Absorbing State Phase Transition with Competing Quantum and Classical Fluctuations
NASA Astrophysics Data System (ADS)
Marcuzzi, Matteo; Buchhold, Michael; Diehl, Sebastian; Lesanovsky, Igor
2016-06-01
Stochastic processes with absorbing states feature examples of nonequilibrium universal phenomena. While the classical regime has been thoroughly investigated in the past, relatively little is known about the behavior of these nonequilibrium systems in the presence of quantum fluctuations. Here, we theoretically address such a scenario in an open quantum spin model which, in its classical limit, undergoes a directed percolation phase transition. By mapping the problem to a nonequilibrium field theory, we show that the introduction of quantum fluctuations stemming from coherent, rather than statistical, spin flips alters the nature of the transition such that it becomes first order. In the intermediate regime, where classical and quantum dynamics compete on equal terms, we highlight the presence of a bicritical point with universal features different from the directed percolation class in a low dimension. We finally propose how this physics could be explored within gases of interacting atoms excited to Rydberg states.
Absorbing State Phase Transition with Competing Quantum and Classical Fluctuations.
Marcuzzi, Matteo; Buchhold, Michael; Diehl, Sebastian; Lesanovsky, Igor
2016-06-17
Stochastic processes with absorbing states feature examples of nonequilibrium universal phenomena. While the classical regime has been thoroughly investigated in the past, relatively little is known about the behavior of these nonequilibrium systems in the presence of quantum fluctuations. Here, we theoretically address such a scenario in an open quantum spin model which, in its classical limit, undergoes a directed percolation phase transition. By mapping the problem to a nonequilibrium field theory, we show that the introduction of quantum fluctuations stemming from coherent, rather than statistical, spin flips alters the nature of the transition such that it becomes first order. In the intermediate regime, where classical and quantum dynamics compete on equal terms, we highlight the presence of a bicritical point with universal features different from the directed percolation class in a low dimension. We finally propose how this physics could be explored within gases of interacting atoms excited to Rydberg states. PMID:27367395
Background field functional renormalization group for absorbing state phase transitions.
Buchhold, Michael; Diehl, Sebastian
2016-07-01
We present a functional renormalization group approach for the active to inactive phase transition in directed percolation-type systems, in which the transition is approached from the active, finite density phase. By expanding the effective potential for the density field around its minimum, we obtain a background field action functional, which serves as a starting point for the functional renormalization group approach. Due to the presence of the background field, the corresponding nonperturbative flow equations yield remarkably good estimates for the critical exponents of the directed percolation universality class, even in low dimensions. PMID:27575107
Background field functional renormalization group for absorbing state phase transitions
NASA Astrophysics Data System (ADS)
Buchhold, Michael; Diehl, Sebastian
2016-07-01
We present a functional renormalization group approach for the active to inactive phase transition in directed percolation-type systems, in which the transition is approached from the active, finite density phase. By expanding the effective potential for the density field around its minimum, we obtain a background field action functional, which serves as a starting point for the functional renormalization group approach. Due to the presence of the background field, the corresponding nonperturbative flow equations yield remarkably good estimates for the critical exponents of the directed percolation universality class, even in low dimensions.
Hybrid phase transition into an absorbing state: Percolation and avalanches
NASA Astrophysics Data System (ADS)
Lee, Deokjae; Choi, S.; Stippinger, M.; Kertész, J.; Kahng, B.
2016-04-01
Interdependent networks are more fragile under random attacks than simplex networks, because interlayer dependencies lead to cascading failures and finally to a sudden collapse. This is a hybrid phase transition (HPT), meaning that at the transition point the order parameter has a jump but there are also critical phenomena related to it. Here we study these phenomena on the Erdős-Rényi and the two-dimensional interdependent networks and show that the hybrid percolation transition exhibits two kinds of critical behaviors: divergence of the fluctuations of the order parameter and power-law size distribution of finite avalanches at a transition point. At the transition point global or "infinite" avalanches occur, while the finite ones have a power law size distribution; thus the avalanche statistics also has the nature of a HPT. The exponent βm of the order parameter is 1 /2 under general conditions, while the value of the exponent γm characterizing the fluctuations of the order parameter depends on the system. The critical behavior of the finite avalanches can be described by another set of exponents, βa and γa. These two critical behaviors are coupled by a scaling law: 1 -βm=γa .
Hybrid phase transition into an absorbing state: Percolation and avalanches.
Lee, Deokjae; Choi, S; Stippinger, M; Kertész, J; Kahng, B
2016-04-01
Interdependent networks are more fragile under random attacks than simplex networks, because interlayer dependencies lead to cascading failures and finally to a sudden collapse. This is a hybrid phase transition (HPT), meaning that at the transition point the order parameter has a jump but there are also critical phenomena related to it. Here we study these phenomena on the Erdős-Rényi and the two-dimensional interdependent networks and show that the hybrid percolation transition exhibits two kinds of critical behaviors: divergence of the fluctuations of the order parameter and power-law size distribution of finite avalanches at a transition point. At the transition point global or "infinite" avalanches occur, while the finite ones have a power law size distribution; thus the avalanche statistics also has the nature of a HPT. The exponent β_{m} of the order parameter is 1/2 under general conditions, while the value of the exponent γ_{m} characterizing the fluctuations of the order parameter depends on the system. The critical behavior of the finite avalanches can be described by another set of exponents, β_{a} and γ_{a}. These two critical behaviors are coupled by a scaling law: 1-β_{m}=γ_{a}.
Hybrid phase transition into an absorbing state: Percolation and avalanches.
Lee, Deokjae; Choi, S; Stippinger, M; Kertész, J; Kahng, B
2016-04-01
Interdependent networks are more fragile under random attacks than simplex networks, because interlayer dependencies lead to cascading failures and finally to a sudden collapse. This is a hybrid phase transition (HPT), meaning that at the transition point the order parameter has a jump but there are also critical phenomena related to it. Here we study these phenomena on the Erdős-Rényi and the two-dimensional interdependent networks and show that the hybrid percolation transition exhibits two kinds of critical behaviors: divergence of the fluctuations of the order parameter and power-law size distribution of finite avalanches at a transition point. At the transition point global or "infinite" avalanches occur, while the finite ones have a power law size distribution; thus the avalanche statistics also has the nature of a HPT. The exponent β_{m} of the order parameter is 1/2 under general conditions, while the value of the exponent γ_{m} characterizing the fluctuations of the order parameter depends on the system. The critical behavior of the finite avalanches can be described by another set of exponents, β_{a} and γ_{a}. These two critical behaviors are coupled by a scaling law: 1-β_{m}=γ_{a}. PMID:27176256
de Oliveira, M M; da Luz, M G E; Fiore, C E
2015-12-01
Based on quasistationary distribution ideas, a general finite size scaling theory is proposed for discontinuous nonequilibrium phase transitions into absorbing states. Analogously to the equilibrium case, we show that quantities such as response functions, cumulants, and equal area probability distributions all scale with the volume, thus allowing proper estimates for the thermodynamic limit. To illustrate these results, five very distinct lattice models displaying nonequilibrium transitions-to single and infinitely many absorbing states-are investigated. The innate difficulties in analyzing absorbing phase transitions are circumvented through quasistationary simulation methods. Our findings (allied to numerical studies in the literature) strongly point to a unifying discontinuous phase transition scaling behavior for equilibrium and this important class of nonequilibrium systems. PMID:26764651
Absorbing phase transition in a four-state predator-prey model in one dimension
NASA Astrophysics Data System (ADS)
Chatterjee, Rakesh; Mohanty, P. K.; Basu, Abhik
2011-05-01
The model of competition between densities of two different species, called predator and prey, is studied on a one-dimensional periodic lattice, where each site can be in one of the four states, say, empty, or occupied by a single predator, or occupied by a single prey, or by both. Along with the pairwise death of predators and growth of prey, we introduce an interaction where the predators can eat one of the neighboring prey and reproduce a new predator there instantly. The model shows a non-equilibrium phase transition into an unusual absorbing state where predators are absent and the lattice is fully occupied by prey. The critical exponents of the system are found to be different from those of the directed percolation universality class and they are robust against addition of explicit diffusion.
Active-to-absorbing-state phase transition in an evolving population with mutation
NASA Astrophysics Data System (ADS)
Sarkar, Niladri
2015-10-01
We study the active to absorbing phase transition (AAPT) in a simple two-component model system for a species and its mutant. We uncover the nontrivial critical scaling behavior and weak dynamic scaling near the AAPT that shows the significance of mutation and highlights the connection of this model with the well-known directed percolation universality class. Our model should be a useful starting point to study how mutation may affect extinction or survival of a species.
Diffusion, Absorbing States, and Nonequilibrium Phase Transitions in Range Expansions and Evolution
NASA Astrophysics Data System (ADS)
Lavrentovich, Maxim Olegovich
The spatial organization of a population plays a key role in its evolutionary dynamics and growth. In this thesis, we study the dynamics of range expansions, in which populations expand into new territory. Focussing on microbes, we first consider how nutrients diffuse and are absorbed in a population, allowing it to grow. These nutrients may be absorbed before reaching the population interior, and this "nutrient shielding'' can confine the growth to a thin region on the population periphery. A thin population front implies a small local effective population size and enhanced number fluctuations (or genetic drift). We then study evolutionary dynamics under these growth conditions. In particular, we calculate the survival probability of mutations with a selective advantage occurring at the population front for two-dimensional expansions (e.g., along the surface of an agar plate), and three-dimensional expansions (e.g., an avascular tumor). We also consider the effects of irreversible, deleterious mutations which can lead to the loss of the advantageous mutation in the population via a "mutational meltdown,'' or non-equilibrium phase transition. We examine the effects of an inflating population frontier on the phase transition. Finally, we discuss how spatial dimension and frontier roughness influence range expansions of mutualistic, cross-feeding variants. We find here universal features of the phase diagram describing the onset of a mutualistic phase in which the variants remain mixed at long times.
NASA Astrophysics Data System (ADS)
Fiore, Carlos E.
2014-02-01
Motivated by recent findings, we discuss the existence of a direct and robust mechanism providing discontinuous absorbing transitions in short-range systems with single species, with no extra symmetries or conservation laws. We consider variants of the contact process, in which at least two adjacent particles (instead of one, as commonly assumed) are required to create a new species. Many interaction rules are analyzed, including distinct cluster annihilations and a modified version of the original pair contact process. Through detailed time-dependent numerical simulations, we find that for our modified models, the phase transitions are of first order, hence contrasting with their corresponding usual formulations in the literature, which are of second order. By calculating the order-parameter distributions, the obtained bimodal shapes as well as the finite-scale analysis reinforce coexisting phases and thus a discontinuous transition. These findings strongly suggest that the above particle creation requirements constitute a minimum and fundamental mechanism determining the phase coexistence in short-range contact processes.
Absorber topography dependence of phase edge effects
NASA Astrophysics Data System (ADS)
Shanker, Aamod; Sczyrba, Martin; Connolly, Brid; Waller, Laura; Neureuther, Andy
2015-10-01
Mask topography contributes to phase at the wafer plane, even for OMOG binary masks currently in use at the 22nm node in deep UV (193nm) lithography. Here, numerical experiments with rigorous FDTD simulation are used to study the impact of mask 3D effects on aerial imaging, by varying the height of the absorber stack and its sidewall angle. Using a thin mask boundary layer model to fit to rigorous simulations it is seen that increasing the absorber thickness, and hence the phase through the middle of a feature (bulk phase) monotonically changes the wafer-plane phase. Absorber height also influences best focus, revealed by an up/down shift in the Bossung plot (linewidth vs. defocus). Bossung plot tilt, however, responsible for process window variability at the wafer, is insensitive to changes in the absorber height (and hence also the bulk phase). It is seen to depend instead on EM edge diffraction from the thick mask edge (edge phase), but stays constant for variations in mask thickness within a 10% range. Both bulk phase and edge phase are also independent of sidewall angle fluctuation, which is seen to linearly affect the CD at the wafer, but does not alter wafer phase or the defocus process window. Notably, as mask topography varies, the effect of edge phase can be replicated by a thin mask model with 8nm wide boundary layers, irrespective of absorber height or sidewall angle. The conclusions are validated with measurements on phase shifting masks having different topographic parameters, confirming the strong dependence of phase variations at the wafer on bulk phase of the mask absorber.
Single-phase Stefan problem in selectively absorbing medium
NASA Astrophysics Data System (ADS)
Sleptsov, S. D.; Rubtsov, N. A.; Savvinova, N. A.
2016-01-01
The thermal state of a translucent selectively absorbing medium was studied by the methods of numerical simulation at different values of the optical properties of boundaries and heat transfer from the left surface in approximation of one-phase Stefan problem. The temperature fields and densities of resultant radiation fluxes as well as the thermal state of the left boundary and dynamics of layer reduction in the melting process were analyzed. The processes of phase transition in a flat layer of selective and gray absorbing media and emitting media were compared, and their fundamental differences were shown.
Cusps, self-organization, and absorbing states.
Bonachela, Juan A; Alava, Mikko; Muñoz, Miguel A
2009-05-01
Elastic interfaces embedded in (quenched) random media exhibit metastability and stick-slip dynamics. These nontrivial dynamical features have been shown to be associated with cusp singularities of the coarse-grained disorder correlator. Here we show that annealed systems with many absorbing states and a conservation law but no quenched disorder exhibit identical cusps. On the other hand, similar nonconserved systems in the directed percolation class are also shown to exhibit cusps but of a different type. These results are obtained both by a recent method to explicitly measure disorder correlators and by defining an alternative new protocol inspired by self-organized criticality, which opens the door to easily accessible experimental realizations.
Calculation of dehydration absorbers based on improved phase equilibrium data
Oi, L.E.
1999-07-01
Dehydration using triethylene glycol (TEG) as an absorbent, is a standard process for natural gas treating. New and more accurate TEG/water equilibrium data have been measured between 1980 and 1990. However, this has not influenced much on the design methods of dehydration absorbers. Inaccurate equilibrium data have been extensively used in design calculations. When using data from a common source like Worley, an overall bubble cap tray efficiency between 25--40% has normally been recommended. This has resulted in a quite satisfactory and consistent design method. It is obvious that newer equilibrium data (Herskowitz, Parrish, Bestani) are more accurate. However, to achieve an improved design method, column efficiencies consistent with the new equilibrium data must be recommended. New equilibrium data have been correlated to an activity coefficient model for the liquid phase and combined with an equation of state for the gas phase. Performance data from the North Sea offshore platform Gullfaks C (drying 4--5 MMscmd) have been measured. The bubble cap column has been simulated, and the tray efficiency has been adjusted to fit the performance data. Tray efficiencies calculated with new equilibrium data are higher than 50%. Calculated tray efficiency values are dependent on the equilibrium data used. There are still uncertainties in equilibrium data for the TEC/water/natural gas system. When using accurate equilibrium data, an overall bubble cap tray efficiency of 40--50% and a Murphree efficiency of 55--70% can be expected at normal absorption conditions.
Direct quantitative tomographic reconstruction for weakly absorbing homogeneous phase objects
NASA Astrophysics Data System (ADS)
Arhatari, B. D.; De Carlo, F.; Peele, A. G.
2007-05-01
We examine a direct filtered back projection approach that is suitable for the reconstruction of weakly absorbing homogeneous phase objects. Like recent similar approaches this method needs only one intensity image in each projection without the requirement for an intermediate step of phase retrieval. We tested the method using simulation and experimental results. Simulation results show good quantitative reconstruction which includes the correct refractive index value and distribution of the sample. However, experimental result still indicates the presence of artifacts.
System size expansion for systems with an absorbing state.
Di Patti, Francesca; Azaele, Sandro; Banavar, Jayanth R; Maritan, Amos
2011-01-01
The well-known van Kampen system size expansion, while of rather general applicability, is shown to fail to reproduce some qualitative features of the time evolution for systems with an absorbing state, apart from a transient initial time interval. We generalize the van Kampen ansatz by introducing a new prescription leading to non-Gaussian fluctuations around the absorbing state. The two expansion predictions are explicitly compared for the infinite range voter model with speciation as a paradigmatic model with an absorbing state. The new expansion, both for a finite size system in the large time limit and at finite time in the large size limit, converges to the exact solution as obtained in a numerical implementation using the Gillespie algorithm. Furthermore, the predicted lifetime distribution is shown to have the correct asymptotic behavior. PMID:21405654
System size expansion for systems with an absorbing state.
Di Patti, Francesca; Azaele, Sandro; Banavar, Jayanth R; Maritan, Amos
2011-01-01
The well-known van Kampen system size expansion, while of rather general applicability, is shown to fail to reproduce some qualitative features of the time evolution for systems with an absorbing state, apart from a transient initial time interval. We generalize the van Kampen ansatz by introducing a new prescription leading to non-Gaussian fluctuations around the absorbing state. The two expansion predictions are explicitly compared for the infinite range voter model with speciation as a paradigmatic model with an absorbing state. The new expansion, both for a finite size system in the large time limit and at finite time in the large size limit, converges to the exact solution as obtained in a numerical implementation using the Gillespie algorithm. Furthermore, the predicted lifetime distribution is shown to have the correct asymptotic behavior.
Directed Percolation and Other Systems with Absorbing States
NASA Astrophysics Data System (ADS)
Fröjdh, Per; Howard, Martin; Lauritsen, Kent Bækgaard
We review the critical behavior of nonequilibrium systems, such as directed percolation (DP) and branching-annihilating random walks (BARW), which possess phase transitions into absorbing states. After reviewing the bulk scaling behavior of these models, we devote the main part of this review to analyzing the impact of walls on their critical behavior. We discuss the possible boundary universality classes for the DP and BARW models, which can be described by a general scaling theory which allows for two independent surface exponents in addition to the bulk critical exponents. Above the upper critical dimension dc, we review the use of mean field theories, whereas in the regime d
Noise-induced absorbing phase transition in a model of opinion formation
NASA Astrophysics Data System (ADS)
Vieira, Allan R.; Crokidakis, Nuno
2016-08-01
In this work we study a 3-state (+1, -1, 0) opinion model in the presence of noise and disorder. We consider pairwise competitive interactions, with a fraction p of those interactions being negative (disorder). Moreover, there is a noise q that represents the probability of an individual spontaneously change his opinion to the neutral state. Our aim is to study how the increase/decrease of the fraction of neutral agents affects the critical behavior of the system and the evolution of opinions. We derive analytical expressions for the order parameter of the model, as well as for the stationary fraction of each opinion, and we show that there are distinct phase transitions. One is the usual ferro-paramagnetic transition, that is in the Ising universality class. In addition, there are para-absorbing and ferro-absorbing transitions, presenting the directed percolation universality class. Our results are complemented by numerical simulations.
Hysteresis of transient populations in absorbing-state systems
NASA Astrophysics Data System (ADS)
Kapitanchuk, Oleksiy L.; Marchenko, Oleksij M.; Teslenko, Victor I.
2016-06-01
A nonequilibrium density matrix theory is used in order to explicitly describe the hysteresis interrelation between populations of nonstationary states in an absorbing multi-stage chain system in the one-particle approximation. As an illustrative example, we restrict ourselves to consideration of the 3-stage absorbing case for which we identify three types of the hysteresis; that is, the causal time dependent hysteresis with leaf-like and triangle-like closed loops, the hidden hysteresis with broken-line loops and the true hysteresis with open loops. Furthermore, we observe a common critical threshold for the hysteresis types and ascertain a reciprocal correspondence of this threshold as between the types as well with the experiment.
NASA Astrophysics Data System (ADS)
Cruz, Claudia P. T.; Lyra, M. L.; Fulco, U. L.; Corso, Gilberto
2012-11-01
We introduce a model for the Contact Process with relaxing immunization CPRI. In this model, local memory is introduced by a time and space dependence of the contamination probability. The model has two parameters: a typical immunization time τ and a maximum contamination probability a. The system presents an absorbing state phase transition whenever the contamination probability a is above a minimum threshold. For short immunization times, the system evolves to a statistically stationary active state. Above τc(a), immunization predominates and the system evolves to the absorbing vacuum state. We employ a finite-size scaling analysis to show that the transition belongs to the standard directed percolation universality class. The critical immunization time diverges in the limit of a→1. In this regime, the density of active sites decays exponentially as τ increases, but never reaches the vacuum state in the thermodynamic limit.
Electrodynamics analysis on coherent perfect absorber and phase-controlled optical switch.
Chen, Tianjie; Duan, Shaoguang; Chen, Y C
2012-05-01
A coherent perfect absorber is essentially a specially designed Fabry-Perot interferometer, which completely extinguishes the incident coherent light. The one- and two-beam coherent perfect absorbers have been analyzed using classical electrodynamics by considering index matching in layered structures to totally suppress reflections. This approach presents a clear and physically intuitive picture for the principle of operation of a perfect absorber. The results show that the incident beam(s) must have correct phases and amplitudes, and the real and imaginary parts of the refractive indices of the media in the interferometer must satisfy a well-defined relation. Our results are in agreement with those obtained using the S-matrix analysis. However, the results were obtained solely based on the superposition of waves from multiple reflections without invoking the concept of time reversal as does the S-matrix approach. Further analysis shows that the two-beam device can be configured to function as a phase-controlled three-state switch.
CO2 Capture with Liquid-to-Solid Absorbents: CO2 Capture Process Using Phase-Changing Absorbents
2010-10-01
IMPACCT Project: GE and the University of Pittsburgh are developing a unique CO2 capture process in which a liquid absorbent, upon contact with CO2, changes into a solid phase. Once in solid form, the material can be separated and the CO2 can be released for storage by heating. Upon heating, the absorbent returns to its liquid form, where it can be reused to capture more CO2. The approach is more efficient than other solventbased processes because it avoids the heating of extraneous solvents such as water. This ultimately leads to a lower cost of CO2 capture and will lower the additional cost to produce electricity for coal-fired power plants that retrofit their facilities to include this technology.
Cao, Tun; Wei, Chen-wei; Simpson, Robert E.; Zhang, Lei; Cryan, Martin J.
2014-01-01
We report a broadband polarization-independent perfect absorber with wide-angle near unity absorbance in the visible regime. Our structure is composed of an array of thin Au squares separated from a continuous Au film by a phase change material (Ge2Sb2Te5) layer. It shows that the near perfect absorbance is flat and broad over a wide-angle incidence up to 80° for either transverse electric or magnetic polarization due to a high imaginary part of the dielectric permittivity of Ge2Sb2Te5. The electric field, magnetic field and current distributions in the absorber are investigated to explain the physical origin of the absorbance. Moreover, we carried out numerical simulations to investigate the temporal variation of temperature in the Ge2Sb2Te5 layer and to show that the temperature of amorphous Ge2Sb2Te5 can be raised from room temperature to > 433 K (amorphous-to-crystalline phase transition temperature) in just 0.37 ns with a low light intensity of 95 nW/μm2, owing to the enhanced broadband light absorbance through strong plasmonic resonances in the absorber. The proposed phase-change metamaterial provides a simple way to realize a broadband perfect absorber in the visible and near-infrared (NIR) regions and is important for a number of applications including thermally controlled photonic devices, solar energy conversion and optical data storage. PMID:24492415
THE TWO-PHASE, TWO-VELOCITY IONIZED ABSORBER IN THE SEYFERT 1 GALAXY NGC 5548
Andrade-Velazquez, Mercedes; Krongold, Yair; Binette, Luc; Jimenez-Bailon, Elena; Elvis, Martin; Nicastro, Fabrizio; Brickhouse, Nancy; Mathur, Smita
2010-03-10
We present an analysis of X-ray high-quality grating spectra of the Seyfert 1 galaxy NGC 5548 using archival Chandra-High Energy Transmission Grating Spectrometer and Low Energy Transmission Grating Spectrometer observations for a total exposure time of 800 ks. The continuum emission (between 0.2 keV and 8 keV) is well represented by a power law (GAMMA = 1.6) plus a blackbody component (kT = 0.1 keV). We find that the well-known X-ray warm absorber (WA) in this source consists of two different outflow velocity systems. One absorbing system has a velocity of -1110 +- 150 km s{sup -1} and the other of -490 +- 150 km s{sup -1}. Recognizing the presence of these kinematically distinct components allows each system to be fitted independently, each with two absorption components with different ionization levels. The high-velocity system consists of two components, one with a temperature of 2.7 +- 0.6 x 10{sup 6} K, log U = 1.23, and another with a temperature of 5.8 +- 1.0 x 10{sup 5} K, log U = 0.67. The high-velocity, high-ionization component produces absorption by charge states Fe XXI-XXIV, while the high-velocity, low-ionization component produces absorption by Ne IX-X, Fe XVII-XX, and O VII-VIII. The low-velocity system also required two absorbing components, one with a temperature of 5.8 +- 0.8 x 10{sup 5} K, log U = 0.67, producing absorption by Ne IX-X, Fe XVII-XX, and O VII-VIII, and the other with a lower temperature of 3.5 +- 0.35 x 10{sup 4} K and a lower ionization of log U = -0.49, producing absorption by O VI-VII and the Fe VII-XII M-shell Unresolved Transitions Array. Once these components are considered, the data do not require any further absorbers. In particular, a model consisting of a continuous radial range of ionization structures (as suggested by a previous analysis) is not required. The two absorbing components in each velocity system are in pressure equilibrium with each other. This suggests that each velocity system consists of a multi-phase
Phase diagrams of orientational transitions in absorbing nematic liquid crystals
Zolot’ko, A. S. Ochkin, V. N.; Smayev, M. P.; Shvetsov, S. A.
2015-05-15
A theory of orientational transitions in nematic liquid crystals (NLCs), which employs the expansion of optical torques acting on the NLC director with respect to the rotation angle, has been developed for NLCs with additives of conformationally active compounds under the action of optical and low-frequency electric and magnetic fields. Phase diagrams of NLCs are constructed as a function of the intensity and polarization of the light field, the strength of low-frequency electric field, and a parameter that characterizes the feedback between the rotation of the NLC director and optical torque. Conditions for the occurrence of first- and second-order transitions are determined. The proposed theory agrees with available experimental data.
Few-layer black phosphorus based saturable absorber mirror for pulsed solid-state lasers.
Ma, Jie; Lu, Shunbin; Guo, Zhinan; Xu, Xiaodong; Zhang, Han; Tang, Dingyuan; Fan, Dianyuan
2015-08-24
We experimentally demonstrated that few-layer black phosphorus (BP) could be used as an optical modulator for solid-state lasers to generate short laser pulses. The BP flakes were fabricated by the liquid phase exfoliation method and drop-casted on a high-reflection mirror to form a BP-based saturable absorber mirror (BP-SAM). Stable Q-switched pulses with a pulse width of 620 ns at the wavelength of 1046 nm were obtained in a Yb:CaYAlO(4) (Yb:CYA) laser with the BP-SAM. The generated pulse train has a repetition rate of 113.6 kHz and an average output power of 37 mW. Our results show that the BP-SAMs could have excellent prospective for ultrafast photonics applications.
Parasitic oscillation suppression in solid state lasers using absorbing thin films
Zapata, Luis E.
1994-01-01
A thin absorbing film is bonded onto at least certain surfaces of a solid state laser gain medium. An absorbing metal-dielectric multilayer film is optimized for a broad range of incidence angles, and is resistant to the corrosive/erosive effects of a coolant such as water, used in the forced convection cooling of the film. Parasitic oscillations hamper the operation of solid state lasers by causing the decay of stored energy to amplified rays trapped within the gain medium by total and partial internal reflections off the gain medium facets. Zigzag lasers intended for high average power operation require the ASE absorber.
Parasitic oscillation suppression in solid state lasers using absorbing thin films
Zapata, L.E.
1994-08-02
A thin absorbing film is bonded onto at least certain surfaces of a solid state laser gain medium. An absorbing metal-dielectric multilayer film is optimized for a broad range of incidence angles, and is resistant to the corrosive/erosive effects of a coolant such as water, used in the forced convection cooling of the film. Parasitic oscillations hamper the operation of solid state lasers by causing the decay of stored energy to amplified rays trapped within the gain medium by total and partial internal reflections off the gain medium facets. Zigzag lasers intended for high average power operation require the ASE absorber. 16 figs.
On the relation between phase path, group path and attenuation in a cold absorbing plasma
NASA Technical Reports Server (NTRS)
Bennett, J. A.; Dyson, P. L.
1978-01-01
Consideration is given to a cold absorbing plasma in which the collision frequency is zero. Expressions are developed which relate the attenuation and the group and phase refractive indices. It is found that because the expressions for the group and phase refractive indices and the imaginary part of the refractive index are closely related in form, the attenuation is related to the difference between the group and phase paths. Numerical calculations have derived approximations which significantly increase the range of known approximations of this type.
Experimental demonstration of a coherent perfect absorber with PT phase transition.
Sun, Yong; Tan, Wei; Li, Hong-qiang; Li, Jensen; Chen, Hong
2014-04-11
We report the realization of a coherent perfect absorber, using a pair of passive resonators coupled to a microwave transmission line in the background, which can completely absorb light in its parity-time (PT-)symmetric phase but not in its broken phase. Instead of balancing material gain and loss, we exploit the incident waves in the open system as an effective gain so that ideal PT symmetry can be established by using only passive materials. Such a route will be effective to construct PT-symmetric metamaterials and also tunable PT-symmetric optical elements in general. It also provides a flexible platform for studying exceptional-point physics with both electric and magnetic responses.
Phase-contrast imaging of weakly absorbing materials using hard X-rays
NASA Astrophysics Data System (ADS)
Davis, T. J.; Gao, D.; Gureyev, T. E.; Stevenson, A. W.; Wilkins, S. W.
1995-02-01
IMAGING with hard X-rays is an important diagnostic tool in medicine, biology and materials science. Contact radiography and tomography using hard X-rays provide information on internal structures that cannot be obtained using other non-destructive methods. The image contrast results from variations in the X-ray absorption arising from density differences and variations in composition and thickness of the object. But although X-rays penetrate deeply into carbon-based compounds, such as soft biological tissue, polymers and carbon-fibre composites, there is little absorption and therefore poor image contrast. Here we describe a method for enhancing the contrast in hard X-ray images of weakly absorbing materials by resolving phase variations across the X-ray beam1-4. The phase gradients are detected using diffraction from perfect silicon crystals. The diffraction properties of the crystal determine the ultimate spatial resolution in the image; we can readily obtain a resolution of a fraction of a millimetre. Our method shows dramatic contrast enhancement for weakly absorbing biological and inorganic materials, compared with conventional radiography using the same X-ray energy. We present both bright-field and dark-field phase-contrast images, and show evidence of contrast reversal. The method should have the clinical advantage of good contrast for low absorbed X-ray dose.
Kocer, Hasan; Butun, Serkan; Palacios, Edgar; Liu, Zizhuo; Tongay, Sefaattin; Fu, Deyi; Wang, Kevin; Wu, Junqiao; Aydin, Koray
2015-01-01
Plasmonic and metamaterial based nano/micro-structured materials enable spectrally selective resonant absorption, where the resonant bandwidth and absorption intensity can be engineered by controlling the size and geometry of nanostructures. Here, we demonstrate a simple, lithography-free approach for obtaining a resonant and dynamically tunable broadband absorber based on vanadium dioxide (VO2) phase transition. Using planar layered thin film structures, where top layer is chosen to be an ultrathin (20 nm) VO2 film, we demonstrate broadband IR light absorption tuning (from ~90% to ~30% in measured absorption) over the entire mid-wavelength infrared spectrum. Our numerical and experimental results indicate that the bandwidth of the absorption bands can be controlled by changing the dielectric spacer layer thickness. Broadband tunable absorbers can find applications in absorption filters, thermal emitters, thermophotovoltaics and sensing. PMID:26294085
Photoexcited triplet states of new UV absorbers, cinnamic acid 2-methylphenyl esters.
Kikuchi, Azusa; Saito, Haruo; Mori, Masao; Yagi, Mikio
2011-12-01
Phosphorescence spectra of nonphosphorescent or very weakly phosphorescent new UV absorbers, 2-methylphenyl cinnamate (MePC), 2-methylphenyl 4-methoxycinnamate (MePMC) and 2-methylphenyl 4-ethoxycinnamate (MePEC) have been observed by using external heavy atom effects of ethyl iodide in ethanol at 77 K. The lowest excited triplet (T(1)) energies of these new UV absorbers are lower than those of a widely used UV-A absorber, 4-tert-butyl-4'-methoxydibenzoylmethane (BM-DBM), in both keto and enol forms. The intermolecular triplet-triplet energy transfer from photolabile BM-DBM to MePMC was observed by measuring the time-resolved phosphorescence spectra. Electron paramagnetic resonance spectra have been observed for the T(1) states of these new UV absorbers in ethanol at 77 K by using benzophenone as a triplet sensitizer. The observed T(1) lifetimes, zero-field splitting (ZFS) parameters and molecular orbital calculations of the ZFS parameters suggest that T(1) states of these new UV absorbers posses mainly (3)ππ* character. The deactivation processes of the lowest excited singlet (S(1)) states are predominantly fluorescence and internal conversion to the ground (G) states in MePMC and MePEC, while the main deactivation process of the S(1) state of MePC is internal conversion to the G state. The molar absorption coefficients of MePMC and MePEC in the UV-A and UV-B regions are larger than that of most widely used UV-B absorber, octyl methoxycinnamate. PMID:22002255
Nanostructured thin film-based near-infrared tunable perfect absorber using phase-change material
NASA Astrophysics Data System (ADS)
Kocer, Hasan
2015-01-01
Nanostructured thin film absorbers embedded with phase-change thermochromic material can provide a large level of absorption tunability in the near-infrared region. Vanadium dioxide was employed as the phase-change material in the designed structures. The optical absorption properties of the designed structures with respect to the geometric and material parameters were systematically investigated using finite-difference time-domain computations. Absorption level of the resonance wavelength in the near-IR region was tuned from the perfect absorption level to a low level (17%) with a high positive dynamic range of near-infrared absorption intensity tunability (83%). Due to the phase transition of vanadium dioxide, the resonance at the near-infrared region is being turned on and turned off actively and reversibly under the thermal bias, thereby rendering these nanostructures suitable for infrared camouflage, emitters, and sensors.
Effect of diffusion in one-dimensional discontinuous absorbing phase transitions.
Fiore, Carlos E; Landi, Gabriel T
2014-09-01
It is known that diffusion provokes substantial changes in continuous absorbing phase transitions. Conversely, its effect on discontinuous transitions is much less understood. In order to shed light in this direction, we study the inclusion of diffusion in the simplest one-dimensional model with a discontinuous absorbing phase transition, namely, the long-range contact process (σ-CP). Particles interact as in the usual CP, but the transition rate depends on the length ℓ of inactive sites according to 1+aℓ(-σ), where a and σ are control parameters. The inclusion of diffusion in this model has been investigated by numerical simulations and mean-field calculations. Results show that there exists three distinct regimes. For sufficiently low and large σ's the transition is, respectively, always discontinuous or continuous, independently of the strength of the diffusion. On the other hand, in an intermediate range of σ's, the diffusion causes a suppression of the phase coexistence leading to a continuous transition belonging to the directed percolation universality class.
Influence of competition in minimal systems with discontinuous absorbing phase transitions
NASA Astrophysics Data System (ADS)
Pianegonda, Salete; Fiore, Carlos E.
2016-06-01
Contact processes (CP's) with particle creation requiring a minimal neighborhood (restrictive or threshold CP's) present a novel sort of discontinuous absorbing transitions, that revealed itself robust under the inclusion of different ingredients, such as distinct lattice topologies, particle annihilations and diffusion. Here, we tackle on the influence of competition between restrictive and standard dynamics (that describes the usual CP and a continuous DP transition is presented). Systems have been studied via mean-field theory (MFT) and numerical simulations. Results show partial contrast between MFT and numerical results. While the former predicts that considerable competition rates are required to shift the phase transition, the latter reveals the change occurs for rather limited (small) fractions. Thus, unlike previous ingredients (such as diffusion and others), limited competitive rates suppress the phase coexistence.
NASA Astrophysics Data System (ADS)
Finders, Jo; Winter, Laurens de; Last, Thorsten
2016-04-01
We will summarize our work on mask topography-induced effects over the last 5 years. We will give a full physical explanation of the effects that can be observed from exposed wafers in state-of-the-art immersion and extreme ultraviolet photolithography. The mask topography-induced phase leads to vertical and lateral displacements of the aerial image, resulting in feature-dependent best focus and position. The feature dependency has been studied for gratings through pitch and size and for two-trench arrangements. The physical explanation involves the analysis and quantification of phase effects in a similar way as was done for projection lens aberrations one decade ago. Phase effects, derived both from rigorous simulations and an analytical model, will be compared with exposure figure or merits (e.g., best focus per feature) and correlate well. Therefore, the analysis of mask topography induced phase and the reduction thereof by absorber thickness optimization can be used to drive lithography improvements.
Zolotovskii, I O; Korobko, D A; Okhotnikov, O G; Gumenyuk, R V
2015-01-31
A numerical model of a soliton fibre laser with a semiconductor saturable absorber mirror (SESAM), characterised by the complex dynamics of absorption relaxation, is considered. It is shown that stationary bound states of pulses can be formed in this laser as a result of their interaction via the dispersion-wave field. The stability of stationary bound states of several pulses is analysed. It is shown that an increase in the number of pulses in a stationary bound state leads eventually to its decay and formation of a random bunch. It is found that the bunch stability is caused by the manifestation of nonlinear self-phase modulation, which attracts pulses to the bunch centre. The simulation results are in qualitative agreement with experimental data. (nonlinear optical phenomena)
Wang, Hao; Yang, Yue; Wang, Liping
2014-08-18
We numerically demonstrate a switchable metamaterial absorber/emitter by thermally turning on or off the excitation of magnetic resonance upon the phase transition of vanadium dioxide (VO{sub 2}). Perfect absorption peak exists around the wavelength of 5 μm when the excitation of magnetic resonance is supported with the insulating VO{sub 2} spacer layer. The wavelength-selective absorption is switched off when the magnetic resonance is disabled with metallic VO{sub 2} that shorts the top and bottom metallic structures. The resonance wavelength can be tuned with different geometry, and the switchable metamaterial exhibits diffuse behaviors at oblique angles. The results would facilitate the design of switchable metamaterials for active control in energy and sensing applications.
A partial eclipse of the heart: the absorbed X-ray low state in Mrk 1048
NASA Astrophysics Data System (ADS)
Parker, M. L.; Schartel, N.; Komossa, S.; Grupe, D.; Santos-Lleó, M.; Fabian, A. C.; Mathur, S.
2014-11-01
We present two new XMM-Newton observations of an unprecedented low-flux state in the Seyfert 1 Mrk 1048 (NGC 985), taken in 2013. The X-ray flux below 1 keV drops by a factor of 4-5, whereas the spectrum above 5 keV is essentially unchanged. This points towards an absorption origin for the low state, and we confirm this with spectral fitting, finding that the spectral differences can be well modelled by the addition of a partial covering neutral absorber, with a column density of ˜3 × 1022 cm-2 and a covering fraction of ˜0.6. The optical and UV fluxes are not affected, and indeed are marginally brighter in the more recent observations, suggesting that only the inner regions of the disc are affected by the absorption event. This indicates either that the absorption is due to a cloud passing over the inner disc, obscuring the X-ray source but leaving the outer disc untouched, or that the absorber is dust-free so the UV continuum is unaffected. We use arguments based on the duration of the event and the physical properties of the absorber to constrain its size and location, and conclude that it is most likely a small cloud at ˜1018 cm from the source.
Nonadditive Mixed State Phases in Neutron Optics
Klepp, J.; Sponar, S.; Filipp, S.; Lettner, M.; Badurek, G.; Hasegawa, Y.
2009-03-10
In a neutron polarimetry experiment mixed neutron spin phases are determined. We consider evolutions leading to purely geometric, purely dynamical and combined phases. It is experimentally demonstrated that the sum of the geometric and dynamical phases--both obtained in separate measurements--is not equal to the associated total phase as obtained from a third measurement, unless the system is in a pure state. In this sense, mixed state phases are not additive.
Femtosecond solid-state laser based on a few-layered black phosphorus saturable absorber.
Su, Xiancui; Wang, Yiran; Zhang, Baitao; Zhao, Ruwei; Yang, Kejian; He, Jingliang; Hu, Qiangqiang; Jia, Zhitai; Tao, Xutang
2016-05-01
In this Letter, a high-quality, few-layered black phosphorus (BP) saturable absorber (SA) was fabricated successfully, and a femtosecond solid-state laser modulated by BP-SA was experimentally demonstrated for the first time, to the best of our knowledge. Pulses as short as 272 fs were achieved with an average output power of 0.82 W, corresponding to the pulse energy of 6.48 nJ and peak power of 23.8 MW. So far, these represent the shortest pulse duration and highest output power ever obtained with a BP-based mode-locked solid-state laser. The results indicate the promising potential of few-layered BP-SA for applications in solid-state femtosecond mode-locked lasers. PMID:27128045
Photoexcited singlet and triplet states of a UV absorber ethylhexyl methoxycrylene.
Kikuchi, Azusa; Hata, Yuki; Kumasaka, Ryo; Nanbu, Yuichi; Yagi, Mikio
2013-01-01
The excited states of UV absorber, ethylhexyl methoxycrylene (EHMCR) have been studied through measurements of UV absorption, fluorescence, phosphorescence and electron paramagnetic resonance (EPR) spectra in ethanol. The energy levels of the lowest excited singlet (S1) and triplet (T1) states of EHMCR were determined. The energy levels of the S1 and T1 states of EHMCR are much lower than those of photolabile 4-tert-butyl-4'-methoxydibenzoylmethane. The energy levels of the S1 and T1 states of EHMCR are lower than those of octyl methoxycinnamate. The weak phosphorescence and EPR B(min) signals were observed and the lifetime was estimated to be 93 ms. These facts suggest that the significant proportion of the S1 molecules undergoes intersystem crossing to the T1 state, and the deactivation process from the T1 state is predominantly radiationless. The photostability of EHMCR arises from the (3)ππ* character in the T1 state. The zero-field splitting (ZFS) parameter in the T1 state is D** = 0.113 cm(-1). PMID:23136952
Tsuchiya, Takumi; Kikuchi, Azusa; Oguchi-Fujiyama, Nozomi; Miyazawa, Kazuyuki; Yagi, Mikio
2015-04-01
The excited states of UV-B absorbers, ethylhexyl triazone (EHT) and diethylhexylbutamido triazone (DBT), have been studied through measurements of UV absorption, fluorescence, phosphorescence, triplet-triplet absorption and electron paramagnetic resonance spectra in ethanol. The energy levels of the lowest excited singlet (S1) and triplet (T1) states and quantum yields of fluorescence and phosphorescence of EHT and DBT were determined. In ethanol at 77 K, the deactivation process of EHT and DBT is predominantly fluorescence, however, a significant portion of the S1 molecules undergoes intersystem crossing to the T1 state. The observed phosphorescence spectra, T1 lifetimes and zero-field splitting parameters suggest that the T1 state of EHT can be assigned to a locally excited (3)ππ* state within p-(N-methylamino)benzoic acid, while the T1 state of DBT can be assigned to a locally excited (3)ππ* state within p-(N-methylamino)benzoic acid or p-amino-N-methylbenzamide. The quantum yields of singlet oxygen generation by EHT and DBT were determined by time-resolved near-IR phosphorescence measurements in ethanol at room temperature. EHT and DBT did not exhibit significantly antioxidative properties by quenching singlet oxygen, in contrast to the study by Lhiaubet-Vallet et al. PMID:25653197
Semiconductor-doped glass saturable absorbers for near-infrared solid-state lasers
NASA Astrophysics Data System (ADS)
Malyarevich, A. M.; Yumashev, K. V.; Lipovskii, A. A.
2008-04-01
A survey of results on use of semiconductor-doped glass saturable absorbers for near-infrared passively mode-locked and Q-switched solid-state lasers is presented. Nanosized semiconductor particles (quantum dots) belong to quantum confined systems where motion of an electron and a hole is defined by the finite size of the nanoparticle. Dependence of the excitonic transition energy on the QDs size provides the possibility to tune the absorption of the glasses embedded with such particles to wavelength of specific light source. IV-VI semiconductor QDs (PbS, PbSe) are of interest for IR application due to their narrow band gap and large exciton Bohr radii. These allow for exciton absorption band at the wavelength through 1-3μm. Nonlinear optical properties of PbS, PbSe, and CuxSe nanoparticles embedded in glass matrices necessary for saturable absorber applications are analyzed. It is shown that these materials can be efficiently used for passive mode locking and Q switching of solid-state lasers based on Nd3+, Yb3+, Cr4+, Tm3+, and Ho3+ ions emitting through 1-2.1μm spectral range.
NASA Astrophysics Data System (ADS)
Yang, Liang; Li, Yanqiu; Liu, Ke
2013-09-01
Hyper numerical aperture (NA) and off-axis illumination enable extension of ArF lithography for 45 nm technology node and beyond. Also, rigorous electromagnetic field modeling is taken into account for the optical and topographical properties of the mask. A rigorous three-dimensional mask model for bilayer absorber alternating phase shift mask (AltPSM) with the rigorous coupled-wave analysis (RCWA) is established. First, the harmonic waves are expanded based on the least common multiple of the periods in order to model the diffraction of multiple grating layers with different periods. Second, Lalanne's formulation is used to improve the convergence of RCWA for multiple grating layers in conical diffraction. Third, the enhanced transmittance matrix approach is also extended to conical diffraction to avoid the numerical instability. Given the chromium oxide/chromium AltPSM, the change of polarization state as a function of mask and incident light properties is investigated. When the linewidth is below 30 nm, the mask acts as a transverse magnetic field polarizer, which is not preferred in terms of image quality, so the mask-induced polarization effects must be considered in the hyper NA lithography.
NASA Astrophysics Data System (ADS)
Xu, S. C.; Man, B. Y.; Jiang, S. Z.; Chen, C. S.; Liu, M.; Yang, C.; Gao, S. B.; Feng, D. J.; Hu, G. D.; Huang, Q. J.; Chen, X. F.; Zhang, C.
2014-08-01
We present a novel method for the direct metal-free growth of graphene on quartz substrate. The direct-grown graphene yields excellent nonlinear saturable absorption properties and is demonstrated to be suitable as a saturable absorber (SA) for an ultrafast solid-state laser. Nearly Fourier-limited 367 fs was obtained at a central wavelength of 1048 nm with a repetition rate of 105.7 MHz. At a pump power of 7.95 W, the average output power was 1.93 W and the highest pulse energy reached 18.3 nJ, with a peak power of 49.8 kW. Our work opens an easy route for making a reliable graphene SA with a mode-locking technique and also displays an exciting prospect in making low-cost and ultrafast lasers.
Exfoliated layers of black phosphorus as saturable absorber for ultrafast solid-state laser.
Zhang, Baitao; Lou, Fei; Zhao, Ruwei; He, Jingliang; Li, Jing; Su, Xiancui; Ning, Jian; Yang, Kejian
2015-08-15
High-quality black phosphorus (BP) saturable absorber mirror (SAM) was successfully fabricated with few-layered BP (phosphorene). By employing the prepared phosphorene SAM, we have demonstrated ultrafast pulse generation from a BP mode-locked bulk laser for the first time to our best knowledge. Pulses as short as 6.1 ps with an average power of 460 mW were obtained at the central wavelength of 1064.1 nm. Considering the direct and flexible band gap for different layers of phosphorene, this work may provide a possible method for fabricating BP SAM to achieve ultrafast solid-state lasers in IR and mid-IR wavelength region.
Solid state saturable absorbers for Q-switching at 1 and 1.3μm: investigation and modeling
NASA Astrophysics Data System (ADS)
Šulc, Jan; Arátor, Pavel; Jelínková, Helena; Nejezchleb, Karel; Škoda, Václav; Kokta, Milan R.
2008-02-01
Yttrium and Lutecium garnets (YAG and LuAG) doped by Chromium or Vanadium ions (Cr 4+ or V 3+) were investigated as saturable absorbers potentially useful for passive Q-switching at wavelengths 1 μm and/or 1.3 μm. For comparison also color center saturable absorber LiF:F - II and Cobalt doped spinel (Co:MALO) were studied. Firstly, low power absorption spectra were recorded for all samples. Next, absorbers transmission in dependence on incident energy/power density was measured using the z-scan method. Crystals Cr:YAG, Cr:LuAG, V:YAG, and LiF:F - II were tested at wavelength 1064 nm. Therefore Alexandrite laser pumped Q-switched Nd:YAG laser was used as a radiation source (pulse length 6.9 ns, energy up to 1.5 mJ). Crystals V:YAG, V:LuAG, and Co:MALO were tested at wavelength 1338 nm. So diode pumped Nd:YAG/V:YAG microchip laser was used as a radiation source (pulse length 6.2 ns, energy up to 0.1 mJ). Using measured data fitting, and by their comparison with numerical model of a "thick" saturable absorber transmission for Q-switched Gaussian laser beam, following parameters were estimated: saturable absorber initial transmission T 0, saturation energy density w s, ground state absorption cross-section σ GSA, saturated absorber transmission T s, excited state absorption cross-section σ ESA, ratio γ = σ GSA/σ ESA, and absorbing ions density. For V:YAG crystal, a polarization dependence of T s was also investigated. With the help of rate equation numerical solution, an impact of saturable absorber parameters on generated Q-switched pulse properties was studied in plane wave approximation. Selected saturable absorbers were also investigated as a Q-switch and results were compared with the model.
Felhofer, Jessica L.; Scida, Karen; Penick, Mark; Willis, Peter A.; Garcia, Carlos D.
2013-01-01
To overcome the problem of poor sensitivity of capillary electrophoresis-UV absorbance for the detection of aliphatic amines, a solid phase extraction and derivatization scheme was developed. This work demonstrates successful coupling of amines to a chromophore immobilized on a solid phase and subsequent cleavage and analysis. Although the analysis of many types of amines is relevant for myriad applications, this paper focuses on the derivatization and separation of amines with environmental relevance. This work aims to provide the foundations for future developments of an integrated sample preparation microreactor capable of performing simultaneous derivatization, preconcentration, and sample cleanup for sensitive analysis of primary amines. PMID:24054648
Super-absorbency and phase transition of gels in physiological salt solutions
NASA Astrophysics Data System (ADS)
Zhang, Yong-Qing; Tanaka, Toyoichi; Shibayama, Mitsuhiro
1992-11-01
IONIC gels with the ability to absorb many times their dry weight of water have found widespread use as absorbents in medical, chemical and agricultural applications1. The dramatic swelling power of these super-absorbent gels results from both the electrostatic repulsion between the charges on the polymer chains, and the osmotic pressure of the counter-ions2. In salt solutions such as saline, urine or blood, however, excess Na+ and Cl- ions screen the polymer charges and eliminate the osmotic imbalance, effectively changing the properties of the material to that of a non-ionic gel3: this greatly diminishes the swelling power, and hence the utility of these materials under physiological conditions. Here we report the development of a system combining a non-ionic gel with ionized surfactants, which shows super-absorbent behaviour even in the presence of salt. In water, the hydrophobic gel facilitates the formation of spherical surfactant micelles, which mimic the charged sites of an ionic gel. As the salt concentration is increased, the micelles become rod-like, maintaining the electrostatic repulsion along the polymer chains and thereby preserving the swelling power of the gel.
Protonation state of Glu142 differs in the green- and blue-absorbing variants of proteorhodopsin.
Kralj, Joel M; Bergo, Vladislav B; Amsden, Jason J; Spudich, Elena N; Spudich, John L; Rothschild, Kenneth J
2008-03-18
Proteorhodopsins are a recently discovered class of microbial rhodopsins, ubiquitous in marine bacteria. Over 4000 variants have thus far been discovered, distributed throughout the oceans of the world. Most variants fall into one of two major groups, green- or blue-absorbing proteorhodopsin (GPR and BPR, respectively), on the basis of both the visible absorption maxima (530 versus 490 nm) and photocycle kinetics ( approximately 20 versus approximately 200 ms). For a well-studied pair, these differences appear to be largely determined by the identity of a single residue at position 105 (leucine/GPR and glutamine/BPR). We find using a combination of visible and infrared spectroscopy that a second difference is the protonation state of a glutamic acid residue located at position 142 on the extracellular side of helix D. In BPR, Glu142 (the GPR numbering system is used) is deprotonated and can act as an alternate proton acceptor, thus explaining the earlier observations that neutralization of the Schiff base counterion, Asp97, does not block the formation of the M intermediate. In contrast, Glu142 in GPR is protonated and cannot act in this state as an alternate proton acceptor for the Schiff base. On the basis of these findings, a mechanism is proposed for proton pumping in BPR. Because the pKa of Glu142 is near the pH of its native marine environment, changes in pH may act to modulate its function in the cell. PMID:18284210
Luminescence readout of nanoparticle phase state
NASA Astrophysics Data System (ADS)
Denisyuk, A. I.; Jonsson, F.; MacDonald, K. F.; Zheludev, N. I.; García de Abajo, F. J.
2008-03-01
We report that the phase state of bistable gallium nanoparticles, controlled by optical or electron beam excitations, can be identified via measurements of their cathodoluminescent emission, thus offering an innovative conceptual basis for the development of high density nonvolatile phase-change memories. Changes of up to 20% in visible emission intensity are observed following low-fluence optical or electron beam induced phase switching in a monolayer of 60nm particles.
Phase Transfer-Catalyzed Fast CO2 Absorption by MgO-Based Absorbents with High Cycling Capacity
Zhang, Keling; Li, Xiaohong S.; Li, Weizhen; Rohatgi, Aashish; Duan, Yuhua; Singh, Prabhakar; Li, Liyu; King, David L.
2014-06-01
CO2 capture from pre-combustion syngas in the temperature range of 250-400°C is highly desirable from an energy efficiency perspective. Thermodynamically, MgO is a promising material for CO2 capture, but the gas-solid reaction to produce MgCO3 is kinetically slow due to high lattice energy. We report here fast CO2 absorption over a solid MgO-molten nitrate/nitrite aggregate through phase transfer catalysis, in which the molten phase serves as both a catalyst and reaction medium. Reaction with CO2 at the gas-solid-liquid triple phase boundary results in formation of MgCO3 with significant reaction rate and a high conversion of MgO. This methodology is also applicable to other alkaline earth oxides, inspiring the design of absorbents which require activation of the bulk material.
Lawrence, J F; Charbonneau, C F
1988-01-01
The artificial sweeteners aspartame, saccharin, cyclamate, alitame, acesulfam-K, sucralose, and dulcin are determined in diet soft drinks and tabletop sweetener preparations. Samples are diluted, filtered, and analyzed directly by liquid chromatography on a C-18 reverse-phase column with a mobile phase gradient ranging from 3% acetonitrile in 0.02M KH2PO4 (pH 5) to 20% acetonitrile in 0.02M KH2PO4 (pH 3.5). Diet puddings and dessert toppings are extracted with ethanol, filtered, and diluted with mobile phase for analysis. The sweeteners, except sucralose and cyclamate, were detected by UV absorbance at either 200 or 210 nm. Sucralose was determined at 200 nm or by refractive index. Cyclamate was determined after post-column ion-pair extraction. The sweeteners stevioside and talin were not detected. Additives such as caffeine, sorbic acid, and benzoic acid did not interfere.
Phase evolution in spatial dark states
McEndoo, S.; Brophy, J.; Busch, Th.; Croke, S.
2010-04-15
Adiabatic techniques using multilevel systems have recently been generalized from the optical case to settings in atom optics, solid state physics, and even classical electrodynamics. The most well known example of these is the so-called stimulated Raman adiabatic passage (STIRAP) process, which allows transfer of a particle between different states with large fidelity. Here we generalize and examine this process for an atomic center-of-mass state with a nontrivial phase distribution and show that even though dark state dynamics can be achieved for the atomic density, the phase dynamics will still have to be considered as a dynamical process. In particular we show that the combination of adiabatic and nonadiabatic behavior can be used to engineer phase superposition states.
Particle Rebound and Phase State of Secondary Organic Material
NASA Astrophysics Data System (ADS)
Bateman, A.; Bertram, A. K.; Martin, S. T.
2014-12-01
Secondary organic material (SOM) is produced in the atmosphere from the oxidation of volatile organic compounds emitted from anthropogenic and biogenic sources. Aerosol particles, composed in part of SOM, play important roles in climate and air quality by scattering/absorbing radiation and serving as cloud condensation nuclei (CCN). The magnitude of climate-relevant perturbations depends on particle chemical composition, hygroscopic growth, and phase state, among other factors. Herein, the hygroscopic influence on particle rebound and the phase state of particles composed of isoprene, toluene, and α-pinene secondary organic material (SOM) was studied. Particle rebound measurements were obtained from 5 to 95% RH using a three-arm impaction apparatus. The experimentally determined rebound fractions were compared with results from a model of the rebound process that took into account the particle kinetic energy, van der Waals forces, and RH-dependent capillary forces. Comparison of the experimental and modeled indicated particles softened due to water uptake. For low RH values, the model explained the rebound behavior for all studied SOMs. At higher RH values specific to each SOM, however, particle rebound was no longer observed, and the model did not capture this behavior. Calibration experiments using sucrose particles of variable known viscosities showed the transition from non-rebounding to rebounding particles occurred for viscosity values from 100 to 1 Pa s, corresponding to a transition from semisolid to liquid material. The implication of the differing RH-dependent behaviors among the SOMs is that each SOM has a specific and quantitatively different interaction with water. A linear correlation between rebound fraction and hygroscopic growth factor was demonstrated, implying that absorbed water volume is the governing factor of viscosity for the studied classes of SOM. The findings of this study suggest that both the chemical composition and the ambient
Propagating confined states in phase dynamics
NASA Technical Reports Server (NTRS)
Brand, Helmut R.; Deissler, Robert J.
1992-01-01
Theoretical treatment is given to the possibility of the existence of propagating confined states in the nonlinear phase equation by generalizing stationary confined states. The nonlinear phase equation is set forth for the case of propagating patterns with long wavelengths and low-frequency modulation. A large range of parameter values is shown to exist for propagating confined states which have spatially localized regions which travel on a background with unique wavelengths. The theoretical phenomena are shown to correspond to such physical systems as spirals in Taylor instabilities, traveling waves in convective systems, and slot-convection phenomena for binary fluid mixtures.
Hydration states of AFm cement phases
Baquerizo, Luis G.; Matschei, Thomas; Scrivener, Karen L.; Saeidpour, Mahsa; Wadsö, Lars
2015-07-15
The AFm phase, one of the main products formed during the hydration of Portland and calcium aluminate cement based systems, belongs to the layered double hydrate (LDH) family having positively charged layers and water plus charge-balancing anions in the interlayer. It is known that these phases present different hydration states (i.e. varying water content) depending on the relative humidity (RH), temperature and anion type, which might be linked to volume changes (swelling and shrinkage). Unfortunately the stability conditions of these phases are insufficiently reported. This paper presents novel experimental results on the different hydration states of the most important AFm phases: monocarboaluminate, hemicarboaluminate, strätlingite, hydroxy-AFm and monosulfoaluminate, and the thermodynamic properties associated with changes in their water content during absorption/desorption. This data opens the possibility to model the response of cementitious systems during drying and wetting and to engineer systems more resistant to harsh external conditions.
Lee, Sang Bub
2015-12-01
The absorbing phase transition of the modified conserved lattice gas (m-CLG) model was investigated in one dimension. The m-CLG model was modified from the conserved lattice gas (CLG) model in such a way that each active particle hops to one of the nearest-neighbor and next-nearest-neighbor empty sites. The order parameter exponent, the dynamic exponent, and the correlation length exponent were estimated from the power-law behavior and finite-size scaling of the active particle densities. The exponents were found to differ considerably from those of the ordinary CLG model and were also distinct from those of the Manna model, suggesting that next-nearest-neighbor hopping is a relevant factor that alters the critical behavior in the one-dimensional CLG model. PMID:26764627
NASA Astrophysics Data System (ADS)
Franceschini, Alexandre; Filippidi, Emmanouela; Guazzelli, Elisabeth; Pine, David
2011-11-01
Shearing fibers and polymer solutions tends to align particles with the flow direction. Here, we report that neutrally buoyant non-Brownian fibers subjected to oscillatory shear are observed to align perpendicular to the flow. This alignment occurs over a finite range of strain amplitudes and is governed by a subtle interplay between fiber orientation and short-range interactions through an athermal (non-equilibrium) process known as random organization. For a given strain amplitude and concentration, the mean field orientation defines a time-dependant control parameter that can drive the suspension through an absorbing phase transition. The slow drift of the control parameter does not influence the class of the transition. The measured critical threshold and exponents are consistent with the one reported for sphere suspensions. This work was supported by the NSF through the NYU MRSEC, Award DMR:0820341. Additional support was provided by a Lavoisier Fellowship (AF) and from the Onassis Foundation (EF).
