - 192 K), Venus (357.5 + or - 13.1 K), Jupiter (179.4 + or - 4.7 K), and Saturn (153.4 + or - 4.8 K) with a standard error of about three percent. This is a significant improvement in accuracy over previous results at millimeter wavelengths. A stable transmitter and novel superheterodyne receiver were constructed and used to determine the effective collecting area of the Millimeter Wave Observatory (MWO) 4.9-m antenna relative to a previously calibrated standard gain horn. The thermal scale was set by calibrating the radiometer with carefully constructed and tested hot and cold loads. The brightness temperatures may be used to establish an absolute calibration scale and to determine the antenna aperture and beam efficiencies of other radio telescopes at 3.5-mm wavelength.

  1. Absolute configuration of isovouacapenol C

    PubMed Central

    Fun, Hoong-Kun; Yodsaoue, Orapun; Karalai, Chatchanok; Chantrapromma, Suchada

    2010-01-01

    The title compound, C27H34O5 {systematic name: (4aR,5R,6R,6aS,7R,11aS,11bR)-4a,6-dihy­droxy-4,4,7,11b-tetra­methyl-1,2,3,4,4a,5,6,6a,7,11,11a,11b-dodeca­hydro­phenanthro[3,2-b]furan-5-yl benzoate}, is a cassane furan­oditerpene, which was isolated from the roots of Caesalpinia pulcherrima. The three cyclo­hexane rings are trans fused: two of these are in chair conformations with the third in a twisted half-chair conformation, whereas the furan ring is almost planar (r.m.s. deviation = 0.003 Å). An intra­molecular C—H⋯O inter­action generates an S(6) ring. The absolute configurations of the stereogenic centres at positions 4a, 5, 6, 6a, 7, 11a and 11b are R, R, R, S, R, S and R, respectively. In the crystal, mol­ecules are linked into infinite chains along [010] by O—H⋯O hydrogen bonds. C⋯O [3.306 (2)–3.347 (2) Å] short contacts and C—H⋯π inter­actions also occur. PMID:21588364

  2. Spectrophotometric determination of isopropamide iodide and trifluoperazine hydrochloride in presence of trifluoperazine oxidative degradate.

    PubMed

    Abbas, Samah S; Zaazaa, Hala E; Abdelkawy, M; Abdelrahman, Maha M

    2010-04-01

    Four sensitive, selective and precise stability indicating methods for the determination of isopropamide iodide (ISO) and trifluoperazine hydrochloride (TPZ) in their binary mixture and in presence of trifluoperazine oxidative degradate (OXD). Method A is a derivative spectrophotometric one, where ISO was determined by first derivative (D(1)) at 226.4 nm while TPZ was determined by second derivative (D(2)) at 270.2 nm. Method B is the first derivative of the ratio spectra (DD(1)) spectrophotometric method, ISO can be determined by measuring the peak amplitude at 227.4 nm using 5 microg mL(-1) of OXD as a divisor, while TPZ can be determined by measuring the peak amplitude at 249.2 and 261.4 nm using 15 microg mL(-1) of ISO as a divisor. Method C is the isoabsorptive spectrophotometric method. This method allows determination of ISO and TPZ in their binary mixture by measuring total concentration of ISO and TPZ at their isoabsorptive point at lambda(229.8) nm (Aiso1) while TPZ concentration alone can be determined at lambda(max) 311.2 nm, then ISO concentration can be determined by subtraction. On the same basis TPZ can be determined in presence of ISO and OXD, where OXD concentration alone was determined by measuring the peak amplitude at lambda(281.6) and lambda(309.4) nm while total concentration of TPZ and OXD was determined at their isoabsorptive points at (Aiso2 = 270.2 nm), (Aiso3 = 310.6 nm) and (Aiso4 = 331.8 nm) then TPZ concentration was determined by subtraction. Method D is the multivariate calibration techniques [the classical least squares (CLS), principal component regression (PCR) and partial least squares (PLS)], using the information contained in the absorption spectra of ISO, TPZ and OXD mixtures. The selectivity of the proposed methods was checked using laboratory prepared mixtures. The proposed methods have been successfully applied to the analysis of ISO and TPZ in pharmaceutical dosage form without interference from other dosage form

  3. [Spectrophotometric determination of scandium,gallium and vanadium in white cabbage leaves].

    PubMed

    Buhl, F; Połedniok, J

    1997-01-01

    Scandium, gallium and vanadium contents in plants is on the ppm level, although plants from industrial areas can show higher concentrations of these elements. In Department of Analytical Chemistry of Silesian University there have been elaborated new, sensitive, spectrophotometric methods of determination of scandium, gallium and vanadium using Chrome Azurol S (CAS) and Sterinol (ST). The aim of this study was the application of these methods in analysis of cultivated plants from polluted regions. White cabbage from Upper Silesia was chosen. Because the spectrophotometric methods are not selective, scandium, gallium and vanadium should be preliminary separated from interfering elements. The solvent reaction was applied for the isolation from main and trace components of investigated material. Tienoiltrifluoracetone solution in xylene was used for the extraction of scandium, mesithyloxide for vanadium and n-butyl acetate--for gallium. Interfering and not separated Fe(III) was isolated using the extraction with acetylacetone solution in CHCl3 in the case of scandium and the reduction to Fe(II) by ascorbic acid in the case of gallium and vanadium. Due to influence of Fe(II) on the vanadium determination, KCN was used as a masking agent directly after the reduction. Scandium, gallium and vanadium were determined in 6 independent samples of white cabbage after dry or wet mineralization and contents of these leemnets were found from calibration graphs. Obtain results were checked by the internal standard addition method and Atomic Emission Spectrometry Method (ICP AES). The amounts of gallium and vanadium in white cabbage from Upper Silesia District determined by elaborated methods are in good correlation with a literature data, although the contents of vanadium are on the toxic level. The scandium concentration is higher than in plants from not industrial areas. The standard recovery is satisfactory. The Atomic Emission Spectrometry Method gave comparable results. The

  4. Automated spectrophotometric analyzer for rapid single-point titration of seawater total alkalinity.

    PubMed

    Li, Quanlong; Wang, Fengzhen; Wang, Zhaohui Aleck; Yuan, Dongxing; Dai, Minhan; Chen, Jinshun; Dai, Junwei; Hoering, Katherine A

    2013-10-01

    An automated analyzer was developed to achieve fast, precise, and accurate measurements of seawater total alkalinity (AT) based on single-point titration and spectrophotometric pH detection. The single-point titration was carried out in a circulating loop, which allowed the titrant (hydrochloric acid and bromocresol green solution) and a seawater sample to mix at a constant volume ratio. The dissolved CO2 in the sample-titrant mixture was efficiently removed by an inline CO2 remover, which consists of a gas-permeable tubing (Teflon AF2400) submerged in a sodium hydroxide (NaOH) solution. The pH of the mixture was then measured with a custom-made spectrophotometric detection system. The analyzer was calibrated against multiple certified reference materials (CRMs) with different AT values. The analyzer features a sample throughput time of 6.5 min with high precision (±0.33-0.36 μmol kg(-1); n = 48) and accuracy (-0.33 ± 0.99 μmol kg(-1); n = 10). Intercomparison to a traditional open-cell AT titrator showed overall good agreement of 0.88 ± 2.03 μmol kg(-1) (n = 22). The analyzer achieved excellent stability without recalibration over 11 days, during which time 320 measurements were made with a total running time of over 40 h. Because of its small size, low power consumption requirements, and its ability to be automated, the new analyzer can be adapted for underway and in situ measurements.

  5. Validated spectrophotometric methods for determination of sodium valproate based on charge transfer complexation reactions

    NASA Astrophysics Data System (ADS)

    Belal, Tarek S.; El-Kafrawy, Dina S.; Mahrous, Mohamed S.; Abdel-Khalek, Magdi M.; Abo-Gharam, Amira H.

    2016-02-01

    This work presents the development, validation and application of four simple and direct spectrophotometric methods for determination of sodium valproate (VP) through charge transfer complexation reactions. The first method is based on the reaction of the drug with p-chloranilic acid (p-CA) in acetone to give a purple colored product with maximum absorbance at 524 nm. The second method depends on the reaction of VP with dichlone (DC) in dimethylformamide forming a reddish orange product measured at 490 nm. The third method is based upon the interaction of VP and picric acid (PA) in chloroform resulting in the formation of a yellow complex measured at 415 nm. The fourth method involves the formation of a yellow complex peaking at 361 nm upon the reaction of the drug with iodine in chloroform. Experimental conditions affecting the color development were studied and optimized. Stoichiometry of the reactions was determined. The proposed spectrophotometric procedures were effectively validated with respect to linearity, ranges, precision, accuracy, specificity, robustness, detection and quantification limits. Calibration curves of the formed color products with p-CA, DC, PA and iodine showed good linear relationships over the concentration ranges 24-144, 40-200, 2-20 and 1-8 μg/mL respectively. The proposed methods were successfully applied to the assay of sodium valproate in tablets and oral solution dosage forms with good accuracy and precision. Assay results were statistically compared to a reference pharmacopoeial HPLC method where no significant differences were observed between the proposed methods and reference method.

  6. Simultaneous spectrophotometric determination of cyanide and thiocyanate after separation on a melamine-formaldehyde resin.

    PubMed

    Gümüş, G; Demirata, B; Apak, R

    2000-11-01

    A simple indirect spectrophotometric method for the determination of cyanide, based on the oxidation of the cyanide with chlorine (Cl(2)) is described. The residual chlorine is determined by the color reaction with o-tolidine (3,3'-dimethylbenzidine). The maximum absorbance for Cl(2) is at 437 nm. A linear calibration graph (0-4.0x10(-5) M CN(-)) is obtained under optimal reaction conditions at room temperature and pH 11-12. The stoichiometric mole ratio of chlorine to cyanide is 1:1. The effective molar absorptivity for cyanide is 5.87x10(4) l mol(-1) cm(-1) at pH 1.6. The limit of quantification (LOQ) is 3.6x10(-7) M or 9.4 ppb. Effects of pH, excess reagent, sensitivity, reaction time and tolerance limits of interferent ions are reported. The method was applied to the determination of cyanide in a real sample. The basic interferent usually accompanying CN(-), i.e. thiocyanate, is separated from cyanide by sorption on a melamine-formaldehyde resin at pH 9 while cyanide is not retained. Thiocyanate is eluted with 0.4 M NaOH from the column and determined spectrophotometrically using the acidic FeCl(3) reagent. The initial column effluent containing cyanide was analyzed by both the developed chlorine-o-tolidine method and the conventional barbituric acid-pyridine (Spectroquant 14800) procedure, and the results were statistically compared. The developed method is relatively inexpensive and less laborious than the standard (Spectroquant) procedure, and insensitive to the common interferent, cyanate (CNO(-)).

  7. Study on the determination of trace Ni (II) by the catalytic kinetic spectrophotometric method

    NASA Astrophysics Data System (ADS)

    Ji, Hongwei; Cao, Hengxia; Xin, Huizhen; Li, Shuang

    2010-03-01

    A new kinetic spectrophotometric method has been developed for the determination of trace Ni (II) in natural water. The method is based on the catalytic effect of Ni (II) on the oxidation of weak acid brilliant blue dye (RAWL) by KIO4 in acid medium. The concentration of nickel (II) can be determined spectrophotometrically by measuring the decrease of absorbance of RAWL at λ = 626 nm using the fix-time method. The influencing factors are investigated by the orthogonal experimental design. The obtained optimum analytical conditions are: pH = 2.00, c RAWL = 5.00×10-5 mol L-1, c KIO 4 = 2.00×10-5 mol L -1, the reaction time t = 10 min and the temperature T = 25°C. Under the optimum conditions, the developed method allows the measurement of Ni (II) in a range of 0-40.0 ng mL-1. The standard deviation of eleven independent measurements of blank reaction is S = 3.08×10-3 and the limit of detection is 2.20 ng mL-1. The relative standard deviations (RSDs) in six replicate determinations of 5 ng mL-1 and 8 ng mL-1 Ni (II) are 2.87% and 1.11%, respectively. Moreover, the experiments show few cations and anions can interfere with the measurement of Ni (II). The recovery efficiencies of this method are in a range of 97.0%-102.5% in freshwater samples. But there is a decreasing effect, which is about 0.2 times the added Ni (II) in seawater medium. After reasonable calibration this processing method is used for the determination of Ni (II) in seawater samples successfully. The results show this developed method has high accuracy and precision, high sensitivity, large range of linearity and high speed. The method can, therefore, be employed at room temperature.