Bench-Scale Process for Low-Cost Carbon Dioxide (CO2) Capture Using a Phase-Changing Absorbent
Westendorf, Tiffany; Caraher, Joel; Chen, Wei; Farnum, Rachael; Perry, Robert; Spiry, Irina; Wilson, Paul; Wood, Benjamin
2015-03-31
The objective of this project is to design and build a bench-scale process for a novel phase-changing aminosilicone-based CO2-capture solvent. The project will establish scalability and technical and economic feasibility of using a phase-changing CO2-capture absorbent for post-combustion capture of CO2 from coal-fired power plants with 90% capture efficiency and 95% CO2 purity at a cost of $40/tonne of CO2 captured by 2025 and a cost of <$10/tonne of CO2 captured by 2035. In the first budget period of this project, the bench-scale phase-changing CO2 capture process was designed using data and operating experience generated under a previous project (ARPA-e project DE-AR0000084). Sizing and specification of all major unit operations was completed, including detailed process and instrumentation diagrams. The system was designed to operate over a wide range of operating conditions to allow for exploration of the effect of process variables on CO2 capture performance.
Note: Gratings on low absorbing substrates for x-ray phase contrast imaging
NASA Astrophysics Data System (ADS)
Koch, F. J.; Schröter, T. J.; Kunka, D.; Meyer, P.; Meiser, J.; Faisal, A.; Khalil, M. I.; Birnbacher, L.; Viermetz, M.; Walter, M.; Schulz, J.; Pfeiffer, F.; Mohr, J.
2015-12-01
Grating based X-ray phase contrast imaging is on the verge of being applied in clinical settings. To achieve this goal, compact setups with high sensitivity and dose efficiency are necessary. Both can be increased by eliminating unwanted absorption in the beam path, which is mainly due to the grating substrates. Fabrication of gratings via deep X-ray lithography can address this issue by replacing the commonly used silicon substrate with materials with lower X-ray absorption that fulfill certain boundary conditions. Gratings were produced on both graphite and polymer substrates without compromising on structure quality. These gratings were tested in a three-grating setup with a source operated at 40 kVp and lead to an increase in the detector photon count rate of almost a factor of 4 compared to a set of gratings on silicon substrates. As the visibility was hardly affected, this corresponds to a significant increase in sensitivity and therefore dose efficiency.
Note: Gratings on low absorbing substrates for x-ray phase contrast imaging
Koch, F. J. Schröter, T. J.; Kunka, D.; Meyer, P.; Meiser, J.; Faisal, A.; Khalil, M. I.; Mohr, J.; Birnbacher, L.; Viermetz, M.; Pfeiffer, F.; Walter, M.; Schulz, J.
2015-12-15
Grating based X-ray phase contrast imaging is on the verge of being applied in clinical settings. To achieve this goal, compact setups with high sensitivity and dose efficiency are necessary. Both can be increased by eliminating unwanted absorption in the beam path, which is mainly due to the grating substrates. Fabrication of gratings via deep X-ray lithography can address this issue by replacing the commonly used silicon substrate with materials with lower X-ray absorption that fulfill certain boundary conditions. Gratings were produced on both graphite and polymer substrates without compromising on structure quality. These gratings were tested in a three-grating setup with a source operated at 40 kVp and lead to an increase in the detector photon count rate of almost a factor of 4 compared to a set of gratings on silicon substrates. As the visibility was hardly affected, this corresponds to a significant increase in sensitivity and therefore dose efficiency.
Phase diagram of two interacting helical states
NASA Astrophysics Data System (ADS)
Santos, Raul A.; Gutman, D. B.; Carr, Sam T.
2016-06-01
We consider two coupled time-reversal-invariant helical edge modes of the same helicity, such as would occur on two stacked quantum spin Hall insulators. In the presence of interaction, the low-energy physics is described by two collective modes, one corresponding to the total current flowing around the edge and the other one describing relative fluctuations between the two edges. We find that quite generically, the relative mode becomes gapped at low temperatures, but only when tunneling between the two helical modes is nonzero. There are two distinct possibilities for the gapped state depending on the relative size of different interactions. If the intraedge interaction is stronger than the interedge interaction, the state is characterized as a spin-nematic phase. However, in the opposite limit, when the interaction between the helical edge modes is strong compared to the interaction within each mode, a spin-density wave forms, with emergent topological properties. First, the gap protects the conducting phase against localization by weak nonmagnetic impurities; second, the protected phase hosts localized zero modes on the ends of the edge that may be created by sufficiently strong nonmagnetic impurities.
Solid-state phased array (SSPA) performance
NASA Astrophysics Data System (ADS)
Kley, Robert C., Jr.; Hull, W. Porter, Jr.; Lamb, Franklin D.
The solid-state phased-array (SSPA) is an active electronically scanned array (AESA) designed and built for airborne radar applications using transmit/receive module hybrid technology. Details of its subassemblies and results of testing the array and its subassemblies are presented. The SSPA T/R (transmit/receive) modules used a hybrid construction that is labor-intensive and leads to parameter variations. The next generation of modules uses monolithic microwave integrated circuit (MMIC) devices, which will result in more uniform parameters and lower manufacturing cost.
1 Mixing state and absorbing properties of black carbon during Arctic haze
NASA Astrophysics Data System (ADS)
Zanatta, Marco; Gysel, Martin; Eleftheriadis, Kosas; Laj, Paolo; Hans-Werner, Jacobi
2016-04-01
The Arctic atmosphere is periodically affected by the Arctic haze occurring in spring. One of its particulate components is the black carbon (BC), which is considered to be an important contributor to climate change in the Arctic region. Beside BC-cloud interaction and albedo reduction of snow, BC may influence Arctic climate interacting directly with the solar radiation, warming the corresponding aerosol layer (Flanner, 2013). Such warming depends on BC atmospheric burden and also on the efficiency of BC to absorb light, in fact the light absorption is enhanced by mixing of BC with other atmospheric non-absorbing materials (lensing effect) (Bond et al., 2013). The BC reaching the Arctic is evilly processed, due to long range transport. Aging promote internal mixing and thus absorption enhancement. Such modification of mixing and is quantification after long range transport have been observed in the Atlantic ocean (China et al., 2015) but never investigated in the Arctic. During field experiments conducted at the Zeppelin research site in Svalbard during the 2012 Arctic spring, we investigated the relative precision of different BC measuring techniques; a single particle soot photometer was then used to assess the coating of Arctic black carbon. This allowed quantifying the absorption enhancement induced by internal mixing via optical modelling; the optical assessment of aged black carbon in the arctic will be of major interest for future radiative forcing assessment.Optical characterization of the total aerosol indicated that in 2012 no extreme smoke events took place and that the aerosol population was dominated by fine and non-absorbing particles. Low mean concentration of rBC was found (30 ng m-3), with a mean mass equivalent diameter above 200 nm. rBC concentration detected with the continuous soot monitoring system and the single particle soot photometer was agreeing within 15%. Combining absorption coefficient observed with an aethalometer and rBC mass
Harmonic mode locking of bound-state solitons fiber laser based on MoS(2) saturable absorber.
Wang, Yadong; Mao, Dong; Gan, Xuetao; Han, Lei; Ma, Chaojie; Xi, Teli; Zhang, Yi; Shang, Wuyun; Hua, Shijia; Zhao, Jianlin
2015-01-12
We present a kind of harmonic mode locking of bound-state solitons in a fiber laser based on molybdenum disulfide (MoS(2)) saturable absorber (SA). The mode locker is fabricated by depositing MoS(2) nanosheets on a D-shaped fiber (DF). In the fiber laser, two solitons form the bound-state pulses with a temporal separation of 3.4 ps, and the bound-state pulses are equally distributed at a repetition rate of 125 MHz, corresponding to 14th harmonics of fundamental cavity repetition rate (8.968 MHz). Single- and multiple-pulses emissions are also observed by changing the pump power and optimizing the DF based MoS(2) SA. Our experiment demonstrates an interesting operation regime of mode-locked fiber laser, and shows that DF based MoS(2) SA can work as a promising high-power mode locker in ultrafast lasers. PMID:25835667
NASA Astrophysics Data System (ADS)
Mohamad, Ahmad Azmin
2016-10-01
The application of quasi-solid state electrolytes for dye-sensitized solar cells opens up an interesting research field to explore, which is evident from the increasing amount of publications on this topic. Since 2010, significant progress has been made with new and more complicated quasi-solid-states materials being produced. The optimization of new materials requires specific characterizations. This review presents a comprehensive overview and recent progress of characterization methods for studying quasi-solid-state electrolytes. Emphasis is then placed on the absorbency and conductivity characterizations. Each characterization will be reviewed according to the objective, experimental set-up, summary of important outcomes, and a few case studies worth discussing. Finally, strategies for future characterizations and developments are described.
Zhang Qiulin; Feng Baohua; Zhang Dongxiang; Fu Panming; Zhang Zhiguo; Zhao Zhiwei; Deng Peizhen; Xu Jun; Xu Xiaodong; Wang Yonggang; Ma Xiaoyu
2004-05-01
We report on recent experimental results of the spontaneous antiphase dynamics that occurs in a laser-diode-pumped multimode passively Q-switched microchip Yb:YAG (where YAG is yttrium aluminum garnet) lasers with a saturable absorber GaAs. We observe that the pulse sequence of the first mode characterized by one, two, and three pulses as a group and all the modes display an antiphase state as the pumping ratio rises. We modify the multimode rate equations to account for nonlinear absorption due to GaAs in the presence of spatial hole burning. We perform numerical simulations based on the proposed rate equations and reproduce the observed antiphase state of two and three active modes.
Sheng, Qiwen; Feng, Ming; Xin, Wei; Han, Tianyu; Liu, Yange; Liu, Zhibo; Tian, Jianguo
2013-06-17
We experimentally demonstrate an operation switchable Erbium-doped fiber laser by employing graphene saturable absorber (GSA) on microfiber. With the introducing of a polydimethylsiloxane layer, a graphene can be considered as a parallel plate on microfiber and induces different propagation losses to TE and TM modes. By the use of such polarization sensitive GSA on microfiber, Erbium doped fiber laser with switchable operation states such as continuous wave, stable Q-switching, Q-switched mode-locking, and continuous-wave mode-locking, can be achieved by simply tuning the polarization states in the laser cavity. Our results show that covering graphene on microfibers could be a promising method for fabricating all fiber SA, and may have high potential in wide applications.
Phase states of methane in fossil coals
NASA Astrophysics Data System (ADS)
Alexeev, A. D.; Vasylenko, T. A.; Ul'yanova, E. V.
2004-06-01
NMR measurements have revealed that methane can exist in coal samples in the state of solid solution rather than only adsorbed gas, opening new ways to prevention of gas dynamic accidents in underground coal mines and true estimation of coalbed methane resources. Understanding molecular structure of coal constituents and forms of methane occurrence in coal is the only way of extracting safely either coal or methane. We had studied nuclear magnetic resonance lines in various coals at room or low temperatures and have found that there exist three species of methane molecules differing in molecular mobility. Based on estimated diffusion parameters, these species were attributed to free methane, adsorbed methane, and solid solution of methane in crystalline coal substance. While first two phases are well known and can be analyzed by many different techniques, the last one hardly can be studied by methods other than NMR, resulting in inadequate estimations of methane resources.
NASA Astrophysics Data System (ADS)
McMeeking, G. R.; Kreidenweis, S. M.; Yokelson, R. J.; Sullivan, A. P.; Lee, T.; Collett, J. L.; Fortner, E.; Onasch, T. B.; Akagi, S. K.; Taylor, J.; Coe, H.
2012-12-01
Black carbon (BC) aerosol emitted from fires absorbs light, leading to visibility degradation as well as regional and global climate impacts. Fires also emit a wide range of trace gases and particulates that can interact with emitted BC and alter its optical properties and atmospheric lifetime. Non-BC particulate species emitted by fires can also scatter and absorb light, leading to additional effects on visibility. Recent work has shown that certain organic species can absorb light strongly at shorter wavelengths, giving it a brown or yellow color. This material has been classified as brown carbon, though it is not yet well defined. Land managers must find a balance between the negative impacts of prescribed fire emissions on visibility and air quality and the need to prevent future catastrophic wildfire as well as manage ecosystems for habitat restoration or other purposes. This decision process requires accurate assessments of the visibility impacts of fire emissions, including BC and brown carbon, which in turn depend on their optical properties. We present recent laboratory and aircraft measurements of black carbon and aerosol optical properties emitted from biomass burning. All measurement campaigns included a single particle soot photometer (SP2) instrument capable of providing size-resolved measurements of BC mass and number distributions and mixing state, which are needed to separate the BC and brown carbon contributions to total light absorption. The laboratory experiments also included a three-wavelength photoacoustic spectrometer that provided accurate measurements of aerosol light absorption. The laboratory systems also characterized emissions after they had been treated with a thermal denuder to remove semi-volatile coatings, allowing an assessment of the role of non-BC coatings on bulk aerosol optical properties. Emissions were also aged in an environmental smog chamber to examine the role of secondary aerosol production on aerosol optical properties.
Bound-state fiber laser mode-locked by a graphene-nanotube saturable absorber
NASA Astrophysics Data System (ADS)
Yang, H. R.; Chen, G. W.; Kong, Y. C.; Li, W. L.
2015-02-01
We have experimentally observed the multiple bound states in a linear-cavity fiber laser mode-locked by a mixture of graphene and single-walled carbon nanotubes. The proposed laser can deliver the fundamental frequency soliton as well as the two and three bound-state solitons at suitable conditions. The numerical simulations confirm the experimental observations. Both the theoretical predictions and experimental results reveal that the spectral filtering effect plays a key role on the lasers.
NASA Astrophysics Data System (ADS)
Ma, Ruixin; Yang, Fan; Li, Shina; Zhang, Xiaoyong; Li, Xiang; Cheng, Shiyao; Liu, Zilin
2016-04-01
CZTSSe is an important earth abundant collection of materials for the development of low cost and high efficiency thin film solar cells. This work developed a simple non-vacuum-based route to fabricate CZTSSe absorber films. This was demonstrated by first synthesizing Cu2ZnSnS4 (CZTS) nano-crystalline based on solid-phase synthesis. Then a stable colloidal ink composed of CZTS nano-crystalline was blade coated on Mo-coated substrates followed by an annealing process under Ar atmosphere. After CZTS films formation, the films were sintered into CZTSSe absorber films by exposing them under Selenium vapor. The formation of a kesterite type CZTS was confirmed using X-ray diffraction and Raman scattering measurements. The band gap of CZTSSe absorber films was determined to be 1.26 eV, which was appropriate for use as an absorber layer in thin film solar cells. The CZTSSe absorber films showed a good photovoltatic performance, demonstrating this simple approach had great potential for CZTSSe solar cell production.
High-repetition-rate Q-modulation in solid-state laser using fast saturable absorber V:YAG
NASA Astrophysics Data System (ADS)
Ma, Jia-Sai; Wang, Feng; Li, Pei-Xin; Hu, Wei-Wei; Yin, Chun-Hao; Xu, Jin-Long
2015-07-01
A high-repetition-rate Q-modulation operation in a solid-state Nd:GdVO4 laser with a V3+:YAG saturable absorber has been demonstrated in this paper. The V3+:YAG crystal behaves as a fast saturable absorber in this laser because of its very short lifetime of 22 ns. Taking advantage of such fast bleaching recovery and effective cooling of the V:YAG by a home-made copper holder, we realized a pulse repetition rate of 2.4 MHz, which is, to our best knowledge, the maximum among the reported passively Q-switched lasers. The corresponding average output power and pulse width were 1.28 W and 170 ns, respectively, giving a slope efficiency of 15.9% and a pulse energy of 0.53 µJ. This compact high-repetition-rate Q-switched laser offers a potential application in the construction of low-cost, integrated and portable sensing detection equipment which needs a high laser pulse repetition rate.
Lin, Kuei-Huei; Kang, Jung-Jui; Wu, Hsiao-Hua; Lee, Chao-Kuei; Lin, Gong-Ru
2009-03-16
We propose an operation switchable ring-cavity erbium-doped fiber laser (EDFL) via intra-cavity polarization control. By using a semiconductor saturable absorber mirror in the EDFL cavity, stable Q-switching, Q-switched mode-locking, continuous-wave mode-locking, pulse splitting, and harmonic mode-locking pulses can be manipulated simply by detuning a polarization controller while keeping the pump power at the same level. All EDFL operation states can be obtained under the polarization angles detuning within 180 degrees. Continuous-wave mode-locking of EDFL with 800-fs pulsewidth repeated at 4 MHz has been obtained, for which the output pulse energy is 0.5 nJ and the peak power is 625 W. Interaction between solitons and the accompanied non-soliton component will lead to either pulse splitting or 5th-order harmonic mode-locking at repetition rate of 20 MHz.
Berry's phase for coherent states of Landau levels
Yang, Wen-Long; Chen, Jing-Ling
2007-02-15
The Berry phases for coherent states and squeezed coherent states of Landau levels are calculated. Coherent states of Landau levels are interpreted as a result of a magnetic flux moved adiabatically from infinity to a finite place on the plane. The Abelian Berry phase for coherent states of Landau levels is an analog of the Aharonov-Bohm effect. Moreover, the non-Abelian Berry phase is calculated for the adiabatic evolution of the magnetic field B.
Excited state quantum phase transitions in many-body systems
Caprio, M.A. Cejnar, P.; Iachello, F.
2008-05-15
Phenomena analogous to ground state quantum phase transitions have recently been noted to occur among states throughout the excitation spectra of certain many-body models. These excited state phase transitions are manifested as simultaneous singularities in the eigenvalue spectrum (including the gap or level density), order parameters, and wave function properties. In this article, the characteristics of excited state quantum phase transitions are investigated. The finite-size scaling behavior is determined at the mean-field level. It is found that excited state quantum phase transitions are universal to two-level bosonic and fermionic models with pairing interactions.
Equations of State and Phase Diagrams of Ammonia
ERIC Educational Resources Information Center
Glasser, Leslie
2009-01-01
We present equations of state relating the phases and a three-dimensional phase diagram for ammonia with its solid, liquid, and vapor phases, based on fitted authentic experimental data and including recent information on the high-pressure solid phases. This presentation follows similar articles on carbon dioxide and water published in this…
Chimera states in two populations with heterogeneous phase-lag
NASA Astrophysics Data System (ADS)
Martens, Erik A.; Bick, Christian; Panaggio, Mark J.
2016-09-01
The simplest network of coupled phase-oscillators exhibiting chimera states is given by two populations with disparate intra- and inter-population coupling strengths. We explore the effects of heterogeneous coupling phase-lags between the two populations. Such heterogeneity arises naturally in various settings, for example, as an approximation to transmission delays, excitatory-inhibitory interactions, or as amplitude and phase responses of oscillators with electrical or mechanical coupling. We find that breaking the phase-lag symmetry results in a variety of states with uniform and non-uniform synchronization, including in-phase and anti-phase synchrony, full incoherence (splay state), chimera states with phase separation of 0 or π between populations, and states where both populations remain desynchronized. These desynchronized states exhibit stable, oscillatory, and even chaotic dynamics. Moreover, we identify the bifurcations through which chimeras emerge. Stable chimera states and desynchronized solutions, which do not arise for homogeneous phase-lag parameters, emerge as a result of competition between synchronized in-phase, anti-phase equilibria, and fully incoherent states when the phase-lags are near ± /π 2 (cosine coupling). These findings elucidate previous experimental results involving a network of mechanical oscillators and provide further insight into the breakdown of synchrony in biological systems.
Geometric Phase for Adiabatic Evolutions of General Quantum States
Wu, Biao; Liu, Jie; Niu, Qian; Singh, David J
2005-01-01
The concept of a geometric phase (Berry's phase) is generalized to the case of noneigenstates, which is applicable to both linear and nonlinear quantum systems. This is particularly important to nonlinear quantum systems, where, due to the lack of the superposition principle, the adiabatic evolution of a general state cannot be described in terms of eigenstates. For linear quantum systems, our new geometric phase reduces to a statistical average of Berry's phases. Our results are demonstrated with a nonlinear two-level model.
High power phase conjugated solid state lasers
Hackel, L.A.; Dane, C.B.; Zapata, L.E.; Hermann, M.R.
1994-07-01
Three laser systems that are being developed for use in x-ray generation which incorporate SBS phase conjugate mirrors are described. A 25J/pulse Nd:glass laser is being developed for commercial proximity print x-ray lithography; a 0.5J/pulse, 1.3 kHz pulse repetition frequency laser is being built for soft x-ray projection lithography; and a 1 kJ/pulse laser driver for a table top x-ray laser has been designed. The results of prototypical experimental investigations are presented and the basic design principles for high average power phase conjugated laser systems shared by each of these lasers are discussed.
NASA Astrophysics Data System (ADS)
Fuchs, H. V.; Möser, M.
Sound absorption indicates the transformation of sound energy into heat. It is, for instance, employed to design the acoustics in rooms. The noise emitted by machinery and plants shall be reduced before arriving at a workplace; auditoria such as lecture rooms or concert halls require a certain reverberation time. Such design goals are realised by installing absorbing components at the walls with well-defined absorption characteristics, which are adjusted for corresponding demands. Sound absorbers also play an important role in acoustic capsules, ducts and screens to avoid sound immission from noise intensive environments into the neighbourhood.
Equations of state and phase diagrams of hydrogen isotopes
Urlin, V. D.
2013-11-15
A new form of the semiempirical equation of state proposed for the liquid phase of hydrogen isotopes is based on the assumption that its structure is formed by cells some of which contain hydrogen molecules and others contain hydrogen atoms. The values of parameters in the equations of state of the solid (molecular and atomic) phases as well as of the liquid phase of hydrogen isotopes (protium and deuterium) are determined. Phase diagrams, shock adiabats, isentropes, isotherms, and the electrical conductivity of compressed hydrogen are calculated. Comparison of the results of calculations with available experimental data in a wide pressure range demonstrates satisfactory coincidence.
NASA Astrophysics Data System (ADS)
Schaeck, S.; Stoermer, A. O.; Hockgeiger, E.
The BMW Group has launched two micro-hybrid functions in high volume models in order to contribute to reduction of fuel consumption in modern passenger cars. Both the brake energy regeneration (BER) and the auto-start-stop function (ASSF) are based on the conventional 14 V vehicle electrical system and current series components with only little modifications. An intelligent control algorithm of the alternator enables recuperative charging in braking and coasting phases, known as BER. By switching off the internal combustion engine at a vehicle standstill the idling fuel consumption is effectively reduced by ASSF. By reason of economy and package a lead-acid battery is used as electrochemical energy storage device. The BMW Group assembles valve-regulated lead-acid (VRLA) batteries in absorbent glass mat (AGM) technology in the micro-hybrid electrical power system since special challenges arise for the batteries. By field data analysis a lower average state-of-charge (SOC) due to partial state-of-charge (PSOC) operation and a higher cycling rate due to BER and ASSF are confirmed in this article. Similar to a design of experiment (DOE) like method we present a long-term lab investigation. Two types of 90 Ah VRLA AGM batteries are operated with a test bench profile that simulates the micro-hybrid vehicle electrical system under varying conditions. The main attention of this lab testing is focused on capacity loss and charge acceptance over cycle life. These effects are put into context with periodically refresh charging the batteries in order to prevent accelerated battery aging due to hard sulfation. We demonstrate the positive effect of refresh chargings concerning preservation of battery charge acceptance. Furthermore, we observe moderate capacity loss over 90 full cycles both at 25 °C and at 3 °C battery temperature.
Bubis, E L
2011-06-30
Self-imaging of transparent objects and structures in focusing of a spatially phase-modulated laser beam into an extended weakly absorbing medium is described. The laser power level that is necessary for effective imaging corresponds to the illuminating beam power when thermal self-defocusing starts evolving in the medium. The effect can be described in terms of the ideology of Zernike's classical phase-contrast method. Edge enhancement in visualised images of transparent objects is experimentally demonstrated. Self-imaging of a microscopic object in the form of transparent letters and long-lived refractive-index fluctuations in liquid glycerol is shown. Due to the adaptivity of the process under consideration, unlike the classical case, self-imaging occurs also in the situations where a beam is displaced (undergoes random walk) as a whole in the Fourier plane, for example, in the presence of thermal flows. (image processing)
Li, Xiaohui; Wu, Kan; Sun, Zhipei; Meng, Bo; Wang, Yonggang; Wang, Yishan; Yu, Xuechao; Yu, Xia; Zhang, Ying; Shum, Perry Ping; Wang, Qi Jie
2016-01-01
Low phase noise mode-locked fiber laser finds important applications in telecommunication, ultrafast sciences, material science, and biology, etc. In this paper, two types of carbon nano-materials, i.e. single-wall carbon nanotube (SWNT) and graphene oxide (GO), are investigated as efficient saturable absorbers (SAs) to achieve low phase noise mode-locked fiber lasers. Various properties of these wall-paper SAs, such as saturable intensity, optical absorption and degree of purity, are found to be key factors determining the performance of the ultrafast pulses. Reduced-noise femtosecond fiber lasers based on such carbon-based SAs are experimentally demonstrated, for which the phase noise has been reduced by more than 10 dB for SWNT SAs and 8 dB for GO SAs at 10 kHz. To the best of our knowledge, this is the first investigation on the relationship between different carbon material based SAs and the phase noise of mode-locked lasers. This work paves the way to generate high-quality low phase noise ultrashort pulses in passively mode-locked fiber lasers. PMID:27126900
Li, Xiaohui; Wu, Kan; Sun, Zhipei; Meng, Bo; Wang, Yonggang; Wang, Yishan; Yu, Xuechao; Yu, Xia; Zhang, Ying; Shum, Perry Ping; Wang, Qi Jie
2016-04-29
Low phase noise mode-locked fiber laser finds important applications in telecommunication, ultrafast sciences, material science, and biology, etc. In this paper, two types of carbon nano-materials, i.e. single-wall carbon nanotube (SWNT) and graphene oxide (GO), are investigated as efficient saturable absorbers (SAs) to achieve low phase noise mode-locked fiber lasers. Various properties of these wall-paper SAs, such as saturable intensity, optical absorption and degree of purity, are found to be key factors determining the performance of the ultrafast pulses. Reduced-noise femtosecond fiber lasers based on such carbon-based SAs are experimentally demonstrated, for which the phase noise has been reduced by more than 10 dB for SWNT SAs and 8 dB for GO SAs at 10 kHz. To the best of our knowledge, this is the first investigation on the relationship between different carbon material based SAs and the phase noise of mode-locked lasers. This work paves the way to generate high-quality low phase noise ultrashort pulses in passively mode-locked fiber lasers.
NASA Astrophysics Data System (ADS)
Li, Xiaohui; Wu, Kan; Sun, Zhipei; Meng, Bo; Wang, Yonggang; Wang, Yishan; Yu, Xuechao; Yu, Xia; Zhang, Ying; Shum, Perry Ping; Wang, Qi Jie
2016-04-01
Low phase noise mode-locked fiber laser finds important applications in telecommunication, ultrafast sciences, material science, and biology, etc. In this paper, two types of carbon nano-materials, i.e. single-wall carbon nanotube (SWNT) and graphene oxide (GO), are investigated as efficient saturable absorbers (SAs) to achieve low phase noise mode-locked fiber lasers. Various properties of these wall-paper SAs, such as saturable intensity, optical absorption and degree of purity, are found to be key factors determining the performance of the ultrafast pulses. Reduced-noise femtosecond fiber lasers based on such carbon-based SAs are experimentally demonstrated, for which the phase noise has been reduced by more than 10 dB for SWNT SAs and 8 dB for GO SAs at 10 kHz. To the best of our knowledge, this is the first investigation on the relationship between different carbon material based SAs and the phase noise of mode-locked lasers. This work paves the way to generate high-quality low phase noise ultrashort pulses in passively mode-locked fiber lasers.
Li, Xiaohui; Wu, Kan; Sun, Zhipei; Meng, Bo; Wang, Yonggang; Wang, Yishan; Yu, Xuechao; Yu, Xia; Zhang, Ying; Shum, Perry Ping; Wang, Qi Jie
2016-01-01
Low phase noise mode-locked fiber laser finds important applications in telecommunication, ultrafast sciences, material science, and biology, etc. In this paper, two types of carbon nano-materials, i.e. single-wall carbon nanotube (SWNT) and graphene oxide (GO), are investigated as efficient saturable absorbers (SAs) to achieve low phase noise mode-locked fiber lasers. Various properties of these wall-paper SAs, such as saturable intensity, optical absorption and degree of purity, are found to be key factors determining the performance of the ultrafast pulses. Reduced-noise femtosecond fiber lasers based on such carbon-based SAs are experimentally demonstrated, for which the phase noise has been reduced by more than 10 dB for SWNT SAs and 8 dB for GO SAs at 10 kHz. To the best of our knowledge, this is the first investigation on the relationship between different carbon material based SAs and the phase noise of mode-locked lasers. This work paves the way to generate high-quality low phase noise ultrashort pulses in passively mode-locked fiber lasers. PMID:27126900
Gaussian cloning of coherent states with known phases
Alexanian, Moorad
2006-04-15
The fidelity for cloning coherent states is improved over that provided by optimal Gaussian and non-Gaussian cloners for the subset of coherent states that are prepared with known phases. Gaussian quantum cloning duplicates all coherent states with an optimal fidelity of 2/3. Non-Gaussian cloners give optimal single-clone fidelity for a symmetric 1-to-2 cloner of 0.6826. Coherent states that have known phases can be cloned with a fidelity of 4/5. The latter is realized by a combination of two beam splitters and a four-wave mixer operated in the nonlinear regime, all of which are realized by interaction Hamiltonians that are quadratic in the photon operators. Therefore, the known Gaussian devices for cloning coherent states are extended when cloning coherent states with known phases by considering a nonbalanced beam splitter at the input side of the amplifier.
Wang, Jianling; Xiao, Xiaofeng; Chen, Tong; Liu, Tingfei; Tao, Huaming; He, Jun
2016-06-17
The glyceride in oil food simulant usually causes serious interferences to target analytes and leads to failure of the normal function of the RP-HPLC column. In this work, a convenient HPLC-UV method for the determination of the total specific migration of nine ultraviolet (UV) absorbers in food simulants was developed based on 1,1,3,3-tetramethylguanidine (TMG) and organic phase anion exchange (OPAE) SPE to efficiently remove glyceride in olive oil simulant. In contrast to the normal ion exchange carried out in an aqueous solution or aqueous phase environment, the OPAE SPE was performed in the organic phase environments, and the time-consuming and challenging extraction of the nine UV absorbers from vegetable oil with aqueous solution could be readily omitted. The method was proved to have good linearity (r≥0.99992), precision (intra-day RSD≤3.3%), and accuracy(91.0%≤recoveries≤107%); furthermore, the lower limit of quantifications (0.05-0.2mg/kg) in five types of food simulants(10% ethanol, 3% acetic acid, 20% ethanol, 50% ethanol and olive oil) was observed. The method was found to be well suited for quantitative determination of the total specific migration of the nine UV absorbers both in aqueous and vegetable oil simulant according to Commission Regulation (EU) No. 10/2011. Migration levels of the nine UV absorbers were determined in 31 plastic samples, and UV-24, UV-531, HHBP and UV-326 were frequently detected, especially in olive oil simulant for UV-326 in PE samples. In addition, the OPAE SPE procedure was also been applied to efficiently enrich or purify seven antioxidants in olive oil simulant. Results indicate that this procedure will have more extensive applications in the enriching or purification of the extremely weak acidic compounds with phenol hydroxyl group that are relatively stable in TMG n-hexane solution and that can be barely extracted from vegetable oil.
Wang, Jianling; Xiao, Xiaofeng; Chen, Tong; Liu, Tingfei; Tao, Huaming; He, Jun
2016-06-17
The glyceride in oil food simulant usually causes serious interferences to target analytes and leads to failure of the normal function of the RP-HPLC column. In this work, a convenient HPLC-UV method for the determination of the total specific migration of nine ultraviolet (UV) absorbers in food simulants was developed based on 1,1,3,3-tetramethylguanidine (TMG) and organic phase anion exchange (OPAE) SPE to efficiently remove glyceride in olive oil simulant. In contrast to the normal ion exchange carried out in an aqueous solution or aqueous phase environment, the OPAE SPE was performed in the organic phase environments, and the time-consuming and challenging extraction of the nine UV absorbers from vegetable oil with aqueous solution could be readily omitted. The method was proved to have good linearity (r≥0.99992), precision (intra-day RSD≤3.3%), and accuracy(91.0%≤recoveries≤107%); furthermore, the lower limit of quantifications (0.05-0.2mg/kg) in five types of food simulants(10% ethanol, 3% acetic acid, 20% ethanol, 50% ethanol and olive oil) was observed. The method was found to be well suited for quantitative determination of the total specific migration of the nine UV absorbers both in aqueous and vegetable oil simulant according to Commission Regulation (EU) No. 10/2011. Migration levels of the nine UV absorbers were determined in 31 plastic samples, and UV-24, UV-531, HHBP and UV-326 were frequently detected, especially in olive oil simulant for UV-326 in PE samples. In addition, the OPAE SPE procedure was also been applied to efficiently enrich or purify seven antioxidants in olive oil simulant. Results indicate that this procedure will have more extensive applications in the enriching or purification of the extremely weak acidic compounds with phenol hydroxyl group that are relatively stable in TMG n-hexane solution and that can be barely extracted from vegetable oil. PMID:27189432
Phase transitions for rotational states within an algebraic cluster model
NASA Astrophysics Data System (ADS)
López Moreno, E.; Morales Hernández, G. E.; Hess, P. O.; Yépez Martínez, H.
2016-07-01
The ground state and excited, rotational phase transitions are investigated within the Semimicroscopic Algebraic Cluster Model (SACM). The catastrophe theory is used to describe these phase transitions. Short introductions to the SACM and the catastrophe theory are given. We apply the formalism to the case of 16O+α→20Ne.
NASA Astrophysics Data System (ADS)
Adachi, Kouji; Moteki, Nobuhiro; Kondo, Yutaka; Igarashi, Yasuhito
2016-08-01
Light-absorbing atmospheric aerosols such as carbonaceous particles influence the climate through absorbing sunlight. The mixing states of these aerosol particles affect their optical properties. This study examines the changes in the mixing states and abundance of strongly light absorbing carbonaceous particles by using transmission electron microscopy (TEM) and single-particle soot photometer (SP2), as well as of iron oxide particles, in Tokyo, Japan. TEM and SP2 use fundamentally different detection techniques for the same light-absorbing particles. TEM allows characterization of the morphological, chemical, and structural features of individual particles, whereas SP2 optically measures the number, size, and mixing states of black carbon (BC). A comparison of the results obtained using these two techniques indicates that the peaks of high soot (nanosphere soot (ns-soot)) concentration periods agree with those of the BC concentrations determined by SP2 and that the high Fe-bearing particle fraction periods measured by TEM agree with that of high number concentrations of iron oxide particles measured using SP2 during the first half of the observation campaign. The results also show that the changes in the ns-soot/BC mixing states primarily correlate with the air mass sources, wind speed, precipitation, and photochemical processes. Nano-sized, aggregated, iron oxide particles mixed with other particles were commonly observed by using TEM during the high iron oxide particle periods. We conclude that although further quantitative comparison between TEM and SP2 data will be needed, the morphologically and optically defined ns-soot and BC, respectively, are essentially the same substance and that their mixing states are generally consistent across the techniques.
Roppo, V.; Cojocaru, C.; Trull, J.; Vilaseca, R.; Raineri, F.; Halioua, Y.; Raj, R.; Sagnes, I.; D'Aguanno, G.; Scalora, M.
2009-10-15
We predict and experimentally observe the enhancement by three orders of magnitude of phase mismatched second and third harmonic generation in a GaAs cavity at 650 and 433 nm, respectively, well above the absorption edge. Phase locking between the pump and the harmonics changes the effective dispersion of the medium and inhibits absorption. Despite hostile conditions the harmonics resonate inside the cavity and become amplified leading to relatively large conversion efficiencies. Field localization thus plays a pivotal role despite the presence of absorption, and ushers in a new class of semiconductor-based devices in the visible and uv ranges.
Quantum phase estimation using path-symmetric entangled states
Lee, Su-Yong; Lee, Chang-Woo; Lee, Jaehak; Nha, Hyunchul
2016-01-01
We study the sensitivity of phase estimation using a generic class of path-symmetric entangled states |φ〉|0〉 + |0〉|φ〉, where an arbitrary state |φ〉 occupies one of two modes in quantum superposition. With this generalization, we identify the fundamental limit of phase estimation under energy constraint that is characterized by the photon statistics of the component state |φ〉. We show that quantum Cramer-Rao bound (QCRB) can be indefinitely lowered with super-Poissonianity of the state |φ〉. For possible measurement schemes, we demonstrate that a full photon-counting employing the path-symmetric entangled states achieves the QCRB over the entire range [0, 2π] of unknown phase shift ϕ whereas a parity measurement does so in a certain confined range of ϕ. By introducing a component state of the form , we particularly show that an arbitrarily small QCRB can be achieved even with a finite energy in an ideal situation. This component state also provides the most robust resource against photon loss among considered entangled states over the range of the average input energy Nav > 1. Finally we propose experimental schemes to generate these path-symmetric entangled states for phase estimation. PMID:27457267
Solid state photomultiplier for astronomy, phase 2
NASA Technical Reports Server (NTRS)
Besser, P. J.; Hays, K. M.; Laviolette, R. A.
1989-01-01
Epitaxial layers with varying donor concentration profiles were grown on silicon substrate wafers using chemical vapor deposition (CVD) techniques, and solid state photomultiplier (SSPM) devices were fabricated from the wafers. Representative detectors were tested in a low background photon flux, low temperature environment to determine the device characteristics for comparison to NASA goals for astronomical applications. The SSPM temperatures varied between 6 and 11 K with background fluxes in the range from less than 5 x 10 to the 6th power to 10 to the 13th power photons/square cm per second at wavelengths of 3.2 and 20 cm. Measured parameters included quantum efficiency, dark count rate and bias current. Temperature for optimal performance is 10 K, the highest ever obtained for SSPMs. The devices exhibit a combination of the lowest dark current and highest quantum efficiency yet achieved. Experimental data were reduced, analyzed and used to generate recommendations for future studies. The background and present status of the microscopic theory of SSPM operation were reviewed and summarized. Present emphasis is on modeling of the avalanche process which is the basis for SSPM operation. Approaches to the solution of the Boltzmann transport equation are described and the treatment of electron scattering mechanisms is presented. The microscopic single-electron transport theory is ready to be implemented for large-scale computations.
Yu, Qinhong; Lim, Sunghyuk; Rockwell, Nathan C; Martin, Shelley S; Clark Lagarias, J; Ames, James B
2016-04-01
Cyanobacteriochrome (CBCR) photosensory proteins are phytochrome homologs using bilin chromophores for light sensing across the visible spectrum. NpR6012g4 is a CBCR from Nostoc punctiforme that serves as a model for a widespread CBCR subfamily with red/green photocycles. We report NMR chemical shift assignments for both the protein backbone and side-chain resonances of the red-absorbing dark state of NpR6012g4 (BMRB no. 26582).
Topological superconducting phase and Majorana bound states in Shiba chains
NASA Astrophysics Data System (ADS)
Pientka, Falko; Peng, Yang; Glazman, Leonid; von Oppen, Felix
2015-12-01
Chains of magnetic adatoms on a conventional superconducting substrate constitute a promising venue for realizing topological superconductivity and Majorana end states. Here, we give a brief overview over recent attempts to describe these systems theoretically, emphasizing how the topological phase emerges from the physics of individual magnetic impurities and their associated Shiba states.
Universal and phase-covariant superbroadcasting for mixed qubit states
Buscemi, Francesco; D'Ariano, Giacomo Mauro; Macchiavello, Chiara; Perinotti, Paolo
2006-10-15
We describe a general framework to study covariant symmetric broadcasting maps for mixed qubit states. We explicitly derive the optimal N{yields}M superbroadcasting maps, achieving optimal purification of the single-site output copy, in both the universal and phase-covariant cases. We also study the bipartite entanglement properties of the superbroadcast states.
Unidirectional perfect absorber
Jin, L.; Wang, P.; Song, Z.
2016-01-01
This study proposes a unidirectional perfect absorber (UPA), which we realized with a two-arm Aharonov-Bohm interferometer, that consists of a dissipative resonator side-coupled to a uniform resonator array. The UPA has reflection-less full absorption on one direction, and reflectionless full transmission on the other, with an appropriate magnetic flux and coupling, detuning, and loss of the side-coupled resonator. The magnetic flux controls the transmission, the left transmission is larger for magnetic flux less than one-half flux quantum; and the right transmission is larger for magnetic flux between one-half and one flux quantum. Besides, a perfect absorber (PA) can be realized based on the UPA, in which light waves from both sides, with arbitrary superposition of the ampli- tude and phase, are perfectly absorbed. The UPA is expected to be useful in the design of novel optical devices. PMID:27615125
Unidirectional perfect absorber
NASA Astrophysics Data System (ADS)
Jin, L.; Wang, P.; Song, Z.
2016-09-01
This study proposes a unidirectional perfect absorber (UPA), which we realized with a two-arm Aharonov-Bohm interferometer, that consists of a dissipative resonator side-coupled to a uniform resonator array. The UPA has reflection-less full absorption on one direction, and reflectionless full transmission on the other, with an appropriate magnetic flux and coupling, detuning, and loss of the side-coupled resonator. The magnetic flux controls the transmission, the left transmission is larger for magnetic flux less than one-half flux quantum; and the right transmission is larger for magnetic flux between one-half and one flux quantum. Besides, a perfect absorber (PA) can be realized based on the UPA, in which light waves from both sides, with arbitrary superposition of the ampli- tude and phase, are perfectly absorbed. The UPA is expected to be useful in the design of novel optical devices.
Unidirectional perfect absorber.
Jin, L; Wang, P; Song, Z
2016-01-01
This study proposes a unidirectional perfect absorber (UPA), which we realized with a two-arm Aharonov-Bohm interferometer, that consists of a dissipative resonator side-coupled to a uniform resonator array. The UPA has reflection-less full absorption on one direction, and reflectionless full transmission on the other, with an appropriate magnetic flux and coupling, detuning, and loss of the side-coupled resonator. The magnetic flux controls the transmission, the left transmission is larger for magnetic flux less than one-half flux quantum; and the right transmission is larger for magnetic flux between one-half and one flux quantum. Besides, a perfect absorber (PA) can be realized based on the UPA, in which light waves from both sides, with arbitrary superposition of the ampli- tude and phase, are perfectly absorbed. The UPA is expected to be useful in the design of novel optical devices. PMID:27615125
Unidirectional perfect absorber.
Jin, L; Wang, P; Song, Z
2016-09-12
This study proposes a unidirectional perfect absorber (UPA), which we realized with a two-arm Aharonov-Bohm interferometer, that consists of a dissipative resonator side-coupled to a uniform resonator array. The UPA has reflection-less full absorption on one direction, and reflectionless full transmission on the other, with an appropriate magnetic flux and coupling, detuning, and loss of the side-coupled resonator. The magnetic flux controls the transmission, the left transmission is larger for magnetic flux less than one-half flux quantum; and the right transmission is larger for magnetic flux between one-half and one flux quantum. Besides, a perfect absorber (PA) can be realized based on the UPA, in which light waves from both sides, with arbitrary superposition of the ampli- tude and phase, are perfectly absorbed. The UPA is expected to be useful in the design of novel optical devices.
Phase diagram of the ground states of DNA condensates
NASA Astrophysics Data System (ADS)
Hoang, Trinh X.; Trinh, Hoa Lan; Giacometti, Achille; Podgornik, Rudolf; Banavar, Jayanth R.; Maritan, Amos
2015-12-01
The phase diagram of the ground states of DNA in a bad solvent is studied for a semiflexible polymer model with a generalized local elastic bending potential characterized by a nonlinearity parameter x and effective self-attraction promoting compaction. x =1 corresponds to the wormlike chain model. Surprisingly, the phase diagram as well as the transition lines between the ground states are found to be a function of x . The model provides a simple explanation for the results of prior experimental and computational studies and makes predictions for the specific geometries of the ground states. The results underscore the impact of the form of the microscopic bending energy at macroscopic observable scales.
Quantum phase estimation for nonlinear phase shifts with entangled spin coherent states of two modes
NASA Astrophysics Data System (ADS)
Berrada, K.; Abdel Khalek, S.
2013-10-01
Recently, we presented (Berrada K, Abdel-Khalek S and Raymond Ooi C H 2012 Phys. Rev. A 86 033823) an improved phase estimation scheme employing entangled spin coherent states (ESCSs) using the Holstein-Primakoff realization of angular momentum algebra. Here, we study the nonlinear phase enhancement from a generalized nonlinearity on ESCSs under perfect and lossy conditions with the same mean photon number and nonlinearity order. The results show that an increase in the spin number gives the smallest variance in the phase parameter in comparison to N00N states for different orders of nonlinearity. Finally, we study the physical properties of the input optical field and explore a connection between this quantity and the output state phase uncertainty. In particular, we show that the Mandel parameter may be used as an indicator of the phase estimation behavior in this interferometric setting.
Edge states and phase diagram for graphene under polarized light
Wang, Yi -Xiang; Li, Fuxiang
2016-03-22
In this paper, we investigate the topological phase transitions in graphene under the modulation of circularly polarized light, by analyzing the changes of edge states and its topological structures. A full phase diagram, with several different topological phases, is presented in the parameter space spanned by the driving frequency and light strength. We find that the high-Chern number behavior is very common in the driven system. While the one-photon resonance can create the chiral edge states in the π-gap, the two-photon resonance will induce the counter-propagating edge modes in the zero-energy gap. When the driving light strength is strong, themore » number and even the chirality of the edge states may change in the π-gap. The robustness of the edge states to disorder potential is also examined. We close by discussing the feasibility of experimental proposals.« less
Edge states and phase diagram for graphene under polarized light
NASA Astrophysics Data System (ADS)
Wang, Yi-Xiang; Li, Fuxiang
2016-07-01
In this work, we investigate the topological phase transitions in graphene under the modulation of circularly polarized light, by analyzing the changes of edge states and its topological structures. A full phase diagram, with several different topological phases, is presented in the parameter space spanned by the driving frequency and light strength. We find that the high-Chern number behavior is very common in the driven system. While the one-photon resonance can create the chiral edge states in the π-gap, the two-photon resonance will induce the counter-propagating edge modes in the zero-energy gap. When the driving light strength is strong, the number and even the chirality of the edge states may change in the π-gap. The robustness of the edge states to disorder potential is also examined. We close by discussing the feasibility of experimental proposals.
Persistent chimera states in nonlocally coupled phase oscillators
NASA Astrophysics Data System (ADS)
Suda, Yusuke; Okuda, Koji
2015-12-01
Chimera states in the systems of nonlocally coupled phase oscillators are considered stable in the continuous limit of spatially distributed oscillators. However, it is reported that in the numerical simulations without taking such limit, chimera states are chaotic transient and finally collapse into the completely synchronous solution. In this Rapid Communication, we numerically study chimera states by using the coupling function different from the previous studies and obtain the result that chimera states can be stable even without taking the continuous limit, which we call the persistent chimera state.
Persistent chimera states in nonlocally coupled phase oscillators.
Suda, Yusuke; Okuda, Koji
2015-12-01
Chimera states in the systems of nonlocally coupled phase oscillators are considered stable in the continuous limit of spatially distributed oscillators. However, it is reported that in the numerical simulations without taking such limit, chimera states are chaotic transient and finally collapse into the completely synchronous solution. In this Rapid Communication, we numerically study chimera states by using the coupling function different from the previous studies and obtain the result that chimera states can be stable even without taking the continuous limit, which we call the persistent chimera state.
State-of-the-art review of phase equilibria
Prausnitz, J.M.
1980-03-01
High-pressure phase-equilibrium calculations using an equation of state are more sensitive to the mixing rules than to details in the effect of density or temperature on pressure. Attention must be given to the problem of how to extend equations of state to mixtures. One possible technique is provided by perturbation theory; another by superposition of chemical equilibria. At low or moderate pressures, vapor-phase corrections are often important. When specific intermolecular forces produce formation of molecular aggregates, strong deviations from ideal-gas behavior can be significant even at pressures well below 1 bar. When vapor-liquid equilibrium data are reduced using conventional expressions for the excess Gibbs energy, the resulting binary parameters tend to be partially correlated, it difficult, but no impossible, to calculate ternary liquid-liquid equilibria using binary parameters only. New models for calculating properties of liquid-phase mixtures mist allow for changes in free volume to give consideration to the effect of mixing on changes in rotational and vibrational degrees of freedom. Liquid-phase volumetric effects are also important in describing the solubilities of gases in solvent mixtures. Therefore, future liquid-phase models should incorporate a liquid-phase equation of state, either of the van der Waals type or, perhaps, as given by the direct-correlation function theory of liquids.
Efficient computations of quantum canonical Gibbs state in phase space
NASA Astrophysics Data System (ADS)
Bondar, Denys I.; Campos, Andre G.; Cabrera, Renan; Rabitz, Herschel A.
2016-06-01
The Gibbs canonical state, as a maximum entropy density matrix, represents a quantum system in equilibrium with a thermostat. This state plays an essential role in thermodynamics and serves as the initial condition for nonequilibrium dynamical simulations. We solve a long standing problem for computing the Gibbs state Wigner function with nearly machine accuracy by solving the Bloch equation directly in the phase space. Furthermore, the algorithms are provided yielding high quality Wigner distributions for pure stationary states as well as for Thomas-Fermi and Bose-Einstein distributions. The developed numerical methods furnish a long-sought efficient computation framework for nonequilibrium quantum simulations directly in the Wigner representation.
Efficient computations of quantum canonical Gibbs state in phase space.
Bondar, Denys I; Campos, Andre G; Cabrera, Renan; Rabitz, Herschel A
2016-06-01
The Gibbs canonical state, as a maximum entropy density matrix, represents a quantum system in equilibrium with a thermostat. This state plays an essential role in thermodynamics and serves as the initial condition for nonequilibrium dynamical simulations. We solve a long standing problem for computing the Gibbs state Wigner function with nearly machine accuracy by solving the Bloch equation directly in the phase space. Furthermore, the algorithms are provided yielding high quality Wigner distributions for pure stationary states as well as for Thomas-Fermi and Bose-Einstein distributions. The developed numerical methods furnish a long-sought efficient computation framework for nonequilibrium quantum simulations directly in the Wigner representation. PMID:27415384
Emerging single-phase state in small manganite nanodisks.
Shao, Jian; Liu, Hao; Zhang, Kai; Yu, Yang; Yu, Weichao; Lin, Hanxuan; Niu, Jiebin; Du, Kai; Kou, Yunfang; Wei, Wengang; Lan, Fanli; Zhu, Yinyan; Wang, Wenbin; Xiao, Jiang; Yin, Lifeng; Plummer, E W; Shen, Jian
2016-08-16
In complex oxides systems such as manganites, electronic phase separation (EPS), a consequence of strong electronic correlations, dictates the exotic electrical and magnetic properties of these materials. A fundamental yet unresolved issue is how EPS responds to spatial confinement; will EPS just scale with size of an object, or will the one of the phases be pinned? Understanding this behavior is critical for future oxides electronics and spintronics because scaling down of the system is unavoidable for these applications. In this work, we use La0.325Pr0.3Ca0.375MnO3 (LPCMO) single crystalline disks to study the effect of spatial confinement on EPS. The EPS state featuring coexistence of ferromagnetic metallic and charge order insulating phases appears to be the low-temperature ground state in bulk, thin films, and large disks, a previously unidentified ground state (i.e., a single ferromagnetic phase state emerges in smaller disks). The critical size is between 500 nm and 800 nm, which is similar to the characteristic length scale of EPS in the LPCMO system. The ability to create a pure ferromagnetic phase in manganite nanodisks is highly desirable for spintronic applications. PMID:27482108
Emerging single-phase state in small manganite nanodisks
NASA Astrophysics Data System (ADS)
Shao, Jian; Liu, Hao; Zhang, Kai; Yu, Yang; Yu, Weichao; Lin, Hanxuan; Niu, Jiebin; Du, Kai; Kou, Yunfang; Wei, Wengang; Lan, Fanli; Zhu, Yinyan; Wang, Wenbin; Xiao, Jiang; Yin, Lifeng; Plummer, E. W.; Shen, Jian
2016-08-01
In complex oxides systems such as manganites, electronic phase separation (EPS), a consequence of strong electronic correlations, dictates the exotic electrical and magnetic properties of these materials. A fundamental yet unresolved issue is how EPS responds to spatial confinement; will EPS just scale with size of an object, or will the one of the phases be pinned? Understanding this behavior is critical for future oxides electronics and spintronics because scaling down of the system is unavoidable for these applications. In this work, we use La0.325Pr0.3Ca0.375MnO3 (LPCMO) single crystalline disks to study the effect of spatial confinement on EPS. The EPS state featuring coexistence of ferromagnetic metallic and charge order insulating phases appears to be the low-temperature ground state in bulk, thin films, and large disks, a previously unidentified ground state (i.e., a single ferromagnetic phase state emerges in smaller disks). The critical size is between 500 nm and 800 nm, which is similar to the characteristic length scale of EPS in the LPCMO system. The ability to create a pure ferromagnetic phase in manganite nanodisks is highly desirable for spintronic applications.
Emerging single-phase state in small manganite nanodisks
Shao, Jian; Liu, Hao; Zhang, Kai; Yu, Yang; Yu, Weichao; Lin, Hanxuan; Niu, Jiebin; Du, Kai; Kou, Yunfang; Wei, Wengang; Lan, Fanli; Zhu, Yinyan; Wang, Wenbin; Xiao, Jiang; Yin, Lifeng; Plummer, E. W.; Shen, Jian
2016-01-01
In complex oxides systems such as manganites, electronic phase separation (EPS), a consequence of strong electronic correlations, dictates the exotic electrical and magnetic properties of these materials. A fundamental yet unresolved issue is how EPS responds to spatial confinement; will EPS just scale with size of an object, or will the one of the phases be pinned? Understanding this behavior is critical for future oxides electronics and spintronics because scaling down of the system is unavoidable for these applications. In this work, we use La0.325Pr0.3Ca0.375MnO3 (LPCMO) single crystalline disks to study the effect of spatial confinement on EPS. The EPS state featuring coexistence of ferromagnetic metallic and charge order insulating phases appears to be the low-temperature ground state in bulk, thin films, and large disks, a previously unidentified ground state (i.e., a single ferromagnetic phase state emerges in smaller disks). The critical size is between 500 nm and 800 nm, which is similar to the characteristic length scale of EPS in the LPCMO system. The ability to create a pure ferromagnetic phase in manganite nanodisks is highly desirable for spintronic applications. PMID:27482108
Ying, Rongjian
2015-01-01
A kind of Sr2+ selective resin was applied as an absorption phase to extract Sr2+ ion from an aqueous solution, and the amount of Sr2+ was determined using inductively coupled plasma optical emission spectrometer. Factors, including absorption time, temperature, stirring rate, salt-out effect, desorption, and the pH of the aqueous solution, were investigated to optimize the absorption efficiency of Sr2+. Foreign ions were examined to observe their effects on the absorption behavior of Sr2+. The optimum condition was absorption time at 20 min, pH of aqueous solution 7, temperature of 35°C, and 600 rpm stirring rate. A 10 mL solution of 0.1 mol/L HCl is used as the desorption agent. The linear range of Sr2+ concentrations from 50 to 1200 μg/L was investigated with the slope of 183 μg/L. The limit of detection was 21 μg/L with 4.23% relative standard deviation. The correlation coefficient was found to be 0.9947. Under the optimized conditions, the concentrations of Sr2+ in four water samples were detected by the developed method. We propose that this method effectively extracts strontium ion from environmental water samples. PMID:26640489
Doorway states in the random-phase approximation
De Pace, A.; Molinari, A.; Weidenmüller, H.A.
2014-12-15
By coupling a doorway state to a sea of random background states, we develop the theory of doorway states in the framework of the random-phase approximation (RPA). Because of the symmetry of the RPA equations, that theory is radically different from the standard description of doorway states in the shell model. We derive the Pastur equation in the limit of large matrix dimension and show that the results agree with those of matrix diagonalization in large spaces. The complexity of the Pastur equation does not allow for an analytical approach that would approximately describe the doorway state. Our numerical results display unexpected features: The coupling of the doorway state with states of opposite energy leads to strong mutual attraction.
Topological phase states of the SU(3) QCD
NASA Astrophysics Data System (ADS)
Protogenov, Alexander P.; Chulkov, Evgueni V.; Teo, Jeffrey C. Y.
2014-03-01
We consider the topologically nontrivial phase states and the corresponding topological defects in the SU(3) d-dimensional quantum chromodynamics (QCD). The homotopy groups for topological classes of such defects are calculated explicitly. We have shown that the three nontrivial groups are π3SU(3) = Bbb Z, π5SU(3) = Bbb Z, and π6SU(3) = Bbb Z6 if 3 <= d <= 6. The latter result means that we are dealing exactly with six topologically different phase states. The topological invariants for d=3,5,6 are described in detail.
Accelerated Superposition State Molecular Dynamics for Condensed Phase Systems.
Ceotto, Michele; Ayton, Gary S; Voth, Gregory A
2008-04-01
An extension of superposition state molecular dynamics (SSMD) [Venkatnathan and Voth J. Chem. Theory Comput. 2005, 1, 36] is presented with the goal to accelerate timescales and enable the study of "long-time" phenomena for condensed phase systems. It does not require any a priori knowledge about final and transition state configurations, or specific topologies. The system is induced to explore new configurations by virtue of a fictitious (free-particle-like) accelerating potential. The acceleration method can be applied to all degrees of freedom in the system and can be applied to condensed phases and fluids. PMID:26620930
Excited-state quantum phase transition in the Rabi model
NASA Astrophysics Data System (ADS)
Puebla, Ricardo; Hwang, Myung-Joong; Plenio, Martin B.
2016-08-01
The Rabi model, a two-level atom coupled to a harmonic oscillator, can undergo a second-order quantum phase transition (QPT) [M.-J. Hwang et al., Phys. Rev. Lett. 115, 180404 (2015), 10.1103/PhysRevLett.115.180404]. Here we show that the Rabi QPT accompanies critical behavior in the higher-energy excited states, i.e., the excited-state QPT (ESQPT). We derive analytic expressions for the semiclassical density of states, which show a logarithmic divergence at a critical energy eigenvalue in the broken symmetry (superradiant) phase. Moreover, we find that the logarithmic singularities in the density of states lead to singularities in the relevant observables in the system such as photon number and atomic polarization. We corroborate our analytical semiclassical prediction of the ESQPT in the Rabi model with its numerically exact quantum mechanical solution.
NASA Astrophysics Data System (ADS)
Decreton, A.; Benigni, P.; Rogez, J.; Mikaelian, G.; Barrachin, M.; Lomello-Tafin, M.; Antion, C.; Janghorban, A.; Fischer, E.
2015-10-01
Most pressurized water reactor (PWR) absorber rods are composed of an Ag-In-Cd (SIC) alloy inside a stainless steel (SS) cladding, themselves inserted into a Zircaloy tube. During a severe accident, the SIC alloy which melts at 800 °C does not practically interact with SS. However, the cladding failure results from its internal pressurization and its eutectic interaction with Zircaloy and occurs at temperatures greater than 1200 °C. The subsequent interaction between the SIC melt and the Zircaloy has a strong impact on the quantities of aerosols released into the primary circuit and finally on the iodine chemistry. Accurate knowledge of the Ag-Zr system is a prerequisite to address this issue. Within this concern, our experimental work is focused both on the investigation of the Ag-Zr phase diagram and on the determination of the thermodynamic properties of the intermetallic compounds in the system. Two intermetallic compounds (AgZr and AgZr2) were identified. Ag-Zr cast alloys with a Ag/Zr ratio of 1:1 elaborated using an arc-melting furnace, once annealed, contained only a single phase AgZr. From metallographic observations, it appears that AgZr2 likely forms by the peritectic reaction from liquid and the bcc (βZr) phase. The partial enthalpies of solution of silver and zirconium in aluminum were experimentally determined at 723 °C in order to determine the enthalpies of formation of the intermetallic compounds. For silver solution calorimetry in aluminum bath, our measurements were successful and in agreement with the previous data. Yet, this study shows that liquid aluminum should not be used as a solvent for zirconium below 1000 °C.
NASA Astrophysics Data System (ADS)
Ouyang, Bing; Xue, Jia-Dan; Zheng, Xuming; Fang, Wei-Hai
2014-05-01
The excited state structural dynamics of phenyl isothiocyanate (PITC) after excitation to the light absorbing S2(A'), S6(A'), and S7(A') excited states were studied by using the resonance Raman spectroscopy and complete active space self-consistent field method calculations. The UV absorption bands of PITC were assigned. The vibrational assignments were done on the basis of the Fourier transform (FT)-Raman and FT-infrared measurements, the density-functional theory computations, and the normal mode analysis. The A-, B-, and C-bands resonance Raman spectra in cyclohexane, acetonitrile, and methanol solvents were, respectively, obtained at 299.1, 282.4, 266.0, 252.7, 228.7, 217.8, and 208.8 nm excitation wavelengths to probe the corresponding structural dynamics of PITC. The results indicated that the structural dynamics in the S2(A'), S6(A'), and S7(A') excited states were very different. The conical intersection point CI(S2/S1) were predicted to play important role in the low-lying excited state decay dynamics. Two major decay channels were predicted for PITC upon excitation to the S2(A') state: the radiative S2,min → S0 transition and the nonradiative S2 → S1 internal conversion via CI(S2/S1). The differences in the decay dynamics between methyl isothiocyanate and PITC in the first light absorbing excited state were discussed. The role of the intersystem crossing point ISC(S1/T1) in the excited state decay dynamics of PITC is evaluated.