  8. Frequency-domain analysis of absolute gravimeters

    NASA Astrophysics Data System (ADS)

    Svitlov, S.

    2012-12-01

    An absolute gravimeter is analysed as a linear time-invariant system in the frequency domain. Frequency responses of absolute gravimeters are derived analytically based on the propagation of the complex exponential signal through their linear measurement functions. Depending on the model of motion and the number of time-distance coordinates, an absolute gravimeter is considered as a second-order (three-level scheme) or third-order (multiple-level scheme) low-pass filter. It is shown that the behaviour of an atom absolute gravimeter in the frequency domain corresponds to that of the three-level corner-cube absolute gravimeter. Theoretical results are applied for evaluation of random and systematic measurement errors and optimization of an experiment. The developed theory agrees with known results of an absolute gravimeter analysis in the time and frequency domains and can be used for measurement uncertainty analyses, building of vibration-isolation systems and synthesis of digital filtering algorithms.

  9. Correction to Method of Establishing the Absolute Radiometric Accuracy of Remote Sensing Systems While On-orbit Using Characterized Stellar Sources

    NASA Technical Reports Server (NTRS)

    Bowen, Howard S.; Cunningham, Douglas M.

    2007-01-01

    The contents include: 1) Brief history of related events; 2) Overview of original method used to establish absolute radiometric accuracy of remote sensing instruments using stellar sources; and 3) Considerations to improve the stellar calibration approach.

  10. Spectrophotometric measurement of calcium carbonate saturation states in seawater.

    PubMed

    Easley, Regina A; Patsavas, Mark C; Byrne, Robert H; Liu, Xuewu; Feely, Richard A; Mathis, Jeremy T

    2013-02-01

    Measurements of ocean pH and carbonate ion concentrations in the North Pacific and Arctic Oceans were used to determine calcium carbonate saturation states (Ω(CaCO(3))) from spectrophotometric methods alone. Total carbonate ion concentrations, [CO(3)(2-)](T), were for the first time at sea directly measured using Pb(II) UV absorbance spectra. The basis of the method is given by the following: [formula see text] where (CO(3))β(1) is the PbCO(3)(0) formation constant, e(i) are molar absorptivity ratios, and R = (250)A/(234)A (ratio of absorbances measured at 250 and 234 nm). On the basis of shipboard and laboratory Pb(II) data and complementary carbon-system measurements, the experimental parameters were determined to be (25 °C) the following: [formula see text]. The resulting mean difference between the shipboard spectrophotometric and conventional determinations of [CO(3)(2-)](T) was ±2.03 μmol kg(-1). The shipboard analytical precision of the Pb(II) method was ∼1.71 μmol kg(-1) (2.28%). Spectrophotometric [CO(3)(2-)](T) and pH(T) were then combined to calculate Ω(CaCO(3)). For the case of aragonite, 95% of the spectrophotometric aragonite saturation states (Ω(Aspec)) were within ±0.06 of the conventionally calculated values (Ω(Acalc)) when 0.5 ≤ Ω(A) ≤ 2.0. When Ω(A) > 2.0, 95% of the Ω(Aspec) values were within ±0.18 of Ω(Acalc). Our shipboard experience indicates that spectrophotometric determinations of [CO(3)(2-)](T) and Ω(CaCO(3)) are straightforward, fast, and precise. The method yields high-quality measurements of two important, rapidly changing aspects of ocean chemistry and offers capabilities suitable for long-term automated in situ monitoring.

  11. Interlaboratory calibration of atmospheric nitrous oxide measurements

    NASA Technical Reports Server (NTRS)

    Rasmussen, R. A.; Pierotti, D.

    1978-01-01

    Samples representative of Northern Hemispheric conditions in mid-1976 were analyzed by 11 laboratories to resolve the question of the absolute tropospheric concentration of nitrous oxide. The laboratories all employed electron capture-gas chromatography for the analysis. After exclusion of one anomalously low determination, the calibration results showed a mean concentration of 323.5 + or - 8.7 ppb v/v nitrous oxide.

  12. Landsat Data Continuity Mission Calibration and Validation

    NASA Technical Reports Server (NTRS)

    Markham, Brian L.; Dabney, Philip W.; Storey, James C.; Morfitt, Ron; Knight, Ed; Kvaran, Geir; Lee, Kenton

    2008-01-01

    The primary payload for the Landsat Data Continuity Mission (LDCM) is the Operational Land Imager (OLI), being built by Ball Aerospace and Technologies, under contract to NASA. The OLI has spectral bands similar to the Landsat-7 ETM+, minus the thermal band and with two new bands, a 443 nm band and 1375 nm cirrus detection band. On-board calibration systems include two solar diffusers (routine and pristine), a shutter and three sets of internal lamps (routine, backup and pristine). Being a pushbroom opposed to a whiskbroom design of ETM+, the system poses new challenges for characterization and calibration, chief among them being the large focal plane with 75000+ detectors. A comprehensive characterization and calibration plan is in place for the instrument and the data throughout the mission including Ball, NASA and the United States Geological Survey, which will take over operations of LDCM after on-orbit commissioning. Driving radiometric calibration requirements for OLI data include radiance calibration to 5% uncertainty (1 q); reflectance calibration to 3% uncertainty (1 q) and relative (detector-to-detector) calibration to 0.5% (J (r). Driving geometric calibration requirements for OLI include bandto- band registration of 4.5 meters (90% confidence), absolute geodetic accuracy of 65 meters (90% CE) and relative geodetic accuracy of 25 meters (90% CE). Key spectral, spatial and radiometric characterization of the OLI will occur in thermal vacuum at Ball Aerospace. During commissioning the OLI will be characterized and calibrated using celestial (sun, moon, stars) sources and terrestrial sources. The USGS EROS ground processing system will incorporate an image assessment system similar to Landsat-7 for characterization and calibration. This system will have the added benefit that characterization data will be extracted as part of the normal image data processing, so that the characterization data available will be significantly larger than for Landsat-7 ETM+.

  13. PACS photometer calibration block analysis

    NASA Astrophysics Data System (ADS)

    Moór, A.; Müller, T. G.; Kiss, C.; Balog, Z.; Billot, N.; Marton, G.

    2014-07-01

    The absolute stability of the PACS bolometer response over the entire mission lifetime without applying any corrections is about 0.5 % (standard deviation) or about 8 % peak-to-peak. This fantastic stability allows us to calibrate all scientific measurements by a fixed and time-independent response file, without using any information from the PACS internal calibration sources. However, the analysis of calibration block observations revealed clear correlations of the internal source signals with the evaporator temperature and a signal drift during the first half hour after the cooler recycling. These effects are small, but can be seen in repeated measurements of standard stars. From our analysis we established corrections for both effects which push the stability of the PACS bolometer response to about 0.2 % (stdev) or 2 % in the blue, 3 % in the green and 5 % in the red channel (peak-to-peak). After both corrections we still see a correlation of the signals with PACS FPU temperatures, possibly caused by parasitic heat influences via the Kevlar wires which connect the bolometers with the PACS Focal Plane Unit. No aging effect or degradation of the photometric system during the mission lifetime has been found.

  14. Simultaneous estimation of ramipril, acetylsalicylic acid and atorvastatin calcium by chemometrics assisted UV-spectrophotometric method in capsules.

    PubMed

    Sankar, A S Kamatchi; Vetrichelvan, Thangarasu; Venkappaya, Devashya

    2011-09-01

    In the present work, three different spectrophotometric methods for simultaneous estimation of ramipril, aspirin and atorvastatin calcium in raw materials and in formulations are described. Overlapped data was quantitatively resolved by using chemometric methods, viz. inverse least squares (ILS), principal component regression (PCR) and partial least squares (PLS). Calibrations were constructed using the absorption data matrix corresponding to the concentration data matrix. The linearity range was found to be 1-5, 10-50 and 2-10 μg mL-1 for ramipril, aspirin and atorvastatin calcium, respectively. The absorbance matrix was obtained by measuring the zero-order absorbance in the wavelength range between 210 and 320 nm. A training set design of the concentration data corresponding to the ramipril, aspirin and atorvastatin calcium mixtures was organized statistically to maximize the information content from the spectra and to minimize the error of multivariate calibrations. By applying the respective algorithms for PLS 1, PCR and ILS to the measured spectra of the calibration set, a suitable model was obtained. This model was selected on the basis of RMSECV and RMSEP values. The same was applied to the prediction set and capsule formulation. Mean recoveries of the commercial formulation set together with the figures of merit (calibration sensitivity, selectivity, limit of detection, limit of quantification and analytical sensitivity) were estimated. Validity of the proposed approaches was successfully assessed for analyses of drugs in the various prepared physical mixtures and formulations.

  15. Radiance calibration of the High Altitude Observatory white-light coronagraph on Skylab

    NASA Technical Reports Server (NTRS)

    Poland, A. I.; Macqueen, R. M.; Munro, R. H.; Gosling, J. T.

    1977-01-01

    The processing of over 35,000 photographs of the solar corona obtained by the white-light coronograph on Skylab is described. Calibration of the vast amount of data was complicated by temporal effects of radiation fog and latent image loss. These effects were compensated by imaging a calibration step wedge on each data frame. Absolute calibration of the wedge was accomplished through comparison with a set of previously calibrated glass opal filters. Analysis employed average characteristic curves derived from measurements of step wedges from many frames within a given camera half-load. The net absolute accuracy of a given radiance measurement is estimated to be 20%.

  16. Selective kinetic spectrophotometric method for determination of gatifloxacin based on formation of its N-vinyl chlorobenzoquinone derivative

    NASA Astrophysics Data System (ADS)

    Darwish, Ibrahim A.; Sultan, Maha A.; Al-Arfaj, Hessa A.

    2010-01-01

    A selective and simple kinetic spectrophotometric has been developed, for the first time, for the determination of gatifloxacin (GAT) in its dosage forms. The method was based on the formation of a colored N-vinyl chlorobenzoquinone derivative of GAT by its reaction with 2,3,5,6-tetrachloro-1,4-benzoquinone in presence of acetaldehyde. The formation of the colored product was monitored spectrophotometrically by measuring the absorbances at 655 nm. The factors affecting the reaction were studied and optimized. The stoichiometry of the reaction was determined, and the reaction pathway was postulated. Under the optimized conditions, the initial rate and fixed time (at 5 min) methods were utilized for constructing the calibration graphs. The graphs were linear in the concentration ranges of 2-100 and 10-140 μg ml -1 with limits of detection of 0.84 and 3.5 μg ml -1 for the initial rate and fixed time methods, respectively. The analytical performance of both methods was fully validated, and the results were satisfactory. The proposed methods were successfully applied to the determination of GAT in its commercial dosage forms. The label claim percentages were 99.7-100.5 and 98.2-99.5% for the initial rate and fixed time methods, respectively. Statistical comparison of the results with those of the reference method showed excellent agreement and proved that there was no significant difference in the accuracy and precision between the reference and the proposed methods. The proposed methods are superior to all the previously reported spectrophotometric methods in terms of the procedure simplicity and assay selectivity.

  17. Simultaneous kinetic spectrophotometric analysis of five synthetic food colorants with the aid of chemometrics.

    PubMed

    Ni, Yongnian; Wang, Yong; Kokot, Serge

    2009-04-30

    This paper describes a simple and sensitive kinetic spectrophotometric method for the simultaneous determination of Amaranth, Ponceau 4R, Sunset Yellow, Tartrazine and Brilliant Blue in mixtures with the aid of chemometrics. The method involved two coupled reactions, viz. the reduction of iron(III) by the analytes to iron(II) in sodium acetate/hydrochloric acid solution (pH 1.71) and the chromogenic reaction between iron(II) and hexacyanoferrate(III) ions to yield a Prussian blue peak at 760 nm. The spectral data were recorded over the 500-1000 nm wavelength range every 2s for 600 s. The kinetic data were collected at 760 nm and 600 s, and linear calibration models were satisfactorily constructed for each of the dyes with detection limits in the range of 0.04-0.50 mg L(-1). Multivariate calibration models for kinetic data were established and verified for methods such as the Iterative target transform factor analysis (ITTFA), principal component regression (PCR), partial least squares (PLS), and principal component-radial basis function-artificial neural network (PC-RBF-ANN) with and without wavelet packet transform (WPT) pre-treatment. The PC-RBF-ANN with WPT calibration performed somewhat better than others on the basis of the %RPE(T) (approximately 9) and %Recovery parameters (approximately 108), although the effect of the WPT pre-treatment was marginal (approximately 0.5% RPE(T)). The proposed method was applied for the simultaneous determination of the five colorants in foodstuff samples, and the results were comparable with those from a reference HPLC method.

  18. Absolute Income, Relative Income, and Happiness

    ERIC Educational Resources Information Center

    Ball, Richard; Chernova, Kateryna

    2008-01-01

    This paper uses data from the World Values Survey to investigate how an individual's self-reported happiness is related to (i) the level of her income in absolute terms, and (ii) the level of her income relative to other people in her country. The main findings are that (i) both absolute and relative income are positively and significantly…

  19. Investigating Absolute Value: A Real World Application

    ERIC Educational Resources Information Center

    Kidd, Margaret; Pagni, David

    2009-01-01

    Making connections between various representations is important in mathematics. In this article, the authors discuss the numeric, algebraic, and graphical representations of sums of absolute values of linear functions. The initial explanations are accessible to all students who have experience graphing and who understand that absolute value simply…

  20. Preschoolers' Success at Coding Absolute Size Values.

    ERIC Educational Resources Information Center

    Russell, James

    1980-01-01

    Forty-five 2-year-old and forty-five 3-year-old children coded relative and absolute sizes using 1.5-inch, 6-inch, and 18-inch cardboard squares. Results indicate that absolute coding is possible for children of this age. (Author/RH)

  1. Introducing the Mean Absolute Deviation "Effect" Size

    ERIC Educational Resources Information Center

    Gorard, Stephen

    2015-01-01

    This paper revisits the use of effect sizes in the analysis of experimental and similar results, and reminds readers of the relative advantages of the mean absolute deviation as a measure of variation, as opposed to the more complex standard deviation. The mean absolute deviation is easier to use and understand, and more tolerant of extreme…

  2. Monolithically integrated absolute frequency comb laser system

    DOEpatents

    Wanke, Michael C.

    2016-07-12

    Rather than down-convert optical frequencies, a QCL laser system directly generates a THz frequency comb in a compact monolithically integrated chip that can be locked to an absolute frequency without the need of a frequency-comb synthesizer. The monolithic, absolute frequency comb can provide a THz frequency reference and tool for high-resolution broad band spectroscopy.

  3. Estimating the absolute wealth of households

    PubMed Central

    Gerkey, Drew; Hadley, Craig

    2015-01-01

    Abstract Objective To estimate the absolute wealth of households using data from demographic and health surveys. Methods We developed a new metric, the absolute wealth estimate, based on the rank of each surveyed household according to its material assets and the assumed shape of the distribution of wealth among surveyed households. Using data from 156 demographic and health surveys in 66 countries, we calculated absolute wealth estimates for households. We validated the method by comparing the proportion of households defined as poor using our estimates with published World Bank poverty headcounts. We also compared the accuracy of absolute versus relative wealth estimates for the prediction of anthropometric measures. Findings The median absolute wealth estimates of 1 403 186 households were 2056 international dollars per capita (interquartile range: 723–6103). The proportion of poor households based on absolute wealth estimates were strongly correlated with World Bank estimates of populations living on less than 2.00 United States dollars per capita per day (R2 = 0.84). Absolute wealth estimates were better predictors of anthropometric measures than relative wealth indexes. Conclusion Absolute wealth estimates provide new opportunities for comparative research to assess the effects of economic resources on health and human capital, as well as the long-term health consequences of economic change and inequality. PMID:26170506

  4. Absolute optical metrology : nanometers to kilometers

    NASA Technical Reports Server (NTRS)

    Dubovitsky, Serge; Lay, O. P.; Peters, R. D.; Liebe, C. C.

    2005-01-01

    We provide and overview of the developments in the field of high-accuracy absolute optical metrology with emphasis on space-based applications. Specific work on the Modulation Sideband Technology for Absolute Ranging (MSTAR) sensor is described along with novel applications of the sensor.

  5. Absolute instability of the Gaussian wake profile

    NASA Technical Reports Server (NTRS)

    Hultgren, Lennart S.; Aggarwal, Arun K.

    1987-01-01

    Linear parallel-flow stability theory has been used to investigate the effect of viscosity on the local absolute instability of a family of wake profiles with a Gaussian velocity distribution. The type of local instability, i.e., convective or absolute, is determined by the location of a branch-point singularity with zero group velocity of the complex dispersion relation for the instability waves. The effects of viscosity were found to be weak for values of the wake Reynolds number, based on the center-line velocity defect and the wake half-width, larger than about 400. Absolute instability occurs only for sufficiently large values of the center-line wake defect. The critical value of this parameter increases with decreasing wake Reynolds number, thereby indicating a shrinking region of absolute instability with decreasing wake Reynolds number. If backflow is not allowed, absolute instability does not occur for wake Reynolds numbers smaller than about 38.

  6. Energy calibration of Cherenkov Telescopes using GLAST data

    SciTech Connect

    Bastieri, D.; Busetto, G.; Piano, G.; Rando, R.; Saggion, A.; De Angelis, A.; Longo, F.

    2007-07-12

    We discuss the possibility of using the observations by GLAST of steady gamma sources, as the Crab Nebula and some selected AGNs, to calibrate the Imaging Air Cherenkov Telescopes (IACT) and improve their energy resolution, in particular. We show that at around 100 GeV, exploiting the features in the spectrum of the Crab Nebula, the absolute energy calibration uncertainty of Cherenkov telescopes can be reduced to < 10%.

  7. Calibration of the Aronson 6-DOF robotic platform

    NASA Technical Reports Server (NTRS)

    Lin, Amy Y.

    1991-01-01

    A discussion is presented of the calibration of the Aronson six-degree-of-freedom platform. Absolute encoders are used to determine the starting positions of all six joints. The hardware implemented are described in detail. Software programs are used to calibrate the hardware and to build the look-up tables that are needed in determining the initial joint positions. The descriptions of all software routines used are given.

  8. THE ABSOLUTE MAGNITUDES OF RED HORIZONTAL BRANCH STARS IN THE ugriz SYSTEM

    SciTech Connect

    Chen, Y. Q.; Zhao, G.; Zhao, J. K.

    2009-09-10

    Based on photometric data of the central parts of eight globular clusters and one open cluster presented by An and his collaborators, we select red horizontal branch (RHB) stars in the (g - r){sub 0}-g {sub 0} diagram and make a statistical study of the distributions of their colors and absolute magnitudes in the SDSS ugriz system. Meanwhile, absolute magnitudes in the Johnson VRI system are calculated through the translation formulae between gri and VRI in the literature. The calibrations of absolute magnitude as functions of metallicity and age are established by linear regressions of the data. It is found that metallicity coefficients in these calibrations decrease, while age coefficients increase, from the blue u filter to the red z filter. The calibration of M{sub i} = 0.06[Fe/H] + 0.040t + 0.03 has the smallest scatter of 0.04 mag, and thus i is the best filter in the ugriz system when RHB stars are used for distance indicators. The comparison of the M{sub I} calibration from our data with that from red clump stars indicates that the previous suggestion that the I filter is better than the V filter in distance determination may not be true because of its significant dependence on age.

  9. An Improved Photometric Calibration of the Sloan Digital Sky Survey Imaging Data

    SciTech Connect

    Padmanabhan, Nikhil; Schlegel, D.J.; Finkbeiner, D.P.; Barentine, J.C.; Blanton, M.R.; Brewington, H.J.; Gunn, J.E.; Harvanek, M.; Hogg, D.W.; Ivezic, Z.; Johnston, D.; /LBL, Berkeley /Princeton U. /Harvard-Smithsonian Ctr. Astrophys. /Texas U., Astron. Dept. /Apache Point Observ. /New York U. /Washington U., Seattle, Astron. Dept. /Caltech, JPL /Fermilab /Subaru Telescope /Mt. Suhora Observ., Cracow

    2007-03-01

    We present an algorithm to photometrically calibrate wide field optical imaging surveys, that simultaneously solves for the calibration parameters and relative stellar fluxes using overlapping observations. The algorithm decouples the problem of ''relative'' calibrations from that of ''absolute'' calibrations; the absolute calibration is reduced to determining a few numbers for the entire survey. We pay special attention to the spatial structure of the calibration errors, allowing one to isolate particular error modes in downstream analyses. Applying this to the Sloan Digital Sky Survey imaging data, we achieve {approx}1% relative calibration errors across 8500 deg{sup 2} in griz; the errors are {approx}2% for the u band. These errors are dominated by unmodeled atmospheric variations at Apache Point Observatory.

  10. Auroral meridian scanning photometer calibration using Jupiter

    NASA Astrophysics Data System (ADS)

    Jackel, Brian J.; Unick, Craig; Creutzberg, Fokke; Baker, Greg; Davis, Eric; Donovan, Eric F.; Connors, Martin; Wilson, Cody; Little, Jarrett; Greffen, M.; McGuffin, Neil

    2016-10-01

    Observations of astronomical sources provide information that can significantly enhance the utility of auroral data for scientific studies. This report presents results obtained by using Jupiter for field cross calibration of four multispectral auroral meridian scanning photometers during the 2011-2015 Northern Hemisphere winters. Seasonal average optical field-of-view and local orientation estimates are obtained with uncertainties of 0.01 and 0.1°, respectively. Estimates of absolute sensitivity are repeatable to roughly 5 % from one month to the next, while the relative response between different wavelength channels is stable to better than 1 %. Astronomical field calibrations and darkroom calibration differences are on the order of 10 %. Atmospheric variability is the primary source of uncertainty; this may be reduced with complementary data from co-located instruments.

  11. Spectrophotometric determination of osmium based on its catalytic effect on the oxidation of carminic acid by hydrogen peroxide.