Ouyang, Bing Xue, Jia-Dan Zheng, Xuming E-mail: zxm@zstu.edu.cn; Fang, Wei-Hai E-mail: fangwh@dnu.edu.cn
2014-05-21
The excited state structural dynamics of phenyl isothiocyanate (PITC) after excitation to the light absorbing S{sub 2}(A′), S{sub 6}(A′), and S{sub 7}(A′) excited states were studied by using the resonance Raman spectroscopy and complete active space self-consistent field method calculations. The UV absorption bands of PITC were assigned. The vibrational assignments were done on the basis of the Fourier transform (FT)-Raman and FT-infrared measurements, the density-functional theory computations, and the normal mode analysis. The A-, B-, and C-bands resonance Raman spectra in cyclohexane, acetonitrile, and methanol solvents were, respectively, obtained at 299.1, 282.4, 266.0, 252.7, 228.7, 217.8, and 208.8 nm excitation wavelengths to probe the corresponding structural dynamics of PITC. The results indicated that the structural dynamics in the S{sub 2}(A′), S{sub 6}(A′), and S{sub 7}(A′) excited states were very different. The conical intersection point CI(S{sub 2}/S{sub 1}) were predicted to play important role in the low-lying excited state decay dynamics. Two major decay channels were predicted for PITC upon excitation to the S{sub 2}(A′) state: the radiative S{sub 2,min} → S{sub 0} transition and the nonradiative S{sub 2} → S{sub 1} internal conversion via CI(S{sub 2}/S{sub 1}). The differences in the decay dynamics between methyl isothiocyanate and PITC in the first light absorbing excited state were discussed. The role of the intersystem crossing point ISC(S{sub 1}/T{sub 1}) in the excited state decay dynamics of PITC is evaluated.
Excited-state quantum phase transitions in Dicke superradiance models.
Brandes, Tobias
2013-09-01
We derive analytical results for various quantities related to the excited-state quantum phase transitions in a class of Dicke superradiance models in the semiclassical limit. Based on a calculation of a partition sum restricted to Dicke states, we discuss the singular behavior of the derivative of the density of states and find observables such as the mean (atomic) inversion and the boson (photon) number and its fluctuations at arbitrary energies. Criticality depends on energy and a parameter that quantifies the relative weight of rotating versus counterrotating terms, and we find a close analogy to the logarithmic and jump-type nonanalyticities known from the Lipkin-Meshkov-Glick model. PMID:24125239
Hydrogen bond symmetrization and equation of state of phase D
Hushur, Anwar; Manghnani, Murli H.; Smyth, Joseph R.; Williams, Quentin; Hellebrand, Eric; Lonappan, Dayana; Ye, Yu; Dera, Przemyslaw; Frost, Daniel J.
2012-10-09
We have synthesized phase D at 24 GPa and at temperatures of 1250-1100 C in a multianvil press under conditions of high silica activity. The compressibility of this high-silica-activity phase D (Mg{sub 1.0}Si{sub 1.7}H{sub 3.0}O{sub 6}) has been measured up to 55.8 GPa at ambient temperature by powder X-ray diffraction. The volume (V) decreases smoothly with increasing pressure up to 40 GPa, consistent with the results reported in earlier studies. However, a kink is observed in the trend of V versus pressure above {approx}40 GPa, reflecting a change in the compression behavior. The data to 30 GPa fit well to a third-order Birch-Murnaghan equation of state (EoS), yielding V{sub o} = 85.1 {+-} 0.2 {angstrom}{sup 3}; K{sub o} = 167.9 {+-} 8.6 GPa; and K{prime}{sub o} = 4.3 {+-} 0.5, similar to results for Fe-Al-free phase D reported by Frost and Fei (1999). However, these parameters are larger than those reported for Fe-Al-bearing phase D and for Fe-Al-free phase D. The abnormal volume change in this study may be attributed to the reported hydrogen bond symmetrization in phase D. Fitting a third-order Birch-Murnaghan EoS to the data below 30 GPa yields a bulk modulus K{sub o} = 173 (2) GPa for the hydrogen-off-centered (HOC) phase and K{sub o} = 212 (15) GPa for the data above 40 GPa for the hydrogen-centered (HC) phase, assuming K{prime}{sub o} is 4. The calculated bulk modulus K{sub o} of the HC phase is 18% larger than the bulk modulus K{sub o} of the HOC phase.
Strain glass state as the boundary of two phase transitions
Zhou, Zhijian; Cui, Jian; Ren, Xiaobing
2015-01-01
A strain glass state was found to be located between B2-B19’ (cubic to monoclinic) phase transition and B2-R (cubic to rhombohedral) phase transition in Ti49Ni51 alloys after aging process. After a short time aging, strong strain glass transition was observed, because the size of the precipitates is small, which means the strain field induced by the precipitates is isotropic and point-defect-like, and the distribution of the precipitates is random. After a long time aging, the average size of the precipitates increases. The strong strain field induced by the precipitates around them forces the symmetry of the matrix materials to conform to the symmetry of the crystalline structure of the precipitates, which results in the new phase transition. The experiment shows that there exists no well-defined boundary in the evolution from the strain glass transition to the new phase transition. Due to its generality, this glass mediated phase transition divergence scheme can be applied to other proper material systems to induce a more important new phase transition path, which can be useful in the field of phase transition engineering. PMID:26307500
All solid-state SBS phase conjugate mirror
Dane, C.B.; Hackel, L.A.
1999-03-09
A stimulated Brillouin scattering (SBS) phase conjugate laser mirror uses a solid-state nonlinear gain medium instead of the conventional liquid or high pressure gas medium. The concept has been effectively demonstrated using common optical-grade fused silica. An energy threshold of 2.5 mJ and a slope efficiency of over 90% were achieved, resulting in an overall energy reflectivity of >80% for 15 ns, 1 um laser pulses. The use of solid-state materials is enabled by a multi-pass resonant architecture which suppresses transient fluctuations that would otherwise result in damage to the SBS medium. This all solid state phase conjugator is safer, more reliable, and more easily manufactured than prior art designs. It allows nonlinear wavefront correction to be implemented in industrial and defense laser systems whose operating environments would preclude the introduction of potentially hazardous liquids or high pressure gases. 8 figs.
All solid-state SBS phase conjugate mirror
Dane, Clifford B.; Hackel, Lloyd A.
1999-01-01
A stimulated Brillouin scattering (SBS) phase conjugate laser mirror uses a solid-state nonlinear gain medium instead of the conventional liquid or high pressure gas medium. The concept has been effectively demonstrated using common optical-grade fused silica. An energy threshold of 2.5 mJ and a slope efficiency of over 90% were achieved, resulting in an overall energy reflectivity of >80% for 15 ns, 1 um laser pulses. The use of solid-state materials is enabled by a multi-pass resonant architecture which suppresses transient fluctuations that would otherwise result in damage to the SBS medium. This all solid state phase conjugator is safer, more reliable, and more easily manufactured than prior art designs. It allows nonlinear wavefront correction to be implemented in industrial and defense laser systems whose operating environments would preclude the introduction of potentially hazardous liquids or high pressure gases.
Classification scheme of pure multipartite states based on topological phases
NASA Astrophysics Data System (ADS)
Johansson, Markus; Ericsson, Marie; Sjöqvist, Erik; Osterloh, Andreas
2014-01-01
We investigate the connection between the concept of affine balancedness (a-balancedness) introduced by M. Johansson et al. [Phys. Rev. A 85, 032112 (2012), 10.1103/PhysRevA.85.032112] and polynomial local SU invariants and the appearance of topological phases, respectively. It is found that different types of a-balancedness correspond to different types of local SU invariants analogously to how different types of balancedness, as defined by A. Osterloh and J. Siewert, [New J. Phys. 12, 075025 (2010), 10.1088/1367-2630/12/7/075025], correspond to different types of local special linear (SL) invariants. These different types of SU invariants distinguish between states exhibiting different topological phases. In the case of three qubits, the different kinds of topological phases are fully distinguished by the three-tangle together with one more invariant. Using this, we present a qualitative classification scheme based on balancedness of a state. While balancedness and local SL invariants of bidegree (2n,0) classify the SL-semistable states [A. Osterloh and J. Siewert, New J. Phys. 12, 075025 (2010), 10.1088/1367-2630/12/7/075025; O. Viehmann et al., Phys. Rev. A 83, 052330 (2011), 10.1103/PhysRevA.83.052330], a-balancedness and local SU invariants of bidegree (2n-m,m) give a more fine-grained classification. In this scheme, the a-balanced states form a bridge from the genuine entanglement of balanced states, invariant under the SL group, towards the entanglement of unbalanced states characterized by U invariants of bidegree (n,n). As a byproduct, we obtain generalizations to the W state, i.e., states that are entangled, but contain only globally distributed entanglement of parts of the system.
Kikuchi, Azusa; Shibata, Kenji; Kumasaka, Ryo; Yagi, Mikio
2013-02-21
The excited states of UV-B absorber (4-methylbenzylidene)camphor (MBC) have been studied through measurements of UV absorption, phosphorescence, triplet-triplet (T-T) absorption, and steady-state and time-resolved electron paramagnetic resonance spectra in ethanol. The energy level and lifetime of the lowest excited triplet (T(1)) state of MBC were determined. The energy level of the T(1) state of MBC is much lower than that of photolabile 4-tert-butyl-4'-methoxydibenzoylmethane. The weak phosphorescence and strong time-resolved EPR signals, and T-T absorption band of MBC were observed. These facts suggest that the significant proportion of the lowest excited singlet (S(1)) molecules undergoes intersystem crossing to the T(1) state and the deactivation process from the T(1) state is predominantly radiationless. The quantum yields of singlet oxygen production by MBC determined by time-resolved near-IR luminescence measurements are 0.05 ± 0.01 and 0.06 ± 0.01 in ethanol and in acetonitrile, respectively. The photostability of MBC arises from the (3)ππ* character in the T(1) state. The zero-field splitting parameters in the T(1) state are D = 0.0901 cm(-1) and E = -0.0498 cm(-1). The sublevel preferentially populated by intersystem crossing is T(y) (y close to in-plane short axis and to the C═O direction). PMID:23320917
A method to resolve the phase state of aerosol particles
NASA Astrophysics Data System (ADS)
Saukko, E.; Kuuluvainen, H.; Virtanen, A.
2012-01-01
The phase state of atmospheric aerosols has an impact on their chemical aging and their deliquescence and thus their ability to act as cloud condensation nuclei (CCN). The phase change of particles can be induced by the deliquescence or efflorescence of water or by chemical aging. Existing methods, such as tandem differential mobility analysis rely on the size change of particles related to the water uptake or release. To address the need to study the phase change induced by mass-preserving and nearly mass-preserving processes a new method has been developed. The method relies on the physical impaction of particles on a smooth substrate and subsequent counting of bounced particles by a condensation particle counter (CPC). The connection between the bounce probability and physical properties of particles is so far qualitative. To evaluate the performance of this method, the phase state of ammonium sulfate and levoglucosan, crystalline and amorphous solid, in the presence of water vapor was studied. The results show a marked difference in particle bouncing properties between substances - not only at the critical relative humidity level, but also on the slope of the bouncing probability with respect to humidity. This suggests that the method can be used to differentiate between amorphous and crystalline substances as well as to differentiate between liquid and solid phases.
A method to resolve the phase state of aerosol particles
NASA Astrophysics Data System (ADS)
Saukko, E.; Kuuluvainen, H.; Virtanen, A.
2011-10-01
The phase state of atmospheric aerosols has impact on their chemical aging and their deliquescence and thus their ability to act as cloud condensation nuclei (CCN). The phase change of particles can be induced by the deliquescence or efflorescence of water or by chemical aging. Existing methods, such as tandem differential mobility analysis rely on the size change of particles related to the water uptake or release related to deliquescence and efflorescence. To address the need to study the phase change induced by mass-preserving and nearly mass-preserving processes a new method has been developed. The method relies on the physical impaction of particles on a smooth substrate and subsequent counting of bounced particles by condensation particle counter (CPC). The connection between the bounce probability and physical properties of particles is so far qualitative. To evaluate the performance of this method, the phase state of ammonium sulfate and levoglucosan, crystalline and amorphous solid, in the presence of water vapor was studied. The results show a marked difference in particle bouncing properties between substances - not only at the critical relative humidity level, but also on the slope of the bouncing probability with respect to humidity. This suggests that the method can be used to differentiate between amorphous and crystalline substances as well as to differentiate between liquid and solid phases.
Dispersion cancellation with phase-sensitive Gaussian-state light
Shapiro, Jeffrey H.
2010-02-15
Franson's paradigm for nonlocal dispersion cancellation [J. D. Franson, Phys. Rev. A 45, 3126 (1992)] is studied using two kinds of jointly Gaussian-state signal and reference beams with phase-sensitive cross correlations. The first joint signal-reference state is nonclassical, with a phase-sensitive cross correlation that is at the ultimate quantum-mechanical limit. It models the outputs obtained from continuous-wave spontaneous parametric down-conversion. The second joint signal-reference state is classical--it has a proper P representation--with a phase-sensitive cross correlation that is at the limit set by classical physics. Using these states we show that a version of Franson's nonlocal dispersion cancellation configuration has essentially identical quantum and classical explanations except for the contrast obtained, which is much higher in the quantum case than it is in the classical case. This work bears on Franson's recent article [J. D. Franson, Phys. Rev. A 80, 032119 (2009)], which asserts that there is no classical explanation for all the features seen in quantum nonlocal dispersion cancellation.
NASA Astrophysics Data System (ADS)
Pradhan, R.; Saha, S.; Datta, P. K.
2013-01-01
Round-trip phase-shifts with intensity of an input signal due to saturable index change and optically induced thermal effects in a vertical cavity semiconductor (quantum wells) saturable absorber (VCSSA) are investigated analytically to observe counter-clockwise bi-stability in transmission mode and clockwise bi-stability in reflection mode. Simultaneous effects of Kerr nonlinearity and cavity heating on resonance wavelength-shift of the VCSSA micro-cavity are investigated. It is found that these bi-stable characteristics are possible to the absorption edge of nonlinear material for long wavelength side operations of low intensity resonance wavelength of the micro-cavity, where dispersion of absorption and refraction are neglected over a small range of optical wavelength tuning (δλ˜10 nm). Simulations are carried out to find out optimized parameters of the device for bi-stable characteristics. Operations are demonstrated for InGaAs/InP quantum wells based VCSSA with low intensity resonance wavelength of 1570 nm. For counter-clockwise bi-stable switching at working wavelength of 1581 nm, an input intensity variation of 0.79IS is required with top (Rt) and back DBR reflectivity (Rb) of 91% and 93%, respectively, where IS represents the absorption saturation intensity of nonlinear medium. Whereas, the clockwise bi-stability occurs at 0.22IS for working wavelength of 1578 nm with Rt of 90% and Rb of 98%, respectively.
Sebesta, F.; John, J.; Motl, A.
1996-05-01
The performance of PAN-based composite absorbers was evaluated in dynamic experiments at flow rates ranging from 25--100 bed volumes (BV) per hour. Composite absorbers with active components of ammonium molybdophosphate (AMP) PAN and K-Co ferrocyanide (KCoFC) PAN were used for separating Cs from a 1 M HNO{sub 3} + 1 M NaNO{sub 3} + 2 {times} 10{sup {minus}5} M CsCl acidic simulant solution. KCoFC-PAN and two other FC-based composite absorbers were tested for separating Cs from alkaline simulant solutions containing 0.01 M to 1 M NaOH and 1 M NaNO{sub 3} + x {times} 10{sup {minus}4} M CsCl. The efficiency of the Cs sorption on the AMP-PAN absorber from acidic simulant solutions was negatively influenced by the dissolution of the AMP active component. At flow rates of 50 BV/hr, the decontamination factor of about 10{sup 3} could be maintained for treatment of 380 BV of the feed. With the KCoFC-PAN absorber, the decontamination factor of about 10{sup 3} could be maintained for a feed volume as great as 1,800 BV. In alkaline simulant solutions, significant decomposition of the active components was observed, and the best performance was exhibited by the KCoFC-PAN absorber. Introductory experiments confirmed that Cs may be washed out of the composite absorbers. Regeneration of both absorbers for repetitive use was also found to be possible. The main result of the study is that PAN was proven to be a versatile polymer capable of forming porous composite absorbers with a large number of primary absorbers. The composite absorbers proved to be capable of withstanding the harsh acidic and alkaline conditions and significant radiation doses that may be expected in the treatment of US DOE wastes. A field demonstration is proposed as a follow-on activity.
Solid State NMR Studies of the Aluminum Hydride Phases
NASA Technical Reports Server (NTRS)
Hwang, Son-Jong; Bowman, R. C., Jr.; Graetz, Jason; Reilly, J. J.
2006-01-01
Several solid state NMR techniques including magic-angle-spinning (MAS) and multiple-quantum (MQ) MAS experiments have been used to characterize various AlH3 samples. MAS-NMR spectra for the 1H and 27Al nuclei have been obtained on a variety of AlH3 samples that include the (beta)- and (gamma)- phases as well as the most stable (alpha)-phase. While the dominant components in these NMR spectra correspond to the aluminum hydride phases, other species were found that include Al metal, molecular hydrogen (H2), as well as peaks that can be assigned to Al-O species in different configurations. The occurrence and concentration of these extraneous components are dependent upon the initial AlH3 phase composition and preparation procedures. Both the (beta)-AlH3 and (gamma)-AlH3 phases were found to generate substantial amounts of Al metal when the materials were stored at room temperature while the (alpha)-phase materials do not exhibit these changes.
NASA Astrophysics Data System (ADS)
Chyba, David Edward
This dissertation presents new results for the steady states of a detuned ring laser with a saturable absorber. The treatment is based on a semiclassical model which assumes homogeneously broadened two-level atoms. Part 1 presents a solution of the Maxwell-Bloch equations for the longitudinal dependence of the steady states of this system. The solution is then simplified by use of the mean field approximation. Graphical results in the mean field approximation are presented for squared electric field versus operating frequency, and for each of these versus cavity tuning and laser excitation. Various cavity linewidths and both resonant and non-resonant amplifier and absorber line center frequencies are considered. The most notable finding is that cavity detuning breaks the degeneracies previously found in the steady state solutions to the fully tuned case. This lead to the prediction that an actual system will bifurcate from the zero intensity solution to a steady state solution as laser excitation increases from zero, rather than to the small amplitude pulsations found for the model with mathematically exact tuning of the cavity and the media line centers. Other phenomena suggested by the steady state results include tuning-dependent hysteresis and bistability, and instability due to the appearance of another steady state solution. Results for the case in which the media have different line center frequencies suggest non-monotonic behavior of the electric field amplitude as laser excitation varies, as well as hysteresis and bistability. Part 2 presents a formulation of the linearized stability problem for the steady state solutions discussed in the first part. Thus the effects of detuning and the other parameters describing the system is incorporated into the stability analysis. The equations of the system are linearized about both the mean field steady states and about the longitudinally dependent steady states. Expansion in Fourier spatial modes is used in the
Thermodynamics and phase coexistence in nonequilibrium steady states
NASA Astrophysics Data System (ADS)
Dickman, Ronald
2016-09-01
I review recent work focussing on whether thermodynamics can be extended to nonequilibrium steady states (NESS), in particular, the possibility of consistent definitions of temperature T and chemical potential μ for NESS. The testing-grounds are simple lattice models with stochastic dynamics. Each model includes a drive that maintains the system far from equilibrium, provoking particle and/or energy flows; for zero drive the system relaxes to equilibrium. Analysis and numerical simulation show that for spatially uniform NESS, consistent definitions of T and μ are possible via coexistence with an appropriate reservoir, if (and in general only if) a particular kind of rate (that proposed by Sasa and Tasaki) is used for exchanges of particles and energy between systems. The program fails, however, for nonuniform systems. The functions T and μ describing isolated phases cannot be used to predict the properties of coexisting phases in a single, phase-separated system.
Engineering aspects of solid-state phase conjugate lasers
NASA Astrophysics Data System (ADS)
Gregor, Eduard; Mordaunt, David W.; Matthews, Steven C.; Kahan, Osher; Muir, Alexander R.; Palombo, Mario
1992-06-01
An engineering approach for the development of laser hardware that takes advantage of the special properties of phase conjugation is reported. The principal advantages of conjugate solid-state lasers are alignment stability and passive compensation of thermal distortion in a double pass laser amplifier chain. Attention is given to the application of phase conjugation techniques to the design, fabrication, and field testing of an Nd:YAG second harmonic 0.5 Joule, 30 Hertz flashlamp pumped laser in a master oscillator power amplifier configuration. The double pass amplifier featured a phase conjugate mirror and a second harmonic crystal within the amplifier chain. The basic Nd:YAG laser produced a doubling efficiency of 75 percent from 1064 to 532 nm. This output was subsequently used as the source, and a conversion efficiency of 80 percent into six wavelengths in the visible spectrum was obtained using stimulated rotational Raman scattering.
Connection between decoherence and excited state quantum phase transitions
Perez-Fernandez, P.; Arias, J. M.; Relano, A.; Dukelsky, J.; Garcia-Ramos, J. E.
2010-04-26
In this work we explore the relationship between an excited state quantum phase transition (ESQPT) and the phenomenon of quantum decoherence. For this purpose, we study how the decoherence is affected by the presence of a continuous ESQPT in the environment. This one is modeled as a two level boson system described by a Lipkin Hamiltonian. We will show that the decoherence of the system is maximal when the environment undergoes a continuous ESQPT.
Phenomena of solid state grain boundaries phase transition in technology
Minaev, Y. A.
2015-03-30
The results of study the phenomenon, discovered by author (1971), of the phase transition of grain boundary by the formation of two-dimensional liquid or quasi-liquid films have been done. The described phenomena of the first order phase transition (two-dimensional melting) at temperatures 0.6 – 0.9 T{sub S0} (of the solid state melting point) is a fundamental property of solid crystalline materials, which has allowed to revise radically scientific representations about a solid state of substance. Using the mathematical tools of the film thermodynamics it has been obtained the generalized equation of Clausius - Clapeyron type for two-dimensional phase transition. The generalized equation has been used for calculating grain boundary phase transition temperature T{sub Sf} of any metal, which value lies in the range of (0.55…0.86) T{sub S0}. Based on these works conclusions the develop strategies for effective forming of coatings (by thermo-chemical processing) on surface layers of functional alloys and hard metals have been made. The short overview of the results of some graded alloys characterization has been done.
Short-time dynamics of 2-thiouracil in the light absorbing S{sub 2}(ππ{sup ∗}) state
Jiang, Jie; Zhang, Teng-shuo; Xue, Jia-dan; Zheng, Xuming; Cui, Ganglong; Fang, Wei-hai
2015-11-07
Ultrahigh quantum yields of intersystem crossing to the lowest triplet state T{sub 1} are observed for 2-thiouracils (2TU), which is in contrast to the natural uracils that predominantly exhibit ultrafast internal conversion to the ground state upon excitation to the singlet excited state. The intersystem crossing mechanism of 2TU has recently been investigated using second-order perturbation methods with a high-level complete-active space self-consistent field. Three competitive nonadiabatic pathways to the lowest triplet state T{sub 1} from the initially populated singlet excited state S{sub 2} were proposed. We investigate the initial decay dynamics of 2TU from the light absorbing excited states using resonance Raman spectroscopy, time-dependent wave-packet theory in the simple model, and complete-active space self-consistent field (CASSCF) and time dependent-Becke’s three-parameter exchange and correlation functional with the Lee-Yang-Parr correlation functional (TD-B3LYP) calculations. The obtained short-time structural dynamics in easy-to-visualize internal coordinates were compared with the CASSCF(16,11) predicted key nonadiabatic decay routes. Our results indicate that the predominant decay pathway initiated at the Franck-Condon region is toward the S{sub 2}/S{sub 1} conical intersection point and S{sub 2}T{sub 3} intersystem crossing point, but not toward the S{sub 2}T{sub 2} intersystem crossing point.
Li, Linsen; Chen-Wiegart, Yu-chen Karen; Wang, Jiajun; Gao, Peng; Ding, Qi; Yu, Young-Sang; Wang, Feng; Cabana, Jordi; Wang, Jun; Jin, Song
2015-04-20
In situ techniques with high temporal, spatial and chemical resolution are key to understand ubiquitous solid-state phase transformations, which are crucial to many technological applications. Hard X-ray spectro-imaging can visualize electrochemically driven phase transformations but demands considerably large samples with strong absorption signal so far. Here we show a conceptually new data analysis method to enable operando visualization of mechanistically relevant weakly absorbing samples at the nanoscale and study electrochemical reaction dynamics of iron fluoride, a promising high-capacity conversion cathode material. In two specially designed samples with distinctive microstructure and porosity, we observe homogeneous phase transformations during both discharge and charge, faster and more complete Li-storage occurring in porous polycrystalline iron fluoride, and further, incomplete charge reaction following a pathway different from conventional belief. In conclusion, these mechanistic insights provide guidelines for designing better conversion cathode materials to realize the promise of high-capacity lithium-ion batteries.
Li, Linsen; Chen-Wiegart, Yu-chen Karen; Wang, Jiajun; Gao, Peng; Ding, Qi; Yu, Young-Sang; Wang, Feng; Cabana, Jordi; Wang, Jun; Jin, Song
2015-01-01
In situ techniques with high temporal, spatial and chemical resolution are key to understand ubiquitous solid-state phase transformations, which are crucial to many technological applications. Hard X-ray spectro-imaging can visualize electrochemically driven phase transformations but demands considerably large samples with strong absorption signal so far. Here we show a conceptually new data analysis method to enable operando visualization of mechanistically relevant weakly absorbing samples at the nanoscale and study electrochemical reaction dynamics of iron fluoride, a promising high-capacity conversion cathode material. In two specially designed samples with distinctive microstructure and porosity, we observe homogeneous phase transformations during both discharge and charge, faster and more complete Li-storage occurring in porous polycrystalline iron fluoride, and further, incomplete charge reaction following a pathway different from conventional belief. These mechanistic insights provide guidelines for designing better conversion cathode materials to realize the promise of high-capacity lithium-ion batteries. PMID:25892338
NASA Astrophysics Data System (ADS)
Conny, J. M.; Ma, X.; Gunn, L. R.
2011-12-01
Particles with heterogeneously-distributed light-absorbing and light-scattering phases were generated from incomplete combustion or thermal decomposition to mimic real atmospheric particles with distinctive optical properties. Individual particles and particle populations were characterized microscopically. The purpose was to examine how optical property measurements of internally-mixed ambient air particles might vary based on the properties of laboratory-generated particles produced under controlled conditions. The project is an initial stage in producing reference samples for calibrating instrumentation for monitoring climatically-important atmospheric aerosols. Binary-phase particles containing black carbon (BC) and a metal or a metal oxide phase were generated from the thermal decomposition or partial combustion of liquid fuels at a variety of temperatures from 600 °C to 1100 °C. Fuels included mixtures of toluene or isooctane and iron pentacarbonyl or titanium tetrachloride. Scanning electron microscopy with energy-dispersive x-ray spectroscopy revealed that burning the fuels at different temperatures resulted in distinctive differences in morphology and carbon vs. metal/metal oxide composition. Particles from toluene/Fe(CO)5 thermal decomposition exhibited aggregated morphologies that were classified as dendritic, soot-like, globular, or composited (dendritic-globular). Particles from isooctane/TiCl4 combustion were typically spherical with surface adducts or aggregates. Diameters of the BC/TiO2 particles averaged 0.68 μm to 0.70 μm. Regardless of combustion temperature, the most abundant particles in each BC/TiO2 sample had an aspect ratio of 1.2. However, for the 600 °C and 900 °C samples the distribution of aspect ratios was skewed toward much larger ratios suggesting significant chainlike aggregation. Carbon and titanium compositions (wt.) for the 600 °C sample were 12 % and 53 %, respectively. In contrast, the composition trended in the opposite
Phase sensitivity in deformed-state superposition considering nonlinear phase shifts
NASA Astrophysics Data System (ADS)
Berrada, K.
2016-07-01
We study the problem of the phase estimation for the deformation-state superposition (DSS) under perfect and lossy (due to a dissipative interaction of DSS with their environment) regimes. The study is also devoted to the phase enhancement of the quantum states resulting from a generalized non-linearity of the phase shifts, both without and with losses. We find that such a kind of superposition can give the smallest variance in the phase parameter in comparison with usual Schrödinger cat states in different order of non-linearity even if for a larger average number of photons. Due to the significance of how a system is quantum correlated with its environment in the construction of a scalable quantum computer, the entanglement between the DSS and its environment is investigated during the dissipation. We show that partial entanglement trapping occurs during the dynamics depending on the kind of deformation and mean photon number. These features make the DSS with a larger average number of photons a good candidate for implementation of schemes of quantum optics and information with high precision.
Partially coherent twisted states in arrays of coupled phase oscillators
Omel'chenko, Oleh E.; Wolfrum, Matthias; Laing, Carlo R.
2014-06-15
We consider a one-dimensional array of phase oscillators with non-local coupling and a Lorentzian distribution of natural frequencies. The primary objects of interest are partially coherent states that are uniformly “twisted” in space. To analyze these, we take the continuum limit, perform an Ott/Antonsen reduction, integrate over the natural frequencies, and study the resulting spatio-temporal system on an unbounded domain. We show that these twisted states and their stability can be calculated explicitly. We find that stable twisted states with different wave numbers appear for increasing coupling strength in the well-known Eckhaus scenario. Simulations of finite arrays of oscillators show good agreement with results of the analysis of the infinite system.
Partially coherent twisted states in arrays of coupled phase oscillators.
Omel'chenko, Oleh E; Wolfrum, Matthias; Laing, Carlo R
2014-06-01
We consider a one-dimensional array of phase oscillators with non-local coupling and a Lorentzian distribution of natural frequencies. The primary objects of interest are partially coherent states that are uniformly "twisted" in space. To analyze these, we take the continuum limit, perform an Ott/Antonsen reduction, integrate over the natural frequencies, and study the resulting spatio-temporal system on an unbounded domain. We show that these twisted states and their stability can be calculated explicitly. We find that stable twisted states with different wave numbers appear for increasing coupling strength in the well-known Eckhaus scenario. Simulations of finite arrays of oscillators show good agreement with results of the analysis of the infinite system.
Velazquez Escobar, Francisco; Utesch, Tillmann; Narikawa, Rei; Ikeuchi, Masahiko; Mroginski, Maria Andrea; Gärtner, Wolfgang; Hildebrandt, Peter
2013-07-23
Cyanobacteriochromes are members of the phytochrome superfamily. In contrast to classical phytochromes, these small photosensors display a considerable variability of electronic absorption maxima. We have studied the light-induced conversions of the second GAF domain of AnPixJ, AnPixJg2, a phycocyanobilin-binding protein from the cyanobacterium Anabaena PCC 7120, using low-temperature resonance Raman spectroscopy combined with molecular dynamics simulations. AnPixJg2 is formed biosynthetically as a red-absorbing form (Pr) and can be photoconverted into a green-absorbing form (Pg). Forward and backward phototransformations involve the same reaction sequences and intermediates of similar cofactor structures as the corresponding processes in canonical phytochromes, including a transient cofactor deprotonation. Whereas the cofactor of the Pr state shows far-reaching similarities to the Pr states of classical phytochromes, the Pg form displays significant upshifts of the methine bridge stretching frequencies concomitant to the hypsochromically shifted absorption maximum. However, the cofactor in Pg is protonated and adopts a conformation very similar to the Pfr state of classical phytochromes. The spectral differences are probably related to an increased solvent accessibility of the chromophore which may reduce the π-electron delocalization in the phycocyanobilin and thus raise the energies of the first electronic transition and the methine bridge stretching modes. Molecular dynamics simulations suggest that the Z → E photoisomerization of the chromophore at the C-D methine bridge alters the interactions with the nearby Trp90 which in turn may act as a gate, allowing the influx of water molecules into the chromophore pocket. Such a mechanism of color tuning AnPixJg2 is unique among the cyanobacteriochromes studied so far. PMID:23808413
Dimensionless Equation of State to Predict Microemulsion Phase Behavior.
Ghosh, Soumyadeep; Johns, Russell T
2016-09-01
Prediction of microemulsion phase behavior for changing state variables is critical to formulation design of surfactant-oil-brine (SOB) systems. SOB systems find applications in various chemical and petroleum processes, including enhanced oil recovery. A dimensional equation-of-state (EoS) was recently presented by Ghosh and Johns1 that relied on estimation of the surfactant tail length and surface area. We give an algorithm for flash calculations for estimation of three-phase Winsor regions that is more robust, simpler, and noniterative by making the equations dimensionless so that estimates of tail length and surface area are no longer needed. We predict phase behavior as a function temperature, pressure, volume, salinity, oil type, oil-water ratio, and surfactant/alcohol concentration. The dimensionless EoS is based on coupling the HLD-NAC (Hydrophilic Lipophilic Difference-Net Average Curvature) equations with new relationships between optimum salinity and solubility. An updated HLD expression that includes pressure is also used to complete the state description. A significant advantage of the dimensionless form of the EoS over the dimensional version is that salinity scans are tuned based only on one parameter, the interfacial volume ratio. Further, stability conditions are developed in a simplified way to predict whether an overall compositions lies within the single, two-, or three-phase regions. Important new microemulsion relationships are also found, the most important of which is that optimum solubilization ratio is equal to the harmonic mean of the oil and water solubilization ratios in the type III region. Thus, only one experimental measurement is needed in the three-phase zone to estimate the optimum solubilization ratio, a result which can aid experimental design and improve estimates of optimum from noisy data. Predictions with changing state variables are illustrated by comparison to experimental data using standard diagrams including a new type
Dimensionless Equation of State to Predict Microemulsion Phase Behavior.
Ghosh, Soumyadeep; Johns, Russell T
2016-09-01
Prediction of microemulsion phase behavior for changing state variables is critical to formulation design of surfactant-oil-brine (SOB) systems. SOB systems find applications in various chemical and petroleum processes, including enhanced oil recovery. A dimensional equation-of-state (EoS) was recently presented by Ghosh and Johns1 that relied on estimation of the surfactant tail length and surface area. We give an algorithm for flash calculations for estimation of three-phase Winsor regions that is more robust, simpler, and noniterative by making the equations dimensionless so that estimates of tail length and surface area are no longer needed. We predict phase behavior as a function temperature, pressure, volume, salinity, oil type, oil-water ratio, and surfactant/alcohol concentration. The dimensionless EoS is based on coupling the HLD-NAC (Hydrophilic Lipophilic Difference-Net Average Curvature) equations with new relationships between optimum salinity and solubility. An updated HLD expression that includes pressure is also used to complete the state description. A significant advantage of the dimensionless form of the EoS over the dimensional version is that salinity scans are tuned based only on one parameter, the interfacial volume ratio. Further, stability conditions are developed in a simplified way to predict whether an overall compositions lies within the single, two-, or three-phase regions. Important new microemulsion relationships are also found, the most important of which is that optimum solubilization ratio is equal to the harmonic mean of the oil and water solubilization ratios in the type III region. Thus, only one experimental measurement is needed in the three-phase zone to estimate the optimum solubilization ratio, a result which can aid experimental design and improve estimates of optimum from noisy data. Predictions with changing state variables are illustrated by comparison to experimental data using standard diagrams including a new type
Equation of state and phase diagram of FeO
Fischer, Rebecca A.; Campbell, Andrew J.; Shofner, Gregory A.; Lord, Oliver T.; Dera, Przemyslaw; Prakapenka, Vitali B.
2012-04-11
Wuestite, Fe{sub 1-x}O, is an important component in the mineralogy of Earth's lower mantle and may also be a component in the core. Therefore the high pressure, high temperature behavior of FeO, including its phase diagram and equation of state, is essential knowledge for understanding the properties and evolution of Earth's deep interior. We performed X-ray diffraction measurements using a laser-heated diamond anvil cell to achieve simultaneous high pressures and temperatures. Wuestite was mixed with iron metal, which served as our pressure standard, under the assumption that negligible oxygen dissolved into the iron. Our data show a positive slope for the subsolidus phase boundary between the B1 and B8 structures, indicating that the B1 phase is stable at the P-T conditions of the lower mantle and core. We have determined the thermal equation of state of B1 FeO to 156 GPa and 3100 K, finding an isothermal bulk modulus K{sub 0} = 149.4 {+-} 1.0 GPa and its pressure derivative K'{sub 0} = 3.60 {+-} 0.4. This implies that 7.7 {+-} 1.1 wt.% oxygen is required in the outer core to match the seismologically-determined density, under the simplifying assumption of a purely Fe-O outer core.
Steady-state phase error for a phase-locked loop subjected to periodic Doppler inputs
NASA Technical Reports Server (NTRS)
Chen, C.-C.; Win, M. Z.
1991-01-01
The performance of a carrier phase locked loop (PLL) driven by a periodic Doppler input is studied. By expanding the Doppler input into a Fourier series and applying the linearized PLL approximations, it is easy to show that, for periodic frequency disturbances, the resulting steady state phase error is also periodic. Compared to the method of expanding frequency excursion into a power series, the Fourier expansion method can be used to predict the maximum phase error excursion for a periodic Doppler input. For systems with a large Doppler rate fluctuation, such as an optical transponder aboard an Earth orbiting spacecraft, the method can be applied to test whether a lower order tracking loop can provide satisfactory tracking and thereby save the effect of a higher order loop design.
Relativistic nuclear hydrodynamics and phase transition to the deconfinement state
Barz, H.W.; Kaempfer, B.; Lukacs, B.
1987-11-01
The possible formation of nuclear matter in the phase of a quark--gluon plasma in relativistic heavy-ion collisions is considered in the framework of a hydrodynamic approach. The main results are obtained in a single-fluid model of the formation of a baryon-enriched plasma and relate to nuclear collisions at energies up to 10 GeV/nucleon. At higher energies, a two-fluid model predicts the formation of a plasma in the fragmentation region, but the baryon density is much lower. In all the investigations, including scaling hydrodynamics in the baryon-depleted region of intermediate rapidities, allowance is made for a delayed phase transition to the deconfinement state. A generally covariant formulation of relativistic hydrodynamics is presented as a useful numerical method, together with some extensions of the methods of the standard theory (selection of comoving coordinates, allowance for sink terms, and two-fluid interaction).
Parameter estimation of qubit states with unknown phase parameter
NASA Astrophysics Data System (ADS)
Suzuki, Jun
2015-02-01
We discuss a problem of parameter estimation for quantum two-level system, qubit system, in presence of unknown phase parameter. We analyze trade-off relations for mean square errors (MSEs) when estimating relevant parameters with separable measurements based on known precision bounds; the symmetric logarithmic derivative (SLD) Cramér-Rao (CR) bound and Hayashi-Gill-Massar (HGM) bound. We investigate the optimal measurement which attains the HGM bound and discuss its properties. We show that the HGM bound for relevant parameters can be attained asymptotically by using some fraction of given n quantum states to estimate the phase parameter. We also discuss the Holevo bound which can be attained asymptotically by a collective measurement.
Economical Gaussian cloning of coherent states with known phase
Dong Yuli; Zou Xubo; Guo Guangcan; Li Shangbin
2007-07-15
We investigate the economical Gaussian cloning of coherent states with the known phase, which produces M copies from N input replica and can be implemented with degenerate parametric amplifiers and beam splitters.The achievable fidelity of single copy is given by 2M{radical}(N)/[{radical}(N)(M-1)+{radical}((1+N)(M{sup 2}+N))], which is bigger than the optimal fidelity of the universal Gaussian cloning. The cloning machine presented here works without ancillary optical modes and can be regarded as the continuous variable generalization of the economical cloning machine for qudits.
Geometric phases causing lifetime modifications of metastable states of hydrogen
NASA Astrophysics Data System (ADS)
Trappe, Martin-Isbjörn; Augenstein, Peter; DeKieviet, Maarten; Gasenzer, Thomas; Nachtmann, Otto
2016-04-01
Externally applied electromagnetic fields in general have an influence on the width of atomic spectral lines. The decay rates of atomic states can also be affected by the geometry of an applied field configuration giving rise to an imaginary geometric phase. A specific chiral electromagnetic field configuration is presented which geometrically modifies the lifetimes of metastable states of hydrogen. We propose to extract the relevant observables in a realistic longitudinal atomic beam spin-echo apparatus which allows the initial and final fluxes of the metastable atoms to be compared with each other interferometrically. A geometry-induced change in lifetimes at the 5%-level is found, an effect large enough to be observed in an available experiment.
Semiclassical Dynamics of Electron Wave Packet States with Phase Vortices
Bliokh, Konstantin Yu.; Bliokh, Yury P.; Savel'ev, Sergey; Nori, Franco
2007-11-09
We consider semiclassical higher-order wave packet solutions of the Schroedinger equation with phase vortices. The vortex line is aligned with the propagation direction, and the wave packet carries a well-defined orbital angular momentum (OAM) ({Dirac_h}/2{pi})l (l is the vortex strength) along its main linear momentum. The probability current coils around the momentum in such OAM states of electrons. In an electric field, these states evolve like massless particles with spin l. The magnetic-monopole Berry curvature appears in momentum space, which results in a spin-orbit-type interaction and a Berry/Magnus transverse force acting on the wave packet. This brings about the OAM Hall effect. In a magnetic field, there is a Zeeman interaction, which, can lead to more complicated dynamics.
Tikhomirov, A. V.; Ponomarenko, G. L.
2012-07-01
An additional verification of bundled software (BS) SAPFIR-95 and amp;RC [1] and code KORSAR/GP [2] was performed. Both software products were developed in A.P. Alexandrov NITI and certified by ROSTEKHNADZOR of RF for numeric simulation of stationary, transitional and emergency conditions of VVER reactors. A benchmark model for neutronics calculations was created within the limits of this work. The cold subcritical state of VVER - 1000 reactor stationary fuelling was simulated on the basis of FA with an increased height of the fuel column (TVS-2M) considering detailed presentation of radial and front neutron reflectors. A case of passing of pure condensate slug through the core in initially deep subcritical state during start of the first RCP set after refueling was considered as an examined condition of reactor operation. A relatively small size of the slug, its spatial position near the reflectors (lower and lateral), as well as failure of the inserted control rods of the control and protection system (CPS CR) to reach the lower limit of the fuel column stipulate for methodical complexity of a correct calculation of the neutron multiplication constant (K{sub eff}) using engineering codes. Code RC was used as a test program in the process of reactor calculated 3-D modeling. Code MCNP5 [3] was used as the precision program, which solves the equation of neutrons transfer by Monte-Carlo method and which was developed in the US (Los-Alamos). As a result of comparative calculations dependency of K{sub eff} on two parameters was evaluated - boron acid concentration (Cb) and CPS CR position. Reactivity effect was evaluated, which is implemented as a result of failure of all CPS control rods to reach the lower fuel limit calculated using the engineering codes mentioned above. (authors)
Equations of state and phase transitions in stellar matter
Raduta, Ad. R.; Gulminelli, F.; Aymard, F.; Oertel, M.; Margueron, J.
2014-05-09
Realistic description of core-collapsing supernovae evolution and structure of proto-neutron stars chiefly depends on microphysics input in terms of equations of state, chemical composition and weak interaction rates. At sub-saturation densities the main uncertainty comes from the symmetry energy. Within a nuclear statistical equilibrium (NSE) model with consistent treatment of clusterized and unbound components we investigate the meaning of symmetry energy in the case of dis-homogeneous systems, as the one thought to constitute the neutron star crust, and its sensitivity to the isovector properties of the effective interaction. At supra-saturation densities the situation is much more difficult because of the poor knowledge of nucleon-hyperon and hyperon-hyperon interactions and thermodynamic behavior in terms of phase transitions. Within a simple (npΛ) model we show that compressed baryonic matter with strangeness manifests a complex phase diagram with first and second order phase transitions. The fact that both are explored under strangeness chemical equilibrium and survive Coulomb suggests that they might have sizable consequences on star evolution. An example in this sense is the drastic reduction of the neutrino-mean free path in the vicinity of the critical point obtained within RPA which would lead to a less rapid star cooling.
Stewart, David J; Dalton, Matthew J; Long, Stephanie L; Kannan, Ramamurthi; Yu, Zhenning; Cooper, Thomas M; Haley, Joy E; Tan, Loon-Seng
2016-02-21
The two-photon absorbing dye AF240 [1, (7-benzothiazol-2-yl-9,9-diethylfluoren-2-yl)diphenylamine] is modified by adding bulky alkyl groups to the diphenylamino moiety. Three new compounds are synthesized which have ethyl groups in both ortho positions of each phenyl ring (2), t-butyl groups in one ortho position of each phenyl ring (3), and t-butyl groups in the para position of each phenyl ring (4). The dyes are examined in several aprotic solvents with varying polarity to observe the effects of the sterically hindering bulky groups on the ground and excited-state photophysical properties. While the ground state shows minimal solvent dependence, there is significant dependence on the fluorescence quantum yield and lifetime, as well as the excited-state energy levels. This effect is caused by the formation of an intramolecular charge-transfer (ICT) state, which is observed in the solvents more polar than n-hexane and supported by TD-DFT calculations. Electronic effects of ortho or para alkyl substitution should be similar, yet drastic differences are observed. A red shift in the fluorescence maximum is observed in 4 relative to 1, yet a blue shift occurs in 2 and 3 because the substituents at the sterically sensitive ortho-positions inhibit excited-state geometric relaxation and result in less ICT character than 1. Coupled with theoretical calculations, the data support a planar ICT (PICT) excited state where the diphenylamino nitrogen in an sp(2)-like geometry is integral with the plane containing the fluorene and benzothiazole moieties. Ultrafast transient absorption experiments show that ICT occurs rapidly (<150 fs) followed by geometric and solvent relaxation in ∼ 1-4 ps to form the PICT or solvent-stabilized ICT (SSICT) state. This relaxation is not observed in non-polar n-hexane because the solvent dependent ICT state energy lies higher than the locally-excited (LE) state. Finally, formation of a triplet state (T1) is only efficiently observed in n
Flores, Gema; Ruiz del Castillo, Maria Luisa; Herraiz, Marta
2007-11-01
A method based on the use of absorbents as packing materials inside the interface of the online coupling between RPLC and GC is proposed for the enantiomeric analysis of beta-pinene and limonene in essential oils. For that purpose, a comparison of the RSD, detection limit and recovery provided by two absorbents and one adsorbent is included in this study. The results found in this work proved the validity of absorbents as packing materials in online RPLC-GC to determine minor compounds in complex matrices. In particular, PDMS seemed to be specially useful to analyse nonpolar compounds, such as beta-pinene and limonene, since it provided higher sensitivity for this kind of compounds. The developed method was applied to the evaluation of the natural and non-natural character of commercial essential oils by means of the determination of the enantiomeric composition of beta-pinene and limonene.
Metastable states in calcium phosphate - aqueous phase equilibrations
NASA Astrophysics Data System (ADS)
Driessens, F. C. M.; Verbeeck, R. M. H.
1981-05-01
A critical evaluation of the literature reveals that during equilibration of well crystallized hydroxyapatite in aqueous solutions metastable states can occur. They are characterized by a persistent supersaturation with respect to hydroxyapatite and a systematical dependence of the ion activity product of this compound on the solution composition. For products synthesized by thermal treatment it is known that they are transformed into oxyhydroxyapatite so that the theoretical solubility behaviour could be predicted from the extrapolated value of the free energy of oxyapatite at room temperature: the negative logarithm of the ionic product for hydroxyapatite should become close to that of oxyapatite during equilibration. The discrepancy with experimental data is probably due to the formation of thin layers seeming dicalcium phosphate dihydrate, octocalcium phosphate or defective hydroxyapatite as coatings on the apatite crystals. This is derived from the apparent Ca/P ratio of the solubility controlling phase. According to chemical potential plots this apparent Ca/P ratio can have values close to 1, 1.33, 1.50 or 1.67. The aqueous solutions are clearly undersaturated with respect to the more acidic calcium phosphates so that the coatings must deviate from the compositions of these compounds in their pure state. The formation of these metastable states during equilibration of oxyhydroxyapatites is compared with others occuring during precipitation and crystal growth of calcium phosphates. A model is proposed which explains the observations qualitatively.
Structural-phase state and creep of mixed nitride fuel
NASA Astrophysics Data System (ADS)
Konovalov, I. I.; Tarasov, B. A.; Glagovsky, E. M.
2016-04-01
By the analysis of thermal creep data in conjunction with structural-phase state the most likely mechanisms of UN creep are considered. An equation relating the thermal and radiation creep of nitride fuel with such important parameters as plutonium content, porosity, grain size, the content of impurities of transition metals and oxygen, the carbon content has been suggested. At stationary operating parameters in reactor the creep of nitride fuel with technical purity is defined by the thermal component at mechanism of intergranular slip and by the radiation component, which plays a significant role at temperatures below 1100°C. Both types of creep in a first approximation have a linear dependence on the stress.
Bhattacharyya, Sirshendu; Dasgupta, Subinay; Das, Arnab
2015-01-01
Understanding phase transitions in quantum matters constitutes a significant part of present day condensed matter physics. Quantum phase transitions concern ground state properties of many-body systems, and hence their signatures are expected to be pronounced in low-energy states. Here we report signature of a quantum critical point manifested in strongly out-of-equilibrium states with finite energy density with respect to the ground state and extensive (subsystem) entanglement entropy, generated by an external pulse. These non-equilibrium states are evidently completely disordered (e.g., paramagnetic in case of a magnetic ordering transition). The pulse is applied by switching a coupling of the Hamiltonian from an initial value (λI) to a final value (λF) for sufficiently long time and back again. The signature appears as non-analyticities (kinks) in the energy absorbed by the system from the pulse as a function of λF at critical-points (i.e., at values of λF corresponding to static critical-points of the system). As one excites higher and higher eigenstates of the final Hamiltonian H(λF) by increasing the pulse height , the non-analyticity grows stronger monotonically with it. This implies adding contributions from higher eigenstates help magnifying the non-analyticity, indicating strong imprint of the critical-point on them. Our findings are grounded on exact analytical results derived for Ising and XY chains in transverse field. PMID:26568306
NASA Astrophysics Data System (ADS)
Qi, Yadong; Bai, Shuju; Gao, Wei; Heisler, Gordon M.
2003-06-01
Increased concentration of leaf UV-B absorbing-compounds due to exposure to UV-B radiation is widely accepted as one of the plant adaptations to resist enhanced UV-B radiation. This paper reports a field comparative study of dynamics and temporal changes of UV-B absorbing-compound concentration in 35 southern broadleaf trees over a growing season. Leaf UV-B absorbing-compound, chlorophyll concentration, and leaf thickness were measured from the sun-exposed leaves of 35 tree species collected monthly from individual trees growing within the city of Baton Rouge, Louisiana from April to October in 2000. The USDA UV-B Monitoring Network Baton Rouge Station provided the ambient UV-B radiation data. Leaf UV-B absorbing-compound concentration varied significantly with leaf age and species. Intra-specifically, leaf UV-B absorbing-compound concentration exhibited a generally increasing trend during leaf growth and development in response to the increased exposure to natural UV-B/solar radiation during the growing season. Inter-specifically, significant differences existed in leaf UV-B absorbing-compound concentration. The species were compared and ranked based on the growing season averages of the leaf total UV-B absorbing-compound concentration. The species were further classified into three levels (high, medium, and low) based on the magnitude of UV-B absorbing-compound concentration.
Gunalp, Bengul
2015-07-01
Myocardial perfusion imaging (MPI) is one the most contributing nuclear medicine technique to the annual population dose. The purpose of this study is to compare radiation-absorbed doses to the patients examined by conventional cardiac SPECT (CSPECT) camera and ultrafast cardiac (UFC) camera with cadmium-zinc-telluride (CZT) solid-state detectors. Total injected activity was reduced by 50 % when both stress and rest images were acquired and by 75 % when only stress images were taken with UFC camera. As a result of this, the mean total effective dose was found significantly lower with UFC camera (2.2 ± 1.2 mSv) than CSPECT (7.7 ± 3.8 mSv) (p < 0.001). Further dose reduction was obtained by reducing equivocal test results and unnecessary additional examinations with UFC camera. Using UFC camera, MPI can be conveniently used for the detection of coronary artery disease (CAD) much less increasing annual population radiation dose as it had been before. PMID:25848109
Carbon Absorber Retrofit Equipment (CARE)
Klein, Eric
2015-12-23
During Project DE-FE0007528, CARE (Carbon Absorber Retrofit Equipment), Neumann Systems Group (NSG) designed, installed and tested a 0.5MW NeuStream® carbon dioxide (CO_{2}) capture system using the patented NeuStream® absorber equipment and concentrated (6 molal) piperazine (PZ) as the solvent at Colorado Springs Utilities’ (CSU’s) Martin Drake pulverized coal (PC) power plant. The 36 month project included design, build and test phases. The 0.5MW NeuStream® CO_{2} capture system was successfully tested on flue gas from both coal and natural gas combustion sources and was shown to meet project objectives. Ninety percent CO_{2} removal was achieved with greater than 95% CO_{2}product purity. The absorbers tested support a 90% reduction in absorber volume compared to packed towers and with an absorber parasitic power of less than 1% when configured for operation with a 550MW coal plant. The preliminary techno-economic analysis (TEA) performed by the Energy and Environmental Research Center (EERC) predicted an over-the-fence cost of $25.73/tonne of CO_{2} captured from a sub-critical PC plant.
Geometric phase of mixed states for three-level open systems
Jiang Yanyan; Ji, Y. H.; Wang, Z. S.; Xu Hualan; Hu Liyun; Chen, Z. Q.; Guo, L. P.
2010-12-15
Geometric phase of mixed state for three-level open system is defined by establishing in connecting density matrix with nonunit vector ray in a three-dimensional complex Hilbert space. Because the geometric phase depends only on the smooth curve on this space, it is formulated entirely in terms of geometric structures. Under the limiting of pure state, our approach is in agreement with the Berry phase, Pantcharatnam phase, and Aharonov and Anandan phase. We find that, furthermore, the Berry phase of mixed state correlated to population inversions of three-level open system.
Composition for absorbing hydrogen
Heung, Leung K.; Wicks, George G.; Enz, Glenn L.
1995-01-01
A hydrogen absorbing composition. The composition comprises a porous glass matrix, made by a sol-gel process, having a hydrogen-absorbing material dispersed throughout the matrix. A sol, made from tetraethyl orthosilicate, is mixed with a hydrogen-absorbing material and solidified to form a porous glass matrix with the hydrogen-absorbing material dispersed uniformly throughout the matrix. The glass matrix has pores large enough to allow gases having hydrogen to pass through the matrix, yet small enough to hold the particles dispersed within the matrix so that the hydrogen-absorbing particles are not released during repeated hydrogen absorption/desorption cycles.
Composition for absorbing hydrogen
Heung, L.K.; Wicks, G.G.; Enz, G.L.
1995-05-02
A hydrogen absorbing composition is described. The composition comprises a porous glass matrix, made by a sol-gel process, having a hydrogen-absorbing material dispersed throughout the matrix. A sol, made from tetraethyl orthosilicate, is mixed with a hydrogen-absorbing material and solidified to form a porous glass matrix with the hydrogen-absorbing material dispersed uniformly throughout the matrix. The glass matrix has pores large enough to allow gases having hydrogen to pass through the matrix, yet small enough to hold the particles dispersed within the matrix so that the hydrogen-absorbing particles are not released during repeated hydrogen absorption/desorption cycles.
Phases of non-extremal multi-centered bound states
NASA Astrophysics Data System (ADS)
Chowdhury, Borun D.; Mayerson, Daniel R.; Vercnocke, Bert
2013-12-01
We investigate the phase space of multi-centered near-extremal configurations previously studied in arXiv:1108.5821 [1] and arXiv:1110.5641 [2] in the probe limit. We confirm that in general the energetically favored ground state of the multi-center potential, which can be a single or multi-center configuration, has the most entropy and is thus thermodynamically stable. However, we find the surprising result that for a subset of configurations, even though a single center black hole seems to be energetically favored, it is entropically not allowed (the resulting black hole would violate cosmic censorship). This disproves classical intuition that everything would just fall into the black hole if energetically favored. Along the way we highlight a shortcoming in the literature regarding the computation of the angular momentum coming from electromagnetic interaction in the probe limit and rectify it. We also demonstrate that static supertubes can exist inside ergoregions where ordinary point particles would be frame dragged.
Lee, Jong Hoon; Naumov, Pance; Chung, Ihn Hee; Lee, Sang Cheol
2011-09-01
The lower 1,3-bis(hydroxyalkylamino) homologues of the strong intramolecular X-type charge transfer (CT) system 1,3-diamino-4,6-dinitrobenzene (DADNB) exhibit reversible color change in the solid state from yellow at room temperature (RT) to orange and red at high temperature (HT). To investigate the structural prerequisites for occurrence of this phenomenon, we prepared 10 new derivatives of DADNB where the hydroxyalkyl arms at the amino groups were replaced with substituents having different electronic and steric profiles. Two of the new materials exhibit sharp and reversible thermochromic change in the solid state: when heated, the bis(aminoethyl) derivative (DADNB-1) undergoes color change from orange-red to brown, while one of the three polymorphs of the bisphenyl product (DADNB-2) changes its color from red to yellow. The physicochemical analysis and the crystal structures of seven of these compounds, one of which is trimorphic, confirmed that both phenomena are due to solid-solid phase transitions. The brown high-temperature phase of DADNB-1 presents the first example where the absorption is shifted beyond the red region. Form C of DADNB-2 is the first material of this group that exhibits "negative" thermochromism, where the high-temperature phase absorbs at lower wavelength than the low-temperature one. The results demonstrate the potentials of these simple and easily accessible organic molecular materials for thermal switching of the optical properties by utility of intermolecular interactions to modulate the intramolecular CT.
Phase-Conjugate Receiver for Gaussian-State Quantum Illumination
NASA Technical Reports Server (NTRS)
Erkmen, Baris I.; Guha, Saikat
2010-01-01
An active optical sensor probes a region of free space that is engulfed in bright thermal noise to determine the presence (or absence) of a weakly reflecting target. The returned light (which is just thermal noise if no target is present, and thermal noise plus a weak reflection of the probe beam if a target is present) is measured and processed by a receiver and a decision is made on whether a target is present. It has been shown that generating an entangled pair of photons (which is a highly nonclassical state of light), using one photon as the probe beam and storing the other photon for comparison to the returned light, has superior performance to the traditional classical-light (coherent-state) target detection sensors. An entangled-photon transmitter and optimal receiver combination can yield up to a factor of 4 (i.e., 6 dB) gain in the error-probability exponent over a coherent state transmitter and optimal receiver combination, in a highly lossy and noisy scenario (when both sensors have the same number of transmitted photons). However, the receiver that achieves this advantage is not known. One structured receiver can close half of the 6-dB gap (i.e., a 3-dB improvement). It is based on phase-conjugating the returned light, then performing dual-balanced difference detection with the stored half of the entangled-photon pair. Active optical sensors are of tremendous value to NASA s missions. Although this work focuses on target detection, it can be extended to imaging (2D, 3D, hyperspectral, etc.) scenarios as well, where the image quality can be better than that offered by traditional active sensors. Although the current work is theoretical, NASA s future missions could benefit significantly from developing and demonstrating this capability. This is an optical receiver design whose components are, in principle, all implementable. However, the work is currently entirely theoretical. It is necessary to: 1. Demonstrate a bench-top proof of the theoretical
Lowe, D J; Fisher, K; Thorneley, R N
1993-01-01
The pre-steady-state absorbance changes that occur during the first 0.6 s of reaction of the nitrogenase of Klebsiella pneumoniae can be simulated by associating redox changes with the different states of the MoFe protein described by our published kinetic model for nitrogenase [Lowe and Thorneley (1984) Biochem. J. 224, 877-886]. When the substrate is changed, from H+ to C2H2 (acetylene) or N2, or the nitrogenase component protein ratio is altered, these pre-steady-state absorbance changes are affected in a manner that is quantitatively predicted by our model. The results, together with parallel e.p.r. studies, are interpreted as showing that the P-clusters become oxidized when the MoFe protein is in the state where bound N2 is irreversibly committed to being reduced and is protonated to the hydrazido(2-) level. PMID:8389132
Quantum theory of the smectic metal state in stripe phases
Emery; Fradkin; Kivelson; Lubensky
2000-09-01
We present a theory of the electron smectic fixed point of the stripe phases of doped layered Mott insulators. We show that in the presence of a spin gap three phases generally arise: (a) a smectic superconductor, (b) an insulating stripe crystal, and (c) a smectic metal. The latter phase is a stable two-dimensional anisotropic non-Fermi liquid. In the absence of a spin gap there is also a more conventional Fermi-liquid-like phase. The smectic superconductor and smectic metal phases (or glassy versions thereof) may have already been seen in Nd-doped La2-xSrxCuO4.
NASA Astrophysics Data System (ADS)
Ban, Masashi
1999-08-01
Phase-space representation of quantum state vectors has been recently formulated by means of the relative-state method developed by the present author [J. Math. Phys. 39, 1744 (1998)]. It is, however, pointed out by Mo/ller that the displacement-operator method provides another basis of phase-space representation of quantum state vectors [J. Math. Phys. (to appear)]. Hence the relation between the relative-state approach and the displacement-operator approach is discussed, both of which yield equivalent phase-space representations.
Phase correlation of ensemble of quantum emitters and timed Dicke state
NASA Astrophysics Data System (ADS)
Yoon, Jae Seok; Hong, Suc-Kyoung; Nam, Seog Woo; Yang, Hyung Jin
2016-06-01
We study the phase-correlated state which is introduced by the instantaneous excitation of an ensemble of identical two-level quantum emitters and its relation with the Dicke states. Under weak coupling regime, the time evolution of the phase-correlated system of the emitters is also derived to see the characteristics of the collective spontaneous emission of the emitters. It is found that the effective coupling of the ensemble in the phase-correlated state with the emitted field is directly determined by the collective phase of the system. Hence, the collective phase is considered for several specified distributions in brief.
Modelling Absorbent Phenomena of Absorbent Structure
NASA Astrophysics Data System (ADS)
Sayeb, S.; Ladhari, N.; Ben Hassen, M.; Sakli, F.
Absorption, retention and strike through time, as evaluating criteria of absorbent structures quality were studied. Determination of influent parameters on these criteria were realized by using the design method of experimental sets. In this study, the studied parameters are: Super absorbent polymer (SAP)/fluff ratio, compression and the porosity of the non woven used as a cover stock. Absorption capacity and retention are mostly influenced by SAP/fluff ratio. However, strike through time is affected by compression. Thus, a modelling of these characteristics in function of the important parameter was established.
Methods for absorbing neutrons
Guillen, Donna P.; Longhurst, Glen R.; Porter, Douglas L.; Parry, James R.
2012-07-24
A conduction cooled neutron absorber may include a metal matrix composite that comprises a metal having a thermal neutron cross-section of at least about 50 barns and a metal having a thermal conductivity of at least about 1 W/cmK. Apparatus for providing a neutron flux having a high fast-to-thermal neutron ratio may include a source of neutrons that produces fast neutrons and thermal neutrons. A neutron absorber positioned adjacent the neutron source absorbs at least some of the thermal neutrons so that a region adjacent the neutron absorber has a fast-to-thermal neutron ratio of at least about 15. A coolant in thermal contact with the neutron absorber removes heat from the neutron absorber.
Externally tuned vibration absorber
Vincent, Ronald J.
1987-09-22
A vibration absorber unit or units are mounted on the exterior housing of a hydraulic drive system of the type that is powered from a pressure wave generated, e.g., by a Stirling engine. The hydraulic drive system employs a piston which is hydraulically driven to oscillate in a direction perpendicular to the axis of the hydraulic drive system. The vibration absorbers each include a spring or other resilient member having one side affixed to the housing and another side to which an absorber mass is affixed. In a preferred embodiment, a pair of vibration absorbers is employed, each absorber being formed of a pair of leaf spring assemblies, between which the absorber mass is suspended.
Quantum Theory of the Smectic Metal State in Stripe Phases
Emery, V. J.; Fradkin, E.; Kivelson, S. A.; Lubensky, T. C.
2000-09-04
We present a theory of the electron smectic fixed point of the stripe phases of doped layered Mott insulators. We show that in the presence of a spin gap three phases generally arise: (a) a smectic superconductor, (b) an insulating stripe crystal, and (c) a smectic metal. The latter phase is a stable two-dimensional anisotropic non-Fermi liquid. In the absence of a spin gap there is also a more conventional Fermi-liquid-like phase. The smectic superconductor and smectic metal phases (or glassy versions thereof) may have already been seen in Nd-doped La{sub 2-x}Sr {sub x}CuO{sub 4} . (c) 2000 The American Physical Society.
Engineering reverse saturable absorbers for desired wavelengths
NASA Astrophysics Data System (ADS)
Band, Yehuda B.; Scharf, Benjamin
1986-06-01
A variety of applications exist for reverse saturable absorbers (RSAs) in laser science (RSAs are substances whose excited-state absorption cross section is larger than their ground-state absorption cross section at a given wavelength and possess a number of other properties). We propose an approach to designing RSAs at a desired wavelength by construction of dimers of dye molecules which absorb near the wavelength of interest. The dimer ground-state absorption is to a state in which the excitation is spread over both monomeric units and the excited-state absorption commences from this state to the doubly excited electronic state in which both monomeric units are excited.
Robust Light State by Quantum Phase Transition in Non-Hermitian Optical Materials.
Zhao, Han; Longhi, Stefano; Feng, Liang
2015-11-23
Robust light transport is the heart of optical information processing, leading to the search for robust light states by topological engineering of material properties. Here, it is shown that quantum phase transition, rather than topology, can be strategically exploited to design a novel robust light state. We consider an interface between parity-time (PT) symmetric media with different quantum phases and use complex Berry phase to reveal the associated quantum phase transition and topological nature. While the system possesses the same topological order within different quantum phases, phase transition from PT symmetry to PT breaking across the interface in the synthetic non-Hermitian metamaterial system facilitates novel interface states, which are robust against a variety of gain/loss perturbations and topological impurities and disorder. The discovery of the robust light state by quantum phase transition may promise fault-tolerant light transport in optical communications and computing.
Robust Light State by Quantum Phase Transition in Non-Hermitian Optical Materials
Zhao, Han; Longhi, Stefano; Feng, Liang
2015-01-01
Robust light transport is the heart of optical information processing, leading to the search for robust light states by topological engineering of material properties. Here, it is shown that quantum phase transition, rather than topology, can be strategically exploited to design a novel robust light state. We consider an interface between parity-time (PT) symmetric media with different quantum phases and use complex Berry phase to reveal the associated quantum phase transition and topological nature. While the system possesses the same topological order within different quantum phases, phase transition from PT symmetry to PT breaking across the interface in the synthetic non-Hermitian metamaterial system facilitates novel interface states, which are robust against a variety of gain/loss perturbations and topological impurities and disorder. The discovery of the robust light state by quantum phase transition may promise fault-tolerant light transport in optical communications and computing. PMID:26592765
Robust Light State by Quantum Phase Transition in Non-Hermitian Optical Materials
NASA Astrophysics Data System (ADS)
Zhao, Han; Longhi, Stefano; Feng, Liang
2015-11-01
Robust light transport is the heart of optical information processing, leading to the search for robust light states by topological engineering of material properties. Here, it is shown that quantum phase transition, rather than topology, can be strategically exploited to design a novel robust light state. We consider an interface between parity-time (PT) symmetric media with different quantum phases and use complex Berry phase to reveal the associated quantum phase transition and topological nature. While the system possesses the same topological order within different quantum phases, phase transition from PT symmetry to PT breaking across the interface in the synthetic non-Hermitian metamaterial system facilitates novel interface states, which are robust against a variety of gain/loss perturbations and topological impurities and disorder. The discovery of the robust light state by quantum phase transition may promise fault-tolerant light transport in optical communications and computing.
NASA Astrophysics Data System (ADS)
Furukawa, Shunsuke; Sato, Masahiro; Onoda, Shigeki; Furusaki, Akira
2012-09-01
The ground-state phase diagram of a spin-(1)/(2) XXZ chain with competing ferromagnetic nearest-neighbor (J1<0) and antiferromagnetic second-neighbor (J2>0) exchange couplings is studied by means of the infinite time evolving block decimation algorithm and effective field theories. For the SU(2)-symmetric (Heisenberg) case, we show that the nonmagnetic phase in the range -4
Li, Linsen; Chen-Wiegart, Yu-chen Karen; Wang, Jiajun; Gao, Peng; Ding, Qi; Yu, Young-Sang; Wang, Feng; Cabana, Jordi; Wang, Jun; Jin, Song
2015-04-20
In situ techniques with high temporal, spatial and chemical resolution are key to understand ubiquitous solid-state phase transformations, which are crucial to many technological applications. Hard X-ray spectro-imaging can visualize electrochemically driven phase transformations but demands considerably large samples with strong absorption signal so far. Here we show a conceptually new data analysis method to enable operando visualization of mechanistically relevant weakly absorbing samples at the nanoscale and study electrochemical reaction dynamics of iron fluoride, a promising high-capacity conversion cathode material. In two specially designed samples with distinctive microstructure and porosity, we observe homogeneous phase transformations during both discharge andmore » charge, faster and more complete Li-storage occurring in porous polycrystalline iron fluoride, and further, incomplete charge reaction following a pathway different from conventional belief. In conclusion, these mechanistic insights provide guidelines for designing better conversion cathode materials to realize the promise of high-capacity lithium-ion batteries.« less
A Multi-Phase Equation of State and Strength Model for Tin
Cox, G. A.
2006-07-28
This paper considers a multi-phase equation of state and a multi-phase strength model for tin in the {beta}, {gamma} and liquid phases. At a phase transition there are changes in volume, energy, and properties of a material that should be included in an accurate model. The strength model will also be affected by a solid-solid phase transition. For many materials there is a lack of experimental data for strength at high pressures making the derivation of strength parameters for some phases difficult. In the case of tin there are longitudinal sound speed data on the Hugoniot available that have been used here in conjunction with a multi-phase equation of state to derive strength parameters for the {gamma} phase, a phase which does not exist at room temperature and pressure.
NASA Astrophysics Data System (ADS)
Leung, Mary Ann
2004-03-01
We propose a model for the generation of Schrödinger cat states of BEC in multiple wells, and also show how squeezed states can be produced nonadiabatically. The condensate in the multiple well evolves, starting with a certain initial phase difference between the neighboring wells, to a state with a well defined entanglement. We propose a general formula for the initial phase difference: j 2 pi/N where j=1,2,..,N-1, and N is the number of wells. We show the generation of cat states for these different phase configurations in two, three and four wells, and thus generalize this method to any number of wells, even or odd. In addition to the macroscopic superposition states, the method can also be used to generate squeezed states in a nonadiabatic fashion. This work was supported by NSF grant PHY-0140091 and the Computational Science Graduate Fellowship program.
Advanced neutron absorber materials
Branagan, Daniel J.; Smolik, Galen R.
2000-01-01
A neutron absorbing material and method utilizing rare earth elements such as gadolinium, europium and samarium to form metallic glasses and/or noble base nano/microcrystalline materials, the neutron absorbing material having a combination of superior neutron capture cross sections coupled with enhanced resistance to corrosion, oxidation and leaching.
NASA Technical Reports Server (NTRS)
Mathur, Smita
2002-01-01
The goal of this program was a comprehensive multiwavelength study of absorption phenomena in active galactic nuclei (AGN). These include a variety of associated absorption systems: X-ray warm absorbers, X-ray cold absorbers. UV absorbers with high ionization lines, MgII absorbers, red quasars and BALQSOs. The aim is to determine the physical conditions in the absorbing outflows, study their inter-relations and their role in AGN. We designed several observing programs to achieve this goal: X-ray spectroscopy, UV spectroscopy, FLAY spectroscopy and X-ray imaging. We were very successful towards achieving the goal over the five year period as shown through following observing programs and papers. Copies of a few papers are attached with this report.
The Iron-Iron Carbide Phase Diagram: A Practical Guide to Some Descriptive Solid State Chemistry.
ERIC Educational Resources Information Center
Long, Gary J.; Leighly, H. P., Jr.
1982-01-01
Discusses the solid state chemistry of iron and steel in terms of the iron-iron carbide phase diagram. Suggests that this is an excellent way of introducing the phase diagram (equilibrium diagram) to undergraduate students while at the same time introducing the descriptive solid state chemistry of iron and steel. (Author/JN)
40 CFR 72.73 - State issuance of Phase II permits.
Code of Federal Regulations, 2013 CFR
2013-07-01
... (CONTINUED) PERMITS REGULATION Acid Rain Phase II Implementation § 72.73 State issuance of Phase II permits... permit program under part 70 of this chapter and that has a State Acid Rain program accepted by the Administrator under § 72.71 shall be responsible for administering and enforcing Acid Rain permits effective...
40 CFR 72.73 - State issuance of Phase II permits.
Code of Federal Regulations, 2010 CFR
2010-07-01
... (CONTINUED) PERMITS REGULATION Acid Rain Phase II Implementation § 72.73 State issuance of Phase II permits... permit program under part 70 of this chapter and that has a State Acid Rain program accepted by the Administrator under § 72.71 shall be responsible for administering and enforcing Acid Rain permits effective...
40 CFR 72.73 - State issuance of Phase II permits.
Code of Federal Regulations, 2012 CFR
2012-07-01
... (CONTINUED) PERMITS REGULATION Acid Rain Phase II Implementation § 72.73 State issuance of Phase II permits... permit program under part 70 of this chapter and that has a State Acid Rain program accepted by the Administrator under § 72.71 shall be responsible for administering and enforcing Acid Rain permits effective...
40 CFR 72.73 - State issuance of Phase II permits.
Code of Federal Regulations, 2011 CFR
2011-07-01
... (CONTINUED) PERMITS REGULATION Acid Rain Phase II Implementation § 72.73 State issuance of Phase II permits... permit program under part 70 of this chapter and that has a State Acid Rain program accepted by the Administrator under § 72.71 shall be responsible for administering and enforcing Acid Rain permits effective...
40 CFR 72.73 - State issuance of Phase II permits.
Code of Federal Regulations, 2014 CFR
2014-07-01
... (CONTINUED) PERMITS REGULATION Acid Rain Phase II Implementation § 72.73 State issuance of Phase II permits... permit program under part 70 of this chapter and that has a State Acid Rain program accepted by the Administrator under § 72.71 shall be responsible for administering and enforcing Acid Rain permits effective...
Phase coexistence in partially symmetric q-state models
NASA Astrophysics Data System (ADS)
Laanait, Lahoussine; Masaif, Noureddine; Ruiz, Jean
1993-08-01
We consider a lattice model whose spins may assume a finite number q of values. The interaction energy between two nearest-neighbor spins takes on the value J 1 + J 2 or J 2, depending on whether the two spins coincide or are different but coincide modulo q1, and it is zero otherwise. This model is a generalization of the Ashkin-Teller model and exhibits the multilayer wetting phenomenon, that is, wetting by one or two or three interfacial layers, depending on the number of phases in coexistence. While we plan to consider interface properties in such a case, here we study the phase diagram of the model. We show that for large values of q 1 and q/q 1, it exhibits, according the value of J 2/ J 1, either a unique first-order temperature-driven phase transition at some point β t where q ordered phases coexist with the disordered one, or two transition temperatures β{t/(1)} and β{t/(2)}, where q1 partially ordered phases coexist with the ordered ones (β{t/(1)}) or with the disordered one (β{t/(2)}), or for a particular value of J 2/ J 1 there is a unique transition temperature where all the previous phases coexist. Proofs are based on the Pirogov-Sinai theory: we perform a random cluster representation of the model (allowing us to consider noninteger values of q 1 and q/q 1) to which we adapt this theory.
Ultraviolet absorbance screening for DNAPL site compliance
Misquitta, N.; Foster, D.; Coll, F.; Brourman, M.
1997-12-31
The UV Absorbance Effectiveness Demonstration was developed to evaluate the feasibility of using UV absorbance as a surrogate for oil & grease methods of measuring the concentration of coal tar-related constituents in groundwater. Since the current oil & grease method via Freon{reg_sign} extraction is being phased out, a new alternative oil & grease method using a hexane extraction will be introduced in the near future. A secondary objective of this evaluation was to compare the two oil & grease methods, as they relate to facility groundwater, in order to demonstrate the overall robustness of UV absorbance as a surrogate for oil & grease analysis, regardless of the method of extraction.
Internal absorber solar collector
Sletten, Carlyle J.; Herskovitz, Sheldon B.; Holt, F. S.; Sletten, E. J.
1981-01-01
Thin solar collecting panels are described made from arrays of small rod collectors consisting of a refracting dielectric rod lens with an absorber imbedded within it and a reflecting mirror coated on the back side of the dielectric rod. Non-tracking collector panels on vertical walls or roof tops receive approximately 90% of solar radiation within an acceptance zone 60.degree. in elevation angle by 120.degree. or more in the azimuth sectors with a collector concentration ratio of approximately 3.0. Miniaturized construction of the circular dielectric rods with internal absorbers reduces the weight per area of glass, plastic and metal used in the collector panels. No external parts or insulation are needed as heat losses are low due to partial vacuum or low conductivity gas surrounding heated portions of the collector. The miniature internal absorbers are generally made of solid copper with black selective surface and the collected solar heat is extracted at the collector ends by thermal conductivity along the absorber rods. Heat is removed from end fittings by use of liquid circulants. Several alternate constructions are provided for simplifying collector panel fabrication and for preventing the thermal expansion and contraction of the heated absorber or circulant tubes from damaging vacuum seals. In a modified version of the internal absorber collector, oil with temperature dependent viscosity is pumped through a segmented absorber which is now composed of closely spaced insulated metal tubes. In this way the circulant is automatically diverted through heated portions of the absorber giving higher collector concentration ratios than theoretically possible for an unsegmented absorber.
NASA Technical Reports Server (NTRS)
Marsh, H. E., Jr.; Wallace, C. J.
1973-01-01
The removal of bile acids and cholesterol by polymeric absorption is discussed in terms of micelle-polymer interaction. The results obtained with a polymer composed of 75 parts PEO and 25 parts PB plus curing ingredients show an absorption of 305 to 309%, based on original polymer weight. Particle size effects on absorption rate are analyzed. It is concluded that crosslinked polyethylene oxide polymers will absorb water, crosslinked polybutadiene polymers will absorb lipids; neither polymer will absorb appreciable amounts of lipids from micellar solutions of lipids in water.
Ultrafast electronic relaxation of excited state vitamin B 12 in the gas phase
NASA Astrophysics Data System (ADS)
Shafizadeh, Niloufar; Poisson, Lionel; Soep, Benoıˆt
2008-06-01
The time evolution of electronically excited vitamin B 12 (cyanocobalamin) has been observed for the first time in the gas phase. It reveals an ultrafast decay to a state corresponding to metal excitation. This decay is interpreted as resulting from a ring to metal electron transfer. This opens the observation of the excited state of other complex biomimetic systems in the gas phase, the key to the characterisation of their complex evolution through excited electronic states.
Pressure induced phase transitions and equation of state of adamantane
NASA Astrophysics Data System (ADS)
Vijayakumar, V.; Garg, Alka B.; Godwal, B. K.; Sikka, S. K.
2001-03-01
Results of angle dispersive x-ray powder diffraction measurements under pressure up to 25 GPa on adamantane carried out at the synchrotron source SPRING-8 are reported. The disorder-order transition at 0.5 GPa in adamantane known earlier is reproduced with detailed structural information. For this ordered tetragonal (Pφ) of the two molecules within the cell about the c-axis increases from 8.5° to 10.5°. This is consistent with values determined from energy minimization in this pressure region. The anomaly in the pressure variation of c/a, and the failure of the constrained Rietveld refinement, occurring close to 9 GPa, are interpreted as due to distortion of the adamantane molecule when H...H distance decreases below the critical value of 1.9 Å. Above 16 GPa there is a subtle change in the diffraction pattern that indicates a transition to a closely related phase. Beyond 22 GPa, a monoclinic phase with one molecule per cell could only index the patterns. The ambient cubic phase is recovered on unloading indicating the absence of decomposition or polymerization. The results of high pressure x-ray diffraction experiments confirm the changes in the Raman spectra observed in the earlier measurements.
Lemasson, Elise; Bertin, Sophie; Hennig, Philippe; Boiteux, Hélène; Lesellier, Eric; West, Caroline
2015-08-21
Supercritical fluid chromatography (SFC) is a very useful tool in the purpose of impurity profiling of drug candidates, as an adequate selection of stationary phases can provide orthogonal separations so as to maximize the chances to see all impurities. The purpose of the present work is to develop a method for chemical purity assessment. The first part, presented here, focuses on mobile phase selection to ensure adequate elution and detection of drug-like molecules, while the second part focuses on stationary phase selection for optimal separation and orthogonality. The use of additives in the carbon dioxide - solvent mobile phase in SFC is now commonplace, and enables in particular to increase the number of eluted compounds and to improve peak shapes. The objective of this first part was to test different additives (acids, bases, salts and water) for their chromatographic performance assessed in gradient elution with a diode-array detector, but also for the mass responses obtained with a single-quadrupole mass detector, equipped with an electrospray ionization source (Waters ACQUITY QDa). In this project, we used a selection of one hundred and sixty compounds issued from Servier Research Laboratories to screen a set of columns and additives in SFC with a Waters ACQUITY UPC(2) system. The selected columns were all high-performance columns (1.7-1.8μm with totally porous particles or 2.6-2.7μm with superficially porous particles) with a variety of stationary phase chemistries. Initially, eight additives dissolved in the methanol co-solvent were tested on a UPC(2) ACQUITY UPC(2) HSS C18 SB column. A Derringer desirability function was used to classify the additives according to selected criteria: elution capability, peak shapes, UV baseline drift, and UV and mass responses (signal-to-noise ratios). Following these tests, the two best additives (ammonium acetate and ammonium hydroxide) were tested on a larger number of columns (10) where the two additives appeared
Q-band 4-state phase shifter in planar technology: Circuit design and performance analysis
NASA Astrophysics Data System (ADS)
Villa, E.; Cagigas, J.; Aja, B.; de la Fuente, L.; Artal, E.
2016-09-01
A 30% bandwidth phase shifter with four phase states is designed to be integrated in a radio astronomy receiver. The circuit has two 90° out-of-phase microwave phase-shifting branches which are combined by Wilkinson power dividers. Each branch is composed of a 180° phase shifter and a band-pass filter. The 180° phase shifter is made of cascaded hybrid rings with microwave PIN diodes as switching devices. The 90° phase shift is achieved with the two band-pass filters. Experimental characterization has shown significant results, with average phase shift values of -90.7°, -181.7°, and 88.5° within the operation band, 35-47 GHz, and mean insertion loss of 7.4 dB. The performance of its integration in a polarimetric receiver for radio astronomy is analyzed, which validates the use of the presented phase shifter in such type of receiver.
Discontinuous phase transition in an annealed multi-state majority-vote model
NASA Astrophysics Data System (ADS)
Li, Guofeng; Chen, Hanshuang; Huang, Feng; Shen, Chuansheng
2016-07-01
In this paper, we generalize the original majority-vote (MV) model with noise from two states to arbitrary q states, where q is an integer no less than two. The main emphasis is paid to the comparison on the nature of phase transitions between the two-state MV (MV2) model and the three-state MV (MV3) model. By extensive Monte Carlo simulation and mean-field analysis, we find that the MV3 model undergoes a discontinuous order-disorder phase transition, in contrast to a continuous phase transition in the MV2 model. A central feature of such a discontinuous transition is a strong hysteresis behavior as noise intensity goes forward and backward. Within the hysteresis region, the disordered phase and ordered phase are coexisting.
Amplitude-phase coupling drives chimera states in globally coupled laser networks.
Böhm, Fabian; Zakharova, Anna; Schöll, Eckehard; Lüdge, Kathy
2015-04-01
For a globally coupled network of semiconductor lasers with delayed optical feedback, we demonstrate the existence of chimera states. The domains of coherence and incoherence that are typical for chimera states are found to exist for the amplitude, phase, and inversion of the coupled lasers. These chimera states defy several of the previously established existence criteria. While chimera states in phase oscillators generally demand nonlocal coupling, large system sizes, and specially prepared initial conditions, we find chimera states that are stable for global coupling in a network of only four coupled lasers for random initial conditions. The existence is linked to a regime of multistability between the synchronous steady state and asynchronous periodic solutions. We show that amplitude-phase coupling, a concept common in different fields, is necessary for the formation of the chimera states.
NASA Astrophysics Data System (ADS)
Andreae, M. O.; Artaxo, P.; Bechtel, M.; Förster, J. D.; Kilcoyne, A. L. D.; Krüger, M. L.; Pöhlker, C.; Saturno, J.; Weigand, M.; Wiedemann, K. T.
2014-12-01
Atmospheric aerosols play a crucial role in the Earth's climate system and hydrological cycle by scattering and absorbing sunlight and affecting the formation and development of clouds and precipitation. Our research focuses on aerosols in remote regions, in order to characterize the properties and sources of natural aerosol particles and the extent of human perturbations of the aerosol burden. The phase and mixing state of atmospheric aerosols, and particularly their hygroscopic response to relative humidity (RH) variations, is a central determinant of their atmospheric life cycle and impacts. We present an investigation using X-ray microspectroscopy on submicrometer aerosols under variable RH conditions, showing in situ changes in morphology, microstructure, and phase state upon humidity cycling. We applied Scanning Transmission X-ray Microscopy with Near-Edge X-ray Absorption Fine Structure spectroscopy (STXM-NEXAFS) under variable RH conditions to standard aerosols for a validation of the experimental approach and to internally mixed aerosol particles from the Amazonian rain forest collected during periods with anthropogenic pollution. The measurements were conducted at X-ray microscopes at the synchrotron facilities Advanced Light Source (ALS) in Berkeley, USA, and BESSY II in Berlin, Germany. Upon hydration, we observed substantial and reproducible changes in microstructure of the Amazonian particles (internal mixture of secondary organic material, ammoniated sulfate, and soot), which appear as mainly driven by efflorescence and recrystallization of sulfate salts. Multiple solid and liquid phases were found to coexist, especially in intermediate humidity regimes (60-80% RH). This shows that X-ray microspectroscopy under variable RH is a valuable technique to analyze the hygroscopic response of individual ambient aerosol particles. Our initial results underline that RH changes can trigger strong particle restructuring, in agreement with previous studies on
Phase diagram of quantum critical system via local convertibility of ground state
Liu, Si-Yuan; Quan, Quan; Chen, Jin-Jun; Zhang, Yu-Ran; Yang, Wen-Li; Fan, Heng
2016-01-01
We investigate the relationship between two kinds of ground-state local convertibility and quantum phase transitions in XY model. The local operations and classical communications (LOCC) convertibility is examined by the majorization relations and the entanglement-assisted local operations and classical communications (ELOCC) via Rényi entropy interception. In the phase diagram of XY model, LOCC convertibility and ELOCC convertibility of ground-states are presented and compared. It is shown that different phases in the phase diagram of XY model can have different LOCC or ELOCC convertibility, which can be used to detect the quantum phase transition. This study will enlighten extensive studies of quantum phase transitions from the perspective of local convertibility, e.g., finite-temperature phase transitions and other quantum many-body models. PMID:27381284
Phase diagram of quantum critical system via local convertibility of ground state.
Liu, Si-Yuan; Quan, Quan; Chen, Jin-Jun; Zhang, Yu-Ran; Yang, Wen-Li; Fan, Heng
2016-01-01
We investigate the relationship between two kinds of ground-state local convertibility and quantum phase transitions in XY model. The local operations and classical communications (LOCC) convertibility is examined by the majorization relations and the entanglement-assisted local operations and classical communications (ELOCC) via Rényi entropy interception. In the phase diagram of XY model, LOCC convertibility and ELOCC convertibility of ground-states are presented and compared. It is shown that different phases in the phase diagram of XY model can have different LOCC or ELOCC convertibility, which can be used to detect the quantum phase transition. This study will enlighten extensive studies of quantum phase transitions from the perspective of local convertibility, e.g., finite-temperature phase transitions and other quantum many-body models.
Loss resilience for two-qubit state transmission using distributed phase sensitive amplification
Dailey, James; Agarwal, Anjali; Toliver, Paul; Peters, Nicholas A.
2015-11-12
We transmit phase-encoded non-orthogonal quantum states through a 5-km long fibre-based distributed optical phase-sensitive amplifier (OPSA) using telecom-wavelength photonic qubit pairs. The gain is set to equal the transmission loss to probabilistically preserve input states during transmission. While neither state is optimally aligned to the OPSA, each input state is equally amplified with no measurable degradation in state quality. These results promise a new approach to reduce the effects of loss by encoding quantum information in a two-qubit Hilbert space which is designed to benefit from transmission through an OPSA.
Formation of physically stable amorphous phase of ibuprofen by solid state milling with kaolin.
Mallick, Subrata; Pattnaik, Satyanarayan; Swain, Kalpana; De, Pintu K; Saha, Arindam; Ghoshal, Gaurisankar; Mondal, Arijit
2008-02-01
Ibuprofen was milled in the solid state with kaolin (hydrated aluminium silicate) in different ratio to examine the extent of transformation from crystalline to amorphous state. The physical stability of the resultant drug was also investigated. X-ray powder diffractometry (XRD) and birefringence by Scanning Electron Microscopy (SEM) studies indicated almost complete amorphization of the drug on ball milling with kaolin at 1:2 ratio. Fourier transform infrared spectroscopy (FTIR) data showed a reduction in the absorbance of the free and the hydrogen-bonded acid carbonyl peak of carboxylic acid group accompanied by a corresponding increase in the absorbance of the carboxylate peak, indicating an acid-base reaction between the carboxylic acid containing ibuprofen and kaolin on milling. The extent of amorphization and reduction in the carbonyl peak and increase in carboxylate peak was a function of kaolin concentration in the milled powder. On storage of milled powder (at 40 degrees C and 75% RH for 10 weeks), XRD and birefringence of SEM study showed the absence of reversion to the crystalline state and FTIR data revealed continued reduction of carbonyl peak, whereas, ibuprofen converted from its crystalline acid form to amorphous salt form on milling with kaolin. Kaolin-bound state of ibuprofen was physically stable during storage. In-vitro dissolution studies revealed that percent release of ibuprofen from the kaolin co-milled powder is in the order: 1:2>1:1>1:0.5>1:0.1>milled alone ibuprofen>crystalline ibuprofen.
Semiclassical States Associated with Isotropic Submanifolds of Phase Space
NASA Astrophysics Data System (ADS)
Guillemin, V.; Uribe, A.; Wang, Z.
2016-05-01
We define classes of quantum states associated with isotropic submanifolds of cotangent bundles. The classes are stable under the action of semiclassical pseudo-differential operators and covariant under the action of semiclassical Fourier integral operators. We develop a symbol calculus for them; the symbols are symplectic spinors. We outline various applications.
Entropy, chaos, and excited-state quantum phase transitions in the Dicke model.
Lóbez, C M; Relaño, A
2016-07-01
We study nonequilibrium processes in an isolated quantum system-the Dicke model-focusing on the role played by the transition from integrability to chaos and the presence of excited-state quantum phase transitions. We show that both diagonal and entanglement entropies are abruptly increased by the onset of chaos. Also, this increase ends in both cases just after the system crosses the critical energy of the excited-state quantum phase transition. The link between entropy production, the development of chaos, and the excited-state quantum phase transition is more clear for the entanglement entropy. PMID:27575109
Entropy, chaos, and excited-state quantum phase transitions in the Dicke model
NASA Astrophysics Data System (ADS)
Lóbez, C. M.; Relaño, A.
2016-07-01
We study nonequilibrium processes in an isolated quantum system—the Dicke model—focusing on the role played by the transition from integrability to chaos and the presence of excited-state quantum phase transitions. We show that both diagonal and entanglement entropies are abruptly increased by the onset of chaos. Also, this increase ends in both cases just after the system crosses the critical energy of the excited-state quantum phase transition. The link between entropy production, the development of chaos, and the excited-state quantum phase transition is more clear for the entanglement entropy.
Edge states at phase boundaries and their stability
NASA Astrophysics Data System (ADS)
Asorey, M.; Balachandran, A. P.; Pérez-Pardo, J. M.
2016-10-01
We analyze the effects of Robin-like boundary conditions on different quantum field theories of spin 0, 1/2 and 1 on manifolds with boundaries. In particular, we show that these conditions often lead to the appearance of edge states. These states play a significant role in physical phenomena like quantum Hall effect and topological insulators. We prove in a rigorous way the existence of spectral lower bounds on the kinetic term of different Hamiltonians, even in the case of Abelian gauge fields where it is a non-elliptic differential operator. This guarantees the stability and consistency of massive field theories with masses larger than the lower bound of the kinetic term. Moreover, we find an upper bound for the deepest edge state. In the case of Abelian gauge theories, we analyze a generalization of Robin boundary conditions. For Dirac fermions, we analyze the cases of Atiyah-Patodi-Singer and chiral bag boundary conditions. The explicit dependence of the bounds on the boundary conditions and the size of the system is derived under general assumptions.
NASA Astrophysics Data System (ADS)
Kuo, Yen-Kuang; Chang, Yi-An
2003-03-01
In a previous work [Appl. Phys. Lett. 65 , 3060 (1994) we experimentally demonstrated that passive ]Q switching of a 2017-nm, flashlamp-pumped Tm,Cr:YAG laser with a Ho:YLF saturable absorber could be obtained with an internal focusing lens. We numerically investigate the optical performance of the Ho:YLF Q -switched Tm:YAG laser system by solving the coupled rate equations. The simulation results indicate that the results obtained numerically are in good agreement with those obtained experimentally. With typical laser configuration, a Q -switched laser pulse of 35 mJ in 30 ns is obtained.
Ground-state phase diagram of the one-dimensional half-filled extended Hubbard model
NASA Astrophysics Data System (ADS)
Tsuchiizu, M.; Furusaki, A.
2004-01-01
We revisit the ground-state phase diagram of the one-dimensional half-filled extended Hubbard model with on-site (U) and nearest-neighbor (V) repulsive interactions. In the first half of the paper, using the weak-coupling renormalization-group approach (g-ology) including second-order corrections to the coupling constants, we show that bond-charge-density-wave (BCDW) phase exists for U≈2V in between charge-density-wave (CDW) and spin-density-wave (SDW) phases. We find that the umklapp scattering of parallel-spin electrons disfavors the BCDW state and leads to a bicritical point where the CDW-BCDW and SDW-BCDW continuous-transition lines merge into the CDW-SDW first-order transition line. In the second half of the paper, we investigate the phase diagram of the extended Hubbard model with either additional staggered site potential Δ or bond alternation δ. Although the alternating site potential Δ strongly favors the CDW state (that is, a band insulator), the BCDW state is not destroyed completely and occupies a finite region in the phase diagram. Our result is a natural generalization of the work by Fabrizio, Gogolin, and Nersesyan [Phys. Rev. Lett. 83, 2014 (1999)], who predicted the existence of a spontaneously dimerized insulating state between a band insulator and a Mott insulator in the phase diagram of the ionic Hubbard model. The bond alternation δ destroys the SDW state and changes it into the BCDW state (or Peierls insulating state). As a result the phase diagram of the model with δ contains only a single critical line separating the Peierls insulator phase and the CDW phase. The addition of Δ or δ changes the universality class of the CDW-BCDW transition from the Gaussian transition into the Ising transition.
Emanuelsson, Eva U; Tschiskale, Morten; Bilde, Merete
2016-09-15
meso-Erythritol is a sugar alcohol identified in atmospheric aerosol particles. In this work, evaporation of submicron-sized particles of meso-erythritol was studied in a TDMA system including a laminar flow tube under dry conditions at five temperatures (278-308 K) and ambient pressure. A complex behavior was observed and attributed to the formation of particles of three different phase states: (1) crystalline, (2) subcooled liquid or amorphous, and (3) mixed. With respect to saturation vapor pressure, the subcooled liquid and amorphous states are treated to be the same. The particle phase state was linked to initial particle size and flow tube temperature. Saturation vapor pressures of two phase states attributed to the crystalline and subcooled liquid state respectively are reported. Our results suggest a mass accommodation coefficient close to one for both states. PMID:27525492
Emanuelsson, Eva U; Tschiskale, Morten; Bilde, Merete
2016-09-15
meso-Erythritol is a sugar alcohol identified in atmospheric aerosol particles. In this work, evaporation of submicron-sized particles of meso-erythritol was studied in a TDMA system including a laminar flow tube under dry conditions at five temperatures (278-308 K) and ambient pressure. A complex behavior was observed and attributed to the formation of particles of three different phase states: (1) crystalline, (2) subcooled liquid or amorphous, and (3) mixed. With respect to saturation vapor pressure, the subcooled liquid and amorphous states are treated to be the same. The particle phase state was linked to initial particle size and flow tube temperature. Saturation vapor pressures of two phase states attributed to the crystalline and subcooled liquid state respectively are reported. Our results suggest a mass accommodation coefficient close to one for both states.
Ground states of stealthy hyperuniform potentials. II. Stacked-slider phases
NASA Astrophysics Data System (ADS)
Zhang, G.; Stillinger, F. H.; Torquato, S.
2015-08-01
Stealthy potentials, a family of long-range isotropic pair potentials, produce infinitely degenerate disordered ground states at high densities and crystalline ground states at low densities in d -dimensional Euclidean space Rd. In the previous paper in this series, we numerically studied the entropically favored ground states in the canonical ensemble in the zero-temperature limit across the first three Euclidean space dimensions. In this paper, we investigate using both numerical and theoretical techniques metastable stacked-slider phases, which are part of the ground-state manifold of stealthy potentials at densities in which crystal ground states are favored entropically. Our numerical results enable us to devise analytical models of this phase in two, three, and higher dimensions. Utilizing this model, we estimated the size of the feasible region in configuration space of the stacked-slider phase, finding it to be smaller than that of crystal structures in the infinite-system-size limit, which is consistent with our recent previous work. In two dimensions, we also determine exact expressions for the pair correlation function and structure factor of the analytical model of stacked-slider phases and analyze the connectedness of the ground-state manifold of stealthy potentials in this density regime. We demonstrate that stacked-slider phases are distinguishable states of matter; they are nonperiodic, statistically anisotropic structures that possess long-range orientational order but have zero shear modulus. We outline some possible future avenues of research to elucidate our understanding of this unusual phase of matter.
Ye Jinwu; Zhang Cunlin
2011-08-15
Recently, strong-coupling regimes of superconducting qubits or quantum dots inside a microwave circuit cavity and BEC atoms inside an optical cavity were achieved experimentally. The strong-coupling regimes in these systems were described by the Dicke model. Here, we solve the Dicke model by a 1/N expansion. In the normal state, we find a {radical}(N) behavior of the collective Rabi splitting. In the superradiant phase, we identify an important Berry phase term that has dramatic effects on both the ground state and the excitation spectra of the strongly interacting system. The single photon excitation spectrum has a low-energy quantum phase diffusion mode in imaginary time with a large spectral weight and also a high-energy optical mode with a low spectral weight. The photons are in a number squeezed state that may have wide applications in high sensitive measurements and quantum-information processing. Comparisons with exact diagonalization studies are made. Possible experimental schemes to realize the superradiant phase are briefly discussed.
NASA Astrophysics Data System (ADS)
Park, Jun Seong; Seo, Jinu; Park, Sang Wook; Jung, Woo Jin; Park, Nae Man; Kim, Jeha; Jeon, Chan Wook
2012-10-01
Among many key parameters required to obtain a record-efficiency Cu(In,Ga)Se2 (CIGS) cell, the band-gap of CIGS should have a double-graded profile in which the band-gap increases toward both of the back and front of the absorber. In an effort to obtain an increased Ga content near the junction area which will raise the band-gap energy of CIGS, a novel metal precursor layered with predetermined amount of Se was annealed in N2 ambient. By inserting the Se layer in between metallic precursor layers, it was found that the front band-gap was increased due to the high Ga content by changing the direction of selenization reaction from inside to outside of metallic precursor. The proposed method is expected to provide a simple process for high quality CIGS photovoltaic absorber layer. The conversion efficiency of 6.80% with Jsc = 37.65 mA/cm2, Voc = 0.51 V, and FF= 35.4% in an active area of 0.48 cm2 was achieved.
Fingerprint of topological Andreev bound states in phase-dependent heat transport
NASA Astrophysics Data System (ADS)
Sothmann, Björn; Hankiewicz, Ewelina M.
2016-08-01
We demonstrate that phase-dependent heat currents through superconductor-topological insulator Josephson junctions provide a useful tool to probe the existence of topological Andreev bound states, even for multichannel surface states. We predict that in the tunneling regime topological Andreev bound states lead to a minimum of the thermal conductance for a phase difference ϕ =π , in clear contrast to a maximum of the thermal conductance at ϕ =π that occurs for trivial Andreev bound states in superconductor-normal-metal tunnel junctions. This opens up the possibility that phase-dependent heat transport can distinguish between topologically trivial and nontrivial 4 π modes. Furthermore, we propose a superconducting quantum interference device geometry where phase-dependent heat currents can be measured using available experimental technology.
Detecting critical state before phase transition of complex systems by hidden Markov model
NASA Astrophysics Data System (ADS)
Liu, Rui; Chen, Pei; Li, Yongjun; Chen, Luonan
Identifying the critical state or pre-transition state just before the occurrence of a phase transition is a challenging task, because the state of the system may show little apparent change before this critical transition during the gradual parameter variations. Such dynamics of phase transition is generally composed of three stages, i.e., before-transition state, pre-transition state, and after-transition state, which can be considered as three different Markov processes. Thus, based on this dynamical feature, we present a novel computational method, i.e., hidden Markov model (HMM), to detect the switching point of the two Markov processes from the before-transition state (a stationary Markov process) to the pre-transition state (a time-varying Markov process), thereby identifying the pre-transition state or early-warning signals of the phase transition. To validate the effectiveness, we apply this method to detect the signals of the imminent phase transitions of complex systems based on the simulated datasets, and further identify the pre-transition states as well as their critical modules for three real datasets, i.e., the acute lung injury triggered by phosgene inhalation, MCF-7 human breast cancer caused by heregulin, and HCV-induced dysplasia and hepatocellular carcinoma.
Simplified formula for mean cycle-slip time of phase-locked loops with steady-state phase error.
NASA Technical Reports Server (NTRS)
Tausworthe, R. C.
1972-01-01
Previous work shows that the mean time from lock to a slipped cycle of a phase-locked loop is given by a certain double integral. Accurate numerical evaluation of this formula for the second-order loop is extremely vexing because the difference between exponentially large quantities is involved. The presented article demonstrates a method in which a much-reduced precision program can be used to obtain the mean first-cycle slip time for a loop of arbitrary degree tracking at a specified SNR and steady-state phase error. It also presents a simple approximate formula that is asymptotically tight at higher loop SNR.
Density and Phase State of a Confined Nonpolar Fluid
NASA Astrophysics Data System (ADS)
Kienle, Daniel F.; Kuhl, Tonya L.
2016-07-01
Measurements of the mean refractive index of a spherelike nonpolar fluid, octamethytetracylclosiloxane (OMCTS), confined between mica sheets, demonstrate direct and conclusive experimental evidence of the absence of a first-order liquid-to-solid phase transition in the fluid when confined, which has been suggested to occur from previous experimental and simulation results. The results also show that the density remains constant throughout confinement, and that the fluid is incompressible. This, along with the observation of very large increases (many orders of magnitude) in viscosity during confinement from the literature, demonstrate that the molecular motion is limited by the confining wall and not the molecular packing. In addition, the recently developed refractive index profile correction method, which enables the structural perturbation inherent at a solid-liquid interface and that of a liquid in confinement to be determined independently, was used to show that there was no measurable excess or depleted mass of OMCTS near the mica surface in bulk films or confined films of only two molecular layers.
Density and Phase State of a Confined Nonpolar Fluid.
Kienle, Daniel F; Kuhl, Tonya L
2016-07-15
Measurements of the mean refractive index of a spherelike nonpolar fluid, octamethytetracylclosiloxane (OMCTS), confined between mica sheets, demonstrate direct and conclusive experimental evidence of the absence of a first-order liquid-to-solid phase transition in the fluid when confined, which has been suggested to occur from previous experimental and simulation results. The results also show that the density remains constant throughout confinement, and that the fluid is incompressible. This, along with the observation of very large increases (many orders of magnitude) in viscosity during confinement from the literature, demonstrate that the molecular motion is limited by the confining wall and not the molecular packing. In addition, the recently developed refractive index profile correction method, which enables the structural perturbation inherent at a solid-liquid interface and that of a liquid in confinement to be determined independently, was used to show that there was no measurable excess or depleted mass of OMCTS near the mica surface in bulk films or confined films of only two molecular layers. PMID:27472123
One-Dimensional Three-State Quantum Walk with Single-Point Phase Defects
NASA Astrophysics Data System (ADS)
Xu, Yong-Zhen; Guo, Gong-De; Lin, Song
2016-09-01
In this paper, we study a three-state quantum walk with a phase defect at a designated position. The coin operator is a parametrization of the eigenvectors of the Grover matrix. We numerically investigate the properties of the proposed model via the position probability distribution, the position standard deviation, and the time-averaged probability at the designated position. It is shown that the localization effect can be governed by the phase defect's position and strength, coin parameter and initial state.
Phase states of a 2D easy-plane ferromagnet with strong inclined anisotropy
Fridman, Yu. A. Klevets, F. N.; Gorelikov, G. A.; Meleshko, A. G.
2012-12-15
We investigate the spin states of a 2D film exhibiting easy-axis anisotropy and a strong single-ion inclined anisotropy whose axis forms a certain angle with the normal to the film surface. Such a system may have an angular ferromagnetic phase, a spatially inhomogeneous state, and a quadrupole phase, whose realization depends substantially on the inclined anisotropy and the orientation of the wavevector in the film plane.
SESAME 96171, a three-phase equation of state for CeO2
Chisolm, Eric D.; Day, Christy M.
2014-06-25
We describe an equation of state (EOS) for cerium (IV) oxide, CeO_{2}, that includes two solid phases and the liquid. The models and parameters used to calculate the EOS are presented in detail, and we compare with data for both crystal phases and ambient melt. We discuss complications that arise when making multiphase EOS.
Geometric phases for laser-induced aligned pendular states of linear molecules
Aleynikov, Dmitriy V.
2006-02-15
Geometric phases may arise in a linear molecule interacting via its anisotropic polarizability with a strong nonresonant laser field. When the polarization vector of laser radiation undergoes cyclic evolution, the molecule returns to its original state but may acquire a Berry or Aharonov-Anandan phase factor.
On the Finiteness of Collisions and Phase-Locked States for the Kuramoto Model
NASA Astrophysics Data System (ADS)
Ha, Seung-Yeal; Kim, Hwa Kil; Ryoo, Sang Woo
2016-06-01
Synchronization phenomenon is ubiquitous in our complex systems, and many phenomenological models have been proposed and studied analytically and numerically. Among them, the Kuramoto model serves as a prototype model for the phase synchronization of weakly coupled oscillators. In this paper, we study the finiteness of collisions (crossings) among Kuramoto oscillators in the relaxation process toward the phase-locked states and the total number of phase-locked states with positive (Kuramoto) order parameters. For identical oscillators, it is well known that collisions between distinct oscillators cannot occur in finite-time, and we show that there are only a finite number of phase-locked states with positive order parameters. However, for non-identical oscillators, oscillators with different natural frequencies can cross each other in their relaxation process, and estimating the total number of phase-locked states is a nontrivial matter. We show that, for the non-identical case, asymptotic phase-locking is equivalent to the finiteness of collisions, and the total number of phase-locked states with positive order parameters is bounded above by 2^N, where N is the number of oscillators.
NASA Technical Reports Server (NTRS)
Wesselski, Clarence J. (Inventor)
1993-01-01
An energy absorbing system for controlling the force where a moving object engages a stationary stop and where the system utilized telescopic tubular members, energy absorbing diaphragm elements, force regulating disc springs, and a return spring to return the telescoping member to its start position after stroking is presented. The energy absorbing system has frusto-conical diaphragm elements frictionally engaging the shaft and are opposed by a force regulating set of disc springs. In principle, this force feedback mechanism serves to keep the stroking load at a reasonable level even if the friction coefficient increases greatly. This force feedback device also serves to desensitize the singular and combined effects of manufacturing tolerances, sliding surface wear, temperature changes, dynamic effects, and lubricity.
The in-phase states of Josephson junctions stacks as attractors
Hristov, I.; Dimova, S.; Hristova, R.
2014-11-12
The aim of this investigation is to show that the coherent, in-phase states of intrinsic Josephson junctions stacks are attractors of the stacks' states when the applied external magnetic field h{sub e} and the external current γ vary within certain domains. Mathematically the problem is to find the solutions of the system of perturbed sine-Gordon equations for fixed other parameters and zero or random initial conditions. We determine the region in the plane (h{sub e}, γ), where the in-phase states are attractors of the stack's states for arbitrary initial perturbations. This is important, because the in-phase states are required for achieving terahertz radiation from the Josephson stacks.
Comparison of time/phase lags in the hard state and plateau state of GRS 1915+105
Pahari, Mayukh; Yadav, J. S.; Neilsen, Joseph; Misra, Ranjeev; Uttley, Phil
2013-12-01
We investigate the complex behavior of energy- and frequency-dependent time/phase lags in the plateau state and the radio-quiet hard (χ) state of GRS 1915+105. In our timing analysis, we find that when the source is faint in the radio, quasi-periodic oscillations (QPOs) are observed above 2 Hz and typically exhibit soft lags (soft photons lag hard photons), whereas QPOs in the radio-bright plateau state are found below 2.2 Hz and consistently show hard lags. The phase lag at the QPO frequency is strongly anti-correlated with that frequency, changing sign at 2.2 Hz. However, the phase lag at the frequency of the first harmonic is positive and nearly independent of that frequency at ∼0.172 rad, regardless of the radio emission. The lag energy dependence at the first harmonic is also independent of radio flux. However, the lags at the QPO frequency are negative at all energies during the radio-quiet state, but lags at the QPO frequency during the plateau state are positive at all energies and show a 'reflection-type' evolution of the lag energy spectra with respect to the radio-quiet state. The lag energy dependence is roughly logarithmic, but there is some evidence for a break around 4-6 keV. Finally, the Fourier-frequency-dependent phase lag spectra are fairly flat during the plateau state, but increase from negative to positive during the radio-quiet state. We discuss the implications of our results in light of some generic models.
Phase boundary of spin-polarized-current state of electrons in bilayer graphene
NASA Astrophysics Data System (ADS)
Yan, Xin-Zhong; Ma, Yinfeng; Ting, C. S.
2016-06-01
Using a four-band Hamiltonian, we study the phase boundary of spin-polarized-current state (SPCS) of interacting electrons in bilayer graphene. The model of spin-polarized-current state has previously been shown to resolve a number of experimental puzzles in bilayer graphene. The phase boundaries of the SPCS with and without the external voltage between the two layers are obtained in this work. An unusual phase boundary where there are two transition temperatures for a given carrier concentration is found at finite external voltage. The physics of this phenomenon is explained.
Circular polarization sensitive absorbers based on graphene
Yang, Kunpeng; Wang, Min; Pu, Mingbo; Wu, Xiaoyu; Gao, Hui; Hu, Chenggang; Luo, Xiangang
2016-01-01
It is well known that the polarization of a linearly polarized (LP) light would rotate after passing through a single layer graphene under the bias of a perpendicular magnetostatic field. Here we show that a corresponding phase shift could be expected for circularly polarized (CP) light, which can be engineered to design the circular polarization sensitive devices. We theoretically validate that an ultrathin graphene-based absorber with the thickness about λ/76 can be obtained, which shows efficient absorption >90% within incident angles of ±80°. The angle-independent phase shift produced by the graphene is responsible for the nearly omnidirectional absorber. Furthermore, a broadband absorber in frequencies ranging from 2.343 to 5.885 THz with absorption over 90% is designed by engineering the dispersion of graphene. PMID:27034257
Canted antiferromagnetic phase of the ν=0 quantum Hall state in bilayer graphene.
Kharitonov, Maxim
2012-07-27
Motivated to understand the nature of the strongly insulating ν=0 quantum Hall state in bilayer graphene, we develop the theory of the state in the framework of quantum Hall ferromagnetism. The generic phase diagram, obtained in the presence of the isospin anisotropy, perpendicular electric field, and Zeeman effect, consists of the spin-polarized ferromagnetic (F), canted antiferromagnetic (CAF), and partially (PLP) and fully (FLP) layer-polarized phases. We address the edge transport properties of the phases. Comparing our findings with the recent data on suspended dual-gated devices, we conclude that the insulating ν=0 state realized in bilayer graphene at lower electric field is the CAF phase. We also predict a continuous and a sharp insulator-metal phase transition upon tilting the magnetic field from the insulating CAF and FLP phases, respectively, to the F phase with metallic edge conductance 2e(2)/h, which could be within the reach of available fields and could allow one to identify and distinguish the phases experimentally.
Bilayer quantum Hall phase transitions and the orbifold non-Abelian fractional quantum Hall states
NASA Astrophysics Data System (ADS)
Barkeshli, Maissam; Wen, Xiao-Gang
2011-09-01
We study continuous quantum phase transitions that can occur in bilayer fractional quantum Hall (FQH) systems as the interlayer tunneling and interlayer repulsion are tuned. We introduce a slave-particle gauge theory description of a series of continuous transitions from the (ppq) Abelian bilayer states to a set of non-Abelian FQH states, which we dub orbifold FQH states, of which the Z4 parafermion (Read-Rezayi) state is a special case. This provides an example in which Z2 electron fractionalization leads to non-Abelian topological phases. The naive “ideal” wave functions and ideal Hamiltonians associated with these orbifold states do not in general correspond to incompressible phases but, instead, lie at a nearby critical point. We discuss this unusual situation from the perspective of the pattern-of-zeros/vertex algebra frameworks and discuss implications for the conceptual foundations of these approaches. Due to the proximity in the phase diagram of these non-Abelian states to the (ppq) bilayer states, they may be experimentally relevant, both as candidates for describing the plateaus in single-layer systems at filling fractions 8/3 and 12/5 and as a way to tune to non-Abelian states in double-layer or wide quantum wells.
Geometric quantum phase for displaced states for a particle with an induced electric dipole moment
NASA Astrophysics Data System (ADS)
Lemos de Melo, J.; Bakke, K.; Furtado, C.
2016-07-01
Basing on the analogue Landau levels for a neutral particle possessing an induced electric dipole moment, we show that displaced states can be built in the presence of electric and magnetic fields. Besides, the Berry phase associated with these displaced quantum states is obtained by performing an adiabatic cyclic evolution in series of paths in parameter space.
Bilayer quantum Hall phase transitions and the orbifold non-Abelian fractional quantum Hall states
Barkeshli, Maissam; Wen Xiaogang
2011-09-15
We study continuous quantum phase transitions that can occur in bilayer fractional quantum Hall (FQH) systems as the interlayer tunneling and interlayer repulsion are tuned. We introduce a slave-particle gauge theory description of a series of continuous transitions from the (ppq) Abelian bilayer states to a set of non-Abelian FQH states, which we dub orbifold FQH states, of which the Z{sub 4} parafermion (Read-Rezayi) state is a special case. This provides an example in which Z{sub 2} electron fractionalization leads to non-Abelian topological phases. The naive ''ideal'' wave functions and ideal Hamiltonians associated with these orbifold states do not in general correspond to incompressible phases but, instead, lie at a nearby critical point. We discuss this unusual situation from the perspective of the pattern-of-zeros/vertex algebra frameworks and discuss implications for the conceptual foundations of these approaches. Due to the proximity in the phase diagram of these non-Abelian states to the (ppq) bilayer states, they may be experimentally relevant, both as candidates for describing the plateaus in single-layer systems at filling fractions 8/3 and 12/5 and as a way to tune to non-Abelian states in double-layer or wide quantum wells.
Mizia, Ronald E.; Shaber, Eric L.; DuPont, John N.; Robino, Charles V.; Williams, David B.
2004-05-04
The present invention is drawn to new classes of advanced neutron absorbing structural materials for use in spent nuclear fuel applications requiring structural strength, weldability, and long term corrosion resistance. Particularly, an austenitic stainless steel alloy containing gadolinium and less than 5% of a ferrite content is disclosed. Additionally, a nickel-based alloy containing gadolinium and greater than 50% nickel is also disclosed.
NASA Technical Reports Server (NTRS)
Von Tiesenhausen, G. F.
1976-01-01
Collector/energy converter, consisting of dual-slope optical concentrator and counterflow thermal energy absorber, is attached to multiaxis support structure. Efficient over wide range of illumination levels, device may be used to generate high temperature steam, serve as solar powered dryer, or power absorption cycle cooler.
NASA Technical Reports Server (NTRS)
Han, D.; Kim, Y. S.; Noz, Marilyn E.
1990-01-01
It is shown that the basic symmetry of two-mode squeezed states is governed by the group SP(4) in the Wigner phase space which is locally isomorphic to the (3 + 2)-dimensional Lorentz group. This symmetry, in the Schroedinger picture, appears as Dirac's two-oscillator representation of O(3,2). It is shown that the SU(2) and SU(1,1) interferometers exhibit the symmetry of this higher-dimensional Lorentz group. The mathematics of two-mode squeezed states is shown to be applicable to other branches of physics including thermally excited states in statistical mechanics and relativistic extended hadrons in the quark model.
Exploring the phase space of multiple states in highly turbulent Taylor-Couette flow
NASA Astrophysics Data System (ADS)
van der Veen, Roeland C. A.; Huisman, Sander G.; Dung, On-Yu; Tang, Ho L.; Sun, Chao; Lohse, Detlef
2016-06-01
We investigate the existence of multiple turbulent states in highly turbulent Taylor-Couette flow in the range of Ta =1011 to 9 ×1012 by measuring the global torques and the local velocities while probing the phase space spanned by the rotation rates of the inner and outer cylinders. The multiple states are found to be very robust and are expected to persist beyond Ta =1013 . The rotation ratio is the parameter that most strongly controls the transitions between the flow states; the transitional values only weakly depend on the Taylor number. However, complex paths in the phase space are necessary to unlock the full region of multiple states. By mapping the flow structures for various rotation ratios in a Taylor-Couette setup with an equal radius ratio but a larger aspect ratio than before, multiple states are again observed. Here they are characterized by even richer roll structure phenomena, including an antisymmetrical roll state.
The steady-state phase distribution of the motor switch complex model of Halobacterium salinarum.
del Rosario, Ricardo C H; Diener, Francine; Diener, Marc; Oesterhelt, Dieter
2009-12-01
Steady-state analysis is performed on the kinetic model for the switch complex of the flagellar motor of Halobacterium salinarum (Nutsch et al.). The existence and uniqueness of a positive steady-state of the system is established and it is demonstrated why the steady-state is centered around the competent phase, a state of the motor in which it is able to respond to light stimuli. It is also demonstrated why the steady-state shifts to the refractory phase when the steady-state value of the response regulator CheYP increases. This work is one aspect of modeling in systems biology wherein the mathematical properties of a model are established. PMID:19857501
Dynamical phase transitions, time-integrated observables, and geometry of states
NASA Astrophysics Data System (ADS)
Hickey, James M.; Genway, Sam; Garrahan, Juan P.
2014-02-01
We show that there exist dynamical phase transitions (DPTs), as defined by Heyl et al. [Phys. Rev. Lett. 110, 135704 (2013), 10.1103/PhysRevLett.110.135704], in the transverse-field Ising model (TFIM) away from the static quantum critical points. We study a class of special states associated with singularities in the generating functions of time-integrated observables as found by Hickey et al. [Phys. Rev. B 87, 184303 (2013)], 10.1103/PhysRevB.87.184303. Studying the dynamics of these special states under the evolution of the TFIM Hamiltonian, we find temporal nonanalyticities in the initial-state return probability associated with dynamical phase transitions. By calculating the Berry phase and Chern number we show the set of special states have interesting geometric features similar to those associated with static quantum critical points.
Phase transitions and isothermal equations of state of epsilon hexanitrohexaazaisowurtzitane (CL-20)
NASA Astrophysics Data System (ADS)
Gump, Jared C.; Peiris, Suhithi M.
2008-10-01
The phase stability of epsilon hexanitrohexaazaisowurtzitane at high pressure and temperature was investigated using synchrotron angle-dispersive x-ray diffraction experiments. The samples were compressed at room temperature using a Merrill-Bassett diamond anvil cell. For high-temperature compression experiments a hydrothermal diamond anvil cell developed by Bassett was used. Pressures and temperatures of around 5 GPa and 175 °C, respectively, were achieved. The epsilon phase was determined to be stable under ambient pressure to a temperature of 120 °C. A phase transition to the gamma phase was seen at 125 °C and the gamma phase remained stable until thermal decomposition above 150 °C. Pressure-volume data for the epsilon phase at ambient and 75 °C were fitted to the Birch-Murnaghan formalism to obtain isothermal equations of state.
Perfect terahertz absorber using fishnet based metafilm
Azad, Abul Kalam; Shchegolkov, Dmitry Yu; Chen, Houtong; Taylor, Antoinette; Smirnova, E I; O' Hara, John F
2009-01-01
We present a perfect terahertz (THz) absorber working for a broad-angle of incidence. The two fold symmetry of rectangular fishnet structure allows either complete absorption or mirror like reflection depending on the polarization of incident the THz beam. Metamaterials enable the ability to control the electromagnetic wave in a unique fashion by designing the permittivity or permeability of composite materials with desired values. Although the initial idea of metamaterials was to obtain a negative index medium, however, the evolution of metamaterials (MMs) offers a variety of practically applicable devices for controlling electromagnetic wave such as tunable filters, modulators, phase shifters, compact antenna, absorbers, etc. Terahertz regime, a crucial domain of the electromagnetic wave, is suffering from the scarcity of the efficient devices and might take the advantage of metamaterials. Here, we demonstrate design, fabrication, and characterization of a terahertz absorber based on a simple fishnet metallic film separated from a ground mirror plane by a dielectric spacer. Such absorbers are in particular important for bolometric terahertz detectors, high sensitivity imaging, and terahertz anechoic chambers. Recently, split-ring-resonators (SRR) have been employed for metamaterial-based absorbers at microwave and THz frequencies. The experimental demonstration reveals that such absorbers have absorptivity close to unity at resonance frequencies. However, the downside of these designs is that they all employ resonators of rather complicated shape with many fine parts and so they are not easy to fabricate and are sensitive to distortions.