    PubMed

    Manzoori, J L; Sorouraddin, M H; Amjadi, M

    2000-10-01

    A highly sensitive spectrophotometric method is described for the determination of trace amounts of osmium(VIII), based on its catalytic effect on the oxidation of carminic acid by hydrogen peroxide. The reaction was monitored spectrophotometrically by measuring the decrease in absorbance of carminic acid at 540 nm after 3 min of mixing the reagents. The optimum reaction conditions were 1x10(-4) mol l(-1) carminic acid, 0.013 mol l(-1) hydrogen peroxide and pH 10 at 25 degrees C. By using the recommended procedure, the calibration graph was linear from 0.1 to 1.5 ng ml(-1) of osmium; the detection limit was 0.02 ng ml(-1); the RSD for five replicate determinations of 0.2-1.4 ng ml(-1) was in the range of 1.8-4.7%. The influence of several foreign ions on osmium determination were studied and the effect of interfering ions were removed by extracting osmium into isobuthyl methyl ketone and back extracting into sodium hydroxide solution. PMID:18968089

  12. Development and validation of sensitive kinetic spectrophotometric method for the determination of moxifloxacin antibiotic in pure and commercial tablets

    NASA Astrophysics Data System (ADS)

    Ashour, Safwan; Bayram, Roula

    2015-04-01

    New, accurate, sensitive and reliable kinetic spectrophotometric method for the assay of moxifloxacin hydrochloride (MOXF) in pure form and pharmaceutical formulations has been developed. The method involves the oxidative coupling reaction of MOXF with 3-methyl-2-benzothiazolinone hydrazone hydrochloride monohydrate (MBTH) in the presence of Ce(IV) in an acidic medium to form colored product with lambda max at 623 and 660 nm. The reaction is followed spectrophotometrically by measuring the increase in absorbance at 623 nm as a function of time. The initial rate and fixed time methods were adopted for constructing the calibration curves. The linearity range was found to be 1.89-40.0 μg mL-1 for initial rate and fixed time methods. The limit of detection for initial rate and fixed time methods is 0.644 and 0.043 μg mL-1, respectively. Molar absorptivity for the method was found to be 0.89 × 104 L mol-1 cm-1. Statistical treatment of the experimental results indicates that the methods are precise and accurate. The proposed method has been applied successfully for the estimation of moxifloxacin hydrochloride in tablet dosage form with no interference from the excipients. The results are compared with the official method.

  13. Calibration system and prototypes for electron detectors for the UCN A experiment

    NASA Astrophysics Data System (ADS)

    Ito, T.; Filippone, B.; Jones, C.; McKeown, R.; Yuan, J.; Young, A. R.; Hoedl, S.; Liu, C.-Y.; Smith, D.; Soyama, K.; Bowles, T.; Brun, T.; Fowler, M.; Hill, R.; Hime, A.; Hogan, G.; Lamoreaux, S.; Morris, C.; Saunders, A.; Seestrom, S.; Walstrom, P.; Alduschenkov, A.; Kharitonov, A.; Lassakov, M.; Rudnev, Y.; Serebrov, A.; Vasilev, A.; Geltenbort, P.; Kitagaki, T.; Asahi, K.; Hino, M.; Kawai, T.; Utsuro, M.; Garcia, A.; Makela, M.; Vogelaar, R. B.; Miyachi, T.

    1999-10-01

    The status of the development of the electron detectors for the UCN A experiemnt will be presented. Absolute energy calibration is of great importance for this experiment and most of the effort has so far been put into a development of a system that allows an off-line absolute energy calibration of 0.1% in the energy range of up to 800keV, using the JPL dynamitron. Some results with a prototype detector will be presented.

  14. Improving self-calibration

    NASA Astrophysics Data System (ADS)

    Enßlin, Torsten A.; Junklewitz, Henrik; Winderling, Lars; Greiner, Maksim; Selig, Marco

    2014-10-01

    Response calibration is the process of inferring how much the measured data depend on the signal one is interested in. It is essential for any quantitative signal estimation on the basis of the data. Here, we investigate self-calibration methods for linear signal measurements and linear dependence of the response on the calibration parameters. The common practice is to augment an external calibration solution using a known reference signal with an internal calibration on the unknown measurement signal itself. Contemporary self-calibration schemes try to find a self-consistent solution for signal and calibration by exploiting redundancies in the measurements. This can be understood in terms of maximizing the joint probability of signal and calibration. However, the full uncertainty structure of this joint probability around its maximum is thereby not taken into account by these schemes. Therefore, better schemes, in sense of minimal square error, can be designed by accounting for asymmetries in the uncertainty of signal and calibration. We argue that at least a systematic correction of the common self-calibration scheme should be applied in many measurement situations in order to properly treat uncertainties of the signal on which one calibrates. Otherwise, the calibration solutions suffer from a systematic bias, which consequently distorts the signal reconstruction. Furthermore, we argue that nonparametric, signal-to-noise filtered calibration should provide more accurate reconstructions than the common bin averages and provide a new, improved self-calibration scheme. We illustrate our findings with a simplistic numerical example.

  15. Inertial Sensor Error Reduction through Calibration and Sensor Fusion.

    PubMed

    Lambrecht, Stefan; Nogueira, Samuel L; Bortole, Magdo; Siqueira, Adriano A G; Terra, Marco H; Rocon, Eduardo; Pons, José L

    2016-01-01

    This paper presents the comparison between cooperative and local Kalman Filters (KF) for estimating the absolute segment angle, under two calibration conditions. A simplified calibration, that can be replicated in most laboratories; and a complex calibration, similar to that applied by commercial vendors. The cooperative filters use information from either all inertial sensors attached to the body, Matricial KF; or use information from the inertial sensors and the potentiometers of an exoskeleton, Markovian KF. A one minute walking trial of a subject walking with a 6-DoF exoskeleton was used to assess the absolute segment angle of the trunk, thigh, shank, and foot. The results indicate that regardless of the segment and filter applied, the more complex calibration always results in a significantly better performance compared to the simplified calibration. The interaction between filter and calibration suggests that when the quality of the calibration is unknown the Markovian KF is recommended. Applying the complex calibration, the Matricial and Markovian KF perform similarly, with average RMSE below 1.22 degrees. Cooperative KFs perform better or at least equally good as Local KF, we therefore recommend to use cooperative KFs instead of local KFs for control or analysis of walking. PMID:26901198

  16. Inertial Sensor Error Reduction through Calibration and Sensor Fusion

    PubMed Central

    Lambrecht, Stefan; Nogueira, Samuel L.; Bortole, Magdo; Siqueira, Adriano A. G.; Terra, Marco H.; Rocon, Eduardo; Pons, José L.

    2016-01-01

    This paper presents the comparison between cooperative and local Kalman Filters (KF) for estimating the absolute segment angle, under two calibration conditions. A simplified calibration, that can be replicated in most laboratories; and a complex calibration, similar to that applied by commercial vendors. The cooperative filters use information from either all inertial sensors attached to the body, Matricial KF; or use information from the inertial sensors and the potentiometers of an exoskeleton, Markovian KF. A one minute walking trial of a subject walking with a 6-DoF exoskeleton was used to assess the absolute segment angle of the trunk, thigh, shank, and foot. The results indicate that regardless of the segment and filter applied, the more complex calibration always results in a significantly better performance compared to the simplified calibration. The interaction between filter and calibration suggests that when the quality of the calibration is unknown the Markovian KF is recommended. Applying the complex calibration, the Matricial and Markovian KF perform similarly, with average RMSE below 1.22 degrees. Cooperative KFs perform better or at least equally good as Local KF, we therefore recommend to use cooperative KFs instead of local KFs for control or analysis of walking. PMID:26901198

  17. Spectrophotometric Determination of Certain Benzimidazole Proton Pump Inhibitors

    PubMed Central

    Syed, A. A.; Syeda, Ayesha

    2008-01-01

    Spectrophotometric method for the determination of certain proton pump inhibitors belonging to the benzimidazole class of compounds has been developed. The method is based on the reaction of omeprazole, lansoprazole, pantoprazole, rabeprazole and esomeprazole with iron (III) and subsequent reaction with ferricyanide under neutral condition which yields Prussian blue product with maximum absorption at 720–730 nm. The commonly encountered excipients and additives that often accompany pharmaceutical preparations did not interfere with the determination. The method was applied for the determination of omeprazole, lansoprazole, pantoprazole, rabeprazole and esomeprazole in pharmaceutical preparations and no difference was found statistically. Thus, the spectrophotometric method can be applied as inexpensive, rapid, easy, accurate and precise method for the routine analysis of the five proton pump inhibitors in pharmaceutical preparations. PMID:20046782

  18. Validated derivative and ratio derivative spectrophotometric methods for the simultaneous determination of levocetirizine dihydrochloride and ambroxol hydrochloride in pharmaceutical dosage form

    NASA Astrophysics Data System (ADS)

    Ali, Omnia I. M.; Ismail, Nahla S.; Elgohary, Rasha M.

    2016-01-01

    Three simple, precise, accurate and validated derivative spectrophotometric methods have been developed for the simultaneous determination of levocetirizine dihydrochloride (LCD) and ambroxol hydrochloride (ABH) in bulk powder and in pharmaceutical formulations. The first method is a first derivative spectrophotometric method (1D) using a zero-crossing technique of measurement at 210.4 nm for LCD and at 220.0 nm for ABH. The second method employs a second derivative spectrophotometry (2D) where the measurements were carried out at 242.0 and 224.4 nm for LCD and ABH, respectively. In the third method, the first derivative of the ratio spectra was calculated and the first derivative of the ratio amplitudes at 222.8 and 247.2 nm was selected for the determination of LCD and ABH, respectively. Calibration graphs were established in the ranges of 1.0-20.0 μg mL- 1 for LCD and 4.0-20.0 μg mL- 1 for ABH using derivative and ratio first derivative spectrophotometric methods with good correlation coefficients. The developed methods have been successfully applied to the simultaneous determination of both drugs in commercial tablet dosage form.

  19. Validated derivative and ratio derivative spectrophotometric methods for the simultaneous determination of levocetirizine dihydrochloride and ambroxol hydrochloride in pharmaceutical dosage form.

    PubMed

    Ali, Omnia I M; Ismail, Nahla S; Elgohary, Rasha M

    2016-01-15

    Three simple, precise, accurate and validated derivative spectrophotometric methods have been developed for the simultaneous determination of levocetirizine dihydrochloride (LCD) and ambroxol hydrochloride (ABH) in bulk powder and in pharmaceutical formulations. The first method is a first derivative spectrophotometric method ((1)D) using a zero-crossing technique of measurement at 210.4 nm for LCD and at 220.0 nm for ABH. The second method employs a second derivative spectrophotometry ((2)D) where the measurements were carried out at 242.0 and 224.4 nm for LCD and ABH, respectively. In the third method, the first derivative of the ratio spectra was calculated and the first derivative of the ratio amplitudes at 222.8 and 247.2 nm was selected for the determination of LCD and ABH, respectively. Calibration graphs were established in the ranges of 1.0-20.0 μg mL(-1) for LCD and 4.0-20.0 μg mL(-1) for ABH using derivative and ratio first derivative spectrophotometric methods with good correlation coefficients. The developed methods have been successfully applied to the simultaneous determination of both drugs in commercial tablet dosage form.

  20. Validated derivative and ratio derivative spectrophotometric methods for the simultaneous determination of levocetirizine dihydrochloride and ambroxol hydrochloride in pharmaceutical dosage form.

    PubMed

    Ali, Omnia I M; Ismail, Nahla S; Elgohary, Rasha M

    2016-01-15

    Three simple, precise, accurate and validated derivative spectrophotometric methods have been developed for the simultaneous determination of levocetirizine dihydrochloride (LCD) and ambroxol hydrochloride (ABH) in bulk powder and in pharmaceutical formulations. The first method is a first derivative spectrophotometric method ((1)D) using a zero-crossing technique of measurement at 210.4 nm for LCD and at 220.0 nm for ABH. The second method employs a second derivative spectrophotometry ((2)D) where the measurements were carried out at 242.0 and 224.4 nm for LCD and ABH, respectively. In the third method, the first derivative of the ratio spectra was calculated and the first derivative of the ratio amplitudes at 222.8 and 247.2 nm was selected for the determination of LCD and ABH, respectively. Calibration graphs were established in the ranges of 1.0-20.0 μg mL(-1) for LCD and 4.0-20.0 μg mL(-1) for ABH using derivative and ratio first derivative spectrophotometric methods with good correlation coefficients. The developed methods have been successfully applied to the simultaneous determination of both drugs in commercial tablet dosage form. PMID:26439526

  1. Spectrophotometric Assays of Major Compounds Extracted from Algae.

    PubMed

    Connan, Solène

    2015-01-01

    This chapter describes spectrophotometric assays of major compounds extracted from microalgae and macroalgae, i.e., proteins, carbohydrates, pigments (chlorophylls, carotenoids, and phycobiliproteins) and phenolic compounds. In contrast to other specific analytical techniques, such as high pressure liquid chromatography (HPLC) or mass spectrometry (MS), commonly applied to purified extracts to reveal more detailed composition and structure of algal compound families, these assays serve as a first assessment of the global contents of extracts.

  2. Screening of conditions controlling spectrophotometric sequential injection analysis

    PubMed Central

    2011-01-01

    Background Despite its potential benefits over univariate, chemometrics is rarely utilized for optimizing sequential injection analysis (SIA) methods. Specifically, in previous vis-spectrophotometric SIA methods, chemometrically optimized conditions were confined within flow rate and reagent concentrations while other conditions were ignored. Results The current manuscript reports, for the first time, a comprehensive screening of conditions controlling vis-spectrophotometric SIA. A new diclofenac assay method was adopted. The method was based on oxidizing diclofenac by permanganate (a major reagent) with sulfuric acid (a minor reagent). The reaction produced a spectrophotometrically detectable diclofenac form. The 26 full-factorial design was utilized to study the effect of volumes of reagents and sample, in addition to flow rate and concentrations of reagents. The main effects and all interaction order effects on method performance, i.e. namely sensitivity, rapidity and reagent consumption, were determined. The method was validated and applied to pharmaceutical formulations (tablets, injection and gel). Conclusions Despite 64 experiments those conducted in the current study were cumbersome, the results obtained would reduce effort and time when developing similar SIA methods in the future. It is recommended to critically optimize effective and interacting conditions using other such optimization tools as fractional-factorial design, response surface and simplex, rather than full-factorial design that used at an initial optimization stage. In vis-spectrophotometric SIA methods those involve developing reactions with two reagents (major and minor), conditions affecting method performance are in the following order: sample volume > flow rate ≈ major reagent concentration >> major reagent volume ≈ minor reagent concentration >> minor reagent volume. PMID:21333024

  3. Spectrophotometric Assays of Major Compounds Extracted from Algae.

    PubMed

    Connan, Solène

    2015-01-01

    This chapter describes spectrophotometric assays of major compounds extracted from microalgae and macroalgae, i.e., proteins, carbohydrates, pigments (chlorophylls, carotenoids, and phycobiliproteins) and phenolic compounds. In contrast to other specific analytical techniques, such as high pressure liquid chromatography (HPLC) or mass spectrometry (MS), commonly applied to purified extracts to reveal more detailed composition and structure of algal compound families, these assays serve as a first assessment of the global contents of extracts. PMID:26108498

  4. Implicit Spacecraft Gyro Calibration

    NASA Technical Reports Server (NTRS)

    Harman, Richard; Bar-Itzhack, Itzhack Y.

    2003-01-01

    This paper presents an implicit algorithm for spacecraft onboard instrument calibration, particularly to onboard gyro calibration. This work is an extension of previous work that was done where an explicit gyro calibration algorithm was applied to the AQUA spacecraft gyros. The algorithm presented in this paper was tested using simulated data and real data that were downloaded from the Microwave Anisotropy Probe (MAP) spacecraft. The calibration tests gave very good results. A comparison between the use of the implicit calibration algorithm used here with the explicit algorithm used for AQUA spacecraft indicates that both provide an excellent estimation of the gyro calibration parameters with similar accuracies.

  5. A distance-independent calibration of the luminosity of type Ia supernovae and the Hubble constant

    NASA Technical Reports Server (NTRS)

    Leibundgut, Bruno; Pinto, Philip A.

    1992-01-01

    The absolute magnitude of SNe Ia at maximum is calibrated here using radioactive decay models for the light curve and a minimum of assumptions. The absolute magnitude parameter space is studied using explosion models and a range of rise times, and absolute B magnitudes at maximum are used to derive a range of the H0 and the distance to the Virgo Cluster from SNe Ia. Rigorous limits for H0 of 45 and 105 km/s/Mpc are derived.

  6. Full field imaging based instantaneous hyperspectral absolute refractive index measurement

    SciTech Connect

    Baba, Justin S; Boudreaux, Philip R

    2012-01-01

    Multispectral refractometers typically measure refractive index (RI) at discrete monochromatic wavelengths via a serial process. We report on the demonstration of a white light full field imaging based refractometer capable of instantaneous multispectral measurement of absolute RI of clear liquid/gel samples across the entire visible light spectrum. The broad optical bandwidth refractometer is capable of hyperspectral measurement of RI in the range 1.30 1.70 between 400nm 700nm with a maximum error of 0.0036 units (0.24% of actual) at 414nm for a = 1.50 sample. We present system design and calibration method details as well as results from a system validation sample.

  7. Flow injection determination of formaldehyde by its catalytic effect on the oxidation of sulfonazo III by bromate with spectrophotometric detection.

    PubMed

    Ensafi, Ali Asghar; Honarmand, Ebrahim

    2005-05-01

    A simple and sensitive flow injection method with spectrophotometric detection was developed for the determination of formaldehyde. The method is based on the catalytic effect of formaldehyde on the oxidation of sulfonazo III with bromate in acidic media. The decrease in absorbance of the reaction mixture was measured at 566 nm. The calibration graph was linear in the range of 0.005 to 2.80 microg ml(-1) formaldehyde at a rate of 38 +/- 4 samples h(-1). The limit of detection was 4 ng ml(-1). The relative standard deviations for ten replicate measurements of 0.20, 0.50 and 1.00 microg ml(-1) formaldehyde were 1.3, 0.8 and 0.7%, respectively. The method was applied to the determination of formaldehyde in river water, shampoo and melamine-formaldehyde resin.

  8. [Wavelength interval selection by iteratively reinitialized GA and its application to spectrophotometric determination of components in cough syrup].

    PubMed

    Cheng, Biao; Wu, Xiao-hua; Chen, De-zhao

    2006-10-01

    Wavelength selection in PLS calibration can be used to reach two goals: improve the predictive ability and simplify the model. Iteratively reinitialized GA is a modified genetic algorithm, and it gives an initializing procedure of selecting the first candidates for every run of GA, which uses the results of previous runs as the guiding information. This algorithm can select wavelength regions instead of scattering points, which is very helpful in understanding the relevant parts of spectra. Furthermore, the continuous wavelength points make the PLS model more robust. Appling IRGA based wavelength selection to the UV-Vis spectrum of cough syrup, the result illustrates that PLS regression can greatly benefit from variable selection when used for multicomponent spectrophotometric determination. PMID:17205754

  9. Simultaneous spectrophotometric determination of calcium and magnesium in mineral waters by means of multivariate partial least-squares regression.

    PubMed

    Blasco, F; Medina-Hernández, M J; Sagrado, S; Fernández, F M

    1997-07-01

    A method for simultaneous spectrophotometric determination of calcium and magnesium in mineral waters using multivariate calibration methods is proposed. The method is based on the development of the reaction between the analytes and Methylthymol Blue at pH 11. Two operational modes were used: static (spectral information) and flow injection (FI) (spectral and kinetic information). The selection of variables was studied. A series of synthetic solutions containing different concentrations of calcium and magnesium were used to check the prediction ability of the partial least-squares models. The method was applied to the analysis of mineral waters and the results were compared with those obtained by complexometry. No significant differences at the 95% confidence level were found. The proposed method is simple, accurate and reproducible, and it could be easily adapted as a portable (static mode) or automatic (FI) method.

  10. Calibration aspects of the JEM-EUSO mission

    NASA Astrophysics Data System (ADS)

    Adams, J. H.; Ahmad, S.; Albert, J.-N.; Allard, D.; Anchordoqui, L.; Andreev, V.; Anzalone, A.; Arai, Y.; Asano, K.; Ave Pernas, M.; Baragatti, P.; Barrillon, P.; Batsch, T.; Bayer, J.; Bechini, R.; Belenguer, T.; Bellotti, R.; Belov, K.; Berlind, A. A.; Bertaina, M.; Biermann, P. L.; Biktemerova, S.; Blaksley, C.; Blanc, N.; Błȩcki, J.; Blin-Bondil, S.; Blümer, J.; Bobik, P.; Bogomilov, M.; Bonamente, M.; Briggs, M. S.; Briz, S.; Bruno, A.; Cafagna, F.; Campana, D.; Capdevielle, J.-N.; Caruso, R.; Casolino, M.; Cassardo, C.; Castellinic, G.; Catalano, C.; Catalano, G.; Cellino, A.; Chikawa, M.; Christl, M. J.; Cline, D.; Connaughton, V.; Conti, L.; Cordero, G.; Crawford, H. J.; Cremonini, R.; Csorna, S.; Dagoret-Campagne, S.; de Castro, A. J.; De Donato, C.; de la Taille, C.; De Santis, C.; del Peral, L.; Dell'Oro, A.; De Simone, N.; Di Martino, M.; Distratis, G.; Dulucq, F.; Dupieux, M.; Ebersoldt, A.; Ebisuzaki, T.; Engel, R.; Falk, S.; Fang, K.; Fenu, F.; Fernández-Gómez, I.; Ferrarese, S.; Finco, D.; Flamini, M.; Fornaro, C.; Franceschi, A.; Fujimoto, J.; Fukushima, M.; Galeotti, P.; Garipov, G.; Geary, J.; Gelmini, G.; Giraudo, G.; Gonchar, M.; González Alvarado, C.; Gorodetzky, P.; Guarino, F.; Guzmán, A.; Hachisu, Y.; Harlov, B.; Haungs, A.; Hernández Carretero, J.; Higashide, K.; Ikeda, D.; Ikeda, H.; Inoue, N.; Inoue, S.; Insolia, A.; Isgrò, F.; Itow, Y.; Joven, E.; Judd, E. G.; Jung, A.; Kajino, F.; Kajino, T.; Kaneko, I.; Karadzhov, Y.; Karczmarczyk, J.; Karus, M.; Katahira, K.; Kawai, K.; Kawasaki, Y.; Keilhauer, B.; Khrenov, B. A.; Kim, J.-S.; Kim, S.-W.; Kim, S.-W.; Kleifges, M.; Klimov, P. A.; Kolev, D.; Kreykenbohm, I.; Kudela, K.; Kurihara, Y.; Kusenko, A.; Kuznetsov, E.; Lacombe, M.; Lachaud, C.; Lee, J.; Licandro, J.; Lim, H.; López, F.; Maccarone, M. C.; Mannheim, K.; Maravilla, D.; Marcelli, L.; Marini, A.; Martinez, O.; Masciantonio, G.; Mase, K.; Matev, R.; Medina-Tanco, G.; Mernik, T.; Miyamoto, H.; Miyazaki, Y.; Mizumoto, Y.; Modestino, G.; Monaco, A.; Monnier-Ragaigne, D.; Morales de los Ríos, J. A.; Moretto, C.; Morozenko, V. S.; Mot, B.; Murakami, T.; Murakami, M. Nagano; Nagata, M.; Nagataki, S.; Nakamura, T.; Napolitano, T.; Naumov, D.; Nava, R.; Neronov, A.; Nomoto, K.; Nonaka, T.; Ogawa, T.; Ogio, S.; Ohmori, H.; Olinto, A. V.; Orleański, P.; Osteria, G.; Panasyuk, M. I.; Parizot, E.; Park, I. H.; Park, H. W.; Pastircak, B.; Patzak, T.; Paul, T.; Pennypacker, C.; Perez Cano, S.; Peter, T.; Picozza, P.; Pierog, T.; Piotrowski, L. W.; Piraino, S.; Plebaniak, Z.; Pollini, A.; Prat, P.; Prévôt, G.; Prieto, H.; Putis, M.; Reardon, P.; Reyes, M.; Ricci, M.; Rodríguez, I.; Rodríguez Frías, M. D.; Ronga, F.; Roth, M.; Rothkaehl, H.; Roudil, G.; Rusinov, I.; Rybczyński, M.; Sabau, M. D.; Sáez-Cano, G.; Sagawa, H.; Saito, A.; Sakaki, N.; Sakata, M.; Salazar, H.; Sánchez, S.; Santangelo, A.; Santiago Crúz, L.; Sanz Palomino, M.; Saprykin, O.; Sarazin, F.; Sato, H.; Sato, M.; Schanz, T.; Schieler, H.; Scotti, V.; Segreto, A.; Selmane, S.; Semikoz, D.; Serra, M.; Sharakin, S.; Shibata, T.; Shimizu, H. M.; Shinozaki, K.; Shirahama, T.; Siemieniec-Oziȩbło, G.; Silva López, H. H.; Sledd, J.; Słomińska, K.; Sobey, A.; Sugiyama, T.; Supanitsky, D.; Suzuki, M.; Szabelska, B.; Szabelski, J.; Tajima, F.; Tajima, N.; Tajima, T.; Takahashi, Y.; Takami, H.; Takeda, M.; Takizawa, Y.; Tenzer, C.; Tibolla, O.; Tkachev, L.; Tokuno, H.; Tomida, T.; Tone, N.; Toscano, S.; Trillaud, F.; Tsenov, R.; Tsunesada, Y.; Tsuno, K.; Tymieniecka, T.; Uchihori, Y.; Unger, M.; Vaduvescu, O.; Valdés-Galicia, J. F.; Vallania, P.; Valore, L.; Vankova, G.; Vigorito, C.; Villaseñor, L.; von Ballmoos, P.; Wada, S.; Watanabe, J.; Watanabe, S.; Watts, J.; Weber, M.; Weiler, T. J.; Wibig, T.; Wiencke, L.; Wille, M.; Wilms, J.; Włodarczyk, Z.; Yamamoto, T.; Yamamoto, Y.; Yang, J.; Yano, H.; Yashin, I. V.; Yonetoku, D.; Yoshida, K.; Yoshida, S.; Young, R.; Zotov, M. Yu.; Zuccaro Marchi, A.