Yu-Shiba-Rusinov states in phase-biased superconductor-quantum dot-superconductor junctions
NASA Astrophysics Data System (ADS)
Kiršanskas, Gediminas; Goldstein, Moshe; Flensberg, Karsten; Glazman, Leonid I.; Paaske, Jens
2015-12-01
We study the effects of a phase difference on Yu-Shiba-Rusinov (YSR) states in a spinful Coulomb-blockaded quantum dot contacted by a superconducting loop. In the limit where charging energy is larger than the superconducting gap, we determine the subgap excitation spectrum, the corresponding supercurrent, and the differential conductance as measured by a normal-metal tunnel probe. In absence of a phase difference only one linear combination of the superconductor lead electrons couples to the spin, which gives a single YSR state. With finite phase difference, however, it is effectively a two-channel scattering problem and therefore an additional state emerges from the gap edge. The energy of the phase-dependent YSR states depend on the gate voltage and one state can cross zero energy twice inside the valley with odd occupancy. These crossings are shifted by the phase difference towards the charge degeneracy points, corresponding to larger exchange couplings. Moreover, the zero-energy crossings give rise to resonant peaks in the differential conductance with magnitude 4 e2/h . Finally, we demonstrate that the quantum fluctuations of the dot spin do not alter qualitatively any of the results.
Role of the aerosol phase state in ammonia/amines exchange reactions.
Chan, Lap P; Chan, Chak K
2013-06-01
The exchange reaction of ammonia in (NH4)2SO4 with an amine and the corresponding reverse reaction of amines in aminium sulfates with ammonia were investigated using an electrodynamic balance coupled with a Raman spectrometer. The temporal changes in particle mass, chemical composition, and phase state were simultaneously monitored. When the salt particles were in an aqueous state at elevated relative humidities (RHs), the exchange of ammonia/amine vapors in the particle phase was reversible. The exchange rates of aqueous particles were in general higher than those of their corresponding solid counterparts. An aqueous phase was essential for the effective displacement of ammonia and amines. Aminium salts in different phase states and with different evaporation characteristics showed remarkably different reaction behaviors in ammonia vapor. The less compact amorphous aminium sulfate solids were more susceptible to ammonia exchange than the crystalline solids. The aminium salts in a liquid state exhibited substantial amine evaporation at <3% RH and formed acidic bisulfate. Under ammonia exposure, these acidic aminium droplets underwent both neutralization and displacement reactions. Stable solid salts containing ammonium, aminium, sulfate, and bisulfate were formed and hindered further reactions. The result suggests that ambient aminium sulfates may be acidic. Overall, the phase states of the ammonium and aminium salt particles crucially determine the heterogeneous reaction rates and final product properties and identities. PMID:23668831
Metasurface Broadband Solar Absorber
Azad, Abul K.; Kort-Kamp, Wilton J. M.; Sykora, Milan; Weisse-Bernstein, Nina R.; Luk, Ting S.; Taylor, Antoinette J.; Dalvit, Diego A. R.; Chen, Hou-Tong
2016-01-01
We demonstrate a broadband, polarization independent, wide-angle absorber based on a metallic metasurface architecture, which accomplishes greater than 90% absorptance in the visible and near-infrared range of the solar spectrum, and exhibits low absorptivity (emissivity) at mid- and far-infrared wavelengths. The complex unit cell of the metasurface solar absorber consists of eight pairs of gold nano-resonators that are separated from a gold ground plane by a thin silicon dioxide spacer. Our experimental measurements reveal high-performance absorption over a wide range of incidence angles for both s- and p-polarizations. We also investigate numerically the frequency-dependent field and current distributions to elucidate how the absorption occurs within the metasurface structure. PMID:26828999
Metasurface Broadband Solar Absorber.
Azad, Abul K; Kort-Kamp, Wilton J M; Sykora, Milan; Weisse-Bernstein, Nina R; Luk, Ting S; Taylor, Antoinette J; Dalvit, Diego A R; Chen, Hou-Tong
2016-01-01
We demonstrate a broadband, polarization independent, wide-angle absorber based on a metallic metasurface architecture, which accomplishes greater than 90% absorptance in the visible and near-infrared range of the solar spectrum, and exhibits low absorptivity (emissivity) at mid- and far-infrared wavelengths. The complex unit cell of the metasurface solar absorber consists of eight pairs of gold nano-resonators that are separated from a gold ground plane by a thin silicon dioxide spacer. Our experimental measurements reveal high-performance absorption over a wide range of incidence angles for both s- and p-polarizations. We also investigate numerically the frequency-dependent field and current distributions to elucidate how the absorption occurs within the metasurface structure.
Metasurface Broadband Solar Absorber
Azad, Abul K.; Kort-Kamp, Wilton J. M.; Sykora, Milan; Weisse-Bernstein, Nina R.; Luk, Ting S.; Taylor, Antoinette J.; Dalvit, Diego A. R.; Chen, Hou-Tong
2016-02-01
Here, we demonstrate a broadband, polarization independent, wide-angle absorber based on a metallic metasurface architecture, which accomplishes greater than 90% absorptance in the visible and near-infrared range of the solar spectrum, and exhibits low absorptivity (emissivity) at mid- and far-infrared wavelengths. The complex unit cell of the metasurface solar absorber consists of eight pairs of gold nano-resonators that are separated from a gold ground plane by a thin silicon dioxide spacer. Moreover, our experimental measurements reveal high-performance absorption over a wide range of incidence angles for both s- and p-polarizations. We also investigate numerically the frequency-dependent field and current distributionsmore » to elucidate how the absorption occurs within the metasurface structure.« less
Metasurface Broadband Solar Absorber.
Azad, Abul K; Kort-Kamp, Wilton J M; Sykora, Milan; Weisse-Bernstein, Nina R; Luk, Ting S; Taylor, Antoinette J; Dalvit, Diego A R; Chen, Hou-Tong
2016-01-01
We demonstrate a broadband, polarization independent, wide-angle absorber based on a metallic metasurface architecture, which accomplishes greater than 90% absorptance in the visible and near-infrared range of the solar spectrum, and exhibits low absorptivity (emissivity) at mid- and far-infrared wavelengths. The complex unit cell of the metasurface solar absorber consists of eight pairs of gold nano-resonators that are separated from a gold ground plane by a thin silicon dioxide spacer. Our experimental measurements reveal high-performance absorption over a wide range of incidence angles for both s- and p-polarizations. We also investigate numerically the frequency-dependent field and current distributions to elucidate how the absorption occurs within the metasurface structure. PMID:26828999
Absorbed dose water calorimeter
Domen, S.R.
1982-01-26
An absorbed dose water calorimeter that takes advantage of the low thermal diffusivity of water and the water-imperviousness of polyethylene film. An ultra-small bead thermistor is sandwiched between two thin polyethylene films stretched between insulative supports in a water bath. The polyethylene films insulate the thermistor and its leads, the leads being run out from between the films in insulated sleeving and then to junctions to form a wheatstone bridge circuit. Convection barriers may be provided to reduce the effects of convection from the point of measurement. Controlled heating of different levels in the water bath is accomplished by electrical heater circuits provided for controlling temperature drift and providing adiabatic operation of the calorimeter. The absorbed dose is determined from the known specific heat of water and the measured temperature change.
Spin Particle in an Absorbing Environment
NASA Astrophysics Data System (ADS)
Amooshahi, M.
2015-10-01
The quantum dynamics of a localized spin Particle interacting with an absorbing environment is investigated. The quantum Langevin-Schrödinger equation for spin is obtained. The susceptibility function of the environment is calculated in terms of the coupling function of the spin and the environment. it is shown that the susceptibility function satisfies the Kramers-Kronig relations. Spontaneous emission and the shift frequency of the spin is obtained in terms of the imaginary part of the susceptibility function in frequency domain. Some transition probabilities between the spin states are calculated when the absorbing environment is in the thermal state.
NASA Technical Reports Server (NTRS)
Mathur, S.
1999-01-01
As a part of this program, we observed three AGN:PKS2251 + 113, PG0043 = 039 and PLH909. Two objects show signatures of absorbtion in their UV spectra. Based on our earlier modeling of X-ray warm absorbents, we expected to observe X-ray observation in these objects. The third, PLH909, is known to have soft excess in EINSTEIN data. Attachment: "Exploratory ASCA observation of broad absorption line quasi-stellar objects".
OSCEE fan exhaust bulk absorber treatment evaluation
NASA Technical Reports Server (NTRS)
Bloomer, H. E.; Samanich, N. E.
1980-01-01
The acoustic suppression capability of bulk absorber material designed for use in the fan exhaust duct walls of the quiet clean short haul experiment engine (OCSEE UTW) was evaluated. The acoustic suppression to the original design for the engine fan duct which consisted of phased single degree-of-freedom wall treatment was tested with a splitter and also with the splitter removed. Peak suppression was about as predicted with the bulk absorber configuration, however, the broadband characteristics were not attained. Post test inspection revealed surface oil contamination on the bulk material which could have caused the loss in bandwidth suppression.
Cluster Mean-Field Approach to the Steady-State Phase Diagram of Dissipative Spin Systems
NASA Astrophysics Data System (ADS)
Jin, Jiasen; Biella, Alberto; Viyuela, Oscar; Mazza, Leonardo; Keeling, Jonathan; Fazio, Rosario; Rossini, Davide
2016-07-01
We show that short-range correlations have a dramatic impact on the steady-state phase diagram of quantum driven-dissipative systems. This effect, never observed in equilibrium, follows from the fact that ordering in the steady state is of dynamical origin, and is established only at very long times, whereas in thermodynamic equilibrium it arises from the properties of the (free) energy. To this end, by combining the cluster methods extensively used in equilibrium phase transitions to quantum trajectories and tensor-network techniques, we extend them to nonequilibrium phase transitions in dissipative many-body systems. We analyze in detail a model of spin-1 /2 on a lattice interacting through an X Y Z Hamiltonian, each of them coupled to an independent environment that induces incoherent spin flips. In the steady-state phase diagram derived from our cluster approach, the location of the phase boundaries and even its topology radically change, introducing reentrance of the paramagnetic phase as compared to the single-site mean field where correlations are neglected. Furthermore, a stability analysis of the cluster mean field indicates a susceptibility towards a possible incommensurate ordering, not present if short-range correlations are ignored.
Phase-locked states and abrupt shifts in Pacific climate indices
NASA Astrophysics Data System (ADS)
Douglass, David H.
2013-10-01
Douglass has shown that ENSO index aNino3.4 contains segments phase locked to subharmonics of the annual solar cycle and also that a set of indices including aNino3.4 shows abrupt shifts between these phase-locked states. Here, four additional Pacific indices are studied. These five indices show that the Pacific climate system alternates between two regimes: (1) Solar cycle (SOL), (2) Teleconnections (TEL). During SOL each index shows two components that are phase locked to the solar cycle. The first is at the annual cycle, while the second is at a subharmonic of the annual cycle. During TEL abrupt climate shifts occur.
M-ary-state phase-shift-keying discrimination below the homodyne limit
Becerra, F. E.; Fan, J.; Polyakov, S. V.; Migdall, A.; Baumgartner, G.; Goldhar, J.; Kosloski, J. T.
2011-12-15
We investigate a strategy for M-ary discrimination of nonorthogonal phase states with error rates below the homodyne limit. This strategy uses feed forward to update a reference field and signal nulling for the state discrimination. We experimentally analyze the receiver performance using postprocessing and a Bayesian strategy to emulate the feed-forward process. This analysis shows that for a moderate system detection efficiency, it is possible to surpass the homodyne error limit for quadrature phase-shift keying signals using feed forward.
Solid-state dimer method for calculating solid-solid phase transitions
Xiao, Penghao; Henkelman, Graeme; Sheppard, Daniel; Rogal, Jutta
2014-05-07
The dimer method is a minimum mode following algorithm for finding saddle points on a potential energy surface of atomic systems. Here, the dimer method is extended to include the cell degrees of freedom for periodic solid-state systems. Using this method, reaction pathways of solid-solid phase transitions can be determined without having to specify the final state structure or reaction mechanism. Example calculations include concerted phase transitions between CdSe polymorphs and a nucleation and growth mechanism for the A15 to BCC transition in Mo.
Generic Weyl phase in the vortex state of quasi-two-dimensional chiral superconductors
NASA Astrophysics Data System (ADS)
Yoshida, Tomohiro; Udagawa, Masafumi
2016-08-01
We study the collective behavior of Majorana modes in the vortex state of chiral p -wave superconductors. Away from the isolated vortex limit, the zero-energy Majorana states communicate with each other on a vortex lattice, and form a coherent band structure with a nontrivial topological character. We reveal that the topological nature of Majorana bands changes sensitively via quantum phase transitions in two-dimensional (2D) systems, by sweeping magnetic field or Fermi energy. Through the idea of dimensional reduction, we show the existence of a generic superconducting Weyl phase in a low magnetic field region of quasi-2D chiral superconductors.
Lattice model theory of the equation of state covering the gas, liquid, and solid phases
NASA Technical Reports Server (NTRS)
Bonavito, N. L.; Tanaka, T.; Chan, E. M.; Horiguchi, T.; Foreman, J. C.
1975-01-01
The three stable states of matter and the corresponding phase transitions were obtained with a single model. Patterned after Lennard-Jones and Devonshires's theory, a simple cubic lattice model containing two fcc sublattices (alpha and beta) is adopted. The interatomic potential is taken to be the Lennard-Jones (6-12) potential. Employing the cluster variation method, the Weiss and the pair approximations on the lattice gas failed to give the correct phase diagrams. Hybrid approximations were devised to describe the lattice term in the free energy. A lattice vibration term corresponding to a free volume correction is included semi-phenomenologically. The combinations of the lattice part and the free volume part yield the three states and the proper phase diagrams. To determine the coexistence regions, the equalities of the pressure and Gibbs free energy per molecule of the coexisting phases were utilized. The ordered branch of the free energy gives rise to the solid phase while the disordered branch yields the gas and liquid phases. It is observed that the triple point and the critical point quantities, the phase diagrams and the coexistence regions plotted are in good agreement with the experimental values and graphs for argon.
Quantum phase transitions in composite matrix product states of one-dimensional spin-1/2 chains
NASA Astrophysics Data System (ADS)
Zhu, Jing-Min
2015-02-01
For matrix product states of one-dimensional spin-1/2 chains, we investigate the properties of quantum phase transition of the proposed composite system. We find that the system has three different ferromagnetic phases, one line of the two ferromagnetic phases coexisting equally describes the paramagnetic state, and the other two lines of two ferromagnetic phases coexisting equally describe the ferrimagnetic states, while the three phases coexisting equally point describes the ferromagnetic state. Whether on phase transition lines or at the phase transition point, the system is always in an isolated mediate-coupling state, the physical quantities are discontinuous and the system has long-range correlation and has long-range classical correlation and long-range quantum correlation. We believe that our work is helpful for comprehensively and profoundly understanding the quantum phase transitions, and of some certain guidance and enlightening on the classification and measure of quantum correlation of quantum many-body systems.
Passively Q-switched nd:YAG laser via a WS2 saturable absorber
NASA Astrophysics Data System (ADS)
Wang, Xi; Wang, Yonggang; Duan, Lina; Li, Lu; Sun, Hang
2016-05-01
In this work, we report a passively Q-switched Nd:YAG laser at 1064 nm by using WS2 solution as the saturable absorber (SA). The WS2 solution with different concentrations (0.25, 0.5, and 1 mg/ml) were fabricated by the liquid-phase-exfoliated method and injected into quartz cells. Such liquid absorbers have the virtues of adjustable optical absorption, high heat dissipation and non-contact damage. By inserting those WS2 solutions in the laser cavity, stable Q-switched laser operations were obtained. The corresponding pulse duration as short as 922 ns was obtained. The result shows that the WS2 material can be act as absorber for solid-state lasers.
Modification of electron states in CdTe absorber due to a buffer layer in CdTe/CdS solar cells
NASA Astrophysics Data System (ADS)
Fedorenko, Y. G.; Major, J. D.; Pressman, A.; Phillips, L. J.; Durose, K.
2015-10-01
By application of the ac admittance spectroscopy method, the defect state energy distributions were determined in CdTe incorporated in thin film solar cell structures concluded on ZnO, ZnSe, and ZnS buffer layers. Together with the Mott-Schottky analysis, the results revealed a strong modification of the defect density of states and the concentration of the uncompensated acceptors as influenced by the choice of the buffer layer. In the solar cells formed on ZnSe and ZnS, the Fermi level and the energy position of the dominant deep trap levels were observed to shift closer to the midgap of CdTe, suggesting the mid-gap states may act as recombination centers and impact the open-circuit voltage and the fill factor of the solar cells. For the deeper states, the broadening parameter was observed to increase, indicating fluctuations of the charge on a microscopic scale. Such changes can be attributed to the grain-boundary strain and the modification of the charge trapped at the grain-boundary interface states in polycrystalline CdTe.
Modification of electron states in CdTe absorber due to a buffer layer in CdTe/CdS solar cells
Fedorenko, Y. G. Major, J. D.; Pressman, A.; Phillips, L. J.; Durose, K.
2015-10-28
By application of the ac admittance spectroscopy method, the defect state energy distributions were determined in CdTe incorporated in thin film solar cell structures concluded on ZnO, ZnSe, and ZnS buffer layers. Together with the Mott-Schottky analysis, the results revealed a strong modification of the defect density of states and the concentration of the uncompensated acceptors as influenced by the choice of the buffer layer. In the solar cells formed on ZnSe and ZnS, the Fermi level and the energy position of the dominant deep trap levels were observed to shift closer to the midgap of CdTe, suggesting the mid-gap states may act as recombination centers and impact the open-circuit voltage and the fill factor of the solar cells. For the deeper states, the broadening parameter was observed to increase, indicating fluctuations of the charge on a microscopic scale. Such changes can be attributed to the grain-boundary strain and the modification of the charge trapped at the grain-boundary interface states in polycrystalline CdTe.
Topological phase transition and quantum spin Hall edge states of antimony few layers
Kim, Sung Hwan; Jin, Kyung-Hwan; Park, Joonbum; Kim, Jun Sung; Jhi, Seung-Hoon; Yeom, Han Woong
2016-01-01
While two-dimensional (2D) topological insulators (TI’s) initiated the field of topological materials, only very few materials were discovered to date and the direct access to their quantum spin Hall edge states has been challenging due to material issues. Here, we introduce a new 2D TI material, Sb few layer films. Electronic structures of ultrathin Sb islands grown on Bi2Te2Se are investigated by scanning tunneling microscopy. The maps of local density of states clearly identify robust edge electronic states over the thickness of three bilayers in clear contrast to thinner islands. This indicates that topological edge states emerge through a 2D topological phase transition predicted between three and four bilayer films in recent theory. The non-trivial phase transition and edge states are confirmed for epitaxial films by extensive density-functional-theory calculations. This work provides an important material platform to exploit microscopic aspects of the quantum spin Hall phase and its quantum phase transition. PMID:27624972
Topological phase transition and quantum spin Hall edge states of antimony few layers
NASA Astrophysics Data System (ADS)
Kim, Sung Hwan; Jin, Kyung-Hwan; Park, Joonbum; Kim, Jun Sung; Jhi, Seung-Hoon; Yeom, Han Woong
2016-09-01
While two-dimensional (2D) topological insulators (TI’s) initiated the field of topological materials, only very few materials were discovered to date and the direct access to their quantum spin Hall edge states has been challenging due to material issues. Here, we introduce a new 2D TI material, Sb few layer films. Electronic structures of ultrathin Sb islands grown on Bi2Te2Se are investigated by scanning tunneling microscopy. The maps of local density of states clearly identify robust edge electronic states over the thickness of three bilayers in clear contrast to thinner islands. This indicates that topological edge states emerge through a 2D topological phase transition predicted between three and four bilayer films in recent theory. The non-trivial phase transition and edge states are confirmed for epitaxial films by extensive density-functional-theory calculations. This work provides an important material platform to exploit microscopic aspects of the quantum spin Hall phase and its quantum phase transition.
Topological phase transition and quantum spin Hall edge states of antimony few layers.
Kim, Sung Hwan; Jin, Kyung-Hwan; Park, Joonbum; Kim, Jun Sung; Jhi, Seung-Hoon; Yeom, Han Woong
2016-01-01
While two-dimensional (2D) topological insulators (TI's) initiated the field of topological materials, only very few materials were discovered to date and the direct access to their quantum spin Hall edge states has been challenging due to material issues. Here, we introduce a new 2D TI material, Sb few layer films. Electronic structures of ultrathin Sb islands grown on Bi2Te2Se are investigated by scanning tunneling microscopy. The maps of local density of states clearly identify robust edge electronic states over the thickness of three bilayers in clear contrast to thinner islands. This indicates that topological edge states emerge through a 2D topological phase transition predicted between three and four bilayer films in recent theory. The non-trivial phase transition and edge states are confirmed for epitaxial films by extensive density-functional-theory calculations. This work provides an important material platform to exploit microscopic aspects of the quantum spin Hall phase and its quantum phase transition. PMID:27624972
Absorber for terahertz radiation management
Biallas, George Herman; Apeldoorn, Cornelis; Williams, Gwyn P.; Benson, Stephen V.; Shinn, Michelle D.; Heckman, John D.
2015-12-08
A method and apparatus for minimizing the degradation of power in a free electron laser (FEL) generating terahertz (THz) radiation. The method includes inserting an absorber ring in the FEL beam path for absorbing any irregular THz radiation and thus minimizes the degradation of downstream optics and the resulting degradation of the FEL output power. The absorber ring includes an upstream side, a downstream side, and a plurality of wedges spaced radially around the absorber ring. The wedges form a scallop-like feature on the innermost edges of the absorber ring that acts as an apodizer, stopping diffractive focusing of the THz radiation that is not intercepted by the absorber. Spacing between the scallop-like features and the shape of the features approximates the Bartlett apodization function. The absorber ring provides a smooth intensity distribution, rather than one that is peaked on-center, thereby eliminating minor distortion downstream of the absorber.
Lim, Sunghyuk; Yu, Qinhong; Rockwell, Nathan C; Martin, Shelley S; Lagarias, J Clark; Ames, James B
2016-04-01
Cyanobacteriochromes (CBCRs) are cyanobacterial photosensory proteins with a tetrapyrrole (bilin) chromophore that belong to the phytochrome superfamily. Like phytochromes, CBCRs photoconvert between two photostates with distinct spectral properties. NpR6012g4 from Nostoc punctiforme is a model system for widespread CBCRs with conserved red/green photocycles. Atomic-level structural information for the photoproduct state in this subfamily is not known. Here, we report NMR backbone chemical shift assignments of the light-activated state of NpR6012g4 (BMRB no. 26577) as a first step toward determining its atomic resolution structure. PMID:26537963
Breakdown of the Bardeen-Cooper-Schrieffer ground state at a quantum phase transtion.
Jaramillo, R.; Feng, Y.; Lang, J. C.; Islam, Z.; Srajer, G.; Littlewood, P. B.; Mc Whan, D. B.; Rosenbaum, T. F.; Univ. of Chicago; Univ. of Cambridge; Massachusetts Innst. of Tech.
2009-05-21
Advances in solid-state and atomic physics are exposing the hidden relationships between conventional and exotic states of quantum matter. Prominent examples include the discovery of exotic superconductivity proximate to conventional spin and charge order, and the crossover from long-range phase order to preformed pairs achieved in gases of cold fermions and inferred for copper oxide superconductors. The unifying theme is that incompatible ground states can be connected by quantum phase transitions. Quantum fluctuations about the transition are manifestations of the competition between qualitatively distinct organizing principles, such as a long-wavelength density wave and a short-coherence-length condensate. They may even give rise to 'protected' phases, like fluctuation-mediated superconductivity that survives only in the vicinity of an antiferromagnetic quantum critical point. However, few model systems that demonstrate continuous quantum phase transitions have been identified, and the complex nature of many systems of interest hinders efforts to more fully understand correlations and fluctuations near a zero-temperature instability. Here we report the suppression of magnetism by hydrostatic pressure in elemental chromium, a simple cubic metal that demonstrates a subtle form of itinerant antiferromagnetism formally equivalent to the Bardeen-Cooper-Schrieffer (BCS) state in conventional superconductors. By directly measuring the associated charge order in a diamond anvil cell at low temperatures, we find a phase transition at pressures of 10 GPa driven by fluctuations that destroy the BCS-like state but preserve the strong magnetic interaction between itinerant electrons and holes. Chromium is unique among stoichiometric magnetic metals studied so far in that the quantum phase transition is continuous, allowing experimental access to the quantum singularity and a direct probe of the competition between conventional and exotic order in a theoretically tractable
Corrosion resistant neutron absorbing coatings
Choi, Jor-Shan; Farmer, Joseph C; Lee, Chuck K; Walker, Jeffrey; Russell, Paige; Kirkwood, Jon; Yang, Nancy; Champagne, Victor
2013-11-12
A method of forming a corrosion resistant neutron absorbing coating comprising the steps of spray or deposition or sputtering or welding processing to form a composite material made of a spray or deposition or sputtering or welding material, and a neutron absorbing material. Also a corrosion resistant neutron absorbing coating comprising a composite material made of a spray or deposition or sputtering or welding material, and a neutron absorbing material.
Corrosion resistant neutron absorbing coatings
Choi, Jor-Shan; Farmer, Joseph C.; Lee, Chuck K.; Walker, Jeffrey; Russell, Paige; Kirkwood, Jon; Yang, Nancy; Champagne, Victor
2012-05-29
A method of forming a corrosion resistant neutron absorbing coating comprising the steps of spray or deposition or sputtering or welding processing to form a composite material made of a spray or deposition or sputtering or welding material, and a neutron absorbing material. Also a corrosion resistant neutron absorbing coating comprising a composite material made of a spray or deposition or sputtering or welding material, and a neutron absorbing material.
A search for the ground state structure and the phase stability of tantalum pentoxide.
Pérez-Walton, S; Valencia-Balvín, C; Padilha, A C M; Dalpian, G M; Osorio-Guillén, J M
2016-01-27
Tantalum pentoxide (Ta2O5) is a wide-gap semiconductor that presents good catalytic and dielectric properties, conferring to this compound promising prospective use in a variety of technological applications. However, there is a lack of understanding regarding the relations among its crystalline phases, as some of them are not even completely characterized and there is currently no agreement about which models better explain the crystallographic data. Additionally, its phase diagram is unknown. In this work we performed first-principles density functional theory calculations to study the structural properties of the different phases and models of Ta2O5, the equation of state and the zone-centered vibrational frequencies. From our results, we conclude that the phases that are built up from only distorted octahedra instead of combinations with pentagonal and/or hexagonal bipyramids are energetically more favorable and dynamically stable. More importantly, this study establishes that, given the pressure range considered, the B-phase is the most favorable structure and there is no a crystallographic phase transition to another phase at high-pressure. Additionally, for the equilibrium volume of the B-phase and the λ-model, the description of the electronic structure and optical properties were performed using semi-local and hybrid functionals.
A search for the ground state structure and the phase stability of tantalum pentoxide
NASA Astrophysics Data System (ADS)
Pérez-Walton, S.; Valencia-Balvín, C.; Padilha, A. C. M.; Dalpian, G. M.; Osorio-Guillén, J. M.
2016-01-01
Tantalum pentoxide (Ta2O5) is a wide-gap semiconductor that presents good catalytic and dielectric properties, conferring to this compound promising prospective use in a variety of technological applications. However, there is a lack of understanding regarding the relations among its crystalline phases, as some of them are not even completely characterized and there is currently no agreement about which models better explain the crystallographic data. Additionally, its phase diagram is unknown. In this work we performed first-principles density functional theory calculations to study the structural properties of the different phases and models of Ta2O5, the equation of state and the zone-centered vibrational frequencies. From our results, we conclude that the phases that are built up from only distorted octahedra instead of combinations with pentagonal and/or hexagonal bipyramids are energetically more favorable and dynamically stable. More importantly, this study establishes that, given the pressure range considered, the B-phase is the most favorable structure and there is no a crystallographic phase transition to another phase at high-pressure. Additionally, for the equilibrium volume of the B-phase and the λ-model, the description of the electronic structure and optical properties were performed using semi-local and hybrid functionals.
Underwater acoustic omnidirectional absorber
NASA Astrophysics Data System (ADS)
Naify, Christina J.; Martin, Theodore P.; Layman, Christopher N.; Nicholas, Michael; Thangawng, Abel L.; Calvo, David C.; Orris, Gregory J.
2014-02-01
Gradient index media, which are designed by varying local element properties in given geometry, have been utilized to manipulate acoustic waves for a variety of devices. This study presents a cylindrical, two-dimensional acoustic "black hole" design that functions as an omnidirectional absorber for underwater applications. The design features a metamaterial shell that focuses acoustic energy into the shell's core. Multiple scattering theory was used to design layers of rubber cylinders with varying filling fractions to produce a linearly graded sound speed profile through the structure. Measured pressure intensity agreed with predicted results over a range of frequencies within the homogenization limit.
Solar radiation absorbing material
Googin, John M.; Schmitt, Charles R.; Schreyer, James M.; Whitehead, Harlan D.
1977-01-01
Solar energy absorbing means in solar collectors are provided by a solar selective carbon surface. A solar selective carbon surface is a microporous carbon surface having pores within the range of 0.2 to 2 micrometers. Such a surface is provided in a microporous carbon article by controlling the pore size. A thermally conductive substrate is provided with a solar selective surface by adhering an array of carbon particles in a suitable binder to the substrate, a majority of said particles having diameters within the range of about 0.2-10 microns.
Direct observations of welding-induced solid-state phase transformations
Elmer, J.W.; Wong, J.; Waide, P.A.
1994-12-31
A new diagnostic tool that uses time-resolved x-ray diffraction (TRXRD) for in-situ, spatially resolved, phase identification around a weld is presented for the purpose of mapping the location of phase fields during welding. In this investigation, TRXRD experiments were conducted at the Stanford Sychrotron Radiation Laboratory where a high-intensity tunable synchrotron x-ray `probe` was available. The high spatial resolution of the x-ray probe (1mm) allowed precise mapping of specific phase fields around the weld, while the high intensity of the beam (10{sup 11} photons/s) yielded high signal-to-noise ratio of the diffracted x-rays. These characteristics enabled the crystal structure to be characterized during a 1-s x-ray integration time, thus providing real-time data to be gathered about welding-induced phase transformations. Experiments were performed on unalloyed Grade 4 titanium (Ti, 0.28%Fe, 0.38%O), which has an allotropic phase transition that occurs at 922{degrees}C, where the low temperature hcp phase transforms to the high temperature bcc phase. Welds were made using a semi-automatic tungsten inert gas procedure to establish a quasisteady-state thermal profile on 4.5 in. diameter titanium bar, which was rotated at a speed of 0.5 rpm beneath a 3.5 kW arc. Characteristic hcp, bcc, and liquid diffraction peaks were measured along x-ray probe scans traveling from the base metal through the heat-affected zone and into the weld pool, respectively. The results of this study clearly demonstrate the feasibility of using TRXRD for in-situ investigations of welding-induced phase transformations, thus allowing verification of welding models, the creation of transformation diagrams during rapid thermal cycling of materials, and the ability for real-time investigations of the nucleation and growth behavior of solid-state phase transformations.
Optimal active vibration absorber: Design and experimental results
NASA Technical Reports Server (NTRS)
Lee-Glauser, Gina; Juang, Jer-Nan; Sulla, Jeffrey L.
1992-01-01
An optimal active vibration absorber can provide guaranteed closed-loop stability and control for large flexible space structures with collocated sensors/actuators. The active vibration absorber is a second-order dynamic system which is designed to suppress any unwanted structural vibration. This can be designed with minimum knowledge of the controlled system. Two methods for optimizing the active vibration absorber parameters are illustrated: minimum resonant amplitude and frequency matched active controllers. The Controls-Structures Interaction Phase-1 Evolutionary Model at NASA LaRC is used to demonstrate the effectiveness of the active vibration absorber for vibration suppression. Performance is compared numerically and experimentally using acceleration feedback.
Ising spin network states for loop quantum gravity: a toy model for phase transitions
NASA Astrophysics Data System (ADS)
Feller, Alexandre; Livine, Etera R.
2016-03-01
Non-perturbative approaches to quantum gravity call for a deep understanding of the emergence of geometry and locality from the quantum state of the gravitational field. Without background geometry, the notion of distance should emerge entirely from the correlations between the gravity fluctuations. In the context of loop quantum gravity, quantum states of geometry are defined as spin networks. These are graphs decorated with spin and intertwiners, which represent quantized excitations of areas and volumes of the space geometry. Here, we develop the condensed-matter point of view on extracting the physical and geometrical information from spin network states: we introduce new Ising spin network states, both in 2d on a square lattice and in 3d on a hexagonal lattice, whose correlations map onto the usual Ising model in statistical physics. We construct these states from the basic holonomy operators of loop gravity and derive a set of local Hamiltonian constraints that entirely characterize our states. We discuss their phase diagram and show how the distance can be reconstructed from the correlations in the various phases. Finally, we propose generalizations of these Ising states, which open the perspective to study the coarse-graining and dynamics of spin network states using well-known condensed-matter techniques and results.
Materials research for passive solar systems: solid-state phase-change materials
Benson, D.K.; Webb, J.D.; Burrows, R.W.; McFadden, J.D.O.; Christensen, C.
1985-03-01
A set of solid-state phase-change materials is being evaluated for possible use in passive solar thermal energy storage systems. The most promising materials are organic solid solutions of pentaerythritol (C/sub 5/H/sub 12/O/sub 4/), pentaglycerinve (C/sub 5/H/sub 12/O/sub 3/), and neopentyl glycol (C/sub 5/H/sub 12/O/sub 2/). Solid solution mixtures of these compounds can be tailored so that they exhibit solid-to-solid phase transformations at any desired temperature betweeen 25/sup 0/C and 188/sup 0/C, and have latent heats of transformation between 20 and 70 cal/g. Transformation temperatures, specific heats, and latent heats of transformation have been measured for a number of these materials. Limited cyclic experiments suggest that the solid solutions are stable. These phase-change materials exhibit large amounts of undercooling; however, the addition of certain nucleating agents as particulate dispersions in the solid phase-change material greatly reduces this effect. Computer simulations suggest that the use of an optimized solid-state phase-change material in a Trombe wall could provide better performance than a concrete Trombe wall four times thicker and nine times heavier. Nevertheless, a higher cost of the phase-change materials (approx. =$0.70 per pound) is likely to limit their applicability in passive solar systems unless their performance can be significantly improved through further research.
Equation of state and phase fluctuations near the chiral critical point
Kapusta, J. I.
2010-05-15
The thermodynamics and critical exponents and amplitudes of high temperature and dense matter near the chiral critical point are studied. The parameterized equation of state matches that calculated with lattice QCD at zero chemical potential and to the known properties of nuclear matter at zero temperature. The extent to which finite size effects wash out the phase separation near the critical point is determined.
Multiple-copy distillation and purification of phase-diffused squeezed states
Marek, Petr; Fiurasek, Jaromir; Hage, Boris; Franzen, Alexander; DiGugliemo, James; Schnabel, Roman
2007-11-15
We provide a detailed theoretical analysis of multiple-copy purification and distillation protocols for phase-diffused squeezed states of light. The standard iterative distillation protocol is generalized to a collective purification of an arbitrary number of N copies. We also derive a semianalytical expression for the asymptotic limit of the iterative distillation and purification protocol and discuss its properties.
Quantum displacement receiver for M-ary phase-shift-keyed coherent states
Izumi, Shuro; Takeoka, Masahiro; Fujiwara, Mikio; Sasaki, Masahide; Pozza, Nicola Dalla; Assalini, Antonio
2014-12-04
We propose quantum receivers for 3- and 4-ary phase-shift-keyed (PSK) coherent state signals to overcome the standard quantum limit (SQL). Our receiver, consisting of a displacement operation and on-off detectors with or without feedforward, provides an error probability performance beyond the SQL. We show feedforward operations can tolerate the requirement for the detector specifications.
ERIC Educational Resources Information Center
Price Waterhouse and Co., New York, NY.
This volume on Phase II of the New York State Educational Information System (NYSEIS) describes the Gross Systems Analysis and Design, which includes the general flow diagram and processing chart for each of the student, personnel, and financial subsystems. Volume II, Functional Specifications, includes input/output requirements and file…
Quantum displacement receiver for M-ary phase-shift-keyed coherent states
NASA Astrophysics Data System (ADS)
Izumi, Shuro; Takeoka, Masahiro; Fujiwara, Mikio; Pozza, Nicola Dalla; Assalini, Antonio; Ema, Kazuhiro; Sasaki, Masahide
2014-12-01
We propose quantum receivers for 3- and 4-ary phase-shift-keyed (PSK) coherent state signals to overcome the standard quantum limit (SQL). Our receiver, consisting of a displacement operation and on-off detectors with or without feedforward, provides an error probability performance beyond the SQL. We show feedforward operations can tolerate the requirement for the detector specifications.
Effects of phase states on reactions of secondary organic materials with chloride
NASA Astrophysics Data System (ADS)
Wang, B.; Laskin, A.; OBrien, R. E.; Kelly, S. T.; Shilling, J. E.; Moffet, R.; Gilles, M. K.
2014-12-01
Secondary organic materials (SOM) in atmospheric aerosols are often mixed with inorganic components. Condensed-phase SOM can exist in a liquid, semi-solid, or solid state at different temperatures and RH. We investigated the effects of phase states of SOM on the reactions of SOM from ozonolysis of limonene (LSOM) and α-pinene (PSOM) with NaCl using a set of complementary micro-spectroscopic analyses. SOM can react with NaCl and result in chloride depletion in the condensed phase, release of gaseous HCl, and formation of organic salts. The reactions driven by the high volatility of HCl are attributed to acid displacement by SOM acidic components. Similar reactions can take place in SOM/NaNO3 particles. Glass transition temperatures and viscosity of PSOM were estimated. The results show that the reaction depends on SOM composition, phase state and viscosity, mixing state, and reaction time. The release and potential recycling of HCl and HNO3 from reacted aerosol particles may have important implications for atmospheric chemistry. This reaction can modify particle physicochemical properties, such as the ability to form clouds, and thus may have important atmospheric implications.
Structural-phase states and wear resistance of surface formed on steel by surfacing
Kapralov, Evgenie V.; Raykov, Sergey V.; Vaschuk, Ekaterina S.; Budovskikh, Evgenie A. Gromov, Victor E.; Ivanov, Yuri F.
2014-11-14
Investigations of elementary and phase structure, state of defect structure and tribological characteristics of a surfacing, formed on a low carbon low-alloy steel by a welding method were carried out. It was revealed that a surfacing, formed on a steel surface is accompanied by the multilayer formation, and increases the wear resistance of the layer surfacing as determined.
Ground state of the U2Mo compound: Physical properties of the Ω-phase
NASA Astrophysics Data System (ADS)
Losada, E. L.; Garcés, J. E.
2016-10-01
Using ab initio calculations, unexpected structural instability was recently found in the ground state of the U2 Mo compound. Instead of the unstable I4/mmm and the Pmmn structures, in this work the P6/mmm (#191) space group, usually called Ω-phase, is proposed as the fundamental state. Total energy calculations using Wien2k code slightly favoured the last structure. Electronic and elastic properties are studied in this work in order to characterize the physical properties of this new phase. The stability of the Ω-phase is studied by means of its elastic constants calculation and phonon dispersion spectrum. Analysis of isotropic indices shows that the new phase is a ductile material with a minimal degree of anisotropy, suggesting that U2 Mo in the P6/mmm structure is an elastic isotropic material. Analysis of charge density, density of electronic states (DOS) and the character of the bands revealed a high level of hybridization between d-molybdenum electronic states and d- and f-uranium ones.
Hacking on decoy-state quantum key distribution system with partial phase randomization.
Sun, Shi-Hai; Jiang, Mu-Sheng; Ma, Xiang-Chun; Li, Chun-Yan; Liang, Lin-Mei
2014-01-01
Quantum key distribution (QKD) provides means for unconditional secure key transmission between two distant parties. However, in practical implementations, it suffers from quantum hacking due to device imperfections. Here we propose a hybrid measurement attack, with only linear optics, homodyne detection, and single photon detection, to the widely used vacuum + weak decoy state QKD system when the phase of source is partially randomized. Our analysis shows that, in some parameter regimes, the proposed attack would result in an entanglement breaking channel but still be able to trick the legitimate users to believe they have transmitted secure keys. That is, the eavesdropper is able to steal all the key information without discovered by the users. Thus, our proposal reveals that partial phase randomization is not sufficient to guarantee the security of phase-encoding QKD systems with weak coherent states. PMID:24755767
State diagram of magnetostatic coupling phase-locked spin-torque oscillators
Zhang, Mengwei; Wang, Longze; Wei, Dan; Gao, Kai-Zhong
2015-05-07
The state diagram of magnetostatic coupling phase-locked spin torque oscillator (STO) with perpendicular reference layer and planar field generation layer (FGL) is studied by the macrospin model and the micromagnetic model. The state diagrams of current densities are calculated under various external fields. The simulation shows that there are two phase-lock current density regions. In the phase-locked STOs in low current region I, the spin configuration of FGL is uniform; in high current region II, the spin configuration of FGL is highly nonuniform. In addition, the results with different STOs separation L{sub s} are compared, and the coupling between two STOs is largely decreased when L{sub s} is increased from 40 nm to 60 nm.
Hacking on decoy-state quantum key distribution system with partial phase randomization.
Sun, Shi-Hai; Jiang, Mu-Sheng; Ma, Xiang-Chun; Li, Chun-Yan; Liang, Lin-Mei
2014-04-23
Quantum key distribution (QKD) provides means for unconditional secure key transmission between two distant parties. However, in practical implementations, it suffers from quantum hacking due to device imperfections. Here we propose a hybrid measurement attack, with only linear optics, homodyne detection, and single photon detection, to the widely used vacuum + weak decoy state QKD system when the phase of source is partially randomized. Our analysis shows that, in some parameter regimes, the proposed attack would result in an entanglement breaking channel but still be able to trick the legitimate users to believe they have transmitted secure keys. That is, the eavesdropper is able to steal all the key information without discovered by the users. Thus, our proposal reveals that partial phase randomization is not sufficient to guarantee the security of phase-encoding QKD systems with weak coherent states.
Hacking on decoy-state quantum key distribution system with partial phase randomization
NASA Astrophysics Data System (ADS)
Sun, Shi-Hai; Jiang, Mu-Sheng; Ma, Xiang-Chun; Li, Chun-Yan; Liang, Lin-Mei
2014-04-01
Quantum key distribution (QKD) provides means for unconditional secure key transmission between two distant parties. However, in practical implementations, it suffers from quantum hacking due to device imperfections. Here we propose a hybrid measurement attack, with only linear optics, homodyne detection, and single photon detection, to the widely used vacuum + weak decoy state QKD system when the phase of source is partially randomized. Our analysis shows that, in some parameter regimes, the proposed attack would result in an entanglement breaking channel but still be able to trick the legitimate users to believe they have transmitted secure keys. That is, the eavesdropper is able to steal all the key information without discovered by the users. Thus, our proposal reveals that partial phase randomization is not sufficient to guarantee the security of phase-encoding QKD systems with weak coherent states.
Hacking on decoy-state quantum key distribution system with partial phase randomization
Sun, Shi-Hai; Jiang, Mu-Sheng; Ma, Xiang-Chun; Li, Chun-Yan; Liang, Lin-Mei
2014-01-01
Quantum key distribution (QKD) provides means for unconditional secure key transmission between two distant parties. However, in practical implementations, it suffers from quantum hacking due to device imperfections. Here we propose a hybrid measurement attack, with only linear optics, homodyne detection, and single photon detection, to the widely used vacuum + weak decoy state QKD system when the phase of source is partially randomized. Our analysis shows that, in some parameter regimes, the proposed attack would result in an entanglement breaking channel but still be able to trick the legitimate users to believe they have transmitted secure keys. That is, the eavesdropper is able to steal all the key information without discovered by the users. Thus, our proposal reveals that partial phase randomization is not sufficient to guarantee the security of phase-encoding QKD systems with weak coherent states. PMID:24755767
Detection of phase-diffused weak-coherent-states using an optical Costas loop
NASA Astrophysics Data System (ADS)
Lopez Leyva, Josue A.; Mondragón, Arturo Arvizu; García, Edith; Mendieta, Francisco J.; Guzman, Eduardo Alvarez; Gallion, Philippe
2012-10-01
We describe a homodyne optical Costas loop receiver intended to detect weak coherent states with diffused phase and suppressed carrier phase modulation. In order to get the information contained in the quadrature components of the optical field, we implement an 8-port receiver operating at 1550 nm, based on the manipulation of the state of polarization of both the local oscillator and the data signal. Employing binary phase-shift keying, we make measurements in the time and frequency domain of the quantum noise and bit error rate using an optimum loop filter, and compare the performance of our receiver against the standard quantum limit for the simultaneous quadrature detection, considering both ideal conditions and the overall efficiency of our set up.
Influence of particle-phase state on the hygroscopic behavior of mixed organic-inorganic aerosols
NASA Astrophysics Data System (ADS)
Hodas, N.; Zuend, A.; Mui, W.; Flagan, R. C.; Seinfeld, J. H.
2015-05-01
Recent work has demonstrated that organic and mixed organic-inorganic particles can exhibit multiple phase states depending on their chemical composition and on ambient conditions such as relative humidity (RH). To explore the extent to which water uptake varies with particle-phase behavior, hygroscopic growth factors (HGFs) of nine laboratory-generated, organic and organic-inorganic aerosol systems with physical states ranging from well-mixed liquids to phase-separated particles to viscous liquids or semi-solids were measured with the Differential Aerosol Sizing and Hygroscopicity Spectrometer Probe at RH values ranging from 40 to 90%. Water-uptake measurements were accompanied by HGF and RH-dependent thermodynamic equilibrium calculations using the Aerosol Inorganic-Organic Mixtures Functional groups Activity Coefficients (AIOMFAC) model. In addition, AIOMFAC-predicted growth curves are compared to several simplified HGF modeling approaches: (1) representing particles as ideal, well-mixed liquids; (2) forcing a single phase but accounting for non-ideal interactions through activity coefficient calculations; and (3) a Zdanovskii-Stokes-Robinson-like calculation in which complete separation of the inorganic and organic components is assumed at all RH values, with water uptake treated separately in each of the individual phases. We observed variability in the characteristics of measured hygroscopic growth curves across aerosol systems with differing phase behaviors, with growth curves approaching smoother, more continuous water uptake with decreasing prevalence of liquid-liquid phase separation and increasing oxygen : carbon ratios of the organic aerosol components. We also observed indirect evidence for the dehydration-induced formation of highly viscous semi-solid phases and for kinetic limitations to the crystallization of ammonium sulfate at low RH for sucrose-containing particles. AIOMFAC-predicted growth curves are generally in good agreement with the HGF
Influence of particle phase state on the hygroscopic behavior of mixed organic-inorganic aerosols
NASA Astrophysics Data System (ADS)
Hodas, N.; Zuend, A.; Mui, W.; Flagan, R. C.; Seinfeld, J. H.
2014-12-01
Recent work has demonstrated that organic and mixed organic-inorganic particles can exhibit multiple phase states depending on their chemical composition and on ambient conditions such as relative humidity (RH). To explore the extent to which water uptake varies with particle phase behavior, hygroscopic growth factors (HGFs) of nine laboratory-generated, organic and organic-inorganic aerosol systems with physical states ranging from well-mixed liquids, to phase-separated particles, to viscous liquids or semi-solids were measured with the Differential Aerosol Sizing and Hygroscopicity Spectrometer Probe at RH values ranging from 40-90%. Water-uptake measurements were accompanied by HGF and RH-dependent thermodynamic equilibrium calculations using the Aerosol Inorganic-Organic Mixtures Functional groups Activity Coefficients (AIOMFAC) model. In addition, AIOMFAC-predicted growth curves are compared to several simplified HGF modeling approaches: (1) representing particles as ideal, well-mixed liquids, (2) forcing a single phase, but accounting for non-ideal interactions through activity coefficient calculations, and (3) a Zdanovskii-Stokes-Robinson-like calculation in which complete separation between the inorganic and organic components is assumed at all RH values, with water-uptake treated separately in each of the individual phases. We observed variability in the characteristics of measured hygroscopic growth curves across aerosol systems with differing phase behaviors, with growth curves approaching smoother, more continuous water uptake with decreasing prevalence of liquid-liquid phase separation and increasing oxygen : carbon ratios of the organic aerosol components. We also observed indirect evidence for the dehydration-induced formation of highly viscous semi-solid phases and for kinetic limitations to the crystallization of ammonium sulfate at low RH for sucrose-containing particles. AIOMFAC-predicted growth curves are generally in good agreement with the HGF
Alternative stable states and phase shifts in coral reefs under anthropogenic stress.
Fung, Tak; Seymour, Robert M; Johnson, Craig R
2011-04-01
Ecosystems with alternative stable states (ASS) may shift discontinuously from one stable state to another as environmental parameters cross a threshold. Reversal can then be difficult due to hysteresis effects. This contrasts with continuous state changes in response to changing environmental parameters, which are less difficult to reverse. Worldwide degradation of coral reefs, involving "phase shifts" from coral to algal dominance, highlights the pressing need to determine the likelihood of discontinuous phase shifts in coral reefs, in contrast to continuous shifts with no ASS. However, there is little evidence either for or against the existence of ASS for coral reefs. We use dynamic models to investigate the likelihood of continuous and discontinuous phase shifts in coral reefs subject to sustained environmental perturbation by fishing, nutrification, and sedimentation. Our modeling results suggest that coral reefs with or without anthropogenic stress can exhibit ASS, such that discontinuous phase shifts can occur. We also find evidence to support the view that high macroalgal growth rates and low grazing rates on macroalgae favor ASS in coral reefs. Further, our results suggest that the three stressors studied, either alone or in combination, can increase the likelihood of both continuous and discontinuous phase shifts by altering the competitive balance between corals and algae. However, in contrast to continuous phase shifts, we find that discontinuous shifts occur only in model coral reefs with parameter values near the extremes of their empirically determined ranges. This suggests that continuous shifts are more likely than discontinuous shifts in coral reefs. Our results also suggest that, for ecosystems in general, tackling multiple human stressors simultaneously maximizes resilience to phase shifts, ASS, and hysteresis, leading to improvements in ecosystem health and functioning.
Linear canonical transformations of coherent and squeezed states in the Wigner phase space
NASA Technical Reports Server (NTRS)
Han, D.; Kim, Y. S.; Noz, Marilyn E.
1988-01-01
It is shown that classical linear canonical transformations are possible in the Wigner phase space. Coherent and squeezed states are shown to be linear canonical transforms of the ground-state harmonic oscillator. It is therefore possible to evaluate the Wigner functions for coherent and squeezed states from that for the harmonic oscillator. Since the group of linear canonical transformations has a subgroup whose algebraic property is the same as that of the (2+1)-dimensional Lorentz group, it may be possible to test certain properties of the Lorentz group using optical devices. A possible experiment to measure the Wigner rotation angle is discussed.
NASA Technical Reports Server (NTRS)
Benet, James
1993-01-01
The final report describes the work performed from 9 Jun. 1992 to 31 Jul. 1993 on the NASA Satellite Communications Application Research (SCAR) Phase 2 program, Efficient High Power, Solid State Amplifier for EHF Communications. The purpose of the program was to demonstrate the feasibility of high-efficiency, high-power, EHF solid state amplifiers that are smaller, lighter, more efficient, and less costly than existing traveling wave tube (TWT) amplifiers by combining the output power from up to several hundred solid state amplifiers using a unique orthomode spatial power combiner (OSPC).
Optical phase estimation via the coherent state and displaced-photon counting
NASA Astrophysics Data System (ADS)
Izumi, Shuro; Takeoka, Masahiro; Wakui, Kentaro; Fujiwara, Mikio; Ema, Kazuhiro; Sasaki, Masahide
2016-09-01
We consider the phase sensing via a weak optical coherent state at quantum limit precision. A detection scheme for the phase estimation is proposed, which is inspired by the suboptimal quantum measurement in coherent optical communication. We theoretically analyze a performance of our detection scheme, which we call the displaced-photon counting, for phase sensing in terms of the Fisher information and show that the displaced-photon counting outperforms the static homodyne and heterodyne detections in a wide range of the target phase. The proof-of-principle experiment is performed with linear optics and a superconducting nanowire single-photon detector. The result shows that our scheme overcomes the limit of the ideal homodyne measurement, even under practical imperfections.
Phase diagram and edge excitations of the ν = 0 quantum Hall state in graphene
NASA Astrophysics Data System (ADS)
Kharitonov, Maxim
2013-03-01
The interaction-induced broken-symmetry incompressible quantum Hall states in graphene at integer and fractional filling factors have by now been firmly established in transport and compressibility measurements. However, identifying their precise nature (e.g., how the symmetry is broken) still remains a tough challenge: on the experimental side, transport and compressibility probes do not provide direct information about the physical order; on the theoretical side, the presence of additional to spin discrete degrees of freedom, valleys, results in a variety of competing phases in this multicomponent system. As the prime example of this rich behavior, I will present a generic phase diagram for the intriguing ν = 0 state, obtained within the framework of quantum Hall ``ferromagnetism.'' The diagram consists of the canted antiferromagnetic, ferromagnetic, charge-density-wave (charge-layer-polarized), and Kekulé (interlayer-coherent) phases in monolayer (bilayer). I will then discuss the edge excitations of the ν = 0 state. Remarkably, the edge excitations are nonuniversal (e.g., can be gapped or gapless) and crucially depend on which phase is realized in the bulk of the system. Besides being of considerable theoretical interest, these unprecedented properties simultaneously allow one to infer about the nature of the phases from the transport experiments. I will present arguments based on this analysis and existing data why the insulating ν = 0 state realized in real bilayer (and possibly, monolayer) graphene is likely to be canted antiferromagnetic. Finally, I will mention how this theoretical framework can be generalized to fractional quantum Hall states in graphene, which could shed light on some of the puzzling features of the recent experiments. This research was supported by the U.S. DOE under contracts No. DE-FG02-99ER45790 and No. DE- AC02-06CH11357.
Liquid Cryogen Absorber for MICE
Baynham, D.E.; Bish, P.; Bradshaw, T.W.; Cummings, M.A.; Green,M.A.; Ishimoto, S.; Ivaniouchenkov, I.; Lau, W.; Yang, S.Q.; Zisman, M.S.
2005-08-20
The Muon Ionization Cooling Experiment (MICE) will test ionization cooling of muons. In order to have effective ionization cooling, one must use an absorber that is made from a low-z material. The most effective low z materials for ionization cooling are hydrogen, helium, lithium hydride, lithium and beryllium, in that order. In order to measure the effect of material on cooling, several absorber materials must be used. This report describes a liquid-hydrogen absorber that is within a pair of superconducting focusing solenoids. The absorber must also be suitable for use with liquid helium. The following absorber components are discussed in this report; the absorber body, its heat exchanger, the hydrogen system, and the hydrogen safety. Absorber cooling and the thin windows are not discussed here.
Tischer, Alexander; Auton, Matthew
2013-09-01
We have analyzed the thermodynamic properties of the von Willebrand factor (VWF) A3 domain using urea-induced unfolding at variable temperature and thermal unfolding at variable urea concentrations to generate a phase diagram that quantitatively describes the equilibrium between native and denatured states. From this analysis, we were able to determine consistent thermodynamic parameters with various spectroscopic and calorimetric methods that define the urea-temperature parameter plane from cold denaturation to heat denaturation. Urea and thermal denaturation are experimentally reversible and independent of the thermal scan rate indicating that all transitions are at equilibrium and the van't Hoff and calorimetric enthalpies obtained from analysis of individual thermal transitions are equivalent demonstrating two-state character. Global analysis of the urea-temperature phase diagram results in a significantly higher enthalpy of unfolding than obtained from analysis of individual thermal transitions and significant cross correlations describing the urea dependence of ΔH0 and ΔCP0 that define a complex temperature dependence of the m-value. Circular dichroism (CD) spectroscopy illustrates a large increase in secondary structure content of the urea-denatured state as temperature increases and a loss of secondary structure in the thermally denatured state upon addition of urea. These structural changes in the denatured ensemble make up ∼40% of the total ellipticity change indicating a highly compact thermally denatured state. The difference between the thermodynamic parameters obtained from phase diagram analysis and those obtained from analysis of individual thermal transitions illustrates that phase diagrams capture both contributions to unfolding and denatured state expansion and by comparison are able to decipher these contributions.
Phase diagram and the pseudogap state in a linear chiral homopolymer model
NASA Astrophysics Data System (ADS)
Sinelnikova, A.; Niemi, A. J.; Ulybyshev, M.
2015-09-01
The phase structure of a single self-interacting homopolymer chain is investigated in terms of a universal theoretical model, designed to describe the chain in the infrared limit of slow spatial variations. The effects of chirality are studied and compared with the influence of a short-range attractive interaction between monomers, at various ambient temperature values. In the high-temperature limit the homopolymer chain is in the self-avoiding random walk phase. At very low temperatures two different phases are possible: When short-range attractive interactions dominate over chirality, the chain collapses into a space-filling conformation. But when the attractive interactions weaken, there is a low-temperature unfolding transition and the chain becomes like a straight rod. Between the high- and low-temperature limits, several intermediate states are observed, including the θ regime and pseudogap state, which is a novel form of phase state in the context of polymer chains. Applications to polymers and proteins, in particular collagen, are suggested.
Topological states and phase transitions in Sb2Te3-GeTe multilayers.
Nguyen, Thuy-Anh; Backes, Dirk; Singh, Angadjit; Mansell, Rhodri; Barnes, Crispin; Ritchie, David A; Mussler, Gregor; Lanius, Martin; Grützmacher, Detlev; Narayan, Vijay
2016-01-01
Topological insulators (TIs) are bulk insulators with exotic 'topologically protected' surface conducting modes. It has recently been pointed out that when stacked together, interactions between surface modes can induce diverse phases including the TI, Dirac semimetal, and Weyl semimetal. However, currently a full experimental understanding of the conditions under which topological modes interact is lacking. Here, working with multilayers of the TI Sb2Te3 and the band insulator GeTe, we provide experimental evidence of multiple topological modes in a single Sb2Te3-GeTe-Sb2Te3 structure. Furthermore, we show that reducing the thickness of the GeTe layer induces a phase transition from a Dirac-like phase to a gapped phase. By comparing different multilayer structures we demonstrate that this transition occurs due to the hybridisation of states associated with different TI films. Our results demonstrate that the Sb2Te3-GeTe system offers strong potential towards manipulating topological states as well as towards controlledly inducing various topological phases. PMID:27291288
Wave packet interferometry and quantum state reconstruction by acousto-optic phase modulation
Tekavec, Patrick F.; Dyke, Thomas R.; Marcus, Andrew H.
2006-11-21
Studies of wave packet dynamics often involve phase-selective measurements of coherent optical signals generated from sequences of ultrashort laser pulses. In wave packet interferometry (WPI), the separation between the temporal envelopes of the pulses must be precisely monitored or maintained. Here we introduce a new (and easy to implement) experimental scheme for phase-selective measurements that combines acousto-optic phase modulation with ultrashort laser excitation to produce an intensity-modulated fluorescence signal. Synchronous detection, with respect to an appropriately constructed reference, allows the signal to be simultaneously measured at two phases differing by 90 deg. Our method effectively decouples the relative temporal phase from the pulse envelopes of a collinear train of optical pulse pairs. We thus achieve a robust and high signal-to-noise scheme for WPI applications, such as quantum state reconstruction and electronic spectroscopy. The validity of the method is demonstrated, and state reconstruction is performed, on a model quantum system - atomic Rb vapor. Moreover, we show that our measurements recover the correct separation between the absorptive and dispersive contributions to the system susceptibility.
Topological states and phase transitions in Sb2Te3-GeTe multilayers
NASA Astrophysics Data System (ADS)
Nguyen, Thuy-Anh; Backes, Dirk; Singh, Angadjit; Mansell, Rhodri; Barnes, Crispin; Ritchie, David A.; Mussler, Gregor; Lanius, Martin; Grützmacher, Detlev; Narayan, Vijay
2016-06-01
Topological insulators (TIs) are bulk insulators with exotic ‘topologically protected’ surface conducting modes. It has recently been pointed out that when stacked together, interactions between surface modes can induce diverse phases including the TI, Dirac semimetal, and Weyl semimetal. However, currently a full experimental understanding of the conditions under which topological modes interact is lacking. Here, working with multilayers of the TI Sb2Te3 and the band insulator GeTe, we provide experimental evidence of multiple topological modes in a single Sb2Te3-GeTe-Sb2Te3 structure. Furthermore, we show that reducing the thickness of the GeTe layer induces a phase transition from a Dirac-like phase to a gapped phase. By comparing different multilayer structures we demonstrate that this transition occurs due to the hybridisation of states associated with different TI films. Our results demonstrate that the Sb2Te3-GeTe system offers strong potential towards manipulating topological states as well as towards controlledly inducing various topological phases.
Topological states and phase transitions in Sb2Te3-GeTe multilayers
Nguyen, Thuy-Anh; Backes, Dirk; Singh, Angadjit; Mansell, Rhodri; Barnes, Crispin; Ritchie, David A.; Mussler, Gregor; Lanius, Martin; Grützmacher, Detlev; Narayan, Vijay
2016-01-01
Topological insulators (TIs) are bulk insulators with exotic ‘topologically protected’ surface conducting modes. It has recently been pointed out that when stacked together, interactions between surface modes can induce diverse phases including the TI, Dirac semimetal, and Weyl semimetal. However, currently a full experimental understanding of the conditions under which topological modes interact is lacking. Here, working with multilayers of the TI Sb2Te3 and the band insulator GeTe, we provide experimental evidence of multiple topological modes in a single Sb2Te3-GeTe-Sb2Te3 structure. Furthermore, we show that reducing the thickness of the GeTe layer induces a phase transition from a Dirac-like phase to a gapped phase. By comparing different multilayer structures we demonstrate that this transition occurs due to the hybridisation of states associated with different TI films. Our results demonstrate that the Sb2Te3-GeTe system offers strong potential towards manipulating topological states as well as towards controlledly inducing various topological phases. PMID:27291288
Dual broadband metamaterial absorber.
Kim, Young Ju; Yoo, Young Joon; Kim, Ki Won; Rhee, Joo Yull; Kim, Yong Hwan; Lee, YoungPak
2015-02-23
We propose polarization-independent and dual-broadband metamaterial absorbers at microwave frequencies. This is a periodic meta-atom array consisting of metal-dielectric-multilayer truncated cones. We demonstrate not only one broadband absorption from the fundamental magnetic resonances but additional broadband absorption in high-frequency range using the third-harmonic resonance, by both simulation and experiment. In simulation, the absorption was over 90% in 3.93-6.05 GHz, and 11.64-14.55 GHz. The corresponding experimental absorption bands over 90% were 3.88-6.08 GHz, 9.95-10.46 GHz and 11.86-13.84 GHz, respectively. The origin of absorption bands was elucidated. Furthermore, it is independent of polarization angle owing to the multilayered circular structures. The design is scalable to smaller size for the infrared and the visible ranges.
Absorber coatings' degradation
Moore, S.W.
1984-01-01
This report is intended to document some of the Los Alamos efforts that have been carried out under the Department of Energy (DOE) Active Heating and Cooling Materials Reliability, Maintainability, and Exposure Testing program. Funding for these activities is obtained directly from DOE although they represent a variety of projects and coordination with other agencies. Major limitations to the use of solar energy are the uncertain reliability and lifetimes of solar systems. This program is aimed at determining material operating limitations, durabilities, and failure modes such that materials improvements can be made and lifetimes can be extended. Although many active and passive materials and systems are being studied at Los Alamos, this paper will concentrate on absorber coatings and degradation of these coatings.
TRANSITION STATE FOR THE GAS-PHASE REACTION OF URANIUM HEXAFLUORIDE WITH WATER
Garrison, S; James Becnel, J
2008-03-18
Density Functional Theory and small-core, relativistic pseudopotentials were used to look for symmetric and asymmetric transitions states of the gas-phase hydrolysis reaction of uranium hexafluoride, UF{sub 6}, with water. At the B3LYP/6-31G(d,p)/SDD level, an asymmetric transition state leading to the formation of a uranium hydroxyl fluoride, U(OH)F{sub 5}, and hydrogen fluoride was found with an energy barrier of +77.3 kJ/mol and an enthalpy of reaction of +63.0 kJ/mol (both including zero-point energy corrections). Addition of diffuse functions to all atoms except uranium led to only minor changes in the structure and relative energies of the reacting complex and transition state. However, a significant change in the product complex structure was found, significantly reducing the enthalpy of reaction to +31.9 kJ/mol. Similar structures and values were found for PBE0 and MP2 calculations with this larger basis set, supporting the B3LYP results. No symmetric transition state leading to the direct formation of uranium oxide tetrafluoride, UOF{sub 4}, was found, indicating that the reaction under ambient conditions likely includes several more steps than the mechanisms commonly mentioned. The transition state presented here appears to be the first published transition state for the important gas-phase reaction of UF{sub 6} with water.
Sobrerol enantiomers and racemates: solid-state spectroscopy, thermal behavior, and phase diagrams.
Bettinetti, G; Giordano, F; Fronza, G; Italia, A; Pellegata, R; Villa, M; Ventura, P
1990-06-01
The characterization of the solid state of sobrerol enantiomers and racemates has been accomplished by a number of techniques on solid phase such as thermal analysis (DSC) and spectroscopy (IR, 13C NMR, and X-ray diffraction both on powders and on single crystal). Experimental and theoretical binary phase diagrams of cis- and trans-sobrerol enantiomers and their mixtures have been drawn and are discussed. Thermal analysis allowed, moreover, the detection of cis racemate polymorphism. Finally, the quantitative analysis of the cis racemate as an impurity of the trans racemate by means of microcalorimetric determinations is reported.
Phase Stability and Equation of State of Vanadium and V-Ti alloys to 220 GPa
NASA Astrophysics Data System (ADS)
Jenei, Zsolt; Cynn, Hyunchae; Evans, William; MacLeod, Simon; Sinogeikin, Stanislav; Meng, Yue
2013-06-01
Experimental studies of vanadium found that during compression it undergoes a phase transition from the low pressure body centered cubic crystal structure to a rhombohedral phase at 65 GPa when compressed under quasihydrostatic conditions and as low as 30 GPa under uniaxial compression (PRB 83, 054101). Theoretical studies are in reasonable agreement with the transition pressure and predict that upon further compression above 200 GPa the bcc phase becomes stable again. The latest study (PRL 103, 235501) predicts that alloying vanadium with small amounts of the neighboring elements can increase or decrease the stability of the bcc phase relative to the rhombohedral phase. We performed powder x-ray diffraction experiments in diamond anvil cell of pure vanadium and V-Ti alloys at ambient temperature up to 220 GPa. In this paper we will discuss our findings related to the stability of the high pressure rhombohedral phase of the pure vanadium and the equation of state, and the influence of the alloying on the EOS. This work performed under the auspices of the US DOE by LLNL under Contract DE-AC52-07NA27344. HPCAT use is supported by DOE-BES, DOE-NNSA, NSF, and the W.M. Keck Foundation. APS is supported by DOE-BES, under Contract No. DE-AC02-06CH11357.
Meeker, Rick; Steurer, Mischa; Li, Hui; Edrington, Chris; Dale, Steinar; Faruque, MD Omar; Schoder, Karl; McLaren, Peter G.; Liu, Liming; Ravindra, Harsha; Henry, Shawn; Zhou, Yan; Liu, Xiaohu; Springstroh, Aaron; Click, David; Reedy, Robert; Moaveni, Houtan; Davis, Kristopher; Cromer, Charlie; Pappalardo, Anthoney; Krueger, Rodica; Domijan, Alexander; Islam, Arif; Islam, Mujahidil; Damole, Ademole
2012-03-30
This report provides details on the activities and accomplishments of Phase 1 of the Sunshine State Solar Grid Initiative (SUNGRIN) Project for the period beginning 4/28/2010 and ending 12/31/2011. SUNGRIN is a five-phase high-penetration solar PV project within the Systems Integration (SI) area of the Solar Energy Technologies (SETP) Program, under the SunShot Initiative. SUNGRIN is focused on understanding and enabling high-penetration grid-connected solar PV through simulation assisted studies of actual Florida utility high-penetration distribution circuits as well as substations and, to a limited extent, the bulk power system. Each phase builds and expands upon the efforts of the previous phase, leading to a comprehensive examination and understanding of high-penetration solar PV issues, from the solar resource to the conversion and integration technologies to the electric power system, with Florida and it’s utility partners providing the broad range of conditions and system integration scenarios necessary to develop useful insight and solutions. This phase, Phase 1, was funded with American Recovery and Reinvestment Act (ARRA) funds. This version of the final report is organized to align with statement of project objectives (SOPO) critical milestones.
Schilt, Stephane; Bucalovic, Nikola; Dolgovskiy, Vladimir; Schori, Christian; Stumpf, Max C; Di Domenico, Gianni; Pekarek, Selina; Oehler, Andreas E H; Südmeyer, Thomas; Keller, Ursula; Thomann, Pierre
2011-11-21
We report the first full stabilization of an optical frequency comb generated from a femtosecond diode-pumped solid-state laser (DPSSL) operating in the 1.5-μm spectral region. The stability of the comb is characterized in free-running and in phase-locked operation by measuring the noise properties of the carrier-envelope offset (CEO) beat, of the repetition rate, and of a comb line at 1558 nm. The high Q-factor of the semiconductor saturable absorber mirror (SESAM)-modelocked 1.5-µm DPSSL results in a low-noise CEO-beat, for which a tight phase lock can be much more easily realized than for a fiber comb. Using a moderate feedback bandwidth of only 5.5 kHz, we achieved a residual integrated phase noise of 0.72 rad rms for the locked CEO, which is one of the smallest values reported for a frequency comb system operating in this spectral region. The fractional frequency stability of the CEO-beat is 20‑fold better than measured in a standard self-referenced commercial fiber comb system and contributes only 10(-15) to the optical carrier frequency instability at 1 s averaging time.
Diversifying the solid state and lyotropic phase behavior of nonionic urea-based surfactants.
Fong, Celesta; Wells, Darrell; Krodkiewska, Irena; Weerawardeena, Asoka; Booth, Jamie; Hartley, Patrick G; Drummond, Calum J
2007-09-13
The solid state and lyotropic phase behavior of 10 new nonionic urea-based surfactants has been characterized. The strong homo-urea interaction, which can prevent urea surfactants from forming lyotropic liquid crystalline phases, has been ameliorated through the use of isoprenoid hydrocarbon tails such as phytanyl (3,7,11,15-tetramethyl-hexadecyl) and hexahydrofarnesyl (3,7,11-trimethyl-dodecyl) or the oleyl chain (cis-octadec-9-enyl). Additionally, the urea head group was modified by attaching either a hydroxy alkyl (short chain alcohol) moiety to one of the nitrogens of the urea or by effectively "doubling" the urea head group by replacing it with a biuret head group. The solid state phase behavior, including the liquid crystal-isotropic liquid, polymorphic, and glass transitions, is interpreted in terms of molecular geometries and probable hydrogen-bonding interactions. Four of the modified urea surfactants displayed ordered lyotropic liquid crystalline phases that were stable in excess water at both room and physiological temperatures, namely, 1-(2-hydroxyethyl)-1-oleyl urea (oleyl 1,1-HEU) with a 1D lamellar phase (Lalpha), 1-(2-hydroxyethyl)-3-phytanyl urea (Phyt 1,3-HEU) with a 2D inverse hexagonal phase (HII), and 1-(2-hydroxyethyl)-1-phytanyl urea (Phyt 1,1-HEU) and 1-(2-hydroxyethyl)-3-hexahydrofarnesyl urea (Hfarn 1,3-HEU) with a 3D bicontinuous cubic phase (QII). Phyt 1,1-HEU exhibited rich mesomorphism (QII1, QII2, Lalpha, LU, and HII), as did one other surfactant, oleyl 1,3-HEU (QII1, QII2, Lalpha, LU, and HII), in the study group. LU is an unusual phase which is mobile and isotropic but possesses shear birefringence, and has been very tentatively assigned as an inverse sponge phase. Three other surfactants exhibited a single lyotropic liquid crystalline phase, either Lalpha or HII, at temperatures >50 degrees C. The 10 new surfactants are compared with other recently reported nonionic urea surfactants. Structure-property correlations are examined for
Nuclear matter at high density: Phase transitions, multiquark states, and supernova outbursts
Krivoruchenko, M. I.; Nadyozhin, D. K.; Rasinkova, T. L.; Simonov, Yu. A.; Trusov, M. A. Yudin, A. V.
2011-03-15
Phase transition from hadronic matter to quark-gluon matter is discussed for various regimes of temperature and baryon number density. For small and medium densities, the phase transition is accurately described in the framework of the Field Correlation Method, whereas at high density predictions are less certain and leave room for the phenomenological models. We study formation of multiquark states (MQS) at zero temperature and high density. Relevant MQS components of the nuclear matter can be described using a previously developed formalism of the quark compound bags (QCB). Partialwave analysis of nucleon-nucleon scattering indicates the existence of 6QS which manifest themselves as poles of P matrix. In the framework of the QCB model, we formulate a self-consistent system of coupled equations for the nucleon and 6QS propagators in nuclear matter and the G matrix. The approach provides a link between high-density nuclear matter with the MQS components and the cumulative effect observed in reactions on the nuclei, which requires the admixture of MQS in the wave functions of nuclei kinematically. 6QS determines the natural scale of the density for a possible phase transition into theMQS phase of nuclear matter. Such a phase transition can lead to dynamic instability of newly born protoneutron stars and dramatically affect the dynamics of supernovae. Numerical simulations show that the phase transition may be a good remedy for the triggering supernova explosions in the spherically symmetric supernovamodels. A specific signature of the phase transition is an additional neutrino peak in the neutrino light curve. For a Galactic core-collapse supernova, such a peak could be resolved by the present neutrino detectors. The possibility of extracting the parameters of the phase of transition from observation of the neutrino signal is discussed also.
Broadband patterned magnetic microwave absorber
Li, Wei; Wu, Tianlong; Wang, Wei; Guan, Jianguo; Zhai, Pengcheng
2014-07-28
It is a tough task to greatly improve the working bandwidth for the traditional flat microwave absorbers because of the restriction of available material parameters. In this work, a simple patterning method is proposed to drastically broaden the absorption bandwidth of a conventional magnetic absorber. As a demonstration, an ultra-broadband microwave absorber with more than 90% absorption in the frequency range of 4–40 GHz is designed and experimentally realized, which has a thin thickness of 3.7 mm and a light weight equivalent to a 2-mm-thick flat absorber. In such a patterned absorber, the broadband strong absorption is mainly originated from the simultaneous incorporation of multiple λ/4 resonances and edge diffraction effects. This work provides a facile route to greatly extend the microwave absorption bandwidth for the currently available absorbing materials.
Liquid Hydrogen Absorber for MICE
Ishimoto, S.; Suzuki, S.; Yoshida, M.; Green, Michael A.; Kuno, Y.; Lau, Wing
2010-05-30
Liquid hydrogen absorbers for the Muon Ionization Cooling Experiment (MICE) have been developed, and the first absorber has been tested at KEK. In the preliminary test at KEK we have successfully filled the absorber with {approx}2 liters of liquid hydrogen. The measured hydrogen condensation speed was 2.5 liters/day at 1.0 bar. No hydrogen leakage to vacuum was found between 300 K and 20 K. The MICE experiment includes three AFC (absorber focusing coil) modules, each containing a 21 liter liquid hydrogen absorber made of aluminum. The AFC module has safety windows to separate its vacuum from that of neighboring modules. Liquid hydrogen is supplied from a cryocooler with cooling power 1.5 W at 4.2 K. The first absorber will be assembled in the AFC module and installed in MICE at RAL.
Electrochemically regenerable carbon dioxide absorber
NASA Technical Reports Server (NTRS)
Woods, R. R.; Marshall, R. D.; Schubert, F. H.; Heppner, D. B.
1979-01-01
Preliminary designs were generated for two electrochemically regenerable carbon dioxide absorber concepts. Initially, an electrochemically regenerable absorption bed concept was designed. This concept incorporated the required electrochemical regeneration components in the absorber design, permitting the absorbent to be regenerated within the absorption bed. This hardware was identified as the electrochemical absorber hardware. The second hardware concept separated the functional components of the regeneration and absorption process. This design approach minimized the extravehicular activity component volume by eliminating regeneration hardware components within the absorber. The electrochemical absorber hardware was extensively characterized for major operating parameters such as inlet carbon dioxide partial pressure, process air flow rate, operational pressure, inlet relative humidity, regeneration current density and absorption/regeneration cycle endurance testing.
Exploring the phase space of multiple states in highly turbulent Taylor-Couette flow
NASA Astrophysics Data System (ADS)
van der Veen, Roeland; Huisman, Sander; Dung, On Yu; Tang, Ho Lun; Sun, Chao; Lohse, Detlef
2015-11-01
It was recently found that multiple turbulent states exist for large Reynolds number (Re =106) Taylor-Couette flow in the regime of ultimate turbulence. Here we investigate how the transitions between the multiple states depend on the Reynolds number in the range of Re =105 to 2 .106 , by measuring global torque and local velocity while probing the phase space spanned by the rotation rates of the inner and outer cylinder. This sheds light on the question whether multiple states persist for Reynolds numbers beyond those currently reached. By mapping the flow structures for various rotation ratios in two Taylor-Couette setups with equal radius ratio but different aspect ratio, we furthermore investigate the influence of aspect ratio on the characteristics of the multiple states.
Solid-state synthesis and phase transformations in Ni/Fe films: Structural and magnetic studies
NASA Astrophysics Data System (ADS)
Myagkov, V. G.; Zhigalov, V. C.; Bykova, L. E.; Bondarenko, G. N.
2006-10-01
We have used X-ray diffraction, volume magnetocrystalline anisotropy constant and resistance measurements to study solid-state synthesis in Ni(0 0 1)/Fe(0 0 1), Ni/Fe(0 0 1) and Ni/Fe thin films with the atomic ratio between Fe and Ni of 1:1 (1Fe:1Ni), and 3:1 (3Fe:1Ni). We have found that the formation of Ni 3Fe and NiFe phases in the 1Fe:1Ni films takes place at temperatures ˜620 and ˜720 K, correspondingly. In the case of the 3Fe:1Ni films the solid-state synthesis starts with Ni 3Fe and NiFe phase formation at the same temperatures as for the 1Fe:1Ni films. The increasing of annealing temperature above 820 K leads to the nucleation of a paramagnetic γpar phase at the FeNi/Fe interface. The final products of solid-state synthesis in the Ni(0 0 1)/Fe(0 0 1) thin films are crystallites which consist of the epitaxially intergrown NiFe and γpar phases according to the [1 0 0](0 0 1)NiFe||[1 0 0](0 0 1) γpar orientation relationship. The crystalline perfection and epitaxial growth of the (NiFe+ γpar) crystallites on the MgO(0 0 1) surface allow to distinguish (0 0 2) γpar and (0 0 2)NiFe X-ray peaks (the cell parameters are: a( γpar)=0.3600±0.0005 nm and a(NiFe)=0.3578±0.0005 nm, correspondingly). At low temperatures the paramagnetic γpar phase undergoes the martensite γ→α' phase transition which can be hindered by thermal and epitaxial strains and epitaxial clamping with a MgO substrate. On the basis of the studies of the thin-film solid-state synthesis we predict the existence of two novel structural phase transformations at the temperatures of about 720 and 820 K for alloys of the invar region of the Fe-Ni system.
Warm Absorber Diagnostics of AGN Dynamics
NASA Astrophysics Data System (ADS)
Kallman, Timothy
Warm absorbers and related phenomena are observable manifestations of outflows or winds from active galactic nuclei (AGN) that have great potential value. Understanding AGN outflows is important for explaining the mass budgets of the central accreting black hole, and also for understanding feedback and the apparent co-evolution of black holes and their host galaxies. In the X-ray band warm absorbers are observed as photoelectric absorption and resonance line scattering features in the 0.5-10 keV energy band; the UV band also shows resonance line absorption. Warm absorbers are common in low luminosity AGN and they have been extensively studied observationally. They may play an important role in AGN feedback, regulating the net accretion onto the black hole and providing mechanical energy to the surroundings. However, fundamental properties of the warm absorbers are not known: What is the mechanism which drives the outflow?; what is the gas density in the flow and the geometrical distribution of the outflow?; what is the explanation for the apparent relation between warm absorbers and the surprising quasi-relativistic 'ultrafast outflows' (UFOs)? We propose a focused set of model calculations that are aimed at synthesizing observable properties of warm absorber flows and associated quantities. These will be used to explore various scenarios for warm absorber dynamics in order to answer the questions in the previous paragraph. The guiding principle will be to examine as wide a range as possible of warm absorber driving mechanisms, geometry and other properties, but with as careful consideration as possible to physical consistency. We will build on our previous work, which was a systematic campaign for testing important class of scenarios for driving the outflows. We have developed a set of tools that are unique and well suited for dynamical calculations including radiation in this context. We also have state-of-the-art tools for generating synthetic spectra, which are
Equation of state and phase diagram of ammonia at high pressures from ab initio simulations
NASA Astrophysics Data System (ADS)
Bethkenhagen, Mandy; French, Martin; Redmer, Ronald
2013-06-01
We present an equation of state as well as a phase diagram of ammonia at high pressures and high temperatures derived from ab initio molecular dynamics simulations. The predicted phases of ammonia are characterized by analyzing diffusion coefficients and structural properties. Both the phase diagram and the subsequently computed Hugoniot curves are compared to experimental results. Furthermore, we discuss two methods that allow us to take into account nuclear quantum effects, which are of considerable importance in molecular fluids. Our data cover pressures up to 330 GPa and a temperature range from 500 K to 10 000 K. This regime is of great interest for interior models of the giant planets Uranus and Neptune, which contain, besides water and methane, significant amounts of ammonia.
Park, Sunghun; Recher, Patrik
2015-12-11
A phase from an adiabatic exchange of Majorana bound states (MBS) reveals their exotic anyonic nature. For detecting this exchange phase, we propose an experimental setup consisting of a Corbino geometry Josephson junction on the surface of a topological insulator, in which two MBS at zero energy can be created and rotated. We find that if a metallic tip is weakly coupled to a point on the junction, the time-averaged differential conductance of the tip-Majorana coupling shows peaks at the tip voltages eV=±(α-2πl)ℏ/T_{J}, where α=π/2 is the exchange phase of the two circulating MBS, T_{J} is the half rotation time of MBS, and l an integer. This result constitutes a clear experimental signature of Majorana fermion exchange.
Equation of state and phase diagram of ammonia at high pressures from ab initio simulations.
Bethkenhagen, Mandy; French, Martin; Redmer, Ronald
2013-06-21
We present an equation of state as well as a phase diagram of ammonia at high pressures and high temperatures derived from ab initio molecular dynamics simulations. The predicted phases of ammonia are characterized by analyzing diffusion coefficients and structural properties. Both the phase diagram and the subsequently computed Hugoniot curves are compared to experimental results. Furthermore, we discuss two methods that allow us to take into account nuclear quantum effects, which are of considerable importance in molecular fluids. Our data cover pressures up to 330 GPa and a temperature range from 500 K to 10,000 K. This regime is of great interest for interior models of the giant planets Uranus and Neptune, which contain, besides water and methane, significant amounts of ammonia. PMID:23802968
Equation of state and phase diagram of ammonia at high pressures from ab initio simulations.
Bethkenhagen, Mandy; French, Martin; Redmer, Ronald
2013-06-21
We present an equation of state as well as a phase diagram of ammonia at high pressures and high temperatures derived from ab initio molecular dynamics simulations. The predicted phases of ammonia are characterized by analyzing diffusion coefficients and structural properties. Both the phase diagram and the subsequently computed Hugoniot curves are compared to experimental results. Furthermore, we discuss two methods that allow us to take into account nuclear quantum effects, which are of considerable importance in molecular fluids. Our data cover pressures up to 330 GPa and a temperature range from 500 K to 10,000 K. This regime is of great interest for interior models of the giant planets Uranus and Neptune, which contain, besides water and methane, significant amounts of ammonia.
Two-dimensional topological insulator state and topological phase transition in bilayer graphene.
Qiao, Zhenhua; Tse, Wang-Kong; Jiang, Hua; Yao, Yugui; Niu, Qian
2011-12-16
We show that gated bilayer graphene hosts a strong topological insulator (TI) phase in the presence of Rashba spin-orbit (SO) coupling. We find that gated bilayer graphene under preserved time-reversal symmetry is a quantum valley Hall insulator for small Rashba SO coupling λ(R), and transitions to a strong TI when λ(R)>√[U(2)+t(⊥)(2)], where U and t(⊥) are, respectively, the interlayer potential and tunneling energy. Different from a conventional quantum spin Hall state, the edge modes of our strong TI phase exhibit both spin and valley filtering, and thus share the properties of both quantum spin Hall and quantum valley Hall insulators. The strong TI phase remains robust in the presence of weak graphene intrinsic SO coupling.
NASA Astrophysics Data System (ADS)
Buehler, Janine Sylvia
The aim of this dissertation is to improve our understanding of the crust and uppermost mantle structure in the western United States, profiting from the wealth of regional phase data recorded at USArray stations. USArray, a transportable seismic array of ˜400 seismometers, has greatly increased seismic data coverage across the United States in the past few years, and allows imaging of the lithosphere of the North American continent with better resolution and new methods. The regional phases are often challenging to analyze, especially in a tectonically-active region like the western United States, because of their sensitivities to the heterogeneities of the crust and uppermost mantle. However, knowledge of the seismic structure of the lithosphere is not only essential in order to accurately image the velocity structure at greater depths, but also for constraining geodynamic models that reconstruct the tectonic evolution of the continent, and hence the information that is carried by the regional phases is very valuable. The data set used in this study consists mostly of the regional seismic phases Pn and Sn, which propagate horizontally along the Moho in the mantle lid and constrain the seismic velocity structure at a confined depth. We applied traditional tomographic methods that profit from the improved ray coverage through USArray, but also employed array-based techniques that take advantage of the regular station spacing of the transportable array and don't depend on regularization. In addition, we used stacking methods to image the propagation efficiency of the Sn phase, which is often highly attenuated in tectonically active regions, on a regional scale. The results complement other seismic studies that average over greater depth intervals, such as surface- and body-wave tomographies and anisotropy analysis from shear-wave splitting, to provide information on temperature, composition, and tectonic processes at depth. Comparisons between Pn azimuthal
Quantum phase transition triggering magnetic bound states in the continuum in graphene
NASA Astrophysics Data System (ADS)
Guessi, L. H.; Marques, Y.; Machado, R. S.; Kristinsson, K.; Ricco, L. S.; Shelykh, I. A.; Figueira, M. S.; de Souza, M.; Seridonio, A. C.
2015-12-01
Graphene hosting a pair of collinear adatoms in the phantom atom configuration has density of states vanishing in the vicinity of the Dirac point which can be described in terms of the pseudogap scaling as cube of the energy, Δ ∝|ɛ| 3 , which leads to the appearance of spin-degenerate bound states in the continuum (BICs) [Phys. Rev. B 92, 045409 (2015), 10.1103/PhysRevB.92.045409]. In the case when adatoms are locally coupled to a single carbon atom the pseudogap scales linearly with energy, which prevents the formation of BICs. Here, we explore the effects of nonlocal coupling characterized by the Fano factor of interference q0, tunable by changing the slope of the Dirac cones in the graphene band structure. We demonstrate that three distinct regimes can be identified: (i) for q0
NASA Astrophysics Data System (ADS)
Slade, Jonathan H.; Knopf, Daniel A.
2014-07-01
Organic aerosol can exhibit different phase states in response to changes in relative humidity (RH), thereby influencing heterogeneous reaction rates with trace gas species. OH radical uptake by laboratory-generated levoglucosan and methyl-nitrocatechol particles, serving as surrogates for biomass burning aerosol, is determined as a function of RH. Increasing RH lowers the viscosity of amorphous levoglucosan aerosol particles enabling enhanced OH uptake. Conversely, OH uptake by methyl-nitrocatechol aerosol particles is suppressed at higher RH as a result of competitive coadsorption of H2O that occupies reactive sites. This is shown to have substantial impacts on organic aerosol lifetimes with respect to OH oxidation. The results emphasize the importance of organic aerosol phase state to accurately describe the multiphase chemical kinetics and thus chemical aging process in atmospheric models to better represent the evolution of organic aerosol and its role in air quality and climate.
Ground state phase transition in the Nilsson mean-field plus standard pairing model
NASA Astrophysics Data System (ADS)
Guan, Xin; Xu, Haocheng; Zhang, Yu; Pan, Feng; Draayer, Jerry P.
2016-08-01
The ground state phase transition in Nd, Sm, and Gd isotopes is investigated by using the Nilsson mean-field plus standard pairing model based on the exact solutions obtained from the extended Heine-Stieltjes correspondence. The results of the model calculations successfully reproduce the critical phenomena observed experimentally in the odd-even mass differences, odd-even differences of two-neutron separation energy, and the α -decay and double β--decay energies of these isotopes. Since the odd-even effects are the most important signatures of pairing interactions in nuclei, the model calculations yield microscopic insight into the nature of the ground state phase transition manifested by the standard pairing interaction.
Cooperative Lamb shift and the cooperative decay rate for an initially detuned phased state
Friedberg, Richard; Manassah, Jamal T.
2010-04-15
The cooperative Lamb shift (CLS) is hard to measure because in samples much larger than a resonant wavelength it is much smaller, for an initially prepared resonantly phased state, than the cooperative decay rate (CDR). We show, however, that if the phasing of the initial state is detuned so that the spatial wave vector is k{sub 1} congruent with k{sub 0{+-}}O((1/R)) (where k{sub 0}={omega}{sub 0}/c is the resonant frequency), the CLS grows to 'giant' magnitudes making it comparable to the CDR. Moreover, for certain controlled values of detuning, the initial CDR becomes small so that the dynamical Lamb shift (DLS) can be measured over a considerable period of time.
Phase transition kinetics and surface binding states of methylammonium lead iodide perovskite.
Rajendra Kumar, G; Dennyson Savariraj, A; Karthick, S N; Selvam, S; Balamuralitharan, B; Kim, Hee-Je; Viswanathan, K K; Vijaykumar, M; Prabakar, Kandasamy
2016-03-14
We have presented a detailed analysis of the phase transition kinetics and binding energy states of solution processed methylammonium lead iodide (MAPbI3) thin films prepared at ambient conditions and annealed at different elevated temperatures. It is the processing temperature and environmental conditions that predominantly control the crystal structure and surface morphology of MAPbI3 thin films. The structural transformation from tetragonal to cubic occurs at 60 °C with a 30 minute annealing time while the 10 minute annealed films posses a tetragonal crystal structure. The transformed phase is greatly intact even at the higher annealing temperature of 150 °C and after a time of 2 hours. The charge transfer interaction between the Pb 4f and I 3d oxidation states is quantified using XPS. PMID:26894928
Graf, D.C.; Warpinski, N.R.
1994-03-01
Laboratory measurements of single-phase, steady-state permeability of porous rock are important for a number of different applications. The oil and gas industry uses permeability data as a key indicator of the producability of a hydrocarbon reservoir; effective containment of large volumes of oil in underground salt caverns is directly dependent upon the permeability of the adjacent cavern walls; and safe, long term underground isolation of radioactive and hazardous waste is contingent upon the flow and transport characteristics of the surrounding geologic formations. An alternative method for measuring single-phase, steady-state permeability of porous rock is presented. The use of troublesome and expensive mass flow meters is eliminated and replaced with a bridge configuration of flow resistors. Permeability values can be determined directly from differential pressures across the bridge network, resulting in potentially significant cost savings and simplification for conducting these types of measurements. Results from the bridge permeameter are compared with results obtained using conventional methods.
Phase Space Analysis of a Gravitationally-Induced, Steady-State Nonequilibrium
NASA Astrophysics Data System (ADS)
Sheehan, D. P.; Glick, J.; Duncan, T.; Langton, J. A.; Gagliardi, M.; Tobe, R.
Recently a new type of pressure gradient was introduced, a gravitationally-induced, dynamically-maintained, steady-state pressure gradient (GDSPG) [D. P. Sheehan and J. Glick, Physica Scripta 61, 635 (2000)]. In this paper, three dimensional numerical test particle simulations detail its phase space structure. These verify the underlying physical mechanism originally hypothesized for its operation and support key assumptions upon which it is based. The GDSPG appears to be a member of a more general class of steady-state nonequilibrium systems that arise under extreme thermodynamic conditions [D. P. Sheehan, Phys. Rev. E57, 6660 (1998)].
Ground State of Magnetic Dipoles on a Two-Dimensional Lattice: Structural Phases in Complex Plasmas
Feldmann, J. D.; Kalman, G. J.; Hartmann, P.; Rosenberg, M.
2008-02-29
We study analytically and by molecular dynamics simulations the ground state configuration of a system of magnetic dipoles fixed on a two-dimensional lattice. We find different phases, in close agreement with previous results. Building on this result and on the minimum energy requirement we determine the equilibrium lattice configuration, the magnetic order (ferromagnetic versus antiferromagnetic), and the magnetic polarization direction of a system of charged mesoscopic particles with magnetic dipole moments, in the domain where the strong electrostatic coupling leads to a crystalline ground state. Orders of magnitudes of the parameters of the system relevant to possible future dusty plasma experiments are discussed.
Two state coercivity driven by phase coexistence in vanadium sesquioxide/nickel bulk hybrid material
NASA Astrophysics Data System (ADS)
Urban, C.; Quesada, A.; Saerbeck, T.; Garcia, M. A.; de la Rubia, M. A.; Valmianski, I.; Fernández, J. F.; Schuller, I. K.
2016-09-01
We developed a bulk hybrid material consisting of a vanadium sesquioxide (V2O3) matrix with nickel (Ni) rich inclusions that exhibit a switchable two-state magnetic coercivity. The V2O3 matrix magnetoelastically couples with the Ni-rich inclusions and its structural phase transition causes two possible magnetic coercivity states. Differences of up to 13% in the temperature window of 14 K are observed, depending whether the transition occurs from rhombohedral to monoclinic or vice versa. These findings provide a pathway for the development of bulk switchable coercivity materials. We present routes to further enhance the magnetoelastic effect by increasing the oxide/ferromagnetic material coupling.
Cascade of quantum phase transitions in tunnel-coupled edge states.
Yang, I; Kang, W; Baldwin, K W; Pfeiffer, L N; West, K W
2004-02-01
We report on the cascade of quantum phase transitions exhibited by tunnel-coupled edge states across a quantum Hall line junction. We identify a series of quantum critical points between successive strong and weak tunneling regimes in the zero-bias conductance. Scaling analysis shows that the conductance near the critical magnetic fields B(c) is a function of a single scaling argument /B-B(c)/T(-kappa), where the exponent kappa=0.42. This puzzling resemblance to a quantum Hall-insulator transition points to the importance of interedge correlation between the coupled edge states.
Invariant criteria for bound states, degree of ionization, and plasma phase transition
NASA Technical Reports Server (NTRS)
Girardeau, M. D.
1990-01-01
Basis invariant characterizations of bound states and bound fraction of a partially ionized hydrogen plasma are given in terms of properties of the spectrum of eigenvalues and eigenfunctions of the equilibrium quantum statistical one-proton-one-electron reduced density matrix. It is suggested that these can be used to place theories of a proposed plasma-ionization phase transition on a firm foundation. This general approach may be relevant to cosmological questions such as the quark deconfinement-confinement transition.
Field-induced switching between states of opposite chirality in a liquid-crystalline phase
NASA Astrophysics Data System (ADS)
Eremin, A.; Diele, S.; Pelzl, G.; Weissflog, W.
2003-02-01
A tilted smectic phase of a new achiral banana-shaped mesogen is presented. It possesses liquidlike order within the layers and appears with a fan-shaped texture. At sufficiently high electric fields, this texture can be transformed into a texture that displays a complete extinction between crossed polarizers and it forms randomly distributed chiral domains. Above a threshold these domains can be reversibly switched into a state of opposite handedness.
Application of the principle of corresponding states to two phase choked flow
NASA Technical Reports Server (NTRS)
Hendricks, R. C.; Simoneau, R. J.
1973-01-01
It is pointed out that several fluids including methane, oxygen, and nitrogen appear to form an average parametric plot which indicates that the isenthalpic Joule-Thomson coefficient must nearly obey the principle of corresponding states. With this as a basis, it was assumed that there could be several thermodynamic flow processes which nearly obey the principle. An examination was made to determine whether two-phase choked flow could be one of them. The analysis is described and the results are given.
Feddema, J.T.; Robinett, R.D.; Driessen, B.J.
1998-03-10
This paper discusses how phase plane analysis can be used to describe the overall behavior of single and multiple autonomous robotic vehicles with finite state machine rules. The importance of this result is that one can begin to design provably asymptotically stable group behaviors from a set of simple control laws and appropriate switching points with decentralized variable structure control. The ability to prove asymptotically stable group behavior is especially important for applications such as locating military targets or land mines.
Phase state of ambient aerosol linked with water uptake and chemical aging in the southeastern US
NASA Astrophysics Data System (ADS)
Pajunoja, Aki; Hu, Weiwei; Leong, Yu J.; Taylor, Nathan F.; Miettinen, Pasi; Palm, Brett B.; Mikkonen, Santtu; Collins, Don R.; Jimenez, Jose L.; Virtanen, Annele
2016-09-01
During the summer 2013 Southern Aerosol and Oxidant Study (SOAS) field campaign in a rural site in the southeastern United States, the effect of hygroscopicity and composition on the phase state of atmospheric aerosol particles dominated by the organic fraction was studied. The analysis is based on hygroscopicity measurements by a Hygroscopic Tandem Differential Mobility Analyzer (HTDMA), physical phase state investigations by an Aerosol Bounce Instrument (ABI) and composition measurements using a high-resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS). To study the effect of atmospheric aging on these properties, an OH-radical oxidation flow reactor (OFR) was used to simulate longer atmospheric aging times of up to 3 weeks. Hygroscopicity and bounce behavior of the particles had a clear relationship showing higher bounce at elevated relative humidity (RH) values for less hygroscopic particles, which agrees well with earlier laboratory studies. Additional OH oxidation of the aerosol particles in the OFR increased the O : C and the hygroscopicity resulting in liquefying of the particles at lower RH values. At the highest OH exposures, the inorganic fraction starts to dominate the bounce process due to production of inorganics and concurrent loss of organics in the OFR. Our results indicate that at typical ambient RH and temperature, organic-dominated particles stay mostly liquid in the atmospheric conditions in the southeastern US, but they often turn semisolid when dried below ˜ 50 % RH in the sampling inlets. While the liquid phase state suggests solution behavior and equilibrium partitioning for the SOA particles in ambient air, the possible phase change in the drying process highlights the importance of thoroughly considered sampling techniques of SOA particles.
Solid state phase equilibria and intermetallic compounds of the Al-Cr-Ho system
Pang, Mingjun; Zhan, Yongzhong; Du, Yong
2013-02-15
The solid state phase equilibria of the Al-Cr-Ho ternary system at 500 Degree-Sign C were experimentally investigated. The phase relations at 500 Degree-Sign C are governed by 14 three-phase regions, 29 two-phase regions and 15 single-phase regions. The existences of 10 binary compounds and 2 ternary phases have been confirmed. Al{sub 11}Cr{sub 2}, Al{sub 11}Cr{sub 4} and Al{sub 17}Ho{sub 2} were not found at 500 Degree-Sign C. Crystal structures of Al{sub 9}Cr{sub 4} and Al{sub 8}Cr{sub 4}Ho were determined by the Rietveld X-ray powder data refinement. Al{sub 9}Cr{sub 4} was found to exhibit cubic structure with space group I4-bar 3m (no. 217) and lattice parameters a=0.9107(5) nm. Al{sub 8}Cr{sub 4}Ho crystallizes in ThMn{sub 12} structure type with space group I4/mmm (no. 139) and lattice parameters a=0.8909(4) nm, c=0.5120(5) nm. It is concluded that the obtained Al{sub 4}Cr phase in this work should be {mu}-Al{sub 4}Cr by comparing with XRD pattern of the hexagonal {mu}-Al{sub 4}Mn compound. - Graphical abstract: The solid state phase equilibria of the Al-Cr-Ho ternary system at 500 Degree-Sign C. Highlights: Black-Right-Pointing-Pointer Al-Cr-Ho system has been investigated. Black-Right-Pointing-Pointer Al{sub 9}Cr{sub 4} has cubic structure with space group I4-bar 3m. Black-Right-Pointing-Pointer Al{sub 8}Cr{sub 4}Ho crystallizes in ThMn{sub 12} type with space group I4/mmm. Black-Right-Pointing-Pointer Al{sub 4}Cr phase is {mu}-type at 500 Degree-Sign C.
ERIC Educational Resources Information Center
Northern Montana Coll., Havre.
The dissemination phase (Phase II) of the Rural Shared Services Project is reported in this document. Efforts of the dissemination phase were concentrated in 5 target states: Vermont, Georgia, Wyoming, Montana, and New Mexico; national dissemination was limited to attendance at national conferences, the U. S. Office of Education PREP materials for…
Classification of ground states and normal modes for phase-frustrated multicomponent superconductors
NASA Astrophysics Data System (ADS)
Weston, Daniel; Babaev, Egor
2013-12-01
We classify ground states and normal modes for n-component superconductors with frustrated intercomponent Josephson couplings, focusing on n=4. The results should be relevant not only to multiband superconductors, but also to Josephson-coupled multilayers and Josephson-junction arrays. It was recently discussed that three-component superconductors can break time-reversal symmetry as a consequence of phase frustration. We discuss how to classify frustrated superconductors with an arbitrary number of components. Although already for the four-component case there are a large number of different combinations of phase-locking and phase-antilocking Josephson couplings, we establish that there are a much smaller number of equivalence classes where properties of frustrated multicomponent superconductors can be mapped to each other. This classification is related to the graph-theoretical concept of Seidel switching. Numerically, we calculate ground states, normal modes, and characteristic length scales for the four-component case. We report conditions of appearance of new accidental continuous ground-state degeneracies.
42 CFR 423.908. - Phased-down State contribution to drug benefit costs assumed by Medicare.
Code of Federal Regulations, 2013 CFR
2013-10-01
... 42 Public Health 3 2013-10-01 2013-10-01 false Phased-down State contribution to drug benefit costs assumed by Medicare. 423.908. Section 423.908. Public Health CENTERS FOR MEDICARE & MEDICAID... General Payment Provisions § 423.908. Phased-down State contribution to drug benefit costs assumed...
42 CFR 423.908. - Phased-down State contribution to drug benefit costs assumed by Medicare.
Code of Federal Regulations, 2012 CFR
2012-10-01
... 42 Public Health 3 2012-10-01 2012-10-01 false Phased-down State contribution to drug benefit costs assumed by Medicare. 423.908. Section 423.908. Public Health CENTERS FOR MEDICARE & MEDICAID... General Payment Provisions § 423.908. Phased-down State contribution to drug benefit costs assumed...
42 CFR 423.908. - Phased-down State contribution to drug benefit costs assumed by Medicare.
Code of Federal Regulations, 2011 CFR
2011-10-01
... 42 Public Health 3 2011-10-01 2011-10-01 false Phased-down State contribution to drug benefit costs assumed by Medicare. 423.908. Section 423.908. Public Health CENTERS FOR MEDICARE & MEDICAID... Provisions § 423.908. Phased-down State contribution to drug benefit costs assumed by Medicare. This...
42 CFR 423.908. - Phased-down State contribution to drug benefit costs assumed by Medicare.
Code of Federal Regulations, 2010 CFR
2010-10-01
... 42 Public Health 3 2010-10-01 2010-10-01 false Phased-down State contribution to drug benefit costs assumed by Medicare. 423.908. Section 423.908. Public Health CENTERS FOR MEDICARE & MEDICAID... Provisions § 423.908. Phased-down State contribution to drug benefit costs assumed by Medicare. This...
42 CFR 423.908. - Phased-down State contribution to drug benefit costs assumed by Medicare.
Code of Federal Regulations, 2014 CFR
2014-10-01
... 42 Public Health 3 2014-10-01 2014-10-01 false Phased-down State contribution to drug benefit costs assumed by Medicare. 423.908. Section 423.908. Public Health CENTERS FOR MEDICARE & MEDICAID... General Payment Provisions § 423.908. Phased-down State contribution to drug benefit costs assumed...
NASA Technical Reports Server (NTRS)
Pogorzelski, Ronald J.
2004-01-01
When electronic oscillators are coupled to nearest neighbors to form an array on a hexagonal lattice, the planar phase distributions desired for excitation of a phased array antenna are not steady state solutions of the governing non-linear equations describing the system. Thus the steady state phase distribution deviates from planar. It is shown to be possible to obtain an exact solution for the steady state phase distribution and thus determine the deviation from the desired planar distribution as a function of beam steering angle.
Parry, J.
1995-02-01
Decontamination of heavy metals-polluted soils remains one of the most intractable problems of cleanup technology. Currently available techniques include extraction of the metals by physical and chemical means, such as acid leaching and electroosmosis, or immobilization by vitrification. There are presently no techniques for cleanup which are low cost and retain soil fertility after metals removal. But a solution to the problem could be on the horizon. A small but growing number of plants native to metalliferous soils are known to be capable of accumulating extremely high concentrations of metals in their aboveground portions. These hyperaccumulators, as they are called, contain up to 1,000 times larger metal concentrations in their aboveground parts than normal species. Their distribution is global, including many different families of flowering plants of varying growth forms, from herbaceous plants to trees. Hyperaccumulators absorb metals they do not need for their own nutrition. The metals are accumulated in the leaf and stem vacuoles, and to a lesser extent in the roots.
Geometry-dependent phase, stress state and electrical properties in nickel-silicide nanowires
NASA Astrophysics Data System (ADS)
Wang, C. C.; Lai, W. T.; Hsiao, Y. Y.; Chen, I. H.; George, T.; Li, P. W.
2016-05-01
We report that the geometry of single-crystalline Si nanowires (NWs) prior to salicidation at 500 °C is the key factor controlling the phase, stress state, and electrical resistivity of the resulting Ni x Si y NWs of width less than 100 nm. This is a radical departure from previous observations of a single phase formation for nickel silicides generated from the silicidation of bulk Si substrates. The phase transition from NiSi for large NWs ( W Si NW = 250-450 nm) to Ni2Si for small NWs ( W Si NW = 70-100 nm) is well correlated with the observed volumetric expansion and electrical resistivity variation with the NW width. For the extremely small dimensions of Ni x Si y NWs, we propose that the preeminent, kinetics-based Zhang and d’Heurle model for salicidation be modified to a more thermodynamically-governed, volume-expansion dependent Ni x Si y phase formation. A novel, plastic deformation mechanism is proposed to explain the observed, geometry-dependent Ni x Si y NW phase formation that also strongly influences the electrical performance of the NWs.
Topological phase and edge states dependence of the RKKY interaction in zigzag silicene nanoribbon
NASA Astrophysics Data System (ADS)
Zare, Moslem; Parhizgar, Fariborz; Asgari, Reza
2016-07-01
We propose versatile materials based on the Ruderman-Kittel-Kasuya-Yosida (RKKY) interaction in a zigzag silicene nanoribbon (ZSNR) on half filling in the presence of an out-of-plane electric field. We show that the topological phase transition in the band dispersion of ZSNR can be probed by using the RKKY interaction. We find that, due to the zero-energy edge states of the ZSNR, the exchange coupling is significantly enhanced when the impurities are located on the zigzag edges, and also explore that the strength of the interaction in the topological insulator phase is much greater than that when the system is in the band insulator region. We present a model to investigate the phase of a system of two magnetic impurities located on the edge of the ZSNR and find that three different magnetic phases, spiral, ferromagnetic, and antiferromagnetic, are possible for different values of the electric field. This electrical tunability of the magnetic phases in silicene can be explored by using current experimental techniques and can be of interest in the field of spintronics.
Equation of state and reaction rate for condensed-phase explosives
NASA Astrophysics Data System (ADS)
Wescott, B. L.; Stewart, D. Scott; Davis, W. C.
2005-09-01
The wide-ranging equation of state is a nonideal equation of state based on empirical fitting forms argued from thermodynamic considerations that yield the proper physical features of detonation. The complete equation of state forms are presented and the equation of state and a reaction rate are calibrated for the condensed-phase explosive PBX-9502. Experimental overdriven Hugoniot data are used to calibrate the products equation of state off the principal isentrope passing through the Chapman-Jouguet state. Shock Hugoniot data are used to calibrate the reactants equation of state. The normal detonation shock speed-shock curvature data (Dn-κ) from rate-stick measurements and shock initiation data from wedge tests are used to calibrate the reaction rate. Simulations are carried out that predict detailed particle velocity transients that are measured experimentally with embedded electromagnetic gauge measurements from gas-gun experiments. Multidimensional simulations of steady detonation in a right circular cylinder rate stick are carried out and compared with experiment.
Leaf absorbance and photosynthesis
NASA Technical Reports Server (NTRS)
Schurer, Kees
1994-01-01
The absorption spectrum of a leaf is often thought to contain some clues to the photosynthetic action spectrum of chlorophyll. Of course, absorption of photons is needed for photosynthesis, but the reverse, photosynthesis when there is absorption, is not necessarily true. As a check on the existence of absorption limits we measured spectra for a few different leaves. Two techniques for measuring absorption have been used, viz. the separate determination of the diffuse reflectance and the diffuse transmittance with the leaf at a port of an integrating sphere and the direct determination of the non-absorbed fraction with the leaf in the sphere. In a cross-check both methods yielded the same results for the absorption spectrum. The spectrum of a Fuchsia leaf, covering the short-wave region from 350 to 2500 nm, shows a high absorption in UV, blue and red, the well known dip in the green and a steep fall-off at 700 nm. Absorption drops to virtually zero in the near infrared, with subsequent absorptions, corresponding to the water absorption bands. In more detailed spectra, taken at 5 nm intervals with a 5 nm bandwidth, differences in chlorophyll content show in the different depths of the dip around 550 nm and in a small shift of the absorption edge at 700 nm. Spectra for Geranium (Pelargonium zonale) and Hibiscus (with a higher chlorophyll content) show that the upper limit for photosynthesis can not be much above 700 nm. No evidence, however, is to be seen of a lower limit for photosynthesis and, in fact, some experiments down to 300 nm still did not show a decrease of the absorption although it is well recognized that no photosynthesis results with 300 nm wavelengths.
Tanaka, T.
1987-03-03
This patent describes a hydraulic shock absorber including a piston reciprocating in a cylinder, a piston upper chamber and a piston lower chamber which are oil-tightly separated by the piston, piston ports formed through the piston in a circle for communicating the piston upper chamber with the piston lower chamber, and return ports formed outside of the piston ports in a circle for communicating the piston upper chamber with the piston lower chamber. It also includes a sheet ring-like non-return valve provided above the piston and fitted to a piston rod, valve holes formed through the non-return valve in opposed relation with the piston ports. A ring-like non-return valve stopper fixed to the piston rod on an upper side of the non-return valve with a small spaced defined between the non-return valve and the non-return valve stopper, and a spring is interposed between the non-return valve and the non-return valve stopper for normally urging the non-return valve to an upper surface of the piston. Movement of the piston to the piston upper chamber allows oil to flow from the piston upper chamber through the piston ports to the piston lower chamber, while the return ports are closed by the non-return valve to generate a vibration damping force by resistance upon pass of the oil through the piston parts. The improvement described here comprises a groove formed in an upper surface of the piston facing the non-return valve and aligned with the valve holes, the groove being in the circle where the piston ports lie and being in communication with the piston ports.
Chimera states in networks of phase oscillators: The case of two small populations
NASA Astrophysics Data System (ADS)
Panaggio, Mark J.; Abrams, Daniel M.; Ashwin, Peter; Laing, Carlo R.
2016-01-01
Chimera states are dynamical patterns in networks of coupled oscillators in which regions of synchronous and asynchronous oscillation coexist. Although these states are typically observed in large ensembles of oscillators and analyzed in the continuum limit, chimeras may also occur in systems with finite (and small) numbers of oscillators. Focusing on networks of 2 N phase oscillators that are organized in two groups, we find that chimera states, corresponding to attracting periodic orbits, appear with as few as two oscillators per group and demonstrate that for N >2 the bifurcations that create them are analogous to those observed in the continuum limit. These findings suggest that chimeras, which bear striking similarities to dynamical patterns in nature, are observable and robust in small networks that are relevant to a variety of real-world systems.
Chimera and phase-cluster states in populations of coupled chemical oscillators
NASA Astrophysics Data System (ADS)
Tinsley, Mark R.; Nkomo, Simbarashe; Showalter, Kenneth
2012-09-01
Populations of coupled oscillators may exhibit two coexisting subpopulations, one with synchronized oscillations and the other with unsynchronized oscillations, even though all of the oscillators are coupled to each other in an equivalent manner. This phenomenon, discovered about ten years ago in theoretical studies, was then further characterized and named the chimera state after the Greek mythological creature made up of different animals. The highly counterintuitive coexistence of coherent and incoherent oscillations in populations of identical oscillators, each with an equivalent coupling structure, inspired great interest and a flurry of theoretical activity. Here we report on experimental studies of chimera states and their relation to other synchronization states in populations of coupled chemical oscillators. Our experiments with coupled Belousov-Zhabotinsky oscillators and corresponding simulations reveal chimera behaviour that differs significantly from the behaviour found in theoretical studies of phase-oscillator models.
Quantum state engineering with flux-biased Josephson phase qubits by rapid adiabatic passages
Nie, W.; Huang, J. S.; Shi, X.; Wei, L. F.
2010-09-15
In this article, the scheme of quantum computing based on the Stark-chirped rapid adiabatic passage (SCRAP) technique [L. F. Wei, J. R. Johansson, L. X. Cen, S. Ashhab, and F. Nori, Phys. Rev. Lett. 100, 113601 (2008)] is extensively applied to implement quantum state manipulations in flux-biased Josephson phase qubits. The broken-parity symmetries of bound states in flux-biased Josephson junctions are utilized to conveniently generate the desirable Stark shifts. Then, assisted by various transition pulses, universal quantum logic gates as well as arbitrary quantum state preparations can be implemented. Compared with the usual {pi}-pulse operations widely used in experiments, the adiabatic population passages proposed here are insensitive to the details of the applied pulses and thus the desirable population transfers can be satisfyingly implemented. The experimental feasibility of the proposal is also discussed.
Competing electronic states in high temperature phase of NaTiO(2).
Dhariwal, M; Pisani, L; Maitra, T
2014-05-21
First principle density functional theory calculations on the high temperature phase of layered triangular lattice system NaTiO2 have revealed that a collective electronic state exists energetically close to the ground state but with competing transport properties: the latter is metallic with partially occupied doubly degenerate e'g orbitals, whereas the former is insulating with a1g orbital fully occupied. Significant occupation of this excited state is possible at non zero temperature either thermally or thanks to very soft (large amplitude) oxygen vibrations. Possible explanations of the experimental low conductivity based on competing orbital transport and of the specific heat jump at a structural transition based on orbital entropy are discussed.
Barkeshli, Maissam; Wen, Xiao-Gang
2010-11-19
We find a series of possible continuous quantum phase transitions between fractional quantum Hall states at the same filling fraction in two-component quantum Hall systems. These can be driven by tuning the interlayer tunneling and/or interlayer repulsion. One side of the transition is the Halperin (p,p,p-3) Abelian two-component state, while the other side is the non-Abelian Z4 parafermion (Read-Rezayi) state. We predict that the transition is a continuous transition in the 3D Ising class. The critical point is described by a Z2 gauged Ginzburg-Landau theory. These results have implications for experiments on two-component systems at ν=2/3 and single-component systems at ν=8/3. PMID:21231341
NASA Astrophysics Data System (ADS)
Barkeshli, Maissam; Wen, Xiao-Gang
2010-11-01
We find a series of possible continuous quantum phase transitions between fractional quantum Hall states at the same filling fraction in two-component quantum Hall systems. These can be driven by tuning the interlayer tunneling and/or interlayer repulsion. One side of the transition is the Halperin (p,p,p-3) Abelian two-component state, while the other side is the non-Abelian Z4 parafermion (Read-Rezayi) state. We predict that the transition is a continuous transition in the 3D Ising class. The critical point is described by a Z2 gauged Ginzburg-Landau theory. These results have implications for experiments on two-component systems at ν=2/3 and single-component systems at ν=8/3.
Chimera states in networks of phase oscillators: The case of two small populations.
Panaggio, Mark J; Abrams, Daniel M; Ashwin, Peter; Laing, Carlo R
2016-01-01
Chimera states are dynamical patterns in networks of coupled oscillators in which regions of synchronous and asynchronous oscillation coexist. Although these states are typically observed in large ensembles of oscillators and analyzed in the continuum limit, chimeras may also occur in systems with finite (and small) numbers of oscillators. Focusing on networks of 2N phase oscillators that are organized in two groups, we find that chimera states, corresponding to attracting periodic orbits, appear with as few as two oscillators per group and demonstrate that for N>2 the bifurcations that create them are analogous to those observed in the continuum limit. These findings suggest that chimeras, which bear striking similarities to dynamical patterns in nature, are observable and robust in small networks that are relevant to a variety of real-world systems.
The use of lipids as phase change materials for thermal energy storage
Technology Transfer Automated Retrieval System (TEKTRAN)
Phase change materials (PCMs) are substances capable of absorbing and releasing large 2 amounts of thermal energy (heat or cold) as latent heat over constant temperature as they 3 undergo a change in state of matter (phase transition), commonly, between solid and 4 liquid phases. Since the late 194...
Metal-shearing energy absorber
NASA Technical Reports Server (NTRS)
Fay, R. J.; Wittrock, E. P.
1971-01-01
Device, consisting of tongue of thin aluminum alloy strip, pull tab, slotted steel plate which serves as cutter, and steel buckle, absorbs mechanical energy when its ends are subjected to tensile loading. Device is applicable as auxiliary shock absorbing anchor for automobile and airplane safety belts.
The broadband dynamic vibration absorber
NASA Astrophysics Data System (ADS)
Hunt, J. B.; Nissen, J.-C.
1982-08-01
The limited effectiveness of the linear passive dynamic vibration absorber is described. This is followed by an analysis producing the response of a primary system when a non-linear softening Belleville spring is used in the absorber. It is shown that the suppression bandwidth can be doubled by this means.
On multiple alternating steady states induced by periodic spin phase perturbation waveforms.
Buračas, Giedrius T; Jung, Youngkyoo; Lee, Jongho; Buxton, Richard B; Wong, Eric C; Liu, Thomas T
2012-05-01
Direct measurement of neural currents by means of MRI can potentially open a high temporal resolution (10-100 ms) window applicable for monitoring dynamics of neuronal activity without loss of the high spatial resolution afforded by MRI. Previously, we have shown that the alternating balanced steady state imaging affords high sensitivity to weak periodic currents owing to its amplification of periodic spin phase perturbations. This technique, however, requires precise synchronization of such perturbations to the radiofrequency pulses. Herein, we extend alternating balanced steady state imaging to multiple balanced alternating steady states for estimation of neural current waveforms. Simulations and phantom experiments show that the off-resonance profile of the multiple alternating steady state signal carries information about the frequency content of driving waveforms. In addition, the method is less sensitive than alternating balanced steady state to precise waveform timing relative to radiofrequency pulses. Thus, multiple alternating steady state technique is potentially applicable to MR imaging of the waveforms of periodic neuronal activity.
Beyer, Andreas; Grohganz, Holger; Löbmann, Korbinian; Rades, Thomas; Leopold, Claudia S
2015-10-27
To benefit from the optimized dissolution properties of active pharmaceutical ingredients in their amorphous forms, co-amorphisation as a viable tool to stabilize these amorphous phases is of both academic and industrial interest. Reports dealing with the physical stability and recrystallization behavior of co-amorphous systems are however limited to qualitative evaluations based on the corresponding X-ray powder diffractograms. Therefore, the objective of the study was to develop a quantification model based on X-ray powder diffractometry (XRPD), followed by a multivariate partial least squares regression approach that enables the simultaneous determination of up to four solid state fractions: crystalline naproxen, γ-indomethacin, α-indomethacin as well as co-amorphous naproxen-indomethacin. For this purpose, a calibration set that covers the whole range of possible combinations of the four components was prepared and analyzed by XRPD. In order to test the model performances, leave-one-out cross validation was performed and revealed root mean square errors of validation between 3.11% and 3.45% for the crystalline molar fractions and 5.57% for the co-amorphous molar fraction. In summary, even four solid state phases, involving one co-amorphous phase, can be quantified with this XRPD data-based approach.
Optimal Gaussian squeezed states for atom interferometry in the presence of phase diffusion
Tikhonenkov, Igor; Moore, Michael G.; Vardi, Amichay
2010-10-15
We optimize the signal-to-noise ratio of a Mach-Zehnder atom interferometer with Gaussian squeezed input states in the presence interactions. For weak interactions, our results coincide with those of Huang and Moore [Y. P. Huang and M. G. Moore, Phys. Rev. Lett. 100, 250406 (2008)], with an optimal initial number variance {sigma}{sub o{proportional_to}}N{sup 1/3} and an optimal signal-to-noise ratio s{sub o{proportional_to}}N{sup 2/3} for the total atom number N. As the interaction strength u increases past unity, phase diffusion becomes dominant, leading to a transition in the optimal squeezing from initial number squeezing to initial phase squeezing with {sigma}{sub o{proportional_to}{radical}}(uN) and s{sub o{proportional_to}{radical}}(N/u) shot-noise scaling. The initial phase squeezing translates into hold-time number squeezing, which is less sensitive to interactions than coherent states and improves s{sub o} by a factor of {radical}(u).