    2015-11-01

    The JEM-EUSO telescope will be, after calibration, a very accurate instrument which yields the number of received photons from the number of measured photo-electrons. The project is in phase A (demonstration of the concept) including already operating prototype instruments, i.e. many parts of the instrument have been constructed and tested. Calibration is a crucial part of the instrument and its use. The focal surface (FS) of the JEM-EUSO telescope will consist of about 5000 photo-multiplier tubes (PMTs), which have to be well calibrated to reach the required accuracy in reconstructing the air-shower parameters. The optics system consists of 3 plastic Fresnel (double-sided) lenses of 2.5 m diameter. The aim of the calibration system is to measure the efficiencies (transmittances) of the optics and absolute efficiencies of the entire focal surface detector. The system consists of 3 main components: (i) Pre-flight calibration devices on ground, where the efficiency and gain of the PMTs will be measured absolutely and also the transmittance of the optics will be. (ii) On-board relative calibration system applying two methods: a) operating during the day when the JEM-EUSO lid will be closed with small light sources on board. b) operating during the night, together with data taking: the monitoring of the background rate over identical sites. (iii) Absolute in-flight calibration, again, applying two methods: a) measurement of the moon light, reflected on high altitude, high albedo clouds. b) measurements of calibrated flashes and tracks produced by the Global Light System (GLS). Some details of each calibration method will be described in this paper.

  11. Automated Camera Calibration

    NASA Technical Reports Server (NTRS)

    Chen, Siqi; Cheng, Yang; Willson, Reg

    2006-01-01

    Automated Camera Calibration (ACAL) is a computer program that automates the generation of calibration data for camera models used in machine vision systems. Machine vision camera models describe the mapping between points in three-dimensional (3D) space in front of the camera and the corresponding points in two-dimensional (2D) space in the camera s image. Calibrating a camera model requires a set of calibration data containing known 3D-to-2D point correspondences for the given camera system. Generating calibration data typically involves taking images of a calibration target where the 3D locations of the target s fiducial marks are known, and then measuring the 2D locations of the fiducial marks in the images. ACAL automates the analysis of calibration target images and greatly speeds the overall calibration process.

  12. Analytical multicollimator camera calibration

    USGS Publications Warehouse

    Tayman, W.P.

    1978-01-01

    Calibration with the U.S. Geological survey multicollimator determines the calibrated focal length, the point of symmetry, the radial distortion referred to the point of symmetry, and the asymmetric characteristiecs of the camera lens. For this project, two cameras were calibrated, a Zeiss RMK A 15/23 and a Wild RC 8. Four test exposures were made with each camera. Results are tabulated for each exposure and averaged for each set. Copies of the standard USGS calibration reports are included. ?? 1978.

  13. Absolute magnitudes of trans-neptunian objects

    NASA Astrophysics Data System (ADS)

    Duffard, R.; Alvarez-candal, A.; Pinilla-Alonso, N.; Ortiz, J. L.; Morales, N.; Santos-Sanz, P.; Thirouin, A.

    2015-10-01

    Accurate measurements of diameters of trans- Neptunian objects are extremely complicated to obtain. Radiomatric techniques applied to thermal measurements can provide good results, but precise absolute magnitudes are needed to constrain diameters and albedos. Our objective is to measure accurate absolute magnitudes for a sample of trans- Neptunian objects, many of which have been observed, and modelled, by the "TNOs are cool" team, one of Herschel Space Observatory key projects grantes with ~ 400 hours of observing time. We observed 56 objects in filters V and R, if possible. These data, along with data available in the literature, was used to obtain phase curves and to measure absolute magnitudes by assuming a linear trend of the phase curves and considering magnitude variability due to rotational light-curve. In total we obtained 234 new magnitudes for the 56 objects, 6 of them with no reported previous measurements. Including the data from the literature we report a total of 109 absolute magnitudes.

  14. A New Gimmick for Assigning Absolute Configuration.

    ERIC Educational Resources Information Center

    Ayorinde, F. O.

    1983-01-01

    A five-step procedure is provided to help students in making the assignment absolute configuration less bothersome. Examples for both single (2-butanol) and multi-chiral carbon (3-chloro-2-butanol) molecules are included. (JN)

  15. The Simplicity Argument and Absolute Morality

    ERIC Educational Resources Information Center

    Mijuskovic, Ben

    1975-01-01

    In this paper the author has maintained that there is a similarity of thought to be found in the writings of Cudworth, Emerson, and Husserl in his investigation of an absolute system of morality. (Author/RK)

  16. Simultaneous spectrophotometric determination of nitroaniline isomers after cloud point extraction by using least-squares support vector machines

    NASA Astrophysics Data System (ADS)

    Niazi, Ali; Ghasemi, Jahanbakhsh; Yazdanipour, Ateesa

    2007-11-01

    Cloud point extraction has been used for the preconcentration of m-nitroaniline, o-nitroaniline and p-nitroaniline and later simultaneous spectrophotometric determination using polyethylene glycol tert-octylphenyl ether (Triton X-100) as surfactant. The resolution of a ternary mixture of the nitroaniline isomers (after extraction by cloud point) by the application of least-squares support vector machines (LS-SVM) was performed. The chemical parameters affecting the separation phase and detection process were studied and optimized. Under the optimum experimental conditions (i.e. pH 7.0, Triton X-100 = 0.6%, equilibrium time 20 min and cloud point 75 °C), calibration graphs were linear in the range of 0.2-20.0, 0.1-15.0 and 0.1-17.0 μg ml -1 with detection limits of 0.08, 0.05 and 0.06 μg ml -1 for m-nitroaniline, o-nitroaniline and p-nitroaniline, respectively. The experimental calibration matrix was designed with 21 mixtures of these chemicals. The concentrations were varied between calibration graphs concentrations of nitroaniline isomers. The root mean square error of prediction (RMSEP) for m-nitroaniline, o-nitroaniline and p-nitroaniline were 0.0146, 0.0308 and 0.0304, respectively. This procedure allows the simultaneous determination of nitroaniline isomers in synthetic and real matrix samples good reliability of the determination was proved.

  17. Landsat-8 Thermal Infrared Sensor (TIRS) Vicarious Radiometric Calibration

    NASA Technical Reports Server (NTRS)

    Barsi, Julia A.; Shott, John R.; Raqueno, Nina G.; Markham, Brian L.; Radocinski, Robert G.

    2014-01-01

    Launched in February 2013, the Landsat-8 carries on-board the Thermal Infrared Sensor (TIRS), a two-band thermal pushbroom imager, to maintain the thermal imaging capability of the Landsat program. The TIRS bands are centered at roughly 10.9 and 12 micrometers (Bands 10 and 11 respectively). They have 100 m spatial resolution and image coincidently with the Operational Land Imager (OLI), also on-board Landsat-8. The TIRS instrument has an internal calibration system consisting of a variable temperature blackbody and a special viewport with which it can see deep space; a two point calibration can be performed twice an orbit. Immediately after launch, a rigorous vicarious calibration program was started to validate the absolute calibration of the system. The two vicarious calibration teams, NASA/Jet Propulsion Laboratory (JPL) and the Rochester Institute of Technology (RIT), both make use of buoys deployed on large water bodies as the primary monitoring technique. RIT took advantage of cross-calibration opportunity soon after launch when Landsat-8 and Landsat-7 were imaging the same targets within a few minutes of each other to perform a validation of the absolute calibration. Terra MODIS is also being used for regular monitoring of the TIRS absolute calibration. The buoy initial results showed a large error in both bands, 0.29 and 0.51 W/sq m·sr·micrometers or -2.1 K and -4.4 K at 300 K in Band 10 and 11 respectively, where TIRS data was too hot. A calibration update was recommended for both bands to correct for a bias error and was implemented on 3 February 2014 in the USGS/EROS processing system, but the residual variability is still larger than desired for both bands (0.12 and 0.2 W/sq m·sr·micrometers or 0.87 and 1.67 K at 300 K). Additional work has uncovered the source of the calibration error: out-of-field stray light. While analysis continues to characterize the stray light contribution, the vicarious calibration work proceeds. The additional data have

  18. Calibration of a helium-cooled infrared spatial radiometer and grating spectrometer

    NASA Technical Reports Server (NTRS)

    Jacobsen, Larry; Sargent, Steve; Wyatt, Clair L.; Steed, Allan J.

    1992-01-01

    Methods used by the Space Dynamics Laboratory of Utah State University (SDL/USU) to calibrate infrared sensors are described, using the Infrared Background Signature Survey (IBSS) spatial radiometer and grating spectrometer as examples. A calibration equation and a radiometric model are given for each sensor to describe their responsivity in terms of individual radiometric parameters. The calibration equation terms include dark offset, linearity, absolute responsivity, and measurement uncertainty, and the radiometric model domains include spatial, spectral, and temporal domains. A portable calibration facility, designed and fabricated by SDL/USU, provided collimated, extended, diffuse scatter, and Jones sources in a single cryogenic dewar. This multi-function calibrator allowed calibration personnel to complete a full calibration of the IBSS infrared radiometer and spectrometer in two 15-day periods. A calibration data system was developed to control and monitor the calibration facility, and to record and analyze sensor data.

  19. 40 CFR 1065.340 - Diluted exhaust flow (CVS) calibration.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... concentration as the independent variable and flow rate as the dependent variable. For each data point... PDP speed to the first speed point at which you intend to calibrate. (5) Set the variable restrictor... temperature at the CFV inlet within ±2% of the mean absolute inlet temperature, T in. (5) Set the...

  20. Calibration Research: Where Do We Go from Here?

    PubMed Central

    Bol, Linda; Hacker, Douglas J.