NASA Astrophysics Data System (ADS)
Li, Qiwei; Zhang, Chunmin; Yan, Tingyu; Wei, Yutong
2016-11-01
The basic principle of channeled Fourier-transform imaging spectropolarimeter (CFTISP) is outlined. The two mainstream techniques existing for performing polarization state demodulation are analyzed, which show uncertainty that may not be suitable for CFTISP based on lateral shear interferometer. A modified demodulation method for Stokes parameters is described. The method separate the phase of the sign and the high-order retarders' retardations from the total phase acquired from the fast Fourier transform of the interferogram, which will not cause the amplitude error from the reference beam. Furthermore, the retardations and the residual phase error in each band introduced by instrument can be seen directly in this method. The effectiveness of this method is experimentally demonstrated with four known input states of polarization, and the results are satisfactory. The RMS error of each Stokes parameters is also presented, which demonstrates that the low spectral signal-to-noise ratio can increase the RMS error by nearly a factor of 2-5 for the individual Stokes parameters. The comparison of reconstructed results by four methods further demonstrates the effectiveness of the proposed method.
Lesanovsky, Igor; van Horssen, Merlijn; Guţă, Mădălin; Garrahan, Juan P
2013-04-12
We describe how to characterize dynamical phase transitions in open quantum systems from a purely dynamical perspective, namely, through the statistical behavior of quantum jump trajectories. This approach goes beyond considering only properties of the steady state. While in small quantum systems dynamical transitions can only occur trivially at limiting values of the controlling parameters, in many-body systems they arise as collective phenomena and within this perspective they are reminiscent of thermodynamic phase transitions. We illustrate this in open models of increasing complexity: a three-level system, the micromaser, and a dissipative version of the quantum Ising model. In these examples dynamical transitions are accompanied by clear changes in static behavior. This is however not always the case, and, in general, dynamical phases need to be uncovered by observables which are strictly dynamical, e.g., dynamical counting fields. We demonstrate this via the example of a class of models of dissipative quantum glasses, whose dynamics can vary widely despite having identical (and trivial) stationary states. PMID:25167231
Mott insulating states and quantum phase transitions of correlated SU(2 N ) Dirac fermions
NASA Astrophysics Data System (ADS)
Zhou, Zhichao; Wang, Da; Meng, Zi Yang; Wang, Yu; Wu, Congjun
2016-06-01
The interplay between charge and spin degrees of freedom in strongly correlated fermionic systems, in particular of Dirac fermions, is a long-standing problem in condensed matter physics. We investigate the competing orders in the half-filled SU (2 N ) Hubbard model on a honeycomb lattice, which can be accurately realized in optical lattices with ultracold large-spin alkaline-earth fermions. Employing large-scale projector determinant quantum Monte Carlo simulations, we have explored quantum phase transitions from the gapless Dirac semimetals to the gapped Mott insulating phases in the SU(4) and SU(6) cases. Both of these Mott insulating states are found to be columnar valence bond solid (cVBS) and to be absent of the antiferromagnetic Néel ordering and the loop current ordering. Inside the cVBS phases, the dimer ordering is enhanced by increasing fermion components and behaves nonmonotonically as the interaction strength increases. Although the transitions generally should be of first order due to a cubic invariance possessed by the cVBS order, the coupling to gapless Dirac fermions can soften the transitions to second order through a nonanalytic term in the free energy. Our simulations provide important guidance for the experimental explorations of novel states of matter with ultracold alkaline-earth fermions.
Crosson, Garry S.; Choi, Sunkyung; Chorover, Jon; Amistadi, Mary K.; O'Day, Peggy A.; Mueller, Karl T.
2006-01-19
The weathering of a specimen kaolinite clay was studied over the course of 369 d via solid-state 29Si magic angle spinning (MAS) nuclear magnetic resonance (NMR) spectroscopy and high-field 27Al MAS NMR. The chosen baseline solution conditions (0.05 mol kg-1 of Al, 2 mol kg-1 of Na+, 1 mol kg-1 of NO3 -, 1 mol kg-1 of OH-, and pH ~13.8) approximate those of solutions leaking from waste tanks at the Hanford Site in Richland, WA. Nonradioactive Cs and Sr cations were added to this synthetic tank waste leachate (STWL) solution at concentrations of 10-3, 10-4, and 10-5 molal (m) to represent their radionuclide counterparts. The transformations of silicon- and aluminum-containing solid phase species were monitored quantitatively by using NMR spectroscopy, with the resulting spectra directly reporting the influence of the initial Cs and Sr on formation and transformation of the neo-formed solids. At the lowest concentration of Cs and Sr employed (10-5 m in each cation) peaks consistent with the formation of zeolite-like minerals were detected via 29Si and 27Al MAS NMR as early as 33 d. At concentrations of 10-3 m in each cation, new silicon species are not detected until 93 d, although neophases containing four-coordinate aluminum were detectable at earlier reaction times via 27Al MAS NMR. At the highest magnetic field strengths employed in this NMR study, deconvolutions of resonances detected in the tetrahedral region of the 27Al MAS spectra yielded multiple components, indicating the existence of at least four new aluminum-containing phases. Two of these phases are identified as sodalite and cancrinite through comparison with diffuse-reflectance infrared (DRIFT) spectra and powder X-ray diffraction (XRD) results, while a third phase may correlate with a previously detected aluminum-rich chabazite phase. All measurable solid reaction products have been quantified via their 27Al MAS resonances acquired at high magnetic field strengths (17.6 T), and the quantitative
NASA Astrophysics Data System (ADS)
Ferruzzo Correa, Diego Paolo; Wulff, Claudia; Piqueira, José Roberto Castilho
2015-05-01
In recent years there has been an increasing interest in studying time-delayed coupled networks of oscillators since these occur in many real life applications. In many cases symmetry patterns can emerge in these networks, as a consequence a part of the system might repeat itself, and properties of this subsystem are representative of the dynamics on the whole phase space. In this paper an analysis of the second order N-node time-delay fully connected network is presented which is based on previous work: synchronous states in time-delay coupled periodic oscillators: a stability criterion. Correa and Piqueira (2013), for a 2-node network. This study is carried out using symmetry groups. We show the existence of multiple eigenvalues forced by symmetry, as well as the existence of Hopf bifurcations. Three different models are used to analyze the network dynamics, namely, the full-phase, the phase, and the phase-difference model. We determine a finite set of frequencies ω , that might correspond to Hopf bifurcations in each case for critical values of the delay. The Sn map is used to actually find Hopf bifurcations along with numerical calculations using the Lambert W function. Numerical simulations are used in order to confirm the analytical results. Although we restrict attention to second order nodes, the results could be extended to higher order networks provided the time-delay in the connections between nodes remains equal.
Phase-field study of three-dimensional steady-state growth shapes in directional solidification.
Gurevich, Sebastian; Karma, Alain; Plapp, Mathis; Trivedi, Rohit
2010-01-01
We use a quantitative phase-field approach to study directional solidification in various three-dimensional geometries for realistic parameters of a transparent binary alloy. The geometries are designed to study the steady-state growth of spatially extended hexagonal arrays, linear arrays in thin samples, and axisymmetric shapes constrained in a tube. As a basis to address issues of dynamical pattern selection, the phase-field simulations are specifically geared to identify ranges of primary spacings for the formation of the classically observed "fingers" (deep cells) with blunt tips and "needles" with parabolic tips. Three distinct growth regimes are identified that include a low-velocity regime with only fingers forming, a second intermediate-velocity regime characterized by coexistence of fingers and needles that exist on separate branches of steady-state growth solutions for small and large spacings, respectively, and a third high-velocity regime where those two branches merge into a single one. Along the latter, the growth shape changes continuously from fingerlike to needlelike with increasing spacing. These regimes are strongly influenced by crystalline anisotropy with the third regime extending to lower velocity for larger anisotropy. Remarkably, however, steady-state shapes and tip undercoolings are only weakly dependent on the growth geometry. Those results are used to test existing theories of directional finger growth as well as to interpret the hysteretic nature of the cell-to-dendrite transition.
Topological phase transition and quantum spin Hall state in TlBiS{sub 2}
Singh, Bahadur Prasad, R.; Lin, Hsin; Bansil, A.
2014-07-21
We have investigated the bulk and surface electronic structures and band topology of TlBiS{sub 2} as a function of strain and electric field using ab-initio calculations. In its pristine form, TlBiS{sub 2} is a normal insulator, which does not support any non-trivial surface states. We show however that a compressive strain along the (111) direction induces a single band inversion with Z{sub 2} = (1;000), resulting in a Dirac cone surface state with a large in-plane spin polarization. Our analysis shows that a critical point lies between the normal and topological phases where the dispersion of the 3D bulk Dirac cone at the Γ-point becomes nearly linear. The band gap in thin films of TlBiS{sub 2} can be tuned through an out-of-the-plane electric field to realize a topological phase transition from a trivial insulator to a quantum spin Hall state. An effective k·p model Hamiltonian is presented to simulate our first-principles results on TlBiS{sub 2}.
Berry's phase observed in the ordered state of Fe(Se,S)
NASA Astrophysics Data System (ADS)
Kasahara, Shigeru; Yamashita, T.; Shimoyama, Y.; Watashige, T.; Matsuda, Y.; Béard, J.; Nardone, M.; Knafo, W.; Watson, M. D.; Davis, N. R.; Coldea, A. I.; Suzuki, M.; Arita, R.; Ikeda, H.; Shibauchi, T.
Among iron-based superconductors, FeSe offers a unique platform in that it exhibits a nematically ordered phase without long-range magnetic ordering. Several experiments have shown that the low-temperature Fermi surface of FeSe consists only of very small, shallow pockets [1-3]. Tuning the ground state via isoelectronic chemical substitution provides an ideal way to solve the puzzles regarding the nematic ordering in this material. Here, by using ultra-high magnetic fields up to ~ 90 T, we report observations of Shubnikov-de Haas (SdH) oscillations in isoelectronically substituted Fe(Se,S). For the smallest pocket of ~ 0 . 2 % of the Brillouin-zone, we observe non-zero π Berry's phase shift in the SdH oscillations. Our results indicate presence of Dirac cone, which would be a key to understand the mechanism of the nematic ordering in this system.
Quantum metrology with two-mode squeezed thermal state: Parity detection and phase sensitivity
NASA Astrophysics Data System (ADS)
Li, Heng-Mei; Xu, Xue-Xiang; Yuan, Hong-Chun; Wang, Zhen
2016-10-01
Based on the Wigner-function method, we investigate the parity detection and phase sensitivity in a Mach-Zehnder interferometer (MZI) with two-mode squeezed thermal state (TMSTS). Using the classical transformation relation of the MZI, we derive the input-output Wigner functions and then obtain the explicit expressions of parity and phase sensitivity. The results from the numerical calculation show that supersensitivity can be reached only if the input TMSTS have a large number photons. Project supported by the National Natural Science Foundation of China (Grant No. 11447002), the Research Foundation of the Education Department of Jiangxi Province of China (Grant No. GJJ150338), and the Research Foundation for Changzhou Institute of Modern Optoelectronic Technology (Grant No. CZGY15).
Qubit phase space: SU(n) coherent-state P representations
NASA Astrophysics Data System (ADS)
Barry, D. W.; Drummond, P. D.
2008-11-01
We introduce a phase-space representation for qubits and spin models. The technique uses an SU(n) coherent-state basis and can equally be used for either static or dynamical simulations. We review previously known definitions and operator identities, and show how these can be used to define an off-diagonal, positive phase-space representation analogous to the positive- P function. As an illustration of the phase-space method, we use the example of the Ising model, which has exact solutions for the finite-temperature canonical ensemble in two dimensions. We show how a canonical ensemble for an Ising model of arbitrary structure can be efficiently simulated using SU(2) or atomic coherent states. The technique utilizes a transformation from a canonical (imaginary-time) weighted simulation to an equivalent unweighted real-time simulation. The results are compared to the exactly soluble two-dimensional case. We note that Ising models in one, two, or three dimensions are potentially achievable experimentally as a lattice gas of ultracold atoms in optical lattices. The technique is not restricted to canonical ensembles or to Ising-like couplings. It is also able to be used for real-time evolution and for systems whose time evolution follows a master equation describing decoherence and coupling to external reservoirs. The case of SU(n) phase space is used to describe n -level systems. In general, the requirement that time evolution be stochastic corresponds to a restriction to Hamiltonians and master equations that are quadratic in the group generators or generalized spin operators.
Kamarchik, Eugene; Jasper, Ahren W
2013-05-21
An algorithm is presented for calculating fully anharmonic vibrational state counts, state densities, and partition functions for molecules using Monte Carlo integration of classical phase space. The algorithm includes numerical evaluations of the elements of the Jacobian and is general enough to allow for sampling in arbitrary curvilinear or rectilinear coordinate systems. Invariance to the choice of coordinate system is demonstrated for vibrational state densities of methane, where we find comparable sampling efficiency when using curvilinear z-matrix and rectilinear Cartesian normal mode coordinates. In agreement with past work, we find that anharmonicity increases the vibrational state density of methane by a factor of ∼2 at its dissociation threshold. For the vinyl radical, we find a significant (∼10×) improvement in sampling efficiency when using curvilinear z-matrix coordinates relative to Cartesian normal mode coordinates. We attribute this improved efficiency, in part, to a more natural curvilinear coordinate description of the double well associated with the H2C-C-H wagging motion. The anharmonicity correction for the vinyl radical state density is ∼1.4 at its dissociation threshold. Finally, we demonstrate that with trivial parallelizations of the Monte Carlo step, tractable calculations can be made for the vinyl radical using direct ab initio potential energy surface evaluations and a composite QCISD(T)/MP2 method.
NASA Astrophysics Data System (ADS)
Liu, Zhao; Vaezi, Abolhassan; Lee, Kyungmin; Kim, Eun-Ah
2015-08-01
Recent theoretical insights into the possibility of non-Abelian phases in ν =2 /3 fractional quantum Hall states revived the interest in the numerical phase diagram of the problem. We investigate the effect of various kinds of two-body interlayer couplings on the (330) bilayer state and exactly solve the Hamiltonian for up to 14 electrons on sphere and torus geometries. We consider interlayer tunneling, short-ranged repulsive/attractive pseudopotential interactions, and Coulomb repulsion. We find a 6-fold ground-state degeneracy on the torus when the interlayer hollow-core interaction is dominant. To identify the topological nature of this phase we measure the orbital-cut entanglement spectrum, quasihole counting, topological entanglement entropy, and wave-function overlap. Comparing the numerical results to the theoretical predictions, we interpret this 6-fold ground-state degeneracy phase to be the non-Abelian bilayer Fibonacci state.
Absorbent product to absorb fluids. [for collection of human wastes
NASA Technical Reports Server (NTRS)
Dawn, F. S.; Correale, J. V. (Inventor)
1982-01-01
A multi-layer absorbent product for use in contact with the skin to absorb fluids is discussed. The product utilizes a water pervious facing layer for contacting the skin, overlayed by a first fibrous wicking layer, the wicking layer preferably being of the one-way variety in which fluid or liquid is moved away from the facing layer. The product further includes a first container section defined by inner and outer layer of a water pervious wicking material between which is disposed a first absorbent mass. A second container section defined by inner and outer layers between which is disposed a second absorbent mass and a liquid impermeable/gas permeable layer. Spacesuit applications are discussed.
Determination of neutron absorbed doses in lithium aluminates.
Delfín Loya, A; Carrera, L M; Ureña-Núñez, F; Palacios, O; Bosch, P
2003-04-01
Lithium-based ceramics have been proposed as tritium breeders for fusion reactors. The lithium aluminate (gamma phase) seems to be thermally and structurally stable, the damages produced by neutron irradiation depend on the absorbed dose. A method based on the measurement of neutron activation of foils through neutron capture has been developed to obtain the neutron absorbed dose in lithium aluminates irradiated in the thermal column facility and in the fixed irradiation system of a Triga Mark III Nuclear Reactor. PMID:12672632
NASA Astrophysics Data System (ADS)
Miškovičová, Ivica; Hell, Natalie; Hanke, Manfred; Nowak, Michael A.; Pottschmidt, Katja; Schulz, Norbert S.; Grinberg, Victoria; Duro, Refiz; Madej, Oliwia K.; Lohfink, Anne M.; Rodriguez, Jérôme; Cadolle Bel, Marion; Bodaghee, Arash; Tomsick, John A.; Lee, Julia C.; Brown, Gregory V.; Wilms, Jörn
2016-05-01
Accretion onto the black hole in the system HDE 226868/Cygnus X-1 is powered by the strong line-driven stellar wind of the O-type donor star. We study the X-ray properties of the stellar wind in the hard state of Cyg X-1, as determined using data from the Chandra High Energy Transmission Gratings. Large density and temperature inhomogeneities are present in the wind, with a fraction of the wind consisting of clumps of matter with higher density and lower temperature embedded in a photoionized gas. Absorption dips observed in the light curve are believed to be caused by these clumps. This work concentrates on the non-dip spectra as a function of orbital phase. The spectra show lines of H-like and He-like ions of S, Si, Na, Mg, Al, and highly ionized Fe (Fe xvii-Fe xxiv). We measure velocity shifts, column densities, and thermal broadening of the line series. The excellent quality of these five observations allows us to investigate the orbital phase-dependence of these parameters. We show that the absorber is located close to the black hole. Doppler shifted lines point at a complex wind structure in this region, while emission lines seen in some observations are from a denser medium than the absorber. The observed line profiles are phase-dependent. Their shapes vary from pure, symmetric absorption at the superior conjunction to P Cygni profiles at the inferior conjunction of the black hole.
Phase transitions and universality in nonequilibrium steady states of stochastic Ising models
Wang, J.S.; Lebowitz, J.L.
1988-06-01
We present results of direct computer simulations and of Monte Carlo renormalization group (MCRG) studies of the nonequilibrium steady states of a spin system with competing dynamics and of the voter model. The MCRG method, previously used only for equilibrium systems, appears to give useful information also for these nonequilibrium systems. The critical exponents are found to be of Ising type for the competing dynamics model at its second-order phase transitions, and of mean-field type for the voter model (consistent with known results for the latter).
Low-temperature solid-state phase transformations in 2H silicon carbide.
NASA Technical Reports Server (NTRS)
Powell, J. A.; Will, H. A.
1972-01-01
Study of the phase transformations taking place in 2H SiC single crystals at temperatures as low as 400 C. Some crystals transformed to a structure with one-dimensional disorder along the crystal c axis. Others transformed to a faulted cubic/6H structure. The transformation is time and temperature dependent, and is greatly enhanced by dislocations. The transformation takes place by means of a slip process perpendicular to the c axis. Cubic SiC crystals were observed to undergo a solid-state transformation above 1400 C.
Low-temperature solid-state phase transformations in 2H silicon carbide
NASA Technical Reports Server (NTRS)
Will, H. A.; Powell, J. A.
1972-01-01
Single crystals of 2H SiC were observed to undergo phase transformations at temperatures as low as 400 C. Some 2H crystals transformed to a structure with one-dimensional disorder along the crystal c axis. Others transformed to a faulted cubic/6H structure. The transformation is time and temperature dependent and is greatly enhanced by dislocations. Observations indicate that the transformation takes place by means of a slip process perpendicular to the c axis. Cubic SiC crystals were observed to undergo a solid state transformation above 1400 C.
On a quantum phase transition in a steady state out of equilibrium
NASA Astrophysics Data System (ADS)
Aschbacher, Walter H.
2016-10-01
Within the rigorous axiomatic framework for the description of quantum mechanical systems with a large number of degrees of freedom, we show that the nonequilibrium steady state, constructed in the quasifree fermionic system corresponding to the isotropic XY chain in which a finite sample, coupled to two thermal reservoirs at different temperatures, is exposed to a local external magnetic field, is breaking translation invariance and exhibits a strictly positive entropy production rate. Moreover, we prove that there exists a second-order nonequilibrium quantum phase transition with respect to the strength of the magnetic field as soon as the system is truly out of equilibrium.
Phase transition and equation of state of paratellurite (TeO2) under high pressure
NASA Astrophysics Data System (ADS)
Liu, Xun; Mashimo, Tsutomu; Kawai, Nobuaki; Sekine, Toshimori; Zeng, Zhaoyi; Zhou, Xianming
2016-07-01
The Hugoniot data for TeO2 single crystals were obtained for pressures up to ˜85 GPa along both the <100> (a-axis) and <001> (c-axis) directions using a velocity interferometer system for any reflector and inclined-mirror method combined with a powder gun or two-stage light gas gun. The Hugoniot-elastic limit of TeO2 was determined to be 3.3-4.3 GPa along the c-axes. The shock velocity (U s) versus particle velocity (U p) relation for TeO2 shows a kink around U p = 1.0 km s-1, which suggests a phase transition completes at ˜26 ± 2 GPa. The Hugoniot relations of the low and high pressure phase are given by U s = 3.13(5) + 1.10(6)U p for U p < 1.0 km s-1 and U s = 2.73(9) + 1.49(5)U p for U p > 1.0 km s-1, respectively. First-principles geometry optimizations based on the generalized gradient approximation after Perdew, Burke and Ernzerhof method were also performed on TeO2. It suggested that a continuous structure distortion occurs up to 22 GPa, and the lattice parameters b and c abruptly increase and decrease at 22 GPa, respectively, indicating a first-order phase transition to the cotunnite structure phase. The equation of state of the cotunnite phase TeO2 is discussed based on the experimental and simulation results.
Phase transition and equation of state of paratellurite (TeO2) under high pressure
NASA Astrophysics Data System (ADS)
Liu, Xun; Mashimo, Tsutomu; Kawai, Nobuaki; Sekine, Toshimori; Zeng, Zhaoyi; Zhou, Xianming
2016-07-01
The Hugoniot data for TeO2 single crystals were obtained for pressures up to ∼85 GPa along both the <100> (a-axis) and <001> (c-axis) directions using a velocity interferometer system for any reflector and inclined-mirror method combined with a powder gun or two-stage light gas gun. The Hugoniot-elastic limit of TeO2 was determined to be 3.3–4.3 GPa along the c-axes. The shock velocity (U s) versus particle velocity (U p) relation for TeO2 shows a kink around U p = 1.0 km s‑1, which suggests a phase transition completes at ∼26 ± 2 GPa. The Hugoniot relations of the low and high pressure phase are given by U s = 3.13(5) + 1.10(6)U p for U p < 1.0 km s‑1 and U s = 2.73(9) + 1.49(5)U p for U p > 1.0 km s‑1, respectively. First-principles geometry optimizations based on the generalized gradient approximation after Perdew, Burke and Ernzerhof method were also performed on TeO2. It suggested that a continuous structure distortion occurs up to 22 GPa, and the lattice parameters b and c abruptly increase and decrease at 22 GPa, respectively, indicating a first-order phase transition to the cotunnite structure phase. The equation of state of the cotunnite phase TeO2 is discussed based on the experimental and simulation results.
Self-Regulating Shock Absorber
NASA Technical Reports Server (NTRS)
Wesselski, Clarence J.
1995-01-01
Mechanical shock absorber keeps frictional damping force within tolerable limit. Its damping force does not increase with coefficient of friction between energy-absorbing components; rather, frictional damping force varies only slightly. Relatively insensitive to manufacturing variations and environmental conditions altering friction. Does not exhibit high breakaway friction and consequent sharp increase followed by sharp decrease in damping force at beginning of stroking. Damping force in absorber does not vary appreciably with speed of stroking. In addition, not vulnerable to leakage of hydraulic fluid.
Kumfer, Benjamin M; Shinoda, Kozo; Jeyadevan, Balachandran; Kennedy, Ian M
2010-01-01
Iron oxide nanoparticles of reduced oxidation state, mainly in the form of magnetite, have been synthesized utilizing a new continuous, gas-phase, nonpremixed flame method using hydrocarbon fuels. This method takes advantage of the characteristics of the inverse flame, which is produced by injection of oxidizer into a surrounding flow of fuel. Unlike traditional flame methods, this configuration allows for the iron particle formation to be maintained in a more reducing environment. The effects of flame temperature, oxygen-enrichment and fuel dilution (i.e. the stoichiometric mixture fraction), and fuel composition on particle size, Fe oxidation state, and magnetic properties are evaluated and discussed. The crystallite size, Fe(II) fraction, and saturation magnetization were all found to increase with flame temperature. Flames of methane and ethylene were used, and the use of ethylene resulted in particles containing metallic Fe(0), in addition to magnetite, while no Fe(0) was present in samples synthesized using methane. PMID:20228941
The Potential Economic Impact of Electricity Restructuring in the State of Oklahoma: Phase II Report
Hadley, SW
2001-10-30
Because of the recent experiences of several states undergoing restructuring (e.g., higher prices, greater volatility, lower reliability), concerns have been raised in states currently considering restructuring as to whether their systems are equally vulnerable. Factors such as local generation costs, transmission constraints, market concentration, and market design can all play a role in the success or failure of the market. These factors along with the mix of generation capacity supplying the state will influence the relative prices paid by consumers. The purpose of this project is to provide a model and process to evaluate the potential price and economic impacts of restructuring the Oklahoma electric industry. The Phase I report concentrated on providing an analysis of the Oklahoma system in the near-term, using only present generation resources and customer demands. This Phase II study analyzed the Oklahoma power market in 2010, incorporating the potential of new generation resources and customer responses. Five key findings of this Phase II were made: (1) Projected expansion in generating capacity exceeds by over 3,000 MW the demands within the state plus the amount that could be exported with the current transmission system. (2) Even with reduced new plant construction, most new plants could lose money (although residential consumers would see lower rates) unless they have sufficient market power to raise their prices without losing significant market share (Figure S-1). (3) If new plants can raise prices to stay profitable, existing low-cost coal and hydro plants will have very high profits. Average prices to customers could be 5% to 25% higher than regulated rates (Figure S-1). If the coal and hydro plants are priced at cost-based rates (through long-term contracts or continued regulation) while all other plants use market-based rates then prices are lower. (4) Customer response to real-time prices can lower the peak capacity requirements by around 9
Space Evaporator Absorber Radiator (SEAR) for Thermal Storage on Manned Spacecraft
NASA Technical Reports Server (NTRS)
Izenson, Michael G.; Chen, Weibo; Chepko, Ariane; Bue, Grant; Quinn, Gregory
2014-01-01
Future manned exploration spacecraft will need to operate in challenging thermal environments. State-of the- art technology for active thermal control relies on sublimating water ice and venting the vapor overboard in very hot environments. This approach can lead to large loss of water and a significant mass penalty for the spacecraft. This paper describes an innovative thermal control system that uses a Space Evaporator Absorber Radiator (SEAR) to control spacecraft temperatures in highly variable environments without venting water. SEAR uses heat pumping and energy storage by LiCl/water absorption to enable effective cooling during hot periods and regeneration during cool periods. The LiCl absorber technology has the potential to absorb over 800 kJ per kg of system mass, compared to phase change heat sink systems that typically achieve approx. 50 kJ/kg. The optimal system is based on a trade-off between the mass of water saved and extra power needed to regenerate the LiCl absorber. This paper describes analysis models and the predicted performance and optimize the size of the SEAR system, estimated size and mass of key components, and power requirements for regeneration. We also present a concept design for an ISS test package to demonstrate operation of a subscale system in zero gravity.
Nakatani, Chie; Chehelcheraghi, Mojtaba; Jarrahi, Behnaz; Nakatani, Hironori; van Leeuwen, Cees
2013-01-01
In active vision, eye-movements depend on perceivers' internal state. We investigated peri-fixation brain activity for internal state-specific tagging. Human participants performed a task, in which a visual object was presented for identification in lateral visual field, to which they moved their eyes as soon as possible from a central fixation point. Next, a phrase appeared in the same location; the phrase could either be an easy or hard question about the object, answered by pressing one of two alternative response buttons, or it could be an instruction to simply press one of these two buttons. Depending on whether these messages were blocked or randomly mixed, one of two different internal states was induced: either the task was known in advance or it wasn't. Eye movements and electroencephalogram (EEG) were recorded simultaneously during task performance. Using eye-event-time-locked averaging and independent component analysis, saccade- and fixation-related components were identified. Coss-frequency phase-synchrony was observed between the alpha/beta1 ranges of fixation-related and beta2/gamma1 ranges of saccade-related activity 50 ms prior to fixation onset in the mixed-phrase condition only. We interpreted this result as evidence for internal state-specific tagging. PMID:23754990
Corrections of Hayes Equation of State for Phase Transform under Dynamic Loading
NASA Astrophysics Data System (ADS)
Chong, Tao
Abstract: The experimental results of iron under ramp wave and shock compression are simulated with Hayes equation of state (EOS) for phase transition. The calculated results are consistent with the experimental data under shock, and don't agree well with the data under ramp wave loading. The reason for the problem is that the bulk modulus in Hayes model is constant (i.e., Bulk sound speed is constant). The sound speed corresponds to the slope of the Rayleigh line when materials leap from the initial state to the final state under shock loading, therefore, the bulk modulus can be considered as a constant. However, under ramp loading, material from initial to the final state is consecutive, and the bulk modulus is not a constant any more but a function of pressure and temperature. The bulk modulus of Hayes EOS is corrected with Murnaghan EOS, and the corrected Hayes EOS is applies to simulate the experimental results. The results show that the calculated data agree well with the experimental data under both shock and ramp wave loadings. . I hope you give me an oral presentation, otherwise I might not be able to attend the meeting.
Stabilizing the phase of superpositions of cat states in a cavity using real-time feedback
NASA Astrophysics Data System (ADS)
Ofek, N.; Petrenko, A.; Heeres, R.; Reinhold, P.; Liu, Y.; Leghtas, Z.; Vlastakis, B.; Frunzio, L.; Jiang, Liang; Mirrahimi, M.; Devoret, M. H.; Schoelkopf, R. J.
In a superconducting cQED architecture, a hardware efficient quantum error correction (QEC) scheme exists, called the cat code, which maps a qubit onto superpositions of cat states in a superconducting resonator, by mapping the occurrence of errors, or single photon jumps, onto unitary rotations of the encoded state. By tracking the parity of the encoded state, we can count the number of photon jumps and are able to apply a correcting unitary transformation. However, the situation is complicated by the fact that photon jumps do not commute with the deterministic anharmonic time evolution of a resonator state, or Kerr, inherited by the resonator from its coupling to a Josephson junction. As predicted in, a field in the resonator will inherit an overall phase θ = KT in IQ space each time a photon jumps that is proportional to the Kerr K and the time T at which the jump occurs. Here I will present how we can track the errors in real time, take them into account together with the time they occur and make it possible to stabilize the qubit information. Please place my talk right after the talk of Andrei Petrenko.
NASA Astrophysics Data System (ADS)
Yoshii, Ryosuke; Takada, Satoshi; Tsuchiya, Shunji; Marmorini, Giacomo; Hayakawa, Hisao; Nitta, Muneto
2015-12-01
We find the angular Fulde-Ferrell-Larkin-Ovchinnikov (FFLO) states (or the twisted kink crystals) in which a phase and an amplitude of a pair potential modulate simultaneously in a quasi-one-dimensional superconducting ring with a static Zeeman magnetic field applied on the ring and static Aharonov-Bohm magnetic flux penetrating the ring. The superconducting ring with magnetic flux produces a persistent current, whereas the Zeeman split of Fermi energy results in the spatial modulation of the pair potential. We show that these two magnetic fields stabilize the FFLO phase in a large parameter region of the magnetic fields. We further draw the phase diagram with the two kinds of first-order phase transitions; one corresponds to phase slips separating the Aharonov-Bohm magnetic flux, and the other separates the number of peaks of the pair amplitude for the Zeeman magnetic field.
Equation of State of CAS Phase to Pressure of the Uppermost Lower Mantle at Ambient Temperature
X Liu; Q He; L Deng; S Zhai; X Hu; B Li; L Zhang; Z Chen; L Qiong
2011-12-31
The CAS phase is a major constituent phase for the continental crust and basaltic compositions at the P-T conditions of the Earth's mantle, and potentially plays an important role in the geodynamic processes related to slab subduction. Its equation of state has been investigated here at ambient temperature up to about 25 GPa by using a diamond-anvil cell and synchrotron X-ray radiation. Its P-V data, fitted to the third-order Birch-Murnaghan equation, yield an isothermal bulk modulus (K'{sub T}) of 185 (9) GPa and first pressure derivative (K'{sub T} ) of 7.2 (12). If K'{sub T} is fixed at 4, the derived K{sub T} is 212 (4) GPa. Additionally, the CAS phase is strongly elastically anisotropic, with its a-axis direction much less compressible than c-axis direction: K{sub T-a}:K{sub T-c} = 2.19.
Phase control of squeezed vacuum states of light in gravitational wave detectors.
Dooley, K L; Schreiber, E; Vahlbruch, H; Affeldt, C; Leong, J R; Wittel, H; Grote, H
2015-04-01
Quantum noise will be the dominant noise source for the advanced laser interferometric gravitational wave detectors currently under construction. Squeezing-enhanced laser interferometers have been recently demonstrated as a viable technique to reduce quantum noise. We propose two new methods of generating an error signal for matching the longitudinal phase of squeezed vacuum states of light to the phase of the laser interferometer output field. Both provide a superior signal to the one used in previous demonstrations of squeezing applied to a gravitational-wave detector. We demonstrate that the new signals are less sensitive to misalignments and higher order modes, and result in an improved stability of the squeezing level. The new signals also offer the potential of reducing the overall rms phase noise and optical losses, each of which would contribute to achieving a higher level of squeezing. The new error signals are a pivotal development towards realizing the goal of 6 dB and more of squeezing in advanced detectors and beyond. PMID:25968662
A Simple State-Determined Model Reproduces Entrainment and Phase-Locking of Human Walking
Ahn, Jooeun; Hogan, Neville
2012-01-01
Theoretical studies and robotic experiments have shown that asymptotically stable periodic walking may emerge from nonlinear limit-cycle oscillators in the neuro-mechanical periphery. We recently reported entrainment of human gait to periodic mechanical perturbations with two essential features: 1) entrainment occurred only when the perturbation period was close to the original (preferred) walking period, and 2) entrainment was always accompanied by phase locking so that the perturbation occurred at the end of the double-stance phase. In this study, we show that a highly-simplified state-determined walking model can reproduce several salient nonlinear limit-cycle behaviors of human walking: 1) periodic gait that is 2) asymptotically stable; 3) entrainment to periodic mechanical perturbations only when the perturbation period is close to the model's unperturbed period; and 4) phase-locking to locate the perturbation at the end of double stance. Importantly, this model requires neither supra-spinal control nor an intrinsic self-sustaining neural oscillator such as a rhythmic central pattern generator. Our results suggest that several prominent limit-cycle features of human walking may stem from simple afferent feedback processes without significant involvement of supra-spinal control or a self-sustaining oscillatory neural network. PMID:23152761
Rhone, Ariane E.; Idsardi, William J.; Simon, Jonathan Z.; Poeppel, David
2013-01-01
Most ecologically natural sensory inputs are not limited to a single modality. While it is possible to use real ecological materials as experimental stimuli to investigate the neural basis of multi-sensory experience, parametric control of such tokens is limited. By using artificial bimodal stimuli composed of approximations to ecological signals, we aim to observe the interactions between putatively relevant stimulus attributes. Here we use MEG as an electrophysiological tool and employ as a measure the steady-state response (SSR), an experimental paradigm typically applied to unimodal signals. In this experiment we quantify the responses to a bimodal audio-visual signal with different degrees of temporal (phase) congruity, focusing on stimulus properties critical to audiovisual speech. An amplitude modulated auditory signal (‘pseudo-speech’) is paired with a radius-modulated ellipse (‘pseudo-mouth’), with the envelope of low-frequency modulations occurring in phase or at offset phase values across modalities. We observe (i) that it is possible to elicit an SSR to bimodal signals; (ii) that bimodal signals exhibit greater response power than unimodal signals; and (iii) that the SSR power at specific harmonics and sensors differentially reflects the congruity between signal components. Importantly, we argue that effects found at the modulation frequency and second harmonic reflect differential aspects of neural coding of multisensory signals. The experimental paradigm facilitates a quantitative characterization of properties of multi-sensory speech and other bimodal computations. PMID:21380858
Countercurrent flow absorber and desorber
Wilkinson, William H.
1984-01-01
Countercurrent flow absorber and desorber devices are provided for use in absorption cycle refrigeration systems and thermal boosting systems. The devices have increased residence time and surface area resulting in improved heat and mass transfer characteristics. The apparatuses may be incorporated into open cycle thermal boosting systems in which steam serves both as the refrigerant vapor which is supplied to the absorber section and as the supply of heat to drive the desorber section of the system.
Countercurrent flow absorber and desorber
Wilkinson, W.H.
1984-10-16
Countercurrent flow absorber and desorber devices are provided for use in absorption cycle refrigeration systems and thermal boosting systems. The devices have increased residence time and surface area resulting in improved heat and mass transfer characteristics. The apparatuses may be incorporated into open cycle thermal boosting systems in which steam serves both as the refrigerant vapor which is supplied to the absorber section and as the supply of heat to drive the desorber section of the system. 9 figs.
Decoherence of odd compass states in the phase-sensitive amplifying/dissipating environment
NASA Astrophysics Data System (ADS)
Dodonov, V. V.; Valverde, C.; Souza, L. S.; Baseia, B.
2016-08-01
We study the evolution of odd compass states (specific superpositions of four coherent states), governed by the standard master equation with phase-sensitive amplifying/attenuating terms, in the presence of a Hamiltonian describing a parametric degenerate linear amplifier. Explicit expressions for the time-dependent Wigner function are obtained. The time of disappearance of the so called "sub-Planck structures" is calculated using the negative value of the Wigner function at the origin of phase space. It is shown that this value rapidly decreases during a short "conventional interference degradation time" (CIDT), which is inversely proportional to the size of quantum superposition, provided the anti-Hermitian terms in the master equation are of the same order (or stronger) as the Hermitian ones (governing the parametric amplification). The CIDT is compared with the final positivization time (FPT), when the Wigner function becomes positive. It appears that the FPT does not depend on the size of superpositions, moreover, it can be much bigger in the amplifying media than in the attenuating ones. Paradoxically, strengthening the Hamiltonian part results in decreasing the CIDT, so that the CIDT almost does not depend on the size of superpositions in the asymptotical case of very weak reservoir coupling. We also analyze the evolution of the Mandel factor, showing that for some sets of parameters this factor remains significantly negative, even when the Wigner function becomes positive.
Phase sensitivity of two nonlinear interferometers with inputting entangled coherent states
NASA Astrophysics Data System (ADS)
Wei, Chao-Ping; Xiao-Yu, Hu; Ya-Fei, Yu; Zhi-Ming, Zhang
2016-04-01
We investigate the phase sensitivity of the SU(1,1) interfereometer [SU(1,1)I] and the modified Mach-Zehnder interferometer (MMZI) with the entangled coherent states (ECS) as inputs. We consider the ideal case and the situations in which the photon losses are taken into account. We find that, under ideal conditions, the phase sensitivity of both the MMZI and the SU(1,1)I can beat the shot-noise limit (SNL) and approach the Heisenberg limit (HL). In the presence of photon losses, the ECS can beat the coherent and squeezed states as inputs in the SU(1,1)I, and the MMZI is more robust against internal photon losses than the SU(1,1)I. Project supported by the Major Research Plan of the National Natural Science Foundation of China (Grant No. 91121023), the National Natural Science Foundation of China (Grant Nos. 11574092, 61378012, and 60978009), the Specialized Research Fund for the Doctoral Program of Higher Education of China (Grant No. 20124407110009), the National Basic Research Program of China (Grant Nos. 2011CBA00200 and 2013CB921804), and the Program for Innovative Research Team in University (Grant No. IRT1243).
Bona fide interaction-driven topological phase transition in correlated SPT states
NASA Astrophysics Data System (ADS)
Meng, Zi Yang; He, Yuan-Yao; Wu, Han-Qing; You, Yi-Zhuang; Xu, Cenke; Lu, Zhong-Yi
It is expected the interplay between non-trivial band topology and strong electron correlation will lead to very rich physics. Thus a controlled study of the competition between topology and correlation is of great interest. Here, employing large-scale quantum Monte Carlo simulations, we provide a concrete example of the Kane-Mele-Hubbard model on an AA stacking bilayer honeycomb lattice with inter-layer antiferromagnetic interaction. Our simulation identified several different phases: a quantum spin-Hall insulator (QSH), a xy-plane antiferromagnetic Mott insulator (xy-AFM) and an inter-layer dimer-singlet insulator (dimer-singlet). Most importantly, a bona fide topological phase transition between the QSH and the dimer-singlet insulators, purely driven by the inter-layer antiferromagnetic interaction is found. At the transition, the spin and charge gap of the system close while the single-particle excitations remain gapped, which means that this transition has no mean field analogue and it can be viewed as a transition between bosonic SPT states. At one special point, this transition is described by a (2+1)d O(4) nonlinear sigma model with exact SO(4) symmetry, and a topological term at theta=p. Relevance of this work towards more general interacting SPT states is discussed.
NASA Astrophysics Data System (ADS)
He, Yuan-Yao; Wu, Han-Qing; You, Yi-Zhuang; Xu, Cenke; Meng, Zi Yang; Lu, Zhong-Yi
2016-03-01
It is expected that the interplay between nontrivial band topology and strong electron correlation will lead to very rich physics. Thus a controlled study of the competition between topology and correlation is of great interest. Here, employing large-scale quantum Monte Carlo simulations, we provide a concrete example of the Kane-Mele-Hubbard model on an AA-stacking bilayer honeycomb lattice with interlayer antiferromagnetic interaction. Our simulation identified several different phases: a quantum spin Hall insulator (QSH), an x y -plane antiferromagnetic Mott insulator, and an interlayer dimer-singlet insulator. Most importantly, a bona fide topological phase transition between the QSH and the dimer-singlet insulators, purely driven by the interlayer antiferromagnetic interaction, is found. At the transition, the spin and charge gap of the system close while the single-particle excitations remain gapped, which means that this transition has no mean-field analog and it can be viewed as a transition between bosonic symmetry-protected topological (SPT) states. At one special point, this transition is described by a (2 +1 )d O (4 ) nonlinear sigma model with exact S O (4 ) symmetry and a topological term at exactly Θ =π . The relevance of this work towards more general interacting SPT states is discussed.
Pressure-induced continuous phase transition of charge-density-wave state in a linear-chain complex
NASA Astrophysics Data System (ADS)
Kuroda, Noritaka; Sakai, Masamichi; Nishina, Yuichiro; Sasaki, Kazuo
1992-05-01
[Pt(en)2][Pt(en)2Cl2](ClO4)4 (en=ethylenediamine) is found to undergo a novel phase transition from the charge-density-wave (CDW) state to a new phase under hydrostatic pressure. The new phase appears at 3 GPa and coexists with the CDW state up to 6 GPa, at least. The volume ratio between the two coexisting phases measured by Raman scattering spectroscopy changes continuously with pressure. The result is discussed in terms of the theoretical approach to the polymorphic phase transition developed recently by Bassler, Sasaki, and Griffiths. It is suggested that kink solitons play an important role in this phase transition.
NASA Astrophysics Data System (ADS)
Devreese, Jeroen P. A.; Tempere, Jacques
2014-01-01
In ultracold Fermi gases, the effect of spin imbalance on superfluidity has been the subject of intense study. One of the reasons for this is that spin imbalance frustrates the Bardeen-Cooper-Schrieffer (BCS) superfluid pairing mechanism, in which fermions in different spin states combine into Cooper pairs with zero momentum. In 1964, it was proposed that an exotic superfluid state called the Fulde-Ferrell-Larkin-Ovchinnikov (FFLO) state, in which the Cooper pairs have nonzero momentum, could exist in a spin-imbalanced Fermi gas. At the saddle-point (mean-field) level, it has been shown that the FFLO state only occupies a very small sliver in the ground-state phase diagram of a three-dimensional (3D) Fermi gas. However, a question that remains to be investigated is as follows: What is the influence of phase fluctuations on the FFLO state? In this work, we show that phase fluctuations only lead to relatively small quantitative corrections to the presence of the FFLO state in the saddle-point phase diagram of a 3D spin-imbalanced Fermi gas. Starting from the partition function of the system, we calculate the effective action within the path-integral adiabatic approximation. The action is then expanded up to second order in the fluctuation field around the saddle point, leading to the fluctuation free energy. Using this free energy, we calculate corrections due to phase fluctuations to the BCS-FFLO transition in the saddle-point phase diagram. At temperatures at which the FFLO state exists, we find only small corrections to the size of the FFLO area. Our results suggest that fluctuations of the phase of the FFLO order parameter, which can be interpreted as an oscillation of its momentum vector, do not cause an instability of the FFLO state with respect to the BCS state.
NASA Astrophysics Data System (ADS)
Meyer, Jessica; Krämer, Martina; Afchine, Armin; Gallagher, Martin; Dorsey, James; Brown, Phil; Woolley, Alan; Bierwirth, Eike; Ehrlich, Andre; Wendisch, Manfred; Gehrmann, Martin
2013-04-01
The influence of mixed-phase clouds on the radiation budget of the earth is largely unknown. One of the key parameters to determine mixed-phase cloud radiative properties however is the fraction of ice particles and liquid droplets in these clouds. The separate detection of liquid droplets and ice crystals especially in the small cloud particle size range below 50 µm remains challenging though. Here, we present airborne NIXE-CAPS mixed-phase cloud particle measurements observed in mid-latitude and Arctic low-level mixed-phase clouds during the COALESC field campaign in 2011 and the Arctic field campaign VERDI in 2012. NIXE-CAPS (Novel Ice EXpEriment - Cloud and Aerosol Particle Spectrometer, manufactured by DMT) is a cloud particle spectrometer which measures the cloud particle number, size as well as their phase for each cloud particle in the diameter range 0.6 to 945 µm. The common understanding in mixed-phase cloud research is that liquid droplets and ice crystals in the same cloud volume are rather sparse, but instead either liquid droplets or ice crystals are present. However, recently published model studies (e.g. Korolev, A. & Field, P., The effect of dynamics on mixed-phase clouds: Theoretical considerations. J. Atmos. Sci. 65, 66-86, 2008) indicate that a cloud state containing both liquid droplets and ice crystals can be kept up by turbulence. Indeed, our particle by particle analyses of the observed mixed-phase clouds during COALESC and VERDI indicate that the real mixed-phase state is rather common in the atmosphere. The spatial distribution of the mixed-phase ice fraction and the size of the droplets and ice crystals however vary substantially from case to case. The latter parameters seem to be influenced not only by concentration of ice nuclei but also - to a large degree - by cloud dynamics.
Properties of meso-Erythritol; phase state, accommodation coefficient and saturation vapour pressure
NASA Astrophysics Data System (ADS)
Emanuelsson, Eva; Tschiskale, Morten; Bilde, Merete
2016-04-01
Introduction Saturation vapour pressure and the associated temperature dependence (enthalpy ΔH), are key parameters for improving predictive atmospheric models. Generally, the atmospheric aerosol community lack experimentally determined values of these properties for relevant organic aerosol compounds (Bilde et al., 2015). In this work we have studied the organic aerosol component meso-Erythritol. Methods Sub-micron airborne particles of meso-Erythritol were generated by nebulization from aqueous solution, dried, and a mono disperse fraction of the aerosol was selected using a differential mobility analyser. The particles were then allowed to evaporate in the ARAGORN (AaRhus Atmospheric Gas phase OR Nano particle) flow tube. It is a temperature controlled 3.5 m long stainless steel tube with an internal diameter of 0.026 m (Bilde et al., 2003, Zardini et al., 2010). Changes in particle size as function of evaporation time were determined using a scanning mobility particle sizer system. Physical properties like air flow, temperature, humidity and pressure were controlled and monitored on several places in the setup. The saturation vapour pressures were then inferred from the experimental results in the MATLAB® program AU_VaPCaP (Aarhus University_Vapour Pressure Calculation Program). Results Following evaporation, meso-Erythriol under some conditions showed a bimodal particle size distribution indicating the formation of particles of two different phase states. The issue of physical phase state, along with critical assumptions e.g. the accommodation coefficient in the calculations of saturation vapour pressures of atmospheric relevant compounds, will be discussed. Saturation vapour pressures from the organic compound meso-Erythritol will be presented at temperatures between 278 and 308 K, and results will be discussed in the context of atmospheric chemistry. References Bilde, M. et al., (2015), Chemical Reviews, 115 (10), 4115-4156. Bilde, M. et. al., (2003
Mechanically stretchable and tunable metamaterial absorber
NASA Astrophysics Data System (ADS)
Zhang, Fuli; Feng, Shuqi; Qiu, Kepeng; Liu, Zijun; Fan, Yuancheng; Zhang, Weihong; Zhao, Qian; Zhou, Ji
2015-03-01
In this letter, we present experimental demonstration of a mechanically stretchable and tunable metamaterial absorber composed of dielectric resonator stacked on a thin conductive rubber layer. A near unity absorption is observed due to strong local field confinement around magnetic Mie resonance of dielectric resonator. Furthermore, the interspacing between unit cells is modulated dynamically under uniaxial stress. Owing to the decreases of longitudinal coupling between neighboring unit cells, the resonant absorption peak is reversibly tuned by 410 MHz, as the stain varies up to 180% along H field direction. On the contrary, the resonant absorption state is nearly independent on strain variation when external stress is applied along E field direction, due to the weak transverse interplaying. The mechanically tunable metamaterial absorber featured by flexibility paves a way forwards for actual application.
ERIC Educational Resources Information Center
Berkey, Arthur L.; And Others
Phase 1 of a two-phase study on employment demand in Agriculture/Agribusiness for New York State focused on data collection. Four objectives were to (1) compile a preliminary listing of current occupations by industry emphasizing grade levels, (2) review cross-coding systems for employment demand data, (3) develop a preliminary system for periodic…
ERIC Educational Resources Information Center
Nicolaides, Cleanthes A.; Constantoudis, Vasilios
2009-01-01
In Planck's model of the harmonic oscillator (HO) a century ago, both the energy and the phase space were quantized according to epsilon[subscript n] = nhv, n = 0, 1, 2..., and [double integral]dp[subscript x] dx = h. By referring to just these two relations, we show how the adoption of "cycle-averaged phase-space states" (CAPSSs) leads to the…
Naikaew, Atittaya; Prajongtat, Pongthep; Lux-Steiner, Martha Ch.; Dittrich, Thomas; Arunchaiya, Marisa
2015-06-08
Modulated surface photovoltage (SPV) spectra have been correlated with the phase composition in layers of CH{sub 3}NH{sub 3}PbI{sub 3} (MAPbI{sub 3}) prepared from MAI and PbCl{sub 2} and annealed at 100 °C. Depending on the annealing time, different compositions of MAPbI{sub 3}, MAPbCl{sub 3}, MACl, PbI{sub 2}, and an un-identified phase were found. It has been demonstrated that evaporation of MAI and HI is crucial for the development of electronic states in MAPbI{sub 3} and that only the appearance and evolution of the phase PbI{sub 2} has an influence on electronic states in MAPbI{sub 3}. With ongoing annealing, (i) a transition from p- to n-type doping was observed with the appearance of PbI{sub 2}, (ii) shallow acceptor states were distinguished and disappeared in n-type doped MAPbI{sub 3}, and (iii) a minimum of the SPV response related to deep defect states was found at the transition from p- to n-type doping. The results are discussed with respect to the further development of highly efficient and stable MAPbI{sub 3} absorbers for solar cells.
The equation of state of the Pmmn phase of NiSi
Lord, Oliver T.; Thomson, Andrew R.; Wann, Elizabeth T. H.; Wood, Ian G.; Dobson, David P.; Vocadlo, Lidunka
2015-01-01
The equation of state of the orthorhombic phase of NiSi with Pmmn symmetry has been determined at room temperature from synchrotron-based X-ray diffraction measurements of its lattice parameters, made in a diamond anvil cell. Measurements were performed up to 44 GPa, using Ne as the pressure medium and Au as the pressure standard. The resulting pressure–volume (P–V) data have been fitted with a Birch–Murnaghan equation of state of third order to yield V 0 = 11.650 (7) Å3 atom−1, K 0 = 162 (3) GPa and K 0′ = 4.6 (2). In addition, P–V data have been collected on Ni53Si47 in the B20 structure using both Ne and He as the pressure media and Cu and Au as the pressure standards, also to 44 GPa. A fit using the same Birch–Murnaghan equation of state of third order yields V 0 = 11.364 (6) Å3 atom−1, K 0 = 171 (4) GPa and K 0′ = 5.5 (3). PMID:26664346
Phase conjugation by wave-mixing interactions in solid-state laser gain media
NASA Astrophysics Data System (ADS)
Brignon, A.
The heat load deposited in solid-state laser medium leads to thermally induced aberrations. This undesirable effect causes wavefront distorsions and reduces the brightness of lasers. Phase-distorsion correction of an optical wave propagating in laser media is thus a crucial problem that must be taken into account in solid-state laser sources. Indeed, many applications require a high-spatial-quality, diffraction-limited output beam. An approach offering great potential to solve this problem involves nonlinear optical phase conjugation. Phase conjugation can be obtained with degenerate wave mixing in the laser medium itself by gain saturation. The use of solid-state laser amplifiers for such operation presents very attractive features including the automatic matching of the nonlinearity with the laser wavelength, a fast response time and a high efficiency of the nonlinear process due to the laser amplification of all interacting beams. In as much as gain saturation is inherent in all tenporal regimes, phase conjugation in inverted media can be performed in both pulsed and cw regimes. This nonlinear mechanism is theoretically analyzed and experimentally demonstrated in flash-lamp pumped Nd:YAG amplifiers and in a compact diode-pumped Nd:YVO4 amplifier in the nanosecond pulsed regime. Efficient continuous wave operation is also demonstrated in a Nd:YVO4 amplifier pumped by a cw Ti:sapphire laser. Applications to dynamic holography and correction of aberrated wavefronts propagating in laser media are presented. Finally, it is shown that saturable gain media can be used as efficient phase conjugate mirrors for all-solid-state high beam quality laser sources. Les lasers solides présentent des avantages relatifs à leur compacité, facilité d'utilisation et à leur durée de vie. Cependant, une partie importante de l'énergie de pompage se dissipe sous forme de chaleur provocant des distorsions de phase importantes dans le milieu laser. Cet effet indésirable dégrade la
Space Evaporator Absorber Radiator (SEAR) for Thermal Storage on Manned Spacecraft
NASA Technical Reports Server (NTRS)
Izenson, Michael G.; Chen, Weibo; Chepko, Ariane; Bue, Grant; Quinn, Gregory
2015-01-01
Future manned exploration spacecraft will need to operate in challenging thermal environments. State-of-the-art technology for active thermal control relies on sublimating water ice and venting the vapor overboard in very hot environments, and or heavy phase change material heat exchangers for thermal storage. These approaches can lead to large loss of water and a significant mass penalties for the spacecraft. This paper describes an innovative thermal control system that uses a Space Evaporator Absorber Radiator (SEAR) to control spacecraft temperatures in highly variable environments without venting water. SEAR uses heat pumping and energy storage by LiCl/water absorption to enable effective cooling during hot periods and regeneration during cool periods. The LiCl absorber technology has the potential to absorb over 800 kJ per kg of system mass, compared to phase change heat sink systems that typically achieve approx. 50 kJ/kg. This paper describes analysis models to predict performance and optimize the size of the SEAR system, estimated size and mass of key components, and an assessment of potential mass savings compared with alternative thermal management approaches. We also describe a concept design for an ISS test package to demonstrate operation of a subscale system in zero gravity.
The Warm Absorber of the Seyfert Galaxy NGC 5548
NASA Astrophysics Data System (ADS)
Andrade, M.; Krongold, Y.; Elvis, M.; Nicastro, F.; Binette, L.; Brickhouse, N.
2008-04-01
We present a spectral analysis of the X-ray Chandraof the Seyfert 1 Galaxy NGC 5548. The warm absorber present in this object was modeled with the code PHASE. We detected two different outflow velocity systems in this source. One of the absorbing systems has outflow velocity of -1091+/-63 km s(-1) and the other of -568+/-49 km s(-1) . Each system required two absorption components with different ionization level to fit the observed features. Each velocity system may consist of a multi-phase medium.
Bina, Matteo; Allevi, Alessia; Bondani, Maria; Olivares, Stefano
2016-01-01
Phase estimation represents a crucial challenge in many fields of Physics, ranging from Quantum Metrology to Quantum Information Processing. This task is usually pursued by means of interferometric schemes, in which the choice of the input states and of the detection apparatus is aimed at minimizing the uncertainty in the estimation of the relative phase between the inputs. State discrimination protocols in communication channels with coherent states also require the monitoring of the optical phase. Therefore, the problem of phase estimation is relevant to face the issue of coherent states discrimination. Here we consider a quasi-optimal Kennedy-like receiver, based on the interference of two coherent signals, to be discriminated, with a reference local oscillator. By means of the Bayesian processing of a small amount of data drawn from the outputs of the shot-by-shot discrimination protocol, we demonstrate the achievement of the minimum uncertainty in phase estimation, also in the presence of uniform phase noise. Moreover, we show that the use of photon-number resolving detectors in the receiver improves the phase-estimation strategy, especially with respect to the usually employed on/off detectors. From the experimental point of view, this comparison is realized by employing hybrid photodetectors. PMID:27189140
Bina, Matteo; Allevi, Alessia; Bondani, Maria; Olivares, Stefano
2016-01-01
Phase estimation represents a crucial challenge in many fields of Physics, ranging from Quantum Metrology to Quantum Information Processing. This task is usually pursued by means of interferometric schemes, in which the choice of the input states and of the detection apparatus is aimed at minimizing the uncertainty in the estimation of the relative phase between the inputs. State discrimination protocols in communication channels with coherent states also require the monitoring of the optical phase. Therefore, the problem of phase estimation is relevant to face the issue of coherent states discrimination. Here we consider a quasi-optimal Kennedy-like receiver, based on the interference of two coherent signals, to be discriminated, with a reference local oscillator. By means of the Bayesian processing of a small amount of data drawn from the outputs of the shot-by-shot discrimination protocol, we demonstrate the achievement of the minimum uncertainty in phase estimation, also in the presence of uniform phase noise. Moreover, we show that the use of photon-number resolving detectors in the receiver improves the phase-estimation strategy, especially with respect to the usually employed on/off detectors. From the experimental point of view, this comparison is realized by employing hybrid photodetectors. PMID:27189140
Mushroom plasmonic metamaterial infrared absorbers
NASA Astrophysics Data System (ADS)
Ogawa, Shinpei; Fujisawa, Daisuke; Hata, Hisatoshi; Uetsuki, Mitsuharu; Misaki, Koji; Kimata, Masafumi
2015-01-01
There has been a considerable amount of interest in the development of various types of electromagnetic wave absorbers for use in different wavelength ranges. In particular, infrared (IR) absorbers with wavelength selectivity can be applied to advanced uncooled IR sensors, which would be capable of identifying objects through their radiation spectrum. In the present study, mushroom plasmonic metamaterial absorbers (MPMAs) for the IR wavelength region were designed and fabricated. The MPMAs consist of a periodic array of thin metal micropatches connected to a thin metal plate with narrow silicon (Si) posts. A Si post height of 200 nm was achieved by isotropic XeF2 etching of a thin Si layer sandwiched between metal plates. This fabrication procedure is relatively simple and is consistent with complementary metal oxide semiconductor technology. The absorption spectra of the fabricated MPMAs were experimentally measured. In addition, theoretical calculations of their absorption properties were conducted using rigorous coupled wave analysis. Both the calculated and measured absorbance results demonstrated that these MPMAs can realize strong selective absorption at wavelengths beyond the period of the array by varying the micropatch width. Absorbance values greater than 90% were achieved. Dual- or single-mode absorption can also be selected by varying the width of the Si posts. Pixel structures using such MPMAs could be used as high responsivity, high resolution and fast uncooled IR sensors.
Additive manufacturing of RF absorbers
NASA Astrophysics Data System (ADS)
Mills, Matthew S.
The ability of additive manufacturing techniques to fabricate integrated electromagnetic absorbers tuned for specific radio frequency bands within structural composites allows for unique combinations of mechanical and electromagnetic properties. These composites and films can be used for RF shielding of sensitive electromagnetic components through in-plane and out-of-plane RF absorption. Structural composites are a common building block of many commercial platforms. These platforms may be placed in situations in which there is a need for embedded RF absorbing properties along with structural properties. Instead of adding radar absorbing treatments to the external surface of existing structures, which adds increased size, weight and cost; it could prove to be advantageous to integrate the microwave absorbing properties directly into the composite during the fabrication process. In this thesis, a method based on additive manufacturing techniques of composites structures with prescribed electromagnetic loss, within the frequency range 1 to 26GHz, is presented. This method utilizes screen printing and nScrypt micro dispensing to pattern a carbon based ink onto low loss substrates. The materials chosen for this study will be presented, and the fabrication technique that these materials went through to create RF absorbing structures will be described. The calibration methods used, the modeling of the RF structures, and the applications in which this technology can be utilized will also be presented.