    2012-01-01

    Research on calibration remains a popular line of inquiry. Calibration is the degree of fit between a person’s judgment of performance and his or her actual performance. Given the continued interest in this topic, the questions posed in this article are fruitful directions to pursue to help address gaps in calibration research. In this article, we have identified six research directions that if productively pursued, could greatly expand our knowledge of calibration. The six research directions are: (a) what are the effects of varying the anchoring mechanisms from which calibration judgments are made, (b) how does calibration accuracy differ as a function of incentives and task authenticity, (c) how do students self-report the basis of their calibration judgments, (d) how do group interactions and social comparisons affect calibration accuracy, (e) what is the relation between absolute and relative accuracy, and (f) to what extent does calibration accuracy predict achievement? To help point the way to where we go from here in calibration research, we provide these research questions, propose research methods designed to address them, and identify prior, related studies that have shown promise in leading the way to fill these gaps in the literature. PMID:22866041

  1. Calibration research: where do we go from here?

    PubMed

    Bol, Linda; Hacker, Douglas J

    2012-01-01

    Research on calibration remains a popular line of inquiry. Calibration is the degree of fit between a person's judgment of performance and his or her actual performance. Given the continued interest in this topic, the questions posed in this article are fruitful directions to pursue to help address gaps in calibration research. In this article, we have identified six research directions that if productively pursued, could greatly expand our knowledge of calibration. The six research directions are: (a) what are the effects of varying the anchoring mechanisms from which calibration judgments are made, (b) how does calibration accuracy differ as a function of incentives and task authenticity, (c) how do students self-report the basis of their calibration judgments, (d) how do group interactions and social comparisons affect calibration accuracy, (e) what is the relation between absolute and relative accuracy, and (f) to what extent does calibration accuracy predict achievement? To help point the way to where we go from here in calibration research, we provide these research questions, propose research methods designed to address them, and identify prior, related studies that have shown promise in leading the way to fill these gaps in the literature. PMID:22866041

  2. MODIS Solar Reflective Calibration Traceability

    NASA Technical Reports Server (NTRS)

    Xiong, Xiaoxiong; Butler, Jim

    2009-01-01

    Long-term climate data records often consist of observations made by multiple sensors. It is, therefore, extremely important to have instrument overlap, to be able to track instrument stability, to quantify, measurement uncertainties, and to establish absolute scale traceable to the International System of Units (SI). The Moderate Resolution Imaging Spectroradiometer (MODIS) is a key instrument for both the Terra and Aqua missions, which were launched in December 1999 and May 2002, respectively. It has 20 reflective solar bands (RSB) with wavelengths from 0.41 to 2.2 micrometers and observes the Earth at three nadir spatial resolutions: 0.25km, 0.5km, and 1km. MODIS RSB on-orbit calibration is reflectance based with reference to the bidirectional reflectance factor (BRF) of its on-board solar diffuser (SD). The SD BRF characterization was made pre-launch by the instrument vendor using reference samples traceable directly to the National Institute of Standards and Technology (NIST). On-orbit SD reflectance degradation is tracked by an on-board solar diffuser monitor (SDSM). This paper provides details of this calibration chain, from prelaunch to on-orbit operation, and associated uncertainty assessments. Using MODIS as an example, this paper also discusses challenges and key design requirements for future missions developed for accurate climate studies.

  3. Validation of a spectrophotometric method for quantification of xanthone in biodegradable nanoparticles.

    PubMed

    Teixeira, M; Pinto, M M M; Barbosa, C M

    2004-04-01

    Xanthone has been incorporated for the first time in nanoparticles of poly(D,L-lactide-co-glycolide) (PLGA). For this purpose the estimation of xanthone content in the nanoparticles is a crucial tool for guaranteeing the reliability of the results. Thus, a simple spectrophotometric method was validated according to USP25 and ICH guidelines for its specificity, linearity, accuracy and precision. The method was found to be specific for xanthone in the presence of nanoparticle excipients. The calibration curve was linear over the concentration range of 0.5 to 4.0 microg/mL (r > 0.999). Recovery of xanthone from nanoparticles ranged from 86.5 to 95.9%. Repeatability (intra-assay precision) and intermediate precision were found to be acceptable with relative standard deviations values (RSD) ranging from 0.3 to 3.0% and from 1.4 to 3.1%, respectively. The method was found to be suitable for the evaluation of xanthone content in nanoparticles of PLGA.

  4. Determination of ammonia in beers by pervaporation flow injection analysis and spectrophotometric detection.

    PubMed

    Wang, Lijuan; Cardwell, Terence J; Cattrall, Robert W; Luque de Castro, Maria D; Kolev, Spas D

    2003-08-29

    A pervaporation flow injection (PFI) method is described for the determination of ammonia in beers. After injecting the sample into a NaOH donor solution, ammonia and other volatiles are transferred in the pervaporation unit from the donor stream to an acceptor stream containing sodium salicylate and nitroprusside, which subsequently mixes with alkaline sodium dichloroisocyanurate to allow the classical Berthelot reaction to take place. The blue-coloured complex formed is monitored spectrophotometrically at 655 nm. A linear calibration curve with a range of 0.1-40 mg l(-1) was obtained. The method has a detection limit of 0.05 mg l(-1) and is capable of a sampling frequency of 11 h(-1) at 4 mg l(-1) ammonia. It was applied successfully to the determination of ammonia in synthetic samples and unfiltered lager beers. The advantages of the present method over the ammonia ion-selective electrode method and the PFI system based on mixed indicator detection are discussed. PMID:18969154

  5. Extractive spectrophotometric determination of some nonsteroidal anti-inflammatory drugs using methylene blue.

    PubMed

    El-Kommos, Michael E; Mohamed, Niveen A; Hakiem, Ahmed F Abdel

    2013-01-01

    A simple, rapid, sensitive, and accurate extractive spectrophotometric method has been developed for the determination of seven nonsteroidal anti-inflammatory drugs (NSAIDs)--namely diclofenac sodium, ibuprofen, indomethacin, ketoprofen, ketorolac tromethamine, mefenamic acid, and naproxen-in pure forms as well as their pharmaceutical dosage forms (tablets, capsules, effervescent granules, syrups, oral drops, ampules, eye drops, gels, and suppositories). The method depends on the formation of an intensely colored ion-pair complex between the acidic drug and methylene blue in alkaline medium. The complex is stable and extractable into methylene chloride. All parameters were optimized. Beer-Lambert's law was obeyed in concentrations ranging from 0.04 to 9 microg/mL. Statistical analysis of the calibration data was carried out, and correlation coefficients were in the range from 0.9996 to 0.9998. The developed method was fully validated according to International Conference on Harmonization guidelines, and complied with U.S. Pharmacopeia guidelines. The proposed method was applied to the analysis of the investigated drugs in their pharmaceutical formulations, and good recoveries were obtained. The results obtained were compared with those of reported and official methods, and no significant differences were found with t- and F-tests. Interference effects of some compounds usually present in combination with NSAIDs were studied, and the tolerance limits of these compounds were determined. PMID:24000745

  6. Automated spectrophotometric assay for urine p-aminophenol by an oxidative coupling reaction.

    PubMed

    Chen, Chi-Fen; Tseng, Yung-Te; Tseng, Hsiu-Kuei; Liu, Tsan-Zon

    2004-01-01

    Urine p-aminophenol (PAP) concentration serves as a biological marker for occupational exposures to aniline. We report the development of a rapid, simple spectrophotometric method for quantification of urine PAP concentration using a chemical autoanalyzer (Olympus Reply). The method involves oxidative coupling of PAP with an aromatic compound, xylenol, that contains an electron-donating group, based on an electrophilic aromatic substitution reaction catalyzed by sodium periodate. A calibration curve is constructed in the same matrix, urine, as the unknown samples to be analyzed. In this way, potential matrix interferences are largely avoided. The linearity range of the method is 20 to 400 mg/L. Time-course studies show that the color formation by reaction of PAP with xylenol is rapid and essentially complete within 5 min. Within-run and day-to-day reproducibility data at medium (50 mg/L) and high (200 mg/L) concentrations yield CV's <5.0%. Several prescription drugs and drugs of abuse, as well as related compounds, gave negative tests for interference in the procedure. Clinical applications of the method are illustrated by data for (a) PAP concentrations in 255 urine samples from workers at a rubber plant, and (b) PAP elimination in serial urine samples from 5 volunteers after an oral dose (500 mg) of acetaminophen. In summary, the new method has the advantages of automation, operational simplicity, and suitability for monitoring workers for exposures to aniline.

  7. Multivariate curve resolution of spectrophotometric data for the determination of artificial food colors.

    PubMed

    Lachenmeier, Dirk W; Kessler, Waltraud

    2008-07-23

    In the analysis of food additives, past emphasis was put on the development of chromatographic techniques to separate target components from a complex matrix. Especially in the case of artificial food colors, direct spectrophotometric measurement was seen to lack in specificity due to a high spectral overlap between different components. Multivariate curve resolution (MCR) may be used to overcome this limitation. MCR is able to (i) extract from a complex spectral feature the number of involved components, (ii) attribute the resulting spectra to chemical compounds, and (iii) quantify the individual spectral contributions with or without a priori knowledge. We have evaluated MCR for the routine analysis of yellow and blue food colors in absinthe spirits. Using calibration standards, we were able to show that MCR equally performs as compared to partial least-squares regression but with much improved chemical information contained in the predicted spectra. MCR was then applied to an authentic collective of different absinthes. As confirmed by reference analytics, the food colors were correctly assigned with a sensitivity of 0.93 and a specificity of 0.85. Besides the artificial colors, the algorithm detected a further component in some samples that could be assigned to natural coloring from chlorophyll.

  8. Spectrophotometric determination of pipazethate HCl, dextromethorphan HBr and drotaverine HCl in their pharmaceutical preparations.

    PubMed

    Amin, Alaa S; El-Sheikh, Ragaa; Zahran, Faten; Gouda, Ayman Abou El-fetouh

    2007-07-01

    A simple, accurate and highly sensitive spectrophotometric method is proposed for the rapid determination of pipazethate hydrochloride, dextromethorphan hydrobromide and drotaverine hydrochloride using chromotrope 2B (C2B) and chromotrope 2R (C2R). The method consists of extracting the formed ion-associates into chloroform in the case of pipazethate HCl and dextromethorphan HBr or into methylene chloride in the case of drotaverine HCl. The ion-associates exhibit absorption maxima at 528, 540 and 532 nm with C2B and at 526, 517 and 522 nm with C2R for pipazethate HCl, dextromethorphan HBr and drotaverine HCl, respectively. The calibration curves resulting from the measurements of absorbance-concentration relations (at the optimum reaction conditions) of the extracted ion-pairs are linear over the concentration range 4.36-52.32 microg mL(-1) for pipazethate, 3.7-48.15 microg mL(-1) for dextromethorphan and 4.34-60.76 microg mL(-1) for drotaverine, respectively. The effect of acidity, reagent concentration, time, solvent and stoichiometric ratio of the ion-associates were estimated. The molar absorptivity and Sandell sensitivity of the reaction products were calculated. Statistical treatment of the results reflects that the procedure is precise, accurate and easily applied for the determination of the drugs under investigation in pure form and in their pharmaceutical preparations.