Mushroom plasmonic metamaterial infrared absorbers
Ogawa, Shinpei Fujisawa, Daisuke; Hata, Hisatoshi; Uetsuki, Mitsuharu; Misaki, Koji; Kimata, Masafumi
2015-01-26
There has been a considerable amount of interest in the development of various types of electromagnetic wave absorbers for use in different wavelength ranges. In particular, infrared (IR) absorbers with wavelength selectivity can be applied to advanced uncooled IR sensors, which would be capable of identifying objects through their radiation spectrum. In the present study, mushroom plasmonic metamaterial absorbers (MPMAs) for the IR wavelength region were designed and fabricated. The MPMAs consist of a periodic array of thin metal micropatches connected to a thin metal plate with narrow silicon (Si) posts. A Si post height of 200 nm was achieved by isotropic XeF{sub 2} etching of a thin Si layer sandwiched between metal plates. This fabrication procedure is relatively simple and is consistent with complementary metal oxide semiconductor technology. The absorption spectra of the fabricated MPMAs were experimentally measured. In addition, theoretical calculations of their absorption properties were conducted using rigorous coupled wave analysis. Both the calculated and measured absorbance results demonstrated that these MPMAs can realize strong selective absorption at wavelengths beyond the period of the array by varying the micropatch width. Absorbance values greater than 90% were achieved. Dual- or single-mode absorption can also be selected by varying the width of the Si posts. Pixel structures using such MPMAs could be used as high responsivity, high resolution and fast uncooled IR sensors.
Nonventing, Regenerable, Lightweight Heat Absorber
NASA Technical Reports Server (NTRS)
Izenson, Michael G.; Chen, Weibo
2008-01-01
A lightweight, regenerable heat absorber (RHA), developed for rejecting metabolic heat from a space suit, may also be useful on Earth for short-term cooling of heavy protective garments. Unlike prior space-suit-cooling systems, a system that includes this RHA does not vent water. The closed system contains water reservoirs, tubes through which water is circulated to absorb heat, an evaporator, and an absorber/radiator. The radiator includes a solution of LiCl contained in a porous material in titanium tubes. The evaporator cools water that circulates through a liquid-cooled garment. Water vapor produced in the evaporator enters the radiator tubes where it is absorbed into the LiCl solution, releasing heat. Much of the heat of absorption is rejected to the environment via the radiator. After use, the RHA is regenerated by heating it to a temperature of 100 C for about 2 hours to drive the absorbed water back to the evaporator. A system including a prototype of the RHA was found to be capable of maintaining a temperature of 20 C while removing heat at a rate of 200 W for 6 hours.
Density of states at disorder-induced phase transitions in a multichannel Majorana wire
NASA Astrophysics Data System (ADS)
Rieder, Maria-Theresa; Brouwer, Piet W.
2014-11-01
An N -channel spinless p -wave superconducting wire is known to go through a series of N topological phase transitions upon increasing the disorder strength. Here, we show that at each of those transitions the density of states shows a Dyson singularity ν (ɛ ) ∝ɛ-1|lnɛ| -3 , whereas ν (ɛ ) ∝ɛ|α |-1 has a power-law singularity for small energies ɛ away from the critical points. Using the concept of "superuniversality" [Gruzberg et al., Phys. Rev. B 71, 245124 (2005), 10.1103/PhysRevB.71.245124], we are able to relate the exponent α to the wire's transport properties at zero energy and, hence, to the mean free path l and the superconducting coherence length ξ .
GAS-PHASE ELECTRONIC SPECTRA OF POLYACETYLENE CATIONS: RELEVANCE OF HIGHER EXCITED STATES
Rice, C. A.; Rudnev, V.; Dietsche, R.; Maier, J. P.
2010-07-15
Transitions to higher electronic states of polyacetylene cations (HC{sub 2n}H{sup +}, n = 4, 5, 6) have been measured in the gas phase at {approx}20 K. The absorption spectra were obtained using a resonant two-color, two-photon fragmentation technique in an ion trap, allowing a direct comparison between laboratory and astrophysical data. The purpose was to investigate the relevance of such transitions to astronomical observations because the general expectation is that the bands could be too broad due to fast intramolecular processes. It is shown that the origin bands are still narrow enough (1-10 cm{sup -1}) to be considered, especially as the higher-lying transitions often possess large oscillator strengths.
Clarke, Patrick J.; Collins, Robert J.; Dunjko, Vedran; Andersson, Erika; Jeffers, John; Buller, Gerald S.
2012-01-01
Digital signatures are frequently used in data transfer to prevent impersonation, repudiation and message tampering. Currently used classical digital signature schemes rely on public key encryption techniques, where the complexity of so-called ‘one-way' mathematical functions is used to provide security over sufficiently long timescales. No mathematical proofs are known for the long-term security of such techniques. Quantum digital signatures offer a means of sending a message, which cannot be forged or repudiated, with security verified by information-theoretical limits and quantum mechanics. Here we demonstrate an experimental system, which distributes quantum signatures from one sender to two receivers and enables message sending ensured against forging and repudiation. Additionally, we analyse the security of the system in some typical scenarios. Our system is based on the interference of phase-encoded coherent states of light and our implementation utilizes polarization-maintaining optical fibre and photons with a wavelength of 850 nm. PMID:23132024
Structure-phase states evolution in rails during a long operation
Peregudov, Oleg Gromov, Victor Morozov, Konstantin Alsaraeva, Krestina Semina, Olga; Ivanov, Yurii
2015-10-27
By methods of scanning and transmission electron microscopy the transformation regularities of structure-phase states, defect substructure, fracture surface of rail surface layer up to 10 mm deep in process of long-term operation (passed tonnage of gross weight 1000 mln tons) were revealed. It has been shown that the surface layer ∼20 μm in thickness has a multiphase, submicro- and nanocrystalline structure and it contains micropores and microcracks. The increased density of bend extinction contours at 2 mm depth from the tread contact surface was noted. The analysis of structure morphological constituents and internal stress fields, created by intra- and interphase boundaries after long operation was carried out. It was shown that the maximum amplitude of stress fields was formed on the interphase boundary the globular cementite particle–matrix. The evaluation of stress fields was done.
Carbonyl Diisocyanate CO(NCO)2: Synthesis and Structures in Solid State and Gas Phase.
Klapötke, Thomas M; Krumm, Burkhard; Rest, Sebastian; Scharf, Regina; Schwabedissen, Jan; Stammler, Hans-Georg; Mitzel, Norbert W
2016-07-01
A modified synthesis for carbonyl diisocyanate, CO(NCO)2, starting from trichloroisocyanuric acid and diphosgene is described. In addition to the previously reported (13)C NMR resonances, the (15)N NMR shift is determined for the first time. The structure in the solid state was determined by X-ray diffraction (XRD) on in situ grown crystals, that in the gas phase was experimentally determined by electron diffraction (GED) and for single molecules theoretically by quantum-chemical calculations. The structures are compared and discussed with related systems. Quantum-chemical calculations as well as GED and XRD prove syn-syn to be the conformation of lowest energy. In quantum-chemical calculations and GED the presence of a syn-anti conformer was confirmed and the structure of this conformer was determined.
Two paramagnetic iron states at the Verwey phase transition in magnetite
NASA Astrophysics Data System (ADS)
Stankowski, J.; Kempiński, W.; Łoś, S.; Bednarski, W.; Waplak, S.; Micnas, R.
2006-06-01
At the Verwey phase transition (VPT) region a wide line of the ferromagnetic resonance (FMR) and a narrow EPR spectrum were observed. The EPR line at 125 K occurred and then disappeared below 85 K. This unexpected phenomenon is observed only if iron charge state transformation is present. Simulation of both FMR as well as EPR spectra has indicated the presence of two different iron clusters in the Fe 3O 4 structure. Best fit of both spectra yielded g=2.4 and 4.1 for FMR, and g=2.8 and 3.4 for EPR. The presence of two-component (EPR, FMR) spectra at about T is due to a frustration of charge distribution in the B-sublattice as a result of the orthorhombic Pmca pseudosymmetry constraints on the atomic positions in monoclinic symmetry cell P2/c. The paramagnetic (EPR) center observed is an admixtured Fe 2+ state in antiferromagnetically ordered A-sublattice ferromagnetically coupled with the B-lattice. Two paramagnetic defects observed (EPR) of localized spin states are evoked by two valency states of Fe 2.4 and Fe 2.6 below T. They can originate from two types of Fe 4O 4 cubes: "electron-rich" and" electron-poor" at a ratio 3:1 [J.P. Wright, J.P. Attfield, P.G. Radaelli, Phys. Rev. Lett. 87 (2001) 266401; Phys. Rev. B 66 (2002) 214422] or from two types of bond dimerization (H. Seo, M. Ogata, H. Fukuyama, Phys. Rev. B65 (2002) 85107).
Synthesis and equation of state of high pressure phase of chromium-bearing spinel
NASA Astrophysics Data System (ADS)
Shieh, S. R.; Khan, T.; Prescher, C.; Prakapenka, V.; MI, Z.
2015-12-01
Chromium-bearing spinel (Mg,Fe)Cr2O4 can be found in the Earth's crust, upper mantle, and even in meteorites. Mantle derived chromium-bearing spinel suggests that its high pressure phase may be existing at deep mantle but however its high pressure elastic property is not well understood yet. In situ synchrotron X-ray diffraction studies of magnesiochromite and chromite using the laser-heated diamond anvil cell were performed at GSECARS, Advanced Photon Source, to explore their high pressure phases and elastic property. Our results on magnesiochromite showed dissociation of MgCr2O4 to Cr2O3+MgO at ~15 GPa and to modified Ludwigite (mLd)-type Mg2Cr2O5+Cr2O3 below and above ~1500 K, respectively. At above 20 GPa, only a single phase CaTi2O4-type structure of MgCr2O4 was observed at 1400-2000 K. Pressure-volume data of CaTi2O4 type structure of MgCr2O4 fitted to Birch-Murnaghan equation of state yield zero-pressure volume (V0) = 264.4(8) Å3, bulk modulus (K0) = 185.4(4) GPa, and pressure derivative (K0') = 4; and mLd-type Mg2Cr2O5 yields: V0 = 338.9(8) Å3, K0 = 186.5(6) GPa, K0' = 4. For CaTi2O4 type structure of natural chromite, our fitted P-V data show V0 = 261(1) Å3, K0 = 175.4(2) GPa, and K0' = 4.
Stroke phases responses around maximal lactate steady state in front crawl.
Pelarigo, Jailton G; Denadai, Benedito S; Greco, Camila C
2011-03-01
The objective of this study was to analyze changes in stroke rate (SR), stroke length (SL) and stroke phases (entry and catch, pull, push and recovery) when swimming at (MLSS) and above (102.5% MLSS) the maximal lactate steady state. Twelve endurance swimmers (21±8 year, 1.77±0.10 m and 71.6±7.7 kg) performed in different days the following tests: (1) 200- and 400-m all-out tests, to determine critical speed (CS), and; (2) 2-4 30-min sub-maximal constant-speed tests, to determine the MLSS and 102.5% MLSS. There was significant difference among MLSS (1.22±0.05 ms(-1)), 102.5% MLSS (1.25±0.04 ms(-1)) and CS (1.30±0.08 ms(-1)). SR and SL were maintained between the 10th and 30th minute of the test swum at MLSS and have modified significantly at 102.5% MLSS (SR - 30.9±3.4 and 32.2±3.5 cycles min(-1) and SL - 2.47±0.2 and 2.38±0.2 m cycle(-1), respectively). All stroke phases were maintained at 10th and 30th minute at MLSS. However, the relative duration of propulsive phase B (pull) increased significantly at 102.5% MLSS (21.7±3.4% and 22.9±3.9%, respectively). Therefore, the metabolic condition may influence the stroke parameters (SR and SL) and stroke strategy to maintain the speed during swim tests lasting 30 min.
Pathways through equilibrated states with coexisting phases for gas hydrate formation
Malolepsza, Edyta; Keyes, Tom
2015-12-01
Under ambient conditions, water freezes to either hexagonal ice or a hexagonal/cubic composite ice. The presence of hydrophobic guest molecules introduces a competing pathway: gas hydrate formation, with the guests in clathrate cages. Here, the pathways of the phase transitions are sought as sequences of states with coexisting phases, using a generalized replica exchange algorithm designed to sample them in equilibrium, avoiding nonequilibrium processes. For a dilute solution of methane in water under 200 atm, initializing the simulation with the full set of replicas leads to methane trapped in hexagonal/cubic ice, while gradually adding replicas with decreasing enthalpy produces themore » initial steps of hydrate growth. Once a small amount of hydrate is formed, water rearranges to form empty cages, eventually transforming the remainder of the system to metastable β ice, a scaffolding for hydrates. It is suggested that configurations with empty cages are reaction intermediates in hydrate formation when more guest molecules are available. Furthermore, free energy profiles show that methane acts as a catalyst reducing the barrier for β ice versus hexagonal/cubic ice formation.« less
Pathways through equilibrated states with coexisting phases for gas hydrate formation
Malolepsza, Edyta; Keyes, Tom
2015-12-01
Under ambient conditions, water freezes to either hexagonal ice or a hexagonal/cubic composite ice. The presence of hydrophobic guest molecules introduces a competing pathway: gas hydrate formation, with the guests in clathrate cages. Here, the pathways of the phase transitions are sought as sequences of states with coexisting phases, using a generalized replica exchange algorithm designed to sample them in equilibrium, avoiding nonequilibrium processes. For a dilute solution of methane in water under 200 atm, initializing the simulation with the full set of replicas leads to methane trapped in hexagonal/cubic ice, while gradually adding replicas with decreasing enthalpy produces the initial steps of hydrate growth. Once a small amount of hydrate is formed, water rearranges to form empty cages, eventually transforming the remainder of the system to metastable β ice, a scaffolding for hydrates. It is suggested that configurations with empty cages are reaction intermediates in hydrate formation when more guest molecules are available. Furthermore, free energy profiles show that methane acts as a catalyst reducing the barrier for β ice versus hexagonal/cubic ice formation.
SESAME 96171, a three-phase equation of state for CeO_{2}
Chisolm, Eric D.
2014-07-08
This report describes an earlier version of an equation of state (EOS) for cerium (IV) oxide, CeO_{2}. This work has been superseded by a newer version that is described in LA-UR-14-24689. Everything from this report needed to understand the new version is included in the new report. I have constructed SESAME 96171, an EOS for cerium (IV) oxide that includes two solid phases and the liquid. Unlike its immediate predecessor, this EOS is valid over a larger range in pressure due to including the extra phase. I have described the process of constructing and testing the EOS, emphasizing its continuity with the previous EOS and the modifications needed for the new frame-work. The comparison with data is good, but is still limited by the same issues with nuclear models that were present in the previous work. The remaining significant issue is the comparison of the crystal-density EOS with experimental porous Hugoniot data, which may require using more sophisticated model to represent porosity, as discussed in the previous report.
Cardiorespiratory Phase Synchronization in OSA subjects during wake and sleep states.
Sola-Soler, Jordi; Giraldo, Beatriz F; Fiz, Jose A; Jane, Raimon
2015-08-01
Cardiorespiratory Phase Synchronization (CRPS) is a manifestation of coupling between cardiac and respiratory systems complementary to Respiratory Sinus Arrhythmia. In this work, we investigated CRPS during wake and sleep stages in Polysomnographic (PSG) recordings of 30 subjects suspected from Obstructive Sleep Apnea (OSA). The population was classified into three severity groups according to the Apnea Hypopnea Index (AHI): G1 (AHI<;15), G2 (15<;=AHI<;30) and G3 (AHI>30). The synchrogram between single lead ECG and respiratory abdominal band signals from PSG was computed with the Hilbert transform technique. The different phase locking ratios (PLR) m:n were monitored throughout the night. Ratio 4:1 was the most frequent and it became more dominant as OSA severity increased. CRPS was characterized by the percentage of synchronized time (%Sync) and the average duration of synchronized epochs (AvDurSync) using three different thresholds. Globally, we observed that %Sync significantly decreased and AvDurSync slightly increased with OSA severity. A high synchronization threshold enhanced these population differences. %Sync was significantly higher in NREM than in REM sleep in G2 and G3 groups. Population differences observed during sleep did not translate to the initial wake state. Reduced CRPS could be an early marker of OSA severity during sleep, but further studies are needed to determine whether CRPS is also present during wakefulness. PMID:26738078
NASA Astrophysics Data System (ADS)
Morinaga, Atsuo; Hasegawa, Yasushi
2015-07-01
The frequency shift induced by the Berry phase between two coherent superposition states with m'=-1 and m =1 was demonstrated under constant rotation of a magnetic field with frequency f for angle θ from the rotation axis. It was found that the frequency shift is v =2 f -2 f cosθ for 0 ≤θ ≤π /3 , v =-2 f cosθ for π /3 <θ <2 π /3 , and v =-2 f -2 f cosθ for 2 π /3 ≤θ ≤π in the case of the right-handed rotation. For the left-handed rotation, the frequency changes in the opposite sign. The frequency shift is zero at θ =0 ,π /2 , and π , and it jumps by 2 f in the vicinity of θ =π /3 and 2 π /3 . We confirm that the frequency shift is given by the time derivative of the Berry phase which does not depend on the sign of the g factor.
Pathways through Equilibrated States with Coexisting Phases for Gas Hydrate Formation.
Małolepsza, Edyta; Keyes, Tom
2015-12-31
Under ambient conditions, water freezes to either hexagonal ice or a hexagonal/cubic composite ice. The presence of hydrophobic guest molecules introduces a competing pathway: gas hydrate formation, with the guests in clathrate cages. Here, the pathways of the phase transitions are sought as sequences of states with coexisting phases, using a generalized replica exchange algorithm designed to sample them in equilibrium, avoiding nonequilibrium processes. For a dilute solution of methane in water under 200 atm, initializing the simulation with the full set of replicas leads to methane trapped in hexagonal/cubic ice, while gradually adding replicas with decreasing enthalpy produces the initial steps of hydrate growth. Once a small amount of hydrate is formed, water rearranges to form empty cages, eventually transforming the remainder of the system to metastable β ice, a scaffolding for hydrates. It is suggested that configurations with empty cages are reaction intermediates in hydrate formation when more guest molecules are available. Free energy profiles show that methane acts as a catalyst reducing the barrier for β ice versus hexagonal/cubic ice formation. PMID:26624929
Ye, Xiaoxin; Tse, Zion T H; Tang, Guoyi; Song, Guolin
2015-02-01
Mechanical properties and phase transition of two-phase biomedical titanium alloy strips (solid solution state Ti-6Al-4V) induced by the high-energy electropulses was studied. Results show that the materials ductility could be enhanced remarkably under EPT at most by 225% while keeping the tensile strength nearly unchanged. EPT facilitates β-Ti phase precipitation noticeably with increasing percentage and average size of the beta phase. In addition, precipitated beta phase gathers into continuous strips or even bulks through migrating from the interior grains to the inter-granular regions, which thus transforms the wormlike microstructure into the equiaxed microstructure. The mechanism for rapid phase change during EPT is put forward with increasing the nucleation rate of the α→β phase transformation and accelerating the diffusion flux of vanadium atoms in the matrix alloy under the coupling of the thermal and athermal effects of EPT. Therefore, EPT provides a highly efficient method of preparing outstanding biomedical titanium alloy with ideal comprehensive mechanical properties, which can be widely applied in the biomaterials engineering like dentistry and artificial implants.
NASA Astrophysics Data System (ADS)
Chung, Chung-Hou; Lee, Der-Hau; Chao, Sung-Po
2014-07-01
We study the quantum phases and phase transitions of the Kane-Mele Hubbard (KMH) model on a zigzag ribbon of honeycomb lattice at a finite size via the weak-coupling renormalization group (RG) approach. In the noninteracting limit, the Kane-Mele (KM) model is known to support topological edge states where electrons show helical property with orientations of the spin and momentum being locked. The effective interedge hopping terms are generated due to finite-size effect. In the presence of an on-site Coulomb (Hubbard) interaction and the interedge hoppings, special focus is put on the stability of the topological edge states (TI phase) in the KMH model against (i) the charge and spin gaped (II) phase, (ii) the charge gaped but spin gapless (IC) phase, and (iii) the spin gaped but charge gapless (CI) phase depending on the number (even/odd) of the zigzag ribbons, doping level (electron filling factor) and the ratio of the Coulomb interaction to the interedge tunneling. We discuss different phase diagrams for even and odd numbers of zigzag ribbons. We find the TI-CI, II-IC, and II-CI quantum phase transitions are of the Kosterlitz-Thouless (KT) type. By computing various correlation functions, we further analyze the nature and leading instabilities of these phases. The relevance of our results for graphene is discussed.
NASA Astrophysics Data System (ADS)
Zhang, Kai; Nusran, N. M.; Slezak, B. R.; Gurudev Dutt, M. V.
2016-05-01
While it is often thought that the geometric phase is less sensitive to fluctuations in the control fields, a very general feature of adiabatic Hamiltonians is the unavoidable dynamic phase that accompanies the geometric phase. The effect of control field noise during adiabatic geometric quantum gate operations has not been probed experimentally, especially in the canonical spin qubit system that is of interest for quantum information. We present measurement of the Berry phase and carry out adiabatic geometric phase gate in a single solid-state spin qubit associated with the nitrogen-vacancy center in diamond. We manipulate the spin qubit geometrically by careful application of microwave radiation that creates an effective rotating magnetic field, and observe the resulting Berry phase signal via spin echo interferometry. Our results show that control field noise at frequencies higher than the spin echo clock frequency causes decay of the quantum phase, and degrades the fidelity of the geometric phase gate to the classical threshold after a few (∼10) operations. This occurs inspite of the geometric nature of the state preparation, due to unavoidable dynamic contributions. We have carried out systematic analysis and numerical simulations to study the effects of the control field noise and imperfect driving waveforms on the quantum phase gate.
NASA Technical Reports Server (NTRS)
Caves, C. M.; Schumaker, B. L.
1985-01-01
A new formalism for analyzing two-photon devices, such as parametric amplifiers and phase-conjugate mirrors, is proposed in part I, focusing on the properties and the significance of the quadrature-phase amplitudes and two-mode squeezed states. Time-stationary quasi-probability noise is also detailed for the case of Gaussian noise, and uncertainty principles for the quadrature-phase amplitudes are outlined, as well as some important properties of the two-mode states. Part II establishes a mathematical foundation for the formalism, with introduction of a vector notation for compact representation of two-mode properties. Fundamental unitary operators and special quantum states are also examined with an emphasis on the two-mode squeezed states. The results are applied to a previously studied degenerate limit (epsilon = 0).
Damage tolerant light absorbing material
Lauf, Robert J.; Hamby, Jr., Clyde; Akerman, M. Alfred; Seals, Roland D.
1993-01-01
A light absorbing article comprised of a composite of carbon-bonded carbon fibers, prepared by: blending carbon fibers with a carbonizable organic powder to form a mixture; dispersing the mixture into an aqueous slurry; vacuum molding the aqueous slurry to form a green article; drying and curing the green article to form a cured article; and, carbonizing the cured article at a temperature of at least about 1000.degree. C. to form a carbon-bonded carbon fiber light absorbing composite article having a bulk density less than 1 g/cm.sup.3.
Damage tolerant light absorbing material
Lauf, R.J.; Hamby, C. Jr.; Akerman, M.A.; Seals, R.D.
1993-09-07
A light absorbing article comprised of a composite of carbon-bonded carbon fibers, is prepared by: blending carbon fibers with a carbonizable organic powder to form a mixture; dispersing the mixture into an aqueous slurry; vacuum molding the aqueous slurry to form a green article; drying and curing the green article to form a cured article; and, carbonizing the cured article at a temperature of at least about 1000 C to form a carbon-bonded carbon fiber light absorbing composite article having a bulk density less than 1 g/cm[sup 3]. 9 figures.
Waveform-Dependent Absorbing Metasurfaces
NASA Astrophysics Data System (ADS)
Wakatsuchi, Hiroki; Kim, Sanghoon; Rushton, Jeremiah J.; Sievenpiper, Daniel F.
2013-12-01
We present the first use of a waveform-dependent absorbing metasurface for high-power pulsed surface currents. The new type of nonlinear metasurface, composed of circuit elements including diodes, is capable of storing high-power pulse energy to dissipate it between pulses, while allowing propagation of small signals. Interestingly, the absorbing performance varies for high-power pulses but not for high-power continuous waves (CW’s), since the capacitors used are fully charged up. Thus, the waveform dependence enables us to distinguish various signal types (i.e., CW or pulse) even at the same frequency, which potentially creates new kinds of microwave technologies and applications.
Solving the inverse Ising problem by mean-field methods in a clustered phase space with many states.
Decelle, Aurélien; Ricci-Tersenghi, Federico
2016-07-01
In this work we explain how to properly use mean-field methods to solve the inverse Ising problem when the phase space is clustered, that is, many states are present. The clustering of the phase space can occur for many reasons, e.g., when a system undergoes a phase transition, but also when data are collected in different regimes (e.g., quiescent and spiking regimes in neural networks). Mean-field methods for the inverse Ising problem are typically used without taking into account the eventual clustered structure of the input configurations and may lead to very poor inference (e.g., in the low-temperature phase of the Curie-Weiss model). In this work we explain how to modify mean-field approaches when the phase space is clustered and we illustrate the effectiveness of our method on different clustered structures (low-temperature phases of Curie-Weiss and Hopfield models). PMID:27575082
Solving the inverse Ising problem by mean-field methods in a clustered phase space with many states
NASA Astrophysics Data System (ADS)
Decelle, Aurélien; Ricci-Tersenghi, Federico
2016-07-01
In this work we explain how to properly use mean-field methods to solve the inverse Ising problem when the phase space is clustered, that is, many states are present. The clustering of the phase space can occur for many reasons, e.g., when a system undergoes a phase transition, but also when data are collected in different regimes (e.g., quiescent and spiking regimes in neural networks). Mean-field methods for the inverse Ising problem are typically used without taking into account the eventual clustered structure of the input configurations and may lead to very poor inference (e.g., in the low-temperature phase of the Curie-Weiss model). In this work we explain how to modify mean-field approaches when the phase space is clustered and we illustrate the effectiveness of our method on different clustered structures (low-temperature phases of Curie-Weiss and Hopfield models).
Structural and Phase State of Ti-Nb Alloy at Selective Laser Melting of the Composite Powder
NASA Astrophysics Data System (ADS)
Sharkeev, Yu. P.; Eroshenko, A. Yu.; Kovalevskaya, Zh. G.; Saprykin, A. A.; Ibragimov, E. A.; Glukhov, I. A.; Khimich, M. A.; Uvarkin, P. V.; Babakova, E. V.
2016-07-01
Phase composition and microstructure of Ti-Nb alloy produced from the composite titanium and niobium powder by selective laser melting (SLM) method were studied in the present research. Ti-Nb alloy produced by SLM is a monolayer and has zones of fine-grained and medium-grained structure with homogenous elemental composition within the range of 36-38 wt.% Nb. Phase state of the alloy corresponds to the main phase of β- solid solution (grain size of 5-7 μm) and non-equilibrium martensite α″-phase (grain size of 0.1-0.7 μm). Grains of the α″-phase are localized along the boundaries of β-phase grains and have a reduced content of niobium. Microhardness of the alloy varies within the range of 4200-5500 MPa.
Dressed-state electromagnetically induced transparency for light storage in uniform-phase spin waves
NASA Astrophysics Data System (ADS)
Šibalić, N.; Kondo, J. M.; Adams, C. S.; Weatherill, K. J.
2016-09-01
We present, experimentally and theoretically, a scheme for dressed-state electromagnetically induced transparency (EIT) in a three-step cascade system in which a four-level system is mapped into an effective three-level system. Theoretical analysis reveals that the scheme provides coherent-state control via adiabatic following and a generalized protocol for light storage in uniform phase spin-waves that are insensitive to motional dephasing. The three-step driving enables a number of other features, including spatial selectivity of the excitation region within the atomic medium, and kick-free and Doppler-free excitation that produces narrow resonances in thermal vapor. As a proof of concept, we present an experimental demonstration of the generalized EIT scheme using the 6 S1 /2→6 P3 /2→7 S1 /2→8 P1 /2 excitation path in thermal cesium vapor. This technique could be applied to cold and thermal ensembles to enable longer storage times for Rydberg polaritons.
Transient scaling and resurgence of chimera states in networks of Boolean phase oscillators
NASA Astrophysics Data System (ADS)
Rosin, David P.; Rontani, Damien; Haynes, Nicholas D.; Schöll, Eckehard; Gauthier, Daniel J.
2014-09-01
We study networks of nonlocally coupled electronic oscillators that can be described approximately by a Kuramoto-like model. The experimental networks show long complex transients from random initial conditions on the route to network synchronization. The transients display complex behaviors, including resurgence of chimera states, which are network dynamics where order and disorder coexists. The spatial domain of the chimera state moves around the network and alternates with desynchronized dynamics. The fast time scale of our oscillators (on the order of 100ns) allows us to study the scaling of the transient time of large networks of more than a hundred nodes, which has not yet been confirmed previously in an experiment and could potentially be important in many natural networks. We find that the average transient time increases exponentially with the network size and can be modeled as a Poisson process in experiment and simulation. This exponential scaling is a result of a synchronization rate that follows a power law of the phase-space volume.
Pekalski, J.; Ciach, A.; Almarza, N. G.
2014-03-21
The short-range attraction and long-range repulsion between nanoparticles or macromolecules can lead to spontaneous pattern formation on solid surfaces, fluid interfaces, or membranes. In order to study the self-assembly in such systems we consider a triangular lattice model with nearest-neighbor attraction and third-neighbor repulsion. At the ground state of the model (T = 0) the lattice is empty for small values of the chemical potential μ, and fully occupied for large μ. For intermediate values of μ periodically distributed clusters, bubbles, or stripes appear if the repulsion is sufficiently strong. At the phase coexistences between the vacuum and the ordered cluster phases and between the cluster and the lamellar (stripe) phases the entropy per site does not vanish. As a consequence of this ground state degeneracy, disordered fluid phases consisting of clusters or stripes are stable, and the surface tension vanishes. For T > 0 we construct the phase diagram in the mean-field approximation and calculate the correlation function in the self-consistent Brazovskii-type field theory.
Cui, H. T.
2010-04-15
Overlap with the separable state is introduced in this article for the purpose of characterizing the overall correlation in many-body systems. This definition has clear geometric and physical meaning and moreover can be considered as the generalization of the concept of the Anderson orthogonality catastrophe. As an exemplification, it is used to mark the phase transition in the Dicke model for zero and finite temperatures, and the discussion shows that it can faithfully reflect the phase transition properties of this model whether for zero or finite temperature. Furthermore, the overlap for the ground state also indicates the appearance of multipartite entanglement in the Dicke model.
NASA Astrophysics Data System (ADS)
Moortgat, Joachim; Li, Zhidong; Firoozabadi, Abbas
2012-12-01
Most simulators for subsurface flow of water, gas, and oil phases use empirical correlations, such as Henry's law, for the CO2 composition in the aqueous phase, and equations of state (EOS) that do not represent the polar interactions between CO2and water. Widely used simulators are also based on lowest-order finite difference methods and suffer from numerical dispersion and grid sensitivity. They may not capture the viscous and gravitational fingering that can negatively affect hydrocarbon (HC) recovery, or aid carbon sequestration in aquifers. We present a three-phase compositional model based on higher-order finite element methods and incorporate rigorous and efficient three-phase-split computations for either three HC phases or water-oil-gas systems. For HC phases, we use the Peng-Robinson EOS. We allow solubility of CO2in water and adopt a new cubic-plus-association (CPA) EOS, which accounts for cross association between H2O and CO2 molecules, and association between H2O molecules. The CPA-EOS is highly accurate over a broad range of pressures and temperatures. The main novelty of this work is the formulation of a reservoir simulator with new EOS-based unique three-phase-split computations, which satisfy both the equalities of fugacities in all three phases and the global minimum of Gibbs free energy. We provide five examples that demonstrate twice the convergence rate of our method compared with a finite difference approach, and compare with experimental data and other simulators. The examples consider gravitational fingering during CO2sequestration in aquifers, viscous fingering in water-alternating-gas injection, and full compositional modeling of three HC phases.
NASA Astrophysics Data System (ADS)
Miyagawa, Kazuya; Hirata, Michihiro; Ishikawa, Kyohei; Taniguchi, Tomotaka; Tamura, Masafumi; Kanoda, Kazushi
2014-03-01
The Dirac electron phase is realized in the bulk organic systems, θ and α-(BEDT-TTF)2I3. The bulky nature of the system allows one to study the Dirac electrons in the spin degrees of freedom by means of NMR (K. Miyagawa et al. JPSJ 79, 063703 (2010)). Moreover, in θ-(BEDT-TTF)2I3, the Dirac electron phase neighbors a metallic (superconducting) phase in a pressure-temperature phase diagram. To clarify how the Dirac phase emerges from the metallic state, we performed 13C NMR measurements for this material at ambient and under pressures. The angular dependence of NMR spectra demonstrates that all the molecules are equivalent (Hirata et al. PRB 85, 195146, (2012)). The temperature dependences of Knight shift and spin-lattice relaxation rate, 1/T1, hold the Korringa relation, which signifies metallicity under pressures before the transition to the Dirac phase. However, after the system undergoes a transition to the Dirac electron state, the NMR spectral shape becomes complicated indicating a structural phase transition. The analysis of the angular dependence of the NMR spectra shows the molecular arrangement changes from theta to alpha type. Supported in part by JSPS KAKENHI under Grant Nos. 20110002, 25220709 and 24654101.
Botcharova, Maria; Berthouze, Luc; Brookes, Matthew J.; Barnes, Gareth R.; Farmer, Simon F.
2015-01-01
The capacity of the human brain to interpret and respond to multiple temporal scales in its surroundings suggests that its internal interactions must also be able to operate over a broad temporal range. In this paper, we utilize a recently introduced method for characterizing the rate of change of the phase difference between MEG signals and use it to study the temporal structure of the phase interactions between MEG recordings from the left and right motor cortices during rest and during a finger-tapping task. We use the Hilbert transform to estimate moment-to-moment fluctuations of the phase difference between signals. After confirming the presence of scale-invariance we estimate the Hurst exponent using detrended fluctuation analysis (DFA). An exponent of >0.5 is indicative of long-range temporal correlations (LRTCs) in the signal. We find that LRTCs are present in the α/μ and β frequency bands of resting state MEG data. We demonstrate that finger movement disrupts LRTCs correlations, producing a phase relationship with a structure similar to that of Gaussian white noise. The results are validated by applying the same analysis to data with Gaussian white noise phase difference, recordings from an empty scanner and phase-shuffled time series. We interpret the findings through comparison of the results with those we obtained from an earlier study during which we adopted this method to characterize phase relationships within a Kuramoto model of oscillators in its sub-critical, critical, and super-critical synchronization states. We find that the resting state MEG from left and right motor cortices shows moment-to-moment fluctuations of phase difference with a similar temporal structure to that of a system of Kuramoto oscillators just prior to its critical level of coupling, and that finger tapping moves the system away from this pre-critical state toward a more random state. PMID:26136690
Erbium concentration dependent absorbance in tellurite glass
Sazali, E. S. Rohani, M. S. Sahar, M. R. Arifin, R. Ghoshal, S. K. Hamzah, K.
2014-09-25
Enhancing the optical absorption cross-section in topically important rare earth doped tellurite glasses is challenging for photonic devices. Controlled synthesis and detailed characterizations of the optical properties of these glasses are important for the optimization. The influence of varying concentration of Er{sup 3+} ions on the absorbance characteristics of lead tellurite glasses synthesized via melt-quenching technique are investigated. The UV-Vis absorption spectra exhibits six prominent peaks centered at 490, 526, 652, 800, 982 and 1520 nm ascribed to the transitions in erbium ion from the ground state to the excited states {sup 4}F{sub 7/2}, {sup 2}H{sub 11/2}, {sup 4}F{sub 9/2}, {sup 4}I{sub 9/2}, {sup 2}H{sub 11/2} and {sup 4}I{sub 13/2}, respectively. The results are analyzed by means of optical band gap E{sub g} and Urbach energy E{sub u}. The values of the energy band gap are found decreased from 2.82 to 2.51 eV and the Urbach energy increased from 0.15 to 0.24 eV with the increase of the Er{sub 2}O{sub 3} concentration from 0 to 1.5 mol%. The excellent absorbance of the prepared tellurite glasses makes them suitable for fabricating solid state lasers.
A metallic mosaic phase and the origin of Mott-insulating state in 1T-TaS2
Ma, Liguo; Ye, Cun; Yu, Yijun; Lu, Xiu Fang; Niu, Xiaohai; Kim, Sejoong; Feng, Donglai; Tománek, David; Son, Young-Woo; Chen, Xian Hui; Zhang, Yuanbo
2016-01-01
Electron–electron and electron–phonon interactions are two major driving forces that stabilize various charge-ordered phases of matter. In layered compound 1T-TaS2, the intricate interplay between the two generates a Mott-insulating ground state with a peculiar charge-density-wave (CDW) order. The delicate balance also makes it possible to use external perturbations to create and manipulate novel phases in this material. Here, we study a mosaic CDW phase induced by voltage pulses, and find that the new phase exhibits electronic structures entirely different from that of the original Mott ground state. The mosaic phase consists of nanometre-sized domains characterized by well-defined phase shifts of the CDW order parameter in the topmost layer, and by altered stacking relative to the layers underneath. We discover that the nature of the new phase is dictated by the stacking order, and our results shed fresh light on the origin of the Mott phase in 1T-TaS2. PMID:26961788
Oil and fat absorbing polymers
NASA Technical Reports Server (NTRS)
Marsh, H. E., Jr. (Inventor)
1977-01-01
A method is described for forming a solid network polymer having a minimal amount of crosslinking for use in absorbing fats and oils. The polymer remains solid at a swelling ratio in oil or fat of at least ten and provides an oil absorption greater than 900 weight percent.
Counterflow absorber for an absorption refrigeration system
Reimann, Robert C.
1984-01-01
An air-cooled, vertical tube absorber for an absorption refrigeration system is disclosed. Strong absorbent solution is supplied to the top of the absorber and refrigerant vapor is supplied to the bottom of the absorber to create a direct counterflow of refrigerant vapor and absorbent solution in the absorber. The refrigeration system is designed so that the volume flow rate of refrigerant vapor in the tubes of the absorber is sufficient to create a substantially direct counterflow along the entire length of each tube in the absorber. This provides several advantages for the absorber such as higher efficiency and improved heat transfer characteristics, and allows improved purging of non-condensibles from the absorber.
Zaveri, Rahul A.; Easter, Richard C.; Shilling, John E.; Seinfeld, J. H.
2014-05-27
Evidence is mounting that the majority of the climatically active aerosols are produced through the growth of smaller particles via secondary organic aerosol (SOA) formation from gas-to-particle conversion of anthropogenic and biogenic volatile organic compounds (VOCs). The timescale of SOA partitioning and the associated size distribution dynamics are expected to depend on the gas-phase oxidation of the precursor VOCs and their products, volatility of these organic solutes, composition and phase state of the pre-existing particles, and diffusivity and reactivity of the solute within the particle phase. This paper describes a new framework for modeling kinetic gas-particle partitioning of SOA, with an analytical treatment for the diffusion-reaction process within the particle phase. The formulation is amenable for eventual use in regional and global climate models, although it currently awaits implementation of the actual particle-phase reactions that are important for SOA formation. In the present work, the model is applied to investigate the competitive growth dynamics of the Aitken and accumulation mode particles while the Kelvin effect and coagulation are neglected for simplicity. The timescale of SOA partitioning and evolution of number and composition size distributions are evaluated for a range of solute volatilities (C*), particle-phase bulk diffusivities (Db), and particle-phase reactivity, as exemplified by a pseudo-first-order rate constant (kc). Results show that irreversible condensation of non-volatile organic vapors (equivalent to ) produces significant narrowing of the size distribution. At the other extreme, non-reactive partitioning of semi-volatile organic vapors is volume-controlled in which the final (equilibrium) size distribution simply shifts to the right on the diameter axis while its shape remains unchanged. However, appreciable narrowing of the size distribution may occur when the pre-existing particles are highly viscous semi-solids such
Chen, Haixia; Zhang, Jing
2007-02-15
We propose a scheme for continuous-variable quantum cloning of coherent states with phase-conjugate input modes using linear optics. The quantum cloning machine yields M identical optimal clones from N replicas of a coherent state and N replicas of its phase conjugate. This scheme can be straightforwardly implemented with the setups accessible at present since its optical implementation only employs simple linear optical elements and homodyne detection. Compared with the original scheme for continuous-variable quantum cloning with phase-conjugate input modes proposed by Cerf and Iblisdir [Phys. Rev. Lett. 87, 247903 (2001)], which utilized a nondegenerate optical parametric amplifier, our scheme loses the output of phase-conjugate clones and is regarded as irreversible quantum cloning.
Yang, Yu; Yao, Hongwei; Hong, Mei
2015-04-16
Nonlamellar lipid membranes are frequently induced by proteins that fuse, bend, and cut membranes. Understanding the mechanism of action of these proteins requires the elucidation of the membrane morphologies that they induce. While hexagonal phases and lamellar phases are readily identified by their characteristic solid-state NMR line shapes, bicontinuous lipid cubic phases are more difficult to discern, since the static NMR spectra of cubic-phase lipids consist of an isotropic (31)P or (2)H peak, indistinguishable from the spectra of isotropic membrane morphologies such as micelles and small vesicles. To date, small-angle X-ray scattering is the only method to identify bicontinuous lipid cubic phases. To explore unique NMR signatures of lipid cubic phases, we first describe the orientation distribution of lipid molecules in cubic phases and simulate the static (31)P chemical shift line shapes of oriented cubic-phase membranes in the limit of slow lateral diffusion. We then show that (31)P T2 relaxation times differ significantly between isotropic micelles and cubic-phase membranes: the latter exhibit 2 orders of magnitude shorter T2 relaxation times. These differences are explained by the different time scales of lipid lateral diffusion on the cubic-phase surface versus the time scales of micelle tumbling. Using this relaxation NMR approach, we investigated a DOPE membrane containing the transmembrane domain (TMD) of a viral fusion protein. The static (31)P spectrum of DOPE shows an isotropic peak, whose T2 relaxation times correspond to that of a cubic phase. Thus, the viral fusion protein TMD induces negative Gaussian curvature, which is an intrinsic characteristic of cubic phases, to the DOPE membrane. This curvature induction has important implications to the mechanism of virus-cell fusion. This study establishes a simple NMR diagnostic probe of lipid cubic phases, which is expected to be useful for studying many protein-induced membrane remodeling phenomena
Cherne, Frank J; Jensen, Brian J; Elkin, Vyacheslav M
2009-01-01
The complexity of cerium combined with its interesting material properties makes it a desirable material to examine dynamically. Characteristics such as the softening of the material before the phase change, low pressure solid-solid phase change, predicted low pressure melt boundary, and the solid-solid critical point add complexity to the construction of its equation of state. Currently, we are incorporating a feedback loop between a theoretical understanding of the material and an experimental understanding. Using a model equation of state for cerium we compare calculated wave profiles with experimental wave profiles for a number of front surface impact (cerium impacting a plated window) experiments. Using the calculated release isentrope we predict the temperature of the observed rarefaction shock. These experiments showed that the release state occurs at different magnitudes, thus allowing us to infer where dynamic {gamma} - {alpha} phase boundary is.
On the formation of molecules and solid-state compounds from the AGB to the PN phases
NASA Astrophysics Data System (ADS)
García-Hernández, D. A.; Manchado, A.
2016-07-01
During the asymptoyic giant branch (AGB) phase, different elements are dredge- up to the stellar surface depending on progenitor mass and metallicity. When the mass loss increases at the end of the AGB, a circumstellar dust shell is formed, where different (C-rich or O-rich) molecules and solid-state compounds are formed. These are further processed in the transition phase between AGB stars and planetary nebulae (PNe) to create more complex organic molecules and inorganic solid-state compounds (e.g., polycyclic aromatic hydrocarbons, fullerenes, and graphene precursors in C-rich environments and oxides and crystalline silicates in O-rich ones). We present an observational review of the different molecules and solid-state materials that are formed from the AGB to the PN phases. We focus on the formation routes of complex fullerene (and fullerene-based) molecules as well as on the level of dust processing depending on metallicity.
Nakane, Kazuya; Kamijo, Takeshi; Ichinose, Ikuo
2011-02-01
In the present paper, we study a spin-1/2 antiferromagnetic (AF) Heisenberg model on layered anisotropic triangular lattice and obtain its phase structure. We use the Schwinger bosons for representing spin operators and also a coherent-state path integral for calculating physical quantities. Finite-temperature properties of the system are investigated by means of the numerical Monte-Carlo simulations. A detailed phase diagram of the system is obtained by calculating internal energy, specific heat, spin correlation functions, etc. There are AF Neel, paramagnetic, and spiral states. Turning on the plaquette term (i.e., the Maxwell term on a lattice) of an emergent U(1) gauge field that flips a pair of parallel spin-singlet bonds, we found that there appears a phase that is regarded as a deconfined spin-liquid state, though 'transition' to this phase from the paramagnetic phase is not of second order but a crossover. In that phase, the emergent gauge boson is a physical gapless excitation coupled with spinons. These results support our previous study on an AF Heisenberg model on a triangular lattice at vanishing temperature.
Electronic Spin and Valence States of Iron in the Al-rich NAL and CF Phases in the Subducted Slabs
NASA Astrophysics Data System (ADS)
Wu, Y.; Wu, X.; Lin, J. F.; Yoshino, T.; McCammon, C. A.; Xiao, Y.; Prakapenka, V.
2014-12-01
The New hexagonal aluminous (NAL) phase and orthorhombic calcium-ferrite (CF) type phase are believed to be the main hosts of aluminum (with ~ 20 wt% proportion) in the MORB composition in the Earth's lower mantle. It has been proposed that the NAL and CF phases contains approximately 12 mol% Fe. Most of previous studies on the NAL and CF phases have focused on their crystal structural stability and transitions1,2, while, their spin and valence states of Fe as well as the Fe effects on the behavior of Al-rich phases remain unclear. The spin transition of Fe-bearing phase in the lower mantle has significant effects on density, compressibility, elasticity and sound velocity of the host mineral, and that is important to understand the geophysics and geodynamics of the Earth's mantle3. Here we have investigated the iron spin and valence states of the NAL and CF phases up to 85 GPa via high-pressure nuclear forward scattering and X-ray diffraction measurements. Our results show that both Fe2+ and Fe3+ valence states exist in the NAL phase structure, and that Fe3+ in the octhahedral site undergoes a high-spin to low-spin transition at approximately 30 GPa. X-ray diffraction results further reveal the effects of the spin and valence states on the equation of state parameters of the NAL phase. These results are applied to understand how the spin transition affects the behavior of the NAL and CF phases in the subducted slabs in the Earth's lower mantle. And the spin transition of Al-rich phases may play a significant role on the subduction behavior of the slabs in the Earth's lower mantle. References[1] Perrillat, J.-P.; Ricolleau, A.; Daniel, I. Physics of the Earth and Planetary Interiors 2006, 157, 139. [2] Ricolleau, A.; Perrillat, J.-P.; Fiquet, G. Journal of Geophysical Research 2010, 115. [3] Lin, J.-F.; Speziale, S.; Mao, Z. Reviews of Geophysics 2013, 51, 244.
Garifullin, Azat; Gurov, Igor; Volynsky, Maxim
2016-08-01
Recovery of an unwrapped wavefront in phase-shifting interferometry is considered when the wavefront phase increments are determined between previous and subsequent fringe patterns as well as between adjacent pixels of the current fringe pattern. A parametric model of a three-dimensional interferometric signal and the recurrence processing algorithm in state space are utilized, providing an evaluation of an unwrapped wavefront phase at each phase shift step in dynamic mode. Estimates of the achievable accuracy and experimental results of the wavefront recovery are presented. Comparison with the conventional seven-frame phase-shifting algorithm, which is one of the most accurate, confirmed the high accuracy and noise immunity of the proposed method. PMID:27505660
Seiler, Hélène; Walsh, Brenna; Palato, Samuel; Kambhampati, Patanjali; Thai, Alexandre; Forget, Nicolas; Crozatier, Vincent
2015-09-14
We present a detailed analysis of a setup capable of arbitrary amplitude, phase, and polarization shaping of broadband visible femtosecond pulses at 1 kHz via a pair of actively phase stabilized acousto-optic programmable dispersive filters arranged in a Mach-Zehnder interferometer geometry. The setup features phase stability values around λ/225 at 580 nm as well as degrees of polarization of at least 0.9 for any polarization state. Both numbers are important metrics to evaluate a setup's potential for applications based on polarization-shaped femtosecond pulses, such as fully coherent multi-dimensional electronic spectroscopy.
NASA Astrophysics Data System (ADS)
Seiler, Hélène; Walsh, Brenna; Palato, Samuel; Thai, Alexandre; Crozatier, Vincent; Forget, Nicolas; Kambhampati, Patanjali
2015-09-01
We present a detailed analysis of a setup capable of arbitrary amplitude, phase, and polarization shaping of broadband visible femtosecond pulses at 1 kHz via a pair of actively phase stabilized acousto-optic programmable dispersive filters arranged in a Mach-Zehnder interferometer geometry. The setup features phase stability values around λ/225 at 580 nm as well as degrees of polarization of at least 0.9 for any polarization state. Both numbers are important metrics to evaluate a setup's potential for applications based on polarization-shaped femtosecond pulses, such as fully coherent multi-dimensional electronic spectroscopy.
Model of quantum stochastic absorption in absorbing disordered media
NASA Astrophysics Data System (ADS)
Pradhan, Prabhakar
2006-08-01
Wave propagation in coherently absorbing disordered media is generally modeled by adding a complex part to the real part of the potential. In such a case, it is already understood that the complex potential plays a duel role; it acts as an absorber as well as a reflector due to the mismatch of the phase of the real and complex parts of the potential. Although this model gives expected results for weakly absorbing disordered media, it gives unphysical results for the strong-absorption regime where it causes the system to behave like a perfect reflector. To overcome this issue, we develop a model here for one-dimentional systems using stochastic absorption for the modeling of absorption by “fake,” or “side,” channels, obviating the need for a complex potential. This model of stochastic absorption eliminates the reflection that is coupled with the absorption in the complex potential model and absorption is proportional to the magnitude of the absorbing parameter. Solving the statistics of the reflection coefficient and its phase for both the models, we argue that stochastic absorption is a potentially better way of modeling absorbing disordered media.
/SIGMA PHI/-tocopherol: modifier of the phase state of the lipid bilayer
Skrypin, V.I.; Bratkcovskaya, L.B.; Erin, A.N.; Kagan, V.E.
1985-05-01
This paper determines the action of low (near-physiological) concentrations of alpha-tocopherol on the character of the gel-liquid crystal transition in a lipid bilayer containing free fatty acids. Fifty mM of K/sup +/-phosphate buffer was made up in D/sub 2/O and kept for several hours to enable substitution of H 1 by D 2, after which the buffer was dried and redissolved in D/sub 2/O. The graphs of temperature dependence of relative signal intensity of protons of methylene groups in liposomes of different composition are presented. It is shown that the stabilizing action of alpha-tocopherol on the phase state of the lipid bilayer of membranes is one of the mechanisms by which the recently demonstrated ability of alpha-tocopherol to protect biological membranes against the injurious action of free fatty acids, through the formation of complexes of alpha-tocopherol with fatty acides, may be effected.
Ground state, collective mode, phase soliton and vortex in multiband superconductors.
Lin, Shi-Zeng
2014-12-10
This article reviews theoretical and experimental work on the novel physics in multiband superconductors. Multiband superconductors are characterized by multiple superconducting energy gaps in different bands with interaction between Cooper pairs in these bands. The discovery of prominent multiband superconductors MgB2 and later iron-based superconductors, has triggered enormous interest in multiband superconductors. The most recently discovered superconductors exhibit multiband features. The multiband superconductors possess novel properties that are not shared with their single-band counterpart. Examples include: the time-reversal symmetry broken state in multiband superconductors with frustrated interband couplings; the collective oscillation of number of Cooper pairs between different bands, known as the Leggett mode; and the phase soliton and fractional vortex, which are the main focus of this review. This review presents a survey of a wide range of theoretical exploratory and experimental investigations of novel physics in multiband superconductors. A vast amount of information derived from these studies is shown to highlight unusual and unique properties of multiband superconductors and to reveal the challenges and opportunities in the research on the multiband superconductivity. PMID:25398159
Steady-state electrodiffusion. Scaling, exact solution for ions of one charge, and the phase plane.
Leuchtag, H R; Swihart, J C
1977-01-01
This is the first of two papers dealing with electrodiffusion theory (the Nernst-Planck equation coupled with Gauss's law) and its application to the current-voltage behavior of squid axon. New developments in the exact analysis of the steady-state electrodiffusion problem presented here include (a) a scale transformation that connects a given solution to an infinity of other solutions, suggesting the po-sibility of direct comparison of electrical data for membranes with different thicknesses and other properties; (b) a first-integral relation between the electric field and ion densities more general than analogous relations previously reported, and (c) an exact solution for the homovalent system, i.e., a membrane system permeated by various ion species of the same charge. The latter is a generalization of the known one-ion solution. The properties of the homovalent solution are investigated analytically and graphically. In particular we study the phase-plane curves, which reduce to the parabolas discussed by K. S. Cole in the special case in which the current-density parameter (a linear combination of the ionic current densities) is zero. PMID:831855
AC-field-induced quantum phase transitions in density of states
NASA Astrophysics Data System (ADS)
Yang, Kai-Hua; Liu, Kai-Di; Wang, Huai-Yu; Qin, Chang-Dong
2016-02-01
We investigate the joint effects of the intralead electron interaction and an external alternating gate voltage on the time-averaged local density of states (DOSs) of a quantum dot coupled to two Luttinger-liquid leads in the Kondo regime. A rich dependence of the DOSs on the driving amplitude and intralead interaction is demonstrated. We show that the feature is quite different for different interaction strengths in the presence of the ac field. It is shown that the photon-assisted transport processes cause an additional splitting of the Kondo peak or dip, which exhibits photon-assisted single-channel (1CK) or two-channel Kondo (2CK) physics behavior. The phase transition between photon-assisted 1CK and 2CK physics occurs when the interaction strength is moderately strong. The inelastic channels associated with photon-assisted electron tunneling can dominate electron transport for weak interaction when the ac amplitude is greater than the frequency by one order of magnitude. In the limit of strong interaction the DOSs scale as a power-law behavior which is strongly affected by the ac field.
When do we need to account for the geometric phase in excited state dynamics?
Ryabinkin, Ilya G.; Joubert-Doriol, Loïc; Izmaylov, Artur F.
2014-06-07
We investigate the role of the geometric phase (GP) in an internal conversion process when the system changes its electronic state by passing through a conical intersection (CI). Local analysis of a two-dimensional linear vibronic coupling (LVC) model Hamiltonian near the CI shows that the role of the GP is twofold. First, it compensates for a repulsion created by the so-called diagonal Born–Oppenheimer correction. Second, the GP enhances the non-adiabatic transition probability for a wave-packet part that experiences a central collision with the CI. To assess the significance of both GP contributions we propose two indicators that can be computed from parameters of electronic surfaces and initial conditions. To generalize our analysis to N-dimensional systems we introduce a reduction of a general N-dimensional LVC model to an effective 2D LVC model using a mode transformation that preserves short-time dynamics of the original N-dimensional model. Using examples of the bis(methylene) adamantyl and butatriene cations, and the pyrazine molecule we have demonstrated that their effective 2D models reproduce the short-time dynamics of the corresponding full dimensional models, and the introduced indicators are very reliable in assessing GP effects.
Bunkin, N. F.; Gorelik, V. S.; Kozlov, V. A. Shkirin, A. V. Suyazov, N. V.
2014-11-15
Phase microscopy is used to show that the refractive index in the near-surface layer of water at the surface of a polymer Nafion membrane increases by a factor of 1.1 as compared to bulk water. Moreover, this layer exhibits birefringence. Experiments on UV irradiation of dry (anhydrous) and water-soaked Nafion are performed in grazing-incidence geometry to study their stimulated luminescence spectra. These spectra are found to be identical in both cases. For dry Nafion, luminescence can only be excited if probing radiation illuminates the polymer surface. The luminescence of water-soaked Nafion can also be excited if the distance between the optical axis and the surface is several hundred micrometers.
ERIC Educational Resources Information Center
Marzano Research Laboratory, 2010
2010-01-01
Phase II provides a more detailed examination of classroom variables important to achievement in Oklahoma schools. Where Phase I addressed all nine of the Oklahoma essential elements using survey data, Phase II focuses on what occurs in Oklahoma classrooms primarily using data from principal interviews, classroom observations (on-site), and video…
NASA Astrophysics Data System (ADS)
Ilo-Okeke, Ebubechukwu O.; Byrnes, Tim
2016-07-01
We further examine a theory of phase contrast imaging (PCI) of cold atomic gases, first introduced by us in Phys. Rev. Lett. 112, 233602 (2014), 10.1103/PhysRevLett.112.233602. We model the PCI measurement by directly calculating the entangled state between the light and the atoms due to the ac Stark shift, which induces a conditional phase shift on the light depending upon the atomic state. By interfering the light that passes through the BEC with the original light, one can obtain information of the atomic state at a single-shot level. We derive an exact expression for a measurement operator that embodies the information obtained from PCI, as well as the backaction on the atomic state. By the use of exact expressions for the measurement process, we go beyond the continuous variables approximation such that the non-Gaussian regime can be accessed for both the measured state and the postmeasurement state. Features such as the photon probability density, signal, signal variance, Fisher information, error of the measurement, and the backaction are calculated by applying the measurement operator to an atomic two-spin-state system. For an atomic state that is initially in a spin-coherent state, we obtain analytical expression for these quantities. There is an optimal atom-light interaction time that scales inversely proportional to the number of atoms, which maximizes the information readout.
Lin, S.; Zhang, G.; Li, C.; Song, Z.
2016-01-01
We study the tight-binding model for a graphene tube with perimeter N threaded by a magnetic field. We show exactly that this model has different nontrivial topological phases as the flux changes. The winding number, as an indicator of topological quantum phase transition (QPT) fixes at N/3 if N/3 equals to its integer part [N/3], otherwise it jumps between [N/3] and [N/3] + 1 periodically as the flux varies a flux quantum. For an open tube with zigzag boundary condition, exact edge states are obtained. There exist two perfect midgap edge states, in which the particle is completely located at the boundary, even for a tube with finite length. The threading flux can be employed to control the quantum states: transferring the perfect edge state from one end to the other, or generating maximal entanglement between them. PMID:27554930
Lin, Shan-Yang
2015-02-01
Here, I provide an overview of the solid-state characteristics, phase transformations and chemical reactions of metoclopramide hydrochloride monohydrate (MCP HCl H2O). Three unique techniques, including thermoanalytical methods, one-step simultaneous differential scanning calorimetry (DSC) and Fourier transform infrared (FTIR) microspectroscopy, and hot-stage microscopic (HSM) imaging, have been applied to study the solid-state phase transitions of MCP HCl H2O in continuous dehydration, amorphization and recrystallization processes. I also review the effects of grinding or heating on ion-exchange reactions, milling, compression or colyophilization on Maillard reactions, and γ-ray irradiation or electron beams on radiolysis in the solid state. I also report the exposure of MCP HCl H2O in solution to light, irradiation, oxidants or π-acceptors. This review will serve as a useful keynote for the evolving realm of solid-state chemistry research.
NASA Astrophysics Data System (ADS)
Lin, S.; Zhang, G.; Li, C.; Song, Z.
2016-08-01
We study the tight-binding model for a graphene tube with perimeter N threaded by a magnetic field. We show exactly that this model has different nontrivial topological phases as the flux changes. The winding number, as an indicator of topological quantum phase transition (QPT) fixes at N/3 if N/3 equals to its integer part [N/3], otherwise it jumps between [N/3] and [N/3] + 1 periodically as the flux varies a flux quantum. For an open tube with zigzag boundary condition, exact edge states are obtained. There exist two perfect midgap edge states, in which the particle is completely located at the boundary, even for a tube with finite length. The threading flux can be employed to control the quantum states: transferring the perfect edge state from one end to the other, or generating maximal entanglement between them.
NASA Astrophysics Data System (ADS)
Miserev, D. S.
2016-06-01
The problem of localized states in 1D systems with a relativistic spectrum, namely, graphene stripes and carbon nanotubes, is studied analytically. The bound state as a superposition of two chiral states is completely described by their relative phase, which is the foundation of the variable phase method (VPM) developed herein. Based on our VPM, we formulate and prove the relativistic Levinson theorem. The problem of bound states can be reduced to the analysis of closed trajectories of some vector field. Remarkably, the Levinson theorem appears as the Poincaré index theorem for these closed trajectories. The VPM equation is also reduced to the nonrelativistic and semiclassical limits. The limit of a small momentum p y of transverse quantization is applicable to an arbitrary integrable potential. In this case, a single confined mode is predicted.