  9. Selective Cloud Point Extraction for the Spectrophotometric Determination of Cetylpyridinium Chloride in Pharmaceutical Formulations

    PubMed Central

    Zarei, Ali Reza; Bagheri Sadeghi, Hayedeh; Abedin, Samira

    2013-01-01

    In this work, we developed a simple and selective method for separation and spectrophotometric determination of trace amounts of cetylpyridinium chloride (CPC) in pharmaceutical products using cloud point extraction (CPE) technique. The method is based on cloud point extraction of the CPC in alkali conditions using of nonionic surfactant Triton X-114. Under optimal conditions, the calibration graph was linear in the range of 0.50-30 μg/ mL of CPC with r=0.9993 (n=10). Average recoveries for spiked samples were determined to be between 95–104%. The relative standard deviation (RSD) for 5.0 μg/mL of CPC was 1.86 % (n=10). Also, the use of micellar extraction for extracting CPC was enhanced the molar absorptivity (ε) from 1.83×103 L/mol.cm in aqueous solution to 1.539×104 L/mol.cm in surfactant-rich phase. The proposed method was applied for the determination of CPC in a commercial mouth washer product PMID:24523746

  10. A Highly Sensitive Kinetic Spectrophotometric Method for the Determination of Ascorbic Acid in Pharmaceutical Samples

    PubMed Central

    Shishehbore, Masoud Reza; Aghamiri, Zahra

    2014-01-01

    In this study, a new reaction system for quantitative determination of ascorbic acid was introduced. The developed method is based on inhibitory effect of ascorbic acid on the Orange G-bromate system. The change in absorbance was followed spectrophotometrically at 478 nm. The dependence of sensitivity on the reaction variables including reagents concentration, temperature and time was investigated. Under optimum experimental conditions, calibration curve was linear over the range 0.7 – 33.5 μg mL-1 of ascorbic acid including two linear segments and the relative standard deviations (n = 6) for 5.0 and 20.0 μg mL–1 of ascorbic acid were 1.08 and 1.02%, respectively. The limit of detection was 0.21 μg mL−1 of ascorbic acid. The effect of diverse species was also investigated. The developed method was successfully applied for the determination of ascorbic acid in pharmaceutical samples. The results were in a good agreement with those of reference method. PMID:25237333

  11. Selective cloud point extraction for the spectrophotometric determination of cetylpyridinium chloride in pharmaceutical formulations.

    PubMed

    Zarei, Ali Reza; Bagheri Sadeghi, Hayedeh; Abedin, Samira

    2013-01-01

    In this work, we developed a simple and selective method for separation and spectrophotometric determination of trace amounts of cetylpyridinium chloride (CPC) in pharmaceutical products using cloud point extraction (CPE) technique. The method is based on cloud point extraction of the CPC in alkali conditions using of nonionic surfactant Triton X-114. Under optimal conditions, the calibration graph was linear in the range of 0.50-30 μg/ mL of CPC with r=0.9993 (n=10). Average recoveries for spiked samples were determined to be between 95-104%. The relative standard deviation (RSD) for 5.0 μg/mL of CPC was 1.86 % (n=10). Also, the use of micellar extraction for extracting CPC was enhanced the molar absorptivity (ε) from 1.83×10(3) L/mol.cm in aqueous solution to 1.539×10(4) L/mol.cm in surfactant-rich phase. The proposed method was applied for the determination of CPC in a commercial mouth washer product.

  12. Preconcentration and Spectrophotometric Determination of a Naphthalene Analog of Medetomidine Using Modified Maghemite Nanoparticles

    NASA Astrophysics Data System (ADS)

    Maddah, B.; Hosseini, F.; Ahmadi, M.; Rajabi, A. Asghar; Beik-Mohammadlood, Z.

    2016-05-01

    A novel and sensitive extraction procedure using sodium dodecyl sulfate (SDS) modified maghemite nanoparticles (MNPs) as an efficient solid phase has been developed for removal, preconcentration, and spectrophotometric determination of trace amounts of a naphthalene analog of dexmedetomidine (4-(1-(na phthalene-1-yl)ethyl)-1Himidazole, NMED). The MNPs were obtained by a coprecipitation method, and their surfaces were furthermore modified by SDS. The size and morphological properties of the synthesized MNPs were determined by X-ray diffraction analysis, FT-IR, vibrating sample magnetometry, and scanning electron microscopy. NMED was adsorbed at pH 3.0. The adsorbed drug was then desorbed and determined by spectrophotometry at 280 nm. The calibration graph was linear in the range 1 × 10-6-1 × 10-4 mol/L of NMED with a correlation coefficient of 0.989. The detection limit of the method for NMED determination was 3.7 × 10-7 mol/L. The method was successfully applied to the determination of NMED in human urine samples.

  13. Novel Spectrophotometric Method for the Determination of Pindolol in Pharmaceutical Samples

    NASA Astrophysics Data System (ADS)

    Nagaraja, P.; Kumar, H. R. Arun; Bhaskara, B. L.; Kumar, S. Anil

    2011-10-01

    A new facile and sensitive spectrophotometric determination of Pindolol (PDL), a beta blocker drug has been developed and validated. The method was based on the reaction between pindolol and K3 [Fe(CN)6] in presence of FeCl3 to form Prussian blue. The absorbance values were recorded at 700 nm and a calibrated graph was constructed. A dynamic Beer's law range was observed in the range 0.125-2.5 μg mL-1 with a detection limit of 0.03 μg mL-1 and a quantitation limit of 0.08 μg mL-1. Various experimental parameters such as effect of solvents, stability, interference effects due to excipients etc were studied. The reproducibility of this methods were checked by six replicate determinations at 1.0 μg ml-1 PDL and the standard deviation was found to be between 0.20 and 0.42%. The results were statistically compared with those of the reference/literature method by applying Student's t-test and F-test. The sensitivity, simplicity, temperature independence and stability of the colored product are the advantages of the proposed method and it is also free from extraction steps and use of carcinogenic solvents.

  14. Incipient fault diagnosis of power transformers using optical spectro-photometric technique

    NASA Astrophysics Data System (ADS)

    Hussain, K.; Karmakar, Subrata

    2015-06-01

    Power transformers are the vital equipment in the network of power generation, transmission and distribution. Mineral oil in oil-filled transformers plays very important role as far as electrical insulation for the winding and cooling of the transformer is concerned. As transformers are always under the influence of electrical and thermal stresses, incipient faults like partial discharge, sparking and arcing take place. As a result, mineral oil deteriorates there by premature failure of the transformer occurs causing huge losses in terms of revenue and assets. Therefore, the transformer health condition has to be monitored continuously. The Dissolved Gas Analysis (DGA) is being extensively used for this purpose, but it has some drawbacks like it needs carrier gas, regular instrument calibration, etc. To overcome these drawbacks, Ultraviolet (UV) -Visible and Fourier Transform Infrared (FTIR) Spectro-photometric techniques are used as diagnostic tools for investigating the degraded transformer oil affected by electrical, mechanical and thermal stresses. The technique has several advantages over the conventional DGA technique.

  15. The solar absolute spectral irradiance 1150-3173 A - May 17, 1982

    NASA Technical Reports Server (NTRS)

    Mount, G. H.; Rottman, G. J.

    1983-01-01

    The full-disk solar spectral irradiance in the spectral range 1150-3173 A was obtained from a rocket observation above White Sands Missile Range, NM, on May 17, 1982, half way in time between solar maximum and solar minimum. Comparison with measurements made during solar maximum in 1980 indicate a large decrease in the absolute solar irradiance at wavelengths below 1900 A to approximately solar minimum values. No change above 1900 A from solar maximum to this flight was observed to within the errors of the measurements. Irradiance values lower than the Broadfoot results in the 2100-2500 A spectral range are found, but excellent agreement with Broadfoot between 2500 and 3173 A is found. The absolute calibration of the instruments for this flight was accomplished at the National Bureau of Standards Synchrotron Radiation Facility which significantly improves calibration of solar measurements made in this spectral region.

  16. Spectrophotometric and fluorimetric determination of diazepam, bromazepam and clonazepam in pharmaceutical and urine samples

    NASA Astrophysics Data System (ADS)

    Salem, A. A.; Barsoum, B. N.; Izake, E. L.

    2004-03-01

    New spectrophotometric and fluorimetric methods have been developed to determine diazepam, bromazepam and clonazepam (1,4-benzodiazepines) in pure forms, pharmaceutical preparations and biological fluid. The new methods are based on measuring absorption or emission spectra in methanolic potassium hydroxide solution. Fluorimetric methods have proved selective with low detection limits, whereas photometric methods showed relatively high detection limits. Successive applications of developed methods for drugs determination in pharmaceutical preparations and urine samples were performed. Photometric methods gave linear calibration graphs in the ranges of 2.85-28.5, 0.316-3.16, and 0.316-3.16 μg ml -1 with detection limits of 1.27, 0.08 and 0.13 μg ml -1 for diazepam, bromazepam and clonazepam, respectively. Corresponding average errors of 2.60, 5.26 and 3.93 and relative standard deviations (R.S.D.s) of 2.79, 2.12 and 2.83, respectively, were obtained. Fluorimetric methods gave linear calibration graphs in the ranges of 0.03-0.34, 0.03-0.32 and 0.03-0.38 μg ml -1 with detection limits of 7.13, 5.67 and 16.47 ng ml -1 for diazepam, bromazepam and clonazepam, respectively. Corresponding average errors of 0.29, 4.33 and 5.42 and R.S.D.s of 1.27, 1.96 and 1.14 were obtained, respectively. Statistical Students t-test and F-test have been used and satisfactory results were obtained.

  17. OARE flight maneuvers and calibration measurements on STS-58

    NASA Technical Reports Server (NTRS)

    Blanchard, Robert C.; Nicholson, John Y.; Ritter, James R.; Larman, Kevin T.

    1994-01-01

    The Orbital Acceleration Research Experiment (OARE), which has flown on STS-40, STS-50, and STS-58, contains a three axis accelerometer with a single, nonpendulous, electrostatically suspended proofmass which can resolve accelerations to the nano-g level. The experiment also contains a full calibration station to permit in situ bias and scale factor calibration. This on-orbit calibration capability eliminates the large uncertainty of ground-based calibrations encountered with accelerometers flown in the past on the orbiter, thus providing absolute acceleration measurement accuracy heretofore unachievable. This is the first time accelerometer scale factor measurements have been performed on orbit. A detailed analysis of the calibration process is given along with results of the calibration factors from the on-orbit OARE flight measurements on STS-58. In addition, the analysis of OARE flight maneuver data used to validate the scale factor measurements in the sensor's most sensitive range is also presented. Estimates on calibration uncertainties are discussed. This provides bounds on the STS-58 absolute acceleration measurements for future applications.

  18. SUMS calibration test report

    NASA Technical Reports Server (NTRS)

    Robertson, G.

    1982-01-01

    Calibration was performed on the shuttle upper atmosphere mass spectrometer (SUMS). The results of the calibration and the as run test procedures are presented. The output data is described, and engineering data conversion factors, tables and curves, and calibration on instrument gauges are included. Static calibration results which include: instrument sensitive versus external pressure for N2 and O2, data from each scan of calibration, data plots from N2 and O2, and sensitivity of SUMS at inlet for N2 and O2, and ratios of 14/28 for nitrogen and 16/32 for oxygen are given.

  19. Standalone Calibration Toolset

    NASA Astrophysics Data System (ADS)

    Cooper, M.

    2013-12-01

    Radioxenon measurements require a well calibrated nuclear detector, which typically requires several weeks to perform a complex analysis of the resulting data to determine the detection efficiencies. To reduce the need to have an expert in nuclear physics, PNNL has developed a Standalone Calibration Toolset (SCT), which will aid an analyst in B-y nuclear detector calibration. SCT takes data generated from measurement of isotopically pure calibration samples: Xe-135, Xe-133, Xe-133m and Xe-131m, and generates nuclear detector configuration files. This will result in a simplified calibration and will make verification and corrections to b-g detectors routine.

  20. The molecular branching ratio method for calibration of optical systems in the vacuum ultraviolet

    NASA Technical Reports Server (NTRS)

    Mumma, M. J.

    1972-01-01

    The intensity distribution of bands belonging to six molecular band systems is discussed with special emphasis on their usefulness for intensity calibration of optical systems in the vacuum ultraviolet (1000A Lambda 3000A). The theory of molecular band intensities is outlined and the technique of measuring the spectral response curve is described. Several methods for establishing an absolute intensity calibration are discussed.